United States
Environmental Protection
Agency
Office of Air Quality
Planning And Standards
Research Triangle Park, NC 27711
EPA-450/2-90-001a
January 1990
AIR
<>EPA
Air Emissions
Species Manual
Volume I
Volatile Organic
Compound
Species Profiles
Second Edition
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EPA-450/2-90-0013
January 1990
Air Emissions Species Manual
Volume I: Volatile Organic Compound
Species Profiles
Second Edition
By:
Radian Corporation
3200 Progress Center
P.O.BOX 13000
Research Triangle Park, North Carolina 27709
Contract No. 68-02-4286
Work Assignment No. 91
William B. Kuykendal, Project Officer
Office Of Air Quality Planning And Standards
Office Of Air And Radation
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
Charles C. Masser, Project Officer
Air And Energy Engineering Research Laboratory
Office Of Research And Development
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
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This report has been reviewed by the Office of Air Quality Planning and Standards,
U.S. Environmental Protection Agency, and approved for publication as received from
the contractor. Approval does not signify that the contents neeessairly reflect the
views and policies of the Agency, neither does mention of trade names or commercial
products constitute endorsement or recommendation for use.
EPA-450/2-90-001a
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REPORT USER FEEDBACK AND MAIL KEY REGISTRATION
The U.S. Environmental Protection Agency's (EPA) Office of Air Quality
Planning and Standards (OAQPS) provides technical support to assist State and
local air pollution control agencies in developing and implementing air toxics
programs. , One way that OAQPS, provides assistance to agencies and other
interested individuals is by compiling and publishing emission data for agencies
and others who are interested in locating potential emitters of toxic air
compounds and in making preliminary estimates of toxic air emissions. These
reports published by EPA are introductory documents only, and they are not
intended to provide exact estimates of air toxics releases from specific
facilities. EPA will update and expand these reports and publish new documents
as toxic air emissions data are obtained. Your comments on the usefulness of
this report and availability of additional data which could be used to extend
and improve it, are important input to this process. Please provide any
information to us that will allow us to improve these reports. The format below
is provided for your convenience.
Please check the appropriate blanks and mail to:
Pollutant Characterization Section
Noncriteria Pollutant Programs Branch (MD-15)
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
I have additional air toxics emission data that would help EPA. Please
contact me.
Other comments on the report or needs for similar reports.
NAME:
POSITION:
COMPANY/AGENCY:
MAILING ADDRESS:
PHONE NUMBER: (
REPORT TITLE:
iia
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FOREWORD
This report is the result of a cooperative effort between the Office of
Air Quality Planning and Standards' Air Quality Management Division (AQMD) and
the Office of Research and Development's Air and Energy Engineering Research
Laboratory (AEERL). The overall management of the program was the
responsibility of AQMD. AEERL was responsible for the development of selected
VOC species profiles as well as program review.
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ABSTRACT
The U. S. Environmental Protection Agency (EPA) has several ongoing
activities that require speciated volatile organic compound (VOC) or
particulate matter (PM) profiles from several source categories. In 1980, EPA
published the "Volatile Organic Compound (VOC) Species Data Manual, Second
Edition" (EPA-450/4-80-015) which provided VOC species profiles for some
emission source categories. In 1985, EPA published the "Receptor Model Source
Composition Library" (EPA-450/4-85/002) which contained particulate matter
(PM) species profiles for several source categories. More recently, EPA
published the "Air Emission Species Manual - Volume I, Volatile Organic
Compound (VOC) Species Profiles" (EPA-450/2-88-033a) and the "Air Emissions
Species Manual - Volume II, Particulate Matter Species Profiles" (EPA-450/2-
88-033b). These documents represent expansions of the 1980 and 1985 VOC and
PM species profile document.
In 1989 EPA updated the VOC and PM profile data bases by adding in new
profiles and making necessary revisions to existing profiles. These updates
are contained in the document "Addendum to the Air Emissions Species Manual"
(EPA-450/2-88-003c). The objective of the current study is to produce a
second edition of the "Air Emissions Species Manual" (EPA-450/2-88-003a,b)
that incorporates and contains all the updates specified in the "Addendum ..."
document.
The updated VOC species profile data base is contained in Volume I of
this second edition document. The VOC profile data base includes VOC profiles
from primarily three sources: (1) the 1980 VOC Data Manual, (2) new VOC
profiles developed from readily available existing data, and (3) new VOC
profiles developed from original data as a result of the VOC speciation field
sampling program. In addition to the VOC profiles, Volume I contains profile
assignments that link a profile to a source category. For categories where
profile data are not available, the profile assignments are based on
engineering judgement.
The revised PM species profile data base is contained in Volume II of
this document. It was developed from multiple sources of information. Many
PM profiles were extracted from the Source Composition Library with minor
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changes in format to facilitate inclusion of additional information in the
profiles. A large number of PM profiles were developed by contacting
researchers working in the areas of PM species profile development and source
receptor modeling. These researchers were questioned regarding the
availability of PM species profile data that were not already contained in the
Source Composition Library or the Air Emissions Species Manual. New species
profiles were developed from data submitted by the researchers for a variety
of source categories. A limited number of new PM profiles developed from
literature review are also included in the PM data base. As in the VOC
profile data base, the PM data base also contains profile assignments.
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VOLUME I - VOLATILE ORGANIC COMPOUND (VOC) SPECIES PROFILES
CONTENTS
Page
Foreword i i i
Abstract iv
Tabl es i x
Executive Summary xi
1. Introduction 1
2. VOC Species Profile Format and Application 7
2.1 VOC Species Profile Format 7
2.2 VOC Species Profiles 11
2.3 VOC Species Profile Application 11
2.3.1 Document Use 12
2.3.2 Example of Use of Profile . 12
3. VOC Species Profiles - Point and Area Sources 15
3.1 External Combustion Boilers 25
3.2 Internal Combustion Engines 37
3.3 Carbon Black Production 45
3.4 Paint Manufacture 49
3.5 Varnish Manufacture 53
3.6 Plastics Production 57
3.7 Printing Ink Manufacture 65
3.8 Synthetic Organic Fiber Production .... 69
3.9 Organic Chemical Manufacture 73
3.10 Food and Agriculture 131
3.11 Primary and Secondary Metal Production 135
3.12 Asphalt Products 147
3.13 Petroleum Products 155
3.14 Plywood Products 165
3.15 Synthetic Rubber Production 169
3.16 Oil and Gas Production 175
3.17 Textile Products 189
3.18 Organic Solvent Evaporation 195
3.19 Surface Coating Operations 223
3.20 Storage, Transportation, and Marketing of
Petroleum Products , 255
3.21 Printing/Publishing Processes 271
3.22 Organic Chemical Storage 281
3.23 Railcar, Tank Truck, and Drum Cleaning 355
3.24 Solid Waste Disposal 363
3.25 Wood Combustion 369
3.26 Mobile Sources - Gasoline Fueled Vehicles 375
3.27 Aircraft 391
3.28 Forest Fires 399
References 403
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CONTENTS (Continued)
Page
Appendices
A. Literature Search and VOC Species Profile Development A-l
B. Industry-Specific Average VOC Profiles and "Zero"
Profile B-l
C. VOC Profile Assignments C-l
D. Chemical Species Data File D-l
E. Chemical Species Classification E-l
F. Data File Description F-l
G. VOC Speciation Test Program G-l
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TABLES
Table Pace
2-1 Sample Profile .... 8
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EXECUTIVE SUMMARY
The U. S. Environmental Protection Agency (EPA) has several activities
that require speciated particulate matter (PM) or volatile organic compound
(VOC) profiles from several source categories. Some of these activities are
preparation of air toxics and acid precipitation emission inventories, acid
precipitation modeling studies, receptor modeling, and ozone strategy
development. In an effort to update the available speciated PM profile data
base, EPA conducted studies to update the "Receptor Model Source Composition
Library" (EPA-450/4-85-002) and produced a revision entitled "Air Emissions
Species Manual - Volume II, Particulate Matter Species Profiles" (EPA-450/2-
88-003b). Similarly for VOC emissions, EPA has performed studies to revise
the "Volatile Organic Compound Species Data Manual - Second Edition" (EPA-
450/4-80-015) and provide and updated version in the "Air Emissions Species
Manual - Volume I, Volatile Organic Compound Species Profiles" (EPA-450/2-88-
003a). The Air Emissions Species Manual (Volumes I and II) was recently
updated by the document "Addendum to the Air Emissions Species Manual (EPA-
450/2-88-003c). The update took the form of adding in new PM and VOC profiles
to the speciation data base and making revisions to several existing VOC
profiles.
The objective of the current study was to produce a second edition of
the Air Emissions Species Manual for VOC that contains all existing VOC
profiles data and those VOC data contained in the "Addendum" document (EPA-
450/2-88-003c). The "Addendum" document added only eight new VOC profiles to
those contained previously in the first edition of the VOC Species Manual
(EPA-450/2-88-003a). These eight profiles are numbered 1205 to 1212 and
pertain to crude oil production and processing sources.
The only other change to the first edition of the VOC Species Manual,
contained in the "Addendum," relates to corrections that were made in three
profiles for mobile sources. Minor revisions were made to existing VOC
profiles for light-duty gasoline vehicles to reflect corrections necessary for
compounds that coelute on the gas chromatography analyses. The specific VOC
profiles affected by the revisions are 1101, 1203, and 1204. The primary
revisions were to the benzene/cyclohexane and propane/propene splits.
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Overall, there are over 250 original VOC profiles in this document. Of
these profiles, about 30 percent are extracted from the 1980 VOC Data Manual,
about 65 percent are new profiles developed from existing data or based on
engineering judgement, and about 5 percent are new profiles from the VOC
species field program. In addition, this document contains about 50 industry-
specific average profiles. The profiles from the 1980 VOC Data Manual cover
the following source categories: petroleum products, surface coating
operations, external and internal combustion, solid waste disposal, primary
and secondary metal production, and asphalt production. Most of the new
profiles developed from existing data represent the following source
categories: organic chemical manufacturing, storage of organic chemicals,
aircraft emissions, oil and gas production, surface coating operations, mobile
sources, and gasoline evaporation. The profiles for the last three categories
were replacements for poor quality and/or outdated profiles in the 1980 VOC
Data Manual.
The VOC profile data contained in this volume are presented in a format
that is basically the same as the one used in the 1980 Data Manual. Each
profile contains the following information:
Profile name
Profile number
Profile data quality
Control device identification
References
Data source
Source Classification Code (SCC)
Chemical species identified by: Storage and Retrieval of Aerometric
Data (SAROAD) code. Chemical Abstract System (CAS) number, species
name, molecular weight, weight percent
Date
In addition to the VOC profiles, this document contains VOC profile
assignments for all SCC's in the National Emissions Data System (NEDS) and
applicable NEDS area source codes and additional area source codes used in the
National Acid Precipitation Assessment Program (NAPAP). Ideally, a profile
XII
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would be needed to represent each one of these categories. However, the
number of categories to be characterized is much larger than the available
profiles. Therefore, profile assignments that involve linking a VOC profile
to a source category that does not have an original profile assignment are
developed using engineering judgement.
Source category profile assignments are especially important in
activities such as preparation of air toxics and acid precipitation emission
inventories and acid precipitation modeling studies. For several SCO's,
profile assignments using engineering judgement were not possible; however, in
such cases, industry-specific average profiles were developed. These profiles
were developed from original profiles representing other SCC's within the same
industry group. The industry-specific average profiles are intended for use
only if there is no other information available. In addition, a "zero"
profile which is an overall average based on all the VOC profiles in the data
base was developed. This profile is intended for use only as a default
profile to represent those SCC's characterized by "zero" or "negligible" VOC
emission factors according to the document "Criteria Pollutant Emission
Factors for the 1985 Emissions Inventory" (EPA-600/7-87-015) and for which the
States or any other agency have reported nonzero emissions.
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XIV
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SECTION 1
INTRODUCTION
The U. S. Environmental Protection Agency (EPA) has several ongoing
activities that require speciated volatile organic compound (VOC) profiles
from several source categories. Some of these activities are preparation of
acid precipitation and air toxics emission inventories and ozone strategy
development.
As part of an effort to update the available speciated PM profile data
base, EPA conducted studies to update the "Receptor Model Source Composition
Library" (EPA-450/4-85-002) and produced a revision entitled "Air Emissions
Species Manual - Volume II, Particulate Matter Species Profiles" (EPA-450/2-
88-003b). Similarly for VOC emissions, EPA has performed studies to revise
the "Volatile Organic Compound Species Data Manual - Second Edition" (EPA-
450/4-80-015) and provide an updated version in the "Air Emissions Species
Manual - Volume I, Volatile Organic Compound Species Profiles" (EPA-450/2-88-
003a). The Air Emissions Species Manual (Volumes I and II) was recently
updated by the document "Addendum to the Air Emissions Species Manual (EPA-
450/2-88-003c). The update took the form of adding in new PM and VOC profiles
to the speciation data base and making revisions to several existing VOC
profiles. The objective of this current document is to provide a Second
Edition of the Air Emissions Species Manual for VOC that incorporates the data
in the previous Volume I report and the Addendum document.
The production of the original Volume I of the Air Emissions Species
Manual (EPA-450/2-88-003a) for VOC was based primarily on the 1980 VOC Data
Manual (EPA-450/4-80-015), a field sampling program, and limited literature
data. Revision of the 1980 VOC Data Manual consisted of identifying poor
quality and/or outdated profiles and replacing them with new VOC profiles.
Profiles for which there were no replacements were retained in the data base
even if the profiles were of low data quality. In cases where there were
several profiles representing a given source category, the most general
profile with the highest quality level was selected. The profiles extracted
from the 1980 VOC Data Manual were included in the current work without any
changes except revisions made to data quality indicators for pure
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solvent/product profiles. The original references used in developing these
profiles in the 1980 VOC Data Manual were also included as part of the
references listed in this report. The profiles from the 1980 VOC Data Manual
are identified by profile numbers ranging from 0001 through 0333.
Several new VOC profiles were developed as a result of literature search
efforts that focused on revising the poor quality and/or outdated VOC profiles
in the 1980 VOC Data Manual, and filling the existing data gaps primarily in
the air toxics area. The key sources of information used included a study
conducted for the California Air Resources Board (Reference 1), source
assessment and background information documents, Section 114 responses and
trip reports from several standard development activities, and work conducted
by the Atmospheric Sciences Research Laboratory. In addition, work performed
during the Northeast Corridor Regional Modeling Project (NECRMP), work
currently in progress under the National Acid Precipitation Assessment Program
(NAPAP), data obtained from Environment Canada, and data obtained from States
were reviewed (see Appendix A for details of the data gathering and review
activities).
In addition to the profiles developed from existing data, five new VOC
profiles were developed from original data that resulted from a VOC speciation
test program (see Appendix G for details). These profiles represent the
following source categories: gasoline marketing, degreasing, drycleaning,
autobody repair, and graphic arts-printing.
Overall, close to 200 new profiles were developed. About 80 percent of
the new profiles cover source categories that were not characterized in the
1980 VOC Data Manual, e.g., organic chemical manufacturing, oil and gas
production, organic chemical storage, plastics production, textiles, aircraft
emissions, etc. The remaining 20 percent are replacements for poor quality
and/or outdated profiles in the 1980 VOC Data Manual. Most of these profiles
cover the surface coating operations, mobile sources, and gasoline
evaporation. Other profiles developed in this study included pure component
profiles to represent storage or solvent usage operations that involve
handling and use of pure compounds. Development of these profiles was based
on engineering judgement.
In several cases, speciated data were available from a single emission
source. In cases where data were available from a number of emission sources,
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the data were composited in proportion to the emissions rate of each source
(refer to Appendix A where a detailed description of species profile
development is included).
This document represents the Second Edition of the VOC Air Emissions
Species Manual. It was compiled from the data in Volume I (EPA-450/2-88-003a)
and from VOC data in the "Addendum to the Air Emissions Species Manual" (EPA-
450/2-88-003c). The Addendum document served to add eight new VOC profiles
and make revisions to three existing data base profiles. The eight additions
reflect information on oil wells and oil field operations that EPA obtained
from the Tulsa City-County Health Department. Tulsa recently conducted a
sampling and analysis program to quantify emissions of 30 organic compounds
from six different types of oil field operations. The Tulsa data were
submitted to EPA and profiles were developed according to the protocols and
procedures specified in the VOC Air Emissions Species Manual (EPA-450/2-88-
033a). The original Tulsa sampling results can be obtained from the report
"Oil Field Emissions of Volatile Organic Compounds" (EPA-450/2-89-007). The
VOC profiles added to the data base by the Tulsa data are numbered 1205 to
1212.
The revisions to the existing data base involved mobile sources
profiles. Minor revisions were made to the VOC profiles for light-duty
gasoline vehicles to reflect corrections necessary for compounds that coelute
on the gas chromatography analyses. The specific VOC profiles affected by the
revisions are 1101, 1203, and 1204. The primary revisions were to the
benzene/cyclohexane and propane/propene splits.
The activities where VOC species profiles are applied typically employ
SCC codes for point sources and the NEDS area source codes to represent
emission source categories. Ideally, each source category would be
characterized by an appropriate VOC profile. Since there are much fewer
species profiles than source categories, a VOC profile is assigned to other
source categories that are judged to be similar to the source category(ies)
having the original profile. This document contains VOC profile assignments
for all the SCC's in the NEDS data base and the applicable NEDS area source
codes. In addition, profile assignments are provided for area source codes
used in the NAPAP studies. The development of VOC profile assignments is
discussed in detail in Appendix C. Also included in this appendix are the
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listings of the assignments for both point and area sources.
To provide the reader/user with guidance on the overall quality of data
contained in each profile, an arbitrary scheme (A, B, C, D, E) similar to the
one used in AP-42 was used to rank each profile. For example, Profile Data
Quality A was assigned to profiles that were considered representative of the
total population of sources within a given SCC and that were based on sound
analytical techniques with full documentation. Profiles based on engineering
judgement and that may not be considered representative of the total
population were assigned Profile Data Quality E. A more detailed discussion
on profile data quality is contained in Section 2.
Data quality indicators were also used to characterize the VOC profile
assignments. Where the VOC profile assignment is based on an original
profile, the data quality indicator reflects the Profile Data Quality on the
profile (see Section 3). In cases where the assignment is based on
engineering judgement, the data quality is typically lowered one or more
levels depending on how well the profile represents the "new" category.
For several SCC's, profile assignment using engineering judgement was
not possible. In such cases, industry-specific average profiles were
developed from original profiles representing other SCC's within the same
industry group. These profiles have numbers starting with 9 and are
recommended for use only if there is no other information available. In
addition, Profile 0000 which is an overall average based on all the profiles
in the data base was developed. This profile is intended for use only as a
default profile in applications such as emission inventory development. The
"zero" profile is applied to those SCC's characterized by "zero" or
"negligible" VOC emission factors and for which the States or any other agency
have reported nonzero VOC emissions. The SCC's with "zero" and "negligible"
emission factors were identified from the document "Criteria Pollutant
Emission Factors for the 1985 NAPAP Emissions Inventory" (EPA-600/7-87-015).
This document is divided into four sections with numerous supporting
appendices. Section 1 contains this introduction. Section 2 describes the
VOC species profile format and discusses the applicability of VOC profiles in
various activities. Section 3 contains the VOC profiles for both point
sources and area sources, followed by the list of references.
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There are seven appendices that provide additional information:
Appendix A - Literature Search and VOC Species Profile Development
Appendix B - Industry-Specific Average Profiles and "Zero" Profile
Appendix C - VOC Profile Assignments
Appendix D - Chemical Species Data File
Appendix E - Chemical Species Classification
Appendix F - Data File Description
Appendix G - VOC Speciation Test Program
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SECTION 2
VOC SPECIES PROFILE FORMAT AND APPLICATION
2.1 VOC SPECIES PROFILE FORMAT
Table 2-1 is an example of the format used in presenting the VOC
profiles for this document; it is basically the same as that used in the 1980
Data Manual except for a few changes. Although the profiles in the 1980 Data
Manual contain chemical classification information for each species, this
information is not included in this document, since there are several
different classification schemes currently used. However, two examples are
included in Appendix E. Another item that is not included in the new VOC
profile format is information on volumetric or molar composition (volumetric
or molar percentages). Several manual users indicated that this information
is of very little use in their work. Each of the entries in Table 2-1 is
described below:
Profile name: In a majority of the cases, the profile name is the
descriptor used for the applicable source category. In cases where a
particular profile is applicable to more than one source category, a more
general term is used to identify a given profile.
Profile number: This is a unique number assigned arbitrarily to a
profile. A numerical listing of all the VOC profiles in this document is
provided in Appendix A.
Profile data quality: A ranking scheme is employed to assign data
quality indicators to each profile. This approach is similar to the one used
in the 1980 Data Manual and also consistent with the approach used in AP-42
for emission factors. The following criteria were used in assigning data
quality indicators:
Data Quality A: Data set based on a composite of several tests
using analytical techniques such as GC/MS and
can be considered representative of the total
population.
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TABLE 2-1. SAMPLE PROFILE
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Terephthalic Acid/Dimethyl Terephthalate Distillation and Recovery Vent
1024
Control Device
Reference(s)
Data Source
Condenser
29
Composite profile developed using data from four
emission sources (weighted according to emission
rates); one data set is based on vent analysis, and the
others are based on engineering calculations.
SCC Assignments: 30103104
Saroad
43301
43350
43432
43503
45204
CAS Number
67-56-1
115-10-6
79-20-9
75-07-0
95-47-6
Name
METHYL ALCOHOL
DIMETHYLETHER
HETHYLACETATE
ACETALDEHYDE
0-XYLENE
Spec_MU
32.04
46.07
74.08
44.05
106.16
Spec_WT Peak
7.77
66.64
16.33
8.43
0.83
TOTAL
100.00
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Data Quality B:
Data Quality C:
Data Quality D:
Data Quality E:
Data set based on a composite of several tests
using analytical techniques such as GC/MS and
can be considered representative of a large
percentage of the total population. Profiles
from the VOC field sampling program are assigned
data quality "B."
Data set based on a small number of tests using
analytical techniques such as GC/MS and can be
considered reasonably representative of the
total population.
Data set based on a single source using analytical
techniques such as GC/MS; or data set from a
number of sources where data are based on
engineering calculations.
Data set based on engineering calculations from one
source; data set(s) based on engineering
judgement; data set(s) with no documentation
provided; may not be considered representative
of the total population.
Control device: This entry is used to indicate if the profile data
represent an emission stream downstream or upstream of a control device (if
present) since the composition of the uncontrolled and controlled streams may
be significantly different.
Reference(s): This entry identifies the primary reference(s) used in
developing the profiles. If more detailed information is required, the
user/reader should consult these references.
Data source: This entry briefly describes the basis of the composition
data used in the profile (e.g., number of tests, number of sources, analytical
methods, how data were composited, etc.). More detailed information about the
data used can be obtained from the references indicated.
SCC: This entry is the code for the source category for which the
profile was originally developed. These codes are obtained from the current
National Emission Data System (NEDS) for point sources (1-01-001-01 through
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5-03-900-10) and area sources (01 through 64). Area source codes from 65
through 115 developed under NAPAP are also considered. A listing of area
source codes and their descriptions is presented in Table C-3 of Appendix C.
Composition data: Each species in the profile data is identified by a
SAROAD code, CAS number, species name, molecular weight, and weight
percentage. SAROAD codes were obtained from Volume V of the Aeros Manual
Series (third edition, September 1986). For species not contained in this
manual, new SAROAD codes have been assigned following the methodology employed
in the Aeros Manual.
In some profiles, the weight percentages are followed by peak
identifiers (ID's). The peak ID's indicate groups of two or three species
identified as a single peak in GC and/or GC/MS analysis. In most cases in
this document, one of the species in a given peak was arbitrarily assigned the
total weight percentage corresponding to the peak because of a lack of data to
specify a better allocation. For example, in Profile 1097, peak (1)
represents butyraldehyde and crotonaldehyde. The weight percentage for
butyraldehyde is indicated as 1.24, while that for crotonaldehyde is listed as
0.00. A footnote is included at the end of such profiles to explain peak ID
and its use. However, in several of the profiles for mobile sources, data
were available to better allocate coeluting species. In these instances, all
of the weight percentage was not arbitrarily assigned to one compound. For
example, in Profile 1203, peak (12) represents benzene and cyclohexane. Test
data have indicated that the split between the two compounds should be about
50/50. Therefore, the profile shows the split and not a total allocation to
either benzene or cyclohexane.
It should also be noted that in some profiles, a given species appears
more than once with different weight percentages and as part of different
peaks. This is primarily due to the inability to distinguish between isomers
of a given species in interpretation of raw GC/MS data. For example, in
Profile 1192, the species isomers of undecane appears three times with
different weight percentages: (1) zero percent, as part of peak (15) shared
with octahydroindene (0.04 percent) and Cll olefins (zero percent);
(2) 3.03 percent as a single peak; and (3) zero percent, as part of peak (17)
shared with isomers of butyl benzene (0.10 percent).
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Most of the CAS numbers were obtained from the National Air Toxics
Information Clearinghouse Data Base (1985) and the Registry of Toxic Effects
of Chemical Substances (1983 supplement to the 1981-82 edition). For some
species/group of species, CAS numbers were not identified.
Date; This entry will be used to indicate the date the profile was last
reviewed/updated by EPA.
2.2 LIMITATIONS OF DATA
All data identified through the literature search efforts were used as
reported when developing the new profiles in this study. Only those data sets
with sufficient documentation were included. No attempt was made to verify
the completeness/accuracy of the data. The profile data (i.e., species and
weight percentages) extracted from the 1980 VOC Data Manual were incorporated
in the updated VOC data base with no changes.
In some cases, the profiles may not be a full characterization of the
emission source. Therefore, the user/reader is cautioned to use these
profiles with discretion. Nevertheless, the profile data quality indicator
provides a qualitative measure of confidence in a particular profile.
Profiles for individual sources may vary considerably from the values
provided in this document. Therefore, profiles in this document should not be
used to characterize specific sources; rather, they should be used for
screening purposes. Source-specific data should always be preferred to the
use of literature data presented in this document.
2.3 VOC SPECIES PROFILE APPLICATION
There are several ongoing EPA activities that require speciated VOC data
as an input parameter. These activities include preparation of air toxics
emission inventories, ozone strategy development, and preparation of acid
precipitation inventories. This section briefly discusses how to use this
document and provides a specific example to illustrate how to use VOC species
profiles in the preparation of air toxics emission inventories.
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2.3.1 Document Guide
In addition to the VOC profiles contained in Section 3, Appendix C in
this document includes VOC profile assignments for all the VOC profiles. This
appendix also contains a listing of area source codes and their descriptions.
Appendix A contains a numerical listing of all the profiles and their location
in this document.
To identify the applicable profile for a given source category, the
reader should (1) refer to Table C-l or C-2 in Appendix C; (2) identify its
location from Table A-l in Appendix A; and (3) locate the actual profile in
Section 3.
2.3.2 Example of Use of Profile
The easiest way to describe how profiles might be applied is to present
a hypothetical example: A State air pollution control agency is interested in
developing an air toxics emission inventory for the State. An earlier study
conducted for the State has identified a list of toxic/potentially toxic
compounds from several emission sources. The emission rates of these
individual compounds will be used as an input to the proposed air toxics
regulatory program for the State.
The profiles can identify the relative amounts of individual compounds
in a given emission stream. In most cases, emission factors are available for
total VOC's where the compound breakdown is not specified (e.g., AP-42 or the
Criteria Pollutant Emission Factor document). The information contained in
this document supplements these general emissions data. For a given source
category, the appropriate VOC species profile should be identified using
Appendix C and the total VOC emission factor should be multiplied by the
weight fractions for each compound in the profile to determine compound-
specific emission factors.
In this example, formaldehyde is one of the toxic compounds on the
State's list and airport operations are a major emission source. From
Appendix C, the reader/user identifies the profile appropriate for airport
operations. Aircraft emissions are classified as area sources, and Table C-3
12
-------
lists three types of airport operations (civil, military, commercial). Since
the airport in question is commercial, the appropriate profile for area source
code 047 is Profile 1098. To locate Profile 1098, the reader should refer to
Table A-l in Appendix A where the location of each profile is given. From
this table, Profile 1098 is on page 395. If the reader/user is concerned with
point sources, the SCC and the VOC emission factor for a particular category
can be obtained from NEDS or the Criteria Pollutant Emission Factor document.
The weight percentage of formaldehyde in Profile 1098 is 15.00.
Applying the weight fraction of formaldehyde to the total VOC emissions for
the airport of 500,000 Ib/yr, formaldehyde emissions are estimated as
500,000 x 0.15 = 75,000 Ib/yr. The reader/user should review the "Data
Source" description for the profile to ensure that the data apply to the
specific situation on hand. If there are questions, the reader may wish to
review the original document on which the profile is based.
13
-------
14
-------
SECTION 3
VOC SPECIES PROFILES - POINT AND AREA SOURCES
This section contains all the VOC profiles grouped in 29 separate
sections according to source categories. The profiles representing point
sources are presented first, followed by those representing area sources. The
profiles are ordered numerically within each subsection. The following list
can be used to identify and locate the profiles within each section.
Page Number
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
3.1
0001
0002
0003
0004
0005
0195
0217
1085
Profile 1178
Profile 1185
SECTION 3.2
Profile 0007
Profile 0008
Profile 0009
Profile 1001
SECTION 3.3
Profile 1002
SECTION 3.4
Profile 1094
SECTION 3.5
Profile 0066
SECTION 3.6
Profile 0068
Profile 1004
Profile 1005
EXTERNAL COMBUSTION BOILERS
External Combustion Boiler - Residual Oil 27
External Combustion Boiler - Distillate Oil 28
External Combustion Boiler - Natural Gas v 29
External Combustion Boiler - Refinery Gas 30
External Combustion Boiler - Coke Oven Gas 31
Residential Fuel - Natural Gas 32
Coke Oven Blast Furnace Gas 33
External Combustion Boiler - Coal-Slurry 34
Fired
Coal-Fired Boiler - Electric Generation 35
Coal-Fired Boiler - Industrial 36
INTERNAL COMBUSTION ENGINES
Natural Gas Turbine 39
Reciprocating Diesel Fuel Engine 40
Reciprocating Distillate Oil Engine 41
Internal Combustion Engine - Natural Gas 42
CARBON BLACK PRODUCTION
Chemical Manufacturing - Carbon Black 47
Production
PAINT MANUFACTURE
Paint Manufacture - Blending Kettle 51
VARNISH MANUFACTURE
Varnish Manufacturing - Bodying Oil 55
PLASTICS PRODUCTION
Manufacturing - Plastics - Polypropylene 59
Plastics Production - Polystyrene 60
Plastics Production - Polyester Resins 61
15
-------
Paoe Number
SECTION 3.6 - PLASTICS PRODUCTION (Continued)
Profile 1009 - Plastics Production - Acrylonitrile-
Butadiene Styrene Resin
Profile 1091 - Plastics Production - Polyvinyl Chlorides
and Copolymers
SECTION 3.7
Profile 0072
SECTION 3.8
Profile 1092
SECTION 3.9 -
Profile 0076 -
Profile 0078 -
Profile 0079 -
Profile 1006 -
Profile 1023 -
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
1024
1025
1027
1028
1029
1030
1032
1033
1034
1035
Profile 1037 -
Profile 1038 -
Profile 1039 -
Profile 1040 -
PRINTING INK MANUFACTURE
Printing Ink Cooking
SYNTHETIC ORGANIC FIBER PRODUCTION
Synthetic Organic Fiber Production -
Nylon Batch Production Process
ORGANIC CHEMICAL MANUFACTURE
General Pesticides
Ethylene Dichloride - Direct Chi orination
Chemical Manufacturing - Flares
Phthalic Anhydride - o-Xylene Oxidation
Main Process Stream
Terephthalic Acid/Dimethyl Terephthalate
Crystallization, Separation and Drying
Vent
Terephthalic Acid/Dimethyl Terephthalate
Distillation and Recovery Vent
Terephthalic Acid/Dimethyl Terephthalate
Product Transfer Vent
Ketone Production - Methyl Ethyl Ketone
(MEK)
Acetone - Light Ends Distillation Vent
Acetone - Acetone Finishing Column
Aldehydes Production - Formaldehyde -
Absorber Vent
Aldehydes Production - Acrolein -
Distillation System
Aldehydes Production - Acrolein - Reactor
Blowoff Gas
Chloroprene - Butadiene Dryer
Chloroprene - Chloroprene Stripper and
Brine Stripper
Organohalogens - Ethylene Dichloride -
Ethylene Dichloride Via Direct
Chlorination - Distillation Vents
Organohalogens Production - Ethylene
Dichloride - Ethylene Dichloride Via
Oxychlorination
Organohalogens Production - Ethylene
Dichloride - Caustic Scrubber
Fluorocarbons/Chlorof1uorocarbons -
General
62
63
67
71
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
16
-------
Paoe Number
SECTION 3.9 -
Profile 1041 -
Profile 1042 -
Profile 1043 -
Profile 1044 -
Profile 1045 -
Profile 1046 -
Profile 1047 -
Profile 1048 -
Profile 1049 -
Profile 1050 -
Profile 1051 -
Profile 1052 -
Profile 1053 -
Profile 1054 -
Profile 1056 -
Profile 1057 -
Profile 1058 -
Profile 1059 -
Profile
Profile
Profile
Profile
1060
1061
1062
1064
Profile
Profile
Profile
Profile
Profile
Profile
1066
1067
1068
1070
1071
1072
ORGANIC CHEMICAL MANUFACTURE (Continued)
Fluorocarbons/Chlorof1uorocarbons -
Distillation Column
Fluorocarbons/Chlorof1uorocarbons -
Fugitive Emissions - General
Acrylic Acid - Quench Absorber
Organic Acids Production - Formic Acid
Organic Acids Production - Acetic
Anhydride - Distillation Column Vent
Esters Production - Acrylates - Ethyl
Acrylate
Esters Production - Butyl Acrylate
Cumene Production - Cumene Distillation
System Vent
Cyclohexane - General
Cyclohexanone/Cyclohexanol - Phenol
Hydrogenation Process - Distillation Vent
Inert Gas Purge Vent
C02 Purge Vent
Inhibitor Mix Tank
Vinyl Acetate
Vinyl Acetate
Vinyl Acetate
Discharge
Vinyl Acetate -
Ethylene Oxide
Refining Column Vent
Oxygen Oxidation Process
Profile 1065 -
Reactor - C02 Purge Vent
Ethylene Oxide - Oxygen Oxidation Process
Reactor - Argon Purge Vent
Ethylene Oxide - Stripper Purge Vent
Methyl Methacrylate (MMA) - Hydrolysis
Reactor, MMA and Light Ends Distillation
Unit
Methyl Methacrylate (MMA) - Acid
Distillation and MMA Purification
Nitrobenzene - Reactor and Separator Vent -
Washer and Neutralizer Vent
Benzene
Olefins Production - Ethylene - Compressor
Lube Oil Vent
Propylene Oxide - Chlorohydronation
Process - General
Styrene - General
Styrene - Benzene Recycle
Styrene - Styrene Purification
Alcohols Production - Methanol - Purge Gas
Vent
Alcohols Production - Methanol -
Distillation Vent
Chlorobenzene - Tail Gas Scrubber
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
17
-------
Paoe Number
ORGANIC CHEMICAL MANUFACTURE (Continued)
Chlorobenzene - Benzene Drying Distillation
Monochlorobenzene
Chlorobenzene - Vacuum System Vent
1076 - Chlorobenzene - DiChlorobenzene
Crystallization
Profile 1077 - Chlorobenzene - DiChlorobenzene Crystal
Handling/Loading
Fluorocarbon Manufacturing - CF 12/11
Fluorocarbon Manufacturing - CF 23/22
Acetylene
SECTION 3.9
Profile 1073
Profile 1074
Profile 1075
Profile
Profile 1090
Profile 1093
Profile 1120
SECTION 3.10 -
Profile 1188 -
SECTION 3.11 -
Profile 0011 -
Profile 0012 -
Profile 0013 -
Profile 0014 -
Profile 0016 -
Profile 1036 -
Profile 1089 -
Profile 1202 -
SECTION 3.12 -
Profile 0023 -
Profile 0024 -
Profile 0025 -
Profile 0026 -
Profile 1007 -
FOOD AND AGRICULTURE
Fermentation Processes
PRIMARY AND SECONDARY METAL PRODUCTION
By- Product Coke Oven Stack Gas
Blast Furnace Ore Charging and Agglomerate
Iron Sintering
Open Hearth Furnace with Oxygen Lance
Basic Oxygen Furnace
Secondary Aluminum - Pouring and Casting
Secondary Metal Production - Gray Iron
Foundries - Pouring/Casting
Primary Aluminum Production
ASPHALT PRODUCTS
Asphalt Roofing - Spraying
Asphalt Roofing - Tar Kettle
Asphaltic Concrete - Natural Gas Rotary Dryer
Asphaltic Concrete - In Place Road Asphalt
Mineral Products - Asphaltic Concrete
SECTION 3.13
Profile 0029
Profile 0031
Profile 0035
Profile 0039
Profile 0051
Profile 0316
Profile 0321
Cooling Towers
Compressor
123
124
125
126
127
128
129
130
133
137
138
139
140
141
142
143
144
149
150
151
152
153
PETROLEUM PRODUCTS
Refinery Fluid Catalytic Cracker
Refinery Fugitive Emissions - Covered
Drainage/Separation Pits
Refinery Fugitive Emissions
Refinery Fugitive Emissions
Seals Refinery Gas
Profile 0047 - Refinery Fugitive Emissions - Relief Valves, 161
Liquified Petroleum Gas
Natural Gas 162
Pipe/Valve Flanges 163
Pump Seals - Composite 164
157
158
159
160
SECTION 3.14
Profile 1189
PLYWOOD PRODUCTION
Pulp and Paper Industry - Plywood Veneer Dryer
167
18
-------
Pace Number
SECTION 3.15
Profile 0272
Profile 0273
Profile 0274
Profile 1008
SECTION 3.16
Profile 1010
Profile 1011
Profile 1012
Profile 1205
Profile 1206
Profile
Profile
Profile
Profile
Profile
Profile
1207
1208
1209
1210
1211
1212
SYNTHETIC RUBBER PRODUCTION
Automotive Tires - Tuber Adhesive
Automotive Tires - Tuber Adhesive White
Sidewall
Automobile Tire Production
Rubber and Miscellaneous Plastics Products
Fabricated Rubber Products - Styrene/
Butadiene Rubber
OIL AND GAS PRODUCTION
Oil and Gas Production - Fugitives -
Unclassified
Oil and Gas Production - Fugitives - Valves
and Fittings - Liquid Service
Oil and Gas Production - Fugitives - Valves
and Fittings - Gas Service
Crude Oil Production - Well Heads
(Water Flood)
Crude Oil Production - Well Heads
(Water Flood)
Well Heads (Water Flood) Composite
Crude Oil Production - Gathering Tanks
Oilfield Pipeline Tanks
Pipeline Terminal Tanks
Refinery Crude Oil Storage Tanks
Crude Oil Production - Well Heads
(Gas Drive)
SECTION 3.17 - TEXTILE PRODUCTS
Profile 1095 - Textile Products - General Fabric
Operations - Dyeing and Curing
Profile 1096 - Textile Products - General Fabric
Operations - Tenter Frame
SECTION 3.18
Profile 0085
Profile 0087
Profile 0088
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
0089
0090
0197
0271
0275
0277
1021
1142
1149
1192
1193
ORGANIC SOLVENT EVAPORATION
Perchloroethylene - Drycleaning
Degreasing - 1,1,1-Trichloroethane
Degreasing - Trichlorofluoromethane
(Freon 11)
Degreasing
Degreasing
Solvent Use
Degreasing
Degreasing
Degreasing
(Freon 113)
Degreasing - Open Top - Chlorosolve
Furfural
Methanol
Degreasing
Drycleaning
1,1,2-Tri chloroethane
To!uene
Domestic Solvents
Trichloroethylene
Dichloromethane
Tri chlorotri f1uoroethane
171
172
173
174
177
178
179
180
181
182
183
184
185
186
187
191
193
197
198
199
200
201
202
203
204
205
206
207
208
209
212
19
-------
SECTION 3.18 -
Profile 1195 -
Profile 1196 -
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
3.19
0127
0219
0220
0221
0222
0223
0225
0226
0227
0228
0229
0282
0288
0289
0290
0291
0292
1003
Profile 1013
Profile 1016
Profile 1017
Profile 1018
Profile 1019
Profile 1020
Profile 1026
Profile 1031
Profile 1088
Profile 1187
Profile 1194
ORGANIC SOLVENT EVAPORATION
(Continued)
Degreasing Composite
Drycleaning Composite
SURFACE COATING OPERATIONS
Surface Coating - Varnish/Shellac
Surface Coating Paint Solvent - Acetone
Paint Solvent - Ethyl Acetate
Paint Solvent - Methyl Ethyl Ketone
Surface Coating - Enamel - Cellosolve Acetate
Surface Coating - Varnish/Shellac Solvent -
Xylene
Surface Coating - Primer
Surface Coating Solvent -
Surface Coating Solvent -
Surface Coating Solvent -
Surface Coating Solvent
Surface Coating Primer -
Surface Coating Solvent
Surface Coating Solvent
Surface Coating Solvent
Surface Coating Solvent
Surface Coating Solvent
Surface Coating Operations - Coating
Application - Solvent-base Paint
Surface Coating Operations - Coating
Application - Water-base Paint
Surface Coating Operations - Thinning
Solvents - Composite
Surface Coating Operations - Coating
Application - Lacquer
Surface Coating Operations - Coating
Application - Enamel
Surface Coating Operations - Coating
Application - Primer
Surface Coating Operations - Coating
Application - Adhesives
Surface Coating Operations - Thinning
Solvent - Hexylene Glycol
Surface Coating Operations - Thinning
Solvent - Ethylene Oxide
Surface Coating Operations - Adhesive
Application
Citrus Coating
Autobody Repair
Mineral Spirits
- Ethyl Alcohol
- Isopropyl Alcohol
- Isopropyl Acetate
- Lactol Spirits
Naphtha
- Butyl Acetate
Butyl Alcohol
- Cellosolve
- Methyl Alcohol
Dimethylformamide
SECTION 3.20 - STORAGE, TRANSPORTATION, AND MARKETING OF
PETROLEUM PRODUCTS
Fixed Roof Tank - Commercial Jet Fuel (Jet A)
Fixed Roof Tank - Crude Oil Production
Fixed Roof Tank - Crude Oil Refinery
Profile 0100
Profile 0296
Profile 0297
Pace Number
215
219
225
226
227
228
229
230
231
232
233
234
235
236
237
238
239
240
241
242
243
244
245
246
247
248
249
250
251
252
253
257
258
259
20
-------
Page Number
SECTION 3.20 - STORAGE, TRANSPORTATION, AND MARKETING OF
PETROLEUM PRODUCTS (Continued)
Fixed Roof Tank - Crude Oil Marine Terminal
Gasoline - Summer Blend
Gasoline - Winter Blend
Gasoline Refueling
Gasoline Marketed
Profile 0305
Profile 1014
Profile 1015
Profile 1100
Profile 1190
SECTION 3.21
Profile 0166
Profile 0182
Profile 0183
Profile 0332
PRINTING/PUBLISHING PROCESSES
Printing Press - Letterpress Inking Process
Gravure General Solvent
Gravure Printing Solvent
Lithography Inking and
Printing Press
Printing Press
Printing Press
Drying
Profile 0333 - Lithography - Inking and Drying - Direct
Fired Dryer
Profile 1022 - Printing/Publishing - Ink Thinning
Solvents - Methyl Isobutyl Ketone
Printing/Flexographic
Graphic Arts - Printing
Profile 1086
Profile 1191
SECTION 3.22 -
Profile 0230 -
Profile 0299 -
Profile 0301 -
Profile 0304 -
Profile 1055 -
Profile 1069 -
Profile 1087 -
ORGANIC CHEMICAL STORAGE
Fixed Roof Tank - Hexane
Fixed Roof Tank
Fixed Roof Tank
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
1103
1104
1105
1106
1107
1108
1109
1110
1111
1112
1114
1115
1116
1118
1119
1121
1122
1123
Cyclohexane
Heptane
Printing Press - Flexographic, n-Propyl
Alcohol
Organic Chemical Storage - Methylamyl
Ketone
Organic Chemical Storage - N-Propyl
Acetate
Organic Chemical Storage/i-Butyl
i-Butyrate
1-Pentene
Acetaldehyde
Acetic Acid
Acetic Anhydrid
Acrolein
Acrylic Acid
Acrylonitrile
Adipic Acid
Aniline
Benzyl Chloride
Butyl Acrylate
Butyl Carbitol
Butyl Cellosolve
Carbitol
Carbon Tetrachloride
Chloroform
Cresol
Cumene
260
261
263
265
267
273
274
275
276
277
278
279
280
283
284
285
286
287
288
289
290
291
292
293
294
295
296
297
298
299
300
301
302
303
304
305
306
307
21
-------
Page Number
SECTION 3.22 - ORGANIC CHEMICAL STORAGE (Continued)
Profile 1124 - Cyclohexanol
Profile 1125 - Cyclohexanone
Profile 1126 - Cyclopentene
Profile 1127 - Diethylene Glycol
Profile 1128 - Diisopropyl Benzene
Profile 1129 - Dipropylene Glycol
Profile 1130 - Dodecene
Profile 1131 - Epichlorohydrin
Profile 1132 - Ethanolamines
Profile 1134 - Ethyl Acrylate
Profile 1135 - Ethyl Benzene
Profile 1136 - Ethyl Ether
Profile 1137 - Ethyl Mercaptan
Profile 1138 - Ethylene Dibromide
Profile 1139 - Ethyleneamines
Profile 1140 - Formaldehyde
Profile 1141 - Formic Acid
Profile 1144 - Heptenes
Profile 1145 - Isobutyraldehyde
Profile 1146 - Isobutyl Acrylate
Profile 1147 - Isobutyl Alcohol
Profile 1148 - Isoprene
Profile 1150 - Methyl Acetate
Profile 1151 - Methyl Acrylate
Profile 1152 - Methyl Carbitol
Profile 1153 - Methyl Cellosolve
Profile 1154 - Methyl Styrene
Profile 1155 - Methyl allene
Profile 1158 - Methyl t-Butyl Ether
Profile 1159 - m-Xylene
Profile 1160 - Nitrobenzene
Profile 1162 - N-Butraldehyde
Profile 1163 - N-Decane
Profile 1164 - N-Dodecane
Profile 1165 - o-Xylene
Profile 1166 - Pentadecane
Profile 1168 - Piperylene
Profile 1171 - Propionaldehyde
Profile 1172 - Propionic Acid
Profile 1173 - Propylene Oxide
Profile 1174 - p-Xylene
Profile 1175 - Tert-Butyl Alcohol
Profile 1176 - Toluene Diisocyanate
Profile 1197 - Isooctane
Profile 1198 - Pentane
Profile 1199 - Isopentane
Profile 1200 - Cyclopentane
308
309
310
311
312
313
314
315
316
317
318
319
320
321
322
323
324
325
326
327
328
329
330
331
332
333
334
335
336
337
338
339
340
341
342
343
344
345
346
347
348
349
350
351
352
353
354
22
-------
Page Number
SECTION 3.23
Profile 1078
Profile 1079
Profile 1080
Profile 1081
Profile 1082
Profile 1083
SECTION
Profile
Profile
Profile
Profi1e
3.24
0121
0122
0202
0203
SECTION 3.25
Profile 1084
Profile 1167
RAILCAR, TANK TRUCK, AND DRUM CLEANING
Rail car Cleaning - Low Vapor Pressure,
High Viscosity Cargo (Ethylene Glycol)
Railcar Cleaning - Low Vapor Pressure,
Medium Viscosity Cargo (o-Dichlorobenzene)
Railcar Cleaning - Low Vapor Pressure,
High Viscosity Cargo (Creosote)
Tank Truck Cleaning - Medium Vapor
Pressure, Medium Viscosity Cargo (Methyl
Methacrylate)
Tank Truck Cleaning - Low Vapor Pressure,
Low Viscosity Cargo (Phenol)
Tank Truck Cleaning - Low Vapor Pressure,
High Viscosity Cargo (Propylene Glycol)
SOLID WASTE DISPOSAL
Open Burning Dump - landscape/Pruning
Bar Screen Waste Incinerator
Solid Waste Landfill Site - Class II
Solid Waste - Animal Waste Decomposition
WOOD COMBUSTION
Residential Wood Combustion (C1-C6)
Residential Wood Combustion
SECTION 3.26 - MOBILE SOURCES
Profile 1101 - Light-Duty Gasoline Vehicles
Profile 1186 - Heavy-Duty Gasoline Trucks
Profile 1201 - Light-Duty Diesel Vehicles
Profile 1203 - Light-Duty Gasoline Vehicles
Emissions
Profile 1204 - Light-Duty Gasoline Vehicles
Emissions
SECTION 3.27
Profile 1097
Profile 1098
Profile 1099
SECTION 3.28
Profile 0307
AIRCRAFT
Aircraft Landing/Takeoff (LTD)
Aircraft Landing/Takeoff (LTO)
Aircraft Landing/Takeoff (LTO)
Aviation
Exhaust
Evaporative
Military
Commercial
General
FOREST FIRES
Miscellaneous Burning - Forest Fires
357
358
359
360
361
362
365
366
367
368
371
372
377
380
383
385
388
393
395
397
401
23
-------
24
-------
3.1 EXTERNAL COMBUSTION BOILERS
External combustion sources include utility, industrial, commercial and
institutional boilers; commercial and domestic combustion units; process
heaters, furnaces, and kilns. Coal, oil, and natural gas are the major fossil
fuels used by these sources.
25
-------
26
-------
VOC Profile Speciation Report
Profile Name
Profile Nunber
Data Quality
Control Device
Reference(s)
Data Source
External Combustion Boiler - Residual Oil
0001
UNCONTROLLED
58,59
Information based on stack sample for residual oil
analyzed by GC/HS.
SCC Assignments: 10100401, 10200401, 10300401, 39990002, 39990012
Saroad
43201
43212
43231
43502
43551
CAS Number
74-82-8
106-97-8
110-54-3
50-00-0
67-64-1
Name
METHANE
N-BUTANE
HEXANE
FORMALDEHYDE
ACETONE
Spec_MW
16.04
58.12
86.17
30.03
58.08
Spec_WT
11.00
14.00
5.00
42.00
28.00
Peak
TOTAL
100.00
27
-------
VCX: Profile Spec i at ion Report
Profile Name
Profile Number
Data Quality
External Combustion Boiler - Distillate Oil
0002
Control Device
Reference(s)
Data Source
Uncontrolled
58,59
Information based on stack sample for residual oil
analyzed by GC/HS.
SCC Assignments: 10100501, 10200501, 10300501, 10500205, 39990001, 39990011
Saroad
CAS Number
Name
Spec_MW Spec_WT Peak
43105
43106
43107
43122
43204
43212
43214
43220
43231
43232
43502
TOTAL
74-98-6
106-97-8
75-28-5
109-66-0
110-54-3
142-82-5
50-00-0
ISOHERS OF HEXANE
ISOHERS OF HEPTANE
ISOHERS OF OCTANE
ISOHERS OF PENTANE
PROPANE
N-BUTANE
ISO-BUTANE
N- PENTANE
HEXANE
HEPTANE
FORMALDEHYDE
86.17
100.20
114.23
72.15
44.09
58.12
58.12
72.15
86.17
100.20
30.03
5.20
2.60
4.70
5.50
1.20
12.20
4.10
4.70
10.80
0.30
48.70
100.00
28
-------
VOC Profile Speciat ion Report
Profile Name
Profile Nunber
Data Quality
External Combustion Boiler - Natural Gas
0003
Control Device
Reference(s)
Data Source
Uncontrolled
58, 59
Information based on stack sample for natural gas
analyzed by GC/MS.
SCC Assignments: 10100601, 10200601, 10300601, 10500106, 10500206, 39990003, 39990013
Saroad
TOTAL
CAS Number
Name
SpecJtW Spec_UT Peak
43105
43122
43201
43204
43212
43220
43248
43502
45201
45202
74-82-8
74-98-6
106-97-8
109-66-0
110-82-7
50-00-0
71-43-2
108-88-3
I SOWERS OF NEXANE
ISOMERS OF PENTANE
METHANE
PROPANE
N- BUTANE
N-PENTANE
CYCLOHEXANE
FORMALDEHYDE
BENZENE
TOLUENE
86.17
72.15
16.04
44.09
58.12
72.15
84.16
30.03
78.11
92.13
1.00
9.00
56.00
4.00
9.00
6.00
1.00
8.00
4.00
2.00
100.00
29
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
External Combustion Boiler - Refinery Gas
0004
C
Uncontrolled
58, 59
Information based on stack sample for refinery gas
analyzed by GC/HS.
SCC Assignments: 10200701
Saroad
TOTAL
CAS Number
Name
Spec_MU Spec_WT Peak
43201
43202
43204
43205
43212
43214
43502
74-82-8
74-84-0
74-98-6
115-07-1
106-97-8
75-28-5
50-00-0
METHANE
ETHANE
PROPANE
PROPENE
N- BUTANE
ISO-BUTANE
FORMALDEHYDE
16.04
30.07
44.09
42.08
58.12
58.12
30.03
7.60
20.90
18.90
17.50
23.10
4.40
7.60
100.00
30
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
External Combustion Boiler - Coke Oven Gas
0005
B
Control Device
Reference(s)
Data Source
SCC Assignments
Uncontrolled
58, 59
Information based on stack sample analyzed by GC/HS.
10200707
Saroad
TOTAL
CAS Number
Name
Spec_HW Spec_WT Peak
43201
43202
43203
43205
43206
45201
74-82-8
74-84-0
74-85-1
115-07-1
74-86-2
71-43-2
METHANE
ETHANE
ETHYLENE
PROPENE
ACETYLENE
BENZENE
16.04
30.07
28.05
42.08
26.04
78.11
82.80
2.50
11.70
0.30
0.80
1.90
100.00
31
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Residential Fuel - Natural Gas
0195
Uncontrolled
59
Information based on composite survey data and GC/HS
analysis of grab sample.
SCC Assignments:
Saroad
43201
TOTAL
CAS Number
74-82-8
Name
METHANE
Spec_HU Spec_UT Peak
16.04 100.00
100.00
-ssss:g:s:ss----SS-S;S!S-=-SES!S=SSJS.
32
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Coke Oven Blast Furnace Gas
0217
B
Control Device
Reference(s)
Data Source
Uncontrolled
49
Information based on composite survey data and GC/NS
analysis of sampling train catch.
SCC Assignments: 39000701
Saroad
TOTAL
CAS Number
Name
Spec_HW Spec_WT Peak
43201
43202
43203
43205
43213
45201
74-82-8
74-84-0
74-85-1
115-07-1
106-98-9
71-43-2
METHANE
ETHANE
ETHYLENE
PROPENE
BUTENE
BENZENE
16.04
30.07
28.05
42.08
56.10
78.11
40.90
1.40
2.80
5.50
6.40
43.00
100.00
33
-------
VOC Profile Speciation Report
Profile Name
Profile Nuriber
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CAS
43140
43201
43202
43220 1
External Combustion Boiler - Coal-Slurry Fired
1085
C
Not reported
16
Information from one source test where data were
obtained using GC.
10200213
! Number Name Spec_HW Spec_UT Peak
C7-C16 PARAFFINS 156.31 39.33
74-82-8 METHANE 16.04 20.00
74-84-0 ETHANE 30.07 38.66
09-66-0 N-PENTANE 72.15 2.00
TOTAL
99.99
34
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Coal-Fired Boiler - Electric Generation
1178
E
Control Device
Reference(s)
Data Source
SCC Assignments
ESP
82
Not described.
10100202
Saroad
TOTAL
CAS Number
Name
Spec_HW Spec_UT Peak
43202
43204
43212
43213
43221
43227
43231
43232
43245
43247
43264
45202
45203
45204
45205
90014
74-84-0
74-98-6
106-97-8
106-98-9
78-78-4
627-20-3
110-54-3
142-82-5
592-41-6
108-08-7
108-88-3
100-41-4
95-47-6
108-38-3
8720-50-9
ETHANE
PROPANE
N-BUTANE
BUTENE
ISO PENTANE
CIS-2-PENTENE
HEXANE
HEPTANE
1-HEXENE
2,4-DIHETHYLPENTANE
HEPTENE
TOLUENE
ETHYLBENZENE
0-XYLENE
H-XYLENE
1-DECENE
30.07
44.09
58.12
56.10
72.15
70.13
86.17
100.20
84.16
100.20
98.18
92.13
106.16
106.16
106.16
140.27
2.09
1.78
0.98
0.79
1.22
1.05
9.45
1.50
3.63
6.39
3.69
5.62
11.25
8.66
39.23
2.67
100.00
35
-------
VOC Profile Speciation Report
Profile Name Coal-Fired Boiler - Industrial
Profile Hunter 1185
Data Quality 0
Control Device Scrubber
Reference(s) 82
Data Source Stack gas
by a GC.
samples collected in Tedlar bags and analyzed
SCC Assignments: 10200204
Saroad
43202
43203
43204
43205
43206
43212
43213
43214
43215
43220
43221
43231
43247
43262
43263
45201
45202
45203
45204
90010
CAS Number
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
106-97-8
106-98-9
75-28-5
115-11-7
109-66-0
78-78-4
110-54-3
108-08-7
96-37-7
591-76-4
71-43-2
108-88-3
100-41-4
95-47-6
Name
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
N-BUTANE
BUTENE
I SO- BUTANE
ISOBUTYLENE
N-PENTANE
ISO PENTANE
HEXANE
2.4-DIHETHYLPENTANE
HETHYLCYCLOPENTANE
2-HETHYL HEXANE
BENZENE
TOLUENE
ETHYLBEMZENE
0-XYLENE
M-XYLENE AND P-XYLENE
Spec_MU
30.07
28.05
44.09
42.08
26.04
58.12
56.10
58.12
56.10
72.15
72.15
86.17
100.20
84.16
100.20
78.11
92.13
106.16
106.16
106.16
Spec_UT
17.79
0.00
5.20
0.77
15.43
6.38
6.09
3.00
0.00
1.18
1.24
7.80
0.00
2.90
0.00
3.78
8.39
5.67
2.60
11.76
Peak
(1 )
(1 )
(2 )
(2 )
(3 )
<4 )
(4 )
(3 )
TOTAL
99.98
36
-------
3.2 INTERNAL COMBUSTION ENGINES
The major types of engines in this category are gas turbines and large,
heavy duty, general utility reciprocating engines. Stationary internal
combustion engines find applications in electrical power generators, in gas
pipeline pump and compressor drives and in various process industries. The
majority of gas turbines are used in electrical generation for continuous,
peaking or stand-by power. The primary fuels used are natural gas and No. 2
(distillate) fuel oil, although residual oil is used in a few applications.
37
-------
38
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Natural Gas Turbine
0007
C
Control Device
Reference(s)
Data Source
Uncontrolled
58, 59
Composite profile developed using data based on GC/MS
analysis of fuel combustion exhaust.
SCC Assignments: 20200201
Saroad
CAS Number
Name
Spec_MW Spec_WT Peak
43201
43502
TOTAL
74-82-8
50-00-0
METHANE
FORMALDEHYDE
16.04
30.03
70.00
30.00
100.00
39
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Reciprocating Diesel Fuel Engine
0008
C
Control Device
Reference(s)
Data Source
Uncontrolled
58, 60
Composite profile developed using data based on GC/MS
analysis of fuel combustion exhaust.
SCC Assignments: 20200401, 20400402
Saroad
TOTAL
CAS Number
Name
Spec_HU Spec_UT Peak
43201
43202
43203
43205
43206
43213
43218
45201
74-82-8
74-84-0
74-85-1
115-07-1
74-86-2
106-98-9
106-99-0
71-43-2
METHANE
ETHANE
ETHYLENE
PROPENE
ACETYLENE
BUTENE
1,3-BUTADIENE
BENZENE
16.04
30.07
28.05
42.08
26.04
56.10
54.09
78.11
11.60
2.80
28.70
17.30
11.30
13.40
7.00
7.90
100.00
40
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Reciprocating Distillate Oil Engine
0009
D
Uncontrolled
58, 60
Composite profile developed using data based on GC/HS
analysis of fuel combustion exhaust.
SCC Assignments: 20100102, 20200102, 20300101
Saroad
CAS Number
Name
Spec_HW SpecJJT Peak
43201
43202
43203
43205
43206
43213
43218
45201
TOTAL
74-82-8
74-84-0
74-85-1
115-07-1
74-86-2
106-98-9
106-99-0
71-43-2
METHANE
ETHANE
ETHYLENE
PROPENE
ACETYLENE
BUTENE
1,3-BUTADIENE
BENZENE
16.04
30.07
28.05
42.08
26.04
56.10
54.09
78.11
11.60
2.80
28.70
17.30
11.30
13.40
7.00
7.90
100.00
41
-------
VOC Profile Speciation Report
Profile Name Internal Combustion Engine - Natural Gas
Profile Number 1001
Data Quality C
Control Device Not reported
Referenee(s)
Data Source
1
Composite
profile developed using samples
two reciprocating engines operating under
taken from
normal
conditions. Samples were analyzed using both a
FID/PID GC and the MBTH method.
SCC Assignments: 20100202,
Saroad
43105
43106
43107
43108
43109
43120
43122
43124
43125
43201
43202
43203
43204
43205
43206
43212
43214
43215
43216
43217
43220
43224
43226
43228
43230
43231
43232
43233
43235
43238
43241
43242
43247
43248
43261
43262
43264
43265
43269
CAS Number
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
106-97-8
75-28-5
115-11-7
624-64-6
590-18-1
109-66-0
109-67-1
646-04-8
513-35-9
96-14-0
110-54-3
142-82-5
111-65-9
111-84-2
124-18-5
1120-21-4
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
111-66-0
124-11-8
20200202, 20200204, 20300201
Name
I SOWERS OF HEXANE
ISOHERS OF HEPTANE
I SOWERS OF OCTANE
ISOHERS OF NONANE
ISOHERS OF DECANE
ISOHERS OF BUTENE
ISOHERS OF PENTANE
C9 OLE FINS
C10 OLEFINS
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
N- BUTANE
I SO- BUTANE
ISOBUTYLENE
T-2-BUTENE
CIS-2-BUTENE
N-PENTANE
1-PENTEHE
TRANS-2-PENTENE
2-HETHYL-2-BUTENE
3-HETHYL PENTANE
HEXANE
HEPTANE
OCTANE
NONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
2,4-DIHETHYLPENTANE
CYCLOHEXANE
METHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
HEPTENE
OCTENE
1-NONENE
Spec_MW
86.17
100.20
114.23
128.25
142.28
56.10
72.15
126.24
140.27
16.04
30.07
28.05
44.09
42.08
26.04
58.12
58.12
56.10
56.11
56.11
72.15
70.13
70.13
70.13
86.17
86.17
100.20
114.23
128.25
142.28
156.31
70.14
100.20
84.16
98.21
84.16
98.18
112.21
126.24
Spec_UT Peak
0.02
0.04
0.02
0.01
0.02
0.26
0.13
0.04
0.02
76.69
14.00
0.63
2.91
1.69
0.32
1.00
0.43
0.02
0.13
0.02
0.13
0.01
0.01
0.01
0.02
0.02
0.02
0.02
0.01
0.01
0.01
0.02
0.01
0.01
0.02
0.04
0.01
0.01
0.01
42
-------
VOC Profile Speciation Report - continued (profile 1001)
Saroad
43291
43295
43298
43502
43503
43511
45102
45109
45110
45201
45202
45203
45204
45205
45207
45208
45211
45212
45225
98040
CAS Number
75-83-2
589-34-4
50-00-0
75-07-0
78-84-2
1330-20-7
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
108-67-8
95-63-6
611-14-3
620-14-4
526-73-8
763-29-1
Name
2,2-DIMETHYlBUTANE
3-METHYLHEXANE
3-HETHYLHEPTANE
FORMALDEHYDE
ACETALDEHYDE
ISOBUTYRALDEHYDE
I SOWERS OF XYLENE
C3/C4/C5 ALKYLBENZENES
C10 AROMATIC
BENZENE
TOLUENE
ETNYLBENZENE
0-XYLENE
H-XYLENE
1,3,5-TRIMETHYLBENZENE
1,2,4-TRIMETHYLBENZENE
0-ETHYLTOLUENE
M-ETHYLTOLUENE
1 ,2,3-TRIHETHYLBENZENE
2-METHYL-1-PENTENE
Spec_HW
86.17
100.20
114.23
30.03
44.05
72.11
106.16
134.21
134.22
78.11
92.13
106.16
106.16
106.16
120.19
120.19
120.19
120.19
120.19
84.16
Spec_WT Peak
0.01
0.01
0.02
0.81
0.03
0.02
0.02
0.01
0.01
0.11
0.04
0.01
0.01
0.01
0.02
0.01
0.01
0.01
0.01
0.02
TOTAL
100.00
43
-------
44
-------
3.3 CARBON BLACK PRODUCTION
Carbon black is produced by the reaction of a hydrocarbon fuel such as. oil
or gas with a limited supply of combustion air at temperatures in excess of
2,000°F. The unburned carbon is collected as an extremely fine black fluffy
particle, 10 to 500 nm in diameter. The principal uses of carbon black are as
a reinforcing agent in rubber compounds (especially tires) and as a black
pigment in printing inks, surface coatings, paper and plastics. The major
process to manufacture carbon black is the oil furnace process. Emission
sources include the main process vent, the dryer vent, the pneumatic transport
system vent, the vacuum cleanup system vent, and fugitive sources.
45
-------
46
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Chemical Manufacturing - Carbon Black Production
1002
D
Uncontrolled
9
Profile was developed from emissions data that was art
average of six sampling runs at a representative plant.
SCC Assignments: 30100504
Saroad
CAS Number
Name
Spec_MW Spec_WT Peak
43201
43203
43204
43206
43212
43214
43933
43934
TOTAL
74-82-8
74-85-1
74-98-6
74-86-2
106-97-8
' 75-28-5
433-58-1
75-15-0
METHANE
ETHYLENE
PROPANE
ACETYLENE
N- BUTANE
I SO- BUTANE
CARBON YL SULF1DE
CARBON SULFIDE
16.04
28.05
44.09
26.04
58.12
58.12
60.08
76.13
22.40
1.40
0.20
40.10
0.20
0.10
8.90
26.70
100.00
47
-------
48
-------
3.4 PAINT MANUFACTURING
Paint manufacture involves the dispersion of a colored oil or pigment,
usually in an oil or resin, followed by the addition of an organic solvent for
viscosity adjustment. Only the physical processes of weighing, mixing,
grinding, tinting, thinning, and packaging take place. No chemical reactions
are involved. These processes take place at room temperature in large mixing
tanks. The primary factors affecting VOC emissions from paint manufacture are
types of solvents used and mixing temperature.
49
-------
50
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Paint Manufacture - Blending Kettle
1094
D
Control Device Uncontrolled
Reference(s) 52
Data Source Seven test runs were conducted to sample the exit vent
the blending kettle. Analytical method and sampling
method are not reported.
SCC Assignments: 30101401
Saroad
CAS Number
Name
Spec_MW Spec_WT Peak
43552
45202
TOTAL
78-93-3
108-88-3
METHYL ETHYL
TOLUENE
KETONE 72.10
92.13
19.35
80.65
100.00
51
-------
52
-------
3.5 VARNISH MANUFACTURE
Processes involved in varnish manufacturing include mixing, blending, and
heating. Varnish is cooked in open or enclosed gas-fired kettles. Cooking
temperatures and times range from 93-340°C and 4-16 hours, respectively.
53
-------
54
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Varnish Manufacturing - Bodying Oil
0066
D
Uncontrolled
61
Information based on engineering evaluation of survey
data.
SCC Assignments: 30101501
Saroad
TOTAL
CAS Number
Name
Spec_MW SpecJJT Peak
43367
43551
43552
43560
111-46-6
67-64-1
78-93-3
108-10-1
GLYCOL ETHER
ACETONE
HETHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
106.14
58.08
72.10
100.16
3.00
38.70
41.60
16.70
100.00
55
-------
56
-------
3.6 PLASTICS PRODUCTION
The manufacture of most resins or plastics begins with the polymerization or
linking of the basic monomer, usually a gas or liquid, into high molecular
weight noncrystalline solids. The manufacture of the basic monomer is not
considered part of the plastics industry; it is usually accomplished at a
chemical or petroleum plant. The manufacture of most plastics involves an
enclosed reaction or polymerization step, a drying step, and a final treating
and forming step. Treatment of the resin after polymerization varies with the
proposed use. The major VOC emission sources in plastics manufacturing are
the emissions of raw materials or monomers, emissions of solvents or other
volatile liquids during the reaction, and emissions of solvents during storage
and handling of thinned resins.
57
-------
58
-------
VOC Profile Speciation Report
Profile Name
Profile Hunter
Data Quality
Control Device
Reference(s)
Data Source
Manufacturing - Plastics - Polypropylene
0068
Uncontrolled
59. 60
Information provided by polypropylene manufacturers,
engineering evaluation of literature data.
SCC Assignments: 30101802
Saroad
43205
TOTAL
CAS Number
115-07-1
Name
PROPENE
Spec_MW SpecJJT Peak
42.08 100.00
100.00
59
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Plastics Production - Polystyrene
1004
D
Not reported
1
Engineering judgement based on survey of plants
in South Coast Air Basin and literature review
conducted by California Air Resources Board (CARS).
SCC Assignments: 30101817
Saroad
45203
45220
CAS Number
100-41-4
100-42-5
Name
ETHYLRENZENE
STYRENE
Spec_MV
106.16
104.14
Spec_WT
10.00
90.00
Peak
TOTAL
SSS==S=========SS===============3S=K=======
100.00
60
-------
VOC Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CAS
45220 1
TOTAL
Plastics Production - Polyester Resins
1005
E
Not reported
1
Engineering judgement.
30101837
1 Number Name Spec_MW Spec_WT Peak
00-42-5 STYRENE 104.14 100.00
100.00
=====:=s=====ss======3:s=s:=ssssss==ss====sssssssssa= s s ssK==sr==ss====s= s
61
-------
VOC Profile Speciation Report
Profile Maine
Profile Number
Data Quality
Plastics Production - Acrylonitrile-Butadiene-Styrene Resin
1009
E
Control Device
Reference(s)
Data Source
SCC Assignments
Not reported
1
Engineering judgement.
30101849
Saroad
CAS Number
Name
Spec_MU Spec_WT Peak
43704
45220
107-13-1
100-42-5
ACRYLONITRILE
STYRENE
53.06
104.14
60.00
40.00
TOTAL
100.00
62
-------
VOC Profile Special ion Report
Profile Name
Profile Number
Data Quality
Plastics Production - Polyvinyl Chlorides and Copolymers
1091
C
Control Device
Reference(s)
Data Source
Scrubber
50
Source emission tests for vinyl chloride of two latex
incinerators. Three test runs were performed on each.
SCC Assignments: 30101801
Saroad
43860
TOTAL
CAS Number
75-01-4
Name
VINYL CHLORIDE
Spec_MW Spec_WT Peak
62.50 100.00
100.00
63
-------
64
-------
3.7 PRINTING INK MANUFACTURE
The major types of printing ink are: letterpress, lithographic,
flexographic, and rotogravure inks. The ink types vary greatly in
composition. The processes involved in printing ink manufacture include:
(1) cooking the vehicle and addition of dyes, (2) grinding the pigment into
the vehicle, and (3) replacing water in the wet pigment pulp with an ink
vehicle. The ink vehicle is cooked to 93-315°C for 8-12 hours. Pigment and
vehicle mixing is done with dough mixers or in agitated tanks. Horizontal or
vertical mills are used for grinding.
65
-------
66
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Printing Ink - Cooking
0072
D
Uncontrolled
62
Engineering evaluation of organic emissions control
strategy report.
SCC Assignments: 30102001
Saroad
CAS Number
Name
SpecJIU Spec_WT Peak
43118
43248
43301
43302
43304
43305
43435
43551
43552
45106
45203
64475-85-0
110-82-7
67-56-1
64-17-5
67-63-t)
71-36-3
138-22-7
67-64-1
78-93-3
100-41-4
MINERAL SPIRITS
CYCLOHEXANE
METHYL ALCOHOL
ETHYL ALCOHOL
ISO-PROPYL ALCOHOL
N-BUTYL ALCOHOL
N-BUTYL ACETATE
ACETONE
METHYL ETHYL KETONE
ISOMERS OF DIETHYLBENZENE
ETHYLBENZENE
114.00
84.16
32.04
46.07
60.09
74.12
116.16
58.08
72.10
134.21
106.16
25.50
5.00
5.00
2.50
38.00
3.00
4.00
5.50
5.00
3.50
3.00
TOTAL
100.00
67
-------
68
-------
3.8 SYNTHETIC ORGANIC FIBER PRODUCTION
Semi-synthetic fibers result when natural polymeric materials such as
cellulose are dissolved or dispersed and then spun into fine filaments. True
synthetic fibers result from addition and other polymerization reactions that
form long chain molecules. The manufacture of true synthetic fibers begins
with the preparation of extremely long, chain-like molecules. The polymer is
then spun in one of four ways: melt spinning, dry spinning, wet spinning, or
core spinning. Emissions may occur during these processes or during drying of
the finished fiber.
69
-------
70
-------
VOC Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Synthetic Organic Fiber Production - Nylon Batch Production Process
1092
D
Control Device
Reference(s)
Data Source
Not reported
51
The evaporator vessel vent stack was sampled during
three separate evaporation cycles with one
hexamethylenediamine emissions run performed during
each cycle. Total organic carbon as carbon cations
were recalculated using a molecular weight ratio for
conversion to hexamethylenediamine.
SCC Assignments: 30102401
Saroad
43776
TOTAL
CAS Number
124-09-4
Name
HEXAMETHYLENEDIAMINE
Spec_HW Spec_WT Peak
116.20 100.00
100.00
71
-------
72
-------
3.9 ORGANIC CHEMICAL MANUFACTURING
The organic chemical industry is a large and diverse industry producing a
large number of intermediate and end-product organic chemicals. A large
proportion of the emissions from the chemical manufacturing industry occur as
organic vapors. Organic particulate emissions may also be generated in some
processes. The emissions typically contain raw material (including
impurities) used and intermediate and final products formed during the
manufacturing process. Emissions sources include storage and handling
emissions, reactor process emissions, separation process emissions, fugitive
emissions, and secondary emissions (e.g., from waste treatment).
73
-------
74
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
General
0076
C
Pesticides
Control Device
Reference(s)
Data Source
Uncontrolled
60, 63
Engineering evaluation of information contained
within State of California pesticide use reports.
SCC Assignments: 30103311, 30103312
Saroad
TOTAL
CAS Number
Name
Spec_MW Spec_WT Peak
43105
43115
43116
43118
43122
43204
43212
43214
43220
43231
43805
45102
45201
45202
64475-85-0
74-98-6
106-97-8
75-28-5
109-66-0
110-54-3
74-95-3
1330-20-7
71-43-2
108-88-3
ISOMERS OF HEXANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
MINERAL SPIRITS
1 SOWERS OF PENTANE
PROPANE
N- BUTANE
I SO- BUTANE
N-PENTANE
HEXANE
METHYLENE BROMIDE
ISOMERS OF XYLENE
BENZENE
TOLUENE
86.17
98.19
112.23
114.00
72.15
44.09
58.12
58.12
72.15
86.17
173.85
106.16
78.11
92.13
8.10
15.40
1.60
15.00
3.10
1.80
4.40
1.40
3.20
3.70
10.00
15.00
12.30
5.00
100.00
75
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Ethylene Dichloride - Direct Chlorination
0078
Control Device Uncontrolled
Reference(s) 64
Data Source Information obtained from ethylene dichloride storage
facility.
SCC Assignments: 30112502, 30112599
Saroad
43815
TOTAL
CAS Number
107-06-2
Name
ETHYLENE DICHLORIDE
Spec_MU Spec_UT Peak
99.00 100.00
100.00
76
-------
Voc Profile Speciation Report
Profile Name
Profile Number
Data Quality
Chemical Manufacturing - Flares
0079
Control Device
Reference(s)
Data Source
SCC Assignments
Uncontrolled
60
Engineering evaluation of composite survey data.
30190099
Saroad
43120
43203
43205
43206
43213
43248
43301
43302
43304
43305
43438
43502
43503
43510
43601
43602
43704
43801
43812
43860
45102
45201
45202
45220
45300
45401
CAS Number
74-85-1
115-07-1
74-86-2
106-98-9
. 110-82-7
67-56-1
64-17-5
67-63-0
71-36-3
140-88-5
50-00-0
75-07-0
123-72-8
75-21-8
75-56-9
107-13-1
74-87-3
75-00-3
75-01-4
1330-20-7
71-43-2
108-88-3
100-42-5
108-95-2
Name
ISOMERS OF BUTENE
ETHYLENE
PROPENE
ACETYLENE
BUTENE
CYCLOHEXANE
METHYL ALCOHOL
ETHYL ALCOHOL
1SO-PROPYL ALCOHOL
N-BUTYL ALCOHOL
ETHYL ACRYLATE
FORMALDEHYDE
ACETALDEHYDE
BUTYRALDEHYDE
ETHYLENE OXIDE
PROPYLENE OXIDE
ACRYLONITRILE
METHYL CHLORIDE
ETHYL CHLORIDE
VINYL CHLORIDE
ISOMERS OF XYLENE
BENZENE
TOLUENE
STYRENE
PHENOL
XYLENE BASE ACIDS
Spec_MU
56.10
28.05
42.08
26.04
56.10
84.16
32.04
46.07
60.09
74.12
100.11
30.03
44.05
72.12
44.05
58.08
53.06
50.49
64.52
62.50
106.16
78.11
92.13
104.14
94.11
230.00
Spec_WT Peak
8.90
21.60
9.00
1.00
4.10
1.80
5.40
1.40
2.50
0.50
0.80
1.70
0.70
0.80
4.60
1.40
3.00
0.90
7.20
0.60
1.30
10.00
4.10
3.40
2.00
1.30
TOTAL
100.00
77
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Phthalic Anhydride - o-Xylene Oxidation - Main Process Stream
1006
E
Control Device Not reported
Reference(s) 1
Data Source Engineering judgement based on review of literature
data (see references listed on page 113 of
Reference 1).
SCC Assignments: 30101901
Saroad
CAS Number
Name
Spec_HU Spec_WT Peak
43603
45204
45402
45601
TOTAL
============
108-31-6
95-47-6
65-85-0
85-44-9
===========
HALE 1C ANHYDRIDE
O-XYLENE
BENZOIC ACID
PHTHALIC ANHYDRIDE
=========================
98.06
106.16
122.13
148.12
=====================
20.00
10.00
10.00
60.00
100.00
==================
78
-------
VOC Profile Spec i at ion Report
Profile Name
Profile Number
Data Quality
Terephthalic Acid/Dimethyl Terephthalate Crystallization, Separation and Drying Vent
1023
D
Control Device Scrubber
Reference(s) 29
Data Source Composite profile developed using data from two
emission sources (weighted according to emission
rates); each data set is based on engineering
calculations.
SCC Assignments: 30103103
Saroad
TOTAL
CAS Number
Name
Spec_MW Spec_WT Peak
43301
45450
67-56-1
120-61-6
METHYL ALCOHOL
DIMETHYL TEREPHTHALATE
32.04
194.19
99.97
0.03
100.00
79
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Terephthalic Acid/Dimethyl Terephthalate Distillation and Recovery Vent
1024
D
Control Device Condenser
Reference(s) 29
Data Source Composite profile developed using data from four
emission sources (weighted according to emission
rates); one data set is based on vent analysis, and the
others are based on engineering calculations.
SCC Assignments: 30103104
Saroad
TOTAL
CAS Number
Name
Spec_HU Spec_WT Peak
43301
43350
43432
43503
45204
67-56-1
115-10-6
79-20-9
75-07-0
95-47-6
HETHYL ALCOHOL
DIMETHYLETHER
METHYLACETATE
ACETALDEHYDE
0-XYLENE
32.04
46.07
74.08
44.05
106.16
7.77
66.64
16.33
8.43
0.83
100.00
80
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Terephthalic Acid/Dimethyl Terephthalate Product Transfer Vent
1025
E
Control Device Not reported
Reference(s) 29
Data Source Information based on engineering calculations from one
emission source.
SCC Assignments: 30103105
Saroad
43201
43404
43432
43503
45206
45403
TOTAL
CAS Number
74-82-8
64-19-7
79-20-9
75-07-0
106-42-3
100-21-0
Name
METHANE
ACETIC ACID
METHYLACETATE
ACETALDEHYDE
P-XYLENE
TEREPHTHALIC ACID
Spec_MW
16.04
60.05
74.08
44.05
106.16
166.14
Spec_WT Peak
17.23
1.35
75.00
1.69
3.38
1.35
100.00
81
-------
VOC Profile Speciation Report
Ketone Production - Methyl Ethyl Ketone (MEK)
Profile Name
Profile Number
Data Quality
1027
E
Control Device Uncontrolled
Reference(s) 39
Data Source Information based on design calculations from one
emission source.
SCC Assignments: 30109105
Saroad
43314
CAS Number
78-92-2
Name
S-BUTYL ALCOHOL
TOTAL
SpecJW Spec_WT Peak
74.12 100.00
100.00
82
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Acetone - Light Ends Distillation Vent
1028
D
Scrubber
21
Information based on vent analysis from one emission
source.
SCC Assignments: 30109153
Saroad
TOTAL
CAS Number
Name
SpecJW Spec_WT Peak
43204
43205
43212
43213
43551
74-98-6
115-07-1
106-97-8
106-98-9
67-64-1
PROPANE
PROPENE
N- BUTANE
BUTENE
ACETONE
44.09
42.08
58.12
56.10
58.08
13.00
24.00
33.00
20.00
10.00
100.00
83
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Acetone
1029
D
Acetone Finishing Column
Condenser
13
Composite profile developed using data based on
engineering calculations from two emission sources
(weighted according to emission rates).
SCC Assignments: 30109154
Saroad
43503
43551
TOTAL
CAS Number
75-07-0
67-64-1
Name
ACETALDEHYDE
ACETONE
Spec_MW
44.05
58.08
Spec_WT
38.03
61.97
100.00
Peak
84
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Aldehydes Production
1030
D
Formaldehyde - Absorber Vent
Control Device
Reference(s)
Data Source
Scrubber
41
Composition data based on vent analysis from one
emission source.
SCC Assignments: 30112005
Saroad
TOTAL
CAS Number
Name
Spec_HW Spec_VT Peak
43201
43301
43430
43457
74-82-8
67-56-1
107-31-3
109-87-5
METHANE
METHYL ALCOHOL
METHYL FORMATE
METHYLAL
16.04
32.04
60.05
76.11
4.28
7.43
63.43
24.86
100.00
85
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Aldehydes Production - Acrolein - Distillation System
1032
E
Control Device Uncontrolled (sent to flare)
Reference(s) 34
Data Source Information based on material balance from one
emission source.
SCC Assignments: 30112033
Saroad
CAS Number
Name
Spec_MU Spec_WT Peak
43503
43505
75-07-0
107-02-8
ACETALDEHYDE
ACROLEIN
44.05
56.07
19.58
80.42
TOTAL
100.00
86
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Aldehydes Production - Acrolein - Reactor Blowoff Gas
1033
D
Control Device Uncontrolled (sent to incinerator)
Reference(s) 34
Data Source Information based on analysis and material balance from
one emission source.
SCC Assignments: 30112099
Saroad
43204
43205
43505
CAS Number
74-98-6
115-07-1
107-02-8
Name
PROPANE
PROPENE
ACROLEIN
Spec_NW
44.09
42.08
56.07
Spec_WT
24.70
37.65
37.65
Peak
TOTAL
100.00
87
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Chloroprene - Butadiene Dryer
1034
Control Device
Reference(s)
Data Source
Uncontrolled
10
Information based on analytical data from one emission
source.
SCC Assignments:
Saroad
43218
TOTAL
CAS Number
106-99-0
Name
1,3-BUTADIENE
Spec_NU Spec_WT Peak
54.09 100.00
100.00
88
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Chloroprene - Chloroprene Stripper and Brine Stripper
1035
Control Device Condenser
Reference(s) 11
Data Source Information based on engineering calculations from one
emission source.
SCC Assignments: 30112406, 30112407
Saroad
43862
TOTAL
CAS Number
126-99-8
Name
CHLOROPRENE
Spec_HW Spec_WT Peak
88.54 100.00
100.00
=========================
89
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organohalogens - Ethylene Dichloride - Ethylene Dichloride Via Direct Chlorination
1037
C
Control Device Uncontrolled
Reference(s) 36, 37
Data Source Composite profile developed using data based on GC
analysis from two emission sources (weighted according
to emissions rate).
SCC Assignments: 30112506
Saroad
CAS Number
Name
SpecJtU !ipec_UT Peak
43201
43202
43203
43812
43815
43860
TOTAL
74-82-8
74-84-0
74-85-1
75-00-3
107-06-2
75-01-4
METHANE
ETHANE
ETHYLENE
ETHYL CHLORIDE
ETHYLENE DICHLORIDE
VINYL CHLORIDE
16.04
30.07
28.05
64.52
99.00
62.50
18.35
3.29
60.60
6.62
11.10
0.04
100.00
90
-------
VOC Profile Spec!ation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Organohalogens Production - Ethylene Dichloride - Ethylene Dichloride Via Oxychlorination
1038
D
Uncontrolled
36
Information based on routine GC and net chemistry
analyses from one emission source.
SCC Assignments: 30112501
Saroad
CAS Number
Name
Spec_MU Spec_UT Peak
43201
43202
43203
43812
43815
43860
99999
TOTAL
ss========:
74-82-8
74-84-0
74-85-1
75-00-3
107-06-2
75-01-4
==============
METHANE
ETHANE
ETHYLENE
ETHYL CHLORIDE
ETHYLENE DICHLORIDE
VINYL CHLORIDE
UNIDENTIFIED
:===-==================--==
16.04
30.07
28.05
64.52
99.00
62.50
86.00
3.73
0.44
10.38
43.40
36.75
1.21
4.09
100.00
91
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organohalogens Production - Ethylene Dichloride - Caustic Scrubber
1039
C
Control Device Scrubber
Reference(s) 36, 37
Data Source Composite profile developed using data based on GC
analysis from two emission sources (weighted according
to emissions rate).
SCC Assignments: 30112504
Saroad
TOTAL
CAS Number
Name
Spec_MU Spec_WT Peak
43201
43202
43203
43812
43815
43860
99999
74-82-8
74-84-0
74-85-1
75-00-3
107-06-2
75-01-4
METHANE
ETHANE
ETHYLENE
ETHYL CHLORIDE
ETHYLENE DICHLORIDE
VINYL CHLORIDE
UNIDENTIFIED
16.04
30.07
28.05
64.52
99.00
62.50
86.00
12.94
1.71
30.50
27.30
18.19
4.13
5.23
100.00
92
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Fluorocarbons/Chlorofluorocarbons - General
1040
D
Condense r/uncont ro11ed
27, 42
Composite profile developed using data from seven
emission sources (weighted according to emissions
rate); each data set is based on operating and design
calculations.
SCC Assignments: 30112701
Saroad
43811
43821
43823
43839
43840
43841
43842
43843
43844
TOTAL
CAS Number
75-69-4
76-13-1
75-71-8
. 75-73-0
75-45-6
76-14-2
76-15-3
76-16-4
75-46-7
Name
TR I CHLOROFLUOROMETHANE
TR I CHLOROTR I FLUOR OETHANE
DICHLORODIFLUOROMETHANE
TETRAFLUOROMETHANE
CHLORCO I FLUOROHETHANE
DICHLOROTETRAFLUORETHANE
CHLOROPENTAFLUOROETHANE
HEXAFLUOROETHANE
TR I FLUOROHETHANE
Spec_MW
137.38
187.38
120.91
88.01
86.47
170.92
154.47
138.01
70.01
Spec_WT Peak
0.01
5.94
0.06
10.02
13.91
4.29
4.76
38.99
22.01
99.99
93
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Fluorocarbons/Chlorofluorocarbons - Distillation Column
1041
D
Control Device Uncontrolled/vacuum jet
Reference(s) 27
Data Source Composite profile developed using data from two
emission sources(ueighted according to emissions rate);
based on vent analysis, and the other on engineering
calculations.
SCC Assignments: 30112702
Saroad
TOTAL
CAS Number
Name
Spec_MU Spec_WT Peak
43804
43811
43823
43843
43844
43845
56-23-5
75-69-4
75-71-8
76-16-4
75-46-7
75-72-9
CARBON TETRACHLORIDE
TRICHLOROFLUOROHETHANE
D I CHLOROD I FLUOROMETHANE
HEXAFLUOROETHANE
TRIFLUOROMETHANE
CHLOROTRI FLUOROMETHANE
153.84
137.38
120.91
138.01
70.01
104.46
0.12
0.24
0.21
79.54
3.98
15.91
100.00
94
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CAJ
43811
43823
TOTAL
Fluorocarbons/Chlorofluorocarbons - Fugitive Emissions - General
1042
E
Not reported
27
Information from one emission source.
30112780
! Number Name SpecJIW Spec_WT Peak
75-69-4 TRICHLOROFLUOROHETHANE 137.38 35.00
75-71-8 DICHLORODIFLUOROMETHANE 120.91 65.00
100.00
95
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Acrylic Acid - Quench Absorber
1043
E
Uncontrolled
28
Information based on design material balance from
one emission source.
SCC Assignments:
Saroad
CAS Number
Name
Spec_MU SpecJJT Peak
43204
43205
43404
43407
43438
43503
43505
43551
TOTAL
===========
74-98-6
115-07-1
64-19-7
79-10-7
140-88-5
75-07-0
107-02-8
67-64-1
================
PROPANE
PROPENE
ACETIC ACID
ACRYLIC ACID
ETHYL ACRYLATE
ACETALDEHYDE
ACROLEIM
ACETONE
======================
44.09
42.08
60.05
72.06
100.11
44.05
56.07
58.08
=======================:
63.12
14.67
1.17
15.09
1.01
0.08
3.77
1.09
100.00
===============
96
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organic Acids Production - Formic Acid
1044
D
Control Device Condenser
Reference(s) 25
Data Source Composite profile developed using data based on
engineering estimates from six emission sources
(weighted according to emission rates).
SCC Assignments: 30113299
Saroad
43403
43404
43552
CAS Number
64-18-6
64-19-7
78-93-3
Name
FORMIC ACID
ACETIC ACID
METHYL ETHYL KETONE
Spec_MV
46.03
60.05
72.10
Spec_WT
6.67
33.33
60.00
Peak
TOTAL
100.00
97
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organic Acids Production - Acetic Anhydride - Distillation Column Vent
1045
D
Control Device Uncontrolled
Reference(s) 33
Data Source Information based on typical vent analysis from one
emission source.
SCC Assignments: 30113303
Saroad
TOTAL
CAS Number
Name
Spec_MW SpecJJT Peak
43404
43551
43604
45201
64-19-7
67-64-1
108-24-7
71-43-2
ACETIC ACID
ACETONE
ACETIC ANHYDRIDE
BENZENE
60.05
58.08
102.09
78.11
58.00
34.00
6.00
2.00
100.00
98
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Esters Production - Acrytates - Ethyl AeryIate
1046
C
Control Device
Reference(s)
Data Source
SCC Assignments:
Uncontrolled
31
Composite profile developed from two profiles each
based on measurement (weighted according to emissions
rate).
Saroad
43201
43302
43351
43438
99933
CAS Number
74-82-8
64-17-5
60-29-7
140-88-5
Name
METHANE
ETHYL ALCOHOL
ETHYL ETHER
ETHYL ACRYLATE
DENATURANT
Spec_MW
16.04
46.07
74.12
100.11
32.04
Spec_WT
4.88
7.88
37.88
20.19
29.16
Peak
TOTAL
99.99
99
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Esters Production - Butyl Acrylate
1047
E
Uncontrolled
28
Information based on material balance from one emission
source.
SCC Assignments: 30113710
Saroad
43305
43438
43440
CAS Number
71-36-3
140-88-5
141-32-2
Name
N-BUTYL ALCOHOL
ETHYL ACRYLATE
BUTYL ACRYLATE
Spec_HU
74.12
100.11
128.17
Spec_WT
70.38
14.81
14.81
Peak
TOTAL
ssssssss==============2
100.00
100
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Cumene Production - Cumene Distillation System Vent
1048
C
Control Device Uncontrolled
Reference(s) 8
Data Source Composite profile developed using data based on gas
analyses from two emission sources (weighted according
to emissions rate).
SCC Assignments: 30115606
Saroad
CAS Number
Name
Spec_MW Spec_UT Peak
43202
43204
43214
43245
45201
45203
45210
TOTAL
74-84-0
74-98-6
75-28-5
592-41-6
71-43-2
100-41-4
98-82-8
ETHANE
PROPANE
I SO- BUTANE
1-HEXENE
BENZENE
ETHYLBENZENE
CUMENE (ISOPROPYL BENZENE)
30.07
44.09
58.12
84.16
78.11
106.16
120.20
1.19
53.34
0.89
5.47
38.47
0.61
0.03
100.00
101
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Cyclohexane - General
1049
D
Not reported
3
Information based on vent stream analysis from one
emission source.
SCC Assignments: 30115701
Saroad
CAS Number
Name
Spec_MU 8pec_UT Peak
43201
43202
43204
43212
43214
43220
43221
74-82-8
74-84-0
74-98-6
106-97-8
75-28-5
109-66-0
78-78-4
METHANE
ETHANE
PROPANE
N- BUTANE
ISO-BUTANE
N-PENTANE
ISO PENTANE
16.04
30.07
44.09
58.12
58.12
72.15
72.15
16.07
28.93
32.32
14.29
2.32
3.04
3.04
TOTAL
100.01
102
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Cyclohexanone/Cyclohexanol Phenol Hydrogenatioo Process - Distillation Vent
1050
E
Condenser
12
Information based on engineering calculations from one
emission source.
SCC Assignments: 30115822
Saroad
43248
43317
43561
45201
45501
CAS Number
110-82-7
108-93-0
108-94-1
71-43-2
100-52-7
Name
CYCLOHEXANE
CYCLOHEXANOL
CYCLOHEXANONE
BENZENE
BENZALDEHYDE
SpecJM
84.16
100.16
98.15
78.11
106.13
Spec_WT
49.86
10.26
10.26
25.07
4.56
Peak
TOTAL
100.01
103
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Vinyl Acetate -
1051
C
Inert Gas Purge Vent
Control Device Condenser/uncontrolled
Reference(s) 22, 23
Data Source Composite profile developed from data based on vent
analyses from two emission sources (weighted according
to emission rates).
SCC Assignments: 30116702
Saroad
TOTAL
CAS Number
Name
Spec.MU SpecJUT Peak
43203
43404
43453
99999
74-85-1
64-19-7
108-05-4
ETHYLENE
ACETIC ACID
VINYL ACETATE
UNIDENTIFIED
28.05
60.05
86.09
86.00
74.97
4.18
16.68
4.17
100.00
104
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Vinyl Acetate - C02 Purge Vent
1052
Control Device
Reference(s)
Data Source
Uncontrolled
22, 23
Information based on vent analyses from two emission
sources.
SCC Assignments: 30116703
Saroad
43203
TOTAL
CAS Number
74-85-1
Name
ETHYLENE
SpecJtU
28.05
Spec_WT Peak
100.00
mn nn
105
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Vinyl Acetate - Inhibitor Mix Tank Discharge
1053
Control Device Not reported
Reference(s) 23
Data Source Information from one emission source based on
engineering calculations.
SCC Assignments: 30116704
Saroad
43453
TOTAL
CAS Number
108-05-4
Name
VINYL ACETATE
Spec_MW Spec_UT Peak
86.09 100.00
100.00
106
-------
VOC Profile Speciation rfeport
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CAS
43453 1
43503
Vinyl Acetate - Refining Column Vent
1054
E
Uncontrolled
24
Not reported
30116799
Number Name Spec_MW Spec_UT Peak
08-05-4 VINYL ACETATE 86.09 46.00
75-07-0 ACETALDEHYDE 44.05 54 00
tkf
TOTAL
100.00
107
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Referer>ce(s)
Data Source
Ethylene Oxide - Oxygen Oxidation Process Reactor - C02 Purge Vent
1056
Uncontrolled
35, 40
Composite profile developed using data reported from
three plants.
SCC Assignments: 30117410
Saroad
43203
TOTAL
CAS Ninber
74-85-1
Name
ETHYLENE
Spec_MU Spec_UT Peak
28.05 '100.00
100.00
108
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Control Device
Referenced )
Data Source
SCC Assignments:
Saroad CAS
43201
43202
43203
Ethylene Oxide - Oxygen Oxidation Process Reactor - Argon Purge Vent
1057
D
Uncontrolled
35, 40
Composite profile developed from information from three
emission sources (weighted according to emission rate).
30117411
Number Name Spec_HU Spec_UT Peak
74-82-8 METHANE 16.04 52.30
74-84-0 ETHANE 30.07 0.28
74-85-1 ETHYLENE 28.05 47.42
TOTAL
100.00
109
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Ethylene Oxide - Stripper Purge Vent
1058
Control Device
Reference(s)
Data Source
SCC Assignments
Not reported
35
Information based on one emission source.
30117421
Saroad
CAS Number
Name
SpecJW Spec_WT Peak
43201
43203
TOTAL
74-82-8
74-85-1
METHANE
ETHYLENE
16.04
28.05
24.38
75.62
100.00
110
-------
VOC Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Methyl Methacrylate (MMA) - Hydrolysis Reactor, HHA and Light Ends Distillation Unit
1059
D
Uncontrolled
30
Information based on measurements from one emission
source.
SCC Assignments: 30119010, 30119012
Saroad
TOTAL
CAS Number
Name
SpecJW Spec_UT Peak
43201
43301
43350
43430
43441
43551
74-82-8
67-56-1
115-10-6
107-31-3
80-62-6
67-64-1
METHANE
METHYL ALCOHOL
DIMETHYLETHER
METHYL FORMATE
METHYL METHACRYLATE
ACETONE
16.04
32.04
46.07
60.05
100.13
58.08
1.79
4.55
88.88
1.67
0.72
2.39
100.00
111
-------
VOC Profile Speciation Report
Profile Name
Profile Hunter
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Methyl Methacrylate (MMA) - Acid Distillation and HMA Purification
1060
E
Condenser
30
Information
based on one emission source.
30119013, 30119014
Saroad CAS Number
43301 67-56-1
43350 115-10-6
43441 80-62-6
Name Spec_HW Spec_UT Peak
METHYL ALCOHOL 32.04 59.21
DIHETHYLETHER 46.07 13.16
METHYL METHACRYLATE 100.13 27.63
TOTAL
100.00
112
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Nitrobenzene - Reactor and Separator Vent - Washer and Neutralizer Vent
1061
E
Control Device Not reported
Reference(s) 14
Data Source Information based on design calculations from one
emission source.
SCC Assignments: 30119502, 30119504
Saroad
CAS Number
Name
SpecJtU Spec_WT Peak
45201
45702
71-43-2
98-95-3
BENZENE
NITROBENZENE
78.11
123.11
99.71
0.29
TOTAL
100.00
113
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Benzene
1062
D
Control Device
Reference(s)
Data Source
Absorber
2. 18, 43
Information based on engineering calculations from
four emission sources representing four SCC's.
SCC Assignments: 30110002, 30119505, 30121104, 30121123
Saroad
45201
CAS Number
71-43-2
Name
BENZENE
SpecJtU Spec_UT Peak
78.11 100.00
100.00
TOTAL
3S3S==S======S2=SS===============::s=============S3==========
114
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Olefins Production - Ethylene - Compressor Lube Oil Vent
1064
C
Control Device Not reported
Reference(s) 44
Data Source Composite profiles developed using data from five
emission sources determined by helium tracer sampling
and mass spectrometer analysis (weighted according to
emission rates).
SCC Assignments: 30119745
Saroad
43201
43202
43204
43212
43220
43301
45201
45202
CAS Number
74-82-8
74-84-0
74-98-6
106-97-8
109-66-0
67-56-1
71-43-2
108-88-3
Name
METHANE
ETHANE
PROPANE
N- BUTANE
N-PENTANE
METHYL ALCOHOL
BENZENE
TOLUENE
Spec_MW
16.04
30.07
44.09
58.12
72.15
32.04
78.11
92.13
Spec UT Peak
12.46
37.75
23.86
15.01
8.07
0.27
2.07
0.51
TOTAL
100.00
115
-------
VCX: Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Propylene Oxide - Chlorohydronation Process - General
1065
D
Scrubber
38
Information based on emissions data from two process
units. Data for the last three species derived from
dividing 16.50 by 3.
SCC Assignments: 30120502
Saroad
CAS Number
Name
Spec_HU Spec_WT Peak
43201
43202
43204
43205
43838
99999
TOTAL
74-82-8
74-84-0
74-98-6
115-07-1
26638-19-7
METHANE
ETHANE
PROPANE
PROPENE
PROPYLENE D I CHLORIDE
UNIDENTIFIED
16.04
30.07
44.09
42.08
112.99
86.00
0.51
5.02
77.97
5.50
5.50
5.50
100.00
116
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Styrene - General
1066
D
Control Device
Reference(s)
Data Source
Not reported
46,47
Composite profile developed using data based on typical
composition and design information from two emission
sources.
SCC Assignments: 30120601
Saroad
CAS Number
Name
Spec_MU Spec_WT Peak
43201
43202
43203
45201
45202
45203
45220
74-82-8
74-84-0
74-85-1
71-43-2
108-88-3
100-41-4
100-42-5
METHANE
ETHANE
ETHYLENE
BENZENE
TOLUENE
ETHYLBENZENE
STYRENE
16.04
30.07
28.05
78.11
92.13
106.16
104.14
21.73
6.53
24.39
23.28
9.21
9.94
4.91
TOTAL
99.99
117
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Styrene - Benzene Recycle
1067
D
Control Device
Reference(s)
Data Source
Condenser
47
Information from one emission source based on vent
analysis.
SCC Assignments: 30120602
Saroad
CAS Number
Name
Spec_HW Spec_UT Peak
43201
43202
43204
43212
43220
43224
45201
TOTAL
74-82-8
74-84-0
74-98-6
106-97-8
109-66-0
. 109-67-1
71-43-2
METHANE
ETHANE
PROPANE
N- BUTANE
N-PENTANE
1-PENTENE
BENZENE
16.04
30.07
44.09
58.12
72.15
70.13
78.11
34.72
6.10
0.75
21.64
1.22
1.19
34.38
100.00
118
-------
VOC Profile Spec i at ion Report
Profile Name
Profile Number
Data Quality
Styrene - Styrene Purification
1068
E
Control Device
Reference(s)
Data Source
Condenser
46
Information from one emission source based on
engineering calculations.
SCC Assignments: 30120603
Saroad
TOTAL
CAS Number
Name
Spec_MW Spec_WT Peak
45201
45202
45203
45220
71-43-2
108-88-3
100-41-4
100-42-5
BENZENE
TOLUENE
ETHYLBENZENE
STYRENE
78.11
92.13
106.16
104.14
41.46
19.51
19.51
19.51
99.99
119
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Alcohols Production - Methanol - Purge Gas Vent
1070
C
Control Device Uncontrolled
Reference(s) 17
Data Source Composite profile developed using data based on mass
spectrometer analysis from two emission sources
(weighted according to emission rates).
SCC Assignments: 30125002
Saroad
CAS Number
Name
Spec_MW
-------
VOC Profile Special Jon Report
Profile Name
Profile Number
Data Quality
Alcohols Production - Hethanol - Distillation Vent
1071
D
Control Device
Reference(s)
Data Source
Condenser
17
Information from one emission source based on mass
spectrometer analysis.
SCC Assignments: 30125003
Saroad
CAS Number
Name
Spec_MW Spec_WT Peak
43301
43350
TOTAL
67-56-1
115-10-6
METHYL ALCOHOL
DIHETHYLETHER
32.04
46.07
1.73
98.27
100.00
121
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Chlorobenzene - Tail Gas Scrubber
1072
D
Control Device Scrubber
Reference(s) 4. 6, 7
Data Source Composite profile developed using data from three
emission sources (weighted according to emission
rates); one set of data is based on analysis of stack
samples and the other two on engineering calculations.
SCC Assignments: 30130101
Saroad
CAS Number
Name
Spec_MW SpecJJT Peak
45201
45801
45808
TOTAL
ssssssssss:
71-43-2
108-90-7
2531-22-6
BENZENE
CHLOROBENZENE
DICHLOROBENZENES
78.11
112.56
147.01
56.95
37.19
5.86
100.00
122
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Chlorobenzene - Benzene Drying Distillation
1073
D
Control Device
Reference(s)
Data Source
Condenser
A, 7
Composite profile developed using data based on
engineering caluclations from two emission sources
(weighted according to emission rates).
SCC Assignments: 30130102
Saroad
45201
45801
CAS Number
71-43-2
108-90-7
Name
BENZENE
CHLOROBENZENE
Spec_HU
78.11
112.56
Spec_WT
95.04
4.96
Peak
TOTAL
100.00
123
-------
VOC Profile Spec)ation Report
Profile Name
Profile Number
Data Quality
MonochIorobenzene
1074
D
Control Device Condenser/not reported
Reference(s) 5, 7, 50
Data Source Information from two emission sources representing SCC
301-301-Ob and measurement data from one emission
source representing SCC 490-003-02.
SCC Assignments: 30130105, 49000302
Saroad
45801
TOTAL
ss s=sssss
CAS Number
108-90-7
Name
CHLOROBENZEHE
Spec_MU Spec_WT
112.56 100.00
100.00
Peak
124
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Chlorobenzene - Vacuum System Vent
1075
D
Control Device
Reference(s)
Data Source
Steam jet
4
Composite profile developed using data from three
emission sources {weighted according to emissions
rate). Two sets of data are based on measurement and
one on engineering calculations.
SCC Assignments: 30130106
Saroad
TOTAL
CAS Number
Name
Spec_HW Spec_WT Peak
45201
45801
45805
45806
45807
71-43-2
108-90-7
95-50-1
541-73-1
106-46-7
BENZENE
CHLOROBENZENE
0-D I CHLOROBENZENE
H-D I CHLOROBENZENE
P-D I CHLOROBENZENE
78.11
112.56
147.01
147.01
147.01
19.62
56.83
4.96
0.63
17.96
100.00
125
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Chlorobenzene - Dichlorobenzene Crystallization
1076
Control Device
Reference(s)
Data Source
Carbon bed
7
Information from one emission source based on
engineering estimate.
SCC Assignments: 30130107
Saroad
45807
TOTAL
CAS Number
106-46-7
Name
P-DICHLOROBENZENE
Spec.HW Spec_WT Peak
147.01 100.00
100.00
126
-------
Profile Spec i at ion Report
Profile Name
Profile Number
Data Quality
Chlorobenzene - Dichlorobenzene Crystal Handling / Loading
1077
E
Control Device
Reference(s)
Data Source
Uncontrolled
4
Information based on engineering calculations for one
emission source.
SCC Assignments: 30130108
Saroad
TOTAL
CAS Number
Name
Spec_HW Spec_WT Peak
45201
45801
45805
45807
71-43-2
108-90-7
95-50-1
106-46-7
BENZENE
CHLOROBENZENE
0-D1 CHLOROBENZENE
P-D I CHLOROBENZENE
78.11
112.56
147.01
147.01
0.11
0.13
5.31
94.45
100.00
127
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CA!
43804
43811
43823
TOTAL
sssssr =========
Fluorocarbon Manufacturing - CF 12/11
1090
D
Uncontrolled
27
Information from one plant based on engineering
calculations on two emission sources.
: 30112720
5 Number Name Spec_MU
56-23-5 CARBON TETRACHLORIDE 153.84
75-69-4 TRICHLOROFLUOROMETHANE 137.38
75-71-8 DICHLOROOIFLUOROMETHANE 120.91
Spec_WT Peak
19.90
40.76
39.34
100.00
128
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Fluorocarbon Manufacturing - CF 23/22
1093
D
Control Device
Reference(s)
Data Source
Condenser
42
Information from one plant based on engineering
calculations on two emission sources.
SCC Assignments: 30112730
Saroad
TOTAL
CAS Number
Name
Spec_MU Spec_UT Peak
43803
43840
43844
67-66-3
75-45-6
75-46-7
CHLOROFORM
CHLORODI FLUOROMETHANE
TRIFLUOROMETHANE
119.39
86.47
70.01
2.73
33.34
63.93
100.00
129
-------
VOC Profile Speciatfon Report
Profile Name
Profile Number
Data Quality
ACETYLENE
1120
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
30114004, 30114005
Saroad
43206
TOTAL
CAS Number
74-86-2
Name
ACETYLENE
Spec_HU Spec_WT Peak
26.04 100.00
100.00
130
-------
3.10 FOOD AND AGRICULTURE
This category includes farming operations and meat and crop processing.
Processes involved in the production of food and agricultural products include
harvesting, refinement, preservation, storage and handling, and packaging.
Refinement processes can include cleaning, drying, grinding, mixing, and
fermentation. Particulate emissions are the dominant emission type from this
source category.
131
-------
132
-------
VOC Profile Speeiation Report
Profile Name
Profile Number
Data Quality
Fermentation Processes
1188
C
Control Device
Reference(s)
Data Source
Not reported
88
Emissions data from four fermentation units in a
whiskey distillery analyzed by GC.
SCC Assignments: 30201002, 30201003, 30201004
Saroad
TOTAL
CAS Number
Name
Spec_HU SpecJUT Peak
43302
43306
43330
43433
64-17-5
78-83-1
123-51-3
141-78-6
ETHYL ALCOHOL
ISOBUTYL ALCOHOL
ISOAHYL ALCOHOL
ETHYL ACETATE
46.07
74.12
88.15
88.10
99.56
0.03
0.09
0.32
100.00
133
-------
134
-------
3.11 PRIMARY AND SECONDARY METAL PRODUCTION
Primary metal production involves many processes which basically produce
metals in elemental form from unprocessed and impure ore. Secondary metal
operations involve the cleaning, melting, refining, and pouring of metals
recovered from scrap. Each process in primary and secondary metal production
is a potential source of emissions.
135
-------
136
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
By Product Coke Oven Stack Gas
0011
Control Device
Reference(s)
Data Source
Uncontrolled
58, 59
Composite profile based on test samples taken from
two different coke oven stacks and analyzed by GC/HS.
SCC Assignments: 30300302, 30300303, 30300304, 30300305, 30300306
Saroad
CAS Number
Name
Spec_HW Spec_WT Peak
43201
43202
43203
43204
43205
43206
43213
43218
45201
45202
TOTAL
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
106-98-9
106-99-0
71-43-2
108-88-3
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
BUTENE
1,3-BUTADIENE
BENZENE
TOLUENE
16.04
30.07
28.05
44.09
42.08
26.04
56.10
54.09
78.11
92.13
45.30
8.00
27.70
0.50
1.90
1.20
0.10
0.50
14.10
0.70
100.00
137
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Blast Furnace Ore Charging and Agglomerate Charging
0012
C
Control Device Uncontrolled
Reference(s) 59
Data Source Information based on one grab sample from blast furnace
exhaust.
SCC Assignments: 30300801, 30300802
Saroad
43201
43822
CAS Number
74-82-8
Name
METHANE
TRIMETHYLFLUOROSILANE
Spec_MU
16.04
92.00
Spec_WT
15.80
84.20
Peak
TOTAL
100.00
138
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Iron Sintering
0013
C
Control Device
Reference(s)
Data Source
Uncontrolled
59
Information based on one grab sample from sintering
plant.
SCC Assignments: 30300813
Saroad
CAS Number
Name
SpecJW Spec_WT Peak
43201
43202
43203
43205
43206
TOTAL
==-===:=====
74-82-8
74-84-0
74-85-1
115-07-1
74-86-2
METHANE
ETHANE
ETHYLENE
PROPENE
ACETYLENE
16.04
30.07
28.05
42.08
26.04
73.30
3.00
5.90
3.00
14.80
100.00
139
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Open Hearth
0014
C
Furnace With Oxygen Lance
Electrostatic Precipitator
59
Information based on two samples at
and outlet.
30300901
Saroad CAS Number
43231 110-54-3
43232 142-82-5
43822
45201 71-43-2
45202 108-88-3
Name
HEXANE
HEPTANE
TRIMETHYLFLUOROSILANE
BENZENE
TOLUENE
precipitator inlet
Spec_HU
86.17
100.20
92.00
78.11
92.13
5pec_WT Peak
7.00
35.80
40.00
13.60
3.60
TOTAL
100.00
140
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Basic Oxygen Furnace
0016
Control Device
Reference(s)
Data Source
SCC Assignments
Electrostatic Precipitator
59
Information based on one sample at precipitator outlet.
30300913, 303009U
Saroad
43201
43204
43822
CAS 'Number
74-82-8
74-98-6
Name
METHANE
PROPANE
TRIMETHYLFIUOROSILANE
Spec_MW
16.04
44.09
92.00
Spec_WT
11.10
39.90
49.00
Peak
TOTAL
100.00
141
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Secondary Aluminun - Pouring and Casting
1036
D
Not reported
57
Information from a laboratory study where data were
collected using liquid and gas chromatography methods.
SCC Assignments: 30400114
Saroad
CAS Number
Name
Spec_MW Spec_WT Peak
45701
45730
46111
46112
46114
TOTAL
ssssssssssss
62-53-3
101-68-8
101-77-9
103-71-9
100-61-8
ANILINE
METHYLENE
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Secondary Metal Production - Gray Iron Foundries - Pouring/Casting
1089
B
Control Device
Reference(s)
Data Source
Not reported
49
Exhaust gases from twelve binder systems and sand
formulations were sampled by enclosed hood during the
pouring of gray iron. Air grab samples were analyzed
by GC; reagent bubblers were analyzed by ion specific
electrodes, titration, GC, or spectrophotometric
methods; sorbent tube samples were analyzed by GC.
SCC Assignments: 30400320
Saroad
TOTAL
CAS Number
Name
Spec_NW Spec_WT Peak
43502
43505
43520
45201
45202
45204
45205
45300
45604
45740
46701
50-00-0
107-02-8
71-43-2
108-88-3
95-47-6
108-38-3
108-95-2
98-00-0
91-12-3
FORMALDEHYDE
ACROLEIN
TOTAL C2-C5 ALDEHYDES
BENZENE
TOLUENE
0-XYLENE
M-XYLENE
PHENOL
FURFURYL ALCOHOL
TOTAL AROMATIC AMINES
NAPTHALENE
30.03
56.07
72.12
78.11
92.13
106.16
106.16
94.11
98.10
93.13
128.17
0.70
0.33
24.20
34.70
14.10
5.50
6.50
6.40
0.07
7.42
0.08
100.00
143
-------
VOC Profile Speciation Report
Profile Name Primary Aluminum Production
Profile Number 1202
Data Quality D
Control Device Baghouse
Reference(s) 95
Data Source Average profile based on EPA Method 625 from a
Soderberg primary aluminum plant. The unidentified
species represents those pollutants detected below the
detection limit.
SCC Assignments: 30300102,
Saroad
43211
43212
43213
43214
43215
43216
43217
43220
43221
43222
43223
43224
43226
43227
43228
43229
43230
43231
43232
43234
43235
43238
43242
43243
43245
43247
43250
43252
43261
43262
43263
43270
43272
43274
43276
43277
43278
43279
43280
CAS Number
760-20-3
106-97-8
106-98-9
75-28-5
115-11-7
624-64-6
590-18-1
109-66-0
78-78-4
463-82-1
563-45-1
109-67-1
646-04-8
627-20-3
513-35-9
107-83-5
96-14-0
110-54-3
142-82-5
563-78-0
111-84-2
124-18-5
287-92-3
78-79-5
592-41-6
108-08-7
540-84-1
565-75-3
108-87-2
96-37-7
591-76-4
922-61-2
693-89-0
565-59-3
79-29-8
592-13-2
760-21-4
30300103
Name
3-HETHYL-1-PENTENE
N- BUTANE
BUTEHE
ISO-BUTANE
ISOBUTYLENE
T-2-BUTENE
CIS-2-BUTENE
N-PENTANE
ISO PENTANE
2,2 DIHETHYLPROPANE
3-METHYL-1-BUTENE
1-PENTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-HETHYL-2-BUTENE
2-HETHYLPENTANE
3-HETHYL PENTANE
HEXANE
HEPTANE
2,3 DIHETHYL-1-BUTENE
NONANE
N-DECANE
CYCLOPENTANE
ISOPRENE
1-HEXENE
2,4-DIMETHYLPENTANE
2,2,4-TRIMETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
HETHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
2-HETHYL HEXANE
3-HETHYL-T-2-PENTENE
HETHYLCYCLOPENTENE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
2,4-DIMETHYLHEXANE
2,5-DIMETHYLHEXANE
2-ETHYL-1-BUTENE
2,3,3 TRIMETHYLPENTANE
Spec_MU
84.16
58.12
56.10
58.12
56.10
56.11
56.11
72.15
72.15
72.17
70.13
70.13
70.13
70.13
70.13
86.17
86.17
86.17
100.20
84.16
128.25
142.28
70.14
68.12
84.16
100.20
114.22
114.22
98.21
84.16
100.20
84.16
82.14
100.20
86.17
114.22
114.22
84.16
114.22
Spec_WT
0.00
16.33
1.35
7.23
0.00
1.60
1.04
3.33
7.92
0.00
0.19
0.32
0.68
0.34
0.81
1.13
0.58
0.45
0.18
0.00
0.02
0.02
0.24
0.01
0.12
0.14
0.19
0.03
0.07
0.43
0.00
0.00
0.27
0.00
0.31
0.06
0.00
0.00
0.05
Peak
(5 )
(1 )
(1 )
(2 )
(3 )
(2 )
(4 )
(6 )
(8 )
(6 )
(5 }
(7 )
<9 )
(10)
(9 )
(10)
(10)
144
-------
VIX Profile Speeiation Report - continued (profile 1202)
Saroad
43281
43282
43283
43284
43285
43286
43289
43290
43291
43292
43295
43296
43297
43298
43299
45110
45201
45202
45203
45204
45205
45206
45207
45208
45209
45217
45225
45300
46701
46705
46706
46707
46708
46709
46710
46713
46715
46716
46719
90002
90004
90005
90006
98033
98044
99911
99912
99916
99917
99918
99999
CAS Number
107-00-6
503-17-3
625-27-4
75-83-2
142-29-0
589-34-4
592-27-8
589-53-7
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
106-42-3
108-67-8
95-63-6
103-65-1
135-01-3
526-73-8
108-95-2
91-12-3
208-96-8
83-32-9
86-73-7
85-01-8
120-12-7
206-44-0
129-00-0
218-01-9
56-55-3
50-32-8
496-11-7
Name
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-METHYL-2-PENTENE
2-HEXENE
DIHETHYLHEXENE
C6 OLE FINS
2.3 DIHETHYLHEXANE
2,2-DIMETHYLBUTANE
CYCLOPENTENE
3-HETHYLHEXANE
2-METHYLHEPTANE
4-HETHYLHEPTANE
3-METHYLHEPTANE
1-METHYLCYCLOHEXENE
C10 AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
1 ,3,5-TRIMETHYLBENZENE
1,2,4-TRIMETHYLBENZENE
N-PROPYLBENZENE
1,2 D I ETHYLBENZENE
1,2,3-TRIMETHYLBENZENE
PHENOL
NAPTHALENE
ACENAPHTHYLENE
ACENAPHTHENE
FLUORENE
PHENANTHRENE
ANTHRACENE
FLUORANTHENE
PYRENE
CHRYSENE
BENZO (a) ANTHRACENE
BENZO (a) PYRENE
2,3.5-TRIHETHYLHEXANE
3,5 DIHETHYLHEPTANE
2,5 DIHETHYLHEPTANE
2,3 DIMETHYLHEPTANE
2,2,5-TRIMETHYLHEXANE
INDANE
3,4 DIHETHYLOCTANE
1 -METHYL-3-ETHYLBENZENE
1-METHYL-3N-PROPYLBENZENE
1 -METHYL-3- ISOPROPYLBENZENE
2-HETHYLDECANE
UNIDENTIFIED
Specjtw
54.09
54.09
84.16
84.16
84.16
112.20
84.16
114.22
86.17
68.11
100.20
114.23
114.23
114.23
96.17
134.22
78.11
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.19
134.22
120.19
94^11
128.17
152.20
154.21
166.22
178.23
178.23
202.26
202.26
228.29
228.30
252.32
128.25
128.26
128.26
128.26
128.26
118.18
142.29
120.19
134.22
134.22
156.32
86.00
Spec_WT Peak
0.00
0.00
0.00
0.18
0.07
0.01
0.09
0.00
0.21
0.10
0.19
0.02
0.03
0.02
0.00
0.06
0.50
0.52
0.14
0.08
0.00
0.15
0.11
0.08
0.01
0.01
0.03
3.35
5.75
10.11
0.61
3.50
7.31
7.51
3.85
2.80
O.K
0.16
0.12
0.01
0.02
0.00
0.00
0.08
0.01
0.04
0.06
0.01
0.04
0.03
6.57
TOTAL
100.13
145
-------
146
-------
3.12 ASPHALT PRODUCTS
This category includes manufacture of asphalt roofing felts and shingles
that involve saturating fiber media with hot asphalt by means of dipping
and/or spraying. Preparation of the asphalt saturant (blowing) consists of
oxidizing the asphalt by bubbling air through the liquid asphalt. Potential
sources of emissions include spraying and dipping, air blowing, hot asphalt
storage, and tar kettles. Hot-mix asphalt paving operations are also included
in this category. A typical hot-mix paving plant consists of an oil- or gas-
fired rotary dryer, a screening and classifying system, a weighing system for
asphalt cement and aggregate, a mixer, and the necessary material handling
equipment. Potential sources of emissions include the rotary dryer, asphalt-
aggregate mixer, truck loading area, and asphalt oil storage.
147
-------
148
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Asphalt Roofing - Spraying
0023
D
Control Device
Reference(s)
Data Source
Uncontrolled
59
Information based on composite survey data and engi-
neering evaluation of literature data.
SCC Assignments: 30500112
Saroad
TOTAL
CAS Number
Name
Spec_MW Spec_UT Peak
43105
43106
43107
43202
43203
43204
43212
43214
43220
43231
43232
74-84-0
74-85-1
74-98-6
106-97-8
75-28-5
109-66-0
110-54-3
142-82-5
ISOHERS OF HEXANE
ISOHERS OF HEPTANE
ISOMERS OF OCTANE
ETHANE
ETHYLENE
PROPANE
N-BUTANE
ISO-BUTANE
N-PENTANE
HEXANE
HEPTANE
86.17
100.20
114.23
30.07
28.05
44.09
58.12
58.12
72.15
86.17
100.20
12.00
11.00
1.00
1.00
2.00
13.00
18.00
8.00
18.00
2.00
14.00
100.00
149
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Asphalt Roofing Tar Kettle
0024
C
Control Device Uncontrolled
Reference(s) 59
Data Source Information based on one sample taken with gas bottle
and charcoal tubes.
SCC Assignments: 30500104
Saroad
TOTAL
CAS Number
Name
Spec_MW Spec_WT Peak
43105
43107
43115
43116
43117
43121
43122
43201
43202
43203
43204
43205
43212
43213
43214
43220
43224
43231
43232
43233
43242
45201
45202
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
106-97-8
106-98-9
75-28-5
109-66-0
109-67-1
110-54-3
142-82-5
111-65-9
287-92-3
71-43-2
108-88-3
ISOMERS OF HEXANE
ISOMERS OF OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
ISOMERS OF PENTENE
ISOMERS OF PENTANE
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
N-BUTANE
BUTENE
I SO- BUTANE
N-PENTANE
1 -PENTENE
HEXANE
HEPTANE
OCTANE ,
CYCLOPENTANE
BENZENE
TOLUENE
86.17
114.23
98.19
112.23
126.26
70.13
72.15
16.04
30.07
28.05
44.09
42.08
58.12
56.10
58.12
72.15
70.13
86.17
100.20
114.23
70.14
78.11
92.13
3.40
7.40
2.90
0.40
1.50
0.50
1.10
21.30
5.40
0.30
10.20
2.00
11.60
7.00
0.70
6.30
3.20
4.90
2.00
2.70
2.50
0.80
1.90
100.00
150
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Asphaltic Concrete - Natural Gas Rotary Dryer
0025
D
Control Device
Reference(s)
Data Source
SCC Assignments
Uncontrolled
60
Information based on test data.
30500201
Saroad
TOTAL
CAS Number
Name
Spec_MW Spec_UT Peak
43105
43122
43201
43204
43212
43220
43248
43502
45201
45202
74-82-8
74-98-6
106-97-8
109-66-0
110-82-7
50-00-0
71-43-2
108-88-3
ISONERS OF HEXANE
ISOHERS OF PENTANE
METHANE
PROPANE
N-BUTANE
N-PENTANE
CYCLOHEXANE
FORMALDEHYDE
BENZENE
TOLUENE
86.17
72.15
16.04
44.09
58.12
72.15
84.16
30.03
78.11
92.13
1.00
9.00
56.00
4.00
9.00
6.00
1.00
8.00
4.00
2.00
100.00
151
-------
VOC Profile Speciation Report
Asphaltic Concrete - In Place Road Ashpalt
Profile Name
Profile Number
Data Quality
0026
B
Control Device
Reference(s)
Data Source
SCC Assignments
Uncontrolled
59
Information based on GC/MS laboratory test samples.
30500202
Saroad
CAS Number
Name
Spec_MW Spec_UT Peak
13105
43115
43122
43201
43202
43203
43204
43205
43212
43213
43214
43220
43231
45201
TOTAL
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
106-97-8
106-98-9
75-28-5
109-66-0
110-54-3
71-43-2
ISOHERS OF HEXANE
C-7 CYCLOPARAFFINS
ISOMERS OF PENTANE
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
N- BUTANE
BUTENE
I SO- BUTANE
N-PENTANE
HEXANE
BENZENE
86.17
98.19
72.15
16.04
30.07
28.05
44.09
42.08
58.12
56.10
58.12
72.15
86.17
78.11
8.10
3.70
5.70
15.70
4.60
2.00
5.50
3.90
10.10
5.90
11.20
5.30
8.80
9.50
100.00
152
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Mineral Products - Asphaltic Concrete
1007
C
Control Device
Reference(s)
Data Source
Uncontrolled
1
A composite sample made up of equal amounts of two
samples each of slow-cure asphalt was prepared and
distilled to generate organic samples representative
of emissions during application. Distillates were
analyzed by GC and GC/HS.
SCC Assignments: 108, 30500203
Saroad
TOTAL
CAS Number
Name
Spec_MW Spec_WT Peak
43111
43113
43130
43131
43238
43241
43255
43467
45107
45703
46701
46702
46711
98063
98083
ISOHERS OF DODECANE
ISOHERS OF TETRADECANE
C5 SUBSTITUTED CYCLOHEXANE
C6 SUBSTITUTED CYCLOHEXANE
124-18-5 N-DECANE
1120-21-4 N-UNDECANE
112-40-3 N-DODECANE
C4 SUBSTITUTED CYCLOHEXANONE
25551-13-7 TRIHETHYLBENZENE
2,2 DICHLORONITROANILINE
91-12-3 NAPTHALENE
METHYL NAPHTHALENES
C2 ALKYL INDAN
N-PENTYLCYCLOHEXANE
TRIHETHYLDECENE
170.32
198.38
154.30
168.32
142.28
156.31
170.33
154.26
120.19
207.02
128.17
142.20
146.23
154.30
182.35
9.59
3.12
4.16
3.12
2.87
7.78
18.56
2.38
8.89
3.94
6.54
10.19
11.21
2.04
5.62
100.01
153
-------
154
-------
3.13 PETROLEUM INDUSTRY
The petroleum industry includes petroleum refining and natural gas
processing. Petroleum refining involves the production of several fuels,
oils, and feeds for the petrochemical industry from crude oil. Refining
processes include distillation, conversion, treatment, and storage and
handling processes. The most significant sources of emissions include
transfer and handling operations, vacuum distillation, catalytic cracking,
thermal cracking, boilers, and heaters. Natural gas processes include
condensate removal and "sweetening."
155
-------
156
-------
VOC Profile Spec1 ation Report
Profile Name
Profile Number
Data Quality
Refinery Fluid Catalytic Cracker
0029
C
Control Device
Reference(s)
Data Source
Uncontrolled
59
Information based on GC/HS analysis of sampling train
catch taken with stack extension.
SCC Assignments: 30600201
Saroad
43105
43201
43502
CAS Number
74-82-8
50-00-0
Name
ISOMERS OF HEXANE
METHANE
FORMALDEHYDE
Spec_MW
86.17
16.04
30.03
Spec_WT
13.00
36.00
51.00
Peak
TOTAL
100.00
157
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Refinery Fugitive Emissions - Covered Drainage / Separation Pits
0031
C
Control Device
Reference(s)
Data Source
Uncontrolled
59
Information based on five separate refinery API
separators and process drain hydrocarbons emissions
tests.
SCC Assignments: 30600503, 30600504
Saroad
CAS Number
Name
Spec_MW Spec_UT Peak
43105
43115
43116
43122
43201
43202
43204
43212
43214
43220
43231
45201
TOTAL
ssssssss==== *:
74-82-8
74-84-0
74-98-6
106-97-8
75-28-5
109-66-0
110-54-3
71-43-2
ISOHERS OF HEXANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
ISOHERS OF PENTANE
METHANE
ETHANE
PROPANE
N- BUTANE
ISO-BUTANE
N-PENTANE
HEXANE
BENZENE
86.17
98.19
112.23
72.15
16.04
30.07
44.09
58.12
58.12
72.15
86.17
78.11
12.20
16.90
5.20
10.10
2.90
1.70
5.90
14.30
4.50
12.00
11.90
2.40
100.00
158
-------
VOC Profile Specfat ion Report
Profile Name
Profile Number
Data Quality
Refinery Fugitive Emissions - Cooling Towers
0035
Control Device Uncontrolled
Reference(s) 49
Data Source Information based on xylene extraction and GC analysis
of water samples at inlet and outlet.
SCC Assignments: 30600701, 30600702
Saroad
43122
TOTAL
CAS Number
Name
ISOMERS OF PENTANE
Spec_MW Spec_UT Peak
72.15 100.00
100.00
159
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Refinery Fugitive Emissions - Compressor Seals - Refinery Gas
0039
0
Control Device
Reference(s)
Data Source
Uncontrolled
59
Information based on composite survey data, GC/HS
analysis of grab sample taken at leak.
SCC Assignments: 30600804
Saroad
CAS Number
Name
Spec_HU Spec_UT Peak
43105
43106
43122
43201
43202
43204
43205
43212
43213
43214
43220
43231
TOTAL
74-82-8
74-84-0
74-98-6
115-07-1
106-97-8
106-98-9
75-28-5
109-66-0
110-54-3
ISOMERS OF HEXANE
ISOHERS OF HEPTANE
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
PROPENE
N- BUTANE
BUTENE
I SO- BUTANE
N-PENTANE
HEXANE
86.17
100.20
72.15
16.04
30.07
44.09
42.08
58.12
56.10
58.12
72.15
86.17
1.00
0.10
8.60
13.30
5.60
16.00
8.80
23.20
1.20
10.00
7.60
4.60
100.00
160
-------
VOC Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Refinery Fugitive Emissions - Relief Valves - Liquified Petroleum Gas
0047
C
Control Device
Reference(s)
Data Source
Uncontrolled
60
Information based on composite survey data, engineering
evaluation of literature data.
SCC Assignments: 30600802
Saroad
TOTAL
CAS Number
Name
SpecJW Spec_WT Peak
43202
43204
43205
43214
74-84-0
74-98-6
115-07-1
75-28-5
ETHANE
PROPANE
PROPENE
ISO-BUTANE
30.07
44.09
42.08
58.12
4.10
90.40
5.10
0.40
100.00
161
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Flares - Natural
0051
D
Gas
Control Device
Referertce(s)
Data Source
Uncontrolled
60
Information based on composite survey data, engineering
evaluation of literature data
SCC Assignments: 30600903
Saroad
CAS Number
Name
Spec_HU SpecJJT Peak
43201
43302
43204
43502
TOTAL
74-82-8
74-84-0
74-98-6
50-00-0
METHANE
ETHANE
PROPANE
FORMALDEHYDE
16.04
30.07
44.09
30.03
20.00
30.00
30.00
20.00
100.00
162
-------
VOC Profile Speciation Report
Profile Name Pipe/Valve
Profile Number 0316
Data Quality C
Flanges
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering
SCC Assignments 30600801
Saroad CAS Number
43105
43106
43107
43108
43109
43115
43117
43122
43201 74-82-8
43202 74-84-0
43204 74-98-6
43205 115-07-1
43212 106-97-8
43214 75-28-5
43220 109-66-0
43231 110-54-3
43232 142-82-5
43233 111-65-9
43235 111-84-2
43238 124-18-5
43248 110-82-7
45102 1330-20-7
45201 71-43-2
45202 108-88-3
TOTAL
evaluation of test
Name
ISOMERS OF NEXANE
ISOMERS OF HEPTANE
ISOHERS OF OCTANE
ISOMERS OF NONANE
ISOHERS OF DECANE
C-7 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
PROPENE
N- BUTANE
I SO- BUTANE
N-PENTANE
HEXANE
HEPTANE
OCTANE
NONANE
N-DECANE
CYCLOHEXANE
ISOMERS OF XYLENE
BENZENE
TOLUENE
data.
Spec_MU
86.17
100.20
114.23
128.25
142.28
98.19
126.26
72.15
16.04
30.07
44.09
42.08
58.12
58.12
72.15
86.17
100.20
114.23
128.25
142.28
84.16
106.16
78.11
92.13
Spec_UT Peak
1.60
0.80
0.40
0.50
0.30
0.20
0.10
7.80
28.60
5.80
11.50
0.10
18.30
7.40
7.70
3.40
1.40
1.80
0.60
0.80
0.10
0.20
0.10
0.50
100.00
========s=============:======:s=======::========;============ -
163
-------
VOC Profile Speciation Report
Profile Name Pump Seals -
Profile Number 0321
Data Quality C
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering <
SCC Assignments 30600803
Saroad CAS Number
43105
43106
43107
43108
43109
43115
43116
43117
43122
43201 74-82-8
43202 74-84-0
43204 74-98-6
43212 106-97-8
43214 75-28-5
43220 109-66-0
43231 110-54-3
43232 142-82-5
43233 111-65-9
43235 111-84-2
43238 124-18-5
43248 110-82-7
45102 1330-20-7
45201 71-43-2
45202 108-88-3
TOTAL
Composite
; valuation of test data.
Name
ISOMERS OF HEXANE
ISOHERS OF HEPTANE
ISOHERS OF OCTANE
ISOHERS OF NONANE
ISOHERS OF DECANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
I SIXERS OF PENTANE
HETHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
N-PENTANE
HEXANE
HEPTANE
OCTANE
NONANE
N-DECANE
CYCLOHEXANE
ISOHERS OF XYLENE
BENZENE
TOLUENE
Spec_HW
86.17
100.20
114.23
128.25
142.28
98.19
112.23
126.26
72.15
16.04
30.07
44.09
58.12
58.12
72.15
86.17
100.20
114.23
128.25
142.28
84.16
106.16
78.11
92.13
Spec_WT Peak
5.50
4.10
2.80
3.10
1.90
1.10
0.10
0.80
6.60
3.30
1.20
3.70
8.10
0.80
11.10
11.00
8.50
12.00
3.90
5.10
0.50
1.30
0.50
3.00
100.00
164
-------
3.14 PLYWOOD PRODUCTION
Plywood is made by adhering layers of thin wood or veneers onto a wood core.
Processes involved in plywood production include: (1) sawing wood into
veneers, (2) drying, (3) application of adhesive, (4) hot press operation, and
(5) finishing. Finishing may include sanding, trimming, or treatment.
165
-------
166
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Pulp and Paper Industry - Plywood Veneer Dryer
1189
C
Control Device Not reported
Reference(s) 89
Data Source Emissions data from 4 plywood veneer dryers analyzed by
FID/GC and GC/HS.
SCC Assignments: 30700711, 30700712, 30700713, 30700714, 30700715
Saroad
TOTAL
CAS Number
Name
Spec_MU Spec_WT Peak
43204
43256
43257
90050
90051
90052
90053
74-98-6
80-56-8
127-91-3
5794-03-6
123-35-3
5989-27-5
PROPANE
A-PINENE
B-PINENE
CAMPHENE
HYRCENE
B-PHELLANDRENE
D-LIHONENE
44.09
136.24
136.24
136.24
136.24
136.24
136.24
0.03
52.71
34.44
1.27
1.87
1.69
7.99
100.00
167
-------
168
-------
3.15 SYNTHETIC RUBBER PRODUCTION
Emulsion type and solution type polymerization reactions are used to produce
styrene-butadiene copolymers. The emulsion products can be sold in either a
granular solid form, known as crumb, or in a liquid form, known as latex.
Copolymers of styrene and butadiene can be made with properties ranging from
those of a rubbery material to those of very resilient plastic. Uncontrolled
VOC emissions may pass to the atmosphere during the emulsion crumb process and
from blending/coagulation tanks and dryers.
169
-------
170
-------
VOC Profile Spcciation Report
Profile Name
Profile Number
Data Quality
Automotive Tires - Tuber Adhesive
0272
C
Control Device
Reference(s)
Data Source
Uncontrolled
59
Information based on composite survey data and GC/HS
analysis of grab sample.
SCC Assignments: 30800121
Saroad
TOTAL
CAS Number
Name
Spec_MU Spec_WT Peak
43106
43107
43115
43116
43231
43232
43233
43248
43262
45201
45202
110-54-3
142-82-5
111-65-9
110-82-7
96-37-7
71-43-2
108-88-3
I SOWERS OF HEPTANE
ISOHERS OF OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
HEXANE
HEPTANE
OCTANE
CYCLOHEXANE
METHYLCYCLOPENTANE
BENZENE
TOLUENE
100.20
114.23
98.19
112.23
86.17
100.20
114.23
84.16
84.16
78.11
92.13
4.70
0.80
43.20
6.00
5.80
1.90
0.40
16.30
17.70
2.80
0.40
100.00
171
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Automotive Tires - Tuber Adhesive White Sidewall
0273
Control Device Uncontrolled
ReferenceCs) 59
Data Source Information based on composite survey data and GC/HS
analysis of grab sample.
SCC Assignments: 30800101, 30800120
Saroad
CAS Number
Name
Spec_MU SpecJJT Peak
43105
43106
43231
43242
43248
43262
45201
TOTAL
110-54-3
287-93-3
110-82-7
96-37-7
71-43-2
ISOMERS OF HEXANE
ISOHERS OF HEPTANE
HEXANE
CYCLOPENTANE
CYCLOHEXANE
HETHYLCYCLOPENTANE
BENZENE
86.17
100.20
86.17
70.14
84.16
84.16
78.11
24.20
0.20
33.60
0.20
0.40
33.70
7.70
100.00
172
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Automobile Tire Production
0274
C
Control Device
Reference(s)
Data Source
Uncontrolled
59
Information based on composite survey data and GC/HS
analysis of grab sample.
SCC Assignments: 30102601
Saroad
43115
43116
43248
43262
TOTAL
=
CAS Number
110-82-7
96-37-7
================
Name
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
CYCLOHEXANE
NETHYLCYCLOPENTANE
============================:
Spec_HW
98.19
112.23
84.16
84.16
=================
Spec_UT
99.84
0.08
0.04
0.04
100.00
==========
Peak
=====
173
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Referenee(s)
Data Source
Rubber and Miscellaneous Plastics Products -
1008
D
Not reported
1
Engineering judgement based on reported emiss
Fabricated Rubber Products - Styrene/ButMt^n;
(ions
(AP-42) of butadiene and styrene from the emulsion
polymerization process.
SCC Assignments: 30800699
Saroad
CAS Number
Name
SpecJtW Spec_UT Peak
43218
45220
106-99-0
100-42-5
1,3-BUTADIENE
STYRENE
54.09
104.14
60.00
40.00
TOTAL
100.00
174
-------
3.16 OIL AND GAS PRODUCTION
The oil and gas production industry includes the following processes:
exploration and site preparation, drilling, crude processing, natural gas
processing, and secondary or tertiary recovery. The principal products of
this industry are natural gas and crude oil. Sources of VOC emissions from
this industry include blowouts during drilling operations, storage tank
breathing and filling losses, wastewater treatment processes, and fugitive
leaks in valves, pumps, pipes, and vessels.
175
-------
176
-------
VOC Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Oil and Gas Production - Fugitives - Unclassified
1010
D
Control Device
Reference(s)
Data Source
Not reported
1
Composite profile developed from profiles 1011, 1012
using the procedure described on pp. 100-112 of
Reference 1: compositing based on relative equipment
count for gas and liquid service for South Coast Air
Basin.
SCC Assignments: 31088801
Saroad
TOTAL
CAS Number
Name
Spec_HW Spec_WT Peak
43105
43106
43107
43115
43116
43122
43201
43202
43204
43212
43214
45201
74-82-8
74-84-0
74-98-6
106-97-8
75-28-5
71-43-2
ISOMERS OF HEXANE
ISOHERS OF HEPTANE
ISOMERS OF OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
ISOHERS OF PENTANE
METHANE
ETHANE
PROPANE
N- BUTANE
I SO- BUTANE
BENZENE
86.17
100.20
114.23
98.19
112.23
72.15
16.04
30.07
44.09
58.12
58.12
78.11
8.08
9.48
6.99
1.30
0.50
4.29
46.31
6.99
9.48
6.19
0.30
0.10
100.01
177
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Oil and Gas Production - Fugitives - Valves and Fittings - Liquid Service
1011
D
Control Device
Reference(s)
Data Source
Not reported
1
Based on liquid service species data developed for
American Petroleum Institute.
SCC Assignments: 31000101
Saroad
TOTAL
CAS Nunfcer
Name
Spec_MU Spec_WT Peak
43105
43106
43107
43115
43116
43122
43201
43202
43204
43212
43214
45201
74-82-8
74-84-0
74-98-6
106-97-8
75-28-5
71-43-2
ISOHERS OF HEXANE
ISOHERS OF HEPTANE
ISOHERS OF OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
ISOHERS OF PENTANE
METHANE
ETHANE
PROPANE
N- BUTANE
I SO- BUTANE
BENZENE
86.17
100.20
114.23
98.19
112.23
72.15
16.04
30.07
44.09
58.12
58.12
78.11
9.90
11.60
8.70
1.60
0.60
5.60
37.60
6.40
10.10
7.40
0.40
0.10
100.00
178
-------
VOC Profile Special ion Report
Profile Name Oil and Gas Production - Fugitives - Valves and Fittings - Gas Service
Profile Number 1012
Data Quality D
Control Device Not reported
Reference(s) 1
Data Source Based on gas service species data developed for
American Petroleum Institute.
SCC Assignments: 31000203
Saroad
TOTAL
CAS Number
Name
Spec_MU Spec_WT Peak
43105
43106
43107
43115
43116
43122
43201
43202
43204
43212
43214
45201
74-82-8
74-84-0
74-98-6
106-97-8
75-28-5
71-43-2
ISOHERS OF HEXANE
ISOHERS OF HEPTANE
ISOHERS OF OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
N-BUTANE
ISO- BUTANE
BENZENE
86.17
100.20
114.23
98.19
112.23
72.15
16.04
30.07
44.09
58.12
58.12
78.11
5.20
6.10
4.60
0.90
0.30
2.10
61.30
7.90
7.00
4.30
0.20
0.10
100.00
179
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Crude Oil Production - Well Heads (Water Flood)
1205
C
Control Device Uncontrolled
Reference(s) 96
Data Source Crude comes from the Oklahoma Glen Sand formation which
at a depth of 1500 feet. Nine samples were taken in
stainless steel canisters and analyzed using a GC with
cryogenic sample pre-concentration and flame ionization
detection.
SCC Assignments: 31000101
Saroad
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
TOTAL
ssssssssirsss:
CAS Number
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
Name
ETHANE
PROPANE
N-BUTANE
N -PENTANE
2-HETHYLPENTANE
3-HETHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2,4-DIMETHYLPENTANE
CYCLOHEXANE
HETHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-METHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-DIHETHYLBUTANE
3-METHYLHEXANE
2-METHYLHEPTANE
3-HETHYLHEPTANE
2-ME-PROPANE
2-ME-BUTANE
2,2,4-TRIHE-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
===============================
Spec_MW
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
Spec_WT Peak
6.27
18.42
14.74
5.68
1.49
0.89
1.95
1.32
1.02
0.49
0.22
0.77
1.27
1.45
0.39
0.16
0.16
0.47
0.05
0.53
0.66
0.35
5.36
4.62
0.75
0.38
0.62
0.95
1.35
3.62
76.40
180
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Crude Oil Production - Well Heads (Water Flood)
1206
C
Control Device Uncontrolled
Reference(s) 96
Data Source Crude comes from the Oklahoma Redfork formation which is at
a depth of 1,300 feet. Eight samples were taken in
stainless steel canisters and analyzed using a GC with
cryogenic sample pre-concentration and flame ionization
detection.
SCC Assignments: 31000101
Saroad
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
CAS Number
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2 '
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
Name
ETHANE
PROPANE
N- BUTANE
N-PENTANE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2,4-DIMETHYLPENTANE
CYCLOHEXANE
HETHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-HETHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-DIMETHYLBUTANE
3-HETHYLHEXANE
2-METHYLHEPTANE
3-METHYLHEPTANE
2-ME-PROPANE
2-HE -BUTANE
2,2,4-TRIME-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
H-XYLENE AND P-XYLENE
Spec.MW
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
Spec_WT Peak
6.74
16.55
18.78
10.97
3.29
1.94
4.78
2.27
1.06
0.91
0.13
1.43
1.97
3.04
0.74
0.32
0.32
0.26
0.09
1.04
0.79
0.34
5.48
8.08
1.37
0.16
0.13
0.12
0.04
0.34
TOTAL
93.48
============================
181
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Well Heads (Water Flood) Composite
1207
C
Uncontrolled
96
Composite
profile developed from Profiles
1205 and 1206
SCC Assignments 31000101
Saroad CAS Number
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
43288 1678-91-7
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
TOTAL
ssssss=srs====s
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
Name
ETHANE
PROPANE
N-BUTANE
N- PENTANE
2-HETHYLPENTANE
' 3-HETHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2,4-DIMETHYLPENTANE
CYCLOHEXANE
HETHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
2-HETHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-DIMETHYLBUTANE
3-HETHYLHEXANE
2-METHYLHEPTANE
3-METHYLHEPTANE
2-ME-PROPANE
2-HE-BUTANE
2,2,4-TRIHE-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
Spec_MW
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
Spec_WT Peak
6.51
17.48
16.77
8.33
2.40
1.42
3.37
1.80
1.04
0.70
0.18
1.11
1.63
2.44
0.57
0.25
0.24
0.37
0.08
0.80
0.73
0.35
5.42
6.36 .
1.07
0.28
0.38
0.54
0.70
1.98
85.30
182
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Crude Oil Production - Gathering Tanks
1208
C
Control Device Uncontrolled
Reference(s) 96
Data Source Seven samples from Oklahoma Glen Sand and Dutcher
formations were taken in stainless steel canisters and
analyzed using a GC with cryogenic sample pre-concentration
and flame ionization detection.
SCC Assignments: 40400302
Saroad
CAS Number
Name
Spec_MW Spec_WT Peak
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
ETHANE
PROPANE
N- BUTANE
N-PENTANE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2,4-DIMETHYLPENTANE
CYCLOHEXANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-HETHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIHETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-DIMETHYlBUTANE
3-HETHYLHEXANE
2-HETHYLHEPTANE
3-HETHYLHEPTANE
2 -HE -PROPANE
2-ME-BUTANE
2,2,4-TRIME-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
9.28
25.84
20.03
7.30
1.80
1.03
2.20
1.21
0.70
0.51
0.06
0.90
1.23
1.48
0.37
0.16
0.20
0.28
0.08
0.51
0.52
0.24
7.14
6.29
0.56
0.12
0.23
0.09
0.11
0.46
TOTAL
90.93
183
-------
VOC Profile Speciation Report
Profile Name Oilfield Pipeline Tanks
Profile Number 1209
Data Quality C
Control Device Internal Floating Roofs with Seals
Reference(s)
Data Source
96
Four samples
sweet" crude
and analyzed
of emissions from tanks storing
"Oklahoma
oil were taken in stainless steel canisters
using a GC with cryogenic sample
pre-
concentration and f la-ne ionization detection.
SCC Assignments: 40400302, 40400305
Saroad
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
CAS Number
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
'108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
Name
ETHANE
PROPANE
N- BUTANE
N-PENTANE
2-HETHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2,4-DIHETHYLPENTANE
CYCLOHEXANE
HETHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
2-HETHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-DIMETHYLBUTANE
3-METHYLHEXANE
2-HETHYLHEPTANE
3-HETHYLHEPTANE
2-HE-PROPANE
2-HE-BUTANE
2,2,4-TRIME-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
Spec_HU
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
Spec_WT Peak
3.95
22.66
13.62
19.21
2.58
1.30
2.74
0.56
0.18
0.61
0.07
0.93
0.78
1.13
0.29
0.09
0.50
0.08
0.31
0.32
0.16 '
0.08
2.47
22.50
0.24
0.08
0.12
0.02
0.03
0.12
TOTAL
97.73
184
-------
VCX: Profile Special ion Report
Profile Name
Profile Number
Data Quality
Pipeline Terminal Tanks
1210
C
Control Device Internal Floating Roof with Seal
Reference(s) 96
Data Source Four samples from Sinclair Terminal storing "Oklahoma
sweet" crude oil were taken in stainless steel canisters
and analyzed using a GC with cryogenic sample pre-
concentration and flame ionization detection.
SCC Assignments: 40400303, 40400304, 40400305
Saroad
TOTAL
CAS Number
Name
Spec_HW Spec_WT Peak
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
ETHANE
PROPANE
N- BUTANE
N-PENTANE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2.4-DIMETHYLPENTANE
CYCLOHEXANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-HETHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-DIHETHYLBUTANE
3-HETHYLHEXANE
2-METHYLHEPTANE
3-METHYLHEPTANE
2 -ME -PROPANE
2 -ME -BUTANE
2,2,4-TRIME-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
0.35
3.31
9.57
9.41
5.26
3.13
4.69
2.11
0.67
2.02
0.38
4.57
5.91
7.22
0.98
0.80
1.07
0.61
0.30
1.50
1.07
0.50
4.51
9.76
3.03
0.54
0.90
0.22
0.16
0.73
85.28
185
-------
VOC Profile Speciation Report
Profile Name Refinery
Profile Number 1211
Data Quality C
Control Device Internal
Reference(s)
Data Source
96
Crude Oi I Storage Tanks
Floating Roof with Seal
Four samples from Sinclair and Sun
Refinery crude oil
storage tanks were taken in stainless steel canisters
analyzed
using a GC with cryogenic
and
sample pre-concentration
and flame ionization detection.
SCC Assignments: 40400303,
Saroad
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
CAS Number
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
TOTAL
==========================
40400304, 40400305
Name
ETHANE
PROPANE
N-BUTANE
N-PENTANE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2,4-DIHETHYLPENTANE
CYCLOHEXANE
HETHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
2-HETHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-DIMETHYLBUTANE
3-METHYLHEXANE
2-METHYLHEPTANE
3-HETHYLHEPTANE
2-ME-PROPANE
2-HE-BUTANE
2.2,4-TRIHE-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
H-XYLENE AND P-XYLENE
SpecJW
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
Spec_WT Peak
4.51
18.97
22.71
13.29
3.12
1.79
3.89
1.31
0.34
0.87
0.11
1.24
1.21
2.15
0.50
0.22
0.38
0.11
0.16
0.77
0.30
0.15
6.06
11.22
0.70
0.32
0.35
0.05
0.04
0.14
96.98
186
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Crude Oil Production - Uell Heads (Gas Drive)
1212
C ' . - .
Uncontrolled
96
Crude comes from the Oklahoma Dutcher formation which is at
a depth of 1,400 feet. Four samples were taken in stainless
steel canisters and analyzed using a GC with cryogenic
sample pre-concentration and flame ionization detection.
SCC Assignments: 31000101
Saroad
CAS Number
Name
Spec_HW Spec_WT Peak
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
ETHANE
PROPANE
N- BUTANE
N-PENTANE
2-METHYLPENTANE
3-HETHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2,4-DIHETHYLPENTANE
CYCLOHEXANE
HETHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
2-METHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-DIHETHYLBUTANE
3-HETHYLHEXANE
2-HETHYLHEPTANE
3-METHYLHEPTANE
2-ME-PROPANE
2-HE-BUTANE
2,2,4-TRIME-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
H-XYLENE AND P-XYLENE
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
17.52
32.63
21.33
6.46
1.48
0.83
1.68
0.68
0.25
0.38
0.05
0.68
0.74
1.04
0.24
0.11
0.17
0.09
0.05
0.32
0.23
0.10
6.44
5.56
0.32
0.05
0.09
0.02
0.03
0.12
TOTAL
99.69
187
-------
188
-------
3.17 TEXTILE PRODUCTS
The textile manufacturing industry converts natural and man-made fibers into
fabrics and other textile products. Fibers are processed into yarns which are
woven, knit, or otherwise processed into fabrics. The fabrics are then dyed,
printed, and/or finished. Finished fabrics are then converted into apparel or
other products such as upholstery, sheeting, and draperies by the apparel
industry. Potential emission sources include process unit operations, vented
fugitive emissions, and chemical and fuel storage tanks.
189
-------
190
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Textile Products - General Fabric Operations - Dyeing and Curing
1095
Control Device Not reported
Reference(s) 20
Data Source Air emissions were sampled with a modified SASS and
analyzed by GC/MS. Profile reflects composite of
weighted data from the exhaust of dyeing and curing
processes at four plants.
SCC Assignments: 33000198, 33000199
Saroad
43132
43133
43134
43318
43408
43454
43455
43456
43460
43461
43462
43463
43464
43465
43466
43650
43780
45109
45226
45227
45228
45229
45232
45233
45310
45311
45402
45451
45452
45454
45455
45470
45703
45704
45705
46102
46103
46701
46702
CAS Number
104-76-7
57-10-3
112-39-0
124-10-7
112-61-8
92-52-4
1321-74-0
103-29-7
65-85-0
131-11-3
84-74-2
131-16-8
136-60-7
1817-73-8
84-65-1
82-45-1
91-12-3
Name
ALIPHATICS
PARAFFINS (C16-C34)
PARAFFINS/OLEFINS (C12-C16)
2-ETHYL HEXANOL
PALMITIC ACID
METHYL PALMITATE
METHYL MYRISTATE
METHYL STEARATE
METHYL C11 ESTER
METHYL C12 ESTER
METHYL C13 ESTER
METHYL C14 ESTER
METHYL C15 ESTER
METHYL C19 ESTER
METHYL C20 ESTER
OXYGENATES
DIMETHYL ALKYL AMINES
C3/C4/C5 ALKYLBENZENES
BIPHENYL
METHYL BIPHENYL
ETHYL STYRENE
DIVINYL BENZENE
DIPHENYL ETHANE
ETHYL-PHENYL-PHENYL-ETHANE
C8 PHENOLS
C9 PHENOLS
BENZOIC ACID
DIMETHYL PHTHALATE
D I BUTYL PHTHALATE
DIPROPYL PHTHALATE
BUTYL BENZOATE
DI-C8 ALKYL PHTHALATE
2,2 DICHLORONITROANILINE
BROMODINITROANILINE
BROMOD I NITROBENZENE
ANTHRAQUINONE
AM I NOANT HRAQU I NONE
NAPTHALENE
METHYL NAPHTHALENES
Spec_MW
100.00
352.43
197.38
130.23
256.43
270.46
242.41
298.52
214.35
228.37
242.40
256.43
270.45
326.56
340.59
86.00
59.11
134.21
154.21
168.24
132.21
130.20
182.27
210.32
122.16
136.19
122.13
194.19
278.35
250.30
178.23
390.56
207.02
262.03
247.02
208.23
223.23
128.17
142.20
Spec_WT Peak
5.02
0.78
0.07
0.41
39.54
7.53
0.32
9.44
0.01
0.02
0.01
0.08
0.04
0.02
0.01
0.19
0.43
2.07
0.48
0.10
0.54
0.04
0.25
0.37
0.06
0.26
1.49
4.27
0.29
0.02
22.07
0.47
0.12
0.03
0.96
1.25
0.04
0.37
0.17
191
-------
VOC Profile Speciation Report - continued (profile 1095)
Saroad CAS Number Name Spec_MU Spec_WT Peak
46703 28804-88-8 DIMETHYL NAPTHALENE 156.23 0.12
99999 UNIDENTIFIED 86.00 0.25
TOTAL 100.01
192
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Textile Products - General Fabric Operations - Tenter Frame
1096
B
Control Device Not reported
Reference(s) 20
Data Source Air emissions were sampled with a modified SASS train
and analyzed by GC/MS. Profile reflects composite of
weighted data from the exhaust of tenter frame
operations at four plants.
SCC Assignments: 33000104
Saroad
43132
43133
43134
43454
43455
43456
43470
43650
43950
43951
45109
45226
45227
45228
45229
45230
45232
45233
45402
45451
45452
45455
45470
45703
45705
45808
45830
45831
46102
46701
46702
46703
99999
CAS Number
112-39-0
124-10-7
112-61-8
111-82-0
556-67-2
92-52-4
1321-74-0
103-29-7
65-85-0
131-11-3
84-74-2
136-60-7
2531-22-6
84-65-1
91-12-3
28804-88-8
Name
ALIPHATICS
PARAFFINS (C16-C34)
PARAFFINS/OLEFINS (C12-C16)
METHYL PALHITATE
METHYL MYRISTATE
METHYL STEARATE
METHYL DODECANOATE
OXYGENATES
OCTAMETHYLCYCLOTETRASILOXANE
S1LOXANE
C3/C4/C5 ALKYLBENZENES
BIPHENYL
METHYL BIPHENYL
ETHYL STYRENE
DIVINYL BENZENE
DI(ETHYLPHENYL) ETHANE
DIPHENYL ETHANE
ETHYL-PHENYL-PHENYL-ETHANE
BENZOIC ACID
DIMETHYL PHTHALATE
01 BUTYL PHTHALATE
BUTYL BENZOATE
DI-C8 ALKYL PHTHALATE
2,2 DICHLORONITROANILINE
BROMODINITROBENZENE
DICHLOROBENZENES
TRICHLOROBENZENES
TETRACHLOR08ENZENES
ANTHRAQUINONE
NAPTHALENE
METHYL NAPHTHALENES .
DIMETHYL NAPTHALENE
UNIDENTIFIED
Sp«C_MW
100.00
352.43
197.38
270.46
242.41
298.52
214.35
86.00
296.62
76.08
134.21
154.21
168.24
132.21
130.20
238.37
182.27
210.32
122.13
194.19
278.35
178.23
390.56
207.02
247.02
147.01
181.45
215.90
208.23
128.17
142.20
156.23
86.00
Spec_WT Peak
14.90
2.83
0.02
8.99
5.84
11.88
0.03
0.35
2.13
1.16
3.49
2.12
0.08
5.41
0.61
0.01
1.16
2.07
0.24
7.19
0.51
20.06
0.15
0.11
1.21
0.13
2.90
0.14
1.36
1.63
0.26
0.42
0.62
TOTAL
100.01
193
-------
194
-------
3.18 ORGANIC SOLVENT EVAPORATION
Organic solvent evaporation is a source of emissions with several
operations. These operations include but are not limited to: dry cleaning,
degreasing, petroleum and chemical storage, surface coating applications,
asphalt related processes, solvent use, printing, and graphic arts.
195
-------
196
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CA!
43817
Perchloroethylene - Dry Cleaning
0085
E
Uncontrolled
59, 60
Engineering judgement.
40100101. 40100103
» Number Name Spec_HW Spec_WT Peak
27-18-4 PERCHLOROETHYLENE 165.83 100.00
TOTAL
100.00
197
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Degreasing - 1,1,1-Trichloroethane
0087
E
Control Device Uncontrolled
Referenced) 49
Data Source Engineering judgement and calculations from composite
survey data.
SCC Assignments: 40100202
Saroad
43814
CAS Number
71-55-6
Name
1,1,1-TRICHLOROETHANE
Spec_MU Spec_WT Peak
133.42 100.00
TOTAL
100.00
198
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Degreasing - Trichlorofluoromethane (Freon 11)
0088
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement and calculations from composite
survey data.
SCC Assignments: 40100258
Saroad
43811
TOTAL
CAS Number Name
73-69-4 TRICHLOROFLUOROMETHANE
Spec_MU Spec_UT Peak
137.38 100.00
100.00
199
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Degreasing - 1,1,2-Trichloroethane
0089
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement and calculations from composite
survey data.
SCC Assignments: 40100259
Saroad
43820
TOTAL
CAS Number
79-00-5
Name
1,1,2-TRICHLOROETHANE
Spec_MW Spec_UT Peak
133.42 100.00
100.00
200
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Degreasing - Toluene
0090
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement, calculations from composite
survey data.
SCC Assignments: 40100206, 40100256
Saroad
45202
TOTAL
CAS Number
108-88-3
Name
TOLUENE
Spec_NW Spec_UT Peak
92.13 100.00
100.00
201
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Solvent Use - Domestic Solvents
0197
D
Control Device
Reference(s)
Data Source
SCC Assignments
Uncontrolled
59
Engineering evaluation of literature test data.
Saroad
CAS Number
Name
Spec_HU SpecJJT Peak
43214
43302
43304
43367
43369
43435
43502
43551
45101
TOTAL
75-28-5
64-17-5
67-63-0
111-46-6
57-55-6
138-22-7
50-00-0
67-64-1
8030-30-6
I SO- BUTANE
ETHYL ALCOHOL
ISO-PROPYL ALCOHOL
GLYCOL ETHER
PROPYLENE GLYCOL
N-BUTYL ACETATE
FORMALDEHYDE
ACETONE
NAPHTHA
58.12
46.07
60.09
106.14
76.11
116.16
30.03
58.08
114.00
5.30
36.90
38.50
8.30
3.20
1.30
0.60
1.40
4.50
100.00
202
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Degreasing - Trichloroethylene
0271
Control Device Uncontrolled
Reference(s) 71
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40100255
Saroad
43824
TOTAL
CAS Number
79-01-6
Name
TRICHLOROETHYLENE
Spec_HW Spec_WT Peak
131.40 100.00
100,00
203
-------
VOC Profile Speciation Report
Profile Name
Profile Humbep
Data Quality
Degreasing - Dichloromethane
0275
Control Device Uncontrolled
ReferenceCs) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40100204, 40100224, 40100254, 40100302
Saroad
43802
CAS Number
75-09-2
Name
DICHLOROHETHANE
Spec_MW Spec_WT Peak
84.94 100.00
100.00
TOTAL
204
-------
VOC Profile Special ion Report
Profile Name
Profile Number
Data Quality
Degreasing - Trichlorotrifluoroethane (Freon 113)
0277
E
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40100105, 40100106, 40100207, 40100257
Saroad
43821
TOTAL
CAS Number Name
76-13-1 TRICHLOROTRIFLUOROETHANE
Spec_MU Spec_WT Peak
187.38 100.00
100.00
205
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CA!
43302
43802
TOTAL
Degreasing - Open Top - Chlorosolve
1021
E
Mot reported
4
Engineering judgement.
40100208
> Number Name Spec_HW SpecJJT Peak
64-17-5 ETHYL ALCOHOL 46.07 30.00
75-09-2 DICHLOROMETHANE 84.94 70.00
100.00
:==== "==='-=»"' =ss=s======s=s=s:======r:s:s=sss:=s:s: =:==================:===:=
206
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
FURFURAL
1142
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
49000104
Saroad
45503
CAS Number
98-01-1
Name
2-FURFURAL
Spec_MU Spec_WT Peak
96.09 100.00
100.00
TOTAL
207
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CA!
43301
TOTAL
SSSSSSSrsSSrSSSS
HETHANOL
1149
E
Controlled/Uncontrolled
76
Engineering judgement.
40100301
> Number Name Spec_MU Spec_WT Peak
67-56-1 METHYL ALCOHOL 32.04 100.00
100.00
208
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Degreasing
1192
B
Control Device Uncontrolled
Reference(s) 90
Data Source Six mineral spirit samples from two companies combined
in equal amounts by volume. Headspace analyzed by
GC/MS. 1974 consumption data used to combine mineral
spirit composite with pure chlorinated solvents.
SCC Assignments: 40100201, 40100221, 40100251, 40100303
Saroad
43109
43110
43110
43110
43111
43111
43111
43112
43113
43113
43124
43124
43124
43125
43125
43125
43125
43125
43125
43135
43138
43138
43141
43146
43146
43146
43146
43146
43146
43146
43147
43147
43147
43147
43147
43147
43148
43148
43150
CAS Number Name
ISOMERS OF DECANE
ISOHERS OF UNDECANE
ISOMERS OF UNDECANE
ISOHERS OF UNDECANE
ISOHERS OF DODECANE
ISOMERS OF DODECANE
ISOMERS OF DODECANE
ISOMERS OF TRIDECANE
ISOMERS OF TETRADECANE
ISOMERS OF TETRADECANE
C9 OLEFINS
C9 OLEFINS
C9 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 PARAFFINS
C-8 OLEFINS
C-8 OLEFINS
C8 PARAFFIN
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
ISOHERS OF C9H16
ISOHERS OF C9H16
ISOHERS OF C10H18
Spec_MW
142.28
156.30
156.30
156.30
170.32
170.32
170.32
184.36
198.38
198.38
126.24
126.24
126.24
140.27
140.27
140.27
140.27
140.27
140.27
142.28
112.23
112.23
114.23
154.29
154.29
154.29
154.29
154.29
154.29
154.29
168.32
168.32
168.32
168.32
168.32
168.32
124.23
124.23
138.25
Spec_WT
4.36
0.00
0.00
3.03
0.18
0.47
0.26
0.03
0.01
0.09
0.00
0.00
0.00
0.04
0.00
1.11
0.00
0.00
0.00
0.00
0.49
0.51
0.00
0.00
0.06
0.00
0.00
0.00
0.23
0.00
0.00
0.00
0.01
0.02
0.00
0.04
0.32
0.07
0.00
Peak
(15)
(17)
(23)
(25)
(27)
(31)
(5 )
(2 )
(3 )
(10)
(7 )
(4 )
(8 )
(6 )
(6 )
(1 )
(1 )
(16)
(13)
(15)
(14)
(24)
(18)
(26)
(22)
(32)
(27)
(25)
(3 )
(11)
209
-------
VOC Profile Speciation Report - continued (profile 1192)
Saroad
43151
43152
43231
43232
43235
43261
43288
43565
45105
45105
45105
45105
45105
45105
45105
45105
45105
45105
45105
45105
45107
45108
45108
45202
45204
45209
45210
45245
45245
45245
45245
45245
45303
45304
45304
45320
45808
46202
46202
46601
46701
46747
46748
46748
46748
46748
46748
46748
46753
90010
90028
90029
CAS Number
110-54-3
142-82-5
111-84-2
108-87-2
1678-91-7
25551-13-7
108-88-3
95-47-6
103-65-1
98-82-8
2531-22-6
2782-91-4
91-12-3
91-17-8
Name
ISOHERS OF C11H20
C12H22
HEXANE
HEPTANE
NONAHE
METHYLCYCLOHEXANE
ETHYLCYCLOHEXANE
DIHETHYLCYCLOBUTANONE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
TRIHETHYLBENZENE
ISOHERS OF PROPYLBENZENE
ISOHERS OF PROPYLBENZENE
TOLUENE
0-XYLENE
N-PROPYLBENZENE
CUHENE (ISOPROPYL BENZENE)
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C4-ALKYLPHENOLS
C5-ALKYLPHENOLS
C5-ALKYLPHENOLS
DIHETHYLBENZYLALCOHOL
DICHLOROBENZENES
OCTAHYDROINDENES
OCTAHYDROINDENES
TETRAHETHYLTHIOUREA
NAPTHALENE
HETHYLINDANS
HETHYLDECALINS
HETHYLDECALINS
HETHYLDECALINS
HETHYLDECALINS
HETHYLDECALINS
HETHYLDECALINS
DECALINS
H-XYLENE AND P-XYLENE
HETHYLHEXANE
HETHYLHEXENES
Spec_MW
152.28
166.31
86.17
100.20
128.25
98.21
112.23
98.14
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
120.19
120.19
120.19
92.13
106.16
120.19
120.20
148.24
148.24
148.24
148.24
148.24
150.22
164.25
164.25
136.19
147.01
244.00
244.00
132.25
128.17
132.21
152.28
152.28
152.28
152.28
152.28
152.28
138.25
106.16
100.20
98.18
Spec_UT
0.00
0.00
0.13
27.59
2.84
5.97
0.26
0.19
0.04
0.04
0.10
0.69
0.03
0.09
0.10
0.09
0.12
0.00
0.03
0.00
1.00
0.15
0.76
20.88
0.57
0.15
0.11
0.00
0.00
0.00
0.02
0.08
0.12
0.00
0.06
0.05
0.00
0.08
0.04
0.02
0.10
0.01
0.00
0.05
0.00
0.00
0.00
0.03
0.19
0.76
4.16
0.40
Peak
(13)
(32)
(9 )
(8 )
(17)
(12)
(16)
(24)
(19)
(22)
(29)
(21)
(20)
(7 )
(6 )
(28)
(30)
(27)
(26)
(33)
(9 )
(15)
(33)
(23)
(25)
(10)
(21)
(11)
(18)
210
-------
VOC Profile Speciation Report - continued (profile 1192)
Saroad
90047
90048
90049
90064
90066
90067
90070
90070
90071
90072
90073
90075
90076
90076
90077
90080
90081
90083
90085
90089
90090
90090
90091
90094
90096
90096
90098
90101
90102
90104
90104
90105
90106
90107
90108
98058
98059
98060
98062
98063
98082
98091
CAS Number Name
METHYLNONANE
HETHYLDECANES
HETHYLUNDECAME
D I HETHYLCYCLOPENTANE
NONAOIENE
DIHETHYLHEXAMES
DIMETHYLOCTANES
DIHETHYLOCTANES
DIMETHYLUNOECAME
METHYLPROPYLCYCLOHEXANES
METHYL 1 SOPROPYLCYCLOHEXANE
ETHYLOCTENE
DIMETHYLNONANES
DIHETHYLNONANES
ETHYLOCTANE
ETHYLMETHYLCYCLOPENTANE
ETHYLHEXANE
ETHYLMETHYLCYCLOHEXANES
ETHYLMETHYLOCTANE
ETHYLD1METHYLCYCLOHEXANE
ETHYLPROPYLCYCLOHEXANES
ETHYLPROPYLCYCLOHEXANES
TETRAMETHYLCYCLOBUTENE
TRIMETHYLHEPTANES
TRIMETHYLOCTANES
TRIMETHYLOCTANES
TETRAMETHYLCYCLOPENTANE
1678-93-9 BUTYLCYCLOHEXANE
HETHYLPROPYLNONANE
METHYLOCTANES
METHYLOCTANES
PROPENYLCYCLOHEXANE
METHYLNONENE
HETHYLDECENE
HETHYLDOOECANE
TR I METHYLCYCLOPENTANE
D 1 METHYLCYCLOHEXANE
3073-66-3 TRIMETHYLCYCLOHEXANES
OIETHYLCYCLOHEXANE
N-PENTYLCYCLOHEXANE
ETHYLHEPTENE
DIHETHYLHEPTANES
Spec_MW
142.28
156.32
170.34
98.19
124.23
114.23
142.28
142.28
184.36
140.27
140.27
140.27
156.31
156.31
142.29
112.21
114.23
126.24
156.31
140.27
154.29
154.29
110.19
142.29
156.31
156.31
126.24
140.27
184.36
128.26
128.26
124.33
140.26
154.29
184.36
112.16
112.24
126.27
140.27
154.30
126.24
128.26
Spec_UT
2.46
1.46
0.10
2.31
0.07
1.09
0.59
0.39
0.00
0.65
0.18
0.14
0.49
0.21
0.08
0.02
0.16
2.24
0.22
0.04
0.00
0.20
0.01
0.71
0.15
0.00
0.22
0.53
0.11
0.85
1.55
0.07
0.09
0.25
0.06
1.17
0.35
0.80
0.25
0.16
0.10
0.05
Peak
(29)
(2 )
(4 )
(31)
(14)
(19)
(12)
(30)
(5 )
(20)
TOTAL
100.01
211
-------
VOC Profile Speciation Report
Profile Name Drycleaning
Profile Number 1193
Data Quality B
Control Device Uncontrolled
Reference(s) 90
Data Source Five mineral spirit samples from two companies combined
in equal amounts by volume. Headspace analyzed by GC/HS
SCC Assignments: 40100102
Saroad
43109
43110
43110
43110
43110
43111
43112
43124
43124
43125
43125
43125
43125
43135
43135
43135
43136
43138
43146
43146
43146
43146
43146
43146
43147
43147
43147
43150
43150
43150
43151
43151
43151
43151
43151
43151
43151
43153
43235
43261
43288
CAS Number Name
I SOWERS OF DECANE
ISOHERS OF UNDECANE
I SOWERS OF UNDECANE
ISOMERS OF UNDECANE
ISOHERS OF UNDECANE
ISOHERS OF DOOECANE
ISOHERS OF TR I DECANE
C9 OLE FINS
C9 OLE FINS
C10 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 PARAFFINS
C10 PARAFFINS
C10 PARAFFINS
C9 PARAFFIN
C-8 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
ISOHERS OF C10H18
ISOHERS OF C10H18
ISOHERS OF C10H18
ISOHERS OF C11H20
ISOHERS OF C11H20
ISOHERS OF C11H20
ISOHERS OF C11H20
ISOHERS OF C11H20
ISOHERS OF C11H20
ISOHERS OF C11H20
C10H16
111-84-2 NONANE
108-87-2 HETHYLCYCLOHEXANE
1678-91-7 ETHYLCYCLOHEXANE
Spec.MU
142.28
156.30
156.30
156.30
156.30
170.32
184.36
126.24
126.24
140.27
140.27
140.27
140.27
142.28
142.28
142.28
128.25
112.23
154.29
154.29
154.29
154.29
154.29
154.29
168.32
168.32
168.32
138.25
138.25
138.25
152.28
152.28
152.28
152.28
152.28
152.28
152.28
136.24
128.25
98.21
112.23
Spec_WT
11.28
7.92
0.00
0.00
0.00
1.12
0.05
0.00
0.02
0.42
1.63
0.00
0.10
0.74
0.00
0.00
0.00
0.00
0.10
0.00
0.88
0.00
0.00
0.00
0.10
0.02
0.00
0.07
0.00
0.00
0.10
0.00
0.00
0.00
0.07
0.15
0.00
0.10
6.96
0.02
0.59
Peak
(19)
(14)
(24)
(3 )
(5 )
(7 )
(12)
(6 )
(4 )
(2 )
(1 >
(18)
(17)
(16)
(6 )
(20)
(25)
(26)
(5 )
(11)
(9 )
(12)
(15)
(25)
(22)
(14)
(8 )
212
-------
VOC Profile Speciation Report - continued (profile 1193)
Saroad
43336
43397
43566
43567
45105
45105
45105
45105
45105
45105
45105
45105
45105
45107
45108
45108
45113
45202
45203
45204
45209
45210
45215
45238
45245
45303
45304
45304
45320
45801
45808
46202
46601
46602
46701
46748
46748
46753
46753
90010
90045
90047
90048
90049
90055
90066
90070
90071
90072
90074
90076
90076
CAS Number
25551-13-7
108-88-3
100-41-4
95-47-6
103-65-1
98-82-8
98-06-6
108-90-7
2531-22-6
2782-91-4
95-16-9
91-12-3
91-17-8
91-17-8
Name
OCTANOL
TR I METHY LCYCLOHEXANOL
TR I HETHYLCYCLOPENTANONE
TETRAMETHYLPENTANONE
1SOMERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
I SOWERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
ISOMERS OF PROPYLBENZENE
C11H10
TOLUENE
ETHYLBENZENE
0-XYLENE
N-PROPYLBENZENE
CUHENE ( I SOPROPYL BENZENE)
TERT-BUTYLBENZENE
ETHYLTOLUENE
C5-ALKYLBENZENES
C4-ALKYLPHENOLS
C5-ALKYLPHENOLS
C5-ALKYLPHENOLS
DIHETHYLBENZYLALCOHOL
CHLOROBENZENE
DICHLOROBENZENES
OCTAHYDROINDENES
TETRAMETHYLTHIOUREA
BENZOTHIAZOLE
NAPTHALENE
METHYLDECALINS
METHYLDECALINS
DECALINS
DECALINS
M-XYLENE AND P-XYLENE
HETHYLHEPTANE
METHYLNONANE
METHYLDECANES
METHYLUNOECANE
PENTYLCYCLOHEXANE
NONAOIENE
DIMETHYLOCTANES
DIMETHYLUNDECANE
HETHYLPROPYLCYCLOHEXANES
DIHETHYLDECANE
DIHETHYLNONANES
DIHETHYLNONANES
Spec_HW
130.26
142.24
126.20
142.24
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
120.19
120.19
120.19
142.20
92.13
106.16
106.16
120.19
120.20
134.21
120.19
148.24
150.22
164.25
164.25
136.19
112.56
147.01
244.00
132.25
135.19
128.17
152.28
152.28
138.25
138.25
106.16
114.23
142.28
156.32
170.34
154.29
124.23
142.28
184.36
140.27
170.34
156.31
156.31
Spee_WT
0.10
0.17
0.15
0.64
1.89
1.00
0.07
0.00
0.35
0.00
0.31
0.12
0.00
2.23
0.98
0.00
0.00
0.50
0.35
1.56
0.00
0.34
0.31
0.38
0.10
0.38
0.17
0.00
0.15
0.26
0.00
0.17
0.05
0.05
0.35
0.00
0.55
0.07
0.53
2.26
0.02
4.17
4.19
0.91
0.43
0.17
6.49
0.24
5.99
0.29
0.57
0.57
Peak
(3 )
(13)
(23)
(18)
(19)
(9 )
(24)
(10)
(21)
(6 )
(23)
(7 )
(26)
(27)
(10)
(27)
(22)
(20)
(4 )
(15)
(16)
213
-------
VOC Profile Speciation Report - continued (profile 1193)
Saroad CAS Number
90076
90077
90081
90082
90083
90089
90090
90094
90094
90095
90096
90096
90097
90098
90101 1678-93-9
90104
90105
90107
90109
90109
90110
90110
90111
90112
90113
90114
90118
90120
98059
98060 3073-66-3
98060 3073-66-3
98062
98091
98091
TOTAL
===========================:
Name
DIMETHYLNONANES
ETHYLOCTANE
ETHYLHEXANE
ETHYLMETHYLHEXANE
ETHYLMETHYLCYCLOHEXANES
ETHYLDIHETHYLCYCLOHEXANE
ETHYLPROPYLCYCLOHEXANES
TRIMETHYLHEPTANES
TRIMETHYLHEPTANES
TRIMETHYLHEXENE
TR I METHYLOCTANES
TR I METHYLOCTANES
TRIMETHYLDECANE
TETRAMETHYLCYCLOPENTANE
BUTYLCYCLOHEXANE
METHYLOCTANES
PROPENYLCYCLOHEXANE
METHYLDECENE
PROPYLHEPTENES
PROPYLHEPTENES
D I ETHYLMETHYLCYCLOHEXANES
D I ETHYLMETHYLCYCLOHEXANES
I SOPROPYLMETHYLCYCLOHEXANE
DIMETHYLOCTYNE
PENTYLIDENECYCLOHEXANE
D I METHYLBUTYLCYCLOHEXANE
OCTAHYDROPENTALENE
PROPYLCYCLOHEXANE
DIMETHYLCYCLOHEXANE
TRIMETHYLCYCLOHEXANES
TRIMETHYLCYCLOHEXANES
DIETHYLCYCLOHEXANE
DIMETHYLHEPTANES
DIMETHYLHEPTANES
=============================
Spec_MU
156.31
142.29
114.23
128.26
126.24
140.27
154.29
142.29
142.29
126.24
156.31
156.31
184.36
126.24
140.27
128.26
124.33
154.29
140.27
140.27
111.20
111.20
140.27
138.25
152.00
168.32
225.20
126.24
112.24
126.27
126.27
140.27
128.26
128.26
===============
Spec_WT
1.34
0.21
0.34
0.10
4.27
0.95
0.50
3.58
2.31
0.35
0.35
0.00
0.02
0.55
1.68
1.49
0.77
0.67
0.34
0.21
0.29
0.26
0.43
0.10
0.17
0.05
0.10
2.11
0.47
1.72
0.29
0.45
0.45
0.10
100.04
:==========:
Peak
(6 )
(11)
(13)
(8 )
(21)
(17)
(2 )
(1 )
214
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Degreasing Composite
1195
B
Uncontrolled
90,92
Composite profile developed using Profile 1192 and
consumption data for solvents used in degreasing
industry.
SCC Assignments: 40100215, 40100216, 40100217, 40100235, 40100236, 40100295, 40100296, 40100297
40100298, 40100299, 40100335, 40100336, 40100398, 40100399
Saroad
CAS Number
Name
Spec_MW Spec_WT Peak
43109
43110
43110
43110
43111
43111
43111
43112
43113
43113
43124
43124
43124
43125
43125
43125
43125
43125
43125
43135
43138
43138
43141
43146
43146
43146
43146
43146
43146
43146
43147
43147
43147
43147
43147
43147
43148
43148
43150
ISOMERS OF DECANE
ISOHERS OF UNDECANE
ISOMERS OF UNDECANE
ISOHERS OF UNDECANE
ISOHERS OF DOOECANE
ISOMERS OF DOOECANE
ISOHERS OF DODECANE
ISOMERS OF TRIDECANE
ISOHERS OF TETRADECANE
ISOHERS OF TETRADECANE
C9 OLE FINS
C9 OLEFINS
C9 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 OLEFINS
CIO OLEFINS
C10 OLEFINS
C10 PARAFFINS
C-8 OLEFINS
C-8 OLEFINS
C8 PARAFFIN
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
ISOMERS OF C9H16
ISOHERS OF C9H16
ISOHERS OF C10H18
142.28
156.30
156.30
156.30
170.32
170.32
170.32
184.36
198.38
198.38
126.24
126.24
126.24
140.27
140.27
140.27
140.27
140.27
140.27
142.28
112.23
112.23
114.23
154.29
154.29
154.29
154.29
154.29
154.29
154.29
168.32
168.32
168.32
168.32
168.32
168.32
124.23
124.23
138.25
1.33
0.93
0.00
0.00
0.08
0.14
0.06
0.01
0.03
0.00
0.00
0.00
0.00
0.01
0.00
0.34
0.00
0.00
0.00
0.00
0.15
0.16
0.00
0.00
0.00
0.07
0.00
0.00
0.02
0.00
0.01
0.01
0.00
0.00
0.00
0.00
0.02
0.10
0.00
(15)
(17)
(25)
(23)
(27)
(31)
(2 )
(5 )
(3 )
(10)
(7 )
<4 >
(8 )
(6 )
(6 )
(1 )
(1 )
(16)
(15)
(18)
(14)
(13)
(24)
(32)
(25)
(27)
(26)
(22)
(3 )
(11)
215
-------
VOC Profile Speciation Report - continued (profile 1195)
Saroad
43151
43152
43231
43232
43235
43248
43261
43288
43314
43351
43551
43552
43565
43802
43814
43817
43821
43824
45102
45105
45105
45105
45105
45105
45105
45105
45105
45105
45105
45105
45105
45107
45108
45108
45201
45202
45204
45209
45210
45245
45245
45245
45245
45245
45303
45304
45304
45320
45808
46202
46202
46601
CAS Number
110-54-3
142-82-5
111-84-2
110-82-7
108-87-2
1678-91-7
78-92-2
60-29-7
67-64-1
78-93-3
75-09-2
71-55-6
127-18-4
76-13-1
79-01-6
1330-20-7
25551-13-7
71-43-2
108-88-3
95-47-6
103-65-1
98-82-8
2531-22-6
2782-91-4
Name
ISOHERS OF C11H20
C12H22
HEXAHE
HEPTANE
NONANE
CYCLOHEXANE
HETHYLCYCLOHEXANE
ETHYLCYCLOHEXANE
S-BUTYL ALCOHOL
ETHYL ETHER
ACETONE
METHYL ETHYL KETONE
D I HETH YLCYCLOBUTANONE
DICHLOROKETHANE
1,1,1 -TR1 CHLOROETHANE
PERCHLOROETHYLENE
TRICHLOROTRI FLUOROETHANE
TRICHLOROCTHYLENE
ISOHERS OF XYLENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
ISOHERS OF BUTYLBENZENE
TRIHETHYLBENZENE
ISOHERS OF PROPYLBENZENE
ISOHERS OF PROPYLBENZENE
BENZENE
TOLUENE
0-XYLENE
N-PROPYLBENZENE
CUHENE (ISOPROPYL BENZENE)
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALICYLBENZENES
C4-ALKYLPHENOLS
C5-ALKYLPHENOLS
C5-ALKYLPHENOLS
DIHETHYLBENZYLALCOHOL
DICHLOROBENZENES
OCTAHYDROINDENES
OCTAHYDROINDENES
TETRAMETHYLTHIOUREA
Spee_MU
152.28
166.31
86.17
100.20
128.25
84.16
98.21
112.23
74.12
74.12
58.08
72.10
98.14
84.94
133.42
165.83
187.38
131.40
106.16
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
120.19
120.19
120.19
78.11
92.13
106.16
120.19
120.20
148.24
148.24
148.24
148.24
148.24
150.22
164.25
164.25
136.19
147.01
244.00
244.00
132.25
Spec_WT
0.00
0.00
0.04
8.44
0.87
0.10
1.83
0.08
0.70
0.80
1.40
1.10
0.06
4.10
" 22.29
7.40
4.10
21.09
3.40
0.04
0.03
0.00
0.03
0.00
0.03
0.01
0.01
0.01
0.03
0.21
0.01
0.31
0.05
0.23
1.00
8.29
0.17
0.05
0.03
0.00
0.00
0.02
0.00
0.01
0.04
0.00
0.02
0.02
0.00
0.02
0.01
0.01
Peak
(13)
(32)
(22)
(24)
(20)
(19)
(29)
(21)
(9 )
(8 )
(17)
(12)
(16)
(7 )
(6 )
(28)
(27)
(30)
(26)
(33)
(9 )
(15)
216
-------
VOC Profile Speciation Report - continued (profile 1195)
Saroad
46701
46747
46748
46748
46748
46748
46748
46748
46753
90010
90028
90029
90047
90048
90049
90064
90066
90067
90070
90070
90071
90072
90073
90075
90076
90076
90077
90080
90081
90083
90085
90089
90090
90090
90091
90094
90096
90096
90098
90101
90102
90104
90104
90105
90106
90107
90108
98058
98059
98060
98062
98063
CAS Number Name
91-12-3 NAPTHALENE
METHYL I NDANS
METHYLDECALINS
METHYLDECALINS
HETHYLDECALINS
METHYLDECALINS
METHYLDECALINS
METHYLDECALINS
91-17-8 DECALINS
M-XYLENE AND P-XYLENE
METHYLHEXANE
METHYLHEXENES
METHYLNONANE
HETHYLDECANES
HETHYLUNDECANE
DIMETHYLCYCLOPENTANE
NONADIENE
DIMETHYLHEXANES
DIMETHYLOCTANES
DIMETHYLOCTANES
DIHETHYLUNDECANE
METHYLPROPYLCYCLOHEXANES
METHYL I SOPROPYLCYCLOHEXANE
ETHYLOCTENE
DIMETHYLNONANES
DIMETHYLNONANES
ETHYLOCTANE
ETHYLMETHYLCYCLOPENTANE
ETHYLHEXANE
ETHYLMETHYLCYCLOHEXANES
ETHYLMETHYLOCTANE
ETHYLD IMETHYLCYCLOHEXANE
ETHYLPROPYLCYCLOHEXANES
ETHYLPROPYLCYCLOHEXANES
TETRAMETHYLCYCL08UTENE
TRIMETHYLHEPTANES
TRIMETHYLOCTANES
TRIMETHYLOCTANES
TETRAMETHYLCYCLOPENTANE
1678-93-9 BUTYLCYCLOHEXANE
METHYLPROPYLNONANE
METHYLOCTANES
METHYLOCTANES
PROPENYLCYCLOHEXANE
METHYLNONENE
METHYLDECENE
METHYLDOOECANE
TRIMETHYLCYCLOPENTANE
D IMETHYLCYCLOHEXANE
3073-66-3 TRIMETHYLCYCLOHEXANES
D1ETHYLCYCLOHEXANE
N-PENTYLCYCLOHEXANE
Spec_MW
128.17
132.21
152.28
152.28
152.28
152.28
152.28
152.28
138.25
106.16
100.20
98.18
142.28
156.32
170.34
98.19
124.23
114.23
142.28
142.28
184.36
140.27
140.27
140.27
156.31
156.31
142.29
112.21
114.23
126.24
156.31
140.27
154.29
154.29
110.19
142.29
156.31
156.31
126.24
140.27
184.36
128.26
128.26
124.33
140.26
154.29
184.36
112.16
112.24
126.27
140.27
154.30
Spec_WT
0.03
0.00
0.02
0.00
0.00
0.00
0.00
0.01
0.06
0.23
1.27
0.12
0.75
0.45
0.03
0.71
0.02
0.33
0.18
0.12
0.00
0.20
0.06
0.04
0.15
0.06
0.02
0.01
0.05
0.69
0.07
0.01
0.00
0.06
0.00
0.22
0.05
0.00
0.07
0.16
0.03
0.26
0.47
0.02
0.03
0.08
0.02
0.36
0.11
0.24
0.08
0.05
Peak
(33)
(10)
(21)
(23)
(25)
(11)
(18)
(29)
(2 )
(4 )
(31)
(14)
(19)
(12)
(30)
(5 )
(20)
217
-------
VOC Profile Speciation Report - continued (profile 1195)
Saroad CAS Nunber Name Spec_MW Spec_UT Peak
98082 ETHYLHEPTENE 126.24 0.03
98091 DIHETHYLHEPTANES 128.26 0.02
TOTAL 100.01
218
-------
VOC Profile speciatIon Report
Profile Name D rye lean ing Composite
Profile Number 1196
Data Quality B
Control Device Uncontrolled
Reference(s)
Data Source
90,91
Composite profile developed from
Profile 1193 and
consumption data for solvent usage in drycleaning
industry.
SCC Assignments: 40100198
Saroad
43109
43110
43110
43110
43110
43111
43112
43124
43124
43125
43125
43125
43125
43135
43135
43135
43136
43138
43146
43146
43146
43146
43146
43146
43147
43147
43147
43150
43150
43150
43151
43151
43151
43151
43151
43151
43151
43153
43235
43261
CAS Number Name
ISOHERS OF DECANE
ISOMERS OF UNDECANE
ISOHERS OF UNDECANE
ISOHERS OF UNDECANE
ISOHERS OF UNDECANE
ISOHERS OF DODECANE
ISOHERS OF TR I DECANE
C9 OLEFINS
C9 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 PARAFFINS
C10 PARAFFINS
C10 PARAFFINS
C9 PARAFFIN
C-8 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
ISOHERS OF C10H18
ISOHERS OF C10H18
ISOHERS OF C10H18
ISOHERS OF C11H20
ISOHERS OF C11H20
ISOHERS OF C11H20
ISOHERS OF C11H20
ISOHERS OF C11H20
ISOHERS OF C11H20
ISOHERS OF C11H20
C10H16
111-84-2 NONANE
108-87-2 HETHYLCYCLOHEXANE
Spee_MW
142.28
156.30
156.30
156.30
156.30
170.32
184.36
126.24
126.24
140.27
140.27
140.27
140.27
142.28
142.28
142.28
128.25
112.23
154.29
154.29
154.29
154.29
154.29
154.29
168.32
168.32
168.32
138.25
138.25
138.25
152.28
152.28
152.28
152.28
152.28
152.28
152.28
136.24
128.25
98.21
Spec_WT
1.74
1.22
0.00
0.00
0.00
0.17
0.01
0.00
0.00
0.01
0.00
0.07
0.25
0.00
0.00
0.11
0.00
0.00
0.00
0.00
0.00
0.01
0.13
0.00
0.01
0.00
0.00
0.00
0.01
0.00
0.00
0.01
0.00
0.00
0.01
0.00
0.02
0.01
1.07
0.00
Peak
(14)
(19)
(24)
(3 )
(12)
(7 )
(5 )
(4 )
(6 )
(2 )
(1 >
(6 )
(16)
(20)
(18)
(17)
(25)
(26)
(5 )
(11)
(15)
(22)
(25)
(8 )
(9 )
(12)
(14)
219
-------
VOC Profile Speciaticn Report - continued (profile 1196)
Saroad
43288
43336
43397
43566
43567
43817
43821
45105
45105
45105
45105
45105
45105
45105
45105
45105
45107
45108
45108
45113
45202
45203
45204
45209
45210
45215
45238
45245
45303
45304
45304
45320
45801
45808
46202
46601
46602
46701
46748
46748
46753
46753
90010
90045
90047
90048
90049
90055
90066
90070
90071
90072
CAS Nunber
1678-91-7
127-18-4
76-13-1
25551-13-7
108-88-3
100-41-4
95-47-6
103-65-1
98-82-8
98-06-6
108-90-7
2531-22-6
2782-91-4
95-16-9
91-12-3
91-17-8
91-17-8
Name
ETHYLCYCLOHEXANE
OCTANOL
TRIHETHYLCYCLOHEXANOL
TRIHETHYLCYCLOPENTANONE
TETRAHETHYLPENTANONE
PERCKLOROETHYLENE
TR I CHLOROTR I FLUOROETHANE
I SOWERS OF BUTYLBENZENE
I SOWERS OF BUTYLBENZENE
I SOWERS OF BUTYLBENZENE
I SOWERS OF BUTYLBENZENE
1 SOWERS OF BUTYLBENZENE
I SOWERS OF BUTYLBENZENE
I SOWERS OF BUTYLBENZENE
I SOWERS OF BUTYLBENZENE
I SOWERS OF BUTYLBENZENE
TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
I SOWERS OF PROPYLBENZENE
C11H10
TOLUENE
ETHYLBENZENE
0-XYLENE
N-PROPYLBENZENE
CUHENE (ISOPROPYL BENZENE)
TERT-BUTYLBENZENE
ETHYLTOLUENE
C5-ALKYLBENZENES
C4-ALKYIPHENOLS
C5-ALKYLPHENOLS
C5-ALKYLPHENOLS
DIHETHYLBENZYLALCOHOL
CHLOROBENZENE
DICHLOROBENZENES
OCTAHYDROINDENES
TETRAMETHYLTHIOUREA
BENZOTHIAZOLE
NAPTHALENE
HETHYLDECALINS
HETHYLDECALINS
DECALINS
DECALINS
H-XYLENE AND P-XYLENE
METHYLHEPTANE
METHYLNONANE
HETHYLDECANES
HETHYLUNDECANE
PENTYLCYCLOHEXANE
NONADIENE
DIMETHYLOCTANES
DIMETHYLUNOECANE
HETHYLPROPYLCYCLOHEXANES
Spec_MU
112.23
130.26
142.24
126.20
142.24
165.83
187.38
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
120.19
120.19
120.19
142.20
92.13
106.16
106.16
120.19
120.20
134.21
120.19
148.24
150.22
164.25
164.25
136.19
112.56
147.01
244.00
132.25
135.19
128.17
152.28
152.28
138.25
138.25
106.16
114.23
142.28
156.32
170.34
154.29
124.23
142.28
184.36
140.27
Spec_UT
0.09
0.01
0.03
0.02
0.10
82.09
3.00
0.29
0.01
0.05
0.05
0.00
0.00
0.02
0.15
0.00
0.34
0.15
0.00
0.00
0.08
0.05
0.24
0.05
0.05
0.05
0.06
0.01
0.06
0.00
0.03
0.02
0.04
0.00
0.03
0.01
0.01
0.05
0.08
0.00
0.08
0.01
0.35
0.00
0.64
0.64
0.14
0.07
0.03
1.00
0.04
0.48
Peak
(3 )
(13)
(23)
(19)
(24)
(21)
(18)
(10)
(9 )
(6 )
(23)
(7 )
(26)
(27)
(10)
(27)
(22)
(20)
(4 )
220
-------
VOC Profile Speciation Report - continued (profile 1196)
Saroad CAS Number Name
Spec_HW Spec_WT Peak
90074
90076
90076
90076
90077
90081
90082
90083
90089
90090
90094
90094
90095
90096
90096
90097
90098
90101
90104
90105
90107
90109
90109
90110
90110
90111
90112
90113
90114
90118
90120
98059
98060
98060
98062
98091
98091
DIMETHYIDECANE
DIMETHYINONANES
DIMETHYLNONANES
DIMETHYLNONANES
ETHYLOCTANE
ETHYLHEXANE
ETHYLMETHYLHEXANE
ETHYLMETHYLCYCLOHEXANES
ETHYLD IHETHYLCYCLOHEXANE
ETHYLPROPYLCYCLOHEXANES
TRIMETHYLHEPTANES
TRIHETHYLHEPTANES
TRIMETHYLHEXENE
TRIHETHYLOCTANES
TRIMETHYLOCTANES
TRIHETHYLDECANE
TETRAMETHYLCYCLOPENTANE
1678-93-9 BUTYLCYCLOHEXAHE
HETHYLOCTANES
PROPENYLCYCLOHEXANE
METHYLDECENE
PROPYLHEPTENES
PROPYLHEPTENES
DIETHYLMETHYLCYCLOHEXANES
DIETHYLMETHYLCYCLOHEXANES
I SOPROPYLHETHYLCYCLOHEXANE
DIHETHYLOCTYNE
PENTYLIDENECYCLOHEXANE
D I METHYLBUTYLCYCLOHEXANE
OCTAHYDROPENTALENE
PROPYLCYCLOHEXANE
D IHETHYLCYCLOHEXANE
3073-66-3 TRIMETHYLCYCLOHEXANES
3073-66-3 TRIMETHYLCYCLOHEXANES
DIETHYLCYCLOHEXANE
DIMETHYLHEPTANES
DIMETHYLHEPTANES
170.34
156.31
156.31
156.31
142.29
114.23
128.26
126.24
140.27
154.29
142.29
142.29
126.24
156.31
156.31
184.36
126.24
140.27
128.26
124.33
154.29
140.27
140.27
111.20
111.20
140.27
138.25
152.00
168.32
225.20
126.24
112.24
126.27
126.27
140.27
128.26
128.26
0.04
0.09
0.21
0.09
0.03
0.05
0.01
0.66
0.15
0.08
0.55
0.35
0.05
0.00
0.05
0.00
0.08
0.26
0.23
0.12
0.10
0.05
0.03
0.04
0.04
0.07
0.01
0.03
0.01
0.01
0.33
0.07
0.26
0.04
0.07
0.07
0.01
(16)
(15)
(6 )
(13)
(11)
(8 )
(21)
(17)
(2 )
(1 )
TOTAL
100.00
221
-------
222
-------
3.19 SURFACE COATING OPERATIONS
Surface coating operations primarily involve the application of paint,
varnish/shellac, lacquer, enamel, or paint primer for surface decoration
and/or protection before products are marketed. Adhesives, as the name
implies, involve the application of a bonding agent for the purpose of
adhering materials together. A number of basic industrial coating operations
are utilized, including spraying, flowcoating, roller coating, dipping and
electro-coating. There are variations and combinations of these operations,
each designed for a special task. The coatings applied in these operations
vary widely as to composition and physical properties. In order to accelerate
the drying of the solvents used in the surface coatings, a drying or baking
operation is usually an integral part of the basic coating process.
223
-------
224
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Surface Coating - Varnish/Shellac
0127
Uncontrolled
59
Engineering evaluation of literature test data.
40200301, 40200310
Saroad
CAS Number
Name
Spec_HW Spec_WT Peak
43367
43551
43552
43560
111-46-6
67-64-1
78-93-3
108-10-1
GLYCOL ETHER
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
106.14
58.08
72.10
100.16
3.00
38.70
41.60
16.70
TOTAL
100.00
225
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Surface Coating Paint Solvent - Acetone
0219
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering Judgement; information based on composite
survey data and inspection of solvent information.
SCC Assignments: 40200902
Saroad
43551
TOTAL
CAS Number
67-64-1
Name
ACETONE
Spec_HW Spec_UT Peak
58.08 100.00
100.00
226
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Paint Solvent - Ethyl Acetate
0220
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent information.
SCC Assignments: 40200909
Saroad
43433
CAS Number
141-78-6
Name
ETHYl ACETATE
Spec_MU Spec_WT Peak
88.10 100.00
TOTAL
100.00
227
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
ReferenceCs)
Data Source
Paint Solvent - Methyl Ethyl Ketone
0221
E
None
59
Engineering judgement; information based on composite
survey data and inspection of solvent information.
SCC Assignments: 40200918
Saroad
43552
CAS Nunber
78-93-3
Name
METHYL ETHYL KETONE
Spec_MW Spec_UT Peak
72.10 100.00
TOTAL
100.00
228
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Surface Coating - Enamel Cellosolve Acetate
0222
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40200907
Saroad
43452
CAS Number
111-15-9
Name
CELLOSOLVE ACETATE
SpecJflJ Spec_WT Peak
132.16 100.00
100.00
TOTAL
229
-------
VCX: Profile Speciation Report
Profile Name
Profile Number
Data Quality
Surface Coating - Varnish/Shellac Solvent - Xylene
0223
Control Device Uncontrolled
ReferenceCs) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40200924
Saroad
45102
CAS Number
1330-20-7
Name
ISOWERS OF XYLENE
Spec_MU Spec_WT Peak
106.16 100.00
100.00
TOTAL
sssssss==========
230
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Surface Coating - Primer - Mineral Spirits
0225
B
Control Device
Reference(s)
Data Source
Uncontrolled
59
Engineering judgement, information based oncomposite
survey data, inspection of solvent formulation.
SCC Assignments: 40200920
Saroad
TOTAL
CAS Number
Name
Spec_HW Spec_WT Peak
43107
43108
43109
43110
I SOBERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
114.23
128.25
142.28
156.30
0.80
27.30
69.30
2.60
100.00
231
-------
VOC Profile Speciation Report
Profile Name
Profile Hunter
Data Quality
Surface Coating Solvent - Ethyl Alcohol
0226
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; calculations from composite
survey data and inspection of solvent formulation.
SCC Assignments: 40200910
Saroad
43302
TOTAL
CAS Number
64-17-5
Name
ETHYL ALCOHOL
Spec_MU Spec_WT Peak
46.07 100.00
100.00
232
-------
VOC Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Surface Coating Solvent - Isopropyl Alcohol
0227
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40200912
Saroad
43304
TOTAL
CAS Number
67-63-0
Name
ISO-PROPYL ALCOHOL
Spec_HW Spec_WT Peak
60.09 100.00
100.00
233
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Surface Coating Solvent - Isopropyl Acetate
0228
E
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40200913
Saroad
43444
TOTAL
CAS Number
108-21-4
Name
ISOPROPYL ACETATE
Spec_HW Spec_WT Peak
102.13 100.00
100.00
234
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Surface Coating Solvent - Lactol Spirits
0229
E
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40200915
Saroad
43119
TOTAL
CAS Number
Name
LACTOL SPIRITS
SpecJtU Spec_WT Peak
114.00 100.00
100.00
235
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Surface Coating Primer - Naptha
0282
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40200921
Saroad
45101
TOTAL
CAS Number
8030-30-6
Name
NAPHTHA
Spec_HW Spec_UT Peak
114.00 100.00
100.00
236
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Surface Coating Solvent - Butyl Acetate
0288
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40200903
Saroad
43435
CAS Number
138-22-7
Name
N-BUTYL ACETATE
SpecJW Spec_WT Peak
116.16 100.00
TOTAL
100.00
237
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Surface Coating Solvent - Butyl Alcohol
0289
E
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40200904
Saroad
43305
TOTAL
CAS Number
71-36-3
Name
N-BUTYL ALCOHOL
Spec_HW Spec_WT Peak
74.12 100.00
100.00
238
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Surface Coating Solvent - Cellosolve
0290
E
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40200906
Saroad
43311
TOTAL
CAS Number
110-80-5
Name
CELLOSOLVE
Spec_HW Spec_WT Peak
90.12 100.00
100.00
239
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Surface Coating Solvent - Methyl Alcohol
0291
Control Device Uncontrolled
ReferenceCs) 59
Data Source Engineering Judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40200917
Saroad
43301
TOTAL
CAS Number
67-56-1
Name
METHYL ALCOHOL
Spec_MW Spec_WT Peak
32.04 100.00
100.00
240
-------
VOC Profile Speciat ion Report
Profile Name
Profile Nunber
Data Quality
Surface Coating Solvent - Dimethylformamide
0292
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40200908
Saroad
43450
TOTAL
CAS Number
68-12-2
Name
DIMETHYL FORMAHIDE
Spec_HW Spec_WT Peak
73.09 100.00
100.00
241
-------
VOC Profile Speciation Report
Profile Name Surface Coating Operations - Coating Application -Solvent-base Paint
Profile Number 1003
Data Quality B
Control Device Uncontrolled
Reference(s)
Data Source
1
Composite
and 1018
of profiles 1017 (lacquer), 1019
(primer).
(enamel) in proportion to individual emission
totals for the South Coast Air Basin.
SCC Assignments: 40200101,
Saroad
43108
43232
43247
43248
43261
43277
43288
43308
43433
43435
43459
43551
43552
43560
43562
43563
45102
45104
45107
45202
45203
45204
98057
98058
98059
98060
98090
98091
CAS Number
142-82-5
108-08-7
110-82-7
108-87-2
1678-91-7
111-76-2
141-78-6
138-22-7
67-64-1
78-93-3
108-10-1
110-43-0
7379-12-6
1330-20-7
25551-13-7
108-88-3
100-41-4
95-47-6
1640-89-7
3073-66-3
TOTAL
==s-sss:====s-=-====r=-s -
40200110
Name
ISOMERS OF NONANE
HEPTANE
2,4-DIMETHYLPENTANE
CYCLOHEXANE
METHYLCYCLOHEXANE
2,4-DIMETHYLHEXANE
ETHYLCYCLOHEXANE
BUTYL CELLOSOLVE
ETHYL ACETATE
N-BUTYL ACETATE
C5 ESTER
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
METHYL AMYL KETONE
2-HETHYL-3-HEXANONE
ISOMERS OF XYLENE
ISOMERS OF ETHYLTOLUENE
TRIMETHYLBENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
ETHYLCYCLOPENTANE
TRIMETHYLCYCLOPENTANE
DIMETHYLCYCLOHEXANE
TRIMETHYLCYCLOHEXANES
METHYLHEPTENE
DIMETHYLHEPTANES
Spec_HU
128.25
100.20
100.20
84.16
98.21
114.22
112.23
118.17
88.10
116.16
130.19
58.08
72.10
100.16
114.21
114.19
106.16
120.19
120.19
92.13
106.16
106.16
98.19
112.16
112.24
126.27
112.22
128.26
sis SSSSSSSS-TS
Spec_WT Peak
2.79
2.94
1.70
0.52
3.61
7.20
1.43
6.48
2.04
9.50
1.26
1.27
0.54
0.36
0.83
3.75
3.70
0.20
0.11
37.87
0.54
4.47 '
0.22
0.17
4.01
1.66
0.15
0.67
99.99
242
-------
VOC Profile Speeiation Report
Profile Name
Profile Number
Data Quality
Surface Coating Operations - Coating Application - Water-Base Paint
1013
B
Control Device
Reference(s)
Data Source
Uncontrolled
1
Seven coatings with the largest emissions in California
representing four product types were combined in
proportion to 1980 California sales and the composite
was distilled. The organic and aqueous layers of the
distillate were analyzed by GC/MS.
SCC Assignments: 40200201, 40200210
Saroad
43110
43238
43241
43305
43312
43313
43318
43320
43370
43371
43372
43391
43453
43454
43457
43458
43562
43801
43802
43812
43835
43836
45201
98106
TOTAL
CAS Number
124-18-5
1120-21-4
71-36-3
112-34-5
104-76-7
123-42-2
107-21-1
107-41-5
142-96-1
108-05-4
112-39-0
109-87-5
110-43-0
74-87-3
75-09-2
75-00-3
78-86-4
71-43-2
Name
ISOMERS OF UNDECANE
N-DECANE
N-UNDECANE
N-BUTYL ALCOHOL
2 - ( 2 - BUTOX YETHOX Y ) - ETHANOL
1-ETHOXY-2-PROPANOL
2-ETHYL HEXANOL
DI ACETONE ALCOHOL
ETHYLENE GLYCOL
HEXYLENE GLYCOL
DIBUTYL ETHER
2-BUTYLTETRAHYDROFURAN
VINYL ACETATE
METHYL PALMITATE
METHYLAL
SUBSTITUTED C9 ESTER (C12)
METHYL AMYL KETONE
METHYL CHLORIDE
DICHLOROMETHANE
ETHYL CHLORIDE
1-CHLOROBUTANE
3- (CHLOROMETHYL ) -HEPTANE
BENZENE
ETHYLISOPROPYL ETHER
SpecJW
156.30
142.28
156.31
74.12
162.26
104.15
130.23
116.18
62.07
118.18
130.23
128.19
86.09
270.46
76.11
218.24
114.21
50.49
84.94
64.52
92.57
148.68
78.11
88.15
Spec_WT Peak
1.00
0.21
0.12
20.09
0.78
1.46
1.01
0.78
0.58
1.43
0.24
0.15
0.12
0.36
26.97
28.58
1.04
0.55
5.52
0.62 .
2.21
0.62
0.36
5.20
100.00
243
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Surface Coating Operations - Thinning Solvents - Composite
1016
B
Control Device Uncontrolled
Reference(s) 1
Data Source A composite sample was prepared based on sales volume
from nine commercially available solvents used with
architectural coatings. The composite was distilled
and the distillate analyzed by GC and GC/HS.
SCC Assignments: 40200901
Saroad
CAS Number
Name
Spec_HW Spec_WT Peak
43108
43109
43110
43125
43126
43127
43128
43129
43150
43232
43241
43261
43304
43435
43552
43570
43802
43837
45202
45203
45205
45206
45501
45502
45601
98062
98082
142-82-5
1120-21-4
108-87-2
67-63-0
138-22-7
78-93-3
75-09-2
106-93-4
108-88-3-
100-41-4
108-38-3
106-42-3
100-52-7
104-87-0
85-44-9
I SOWERS OF NONANE
ISOMERS OF DECANE
ISOHERS OF UNDECANE
C10 OLEFINS
C2 CYCLOHEXANE
C3 CYCLOHEXANE
C5 CYCLOHEXANE
C4 SUBSTITUTED CYCLOHEXANE
ISOHERS OF C10H18
HEPTANE
N-UNOECANE
METHYLCYCLOHEXANE
ISO-PROPYL ALCOHOL
N-BUTYL ACETATE
METHYL ETHYL KETONE
ALKENE KETONE
DICHLOROMETHANE
ETHYLENE D I BROMIDE
TOLUENE
ETHYLBENZENE
H-XYLENE
P-XYLENE
BENZALDEHYDE
P-TOLUALDEHYDE
PHTHALIC ANHYDRIDE
DIETHYLCYCLOHEXANE
ETHYLHEPTENE
128.25
142.28
156.30
140.27
112.22
126.24
154.30
140.27
138.25
100.20
156.31
98.21
60.09
116.16
72.10
72.10
84.94
187.88
92.13
106.16
106.16
106.16
106.13
120.16
148.12
140.27
126.24
5.24
6.47
1.63
7.18
2.89
1.99
0.91
2.89
4.45
3.07
2.51
6.72
4.91
9.27
4.06
1.99
1.22
0.91
15.22
0.93
1.65
1.07
0.76
1.05
0.76
7.96
2.26
TOTAL
99.97
244
-------
VOC Profile Special ion Report
Profile Name
Profile Number
Data Quality
Surface Coating Operations - Coating Application - Lacquer
1017
B
Control Device Uncontrolled
Reference(s) 1
Data Source Distillates of four lacquer samples attained from
surface coating facilities were combined in proportion
to the emission facility and analyzed by GC and GC/HS.
SCC Assignments: 40200401, 40200410
Saroad
TOTAL
CAS Number
Name
Spec_HW Spec_WT Peak
43108
43232
43261
43277
43288
43435
45102
45202
45204
98057
98058
98060
98090
142-82-5
108-87-2
1678-91-7
138-22-7
1330-20-7
108-88-3
95-47-6
1640-89-7
3073-66-3
ISOHERS OF NONANE
HEPTANE
METHYLCYCLOHEXANE
2,4-DIHETHYLHEXANE
ETHYLCYCLOHEXANE
N-BUTYL ACETATE
ISOHERS OF XYLENE
TOLUENE
0-XYLENE
ETHYLCYCLOPENTANE
TR I HETHYLCYCLOPENTANE
TR I HETHYLCYCLOHEXANES
METHYLHEPTENE
128.25
100.20
98.21
114.22
112.23
116.16
106.16
92.13
106.16
98.19
112.16
126.27
112.22
4.43
10.17
15.25
0.76
0.79
14.90
1.04
44.59
3.14
1.68
1.29
0.81
1.14
99.99
245
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
ReferenceCs)
Data Source
Surface Coating Operations Coating Application - Enamel
1018
B
Uncontrolled
1
Distillates of five enamel samples obtained from
coating facilities were combined in proportion to
facility emissions and analyzed by GC/MS. Four
samples from coating manufacturers were also combined
and analyzed. The two data sets were then averaged.
SCC Assignments: 40200501, 40200510
TOTAL
100.00
Saroad
43232
43248
43433
43435
43459
43551
43552
43560
43562
43563
45102
45104
45107
45202
45203
45204
CAS Number
142-82-5
110-82-7
141-78-6
138-22-7
67-64-1
78-93-3
108-10-1
110-43-0
7379-12-6
1330-20-7
25551-13-7
108-88-3
100-41-4
95-47-6
Name
HEPTANE
CYCLOHEXANE
ETHYL ACETATE
N- BUTYL ACETATE
C5 ESTER
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
METHYL AHYL KETONE
2-METHYL-3-HEXANONE
ISOHERS OF XYLENE
ISOMERS OF ETHYLTOLUENE
TRIMETHYLBENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
Spec_MW
100.20
84.16
88.10
116.16
130.19
58.08
72.10
100.16
114.21
114.19
106.16
120.19
120.19
92.13
106.16
106.16
Spec_WT Peak
1.56
2.27
8.96
9.41
5.51
5.57
2.36
1.57
3.62
16.44
11.56
0.88
0.50
15.90
2.36
11.53
246
-------
VOC Profile Special ion Report
Profile Name
Profile Number
Data Quality
Surface Coating Operations - Coating Application - Primer
1019
B
Control Device Uncontrolled
Reference(s) 1
Data Source Distillates of three primer samples from surface
coating facilities were combined (weighted according
to emissions from each facility) and analyzed by
GC/MS.
SCC Assignments: 40200601, 40200610
Saroad
CAS Number
Name
Spec_NW Spec_WT Peak
43108
43232
43247
43261
43277
43288
43308
43435
45102
45202
45204
98059
98060
98091
142-82-5
108-08-7
. 108-87-2
1678-91-7
111-76-2
138-22-7
1330-20-7
108-88-3
95-47-6
3073-66-3
ISOHERS OF NONANE
HEPTANE
2,4-DIMETHYLPENTANE
HETHYLCYCLOHEXANE
2,4-DIMETHYLHEXANE
ETHYLCYCLOHEXANE
BUTYL CELLOSOLVE
N-BUTYL ACETATE
ISOHERS OF XYLENE
TOLUENE
0-XYLENE
DIMETHYLCYCLOHEXANE
TRIMETHYLCYCLOHEXANES
DIHETHYLHEPTANES
128.25
100.20
100.20
98.21
114.22
112.23
118.17
116.16
106.16
92.13
106.16
112.24
126.27
128.26
3.45
1.94
2.66
2.50
11.09
2.08
10.13
8.42
1.45
44.31
2.23
6.26
2.43
1.04
TOTAL
99.99
247
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Surface Coating Operations - Coating Application - Adhesives
1020
B
Control Device Uncontrolled.
Reference(s) 1
Data Source Distillates of three adhesive samples from coating
facilities and a coating manufacturer were combined
(weighted according to emissions from each facility)
and analyzed by GC and GC/HS.
SCC Assignments: 40200706
Saroad
TOTAL
CAS Number
Name
SpecJtW Spec_WT Peak
43122
43231
43262
43322
43551
43552
43560
45202
110-54-3
96-37-7
110-63-4
67-64-1
78-93-3
108-10-1
108-88-3
I SOWERS OF PENTANE
KEXANE
METHYLCYCLOPENTANE
1,4 BUTANEDIOL
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
TOLUENE
72.15
86.17
84.16
90.12
58.08
72.10
100.16
92.13
56.04
0.90
3.22
11.17
13.28
11.17
0.80
3.42
100.00
248
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Surface Coating Operations - Thinning Solvent - Hexylene Glycol
1026
Control Device
Reference(s)
Data Source
SCC Assignments
Not reported
1
Engineering judgement.
40200927
Saroad
43371
CAS Number
107-41-5
Name
HEXYLENE GLYCOL
Spec_HU Spec_WT Peak
118.18 100.00
TOTAL
100.00
249
-------
VCX: Profile Speciation Report
Profile Name
Profile Nunber
Data Quality
Surface Coating Operations - Thinning Solvent - Ethylene Oxide
1031
E
Control Device
Reference(s)
Data Source
SCC Assignments
Not reported
1
Engineering judgement.
40200928
Saroad
43601
CAS Number
75-21-8
Name
ETHYLENE OXIDE
Spec_MW Spec_WT Peak
44.05 100.00
100.00
TOTAL
250
-------
VOC Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Surface Coating Operations - Adhesive Application
1088
C
Control Device Direct flame incinerator
Reference(s) 48
Data Source Volatile organics source test. Exhaust gases from one
laminating machine were allowed to enter the control
device. Three one-hour test runs were performed at the
inlet and outlet of the control device. Outlet
concentrations are shown here.
SCC Assignments: 40200701, 40200710
Saroad
TOTAL
CAS Number
Name
Spec_MW Spec_WT Peak
43232
43304
43433
43551
43552
43560
45202
142-82-5
67-63-0
141-78-6
67-64-1
78-93-3
108-10-1
108-88-3
HEPTANE
ISO-PROPYL ALCOHOL
ETHYL ACETATE
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
TOLUENE
100.20
60.09
88.10
58.08
72.10
100.16
92.13
36.50
6.10
13.30
14.20
5.30
4.30
20.30
100.00
251
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Citrus Coating
1187
D
Control Device Uncontrolled
Reference(s) 59
Data Source Composite profile developed from profiles 0293, 0294,
and 0295 from the 1980 VOC Data Manual.
SCC Assignments: 40299995, 40299996, 40299997, 40299998
Saroad
TOTAL
CAS Number
Name
Spec_MW Spec_WT Peak
43231
43248
45102
45104
45107
45108
45201
45202
45203
110-54-3
110-82-7
1330-20-7
25551-13-7
71-43-2
108-88-3
100-41-4
HEXANE
CYCLOHEXANE
ISOHERS OF XYLENE
ISOHERS OF ETHYLTOLUENE
TRIMETHYLBENZENE
ISOHERS OF PROPYLBENZENE
BENZENE
TOLUENE
ETHYLBENZENE
86.17
84.16
106.16
120.19
120.19
120.19
78.11
92.13
106.16
11.33
14.37
26.94
6.51
9.67
1.34
1.04
20.12
8.68
100.00
252
-------
VOC Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Autobody Repair
1194
B
Control Device
Reference(s)
Data Source
Uncontrolled
90
Twelve automotive after-market paint and thinner samples
of acrylic lacquer and alkyd enamel from three paint
manufacturers combined using market statistics.
Semivotatiles analyzed by GC/HS.
SCC Assignments:
Saroad
43107
43109
43110
43124
43124
43125
43125
43125
43146
43146
43146
43148
43151
43232
43235
43261
43273
43288
43294
43331
43335
43337
43410
43469
43472
43473
43474
43476
43477
43567
43568
45102
45102
45105
45105
45108
45108
45201
45202
CAS Number
142-82-5
111-84-2
108-87-2
110-83-8
1678-91-7
10143-23-4
112-34-5
57-10-3
124-17-4
1330-20-7
1330-20-7
71-43-2
108-88-3
Name
I SIXERS OF OCTANE
ISOMERS OF DECANE
ISOHERS OF UNDECANE
C9 OLEFINS
C9 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 OLEFINS
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
ISOMERS OF C9H16
ISOHERS OF C11H20
HEPTANE
NONANE
HETHYLCYCLOHEXANE
CYCLOHEXENE
ETHYLCYCLOHEXANE
C7 OLEFINS
DIMETHYLPENTANOL
METHOXYETHOXYETHANOL
BUTOXYETHOXYETHANOL
HEXADECANOIC ACID
BUTOXYETHOXYETHANOL ACETATE
BUTOXYBUTENE
ETHYLHEXANOATE
HETHYLMETHYLPROPENOATE
DIHETHYLHEXANEDIOATE
D IHETHYLPENTANED I OATE
TETRAMETHYLPENTANONE
NONENONE
ISOHERS OF XYLENE
ISOHERS OF XYLENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOHERS OF PROPYLBENZENE
ISOMERS OF PROPYLBENZENE
BENZENE
TOLUENE
SpecJW
114.23
142.28
156.30
126.24
126.24
140.27
140.27
140.27
154.29
154.29
154.29
124.23
152.28
100.20
128.25
98.21
82.14
112.23
98.18
116.20
120.15
162.23
256.48
220.26
128.21
144.24
100.13
174.20
160.17
142.24
140.22
106.16
106.16
134.22
134.22
120.19
120.19
78.11
92.13
Spec_WT
1.27
0.94
0.57
0.00
0.94
0.02
0.18
0.00
0.00
0.00
0.03
0.02
0.00
4.35
2.48
3.93
0.32
1.57
0.05
0.41
0.00
0.57
0.01
3.23
1.75
0.11
0.32
0.08
0.81
1.30
6.77
14.55
6.12
0.44
8.66
0.00
4.36
1.51
8.65
Peak
(3 )
(5 >
(4 )
(2 )
(7 )
(8 )
(10)
(10)
(1 )
(6 )
(1 )
(12)
(6 )
253
-------
VOC Profile Speciation Report - continued (profile 1194)
Saroad
45221
45226
45245
45245
45247
45404
45452
45470
45477
45601
46204
46701
46702
46702
46747
46747
46750
46753
90028
90047
90048
90048
90064
90070
90076
90076
90080
90081
90083
90104
90105
90115
90115
90117
90118
90121
90122
90128
98057
98058
98059
98060
CAS Nuifcer
25013-15-4
92-52-4
84-74-2
85-68-7
85-44-9
91-12-3
91-17-8
5989-27-5
1640-89-7
3073-66-3
Name
HETHYL STYRENE
BIPHENYL
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C6-ALKYLBENZENE
DIHETHYLETHYLBENZOIC ACID
D I BUTYL PHTHALATE
DI-C8 ALKYL PHTHALATE
BUTYLBENZYLPHTHALATE
PHTHALIC ANHYDRIDE
D I HYDROXYNAPTHALENED I ONE
NAPTHALENE
METHYL NAPHTHALENES
HETHYL NAPHTHALENES
HETHYLINDANS
HETHYL I NDANS
DIHETHYLINDANS
DECALINS
METHYLHEXANE
METHYLNONANE
HETHYLDECANES
HETHYLDECANES
DIHETHYLCYCLOPENTANE
DIMETHYLOCTANES
DIHETHYLMONANES
DIHETHYLMONANES
ETHYLMETHYLCYCLOPENTANE
ETHYLHEXANE
ETHYLHETHYLCYCLOHEXANES
HETHYLOCTANES
PROPENYLCYCLOHEXANE
TRIHETHYLHEXANES
TRIHETHYLHEXANES
LIHONENE
OCTAHYDROPENTALENE
HETHYLETHYLHEPTANE
TETRAMETHYLHEXANE
I SOPROPYLCYCLOHEXANE
ETHYLCYCLOPENTANE
TRIHETHYLCYCLOPENTANE
DIHETHYLCYCLOHEXANE
TRIHETHYLCYCLOHEXANES
SpecJW
118.19
154.21
148.24
148.24
162.27
178.23
278.35
390.56
312.39
148.12
160.17
128.17
142.20
142.20
132.21
132.21
146.23
138.25
100.20
142.28
156.32
156.32
98.19
142.28
156.31
156.31
112.21
114.23
126.24
128.26
124.33
128.26
128.26
136.24
225.20
142.22
142.28
126.25
98.19
112.16
112.24
126.27
Spee_WT
0.18
0.02
1.14
0.34
0.02
0.01
0.01
0.30
1.17
0.11
0.05
1.46
0.15
0.13
0.00
0.00
0.05
0.00
2.16
0.26
0.05
0.08
0.81
0.11
0.18
0.08
0.13
5.32
1.00
1.20
0.18
0.41
0.34
0.11
0.00
0.00
0.08
0.32
0.41
1.17
3.47
0.70
Peak
(11)
(12)
(11)
(9 )
(9 )
(8 )
(3 )
(7 )
.
(5 )
(4 )
(2 )
TOTAL
100.03
254
-------
3.20 STORAGE, TRANSPORTATION, AND MARKETING OF PETROLEUM PRODUCTS
The storage, transportation, and marketing of petroleum liquids involves
many distinct operations, each of which represents a potential source of VOC
evaporative loss. Petroleum liquids are transported or conveyed by tankers,
barges, tank cars, tank trucks, and pipelines. Refined fuels are delivered by
tank trucks to service stations, commercial accounts, and local bulk storage
plants. Emission sources include working and breathing storage losses, and
loading, transit, and refueling losses. Refueling losses include evaporative
emissions that occur from vapor displacement during vehicle refueling
operations.
255
-------
256
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Fixed Roof Tank - Commercial Jet Fuel (Jet A)
0100
Uncontrolled
65
Engineering evaluation of literature data.
40301013
Saroad
43232
43233
43235
43238
43241
43255
43258
43259
43260
CAS Number
142-82-5
111-65-9
111-84-2
124-18-5
1120-21-4
112-40-3
629-50-5
629-59-4
629-62-9
Name
HEPTANE
OCTANE
NONANE
N-DECANE
N-UNDECANE
N-DODECANE
N-TRIDECANE
N-TETRADECANE
N-PENTADECANE
Spec_HU
100.20
114.23
128.25
142.28
156.31
170.33
184.36
198.38
212.41
Spec_WT Peak
0.10
0.50
4.70
19.60
20.30
18.20
17.70
11.70
7.20
TOTAL
100.00
257
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Fixed Roof Tank - Crude Oil Production
0296
Control Device
Reference(s)
Data Source
SCC Assignments
Uncontrolled
59, 72
Engineering evaluation of test data and literature data
40301010, 40301011, 40301012, 40301109
Saroad
TOTAL
CAS Number
Name
Spec_MU Spec_UT Peak
43115
43116
43122
43201
43202
43204
43212
43214
43220
43231
43232
43233
45201
74-82-8
74-84-0
74-98-6
106-97-8
75-28-5
109-66-0
110-54-3
142-82-5
111-65-9
71-43-2
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
ISOHERS OF PENTANE
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
N-PENTANE
HEXANE
HEPTANE
OCTANE
BENZENE
98.19
112.23
72.15
16.04
30.07
44.09
58.12
58.12
72.15
86.17
100.20
114.23
78.11
1.30
0.50
1.50
6.20
5.60
17.60
27.10
1.50
14.60
7.90
9.20
6.90
0.10
100.00
SSSSSSS:2:: = := = ===:rS = = S =====:=SS = SSS==:==
258
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Fixed Roof Tank - Crude Oil Refinery
0297
Control Device
Reference(s)
Data Source
Uncontrolled
59, 72
Engineering evaluation of test data and literature
data.
SCC Assignments: 40400301, 40400302
Saroad
TOTAL
CAS Number
Name
Spec_MW Spec_UT Peak
43105
43106
43107
43122
43201
43202
43204
43212
43214
43220
43231
43232
45201
45202
74-82-8
74-84-0
74-98-6
106-97-8
75-28-5
109-66-0
110-54-3
142-82-5
71-43-2
108-88-3
ISOMERS OF HEXANE
1SOMERS OF HEPTANE
ISOHERS OF OCTANE
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
N- BUTANE
I SO- BUTANE
N-PENTANE
HEXANE
HEPTANE
BENZENE
TOLUENE
86.17
100.20
114.23
72.15
16.04
30.07
44.09
58.12
58.12
72.15
86.17
100.20
78.11
92.13
5.10
5.00
0.40
11.20
8.80
2.70
16.10
20.80
9.30
10.10
4.70
2.00
2.40
1.40
100.00
259
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Fixed Roof Tank - Crude Oil Marine Terminal
0305
C
Control Device
Reference(s)
Data Source
SCC Assignments
Uncontrolled
72
Engineering evaluation of literature data.
40600253
Saroad
TOTAL
CAS Number
Name
Spec_MW Spec_UT Peak
43201
43202
43204
43212
43220
43231
43232
43233
74-.82-S
74-84-0
74-98-6
106-97-8
109-66-0
110-54-3
142-82-5
111-65-9
METHANE
ETHANE
PROPANE
N-BUTANE
N-PENTANE
HEXANE
HEPTANE
OCTANE
16.04
30.07
44.09
58.12
72.15
86.17
100.20
114.23
2.60
3.70
15.80
30.20
18.50
8.80
10.80
9.60
100.00
260
-------
VOC Pro/ite Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Gasoline - Summer Blend
1014
B
Uncontrolled
1
A composite of four product 1
:ypes combined in
proportion to 1979 sales figures for California
was used to develop vapor samples which were
analyzed using a dual detector FID/PID GC.
SCC Assignments: 40301003, 40301006, 40301009, 40301103, 40301203, 40400103, 40400106, 40400109
40400112, 40400115, 40400120, 40400203, 40400206, 40400209, 40400213, 40400406
Saroad
43105
43106
43107
43108
43120
43122
43124
43125
43202
43204
43212
43214
43216
43217
43220
43223
43224
43225
43226
43227
43228
43230
43231
43232
43233
43242
43245
43247
43248
43250
43252
43261
43262
43270
43271
43278
43289
CAS Number
74-84-0
74-98-6
106-97-8
75-28-5
624-64-6
590-18-1
109-66-0
563-45-1
109-67-1
563-46-2
646-04-8
627-20-3
513-35-9
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
592-41-6
108-08-7
110-82-7
540-84-1
565-75-3
108-87-2
96-37-7
922-61-2
592-13-2
Name
ISOHERS OF HEXANE
ISOMERS OF HEPTANE
ISOHERS OF OCTANE
ISOHERS OF NONANE
ISOHERS OF BUTENE
ISOHERS OF PENTANE
C9 OLEFINS
C10 OLEFINS
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
T- 2- BUTENE
CIS-2-BUTENE
N- PENTANE
3-HETHYL-1-BUTENE
1-PENTENE
2-HETHYL-1 -BUTENE
TRANS- 2-PENTENE
CIS-2-PENTENE
2-HETHYL-2-BUTENE
3-HETHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
1-HEXENE
2,4-DIHETHYLPENTANE
CYCLOHEXANE
2,2,4-TRIHETHYLPENTANE
2,3,4-TRIHETHYLPENTANE
METHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
3-HETHYL-T-2-PENTENE
3,5,5-TRIHETHYLHEXANE
2,5-DIMETHYLHEXANE
C6 OLEFINS
Spec_HU
86.17
100.20
114.23
128.25
56.10
72.15
126.24
140.27
30.07
44.09
58.12
58.12
56.11
56.11
72.15
70.13
70.13
70.13
70.13
70.13
70.13
86.17
86.17
100.20
114.23
70.14
84.16
100.20
84.16
114.22
114.22
98.21
84.16
84.16
128.26
114.22
84.16
Spec_WT Peak
4.78
1.53
0.05
0.02
1.11
26.79
0.03
0.00
0.08
1.25
22.95
9.83
1.21
0.98
8.56
0.40
1.02
1.93
1.61
0.79
1.04
2.34
1.84
0.32
0.02
0.72
0.27
0.51
0.26
0.49
0.08
0.13
1.66
0.09
0.10
0.11
0.06
261
-------
VOC Profile Speciation Report - continued (profile 1014)
Saroad
43291
43292
43293
43294
43295
43298
43299
45102
45110
45201
45202
45203
45204
45207
45208
45211
45215
45218
45225
46712
98033
98034
98035
98054
TOTAL
CAS Number
75-83:2
142-29-0
27236-46-0
589-34-4
1330-20-7
71-43-2
108-88-3
100-41-4
95-47-6
108-67-8
95-63-6
611-14-3
' 98-06-6
141-93-5
526-73-8
95-13-6
40504-55-7
592-43-8
107-39-1
Name
2,2-DIHETHYLBUTANE
CYCLOPENTENE
4-HETHYL-T-2-PENTENE
C7 OLEFINS
3-HETHYLHEXANE
3-HETHYLHEPTANE
1-METHYLCYCLOHEXENE
ISOMERS OF XYLENE
CIO AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
1,3,5-TRIHETHYLBENZENE
1,2,4-TRIMETHYLBENZENE
0-ETHYLTOLUENE
TERT-BUTYLBENZENE
H-D I ETHYLBENZENE
1,2,3-TRlMETHYLBENZENE
INOEHE
2,2,5-TRIHETHYLHEXANE
T-2-HEXENE
C-2-HEXENE
2,4,4-TRIMETHYL-1-PENTENE
Spec_MU
86.17
68.11
84.18
98.18
100.20
114.23
96.17
106.16
134.22
78.11
92.13
106.16
106.16
120.19
120.19
120.19
134.21
134.22
120.19
116.16
128.26
84.16
84.16
112.22
Spec_WT Peak
1.23
0.25
0.25
0.06
0.49
0.07
0.05
0.15
0.01
0.77
0.66
0.04
0.05
0.02
0.06
0.05
0.00
0.00
0.05
0.01
0.02
0.30
0.42
0.02
99.99
262
-------
VOC Profile Special ion Report
Profile Name
Profile Number
Data Quality
Gasoline - Winter Blend
1015
B
Control Device
Reference(s)
Data Source
Uncontrolled
1
Four product types combined in proportion to 1979 sales
figures for California was used to develop vapor
samples that were analyzed using a dual detector
FID/PID GC.
SCC Assignments: 40301001, 40301004. 40301007, 40301101, 40301104, 40301201, 40400101, 40400104
40400107, 40400110, 40400113, 40400118, 40400201, 40400204, 40400207, 40400211
40400402
Saroad
CAS Number
Name
Spec_MW Spec_WT Peak
43105
43106
43107
43108
43109
43120
43122
43124
43138
43202
43204
43212
43214
43216
43217
43220
43223
43224
43225
43226
43227
43230
43231
43232
43233
43235
43238
43242
43245
43247
43248
43252
43261
43262
43265
43271
43278
74-84-0
74-98-6
106-97-8
75-28-5
624-64-6
590-18-1
109-66-0
563-45-1
109-67-1
563-46-2
646-04-8
627-20-3
96-14-0
110-54-3
142-82-5
111-65-9
111-84-2
124-18-5
287-92-3
592-41-6
108-08-7
110-82-7
565-75-3
108-87-2
96-37-7
111-66-0
592-13-2
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF BUTENE
ISOMERS OF PENTANE
C9 OLE FINS
C-8 OLEFINS
ETHANE
PROPANE
N- BUTANE
I SO- BUTANE
T-2-BUTENE
CIS-2-BUTENE
N-PENTANE
3-METHYL-1-BUTENE
1-PENTENE
2-METHYL-1-BUTENE
TRANS-2-PENTENE
CIS-2-PENTENE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
NONANE
N- DECANE
CYCLOPENTANE
1-HEXENE
2,4-DlHETHYLPENTANE
CYCLOHEXANE
2,3,4-TRIMETHYLPENTANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
OCTENE
3,5,5-TRIHETHYLHEXANE
2,5-DIMETHYLHEXANE
86.17
100.20
114.23
128.25
142.28
56.10
72.15
126.24
112.23
30.07
44.09
58.12
58.12
56.11
56.11
72.15
70.13
70.13
70.13
70.13
70.13
86.17
86.17
100.20
114.23
128.25
142.28
70.14
84.16
100.20
84.16
114.22
98.21
84.16
112.21
128.26
114.22
4.03
3.41
1.44
0.41
0.06
1.28
16.09
0.27
0.21
0.04
1.10
24.97
13.94
1.13
0.84
5.44
0.25
0.71
0.82
1.09
0.56
2.25
1.86
0.85
0.24
0.03
0.01
0.70
0.41
0.70
0.54
0.11
0.54
2.54
0.06
0.45
0.35
263
-------
VOC Profile Speciation Report - continued (profile 1015)
Saroad
43284
43289
43291
43292
43293
43294
43295
43298
43299
43820
45102
45109
45201
45202
45203
45204
45207
45208
45209
45210
45211
45212
45215
45218
45225
45801
46701
90013
98033
98034
98035
98040
98041
98044
98054
98056
CAS Nurfcer
625-27-4
75-83-2
142-29-0
27236-46-0
589-34-4
79-00-5
1330-20-7
71-43-2
108-88-3
100-41-4
95-47-6
108-67-8
95-63-6
103-65-1
98-82-8
611-14-3
620-14-4
98-06-6
141-93-5
526-73-8
108-90-7
91-12-3
40504-55-7
592-43-8
763-29-1
496-11-7
107-39-1
590-86-3
Name
2-METHYL-2-PENTENE
C6 OLEFINS
2,2-DIMETHYLBUTANE
CYCLOPENTENE
4-NETHYL-T-2-PENTENE
C7 OLEFINS
3-METHYLHEXANE
3-HETNYLHEPTANE
1-HETHYLCYCLOHEXENE
1 ,1 ,2-TRICHLOROETHANE
ISOMERS OF XYLENE
C3/C4/C5 ALKYLBENZENES
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
1 ,3,5-TRIMETHYLBENZENE
1 ,2,4-TRIHETHYLBENZENE
N-PROPYLBENZENE
CUHENE (ISOPROPYL BENZENE)
0-ETHYLTOLUENE
M-ETHYLTOLUENE
TERT-BUTYLBENZENE
H-DIETHYLBENZENE
1,2,3-TRIHETHYLBENZENE
CHLOROBENZENE
NAPTHALENE
C-2-OCTENE
2,2,5-TRIMETHYLHEXANE
T-2-HEXENE
C-2-HEXENE
2-HETHYL-1-PENTENE
3-HEPTENE
INDANE
2.4.4-TRIMETHYL-1-PENTENE
I SOVALER ALDEHYDE
Spec_HU
84.16
84.16
86.17
68.11
84.18
98.18
100.20
114.23
96.17
133.42
106.16
134.21
78.11
92.13
106.16
106.16
120.19
120.19
120.19
120.20
120.19
120.19
134.21
134.22
120.19
112.56
128.17
112.21
128.26
84.16
84.16
84.16
98.19
118.18
112.22
86.14
Spec_WT Peak
0.11
0.65
0.97
0.24
0.20
0.09
1.07
0.44
0.18
0.02
0.76
0.02
1.58
2.11
0.22
0.31
0.03
0.09
0.02
0.01
0.03
0.09
0.01
0.00
0.04
0.02
0.01
0.03
0.17
0.44
0.15
0.05
0.03
0.01
0.05
0.01
TOTAL
99.99
264
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Refueling
1100
C
Uncontrolled
54
Composite profile deve
oped using data from refueling
four cars fueled with unleaded/winter blend gasoline.
Data obtained by GC/FID are weighted according to
hydrocarbon emissions.
SCC Assignments: 40600401, 40600403
Saroad
43136
43211
43212
43213
43214
43215
43216
43217
43220
43221
43222
43223
43224
43226
43227
43228
43229
43230
43231
43232
43234
43235
43238
43242
43243
43245
43247
43250
43252
43261
43262
43263
43270
43272
43273
43274
43276
43277
43278
CAS Number
760-20-3
106-97-8
106-98-9
75-28-5
115-11-7
624-64-6
590-18-1
109-66-0
78-78-4
463-82-1
563-45-1
109-67-1
646-04-8
627-20-3
513-35-9
107-83-5
96-14-0
110-54-3
142-82-5
563-78-0
111-84-2
124-18-5
287-92-3
78-79-5
592-41-6
108-08-7
540-84-1
565-75-3
108-87-2
96-37-7
591-76-4
922-61-2
693-89-0
110-83-8
565-59-3
79-29-8
592-13-2
Name
C9 PARAFFIN
3-METHYL-1-PENTENE
N- BUTANE
BUTENE
ISO- BUTANE
ISOBUTYLENE
T-2- BUTENE
CIS-2-BUTENE
N-PENTANE
ISO PENTANE
2,2 DIMETHYLPROPANE
3-METHYL-1-BUTENE
1-PENTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-METHYL-2-BUTENE
2-METHYLPENTANE
3-HETHYL PENTANE
HEXANE
HEPTANE
2,3 DIHETHYL-1 -BUTENE
NONANE
N-DECANE
CYCLOPENTANE
ISOPRENE
1-HEXENE
2,4-DIHETHYLPENTANE
2,2,4-TRIHETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
METHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
2-METHYL HEXANE
3-METHYL-T-2-PENTENE
METHYLCYCLOPENTENE
CYCLOHEXENE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
2,4-DIMETHYLHEXANE
2,5-DIMETHYLHEXANE
Spec_MU
128.25
84.16
58.12
56.10
58.12
56.10
56.11
56.11
, 72.15
72.15
72.17
70.13
70.13
70.13
70.13
70.13
86.17
86.17
86.17
100.20
84.16
128.25
142.28
70.14
68.12
84.16
100.20
114.22
114.22
98.21
84.16
100.20
84.16
82.14
82.14
100.20
86.17
114.22
114.22
Spec_UT
0.00
0.00
32.63
2.69
14.45
0.00
3.19
2.07
6.66
15.83
0.00
0.37
0.64
1.36
0.68
1.61
2.26
1.16
0.90
0.35
0.00
0.04
0.03
0.47
0.02
0.23
0.28
0.37
0.06
0.14
0.85
0.00
0.00
0.17
0.53
0.00
0.62
0.12
0.00
Peak
(17)
( 5)
( D
( 1)
( 2)
{ 3)
( 2)
( 4)
( 6)
( 8)
( 6)
( 5)
( 7)
( 9)
(10)
( 9)
(10)
(10)
(11)
(11)
265
-------
VOC Profile Speciation Report - continued (profile 1100)
Saroad CAS Number Name
Spec_MW Spec_UT Peak
43279
43280
43281
43282
43283
43284
43285
43286
43289
43290
43291
43292
43295
43296
43297
43298
43299
45110
45201
45202
45203
45204
45205
45206
45207
45208
45209
45217
45225
90002
90004
90005
90006
98033
98044
99911
99912
99916
99917
99918
99999
760-21-4
107-00-6
503-17-3
625-27-4
75-83-2
142-29-0
589-34-4
592-27-8
589-53-7
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
106-42-3
108-67-8
95-63-6
103-65-1
135-01-3
526-73-8
496-11-7
2-ETHYL-1-BUTENE
2,3,3 TRIMETHYLPENTANE
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-METHYL-2-PENTENE
2-HEXENE
DIMETHYLHEXENE
C6 OLEFINS
2,3 DIMETHYLHEXANE
2,2-DIMETHYLBUTANE
CYCLOPENTENE
3-HETHYLHEXANE
2-METHYLHEPTANE
4-METHYLHEPTANE
3-METHYLHEPTANE
1-METHYLCYCLOHEXENE
C10 AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
1 ,3,5-TRIHETHYLBENZENE
1 ,2,4-TRIMETHYLBENZENE
N-PROPYLBENZENE
1,2 D I ETHYLBENZENE
1 ,2,3-TRIMETHYLBENZENE
2,3,5-TRIMETHYLHEXANE
3,5 DIMETHYLHEPTANE
2,5 DIHETHYLHEPTANE
2,3 DIMETHYLHEPTANE
2,2,5-TRIHETHYLHEXANE
INDANE
3,4 DIMETHYLOCTANE
1 -HETHYL-3-ETHYLBENZENE
1 -HETHYL-3N-PROPYLBENZENE
1 -METHYL-3- ISOPROPYLBENZENE
2-HETHYLDECANE
UNIDENTIFIED
84.16
114.22
54.09
54.09
84.16
84.16
84.16
112.20
84.16
114.22
86.17
68.11
100.20
114.23
114.23
114.23
96.17
134.22
78.11
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.19
134.22
120.19
128.25
128.26
128.26
128.26
128.26
118.18
142.29
120.19
134.22
134.22
156.32
86.00
0.00
0.10
0.00
0.00
0.00
0.36
0.13
0.02
0.18
0.00
0.42
0.19
0.38
0.03
0.06
0.04
0.00
0.11
1.00
1.03
0.28
0.15
0.00
0.29
0.21
0.15
0.02
0.01
0.06
0.01
0.04
0.00
0.00
0.16
0.01
0.08
0.11
0.02
0.08
0.05
3.44
( 7)
( 3)
( 4)
( 8)
(12)
(13)
(13)
(12)
(15)
(17)
(16)
(16)
(14)
(14)
(15)
TOTAL
100.00
266
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Gasoline Marketed
1190
B
Control Device
Reference(s)
Data Source
Uncontrolled
90
Fourteen samples of leaded, unleaded and unleaded pre-
mium grades from five oil companies composite based on
1984 national sales data. Headspace analyzed by GC/HS.
Profile represents summer blend gasoline from one
bulk terminal distribution region.
SCC Assignments:
Saroad
43105
43109
43110
43110
43111
43111
43113
43115
43124
43124
43124
43124
43125
43125
43135
43135
43135
43136
43138
43138
43141
43142
43143
43144
43145
43146
43146
43146
43148
43148
43148
43149
43213
43214
43215
43231
43232
43242
CAS Number Name
I SIXERS OF HEXANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
ISOMERS OF UNDECANE
ISOMERS OF DODECANE
ISOMERS OF DODECANE
ISOMERS OF TETRADECANE
C-7 CYCLOPARAFFINS
C9 OLEFINS
C9 OLEFINS
C9 OLEFINS
C9 OLEFINS
C10 OLEFINS
C10 OLEFINS
C10 PARAFFINS
C10 PARAFFINS
C10 PARAFFINS
C9 PARAFFIN
C-8 OLEFINS
C-8 OLEFINS
C8 PARAFFIN
C7 PARAFFINS
C5 OLEFIN
C5 PARAFFIN
C5 PARAFFIN/OLEFIN
C11 OLEFINS
C11 OLEFINS
C11 OLEFINS
ISOMERS OF C9H16
ISOMERS OF C9H16
ISOMERS OF C9H16
C8H14
106-98-9 BUTENE
75-28-5 ISO-BUTANE
115-11-7 ISOBUTYLENE
110-54-3 HEXANE
142-82-5 HEPTANE
287-92-3 CYCLOPENTANE
Spec_MU
86.17
142.28
156.30
156.30
170.32
170.32
198.38
98.19
126.24
126.24
126.24
126.24
140.27
140.27
142.28
142.28
142.28
128.25
112.23
112.23
114.23
100.20
70.13
72.15
70.13
154.29
154.29
154.29
124.23
124.23
124.23
110.20
56.10
58.12
56.10
86.17
100.20
70.14
Spec_WT
0.10
0.10
0.00
0.09
0.05
0.00
0.02
0.05
0.01
0.00
0.08
0.01
0.00
0.04
0.00
0.00
0.00
0.48
0.21
0.00
3.84
0.04
1.91
2.09
1.08
0.00
0.04
0.01
0.00
0.02
0.00
0.00
0.14
2.65
0.14
3.91
1.84
0.16
Peak
(12)
(15)
(7 )
(10)
(6 )
(11)
(8 )
(18)
(4 )
(2 )
(13)
(12)
(7 )
(5 )
(6 )
267
-------
VOC Profile Speciation Report - continued (profile 1190)
Saroad
43261
43262
43264
43272
43273
43288
43292
43395
43565
45105
45105
45106
45107
45108
45111
45112
45112
45201
45202
45203
45204
45209
45210
45220
45221
45238
45243
45244
45245
45245
45245
45245
45245
45245
45245
45246
45247
45247
45247
45247
45247
45247
45248
45248
45248
45248
45249
45501
45801
46115
46701
46702
CAS Nunber
108-87-2
96-37-7
693-89-0
110-83-8
1678-91-7
142-29-0
25551-13-7
71-43-2
108-88-3
100-41-4
95-47-6
103-65-1
98-82-8
100-42-5
25013-15-4
100-52-7
108-90-7
91-12-3
Name
METHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
HEPTENE
HETHYLCYCLOPENTENE
CYCLOHEXENE
ETHYLCYCLOHEXANE
CYCLOPENTENE
C7H120
DIHETHYLCYCLOBUTANOME
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOHERS OF DIETHYLBENZENE
TRIHETHYLBENZENE
ISOMERS OF PROPYLBENZENE
C10H12
ISOHERS OF C10H10
ISOHERS OF C10H10
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
N- PROPYLBENZENE
CUMENE (ISOPROPYL BENZENE)
STYRENE
HETHYL STYRENE
ETHYLTOLUENE
ETHYLOIHETHYLBENZENE
TETRAHETHYLBENZENE
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES (UNSAT.)
C6-ALKYLBENZENE
C6-ALKYLBENZENE
C6-ALKYLBENZENE
C6-ALKYLBENZENE
C6-ALKYLBENZENE
C6-ALKYLBENZENE
C4-ALKYLSTYRENES
C4-ALKYLSTYRENES
C4-ALKYLSTYRENES
C4-ALKYLSTYRENES
C7-ALKYLBENZENE
BENZALDEHYDE
CHLOROBENZENE
DIHETHYLNAPHTHYRIDINE
NAPTHALENE
HETHYL NAPHTHALENES
Spec_MU
98.21
84.16
98.18
82.14
82.14
112.23
68.11
112.17
98.14
134.22
134.22
134.21
120.19
120.19
132.22
130.19
130.19
78.11
92.13
106.16
106.16
120.19
120.20
104.14
118.19
120.19
134.22
134.22
148.24
148.24
148.24
148.24
148.24
148.24
148.24
146.25
162.27
162.27
162.27
162.27
162.27
162.27
160.26
160.26
160.26
160.26
176.30
106.13
112.56
158.20
128.17
142.20
Spec_WT
0.21
0.68
0.03
0.45
0.04
0.08
0.18
0.04
0.05
3.18
0.03
0.02
4.29
0.76
0.04
0.00
0.00
3.25
15.22
4.07
6.41
0.92
0.33
0.17
0.05
3.61
1.24
1.03
0.35
0.04
0.83
0.09
0.02
0.05
0.05
0.05
0.00
0.00
0.02
0.06
0.00
0.03
0.04
0.00
0.01
0.02
0.00
0.00
0.03
0.01
0.80
0.64
Peak
(13)
(9 )
(17)
(16)
(18)
(20)
(14)
(17)
(24)
(22)
(24)
(21)
(26)
(23)
(23)
(26)
(25)
(25)
(21)
268
-------
VOC Profile Speciation Report - continued (profile 1190)
Saroad
46746
46747
46747
46747
46749
46750
46750
46750
46751
46752
46754
46755
90010
90023
90024
90025
90025
90026
90027
90028
90029
90029
90039
90041
90043
90044
90045
90046
90047
90048
90054
90056
90058
90059
90060
90061
90062
90063
90064
90065
90065
90067
90067
90068
90069
90070
90070
90071
90074
90078
90079
90080
CAS Hunter Name
C2-ALKYLNAPHTHAIENE
METHYL I NDANS
METHYL I NDANS
METHYLINDANS
METHYLDIHYDRONAPHTHALENE
DIMETHYLINOANS
DIMETHYL I NDANS
DIMETHYLINDANS
DIHYDRONAPTHALENE
DIMETHYLINDENE
ETHYLINDAN
TRIMETHYLINDAN
M-XYLENE AND P-XYLENE
METHYLBUTENE
METHYLBUTADIENE
METHYLPENTENES
METHYLPENTENES
METHYLPENTANE
METHYLCYCLOPENTADIENE
METHYLHEXANE
METHYLHEXENES
METHYLHEXENES
METHYLHEXADIENE
4313-57-9 METHYLCYCLOHEXADIENE
HETHYLHEXANAL
HETHYLHEPTYNE
METHYLHEPTANE
METHYLCYCLOHEXENE
METHYLNONANE
HETHYLDECANES
PENTENYNE
HEXENE
142-83-6 HEXADIENAL
5910-85-9 HEPTADIENAL
79-29-8 OIMETHYLBUTANE
DIMETHYLBUTENE
DIMETHYLPENTANE
DIMETHYLPENTENE
DIMETHYLCYCLOPENTANE
DIMETHYLCYCLOPENTENES
D I HETHYLCYCLOPENTENES
DIHETHYLHEXANES
DIMETHYLHEXANES
DIHETHYLHEXADIENE
DIMETHYLETHYLCYCLOHEXANE
DIMETHYLOCTANES
DIMETHYLOCTANES
DIHETHYLUNDECANE
DIHETHYLDECANE
ETHYLPENTENE
ETHYLCYCLOPENTENE
ETHYLMETHYLCYCLOPENTANE
t
269
Spec_MW
156.23
132.21
132.21
132.21
144.22
146.23
146.23
146.23
130.19
144.22
146.23
160.26
106.16
70.13
68.12
84.16
84.16
86.17
80.14
100.20
98.18
98.18
96.17
94.15
114.19
110.20
114.23
96.17
142.28
156.32
66.10
84.16
96.14
110.17
86.18
84.16
100.20
98.19
98.19
96.17
96.17
114.23
114.23
110.20
140.26
142.28
142.28
184.36
170.34
98.19
96.17
112.21
Spec_WT
0.10
0.52
0.01
0.00
0.01
0.42
0.00
0.00
0.06
0.01
0.04
0.06
15.28
0.06
0.01
0.41
0.48
1.76
0.04
1.68
0.00
0.03
0.25
0.02
0.92
0.02
0.35
0.14
0.21
0.12
0.03
0.40
0.03
0.02 .
2.29
0.30
0.36
0.02
0.15
0.22
0.09
0.48
0.28
0.10
0.09
0.04
0.02
0.00
0.07
0.03
0.06
0.12
Peak
(15)
(16)
(22)
(20)
(19)
(1 )
(3 )
(3 )
(2 )
(8 )
(11)
(14)
(19)
-------
VOC Profile Speciation Report - continued (profile 1190)
Saroad
90081
90082
90083
90083
90084
90085
90086
90087
90091
90092
90093
90094
90094
90095
90096
90097
90099
90100
90103
90104
98044
98058
98059
98060
98091
99999
TOTAL
CAS Number Name
ETHYLHEXANE
ETHYLMETHYLHEXANE
ETHYLMETHYLCYCLOHEXANES
ETHYLMETHYLCYCLOHEXANES
ETHYLHEPTANE
ETHYLMETHYLOCTANE
ETHYLBICYCLOHEPTANE
ETHYLDIHETHYLPENTANE
TETRAMETHYLCYCLOBUTENE
TRIMETHYLPEHTANE
TRIMETHYLPENTADIENE
TRIHETHYLHEPTANES
TRIMETHYLHEPTANES
TRIHETHYLHEXENE
TRIMETHYLOCTANES
TRIMETHYLDECANE
OCTATRIENE
NONENE
PENTAD I ENE
METHYLOCTANES
496-11-7 INDANE
TRIMETHYLCYCLOPENTANE
DIHETHYLCYCLOHEXANE
3073-66-3 TRIMETHYLCYCLOHEXANES
DIMETHYLHEPTANES
UNIDENTIFIED
SpeC_MU
114.23
128.26
126.24
126.24
128.26
156.31
223.42
128.26
110.19
114.22
110.20
142.29
142.29
126.24
156.31
184.36
108.19
126.24
68.13
128.26
118.18
112.16
112.24
126.27
128.26
86.00
Spec_WT
0.24
0.21
0.04
0.02
0.02
0.02
0.01
0.13
0.04
0.68
0.05
0.09
0.05
0.04
0.07
0.03
0.01
0.03
0.04
0.55
0.44
0.09
0.10
0.02
0.16
0.00
100.02
SSBSSSSBBS:
Peak
(4 )
(5 )
(10)
(9 )
(1 )
270
-------
3.21 PRINTING/PUBLISHING PROCESSES
Printing may be performed on coated and uncoated paper as well as other
surfaces such as metals and fabric. Printing always involves the application
of ink by a printing press. Typical printing processes include application of
a relatively high solvent content material to the surface of a moving web or
film, rapid solvent evaporation by movement of heated air across the wet
surface, and solvent-laden air exhausted from the system.
271
-------
272
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Printing Press - Letterpress Inking Process
0166
Control Device Catalytic afterburner
Reference(s) 59
Data Source Information based on composite survey data and GC/HS
analysis of sampling train catch.
SCC Assignments: 40500201, 40500211
Saroad
TOTAL
CAS Number
Name
SpecJtW Spec_WT Peak
43201
43202
43204
43212
74-82-8
74-84-0
74-98-6
106-97-8
METHANE
ETHANE
PROPANE
N-BUTANE
16.04
30.07
44.09
58.12
63.00
24.00
12.00
1.00
100.00
273
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Printing Press - Gravure General Solvent
0182
C
Control Device Uncontrolled
Reference(s) 59
Data Source Information based on composite survey data and engi-
neering evaluation of literature data.
SCC Assignments: 40500501, 40500511, 40500512
SBroad
TOTAL
CAS Number
Name
Spec_HW Spec_WT Peak
43118
43248
43301
43304
43305
43435
45106
45203
64475-85-0
110-82-7
67-56-1
67-63-0
71-36-3
138-22-7
100-41-4
MINERAL SPIRITS
CYCLOHEXANE
METHYL ALCOHOL
ISO-PROPYL ALCOHOL
N- BUTYL ALCOHOL
N- BUTYL ACETATE
ISOMERS OF DIETHYLBENZENE
ETHYLBENZENE
114.00
84.16
32.04
60.09
74.12
116.16
134.21
106.16
51.00
10.00
6.00
6.00
6.00
8.00
7.00
6.00
100.00
274
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Printing Press - Gravure Printing Solvent
0183
D
Control Device Uncontrolled
Reference(s) 60
Data Source Information based on calculations from composite survey
data.
SCC Assignments: 40500513
Saroad
43118
45102
45202
CAS Number
64475-85-0
1330-20-7
108-88-3
Name
MINERAL SPIRITS
ISOMERS OF XYLENE
TOLUENE
Spec_MW
114.00
106.16
92.13
Spec_WT
83.00
4.00
13.00
Peak
TOTAL
100.00
275
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Printing Press - Lithography Inking and Drying
0332
Control Device
Reference(s)
Data Source
Thermal afterburner
59
Information based on composite survey data and GC/HS
analysis of sampling train catch.
SCC Assignments: 40500401, 40500411
Saroad
TOTAL
CAS Number
Name
Spec_HW Spec_WT Peak
43201
43203
43205
43213
43224
43502
74-82-8
74-85-1
115-07-1
106-98-9
109-67-1
50-00-0
METHANE
ETHYLENE
PROPENE
BUTENE
1-PENTENE
FORMALDEHYDE
16.04
28.05
42.08
56.10
70.13
30.03
17.10
2.00
33.60
13.60
11.90
21.80
100.00
276
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Lithography - Inking and Drying-Direct Fired Dryer
0333
D
Control Device
Reference(s)
Data Source
Uncontrolled
59
Information based on composite survey data and GC/HS
analysis of sampling train catch.
SCC Assignments:
Saroad
CAS Number
Name
Spec_MW Spec_WT Peak
43201
43202
43204
43212
43214
43304
43802
74-82-8
74-84-0
74-98-6
106-97-8
75-28-5
67-63-0
75-09-2
METHANE
ETHANE
PROPANE
N- BUTANE
I SO- BUTANE
ISO-PROPYL ALCOHOL
DICHLOROMETHANE
16.04
30.07
44.09
58.12
58.12
60.09
84.94
37.66
9.99
3.30
11.49
1.80
0.90
34.87
TOTAL
100.01
277
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Printing/Publishing - Ink Thinning Solvents - Methyl Isobutyl Ketone
1022
Control Device
Reference(s)
Data Source
SCO Assignments
Uncontrolled
1
Engineering judgement.
40500507
Saroad
43560
TOTAL
CAS Number
108-10-1
Name
METHYL ISOBUTYL KETONE
Spec_MW Spec_WT Peak
100.16 100.00
100.00
278
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Printing/Flexographic
1086
C
Control Device
Reference(s)
Data Source
Not reported
19,32
Composite profile developed using data from volatile
organic source tests at two facilities.
SCC Assignments: 40500301, 40500311, 40500312
Saroad
43551
43552
43560
45202
TOTAL
CAS Number
67-64-1
78-93-3
108-10-1
108-88-3
=====================
Name
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
TOLUENE
Spec_MW
58.08
72.10
100.16
92.13
===========:
Spec_UT
24.47
54.27
14.78
6.48
100.00
Peak
279
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Graphic Arts - (Printing)
1191
B
Uncontrolled
90
Distri Hates from five samples of lithographic, roto-
gravure, flexographic, and letter press
inks from four
printing companies composite based on 1978 emissions
data. Semivolatiles analyzed by GC/MS.
SCC Assignments: 40588801
Saroad CAS Number Name
43114
43125
43155
43156
43248
43273
43332
43333
43334
43335
43434
43444
43474
43475
45304
45330
45402
45452
45456
45706
45731
90030
90049
90071
90077
90096
90097
90125
90126
90127
90130
ISOHERS OF PENTADECANE
CIO OLEFINS
ISOHERS OF HEPTADECANE
ISOHERS OF OCTAOECANE
110-82-7 CYCLOHEXANE
110-83-8 CYCLOHEXENE
106-21-8 DIHETHYLOCTANOL
DIHETHYLHEPTANOL
HETHYLHEPTANOL
METHOXYETHOXYETHANOL
109-60-4 N-PROPYL ACETATE
108-21-4 ISOPROPYL ACETATE
HETHYLHETHYLPROPENOATE
HETHYLETHYLPENTANOATE
C5-ALKYLPHENOLS
90-43-7 BIPHENYLOL
65-85-0 BENZOIC ACID
84-74-2 DIBUTYL PHTHALATE
BUTYLISOPROPYLPHTHALATE
N-PHENYLANILINE
58-84-9 TOLUENE DI1SOCYANATE
544-76-3 HEXADECANE
METHYLUNDECANE
DIMETHYLUNDECANE
ETHYLOCTANE
TRIHETHYLOCTANES
TRIHETHYLDECANE
629-94-7 HENEICOSANE
112-95-8 EICOSANE
NONADECANE
87-44-5 CARYOPHYLLENE
Spec_MW
212.41
140.27
240.47
254.50
84.16
82.14
158.32
144.26
130.26
120.15
102.15
102.13
100.13
144.22
164.25
170.22
122.13
278.35
264.32
169.24
174.17
226.45
170.34
184.36
142.29
156.31
184.36
296.59
282.56
268.53
204.36
Spec_WT Peak
0.15
0.18
3.69
1.69
4.57
0.22
0.06
0.04
0.07
0.04
27.44
30.10
0.03
0.03
0.18
0.07
0.02
9.99
12.76
0.04
0.03 '
3.32
1.70
0.25
0.44
0.81
0.30
0.30
0.48
0.89
0.11
TOTAL
100.00
280
-------
3.22 ORGANIC CHEMICAL STORAGE
Five basic storage vessel designs are used for organic chemical storage:
fixed roof, external floating roof, internal floating roof, variable vapor
space, and pressure. Typically, organic liquids in the chemical industry are
composed of pure chemicals or mixtures of chemicals with similar true vapor
pressures. Sources of emissions from organic chemicals in storage include:
fixed roof breathing losses, fixed roof working losses, floating roof standing
storage losses, floating roof withdrawal losses, variable vapor space filling
losses, and pressure tank losses.
281
-------
282
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Fixed Roof Tank - Hexane
0230
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of stored product formula-
tion.
SCC Assignments: 40717603, 40717604
Saroad
43231
TOTAL
CAS Number
110-54-3
Name
HEXANE
Spec.MW Spec_UT Peak
86.17 100.00
100.00
283
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Fixed Roof Tank Cyclohexane
0299
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of stored product content.
SCC Assignments: 40717601, 40717602
Saroad
43248
CAS Number
110-82-7
Name
CYCLOHEXANE
SpecJW Spec_WT Peak
84.16 100.00
100.00
TOTAL
284
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Fixed Roof Tank - Heptane
0301
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of stored product formulatio
SCC Assignments: 40701605, 40701606
Saroad
43232
TOTAL
CAS Number
142-82-5
Name
HEPTANE
Spec_MU Spec_WT Peak
100.20 100.00
100.00
285
-------
VCX: Profile Special ion Report
Profile Name
Profile number
Data Quality
Printing Press - Fleicographic, n-Propyl Alcohol
0304
Control Device Uncontrolled
Reference(s) 59
Data Source Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC Assignments: 40700817, 40700818
Saroad
43303
CAS Number
71-23-8
Name
N-PROPYL ALCOHOL
Spec_HW Spec_UT Peak
60.10 100.00
TOTAL
100.00
SS=!SS=S======5= ===
286
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organic Chemical Storage - Methylamyl Ketone
1055
Control Device
Reference(s)
Data Source
SCC Assignments
Not reported
1
Engineering judgement.
40706813, 40706814
Saroad
43562
CAS Number
110-43-0
Name
METHYL AHYL KETONE
SpecJW Spec_WT Peak
114.21 100.00
100.00
TOTAL
287
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organic Chemical Storage - N-Propyl Acetate
1069
Control Device
Reference(s)
Data Source
SCC Assignments
Not reported
1
Engineering judgement.
40704421. 40704422
Saroad
43434
TOTAL
CAS Number
109-60-4
Name
N-PROPYL ACETATE
Spec_HW Spec_WT Peak
102.15 100.00
100.00
288
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organic Chemical Storage - i-Butyl, i-Butyrate
1087
Control Device
Reference(s)
Data Source
SCC Assignments
Not reported
1
Engineering judgement.
40704423, 40704424
Saroad
43451
TOTAL
CAS Number
297-85-8
Name
ISOBUTYL ISOBUTYRATE
Spec_HW Spec_WT Peak
144.21 100.00
100.00
289
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
1-PENTENE
1103
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40782009
Saroad
43224
TOTAL
CAS Number
109-67-1
Name
1-PENTENE
Spec_HU Spec_WT Peak
70.13 100.00
100.00
290
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
ACETALDEHYDE
1104
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40781201
Saroad
43503
CAS Number
75-07-0
Name
ACETALDEHYDE
Spec_HW Spec_WT Peak
44.05 100.00
TOTAL
100.00
291
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
ACETIC ACID
1105
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40704001, 40704002
Saroad
43404
TOTAL
CAS Number
64-19-7
Name
ACETIC ACID
Spec_HW Spec_WT Peak
60.05 100.00
100.00
292
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
ACETIC ANHYDRIDE
1106
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40700401, 40700402
Saroad
43604
TOTAL
CAS Number
108-24-7
Name
ACETIC ANHYDRIDE
Spec_MW Spec_WT Peak
102.09 100.00
100.00
293
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
ACROLEIN
1107
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40781202
Saroad
43505
TOTAL
CAS Number
107-02-8
Name
ACROLEIN
SpecJIU Spec_WT Peak
56.07 100.00
100.00
-5^=
294
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CA!
43407
TOTAL
ACRYLIC ACID
1108
E
Controlled/Uncontrolled
76
Engineering judgement.
40704003. 40704004
5 Number Name Spec_MW Spec_WT Peak
79-10-7 ACRYLIC ACID 72.06 100.00
100.00
295
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
ACRYLONITRILE
1109
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40707601, 40707602
Saroad
43704
TOTAL
CAS Number
107-13-1
Name
ACRYLONITRILE
Spec_HW Spec_WT Peak
53.06 100.00
100.00
296
-------
VOC Profile Sped at ion Report
Profile Name
Profile Number
Data Quality
ADIPIC ACID
1110
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40704005
Saroad
43409
CAS Number
124-04-9
Name
ADIPIC ACID
SpecJW Spec_WT Peak
146.14 100.00
TOTAL
100.00
297
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
ANILINE
1111
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40703201, 40703202
Saroad
45701
TOTAL
CAS Number
62-53-3
Name
ANILINE
Spec_HW Spec_UT Peak
93.13 100.00
100.00
298
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CAS
45810 1
TOTAL
BENZYL CHLORIDE
1112
E
Control Led/Uncontrol led
76
Engineering judgement.
40706001, 40706002
> Number Name . Spec_HW Spec_WT Peak
00-44-7 BENZYL CHLORIDE 126.59 100.00
100.00
299
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CAS
43440 1
BUTYL ACRYLATE
1114
E
Control led/Uncontrol led
76
Engineering judgement.
40704403, 40704404
» Number Name Spec_HW Spec_WT Peak
41-32-2 BUTYL ACRYLATE 128.17 100.00
TOTAL
100.00
300
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
BUTYL CARBITOL
1115
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40705201, 40705202
Saroad
43379
CAS Number
112-34-5
Name
BUTYL CARBITOL
Spec_MU Spec_WT Peak
162.23 100.00
TOTAL
==:====
100.00
301
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
BUTYL CELLOSOLVE
1116
Control Device
Referenced >
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40705203. 40705204
Saroad
43308
CAS Number
111-76-2
Name
BUTYL CELLOSOLVE
Spec_HU Spec_WT Peak
118.17 100.00
100.00
TOTAL
SSSSSSS
302
-------
Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CA!
43377 1
TOTAL
CARBITOL
1118
Control led/Uncontrol led
76
Engineering judgement.
40200905, 40500302, 40705205, 40705206
> Number Name Spec_MU Spec_UT Peak
11-90-0 CARBITOL 134.18 100.00
100.00
:=== ==========S====S=:KSS==:=======:SSS=:=S:SSSSS=SSSSS===========
303
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
CARBON TETRACHLORIDE
1119
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering Judgement
40706005, 40706006, 40722001, 40722002
Saroad
43804
CAS Number
56-23-5
Name
CARBON TETRACHLORIDE
Spec_MU Spec_WT Peak
153.84 100.00
100.00
TOTAL
ssssssr
304
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
CHLOROFORM
1121
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40722003, 40722004
Saroad
43803
CAS Number
67-66-3
Name
CHLOROFORM
Spec_MW Spec_WT Peak
119.39 100.00
100.00
TOTAL
305
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
CRESOL
1122
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40703603, 40703604
Saroad
45605
TOTAL
CAS Number
1319-77-3
Name
CRESOL
Spec_HU Spec_UT Peak
108.14 100.00
100.00
306
-------
VOC Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
CUMENE
1123
Control Device
Reference(s)
Data Source
Controlled/Uncontrolled
76
Engineering judgement.
SCC Assignments 40703605, 40703606
Saroad
45210
TOTAL
CAS Number Name
98-82-8 CUMENE CISOPROPYL BENZENE)
Spec_HW Spec_WT Peak
120.20 100.00
100.00
307
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
CYCLOHEXANOL
1124
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40700807, 40700808
Saroad
43317
CAS Number
108-93-0
Name
CYCLOHEXANOL
Spec_MW Spec_WT Peak
100.16 100.00
100.00
TOTAL
308
-------
VOC Profile Special ion Report
Profile Name
Profile Number
Data Quality
CYCLOHEXANONE
1125
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40706801, 40706802
Saroad
43561
CAS Number
108-94-1
Name
CYCLOHEXANONE
Spec_HW Spec_WT Peak
98.15 100.00
100.00
TOTAL
309
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CA!
43292 1
CYCLOPENTENE
1126
E
Control led/Uncontrol led
76
Engineering judgement.
40782011
i Number Name Spec_HW Spec_WT Peak
42-29-0 CYCLOPENTENE 68.11 100.00
TOTAL
100.00
310
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
DIETHYLENE GLYCOL
1127
Control Device
Referenced )
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40705209, 40705210
Saroad
43373
TOTAL
CAS Number
111-46-6
Name
DIETHYLENE GLYCOL
Spec_HW Spec_WT Peak
106.12 100.00
100.00
311
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CA!
45236
TOTAL
DIISOPROPYL BENZENE
1128
E
Control led/Uncontrol led
76
Engineering judgement.
40703607, 40703608
5 Number Name Spec_HW SpecJJT Peak
DIISOPROPYL BENZENE 162.28 100.00
100.00
312
-------
VOC Profile Specfation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CA<
43374
TOTAL
D1PROPYLENE GLYCOL
1129
E
Control led/Uncontrol led
76
Engineering judgement.
40705605, 40705606
3 Number Name Spec_HU Spec_UT Peak
I06-62-7 DIPROPYLENE GLYCOL 134.18 100.00
100.00
313
-------
VOC Profile Speeiation Report
Profile Name
Profile Number
Data Quality
DODECENE
1130
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40702001, 40702002
Saroad
90001
CAS Number
112-41-4
Name
DODECENE
Spec_HW Spec_WT Peak
168.32 100.00
TOTAL
s==ss
100.00
sr============
314
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CAS
43863 1
TOTAL
EPICHLOROHYDRIN
1131
E
Cont roll ed/Uncont ro 1 1 ed
76
Engineering judgement.
40706013, 40706014
Number Name Spec_MU Spec_WT Peak
06-89-8 EPICHLOROHYDRIN 92.53 100.00
100.00
315
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
ETHANOLAMNES
1132
Control Device
Reference(s)
Data Source
SCC Assignments
Control led/Uncontrol led
76
Engineering judgement.
40703203, 40703204
Saroad
43777
TOTAL
CAS Number
141-43-5
Name
ETHAHOLAMINE
SpecJW Spec_UT Peak
61.08 100.00
100.00
316
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
ETHYL ACRYLATE
1134
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40704407, 40704408
Saroad
43438
TOTAL
CAS Number
140-88-5
Name
ETHYL ACRYLATE
Spec_MU Spec_UT Peak
100.11 100.00
100.00
317
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
ETHYL BENZENE
1135
Control Device
Reference(s)
Data Source
SCC Assignments
Control led/llncontrol led
76
Engineering judgement.
40703609. 40703610
Saroad
45203
TOTAL
CAS Number
100-41-4
Name
ETHYLBENZENE
Spec_HU Spec_UT Peak
106.16 100.00
100.00
318
-------
VOC Profile Speciation Report
Profile Name
Profile Nunber
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CAi
43351
TOTAL
ETHYL ETHER
1136
E
Cont ro 1 1 ed/Uncont ro 1 1 ed
76
Engineering judgement.
40720801, 40720802
» Number Name Spec_MW Spec_WT Peak
60-29-7 ETHYL ETHER 74.12 100.00
100.00
:============================r===============================r===-------
319
-------
VOC Profile Speciation Report
Profile Name
Profile Hunter
Data Quality
ETHYL NERCAPTAN
1137
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrol led
76
Engineering Judgement.
40723201, 40723202
Saroad
43902
TOTAL
CAS Number
75-08-1
Name
ETHYL MERCAPTAH
Spec_MU Spee_WT Peak
62.13 100.00
100.00
320
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
ETHYLENE DIBROMIDE
1138
Control Device
Reference(s)
Data Source
SCC Assignments
Cont ro11ed/Uncont ro11ed
76
Engineering judgement.
40706015, 40706016
Saroad
43837
CAS Number
106-93-4
Name
ETHYLENE DIBROMIDE
Spec_HW Spec_WT Peak
187.88 100.00
TOTAL
100.00
321
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
ETHYLENEAMINES
1139
Control Device
Referenee(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40703205, 40703206
Saroad
43778
TOTAL
CAS Number
Name
ETHYLENEAHINES
Spec_HW Spec_UT Peak
45.08 100.00
100.00
322
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
FORMALDEHYDE
1140
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40717207, 40717208
Saroad
43502
TOTAL
CAS Number
50-00-0
Name
FORMALDEHYDE
Spec_MW SpecJJT Peak
30.03 100.00
100.00
323
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
FORMIC ACID
1141
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40704007, 40704008
Saroad
43403
TOTAL
CAS Number
64-18-6
Name
FORMIC ACID
Spec_HU Spec_UT Peak
46.03 100.00
100.00
324
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
HEPTENES
1144
E
Control Device
Reference(s)
Data Source
SCC Assignments
Control led/Uncontrolled
76
Engineering judgement.
40702003, 40702004
Saroad
43264
CAS Number
Name
HEPTENE
SpecJW Spec_WT Peak
98.18 100.00
100.00
TOTAL
325
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
ISOBUTYRLDEHYDE
1145
Controlled/Uncontrolled
76
Engineering judgement.
40717209, 40717210
Saroad
43511
TOTAL
CAS Number
78-84-2
Name
ISOBUTYRALDEHYDE
Spec_HU Spec_WT Peak
72.11 100.00
100.00
326
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CA!
43468
TOTAL
ISOBUTYL ACRYLATE
1146
E
Controlled/Uncontrolled
76
Engineering judgement.
40704409, 40704410
> Number Name Spec_MU Spec_WT Peak
06-63-8 ISOBUTYL ACRYLATE 128.19 100.00
100.00
327
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
ISOBUTYL ALCOHOL
1147
Control Device
Reference(s)
Data Source
SCC Assignments
Controlted/Uncontrolled
76
Engineering judgement.
40700811, 40700812
Saroad
43306
TOTAL
CAS Number
78-83-1
Name
ISOBUTYL ALCOHOL
Spec_HU Spec_WT Peak
74.12 100.00
100.00
328
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
ISOPRENE
1148
E
Control Device
Reference(s)
Data Source
SCC Assignments
Control led/Uncontrolled
76
Engineering judgement.
40782007
Saroad
43243
TOTAL
CAS Number
78-79-5
Name
ISOPRENE
Spec_HU Spec_UT Peak
68.12 100.00
100.00
329
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
METHYL ACETATE
1150
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40200916, 40704413, 40704414
Saroad
43432
CAS Number
79-20-9
Name
HETHYLACETATE
Spec_MU SpecJJT Peak
74.08 100.00
TOTAL
100.00
330
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
METHYL ACRYLATE
1151
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40704415, 40704416
Saroad
43437
CAS Number
96-33-3
Name
METHYL ACRYLATE
Spec_MW Spec_UT Peak
86.09 100.00
100.00
TOTAL
331
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CAS
43378 1
TOTAL
METHYL CARBITOL
1152
E
Control led/Uncontrolled
76
Engineering judgement.
40705211, 40705212
> Number Name Spec_MU SpecJJT Peak
11-77-3 METHYL CARBITOL 120.15 100.00
100.00
332
-------
VCX; Profile Speciation Report
Profile Name
Profile Number
Data Quality
METHYL CELLOSOLVE
1153
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40705213, 40705214
Saroad
43310
CAS Number
109-86-4
Name
METHYL CELLOSOLVE
Spec_MW Spec_WT Peak
76.11 100.00
100.00
TOTAL
333
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
METHYL STYRENE
1154
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40703611, 40703612
Saroad
45221
CAS Number
25013-15-4
Name
METHYL STYRENE
Spec_MW Spec_WT Peak
118.19 100.00
100.00
TOTAL
334
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
METHYLAUENE
1155
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40782008
Saroad
90011
TOTAL
CAS Number
Name
METHYLALLENE
Spec_HW Spec_WT Peak
54.09 100.00
100.00
335
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
METHYL t-BUTYL ETHER
1158
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40704801, 40704802
Saroad
43376
CAS Number
628-28-4
Name
METHYL T-BUTYL ETHER
Spec_MU Spec_WT Peak
88.15 100.00
100.00
TOTAL
336
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
M-XYLENE
1159
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40703617, 40703618
Saroad
45205
TOTAL
CAS Number
108-38-3
Name
M-XYLENE
Spec_MW SpecJJT Peak
106.16 100.00
100.00
==============================================
337
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
NITROBENZENE
1160
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40708001, 40708002
Saroad
«5702
TOTAL
CAS Number
98-95-3
Name
NITROBENZENE
Spec_HU SpecJJT Peak
123.11 100.00
100.00
===::=:::===================
338
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
N-BUTRALDEHYDE
1162
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40717205. 40717206
Saroad
43510
CAS Number
123-72-8
Name
BUTYRALDEHYDE
Spec_HU Spec_WT Peak
72.12 100.00
100.00
TOTAL
339
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
N-DECANE
1163
Control Device
Reference(s)
Data Source
SCO Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40701601, 40701602
Saroad
43238
TOTAL
CAS Number
124-18-5
Name
N-DECANE
Spec_MU SpecJJT Peak
142.28 100.00
100.00
340
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
N-DOOECANE
1164
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40701603, 40701604
Saroad
43111
TOTAL
CAS Number
Name
1SOMERS OF DOOECANE
Spec_MU Spec_WT Peak
170.32 100.00
100.00
341
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
0-XYLENE
1165
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40703619, 40703620
Saroad
45204
TOTAL
CAS Number
95-47-6
Name
0-XYLENE
Spec_HU Spec_WT Peak
106.16 100.00
100.00
342
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
PENTADECANE
1166
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40701609, 40701610
Saroad
43114
TOTAL
CAS Number
Name
ISOMERS OF PENTADECANE
Specjftl Spec_WT Peak
212.41 100.00
100.00
343
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
PIPERYLENE
1168
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40782010
Saroad
45750
CAS Number
504-60-9
Name
PIPERYLENE
Spec_MU Spec_UT Peak
68.12 100.00
100.00
TOTAL
344
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
PROPIONALDEHYDE
1171
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40717211, 40717212
Saroad
43504
CAS Number
123-38-6
Name
PROPIONALDEHYDE
Spec_HW Spec_WT Peak
58.08 100.00
100.00
TOTAL
==============
345
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CAS
43405
TOTAL
ssssssrnrssrrsi
PROP I ON 1C ACID
1172
E
Control led/Uncontrol led
76
Engineering judgement.
40704009, 40704010
> Number Name Spec_MU Spec_UT Peak
79-09-4 PROPIONIC ACID 74.08 100.00
100.00
346
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Saroad CAS
43602
PROPYLENE OXIDE
1173
E
Control led/Uncontrolled
76
Engineering judgement.
40720803, 40720804
> Number Name SpecJW Spec_WT Peak
75-56-9 PROPYLENE OXIDE 58.08 100.00
TOTAL
100.00
347
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
P-XYLENE
1174
Control Device
ReferenceCs)
Data Source
SCC Assignments
Controlled/Uncontrol led
76
Engineering judgement.
40703621, 40703622
Saroad
45206
CAS Number
106-42-3
Name
P-XYLENE
Spec_MU Spec_UT Peak
106.16 100.00
100.00
TOTAL
348
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
TERT- BUTYL ALCOHOL
1175
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement.
40700805, 40700806
Saroad
43309
CAS Number
75-65-0
Name
TERT-BUTYL ALCOHOL
SpecJW Spec_WT Peak
74.12 100.00
100.00
TOTAL
349
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
TOLUENE DIISOCYANATE
1176
E
Control led/Uncontrolled
76
Engineering Judgement
40706403, 40706404
Saroad
45731
TOTAL
CAS Nunfcer
58-84-9
Name
TOLUENE DIISOCYANATE
Spec_HU SpecJJT Peak
174.17 100.00
100.00
350
-------
VOC Profile Speciatfon Report
Profile Name
Profile Number
Data Quality
Isooctane
1197
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgement
40300113
Saroad
43250
TOTAL
CAS Number
540-84-1
Name
2,2,4-TRIHETHYLPENTANE
Spec_HU Spec_UT Peak
114.22 100.00
100.00
351
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Pentane
1198
E
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrol led
76
Engineering judgement.
40300115
Saroad
43220
TOTAL
CAS Number
109-66-0
Name
N-PENTANE
Spec_HU Spec_WT Peak
72.15 100.00
100.00
352
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Isopentane
1199
Control Device
Reference(s)
Data Source
SCC Assignments
Controlled/Uncontrolled
76
Engineering judgment
40300114
Saroad
43221
TOTAL
CAS Number
78-78-4
Name
ISO PENTANE
Spec_HW Spec_WT Peak
72.15 100.00
100.00
353
-------
VOC Profile Spec!ation Report
Profile Name
Profile Nunber
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Cyclopentane
1200
Controlled/Uncontrolled
76
Engineering judgement
40300210
Saroad
43242
TOTAL
CAS Number
287-92-3
Name
CYCLOPENTANE
Spec_HU SpecJJT Peak
70.14 100.00
100.00
354
-------
3.23 RAILCAR, TANK TRUCK, AND DRUM CLEANING
Rail tank cars, tank trucks, and drums are used to transport about
700 different commodities. Rail tank cars and most tank trucks and drums are
in dedicated service (carrying one commodity only) and, unless contaminated,
are cleaned only prior to repair or testing. Cleaning agents include steam,
water, detergents, and solvents which are applied using steam hoses, pressure
wands, or rotatory spray heads. Vapors from cleaning which are not flared or
dissolved in water are emitted to the atmosphere.
355
-------
356
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Railcar Cleaning - Lou Vapor Pressure, High Viscosity Cargo (Ethylene Glycol)
1078
Control Device Not reported
Reference(s) 55
Data Source Information based on measurement from one emission
source.
SCC Assignments: 49000301
Saroad
43370
TOTAL
CAS Number
107-21-1
Name
ETHYLENE GLYCOL
Spec_MW Spec_WT Peak
62.07 100.00
100.00
357
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Rail Car Cleaning - Lou Vapor Pressure, Hedium Viscosity Cargo
-------
voc Profile sped at Ion Report
Profile Name
Profile Number
Data Quality
Rail Car Cleaning - Low Vapor Pressure, High Viscosity Cargo (Creosote)
1080
Control Device Not reported
Reference(s) 55
Data Source Information based on measurement from one emission
source.
SCC Assignments: 49000304
Saroad
46210
TOTAL
CAS Number
8001-58-9
Name
CREOSOTE
SpecJW Spec_WT
130.19 100.00
100.00
Peak
359
-------
VOC Profile Specialion Report
Profile Name
Profile Number
Data Quality
Tank Truck Cleaning - Medina Vapor Pressure, Medium Viscosity Cargo (Methyl Hethacryl
1081
Control Device Not repbrted
Reference(s) 55
Data Source Information based on measurement from one emission
source.
SCC Assignments: 49000403
Saroad
43441
CAS Number
80-62-6
Name
METHYL METHACRYLATE
Spec_HU Spec_WT Peak
100.13 100.00
TOTAL
100.00
360
-------
VOC Profile Specfation Report
Profile Name
Profile Number
Data Quality
Tank Truck Cleaning - Low Vapor Pressure. Low Viscosity Cargo (Phenol)
1082
Control Device Not reported
Reference(s) 55
Data Source Information based on measurement from one emission
source.
SCC Assignments: 49000404
Saroad
45300
TOTAL
CAS Number
108-95-2
Name
PHENOL
Spec_MW
94.11
Spec_WT Peak
100.00
inn nn
361
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Tank Truck Cleaning - Low Vapor Pressure, High Viscosity Cargo (Propylene Glycol)
1083
D
Control Device Not reported
Reference(s) 55
Data Source Information based on measurement from one emission
source.
SCC Assignments: 49000405
Saroad
43369
CAS Number
57-55-6
Name
PROPYLENE GLYCOL
Spec_MW Spec_UT Peak
76.11 100.00
100.00
TOTAL
=3ss================================
362
-------
3.24 SOLID WASTE DISPOSAL
Solid waste sources can be industrial, urban, agricultural, or construction.
Solid waste may be disposed of in landfills or land application units or
incinerated. A large percentage of urban and industrial waste is burned.
Waste burning processes include open burning and controlled and uncontrolled
incineration where significant particulate emissions may be generated.
363
-------
364
-------
VOC Profile Special ion Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Open Burning Dump - Landscape/Pruning
0121
C
Uncontrolled
60
Calculations from composite survey data and engineering
evaluation of literature data.
SCC Assignments: 50100202
Saroad
TOTAL
CAS Number
Name
SpecJW Spec_WT Peak
43121
43203
43204
43206
43212
43213
43214
43220
43224
43231
43232
43233
74-85-1
74-98-6
74-86-2
106-97-8
106-98-9
75-28-5
109-66-0
109-67-1
110-54-3
142-82-5
111-65-9
ISOHERS OF PENTENE
ETHYLENE
PROPANE
ACETYLENE
N-BUTANE
BUTENE
ISO- BUTANE
N-PENTANE
1 -PENTENE
HEXANE
HEPTANE
OCTANE
70.13
28.05
44.09
26.04
58.12
56.10
58.12
72.15
70.13
86.17
100.20
114.23
11.80
19.40
1.90
1.90
1.90
5.90
1.90
1.90
11.80
13.90
13.90
13.80
100.00
365
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Bar Screen Waste Incinerator
0122
D
Control Device Uncontrolled
Reference(s) 59
Data Source Calculations from composite survey data and GC/MS
analysis of grab sample.
SCC Assignments: 50100101, 50100102
Saroad
CAS Number
Name
Spec_HW Spec_WT Peak
43201
43202
43203
43205
45201
TOTAL
74-82-8
74-84-0
74-85-1
115-07-1
71-43-2
METHANE
ETHANE
ETHYLENE
PROPENE
BENZENE
16.04
30.07
28.05
42.08
78.11
80.40
2.70
8.70
0.50
7.70
100.00
366
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Solid Waste Landfill Site Class II
0202
C
Control Device Uncontrolled
Reference(s) 59
Data Source Information based on composite survey data and GC/HS
analysis of grab samples.
SCC Assignments: 50200602
Saroad
TOTAL
CAS Number
Name
Spec_MU Spec_WT Peak
43123
43201
43202
43204
43212
43214
43220
43242
43817
45102
45202
74-82-8
74-84-0
74-98-6
106-97-8
75-28-5
109-66-0
287-92-3
127-18-4
1330-20-7
108-88-3
TERPENES
METHANE
ETHANE
PROPANE
N- BUTANE
ISO-BUTANE
N-PENTANE
CYCLOPENTANE
PERCHLOROETHYLENE
ISOHERS OF XYLENE
TOLUENE
136.23
16.04
30.07
44.09
58.12
58.12
72.15
70.14
165.83
106.16
92.13
0.10
98.70
0.10
0.10
0.20
0.10
0.10
0.10
0.30
0.10
0.10
100.00
367
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Solid Waste - Animal Waste Decomposition
0203
C
Control Device
Reference(s)
Data Source
Uncontrolled
59, 67, 68, 69, 70
Information based on composite survey data and engi-
neering evaluation of literature data.
SCC Assignments:
Saroad
CAS Number
.Name
Spec_HU Spec_UT Peak
43201
43202
43302
43304
43434
43551
43721
43740
TOTAL
74-82-8
74-84-0
64-17-5
67-63-0
109-60-4
67-64-1
75-05-7
75-50-3
METHANE
ETHANE
ETHYL ALCOHOL
ISO-PROPYL ALCOHOL
N-PROPYL ACETATE
ACETONE
ETHYLAHINE
TRIHETHYLAHINE
16.04
30.07
46.07
60.09
102.15
58.08
45.09
59.11
70.00
20.00
2.00
2.00
2.00
2.00
1.00
1.00
100.00
368
-------
3.25 WOOD COMBUSTION
Wood is burned in industrial/commercial boilers to obtain heat energy and to
alleviate waste disposal problems in the pulp and paper industries.
Residential wood burning is commonly used to supplement conventional heating
systems. In the industrial sector, the burning of wood waste in boilers is
mostly confined to those industries where wood is available as a by-product.
A variety of boiler configurations is used for burning wood waste. These
include dutch oven configurations, spreader stokers, and tangentially-fired or
cyclone-fired boilers. Residential wood stoves are usually radiating or
circulatory designs constructed from cast iron, heavy gauge sheet metal, or
stainless steel. Emissions from wood combustion are affected by furnace
design and operating conditions, and fuel characteristics such as fuel
composition, moisture content, and effective burning surface area.
369
-------
370
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Residential Wood Combustion (C-1 - c-6>
1084
D
Control Device
Reference(s)
Data Source
Catalyst
15
Five samples were taken into a preevacuated 3-liter
glass bulb. Four test runs were with a catalyst in
use, one when it was not. Samples were analyzed using
a combination of mass spectrometry and trace gas
chromatographic techniques. (See also profile 1167).
SCC Assignments:
Saroad
TOTAL
CAS Number
Name
Spec_MW Spec_WT Peak
43201
43202
43203
43204
43205
43213
43214
43302
45201
99999
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
106-98-9
75-28-5
64-17-5
71-43-2
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
BUTENE
ISO-BUTANE
ETHYL ALCOHOL
BENZENE
UNIDENTIFIED
16.04
30.07
28.05
44.09
42.08
56.10
58.12
46.07
78.11
86.00
38.39
5.21
16.38
1.37
2.00
0.49
0.09
16.47
18.91
0.68
99.99
371
-------
VOC Profile Speciation Report '
Profile Name Residential Wood Combustion
Profile Number 1167
Data Quality C
Control Device Uncontrolled/Catalyst
Referenee(s)
Data Source
77, 78, 79, 80, 81
Composite profile developed from literature data from
66 tests. Tests weighted by burn rate and
Saroad
43319
43502
43503
43504
43510
43511
45300
46701
46702
46704
46705
46706
46707
46708
46709
46710
46713
46714
46715
46716
46717
46718
46719
46720
46721
46722
46723
46724
46725
46726
46727
46728
46729
46730
46731
46732
46733
46734
46735
46736
46737
non-catalyst
all species
CAS Number
71-41-0
50-00-0
75-07-0
123-38-6
123-72-8
78-84-2
108-95-2
91-12-3
208-96-8
83-32-9
86-73-7
85-01-8
120-12-7
206-44-0
129-00-0
218-01-9
56-55-3
205-99-2
207-08-9
50-32-8
193-39-5
191-24-2
53-70-3
198-55-0
192-97-2
191-26-4
191-07-1
27208-37-3
195-19-7
catalyst/
tests equally weighted. Profile based on
identified. (See also Profile
Name
PENTANOL
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
BUTYRALDEHYDE
ISOBUTYRALDEHYDE
PHENOL
NAPTHALENE
METHYL NAPHTHALENES
PHENYLNAPHTHALENES
ACENAPHTHYLENE
ACENAPHTHENE
FLUORENE
PHENANTHRENE
ANTHRACENE
FLUORANTHENE
PYRENE
BENZOCg.h.O FLUORANTHENE
CHRYSENE
BENZO (a) ANTHRACENE
BENZO (b) FLUORANTHENE
BENZO (k) FLUORANTHENE
BENZO (a) PYRENE
INDENO(1,2,3-cd) PYRENE
BENZO (g.h.i) PERYLENE
DIBENZO(a,h) ANTHRACENE
PERYLENE
BENZO (e) PYRENE
ANTHANTHRENE
CORONENE
METHYL-ANTHRACENES
METHYL-PHENANTHRENES
C2-ALKYL-ANTHRACENES
C2-ALKYL-PHENANTHRENES
CYCLOPEMTA-ANTHRACENES
CYCLOPENTA-PHENANTHRENES
METHYL- FLUORANTHENES
CYCLOPEHTA(C,d)PYRENE
BENZO(C)PHENANTHRENE
METHYL-BENZANTHRACENES
METHYL-BENZPHENANTHRENES
1084).
Spec_MW
88.15
30.03
44.05
58.08
72.12
72.11
94.11
128.17
142.20
204.27
152.20
154.21
166.22
178.23
178.23
202.26
' 202.26
252.32
228.29
228.30
252.32
252.32
252.32
276.34
276.34
278.35
252.32
252.32
276.34
300.36
192.26
192.26
158.24
206.28
247.36
190.25
216.29
226.28
228.30
242.33
242.33
Spec_UT
0.25
0.66
0.24
0.18
2.08
1.70
6.84
43.65
0.00
0.00
7.19
1.22
2.59
16.84
0.00
3.63
3.35
1.30
2.39
0.00
1.14
0.00
0.90
0.66
0.00
0.04
0.06
0.09
0.08
0.03
0.93
0.00
0.17
0.00
0.14
0.00
0.40
0.22
0.07
0.21
0.00
Peak
(1 )
(1 )
(1 )
(2 )
(2 )
(3 )
(3.)
(4 >
(4 )
(5 )
(5 )
(6 )
(6 )
(7 )
(7 )
(8 )
(8 )
(9 )
(9 )
372
-------
VOC Profile Speciation Report - continued (profile 1167)
Saroad
46738
46739
46740
46741
46742
46743
46744
46745
TOTAL
CAS Number Name
HETHYL-CHRYSENES
C2-ALKYL-BENZANTHRACENES
C2-ALKYL-BENZOPHENANTHRENES
C2-ALKYL-CHRYSENES
BENZOPYRENES
DIBENZANTHRACENES
OIBENZPHENANTHRENES
D I BENZOPYRENES
Spec_MU
242.33
256.35
230.31
256.34
252.32
278.35
278.36
302.38
===S=======:
Spec_WT
0.00
0.41
0.00
0.00
0.29
0.03
0.00
0.02
100.00
Peak
(9 )
(10)
(10)
(10)
(11)
(11)
373
-------
374
-------
3.26 MOBILE SOURCES
Because of their widespread use, the internal combustion gasoline powered
engine in mobile applications is a major source of VOC emissions. Gasoline
fueled light-duty vehicles account for about 75 percent of VOC emissions from
mobile sources (1983). Automotive VOC emissions consist of exhaust emissions
that occur from the tailpipe, evaporative emissions that occur from (1) the
gas tank as the temperature rises during the day, (2) the carburetor after the
engine has been shut off (hot soak emissions), and (3) emissions from vehicle
refueling. This section also contains data on diesel vehicles. Profile data
for refueling are included in Section 3.20.
375
-------
376
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Light Duty Gasoline Vehicles
1101
B
Control Device
Reference(s)
Data Source
Catalyst
56
Composition data collected using GC/FID and DNPH
methods for exhaust and evaporative (hot soak)
emissions from 45 cars were composited. Based on AP-42
(4th. edition), data were weighted according to travel
fractions. (See Appendix A for details).
SCC Assignments:
Saroad
43135
43136
43201
43202
43203
43204
43205
43206
43208
43209
43211
43212
43213
43214
43215
43216
43217
43218
43220
43221
43223
43224
43226
43227
43228
43229
43230
43231
43232
43233
43234
43235
43238
43241
43242
43243
43245
43247
CAS Number
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
463-49-0
74-99-7
760-20-3
106-97-8
106-98-9
75-28-5
115-11-7
624-64-6
590-18-1
106-99-0
109-66-0
78-78-4
563-45-1
109-67-1
646-04-8
627-20-3
513-35-9
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
563-78-0
111-84-2
124-18-5
1120-21-4
287-92-3
78-79-5
592-41-6
108-08-7
Name
C10 PARAFFINS
C9 PARAFFIN
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
PROPADIENE
METHYLACETYLENE (PROPYNE)
3-METHYL-1-PENTENE
N- BUTANE
BUTENE
I SO- BUTANE
ISOBUTYLENE
T-2-BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
ISO PENTANE
3-HETHYL-1 -BUTENE
1-PENTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-METHYL-2-BUTENE
2-METHYLPENTANE
3-HETHYL PENTANE
HEXANE
HEPTANE
OCTANE
2,3 DIMETHYL-1-BUTENE
NONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
ISOPRENE
1-HEXENE
2,4-DIHETHYLPENTANE
Spec_MU
142.28
128.25
16.04
30.07
28.05
44.09
42.08
26.04
40.06
40.06
84.16
58.12
56.10
58.12
56.10
56.11
56.11
54.09
72.15
72.15
70.13
70.13
70.13
70.13
70.13
86.17
86.17
86.17
100.20
114.23
84.16
128.25
142.28
156.31
70.14
68.12
84.16
100.20
Spec_WT
0.16
0.00
10.07
1.41
3.92
0.56
1.06
0.75
0.08
0.06
0.00
9.48
0.85
1.70
0.00
0.55
0.50
1.68
2.88
6.54
0.15
0.32
0.68
0.38
0.98
1.76
1.09
0.87
0.65
0.31
0.00
0.19
0.16
0.53
0.35
0.07
0.31
0.58
Peak
(20)
( 1)
( 1)
( 7)
( 3)
( 2)
( 2)
(4)
( 5)
( 3)
( 6)
( 8)
(10)
< 8)
( 7)
( 9)
377
-------
VOC Profile Specialion Report - continued (profile 1101)
Saroad
43248
43250
43252
43261
43262
43263
43270
43272
43273
43274
43276
43277
43278
43279
43280
43281
43282
43283
43284
43285
43286
43287
43290
43291
43292
43295
43296
43297
43298
43299
43502
43503
43504
43505
43515
45110
45201
45202
45203
45204
45205
45206
45207
45208
45209
45216
45217
45218
45225
45501
90002
90003
CAS Number
110-82-7
540-84-1
565-75-3
108-87-2
96-37-7
591-76-4
922-61-2
693-89-0
110-83-8
565-59-3
79-29-8
592-13-2
760-21-4
107-00-6
503-17-3
625-27-4
590-73-8
75-83-2
142-29-0
589-34-4
592-27-8
589-53-7
50-00-0
75-07-0
123-38-6
107-02-8
123-73-9
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
106-42-3
108-67-8
95-63-6
103-65-1
135-98-8
135-01-3
141-93-5
526-73-8
100-52-7
Name
CYCLOHEXANE
2,2,4-TRIHETHYLPENTANE
2,3,4-TRIHETHYLPENTANE
HETHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
2-METHYL HEXANE
3-HETHYL-T-2-PENTENE
METHYLCYCLOPENTENE
CYCLOHEXENE
2,3 DIMETHYL PENTANE
2,3 DIHETHYLBUTANE
2,4-DIHETHYLHEXANE
2,5-DIMETHYLHEXANE
2-ETHYL-1-BUTENE
2,3,3 TRIHETHYLPENTANE
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-METHYL-2-PENTENE
2-HEXENE
DIMETHYLHEXENE
2,2 DIHETHYLHEXANE
2,3 DIHETHYLHEXANE
2,2-DIHETHYLBUTANE
CYCLOPENTENE
3-METHYLHEXANE
2-HETHYLHEPTANE
4-METHYLHEPTANE
3-METHYLHEPTANE
1 -METHYLCYCLOHEXENE
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
ACROLEIN
CROTONALDEHYDE
C10 AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
H-XYLENE
P-XYLENE
1,3,5-TRIHETHYLBENZENE
1 ,2,4-TRIHETHYLBENZENE
N-PROPYLBENZENE
S-BUTYLBENZENE
1,2 D I ETHYLBENZENE
H-DIETHYLBENZENE
1 ,2,3-TRIMETHYLBENZENE
BENZALDEHYOE
2,3,5-TRIMETHYLHEXANE
2,4 DIHETHYLHEPTANE
Spec_MU
84.16
114.22
114.22
98.21
84.16
100.20
84.16
82.14
82.14
100.20
86.17
114.22
114.22
84.16
114.22
54.09
54.09
84.16
84.16
84.16
112.20
114.22
114.22
86.17
68.11
100.20
114.23
114.23
114.23
96.17
30.03
44.05
58.08
56.07
70.09
134.22
78.11
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.19
134.21
134.22
134.22
120.19
106.13
128.25
128.26
Spee_WT
1.40
1.97
0.12
0.50
0.78
0.00
0.00
0.01
0.00
1.40
0.69
0.63
0.00
0.00
1.09
0.00
0.00
0.00
0.42
0.16
0.12
0.05
0.00
0.21
0.37
1.06
0.19
0.45
0.36
0.00
0.74
0.28
0.02
0.06
0.02
2.02
1.39
5.14
0.77
1.56
0.00
2.56
1.87
2.30
0.48
0.11
0.59
0.59
0.66
0.08
0.09
0.11
Peak
(12)
(11)
(13)
(11)
(13)
(13)
(14)
(14)
( 9)
( 5)
( 6)
(10)
(15)
( 4)
(16)
(16)
(12)
(15)
(18)
(20)
(19)
(19)
378
-------
VOC Profile Speciation Report - continued (profile 1101)
Saroad
90004
90005
90006
90007
90008
90009
90042
98033
98044
99910
99911
99912
99913
99915
99916
99917
99918
99999
CAS Number Name
3,5 OIHETHYLHEPTANE
2,5 0 IMETHYLHEPTANE
2,3 DIHETHYLHEPTANE
691-37-2 4-HETHYL-1-PEMTENE
2-METHYLOCTANE
2,4, 5-TR IMETHYLHEPTANE
13269-52-8 T-3-HEXENE
2,2,5-TRIMETHYLHEXANE
496-11-7 INDANE
2,4 DIMETHYLOCTANE
3,4 DIMETHYLOCTANE
1 -METHYL-3-ETHYLBENZENE
1 -METHYL-2-ETHYLBENZENE
538-93-2 ISOBUTYLBENZENE
1-METHYL-3N-PROPYLBENZENE
1-HETHYL-3-ISOPROPYLBENZENE
2-HETHYLDECANE
UNIDENTIFIED
Spec_HU
128.26
128.26
128.26
84.16
128.26
142.29
84.16
128.26
118.18
142.29
142.29
120.19
120.19
134.22
134.22
134.22
156.32
86.00
Spec_WT
0.00
0.73
0.00
0.00
0.01
0.26
0.29
0.46
0.52
0.07
0.74
1.06
0.21
0.55
0.17
0.38
1.08
8.46
Peak
(17)
(17)
(18)
( 7)
TOTAL
100.04
379
-------
VOC Profile Speciation Report
Profile Name Heavy Duty Gasoline Trucks
Profile Number 1186
Data Quality C
Control Device Uncontrolled
Reference(s) 85,86,87
Data Source Exhaust emission data from four trucks combined with
diurnal and hotsoalc emission data from passenger cars
using leaded gasoline.
SCC Assignments:
Saroad
43135
43136
43201
43202
43203
43204
43205
43206
43208
43209
43211
43212
43213
43214
43215
43216
43217
43218
43220
43221
43223
43224
43225
43226
43227
43228
43229
43230
43231
43232
43233
43234
43235
43238
43241
43242
43243
43245
43247
43248
CAS Number
74-82-8
74-84-0
. 74-85-1
74-98-6
115-07-1
74-86-2
463-49-0
74-99-7
760-20-3
106-97-8
106-98-9
75-28-5
115-11-7
624-64-6
590-18-1
106-99-0
109-66-0
78-78-4
563-45-1
109-67-1
563-46-2
646-04-8
627-20-3
513-35-9
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
563-78-0
111-84-2
124-18-5
1120-21-4
287-92-3
78-79-5
592-41-6
108-08-7
110-82-7
Name
C10 PARAFFINS
C9 PARAFFIN
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
PROPADIENE
HETHYLACETYLENE (PROPYNE)
3-METHYL-1-PENTENE
N-BUTANE
BUTENE
I SO- BUTANE
ISOBUTYLENE
T-2-BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
ISO PENTANE
3-HETHYL-1-BUTENE
1-PENTENE
2-HETHYL-1 -BUTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-HETHYL-2-BUTENE
2-HETHYLPENTANE
3-HETHYL PENTANE
HEXANE
HEPTANE
OCTANE
2,3 DIHETHYL-1-BUTENE
NONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
ISOPRENE
1-HEXENE
2,4-DIHETHYLPENTANE
CYCLOHEXAHE
Spec_HW
142.28
128.25
16.04
30.07
28.05
44.09
42.08
26.04
40.06
40.06
84.16
58.12
56.10
58.12
56.10
56.11
56.11
54.09
72.15
72.15
70.13
70.13
70.13
70.13
70.13
70.13
86.17
86.17
86.17
100.20
114.23
84.16
128.25
142.28
156.31
70.14
68.12
84.16
100.20
84.16
Spec_WT
0.00
0.00
2.45
0.69
4.35
0.00
1.57
2.66
0.11
0.24
0.00
22.42
1.11
3.43
0.00
0.89
0.67
0.00
4.86
11.04
0.14
0.41
0.00
0.82
0.97
0.11
2.81
1.54
1.53
0.73
0.24
0.00
0.11
0.11
0.14
0.48
0.10
0.28
0.64
0.00
Peak
(19)
(18)
(1 )
(1 )
(5 )
(3 )
(2 )
(2 )
(3 )
(4 )
(4 )
(6 )
(8 )
(6 )
(5 )
(7 )
(10)
380
-------
VOC Profile Speciation Report - continued (profile 1186)
Saroad
43250
43252
43261
43262
43263
43270
43272
43273
43274
43276
43277
43278
43279
43280
43283
43284
43290
43291
43292
43295
43296
43297
43298
45201
45202
45203
45204
45205
45206
45207
45208
45209
45216
45217
45218
45225
45235
45241
45242
90002
90003
90004
90005
90006
90008
90015
90016
90017
90032
90033
90034
90036
CAS Number
540-84-1
565-75-3
108-87-2
96-37-7
591-76-4
922-61-2
693-89-0
110-83-8
565-59-3
79-29-8
592-13-2
760-21-4
625-27-4
75-83-2
142-29-0
589-34-4
592-27-8
589-53-7
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
106-42-3
108-67-8
95-63-6
103-65-1
135-98-8
135-01-3
141-93-5
526-73-8
104-51-8
768-56-9
821-95-4
6434-78-2
Name
2,2,4-TRIHETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
HETHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-HETHYL HEXANE
3-METHYL-T-2-PENTENE
METHYLCYCLOPENTENE
CYCLOHEXENE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
2,4-DIMETHYLHEXANE
2,5-DIHETHYLHEXANE
2-ETHYL-1-BUTENE
2,3,3 TRIMETHYLPENTANE
C-3-HEXENE
2-HETHYL-2-PENTENE
2,3 DIHETHYLHEXANE
2,2-DIMETHYLBUTANE
CYCLOPENTENE
3-HETHYLHEXANE
2-HETHYLHEPTANE
4-METHYLHEPTANE
3-METHYLHEPTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
1,3,5-TRIMETHYLBENZENE
1,2,4-TRIHETHYLBENZENE
N-PROPYLBENZENE
S-BUTYLBENZENE
1,2 D1ETHYLBENZENE
H-DIETHYLBENZENE
1,2,3-TRIMETHYLBENZENE
BUTYL BENZENE
4-PHENYL-1-BUTENE
T-1-PHENYLBUTENE
2,3,5-TRIMETHYLHEXANE
2,4 DIHETHYLHEPTANE
3,5 DIMETHYLHEPTANE
2,5 DIHETHYLHEPTANE
2,3 DIHETHYLHEPTANE
2-HETHYLOCTANE
3-METHYLOCTANE
4-METHYLOCTANE
HETHYLCYCLOOCTANE
1-UNDECENE
CYCLOPENTYLCYCLOPENTANE
T-2-NONENE
PENTYNE
SpecJW
114.22
114.22
98.21
84.16
100.20
84.16
82.14
82.14
100.20
86.17
114.22
114.22
84.16
114.22
84.16
84.16
114.22
86.17
68.11
100.20
114.23
114.23
114.23
78.11
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.19
134.21
134.22
134.22
120.19
134.21
132.20
132.20
128.25
128.26
128.26
128.26
128.26
128.26
128.26
128.26
127.25
154.30
138.25
126.24
68.12
Spec_WT
1.50
0.26
0.26
1.11
0.00
0.00
0.03
1.58
0.00
0.98
0.42
0.00
0.00
0.42
0.00
0.34
0.00
0.22
0.29
0.00
0.26
0.25
0.35
1.75
2.98
0.67
0.91
1.86
0.00
1.21
1.44
0.31
0.05
0.30
0.23
0.26
0.21
0.26
0.23
0.08
0.08
0.00
0.13
0.00
0.04
0.31
0.39
0.33
0.14
0.46
0.17
0.19
Peak
(9 )
(11)
<9 }
(11)
(11)
(13)
(13)
(7 )
(8 )
(14)
(12)
(10)
(14)
(16)
(18)
(17)
(17)
(15)
(15)
(16)
381
-------
VOC Profile Speeiation Report. - continued (profile 1186)
Saroad CAS Hunter Name
TOTAL
Spec_MU Spec_WT Peak
90037
90038
98033
98035
98044
98054
99908
99909
99912
99913
99916
99918
OQOQQ
yyyyy
HEXYNE
624-29-3 CIS-1.4 DIHETHYLCYCLOHEXANE
2,2.5-TRIHETHYLHEXANE
592-43-8 C-2-HEXEHE
496-11-7 INDANE
107-39- 1 2,4,4-TRIHETHYL- 1 -PENTENE
2,3 DIHETHYLOCTANE
2,6 DIHETHYLOCTANE
1 -HETHYL-3-ETHYLBENZENE
1 -METHYL-2-ETHYLBENZENE
1-METHYL-3N-PROPYLBENZENE
2-METHYLDECANE
UNIDENTIFIED
82.15
112.22
128.26
84.16
118.18
112.22
142.28
167.31
120.19
120.19
134.22
156.32
86.00
0.02
0.08
0.24
0.11
0.32
1.73
0.52
0.07
0.16
0.00
0.16
0.63
5.07
(12)
(19)
100.02
382
-------
VOC Profile Spec)ation Report
Profile Name
Profile Number
Data Quality
Light-Duty Diesel Vehicles
1201
C
Control Device
Reference(s)
Data Source
Uncontrolled
83, 84, 94
Species data by carbon number from three cars combined
with aldehydes data from two cars. C1 to C43 organics
analyzed using a combination of FID and solvent extract
ion. Aldehydes measured by 2, 4-DNP method. Hoi. Uts.
of C1 to C7 based on species distribution data (1 car);
C8 to C43 based on hydrogen to carbon ratio of 2.
SCC Assignments: 111
Saroad
43502
43503
43504
43505
43512
43515
45501
99101
99102
99103
99104
99105
99106
99107
99108
99109
99110
99111
99112
99113
99114
99115
99116
99117
99118
99119
99120
99121
99122
99123
99124
99125
99126
99127
99128
99129
99130
CAS Number Name
50-00-0 FORMALDEHYDE
75-07-0 ACETALDEHYDE
123-38-6 PROPIONALDEHYDE
107-02-8 ACROLEIN
66-25-1 HEXANAL
123-73-9 CROTONALDEHYDE
100-52-7 BENZALDEHYDE
C-1 COMPOUNDS
C-2 COMPOUNDS
C-3 COMPOUNDS
C-4 COMPOUNDS
C-5 COMPOUNDS
C-6 COMPOUNDS
C-7 COMPOUNDS
C-8 COMPOUNDS
C-9 COMPOUNDS
C-10 COMPOUNDS
C-11 COMPOUNDS
C-1 2 COMPOUNDS
C-13 COMPOUNDS
C-1 4 COMPOUNDS
C-1 5 COMPOUNDS
C-16 COMPOUNDS
C-1 7 COMPOUNDS
C-18 COMPOUNDS
C-19 COMPOUNDS
C-20 COMPOUNDS
C-21 COMPOUNDS
C-22 COMPOUNDS
C-23 COMPOUNDS
C-24 COMPOUNDS
C-25 COMPOUNDS
C-26 COMPOUNDS
C-27 COMPOUNDS
C-28 COMPOUNDS
C-29 COMPOUNDS
C-30 COMPOUNDS
Spec_MU
30.03
44.05
58.08
56.07
100.16
70.09
106.13
16.04
28.55
42.08
57.08
71.00
79.12
93.18
112.00
126.00
140.00
154.00
168.00
182.00
196.00
210.00
224.00
238.00
252.00
266.00
280.00
294.00
308.00
322.00
336.00
350.00
364.00
378.00
392.00
406.00
420.00
Spec_UT Peak
8.61
2.91
1.77 (1 )
0.00 (1 )
0.08
1.01
0.55
5.80
19.94
5.21
4.08
2.36
4.30
2.89
1.13
0.75
3.52
3.58
2.20
3.43
4.45
4.35
3.49
3.06
2.04
1.56
0.91
0.75
0.59
0.48
0.48
0.54
0.44
0.22
0.32
0.14
0.32
383
-------
VOC Profile Speciation Report - continued (profile 1201)
Saroad CAS Nunber Name
Spec_HW Spec_WT Peak
99131
99132
99133
99134
99135
99136
99137
99138
99139
99140
99141
99142
99143
TOTAL
C-31 COMPOUNDS
C-32 COMPOUNDS
C-33 COMPOUNDS
C-34 COMPOUNDS
C-35 COMPOUNDS
C-36 COMPOUNDS
C-37 COMPOUNDS
C-38 COMPOUNDS
C-39 COMPOUNDS
C-40 COMPOUNDS
C-41 COMPOUNDS
C-42 COMPOUNDS
C-43 COMPOUNDS
434.00
448.00
462.00
476.00
490.00
504.00
518.00
532.00
546.00
560.00
574.00
588.00
602.00
0.29
0.27
0.22
0.24
0.16
0.20
0.08
0.05
0.11
0.02
0.05
0.02
0.01
99.98
384
-------
VOC Profile Sped at Ion Report
Profile Name
tight-Duty Gasoline Vehicles - Exhaust
Profile Number 1203
Data Quality
B
Control Device Catalyst
Reference(s)
Data Source
56, 86
Composition
methods for
data collected using GC/FID and
exhaust emissions (see Appendix
DNPH
A for
details; see also Profile 1101).
Saroad
43135
43136
43201
43202
43203
43204
43205
43206
43208
43209
43211
43212
43213
43214
43215
43216
43217
43218
43220
43221
43223
43224
43226
43227
43228
43229
43230
43231
43232
43233
43234
43235
43238
43241
43242
43243
43245
43247
43248
43250
43252
43261
CAS Number
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
463-49-0
74-99-7
760-20-3
106-97-8
106-98-9
75-28-5
115-11-7
624-64-6
590-18-1
106-99-0
109-66-0
78-78-4
563-45-1
109-67-1
646-04-8
627-20-3
513-35-9
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
563-78-0
111-84-2
124-18-5
1120-21-4
287-92-3
78-79-5
592-41-6
108-08-7
110-82-7
540-84-1
565-75-3
108-87-2
Name
C10 PARAFFINS
C9 PARAFFIN
METHANE
ETHANE
ETHYtENE
PROPANE
PROPENE
ACETYLENE
PROPADIENE
METHYLACETYtENE (PROPYNE)
3-METHYt-1-PENTENE
N- BUTANE
BUTENE
I SO- BUTANE
ISOBUTYLENE
T-2-BUTENE
CIS- 2- BUTENE
1,3 -BUTADIENE
N-PENTANE
ISO PENTANE
3-METHYL-1-BUTENE
1-PENTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-METHYL-2-BUTENE
2-HETHYLPENTANE
3-HETHYL PENTANE
HEXANE
HEPTANE
OCTANE
2,3 DIHETHYt-1-BUTENE
NONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
ISOPRENE
1-HEXENE
2,4-DIMETHYLPENTANE
CYCLOHEXANE
2,2,4-TRIMETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
METHYLCYCLOHEXANE
Spec_HU
142.28
128.25
16.04
30.07
28.05
44.09
42.08
26.04
40.06
40.06
84.16
58.12
56.10
58.12
56.10
56.11
56.11
54.09
72.15
72.15
70.13
70.13
70.13
70.13
70.13
86.17
86.17
86.17
100.20
114.23
84.16
128.25
142.28
156.31
70.14
68.12
84.16
100.20
84.16
114.22
114.22
98.21
SpecJJT
0.19
0.00
10.97
1.79
8.41
0.00
2.88
2.25
0.13
0.17
0.00
3.81
0.00
0.62
1.41
0.00
0.46
0.67
1.60
3.51
0.18
0.19
0.34
0.20
0.51
1.27
0.86
0.67
0.53
0.30
0.00
0.25
0.20
0.60
0.00
0.17
0.22
0.53
1.62
1.95
0.11
0.47
Peak
(20)
( 1)
( 1)
( 7)
( 3)
( 2)
( 2)
( 4)
( 5)
( 3)
( 6)
( 8)
(10)
( 8)
( 7)
( 9)
(12)
385
-------
VOC Profile Speciation Report - continued (profile 1203)
Sa road
43262
43263
43270
43272
43273
43274
43276
43277
43278
43279
43280
43281
43282
43283
43284
43285
43286
43287
43290
43291
43292
43295
43296
43297
43298
43299
43502
43503
43504
43505
43515
45110
45201
45202
45203
45204
45205
45206
45207
45208
45209
45216
45217
45218
45225
45501
90002
90003
90004
90005
90006
90007
CAS Number
96-37-7
591-76-4
922-61-2
693-89-0
110-83-8
565-59-3
79-29-8
592-13-2
760-21-4
107-00-6
503-17-3
625-27-4
590-73-8
75-83-2
142-29-0
589-34-4
592-27-8
589-53-7
50-00-0
75-07-0
123-38-6
107-02-8
123-73-9
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
106-42-3
108-67-8
95-63-6
103-65-1
135-98-8
135-01-3
141-93-5
526-73-8
100-52-7
691-37-2
Name
HETHYLCYCLOPENTANE
2-HETHYL HEXANE
3-METHYL-T-2-PENTENE
HETHYLCYCLOPENTENE
CYCLOHEXENE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
2,4-DIHETHYLHEXANE
2,5-DIMETHYLHEXANE
2-ETHYL-1-BUTENE
2.3,3 TRIMETHYLPENTANE
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-HETHYL-2-PENTENE
2-HEXENE
DIMETHYLHEXENE
2,2 DIMETHYLHEXANE
2,3 DIMETHYLHEXANE
2.2-DIMETHYLBUTANE
CYCLOPENTENE
3-HETHYLHEXANE
2-HETHYLHEPTANE
4-HETHYLHEPTANE
3-METHYLHEPTANE
1-METHYLCYCLOHEXENE
FORMALDEHYDE
ACETALDEHYDE
PROP I ON ALDEHYDE
ACROLEIN
CROTONALDEHYDE
C10 AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
H-XYLENE
P-XYLENE
1 ,3,5-TRIHETHYLBENZENE
1,2,4-TRIMETHYLBENZENE
N-PROPYLBENZENE
S-BUTYLBENZENE
1,2 DIETHYLBENZENE
M-DIETHYLBENZENE
1,2,3-TRIMETHYLBENZENE
BENZALDEHYDE
2,3,5-TRIMETHYLHEXANE
2,4 DIMETHYLHEPTANE
3,5 DIMETHYLHEPTANE
2,5 DIMETHYLHEPTANE
2,3 DIMETHYLHEPTANE
4-METHYL-1-PENTENE
Spec_HU
84.16
100.20
84.16
82.14
82.14
100.20
86.17
114.22
114.22
84.16
114.22
54.09
54.09
84.16
84.16
84.16
112.20
114.22
114.22
86.17
68.11
100.20
114.23
114.23
114.23
96.17
30.03
44.05
58.08
56.07
70.09
134.22
78.11
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.19
134.21
134.22
134.22
120.19
106.13
128.25
128.26
128.26
128.26
128.26
84.16
Spec_WT
0.61
0.00
0.00
0.02
0.00
1.25
0.53
0.00
0.63
0.00
1.10
0.00
0.00
0.00
0.23
6.08
0.13
0.07
0.00
0.71
0.27
0.92
0.22
0.52
0.36
0.00
1.42
0.49
0.05
0.15
0.07
2.65
1.62
5.72
0.88
1.76
0.00
2.87
2.21
2.90
0.56
0.17
0.67
0.57
0.81
0.24
0.11
0.13
0.00
0.00
0.00
0.25
Peak
(11)
(13)
(11)
(13)
(13)
(14)
(14)
( 9)
( 5)
( 6)
(10)
(15)
( 4)
(16)
(16)
(12)
(15)
(18)
(20)
(19)
(19)
(17)
(17)
(18)
( 7)
386
-------
VOC Profile Speciat ion Report - continued (profile 1203)
Saroad CAS Number Name
TOTAL
Spec_MW Spec_WT Peak
90008
90009
90042
98033
98044
99910
99911
99912
99913
99915
99916
99917
99918
99999
2-METHYLOCTANE
2,4,5-TRIHETHYLHEPTANE
13269-52-8 T-3-HEXENE
2,2,5-TRIMETHYLHEXANE
496-11-7 INDANE
2,4 OIHETHYLOCTANE
3,4 OIHETHYLOCTANE
1 -HETHYL-3-ETHYLBENZENE
1 -METHYL - 2- ETHYLBENZENE
538-93-2 ISOBUTYLBENZENE
1 -METHYL-3N-PROPYLBENZENE
1 -HETHYL-3- ISOPROPYLBENZENE
2-HETHYLDECANE
UNIDENTIFIED
128.26
142.29
84.16
128.26
118.18
142.29
142.29
120.19
120.19
134.22
134.22
134.22
156.32
86.00
0.02
0.45
0.20
0.48
0.54
0.10
0.96
1.25
0.26
0.49
0.39
0.51
1.32
9.08
100.04
387
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Light-Duty
1204
B
56, 86
Gasoline Vehicles - Evaporative
Composition data collected using GC/FID for
emissions
1101).
Saroad CAS Number
43135
43136
43201
43202
43203
43204
43205
43206
43208
43209
43211
43212
43213
43214
43215
43216
43217
43218
43220
43221
43223
43224
43226
43227
43228
43229
43230
43231
43232
43233
43234
43235
43238
43241
43242
43243
43245
43247
43248
43250
43252
43261
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
463-49-0
74-99-7
760-20-3
106-97-8
106-98-9
75-28-5
115-11-7
624-64-6
590-18-1
106-99-0
109-66-0
78-78-4
563-45-1
109-67-1
646-04-8
627-20-3
513-35-9
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
563-78-0
111-84-2
124-18-5
1120-21-4
287-92-3
78-79-5
592-41-6
108-08-7
110-82-7
540-84-1
565-75-3
108-87-2
(see Appendix A for detai Is; see
Name
C10 PARAFFINS
C9 PARAFFIN
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
PROPADIENE
HETHYLACETYLENE (PROPYNE)
3-METHYL-1-PENTENE
N-BUTANE
BUTENE
I SO- BUTANE
ISOBUTYLENE
T-2-8UTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
ISO PENTANE
3-METHYL-1 -BUTENE
1-PENTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-HETHYL-2-BUTENE
2-HETHYLPENTANE
3-HETHYL PENTANE
HEXANE
HEPTANE
OCTANE
2,3 DIMETHYL-1-BUTENE
NONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
ISOPRENE
1-HEXENE
2,4-DIHETHYLPENTANE
CYCLOHEXANE
2,2,4-TRIHETHYLPENTANE
2,3,4-TRIHETHYLPENTANE
METHYLCYCLOHEXANE
evaporative
also Profile
Spec_HU
142.28
128.25
16.04
30.07
28.05
44.09
42.08
26.04
40.06
40.06
84.16
58.12
56.10
58.12
56.10
56.11
56.11
54.09
72.15
72.15
70.13
70.13
70.13
70.13
70.13
86.17
86.17
86.17
100.20
114.23
84.16
128.25
142.28
156.31
70.14
68.12
84.16
100.20
84.16
114.22
114.22
98.21
Spec_WT
0.09
0.00
0.04
0.03
0.03
1.54
0.00
0.01
0.02
0.00
0.00
28.34
0.00
6.56
0.86
0.00
0.81
0.00
4.67
13.60
0.18
0.62
1.11
1.13
0.74
2.28
1.17
0.72
0.52
0.24
0.00
0.12
0.20
0.09
0.00
0.00
0.39
0.59
0.67
0.59
0.59
0.33
Peak
(20)
( 1)
( 1)
( 7)
( 3)
( 2)
( 2)
C 4)
( 5)
( 3)
( 6)
( 8)
(10)
( 8)
( 7)
( 9)
(12)
388
-------
VOC Profile Speci'ation Report - continued (profile 1204)
Saroad
43262
43263
43270
43272
43273
43274
43276
43277
43278
43279
43280
43281
43282
43283
43284
43285
43286
43287
43290
43291
43292
43295
43296
43297
43298
43299
43502
43503
43504
43505
43515
45110
45201
45202
45203
45204
45205
45206
45207
45208
45209
45216
45217
45218
45225
45501
90002
90003
90004
90005
90006
90007
CAS Number
96-37-7
591-76-4
922-61-2
693-89-0
110-83-8
565-59-3
79-29-8
592-13-2
760-21-4
107-00-6
503-17-3
625-27-4
590-73-8
75-83-2
142-29-0
589-34-4
592-27-8
589-53-7
50-00-0
75-07-0
123-38-6
107-02-8
123-73-9
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
106-42-3
108-67-8
95-63-6
103-65-1
135-98-8
135-01-3
141-93-5
526-73-8
100-52-7
691-37-2
Name
METHYLCYCLOPENTANE
2-HETHYL HEXANE
3-METHYL-T-2-PENTENE
METHYLCYCLOPENTENE
CYCLOHEXENE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
2,4-DIMETHYLHEXANE
2.5-DIMETHYLHEXANE
2-ETHYL-1-BUTENE
2,3,3 TRIMETHYLPENTANE
1-BUTYME
2-BUTYNE
C-3-HEXENE
2-HETHYL-2-PENTENE
2-HEXENE
DIMETHYLHEXENE
2,2 DIMETHYLHEXANE
2,3 DIMETHYLHEXANE
2,2-DIHETHYLBUTANE
CYCLOPENTENE
3-METHYLHEXANE
2-HETHYLHEPTANE
4-HETHYLHEPTANE
3-HETHYLHEPTANE
1-HETHYLCYCLOHEXENE
FORMALDEHYDE
ACETALDEHYDE
PROP I ON ALDEHYDE
ACROLEIN
CROTONALDEHYDE
C10 AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
1 ,3,5-TRIHETHYLBENZENE
1 ,2,4-TRIMETHYLBENZENE
N-PROPYLBENZENE
S-BUTYLBENZENE
1,2 DIETHYLBENZENE
M-DIETHYLBENZENE
1,2,3-TRIHETHYLBENZENE
BENZALDEHYDE
2,3,5-TRIHETHYLHEXANE
2,4 DIHETHYLHEPTANE
3,5 DIMETHYLHEPTANE
2,5 DIHETHYLHEPTANE
2,3 DIHETHYLHEPTANE
4-METHYL-1-PENTENE
Spec_NU
84.16
100.20
84.16
82.14
82.14
100.20
86.17
114.22
114.22
84.16
114.22
54.09
54.09
84.16
84.16
84.16
112.20
114.22
114.22
86.17
68.11
100.20
114.23
114.23
114.23
96.17
30.03
44.05
58.08
56.07
70.09
134.22
78.11
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.19
134.21
134.22
134.22
120.19
106.13
128.25
128.26
128.26
128.26
128.26
84.16
Spec_WT
0.84
0.00
0.00
0.07
0.00
1.03
1.04
0.00
0.48
0.00
0.41
0.00
0.00
0.00
0.64
0.08
0.05
0.05
0.00
1.68
0.20
0.77
0.22
0.10
0.35
0.00
0.00
0.00
0.00
0.00
0.00
0.63
0.66
8.51
0.53
0.87
0.00
2.11
0.71
1.21
0.36
0.16
0.13
0.13
0.17
0.00
0.07
0.05
0.00
0.00
0.00
1.49
Peak
(11)
(13)
(11)
(13)
(13)
(14)
(14)
( 9)
( 5)
( 6)
(10)
(15)
( 4)
(16)
(16)
(12)
(15)
(18)
(20)
(19)
(19)
(17)
(17)
(18)
( 7)
389
-------
VOC Profile Specialion Report - continued (profile 1204)
Saroad CAS Number Name
TOTAL
Spec_MU Spec_UT Peak
90008
90009
90042
98033
98044
99910
99911
99912
99913
99915
99916
99917
99918
99999
2-HETHYLOCTANE
2.4. 5-TR IMETHYLHEPTANE
13269-52-8 T-3-HEXEME
2,2,5-TRIMETHYLHEXANE
496-11-7 INDANE
2,4 DIHETHYLOCTANE
3,4 DIHETHYLOCTANE
1 -HETHYL-3-ETHYLBENZENE
1 -METHYL-2-ETHYLBENZENE
538-93-2 ISOBUTYLBENZENE
1 -METHYL-3N-PROPYLBENZENE
1 -HETHYL-3- ISOPROPYLBENZENE
2-HETHYLDECANE
UNIDENTIFIED
128.26
142.29
84.16
128.26
118.18
142.29
142.29
120.19
120.19
134.22
134.22
134.22
156.32
86.00
0.00
0.15
0.13
0.38
0.13
0.20
0.40
0.95
0.04
0.03
0.02
0.13
0.21
2.61
100.06
390
-------
3.27 AIRCRAFT
Aircraft engines are primarily reciprocating piston and gas turbine.
Aircraft emissions of concern typically occur during landing/takeoff (LTO)
cycles. Each class of aircraft has its own typical LTO cycle which includes
all of the normal flight and ground operation modes. These operations are
divided into five modes: approach, taxi/idle in, taxi/idle out, takeoff, and
climbout.
391
-------
392
-------
VOC Profile Sped at ion Report
Profile Name
Profile Number
Data Quality
Aircraft Landing/Takeoff (LTD) - Military
1097
B
Control Device
Reference(s)
Data Source
Uncontrolled
53
Composite profile developed from data for a CFH-36 jet
engine fired with JP-5 fuel at idle, 30X thrust and 80%
thrust. Data collected by GC/MS and DNPH analyses were
combined according to average LTD cycle times obtained
from AP-42 (4th. Edition) for military aircraft.
SCC Assignments:
Saroad
43111
43113
43114
43121
43137
43140
43201
43202
43203
43204
43205
43206
43213
43217
43218
43220
43224
43228
43229
43232
43233
43235
43238
43241
43245
43255
43258
43259
43260
43264
43265
43269
43502
43503
43504
43505
43510
43512
CAS Number
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
106-98-9
590-18-1
106-99-0
109-66-0
109-67-1
513-35-9
107-83-5
142-82-5
111-65-9
111-84-2
124-18-5
1120-21-4
592-41-6
112-40-3
629-50-5
629-59-4
629-62-9
111-66-0
124-11-8
50-00-0
75-07-0
123-38-6
107-02-8
123-72-8
66-25-1
Name
ISOHERS OF DODECANE
ISOMERS OF TETRADECANE
ISOHERS OF PENTADECANE
ISOHERS OF PENTENE
C16 BRANCHED ALKANE
C7-C16 PARAFFINS
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
1 -PENTENE
2-METHYL-2-BUTENE
2-HETHYLPENTANE
HEPTANE
OCTANE
NONANE
N-DECANE
N-UNDECANE
1-HEXENE
N-DODECANE
N-TRIDECANE
N- TETRADECANE
N-PENTADECANE
HEPTENE
OCTENE
1-NONENE
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
ACROLEIN
BUTYRALDEHYDE
HEXANAL
Spec_MU
170.32
198.38
212.41
70.13
226.45
156.31
16.04
30.07
28.05
44.09
42.08
26.04
56.10
56.11
54.09
72.15
70.13
70.13
86.17
100.20
114.23
128.25
142.28
156.31
84.16
170.33
184.36
198.38
212.41
98.18
112.21
126.24
30.03
44.05
58.08
56.07
72.12
100.16
Spec_WT Peak
0.19
0.20
0.18
0.76
0.16
0.32
9.38
0.91
18.37
0.19
5.44
4.41
2.06
0.50
1.89
0.22
0.89
0.21
0.41
0.07
0.05
0.13
0.44
0.54
0.86
1.07.
0.67
0.59
0.26
0.54
0.30
0.26
15.48
4.83
0.98
2.38
1.24 (1)
0.22
393
-------
VOC Profile Spcciation Report - continued (profile 1097)
Saroad
43513
43514
43515
43551
45201
45202
45203
45204
45220
45231
45235
45300
45501
46701
46702
90010
90014
90019
90020
90030
90031
CAS Number
107-22-2
78-98-8
123-73-9
67-64-1
71-43-2
108-88-3
100-41-4
95-47-6
100-42-5
104-51-8
108-95-2
100-52-7
91-12-3
8720-50-9
544-76-3
629-78-7
Name
GLYOXAL
METHYL GLYOXAL
CROTONALDEHYDE
ACETONE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
STYRENE
PENTYL BENZENE
BUTYL BENZENE
PHENOL
BENZALDEHYDE
NAPTHALENE
METHYL NAPHTHALENES
M-XYLENE AND P-XYLENE
1-DECENE
C6H1803SI3
C8H2404SI4
HEXADECANE
N-HEPTADECANE
Spec_MW
58.04
72.07
70.09
58.08
78.11
92.13
106.16
106.16
104.14
148.25
134.21
94.11
106.13
128.17
142.20
106.16
140.27
222.47
296.60
226.45
240.46
Spec_WT Peak
2.18
2.06
0.00 ( 1}
2.41
2.02
0.55
0.18
0.20
0.41
0.21
0.26
0.26
0.57
0.60
0.52
0.30
0.17
6.96
2.37
0.12
0.01
TOTAL
99.96
394
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Aircraft Landing/Takeoff (LTD) - Commercial
1098
B
Control Device
Reference(s)
Data Source
Uncontrolled
53
Composite profile developed from data for a CFM-36 jet
engine fired with JP-5 fuel at idle, 30X thrust and SOX
thrust. Data collected by GC/HS and DNPH analyses were
combined according to average LTD cycle times obtained
from AP-42 (4th. Edition) for commercial aircraft.
SCC Assignments:
Saroad
43111
43113
43114
43121
43137
43140
43201
43202
43203
43204
43205
43206
43213
43217
43218
43220
43224
43228
43229
43232
43233
43235
43238
43241
43245
43255
43258
43259
43260
43264
43265
43269
43502
43503
43504
43505
43510
43512
CAS Number
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
106-98-9
590-18-1
106-99-0
109-66-0
109-67-1
513-35-9
107-83-5
142-82-5
111-65-9
111-84-2
124-18-5
1120-21-4
592-41-6
112-40-3
629-50-5
629-59-4
629-62-9
111-66-0
124-11-8
50-00-0
75-07-0
123-38-6
107-02-8
123-72-8
66-25-1
Name
ISOMERS OF DOOECANE
ISOHERS OF TETRADECANE
ISOMERS OF PENTADECANE
ISOMERS OF PENTENE
C16 BRANCHED ALKANE
C7-C16 PARAFFINS
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
1-PENTENE
2-METHYL-2-BUTENE
2-METHYLPENTANE
HEPTANE
OCTANE
NONANE
N-DECANE
N-UNDECANE
1-HEXENE
N-DODECANE
N-TRIDECANE
N-TETRADECANE
N- PENTADECANE
HEPTENE
OCTENE
1-NONENE
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
ACROLEIN
BUTYRALDEHYDE
HEXANAL
Spec_MU
170.32
198.38
212.41
70.13
226.45
156.31
16.04
30.07
28.05
44.09
42.08
26.04
56.10
56.11
54.09
72.15
70.13
70.13
86.17
100.20
114.23
128.25
142.28
156.31
84.16
170.33
184.36
198.38
212.41
98.18
112.21
126.24
30.03
44.05
58.08
56.07
72.12
100.16
Spec_WT Peak
0.18
0.19
0.17
0.73
0.14
0.30
9.57
0.88
17.43
0.18
5.15
4.17
1.97
0.48
1.80
0.21
0.84
0.20
0.39
0.06
0.05
0.13
0.42
0.53
0.82
1.07
0.66
0.58
0.26
0.54
0.28
0.24
15.01
4.65
0.95
2.27
1.20 (1)
0.21
395
-------
VOC Profile Speciation Report - continued (profile 1098)
Saroad
43513
43514
43515
43551
45201
45202
45203
45204
45220
45231
45235
45300
45501
46701
46702
90010
90014
90019
90020
90030
90031
CAS Number
107-22-2
78-98-8
123-73-9
67-64-1
71-43-2
108-88-3
100-41-4
95-47-6
100-42-5
104-51-8
108-95-2
100-52-7
91-12-3
8720-50-9
544-76-3
629-78-7
Name
GLYOXAL
METHYL GLYOXAL
CROTONALOEHYDE
ACETONE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
STYRENE
PENTYL BENZENE
BUTYL BENZENE
PHENOL
BENZALDEHYOE
NAPTHALENE
METHYL NAPHTHALENES
M-XYLENE AND P-XYLENE
1-DECENE
C6H1803SI3
C8H2404SI4
HEXADECANE
N-HEPTADECANE
Spec_MW
58.04
72.07
70.09
58.08
78.11
92.13
106.16
106.16
104.14
148.25
134.21
94.11
106.13
128.17
142.20
106.16
140.27
222.47
296.60
226.45
240.46
Spec_WT Peak
2.54
1.97
0.00 ( 1)
2.45
1.94
0.52
0.17
0.19
0.39
0.19
0.24
0.24
0.55
0.57
0.49
0.29
0.17
9.11
2.92
0.12
0.01
TOTAL
99.98
396
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Aircraft Landing/Takeoff (LTD) - General Aviation
1099
C
Control Device
Reference(s)
Data Source
Uncontrolled
53
Composite profile developed from data for a CFH-36
jet engine fired JP-5 fuel at idle, 30X thrust, and 80%
thrust. Data collected by GC/MS and DNPH analyses were
combined according to average LTD cycle times obtained
from AP-42 (4th. Edition) for general aviation.
SCC Assignments:
Saroad
43111
43113
43114
43121
43137
43140
43201
43202
43203
43204
43205
43206
43213
43217
43218
43220
43224
43228
43229
43232
43233
43235
43238
43241
43245
43255
43258
43259
43260
43264
43265
43269
43502
43503
43504
43505
43510
43512
CAS Number
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
106-98-9
590-18-1
106-99-0
109-66-0
109-67-1
513-35-9
107-83-5
142-82-5
111-65-9
111-84-2
124-18-5
1120-21-4
592-41-6
112-40-3
629-50-5
629-59-4
629-62-9
111-66-0
124-11-8
50-00-0
75-07-0
123-38-6
107-02-8
123-72-8
66-25-1
Name
ISOMERS OF DODECANE
ISOHERS OF TETRADECANE
ISOMERS OF PENTADECANE
ISOHERS OF PENTENE
C16 BRANCHED ALKANE
C7-C16 PARAFFINS
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
1 -PENTENE
2-METHYL-2-BUTENE
2-METHYLPENTANE
HEPTANE
OCTANE
NONANE
N-DECANE
N-UNDECANE
1-HEXENE
N-DODECANE
N-TRIDECANE
N-TETRADECANE
N-PENTADECANE
HEPTENE
OCTENE
1-NONENE
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
ACROLEIN
BUTYRALDEHYDE
HEXANAL
Spec_MW
170.32
198.38
212.41
70.13
226.45
156.31
16.04
30.07
28.05
44.09
42.08
26.04
56.10
56.11
54.09
72.15
70.13
70.13
86.17
100.20
114.23
128.25
142.28
156.31
84.16
170.33
184.36
198.38
212.41
98.18
112.21
126.24
30.03
44.05
58.08
56.07
72.12
100.16
Spec_UT Peak
0.16
0.17
0.15
0.64
0.13
0.27
10.95
0.92
15.48
0.20
4.59
3.69
1.79
0.45
1.57
0.19
0.75
0.18
0.35
0.06 .
0.04
0.15
0.42
0.52
0.76
1.21
0.66
0.59
0.27
0.52
0.25
0.22
14.14
4.32
0.90
2.06
1.19 ( 1)
0.20
397
-------
VOC Profile Speciation Report - continued (profile 1099)
Saroad
43513
43514
43515
43551
45201
45202
45203
45204
45220
45231
45235
45300
45501
46701
46702
90010
90014
90019
90020
90030
90031
CAS Number
107-22-2
78-98-8
123-73-9
67-64-1
71-43-2
108-88-3
100-41-4
95-47-6
100-42-5
104-51-8
108-95-2
100-52-7
91-12-3
8720-50-9
544-76-3
629-78-7
Name
GLYOXAL
METHYL GLYOXAL
CROTONALDEHYDE
ACETONE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
STYRENE
PENTYL BENZENE
BUTYL BENZENE
PHENOL
BENZALDEHYDE
NAPTHALENE
METHYL NAPHTHALENES
M-XYLENE AND P-XYLENE
1-DECENE
C6H1803SI3
C8H2404SI4
HEXADECANE
N-HEPTADECANE
Spec.MW
58.04
72.07
70.09
58.08
78.11
92.13
106.16
106.16
104.14
148.25
134.21
94.11
106.13
128.17
142.20
106.16
140.27
222.47
296.60
226.45
240.46
Spec_WT Peak
2.53
1.81
0.00 ( 1)
2.93
1.79
0.49
0.15
0.18
0.37
0.17
0.22
0.22
0.53
0.51
0.44
0.26
0.15
11.77
4.20
0.14
0.01
TOTAL
99.98
===========================================================
398
-------
3.28 FOREST FIRES
A forest "wildfire" is a large-scale natural combustion process that
consun.es various types of botanical specimens growing outdoors in a defined
geography, area. The size and intensity of a wildfire is dependent ouch
variables as the local meteorological conditions, tree types and th r
r^r"*'-"1" the wefsht °f c°nsumabu fu" "« < -^"-..j.
r,rh«* H- .7""10115 are a col"Plex "'xture of solids, liquids, and gases
emitted "*" "aPOr C°nSt1tUte °V6r 9° PerC6nt °f the total
399
-------
400
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Miscellaneous Burning - Forest Fires
0307
C
Control Device
Reference(s)
Data Source
SCC Assignments
Uncontrolled
73
Engineering evaluation of literature data.
Saroad
CAS Number
Name
Spec_HU Spec_WT Peak
43120
43122
43201
43202
43203
43204
43205
43206
43209
43212
43213
43214
43218
43223
99999
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
74-99-7
106-97-8
106-98-9
75-28-5
106-99-0
563-45-1
ISOMERS OF BUTENE
ISOMERS OF PENTANE
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
METHYLACETYLENE (PROPYNE)
N- BUTANE
BUTENE
ISO-BUTANE
1,3-BUTADIENE
3-METHYL-1 -BUTENE
UNIDENTIFIED
56.10
72.15
16.04
30.07
28.05
44.09
42.08
26.04
40.06
58.12
56.10
58.12
54.09
70.13
86.00
0.92
0.15
9.82
10.47
19.11
0.35
3.93
8.40
0.41
0.24
0.81
0.11
0.52
0.17
44.59
TOTAL
100.00
401
-------
402
-------
REFERENCES*
1. Oliver, W. R. and S. H. Peoples, Improvement of the Emission Inventory
for Reactive Organic Gases and Oxides of Nitrogen in the South Coast Air
Basin, Volumes I and II, Final Report (Prepared for California Air
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2. Smith, D. W., E. I. DuPont de Nemours and Company, Wilmington, DE,
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3. Zanotti, M. P., Gulf Oil Company - U. S., Letter Dated January 26, 1978
to D. R. Goodwin, U. S. Environmental Protection Agency.
4. Dwlewski, S. W., Hydroscience, Inc., Knoxville, TN, Trip Report for
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September 7 and 8, 1977.
5. Peterson, C. A., Hydroscience, Inc., Knoxville, TN, Trip Report for
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October 27, 1977. .
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7. Beale, J., Dow Chemical, U.S.A., Midland, MI, Letter Dated
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1978 to D. R. Goodwin, U. S. Environmental Protection Agency.
9. Serth, R. W. and T. W. Hughes, Source Assessment: Carbon Black
Manufacture, EPA-600/2-77-107k (NTIS No. PB 273068), U. S. Environmental
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^References 2-8, 10-14, 17-18, 21-47, and 50 are available in the Synthetic
Organic Chemical Manufacturing Industry New Source Performance Standard
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403
-------
11. Smith, H. A., E. I. DuPont de Nemours and Company, Wilmington, DE,
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12. Bess, F. D., Union Carbide Corporation, Charleston, WV, Letter Dated May
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404
-------
23. Carpenter, K. G., U. S. Industrial Chemicals Company, Letter Dated
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26. Tretter, V. J., Jr., Georgia-Pacific Corporation, Portland, OR, Letter
Dated.July 19, 1978 to D. R. Goodwin, U. S. Environmental Protection
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27. Smith, D. W., E. I. DuPont, Wilmington, DE, Letter Dated January 7, 1978
to D. R. Goodwin, U. S. Environmental Protection Agency.
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April 21, 1978 to L. B. Evans, U. S. Environmental Protection Agency.
29. Edwards, J. C., Tennessee Eastman Company, Kingsport, TN, Letter Dated
August 31, 1978 to D. R. Goodwin, U. S. Environmental Protection Agency.
30. Blackburn, J. W., Hydroscience, Inc., Knoxville, TN, Trip Report for
Visit to Rohm and Haas Company, Deer Park, TX, November 1, 1977.
31. Blackburn, J. W., Hydroscience, Inc., Knoxville, TN, Trip Report for
Visit to Union Carbide Corporation, Taft, LA, June 1, 1978.
32. New Jersey State Department of Environmental Protection, Division of
Environmental Quality, Report of Emission Test, N.J.D.E.P,
I.D. No. 030050, June 2, 1986.
33. Helsel, R. W., Hydroscience, Inc., Knoxville, TN, Trip Report for Visit
to Celanese Chemical Company, Pampa, TX, March 1, 1978.
34. Bess, F. D., Union Carbide Corporation, South Charleston, WV, Letter
Dated April 21, 1978 to L. B. Evans, U. S. Environmental Protection
Agency.
35. Lawson, J. F., Hydroscience, Inc., Knoxville, TN, Trip Report for Visit
to BASF Wyandotte Corporation, Geismar, LA, July 12, 1977.
36. DeBernardi, J. A., Conoco Chemicals, Westlake, LA, Letter Dated
May 16, 1978 to D. R. Goodwin, U. S. Environmental Protection Agency.
37. Samelson, R. J., PPG Industries, Letter Dated June 2, 1978 to
D. R. Goodwin, U. S. Environmental Protection Agency.
38. Stuewe, C. W., Hydroscience, Inc., Knoxville, TN, Trip Report for Visit
to Dow Chemical USA, November 16-17, 1977.
405
-------
39. Mull ins, J. A., Shell Oil Company, Houston, TX, Letter Dated
June 22, 1978 to D. R. Goodwin, U. S. Environmental Protection Agency.
40. Lawson, J. F., Hydroscience, Inc., Knoxville, TN, Trip Report for Visit
to Celanese Chemical Company, Pasadena, TX, June 21 and 22, 1977.
41. Dehnke, T. H. and J. F. Lawson, Hydroscience, Inc., Knoxville, TN, Trip
Report for Visit to Celanese Chemical Company, Bishop, TX,
July 26, 1977.
42. Smith, D. U., E. I. DuPont de Nemours and Company, Wilmington, DE,
Letter Dated August 21, 1978 to D. R. Goodwin, U. S. Environmental
Protection Agency.
43. Cundiff, T. W., Pfizer, Terre Haute, IN, Letter Dated April 16, 1979 to
D. R. Goodwin, U. S. Environmental Protection Agency.
44. Walsh, J. P., Exxon Chemical Company USA, Baton Rouge, LA, Letter Dated
February 10, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
45. Smith, A. G., Shell Oil Company, Houston, TX, Letter Dated
February 22, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
46. Kuykendall, C. R., El Paso Products Company, Odessa, TX, Letter Dated
January 31, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
47. Berry, F. E., Gulf Oil Chemicals Company, St. James, LA, Letter Dated
January 27, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
48. New Jersey State Department of Environmental Protection, Division of
Environmental Quality, Report of Emission Test, N.J.D.E.P.,
I.D. No. 30147, May 28, 1986.
49. Scott, W. D., C. E. Bates, and R. H. James, Chemical Emissions from
Foundry Molds, Transactions of the American Foundrymen's Society,
Volume 86, 1978, pp. 203-208.
50. Taylor, L., Georgia Department of Natural Resources, Letter Dated
January 19, 1979 to M. M. Lowry, Section Chief, Air Quality Control
Section, Georgia Department of Natural Resources.
51. Entropy Environmentalists, Inc., Stationary Source Sampling Report EEI
Ref. No. 2549, Hexamethylenediamene Emissions Testing, T-37 Evaporator
Process Vent, July 3, 1984.
52. Tucker, T. N., Area Supervisor, Southwestern Ohio Air Pollution Control
Agency, Letter Dated May 22, 1986 to E. L. Martinez, Chief, Source
Analysis Section/AMTB, U. S. Environmental Protection Agency.
406
-------
53. Spicer, C. W., et al., Battelle Columbus Laboratories, Composition and
Photochemical Reactivity of Turbine Engine Exhaust, Report No. ESL-TR-
84-28, Prepared for Air Force Engineering and Services Center (RDVS),
Tyndall AFB, FL, September 1984.
54. Bond, A. E., et al., Self-Service Station Vehicle Refueling Exposure
Study, U. S. Environmental Protection Agency, Research Triangle Park,
NC, 1985, Presented at the 1986 EPA/APCA Symposium on Measurement of
Toxic Air Pollutants, Raleigh, NC, April 1986.
55. Earley, D. E., et al., Monsanto Research Corporation, Source Assessment:
Rail Tank Car, Tank Truck, and Drum Cleaning State of the Art,
Publication No. EPA-600/2-78-004g (NTIS No. PB 280726), April 1978,
P 4.4. *
56. Sigsby, J. E., Jr., et al., Volatile Organic Compound Emissions from
46 In-Use Passenger Cars, Environmental Science and Technology,
Volume 21, No. 5, 1987, pp. 466-475.
57. Renman, L., et al,, Determination of Isocyanate and Aromatic Amine
Emissions from Thermally Degraded Polyurethanes in Foundries, Am. Ind.
Hyg. Assoc. J., 4_7_(10), pp. 621-628, October 1986.
58. Compilation of Air Pollutant Emission Factors, Volume I: Stationary
Point and Area Sources, Fourth Edition, AP-42, U. S. Environmental
Protection Agency, Research Triangle Park, NC, September 1985.
59. Taback, H. J., et al., Control of Hydrocarbon Emissions from Stationary
Sources in the California South Coast Air Basin, Volume II, KVB, Inc.,
Tustin, CA, June 1978.
60. Sonnichsen, T. W., KVB Engineer.
61. Hughes, T. W., et al., Source Assessment: Prioritization of Air
Pollution from Industrial Surface Coating Operations, U. S.
Environmental Protection Agency, Publication No. EPA-650/2-75-019a (NTIS
No. PB 243423), February 1975.
62. Trijonas, J. C. and K. W. Arledge, Utility of Reactivity Criteria on
Organics Emission Control Strategies in the Metropolitan Los Angeles
AQCR, U. S. Environmental Protection Agency, Publication No. EPA-600/3-
76-091 (NTIS No. PB 257706), August 1976.
63. Pesticide Use Report, Annual 1976, Department of Food and Agriculture,
Agricultural Chemicals and Food.
64. Danielson, J. A., Air Pollution Engineering Manual, U. S. Environmental
Protection Agency, Research Triangle Park, NC, AP-40 (NTIS
No. PB 225132), May 1973. V
65. Mayrsohn, H. and J. Crabtree, Source Reconciliation of Atmospheric
Hydrocarbons in the South Coast Air Basin, 1975, California Air
Resources Board, December 1976.
407
-------
66. Zimmerman, P. R., Tampa Bay Area Photochemical Oxidant Study - Final
Appendix C: Determination of Emission Rates of Hydrocarbons from
Indigenous Species of Vegetation in the Tampa/St. Petersburg Area,
Publication No. EPA-904/9-77-028 (NTIS No. PB 297057/2), 1977.
. t
67. Bethea, Robert N., Solution for Feedlot Odor Control Problems, Journal
of APCA, Volume 22, No. 10, October 1972.
68. Horton, R. and D. Daniels, The Energy and Fertilizer Potential of
Natural Organic Wastes, June 1976.
69. Aschbacher, P. W., Air Pollution Research Needs Livestock Production
Systems, Journal of APCA, Volume 23, No. 4, April 1973.
70. Keller, R. H. and C. Cowherd, Identification and Measurement of
Atmospheric Organic Emissions from Natural and Quasi-Natural Sources,
Interim Report for EPA Contract No. 68-02-2524, July 1977.
71. Formica, P. N., Controlled and Uncontrolled Emission Rates and
Applicable Limitations for Eighty Processes, Prepared for U. S.
Environmental Protection Agency, OAQPS, Research Triangle Park, NC,
Publication No. EPA-340/1-78-004, April 1978.
72. Hydrocarbon Emissions from Fixed-Roof Petroleum Tanks, Engineering
Science, Inc., Sponsored by the Western Oil and Gas Association,
July 1977.
73. Sandberg, D. V., et a!., Emissions from Slash Burning and the Influence
of Flame Retardant Chemicals, J. Air Poll. Cont. Assoc., Volume 25,
No. 3, March 1975.
74. Black, F. and L. High, Diesel Hydrocarbon Emission - Particulate and Gas
Phase, Symp. of Diesel Particulate Emission Measurement and
Characterization, May 1978.
75. Springer, K. J. and T. M. Baines, Emissions from Diesel Versions of
Production Passenger Cars, Society of Automotive Engineers, Paper
No. 770818, September 26-30, 1977.
76. Butler, W. A. and M. B. Stockton, Engineering Judgement, Radian
Corporation, July 1987.
77. Residential Wood Heater Test Report, Tennessee Valley Authority
(Tables 6, 7, 13, 20, 27, and 33), Phase II Testing, Volume I, Energy
Use Test Facility, August 1983.
78. Allen, J. M., W. H. Piispanen, and M. Cooke, Study of the Effectiveness
of a Catalytic Combustion Device on a Wood Burning Appliance, Battelle
Columbus Labs, Ohio, Publication No. EPA-600/7-84-046 (NTIS No. PB84-
171545), March 1984, Table 6, page 22.
408
-------
79. DeAngelis, D. G., D. S. Ruffin, and R. B. Reznik, Preliminary
Characterization of Emissions from Wood-Fired Residential Combustion
Equipment, Interagency Energy/Environmental R&D Program Report,
Publication No. EPA-600/7-80-040 (NTIS No. PB80-182066), March 1980.
80. Leese, K. E. and S. M. Harkins, Integrated Air Cancer Project - Source
Measurement, Research Triangle Institute, March 1986.
81. Cottone, L. E. and E. Messer, Test Method Evaluations and Emissions
Testing for Rating Woodstoves, Publication No. EPA-600/2-86-100 (NTIS
No. PB87-119897), October 1986.
82. U. S. Environmental Protection Agency, Regional Air Pollution Study -
Point Source Emission Inventory, Publication No. EPA-600/4-77-014 (NTIS
No. PB 269567), March 1977.
83. Carey, P. and J. Cohen, Comparison of Gas Phase Hydrocarbon Emissions
from Light-Duty Gasoline Vehicles and Light-Duty Vehicles Equipped with
Diesel Engines, U. S. Environmental Protection Agency, Technical Report
CTAB/PA/80-5, September 1980.
84. Braddock, J. M. and R. L. Bradow, Emission Patterns of Diesel-Powered
Passenger Cars, Society of Automotive Engineers, Paper No. 750682,
June 3-5, 1975.
85. Data obtained from personal communication with Frank Black, U. S.
Environmental Protection Agency, July 1987.
86. Black, F. and L. High, Passenger Car Hydrocarbon Emissions Speciation,
Publication No. EPA-600/2-80-085, May 1980, page 5.
87. Black, F., et al., SAE Technical Paper, Emissions from In-Use Heavy-Duty
Gasoline Trucks, Presented at the Fuels and Lubricants Meeting and
Exposition, October 8-11, 1984, Baltimore, MD.
88. Carter, R. V. and B. Linsky, Gaseous Emissions from Whiskey Fermentation
Units, Atmospheric Environment, Volume 8, pp. 57-62, 1974.
89. Cronn, D. R., et al., Chemical Characterization of Plywood Veneer Dryer
Emissions, Atmospheric Environment, 8(2), pp. 201-211, 1983.
90. VOC species profiles developed by Radian Corporation from test program
(see Appendix G for details), September 1987.
91. Meeting Summary, Meeting with Safety-Kleen, Radian Corporation, and
U. S. Environmental Protection Agency, Research Triangle Park, NC.
November 12, 1986.
92. Organic Solvent Cleaners - Background Information for Proposed
Standards. EPA Report No. EPA-450/2-78-045a (NTIS No. PB80-137912).
U. S. Environmental Protection Agency, Research Triangle Park, NC.
October 1979.
409
-------
93. Shareef, G. S., Engineering Judgment, Radian Corporation, August 1987.
94. Braddock, J. M. and P. A. Gabele, Emission Patterns of Diesel-Powered
Passenger Cars, Part II, Society of Automotive Engineers, Paper
No. 770168, February 28-March 4, 1977.
95. Department of Ecology, State of Washington, Source Test Report 85-14,
Kaiser Aluminum and Chemical Corporation, September 24-26, 1985.
96. Viswanath, R.S. and O.H. Van Sandt. Oil Field Emissions of Volatile
Organic Compounds. EPA-450/2-89-007. Office of Air Quality Planning
and Standards, U.. S. Environmental Protection Agency, Research Triangle
Park, North Carolina. April 1989.
410
-------
APPENDIX A
LITERATURE SEARCH AND VOC SPECIES PROFILE DEVELOPMENT
-------
A-2
-------
APPENDIX A
LITERATURE SEARCH AND VOC SPECIES PROFILE DEVELOPMENT
This appendix briefly summarizes the literature search conducted in this
study and describes how new VOC profiles were developed from these data.
A.I LITERATURE SEARCH AND DATA REVIEW
Before conducting a literature search to collect new data, the 1980 Data
Manual was carefully reviewed to identify poor quality and/or outdated profile
data, and data gaps. The data confidence levels assigned to each profile in
the Data Manual were used as a criterion for poor quality. Profiles for the
following source categories were identified to be of poor quality: surface
coating, printing press, solvent use, solid waste incineration, petroleum
industry, chemical manufacturing, textiles, mineral products, and internal
combustion engines. Conversations with users of the Data Manual have helped
to identify outdated data (e.g., mobile sources, gasoline storage/marketing/
handling, and organic solvent usage).
The first step in data collection was to conduct a computerized
literature search of the Engineering Index, Chemical Abstracts, and National
Technical Information Services data bases. The key words (and several
combinations) used in the search included the following:
VOC
Volatile organic compound
Speciation
Organic species profiles
Profiles
Emission inventories (air)
Photochemical modeling
Chemical species distribution
Species
Particulate matter profiles
Volatile matter
Smog
Exhaust emissions
Gasoline motor vehicle emissions
Diesel motor vehicle emissions
Organic solvents
Hydrocarbon composition
Cleaningsolvents
Household (consumer) products
Asphalt
A-3
-------
PH10 Petroleum products
PH Textile industry
Particles Degreasing
Hydrocarbon emissions Vegetation
Reactive organic compounds Natural emissions
Reactive hydrocarbons Biogenic
The literature search efforts also focused on the following list of
toxic/potentially toxic air pollutants:
Arsenic Ethylene oxide
Asbestos Formaldehyde
Benzene Gasoline vapors
Beryllium Mercury
1,3-Butadiene Methylene chloride
Cadmium Perchloroethylene
Carbon tetrachloride Polycyclic organic matter
Chloroform Radionuclides
Chromium Trichloroethylene
Coke oven emissions Vinyl chloride
Ethylene dibromide Vinylidene chloride
Ethylene dichloride
Although no particulate matter (PM) profiles are contained in the interim
document, the computerized literature search efforts also included PM species.
Information identified relating to PM species will be used in the second phase
of this study.
One of the key references used in this study was a study conducted for
the California Air Resources Board (Improvement of the Emission Inventory for
Reactive Organic Gases and Oxides of Nitrogen in the South Coast Air Basin,
Reference 1). Other sources of information reviewed included the National
Acid Precipitation Assessment Program (NAPAP), Northeast Corridor Regional
Modeling Project (NECRMP), State data files, Atmospheric Sciences Research
A-4
-------
Laboratory, Environment Canada, and Section 114 responses and trip reports
from several standard development activities. See the References section for
a complete listing of references used to develop the new profiles. (This list
does not include the documents that were also reviewed but not found useful.)
A.2 VOC SPECIES PROFILE DEVELOPMENT
A.2.1 Profile Development Based on Existing Data
All data identified through the literature search efforts were used as
reported. No attempt was made to verify their completeness. Only those data
for which original documentation was available were included. The data used
in developing the profiles were available in different forms. Some of the
data were already expressed as weight percentages. In other cases,
calculations were necessary to convert from volumetric percentage (or mole
percentage) and emission flow rate (volumetric or mass rate) to weight
percentages.
For several cases, data available from a number of facilities/sources
were combined in proportion to the VOC emissions from each facility/source to
develop a composite profile. For example, in developing Profile 1070
(methanol production - purge gas vent), two sets of data each based on volume
percent were available. The first calculation consisted of conversion from
volume percent to weight percent. Assuming 100 Ib. moles of VOC gas mixture,
the weight of each species in the mixture was calculated by multiplying its
volume percent by its molecular weight. The weight percentages were
calculated by dividing the weight of each species by the total weight and
multiplying by 100. These calculations are summarized below:
Stream A Stream B
Species
Methanol
Dimethyl
ether
Molecular
Weiaht
32.04
46.10
Vol
%
0.20
1.72
Weight
Ib
6.41
79.29
Weight
%
0.39
4.78
Vol
2.62
12.08
Weight
Ib
83.94
556.89
Weight
%
4.18
27.72
Methane 16.04 98.08 1573.20 94.83 85.29 1368.05 68.10
1658.90 2008.88
A-5
-------
These two streams were combined in proportion to their VOC emissions to
develop Profile 1070. The VOC emission rates for Stream A and B were
1059 Ib/hr and 462 Ib/hr, respectively. The data for Stream A were weighted
by a factor of [1059/(1059 + 462)] = 0.6963 and for Stream B were weighted by
a factor of [462/(1059 + 462)] = 0.3037 as shown below:
Composite Data:
Species Weight %
Methanol (0.39 x 0.6963) + (4.18 x 0.3037) - 1.54
Dimethyl ether (4.78 x 0.6963) + (27.72 x 0.3037) = 11.75
Methane (94.83 x 0.6963) + (68.10 x 0.3037) = 86.71
In a few cases, developing profiles and composite profiles was based on
more complex calculations. Section A.2.2 provides a documentation of the
procedures that were required to develop profiles for light-duty gasoline
vehicles.
A.2.2 Documentation of the Mobile Source Profile Development Procedures
The purpose of this section is to provide a description of the
calculation procedures used to develop VOC speciation profiles for the Light-
Duty Gasoline Vehicles (LD6V) category. The specific profiles of concern are
1101, 1203, and 1204. The Light-Duty Gasoline Vehicles Profile 1101 was
developed using the 46 in-use passenger car study conducted by Sigsby, et al.1
Exhaust and evaporative (hot soak) emission composition data collected during
this study were composited using information from AP-42, Volume II (fourth
edition).2 Data generated by Sigsby, et al did not contain measurements of
diurnal emission composition. Therefore, diurnal emission composition data
were estimated using data from a study by Black and High and another study by
Gabele.3-*
The data set from the 46-car study was representative of in-use vehicles
from 1975 to 1982. For model years prior to 1975 and after 1982, it was
A-6
-------
assumed that the data for model years 1975 and 1982, respectively, would be
representative.
In developing Profile 1101, average exhaust and evaporative emission
profiles for each model year were weighted according to the exhaust and
evaporative hydrocarbon emission rates reported in AP-42 for light duty
gasoline vehicles - low altitude (includes tampering). Then, the composite
profile for each calendar year was weighted in proportion to the travel
fraction for that model year to yield Profile 1101. The travel fractions were
calculated using the information in AP-42. The calculation procedure used for
Profile 1101 is illustrated below.
(a) For each car, estimate average exhaust emission composition from
the Federal Test Procedures (FTP), New York City Cycle (NYCC), and
Crowded Urban Expressway (CUE) test data:
Exhaust average car = (FTP + NYCC + CUE)/3
(b) For each model year, calculate average exhaust emission
composition:
n
Exhaust average model year = fml exhaust average car/n
where n is the number of cars tested for a given model year.
(c) For each model year, calculate average hot soak evaporative
composite:
n
Hot soak average model year = fml hot soak car/n
(d) Estimate an average diurnal evaporative composition using the data
from References 3 and 4. Assume this represents all model years.
(e) For each model year, estimate average evaporative emission
composition:
Evaporative average model year = (0.265 x hot soak average model
year + 0.735 x average diurnal)/2
The weighting factors 0.265 and 0.735 were estimated from
Reference 5.
A-7
-------
(f) Estimate weighting factors for exhaust and evaporative emissions
for model years 1968-1987. Use AP-42 (pp. H-4,6) for LDGV at low
altitude (including tampering).
estimate accumulated mileage
estimate evaporative emissions
estimate exhaust emissions
estimate fraction of evaporative emissions (fev)
estimate fraction of exhaust emissions (fej
(g) Estimate weighted average exhaust/evaporative emission composition
for each model year:
Exhaust/evaporative average model year =
fex(exhaust average model year) + fev(evaporative average model year)
(h) Estimate travel fraction (ftr) for each model year from 1968-1987.
Use the procedure in AP-42 (pp. H-11,12).
(i) Weight the profiles from (g) by travel fractions estimated in (h).
1987
Profile 1101 = 1968 ftr model year x (Exhaust/evaporative
average model year)
In the profile data, 15 percent of n-butane in exhaust emissions was assumed
to exist as 1,3-butadiene.6'7 Also, the split between cyclohexane and benzene
in the cyclohexane/benzene peak was assumed as 50/50.8
FACTORS USED IN DEVELOPING PROFILE 1101
Year fex fev ftr
1968
1969
1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
.67
.67
.68
.71
.72
.72
.72
.70
.69
.68
.84
.83
.33
, .33
.32
.29
.28
.28
.28
.30
.31
.32
.16
.17
.004
.003
.005
.007
.011
.016
.021
.028
.034
.041
.049
.056
A-8
-------
FACTORS USED IN DEVELOPING PROFILE 1101
(Continued)
Year ffx fev ftr
1980
1981
1982
1983
1984
1985
1986
1987
.69
.66
.63
.60
.56
.50
.40
.33
.31
.34
.37
.40
.44
.50
.60
.67
.065
.074
.084
.097
.110
.123
.135
.038
fex = exhaust average model year emission composition.
fev = evaporative average model year emission
composition.
ftr = travel fraction for each model year.
The approach used for developing Profiles 1203 and 1204 to represent
exhaust and evaporative emissions, respectively, from light-duty vehicles was
similar to that used for Profile 1101. For Profile 1203, steps (c), (d), (e),
(f), and (g) outlined for Profile 1101 were not applied. Step (i) was applied
after the exhaust average model year term replaced the exhaust/evaporative
average model year term. For Profile 1204, steps (a), (b), (f), and (g) were
not applied. In the final step (i), the exhaust/evaporative average model
year term was replaced by the evaporative average model year and the ftr model
year term was applied to only the hot soak average model year position.
Table A-l provides a numerical listing of new profiles contained in this
document including the profile name and its location in this volume.
A.2.3 Profile Development Based on Engineering Judgement
Pure Component Profiles - For several categories representing storage of
pure organic chemicals or use of pure solvents in operations such as dry
cleaning, degreasing, or surface coating, new VOC profiles were developed
using engineering judgement. In all cases, these profiles consisted of a
single species with a weight percent of 100.
A-9
-------
Industry-Specific Average Profiles - In characterizing SCC's with
profile assignments, there were several instances where it was difficult to
make profile assignments based on engineering judgement. For such SCC's,
industry-specific average profiles were developed from original profiles
representing other SCC's within the particular industry group. These profiles
have profile numbers beginning with 9 and they are assigned a data quality
level of "E." The industry-specific average profiles are recommended for use
only if no other information is available. These profiles are presented in
Appendix B.
"Zero" Profile - Profile 0000 is an overall average of all the VOC
profiles in the data base. It is intended for use as a default profile in
emission inventory development applications to characterize nonzero VOC
emissions reported for SCC's that are associated with "zero" or "negligible"
VOC emission factors. The SCC's with "zero" or "negligible" VOC emission
factors are based on the document "Emission Factors for the 1985 NAPAP
Emissions Inventory" (EPA-600/7-87-015).
A-10
-------
REFERENCES FOR APPENDIX A
1. Sigsby, J. E., Jr. et al. Volatile Organic Compound Emissions from 46
In-Use Passenger Cars. Environmental Science and Technology, Volume 21,
No. 5, 1987. pp. 466-475.
2. U. S. Environmental Protection Agency. Compilation of Air Pollutant
Emission Factors, Volume II -'Mobile Sources, AP-42 (fourth edition).
September 1985.
3. Black, F. and L. High. Passenger Car Hydrocarbon Emissions Speciation.
EPA Report No. EPA-600/2-80-085. U. S. Environmental Protection Agency,
Research Triangle Park, North Carolina. May 1980.
4. Telecon. Gunseli Shareef, Radian Corporation with P. A. Gabele, U. S.
Environmental Protection Agency. July 1987. Diurnal emission
composition data.
5. Black, F. HC Emissions from Late Model Gasoline Motor Vehicles. U. S.
Environmental Protection Agency, Research Triangle Park, North Carolina.
1987.
6. Memorandum from John E. Sigsby, Jr., U. S. Environmental Protection
Agency/Atmospheric Sciences Research Laboratory to John Summerhays,
U. S. Environmental Agency/Region 5. January 30, 1987. Review of
report "Air Toxics Emission Inventory for the Southeast Chicago Area".
7. Telecon. Gunseli Shareef, Radian Corporation with Penny Carey, U. S.
Environmental Protection Agency/Office of Mobile Sources. March 24,
1987. Percentage of 1,3-butadiene in vehicle emissions where it is
reported as n-butane/ 1,3-butadiene.
8. Memorandum from Gray, C. L., U. S. Environmental Protection Agency to J.
Calcagni, U. S. Environmental Protection Agency and W. Laxton, U. S.
Environmental Protection Agency. March 23, 1989. Motor Vehicle VOC
Speciation for SIP Development.
A-ll
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A-22
-------
APPENDIX B
INDUSTRY-SPECIFIC AVERAGE PROFILES AND "ZERO" PROFILE
-------
B-2
-------
APPENDIX B
INDUSTRY-SPECIFIC AVERAGE PROFILES AND "ZERO" PROFILE
This appendix contains the industry-specific average profiles developed
from original profiles representing specific SCC's within the particular
industry group. These profiles are recommended for use only if no other
information is available. Since there is no specific SCC associated with
these profiles, the entry for SCC designation on the profile is modified as
"no original SCC."
This appendix also contains Profile 0000 which is an overall average of
all the VOC profiles in this document. This profile is intended for use as a
default profile to characterize nonzero VOC emissions reported by States or
any other agency for SCC's with "zero" or "negligible" VOC emission factors in
the "Criteria Pollutant Emission Factors for the 1985 NAPAP Emissions
Inventory" (EPA-600/7-87-015).
A numerical listing of the profiles included in this appendix is given
below:
Profile Number Profile Name
0000 Overall Average
9001 External Combustion Boilers - Industrial - Average
9002 Internal Combustion - Average
9003 Industrial Processes - Average
9004 Chemical Manufacturing - Average
9005 Plastics Production - Average
9006 Synthetic Organic Fiber Production - Average
9007 Alcohols Production - Average
9008 Food and Agriculture - Average
9009 Primary Metal Production - Average
B-3
-------
Profile Number
9010
9011
9012
9013
9014
9015
9016
9017
9021
9022
9023
9024
9025
9026
9027
9028
9029
9030
9031
9032
9033
Profile Name
Secondary Metal Production - Average
Mineral Products - Average
Petroleum Industry - Average
Pulp and Paper Industry - Average
Rubber and Miscellaneous Plastics Products
Average
Oil and Gas Production - Average
Textile Products - Average
Drycleaning/Degreasing - Average
Surface Coating Operations - Average
Solid Waste Disposal - Average
Thinning Solvents - Average
Petroleum Product Storage - Average
Bulk Terminals - Petroleum Storage Tanks -
Average
Printing/Publishing - Average
Transportation and Marketing of Petroleum
Products - Average
Organic Chemical Storage - Average
Organic Chemical Storage - Fixed Roof Tanks
Alcohols - Average
Organic Chemical Storage - Fixed Roof Tanks
Alkanes - Average
Organic Chemical Storage - Fixed Roof Tanks
Ikenes - Average
Organic Chemical Storage - Fixed Roof Tanks
Amines - Average
Organic Chemical Storage - Fixed Roof Tanks
Aromatics - Average
B-4
-------
Profile Number Profile Name
9°34 Organic Chemical Storage - Fixed Roof Tanks
Carboxylic Acids - Average
9035 Organic Chemical Storage - Fixed Roof Tanks
Esters - Average
9°36 Organic Chemical Storage - Fixed Roof Tanks
Glycol Ethers - Average
9°37 Organic Chemical Storage - Fixed Roof Tanks
Glycols - Average
9°38 Organic Chemical Storage - Fixed Roof Tanks
Halogenated Organics - Average
9039 Organic Chemical Storage - Fixed Roof Tanks
Isocyanates - Average
9040 Organic Chemical Storage - Fixed Roof Tanks
Ketones - Average
9041 Organic Chemical Storage - Floating Roof
Tanks - Aldehydes - Average
9042 Organic Chemical Storage - Floating Roof
Tanks - Alkanes - Average
9043 Organic Chemical Storage - Floating Roof
Tanks - Ethers - Average
9°44 Organic Chemical Storage - Floating Roof
Tanks - Halogenated Organics - Average
9045 Organic Chemical Storage - Pressure Tanks -
Alkenes - Average
Organic Solvent Evaporation - Miscellaneous
Average
B-5
-------
VOC Profile Speciation Report
Profile Name External Combustion Boilers - Industrial
Profile Number 9001
Data Quality E
- Average
Control Device Not Applicable
Reference(s) 93
Data Source Average profile developed from original profiles
representing
the source category 102XXXXX
SCC Assignments:
Saroad
43105
43106
43107
43122
43140
43201
43202
43203
43204
43205
43206
43212
43213
43214
43215
43220
43221
43231
43232
43247
43248
43262
43263
43502
43551
45201
45202
45203
45204
90010
TOTAL
========:
CAS Number
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
106-97-8
106-98-9
75-28-5
115-11-7
109-66-0
78-78-4
110-54-3
142-82-5
108-08-7
110-82-7
96-37-7
591-76-4
50-00-0
67-64-1
71-43-2
108-88-3
100-41-4
95-47-6
=====================
Name
ISOHERS OF HEXANE
ISOHERS OF HEPTANE
ISOHERS OF OCTANE
ISOHERS OF PENTANE
C7-C16 PARAFFINS
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
N-BUTANE
BUTENE
ISO-BUTANE
ISOBUTYLENE
N-PEMTANE
ISO PENTANE
HEXANE
HEPTANE
2,4-DIMETHYLPENTANE
CYCLOHEXANE
METHYLCYCLOPENTANE
2-METHYL HEXANE
FORMALDEHYDE
ACETONE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
=============================
Spec_MU
86.17
100.20
114.23
72.15
156.31
16.04
30.07
28.05
44.09
42.08
26.04
58.12
56.10
58.12
56.10
72.15
72.15
86.17
100.20
100.20
84.16
84.16
100.20
30.03
58.08
78.11
92.13
106.16
106.16
106.16
============:
Spec_UT Peak
0.89
0.37
0.67
2.07
5.62
25.35
11.41
1.67
4.19
2.65
2.32
9.24
0.87
1.64
0.00
1.98
0.18
3.37
0.04
0.00
0.14
0.41
0.00
15.19
4.00
1.38
1.48
0.81
0.37
1.68
99.99
=================
B-6
-------
VOC Profile Speciation Report
Profile Name
Internal
Combustion - Average
Profile Number 9002
Data Quality
E
Control Device Not Applicable
Reference(s)
Data Source
93
Average
sent ing
profile developed from original
source category 2XXXXXXX.
profiles repre-
SCC Assignments:
Saroad
43105
43106
43107
43108
43109
43120
43122
43124
43125
43201
43202
43203
43204
43205
43206
43212
43213
43214
43215
43216
43217
43218
43220
43224
43226
43228
43230
43231
43232
43233
43235
43238
43241
43242
43247
43248
43261
43262
43264
43265
43269
CAS Number
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
106-97-8
106-98-9
75-28-5
115-11-7
624-64-6
590-18-1
106-99-0
109-66-0
109-67-1
646-04-8
513-35-9
96-14-0
110-54-3
142-82-5
111-65-9
111-84-2
124-18-5
1120-21-4
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
111-66-0
124-11-8
Name
ISOHERS OF HEXANE
ISOHERS OF HEPTANE
ISOHERS OF OCTANE
ISOMERS OF NONANE
ISOHERS OF DECANE
ISOHERS OF BUTENE
ISOHERS OF PENTANE
C9 OLEFINS
C10 OLEFINS
HETHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
N-BUTANE
BUTENE
I SO- BUTANE
ISOBUTYLENE
T-2-BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N -PENTANE
1-PENTENE
TRANS-2-PENTENE
2-METHYL-2-BUTENE
3-HETHYL PENTANE
HEXANE
HEPTANE
OCTANE
NONANE
N-DECANE
N-UNOECANE
CYCLOPENTANE
2,4-DIHETHYLPENTANE
CYCLOHEXANE
METHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
HEPTENE
OCTENE
1-NONENE
Spec_MU
86.17
100.20
114.23
128.25
142.28
56.10
72.15
126.24
140.27
16.04
30.07
28.05
44.09
42.08
26.04
58.12
56.10
58.12
56.10
56.11
56.11
54.09
72.15
70.13
70.13
70.13
86.17
86.17
100.20
114.23
128.25
142.28
156.31
70.14
100.20
84.16
98.21
84.16
98.18
112.21
126.24
Spec_WT Peak
0.01
0.01
0.01
0.00
0.01
0.07
0.03
0.01
0.01
42.46
4.90
14.51
0.73
9.07
5.73
0.25
6.70
0.11
0.01
0.03
0.01
3.50
0.03
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.00
0.00
0.00
0.01
0.00
0.00
0.01
0.01
0.00
0.00
0.00
8-7
-------
VOC Profile Speciation Report - continued (profile 9002)
Saroad
43291
43295
43298
43502
43503
43511
45102
45109
45110
45201
45202
45203
45204
45205
45207
45208
45211
45212
45225
98040
TOTAL
CAS Nunber
75-83-2
589-34-4
50-00-0
75-07-0
78-84-2
1330-20-7
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
108-67-8
95-63-6
611-14-3
620-14-4
526-73-8
763-29-1
Name
2,2-DIHETHYLBUTANE
3-HETHYLHEXANE
3-NETHYLHEPTANE
FORMALDEHYDE
ACETALDEHYOE
I SOBUTYR ALDEHYDE
ISOHERS OF XYLENE
C3/C4/C5 ALKYLBENZENES
CIO AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
1,3,5-TRIMETHYLBENZENE
1,2,4-TRIMETHYLBENZENE
0-ETKYLTOLUENE
M-ETHYLTOLUENE
1,2,3-TRIMETHYLBENZENE
2-HETHYL-1-PENTENE
Spec_HU
86.17
100.20
114.23
30.03
44.05
72.11
106.16
134.21
134.22
78.11
92.13
106.16
106.16
106.16
120.19
120.19
120.19
120.19
120.19
84.16
~"~~===Z==:3::~SS~
Spec_WT Peak
0.00
0.00
0.01
7.70
0.01
0.01
0.01
0.00
0.00
3.98
0.01
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.01
100.02
B-8
-------
VOC Profile Speciation Report
Profile Name Industrial Processes - Average
Profile Number 9003
Data Quality E
Control Device Not Applicable
Referenced) 93
Data Source Average profile developed from original
sent ing the source category 3XXXXXXX.
SCC Assignments:
Saroad CAS Number Name
43105 ISOMERS OF HEXANE
43106 ISOMERS OF HEPTANE
43107 ISOMERS OF OCTANE
43108 ISOMERS OF NONANE
43109 . ISOMERS OF DECANE
43111 ISOMERS OF DODECANE
43113 ISOMERS OF TETRADECANE
43115 C-7 CYCLOPARAFFINS
43116 c-8 CYCLOPARAFFINS
43117 c-9 CYCLOPARAFFINS
43118 64475-85-0 MINERAL SPIRITS
43120 ISOMERS OF BUTENE
43121 ISOMERS OF PENTENE
43122 ISOMERS OF PENTANE
43130 C5 SUBSTITUTED CYCLOHEXANE
43131 C6 SUBSTITUTED CYCLOHEXANE
43132 ALIPHATICS
43133 PARAFFINS (C16-C34)
43134 PARAFFINS/OLEFINS (C12-C16)
43201 74-82-8 METHANE
43202 74-84-0 ETHANE
43203 74-85-1 ETHYLENE
43204 74-98-6 PROPANE
43205 115-07-1 PROPENE
43206 74-86-2 ACETYLENE
43212 106-97-8 N-BUTANE
43213 106-98-9 BUTENE
43214 75-28-5 I SO- BUTANE
43218 106-99-0 1,3-BUTADIENE
43220 109-66-0 N-PENTANE
43221 78-78-4 ISO PENTANE
43224 109-67-1 1 -PENTENE
43231 110-54-3 HEXANE
43232 142-82-5 HEPTANE
43233 111-65-9 OCTANE
43235 111-84-2 NONANE
43238 124-18-5 N-DECANE
43241 1120-21-4 N-UNDECANE
43242 287-92-3 CYCLOPENTANE
43245 592-41-6 1-HEXENE
43248 110-82-7 CYCLOHEXANE
profiles repre-
Spec_MU
86.17
100.20
114.23
128.25
142.28
170.32
198.38
98.19
112.23
126.26
114.00
56.10
70.13
72.15
154.30
168.32
100.00
352.43
197.38
16.04
30.07
28.05
44.09
42.08
26.04
58.12
56.10
58.12
54.09
72.15
72.15
70.13
86.17
100.20
114.23
128.25
142.28
156.31
70.14
84.16
84.16
Spec_WT Peak
1.11
0.39
0.29
0.04
0.02
0.10
0.03
1.87
0.14
0.02
0.41
0.09
0.01
1.75
0.04
0.03
0.20
0.04
0.00
9.02
1.80
5.94
4.85
2.09
1.59
2.49
0.45
0.53
0.61
1.01
0.03
0.04
1.14
0.65
0.17
0.05
0.09
0.08
0.03
0.06
0.77
B-9
-------
VOC Profile Speciation Report - continued (profile 9003)
Saroad
43255
43256
43257
43262
43301
43302
43304
43305
43306
43314
43317
43318
43330
43350
43351
43367
43403
43404
43408
43430
43432
43433
43435
43438
43440
43441
43453
43454
43455
43456
43457
43460
43461
43462
43463
43464
43465
43466
43467
43470
43502
43503
43505
43510
43520
43551
43552
43560
43561
43601
43602
43603
CAS Number
112-40-3
80-56-8
127-91-3
96-37-7
67-56-1
64-17-5
67-63-0
71-36-3
78-83-1
78-92-2
108-93-0
104-76-7
123-51-3
115-10-6
60-29-7
111-46-6
64-18-6
64-19-7
57-10-3
107-31-3
79-20-9
141-78-6
138-22-7
140-88-5
141-32-2
80-62-6
108-05-4
112-39-0
124-10-7
112-61-8
109-87-5
111-82-0
50-00-0
75-07-0
107-02-8
123-72-8
67-64-1
78-93-3
108-10-1
108-94-1
75-21-8
75-56-9
108-31-6
Name
N-DOOECANE
A-PINENE
B-PINENE
HETHYLCYCLOPENTANE
METHYL ALCOHOL
ETHYL ALCOHOL
ISO-PROPYL ALCOHOL
H-BUTYL ALCOHOL
IS08UTYL ALCOHOL
S-BUTYL ALCOHOL
CYCLOHEXANOL
2-ETHYL HEXANOL
ISOAMYL ALCOHOL
DIHETHYLETHER
ETHYL ETHER
GLYCOL ETHER
FORMIC ACID
ACETIC ACID
PALMITIC ACID
METHYL FORMATE
METHYLACETATE
ETHYL ACETATE
N-BUTYL ACETATE
ETHYL ACRYLATE
BUTYL ACRYLATE
METHYL METHACRYLATE
VINYL ACETATE
METHYL PALMITATE
METHYL HYRISTATE
METHYL STEARATE
METHYLAL
METHYL C11 ESTER
METHYL C12 ESTER
METHYL C13 ESTER
METHYL C14 ESTER
METHYL C15 ESTER
METHYL C19 ESTER
METHYL C20 ESTER
C4 SUBSTITUTED CYCLOHEXANONE
METHYL DODECANOATE
FORMALDEHYDE
ACETALDEHYDE
ACROLEIN
BUTYRALDEHYDE
TOTAL C2-C5 ALDEHYDES
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
CYCLOHEXANONE
ETHYLENE OXIDE
PROPYLENE OXIDE
MALEIC ANHYDRIDE
Spee_MW
170.33
136.24
136.24
84.16
32.04
46.07
60.09
74.12
74.12
74.12
100.16
130.23
88.15
46.07
74.12
106.14
46.03
60.05
256.43
60.05
74.08
88.10
116.16
100.11
128.17
100.13
86.09
270.46
242.41
298.52
76.11
214.35
228.37
242.40
256.43
270.45
326.56
340.59
154.26
214.35
30.03
44.05
56.07
72.12
72.12
58.08
72.10
100.16
98.15
44.05
58.08
98.06
Spec_WT Peak
0.19
0.53
0.35
0.52
1.95
1.12
0.41
0.75
0.00
1.01
0.10
0.00
0.00
2.82
0.38
0.03
0.07
0.98
0.40
0.66
0.92
0.00
0.04
0.36
0.15
0.29
1.64
0.17
0.06
0.22
0.25
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.02
0.00
1.82
1.24
1.20
0.01
0.24
1.82
1.27
0.17
0.10
0.05
0.01
0.20
B-10
-------
VOC Profile Speciation Report - continued (profile 9003)
Saroad
43604
43650
43704
43776
43780
43801
43803
43804
43805
43811
43812
43815
43821
43822
43823
43838
43839
43840
43841
43842
43843
43844
43845
43860
43862
43933
43934
43950
43951
45102
45106
45107
45109
45201
45202
45203
45204
45205
45206
45210
45220
45226
45227
45228
45229
45230
45232
45233
45300
45310
45311
45401
CAS Number
108-24-7
107-13-1
124-09-4
74-87-3
67-66-3
56-23-5
74-95-3
75-69-4
75-00-3
107-06-2
76-13-1
75-71-8
26638-19-7
75-73-0
75-45-6
76-14-2
76-15-3
76-16-4
75-46-7
75-72-9
75-01-4
126-99-8
433-58-1
75-15-0
556-67-2
1330-20-7
25551-13-7
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
106-42-3
98-82-8
100-42-5
92-52-4
1321-74-0
103-29-7
108-95-2
Name
ACETIC ANHYDRIDE
OXYGENATES
ACRYLONITRILE
HEXAHETHYLENED I AM I NE
DIMETHYL ALKYL AMINES
METHYL CHLORIDE
CHLOROFORM
CARBON TETRACHLORIDE
METHYLENE BROMIDE
TRICHLOROFLUOROMETHANE
ETHYL CHLORIDE
ETHYLENE D I CHLORIDE
TRI CHLOROTR I FLUOROETHANE
TR IMETHYL FLUOROS I LANE
D I CHLOROD I FLUOROMETHANE
PROPYLENE DICHLORIDE
TETRAFLUOROMETHANE
CHLORODI FLUOROMETHANE
DICHLOROTETRAFLUORETHANE
CHLOROPENTAFLUOROETHANE
HEXAFLUOROETHANE
TRI FLUOROMETHANE
CHLOROTR I FLUOROMETHANE
VINYL CHLORIDE
CHLOROPRENE
CARBONYL SULFIDE
CARBON SULFIDE
OCTAMETHYLCYCLOTETRAS I LOXANE
SILOXANE
ISOMERS OF XYLENE
ISOHERS OF DIETHYLBENZENE
TRIMETHYLBENZENE
C3/C4/C5 ALKYLBENZENES
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
CUMENE (ISOPROPYL BENZENE)
STYRENE
BIPHENYL
METHYL BIPHENYL
ETHYL STYRENE
D I VINYL BENZENE
DKETHYLPHENYL) ETHANE
DIPHENYL ETHANE
ETHYL-PHENYL-PHENYL-ETHANE
PHENOL
C8 PHENOLS
C9 PHENOLS
XYLENE BASE ACIDS
Spec.MW
102.09
86.00
53.06
116.20
59.11
50.49
119.39
153.84
173.85
137.38
64.52
99.00
187.38
92.00
120.91
112.99
88.01
86.47
170.92
154.47
138.01
70.01
104.46
62.50
88.54
60.08
76.13
296.62
76.08
106.16
134.21
120.19
134.21
78.11
92.13
106.16
106.16
106.16
106.16
120.20
104.14
154.21
168.24
132.21
130.20
238.37
182.27
210.32
94.11
122.16
136.19
230.00
Spec_WT Peak
0.06
0.01
0.64
1.01
0.00
0.01
0.03
0.20
0.10
0.77
0.85
1.68
0.06
1.75
1.06
0.06
0.10
0.48
0.04
0.05
1.20
0.91
0.16
1.07
1.01
0.09
0.27
0.02
0.01
0.18
0.04
0.09
0.06
7.05
1.49
0.43
0.16
0.07
0.03
0.00
3.01
0.03
0.00
0.06
0.01
0.00
0.01
0.02
1.09
0.00
0.00
0.01
B-ll
-------
VOC Profile Speciation Report - continued (profile 9003)
Saroad
45402
45403
45450
45451
45452
45454
45455
45470
45501
45601
45604
45701
45702
45703
45704
45705
45730
45740
45801
45805
45806
45807
45808
45830
45831
46102
46103
46111
46112
46114
46701
46702
46703
46711
90050
90051
90052
90053
98063
98083
99933
99999
TOTAL
XSXSSSSKSS;
CAS Number
65-85-0
100-21-0
120-61-6
131-11-3
84-74-2
131-16-8
136-60-7
100-52-7
85-44-9
98-00-0
62-53-3
98-95-3
1817-73-8
101-68-8
108-90-7
95-50-1
541-73-1
106-46-7
2531-22-6
84-65-1
82-45-1
101-77-9
103-71-9
100-61-8
91-12-3
28804-88-8
5794-03-6
123-35-3
5989-27-5
Name
BENZOIC ACID
TEREPHTHALIC ACID
DIMETHYL TEREPHTHALATE
DIMETHYL PHTHALATE
D I BUTYL PHTHALATE
DIPROPYL PHTHALATE
BUTYL BEHZOATE
DI-C8 ALKYL PHTHALATE
BENZALDEHYDE
PHTHALIC ANHYDRIDE
FURFUSYL ALCOHOL
ANILINE
NITROBENZENE
2,2 DICHLORONITROANILINE
BROMODINITROANILINE
BROHODINITROBENZENE
METHYLENE(b)4-PHENYLISOCYANATE
TOTAL AROMATIC AMINES
CHLOROBENZENE
0-D I CHLOROBENZENE
H-D I CHLOROBENZENE
P-DICHLOROBENZENE
DICHLOROBENZENES
TRICHLOROBENZENES
TETRACHLOROBENZENES
ANTHRAQUINONE
AMINOANTHRAQUINONE
4,4-METHYLENE DIANILINE
PHENYL ISOCYANATE
4-METHYLANILINE
NAPTHALENE
METHYL NAPHTHALENES
DIMETHYL NAPTHALENE
C2 ALKYL INDAN
CAMPHENE
MYRCENE
B-PHELLANORENE
D-LIMONENE
N-PENTYLCYCLOHEXANE
TRIMETHYLDECENE
DENATURANT
UNIDENTIFIED
Spec_MU
122.13
166.14
194.19
194.19
278.35
250.30
178.23
390.56
106.13
148.12
98.10
93.13
123.11
207.02
262.03
247.02
250.27
93.13
112.56
147.01
147.01
147.01
147.01
181.45
215.90
208.23
223.23
198.17
119.13
107.17
128.17
142.20
156.23
146.23
136.24
136.24
136.24
136.24
154.30
182.35
32.04
86.00
Spec_WT Peak
0.12
0.01
0.00
0.12
0.01
0.00
0.43
0.01
0.05
0.61
0.00
0.72
0.00
0.04
0.00
0.02
0.00
0.07
2.01
0.10
0.01
2.15
0.06
0.03
0.00
0.03
0.00
0.00
0.24
0.06
0.09
0.11
0.01 .
0.11
0.01
0.02
0.02
0.08
0.02
0.06
0.29
0.20
100.05
sss: =:=============
B-12
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Chemical
9004
E
Manufacturing - Average
Not Applicable
93
Average
sent ing
profile developed from original
the source category 301XXXXX
profiles repre-
SCC Assignments: 30113799
Saroad CAS Number
43105
43115
43116
43118 64475-85-0
43120
43122
43201
43202
43203
43204
43205
43206
43212
43213
43214
43220
43221
43224
43231
43245
43248
43262
43301
43302
43304
43305
43314
43317
43350
43351
43367
43403
43404
43430
43432
43435
43438
43440
43441
43453
43457
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
106-97-8
106-98-9
75-28-5
109-66-0
78-78-4
109-67-1
110-54-3
592-41-6
110-82-7
96-37-7
67-56-1
64-17-5
67-63-0
71-36-3
78-92-2
108-93-0
115-10-6
60-29-7
111-46-6
64-18-6
64-19-7
107-31-3
79-20-9
138-22-7
140-88-5
141-32-2
80-62-6
108-05-4
109-87-5
Name
ISOMERS OF HEXANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
MINERAL SPIRITS
ISOMERS OF BUTENE
ISOMERS OF PENTANE
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
N- BUTANE
BUTENE
I SO- BUTANE
N-PENTANE
ISO PENTANE
1-PENTENE
HEXANE
1-HEXENE
CYCLOHEXANE
HETHYLCYCLOPENTANE
METHYL ALCOHOL
ETHYL ALCOHOL
1SO-PROPYL ALCOHOL
N- BUTYL ALCOHOL
S-BUTYL ALCOHOL
CYCLOHEXANOL
DIMETHYLETHER
ETHYL ETHER
GLYCOL ETHER
FORMIC ACID
ACETIC ACID
METHYL FORMATE
METHYLACETATE
N- BUTYL ACETATE
ETHYL ACRYLATE
BUTYL ACRYLATE
METHYL HETHACRYLATE
VINYL ACETATE
METHYLAL
Spec_HU
86.17
98.19
112.23
114.00
56.10
72.15
16.04
30.07
28.05
44.09
42.08
26.04
58.12
56.10
58.12
72.15
72.15
70.13
86.17
84.16
84.16
84.16
32.04
46.07
60.09
74.12
74.12
100.16
46.07
74.12
106.14
46.03
60.05
60.05
74.08
116.16
100.11
128.17
100.13
86.09
76.11
Spec_WT Peak
0.12
1.75
0.03
0.61
0.13
0.05
5.07
1.38
8.29
3.45
2.67
2.14
1.34
0.37
0.07
0.24
0.05
0.02
0.06
0.08
0.86
0.00
2.92
0.18
0.61
1.12
1.52
0.16
4.22
0.57
0.05
0.10
1.47
0.99
1.38
0.06
0.54
0.22
0.43
2.46
0.38
B-13
-------
VOC Profile Speciation Report - continued (profile 9004)
Saroad
43502
43503
43505
43510
43551
43552
43560
43561
43601
43602
43603
43604
43704
43776
43801
43803
43804
43805
43811
43812
43815
43821
43823
43838
43839
43840
43841
43842
43843
43844
43845
43860
43862
43933
43934
45102
45106
45201
45202
45203
45204
45206
45210
45220
45300
45401
45402
45403
45450
45501
45601
45702
CAS Nunfcer
50-00-0
75-07-0
107-02-8
123-72-8
67-64-1
78-93-3
108-10-1
108-94-1
75-21-8
75-56-9
108-31-6
108-24-7
107-13-1
124-09-4
74-87-3
. 67-66-3
56-23-5
74-95-3
75-69-4
75-00-3
107-06-2
76-13-1
75-71-8
26638-19-7
75-73-0
75-45-6
76-14-2
76-15-3
76-16-4
75-46-7
75-72-9
75-01-4
126-99-8
433-58-1
75-15-0
1330-20-7
71-43-2
108-88-3
100-41-4
95-47-6
106-42-3
98-82-8
100-42-5
108-95-2
65-85-0
100-21-0
120-61-6
100-52-7
85-44-9
98-95-3
Name
FORMALDEHYDE
ACETALDEHYDE
ACROLEIN
BUTYRALDEHYDE
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
CYCLOHEXANONE
ETHYLENE OXIDE
PROPYLENE OXIDE
MALEIC ANHYDRIDE
ACETIC ANHYDRIDE
ACRYLONITRILE
HEXAMETHYLENEDIAMINE
METHYL CHLORIDE
CHLOROFORM
CARBON TETRACHLORIDE
METHYLENE BROMIDE
TR I CHLOROFLUOROMETHANE
ETHYL CHLORIDE
ETHYLENE DICHLORIDE
TRICHLOROTRIFLUOROETHANE
D I CHLOROD I FLUOROMETHANE
PROPYLENE DICHLORIDE
TETRAFLUOROMETHANE
CHLOROD I FLUOROMETHANE
D I CHLOROTETRAFLUORETHANE
CHLOROPENTAFLUOROETHANE
HEXAFLUOROETHANE
TRI FLUOROMETHANE
CHLOROTR I FLUOROMETHANE
VINYL CHLORIDE
CHLOROPRENE
CARBON YL SULFIDE
CARBON SULFIDE
ISOMERS OF XYLENE
ISOMERS OF DIETHYLBENZENE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
P-XYLENE
CUMENE (ISOPROPYL BENZENE)
STYRENE
PHENOL
XYLENE BASE ACIDS
BENZOIC ACID
TEREPHTHALIC ACID
DIMETHYL TEREPHTHALATE
BENZALDEHYDE
PHTHALIC ANHYDRIDE
NITROBENZENE
Spec_MW
30.03
44.05
56.07
72.12
58.08
72.10
100.16
98.15
44.05
58.08
98.06
102.09
53.06
116.20
50.49
119.39
153.84
173.85
137.38
64.52
99.00
187.38
120.91
112.99
88.01
86.47
170.92
154.47
138.01
70.01
104.46
62.50
' 88.54
60.08
76.13
106.16
134.21
78.11
92.13
106.16
106.16
106.16
120.20
104.14
94.11
230.00
122.13
166.14
194.19
106.13
148.12
123.11
Spee_UT Peak
0.03
1.86
1.79
0.01
2.31
1.91
0.25
0.16
0.07
0.02
0.30
0.09
0.95
1.52
0.01
0.04
0.30
0.15
1.15
1.28
2.52
0.09
1.59
0.08
0.15
0.72
0.07
0.07
1.80
1.36
0.24
1.61
1.52
0.13
0.40
0.25
0.05
8.49
1.80
0.65
0.16
0.05
0.00
3.91
1.55
0.02
0.15
0.02
0.00
0.07
0.91
0.00
B-14
-------
VOC Profile Speciation Report - continued (profile 9004)
Saroad CAS Nunfcer Name SpecJW Spec_WT Peak
45801
45805
45806
45807
45808
99933
99999
TOTAL
108-90-7
95-50-1
541-73-1
106-46-7
2531-22-6
CHLOROBEHZENE
0-DICHLOROBENZENE
H-DICHLOROBENZENE
P-DICHLOROBENZENE
DICHLOROBENZENES
DENATURANT
UNIDENTIFIED
112.56
147.01
147.01
147.01
147.01
32.04
86.00
3.02
0.16
0.01
3.22
0.09
0.44
0.29
100.02
B-15
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Plastics Production - Average
9005
E
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 301018XX.
SCC Assignments:
Saroad
TOTAL
CAS Number
Name
Spec_MU Spec_UT Peak
43205
43704
43860
45203
45220
115-07-1
107-13-1
75-01-4
100-41-4
100-42-5
PROPENE
ACRYLON1TRILE
VINYL CHLORIDE
ETHYLBENZENE
STYRENE
42.08
53.06
62.50
106.16
104.14
20.00
12.00
20.00
2.00
46.00
100.00
B-16
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Synthetic Organic Fiber Production - Average
9006
E
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 301024XX
SCC Assignments:
Saroad
43776
TOTAL
CAS Number
124-09-4
Name
HEXAMETHYLENEDIAHINE
Spec_MU Spec_UT Peak
116.20 100.00
100.00
B-17
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Alcohols Production - Average
9007
E
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 301250XX.
SCC Assignments:
Saroad
CAS Number
Name
SpecJW SpecJJT Peak
43201
43301
43350
TOTAL
2=3==========
74-82-8
67-56-1
115-10-6
====s=s====:
METHANE
METHYL ALCOHOL
DIMETHYLETHER
=======================
16.04
32.04
46.07
=========================
43.35
1.64
55.01
100.00
===============
B-18
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Food and Agriculture
9008
E
Average
Control Device
Reference(s)
Data Source
NOT APPLICABLE
93
Average profile developed from original profiles repre-
senting the source category 302XXXXX.
SCC Assignments:
Saroad
CAS Number
Name
Spec_HW Spec_WT Peak
43302
43306
43330
43433
64-17-5
78-83-1
123-51-3
141-78-6
ETHYL ALCOHOL
ISOBUTYL ALCOHOL
ISOAHYL ALCOHOL
ETHYL ACETATE
46.07
74.12
88.15
88.10
99.56
0.03
0.09
0.32
TOTAL
100.00
B-19
-------
VOC Profile Specialion Report
Profile Name Primary
Profile Number 9009
Data Quality E
Metal Production - Average
Control Device Not Applicable
Reference(s) 93
Data Source Average
sent ing
SCC Assignments:
Saroad CAS Number
43201 74-82-8
43202 74-84-0
43203 74-85-1
43204 74-98-6
43205 115-07-1
43206 74-86-2
43213 106-98-9
43218 106-99-0
43231 110-54-3
43232 142-82-5
43822
45201 71-43-2
45202 108-88-3
TOTAL
profile developed from original
the source category 303XXXXX.
Name
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
BUTENE
1,3 -BUTADIENE
HEXANE
HEPTANE
TRIMETHYLFLUOROSILANE
BENZENE
TOLUENE
profiles repre-
Spec_HW
16.04
30.07
28.05
44.09
42.08
26.04
56.10
54.09
86.17
100.20
92.00
78.11
92.13
Spec_WT Peak
29.10
2.20
6.72
8.08
0.98
3.20
0.02
0.10
1.40
7.16
34.64
5.54
0.86
100.00
B-20
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Secondary Metal Production - Average
9010
E
Not Applicable
93
Average
sent ing
profile developed from original
the source category 304XXXXX.
profiles repre-
SCC Assignments:
Saroad CAS Number
43502
43505
43520
45201
45202
45204
45205
45300
45604
45701
45730
45740
46111
46112
46114
46701
50-00-0
107-02-8
71-43-2
108-88-3
95-47-6
108-38-3
108-95-2
98-00-0
62-53-3
101-68-8
101-77-9
103-71-9
100-61-8
91-12-3
Name
FORMALDEHYDE
ACROLEIN
TOTAL C2-C5 ALDEHYDES
BENZENE
TOLUENE
0-XYLENE
M-XYLENE
PHENOL
FURFURYL ALCOHOL
ANILINE
Spec_MU
30.03
56.07
72.12
78.11
92.13
106.16
106.16
94.11
98.10
93.13
METHYLENE(b)4-PHENYLISOCYANATE 250.27
TOTAL AROMATIC AMINES
4,4-METHYLENE DIANILINE
PHENYL ISOCYANATE
4-METHYLANILINE
NAPTHALENE
93.13
198.17
119.13
107.17
128.17
Spec_WT Peak
0.35
0.17
12.10
17.35
7.05
2.75
3.25
3.20
0.04
35.42
0.01
3.71
0.00
11.80
2.75
0.04
TOTAL
99.99
B-21
-------
VOC Profile Speciation Report
Profile Name Mineral
Profile Number 9011
Data Quality E
Products - Average
Control Device Not Applicable
Reference(s) 93
Data Source Average profile developed from original profiles repre-
senting the source category 305XXXXX.
SCC Assignments:
Saroad
43105
43106
43107
43111
43113
43115
43116
43117
43121
43122
43130
43131
43201
43202
43203
43204
43205
43212
43213
43214
43220
43224
43231
43232
43233
43238
43241
43242
43248
43255
43467
43502
45107
45201
45202
45703
46701
46702
46711
98063
98083
CAS Number
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
106-97-8
106-98-9
75-28-5
109-66-0
109-67-1
110-54-3
142-82-5
111-65-9
124-18-5
1120-21-4
287-92-3
110-82-7
112-40-3
50-00-0
25551-13-7
71-43-2
108-88-3
91-12-3
Name
ISOHERS OF HEXANE
ISONERS OF HEPTANE
ISOHERS OF OCTANE
ISOHERS OF DODECANE
ISOHERS OF TETRADECANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
ISOHERS OF PENTENE
ISOHERS OF PENTANE
C5 SUBSTITUTED CYCLOHEXANE
C6 SUBSTITUTED CYCLOHEXANE
HETHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
N-BUTANE
BUTENE
I SO- BUTANE
N-PENTANE
1 -PENTENE
HEXANE
HEPTANE
OCTANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
CYCLOHEXANE
N- DODECANE
C4 SUBSTITUTED CYCLOHEXANONE
FORHALDEHYDE
TRIHETHYLBENZENE
BENZENE
TOLUENE
2,2 DICHLORONITROANILINE
NAPTHALENE
HETHYL NAPHTHALENES
C2 ALKYL INDAN
N-PENTYLCYCLOHEXANE
TRIHETHYLDECENE
Spec_MU
86.17
100.20
114.23
170.32
198.38
98.19
112.23
126.26
70.13
72.15
154.30
168.32
16.04
30.07
28.05
44.09
42.08
58.12
56.10
58.12
72.15
70.13
86.17
100.20
114.23
142.28
156.31
70.14
84.16
170.33
154.26
30.03
120.19
78.11
92.13
207.02
128.17
142.20
146.23
154.30
182.35
TOTAL
Spec_UT Peak
4.90
2.20
1.68
1.92
0.62
1.32
0.08
0.30
0.10
3.16
0.83
0.62
18.60
2.20
0.86
6.54
1.18
9.74
2.58
3.98
7.12
0.64
3.14 .
3.20
0.54
0.57
1.56
0.50
0.20
3.71
0.48
1.60
1.78
2.86
0.78
0.79
1.31
2.04
2.24
0.41
1.12
100.00
B-22
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Petroleum Industry - Average
9012
E
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 306XXXXX.
SCC Assignments:
Saroad
CAS Number
Name
SpecJW SpecJJT Peak
43105
43106
43107
43108
43109
43115
43116
43117
43122
43201
43202
43204
43205
43212
43213
43214
43220
43231
43232
43233
43235
43238
43248
43502
45102
45201
45202
74-82-8
74-84-0
74-98-6
115-07-1
106-97-8
106-98-9
75-28-5
109-66-0
110-54-3
142-82-5
111-65-9
111-84-2
124-18-5
110-82-7
50-00-0
1330-20-7
71-43-2
108-88-3
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
PROPENE
N- BUTANE
BUTENE
I SO- BUTANE
N- PENTANE
HEXANE
HEPTANE
OCTANE
NONANE
N -DECANE
CYCLOHEXANE
FORMALDEHYDE
ISOMERS OF XYLENE
BENZENE
TOLUENE
86.17
100.20
114.23
128.25
142.28
98.19
112.23
126.26
72.15
16.04
30.07
44.09
42.08
58.12
56.10
58.12
72.15
86.17
100.20
114.23
128.25
142.28
84.16
30.03
106.16
78.11
92.13
4.16
0.63
0.40
0.45
0.28
2.27
0.66
0.11
16.64
13.01
6.05
19.68
1.75
7.99
0.15
2.89
4.80
3.86
1.24
1.73
0.56
0.74
0.08
8.88
0.19
0.38
0.44
TOTAL
100.02
B-23
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Pulp and Paper Industry - Average
9013
E
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 307XXXXX.
SCC Assignments:
Saroad
TOTAL
CAS Number
Name
Spec_MW Spec_UT Peak
43204
43256
43257
90050
90051
90052
90053
74-98-6
80-56-8
127-91-3
5794-03-6
. 123-35-3
5989-27-5
PROPANE
A-PINENE
B-PINENE
CAHPHENE
HYRCENE
B-PHELLANDRENE
D-LIMONENE
44.09
136.24
136.24
136.24
136.24
136.24
136.24
0.03
52.71
34.44
1.27
1.87
1.69
7.99
100.00
B-24
-------
VOC Prrfile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Rubber
9014
E
and Miscellaneous Plastics Products - Average
Not Applicable
93
Average
sent ing
profile developed from original
the source category 308XXXXX.
profiles repre-
SCC Assignments:
Saroad CAS Number
43105
43106
43107
43115
43116
43218
43231
43232
43233
43242
43248
43262
45201
45202
45220
106-99-0
110-54-3
142-82-5
111-65-9
287-92-3
110-82-7
96-37-7
71-43-2
108-88-3
100-42-5
Name
ISOMERS OF HEXANE
ISOHERS OF HEPTANE
ISOMERS OF OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
1,3 -BUTADIENE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
CYCLOHEXANE
METHYLCYCLOPENTANE
BENZENE
TOLUENE
STYRENE
Spec_MW
86.17
100.20
114.23
98.19
112.23
54.09
86.17
100.20
114.23
70.14
84.16
84.16
78.11
92.13
104.14
Spec_WT Peak
8.07
1.63
0.27
14.40
2.00
20.00
13.13
0.63
0.13
0.07
5.57
17.13
3.50
0.13
13.33
TOTAL
99.99
B-25
-------
VOC Profile Speciati«n Report
Profile Name
Profile Number
Data Quality
Oil and Gas Production - Average
9015
E
Control Device
Referenced)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 310XXXXX.
SCC Assignments:
Saroad
CAS Number
Name
TOTAL
Spec.MW SpecJJT Peak
43105
43106
43107
43115
43116
43122
43201
43202
43204
43212
43214
45201
74-82-8
74-84-0
74-98-6
106-97-8
75-28-5
71-43-2
ISOHERS OF HEXANE
ISOHERS OF HEPTANE
ISOHERS OF OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
ISOHERS OF PENTANE
HETHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
BENZENE
86.17
100.20
114.23
98.19
112.23
72.15
16.04
30.07
44.09
58.12
58.12
78.11
6.64
7.79
5.79
1.10
0.40
3.20
53.81
7.44
8.24
5.24
0.25
0.10
100.00
=i::=r:=ss==sr=====:=========:=====:=s==:=s====:3::===:===:====:===s=
B-26
-------
VOC Profile Special ion Report
Profile Name Textile
Profile Number 9016
Data Quality E
Products - Average
Control Device Hot Applicable
Reference(s) 93
Data Source Average
sent ing
profile developed from original profiles repre-
the source category 330XXXXX.
SCC Assignments:
Saroad
43132
43133
43134
43318
43408
43454
43455
43456
43460
43461
43462
43463
43464
43465
43466
43470
43650
43780
43950
43951
45109
45226
45227
45228
45229
45230
45232
45233
45310
45311
45402
45451
45452
45454
45455
45470
45703
45704
45705
45808
45830
CAS Nunfcer
104-76-7
57-10-3
112-39-0
124-10-7
112-61-8
111-82-0
556-67-2
92-52-4
1321-74-0
103-29-7
65-85-0
131-11-3
84-74-2
131-16-8
136-60-7
1817-73-8
2531-22-6
Name
ALIPHATICS
PARAFFINS (C16-C34)
PARAFFINS/OLEF1NS (C12-C16)
2-ETHYL HEXANOL
PALMITIC ACID
METHYL PALMITATE
METHYL MYRISTATE
METHYL STEARATE
METHYL C11 ESTER
METHYL C12 ESTER
METHYL C13 ESTER
METHYL C14 ESTER
METHYL C15 ESTER
METHYL C19 ESTER
METHYL C20 ESTER
METHYL DOOECANOATE
OXYGENATES
DIMETHYL ALKYL AMINES
OCTAMETHYLCYCLOTETRASILOXANE
SILOXANE
C3/C4/C5 ALKYLBENZENES
BIPHENYL
METHYL BIPHENYL
ETHYL STYRENE
DIVINYL BENZENE
DI(ETHYLPHENYL) ETHANE
DIPHENYL ETHANE
ETHYL-PHENYL-PHENYL-ETHANE
C8 PHENOLS
C9 PHENOLS
BENZOIC ACID
DIMETHYL PHTHALATE
D I BUTYL PHTHALATE
DIPROPYL PHTHALATE
BUTYL BENZOATE
DI-C8 ALKYL PHTHALATE
2,2 DICHLORONITROANILINE
BROMOOINITROANILINE
BROMOO I NITROBENZENE
DICHLOROBENZENES
TRICHLOROBENZENES
Spec_MW
100.00
352.43
197.38
130.23
256.43
270.46
242.41
298.52
214.35
228.37
242.40
256.43
270.45
326.56
340.59
214.35
86.00
59.11
296.62
76.08
134.21
154.21
168.24
132.21
130.20
238.37
182.27
210.32
122.16
136.19
122.13
194.19
278.35
250.30
178.23
390.56
207.02
262.03
247.02
147.01
181.45
Spec_WT Peak
9.97
1.81
0.04
0.20
19.78
8.26
3.08
10.67
0.00
0.01
0.00
0.04
0.02
0.01
0.00
0.01
0.27
0.21
1.06
0.58
2.78
1.30
0.09
2.97
0.32
0.00
0.71
1.22
0.03
0.13
0.87
5.73
0.40
0.01
21.07
0.31
0.11
0.01
1.08
0.06
1.45
B-27
-------
VOC Profile Speciation Report - continued (profile 9016)
Saroad CAS Number Name
Spec_HU Spec_UT Peak
45831
46102
46103
46701
46702
46703
99999
TOTAL
84-65-1
82-45-1
91-12-3
28804-88-8
TETRACHLOROBENZENES
ANTHRAQUINONE
AMINOANTMRAOUINONE
NAPTHALENE
METHYL NAPHTHALENES
DIMETHYL NAPTHALENE
UNIDENTIFIED
215.90
208.23
223.23
128.17
142.20
156.23
86.00
0.07
1.30
0.02
1.00
0.22
0.27
0.43
99.98
:ss====sss:==r :=====
B-28
-------
VOC Profile Speciation Report
Profile Name Drycleaning/Degreasing - Average
Profile Number 9017
Data Quality E
Control Device Not Applicable
Reference(s) 93
Data Source Average
sent ing
profile developed from original profiles repre-
the source category 401XXXXX.
SCC Assignments:
Saroad
43109
43110
43111
43112
43113
43124
43125
43135
43136
43138
43141
43146
43147
43148
43150
43151
43151
43152
43153
43231
43232
43235
43248
43261
43288
43301
43302
43314
43336
43351
43397
43551
43552
43565
43566
43567
43802
43811
43814
43817
43820
CAS Number
110-54-3
142-82-5
111-84-2
110-82-7
108-87-2
1678-91-7
67-56-1
64-17-5
78-92-2
60-29-7
67-64-1
78-93-3
75-09-2
75-69-4
71-55-6
127-18-4
79-00-5
Name
ISOHERS OF DECANE
ISOHERS OF UNDECANE
ISOHERS OF DOOECANE
ISOHERS OF TRIDECANE
ISOHERS OF TETRADECANE
C9 OLEFINS
C10 OLEFINS
C10 PARAFFINS
C9 PARAFFIN
C-8 OLEFINS
C8 PARAFFIN
C11 OLEFINS
C12 OLEFINS
ISOHERS OF C9H16
ISOHERS OF C10H18
ISOHERS OF C11H20
ISOHERS OF C11H20
C12H22
C10H16
HEXANE
HEPTANE
NONANE
CYCLOHEXANE
HETHYLCYCLOHEXANE
ETHYLCYCLOHEXANE
HETHYL ALCOHOL
ETHYL ALCOHOL
S-BUTYL ALCOHOL
OCTANOL
ETHYL ETHER
TR I HETHYLCYCLOHEXANOL
ACETONE
HETHYL ETHYL KETONE
D I HETHYLCYCLOBUTANONE
TRIHETHYLCYCLOPENTANONE
TETRAHETHYLPENTANONE
DICHLOROHETHANE
TRICHLOROFLUOROHETHANE
1,1,1-TRICHLOROETHANE
PERCHLOROETHYLENE
1,1,2-TRICHLOROETHANE
Spec_HW
142.28
156.30
170.32
184.36
198.38
126.24
140.27
142.28
128.25
112.23
114.23
154.29
168.32
124.23
138.25
152.28
152.28
166.31
136.24
86.17
100.20
128.25
84.16
98.21
112.23
32.04
46.07
74.12
130.26
74.12
142.24
58.08
72.10
98.14
126.20
142.24
84.94
137.38
133.42
165.83
133.42
Spec_UT Peak
1.36
0.95
0.18
0.01
.0.01
0.00
0.29
0.06
0.00
0.09
0.00
0.11
0.02
0.04
0.01
0.01
0.01
0.00
0.01
0.01
2.57
0.85
0.01
0.56
0.07
7.14
2.14
0.05
0.01
0.06
0.01
0.10
0.08
0.02
0.01
0.05
12.44
7.14
8.74
13.53
7.14
B-29
-------
VCX: Profile Spcciation Report - continued (profile 9017)
Saroad
43821
43824
45102
45105
45107
45108
45113
45201
45202
45203
45204
45209
45210
45215
45238
45245
45303
45304
45320
45801
45808
46202
46601
46602
46701
46747
46748
46753
90010
90028
90029
90045
90047
90048
90049
90055
90064
90066
90067
90070
90071
90072
90073
90074
90075
90076
90077
90080
90081
90082
90083
90085
CAS Nunber
76-13-1
79-01-6
1330-20-7
25551-13-7
71-43-2
108-88-3
100-41-4
95-47-6
103-65-1
98-82-8
98-06-6
108-90-7
2531-22-6
2782-91-4
95-16-9
91-12-3
91-17-8
Name
TRICHLOROTRI FLUOROETHANE
TRICHLOROETHYLENE
ISOMERS OF XYLENE
I SOBERS OF BUTYLBENZENE
TRIKETHYLBENZENE
ISOKERS OF PROPYLBENZENE
C11H10
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
N-PROPYLBENZENE
CUMENE (ISOPROPYL BENZENE)
TERT-BUTYLBENZENE
ETHYLTOLUENE
C5-ALKYLBENZENES
C4-ALKYLPHENOLS
C5-ALKYLPHENOLS
D IHETHYLBENZYLALCOHOL
CHLOROBENZENE
DICHLOROBENZENES
OCTAHYDROINDENES
TETRAHETHYLTH10UREA
BENZOTHIAZOLE
NAPTHALENE
METHYL I NOANS
HETHYLDECALINS
DECALINS
H-XYLENE AND P-XYLENE
METHYLHEXANE
HETHYLHEXENES
HETHYLHEPTANE
HETHYLNONANE
HETHYLDECANES
HETHYLUHOECANE
PENTYLCYCLOHEXANE
DIHETHYLCYCLOPENTANE
NONADIEME
DIHETHYLHEXANES
DIHETHYLOCTANES
DIMETHYLUNOECANE
METHYLPROPYLCYCLOHEXANES
METHYL I SOPROPYLCYCLOHEXANE
DIHETHYLDECANE
ETHYLOCTENE
DIMETHYLNONANES
ETHYLOCTANE
ETHYLHETHYLCYCLOPENTANE
ETHYLHEXANE
ETHYLHETHYLHEXANE
ETHYLMETHYLCYCLOHEXANES
ETHYLMETHYLOCTANE
Spec_HW
187.38
131.40
106.16
134.22
120.19
120.19
142.20
78.11
92.13
106.16
106.16
120.19
120.20
134.21
120.19
148.24
150.22
164.25
136.19
112.56
147.01
244.00
132.25
135.19
128.17
132.21
152.28
138.25
106.16
100.20
98.18
114.23
142.28
156.32
170.34
154.29
98.19
124.23
114.23
142.28
184.36
140.27
140.27
170.34
140.27
156.31
142.29
112.21
114.23
128.26
126.24
156.31
Spec_UT Peak
7.65
8.65
0.24
0.44
0.28
0.17
0.00
0.07
9.27
0.03
0.18
0.04
0.04
0.03
0.03
0.02
0.04
0.02
0.02
0.02
0.00
0.02
0.01
0.00
0.04
0.00
0.05
0.07
0.26
0.39
0.04
0.00
0.58
0.49
0.09
0.04
0.22
0.02
0.10
0.64
0.02
0.32
0.02
0.02
0.01
0.28
0.02
0.00
0.04
0.01
0.57
0.02
B-30
-------
VOC Profile Speciation Report - continued (profile 9017)
Saroad CAS Number Name
Spec_MW Spec_UT Peak
90089
90090
90091
90094
90095
90096
90097
90098
90101
90102
90104
90105
90106
90107
90108
90109
90110
90111
90112
90113
90114
90118
90120
98058
98059
98060
98062
98063
98082
98091
ETH YLD IMETH YLCYCLOHEXANE
ETHYLPROPYLCYCLOHEXANES
TETRAMETHYLCYCLOBUTENE
TRIMETHYLHEPTANES
TRIMETHYLHEXENE
TRIMETHYLOCTANES
TRIHETHYLDECANE
TETRAMETHYLCYCLOPENTANE
1678-93-9 BUTYLCYCLOHEXANE
METHYLPROPYLNONANE
HETHYLOCTANES
PROPENYLCYCLOHEXANE
HETHYLNONEHE
METHYLDECEHE
HETHYLDOOECANE
PROPYLHEPTENES
D I ETHYLMETHYLCYCLOHEXANES
I SOPROPYLMETHYLCYCLOHEXANE
DIMETHYLOCTYNE
PENTYLIDENECYCLOHEXANE
DIHETHYLBUTYLCYCLOHEXANE
OCTAHYOROPENTALENE
PROPYLCYCLOHEXANE
TRIHETHYLCYCLOPENTANE
DIHETHYLCYCLOHEXANE
3073-66-3 TRIMETHYLCYCLOHEXANES
DIETHYLCYCLOHEXANE
N-PENTYLCYCLOHEXANE
ETHYLHEPTENE
DIHETHYLHEPTANES
140.27
154.29
110.19
142.29
126.24
156.31
184.36
126.24
140.27
184.36
128.26
124.33
140.26
154.29
184.36
140.27
111.20
140.27
138.25
152.00
168.32
225.20
126.24
112.16
112.24
126.27
140.27
154.30
126.24
128.26
0.08
0.06
0.00
0.56
0.03
0.04
0.00
0.07
0.19
0.01
0.35
0.07
0.01
0.08
0.01
0.05
0.05
0.04
0.01
0.01
0.00
0.01
0.18
0.11
0.07
0.24
0.06
0.01
0.01
0.05
TOTAL
99.98
B-31
-------
VOC Profile Specialion Report
Profile Name Surface
Profile Number 9021
Data Quality E
Coating Operations - Average
Control Device Not Applicable
Reference(s) 93
Data Source Average
sent ing
profile developed from original profiles repre-
the source category 402XXXXX.
SCC Assignments:
Saroad
43107
43108
43109
43110
43119
43122
43125
43126
43127
43128
43129
43150
43231
43232
43238
43241
43247
43248
43261
43262
43277
43288
43301
43302
43304
43305
43308
43311
43312
43313
43318
43320
43322
43367
43370
43371
43372
43377
43391
43432
43433
CAS Number
110-54-3
142-82-5
124-18-5
1120-21-4
108-08-7
110-82-7
108-87-2
96-37-7
1678-91-7
67-56-1
64-17-5
67-63-0
71-36-3
111-76-2
110-80-5
112-34-5
104-76-7
123-42-2
110-63-4
111-46-6
107-21-1
107-41-5
142-96-1
111-90-0
79-20-9
141-78-6
Name
ISOMERS OF OCTANE
ISOHGRS OF MONANE
ISOHERS OF DECANE
ISOHERS OF UNDECANE
LACTOL SPIRITS
ISOHERS OF PENTANE
C10 OLEFINS
C2 CYCLOHEXANE
C3 CYCLOHEXANE
C5 CYCLOHEXANE
C4 SUBSTITUTED CYCLOHEXANE
ISOHERS OF C10H18
HEXAHE
HEPTANE
N-DECANE
N-UNDECANE
2,4-DIHETHYLPENTANE
CYCLOHEXANE
HETHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2,4-DIHETHYLHEXANE
ETHYLCYCLOHEXANE
METHYL ALCOHOL
ETHYL ALCOHOL
ISO-PROPYL ALCOHOL
N-BUTYL ALCOHOL
BUTYL CELLOSOLVE
CELLOSOLVE
2-(2-BUTOXYETHOXY)-ETHANOL
1-ETHOXY-2-PROPANOL
2-ETHYL HEXANOL
DIACETONE ALCOHOL
1,4 BUTANEDIOL
GLYCOL ETHER
ETHYLENE GLYCOL
HEXYLENE GLYCOL
DIBUTYL ETHER
CARBITOL
2-BUTYLTETRAHYDROFURAN
HETHYLACETATE
ETHYL ACETATE
Spec_MW
114.23
128.25
142.28
156.30
114.00
72.15
140.27
112.22
126.24
154.30
140.27
138.25
86.17
100.20
142.28
156.31
100.20
84.16
98.21
84.16
114.22
112.23
32.04
46.07
60.09
74.12
118.17
90.12
162.26
104.15
130.23
116.18
90.12
106.14
62.07
118.18
130.23
134.18
128.19
74.08
88.10
Spec_UT Peak
0.03
1.44
2.53
0.17
3.33
1.87
0.24
0.10
0.07
0.03
0.10
0.15
0.41
1.87
0.01
0.09
0.15
0.57
0.94
0.11
0.64
0.14
3.33
3.33
3.70
4.00
0.55
3.33
0.03
0.05
0.03
0.03
0.37
0.10
0.02
3.38
0.01
3.33
0.01
3.33
4.14
B-32
-------
VOC Profile Speciation Report - continued (profile 9021)
Saroad
43435
43444
43450
43452
43453
43454
43457
43458
43459
43551
43552
43560
43562
43563
43570
43601
43801
43802
43812
43835
43836
43837
45101
45102
45104
45107
45108
45201
45202
45203
45204
45205
45206
45501
45502
45601
98057
98058
98059
98060
98062
98082
98090
98091
98106
CAS Number
138-22-7
108-21-4
68-12-2
111-15-9
108-05-4
112-39-0
109-87-5
67-64-1
78-93-3
108-10-1
110-43-0
7379-12-6
75-21-8
74-87-3
75-09-2
75-00-3
78-86-4
106-93-4
8030-30-6
1330-20-7
25551-13-7
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
106-42-3
100-52-7
104-87-0
85-44-9
1640-89-7
3073-66-3
Name
N-BUTYL ACETATE
1SOPROPYL ACETATE
DIMETHYL FORHAHIDE
CELLOSOLVE ACETATE
VINYL ACETATE
METHYL PALMITATE
METHYLAL
SUBSTITUTED C9 ESTER (C12)
C5 ESTER
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
METHYL AMYL KETONE
2-HETHYL-3-HEXANONE
ALKENE KETONE
ETHYLENE OXIDE
METHYL CHLORIDE
DICHLOROMETHANE
ETHYL CHLORIDE
1-CHLOROBUTANE
3-
-------
VOC Profile Speciation Report
Profile Name Solid Waste Disposal - Average
Profile Number 9022
Data Quality E
Control Device Not Applicable
Reference(s) 93
Data Source Average
sent ing
SCC Assignments:
Saroad CAS Number
43121
43123
43201 74-82-8
43202 74-84-0
43203 . 74-85-1
43204 74-98-6
43205 115-07-1
43206 74-86-2
43212 106-97-8
43213 106-98-9
43214 75-28-5
43220 109-66-0
43224 109-67-1
43231 110-54-3
43232 142-82-5
43233 111-65-9
43242 287-92-3
43817 127-18-4
45102 1330-20-7
45201 71-43-2
45202 108-88-3
TOTAL
profile developed from original
the source category 5XXXXXXX.
Name
ISOHERS OF PENTENE
TERPENES
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
N-BUTANE
BUTENE
ISO-BUTANE
N-PENTANE
1 -PENTENE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
PERCHLOROETHYLENE
ISOHERS OF XYLENE
BENZENE
TOLUENE
profiles repre-
Spec_MW
70.13
136.23
16.04
30.07
28.05
44.09
42.08
26.04
58.12
56.10
58.12
72.15
70.13
86.17
100.20
114.23
70.14
165.83
106.16
78.11
92.13
Spec_WT Peak
3.93
0.03
59.71
0.93
9.37
0.67
0.17
0.63
0.70
1.97
0.67
0.67
3.93
4.63
4.63
4.60
0.03
0.10
0.03
2.57
0.03
100.00
B-34
-------
VOC Profile Specialion Report
Profile Name Thinning Solvents - Average
Profile Number 9023
Data Quality E
Control Device Not Applicable
Reference(s) 93
Data Source Average
sent ing
profile developed from original profiles repre-
the source category 402009XX.
SCC Assignments:
Saroad
43107
43108
43109
43110
43119
43125
43126
43127
43128
43129
43150
43232
43241
43261
43301
43302
43304
43305
43311
43371
43377
43432
43433
43435
43444
43450
43452
43551
43552
43570
43601
43802
43837
45101
45102
45202
45203
45205
45206
45501
45502
CAS Number
142-82-5
1120-21-4
108-87-2
67-56-1
64-17-5
67-63-0
71-36-3
110-80-5
107-41-5
111-90-0
79-20-9
141-78-6
138-22-7
108-21-4
68-12-2
111-15-9
67-64-1
78-93-3
75-21-8
75-09-2
106-93-4
8030-30-6
1330-20-7
108-88-3
100-41-4
108-38-3
106-42-3
100-52-7
104-87-0
Name
ISOMERS OF OCTANE
ISOHERS OF NONANE
I SOWERS OF DECANE
ISOHERS OF UNDECANE
LACTOL SPIRITS
C10 OLEFINS
C2 CYCLOHEXANE
C3 CYCLOHEXANE
C5 CYCLOHEXANE
C4 SUBSTITUTED CYCLOHEXANE
ISOHERS OF C10H18
HEPTANE
N-UNDECANE
HETHYLCYCLOHEXANE
HETHYL ALCOHOL
ETHYL ALCOHOL
ISO-PROPYL ALCOHOL
N-BUTYL ALCOHOL
CELLOSOLVE
HEXYLENE GLYCOL
CARBITOL
HETHYLACETATE
ETHYL ACETATE
N-BUTYL ACETATE
ISOPROPYL ACETATE
DIHETHYL FORHAHIDE
CELLOSOLVE ACETATE
ACETONE
HETHYL ETHYL KETONE
ALKENE KETONE
ETHYLENE OXIDE
DICHLOROHETHANE
ETHYLENE DIBROMIDE
NAPHTHA
ISOHERS OF XYLENE
TOLUENE
ETHYLBENZENE
H-XYLENE
P-XYLENE
BENZALDEHYDE
P-TOLUALDEHYDE
Spec_HW
114.23
128.25
142.28
156.30
114.00
140.27
112.22
126.24
154.30
140.27
138.25
100.20
156.31
98.21
32.04
46.07
60.09
74.12
90.12
118.18
134.18
74.08
88.10
116.16
102.13
73.09
132.16
58.08
72.10
72.10
44.05
84.94
187.88
114.00
106.16
92.13
106.16
106.16
106.16
106.13
120.16
Spec_UT Peak
0.04
1.55
3.61
0.20
4.76
0.34
0.14
0.09
0.04
0.14
0.21
0.15
0.12
0.32
4.76
4.76
5.00
4.76
4.76
4.76
4.76
4.76
4.76
5.20
4.76
4.76
4.76
4.76
4.96
0.09
4.76
0.06
0.04
4.76
4.76
0.72
0.04
0.08
0.05
0.04
0.05
B-35
-------
VOC Profile Speciation Report - continued (profile 9023)
S a road
45601
98062
98082
CAS Number
85-44-9
Name
PHTHALIC ANHYDRIDE
DIETHYLCYCLOHEXANE
ETHYLHEPTENE
SpecJW
148.12
140.27
126.24
Spec_WT
0.04
0.38
0.11
Peak
TOTAL
99.97
SSSS3SSSSSSSSS53
B-36
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Petroleum Product Storage - Average
9024
E
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 403XXXXX.
SCC Assignments:
Saroad
TOTAL
CAS Number
Name
Spec_HU Spec_WT Peak
43105
43115
43116
43122
43201
43202
43204
43212
43214
43220
43231
43232
43233
43235
43238
43241
43255
43258
43259
43260
45201
74-82-8
74-84-0
74-98-6
106-97-8
75-28-5
109-66-0
110-54-3
142-82-5
111-65-9
111-84-2
124-18-5
1120-21-4
112-40-3
629-50-5
629-59-4
629-62-9
71-43-2
ISOMERS OF NEXANE
C-7 CYCLOPARAFF1NS
C-8 CYCLOPARAFFINS
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
N-PENTANE
HEXANE
HEPTANE
OCTANE
NONANE
N-DECANE
N-UNDECANE
N-DODECANE
N-TRIDECANE
N-TETRADECANE
N-PENTADECANE
BENZENE
86.17
98.19
112.23
72.15
16.04
30.07
44.09
58.12
58.12
72.15
86.17
100.20
114.23
128.25
142.28
156.31
170.33
184.36
198.38
212.41
78.11
2.86
0.42
0.16
0.49
2.01
1.81
5.70
8.78
0.49
4.73
2.56
3.01
2.40
1.52
6.35
6.57
5.89
5.73
3.79
2.33
32.41
100.01
B-37
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Bulk Terminals - Petroleum Storage Tanks
9025
E
- Average
Not Applicable
93
Average
sent ing
:
Saroad CAS Number
43105
43106
43107
43108
43109
43120
43122
43124
43125
43138
43201
43202
43204
43212
43214
43216
43217
43220
43223
43224
43225
43226
43227
43228
43230
43231
43232
43233
43235
43238
43242
43245
43247
43248
43250
43252
43261
43262
43265
43270
43271
74-82-8
74-84-0
74-98-6
106-97-8
75-28-5
624-64-6
590-18-1
109-66-0
563-45-1
109-67-1
563-46-2
646-04-8
627-20-3
513-35-9
96-14-0
110-54-3
142-82-5
111-65-9
111-84-2
124-18-5
287-92-3
592-41-6
108-08-7
110-82-7
540-84-1
565-75-3
108-87-2
96-37-7
111-66-0
922-61-2
profile developed from original profiles repre-
the source category 404XXXXX.
Name
ISOHERS OF HEXANE
ISOHERS OF HEPTANE
ISOHERS OF OCTANE
ISOHERS OF NONANE
ISOHERS OF DECANE
ISOHERS OF BUTENE
ISOHERS OF PENTANE
C9 OLE FINS
CIO OLEFINS
C-8 OLEFINS
METHANE
ETHANE
PROPANE
N -BUTANE
ISO-BUTANE
T-2-BUTENE
CIS-2-BUTENE
N-PENTANE
3-HETHYL-1 -BUTENE
1-PENTENE
2-HETHYL-1-BUTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-HETHYL-2-BUTENE
3-HETHYL PENTANE
HEXANE
HEPTANE
OCTANE
NONANE
N-DECANE
CYCLOPENTANE
1-HEXENE
2,4-DIMETHYLPENTANE
CYCLOHEXANE
2,2,4-TRlMETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
HETHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
OCTENE
3-METHYL-T-2-PENTENE
3,5,5-TRIMETHYLHEXANE
Spec_MU
86.17
100.20
114.23
128.25
142.28
56.10
72.15
126.24
140.27
112.23
16.04
30.07
44.09
58.12
58.12
56.11
56.11
72.15
70.13
70.13
70.13
70.13
70.13
70.13
86.17
86.17
100.20
114.23
128.25
142.28
70.14
84.16
100.20
84.16
114.22
114.22
98.21
84.16
112.21
84.16
128.26
Spec_WT Peak
1.75
3.41
0.65
0.15
0.02
0.82
18.58
0.10
0.00
0.07
3.02
0.97
6.33
23.61
11.35
0.80
0.62
8.28
0.23
0.59
0.95
0.93
0.46
0.36
1.58
2.88
1.09
0.09
0.01
0.00
0.49
0.23
0.42
0.27
0.17
0.07
0.23
1.44
0.02
0.03
0.19
B-38
-------
VOC Profile Speciation Report - continued (profile 9025)
Saroad
43278
43284
43289
43291
43292
43293
43294
43295
43298
43299
43820
45102
45109
45110
45201
45202
45203
45204
45207
45208
45209
45210
45211
45212
45215
45218
45225
45801
46701
46712
90013
98033
98034
98035
98040
98041
98044
98054
98056
TOTAL
CAS Number
592-13-2
625-27-4
75-83-2
142-29-0
27236-46-0
589-34-4
79-00-5
1330-20-7
71-43-2
108-88-3
100-41-4
95-47-6
108-67-8
95-63-6
103-65-1
98-82-8
611-14-3
620-14-4
98-06-6
141-93-5
526-73-8
108-90-7
91-12-3
95-13-6
40504-55-7
592-43-8
763-29-1
496-11-7
107-39-1
590-86-3
Name
2,5-DIHETHYLHEXANE
2-HETHYL-2-PENTENE
C6 OLEFINS
2,2-DIHETHYLBUTANE
CYCLOPENTENE
4-METHYL-T-2-PENTENE
C7 OLEFINS
3-METHYLHEXANE
3-METHYLHEPTANE
1-METHYLCYCLOHEXENE
1 , 1 ,2-TRICHLOROETHANE
ISOMERS OF XYLENE
C3/C4/C5 ALKYLBENZENES
C10 AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
1 ,3,5-TRIMETHYLBENZENE
1,2,4-TRIMETHYLBENZENE
N-PROPYLBENZENE
CUMENE (ISOPROPYL BENZENE)
0-ETHYLTOLUENE
M-ETHYLTOLUENE
TERT-BUTYLBENZENE
M-0 I ETHYLBENZENE
1 ,2,3-TRIMETHYLBENZENE
CHLOROBENZENE
NAPTHALENE
INDENE
C-2-OCTENE
2,2,5-TRIMETHYLHEXANE
T-2-HEXENE
C-2-HEXENE
2-METHYL-1-PENTENE
3-HEPTENE
INDANE
2,4,4-TRIMETHYL-1-PENTENE
ISOVALERALDEHYDE
Spec_MU
114.22
84.16
84.16
86.17
68.11
84.18
98.18
100.20
114.23
96.17
133.42
106.16
134.21
134.22
78.11
92.13
106.16
106.16
120.19
120.19
120.19
120.20
120.19
120.19
134.21
134.22
120.19
112.56
128.17
116.16
112.21
128.26
84.16
84.16
84.16
98.19
118.18
112.22
86.14
Spec_WT Peak
0.16
0.04
0.24
0.75
0.17
0.16
0.05
0.54
0.17
0.08
0.01
0.31
0.01
0.00
1.63
1.43
0.09
0.13
0.02
0.05
0.01
0.00
0.03
0.03
0.00
0.00
0.03
0.01
0.00
0.00
0.01
0.07
0.25
0.20
0.02
0.01
0.00
0.02
0.00
99.99
B-39
-------
VOC Profile Speciation Report
Profile Mame Printing/Publishing - Average
Profile Number 9026
Data Quality E
Control Device Not Applicable
Reference(s) 93
Data Source Average
sent ing
SCC Assignments: 40500601
Saroad
431 14
43118
43125
43155
43156
43201
43202
43203
43204
43205
43212
43213
43224
43248
43273
43301
43304
43305
43332
43333
43334
43335
43377
43434
43435
43444
43474
43475
43502
43551
43552
43560
45102
45106
45202
45203
45304
45330
45402
45452
45456
CAS Number
64475-85-0
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
106-97-8
106-98-9
109-67-1
110-82-7
110-83-8
67-56-1
67-63-0
71-36-3
106-21-8
111-90-0
109-60-4
138-22-7
108-21-4
50-00-0
67-64-1
78-93-3
108-10-1
1330-20-7
108-88-3
100-41-4
90-43-7
65-85-0
84-74-2
profile developed from original profiles repre-
the source category 405XXXXX.
, 40500701
Name
ISOMERS OF PENTADECANE
MINERAL SPIRITS
C10 OLEFINS
I SOWERS OF HEPTADECANE
ISOHERS OF OCTADECANE
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
N-BUTANE
BUTENE
1-PENTENE
CYCLOHEXANE
CYCLOHEXENE
METHYL ALCOHOL
ISO-PROPYL ALCOHOL
N- BUTYL ALCOHOL
DIMETHYLOCTANOL
DIHETHYLHEPTANOL
METHYLHEPTANOL
METHOXYETHOXYETHANOL
CARBITOL
N-PROPYL ACETATE
N-BUTYL ACETATE
ISOPROPYL ACETATE
METHYLMETHYLPROPENOATE
METHYLETHYLPENTANOATE
FORMALDEHYDE
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
ISOHERS OF XYLENE
ISOHERS OF DIETHYLBENZENE
TOLUENE
ETHYLBENZENE
C5-ALKYLPHENOLS
BIPKENYLOL
BENZOIC ACID
DIBUTYL PHTHALATE
BUTYL I SOPROPYLPHTHALATE
Spec.MU
212.41
114.00
140.27
240.47
254.50
16.04
30.07
28.05
44.09
42.08
58.12
56.10
70.13
84.16
82.14
32.04
60.09
74.12
158.32
144.26
130.26
120.15
134.18
102.15
116.16
102.13
100.13
144.22
30.03
58.08
72.10
100.16
106.16
134.21
92.13
106.16
164.25
170.22
122.13
278.35
264.32
Spec_WT Peak
0.02
16.75
0.02
0.46
0.21
10.01
3.00
0.25
1.50
4.20
0.13
1.70
1.49
1.82
0.03
0.75
0.75
0.75
0.01
0.01
0.01
0.01
12.50 '
3.43
1.00
3.76
0.00
0.00
2.73
3.06
6.78
14.35
0.50
0.88
2.44
0.75
0.02
0.01
0.00
1.25
1.60
B-40
-------
VOC Profile Special ion Report - continued (profile 9026}
Saroad CAS Number Name Spec_MU Spec_UT Peak
45706
45731
90030
90049
90071
90077
90096
90097
90125
90126
90127
90130
58-84-9
544-76-3
629-94-7
112-95-8
87-44-5
N-PHENYLANILINE
TOLUENE DIISOCYANATE
HEXADECANE
METHYLUNDECANE
DIHETHYLUNDECANE
ETHYLOCTANE
TRIMETHYLOCTANES
TRIMETHYLDECAME
NENEICOSANE
EICOSANE
NONADECANE
CARYOPHYLLENE
169.24
174.17
226.45
170.34
184.36
142.29
156.31
184.36
296.59
282.56
268.53
204.36
0.01
0.00
0.41
0.21
0.03
0.06
0.10
0.04
0.04
0.06
0.11
0.01
TOTAL 100.02
B-41
-------
VOC Profile Speciation Report
Profile Name Transportation and Marketing of Petroleum Products - Average
Profile Number 9027
Data Quality E
Control Device Not Applicable
Reference(s) 93
Data Source Average
sent ing
profile developed from original profiles repre-
the source category 406XXXXX.
SCC Assignments:
Saroad
43105
43109
43110
43111
43113
43115
43124
43125
43135
43136
43138
43141
43142
43143
43144
43145
43146
43148
43149
43201
43202
43204
43212
43213
43220
43231
43232
43233
43242
43261
43262
43264
43272
43273
43288
43292
43395
43565
45105
45106
45107
CAS Number
74-82-8
74-84-0
74-98-6
106-97-8
106-98-9
109-66-0
110-54-3
142-82-5
111-65-9
287-92-3
108-87-2
96-37-7
693-89-0
110-83-8
1678-91-7
142-29-0
25551-13-7
Name
ISOHERS OF HEXANE
ISOHERS OF DECANE
ISOHERS OF UNDECANE
ISOMERS OF DODECANE
ISOHERS OF TETRADECANE
C-7 CYCLOPARAFFINS
C9 OLEFINS
C10 OLEFINS
C10 PARAFFINS
C9 PARAFFIN
C-8 OLEFINS
C8 PARAFFIN
C7 PARAFFINS
C5 OLEFIN
C5 PARAFFIN
C5 PARAFFIN/OLEFIN
C11 OLEFINS
ISOHERS OF C9H16
C8H14
HETHANE
ETHANE
PROPANE
N-BUTANE
BUTEHE
N-PEHTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
HETHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
HEPTENE
HETHYLCYCLOPENTENE
CYCLOHEXENE
ETHYLCYCLOHEXANE
CYCLOPENTENE
C7H120
DIHETHYLCYCLOBUTANONE
ISOHERS OF BUTYLBENZENE
ISOHERS OF D1ETHYLBENZENE
TRIHETHYLBENZENE
Spec_MU
86.17
142.28
156.30
170.32
198.38
98.19
126.24
140.27
142.28
128.25
112.23
114.23
100.20
70.13
72.15
70.13
154.29
124.23
110.20
16.04
30.07
44.09
58.12
56.10
72.15
86.17
100.20
114.23
70.14
98.21
84.16
98.18
82.14
82.14
112.23
68.11
112.17
98.14
134.22
134.21
120.19
Spec_WT Peak
0.05
0.05
0.04
0.02
0.01
0.02
0.05
0.02
0.00
0.24
0.10
1.93
0.02
0.95
1.04
0.54
0.02
0.01
0.00
1.30
1.86
7.92
15.14 .
0.07
9.28
6.37
6.34
4.81
0.08
0.10
0.34
0.01
0.22
0.02
0.04
0.09
0.02
0.02
1.60
0.01
2.15
B-42
-------
VOC Profile Speciation Report - continued (profile 9027}
Saroad
45108
45111
45112
45201
45202
45203
45204
45209
45210
45220
45221
45238
45243
45244
45245
45246
45247
45248
45249
45501
45801
46115
46701
46702
46746
46747
46749
46750
46751
46752
46754
46755
90010
90021
90022
90023
90024
90025
90026
90027
90028
90029
90039
90041
90043
90044
90045
90046
90047
90048
90054
90056
CAS Number
71-43-2
108-88-3
100-41-4
95-47-6
103-65-1
98-82-8
100-42-5
25013-15-4
100-52-7
108-90-7
91-12-3
4313-57-9
Name
ISOHERS OF PROPYLBENZENE
C10H12
ISOMERS OF C10H10
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
N- PROPYLBENZENE
CUHENE (1SOPROPYL BENZENE)
STYRENE
METHYL STYRENE
ETHYLTOLUENE
ETHYLDIHETHYLBENZENE
TETRAMETHYLBENZENE
C5-ALKYLBENZENES
C5-ALKYLBENZENES (UNSAT.)
C6-ALKYLBENZENE
C4-ALKYLSTYRENES
C7-ALKYLBENZENE
BENZALDEHYDE
CHLOROBENZENE
DIMETHYLNAPHTHYR1DINE
NAPTHALENE
METHYL NAPHTHALENES
C2-ALKYLNAPHTHALENE
METHYLINOANS
METHYLD I HYDRONAPHTHALENE
DIMETHYLINOANS
DIHYDRONAPTHALENE
DIMETHYLINDENE
ETHYLINDAN
TRIMETHYLINDAN
H-XYLENE AND P-XYLENE
METHYLPROPANE
METHYLPROPENE
METHYLBUTENE
HETHYLBUTADIENE
METHYLPENTENES
METHYLPENTANE
METHYLCYCLOPENTAD I ENE
METHYLHEXANE
METHYLHEXENES
HETHYLHEXADIENE
METHYLCYCLOHEXAO I ENE
METHYLHEXANAL
METHYLHEPTYNE
METHYLHEPTANE
METHYLCYCLOHEXENE
METHYLNONANE
METHYLDECANES
PENTENYNE
HEXENE
Spec_NW
120.19
132.22
130.19
78.11
92.13
106.16
106.16
120.19
120.20
104.14
118.19
120.19
134.22
134.22
148.24
146.25
162.27
160.26
176.30
106.13
112.56
158.20
128.17
142.20
156.23
132.21
144.22
146.23
130.19
144.22
146.23
160.26
106.16
58.12
56.10
70.13
68.12
84.16
86.17
80.14
100.20
98.18
96.17
94.15
114.19
110.20
114.23
96.17
142.28
156.32
66.10
84.16
Spec_UT Peak
0.38
0.02
0.00
1.62
7.63
2.04
3.21
0.46
0.16
0.08
0.02
1.80
0.62
0.51
0.71
0.02
0.05
0.03
0.00
0.00
0.01
0.00
0.40
0.32
0.05
0.26
0.00
0.21
0.03
0.00
0.02
0.03
7.66
1.32
0.07
0.03
0.00
0.44
0.88
0.02
0.84
0.01
0.12
0.01
0.46
0.01
0.17
0.07
0.10
0.06
0.01
0.20
B-43
-------
VOC Profile Speciation Report - continued (profile 9027)
Saroad
90058
90059
90060
90061
90062
90063
90064
90065
90067
90068
90069
90070
90071
90074
90078
90079
90080
90081
90082
90083
90084
90085
90086
90087
90091
90092
90093
90094
90095
90096
90097
90099
90100
90103
90104
98044
98058
98059
98060
98091
99999
CAS Number Name
142-83-6 HEXADIENAL
5910-85-9 HEPTADIEMAL
79-29-8 DIHETHYLBUTANE
DIMETHYLBUTENE
DIMETHYLPENTANE
DIHETHYLPENTENE
DIMETHYLCYCLOPENTANE
DIHETHYLCYCLOPENTENES
DIHETHYLHEXANES
DIMETHYLHEXADIENE
D IHETHYLETHYLCYCLOHEXANE
DIHETHYLOCTANES
DIMETHYLUNDECANE
DIMETHYLDECANE
ETHYLPENTENE
ETHYLCYCLOPENTENE
ETHYLHETHYLCYCLOPENTANE
ETHYLHEXANE
ETHYLHETHYLHEXANE
ETHYLHETHYLCYCLOHEXANES
ETHYLHEPTANE
ETHYLMETHYLOCTANE
ETHYLBICYCLOHEPTANE
ETHYLDIHETHYLPENTANE
TETRAHETHYLCYCLOBUTENE
TRIHETHYLPENTANE
TRIHETHYLPENTADIENE
TRIHETHYLHEPTANES
TRIHETHYLHEXENE
TRIMETHYLOCTANES
TRIMETHYLDECANE
OCTATRIENE
NONENE
PENTAD I ENE
METHYLOCTANES
496-11-7 INOANE
TRIMETHYLCYCLOPENTANE
DIMETHYLCYCLOHEXANE
3073-66-3 TRIMETHYLCYCLOHEXANES
DIMETHYLHEPTANES
UNIDENTIFIED
Spec_HU
96.14
110.17
86.18
84.16
100.20
98.19
98.19
96.17
114.23
110.20
140.26
142.28
184.36
170.34
98.19
96.17
112.21
114.23
128.26
126.24
128.26
156.31
223.42
128.26
110.19
114.22
110.20
142.29
126.24
156.31
184.36
108.19
126.24
68.13
128.26
118.18
112.16
112.24
126.27
128.26
86.00
Spee_WT Peak
0.01
0.01
1.14
0.15
0.18
0.01
0.07
0.15
0.38
0.05
0.04
0.03
0.00
0.03
0.01
0.03
0.06
0.12
0.10
0.03
0.01
0.01
0.00
0.06
0.02
0.34
0.02
0.07
0.02
0.03
0.01
0.00
0.01 .
0.02 '
0.27
0.22
0.04
0.05
0.01
0.08
0.00
TOTAL
99.96
B-44
-------
VOC Profile Specialion Report
Profile Name Organic
Profile Number 9028
Data Quality E
Chemical Storage - Average
Control Device Not Applicable
Reference(s) 93
Data Source Average
sent ing
profile developed from original profiles repre-
the source category 407XXXXX.
SCC Assignments:
Saroad
43111
43114
43224
43231
43232
43238
43243
43248
43264
43292
43303
43306
43308
43309
43310
43317
43351
43373
43374
43376
43377
43378
43379
43403
43404
43405
43407
43409
43432
43434
43437
43438
43440
43451
43468
43502
43503
43504
43505
43510
43511
CAS Number
109-67-1
110-54-3
142-82-5
124-18-5
78-79-5
110-82-7
142-29-0
71-23-8
78-83-1
111-76-2
75-65-0
109-86-4
108-93-0
60-29-7
111-46-6
106-62-7
628-28-4
111-90-0
111-77-3
112-34-5
64-18-6
64-19-7
79-09-4
79-10-7
124-04-9
79-20-9
109-60-4
96-33-3
140-88-5
141-32-2
297-85-8
106-63-8
50-00-0
75-07-0
123-38-6
107-02-8
123-72-8
78-84-2
Name
ISOMERS OF DOOECANE
ISOMERS OF PENTADECANE
1-PENTENE
HEXANE
HEPTANE
N-DECANE
ISOPRENE
CYCLOHEXANE
HEPTENE
CYCLOPENTENE
N-PROPYL ALCOHOL
ISOBUTYL ALCOHOL
BUTYL CELLOSOLVE
TERT- BUTYL ALCOHOL
METHYL CELLOSOLVE
CYCLOHEXANOL
ETHYL ETHER
DIETHYLENE GLYCOL
DIPROPYLENE GLYCOL
METHYL T-BUTYL ETHER
CARBITOL
METHYL CARBITOL
BUTYL CARBITOL
FORMIC ACID
ACETIC ACID
PROP I ON 1C ACID
ACRYLIC ACID
ADIPIC ACID
METHYLACETATE
N-PROPYL ACETATE
METHYL ACRYLATE
ETHYL ACRYLATE
BUTYL ACRYLATE
ISOBUTYL ISOBUTYRATE
ISOBUTYL ACRYLATE
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
ACROLEIN
BUTYRALDEHYDE
ISOBUTYRALDEHYDE
Spec_MU
170.32
212.41
70.13
86.17
100.20
142.28
68.12
84.16
98.18
68.11
60.10
74.12
118.17
74.12
76.11
100.16
74.12
106.12
134.18
88.15
134.18
120.15
162.23
46.03
60.05
74.08
72.06
146.14
74.08
102.15
86.09
100.11
128.17
144.21
128.19
30.03
44.05
58.08
56.07
72.12
72.11
Spec_WT Peak
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
.47
.47
.47
.47
.47
.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
B-45
-------
VOC Profile Speciation Report - continued (profile 9028)
Saroad
43561
43562
43602
43604
43704
43777
43778
43803
43804
43837
43863
43902
45203
45204
45205
45206
45210
45221
45236
45605
45701
45702
45731
45750
45810
90001
90011
TOTAL
CAS Number
108-94-1
110-43-0
75-56-9
108-24-7
107-13-1
141-43-5
67-66-3
56-23-5
106-93-4
106-89-8
75-08-1
100-41-4
95-47-6
108-38-3
106-42-3
98-82-8
25013-15-4
1319-77-3
62-53-3
98-95-3
58-84-9
504-60-9
100-44-7
112-41-4
Name
CYCLOHEXANONE
METHYL AMYL KETONE
PROPYLENE OXIDE
ACETIC ANHYDRIDE
ACRYLONITRILE
ETHANOLAMINE
ETHYLENEAMINES
CHLOROFORM
CARBON TETRACHLORIDE
ETHYLENE D I BROMIDE
EPICHLOROHYDRIN
ETHYL MERCAPTAN
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
CUMENE (ISOPROPYL BENZENE)
METHYL STYRENE
DIISOPROPYL BENZENE
CRESOL
ANILINE
NITROBENZENE
TOLUENE DIISOCYANATE
PIPERYLENE
BENZYL CHLORIDE
DOOECEHE
METHYLALLENE
Spec_MU
98.15
114.21
58.08
102.09
53.06
61.08
45.08
119.39
153.84
187.88
92.53
62.13
106.16
106.16
106.16
106.16
120.20
118.19
162.28
108.14
93.13
123.11
174.17
68.12
126.59
168.32
54.09
Spec_WT Peak
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
.47
.47
.47
.47
.47
.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
1.47
99.96
B-46
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organic Chemical Storage - Fixed Roof Tanks - Alcohols - Average
9029
E
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407008XX.
SCC Assignments:
Saroad
TOTAL
CAS Number
Name
SpecJW Spec_UT Peak
43303
43306
43309
43317
71-33-8
78-83-1
75-65-0
108-93-0
N-PROPYL ALCOHOL
ISOBUTYL ALCOHOL
TERT-BUTYL ALCOHOL
CYCLOHEXANOL
60.10
74.12
74.12
100.16
25.00
25.00
25.00
25.00
100.00
B-47
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Organic
9030
E
Chemical Storage - Fixed Roof Tanks - Alkanes -
Not Applicable
93
Average profile developed from original
senting the source category 407016XX.
.
Saroad CAS Number
43111
43114
43Z32 142-82-5
43238 124-18-5
Name
ISOMERS OF DOOECANE
ISOMERS OF PENTADECANE
HEPTANE
N-DECANE
profiles repre-
SpecJW
170.32
212.41
100.20
142.28
Average
Spec_UT Peak
25.00
25.00
25.00
25.00
TOTAL 100.00
===ss=s===========================:======== =============================================
B-4&
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organic Chemical Storage - Fixed Roof Tanks - Alkenes - Average
9031
Control Device
Referenced)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407020XX.
SCC Assignments:
Saroad
CAS Number
Name
Spec_MW Spec_WT Peak
43264
90001
HEPTENE
112-41-4 DODECENE
98.18
168.32
50.00
50.00
TOTAL
100.00
B-49
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments:
Organic
9032
E
Chemical Storage -
Fixed Roof Tanks - Amines - Average
Not Applicable
93
Average profile developed from original profiles repre-
senting1 the source category 407032XX.
Saroad CAS Number
43777 141-43-5
43778
45701 62-53-3
Name
ETHANOLAHINE
ETHYLENEAHINES
ANILINE
Spec_HW SpecJJT Peak
61.08 33.33
45.08 33.33
93.13 33.33
TOTAL
99.99
B-50
-------
VOC Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Organic Chemical Storage - Fixed Roof Tanks - Aromatics - Average
9033
E
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407036XX.
SCC Assignments:
Saroad
TOTAL
CAS Number
Name
Spec_HW Spec_WT Peak
45203
45204
45205
45206
45210
45221
45236
45605
100-41-4
95-47-6
108-38-3
106-42-3
98-82-8
25013-15-4
1319-77-3
ETHYLBENZENE
0-XYLENE
H-XYLENE
P-XYLENE
CUMENE (ISOPROPYL BENZENE)
METHYL STYRENE
DI1SOPROPYL BENZENE
CRESOL
106.16
106.16
106.16
106.16
120.20
118.19
162.28
108.14
12.50
12.50
12.50
12.50
12.50
12.50
12.50
12.50
100.00
B-51
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organic Chemical Storage - Fixed Roof Tanks - Carboxylie Acids - Average
9034
E
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407040XX.
SCC Assignments:
Soroad
CAS Number
Name
Spec_HW Spec_UT Peak
43403
43404
43405
43407
43409
TOTAL
sss===s===:===3
64-18-6
64-19-7 .
79-09-4
79-10-7
124-04-9
:==s=s=:=srs=s
FORMIC ACID
ACETIC ACID
PROP I OH 1C ACID
ACRYLIC ACID
ADIPIC ACID
=======~r:=====:s:s==s:s:=s:s:==
46.03
60.05
74.08
72.06
146.14
===================
20.00
20.00
20.00
20.00
20.00
100.00
=================
B-52
-------
VOC Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Organic Chemical Storage - Fixed Roof Tanks - Esters - Average
9035
E
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407044XX.
SCC Assignments:
Saroad
CAS Number
Name
Spec_MU SpecJJT Peak
43432
43434
43437
43438
43440
43451
43468
TOTAL
79-20-9
109-60-4
96-33-3
140-88-5
141-32-2
297-85-8
106-63-8
METHYLACETATE
N-PROPYL ACETATE
METHYL ACRYLATE
ETHYL ACRYLATE
BUTYL ACRYLATE
ISOBUTYL ISOBUTYRATE
1SOBUTYL ACRYLATE
74.08
102.15
86.09
100.11
128.17
144.21
128.19
========:
14.29
14.29
14.29
14.29
14.29
14.29
14.29
100.03
B-53
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Organic Chemical Storage - Fixed Roof Tanks - Glycol Ethers - Average
9036
E
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407052XX.
SCC Assignments:
Saroad
CAS Number
Name
SpecJW Spec_UT Peak
43308
43310
43373
43377
43378
43379
111-76-2
109-86-4
111-46-6
111-90-0
. 111-77-3
112-34-5
BUTYL CELLOSOLVE
METHYL CELLOSOLVE
DIETHYLENE GLYCOL
CARBITOL
METHYL CARBITOL
BUTYL CARBITOL
118.17
76.11
106.12
134.18
120.15
162.23
16.67
16.67
16.67
16.67
16.67
16.67
TOTAL
100.02
B-54
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organic Chemical Storage - Fixed Roof Tanks - Glycols - Average
9037
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407056XX.
SCC Assignments:
Saroad
43374
CAS Number
106-62-7
Name
DIPROPYLENE GLYCOL
Spec_MW Spec_WT Peak
134.18 100.00
TOTAL
100.00
B-55
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Organic Chemical Storage - Fixed Roof Tanks - Halogenated Organics
9038
E
Average
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407060XX.
SCC Assignments:
Saroad
CAS Hunker
Name
Spec_HU Spec_UT Peak
43804
43837
43863
45810
TOTAL
==========:
56-23-5
106-93-4
106-89-8
100-44-7
S============!
CARBON TETRACHLORIDE
ETHYLENE D I BROMIDE
EPICHLOROHYDRIN
BENZYL CHLORIDE
:==============================
153.84
187.88
92.53
126.59
==================:
25.00
25.00
25.00
25.00
100.00
; ===========s
B-56
-------
VOC Profile Special ion Report
Profile Name
Profile Number
Data Quality
Organic Chemical Storage - Fixed Roof Tanks - Isocyanates - Average
9039
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407064XX.
SCC Assignments:
Saroad
45731
TOTAL
CAS Number
58-84-9
Name
TOLUENE
SpecJW Spec_WT
DIISOCYANATE 174.17 100.00
100.00
Peak
B-57
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organic Chemical Storage - Fixed Roof Tanks - Ketones - Average
9040
E
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407068XX.
SCC Assignments:
Saroad
43561
43562
CAS Number
108-94-1
110-43-0
Name
CYCLOHEXANONE
METHYL AHYL KETONE
Spec_MW
98.15
114.21
Spec_UT
50.00
50.00
Peak
TOTAL
100.00
=:::==: =::==£::::!:=::=:==:=:=::::==::: =:==:=
B-58
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Referenced)
Data Source
Organic Chemical Storage - Floating Roof Tanks - Aldehydes - Average
9041
E
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407172XX.
SCC Assignments:
Saroad
CAS Number
Name
Spec_MU Spec_WT Peak
43502
43504
43510
43511
50-00-0
123-38-6
123-72-8
78-84-2
FORMALDEHYDE
PROP I ON ALDEHYDE
BUTYRALDEHYDE
ISOBUTYRALDEHYDE
30.03
58.08
72.12
72.11
25.00
25.00
25.00
25.00
TOTAL
100.00
B-59
-------
VOC Profile Speciation Report
Profile Name
Profile Umber
Data Quality
Organic Chemical Storage Floating Roof Tanks - Alkanes - Average
9042
E
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407176XX.
SCC Assignments:
Saroad
43231
43248
CAS Number
110-54-3
110-82-7
Name
HEXAHE
CYCLOHEXANE
Spec_MW
86.17
84.16
Spec_UT
50.00
50.00
Peak
TOTAL
100.00
B-60
-------
VOC Profile, Speciation Report
Organic Chemical Storage - Floating Roof Tanks - Ethers - Average
Profile Name
Profile Number
Data Quality
9043
E
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407208XX.
SCC Assignments:
Saroad
CAS Number
Name
Spec_HW Spec_WT Peak
43351
43602
TOTAL
60-29-7
75-56-9
ETHYL ETHER
PROPYLENE OXIDE
74.12 50.00
58.08 50.00
100.00
=============================================
B-61
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Organic Chemical Storage - Floating Roof Tanks - Halogenated Organics - Average
9044
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407220XX.
SCC Assignments:
Saroad
43803
43804
CAS Number
67-66-3
56-23-5
Name
CHLOROFORM
CARBON TETRACHLORIDE
Spec_MU
119.39
153.84
Spec_UT
50.00
50.00
Peak
TOTAL
100.00
B-62
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organic Chemical Storage - Pressure Tanks - Alkenes - Average
9046
E
Control Device
Reference(s)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 407820XX.
SCC Assignments:
Saroad
TOTAL
CAS Number
Name
SpecJW Spec_WT Peak
43224
43243
43292
45750
90011
109-67-1
78-79-5
142-29-0
504-60-9
1-PENTENE
ISOPRENE
CYCLOPENTENE
PIPERYLENE
METHYLALLENE
70.13
68.12
68.11
68.12
54.09
20.00
20.00
20.00
20.00
20.00
100.00
B-63
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Organic Solvent Evaporation Miscellaneous - Average
9047
E
Control Device
Referenced)
Data Source
Not Applicable
93
Average profile developed from original profiles repre-
senting the source category 490XXXXX.
SCC Assignments:
Saroad
TOTAL
CAS Number
Name
Spec_MU SpecJJT Peak
43369
43370
43441
45300
45503
45801
45805
46210
57-55-6
107-21-1
80-62-6
108-95-2
98-01-1
' 108-90-7
95-50-1
8001-58-9
PROPYLENE GLYCOL
ETHYLENE GLYCOL
METHYL METHACRYLATE
PHENOL
2- FURFURAL
CHLOROBENZENE
0-DICHLOROBENZENE
CREOSOTE
76.11
62.07
100.13
94.11
96.09
112.56
147.01
130.19
12.50
12.50
12.50
12.50
12.50
12.50
12.50
12.50
100.00
B-64
-------
VOC Profile Speciation Report
Profile Name
Over all
Average
Profile Number 0000
Data Quality
E
Control Device NOT APPLICABLE
Reference(s)
Data Source
93
Profile
based on average of all profiles.
SCC Assignments
Saroad
43105
43106
43107
43108
43109
43110
43111
43113
43114
43115
43116
43117
43118
43119
43120
43121
43122
43125
43126
43127
43129
43130
43131
43132
43133
43140
43141
43143
43144
43145
43150
43155
43156
43201
43202
43203
43204
43205
43206
43212
43213
43214
CAS Number
64475-85-0
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
106-97-8
106-98-9
75-28-5
Name
ISOHERS OF HEXANE
ISOHERS OF HEPTANE
ISOHERS OF OCTANE
I SOBERS OF NONANE
ISOMERS OF DECANE
ISOHERS OF UNDECANE
ISOHERS OF DODECANE
ISOHERS OF TETRADECANE
ISOHERS OF PENTADECANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
HINERAL SPIRITS
LACTOL SPIRITS
ISOHERS OF BUTENE
ISOHERS OF PENTENE
ISOHERS OF PENTANE
C10 OLEFINS
C2 CYCLOHEXANE
C3 CYCLOHEXANE
C4 SUBSTITUTED CYCLOHEXANE
C5 SUBSTITUTED CYCLOHEXANE
C6 SUBSTITUTED CYCLOHEXANE
ALIPHATICS
PARAFFINS (C16-C34)
C7-C16 PARAFFINS
C8 PARAFFIN
C5 OLEFIN
C5 PARAFFIN
C5 PARAFFIN/OLEFIN
ISOHERS OF C10H18
ISOHERS OF HEPTADECANE
ISOHERS OF OCTADECANE
HETHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
N-BUTANE
BUTENE
I SO- BUTANE
Spec_HU
86.17
100.20
114.23
128.25
142.28
156.30
170.32
198.38
212.41
98.19
112.23
126.26
114.00
114.00
56.10
70.13
72.15
140.27
112.22
126.24
140.27
154.30
168.32
100.00
352.43
156.31
114.23
70.13
72.15
70.13
138.25
240.47
254.50
16.04
30.07
28.05
44.09
42.08
26.04
58.12
56.10
58.12
Spec_WT Peak
0.54
0.25
0.15
0.19
0.40
0.05
0.46
0.01
0.42
0.71
0.05
0.00
0.64
0.36
0.05
0.05
1.11
0.03
0.01
0.01
0.01
0.01
0.01
0.10
0.02
0.15
0.02
0.01
0.01
0.00
0.01
0.01
0.01
7.36
1.39
2.86
2.40
1.40
0.86
1.81
0.40
0.42
B-65
-------
VOC Profile Specialion Report - continued (profile 0000)
Saroad
43216
43218
43220
43221
43224
43225
43226
43227
43228
43229
43230
43231
43232
43233
43235
43238
43241
43242
43243
43245
43247
43248
43250
43255
43256
43257
43258
43259
43260
43261
43262
43264
43273
43277
43280
43281
43282
43283
43284
43285
43286
43288
43291
43292
43295
43301
43302
43303
43304
43305
43306
43308
CAS Nuifcer
624-64-6
106-99-0
109-66-0
78-78-4
109-67-1
563-46-2
646-04-8
627-20-3
513-35-9
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
111-84-2
124-18-5
1120-21-4
287-92-3
78-79-5
592-41-6
108-08-7
110-82-7
540-84-1
112-40-3
80-56-8
127-91-3
629-50-5
629-59-4
629-62-9
108-87-2
96-37-7
110-83-8
107-00-6
503-17-3
625-27-4
1678-91-7
75-83-2
142-29-0
589-34-4
67-56-1
64-17-5
71-23-8
67-63-0
71-36-3
78-83-1
111-76-2
Name
T-2-BUTEWE
1,3-BUTADIENE
N-PENTANE
ISO PENTANE
1-PENTENE
2-METHYL-1-BUTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-METHYL-2-BUTENE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
MONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
ISOPRENE
1-HEXENE
2,4-DIHETHYLPENTANE
CYCLOHEXANE
2,2,4-TRIMETHYLPENTANE
N-OODECANE
A-PINENE
B-PINENE
N-TRIDECANE
N-TETRADECANE
N-PENTADECANE
HETHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
HEPTENE
CYCLOHEXENE
2,4-DIHETHYLHEXANE
2,3,3 TRIHETHYLPENTANE
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-HETHYL-2-PENTENE
2-HEXENE
DIHETHYLHEXENE
ETHYLCYCLOHEXANE
2,2-DIMETHYLBUTANE
CYCLOPENTENE
3-HETHYLKEXANE
METHYL ALCOHOL
ETHYL ALCOHOL
N-PROPYL ALCOHOL
ISO-PROPYL ALCOHOL
N-BUTYL ALCOHOL
ISOBUTYL ALCOHOL
BUTYL CELLOSOLVE
Spec_MU
56.11
54.09
72.15
72.15
70.13
70.13
70.13
70.13
70.13
86.17
86.17
86.17
100.20
114.23
128.25
142.28
156.31
70.14
68.12
84.16
100.20
84.16
114.22
170.33
136.24
136.24
184.36
198.38
212.41
98.21
84.16
98.18
82.14
114.22
114.22
54.09
54.09
84.16
84.16
84.16
112.20
112.23
86.17
68.11
100.20
32.04
46.07
60.10
60.09
74.12
74.12
118,17
Spec_WT Peak
0.01
0.67
0.71
0.08
0.54
0.01
0.01
0.00
0.00
0.02
0.03
1.37
1.40
0.21
0.09
0.54
0.14
0.01
0.40
0.03
0.04
0.90
0.01
0.19
0.35
0.23
0.10
0.07
0.17
0.13
0.27
0.51
0.01
0.06
0.00
0.02
0.01
0.01
0.01
0.01
0.00
0.02
0.00
0.40
0.01
1.40
1.36
0.42
0.73
0.69
0.42
0.44
B-66
-------
VOC Profile Speciation Report - continued (profile 0000)
Saroad
43309
43310
43311
43313
43314
43317
43318
43322
43350
43351
43367
43369
43370
43371
43373
43374
43376
43377
43378
43379
43403
43404
43405
43407
43408
43409
43430
43432
43433
43434
43435
43437
43438
43440
43441
43444
43450
43451
43452
43453
43454
43455
43456
43457
43458
43459
43467
43468
43469
43472
43502
43503
CAS Nunber
75-65-0
109-86-4
110-80-5
78-92-2
108-93-0
104-76-7
110-63-4
115-10-6
60-29-7
111-46-6
57-55-6
107-21-1
107-41-5
111-46-6
106-62-7
628-28-4
111-90-0
111-77-3
112-34-5
64-18-6
64-19-7
79-09-4
79-10-7
57-10-3
124-04-9
107-31-3
79-20-9
141-78-6
109-60-4
138-22-7
96-33-3
140-88-5
141-32-2
80-62-6
108-21-4
68-12-2
297-85-8
111-15-9
108-05-4
112-39-0
124-10-7
112-61-8
109-87-5
106-63-8
124-17-4
50-00-0
75-07-0
Name
TERT-BUTYL ALCOHOL
METHYL CELLOSOLVE
CELLOSOLVE
1-ETHOXY-2-PROPANOL
S-BUTYL ALCOHOL
CYCLOHEXANOL
2-ETHYL HEXANOL
1,4 BUTANEDIOL
DIMETHYLETHER
ETHYL ETHER
GLYCOL ETHER
PROPYLENE GLYCOL
ETHYLENE GLYCOL
HEXYLENE GLYCOL
D I ETHYLENE GLYCOL
01 PROPYLENE GLYCOL
METHYL T-BUTYL ETHER
CARBITOL
METHYL CARBITOL
BUTYL CARBITOL
FORMIC ACID
ACETIC ACID
PROP I ON 1C ACID
ACRYLIC ACID
PALMITIC ACID
ADIPIC ACID
METHYL FORMATE
METHYLACETATE
ETHYL ACETATE
N-PROPYL ACETATE
N-BUTYL ACETATE
METHYL ACRYLATE
ETHYL ACRYLATE
BUTYL ACRYLATE
METHYL METHACRYLATE
ISOPROPYL ACETATE
DIMETHYL FORMAMIDE
ISOBUTYL ISOBUTYRATE
CELLOSOLVE ACETATE
VINYL ACETATE
METHYL PALMITATE
METHYL MYRISTATE
METHYL STEARATE
METHYLAL
SUBSTITUTED C9 ESTER (C12)
C5 ESTER
C4 SUBSTITUTED CYCLOHEXANONE
ISOBUTYL ACRYLATE
BUTOXYETHOXYETHANOL ACETATE
BUTOXYBUTENE
FORMALDEHYDE
ACETALDEHYDE
Spec_HW
74.12
76.11
90.12
104.15
74.12
100.16
130.23
90.12
46.07
74.12
106.14
76.11
62.07
118.18
106.12
134.18
88.15
134.18
120.15
162.23
46.03
60.05
74.08
72.06
256.43
146.14
60.05
74.08
88.10
102.15
116.16
86.09
100.11
128.17
100.13
102.13
73.09
144.21
132.16
86.09
270.46
242.41
298.52
76.11
218.24
130.19
154.26
128.19
220.26
128.21
30.03
44.05
Spee_WT Peak
0.42
0.39
0.36
0.00
0.34
0.45
0.00
0.04
1.12
0.62
0.05
0.38
0.37
0.36
0.39
0.66
0.33
0.46
0.39
0.39
0.42
0.73
0.40
0.45
0.20
0.40
0.21
0.71
0.44
0.49
0.58
0.38
0.50
0.43
0.46
0.47
0.36
0.39
0.36
0.55
0.08
0.03
0.11
0.17
0.09
0.02
0.01
0.38
0.01
0.01
1.55
0.84
B-67
-------
VOC Profile Speciation Report - continued (profile 0000)
S a road
43504
43505
43510
43511
43513
43514
43520
43551
43552
43560
43561
43562
43562
43563
43567
43568
43570
43601
43602
43603
43604
43704
43721
43740
43776
43777
43778
43802
43803
43804
43805
43811
43812
43814
43815
43817
43820
43821
43822
43823
43824
43835
43837
43838
43839
43840
43841
43842
43843
43844
43845
43860
CAS Number
123-38-6
107-02-8
123-72-8
78-84-2
107-22-2
78-98-8
67-64-1
78-93-3
108-10-1
108-94-1
110-43-0
110-43-0
7379-12-6
75-21-8
75-56-9
108-31-6
108-24-7
107-13-1
75-05-7
75-50-3
124-09-4
141-43-5
75-09-2
67-66-3
56-23-5
74-95-3
75-69-4
75-00-3
71-55-6
107-06-2
127-18-4
79-00-5
76-13-1
75-71-8
79-01-6
78-86-4
106-93-4
26638-19-7
75-73-0
75-45-6
76-14-2
76-15-3
76-16-4
75-46-7
75-72-9
75-01-4
Name
PROPIONALDEHYDE
ACROLEIN
BUTYRALDEHYDE
ISOBUTYRALDEHYOE
GLYOXAL
METHYL GLYOXAL
TOTAL C2-C5 ALDEHYDES
ACETONE
HETHYL ETHYL KETONE
HETHYL ISOBUTYL KETONE
CYCLOHEXANONE
HETHYL AHYL KETONE
HETHYL AHYL KETONE
2-METHYL-3-HEXANONE
TETRAMETHYLPEMTANONE
NONENONE
ALKENE KETONE
ETHYLENE OXIDE
PROPYLENE OXIDE
HALE 1C ANHYDRIDE
ACETIC ANHYDRIDE
ACRYLONITRILE
ETHYLAHINE
TRIHETHYLAMINE
HEXAMETHYLENEDIAMINE
ETHANOLAHINE
ETHYLENEAMINES
DICHLOROMETHANE
CHLOROFORM
CARBON TETRACHLORIDE
METHYLENE BROMIDE
TRICHLOROFLUOROMETHANE
ETHYL CHLORIDE
1,1,1-TRICHLOROETHANE
ETHYLENE DICHLORIDE
PERCHLOROETHYLENE
1,1,2-TRICHLOROETHANE
TR I CHLOROTR1 FLUOR OETHANE
TRIMETHYLFLUOROSILANE
D I CHLOROD I FLUOROMETHANE
TRICHLOROETHYLENE
1-CHLOROBUTANE
ETHYLENE D I BROMIDE
PROPYLENE DICHLORIDE
TETRAFLUOROMETHANE
CHLOROO I FLUOROMETHANE
D I CHLOROTETRAFLUORETHANE
CHLOROPENTAFLUOROETHANE
HEXAFLUOROETHANE
TR I FLUOROMETHANE
CHLOROTRI FLUOROHETHANE
VINYL CHLORIDE
Spec_MU
58.08
56.07
72.12
72.11
58.04
72.07
72.12
58.08
72.10
100.16
98.15
114.21
114.21
114.19
142.24
140.22
72.10
44.05
58.08
98.06
102.09
53.06
45.09
59.11
116.20
61.08
45.08
84.94
119.39
153.84
173.85
137.38
64.52
133.42
99.00
165.83
133.42
187.38
92.00
120.91
131.40
92.57
187.88
112.99
88.01
86.47
170.92
154.47
138.01
70.01
104.46
62.50
Spee_UT Peak
0.42
0.77
0.44
0.42
0.02
0.02
0.12
1.47
1.22
0.56
0.53
0.50
0.01
0.07
0.00
0.02
0.01
0.38
0.50
0.07
0.35
0.58
0.00
0.00
0.67
0.44
0.44
0.75
0.51
0.65
0.03
0.61
0.29 .
0.43
0.58
0.70
0.35
0.40
0.69
0.35
0.43
0.01
0.42
0.02
0.03
0.16
0.01
0.02
0.40
0.30
0.05
0.42
B-68
-------
VOC Profile Speciation Report - continued (profile 0000)
Saroad
43862
43863
43902
43933
43934
43950
43951
45101
45102
45104
45105
45106
45107
45108
45109
45110
45201
45202
45203
45204
45205
45206
45207
45208
45210
45212
45220
45221
45226
45228
45232
45233
45236
45238
45243
45244
45245
45300
45401
45402
45403
45451
45452
45455
45456
45477
45501
45502
45503
45601
45605
45701
CAS Nuriber
126-99-8
106-89-8
75-08-1
433-58-1
75-15-0
556-67-2
8030-30-6
1330-20-7
25551-13-7
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
106-42-3
108-67-8
95-63-6
98-82-8
620-14-4
100-42-5
25013-15-4
92-52-4
103-29-7
108-95-2
65-85-0
100-21-0
131-11-3
84-74-2
136-60-7
85-68-7
100-52-7
104-87-0
98-01-1
85-44-9
1319-77-3
62-53-3
N 311)6
CHLOROPRENE
EPICHLOROHYDRIN
ETHYL HERCAPTAN
CARBONYL SULFIDE
CARBON SULFIDE
OCTAHETHYLCYCLOTETRASILOXANE
SILOXANE
NAPHTHA
ISOMERS OF XYLENE
ISOHERS OF ETHYLTOLUENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF DIETHYLBENZENE
TRIHETHYLBENZENE
ISOMERS OF PROPYLBENZENE
C3/C4/C5 ALKYLBENZENES
C10 AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
1,3,5-TRIMETHYLBENZENE
1 ,2,4-TRIMETHYLBENZENE
CUMENE (ISOPROPYL BENZENE)
M-ETHYLTOLUENE
STYRENE
METHYL STYRENE
BIPHENYL
ETHYL STYRENE
DIPHENYL ETHANE
ETHYL-PHENYL-PHENYL-ETHANE
01 ISOPROPYL BENZENE
ETHYLTOLUENE
ETHYLDIMETHYLBENZENE
TETRAMETHYLBENZENE
C5 -ALKYLBENZENES
PHENOL
XYLENE BASE ACIDS
BENZOIC ACIO
TEREPHTHALIC ACID
DIMETHYL PHTHALATE
D I BUTYL PHTHALATE
BUTYL BENZOATE
BUTYLISOPROPYLPHTHALATE
BUTYLBENZYLPHTHALATE
BENZALDEHYDE
P-TOLUALDEHYDE
2 -FURFURAL
PHTHALIC ANHYDRIDE
CRESOL
ANILINE
Spec.MU
88.54
92.53
62.13
60.08
76.13
296.62
76.08
114.00
106.16
120.19
134.22
134.21
120.19
120.19
134.21
134.22
78.11
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.20
120.19
104.14
118.19
154.21
132.21
182.27
210.32
162.28
120.19
134.22
134.22
148.24
94.11
230.00
122.13
166.14
194.19
278.35
178.23
264.32
312.39
106.13
120.16
96.09
148.12
108.14
93.13
Spec_WT Peak
0.34
0.42
0.33
0.03
0.09
0.01
0.00
0.47
0.70
0.04
0.06
0.03
0.11
0.02
0.03
0.01
2.82
2.04
0.65
0.59
0.57
0.40
0.03
0.01
0.38
0.03
1.20
0.41
0.01
0.03
0.00
0.01
0.38
0.02
0.00
0.00
0.00
0.44
0.00
0.04
0.00
0.06
0.04
0.21
0.05
0.00
0.02
0.00
0.37
0.20
0.38
0.79
B-69
-------
VOC Profile Speciation Report - continued (profile 0000}
Sarosd
45702
45703
45705
45731
45740
45750
45801
45805
45807
45808
45810
45830
46102
46112
46114
46210
46701
46702
46705
46706
46707
46708
46710
46711
46713
46714
46715
46717
90001
90010
90011
90014
90019
90020
90021
90026
90028
90030
90047
90048
90049
90050
90051
90052
90053
90060
90064
90067
90070
90072
90076
90081
CAS Number
98-95-3
58-84-9
504-60-9
108-90-7
95-50-1
106-46-7
2531-22-6
100-44-7
84-65-1
103-71-9
100-61-8
8001-58-9
91-12-3
208-96-8
83-32-9
86-73-7
85-01-8
206-44-0
129-00-0
218-01-9
205-99-2
112-41-4
8720-50-9
544-76-3
5794-03-6
123-35-3
5989-27-5
79-29-8
Name
NITROBENZENE
2,2 DICHLORONITROANILINE
BROHOD I N I TR08EN2ENE
TOLUENE DIISOCYANATE
TOTAL AROMATIC AMINES
PIPERYLENE
CHLOROBENZENE
0-DICHLOR06ENZENE
P-D I CHLOROBENZENE
DICHLOROBENZENES
BENZYL CHLORIDE
TRICHLOR06ENZENES
ANTHRAQUINONE
PHENYL ISOCYANATE
4-METHYL ANILINE
CREOSOTE
NAPTHALENE
METHYL NAPHTHALENES
ACENAPHTHYLENE
ACENAPHTHENE
FLUORENE
PHENANTHRENE
FLUORANTHENE
C2 ALKYL INDAN
PYRENE
BENZO(g,h,i) FLUORANTHENE
CHRYSENE
BENZO (b) FLUORANTHENE
DOOECENE
M-XYLENE AND P-XYLENE
HETHYLALLENE
1-DECENE
C6H1803SI3
C8H2404SI4
HETHYLPROPANE
METHYLPENTANE
METHYLHEXANE
HEXADECAME
HETHYLNONANE
METHYLDECANES
HETHYLUNDECANE
CAMPHENE
MYRCENE
B-PHELLANDRENE
D-LIMONENE
DIMETHYLDUTANE
DIMETHYLCYCLOPENTANE
DIHETHYLHEXANES
DIMETHYLOCTANES
METHYLPROPYLCYCLOHEXANES
DIMETHYLNONANES
ETHYLHEXANE
Spec.MU
123.11
207.02
247.02
174.17
93.13
68.12
112.56
147.01
147.01
147.01
126.59
181.45
208.23
119.13
107.17
130.19
128.17
142.20
152.20
154.21
166.22
178.23
202.26
146.23
202.26
252.32
228.29
252.32
168.32
106.16
54.09
140.27
222.47
296.60
58.12
86.17
100.20
226.45
142.28
156.32
170.34
136.24
136.24
136.24
136.24
86.18
98.19
114.23
142.28
140.27
156.31
114.23
Spec_WT Peak
0.33
0.01
0.01
0.66
0.04
0.40
0.71
0.40
0.72
0.02
0.42
0.01
0.01
0.12
0.03
0.37
0.18
0.04
0.02
0.00
0.01
0.06
0.01
0.04
0.01
0.00
0.01
0.00
0.50
0.13
0.40
0.01
0.09
0.03
0.01
0.01
0.03
0.01
0.02
0.02
0.01
0.01
0.01
0.01
0.05
0.01
0.01
- o.oo
0.03
0.01
0.00
0.02
B-70
-------
VOC Profile Speciation Report - continued (profile 0000)
Saroad
90083
90094
90101
90104
90120
98054
98057
98058
98059
98060
98062
98063
98082
98083
98090
98091
98106
99912
99918
99933
99999
CAS Nunber Name
ETHYLNETHYLCYCLOHEXANES
TRIMETHYLHEPTANES
1678-93-9 BUTYLCYCLOHEXANE
HETHYLOCTANES
PROPYLCYCLOHEXANE
107-39-1 2,4,4-TRIMTHYL-1-PENTENE
1640-89-7 ETHYLCYCLOPENTANE
TRIHETHYLCYCLOPENTANE
DIMETHYLCYCLOHEXANE
3073-66-3 TRIMETHYLCYCLOHEXANES
DIETHYLCYCLOHEXANE
N-PENTYLCYCLOHEXANE
ETHYLHEPTENE
TRIMETHYLDECENE
METHYLHEPTENE
DIMETHYLHEPTANES.
ETHYLISOPROPYL ETHER
1 -HETHYL-3-ETHYLBENZENE
2-METHYLDECANE
DENATURANT
UNIDENTIFIED
SpecJW
126.24
142.29
140.27
128.26
126.24
112.22
98.19
112.16
112.24
126.27
140.27
154.30
126.24
182.35
112.22
128.26
88.15
120.19
156.32
32.04
86.00
Spec_UT Peak
0.02
0.02
0.01
0.01
0.01
0.01
0.01
0.01
0.05
0.02
0.03
0.01
0.01
0.02
0.00
0.00
0.02
0.00
0.00
0.10
0.25
TOTAL
99.96
B-71
-------
-------
APPENDIX C
VOC PROFILE ASSIGNMENTS
-------
C-2
-------
APPENDIX C
VOC PROFILE ASSIGNMENTS
The activities where VOC species profiles are applied typically employ
Source Classification Codes (SCC's) for point sources and area source codes
from the National Emissions Data System (NEDS) to represent the emission
source categories. Ideally, each source category would be characterized by an
appropriate VOC (and/or PM) profile. However, there are a limited number of
VOC species profiles that represent a relatively small number of source
categories. To increase the usefulness of a given VOC profile and to
characterize those source categories for which there are no profiles, VOC
profile assignments are made based on engineering judgement.
For several SCC's in the Criteria Pollutant Emission Factor document,
the VOC emission factor is designated as "zero" or "negligible." Profile 0000
was assigned to these categories. As described in Appendix B, Profile 0000 is
an overall average of all the profiles in the VOC species profile data base.
It is intended for use as a default profile in large-scale computer
applications of the VOC data base for developing emission inventories. In
such applications, the "zero" profile will not be used unless nonzero VOC
emissions are reported by the States or any other agency for an SCC which is
designated in the Criteria Pollutant Emission Factor document as having a
"zero" or "negligible" emission factor. For some SCC's, profile assignments
were made although the VOC emission factor was "zero" or "negligible." These
SCC's involved profiles with high data quality levels.
There were several cases where it was not possible to make an assignment
based on engineering judgement. For these cases, industry-specific average
profiles were developed from original profiles representing individual SCC's
within the particular industry group.
Table C-l is the listing of all the point source categories that are
characterized by the VOC profiles included in this document. Descriptions of
the source categories represented by SCC's can be obtained from "Criteria
Pollutant Emission Factors for the 1985 NAPAP Emissions Inventory" (EPA-600/
C-3
-------
7-87-015). Table C-2 Is the listing for the area source codes. In addition
to the area source codes from NEDS, profile assignments are provided for
additional area source codes used in the National Acid Precipitation
Assessment Program (NAPAP). A listing of area source codes and their
descriptions are presented in Table C-3.
The entry "Data Quality" in the two tables is based on the Profile Data
Quality description. Where the VOC profile assignment is based on an original
profile, this parameter reflects the Profile Data Quality as it appears in
Section 3. In cases where the assignment is based on engineering judgement
(as indicated by an asterisk [*]), the data quality is lowered one or more
levels, depending on how well the profile represents the "new" source
category. If an original profile represents a pure compound, then the data
quality is kept the same when this profile is used to represent the source
categories describing the storage of that compound. For industry-specific
average profiles, the data quality level associated with the assignment is
"E." These profiles are recommended for use only if there is no other
information available.
C-4
-------
TABLE C-l. POINT SOURCE PROFILE ASSIGNMENTS
Page No.
10/11/89
sec
10100101
10100102
10100201
10100202
10100203
10100204
10100205
10100212
10100217
10100221
10100222
10100223
10100224
10100225
10100226
10100301
10100302
10100303
10100304
10100306
10100401
10100404
10100405
10100406
10100501
10100504
10100505
10100601
10100602
10100604
10100701
10100702
10100801
10100901
10100902
10100903
10101001
10101002
10101101
10101201
10101301
10101302
PROFILE
NUMBER
1178*
1178*
1178*
1178
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
0001
0001*
0001*
0001*
0002
0002*
0002*
0003
0003*
0003*
0004*
0004*
0005*
1084*
1084*
1084*
0003*
0003*
0003*
0122*
0122*
0001*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
B
C
C
C
B
C
C
B
C
C
D
D
C
E
E
E
C
C
C
E
E
C
C-5
-------
TABLE C-l. (Continued)
Page No.
10/11/89
sec
10200101
10200104
10200107
10200201
10200202
10200203
10200204
10200205
10200206
10200210
10200212
10200213
10200217
10200219
10200221
10200222
10200223
10200224
10200225
10200226
10200229
10200301
10200302
10200303
10200304
10200306
10200307
10200401
10200402
10200403
10200404
10200405
10200501
10200502
10200503
10200504
10200505
10200601
10200602
10200603
10200604
10200701
PROFILE
NUMBER
1185*
1185*
1185*
1185*
1185*
1185*
1185
1185*
1185*
1185*
1185*
1085
1185*
1185*
1185*
1185*
1185*
1185*
1185*
1185*
1185*
1185*
1185*
1185*
1185*
1185*
1185*
0001
0001*
0001*
0001*
0001*
0002
0002*
0002*
0002*
0002*
0003
0003*
0003*
0003*
0004
QUALITY
E
E
E
E
E
E
D
E
E
E
E
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
B
C
C
C
C
B
C
C
C
C
B
C
C
C
C
C-6
-------
TABLE C-l. (Continued)
Page No.
10/11/89
sec
10200704
10200707
10200710
10200799
10200802
10200804
10200901
10200902
10200903
10200904
10200905
10200906
10200907
10201001
10201002
10201101
10201201
10201301
10201302
10201401
10201402
10201403
10201404
10300101
10300102
10300103
10300205
10300206
10300207
10300208
10300209
10300211
10300214
10300216
10300217
10300221
10300222
10300223
10300224
10300225
10300226
10300305
PROFILE
NUMBER
0004*
0005
0004*
0004*
0005*
0005*
1084*
1084*
1084*
1084*
1084*
1084*
1084*
0003*
0003*
1084*
0122*
0122*
0001*
0003*
0004*
0002*
0001*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
QUALITY
D
B
D
D
C
C
E
E
E
E
E
E
E
C
C
E
E
E
C
C
D
C
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-7
-------
TABLE C-l. (Continued)
Page No.
10/11/89
sec
10300306
10300307
10300309
10300401
10300402
10300403
10300404
10300501
10300502
10300503
10300504
10300601
10300602
10300603
10300701
10300799
10300901
10300902
10300903
10301001
10301002
10301201
10301301
10301302
10301303
10500102
10500105
10500106
10500110
10500202
10500205
10500206
10500209
10500210
20100101
20100102
20100201
20100202
20100702
20100901
20100902
20101001
PROFILE
NUMBER
1178*
1178*
1178*
0001
0001*
0001*
0001*
0002
0002*
0002*
0002*
0003
0003*
0003*
0004*
0004*
1084*
1084*
1084*
0003*
0003*
0122*
0122*
0001*
0122*
1178*
0002*
0003
0003*
1178*
0002
0003
1084*
0003*
1098*
0009
0007*
1001
1001*
1098*
1098*
0000*
QUALITY
E
E
E
B
C
C
C
B
C
C
C
B
C
C
D
D
D
D
D
C
C
E
E
C
E
E
C
B
E
E
B
B
D
C
C
D
D
C
D
C
C
E
C-8
-------
TABLE C-l. (Continued)
Page No.
10/11/89
sec
20200101
20200102
20200103
20200104
20200201
20200202
20200203
20200204
20200301
20200401
20200402
20200403
20200501
20200901
20200902
20201001
20201002
20300101
20300102
20300201
20300202
20300301
20301001
20301002
20400101
20400102
20400201
20400301
20400302
20400401
20400402
28888801
28888802
28888803
30100101
30100102
30100103
30100104
30100105
30100106
30100107
30100108
PROFILE
NUMBER
1098*
0009
1098*
0009*
0007
1001
0007*
1001
1101*
0008
1201*
1201*
0009*
1098*
1098*
1001*
1001*
0009
1098*
1001
1001*
1101*
1001*
1001*
1098*
1098*
9002*
0007*
1001*
1101*
0008
9002*
9002*
9002*
1110*
1110*
0299*
0000*
1110*
0000*
1110*
0000*
QUALITY
C
D
C
E
C
C
D
C
C
C
D
D
E
C
C
D
D
D
C
C
D
C
D
D
C
C
E
D
D
C
C
E
E
E
E
E
E
E
E
E
E
E
C-9
-------
TABLE C-l. (Continued)
Page No.
10/11/89
sec
30100109
30100180
30100199
30100305
30100306
30100307
30100308
30100309
30100399
30100501
30100502
30100503
30100504
30100506
30100507
30100508
30100509
30100599
30100601
30100603
30100604
30100605
30100699
30100799
30100801
30100802
30100803
30100804
30100805
30100899
30100901
30100902
30100910
30100999
30101011
30101012
30101013
30101014
30101015
30101021
30101022
30101023
PROFILE
NUMBER
0000*
1110*
1110*
9004*
0003*
0001*
9004*
9004*
9004*
1002*
0000*
1002*
1002
0000*
0003*
0000*
0000*
1002*
0307*
0307*
0307*
0000*
9004*
9004*
0000*
0000*
0000*
0000*
0000*
9004*
9017*
9017*
9017*
9017*
0000*
0000*
0000*
0000*
0122*
0000*
0000*
0122*
QUALITY
E
E
E
E
C
C
E
E
E
E
E
E
D
E
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-10
-------
TABLE C-l. (Continued)
Page No.
10/11/89
sec
30101030
30101099
30101101
30101198
30101199
30101202
30101203
30101204
30101205
30101206
30101299
30101301
30101302
30101303
30101304
30101399
30101401
30101402
30101499
30101501
30101502
30101503
30101505
30101599
30101601
30101602
30101603
30101699
30101702
30101703
30101704
30101705
30101706
30101707
30101708
30101799
30101801
30101802
30101803
30101805
30101807
30101808
PROFILE
NUMBER
0122*
0122*
0000*
0000*
9004*
0003*
0000*
0000*
0000*
9004*
9004*
0000*
0000*
0000*
0000*
9004*
1094
0000*
1094*
0066
0066*
0066*
0066*
0066*
0000*
0000*
0000*
9004*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9004*
1091
0068
0068*
1056*
1056*
1056*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
E
D
E
E
E
C-ll
-------
TABLE C-l. (Continued)
Page No.
10/11/89
8
sec
30101809
30101810
30101811
30101812
30101813
30101814
30101815
30101816
30101817
30101818
30101819
30101820
30101821
30101822
30101827
30101832
30101837
30101838
30101839
30101840
30101842
30101847
30101849
30101852
30101860
30101861
30101863
30101864
30101865
30101866
30101870
30101871
30101872
30101880
30101881
30101882
30101883
30101884
30101885
30101890
30101891
30101892
PROFILE
NUMBER
1056*
1056*
1056*
1056*
1056*
1056*
0000*
0000*
1004
0000*
1004*
0000*
0000*
1009*
1009*
1004*
1005
1005*
1005*
1005*
1005*
1005*
1009
1040*
1056*
1056*
1056*
0000*
0000*
0000*
1005*
0000*
1005*
1005*
0000*
0000*
0000*
0000*
1005*
9005*
9005*
9005*
QUALITY
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-12
-------
TABLE C-l. (Continued)
Page No.
10/11/89
sec
30101893
30101894
30101899
30101901
30101902
30101904
30101905
30101906
30101907
30102001
30102002
30102003
30102004
30102005
30102099
30102101
30102102
30102103
30102104
30102105
30102106
30102107
30102108
30102110
30102111
30102112
30102113
30102120
30102199
30102201
30102301
30102304
30102306
30102308
30102310
30102312
30102314
30102316
30102318
30102319
30102320
30102321
PROFILE
NUMBER
9005*
9005*
9005*
1006
0000*
1006*
0000*
0000*
1006*
0072
9026*
9026*
9026*
9026*
9026*
0000*
0000*
0000*
0003*
1185*
0000*
0000*
0000*
0003*
0003*
0000*
0000*
0003*
9004*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
C
E
E
E
E
C
C
E
E
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-13
-------
TABLE C-l. (Continued)
Page No.
10/11/89
10
sec
30102322
30102399
30102401
30102402
30102405
30102410
30102414
30102415
30102416
30102421
30102422
30102423
30102424
30102425
30102426
30102427
30102499
30102501
30102505
30102599
30102601
30102602
30102608
30102609
30102610
30102611
30102612
30102613
30102614
30102615
30102616
30102617
30102625
30102630
30102699
30102701
30102704
30102705
30102706
30102707
30102708
30102709
PROFILE
NUMBER
0000*
0000*
1092
1005*
1040*
1009*
0068*
1091*
1061*
9006*
9006*
9006*
9006*
0000*
0000*
9006*
9006*
0000*
1045*
0000*
0274
0274*
0274*
0274*
0000*
0000*
0000*
0274*
0274*
0274*
0274*
0274*
0274*
0274*
0274*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
QUALITY
E
E
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
D
D
D
E
E
E
D
D
D
D
D
D
D
D
E
E
E
E
E
E
E
C-14
-------
TABLE C-l. (Continued)
Page No.
10/11/89
11
sec
30102710
30102711
30102712
30102713
30102714
30102717
30102718
30102720
30102721
30102722
30102723
30102724
30102725
30102727
30102728
30102729
30102730
30102801
30102803
30102804
30102805
30102806
30102807
30102820
30102821
30102822
30102823
30102824
30102825
30102903
30102904
30102905
30102906
30102907
30102908
30102920
30102921
30102922
30102923
30102924
30102925
30103001
PROFILE
NUMBER
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0003*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
C-15
-------
TABLE C-l. (Continued)
Page No.
10/11/89
12
sec
30103002
30103003
30103004
30103020
30103021
30103022
30103023
30103024
30103025
30103099
30103101
30103102
30103103
30103104
30103105
30103199
30103201
30103202
30103203
30103204
30103299
30103301
30103311
30103312
30103399
30103402
30103403
30103404
30103405
30103406
30103410
30103411
30103412
30103414
30103415
30103420
30103425
30103430
30103435
30103499
30103501
30103502
PROFILE
NUMBER
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
1024*
1024*
1023
1024
1025
1024*
9004*
9004*
9004*
9004*
9004*
0076*
0076
0076
0076*
1036*
1036*
1036*
1036*
1036*
1036*
0000*
0000*
1092*
1132*
1092*
1092*
1132*
1092*
1092*
0000*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
E
E
E
E
E
D
C
C
D
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
C-16
-------
TABLE C-l. (Continued)
Page No.
10/11/89
13
sec
30103503
30103506
30103507
30103510
30103515
30103520
30103550
30103551
30103552
30103553
30103554
30103599
30103801
30103901
30103902
30103903
30104001
30104002
30104003
30104004
30104005
30104006
30104007
30104008
30104009
30104010
30104011
30104012
30104013
30104101
30104102
30104103
30104104
30104199
30104201
30104202
30104203
30104204
30104301
30104501
30105001
30106001
PROFILE
NUMBER
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9004*
9004*
9004*
0000*
0000*
0000*
0000*
0000*
9004*
0000*
0000*
0000*
0000*
0000*
9004*
9004*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0202*
0000*
0000*
9021*
9004*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
C-17
-------
TABLE C-l. (Continued)
Page No.
10/11/89
14
sec
30106002
30106003
30106004
30106005
30106006
30106007
30106008
30106009
30106010
30106011
30106012
30106099
30107001
30107002
30109101
30109105
30109110
30109151
30109152
30109153
30109154
30109180
30109199
30110002
30110003
30110004
30110005
30110099
30111103
30111199
30111201
30111202
30111299
30112001
30112002
30112005
30112006
30112007
30112011
30112012
30112013
30112014
PROFILE
NUMBER
0000*
9004*
9004*
9004*
9004*
9004*
9004*
9004*
9004*
9004*
9004*
9004*
0000*
0000*
1028*
1027
1027*
1028*
1028*
1028
1029
1028*
0221*
1062
1062*
0000*
1062*
1062*
9011*
9011*
0000*
0000*
9004*
1030*
1030*
1030
1030*
1030*
1032*
1032*
1032*
1032*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
D
E
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
C-18
-------
TABLE C-l. (Continued)
Page No.
10/11/89
15
sec
30112017
30112021
30112031
30112032
30112033
30112034
30112037
30112099
30112199
30112401
30112402
30112403
30112404
30112405
30112406
30112407
30112480
30112501
30112502
30112504
30112505
30112506
30112509
30112510
30112511
30112512
30112514
30112515
30112520
30112521
30112522
30112524
30112525
30112526
30112527
30112528
30112529
30112530
30112531
30112532
30112533
30112534
PROFILE
NUMBER
1032*
1032*
1032*
1032*
1032
1032*
1032*
1033
1032*
1034*
1034*
1034*
0000*
0000*
1035
1035
1034*
1038
0078
1039
0000*
1037
1038*
1070*
1070*
1070*
1070*
0000*
0085*
0085*
0085*
0085*
0087*
0087*
0087*
0087*
0087*
0271*
0271*
0271*
0271*
0271*
QUALITY
E
E
E
E
E
E
E
D
E
E
D
E
E
E
E
E
E
D
C
C
E
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-19
-------
TABLE C-l. (Continued)
Page No.
10/11/89
16
sec
30112535
30112540
30112541
30112542
30112543
30112544
30112545
30112546
30112547
30112550
30112551
30112552
30112553
30112555
30112599
30112699
30112701
30112702
30112703
30112720
30112730
30112740
30112780
30113004
30113005
30113201
30113205
30113210
30113221
30113222
30113223
30113224
30113227
30113299
30113301
30113302
30113303
30113380
30113701
30113710
30113799
30114001
PROFILE
NUMBER
1072*
1091*
0000*
1091*
1091*
1091*
1091*
1091*
0000*
1091*
1091*
1091*
1091*
1091*
0078
9004*
1040
1041
0000*
1090
1093
0277*
1042
0003*
0003*
1070*
9004*
1032*
1043*
1043*
1043*
1043*
1043*
1044
1045*
1045*
1045
1045*
1046*
1047
9004
0000*
QUALITY
D
E
E
E
E
E
E
E
E
E
E
E
E
E
C
E
D
D
E
D
D
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
D
E
C
E
E
E
C-20
-------
TABLE C-l. (Continued)
Page No.
10/11/89
17
sec
30114002
30114003
30114004
30114005
30115201
30115301
30115310
30115311
30115312
30115320
30115321
30115322
30115380
30115601
30115602
30115603
30115604
30115605
30115606
30115607
30115680
30115701
30115702
30115704
30115780
30115801
30115802
30115803
30115821
30115822
30115880
30116701
30116702
30116703
30116704
30116780
30116799
30116901
30116902
30116903
30116904
30116905
PROFILE
NUMBER
0000*
0000*
1120
1120
0000*
1034*
1034*
1034*
1034*
1034*
1034*
1034*
1034*
1048*
1062*
1048*
1048*
1062*
1048
1048*
1048*
1049
0000*
0000*
1049*
1050*
1050*
1050*
1050*
1050
1050*
1052*
1051
1052
1053
1052*
1054
1062*
0000*
0000*
0000*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
D
D
E
C
D
D
D
E
E
E
E
E
E
E
E
E
D
C
C
E
D
E
E
E
E
E
E
C-21
-------
TABLE C-l. (Continued)
Page No.
10/11/89
IS
sec
30116906
30116980
30117401
30117402
30117410
30117411
30117421
30117480
30117601
30117610
30117611
30117612
30117613
30117614
30117615
30117616
30117617
30117618
30117630
30117631
30117632
30117633
30117634
30117680
30118101
30118102
30118103
30118104
30118105
30118106
30118107
30118108
30118109
30118110
30118180
30119001
30119002
30119003
30119004
30119010
30119011
30119012
PROFILE
NUMBER
0000*
1062*
1057*
1057*
1056
1057
1058
1057*
9004*
9004*
0000*
0000*
0000*
0000*
0000*
9004*
0000*
9004*
9004*
9004*
9004*
9004*
9004*
9004*
1176*
1176*
1176*
1176*
1176*
1077*
1176*
1176*
0000*
0000*
1176*
1059*
1059*
1059*
1059*
1059
1059*
1059
QUALITY
E
E
E
E
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
D
C-22
-------
TABLE C-l. (Continued)
Page No.
10/11/89
19
sec
30119013
30119014
30119080
30119501
30119502
30119503
30119504
30119505
30119506
30119580
30119701
30119705
30119706
30119707
30119708
30119709
30119710
30119741
30119742
30119743
30119744
30119745
30119749
30119799
30120201
30120202
30120203
30120204
30120205
30120206
30120210
30120211
30120280
30120501
30120502
30120503
30120504
30120505
30120506
30120507
30120508
30120509
PROFILE
NUMBER
1060
1060
1059*
1062*
1061
1062*
1061
1062
1062*
1062*
1064*
9004*
0000*
9004*
9004*
9004*
9004*
1064*
0000*
1064*
0000*
1064
1064*
9004*
1082*
1082*
1082*
1082*
1029*
1082*
1082*
1082*
1082*
1065*
1065
1065*
1065*
1065*
1065*
1065*
1065*
0000*
QUALITY
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
E
E
E
E
E
C
E
E
E
D
D
D
D
D
D
D
D
E
D
E
E
D
E
E
E
E
C-23
-------
TABLE C-l. (Continued)
Page No.
10/11/89
20
sec
30120520
30120521
30120522
30120523
30120524
30120525
30120526
30120527
30120528
30120529
30120530
30120531
30120532
30120540
30120541
30120542
30120543
30120544
30120545
30120546
30120547
30120548
30120549
30120550
30120551
30120552
30120553
30120554
30120555
30120580
30120601
30120602
30120603
30120680
30121001
30121002
30121003
30121004
30121005
30121006
30121007
30121008
PROFILE
NUMBER
1173*
1173*
1173*
0000*
1173*
1173*
1173*
1173*
1173*
1173*
1173*
1173*
1173*
1173*
1173*
1173*
0000*
1173*
1173*
0068*
1173*
1173*
1173*
1173*
1173*
1173*
1173*
1173*
1173*
1173*
1066
1067
1068
1066*
9004*
9004*
9004*
0000*
9004*
9004*
9004*
9004*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
E
E
D
D
E
E
E
E
E
E
E
E
E
E
C-24
-------
TABLE C-l. (Continued)
Page No.
10/11/89
21
sec
30121009
30121010
30121080
30121101
30121102
30121103
30121104
30121121
30121122
30121123
30121124
30121125
30121180
30125001
30125002
30125003
30125004
30125005
30125010
30125015
30125020
30125021
30125025
30125099
30125101
30125102
30125103
30125104
30125180
30125201
30125301
30125302
30125305
30125306
30125315
30125316
30125325
30125326
30125380
30125401
30125405
30125406
PROFILE
NUMBER
9004*
9004*
9004*
1062*
1062*
1062*
1062
1062*
1062*
1062
1062*
1062*
1062*
1070*
1070
1071
1070*
0226*
0226*
0000*
9007*
9007*
9007*
9007*
1078*
1078*
1078*
0000*
1078*
1136*
9004*
9004*
1070*
1070*
0226*
0226*
1027*
1027*
9004*
9004*
1109*
1009*
QUALITY
E
E
E
E
E
E
D
E
E
D
E
E
E
E
C
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
E
E
E
E
E
E
C-25
-------
TABLE C-l. (Continued)
Page No.
10/11/89
22
sec
30125407
30125408
30125409
30125410
30125411
30125412
30125413
30125415
30125416
30125417
30125418
30125420
30125499
30125801
30125802
30125803
30125805
30125806
30125807
30125810
30125815
30125816
30125817
30125880
30125899
30130101
30130102
30130103
30130104
30130105
30130106
30130107
30130108
30130110
30130135
30130180
30130201
30130202
30130203
30130280
30130301
30130302
PROFILE
NUMBER
1109*
1109*
1109*
1110*
0000*
1110*
1110*
1034*
1110*
0000*
1110*
1110*
9004*
1073*
1073*
1062*
0090*
0090*
0090*
1174*
0223*
0223*
0223*
0223*
0223*
1072
1073
1073*
1072*
1074
1075
1076
1077
0000*
1072*
1072*
1119*
1119*
1119*
1119*
9004*
9004*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
E
D
D
E
E
D
D
E
E
E
E
E
E
E
E
E
E
E
C-26
-------
TABLE C-l. (Continued)
Page No.
10/11/89
23
sec
30130303
30130304
30130305
30130380
30130401
30130402
30130403
30130404
30130405
30130480
30130501
30130502
30130503
30130504
30130505
30130580
30180001
30181001
30182001
30183001
30184001
30187001
30187002
30187003
30187004
30187005
30187006
30187007
30187008
30187009
30187010
30187097
30187098
30187501
30187502
30187597
30187598
30188501
30188502
30188503
30188504
30188505
PROFILE
NUMBER
9004*
9004*
9004*
9004*
9004*
9004*
9004*
9004*
9004*
9004*
1131*
1131*
1131*
1131*
1131*
1131*
9004*
9004*
9004*
9004*
9004*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-27
-------
TABLE C-l. (Continued)
Page No.
10/11/89
24
sec
30188599
30188801
30188802
30188803
30188804
30188805
30190001
30190002
30190003
30190004
30190011
30190012
30190013
30190014
30190099
30199998
30199999
30200101
30200102
30200103
30200104
30200199
30200201
30200202
30200203
30200299
30200301
30200401
30200402
30200403
30200404
30200410
30200501
30200502
30200503
30200504
30200505
30200506
30200507
30200508
30200509
30200510
PROFILE
NUMBER
0000*
9004*
9004*
9004*
9004*
9004*
0002*
0001*
0003*
0004*
0002*
0001*
0003*
0004*
0079
9004*
9004*
9008*
0000*
0000*
0000*
9008*
1032*
1032*
0000*
9008*
0000*
0000*
0000*
0000*
0000*
0000*
9008*
9008*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
QUALITY
E
E
E
E
E
E
C
C
C
D
C
C
C
D
D
E
E
E
E
E
. E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-28
-------
TABLE C-l. (Continued)
Page No.
10/11/89
25
sec
30200511
30200512
30200601
30200602
30200603
30200604
30200605
30200606
30200607
30200608
30200609
30200610
30200611
30200699
30200701
30200702
30200703
30200704
30200705
30200711
30200712
30200713
30200714
30200721
30200722
30200723
30200724
30200731
30200732
30200733
30200734
30200741
30200742
30200743
30200744
30200745
30200751
30200752
30200753
30200754
30200755
30200756
PROFILE
NUMBER
0000*
0000*
9008*
9008*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9008*
9008*
9008*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-29
-------
TABLE C-l. (Continued)
Page No.
10/11/89
26
sec
30200760
30200771
30200772
30200773
30200774
30200781
30200782
30200783
30200784
30200785
30200786
30200787
30200788
30200789
30200790
30200791
30200799
30200801
30200802
30200803
30200804
30200805
30200806
30200899
30200901
30200902
30200903
30200904
30200905
30200998
30200999
30201001
30201002
30201003
30201004
30201103
30201104
30201105
30201106
30201199
30201201
30201202
PROFILE
NUMBER
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9008*
9008*
0000*
0000*
0000*
0000*
0000*
9008*
0000*
1188*
0000*
0000*
0000*
1188*
1188*
0000*
1188
1188
1188
0000*
1188*
1188*
1188*
1188*
9008*
9008*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
E
D
D
E
C
C
C
E
D
D
D
D
E
E
C-30
-------
TABLE C-l. (Continued)
Page No.
10/11/89
27
sec
30201203
30201204
30201205
30201206
30201301
30201401
30201501
30201599
30201601
30201699
30201799
30201899
30201901
30201902
30201903
30201904
30201906
30201907
30201908
30201909
30201911
30201912
30201913
30201914
30201915
30201916
30201917
30201918
30201919
30201920
30201999
30202001
30202002
30202101
30202102
30202105
30202106
30202201
30202601
30202801
30203001
30203099
PROFILE
NUMBER
9008*
9008*
9008*
9008*
1084*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
0000*
0000*
0000*
0000*
9008*
0000*
9008*
9008*
9008*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-31
-------
TABLE C-l. (Continued)
Page No.
10/11/89
28
sec
30203103
30203104
30203105
30203106
30203107
30203108
30203109
30203110
30203111
30203201
30203202
30203299
30203399
30203601
30203801
30288801
30288802
30288803
30288804
30288805
30290001
30290002
30290003
30299998
30299999
30300001
30300002
30300101
30300102
30300103
30300104
30300105
30300106
30300107
30300108
30300109
30300110
30300111
30300199
30300201
30300302
30300303
PROFILE
NUMBER
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
9008*
0002*
0001*
0003*
9008*
9008*
0000*
0025*
1202*
1202
1202
0000*
1202*
0000*
1202*
0000*
0000*
0000*
0000*
0011*
0003*
0011
0011
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
C
E
E
E
E
E
D
D
E
E
E
E
E
E
E
E
E
C
C
C
C-32
-------
TABLE C-l. (Continued)
Page No.
10/11/89
29
sec
30300304
30300305
30300306
30300307
30300308
30300309
30300310
30300311
30300312
30300313
30300314
30300315
30300316
30300399
30300401
30300502
30300503
30300504
30300505
30300506
30300507
30300508
30300509
30300510
30300511
30300512
30300513
30300514
30300515
30300516
30300517
30300518
30300521
30300522
30300523
30300524
30300525
30300526
30300527
30300528
30300599
30300601
PROFILE
NUMBER
0011
0011
0011
0000*
0011*
0000*
0000*
0000*
0000*
0011*
0011*
0000*
0000*
0011*
0011*
0016*
0016*
0000*
0000*
0016*
0016*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9009*
0016*
QUALITY
C
C
C
E
E
E
E
E
E
D
D
E
E
E
D
D
D
E
E
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
C-33
-------
TABLE C-l. (Continued)
Page No.
10/11/89
30
sec
30300602
30300603
30300604
30300605
30300610
30300611
30300613
30300614
30300615
30300616
30300617
30300699
30300701
30300702
30300703
30300704
30300801
30300802
30300804
30300805
30300808
30300809
30300811
30300812
30300813
30300814
30300815
30300816
30300817
30300818
30300819
30300820
30300821
30300822
30300823
30300824
30300825
30300826
30300827
30300831
30300832
30300833
PROFILE
NUMBER
0016*
0016*
0016*
0016*
0000*
0016*
0000*
0000*
0016*
0016*
0016*
0016*
0016*
0016*
0016*
0016*
0012
0012
0000*
0000*
0000*
0000*
0013*
0000*
0013
0000*
0000*
0000*
0000*
0000*
0013*
0000*
0000*
0013*
0000*
0013*
9009*
0000*
0000*
0000*
0000*
0000*
QUALITY
D
D
D
D
E
D
E
E
D
D
D
D
D
D
D
D
E
E
E
E
E
E
D
E
C
E
E
E
E
E
D
E
E
D
E
D
E
E
E
E
E
E
C-34
-------
TABLE C-l. (Continued)
Page No.
10/11/89
31
sec
30300834
30300899
30300901
30300904
30300906
30300907
30300908
30300910
30300911
30300912
30300913
30300914
30300915
30300916
30300917
30300918
30300919
30300921
30300922
30300923
30300924
30300925
30300931
30300932
30300933
30300934
30300935
30300936
30300998
30300999
30301001
30301002
30301003
30301004
30301005
30301006
30301007
30301008
30301009
30301010
30301011
30301012
PROFILE
NUMBER
0000*
9009*
0014
0016*
0014*
0014*
0014*
0000*
0014*
0000*
0016
0016
1089*
0012*
0012*
0012*
0012*
1089*
0000*
1089*
0000*
1089*
1004*
0000*
1009*
0003*
1089*
1089*
9009*
9009*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
1089*
0000*
0000*
0000*
QUALITY
E
E
C
D
D
D
D
E
D
E
C
C
C
D
D
D
D
C
E
C
E
C
E
E
E
D
C
C
E
E
E
E
E
E
E
E
E
E
C
E
E
E
C-35
-------
TABLE C-l. (Continued)
Page No.
10/11/89
32
sec
30301013
30301014
30301015
30301016
30301017
30301018
30301019
30301020
30301021
30301022
30301023
30301024
30301025
30301026
30301099
30301101
30301102
30301199
30301201
30301202
30301299
30301301
30301401
30301402
30301403
30301499
30302301
30302302
30302303
30302304
30302305
30302306
30302307
30302308
30302309
30302310
30302311
30302312
30302313
30302314
30302315
30302316
PROFILE
NUMBER
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9009*
0000*
0000*
9009*
0000*
0025*
0025*
0000*
0000*
0025*
0025*
9009*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0003*
0001*
1085*
0000*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
D
E
E
C-36
-------
TABLE C-l. (Continued)
Page No.
10/11/89
33
sec
30302321
30302322
30302401
30302402
30302403
30302404
30302405
30302406
30302407
30302408
30302409
30302410
30302411
30303002
30303003
30303005
30303006
30303007
30303008
30303009
30303010
30303011
30303012
30303014
30303015
30303016
30303099
30388801
30388802
30388803
30388804
30388805
30390001
30390002
30390003
30390004
30390011
30390012
30390013
30390014
30390023
30390024
PROFILE
NUMBER
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0025*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9009*
9009*
9009*
9009*
9009*
9009*
0002*
0001*
0003*
0004*
0002*
0001*
0003*
0004*
0051*
0079*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
C
D
C
C
C
D
E
E
C-37
-------
TABLE C-l. (Continued)
Page No.
10/11/89
34
sec
30399999
30400101
30400102
30400103
30400104
30400105
30400106
30400107
30400108
30400109
30400110
30400111
30400112
30400113
30400114
30400120
30400150
30400199
30400204
30400207
30400208
30400209
30400210
30400211
30400212
30400214
30400215
30400217
30400219
30400220
30400221
30400223
30400224
30400230
30400231
30400232
30400233
30400234
30400235
30400236
30400237
30400238
PROFILE
NUMBER
9009*
1036*
1036*
1036*
0000*
0000*
0000*
0000*
0000*
1036*
9010*
9010*
9010*
9010*
1036
9010*
1036*
1036*
9010*
0025*
0011*
0003*
0012*
0012*
0012*
0014*
0014*
0014*
0014*
0014*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
D
D
E
D
D
D
D
D
D
E
E
E
E
E
E
E
E
E
E
E
E
C-38
-------
TABLE C-l. (Continued)
Page No.
10/11/89
35
sec
30400239
30400299
30400301
30400302
30400303
30400304
30400305
30400310
30400315
30400320
30400325
30400330
30400331
30400332
30400333
30400340
30400341
30400342
30400350
30400351
30400352
30400353
30400354
30400355
30400356
30400357
30400358
30400360
30400370
30400371
30400398
30400399
30400401
30400402
30400403
30400404
30400405
30400406
30400407
30400408
30400409
30400410
PROFILE
NUMBER
0000*
9010*
1089*
1089*
0000*
1089*
1089*
1089*
0000*
1089
1089*
1089*
1089*
1089*
1089*
0000*
0000*
0000*
0000*
1089*
0000*
1089*
1089*
1089*
0000*
0000*
0000*
0000*
1089*
1089*
9010*
9010*
0000*
0000*
0000*
0000*
0000*
1089*
1089*
0000*
0000*
0000*
QUALITY
E
E
C
C
E
C
C
C
E
B
C
C
C
C
C
E
E
E
E
C
E
C
C
C
E
E
E
E
C
C
E
E
E
E
E
E
E
D
D
E
E
E
C-39
-------
TABLE C-l. (Continued)
Page No.
10/11/89
36
sec
30400411
30400412
30400413
30400414
30400499
30400501
30400505
30400506
30400507
30400508
30400509
30400510
30400511
30400512
30400513
30400521
30400522
30400523
30400524
30400525
30400526
30400527
30400528
30400599
30400601
30400699
30400701
30400702
30400703
30400704
30400705
30400706
30400707
30400708
30400709
30400710
30400711
30400712
30400713
30400714
30400715
30400716
PROFILE
NUMBER
0000*
0000*
0000*
0000*
9010*
9010*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9010*
1089*
9010*
0014*
0014*
0014*
0014*
0000*
0000*
0014*
1089*
1089*
1089*
0000*
0000*
0000*
1089*
1089*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
D
D
D
D
E
E
D
C
C
C
E
E
E
C
C
E
C-40
-------
TABLE C-l. (Continued)
Page No.
10/11/89
37
sec
30400717
30400718
30400720
30400721
30400722
30400723
30400724
30400725
30400726
30400730
30400731
30400799
30400801
30400802
30400803
30400805
30400806
30400807
30400809
30400810
30400811
30400812
30400814
30400818
30400824
30400828
30400834
30400838
30400840
30400841
30400842
30400843
30400851
30400852
30400853
30400854
30400855
30400861
30400862
30400863
30400864
30400865
PROFILE
NUMBER
1089*
1089*
1089*
0000*
0000*
0000*
0000*
0000*
0000*
1089*
1089*
1089*
0000*
1036*
1036*
1036*
1036*
1036*
1036*
1036*
1036*
0000*
0000*
0000*
1036*
1036*
1036*
1036*
0000*
1036*
1036*
1036*
0000*
0000*
0000*
0000*
0000*
1036*
1036*
1036*
1036*
1036*
QUALITY
C
C
C
E
E
E
E
E
E
C
C
B
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-41
-------
TABLE C-l. (Continued)
Page No.
10/11/89
38
sec
30400866
30400867
30400868
30400869
30400870
30400871
30400872
30400873
30400874
30400875
30400876
30400877
30400899
30400901
30400999
30401001
30401002
30401004
30401005
30401006
30401007
30401008
30401010
30401011
30401099
30402001
30402002
30402003
30402004
30402099
30402201
30402210
30404001
30404901
30405001
30405099
30488801
30488802
30488803
30488804
30488805
30490001
PROFILE
NUMBER
0000*
1036*
1036*
1036*
1036*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9010*
1036*
1036*
0003*
0000*
0003*
0000*
0000*
0014*
0014*
0000*
0000*
9010*
9010*
0000*
0000*
9001*
9010*
0003*
1036*
1091*
0000*
9010*
9010*
9010*
9010*
9010*
9010*
9010*
0002*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
D
E
E
D
D
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
E
E
C
C-42
-------
TABLE C-l. (Continued)
Page No.
10/11/89
39
sec
30490002
30490003
30490004
30490011
30490012
30490013
30490014
30490023
30490024
30499999
30500101
30500102
30500103
30500104
30500105
30500110
30500111
30500112
30500113
30500198
30500199
30500201
30500202
30500203
30500204
30500205
30500206
30500207
30500208
30500299
30500301
30500302
30500303
30500304
30500307
30500308
30500309
30500311
30500312
30500313
30500314
30500315
PROFILE
NUMBER
0001*
0003*
0004*
0002*
0001*
0003*
0004*
0051*
0079*
9010*
1007*
1007*
1007*
0024
0024*
1007*
1007*
0023
1007*
9011*
1007*
0025
0026
1007
1007*
0000*
0025*
0025*
0025*
1007*
9001*
0000*
0000*
0003*
9001*
0000*
0000*
0003*
0001*
1185*
0003*
0001*
QUALITY
C
C
D
C
C
C
D
D
D
E
E
E
E
C
D
E
E
D
E
E
E
D
B
C
E
E
E
E
E
E
E
E
E
C
E
E
E
C
C
E
C
C
C-43
-------
TABLE C-l. (Continued)
Page No.
10/11/89
40
sec
30500316
30500398
30500399
30500401
30500402
30500403
30500404
30500405
30500406
30500499
30500501
30500502
30500503
30500504
30500505
30500598
30500599
30500606
30500607
30500608
30500609
30500610
30500611
30500612
30500613
30500614
30500615
30500616
30500617
30500618
30500619
30500699
30500706
30500707
30500708
30500709
30500710
30500711
30500712
30500714
30500715
30500716
PROFILE
NUMBER
1185*
9011*
9011*
0000*
0000*
0000*
0000*
0000*
0000*
9011*
9001*
0000*
0000*
9001*
9011*
9011*
9011*
9001*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9011*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-44
-------
TABLE C-l. (Continued)
Page No.
10/11/89
41
sec
30500717
30500718
30500719
30500799
30500801 .
30500802
30500803
30500899
30500901
30500902
30500903
30500904
30500905
30500906
30500907
30500908
30500909
30500910
30500999
30501001
30501002
30501003
30501004
30501005
30501006
30501007
30501008
30501009
30501010
30501011
30501012
30501013
30501014
30501015
30501016
30501017
30501021
30501022
30501023
30501024
30501030
30501031
PROFILE
NUMBER
0000*
0000*
0000*
9011*
9001*
0000*
0000*
9011*
0003*
0003*
0003*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9011*
9001*
9001*
9001*
9001*
9001*
9001*
9001*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
QUALITY
E
E
E
E
E
E
E
E
C
C
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-45
-------
TABLE C-l. (Continued)
Page No.
10/11/89
42
sec
30501032
30501033
30501034
30501035
30501036
30501037
30501038
30501039
30501040
30501041
30501042
30501043
30501044
30501045
30501046
30501047
30501048
30501049
30501050
30501090
30501099
30501101
30501106
30501107
30501108
30501109
30501110
30501111
30501112
30501113
30501114
30501115
30501120
30501199
30501201
30501202
30501203
30501204
30501205
30501206
30501207
30501208
PROFILE
NUMBER
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9011*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9011*
9011*
9011*
9011*
9011*
9011*
9011*
0000*
9011*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-46
-------
TABLE C-l. (Continued)
Page No.
10/11/89
43
sec
30501209
30501211
30501212
30501213
30501214
30501215
30501221
30501222
30501223
30501224
30501299
30501301
30501399
30501401
30501402
30501403
30501404
30501406
30501407
30501408
30501410
30501411
30501412
30501413
30501414
30501415
30501499
30501501
30501502
30501503
30501504
30501505
30501506
30501507
30501508
30501509
30501510
30501511
30501512
30501513
30501514
30501515
PROFILE
NUMBER
9011*
9011*
9011*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9011*
9011*
9011*
9011*
9011*
9011*
9011*
9011*
0000*
9011*
0000*
9011*
9011*
0000*
9001*
0000*
9011*
9001*
0000*
9001*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9001*
9001*
9001*
0000*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-47
-------
TABLE C-l. (Continued)
Page No.
10/11/89
44
sec
30501516
30501517
30501518
30501519
30501520
30501521
30501522
30501599
30501601
30501602
30501603
30501604
30501605
30501606
30501607
30501608
30501609
30501610
30501611
30501612
30501613
30501614
30501615
30501616
30501617
30501699
30501701
30501702
30501703
30501704
30501705
30501799
30501801
30501899
30501901
30501902
30501903
30501904
30501905
30501999
30502001
30502002
PROFILE
NUMBER
0000*
0000*
0000*
0000*
9001*
0000*
0000*
9011*
0000*
0000*
9001*
9001*
9001*
9001*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9001*
9011*
0000*
0000*
9001*
9001*
9001*
9001*
0000*
9001*
9001*
0000*
0000*
0000*
0000*
9011*
0000*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-48
-------
TABLE C-l. (Continued)
Page No.
10/11/89
45
sec
30502003
30502004
30502005
30502006
30502007
30502008
30502009
30502010
30502011
30502012
30502013
30502014
30502015
30502016
30502020
30502099
30502101
30502102
30502103
30502104
30502105
30502106
30502201
30502299
30502401
30502499
30502501
30502502
30502503
30502504
30502505
30502506
30502507
30502508
30502509
30502510
30502511
30502599
30502601
30502699
30503099
30503101
PROFILE
NUMBER
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9001*
0000*
0000*
0000*
0000*
0000*
9001*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9001*
0000*
0000*
0000*
0000*
0000*
9011*
9011*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-49
-------
TABLE C-l. (Continued)
Page No.
10/11/89
46
sec
30503102
30503103
30503104
30503105
30503106
30503107
30503108
30503109
30503110
30503111
30503199
30503201
30503202
30503203
30503204
30503205
30503206
30503299
30503301
30504001
30504002
30504003
30504010
30504020
30504021
30504022
30504023
30504024
30504025
30504030
30504031
30504032
30504033
30504034
30504036
30504099
30510001
30510002
30510003
30510004
30510005
30510006
PROFILE
NUMBER
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9011*
0000*
0000*
0000*
0000*
0000*
0000*
9011*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9011*
0000*
0000*
0000*
0000*
0000*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-50
-------
TABLE C-l. (Continued)
Page No.
10/11/89
47
sec
30510007
30510101
30510102
30510103
30510104
30510105
30510106
30510107
30510108
30510196
30510197
30510198
30510199
30510201
30510202
30510203
30510204
30510205
30510206
30510207
30510208
30510296
30510297
30510298
30510299
30510301
30510302
30510303
30510304
30510305
30510306
30510307
30510308
30510396
30510397
30510398
30510399
30510401
30510402
30510403
30510404
30510405
PROFILE
NUMBER
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9011*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9011*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9011*
0000*
0000*
0000*
0000*
0000*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-51
-------
TABLE C-l. (Continued)
Page No.
10/11/89
48
sec
30510406
30510407
30510408
30510496
30510497
30510498
30510499
30510501
30510502
30510503
30510504
30510505
30510506
30510507
30510508
30510596
30510597
30510598
30510599
30515001
30515002
30515003
30515004
30515005
30588801
30588802
30588803
30588804
30588805
30590001
30590002
30590003
30590011
30590012
30590013
30590023
30599999
30600101
30600102
30600103
30600104
30600105
PROFILE
NUMBER
0000*
0000*
0000*
0000*
0000*
0000*
9011*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9011*
0000*
0000*
0000*
0000*
0000*
9011*
9011*
9011*
9011*
9011*
0002*
0001*
0003*
0002*
0001*
0003*
0051*
9011*
0001*
0003*
0001*
0003*
0003*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
C
C
C
C
D
E
C
C
C
C
C
C-52
-------
TABLE C-l. (Continued)
Page No.
10/11/89
49
sec
30600106
30600107
30600108
30600199
30600201
30600202
30600301
30600401
30600402
30600503
30600504
30600505
30600506
30600602
30600603
30600701
30600702
30600801
30600802
30600803
30600804
30600805
30600806
30600807
30600811
30600812
30600813
30600814
30600815
30600816
30600817
30600818
30600819
30600820
30600821
30600822
30600901
30600902
30600903
30600904
30600999
30601001
PROFILE
NUMBER
0004*
0003*
0202*
9012*
0029
0000*
0029*
9012*
9012*
0031
0031
9012*
9012*
9012*
9012*
0035
0035
0316
0047
0321
0039
0321*
0321*
0321*
0047*
0047*
0047*
0047*
0047*
0047*
0321*
0321*
0039*
0039*
0031*
0047*
0002*
0001*
0051
0079*
0079*
9012*
QUALITY
D
C
E
E
C
E
D
E
E
C
C
E
E
E
E
C
C
C
C
C
D
D
D
D
E
E
E
E
E
E
E
E
E
E
E
E
D
D
D
D
D
E
C-53
-------
TABLE C-l. (Continued)
Page No.
10/11/89
50
sec
30601101
30601201
30601401
30601599
30609902
30609903
30609904
30609911
30609912
30609913
30609914
30610001
30688801
30688802
30688803
30688804
30688805
30699998
30699999
30700101
30700102
30700103
30700104
30700105
30700106
30700107
30700108
30700109
30700110
30700199
30700203
30700211
30700212
30700213
30700214
30700215
30700221
30700222
30700223
30700231
30700232
30700233
PROFILE
NUMBER
1007*
9012*
9012*
9012*
0001*
0003*
0004*
0002*
0001*
0003*
0004*
9012*
9012*
9012*
9012*
9012*
9012*
9012*
9012*
0000*
9001*
0000*
9001*
9001*
9001*
9001*
9001*
9001*
9001*
9001*
0000*
0000*
0000*
0000*
0000*
0000*
9001*
9001*
9001*
0000*
0000*
0000*
QUALITY
E
E
E
E
C
C
C
C
C
C
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-54
-------
TABLE C-l. (Continued)
Page No.
10/11/89
51
sec
30700234
30700299
30700301
30700302
30700303
30700304
30700401
30700402
30700499
30700501
30700597
30700598
30700599
30700701
30700702
30700703
30700704
30700705
30700706
30700707
30700708
30700709
30700711
30700712
30700713
30700714
30700715
30700798
30700799
30700801
30700802
30700803
30700804
30700805
30700806
30700807
30700808
30700896
30700897
30700898
30700899
30701199
PROFILE
NUMBER
0000*
9013*
0000*
0000*
9001*
0000*
9001*
9001*
9013*
0000*
9001*
9001*
9001*
1189*
0000*
0000*
1189*
1189*
1189*
1189*
0000*
1189*
1189
1189
1189
1189
1189
1189*
1189*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9013*
9013*
9013*
9013*
9013*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
D
D
D
D
E
D
C
C
C
C
C
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
C-55
-------
TABLE C-l. (Continued)
Page No.
10/11/89
52
sec
30701301
30701399
30702098
30702099
30703001
30703002
30703096
30703097
30703098
30703099
30788801
30788802
30788803
30788804
30788805
30788898
30790001
30790002
30790003
30790011
30790012
30790013
30790023
30799998
30799999
30800101
30800102
30800103
30800104
30800105
30800106
30800107
30800108
30800109
30800110
30800120
30800121
30800122
30800123
30800197
30800198
30800199
PROFILE
NUMBER
9013*
9013*
9013*
9013*
0000*
0000*
0000*
0000*
0000*
0000*
9013*
9013*
9013*
9013*
9013*
9013*
0002*
0001*
0003*
0002*
0001*
0003*
0051*
9013*
9013*
0273
0274*
0274*
0274*
0272*
0274*
0274*
0274*
0000*
0000*
0273
0272
0274*
0274*
0274*
0274*
0274*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
C
C
C
C
E
E
E
C
D
D
D
C
D
D
D
E
E
C
C
D
D
D
D
D
C-56
-------
TABLE C-l. (Continued)
Page No.
10/11/89
53
sec
30800501
30800699
30800701
30800702
30800703
30800704
30800705
30800720
30800721
30800722
30800723
30800724
30800799
30890001
30890002
30890003
30890011
30890012
30890013
30890023
30899999
30900198
30900199
30900201
30900202
30900203
30900204
30900205
30900206
30900207
30900208
30900298
30900299
30900301
30900302
30900303
30900304
30901001
30901097
30901098
30901099
30901101
PROFILE
NUMBER
0274*
1008
9021*
0000*
9021*
9021*
0000*
1005*
1005*
1005*
1005*
1005*
9014*
0002*
0001*
0003*
0002*
0001*
0003*
0051*
9014*
9003*
9003*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9003*
9003*
9003*
9003*
0000*
QUALITY
0
D
E
E
E
E
E
E
E
E
E
E
E
C
C
C
C
C
C
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-57
-------
TABLE C-l. (Continued)
Page No.
10/11/89
54
sec
30901102
30901103
30901104
30901199
30901501
30901601
30901604
30901605
30901606
30901607
30902099
30902501
30903004
30903005
30903006
30903099
30904001
30904010
30904020
30906001
30906099
30988801
30988802
30988803
30988804
30988805
30990001
30990002
30990003
30990011
30990012
30990013
30990023
30999997
30999998
30999999
31000101
31000101
31000101
31000101
31000101
31000102
PROFILE
NUMBER
0000*
0000*
9003*
9003*
0000*
0024*
0000*
1007*
1007*
1007*
9010*
9003*
9003*
9003*
9003*
9003*
9003*
0000*
9003*
9003*
9003*
9003*
9003*
9003*
9003*
9003*
0002*
0001*
0003*
0002*
0001*
0003*
0051*
9003*
9003*
9003*
1011
1205
1206
1207
1212
1011*
QUALITY
E
E
E
E
E
D
E
D
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
C
C
C
C
D
E
E
E
D
C
C
C
C
E
C-58
-------
TABLE C-l. (Continued)
Page No.
10/11/89
55
sec
31000103
31000104
31000105
31000199
31000201
31000202
31000203
31000204
31000205
31000206
31000207
31000299
31000401
31000402
31000403
31000404
31000405
31000411
31000412
31000413
31000414
31000415
31088801
31088802
31088803
31088804
31088805
31088904
31100199
31100299
31299999
31307001
31307002
31390001
31390002
31390003
31399999
31400901
31401001
31401002
31401101
31401102
PROFILE
NUMBER
1011*
1011*
1011*
1011*
0000*
1012*
1012
1012*
0051*
1012*
1012*
1012*
0002*
0001*
0001*
0003*
0004*
0002*
0001*
0001*
0003*
0004*
1010
9015*
9015*
9012*
9015*
9015*
9003*
9003*
9003*
0122*
0122*
0002*
0001*
0003*
9003*
0000*
0122*
0122*
0000*
0000*
QUALITY
E
E
E
E
E
E
D
E
E
E
E
E
C
C
C
C
D
C
C
C
C
D
D
E
E
E
E
E
E
E
E
E
E
C
C
C
E
E
E
E
E
E
C-59
-------
TABLE C-l. (Continued)
Page No.
10/11/89
56
sec
31499999
31501001
31501002
31501003
31502001
32099997
32099998
32099999
33000101
33000102
33000103
33000104
33000105
33000198
33000199
33000201
33000202
33000211
33000212
33000213
33000214
33000298
33000299
33000399
33000499
33000599
33088801
33088802
33088803
33088804
33088805
36000101
39000199
39000201
39000203
39000289
39000299
39000389
39000399
39000402
39000403
39000489
PROFILE
NUMBER
9003*
0000*
9026*
0000*
1031*
9016*
9016*
9016*
0000*
1096*
0000*
1096
0000*
1095
1095
9023*
9023*
9023*
9023*
9023*
9023*
9023*
9023*
9016*
9016*
9016*
9016*
9016*
9016*
9016*
9016*
0000*
0000*
0000*
0000*
1178*
0000*
1178*
0000*
0000*
0000*
0001*
QUALITY
E
E
E
E
E
E
E
E
E
D
E
B
E
B
B
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C-60
-------
TABLE C-l. (Continued)
Page No.
10/11/89
57
sec
39000499
39000501
39000502
39000503
39000589
39000598
39000599
39000602
39000603
39000605
39000689
39000699
39000701
39000702
39000788
39000789
39000797
39000798
39000799
39000801
39000889
39000899
39000989
39000999
39001089
39001099
39001299
39001389
39001399
39990001
39990002
39990003
39990004
39990011
39990012
39990013
39990014
39990022
39990023
39990024
39999993
39999994
PROFILE
NUMBER
0000*
0002*
0000*
0000*
0003*
0000*
0000*
0000*
0000*
0003*
0003*
0000*
0217
0000*
0004*
0005*
0000*
0000*
0000*
0005*
0005*
0000*
1084*
0000*
0003*
0000*
0000*
0122*
0000*
0002
0001
0003
0004*
0002
0001
0003
0004*
0079*
0051*
0079*
9003*
9003*
QUALITY
E
C
E
E
C
E
E
E
E
C
C
E
B
E
C
C
E
E
E
C
C
E
E
E
C
E
E
E
E
B
B
B
D
B
B
B
D
E
E
E
E
E
C-61
-------
TABLE C-l. (Continued)
Page No.
10/11/89
58
sec
39999995
39999996
39999998
39999999
40100101
40100102
40100103
40100104
40100105
40100106
40100198
40100199
40100201
40100202
40100203
40100204
40100205
40100206
40100207
40100208
40100215
40100216
40100217
40100221
40100222
40100223
40100224
40100225
40100235
40100236
40100251
40100252
40100253
40100254
40100255
40100256
40100257
40100258
40100259
40100295
40100296
40100297
PROFILE
NUMBER
9003*
9003*
9003*
9003*
0085
1193
0085
1193*
0277
0277
1196
1196*
1192
0087
0085*
0275
0271*
0090
0277
1021
1195
1195
1195
1192
0087*
0085*
0275
0271*
1195
1195
1192
0087*
0085*
0275
0271
0090
0277
0088
0089
1195
1195
1195
QUALITY
E
E
E
E
E
B
E
C
E
E
B
B
B
E
E
E
E
E
E
E
B
B
B
B
E
E
E
E
B
B
B
E
E
E
E
E
E
E
E
B
B
B
C-62
-------
TABLE C-l. (Continued)
Page No.
10/11/89
59
sec
40100298
40100299
40100301
40100302
40100303
40100304
40100305
40100306
40100335
40100336
40100398
40100399
40100401
40100499
40188801
40188802
40188803
40188804
40188805
40188898
40200101
40200110
40200201
40200210
40200301
40200310
40200401
40200410
40200501
40200510
40200601
40200610
40200701
40200706
40200707
40200710
40200801
40200802
40200803
40200810
40200898
40200899
PROFILE
NUMBER
1195
1195
1149
0275
1192
0085*
0087*
0271*
1195
1195
1195
1195
0085*
9017*
9017*
9017*
9017*
9017*
9017*
9017*
1003
1003
1013
1013
0127
0127
1017
1017
1018
1018
1019
1019
1088
1020
0000*
1088
1003*
1003*
1003*
1003*
1003*
1003*
QUALITY
B
B
E
E
B
E
E
E
B
B
B
B
E
E
E
E
E
E
E
E
B
B
B
B
D
D
B
B
B
B
B
B
C
B
E
C
C
C
C
C
B
C
C-63
-------
TABLE C-l. (Continued)
Page No. 60
10/11/89
sec
40200901
40200902
40200903
40200904
40200905
40200906
40200907
40200908
40200909
40200910
40200911
40200912
40200913
40200914
40200915
40200916
40200917
40200918
40200919
40200920
40200921
40200922
40200923
40200924
40200925
40200926
40200927
40200928
40200998
40201001
40201002
40201003
40201004
40201101
40201103
40201104
40201105
40201111
40201112
40201113
40201114
40201115
PROFILE
NUMBER
1016
0219
0288
0289
1118
0290
0222
0292
0220
0226
1015*
0227
0228
1014*
0229
1150
0291
0221
1022*
0225
0282
0090*
0225*
0223
1062*
9023*
1026
1031
9021*
0003*
0002*
0001*
0000*
1003*
1003*
0000*
1003*
1003*
1003*
1003*
1003*
1003*
QUALITY
B
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
E
E
E
E
E
C
E
E
E
E
D
D
D
E
D
D
E
D
D
D
D
D
D
C-64
-------
TABLE C-l. (Continued)
Page No.
10/11/89
61
sec
40201116
40201199
40201201
40201210
40201301
40201303
40201304
40201305
40201399
40201401
40201402
40201403
40201404
40201405
40201406
40201431
40201432
40201433
40201434
40201435
40201436
40201437
40201438
40201499
40201501
40201502
40201503
40201504
40201505
40201531
40201599
40201601
40201602
40201603
40201604
40201605
40201606
40201619
40201620
40201621
40201622
40201623
PROFILE
NUMBER
1003*
1003*
1003*
1003*
1003*
1003*
0000*
1003*
1003*
1003*
0000*
1003*
0000*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
0000*
1003*
0000*
1003*
1003*
1003*
1194*
0000*
1194*
0000*
1194*
1194*
1194*
1003*
1194*
1194*
1194*
QUALITY
D
D
0
D
D
D
E
D
D
D
E
D
E
D
D
0
D
D
D
D
D
D
D
D
D
E
D
E
D
D
D
C
E
C
E
C
C
C
B
C
D
C
C-65
-------
TABLE C-l. (Continued)
Page No.
10/11/89
62
sec
40201624
40201625
40201626
40201627
40201628
40201629
40201630
40201631
40201632
40201699
40201702
40201703
40201704
40201705
40201721
40201722
40201723
40201724
40201725
40201726
40201727
40201728
40201731
40201732
40201733
40201734
40201735
40201736
40201799
40201801
40201803
40201804
40201805
40201806
40201899
40201901
40201903
40201904
40201999
40202001
40202002
40202003
PROFILE
NUMBER
1194*
1194*
1194*
1194*
1194*
1194*
1194*
1194*
1194*
1194*
0000*
1003*
0000*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
0000*
1003*
1003*
1003*
1003*
1003*
0000*
1003*
1003*
0000*
1003*
QUALITY
D
C
C
C
D
C
D
C
D
D
E
D
E
D
D
D
D
D
D
D
D
D
D
D
D
D
D
. D
D
D
D
E
D
D
D
D
D
E
D
D
E
D
C-66
-------
TABLE C-l. (Continued)
Page No.
10/11/89
63
sec
40202004
40202005
40202031
40202032
40202033
40202034
40202099
40202101
40202103
40202104
40202105
40202106
40202107
40202108
40202109
40202131
40202132
40202133
40202199
40202201
40202202
40202203
40202204
40202205
40202299
40202301
40202302
40202303
40202304
40202305
40202306
40202399
40202401
40202402
40202403
40202404
40202405
40202406
40202499
40202501
40202502
40202503
PROFILE
NUMBER
0000*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
0000*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
0000*
1003*
0000*
1003*
1003*
1003*
0000*
1003*
0000*
1003*
1003*
1003*
1003*
0000*
1003*
0000*
1003*
1003*
1003*
1003*
0000*
1003*
QUALITY
E
D
D
D
D
D
D
D
D
E
D
D
D
D
D
D
D
D
D
D
E
D
E
D
D
D
E
D
E
D
D
D
D
E
D
E
D
D
D
D
E
D
C-67
-------
TABLE C-l. (Continued)
Page No.
10/11/89
64
sec
40202504
40202505
40202531
40202532
40202533
40202534
40202535
40202536
40202537
40202599
40202601
40202602
40202603
40202604
40202605
40202606
40202607
40202699
40288801
40288802
40288803
40288804
40288805
40290023
40299995
40299996
40299997
40299998
40299999
40300101
40300102
40300103
40300104
40300105
40300106
40300107
40300108
40300109
40300110
40300111
40300112
40300113
PROFILE
NUMBER
0000*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
0000*
1003*
0000*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
0051*
1187
1187
1187
1187
9021*
1014*
0297*
1015*
0297*
0100*
0100*
0297*
1062*
0299*
1200*
0301*
0230*
1197
QUALITY
E
D
D
0
D
0
D
Q
D
D
D
E
D
E
D
D
D
D
D
D
D
D
D
D
D
D
D
D
E
D
E
D
E
D
D
E
E
E
E
E
E
E
C-68
-------
TABLE C-l. (Continued)
Page No.
10/11/89
65
sec
40300114
40300115
40300116
40300150
40300151
40300152
40300153
40300154
40300155
40300156
40300157
40300158
40300159
40300160
40300161
40300198
40300199
40300201
40300202
40300203
40300204
40300205
40300207
40300208
40300209
40300210
40300211
40300212
40300213
40300214
40300215
40300216
40300299
40300302
40301001
40301002
40301003
40301004
40301005
40301006
40301007
40301008
PROFILE
NUMBER
1199
1198
0090*
0100*
0297*
0100*
1062*
0299*
1200*
0301*
0230*
1197*
1199*
1198*
0090*
9024*
9024*
1014*
1014*
0297*
0297*
0100*
0100*
1062*
0299*
1200
0301*
0230*
1197*
1199*
1198*
0090*
9024*
1014*
1015
1014*
1014
1015
1014*
1014
1015
1014*
QUALITY
E
E
E
D
E
D
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
D
D
E
E
E
E
E
E
E
E
E
E
D
B
D
B
B
D
B
B
D
C-69
-------
TABLE C-l. (Continued)
Page No.
10/11/89
66
sec
40301009
40301010
40301011
40301012
40301013
40301014
40301015
40301016
40301017
40301018
40301019
40301020
40301021
40301097
40301098
40301099
40301101
40301102
40301103
40301104
40301105
40301106
40301107
40301108
40301109
40301110
40301111
40301112
40301113
40301114
40301115
40301116
40301117
40301118
40301119
40301120
40301130
40301131
40301132
40301133
40301134
40301135
PROFILE
NUMBER
1014
0296
0296
0296
0100
0100*
0100*
0100*
0100*
0100*
0297*
0297*
0297*
9024*
9024*
9024*
1015
1014*
1014
1015
1014*
1014*
1014*
1014*
0296
0296*
0100*
0100*
0100*
0100*
0297*
0297*
0296*
0100*
0100*
0297*
9024*
1014*
0296*
0100*
0100*
0297*
QUALITY
B
C
C
C
C
D
D
D
D
D
E
E
E
E
E
E
B
D
B
C
D
C
D
D
C
D
D
D
D
D
E
E
D
D
D
E
E
C
D
D
D
E
C-70
-------
TABLE C-l. (Continued)
Page No.
10/11/89
67
sec
40301140
40301141
40301142
40301143
40301144
40301145
40301150
40301151
40301152
40301153
40301154
40301155
40301197
40301198
40301199
40301201
40301202
40301203
40301204
40301205
40301206
40301207
40301299
40388801
40388802
40388803
40388804
40388805
40399999
40400101
40400102
40400103
40400104
40400105
40400106
40400107
40400108
40400109
40400110
40400111
40400112
40400113
PROFILE
NUMBER
9024*
1014*
0296*
0100*
0100*
0297*
9024*
1014*
0296*
0100*
0100*
0297*
9024*
9024*
9024*
1015
1014*
1014
0100*
0100*
0297*
1062*
9024*
9024*
9024*
9024*
9024*
9024*
9024*
1015
1014*
1014
1015
1014*
1014
1015
1014*
1014
1015
1014*
1014
1015
QUALITY
E
C
D
D
D
E
E
C
D
D
D
E
E
E
E
B
D
B
D
D
E
D
E
E
E
E
E
E
E
B
D
B
B
D
B
B
D
B
B
D
B
B
C-71
-------
TABLE C-l. (Continued)
Page No.
10/11/89
68
sec
40400114
40400115
40400116
40400117
40400118
40400119
40400120
40400151
40400152
40400153
40400154
40400199
40400201
40400202
40400203
40400204
40400205
40400206
40400207
40400208
40400209
40400210
40400211
40400212
40400213
40400250
40400251
40400254
40400301
40400302
40400302
40400302
40400303
40400303
40400303
40400304
40400304
40400304
40400305
40400305
40400305
40400305
PROFILE
NUMBER
1014*
1014
1014*
1014*
1015
1014*
1014
9025*
9025*
9025*
9025*
1015*
1015
1014*
1014
1015
1014*
1014
1015
1014*
1014
1014*
1015
1014*
1014
9025*
9025*
9025*
0297
0297
1208
1209
0297*
1210
1211
0297*
1210
1211
0297*
1209
1210
1211
QUALITY
D
B
D
D
B
D
B
E
E
E
E
C
B
C
B
B
C
B
B
C
B
C
B
C
B
E
E
E
C
C
C
C
D
C
C
D
C
C
D
C
C
C
C-72
-------
TABLE C-l. (Continued)
Page No.
10/11/89
69
sec
40400401
40400402
40400403
40400404
40400405
40400406
40400407
40400408
40400409
40400410
40400411
40400412
40400413
40400414
40400497
40400498
40500101
40500199
40500201
40500202
40500203
40500211
40500212
40500301
40500302
40500303
40500304
40500305
40500306
40500307
40500311
40500312
40500401
40500411
40500412
40500413
40500501
40500502
40500503
40500506
40500507
40500510
PROFILE
NUMBER
0000*
1015
0000*
1014*
0000*
1014
0000*
0297*
0000*
0100*
0000*
0100*
0000*
0297*
9025*
9025*
0333*
0333*
0166
1014*
0225*
0166
0166*
1086
1118
0290*
0226*
0227*
0304*
0282*
1086
1086
0332
0332
0332*
0227*
0182
0292*
0220*
0221*
1022
0090*
QUALITY
E
B
E
C
E
B
E
D
E
D
E
D
E
E
E
E
D
D
D
E
E
D
E
C
E
E
E
E
E
E
C
C
D
D
E
E
C
E
E
E
E
E
C-73
-------
TABLE C-l. (Continued)
Page No.
10/11/89
70
sec
40500511
40500512
40500513
40500598
40500599
40500601
40500701
40588801
40588802
40588803
40588804
40588805
40600101
40600126
40600130
40600131
40600132
40600133
40600134
40600135
40600136
40600137
40600138
40600139
40600140
40600141
40600142
40600143
40600144
40600145
40600146
40600147
40600148
40600149
40600160
40600161
40600162
40600163
40600197
40600198
40600199
40600231
PROFILE
NUMBER
0182
0182
0183
9026*
9026*
9026
9026
1191
1191*
1191*
1191*
1191*
1190*
1190*
0297*
1190*
0297*
0100*
0100*
0297*
1190*
0297*
0100*
0100*
0297*
1190*
0297*
0100*
1190*
0297*
0100*
1190*
0297*
0100*
0100*
0297*
1190*
1190*
1190*
1190*
1190*
1190*
QUALITY
C
C
D
E
E
E
E
B
B
B
B
B
C
C
E
B
D
D
D
E
B
D
D
D
D
B
D
D
B
D
D
B
D
D
D
E
B
B
D
D
D
B
C-74
-------
TABLE C-l. (Continued)
Page No.
10/11/89
71
sec
40600232
40600233
40600234
40600235
40600236
40600237
40600238
40600239
40600240
40600241
40600242
40600243
40600244
40600245
40600246
40600248
40600249
40600250
40600251
40600253
40600254
40600255
40600256
40600257
40600259
40600298
40600299
40600301
40600302
40600305
40600306
40600307
40600399
40600401
40600402
40600403
40600499
40602234
40688801
40688802
40688803
40688804
PROFILE
NUMBER
1190*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
0297*
0100*
1014*
0100*
0297*
0100*
1014*
0297*
0305
0305*
0100*
1014*
0297*
9027*
1190*
1190*
1190*
1190*
1190*
1190*
1014*
1190*
1100
1100*
1100
1190*
1100*
9027*
9027*
9027*
9027*
QUALITY
B
B
C
B
B
B
B
B
B
B
B
D
D
E
E
D
D
E
E
C
D
D
E
E
E
D
D
B
B
B
B
C
C
C
C
C
C
C
E
E
E
E
C-75
-------
TABLE C-l. (Continued)
Page No.
10/11/89
72
sec
40688805
40700401
40700402
40700497
40700498
40700801
40700802
40700803
40700804
40700805
40700806
40700807
40700808
40700809
40700810
40700811
40700812
40700813
40700814
40700815
40700816
40700817
40700818
40700897
40700898
40701601
40701602
40701603
40701604
40701605
40701606
40701609
40701610
40701611
40701612
40701613
40701614
40701697
40701698
40702001
40702002
40702003
PROFILE
NUMBER
9027*
1106
1106
1106*
1106*
0289*
0289*
1027*
1027*
1175
1175
1124
1124
0226*
0226*
1147
1147
0227*
0227*
0291*
0291*
0304
0304
9029*
9029*
1163
1163
1164
1164
0301
0301
1166
1166
0282*
0282*
0282*
0282*
9030*
9030*
1130
1130
1144
QUALITY
E
E
E
E
E
E
E
C
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-76
-------
TABLE C-l. (Continued)
Page No.
10/11/89
73
sec
40702004
40702097
40702098
40703201
40703202
40703203
40703204
40703205
40703206
40703297
40703298
40703601
40703602
40703603
40703604
40703605
40703606
40703607
40703608
40703609
40703610
40703611
40703612
40703613
40703614
40703615
40703616
40703617
40703618
40703619
40703620
40703621
40703622
40703623
40703624
40703697
40703698
40704001
40704002
40704003
40704004
40704005
PROFILE
NUMBER
1144
9031*
9031*
1111
1111
1132
1132
1139
1139
9032*
9032*
1062*
1062*
1122
1122
1123
1123
1128
1128
1135
1135
1154
1154
1005*
1005*
0090*
0090*
1159
1159
1165
1165
1174
1174
0223*
0223*
9033*
9033*
1105
1105
1108
1108
1110
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-77
-------
TABLE C-l. (Continued)
Page No.
10/11/89
74
sec
40704006
40704007
40704008
40704009
40704010
40704097
40704098
40704401
40704402
40704403
40704404
40704405
40704406
40704407
40704408
40704409
40704410
40704411
40704412
40704413
40704414
40704415
40704416
40704417
40704418
40704419
40704420
40704421
40704422
40704423
40704424
40704497
40704498
40704801
40704802
40704897
40704898
40705201
40705202
40705203
40705204
40705205
PROFILE
NUMBER
0000*
1141
1141
1172
1172
9034*
9034*
0288*
0288*
1114
1114
0220*
0220*
1134
1134
1146
1146
0228*
0228*
1150
1150
1151
1151
1081*
1081*
1053*
1053*
1069
1069
1087
1087
9035*
9035*
1158
1158
1158*
1158*
1115
1115
1116
1116
1118
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E '
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-78
-------
TABLE C-l. (Continued)
Page No.
10/11/89
75
sec
40705206
40705207
40705208
40705209
40705210
40705211
40705212
40705213
40705214
40705215
40705216
40705217
40705218
40705297
40705298
40705601
40705602
40705603
40705604
40705605
40705606
40705607
40705608
40705609
40705610
40705697
40705698
40706001
40706002
40706003
40706004
40706005
40706006
40706007
40706008
40706009
40706010
40706011
40706012
40706013
40706014
40706015
PROFILE
NUMBER
1118
0290*
0290*
1127
1127
1152
1152
1153
1153
0000*
0000*
0000*
0000*
9036*
9036*
0000*
0000*
1078*
1078*
1129
1129
0000*
0000*
1083*
0000*
9037*
9037*
1112
1112
0000*
0000*
1119
1119
1074*
1074*
1079*
1079*
1076*
1076*
1131
1131
1138
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
E
E
E
E
C
E
E
E
E
E
E
E
E
E
C
C
C
C
C
C
E
E
E
C-79
-------
TABLE C-l. (Continued)
Page No.
10/11/89
76
sec
40706016
40706017
40706018
40706019
40706020
40706021
40706022
40706023
40706024
40706097
40706098
40706401
40706402
40706403
40706404
40706497
40706498
40706801
40706802
40706813
40706814
40706897
40706898
40707601
40707602
40707697
40707698
40708001
40708002
40708097
40708098
40708401
40708402
40708403
40708404
40708497
40708498
40717205
40717206
40717207
40717208
40717209
PROFILE
NUMBER
1138
0078*
0078*
0000*
0000*
0085*
0085*
0271*
0271*
9038*
9038*
0000*
0000*
1176
1176
9039*
9039*
1125
1125
1055
1055
9040*
9040*
1109
1109
1109*
1109*
1160
1160
1160*
1160*
0000*
0000*
1082*
1082*
9028*
9028*
1162
1162
1140
1140
1145
QUALITY
E
B
B
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
E
E
E
E
E
E
E
C-80
-------
TABLE C-l. (Continued)
Page No.
10/11/89
77
sec
40717210
40717211
40717212
40717297
40717298
40717601
40717602
40717603
40717604
40717697
40717698
40718097
40720801
40720802
40720803
40720804
40720897
40720898
40722001
40722002
40722003
40722004
40722005
40722006
40722007
40722008
40722009
40722010
40722097
40722098
40722801
40722802
40722803
40722804
40722805
40722806
40722897
40722898
40723201
40723202
40723297
40723298
PROFILE
NUMBER
1145
1171
1171
9041*
9041*
0299
0299
0230
0230
9042*
9042*
9046*
1136
1136
1173
1173
9043*
9043*
1119
1119
1121
1121
0078*
0078*
0000*
0000*
0087*
0087*
9044*
9044*
0219*
0219*
0221*
0221*
1022*
1022*
9028*
9028*
1137
1137
1137*
1137*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
B
B
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-81
-------
TABLE C-l. (Continued)
Page No.
10/11/89
78
sec
40781201
40781202
40781601
40781602
40781603
40781604
40781605
40781699
40782001
40782002
40782003
40782004
40782005
40782006
40782007
40782008
40782009
40782010
40782011
40782099
40782401
40782499
40783201
40783202
40783203
40783299
40784801
40784899
40786001
40786002
40786003
40786004
40786099
40786401
40786499
40787201
40787299
40799997
40799998
40899995
40899997
40899999
PROFILE
NUMBER
1104
1107
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
1148
1155
1103
1168
1126
9046*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
0000*
9028*
9028*
9028*
9028*
9028*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C-82
-------
TABLE C-U, (Continued)
Page No.
10/11/89
79
sec
49000101
49000102
49000103
49000104
49000105
49000199
49000201
49000202
49000203
49000204
49000205
49000206
49000299
49000301
49000302
49000303
49000304
49000399
49000401
49000402
49000403
49000404
49000405
49000499
49090011
49090012
49090013
49090023
49099998
49099999
50100101
50100102
50100201
50100202
50100505
50100506
50100507
50100508
50100510
50100511
50100512
50100601
PROFILE
NUMBER
1193*
0221*
1022*
1142
0271*
9047*
9047*
9047*
9047*
9047*
9047*
9047*
9047*
1078
1074
1079
1080
9047*
0219*
0085*
1081
1082
1083
9047*
0002*
0001*
0003*
0051*
9047*
9047*
0122
0122
0121*
0121
0122*
0122*
0122*
0121*
0121*
0122*
0122*
9022*
QUALITY
C
E
E
E
E
E
E
E
E
E
E
E
E
D
D
D
D
E
E
E
D
D
D
E
C
C
C
E
E
E
D
D
E
C
D
D
E
E
E
E
E
E
C-83
-------
TABLE C-l. (Continued)
Page No.
10/11/89
80
sec
50100602
50100603
50100604
50100701
50100702
50100703
50100704
50190005
50190006
50190010
50200101
50200102
50200103
50200104
50200105
50200201
50200202
50200301
50200302
50200505
50200506
50200601
50200602
50200901
50290005
50290006
50290010
50300101
50300102
50300103
50300104
50300105
50300106
50300107
50300108
50300109
50300201
50300202
50300203
50300204
50300501
50300506
PROFILE
NUMBER
9022*
9022*
0121*
9022*
9022*
9022*
0000*
0000*
0000*
0000*
0122*
0122*
0000*
0122*
0121*
0121*
0122*
0122*
0122*
0122*
0122*
0079*
0202
0000*
0000*
0000*
0000*
0122*
0122*
0000*
0122*
0121*
0000*
0122*
9022*
0122*
0121*
0122*
9022*
9022*
9022*
0122*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
C
E
E
E
E
E
E
E
E
D
E
E
E
E
D
E
E
E
E
E
C-84
-------
TABLE C-l. (Continued)
Page No. 81
10/11/89
PROFILE
SCC NUMBER QUALITY
50300601 0079* D
50300602 9022* E
50300603 9022* E
50300701 9022* E
50300801 9022* E
50300810 9022* E
50300820 9022* E
50300901 0000* E
50390005 0000* E
50390006 0000* E
50390010 0000* E
C-85
-------
TABLE C-2. AREA SOURCE PROFILE ASSIGNMENTS
Page No.
10/11/89
82
AREA SOURCE CODE PROFILE NUMBER DATA QUALITY
001
002
003
004
005
006
007
008
009
010
Oil
012
013
014
015
016
017
018
019
020
021
022
023
024
025
026
027
028
029
030
031
032
033
034
035
036
037
038
039
040
041
042
043
1185*
1185*
0002*
0001*
0195*
1084*
1178*
1178*
0002*
0001*
0003*
1084*
1185*
1185*
0005*
0002*
0001*
0003*
1084*
0004*
0122*
0122*
0122*
0121*
0121*
0121*
1101*
1101*
1101*
1101*
1101*
1101*
1101*
1101*
1186*
1186*
1186*
1186*
1186*
1201*
1201*
1201*
1201*
E
E
C
C
C
D
E
E
C
C
C
D
E
D
C
C
C
C
D
D
E
E
D
D
C
D
B
B
B
B
C
C
C
C
C
C
C
C
C
D
D
D
D
C-86
-------
TABLE C-2. (Continued).
Page No.
10/11/89
83
AREA SOURCE CODE PROFILE NUMBER DATA QUALITY
044
045
046
047
048
049
050
051
052
054
055
056
057
058
059
060
061
062
063
064
071
072
073
074
075
076
077
078
079
080
081
082
083
084
085
086
087
088
089
090
091
092
093
1201*
1201*
1097*
1099*
1098*
1178*
1201*
0001*
1186*
1190*
0000*
1099*
0000*
0000*
0000*
0307*
0307*
0307*
0001*
0307*
0203*
0203*
0203*
0203*
0203*
0203*
0203*
1195*
1196*
1191*
9014*
1016*
1194*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
9003*
D
D
B
C
B
E
D
C
D
B
E
D
E
E
E
C
C
D
D
C
C
C
C
C
C
D
C
B
B
B
E
B
B
D
D
D
D
D
D
D
D
D
E
C-87
-------
TABLE C-2. (Continued).
Page No. 84
10/11/89
AREA SOURCE CODE PROFILE NUMBER DATA QUALITY
094 9028* E
095 0197* D
096 1178* E
097 0001* B
098 0003* B
099 0000* E
100 9022* E
101 9004* E
102 9025* E
103 9012* E
104 9003* E
105 9004* E
106 9006* E
107 9015* E
108 1007 E
109 9022* E
110 1101* D
111 1201 C
112 0000* E
113 0000* E
114 0000* E
115 0000* E
C-88
-------
TABLE C-3. AREA SOURCE CODE DESCRIPTIONS
Area
Source Code
Category Description
001
002
003
004
005
006
007
008
009
010
Oil
012
013
014
015
016
017
018
019
020
021
022
023
024
025
026
027
028
029
Residential Fuel - Anthracite Coal
Residential Fuel - Bituminous Coal
Residential Fuel - Distillate Oil
Residential Fuel - Residual Oil
Residential Fuel - Natural Gas
Residential Fuel - Wood
Commercial/Institutional Fuel - Anthracite Coal
Commercial/Institutional Fuel - Bituminous Coal
Commercial/Institutional Fuel - Distillate Oil
Commercial/Institutional Fuel - Residual Oil
Commercial/Institutional Fuel - Natural Gas
Commercial/Institutional Fuel - Wood
Industrial Fuel - Anthracite Coal
Industrial Fuel - Bituminous Coal
Industrial Fuel - Coke
Industrial Fuel - Distillate Oil
Residual Oil
Natural Gas
Wood
Process Gas
On-Site Incineration - Residential
On-Site Incineration - Industrial
On-Site Incineration - Commercial/Institutional
Open Burning - Residential
Open Burning - Industrial
Open Burning - Commercial/Institutional
Light-Duty Gasoline Vehicles - Limited Access Roads
Light-Duty Gasoline Vehicles - Rural Roads
Light-Duty Gasoline Vehicles - Suburban Roads
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
C-89
-------
TABLE C-3. AREA SOURCE CODE DESCRIPTIONS
Area
Source Code
Category Description
030
031
032
033
034
035
036
037
038
039
040
041
042
043
044
045
046
047
048
049
050
051
052
054
055
056
057
058
059
Light-Duty Gasoline Vehicles - Urban Roads
Medium-Duty Gasoline Vehicles - Limited Access Roads
Medium-Duty Gasoline Vehicles - Rural Roads
Medium-Duty Gasoline Vehicles - Suburban Roads
Medium-Duty Gasoline Vehicles - Urban Roads
Heavy-Duty Gasoline Vehicles - Limited Access Roads
Heavy-Duty Gasoline Vehicles - Rural Roads
Heavy-Duty Gasoline Vehicles - Suburban Roads
Heavy-Duty Gasoline Vehicles - Urban Roads
Off-Highway Gasoline Vehicles
Heavy-Duty Diesel Vehicles - Limited Access Roads
Heavy-Duty Diesel Vehicles - Rural Roads
Heavy-Duty Diesel Vehicles - Suburban Roads
Heavy-Duty Diesel Vehicles - Urban Roads
Off-Highway Diesel Vehicles
Railroad Locomotives
Aircraft Landing and Takeoff (LTO) - Military
Aircraft Landing and Takeoff (LTO) - Civil
Aircraft Landing and Takeoff (LTO) - Commercial
Vessels - Coal
Vessels - Diesel Oil
Vessels - Residual Oil
Vessels - Gasoline
Gasoline Marketed
Unpaved Road Travel
Unpaved Airstrip LTOs
Construction
Miscellaneous Wind Erosion
Land Tilling
C-90
-------
TABLE C-3. AREA SOURCE CODE DESCRIPTIONS
Area
Source Code Category Description
060 Forest Wild Fires
061 Managed Burning - Prescribed
062 Agricultural Field Burning
063 Frost Control - Orchard Heaters
064 Structural Fires
071 Beef Cattle Manure Field Application
072 Dairy Cattle Manure Field Application
073 Hog and Pig Manure Field Application
074 Broiler Chicken Manure Field Application
075 Other Chicken Manure Field Application
076 Anhydrous Ammonia Fertilizer Application
077 Beef Cattle Feed Lots
078 Degreasing
079 Drycleaning
080 Graphic Arts (Printing)
081 Rubber and Plastics Manufacturing
082 Architectural Coating
083 Auto Body Repair
084 Motor Vehicle Manufacturing
085 Paper Coating
086 Fabricated Metals
087 Machinery Manufacturing
088 Furniture Manufacturing
089 Flat Wood Products
090 Other Transportation Equipment Manufacturing
091 Electrical Equipment Manufacturing
092 Ship Building and Repairing
093 Miscellaneous Industrial Manufacturing
094 Miscellaneous Industrial Solvent Use
C-91
-------
TABLE C-3. AREA SOURCE CODE DESCRIPTIONS
Area
Source Code
Category Description
095
096
097
098
099
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
Miscellaneous Nonindustrial Solvent Use
Minor Utility Sources - Coal
Minor Utility Sources - Oil
Minor Utility Sources - Gas
Minor Point Sources
Publicly Owned Treatment Works (POTWs)
Fugitive Emissions from Synthetic Organic Chemical Manufacture
Bulk Terminals and Bulk Plants
Fugitive Emissions from Petroleum Refining Operations
Process Emissions from Bakeries
Process Emissions from Pharmaceutical Manufacture
Process Emissions from Synthetic Fibers Manufacture
Crude Oil and Natural Gas Production Fields
Cutback Asphalt Paving Operations
Hazardous Waste Treatment, Storage, and Disposal Facilities
Transportation Composite
Light-Duty Diesel Vehicles
Tire Wear
Paved Roads
Marine Aerosol
Volcanic Ash
C-92
-------
APPENDIX D
CHEMICAL SPECIES DATA FILE
-------
D-2
-------
APPENDIX D
CHEMICAL SPECIES DATA FILE
In this appendix, Table D-l presents an alphabetical listing of all
species used in the profiles including their molecular weight, SAROAD code,
and CAS number. Table D-2 presents the same information ordered according to
SAROAD codes.
If the CAS number for a species were not readily available, this is
indicated by a "0" in the appropriate column. This does not mean that the CAS
number for a particular species is zero. For several uncommon species, it was
difficult to find or calculate molecular weights. An estimate is provided for
these species. In cases where a species represents a group or class of
compounds, an average molecular weight value is provided.
D-3
-------
TABLE D-l. SPECIES DATA FILE (ALPHABETICAL LISTING)
Page No. 1
10/11/89
MOLECULAR SAROAD
WEIGHT NUMBER
133.42
133.42
134.22
134.22
120.19
120.19
120.19
54.09
90.12
54.09
92.57
140.27
104.15
98.18
84.16
120.19
120.19
134.22
134.22
96.17
126.24
70.13
154.30
207.02
114.22
72.17
114.20
114.22
128.26
86.17
100.20
84.16
86.17
128.26
114.22
142.28
114.22
114.22
128.25
128.26
142.29
112.22
43814
43820
45217
45237
45225
45208
45207
43218
43322
43281
43835
90014
43313
90057
43245
99913
99912
99917
99916
43299
43269
43224
90032
45703
43287
43222
43912
43250
98033
43291
43274
43234
43276
. 90006
43290
99908
43280
43252
90002
90003
99910
98054
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2,
2
2,
2,
2,
2,
SPECIES NAME
1,1,1-TRICHLOROETHANE
1,1,2-TRICHLOROETHANE
1,2 DIETHYLBENZENE
1,2,3,4 TETRAMETHYLBENZENE
1,2,3-TRIMETHYLBENZENE
1,2,4-TRIMETHYLBENZENE
1,3,5-TRIMETHYLBENZENE
1,3-BUTADIENE
1,4 BUTANEDIOL
1-BUTYNE
1-CHLOROBUTANE
1-DECENE
l-ETHOXY-2-PROPANOL
1-HEPTENE
1-HEXENE
l-METHYL-2-ETHYLBENZENE
l-METHYL-3-ETHYLBENZENE
l-METHYL-3-ISOPROPYLBENZENE
1-METHYL-3N-PROPYLBENZENE
1-METHYLCYCLOHEXENE
1-NONENE
1-PENTENE
1-UNDECENE
2,2 DICHLORONITROANILINE
2,2 DIMETHYLHEXANE
2,2 DIMETHYLPROPANE
2,2,4-TRIME-PENTANE
2,2,4-TRIMETHYLPENTANE
2,2,5-TRIMETHYLHEXANE
2,2-DIMETHYLBUTANE
2,3 DIMETHYL PENTANE
2,3 DIMETHYL-1-BUTENE
2,3 DIMETHYLBUTANE
2,3 DIMETHYLHEPTANE
2,3 DIMETHYLHEXANE
2,3 DIMETHYLOCTANE
2,3,3 TRIMETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
2,3,5-TRIMETHYLHEXANE
2,4 DIMETHYLHEPTANE
2,4 DIMETHYLOCTANE
2,4,4-TRIMETHYL-l-PENTENE
CAS NUMBER
71556
79005
135013
488233
526738
95636
108678
106990
110634
107006
78864
8720509
592767
592416
124118
109671
821954
590738
463821
540841
540841
75832
565593
563780
79298
565753
107391
D-4
-------
TABLE D-l. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
142.29
114.22
100.20
128.26
114.22
167.31
162.26
128.19
54.09
130.23
84.16
96.09
84.16
72.20
58.10
100.20
70.13
84.16
70.13
84.16
114.19
156.32
114.23
128.26
86.17
100.20
142.29
128.26
128.26
148.68
98.19
86.17
70.13
84.16
84.16
114.23
100.20
128.26
198.17
84.16
84.18
107.17
2
SAROAD
NUMBER
90009
43277
43247
90005
43278
99909
43312
43391
43282
43318
43279
45503
43285
43911
43910
43263
43225
98040
43228
43284
43563
99918
43296
90008
43229
90040
99911
90004
43271
43836
98041
43230
43223
43211
43270
43298
43295
90015
46111
90007
43293
46114
SPECIES NAME
2,4,5-TRIMETHYLHEPTANE
2,4-DIMETHYLHEXANE
2,4-DIMETHYLPENTANE
2,5 DIMETHYLHEPTANE
2,5-DIMETHYLHEXANE
2,6 DIMETHYLOCTANE
2 - ( 2 - BUTOXYETHOXY ) - ETHANOL
2 - BUTYLTETRAHYDROFURAN
2-BUTYNE
2 -ETHYL HEXANOL
2-ETHYL-l-BUTENE
2 -FURFURAL
2-HEXENE
2-ME-BUTANE
2-ME-PROPANE
2-METHYL HEXANE
2-METHYL-l-BUTENE
2-METHYL-l-PENTENE
2-METHYL-2-BUTENE
2-METHYL-2-PENTENE
2-METHYL-3-HEXANONE
2-METHYLDECANE
2-METHYLHEPTANE
2-METHYLOCTANE
2-METHYLPENTANE
3,3 DIMETHYLPENTANE
3,4 DIMETHYLOCTANE
3,5 DIMETHYLHEPTANE
3,5,5-TRIMETHYLHEXANE
3- (CHLOROMETHYL) -HEPTANE
3-HEPTENE
3 -METHYL PENTANE
3-METHYL-l-BUTENE
3-METHYL-l-PENTENE
3-METHYL-T-2-PENTENE
3-METHYLHEPTANE
3-METHYLHEXANE
3-METHYLOCTANE
4,4-METHYLENE DIANILINE
4-METHYL-l-PENTENE
4-METHYL-T-2-PENTENE
4-METHYLANILINE
CAS NUMBER
108087
592132
112345
503173
104767
760214
98011
78784
75285
591764
563462
763291
513359
625274
7379126
592278
107835
562492
96140
563451
760203
922612
589344
101779
691372
27236460
100618
D-5
-------
TABLE D-l. (Continued)
Page No. 3
10/11/89
MOLECULAR SAROAD
WEIGHT NUMBER
114.23
128.26
132.20
136.24
154.21
152.20
44.05
60.05
102.09
58.08
26.04
56.07
72.06
53.06
146.14
100.00
72.10
223.23
93.13
276.34
178.23
208.23
136.24
136.24
106.13
78.11
228.30
252.32
252.32
252.32
276.34
252.32
228.30
252.32
122.13
252.32
135.19
126.59
154.21
170.22
262.03
247.02
43297
90016
45241
43256
46706
46705
43503
43404
43604
43551
43206
43505
43407
43704
43409
43132
43570
46103
45701
46725
46709
46102
90052
43257
45501
45201
46716
46719
46717
46724
46721
46718
46735
46714
45402
46742
46602
45810
45226
45330
45704
45705
SPECIES NAME CAS NUMBER
4-METHYLHEPTANE 589537
4-METHYLOCTANE
4-PHENYL-l-BUTENE 768569
A-PINENE 80568
ACENAPHTHENE 83329
ACENAPHTHYLENE 208968
ACETALDEHYDE 75070
ACETIC ACID 64197
ACETIC ANHYDRIDE 108247
ACETONE 67641
ACETYLENE 74862
ACROLEIN 107028
ACRYLIC ACID 79107
ACRYLONITRILE 107131
ADIPIC ACID 124049
ALIPHATICS
ALKENE KETONE
AMINOANTHRAQUINONE 82451
ANILINE 62533
ANTHANTHRENE 191264
ANTHRACENE 120127
ANTHRAQUINONE 84651
B-PHELLANDRENE
B-PINENE 127913
BENZALDEHYDE 100527
BENZENE 71432
BENZO (a) ANTHRACENE 56553
BENZO (a) PYRENE 50328
BENZO (b) FLUORANTHENE 205992
BENZO (e) PYRENE 192972
BENZO (g,h,i) PERYLENE 191242
BENZO (k) FLUORANTHENE 207089
BENZO(c)PHENANTHRENE 195197
BENZO(g,h,i) FLUORANTHENE
BENZOIC ACID 65850
BENZOPYRENES
BENZOTHIAZOLE 95169
BENZYL CHLORIDE 100447
BIPHENYL 92524
BIPHENYLOL 90437
BROMODINITROANILINE 1817738
BROMODINITROBENZENE
D-6
-------
TABLE D-l. (Continued)
Page No. 4
10/11/89
MOLECULAR SAROAD
WEIGHT NUMBER
SPECIES NAME
56.10
128.21
162.23
220.26
128.17
134.21
178.23
162.23
118.17
312.39
140.27
264.32
72.12
16.04
140.00
154.00
168.00
182.00
196.00
210.00
224.00
238.00
252.00
266.00
28.55
84.16
112.21
280.00
294.00
308.00
322.00
336.00
350.00
364.00
378.00
392.00
406.00
42.08
84.16
420.00
434.00
448.00
43213
43472
43337
43469
43440
45235
45455
43379
43308
45477
90101
45456
43510
99101
99110
99111
99112
99113
99114
99115
99116
99117
99118
99119
99102
98035
90013
99120
99121
99122
99123
99124
99125
99126
99127
99128
99129
99103
43283
99130
99131
99132
BUTENE
BUTOXYBUTENE
BUTOXYETHOXYETHANOL
BUTOXYETHOXYETHANOL ACETATE
BUTYL ACRYLATE
BUTYL BENZENE
BUTYL BENZOATE
BUTYL CARBITOL
BUTYL CELLOSOLVE
BUTYLBENZYLPHTHALATE
BUTYLCYCLOHEXANE
BUTYLISOPROPYLPHTHALATE
BUTYRALDEHYDE
C-l COMPOUNDS
C-10 COMPOUNDS
C-ll COMPOUNDS
C-l 2 COMPOUNDS
C-13 COMPOUNDS
C-14 COMPOUNDS
C-l 5 COMPOUNDS
C-l 6 COMPOUNDS
C-l 7 COMPOUNDS
C-18 COMPOUNDS
C-19 COMPOUNDS
C-2 COMPOUNDS
C-2-HEXENE
C-2-OCTENE
C-20 COMPOUNDS
C-21 COMPOUNDS
C-22 COMPOUNDS
C-23 COMPOUNDS
C-24 COMPOUNDS
C-25 COMPOUNDS
C-26 COMPOUNDS
C-27 COMPOUNDS
C-28 COMPOUNDS
C-29 COMPOUNDS
C-3 COMPOUNDS
C-3-HEXENE
C-30 COMPOUNDS
C-31 COMPOUNDS
C-32 COMPOUNDS
CAS NUMBER
106989
112345
124174
141322
104518
136607
112345
111762
85687
1678939
123728
592438
D-7
-------
TABLE D-l. (Continued)
Page No. 5
10/11/89
MOLECULAR SAROAD
WEIGHT NUMBER
SPECIES NAME
CAS NUMBER
462.00
476.00
490.00
504.00
518.00
532.00
546.00
57.08
560.00
574.00
588.00
602.00
71.00
79.12
93.18
98.19
112.00
112.23
112.23
126.00
126.26
134.22
140.27
142.28
132.22
136.24
152.24
154.29
142.20
162.23
168.32
166.31
226.45
146.23
112.22
158.24
256.35
230.31
256.34
206.28
156.23
126.24
99133
99134
99135
99136
99137
99138
99139
99104
99140
99141
99142
99143
99105
99106
99107
43115
99108
43116
43138
99109
43117
45110
43125
43135
45111
43153
43396
43146
45113
45610
43147
43152
43137
46711
43126
46729
46739
46740
46741
46730
46746
43127
C-33 COMPOUNDS
C-34 COMPOUNDS
C-35 COMPOUNDS
C-36 COMPOUNDS
C-37 COMPOUNDS
C-38 COMPOUNDS
C-39 COMPOUNDS
C-4 COMPOUNDS
C-40 COMPOUNDS
C-41 COMPOUNDS
C-42 COMPOUNDS
C-43 COMPOUNDS
C-5 COMPOUNDS
C-6 COMPOUNDS
C-7 COMPOUNDS
C-7 CYCLOPARAFFINS
C-8 COMPOUNDS
C-8 CYCLOPARAFFINS
C-8 OLEFINS
C-9 COMPOUNDS
C-9 CYCLOPARAFFINS
CIO AROMATIC
CIO OLEFINS
CIO PARAFFINS
C10H12
C10H16
C10H160
Cll OLEFINS
C11H10
C11H140
C12 OLEFINS
C12H22
C16 BRANCHED ALKANE
C2 ALKYL INDAN
C2 CYCLOHEXANE
C2-ALKYL-ANTHRACENES
C2-ALKYL-BENZANTHRACENES
C2-ALKYL-BENZOPHENANTHRENES
C2-ALKYL-CHRYSENES
C2-ALKYL-PHENANTHRENES
C2-ALKYLNAPHTHALENE
C3 CYCLOHEXANE
D-8
-------
TABLE D-l. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
146.23
134.21
140.27
154.26
150.22
160.26
154.30
130.19
70.13
72.15
70.13
154.30
148.24
146.25
164.25
86.13
84.16
168.32
162.27
222.47
98.18
100.20
176.30
156.31
96.17
112.17
114.23
122.16
110.20
296.60
126.24
128.25
136.19
136.24
113.16
134.18
76.13
153.84
60.08
204.36
90.12
132.16
6
SAROAD
NUMBER
45250
45109
43129
43467
45303
45248
43128
43459
43143
43144
43145
43130
45245
45246
45304
43399
43289
43131
45247
90019
43294
43142
45249
43140
43154
43395
43141
45310
43149
90020
43124
43136
45311
90050
43779
43377
43934
43804
43933
90130
43311
43452
SPECIES NAME CAS NUMBER
C3-ALKYLSTYRENE
C3/C4/C5 ALKYLBENZENES
C4 SUBSTITUTED CYCLOHEXANE
C4 SUBSTITUTED CYCLOHEXANONE
C4-ALKYLPHENOLS
C4-ALKYLSTYRENES
C5 CYCLOHEXANE
C5 ESTER
C5 OLEFIN
C5 PARAFFIN
C5 PARAFFIN/OLEFIN
C5 SUBSTITUTED CYCLOHEXANE
C5-ALKYLBENZENES
C5-ALKYLBENZENES (UNSAT.)
C5-ALKYLPHENOLS
C5H100
C6 OLEFINS
C6 SUBSTITUTED CYCLOHEXANE
C6-ALKYLBENZENE
C6H1803SI3
C7 OLEFINS
C7 PARAFFINS
C7-ALKYLBENZENE
C7-C16 PARAFFINS
C7H12
C7H120
C8 PARAFFIN
C8 PHENOLS
C8H14
C8H2404SI4
C9 OLEFINS
C9 PARAFFIN
C9 PHENOLS
CAMPHENE 5794036
CAPROLACTAM 105602
CARBITOL 111900
CARBON SULFIDE 75150
CARBON TETRACHLORIDE 56235
CARBONYL SULFIDE 433581
CARYOPHYLLENE 87445
CELLOSOLVE 110805
CELLOSOLVE ACETATE 111159
D-9
-------
TABLE D-l. (Continued)
Page No. 7
10/11/89
MOLECULAR SAROAD
WEIGHT NUMBER
112.56
86.47
119.39
154.47
88.54
104.46
228.29
112.22
56.11
70.13
300.36
130.19
108.14
70.09
120.20
84.16
100.16
98.15
82.14
226.28
247.36
190.25
70.14
68.11
138.25
136.24
138.25
32.04
238.37
390.56
116.18
278.35
278.35
302.38
278.36
130.23
278.35
147.01
120.91
84.94
170.92
140.27
45801
43840
43803
43842
43862
43845
46715
90038
43217
43227
46726
46210
45605
43515
45210
43248
43317
43561
43273
46734
46731
46732
43242
43292
90033
90053
46753
99933
45230
45470
43320
46743
46722
46745
46744
43372
45452
45808
43823
43802
43841
98062
SPECIES NAME CAS NUMBER
CHLOROBENZENE 108907
CHLORODIFLUOROMETHANE 75456
CHLOROFORM 67663
CHLOROPENTAFLUOROETHANE 76153
CHLOROPRENE 126998
CHLOROTRIFLUOROMETHANE 75729
CHRYSENE 218019
CIS-1,4 DIMETHYLCYCLOHEXANE 624293
CIS-2-BUTENE 590181
CIS-2-PENTENE 627203
CORONENE 191071
CREOSOTE 8001589
CRESOL 1319773
CROTONALDEHYDE 123739
CUMENE (ISOPROPYL BENZENE) 98828
CYCLOHEXANE 110827
CYCLOHEXANOL 108930
CYCLOHEXANONE 108941
CYCLOHEXENE 110838
CYCLOPENTA(c,d)PYRENE 27208373
CYCLOPENTA-ANTHRACENES
CYCLOPENTA-PHENANTHRENES
CYCLOPENTANE 287923
CYCLOPENTENE 142290
CYCLOPENTYLCYCLOPENTANE
D-LIMONENE 5989275
DECALINS 91178
DENATURANT
DI(ETHYLPHENYL) ETHANE
DI-C8 ALKYL PHTHALATE
DIACETONE ALCOHOL 123422
DIBENZANTHRACENES
DIBENZO(a,h) ANTHRACENE 53703
DIBENZOPYRENES
DIBENZPHENANTHRENES
DIBUTYL ETHER 142961
DIBUTYL PHTHALATE 84742
DICHLOROBENZENES 2531226
DICHLORODIFLUOROMETHANE 75718
DICHLOROMETHANE 75092
DICHLOROTETRAFLUORETHANE 76142
DIETHYLCYCLOHEXANE
D-10
-------
TABLE D-l. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
106.12
111.20
130.19
160.17
162.28
59.11
73.09
156.23
194.19
194.19
136.19
86.18
118.00
84.16
168.32 ,
98.14
112.24
98.19
96.17
170.34
46.07
178.23
140.26
128.26
144.26
110.20
174.20
114.23
112.20
146.23
144.22
158.20
156.31
142.28
158.32
140.27
138.25
100.20
160.17
116.20
98.19
184.36
8
SAROAD
NUMBER
43373
90110
46751
46204
45236
43780
43450
46703
45451
45450
45320
90060
43471
90061
90114
43565
98059
90064
90065
90074
43350
45404
90069
98091
43333
90068
43476
90067
43286
46750
46752
46115
90076
90070
43332
90124
90112
90062
43477
43331
90063
90071
SPECIES NAME
DIETHYLENE 6LYCOL
DIETHYLMETHYLCYCLOHEXANES
DIHYDRONAPTHALENE
DIHYDROXYNAPTHALENEDIONE
DIISOPROPYL BENZENE
DIMETHYL ALKYL AMINES
DIMETHYL FORMAMIDE
DIMETHYL NAPTHALENE
DIMETHYL PHTHALATE
DIMETHYL TEREPHTHALATE
DIMETHYLBENZYLALCOHOL
DIMETHYLBUTANE
DIMETHYLBUTANEDIOATE
DIMETHYLBUTENE
DIMETHYLBUTYLCYCLOHEXANE
DIMETHYLCYCLOBUTANONE
DIMETHYLCYCLOHEXANE
DIMETHYLCYCLOPENTANE
DIMETHYLCYCLOPENTENES
DIMETHYLDECANE
DIMETHYLETHER
DIMETHYLETHYLBENZOIC ACID
DIMETHYLETHYLCYCLOHEXANE
DIMETHYLHEPTANES
DIMETHYLHEPTANOL
DIMETHYLHEXADIENE
DIMETHYLHEXANEDIOATE
DIMETHYLHEXANES
DIMETHYLHEXENE
DIMETHYLINDANS
DIMETHYLINDENE
DIMETHYLNAPHTHYRIDINE
DIMETHYLNONANES
DIMETHYLOCTANES
DIMETHYLOCTANOL
DIMETHYLOCTENES
DIMETHYLOCTYNE
DIMETHYLPENTANE
DIMETHYLPENTANEDIOATE
DIMETHYLPENTANOL
DIMETHYLPENTENE
DIMETHYLUNDECANE
CAS NUMBER
111466
68122
28804888
131113
120616
79298
115106
106218
10143234
D-ll
-------
TABLE D-l. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
182.27
250.30
134.18
130.20
168.32
282.56
92.53
30.07
61.08
88.10
100.11
46.07
64.52
74.12
62.13
132.21
210.32
45.09
106.16
223.42
112.23
98.19
96.17
134.22
140.27
172.35
128.26
150.22
28.05
187.88
99.00
62.07
44.05
45.08
96.14
128.26
126.24
114.23
144.24
146.23
88.15
126.24
9
SAROAD
NUMBER
45232
45454
43374
45229
90001
90126
43863
43202
43777
43433
43438
43302
43812
43351
43902
45228
45233
43721
45203
90086
43288
98057
90079
45243
90089
90129
90087
45302
43203
43837
43815
43370
43601
43778
43392
90084
98082
90081
43473
46754
98106
90083
SPECIES NAME
DIPHENYL ETHANE
DIPROPYL PHTHALATE
DIPROPYLENE GLYCOL
DIVINYL BENZENE
DODECENE
EICOSANE
EPICHLOROHYDRIN
ETHANE
ETHANOLAMINE
ETHYL ACETATE
ETHYL ACRYLATE
ETHYL ALCOHOL
ETHYL CHLORIDE
ETHYL ETHER
ETHYL MERCAPTAN
ETHYL STYRENE
ETHYL-PHENYL-PHENYL-ETHANE
ETHYLAMINE
ETHYLBENZENE
ETHYLBICYCLOHEPTANE
ETHYLCYCLOHEXANE
ETHYLCYCLOPENTANE
ETHYLCYCLOPENTENE
ETHYLDIMETHYLBENZENE
ETHYLDIMETHYLCYCLOHEXANE
ETHYLDIMETHYLOCTANE
ETHYLDIMETHYLPENTANE
ETHYLDIMETHYLPHENOL
ETHYLENE
ETHYLENE DIBROMIDE
ETHYLENE DICHLORIDE
ETHYLENE GLYCOL
ETHYLENE OXIDE
ETHYLENEAMINES
ETHYLFURAN
ETHYLHEPTANE
ETHYLHEPTENE
ETHYLHEXANE
ETHYLHEXANOATE
ETHYLINDAN
ETHYLISOPROPYL ETHER
ETHYLMETHYLCYCLOHEXANES
CAS NUMBER
103297
131168
106627
1321740
112414
112958
106898
74840
141435
141786
140885
64175
75003
60297
75081
75057
100414
1678917
1640897
74851
106934
107062
107211
75218
D-12
-------
TABLE 0-1. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
112.21
128.26
156.31
142.29
140.27
98.19
154.29
120.19
202.26
166.22
30.03
46.03
98.10
92.09
61.09
106.14
58.04
296.59
110.17
100.20
98.18
226.45
256.48
96.14
138.01
116.20
100.16
86.17
84.16
118.18
82.15
118.18
116.16
276.34
72.15
58.12
60.09
88.15
116.16
128.19
74.12
144.21
10
SAROAD
NUMBER
90080
90082
90085
90077
90075
90078
90090
45238
46710
46707
43502
43403
45604
43380
43368
43367
43513
90125
90059
43232
43264
90030
43410
90058
43843
43776
43512
43231
90056
43371
90037
98044
46712
46720
43221
43214
43304
43330
43446
43468
43306
43451
SPECIES NAME
ETHYLMETHYLCYCLOPENTANE
ETHYLMETHYLHEXANE
ETHYLMETHYLOCTANE
ETHYLOCTANE
ETHYLOCTENE
ETHYLPENTENE
ETHYLPROPYLCYCLOHEXANES
ETHYLTOLUENE
FLUORANTHENE
FLUORENE
FORMALDEHYDE
FORMIC ACID
FURFURYL ALCOHOL
GLYCEROL
GLYCOL
GLYCOL ETHER
GLYOXAL
HENEICOSANE
HEPTADIENAL
HEPTANE
HEPTENE
HEXADECANE
HEXADECANOIC ACID
HEXADIENAL
HEXAFLUOROETHANE
HEXAMETHYLENEDIAMINE
HEXANAL
HEXANE
HEXENE
HEXYLENE GLYCOL
HEXYNE
INDANE
INDENE
INDENO(l,2,3-cd) PYRENE
ISO PENTANE
ISO-BUTANE
ISO-PROPYL ALCOHOL
ISOAMYL ALCOHOL
ISOBUTYL ACETATE
ISOBUTYL ACRYLATE
ISOBUTYL ALCOHOL
ISOBUTYL ISOBUTYRATE
CAS NUMBER
206440
86737
50000
64186
98000
56815
111466
107222
629947
5910859
142825
544763
57103
142836
76164
124094
66251
110543
107415
496117
95136
193395
78784
75285
67630
123513
110190
106638
78831
297858
D-13
-------
TABLE D-l. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
134.22
56.10
72.11
56.10
134.22
130.19
138.25
152.28
124.23
142.28
134.21
170.32
120.19
240.47
100.20
86.17
128.25
254.50
114.23
212.41
72.15
70.13
120.19
198.38
184.36
156.30
106.16
68.12
102.13
126.25
113.22
140.27
86.14
114.00
136.24
147.01
134.22
120.19
106.16
106.16
98.06
16.04
11
SAROAD
NUMBER
99915
43215
43511
43120
45105
45112
43150
43151
43148
43109
45106
43111
45104
43155
43106
43105
43108
43156
43107
43114
43122
43121
45108
43113
43112
43110
45102
43243
43444
90128
90116
90111
98056
43119
90117
45806
45218
45212
45205
90010
43603
43201
SPECIES NAME
ISOBUTYLBENZENE
ISOBUTYLENE
ISOBUTYRALDEHYDE
ISOMERS OF BUTENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF C10H10
ISOMERS OF C10H18
ISOMERS OF C11H20
ISOMERS OF C9H16
ISOMERS OF DECANE
ISOMERS OF DIETHYLBENZENE
ISOMERS OF DODECANE
ISOMERS OF ETHYLTOLUENE
ISOMERS OF HEPTADECANE
ISOMERS OF HEPTANE
ISOMERS OF HEXANE
ISOMERS OF NONANE
ISOMERS OF OCTADECANE
ISOMERS OF OCTANE
ISOMERS OF PENTADECANE
ISOMERS OF PENTANE
ISOMERS OF PENTENE
ISOMERS OF PROPYLBENZENE
ISOMERS OF TETRADECANE
ISOMERS OF TRIDECANE
ISOMERS OF UNDECANE
ISOMERS OF XYLENE
ISOPRENE
ISOPROPYL ACETATE
ISOPROPYLCYCLOHEXANE
ISOPROPYLCYCLOPENTANE
ISOPROPYLMETHYLCYCLOHEXANE
ISOVALERALDEHYDE
LACTOL SPIRITS
LIMONENE
M-DICHLOROBENZENE
M-DIETHYLBENZENE
M-ETHYLTOLUENE
M-XYLENE
M-XYLENE AND P-XYLENE
MALEIC ANHYDRIDE
METHANE
CAS NUMBER
538932
115117
78842
1330207
78795
108214
590863
5989275
541731
141935
620144
108383
108316
74828
D-14
-------
TABLE D-l. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
120.15
116.00
158.20
86.09
32.04
114.21
168.24
100.16
214.35
228.37
242.40
256.43
270.45
326.56
340.59
120.15
76.11
50.49
214.35
72.10
60.05
72.07
100.16
100.13
242.41
142.20
270.46
298.52
118.19
88.15
192.26
242.33
242.33
242.33
216.29
192.26
74.08
134.17
40.06
76.11
54.09
68.12
12
SAROAD
NUMBER
43335
43569
46203
43437
43301
43562
45227
43559
43460
43461
43462
43463
43464
43465
43466
43378
43310
43801
43470
43552
43430
43514
43560
43441
43455
46702
43454
43456
45221
43376
46727
46736
46737
46738
46733
46728
43432
45550
43209
43457
90011
90024
SPECIES NAME
METHOXYETHOXYETHANOL
METHOXYMETHYLBUTANONE
METHOXYNAPHTHALENE
METHYL ACRYLATE
METHYL ALCOHOL
METHYL AMYL KETONE
METHYL BIPHENYL
METHYL BUTYL KETONE
METHYL Cll ESTER
METHYL C12 ESTER
METHYL C13 ESTER
METHYL C14 ESTER
METHYL CIS ESTER
METHYL C19 ESTER
METHYL C20 ESTER
METHYL CARBITOL
METHYL CELLOSOLVE
METHYL CHLORIDE
METHYL DODECANOATE
METHYL ETHYL KETONE
METHYL FORMATE
METHYL GLYOXAL
METHYL ISOBUTYL KETONE
METHYL METHACRYLATE
METHYL MYRI STATE
METHYL NAPHTHALENES
METHYL PALMITATE
METHYL STEARATE
METHYL STYRENE
METHYL T- BUTYL ETHER
METHYL-ANTHRACENES
METHYL-BENZANTHRACENES
METHYL-BENZPHENANTHRENES
METHYL-CHRYSENES
METHYL- FLUORANTHENES
METHYL- PHENANTHRENES
METHYLACETATE
METHYLACETOPHENONE
METHYLACETYLENE (PROPYNE)
METHYLAL
METHYLALLENE
METHYLBUTAOIENE
CAS NUMBER
96333
67561
110430
591786
111773
109864
74873
111820
78933
107313
78988
108101
80626
124107
112390
112618
25013154
628284
79209
74997
109875
D-15
-------
TABLE D-l. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
70.13
94.15
98.21
96.17
127.25
80.14
84.16
82.14
152.28
156.32
154.29
144.22
184.36
173.85
250.27
142.22
144.22
114.23
130.26
112.22
110.20
96.17
114.19
100.20
98.18
132.21
130.19
140.27
100.13
142.28
140.26
128.26
86.17
84.16
58.12
56.10
140.27
184.36
170.34
114.00
136.24
58.12
13
SAROAD
NUMBER
90023
90041
43261
90046
90017
90027
43262
43272
46748
90048
90107
46749
90108
43805
45730
90121
43475
90045
43334
98090
90044
90039
90043
90028
90029
46747
90119
90073
43474
90047
90106
90104
90026
90025
90021
90022
90072
90102
90049
43118
90051
43212
SPECIES NAME CAS NUMBER
METHYLBUTENE
METHYLCYCLOHEXADIENE 4313579
METHYLCYCLOHEXANE 108872
METHYLCYCLOHEXENE
METHYLCYCLOOCTANE
METHYLCYCLOPENTADIENE
METHYLCYCLOPENTANE 96377
METHYLCYCLOPENTENE 693890
METHYLDECALINS
METHYLDECANES
METHYLDECENE
METHYLDIHYDRONAPHTHALENE
METHYLDODECANE
METHYLENE BROMIDE 74953
METHYLENE(b)4-PHENYLISOCYANATE 101688
METHYLETHYLHEPTANE
METHYLETHYLPENTANOATE
METHYLHEPTANE
METHYLHEPTANOL
METHYLHEPTENE
METHYLHEPTYNE
METHYLHEXADIENE
METHYLHEXANAL
METHYLHEXANE
METHYLHEXENES
METHYLINDANS
METHYLINDENE
METHYLISOPROPYLCYCLOHEXANE
METHYLMETHYLPROPENOATE
METHYLNONANE
METHYLNONENE
METHYLOCTANES
METHYLPENTANE
METHYLPENTENES
METHYLPROPANE
METHYLPROPENE
METHYLPROPYLCYCLOHEXANES
METHYLPROPYLNONANE
METHYLUNDECANE
MINERAL SPIRITS 64475850
MYRCENE 123353
N-BUTANE 106978
n-ie
-------
TABLE D-l. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
116.16
74.12
142.28
170.33
240.46
212.41
72.15
70.14
154.30
169.24
102.15
60.10
120.19
198.38
184.36
156.31
114.00
128.17
123.11
268.53
124.23
128.25
126.24
140.22
220.36
147.01
120.19
106.16
244.00
225.20
296.62
114.23
130.26
108.19
112.21
86.00
147.01
120.16
106.16
256.43
352.43
65.14
14
SAROAD
NUMBER
43435
43305
43238
43255
90031
43260
43220
90035
98063
45706
43434
43303
45209
43259
43258
43241
45101
46701
45702
90127
90066
43235
90100
43568
45301
45805
45211
45204
46202
90118
43950
43233
43336
90099
43265
43650
45807
45502
45206
43408
43133
43139
SPECIES NAME
N-BUTYL ACETATE
N-BUTYL ALCOHOL
N-DECANE
N-DODECANE
N-HEPTADECANE
N-PENTADECANE
N-PENTANE
N-PENTENE
N-PENTYLCYCLOHEXANE
N-PHENYLANILINE
N-PROPYL ACETATE
N-PROPYL ALCOHOL
N-PROPYLBENZENE
N-TETRADECANE
N-TRIDECANE
N-UNDECANE
NAPHTHA
NAPTHALENE
NITROBENZENE
NONADECANE
NONADIENE
NONANE
NONENE
NONENONE
NONYLPHENOL
0-DICHLOROBENZENE
0-ETHYLTOLUENE
0-XYLENE
OCTAHYDROINDENES
OCTAHYDROPENTALENE
OCTAMETHYLCYCLOTETRASILOXANE
OCTANE
OCTANOL
OCTATRIENE
OCTENE
OXYGENATES
P-DICHLOROBENZENE
P-TOLUALDEHYDE
P-XYLENE
PALMITIC ACID
PARAFFINS (C16-C34)
PARAFFINS (C2-C7)
CAS NUMBER
138227
71363
124185
112403
629787
629629
109660
25377724
109604
71238
103651
629594
629505
1120214
8030306
91123
98953
111842
25154523
95501
611143
95476
556672
111659
111660
106467
104870
106423
57103
D-17
-------
TABLE D-l. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
197.38
68.13
88.15
66.10
148.25
154.29
152.00
68.12
165.83-
252.32
178.23
94.11
119.13
204.27
148.12
68.12
200.00
40.06
44.09
42.08
124.33
58.08
74.08
126.24
112.99
76.11
58.08
140.27
202.26
74.12
134.21
76.08
104.14
218.24
132.20
56.11
84.16
126.24
84.16
166.14
136.23
74.12
15
SAROAD
NUMBER
43134
90103
43319
90054
45231
90055
90113
90036
43817
46723
46708
45300
46112
46704
45601
45750
43381
43208
43204
43205
90105
43504
43405
90120
43838
43369
43602
90109
46713
43314
45216
43951
45220
43458
45242
43216
98034
90034
90042
45403
43123
43309
SPECIES NAME CAS NUMBER
PARAFFINS/OLEFINS (C12-C16)
PENTADIENE
PENTANOL 71410
PENTENYNE
PENTYL BENZENE
PENTYLCYCLOHEXANE
PENTYLIDENECYCLOHEXANE
PENTYNE
PERCHLOROETHYLENE 127184
PERYLENE 198550
PHENANTHRENE 85018
PHENOL 108952
PHENYL ISOCYANATE 103719
PHENYLNAPHTHALENES
PHTHALIC ANHYDRIDE 85449
PIPERYLENE 504609
POLYETHYLENE GLYCOL 25322683
PROPADIENE 463490
PROPANE 74986
PROPENE 115071
PROPENYLCYCLOHEXANE
PROPIONALDEHYDE 123386
PROPIONIC ACID 79094
PROPYLCYCLOHEXANE
PROPYLENE DICHLORIDE 26638197
PROPYLENE GLYCOL 57556
PROPYLENE OXIDE 75569
PROPYLHEPTENES
PYRENE 129000
S-BUTYL ALCOHOL 78922
S-BUTYLBENZENE 135988
SILOXANE
STYRENE 100425
SUBSTITUTED C9 ESTER (C12)
T-1-PHENYLBUTENE
T-2-BUTENE 624646
T-2-HEXENE 40504557
T-2-NONENE 6434782
T-3-HEXENE 13269528
TEREPHTHALIC ACID 100210
TERPENES
TERT-BUTYL ALCOHOL 75650
D-18
-------
TABLE D-l. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
134.21
215.90
88.01
134.22
110.19
126.24
142.28
142.24
88.23
132.25
92.13
174.17
117.15
93.13
72.12
70.13
181.45
131.40
137.38
187.38
150.17
70.01
59.11
120.19
126.27
142.24
112.16
126.20
184.36
182.35
92.00
142.29
128.26
126.24
160.26
168.32
156.31
110.20
114.22
86.00
86.09
62.50
16
SAROAD
NUMBER
45215
45831
43839
45244
90091
90098
90122
43567
43952
46601
45202
45731
45732
45740
43520
43226
45830
43824
43811
43821
43375
43844
43740
45107
98060
43397
98058
43566
90097
98083
43822
90094
90115
90095
46755
90123
90096
90093
90092
99999
43453
43860
SPECIES NAME
TERT-BUTYLBENZENE
TETRACHLOROBENZENES
TETRAFLUOROMETHANE
TETRAMETHYLBENZENE
TETRAMETHYLCYCLOBUTENE
TETRAMETHYLCYCLOPENTANE
TETRAMETHYLHEXANE
TETRAMETHYLPENTANONE
TETRAMETHYLSILANE
TETRAMETHYLTHIOUREA
TOLUENE
TOLUENE DIISOCYANATE
TOLUENEISOCYANIDE
TOTAL AROMATIC AMINES
TOTAL C2-C5 ALDEHYDES
TRANS-2-PENTENE
TRICHLOROBENZENES
TRICHLOROETHYLENE
TRICHLOROFLUOROMETHANE
TRICHLOROTRIFLUOROETHANE
TRIETHYLENE 6LYCOL
TRIFLUOROMETHANE
TRIMETHYLAMINE
TRIMETHYLBENZENE
TRIMETHYLCYCLOHEXANES
TRIMETHYLCYCLOHEXANOL
TRIMETHYLCYCLOPENTANE
TRIMETHYLCYCLOPENTANONE
TRIMETHYLDECANE
TRIMETHYLDECENE
TRIMETHYLFLUOROSILANE
TRIMETHYLHEPTANES
TRIMETHYLHEXANES
TRIMETHYLHEXENE
TRIMETHYLINDAN
TRIMETHYLNONENE
TRIMETHYLOCTANES
TRIMETHYLPENTADIENE
TRIMETHYLPENTANE
UNIDENTIFIED
VINYL ACETATE
VINYL CHLORIDE
CAS NUMBER
98066
75730
75763
2782914
108883
58849
646048
79016
75694
76131
112276
75467
75503
25551137
3073663
108054
75014
D-19
-------
TABLE D-l. (Continued)
Page No. 17
10/11/89
MOLECULAR SAROAD
WEIGHT NUMBER
230.00
45401
SPECIES NAME
XYLENE BASE ACIDS
CAS NUMBER
D-20
-------
TABLE D-2. SPECIES DATA FILE (ACCORDING TO SAROAD CODE)
Page No. 1
10/11/89
MOLECULAR SAROAD
WEIGHT NUMBER
86.17
100.20
114.23
128.25
142.28
156.30
170.32
184.36
198.38
212.41
98.19
112.23
126.26
114.00
114.00
56.10
70.13
72.15
136.23
126.24
140.27
112.22
126.24
154.30
140.27
154.30
168.32
100.00
352.43
197.38
142.28
128.25
226.45
112.23
65.14
156.31
114.23
100.20
70.13
72.15
70.13
154.29
43105
43106
43107
43108
43109
43110
43111
43112
43113
43114
43115
43116
43117
43118
43119
43120
43121
43122
43123
43124
43125
43126
43127
43128
43129
43130
43131
43132
43133
43134
43135
43136
43137
43138
43139
43140
43141
43142
43143
43144
43145
43146
SPECIES NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
ISOMERS OF DODECANE
ISOMERS OF TRIDECANE
ISOMERS OF TETRADECANE
ISOMERS OF PENTADECANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
MINERAL SPIRITS
LACTOL SPIRITS
ISOMERS OF BUTENE
ISOMERS OF PENTENE
ISOMERS OF PENTANE
TERPENES
C9 OLEFINS
CIO OLEFINS
C2 CYCLOHEXANE
C3 CYCLOHEXANE
C5 CYCLOHEXANE
C4 SUBSTITUTED CYCLOHEXANE
C5 SUBSTITUTED CYCLOHEXANE
C6 SUBSTITUTED CYCLOHEXANE
ALIPHATICS
PARAFFINS (C16-C34)
PARAFFINS/OLEFINS (C12-C16)
CIO PARAFFINS
C9 PARAFFIN
C16 BRANCHED ALKANE
C-8 OLEFINS
PARAFFINS (C2-C7)
C7-C16 PARAFFINS
C8 PARAFFIN
C7 PARAFFINS
C5 OLEFIN
C5 PARAFFIN
C5 PARAFFIN/OLEFIN
Cll OLEFINS
CAS NUMBER
64475850
D-21
-------
TABLE D-2. (Continued)
Page No. 2
10/11/89
MOLECULAR SAROAD
WEIGHT NUMBER
168.32
124.23
110.20
138.25
152.28
166.31
136.24
96.17
240.47
254.50
16.04
30.07
28.05
44.09
42.08
26.04
40.06
40.06
84.16
58.12
56.10
58.12
56.10
56.11
56.11
54.09
72.15
72.15
72.17
70.13
70.13
70.13
70.13
70.13
70.13
86.17
86.17
86.17
100.20
114.23
84.16
128.25
43147
43148
43149
43150
43151
43152
43153
43154
43155
43156
43201
43202
43203
43204
43205
43206
43208
43209
43211
43212
43213
43214
43215
43216
43217
43218
43220
43221
43222
43223
43224
43225
43226
43227
43228
43229
43230
43231
43232
43233
43234
43235
SPECIES NAME
C12 OLEFINS
ISOMERS OF C9H16
C8H14
ISOMERS OF C10H18
ISOMERS OF C11H20
C12H22
C10H16
C7H12
ISOMERS OF HEPTADECANE
ISOMERS OF OCTADECANE
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
PROPADIENE
METHYLACETYLENE (PROPYNE)
3-METHYL-l-PENTENE
N-BUTANE
BUTENE
ISO-BUTANE
ISOBUTYLENE
T-2-BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
ISO PENTANE
2,2 DIMETHYLPROPANE
3-METHYL-l-BUTENE
1-PENTENE
2-METHYL-l-BUTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-METHYL-2-BUTENE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
2,3 DIMETHYL-1-BUTENE
NONANE
CAS NUMBER
74828
74840
74851
74986
115071
74862
463490
74997
760203
106978
106989
75285
115117
624646
590181
106990
109660
78784
463821
563451
109671
563462
646048
627203
513359
107835
96140
110543
142825
111659
563780
111842
D-22
-------
TABLE D-2. (Continued)
Page No. 3
10/11/89
MOLECULAR SAROAD
WEIGHT NUMBER
142.28
156.31
70.14
68.12
84.16
100.20
84.16
114.22
114.22
170.33
136.24
136.24
184.36
198.38
212.41
98.21
84.16
100.20
98.18
112.21
126.24
84.16
128.26
82.14
82.14
100.20
86.17
114.22
114.22
84.16
114.22
54.09
54.09
84.16
84.16
84.16
112.20
114.22
112.23
84.16
114.22
86.17
43238
43241
43242
43243
43245
43247
43248
43250
43252
43255
43256
43257
43258
43259
43260
43261
43262
43263
43264
43265
43269
43270
43271
43272
43273
43274
43276
43277
43278
43279
43280
43281
43282
43283
43284
43285
43286
43287
43288
43289
43290
43291
SPECIES NAME
N-DECANE
N-UNDECANE
CYCLOPENTANE
ISOPRENE
1-HEXENE
2,4-DIMETHYLPENTANE
CYCLOHEXANE
2,2,4-TRIMETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
N-DODECANE
A-PINENE
B-PINENE
N-TRIDECANE
N-TETRADECANE
N-PENTADECANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-METHYL HEXANE
HEPTENE
OCTENE
1-NONENE
3-METHYL-T-2-PENTENE
3,5,5-TRIMETHYLHEXANE
METHYLCYCLOPENTENE
CYCLOHEXENE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
2,4-DIMETHYLHEXANE
2,5-DIMETHYLHEXANE
2-ETHYL-l-BUTENE
2,3,3 TRIMETHYLPENTANE
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-METHYL-2-PENTENE
2-HEXENE
DIMETHYLHEXENE
2,2 DIMETHYLHEXANE
ETHYLCYCLOHEXANE
C6 OLEFINS
2,3 DIMETHYLHEXANE
2,2-DIMETHYLBUTANE
CAS NUMBER
124185
1120214
287923
78795
592416
108087
110827
540841
565753
112403
80568
127913
629505
629594
629629
108872
96377
591764
111660
124118
922612
693890
110838
565593
79298
592132
760214
107006
503173
625274
590738
1678917
75832
D-23
-------
TABLE D-2. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
68.11
84.18
98.18
100.20
114.23
114.23
114.23
96.17
32.04
46.07
60.10
60.09
74.12
74.12
118.17
74.12
76.11
90.12
162.26
104.15
74.12
100.16
130.23
88.15
116.18
90.12
88.15
116.20
158.32
144.26
130.26
120.15
130.26
162.23
46.07
74.12
106.14
61.09
76.11
62.07
118.18
130.23
4
SAROAD
NUMBER
43292
43293
43294
43295
43296
43297
43298
43299
43301
43302
43303
43304
43305
43306
43308
43309
43310
43311
43312
43313
43314
43317
43318
43319
43320
43322
43330
43331
43332
43333
43334
43335
43336
43337
43350
43351
43367
43368
43369
43370
43371
43372
SPECIES NAME CAS NUMBER
CYCLOPENTENE 142290
4-METHYL-T-2-PENTENE 27236460
C7 OLEFINS
3-METHYLHEXANE 589344
2-METHYLHEPTANE 592278
4-METHYLHEPTANE 589537
3-METHYLHEPTANE
1-METHYLCYCLOHEXENE
METHYL ALCOHOL 67561
ETHYL ALCOHOL 64175
N-PROPYL ALCOHOL 71238
ISO-PROPYL ALCOHOL 67630
N-BUTYL ALCOHOL 71363
ISOBUTYL ALCOHOL 78831
BUTYL CELLOSOLVE 111762
TERT-BUTYL ALCOHOL 75650
METHYL CELLOSOLVE 109864
CELLOSOLVE 110805
2-(2-BUTOXYETHOXY)-ETHANOL 112345
l-ETHOXY-2-PROPANOL
S-BUTYL ALCOHOL 78922
CYCLOHEXANOL 108930
2-ETHYL HEXANOL 104767
PENTANOL 71410
DIACETONE ALCOHOL 123422
1,4 BUTANEDIOL 110634
ISOAMYL ALCOHOL 123513
DIMETHYLPENTANOL 10143234
DIMETHYLOCTANOL 106218
DIMETHYLHEPTANOL
METHYLHEPTANOL
METHOXYETHOXYETHANOL
OCTANOL
BUTOXYETHOXYETHANOL 112345
DIMETHYLETHER 115106
ETHYL ETHER 60297
GLYCOL ETHER 111466
GLYCOL
PROPYLENE GLYCOL 57556
ETHYLENE GLYCOL 107211
HEXYLENE GLYCOL 107415
DIBUTYL ETHER 142961
D-24
-------
TABLE D-2. (Continued)
Page No. 5
10/11/89
MOLECULAR SAROAD
WEIGHT NUMBER
106.12
134.18
150.17
88.15
134.18
120.15
162.23
92.09
200.00
128.19
96.14
112.17
152.24
142.24
86.13
46.03
60.05
74.08
72.06
256.43
146.14
256.48
60.05
74.08
88.10
102.15
116.16
86.09
100.11
128.17
100.13
102.13
116.16
73.09
144.21
132.16
86.09
270.46
242.41
298.52
76.11
218.24
43373
43374
43375
43376
43377
43378
43379
43380
43381
43391
43392
43395
43396
43397
43399
43403
43404
43405
43407
43408
43409
43410
43430
43432
43433
43434
43435
43437
43438
43440
43441
43444
43446
43450
43451
43452
43453
43454
43455
43456
43457
43458
SPECIES NAME
DIETHYLENE GLYCOL
DIPROPYLENE GLYCOL
TRIETHYLENE GLYCOL
METHYL T-BUTYL ETHER
CARBITOL
METHYL CARBITOL
BUTYL CARBITOL
GLYCEROL
POLYETHYLENE GLYCOL
2-BUTYLTETRAHYDROFURAN
ETHYLFURAN
C7H120
C10H160
TRIMETHYLCYCLOHEXANOL
C5H100
FORMIC ACID
ACETIC ACID
PROPIONIC ACID
ACRYLIC ACID
PALMITIC ACID
ADIPIC ACID
HEXADECANOIC ACID
METHYL FORMATE
METHYLACETATE
ETHYL ACETATE
N-PROPYL ACETATE
N-BUTYL ACETATE
METHYL ACRYLATE
ETHYL ACRYLATE
BUTYL ACRYLATE
METHYL METHACRYLATE
ISOPROPYL ACETATE
ISOBUTYL ACETATE
DIMETHYL FORMAMIDE
ISOBUTYL ISOBUTYRATE
CELLOSOLVE ACETATE
VINYL ACETATE
METHYL PALMITATE
METHYL MYRISTATE
METHYL STEARATE
METHYLAL
SUBSTITUTED C9 ESTER (C12)
CAS NUMBER
111466
106627
112276
628284
111900
111773
112345
56815
25322683
64186
64197
79094
79107
57103
124049
57103
107313
79209
141786
109604
138227
96333
140885
141322
80626
108214
110190
68122
297858
111159
108054
112390
124107
112618
109875
D-25
-------
TABLE D-2. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
130.19
214.35
228.37
242.40
256.43
270.45
326.56
340.59
154.26
128.19
220.26
214.35
118.00
128.21
144.24
100.13
144.22
174.20
160.17
30.03
44.05
58.08
56.07
72.12
72.11
100.16
58.04
72.07
70.09
72.12
58.08
72.10
100.16
100.16
98.15
114.21
114.19
98.14
126.20
142.24
140.22
116.00
6
SAROAD
NUMBER
43459
43460
43461
43462
43463
43464
43465
43466
43467
43468
43469
43470
43471
43472
43473
43474
43475
43476
43477
43502
43503
43504
43505
43510
43511
43512
43513
43514
43515
43520
43551
43552
43559
43560
43561
43562
43563
43565
43566
43567
43568
43569
SPECIES NAME CAS NUMBER
C5 ESTER
METHYL Cll ESTER
METHYL C12 ESTER
METHYL C13 ESTER
METHYL C14 ESTER
METHYL C15 ESTER
METHYL C19 ESTER
METHYL C20 ESTER
C4 SUBSTITUTED CYCLOHEXANONE
ISOBUTYL ACRYLATE 106638
BUTOXYETHOXYETHANOL ACETATE 124174
METHYL DODECANOATE 111820
DIMETHYLBUTANEDIOATE
BUTOXYBUTENE
ETHYLHEXANOATE
METHYLMETHYLPROPENOATE
METHYLETHYLPENTANOATE
DIMETHYLHEXANEDIOATE
DIMETHYLPENTANEDIOATE
FORMALDEHYDE 50000
ACETALDEHYDE 75070
PROPIONALDEHYDE 123386
ACROLEIN 107028
BUTYRALDEHYDE 123728
ISOBUTYRALDEHYDE 78842
HEXANAL 66251
6LYOXAL 107222
METHYL GLYOXAL 78988
CROTONALDEHYDE 123739
TOTAL C2-C5 ALDEHYDES
ACETONE 67641
METHYL ETHYL KETONE 78933
METHYL BUTYL KETONE 591786
METHYL ISOBUTYL KETONE 108101
CYCLOHEXANONE 108941
METHYL AMYL KETONE 110430
2-METHYL-3-HEXANONE 7379126
DIMETHYLCYCLOBUTANONE
TRIMETHYLCYCLOPENTANONE
TETRAMETHYLPENTANONE
NONENONE
METHOXYMETHYLBUTANONE
D-26
-------
TABLE D-2. (Continued)
Page No. 7
10/11/89
MOLECULAR SAROAD
WEIGHT NUMBER
72.10
44.05
58.08
98.06
102.09
86.00
53.06
45.09
59.11
116.20
61.08
45.08
113.16
59.11
50.49
84.94
119.39
153.84
173.85
137.38
64.52
133.42
99.00
165.83
133.42
187.38
92.00
120.91
131.40
92.57
148.68
187.88
112.99
88.01
86.47
170.92
154.47
138.01
70.01
104.46
62.50
88.54
43570
43601
43602
43603
43604
43650
43704
43721
43740
43776
43777
43778
43779
43780
43801
43802
43803
43804
43805
43811
43812
43814
43815
43817
43820
43821
43822
43823
43824
43835
43836
43837
43838
43839
43840
43841
43842
43843
43844
43845
43860
43862
SPECIES NAME
ALKENE KETONE
ETHYLENE OXIDE
PROPYLENE OXIDE
MALEIC ANHYDRIDE
ACETIC ANHYDRIDE
OXYGENATES
ACRYLONITRILE
ETHYLAMINE
TRIMETHYLAMINE
HEXAMETHYLENEDIAMINE
ETHANOLAMINE
ETHYLENEAMINES
CAPROLACTAM
DIMETHYL ALKYL AMINES
METHYL CHLORIDE
DICHLOROMETHANE
CHLOROFORM
CARBON TETRACHLORIDE
METHYLENE BROMIDE
TRICHLOROFLUOROMETHANE
ETHYL CHLORIDE
1,1,1-TRICHLOROETHANE
ETHYLENE DICHLORIDE
PERCHLOROETHYLENE
1,1,2-TRICHLOROETHANE
TRICHLOROTRIFLUOROETHANE
TRIMETHYLFLUOROSILANE
DICHLORODIFLUOROMETHANE
TRICHLOROETHYLENE
1-CHLOROBUTANE
3-(CHLOROMETHYL)-HEPTANE
ETHYLENE DIBROMIDE
PROPYLENE DICHLORIDE
TETRAFLUOROMETHANE
CHLORODIFLUOROMETHANE
DICHLOROTETRAFLUORETHANE
CHLOROPENTAFLUOROETHANE
HEXAFLUOROETHANE
TRIFLUOROMETHANE
CHLOROTRIFLUOROMETHANE
VINYL CHLORIDE
CHLOROPRENE
CAS NUMBER
75218
75569
108316
108247
107131
75057
75503
124094
141435
105602
74873
75092
67663
56235
74953
75694
75003
71556
107062
127184
79005
76131
75718
79016
78864
106934
26638197
75730
75456
76142
76153
76164
75467
75729
75014
126998
D-27
-------
TABLE D-2. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
92.53
62.13
58.10
72.20
114.20
60.08
76.13
296.62
76.08
88.23
114.00
106.16
120.19
134.22
134.21
120.19
120.19
134.21
134.22
132.22
130.19
142.20
78.11
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.19
120.20
120.19
120.19
134.21
134.21
134.22
134.22
104.14
118.19
120.19
154.21
8
SAROAD
NUMBER
43863
43902
43910
43911
43912
43933
43934
43950
43951
43952
45101
45102
45104
45105
45106
45107
45108
45109
45110
45111
45112
45113
45201
45202
45203
45204
45205
45206
45207
45208
45209
45210
45211
45212
45215
45216
45217
45218
45220
45221
45225
45226
SPECIES NAME CAS NUMBER
EPICHLOROHYDRIN 106898
ETHYL MERCAPTAN 75081
2-ME-PROPANE 75285
2-ME-BUTANE 78784
2,2,4-TRIME-PENTANE 540841
CARBONYL SULFIDE 433581
CARBON SULFIDE 75150
OCTAMETHYLCYCLOTETRASILOXANE 556672
SILOXANE
TETRAMETHYLSILANE 75763
NAPHTHA 8030306
ISOMERS OF XYLENE 1330207
ISOMERS OF ETHYLTOLUENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF DIETHYLBENZENE
TRIMETHYLBENZENE 25551137
ISOMERS OF PROPYLBENZENE
C3/C4/C5 ALKYLBENZENES
CIO AROMATIC
C10H12
ISOMERS OF C10H10
C11H10
BENZENE 71432
TOLUENE 108883
ETHYLBENZENE 100414
0-XYLENE 95476
M-XYLENE 108383
P-XYLENE 106423
1,3,5-TRIMETHYLBENZENE 108678
1,2,4-TRIMETHYLBENZENE 95636
N-PROPYLBENZENE 103651
CUMENE (ISOPROPYL BENZENE) 98828
0-ETHYLTOLUENE 611143
M-ETHYLTOLUENE 620144
TERT-BUTYLBENZENE 98066
S-BUTYLBENZENE 135988
1,2 DIETHYLBENZENE 135013
M-DIETHYLBENZENE 141935
STYRENE 100425
METHYL STYRENE 25013154
1,2,3-TRIMETHYLBENZENE . 526738
BIPHENYL 92524
D-28
-------
TABLE D-2. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
168.24
132.21
130.20
238.37
148.25
182.27
210.32
134.21
162.28
134.22
120.19
132.20
132.20
134.22
134.22
148.24
146.25
162.27
160.26
176.30
146.23
94.11
220.36
150.22
150.22
164.25
122.16
136.19
136.19
170.22
230.00
122.13
166.14
178.23
194.19
194.19
278.35
250.30
178.23
264.32
390.56
312.39
9
SAROAD
NUMBER
45227
45228
45229
45230
45231
45232
45233
45235
45236
45237
45238
45241
45242
45243
45244
45245
45246
45247
45248
45249
45250
45300
45301
45302
45303
45304
45310
45311
45320
45330
45401
45402
45403
45404
45450
45451
45452
45454
45455
45456
45470
45477
SPECIES NAME
METHYL BIPHENYL
ETHYL STYRENE
DIVINYL BENZENE
DI(ETHYLPHENYL) ETHANE
PENTYL BENZENE
DIPHENYL ETHANE
ETHYL-PHENYL-PHENYL-ETHANE
BUTYL BENZENE
DIISOPROPYL BENZENE
1,2,3,4 TETRAMETHYLBENZENE
ETHYLTOLUENE
4-PHENYL-l-BUTENE
T-1-PHENYLBUTENE
ETHYLDIMETHYLBENZENE
TETRAMETHYLBENZENE
C5-ALKYLBENZENES
C5-ALKYLBENZENES (UNSAT.)
C6-ALKYLBENZENE
C4-ALKYLSTYRENES
C7-ALKYLBENZENE
C3-ALKYLSTYRENE
PHENOL
NONYLPHENOL
ETHYLDIMETHYLPHENOL
C4-ALKYLPHENOLS
C5-ALKYLPHENOLS
C8 PHENOLS
C9 PHENOLS
DIMETHYLBENZYLALCOHOL
BIPHENYLOL
XYLENE BASE ACIDS
BENZOIC ACID
TEREPHTHALIC ACID
DIMETHYLETHYLBENZOIC ACID
DIMETHYL TEREPHTHALATE
DIMETHYL PHTHALATE
DIBUTYL PHTHALATE
DIPROPYL PHTHALATE
BUTYL BENZOATE
BUTYLISOPROPYLPHTHALATE
DI-C8 ALKYL PHTHALATE
BUTYLBENZYLPHTHALATE
CAS NUMBER
1321740
103297
104518
488233
768569
108952
25154523
90437
65850
100210
120616
131113
84742
131168
136607
85687
D-29
-------
TABLE D-2. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
106.13
120.16
96.09
134.17
148.12
98.10
108.14
162.23
93.13
123.11
207.02
262.03
247.02
169.24
250.27
174.17
117.15
93.13
68.12
112.56
147.01
147.01
147.01
147.01
126.59
181.45
215.90
208.23
223.23
198.17
119.13
107.17
158.20
244.00
158.20
160.17
130.19
132.25
135.19
128.17
142.20
156.23
10
SAROAD
NUMBER
45501
45502
45503
45550
45601
45604
45605
45610
45701
45702
45703
45704
45705
45706
45730
45731
45732
45740
45750
45801
45805
45806
45807
45808
45810
45830
45831
46102
46103
46111
46112
46114
46115
46202
46203
46204
46210
46601
46602
46701
46702
46703
SPECIES NAME CAS NUMBER
BENZALDEHYDE 100527
P-TOLUALDEHYDE 104870
2-FURFURAL 98011
METHYLACETOPHENONE
PHTHALIC ANHYDRIDE 85449
FURFURYL ALCOHOL 98000
CRESOL 1319773
C11H140
ANILINE 62533
NITROBENZENE 98953
2,2 DICHLORONITROANILINE
BROMODINITROANILINE 1817738
BROMODINITROBENZENE
N-PHENYLANILINE
METHYLENE(b)4-PHENYLISOCYANATE 101688
TOLUENE DIISOCYANATE 58849
TOLUENEISOCYANIDE
TOTAL AROMATIC AMINES
PIPERYLENE 504609
CHLOROBENZENE 108907
0-DICHLOROBENZENE 95501
M-DICHLOROBENZENE 541731
P-DICHLOROBENZENE 106467
DICHLOROBENZENES 2531226
BENZYL CHLORIDE 100447
TRICHLOROBENZENES
TETRACHLOROBENZENES
ANTHRAQUINONE 84651
AMINOANTHRAQUINONE 82451
4,4-METHYLENE DIANILINE 101779
PHENYL ISOCYANATE 103719
4-METHYLANILINE 100618
DIMETHYLNAPHTHYRIDINE
OCTAHYDROINDENES
METHOXYNAPHTHALENE
DIHYDROXYNAPTHALENEDIONE
CREOSOTE 8001589
TETRAMETHYLTHIOUREA 2782914
BENZOTHIAZOLE 95169
NAPTHALENE 91123
METHYL NAPHTHALENES
DIMETHYL NAPTHALENE 28804888
D-30
-------
TABLE D-2. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
204.27
152.20
154.21
166.22
178.23
178.23
202.26
146.23
116.16
202.26
252.32
228.29
228.30
252.32
252.32
252.32
276.34
276.34
278.35
252.32
252.32
276.34
300.36
192.26
192.26
158.24
206.28
247.36
190.25
216.29
226.28
228.30
242.33
242.33
242.33
256.35
230.31
256.34
252.32
278.35
278.36
302.38
11
SAROAD
NUMBER
46704
46705
46706
46707
46708
46709
46710
46711
46712
46713
46714
46715
46716
46717
46718
46719
46720
46721
46722
46723
46724
46725
46726
46727
46728
46729
46730
46731
46732
46733
46734
46735
46736
46737
46738
46739
46740
46741
46742
46743
46744
46745
SPECIES NAME CAS NUMBER
PHENYLNAPHTHALENES
ACENAPHTHYLENE 208968
ACENAPHTHENE 83329
FLUORENE 86737
PHENANTHRENE 85018
ANTHRACENE 120127
FLUORANTHENE 206440
C2 ALKYL INDAN
INDENE 95136
PYRENE 129000
BENZO(g,h,i) FLUORANTHENE
CHRYSENE 218019
BENZO (a) ANTHRACENE 56553
BENZO (b) FLUORANTHENE 205992
BENZO (k) FLUORANTHENE 207089
BENZO (a) PYRENE 50328
INDENO(l,2,3-cd) PYRENE 193395
BENZO (g,h,i) PERYLENE 191242
DIBENZO(a,h) ANTHRACENE 53703
PERYLENE 198550
BENZO (e) PYRENE 192972
ANTHANTHRENE 191264
CORONENE 191071
METHYL-ANTHRACENES
METHYL-PHENANTHRENES
C2-ALKYL-ANTHRACENES
C2-ALKYL-PHENANTHRENES
CYCLOPENTA-ANTHRACENES
CYCLOPENTA-PHENANTHRENES
METHYL-FLUORANTHENES
CYCLOPENTA(c,d)PYRENE 27208373
BENZO(c)PHENANTHRENE 195197
METHYL-BENZANTHRACENES
METHYL-BENZPHENANTHRENES
METHYL-CHRYSENES
C2-ALKYL-BENZANTHRACENES
C2-ALKYL-BENZOPHENANTHRENES
C2-ALKYL-CHRYSENES
BENZOPYRENES
DIBENZANTHRACENES
DIBENZPHENANTHRENES
DIBENZOPYRENES
D-31
-------
. TABLE D-2. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
156.23
132.21
152.28
144.22
146.23
130.19
144.22
138.25
146.23
160.26
168.32
128.25
128.26
128.26
128.26
128.26
84.16
128.26
142.29
106.16
54.09
112.21
140.27
128.26
128.26
127.25
222.47
296.60
58.12
56.10
70.13
68.12
84.16
86.17
80.14
100.20
98.18
226.45
240.46
154.30
138.25
126.24
12
SAROAD
NUMBER
46746
46747
46748
46749
46750
46751
46752
46753
46754
46755
90001
90002
90003
90004
90005
90006
90007
90008
90009
90010
90011
90013
90014
90015
90016
90017
90019
90020
90021
90022
90023
90024
90025
90026
90027
90028
90029
90030
90031
90032
90033
90034
SPECIES NAME
C2-ALKYLNAPHTHALENE
METHYLINDANS
METHYLDECALINS
METHYLDIHYDRONAPHTHALENE
DIMETHYLINDANS
DIHYDRONAPTHALENE
DIMETHYLINDENE
DECALINS
ETHYLINDAN
TRIMETHYLINDAN
DODECENE
2,3,5-TRIMETHYLHEXANE
2,4 DIMETHYLHEPTANE
3,5 DIMETHYLHEPTANE
2,5 DIMETHYLHEPTANE
2,3 DIMETHYLHEPTANE
4-METHYL-l-PENTENE
2-METHYLOCTANE
2,4,5-TRIMETHYLHEPTANE
M-XYLENE AND P-XYLENE
METHYLALLENE
C-2-OCTENE
1-DECENE
3-METHYLOCTANE
4-METHYLOCTANE
METHYLCYCLOOCTANE
C6H1803SI3
C8H2404SI4
METHYLPROPANE
METHYLPROPENE
METHYLBUTENE
METHYLBUTADIENE
METHYLPENTENES
METHYLPENTANE
METHYLCYCLOPENTADIENE
METHYLHEXANE
METHYLHEXENES
HEXADECANE
N-HEPTADECANE
1-UNDECENE
CYCLOPENTYLCYCLOPENTANE
T-2-NONENE
CAS NUMBER
91178
112414
691372
8720509
544763
629787
821954
6434782
D-32
-------
TABLE D-2. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
70.14
68.12
82.15
112.22
96.17
100.20
94.15
84.16
114.19
110.20
114.23
96.17
142.28
156.32
170.34
136.24
136.24
136.24
136.24
66.10
154.29
84.16
98.18
96.14
110.17
86.18
84.16
100.20
98.19
98.19
96.17
124.23
114.23
110.20
140.26
142.28
184.36
140.27
140.27
170.34
140.27
156.31
13
SAROAD
NUMBER
90035
90036
90037
90038
90039
90040
90041
90042
90043
90044
90045
90046
90047
90048
90049
90050
90051
90052
90053
90054
90055
90056
90057
90058
90059
90060
90061
90062
90063
90064
90065
90066
90067
90068
90069
90070
90071
90072
90073
90074
90075
90076
SPECIES NAME CAS NUMBER
N-PENTENE 25377724
PENTYNE
HEXYNE
CIS-1,4 DIMETHYLCYCLOHEXANE 624293
METHYLHEXADIENE
3,3 DIMETHYLPENTANE 562492
METHYLCYCLOHEXADIENE 4313579
T-3-HEXENE 13269528
METHYLHEXANAL
METHYLHEPTYNE
METHYLHEPTANE
METHYLCYCLOHEXENE
METHYLNONANE
METHYLDECANES
METHYLUNDECANE
CAMPHENE 5794036
MYRCENE 123353
B-PHELLANDRENE
D-LIMONENE 5989275
PENTENYNE
PENTYLCYCLOHEXANE
HEXENE
1-HEPTENE 592767
HEXADIENAL 142836
HEPTADIENAL 5910859
DIMETHYLBUTANE 79298
DIMETHYLBUTENE
DIMETHYLPENTANE
DIMETHYLPENTENE
DIMETHYLCYCLOPENTANE
DIMETHYLCYCLOPENTENES
NONADIENE
DIMETHYLHEXANES
DIMETHYLHEXADIENE
DIMETHYLETHYLCYCLOHEXANE
DIMETHYLOCTANES
DIMETHYLUNDECANE
METHYLPROPYLCYCLOHEXANES
METHYLISOPROPYLCYCLOHEXANE
DIMETHYLDECANE
ETHYLOCTENE
DIMETHYLNONANES
D-33
-------
TABLE D-2. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
142.29
98.19
96.17
112.21
114.23
128.26
126.24
128.26
156.31
223.42
128.26
140.27
154.29
110.19
114.22
110.20
142.29
126.24
156.31
184.36
126.24
108.19
126.24
140.27
184.36
68.13
128.26
124.33
140.26
154.29
184.36
140.27
111.20
140.27
138.25
152.00
168.32
128.26
113.22
136.24
225.20
130.19
14
SAROAD
NUMBER
90077
90078
90079
90080
90081
90082
90083
90084
90085
90086
90087
90089
90090
90091
90092
90093
90094
90095
90096
90097
90098
90099
90100
90101
90102
90103
90104
90105
90106
90107
90108
90109
90110
90111
90112
90113
90114
90115
90116
90117
90118
90119
SPECIES NAME
ETHYLOCTANE
ETHYLPENTENE
ETHYLCYCLOPENTENE
ETHYLMETHYLCYCLOPENTANE
ETHYLHEXANE
ETHYLMETHYLHEXANE
ETHYLMETHYLCYCLOHEXANES
ETHYLHEPTANE
ETHYLMETHYLOCTANE
ETHYLBICYCLOHEPTANE
ETHYLDIMETHYLPENTANE
ETHYLDIMETHYLCYCLOHEXANE
ETHYLPROPYLCYCLOHEXANES
TETRAMETHYLCYCLOBUTENE
TRIMETHYLPENTANE
TRIMETHYLPENTADIENE
TRIMETHYLHEPTANES
TRIMETHYLHEXENE
TRIMETHYLOCTANES
TRIMETHYLDECANE
TETRAMETHYLCYCLOPENTANE
OCTATRIENE
NONENE
BUTYLCYCLOHEXANE
METHYLPROPYLNONANE
PENTADIENE
METHYLOCTANES
PROPENYLCYCLOHEXANE
METHYLNONENE
METHYLDECENE
METHYLDODECANE
PROPYLHEPTENES
DIETHYLMETHYLCYCLOHEXANES
ISOPROPYLMETHYLCYCLOHEXANE
DIMETHYLOCTYNE
PENTYLIDENECYCLOHEXANE
DIMETHYLBUTYLCYCLOHEXANE
TRIMETHYLHEXANES
ISOPROPYLCYCLOPENTANE
LIMONENE
OCTAHYDROPENTALENE
METHYLINDENE
CAS NUMBER
1678939
5989275
D-34
-------
TABLE D-2. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
126.24
142.22
142.28
168.32
140.27
296.59
282.56
268.53
126.25
172.35
204.36
128.26
84.16
84.16
84.16
98.19
118.18
112.22
86.14
98.19
112.16
112.24
126.27
140.27
154.30
126.24
182.35
112.22
128.26
88.15
16.04
28.55
42.08
57.08
71.00
79.12
93.18
112.00
126.00
140.00
154.00
168.00
15
SAROAD
NUMBER
90120
90121
90122
90123
90124
90125
90126
90127
90128
90129
90130
98033
98034
98035
98040
98041
98044
98054
98056
98057
98058
98059
98060
98062
98063
98082
98083
98090
98091
98106
99101
99102
99103
99104
99105
99106
99107
99108
99109
99110
99111
99112
SPECIES NAME
PROPYLCYCLOHEXANE
METHYLETHYLHEPTANE
TETRAMETHYLHEXANE
TRIMETHYLNONENE
DIMETHYLOCTENES
HENEICOSANE
EICOSANE
NONADECANE
ISOPROPYLCYCLOHEXANE
ETHYLDIMETHYLOCTANE
CARYOPHYLLENE
2,2,5-TRIMETHYLHEXANE
T-2-HEXENE
C-2-HEXENE
2-METHYL-l-PENTENE
3-HEPTENE
INDANE
2,4,4-TRIMETHYL-l-PENTENE
ISOVALERALDEHYDE
ETHYLCYCLOPENTANE
TRIMETHYLCYCLOPENTANE
DIMETHYLCYCLOHEXANE
TRIMETHYLCYCLOHEXANES
DIETHYLCYCLOHEXANE
N-PENTYLCYCLOHEXANE
ETHYLHEPTENE
TRIMETHYLDECENE
METHYLHEPTENE
DIMETHYLHEPTANES
ETHYLISOPROPYL ETHER
C-l COMPOUNDS
C-2 COMPOUNDS
C-3 COMPOUNDS
C-4 COMPOUNDS
C-5 COMPOUNDS
C-6 COMPOUNDS
C-7 COMPOUNDS
C-8 COMPOUNDS
C-9 COMPOUNDS
C-10 COMPOUNDS
C-ll COMPOUNDS
C-l2 COMPOUNDS
CAS NUMBER
629947
112958
87445
40504557
592438
763291
496117
107391
590863
1640897
3073663
D-35
-------
TABLE D-2. (Continued)
Page No.
10/11/89
MOLECULAR
WEIGHT
182.00
196.00
210.00
224.00
238.00
252.00
266.00
280.00
294.00
308.00
322.00
336.00
350.00
364.00
378.00
392.00
406.00
420.00
434.00
448.00
462.00
476.00
490.00
504.00
518.00
532.00
546.00
560.00
574.00
588.00
602.00
142.28
167.31
142.29
142.29
120.19
120.19
134.22
134.22
134.22
156.32
32.04
16
SAROAD
NUMBER
99113
99114
99115
99116
99117
99118
99119
99120
99121
99122
99123
99124
99125
99126
99127
99128
99129
99130
99131
99132
99133
99134
99135
99136
99137
99138
99139
99140
99141
99142
99143
99908
99909
99910
99911
99912
99913
99915
99916
99917
99918
99933
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
2
2
2
3
1
1
I:
1
1
2
D!
SPECIES NAME
C-13 COMPOUNDS
C-14 COMPOUNDS
C-15 COMPOUNDS
C-16 COMPOUNDS
C-17 COMPOUNDS
C-18 COMPOUNDS
C-19 COMPOUNDS
C-20 COMPOUNDS
C-21 COMPOUNDS
C-22 COMPOUNDS
C-23 COMPOUNDS
C-24 COMPOUNDS
C-25 COMPOUNDS
C-26 COMPOUNDS
C-27 COMPOUNDS
C-28 COMPOUNDS
C-29 COMPOUNDS
C-30 COMPOUNDS
C-31 COMPOUNDS
C-32 COMPOUNDS
C-33 COMPOUNDS
C-34 COMPOUNDS
C-35 COMPOUNDS
C-36 COMPOUNDS
C-37 COMPOUNDS
C-38 COMPOUNDS
C-39 COMPOUNDS
C-40 COMPOUNDS
COMPOUNDS
C-42 COMPOUNDS
C-43 COMPOUNDS
2,3 DIMETHYLOCTANE
2,6 DIMETHYLOCTANE
2,4 DIMETHYLOCTANE
3,4 DIMETHYLOCTANE
l-METHYL-3-ETHYLBENZENE
l-METHYL-2-ETHYLBENZENE
ISOBUTYLBENZENE
1-METHYL-3N-PROPYLBENZENE
l-METHYL-3-ISOPROPYLBENZENE
2-METHYLDECANE
DENATURANT
CAS NUMBER
538932
D-36
-------
TABLE D-2. (Continued)
Page No. 17
10/11/89
MOLECULAR SAROAD
WEIGHT NUMBER SPECIES NAME CAS NUMBER
86.00 99999 UNIDENTIFIED
D-37
-------
D-38
-------
APPENDIX E
CHEMICAL SPECIES CLASSIFICATION
-------
E-2
-------
APPENDIX E
CHEMICAL SPECIES CLASSIFICATION
This appendix contains two examples of chemical species classification
schemes (Tables E-l and E-2). Since there are several different schemes used
based on specific modeling needs, chemical species classification data are not
included in the profiles in the text.
E-3
-------
E-4
-------
TABLE E-l. HYDROCARBON SPECIES/CLASS ASSIGNMENTS
FOR 1980 NAPAP INVENTORY VERSION 5.2
HYDROCARBON SPECIES
UNIDENTIFIED HYDROCARBONS
ISOMERS OF HEXANE
ISOMERS OF HEPIANE
ISOMERS OF OCTANE
ISOMERS OF KONANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
ISOHERS OF TRIDECANE
ISOMERS OF DODECANE
ISOMERS OF TETRADECANE
ISOKERS OF PENTADECANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
MINERAL SPIRITS
LACTOL SPIRITS
ISOMERS OF BOTENE
ISOKERS OF PENTENE
ISOMERS OF PENIANE
TERPENES
METHANE
ETHANE
ETHYLENE
PROPANE
PROPYLENE
ACETYLENE
CYCLOPROPANE
PROPADIENE
METHYLACETYLENE
N-BUTANE
BOTENE
ISOBUTANE
ISOBUTYLENE
1,3-BUTADIENE
ETHYLACETYLENE
N-PENTANE
ISOPENIANE
3-METHYL-l-BOTENE
1-PENTENE
CIS, 2-PENTENE
2-METHYL,2-BUTENE
N-HEXANE
N-HEPTANE
N-OCTANE
N-NONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
1-HEXENE
2,4, DIMETHYL PENIANE
SAROAD
CODE
43000
43105
43106
43107
43108
43109
43110
43111
43112
43113
43114
43115
43116
43117
43118
43119
43120
43121
43122
43123
43201
43202
43203
43204
43205
43206
43207
43208
43209
43212
43213
43214
43215
43218
43219
43220
43221
43223
43224
43227
43228
43231
43232
43233
43235
43238
43241
43242
43245
43247
5.2
CLASS
«««**««
09
09
09
09
09
09
09
09
09
09
09
09
09
09
09
09
15
15
09
15
01
02
10
03
11
09
09
15
15
04
15
05
13
15
15
07
08
15
15
15
15
09
09
09
09
09
09
09
15
09
E-5
-------
TABLE E-l. (Continued)
HYDROCARBON SPECIES
CYCLOHEXAHE
H-DODECANE
N-TRIDECAHE
N-TEIRADECANE
N-PENIADECANE
KETHYLCYCLOHEXANE
HETHYLCYCLOPENIANE
1-HEPTENE
1-OCTEHE
3,3 DIMETHYL, 1-PENIERE
N-HEXADECANE
N-HEFIADECANE
N-OCIADECAHE
N-HOHADECANE
H-EICOSANE
H-HENEICOSANE
K-DOCOSANE
C8 OLUTN UNK
METHYL ALCOHOL
ETHYL ALCOHOL
N-PROPYL ALCOHOL
ISOPROFYL ALCOHOL
H-BUTYL ALCOHOL
ISOBUIYL ALCOHOL
BUTYL CELLOSOLVE
TERT-BUTYL ALCOHOL
METHYL CELLOSOLVE
CELLOSOLVE
DIACETONE ALCOHOL
ETHYL t'UiLK
GLYCOL ETHER
GLYCOL
PROPYLENE GLYCOL
ETHYLEHE GLYCOL
TETRAHYDROFURAH
ACETIC ACID
METHYL ACETATE
ETHYL ACETATE
FROFYL ACETATE
N-BUTYL ACETATE
ETHYL ACRYLATE
CELLOSOLVE ACETATE
ISOPROPYL ACETATE
METHYL AKYL ACETATE
ISOBUTYL ACETATE
DIKEIHYLFORMAHIDE
ISOBUTYL ISOBUTYRATE
2-ETHOXYETHYL ACETATE
FORMALDEHYDE
ACETALDEHYDE
SAROAD
CODE
U3ZU8
43255
43258
43259
43260
43261
43262
43264
43265
43268
43281
43282
43283
43284
43285
43286
43287
43290
43301
43302
43303
43304
43305
43306
43308
43309
43310
43311
43320
43351
43367
43368
43369
43370
43390
43404
43432
43433
43434
43435
43438
43443
43444
43445
43446
43450
43451
43452
43502
43503
5.2
CLASS
09
09
09
09
09
09
09
15
15
it
09
09
09
09
09
09
09
15
09
' 09
09
09
09
09
09
09
09
09
26
09
09
09
09
09
09
28
29
29
29
29
15
09
09
09
09
24
09
09
21
22
E-6
-------
TABLE E-l. (Continued)
HYDROCARBON SPECIES
BUTYRALDEHYDE
ALDEHYDE
ACETONE
METHYL ETHYL KETONE
METHYL N-BUTYL KETONE
METHYL ISOBUTYL KETONE
CYCLOHEXANONE
ETHYLENE OXIDE
PROPYLENE OXIDE
ACETONITRILE
ACRYLONITRILE
METHYLAHINE
ETHYLAMINE
TRIMETHYLAMIIIE
METHYL CHLORIDE
DICHLOROMETHANE
CHLOROFORM
CARBON TETRABROMIDE
TRICHLORO-FLTOROHETHANE
ETHYL CHLORIDE
1,1,DICHLOROETHANE
1,1,1,-TRICHLOROETHANE
ETHYLENE DICHLORIDE
PERCHLOROETHYLENE
METHYLENE BROMIDE
1,1,2-TRICHLOROETHANE
TRICHLOROTRIFLUOROETHANE
TRIMETHYLFLUOROSILANE
DICHLORODIFLUOROMETHANE
TRICHLOROETHYLENE
VINYL CHLORIDE
PRIM. & SEC-ALKYL BENZENES
NAPHTHA
ISOMERS OF XYLENE
DIMETHYLETHYLBEN2EHE
ISOMERS OF ETHYLTOLUENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF DIETHYLBENZEJO;
ISOMERS OF TRIMETHYLBENZEHE
ISOMERS OF PROPYLBENZENE
BENZENE
TOLUENE
ETHYLBENZENE
ORTHO XYLENE
1,3 DIMETHYLBENZENE
1,3,5-TRIMETHYLBENZENE
M-ETHYLTOLUENE
N-BUTYLBENZENE
TERT-BUTYLBENZENE
SEC-BUTYLBENZENE
SAROAD
CODE
43510
43513
43SS1
43552
43559
43560
43561
43601
43602
43702
43704
43720
43721
43740
43801
43802
43803
43807
43811
43812
43813
43814
43815
43817
43819
43820
43821
43822
43823
43824
43860
45100
45101
45102
45103
45104
45105
45106
45107
45108
45201
45202
45203
45204
45205
45207
45212
45214
45215
45216
5.2
CLASS
24
24
25
26
26
26
26
09
09
15
15
09
09
09
09
09
09
09
09
09
09
09
09
15
09
09
09
09
09
15
15
20
09
18
20
20
20
20
20
20
16
17
19
18
18
20
20
20
20
20
E-7
-------
TABLE E-l. (Continued)
HYDROCARBON SPECIES
STYRDCE
A-HEnffLSKHDCE
1 , 2 , 3 -IKDCCXHILBIMZBS
ISOKERS 07 TMHETHYLMJCDDt
mzm
FHZMOLS
XYLEHE BASE AGIOS
CHLOBOMHZnO
1,4 DIOXAKE
coot
!
45220
45221
45225
45230
45232
45233
45300
45401
45*01
4*201
5.2
cuts
20
20
20
20
20
20
20
29
20
09
REACTIVITY CLASSES FOR 1980 NAPAP INVENTORY VERSION 5.2
Class Number Class Name Class SAROAD Code
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
2,3-DIMETHYLBUTANE
PENTANE
ISO-PENTANE
OTHER ALKANES
ETHYLENE
PROPYLENE
Not Used
ISO-BUTENE
TRANS-2-BUTENE
OTHER ALKENES
BENZENE
TOLUENE
XYLENES
ETHYL BENZENES
OTHER AROMATICS
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
OTHER ALDEHYDES
ACETONE
OTHER KETONES
FORMIC ACID
ACETIC ACID
OTHER ORGANIC ACIDS
Not Used
43201
43202
43204
43212
43214
43244
43220
43221
43299
43203
43205
43215
43216
43298
45201
45202
45102
45203
45999
43502
43503
43504
43599
43551
43598
43403
43404
43499
E-8
-------
TABLE E-2. HYDROCARBON SPECIES/CLASS ASSIGNMENTS, 1980
NAPAP EMISSIONS INVENTORY VERSION 5.3
HYDROCARBON SPECIES
SAROAD
5.3
CLASS:
5.3 CARBON NUMBER/CLASS ASSIGNMENTS
345678
10
UNIDENTIFIED HYDROCARBONS 43000
ISOMERS OF HEXANE 43105
ISOMERS OF HEPTANE 43106
ISOMERS OF OCTANE 43107
ISOMERS OF NONANE 43108
ISOMERS OF DECANE 43109
ISOMERS OF UNDECANE 43110
ISOMERS OF TRIDECANE 43111
ISOMERS OF DODECANE 43112
ISOMERS OF TETRADECANE 43113
ISOMERS OF PENTADECANE 43114
C-7 CYCLOPARAFFINS 43115
C-8 CYCLOPARAFFINS 43116
C-9 CYCLOPARAFFINS 43117
MINERAL SPIRITS 43118
LACTOL SPIRITS 43119
ISOMERS OF BUTENE 43120
ISOMERS OF PENTENE 43121
ISOMERS OF PENTANE 43122
TERPENES 43123
METHANE 43201
ETHANE 43202
ETRYLENE 43203
PROPANE 43204
PROPYLENE 43205
ACETYLENE 43206
CYCLOPROPANE 43207
PROPADIENE 43208
METHYLACETYLENE 43209
N-BUIANE 43212
BUTENE 43213
ISOBUIANE 43214
ISOBUTYLENE 43215
1,3-BUTADIEKE 43218
ETHYLACETYLENE 43219
N-PENXANE 43220
ISOPENIANE 43221
3-METHYL-l-BUTENE 43223
1-FENTENE 43224
CIS, 2-PENTEKE 43227
2-METHYL,2-BUTENE 43228
N-HEXANE 43231
N-HEPTANE 43232
N-OCIANE 43233
N-NONANE 43235
N-DECANE 43238
N-UNDECANE 43241
CYCLOPENTANE 43242
1-HEXENE 43245
2,4, DIMETHYL PENTANE 43247
2
6
7
8
9
10
11
13
12
14
15
7
8
9
6
8
1
5
8
0.01
0.4
1.5
1
1
3
1.5
4
2
4
1
4
5
5
3
3
1
3
6
7
8
9
10
11
5
4
7
0.99
1 1
1 1
2
1.6
1.5
1
1.5
E-9
-------
TABLE E-2. (Continued)
HYDROCARBON SPECIES
CYCLOHEXAHE
N-DOOECAHE
N-TRIDECAHE
N-IETRADECAHE
H-PZMIADECAHE
KEXHYLCYCLOHEXAME
KEimcYCLOpEtrrANE
1-HEPTEKE
1-OCIEHE
3,3 DIMETHYL, l-PENTEHE
H-HEXADECAHE
N-HZPIADECAHE
H-OCTADECANE
H-MOKADECAKE
N-nCOSANE
H-HENEICOSANE
M-DOCOSAHK
CS ntinrnt UNK
KEIHYL ALCOHOL
ETHYL ALCOHOL
N-FROPYL ALCOHOL
ISOPROPYL ALCOHOL
H-NJIYL ALCOHOL
ISOBUIYL ALC080L
BUTYL CXLLOSOLVE
TEKr-BUTYL ALCOHOL
KEIHYL CELLOSOLVE
CELLOSOLVZ
DIACEIOHE ALCOHOL
ETHYL E3HEK
CLYCOL EfflER
GLYCOL
PROPYLEKE GLYCOL
EXHYLEHE GLYCOL
TETRAHYDROFURAB
ACEHC ACID
KEIHYL ACETATE
ETHYL ACETATE
PROPYL ACETATE
H-HITYL ACEIAIE
ETHYL ACKYLAIE
rrr.Tfljtoi.vr. ACETATE
ISOPROPYL ACEIAIE
KEIHYL AMYL ACEIAIE
ISOBUTYL ACEIAIE
DIMnHYUOKMAKIBE
ISOBUIYL ISOBOTIRAXE
2-EIBOXYEIHYL ACEIAIE
FORHALDEHYDE
ACdALDEHYDE
SAROAD
CODE
432b8
b3255
b3258
43259
43260
43261
43262
43264
43265
43268
43281
43282
43283
43284
43285
43286
43287
43290
43301
43302
43303
43304
43305
43306
43308
43309
43310
43311
43320
43351
43367
43368
43369
43370
43390
43404
43432
43433
43434
43435
43438
43443
43444
43445
43446
43450
43451
43452
43502
43503
5.3 5.3 CARBON NUMBER/CLASS ASSIQMEHIS
6
12
13
14
15
7
6
1 5
1 6
5
16
17
18
19
20
21
22
1 6
1
2
3
3
2 1
4
4 1
4
1 1
2 1
4 1
2 1
2
2
3
2
3 1
1 1
3
3 1
4 1
5 1
1 2
3 11
5
8
6
3
6 1
4 1
1
1
E-10
-------
TABLE E-2. (Continued)
HYDROCARBON SPECIES
BUTYRALDEHYDE
ALDEHYDE
ACETONE
METHYL ETHYL KETONE
METHYL N-BUTYL KETONE
MnHYL ISOBUTYL KETONE
CYOOHEXANONE
ETHYLENE OXIDE
PROPYLENE OXIDE
ACETONTTRILE
ACKYLOHTrRTLE
METHYUMINE
ETHYLAHINE
TRIMEIHYLAMINE
METHYL CHLORIDE
DICHLOROMETHANE
CHLOROFORM
CARBON TETRABROMIDE
TRICHLORO-FLUOROKETHANE
ETHYL CHLORIDE
1,1,DICHLOROETHANE
1,1,1,-TRICHLOROETHANE
ETHYLENE DICBLORIDE
PERCHLOROETHYLENE
METHYLEKE BROMIDE
1 , 1 ,2-TRICHLOROZ3HAKE
XRICHLOROTRIFLUOROETHAKE
TRIMETHYLFLUOROSILANE
DICHLORODIFLUOROKETHANE
TRICHLOROETHYLENE
VINYL CHLORIDE
PRIM. & SEC-ALKYL BENZENES
NAPHTHA
ISOMERS OF XYLENE
DIMETHYLETHYLBENZENE
ISOMERS OF ETHYLTOLUENE
ISOMERS OF BUTYLBEHZENE
ISOMERS OF DIETHYLBEKZEKE
ISOMERS OF TRXMETHTLBEHZERE
ISOMERS OF PROFYLBEHZENE
BENZENE
TOLUENE
ETHYLBENZEHE
ORTHO XYLENE
1,3 DMETHYLBENZENE
1,3,5-TRMEIHYLBENZENE
M-ETHYLTOLUENE
N-BUTYLBENZENE
TERT-BUTYLBENZENE
SEC-BUTYLBENZENE
SAROAD
CODE
43510
43513
43551
43552
43559
43560
43561
43601
43602
43702
43704
43720
43721
43740
43801
43802
43803
43807
43811
43812
43813
43814
43815
43817
43819
43820
43821
43822
43823
43824
43860
45100
45101
45102
45103
45104
45105
45106
45107
45108
45201
45202
45203
45204
45205
45207
45212
45214
45215
45216
5.3
CLASS: 1 2
2
6
3
4
6
6
7
1
2
1
1 1
1
3
3
8
2
1
3
2
1
2
1
1
1
1
1
3
5.3 CARBON NUMBER/CLASS ASSIGNMENTS
3456789 10
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
1
2
1
2
2
3
1
1
1
1
1
1
1
1
1
1
1
5
1
1
1
1
1
1
1 3
1
E-ll
-------
TABLE E-2. (Continued)
HYDROCARBON SPECIES
SXYKZHE
A-KEXERLSXXXm
1 f 2 , 3 "TXXHCDU U^HZJSU
ISGt^DtS tff XRIKmfflrTiB17
n ,,. .,.-___. ......_
TRI/UJKAALJCYL SXHZZXE
PHBtOLS
XYIZXE BASE ACIDS
CHLQRQftfidXX
1,4 DIOXAXE
SAXOAD
OOW
43220
45221
45223
3XE 45230
43233
43300
45401
45801
44201
S.3
cunt
am
5.3 cum rant/cuss ASSI
2343*7
10
1
1
1
1
REACTIVITY CLASSES FOR 1980 NAPAP INVENTORY VERSION 5.3
Class Number Class Name Class SAROAD Code
01
02
03
04
05
06
07
08
09
10
11-30
OLEFINS
PARAFFINS
TOLUENE
XYLENE
FORMALDEHYDE
OTHER ALDEHYDES
ETHYLENE
NON-REACTIVES
ISOPRENE
METHANE
Not Used
43298
43199
45202
45102
43502
43511
43203
43899
43243
43201
*The SAROAD codes listed here are different for some species from the codes
used in this document. Refer to Section 2.1 for the SAROAD codes used in
this document.
E-12
-------
APPENDIX F
DATA FILE DESCRIPTION
-------
F-2
-------
APPENDIX F
DATA FILE DESCRIPTION
The VOC Speciation Data Base consists of six working files. The content
of each file is as follows:
File
Content
V ASSIGN
SCC DATA
V PROFIL
V SPECIE
V FTNOTE
SCC number
Profile number
Notation of whether SCC assignment is
original or a surrogate
Notation of whether the profile is based
on test data
SCC assignment data quality rating
SCC number
Primary SCC name
Secondary SCC name
Tertiary SCC name
Quaternary SCC name
Area source code description
Emission factor units
Total suspended particles emission factor
Volatile organic compounds emission factor
Profile number
SAROAD number of each pollutant specie
Molecular weight of each pollutant specie
Identification of peaks for coeluting species
Logical flags to designate missing data in all
particle size ranges
Logical flag to designate status of profile
Calendar date profile was designated current
'Pollutant species name
Pollutant species SAROAD number
Pollutant species CAS number
Molecular weight of each pollutant specie
Profile number
Footnote indicators
Profile footnote
F-3
-------
File
Content
V COMMON
Profile number
Profile name
Profile data quality
Profile reference(s)
Comments describing the profile
Control device
Logical flag to designate profile status
Calendar date profile was designated current
F-4
-------
APPENDIX G
VOC SPECIATION TEST PROGRAM
-------
G-2
-------
APPENDIX G
VOC SPECIATION TEST PROGRAM
This appendix describes the VOC speciation testing efforts conducted as
part of the overall speciation program to develop original speciated data to
characterize high priority emission sources.
G.I SUMMARY
Source categories where the VOC impacts are the most significant were
selected for sampling: gasoline marketed, degreasing, drycleaning, autobody
repair, and graphic arts. Due to resource limitations, emphasis was placed on
area type emission sources which would not require ambient or stack sampling.
The selection of specific sites for sampling within each category simply
consisted of identifying major users/producers for each category. Samples
were collected in a number of ways. Some of the samples were obtained from
the producers through mail. In some cases, they were purchased from retail
outlets. In other cases, they were obtained directly from the users.
Sample preparation involved development of proportions for making
composite samples representative of a given category, from individual samples
collected from each category. This was based primarily on data gathered
through literature search, review of vendor literature, and vendor and trade
association contacts. Composite samples from each category were analyzed
using two analytical procedures. These procedures were similar to SW-846
Method 3810 "Headspace Method" and SW-846 Method 8270 "Gas Chromatography/Mass
Spectrometry for Semi-Volatile Organics." All analytical determinations were
performed using a combination of capillary gas chromatography with quadrupole
mass spectrometry.
Accurate quantitative determinations were made for compounds included in
the calibrations. In addition to these compounds, complete qualitative
analysis was performed for all samples using a computerized library search and
a skilled interpreter of mass spectral data. In order to determine the
relative weight percentages of compounds in a given sample, the values
G-3
-------
calculated accurately were integrated with the semi-quantitative values based
on the qualitative analysis described above. The total organic content of the
samples were then summed and each component was expressed as a percentage of
the whole, consistent with the current VOC species profile format. A
threshold level of 0.01 percent was used to include a compound in a profile.
The following sections discuss source category and site selection,
sampling and analytical procedures, results, and internal quality
assurance/quality control procedures in detail.
G.2 SELECTION OF SOURCE CATEGORIES AND SAMPLING SITES
G.2.1 Source Cateoorv Selection
To determine the source categories where the new and/or improved
profiles would have significant impacts, the following were reviewed:1'2
1980 VOC Species Data Manual,
1980 National and Precipitation Assessment Program (NAPAP)
Emissions Inventory, and
New profiles developed from literature review.
Based on this review, the following source categories were selected for this
sampling program:
gasoline marketed,
degreasing,
drycleaning,
autobody repair, and
graphic arts-printing.
Table G-l presents the Source Classification Codes (SCC's) and the
applicable National Emissions Data System (NEDS) area source codes for these
source categories. As shown in Table G-l, sampling in these categories would
result in speciation of approximately 2,232,000 tons/year of VOC emissions;
this is equivalent to about 10 percent of total national VOC emissions.3 Due
G-4
-------
to time and budget limitations, emphasis was placed on area type emission
sources which would not require ambient or stack sampling.
G.2.2 Selection of Sampling Sites
To characterize the five source categories selected for sampling,
samples from major users/producers in each category were collected and the
composition of potential VOC emissions associated with these products were
characterized by laboratory methods. It was assumed that composition of the
volatile portion of a product reflects the composition of VOC emissions from
operations where the product is used.
Sample acquisition involved clearly defining each of the five source
categories in terms of the products (i.e., types of solvents) used. Available
literature was consulted to determine the major users/producers and their
market share within the five categories. The major producers were solicited
for representative samples. An alternate approach for certain categories was
to purchase some of the products at local retailers once the products of
interest have been specified.
In order to select sites for the gasoline marketed source category, the
leading five oil companies in 1984 sales were identified from the "Basic
Petroleum Data Book."4 The five oil companies and corresponding local service
stations where samples were collected included the following:
1. Chevron (Gulf)
2. Standard of Indiana (Amoco)
3. Texaco
4. Shell
5. Exxon
The 1984 sales data presented for Chevron Corporation reflected the
acquisition of Gulf Corporation. No local Chevron stations could be found, so
only Gulf service stations were selected for collecting samples.
Degreasing and drycleaning operations use similar solvents and the
producers of solvents used in these operations are often the same for each
industry. The main type of solvent used in both industries that is not a pure
G-5
-------
TABLE 6-1. SOURCE CATEGORIES SELECTED FOR SAMPLING*
SCC/Area
Source Code
54
78,4-01-002
79
83
80
Description
Gasoline marketed
Degreasing
Dry clean ing
Autobody repair
Graphic arts-printing
National VOC
Emissions
(tons/yr)
966,000
607,000
300,000
183,000
176.000
2,232,000
% of National
VOC Emissions
4.2
2.6
1.3
0.8
0.8
9.7
'Source: Reference 3.
G-6
-------
compound is mineral spirits. Since evaporative emissions from a pure solvent
can be accurately assumed to be the compound comprising the solvent, mineral
spirits was the only solvent type which was investigated in this study. Major
producers of mineral spirits were identified through contacts with trade
associations and vendor literature review. As a result of these contacts, one
company provided a sample of their main mineral spirit product and another
company sent five of their mineral spirit products through the mail in 4-ounce
sample bottles with minimal headspace.
The main producers of automotive aftermarket paint (i.e., paint applied
after the car leaves the factory) were identified by review of vendor
literature and by talking with sales representatives. The main types of paint
used presently within the industry were identified along with their tradenames
for each main producer. Once the tradenames of the samples were established,
local paint distributors were contacted to see if they carried the product,
along with the compatible thinner. Paint distributors of DuPont, Sherwin-
Williams, and PPG (Ditzler) paints were selected. The types of paints and
thinners selected are as follows:
DuPont - "Centari," and "Lucite"
Sherwin-Williams - "Acrylyd," "Kern Transport," and Acrylic Enamel
PPG (Ditzler) - "Ditzco"
For the graphic arts industry, the main industry subcategories
identified from Reference 5 were:
1. Rotogravure
2. Lithography
3. Letter Press
4. Flexography
The main types of printed products (i.e., newspaper, magazine, etc.) made with
each of these printing processes were identified from the Printing Ink
Handbook.6 Local printers which use these processes were contacted and
G-7
-------
samples were obtained by mail or arrangements were made to pick up the ink
samp! es.
G.3 SAMPLING AND ANALYTICAL PROCEDURES
G.3.1 Sampling Procedures
Table G-2 presents an overview of the sample collection efforts
including information on the number and type of samples collected, the number
of participating companies, and how the samples were actually obtained.
When samples were obtained on a first hand basis by visiting sites, an
attempt was made to minimize VOC loss. The time the sample was exposed to the
open air was reduced as much as possible. Before taking gasoline samples,
approximately one gallon of gasoline was dispensed to purge the delivery hose.
This gasoline was not desirable because it was exposed to ambient summer
temperatures and may have lost the more volatile components. Gasoline samples
were collected in clean vials obtained from the Radian laboratory. As soon as
each gasoline sample was sealed and labeled, it was placed in a plastic bag
and put in an ice chest. The samples were then transported to the 4°C walk-in
freezer at the Radian laboratory.
One sample for the degreasing and drycleaning categories was obtained
directly from the producer. It was stored along with five other solvents
received by mail in the walk-in freezer.
Acquisition of autobody repair paint was a simple matter of purchasing
the desired paint and its compatible/recommended thinner at local paint
distributors. The paint which was in metal cans or plastic bottles, was then
transported to the walk-in freezer.
Most of the printing inks for the graphic arts category were obtained by
site visits. One lithographic ink sample was obtained by mail and taken to
the walk-in freezer. Letterpress, flexographic, and gravure ink samples
G-8
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were obtained by drawing off ink samples from the actual printing processes.
An attempt was made to minimize the headspace in the sample, but this could
not be monitored carefully because only authorized personnel were allowed near
the moving machinery to extract the sample. In any case, the headspace was
small. Since inks typically contain compounds with high boiling points
(i.e., low volatility), this would have a negligible impact on the results.
The samples were sealed, labeled and stored in an ice chest until taken to the
laboratory.
G.3.2 Compositing Procedures
After all the samples for a given source category were collected, a
composite sample for each source category was developed in the laboratory.
The actual number of samples used to develop the composite sample varied
between categories. At least five samples from each category were included in
each composite.
Composite samples were developed according to the type of data available
for a given category. If product usage data were available, then the
individual samples were mixed in proportion to the usage data. For example,
if 2,000 tons/year of solvent X and 1,000 tons/year of solvent Y were used in
a source category, then the composite sample consisted of solvent X and
solvent Y combined in a two-to-one ratio. If emissions data were available
for a source category, then the composite sample was developed in proportion
to the emissions data. If usage or emissions data were insufficient, the
individual samples for a particular category were combined in equivalent
proportions.
The specific compositing procedure used for each category is described
in detail below. In each case, the composite was prepared in a walk-in
refrigerator at 4°C immediately prior to analysis.
G.3.2.1 Gasoline Marketed Composite. In developing the composite for
this category, 1984 sales data for the leading five oil companies was used to
determine the percent contribution to U.S. sales.4 Thirty-eight percent of
the U.S. gasoline market is characterized by this composite sample. Breakdown
of company sales figures by gasoline type (i.e., leaded, unleaded, etc.) was
G-10
-------
based on average data for 1985 and 1986.7 Amoco no longer carries leaded
gasoline, so the percent contribution to Amoco sales was based only on
unleaded regular and unleaded premium gasoline.
The assumptions used to develop this composite included the following:
(1) the company contributions to the market are based on 1984 sales data;
(2) sample based on Chevron and Gulf sales is represented only by Gulf
gasoline; (3) average of 1985 and 1986 nationwide production data was used to
estimate the percentage of gasoline types per company; (4) gasoline was only
sampled in the Research Triangle area (North Carolina); (5) since samples were
collected in July, this composite does not reflect winter-blend gasolines.
The proportions in Table G-3 were used to make up 100 ml of the
composite. Of this volume, 30 ml (22.6 g) was put into a 40 ml septum-top VOA
vial and put into a freezer until analysis.
G.3.2.2 Deqreasina Composite. Data of sufficient quality were not
available which could be used to composite the mineral spirit samples. All
six mineral spirit samples were composited by volume in equal amounts as shown
in Table G-3. The final volume of the degreasing composite was 120 mL. Of
this volume, 30 ml (23.1 g) T^as measured into a 40 ml septum capped VOA vial
and stored in a freezer until analysis.
G.3.2.3 Drvcleaning Composite. Five of the six mineral spirit samples
were composited by volume in equal proportions since no data were available to
permit compositing by varying amounts (see Table G-3). The sixth sample was
not included because of its high volatility. Most mineral spirits used by
small independent dry cleaners have a minimum flash point of around 100°F.
The sixth sample had a flash point of less than 20°F, which was not typical of
petroleum drycleaning solvents and, therefore, was not included in the
analysis.
The final volume of the drycleaning composite was 100 ml. Of this
volume, 30 ml (23.3 g) was measured into a septum capped 40 ml VOA vial and
stored in a freezer until analysis. A duplicate sample was prepared by
G-ll
-------
TABLE G-3. COMPOSITE SAMPLE DEVELOPMENT
Sample
Identifier
GASOLINE MARKETED
GM-0714-01
GM-0714-02
GM-0714-03
GM-0714-04
GM-0714-05
GM-0714-06
GM-0714-07
GM-0714-08
GM-0714-09
GM-0714-10
GM-0714-11
GM-0714-12
GM-0714-13
GM-0714-14
DECREASING
DD-0716-01
DD-0717-01
DD-0717-02
DD-0717-03
DD-0717-04
DD-0717-05
Sampl e
Description
Gulf leaded
Gulf unleaded
Gulf unleaded premium
Amoco unleaded
Amoco unleaded premium
Texaco leaded
Texaco unleaded
Texaco unleaded premium
Shell leaded
Shell unleaded
Shell unleaded premium
Exxon leaded
Exxon unleaded
Exxon unleaded premium
Mineral spirits
Mineral spirits
Mineral spirits
Mineral spirits
Mineral spirits
Mineral spirits
Percentage
(by Volume)
Contribution
to Composite
7
14
5
14
5
5
10
4
5
10
3
5
10
3
100
16.7
16.7
16.7
16.7
16.7
16.7
100
G-12
-------
TABLE G-3. COMPOSITE SAMPLE DEVELOPMENT (Continued)
Sample
Identifier
DRYCLEANING
DD-0716-01
DD-0717-01
DD-0717-03
DD-0717-04
DD-0717-05
AUTO BODY REPAIR
ABR-0717-01
ABR-0717-02
ABR-0717-03
ABR-0717-04
ABR-0717-05
ABR-0717-06
Sample
Description
Mineral spirits
Mineral spirits
Mineral spirits
Mineral spirits
Mineral spirits
DuPont "Centari" acrylic enamel
DuPont "Lucite" acrylic lacquer
Sherwin-Williams acrylic enamel
Sherwin-Williams "Acrylyd" acrylic
lacquer
Sherwin-Williams "Kern Transport"
alkyd enamel
PPG/Ditzler "Ditzco" alkyd enamel
Percentage
(by Volume)
Contribution
to Composite
20
20
20
20
_20
100
25
23
19
17
10
_6
100
G-13
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TABLE G-3. COMPOSITE SAMPLE DEVELOPMENT (Continued)
Sample
Identifier
GRAPHIC ARTS
GA-0716-01
GA-0716-02
GA-0716-03A
GA-0716-03B
GA-0716-04
Samp] e
Description
Flexographic (yellow)
Lithographic
Gravure (red)
Gravure (clear)
Letterpress (black)
Percentage
(by Volume)
Contribution
to Composite
12.9*
28.5*
20.3*
20.5*
17.8*
100
G-14
-------
measuring a second 30 ml volume of the composite (22.8 g) into a 40 ml septum
capped VGA vial. The duplicate sample was also stored in a freezer until
analysis.
G.3.2.4 Autobodv Repair Composite. The composite for this category was
developed using a method similar to the one used for the gasoline marketed
category. A list of main automotive aftermarket paint producers with their
percent contribution in sales to the market was used to develop the autobody
repair composite (see Reference 8). This information was coupled with
information on main autobody paint types and their percent contribution to the
company-wide paint sales for each company to develop the criteria for
compositing. By obtaining two samples of DuPont paint, three samples of
Sherwin-Williams paint, and one sample of Ditzler paint, 42 percent of the
market was characterized. The following assumptions were made in the
development of the composite: (1) paints all cost roughly the same to remain
competitive in the market, thus sales percentages were assumed to be the same
as production percentages; and (2) each company had the same percent
contribution to sales for each type of paint.
Paints were combined with the thinners/reducers according to the
instructions provided on the paint cans resulting in actual paint samples.
Approximately 1:1.25 to 1:1.5 proportions of paint and thinner were used for
each sample. Each paint sample of a certain type and company origin was then
combined according to the scheme presented in Table G-3. The total volume of
this composite was 100 ml, of which 30 ml (27.3 g) was measured into a 40 ml
VOA vial and stored in a freezer until analysis.
Samples of polyurethane and acrylic urethane paints were not considered
because of the potential problems with mixing these paints into the composite.
Paints of this type require an activator to make the paint harden. This
possibly could form lumps of reacted paint in the composite. In addition, the
reactivity of all components with other paint mixtures was unknown.
G.3.2.5 Graphic Arts Composite. Compositing of graphic arts inks was
based on 1978 nationwide mass emissions.5 Since the composite was based on
mass emissions, the individual ink samples were composited by weight percent
according to the proportions shown in Table 6-3. Two gravure samples were
G-15
-------
mixed in equal amounts to obtain one gravure sample. For this category, only
one company was sampled per each subcategory (flexography, gravure,
letterpress, and lithography).
The total composite amount v/as 101.0 g. Of this amount, 21.1 g was put
into a 40 ml septum capped VGA vial and stored in a freezer until analysis.
G.3.3 Analytical Procedures
6.3.3.1 Headsoace Analysis. All of the composite samples were
subjected to analysis of the headspace of the VOA vials. The headspace of the
gasoline sample was sampled at room temperature. All of the other composites
were allowed to equilibrate in an oven at 90oC for one hour before the
headspace was removed for analysis.
The combination of capillary gas chromatography (DB-5 fused silica
capillary column, 30 m, 0.32 mm ID, 1.0 microns film thickness) with
quadrupole mass spectrometry was used to perform all analytical
determinations. For the headspace analyses, a coil of the column was frozen
with liquid nitrogen to allow the introduction of the gaseous materials from
the VOA vial headspace by a "direct injection using a gas-tight syringe. The
optimum sample size was determined as 1 ul. The temperature program used
consisted of an initial temperature of -50oC for 1 minute and an increase of
6oC per minute up to a final temperature of 250oC. The analytical system was
tuned using perfluorotributyl amine (FC-43), according to the manufacturer's
specifications. An accurate three-point calibration was performed using the
Air Toxics quantitation standards and surrogates (see Table G-4).
The calibration samples were prepared as a mixture of compounds in a
static dilution bulb from which gaseous injections were made to calibrate the
analytical system.
G.3.3.2 Semi-Volatile Analysis. A weighed quantity of the composite
was put into a carbon disulfide solution and an analysis of the organic
contents of the carbon disulfide solution was performed using GC/MS in order
to assess whether compounds were detected under these conditions when those
same compounds could not be observed in the headspace analysis. Since carbon
disulfide is not a polar compound, it was judged to be an optimal agent for
G-16
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TABLE G-4. CALIBRATION COMPOUNDS FOR HEADSPACE ANALYSIS
Tri chlorof1uoromethane
1,1-Dichloroethene
Methylene chloride
trans-l,2-Dichloroethene
1,1-Dichloroethane
Chloroform
1,1,1-Tri chloroethane
Carbon tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
trans-1,3-Dichloropropene
Toluene
cis-1,3-Dichloropropene
1,1,2-Trichloroethane
Chloromethane
Bromomethane
Tetrachloroethene
Di bromochloromethane
Chlorobenzene
Ethyl benzene
m-, p-Xylene
o-Xylene
Bromoform
1,1,2,2-Tetrachloroethane
m-Dichlorobenzene
p-Dichlorobenzene
o-Dichlorobenzene
Styrene
Acetone
2-Butanone
Heptane
Isopropylbenzene
Hexane
Vinyl chloride
Chloroethane
G-17
-------
dissolving any polar or nonpolar compounds that may exist in a sample. The
system was calibrated for the target compounds of SW-846 Method 8270. A
three-point calibration was performed for the compounds listed in Table G-5.
The sample size used for this analysis was also 1 uL. The temperature program
used consisted of an initial temperature of 35oC for 4 minutes and an increase
of 10°C per minute up to 270°C.
G.4 RESULTS AND DISCUSSION
G.4.1 Headspace Analyses
The technique used for analysis of headspace from composite samples
equilibrated at 90°C for 1 hour was similar to SW-846 Method 3810 "Headspace
Method." In this study, the method was intended for identification and
quantification of volatile organic compounds with boiling points less than
-100°C.
For analysis of headspace samples, an accurate three-point calibration
was performed for compounds that are designated as Air Toxics Standards (see
Table G-4). In addition to accurate quantitative determination of these
compounds, a complete qualitative .analysis was performed on all samples using
the combination of computerized library search techniques and a skilled
interpreter of mass spectral data. Compounds were identified and semi-
quantitative values were calculated using a response factor of one relative to
the analytical standard. By far the major components of most samples were
hydrocarbons; alkanes, alkenes, and aromatic compounds. In most cases, a
definitive identification of specific isomers could not be made, so a class
identification was made (e.g., methyl pentane).
In order to determine the relative percentages of the organic compounds,
the values which are calculated accurately for compounds included in the
calibration curve were integrated with the values calculated on the basis of a
relative response factor of one. The total organic content of the sample was
then summed and the quantity of each component was expressed as a percentage
of the whole to be consistent with the current VOC species profile format. A
threshold level of 0.01 percent was used to include a compound in a given
profile. See example calculations below for a hypothetical composite sample.
G-18
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TABLE G-5. CALIBRATION COMPOUNDS FOR SEMI-VOLATILE ANALYSIS
Benzyl alcohol
Bis(2-chloroisopropyl)ether
1,3-Dichlorobenzene
1,2-Di chlorobenzene
Hexachloroethane
2-Methylphenol
N-nitrosodimethylamine
Phenol
Aniline
Benzoic acid
4-Chloroaniline
2,4-Dichlorophenol
2,4-Dimethylphenol
Isophorone
Naphthalene
2-Nitrophenol
N-nitrosopiperidine
Acenaphthene
1-Chloronaphthalene
4-Chlorophenyl phenyl ether
Diethyl phthalate
Fluorene
1-Naphthylamine
2-Nitroaniline
Bis(2-chloroethyl)ether
2-Chlorophenol
1,4-Dichlorobenzene
Ethyl methane sulfonate
Methyl methane sulfonate
4-Methylphenol
N-nitroso-di-n-propylamine
2-Picoline
Acetophenone
Bi s(2-chloroethoxy)methane
4-Chloro-3-methylphenol
2,6-Dichlorophenol
Hexachlorobutadiene
2-Methylnaphthalene
Nitrobenzene
N-nitroso-di-n-butylamine
1,2,4-Tri chlorobenzene
Acenaphthylene
2-Chloronaphthalene
Dibenzofuran
2,6-Dinitrotoluene
Hexachlorocyclopentadi ene
2-Naphthylamine
3-Nitroaniline
G-19
-------
TABLE G-5. CALIBRATION COMPOUNDS FOR SEMI-VOLATILE ANALYSIS (Continued)
4-Nitroaniline
Pentachlorobenzene
2,3,4,6-Tetrachlorophenol
2,4,5-Trlchlorophenol
Anthracene
di-n-Butyl phthalate
Diphenylamine
Fluoranthene
N-ni trosodi phenylami ne
Pentachloronitrobenzene
Phenanthrene
Benzidine
Bi s(2-ethylhexyl)phthalate
Chrysene
p-Dimethylaminoazobenzene
Benzo(b)f1uoranthene
Benzo(g,h,i)perylene
Dibenz(a,h)anthracene
di-n-Octyl phthalate
4-Nitrophenol
1,2,4,5-Tetrachlorobenzene
2,4,6-Trichlorophenol
4-Aminobiphenyl
4-Bromophenyl phenyl ether
4,6-Dinitro-2-methylphenol
1,2-Diphenylhydrazi ne
Hexachlorobenzene
Pentachlorophenol
Phenacetin
Pronamide
Benzo(a)anthracene
Butyl benzyl phthalate
3,3-Dichlorobenzidine
Pyrene
Benzo(k)fluoranthene
Benzo(a)pyrene
7,12-Dimethylbenz(a)anthracene
G-20
-------
Assume for composite sample A, the following compounds were identified and
quantified:
Relative % =
Species nq (no/total no) 1QQ
Benzene* 80 12 82
Toluene* 100 ie!o3
o-Xylene* 25 4.01
Isopropylbenzene** 62 9 94
Hexane** 50 s!oi
Cyclohexane** 300 48.08
Methyl undecane** 7 1.12
TOTAL ng 624 10o!oi
Compounds that are accurately quantified (i.e., compounds included in the
three-point calibration).
**Compounds that are identified using computerized library search and a
skilled interpreter of mass spectral data (i.e., compounds not included
in calibration).
G.4.2 Semi-Volatile Analyses
Identification and quantification of semi-volatile organic compounds
(boiling points greater than 100°C) was made using procedures similar to
SW-846 Method 8270 "Gas Chromatography/Mass Spectrometry for Semi-Volatile
Organics." This method is very similar to Method 625 proposed in the
Test/Quality Assurance Project Plan. For example, the set of target compounds
used in both methods is the same. Differences between the two methods are
believed to be relatively unimportant as they relate to the overall program
objectives. In analysis of semi-volatile compounds, an accurate three-point
calibration was performed for target compounds of Method 8270 (see Table 6-5).
As discussed in Section G.4.1 for headspace analyses, accurate quantitative
determination of the target compounds was performed. This was combined with
the qualitative analysis performed on all samples using a computerized library
search and a skilled interpreter of mass spectral data. The compounds
identified in this manner were quantified using a response factor of one
relative to the analytical standard. Similar to the results observed from
headspace analyses, the major components of most samples were hydrocarbons;
alkanes, alkenes, and aromatics. Since a definitive identification of
6-21
-------
specific isomers was not possible in most cases, a class identification was
made.
The calculations used for developing the VOC profiles from the analytical
data are the same as those discussed in Section G.4.1 for the headspace
method.
6.4.3 Discussion of Results
G.4.3.1 Gasoline Marketed. Decreasing, and Drvcleanina Categories. At the
onset of the program, it was anticipated that there would be two relatively
distinct ranges of compounds (according to their boiling points or molecular
weights). These ranges would be characterized by the two analytical methods.
Some overlap was also expected. Comparison of data, based on headspace and
semi-volatile analyses, for some composite samples, however, showed a
different trend. For the gasoline marketed, degreasing, and drycleaning
composite samples, the species identified using the two methods fall
approximately in the same range (according to molecular weight). For example,
headspace analytical results for the degreasing composite span a range from C6
through C14. The semi-volatile analysis for the same composite covers a
similar range from C6 through C12. The respective ranges for the headspace
and semi-volatile analyses for the gasoline marketed composite were C4 through
C12 and C6 through C12. For the drycleaning composite, these ranges were C7
through C13 and C6 through C16. In the latter case, the identification of a
very small quantity of di-n-butyl phthalate (C16) in the sample was attributed
to possible contamination prior to sample collection. If contamination did
occur, the range covered by the semi-volatile analysis for the drycleaning
composite would be C6 to C12, which is in agreement with the ranges observed
for the other two composites discussed above.
Although there is good agreement in the ranges of compounds identified and
quantitated for the gasoline marketed, degreasing, and drycleaning composites,
it is difficult to compare the percentages for a given compound from the two
analyses for these categories. In some cases, a compound was reported in one
analysis and not reported in the other analysis. The judgement call made by
the computer and/or the analyst during analysis of the data (i.e., where peaks
do not resolve completely, where there is enough of a valley to decide that
G-22
-------
another peak is occurring, etc.) was probably one of the reasons why a
compound is observed in one analysis and not in the other.
In other cases, the values for the same compound were significantly
different. One of the reasons contributing to this discrepancy is probably
the use of semi-quantitative values based on a relative response factor of 1
in the VOC species profiles. In some cases, this may have resulted in a
significant bias in the relative percentages. Due to resource limitations, it
was not possible to fine tune the analytical procedures. It is believed that
some effort on method development would be necessary in order to get better
agreement between the two methods.
G-4-3.2 Autobodv Repair and Graphic Arts Categories. For the autobody
repair and graphic arts composites, a wider range of species was observed with
the semi-volatile analysis. For the autobody repair composite sample, the
ranges spanned using the headspace and semi-volatile analyses were C3 through
Cll and C6 through C19, respectively. The corresponding ranges for the
graphic arts composite sample were C3 through C12 and C6 through C21. In
contrast with the ranges observed for the gasoline marketed, degreasing, and
drycleaning composites, the semi-volatile analysis results for autobody repair
and graphic arts samples covered a wider range. Several compounds that were
not found in the headspace analysis were identified including significant
quantities of phthalates.
G.4.3.3 VOC Species Profiles. The headspace analytical results were
considered representative of the gasoline marketed, degreasing, and
drycleaning composite samples. The semi-volatile analytical results were
considered representative of the autobody repair and graphic arts composite
samples due to the wider range of compounds identified. Generally speaking,
the headspace method simulates real-life situations more closely than the
method used in identifying and quantifying semi-volatile compounds. In the
latter method, the species in a given sample are forced into a solution (using
carbon disulfide in this case). The solution is then analyzed. Solubility of
the species in a given sample determines the extent to which the species can
be identified and/or quantitated.
G-23
-------
The profiles developed in this study include the following:
Profile Number Profile Name
1190 Gasoline Marketed
1191 Graphic Arts-Printing
1192 Oegreasing
1193 Drycleaning
1194 Autobody Repair
G.5 INTERNAL QUALITY ASSURANCE/QUALITY CONTROL
G.5.1 Sampling Quality Control
Sampling quality control activities focused on ensuring the cleanliness of
the sampling equipment and the proper logging and documentation of each sample
to avoid loss of sample integrity. The time each sample was exposed to the
open air was reduced as much as possible.
Gasoline samples were collected in vials precleaned by Radian personnel.
Before collecting a gasoline sample, approximately one gallon of gasoline was
dispensed to purge the delivery hose of ambient temperature gas which may have
lost the more volatile compounds due to high summer temperatures.
Letterpress, flexographic, and gravure ink samples were obtained by drawing
off ink samples from the actual printing processes. The headspace in the
sample vial was minimized as much as possible. The remaining samples
(degreasing, drycleaning, autobody repair, and lithographic ink) were all
purchased or obtained directly in sealed containers.
Sample compositing procedures were based on proportions developed for each
source category as discussed in Section G.3.2. A minimum of five samples from
each category was included in each composite.
G.5.2 Analytical Quality Control
The analyses for this program were performed using accepted laboratory
procedures in accordance with the specified analytical protocols. The
G-24
-------
following general QC procedures were incorporated into the analytical effort,
where applicable:
o The Analytical Task Leader reviewed all analytical data and QC data on
a daily basis for completeness and data quality.
o A master logbook was maintained to record all pertinent sample
information.
o All hardcopy raw data (i.e., chromatograms, computer printouts, etc.)
were maintained in organized files.
The following sections summarize the results of all analytical QC data.
This includes surrogate recoveries, duplicate analyses, control samples, and
blank samples.
G-5.2.1 Surrogate Compounds. Each sample analyzed was spiked with
surrogate compounds prior to analysis. The use of surrogates is essential to
monitor the efficiency of the analytical process. The compounds were spiked
into the matrix prior to initiation of any sample preparation procedures
(following sample compositing) and carried through the entire analytical
process. The QC criteria is surrogate recovery within ±50 percent. The
surrogate results are presented in Tables 6-6 and G-7. As seen from the
tables, all surrogate recoveries were well within the QC criteria, averaging
87 percent for the headspace samples and 94 percent for the carbon disulfide
solutions (semi-volatiles).
G.5.2.2 Method Blank. One method blank sample was processed and analyzed
for the sample set to assess the background levels present in the analytical
system. The method blank was a reagent sample (carbon disulfide) taken
through the entire sample preparation and analytical process. It was spiked
with the same surrogate compounds and quantitation standards as the field
samples so that recoveries could be calculated. (The field sample results
were not corrected for the concentrations of compounds found in the method
blank.)
G-25
-------
TABLE G-6. SURROGATE RECOVERIES OF VOC SAMPLES - HEADSPACE ANALYSES
Surrogates*'1*
Sample Perfluorobenzene Perfl uorotoluene D10-Ethyl benzene
Autobody Repair 91 79 74
Drycleaning Composite 90 87 84
Drycleaning Composite 90 88 87
(Duplicate)
Degreasing Composite 79 76 84
Graphic Arts Composite 90 86 97
Gasoline Composite 100 98 92
*A11 values reported as percent surrogate recovery.
bThe QC criterion was surrogate recoveries within ±50 percent.
G-26
-------
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G-27
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The compounds and their respective concentrations found in the method blank
were as follows:
Benzene 62.0 ng/uL
Cyclohexane 62.0 ng/uL
C16H3004 10.6 ng/uL
Cyclohexene 6.4 ng/uL
Methylene chloride 4.2 ng/uL
Unknown 1.7 ng/uL
N-phenylaniline 1.5 ng/uL
The only compounds present in significant quantities were benzene and
cyclohexane. Benzene is a common contaminant found in carbon disulfide and it
is virtually impossible to find carbon disulfide which is benzene free.
Cyclohexane is frequently added to organic solvents as a stabilizer and
cyclohexene is often added to organic solvents as an anti-oxidant. ClfiH3004
and N-phenylaniline were both observed in all of the samples analyzed and are
both considered to be chromatographic artifacts from the column. The unknown
is a small quantity of compound that is an artifact of the column or solvent,
which could not be identified. It was not observed in the samples and is
considered to be insignificant in terms of quantity.
6.5.2.3 Duplicate Analyses. The composite sample from the dry cleaning
category was analyzed in duplicate for both headspace and semi-volatile
compounds. The duplicate sample was analyzed in order to evaluate the
reproducibility of the analytical methodology for the headspace and semi-
volatiles analyses. The QC criteria for agreement of the two results for the
same compound, in terms of total micrograms, were within +50 percent for each
VOC detected.
In the case of the duplicate drycleaning headspace sample, the compounds
identified were the same, but the signal levels for the compounds in the two
samples differed by approximately 50 percent. This roughly 50 percent
difference was observed for the two results, expressed in total micrograms.
The two samples used to determine results #1 and #2 were taken from the same
composite, at approximately the same volume (22.8 grams in one case,
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23.3 grams in the other). The same volume of the headspace was injected after
the vials containing the sample had been heated to 90°C. Scan times are
exactly the same for the same compounds. There is no explanation for the
difference in the headspace samples. The only possible explanation is that,
for some reason, substantially less material was delivered to the ion source
in one case than in the other. Since the quantitation standards were
introduced separately from a static dilution bulb, it is possible for the
standards to be consistent while the values obtained for the samples differ.
The close correspondence of the standards shows that there was nothing
inherently irreproducible in the analytical process. The better comparison is
the relative percentages (weight percents) of any two compounds which appear
to be more reproducible than the absolute values (micrograms). Since the
relative percentages are the data that will be used in the VOC species
profiles, this is an appropriate comparison.
The two results for the semi-volatiles duplicate analysis are all within the
QC criteria of +50 percent agreement between results #1 and #2 for the same
compound. However, several compounds were identified in the second analysis
in quantities which were nondetectable in the first analysis. This is not
unusual since the presence of a given compound is decided upon by the computer
and/or analyst who must decide what constitutes a peak, This type of
judgement may explain why in some instances a compound is observed in one
analysis and not in the other.
G-29
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