United States
Environmental Protection
Agency
Office of Air Quality
Planning And Standards
Research Triangle Park, NC 27711
EPA-450/2-90-001b
January 1990
AIR
&EPA
Air Emissions
Species Manual
Volume II
Particulate Matter
Species Profiles
Second Edition
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EPA-450/2-90-001b
January 1990
Air Emissions Species Manual
Volume: II Participate Matter
Species Profiles
Second Edition
By:
Radian Corporation
3200 Progress Center
P.O.BOX 13000
Research Triangle Park, North Carolina 27709
Contract No. 68-02-4286
Work Assignment No. 91
William B. Kuykendal, Project Officer
Office Of Air Quality Planning And Standards
Office Of Air And Radation
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
Charles C. Masser, Project Officer
Air And Energy Engineering Research Laboratory
Office Of Research And Development
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
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FOREWORD
This report is the result of i cooperative effort between the Office of
Air Quality Planning and Standards' Air Quality Management Division (AQMD) and
the Office of Research and Development's Air and Energy Engineering Research
Laboratory (AEERL). The overall management of the program was the
responsibility of AQMD. AEERL was responsible for the development of selected
VOC species profiles as well as program review.
m
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ABSTRACT
The U. S. Environmental Protection Agency (EPA) has several ongoing
activities that require speciated volatile organic compound (VOC) or
particulate matter (PM) profiles from several source categories. In 1980, EPA
published the "Volatile Organic Compound (VOC) Species Data Manual, Second
Edition" (EPA-450/4-80-015) which provided VOC species profiles for some
emission source categories. In 1985, EPA published the "Receptor Model Source
Composition Library" (EPA-450/4-85/002) which contained particulate matter
(PM) species profiles for several source categories. More recently, EPA
published the "Air Emission Species Manual - Volume I, Volatile Organic
Compound (VOC) Species Profiles" (EPA-450/2-88-033a) and the "Air Emissions
Species Manual - Volume II, Particulate Matter Species Profiles" (EPA-450/2-
88-033b). These documents represent expansions of the 1980 and 1985 VOC and
PM species profile document.
In 1989 EPA updated the VOC and PM profile data bases by adding in new
profiles and making necessary revisions to existing profiles. These updates
are contained in the document "Addendum to the Air Emissions Species Manual"
(EPA-450/2-88-003c). The objective of the current study is to produce a
second edition of the "Air Emissions Species Manual" (EPA-450/2-88-003a,b)
that incorporates and contains all the updates specified in the "Addendum ..."
document.
The updated VOC species profile data base is contained in Volume I of
this document. The VOC profile data base includes VOC profiles from primarily
three sources: (1) the 1980 VOC Data Manual, (2) new VOC profiles developed
from readily available existing data, and (3) new VOC profiles developed from
original data as a result of the VOC speciation field sampling program. In
addition to the VOC profiles, Volume I contains profile assignments that link
a profile to a source category. For categories where profile data are not
available, the profile assignments are based on engineering judgement.
The revised PM species profile data base is contained in Volume II of
this document. It was developed from multiple sources of information. Many
PM profiles were extracted from the Source Composition Library with minor
changes in format to facilitate inclusion of additional information in the
iv
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profiles. A large number of PM profiles were developed by contacting
researchers working in the areas of PM species profile development and source
receptor modeling. These researchers were questioned regarding the
availability of PM species profile data that were not already contained in the
Source Composition Library or, the Air Emissions Species Manual. New species
profiles were developed from data submitted by the researchers for a variety
of source categories. A limited number of new PM profiles developed from
literature review are also included in the PM data base. As in the VOC
profile data base, the PM data base also contains profile assignments.
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VI
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VOLUME II - PARTICULATE MATTER (PM) SPECIES PROFILES
CONTENTS
Page
Foreword ...:.... i i i
Abstract ; i v
Tabl es i x
Executive Summary xi
1. Introduction 1
2. PM Species Profile Format and Application 7
2.1 PM Species Profile Format 7
2.2 Limitations of Data 15
2.3 PM Species Profile Application 17
2.3.1 Document Guide 17
2.3.2 Example of Use of a Profile 18
2.4 References for Section 2 20
3. PM Species Profiles - Point and Area Sources 21
3.1 External Combustion Boi1ers 29
3.2 Chemical Manufacturing 87
3.3 Food and Agriculture Ill
3.4 Primary Metal Production 115
3.5 Secondary Metal Production 189
3.6 Mineral Products 223
3.7 Petroleum Industry 253
3.8 Pulp and Paper Industry 271
3.9 Surface Coati ng Operations 289
3.10 Solid Waste Disposal 293
3.11 Metal Fabrication 313
3.12 Heavy Construction 319
3.13 Unpaved Roads 325
3.14 Paved Roads 335
3.15 Natural Sources 387
3.16 Wood Combustion y 445
3.17 Agricultural Field Burning ' 477
3.18 Mobile Sources 487
3.19 Aircraft 549
3.20 Other Sources 553
References 559
vii
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Appendices
A. PM Profile Listing A-l
B. PM Profile Calculations B-l
C. Particle Size Distribution Data ...-; '. C-l
D. Industry-Specific. Average PM Profiles and "Zero"
Profile .'. D-l
E. PM Profile Assignments E-l
F. Reactivity Fractions for the Alkaline Elements K, Na,
Ca, and Mg F-l
G. Data File Description G-l
VI 1 1
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TABLES
Table Page
2-1 Sample Profile 8
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EXECUTIVE SUMMARY
The U. S. Environmental Protection Agency (EPA) has several activities
that require speciated participate matter (PM) or volatile organic compound
(VOC) profiles from several source categories. Some of these activities are
preparation of air toxics and acid precipitation emission inventories, acid
precipitation modeling studies, receptor modeling, and ozone strategy
development. In an effort to update the available speciated PM profile data
base, EPA conducted studies to update the "Receptor Model Source Composition
Library" (EPA-450/4-85-002) and produced a revision entitled "Air Emissions
Species Manual - Volume II, Particulate Matter Species Profiles" (EPA-450/2-
88-003b). Similarly for VOC emissions, EPA has performed studies to revise
the "Volatile Organic Compound Species Data Manual - Second Edition" (EPA-
450/4-80-015) and provide an updated version in the "Air Emissions Species
Manual - Volume I, Volatile Organic Compound Species Profiles" (EPA-450/2-88-
003a). The Air Emissions Species Manual (Volumes I and II) was recently
updated by the document "Addendum to the Air Emissions Species Manual (EPA-
450/2-88-003c). The update took the form of adding in new PM and VOC profiles
to the speciation data base and making revisions to several existing VOC
profiles.
The objective of the current study was to produce a second edition of
the Air Emissions Species Manual for PM that contains all existing profile
data and those data contained in the "Addendum" document (EPA-450/2-88-003c).
The second edition of the PM Manual contains profiles derived from the Source
Composition Library, profiles developed from data collected from researchers
working in the areas of PM speciation and source receptor modeling, and a
limited number of profiles developed from published literature.
Each PM profile in this document contains the following information:
Profile name
Profile number
Profile data quality
Control device identification
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Reference(s)
Data source
Source Class!ficition Code (SCC)
Mass fraction data
Species identification: species identified by Chemical Abstract
System (CAS) number, species number, and species name
Composition data in weight percent for four size ranges: 0-2.5 urn,
2.5-10 urn, 0-10 uro, and total particulate measured
Uncertainty associated with composition data for four size ranges:
0-2.5 urn, 2.5-10 urn, 0-10 urn, and total particulate measured
Date
The new information in th
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SECTION 1
INTRODUCTION
The U. S. Environmental Protection Agency (EPA) has several ongoing
activities that require speciated particulate matter (PM) and volatile organic
compound (VOC) profiles from .several source categories. Some of these
activities include receptor modeling, preparation of acid precipitation and
air toxics emission inventories, acid precipitation modeling studies, and
ozone strategy development.
As part of an effort to update the available speciated VOC and PM
profile data bases, EPA has conducted several studies to update the "Volatile
Organic Compound Species Data Manual - Second Edition" (EPA-450/4-80-015) and
the "Receptor Model Source Composition Library" (EPA-450/4-85-002). These
updates produced two new species profile documents entitled "Air Emissions
Species Manual - Volume I, Volatile Organic Compound Species Profiles" (EPA-
450/2-88-003a) and "Air Emissions Species Manual - Volume II, Particulate
Matter Species Profiles" (EPA-450/2-88-003b). Recently, the Air Emissions
Species Manual was updated by the document "Addendum to the Air Emissions
Species Manual" (EPA-450/2-88-003c). In the "Addendum" document, 158 new PM
profiles, spanning different 14 source categories, were added to the PM
speciation data base, eight new VOC profiles were added for the oil production
source category, and minor revisions were made to three existing VOC profiles
for unleaded gasoline vehicles. The three existing profiles affected were
1101, 1203, and 1204.
In the PM area, the objective of the current study is to produce a
second edition of the "Air Emissions Species Manual - Volume II, Particulate
Matter Species Profiles" (EPA-450/2-88-003a). This second edition
incorporates and contains all of the updated information specified in the
"Addendum..." document, in addition to all of the profile data in the 1988 PM
Species Manual.
Composition data are reported for four size ranges: 0-2.5 urn, 2.5-10
urn, 0-10 urn, and total particulate measured. In addition, uncertainties
associated with composition data of each size interval are reported when
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available. The size interval 0-10 urn is of particular interest in PM10 source
apportionment studies and in modeling efforts under the National Acid
Precipitation Assessment Program (NAPAP). When data for the 0-10 urn interval
were not reported by the sources listed, they were calculated from data for
the 0-2.5 urn and 2.5-10 urn intervals according to procedures outlined in the
Source Composition Library (refer to Appendix B). Uncertainty values for the
0-10 urn size range are also calculated, when sufficient data were available,
based on the methodology discussed in the Source Composition Library (see
Appendix B). This appendix also contains a procedure that may be used to
estimate composition data for-the E.5-6 urn and 6-10 urn size intervals from
data for the 2.5-10 urn size interval.
In addition to the composition data, mass fraction data (i.e., fraction
of mass of particulate emissions within a given size range) are also presented
in the profiles. These data are provided for the following size intervals:
0-2.5 urn, 0-6 urn, and 0-10 urn. About half of the mass fraction data were
obtained from AP-42 (see Appendix C).
In the PM data base, several individual profiles were available for each
of several source categories. In these cases, profiles for the same category
were grouped together to form a composite profile. These profiles would be
useful in applications such as acid precipitation modeling studies where
national average values are desired. Individual profiles used in developing
the composite profile are reported as well as the composite profile since the
individual profile may be applicable in a specific situation (region, fuel,
product, etc.).
To provide the user/reader with guidance on the overall quality of data
contained in a given profile, each profile is ranked A, B, C, D, or £, similar
to the ranking scheme used in AP-42.1 The overall quality ratings reflect the
uncertainties associated with composition data, mass fraction data,
calculational procedures (associated with the 0-10 urn range), and assumptions
about composition of size fractions to fill data gaps. A more detailed
discussion on profile data quality is contained in Section 2.
The activities where PM species profiles are applied may employ source
classification codes (SCC's) for representing point sources and the National
Emissions Data System (NEDS) area source codes for representing area sources.
Ideally, each source category/source code would be characterized by an
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appropriate PM profile. Since there are much fewer species profiles than
source categories, a PH profile for one category is assigned to other
categories that are judged to be similar to the source category(ies) having an
original profile. This document contains PM profile assignments for all SCC's
and applicable NEDS area source codes. In addition, profile assignments are
provided for additional area source codes used in the NAPAP efforts. In cases
where there were more than one profile (including a composite profile)
characterizing a source category, profile assignments were based on the
composite profile. For some source categories characterized by more than one
profile, composite profiles were not developed. These profiles represented
data based on different control devices. Therefore, they were all included in
the profile assignments. A file containing control device codes for each
profile was developed for use in identifying the type of control device used.
Development of PM profile assignments is discussed further in Appendix E.
Also included in this appendix are the listings of the PM profile assignments
for point and area sources.
For several SCC's, profile assignment using engineering judgement was
not possible. In such cases, industry-specific average profiles were
developed from original profiles representing other SCC's within the same
industry group. These profiles have numbers starting with 9 and are
recommended for use only if there is no other information available. Another
profile developed using engineering judgement was the "zero" profile
(Profile 00000). This profile is an overall average of all the PM profiles in
the data base. It is intended for use only as a default profile in
applications where nonzero emissions are reported for those SCC's designated
as having zero or negligible emission factors in the Criteria Pollutant
Emission Factor Document.2 Such applications may involve preparation of air
toxics and acid precipitation emission inventories and acid precipitation
modeling studies. The industry-specific average profiles and the "zero"
profile are presented in Appendix D.
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This document Is divided into three sections. Section 1 contains this
introduction. Section 2 describes the PH species profile format and discusses
the applicability of PM profiles. Section 3 contains the profiles for both
point and area sources, followed by the list of references. There are seven
appendices that provide additional information;
Appendix A - Listing of PM Profiles
Appendix B - PM Profile Calculations
Appendix C - Particle Size Distribution Data
Appendix D - Industry-Specific Average PM Profiles and "Zero" Profile
Appendix E - PM Profile Assignments
Appendix F - Reactivity Fractions for the Alkaline Elements (Ca, Mg,
Na, and K)
Appendix G - Data File Description
4.
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REFERENCES FOR SECTION 1
1. U. S. Environmental Protection Agency. Compilation of Air Pollutant
Emission Factors, AP-42. Fourth Edition. Office of Air Quality,
Planning and Standards, Research Triangle Park, North Carolina.
September 1985; Supplement A, October 1986; Supplement B, September
1988.
2. U. S. Environmental Protection Agency. Criteria Pollutant Emission
Factors for the 1985 NAPAP Emissions Inventory. EPA-600/7-87-015.
Office of Research and Development, Air and Energy Engineering Research
Laboratory, Research Triangle Park, North Carolina. May 1987.
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SECTION 2
PM SPECIES PROFILE FORMAT AND APPLICATION
2.1 PM SPECIES PROFILE FORMAT
Table 2-1 Is an example of the format used In presenting the PM profiles
In this document. This format is similar to that used in the Receptor Model
Source Composition Library except for a few changes. Composition data and
uncertainty information are reported in the Source Composition Library for
size intervals 0-2.5 urn, 2.5-10 urn, and total particulate measured. In
addition to these data, the PM profiles in the current document contain
composition data for the 0-10 urn size interval and uncertainty information for
the 0-10 urn interval. The size interval 0-10 urn is of particular interest in
PM10 source apportionment studies and in modeling and emission inventory
preparation efforts under NAPAP. Therefore, composition data for this size
range are also included in this document.
Another data item that is included in the profiles in this document is
particle size distribution data (i.e., fraction of mass in a given size
interval). The particle size distribution data can be used in estimating
size-specific particulate emission rates in preparation of emission
inventories. When combined with the composition data from the profiles, these
data can be used to estimate size-specific and speciated particulate emission
rates. In this document, size distribution data are coupled with the source
profiles from the Source Composition Library to develop composition data for
the 0-10 urn size interval.
The profile ratings used in the Source Composition Library were adopted
as data quality indicators. These ratings, however, were modified to take
into account the uncertainties associated with mass fraction data,
calculational procedures used for the 0-10 urn size interval, and also
assumptions used in filling data gaps. As shown in Table 2-1, a dual data
quality indicator is used for the profiles from the Source Composition
Library. The first quality indicator is the rating as it appears in the
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TABLE 2-1. SAMPLE PROFILE
PH Proffit Speeiation Report
Profile Nam Municipal Incinerator (Philadelphia)
Profile Nwber 17105
Data Quality B/D
Control Device ISPC Inoperative)
Raference(s) 52
Data Source Dilution aanpler. Representative iiaopla from group of
SCC Assisnmentt 50100101
Mass Fraction Data - Size Interval (m) : (0-2.5) (0-6)
Hast Fraction : 0.260 0.310
Total Particulars Hattor »
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-15-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
42
48
50
51
55
56
Syra
Be
8
F
Na
M8
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Nn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Mo
Cd
Sn
Sb
Cs
Sa
0-2
Xwt
0
1
0
1
21
6
0
0
0
0
0
Q
0
0
11
0
0
0
0
0
0
0
0
0
0
0
0
NA
NA
NA
NA
HA
.819
.442
.543
.906
.299
.464
.223
<
.012
.000
.015
.018
.279
<
.032
.148
.503
.016
<
.000
.003
.563
.016
.009
.000
.036
.284
.829
.442
<
.020
.5 ym
unc
0.000
0.000
0.000
0.000
0.000
0.117
0.067
0.098
0.301
0.985
0.305
0.030
0.000
0.003
0.001
0.001
0.001
0.013
0.000
0.002
0.007
0.525
0.011
0.000
0.031
0.011
0.027
0.002
0.002
0.014
0.003
0.016
0.041
0.028
0.000
0.029
2.5-10 un
Xut
HA
NA
NA
NA
NA
5.827
8.570
0.894
3.487
16.678
4.491
5.870
<
1.097
0.024
0.111
0.091
1.874
<
0.085
0.053
4.012
0.000
<
0.000
0.003
0.375
0.005
0.023
0.000
0.003
0.024
0.004
0.086
<
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.466
0.581
0.299
0.601
2.218
0.640
0.381
0.000
0.069
0.008
0.009
0.008
0.129
0.000
0.010
0.015
0.918
0.022
0.000
0.071
0.020
0.057
0.008
0.008
0.039
0.023
0.049
0.089
0.113
0.000
0.242
0-10 urn
Xwt
NE
NE
NE
NE
NE
2.400
3.693
0.654
2.405
19.840
5.841
2.006
NE
0.355
0.008
0.045
0.041
0.783
NE
0.049
0.118
9.137
0.011
HE
0.000
0.003
0.504
0.013
0.013
0.000
0.026
0.202
0.568
0.330
NE
0.014
unc
0.000
0.000
0.000
0.000
0.000
0.657
0.931
0.238
0.599
3.100
0.903
0.626
0.000
0.116
0.006
0.012
0.011
0.204
0.000
0.011
0.019
1*383
0.017
0.000
0.053
0.016
0.078
0.006
0.006
0.028
0.016
0.045
0.105
0.091
0.000
0.167
10.
<0-10)
0.380
Total
Measured
Xwt
HE
NE
HE
HE
HE
2.400
3.693
0.654
2.405
19.840
5.841
2.006
NE
0.355
0.008
0.045
0.041
0.783
NE
0.049
0.118
9.137
0.011
NE
0.000
0.003
0.504
0.013
0.013
0.000
0.026
0.202
0.568
0.330
NE
0.014
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
8
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TABLE 2-1. SAMPLE PROFILE (Continued)
PM Profile Specietlon Report - continued (profile 17105)
Total Partieulate Matter
CAS Number
7440-45-1
7439-97-6
7439-92-1
Nun Sytn
58
80
82
201
202
203
204
C*
H|
Pb
OC
EC
S04
N03
0-2
XHt
<
0.009
8.116
NA
NA
NA
NA
.5 un
unc
0.000
0.004
0.371
0.000
0.000
0.000
0.000
2.5-10 urn
XHt
<
0.011
2.420
NA
NA
NA
NA
unc
0.000
0.012
0.633
0.000
0.000
0.000
0.000
0-10 un
Xut
NE
0.010
6.320
NE
NE
HE
NE
unc •
0.000
0.009
0.961
0.000
0.000
0.000
0.000
Total
Measured
%ut
HE
0.010
6.320
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
55.046
56.126
55.389
55.389
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Source Composition Library, followed by the modified quality indicator. The
presence of a single data quality indicator indicates the profile was
developed during the current study. Each of the entries in Table 2-1 is
described below: '
Prof lie Name: The profile name is the descriptor used for the
applicable source category.
Profile Number; This is a unique number assigned to each profile.
Profiles are coded into four groups as follows: combustion sources (10000
series), industrial processes (ZOOOO series), mobile sources (30000 series),
and area sources (40000 series). New PM profiles developed during this study
are also coded according to this general scheme. Composite profiles developed
during this study from individual profiles are assigned profile numbers in the
same series. For example, the profile Unpaved Roads - Composite is developed
from Profiles 41201, 41203, and 41204 and assigned the number 41220. The
industry-specific average profiles developed from available profiles to
characterize source categories for which no data are available are assigned
profile numbers beginning with 9. There are 16 such profiles (90001 through
90016) and they are presented in Appendix D. Profile 00000 is an overall
average of the profiles in the data base. It is intended for use as a default
profile in applications where nonzero emissions are reported for those SCC's
designated as having zero or negligible emission factors in the Criteria
Pollutant Emission Factor Document.1 Profile 00000 is also presented in
Appendix D.
Prof lie Data ..Qua! i ty: Dual data quality indicators are used in the
profiles contained in this document (e.g., C/D). The first quality indicator
is the profile rating as reported in the Source Composition Library. The
second quality indicator is the modified rating assigned in this document.
For a profile obtained from the Source Composition Library, the rating was
modified to include the data quality associated with size distribution data
and any assumptions associated with developing the composition data for the 0-
10 urn size Interval and filling data gaps. The guidelines used in assigning
data quality indicators were somewhat subjective. For those profiles that
were not extracted from the Source Composition Library, a single data quality
indicator is included.
10
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It was assumed that the procedures for calculating composition data for
the 0-10 urn size interval using mass fraction data would lower the overall
profile data quality by one level. Additional assumptions about missing data
(e.g., no data reported for the 0-2.5 urn size interval) would also lower the
data quality by one or two levels. For example, Profile 29301 (Primary Lead
Smelting - Slag Pouring) has a profile rating of "C" in the Source Composition
Library. The mass fraction data for this profile has a data quality indicator
of "E." For this profile, composition data for the 0-2.5 urn and 2.5-10 urn
size intervals were not reported. To fill these two data gaps, it was assumed
that the composition data for these two intervals are the same as the one for
the total particulate measured. Thus, the data quality assigned to
Profile 29301 in this document was modified as "E." Specifically, each data
quality indicator represents the following:
Data Quality A: Composition and mass fraction data obtained for the
size intervals 0-2.5 urn, 2.5-10 urn, and total
particulate measured from several sources using
sound sampling and analytical methodology.
Profiles are considered representative and
recommended for use.
Data Quality B: Composition and mass fraction data obtained for the
size intervals 0-2.5 urn, 2.5-10 urn, and total
particulate measured from a few sources using a
generally sound methodology.
Data Quality C: Composition data obtained for the size intervals
0-2.5 urn, 2.5-10 urn, and total particulate
measured from a few sources using a generally
sound methodology and mass fraction data of
below average quality; or composition data
obtained for two of the three size intervals 0-
2.5 urn, 2.5-10 urn, and total particulate
measured from a large number of sources using a
sound methodology coupled with mass fraction
data of below average quality.
11
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Data Quality D: Composition data obtained for size intervals
0-2.5 urn, 2.5-10 urn, and total participate
measured obtained from a limited number of
sources using uncertain or undocumented
"methodology coupled with mass fraction data of
average or below average quality; or composition
data obtained for two of the three size
intervals 0-2.5 ui» 2.5-10 urn, and total
particulate measured from a few sources using a
generally sound methodology coupled with mass
fraction data of poor quality.
Data Quality E: Composition data obtained for the size intervals
0-2.5 urn, 2.1-10 urn, and total particulate
measured from a single source using poorly
documented methodology coupled with mass
fraction data of poor quality; or composition
data obtained for two of the three size
Intervals 0-2.5 urn, 2.5-10 urn, and total
particulate measured from a limited number of
sources using poorly documented methodology
coupled with mass fraction data of poor quality;
or composition data obtained for one of the
three size intervals 0-2.5 urn, 2.5-10 .urn, and
total particulate measured coupled with mass
fraction data of poor quality; or industry-
specific average profiles; profiles with "E"
rating are recommended for use only if there is
no other information available.
Control Device: This entry is used to indicate if the profile data
represent an emission stream downstream or upstream of a control device (if
present). The downstream composition and size distribution of particulate
emissions would be affected by the presence of a control device.
Reference(s): This entry identifies the primary reference(s) used in
development of the profiles. The reference list is the same as that contained
12
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in the Source Composition Library except for additional references used in
developing the new profiles. If more detailed information is required about
the data contained in the profile, the user/reader should consult these
reference(s). •
Data Source: This entry briefly describes the basis of the composition
data used in the profile (e.g., number of tests, sources and samples, sampling
and analytical methods, how data were composited, etc.). More detailed
information about the data used can be obtained from the references indicated
in the profile.
SCC: This entry is the code for the source category for which the
profile was originally developed. These codes are obtained from NEDS for
point sources (1-01-001-01 through 5-03-900-10) and area sources (01 through
64). Area source codes from 65 through 115 developed under NAPAP are also
considered. A listing of area source codes included in this document and
their descriptions is presented in Appendix E.
Mass Fraction Data: Size distribution data (i.e., the fraction of mass
[particulate emissions] contained within a specific size range) are reported
in this entry. Three size ranges are considered: 0-2.5 urn, 0-6 urn, and 0-
10 urn. Mass fraction data for 0-2.5 urn and 0-10 urn size ranges are used to
estimate composition data for the 0-10 urn size range. Mass fraction data for
the 0-6 urn interval are presented as additional information. A large
proportion of the mass fraction data was obtained from AP-42.2 A detailed
description of the mass fraction data (how data were compiled, data quality,
references, etc.) used in this document is included in Appendix C.
One area of concern is that the mass distribution data and the source
profiles used to estimate composition of the 0-10 urn size range are not from
the same data set and represent data collected from different emission
sources. This introduces an additional source of uncertainty in the
calculations of composition data for the 0-10 urn size interval.
Species Identification: Each species in the profile data is identified
by a species number, species name, and CAS number. In general, the species
number is the atomic number for the element. Other species are arbitrarily
assigned the numbers starting with 200 (e.g., total carbon - 200; organic
carbon - 201; elemental carbon - 202; sulfate ion - 203, etc.). The CAS
numbers for the species were obtained from the Registry of Toxic Effects of
13
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Chemical Substances (1983 Supplement to the 1981-82 edition).
The species listed in Table 2-1 are those that are most commonly
reported in the literature. As indicated in the Source Composition Library,
for those profiles that include other key species, any standard component may
be deleted to permit inclusion of a nonstandard component. Therefore, some
variability exists in the profile format with respect to the list of species
considered.
Composition Data; In a typical profile, composition data expressed as
weight percent are presented for four size ranges: 0-2.5 urn, 2.5-10 urn, 0-
10 urn, and total particulate measured. Values for the 0-2.5 urn, 2.5-10 urn,
and total particulate measured are based on actual data and are extracted
directly from the Source Composition Library, where available. Values for the
0-10 urn size interval are derived from calculations based on the methodology
described in the Source Composition Library (refer to Appendix B). In each
profile, footnote (1) indicates that the information for a specific size
interval is extracted from the Source Composition Library. Footnote (2)
indicates that the data are based on calculations described in Appendix B.
In some cases, profile data were not complete, i.e., data were only
reported for one or two size intervals. In these cases, engineering judgement
was used to fill the data gaps. For example, in Profile 17106 (Municipal
Incinerator - Composite), composition data are reported only for the total
particulate measured as indicated by footnote (1) for the last column in the
profile. In absence of other information, it was assumed that the composition
data for the 0-2.5 urn and 2.5-10 urn size intervals were the same as that for
the total particulate measured. This assumption is indicated by footnote (3)
for these two size intervals.- The following symbols are used in the
composition data: NA (not analyzed), NE (not estimated), and < (below the
detection limit). The NE symbol is used in cases where a specific calculation
could not be carried out due to missing data (e.g., NA, <).
Following the data tabulation, the percent of mass accounted for by the
composition data under each size interval is presented. This value is based
on the summation of weight percentages of the species in a given column. The
sum does not include oxygen, hydrogen, nitrogen, water, or other components
that were not included in the analysis. In some profiles, the summation of
weight percentages may be greater than 100 due to double counting
14
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(e.g., sillfur/sulfate, total carbon/elemental carbon/organic carbon, etc.).
Failure to include the carbonaceous, oxygen, and hydrogen components in the
aerosol characterization is often the largest source of unexplained mass.
Since the composition data in weight percentages are associated with a
specific size interval, it 1s'not possible to add the percentages for a
particular species across size intervals. For example, in Table 2-1, the
percentages for Al in the 0-2=5 urn, 2.5-10 urn, and 0-10 urn size intervals are
0.819, 5.827, and 2.400; and 0.819 + 5.827 t 2.400.
Uncertainty: The uncertainty associated with composition data for the
size ranges 0-2.5 urn, 2.5-10 urn, and the total particulate measured are based
on either the estimated analytical precision of the measurement (single
sample) or the standard deviation of the data sets. The uncertainty
associated with the 0-10 urn size range is calculated according to the
procedure outlined in the,Source Composition Library (refer to Appendix B).
As Table 2-1 shows, the footnotes for the uncertainty columns indicate whether
they are based on data (i.e., extracted from the Source Composition Library)
or calculated. In many cases, uncertainties were either not reported or not
known by the authors. The abbreviations used for uncertainty values include
NR (not reported) and NE.
Date: This entry will be used to indicate the date the profile was last
reviewed/updated by EPA.
2.2 LIMITATIONS OF DATA
As indicated in the Source Composition Library and in the first edition
of the Air Emissions Species Manual, the reader/user should be aware of the
limitations of each data set, specifically with respect to measurements of
carbonaceous emissions and volatile elements (e.g., Pb, As, Hg, etc.) that
partially exist in the gaseous phase at high stack temperatures. Unless
special precautions such as dilution source sampling, aircraft or balloon
methods are exercised, these components will not be accurately represented in
the data. In addition, many of the studies from literature do not report a
sufficiently broad range of particulate matter components to account for the
majority of the mass, typically due to the specific sampling and analytical
protocols employed. Therefore, studies that use these source profiles
15
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(e.g., receptor modeling) may be unable to apportion all of the ambient
aerosol mass accurately. Thus, the user/reader is cautioned to use these
profiles with discretion. The profile data should be carefully reviewed to
ensure that they represent the sources being studied reasonably well.
In estimating composition data for the 0-10 urn size interval, size
distribution data were combined with composition data reported for the 0-
2.5 urn and 2.5-10 urn size Intervals. The size distribution data and the
composition data from the source profiles represent data collected from
different emission sources. Therefore, this introduces an additional source
of uncertainty in calculating composition data for the 0-10 urn size interval.
In several profiles from the Source Composition Library, composition
data information for one or two size intervals were not reported. To increase
the usefulness of the profiles, certain assumptions were employed to fill
these data gaps.
If data were reported for a single size interval, it was assumed
that data for the other two intervals were the same. Values for
the 0-10 urn size interval were also assumed to be the same.
If data for the 0-2.5 urn size interval were missing, it was
assumed the data for the 2.5-10 urn size interval could be
substituted and vice versa. Values for the 0-10 urn size interval
were also assumed to be the same.
If data for the total particulate measured were not reported,
assume the estimated data for the 0-10 urn size fraction can be
substituted.
Since the chemical composition of particulate emissions of many sources
is a function of particle size, application of data based on total particulate
measured to particulate mass in the fine particle fraction (0-2.5 urn) or
coarse particle fraction (2.5-10 urn) may affect the validity of the analysis.
Where such an assumption is made, it is indicated with a footnote in each
profile.
As pointed out in the Source Composition Library, the user/reader should
be aware of the potential variability in the chemical composition of
emissions, both within a source group and between similar sources. Due to
limited availability of high-quality, size-resolved profile data sets, an
16
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Indepth evaluation of the magnitude of profile variability is not possible.
However, comparisons of profiles based on literature on the total particulate
measured indicate that profile variability is dependent on the chemical
composition of fuels or process materials, volatility, and sampling and.
analytical procedures.
Profiles for individual sources may vary considerably from the values
provided in this document. Source-specific data from local sources are
therefore preferable to the use of literature data and are recommended,
particularly for regulatory applications. Nevertheless, preliminary analyses
based on source profiles in this document may be adequate to meet a number of
objectives. The reader/user must ultimately assess whether the data in the
document are appropriate for use in any particular application.
2.3 PM SPECIES PROFILE APPLICATION
There are several ongoing EPA activities that require speciated PM data
as an input parameter. These activities include preparation of air toxics
emission inventories, receptor modeling, preparation of acid precipitation
inventories, and acid precipitation modeling studies. This section briefly
discusses how to use this document. It also provides a specific example to
illustrate how to use PM species profiles in preparation of an air toxics
emission inventory.
2.3.1 Document Guide
In addition to the profiles contained In Section 3, this document
includes PM profile assignments for point and area source categories in
Appendix E, Tables E-l and E-2 in Appendix E contain the PM profile
assignments for point and area sources, respectively. To identify the
applicable profile for a given source category, the user/reader should refer
to Tables E-l and E-2. The actual profile is contained in Section 3 and its
location in Section 3 can be identified from a numerical listing in Table A-l
in Appendix A.
17
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2.3.2 Example of Use of a Profile
A hypothetical example will be used to describe how profiles might be
applied: a State air-pollution control agency is developing an air toxics
emission inventory for the State. An earlier study conducted for the State
has identified a list of potentially toxic species from several emission
sources. The emission rates of these individual species will be used as an
input to the proposed air toxics regulatory program for the State. The
proposed program advocates regulating particulate species 1n the fine fraction
(i.e., <2.5 urn).
The PM profiles can identify the relative amounts of individual
particulate species within specified size intervals in a given emission
stream. In most cases, emission factors are available for total particulate
matter where the elemental breakdown is not specified (e.g., AP-42, Criteria
Pollutant Emission Factor Document). The information contained in this
document supplements the general emissions data in AP-42 or the Criteria
Pollutant Emission Factor Document.1'2 For a given source category, the
appropriate PM species profile should be identified using Appendix E and the
total particulate emission factor should be multiplied by the weight fractions
for each species in a given size interval as given in the profile to determine
size-specific individual emission factors.
In this example, cadmium is one of the species on a State's list and
emissions from a municipal waste incinerator are of concern. The incinerator
burns routine residential and commercial refuse and is uncontrolled. Since
the species profiles are keyed off of SCC, the first task is to determine the
SCC for the municipal waste incinerator. The SCC and PM emission factor for a
specific category can ue obtained from the National Emissions Data System
(NEDS) or the Criteria Pollutant Emission Factor Document. These materials
would indicate that the appropriate SCC for municipal incinerators is 5-01-
001-01. The reader/user can then refer to the SCC/profile list in Appendix E
to identify which profiles correspond to the subject SCC. For 5-01-001-01,
three profiles, 17106, 17107 and 17108, are listed in Appendix E and the
document page numbers of each are given. At this point, the reader/user
should review all of the candidate profiles to see which best corresponds to
the particular source in question. A review of the "Control Device" field
18
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shows that there is only one profile specifically for uncontrolled
incincerators. This would be Profile 17108. A review of the "Species" field
indicates that cadmium is contained in the profile. If there had been more
than one profile applicable to this situation, the reader/user could have
consulted the "Data Source" field for more refined Information on which to
made a profile selection, or the original references(s) on which the profiles
were based could be consulted. In cases with multiple potentially applicable
profiles, the "Data Quality" field may also be useful in selecting the most
preferred profile.
In Profile 17108, the weight percentage of cadmium (Cd) under the "0-2.5
urn" column is 0.110 and the fraction of mass associated with this size
interval is 0.26. Applying the weight fraction of cadmium to the total
particulate emissions of 1,500,000 Ib/yr for the incinerator, cadmium
emissions in the fine fraction are estimated as 1,500,000 x 0.0011 x 0.26 =
429 Ib/yr. The uncertainty associated with the cadmium weight percentage is
reported as 0.060 percent in the profile. From this information, a range for
cadmium emissions can be specified as follows:
1,500,000 x 0.26 x (0.0011 - 0.0006) - 195 Ib/yr
1,500,000 x 0.25 x (0.0011 + 0.0006) « 663 Ib/yr
Thus, the annual cadmium emissions in the 0-2.5 urn size range may be expected
to range from 195 to 662 Ib/yr, with a mean of 429 Ib/yr.
19
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2.4 REFERENCES FOR SECTION 2
1. U. S. Environmental Protection Agency. Criteria Pollutant Emission
Factors for the 198S NAPAP Emissions Inventory. EPA-6QQ/7-87-Q15.
Office of Research and Development, Air and Energy Engineering Research
Laboratory, Research Triangle Park, North Carolina. May 1987.
2. U. S. Environmental Protection Agency. Compilation of Air Pollutant
Emission Factors, AP-42. Fourth Edition. Office of Air Quality
Planning and Standards, Research Triangle Park, North Carolina.
September 1985; Supplement A, October 1986; Supplement B, September
1988.
20
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SECTION 3
PM SPECIES PROFILES - POINT AND AREA SOURCES
This section contains the 302 PM profiles grouped In 20 separate
subsections according to source categories. The profiles representing point
sources are presented first, followed by those representing area sources. The
following 11st can be used to identify and locate the profiles for each source
category group. Individual profiles within each source category group are
presented in numerical order.
POINT SOURCES
SECTION 3.1
Profile 11201
Profile 11202
Profile 11203
Profile 11204
Profile 11205
Profile 11206
Profile 11207
Profile 11208
Profile 11209
Profile 11210
Profile 11211
Profile 11212
Profile 11213
Profile 11214
Profile 11215
Profile 11301
Profile 11501
Profile 11502
Profile 11503
Profile 11504
Profile 11505
Profile 11506
Profile 11507
Profile 11508
Profile 11509
Profile 11510
Profile 11801
Profile 12201
Profile 12301
Profile 12704
Profile 12705
Profile 13501
Page Number
EXTERNAL COMBUSTION BOILERS
Coal-Fired Power Plant 30
Coal-Fired Power Plant 32
Coal-Fired Power Plant 34
Coal-Fired Power Plant 35
Coal-Fired Power Plant 37
Coal-Fired Power Plant 38
Coal-Fired Power Plant 39
Coal-Fired Power Plant 40
Coal-Fired Power Plant 41
Coal-Fired Power Plant 42
Coal-Fired Power Plant 43
Coal-Fired Power Plant 44
External Combustion - Coal-Fired Composite 45
Uncontrolled Coal-Fired Power Plant Composite 46
Coal-Fired Power Plant/ESP Composite 47
Coal and RDF-Fired Power Plant 48
Oil-Fired Power Plant 50
Oil-Fired Power Plant 52
Oil-Fired Power Plant 54
Oil-Fired Power Plant 56
Oil-Fired Power Plant 58
Oil-Fired Power Plant 60
Oil-Fired Power Plant 62
Oil-Fired Power Plant 64
Oil-Fired Power Plant 65
Oil-Fired Power Plant Composite 67
Wood-Fired Boiler 68
Coal-Slurry Fired Boiler 70
Kerosene-Fired Boiler Composite 72
Wood-Fired Boiler 73
Wood-Fired Boiler Composite 75
Residual Oil Combustion 76
21
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POINT SOURCES (Continued)
Page Number
SECTION 3.1 - EXTERNAL COMBUSTION BOILERS (Continued)
Profile 13502 - Heavy Oil-Fired Boiler Composite 78
Profile 13503 -.Indonesian Oil-Fired Boiler Composite 79
Profile 13504 - Oil-Fired Boiler 80
Profile 14101 - External Combustion - Waste Oil-Fired Boiler 81
Profile 14102 - External Combustion - Liquid Waste-Fired Boiler 82
Profile 15101 - External Combustion - Solid Waste-Fired Boiler 83
Profile 43303 - Coal-Fired Power Plant Flyash 84
SECTION 3.2 - CHEMICAL MANUFACTURING
Profile 25302 - Charcoal Manufacturing 89
Profile 25404 - Urea Fertilizer Production 91
Profile 25405 - Boric Acid Manufacturing 93
Profile 25407 - Phosphorous Plant Plume 95
Profile 25408 - Fertilizer Production - Phosphate Rock Dust 97
Profile 25409 - Ammonium Nitrate - Prill Tower 99
Profile 25410 - Ammonium Sulfate Production 100
Profile 25411 - Diammonium Phosphate Plant 101
Profile 25412 - Superphosphate Plant 103
Profile 25413 - Superphosphate Granulation 105
Profile 25414 - Sodium Tripolyphosphate - Cyclone Dust 107
Profile 25415 - NPK Fertilizer 109
FOOD AND AGRICULTURE
Feed and Grain Handling Dust 113
PRIMARY METAL PRODUCTION
Primary Lead Smelting - Ore Concentrate 117'
Primary Lead Smelting - Ore Concentrate 119
Composite
Primary Lead Smelting - Materials 121
Handling
Primary Lead Smelting - Speiss Fugitive 123
Dust
Primary Lead Smelting - Soda Flux 125
Fugitive Dust
Profile 21301 - Copper Ore Crushing 127
Profile 21302 - Copper Ore Mill Wastepile 129
Profile 21303 - Copper Ore Concentrate 131
Profile 21304 - Copper Mining Waste 133
Profile 21320 - Copper Ore Processing Composite 135
Profile 21340 - Composite of Copper Ore Concentrate and 137
Mining Waste
Profile 21501 - Primary Lead Smelting - Slag Dust 139
Profile 28301 - Steel Production - Steel Sinter Plant 141
Profile 28302 - Steel Production - Open Hearth Furnace 143
Profile 28303 - Steel Production - Basic Oxygen Furnace 145
Profile 28304 - Iron Ore Dust - Sinter 147
Profile 28306 - Steel Desulfurization Baghouse Dust 148
Profile 28307 - Steel Production - Basic Oxygen Furnace 149
SECTION 3.3 -
Profile 21401 -
SECTION 3.4 -
Profile 21102 -
Profile 21103 -
Profile 21150 -
Profile 21205 -
Profile 21206 -
22
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POINT SOURCES (Continued)
Page Number
SECTION
Profile
Profile
Profile
Profile
Profile
3.4
28401
29101
29102
29202
29203
Profile 29204 -
Profile 29205 -
Profile 29206 -
Profile 29207 -
Profile 29208 -
Profile 29209 -
Profile 29210 -
Profile 29211 -
Profile 29301 -
Profile 29302 -
Profile 29303 -
Profile 29304 -
Profile 29305 -
Profile 29306 -
Profile 29307 -
Profile 29309 -
Profile 29310 -
Profile 29311 -
Profile 29330 -
SECTION 3.5
Profile 19101 -
Profile 20101 -
Profile 20102 -
Profile
Profile
Profile
Profile
Profile
Profile
ProfiIt
Profile
Profile
Profile
Profile
Profile
20103
20401
20402
20403
20404
20405
20406
20501
205Q2
20503
28201
28202
PRIMARY METAL PRODUCTION (Continued)
Ferromanganese Furnace
Aluminum Processing
Aluminum Reduction Potline
Primary Copper Smelter
Primary Copper Reverberatory Furnace -
Slag Tap
Primary Copper Reverberatory Furnace -
Slag Skim and Pour
Primary Copper Converter - Secondary Hood
Primary Copper Converter - Secondary Hood
Primary Copper Flash Furnance - Matte and
Slag Tap
Primary Copper - Process Stack
Primary Copper - Roaster
Primary Copper Reverberatory Furnace
Fugitives Composite
Primary Copper Converter - Secondary Hood
Composite
Primary Lead Smelting
Primary Lead Smelting
Primary Lead Smelting
Primary Lead Smelting
Primary Lead Smelting
Slag Pouring
Blast Furnace
Zinc Fuming
Sintering
Blast Furnace
Zinc Baghouse
Dross Reverberatory
Upset
Primary Lead Smelting
Primary Lead Smelting
Furnace
Primary Lead Smelting - Sinter Production
Primary Lead - Dross Building
Primary Lead - Slag Pour
Primary Lead Smelting - Composite
SECONDARY METAL PRODUCTION
Scrap Copper Incinerator
Aluminum Foundry - Reverberatory Furnace
Secondary Aluminum Plant - Dross Recovery
Furnace
Secondary Aluminum - Dross Recovery Furnace
Secondary Lead Smelter - Blast Furnace
Secondary Lead - Sanitary Baghouse
Secondary Lead - Reverberatory Furnace
Secondary Lead - Melting Pot Fugitives
Secondary Lead - Melting Pot Stack
Secondary Lead - Yard Dust
Zinc Oxide Kiln
Antimony Oxide Plant - Antimony Roasting
Antimony Oxide Plant - Antimony Roasting
Cast Iron Induction Furnace
Cast Iron Cupola
151
153
155
157
159
160
161
162
163
164
165
166
167
168
170
172
174
176
178
180
182
184
185
186
191
193
195
197
198
200
201
202
203
204
205
207
209
210
212
23
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POINT SOURCES (Continued)
Paoe Number
SECTION 3.5
Profile 28305
Profile 28601
Profile 29201
Profile 29501
Profile 29502
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profi1e
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
SECTION
Profile
Profile
Profi 1 e
Profile
Profile
Profile
Profile
Profi1e
Profile
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
3.6
21101
21203
21204
25201
25401
25402
25406
27102
27201
27203
27204
27205
27501
27502
27503
27601
27602
3.7
26101
26202
26203
26204
26205
26206
26207
26208
26209
3.8
22101
22102
22201
22202
22301
23103
23202
24101
SECTION 3.9
Profile 25403
SECONDARY METAL PRODUCTION (Continued)
Steel Electric Arc Furnace 214
Steel Foundry - Steel Heat Treating 216
(Salt Quench)
Copper Oxide Kiln 218
Secondary Copper Pyrometal - Cathode Charge 220
Secondary Copper Pyrometal - Regular Charge 221
MINERAL PRODUCTS
Limestone Dust 225
Coke Dust 227
Coal Dust 229
Calcium Carbide Furnace 231
Silica Manufacturing 233
Asphalt Roofing Manufacturing 235
Carborundum Manufacturing 237
Glass Furnace 239
Cement Kiln (Gas-Fired) 241
Cement Kiln (Coal-Fired) 243
Portland Cement Dust 245
Cement Ball Mill 246
Gypsum Calciner 247
Gypsum Handling 249
Gypsum Kiln 250
Lime Handling 251
Lime Kiln 252
PETROLEUM INDUSTRY
Refinery Process Heaters (Gas) 255
Petroleum Refinery Catalytic Cracker 257
Petroleum Refinery Catalytic Cracker 259
Petroleum Refinery Catalytic Cracker 261
Petroleum Refinery Catalytic Cracker 262
Coke Calciner 264
Green Coke Dust 265
Coke Cooler 267
Catalytic Cracker Composite 269
PULP AND PAPER INDUSTRY
Particleboard Dryer 273
Particleboard Dryer 275
Wood Products - Sanderdust 277
Sawdust 279
Veneer Dryer 281
Kraft Recovery Furnace 283
Lime Kiln 285
Suit He Recovery Boiler 287
SURFACE COATING OPERATIONS
Paint Spray Booth 291
24
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POINT SOURCES (Continued)
Page Number
SECTION
Profile
Profile
Profile
Profi1e
Profile
Profile
Profile
Profile
Profile
Profile
3.10
17105
17106
17107
17108
17109
17120
17121
17122
17123
17124
SECTION 3.11
Profile 25701
Profile 25702
Profile 25703
AREA SOURCES
SECTION 3.12
Profile 44101
Profile 44102
Profile 44103
Profile 44104
SECTION 3.13
Profile 41201
Profile 41203
Profile 41204
Profile 41205
Profile 41220
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
3.14
41101
41102
41103
41104
41105
41106
41107
41109
41110
41111
41112
41113
41114
41115
41116
41117
41118
SOLID WASTE DISPOSAL
Municipal Incinerator (Philadelphia)
Municipal Incinerator Composite
Municipal Incinerator (East Chicago, IN)
Municipal Incinerator (Philadelphia)
Car Shredder
Sewage Sludge Incineration - Composite
Sewage Sludge Incineration
Sewage Sludge Incineration
Sewage Sludge Incineration
Sewage Sludge Incineration
METAL FABRICATION
Metal Fabrication
Metal Fabrication
Metal Fabrication
Galvanizing (Zno)
Sandblasting
Welding
HEAVY CONSTRUCTION
Excavation - El Segundo, CA
Excavation - Haul Road
Rock Crushing
Sandblasting and Plastering
UNPAVED ROADS
Unpaved Road Dust (Copper Mine)
Unpaved Road Dust - Haul Road
Unpaved Road Dust - East Helena, Montana
Unpaved Road Dust - Riverside, CA
Unpaved Road Dust Composite
PAVED ROADS
Paved Road Dust - Missoula, Montana
Paved Road Dust - Juneau, Alaska
Paved Road Dust - Lewiston, Idaho
Paved Road Dust - Butte, Montana
Paved Road Dust - East Helena, Montana
Paved Road Dust - Medford, Oregon
Paved Road Dust - Portland, Oregon
Paved Road Dust - Alabama
Paved Road Dust - Spokane, Washington
Paved Road Dust - Pasadena Fwy (CA)
Paved Road Dust - Artesia Fwy (CA)
Paved Road Dust - Long Beach Blvd (CA)
Paved Road Dust - Long Beach (CA)
Paved Road Dust - La Cienega Blvd (CA)
Paved Road Dust - Hawthorne, CA
Paved Road Dust - Victory Blvd (CA)
Paved Road Dust - Burbank, CA
295
297
299
300
302
303
305
307
309
311
315
316
317
321
322
323
324
327
329
331
332
333
337
339
341
343
345
346
348
350
352
354
356
357
358
360
361
362
363
25
-------
AREA SOURCES (Continued)
Page Number
SECTION 3.14
Profile 41119
Profile 41120
Profile 41121
Profile 41122
Profile 41123
Profile 41124
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profi1e
Profile
41130
41131
41132
41133
41134
41135
41136
41137
41401
3.15
41301
41302
41303
41304
41305
41306
41307
41308
41309
41310
41311
41312
41313
41314
41315
41316
41318
41319
41320
41321
41322
41323
41324
41350
41351
43101
43301
43304
43305
43306
PAVED ROADS (Continued)
Paved Road Dust - North Main Street
(Los Angeles, CA)
Paved Road Dust - Los Angeles, CA
Paved Road Dust -
Paved Road Dust -
Paved Road Dust -
Paved Road Dust -
(Los Angeles, CA)
Paved Road Dust -
Paved Road Dust -
Paved Road Dust -
Paved Road Dust -
South Harbor Blvd
Anaheim, CA
Riverside, CA
Sepulveda Tunnel
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Composite
Composite
Long Beach Composite
Hawthorne Composite
Burbank Composite
Los Angeles Composite
Anaheim Composite
SCAB Composite
- Road Sand and Salt Mix
- NATURAL SOURCES
- Soil Dust - Des Moines, Iowa
- Soil Dust - Seattle, Washington
- Soil Dust - Visalia, California
- Soil Dust - South Bend, Indiana
- Soil Dust - Houston, Texas
- Soil Dust - East Helena, Montana
- Soil Dust - Idaho
- Soil Dust - Creston, Iowa
- Soil Dust - Council Bluffs, Iowa
- Soil Dust - Sioux City, Iowa
- Soil Dust - Cedar Rapids, Iowa
- Soil Dust - Davenport, Iowa
- Soil Dust - Spokane, Washington
- Soil Dust - Boise, Idaho
- Soil Dust - Bakersfield, California
- Soil Dust - Pasedena, California
- Soil Dust - Medford, Oregon
- Soil Dust - Portland, Oregon
- Soil Dust - Alabama
- Soil Dust - Laurel, MD
- Soil Dust - Washington, DC Area
- Soil Dust - Riverside, CA
- Soil Dust - Hawthorne, CA
- Soil Dust - Composite
- Soil Dust - SCAB Composite
- Marine Aerosol
- Volcanic Ash
- Limestone, Crustal
- Shale, Crustal
- Sandstone, Crustal
365
367
368
369
370
372
374
376
377
378
379
380
381
382
384
389
391
393
395
397
399
401
403
405
407
409
411
413
415
417
419
421
423
425
427
428
429
430
431
433
434
436
438
439
440
26
-------
AREA SOURCES (Continued)
Page Number
SECTION 3.15
Profile 43307
Profile 43308
Profile 43309
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
3.16
42101
42102
42103
42201
42202
42303
42305
42306
42307
42308
42309
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
42313
42314
42315
42316
42317
42318
42319
42330
SECTION 3.17
Profile 42301
Profile 42302
Profile 42304
Profile 42320
NATURAL SOURCES (Continued)
Sediment, Crustal
Igneous, Rock
Earth's Crust
WOOD COMBUSTION
Woodstoves - Pine Fuel
Woodstoves
Woodstoves
Fireplaces
Fireplaces
Profile 42310 -
Profile 42311 -
Profile 42312 -
Average, All Fuels
Oak Fuel
Softwoods
Hardwoods
Residential Wood Combustion - Composite
Slash Burning (Conifer - Flaming Phase)
Slash Burning (Conifer - Smoldering Phase)
Slash Burning (Hardwood
Slash Burning (Hardwood
Slash Burning (Ponderosa Pine
Phase)
Slash Burning (Ponderosa Pine - Smoldering
Flaming Phase)
Smoldering Phase)
Flaming
Phase)
Slash Burning (Tractor Piled
Slash Burning (Tractor Piled
Phase)
Slash Burning (Crane Piled
Slash Burning (Crane Piled
Flaming Phase)
Smoldering
Flaming Phase)
Smoldering Phase)
Slash Burning (Chaparral - Flaming Plase)
Slash Burning (Chaparral - Smoldering Phase)
Wood Combustion - Las Vegas Valley (1987)
Residential Wood Combustion
Residential Wood Combustion Composite
Composite of Residential Wood Burning
Sources
AGRICULTURAL FIELD BURNING
Slash Burning
Slash Burning
Agricultural Field Burning
Agricultural Field Burning Composite
441
442
443
447
449
451
453
455
457
459
460
461
462
463
464
465
466
467
468
469
470
471
472
473
474
478
480
482
484
SECTION 3.18 - MOBILE SOURCES
Profile 31101 - Light-Duty Vehicles
Profile 31102 - Heavy-Duty Vehicles
Profile 31103 - Light-Duty Vehicles
Profile 31104 - Light-Duty Vehicles
Profile 31105 - Light-Duty Vehicles
Profile 31201 - Light-Duty Vehicles
Profile 31202 - Light-Duty Vehicles
Profile 31203 - Light-Duty Vehicles
Profile 31230 - Light-Duty Vehicles
Leaded
Leaded
Leaded
Leaded
Leaded Composite
Unleaded
Unleaded
Unleaded
Composite
489
491
493
495
497
498
500
502
504
27
-------
AREA SOURCES (Continued)
Page Number
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
3.18
32101
32102
32103
32104
32202
32203
32204
32205
32206
33001
33002
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
33004
33005
33006
33007
33008
33009
33010
33011
33020
34002
34003
34004
34005
34005
SECTION 3.19
Profile 34001
SECTION 3.20
Profile 43201
Profile 43302
MOBILE SOURCES (Continued)
Light-Duty Vehicles
Light-Duty Vehicles
Light-Duty Vehicles
Light-Duty Vehicles
Heavy-Duty Diesel
Heavy-Duty Vehicles
Heavy-Duty Vehicles
Diesel
Diesel
Diesel
Diesel Composite
Profile 33003 -
Diesel
Diesel
Diesel Vehicles - Las Vegas Valley (1987)
Heavy-Duty Vehicles - Diesel Composite
Leaded/Unleaded Gasoline Composite - 1977
Transportation Composite - Medford, Oregon
(1980)
Transportation Composite - Portland,
Oregon (1979)
Transportation Composite
Transportation Composite
Transportation Composite
Transportation Composite
Transportation Composite
Transportation Composite
Gasoline Vehicles - Las Vegas Valley (1987)
Highway Vehicles Composite
Transportation Composite
Tire Wear
Tire Wear
Brake Lining, Asbestos
Motor Oil
Semi-metal Disk Brake Pads
AIRCRAFT
Jet Aircraft
OTHER SOURCES
Residential Space Heating - Coal
Orchard Heating - Smudge Pots
506
508
510
512
513
515
517
518
519
520
522
524
526
528
530
532
534
536
538
539
541
543
545
546
547
548
551
554
556
28
-------
3.1 EXTERNAL COMBUSTION BOILERS
External combustion sources include utility, industrial, commercial and
institutional boilers; commercial and domestic combustion units; process
heaters, furnaces, and kilns. Coal, oil, and natural gas are the major fossil
fuels used by these sources.
29
-------
PH Profile Speeiation Report
Profile Name Coal-Fired Power
Profile Number 11201
Data Quality B/D
Plant
Control Device ESP
Referenee(s) 52 •
Data Source Dilution train samples.
nine.
SCC Assignments: 10100201
Hass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Hatter -
Spccicc
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-15-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31 -S
7440-36-0
7440-46-2
Nun
4
5
9
11
12
13
14
15
16
17
10
20
21
22
23
24
25
*>'
£_W
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Sym
Be
B
F
Na
Hg
Al
Si
P
S
ct
If
Ca
Sc
Ti
V
Cr
Hn
I t_
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
15
23
0
3
0
1
1
0
0
0
0-2
Xwt
NA
NA
NA
NA
NA
.679
.837
.620
.305
.094
.304
.235
<
.967
.079
.058
0-043
8
0
0
0
0
0
0
0
0
0
0
0
0
0
,491
<
.049
.031
.069
.027
<
.081
.036
.000
,009
.124
.076
.022
.012
.000
NR
<
.5 in
unc
0.000
0.000
0.000
0.000
0.000
0.789
1.192
0.114
0.180
0.041
0.069
0.080
0.000
0.050
0.007
0.004
0.003
0.428
0.000
0.004
0.003
0.005
0.003
0.000
0.006
0.003
0.007
0.002
0.007
0.003
0.010
0.013
0.020
0.000
0.000
Representative
: (0-2.5)
0.290
2.5-10 urn
Xwt
NA
NA
NA
NA
NA
14.205
22.872
0.279
0.656
0.102
1.436
1.514
<
1.008
0.066
0.051
0.046
9.524
<
0.032
0.027
0.045
0.021
<
0.036
0.005
0.000
0.012
0.159
0.035
0.002
0.000
0.011
NR
<
unc
0.000
0.000
0.000
0.000
0.000
0.742
1.191
0.060
0.043
0.013
0.076
0.080
0.000
0.053
0.006
0.003
0.003
0.496
0.000
0.002
0.002
0.003
0.002
0.000
0.003
0.001
0.002
0.001
0.009
0.007
0.004
0.006
0.008
0.000
0.000
sample from set of
(0-6)
0.500
0-10 urn
Xwt
HE
NE
NE
NE
NE
14.843
23.290
0.427
1.803
0.099
1.379
1.393
NE
0.990
0.072
0.054
0.045
9.077
NE
0.039
0.029
0.055
0.024
NE
0.055
0.018
0.000
0.011
0.144
0.053
0.011
0.005
0.006
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
1.377
2.150
0.070
0.221
0.020
0.127
0.129
0.000
0.091
0.007
0.005
0.004
0.831
0.000
0.004
0.003
0.006
0.003
0.000
0.006
0.003
0.003
0.001
0.013
0.006
0.005
0.006
0.009
0.000
0.000
(0-10)
0.670
. Total
Measured
%wt
NE
NE
NE
NE
NE
14.843
23.290
0.427
1.803
0.099
1.379
1.393
NE
0.990
0.072
0.054
0.045
9.077
NE
0.039
0.029
0.055
0.024
NE
0.055
0.018
0.000
0.011
0.144
0.053
0.011
0.005
0.006
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.odo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
30
-------
PH Profile Speciation Report - continued (profile 11201)
Total Paniculate Hatter -
0-2
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
Nun Sym
56
58
80
62
201
202
203
204
Ba
Ce
Hg
Pb
OC
EC
504
N03
Xwt
0.000
<
0.000
0.036
NA
NA
NA
NA
56.284
.5 urn
unc
0.098
0.000
0.006
0.006
0.000
0.000
0.000
0.000
2.5-
Xut
0.098
<
<
0.025
NA
NA
NA
NA
52.267
10 urn
unc
0.040
0.000
0.003
0.003
0.000
0.000
0.000
0.000
0-10 un
Xwt
0.056
NE
NE
0.030
NE
NE
NE
NE
54.008
unc
0
0
0
0
0
0
0
0
.046
.000
.000
.004
.000
.000
.000
.000
Total
Measured
Xwt
0.056
NE
NE
0.030
NE
NE
NE
NE
54.008
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
31
-------
PH Profile Speciation Report
Profile Name
Profile Number
Data Quality
: Coal-Fired Power Plant
: 11202
: D
Control Device : UncontrclledCO
Reference(s) : 62,63
Data Source : Data taken fros Reference 62. For details, consult Referene
63.
SCC Assignments: 10100201
Mass Fraction Data • size Interval Cum)
Mass Fraction
Total Partfculate Matter
Species
CAS Number Hum Sym
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-00-8
7440-19-9
7440-53-1
7440-54-2
7440-27-9
11
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
40
42
55
56
57
58
60
62
63
64
65
Ha
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fc
CO
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Zr
NO
Cs
Ba
La
Ce
Nd
Sm
Eu
Cd
Tb
*"
0-2
Xut
0
13
m
0
3
0
1
1
0
1
0
0
0
7
0
0
0
0
0
0
0
0
0
Q
0
0
0
0
0
0
0
0
0
.300
.400
.800
.620
.400
.020
.200
.400
.004
.100
.051
.036
.028
.200
.009
.038
.029
.039
NR
.061
.024
.003
.018
.129
.063
.017
.001
.300
.011
.017
.007
.002
.001
NR
.000
.5 urn
unc
0.020
1.500
1.600
0.060
0.600
0.011
0.090
0.500
0.000
0.100
0.014
0.012
0.001
0.400
0.001
0.005
0.002
0.005
0.000
0.008
0.002
0.001
0.008
0.006
0.014
0.006
0.000
0.190
0.001
0,001
0.002
0.000
0.000
0.000
0.000
: CO-2.5}
: 0.060
2.5-10 urn
Xut
0.410
18.400
18.500
0.220
0.540
0.103
1.330
2.300
0.004
1.300
0.043
0.019
0.022
8.100
0.008
0.032
0.024
0.028
0.016
0.020
0.002
0.001
0.012
0.123
0.042
0.007
0.001
0.094
0.013
0.019
0.007
0.003
0.001
0.004
0.000
une
0.020
2.700
2.800
0.040
0.070
0.005
0.080
0.300
0.000
0.200
0.009
0.001
0.001
0.400
0.000
0.002
0.001
0.002
0.006
0.007
0.000
0.001
0.001
0.025
0.014
0.001
0.000
0.016
0.001
0.001
0.001
0.000
0.000
0.002
0.000
<0-6)
0.170
0-10
Xut
0.381
17.096
19.361
0.324
1.286
0.081
1.296
2.065
0.004
1.248
0.045
0.023
0.024
7.865
0.008
0.034
0.025
0.031
NE
0.031
0.008
0.001
0.013
0.125
0.047
0.010
0.001
0.148
0.013
0.018
0.007
0.002
0.001
NE
0.000
umCZj
unc
0.021
1.591
1.761
0.035
0.204
0.006
0.075
0.217
0.001
0.119
0.007
0.004
0.002
0.411
0.001
0.003
0.002
0.003
0.000
0.005
0.001
0.000
0.003
0.015
0.009
0.002
0.000
0.052
0.002
0.002
0.001
0.001
0.000
0.000
0.000
CO-10)
0.230
Total
Measured
Xwt
0.382
17.104
19.356
0.324
1.282
0.082
1.296
2.067
0.004
1.248
0.045
0.023
0.024
7.867
0.008
0.034
0.025
0.031
0.012
0.031
0.008
0.001
0.013
0.125
0.047
0.010
0.001
0.147
0.013
0.018
0.007
0.002
0.001
0.003
0.000
unc
0.020
2.114
2.246
0.038
0.189
0.005
0.078
0.265
0.000
0.157
0.008
0.003
0.001
0.418
0.001
0.002
0.001
0.002
0.005
0.006
0.001
0.001
0.002
0.019
0.011
0.002
0.000
0.051
0.001
0.001
0.001
0.000
0.000
0.001
0.000
32
-------
PM Profile Speciation Report - continued (profile 11202}
Total Participate Natter -
0-2.5 urn 2.5-10 un 0-10 umC2>
Total
Measured
Species •
CAS Number Hum Sym %ut unc %ut unc Xut
unc
Xut
unc
7440-64-4
7439-94-3
7440-58-6
7440-25-7
7440-33-7
7439-92-1
7440-29-1
70
71
72
73
74
82
90
201
203
Yb
Lu
Hf
Ta
W
Pb
Th
OC
S04
0
0
0
0
0
0
11
.001
NR
.001
NR
.002
.041
.002
.890
.900
0.000
0.000
0.000
0.000
0.001
0.004
0.000
0.120
0.600
0.001
0.000
0.001
0.000
0.001
0.026
0.003
2.000
2.400
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.100
0.200
0.001
NE
0.001
NE
0.002
0.030
0.003
1.710
4.878
0.000
0.000
0.000
0.000
0.001
0.003
0.001
0.088
0.482
0.001
0.000
0.001
0.000
0.002
0.030
0.003
1.712
4.863
0.000
0.000
0.000
0.000
0,000
0.002
0.000
0.095
0.397
TOTALS!
64.165
56.180
58.247
58.253
<1> No control specified; thus, assumed uncontrolled.
C2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
33
-------
PH Profi It Speciation Report
Profile Name
Profile Number
Data duality
Coal-Fired Power
11203
C
Plant
Control Device Cyclonic Precipitator
Refarence(s) 64,65
Data Source Sampled with an Andersen inpactor. Analyzed using AAS
AES, X-ray s'pectrometry, and spark-source MS.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.610 0.840
Total Participate Matter -
CAS Number
7440-41-7
7439-95-4
7429-90-5
7440-21-3
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7440-43-9
7440-31-5
7440-36-0
7440-28-0
7439-92-1
TOTALS:
&1/1ZI* ICO
Num Sym
4
12
13
14
16
19
20
22
23
24
25
to
27
28
29
30
33
34
48
50
51
81
82
200
Be
M9
At
Si
S
K
Ca
Ti
V
Cr
Mn
Fe
Co
Hi
CU
Zn
As
Se
Cd
Sn
Sb
Tl
Pb
TC
0-2.5 un
Xwt
0
0
13
27
40
3
3
1
0
0
0
15
0
0
• o
1
0
0
0
0
0
0
0
.006
.463
.600
.000
.933
.400
.400
.247
.050
.353
.050
.667
.013
.173
.030
.300
.180
.007
.004
.002
.006
.008
.163
0.640
108.695
KS=s:axBzssssr:=:s;ss:KS=s:
unc
0.000
0.093
2.720
5.400
2.047
0.170
0.170
0.062
0.008
0.071
0.002
3.133
0.004
0.035
0.006
0.390
0.036
0.001
0.001
0.000
0.002
0.002
0.033
0.128
SSBSESSES
2.5-10 urn
Xwt
0.004
1.064
18.948
31.714
11.096
4.653
4.653
1.182
0.026
0.069
0.020
13.741
0.008
0.054
0.034
0.838
0.089
0.002
0.002
0.001
0.003
0.005
0.135
0.669
unc
0.000
0.213
3.790
6.394
0.555
0.233
0.233
0.059
0.004
0.014
0.001
2.748
0.002
0.011
0.007
0.251
0.018
0.000
0.000
0.000
0.001
0.002
0.027
0.134
0-10
Xwt
0.005
0.804
16.633
29.674
24.011
4.111
4.111
1.210
0.036
0.192
0.033
14.575
0.010
0.106
0.032
1.038
0.128
0.004
0.003
0.001
0.004
0.006
0.147
0.656
89.010 97.530
umCl>
unc
0.005
0.157
2.998
5.273
2.735
0.342
0.342
0.111
0.010
0.044
0.009
2.530
O.OOS
0.02S
0.008
0.255
0.027
0.003
0.002
0.002!
0.003
0.004
0.029
0.118
, dc
(0-10)
0.930
Total
Measured
Xwt
0.005
0.958
18.004
30.882
16.362
4.432
4.432
1.193
0.030
0.119
0.025
14.081
0.009
0.075
0.033
0.919
0.106
0.003
0.002
0.001
0.003
0.006
0.140
0.664
92.484
unc
0.000
0.192
3.601
6.176
0.818
0.222
0.222
0.060
0.005
0.024
0.001
2.816
0.003
0.015
0.007
0.276
0.021
0.001
0.000
0.000
0.001
0.002
0.028
0.133
C1> Calculated based on methodology in the Air Emissions Species Manual, Volume II.
34
-------
PN Profile Speciation Report
Profile Name
Profile Number
Data Quality
i Coal*Fired Power Plant
: 11204
: C
Control Device : |SP
Reference(s) : 64,66
Data Source : Sampled with a SASS train. Analyzed using XRF, IHAA, and
MA.
SCC Assignments: 10100201
Mass Fraction Data - size Interval (urn)
Mass Fraction
Total Particulate Hatter
Species
CAS Number
7440-23-5
7429-90-5
7440-21-3
7704-34-9
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-53-1
7440-27-9
7440-64-4
7440-58-6
7440-25-7
Nun
11
13
14
16
19
20
21
22
24
25
26
27
28
29
30
31
32
33
34
35
37
38
48
50
51
55
56
57
58
62
63
65
70
72
73
Sym
Na
Al
Si
S
K
Ca
Sc
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Cd
Sn
Sb
Cs
Ba
La
Ce
Sfli
Eu
Tb
Yb
Hf
Ta
0-2.5 urn
%wt
0.
11.
17.
3.
1.
6.
0.
0.
0.
0,
10,
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
996
567
795
959
954
495
002
906
027
097
445
004
017
014
225
013
018
NR
001
NR
014
148
m
002
002
001
722
010
015
002
000
000
001
000
000
unc
0.286
6.345
9.090
1.521
0.442
1.191
0.000
0.227
0.009
0.027
1.393
0.001
0.003
0.004
0.029
0.004
0.005
0.000
0.000
0.000
0.002
0.021
0.000
0.000
0.001
0.000
0.095
0.003
0.005
0.000
0.000
0.000
0.000
0.000
0.000
: CO
: 0
-2.5)
.290
2.5-10 urn
Xut
0.853
11.597
22.000
1.126
1.740
8.418
0.002
0.702
0.018
0.077
10.754
0.003
0.011
0.009
0.136
0.006
0.012
0.005
0.000
0.000
0.010
0.135
0.001
0.002
0.002
0.001
0.410
0.008
0.013
0.001
0.000
0.000
0.000
0.001
0.000
unc
0.200
4.237
7.996
0.420
0.311
1.100
0.000
0.157
0.003
0.017
0.995
0.001
0.001
0.002
0.013
0.002
0.003
0.001
0.000
0.000
0.001
0.019
0.000
0.001
0.001
0.000
0.039
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.500
0-10
Xwt
0.915
11.584
20.180
2.352
1.833
7.586
0.002
0.790
0.022
0.086
10.620
0.003
0.014
0.011
0.175
0.009
0.015
NE
0.000
NE
0.012
0.141
NE
0.002
0.002
0.001
0.545
0.009
0.014
0.001
0.000
0.000
0.000
0.001
0.000
(0-10)
0.670
Total
um{1> Measured
unc
0.197
4.010
6.728
0.759
0.318
1.043
0.002
0.160
0.008
0.021
1.196
0.002
0.005
0.005
0.027
0.005
0.006
0.000
0.001
0.000
0.004
0.023
0.000
0.002
0.002
0.001
0.074
0.004
0.005
0.002
0.000
0.000
0.001
0.000
0.000
Xwt
0.864
11.579
21.683
1.339
1.756
8.273
0.002
0.717
0.019
0.078
10.731
0.003
0.012
0.009
0.143
0,007
0.013
NR
0.000
NR
0.010
0.136
Ni
0.002
0.002
0.001
0.434
0.008
0.013
0.001
0.000
0.000
o.ooo
0.001
0.000
unc
0.186
3.947
7.426
0.405
0.289
1.022
0.000
0.146
0.003
0.016
0.926
0.001
0.001
0.002
0.013
0.001
0.003
0.000
0.000
0.000
0.001
0.018
0.000
0.001
0.001
0.000
0.036
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
35
-------
PH Profile Speefation Report - continued (profile 11204}
Total Participate Hatter -
Species
CAS Ntnfcer
7440-33-7
7439-92-1
7440-29-1
7440-61-1
Hum
74
82
90
52
Syro
U
Pb
Th
u
0-2
Xwt
0.001
0.114
0.002
0.001
.5 tan
unc
0.000
0.016
0.001
0.000
2.5-10
%Mt
0.001
0.075
0.002
0.001
urn
unc
0
0
0
0
.000
.007
.001
.000
0-10
Xut
0.001
0.092
0.002
0.001
UmC1>
unc
0.001
0.016
0.002
0.001
Total
Measured
Xut
0.001
0.078
0.002
0.001
unc
0.000
0.007
0.000
0.000
TOmSs
55.170
58.132
57.021
C1> Calculated based on methodology described in the Air Emission
Volume II.
57.918
Species Manual,
36
-------
PM Profile Speciation Report
Profile Name Coal-Fired Power
Prof i le Number 11205
Data Quality C
Plant
Control Device ESP
Referenced) 64,67
Data Source Plant A sampled with EPA Method 5 and Andersen inpactor.
Analyzed using XRF and INAA.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction ; 0.290 0.500
Total Parti cut ate
Matter -
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-31-2
7782-49-2
7439-92-1
Nun Sym
11
12
13
14
16
19
20
22
23
24
25
26
28
29
30
33
34
82
Na
M8
Al
Si
S
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
Pb
TOTALS:
0-2
Xwt
0
1
10
17
0
1
0
0
0
0
0
2
0
0
0
0
0
0
.168
.656
.018
.120
,501
.136
.575
.614
.051
.064
.023
.330
.028
.023
.039
.062
.014
.016
.5 urn
unc
0.025
0.331
1.503
2.568
0.050
0.170
0.058
0.092
0.005
0.013
0.003
0.350
0.007
0.003
0.006
0.009
0.004
0.009
34.438
2.5-10 urn
%Mt
0.384
3.770
23.103
40.031
0.405
2.180
0.750
1.435
0.067
0.065
0.030
3.523
0.017
0.030
0.086
0.030
0.005
0.024
75.935
unc
0.059
0.479
3.535
6.108
0.135
0.573
0.215
0.261
0.009
0.021
0.010
0.708
0.007
0.008
0.026
0.010
0.002
0.008
0-10
gut
0.291
2.855
17.439
30.114
0.447
t.728
0.674
1.080
0.060
0.065
0.027
3.007
0.022
0.027
0.066
0.044
0.009
0.021
57.976
unCl>
unc
0.047
0.399
2.687
4.637
0.101
0.403
0.154
0.193
0.011
0.018
0.009
0.535
0.008
0.001
0.019
0.012
0.005
0.008
(0-10)
0.670
Total
Measured
%ut
0.316
3.103
18.971
32.796
0.435
1.850
0.146
1.176
0.062
0.065
0.040
3.146
0.020
0.028
0.071
0.040
0.008
0.022
unc
0.039
0.310
2.371
4.100
0.091
0.389
1.022
0.176
0.006
0.014
0.006
0.472
0.004
0.006
0.018
0.006
0.001
0.004
62.295
<1> Calculated based on methodology described in the Air Emission Species Manual,
Volume II.
37
-------
PH Profile Speeiation Report
Profile Name
Profile Number
Data Quality
Coal -Fired Power
11206
C
Plant
Control Device ISP
Reference(s) 64,67
Data Source Plant S sampled with EPA Method 5 and Andersen impactor.
Analyzed using XRF and INAA. •
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (un) : (0-2.5) (0-6)
Mass Fraction : 0.290 0.500
Total Particulate Matt
Species
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7439-92-1
TOTALS!
Nun Sym
11
12
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
34
82
Na
Mg
Al
Si
S
ct
K
Ca
Ti
V
Cr
Hn
Fe
Hi
Cu
In
As
Se
Pb
er -
0-2.5 un
Xut
0
0
4
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
13
.076
.673
.093
.550
.199
.051
.393
.234
.260
.020
.015
.015
.953
.010
.015
.015
.015
.010
.000
.597
unc
0.009
0.336
1.023
2.129
0.066
0.006
0.099
0.070
0.105
0.014
0,017
0.014
0.238
0.008
0.014
0.014
0.011
0.007
0.000
2.5-10 un
Xut
0.146
1.649
10.730
17.729
0.402
0.023
0.927
0.373
0.589
0.023
0.041
0.017
2.390
0.023
0.017
0.029
0.017
0.000
0.000
35.125
unc
0.025
0.716
9.702
15.948
0.634
0.022
0.235
0.179
0.292
0.029
0.035
0.030
0.911
0.028
0.030
0.028
0.029
0.014
0.000
0-10
Xut
0.116
1.227
7.857
12.890
0.314
0.035
0.696
0.313
0.447
0.022
0.030
0.016
1.768
0.017
0.016
0.023
0.016
0.004
0.000
um€1J
unc
0.021
0.501
6.420
10.569
0.419
0.017
0.169
0.125
0.201
0.021
0.025
0.021
0.621
0.019
0.021
0.020
0.020
0.010
0.000
25.807
(0-10)
0.670
Total
Measured
Xut
0.109
1.128
7.189
11.765
0.294
0.038
0.642
0.299
0.413
0.022
0.027
0.016
1.623
0.016
0.016
0.022
0.016
0.005
0.011
23.651
unc
0.011
0.282
4.493
7.353
0.033
0.009
0.096
0.075
0.124
0.011
0.014
0.012
0.406
0.012
0.012
0.011
0.012
0.005
0.005
{1> Calculated based on methodology described in the Air Emission Species Manual,
Volume II.
38
-------
PM Profile Specialion Report
Profile Name
Profile Number
Data Quality
Coal-Fired Power Plant
11207
C
Control Device : iSP
References) : 64,67
Data Source : Plant C sampled with EPA Method ! and Andersen impactor.
Analyzed using XRF and INAA.
SCC Assignments; 10100201
Mass Fraction Data •
Size Interval (urn)
Mass Fraction
Total Particulate Natter -
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21 -3
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7439-92-1
TOTALS:
opvi; i cb
Nun Sym
11
12
13
14
16
19
20
22
23
24
25
26
28
29
30
33
34
82
Na
US
Al
Si
S
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
In
As
Se
Pb
0
2
12
21
0
1
0
0
0-2.5 in
Swt
.231
.027
.030
.689
.362
.420
.636
.808
0.036
0
0
2
0
0
0
0
d
0
42
.041
.028
.690
.021
.027
.028
.034
.006
.009
.123
unc
0.058
0.507
3.308
5.422
0.109
0.403
0.184
0.173
0.008
0.014
0.008
1.009
0.004
0.008
0.008
0.009
0.002
0.008
s (0-2.5)
: 0.290
2.5-10 un
Xwt
0.366
3.021
15.144
25.945
0.327
1.112
0.562
1.173
0.036
0.026
0.006
3.192
0.021
0.018
0.028
0.002
0.003
0.036
unc
0.115
0.854
4.078
6.975
0.126
0.437
0.186
0.274
0.010
0.013
0.013
1.118
0.016
0.010
0.011
0.007
0.002
0.012
51.418
(0-6)
0.500
0-10 umCU
%Ht
0.308
2.591
13.796
24.103
0.342
1.472
0.594
1.015
0.036
0.032
0.016
2.975
0.021
0.022
0.028
0.016
0.004
0.024
47.395
unc
0.084
0.632
3.199
5.442
0.101
0.356
0.156
0.210
0.010
0.013
0.011
0.884
0.012
0.010
0.010
0.009
0.003
0.009
CO-103
0.670
Total
Measured
Xwt
0.310
2.607
13.847
24.172
0.342
1.473
0.593
1.021
0.036
0.033
0.015
2.983
0.021
0.022
0.028
0.015
0.004
0.025
unc
0.063
0.451
1.939
3.379
0.058
0.191
0.077
0.143
0.004
0.005
0.007
0.498
0.009
0.005
0.006
0.002
0.001
0.006
47.547
C1> Calculated based on methodology described in the Air Emission Species Manual,
Volume II.
39
-------
PM Profile Speciation Report
Profile Name Coal-Fired Power
Profile Number 11208
Data Quality E
Plant
Control Device ESP
Reference(s) 64,68
Data Source Samples collected isokinetically using bag filters. Analyzed
by AAS and XRF.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval CuiO : (0-2.5) (0-6)
Mass Fraction : 0.290 0.500
Total Paniculate Hatter
Species
CAS Number
7429-90-5
7439-89-6
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-36-0
7439-92-1
Hum
13
26
29
30
33
34
37
38
39
40
41
42
51
82
Sytn
Al
Fe
Cu
Zn
As
Se
Rb
Sr
Y
Zr
Nb
No
Sb
Pb
0-2.5
Xut
9.200
7.400
0.032
0.037
0.015
0.006
0.006
0.247
0.006
0.019
0.002
0.006
0.002
0.013
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.
5-10
%Ht
9.
7.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
200
400
032
037
015
006
006
247
006
019
002
006
002
013
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 unC1>
Xwt
9.200
7.400
0.032
0.037
0.015
0.006
0.006
0.247
0.006
0.019
0.002
0.006
0.002
0.013
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.670
Total
Measured
%Ht
9.200
7.400
0.032
0.037
0.015
0.006
0.006
0.247
0.006
0.019
0.002
0.006
0.002
0.013
unc
0.497
0.400
0.005
0.001
0.000
0.001
0.000
0.008
0.000
0.001
0.001
0,001
0.000
0.002
TOTALS: 16.991
C1> Estimated / extrapolated.
16.991
16.991
16.991
40
-------
PM Profile Specialion Report
Profile Name : Coal-Fired Power Plant
Profile Number : 11209
Data Quality : E
Control Device : Met Scrubber
Reference(s) : 64,68
Data Source : Samples collected tsokfnetically using alundum thimbles
backed up with wet inpinflers. AnIyzed by AAS and XRF.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn}
Mass Fraction
Total Partieulate Matter -
0-2.5 umm
CAS Number
7429-90-5
7439-89-6
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7440-17-7
7440-24-6
7440-65-S
7440-67-7
74400-30-1
7439-98-7
7440-36-0
7439-92-1
TOTALS:
Nun Sym
13
26
29
30
33
34
37
38
39
40
41
42
51
82
Al
Fe
CU
Zn
As
se
Kb
Sr
y
Zr
Nb
MO
Sb
Pb
Xwt
7
4
0
0
0
0
0
0
0
0
0
0
0
0
12
.400
.900
,029
.060
.028
.044
.003
.247
.003
.008
.002
.011
.002
.034
.771
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: CO-2.5)
: O.S10
2.5-10
Xwt
7.400
4.900
0.029
0.060
0.028
0.044
0.003
0.247
0.003
0.008
0.002
0.011
0.002
0.034
12.771
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<0-6>
0.620
0-10
Xwt
7.400
4.900
0.029
0.060
0.028
0.044
0.003
0.247
0.003
0.008
0.002
0.011
0.002
0.034
12.771
unC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-10J
0.710
Total
Measured
Xwt
7.400
4,900
0.029
0.060
0.028
0.044
0.003
0.247
0.003
0.008
0.002
0.011
0.002
0.034
12.771
unc
0.999
0.300
0.010
0.012
0.008
0.011
0.001
0.004
0.002
0.001
0.001
0.002
0.001
0.008
C1> Estimated / extrapolated.
41
-------
PH Prof fie Speciation Report
Profile Name Coal- Fired Power
Profile Nwber 11210
Data Quality E
Plant
Control Device ESP
Reference(s) 64,69
Data Source Samples collected fsokinetically using EPA train with
12-rainute runs. Analyzed by AAS and 1NAA.
SCC Assignments; 10100201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.290 O.SOO
Total Participate Hotter
Species
CAS Umber
7440-23-5
7439-95-4
7429-90-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-38-2
7782-49-2
7440-24-6
7440-74-6
7440-36-0
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-53-1
7429-91-6
7439-92-1
7440-29-1
Nur,
11
12
13
19
20
21
22
23
24
25
U
27
28
29
33
34
38
49
51
56
57
58
62
63
66
82
90
0-2.5
-r... Swt
Na
Kg
Al
K
Ca
Sc
Ti
V
Cr
tin
Fe
Co
Hi
Cu
As
Se
Sr
In
Sb
Bo
La
Ce
Sffl
Eu
Dy
Pb
Th
0.
3.
19.
1.
2.
0.
1.
0.
0.
0.
11.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
" 0.
0.
0.
0.
0.
280
300
700
200
600
015
800
062
061
074
700
013
017
021
048
031
180
001
007
160
013
035
004
001
003
011
005
uroCU
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
%ut
0.280
3.300
19.700
1.200
2.600
0.015
1.800
0.062
0.061
0.074
11.700
0.013
0.017
0.021
0.048
0.031
0.180
0.001
0.007
0.160
0.013
0.035
0.004
0.001
0.003
0.011
0.005
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
%ut
0.280
3.300
19.700
1.200
2.600
0.015
1.800
0.062
0.061
0.074
11.700
0.013
0.017
0.021
0.048
0.031
0.180
0.001
0.007
0.160
0.013
0.035
0.004
0.001
0.003
0.011
0.005
umCU
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.670
Total
Measured
Xut
0.280
3.300
19.700
1.200
2.600
0.015
1.800
0.062
0.061
0.074
11.700
0.013
0.017
0.021
0.048
0.031
0.180
0.001
0.007
0.160
0.013
0.035
0.004
0.001
0.003
0.011
0.005
unc
0.130
0.800
6.500
0.500
0.600
0,007
0.700
0,021
0.016
0.064
7,300
0.008
0.005
0.002
0.019
0.014
0.040
0.001
0.005
0.020
0.004
0.006
0.001
0.000
0.000
0.002
0.002
TOTALS: 41.342 41.342 41.342
<1> Estimated / extrapolated.
41.342
42
-------
PK Profile Speciation Report
Profile Name
Profile Nunber
Data Quality
Coal-Fired Power Plant
11211
e
Control Device
Reference(s)
Data Source
Uncontrolled
64,70
Sanples collected with a University of Wash inston Nark 10
impactor end an MRI Model 1502 impactor. Analyzed by INAA
•nd XRF.
SCC Assignments: 10100201
Mass Fraction
Data - Size Interval (un>
Mass Fraction
Total Participate Mattel
Species
CAS Nunber Nun
7429-90-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7439-96-5
7439-89-6
7440-55-3
7440-38-2
7782-49-2
7440-24-6
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-27-9
7440-58-6
7440-25-7
7440-29-1
TOTALS!
jg. _ -. mm JM •_«. •».«. — _ y. w. .
13
19
20
21
22
23
25
26
31
33
34
38
51
55
56
57
58
62
65
72
73
90
Syirt
Al
K
Ca
sc
Ti
V
Hn
Fe
68
As
Se
Sr
Sb
Cs
Ba
La
Ce
Em
Tb
Hf
To
Th
0-2.
Xwt
9
0
2
0
0
0
0
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
16
.325
.423
.883
.001
.429
.009
.023
.761
.004
.003
.001
.135
.000
.000
.190
.005
.009
.001
.000
.001
.000
.002
.205
5 um€1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: C0-2.il
: 0.060
2.5-10 um€1>
%ut
9.325
0.423
2.883
0.001
0.429
0.009
0.023
2.761
0.004
0.003
0.001
0.135
0.000
0.000
0.190
0.005
0.009
0.001
0.000
0.001
0.000
0.002
16.205
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
sssssE— SfSBS!
CO-6J
0.170
0-10
Xwt
9.325
0.423
2.883
0.001
0.429
0.009
0.023
2.761
0.004
0.003
0.001
0.135
0.000
0.000
0.190
0.005
0.009
0.001
0.000
0.001
0.000
0.002
16.205
untO
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-10)
0.230
Total
Measured
Xwt
9.325
0.423
2.883
0.001
0.429
0.009
0.023
2.761
0.004
0.003
0.001
0.135
0.000
0.000
0.190
0.005
0.009
0.001
0.000
0.001
0.000
0.002
16.205
unc
1.119
0.051
0.346
0.000
0.052
0.001
0.003
0.331
0.000
0.000
0.000
0.135
0.000
0.000
0.023
0.001
0.001
0.000
0.000
0.000
0.000
0.000
CD Estimated / extrapolated.
43
-------
PH Proffie Speefation Report
Profile Name
Profile Number
Pata Quality
Coal-Fired Power Plant
11212
E
Control Device ESP
Reference(s) 64,71
Data Source Sanplcs collected using ASTM sampling train; two data sets
consisting of three 4 to 5-hr runs per set. Analyzed by XRF,
• CC, f tameless MS, and INAA.
SCC Assignments: 10100203
Mass Fraction Oat* - Size Interval (urn)
Mass fraction
Total Participate Matter
Species
CAS Number
7440-23-5
7429-90-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-66-6
7440-38-2
7782-49-2
7440-17-7
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-53-1
7440-58-6
7440-25-?
7439-92-1
7440-29-1
Hum
11
13
19
20
21
22
23
24
25
26
27
30
33
34
37
48
51
55
56
57
58
62
63
72
73
82
90
Sym
Na
Al
K
Ca
Sc
Ti
V
Cr
Nn
Fe
Co
In
As
Se
Rb
Cd
Sb
Cs
Ba
La
Ce
Sen
Eu
Hf
Ta
Pb
Th
0-2.5
Xut
1
7
2
3
0
0
0
0
0
15
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.129
.576
.424
.182
.004
.985
.121
.089
.043
.152
.007
.591
.044
.009
.019
.005
.005
.003
.075
.004
.012
.001
.000
.000
.000
.065
.003
um£1>
unc
0.000
0.000
0,000
0,000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
s CO-2.53
: 0.360
2.5-10
Xut
1.129
7.576
2.424
3.182
0.004
0.985
0.121
0.089
0.043
15.152
0.007
0.591
0.044
0.009
*0.019
0.005
0.005
0.003
0.075
0.004
0.012
0.001
0.000
0.000
0.000
0.065
0.003
um€1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-6)
0.560
0-10 unCU
Xut
1.129
7.576
2.424
3.182
0.004
0.985
0.121
0.089
0.043
15.152
0.007
0.591
0.044
0.009
0.019
0.005
0.005
0.003
0.075
0.004
0.012
0.001
0.000
0.000
0.000
0.065
0.003
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-105
0.680
Total
Measured
Xut
1.129
7.176
2.424
3.182
0.004
0.985
0.121
0.089
0.043
15.152
0.007
0.591
0.044
0.009
0.019
0.005
0.005
0.003
0.075
0.004
0.012
0.001
0.000
0.000
0.000
0.065
0.003
unc
0.068
0.379
0.152
0.152
0.001
0.152
0.015
0.005
0.006
0.758
0.000
0.045
0.003
0.000
0.001
0.003
0.001
0.000
0.011
0.000
0.001
0.000
0.000
0.000
0.000
0.003
0.000
TOTALS:
31.548
31.548
31.548
31.548
€1} Estimated / extrapolated.
44
-------
PM Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
External Combustion
11213
E
Coal-Fired Composite
Control Device
Reference(s)
Data Source
two bag filters, one ESP, and two uncontrolled.
64,72
Composite of five coal fired plants in Japan. Samples
collected on on PTFE filters and analyzed using XRF and
INM.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn) :
Ness Fraction ;
Total Particulate Natter
CAS Number
7440-23-5
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7439-92-1
s|^?v ic»
Hum Sym
11
13
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
35
37
47
51
55
56
57
82
Na
Al
S
Cl
1C
Ca
SC
Ti
V
Cr
Hn
Fe
Co
Hi
Cu
Zn
As
Br
Rb
AS
Sb
Cs
Ba
La
Pb
0-2.5
Xwt
0
2
1
1
1
2
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
.970
.600
.500
.100
.000
.300
.001
.260
.013
.040
.031
.800
.010
.018
.130
.300
.026
.016
.005
.004
.008
.001
.110
0.001
0
.200
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
! CO-2.5)
: 0.290
2.5-10
Xut
0.970
2.600
1.500
1.100
1.000
2.300
0.001
0.260
0.013
0.040
0.031
1.800
0.010
0.018
0.130
0.300
0.026
0.016
0.005
0.004
0.008
0.001
0.110
0.001
0.200
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-6)
0.500
0-10
Xut
0.970
2.600
1.500
1.100
1.000
2.300
0.001
0.260
0.013
0.040
0.031
1.800
0.010
0.018
0.130
0.300
0.026
0.016
0.005
0.004
0.008
0.001
0.110
0.001
0.200
(0-10)
0.670
Total
umC1> Measured
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.200
Xwt
0.970
2.600
1.500
1.100
1.000
2.300
0.001
0.260
0.013
0.040
0.031
1.800
0.010
0.018
0.130
0.300
0.026
0.016
0.005
0.004
O.OOS
0.001
0.110
0.001
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 12.444
szssjBJEteBBsssssESBSSSBessssfflESBSSSEsssjssss
{1} Estimated / extrapolated.
12.444
12.444
12.244
45
-------
PM Profile Specialion Report
Profile Name
Profile Number
Data Quality
Uncontrolled Coal-fired Power Plant Composite
11214
E
Control Device
Reference(s)
Data Source
Uncontrolled
Profile represents a composite of Profiles 11202 and 11211
uncontrolled utility boiler, wet bottom design, firing
pulverized bituminous coal.
SCC Assignments: 10100201
Mass Fraction Data - Size
Mass
Total Participate Matter -
CAS Number
7429-90-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7439-96-5
7439-89-6
7440-38-2
7782-49-2
7440-24-6
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-27-9
7440-58-6
7440-29-1
TOTALS:
ofj^c ie:»
Nun Sym
13
19
20
21
22
23
25
26
33
34
23
55
56
57
58
62
65
72
90
Al
K
Ca
Sc
Ti
V
Hn
Fe
As
Se
Sr
Cs
Ba
La
Ce
Sm
Tb
Hf
Th
Interval (urn)
Fraction
0-2
Xwt
11.363
0.812
2.142
0.003
0.765
0.030
0.026
4.981
0.032
0.013
0.132
0.001
0.245
0.008
0.013
0.002
0.000
0.001
0.002
20.571
.5 urn
uncO>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-2.5)
: 0.060
2.5-10 urn
Xwt
13.863
0.877
2.592
0.003
0.865
0.026
0.023
5.431
0.012
0.002
0.129
0.001
0.142
0.009
0.014
0.002
0.000
0.001
0.003
23.995
unc£1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.170
0-10 urn
Xwt
13.211
0.860
2.474
0.003
0.839
0.027
0.024
5.313
0.017
0.005
0.130
0.001
0.169
0.009
0.014
0.002
0.000
0.001
0.003
23.102
uncm
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.465
Total
Measured
Xwt une{1>
13
0
2
0
0
0
0
5
0
0
0
0
0
0
0
0
0
0
0
23
.215
.860
.475
.003
.839
.000
.024
.314
.017
.005
.130
.001
.169
.009
.014
.002
.000
.001
.003
.081
0.000
0.000
0.000
0.000
0.000
0.000
o.odo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
===E===============I====================:I:=============:================:====J============
•C1> Uncertainty not evaluated.
46
-------
PK Profile Spec!ation Report
Profile Name Coal-fired Power Plant/ESP Composite
Profile Number 11215
Data Quality D
Control Device ESP
Reference(s)
Data Source Profile represents a composite of Profiles 11204, 11205,
11206, 11207, 11208, 11210, and 11212.
SCC Assignments: 10100201
Mass Fraction Data - Siie Interval Cun) : (0-2.5) (0-6)
Mass Fraction : 0.290 0.500
Total Participate Natter
Species
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7440-36-0
7439-92-1
Kun
11
12
13
14
16
19
20
22
23
24
25
26
28
29
30
33
34
51
82
Syrn
Na
HS
Al
Si
S
K
Ca
Ti
V
Cr
Kn
Fe
Nf
Cu
Zn
AS
Sf
Sb
Pb
*
0-2
Xwt
0.
1.
10.
15.
1.
1.
2.
0.
0.
0.
0.
7.
0.
480
914
598
789
255
421
287
896
058
050
047
239
019
0.022
q.
0.
0.
0.
0.
156
036
011
004
033
.5 un
uncW
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xut uncm
0.526
2.935
13.864
26.426
0.565
1.665
2.648
1.114
0.062
0.050
0.041
7.730
0.018
0.021
0.151
0.023
0.008
0.004
0.032
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
0.507
2.493
12.450
21.822
2.864
1.559
2.492
1.020
0.060
0.050
0.044
6.089
0.018
0.022
0.153
0.031
0.009
0.004
0.032
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-10)
0.670
Total
Measured
Xwt
0.501
2.555
12.580
22.604
0.603
1.558
2.516
1.019
0.061
0.049
0.044
7.534
0.017
0.021
0.149
0.030
0.009
0.004
0.032
unc<1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
42.315
57.883
51.719
51.886
{1} Uncertainty not evaluated.
47
-------
PH Profile Speciat ion Report
Profile Name Coal- and Refuse
Profile Nuifeer 11301
Data Quality D
Derived Fuel (Ron-Fired Potter
Plant
Control Dtvice ESP
Reftrence(s) £4,66
Data Source Sampled with a SASS train. Analyzed wing XRF, INAA( and
FAA.
SCC Assignments: 10100201, 10101201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.290 0.500
Total Participate Matter -
CAS Number
7440-23-5
7419-90-5
7440-21-3
7704-34-9
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-t
7440-19-9
7440-53-1
7440-27-9
7440-64-4
7440-58-6
7440-25-7
*?p
Xwt
0.768
11.021
20.200
1.866
1.803
7.802
0.002
0.701
0.023
0.092
12.950
0.003
0.012
0.010
0.236
0.007
0.012
0.005
0.001
0.001
0.009
0.087
0.003
0.004
0.004
0.001
0.218
0.007
0.011
0.001
0.000
0.000
0.001
0.000
0.000
unc
0.187
3.728
6.705
1.030
0.368
1.320
0.002
0.173
0.009
0.028
2.018
0.003
0.005
0.006
0.072
0.006
0.007
0.004
0.001
0.001
0.004
0.025
0.004
0.003
0.003
0.001
0.052
0.004
0.005
0.002
0.000
0.000
0.001
0.000
0.000
CO-10)
0.670
Total
Measured
Xwt
0.741
11.100
20.352
1.706
1.782
7.875
0.002
0.694
0.022
0.090
12.933
0.003
0.012
0.010
0.222
0.007
0.012
0.006
0.001
0.001
0.009
0.085
0.003
0.004
0.004
0.001
0.211
0.007
0.011
0.001
0.000
0.000
0.001
0.000
0.000
unc
0.155
3.866
6.889
0.512
0.251
1.095
0.000
0.139
0.003
0.018
1.008
0.001
0.001
0.002
0.019
0.001
0.003
0.001
0.000
0.001
0.002
0.015
0.000
0.001
0.001
0.000
0.019
0.001
0.002
0.000
0.000
0.000
0.000
0.000
0.000
48
-------
W Profile Specialism Report - continued Cprofile 11301)
Total Particulate Natter -
Species
CAS Number
7440-33-7
7439-92-1
7440-29-1
7440-61-1
Hum
74
82
90
92
Sym
U
Pb
Th
U
0-2
Xwt
0.001
0.253
0.002
0.001
.5 urn
unc
0.000
0.068
0.001
0.000
2.5-10 u»
0
0
0
0
Xwt:
.000
.112
.002
.001
unc
0.000
0.010
0.000
0.000
0-10
Xwt
0.000
0.129
0.002
0.001
u»C1>
unc
0.001
0.039
0.002
0.001
Total
Measured
Xut
0.000
0.122
0.002
0.001
unc
0.000
0.011
0.000
0.000
TOTALS: 57.246 58.071 57.993 58.033
ssssxssessssssssssssssssssssssessssEissssswxsESSKSKsssiesffisisssssssasEssxffissssssssssKssssss:::
<1> Calculated based on methodology in the Air Emissions Species Manual, Volume II.
49
-------
PH Profile Speeiat ion Report
Profile Name Oil-Fired Power Plant
Profile Umber 11S01
Data Quality B/D
Control Device Mechanical collector
Reference(s) 52
Data Source Dilution train sample.
nine. Plant burns No. 61
SCC Assignments: 10100401
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate
**——.,
CAS Nunber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7762-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-43-9
7440-31-5
7440-36-0
7440-46-2
opca
Hum
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
42
48
50
51
55
Matter
~{*c
«ies
Sym
Be
B
F
Na
Mi
Al
Si
P
S
Cl
K
Ca
Se
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ce
As
Se
Br
Rb
Sr
Zr
Mo
Cd
Sn
Sb
Cs
*
0-2
Xwt
1
2
1
11
0
0
2
0
1
0
0
2
2
NA
NA
NA
NA
NA
.468
.512
.012
.027
.000
.217
.353
<
.129
.504
.051
.039
.043
<
.036
NR
1.095
0
0
0
0
0
0
0
0
0
0
.010
<
.008
.003
.004
.003
.031
.003
.169
.002
.019
0.074
<
.5 um
unc
0.000
0.000
0.000
0.000
0.000
0.068
0.115
0.184
0.513
0.129
0.011
0.110
0.000
0.129
0.069
0.090
0.002
0.094
0.000
0.093
0.000
0.050
0.002
0.000
0.007
0.002
0.002
0.001
0.002
0.004
0.008
0.003
0.005
0.010
0.000
Representative tuple from set
fuel oil.
: CO-2.5) (0-6)
: 0.520 0.580
2.5-10 um
Xut
NA
NA
NA
NA
NA
10.126
20.321
2.484
9.718
0.000
0.386
10.805
<
1.122
1.944
0.127
0.069
3.715
<
1.208
NR
0.710
0.030
<
0.022
0.000
0.010
0.000
0.159
0.166
0.085
0.000
0.000
0.230
<
unc
0.000
0.000
0.000
0.000
0.000
0.992
1.909
1.140
2.498
0.601
0.386
1.141
0.000
0.110
0.370
0.050
0.015
0.578
0.000
0.422
0.000
0.231
0.015
0.000
0.053
0.010
0.009
0.007
0.020
0.047
0.050
0.050
0.070
0.145
0.000
0-10 um
Xwt
NE
NE
"NE
NE
NE
3.785
7.278
1.406
10.677
0.000
0.262
4.615
NE
0.395
1.622
0.071
0.047
2.490
Ni
1.814
NE
0.992
0.015
NE
0.012
0.002
0.006
0.002
0.065
0.047
0.147
0.001
0.014
0.116
NE
unc
0.000
0.000
0.000
0.000
0.000
1.286
2.542
0.890
2.410
0.450
0.287
1.420
0.000
0.171
0.375
0.077
0.014
0.614
0.000
0.400
0.000
0.220
0.012
0.000
0.039
0.00?
0.007
0.005
0.022
0.039
0.042
0.037
0.051
0.109
0.000
of
0.710
Total
Measured
Xwt
NE
m
Hi
NE
NE
3.785
7.278
1.406
10.677
0.000
0.262
4.615
NE
0.395
1.622
0.071
0.047
2.490
NE
1.814
NE
0.992
0.015
NE
0.012
0.002
0.006
0.002
0.065
0.047
0.147
0.001
0.014
0.116
NE
unc
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
50
-------
PH Profile Special ion Report - continued (profile 11501)
Total Participate Natter *
0-2.5 urn 2.5-10 un 0-10 urn
Xwt unc Xut unc Xut unc
Total
Measured
Species
CAS Number Hum Sym
Xut
TOTALS:
27,454
63.859
37.196
37.196
unc
7440-39-3
7440-45-1
7439-97-6
7439-92-1
56
58
BO
82
201
202
203
204
Ba
Ce
KB
Pb
OC
EC
$04
N03
0.219
<
0.000
1.423
NA
NA
NA
NA
0.025
0.000
0.001
0.065
0.000
0.000
0.000
0.000
0
0
0
.000
<
.000
.422
NA
NA
NA
NA
0.358
0.000
0.012
0.278
0.000
0.000
0.000
0.000
0.160
NE
0.000
1.155
NE
NE
NE
NE
0.264
0.000
0.009
0.260
0.000
0.000
0.000
0.000
0.160
NE
0.000
1.155
NE
Ni
NE
NE
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
51
-------
PH Profile Speefation Report
Profile Name Oil-Fired Power Plant
Profile Nunfcer 11502
Data Quality E
Control Device Uncontrolleckl}
Reference(s) 64,73
Data Source Samples collected using EPA Method 5 probe and PTFE bag.
Method of elemental analysis not given.
SCC Assigrments: 10100401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.520 0.580
Total Particulate
C.UK.
CAS Nunber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-a
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-43-9
7440-31-5
7440-36-0
7440-39-3
apt*.
Hum
4
5
9
11
12
13
14
15
16
19
20
21
22
23
24
25
26
27
28
iv
30
31
33
34
35
37
38
39
40
41
42
48
50
51
56
Matter
*ies
Sym
Be
B
F
Na
US
Al
Si
P
S
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Nb
Mo
Cd
Sn
Sb
Ga
0-2.5
Xut
0
0
0
3
18
.000
.003
.000
.906
.380
1.249
0
0
12
0
0
0
0
2
0
0
0
0
.310
.008
.317
.130
.999
.000
.050
.268
.010
.020
.609
.050
1.658
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.050
.004
.000
.003
.001
.001
.000
.050
.005
.005
.001
.010
.000
.002
.000
.100
unC2}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xut
0.000
0.003
0.000
3.906
18.380
1.249
0.310
0.008
12.317
0.130
0.999
0.000
0.050
2.268
0.010
0.020
0.609
0.050
1.658
0.050
0.004
0.000
0.003
0.001
0.001
0.000
0.050
0.005
0.005
0.001
0.010
0.000
0.002
0.000
0.100
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.000
0.003
0.000
3.906
18.380
1.249
0.310
0.008
12.317
0.130
0.999
0.000
0.050
2.268
0.010
0.020
0.609
0.050
1.658
0.050
0.004
0.000
0.003
0.001
0.001
0.000
0.050
0.005
0.005
0.001
0.010
0.000
0.002
0.000
0.100
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-10)
0.710
Total
Measured
%W£
0.000
0.003
0.000
3.906
18.380
1.249
0.310
0.008
12.317
0.130
0.999
0.000
0.050
2.268
0.010
0.020
0.609
0.050
1.658
0.050
0.004
0.000
0.003
0.001
0.001
0.000
0.050
0.005
0.005
0.001
0.010
0.000
0.002
0.000
0.100
unc
0.000
0.000
0.000
0.200
0.919
0.060
0.020
0.001
0.609
0.006
0.050
0.000
0.005
0.110
0.001
0.002
0.031
0.005
0.080
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.005
52
-------
PH Profile Speciation Report - continued (profile 11502}
Total Participate Hatter -
Species
CAS Number
7439-91-0
7440-45-1
7440-28-0
7439-92-1
7440-29-1
7440-61-1
Hum
57
58
81
82
90
92
200
203
204
Sym
La
Ce
Tl
Pb
Th
U
TC
S04
NOS
0-2.5
Xut
0.
0.
0.
0.
0.
0.
12.
36.
0.
004
005
001
300
001
001
387
861
005
umC2>
one
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
XNt
0.004
0.005
0.001
0.300
0.001
0.001
12.387
36.861
0.005
um€2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
XNt
0.004
0.005
0.001
0.300
0.001
0.001
12.387
36.861
0.005
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xwt
0.004
0.005
0.001
0.300
0.001
0.001
12.3S7
36.861
0.005
unc
0.000
0.000
0.000
0.015
0.000
0.000
0.619
1.838
0.000
TOTALS: 91.764 91.764 91.764 91.764
SSB!»SSS&SSSSSSSS£E=SwSSwBS=SS£=SSe=B««£~E;SSSXSBC2:SBCSSS3::£:iE3C3BSBSBSVSSS£SSS3SiSS
CD No control specified; thus, assumed uncontrolled.
C2> Estimated / extrapolated.
53
-------
PN Profile Speeiation Report
Profile Name . Oil-Fired Power Plant
Profile Nunber 11503
Data Quality E
Control Device UneontrolledCO
Reference(s) 64,73
Data Source Samples collected 'using EPA Method 5 probe and PTFE bag.
Method of elemental analysis not given.
SCC Assignments: 10100401
Mass Fraction Data - Size Interval (un) : (0-2.55 (0-6)
Mass Fraction : 0.520 0.580
Total Particulate Matter
Species
CAS Nunber
7440-41-7
7440-42-8
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-43-9
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7440-45-1
Nun
4
5
11
12
13
14
15
16
19
20
22
23
2/;
25
26
27
28
29
30
J 1
33
34
35
37
38
39
40
41
42
48
50
51
56
57
58
Syst
Be
B
Na
Kg
At
Si
p
5
K
Co
Ti
V
n-«
Mn
Fe
Co
Ni
Cu
2n
«jo
As
Se
Br
Kb
Sr
Y
2r
Nb
Ho
Cd
Sn
Sb
Be
La
Ce
0-2.5
Xilt
0
0
0
3
0
0
0
4
0
0
0
6
0
0
0
0
0
0
o
0
0
0
0
0
0
Q
0
0
0
0
0
0
0
0
0
.000
.000
.299
.403
.050
.200
.002
.000
.100
.309
.030
,667
.050
.020
.399
.005
.848
.010
.004
.000
.002
.000
.000
.000
.010
.000
.000
.000
.005
.000
.000
.000
.020
.001
.000
um{2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
%Ht
0.000
0.000
0.299
3.403
0.050
0.200
0.002
4.000
0.100
0.309
0.030
6.667
0.050
0.020
0.399
0.005
0.848
0.010
0.004
0.000
0.002
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.005
0.000
0.000
0.000
0.020
0.001
0.000
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
%Mt
0.000
0.000
0.299
3.403
0.050
0.200
0.002
4.000
0.100
0.309
0.030
6.667
0.050
0.020
0.399
0.005
0.848
0.010
0.004
0.000
0.002
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.005
0.000
0.000
0.000
0.020
0.001
0.000
um{2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-10)
0.710
Total
Measured
Xwt
0.000
0.000
0.299
3.403
o.oso
0.200
0.002
4.000
0.100
0.309
0.030
6.667
0.050
0.020
0.399
0.005
0.84S
0.010
0.004
0.000
0.002
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.005
0.000
0.000
0.000
0.020
0.001
0.000
unc
0.000
0.000
0.015
0.170
0.005
0.010
0.000
0.200
0.005
0.016
0.003
0.333
0.005
0.002
0.020
0.000
0.043
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.000
0.000
54
-------
PM Profile Special ion Report - continued (profile 11503}
Total Paniculate Matter -
Total
0*1.5 mtZy 2.5-10 un>C2> 0-10 unC2> Measured
Speci.es --- — - -
CAS Number Hum Sym %wt unc Xwt unc Xwt unc Xwt unc
7639-92-1
7440-29-1
7440-61-1
82
90
92
200
203
204
Pb
Th
U
TC
S04
W03
0
0
0
68
11
0
.020
.000
.000
.862
.976
.013
0.000
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
68.862
11.976
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
68.862
11.976
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
68.862
11.976
0.013
0.002
0.000
0.000
3.443
0.599
0.001
TOTALS: 97.305 97.305 97.305 97.305
CD Mo control specified; thus, assumed uncontrolled.
•C2> Estimated / extrapolated.
55'
-------
PH ProffIc Spec!ation Report
Profile Name Oil-Fired Potter Plant
Profile Number 11504
Date Quality E
Control Device UneontroUedCI}
Reference^} 64*,73
Data Source Samples collected using EPA Method S probe and PTFE bag.
Method of elemental analysis not given.
SCC Assignments; 10100401
Mass Fraction Data - Size Interval CUB) : (0-2.5) (0-6)
Mass Fraction : 0.520 0.580
Total Participate Hatter
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-43-9
7440-31-5
7440-36-0
7440-39-3
Nun
4
5
9
11
12
13
14
15
16
19
20
21
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
41
42
48
50
51
56
Sym
Be
B
F
Na
Hg
Al
Si
P
S
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Nb
Ho
Cd
Sn
Sb
Ba
0-2.5
Xwt
0.
0.
0.
0.
5.
0.
0.
0.
13.
0.
0.
0.
0.
10.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0,
0.
0,
0.
0.
0.
0.
Q.
0.
0.
000
001
000
500
942
400
200
004
766
100
100
001
040
204
100
020
410
020
291
020
020
005
003
001
003
001
030
001
002
000
010
000
001
001
020
um£2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000*
0.000
0.000
0.000
o.opo
0.000
0.000
0.000
2.5-10
XHt
0.000
0.001
0.000
0.500
5.942
0.400
0.200
0.004
13.766
0.100
0.100
0.001
0.040
10.204
0.100
0.020
0.410
0.020
1.291
0.020
0.020
0.005
0.003
0.001
0.003
0.001
0.030
0.001
0.002
0.000
0.010
0.000
0.001
0.001
0.020
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.000
0.001
0.000
0.500
5.942
0.400
0.200
0.004
13.766
0.100
0.100
0.001
0.040
10.204
0.100
0.020
0.410
0.020
1.291
0.020
0.020
0.005
0.003
0.001
0.003
0.001
0.030
0.001
0.002
0.000
0.010
0.000
0.001
0.001
0.020
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.710
Total
Measured
Xwt
0.000
0.001
0.000
0.500
5.942
0.400
0.200
0.004
13.766
0.100
0.100
0.001
0.040
10.204
0.100
0.020
0.410
0.020
1.291
0.020
0.020
0.005
0.003
0.001
0.003
0.001
0.030
0.001
0.002
0.000
0.010
0.000
0.001
0.001
0.020
unc
0.000
0.000
0.000
0.025
0.297
0.020
0.010
0.000
0.688
0.005
0.005
0.000
0.004
0.510
0.005
0.002
0.021
0.002
0.065
0.002
0.002
0.001
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.002
56
-------
PH Profile Special ion Report - continued (profile 11504)
Total Participate
&•%«.
CAS Number
7439-91-0
7440-45-1
7440-33-7
7440-28-0
7439-92-1
7440-29-1
7440-61-1
TOTALS:
afx>,
Nun
57
58
74
81
82
90
92
200
203
204
Natter -
Sym
La
Ce
w
Tl
Pb
Th
U
TC
S04
N03
0-2.5
Xwt
0.005
0.003
0.000
0.000
0.040
0.001
0.000
21.509
4T.216
0.020
96.011
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
'
2
.5-10
Xwt
0
0
0
0
0
0
0
21
41
0
96
.005
.003
.000
.000
.040
.001
.000
.509
.216
.020
.011
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.005
0.003
0.000
0.000
0.040
0.001
0.000
21.509
41.216
0.020
96.011
unC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xwt
0.005
0.003
0.000
0.000
0.040
0.001
0.000
21.509
41.216
0.020
96.011
unc
0.001
0.000
0.000
0.000
0.004
0.000
0.000
1.080
2.061
0.002
(1> No control specified; thus, assumed uncontrolled.
C2> Estimated / extrapolated.
57
-------
PH Profile Speciatfon Report
Profile Manse Ofl-Ffred Power Plant
Profile timber 11505
Data Quality E
Control Dtviee UneontrolledC1>
Reference(s> 64,73
Data Source Samples collected using EPA Method S probe and PTFE bag.
Method of elemental analysis not given.
SCC Assignments: 10100401
Mass Fraction Data - Slz« Interval {un> : {0-2.5} (0-65
Mass Fraction : 0.520 0.580
Total Participate Natter *
CAS Hunber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-9S-7
7440-43-9
7440-31-5
7440-36-0
7440-46-2
unc
0.000
0.000
0.000
0.000
0.000
0.000
o.poo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.710
Total
Measured
Xwt
0.000
0.000
0.000
1.995
2.494
0.010
0.050
0.001
19.196
0.100
0.200
0.000
0.040
12.821
0.050
0.050
0.479
0.030
2.275
0.040
0.040
0.006
0.003
0.000
0.002
0.000
0.030
0.001
0.002
0.000
0.010
0.000
0.000
0.001
0.000
unc
0.000
0.000
0.000
0.100
0.130
0.001
0.005
0.000
0.960
0.005
0.010
0.000
0.004
0.639
0.005
0.005
0.024
0.003
0.110
0.004
0.004
0.001
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
58
-------
PM Profile Specletion Report - continued (profile 11505)
Total Participate
e^».
CAS Hunter
7440-39-3
7439-91-0
7440-45-1
7440-33-7
7440-28-0
7439-92-1
7440-29-1
7440-61-1
«K=»
Hum
56
57
58
74
81
82
90
92
200
203
204
Matter
;ies
Sym
Ba
La
Ce
y
Tl
Pb
Th
U
TC
$04
N03
0-2.5
%ut
0.
0.
0.
0.
0.
0.
0.
0.
1.
57.
0.
100
005
003
000
000
040
000
001
497
468
020
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
at
0.100
0.005
0.003
0.000
0.000
0.040
0.000
0.001
1.497
57.468
0.020
um£2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.100
0.005
0.003
0.000
0.000
0.040
0.000
0.001
1.497
57.468
0.020
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xwt
0.100
0.005
0.003
0.000
0.000
0.040
0.000
0.001
1.497
57.468
0.020
unc
0.005
0.000
0.000
0.000
0.000
0.004
0.000
0.000
0.075
2.873
0.002
TOTALS!
99.060
99.060
99.060
C1> No control specified; thus, assuned uncontrolled.
C2> Estimated / extrapolated.
99.060
59
-------
PM Profile Speciation Report
Profile Name Oil-Fired Power Plant
Profile Nunfcer 11506
Data duality E
Control Device Uncontrolled{1>
ReferenceCs) 64,75
Data Source Samples collected using EPA Method 5 probe and PTFE teg.
Method of elemental analysis not given.
SCC Assignments: 10100401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.520 0.580
Total Participate Hatter
Species
CAS Nurrfcer
7440-41-7
7440-42-8
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7'
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-4S-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
Nun
4
5
11
12
13
14
15
16
19
20
22
23
24
25
26
27
28
29
30
51
33
34
35
37
38
39
40
41
42
48
50
51
55
56
57
SyiB
Be
B
Ha
MS
Al
Si
P
S
K
Co
Ti
V
Ci
Hn
Fe
Co
Hi
Cu
•7"
Ga
AS
Se
Br
Rb
Sr
Y
Zr
Nb
Ho
Cd
Sn
Sb
Cs
Ba
La
0-2.5
Xut
0
0
d
2
1
0
0
16
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.200
.400
.420
.220
.050
.432
.120
.320
.070
,100
.045
.030
.400
.030
.350
.040
.020
.004
.002
.001
.000
.001
.020
.001
.001
.000
.015
.000
.000
.015
.000
.100
.015
un{2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
0.000
0.000
0.200
2.400
1.420
0.220
0.050
16.432
0.120
0.320
0.070
1.100
0.045
0.030
0.400
0.030
0.350
0.040
0.020
0.004
0.002
0.001
0.000
0.001
0.020
0.001
0.001
0.000
0.015
0.000
0.000
0.015
0.000
0.100
0.015
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.000
0.000
0.200
2.400
1.420
0.220
0.050
16.432
0.120
0.320
0.070
1.100
0.045
0.030
0.400
0.030
0.350
0.040
0.020
0.004
0.002
0.001
0.000
0.001
0.020
0.001
0.001
0.000
0.015
0.000
0.000
0.015
0.000
0.100
0.015
UiK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-10)
0.710
Total
Measured
Xut
0.000
0.000
0.200
2.400
1.420
0.220
0.050
16.432
0.120
0.320
0.070
1.100
0.045
0.030
0.400
0.030
0.350
0.040
0.020
0.004
0.002
0.001
0.000
0.001
0.020
0.001
0.001
0,000
0.015
0.000
0.000
0.015
0.000
0.100
0.015
unc
0.000
0.000
0.001
0.120
0.071
0.011
0.005
0.822
0.006
0.016
0.007
0.055
0.005
0.003
0.020
0.003
0.018
0.004
0.002
0.000
0.000
0.000
0.000
0.000
0.002
0.000
0.000
0.000
0.002
0.000
0.000
0.002
0.000
0.005
0.002
60
-------
PM Profile Special ion Report - continued (profile 11506)
Total Participate Matter •
Total
0-2.5 umC2> 2.5-10 um€2> 0-10 UBC2J Measured
Species ' • —-> —
CAS Number Mum Sym Xut unc %wt unc Xut unc
Xwt
unc
7440-45-1
7440-33-7
7440-28-0
7439-92-1
7440-29-1
7440-61-1
58
74
81
82
90
92
200
203
Ce
U
Tl
Pb
Th
U
TC
$04
0
0
0
0
0
0
14
49
.010
.000
.000
.030
.000
.000
.501
.205
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.030
0.000
0.000
14.501
49.205
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
o.ooo
0.000
0.030
0.000
0.000
14.501
49.205
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.030
0.000
0.000
14.501
49.205
0.005
0.000
0.000
0.003
0.000
0.000
0.730
2.460
TOTALS:
87.168
87.168
87.168
87.168
C1> No control specified; thus, assumed uncontrolled.
{2} Estimated / extrapolated.
61
-------
PH Profile Speciation Report
Profile Name 011 -Fired Power Plant
Profile dumber 11107
Data Quality C
Control Device Uncontrolled{1>
Reference(s) 62
Data Source Twenty five.tarcples from four boilers collected over n
period.
SCC Assignments: 10100401
Mass Fraction Date - Size Interval CUR) : CO-2.5) (0-6)
Hass Fraction : 0.520 0.580
Total Participate Natter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-54-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
Sym
Al
Si
P
S
Cl
K
CB
Ti
V
Cr
Nn
Fe
Ni
Cu
Zn
Ga
As
Se
ir
ib
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
sn
Sb
Bs
La
Hg
Pb
oc
0-2.5 urn
Xwt
0
0
0
11
0
0
0
0
0
0*
0
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
.097
.263
.026
.858
.144
.149
.609
.045
.519
.050
.017
.267
.115
.007
.100
.005
.025
.002
.001
.000
.001
.000
.006
.000
.001
.005
.002
.003
.000
.002
.000
.000
.000
.032
.000
unc
0.139
0.152
0.032
1.071
0.122
0.068
0.172
0.016
0.146
0.024
0.007
0.675
0.425
0.007
0.030
0.004
0.008
0.002
0.002
0.003
0.002
0.005
0.013
0.001
0.005
0.007
0.003
0.005
0.001
0.007
0.134
0.244
0.000
0.014
2.500
2.5-10 un
Xwt
1.063
1.448
0.087
10.758
1.056
0.165
0.978
0.128
0.381
0.164
0.107
1.254
0.728
0.021
0.050
0.007
0.019
0.034
0.053
0.028
0.021
0.029
0.006
0.000
0.096
0.218
0.227
0.293
0.218
0.598
0.996
1.728
0.019
0.136
44.000
unc
0.594
0.467
0.091
3.227
0.629
0.127
0.268
0.065
0.105
0.061
0.063
0.600
0.111
0.034
0.039
0.011
0.029
0.031
0.058
0.050
0.041
0.057
0.021
0.180
0.145
0.247
0.193
0,263
0.326
0.770
1.449
2.660
0.018
0.164
16.500
0-10 un
Xut
0.155
0.334
0.029
11.792
0.199
0.150
0.631
0.050
0.511
0.057
0.023
1.266
1.092
0.008
0.097
0.005
0.025
0.004
0.004
0.002
0.002
0.002
0.006
0.000
0.007
0.018
0.015
0.020
0.013
0.038
0.060
0.104
0.001
0.038
7.300
unc
0.528
0.435
0.083
3.227
0.555
0.124
0.285
0.062
0.157
0.062
0.059
0.734
0.353
0.031
0.044
0.011
0.027
0.029
0.052
0.044
0.036
0.050
0.021
0.154
0.125
0.214
0.169
0.228
0.281
0.662
1.247
2.288
0.017
0.143
14.614
6-day
CO-10J
0.710
Total
MeasuredO
Xwt
0.155
0.334
0.029
11.792
0.199
0.150
0.631
0.050
0.511
0.057
0.023
1.266
1.092
0.008
0.097
0.005
0.025
0.004
0.004
0.002
0.002
0.002
0.006
0.000
0.007
0.018
0.015
0.020
0.013
0.038
0.060
0.104
0.001
0.038
7.300
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.doo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
62
-------
PM Profile Specialion Report - continued (profile 1150?)
Total Participate Matter -
Total
0-2.5 urn 2.5-10 un 0-10 urn MeasuredC2>
Species •• ------- -•- — ---------- — ---» ------ — • -------- -
CAS Nunber Num Sym Sfart unc Xut one Xut unc Xut unc
202 EC 12.800 9.300 18.700 15.000 13.200 14.659 13.200 0.000
TOTALS: 34.151 85.814 37.258 37.258
<1> No control specified: thus, assumed uncontrolled.
C2> EstiMted / extrapolated.
63
-------
PH Profile Speciation Report
Profile Name Oil-Fired Power Plant
Profile Number 11508
Data Quality D
Control Device UncontrolledCO
Reference(s) 62
Data Source Unspecified methodology.
SCC Assignments 10100401
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter -
Species
CAS Number
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-67-7
7439-98-7
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7440-45-1
7440-00-8
7440-19-9
7439-92-1
Nun
11
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
33
34
35
38
40
42
50
51
56
57
58
60
62
82
201
202
203
Sym
Na
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Br
Sr
Zr
Mo
Sn
Sb
Ba
La
Ce
Nd
Sm
Pb
OC
EC
S04
0-2
Xwt
2
0
1
1
11
0
0
3
0
1
0
0
1
0
1
0
1
d
0
0
0
0
0
0
0
0
0
0
0
0
1
3
7
40
.600
.420
.900
.500
.000
.018
.160
.400
.050
.100
.022
.035
.500
.075
.500
.098
.200
.003
.002
.011
.016
.021
.087
.034
.035
.186
.012
.008
.003
.000
.800
.200
.700
.000
.5 un
unc
0.600
0.080
0.600
0.400
2.000
0.008
0.050
0.900
0.050
0.300
0.001
0.004
0.200
0.014
0.500
0.032
0.300
0.001
0.001
0.006
0.005
0.021
0.018
0.022
0.038
0.009
0.002
0.002
0.000
0.000
0.600
0.500
1.500
3.000
: (0-2.5)
: 0.520
2.5-10 un
Xwt
2.500
3.700
8.200
2.300
9.000
0.160
0.350
7.600
0.690
1.500
0.065
0.057
2.900
0.100
2.100
0.140
1.600
0.004
0.003
0.002
0.100
0.200
0.077
NR
0.012
0.550
0.170
0.058
0.050
0.004
3.000
12.000
21.000
47.000
unc
1.100
0.300
1.500
0.200
1.000
0.090
0.050
3.800
0.140
0.800
0.016
0.018
0.400
0.020
0.200
0.020
0.500
0.003
0.001
0.001
0.013
0.110
0.022
0.000
0.013
0.260
0.020
0.007
0.021
0.001
0.400
8.000
1.000
4.000
<0-6)
0.580
0-10 un
Xwt
2.594
0.602
2.250
1.544
10.889
0.026
0.171
3.633
0.086
1.122
0.024
0.036
1.578
0.076
1.533
0.100
1.222
0.003
0.002
0.011
0.021
0.031
0.086
0.032
0.034
0.206
0.021
0.011
0.005
0.001
1.867
3.689
8.439
40.389
unc
1.093
0.398
1.507
0.420
2.155
0.082
0.074
3.387
0.145
0.740
0.022
0.022
0.468
0.030
0.468
0.040
0.516
0.005
0.003
0.006
0.024
0.100
0.031
0.016
0.031
0.232
0.033
0.017
0.023
0.004
0.636
6.924
Z.241
6.763
0.710
Total
Heasured{2>
Xwt
2.594
0.602
2.250
1.544
10.889
0.026
0.171
3.633
0.086
1.122
0.024
0.036
1.578
0.076
1.533
0.100
1.222
0.003
0.002
0.011
0.021
0.031
0.086
0.032
0.034
0.206
0.021
0.011
0.005
0.001
1.867
3.689
8.439
40.389
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
79.696
127.192
82.334
82.334
{1} No control specified: thus, assumed uncontrolled.
C2> Estimated / extrapolated. 64
-------
PM Profile Specintion Report
Profile Kane 0fl-Fir«d Power Plant
Profile number 11509
Data Quality 0
Control Device Uncontrolled^}
Referervce(s) 62
Data Source Unspecified methodology.
SCO Assignments 10100401
Mass Fraction Data * Site Interval (uti)
Mass Fraction
Total Participate Natter -
CAS Number
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-67-7
7439-98-7
7440-22-4
7440-31-5 '
7440-36-0
7440-39-3
7439-91-0
7440-45-1
7440-00-8
7440-19-9
7440-53-1
7440-27-9
7439-92-1
7440-29-1
afxss; i es>
Nun Sym
11
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
34
35
38
40
42
47
50
51
56
57
58
60
62
63
65
82
90
Na
At
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
«n
Fe
Co
Ni
Cu
Zn
As
Sc
Br
Sr
Zr
Ho
As
Sn
Sb
Ba
La
Ce
Nd
Sm
Eu
Tb
Pb
Th
0-2
Xwt
3
0
2
1
13
0
2
0
1
0
0
1
0
1
0
0
0
0
0
0
0
0
0
.100
.890
.600
.000
.000
NR
.210
.100
HR
.120
.900
.022
.023
.600
.110
.900
.110
.730
.005
.002
.004
.028
.016
.160
NR
.021
0.097
0
.130
0.042
0
0
0
1
.034
.022
.002
m
NR
.000
NR
.5 urn
une
0.900
0.070
0.400
0.100
1.000
0.000
0.030
0.900
0.000
0.020
0.300
0.007
0.008
0.400
0.010
0.200
0.050
0.290
0.001
0.001
0.000
0.007
0.013
0.020
0.000
0.008
0.008
0.005
0.003
0.002
0.002
0.000
0.000
0.000
0.200
0.000
s (0-2.5)
: 0.520
2.5-10 urn
Xwt
4.400
9.700
22.000
1.700
9.200
0.430
0.340
16.000
0.001
1.000
1.000
0.041
0.062
3.200
0.120
1.800
0.800
0.840
0.008
0.001
0.007
0.150
0.190
0.240
0.010
0.330
0.064
0.940
0.590
0.350
0.270
0.028
0.001
0.001
0.650
0.002
unc
4.300
1.400
6.000
0.600
4.000
0.260
0.110
2.000
0.000
0.200
1.800
0.013
0.017
0.500
0.030
0.500
0.800
0.110
0.007
0.001
0.004
0.040
0.050
0.160
0.004
0.310
0.034
0.060
0.140
0.020
0.030
0.007
0.000
0.000
0.340
0.000
<0-6)
0.580
0-10 un
Xwt
3.152
1.242
3.376
1.028
12.848
0.017
0.215
2.656
0.000
0.155
1.864
0.023
0.025
1.664
0.110
1.896
0.138
0.734
0.006
0.002
0.005
0.033
0.023
0.163
0.000
0.033
0.096
0.162
0.064
0.047
0.032
0.003
0.000
0.000
0.9S6
0.000
unc
3.768
1.410
5.404
0.549
3.815
0.228
0.108
2.201
0.001
0.197
1.571
0.018
0.023
0.603
0.037
0.517
0.690
0.258
0.008
0.002
0.006
0.044
0.053
0.143
0.007
0.269
0.035
0.106
0.136
0.048
0.046
0.012
0.002
0.002
0.349
0.003
CO-10)
0.710
Total
Measured{2>
XMt
3.152
1.242
3.376
1.028
12.848
0.017
0.215
2.656
0.000
0.155
1.864
0.023
0.025
1.664
0.110
1.896
0.138
0.734
0.006
0.002
0.005
0.033
0.023
0.163
0.000
0.033
0.096
0.162
0.064
0.047
0.032
0.003
0.000
0.000
0.986
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
65
-------
PH Profile Special ion Report - continued (profile 11509)
Total Partieulnte Matter -
Total
0-2.5 un 2.5-10 urn 0-10 un Measured{2>
Species ' •— -*— •— •
CAS Nunber Hum Sym -KM* unc Xut unc Xwt unc Xwt unc
201 DC 1.000 0.500 26.000 16.000 2.000 13.833 2.000 0.000
202 EC 0.220 0.170 1.100 1.100 0.255 0.955 0.255 0.000
203 504 45.000 7.000 40.000 30.000 44.800 26.756 44.800 0.000
TOTALS: 77.198 143.566 79.853 79.853
«:«»BK*«SEBE=SSESOS=B=SSS;SK3S3e=SBeSKSH=3SS33Be3S:B=:SB3:CCBSK=:SS=:3==5:SES«CJ==S5:S«aS==S5:C==SS
{1} No control specified: thus, assumed uncontrolled.
€2} Estimated / extrapolated.
66
-------
Profile Speciat ion Report
Profile Name Oil-fired
Profile Number 11510
Data Quality E
Power Plant Composite
Control Device Uncontrolled
Reference(s)
Date Source Profile represents a composite of Profiles 11502, 11503,
11504, 11505, 11506, 11507, 11508, and 11509.
SCC Assignments: 10100401
Mass Fraction Data - Size Interval Cum) : (0-2.5) (0-6)
Mass Fraction : 0.520 0.580
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-67-7
7439-98-7
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-92-1
TOTALS;
0|^wV lea
Hum Svm
13
14
15
16
19
20
22
23
24
25
26
28
29
30
33
34
35
38
40
42
50
51
56
57
82
Al
S!
P
S
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
Br
Sr
2r
Mo
Sn
Sb
Ba
La
Pb
==============-============
0-2.5 urn
Xwt
0.567
0.718
0.324
12.696
0.134
1.005
0.056
4.572
0.044
0.027
0.833
1.367
0.047
0.265
0.006
0.001
0.003
0.023
0.007
0.037
0.007
0.019
0.082
0.011
0.408
23.259
sssftssssss
uncd>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
ssssses:
2.5-10 urn
Xwt
2.199
4.079
0.519
11.834
0.176
3.313
0.256
4.493
0.066
0.046
1.206
1.381
0.140
0.322
0.006
0.005
0.009
0.051
0.051
0.046
0.079
0.086
0.353
0.315
0.527
31.558
========1
unecn
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.oao
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
:======:
0-10 urn
Xwt
0.641
0.868
0.333
12.655
0.136
1.106
0.065
4.570
0.045
0.028
0.851
1.368
0.051
0.268
0.006
0.001
0.003
0.025
0.009
0.037
0.010
0.023
0.096
0.027
0.415
23.637
:===±==n==
unc<1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
======
(0-10)
0.710
Total
Measured
Xwt uncC1>
0
0
0
12
0
1
0
4
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
23
SOB
.641
.868
.333
.655
.136
.106
.065
.570
.045
.028
.851
.368
.051
.268
.006
.001
.003
.025
.009
.037
.010
.023
.096
.027
.415
.637
=====
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
======
Uncertainty not evaluated.
67
-------
PM Prof ile Speci»tion Repsrt
Profile Name Wood- Fined Boiler
Profile Number 11801
Data Quality B/D
Control Device HuU icy clone
Refcrence(s) 21
Data source Sampled with a stage virtual iapactor.
SCC Assignments 10100902
Nass Fraction Data - Size Interval (tin) : (0-2.S)
Mass Fraction : 0.160
Total Paniculate Matter
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Sym
Be
B
f
Ha
Ng
Al
Si
P
s
Cl
K
Cs
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cll
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
*
0-2.5 urn
%wt
o.
3.
0.
0.
NA
NA
150
400
<
240
760
<
8.800
9.
22.
5.
0.
0.
1.
500
400
600
<
<
<
015
510
260
<
0.006
0.
0.
0.
120
730
<
<
<
<
055
<
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.050
2.900
1.000
0.180
0.370
0.000
2.400
4.900
11.200
4.000
0.000
0.060
0.002
0.006
0.340
0.880
0.000
0.004
0.060
0.340
0.000
0.000
0.000
0.000
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
%Mt
NA
NA
0.110
0.690
0.460
0.280
0.960
<
0.590
0.830
1.300
5.200
<
0.097
0.005
0.007
0.290
0.920
<
<
0.023
0.039
<
<
<
<
0.001
<
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.041
0.960
0.170
0.090
0.140
0.000
0.090
0.760
0.210
0.520
0.000
0.080
0.003
0.001
0.040
0.220
0.000
0.005
0.004
0.005
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.270
0-10 urn
Xut
NE
NE
0.130
2.045
NE
0.260
0.860
NE
4.695
5.165
11.850
S.400
NE
NE
NE
0.011
0.400
1.090
NE
NE
0.071
0.385
Ni
NE
NE
NE
0.028
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.03!i
1.547
0.000
0.104
0.216
0.000
1.352!
2.S69
5.821
2.088
0.000
0.000
0.000
0.003
0.176
0.467
0.000
0.000
0.031
0.178
0.000
0.000
0.000
0.000
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.320
Total
Measured
£wt
HE
NE
0.130
2.045
NE
0.260
0.860
NE
4.695
5.165
11.850
5.400
NE
NE
NE
0.011
0.400
1.090
NE
NE
0.071
0.385
NE
NE
NE
NE
0.028
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
68
-------
PN Profile Special ion Report - continued (profile 11801)
Total Participate Natter -
0-2.5 un 2.5-10 urn 0-10 in
Total
Measured
CAS Nimber Nun Sym
Xut
unc
Xwt
unc
Xut
unc
Xwt
unc
7440-45-1
7439-97-6
7439-92-1
58
80
82
201
202
203
204
Ce
Hi
Pb
OC
EC
$04
N03
0
33
0
<
<
.420
NA
NA
.800
.510
0.000
0.000
0.220
0.000
0.000
9.000
0.230
«
<
0.020
11.100
4.300
1.500
0.200
0.000
0.000
0.003
5.400
1.400
0.370
0.130
NE
NE
0.220
NE
NE
17.650
0.355
0.000
0.000
0.114
0.000
0.000
5.100
0.138
NE
NE
0.220
NE
NE
17.650
0.355
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
88.276
28.922
50.615
50.615
69
-------
PH Profile Specialion Report
Profile Name
Profile Nurfcer
Data Quality
Externol Combustion Boiler * Coal-Slurry Fired
12201
0
Control Device Uncontrolled
Reference(s) 61
Data Source Boiler flue gas SASS train camples analyzed for 73 elements
by spark source mass spectroscopy and atomic absorption
speetroscopy.
SCC Assignments: 10200213
Mass Fraction Data - Size Interval (un) :
Mass Fraction :
Total Particulate Matter
Species
CAS Nurfcer Nun Syrn
7439-93-2
7440-41-?
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7783-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
3
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
39
40
41
42
Li
Be
B
F
Ho
Kg
Al
Si
P
S
ct
K
Ca '
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
AS
se
Br
Rb
Sr
Y
Zr
Nb
Mo
*
0-2
Xwt
0
0
0
0
3
0
7
12
0
0
0
0
0
0
0
0
0
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.007
,000
.120
.180
.460
.450
.330
.400
.280
.520
.840
.450
.238
.006
.450
.040
.002
.053
.050
.003
.048
.007
.007
.043
.005
.044
.003
.003
.002
.030
.012
.005
.001
.008
.5 un
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.310
2.5-10 un
Xut
0.003
0.001
0.001
0.016
0.820
0.120
3.130
6.060
0.160
0.550
0.041
0.210
0.440
0.001
0.250
0.018
0.017
0.009
2.410
0.001
0.003
0.011
0.009
0.002
0.000
0.003
0.002
0.004
0.004
0.100
0.008
0.023
0.002
0.007
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.340
0-10 un
Xwt
0.006
0.000
0.101
0.153
3.032
0.396
6.649
11.372
0.261
0.525
0.710
0.411
0.271
0.005
0.418
0.036
0.004
0.046
3.784
0.003
0.041
0.008
0.007
0.036
0.004
0.037
0.003
0.003
0.002
0.041
0.011
0.008
0.001
0.008
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.370
Total
Measured
%ut
0.006
0.000
0.101
0.153
3.032
0.396
6.649
11.372
0.261
0.525
0.710
0.411
0.271
0.005
0.418
0.036
0.004
0.046
3.784
0.003
0.041
0.008
0.007
0.036
0.004
0.037
0.003
0.003
0.002
0.041
0.011
0.008
0.001
0.008
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
70
-------
PH Profile Specialion Report • continued (profile 12201)
Total Participate Natter
Species
CAS Number Nun Sym
7440-18-8
7440-16-6
7440-05-3
7440-22-4
7440-43-9
7440-31-5
7440-36-0
13494-80-9
7553-56-2
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-10-0
7440-00-8
7440-19-9
7440-53-1
7440-54-2
7440-27-9
7429-91-6
7440-60-0
7440-52-0
7440-30-4
7440-64-4
7439-94-3
7440-58-6
7440-25-7
7440-33-7
7440-15-5
7440-04-2
7439-88-5
7440-06-4
7440-57-5
7439-97-6
7440-28-0
7439-92-1
7440-69-9
7440-29-1
7440-61-1
44
45
46
47
48
50
51
52
53
55
56
57
58
59
60
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
90
92
201
202
203
204
Ru
Rh
Pd
Ag
Cd
Sn
Sb
Te
I
Cs
Ba
La
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tin
Yb
Lu
Hf
Ta
U
Re
Os
Ir
Pt
Au
Hg
Tt
Pb
Bi
Th
U
OC
EC
S04
N03
-
0-2
%wt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
NR
NR
.000
.003
.001
.002
.000
.000
.000
.160
.005
.006
.001
.001
.001
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
NR
NR
NR
NR
NR
NR
.001
.008
.000
.001
.001
NR
NR
NR
NR
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt .
NR
NR
NR
0.000
0.003
0.001
0.002
0.000
0.000
0.000
0.100
0.008
0.009
0.002
0.002
0.002
0.000
0.000
0.000
0.001
0.001
0.000
0.000
0.001
0.000
0.000
0.002
0.001
NR
NR
NR
NR
NR
NR
NR
0.015
NR
0.003
0.002
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
%wt
NE
NE
NE
0.000
0.003
0.001
0.002
0.000
0.000
0.000
0.150
0.005
0.006
0.001
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
NE
NE
NE
NE
NE
NE
NE
0.009
NE
0.001
0.001
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
%wt
NE
NE
NE
0.000
0.003
0.001
0.002
0.000
0.000
0.000
0.150
0.005
0.006
0.001
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
NE
NE
NE
NE
NE
NE
NE
0.009
NE
0.001
0.001
NE
NE
NE
NE
unc
0.000
0.000
0.000,
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
31.288
14.591
28.574
28.574
71
-------
PN Proffit Speciatfon Report
Profile Nam
Profile Number
Data Quality
External Confcustion - Kerosene- Fired Boiler Composite
12301
i
Control Device uncontrolled
Reference(s) 64,72
Data Source Composite of three kerosene- fired boilers in Japan. Samples
collected on PTFE filters and analyzed using XRF and INAA.
SCC Assignments: 10200500
Mass Fraction Data - Size interval (urn) : (0-2.5K1> (0-6)C1> <0-10)C1>
Mass Fraction : 0.120 0.300 0.500
Total Particulate Matter -
CAS Number
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7439-92-1
TOTALS:
•0-2.5 ifltC2>
ot^i* i ca
Num Sym
11
12
13
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
25
37
47
48
51
55
56
57
82
Na
Hg
Al
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
O-
Rb
Ag
Cd
Sb
Cs
Ba
La
Pb
0
0
0
1
0
0
0
0
0
0
0
Xwt
.380
.000
.600
.400
.260
.000
.360
.000
.045
.015
.024
0.026
1
0
0
0
0
0
q
0
0
0
0
0
4
0
0
9
.500
.002
.120
.000
.140
.003
.005
.000
.000
.000
.002
.000
.700
.000
.000
.582
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CD Mass fraction data for uncontrolled
C2} Estimated /
2.5-10
Xut
0.380
0.000
0.600
1.400
•0.260
0.000
0.360
0.000
0.045
0.015
0.024
0.026
1.500
0.002
0.120
0.000
0.140
0.003
0.005
0.000
0.000
0.000
0.002
0.000
4.700
0.000
0.000
9.582
un{2}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
distillate oil
0-10
Xwt
0.380
0.000
0.600
1.400
0.260
0.000
0.360
0.000
0.045
0.015
0.024
0.026
1.500
0.002
0.120
0.000
0.140
0.003
0.005
0.000
0.000
0.000
0.002
0.000
4.700
0.000
0.000
9.582
firing.
Total
umC2} Measured
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
ESSffiSSSSS
Xwt
0.380
0.000
0.600
1.400
0.260
0.000
0.360
0.000
0.045
0.015
0.024
0.026
1.500
0.002
0.120
0.000
0.140
0.003
0.005
0.000
0.000
0.000
0.002
0.000
4.700
0.000
0.000
9.582
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.oqo
o.odo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
extrapolated.
72
-------
PH Profile Speciatlon Report
Prof fie Name Wood- Fired toiler
Profile Number 12704
Data Quality B/D
Control Device Wet Scrubber
ReferenceCs) 49
Data Source Average of 3 replicates.
virtual impact or.
SCC Assignments: 10200902
Mass Fraction Data - Size Interval (un)
Mass Fraction
Total Participate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
0^*;^ i *s»
Nun Sytn
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
33
34
35
37
38
40
42
46
47
48
49
50
51
56
Be
B
f
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
CO
Ni
Cu
Zn
As
Se
Br
Rb
Sr
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
0-2
Xwt
0
0
1
7
1
1
0
0
2
20
16
3
0
0
0
0
0
0
Q
0
0
.020
.250
.600
.260
.140
.410
.910
.760
.600
.400
.300
.700
.048
.005
.008
.340
.980
.060
.005
.037
.640
0.028
0
0
0
0
0
0
0
0
0
0
0
0
0
.002
.181
.045
.035
.008
.025
.004
.007
.002
.010
.013
.024
.055
.5 urn
unc
0.020
0.130
0.400
0.730
0.114
0.990
0.550
0.250
0.260
2. ZOO
3.300
2.100
0.021
0.006
0.002
0.170
0.430
0.060
0.005
0.007
0.210
0.007
0.002
0.020
0.006
0.016
0.008
0.013
0.004
0.007
0.020
0.010
0.013
0.034
0.055
Dilution sampler uith 2-stage
s (0-2.5) (0-6)
: 0.980 0.980
2.5-10 un
Xwt
0.020
0.250
1.600
7.260
1.140
1.410
0.910
0.760
2.600
20.400
16.300
3.700
0.048
0.005
0.008
0.340
0.980
0.060
0.005
0.037
0.640
0.028
0.002
0.181
0.045
0.035
0.008
0.025
0.004
0.007
0.002
0.010
0.013
0.024
0.055
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 un
Xwt
0.020
0.250
1.600
7.260
1.140
1.410
0.910
0.760
2.600
20.400
16.300
3.700
0.048
0.005
0.008
0.340
0.980
0.060
0.005
0.037
0.640
0.028
0.002
0.181
0.045
0.035
0.008
0.025
0.004
0.007
0.002
0.010
0.013
0.024
0.055
unc
0.020
0.139
0.512
1.625
0.255
1.029
0.579
0.293
0.581
4.635
4.639
2.227
0.023
0.006
0.003
0.183
0.473
0.061
0.005
0.010
0.246
0.009
0.002
0.041
0.011
0.017
0.008
0.014
0.004
0.007
0.020
0.010
0.013
0.034
0.056
(0-10)
0.980
Total
Measured
Xwt
NA
NA
2.275
NA
NA
1.603
1.175
0.856
2.742
19.530
15.505
4.120
0.056
0.009
0.009
0.373
1.071
NA
0.005
0.033
0.601
0.025
0.002
0.175
0.045
0.040
0.011
0.030
0.006
0.010
0.007
0.015
0.019
0.029
0.087
unc
0.000
0.000
0.378
0.000
0.000
0.857
0.470
0.213
0.274
2.153
2.990
1.793
0.018
0.005
0.002
0.145
0.366
0.000
0.004
0.006
0.179
0.006
0.002
0.020
0.005
0.014
0.008
0.031
0.004
0.007
0.018
0.011
0.013
0.045
0.062
73
-------
PM Profile Speciation Report - continued (profile 12704)
Total Participate Matter - "
Spec.iea
CAS Number
7439-91-0
7440-45-1
7439-97-6
7439-92-1
Hum
57
58
80
82
201
202
203
204
Syro
La
Ce
Hg
P'o
oc
EC
S04
N03
0-2
%Ht
0
0
0
1
5
4
7
0
.065
.004
.206
.300
.600
.600
.000
.085
.5 urn
unc
0.065
0.003
0.033
1.300
0.600
0.600
1.100
0.085
2.5-10 un
XMt
0.065
0.004
0.206
1.300
5.600
4.600
7.000
0.085
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 un
Xut
0.065
0.004
0.206
1.300
5.600
4.600
7.000
0.085
unc;
0.066
0.003
0.053
1.326
1.271
1.098
1.780
0.087
Total
Measured
Xut
0.103
0.005
0.210
MA
7.070
4.450
7.285
0.134
unc
0.073
0.003
0.031
0.000
0.858
0.536
0.982
0.095
TOTALS: 77.772 77.772 77.772 69.721
ss KSSESS; ffi ssss== Ess&ssss ssssssssisss:—ssssssss scssssssssssssssissssasssssssssss
74
-------
PM Profile Speciat ion Report
Profile Kane : External Combustion - Mood-Fired Sailer composite
Profile Hunfcer : 12705
Data duality : E
»««-..««. — »*«---••»----• •»™»«»»..»«-»«»»»»».»»»«»«w«. ••*•»»•-•**»- — —-"»--»«»'"
Control Device ; Three nulticyelone and bag filter, one multicyclon
Referenee(s) s 64,72
Data Source : Six wood-fired boilers in Japan. Samples collected on PTFE
filters and analyzed using XRF and INAA.
SCC Assignments: 10200903
Mass Fraction Data - Size Interval
0.800
0-10
Xwt
15.000
0.000
0.100
0.000
23.000
5.200
4.000
0.000
0.010
0.000
0.004
0.100
0.230
0.000
0.027
0.024
0.067
0.008
0.180
0.009
0.001
0.000
0.000
0.000
0.066
0.035
48.061
urad>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.910
Total
Measured
Xwt
15.000
0.000
0.100
0.000
23.000
5.200
4.000
0.000
0.010
0.000
0.004
0.100
0.230
0.000
0.027
0.024
0.067
0.008
0.180
0.009
0.001
0.000
0.000
0.000
0.066
0.035
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
48.061
C1> Estimated / extrapolated.
75
-------
PK Proffit Speciation Report
Profile Name
Profile Nunber
Data Quality
Residual Oil Gonfeustion
15501
A/C
Control Device : Uncontrolled
Reference(s) : 46
Data Source : Sampled with a 2-stage virtual impnctor and Method % heated
probe. Average of 8 sannplea from cchools, hospitals,
apartments, and industrial boilers. Analysis by XRF,
1NNA, 1C, and carbon oxidation.
SCC Assignments: 10300401
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
ap<2b. 1 CZ>
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
Be
B
F
Na
Mg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Be
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
0-2
Xwt
0.
3.
0.
0,
13.
0.
1.
0.
3.
0.
0.
2.
5.
0.
0.
0.
NA
NA
053
500
<
530
960
<
300
<
280
580
<
110
440
047
046
970
<
360
075
400
<
<
<
<
013
<
<
<
<
<
<
.5 un
unc
0.000
0.000
0.019
1.700
3.000
0.240
0.480
0.000
2.400
0.100
0.100
0.640
0.000
0.038
0.750
0.015
0.013
0.610
0.000
1.210
0.025
0.180
0.000
0.000
0.000
o.oob
0.021
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.55
: 0.230
2.5-10 un
Xwt
NA
NA
0.052
3.500
<
0.530
0.960
<
13.300
<
0.280
1.580
<
0.110
3.440
0.047
0.046
2.970
<
5.360
0.075
0.400
<
<
<
<
0.013
<
<
<
<
<
<
unc
0.000
0.000
0.019
1.700
3.000
0.240
0.480
0.000
2.400
0.100
0.100
0.640
0.000
0.038
0.750
0.015
0.013
0.610
0.000
1 .210
0.025
0.180
0.000
0.000
0.000
0.000
0.021
0.000
0.000
0.000
0.000
0.000
0.000
CO-6)
0.440
0-10 un
Xwt
NE
NE
0.052
3.500
NE
0.530
0.960
NE
13.300
NE
0.280
1.580
NE
0.110
3.440
0.047
0.046
2.970
NE
5.360
0.075
0.400
NE
NE
NE
NE
0.013
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.011
0.929
0.000
0.132
0.262
0.000
1.600
0.000
O.OS6
0.356
0.000
0.022
0.469
0.009
o.ooe
0.389
0.000
0.749
0.014
0.099
0.000
0.000
0.000
0.000
0.011
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.620
Total
Measured
Xwt
NE
NE
0.052
3.500
HE
0.530
0.960
NE
13.300
NE
0.280
1.580
NE
0.110
3.440
0.047
0.046
2.970
NE
5.360
0.075
0.400
NE
NE
NE
NE
0.013
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0,000
0.000
76
-------
PM Proffie Speciation Report - continued (profile 13501)
Total Paniculate Natter -
0-2.5 un 2.5-10 urn 0-10 urn
Total
Measured
Species ...... ..—. .. —..
CAS Number Nun Sym Xut unc Xwt unc Xwt
unc
Xwt
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
51
55
56
58
80
82
201
202
203
204
Sb
Cs
8a
Ce
HS
Pb
oc
EC
S04
N03
*
<
0.110
7.800
2.420
48.100
0.650
0
0
0
0
0
0
6
2
11
0
.000
.000
.000
.000
.000
.064
.200
.500
.900
.440
<
<
0.110
7.800
2.420
48.100
0.650
0.000
0.000
0.000
0.000
0.000
0.064
6.200
2.500
11.900
0.440
HE
NE
NI
NE
NE
0.110
7.800
2.420
48.100
0.650
0.000
0.000
0.000
0.000
0.000
0.035
3.304
1.324
0.000
0.236
NE
NE
NE
NE
NE
0.110
7.800
2.420
48.100
0.650
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
91.744
91.743
91.743
91.743
77
-------
PH Profile Speeiation Report
Profile Name External Combustion - Heavy Oil -Fired Boiler Composite
Profile Nunfcer 13502
Data Quality E
Control Device Seven uncontrolled and five FGD.
Reference^} 64,72
Data Source Composite of 13 heavy oil-fired boilers in Japan. Samples
collected on PTFE filters and analyzed using XRF and INAA.
SCC Assignments: 10200401
Mass Fraction Data - Size Interval {urn} s (0-2.5} (0-6)
Mass Fraction : 0.560 0.770
Total Particulate Hatter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7439-92-1
ajjt;*; i e!>
Hum gym
11
12
13
16
17
19
20
21
22
23
24
2S
26
27
28
29
30
33
TS
37
47
48
51
55
56
57
82
Na
Hg
Al
S
Cl
K
Ca
Sc
Ti
V
Cr
Kn
Fe
Co
Ni
Cu
Zn
As
D~
Rb
Ag
Cd
Sb
Cs
Ba
La
Pb
0-2.5
Xwt
1.
0.
9.
0.
d.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
o.
0.
0.
0.
0.
0.
0.
0.
000
NR
210
600
092
085
085
000
074
920
021
012
460
003
490
000
040
002
001
000
000
000
001
000
092
000
033
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
1.000
NR
0.210
9.600
0.092
0.085
0.085
0.000
0.074
0.920
0.021
0.012
0.460
0.003
0.490
0.000
0.040
0.002
0.001
0.000
0.000
0.000
0.001
0.000
0.092
0.000
0.033
unCl>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
%Mt
1.000
NR
0.210
9.600
0.092
0.085
0.085
0.000
0.074
0.920
0.021
0.012
0.460
0.003
0.490
0.000
0.040
0.002
0.001
0.000
0.000
0.000
0.001
0.000
0.092
0.000
0.033
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<0-10)
0.860
Total
Measured
Xwt
1.000
0.000
0.210
9.600
0.092
0.085
0.085
0.000
0.074
0.920
0.021
0.012
0.460
0.003
0.490
0.000
0.040
0.002
0.001
0.000
0.000
0.000
0.001
0.000
0.092
0.000
0.033
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.boo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 13.221
C1> Estimated / extrapolated. ,
13.221
13.221
13.221
78
-------
PM Profile Special ion Report
Profile Name
Profile Hunter
Data Quality
: External Combustion
s 13503
: E
Indonesian Oil-Pi red Boiler Composite
Control Device : ESP or multicyclone plus ESP
Reference(s) : 64,72
Data Source : Composite of three Indonesian oil-fired boilers in Japan.
Samples collected on PTFE filters and analyzed using XRF and
INAA.
SCC Assignments: 10200401
Mass Fraction Data - Size Interval (tn) :
Mass Fraction :
Total Particulate Natter •
Species
CAS Number
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7439- 92- 1
Nun
11
12
13
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
35
37
47
48
51
55
56
57
82
Sym
Ha
Hg
Al
S
Cl
1C
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
AS
Br
Rb
AS
Cd
Sb
Cs
Ba
La
Pb
TOTALS:
0-2.5
%ut
2.200
0.000
0.540
11.000
1.200
0.140
0.860
0.000
0.110
0.067
0.042
0.014
1.300
0.070
2.400
0.000
0.130
0.025
0.039
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.380
umCU
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
! (0
i 0
2.5-10
Xwt
2.200
0.000
0.540
11.000
1.200
0.140
0.860
0.000
0.110
0.067
0.042
0.014
1.300
0.070
2.400
0.000
0.130
0.025
0.039
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.380
-2.5)
.410
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.520
0-10
Xwt
2.200
0.000
0.540
11.000
1.200
0.140
0.860
0.000
0.110
0.067
0.042
0.014
1.300
0.070
2.400
0.000
0.130
0.02S
0.039
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.380
um€1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
20.520 20.520 20.520
(0-10)
0.630
Total
Measured
Xwt
2
0
0
11
1
0
0
0
0
0
0
0
1
0
2
0
0
0
0
0
0
0
0
0
0
0
0
20
.200
.000
.540
.000
.200
.140
.860
.000
.110
.067
.042
.014
.300
.070
.400
.000
.130
.025
.039
.000
.000
.000
.003
.000
.000
.000
.380
.520
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
€1> Estimated / extrapolated.
79
-------
PH Profile Speciation Report
Profile Nanw Oit-Firad toiler
Profile Nunber 13504
Data Quality D
Control Device Uncontrol ledW
Referenee(s) 62
Data Source Unspecified methodology.
SCC Assigrments 10200401
Mass Fraction Data - Size Interval (un) :
Haas Fraction :
Total Particulate Hatter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
' 7439-97-6
7439-92-1
TOTALS:
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
202
Sym
At
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
ZR
Go
As
Se
Br
Rb
Sr
v
Zr
Ho
Pd
As
Cd
In
Sn
Sb
ia
La
MS
Pb
oc
EC
0-2.5 un
Kit
1.203
2.077
0.398
13.074
0.000
0.056
0.208
0.079
1.004
0.003
0.011
0.357
1.595
0.051
0.052
0.008
0.034
0.004
0.005
0.003
0.011
u*CG.3
0.018
0.024
0.017
0.001
0.000
0.001
0.003
0.019
0.020
0.094
0.001
0.032
3.960
8.690
38.116
unc
0.120
0.203
0.073
1.307
0.056
0.006
0.021
0.009
0.100
0.012
0.002
0.036
0.160
0.008
0.005
0.002
0.005
0.001
0.002
0.002
0.002
G.004
0.015
0.008
0.017
0.011
0.015
0.014
0.018
0.031
0.085
0.124
0.002
0.006
0.896
0.869
(0-2.5)
0.560
2.5-10 un
XMt
2
4
0
1
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
80
.217
.505
.151
.761
.000
.046
.571
.168
.689
.028
.018
.696
.508
.120
.017
.002
.002
.002
.005
.002
.030
.004
.006
.008
.019
.001
.000
.053
.003
.014
.010
.177
.002
.012
.630
.200
unc
0.222
0.451
0.050
0.280
0.028
0.008
0.057
0.017
0.069
0.013
0.004
0.070
0.151
0.013
0.004
0.002
0.006
0.002
0.003
0.003
0.005
0.006
0.020
0.015
0.012
0.020
0.026
0.028
0.034
0.056
0.155
0.230
0.004
0.009
0.563
8.020
98.677
(0-6)
0.770
0-10 umC2>
Xut
1.557
2.924
0.312
9.127
0.000
0.053
0.334
0.110
0.894
0.011
0.013
0.475
1.565
0.075
0.040
0.006
0.023
0.003
0.005
0.003
0.018
0.004
0.014
0.019
0.017
0.001
0.000
0.019
0.003
0.017
0.017
0.123
0.002
0.025
7.798
33.635
59.242
unc
0.282
0.538
0.077
1.498
0.043
0.016
0.078
0.032
0.143
0.017
0.009
0.097
0.250
0.026
0.010
0.003
0.007
0.003
0.005
0.004
0.011
0.007
0.019
0.014
0.017
0.017
0.023
0.028
0.030
0.050
0.137
0.204
0.004
0.011
1.176
8.391
(0-10)
0.860
Total
Measured
Xwt
1.541
2.879
0.316
9.321
0.000
0.053
0.329
0.108
0.898
0.011
0.013
0,470
1.564
0.074
0.041
0.006
0.023
0.003
0.005
0.003
0.017
0.004
0.014
0.019
0.017
0.001
0.000
0.019
0.003
0.018
0.018
0.117
0.002
0.026
7.850
32.500
58.283
unc
0.154
0.288
0.065
0.932
0.047
0.006
0.043
0.011
0.090
0.012
0.003
0.047
0.156
0.010
0.004
0.002
0.005
0.002
0.002
0.002
0.003
0.005
0.014
0.011
0.010
0.014
0.018
0.019
0.023
0.039
0.108
0.159
0.003
0.007
0.785
3.250
{1} No control specified: thus, assumed uncontrolled.
C2> Calculation based on me'^odotogy described in the Air Emissions Species Manual,
Volume II.
80
-------
PM Profile Special ion Report
Profile Name External Combustion - Waste Oil-Fired Boiler
Profile Number 14101
Data Quality E
Control Device Uncontrol ledC1>
Reference(s) 64,72
Data Source toiler firing Haste oil in Japan. Samples collected on
filters and analyzed using XRF and INAA.
SCC Assignments: 10201302
Mass Fraction Data - Size Interval (urn) ; (0-2.5K2} (0-6X2}
Mass Fraction : 0.520 0.580
Total Particulate Matt
Species
CAS Number Nun
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7439-92-1
TOTALS:
11
12
13
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
35
37
47
48
51
55
56
57
82
Sym
Na
Kg
Al
S
Cl
K
Ca
Sc
Ti
¥
Cr
Hn
Fe
Co
Ni
Cu
Zn
As
Br
Rb
Ag
Cd
Sb
Cs
Ba
La
Pb
er -
0-2.5
Xut
1
0
0
15
3
4
4
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
1
34
.500
.710
.330
.000
.600
.200
.000
.000
.013
.002
.021
.074
.000
.001
.007
.150
.850
.000
.220
.017
.001
.012
.003
.000
.710
.000
.900
.321
«*3>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xut
1.500
0.710
0.330
15.000
3.600
4.200
4.000
0.000
0.013
0.002
0.021
0.074
1.000
0.001
0.007
0.150
0.850
0.000
0.220
0.017
0.001
0.012
0.003
0.000
0.710
0.000
1.900
34.321
URK3)
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
1.500
0.710
0.330
15.000
3.600
4.200
4.000
0.000
0.013
0.002
0.021
0.074
1.000
0.001
0.007
0.150
0.850
0.000
0.220
0.017
0.001
0.012
0.003
0.000
0.710
0.000
1.900
34.321
u»C3>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
PTFE
C0-10K2>
0.710
Total
Measured
%wt
1.500
0.710
0.330
15.000
3.600
4.200
4.000
0.000
0.013
0.002
0.021
0.074
1.000
0.001
0.007
0.150
0.850
0.000
0.220
0.017
0.001
0.012
0.003
0.000
0.710
0.000
1.900
34.321
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C1> No control specified: thus, assumed uncontrolled.
C2> Mass fraction data for uncontrolled residual oil firing.
<3> Estimated / extrapolated.
81
-------
PM Profile Specialion Report
Profile Name External Combustion
Profile Hunger 14102
Data Quality E
- Liquid Waste-Fired Boiler
Control Device Ui)control leddl
Referencc(s) 64,72
Data Source Boiler firing pitch in Japan. Samples collected on PTFE
filters «nd analyzed using XRF and INAA.
SCC Assignments: 10201301
Mass Fraction Data - Size
Total Particulate
Mass
Matter -
Interval
: 0.560
<0-6K2>
0
.770
<0-10)€2>
0.
860
Total
CAS Number
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-92-1
TOTALS:
o|i*;i; i c»
Hum Sym
11
12
13
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
35
37
47
48
51
55
56
82
Na
Kg
Al
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
As
Br
Rb
Ag
Cd
Sb
Cs
Ba
Pb
0-2.
Xwt
15.000
0.000
0.450
25.000
0.000
0.000
1.300
0.000
0.000
1.200
0.015
0.030
1.700
0.013
1,500
0.000
0.066
0.003
0.000
0.000
0.003
0.000
0,002
0.000
0.000
0.100
46.382
5 unC3>
unc
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0.000
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
2.5-10
%Ht
15.000
0.000
0.450
25.000
0.000
0.000
1.300
0.000
0.000
1.200
0.015
0.030
1.700
0.013
1.500
0.000
0.066
0.003
0.000
0.000
0.003
0.000
0.002
0.000
0.000
0.100
umO
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
' 46.382
0-10
Xwt
15.000
0.000
0.450
25.000
0.000
0.000
1.300
0.000
0.000
1.200
0.015
0.030
1.700
0.013
1.500
0.000
0.066
0.003
0.000
0.000
0.003
0.000
0.002
0.000
0.000
0.100
umC3>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xut
15.000
0.000
0.450
2S.OOO
0.000
0.000
1.300
0.000
0.000
1.200
0.015
0.030
1.700
0.013
1.500
0.000
0.066
0.003
0.000
0.000
0.003
0.000
0.002
0.000
0.000
0.100
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
46.382 46.382
{1> No control specified: thus, assumed uncontrolled.
C2> Mass fraction data for uncontrolled residual oil-fired boiler.
C3> Estimated / extrapolated.
82
-------
PH Profile Special ion Report
Profile Name : External Combustion - Solid Waste-Fired Boiler
Profile Number : 15101
Data Quality : E
Control Device : UncontrolledC1>
Reference(s) : 64,72
Data Source : Boiler firing Miscellaneous fuel (primarily wood and
building materials) in Japan. Samples collected on PTFE
filters and analyzed using XRF and INAA.
SCC Assignments: 10201201
Mass Fraction Data - Size Interval (urn) :
Hass Fraction :
Total Particulate Hatter -
CAS Number
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-92-1
TOTALS:
<9|^;Lr I CO
Num Sym
11
12
13
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
35
37
47
48
51
55
56
82
Na
MS
Al
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Br
Rb
Ag
Cd
Sb
Cs
Ba
Pb
<1> No control specified:
0-2.5
Xwt
0.840
2.100
0.220
9.100
6.800
0.000
18.000
0.000
0.000
0.001
0.063
0.016
0.980
0.001
0.014
0.190
8.400
0.000
0.310
0.000
0.002
0.003
0.007
0.000
2.000
2.000
51.047
u*3>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
thus, assumed
<2> Hass fraction data for uncontrolled
<3> Estimated /
2
<[0-2.5X2>
0.760
.5-10
Xwt
0
2
0
9
6
0
18
0
0
0
0
0
0
0
0
0
8
0
0
0
0
0
0
0
2
2
51
.840
.100
.220
.100
.600
.000
.000
.000
.000
.001
.063
.016
.980
.001
.014
.190
.400
.000
.310
.000
.002
.003
.007
.000
.000
.000
.047
um<3>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<0-6X2>
0.860
0-10
Xwt
0.840
2.100
0.220
9.100
6.600
0.000
18.000
0.000
0.000
0.001
0.063
0.016
0.980
0.001
0.014
0.190
8.400
0.000
0.310
0.000
0.002
0.003
0.007
0.000
2.000
2.000
51.047
unt3>
unc
0.000
0.000
0.000
0.000
o.oqo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<0-10X2>
0.900
Total
Measured
Xwt
0.840
2.100
0.220
9.100
6.800
0.000
16.000
0.000
0.000
0.001
0.063
0.016
0.980
0.001
0.014
0.190
8.400
0.000
0.310
0.000
0.002
0.003
0.007
0.000
2.000
2.000
51.047
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
uncontrolled.
residual
Hood/baric-fired boiler.
extrapolated.
83
-------
PH Profile Speciation Report
Profile Name Coal-Fired Power
Profile Nuntoer 43303
Data Quality A/C
Utility Fly Ash
(SRN 1633)
Control Device ESP catch
Reference(s) 9
Data Source Fly ash taken from several potter plant control systems.
Not representative of stack emissions.
SCC Assignments: 10100101
Mass Fraction Data - Size Interval (un) : (0-2.5) (0-6)
Moss Fraction : 0.000 0.001
Total Participate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
df^cw I t;i»
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Se
B
F
Na
Mi
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Af
Cd
Sn
Sb
Cs
0-2
%wt
0.
1.
13.
21.
0.
1.
4.
0.
0.
0.
0.
0.
6.
0.
0.
0.
0.
0.
0.
0.
0.
0.
:
<
340
500
200
000
<
<
004
600
200
002
730
025
013
051
200
004
009
<
022
<
<
006
001
<
013
<
030
<
<
<
001
001
.5 un
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.OQO
0.000
0.000
0.000
0.000
O.OQO
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
%ut
:
<
0.340
1.500
13.200
21.000
<
<
0.004
1.600
4.2CO
0.002
0.730
0.025
0.013
0.051
6.200
0.004
0.009
<
0.022
<
<
0.006
0.001
• <
0.013
<
0.030
<
<
<
0.001
0.001
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.OQO
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 um
Xut
<
<
0.340
1.500
13.200
21.000
<
<
0.004
1.600
4.200
0.002
0.730
0.025
0.013
0.051
6.200
0.004
0.009
<
0.022
<
<
0.006
0.001
<
0.013
<
0.030
<
<
<
0.001
0.001
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.004
Total
Measured
%ut
:
<
0.340
1.500
13.200
21.000
<
<
0.004
1.600
4.200
0.002
0.730
0.025
0.013
0.051
6.200
0.004
0.009
<
0.022
<
<
0.006
0.001
<
0.013
<
0.030
<
<
<
0.001
0.001
unc
0.000
0.000
0.000
0.200
0.160
0.500
2.000
0.000
0.000
0.001
0.080
0.400
0.001
0.040
0.003
O.D01
0.001
0.300
0.001
0.001
0.000
0.002
0.000
0.000
0.001
0.001
0.000
0.001
0.000
0,001
0.000
0.000
o.ooo
0.001
0.001
84
-------
PM Profile Speciation Report - continued (profile 43303)
Total Participate Matter -
0*2.5 un 2.5-10 un 0-10 un
Total
Measured
CAS Number Nun Sytti
Xut
unc
fet
unc
Xut
unc
%ut unc
7440-39-3
7440-45-1
7439-97-6
7439-92-1
56
58
80
82
201
202
203
204
la
Ce
Hg
Pb
OC
EC
$04
N03
0.270
0.015
<^
0.007
NA
NA
NA
NA
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.270
0.015
<
0.007
NA
NA
NA
NA
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.270
0.015
<
0.007
NA
NA
NA
NA
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0
.270
.015
<
.007
NA
NA
NA
NA
0.020
0.001
0.000
0.001
0.000
0.000
0.000
0.000
TOTALS;
49.244
49.244
49.244
49.244
85
-------
86
-------
3.2 CHEMICAL MANUFACTURING
The manufacture of organic and inorganic chemicals involves the
production of a wide variety of end-product and intermediate chemicals.
Emissions from the chemical manufacturing industry can be high but are usually
recovered for economic reasons. The particulate emissions are usually very
finely sized and difficult to remove. Emission sources can include storage
and handling operations, reactor processes, separation processes, and fugitive
and secondary sources.
87
-------
88
-------
PH Profile Speciation Report
Profile Name
Profile Number
Data Quality
Charcoal Manufacturing
25302
C/E
Control Device : Uncontrolled
Reference(s) : 45
Data Source : Average of 2 samples collected with a 2-stage virtual
impactor from a Herchoff furnace.
SCC Assignments: 30100601
Mass Fraction Data • Size Interval (urn)
Mass Fraction
Total Particulate Hatter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
afjeu i c»
Num Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Be
B
F
Na
Kg
Al
Si
P
s
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
0-2
Xwt
1.
7.
15.
3.
5.
7.
9.
0.
0.
0.
0.
6.
0.
0.
0.
NA
NA
NA
NA
900
000
000
NA
100
000
400
500
NA
360
028
044
440
400
NA
<
054
360
NA
<
<
<
090
NA
<
NA
NA
<
NA
<
NA
.5 urn
unc
0.000
0.000
0.000
0.000
0.300
1.000
1.000
0.000
0.300
0.600
0.500
0.600
0.000
0.090
0.000
0.000
0.050
0.400
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.180
2.5-10 urn
Xwt
NA
NA
NA
NA
2.400
10.200
21.000
NA
0.800
0.900
3.600
12.900
NA
0.680
0.040
0.050
0.420
6.600
NA
<
0.022
0.140
HA
<
<
<
0.011
NA
<
NA
NA
<
NA
<
NA
unc
0.000
0.000
0.000
0.000
0.300
0.800
10.000
0.000
0.100
0.600
0.600
0.800
0.000
0.000
0.020
0.020
0.030
0.400
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.370
0-10 urn
Xut
NE
NE
NE
NE
2.230
9.113
18.962
NE
1.581
2.292
4.891
11.745
NE
0.571
0.036
0.048
0.427
6.532
NE
NE
0.033
0.215
NE
NE
NE
NE
0.038
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.206
0.736
0.000
0.000
0.188
0.378
0.476
0.841
0.000
0.000
0.000
0.000
0.035
0.482
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.530
total
Measured
Xwt
NE
NE
NE
NE
2.230
9.113
18.962
NE
1.581
2.292
4.891
11.745
NE
0.571
0.036
0.048
0.427
6.532
NE
NE
0.033
.0.215
NE
NE
NE
NE
0.038
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Q.OOO
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
89
-------
PM Profile Speciation teport. - eontinued (profile 25302)
Total Particulate
US Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Nun
56
58
80
82
201
202
203
204
Hatter
••;«.c
Sym
Ba
Cm
Kg
Pb
oc
EC
S04
N03
Total
0-2
Xut
<
<
<
0.090
1.800
5.200
6.500
0.300
.5 urn
unc
0.000
0.000
0.000
0.030
0.900
0.400
0.500
0.200
2.5-10
Xut
<
<
<
NA
1.800
5.200
0.600
NA
0
0
0
0
0
0
0
0
urn
unc
.000
.000
.000
.000
.900
.400
.100
.000
0-10 urn
Xut
NE
NE
NE
NE
1.800
5.200
2.604
NE
unc
0.000
0.000
0.000
0.000
0.449
0.402
0.358
0.000
Measured
Xut
NE
NE
NE
NE
1.800
5.200
2.604
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
70.566
67.363
68.318
68.318
90
-------
PM Prof He Specintion Report
Profile Name
Profile Hunter
Data duality
Urea FertHiier Production
25404
0/E
Control Device Cyclone and Baghouse
ReferenceCs) 10
Data Source SASS train with heated Method 5 probe, 3 cyclones at 400
deg C. Cyclone and filter catches analyzed by XRF. Si, P,
and S non-quantitative. Rotary kiln emissions at control
device exit.
SCC Assignments: 30104001
Mass Fraction Date - Size Interval
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
Be
8
F
Na
MB
Al
Si
P
S
ct
K
Ca
SC
T!
V
Cr
Hn
Fe
Co
Hi
CU
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
0-2
Xwt
NA
NA
NA
NR
NR
NR
• m
NR
1,300
11.000
0.550
0.550
<
<
<
<
0.050
0.050
0.050
0.050
0.050
0.050
<
<
<
0.050
0.050
<
<
<
<
0.050
<
.5 un
unc
0.000
0.000
0.000
0.000
0,000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<0-2.5>
0.180
2.5-10 un
Xwt
2.
7.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
NA
NA
NA
NR
NR
NR
NR
NR
000
000
550
550
<
<
<
<
050
050
<
050
050
050
<
<
<
050
050
<
<
<
<
050
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.370
0-10 tin
Xwt
NE
NE
NE
NE
NE
NE
NE
NE
1.762
8.358
0.550
0.550
NE
NE
NE
NE
0.050
0.050
NE
0.050
0.050
0.050
NE
NE
NE
0.050
0.050
NE
NE
NE
NE
0.050
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.130
Total
Measured
Xwt
NA
NA
NA
NR
NR
NR
NR
NR
2.600
5.000
0.550
0.550
<
<
<
<
0.050
0.050
<
0.050
0.050
0.050
<
<
<
0.050
0.050
<
0.050
<
<
0.050
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
91
-------
PH Profile Specfat ion Report - continued (profile 25404)
Total Particular* Matter
Species
CAS Number
7440-36-0
7440-46-2
7440-39-3
7440-41-1
7439-97-6
7439-92-1
TOTALS:
SBSBSSSSESSSSS
Nun
51
55
56
•58
80
82
201
202
203
204
======
Sym
Sb
Cs
Ba
CE
H9
Pb
OC
EC
504
N03
=======
» *.
0-2
Xwt
<
<
<
<
<
<
31.000
2.000
4.000
0.550
51 .400
:=::========
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
=======
2.5-10 un
Xwt
<
- <
<
<
<
<
31.000
2.000
6.000
0.550
50.050
========
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
:=======:
.V;
31
2
5
0
50
:==
0-10 -urn
Xwt
NE
NE
NE
NE
NE
NE
.000
.000
.321
.550
.491
=====
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
========
Total
Measured
Xwt
„
<
<
<
<
^<
31.000
2.000
8.000
0.550
50.700
========
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
======
92
-------
PM Profile Speciation Report
Profile Name : Boric Acid Manufacturing
Profile Number : 25405
Data Quality : D/E
Control Device : Baghouse
Reference(s) : 10
Data Source : SASS train with heated Method 5 probe, 3 cyclones, at 400
deg F. Cyclone and filter catches analyzed by XRF. Si, P,
and S non-quantitative. Average of 2 tests at the outlet
of the baghouse.
SCC Assignments: 30199998, 30199999
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Particulate
P.UK
CAS Number
7440-41-7
7440-42-8
7782-41 -4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31 -5
»p
0-2
Xwt
NA
77.640
NA
NR
NR
NR
<
<
0.660
0.550
<
0.050
•c
<
<
<
<
0.550
<
0.050
0.050
0.050
<
<
<
<
<
<
<
<
0.050
0.050
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-E.5)
0.030
2.5-10 urn
Xwt
77
0
0
0
0
0
0
0
0
0
NA
.640
NA
NR
NR
m
<
<
.660
.550
<
.050
<
<
<
<
«
.550
<
.050
.050
.050
<
<
<
<
<
<
<
<
.050
.050
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.070
0-10 um
Xut
NE
77.640
NE
Ni
NE
NE
NE
NE
0.660
0.550
NE
0.050
NE
NE
NE
NE
NE
0.550
NE
0.050
0.050
0.050
NE
NE
NE
NE
NE
NE
NE
NE
0.050
0.050
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.110
Total
Measured
Xut
NA
77.640
NA
NR
NR
NR
<
<
0.660
0.550
*
0.050
<
<
<
<
<
0.550
<
0.050
0.050
0.050
<
<
<
<
<
<
<
<
0.050
0.050
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
93
-------
PN Profile Speciation Report - continued (profile 25405)
Total Particulate Matter -
0-2.5 urn 2.5-10 urn 0-10 urn
CAS Number Nun Sym
SHt
unc
XMt
unc
Xwt
unc
Total
Measured
Xwt
TOTALS;
86.250
86.250
86.250
86.250
unc
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
51
55
56
58
80
82
201
202
203
204
Sb
Cs
Ba ,
Ce
Hg
Pb
OC
EC
S04
N03
3
0
2
0
<
<
<
«
<
<
.900
.100
.000
.550
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<
<
<
<
<
<
3.900
0.100
2.000
0.550
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
NE
NE
NE
NE
NE
NE
3.900
0.100
2.000
0.550
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<
<•
<
<
<
<
3.900
0.100
2.000
0.550
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
94
-------
PM Profile Speeletion Report
Profile Name Phosphorous Plant
Profile Number 25407
Data Quality D/E
PI une
Control Device Uncontrolled
Referenced) 44
Data Source Collected with low-volume sanpler by aircraft.
SCC Assignments 30111299
Mass Fraction Data - Size Interval (cm) : (0-2.5) (0-6)
Mass Fraction : 0.780 0.910
Total Part icul ate Natter -
CAS Number
7440-41-7
7440-42-8
7782-41 -4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
spec i es
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
46
47
48
49
50
51
56
Be
B
F
Na
Mg
Al
Si
P
S
Cl
K
Ce
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Pd
Ag
Cd
in
• Sn
Sb
Ba
0-2
%Wt
1
2
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NA
NA
NA
NA
NA
.250
.790
.400
.300
.040
.340
.940
<
.018
<
.015
<
.260
<
<
<
.220
<
<
<
.012
<
<
.013
.021
.030
.041
.090
.130
.100
.700
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
NA
NA
NA
NA
NA
1.250
2.790
3.400
0.300
0.040
0.340
0.940
<
0.018
<
0.015
<
0.260
<
<
<
0.220
<
<
<
0.012
<
<
0.013
0.021
0.030
0.041
0.090
0.130
0.100
0.700
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xut
NA
NA
NA
NA
NA
1.250
2.790
3.400
0.300
0.040
0.340
0.940
<
0.018
<
0.015
<
0.260
<
<
<
0.220
<
<
<
0.012
<
<
0.013
0.021
0.030
0.041
0.090
0.130
0.100
0.700
unc
0.000
0.000
0.000
0.000
0.000
0.207
0.463
0.564
0.050
0.007
0.056
0.156
0.000
0.003
0.000
0.002
0.000
0.043
0.000
0.000
0.000
0.037
0.000
0.000
0.000
0.002
0.000
0.000
0.002
0.003
0.005
0.007
0.015
0.022
0.017
0.116
(0-10)
0.940
Total
Measured
%Ht
NA
NA
NA
NA
NA
1.250
2.790
3.400
0.300
0.040
0.340
0.940
<
0.018
<
0.015
<
0.260
<
<
<
0.220
<
<
<
0.012
<
<
0.013
0.021
0.030
0.041
0.090
0.130
0.100
0.700
unc
0.000
0.000
0.000
0.000
0.000
0.250
1.540
0.300
0.090
0.030
0.060
0.280
0.000
0.000
0.000
0.000
0.000
0.060
0.000
0.000
0.000
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.015
0.040
0.060
0.083
0.093
0.110
0.210
0.600
95
-------
PM Profile Speciatlon Report - continued (profile 25407}
Total Partieulate Matter -
Total
0-2.5 uii 2.5-10 urn 0-10 urn Measured
Species - • — - • — •-•—
CAS Nunfoer Mum Sym Xwt une %wt unc Xwt unc Xwt unc
7440-45-1
7439-97-6
7439-92-1
58
80
82
201
202
203
204
Ce
Hg
Pb
OC
EC
S04
N03
<
<
0.040
NA
NA
NA
NA
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<
<
0.040
NA
NA
HA
NA
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
<
<
0.040
NA
NA
NA
MA
0.000
0.000
0.007
0.000
0.000
0.000
0.000
<
<
0.040
MA
NA
NA
NA
0.000
0.000
0.030
0.000
0.000
0.000
0.000
TOTALS: 10.750 10.750 10.750 10.750
96
-------
PM Profile Speciation Report
Profile Name Fertilizer Production - Phosphate Rock Oust
Profile Number 25408
Data Quality D
Control Device Uncontrolledd}
Reference(s) 62,78
Data Source Data taken front Reference 62. For details, consult Reference
76,
SCC Assignments: 30102803, 30102804, 30102923, 30102924
Mass Fraction Data - Size Interval Cum) : (0-2.5) (0-6}
Mass Fraction : 0.150 0.340
Total Particulate Matter •
CAS Nunfcer
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-1
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
apvi' f es
Num Sym
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
Na
MS
Al
Si
P
s
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
AS
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
sb
Ba
La
Hg
0-2
Xwt
2
3
11
1
0
0
19
1
0
0
0
7
0
0
0
0
0
0
0
0
0
q
0
0
0
0
0
0
0
0
1
0
0
NR
MR
,543
.349
.152
.285
.364
.368
.872
.057
.138
.108
.332
.579
.032
.032
.086
.000
.000
.001
.025
.003
.551
.029
.127
.002
.004
.000
.000
.049
.038
.131
.531
.491
.005
.5 urn
unc
0.000
0.000
0.254
0.335
2.231
0.129
0.040
0.042
1.987
0.106
0.034
0.011
0.033
0.758
0.005
0.006
0.009
0.003
0.013
0.003
0.004
0.004
0.055
0.006
0.039
0.018
0.019
0.023
0.032
0.036
0.044
0.077
0.263
0.324
0.004
2.5-10 urn
Xwt
0.340
0.130
2.099
2.482
9.547
0.882
0.411
0.203
22.922
0.842
0.099
0.087
0.188
4.162
0.014
0.011
0.049
0.003
0.000
0.000
0.003
0.004
0.706
0.034
0.088
0.009
0.011
0.000
0.011
0.000
0.025
0.000
1.873
0.000
0.004
unc
0.020
0.010
0.210
0.248
1.910
0.088
0.041
0.034
2.292
0.084
0.026
0.009
0.019
0.416
0.003
0.003
0.005
0.001
0.004
0.001
0.002
0.002
0.071
0.004
0.036
0.009
0.009
0.012
0.016
0.018
0.023
0.036
0.187
0.172
0.003
0-10
Xwt
NE
HE
2.230
2.737
10.019
1.000
0,397
0.251
22.025
0.905
0.110
0.093
0.230
5.167
0.020
0.017
0.060
0.002
0.000
0.000
0.009
0.004
0.660
0.033
0.100
0.007
0.009
0.000
0.007
0.014
0.029
0.038
1.772
0.144
0.004
unC2>
unc
0.000
0.000
0.186
0.232
1.342
0.087
0.035
0.029
1.742
0.077
0.020
0.010
0.022
0.466
0.004
0.003
0.007
0.002
0.004
0.001
0.002
0.002
0.055
0.005
0.024
0.008
0.008
0.009
0.013
0.015
0.018
0.031
0.156
0.135
0.002
(0-10)
0.510
Total
Measured
%wt
0.306
0,117
2.143
2.568
9.706
0.922
0.407
0.219
22.620
0.863
0.103
0.089
0.202
4.501
0.016
0.013
0.052
0.003
0.000
0.000
0.005
0.004
0.690
0.033
0.092
0.009
0.011
0.000
0.010
0.005
0.026
0.013
1.839
0.049
0.004
unc
0.018
0.009
0.194
0.230
1.741
0.082
0.038
0.031
2.096
0.078
0.024
0.008
0.018
0.392
0.003
0.003
0.005
0.001
0.004
0.001
0.002
0.002
0.064
0.003
0.033
0.008
0.008
0.011
0.015
0.016
0.021
0.034
0.172
0.159
0.003
97
-------
PM Prof i le Speciati on Report • continued Cprofile 25408)
Total ParticuUte Matter -
Total
0-2.5 tin 2.5-10 un 0-10 un€2> Measured
Species , • ----------- -------- - — •• --------- - -•• ---- • ---- --
CAS Hunter Nun *Sym Xut une Sat une %ut unc Xwt urtc
7439-92-1 82 Pb 0.143 0.01? 0.035 0.001 0.066 0.009 0.045 0.002
7440-69-9 83 Bi MR 0.000 O.GOO 0.020 HE 0.000 0.000 0.018
TOTALS! 51,427 47.274 48.159 47.685
•CO No control specif fed; thus, assumed uncontrolled.
<2> Calculated based on methodology described in the Air Emissions Species Manual,
Volune II.
98
-------
PM Profile Spec?at ion Report
Profile Name
Profile Number
Data Quality
Ammonium Nitrate - Prfll Tower
25409
Control Device
Reference(s)
Data Source
UncontrolledC1>
62.78
Data taken from Reference 62. For details, consult Reference
78.
SCC Assignments: 30102712
Mass Fraction Data - Size Interval Cut>> : <0-2.5> <0-6> 2.5-10 unK2> 0-10 un<2> Measured
Species •— .
CAS Number Hum Sym %ut urvc %wt unc Xwt unc Xwt unc
204 M03 77.500 0.000 77.500 0.000 77.500 0.000 77.500 7.750
TOTALS: 77.100 77.500 77.500 77.500
•C1> No control specified: thus, assumed uncontrolled.
C2> Estimated / extrapolated.
99
-------
PH Profile Special!on Report
Profile Name Ammonium Sulfate Production
Profile Number 25410
Data Quality E
Control Device Uncontrolled^}
Reference(s) 62,78
Data Source Data taken from Reference 62. for details, consult Reference
78.
SCC Assignments: 30113004, 30113005
Hess Fraction Data - Size Interval (tin) : (0-2.5) (0-6) (0-10)
Mass Fraction : 0.110 0.490 0.990
Total Paniculate Matter -
Total
0-2.5 umC2> 2.5-10 unC2> 0-10 umC2> Measured
Species
CAS Number Nun Sym Xwt unc %wt unc Xwt unc Xwt unc
7704-34-9 16 S Ni 24.200 Hi 26.155 NE 24.200 2.420 7.750
203 $04 72.700 0.000 72.700 0.000 72.700 0.000 72.700 7.270
TOTALS?
72.700
72.700
72.700
75.120
•C15 No control specified: thus, assumed uncontrolled.
•C2> Estimated / extrapolated.
100
-------
PM Profile Special ion Report
Profile Name Diammoniun Phoshate Plant
Profile Number 25411
Data Quality 0
Control Device Uneontrol LedC1>
Reference(s) 62,78
Data Source Data taken from Reference 62. For details, consult Reference
78.
SCC Assignments: 30103001, 30103002, 30103003. 30103004
Nass Fraction Data - Size Interval (un) ; (0-2. S) (0-6}
Mass Fraction : 0.300 0.620
Total Participate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
Nun
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
Sym
Be
B
F
Ha
Mg
Al
Si
p
S
Cl
K
Cs
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
En
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
0-2
Xut
0
0
0
0
0
1
25
0
6
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.092
.000
.270
.023
.103
.806
.725
.687
.868
.602
.617
.020
,042
.006
.024
.925
.000
.013
.023
.096
.001
.019
.000
.022
.000
.015
.000
.011
.028
.011
.000
.000
.012
.000
.5 urn
unc
0.023
0.092
0.092
0.900
0.012
0.221
5.161
0.145
0.937
1.174
0.120
0.123
0.004
0.008
0.003
0.005
0.185
0.210
0.004
0.005
0.019
0.002
0.009
0.003
0.004
0.003
0.004
0.005
0.021
0.015
0.011
0.020
0.027
0.030
0.037
2.5-10 urn
Xwt
NR
m
NR
NR
NR
3.561
39.441
4.541
5.327
4.271
2.105
6.520
0.199
0.035
0.000
0.151
3.551
NR
0.000
0.251
0.091
0.000
0.000
0.000
0.000
0.000
0.2Z9
0.000
0.000
0.334
0.340
0.077
0.439
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.890
9.860
1.337
1.332
1.068
0.526
1.630
0.056
0.026
0.025
0.042
0.888
0.000
0.028
0.066
0.041
0.018
0.064
0.027
0.029
0.034
0.062
0.049
0.212
0.172
0.150
0.220
0.320
0.302
0.390
0-10
Xwt
NE
NE
NE
NE
NE
2.693
34.629
3.194
5.101
4.835
1.575
4.437
0.136
0.037
0.002
0.106
2.624
NE
0.005
0.171
0.093
0.000
0.007
0.000
0.008
0.000
0.153
0.000
0.004
0.226
0.224
0.050
0.284
0.004
0.000
unC2>
unc
0.000
0.000
0.000
0.000
0.000
0.555
6.424
0.816
0.912
0.829
0.329
1.000
0.037
0.017
0.015
0.029
0.551
0.074
0.017
0.043
0.028
0.011
0.038
0.016
0.017
0.020
0.041
0.029
0.126
0.105
0.092
0.131
0.192
0.180
0.232
(0-10)
0.850
Total
Measured
Xut
NR
NR
NR
NR
NR
1.330
27.063
1.077
4.746
5.721
0.741
1.162
0.037
0.041
0.006
0.036
1.168
NR
0.011
0.044
0.096
0.001
0.018
0.000
0.020
0.000
0.003
0.000
0.010
0.056
0.041
0.007
0.041
0.011
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.332
6.766
0.269
1.187
1.430
0.185
0.290
0.009
0.010
0.005
0.009
0.292
0.000
0.006
0.011
0.024
0.004
0.014
0.005
0.006
0.006
0.008
0.009
0.038
0.029
0.023
0.038
0.053
0.055
0.070
101
-------
PH Profile Speciation Report - continued (profile 25411)
Total Particulate Matter -
0-2.5 urn 2.5-10 urn 0-10 umC2>
%ut unc Xwt unc Xut unc
Total
Measured
Species
CAS Nuifcer Nun Sym
%ut
7440-56-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
51
56
57
80
82
203
204
Sb
Sa
La
Ha
Pb
S04
N03
0.000
0.000
0.000
0.005
0.081
3.220
3.780
0
0
0
0
0
0
0
.064
.172
.239
.005
.016
.810
.950
0.000
0.000
4.411
0.000
0.194
HR
NR
0.675
1.810
2.769
0.037
0.105
0.000
0.000
0.000
0.000
2.854
0.002
0.154
HE
m
0.402
1.077
1.656
0.022
0.065
0.000
0.000
0.000
0.000
0.407
0.047
0.091
NR
NR
0.120
0.323
0.462
0,076
0.023
0.000
0,000
TOTALS:
48.147
76.068
63.608
44.032
O> No controlled specified: thus, assumed uncontrolled.
<2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
102
-------
PM Profile Speciation Report
Profile Name Superphosphate Plant
Profile Nwber 25412
Data Quality D
Control Device Uneontroll*d€l>
Reference(s) 62,73
Data Source Data taken fron Reference 62. For details, consult Reference
78.
SCC Assignments: 30102823, 30102824, 30103825
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.150 0.340
Total Paniculate Matter -
CAS Number
7782-41-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
a^fc. i «;»
Hum Sym
9
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
SO
82
f
Al
Sf
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ki
Cu
Zn
Gs
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
cd
In
Sn
Sb
Ba
U
Hi
Pb
0-2
Xwt
52
0
26
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.900
.572
.606
.070
.136
.309
.003
.079
.003
.004
.000
.001
.025
.001
.000
,001
.000
.059
.000
.005
.000
.007
.000
.000
.018
.011
.000
.010
.000
,000
.000
.000
.111
.001
.009
.5 urn
unc
5.290
0.114
2.661
0.014
0.027
0.262
0.002
0.016
0.001
0.001
0.001
0.001
0.005
0.001
0.001
0.001
0.001
0.012
0.001
0.001
0.001
0.002
0.002
0.009
0.007
0.005
0.009
0.013
0.013
0.016
0.028
0.073
0.109
0.002
0.004
2.5-10 urn
%ut
m
1.541
64.783
0.350
0.518
3.727
0.012
0.322
0.021
0.003
0.010
0.001
0.041
0.009
0.000
0.004
0.000
0.000
0.000
0.022
0.000
0.025
0.014
0.114
0.031
0.058
0.024
0.024
0.089
0.020
0.000
0.000
0.601
0.000
0.009
unc
0.000
0.308
6.478
0.087
0.114
0.745
0.016
0.064
0.010
0.006
0.007
0.007
0.023
0.009
0.009
0.007
0.005
0.017
0.007
0.009
0.010
0.012
0.014
0.062
0.044
0.037
0.062
0.083
0.091
0.111
0.190
0.499
0.732
0.012
0.026
0-10
Xwt
HE
1.256
53.554
0.268
0.406
3.016
0.009
0.251
0,016
0.003
0.007
0.001
0.036
0.007
0.000
0.003
0.000
0.017
0.000
0.017
0.000
0.020
0.010
0.080
0.027
0.044
0.017
0.020
0.063
0.014
0.000
0.000
0.457
0.000
0.009
unC2>
unc
0.000
0.180
4.224
0.050
0.066
0.431
0.009
0.039
0.006
0.003
0.004
0.004
0.013
0.005
0.005
0.004
0.003
0.010
0.004
0.006
0.005
0.007
0.008
0.035
0.024
0.021
0.034
0.045
0.050
0.060
0.103
0.271
0.399
0.007
0.014
(0-10)
0.510
Total
Measured
Xwt
NR
0.679
30.813
0.101
0.178
1.576
0.004
0.106
0.005
0.004
0.001
0.001
0.027
0.002
0.000
0.002
0.000
0.052
0.000
0.007
0.000
0.009
0.002
0.013
0.020
0.017
0.003
0.012
0.010
0.002
0.000
0.000
0.165
0.001
0.009
unc
0.000
0.136
3.081
0.021
0.036
0,315
0.004
0.021
0.002
0.002
0.002
0.002
0.006
0.002
0.002
0.002
0.001
0.010
0.002
0.002
0.002
0.003
0.003
0.015
0.011
0.009
0.015
0.020
0.021
0.027
0.046
0.120
0.178
0.003
0.006
103
-------
PH Profile SpecialIon Report - continued (profile 25412)
Total Paniculate Hatter -
0-2.5 urn
CAS Number Nun Sym Xwt unc
203 S04 0.060 0.034
204 N03 0.000 0.166
TOTALS! 82.001
S3JS===S3SS»==sss=s=s£s:s:=2r2s&sB=ssess=fflsesa
Total
2.5-10 urn 0-10 un(2> Measured
Xut unc %ut unc %ut
NR 0.000 NE 0.000 NR
NR 0.000 NE 0.000 NR
72.373 59.628 35.821
:=============i:=============3:==========
unc
0.000
0.000
•SB— — **a5*B
C1> No controlled specified: thus, assumed uncontrolled.
{2} Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
104
-------
Prof He speciotion Report
Profile Name
Profile Number
Data Quality
Superphosphate Granulation
25413
0
Control Device : Uncontrolled^}
Referenced) : 62,78
Data Source : Data taken from Reference 62. For details, consult Reference
78.
SCC Assignments: 30102823
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate
£>_.«..
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7-40-31-5
OfJVC
Nun
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
Matter
?ies
Sym
Be
B
r
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
fe
Co
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
A3
Cd
In
Sn
-
0-2
%ut
0
0
0
0
0
0
5
3
6
14
0
0
0
0
0
.000
.067
.051
.000
.000
.973
.791
.016
.112
.676
.051
.486
.019
.268
.000
0.004
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.052
.000
.127
.002
.006
.001
.043
.000
.033
.000
.021
.000
.000
.016
.020
.005
.000
.002
.005
.5 urn
unc
0.011
0.045
0.045
0.440
0.006
0.097
1.453
1.806
0.813
6.014
0.006
0.204
0.003
0.105
0.004
0.002
0.008
0.091
0.037
0.002
0.003
0.001
0.028
0.002
0.007
0.002
0.003
0.003
0.012
0.009
0.007
0.012
0.016
0.017
0.021
s CO-2.5)
: 0.150
2.5-10 urn
Xwt
NR
MR
NR
NR
NR
3.137
10.562
7.098
11.579
8.479
0.131
4.882
0.049
0.132
0.008
0,033
0.302
NR
0.041
0.023
0.014
0.005
0.000
0.000
0.002
0.000
0.211
0.000
0.000
0.367
0.229
0.002
0.137
0.173
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.784
3.675
3.924
2.895
7.313
0.102
3.163
0.048
0.094
0.044
0.037
0.224
0.000
0.072
0.051
0.032
0.025
0.086
0.038
0.045
0.049
0.064
0.069
0.305
0.230
0.223
0.306
0.422
0.446
0.547
CO-6)
0.340
0-10
Xwt
Ni
Mi
Ni
NE
Ni
2.501
9.159
5.898
9.971
10.301
0.108
3.589
0.040
0.172
0.005
0.024
0.228
Ni
0.066
0.017
0.012
0.004
0.013
0.000
0.011
0.000
0.155
0.000
0.000
0.264
0.167
0.003
0.097
0.123
0.002
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.440
2.077
2.208
1.646
4.393
0.056
1.723
0.027
0.061
0.024
0.020
0.122
0.000
0.041
0.028
0.018
0.014
0.047
0.021
0.025
0.027
0.037
0.038
0.165
0.126
0.122
0.166
0.229
0.242
0.296
(0-10}
0.510
Total
Measured
Xwt
NR
NR
NR
NR
NR
1.046
5.950
3.157
6.295
14.465
0.054
0.638
0.020
0.264
0.000
0.005
0.061
NR
0.124
0.002
0.006
0.001
0.042
0.000
0.032
0.000
0.027
0.000
0.000
0.028
0.027
0.005
0.005
0.007
0.005
unc
0.000
0.000
0.000
0.000
0.000
0.105
1.515
1.888
0.841
6.075
0.009
0.316
0.005
0.099
0.005
0.003
0.010
0.000
0.038
0.004
0.003
0.002
,0.027
0.003
0.006
0.004
0.005
0.005
0.021
0.016
0.013
0.022
0.029
0.031
0.039
105
-------
PH Profile Speeiation Report - continued (profile 25413)
Total Particulate Matter -
0-2.5 urn 2.5-10 urn 0-10 unC2>
Xwt unc Xut unc Xwt unc
Total
Measured
Species
CAS Hunber Hum Sym
Xwt
unc
7440-36-0
7440-39.3
7439-91-0
7439-97-6
7439-92-1
51
56 .
57
80
82
201
202
203
204
Sb
Ba
La
Hi
Pb
OC
EC
S04
N03
0
0
0
0
0
.000
.000
.000
.062
.016
21 .000
3
3
3
.230
.430
.140
0.037
0.095
0.136
0.007
0.005
2.100
0.323
0.343
0.314
0.000
0.000
1.764
0.000
0.126
NR
NR
NR
NR
0.978
2.595
3.655
0.072
0.134
0.000
0.000
0.000
0.000
0.000
0.000
1.245
0.018
0.094
NE
NE
NE
NE
0.530
1.408
1.983
0.039
0.073
0.000
0.000
0.000
0.000
0.000
0.000
0.056
0.059
0.020
NR
NR
m
NR
0.069
0.179
0.255
0.009
0.010
0.000
0.000
0.000
0.000
TOTALS:
62.725
49.486
44.287
32.401
C1> No controlled specified: thus, assumed uncontrolled.
C2} Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
106
-------
PM Profile Speciatfon Report
Prof i le Name Sod inn Tripolyphosphate
Profile Hunter 25414
Data Quality D
- cyclone Dust
Control Device Not ApplfcableCU
Referenee(s) 62,78
Data Source Data taken from Reference 62. For details, consult Reference
78,
SCC Assignments: 30104501
Mass Fraction Data * Size interval (urn) : (0-2.5) (0-6)
Nass Fraction : 0.300 0.620
Total Paniculate Natter -
CAS Number
7440-23-5
7439-95-4
7629-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
«pc;i- i K»
Nun Sym
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
Na
Ms
Al
si
p
s
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Co
Hi
Cu
2n
Ga
As
Se
Br
Rb
Sr
Y
2r
No
Pd
AS
Co-
in
Sn
Sb
Ba
La
0-2
Swt
2
0
2
0
q
0
0
MR
m
.537
.875
.086
.870
.380
.479
.131
0.006
0
0
0
.044
.023
.000
0.052
0
0
0
0
0
0
0
.002
.043
.122
.157
.000
.000
.000
0.060
0
0
0
0
0
0
0
0
0
0
0
1
0
.000
.004
.000
.000
.050
.000
.007
.000
.544
.063
.390
.696
.000
.5 urn
unc
0.000
0.000
0.357
0.141
0.486
0.289
0.118
0.091
0.039
0.018
0.016
0.017
0.017
0.053
0.001
0.018
0.032
0.031
0.014
0.063
0.015
0.022
0.023
0.028
0.033
0.143
0.111
0.104
0.152
0.188
0.234
0.259
0.440
1.338
1.836
2.5-10 urn
Swt
13.400
0.023
1.732
1.947
11.733
0.270
0.048
0.036
0.075
•0.006
0.004
0.001
0.014
0.097
NR
0.000
0.132
0.046
0.000
0.005
0.001
0.003
0.005
0.003
0.003
0.000
0.000
0.000
0.003
0.000
0.006
0.025
0.016
0.150
0.051
unc
2.680
0.006
0.173
0.195
2.350
0.033
0.013
0.006
0.008
0.002
0.002
0.001
0.002
0.010
0.000
0.002
0.013
0.005
0.002
0.006
0.001
0.002
0.002
0.002
0.003
0.013
0.010
0.010
0.013
0.018
0.021
0.027
0.045
0.128
0.182
0-10
Xut
NE
NE
2.016
1.569
8.328
0.482
0.165
0.192
0.095
0.006
0.018
0.009
0.009
0.081
NE
0.015
0.128
0.085
0.000
0.003
0.001
0.023
0.003
0.003
0.002
0.000
0.018
0.000
0.004
0.000
0.196
0.038
0.148
0.696
0.033
umC2>
unc
0.000
0.000
0.219
0.157
1.474
0.114
0.047
0.041
0.018
0.007
0.007
0.006
0.007
0.022
0.000
0.007
0.020
0.015
0.005
0.023
0.005
0.009
0.009
0.010
0.012
0.051
0.040
0.037
0.054
0.067
0.088
0.093
0.159
0,486
0.657
(0-10}
0.850
Total
Measured
%ut
13.400
0.023
1.732
1.947
11.733
0.270
0.048
0.036
0.075
0.006
0.004
0.001
0.014
0.097
HE
0.000
0.132
0.046
0.000
0.005
0.001
0.003
0.005
0.003
0.003
0.000
0.000
0.000
0.003
0.000
0.006
0.025
0.016
0.150
0.051
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.coo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
107
-------
PH Profile Spec! at ion Report - continued (profile 25414)
Total Porticulate Natter -
Total
0-2.5 un 2.5-10 urn 0-10 unC2> Measured
Species .................... ---• ............. - ..........
CAS Number Nun Sym Xwt unc Xwt unc %wt unc Xut unc
7419*97-6 80 Hg 0.020 0.023 0.001 0.003 0.008 0.008 0.001 0.000
7439-92-1 82 Pb 0.615 0.112 0.072 0.008 0.264 0.051 0.072 0.000
7440-69-9 83 Bi NR 0.000 0.000 0.005 m 0.000 0.000 0.000
TOTALS: 11.256 29.908 14.638 29.908
<1> No controlled specified: thus, assumed uncontrolled.
C2> Calculated based on nethodology described In the Air Emissions Species Manual,
Volume II.
108
-------
PM Profile Speciation Report
Profile Nam : NPK Fertilizer
Profile Number : 25415
Data Quality : E
Control Device : UneontrolledCt>
Reference(s) : 62,78
Data Source : Data taken from Reference 62. For details, consult Referenc
re.
SCC Assignments: 30104501
Mass Fraction Data - Size Interval (un) : (0-2.5) (0-6) (0-10)
Mass Fraction : 0.150 0.340 0.510
Total Participate Natter -
Total
0-2.5 un 2.5-10 urn 0-10 urn Measured
Species
CAS Number Nun Sym Swt unc Xwt unc Xwt unc Xwt unc
7723-14-0 15 P 20.000 0.000 20.000 0.000 20.000 0.000 20.000 10.000
7440-09-7 19 K 18,000 0.000 18.000 0.000 1S.OOO 0.000 18.000 10.000
TOTALS: 38.000 36.000 38.000 38.000
O> Estimated / extrapolated.
109
-------
110
-------
3.3 FOOD AND AGRICULTURE
This category includes farming operations and meat and crop processing.
Processes involved in the production of food and agricultural products include
harvesting, refinement, preservation, storage and handling, and packaging.
Refinement processes can inclyde cleaning, drying, grinding, mixing, and
fermentation. Particulate emissions ire the dominant emission type from this
source category.
Ill
-------
112
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Feed and Gram Handling Dust
21401
D/E
Control Device Uncontrolled
Reference(s) 10
Data Source SASS train with heated Method 5 probe, 3 cyclones, at 400
deg f, Cylone and filter catches analyzed by XRF. si,
P, and S non-quantitative.
SCC Assignments: 30200505, 30200506
Mass Fraction Data - Size
Total Paniculate
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
.»_ — -
spec
Hum
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
Mass
Matter -
nes
Sym
Bf
B
f
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
2n
Ga
Ge
As
Se
Sr
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Interval
Fraction
0-2.5
Xwt
NA 0
NA 0
• NA 0
NR 0
NR 0
NR 0
15.000 0
< 0
< 0
< 0
0.550 0
0.550 0
< 0
< 0
< 0
< 0
< 0
0.050 0
< 0
< 0
(urn)
urn
unc
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0.050 0.000
< 0
< 0
< 0
. < o
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
(0-2.5)
: 0.
140
2.5-10 urn
Xwt
NA
NA
NA
NR
NR
NR
15.000
.<
<
<
0.550
0.550
<
<
<
<
<
0.050
<
<
0.050
<
<
<
<
<
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0
,310
0-10 tin ,
Xwt
NE
NE
NE
NE
NE
NE
15.000
HE
NE
NE
0.550
0.550
NE
NE
NE
NE
NE
0.050
NE
m
0.050
NE
NE
NE
NE
NE
NE
NE
NE
Ni
NE
Ni
NE
NE
unc
0
0
.000
.000
0.000
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
,000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0.000
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
(0-10)
0
Total
.490
Measured
Xwt unc
NA 0
NA 0
NA 0
NR 0
NR 0
NR 0
15.000 0
< 0
< 0
< 0
0.550 0
0.550 0
< 0
< 0
< 0
< 0
< 0
0.050 0
< 0
< 0
0.050 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
113
-------
PH Profile Speciation Report - continued (profile 21401)
Total Particulate
C»A.
CAS Number Nun
7440-46-2 S5
7440-39-3 56
7440-45-1 SB
7439-97-6 80
7439-92-1 82
TOTALS:
200
202
203
204
Hatter
Syro
Cs
Ba
Ce
HO
Pb
TC
EC
S04
N03
0-2,
Xwt
-
30.
0.
46.
*
<
000
NA
550
NA
750
.5 un
urn:
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
*
<
30.000
NA
0.550
NA
46.750
0*10 urn
unc %ut
0.000
0.000
0.000
0.000
0.000
0.000 30
0.000
0.000 0
0.000
46
m
m
NE
NE
NE
.000
NE
.550
NE
.750
======= ===============================::=========================
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
%wt
<
<
30.000
NA
0.550
NA
46.750
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
=====================
114
-------
3.4 PRIMARY METAL PRODUCTION
Primary metal production is the production of metals from unprocessed
ore. Processes involved depend on the element of concern. Processes
generating particulate emissions in this industry include smelting operations,
grinding, sintering, electrolytic processes, refining, and leaching.
115
-------
116
-------
PM Profile Speciation Report
Proffie Name ; Primary Lead Smelting - Ore Concentrate
Profile Number : 21102
Data Quality : B/C
Control Device : Uncontrolled
Reference(s) : 43
Data Source : Proportioning and blending operation. Sampled by
dichotomous and low-volume samplers.
SCC Assignments: 30301004, 30301005, 30301011, 30301012. 30301013, 30301014
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
opct
Hum
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
38
46
47
48
49
50
51
56
80
82
201
202
Natter
nes
Sytn
Be
B
f
Na
Ma
Al
Si
p
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni"
Cu
2n
As
Se
Br
Sr
Pd
Ag
Cd
in
Sn
Sb
Ba
Hg
Pb
OC
iC
-
0-2
Xwt
1
3
0
8
1
0
2
0
0
0
3
0
1
3
1
0
0
0
NA
NA
NA
NA
NA
.300
.800
.500
.000
.000
.880
.200
.100
<
.092
.200
.700
.040
.200
.492
.340
.024
.200
.056
0.044
0
0
0
0
0
0
.140
.788
.013
.101
.299
.172
0.042
10
.377
NA
NA
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.200
0.400
0.100
1.000
0.100
0.100
0.220
0.030
0.000
0.000
0.030
0.400
0.000
0.200
0.349
0.134
0.000
0.050
0.000
0.021
0.039
0.090
0.000
0.064
0.132
0.297
0.014
1.034
0.000
0.000
: <0
: 0
•2.5)
.820
2.5-10 urn
%wt
NA
NA
NA
NA
NA
0.500
1.800
0.200
4.000
0.160
0.250
2.100
0.100
NR
0.107
0.280
5.300
0.050
1.600
3.817
0.737
0.021
0.040
0.101
0.085
0.159
0.536
0.011
0.160
0.717
0.083
0.033
13.786
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.100
0.200
0.050
1.000
0.040
0.030
0.210
0.300
0.000
0.011
0.040
0.530
0.000
0.200
0.382
0.074
0.000
0.000
0.010
0.000
0.016
0.054
0.000
0.016
0.072
0.021
0.000
1.379
0.000
0.000
(0-6)
0.890
0-10 urn
Xwt
ME
NE
NE
NE
NE
1.213
3.583
0.467
7.565
0.909
0.812
2.189
0.100
NE
0.094
0.209
3.874
0.041
1.243
3.527
1.274
0.024
0.183
0.061
0.048
0.142
0.761
0.013
0.107
0.344
0.162
0.041
10.748
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.266
0.663
0.121
1.691
0.160
0.148
0.470
0.269
0.000
0.000
0.062
1.007
0.000
0.357
0.799
0.236
0.000
0.000
0.000
0.000
0.046
0.152
0.000
0.063
0.166
0.266
0.000
2.663
0.000
0.000
CO-10)
0.920
Total
Measured
Xwt
NA
NA
NA
NA
NA
0.500
1.500
0.306
4.000
0.160
0.373
3.290
0.101
0.020
0.179
0.460
9.150
0.091
2.575
6.659
1.097
0.050
0.040
0.176
0.095
0.239
0.834
NR
0.224
0.979
0.185
0.047
22.871
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.100
0.500
0.031
1.000
0.040
0.037
0.329
0.011
0.000
0.018
0.046
0.915
0.000
0.257
0.666
0.110
0.000
0.020
0.018
0.000
0.024
0.083
0.000
0.022
0.098
0.036
0.000
2.287
0.000
0.000
117
-------
PH Profile Speciation Report - continued (profile 21102}
Total Paniculate Natter -
Total
0-2.5 unt 2.5-10 urn 0-10 urn Measured
Species -— •
CAS Number Hum Sytn Xut unc Xut tnc Xut unc Xwt unc
203 S04 NA 0.000 NA 0.000 - NE 0.000 NA 0.000
204 K03 NA 0.000 NA 0.000 .NE 0.000 NA 0.000
TOTALS: 40.100 36.733 39.734 56.201
sacs ar&sssjB&sssssssaesssssasKssass BSSSSESSSSSSSBBS BiasssBesisEsssaaBssssssssBBsssBsas ssssssassas
118
-------
PH Profile Speciation Report
Profile Name : Primary Lead Smelting - Ore Concentrate Composite
Profile Nunber : 21103
Data Quality : C/D
Control Device : Uncontrolled
ReferenceCs) : 43 .
Data Source : Fugitive dust from storage and handling. Average of 14
lead material and ore samples each sieved and resuspended.
SCC Assignments: 30301004, 30301005, 30301011, 30301012, 30301013, 30301014
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate
e«j»
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
ape*
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Natter
wfes
Sym
Be
B
F
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
*"
0-2
Xut
4
9
0
17
0
0
2
0
0
0
0
6
0
6
3
3
0
0
0
0
0
0
4
NA
NA
NA
NA
NA
.374
.709
.808
.067
.016
.895
.025
<
.219
.027
.039
.296
.708
<
.092
.588
.561
<
<
.935
.030
.353
<
.056
<
.600
.213
.292
.593
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
2.914
6.315
0.159
4.343
0.049
0.489
1.218
0.000
0.104
0.013
0.016
0.482
5.077
0.000
0.047
5.355
2.921
0.000
0.000
2.847
0.023
0.237
0.000
0.105
0.000
0.571
0.183
0.252
4.246
0.000
: CO-2.5J
; 0.690
2.5-10 un
Xut
NA
NA
NA
NA
NA
2.280
5.627
0.539
12.353
0.000
0.486
1.888
<
0.172
0.014
0.031
0.206
6.448
<
0.102
7.088
4.300
.<
<
3.679
0.033
0.335
<
0.063
<
0.596
0.393
0.385
4.178
<
unc
0.000
0.000
0.000
0.000
0.000
2.064
4.352
0.109
2.980
0.000
0.533
1.099
0.000
0.093
0.011
0.017
0.305
5.536
0.000
0.066
5.705
3.241
0.000
0.000
2.745
0.021
0.219
0.000
0.154
0.000
0.370
0.017
0.214
4.316
0.000
(0-63
0.800
0-10 urn
Xwt
NE
NE
NE
NE
NE
3.960
8.902
0.755
16.135
0.013
0.814
1.998
NE
0.210
0.024
0.037
0.278
6.657
NE
0.094
6.687
3.707
NE
NE
3.884
0.031
0.349
HE
0.057
NE
0.599
0.249
0.310
4.511
NE
unc
0.000
0.000
0.000
0.000
0.000
2.919
.6.284
0.190
4.855
0.039
0.592
1.353
0.000
0.116
0.014
0.020
0.459
6.118
0.000
0.067
6.373
3.557
0.000
0.000
3.231
0.025
0.265
0.000
0.150
0.000
0.554
0.156
0.271
4.908
0.000
(0-10)
0.860
Total
Measured
Xwt
NA
NA
NA
NA
NA
2.238
5.581
0.495
10.715
0.029
0.441
1.479
<
0.167
0.019
0.035
0.211
7.044
<
0.125
7.312
4.647
<
<
3.074
0.022
0.315
<
0.059
<
0.610
0.382
0.313
4.723
<
unc
0.000
0.000
0.000
0.000
0.000
2.073
4.510
0.121
4.069
0.183
0.504
1.239
0.000
0.109
0.000
0.017
0.324
6.466
0.000
0.079
6.216
3.911
0.000
0.000
3.755
0.013
0.299
0.000
0.158
0.000
0.648
0.190
0.245
5.568
0.000
119
-------
PH Profile Speciatico Report - continued (profile 21103)
Total Paniculate Hatter -
. 0-3,5 an 2.5-10 on 0-10 urn
Xut unc Xut unc %wt unc
Total
Measured
Species
CAS timber Hun Sym
Xut
unc
7440-39-3
7440-45-1
7439-97-6
7439-92-1
56
58
80
82
201
202
203
204
Bo
Ce
Kg
Pb
OC
EC
S04
N03
0.266
<
0.026
24.865
NA
HA
NA
NA
0.449
0.000
0.020
15.000
0.000
0.000
0.000
0.000
0.077
<
0.026
25.959
NA
NA
NA
NA
0.070
0.000
0.023
16.800
0.000
0.000
0.000
0.000
0.229
HE
0.026
25.081
NE
NE
NE
NE
0
0
0
0
0
0
0
0
.366
.000
.025
.000
.000
.000
.000
.000
0.113
<
0.034
28.996
NA
NA
NA
NA
0.071
0.000
0.039
16.700
0.000
0.000
0.000
0.000
TOTALS:
87.653
77.258
85.597
79.179
120
-------
PM Profile Specialion Report
Profile Name Primary
Profile Hunber 21150
Data Quality D
Lead
Smelting Materials
Handling - Composite
Control Device Uncontrolled
Reference^} 43
Data Source Developed from profiles 21102, 21103, and 21206.
SCC Assignments 30301004, 30301011, 30301012, 30301013, 30301014, 30330111
Mass Fraction Data - Size Interval (un) : (0-2.5) (0-6)
Mass Fraction ; 0,730 0.830
Total Particulate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
af^Rsu i es
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
46
47
48
49
50
51
Be
B
F
Na
Ms
Al
Si
p
s
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ki
Cu
Zn
Ga
Ge
As
Se
Br
Kb
Sr
Zr
Pd
Ag
Cd
In
Sn
Sb
0-2
%ut
0
0
0
0
0
2
4
0
8
0
0
1
0
0
0
0
0
3
0
0
2
2
0
0
1
0
0
0
0
0
0
0
0
0
0
1
.000
.000
.000
.000
.000
.062
.871
.462
.953
.427
.672
.546
.000
.113
.013
.044
.172
.581
.000
.044
.642
.590
.000
.000
.815
.018
.215
.000
.037
.000
.015
.247
.496
.004
.137
.631
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
1.687
3.654
0.110
2.577
0.074
0.289
0.715
0.000
0.062
0.008
0.009
0.279
2.940
0.000
0.027
3.094
1.699
0.000
0.000
1.646
0.013
0.140
0.000
0.061
0.000
0.012
0.332
0.134
0.000
0.162
2.455
2.5-10 un
%wt
0.000
0.000
0.000
0.000
0.000
0.945
2.543
0.251
5.550
0.061
0.258
1.383
0.000
0.091
0.005
0.046
0.162
3.976
0.000
0.051
2.923
2.783
0.000
0.000
1.502
0.018
0.129
0.000
0.055
0.000
0.028
0.252
0.333
0.004
0.185
1.647
unc
0.000
0.000
0.000
0.000
0.000
1.193
2.51S
0.069
1.815
0.023
0.308
0.646
0.000
0.181
0.006
0.012
0.178
3.211
0.000
0.038
3.296
1.884
0.000
0.000
1.585
0.012
0.126
0.000
0.089
0.000
0.000
0.214
0.034
0.000
0.124
2.492
0-10 urn
%Ht
0.000
0.000
0.000
0.000
0.000
1.871
4.474
0.426
8.373
0.365
0.601
1.518
0.000
0.109
0.012
0.044
0.171
3.649
0.000
0.045
2.690
2.623
0.000
0.000
1.761
0.018
0.201
0.000
0.040
0.000
0.017
0.248
0.468
0.004
0.145
1.633
unc
0.000
0.000
0.000
0.000
0.000
1.735
3.736
0.124
2.892
0.082
0.361
0.836
0.000
0.160
0.008
0.014
0.276
3.666
0.000
0.040
3.778
2.151
0.000
0.000
1.916
0.015
0.159
0.000
0.090
0.000
0.011
0.330
0.134
0.001
0.171
2.915
{0-10)
0.880
Total
Measured
%wt
0.000
0.000
0.000
0.000
0.000
0.933
2.418
0.267
4.977
0.063
0.276
1.636
0.000
0.089
0.013
0.071
0.224
5.467
0.000
0.072
3.323
3. 845
0.000
0.000
1.411
0.024
0.118
0.000
0.078
0.000
0.032
0.283
0.424
0.000
0.184
1.901
unc
0.000
0.000
0.000
0.000
0.000
1.198
2.620
0.072
2.419
0.108
0.292
0.740
0.000
0.063
0.000
0.014
0.189
3.770
0.000
0.046
3.592
2.291
0.000
0.000
2.169
0.008
0.173
0.000
0.092
0.000
0.000
0.374
0.120
0.000
0.142
3.215
121
-------
PH Profile Speciation Report - continued (profile 21150}
Total Particulate Matter -
Species
CAS Number
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Nun
55
56
58
80
82
201
202
203
204
Sym
Cs
Ba •
Ce
HS
Pb
oc
EC
S04
N03
0-2
Sat
0
0
0
0
12
0
0
0
0
.000
.146
.000
.023
.471
.000
.000
.000
.000
.5 urn
unc
0.000
0.422
0.000
0.016
8.682.
0.000
0.000
0.000
0.000
2.5-10 urn
%ut
0.000
0.066
0.000
0.020
13.529
0.000
0.000
0.000
0.000
unc
0.000
0.059
0.000
0.013
9.732
0.000
0.000
0.000
0.000
0-10 urn
XMt
0.000
0.132
0.000
0.022
12.652
0.000
0.000
0.000
0.008
unc
0.000
0.354
0.000
0.018
11.032
0.000
0.000
0.000
0.000
Total
Measured
Xut
0.000
0.099
0.000
0.027
17.560
0.000
0.000
0.000
0.000
unc
0.000
0.048
0.000
0.023
9.732
0.000
0.000
0.000
0.000
TOTALS: 45.447 38.796 44.312 45.815
122
-------
PM Profile Speciat ion Report
Profile Name : Primary
Profile Hunter 21205
Data Quality D/E
Lead
Smelting - Speiss Fugitive
Control Device Uncontrolled
Reference(s) 43
Data Source Speiss fugitive dust.
SCC Assignments 30301009
Mass Fraction Data - Size Interval (un)
Mass Fraction
Total Particulate Natter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
0p
-------
PH Prof fit Speefatfon Rtport - continued (profile 21205}
Total Participate Hatter -
CAS Number
7440-45-1
7439-97-6
7439-92-1
*?}jcvjca
Nun Sym
58
80
82
201
202
203
204
Ce
Hg
Pb
oc
EC
S04
N03
0-2.5 un
Xwt
<
0.024
17.880
NA
NA
NA
NA
unc
0.000
0.000
1.788
0.000
0.000
0.000
0.000
2.5-10 un
Xwt
<
0.024
17.880
NA
NA
NA
NA
unc
0.000
0.000
1.788
0.000
0.000
0.000
0.000
0-10
Xwt
KE
0.024
17.880
NE
NE
NE
NE
un
unc
0
0
3
0
0
0
0
.000
.004
.514
.000
.000
.000
.000
Total
Measured
Xwt
<
0.024
17.880
NA
NA
NA
NA
unc
0.000
0.000
1.788
0.000
0.000
0.000
0.000
TOTALS: 81.159 81.159 81.159 81.119
124
-------
Ptt Profile Specialion Report
Profile Name Primary Lead Smelting - Soda Flux Fugative Dust
Profile Number 21206
Data Quality C/D
Control Device Uncontrolled
Reference(s) 43
Data Source Soda flux fugitive dust.
SCC Assignments 30301004, 30301005, 30301011, 30301012,
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.690
Total Participate
Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
opeu i ea
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Be
B
F
Na
Kg
Al
Si
P
s
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
30301013, 30301014
(0-6)
0.800
CO-10)
0.860
Total
0-2.5 urn
Xut
NA
NA
NA
NA
NA
0.511
1.105
0.079
1.792
0.266
0.240
0.414
<
0.019
0.013
0.000
0.021
0.336
<
0.000
0.137
0.717
<
<
0.169
0.000
0.093
<
0.000
<
0.000
0.487
0.017
0.000
<
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.103
0.139
0.030
0.261
0.065
0.042
0.053
0.000
0.000
0.000
0.000
0.000
0.049
0.000
0.000
0.020
0.082
0.000
0.000
0.049
0.000
0.015
0.000
0,012
0.000
0.055
0.109
0.105
0.191
O.OOQ
0.495
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2.5-10 urn
Xwt
NA
NA
NA
NA
NA
.055
.201
.013
.298
.022
.038
.161
<
.000
.000
.000
.000
,180
<
.000
.080
.233
<
<
.090
.000
.011
«
.000
<
,000
.070
.011
.046
<
.038
unc
0.000
0.000
0.000
0.000
0.000
0.014
0.020
0.000
0.047
0.000
0.000
0.016
0.000
0.000
0.000
0.000
0.000
0.018
0.000
0.000
0.000
0.023
0.000
0.000
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.014
0.014
0.028
0.000
0.072
0-10 tin
Xwt
NE
NE
NE
NE
NE
0.421
0.926
0.066
1.497
0.218
0.200
0.364
NE
0.015
0.010
0.000
0.017
0.305
NE
0.000
0.126
0.621
NE
NE
0.153
0.000
0.077
NE
0.000
NE
0.000
0.405
0.016
0.009
NE
0.008
unc
0.000
0.000
0.000
0.000
0.000
0.102
0.170
0.026
0.296
0.060
0.044
0.067
0.000
0.002
0.001
0.000
0.002
0.060
0.000
0.000
0.024
0.109
0.000
0.000
0.046
0.000
0.016
0.000
0.010
0.000
0.044
0.104
0.085
0.155
0.000
0.401
Measured
Xwt
NA
NA
NA
NA
NA
0.062
0.174
0.000
0.215
0.000
0.014
0.139
<
0.000
0.000
0.000
0.000
0.206
<
0.000
0.082
0.229
<
<
0.063
0.000
0.000
<
0.000
<
0.000
0.055
0.014
0.000
<
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.017
0.000
0.036
0.000
0.000
0.014
0.000
0.000
0.000
0.000
0.000
0.021
0.000
0.000
0.000
0,023
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.011
0.000
0.023
125
-------
PH Profile Specfntion Report - continued {profile 21206)
Total Participate Natter -
Total
0-2.5 un 2.5-10 un 0-10 un Measured
Species — - —• - —
CAS Number Nun Syro Xwt unc %wt unc Xut unc Xwt line
7440-45-1
7439-97-6
7439-92-1
58
80
82
201
202
203
204
Ce
Kg
Pb
oc
EC
S04
K03
<
0.000
2.172
NA
NA
NA
NA
0.000
0.014
0.243
0.000
0.000
0.000
0.000
<
0.000
0.841
NA
NA
NA
MA
0,000
0.000
0.084
0.000
0.000
0.000
0.000
NE
0.000
1.909
NE
NE
NE
NE
0.000
0.011
0.335
0.000
0.000
0.000
0.000
<
0.000
0.813
NA
NA
NA
NA
0.000
0.000
0.081
0.000
0.000
0.000
0.000
TOTALS: 8.588 2.388 7.363 2.066
126
-------
PH Profile Speciat ion Report
Profile Name Copper Ore Crushing
Profile Number 21301 :
Data Duality D/E
Control Device Uncontrolled
Reference(s) 44
Data Source Fugitive dust. Bulk sanple sieved and
SCC Assignments 30302401
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.150
Total Paniculate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440- 02 -0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
apci* * «;»
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
Be
B
F
Ne
Hg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
0-2
Stat
18.
42.
0.
1.
0.
3.
0.
0.
0.
0.
0.
4.
0.
1.
0.
0.
0.
0.
0.
0.
0.
NA
NA
NA
NA
NA
798
046
541
600
122
942
881
311
046
030
087
359
012
009
212
<
018
013
<
<
041
<
<
<
<
023
<
025
<
<
656
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
1.880
4.205
0.054
0.172
0.035
0.394
0.088
0.031
0.000
0.000
0.000
0.436
0.000
0.101
0.022
0.000
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.027
0.039
0.056
0.059
0.072
0.127
0.353
2.5-10 urn
%wt
NA
NA
NA
NA
NA
13.899
31 .945
0.258
1.149
0.102
3.662
0.717
0.390
0.032
0.021
0.102
4.062
0.510
Total
Measured
Xwt
NE
NE
NE
NE
NE
15.340
34.916
0.341
1.282
0.108
3.744
0.765
0.367
0.036
0.024
0.098
4.1'-9
NE
1.047
0.227
NE
0.029
NE
NE
NE
0.036
NE
NE
NE
NE
NE
NE
NE
NE
NE
0.218
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
127
-------
PM Profile Speciation Report - continued {profile 21301)
Total PartfeuUte Matter -
Total
0-2.5 urn 2.5-to urn 0-10 urn Measured
Species ....... ..... . . . . ,
CAS Number Nutn Syni %wt unc Xut unc Xut unc Xut unc
7439-91-0
7439-97-6
7439-92-1
57
80
82
201
202
203
204
La
Hg
Pb
OC
EC
S04
N03
<
<
0.214
NA
NA
NA
NA
0.000
0.000
0.029
0.000
0.000
0.000
0.000
<
<
0.105
NA
NA
NA
NA
0
0
0
0
0
0
0
.075
.000
.010
.000
.000
.000
.000
NE
NE
0.137
NE
NE
NE
NE
0.000
0.000
0.013
0.000
0.000
0.000
0.000
NE
NE
0.137
NE
NE
NE
NE
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS! 74.986 57.973 62.864 62.864
128
-------
Ml Profile Speciatfon Report
Profile Name Copper Ore Mill Uastepile
Profile Number 21102
Data Quality 0/E
Control Device Uncontrolled
Reference(s) 44
Data Source Bulk sample sieved and resuspended.
SCC Assignments 30302401
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction ; 0.150
Total Participate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
Nun
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
Sym
Be
8
F
Na
Hg
At
Si
p
S
Cl
1C
Ca
Ti
V
Cr
Nn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
0-2
%Ht
21
40
0
1
NA
NA
NA
NA
NA
.269
.602
.346
.349
0.111
4
0
0
0
0
.353
.561
.292
.025
.028
0.108
3
1
0
0
0
0
0
0
.075
<
.234
.400
<
.049
<
<
<
.026
<
<
<
<
<
.046
<
<
.053
.106
.5 Lin
unc
0.000
0.000
0.000
0.000
0.000
2.127
4.060
0.035
0.135
0.025
0.435
0.056
0.029
0.000
0.000
0.011
0.307
0.000
0.123
0.040
0.000
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
0.025
0.038
0.038
0.048
0.088
0.222
2.5-10 urn
Xut
NA
NA
NA
NA
NA
14.655
30.240
0.203
1.272
0.102
3.900
0.757
0.422
0.030
0.018
0.112
3.270
<
1.238
0.496
<
0.062
<
<
0.022
0.032
<
<
0.038
<
<
<
0.014
<
<
0.066
unc
0.000
0.000
0.000
0.000
0.000
1.465
3.024
0.020
0.127
0.010
0.390
0.076
0.042
0.000
0.000
0.011
0.327
0.000
0.124
0.050
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
0.038
(0-6)
0.340
0-10 un
Xwt
NE
NE
NE
NE
NE
16.600
33.288
0.245
1.295
0.10S
4.033
0.699
0.384
0.029
0.021
0.111
3.213
NE
1.237
0.468
NE
0.058
NE
NE
NE
0.030
NE
NE
NE
NE
NE
NE
NE
NE
NE
0.078
unc
0.000
0.000
0.000
0.000
0.000
1.316
2.579
0.020
0.094
0.010
0.298
0.048
0.026
0.000
0.000
0.008
0.229
0.000
0.089
0.033
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.066
(0-10)
0.510
Total
Measured
Xwt
NE
NE
NE
NE
NE
16.600
33.288
0.245
1.295
o.tos
4.033
0.699
0.384
0.029
0.021
0.111
3.213
NE
1.237
0.468
NE
0.058
NE
NE
NE
0.030
NE
NE
NE
NE
NE
NE
NE
NE
NE
0,078
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
129
-------
PH Profile Speeiation Report - continued (profile 21302}
Total Participate Matter -
Total
0-2.5 UMI 2.5-10 urn 0-10 urn Measured
Species • -• • — •
CAS Number Nun Sym Xut unc Xut unc X*rt unc Xut unc
7439-91-0
7439-97-6
7439-92-1
57
80
82
201
202
203
204
La
HB
Pb
oc
EC
S04
1103
«
<
0.287
MA
NA
NA
0.000
0.000
0.000
0.029
0.000
0.000
0.000
0.000
<
<
0.202
NA
NA
NA
0.000
0.061
0.000
0.020
0.000
0.000
0.000
0.000
NE
NE
0.227
NE
NE
NE
0.000
0.000
0.000
0.018
0.000
0.000
0.000
0.000
NE
NE
0.227
NE
NE
NE
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS! 74.320 57.151 62.121 62.121
130
-------
PH Profile Speciat ion Report
Profile Name Copper Ore Concentrate
Profile number 21303
Data Quality D/E
Control Device Uncontrolled
Refer ence(s) 44
Data Source Fugitive dust. Bulk sample sieved and
SCC Assignments 30302404
Mass Fraction Data * Size Interval (urn) : (0-2.5)
Mass Fraction ; 0.150
Total Paniculate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
" 7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
opeu i ea
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
Be
6
F
Na
MS
Al
Si
P
S
Cl
K
ca
Ti
V
Cr
Mn
Fe
Hi
Cu
In
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
0-2
%wt
7
15
0
12
0
1
0
0
0
0
0
10
0
21
4
1
0
0
0
0
0
0
0
0
NA
NA
NA
NA
NA
.923
.915
.596
.929
.020
.745
.517
.239
.039
.050
.087
.355
.103
.726
.717
NA
.016
.012
.081
NA
.017
NA
NA
NA
<
.090
.043
.019
.036
.094
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.792
1.S95
0.060
1.293
0.042
0.174
0.052
0.024
0.000
0.000
0.000
1.035
0.010
2.173
0.472
0.000
0.102
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
0.012
0.012
0.014
0.026
0.068
2.5-10 urn
Xwt
NA
NA
NA
NA
NA
2.648
5.969
0.326
10.182
<
0.887
0.456
0.219
0.034
0.042
0.069
12.101
0.109
22.110
6.446
0.051
0.991
<
0.081
«
0.017
<
0.035
0.520
0.020
0.063
0.052
0.025
0.051
0.073
<
unc
0.000
0.000
0.000
0.000
0.000
0.265
0.597
0.033
1.018
0.032
0.089
0.046
0.022
0.000
0.000
0.000
1.210
0.011
2.211
0.645
0.000
0.099
0.000
0.000
0.000
0.000
0.000
0.000
0.052
0.000
0.000
0.000
0.000
0.000
0.000
0.015
resuspended.
(0-6)
0.340
0-10 urn
Xwt
NE
HE
ME
HE
NE
4.199
8.906
0.405
10.990
NE
1.139
0.474
0.225
0.035
0.044
0.074
11.587
0.107
21.997
5.937
NE
0.998
Ni
0.081
NE
0.017
NE
NE
NE
NE
0.071
0.049
0.023
0.047
0.079
NE
unc
0.000
0.000
0.000
0.000
0.000
0.426
0.868
0.035
0.838
0.000
0.100
0.035
0.017
0.000
0.000
0.000
0.811
0.008
1.579
0.407
0.000
0.072
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.510
Total
Measured
Xtrt
NE
NE
NE
NE
NE
4.199
8.906
0.405
10.990
NE
1.139
0.474
0.225
0.035
0.044
0.074
11.587
0.107
21.997
5.937
NE
0.998
NE
0.081
Ni
0.017
NE
NE
NE
NE
0.071
0.049
0.023
0.047
0.079
NE
" unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
131
-------
PH Profile Speciatfon Report - continued (profile 21303)
Total Participate Hatter -
Total
CAS Number
7439-91-0
7439-97-6
7439-92-1
ap*sw i ca
Nun Sym
57
80
82
201
202
203
204
La
Hg
Pb
OC
EC
S04
H03
0-2
Xwt
NA
0.020
1.082
NA,
NA
NA
NA
.5 IB
unc
0.000
0.000
0.108
0.000
0.000
0.000
0.000
2.5-
Xut
<
0.022
1.023
NA
NA
NA
NA
10 urn
unc
0.023
0.000
0.102
0.000
0.000
0.000
0.000
0-10 tm
%wt
NE
0.021
1.040
NE
Ni
NE
NE
unc
0.000
0.000
0.076
0.000
0.000
0.000
0.000
Measured
Xwt
NE
0.021
1.040
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 79.511 64.622 68,545 68.545
132
-------
PH Profile Speciation Report
Profile Name Copper Nining Waste
Profile Number 21304
Data Quality D/E
Control Device Uncontrolled
Reference(s) 44
Data Source Bulk sample sieved and resuspsnded.
SCC Assignments 30302404
Mass Fraction Data - Size Interval
-------
PH Profile Special ion Report- - continued (profile 21304)
Total Particulate
Matter
CAS Number
7439-91-0
7439-97-6
7439-92-1
Nun Sym
57
80
82
201
202
203
204
La
Kg
Pb
cc
EC
S04
N03
Total
0-2
Xwt
NA
<
1.197
HA
NA
NA
NA
.5 URl
unc
0.000
0.000
0.120
0.000
0.000
0.000
0.000
2.5-10 un
Xwt
<
<
0.633
NA
NA
NA
NA
unc
0.069
0.000
0.063
0.000
0.000
0.000
0.000
0-10 un
Xut
NE
NE
0.799
NE
NE
NE
NE
unc
0.000
0.000
0.069
0.000
0.000
0.000
0.000
Measured
Xwt
NE
NE
0.799
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 62.929 53.029 55.872 55.872
134
-------
PH Profile Speciation Report
Profile Name Copper
Profile Number 21320
Data Quality 1
Ore -
Composite
Control Device Uncontrolled
ReferenceCs) 44
Data Source Developed from profiles
SCC Assignments 10302401
Mass Fraction Data - Size Interval (um)
Mass Fraction
Total Participate Hatter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
0-2
Hum Sym Xwt
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
Be
B
f
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
2r
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
0
0
0
0
0
20
41
0
1
0
4
0
0
0
0
.000
.000
,000
.000
,000
,033
.324
.444
.474
.116
.147
.721
.101
.036
.029
0.098
3
0
1
0
0
0
0
0
.717
.006
.121
.306
.000
.034
.006
.000
Q.OOO
0
0
0
0
0
0
0
0
0
0
0
.034
.000
.000
.000
.000
.011
.023
.013
.000
.026
.381
.5 un
unc
0.000
0.000
0.000
0.000
0.000
2.007
4.133
0.046
0.155
0.030
0.415
0.074
0.030
0.000
0.000
0.008
0.377
0.000
0.113
0.032
0.000
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.023
0.033
0.048
0.050
0.061
0.109
0.295
21301 and 21302
: CO-2.5)
: 0.150
2.5-10 um
Xut
0.000
0.000
0.000
0.000
0.000
14.277
31.093
0.231
1.211
0.102
3.781
0.737
0.406
0.031
0.019
0.107
3.666
0.000
1.151
0.364
0.000
0.048
0.000
0.000
0.021
0.033
0.000
0.000
0.068
0.000
0.000
0.000
0.007
0.000
0.006
0.051
unc
0.000
0.000
0.000
0.000
0.000
1.428
3.110
0.023
0.121
0.010
0.378
0.074
0.041
0.000
0.000
0.011
0.369
0.000
0.115
0.039
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
0.043
CO-6>
0.340
0-10 um
Xwt
0.000
0.000
0.000
0.000
0.000
1S.970
34.102
0.293
1.288
0.106
3.889
0.732
0.375
0.032
0.022
0.104
3.681
0.002
1.142
0.347
0.000
0.043
0.002
0.000
0.015
0.033
0.000
0.000
0.048
0.000
0.003
0.007
0.009
0.000
0.012
0.148
unc
0.000
0.000
0.000
0.000
0.000
1.254
2.635
0.026
0.098
0.011
0.286
0.053
0.026
0.002
0.001
0.007
0.267
0.000
0.082
0.025
0.000
0.005
0.000
0.000
0.001
0.002
0.000
0.000
0.003
0.007
0.010
0.014
0.015
0.018
0.033
0.089
CO-10)
0.510
Total
Measured
Xwt
0.000
0.000
0.000
0.000
0.000
15.970
34.102
0.293
1.288
0.106
3.889
0.732
0.375
0.032
0.022
0.104
3.681
0.002
1.142
0.347
0.000
0.043
0.002
0.000
0.015
0.033
0.000
0.000
0,048
0.000
0.003
0.007
0.009
0.000
0.012
0.148
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
131
-------
PH Profile Speefation Report - continued (profile 21320)
Total Particutate Matter -
CAS Number
7439-91-0
7439-97-6
7439-92-1
Nun Syro
57
80
82
201
202
203
204
La
Ho
Pb
OC
EC
S04
H03
0-2
Xwt
0
0
0
0
0
0
0
.000
.000
.251
.000
.000
.000
.000
.5 un
unc
0.000
0.000
0.029
0.000
0.000
0.000
0.000
2.5-10 un
Xut
0.000
0.000
0.153
0.000
0.000
0.000
0.000
unc ,
0.068
0.000
0.016
0.000
0.000
0.000
0.000
0-10 un
Xwt
0.000
0.000
0.182
0.000
0.000
0.000
0.000
unc
0.020
0.000
0.016
0.000
0.000
0.000
0.000
Total
Measured
Xut
0.000
0.000
0.182
0.000
0,000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0,000
0,000
0.000
TOTALS:
74.652
57.563
62.587
62.587
136
-------
PM Profile Special ion Report
Profile Name Composite of
Profile Hunter 21340
Data Quality E
Copper Ore Concentrate and
Control Device Uncontrolled
Reference(s) 44
Data Source Developed from profiles 21303 and 21304
SCC Ass foments 30302404
Mass Fraction Data - Size Interval (urn) : CO-2.5)
Mass Fraction ; 0.150
Total Participate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-S
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
Nun
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
Sym
Be
B
F
Na
MS
Al
SI
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
AS
Cd
In
Sn
Sb
Ba
0-2
Xwt
0
0
0
0
0
9
20
0
8
0
2
0
0
0
0
0
12
0
11
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.685
.489
.576
.937
.059
.024
.802
.321
.041
.051
.088
.370
.058
.040
.683
.000
.533
.006
.050
.000
.009
.000
.000
.000
.000
.053
.037
.009
.018
.132
.000
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.984
2.098
0.058
0.979
0.039
0.204
0.085
0.033
0.000
0.000
0.000
1,253
0.007
1.537
0.337
0.000
0.074
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
0.023
0.032
0.034
0.037
0.070
0.196
2.5-10 un
%ut
0.000
0.000
0.000
0.000
0.000
6.208
15.273
0.318
6.437
0.048
1.490
1.197
0.369
0.035
0.039
0.088
10.604
0.054
11.191
3.571
0.025
0.517
0.000
0.041
0.007
0.013
0.000
0.026
0.267
0.010
0.032
0.026
0.013
0.025
0.059
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.716
1.789
0.032
0.745
0.024
0.161
0.141
0.040
0.000
0.000
0.008
1.071
0.008
1.563
0.456
0.049
0.070
0.000
0.000
0.000
0.000
0.000
0.000
0.037
0.000
0.000
0.000
0.000
0.000
0.012
0.034
Mining
Waste
•
<0-6)
0.340
0-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
7.231
16.807
0.394
7.172
0.051
1.647
1.080
0.355
0.037
0.043
0.088
11.123
0.056
11.146
3.310
0.018
0.522
0.002
0.043
0.005
0.015
0.000
0.018
0.188
0.007
0.038
0.029
0.012
0.023
0.081
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.598
1.337
0.034
0.584
0.014
0.129
0.077
0.025
0.002
0.003
0.006
0.833
0.005
0.918
0.250
0.015
0.043
0.000
0.003
0.000
0.001
0.000
0.001
0.016
0.004
0.007
0.010
0.010
0.011
0.022
0.059
<0-10)
0.510
Total
Measured
Xwt
0.000
0.000
0.000
0.000
0.000
7.231
16.807
0.394
7.172
0.051
1.647
1.080
0.355
0.037
0.043
0.088
11.123
0.056
11.146
3.310
0.018
0.522
0.002
0.043
0.005
0.015
0.000
0.018
0.188
0.007
0.038
0.029
0.012
0.023
0.081
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
137
-------
PH Profile Speclation Report - continued (profile 21340)
Total Paniculate Matter *
Total
0-2.5 urn 2.5*10 urn 0-10 urn Measured
Species • •- •"—
CAS Number Hum Sym Xwt unc Xut unc Xwt unc Xwt unc
7439-91-0
7430-97-6
7439-92-1
57
80
82
201
202
203
204
La
HB
Pb
DC
EC
504
N03
0
0
1
0
0
0
0
.000
.010
.139
.000
.000
.000
.000
0.000
0.000
0.114
0.000
0.000
0.000
0.000
0.000
0.011
0.828
0.000
0.000
0.000
0.000
0.051
0.000
0.085
0.000
0.000
0.000
0.000
0.000
0.011
0.920
0.000
0.000
0.000
0.000
0.015
0.001
0.072
0.000
0.000
0.000
0.000
0.000
0.011
0.920
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 71.220 58.827 62.472 62.472
138
-------
PM Profile Spectat ion Report
Profile Name Primary
Profile Number 21501
Data Quality C/0
Lead
Smelting -
Slag dust
Control Device Uncontrolled
Reference(s) 43
Data Source Sample is composite of samples from various locations on the
pile; sieved and resuspended.
SCC Assignments 30399999
Mass Fraction Data - Size Interval Cum) : (0-2.5) (0-6)
Mass Fraction : 0.150 0.340
Total Participate
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
apes
Num
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
38
46
47
48
49
50
51
56
80
82
201
202
Natter
5ies
Sym
Be
B
F
Na
M3
Al
Si
P
s
ct
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
As
Se
Br
sr
Pd
Ag
Cd
In
Sn
sb
Bo
HS
Pb
oc
EC
"
0-2
%wt
3
18
0
4
0
0
9
0
0
0
1
16
0
1
11
0
0
0
0
0
0
NA
NA
NA
NA
NA
.744
.202
.352
.260
.229
.777
.313
.372
.092
.096
.168
.292
.054
,766
.305
.634
<
.065
.182
<
.033
.050
.053
<
0.244
0
0
6
.084
.023
.114
NA
NA
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.374
1.820
0.035
0.426
0.052
0.078
0.931
0.037
0.000
0.000
0.117
1.629
0.000
0.177
1.130
0.068
0.000
0.000
0.018
0.020
0.028
0.043
0.047
0.055
0.108
0.269
0.011
0.611
0.000
0.000
2.5-10 urn
%wt
NA
NA
NA
NA
MA
2.150
11.323
0.202
2.237
0.119
0.570
7.499
0.290
0.051
0.086
0.988
15.294
0.046
1.044
7.296
0.357
<
0.031
0.150
<
<
O.OS7
<
0.094
0.069
0.194
0.014
3.159
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.215
1.132
0.020
0.224
0.025
0.057
0.750
0.029
0.000
0.000
0.099
1.529
0.000
0.104
0.730
0.036
0.000
0.000
0.015
0.000
0.012
0.020
0.018
0.023
0.042
0.109
0.000
0.316
0.000
0.000
0-10 urn
Xwt
NE
NE
NE
NE
NE
2.619
13.346
0.246
2.832
0.151
0.631
8.033
0.314
0.063
0.089
1.041
15.588
0.048
1.256
8.475
0.438
NE
0.041
0.159
NE
NE
0.041
NE
NE
0.120
0.162
0.017
4.028
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.220
1.092
0.021
0.245
0.020
0.049
0.609
0.024
0.000
0.000
0.078
1.138
0.000
0.105
0.685
0.038
0.000
0.000
0.012
0.000
0.000
0.014
0.000
0.000
0.036
0.086
0.000
0.351
0.000
0.000
(0-10)
0.510
Total
Measured
Xut
NA
NA
NA
NA
NA
2.349
12.509
0.183
1.967
0.112
0.648
9.245
0.257
0.044
0.112
1.278
21.323
0.048
1.189
9.203
0.325
<
0.034
0.195
0.018
0.018
0.055
<
0.062
0.202
0.353
0.014
3.500
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.235
1.251
0.018
0.197
0.017
0.065
0.924
0.026
0.000
0.011
0.128
2.132
0.000
0.119
0.920
0.032
0.000
0.000
0.019
0.000
0.000
0.000
0.000
0.000
0.021
0.042
0.000
0.350
0.000
0.000
13S
-------
PH Profile Specintion Report - continued (profile 21501)
Total Partfeulate Hatter -
Total
0-2.5 LID 2.5-10 urn 0-10 urn Measured
Species —• — ' —•
GAS Nunfcer Hun Sym Xut une Xut unc Xwt unc Xwt unc
203 S04 NA 0.000 NA 0.000 HE 0.000 NA 0.000
204 M03 MA 0.000 NA 0.000 NE 0.000 NA 0.000
TOTALS! 75.504 53.300 59.738 6S.243
140
-------
PM Profile Spec!at ion Report
Profile Name
Profile Number
Data Quality
Steel Production - Steel Sinter Plant
28301
D/D
Control Device Baghouse
Reference(s) 10
Data Source SASS train with heated Method 5 probe, 1 cyclones at 400
deg F. Cyclone and filter catches analyzed by XRF. Si,
P, and S non-quantitative. Average of 2 tests downstream
of baghouse.
SCC Assignments: 30300813
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Natter -
CAS Humber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
9^x5^ i es
Num Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
Be
B
F
Na
Mg
Al
Si
P
S
ct
1C
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
CU
Zn
Ca
Ge
As
Se
Br
Rb
Sr
Zr
AS
Cd
Sn
0-2
Xwt
6
17
20
0
0
3
0
13
0
2
0
0
0
0
0
0
0
0
0
0
NA
NA
NA
NA
NR
NR
NR
<
.600
.000
.000
.550
<
<
.550
.000
.550
.000
<
.550
.000
.550
<
<
.550
.050
,550
.550
.050
.050
.050
.550
.050
.5 un
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: <0-2.5)
; 0.270
2.5-10 um
Xwt
NA
NA
NA
NA
NR
NR
NR
<
2.600
14.000
9.000
1.000
«
<
<
0.550
0.550
20.000
<
<
2.000
0.550
«
<
0.550
0.050
0.550
0.550
<
<
0.050
0.550
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
«0-6)
0.600
0-10 um
Xwt
NE
HE
NE
Ni
NE
NE
NE
NE
4.165
15.174
13.304
0.824
NE
NE
NE
1.509
0.550
17.261
NE
NE
2.000
0.550
NE
NE
0.550
0.050
0.550
0.550
NE
NE
0.050
0.550
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.690
Total
Measured
Xwt
NA
NA
NA
NA
NR
NR
NR
<
6.330
28.000
19.000
0.550
<
<
<
3.000
0.550
14.000
<
<
2.000
0.550
<
<
0.550
0.050
0.550
0.550
0.050
0.050
0.050
0.550
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
141
-------
PH Profile Speciation Report - continued (profile 28301)
Total Particulate Natter -
0-2.5 un 2.5-10 urn 0-10 un
Xut unc %wt unc Xut unc
Total
Measured
Species
CAS Number Nun Sym
Xut
unc
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
============:
51
55
56
58
80
82
201
202
203
204
BBBBI
Sb
Cs
ia
Ce
H8
Pb
oc
EC
S04
1103
======:
0
0
11
20
.
98
==•==«£=
.050
<
<
.550
<
.000
NA
NA
.000
NA
.400
====S
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
=======
<
<
<
0.550
<
13.000
NA
NA
8.000
NA
74.100
=======:
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
========
m
m
HE
0.550
HE
12.217
HE
NE
12.696
NE
83.100
========
0.000
0.000
0.000
0.000 0
0.000
0.000 10
0.000
0.000
0.000 19
0.000
105
=========B
<.
<
<
.550
<
.000
NA
NA
.000
NA
.930
=====
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
======
142
-------
PM Profile Specintion Report
Profile Name : Steel Production - Open Hearth Furnace
Profile Number : 28302
Data Quality : D/E
Control Device : ESP
Reference(s) : 10
Data Source : SASS train with heated Method 5 probe, 3 cyclones at 400
deg f. Cyclone and filter catches by XRF. Si, P, and S
non-quantitative. Average of 2 tests downstream of ESP.
S is estimated at 1/3 of S04.
SCC Assignments: 30300901
Mass Fraction Data * Size Interval (urn)
Mass Fraction
Total Participate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
Hum
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
Sym
Be
S
F
Na
Mg
At
Si
P
S
ct
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
As
Cd
Sn
i
13
5
0
0
2
0
11
0
0
0
0
0
0
0
0
0-2
Kwt
NA
NA
NA
NA
NR
NR
NR
<
.300
<
.000
.550
<
<
.550
.000
.550
.000
<
.550
.550
<
<
<
.050
<
.050
.050
<
<
.050
.050
.050
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.390
2.5-10 um
Xut
NA
NA
NA
NA
NR
NR
NR
<
3.000
<
5.000
0.550
<
<
0.550
0.550
0.550
16.000
<
0.550
0.550
<
<
<
0.050
«
0.050
0.050
<
<
0.050
0.050
0.050
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.500
0-10 urn
%ut
NE
NE
NE
NE
NE
NE
NE
NE
10.579
NE
5.000
0.550
NE
NE
0.550
1.617
0.550
12.321
NE
0.550
0.550
NE
NE
NE
0.050
NE
0.050
0.050
NE
NE
0.050
0.050
0.050
unc
0.000
0.000
0.000
0.000
o.obo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.530
Total
Measured
Xwt
NA
NA
NA
NA
NR
NR
NR
<
13.300
<
5.000
0.550
<
<
0.550
2.000
0.550
11.000
<
0.550
0.550
<
<
<
0.050
<
0.050
0.050
<
<
0.050
0.050
0.050
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
143
-------
PH Profile Speciatfon Report - continued (profile 28302)
Total Perticulate Natter - ,
0-2.5 un 2.5-10 urn 0-10 urn
Total
Measured
CAS Number Nun Sym
Xut
unc
%Mt
unc
Xut
unc
XHt
TOTALS!
75.500
63.750
72.396
75.500
unc
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
51
55
56
58
80
82
201
202
203
204
Sb
Cs
Da
Ce
Hg
Pb
oc
EC
S04
N03
0.
0.
40.
0.
050
<
<
<
<
550
NA
NA
000
550
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
<
<
<
<
0.550
NA
HA
35.000
0.550
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
NE
NE
NE
NE
0.550
NE
NE
38.679
0.550
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
<
<
<
<
0.550
NA
NA
40.000
O.S50
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
144
-------
PH Proffie Spedation Report
Profile Name : Steel Production
Profile Number : 28303
Data Quality : D/E
Basic Oxygen Furnace
Control Device : ESP
Reference(s) : 10
Data Source : SASS train wtth heated Method § probe, 3 cyclones at 400
des F. Cyclone and filter catches analyzed by XRF. si,
P, and S non-quantitative. S estimated as 1/3 of S04.
SCC Assignments: 30300913
Mass Fraction Data - Size Interval (un)
Mass Fraction
Total Particulate Matter
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
Sym
Be
B
F
Na
M8
At
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
""
0-2
%Mt
,
9.
13.
5.
0.
0.
2.
0.
11.
0.
0.
q.
0.
0.
0.
0.
0.
0,
NA
NA
NA
NA
NR
NR
900
<
330
<
000
550
<
<
550
000
550
000
<
550
550
<
<
<
050
<
050
050
<
<
050
050
050
050
.5 urn
unc
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
o.ooo •
0.000
0.000
: CO-2.S)
: 0.650
2.5-10 urn
Xut
NA
NA
NA
NA
NR
NR
9,900
<
13.330
<
5.000
0.550
<
<
0.550
2.000
0.550
11.000
<
0.550
0.550
<
<
<
0.050
<
0.050
0.050
<
<
0.050
0.050
0.050
0.050
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.coo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-6J
0.660
0-10 urn
%ut
NE
NE
NE
NE
NE
NE
9.900
NE
13.330
NE
5.000
0.550
NE
NE
0.550
2.000
0.550
11.000
NE
0.550
0.550
NE
NE
NE
0.050
NE
0.050
0.050
NE
NE
0.050
0.050
0.050
0.050
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<0-10)
0.670
Total
Measured
Xwt
NA
NA
NA
NA
NR
NR
9.900
<
13.330
<
5.000
0.550
<
<
0.550
2.000
0.550
11.000
<
0.550
0.550
<
<
<
0.050
<
0.050
0.050
<
<
0.050
0.050
0.050
0.050
unc
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
145
-------
PH Profit* Speciation Report - continued (profile 28303}
'Total Particulate Matter -
0-2.5 urn 2.5-10 un 0-10 urn
Xtrt me Xut une Xut
, Total
Measured
Species
CAS Nwfcer Hum Sym
unc
XMt
unc
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
55
56
58
80
82
201
202
203
204
Cs
ia
Ce
Hi
Pb
OC
EC
S04
N03
<
<
0.550
20.000
<
40.000
0.550
105.430
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<
<
0.550
20.000
<
40.000
0.550
105.430
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
20
40
0
105
NE
NE
NE
NE
.550
.000
NE
.000
.550
.430
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
*
<
0.550
20.000
<
40.000
0.550
105.430
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
146
-------
Profile Speciation Report
Profile Name Iron Ore Dust - Sinter
Prof fit Number 28304
Data Quality D
Control Device UncontrolledCI}
Referenee(s) 62, 7$
Data Source Data taken from Reference 62. For details, consult Reference
78.
SCC Assignments: 30300813, 30400701
Mass Fraction Data - Size Interval (urn) : (0-2,5) (0-6)
Mass Fraction : 0.270 0.600
Total Particulate Matt
Species
CAS Number Him
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
SO
51
56
57
80
82
er -
0-2.5 urn
Sym %ut
Al
Si
P
S
Cl
1C
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
2
6
0
1
0
0
12
0
0
0
0
27
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.634
.447
.145
.050
.319
.300
.655
.290
.055
.094
.652
.491
,018
.053
.058
.000
.000
.001
.014
.005
.023
.009
.000
.039
.000
.000
.082
.029
.030
.037
,000
.000
.011
.060
unc
0.263
0.645
0.033
0.105
0.037
0.032
1.266
0.029
0.007
0.009
0.065
2.749
0,004
0.007
0.006
0.003
0.009
0.003
0.004
0.004
0.006
0.006
0.027
0.021
0.019
0.026
0.040
0.039
0.049
0.080
0.234
0.337
0.005
0.014
52.601
2.5-10 urn
%Ht
1.139
3.308
0.051
0.000
0.206
0.186
14.174
0.280
0.049
0.103
0.536
32.511
0.012
0.015
0.008
0.000
0.000
0.002
0.003
o.ooa
0.015
0.007
0.009
0.021
0.007
0.012
0.039
0.011
0.000
0.000
0.000
0.000
0.013
0.051
52.776
unc
0.114
0.331
0.017
0.101
0.026
0.022
1.417
0.028
0.005
0.010
0.054
3.251
0.001
0.002
0.001
0.001
0.003
0.001
0.001
0.001
0.002
0.001
0.005
0.004
0.004
0.005
0.009
0.008
0.010
0.017
0.046
0.067
0.002
0.005
0-10
%wt
1.724
4.537
0.088
0.411
0.250
0.231
13.580
0.283
0.052
0.099
0.581
30.547
0.014
0.030
0.027
0.000
0.000
0.002
0.007
0.007
0.018
0.008
0.006
0.028
0.004
0.007
0.055
0.018
0.012
0.014
0.000
0.000
0.012
0.054
52.706
umC2>
unc
0.200
0.504
0.020
0.095
0.032
0.029
1.358
0.033
0.009
0.014
0.064
3.043
0.004
0.006
0.005
0.001
0.004
0.002
0.003
0.003
0.005
0.004
0.012
0.010
0.008
0.011
0.018
0.016
0.020
0.033
0.096
0.138
0.004
0.010
(0-10)
0.690
Total
Measured
%wt
2.244
5.628
0.120
0.776
0.289
0.270
13.052
0.287
0,054
0.096
0.622
28.802
0.017
0.043
0.045
0.000
0.000
0.001
0.011
0.006
0.021
0.009
0.002
0.034
0.002
0.003
0.070
0.024
0.022
0.027
0.000
0.000
0.011
0.058
52.646
unc
0.323
0.796
0.029
0.127
0.042
0.039
1.678
0.038
0.008
0.012
0.083
3.675
0.004
0.007
0.007
0.002
0.007
0.002
0.003
0.003
0.005
0.005
0.020
0.016
0.014
0.019
0.031
0.029
0.036
0.059
0.173
0.250
0.004
0.012
{1> No controlled specified: thus, assumed uncontrolled.
<2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
-------
PM Profile Special ion Report
Profile Name
Profile Number
Data Quality
Steel
26306
D
Desulfurization Baghouse Dust
Control Device Hot Applicable
Referenced) 62,78
Data Source Sample of bsghouse dust from steel plant desulfurizatien
unJt.
SCC Assignments: 30300999
Mass Fraction Data - Size Interval (un) : (0-2.5) (0-6)
Mass Fraction : 0,420 0,650
Total Participate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
QfJCk. 1 ISO
Nun Syro
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
tc
Ca
Ti
V
Cr
Mn
Fe
Hi
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Ho
Pd
AS
Cd
In
Sn
Sb
Ba
la
Kg
Pb
0
1
0
2
0
2
25
0
0
0
0
20
0
0
0
0
0
0
0
0
0
0
0-2
%wt
.878
.628
.226
.739
.458
.539
.445
.165
.041
.064
.277
.537
.016
.016
.091
.002
.000
.004
.006
.019
.116
.003
0.000
0
0
0
0
0
.013
.000
.015
.033
.007
0.008
0
.063
0.000
0
0
0
• 55
.000
.010
.059
.478
.5 um
unc
0.088
0.163
0.053
0.274
0.046
0.254
2.545
0.017
0.005
0.006
0.028
2.054
0.004
0.005
0.009
0.003
0.008
0.003
0.003
0.005
0,012
0.006
0.025
0.019
0.018
0.026
0.034
0.034
0.043
0.073
0.213
0.301
0.005
0.013
2.5-10 um
%Ht
0.561
0,967
0.081
0.437
0.265
1.020
21.313
0.227
0.047
0.079
0.221
29.277
0.014
0.010
0.034
0,001
0.000
0.002
0.004
0.015
0.095
0.004
0.015
0.018
0.008
0.015
0.025
0.021
0.009
0.000
0.000
0.030
0.022
0.069
54.906
unc
0.056
0.097
0.025
0.115
0,029
0.102
2.131
0.023
0,005
0.008
0.022
2.928
0.001
0.001
0.003
0.001
0.004
0.001
0.001
0.002
0.010
0.001
0.006
0.003
0.004
0.004
0,007
0.007
0.008
0.013
0.036
0,055
0.002
0.007
0-10
Xwt
0.732
1.323
0.159
1.676
0,369
1.838
23.538
0.193
0.043
0.071
0.251
24.571
0.015
0.013
0.065
0.001
0.000
0.003
0.005
0.017
0.106
0.003
0.007
0.015
0.004
0.015
0.030
0.013
0.008
0.034
0.000
0.014
0.016
0.063
55.211
um{1>
unc
0.103
0.124
0.028
0.183
0.038
0.174
2.147
0.024
0,008
0.011
0.027
2.387
0.004
0.004
0.009
0.001
0.004
0.002
0.002
0.005
0.014
0.003
0.011
0.008
0.007
0.010
0.014
0.014
0.016
0.027
0.078
0.111
0.005
0.011
(0-10)
0.850
Total
Measured
%wt
0.598
1.043
0.098
0.702
0.287
1.195
21.788
0.219
0.046
0.077
0.228
28.271
0.014
0.011
0.041
0.001
0.000
0.002
0.004
0.016
0.097
0.004
0.014
0.017
0.007
0.015
0.026
0.019
0.009
0.007
0.000
0.027
0.020
0.068
54.971
unc
0.052
0.090
0.023
0.111
0.027
0.100
1.947
0.020
0.004
0.007
0,020
2.633
0.001
0.001
0.003
0.001
0.004
0.001
0.001
0.002
0.009
0.001
0.006
0.004
0.004
0.005
0.007
0.007
0.009
0.014
0.040
0,059
0.002
0.006
Cl> Calculated based on methodology in the Air missions Species Manual, Volume II.
148
-------
PM Profile Speciation Report
Profile Name Steel Production
Profile Number 28307
Data Quality D
- Basic
Oxygen
Furnace
Control Device UhcontrolledC1>
Reference(s) 62,78
Data Source Data taken from Reference 62. For details, consult Reference
78.
SCC Assignments: 30300913
Mass Fraction Data - Size Interval (tin) : (0-2.5) (0-6)
Mass Fraction : 0.650 0.660
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
apct. i ca
Nan Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
Al
Si
P
$
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
0-2.5 urn
%wt
0
1
0
1
1
2
0
0
0
0
2
50
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.383
.500
.223
.525
.819
.803
.981
.375
.093
.189
.073
.131
.017
.020
.057
.007
.002
.003
.016
.022
.013
.002
.017
.024
.020
.040
.039
.004
.028
.018
.059
.021
.014
.081
NR
unc
0.055
0.648
0.045
1.126
0.825
0.554
0.612
0.102
0.014
0.019
1.138
15.178
0.005
0.009
0.024
0.006
0.007
0.001
0.009
0.004
0.003
0.003
0.012
0.009
0.008
0.012
0.054
0.017
0.020
0.033
0.090
0.138
0.003
0.009
0.000
2.5-10 un
Xwt
0.28S
1.060
0.111
0.019
0.393
1.421
0.944
0.421
0.097
0.191
1.250
60.592
0.018
0.013
0.034
0.003
0.000
0.003
0.006
0.020
0.011
0.000
0.007
0.018
0.017
0.023
0.035
0.017
0.029
0.005
0.019
0.010
0.011
0.102
NR
unc
0.092
0.637
0.051
0.198
0.394
0.536
0.851
0.046
0.014
0.021
0.622
6,059
0.003
0,003
0.023
0.003
0.008
0.001
0.002
0.008
0.004
0.003
0.010
0.008
0.009
0.010
0.016
0.016
0.018
0.030
0.078
0.120
0.004
0.045
0.000
0-10
%Mt
0.383
1.500
0.223
1.525
1.819
2.803
0.981
0.375
0.093
0,189
2.073
50.131
0.017
0.020
0.057
0.007
0.002
0.003
0.016
0.022
0.013
0.002
0.017
0.024
0.020
0.040
0.039
0.004
0.028
0.018
0.059
0.021
0.014
0.081
NE
(0-10)
0.670
Total
un{2> Measured
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Xwt
0.465
1.229
0.149
1.129
0.654
3.636
1.545
0.369
0.085
0.167
1.470
50.199
0.016
0.014
0.047
0.005
0.003
0.002
0,009
0.027
0.016
0.002
0.005
0.013
0.030
0.035
0.020
0.012
0.035
0.017
0.083
0.000
0.012
0.076
0.440
unc
0.162
0.545
0.056
1.261
0.504
2.803
0.758
0.160
0.033
0.046
0.338
20.979
0.005
0,005
0.033
0.003
0.007
0.002
0.003
0.011
0.003
0.004
0.014
0.012
0.017
0.015
0.020
0.021
0.025
0.042
0.112
0.168
0.007
0.069
0.044
149
-------
PH Profile Speciation Report - continued (profile 28307}
Total Particulatc Hatter -
Total
0-2.5 urn 2.5-10 urn 0-10 unC2> Measured
•Species - ---- ..... - ....... •• ....... - ......... - ..........
CAS Number Nun Sym Xwt unc Xut unc Xwt unc Xut unc
202 1C NR 0,000 NR 0.000 NE 0.000 0.000 0.030
TOTALS: 62.619 67.190 62.619 62.016
€1> No controlled specified; thus, assumed uncontrolled.
<2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
150
-------
PM Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Ferromanganese Furnace
28401
B/C
Control Device
Reference(s)
Data Source
Baghouse
46
Sampled uith a 2-stage virtual impactor with a Method 5
heated probe. No dilution air, Analysis by INNA, 1C, and
carbon oxidation. Average of 2 samples from one source.
SCC Assignments: 30300701
Mass Fraction Data - Size Interval (urn)
Nass Fraction
Total Particulate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
O|»>15V 1 CO
Nun) Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
Be
B
f
Na
Hg
Al
Si
P
s
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe"
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
0-2
Xwt
0
3
0
0
1
0
10
1
0
0
0
17
2
0
0
0
NA
NA
.290
.100
<
.640
.990
<
.700
.420
.500
.300
<
.046
.024
.042
.300
.100
<
<
.036
.580
<
<
<
<
.160
<
<
<
<
<
<
<
.5 urn
unc
0.000
0.000
0.080
0.300
4.000
0.130
0.300
0.000
0.350
0.160
3.900
0.140
0.000
0.007
0.019
0.003
0.990
1.400
0.000
0.005
0.004
0.250
0.000
0.000
0.000
0.000
0.220
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: <0
; 0
-2.5)
.490
2.5-10 urn
Xwt
NA
NA
0.290
3.100
<
0.640
0.990
<
1.700
0.420
10.500
1.300
<
0.046
0.024
0.042
17.300
2.100
<
<
0.036
0.580
<
<
t
V
0.160
<
<
<
<
<
<
<
unc
0.000
0.000
0.080
0,300
4.000
0.130
0.300
0.000
0.350
0.160
3.900
0.140
0.000
0.007
0.019
0.003
0.990
1.400
0.000
0.005
0.004
0.250
0.000
0.000
0.000
0.000
0.220
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.670
0-10 urn
Xwt
NE
NE
0.290
3.100
NE
0.640
0.990
NE
1.700
0.420
10.500
1.300
NE
0.046
0.024
0.042
17.300
2.100
NE
NE
0.036
0.580
NE
NE
NE
NE
0.160
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.075
0.444
0.000
0.132
0.276
0.000
0.355
0.142
3.484
0.193
0.000
0.008
0.016
0.006
2.204
1.195
0.000
0.000
0.005
0.220
0.000
0.000
0.000
0.000
0.185
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.830
Total
Measured
Xwt
NE
NE
0.290
3.100
NE
0.640
0.990
NE
1.700
0.420
10.500
1.300
NE
0.046
0.024
0.042
17.300
2.100
NE
NE
0.036
0.580
NE
NE
NE
NE
0.160
NE
HE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
151
-------
PM Profile Speciation Report - continued {profile 284015
Total Particulars Hatter -
CAS Number
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
ogjKi* i tsa
Nun Sym
55
56
58
on
82
201
202
203
204
CS
Ba
Ce
M-
"9
Pb
OC
EC
S04
N03
0-2.5
urn
%nt unc
< 0
< 0
< 0
< 0
0.045 0
9.000 0
1.500 0
4.200 0
5.700 2
.000
.000
.000
.000
.016
.090
.150
.400
,800
2.5-10
urn
0-10 urn
%wt unc
< 0
< 0
< 0
< 0
0.045 0
9.000 0
1 .500 0
4.200 0
5.700 2
.000
.000
.000
.000
.016
.090
.150
.400
.800
0
9
1
4
5
Xwt
NE
NE
NE
NE
.045
.000
.500
.200
.700
unc
0.000
0.000
0.000
0.000
0.014
1.065
0.217
0.598
2.433
Total
Measured
Xwt
NE
NE
NE
NE
0.045
9.000
1.500
4.200
5.700
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 59.673 59.673 59.673 59.673
152
-------
PN Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Aluninun Processing
29101
B/D
Control Device
Reference(s)
Data Source
Baghouse
46,54
Sampled with a 2-stage virtual inspector with a Method 5
heated probe. No dilution air. Analysis by XRF, INNA, 1C,
and carbon oxidation. Average of 3 samples from Z plants.
Sampled downstream of baghouse.
SCC Assignments: 30300107
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter -
CAS Nurber
7440-41-7
7440-42-8
7782-41 -4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
w|jt?^ i ca
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
Se
B
F
Na
«9
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
2r
Ag
Cd
Sn
0-2
Xwt
6
4
2
27.
Q
1
1
0
0
0
0
0
0
0
0
0
0
NA
NA
.000
.100
.800
.000
.340
<
.400
.330
.220
.330
<
.040
.064
<
.011
.450
<
.190
.044
.015
<
<
<
<
.037
<
<
<
<
<
<
.5 urn
unc
0.000
0.000
2.300
1.700
1.800
8.000
0.340
0.000
0.200
0.840
0.060
0,030
0.000
0.030
0.036
0.010
0.008
0.290
0.000
0.085
0,007
0.011
0.000
0.000
0.000
0.000
0.054
0.000
0.000
0.000
0.000
0.000
0.000
: (0-1.5)
: 0.400
2.5-10 urn
Xwt
NA
NA
4.200
2.400
2.700
31 .300
0.097
<
<
1.200
<
0.810
<
0.076
0.040
0.016
<
0.380
<
0.210
0.140
0.009
<
<
• <
<
0.120
«
<
<
<
<
<
unc
0.000
0.000
1.900
0.600
0.550
4.900
0.080
0.000
0.300
0.150
0.100
0.340
0.000
0.041
0.011
0.018
0.020
0.150
0.000
0.060
0.040
0.004
0.000
0.000
0.000
0.000
0.200
0.000
0.000
0.000
0.000
0.000
0.000
<0-6>
0.520
0-10 urn
Xwt
NE
NE
5.441
3.572
2.769
28.334
0.265
NE
m
1.290
NE
0.479
NE
0.051
0.057
NE
NE
0.428
NE
0.196
0.074
0.013
NE
NE
NE
HE
0.063
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
2.178
1.327
1.352
7.623
0.243
0.000
0.000
0.614
0.000
0.250
0.000
0.036
0.027
0.000
0.000
0.232
0.000
0.077
0.031
0.008
0.000
0.000
0.000
0.000
0.143
0.000
0.000
0.000
0.000
0.000
0.000
CO-10)
0.580
Total
Measured
Xwt
NE
NE
5.441
3.172
2.769
28,334
0.265
NE
NE
1.290
NE
0.479
NE
0.051
0.057
NE
NE
0.428
NE
0.196
0.074
0.013
NE
NE
NE
NE
0.063
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
o.poo
153
-------
PM Profile Speciation Report - continued (profile 29101)
Total Participate Matter *
Total
0-2.5 un 2.5-10 un 0-10 urn Measured
Species •-• ..... ............ ....... .. ..—
CAS Number Nun Sym Xut unc Xut unc %ut unc Xwt unc
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
51
55
56
58
80
82
201
202
203
204
Sb
Cs
Ba
Ce
Kg
Pb
OC
EC
$04
N03
0
3
2
4
0
55
<
<
<
<
<
.012
.900
.300
.400
.410
.393
0.000
0.000
0.000
0.000
0.000
0.010
3.900
1.000
3.900
0.180
< 0
< 0
< 0
< 0
< 0
< 0
< 2
1.600 1
1.700 1
NA 2
46.998
.000
.000
.000
.000
.000
.100
.000
.500
.100
.000
NE
NE
NE
NE
NE
NE
NE
2.083
3.562
NE
48.677
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.273
2.832
0.000
NE
NE
NE
NE
NE
NE
NE
2.083
3.562
NE
48.677
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
154
-------
PM Profile Speciation Report
Profile Name Aluminum Reduction Pot line
Profile Number 29102
Data Quality B/D
Control Device Uncontrolled
Reference(s) 49
Data Source Sampled with a 2-stage virtual impact or
roof vents,
SCC Assignments: 30300107
Nass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Ff act ion : 0.400
Total Parttculate Hatter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
agjcu i e»
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
22
23
25
26
27
28
29
30
31
33
34
35
37
38
40
42
46
47
48
49
50
51
56
Be
B
F
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Mn
Fe
Co
Ni
Cu
In
Ga
As
Se
Br
Rb
Sr
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
0-2
%ut
0
13
14
0
15
0
0
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
<
,190
.500
.900
.055
.200
.340
.030
.000
.800
.527
.100
.002
.015
.008
.114
.002
.014
.018
.007
.028
.022
.003
.022
.005
<
<
.006
<
<
.003
<
<
.001
.001
.5 urn
unc
0.000
0.020
5.900
1.700
0.006
1.700
0.040
0.030
3.800
0.160
0.470
0.140
0.000
0.004
0.011
0.095
0.002
0.008
0.008
0.001
0.018
0.014
0.000
0.008
0.001
0.000
0.000
0.006
0.000
0.000
0.001
0.000
0.000
0.003
0.000
2.5-10 urn
Xwt
<
0.190
13.500
14.900
0.055
15.200
0.340
0.030
5.000
0.800
0.527
0.100
0.002
0.015
O.OOS
0.114
0.002
0.014
0.018
0.007
0.028
0.022
0.003
0.022
0.005
<
<
0.006
<
<
0.003
<
<
0.001
0.001
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
. Average from
(0-6)
0.520
0*10 urn
Xwt
<
0.190
13.500
14.900
0.055
15.200
0.340
0.030
5.000
0.800
0.527
0.100
0.002
0.015
0.008
0.114
0.002
0.014
0.018
0.007
0.028
0.022
0.003
0.022
0.005
<
<
0.006
<
<
0.003
<
<
0.001
0.001
unc
0.000
0.030
4.475
2.366
0.009
2.402
0.054
0.021
2.710
0.156
0.332
0.098
0.000
0.003
0.008
0.067
0.001
0.006
0.006
0.001
0.013
0.010
0.000
0.006
0.001
0.000
0.000
0.004
0.000
0.000
0.001
0.000
0.000
0.002
0.000
2
(0-10)
0.580
Total
Measured
Xwt
NA
KA
15.454
NA
NA
15.926
0.398
0.042
3.908
0.834
0.3S8
0.414
0.015
0.073
0.004
0.812
NA
0.288
0.078
0.006
0.050
0.018
0.002
0.016
0.004
0.003
<
0.012
<
<
0.002
<
<
0.001
0.002
unc
0.000
0.000
3.387
0.000
0.000
1.657
0.047
0.019
2.065
0.338
0.254
0.083
0.002
0.013
0.006
0.281
0.000
0.078
0.011
0.003
0.014
0.008
0.000
0.004
0.000
0.000
0.000
0.005
0.000
0.000
0.001
0.000
0.000
0.002
0.001
155
-------
PH Profile Speciation Report - continued (profile 29102)
Total Particulate Matter -
CAS Number
7439-91-0
7439-97-6
7439-92-1
7440-69-9
TOTALS:
Nun Sym
57
80
82
83
200
201
202
203
204
La
Hg
Pb
Of
TC
DC
EC
S04
N03
0-2.5 urn
Xwt
0
. 0
0
28
2
17
0
100
.004
<
.072
.030
NA
.200
.680
.411
.690
.000
unc
0.004
0.000
0.026
0.030
0.000
5.000
0.320
9.300
0.130
2.5-10 urn
%ut
0.004
<
0.072
0.030
NA
28.200
2.680
17.411
0.690
100.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
0.004
<
0.072
0.030
NA
28.200
2.680
17.411
0.690
100.000
unc
0.003
0.000
0.020
0.021
0.000
5.198
0.431
.6.849
0.131
Total
Measured
Xwt
0.004
<
0.053
NA
NA
22.180
15.247
12.764
0.593
89.561
unc
0.003
0.000
0.014
0.000
0.000
3.032
2.765
5.043
0.086
156
-------
PM Profile Speciat ion Report
Profile Name Primary
Profile Number 29202
Data Quality D/E
Copper Smelter
Control Device ESP
Referenced) 24
Data Source Analyzed by XRF/SSMS. 1-2 samples downstream of iSP on a
reverberatory furnace.
SCC Assignments: 30300503
Mass Fraction Data • Size Interval (urn} : (0-2.5) {0-6} (0-10)
Mass Fraction : 0.840 0.980 0.990
Total Particulate Matter
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
3|J
-------
PH Profile Specialion Report - continued (profile 29202}
Total Particulaw
Matter
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
J(^=k-, 1 CB
Hum Sym
56
58
80
DO
201
202
203
204
Ba
Ce
Hg
ni.
OC
EC
S04
N03
Total
0-2
Xut
<
<
<
0.049
NA
NA
NA
NA
.5
0
0
0
0
0
0
0
0
urn
unc
.000
.000
.000
.000
.000
.000
.000
.000
2.S-10 urn
Xut
<
<
<
0.049
NA
HA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xut
<
<
<
0.049
NA
NA
NA
NA
unc
0.000
0.000
0.000
0.008
0.000
0.000
0.000
0.000
Measured
Xut
<
<
<
0.049
NA
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
99.884
99.884
99.884
99.884
158
-------
PM Profile Speciation Report
profile Name Primary Copper Reverberator/ Furnace -
Profile Number 29203
Data Quality D
Slag Tap
Control Device Uncontrolledd}
Reference(s) 62,79
Data Source . Data taken from Reference 62. For details, consult Reference
79.
SCC Assignments: 30300514, 30499999
Mass Fraction Data - Size Interval
Mass Fraction ; 0.210 0.230
Total Participate Matter -
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
13494-80-9
7439-97-6
7439-92-1
7440-69-9
TOTALS:
Nun Sym
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
, 39
42
47
48
49
50
51
52
80
82
83
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Mtt
Fe
Ni
Cu
Zn
As
Se
Br
Rb
sr
Y
Mo
Ag
Cd
In
Sn
Sb
Te
Hg
Pb
Bi
0-2.5 um
%wt
0
0
0
0
0
0
0
0
0
0
0
0
0
1
60
0
0
0
0
0
0
0
0
0
0
1
0
0
6
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.190
.000
.150
.700
.000
.000
.000
.000
.000
.000
.092
.011
.630
.012
.130
.100
.090
.000
.000
.370
une
0.200
0.200
1.000
0.200
0.500
0.500
0.300
0.010
0.010
0.010
0.016
0.030
0.005
0.050
3.600
0.200
0.200
0.100
0.100
0.100
0.005
0.002
0.220
0.001
0.021
0.029
0.022
0.030
0.790
0.100
70.475
2,5-10 um
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.380
0.000
0.167
0.820
71.000
0.000
0.000
0.000
0.000
0.000
0,110
0.000
0.530
0.000
0.210
0.9SO
0.130
0.000
8.000
N8
82.327
unc
1.000
1.000
5.000
0.500
2.000
0.800
0.060
0.020
0.010
0.030
0.060
0.050
0.010
0.090
2.000
0.300
0.900
0.300
0.050
0.200
0.010
0.030
0.460
0.020
0.020
0.080
0.010
0.500
0.400
0.000
0-10 um
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.215
0.000
0.152
1.586
61.423
0.000
0.000
0.000
0.000
0.000
0.094
0.010
0.617
0.010
0.140
1.085
0.095
0.000
6.259
0.322
unc
0.896
0.896
4.478
0.468
1.806
0.806
0.239
0.019
0.012
0.028
0.070
0.050
0.028
0.220
9.226
0-.307
0.809
0.276
0.089
0.193
0.021
0.027
0.449
0.018
0.037
0.166
0.028
0.442
1.157
0.088
, 72.008
(0-10)
0.270
Total
MeasuredC2>
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.215
0.000
0.152
1.586
61.423
0.000
0.000
0.000
0.000
0.000
0.094
0.010
0.617
0.010
0.140
1.085
0.095
0.000
6.259
0.322
72.008
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{1} No controlled specified: thus, assumed .uncontrolled.
C2> Estimated / extrapolated.
159
-------
PH Profile Speciation Report
Profile Name Primary Cupper Reverberatory Furnace -
Profile Ntnfcer 29204
Data Quality D
Slag Skim & Pour
Control Device UncontrolledC1>
Referenced) 62,80
Data Source Data taken from Reference 62. For details, consult Reference
80.
SCC Assignments: 30300514
Mass Fraction Data * Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.210 0.230
Total Particulate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
p
s
Cl
K
Co
Ti
V
Cr
Mn
Fe
Hi
CU
In
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
24
0
15
0
0
0
0
0
0
0
0
0
1
0
0
1
0
0
0
21
68
0-2
%Mt
.000
.000
.000
.050
.000
.361
.000
.010
.003
.000
.010
.663
.000
.194
.455
.000
.725
.000
.000
.000
.004
.021
.001
.368
.000
.000
.840
.061
.721
.648
.000
.000
.000
.951
.086
.5 urn
une
0.081
0.296
0.097
1.351
0.209
0.049
0.338
0.009
0.003
0.013
0.004
0.066
0.049
0.019
2.446
0.075
1.573
0.071
0.8S5
0.012
0.004
0.054
0.016
0.037
0.001
0.004
0.184
0.007
0.072
0.165
0.008
0.014
0.077
2.195
2.5-10 urn
Xut
0.030
3.593
0.000
0.000
0.000
0.435
0.123
0.059
0.175
0.085
0.020
6.401
0.115
6.795
13.279
0.009
11.732
0.000
0.000
0.000
0.001
0.007
0.000
0.377
0.000
0.003
1.045
0.083
0.405
1.086
0.000
0.000
0.000
13.763
59.621
unc
0.733
0.359
0.291
2.596
0.345
0.086
1.151
0.055
0.021
0.019
0.005
0.640
0.057
0.680
1.375
0.116
1.601
0.146
1.461
0.020
0.008
0.080
0.082
0.038
0.003
0.017
0.231
0.025
0.077
0.215
0.042
0.078
0.145
1.376
0-10 urn
%ut
0.002
0.233
0.000
0.047
0.000
0.366
0.008
0.013
0.014
0.006
0.010
1.035
0.008
0.622
23.730
0.001
15.466
0.000
0.000
0.000
0.004
0.020
0.001
0.369
0.000
0.000
1.789
0.062
0.701
1.612
0.000
0.000
0.000
21 .420
67.539
unc
0.649
0.487
0.267
2.519
0.345
0.103
1.048
0.050
0.028
0.024
0.008
0.765
0.065
0.806
3.662
0.118
2.708
0.140
1.450
0.020
0.008
0.082
0.073
0.071
0.002
0.016
0.334
0.027
0.125
0.307
0.038
0.070
0.141
3.374
(0-10)
0.270
Total
Measured
%ut
0.002
0.233
0.000
0.047
0.000
0.366
0.008
0.013
0.014
0.006
0.010
1.035
0.008
0.622
23.730
0.001
15.466
0.000
0.000
0.000
0.004
0.020
0.001
0.369
0.000
0.000
1.789
0.062
0.701
1.612
0.000
0.000
0.000
21 .420
67.539
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
C1> Ho controlled specified: thus, assumed uncontrolled.
C2J Estimated / extrapolated.
160
-------
PM Profile Speciation Report
Profile Name Primary
Profile Number 29205
Data Quality D
Copper Converter
- Secondary Nood
Control Device Uncontrolled{1}
Reference(s) 62,79
Data Source Data taken from Reference 62. For details, consult Reference
79.
SCC Assignments: 30300515
Mass Fraction Data - Size Interval (un) : (0-2.5) (0-6)
Mass Fraction : 0.120 0.320
Total Particulate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
13494-80-9
7439-97-6
7439-92-1
7440-69-9
Nun
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
39
42
47
48
49
50
51
52
80
82
83
Sym
Al
Si
s
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
Br
Rb
Sr
Y
Mo
Ag
Cd
In
Sn
Sb
Te
Hg
Pb
Bi
0-2.5 urn
Xwt
0
0
0
0
0
0
0
0
0
0
0
0
1
2
26
0
0
0
0
Q
0
0
0
0
0
3
0
0
28
1
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.260
.000
.100
.600
.000
.000
.000
.000
.000
.000
.000
.260
.600
.140
.530
.100
.072
.000
.000
.000
unc
0.200
0.200
2.000
0.200
0.400
0.100
0.020
0.020
0.020
0.020
0.190
0.030
1.100
2.600
11.000
0.200
0.200
0.060
0.050
0.090
0.100
0.360
0.870
0.120
0.320
2.200
0.038
0.200
13.000
0.920
2.5-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
NR
7.100
NR
9.400
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.160
0.260
0.000
0.420
1.730
0.000
NR
0.000
NR
unc
3.000
10.000
30.000
5.000
5.000
2.000
0.200
0.050
0.050
0.000
1.200
0.000
1.500
2.000
22.000
0.400
1.000
0.300
0.200
2.000
0.200
0.040
0.050
0.050
0.080
0.300
0.020
0.000
20.000
0.000
0-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.113
0.000
2.135
2.276
22.758
0.000
0.000
0.000
0.000
0.000
0.000
0.248
0.558
0.123
0.516
2.929
0.063
0.000
24.509
0.875
unc
1.354
4.510
13.536
2.255
2.256
0.902
0.090
0.023
0.023
0.004
0.563
0.006
0.740
1.048
10.198
0.185
0.453
0.136
0.091
0.902
0.092
0.076
0.179
0.033
0.077
0.478
0.012
0.041
9.434
0.189
(0-10)
0.590
Total
Measured{2>
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.113
0.000
2.135
2.276
22.758
0.000
0.000
0.000
0.000
0.000
0.000
0.248
0.558
0.123
0.516
2.929
0.063
0.000
24.509
0.875
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
63.662
19.070
58.103
58.103
O> No controlled specified: thus, assumed uncontrolled.
C2> Estimated / extrapolated.
161
-------
PH Profile Speciation Report
Profile Name Primary Copper Converter
Profile Number 29206
Data Quality D
- Secondary Hood
Control Device IfneontrolledCI}
Reference(s) 62,80
Data Source Data taken from Reference 62. For details, consult Reference
80.
SCC Assignments: 30300515
Mass Fraction Data - Size Interval (uii) : {0-2.5} (0-6)
Mass Fraction : 0.120 0.320
Total Paniculate
**—.—.
CAS Nunfcer
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-9S-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
0|JC
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Matter -
ci@s
Sym
Al
Si
P
s
Cl
K
Ca
Tt
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
AS
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2.5 urn
Swt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
• 7
0
7
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
23
40
.000
.000
.000
.000
.000
.133
.000
.000
.000
.000
.000
.039
.007
.499
.250
.024
.229
.000
.000
.000
.000
.037
.014
.050
.000
.050
.631
.036
.305
.107
.000
.000
.000
.558
.969
unc
0.039
0.231
0.087
1.393
0.215
0.017
0.145
0.003
0.001
0.005
0.004
0.004
0.002
0.050
0.725
0.035
0.831
0.059
0.359
0.006
0.004
0.046
0.014
0.005
0.000
0.005
0.063
0.004
0.031
0.111
0.004
0.008
0.025
2.356
2.5-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.310
0.000
0.000
0.000
0.000
0.000
0.283
0.009
1.323
8.546
0.000
10.534
0.000
0.000
0.000
0.001
0.064
0.015
0.095
0.000
0.033
0.825
0.048
0.445
1.577
0.000
0.000
0.000
28.996
53.104
unc
0.503
1.999
0.496
4.031
0.678
0.043
0.755
0.020
0.008
0.018
0.017
0.028
0.005
0.132
0.855
0.091
2.608
0.196
1.175
0.020
0.013
0.142
0.056
0.010
0.002
0.016
0.146
0.018
0.068
0.254
0.030
0.055
0.094
2.900
0-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.145
0.000
0.000
0.000
0.000
0.000
0.055
0.007
0.552
7.333
0.023
7.440
0.000
0.000
0.000
0.000
0.039
0.014
0.053
0.000
0.049
0.643
0.037
0.314
1.137
0.000
0.000
0.000
23.904
41.745
unc
0.227
0.903
0.224
1.840
0.309
0.023
0.342
0.009
0.004
0.008
0.008
0.016
0.003
0.070
0.496
0.041
1.226
0.089
0.535
0.009
0.006
0.065
0.026
0.007
0.001
0.008
0.073
0.009
0.035
0.127
0.013
0.025
0.043
1.659
{0-10}
0.590
Total
Measured{2>
Xwt
0.000
0.000
0.000
0.000
0.000
0.145
0.000
0.000
0.000
0.000
0.000
0.055
0.007
0.552
7.333
0.023
7.440
0.000
0.000
0.000
0.000
0.039
0.014
0.053
0.000
0.049
0.643
0.037
0.314
1.137
0.000
0.000
0.000
23.904
41.745
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C1> Mo controlled spec!' ed: thus, asswned uncontrolled.
€2> Estimated / extrapolated.
162
-------
PH Profile Speciation Report
Profile Name Primary Copper Flash Furnace - Matte &
Profile Nuttoer 29207
Data Quality D
Slag Tap
Control Device Uncontrolled€1>
Reference(s) 62,80
Data Source Data taken from Reference 62, For details, consult Reference
80.
SCC Assignments: 30300512
Mass Fraction Data - Size Interval (un) : (0-2.15 <0-6>
Mass Fraction : 0.840 0.890
Total Participate Natter -
CAS Nuifcer
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
ope& l es
Nun) Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
CB
Ti
V
Cr
Mrs
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
AS
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
0
0
0
0
0
0
0
0
0
0
0
2
0
3
9
0
32
0
2
0
0
0
0
0
0
0
I
0
0
1
0
0
0
12
68
,000
.000
.000
.000
.000
.331
.000
.000
.000
.018
.013
.688
,000
.354
.767
.000
.785
.000
.532
.000
.000
.000
.000
.161
.000
.024
.679
.031
.423
.991
.000
.000
.000
.464
.261
.5 un
unc
0.228
0.204
0.088
1.195
0.185
0.033
0.508
0.020
0.007
0.002
0.002
0.269
0.004
0.335
0.977
0.087
3.279
0.098
0.253
0.032
0.004
0.107
0.069
0.016
0.001
0.004
0.169
0.006
0.043
0.229
0.008
0.014
0.196
1.246
2,5-
Xwt
0.000
2.188
0.000
0.467
0.000
0.583
0.000
0.000
0.000
0.123
0.042
7.085
0.023
8.420
7.812
0.000
31 .823
0.000
0.000
0.000
0.000
0.000
0.000
0.154
0.000
0.086
1.257
0.000
0.427
2.014
0.000
0.000
0.000
11.596
74.100
10 un
unc
0.691
0.361
0.167
3.455
0.536
0.119
2.104
0.222
0.046
0.012
0.009
0.709
0.015
0.842
1.403
0.265
5.174
0.343
5.961
0.090
0.014
0.274
0.221
0.031
0.004
0.029
0.465
0.037
0.136
0.658
0.067
0.124
0.592
1.791
0-10 urn
Xwt
0.000
0.137
0.000
0.029
0.000
0.347
0.000
0.000
0.000
0.025
0.015
2.962
0.002
3.670
9.645
0.000
32.725
0.000
2.374
0.000
0.000
0.000
0.000
0.160
0.000
0.028
1.652
0.029
0.424
1.992
0.000
0.000
0.000
12.410
68.626
unc
0.692
0.459
0.178
3.478
0.539
0.151
2.063
0.213
0.044
0.035
0.020
1.054
0.020
1.259
2.180
0.265
7.746
0.339
5.710
0.090
0.014
0.279
0.220
0.054
0.004
0.039
0.539
0.036
0.162
0.745
0.064
0.119
0.594
2.833
(0-10>
0.920
Total
Measured^}
Xwt
0.000
0.137
0.000
0.029
0.000
0.347
0.000
0.000
0.000
0.025
0.015
2.962
0.002
3.670
9.645
0.000
32.725
0.000
2.374
0.000
0.000
0.000
0.000
0.160
0.000
0.028
1.652
0.029
0.424
1.992
0.000
0.000
0.000
12.410
68.626
une
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<1> No controlled specified: thus, assuned > -icorvtrolled.
C2> Estimated / extrapolated.
163
-------
PM Profile Speciation Report
Profile Name
Profile Nunber
Data Quality
Primary Copper -
29E05
D
Process
Stack
Control Device UncontrolledCO
Reference(s) 62,79
Data Source Data taken from Reference 62. For details, consult Reference
79.
SCC Assignments: 30300524
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.970 1.000
Total Particulate Matter -
CAS Nunber
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440 -24 -A
7440-65-5
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
13494-80-9
7439-97-6
7439-92-1
7440-69-9
TOTALS:
opcu i cj>
u. — o. _
13
14
16
17
19
20
22
23
24
25
26
?s.
29
30
33
34
35
37
ta
39
42
47
48
49
50
51
52
80
82
83
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Nn
Fe
Ni
CU
Zn
As
Se
Br
Rb
Cr-
Y
Ho
Ag
cd
In
Sn
Sb
Te
Hg
Pb
Bi
0-2.5
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
0.014
0.009
,0.290
0.040
3.000
4.200
24.000
0.000
0.000
0.000
C.QQC
0.000
0.100
0.120
0.510
0.023
0.400
6.000
0.170
0.000
18.000
0.400
57.292
0
0
2
0
0
0
0
0
0
0
0
0
0
1
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
urn
unc
.200
.200
.000
.300
.500
.800
.100
.001
.001
.004
.020
.008
.260
.400
.600
.100
.300
.100
.100
.100
.012
.015
.150
.005
.063
.580
.025
.200
.930
.082
2.5-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
0.017
0.015
0.400
0.070
2.400
4.000
38.000
0.000
0.000
0.000
0.000
0.000
0.134
0.120
0.460
0.000
0.390
5.600
0.180
0.000
16.000
NR
67.801
unc
2.000
1.000
2.000
0.500
0.500
2.000
0.200
0.003
0.005
0.003
0.060
0.020
0.200
1.400
9.000
0.200
1.000
0.100
0.100
0.100
0.035
0.050
0.080
0.020
0.070
0.400
0.030
0.500
2.000
0.000
0-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
0.015
0.010
0.313
0.046
2.876
4.159
26.893
0.000
0.000
0.000
0.000
0.000
0.107
0.120
0.500
0.018
0.398
5.917
0.172
0.000
17.587
0.317
59.464
unc
1.979
1.004
2.765
0.572
0.691
2.117
0.220
0.013
0.014
0.013
0.104
0.034
0.590
2.065
10.474
0.220
1.027
0.138
0.138
0.138
0.054
0.065
0.196
0.021
0.129
1.223
0.063
0.529
3.654
0.097
(0-10)
1.000
Total
Measured{2>
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
0.015
0.010
0.313
0.046
2.876
4.159
26.893
0.000
0.000
0.000
0.000
0.000
0.107
0.120
0.500
0.018
0.398
5.917
0.172
0.000
17.587
0.317
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
59.464
C1> No controlled specified; thus, assumed uncontrolled.
CH) Estimated / extrapolated.
164
-------
PM Profile Special ion Report
Profile Name Primary Copper Roaster
Profile Number 29209
Data Quality 0
Control Device Uncontrolledd}
Reference(s) 62,79
Data Source Data taken from Reference 62. For details, consult Reference
79.
SCC Assignments: 30300502, 30300509
Mass Fraction Data * Size Interval (urn) : (0-2.5) (0-6)
Hass Fraction : 0.970 1.000
Total Particulate Hatter *
CAS Number Nun Sym
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
13494-80-9
7439-97-6
7439-92-1
7440-69-9
TOTALS:
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
39
42
47
48
49
50
51
52
80
82
83
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Hi
CU
Zn
As
Se
Br
Rb
Sr
Y
Ho
Ag
Cd
In
Sn
Sb
Te
Hg
Pb
Bi
0-2.5 urn
%wt
6". 300
13.500
9.800
0.000
1.010
2.000
0.260
0.000
0.066
0.137
18,600
0.110
18.600
1.090
4.200
0.000
0.000
0.000
0.050
0.000
0.160
0.000
0.000
0.000
0.000
0.340
0.000
0.000
2.130
0.300
78.653
unc
0.600
1.200
0.900
0.100
0.100
0.170
0.050
0.050
0.015
0.015
1.500
0.050
1.500
0.120
0.400
0.050
0.300
0.040
0.020
0.030
0.050
0.200
0.200
0.200
0.200
0.160
0.200
0.100
0.180
0.100
2.5-10 urn
Swt
2.400
4.800
8.100
0.000
0.420
1.620
0.160
0.000
0.040
0.081
13.000
0.000
18.400
1.020
3.700
0.000
0.000
0.000
0.000
0.000
0.120
0.042
0.000
0.000
0.000
0.076
0.000
0.000
1.750
0.060
55.789
unc
0.200
0.500
0.300
0.100
0.080
0.110
0.040
0.040
0.020
0.018
0.600
0.080
1.900
0.080
0.600
0.030
0.200
0.050
0.040
0.040
0.040
0.010
0.020
0.020
0.020
0.021
0.100
0.040
0.100
0.030
0-10 urn
Art
2.621
5.293
8.196
0.000
0.453
1.642
0.166
0.000
0.042
0.084
13.317
0.006
18.411
1.024
3.728
0.000
0.000
0.000
0.003
0.000
0.122
0.040
0.000
0.000
o.oob
0.091
0.000
0.000
1.772
0.074
57.085
unc
1.096
2.300
1.830
0.138
0.201
0.393
0.083
0.062
0.033
0.041
3.269
0.094
3.935
0.248
0.998
0.057
0.351
0.063
0.044
0.049
0.075
0.195
0.195
0.195
0.195
0.166
0.218
0.105
0.413
0.112
(0-10)
1.000
Total
Heasured{2}
Swt
2
5
8
0
0
1
0
0
0
0
13
0
18
1
3
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
57
.621
.293
.196
.000
.453
.642
.166
.000
.042
.084
.317
.006
.411
.024
.728
.000
.000
.000
.003
.000
.122
.040
.000
.000
.000
.091
.000
.000
.772
.074
.085
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
O.OOQ
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<1} No controlled specified: thus, assumed uncontrolled.
<2> Estimated / extrapolated.
165
-------
PM Profile Spec!ation Report
Profile Name
Profile Number
Data Quality
Primary Copper Reverberatory Furnace Fugitives Composite
29210
0
Control Device
Reference(s)
Data Source
Uncontrolled
Profile represents a composite of Profiles 29203 and 29204,
fugitive emissions from reverb furnace slag tapping and
slag skinning.
SCC Assignments: 30300514
Mass Fraction Data - Size Interval CUB)
Mass Fraction
Total Paniculate
£*.»_._
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7439-97-6
7439-92-1
TOTALS:
apec
Hum
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
39
42
47
48
49
50
51
80
82
Hatter
;fes
Sym
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Hi
Cu
2n
As
Se
Br
Kb
Sr
Y
Mo
AS
Cd
In
Sn
Sb
Hg
Pb
0-2.5 urn
Xwt
0.000
0.000
0.050
0.000
0.361
0.000
0.010
0.003
0.000
0.010
0.427
0.000
0.172
13.078
37.863
0.000
0.000
0.000
0.004
0.021
0.230
0.006
1.235
0.037
0.426
1.374
0.000
13.976
69.283
uncCU
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.OOQ
0.000
0.000
: CO-2.5)
: 0.210
2.5-10 urn
Xwt
0.003
3.593
0.000
0.000
0.435
0.123
0.059
0.175
O.OS5
0.020
3.391
0.115
3.431
7.050
41.366
0.000
0.000
0.000
0.001
0.007
0.244
0.002
0.788
0.042
0.308
1.033
0.000
10.882
73.203
unc<1J
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
=======================:==========.====.================="
<
0
0-6)
.230
0-10 urn
Xwt
0.002
0.233
0.047
0.000
0.366
0.008
0.013
0.014
0.006
0.010
0.625
0.008
0.387
12.658
38.445
0.000
0.000
0.000
0.004
0.020
0.232
0.005
1.203
0.036
0.421
1.349
0.000
13.840
69.932
uneC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<
0-10)
0.270
Total
Measured
Xwt uncCI}
0
0
0
0
0
0
0
0
0
0
0
0
0
12
38
0
0
0
0
0
0
0
1
0
0
1
0
13
69
.002
.233
.047
.000
.366
.008
.013
.014
.006
.010
.625
.008
.387
.658
.445
.000
.000
.000
.004
.020
.232
.005
.203
.036
.421
.349
.000
.840
.932
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
=============================
CD Uncertainty not evaluated.
166
-------
PH Profile Speciotion Report
Profile Name Primary
Profile Number 29211
Data Quality D
Copper Converter
- Secondary Hood Composite
Control Device Uncontrol led
ReferenceCs)
Data Source Profile represents a composite of Profiles 29205 and
SCC Assignments 30300515
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction ; 0.120 0.320
Total Participate Matter -
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7439-97-6
7439-92-1
Hum Sym
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
39
42
47
48
49
50
51
80
82
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Hi
Cu
Zn
As
Se
Br
Rb
Sr
V
No
Ag
Cd
In
Sn
Sb
Hg
Pb
TOTALS:
0-2
Xwt
0
0
0
0
0
0
0
0
0
0
0
0
0
4
16
0
0
0
0
0
0
0
0
0
0
2
0
25
51
.000
.000
.000
.000
.067
.000
.000
.000
.000
.000
.150
.004
.800
.925
.615
.000
.000
.000
.000
.019
.030
.155
.616
.088
.418
.104
.000
.779
.5 un
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 UB
Xwt
0.000
0.000
0.000
0.000
0.155
0.000
0.000
0.000
0.000
0.000
3.692
0.005
5.362
4.273
5.267
0.000
0.000
0.000
0.000
0.032
0.048
0.097
0.543
0.024
0.433
1.654
0.000
14.498
uneC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.770 36.083
0-10 un
Xwt
0.000
0.000
0.000
0.000
0.073
0.000
0.000
0.000
0.000
0.000
0.584
0.004
1.344
4.805
15.099
0.000
0.000
0.000
0.000
0.020
0.027
0.149
0.601
0.080
0.415
2.033
0.000
24.207
49.441
unct1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
29206.
(0-10)
0.590
Total
Measured
Xwt
0.000
0.000
0.000
0.000
0.073
0.000
0.000
0.000
0.000
0.000
0.584
0.004
1.344
4.805
15.099
0.000
0.000
0.000
0.000
0.020
0.027
0.149
0.601
0.080
0.415
2.033
0.000
24.207
49.441
uneCI}
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{1> Uncertainty not evaluated.
167
-------
PH Proffie Speciation Report
Profile Name Primary Leac
Profile Nuifeer 29301
Data Quality C/E
Smelting -
Slag Pouring
Control Device Uncontrolled
Reference(s) 43
Data Source Sample is composite of short episodic emissions from many
pours. Collected with modified high volume sampler.
SCC Assignments: 30301021
Mass Fraction Data - Size Interval Cum) : CO-2.5) CO-6)
Mass Fraction ; 0.830 0.910
Total Particulate
CAS Nunfcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-46-2
3(J«l
Hum
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
47
48
49
50
51
55
Hatter
-ies
Sym
Be
B
F
Ka
Mg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Nn
Fe
Co
Hi
Cu
In
Sa
Be
As
Se
Br
Rb
Sr
Ag
Cd
In
Sn
Sb
Cs
*
0
1
0
5
0
4
2
0
0
0
3
0
0
32
5
0
0
0
0
0
3
t
0-2
%wt
NA
NA
HA
NA
NA
.420
.900
.266
.523
.090
.174
.600
<
.104
<
.020
.100
.735
<
.066
.375
.477
<
<
.196
.208
<
<
.052
.130
.159
.011
.849
.626
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
%Ht
NA
NA
NA
NA
NA
0.420
1.900
0.266
5.523
0.090
4.174
2.600
<
0.104
<
0.020
0.100
3.735
<
0.066
0.375
32.477
<
<
5.196
0.208
<
<
0.052
0.130
0.159
0.011
3.849
1.626
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
%Ht
NA
NA
NA
NA
NA
0.420
1.900
0.266
5.523
0.090
4.174
2.600
«
0.104
<
0.020
0.100
3.735
<
0.066
0.375
32.477
<
<
5.196
0.208
<
<
0.052
0.130
0.159
0.011
3.849
1.626
<
unc
0.000
0.000
0.000
0.000
0.000
0.073
0.332
0.046
0.965
0.016
0.729
0.454
0.000
0.018
0.000
0.003
0.017
0.653
0.000
0.012
0.066
5.675
0.000
0.000
0.908
0.036
0.000
0.000
0.009
0.023
0.028
0.002
0.673
0.284
0.000
0.950
Total
Measured
%Ht
NA
NA
NA
NA
NA
0.420
1.900
0.266
5.523
0.090
4.174
2.600
<
0.104
<
0.020
0.100
3.735
<
0.066
0.375
32.477
<
<
5.196
0.208
<
<
0.052
0.130
0.159
0.011
3.849
1.626
<
unc
0.000
0.000
0.000
0.000
0.000
0.100
0.500
0.027
0.552
0.020
0.417
0.400
0.000
0.010
0.000
0.000
0.030
0.373
0.000
0.000
0.037
3.248
0.000
0.000
0.520
0.121
0.000
0.000
0.000
0.019
0.024
0.000
0.385
0.163
0.000
168
-------
PH Profile Special ion Report - continued (profile 29301}
Total Partlculate Matter -
Total
CAS Nunber
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
Nun Sym
56
58
80
82
201
202
203
204
Ba
Ce
Hg
Pb
OC
EC
S04
N03
0-2
%Ht
<
<
0.092
3.156
NA
HA
NA
NA
66.329
.5
urn
unc
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
2.5-10 urn
Xut
<
<
0.092
3.156
«A
HA
NA
HA
66.329
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
%Mt
<
<_
0.092
3.156
HA
NA
NA
NA
66.329
unc
0.000
0.000
0.016
O.S51
0.000
0.000
0.000
0.000
Measured
%wt
<
<
0.092
3.156
NA
NA
NA
NA
66.329
unc
0.102
0.000
0.011
0.316
0.000
0.000
0.000
0.000
169
-------
PH Profile Speciation Report
Profile Name Primary
Profile Hunter 29302
Data Quality B/C
Lead Smelting -
Control Device Baghouse
Reference(s) O
Data Source Sampled with a dilution
SCC Assignments 30301002
Mass Fraction uata - size Interval (un)
Mass Fraction
Total Participate Hatter
CAS Nuriber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-60-0
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
•ap^V 1Cy>
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
50
cc
23
24
25
26
28
29
iU
33
34
35
38
46
47
48
49
50
51
56
80
82
201
202
203
Be
B
F
Ma
Mg
Al
Si
P
S
Cl
K
rv
T i
V
Cr
Mn
Fe
Mi
Cu
in
As
Se
Br
Sr
Pd
Ag
Cd
In
Sn
Sb
86
Hg
Pb
OC
EC
S04
. 0-2
%wt
NA
NA
NA
NA
NA
0.100
0.200
0.764
13.269
5.000
2.075
0.550
0.027
<
0.020
<
0.131
0.060
0.354
15.Z17
3.047
0.037
0.130
<
0.201
0.166
23.503
0.015
0.501
0.137
0.178
0.022
30.867
NA
NA
NA
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0,100
0.200
0.076
1.446
0.800
0.207
0.055
0.000
0.000
0.000
0.000
0.013
0.000
0.035
1.522
0.305
0.000
0.030
0.000
0.020
0.017
2.350
0.000
0.050
0.065
0.066
0.013
3.087
0.000
0.000
0.000
Blast Furnace
sampler.
: (0-2.5)
: 0.570
2.5-10 un
Xut
NA
NA
NA
NA
NA
0.100
0.200
0.730
13.189
4.700
2.179
0.540
0.038
<
0.031
<
0.163
0.055
0.355
14.917
3.347
0.018
0.120
<
0.025
0.146
21 .308
0.050
0.482
0.059
0.216
0.025
29.683
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.100
0.200
0.073
1.607
0.500
0.218
0.070
0.000
0.000
0.000
0.000
0.021
0.000
0.035
1.492
0.335
0.000
0.020
0.011
0.024
0.040
2.131
0.000
O.OS1
0.151
0.308
0.020
2.968
0.000
0.000
0.000
(0-6)
0.720
0-10 urn
Xwt
0
0
0
13
4
2
0
0
0
0
0
0
15
3
0
0
0
0
22
0
0
0
0
0
NE
NE
NE
NE
NE
.100
.200
.753
.242
.899
.110
.547
.031
NE
.024
NE
.142
.058
.354
.116
.148
.031
.127
NE
.142
.159
.763
.027
.495
.111
.191
.023
30.468
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.095
0.189
0.121
2.265
0.897
0.345
0.093
0.000
0.000
0.000
0.000
0.026
0.000
0.057
2.446
0.520
0.000
0.029
0.000
0.028
0.035
3.642
0.000
0.091
0.110
0.210
0.016
4.916
0.000
0.000
0.000
(0-10)
0.860
Total
Measured
%Ht
NA
NA
NA
NA
NA
0.100
' 0.200
0.758
13.255
4.949
2.093
0.548
0.029
<
0.022
<
0.136
0.059
0.354
15.166
3.098
0.034
0.128
<
0.171
0.163
23.130
0.021
0.498
0.124
0.184
0.022
30.666
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.071
0.141
0.076
1.325
0.495
0.209
0.055
0.000
0.000
0.000
0.000
0.014
0.000
0.035
1.517
0.310
0.000
0.018
0.000
0.017
0.021
2.313
0.000
0.050
0.082
0.157
0.012
3.067
0.000
0.000
0.000
170
-------
PM Profile Speciation Report - continued (profile 29302}
Total Particulats Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 urn Measured
Species ••• ...... . ;.,--
CAS Number Nun Sym %ut unc Xut unc Xwt unc Xut unc
204 N03 NA 0.000 NA 0.000 NE 0.000 NA 0.000
TOTALS: 96.571 92.676 95.261 95,908
171
-------
PH Profile Speciation Report
Profile Name Primary
Profile Nunfeer 29303
Data Quality B/C
Lead
Smelting -
Control Device Baghouse
Reference(s) 43
Data Source Sampled with a dilution
SCC Assignments 30301008
Mass Fraction Data • Size Interval (urn)
Mass Fraction
Total Particulate Hatter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
•jpwv I vo
Hum Sym
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
38
46
47
48
49
50
51
56
80
82
201
202
203
Be
B
F
Na
Ng
Al
Si
P
s
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
Br
Sr
Pd
Ag
Cd
In
Sn
Sb
Ba
Hg
Pb
oc
EC
S04
0-2
%Ht
0.
1.
0.
2.
1.
0.
0.
0.
0.
' 0.
0.
0.
53.
1.
0.
0.
q.
d.
0.
0.
0.
0.
7.
NA
NA
NA
NA
NA
500
500
164
567
700
550
200
026
<
011
<
164
098
207
517
424
011
<
<
128
048
084
056
703
545
<
064
459
NA
NA
NA
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.100
0.300
0.016
0.334
0.400
0.055
0.100
0.000
0.000
0.000
0.000
0.016
0.000
0.021
5.352
0.142
0.000
0.000
0.000
0.013
0.000
0.000
0.000
0.070
0.054
0.039
0.000
0.746
0.000
0.000
0.000
Zinc Fuming
sampler.
s {0-2.5}
: 0.570
2.5-10 urn
Xwt
NA
NA
NA
NA
NA
0.300
0.700
0.182
3.544
0.300
0.613
0.300
0.033
<
0.014
<
0.386
0.104
0.273
59.174
1.525
0.012
<
<
0.063
0.039
0.062
0.030
0.706
0.587
<
0.061
9.645
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.100
0.200
0.018
0.449
0.100
0.061
0.100
0.000
0.000
0.000
0.000
0.039
0.010
0.027
5.917
0.152
0.000
0.000
0.000
0.011
0.012
0.019
0.000
0.071
0.061
0.100
0.000
0.964
0.000
0.000
0.000
(0-6)
0.720
0-10 ym
Xwt
NE
HE
NE
NE
NE
0.433
1.230
0.170
2.896
1.228
0.571
0.234
0.028
NE
0.012
NE
0.239
0.100
0.229
55.425
1.458
0.011
NE
NE
0.106
0.045
0.077
0.047
0.704
0.559
NE
0.063
8.196
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.109
0.285
0.028
0.553
0.318
0.094
0.100
0.000
0.000
0.000
0.000
0.048
0.000
0.039
9.159
0.239
0.000
0.000
0.000
0.017
0.000
0.000
0.000
0.114
0.092
0.000
0.000
1.400
0.000
0.000
0.000
(0-10)
0.860
Total
Measured
Xwt
NA
NA
NA
NA
NA
0.450
1.300
0.168
2.811
1 .350
0.566
0.225
0.028
<
0.012
<
0.219
0.099
0.223
54.931
1.449
0.011
<
<
0.112
0.046
0.078
0.049
0.704
0.555
<
0,063
8.005
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0,071
0.180
0.017
0.281
0.206
0.057
0.071
0.000
0.000
0.000
0.000
0.022
0.000
0.022
5.493
0.145
0.000
0.000
o.ooo
0.011
0.000
0.011
0.000
0.070
0.055
0.054
0.000
0.800
0.000
0.000
0.000
171'
-------
PM Profile Speciation Report - continued (profile 29303)
Total Particulate Matter -
Total
0*2.5 urn 2.5-10 urn 0-10 urn Measured
Species --»—-* — '-•>.
CAS Number Nun Sym %wt unc Xut unc Xwt unc %ut unc
204 N03 • NA 0.000 KA 0.000 NE 0.000 NA 0.000
TOTALS: 71.726 78.653 74.061 73.454
173
-------
PH Prof He Specfation Report
Prof fie Name Primary
Profile Number 29304
Data Quality B/C
Lead
Smelting •
Control Dtvice Boghouse
Reference(s) 43
Data Source Sampled with a dilution
SCC Assignments 30301001
Mass Fraction Data - Size Interval Cum)
Mass fraction
Total Paniculate Hatter -
CAS Nuifcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
<0p\?V 1 C2>
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Be
B
F
Ha
MB
Al
Si
P
s
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Mi
Cu
In
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ai
Cd
Sn
Sb
Cs
ia
0-2
Xut
0
3
0
15
1
0
2
0
0
0
0
5
0
1
4
4
0
0
0
0
1
q
1
0
NA
NA
NA
NA
NA
.900
.000
.798
.829
.000
.889
.600
<
.169
.000
.046
.380
.764
<
.082
.498
.174
<
<
.948
.129
.080
<
.198
<
.246
.358
.234
.907
<
.115
.5 un
unc
0.000
0.000
0.000
0.000
0.000
0.090
0,300
0.080
1.583
0.100
0.089
0.260
0.000
0.017
0.000
0.005
0.038
0.576
0.000
0.008
0.150
0.417
0.000
0.000
0.495
0.013
0.020
0.000
0.020
0.000
0.034
0.000
0.049
0.191
0.000
0.205
Sintering
sampler.
: CO-2.5)
: 0.820
2.5-10 urn
%ut
NA
NA
NA
NA
NA
1.000
3.500
0.767
15.097
0.900
0.741
5.000
<
0.203
0.000
0.065
0.500
7.761
<
0.093
2.060
5.678
<
<
2.900
0.085
0.060
<
0.262
<
0.234
1.158
0.128
1.603
<
0.375
unc
0.000
0.000
0.000
0.000
0.000
0.300
1.000
0.120
2.390
0.200
0.112
1.000
0.000
0.031
0.000
0.013
0.100
1.085
0.000
0.017
0.289
0.793
0.000
0.000
0.429
0.018
0.000
0.000
0.040
0.000
0.070
0.192
0.106
0.312
0.000
0.491
W-65
0.890
0-10 urn
%wt
NE
NE
NE
NE,
NE
0.911
3.054
0.795
15.749
0.989
0.873
2.861
NE
0.173
0.000
0.048
0.393
5.981
NE
0.083
1.559
4.337
NE
NE
4.725
0.124
0.078
NE
0.205
NE
0.245
1.336
0.222
1.874
NE
0.143
unc
0.000
0.000
0.000
0.000
0.000
0.327
1.097
0.190
3.759
0.262
0.194
1.163
0.000
0.046
0.000
0.016
0.124
1.638
0.000
0,023
0.433
1.194
0.000
0.000
0.929
0.028
0.022
0.000
0.057
0.000
0.082
0.283
0.109
0.453
0.000
0.477
<0-103
0.920
Total
Measured
%ut
NA
NA
NA
NA
NA
0.922
3.110
0.791
15.667
0.978
0.856
3.128
<
0.176
0.000
0.050
0.406
6.203
<
0.084
1.622
4.505
<
<
4.497
0.119
0.076
<
0.212
<
0.243
1.314
0.211
1.840
<
0.172
unc
0.000
0.000
0.000
0.000
0.000
0.180
0.707
0.079
1.567
0.269
0.086
0.522
0.000
0.018
0.000
0.000
0.064
0.620
0.000
0.000
0.162
0.450
0.000
0.000
0.450
0.012
0.011
0.000
0.021
0.000
0.039
0.131
0.058
0.184
0.000
0.266
174
-------
PM Profile Speciatfon Report - continued (profile 29304J
Total Participate Matter -
Total
0-2.5 un 2.5-10 urn 0-10 urn Measured
Speqies — • •• _
CAS Number Num Sym Xut unc Xwt unc Xwt unc Xwt unc
7440-45-1
7439-97-6
7439-92-1
58
80
82
201
202
203
204
Ce
Hg
Pb
QC
EC
S04
N03
<
0.172
26.610
NA
NA
NA
NA
0.000
0.022
2.661
0.000
0.000
0.000
0.000
<
0.142
26.900
«A
.HA
NA
NA
0
0
3
0
0
0
0
.000
.033
.750
.000
.000
.000
.000
NE
0.169
26.642
NE
NE
NE
NE
0.000
0.045
6.268
0.000
0.000
0.000
0.000
«
0.165
26.674
NA
NA
NA
NA
0.000
0.020
2.667
0.000
0.000
0.000
0.000
TOTALS: 73.126 77.212 73.569 74.021
175
-------
PH Profile Speciation Report
Profile Name Priiwry Lead
Profile Nurfcer 29305
Data Quality B/C
Smelting - Blast Furnace Upset
Control Device Baghouse
Reference(s) 43
Data Source Blast furnace upset samples collected with a dilution
sampler.
SCO Assignments: 30301002
Ness Fraction Data - Size Interval (un) : (0-2. S) (0-6)
Mass Fraction ; 0.570 0.720
Total Particulate Hatter •
CAS Nunber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
77S2-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
3W
-------
PH Profile Speciat ion Report - continued (profile 29305)
Total Partfculate Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 un Measured
Species
CAS Number Nun Sym %wt unc %ut unc Xwt unc %ut unc
203 S04 NA 0.000 HA 0.000 NE 0.000 NA 0.000
204 N03 NA 0.000 NA 0.000 NE 0.000 NA 0.000
TOTALS: 100.000 73.373 90.851 86.712
177
-------
PH Profile Speciation Report
Profile Name Primary
Profile Nunfcer 29306
Data Quality B/C
Lead
Smetting-Zinc Baghouse
Control Device Bflghouse
Reference(s) 43
Data Source Sampled within the zinc fining baghouse
and low- volume samplers.
SCO Assignments: 30301008
Mass Fraction Data - size Interval (un) : (0-2.5)
Mass Fraction : 0.820
Total Paniculate Natter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
Num
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
38
46
47
48
49
50
51
56
80
82
201
202
Sym
Be
B
r
Ha
Kg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
Br
Sr
Pd
Ag
Cd
In
Sn
Sb
Ba
Hg
Pb
OC
EC
0-2
%Ht
NA
NA
NA
NA
NA
0.050
0
0
.779
.311
6.254
0
0
' 0
0
0
0
0
50
2
0
0
0
0
0
<
.949
.500
.042
<
.016
<
.221
.095
.259
.140
.298
.011
.030
<
.034
.032
.080
0.030
1
0
0
12
.066
.717
<
.048
.440
NA
NA
.5 un
unc
0.000
0.000
0,000
0.000
0.000
0.020
0.078
0.031
0.639
0.054
0.095
0.300
0.000
0.000
0.000
0.000
0.022
0.000
0.026
5.014
0.230
0.000
0.000
0.000
0.014
0.019
0.03t
0.000
0.107
0.092
0.168
0.011
1.244
0.000
0.000
2.5-10 un
XHt
HA
HA
HA
NA
HA
1.551
5.091
0.272
4.308
0.050
0.834
1.000
0.090
<
0.014
0.050
1.150
0.098
0.498
43.478
1.457
0.011
<
0.014
0.053
0.037
0.030
<
0.702
0.413
<
0.049
12.482
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.155
0.509
0.027
0.575
0.050
0.083
0.200
0.000
0.000
0.000
0.000
0.115
0.000
0.050
4.348
0.146
0.000
0.000
0.000
0.013
0.017
0.026
0.000
0.070
0.069
0.144
0.000
1.248
0.000
0.000
with dichotomous
(0-6)
0.890
0-10 urn
%wt
NE
NE
NE
NE
NE
0.213
1.248
0.307
6.042
NE
0.936
0.554
0.047
NE
0.016
NE
0.322
0.095
0.285
49.416
2.207
0.011
NE
Ni
0.036
0.033
0.075
NE
1.026
0.684
NE
0.048
12.445
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.240
0.795
0.064
1.226
0.000
0.195
0.351
0.000
0.000
0.000
0.000
0.181
0.000
0.087
10.245
0.420
0.000
0.000
0.000
0.019
0.024
0.038
0.000
0.197
0.146
0.000
0.000
2.720
0.000
0.000
(0-10)
0.920
Total
Measured
%ut
NA
NA
NA
NA
NA
0.600
2.000
0.190
3.041
0.150
0.862
0.500
0.082
<
0.017
0.030
1.042
0.115
0.625
53.304
1.777
0.020
<
0.011
0.080
0.033
0.070
0.011
0.861
0.728
<
0.059
12.780
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.200
0.800
0.019
0.558
0.050
0.086
0.100
0.000
0.000
0.000
0.000
0.104
0.011
0.062
5.330
0.178
0.000
0.000
0.000
0.000
0.000
0.013
0.000
0.086
0.073
0.055
0.000
1.278
0.000
0.000
178
-------
PM Profile Speciation Report - continued (profile 29306)
Total Participate
Matter •
Total
-
CAS Number Nun Sym
203
204
S04
N03
0-2.
%wt
NA
NA
5 un
unc
0.000
0.000
2.5-10 urn
Xwt unc
NA 0.000
Kft 0.000
0-10
Xwt
NE 0
Hi 0
urn
unc
.000
.000
Measured
Xwt
NA
NA
unc
0.000
0.000
TOTALS: 76.402 73. B2 76.046 78.988
179
-------
PH Profile Speciation Report
Profile Name : Primary Lead Smelting-Dross Reverberator/ Furnace
Profile Number : 2930?
Data Quality : 8/C
Control Device ; Uncontrolled
Reference(s) : 43
Data Source : Samples collected near building vents with dichotomous
and low-volume sampler.
SCC Assignments: 30301003
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Parttculate Matter
Species
CAS Number Hum Sym
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
38
46
47
48
49
50
51
56
80
82
201
202
Be
B
f
Na
Mi
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Hi
CU
Zn
As
Se
Br
Sr
Pd
Ai
Cd
In
Sn
Sb
Ba
Hi
Pb
oc
EC
"
0-2
%wt
0
0
0
f
0
0
0
0
0
0
0
2
57
0
2
0
1
0
0
5
0
0
5
NA
NA
NA
NA
NA
.030
.200
.125
.667
<
.108
.600
.060
<
<
.013
.106
.054
.140
.361
.818
.115
<
<
.389
.854
.164
.023
.191
.200
.078
.269
.561
NA
NA
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.100
0.012
0.244
0.017
0.011
0.100
0.000
0.000
0.000
0.000
0.011
0.000
0.014
0.236
5.782
0.011
0.000
0.000
0.239
0.085
0.116
0.000
0.019
1.000
0.022
0.027
0.556
0.000
0.000
: (0-2.5)
: 0.810
2.5-10 urn
%Nt
NA
NA
HA
NA
NA
0.500
1.460
0.141
1.534
<
0.279
1.160
0.056
<
0.013
0.039
0.752
0.076
1.873
0.963
20.000
0.084
<
0.014
0.504
0.300
0.800
0.191
1.600
2.000
0.032
0.107
16.000
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.100
0.146
0.014
0.533
0.034
0.028
0.116
0.000
0.000
0.000
0.000
0.075
0.000
0.187
0.096
2.000
0.000
0.000
0.000
0.050
0.030
0.200
0.019
0.300
0.300
0.023
0.011
4.000
0.000
0.000
(0-6)
0.920
0-10 urc
%ut
NE
NE
NE
NE
NE
0.112
0.419
0.128
1.644
NE
0.138
0.697
0.059
NE
NE
0.018
0.218
0.058
0.441
2.118
51.258
0.110
NE
NE
2.062
0.758
1.101
0.052
0.435
4.645
0.070
0.241
7.372
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.226
0.027
0.552
0.000
0.043
0.198
0.000
0.000
0.000
0.000
0.109
0.000
0.269
0.365
8.758
0.000
0.000
0.000
0.350
0.129
0.253
0.000
0.312
1.081
0.028
0.042
3.881
0.000
0.000
(0-10)
0.980
Total
Measured
%wt
NA
NA
NA
NA
NA
0.030
0.200
0.035
<
<
<
0.763
0.016
<
0.016
0.024
0.744
0.086
2.894
1.358
24.000
0.093
<
0.011
1.090
0.494
1.219
0.231
1.242
2.700
0.125
0.104
13.482
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.100
0.000
0.582
0.038
0.000
0.076
0.000
0.000
0.000
0.000
0.074
0.000
0.289
0.136
3.000
0.000
0.000
0.000
0.109
0.049
0.122
0.023
0.124
0.400
0.014
0.010
1 .348
0.000
0.000
180
-------
PH Profile Speciation Report - continued (profile 29307}
Total Participate
Matter •
Total
CAS Ntnber Nun Sym
203
204
804
N03
0-2
Xwt
NA
NA
.5 urn
unc
0.000
0.000
2.5-10 urn
Xwt unc
MA 0.000
NA 0.000
0-10
Xwt
NE
HE
urn
Line
0.000
0.000
Measured
Xwt
NA
NA
unc
0.000
0.000
TOTALSs 79.126 50.478 74.154 50.957
181
-------
PH Profile Speciation Report
Profile Name Primary
Profile Number 2?30?
Data Quality B/C
Lead
Smelt ing- Sinter Production
Control Device Uncontrolled
Reference^) 43
Data Source Samples collected at various locations on the pile.
Bulk sample sieved and resuspended.
SCC Assignments: 30301025
Mass Fraction Data - Size Interval (urn) : {0-2.5} CO-65
Mass Fraction s 0.870 0.940
Total Particulate Hatter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
OJ^lSt. 1 C!>
Nlirn ^vfn
4
5
9
11
12
13
14
15
16
17
19
t.\i
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
33
46
47
48
49
50
51
Be
B
F
Na
Ms
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
CU
Zn
Ga
Ge
As
Se
Br
Rb
5r
Pd
Ag
Cd
In
Sn
Sb
0-2
Xwt
0.
0.
0.
1.
2.
0.
0.
d.
0.
0.
0.
0.
0.
8.
0,
0.
0.
2.
0.
8.
2.
2,
NA
NA
NA
NA
NA
050
900
300
400
000
020
050
<
<
<
016
015
160
<
056
221
867
<
<
692
155
100
<
030
702
699
859
<
541
380
,5 un
unc
0.000
0.000
0.000
0.000
0.000
0.050
0.200
0.030
2.000
1.000
0.020
0.020
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
0.022
0.087
0.000
0.000
0.869
0.015
0.050
0.000
0.000
0.270
0.070
0.886
0.000
0.254
0.238
2.5-10 urn
Xut
NA
NA
NA
NA
NA
0.650
2.900
0.360
6.000
1.000
0.240
2.000
<
0.040
<
0.038
0.300
4.800
<
0.083
1.659
4.243
<
<
5.532
0.084
0.100
<
0.184
0.746
• 0.378
2.884
<
0.680
1.833
unc
0.000
0.000
0.000
0.000
0.000
0.065
0.400
0.040
2.000
0.300
0.024
0.200
0.000
0.000
0.000
0.000
0.100
0.500
0.000
0.000
0.166
0.424
0.000
0.000
0.553
0.000
0.050
0.000
0.018
0.075
0.038
0.288
0.000
0.068
0.183
0-10 urn
Xut
NE
NE
NE
NE
NE
0.117
1.124
0.307
1.916
1.888
0.045
0.269
NE
NE
NE
0.018
0.047
0.681
NE
0.059
0.382
1.246
NE
NE
8.337
0.147
0.100
NE
0.047
2.482
0.663
8.188
NE
2.332
2.319
unc
0.000
0.000
0.000
0.000
0.000
0.110
0.550
0.074
2.627
0.968
0.041
0.308
0.000
0.000
0.000
0.000
0.000
0.749
0.000
0.000
0.257
0.666
0.000
0.000
1.584
0.000
0.065
0.000
0.000
0.431
0.122
1.433
0.000
0.404
0.462
(0-10)
0.980
Total
Measured
%Ut
NA
NA
NA
NA
NA
0.050
0.460
0.120
1.000
0.500
0.050
0.500
<
<
<
0.017
0.120
2.344
<
0.061
1.007
2.688
<
<
4.921
0.101
0.100
<
0.097
0.730
0.347
3.705
<
0.776
1.725
unc
0.000
0.000
0.000
0.000
0.000
0,050
0.100
0.040
1.000
0.500
0.050
0.100
0,000
0.000
0.000
0.000
0.012
0.234
0,000
0.000
0.101
0.269
0.000
0.000
0.492
0.010
0.050
0.000
0.000
0.073
0.035
0.370
0.000
0.078
0.172
182
-------
PH Profile Speciation Report - continued (profile 29309)
Total Perticulate Matter -
.
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
0pi;b. i c»
Nun Sym
56
58
80
82
201
202
203
204
Ba
Ce
HS
Pb
oc
EC
S04
N03
0-2
Xwt
0.522
<
0.129
46.503
NA
NA
NA
NA
.5
un
unc
0
0
0
4
0
0
0
0
.052
.000
.018
.650
.000
.000
.000
.000
2.5-10 us
Xwt
0.257
<
0.187
27.915
NA
NA
NA
NA
unc
0.026
0.000
0.019
2.791
0.000
0.000
0.000
0.000
0-10 un
Xwt
0.492
NE
0.136
44.417
NE
N|
NE
NE
unc
0.089
0.000
0.037
8.340
0.000
0.000
0.000
0.000
Total
Measured
Xwt
0.275
<
0.119
31.410
NA
NA
NA
NA
unc
0.027
0.000
0.013
3.141
0.000
0.000
0.000
0.000
TOTALS:
79.367
65.093
77.759
53.223
183
-------
PH Profile Speciation Beport
Profile Name Primary Lead
Profile Number 29310
Oats Quality D
-.Dross Building
Control Device UncontrolledC!}
Reference(s) 62,75
Data Source Data taken from Reference 62. For details, consult Reference
75,
SEC Assignments: 30301009
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6} (0-10)
Mass Fraction : 0.830 0.930 0.980
Total Particulate Matter -
CAS Number
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
~™~""~~e~^K»=
tjpc^ I CO
Hum Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
1C
Ca
Ti
V
Cr
Mn
Fe
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Kg
Pb
0-2
Xut
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
58.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
5,
0.
0.
0.
13.
80.
000
000
000
000
000
000
000
000
000
003
000
482
023
179
745
027
289
000
000
000
007
026
018
051
000
081
548
028
233
871
065
122
000
256
054
.5 urn
unc
0.078
0.024
0.016
0.416
0.147
0.040
0.080
0.008
0.002
0.008
0.003
0.634
0.042
0.052
0.200
0.092
9.831
0.016
0.194
0.042
0.012
0.088
0.009
0.026
0.002
0.075
0.297
O.OB4
0.400
4.088
0.060
0.141
0.024
9.693
2.5-10 un
%Mt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.000
0.000
1.431
0.073
1.889
0.672
0.035
6.755
0.000
0.000
0.000
0.016
0.000
0.039
0.033
0.017
0.290
0.133
0.047
0.842
1.077
0.000
0.000
0.040
15.791
29.185
unc
0.111
0.056
0.023
0.635
0.130
0.045
0.113
0.011
0.021
0.003
0.006
0.820
0.102
0.457
0.235
0.146
5.152
0.028
0.065
0.016
0.055
0.039
0.128
0.089
0.056
0.155
0.235
0.190
0.320
0.855
0.028
0.028
0.155
5.847
0-10 UJI»C2>
%wt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.003
0.000
0.627
0.031
0.441
0.734
0.028
50.401
0.000
0.000
0.000
0.008
0.022
0.021
0.048
0.003
0.113
0.484
0.031
0.326
5.137
0.055
0.103
0.006
13.644
72.267
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.002
o.ooo
0.770
0.038
0.697
0.723
0.030
42.673
0.000
0.000
0.000
0.010
0.018
0.024
0.046
0.005
0.144
0.422
0.034
0.418
4.418
0.045
0.085
0.012
14.024
64.640
unc
0.064
0.024
0.013
0.348
0.110
0.031
0.065
0.007
0.007
0.006
0.003
0.511
0.043
0.152
0.172
0.078
8.645
0.014
0.137
0.030
0.019
0.063
0.039
0.033
0.017
0.071
0.224
0.082
0.297
2.906
0.043
0.099
0.050
7.113
C1> No controlled specified: thus, assumed uncontrolled.
tZy Calculated based on methodology described in the Air Emissions Species Manual,
Volume II. 184
-------
PH Profile Speciation Report
Profile Name Primary
Profile Number 29311
Data Quality E
Lead
- Slag Pour
Control Device UncontrolledC1>
Reference(s) 62,75
Data Source Data taken from Reference 62. For details, consult Reference
75.
SCC Assignments: 30301021
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.730 0.830
Total Participate Matter
Species
CAS Number Nun
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
MO
Pd
Ag
Cd
In
Sn
Sb
Ba
La
»9
Pb
0-2.5
Xwt
0.
0.
0.
0.
0.
0.
q.
0.
0.
0.
0.
0.
0.
0.
48.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
000
000
000
000
959
091
000
000
043
044
319
000
084
556
034
060
000
000
021
000
000
015
000
000
000
000
0.013
0.
d.
0.
0.
000
000
000
000
0.015
27.
77.
417
671
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 umC2>
Xwt
0.000
0.000
0.000
0.000
0.000
0.959
0.091
0.000
0.000
0.043
0.044
0.319
0.000
0.084
48.556
0.034
0.060
0.000
0.000
0.021
0.000
0.000
0.015
0.000
0.000
0.000
0.000
0.013
0.000
0.000
0.000
0.000
0.015
27.417
77.671
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.000
0.000
0.000
0.000
0.000
0.959
0.091
0.000
0.000
0.043
0.044
0.319
0.000
0.084
48.556
0.034
0.060
0.000
0.000
0.021
0.000
0.000
0.015
0.000
0.000
0.000
0.000
0.013
0.000
0.000
0.000
0.000
0.015
27.417
77.671
um<2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.890
Total
Measured
Xwt
0.000
0.000
0.000
0.000
0.000
0.959
0.091
0.000
0.000
0.043
0.044
0.319
0.000
0.084
48.556
0.034
0.060
0.000
0.000
0.021
0.000
0.000
0.015
0.000
0.000
0.000
0.000
0.013
0.000
0.000
0.000
0.000
0.015
27.417
77.671
unc
0.023
0.011
0.011
1.506
0.311
0.557
0.104
0.002
0.001
0.082
0.081
0.039
0.010
0.181
11.856
0.123
1.626
0.011
0.016
0.125
0.010
0.079
0.034
0.007
0.023
0.011
0.023
0.062
0.045
0.023
0.045
0.045
0.042
2.821
<1> No control specified: thus, assumed uncontrolled.
<2> Estimated / extrapolated.
185
-------
PH Profile Speclet ion Report
Profile Name Primary
Profile Humber 29330
Data Quality C
Lead
Smelting -
Composite
Control Device Saghouse
Reference(s) 43
Data Source Developed from profiles 29303 and 29306
SCC Assignments 30301008
Mass Fraction Data * Size Interval (urn) : (0-2.5)
Mass Fraction : 0.690
Total Particulate Natter -
CAS Hunfcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
, 7440-21 -3
7723-14-0
7704-34-9
7782-50-5
, 7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-3S-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
0^*;h» I1«B»
Hum Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
46
47
48
49
50
51
Be
B
F
lia
Kg
Al
S!
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
2n
Ga
Ge
As
Se
ir
Rb
Sr
Zr
Pd
AS
Cd
In
Sn
Sb
0-2.5 urn
%wt
0.
0.
0.
0.
0.
0.
1.
0.
8.
0.
0.
1.
0.
0.
q.
6.
0.
2.
0.
0.
0.
35.
0.
0.
2.
0.
0.
0.
0.
. 0.
0.
0,
0.
0.
0.
1.
000
000
000
000
000
483
760
424
217
900
796
100
000
079
000
024
127
050
000
092
655
944
000
000
890
050
037
000
066
000
054
109
507
029
668
056
unc
0.000
0.000
0.000
0.000
0.000
0.079
0.249
0.050
1 .004
0.240
0.082
0.236
0.000
0.010
0.000
0.003
0.022
0.333
0.000
O.OOS
0.089
4.241
0.000
0.000
0.326
0.008
0.012
0.000
0.012
0.000
0.011
0.022
0.018
0.000
0.079
0.126
2.5-10 un
Xwt
0.000
0.000
0.000
0.000
0.000
0.950
3.097
0.407
7.650
0.417
0.729
2.100
0.000
0.109
0.000
0.031
0.183
3.099
0.000
0.098
0.944
36.110
0.000
0.000
1.961
0.036
0.020
0.000
0.092
0.000
0.039
0.103
0.417
0.010
0.512
0.868
unc
0.000
0.000
0.000
0.000
0.000
0.203
0.658
0.072
1.443
0.132
0.088
0.592
0.000
0.018
0.000
0.008
0.058
0.630
0.000
0.011
0.170
4.264
0.000
0.000
0.276
0.010
0.000
0.000
0.023
0.000
0.010
0.042
0.112
0,000
0.084
0.188
(0-6)
0.800
0-10 UT)
%Ht
0.000
0.000
0.000
0.000
0.000
0.588
2.060
0,420'
8.089
0.791
0.781
1.325
0.000
0.086
0.000
0.026
0.139
2.285
0.000
0.093
0.720
35.981
0.000
0.000
2.681
0.047
0.033
0.000
0.072
0.000
0.051
0.107
0.487
0.024
0.633
1.014
unc
0.000
0.000
0.000
0.000
0.000
0.205
0.671
0.094
1.836
0.239
0.151
0.558
0.000
0.022
0.000
0.008
0.054
0.687
0.000
0.018
0.195
7.276
0.000
0.000
0.506
0.012
0.010
0.000
0.024
0.000
0.014
0.041
0.114
0.003
0.128
0.231
(0-10)
0.890
Total
Measured
%Ht
0.000
0.000
0.000
0.000
0.000
0.657
2.137
0.383
7.173
0.826
0.761
1.284
,0.000
0.095
0.000
0.026
0.145
2.488
0.000
0.099
0.823
37.580
0.000
0.000
2.574
0.050
0.025
0.000
0.074
0.000
0.064
0.107
0.487
0.020
0.592
1.041
unc
0.000
0.000
0.000
0.000
0.000
0.161
0.625
0.048
0.974
0.198
0.078
0.310
0.000
0.010
0.000
0.000
0.037
0.363
0.000
0.006
0.101
4,427
0.000
0.000
0.292
0,007
0.006
0.000
0.012
0.000
0.006
0.023
0.076
0.000
0.072
0.119
186
-------
PH Profile Speciat ion Report - continued (profile 29330}
Total Paniculate Hatter -
0-2.5 un 2.5-10 urn 0-10 un
Total
Measured
CAS Number Nun Sym
Xwt
unc
%ut
unc
Xwt
une
XMt
unc
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
55
56
58
80
82
201
202
203
204
Cs
Ba
Ce
Hg
Pb
OC
EC
$04
N03
0
0
0
0
15
0
0
0
0
73
.000
.038
.000
.095
.503
.000
.000
.000
.000
.753
0.000
0.155
0.000
0.014
1.750
0.000
0.000
0.000
0.000
0.000
0.125
0.000
0.084
16.342
0.000
0.000
0.000
0.000
76.533
0.000
0.301
0.000
0.019
2.349
0.000
0.000
0.000
0.000
0.000
0.058
0.000
0.092
15.692
0.000
0.000
0.000
0.000
74.375
0.000
0.263
0.000
0.023
3.355
0.000
0.000
0.000
0.000
0.000
0.057
0.000
0.096
15.820
0.000
0.000
0.000
0.000
75.484
0.000
0.160
0.000
0.012
1.769
0.000
0.000
0.000
0.000
187
-------
188
-------
3.5 SECONDARY METAL PRODUCTION
Secondary metal"production is the production of metals from scrap
material. Processes generating participate emissions can include smelting,
pouring into molds, cleaning, refining, alloying, and storage and handling.
189
-------
190
-------
PM Profile Speciat ion Report
Profile Name : Scrap Copper Incinerator
Profile Number : 19101
Data Quality : 0/E
Control Device : Uncontrolled
Reference(s) : 43
Data Source : Plume sample collected with low-volume sampler.
Incineration of machinery oil end plastic and insulation.
SCC Assignments: 30400208
Mass Fraction
Data
Total Participate
• Size
Mass
Hatter -
Species
CAS Number Nun
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Sym
Be
B
F
Na
Hg
Al
Si
P
S
Cl
K
Ca
SC
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ce
As
Se
Br
Kb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Interval Cum) :
Fraction :
0-2.5 urn
Xwt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
• < 0.000
< 0.000
< 0.000
0.115 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.071 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
CO-2.S3
0.240
2.5-10 urn
Xwt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
< 0.000
< 0.000
< 0.000
0.115 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.071 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
<0-6)
0.320
0-10 urn
Xwt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
< 0.000
< 0.000
< 0.000
0.115 0.013
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.071 0.008
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
(0-10)
0.420
Total
Measured
Xwt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
< 0.000
< 0.000
< 0.000
0.115 0.011
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.071 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
191
-------
PM Profile Specfatfon Report - continued {profile 191015
Total Paniculate Hatter •
Total
0-2.5 urn 2.5-10 un 0-10 urn Measured
Species ' -•— • •
CAS Number Nun Syra Xwt unc Xwt unc Xwt unc %wt unc
7440-39-3 56
7440-45-1 58
7439-97-6 80
7439-92-1 82
201
202
203
204
Ba
Ce
Ha
Pb
oc
EC
S04
N03
<
' <
NA
NA
NA
NA
0.
0.
0.
0.
0.
0.
0.
0.
000
000
000
000
000
000
000
000
<
<
NA
NA
NA
NA
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<
<
NA
NA
NA
NA
0.
0.
0.
0.
0.
0.
0.
0.
000
000
000
000
000
000
000
000
<
<
NA
NA
NA
NA
0.000
0.000
0.000
0.000
0.000
O.DOO
0.000
0.000
TOTALS: 0.186 0.186 0.186 0.186
192
-------
PM Profile Spec!at ion Report
Profile Name
Profile Number
Data Quality
Aluminum Foundry-Reverboratory Furnace
20101
0/E
Control Device Uncontrolled
Referenced) 10
Data Source SASS train with heated Method 5 probe, 3 cyclones, at 600
cleg. F. Cyclone and filter catches analyzed by XRF. si,
P, and S nomquantitative.
SCC Assignments: 30400103
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate
<*.*«.
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
apw
Hum
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
Matter
:ies
Sym
Be
B
f
Na
Kg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
0-2
%wt
NA
NA
NA
NA
NA
NR
<
<
<
11.000
0.550
3.000
<
0.050
<
0.050
0.550
6.000
0.050
0.550
0.050
0.050
<
<
<
<
<
<
<
<
<
<
0.050
. <
.5 un
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.500
2.5-10 un
Xwt
NA
NA
NA
NA
NA
NR
<
<
<
11.000
0.550
3.000
<
0.050
<
0.050
0.550
6.000
0.050
0.550
0.050
0.050
<
<
<
<
<
<
<
<
«
<
0.050
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.530
0-10 urn
%Mt
11
0
3
0
0
0
6
0
0
0
0
0
NE
NE
NE
NE
NE
NE
NE
NE
Ni
.000
.550
.000
NE
.050
NE
.050
.550
.000
.050
.550
.050
.050
NE
NE
NE
Ni
NE
NE
Ni
NE
NE
Ni
.050
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-10)
0.600
Total
Measured
Xwt
NA
NA
NA
NA
NA
NR
<
<
<
11.000
0.550
3.000
<
0.050
<
0.050
0.550
6.000
0.050
0.550
0.050
0.050
<
<
<
<
<
<
<
<
<
<
0.050
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
193
-------
PH Profile Speciation Report - continued (profile 20101)
Total Participate Hatter -
Total
0-2.5 urn 2.5-10 urn 0-10 urn Measured
Species «— ..... ...... ...
CAS Number Hum Sym %nt unc Xut unc Xwt unc %ut unc
7440-46-2 55
7440-39-3 56
7440-45-1 58
7439-97-6 SC
7439-92-1 82
201
202
203
204
Cs
Ba
Ce
"*
Pb
OC
EC
S04
N03
! °
13
16
0
<
<
.050
.000
NA
.000
.550
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
13
16
0
<
<
.050
.000
NA
.000
.550
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
m
NE
NE
NE
0.050
13.000
NE
16.000
0.550
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<
<
0.050
13.000
NA
16.000
0.550
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS; 51'.550 51.550 51.550 51.550
194
-------
PM Profile Special ion Report
Profile Name Secondary Aluminum Plant
Profile Kutnber 20102
Data Quality B/D
- Dross
Control Device Baghouse
Referenced 52
Data Source Dilution sampling train.
SCC Assignments 30400107
Mass Fraction Data - Size Interval (urn) :
Nass Fraction :
Total Particulate
Natter
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
9I/*SI* 1 «tt
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Be
B
f
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
«n
Fe
Co
Ni
Cu
2n
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
cd
Sn
Sb
CS
Ba
Recovery Furnace
tO-2.5>
0.820
<0-6>
0.890
(0-10)
0.920
Total
0-2
%wt
NA
NA
NA
NA
NA
1.447
6.412
0.373
2.883
23.212
10.035
0.079
<
0.025
0.006
0.028
0.010
0.251
<
0.033
0.042
0.079
0.000
<
0.011
0.016
0.065
0.004
0.005
0.002
0.020
0.000
0.047
0.597
<
0.036
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.082
0.315
0.068
0.156
1.139
0.490
0.030
0.000
0.003
0.001
0.003
0.002
0.015
0.000
0.003
0.004
0.005
0.001
0.005
0.005
0.002
0.004
0.003
0.003
0.015
0.014
0.019
0.025
0.068
0.000
0.113
4
11
0
1
17
10
0
0
0
0
0
1
0
2.5-
Xut
NA
NA
NA
NA
NA
.857
.501
.374
.959
.746
.295
.764
<
.112
.010
.063
.037
.319
<
.052
0.104
0
0
0
0
0
0
0
0
0
0
0
0
0
.202
.000
<
.005
.013
.039
.000
.003
.039
.061
.083
.000
.353
<
.000
10 un
unc
0.000
0.000
0.000
0.000
0.000
0.447
1.055
0.114
0.261
1.875
1.017
0.090
0.000
0.015
0.005
0.009
0.007
0.120
0.000
0.010
0.014
0.022
0.004
0.000
0.014
0.005
0.009
0.007
0.009
0.044
0.043
0.057
0.079
0.162
0.000
0.347
0-10 urn
Xut
NE
NE
NE
NE
NE
1.818
6.965
0.373
2.783
22.618
10.063
0.153
NE
0.034
0.006
0.032
0.013
0.367
NE
0.035
0.049
0.092
0.000
NE
0.010
0.016
0.062
0.004
0.005
0.006
0.024
0.009
0.042
0.570
NE
0.032
unc
0.000
0.000
0.000
0.000
0.000
0.756
1.928
0.136
0.516
4.170
2.073
0.129
0.000
0.020
0.005
0.012
0.008
0.201
0.000
0.012
0.019
0.034
0.004
0.000
0.013
0.005
0.013
0.007
0.008
0.042
0.041
0.055
0.074
0.179
0.000
0.325
Measured
Xwt
NE
NE
NE
NE
NE
1.818
6.965
0.373
2.783
22.618
10.063
0.153
• NE
0.034
0.006
0.032
0.013
0.367
NE
0.035
0.049
0.092
0.000
NE
0.010
0.016
0.062
0.004
0.005
0.006
0.024
0.009
0.042
0.570
NE
0.032
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1S5
-------
PN Profile Speciation Report - continued (profile 20102)
Total Partieulate Hatter -
Species
CAS Nunfcer
7440*45-1
7439-97-6
7439-92-1
Nun
58
80
82
201
202
203
204
Sym
cc
Ng
Pb
DC
EC
SQ4
NOB
0-2
Xwt
<
0.000
0.079
NA
HA
HA
NA
.5
un
unc
0
0
0
0
0
0
0
.000
.003
.009
.000
.000
,000
.000
2.5-10 urn
Xwt
<
0.000
0.094
NA
NA
NA
NA
unc
0,000
0.010
0.023
0.000
0.000
0.000
0.000
0-10 un
Xwt
NE
0.000
0.031
NE
NE
HE
NE
unc
0.000
0.009
0.027
0.000
0.000
0.000
0.000
Total
.Measured
Xwt
NE
0.000
0.081
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
45.797
50.085
46.262
46.262
196
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Secondary Aluminum - Dross Recovery Furnace
20103
D
Control Device Uncontrolled{1>
Reference(s) 62,63
Data Source Data taken from Reference 62. For details, consult Reference
63.
SCC Assignments: 30400107
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.820 0.890
Total Participate Hatter -
CAS Number
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-22-4
7440-31-5
7440-36-0
7439-91-0
7440-45-1
7439-92-1
7440-29-1
TOTALS:
0-2.5 urn
Num Sym Xwt
11
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
34
35
37
47
50
51
57
58
82
90
201
202
203
204
Na
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Br
Rb
Ag
Sn
Sb
La
Ce
Pb
Th
OC
EC
S04
N03
15
1
3
0
3
20
10
0
0
0
0
0
0
0
0
0
0
.500
.700
.100
.450
.000
.000
.900
.120
NR
.024
.004
.039
.012
.290
.001
.033
.045
.075
0.002
0
0
0
0
0
0
0
1
0
0
2
60
.006
.063
.009
NR
.055
.570
.002
NR
.081
NR
.500
.190
.400
.200
.371
unc
1.600
0.200
2.200
0.270
4.000
4.000
1.500
0.090
0.000
0.003
0.001
0.004
0.001
0.090
0.000
0.003
0.020
0.008
0.001
0.001
0.007
0.004
0.000
0.054
0.060
0.001
0.000
0.014
0.000
1.400
0.070
0.360
0.900
2.5-10 urn
Xwt
18.000
4.700
7.600
0.370
2.000
21.000
6.300
0.870
0.000
0.120
0.006
0.061
0.029
1.200
0.006
0.056
0.110
0.190
0.002
0.009
0.039
NR
0.008
NR
NR
NR
0.002
0.098
0.000
43.000
4.000
NR
NR
109.776
unc
4.400
0.800
3.700
0.110
0.200
5.000
4.500
0.260
0.000
0.040
0.004
0.007
0.011
0.200
0.001
0.029
0.030
0.020
0.001
0.001
0.008
0.000
0.001
0.000
0.000
0.000
0.001
0.031
0.000
33.000
1.400
0.000
0.000
0-10
Xwt
15.772
2.026
3.589
0.441
2.891
20.109
10.400
0.202
NE
0.034
0.004
0.041
0.014
0.389
0.002
0.036
0.052
0.088
0.002
0.007
0.060
NE
NE
NE
NE
NE
NE
0.083
NE
6.011
0.604
NE
NE
62.857
um{2>
unc
5.081
0.926
4.088
0.275
3.597
6.709
4.700
0.282
0.000
0.049
0.008
0.024
0.018
0.252
0.006
0.035
0.045
0.047
0.004
0.008
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.044
0.000
31.420
1.381
0.000
0.000
(0-10)
0.920
Total
Measured
Xwt
15.972
2.266
3.949
0.435
2.811
20.189
10.032
0.262
0.000
0.042
0.004
0.043
0.015
0.462
0.002
0.037
0.057
0.097
0.002
0.007
0,059
0.008
0.002
0.045
0.463
0.001
0.000
0.084
0.000
9.330
0.909
0.325
1.785
69.695
unc
2.374
0.319
1.959
0.226
3.263
4.091
1.910
0.091
0.000
0.009
0.001
0.006
0.003
0.093
0.000
0.007
0.018
0.012
0.001
0.001
0.009
0.003
0.000
0.044
0.077
0.000
0.000
0.016
0.000
6.375
0.281
0.295
0.766
C1> No control specified: thus, assumed uncontrolled.
C2> alculated based on methodology described in the Air Emissions Species Manual,
Volume II.
-------
PH Profile Speclatfon Report
Profile Name Secondary Lead Smelter -
Profile Number 20401
Data Quality D/E
Blast Furnace
Control Device Baghouse
Reference(s) 23
Data Source Samples by isokinetfc Method 5 downstream of a baghouse.
Analysis by Optical Emission Spec.
SCC Assignments: 30400403
Mass Fraction Data - Size Interval (un) : (0-2.5) (0-6)
Mass Fraction : 0.650 0.780
Total Particulate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
w|^:i* ics»
Nun Sytn
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Be
B
F
Na
Mi
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
N;
Cu
Zn
Ca
Ge
As
Se
Br
Rb
Sr
Zr
AS
Cd
Sn
Sb
Cs
0-2
%wt
3
0
0
0
0
19
1
6
0
0
0
0
0
0
0
0
0
2
0
<
<
.000
.001
.003
.300
.050
<
.300
.000
.030
<
<
.001
.001
.003
.100
<
.001
.030
.300
<
<
.300
<
<
<
<
<
<
.700
.000
.200
<
.5 un
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
<
<
3.000
0.001
0.003
0.300
0.050
<
19.300
1.000
0.030
<
<
0.001
0.001
0.003
0.100
<
0.001
0.030
0.300
<
<
0.300
<
<
<
<
<
<
0.700
2.000
0.200
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
<
<
3.000
0,001
0.003
0.300
0.050
<
19.300
1.000
0.030
<
<
0.001
0.001
0.003
0.100
<
0.001
0.030
0.300
<
<
0.300
<
<
<
<
<
<
0.700
2.000
0.200
<
unc
0.000
0.000
0.000
0.464
0.000
0.000
0.046
0.008
0.000
2.987
0.155
0.005
0.000
0.000
0.000
0.000
0.000
0.015
0.000
0.000
0.005
0.046
0.000
0.000
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.108
0.310
0.031
0.000
(0-10)
0.840
Total
Measured
%wt
<
<
3.000
0.001
0.003
0.300
0.050
<
19.300
1.000
0.030
<
<
0.001
0.001
0.003
0.100
<
0.001
0.030
0.300
<
<
0.300
<
<
<
<
<
<
0.700
2.000
0.200
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
198
-------
PN Profile Specialion Report - continued (profile 20401}
Total Particulate Matter
Species
CAS Number
7440-39-3
7440-45-1
, 7439-97-6
7439-92-1
Nun
56
58
80
82
201
202
203
204
Sym
Ba
Ce
Hg
Pb
DC
EC
S04
N03
0-2
Xut
<
<
<
50.000
NA
NA
7.530
NA
.5
un
unc
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
2.5-
Xwt
<
<
<
50.000
NA
NA
7.530
NA
10 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
%Ht
<
<
<
50.000
NA
HA
7.530
NA
unc
0.000
0.000
0.000
7.738
0.000
0.000
1.165
0.000
Total
Measured
Xut
<
<
<
50.000
NA
NA
7.530
NA
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 84.850 84.850 84.850 84.850
199
-------
PH Profile Speciation Report
Profile Name Seconary Lead - Sanitary Baghouse
Profile Number 2G402
Data Quality E
Control Device Not Applicable
Reference(s) 62,76
Data Source Data taken from Reference 62. For details, consult Reference
76,
SCC Assignments: 30400499
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.650 0.780
Total Particulote Matter
Species
CAS Nunber
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-'
7726-95-6
7440-17-7
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
TOTALS:
0-2.5
i'.-jr S-,- Xut
11
12
13
14
15
17
19
20
22
23
24
&
26
27
28
29
30
33
T/
35
37
38
46
47
48
49
50
51
56
80
82
Us
Mg
Al
Si
P
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Co
Hi
Cu
Zn
As
c"
Br
Rb
Sr
Pd
Ag
Cd
In
Sn
Sb
Ba
Hg
Pb
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
120
015
150
072
010
380
390
039
011
000
015
031
4.320
0.
0.
0.
0.
Q.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
11.
18.
002
021
120
032
035
003
004
001
004
014
000
010
001
106
840
035
003
500
286
un>C1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
0.120
0.015
0.150
0.072
0.010
0.380
0.390
0.039
0.011
0.000
0.015
0.031
4.320
0.002
0.021
0.120
0.032
0.035
0.005
0.004
0.001
0.004
0.014
0.000
0.010
0.001
0.106
0.840
0.035
0.003
11.500
18.286
«C1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.120
0.015
0.150
0.072
0.010
0.380
0.390
0.039
0.011
0.000
0.015
0.031
4.320
0.002
0.021
0.120
0.032
0.035
0.005
0.004
0.001
0.004
0.014
0.000
0.010
0.001
0.106
0.840
0.035
0.003
11.500
18.286
(0-10)
0.840
Total
unvCU Measured
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Xwt
0.120
0.015
0.150
0.072
0.010
0.380
0.390
0.039
0.011
0.000
0.015
0.031
4.320
0.002
0.021
0.120
0.032
0.035
0.005
0.004
0.001
0.004
0.014
0.000
0.010
0.001
0.106
0.840
0.035
0.003
11.500
18.286
unc
0.024
0.015
0.030
0.014
0.010
0.076
0.120
0.020
0.008
0.000
0.003
0.006
0.864
0.001
0.004
0.024
0.013
0.012
0.002
0.001
0.001
0.003
0.014
0.001
0.010
0.000
0.106
0.168
0.035
0.005
1.200
{1} Estimated / extrapolated.
200
-------
PH profile Speciat ion Report
Profile Name Seconary Lead - Reverberatory Furnace
Profile Number 20403
Data Quality E
Control Device Uncontrolled{1>
Reference(s) 62,76
Data Source Data taken from Reference 62. For details, consult Reference
76.
SCC Assignments: 30400402
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.350 0.390
Total Particulate Natter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
TOTALS:
0-2.5
o^nrb i e»
Nun Sym
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
33
34
35
37
38
46
47
48
49
50
51
56
80
82
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Br
Rb
Sr
Pd
Ag
Cd
In
Sn
Sb
Ba
Hg
Pb
1
0
Xwt
.043
.054
0.323
0
0
2
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
11
23
.398
.215
.118
.312
.301
.688
.005
.005
.118
.033
.946
.002
.022
.269
.172
.355
.050
.290
.022
.027
.280
.022
.645
.000
.065
.893
.807
.108
.400
.988
uiK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
1.043
0.054
0.323
0.398
0.215
2.118
1.312
0.301
0.688
0.005
0.005
0.118
0.033
0.946
0.002
0.022
0.269
0.172
0.355
0.050
0.290
0.022
0.027
0.280
0.022
0.645
0.000
0.065
1.893
0.807
0.108
11.400
23.988
un<2}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
1.043
0.054
0.323
0.398
0.215
2.118
1.312
0.301
0.688
0.005
0.005
0.118
0.033
0.946
0.002
0.022
0.269
0.172
0.355
0.050
0.290
0.022
0.027
0.280
0.022
0.645
0.000
0.065
1.893
0.807
0.108
11.400
23.988
(0-10)
0.400
Total
um<2} Measured
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.obo
0.000
0.000
Xwt
1.043
0.054
0.323
0.398
0.215
2.118
1.312
0.301
0.688
0.005
0.005
0.118
0.033
0.946
0.002
0.022
0.269
0.172
0.355
0.050
0.290
0.022
0.027
0.280
0.022
0.645
0.000
0.065
1.893
0.807
0.108
11.400
23.988
unc{2>
0.209
0.054
0.065
0.080
0.215
0.422
0.262
0.065
0.138
0.005
0.001
0.032
0.007
0.189
0.002
0.022
0.054
0.034
0.071
0.013
0.058
0.043
0.027
0.151
0.022
0.430
0.000
0.409
0.379
0.807
0.043
1.183
======
{1} No control specified: thus, assumed uncontrolled.
{2} Estimated / extrapolated.
201
-------
PH Profile Speciation Report
Profile Name Seconary Lead - Melting
Profile Number 20404
Data Quality E
Pot Fugitives
Control Device UncontrolledCD
Reference(s) 62,76
Data Source Data taken from Reference 62. For details, consult Reference
76.
SCC Assignments: 30400413
Hass Fraction Data - Size Interval (in) : (0-2.5) (0-6)
Mass Fraction : 0.650 0.780
Total Participate Hatter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
dfJCV ICd
Hum Sym
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
33
34
35
37
38
46
47
48
49
50
51
56
80
82
Na
Hg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Br
Rb
Sr
Pd
Ag
Cd
In
Sn
Sb
Ba
Hg
Pb
0-2.5
Xwt
0
0
T
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
10
.559
.353
.529
.412
.112
.230
.506
.065
.218
.039
.002
.006
.010
.329
.001
.018
.129
.055
.212
.003
.007
.012
.012
.088
.001
.035
.001
.171
.294
.588
.024
.000
um<2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000*
0.000
0.000
0.000
0.000
2.5-10
Xwt
0.559
0.353
1.529
1.412
0.112
0.230
0.506
0.065
0.218
0.039
0.002
0.006
0.010
0.329
0.001
0.018
0.129
0.055
0.212
0.003
0.007
0.012
0.012
0.088
0.001
0.035
0.001
0.171
1.294
0.588
0.024
10.000
um<2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.559
0.353
1.529
1.412
0.112
0.230
0.506
0.065
0.218
0.039
0.002
0.006
0.010
0.329
0.001
0.018
0.129
0.055
0.212
0.003
0.007
0.012
0.012
0.088
0.001
0.035
0.001
0.171
1.294
0.588
0.024
10.000
um<2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.840
Total
Measured
Xwt
0.559
0.353
1.529
1.412
0.112
0.230
0.506
0.065
0.218
0.039
0.002
0.006
0.010
0.329
0.001
0.018
0.129
0.055
0.212
0.003
0.007
0.012
0.012
0.088
0.001
0.035
0.001
0.171
1.294
0.588
0.024
10.000
unct2>
0.112
0.077
0.306
0.282
0.112
0.230
0.101
0.029
0.047
0.014
0.001
0.012
0.002
0.066
0.001
0.012
0.026
0.011
0.042
0.003
0.001
0.012
0.012
0.071
0.001
0.029
0.001
0.171
0.259
0.588
0.024
1.177
TOTALS: 18.021 18.021 18.021 18.021
C1> No control specified: thus, assured uncontrolled.
{2} Estimated / extrapolated.
202
-------
PH Profile Speciation Report
Profile Name Seconary Lead - Melting
Profile Number 20405
Data Quality E
Pot Stack
Control Device Baghouse
RefereneeCs) 62,76
Data Source Data taken from Reference 62. For details, consult Reference
76.
SCC Assignments: 30400401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6) (0-10)
Mass Fraction : 0.710 O.S40 0.890
Total Participate Matter
Species
CAS Number Hum
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
TOTALS:
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
33
34
35
37
38
46
47
48
49
50
51
56
80
82
Sym
Ne
Mi
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr ,
Mn
Fe
Co
Hi
Cu
Zn
As
Se
Br
Kb
Sr
Pd
Ag
Cd
In
Sn
Sb
Ba
Hg
Pb
0-2.5 unK1>
Xwt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
b
0
H
13
.205
.063
.243
.234
.097
.167
.365
.083
.039
.017
.000
.007
.002
.175
.000
.019
.020
.034
.036
.001
.032
.005
.005
.010
.001
.004
.000
.073
.080
.122
.020
.100
.259
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
%ut
0.205
0.063
0.243
0.234
0.097
0.167
0.365
0.083
0.039
0.017
0.000
0.007
0.002
0.175
0.000
0.019
0.020
0.034
0.036
0.001
0.032
0.005
0.005
0.010
0.001
0.004
0.000
0.073
0.08C
0.122
0.020
11.100
13.259
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.205
0.063
0.243
0.234
0.097
0.167
0.365
0.083
0.039
0.017
0.000
0.007
0.002
0.175
0.000
0.019
0.020
0.034
0.036
0.001
0.032
0.005
0.005
0.010
0.001
0.004
0.000
0.073
0.080
0.122
0.020
11.100
13.259
urnm
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.OOQ
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xwt
0.205
0.063
0.243
0.234
0.097
0.167
0.365
0.083
0.039
0.017
0.000
0.007
0.002
0.175
0.000
0.019
0.020
0.034
0.036
0.001
0.032
0.005
0.005
0.010
0.001
0.004
0.000
0.073
0.080
0.122
0.020
11.100
13.259
unc
0.041
0.027
0.049
0.047
0.097
0.167
0.073
0.017
0.020
0.006
0.000
0.005
0.000
0.035
0.000
0.006
0.005
0.007
0.007
0.001
0.006
0.005
O.Q05
0.034
0.001
0.004
0.000
0.097
0.016
0.122
0.015
1.120
C1> Estimated / extrapolated.
203
-------
PH Profile Speeiation Report
Profile Name
Profile Number
Data Quality
Seconary Lead - Yard Dust
20406
I
Control Device Not Applicable
Reference(s) 62,77
Data Source Data taken from Reference 62. For details, consult Reference
77.
SCO Assignments: 30400499
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Kass Fraction : 0.350 0.390
Total Particulate Hatter -
Species
CAS Hunter Hum
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
11
13
14
15
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Ha
Al
Si
P
cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
y
Zr
No
Pd
A3
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xut
0
1
2
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
2
0
0
0
66
79
.420
.866
.971
.909
.610
.406
.122
.041
.017
.021
.020
.458
.090
.151
.150
.042
.000
.052
.014
.008
.020
.041
.063
.097
.044
.064
.650
.000
.186
.600
.020
.088
.016
.630
.887
.5 urn
unc
0.084
0.373
0.549
0.183
0.120
0.018
0.054
0.008
0.003
0.004
0.004
0.092
0.018
0.030
0.030
0.042
0.200
0.052
0.003
0.008
0.020
0.041
0.063
0.019
0.044
0.016
0.620
0.000
0.186
0.520
0.010
0.088
0.016
6.663
2.5-10
%wt
0.533
1.466
2.367
0.681
0.872
0.500
0.124
0.009
0.005
0.023
0.020
0.408
0.090
0.156
0.116
0.041
0.397
0.053
0.010
0.008
0.014
0.041
0.063
0.121
0.163
0.039
0.527
0.000
0.347
1.055
0.015
0.046
0.014
68.091
78.455
umC1> 0-1Q umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
%wt
0.434
1.816
2.896
0.880
0.643
0.418
0.122
0.037
0.016
0.021
0.020
0.452
0.090
0.152
0.151
0.041
0.925
0.052
0.013
0.008
0.019
0.041
0.063
0.100
0.059
0.061
0.635
0.000
0.206
2.407
0.019
0.083
0.015
66.813
79.708
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.400
Total
Measured
Xwt
0.533
1.466
2.367
0.681
0.872
0.500
0.124
0.009
0.005
0.023
0.020
0.408
0.090
0.156
0.156
0.041
0.397
0.053
0.010
0.008
0.014
0.041
0.063
0.121
0.163
0.039
0.527
0.000
0.347
1.055
0.015
0.046
0.014
68.091
78.455
unc
0.091
0.229
0.370
0.105
0.151
0.085
0.037
0.002
0.002
0.004
0.003
0.065
0.015
0.026
0.026
0.034
0.056
0.044
0.002
0.006
0.016
0.034
0.052
0.021
0.154
0.026
0.411
0.000
0.311
0.149
0.005
0.033
0.012
6.809
C1> Estimated / extrapolated.
€2} Calculated based on methodology described in the Air Emissions Species Manual,
Volume II. £04
-------
PM Profile Specieticn Report
Profile Name Zinc Oxide Kiln
Profile Number 20501
Data Quality C/E
Control Device Unspecified
Reference(s) 43
Data Source Sample collected at duct
SCC Assignments 30400899
Mass Fraction Data - Size Interval (um)
Mass Fraction
Total Particulate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
46
47
48
49
50
51
56
Sym
Be
B
F
Na
MS
Al
Si
P
S
Cl
1C
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Pd
Ag
Cd
In
Sn
Sb
Ba
0-2
Xwt
0
0
0
3
0
0
0
0
0
0
0
0
0
0
63
1
0
0
0
0
0
0
0
0
NA
NA
NA
NA
NA
.423
.574
.188
.290
.427
.615
.231
<
.031
.011
.018
.021
.188
<
.106
.254
.182
<
<
.184
.377
.120
<
<
.055
.036
.080
.033
.424
.391
<
.5 um
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
discharge with
: (0-2.5)
: 0.180
2.5-
Xwt
NA
NA
NA
MA
NA
0.423
0.574
0.183
3.290
0.427
0.615
0.231
<
0.031
0.011
0.018
0.021
0.188
<
0.106
0.254
63.182
<
<
1.184
0.377
0.120
<
<
0.055
0.036
0.080
0.033
0.424
0.391
<
10 um
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
low-volume sampler.
(0-6)
0.370
0-10 um
Xwt
NA
NA
NA
NA
NA
0.423
0.574
0.188
3.290
0.427
0.615
0.231
<
0.031
0.011
0.018
0.021
0.188
<
0.106
0.254
63.182
<
<
1.184
0.377
0.120
<
<
0.055
0.036
0.080
0.033
0.424
0.391
<
unc
0.000
0.000
0.000
0.000
0.000
0.029
0.039
0.013
0.223
0.029
0.042
0.016
0.000
0.002
0.001
0.001
0.001
0.013
0.000
0.007
0.017
4.292
0.000
0.000
0.080
0.026
0.008
0.000
0.000
0.004
0.002
0.005
0.002
0.029
0.027
0.000
(0-10)
0.530
Total
Measured
Xwt
NA
NA
NA
NA
NA
0.423
0.574
0.188
3.290
0.427
0.615
0.231
<
0.031
0.011
0.018
0.021
0.188
<
0.106
0.254
63.182
<
<
1.184
0.377
0.120
<
<
0.055
0.036
0.080
0.033
0.424
0.391
<
unc
0.000
0.000
0.000
0.000
0.000
0.045
0.057
0.019
0.516
0.057
0.061
0.023
0.000
0.000
0.000
0.000
0.000
0.019
0.000
0.011
0.025
6.318
0.000
0.000
0.118
0.038
0.012
0.000
0.000
0.011
0.000
0.018
0.016
0.042
0.053
0.078
205
-------
PM Profile Speciation Report - continued (profile 20501)
Total Particulate Matter -
0-2.5 urn 2.5-10 un 0-10 un
Xwt unc Xut unc ' %wt unc
Total
Measured
Species
CAS Number Hum Syrn
Xwt
unc
7440-41-1 58
7439-97-6 80
7439-92-1 82
?ni
202
203
204
TOTALS:
Ce
Hg
Pb
nr
EC
S04
N03
<
0.064
11.664
NA
NA
NA
NA
83.987
============ ===============sqa===i
0.
0.
0.
0.
0.
0.
0.
zsssz
000
000
000
000
000
000
000
«
0.064
11.664
NA
NA
NA
NA
83.987
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<
0.064
11.664
NA
NA
NA
NA
83.987
0
.000
<
0.004 0.064
0
0
0
0
0
.792 11
.000
.000
.000
.000
83
.664
NA
NA
NA
NA
.987
0.000
0.000
1.166
0.000
0.000
0.000
0.000
========a========is==s===========================
206
-------
Profile SpecialIon Report •
Profile Name
Profile Number
Data Quality
Antimony Oxide Plant
20502
B/D
Antimony Roast ing
Control Device Wet Scrubber
Reference(s) 52
Data Source Samples downstream from water scrubber system, collected
with dilution sampler. One representative sample from
group nine.
SCC Assignments: 30400299
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
Sym
Be
B
F
Na
Hi
Al
Si
P
S
Cl
K
Cs
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
0
0
0
1
0
0
0
0
0
0
0
0
0
q
0
0
0
0
0
0
0
0
0
0
76
0-2.5 urn
ftrt
NA
NA
NA
NA
NA
.000
.000
.000
.334
.754
.000
<
<
.000
.000
.005
.006
.108
<
.015
.011
.070
.005
<
.078
.008
.000
.000
.000
.000
,000
.000
.000
.651
une
0.000
0.000
0.000
0.000
0.000
0.148
0.148
0.037
0.068
0.042
0.538
9.197
0.000
0.462
0.004
0.001
0.001
0.006
0.000
0.001
0.001
0.001
0.001
0.000
0.005
0.001
0.008
0.001
0.001
0.007
0.007
0.011
0.027
3.630
: (0-2.5)
: 0.180
2.5-10 un
Xwt
NA
NA
NA
NA
NA
0.000
0.000
0.000
1.493
0,786
0.000
<
<
0.000
0.000
0.080
0.008
0.125
<
0.010
0.005
0.012
0.004
<
0.090
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
87.726
une
0.000
0.000
0.000
0.000
0.000
0.281
0.281
0.066
0.146
0.084
0.935
16.100
0.000
0.805
0.007
0.004
0.004
0.016
0.000
0.004
0.004
0.003
0.003
0.000
0.013
0.003
0.017
0.005
0.007
0.029
0.029
0.039
0.355
7.138
CO-6)
0.370
0-10 urn
Xut
NE
NE
NE
NE
NE
0.000
0.000
0.000
1.439
0.775
0.000
HE
NE
0.000
0.000
0.055
0.007
0.119
NE
0.012
0.007
0.032
0.004
NE
0.086
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
83.965
une
0.000
0.000
0.000
0.000
0.000
0.108
0.108
0,026
0.111
0.061
0.366
0.000
0.000
0.315
0.003
0.004
0.001
0.010
0.000
0.002
0.002
0,004
0.001
0.000
0.007
0.001
0.006
0.002
0.002
0.010
0.010
0.014
0.121
6,221
(0-10)
0.530
Total
Measured
Xwt
NE
NE
NE
NE
NE
0.000
0.000
0,000
1.439
0.775
0.000
NE
NE
0.000
0.000
0.055
0.007
0.119
NE
0.012
0.007
0.032
0.004
NE
0.086
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
83.965
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
207
-------
PM Prof!le Speefation Report • continued (profit* 20502)
Total Participate Hatter -
0-2.5 urn 2.5-10 urn 0-10 urn
Total
Measured
CAS Number Hum Sym
•Xut
unc
Xwt
ync
Xut
une
%ut
unc
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
ssSKSssssssssw!
55
56
58
80
82
201
202
203
204
:=====:
Cs
Ba
Ce
Hg
Pb
OC
EC
S04
N03
= = = = :
<
0.000
<
0.000
0.128
NA
NA
NA
NA
79.173
===========
0.000
0.039
0.000
0.002
0.007
0.000
0.000
0.000
0.000
========
<
0.000
<
0.028
0.103
NA
NA
NA
NA
90.478
========
0.000
0.212
0.000
0.007
0.018
0.000
0.000
0.000
0.000
=======
0.
0.
0.
86.
====
NE
000
NE
018
111
NE
NE
NE
NE
638
;====
0.000
0.073
0.000
0.003
0.010
0.000
0.000
0.000
0.000
=======
NE
0.000
NE
0.018
0.111
NE
NE
NE
NE
86.638
========
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: = =====
208
-------
PH Profit* Speetation Report
Profile Name
Profile Nimber
Data Duality
Antimony Oxide Plant - Antimony Roasting
20503
Control Device
Reference(s)
Data Source
UncontrolledC1>
62,63
Data taken from Reference 62. For details, consult Reference
63.
SCC Assignments: 30400299
Mass Fraction Data -
Size Interval (urn) :
Mass Fraction :
(0-2.5)
0.180
{0-6J
0.370
(0-10)
0.530
Total Participate Matter -
Total
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-32-6
7440-62-2
7439-96-5
7440-02-0
7726-95-6
7440-31-5
7440-36-0
7439-92-1
Species
Hum Sym
13
14
16
17
22
23
25
28
35
50
51
82
201
202
203
Al
Si
S
Cl
Ti
V
Mn
Ni
Br
Sn
Sb
Pb
OC
EC
S04
0-2
%wt
0
1
0
0
0
0
0
0
74
0
1
0
0
.030
NR
.280
.011
NR
.001
.001
.014
.022
.530
.000
.170
,000
.099
.052
.5 urn
unc
0.053
0.000
0.070
0.018
0.000
0.000
0.000
0.001
0.001
0.030
4.000
0.040
0.600
0.014
0.012
2.5-10 urn
%ut
0.330
0.750
1.300
0.990
1.000
0.002
0.001
0.012
0.028
NR
76.000
0.110
4.800
0.230
NR
unc
0.500
0.810
0.100
0.130
0.600
0.003
0.001
0.003
0.001
0.000
13.000
0.020
1.600
0.280
0.000
0-10
%wt
0.228
NE
1.293
0.658
NE
0.001
0.001
0.013
0.026
NE
75.321
0.130
3.509
0.186
NE
unC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured£3>
Xwt
0.228
NE
1.293
0.658
NE
0.001
0.001
0.013
0.026
ME
75.321
0.130
3.509
0.186
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
TOTALS:
77.210
85.553
81.366
81.366
•C1> No control specified: thus, assumed uncontrolled.
{2} Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
C3> Estimated / extrapolated.
209
-------
PH Profile Speclation Report
Profile Name Cast Iron Induction Furnace
Profile Hunter 38201
Data Quality C/E
Control Device Unspecified
RefereneeCs) 47
Data Source Mean of 3 tests during, melting, refining, and discharge.
SCC Assignments 30400303
Mass Fraction Data - Sire Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.820 0.890
Total Particulate Hatter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31 -5
7440-36-0
7440-46-2
7440-39-3
^)JCI* 1 d»»
Hum Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Ge
B
f
Na
Mg
At
SI
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Mi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
0-2
Xut
2
1
2
2
, 3
1
NA
NA
NA
.000
<
.300
.100
<
<
.500
.200
.500
<
0.480
0
0
1
. 5
0
0
0
2
0
.006
.024
.700
.700
.002
.098
.120
.900
<
<
.012
<
0.021
1 0
0
.011
<
<
<
.012
<
<
<
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
q.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
%ut
NA
NA
NA
2.000
<
1.300
2.100
<
<
2.500
3.200
1.500
<
0.480
0.006
0.024
1.700
5.700
0.002
0.098
0.120
2.900
<
<
0.012
<
0.021
0.011
<
<
<
0.012
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NA
NA
NA
2.000
<
1.300
2.100
<
<
2.500
3.200
1.500
<
0.480
0.006
0.024
1.700
5.700
0.002
0.098
0.120
2.900
<
<
0.012
<
0.021
0.011
<
<
<
0.012
<
<
<
<
unc
0.000
0.000
0.000
0.357
0.000
0.232
0.374
0.000
0.000
0.446
0.570
0.267
0.000
0.086
0.001
0.004
0.303
1.016
0.000
0.017
0.021
0.517
0.000
0.000
0.002
0.000
0.004
0.002
0.000
0.000
0.000
0.002
0.000
0.000
0.000
0.000
tO-10)
0.920
Total
Measured
Xwt
NA
NA
NA
2.000
<
1.300
2.100
<
<
2.500
3.200
1.500
<
0.480
0.006
0.024
1.700
5.700
0.002
0.098
0.120
2.900
<
<
0.012
<
0.021
0.011
<
<
<
0.012
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
210
-------
PH Profile Speeiation Report - continued Cprofile 28201)
Total Partieulate Natter
CAS Number
7440-45-1
7439-97-6
7439-92-1
TOTALS:
Hum Syrn
58
80
82
201
202
203
204
Ce
Hs
Pb
oc
1C
S04
N03
' 0-2
Swt
<
<
0.540
NA
NA
NA
NA
24.226
.5
0
0
0
0
0
0
0
urn
unc
.000
.000
.000
.000
.000
.000
.000
2.5-10 urn
Xwt
<
<
0.540
NA
NA
NA
HA
24.226
unc
0.000
.0.000
0.000
0.000
0.000
0.000
0.000
.=S3BSSiBss=
0-
Xwt
<
<
0.540
NA
NA
NA
NA
24.226
10 urn
unc
0.000
0.000
0.096
0.000
0.000
0.000
0.000
Total
Measured
Xut
<
<
0.540
NA
NA
NA
NA
24.226
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
211
-------
PH Profile Specfation Report
Profile Name Cast Iron Cupola
Profile Nuiber 28202
Data Quality C/D
Control Device Unspecified
Reference(s) *»i
Data Source Mean of 5 tests. XRF and INNA analysis
coke, arid limestone rau materials.
SCC Assignments: 30400301
Mass Fraction Data • Size Interval (urn) : CO-2.5)
Hass Fraction : 0.850
Total Particulate Hatter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
0-2
4
5
9
11
12
13
14
15
16
17
•-
Z(i
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Be
B
F
Na
Mg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
t>b
Sr
Zr
AS
Cd
Sn
Sb
Cs
1
T
24
2
0
3
1
0
0
0
4
15
0
0
0
0
0
0
0
0
NA
NA
NA
.300
<
.100
.000
<
.300
.890
.000
.000
<
.060
.009
.052
.500
.000
.004
.035
.260
.830
<
<
.013
.002
.009
.022
<
<
<
<
<
0.370
<
.5 urn
unc
0.000
0.000
0.000
6.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
Xwt
NA
NA
NA
1.300
<
1.100
24.000
<
2.300
0.890
3.000
1.000
<
0.060
0.009
0.052
4.500
15.000
0.004
0.035
0.260
0.830
<
<
0.013
0.002
0.009
0.022
<
<
<
«'
<
0.370
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
. Scrap, pig iron,
CO-6)
0.920
0-10 tin
Xwt
NA
NA
NA
1.300
<
1.100
24.000
<
2.300
0.890
3.000
1.000
<
0.060
0.009
0.052
4.500
15.000
0.004
0.035
0.260
0.830
<
<
0.013
0.002
0.009
0.022
<
<
<
<
<
0.370
<
unc
0.000
0.000
0.000
0.238
0.000
0.201
4.387
0.000
0.420
0.163
0.54B
0.183
0.000
0.011
0.002
0.010
0.823
2.742
0.001
0.006
0.048
0.152
0.000
0.000
0.002
0.000
0.002
0.004
0.000
0.000
0.000
0.000
0.000
0.068
0.000
CO-10)
0.930
Total
Measured
Xut
NA
NA
NA
1.300
<
1.100
24.000
<
2.300
0.890
3.000
1.000
<
0.060
0.009
0.052
4.500
15.000
0.004
0.035
0.260
0.830
<
<
0.013
0.002
0.009
0.022
<
<
<
<
<
0.370
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
212
-------
PH Profile Speciation Report - continued (profile 28202)
Total Partfculate Matter -
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Nun Sym
56
58
80
82
201
202
203
204
TOTALS:
Be
Ce
Hg
Pb
OC
1C
S04
N03
0-2.5 urn
%ut
<
<
<
0.230
NA
NA
NA
NA
54.986
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
<
- <
<
0.230
NA
NA
NA
NA
54.986
urn
unc
0.
0.
0.
0.
0.
0.
0.
0.
000
000
000
000
000
000
000
000
0-10 urn
Xut
<
<
<
0.230
NA
NA
NA
NA
54.986
unc
0.000
0.000
0.000
0.042
0.000
0.000
0.000
0.000
Total
Measured
XHt
<
<
<
0.230
NA
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
54.986
213
-------
PM Proffie Speciation Report
Profile Kama .
Profile Number
Data Quality
Steel Electric Arc Furnace
28305
C/D
Control Device
ReferenceCs)
Data Source
Baghouse
46
Sampled With o 2-stage virtual impactor with a Method 5
heated probe. No dilution air. Analysis by XRF, IHNA,
1C, and carbon oxidation. Average of 2 baghouse samples.
SCC Assignments: 30400701
Mass Fraction Data - Size Interval (un)
Mass Fraction
Total Particulate Hatter
Species
CAS Nmfcer Hum Sym
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
39
40
42
46
47
Be
B
F
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
0-2.5
Xut
1
6
.0
5
1
1
0
6
0
0
2
8
32
0
0
1
0
0
0
NA
NA
NA
.260
.500
.650
.000
<
.960
.850
.920
.200
<
.200
.060
.100
.700
.000
<
.700
.280
.200
<
<
<
<
<
<
<
.009
<
.039
.000
<
umCU
unc
0.000
0.000
0.500
0.480
0.710
0.160
0.210
0.000
0.070
0.780
0.070
0.570
0.000
0.020
0.010
1.400
0.900
3.000
0.000
0.070
0.030
0.120
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
0.000
0.021
0.019
0.000
i CO-2.5J
: 0.750
2.5-10
Xut
NA
NA
NA
1.260
6.500
0.650
5.000
<
1.950
1.850
0.920
6.200
<
0.200
0.060
2.100
8.700
32.000
<
0.700
0.280
1.200
<
<
<
<
<
<
<
0.007
<
0.021
0.007
*
umC1>
unc
0.000
0.000
0.500
0.480
0.710
0.160
0.210
0.000
0.070
0.780
0.070
0.570
0.000
0.020
0.010
1.400
0.900
3.000
0.000
0.070
0.030
0.120
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.004
0.004
0.000
(0-6)
0.760
0-10
%ut
NE
NE
NE
1.260
6.500
0.650
5.000
NE
1.960
1.850
0.920
6.200
NE
0.200
0.060
2.100
8.700
32.000
NE
0.700
0.280
1.200
NE
NE
NE
NE
NE
NE
NE
0.008
NE
0.028
0.004
NE
uiK2>
unc
0.000
0.000
0.000
0.696
1.579
0.251
1.003
0.000
0.388
1.119
0.201
1.422
0.000
0.047
0.018
1.946
2.073
7.383
0.000
0.165
0.068
0.283
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
0.000
0.010
0.008
0.000
CO-10)
0.780
Total
MeasuredC3>
Xwt
NE
NE
NE
1.260
6,500
0.650
5.000
NE
1.960
1.850
0.920
6.200
NE
0.200
0.060
2.100
8.700
32.000
NE
0.700
0.280
1.200
NE
NE
NE
NE
NE
NE
NE
0.009
NE
0.034
0.002
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.000
0.016
0.014
0.000
214
-------
PH Profile Speciation Report - continued (profile 28305)
Total Participate Matter -
0-2.5 uroC1> 2.5-10 unCU 0-10 umC2>
Total
tteasured€3>
Species
CAS Number Hum Sym %wt unc %wt unc Xwt unc
%ut
unc
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7439-97-6
7439-92-1
TOTALS:
€1} Data as
48
49
50
51
55
56
57
58
80
82
201
202
203
204
Cd
In
Sn
sb
Cs
Ba
La
ce
Ha
Pb
oc
EC
S04
N03
reported in
<2> Calculated based on
{3} Extrapolated
0.
0.
0.
2.
72.
<•
029
<
<
<
<
000
<
<
760
NA
NA
500
NA
917
Receptor
0.000
0.039
0.000
0.000
0.000
0.000
0.337
0.000
0.000
0.070
0.000
0.000
1.300
1.400
Model
<
0.011
<
<
<
<
0.000
<
<
0.760
NA
NA
2,500
NA
72.876
0.000
0.008
0.000
0,000
0.000
0.000
0.067
0.000
0.000
0.070
0.000
0.000
1.300
1.400
NE
0.018
NE
NE
NE
NE
0.000
NE
NE
0.760
NE
NE
2.500
NE
72.898
0.000
0.016
0.000
0.000
0.000
0.000
0.138
0.000
0.000
0.174
0.000
0.000
1.832
0.000
NE
0.024
NE
NE
NE
NE
0.000
NE
NE
0.760
NE
NE
2.500
NE
72.909
0.000
0.029
0.000
0.000
0.000
0.000
0.250
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Source Composition Library.
a methodology described
in Source Composition
Library
.
/ Estimated.
215
-------
PH Profile Speciatiofi Report-
Profile Name
Profile Nuntoer
Data Quality
Steel Foundry - Steel Meat Treating (Salt Quench)
28601
C/i
Control Device
Reference(s)
Data Source
Uncontrolled
10
SASS train with heated Method 5 probe, 3 cyclones, at 400
deg F. analyzed by XRF. Si, P. and S non-quantitative.
Average of 2 tests from baghouse outlet.
SCC Assignments: 30400704
Mass Fraction Data * Size Interval (urn)
Mass Fraction
Total Particulate
Hatter
CAS Number
7440-41-7
7440-42-8
77S2-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
a^x*f ll-»
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
Be
B
F
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ce
As'
Se
Br
Rb
Sr
2r
*S
Cd
Sn
Sb
: CO-2.5)
: 0.780
CO-6)
0.910
CO- 10)
0.940
Total
0-2
Xut
MA
NA
NA
MR
NR
NR
<
<
<
30.000
4.000
0.550
<
<
<
0.550
<
9.000
<
2.000
0.050
0.050
<
<
<
<
0.050
<
<
<
<
0.050
<
<
.5 urn
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
%ut
NA
NA
NA
NR
NR
NR
<
<
<
30.000
4.000
0.550
<
<
<
0.550
<
9.000
<
2.000
0.050
0.050
<
<
<
<
0.050
<
<
<
<
0.050
<
<
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
unc
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0-10 urn
Xut
NA
NA
NA
NR
NR
NR
<
<
<
30.000
4.000
0.550
<
<
<
0.550
<
9.000
<
2.000
0.050
0.050
<
<
< •
<
0.050
<
<
<
<
0.050
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.979
0.664
0.091
0.000
0.000
0.000
0.091
0.000
1.494
0.000
0.332
0.008
0.008
0.000
0.000
0.000
0.000
0.008
0.000
0.000
0.000
0.000
0.008
0.000
0.000
Measured
%Mt
NA
NA
HA
NR
NR
NR
<
<
<
30.000
4.000
0.550
<
<
<
0.550
<
9.000
<
2.000
0.050
0.050
<
<
<
<
0.050
<
<
<
<
0.050
<
<
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
216
-------
PM Profile Speciation Report - continued (profile 28601)
Total Participate Matter -
CAS Number
7440-46-2
7440-39-3-
7440-45-1
7439-97-6
7439-92-1
species
Nun Sym
55
56
58
80
82
201
202
203
204
Cs
Ba
Ce
Kg
Pb
oc
EC
SQ4
N03
0-2.5 m
•Xut
0
0
&
32
<
.550
<
<
.050
.000
MA
.000
0.550
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
<
0.550
<
<
0.050
6.000
HA
32.000
0.550
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
<
0.550
<
<
0.050
6.000
NA
32.000
0.550
unc
0.000
0.091
0.000
0.000
0.008
0.996
0.000
5.311
0.091
Total
Measured
Xwt
«
0.550
<
<
0.050
6.000
NA
32.000
0.550
unc
0.000
0.000
0.000
0. 000
0.000
0.000
0.000
0.000
0.000
TOTALS:
85.450
85.450
8S.450
85.450
217
-------
PH Profile Speciation Report
Profile Dame Copper
Profile Number 29201
Data Quality C/E
Oxide
Ki In
Control Device Wet Scrubber
Reference(s) 43
Data Source Sampled with high-volume sampler from plume level at top of
stack.
SCC Assignments: 30499999
Mass Fraction Data - Size Interval
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.100
0.005
0.000
0.002
0.000
0.000
2.5-10
%Mt
NA
NA
NA
NA
NA
0.347
0.362
0.193
4.488
2.116
0.211
0.750
<
0.018
<
0.014
<
0.100
<
0.203
54.151
0.127
<
<
<
<
0.018
<
0.011
0.000
0.110
0.011
0.000
0.088
<
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.200
0.010
0.000
0.030
0.000
0.000
0-10
%ut
NA
NA
NA
NA
NA
0.347
0.362
0.193
4.488
2.116
0.211
0.750
<
0.018
<
0.014
<
0.100
<
0.203
54.151
0.127
<
<
<
<
0.018
<
0.011
0.000
0.094
0.011
0.010
0.088
<
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.024
0.025
0.013
0.305
0.144
0.014
0.051
0.000
0.001
0.000
0.001
0.000
0.007
0.000
0.014
3.678
0.009
0.000
0.000
0.000
0.000
0.001
0.000
0.001
0.193
0.021
0.001
0.027
0.006
0.000
0.530
Total
Measured{2>
%wt
NA
NA
NA
NA
NA
0.347
0.362
0.193
4.488
2.116
0.211
0.750
<
0.018
<
0.014
<
0.100
<
0.203
54.151
0.127
<
<
<
<
0.018
<
0.011
0.000
0.094
0.011
0.010
0.088
<
unc
0.000
0.000
0.000
0.000
0.000
0.035
0.036
0.019
0.449
0.212
0.021
0.100
0.000
0.000
0.000
0.000
0.000
0.100
0.000
0.020
5.415
0.039
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
0.000
218
-------
PK Profile Speciat ion Report - continued (profile 29201)
Total Participate Matter -
0-2.5 umC1>
CAS Number
7440-31-5
7440-36-0
13494-80-9
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
7440-69-9
TOTALS!
Hum Sym
50
51
52
55
56
58
80
82
83
201
202
203
204
CD Extrapolated
{2} Data as
Sn
Sb
Te
Cs
Ba
Ce
KS
Pb
Bi
DC
EC
S04
N03
Xwt
0.
0.
0.
0.
64.
<
<
090
<
013
<
<
234
370
NA
NA
NA
NA
018
unc
0.000
0.000
0.022
0.000
0.000
0.000
0.000
0.000
0.100
0.000
0.000
0.000
0.000
/ Estimated.
reported
in Receptor
Model
2.5-10
%Ht
<
<
0.130
<
0.013
<
<
0.234
NR
NA
NA
NA
NA
63.695
umTO
0-10
unc Xwt
0.000
0.000
0.010 0
0.000
<
<
.095
<
0.000 0.013
0.000
0.000
0.000 0
0.000 0
0.000
0.000
0.000
0.000
63
Source Composition
<
<.
.234
.322
MA
NA
NA
NA
.976
umC1>
unc
0.000
0.000
0.028
0.000
0.001
0.000
0.000
0.016
0.088
0.000
0.000
0.000
0.000
Total
MeasuredC2>
Xwt
<
<
0.095
<
0.013
<
<
0.234
0.322
NA
NA
NA
NA
63.976
unc
0.018
0.000
0.000
0.000
0.083
0.000
0.000
0.023
0.000
0.000
0.000
0.000
0.000
Library.
219
-------
PH Profile Speeiation Report
Profile Name : Secondary Copper,PyrometaI - Cathode Charge
Profile Number : 29501
Data Quality : E
Control Device : Uncontroll«dC1>
ReferenceCs) : 62,75
Data Source : Data taken from Reference 62. For details, consult Reference
75.
SCC Assignments: 30400215
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Particulate Hatter -
CAS Number
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
e|^5fc»ii;»
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
TOTALS:
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Ha
Pb
C1} No control specified:
C2J Estimated /
0-2.
•Xwt
0.000
0.000
0.000
0.187
0.373
0.152
0.273
0.000
0.000
0.000
0.007
0.176
0.000
15.435
1.672
0.000
0.015
0.000
0.037
0.001
q.ooo
0.000
0.004
0.046
0.000
0.000
0.000
0.000
0.349
0.000
0.000
0.000
, 0.000
2.521
21.248
thus.
extrapolated.
5 um{2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
assumed
2
0
0
0
0
0
0
0
0
0
0
0
0
0
15
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2
21
CO-2.5)
0.820
.5-10
Xwt
.000
.000
.000
.187
.373
.152
.273
.000
.000
.000
.007
.176
.000
.435
.672
.000
.015
.000
.037
.001
.000
.000
.004
.046
.000
.000
.000
.000
.349
.000
.000
.000
.000
.521
.248
uiK2}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.890
0-10 uiK2>
Xwt
0.000
0.000
0.000
0.187
0.373
0.152
0.273
0.000
0.000
0.000
0.007
0.176
0.000
15.435
1.672
0.000
0.015
0.000
0.037
0.001
0.000
0.000
0.004
0.046
0.000
0.000
0.000
0.000
0.349
0.000
0.000
0.000
0.000
2.521
21 .248
uncontrolled.
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.920
Total
Measured
Xwt
0.000
0.000
0.000
0.187
0.373
0.152
0.273
0.000
0.000
0.000
0.007
0.176
0.000
15.435
1.672
0.000
0.015
0.000
0.037
0.001
0.000
0.000
0.004
0.046
0.000
0.000
0.000
0.000
0.349
0.000
0.000
0.000
0.000
2.521
unc
0.076
0.152
0.030
0.182
0.075
0.061
0.076
0.008
0.005
0.003
0.002
0.035
0.015
3.087
0.334
0.015
0.142
0.008
0.007
0.002
0.003
0.010
0.008
0.015
0.008
0.012
0.030
0.015
0.070
0.015
0.076
0.122
0.008
0.504
21.248
220
-------
PH Profile Speciat1 on Report
Profile Name Secondary Copper Pyrometal * Regular Charge
Profile Nuntoer 29502
Data duality E
Control Device UncontrolledC1>
Referenee(s) 62,75
Data Source Data taken from Reference 62. For details, consult Reference
75-
SCC Ass iorments: 30400214
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.820 0.890
Total Partieulate Matter -
Species
CAS Number
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Hi
Cu
Zn
Sa
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Be
La
Hg
Pb
0
0
0
0
2
0
0
0
0
0
0
0
0
18
2
0
0
0
0
0
0
0
0
0
0
0
0
Q
0
0
0
0
0
7
33
0-2.5
Xwt
.000
.000
.000
.348
.004
.320
.594
.000
.000
.000
.000
.312
.093
.755
.745
.027
.135
.157
.017
.000
.000
.000
.000
.000
.000
.000
.000
.000
.532
.000
.000
.000
.000
.159
.198
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
0.000
0.000
0.000
0.348
2.004
0.320
0.594
0.000
0.000
0.000
0.000
0.312
0.093
18.755
2.745
0.027
0.135
0.157
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.532
0.000
0.000
0.000
0.000
7.159
33.198
unC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.OQO
0-10
Xwt
0.000
0.000
0.000
0.348
2.004
0.320
0.594
0.000
0.000
0.000
0.000
0.312
0.093
18.755
2.745
0.027
0.135
0.157
0.017
0.000
0.000
0.000
. 0.000
0.000
0.000
0.000
0.000
0.000
0.532
0.000
0.000
0.000
0.000
7.159
33.198
um€2>
unc
0.000
0.000
0.000
.0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.920
Total
Measured
Xwt
0.000
0.000
0.000
0.348
2.004
0.320
0.594
0.000
0.000
0.000
0.000
0.312
0.093
18.7S5
2.745
0.027
0.135
0.157
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.532
0.000
0.000
0.000
0.000
7.159
33.198
unc
0.191
0.511
0,064
0.579
0.401
0.064
0.119
0.006
0.006
0.006
0.006
0.062
0.019
3.751
0.549
0.035
0.410
0.031
0.011
0.008
0.009
0.030
0.039
0.032
0.032
0.032
0.057
0.063
0.115
0.097
0.319
0.638
0.010
1.432
•C1> No control specified: thus, assumed uncontrolled.
-------
222
-------
3.6 MINERAL PRODUCTS INDUSTRY
Production and processing of minerals produces participate emissions
frequently of the same composition as the finished product. This is because
most of the processes involved generate dust. These processes include
quarrying, crushing, screening, drying, and storage and handling.
223
-------
224
-------
PH Profile Special ion Report
Profile Name Limestone Oust
Profile Number 21101
Data Quality B/C
Control Device Uncontrolled
Reference(s) 43
Data Source Limestone ground for use
resuspended.
SCC Assignments: 30301005
Mass Fraction Data * Size interval (urn)
Nass Fraction
Total Paniculate Hatter -
CAS Hunter
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
apcv i «?a>
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
38
46
47
48
49
50
51
56
80 •
82
201
202
Be
B
f
Ka
MS
At
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
As
Se
Br
Sr
Pd
Ag
Cd
In
Sn
Sb
Ba
Hg
Pfa
oc
EC
0-2
Xwt
2
6
0
1
0
0
29
0
0
1
Q
0
0
0
0
0
0
NA
NA
NA
NA
NA
.110
.496
.126
.023
.455
.163
,515
.081
<
<
.050
.043
<
.016
.104
.020
<
.027
.024
<
<
.042
<
<
<
<
<
.270
NA
NA
.5 un
une
0.000
0.000
0.000
0.000
0.000
0.211
0.650
0,040
0.104
0.048
0.042
2.951
0.000
0.000
0.000
0.000
0.104
0.000
0.000
0.010
0.013
0.000
0.000
0.000
0.021
0.027
0.045
0.047
0.052
0.095
0.256
0.000
0.027
0.000
0.000
as flux. Samples sieved and
: (0-2.5) (0-6)
; 0.300 0.620
2.5-10 urn
Xwt
NA
NA
NA
NA
NA
1.199
3.394
<
0.663
0.410
0.135
29.723
0.053
<
<
0.028
0.536
<
<
0.020
<
<
<
0.018
<
<
<
<
<
<
<
<
0.048
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.120
0.339
0.029
0.066
0.041
0.023
2.972
0.000
0.000
0.000
0.000
0.054
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
0.044
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NE
NE
NE
NE
NE
1.521
4.489
NE
0.790
0.426
0.145
29.650
0.063
NE
Ni
0.036
0.715
NE
NE
0.050
NE
NE
Ni
0.020
NE
NE
NE
NE
NE
NE
NE
NE
0.126
NE,
NE
unc
0.000
0.000
0.000
0.000
0.000
0.148
0.448
0.000
0.075
0.038
0.020
2.561
0.000
0.000
0.000
0.000
0.072
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.850
Total
Measured
Xwt
NA
NA
NA
NA
NA
1.067
2.813
<
0.743
0.420
0.091
28.643
0.046
<
<
0.025
0.441
<
<
0.014
<
<
<
0.022
<
<
<
<
<
<
<
<
0.051
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.107
0.281
0.029
0.074
0.042
0.022
2.864
0.000
0.000
0.000
0.000
0.044
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.022
0.000
0.000
0.000
0.000
225
-------
PH Profile Speciation Report - continued (profile 21101)
Total Participate Hatter - '
Total
0-2.5 in 2.5-10 un 0-10 um Measured
Species ............ ....—.....
CAS Nunber Nun Sym Swt unc Xwt unc Xwt unc %ut unc
203 S04 NA 0.000 NA 0.000 NE 0.000 NA 0.000
204 N03 NA 0.000 NA 0.000 NE 0.000 NA 0.000
TOTALS: 41.565 36.227 38.031 34.376
226
-------
Profile Sped at ion Report
Profile Name Coke Dust
Profile Number 21203
Data Quality C/D
Control Device Uncontrolled
ReferenceCs) 43
Data Source Fugitive dust from storage and handling
ground, sieved, and resuspended.
SCC Assignments: 30510104, 30510204, 30510304, 30510404,
Mass Fraction Data - Size Interval (um3 i (0-2.5)
Mass Fraction : 0.150
Total Participate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-S6-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
0^Cb 1 CO
Hum Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Be
B
F
Na
MS
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
0-2
Xwt
4
8
0
0
0
0
2
d
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
NA
NA
NA
NA
NA
.039
.131
.137
.381
.164
.217
.738
<
.236
.022
.016
.000
.464
<
.000
.516
.399
<
<
.041
.000
.014
<
.012
<
.000
.050
.000
.225
<
.5 um
unc
0.000
0.000
0.000
0.000
0.000
0.519
1.005
0.041
0.132
0.055
0.038
0.342
0.000
0.034
0.000
0.000
0.000
0.189
0.000
0.000
0.068
0.054
0.000
0.000
0.026
0.000
0.000
0.000
0.014
0.000
0.062
0.089
0.119
0.203
0.000
2.5-10 um
Xwt
NA
NA
NA
NA
NA
2.568
6.250
0.118
0.568
0.032
0.167
2.285
<
0.157
0.000
0.000
0.010
0.907
<
0.000
0.731
0.313
<
<
0.021
0.000
0.000
<
0.000
<
0.000
0.013
0.000
0.069
<
unc
0.000
0.000
0.000
0.000
0.000
0.257
0.625
0.012
0.057
0.000
0.017
0.228
0.000
0.016
0.000
0.000
0.000
0.091
0.000
0.000
0.073
0.031
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
0.023
0.000
Bulk sample
30510504
(0-65
0.340
0-10 un
Xwt
NE
NE
NE
NE
Ni
3.001
6.803
0.124
0,513
0.071
0.182
2.418
NE
0.180
0.006
0.005
0.007
1.071
NE
0.000
0.668
0.338
NE
NE
0.027
0.000
0.004
' NE
0.004
NE
0.000
0.024
0.000
0.115
NE
unc
0.000
0.000
0.000
0.000
0.000
0.262
0.551
0.015
0.051
C.018
0.017
0.191
0.000
0.016
0.001
0.001
0.000
0.095
0.000
0.000
0.047
0.028
0.000
0.000
0.008
0,000
0.001
0.000
0.004
0.000
0.018
0.026
0.035
0.061
0.000
(0-10>
0.510
Total
Measured
Xwt
NA
NA
NA
NA
NA
3.007
7.663
0.144
0.596
0.047
0.187
2.229
<
0.181
0.000
0.000
0.013
1.037
<
0.000
1.083
0.459
<
<
0.023
0.000
0.000
<
0.000
<
0.000
0.012
0.000
0.000
<
unc
0.000
0.000
0.000
0.000
0.000
0.301
0.766
0.014
0.060
0.000
0.019
0.223
0.000
0.018
0.000
0.000
0.000
0.104
0.000
0.000
0.108
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
0.000
227
-------
PH Profile Special ion Report - continued (profile 21203)
Total Participate
Matter
CAS Number
?440-39-3
7440-45-1
7439-97-6
7439-92-1
Hum Sym
56
58
80
82
201
202
203
204
Ba
Ce
Hg
Pb
oc
EC
S04
N03
Total
0-2
Xwt
0.560
<
0.017
0.249
NA
NA
NA
NA
.5
urn
unc
0.
0.
0.
0.
0.
0.
0.
0.
610
000
016
049
000
000
000
000
2.5-
Xwt
0.000
<
0.000
0.131
NA
NA
NA
NA
10 urn
unc
0.061
0.000
0.000
0.013
0.000
0.000
0.000
0.000
0-10 urn
Xwt
0.165
NE
0.005
0.166
NE
Ni
NE
NE
unc
0.182
0.000
0.005
0.019
0.000
0.000
0.000
0.000
Measured
Xwt
0.066
<
0.000
0.201
NA
NA
NA
NA
unc
0.048
0.000
0.000
0.020
0.000
0.000
0.000
0.000
TOTALS: 19.628 14.340 15.897 16.948
228
-------
PN Profile Speciation Report
Profile Name Coal Dust
Profile Number 21204
Data Quality B/C
Control Device Uncontrolled
Reference(s) 43
Data Source Fugitive dust from storage and handling
resuspended.
SCC Assignments: 30510103, 30510203, 30510303, 30510403,
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.150
Total Partieulate Matter -
CAS Nunber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
0-2
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
2?
28
29
30
31
32
33
34
35
37
38
40
47
48
49
50
51
Be
B
F
Na
Ms
Al
Si
P
S
Cl
f
Ca
Sc
Ti
V
Cr
Hn .
Fe
Co
Ni
Cu
Zn
Sa
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
In
Sn
sb
10
22
0
0
0
0
3
0
0
0
1
0
0
0
0
0
0
NA
NA
NA
NA
NA
.865
.466
.194
.566
.171
.968
.142
<
.283
<
.015
.013
.422
<
<
.022
.033
<
<
<
<
<
<
.015
.000
<
<
.031
.027
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
1.086
2.247
0.019
0.057
0.020
0.097
0.314
0.000
0.028
0.000
0.000
0.000
0.142
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
0.014
0.021
0.024
0.028
0.054
2.5-
%wt
NA
NA
NA
NA
NA
4.627
11.346
0.085
0.417
0.067
0.489
3.422
<
0.161
<
<
<
<
0.945
<
<
<
<
<
<
<
<
<
0.015
0.000
<
0.017
<
<
0.018
10 urn
unc
0.000
0.000
0.000
0.000
0.000
0.463
1.135
0.000
0.042
0.000
0.049
0.342
0.000
0.016
0.000
0.000
0.000
0.094
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
0.013
0.021
. Sample sieved and
30510503
(0-63
0.340
0-10 urn
Xwt
NE
NE
NE
NE
NE
6.462
14.617
0.117
0.461
0.098
0.630
3.340
NE
0.197
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
0.015
0.000
NE
NE
NE
ME
NE
unc
0.000
0.000
0.000
0.000
0.000
0.602
1.282
0.000
0.036
0.000
0.055
0.237
0.000
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000 .
0.000
0.000
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.000
0.000
(0-10)
0.110
Total
Measured
Xwt
NA
NA
NA
NA
NA
5.273
12.956
0.097
0.533
0.086
0.519
4.465
<
0.172
<
<
<
1.109
<
<
0.049
0.041
<
<
<
<
<
<
0.016
0.000
<
0.012
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.527
1.296
0.000
O.D53
0.000
0.052
0.446
0.000
0.017
0.000
0.000
0.000
0.111
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
0.012
0.022
229
-------
PH Profile Speciatfon Report - continued (profile 21204}
Total Participate Matter •
CAS Number
7440-46-2
7440-39-3
7439-97-6
7439-92-1
Nun Sym
55
56
80
82
201
202
203
204
TOTALS:
Cs
Ba
H9
Pb
OC
EC
S04
N03
0-2
Xut
<
0,077
<
0.072
NA
NA
NA
NA
.5
urn
unc
0
0
0
0
0
0
0
0
.000
.138'
.000
.000
.000
.000
.000
.000
2.5-10 urn
Xwt
<
<
<
0.018
NA
NA
NA
NA
unc
0.000
0.061
0.000
0.000
0.000
0.000
0.000
0.000
40.382 21.627
0-10 urn
Xwt
NE
NE
NE
0.034
NE
NE
NE
NE
25.971
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
%wt
<
0.108
<
0.044
NA
NA
NA
NA
25.480
unc
0.000
0.056
0.000
0.000
0.000
0.000
0.000
0.000
230
-------
PN Profile Speciation Report
Profile Name
Profile Number
Data Quality
Calcium Carbide Furnace
25201
D/E
Control Device Uncontrolled
Referenced) 46
Data Source Sampled with a 2-stage virtual impactor with a Method 5
heated probe. Analysis by XRF, INNA, 1C, and carbon
oxidation. No dilution air. Average of 2 samples from
same source.
SCC Assignments: 30500999
Mass Fraction Data - Size Interval (urn) ;
Mass Fraction :
Total Particulate Matter
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
O^XSU 1 C»
Hum Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
Be
B
F
Na
MS
Al
Si
p
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
AS
Se
Bf
Rb
Sr
Zr
Ag
Cd
Sn
0-2
%wt
NA
NA
NA
0.920
2,400
0,580
2.500
<
1.600
1.050
1.250
30.000
<
<
<
<
0.042
0.540
<
0.022
0.020
0.015
<
<
<
<
<
<
<
<
<
<
<
.5 urn
une
0.000
0.000
0.100
0.100
0.350
0.110
0.070
0.000
0.420
0.070
0.350
4.000
0.000
0.020
0.000
0.010
0.003
0.080
0.000
0.008
0.011
0.007
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.000
o.ooo
0.000
o.ooo
(0-2.5)
0.180
2,5-10 urn
%ut
0
1
0
2
0
0
0
25
0
0
0
0
0
NA
NA
NA
.430
.250
.860
.900
<
.540
.960
.480
.800
<
<
.009
<
.036
.330
<
.021
.040
<
<
<
<
<
<
<
<
<
<
<
<
une
0.000
0.000
0.200
0.050
0.350
0.130
1.300
0.000
0,570
0.630
0.300
8.700
0.000
0.020
0.000
0.010
0.010
0.130
0.000
0.006
0,004
0.010
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.000
0.000
0.000
<0-6)
0.370
0-10 urn
Xwt
NE
NE
NE
0.596
1.641
0.765
2.764
NE
0.900
0.991
0.742
27.226
NE
NE
NE
NE
0.038
0.401
NE
0.021
0.033
NE
NE
NE
NE
NE
NE
NE
WE
NE
NE
NE
NE
une
0.000
0.000
0.000
0.062
0.212
0.076
0.479
0.000
0.254
0,226
0.169
3.767
0.000
0.000
0.000
0.000
0.004
0.060
0.000
0.004
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-10)
0.530
Total
Measured
Xwt
NE
NE
NE
0.596
1.641
0.765
2.764
NE
0.900
0.991
0.742
27.226
NE
NE
NE
NE
0.038
0.401
NE
0.021
0.033
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
231
-------
PN Profile Speciation Report - continued (profile 25201)
Total Partieulate Hatter
CAS Number
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Num Eym
51
55
56
58
80
82
201
202
203
204
Sb
Cs
Ba
Ce
US
Pb
OC
EC
S04
N03
0-2
Xut
<
<
<
<
<
0.008
7.300
1.200
* 3.200
0.570
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.004
1.300
0.280
0.420
0.240
2.5-10
urn
Xut unc
< 0
< Q
< 0
< 0
< 0
< 0
4.500 0
3.600 1
0.930 1
NA 0
.000
.000
.000
.000
.000
.000
.780
.800
.100
.500
0-10
Xut
NE
NE
NE
NE
NE
NE
5.451
2.785
1.701
NE
0
urn
unc
.000
0.000
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.659
.645
.431
.000
Total
Measured
%Mt
NE
NE
NE
NE
NE
NE
5.451
2.785
1.701
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
53.217
42.686
46.055
46.055
232
-------
PM Profile Speciat ion Report
Profile Name Silica Manufacturing
Profile Number 25401
Data Quality C/D
Control Device Beghouse
Reference(s) 21
Data Source Sampled with • 2-stage virtual impactor. Analysis by XRF.
Average of 3 source tests from a baghouse outlet.
SCC Assignments: 30599999
Mass Fraction Data - Size Interval (un) : (0-2.5} (0-6)
Mass Fraction ; 0.485 0.390
Total Particulate Matter
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-4S-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Sym
Be
B
F
Na
MS
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
cr
Mn
Fe
Co
Ni
CU
Zn
Ga
Ge
As
se
Br
Rb
sr
Zr
Ag
Cd
Sri
Sb
Cs
0-2.5 un
Xwt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
0.990 0.200
45.320 9.120
< 0.000
0.140 0.030
. < 0.000
0.280 0.060
< 0.000
< 0.000
0.005 0.001
< 0.000
< 0.000
< 0.000
0.160 0.030
< 0.000
< 0.000
0.013 0.003
0.003 0.001
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
2.5-10
urn
Xwt unc
NA 0
NA 0
NA 0
NA 0
NA 0
< 0
46.360 9
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
0.390 0
< 0
< 0
.000
.000
.000
.000
.000
.000
.270
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.078
.000
.000
< 0.000
< 0
< 0
.000
.000
< 0.000
< 0
< 0
< 0
< 0
< 0
« 0
< 0
< 0
< 0
.000
.000
.000
.000
.000
.000
.000
.000
.000
< 0.000
< 0
.000
0-10 urn
Xwt
NE
NE
NE
NE
NE
NE
45.448
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
0.188
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0
0
0
0
0
0
13
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.955
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.090
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
(0-10)
0.553
Total
Measured
Xwt
NE
NE
NE
NE
NE
NE
45.448
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
0.188
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
233
-------
PH Profile Speciation Report • continued (profile 25401)
Total Partfculate Matter -
Species
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Nun
56
58
SO
82
201
202
203
204
'Sym
Ba
Ce
Hg
Pb
OC
EC
S04
N03
0-2.5 urn
Xut
<
<
<
<
NA
NA
NA
* NA
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
<
<
<
<
NA
NA
NA
NA
0
0
0
0
0
0
0
0
un
unc
.000
.000
.000
.000
.000
.000
.000
.000
0-10 urn
Xwt
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xyt
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
46.911
46.750
45.636
45.636
234
-------
PN Profile Specfatfon Report
Profile Name
Profile Nunber
Data Quality
Asphalt Roofing Manufacturing
25402
C/D
Control Device
Reference(s)
Data Source
Unspecified
10
SASS train with heated Method 5 probe, 3 cyclones at 400
des F. Cyclone and filter catches analyzed by XRF. Si,
P, and S non-quantitative. Average of 2 samples taken
down stream of control system.
SCC Assignments: 30500102
Mass Fraction Data - size Interval (urn)
Mass Fraction
Total Participate Matter
CAS Number
7*40-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
0-2
Nun Sym fort
4
5
9
11
12
13
14
15
1*
17
19
20
21
22
23
24
o
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
Be
B
F
Na
Mg
Al
Si
P
c
C c
K
Ca
Sc
Ti
V
Cr
wn
Fe
Co
Hi
Cu
Zn
Ga
Go
As
Se
8r
Rfa
Sr
Zr
Ag
Cd
Sn
NA
NA
NA
<
<
<
<
<
7.600
12.000
0.550
3.400
<
<
. <
0.550
O.S5Q
2.100
1.800
<
<
0.550
<
<
<
0.550
<
<
<
<
<
<
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
7.000
3.000
0.000
0.700
0.000
0.000
0.000
0.000
0.000
0.300
0.300
0.000
0.000
0.000
0.000
0.000
0^000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.330
2.5-10 urn
Xut
NA
NA
NA
<
<
<
<
<
5.000
12.000
0.550
3.400
<
<
<
0.550
0.550
2.100
1.800
<
<
0.550
<
<
<
0.550
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
7.000
3.000
0.000
0.700
0.000
0.000
0.000
0.000
0.000
0.300
0.300
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.380
0-10
Xut
NE
NE
NE
NE
NE
NE
NE
NE
7.145
12,000
0.550
3.400
NE
NE
NE
0.550
0.550
2.100
1.800
NE
NE
0.550
NE
NE
NE
0.550
NE
NE
NE
NE
NE
NE
NE
urn
unc
0
0
0
0
0
0
0
0
8
4
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.236
.021
.000
.991
.000
.000
.000
.000
.000
.493
.459
.000
.000
.000
(0-10)
0.400
Total
Measured
%ut
NA
NA
NA
<
<
<
<
' <
7.330
12.000
0.550
3.400
<
<
<
0.550
0.550
2.100
1.800
<
<
0.550
0.000 <
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
<
<
0.550
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
7.000
3.000
0.000
0.700
0.000
0.000
0.000
0.000
0.000
0.300
0.300
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
235
-------
PH Profile Speciation Report* - continued (profile 25402)
Total Participate Matter -
0-2.5 urn 2.5-10 urn 0-10 urn
CAS Number Nun Sym
%ut
unc
%Mt
unc
Xut
unc
Total
Measured
Xut
TOTALS:
76.650
74.050
76.195
76.380
unc
7440-36-0 51
7440-46-2 55
7440-39-3 56
7440-45-1 58
7439-97-6 80
7439-92-1 82
201
202
203
204
Sb
Cs
Be
Ce
«8
Pb
oc
EC
S04
N03
23
1
23
<
<
.000
.000
.000
«
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<
<
23.000
1.000
23.000
*
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
23
1
23
NE
m
m
NE
NE
NE
.000
.000
.000
NE
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<
<
23.000
1.000
23.000
<
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
236
-------
PH profile Special ion Report
Profile Name
Profile Number
Data Quality
Carborundum Manufacturing
25406
B/0
Control Device Uncontrolled
Reference(s) 46, 54
Data Source Sampled with a 2-stage virtual impactor with a Method 5
heated probe. No dilution air. Analysis by XRF, INNA, 1C,
and carbon oxidation. Samples from roof exhaust vent.
Average of 4 samples from burn cycle and bottom removal.
SCC Assignments: 30500999
Mass Fraction Data • Size Interval (tin)
Mass Fraction
Total Particulate Matter -
Species
CAS Number
7440-41 -7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
?5
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
Syra
Be
8
F
Na
MS
Al
Si
P
s
Cl
K
Ca
Sc
Ti
V
Cr
Mr>
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
0-2
%wt
0
NA
NA
.050
0.120
0
0
.780
.350
3.500
4
1
0
0
0
0
0
0
0
0
0
0
0
'<
.800
.700
.790
.140
<
.014
.007
.009
.035
.330
<
.004
.019
.004
<
<
<
<
.017
<
<
<
<
<
<
.5 urn
unc
0.000
0.000
0.030
0.100
1.200
0.400
4.300
0.000
6.600
1.500
1.100
0.130
0.000
0.019
0.008
0.011
0.041
0.610
0.000
0.007
0.023
0.004
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.485
2.5-10 urn
%wt
NA
NA
NA
0.260
<
2.800
12.000
<
0.410
0.990
0.720
0.570
<
0.033
0.012
0.004
0.029
0.270
<
0.017
0.055
<
<
<
<
<
0.011
<
<
<
<
<
<
unc
0.000
0.000
0.400
0.170
0.400
4.300
15.000
0.000
0.310
0.430
1.100
0.490
0.000
0.490
0.010
0.007
0.025
0.210
0.000
0.230
0.018
0.010
0.000
0.000
0.000
0.000
0.009
0.000
0.000
0.000
0.000
0.000
0.000
{0-6)
0.390
0-10 urn
Xwt
HE
NE
NE
0.137
NE
0.651
4.545
NE
4.260
1.613
0.781
0.193
NE
0.016
0.008
0.008
0.034
0.323
NE
0.006
0.023
NE
NE
NE
NE
NE
0.016
NE
NE
NE
NE
Ni
NE
unc
0.000
0.000
0.000
0.177
0.000
3.804
0.000
0.000
5.826
1.390
1.371
0.451
0.000
0.430
0.011
0.012
0.042
0.568
0.000
0.202
0.027
0.000
0.000
0.000
0.000
0.000
0.012
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.553
Total
Measured
Xut
NE
NE
NE
0.137
NE
0.651
4.545
NE
4.260
1.613
0.781
0.193
NE
0.016
0.008
0.008
0.034
0.323
NE
0.006
0.023
NE
NE
NE
NE
NE
0.016
HE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
237
-------
PH Profile Speciation Report - continued (profile 25406)
Total Particulete Hatter -
Total
CAS Number
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
<3}iJV»^ ICO
Nun Sym
51
55
56
58
80
82
201
202
203
204
Sb
Cs
Ba
Ce
Hfl
Pfa
OC
EC
S04
K03
0-2.5
urn
Xut unc
< 0
< 0
< 0
< 0
< 0
< 0
21 .400 7
13.670 13
16.000 25
1.600 2
.000
.000
.000
.000
.000
.010
.400
.000
.000
.100
2.5-10
Xwt
< 0
< 0
< 0
< 0
< 0
< 0
4.600 2
24.000 15
1.600 1
0.830 0
urn
unc
.000
.000
.000
.000
.000
.010
.300
.000
.830
.480
0-10
Xut
NE
NE
NE
NE
NE
NE
19.334
14.940
14.229
1.505
0
0
0
0
0
0
7
0
0
1
un
unc
.000
.000
.000
.000
.000
.000
.319
.000
.000
.902
Measured
Xwt
NE
NE
NE
NE
NE
NE
19.334
14.940
14.229
1.505
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
65.339
49.211
62.622
62.622
238
-------
PH Profile SpecIation Report
Profile Name Class Furnace
Profile number 27102
Data Quality I/O
Control Device Uncontrolled
Referenced ) 49
Data Source Average of 3 replicate samples collected with a dilution
sampler.
SCC Assignments: 30501402
Mass Fraction Data - Size Interval (un) ; (0-2.5) (0-6)
Mass Fraction : 0.910 0.930
Total Parti cut ate
CAS Number
7440-41 -7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
77B2-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7439-98-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
VJKI
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
42
47
48
50
51
55
Matter
?ies
Sym
Be
B
F
Na
MS
Al
si
p
s
ct
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Mo
Ag
Cd
Sn
Sb
Cs
-
0-2
Xwt
0
0
0
12
0
0
0
0
17
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.003
.010
.027
.800
.183
.011
.320
.025
.600
.016
,800
.427
<
.004
.006
,215
,003
.026
.020
.004
.001
.022
<
<
.023
,014
.004
.013
.003
.042
.001
.003
.015
.002
<
.5 un
unc
0.003
0.010
0.006
1.280
0.018
0.011
0.060
0.025
1.760
0.003
0.180
0.043
0.000
0.000
0.000
0.021
0.001
0.003
0.020
0.000
0.000
0.002
0.000
0.000
0.002
0.003
0.000
0.001
0.000
0.004
0.001
0.002
0.003
0.002
0.000
2.5-10 urn
Xut
0.003
0.010
0.027
12.800
0.1S3
0.011
0.320
0.025
17.600
0.016
1.800
0.427
<
0.004
0.006
0.215
0.003
0.026
0.020
0.004
0.001
0.022
«
<
0.023
0.014
0.004
0.013
0.003
0.042
0.001
0.003
0.015
0.002
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
0.003
0.010
0.027
12.800
0.183
0.011
0.320
0.025
17.600
0.016
1.800
0.427
<
0.004
0.006
0.215
0.003
0.026
0.020
0.004
0.001
0.022
<
<
0.023
0.014
0.004
0.013
0.003
0.042
0.001
0.003
0.015
0.002
<
unc
0.003
0.010
0.008
2.742
0.039
0.011
0.084
0.024
3.770
0.004
0.386
0.092
0.000
0.001
0.001
0.046
0.001
0.006
0.020
0.001
0.000
0.005
0.000
0.000
0.005
0.004
0.001
0.003
0.001
0.009
0.001
0.002
0.004
0.002
0.000
(0-10)
0.950
Total
Measured
Xwt
NA
NA
0.025
NA
NA
0.028
0.347
0.032
17.512
0.020
1.835
0.461
<
0.005
0.006
0.218
0.003
0.034
<
0.004
0.001
0.023
<
<
0.023
0.014
0.004
0.013
0.003
0.044
0.001
0.003
0.014
0.002
<
unc
0.000
0.000
0.005
0.000
0.000
0.010
0.055
0.024
1.751
0.007
0.183
0.046
0.000
0,000
0.000
0.022
0.000
0.006
0.000
0.000
0.000
0.002
0.000
0.000
0.002
0.003
0.000
0.001
0.000
0.004
0.001
O.C02
0.003
0.003
0.000
239
-------
PH Profile Speciation Report- - continued (profile 27102)
Total Paniculate Hatter -
Total
0-2.5 urn 2.5-10 un 0-10 un Measured
CAS Number Nun Syro Xut unc Xwt unc Xwt unc Xwt unc
7440-39-3
7440-45-1
7439-97-6
7439-92-1
56
58
80
82
201
202
203
204
Ba
Ce
Hg
Pb
DC
EC
S04
N03
0
0
0
0
48
0
.003
<
<
.195
.710
.062
.900
.015
0.001
0.000
0.000
0.019
0.080
0.080
7.300
0.003
0.003
<
<
0.195
0.710
0.062
48.900
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
<
<
0.195
0.710
0.062
48.900
0.015
0.001
0.000
0.000
0.042
0.156
0.078
11.690
0.004
0.009
<
<
0.194
1.050
0.154
50.341
0.018
0.008
0.000
0.000
0.019
0.105
0.105
6.579
0.006
TOTALS: 83.528 83.528 83.528 72.441
240
-------
PM Profile Speciation Report
Profile Name
Profile Nunber
Data Quality
Cement Kiln (Gas-Fired}
27201
D/E
Control Device Baghouse
Reference 10
Data Source SASS train with Method 5 heated probe, 3 cyclones, at 400
deg F. Cyclone and filter catches analyzed by XRF. Si,
P, and S non-quantitative. Average of 2 samples downstream
from baghouse.
SCC Assignments: 30500606
Mass Fraction Data - Size
Total Particulate
Mass
Matter -
CAS Winter
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7733-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
apet* i es>
Hum Syra
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
2:
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
Be
8
F
Na
Kg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mr,
fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Interval (urn)
Fraction
0-2.5 urn
Xwt unc
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
< 0.000
< 0.000
2.400 0.400
< 0.000
2.400 0.400
16.100 3.000
< 0.000
0.550 0.000
< 0.000
< 0.000
< o.oco
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
! (0-2.5)
: 0.450
2.5-10 urn
Xwt unc
HA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
< 0.000
< 0.000
< 0.000
< 0.000
1.500 0.300
22.000 3.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.550 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
(0-6}
0.
0-10
Xwt
NE
NE
NE
NE
NE
NE
Ni
NE
Ni
NE
1.982
18.839
NE
NE
NE
NE
NE
NE
NE
Ni
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
790
urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.343
3.071
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
(0-10)
0.840
Total
Measured
%ut unc
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
< 0.000
< 0.000
2.200 0.800
< 0.000
1.400 0.300
27.000 3.000
< 0.000
< 0.000
< 0.000
0.550 0.000
< 0.000
1.200 0.100
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
241
-------
PH Profile Speciation Report - continued (profile 27201)
Total Partfeulste Hatter
CAS Number
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
species
Nun *Sym
51
55
56
58
80
82
201
202
203
204
206
Sb
Cs
Ba
Ce
HO
Pb
oc
EC
504
N03
C03
0-2.5
un
%ut unc
< 0
< 0
< 0
.000
.000
.000
< 0.000
< 0
< 0
NA 0
NA 0
4.270 0
.000
.000
.000
.000
.000
0.550 0.000
0.000 0
.000
2.5-10
un
Xut unc
< 0
< 0
< 0
< 0
< 0
< 0
2.660 0
NA 0
1.680 0
0.550 0
8.100 0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0-10
Xut
NE
NE
NE
NE
NE
NE
NE
NE
3.067
0.550
3.761
um
unc
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
0.000
0
0
.000
.614
Total
Measured
Xwt
< 0
< 0
< 0
< 0
« 0
< 0
3.220 0
NA 0
1 .260 0
0.550 0
8.790 0
unc
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
TOTALS;
26.270
37.040
28.199
46.170
242
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Cement Kiln (Coal-Fired)
27203
S/D
Control Device ;
Referenee(s) :
Data Source :
ESP
49
Average of 2 replicate samples from a single stack collected
with a dilution sampler with a 2-stage virtual impactor.
SCC Assignments: 30500706
Mass Fraction Data - Size Interval (im)
Mass Fraction
Total Participate Matter -
CAS Nurfcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-39-3
7439-91-0
e|i«5t» i Ka
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
33
34
35
37
38
40
42
46
47
48
49
50
56
57
Be
B
f
Na
Ng
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Br
Rb
Sr
Zr
No
Pd
Ag
Cd
In
Sn
Ba
La
0-2
JtHt
0
0
0
2
0
4
8
.020
.050
.200
.290
.240
.280
.440
0.017
6
7
5
10
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
q
0
0
0
0
.800
.800
.400
.000
.298
.010
.027
.034
.930
.100
.093
.023
.217
.004
.010
.020
.075
.032
.006
,016
.005
.006
.016
.006
.004
.034
.024
.5 urn
unc
0.020
0.050
0.028
0.460
0.024
0.430
0.844
0.075
1.400
1.900
1.500
1.300
0.036
0.002
0.024
0.019
0.140
0.100
0.096
0.004
0.022
0.010
0.003
0.006
0.019
0.003
0.009.
0.015
0.009
0.004
0.015
0.008
0.004
0.007
0.024
: (0-2.5)
: 0.640
2.5-
%wt
0.020
0.050
0.200
2.290
0.240
4.280
8.440
0.017
6.800
7.800
5.400
10.000
0.298
0.010
0.027
0.034
0.930
0.100
0.093
0.023
0.217
0.004
0.010
0.020
0.075
0.032
0.006
0.016
0.005
0.006
0.016
0.006
0.004
0.034
0.024
10 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.840
0-10 urn
Xwt
0.020
0.050
0.200
2.290
0.240
4.280
8.440
0.017
6.800
7.800
5.400
10.000
0.298
0.010
0.027
0.034
0.930
0.100
0.093
0.023
0.217
0.004
0.010
0.020
0.075
0.032
0.006
0.016
0.005
0.006
0.016
0.006
0.004
0.034
0.024
unc
0.015
0.038
0.037
0.489
0.040
0.721
1.421
0.057
1.470
1.851
1.392
1.796
0.052
0.002
0.019
0.015
0.175
0.077
0.074
0.005
0.037
0.008
0.003
0.005
0.018
0.005
0.007
«.012
0.007
0.003
0.012
0.006
0.003
0.007
0.018
CO-10)
0.850
Total
Measured
Xwt
NA
NA
0.200
NA
NA
4.106
8.896
0.029
5.000
4.392
3.792
14.800
0.302
0.011
0.016
0.027
1.038
NA
0.043
0.017
0.203
0.005
0.009
0.012
0.055
0.037
0.004
0.018
0.003
0.003
0.010
0.004
0.004
0.026
0.025
unc
0.000
0.000
0.109
0.000
0.000
0.411
1.362
0.049
0.912
0.771
0.622
1.480
0.032
0.001
0.010
0.008
0,104
0.000
0.038
0.002
0.020
0.006
0.002
0.002
0.008
0.004
0.004
0.012
0.004
0.003
0.007
0.004
0.003
0.013
0.018
243
-------
PH Profile Speciation Report - continued (profile 272033
Total Particular Hatter -
0-2.5 urn 2.5-10 urn 0-10 urn
*ut unc %ut unc Xwt
Total
Measured
Species
CAS Number Nun 'sym
unc
Xwt
unc
7439-97-6
7439-92-1
7440-69-9
TOTALS:
80
82
83
201
202
203
204
Ha
Pb
Bi-
OC
EC
S04
N03
0
1
1
5
0
18
0
74
.001
.820
.000
.400
.200
.300
.200
.448
0.001
0.280
1.000
0.600
0.400
6.400
0.040
0.001
1.820
1.000
5.400
0.200
18.300
0.200
74.448
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.001
1.820
1.000
5.400
0.200
18.300
0.200
74.448
0.001
0.346
0.768
0.930
0.303
5.551
0.043
0.001
1.346
HA
6.654
0.188
14.520
0.740
66.536
0.000
0.136
0.000
0.665
0.288
7.642
0.660
244
-------
PM Profile Speciation ieport
Profile Name
Profile Number
Data Quality
Portland Cement Oust
27204
Control Device
Reference(s)
Data Source
Uocontpol ledCU
62
Unspecified methodology.
SCC Assignments 30500618, 30500619
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-47-3
7439-96-5
7439-89-6
7440-66-6
7440-24-6
Hum
13
14
15
16
19
20
22
24
25
26
30
38
Sym
Al
Si
P
S
1C
Ca
Ti
Cr
Mn
Fe
1 Zn
Sr
0-2.5 unvC2>
Xwt
2.
10.
0.
0.
0.
46.
0.
0.
0.
2,
0.
0.
000
200
100
880
140
100
140
007
030
940
008
260
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
2.000
10.200
0.100
0.880
0.140
46.100
0.140
0.007
0.030
2.940
0.008
0.260
un»C2}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
2.000
10.200
0.100
0.880
0.140
46.100
0.140
0.007
0.030
2.940
0.008
0.260
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xwt
2.000
10.200
0.100
0.880
0.140
46.100
0.140
0.007
0.030
2.940
0.008
0.260
unc
0.400
2.000
0.020
0.170
0.028
4.610
0.028
0.001
0.006
0.580
0.002
0.052
TOTALS:
62,805
62.805
62.805 62.805
CD No control specified: thus, assumed uncontrolled.
<2> Estimated / extrapolated.
245
-------
PH Profile Specfation Report
Profile Name : Cement Ball Mill
Profile Nunfoer : 27205
Data Quality : D
Control Device : Uncontrolled^}
Referenee{s> : 62,78
Data Source : Data taken from Reference 62. For details, consult Reference
78.
SCC Assignments: 30500609, 30500610
Mass Fraction Data - Size Interval (urn)
Kass Fraction
Total Particulate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
2SS===!3S:SS==
&}J*S\f i C»
Hum Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
As
Cd
In
Sn
Sb
Ba
La
H3
Pb
0-2.5
Xut
2
«J
0
2
0
0
24
0
0
0
. 0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
40
.542
.363
.105
.357
.328
.873
.175
.186
.016
.016
.273
.221
.004
.000
.013
.001
.002
.001
.002
.010
.091
.010
.015
.015
.005
.008
.013
.000
.005
.000
.063
.001
.002
.011
.727
umt2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: <0-2.5)
: 0.300
2.5-10
Xwt
2.542
8.363
0.105
2.357
0.328
0.873
24.175
0.186
0.016
0.016
0.273
1.221
0.004
0.000
0.013
0.001
0.002
0.001
0.002
0.010
0.091
0.010
0.015
0.015
0.005
0.008
0.013
0.000
0.005
0.000
0.063
0.001
0.002
0.011
40.727
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-6)
0.620
0-10
%ut
2.542
8.363
0.105
2.357
0.328
0.873
24.175
0.186
0.016
0.016
0.273
1^221
0.004
0.000
0.013
0.001
0.002
0.001
0.002
0,010
0.091
0.010
0.015
0.015
0.005
0.008
0.013
0.000
0.005
0.000
0.063
0.001
0.002
0.011
40.727
um<2>
unc
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{0-10}
0.850
Total
Measured
%ut
2.542
8.363
0.105
2.357
0.328
0.873
24.175
0.186
0.016
0.016
0.273
1.221
0.004
0.000
0.013
0.001
0.002
0.001
0.002
0.010
0.091
0.010
0.015
0.015
0.005
0.008
0.013
0.000
0.005
0.000
0.063
0.001
0.002
0.011
unc
0.639
2.332
0.029
0.480
0.049
0.131
3.626
0.029
0.004
0.002
0.041
0.183
0.001
0.001
0.002
0.000
0.001
0.000
0.001
0.002
0.014
0.001
0.005
0.003
0.002
0,003
0.005
0.005
0.005
0.009
0.024
0.034
0.001
0.002
40.727
C1> No control specified: thus, assumed uncontrolled.
C2> Estimated / extrapolated. 246
-------
PM Profile Speciat ion Report
Profile Name
Profile Nunber
Data Quality
Gypsum Catciner
27501
D/E
Control Device Baghouse
Reference(s) 10
Data Source SASS train uith Method 5 heated probe, 3 cyclones, at 400,
dei» f. Cyclone and filter catches analyzed by XRF. si,
P, and S non-quantitative. The one sample analyzed was
taken downstream of the baghouse.
SCC Assignments: 30501501, 30501520
Mass Fraction Data - size Interval (in)
Mass fraction
Total Participate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
aj^Siw 1 KS
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
Be
E
F
Na
Mg
At
Si
p
R
I"1 *
V *.
K
Ca
Sc
Ti
V
Cr
nn
Fe
Co
Ki
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
0-2
'%Ht
13
0
0
13
0
0
0
0
0
0
0
0
0
0
NA
NA
NA
NR
NR
NR
<
<
.660
.550
.550
.000
<
<
<
.550
.050
.550
<
.550
.050
.050
<
<
<
.050
.050
<
.050
<
<
.050
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5 CO
: 0
-2.5)
.180
2.5-10 un
Xwt
NA
NA
NA
NR
NR
NR
<
<
19.000
<
0.050
0.900
<
<
<
0.050
0.050
0.550
<
0.050
0.050
0.050
<
<
0.050
0.050
<
<
0.050
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{0-6)
0.370
0-10 urn
Xwt
NE
NE
NE
NE
NE
NE
NE
NE
17,186
NE
0.220
5.009
NE
NE
NE
0.220
O.OSO
0.550
NE
0.220
0.050
0.050
NE
NE
NE
0.050
NE
m
0.050
NE
NE
NE
NE
unc
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.530
Total
Measured
Xwt
NA
NA
NA
NR
UK
m
<
<
18.300
0.550
0.550
12.000
<
<
<
0.550
0.050
0.550
<
0.550
0.050
0.050
<
<
0.050
0.050
<
<
0.050
<
<
0.050
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
247
-------
PH Profile Speeiation Report - continued (profile 27501)
Total Particulate
£*«.*..
CAS Number
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
aj^«i
Hum
51
55
56
58
80
82
200
202
203
204
206
Hatter
*ies
Sym
Sb
Cs
Ba
Ce
Kg
Pb
TC
EC
S04
N03
C03
0-2.5 uni
Xut
0
1
41
0
0
<
<"
<
<
<
.050
.000
NA
.000
.050
.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xut
<
<
0.050
<
<
<
0.550
NA
57.000
0.050
0.550
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xut
NE
NE
NE
NE
NE
NE
0.703
NE
51.566
0.050
0.363
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Total
Measured
Xwt
<
<
0.050
<
<
0.050
2.000
NA
55.000
0.050
0.550
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0,000
TOTALS: 71.860 79.100 76.337 91.100
248
-------
PM Profile Speciatlon Report
Profile Name Gypsum Handling
Profile Hunter 27502
Data Quality f
Control Device Uheontrol ledCU
Reference(s) 62
Data Source Unspecified methodology.
SCC Assignments 30501504, 30501508
Mass Fraction Data - Size Interval (un) : (0-2.5) (0-6) (0-10)
Mass Fraction : 0.300 0.620 0.850
Total Particulate Matter -
Total
0-2.5 umC2> 2.5-10 um<2> 0-10 un<:2> Measured
Species -- —
CAS Number Hum Sytn Xut unc %ut unc Xwt unc Xwt unc
7704-34-9 16 S 18.600 0.000 18.600 0.000 18.600 0.000 18.600 1.860
7440-70-2 20 Ca 23.300 0.000 23.300 0.000 23.300 0.000 23.300 2.330
203 S04 55.800 0.000 55.800 0.000 55.800 0.000 55.800 5.580
TOTALS: 97.700 97.700 97.700 97.700
C1> No control specified! thus, assumed uncontrolled.
C2> estimated / extrapolated.
249
-------
PH Profile Speciation Report
Profile Name
Profile Number
Data Quality
Gypsum
27103
E
Kiln
Control Device ESP
Reference(s) 62,78
Data Source Data taken from Reference 62. For details, consult Reference
78.
SCC Assignments: 30501520
Mass Fraction Data - Size Interval Cum} : (0-2.5) (0-6)
Mass Fraction : 0.180 0.370
Total Paniculate Matte
Species
CAS Mutfcer
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-1
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
p
S
Cl
<
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Er
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
r -
0-2
Xwt
2
1
1
11
0
0
23.
0
0
,044
.036
.733
.783
,000
.148
.792
.530
.334
0.123
0
0
0
0
0
. 0
0
0
0
0
1
0
0
0
0
0
0
0
0
d
0
0
0
0
45
.068
.928
.010
.019
.017
.003
.000
.002
.015
.007
.768
.058
.178
.015
.032
.000
.000
.000
.000
.000
.260
.077
.009
.083
.072
.5 urn
unc
0.204
0.283
0.348
1.17'8
0.063
0.037
2.379
0.053
0.033
0.012
0.007
0.093
0.004
0.004
0.003
0.002
0.009
0.003
0.004
0.004
0.177
0.007
0.085
0.016
0.015
0.020
0.029
0.031
0.035
0.066
0.189
0.270
0.005
0.012
2.5-10 urn
Xwt
1.200
0.728
0.736
15.456
0.000
0.058
20.938
0.179
0.089
0.032
0.022
0.327
0.002
0.018
0.007
0.001
0.000
0.001
0.004
0.007
0.697
0.017
0.073
0.005
0.000
0.009
0.014
0.000
0.000
0.000
0.114
0.098
0.004
0.036
40.872
unc
0.120
0.127
0.149
1.546
0.073
0.028
2.094
0.018
0.009
0.003
0.002
0.033
0.001
0.002
0.001
0.001
0.003
0.001
0.001
0.001
0.070
0.002
0.033
0.006
0.006
0.008
0.011
0.011
0.015
0.024
0.072
0.103
0.002
0.005
0-10
Xwt
1.487
0.832
1.074
14.208
0.000
0.088
21 .907
0.298
0.172
0.063
0.038
0.531
0.005
0.018
0.010
0.002
0.000
0.001
0.008
0.007
1.061
0.031
0.108
0.008
0.011
0.006
0.010
0.000
0.000
0.000
0.164
0.091
0.005
0.052
42.296
CO-10}
0.850
Total
unvC 1 > HeasuredC2>
unc
0.147
0.135
0.172
1.256
0.048
0.023
1.991
0.035
0.022
0.009
0.006
0.061
0.002
0.004
0.003
0.001
0.003
0.001
0.002
0.002
0.116
0.005
0.037
0.007
0.006
0.009
0.012
0.013
0.015
0.026
0.078
0.110
0.002
0.008
Xwt
1.487
0.832
1.074
14.208
0.000
0.088
21.907
0.298
0.172
0.063
0.038
0.531
0.005
0.018
0.010
0.002
0.000
0.001
0.008
0.007
1.061
0.031
0.108
0.008
0.011
0.006
0.010
0.000
0.000
0.000
0.164
0.091
0.005
0.052
42.296
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CD Calc-.i.ated based on methodology described in the Air Emissions Species Manual,
Volume II.
{2} Estimated / extrapolated.
250
-------
PM Profile Speciat ion Report
Profile Name Lime Handling
Profile Number 27601
Data Quality E
<••.<•••••••<•••BHKII.il>*> • •••••••(••••W«***W*»KBB*B****1«W******»«*WB««KVW1»*<**«»«WB«K..
Reference(s) 62
Data Source Unspecified methodology.
SCC Assignments 30501607, 30501608, 30501615
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6) (0-10)
Mass Fraction ; 0.300 0.620 0.850
Total Paniculate Matter -
Total
0*2.5 um<2} 2.5-10 unC2} 0-10 uiK2> Measured
Species —•
CAS Number Nun Sym Xut unc %ut unc Xwt unc Xut unc
7440-70-2 20 Ca 71.000 0.000 71.000 0.000 71.000 0.000 71.000 7.100
TOTALS: 71.000 71.000 71.000 71.000
O> No control specified; thus, assured uncontrolled.
<2~> Estimated / extrapolated.
251
-------
PH Profile Specfatfon Report
Profile Name If me Kiln
Profile Nuifeer 27602
Data Quality D
Control Device Uncontrolled^}
Reference(s) 62,78
Data Source Data taken from Reference 62. For details, consult Reference
78.
SCC Assignments: 30700106
Hass Fraction Data • Size Interval (urn) : (0-2.5) (0-6)
Hass Fraction s 0.180 0.370
Total Particulars Hatter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31 -5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sytn
Al
Si
p
s
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
?
Zr
Ho
Pd
A3
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xut
1
1
0
7
0
1
22
0
0
0
0
1
0
0
0
0
0
0
0
0
.138
.812
.231
.531
.439
.825
.580
.030
.006
.008
.240
.870
.004
.007
.007
.001
.017
.002
.012
.013
0.011
0
0
0
0
0
0
0
0
0
0
0
0
0
37
.002
.006
.016
.012
.010
.001
.006
.017
.003
.035
.000
.006
.044
.942
.5 urn
unc
0.114
0.222
0.047
0.753
0.218
1.322
2.258
0.007
0.001
0.003
0.045
0.405
0.001
0.003
0.001
0.001
0.003
0.002
0.002
0.007
0.003
0.002
0.008
0.004
0.004
0.005
0.008
0.008
0.009
0.016
0.048
0.064
0.001
0.010
2.5-10 urn
Xwt
0.765
1.300
0.088
3.819
0.287
0.166
26.651
0.037
0.005
0.008
0.198
1.590
0.005
0.007
0.005
0.001
0.004
0.001
0.003
0.003
0.014
0.003
0.005
0.012
0.009
0.005
0.001
0.007
0.004
0.000
0.000
0.000
0.003
0.015
35.021
unc
0.077
0.130
0.031
0.382
0.034
0.037
2.665
0.004
0.001
0.001
0.020
0.159
0.001
0.001
0.001
0.000
0.001
0.000
0.000
0.001
0.001
0.001
0.003
0.002
. 0.002
0.003
0.004
0.004
0.004
0.008
0.020
0.030
0.001
0.002
0-10
Xwt
0.892
1.474
0.136
5.080
0.338
0.729
25.268
0.035
0.005
0.008
0.212
1.685
0.005
0.007
0.006
0.001
0.009
0.001
0.006
0.006
0.013
0.003
0.005
0.013
0.010
0.006
0.001
0.007
0.008
0.001
0.012
0.000
0.004
0.025
36.011
un£2>
unc
0.087
0.147
0.028
0.515
0.081
0.458
2.239
0.006
0.002
0.002
0.026
0.199
0.002
0.002
0.002
0.001
0.002
0.001
0.002
0.003
0.003
0.002
0.004
0.003
0.003
0.003
0.003
0.004
0.004
0.007
0.020
0.028
0.002
0.005
(0-10)
0.530
Total
Measured
%Ht
0.868
1.440
0.128
4.851
0.330
0.633
25.510
0.035
0.005
0.008
0.209
1.666
0.005
0.007
0.006
0.001
0.008
0.001
O.OOS
0.005
0.013
0.003
0.005
0.013
0.010
0.006
0.001
0.007
0.008
0.001
0.009
0.000
0.004
0.023
35.824
unc
0.087
0.144
0.035
0.485
0.086
0,390
2,551
0.005
0,001
0.001
0.021
0.167
0.001
0.001
0.001
0.000
0.002
0.001
0,001
0.002
0.001
0.001
0.004
0.003
0.002
0.003
0.005
0.005
0.006
0.010
0.026
0.040
0.001
0.004
€13 No control specified: thus, assumed uneontrc-. ,ed.
C2J Calculated based on methodology described in the Air Emissions Species Manual,
Volume II. 252
-------
3.7 PETROLEUM INDUSTRY
The petroleum industry includes petroleum refining and natural gas
processing. Petroleum refining involves the production of several fuels,
oils, and feeds for the petrochemical industry from crude oil. Refining
processes include distillation, conversion, treatment, and storage and
handling processes. The must significant sources of emissions include vacuum
distillation, catalytic cracking, thermal cracking, boilers, and heaters.
253
-------
254
-------
Pro-fU* Speeiat
-------
PM Profile Specfation Report - continued (profile 26101)
Total Partfeulate Matter -
Total
Species
CAS Number
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Hum
51
55
56
58
80
82
201
202
203
204
Sym
Sb
Cs
Ba
Ce
Hg
Pb
OC
EC
S04
N03
0-2
Xwt
<
<
<
<
<
0.050
7.000
<
47.000
'0.550
.5
urn
unc
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
2.5-10 urn
Xwt
<
<
<
<
<
0.050
7.000
<
47.000
0.550
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NE
NE
NE
NE
NE
0.050
7.000
NE
47.000
0.550
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xwt
<
<
<
<
<
0.050
7.000
<
47.000
0.550
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
80.200
80.200
80.200
80.200
256
-------
ProfUe Speciation Report
Profile Name Petroleum Refinery Catalytic Cracker
Profile Number 26202
Data Quality B/D
Control Device ESP
Reference(s) 52
Data Source One representative sample from a group of 9 collected
with a dilution sampler.
SCC Assignments: 30600201
Mass Fraction Data • Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction ; 0.485 0.390
Total Particulate
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
ape*
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Hatter
*ies
Sym
Be
B
f
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
MR
Fe
Co
Ni
Cu
In
fia
Ge
As
Se
Br
Rb
Sr
Zr
AS
Cd
Sn
Sb
Cs
0-2.5 urn
Xwt
4
11
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NA
NA
NA
NA
NA
.968
.796
.000
.511
.000
.038
.036
<
.117
.000
.000
.000
.247
<
.027
.003
.005
.002
<
.000
.002
.000
.001
.005
.000
.000
.000
.001
.002
<
unc
0.000
0.000
0.000
0.000
0.000
0.227
0.537
0.074
0.209
0.052
0.002
0.002
0.000
0.053
0.023
0.011
0.003
0.012
0.000
0.001
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.002
0.002
0.002
0.003
0.005
0.000
2.5-10 urn
%ut
NA
NA
NA
NA
NA
23.469
50.570
0.000
2.237
0.000
0.117
0.155
<
0.117
0.000
0.000
0.000
0.567
<
0.059
0.005
0.012
0.005
<
0.000
0.007
0.003
0.003
0.006
0.026
0.045
0.019
0.000
0.000
<
unc
0.000
0.000
0.000
0.000
0.000
1.914
4.227
0.315
0.750
0.183
0.018
0.018
0.000
0.275
0.121
0.055
0.018
0.067
0.000
0.010
0.004
0.003
0.002
0.000
0.007
0.003
0.004
0.004
0.005
0.025
0.022
0.030
0.042
0.080
0.000
0-10 urn
%wt
NE
NE
NE
NE
NE
7.243
16.564
0.000
4.231
0.000
0.048
0.051
NE
0.117
0.000
0.000
0.000
0.286
NE
0.031
0.003
0.006
0.002
NE
0.000
0.003
0.000
0.001
0.005
0.003
0.006
0.002
0.001
0.002
NE
unc
0.000
0.000
0.000
0.000
0.000
3.422
7,446
0.284
0.925
0.167
0.022
0.025
0.000
0.246
0.108
0.049
0.016
0.097
0.000
0.012
0.004
0.003
0.002
0.000
0.006
0.003
0.004
0.004
0.004
0.022
0.020
0.026
0.037
0.070
0.000
(0-10)
0.553
Total
Measured
Xut
NE
NE
NE
NE
NE
7.243
16.564
0.000
4.231
0.000
0.048
0.051
NE
0.117
0.000
0.000
0.000
0.286
NE
0.031
0.003
0.006
0.002
NE
0.000
0.003
0.000
0.001
0.005
0.003
0.006
0.002
0.001
0.002
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
257
-------
PH Profit* Spcciation Report - continued (profile 26202)
Total Particulate Matt
Species
CAS Nuraber
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
ssssssssesssxK
Nun
56
57
80
82
201
202
203
204
sssss
er •
0-2,
Sym Xwt
Ba
La
Hg
Pb
oc
EC
S04
N03
sssss
0.
0.
0.
0.
22.
000
246
000
008
NA
NA
NA
NA
015
.5 un
unc
0.012
0.025
0.000
0.001
0.000
0.000
0.000
0.000
2.5-10 un
Xwt
0.308
0.645
0.006
0.023
NA
NA
NA
NA
unc
0.196
0.334
0.006
0.012
0.000
0.000
0.000
0.000
78.404
0-10 un
Xwt
0.038
0.295
0.001
0.010
NE
NE
NE
NE
28.949
unc
0.176
0.306
0.005
0.011
0.000
0.000
0.000
0.000
Total
Measured
Xwt
0.038
0.295
0.001
0.010
NE
NE
NE
NE
28.949
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
258
-------
PH Profile Special ion Report
Profile Name
Profile Number
Data Quality
Petroleum Refinery Catalytic Cracker
26203
C
Control Device Uncontrolled{1>
Reference(s) 62
Data Source Size-selective dilution samplers used to collect three
samples with two dlehotomous virtual inpactors.
Spectrographic analysis used.
SCC Assignments; 3C£CC£31
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Paniculate
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7440-45-1
7440-00-8
*9b*=t.
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
•5 *
35
37
38
39
40
42
46
47
48
49
50
51
56
57
58
60
Matter
Sym
SI
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
fe
Nj
Cu
Zn
Ga
As
Sc
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Ce
Nd
"
0-2
%Mt
18.
17,
0.
1.
d.
0.
0.
0.
0,
0.
Q.
0.
0.
0.
0.
0.
0.
A
V*
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0,
377
845
042
647
246
179
156
799
000
000
000
688
017
001
012
003
010
OC6
003
000
000
000
000
000
000
000
000
000
000
000
000
431
357
404
.5 urn
unc
2.426
2.479
0.024
0.380
0.069
0.016
0.024
0.093
0.199
0.078
0.030
0.113
0,010
0.002
0.007
0.002
0.007
0.002
0.004
0.002
0.003
0.004
0.015
0.010
0.010
0.013
0.017
0.021
0.025
0.057
0.105
0.318
0.122
0.060
: (0-2.5)
: 0.450
2.5-10 urn
%ut
18.761
17.395
0.055
0.504
0.253
0.119
0.177
0.825
0.000
0.000
0.000
0.822
0.033
0.001
0.014
0.003
0.000
0.006
0.009
0.000
0.012
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.594
1.285
0.361
unc
3.154
2.808
0.009
0.092
0.061
0.017
0.033
0,163
0.239
0.096
0.039
0.094
0.004
0.002
0.003
0.001
0.001
0.001
0.001
0.001
0.004
0.003
0.004
0.002
0.002
0.003
0.004
0.005
0.006
0.013
0.025
0.266
0.280
0.075
(0-6)
0.700
0-10 un
%Ht
18.481
17.628
0.048
1.189
0.252
0.154
0.165
0.806
0.000
0.000
0.000
0.744
0.024
0.001
0.013
0.003
0.006
0.006
0.005
0.000
0.005
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.512
1.316
0.382
unc
3.310
3.668
0.023
0.329
0.082
0.033
0.044
0.188
0.246
0.098
0.039
0.152
0.012
0.003
0.008
0.003
0.005
0.004
0.006
0.002
0.007
0.007
0.011
0.007
0.007
0.010
0.012
0.016
0.019
0.042
0.077
0.326
0.306
0.095
(0-10)
0.790
Total
MeasuredC2>
Xwt
18.481
17.628
0.048
1.189
0.252
0.154
0.165
0.806
0.000
0.000
0.000
0.744
0.024
0.001
0.013
0.003
0.006
0.006
0.005
0.000
0.005
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.512
1.316
0.382
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.QOO
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
259
-------
PH Profile Speeiation Report - continued (profile 26203)
Total Paniculate Hatter -
Total
0-2.5 un 2,5-10 un 0-10 urn Heasured<2>
Species •• ••••• -
CAS Number Hum Sym Xwt unc Xut unc Xut unc %wt unc
7439-97-6 80 Hg 0.001 0.002 0.001 0.000 0.001 0.002 0.001 0.000
7439-92-1 82 Pb 0.000 0.006 0.031 0.006 0.013 0.012 0.013 0.000
TOTALS: 42.224 41.274 41.759 41.759
ata;SK**«»SBSss«Ksi3~Kzs:;sssseEsKseK=BS8SCBSBSB!™—B*S.;S~SS»SS:BS—SSSBSISSSSSSB—sstessssrsxiBsss—s
C1> No control specified: thus, assumed uncontrolled.
C2> Estimated / extrapolated.
260
-------
PM Profile Special ion Report
Profile Name Petroleun Refinery Catalytic Cracker
Profile Number 26204
Data Quality C
Control Device UneontrolltdC1>
Reference(s) 62,78
Data Source Data taken from Reference 62. for details, consult Reference
7B.
SCC Assignments: 30600201
Mass Fraction Data - Size Interval Cum) s {0-2.5} {0-6}
Mass Fraction : 0.450 0.700
Total Participate
Matter
CO-10)
0.790
Total
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
wf^fv I va
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Tt
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Be
La
Hg
Pb
21
43
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
69
0-2
Xwt
.412
.462
.249
.324
.059
.148
.247
.998
.441
.113
.065
.956
.251
.047
.040
.000
.000
.000
.015
.000
.017
.003
.000
.000
.000
.000
.011
.098
.072
.174
.000
.196
.017
.150
.565
.5 urn
unc
2.141
4.346
0.052
0.077
0.028
0.022
0.025
0.100
0.044
0.013
0.008
0.096
0.025
0.009
0.007
0.005
0.017
0.004
0.006
0.006
0.008
0.009
0.040
0.030
0.028
0.042
0.055
0.061
0.074
0.126
0.352
0.526
0.008
0.024
2.5-10 UB
Xut
16.911
32.652
0.125
0.192
0.012
0.115
0.319
1.065
0.447
0.118
0.065
0.829
0.171
0.068
0.027
0.004
0.000
0.001
0.003
0.007
0.019
0.018
0.023
0.000
0.000
0.017
0.006
0.001
0.008
0.009
0.000
0.995
0.002
0.066
54.295
we
1.691
3.265
0.025
0.026
0.010
0.012
0.032
0.107
0.045
0.019
0.007
0.083
0.017
0.007
0.003
0.002
0.006
0.001
0.001
0.002
0.003
0.003
0.011
0.008
0.008
0.011
0,015
0.017
0.022
0.036
0.097
0.270
0.002
0.007
0-10
Xut
19.475
38.809
0.196
0.267
0.038
0.134
0.278
1.027
0.444
0.115
0.065
0.901
0.217
0.056
0.034
0.002
0.000
0.000
0.010
0.003
0.018
0.009
0.010
0.000
0.000
0.007
0.009
0.056
0.045
0.103
0.000
0.540
0.010
0.114
62.992
umC2>
unc
2.658
6.442
0.053
0.073
0.023
0.031
0.055
0.178
0.08.1
0.029
0.018
0.156
0.042
0.018
0.011
0.005
0.013
0.003
0.005
0.006
0.010
0.010
0.031
0.022
0.021
0.032
0.041
0.047
0.057
0.096
0.262
0.446
0.006
0.027
Measured^}
Swt
19.475
38.809
0,196
0.267
0.038
0.154
0.278
1.027
0.444
0.115
0.065
0.901
0.217
0.056
0.034
0.002
0.000
0.000
0.010
0.003
0.018
0.009
0.010
0.000
0.000
0.007
0.009
0.056
0.045
0.103
0.000
0.540
0.010
0.114
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
62.992
C1> No control specified: thus, assumed uncontrolled.
C2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume 11.
C3> Estimated / extrapolated. £61
-------
PM Profile Speciation Report
Profile Name Petroletm Refinery Catalytic Cracker
Profile Number 26205
Data Quality D
Control Device UncontrolledC1>
Reference(s) £2,63
Data Source Four simples analyzed using XRF and neutron activation.
SCC Assignments 30600201
Hass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.450 0.700
Total Particulate Matter -
Species
CAS Number
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7440-45-1
7440-00-8
7440-19-9
7440-53-1
7440-54-2
7440-27-9
7440-64-4
7440-58-6
Nun
11
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
34
35
37
38
40
50
51
56
57
58
60
62
63
64
65
70
72
Sym
Ka
Al
Si
P
S
Cl
1C
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
As
Se
Br
Rb
Sr
Zr
Sn
So
Ba
La
Ce
Nd
Sm
6u
Gd
Tb
Yb
Hf
0-2.5 urn
Xwt
0
.360
6.500
9
0
4
0
0
0
0
0
0
0
0
0
0
0
0
Q
0
0
; 0
0
0
0
0
0
0
0
0
0
0
0
.800
.160
.200
NR
.031
.030
.000
.350
.023
.006
.001
.200
.001
.022
.001
,002
NR
.001
.001
NR
.004
.012
.005
.001
.032
.310
.250
.170
.016
.001
.007
.001
.000
NR
unc
0.040
1.100
1.300
0.030
O.SOO
0.000
0.005
0.004
0.000
0.090
0.007
0.001
0.000
0.030
0.000
0.003
0.001
0.001
0.000
0.000
0.000
0.000
0.001
0.004
0.002
0.000
0.004
0.040
0.040
0.020
0.002
0.000
0.001
0.000
0.000
0.000
2,5-10 um
Xwt
0.944
16.520
49.560
UR
4.012
0.384
0.118
0.159
0.001
0.708
0.049
0.015
0.005
0.590
0.004
0.058
0.008
0.012
0.004
0.001
0.004
0.007
0.012
0.094
NR
0.002
NR
0.873
0.684
0.454
0.045
0.001
0.017
0.002
0.001
0.000
unc
0.118
2.360
2.950
0.000
1.829
0.153
0.018
0.035
0.000
0.708
0.027
0.002
0.001
0.030
0.001
0.010
0.007
0.001
0.001
0.000
0.001
0.003
0.001
0.030
0.000
0.003
0.000
0.041
0.041
0.035
0.002
0.000
0.003
0.000
0.000
0.000
0-10
Xwt
0.611
10.812
26.912
NE
4.119
NE
0.068
0.086
0.000
0.504
0.034
0.010
0.003
0.368
0.003
0.037
0.004
0.006
NE
0.001
0.002
NE
0.007
0.047
NE
0.001
NE
0.552
0.437
0.292
0.028
0.001
0.011
0.001
0.001
NE
umC2}
unc
0.121
2.530
4.525
0.000
1.663
0.000
0.025
0.038
0.001
0.604
0.026
0.007
0.004
0.070
0.003
0.016
0.007
0.006
0.000
0.002
0.003
0.000
0.006
0.031
0.000
0.003
0.000
0.096
0.083
0.061
0.012
0.002
0.007
0.003
0.002
O'.OOO
(0-105
0.790
Total
Measured
Xut
0.384
6.911
11.430
0.153
4.192
0.016
0.035
0.035
0.000
0.365
0.024
0.006
0.001
0.216
0.002
0.024
0.002
0.003
0.000
0.001
0.001
0.000
0.004
0.015
0.005
0.001
0.031
0.333
0.268
0.182
0.017
0.001
0.007
0.001
0.000
0.000
unc
0.064
1.396
1.912
0.036
0.748
0.007
0.007
0.006
O.OQO
0.103
0.008
0.001
0.000
0.040
0.000
0.004
0.001
0.001
0.000
0.000
0.000
0.000
0.001
0.004
0.002
0.000
0.006
0.058
0.052
0.031
0.003
0.000
0.001
0.000
0.000
0.000
262
-------
PM Profile Speciation Report - continued (profile 26205}
Total Participate Hatter *
Species
CAS Number Nun
7440-25-7 73
7439-92-1 82
7440-29-1 90
201
202
203
204
TOTALS!
Sym
Ta
Pb
Th
OC
EC
S04
N03
0-2
%wt
0
0
0
0
38
0
60
NR
.009
.001
.280
.160
.000
.051
.5 un
unc
0.000
0.002
0.000
0.990
0.050
4.000
0.220
2.5-10 urn
Xut
0
0
0
0
.000
.033
.002
NR
.277
NR
NR
unc
0.000
0.013
0.000
0.000
0.071
0.000
0.000
.999 75.660
0-10
%wt
NE
0.019
0.001
NE
0.210
NE
NE
45.188
Total
umC2> Measured
unc
0.000
0.015
0.002
0.000
0.079
0.000
0.000
Xut
0,000
0.010
0.001
0.269
0.165
36.443
0.049
61 .603
unc
0.000
0.003
0.000
0.950
0.053
6.341
0.022
CO No control specified; thus, assumed uncontrolled.
<2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
263
-------
PH Profile Speciation Report
Profile Name Coke Calciner
Profile Number 26206
Data Quality D
Control Device Baghouse
Reference(s) 62
Data Source Baghouse catch dust sampled by operating personnel.
SCC Assignments 30601401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.180 0.370
Total Particulate Natter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
0
0
0
16
0
0
25
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.054
.000
.000
.184
.000
.037
.778
.009
.105
.000
.000
.059
.028
.000
.005
.000
.000
.000
.002
.000
.018
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.005
.5 urn
unc
0.054
0.047
0.060
0.824
0.039
0.037
1.293
0.002
0.007
0.002
0.002
0.005
0.003
0.001
0.001
0.001
0.003
0.001
0.001
0.002
0.003
0.003
0.011
0.007
0.008
0.009
0.012
0.015
0.018
0.041
0.073
0.136
0.001
0.005
2.5-10 un
Xwt
0.150
0.105
0.000
15.272
0.000
0.061
28.154
0.006
0.122
0.002
0.006
0.096
0.035
0.002
0.006
0.000
0.000
0.000
0.004
0.001
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.022
0.000
0.000
0.018
unc
0.051
0.047
0.052
0.816
0.033
0.039
1.410
0.001
0.007
0.002
0.001
0.006
0.002
0.001
0.001
0.000
0.001
0.000
0.001
0.001
0.001
0.001
0.004
0.003
0.003
0.003
0.004
0.005
0.006
0.013
0.024
0.044
0.001
0.002
0-10 urn
Xwt
0.141
0.095
0.000
15.355
0.000
0.058
27.937
0.007
0.120
0.002
0.005
0.093
0.035
0.002
0.006
0.000
0.000
0.000
0.003
0.001
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
0.016
unc
0.037
0.033
0.037
1.089
0.023
0.027
1.826
0.002
0.012
0.002
0.002
0.010
0.005
0.001
0.002
0.000
0.001
0.000
0.002
0.001
0.004
0.001
0.004
0.003
0.003
0.004
0.005
0.006
0.007
0.016
0.029
0.053
0.001
0.004
(0-10)
0.530
Total
Measuredd}
Xwt
0.141
0.095
0.000
15.355
0.000
0.058
27.937
0.007
0.120
0.002
0.005
0.093
0.035
0.002
0.006
0.000
0.000
0.000
0.003
0.001
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
0.016
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
42.284
44.084
43.918
43.918
C1> Estimated / extrapolated.
264
-------
PH Profile Speciation Report
Prof1le Name : Green Coke Oust
Profile Number : 26207
Data Quality : D
Control Device : Uneontrolle
Reference(s) : 62,78
Data Source : Data taken front Reference 62. For details, consult Reference
78,
SCC Assignments: 3060U01
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Partfculata Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-c
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92- 1
apew i e.a
|Ml m
unc
0.012
0.012
0.010
0.059
0.005
0.002
0.005
0.001
0.003
0.001
0.001
0.004
0.003
0.003
0.001
0.001
0.002
0.001
0.001
0.001
0.001
0.002
0.006
0.005
0.004
0.006
0.009
0.009
0.013
0.020
0.057
0.082
0.001
0.004
0.000
(0-103
0.510
Total
Measured
%Ht
0.113
0.122
0.066
0.698
0.000
0.000
0.031
0.000
0.013
0.000
0.000
0.017
0.018
0.008
0.003
0.000
0.000
0.001
0.001
0.001
0.001
0.000
0.000
0.005
0.000
0.000
0.000
0.004
0.025
0.000
0.000
0.000
0.001
0.010
16.966
unc
0.011
0.011
0.010
0.061
0.006
0.002
0.003
0.001
0.001
0.001
0.001
0.003
0.002
0.002
0.001
0.001
0.002
0.001
0.001
0.001
0.001
0.002
0.007
0.006
0.005
0.007
0.010
0.011
0.015
0.023
0.066
0.096
0.001
0.003
3.434
265
-------
PH Profile Speefation Report * continued (profile 26207)
Total Participate Hatter -
Total
0-2.5 urn 2.5-10 urn 0-10 um{2} Measured
Species — > •
CAS Number Nun Sym Xut une Xut unc Xwt unc Xwt unc
202 EC Wt 0.000 80.500 16.100 Ni 0.000 55.51? 11.236
TOTALS: 1.227 106.192 1.133 73.621
•3BaxBS3Szss£==s!ssssasa:&3ss£S£»8£:s==5»s^S7£33saee£=sssffiS8SEaaasE===s;cse!=£=Bss=Es=sKsss5:
C1> No control specified: thus, assumed uncontrolled.
€2} Calculated based on methodology described In the Air Emissions Species Manual,
Volume ft.
266
-------
PM Profile Speciat ion Report
Profile Name Coke Cooler
Profile Number 26208
Data Quality D
Control Device UncontrolledCD
Referenced) 62,78
Data Source Data taken from Reference 62. For detai Is, consult Reference
78.
SCC Assignments; 30601201
Hass Fraction Data - Size Interval (um5 : CO-2.S) {0-65
Mass Fraction : 0.150 0,340
Total Paniculate Hatter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Hum
13
14
15
16
17
19
20
22
23
24
25
26
26
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
Sym
At
Si
P
s
Cl
K
Ca
Ti
¥
Cr
Hn
Fe
Ni •
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
A9
Cd
In
Sn
Sb
Ba
La
Hg
Pb
oc
0-2
Xut
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
,211
.304
.142
.485
.071
.056
.161
.010
.100
.011
.007
.329
.038
.003
.007
.001
.345
.004
.023
.000
.004
.000
.006
.006
.014
.000
.000
.007
.011
.018
.000
.051
.005
.007
.280
.5 urn
unc
0.021
0.056
0.026
0.149
0.101
0.007
0.016
0.002
0.012
0.002
0.007
0.065
0.004
0.001
0.003
0.001
0.219
0.001
0.010
0.001
0.002
0.002
0.009
0.007
0.008
0.009
0.012
0.012
0.015
0.025
0.069
0.102
0.002
0.004
0.328
2.5-10 un
Xwt
0.166
0.169
0.080
0.702
0.000
0.014
0.052
0.004
0.047
0.010
0.003
0.213
0.038
0.000
0.001
0.000
0.051
0.001
0.004
0.000
0.001
0.000
0.000
0.004
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.001
1.300
unc
0.042
0.017
0.018
0.070
0.005
0.002
0.005
0.001
0.005
0.001
0.005
0.057
0.004
0.001
0.001
0.000
0.031
0.001
0.002
0.001
0.001
0.001
0.005
0.004
0.006
0.005
0.006
0.007
0.008
0.013
0.038
0.055
0.001
0.002
0.130
0-10
Xwt
0.179
0.209
0.098
0.932
0.021
0.026
0.084
0.006
0.063
0.010
0.004
0.247
0.038
0.001
0.003
0.000
0.138
0.002
0.009
0.000
0.001
0.000
0.002
0.005
0.007
0.000
0.000
0.002
0.003
0.005
0.000
0.015
0.002
0.003
1.882
unK2>
unc
0.017.
0.021
0.011
0.089
0.004
0.004
0.010
0.001
0.007
0.002
0.001
0.023
0.005
0.000
0.001
0.000
0.018
0.001
0.002
0.000
0.001
0.000
0.000
0.001
0.002
0.000
0.000
0.000
0.001
0.001
0.000
0.003
0.001
0.001
0.187
(0-105
0.510
Total
Measured
Xwt
,0.180
0.211
0.099
0.949
0.023
0.027
0.087
0.006
0.064
0.010
0.004
0.250
0.038
0.001
0.003
0.000
0.144
0.002
0.010
0.000
0.002
0.000
0.002
0.005
0.008
0.000
0.000
0.002
0.003
0.005
0.000
0.016
0.002
0.003
1.920
unc
0.030
0.026
0.020
0.095
0.032
0.003
0.009
0.001
0.006
0.002
0.006
0.060
0,004
0.001
0.001
0.001
0.092
0.001
0.004
0.001
0.001
0.001
0.006
0,005
0.007
0.006
0.008
0.008
0.010
0.017
0.048
0.070
0.001
0.003
0.192
267
-------
PH Profile Specfation Report - continued (profile 26208)
Total Paniculate Matter -
Total
0-2.5 un 2.5-10 in 0-10 un€D Measured
Species ............ ...—...— ...... —... ...... ..
CAS Husber Nun Sym %ut unc Xwt unc %wt unc Xwt une
202 EC 73.900 7.390 94.700 9.470 88.582 6.953 88.100 8.810
TOTALS: 80.617 97.567 92.579 92.176
xs«2asms!CSSSxs:3Ktf8Beaasaia!=^ffis:s===sss=3:zss^5cssss=E=xssa:a3SK^s:sssrs=xsss=:=ssss£:=ase==:£sffi
<1> No control specified; thus, assumed uncontrolled.
{2> Calculated based on methodology described in the Air Emissions Species Manuel,
Volume II.
268
-------
PW Profile Speciaxion Report
Profile Name
profile Number
Data Quality
Catalytic Cracker
26209
D
Composite
Control Device Uncontrolled
Reference(s)
Data Source Profile represents a composite of Profiles 26203, 26204,
and 26205.
SCC Assignments: 30600201
Mass Fraction Data • Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.450 0.700
Total Paniculate Hatter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-92-1
TOTALS:
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
40
50
51
56
57
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
fe
Hi
Cu
Zn
As
Se
Br
Rb
Sr
Zr
Sn
Sb
Ba
La
Pb
15
23
0
2
0
0
0
0
0
0
0
0-2
fat
.430
.702
,150
.057
.153
.119
.144
.716
.155
.040
.022
0.615
0
0
0
0
0
d
0
0
0
.100
.016
.018
.005
.002
.006
.000
.007
.004
0.026
0
0
0
0
43
.058
.011
.312
.053
.921
.5 um
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
%yt
17.397
33.202
0.090
1.569
0.216
0.117
0.218
0.866
0.165
0.044
0.023
0.747
0.087
0.026
0.018
0.001
0.003
0.005
0.005
0.014
0.039
0.004
0.004
0.000
0.821
0.043
55.724
uncd>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt uncC1>
16.256
27.783
0.122
1.858
0.145
0.119
0.176
0.779
0.159
0.042
0.023
0.671
0.093
0.020
0.018
0.003
0.002
0.057
0.002
0.010
0.019
0.023
0.035
0.000
0.535
0.049
48.999
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
xsssssi&xn
(0-10)
0.790
Total
Measured
%wt
14.956
22.622
0.132
1.883
0.102
0.108
0.159
0.733
0.156
0.040
0.022
0.620
0.088
0.020
0.017
0.002
0.002
0.005
0.001
0.009
0.008
0.017
0.035
0.010
0.462
0.046
42.255
uncd}
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C1> Uncertainty not evaluated.
269
-------
270
-------
3.8 PULP AND PAPER INDUSTRY
The most common, wood pulping processes include Kraft, Sulfite, Neutral
Sulfite Semi chemical, and Soda. Chemical wood pulping is the extraction of
cellulose fiber from wood by dissolving the lignin which binds the fibers.
Particulate emissions can arise when fluidized bed reactors are used to burn
spent process liquor. The flue gas contains sodium sulfate and sodium
carbonate dust. The paper products industry includes a variety of wood
working and paper processing operations. Particulate emissions can arise from
sawing and cutting operations among other processes.
271
-------
272
-------
PH Profile Speciotion Report
Profile Name Particle Board Dryer
Profile Nunber 22101
Data Quality B/D
Control Device Hulticyclooes
Reference(s) 45
Data Source Average of 2 samples from one source. Glues used are less
than IX MaC I.
SCC Assignments: 30700703
Mass Fraction Data - Size Interval (ura) : CO-2.5) CQ-6)
Mass Fraction : 0.485 0.390
Total Participate Matter
Species
CAS Nunfcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
Hum
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Sym
Be
B
F
Ma
«9
At
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
As
Cd
Sn
Sb
Cs
0-2.5 urn
Xwt
NA
NA
NA
3.700
NA
<
0.250
NA
1.400
4.500
4.000
0.500
NA
<
<
<
0.090
0.100
NA
<
<
0.060
NA
<
<
<
<
NA
<
' NA
NA
<
NA
<
NA
unc
0.000
0.000
0.000
4.000
0.000
0.000
0.070
0.000
0.200
0.800
0.800
0.100
0.000
0.000
0.000
0.000
0.010
0.010
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
%Ht
NA
NA
NA
0.300
0.040
• <
<
NA
0.030
<
<
0.100
NA
<
<
<
NA
NA
NA
<
<
NA
NA
<
<
<
<
NA
<
NA
NA
<
NA
<
NA
unc
0.000
0.000
0.000
0.100
0.020
0.000
0.100
0.000
0.003
0.000
0.000
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NE
NE
NE
3.282
NE
NE
NE
NE
1.232
NE
NE
0.451
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
3.539
0.000
0.000
0.000
0.000
0.247
0.000
0.000
0.111
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-10)
0.553
Total
Measured
Xwt
NE
NE
NE
3.282
NE
NE
NE
NE
1.232
NE
NE
0.451
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
273
-------
PH Profile Spcciation Report - continued (profile 22101)
Total Particulate Hatter •
Total
0-2.5 urn 2.5-10 urn 0-10 urn Measured
Species —• •—- •— — •-- --
CAS Number Hum Sym Xut unc %ut unc Xwt unc Xwt unc
7440-39-3
7440-45-1
7439-97-6
7439-92-1
56
58
80
82
200
201
202
203
204
la
Ce
Kg
Pb
TC
OC
EC
S04
H03
50
8
3
1
<
<
<
<
NA
.000
.000
.650
.250
0.000
0.000
0.000
0.000
0.000
17.000
5.000
0.600
0.350
«
<
<
<
58.000
NA
NA
0.100
0.500
0.000
0.000
0.000
0.000
17.700
0.000
0.000
0.100
0.200
NE
NE
NE
NE
NE
NE
NE
3.213
1.158
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.700
0.391
NE
NE
NE
NE
NE
NE
m
3.213
1.158
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
TOTALS: 77.500 59.070 9.336 9.336
274
-------
PM Profile Special ion Report
profile Name
Profile Number
Data Quality
Particle Board Dryer
22102
B/D
Control Device Wet Scrubber
ReferenceCs) 45
Data Source Average of 2 samples from one source collected with a
2-stage virtual impactor. High Had due to salcontent of
resin glues.
SCC Assignments: 30700703
Mass Fraction Data - Size Interval
Mass Fraction
Total Particulate Natter
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-6E-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-Z2-4
7440-43-9
7440-31-5
7440-36-0
o}^w I GO
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
ZZ
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
Be
B
f
Na
Ms
Al
Si
P
s
Ct
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ca
Ge
As
Se
Sr
Rb
Sr
Zr
Ag
Cd
Sn
Sb
0-2.5
Cum) : (0-2.5)
: 0.485
urn 2.5-10
Jiwt unc Xwt
NA 0
NA 0
NA 0
18.200 3
< 0
< 0
0.250 0
< 0
1.000 0
23.400 1
1.050 0
0.200 0
< 0
< 0
< 0
< 0
0.020 0
0.020 0
< 0
< 0
< 0
. 0.020 0
< 0
< 0
< 0
< 0
< 0
< 0
< '0
< 0
< 0
< 0
< 0
< 0
.000 NA
.000 NA
.000 NA
.100 17.000
.000 0.400
.000 NA
.070 1.100
.000 NA
.400 1.900
.900 25.000
.070 1.500
.000 1.100
.000 <
.000 <
.000 <
.000 <
.000 <
.030 <
.000 <
.000 <
.000 <
.000 «
.000 <
.000 <
.000 <
.000 <
.000 <
.000 <
.000 <
.000 <
.000 <
.000 <
.000 <
.000 <
un
unc
0.
0.
0.
4.
0.
0.
0.
0.
0.
000
000
000
000
600
000
100
000
500
6.000
0.
0.
0.
0.
0.
0.
0.
0.
300
400
000
000
000
000
000
000
0.000
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
CO-6)
0.390
0-10 un
Xwt
m
m
m
18.052
NE
NE
0.355
NE
1.111
23.597
1.105
0.311
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0
0
0
5
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.407
.000
.000
.176
.000
.622
.965
.353
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
(0-10)
0.553
Total
Measured
Xwt
NE
NE
NE
18.052
NE
NE
0.355
NE
1.111
23.597
1.105
0.311
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.obo
275
-------
PH Profile Speciation Report - continued (profile 22102)
Total Particulate Hatter -
CAS Number
7440-46-2
7440-39-3
7440-45-1
7439-97-fi
7439-92-1
aperies
Hum Sym
55
56
58
80
82
201
202
203
204
Cs
Ba
Ce
Kg
Pb
OC
EC
S04
N03
0-2.5
urn
Xwt unc
< 0
< 0
< 0
< 0
< 0
10.000 5
1 .200 0
3.650 0
1.250 0
.000
.000
.000
.000
.000
.000
.300
.070
.350
2.5-10
Xwt
< 0
< 0
< 0
< 0
< 0
10.000 5
1.200 0
2.200 0
0.500 0
urn
unc
.000
.000
.000
.000
.000
.000
.300
.500
.200
0-10
Xwt
NE
NE
NE
NE
NE
10.000
1.200
3.472
1.158
0
0
0
0
0
6
0
0
0
urn
unc
.000
.000
.000
.000
.000
.445
.428
.690
.391
Total
Measured
Xwt
NE
NE
NE
NE
NE
10.000
1.200
3.472
1.158
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 60.260 61.900 60.361 60.361
276
-------
PM Profile specintion Report
Profile Name
Profile Number
Data Quality
Wood Products - Sanderefust
22201
C/D
Control Device
Reference(s)
Data Source
Cyclone
10
Average of 5 source tests. SASS train with heated Method 5
probe, 3 cyclones; at 400 deg F, Cyclone and filter
catches analyzed by XRF. si, P and S non-quantitative.
SCC Assignments: S07MT02
Mass Fraction Data
Total Participate
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-S4-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
Hum
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
2*
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
- Size
Mass
Matter -
Svm
Be
B
f
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Co
Co
N5
Cu
In
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Interval (urn) :
Fraction :
0-2.5 urn
%wt unc
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.050 0.000
< 0.000
<' 0.000
< 0.000
< 0.000
0.050 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.050 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
(0-2.55
0.300
2.5-10 urn
%wt unc
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.050 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.050 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.050 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
<0-65
0
.430
0-10 urn
Xwt
NE
NE
NE
NE
NE
NE
NE
NE
Ni
NE
NE
0.050
NE
NE
NE
NE
0.050
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
0.050
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-103
0.530
Total
Measured
Xwt unc
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.050 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.050 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.050 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
277
-------
PM Profile Speciation Report - continued
-------
PM Profile Special ion Report
Profile Name Sawdust
Profile Number 22202
Data Quality B/D
Control Device Uncontrolled
Referenee(s) 45
Data Source Grab sample from cyclone
SCC Assignments 30700804
Mass Fraction Data - Size Interval (urn) ;
Mass Fraction :
Total Partieulate
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
apei
Num
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Matter
if es
Sym
Be
B
f
Ne
*9
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
0-2.5 urn
%ut unc
NA 0.000
NA 0.000
NA 0.000
0.240 0.100
< 0.000
.0.180 0.130
0.300 0.400
< 0.000
< 0.000
0,030 0.030
0.030 0.040
0,240 0.140
< 0.000
< 0.000
< 0.000
< 0.000
0.010 0.000
0.210 0.180
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
<> 0,000
< 0.000
. < 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
catch. Average of 6 samples.
(0-2.5) (0-6)
0.485 0.390
2.5-10 urn
Xwt unc
NA 0.000
NA 0.000
NA 0.000
0.240 0.100
< 0.000
0.090 0.090
0.110 0.160
< 0.000
< 0.000
0.140 0,140
0.060 0.030
0.500 0.400
< 0.000
< 0.000
< 0.000
< 0.000
0.010 0.000
0.130 0.110
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0,000
< 0.000
< 0,000
0-10 urn
Xwt
NE
NE
NE
0.240
NE
0.169
0.277
NE
NE
0.044
0.034
0.272
NE
NE
NE
NE
0.010
0.200
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.131
0.000
0.141
0.380
0.000
0.000
0.127
0.045
0.378
0.000
0.000
0.000
0.000
0.000
0.188
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.553
Total
Measured
Xwt
NE
NE
NE
0.240
NE
0.169
0.277
NE
NE
0,044
0.034
0.272
NE
NE
NE
NE
0.010
0.200
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
m
m
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.ODO
279
-------
PN Profile Specfatfon Report - continued (profile 22202)
Total Paniculate Matter
Species
CAS Number
7440-45-1
7439-97-6
7439-92-1
Nun
58
80
82
201
202
203
204
Sym
Ce
Hg
Pb
OC
EC
S04
N03
0-2
%wt
<
<
<
50.000
4.600
NA
NA
.5 an
unc
0.000
0.000
0.000
3.500
1.000
0.000
0.000
2.5-10
Xut
<
<
<
48.000
4.700
NA
NA
0
0
0
5
1
0
0
un
unc
.000
.000
.000
.000
.500
.000
.000
0*10 un
Xwt
HE
NE
NE
49.754
4.612
NE
NE
unc
0.000
0.000
0.000
10.127
1.779
0.000
0.000
Total
Measured
%Nt
NE
NE
NE
49.754
4.612
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 55.840 53.980 55.612 55.612
280
-------
PH Profile Speciation Report
Profile Name Veneer Dryer
Profile Number 22301
Data Quality 8/0
Control Device Uncontrolled
Reference(s) 45
Data Source Average of 6 samples collected from 3 sources with a
2-stage virtual inpactor.
SCC Assignments: 30700701
Mass fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass fraction : 0.180 0.370
Total Particulate Matter
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Sym
Be
i
F
Na
Mg
Al
Si
P
S
Cl
K
Ca
Sc
Tf
V
Cr
Mn
Pe
Co
Ni
Cu
2n
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
0-2.5
urn
%ut unc
NA 0
NA 0
NA 0
NA 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
• < 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
. < 0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
2.5-10
urn
%«t unc
NA 0
NA 0
NA 0
NA 0
< 0
.000
.000
.000
.000
.000
< 0.000
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
< 0.000
< 0
.000
< 0.000
< 0
< 0
.000
.000
< 0.000
< 0
< 0
< 0
< 0
< 0
.000
.000
.000
.000
.000
< 0.000
< 0
.000
< 0.000
< 0
< 0
< 0
.0(30
.000
.000
0-10 urn
Xwt
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
(0-10)
0.130
Total
Measured
Xwt
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
281
-------
PM Profile Spec!ation Report - continued (profile 22301)
Total Participate Matter
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-93-1
Nun Sym
56
58
80
82
201
202
203
204
Ba
Ce
HS
Pb
oc
EC
S04
N03
0-2.5
urn
Xut unc
< 0
< 0
< 0
< 0
81.650 10
0.767 0
NA 0
NA 0
.000
.000
.000
.000
.370
.522
.000
.000
2.5-10
%Ht
< 0
< 0
< 0
< 0
81.650 10
0.767 0
NA 0
NA 0
urn
unc
.000
.000
.000
.000
.370
.522
.000
.000
0-10 un
%wt
NE
NE
NE
NE
81 .650
0.767
NE
NE
unc
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.256
.000
.000
Total
Measured
%Mt
NE
NE
NE
NE
81 .650
0.767
NE
NE
unc
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 82.417 82.417 82.417 82.417
282
-------
PM Profile Speciation Report
Profile Name Kraft Recovery Furnace
Prof i le Member 23103
Data Quality B/C
Control Device ESP and Wet Scrubber
Referenced ) 49
Data Source Average of 4 replicate samples collected from one stack
with a dilution sampler.
SCC Assignments: 30700110
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6}
Nass Fraction : 0.670 0.720
Total ParticuUte Hatter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
opcw. i co
HU« ;,,„
4
5
9
11
13
14
15
16
17
19
*$t\
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
Be
8
F
Na
Al
Si
P
S
Cl
K
t.(3
11
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr '
Mo
Pd
AS
Cd
In
Sn
Sb
Ba
0-2.5 urn
Xwt
1
25
0
0
0
14
1
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NA
NA
.859
.350
.473
.219
.101
.440
.707
.010
.063
.007
.002
.008
.010
.143
.025
.001
.014
.001
.003
.003
.056
.012
.006
.000
.009
,008
.015
.018
.013
,013
0.017
0
0
.010
.097
unc
0.000
0.000
3.100
13.000
0.430
0.170
0.170
1.800
0.380
0.238
0.094
0.006
0.002
0.012
0.012
0.210
0.052
0.001
0.018
0.001
0.003
0.003
0.012
0.004
0,008
0.002
0.011
0.010
0.019
0.019
0.015
0.030
0.020
0.060
0.115
2.5-10 urn
Xwt
NA
NA
1.859
25.350
0.473
0.219
0.101
14.440
1.707
2.010
0.063
0.007
0.002
0.008
0.010
0.143
0.025
0.001
0.014
0.000
0.003
0.003
0.056
0.012
0.006
0.000
0.009
0.008
0.015
0.018
0.013
0.013
0.017
0.010
0.097
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0*10 urn
%ut
NA
NA
1.859
25.350
0.473
0.219
0.101
14.440
1.707
2.010
0.063
0.007
0.002
0.008
0.010
0.143
0.025
0.001
0.014
0.000
0.003
0.003
0.056
0.012
0.006
0.000
0.009
0.008
0.015
0.018
0.013
0.013
0.017
0.010
0.097
unc
0.000
0.000
2.789
12.465
0.393
0.157
0.153
3.040
0.456
0.417
0.085
0.006
0.002
0.011
0.011
0.189
0.047
0.001
0.016
0.000
0.003
0.003
0.015
0.004
0.007
0.001
0.010
0.009
0.017
0.017
0.014
0.027
0.018
0.054
0.104
(0-10)
0.750
Total
Measured
Xwt
NA
NA
1.570
26.740
0.490
0.311
0.135
14.430
1.700
1.960
0.081
0.008
0.002
0.016
0.014
0.147
0.026
0.004
0.017
0.000
0.004
0.005
0.052
0.020
0.005
0.000
0.021
0.010
0.029
0.020
0.018
0.039
0.024
0.026
0.115
unc
0.000
0.000
2.452
10.740
0.367
0.1B7
0.143
1.676
0.334
0.232
0.076
0.005
0.002
0.010
0.010
0.168
0.042
0.004
0.014
0.001
0.003
0.004
0.010
0.007
0.007
0.001
0.023
0.010
0.015
0.022
0.013
0.061
0.018
0.059
0.102
283
-------
PH Proffie Speciation Report - continued (profile 23103) '
Total Particulate Hatter -
Total
0*2.5 urn 2.5-10 un 0-10 urn Measured
Species ............ .... .... .. ,
CAS Number Nun Sym Xwt unc Xwt unc Xwt unc Xwt unc
7439-91-0
7439-97-6
7439-92-1
57
80
82
201
202
203
204
La
Hg
Pb
OC
EC
S04
H03
0
0
0
1
0
51
0
.114
.001
.016
.951
.042
.038
.101
0.131
0.003
0.020
0.250
0.050
9.000
0.170
0.114
0.001
0.016
1.951
0.042
51.038
0.101
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.114
0.001
0.016
1.951
0.042
51.038
0.101
0.122
0.003
0.018
0.414
0.045
12.157
0.153
0.218
0.002
0.026
2.567
0.142
48.812
0.126
0.217
0,003
0.017
0.320
0,132
7.379
0.144
TOTALS: 99.976 99.975 99.975 99.932
284
-------
PN Profile Special ion Report
Profile Name Lime Kiln
Profile Number 21202
Data Quality B/C
Control Device Wet Scrubber
Referenced ) 49
Data Source Average of 3 replicate samples from a single stack using a
dilution sampler with a 2-stage virtual impactor.
SCC Assignments: 30700106
Mass Fraction Data - Size Interval (urn) ; (0-2.5) (0-6)
Mass Fraction : 0.960 0.980
Total Paniculate
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7440-45-1
ape>
Nun
4
5
9
11
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
39
40
42
46
47
48
50
51
56
57
58
Matter
sies
Syn
Be
B
F
Na
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Nn
Fe
Ni
Cu
Zrt
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
Sn
Sb
Ba
La
Ce
*
0-2
Xwt
0
36
0'
0
0
16
2
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NA
NA
.038
.210
.064
.038
.105
.520
.618
.299
.342
.004
.068
.011
.015
.041
.032
.005
.006
.003
.003
.024
.006
.003
.003
.012
.004
.006
.027
.015
.047
.019
.029
.099
.118
.5 un
unc
0.000
0.000
0.007
4.000
0.074
0.042
0.227
1.780
0.282
0.140
0.037
0.003
0.007
0.003
0.003
0.009
0.005
0.004
0.002
0.007
0.002
0.004
0.004
0.005
0.003
0.012
0.009.
0.006
0.020
0.015
0.032
0.019
0.029
0.107
0.127
2.5-10 urn
Xwt
NA
NA
0.038
36.210
0.064
0.038
0.105
16.520
2.618
1.299
0.342
0.004
0.068
0.011
0.015
0.041
0.032
0.005
0.006
0.003
0.003
0.024
0.006
0.003
0.003
0.012
0.004
0.006
0.027
0.015
0.047
0.019
0.029
0.099
0.118
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NA
NA
0.038
36.210
0.064
0.038
0.105
16.520
2.618
1.299
0.342
0.004
0.068
0.011
0.015
0.041
0.032
0.005
0.006
0.003
0.003
0.024
0.006
0.003
0.003
0.012
0.004
0.006
0.027
0.015
0.047
0.019
0.029
0.099
0.118
unc
0.000
0.000
0.010
8.104
0.074
0.042
0.223
3.676
0.583
0.289
0.076
0.003
0.015
0.004
0.004
0.012
0.008
0.004
0.002
0.007
0.002
0.006
0.004
0.005
0.003
0.012
0.009
0.006
0.020
0.015
0.033
0.019
0.029
0.107
0.127
(0-10)
0.980
Total
Measured
Xwt
NA
NA
1.296
34.680
0.303
0.200
0.175
16.040
2.630
1.280
0.390
0.004
0.063
0.015
0.022
0.066
0.047
0.006
0.013
0.005
0.005
0.023
0,011
0.009
0.005
0.020
0.033
0.015
0.068
0.026
0.069
0.032
0.049
0.169
0.201
Unc
0.000
0.000
0.240
3.681
0.094
0.056
0.195
1.703
0.326
0.136
0.042
0.003
0.007
0.004
0.004
0.012
0.006
0.004
0.003
0.007
0.003
0.004
0.005
0.006
0.003
0.014
0.019
0.012
0.025
0.018
0.038
0.023
0.035
0.127
0.151
285
-------
PH Profile Speeiation Report - continued (profile 23202)
Total Participate Matter -
Total
0-2.5 urn 2.5-10 un 0-10 un Measured
Specjes —• •••
CAS Number Nun Sym Xut unc Xut unc Xut unc %wt unc
7439-97-6
7439-92-1
80
82
201
202
203
204
Hg
Pb
OC
EC
S04
K03
0
0
9
0
48
0
.002
.018
.280
.464
.830
.092
0.004
0.011
1.000
0.500
8.000
0.100
0.002
0.018
9.280
0.464
48.830
0.092
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.013
9.280
0.464
48.830
0.092
0.004
0.011
2.065
0.498
12.367
0.100
0.004
0.023
10.120
0.576
47.197
0.150
0.005
0.013
1.724
0.481
6.881
0.113
TOTALS: 116.520 116.520 116.520 116.040
286
-------
PM Profi U Speciation Report
Profile Name
Profile Number
Data Quality
Sulfite Recovery Soiler
24101
i/C
Control Device : Uncontrolled
Reference(s) : 46
Data Source : Sampled with a 2-stage virtual inpactor with a Method 5
heated probe. Analysis by XRF, INNA, 1C and carbon
oxidation. 'No dilution air. Average of 2 samples from 2
plants.
SCC Assignments: 30700234
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
CAS Nunfcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
9fjt?i~ i «&
Hum Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
Be
B
f
Na
Mg
At
Si
p
s
Cl
1C
Ca
Sc
Ti
V
Cr
Mr,
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
0-2.5 urn
Xwt
2
0
0
12
0
30
2
0
0
0
0
0
NA
NA
NA
.500
.730
<
.400
<
.000
.580
,000
.000
<
.010
<
<
.054
.066
<
<
.016
.017
<
<
<
<
<
<
<
<
<
<
<
unc
0.000
o.ooo-
0.000
0.800
0.520
0.000
0.150
0.000
2.000
0.100
10.000
0.200
0.000
0.001
0.001
0.001
0.070
0.036
0.000
0.001
0.017
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.780
2.5-
%wt
NA
NA
NA
2.500
0.730
<
0.400
<
12.000
0.580
30.000
2.000
<
0.010
<
<
0.054
0.066
<
<
0.016
0.017
<
<
<
<
<
<
<
<
<
<
<
10 urn
unc
0.000
0.000
0.000
0.800
0.520
0.000
0.150
0.000
2.000
0.100
10.000
0.200
0.000
0.001
0.001
0.001
0.070
0.036
0.000
0.001
0.017
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.880
0-10 urn
%wt
NE
NE
Ni
2.500
0.730
NE
0.400
NE
12.000
0.580
30.000
2.000
NE
0.010
NE
NE
0.054
0.066
NE
NE
0.016
0.017
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.984
0.597
0.000
0.180
0.000
2.952
0.146
0.000
0.390
0.000
0.002
0.000
0.000
0.079
0.042
0.000
0.000
0.019
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.980
Total
Measured
Xwt
NE
NE
NE
2.500
0.730
NE
0.400
NE
12.000
0.580
30.000
2.000
NE
0.010
NE
NE
0.054
0.066
NE
NE
0.016
0.017
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
207
-------
PH Profile Speciation Report - continued (profile 24101)
Total Particulate Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 urn Measured
Species •
CAS Number Hum Sym Xwt unc Xut unc Xwt unc %ut unc
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
51
55
56
58
80
82
201
202
203
204
Sb
Cs
Bo
Ce
H3
Pb
OC
EC
S04
N03
< 0
< 0
< 0
< 0
< 0
< 0
NA 0
NA 0
56". 000 11
0.300 0
.000
.000
.000
.000
.000
.030
.000
.000
.200
.060
< 0
< 0
< 0
< 0
< 0
< 0
NA 0
NA 0
56. "000 11
0.300 0
.000
.000
.000
.000
.000
.030
.000
.000
.200
.060
NE
NE
NE
NE
NE
NE
NE
NE
56.000
0.300
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.083
NE
NE
NE
NE
NE
NE
NE
NE
56.000
0.300
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
TOTALS: 104.673 104.673 104.673 104.673
288
-------
3.9 SURFACE COATING OPERATIONS
Surface coating"operations primarily involve the application of paint,
varnish/shellac, lacquer, enamel, or paint primer for surface decoration
and/or protection before products are marketed. Adhesives, as the name
implies, involve the application of a bonding agent for the purpose of
adhering materials together. A number of basic industrial coating operations
are utilized, including spraying, flowcoating, roller coating, dipping, and
electro-coating. There are variations and combinations of these operations,
each designed for a special task. The coatings applied in these operations
vary widely as to composition and physical properties. In order to accelerate
the drying of the solvents used in the surface coatings, a drying or baking
operation is usually an integral part of the basic coating process.
289
-------
290
-------
PH Profile Spec!ation Report
Profile Name
Profile Number
Data Quality
Paint Spray Sooth
25403
D/E
Control Device : Uater Spray Booth
ReferenceCs} s 10
Data Source : SASS train with Method 5 probe, I cyclones at 400 cteg F.
Cyclone and filter catches analyzed by XRF. Si, P, and S
non-quantitative. Analysis of one sample downstream of
control device. Carbon value estimated.
SCC Assignments: 40200101
Mass Fraction Data - Size Interval
0.380
<0-10)
0.470
Total
0-2
Xwt
NA
NA
NA
NR
NR
NR
<
<
0.660
<
<
0.550
<
3.000
<
0.050
<
0.550
<
0.050
0.050
0.050
<
<
<
<
0.050
<
<
<
<
0.050
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
NA
NA
NA
NR
NR
NR
<
<
0.660
<
<
0.550
<
3.000
<
0.050
<
0.550
<
0.050
0.050
0.050
<
<
<
<
0.050
•<
<
<
<
0.050
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NE
NE
NE
NE
NE
NE
NE
NE
0.660
NE
NE
0.550
NE
3.000
NE
0.050
NE
0.550
NE
0.050
0.050
0.050
NE
NE
NE
NE
0.050
NE
NE
NE
NE
0.050
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
%wt
NA
NA
NA
NR
NR
NR
<
<
0.660
<
<
0.550
<
3.000
<
0.050
<
0.550
<
0.050
0.050
0.050
<
<
<
<
0.050
"<
<
<
<
0.050
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
291
-------
PH Profile Speciation Report - continued (proffie 25403)
Total Participate Hatter
Spec-ies
CAS Nunfcer
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Nun
51
55
56
58
80
82
201
202
203
204
Sym
Sb
Cs
Ea
Ce
Ha
Pb
OC
EC
S04
NQ3
0-2
Xwt
<
<
<
<
<
<
40.000
10.000
2.000
0.050
.5
0
0
0
0
0
0
0
0
0
0
um
unc
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
2.5-10
*rt
< 0
'< 0
< 0
< 0
< 0
< 0
40.000 0
10.000 0
2.000 0
um
unc
.000
.000
.000
.000
.000
.000
.000
.000
.000
0.050 0.000
0-10 um
XMt
NE
NE
NE
NE
NE
NE
40.000
10.000
2.000
0.050
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
%wt unc
< 0
< 0
< 0
< 0
< 0
< 0
40.000 0
10.000 0
2.000 0
0.050 0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
TOTALS! 57.110 57.110 57.110 57.110
292
-------
3.10 SOLID WASTE DISPOSAL
Solid waste sources can be industrial, urban, agricultural, or
construction. Solid waste may be disposed of In landfills or land application
units or incinerated, A large percentage of urban and industrial waste is
burned. Waste burning processes include open burning and controlled and
uncontrolled incineration where significant particulate emissions may be
generated.
2S3
-------
294
-------
PM Profile Speeiation Report
Profile Name Municipal Incinerator (Philadelphia)
Profile Nunber 17105
Data Quality B/D
Control Device ESP( Inoperative)
Reference(s) 52
Data Source Dilution sampler. Representative sample from group of
SCC Assignments 50100101
Mass Fraction Pets - Sirs Interval {urn) ; (0-2.5) <0-6)
Mass Fraction : 0.260 0.310
Total Paniculate Matter -
Species
CAS Nuifcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
22
29
30
31
32
33
34
35
37
38
40
42
48
50
51
55
56
Sym
Be
B
f
Na
Kg
Al
si
p
s
Cl
K
Ca
Sr
Ti
V
Cr
Hn
Fe
Co
*; *
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ho
cd
Sn
Sb
Cs
Ba
0-2
Xwt
0
1
0
1
21
6
0
0
0
0
0
Q
0
0
11
0
0
0
0
0
0
0
0
0
0
0
0
NA
NA
NA
NA
NA
.819
.442
.543
.906
.299
.464
.223
<
.012
.000
.015
.018
.279
<
n?1*
.148
.503
.016
<
.000
.003
.563
.016
.009
.000
.036
.284
.829
.442
<
.020
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.117
0.067
0.098
0.301
0.985
0.305
0.030
0.000
0.003
0.001
0.001
0.001
0.013
0.000
0.002
0.007
0.525
0.011
0.000
0.031
0.011
0.027
0.002
0.002
0.014
0.003
0.016
0.041
0.028
0.000
0.029
2.5-10 urn
%Ht
NA
NA
NA
NA
NA
5.827
8.570
0.894
3.487
16.678
4.491
5.870
<
1.097
0.024
0.111
0.091
1.874
<
0.085
0.053
4.012
0.000
<
0.000
0.003
0.375
0.005
0.023
0.000
0.003
0.024
0.004
0.086
<
0.000
unc
0.000
0.000
o.ooo
0.000
0.000
0.466
0.581
0.299
0.601
2.218
0.640
0.381
0.000
0.069
0.008
0.009
0.008
0.129
0.000
0.010
0.015
0.918
0.022
0.000
0.071
0.020
0.057
0.008
0.008
0.039
0.023
0.049
0.089
0.113
0.000
0.242
0-10 urn
%wt
NE
NE
NE
NE
NE
2.400
3.693
0.654
2.405
19.840
5.841
2.006
NE
0.355
0.008
0.045
0.041
0.783
NE
0.049
0.118
9.137
0.011
NE
0.000
0.003
0.504
0.013
0.013
0.000
0.026
0.202
0.568
0.330
NE
0.014
unc
0.000
0.000
0.000
0.000
0.000
0.657
0.931
0.238
0.599
3.100
0.903
0.626
0.000
0.116
0.006
0.012
0.011
0.204
0.000
0.011
0.019
1.383
0.017
0.000
0.053
0.016
0.078
0.006
0.006
0.028
0.016
0.045
0.105
0.091
0.000
0.167
10.
(0-10J
0.380
Total
Measured
%wt
NE
NE
NE
NE
NE
2.400
3.693
0.654
2.405
19.840
5.841
2.006
NE
0.355
0.008
0.045
0.041
0.783
NE
0.049
0.118
9.137
0.011
NE
0.000
0.003
0.504
0.013
0.013
0.000
0.026
0.202
0.568
0.330
Ni
0.014
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
295
-------
PM Profile Speeiation Report • - continued (profile 17105)
Total Paniculate Hatter -
Species
CAS Number Nun Syro
Total
0-2.5 urn 2.5-10 urn 0-10 un Measured
Sfat unc %Mt unc Xut unc %wt unc
7440-45-1
7439-97-6
7439-92-1
58
80
82
201
202
203
204
Ce
HO
Pb
OC
EC
S04
N03
<
0.009
8.116
NA
NA
HA
NA
0.000
0.004
0.371
0.000
0.000
0.000
0.000
<
0.011
2.428
NA
NA
NA
NA
0.000
0.012
0.633
0.000
0.000
0.000
0.000
NE
0.010
6.320
NE
NE
NE
NE
0.000
0.009
0.961
0.000
0.000
0.000
0.000
NE
0.010
6.320
NE
NE
NE
NE
0.000
0.000
0.000
0.000
0,000
0.000
0.000
TOTALS: 55.046 56.126 55.389 55.389
296
-------
PM Profile Special ion Report
Profile Name
Profile Number
Data Quality
Municipal Incinerator Composite
17106
B/E
Control Device
Reference(s)
Data Source
ESP, Baghouse, and Scrubbers
Not specified
Composite profiles of 17101, 17102, 17103, and 17104.
(Note: These profiles were not included in the Receptor
Model Source Composition Library.)
SCC Assignments: 50100101
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
Sym
Be
B
F
Na
Mg
Al
Si
P
s
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ca
Ce
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
0-2
%Ht
9
1
1
4
NA
NA
NA
.550
.420
.170
<
<
.300
22.300
5.000
0
0
0
0
0
0
0
0
11
0
.767
<
.193
.000
.036
.083
.627
<
.014
.180
.800
<
<
.020
<
0.166
0
0
0
0
<
<
<
.025
.115
.885
.168
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
i (0-2.5)
; 0.260
2.5-10 urn
%ut
NA
NA
NA
9.550
1.420
1.170
<
<
4.300
22.300
5.000
0.767
<
0.193
0.000
0.036
0.083
0.627
<
0.014
0.180
11.800
<
<
0.020
<
0.166
<
<
<
0.025
0.115
0.885
0.168
we
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.310
0-10 urn
Xwt
NA
NA
NA
9.550
1.420
1.170
<
<
4.300
22.300
5.000
0.767
<
0.193
0.000
0.036
0.083
0.627
<
0.014
0.180
11.800
<
<
0.020
<
0.166
<
<
<
0.025
0.115
0.885
0.168
unc
0.000
0.000
0.000
1.307
0.194
0.160
0.000
0.000
0.588
3.052
0.684
0.105
0.000
0.026
0.000
0.005
0.011
0.086
0.000
0.002
0.025
1.615
0.000
0.000
0.003
0.000
0.023
0.000
0.000
0.000
0.003
0.016
0.121
0.023
(0-10)
0.380
Total
Measured
Xwt
NA
NA
NA
9.550
1.420
1.170
<
<
4.300
22.300
5.000
0.767
<
0.193
0.000
0.036
0.083
0.627
<
0.014
0.180
11.800
<
<
0.020
<
0.166
<
<
<
0.025
0.115
0.885
0.168
unc
0.000
0.000
0.000
1.800
1.150
0.590
0.000
0.000
7.500
4.300
10.000
1.330
0.000
0.127
0.001
0.023
0.062
0.286
0.000
0.006
0.017
0.350
0.000
0.000
0.004
0.000
0.097
0.000
0.000
0.000
0.023
0.047
0.577
0.078
297
-------
PH Profile Speeiatfon Report - continued {profile 17106)
Total Participate Natter
Species
CAS Nwber
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Nun
55
56'
58
80
82
201
202
203
204
Sym
Cs
Ba
Ce
Kg
Pb
OC
EC
S04
N03
0-2
fet
0.004
0.007
<
5.330
8.230
NA
NA
NA
NA
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-
XUt
0.004
0.007
<
5.330
8.230
NA
NA
NA
NA
10 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.004
0.007
• <
5.330
8.230
NA
NA
NA
NA
0
0
0
0
1
0
0
0
0
un
unc
.001
.001
.000
.729
.126
.000
.000
.000
.000
Total
Measured
Xwt
0.004
0.007
<
5.330
8.230
NA
NA
NA
NA
unc
0.004
0.010
0.000
9.230
1.400
0.000
0.000
0.000
0.000
TOTALS:
72.390
72.390
72.390
72.390
298
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Municipal incinerator (East Chicago,IN)
17107
E
Control Device
Reference(s)
Data Source
Spray chamber and 3-stage scrubbing tower.
64,74
Samples collected according to EPA incinerator method (HNQ3
impingers) and with Andersen impactors. Analyzed by INAA and
AA.
SCC Assignments: 50100101
Mass Fraction Data - Size Interval Cum)
Mass Fraction
Total Particulate Matter
Species
CAS Number
7440-23-5
7439-95-4
7782-50-5
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-19-9
7440-57-5
7439-92-1
7440-29-1
Hum
11
12
17
24
25
26
27
28
29
30
33
34
35
47
48
49
50
51
55
56
57
62
79
82
90
Sym
Na
Mg
Cl
Cr
Nn
Fe
Co
Ni
Cu
In
As
Se
Br
ftg
Cd
In
Sn
Sb
Cs
Ba
La
Sffl
Au
Pb
Th
0-2.5
%wt
8.
2.
27.
0.
0.
0.
0.
0.
0.
11.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
6.
0.
200
800
000
010
027
330
000
008
170
400
020
005
088
011
150
001
290
160
001
022
000
000
000
900
000
um{1}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: 0
2.5-10
Xwt
8.200
2.800
27.000
0.010
0.027
0.330
0.000
o.oos
0.170
11.400
0.020
0.005
0.088
0.011
0.150
0.001
1.290
0.160
0.001
0.022
0.000
0.000
0.000
6.900
0.000
.260
umCU
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6}
0.310
0-10
%wt
8.200
2.800
27.000
0.010
0.027
0.330
0.000
0.008
0.170
11.400
0.020
0.005
0.088
0.011
0.150
0.001
1.290
0.160
0.001
0.022
0.000
0.000
0.000
6.900
0.000
umCD
unc
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.380
Total
Measured
%wt
8.200
2.800
27.000
0.010
0.027
0.330
0.000
0.008
0.170
11.400
0.020
0.005
0.088
0.011
0.150
0.001
1 .290
0.160
0.001
0.022
0.000
0.000
0.000
6.900
0.000
unc
1.300
0.800
3.000
0.002
0.008
0.150
0.000
0.003
0.030
2.800
0.009
0.004
0.039
0.008
0.040
0.000
0.160
0.080
0.000
0.013
0.000
0.000
0.000
1.000
0.000
TOTALS: 58.593
€1> Estimated / extrapolated.
58.593
58.593
58.593
299
-------
PH Profile Speciation Report
Profile Name Municipal Incinerator (Philadelphia)
Profile Number 17108
Data Quality E
Control Device UncontrolledCD
Reference(s) £2,63
Data Source Data taken •from Reference 62. for details, consult Reference
63.
SCC Assignments; 50100101
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass fraction : 0.260 0.310
Total Participate Hatter -
CAS Nuber
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-58-6
OptSb 1 CO
Nun Sym
11
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
33
34
35
37
38
40
42
47
48
49
50
51
55
56
57
58
62
72
No
Al
Si
P
S
cl
K
Ca
Ti
V
Cr
Hn
Fe
Co
Nf
Cu
zn
As
So
Br
Rb
Sr
Zr
No
Ag
Cd
In
Sn
sb
Cs
Ba
La
Co
Sm
Hf
0-2
%Ht
6.
0.
1.
• 0.
2.
27.
7.
0.
0.
0.
0.
0.
0.
0.
0.
0.
9.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
200
230
700
630
900
000
600
230
030
001
009
016
220
000
029
120
BOO
007
004
230
022
009
029
038
007
110
001
670
140
001
083
000
NR
NR
NR
.5 urn
unc
3.200
0.100
0.300
0.120
0.800
4.000
2.300
0.100
0.015
0.001
0.003
0.003
0.050
0.000
0.004
0.004
0.500
0.003
0.001
0.080
0.004
0.001
0.002
0.004
0.001
0.060
0.000
0.190
0.080
0.000
0.042
0.000
0.000
0.000
0.000
2.5-10 urn
%Kt
5.700
5.200
8.600
0.900
3.200
15.000
4.500
11.200
1.500
0.010
0.110
0.095
1.600
0.003
0.110
0.073
4.200
0.006
0.007
0.120
0.009
0.036
NR
0.011
O.OOS
0.079
0.001
1.460
0.049
0.000
NR
0.002
0.001
0.000
0.000
unc
0.800
0.600
2.000
0.140
0.700
3.000
0.600
0.600
0.300
0.004
0.040
0.005
0.200
0.001
0.050
0.021
3.300
0.006
0.002
0.050
0.004
0.009
0.000
O.OOS
0.001
0.023
0.000
0.080
0.049
0.000
0.000
0.000
0.001
0.000
0.000
0-10
%ut
6.042
1.799
3.879
0.715
2.995
23.211
6.621
3.694
0.494
0.004
0.041
0.041
0.656
0.001
0.055
0.105
8.032
0.006
0.005
0.195
0.018
0.017
NE
0.029
0.007
0.100
0.001
0.919
0.111
0.000
NE
0.001
NE
NE
NE
umC2>
unc
0.961
0.567
0.953
0.128
0.492
3.586
1.026
1.211
0.169
0.004
0.018
0.017
0.182
0.002
0.019
0.020
1.249
0.003
0.004
0.034
0.005
0.009
0.000
0.006
0.004
0.020
0.001
0.183
0.020
0.001
0.000
0.002
0.000
0.000
0.000
<0-10)
0.380
Total
Measured
Xwt
6.148
0.748
2.419
0.658
2.931
25.750
7.277
1.373
0.183
0.002
0.019
0.024
0.364
0.001
0.037
0.115
9.217
0.007
0.004
0.219
0.021
0.012
0.026
0.035
0.007
0.107
0.001
0.752
0.131
0.001
0.074
0.000
0.000
0.000
0.000
unc
2.973
0.130
0.431
0.136
0.810
4.910
2.267
0.166
0.038
0.001
0.005
0.004
0.062
0.000
0.008
0.016
1.331
0.003
0.001
0.077
0.005
0.002
0.004
0.006
0.002
0.056
0.000
0.193
0.074
0.000
0.039
0.000
0.000
0.000
0.000
300
-------
PM Profile Speciation Report - continued (profile 17108)
Total Paniculate Hatter -
Total
0-2.5 urn 2.5-10 un 0-10 un€2> Measured
CAS Nunber Nun Sym Xwt unc Xut unc Xut unc Xut unc
7439-92-1
7440-29-1
82
90
201
202
203
Pb
Th
OC
6C
S04
5
0
3
6
.800
NR
.570
300
.800
1.200
0.000
0.230
0.200
2.300
1.700
0.000
0.570
2.300
12.000
0.500
0.000
0.230
0.500
3.000
4.505
NE
0.570
3.121
8.442
0.713
0.000
0.097
0.4B7
1.526
5.373
0.000
0.570
3.375
7.342
1.288
0.000
0.220
0.474
2.269
TOTALS: 74.736 80.360 76.432 75.323
€1} No control specified: thus, assumed uncontrolled.
C2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume H.
301
-------
PH Profile Speciation Report
Profile Name Car Shredder
Prof i le Number 17109
Data Quality E
Control Device UncontroU«d€1>
Reference(s) 62,93
Data Source Data taken from Reference 62. For details, consult Refrence
93.
SCC Assignments! 31401101, 31401102
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.390 0.480
Total Particulate Matter -
CAS Number
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7439-92-1
Hum Sym
9
11
12
13
14
16
17
19
20
22
23
24
25
26
28
29
30
35
82
201
202
203
204
F
Na
Hg
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Hi
Cu
Zn
Br
Pb
OC
EC
S04
N03
TOTALS:
0-2
Xwt
0.
0.
0.
0.
0.
0.
0.
0.
: 0.
0.
0.
0.
0.
5.
0.
0.
2.
0.
0.
7.
0.
0.
0.
21.
050
180
100
470
870
470
680
270
480
025
001
040
088
760
031
100
100
490
490
700
600
290
150
435
.5 \m
unc
0.050
0.240
0.100
0.064
0.190
0.085
0.460
0.180
0.057
0.025
0.001
0.004
0.045
0.980
0.007
0.014
0.210
0.350
0.049
3.300
0.060
0.030
0.150
2.5-10 urn
Xwt
0.000
HR
. NR
1.900
HR
NR
8.700
NR
5.500
NR
NR
0.000
0.078
3.700
0.000
0.990
0.870
8.400
0.000
31.000
4.000
0.000
0.000
65.133
unc
5.000
0.000
0.000
0.350
0.000
0.000
0.790
0.000
0.710
0.000
0.000
2.000
0.100
1.100
0.001
0.300
0.120
1.100
0.005
2.800
4.200
6.000
15.000
0-10 urn
Xwt
0.035
NE
NE
0.886
NE
NE
3.013
NE
1.940
NE
NE
0.028
0.085
5.161
0.022
0.359
1.742
2.791
0.347
14.478
1.589
0.206
0.106
32.788
unc
4.211
0.000
0.000
0.338
0.000
0.000
0.979
0.000
0.727
0.000
0.000
1.684
0.092
1.324
0.006
0.268
0.288
1.140
0.060
4.068
3.550
5.053
12.632
(0-10)
0.550
Total
Measured
%wt
0.197
NR
NR
0.556
NR
NR
1.161
NR
0.781
NR
NR
0.098
0.087
5.636
0.029
0.153
2.026
0.965
0.461
9.098
0.804
0.453
0.591
23.096
unc
0.157
0.000
0.000
0.064
0.000
0.000
0.436
0.000
0.078
0.000
0.000
0.060
0.043
0.924
0.007
0.022
0.203
0.336
0.046
3.108
0.258
0.182
0.472
CO No control specified: thus, assumed uncontrolled.
3U2
-------
PM Profile Speciation Report
Profile Name Sewage Sludge Incineration - Composite
Prof i le Number 17120
Data Quality 0
Control Device Scrubber
Reference(s) 60
Data Source Composite of profiles 17121, 17122, 17123, and 17124.
SCC Assignments 50100506
Mass Fraction Data - Size Interval Cum} : (0-2.5) (0-6}
Mass Fraction : 0.240 0.320
Total Particulate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09*7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
42
48
50
51
55
56
Synt
Be
B
F
Na
Mg
Al
Si
P
S
Cl
K
Ca
sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
ir
Rb
Sr
Zr
Mo
Cd
Sn
Sb
Cs
Ba
1
0
1
4
3
6
1
0
5
0
0
0
0
5
0
0
0
0
0
1
0
0
0-2
Art
NR
NR
NR
.410
.650
.800
.770
.260
.330
.480
.960
.070
NR
.440
.180
.580
.210
.380
NR
NR
.880
.361
NR
NR
NR
.150
.380
NR
NR
NR
NR
.830
.390
.050
NR
.270
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-
Xut
NR
NR
NR
1.410
0.650
1.800
4.770
3.260
6.330
1.480
0.960
5.070
NR
0.440
0.180
0.580
0.210
5.380
NR
NR
0.880
0.361
NR
NR
NR
0.150
0.380
NR
NR
NR
NR
0.830
1.390
0.050
NR
0.270
10 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.QOO
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NR
NR
NR
1.410
0.650
1.800
4.770
3.260
6.330
1.480
0.960
5.070
NR
0.440
0.180
0.580
0.210
5.380
NR
NR
0.880
0.361
NR
NR
NR
0.150
0.380
NR
NR
NR
NR
0.830
1.390
0.050
NR
0.270
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-10J
0.420
Total
Measured
%ut
NR
NR
NR
1.410
0.650
1.800
4.770
3.260
6.330
1.480
0.960
5.070
NR
0.440
0.180
0.580
0.210
5.380
NR
NR
0.880
0.361
NR
NR
NR
0.150
0.380
NR
NR
NR
NR
0.830
1.390
0.050
NR
0.270
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3U3
-------
PH Profile Speciation Report - continued (profile 17120)
Total Paniculate Hatter -
0-2.5 urn 2.5*10 un 0-10 urn
Xwt unc Xwt , unc %ut unc
Total
Measured
Species
CAS Number Hum Sym
%ut
unc
7440-45-1
7439-97-6
7439-92-1
58
80
82
201
202
203
204
Ce
Hg
Pb
oc
EC
S04
N03
NR
NR
2.940
NR
NR
NR
NR
0.000
0.000
0.000
0.000
0.000
0.000
0.000
NR
NR
2.940
NR
NR
NR
NR
0.000
0.000
0.000
0.000
0.000
0.000
0.000
NR
NR
2.940
NR
NR
NR
NR
0.000
0.000
0.000
0.000
0.000
0.000
0.000
NR
NR
2.940
NR
NR
NR
NR
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
39.771
39.771
39.771
39.771
304
-------
Wf Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Sewage Sludge Incineration
17121
0
Control Device
Reference(s)
Data Source
Scrubber
60
Swples collected with a modified EPA Method S train were
analyzed by X-ray fluorescence for elemental composition.
Particle size distribution data Mere collected by cascade
fnpactors. Data reflect average of tests conducted at a
seven-ehanfcered multiple-hearth furnace.
. SCC Assignments: 50100506
Mass Fraction Data - Size interval (urn) :
Mass Fraction :
Total Particulate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-43-9
Hum
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
42
48
Sym
Be
B
f
Ha
MB
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Mo
Cd
0-2
Xwt
2
0
1
4
4
. 5
1
1
6
0
0
0
0
2
6
0
NR
NR
NR
.760
.710
.020
.690
.690
.250
.800
.710
.200
NR
.220
.280
.770
.210
.910
NR
NR
NR
.440
NR
NR
NR
NR
NR
NR
NR
NR
NR
.330
.5 urn
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
! (0-2. 55
: 0.250
2.5-10 un
Xwt
NR
m
NR
2.760
0.710
1.020
4.690
4.690
5.250
1.800
1.710
6.200
NR
0.220
0.280
0.770
0.210
2.910
NR
NR
NR
6.440
NR
NR
NR
NR
NR
NR
NR
NR
NR
0.330
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.280
0-10 un
Xwt
NR
NR
NR
2.760
0.710
1.020
4.690
4.690
5.250
1.800
1.710
6.200
NR
0.220
0.280
0.770
0.210
2.910
NR
HR
NR
6.440
NR
NR
NR
NR
NR
NR
NR
NR
NR
0.330
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.280
Total
Measured
Xwt
NR
NR
NR
2.760
0.710
1.020
4.690
4.690
5.250
1.800
1.710
6.200
NR
0.220
0.280
0.770
0.210
2.910
NR
NR
NR
6.440
NR
NR
NR
NR
NR
NR
NR
NR
NR
0.330
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
305
-------
PM Profile Speciation Report - continued (profile 17121}
Total Participate Hatter -
CAS Number
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Nun Sym
50
51
55
56
58
80
82
201
202
203
204
TOTALS:
Sn
Sb
Cs
Ba
Ce
flg
Pb
OC
EC
S04
N03
0-2.5 m
Xut
1.420
0.050
NR
0.080
m
m
4.070
MR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.S-10 urn
Xwr
1.420
0.050
NR
o.oao
NR
MR
4.070
NR
NR
NR
NR
45.610 45.610
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
%Ht
1.420
0.050
NR
0.080
NR
NR
4.070
NR
NR
NR
NR
urn
unc
0.000 1
0
0
0
0
0
0
0
0
0
0
45.610
.000 0
.000
.000 0
.000
.000
.000 4
.000
.000
.000
.000
45
Total
Measured
Xwt
.420
.050
NR
.080
NR
NR
.070
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.610
306
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Sewage Sludge Incineration
17122
D
Control Device : Scrubber
ReferenceCs) s 60
Data Source : Samples collected with a modified EPA Method 5 train were
analyzed by X-ray fluorescence for elemental composition.
Particle size distribution data were collected by cascade
impactors. Data reflect average of tests conducted at a
eight-chartered multiple-hearth furnace.
SCC Assignments: 50100506
Mass Fraction Data - Size Interval Cum)
Mass Fraction
Total Participate Matter -
CAS Number
7440-41 -7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-43-9
9\KH i e&
Num Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
2S
26
27
28
29
30
31
32
33
34
35
37
38
40
42
48
Be
B
F
Ha
MS
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Mo
Cd
0-2
Xut
0
0
3
8
3
1
0
0
5
0
0
0
0
13
NR
m
NR
.570
.860
.050
.130
.360
.800
.260
.890
.090
NR
.880
.070
.940
.160
.750
0.050
0
1
3
0
d
0
.240
.580
.580
NR
NR
NR
.040
.110
NR
NR
NR
NR
.070
.5 UR!
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
: (0-2.55
: 0.240
2.5-
XMt
NR
NR
NR
0.570
0.860
3.050
8.130
3.360
1.800
0.260
0.890
5.090
NR
0.880
0.070
0.940
0.160
13.750
0.050
0.240
1.580
3.580
NR
NR
NR
0.040
0.110
NR
NR
NR
NR
0.070
10 un
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.320
0-10 an
%wt
NR
NR
NR
0.570
0.860
3.050
8.130
3.360
1.800
0.260
0.890
5.090
NR
0.880
0.070
0.940
0.160
13.750
0.050
0.240
1.580
3.580
NR
NR
NR
0.040
0.110
NR
NR
NR
NR
' 0.070
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.420
Total
Measured
%Ht
NR
NR
NR
0.570
0.860
3.050
8.130
3.360
1.800
0.260
0.890
5.090
NR
0.880
0.070
0.940
0.160
13.750
0.050
0.240
1.580
3.580
NR
NR
NR
0.040
0.110
NR
NR
NR
NR
0.070
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
307
-------
PH Profile Speclation Report - continued (profile 17122)
Total Particutote Natter
CAS Nunber
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
at*=i> I
Sb
Cs
Bo
Ce
Ha
Pb
oc
EC
S04
N03
0-2.5 urn
Xwt
2.390
0.050
NR
0.560
• NR
NR
2.270
NR
NR
NR
NR
U1C
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
2.390
0.050
NR
0.560
NR
NR
2.270
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 un
Xwt
2.390
0.050
NR
0.560
NR
NR
2.270
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xut
2.390
0.050
NR
0.560
m
NR
2.270
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
50.750
50.750
10.750
50.750
308
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Sewage Sludge Incineration
17123
D
Control Device : Scrubber
Reference(s) : 60
Date Source : Samples collected with a modified fPA Method S train were
analyzed by X-rey fluorescence for elemental composition.
Particle size distribution data were collected by cascade
impactors. Data reflect average of tests at a flufdized
bed furnace.
SCC Assigrments: 50100506
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-43-9
0|^;i. i «r»
Hum Syn
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
42
48
Be
8
F
Na
Ms
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Ee
ir
Rb
Sr
Zr
Mo
Cd
0-2
Xut
1
1
3
5
4
14
0
1
8
0
0
0
0
4
0
1
0
0
0
NR
NR
NR
.960
.010
.070
.330
.140
.420
.930
.070
.760
NR
.650
.180
.280
.460
.520
NR
NR
.280
.720
NR
NR
NR
.360
.770
NR
NR
NR
NR
.130
,5 UD
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.240
2.5-10 urn
Xwt
NR
NR
NR
1.960
1.010
3.070
5.330
4.140
14.420
0.930
1.070
8.760
NR
0.650
0.180
0.280
0.460
4.520
NR
NR
0.280
1.720
NR
NR
NR
0.360
0.770
NR
NR
NR
NR
0.130
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.320
0-10 uffl
%Mt
NR
NR
NR
1.960
1.010
3.070
5.330
4.140
14.420
0.930
1.070
8.760
NR
0.650
0.180
0.280
0.460
4.520
NR
NR
0.280
1.720
NR
NR
NR
0.360
0.770
NR
NR
NR
NR
0.130
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.420
Total
Measured
%Ht
NR
NR
NR
1.960
1.010
3.070
5.330
4.140
14.420
0.930
1.070
8.760
NR
0.650
0.180
0.280
0.460
4.520
NR
NR
0.280
1.720
NR
NR
NR
0.360
0.770
NR
NR
NR
NR
0.130
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
309
-------
PH Profile Speciation Report - continued (profile 17123)
Total Participate Hatter •
Species
CAS Number
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
Hum
50
51
55
56
58
80
82
201
202
203
204
Syn
Sn
Sb
Cs
Ba
Ce
Hfl
Pb
DC
EC
S04
N03
0-2
Xut
0.190
NR
NR
0.400
NR
NR
2.260
NR
NR
NR
NR
53.290
.5 un
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
Xwt
0.590
NR
NR
0.400
NR
NR
2.260
NR
NR
NR
NR
53.290
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xut
0.590
NR
NR
0.400
NR
NR
2.260
NR
NR
NR
NR
53.290
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xwt
0.590
NR
NR
0.400
NR
NR
2.260
NR
NR
NR
NR
53.290
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
E3==E=r:=r==rm=r===========:===================c=====================================
310
-------
PK Profile SpecIation Report
Profile Name
Profile Number
Data Quality
Sewage Sludge Incineration
17124
D
Control Device
Reference(s)
Data Source
Scrubber
60
Samples collected with a modified EPA Method 5 train were
analyzed by x-ray fluorescence for elemental composition.
Particle size distribution data were collected by cascade
impactors. Data reflect average of tests conducted at a
seven-chan»ered multiple-hearth furnace.
SCO Assignments: 50100506
Mass Fraction Data - Size Interval Cum) :
Mass Fraction :
Total Particulate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723- U-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-Z
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-43-9
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
42
48
Syro
Be
8
F
Na
Hg
Al
si
D
s
Cl
1C
Ca
Se
Ti
V
tr
Hn
fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
HO
Cd
0-2
%wt
0
0
0
0
0
3
2
0
0
0
u
0
q
0
2
0
0
2
NR
m
m
.340
.030
.050
.910
.840
.830
.910
.180
.230
NR
.020
NR
.330
.010
.340
NR
NR
.770
.690
NR
NR
NR
.040
.260
NR
NR
NR
NR
.770
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
i (0-2.5)
; 0.240
2.S-10 urn
Xwt
m
m
m
0.340
0.030
0.050
0.910
0.840
3.830
2.910
0.180
0.230
m
0.020
NR
0.330
0.010
0.340
m
NR
0.770
2.690
m
NR
NR'
0.040
0.260
NR
NR
NR
NR
2.770
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.370
0-10 urn
Xwt
NR
NR
NR
0.340
0.030
0.050
0.910
0.840
3.830
2.910
0,180
0.230
m
0.020
NR
0.330
0.010
0.340
NR
NR
0.770
2.690
NR
NR
NR
0.040
0.260
NR
NR
NR
NR
2.770
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.550
Total
Measured
Xwt
NR
NR
NR
0.340
0.030
0.050
0.910
O.S40
3.830
2.910
0.180
0.230
NR
0.020
NR
0.330
0.010
0.340
NR
NR
0.770
2.690
NR
NR
NR
0.040
0.260
NR
NR
NR
NR
2.770
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
311
-------
PH Profile Spec)ation Report - continued (profile 17124}
Total Paniculate
Hatter
CAS Nurrber
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
CpCb. I Co
Hum Sym
50
51
55
56
58
80
82
201
202
203
204
Sn
Sb
Cs
Be
Ce
Hg
Pb
OC
EC
S04
N03
Total
* 0-2.5 urn
Xwt
1.160
0.060
NR
0.020
NR
NR
3,140
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xut
1.160
0.060
NR
0.020
m
NR
3.140
NR
NR
NR
NR
0
0
0
0
0
0
0
0
0
0
0
unc
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0-10 un
Xwt
1.160
0.060
NR
0.020
NR
NR
3.140
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xwt
1.160
0.060
NR
0.020
NR
NR
3.140
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
TOTALS:
•20.930
20.930
20.930
20.930
312
-------
3.11 METAL FABRICATION
Metal fabrication Includes establishments engaged in fabricating ferrous
and nonferrous metal products, such as metal cans, tinware, handtools,
cutlery, general hardware, nonelectric heating apparatus, fabricated
structural metal products, metal forgings, metal stampings, and a variety of
metal and wire products. Emission sources include, but are not limited to,
casting, rolling, forging, welding, and sandblasting of metals.
313
-------
314
-------
PM Profile Speciation Report
Profile Name : Metal Fabrication - Galvanizing (ZnO)
Profile Number : 25701
Data Quality : E
Control Device : Uncontrolled^}
Referenee(s) : 62,76
Data Source : Data taken from Reference 62. for details, consult Reference
76.
SCC Assignments: 034
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6) (0-10)
Mass Fraction : 0.820 0.890 0.920
Total Particulate Hatter -
Total
0-2.5 um{2> 2.5-10 unC2> 0-10 umC2> Measured
Species - -
CAS Number Nun Sym Xwt unc Xwt unc Xwt unc %wt unc
7440-66*6 30 Zn 80.000 0.000 80.000 0.000 80.000 0.000 80.000 8.000
TOTALS: 80.000 80.000 80.000 80.000
——• S3S33SSSSB5E *5 CS3SS S — ~ SSSS—S—3ESSESSESSSS3I2J5SSSS2ISKSSSSSIS2JSSSSS2—SSSJSS—SSSS5S—5—SSS™—S3SSS™
C1> No control specified: thus assumed uncontrolled.
<2> Estimated / extrapolated.
315
-------
PM Profile Speciation Report
profile Name : Metal Fabrication - Sandblasting
Profile Number : 25702
Data Quality : E
Control Device : Uncontrolled}
Reference(s) s 62,76
Data Source : Data taken from Reference 62. For details, consult Reference
76,
SCO Assignments: 30900202
Mass Fraction Dat« - Size Interval (urn) :
Mass Fraction :
Total Participate Matter -
Species
CAS Number
7440-23-5
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7439-92-1
TOTALS:
SSSSSSBBSSS:
Hun Sym
11
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
35
82
200
Na
Al
Si
S
Cl
K
ca
Ti
¥
Cr
Hn
Fe
Ni
Cu
Zn
As
Br
Pb
TC
0-2.5
Swt
0.800
0.750
40.000
0.880
2.800
0.700
0.820
0.400
0.003
0.580
0.140
6.300
0.320
0.690
0.470
0.010
0.005
0.580
0.500
um<2>
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
56.748
2
0
0
40
0
2
0
0
0
0
CO
0
.5-10
Swt
.800
.750
.000
.880
.800
.700
.820
.400
.003
0.580
0
6
0
0
0
0
0
0
0
56
.140
.300
.320
.690
.470
.010
.005
.580
.500
.748
-2.5)
.300
umC2>
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Swt
0.800
0.750
40.000
0.880
2.800
0.700
0.820
0.400
0.003
0.580
0.140
6.300
0.320
0.690
0.470
0.010
0.005
0,580
0.500
56.748
<0-6)
0.620
C0-10>
0.850
Total
umf2> Measured
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Swt
0.800
0.750
40.000
0.880
2.800
0.700
0.820
0.400
0.003
0.580
0.140
6.300
0.320
0.690
0.470
0.010
0.005
0.580
0.500
56.748
une
0.080
0.075
4.000
0.088
0.280
0.070
0.082
0.040
0.000
0.058
0.014
0.630
0.032
0.069
0.047
0.001
0.001
0.058
0.050
CD No control specified: thus, assumed uncontrolled.
{2} Estimated / extrapolated.
316
-------
PM Profile Speciation Report
Profile Name
Profile Nuifcer
Oats Quality
Metal Fabrication - Welding
25703
E
Control Device
Referenced)
Oats Source
UneontrolledCO
62,93
Data taken from Reference 62. For details, consult Reference
93.
SCC Assignments: 034
Mass Fraction Data -
Size Interval (urn) :
Mass Fraction :
CO-2.5)
0.820
(0-6)
0.890
(0-10)
0.920
Total Participate Matter -
Total
0-2.5 urn 2.5-10 umCZ} 0-10 umt2> Measured£21
CAS Number Nun
Xwt unc
Xut unc Xut unc
Xwt unc
7440-09-7
7440-70-2
7439-96-5
7439-89-6
TOTALS;
19
20
25
26
K
C«
Mn
Fe
20.900
19.400
6.280
24.600
71.180
2.090
1.940
0.628
2.460
20.900
19.400
6.280
24.600
71.180
SKSSSSSSB
0.000
0.000
0.000
0.000
20
19
6
24
71
.900
.400
.280
.600
.180
4.234
3.931
1.285
4.980
20.900
19.400
6.280
24.600
71.180
0.000
0.000
0.000
0.000
•C1> No control specified; thus, assumed uncontrolled.
{2} Estimated / extrapolated.
317
-------
318
-------
3.12 HEAVY CONSTRUCTION
Heavy construction is a source of dust emissions that may have
substantial temporary impact on local air quality. Building and road
construction are the prevalent construction categories with the highest
emissions potential. Emissions during the construction of a building or road
are associated with land clearing, blasting, ground excavation, cut and fill
operations, and the construction of the particular facility itself. Dust
emissions vary substantially^ from day to day depending on the level of
activity, the specific operations, and the prevailing weather. A large
portion of the emissions result from equipment traffic over temporary roads at
the construction site.
319
-------
320
-------
PM Profile Spec!ation Report
Profile Name Excavation -
Profile Number 44101
Data Quality C
El Segundo,
CA
Control Device Not Applicable
Reference(s) 62
Data Source Soil sample from excavation site. Analyzed using XRF.
SCC Assignments 015
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction ; 0.020 0.040
Total Particulate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
•as=s=2
Sym
Al
S!
p
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
AS
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
%wt
11
24
0
0
0
1
1
0
0
0
0
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.513
.710
.033
.350
.035
.548
.186
.578
.025
.023
.112
.243
.009
.008
.023
.001
.008
.000
.000
.000
.020
.000
.000
.000
.000
.000
.000
.000
.000
.040
.000
.000
.000
0.011
45
.476
2.===g-
.5 urn
unc
1.727
3.707
0.007
0.018
0.002
0.077
0.059
0.032
0.008
0.004
0.008
0.267
0.002
0.002
0.003
0.001
0.004
0.001
0.002
0.002
0.003
0.003
0.016
0.009
0.010
0.012
0.017
0.020
0.024
0.055
0.099
0.183
0.002
0.006
2.5-10 urn
Xwt
9.749
21.239
0.025
0.108
0.019
1.721
1.359
0.612
0.021
0.020
0.133
5.655
0.008
0.004
0.014
0.000
0.000
0.000
0.004
0.014
0.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
0.000
0.000
0.000
0.024
40.782
unc
1.462
3.186
0.005
O.OOi
0.001
0.086
0.068
0.032
0.007
0.002
0.007
0.285
0.001
0.001
0.001
0.002
0.002
0.000
0.001
0.001
0.002
0.001
0.005
0.003
0,003
0.004
0.005
0.006
0.008
0.017
0.032
0.055
0.001
0.002
0-10 urn
Xwt
9.873
21.483
0.025
0.125
0.020
1.709
1.347
0.609
0.022
0.020
0.131
5.626
0.008
0.004
0.015
0.000
0.001
0.000
0.004
0.013
0.036
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
0.000
0.000
0.000
0.024
41.113
unc
0.973
2.108
0.003
0.014
0.002
0.085
0.066
0.032
0.004
0.002
0.007
0.282
0.001
0.001
0.002
0.001
0.001
0.000
0.001
0.001
0.002
0.001
0.005
0.003
0.003
0.004
0.005
0.006
0.007
0.016
0.029
0.053
0.001
0.002
(0-10)
0.080
Total
Measured^!}
Xwt
9.873
21.483
0.025
0.125
0.020
1.709
1.347
0.609
0.022
0.020
0.131
5.626
0.008
0.004
0.015
0.000
0.001
0.000
0.004
0.013
0.036
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
0.000
0.000
0.000
0.024
41.113
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
. 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
rSSSSJSSStt
Estimated / extrapolated.
321
-------
PM Profile Speciation Report
Profile Name Excavation -
Profile Nunfcer 44102
Data Quality C
Haul
Road
Control Device Not Applicable
ReferenceCs) 62
Data Source Soil sample from haul road at highway construction site.
Analyzed usinj XRF,
SCC Assignments: 30100103
Mass Fraction Data - Size Interval (un) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Op«W 1 V*>
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
6r
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
ia
La
Hg
Pb
0-2
Xwt
11
22
0
0
0
1
.041
.441
.033
.250
.087
.393
1.371
0.503
0
. 0
0
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
, 0
0
0
0
42
.025
,015
.101
.112
.004
.018
.079
.000
.021
.000
.000
.002
.017
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.513
.5 urn
unc
1.656
3.366
0.007
0.013
0.004
0.070
0.069
0.029
0.007
0.003
0.007
0.261
0.002
0.003
0.006
0.001
0.004
0.002
0.002
0.003
0.004
0.004
0.018
0.011
0.012
0.014
0.018
0.023
0.027
0.056
0.113
0.202
0.002
0.007
2.5-10 urn
Xwt
10.292
21.196
0.000
0.082
0.021
1.645
1.278
0.551
0.024
0.023
0.126
5.532
0.008
0.006
0.018
0.000
0.000
0.000
0.000
0.013
0.032
0.001
o.oco
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.046
0.025
0.000
0.024
40.943
unc
1.544
3.179
0.000
0.004
0.001
0.082
0.064
0.030
0.006
0.002
0.007
0.279
0.001
0.001
0.001
0.003
0.002
0.000
0.000
0.001
0.002
0.001
0.004
0.003
0.002
0.003
0.004
0.005
0.006
0.012
0.024
0.040
0.000
0.002
0-10 urn
Xwt
10.325
21.250
0.002
0.090
0.024
1.634
1.282
0.549
0.024
0.022
0.125
5,513
0.008
0.007
0.021
0.000
0.001
0.000
0.000
0.013
0.031
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.044
0.024
0.000
0.023
41.013
unc
0.993
2.036
0.002
0.010
0.004
0.079
0.069
0.028
0.004
0.002
0.007
0.275
0.001
0.001
0.003
0.002
0.002
0.000
0.001
0.001
0.002
0.001
0.005
0.003
0.003
0.004
0.005
0.006
0.007
0.015
0.031
0.054
0.000
0.002
CO-10)
0.080
Total
MeasuredCI}
%Mt
10.325
21.250
0.002
0.090
0.024
1.634
1.282
0.549
0.024
0.022
0.125
5.513
0.008
0.007
0.021
0.000
0.001
0.000
0.000
0.013
0.031
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.044
0.024
0.000
0.023
41.013
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Estimated / extrapolated.
322
-------
PH Profile Speciation Report
Profile Name
Profile Number
Data Quality
Excavation -
44103
C
Rock
Crushing
Control Device Not Applicable
Referenced) 62
Data Source Dust sample collected from rock crushing site. Analyzed
using XRF.
SCC Assignments: 30502001
Hass Fraction Data - Size Interval (urn) i (0-2.5) (0-6)
Mass Fraction ; 0.150 0.300
Total Partieylate Matt
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7736-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
K^r
13
14
15
16
17
19
20
22
23
24
?s
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
— /"
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
u~
Fe
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
As
Cd
In
Sn
Sb
Ba
La
Kg
Pb
er -
11
34
0
0
0
2
1
0
0
0
0
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
53
0-2
5fat
.539
.003
.000
.028
.014
.715
.509
.359
.032
.004
.119
.958
.003
.007
.023
.000
.003
.000
.000
.006
.043
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.003
.368
.5 urn
une
1.731
5.100
0.000
0.001
0.001
0.136
0.075
0.020
0.005
0,002
0.007
0.151
0.001
0.001
0.002
0.001
0.002
0.001
0.001
0.002
0.003
0.002
0.010
0.006
0.006
0.008
0.012
0.012
0.015
0.034
0.063
0.117
0.001
0.004
2.5-10 urn
%ut
9.681
29.414
0.000
0.000
0.000
2.721
1.732
0.339
0.008
0.007
0.117
2.908
0.003
0.005
0.010
0.000
0.000
0.000
0.000
0.012
0.057
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.027
0.000
0.000
0.014
47.055
une
1.452
4.412
0.000
0.000
0.000
0.136
0.087
0.022
0.006
0.001
0.006
0.147
0.001
0.001
0.001
0.002
0,001
0.000
0.000
0.001
0.003
0.001
0.005
0.002
0.002
0.003
0.004
0.005
0.006
0.013
0.027
0.043
0.000
0.002
0-10 un
Xwt
9.857
29.849
0.000
0.003
0.001
2.720
1.711
0.341
0.011
0.006
0.117
2.912
0.003
0.005
0.011
0.000
0.000
0.000
0.000
0.012
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
0.000
0.000
0.013
47.653
une
1.093
3.277
0.000
0.001
0.001
0.165
0.100
0.025
0.004
0.002
0.010
0.179
0.001
0.002
0.002
0.001
0.001
0.000
0.000
0.002
0.006
0.001
0.004
0.002
0.002
0.003
0.004
0.005
0.005
0.012
0.024
0.041
0.000
0.003
(0-10)
0.810
Total
MeasuredCI}
%ut
9.857
29.849
0.000
0.003
0.001
2.720
1.711
0.341
0.011
0.006
0.117
2.912
0.003
0.005
0.011
0.000
0.000
0.000
0.000
0.012
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,025
0.000
0.000
0.013
47.653
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{1> Estimated / extrapolated.
323
-------
PH Profile Specialion Report.
Profile Name Soil
Profile Hunfcer 44104
Data Quality C
Dust •
Sandblasting & Plastering
Control Device Npt Applicable
Reference(s) 62
Data Source Dust satrple collected from concrete structure sandblasting,
plastering, and waUbosrding site. Analyzed using XRF.
SCC Assignments: 015
Mass Fraction Data - Size Interval (urn) : (0-2,5) CO-65
Mass Fraction : 0.300 0.620
Total Particulate Hatt
Species
CAS Number Nun
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31 -5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
13
14
15-
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
AS
Cd
In
Sn
Sb
Ba
La
Hg
Pb
er -
- 5
16
0
1
0
1
14
0
0
0
0
2
0
0
0
0
0
0
0
0
0
0
0
0
' 0
0
0
0
0
0
0
0
0
0
42
0-2
%ut
.553
.443
.031
.982
.022
.288
.350
.245
.013
.022
.051
.325
.004
.007
.181
.000
.006
.000
.000
.000
.028
.000
.000
.000
.000
.000
.000
.000
,000
.000
.000
.000
.001
.005
.557
.5 urn
unc
0.833
2.466
0.006
0.099
0.001
0.064
0.718
0.014
0.003
0.002
0.004
0.118
0.001
0.001
0.010
0.001
0.002
0.001
0.001
0.001
0.002
0.002
0.008
0.005
0.005
0.007
0.008
0.011
0.013
0.028
0.052
0.092
0.001
0.003
2.5-10 urn
Xwt
4.944
14.210
0.000
1.524
0.016
1.353
14.212
0.223
0.005
0.011
0.062
2.377
0.005
0.008
0.131
0.000
0.000
0.000
0.003
0.009
0.043
0.001
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
0.000
0.000
0.015
39.173
unc
0.742
2,132
0.000
0.076
0.001
0.068
0.711
0.013
0.004
0.001
0.003
0.120
0.000
0.001
0.007
0.002
0.001
0.000
0.000
0.001
0.002
0.001
0.003
0.002
0.002
0.002
0.002
0.003
0.004
0.008
0.015
0.025
0.000
0.001
0-10 urn
Xwt
4.984
14.355
0.002
1.554
0.016
1.349
14.221
0.224
0.005
0.012
0.061
2.374
0.004
0.008
0.134
0.000
0.000
0.000
0.003
0.009
0.042
0.001
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
0.000
0.000
0.015
39.392
unc
0.627
1.817
0,003
0.133
0.004
0.100
1.011
0.023
0.003
0.004
0.009
0.173
0.002
0.003
0.016
0.001
0.001
0.000
0.002
0.003
0.007
0.001
0.004
0.002
0.002
0.003
0.003
0.004
0.005
0.011
0.021
0.036
0.000
0.004
(0-105
0.850
Total
NeasuredC1>
Xwt
4.984
14.355
0.002
1.554
0.016
1.349
14.221
0.224
0.005
0.012
0.061
2.374
0.004'
0.008
0.134
0.000
0.000
0.000
0.003
0.009
0.042
0.001
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
0.000
0.000
0.015
39.392
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0,000
0,000
0,000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Estimated / extrapolated.
324
-------
3.13 UNPAVED ROADS
Dust particles can become airborne on unpaved roads by vehicular traffic
and wind action can Increase the activity. Particulate emissions on unpaved
roads can be controlled to some degree by chemical stabilizers.
325
-------
326
-------
PH Profile Speciation Report
Profile Name Unpaved
Profile Number 41201
Data Quality 0/E
Road
Dust
(Copper Mine)
Control Device Mot applicable
Reference(s) 44
Data Source Bulk sample sieved and resuspended.
Mass Fraction Data - Size Interval Cum) : (0-2.5)
Mass Fraction : 0.300
Total Participate Matter •
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
39
40
42
46
47
48
49
50
51
Sym
Be
B
F
Na
Mg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Y
Ir
Mo
Pd
Ag
Cd
In
Sn
Sb
0-2
%wt
14
28
0
1
0
3
3
0
0
0
0
4
1
0
0
0
NA
NA
NA
NA
<
.618
.738
.282
.532
.215
.204
.420
<
.331
.030
.025
.186
.371
<
<
.436
.535
<
<
.046
<
<
<
.024
<
<
<
<
<
<
<
<
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
1.462
2.874
0.028
0.153
0.021
0.320
0.342
0.000
0.033
0.000
0.000
0.019
0.437
0.000
0.000
0.144
0.053
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
2.5-10 urn
%ut
NA
NA
NA
NA
<
10.448
22.471
0.218
1.817
0.185
3.097
4.028
<
0.402
0.031
0.023
0.160
4.441
«
0,012
1.431
0.546
<
<
0.065
<
<
0.019
0.034
<
<
0.029
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
1.045
2.247
0.022
0.182
0.018
0.310
0.403
0.000
0.040
0.000
0.000
0.016
0.444
0.000
0.000
0.143
0.055
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.590
0-10 urn
%Mt
NE
NE
NE
Ni
NE
12,288
25.236
0.246
1.691
0.198
3.144
3.760
m
0.371
0.031
0.024
0.171
4.410
NE
NE
1.433
0.541
NE
NE
O.OS7
NE
NE
NE
0.030
NE
NE
NE
Ni
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
1.373
2.788
0.027
0.182
0.021
0.340
0.404
0.000
0.040
0.000
0.000
0.019
0.476
0.000
0.000
0.155
0.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.680
Total
Measured
%Ht
NE
NE
NE
NE
NE
12.288
25.236
0.246
1.691
0.198
3.144
3.760
NE
0.371
0.031
0.024
0.171
4.410
NE
NE
1.433
0.541
NE
NE
0.057
HE
NE
NE
0.030
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
327
-------
PH Profile Speciatton Report - continued (profile 41201)
™™»«<.«™— —«•*•«»»»•»»*»•* — —»»»•«»»».*•—•••»»•— *«»••!.«••••»«*«.«•»»•••»«•••»•„»» W— _ — w— ..^.^ _
Total Partieulate Hatter -
Total
0-2.5 im 2.5-10 urn 0-10 urn Measured
Species -- - - ----
CAS Ninber Hum Syro Xwt unc . Xwt unc Xwt unc %ut unc
7440-39-3
7439-91-0
7439-97-6
7439-92-1
56
57
80
82
204
Be
La
Hg
Pb
N03
<
NA
NA
0.117
NA
0.012
0.000
0.000
0.012
0.000
0.023
NA
NA
0.100
NA
0
0
0
0
0
.022
.000
.000
.000
.000
NE
NE
m
0.107
NE
0.000
0.000
0.000
0.000
0.000
NE
NE
NE
0.107
NE
0.000
0.000
0.000
0.000
0.000
TOTALS: 19.110 49.180 53.738 53.738
328
-------
PH profile Speeiation Report
Profile Name Unpaved
Profile Number 41203
Data Quality D/E
Road
Dust
- Haul
Road
Control Device Not applicable
References) 44
Data Source Sampled near a copper ore concentrator.
and resuspended.
Mass Fraction Data - Size Interval Cum) : (0-2.5)
Hass Fraction : 0.300
Total Participate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7736-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7440-45-1
Sp%£W I CO
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
??
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
46
47
48
49
50
51
56
57
58
M<£
B
F
Na
Hg
Al
Si
P
S
Cl
K
Ca
7;
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Pd
Ag
Cd
in
Sn
Sb
Ba
La
Ce
0-2
Xwt
17
34
0
2
0
3
1
0
0
0
0
4
0
1
HA
NA
NA
NA
NA
.765
.358
.427
.810
.726
.504
.128
.420
.035
.027
.288
.364
.012
.393
0.568
0
0
0
0
0
0
<
.030
<
.014
<
.029
<
<
<
<
.034
.045
<
<
.274
<
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
1.776
3.436
0.043
0.281
0.073
0.350
0.113
0.042
0.000
0.000
0.029
0.436
0.000
0.139
0.057
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
0.024
0.036
0.038
0.044
0.080
0.214
0.000
0.000
2.5-10 urn
%wt
NA
NA
NA
NA
NA
12.872
25.981
0.241
2.277
0.496
3.554
1.671
0.501
0.035
0.021 .
0.255
3.779
<
0.989
0.504
<
0.016
<
<
0.020
0.029
<
<
<
<
<
<
<
<
0.064
<
<
unc
0.000
0.000
0.000
0.000
0.000
1.287
2.598
0.024
0.228
0.050
0.355
0.167
0.050
0.000
0.000
0.025
0.378
0.000
0.099
0.050
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
0.049
0.076
0.000
Bulk sample sieved
CO-6)
0.590
0-10 urn
Xwt
HE
NE
NE
NE
NE
15.031
29.677
0.323
2.512
0.597
3.532
1.431
0.465
0.035
0.024
0.270
4.037
NE
1.167
0.532
NE
0.022
NE
NE
NE
0.029
NE
NE
NE
NE
NE
NE
NE
NE
0.157
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
1.676
3.292
0.038
0.276
0,067
0.381
0.154
0.050
0.000
0.000
0.029
0.441
0.000
0.130
0.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.098
0.000
0.000
(0-10)
0.680
Total
Measured
Xut
NE
NE
NE
NE
NE
15.031
29.677
0.323
2.512
0,597
3.532
1.431
0.465
0.035
0.024
0.270
4.037
NE
1.167
0.532
' NE
0.022
• NE
NE
NE
0.029
NE
NE
NE
NE
NE
NE
NE
NE
0.157
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
329
-------
PH Profile Speciation Report - continued (profile 41203)
Total Particulate Matter »
Total
0-2.5 urn 2.5-10 urn 0-10 urn Measured
Species ............ —. ,
CAS Number Nun Sym %ut une %ut unc Xut unc Xwt unc
7439-97-6 80 Kg < 0.000 < 0.000 NE 0.000 Ni 0.000
7439-92-1 82 Pb 0.170 0.018 0.102 0.010 0.132 0.015 0.132 0.000
201
202
203
204
OC
EC
S04
N03
NA
NA
NA
NA
0.000
0.000
0.000
0.000
NA
NA
NA
NA
0
0
0
0
.000
.000
.000
.000
Ni
NE
NE
NE
0
0
0
0
.000
.000
.000
.000
Ni
NE
NE
NE
0.000
0.000
0.000
0.000
TOTALS: 68.421 53.407 59.973 59.973
-5— SSKS SSSSEKfflSSSISKSSSSSSSBS SSSSSSSSSSSJBSSSS BSSSKSSSBSSSJSSSCSSSSSSISSSSSSESS SSSiSSS!—S3
330
-------
PM Profile Speciation Rtport
Profile Name Unpaved Road
Profile Number 41204
Data Quality B/C
Dust
- East Helena,
Montana
Control Device Not applicable
Reference(s) 43
Data Source Sampled near a primary Pb smelter and Zn and Cu oxide
manufacturing plants. Samples sieved and resuspended.
Mass Fraction Data - Size Interval Cun) : CO-2.5) CO-6)
Mass Fraction ; 0.300 0.420
Total Participate Matte
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
TOTALS:
— 3-5S JBSJSSSSSSSS
Num
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
38
46
47
48
49
50
51
56
80'
82
201
202
203
204
Svtn
Be
B
F
Na
Kg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
Br
Sr
Pd
Ag
Cd
In
Sn
Sb
Ba
Hi
Pb
OC
EC
S04
N03
* SK~
r -
0-2
%wt
13
37
0
0
0
1
6
0
0
0
0
2
0
0
0
0
0
0
0
63
NA
NA
NA
NA
NA
.343
.418
.224
.419
.181
.725
.194
.741
.039
.021
.049
.340
<
.013
.028
<
<
<
.027
.052
<
<
<
<
.028
.320
<
.042
NA
NA
NA
NA
.204
5 urn
unc
0.000
0.000
0.000
0.000
0.000
1.334
3.742
0.025
0,060
0.028
0,172
0.619
0.074
0.000
0.000
0.000
0.234
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.019
0.025
0.039
0.042
0.046
0,089
0.250
0.000
0.014
0.000
0.000
0.000
0.000
2.5-10 urn
%ut
NA
NA
NA
NA
NA
9.347
29.370
0.149
0.248
0.113
2.139
3.994
0.433
0.016
0.019
0.040
2.158
<
0,014
0.030
<
<
<
0.033
<
<
<
<
<
<
0.306
<
0.027
NA
NA
NA
NA
48.436
331
unc
0.000
0.000
0.000
0.000
0.000
0.935
2.937
0.015
0.025
0.011
0.214
0.399
0.043
0.000
0.000
0.000
0.216
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
0.047
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NE
NE
NE
NE
NE
12.072
34.857
0.200
0.365
0.159
1.857
5.494
0.643
0.032
0.020
0.046
2,282
NE
0.013
0.029
NE
NE
NE
0.029
NE
NE
NE
NE
NE
NE
0.316
NE
0.037
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
1.924
5.618
0.033
0.065
0.029
0.324
0.870
0.10'1
0.000
0.000
0.000
0.376
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.179
0.000
0.000
0.000
0.000
0.000
0.000
58.451
(0-10)
0.440
Total
Measured
Xwt
NA
NA
NA
NA
NA
9.937
32.679
0.154
0.236
0.125
2.242
3.854
0.473
0.023
0.021
0.037
2.213
<
0.024
0.029
<
<
. <
0.037
<
<
<
<
<
0.011
0.270
<
0.035
NA
NA
NA
NA
52.400
unc
0.000
0.000
0.000
0.000
0.000
0.994
3.268
0.015
0.024
0.012
0.224
0.385
0.047
0.000
0.000
0.000
0,221
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.015
0.051
0.000
0.000
0.000
0.000
0.000
0.000
-------
PH Profile Speciatfon Report
Profile Name
Profile Number
Data Quality
Unpavcd Road Dust
41205
C
- Riverside, CA
Control Device Mot Applicable
Reference(s) 62
Data Source Surface dust sampled, aerosolized, and recollected Mith a
Sierra dtchotomus virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 055
Mass Fraction Data - Size Interval (urn) : CO-2.5) CO-6)
Mass Fraction : 0.300 0.590
Total Partieulate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
CD Estimated /
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Hi
Cu
2n
Ga
As
Se ;
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hi
Pb
0-2
Xwt
9.890
20.360
0.212
0.406
0.157
1.981
2.831
0.529
0.038
0.024
0.159
5.671
d.009
0.011
0.028
0.003
0.008
0.000
0.002
0.007
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.013
42.352
5 urn
unc
1.484
3.054
0.043
0.020
0.008
0.099
0.142
0.027
0.006
0.002
0.008
0.286
0.001
0.002
0.002
0.001
0.003
0.001
0.001
0.002
0.002
0.002
0.011
0.007
0.007
0.009
0.012
0.014
0.017
0.038
0.071
0.128
0.001
0.004
extrapolated.
2.5-10
Xwt
9.231
19.190
0.175
0.332
0.179
2.227
2.900
0.556
0.025
0.029
0.150
5.955
0.007
0.007
0.026
0.000
0.0 00
0.000
0.003
0.016
0.028
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
0.000
0.000
0.030
41.122
332
un
unc
1
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.385
.878
.035
.017
.009
.111
.145
.029
.006
.002
.008
.299
.001
.001
.001
.003
.002
.000
.000
.001
.002
.001
.003
.001
.001
.002
.002
.003
.003
.007
.013
.022
.000
.002
0-10 tin
Xwt
9.267
19.253
0.177
0.336
0.177
2.213
2.897
0.554
0.026
0.029
0.150
5.940
0.007
0.007
0.027
0.000
0.000
0.000
0.003
0.016
0.027
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
0.000
0.000
0.029
41.189
unc
1.283
2.651
0.035
0.037
0.020
0.176
0.238
0.051
0.008
0.006
0.019
0.476
0.003
0.003
0.006
0.002
0.002
0.000
0.002
0.005
0.006
0.003
0.005
0.003
0.003
0.004
0.005
0.006
0.007
0.016
0.031
0.055
0.001
0.007
CO-10)
0.730
Total
HeasuredC1>
Xut
9.267
19.253
0.177
0.336
0.177
2.213
2.897
0.554
0.026
0.029
0.150
5.940
0.007
0.007
0.027
0.000
0.000
0.000
0.003
0.016
0.027
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
0.000
0.000
0.029
41.189
unc
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-------
PM Profile Speciation Report
Prof fie Name Unpaved
Profile Number 41220
Data Quality D
Road
Dust
- Composite
Control Device Hot applicable
Reference(s) 44,43
Data Source Developed from profiles 41201, 41203, and 41204.
SCC Assignments
Mass Fraction Data • Size Interval (urn) : {0-2,5) (0-6)
Mass Fraction ; 0.300 0.590
Total Paniculate Matter -
CAS Number
7440^41 -7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
?pvi» i e»
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
39
40
42
46
47
48
49
Be
B
f
Na
Hg
Al
Si
P
S
Ci
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
0-2
Xwt
0
0
0
0
0
15
33
0
1
0
2
3
0
0
0
0
0
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.242
.505
.311
.587
.374
.811
.581
.000
.497
.035
.024
.174
.692
.000
,004
.947
.377
.000
.000
.025
.000
,005
.000
.027
.000
,000
.000
.017
0.000
0
0
.011
.015
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
1.535
3.370
0.033
0.1B8
0.047
0.291
0.413
0.000
0.053
0.000
0.000
0.020
0.381
0.000
0.000
0.116
0.045
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
0.020
0.031
0.033
2.5-10 urn
%wt
0.000
0.000
0.000
0.000
0.000
10.889
25.941
0.203
1.447
0.265
2.930
3.231
0.000
0.445
0.027
0.021
0.152
3.459
0.000
0.004
0.811
0.360
0.000
0.000
0.027
0.000
0.000
0.013
0.032
0.000
0.000
0.010
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
1.099
2.609
0.021
0.169
0.031
0.299
0.341
0.000
0.045
0.000
0.000
0.017
0.359
0.000
0.000
0.100
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
12.809
29.278
0.250
1.509
0.313
2.877
3.385
0.000
0.468
0.031
0,022
0.162
3.562
0.000
0.004
0.871
0.367
0.000
0.000
0.026
0.000
0.002
0.007
0.030
0.000
0.000
0.005
0.008
0.000
0.005
0.007
unc
0.000
0.000
0.000
0.000
0.000
1.435
3.244
0.029
0.174
0.038
0.313
0.383
0.000
0.052
0.003
0.002
0.019
0.391
0.000
0.000
0.103
0.043
0.000
0.000
0.002
0.000
0.000
0.001
0.003
0.000
0.000
0.001
0.007
0.009
0.014
0.014
(0-10)
0.680
Total
Measured
Xwt
0.000.
0.000
0.000
0.000
Q.OOO
3.312
10.893
0.051
0.079
0.042
0.747
1.285
0.000
0.158
0.008
0.007
0.012
0.738
0.000
0.000
0.008
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.574
1.887
0.009
0.014
0.007
0.129
0.222
0.000
0.027
0.000
0.000
0.000
0.128
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
333
-------
PH Profile Speciotion Report - continued (profile 41220)
Total Paniculate Matter •
Spec-ies
CAS Number
7440-3 1-i
7440-36-0
7440-39-3
7439-91-0
7440-45-1
7439-97-6
7439-92-1
Mum
50
51
56
57
58
80
82
201
202
203
204
Sym
Sn
Sb
Ba
La
Ce
Kg
Pb
OC
EC
S04
N03
0-2
Xwt
0
0
. 0
0
0
0
0
0
0
0
0
.000
.009
.198
.000
.000
.000
.110
.000
.000
.000
.000
,5 urn
unc
0.037
0.070
0.190
0.000
0.000
0.000
0.015
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
0.000
0.000
0.131
0.000
0.000
0.000
0.076
0.000
0.000
0.000
0.000
unc
0.000
0.013
0.041
0.044
0.000
0.000
0.006
0.000
0.000
0.000
0.000
0-10 urn
Xwt
0.000
0.004
0.161
0.000
0.000
0.000
0.091
0.000
0.000
0.000
0.000
unc
0.016
0.031
0.087
0.019
0.000
0.000
0.011
0.000
0.000
0.000
0.000
Total
Measured
%wt
0.000
0.004
0.090
0.000
0.000
0.000
0.012
0.000
0.000
0.000
0.000
unc
0.000
0.009
0.029
0.000
0,000
0.000
0,000
0.000
0.000
0.000
0.000
TOTALS:
63.578
50.474
56.254
17.468
334
-------
3.14 PAVED ROADS
Reentrained dust from paved roads consists mostly of sand and soil.
Road dust also contains participates from engine exhaust, wear of bearings and
brake linings, and tire abrasion. Particulate emissions are further generated
when wind activity is high (>20 kilometers per hour). Emission rates are
chiefly affected by volume of traffic, and quantity and size of dust
particles.
335
-------
336
-------
PM Profile Speciat ion Report
Profile Name Paved Road Dust Hissoula
Profile Number 41101
Data Quality C/E
, Montana
Control Device Not applicable
Reference(s) 28
Data Source Analysis by XRF and carbon oxidation.
through a diehotomous sampler.
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.250
Total Particulate
Matter
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
0^*^h> 1 CO
Nun Syn
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
Be
B
F
NB
Kg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Ir
Ag
Cd
Sn
Sb
Cs
Ba
Ce
Sample resuspended
<0-6)
0.370
CO-10)
0,440
Total
. 0-2
Xwt
NA
NA
NA
0.960
1.000
8.100
23.800
<
<
0.030
2.300
1.700
<
0.260
0.004
<
0.026
3.200
<
<
0.110
0.040
<
<
<
<
0.002
<
<
<
<
<
<
<
<
<
<
.5 urn
unc
0.000
0.000
0.000
0.060
0.130
1.000
3.000
0.000
0.000
0.016
0.500
0.100
0.000
0.020
0.001
0.000
0.001
0.400
0.000
0.000
0.030
0.010
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-
Xwt
NA
NA
NA
0.960
1.000
6.500
28.000
<
<
0.032
2.300
1.700
«s
0.260
0.004
<
0.026
3.200
<
<
0.110
0.040
<
<
<
<
0.002
<
<
<
<
<
<
<
<
<
<
10 in
unc
0.000
0.000
0.000
0.060
0.130
1.000
3.000
0.000
0.000
0.016
0.500
0.100
0.000
0.020
0.001
0.000
0.001
0.400
0.000
0.000
0.030
0.010
0.000
0.000
0.000
0.000
0,001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
NE
HE
NE
0.960
1.000
7.409
25.614
NE
NE
0.031
2.300
1.700
NE
0.260
0.004
NE
0.026
3.200
NE
NE
0.110
0.040
NE
NE
NE
NE
0.002
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
0
0
0
0
0
1
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
urn
unc
.000
.000
.000
.119
.154
.158
.812
.000
.000
.013
.479
.209
.000
.034
.001
.000
.003
.485
.000
.000
.027
.009
.000
.000
.000
.000
.001
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
Measured
Xwt
NE
NE
NE
0.960
1.000
7.409
25.614
NE
NE
0.031
2.300
1.700
NE
0.260
0.004
NE
0.026
3.200
NE
NE
0.110
0.040
NE
NE
NE
NE
0.002
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
337
-------
PH Profile Speciation Report- - continued (profile 41101}
Total Perticulate Hatter -
Total
0-2.5 un 2.5-10 un 0-10 urn Measured
Species
MS Number Nun Sym %Ht unc Xwt unc Xwt unc %wt unc
7439-97-6
7439-92-1
80
82
201
202
203
204
HS
Pb
OC
EC
S04
N03
0
10
1
<
.130
.000
.400
NA
NA
0.000
0.020
0.000
0.000
0.000
0.000
<
0.130
10.000
1.400
NA
NA
0.000
0.020
0.000
0.000
0.000
0.000
NE
0.130
10.000
1.400
NE
NE
0.000
0.022
0.000
0.000
0.000
0.000
NE
0.130
10.000
1.400
NE
NE
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS; 53.062 55.664 54.186 54.186
338
-------
PH Profile Spec!ation Report
Profile Name Paved Road Dust -
Profile Nunfcer 41102
Data Quality C/E
Juncau
, Alaska
Control Device Not applicable
Referenced) 19
Data Source Composite of 3 subsamples (fine fraction). Resuspended
and analyzed by XRF.
Mass Fraction Data - Size Interval Cum) : (0-2.5) (0-6)
Ness Fraction : 0.250 0,370
Total Participate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
af-Kst; i e&
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
Be
B
F
Na
Mg
Al
s:
p
s
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Ce
0-2
Xwt
10
32
0
0
0
1
3
0
0
0
0
7
0
0
0
d
0
0
0
0
0
NA
NA
NA
NA
NA
.900
.800
.190
.250
.150
.460
.290
<
.810
.050
.030
.130
.190
<
.010
.010
.700
<
<
• <
<
.020
<
.050
.010
<
<
.080
.030
<
.280
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
Xwt
NA
NA
NA
NA
NA
10.900
32.800
0.190
0.250
0.150
1.460
3.290
<
0.810
0.050
0.030
0.130
7.190
<
0.010
0.010
0.700
<
<
<
<
0.020
<
0.050
0.010
<
<
0.080
0.030
<
0.280
<
unc
0.000
0.000
0.000
0.000
0.000
0.580
1.680
0.040
0.060
0.020
0.080
0.170
0.000
0.040
0.000
0.000
0.000
0.370
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
0.030
0.040
0.000
0.160
0.000
0*10 urn
Xwt
NA
NA
NA
NA
NA
10.900
32.800
0.190
0.250
0.150
1.460
3.290
<
0.810
0.050
0.030
0.130
7.190
- <
0.010
0.010
0.700
<
<
<
<
0.020
<
0.050
0.010
<
<
0.080
0.030
<
0.280
<
unc
0.000
0.000
0.000
0.000
0.000
1.282
3.848
0.031
0.044
0.020
0.172
0.3S6
0.000
0.095
0.006
0.003
0.015
0.644
0.000
0.001
0.001
0.080
0.000
0.000
0.000
0.000
0.002
0.000
0.006
0.011
0.000
0.000
0.019
0.023
0.000
0.096
0.000
(0-10)
0.440
Total
Measured
Xwt
NA
NA
NA
NA
NA
10.900
32.800
0.190
0.250
0.150
1.460
3.290
<
0.810
0.050
0.030
0.130
7.190
<
0.010
0.010
0.700
<
<
<
<
0.020
<
0.050
0.010
<
<
0.080
0.030
<
0.280
<
unc
0.000
0.000
0.000
0.000
0.000
0.580
1.680
0.040
0.060
0.020
0.080
0.170
0.000
0.040
0.000
0.000
0.000
0.370
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
0.030
0.040
0.000
0.160
0.000
339
-------
PM Profile Speeiatfon Report - continued (profile 41102}
Total Participate Hatter -
Total
0-2.5 urn 3.5-10 urn 0-10 urn Measured
Species , ...... . ,
CAS Number Nun Sym , Xut une Xut unc %ut unc Xwt unc
7439-97-6
7439-92-1
~
TOTALS:
80
82
201
202
203
204
Hg
Pb
OC
EC
S04
N03
0
0
59
«
.530
NA
NA
.750
NA
.720
0.000
0.000
0.000
0.000
0.000
0.000
<
0.530
NA
NA
0.750
NA
59.720
0.000
0.030
0.000
0.000
0.180
0.000
<
O.S30
NA
NA
0.750
NA
59.720
0.000
0.063
0.000
0.000
0.133
0.000
<
0.530
NA
NA
0.750
NA
59.720
0.000
0.030
0.000
0.000
0.180
0.000
340
-------
PH Profile Spectation Report
Profile Name : Paved Road Dust -
Profile Number : 41103
Data Quality : C/E
Lewi 8 ton, Idaho
Control Device : Mot applicable
Reference(s) : 42
Data Source : Resuspanded -and analyzed
Mass Fraction Data * Size Interval (un)
Mass Fraction
Total Particulate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
Num
4
5
o
11
12
13
14
15
16
17
19
20
21
22
7*
24
25
26
27
28
29
30
5l
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Sym
Be
B
c
He
Mg
At
Si
P
S
Cl
K
Ca
Sc
Ti
y
Cr
Mn
Fe
Co
Ni
Cu
Zn
l»a
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Ce
Hg
0-2
%wt
1
2
11
36
0
0
1
2
0
0
c
0
NA
NA
NA
.300
.200
.600
.000
<
.600
.310
.180
.400
<
.630
.020
.030
.120
5.700
<
0.040
0
0
0
.040
.160
<
<
<
<
.020
<
<
<
<
<
<
<
<
<
<
<
.5 un
unc
0.000
0.000
0.000
0.200
0.500
0.700
2.000
0.000
0.100
0.070
0.090
0.100
0.000
0.040
0.010
0.000
0.020
0.300
0.000
0.000
0.020
0.020
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
by XRF.
z (0-2.5)
: 0.250
2.5-
Xwt
NA
NA
NA
1.600
1.600
6.900
24.000
<
0.360
0.140
1.200
2.800
<
0.860
0.030
0.030
0.130
6.600
<
0.010
0.010
0.080
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
10 urn
unc
0.000
0.000
0.000
0.100
0.200
0.300
1.000
0.000
0.020
0.000
0.060
0.100
0.000
0.040
0.000
0.000
0.000
0.300
0.000
0.000
0.000
0.040
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.370
0-10 urn
%wt
NE
NE
NE
1.430
1.941
9.570
30.818
NE
0.496
0.237
1.189
2.573
NE
0.729
0.024
0.030
0.124
6.089
NE
0.027
0.027
0.125
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.209
0.376
1.168
3.701
0.000
0.081
0.000
0.149
0.307
0.000
0.091
0.000
0.000
0.000
0.741
0.000
0.000
0.000
0.029
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.440
Total
Measured
%wt
NE
NE
NE
1.430
1.941
9.570
30.818
NE
0.496
0.237
1.189
2.573
NE
0.729
0.024
0.030
0.124
6.089
NE
0.027
0.027
0.125
NE
NE
NE
m
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
HE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
341
-------
PH Profile Special ion Report - continued (profile 41103)
Total Participate Hatter -
Total
CAS Number
7439-92-1
Hum Sysn
82
201
202
203
204
Pb
oc
EC
S04
N03
0-2
%wt
0.330
NA
NA
NA
NA
.5 urn
unc
0.050
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
0.140
NA
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0*10 urn
XMt
0.248
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
Measured
Xwt
0.248
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
TOTALS: 62.680 46.490 55.677 15.677
342
-------
Profile Speciation Report
Profile Name Paved Road Dust -
Profile Number 41104
Data Quality D/E
Butte,
Montana
Control Device Not applicable
ReferenceCs) 44
Data Source Road near copper mine. Bulk sample sieved and resuspended.
Mass Fraction Data - Size Interval Cum) : (0*2.5) (0-6)
Mass Fraction : 0.250 0.370
Total Paniculate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-1
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7440-17-7
7440-24-6
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
37
38
42
46
47
48
49
50
51
56
57
80
Sym
Be
B
F
Na
MS
At
SI
P
s
ct
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Rb
Sr
Mo
Pd
AS
Cd
In
Sn
Sb
Ba
La
Kg
0-2
%Ht
13
34
0
1
0
2
3
0
0
0
0
4
0
0
0
0
0
0
0
NA
NA
NA
NA
NA
.493
.850
.406
.029
.173
.374
.937
<
.336
.031
.032
.134
.354
<
.013
.327
.254
<
<
.023
<
<
.027
<
.023
<
<
<
<
.091
<
<
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
1.349
3.493
0.041
0.103
0.022
0.237
0.394
0.000
0.037
0.000
0.000
0.013
0.435
0.000
0.000
0.033
0.025
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
0.018
0.026
0.029
0.032
0.057
0.162
0.000
0.000
2.5-10 urn
Xwt
NA
NA
NA
NA
NA
8.195
23.641
0.234
0.750
0.127
2.330
4.091
<
0.409
0.028
0.032
0.116
4.052
<
<
0.302
2.100
<
<
0.016
<
0.015
0.035
0.020
<
<
<
<
<
0.019
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.819
2.364
0.023
0.075
0.013
0.233
0.409
0.000
0.041
0.000
0.000
0.012
0.405
0.000
0.000
0.030
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.024
0.035
0.000
0-10 urn
%wt
NE
NE
NE
NE
NE
11.205
30.010
0.332
0.909
0.153
2.355
4.003
NE
0.368
0.030
0.032
0.126
4.224
NE
NE
0.316
1.051
m
m
0.020
NE
NE
0.030
NE
NE
NE
NE
NE
NE
0.060
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
1.553
4.146
0.046
0.125
0.023
0.327
0.559
0.000
0.053
0.000
0.000
0.017
0.585
0.000
0.000
0.044
0.171
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.440
Total
Measured
Xwt
NE
NE
NE
NE
NE
11.205
30.010
0.332
0.909
0.153
2.355
4.003
NE
0.368
0.030
0.032
0.126
4,224
NE
NE
0.316
1.051
NE
NE
0.020
NE
NE
0.030
NE
NE
NE
NE
NE
NE
0.060
NE
NE
.NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
343
-------
PH Profile Speciation Report - continued (profile 41104)
Total Particulate Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 urn Measured
Species ..... .. ,
CAS Number Nun Sym %wt unc %ut unc Xwt unc %wt unc
7439-92-1
82
201
202
202
204
Pb
OC
EC
S04
N03
0.178
NA
NA
NA
NA
0
0
0
0
0
.018
.000
.000
.000
.000
0.125
NA
NA
NA
NA
0.012
0.000
0.000
0.000
0.000
0.155
m
m
m.
m
0.021
0.000
0.000
0.000
0.000
0.155
m
HE
HE
m
0.000
0.000
0.000
0.000
0.000
TOTALS: 62.085 46.637 55.379 55.379
344
-------
PN Profile Specfation Report
Profile Name Paved Road Oust -
Profile Number 41105
Data Quality C/D
East Helena, Montana
Control Device Not applicable
RefereneeCsJ 43
Data Source Road dust near a primary Pb smelter and Zn and Cu oxide
manufacturing plants. Samples sieved and resuspended.
Mass Fraction Data - Size Interval Cum) : CO-2.5) CO-6}
Mass Fraction : 0.250 0.370
Total Particulate
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
TOTALS:
ope<
Nun
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
38
46
47
48
49
50
-------
PH Profile Speciatt'on Report
Profile Name Paved Road Dust -
Profile Hunter 41106
Data Quality B/D
Bedford OR
Control Dtvice Not applicable
Reference(s) 45
Data Source Resuspended and sampled
Nass Fraction Data - Size Interval (tin)
Mass Fraction
Total Paniculate Matter -
CAS Nunfcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
apcfc. i ca*
Nun Syrn
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Be
B
F
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Se
As
se
Br
Rb
sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Ce
Hg
0-2
%wt
2
2
8
23
0
0
0
2
0
. 0
0
0
4
, 0
0
0
NA
NA
NA
.000
.000
.100
.800
NA
.400
.040
.920
.500
NA
.650
.023
.026
.110
.900
NA
.010
.040
.050
NA
<
<
<
<
NA
<
NA
NA
<
NA
<
NA
<
<
<
.5 un
unc
0.000
0.000
0.000
0.300
0.300
0.300
1.300
0.000
0.100
0.000
0.080
1.100
0.000
0.110
0.000
0.000
0.000
0.400
0.000
0.000
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
with a dichotomous sampler.
: (0-2.5) CO-6)
: 0.250 0.370
2.5-10 un
Xwt
NA
NA
NA
2.000
1.900
8.200
24.800
NA
0.320
NA
0.830
2.400
NA
0.540
0.031
0.026
0.120
4.700
NA
0.100
0.080
0.040
NA
<
<
<
<
NA
<
NA
NA
<
NA
<
NA
<
<
<
unc
0.000
0.000
0.000
0.300
0.100
0.500
1.300
0.000
0.200
0.000
0.080
1.200
0.000
0.060
0.000
0.000
0.020
0.400
0.000
0.000
0.090
0.020
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
%Mt
NE
Ni
NE
2.000
1.957
8.143
24.232
NE
0.365
NE
0.881
2.457
NE
0.603
0.026
0.026
0.114
4.814
NE
0.049
0.057
0.046
NE
NE
NE
NE
m
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.331
0.285
0.984
2.953
0.000
0,134
0.000
0.119
0.966
0.000
0.098
0.000
0.000
0.000
0.633
0.000
0.000
0.054
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<0-10>
0.440
Total
Measured
Xwt
NE
NE
NE
2.000
1.957
8.143
24.232
NE
0.365
NE
0.881
2.457
NE
0.603
0.026
0.026
0.114
4.814
NE
0.049
0.057
0.046
NE
Ni
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
346
-------
PH Profile Speefttion Report - continued (proffit 411063
Tetal Paniculate Matter -
Total
0-2.5 un 2.5-10 urn 0-10 urn Measured
Species '•
CAS Number Nun sym Xwt unc Xwt unc Xwt unc Xut unc
7439-92-1
TOTALS:
82
201
202
203
204
Pb
oc
EC
S04
N03
0
10
1
0
0
57
.130
.000
.400
.240
.100
.439
0.040
2.000
0.500
0.170
0.030
0.090
8.700
1.600
0.230
NA
56.707
0.040
1.900
0.800
0.120
0.000
0.113
9.439
1.486
0.236
NE
57.044
0.035
1.895
0.563
0.121
0.000
0.113
9.439
1.486
0.236
HE
57.044
0.000
0.000
0.000
0.000
0.000
347
-------
PH Profile Speciation Report
Profile Kane Paved Road Dust •
Profile number 41107
Date Quality A/c
Portland, OR
Control Device Hot applicable
Refercnce(s) 46
Data Source Resuspended and sampled with a 2-stage virtual impactor
with a Method 5 heated probe. No dilution air. Analysis
is by XRF, INNA, 1C, and carbon oxidation.
Mass Fraction Data - Size Interval (urn) : (0-2. 5} (0-6)
Mass Fraction : 0.250 0.370
Total Particulate Hatter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
«pci» i e»
Hum Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Be
B
F
Na
Hg
Al
Si
P
* S
Cl
K
Ca
So
Ti
V
Cr
Hn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
0-2
%Wt
1
1
8
22
0
1
' 2
0
. 0
0
0
6
0
0
0
0
NA
NA
NA
.250
.300
.840
.300
<
.370
<
.030
.440
<
.640
.023
.045
.123
.000
<
.009
.030
.110
<
<
<
<
.020
<
<
<
<
<
<
<
<
<
.5 un
unc
0.000
0.000
0.010
0.340
0.270
2.710
1.100
0.000
0.140
0.010
0.060
0.400
0.000
0.120
0.005
0.017
0.017
0.600
0.000
0.003
0.012
0.037
0.000
0.000
0.000
0.000
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
NA
NA
0.008
1.750
1.540
6.600
28.400
<
<
<
1.030
3.000
<
1.010
0.027
0.045
0.100
5.730
<
0.004
0.030
0.110
<
<
<
<
0.008
<
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.007
0.091
0.140
0.700
0.790
0.000
0.020
0.020
0.058
0.220
0.000
0.180
0.005
0.017
0'.011
0.290
0.000
0.003
0.012
0.037
0.000
0.000
0.000
0.000
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
%wt
NE
HE
NE
1.466
1.404
7.873
24.934
NE
NE
NE
1.030
2.682
NE
0.800
0.025
0.045
0.113
5.883
NE
0.007
0.030
0.110
NE
NE
NE
NE
0.015
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.264
0.237
1.821
3.002
0.000
0.000
0.000
0.126
0.405
0.000
0.156
0.005
0.015
0.017
0.767
0.000
0.003
0.010
0.032
0.000
0.000
0.000
0.000
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
(0-10)
0.440
Total
Measured
%ut
NE
NE
NE
1.466
1.404
7.873
24.934
NE
NE
NE
1.030
2.682
NE
0.800
0.025
0.045
0.113
5.883
NE
0.007
0.030
0.110
NE
NE
NE
NE
0.015
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
348
-------
PM Profile Specfation Report - continued (profile 41107)
Total Paniculate Hatter -
CAS Number Hum Sym
7440-45-1 58
7439-97-6 80
7439-92-1 82
201
202
203
204
TOTALS:
sszs::=sss==sE=ss5s=s:s
Ce
H9
Pb
oc
EC
S04
N03
0
11
1
0
58
0-2
Xwt
<
<
.370
.800
.850
,420
NA
.970
,5 urn
unc
0.000
0,000
0.150
4.300
0.910
0.310
0.000
2.5-
%wt
<
<
0.370
3.340
1.550
0.074
0.020
54.746
•10 urn
unc
0.000
0.000
0.150
0.980
0.780
0.045
0.010
0-10 urn
Swt
NE
HE
0.370
8.147
1.720
0.271
NE
56.925
wwSBS==S
ync
0.000
0.000
0.128
2.693
0.708
0.181
0.000
'0
8
1
0
56
Total
Measured
%ut
NE
NE
.370
.147
.720
.271
NE
.925
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
349
-------
PH Profile Speciation Report
Profile Name : Paved Road Dust - Alabama
Profile Nunber : 41109
Data Quality : D/E '
Control Device : Not applicable
Reference(s) : 48
Data Source : Resuspend*d and sampled
Mass Fraction Data - Size Interval (un)
Mass Fraction
Total Particulate
C'Bfc— .
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
ofjei
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Matter
sies
Sym
Be
B
F
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Ce
KB
""
0-2
Xwt
9.
19.
0.
0.
0.
0.
3.
0.
0.
0.
0.
3.
0.
0.
0.
0.
NA
NA
NA
NA
NA
280
700
123
800
247
494
150
<
444
030
270
080
140
<
<
<
090
005
<
<
010
036
<
<
<
<
<
<
<
<
<
<
<
.5 un
unc
0.000
0.000
0.000
0.000
0.000
2.970
6.200
0.104
0.384
0.163
0.174
1.090
0.000
0.147
0.022
0.025
0.035
1.010
0.000
0.023
0.026
0.037
0.017
0.000
0.055
0.018
0.027
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
with a dichotomous sampler.
: (0-2.5) (0-6)
: 0.250 0.370
2.5-10 urn
%Mt
NA
NA
NA
NA
NA
6.320
23.900
0.239
0.612
0.230
0.595
7.990
<
0.466
0.014
0.023
0.070
2.750
<
0.013
0.016
0.119
<
<
<
0.001
0.013
<
<
<
<
<
<
<
«
«
<
<
unc
0.000
0.000
0.000
0.000
0.000
1.200
4.800
0.048
0.120
0.046
0.120
1.600
0.000
0.094
0.004
0.004
0.014
0.560
0.000
0.003
0.004
0.024
0.002
0.000
0.008
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
%Ht
NE
NE
NE
NE
NE
8.002
21.514
0.173
0.719
0.240
0.538
5.240
NE
0.454
0.023
0.163
0.076
2.972
NE
NE
NE
0.103
NE
NE
NE
0.006
0.026
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
2.031
5.103
0.069
0.242
0.100
0.135
1.299
0.000
0.112
0.013
0.026
0.023
0.737
0.000
0.000
0.000
0.028
0.000
0.000
0.000
0.010
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.440
Total
Measured
%Ht
NE
NE
NE
NE
NE
8.002
21.514
0.173
0.719
0.240
0.538
5.240
NE
0.454
0.023
0.163
0.076
2.972
NE
NE
NE
0.103
NE
NE
NE
0.006
0.026
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
350
-------
PM Profile Specfation Report • continued {profile 41109)
Total Participate Natter -
Species
CAS Nurber Nun Sym
Total
0-2.5 urn 2.S-10 ura 0-10 urn Measured
%wt unc Xut unc Xwt unc %ut unc
7439-92-1
TOTALS:
82
201
202
203
204
Pb
OC
EC
S04
N03
0.187
NA
NA
NA
NA
38.086
0.103
0.000
0.000
0.000
0.000
0.163
NA
NA
NA
NA
43.534
0
0
0
0
0
.032
.000
.000
.000
.000
0.177
NE
NE
NE
NE
40.426
0.064
0.000
0.000
0.000
0.000
0,177
NE
NE
NE
NE
40.426
0.000
0.000
0.000
0.000
0.000
351
-------
PM Profile Speciation Report
Profile Name Paved Road Dust -
Prof i le Huntoer 41110
Data Quality B/D
Spokane, WA
Control Device Not applicable
Reference(s) 27
Data Source Resuspended and analyzed
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Paniculate Hatter -
CAS Nurber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
0t*^» i ca
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
26
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Be
B
F
Na
Hg
Al
S)
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
In
GB
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Ce
Hg
0-2
%ut
1.
11.
27.
0.
0.
0.
1.
0.
0.
0.
0.
5.
0.
0.
0.
0.
0.
NA
HA
NA
NA
870
010
970
300
370
110
540
790
<
440
020
<
240
280
<
010
020
030
<
<
<
<
<
<
010
<
<
050
<
<
<
<
<
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.150
0.780
1.930
0.030
0.100
0.050
0.130
0.070
0.000
0.040
0.000
0.000
0.020
0.370
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.060
0.000
0.000
0.000
0.000
0.000
0.000
by XRF.
: (0-2.5)
: 0.250
2.5-10 urn
Swt
NA
NA
NA
NA
1.870
11.010
27.970
0.300
0.370
0.110
1.540
0.790
<
0.440
0.020
<
0.240
5.280
<
0.010
0.020
0.030
<
<
<
<
<
<
0.010
<
«
0.050
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.150
0.780
1.930
0.030
0.100
0.050
0.130
0.070
0.000
0.040
0.000
0.000
0.020
0.370
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.060
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.370
0-10 urn
Xwt
HE
NE
HE
NE
1.870
11.010
27.970
0.300
0.370
0.110
1.540
0.790
NE
0.440
0.020
Ni
0.240
5.280
NE
0.010
0.020
0.030
NE
NE
NE
NE
NE
NE
0.010
NE
NE
0.050
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.244
1.399
3.537
0.042
0.091
0.042
0.204
0.106
0.000
0.059
0.000
0.000
0.032
0.670
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.049
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.440
Total
Measured
%ut
NE
NE
NE
NE
1.870
11.010
27.970
0.300
0.370
0.110
1.540
0.790
NE
0.440
0.020
NE
0.240
5.280
WE
0.010
0.020
0.030
NE
NE
NE
NE
NE
NE
0.010
NE
NE
0.050
NE
NE
ME
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
352
-------
PK Profile Specialion Report - continued (profile 41110)
Total Participate Matter -
Total
0-2.5 un 2.5-10 urn 0-10 urn Measured
Species ...... .. ............ . ...^
CAS Number Nun Syn %ut unc %Ht unc Xut unc %wt unc
7439-92-1
82
201
202
203
204
Pb
OC
EC
SQ4
N03
0.110
NA
NA
MA
NA
0.020
0.000
0.000
0.000
0.000
0.110
NA
NA
NA
NA
0.020
0.000
0.000
0.000
0.000
0.110
NE
NE
NE
NE
0.020
0.000
0.000
0.000
0.000
0.110
NE
NE
NE
NE
0.000
0.000
0.000
0.000
0.000
TOTALS; 50.170 50.170 50.170 50.t70
353
-------
PH Profile Speciation Report
Profile Name
Profile Nunber
Data Quality
Paved Road Dust - Pasadena Freeway (CA)
41111
C
Control Device
Reference(s)
Data Source
Not Applicable
62 , "
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual inpactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Hass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Hatter
Species
CAS Nurfcer Hunt Sym
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
In
Ga
As
Se
ir
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
**
0-2
%Mt
6
23
. 0
0
0
0
3
0
0
d
0
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
.571
.703
.059
.356
.025
.643
.149
.392
.025
.019
,059
.704
,018
.032
.171
.000
.005
.000
.004
.004
.094
.004
.009
.000
.000
.000
.000
.000
.000
,000
.000
.000
.000
.344
.5 urn
unc
0.936
3.555
0.012
0.018
0.001
0.032
0.157
0.020
0.004
0.002
0.003
0.187
0.001
0.002
0.029
0.005
0.074
0.001
0.001
0.001
0.005
0.004
0.007
0.003
0.003
0.004
0.005
0.006
0.007
0.015
0.031
0.054
0.001
0.063
: <0
: 0
-2.5)
.250
2.5-10 urn
Xwt
6.920
22.315
0.056
0.000
0.000
1.017
4.984
0.493
0.006
0.022
0.108
5.997
0.020
0.037
O.S80
0.001
0.000
0.000
0.001
0.009
0.148
0.005
0.000
0.000
0.000
0.001
0.003
0.000
0.000
0.000
0.117
0.000
0.000
1.526
unc
1.038
3.347
0.011
0.000
0.000
0.051
0.249
0.027
0.006
0.002
0.006
0.302
0.001
0.002
0.029
0.005
0.084
0.001
0.001
0.001
0.008
0.005
0.009
0.002
0.002
0.002
0.003
0.003
0.004
0.009
0.019
0.030
0.001
0.077
(0-6)
0.370
0-10 un
%ut
6.880
22.474
0.057
0.041
0.003
0.974
4.774
0.482
0.009
0.022
0.102
5.735
0.020
0.036
0.579
0.001
0.001
0.000
0.001
0.009
0.142
0.005
0.001
0.000
0.000
0.001
0.003
0.000
0.000
0.000
0.104
0.000
0.000
1.505
unc
1.170
3.964
0.015
0.030
0.002
0.096
0.441
0.055
0.006
0.006
0.015
0.525
0.006
0.008
0.069
0.005
0.076
0.001
0.002
0.004
0.019
0.005
0.008
0.002
0.002
0.003
0.004
0.004
0.005
0.011
0.027
0.038
0.001
0.162
(0-10)
0.440
Total
BeasuredC1>
Xwt
6.880
22.474
0.057
0.041
0.003
0.974
4.774
0.482
0.009
0.022
0.102
5.735
0.020
0.036
0.579
0.001
0.001
0.000
0.001
0.009
0.142
0.005
0.001
0,000
0.000
0.001
0.003
0.000
0.000
0.000
0.104
0.000
0.000
1.505
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
354
-------
PH Profile Speciation Report - continued (profHe 41111)
Total Partieulste Matter -
Total
0-2.5 un 2.5-10 in 0-10 in MeasuredtO
Specfes --—- -•- '...... ... ...
CAS Nunber Hum Sym *;wt unc Xwt unc Xwt unc Xwt unc
201 OC 17.574 1.597 14.502 71.384 14.854 53.840 14.854 0.000
202 EC 0,451 0.130 0.401 0.074 0.407 0.105 0.407 0.000
TOTALS: 58.815 59.269 59.222 59.222
sssss:££ss:sBSSK==isssBBSss=ss5£Sffis=s=s£sssssc£:essssss=caESS=;sszs«ss=£SBCs=ssss:sasB»=s=&s8
<1> Estimated / extrapolated.
355
-------
PH Profile Speciatton Report
Profile Name Paved Road Dust
Profile Number 41112
Data Quality C
- Artesia Freeway {CA>
Control Device Not Applicable
Referencets) 62
Data Source Surface dust sampled, aerosolized, and recollected with a
Sierra diehotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments; 113
Mass Fraction Data - Size Interval (urn) ; (0-2.5) (0-6) (0-10)
Mass Fraction : 0.210 0.370 0.440
Total Partieulate Mattel
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ca
As
Se
Br
Rb
Sr
Y
Er
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Ng
Pb
0-2.5 urn
Xwt
6
17
0
0
.371
.995
.039
.874
0.190
1
4
0
0
0
0
4
0
0
0
q
0
0
0
0
0
0
0
0
0
.0
0
0
0
1 0
0
0
0
0
36
.242
.081
.544
,029
.020
.094
.530
.018
.044
.253
.000
,002
.000
.008
.006
.072
.000
.005
.000
.000
.000
.000
.000
.000
.000
.052
.000
.002
.288
.759
unc
0.956
2.699
0.008
0.044
0.010
0.062
0.204
0.028
0.006
0.002
0.005
0.229
0.002
0.003
0.013
0.001
0.016
0.001
0.001
0.001
0.004
0.002
0.009
0.005
0.005
0.007
0.008
0.010
0.013
0.027
0.052
0.093
0.001
0.015
2.5-10 urn
Xwt
6.460
17.486
0.035
0.718
0.200
1.691
4.512
0.593
0.002
0.020
0.122
5.534
0.019
0.034
0.195
0.001
0.000
0.000
0.011
0.012
0.112
0.001
0.000
0.000
0.000
0.000
0.013
0.000
0.000
0.000
0.145
0.000
0.000
0.278
38.194
unc
0.969
2.623
0.007
0.036
0.010
0.085
0.226
0.033
0.007
0.002
0.006
0.278
0.001
0.002
0.010
0.001
0.015
0.000
0.001
0.001
0.006
0.001
0.007
0.002
0.002
0.002
0.003
0.004
0.005
0.010
0.020
0.033
0.000
0.014
0-10 urn
%wt
6.454
17.524
0.035
0.730
0.199
1.658
4.480
0.589
0.004
0.020
0.120
5.460
0.019
0.034
0.199
0.001
0.000
0.000
0.011
0.012
0.109
0.001
0.000
0.000
0.000
0.000
0.012
0.000
0.000
0.000
0.139
0.000
0.001
0.279
38.090
unc
1.111
3.060
0.011
0.095
0.027
0.164
0.471
0.069
0.007
0.006
0.018
0.548
0.006
0.008
0.030
0.002
0.015
0.001
0.004
0.004
0.016
0.002
0.007
0.003
0.003
0.004
0.007
0.006
0.008
0.017
0.037
0.058
0.001
0.037
Total
HeasuredC1>
%ut
6.454
17.524
0.035
0.730
0.199
1.658
4.480
0.589
0.004
0.020
0.120
5.460
0.019
0.034
0.199
0.001
0.000
0.000
0.011
0.012
0.109
0.001
0.000
0.000
0.000
0.000
0.012
0.000
0.000
0.000
0.139
0.000
0.001
0.279
38.090
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
€13 Estimated / cxtraoolated. 356
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Paved Road Dust * Long Beach Blvd. (CA)
41113
C
Control Device
Referenced)
Data Source
Not Applicable
62
Surface dust sampled, aerosolized, and recollected Kith a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval Cum)
Mass Fraction
Total Partlculate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
^f*»v >«o
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Kn
Fe
Ni
Cu
Zn
Ca
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
ftg
Cd
In
Sn
Sb
Ba
La
Hi
Pb
0-2
%wt
5
17
0
0
0
1
3
0
0
0
0
3
0
0
.611
.174
.250
.576
.268
.260
.836
.347
.028
.024
.091
,967
.014
.025
0.306
0
0
0
0
0
0
0
Q
0
0
0
0
0
0
0
0
0
0
0
34
.000
.004
.000
.005
.002
.028
,000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.302
.118
.5 um
unc
0.842
2.576
0.050
0.029
0.013
0.063
0.192
0.018
0.004
0.002
0.005
0.200
0.002
0.002
0.016
0.002
0.017
0.001
0.002
0.002
0.003
0.003
0.012
0.008
0.008
0.010
0.013
0.016
0.020
0.043
0.081
0.147
0.001
0.017
: (0-2.5)
: 0.250
2.5-10 um
Xwt
5.681
16.088
0.210
0.531
0.258
1.633
3.747
0.415
0.020
0.030
0.104
4.779
0.014
0.025
0.273
0.000
0.000
0.000
0.009
0.011
0.053
0.000
0.014
0.000
0.000
0.000
0.000
0.000
0.007
0.000
0.072
0.000
0.000
0.284
34.258
unc
0.852
2.413
0.042
0.027
0.013
0.082
0.187
0.023
0.006
0.002
0.005
0.240
0.001
0.001
0.014
0.002
0.016
0.000
0.001
0.001
0.003
0.001
0.004
0.002
0.002
0.002
0.003
0.004
0.005
0.011
0.020
0.035
0.000
0.014
•==:2:s;zsKSZ
(0-6)
0.370
0-10 um
Xwt
5.676
16.165
0.213
0.535
0.258
1.606
3.753
0.410
0.021
0.029
0.103
4.721
0.014
0.025
0.275
0.000
0.000
0.000
0.009
0.010
0.051
0.000
0.013
0.000
0.000
0.000
0.000
0.000
0.006
0.000
0.067
0.000
0.000
0.285
34.245
iSE — -BSCSftSS !=
unc
0.978
2.866
0.052
0.067
0.035
0.162
0.421
0.048
0.008
0.007
0.016
0.477
0.005
0.007
0.038
0.001
0.015
0.001
0.004
0.004
0.010
0.002
0.009
0.005
0.005
0.006
0.008
0.010
0.012
0.026
0.050
0.088
0.001
0.038
(0-10)
0.440
Total
MeasuredC1>
Xwt
5.676
16.165
0.213
0.535
0.2S8
1.606
3.753
0.410
0.021
0.029
0.103
4.721
0.014
0.025
0.275
0.000
0.000
0.000
0.009
0.010
0.051
0.000
0.013
0.000
0.000
0.000
0.000
0.000
0.006
0.000
0.067
0.000
0.000
0.285
34.245
*"••"•"- •?: ^ *a as a» a
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
:==csss=
C1> Estimated / extrapolated. 357
-------
PJi Profile Speciation Report
Profile Name
Profile Number
Data Quality
Paved Road Oust - Long Beach, CA
41114
C
Control Device
ReferenceCs}
Data Source
Not Applicable
62 ;
Surface dust* sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Hatter -
Species
CAS Hunter
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Syn
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
2r
NO
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Kg
Pb
0-2
Xut
: 5
13
0
1
0
1
' 4
0
0
0
0
3
0
0
0
0
0
0
0
0
0
.185
.459
.254
.002
.406
.222
.193
.328
.027
.022
.083
.692
.012
.025
.223
.001
.008
.000
.007
.002
.038
0.000
0
0
0
0
0
0
0
Q
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.156
.5 urn
unc
0.778
2.019
0.051
0.050
0.020
0.061
0.210
0.017
0.004
0.002
0.005
0.187
0.002
0.002
0.012
0.001
0.009
0.001
0.002
0.002
0.003
0.003
0.013
0.008
0.008
0.010
0.014
0.017
0.021
0.046
0.086
0.157
0.002
0.010
: CO
: 0
-2.5)
.250
2.5-10 urn
Xwt
5.181
14.306
0.227
0.903
0.460
1.551
3.929
0.404
0.016
0.027
0.092
4.314
O."013
0.026
0.226
0.000
0.000
0.000
0.009
0.011
0.083
0.000
0.015
0.000
0.000
0.000
0.008
0.000
0.008
0.000
0.104
0.000
0.000
0.152
unc
0.777
2.146
0.046
0.045
0.023
0,078
0.196
0.022
0.005
0.002
0.005
0.217
0.001
0.001
0.011
0.002
0.009
0.001
0.001
0.001
0.004
0.001
0.005
0.002
0.002
0.002
0.003
0.003
0.004
0.009
0.018
0.029
0.000
0.008
(0-6)
0.370
0-10 urn
%wt
5.181
14.251
0.229
0.909
0.456
1.530
3.946
0.400
0.017
0.027
0.092
4.274
0.013
0.026
0.225
0.000
0.001
0.000
0.008
0.010
0.081
0.000
0.014
0.000
0.000
0.000
0.007
0.000
0.008
0.000
0.097
0.000
0.000
0.153
unc
0.898
2.405
0.054
0.111
0.053
0.156
0.453
0.047
0.007
0,007
0.015
0.438
0.005
0.007
0.030
0.001
0.008
0.001
0.004
0.004
0.013
0.002
0.010
0.005
0.005
0.006
0.009
0.010
0.013
0.027
0.052
0.092
0.001
0.023
(0-10)
0.440
Total
Measured^
Xwt
5.181
14.251
0.229
0.909
0.456
1.530
3.946
0.400
0.017
0.027
0.092
4.274
0.013
0.026
0.225
0.000
0.001
0.000
0.008
0.010
0.081
0.000
0.014
0.000
0.000
0.000
0.007
0.000
0.008
0.000
0.097
0.000
0.000
0.153
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
358
-------
PN Profile Speefation Report - continued (profile 41114J
Total Particulate
CAS Number Hum
201
202
Matter
Sym
OC
EC
Total
0-2.5 un 2.5-10 urn 0-10 urn Measuredd}
%ut unc %wt unc %wt unc Xwt unc
19.626 3.184 18.959 1.465 19.002 2.858 19.002 0.000
2.213 0.407 1.188 0.100 1.254 0.311 1.254 0.000
TOTALS: 52.184 52.212 52.211 52.211
sssssssssssxssssscBsrascssssssssasssssKSSsssssBrBscssBsssBKsssss
<1> Estimated / extrapolated.
359
-------
PH Profile Speeiation Rtport
Profile Hatne
Profile Number
Data Quality
Paved Road Oust - La Cienega Blvd. (CA)
41115
C
Control Device
ReferenceCs)
Data Source
Not Applicable
62
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ioniration.
SCC Assignments: 113
Mass Fraction Data -
Size Interval (un)
Hass Fraction
Total Particulate Hatter - .
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS;
0-2
Hum Sym Xwt
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
<1> Estimated /
Al
Si
P
S
ct
(C
ca
Ti
V
cr
Hn
Fe
Ni
Cu
In
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
5.
14.
0.
0.
0.
0.
1.
0.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
837
851
023
220
067
915
622
308
017
009
063
268
007
010
046
000
003
000
002
003
014
000
000
000
000
000
000
0.000
0.
0.
0.
0.
0.
0.
000
000
000
000
000
026
.5 urn
unc
0.876
2.228
0.005
0.011
0.003
0.046
0.081
0.016
0.004
0.001
0.004
0.165
0.001
0.001
0.003
0.001
0.002
0.001
0.001
0.001
0.002
0.002
0.007
0.005
0.004
0.006
0.008
0.010
0.011
0.025
0.048
0.087
0.001
0.003
27.311
extrapolated.
: (0-2.5)
s 0.250
2.5-10 urn
Xut
8.096
20.769
0.028
0.184
0.059
1.698
2.336
0.517
0.011
0.018
0.111
5.302
0.011
0.013
0.062
0.000
0.000
0.000
0.004
0.014
0.040
0.001
0.005
0.000
0.000
0.000
0.000
0.000
0.004
o.oos
0.099
0.000
0.000
0.049
39.436
360
unc
1.214
3.115
0.006
0.009
0.003
0.085
0.117
0.028
0.006
0.002
0.006
0.267
0.001
0.001
0.003
0.000
0.003
0.000
0.000
0.001
0.002
0.001
0.004
0.002
0.002
0.002
0.003
0.003
0.004
0.009
0.018
0.029
0.000
0.003
CO-6)
0.370
0-10 urn
Xut
7.957
20.406
0.028
0.186
0.059
1.650
2.292
0.504
0.011
0.018
0.108
5.177
0.011
0.013
0.061
0.000
0.000
0.000
0.004
0.013
0.038
0.001
0.005
0.000
0.000
0.000
0.000
0.000
0.004
0.005
0.093
0.000
0.000
0.048
38.692
unc
1.236
3.156
0.008
0.028
0.012
0.148
0.219
0.052
0.007
0.005
0.016
0.465
0.004
0.005
0.011
0.000
0.003
0.000
0.003
0.005
0.008
0.001
0.006
0.003
0.003
0.004
0.005
0.006
0.008
0.016
0.033
0.054
0.001
0.009
(0-10)
0.440
Total
HeasuredC1>
Xwt
7.957
20.406
0.028
0.186
0.059
1.650
2.292
0.504
0.011
0.018
0.108
5.177
0.011
0.013
0.061
0.000
0.000
0.000
0.004
0.013
0.038
0.001
0.005
0.000
0.000
0.000
0.000
0.000
0.004
0.005
0.093
0.000
0.000
0.048
38.692
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-------
PM Profile Spec!ation Report
Profile Name
Profile number
Data Quality
Paved Road Dust - Hawthorne, CA
41116
C
Control Device
Reference(s)
Data Source
Not Applicable
62
Surface dust sarqpled, aerosolized, and recollected with a
Sierra dichototnous virtual impactor. Analyzed using XRF and
flame ionizatlon.
SCC Assignments: 113
Mass Fraction Data - Sfze Interval (urn)
Mass Fraction
Total Particulate Matter
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS;
ap^w i e?s
Hum Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
AS
Cd
In
Sn
Sb
Ba
La
Hi
Pb
0-2.5 urn
%ut
6.146
17,411
0.040
0,648
0.130
1.080
2.864
0.326
0.024
0.018
0.076
3.530
0.016
0.031
0.164
0.000
0.004
0.000
0.008
0.004
0.044
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.180
32.744
unc
0.922
2.612
0.008
0.032
0.007
0.054
0.143
0.017
0.004
0.002
0.004
0.178
0.002
0.002
0.009
0.001
0.011
0.001
0.001
0.001
0.003
0.002
0.009
0.006
0.005
0.007
0.009
0.011
0.014
0.030
0.056
0.102
0.001
0.010
: (0-2.5)
: 0.250
2.5-10 urn
Sut
5,810
15.633
0.031
0.398
0.134
1.414
2.618
0.408
0.009
0.017
0.101
4.245
0.013
0.020
0.162
0.000
0.000
0.000
0.008
0.012
0.076
0.001
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.085
0.004
0.000
0.132
31 .339
unc
0.872
2.345
0.006
0.020
0.007
0.071
0.131
0.023
0.005
0.002
0.005
0.214
0.001
0.001
0.008
0.001
0.007
0.000
0.001
0.001
0.004
0.001
0.005
0.002
0.002
0.002
0.003
0.004
0.005
0.010
0.019
0.032
0.000
0.007
(0-6)
0.370
0-10 um
Xwt
5.
15.
0.
0.
0.
1.
2.
0.
0.
0.
0.
4.
0.
. o.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
830
739
032
413
134
394
633
403
010
017
100
202
013
021
162
000
000
000
008
011
074
001
007
000
000
000
0.000
0.
0.
0.
0.
0.
0.
0.
31.
000
000
000
080
003
000
135
422
unc
1.033
2.845
0.010
0.066
0.020
0.141
0.308
0.047
0.006
0.005
0.015
0.425
0.005
0.006
0.023
0.001
0.008
0.000
0.004
0.004
0.012
0.002
0.007
0.004
0.003
0.004
0.006
0.007
0.008
0.018
0.037
0.063
0.001
0.023
(0-10)
0.440
Total
Heasured£1>
Xwt
5.830
15.739
0.032
0.413
0.134
1.394
2.633
0.403
0.010
0.017
0.100
4.202
0.013
0.021
0.162
0.000
0.000
0.000
0.008
0.011
0.074
0.001
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,080
0,003
0.000
0.135
31.422
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{1> Estimated / extrapolated.
3C1
-------
PM Profile Specfation Report
Profile Name
Profile Number
Data Quality
Paved Road Dust • Victory Blvd. (CA)
41117
C
Control Device
Reference(s)
Data Source
Not Applicable
62
Surface dust sampled, aerosolized, and recollected with a
Sierra dfehotomous virtual inpaetor. Analyzed using XRF and
flame ionization.
SCO Assignments: 113
Mass Fraction Data - Size Interval Cum) :
Hess Fraction :
Total Particulatt Matter
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
s
Cl
K
Ca
Tf
V
Cr
Kn
Fe
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
4
12
0
0
0
q
3
0
0
0
; 0
3
0
0
0
0
0
, 0
0
0
0
.062
.435
.325
.864
.368
.836
.941
,331
.022
.023
.067
.538
.011
.041
.267
.001
.009
.000
,008
.000
.019
0.000
0
0
0
0
0
0
d
0
0
0
0
0
27
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.281
.449
.5 urn
unc
0.609
1.865
0.065
0.043
0.018
0.042
0.197
0.017
0.004
0.002
0.004
0.179
0.001
0.003
0.014
0.002
0.016
0.001
0.001
0.002
0.002
0.003
0.011
0.006
0.006
0.009
0.011
0.014
0.017
0.037
0.070
0.125
0.001
0.015
r <0-2.5)
: 0.250
2.5-10 urn
Xwt
4.913
13.602
0.283
0.700
0.389
1.332
4.986
0.441
0.020
0.031
0.092
4.618
0.013
0.040
0.275
0.000
0.000
0.000
0.012
0.010
0.054
0.000
0.009
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.081
0.000
0.000
0,334
32.238
unc
0.737
2.040
0.057
0.035
0.019
0.067
0.249
0.023
0.005
0.002
0.005
0.232
0.001
0.002
0.014
0.001
0.018
0.000
0.001
0.001
0.003
0.001
0.004
0.002
0.001
0.002
0.002
0.003
0.004
0.008
0.015
0.026
0.000
0.017
<0-6)
0.370
0-10 urn
Xwt
4.880
13.557
0.284
0.707
0.388
1.312
4.946
0.437
0.020
0.031
0.091
4.576
0.013
0.040
0.275
0.000
0.000
0.000
0.012
0.010
0.052
0.000
0.009
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.078
0.000
0.000
0.332
32.053
unc
0.787
2.259
0.067
0.093
0.047
0.123
0.485
0.049
0.007
0.007
0.014
0.444
0.005
0.009
0.036
0.001
0.017
0.001
0.004
0.004
0.010
0.002
0.008
0.004
0.004
0.005
0.007
0.008
0.010
0.022
0.043
0.074
0.001
0.040
<0-105
0.440
Total
Measured-CD
Xwt
4.880
13.157
0.284
0.707
0.388
1.312
4.946
0.437
0.020
0.031
0.091
4.576
0.013
0.040
0.275
0.000
0.000
0.000
0.012
0.010
0.052
0.000
0.009
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.078
0.000
0.000
0.332
32.053
_ _ m. — sj-ag «*t 3—3
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C1> istimated / extrapolated.
362 .
-------
PH Profile Speciat ion Report
Profile Name
Profile ttunber
Data Quality
Paved Road Dust - Burbank, CA
41118
C
Control Device Net Applicable
Reference(s) 62
Data Source Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual fmpsctor. Analyzed using XRF and
flame ionizetion.
SCC Assignments: 113
Mass Fraction Data - Size Interval
-------
PH Profile Speciation Report - continued (profile 41118)
Total Participate Natter *
Total
0-2.5 in 2.5-10 urn 0-10 urn MeasuredCD
Species ' ••
CAS Number Hum Sym Xwt unc Xwt unc Xut unc %ut unc
201 OC 10.647 1.669 15.978 2.162 15.651 2.266 15.651 0.000
202 EC 0.999 0.207 1.778 0.225 1.730 0.248 1.730 0.000
TOTALS: 40.966 50.726 50.128 50.128
KESESX3=SE3SSKff&S:3KSX3X=S3:X33:S=:SS3SSES=S:s;S£SS=Sr=SS!KK=SSSS:RSS==SSS:«S3:5SSSSS=;SSSS8&=SSSSSS:
<1> Estimated / extrapolated.
364
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Paved Koed Dust - North Main St., Los Angeles, CA
41119
€
Control Device
Reference(s)
Data Source
Net Applicable
62
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionizstion.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-SO-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
,3j^^v i ^a
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
73
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Ai
Si
P
S
Cl
1C
Cs
T)
V
Cr
Hn
Fe
Ni
Cu
Zn
Ge
A,-
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
sb
Ba
La
Kg
Pb
0-2
%wt
2
9
0
0
0
0
3
0
0
0
0
7
0
0
0
0
n
0
0
Q
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.893
.439
.524
.852
.352
.663
.609
.258
.025
,031
.078
.120
.011
.050
.398
.001
.006
.000
,002
.000
,030
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.137
.5 un
unc
0.434
1.416
0.105
0.043
0.018
0.033
0.180
0.014
0.004
0.002
0.005
0,359
0.002
0.003
0.021
0.001
0.008
0.001
0.001
0.002
0.003
0.002
0.012
0.007
0.007
0.009
0.012
0.014
0.017
0.039
0.073
0.130
0.001
0.009
: (0-Z.5)
: 0.250
2.5-10 urn
%wt
3.734
10.987
0.496
0.782
0.428
1.107
4.405
0.354
0.019
0.039
0.089
6.131
0.013
0.059
0.437
0.000
0.000
0.000
0.006
0.009
0.084
0.000
0.013
0.004
0.000
0.000
0.000
0.000
0.012
0.000
0.091
0.000
0,000
0.175
unc
0.560
1.648
0.099
0.039
0.021
0.055
0.220
0.020
0.005
0.002
0.005
0.308
0.001
0.003
0.022
0.001
0.010
0.000
0.001
0.001
0.004
0.001
0.005
0.002
0.002
0.002
0.003
0.003
0.004
0.009
0.018
0.030
0,000
0.009
<0-6)
0.370
0-10 urn
Xwt
3.689
10.905
0.498
0.785
0.424
1.084
4.363
0.349
0.019
0,039
0.088
6.184
0.012
0.059
0.435
0.000
0.000
0.000
0.006
0.008
0.081
0.000
0.012
0.003
0.000
0.000
0.000
0.000
0.012
0.000
0.086
0.000
o.boo
0.173
unc
0.586
1.781
0.111
0.096
0.049
0.102
0.437
0.040
0.007
0.008
0.014
0.744
0.004
0.011
0.052
0.001
0.009
0.001
0.003
0.004
0.013
0.002
0.009
0.005
0.004
0.005
0.007
0.009
0.011
0,023
0,045
0.077
0.001
0.023
(0-10)
0.440
Total
HeasuredO }
Xwt
3.689
10.905
0.498
0.785
0.424
1.084
4.363
0.349
0.019
0.039
0.088
6.184
0.012
0.059
0.435
0.000
0.000
0.000
0.006
0.008
0.081
0.000
0.012
0.003
0.000
0.000
0.000
0.000
0.012
0.000
0.086
0.000
0.000
0.173
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
365
-------
PH Profile Speciation Report - continued (profile 41119}
Total ParticuUte Hatter -
Total
• 0-2.5 un 2.5-10 urn 0-10 un HeasuredCO
Species —......... ... , ...
CAS Number Hum Sym Xwt unc Xwt unc Xut unc %wt unc
201 OC 19.26? 5.454 21.522 1.630 21.403 3.877 21.403 0,000
202 EC 0.858 0.429 1,718 0.137 1.672 0.295 1.672 0.000
TOTALS: 46.604 52.714 52.389 52.389
»&SKKSCCSS:SS£:=S£SCSCS=Se=£SCKSE==ttBSS=SKSS==SXe£=S=Sa£SeSSSSSSSSK:33;=SS££E==aSS35=£?S:=S=
C1> Estimated / extrapolated.
366
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Paved Road Dust - Los Angeles, CA
41120
C
Control Device
Reference(s)
Data Source
Not Applicable
62
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impector. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval (un> ;
Mass Fraction ;
Total Particulate Hatter -
Species
CAS Nuiber
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91 -0
7439-97-6
7439-92-1
TOTALS:
Num
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br '
Rb
Sr
Y
Zr
Mo
Pd
AS
Cd
In
Sn
Sb
ia
La
Hg
Pb
0-2,
Xut
4
10
0
0
0
0
2
0
0
0
0
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Q
0
0
0
0
0
0
0
24
.456
.398
.223
.943
.270
.641
.877
.352
.031
.066
.077
.301
.048
.056
.458
.000
.014
.000
.002
.000
.012
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.282
.507
,5 urn
unc
0.669
1.560
0.045
0.047
0.014
0.032
0.144
0.019
0.005
0.004
0.005
0.167
0.003
0.004
0.024
0.002
0.016
0.001
0.002
0.002
0.003
0.003
0.014
0.008
0.008
0.010
0.014
0.017
0.021
0.046
0.085
0.157
0.002
0.016
: (0-2.5)
! 0.250
2.5-10 urn
%wt
4.859
11.889
0.224
0.838
0.300
1.059
3.715
0.560
0.033
0.103
0.080
4.621
0.070
0.061
0.426
0.000
0.000
0.000
0.006
0.009
0.066
0.000
0.005
0.016
0.000
0.000
0.000
0.000
0.007
0.000
0.050
0.000
0.000
0.307
29.304
unc
0.729
1.783
0.045
0.042
0.015
0.053
0.186
0.029
0.007
0.005
0.004
0.232
0.004
0.003
0.021
0.002
0.017
0.000
0.001
0.001
0.003
0.001
0.005
0.003
0.002
0.002
0.003
0.004
0.004
0.009
0.019
0.032
0.000
0.016
(0-6)
0.370
0-10 urn
Xut
4.843
11.827
0.224
0.843
0.299
1.041
3.680
0.552
0.033
0.101
0.080
4.566
0.069
0.061
0.427
0.000
0.001
0.000
0.006
0.008
0.064
0.000
0.005
0.015
0.000
0.000
0.000
0.000
0.007
0.000
0.048
0.000
0.000
0.306
29.106
unc
0.811
1.940
0.051
0.104
0.037
0.098
0.360
0.057
0.009
0.015
0.014
0.431
0.012
0.011
0.055
0.002
0.016
0.001
0.003
0.004
0.011
0,002
0.009
0.007
0.005
0.006
0.008
0.010
0.013
0.027
0.051
0.092
0.001
0.038
(0-10)
0.440
Total
Measureddl
%Ht
4.843
11.827
0.224
0.843
0.299
1.041
3.680
0.552
0.033
0.101
0.080
4.566
0.069
0.061
0.427
0.000
0.001
0.000
0.006
0.008
0.064
0.000
0.005
0.015
0.000
0.000
0.000
0.000
0.007
0.000
0.048
0.000
0.000
0.306
29.106
unc
0.000
0.000
0.000
O.OQO
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<1> Estimated / extrapolated.
367
-------
PH Profile Speciat ion Report
Profile Name
Profile Nunber
Data Quality
Paved Road Dust - South Harbor Blvd., Anaheim, CA
41121
C
Control Device
Reference(s)
Data Source
Not Applicable
62
Surface dust sampled, aerosolized, and recollected with a
Sierra djchotanous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval Cum}
Mass Fraction
Total Paniculate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
apet* i es
Num Syra
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2.
' Xwt
: 3.
10.
0.
1.
0.
0.
3.
0.
0.
0.
0.
2.
0.
0.
0.
, 0.
0.
0.
0.
0.
: 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
23.
821
645
191
209
818
847
108
188
017
023
050
268
008
041
220
000
002
000
007
000
081
000
000
000
000
000
000
000
000
000
000
000.
000
126
670
,5 urn
unc
0.573
1.597
0.038
0.060
0.041
0.042
0.155
0.011
0.003
0.002
0.004
0.115
0.002
0.003
0.012
0.001
0.008
0.001
0.002
0.002
0.005
0.003
0.015
0.009
0.009
0.012
0.015
0.019
0.023
0.050
0.094
0.171
0.002
0.009
! (0-2.5}
: 0.250
2.5-10 urn
Xwt
3.720
11.378
0.185
1.237
0.797
1.320
3.864
0.288
0.015
0.036
0.073
3.416
0.012
0.017
0.178
0.000
0.000
0.000
0.011
0.011
0.132
0.000
0.015
0.000
0.004
0.005
0.005
0.000
0.008
0.000
0.108
0.000
0.000
0.169
27.004
unc
0.558
1.707
0.037
0.062
0.040
0.066
0.193
0.017
0.005
0.002
0.004
0.172
0.001
0.001
0.009
0.001
0.009
0.000
0.001
0.001
0.007
0.001
0.008
0.002
0.002
0.002
0.003
0.004
0.005
0.010
0.020
0.033
0.000
0.009
(0-6}
0.370
0-10 urn
Xwt
3.726
11.337
0.186
1.235
0.798
1.293
3.822
0.283
0.015
0.035
0.072
3.353
0.011
0.018
0.181
0.000
0.000
0.000
0.011
0.011
0.129
0.000
0.014
0.000
0.003
0.004
0.005
0.000
0.008
0.000
0.102
0.000
0.000
0.167
26.819
unc
0.654
1.909
0.043
0.140
0.095
0.123
0.381
0.033
0.006
0.008
0.012
0.311
0.004
0.006
0.028
0.001
0.008
0.001
0.004
0.004
0.018
0.002
0.011
0.005
0.006
0.007
0.009
0.011
0.014
0.030
0.057
0.100
0.001
0.022
0.440
Total
Measuredd)
Xwt
3.726
11.337
0.186
1.235
0.798
1.293
3.822
0.283
0.015
0.035
0.072
3.353
0.011
0.018
0.181
0.000
0.000
0.000
0.011
0.011
0.129
0.000
0.014
0.000
0.003
0.004
0.005
0.000
0.008
0.000
0.102
0.000
0.000
0.167
26.819
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.QQO
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
----=----~-==------~-==-=-=-=------==----.-.-,.....=-..-..-=--~=-------~-===~=----==--=~=--=
{13 Estimated /
extrapolated.
368
-------
PM Profile Speciation Report
Prof i le Name
Profile Number
Data Quality
Paved Road Dust
41122
C
Anaheim, CA
Control Device
Reference(s)
Data Source
Not Applicable
62
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size
Mass
Total Paniculate Matter -
Species
CAS Number Nun
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-15-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
C1> Estimated
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
p
S
Cl
1C
Ca
T)
V
Cr
Hn
Fe
Ni
Cu
In
Ga
As
Se
Sr
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
ia
La
Hg
Pb
Interval (urn) :
Fraction ;
0-2
%wt
4
14
0
0
0
1
4
0
0
0
0
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
31
/ extrapolated
.994
.029
.290
.941
.412
.073
.890
.338
.024
.022
.098
.550
.015
.023
.202
.000
.005
.000
.005
.001
.035
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.167
.114
.5 un
unc
0.749
2.104
0.058
0.047
0.021
0.054
0.244
0.018
0.004
0.002
0.005
0.179
0.001
0.002
0.010
0.001
0.010
0.001
0.001
0.001
0.002
0.002
0.007
0.004
0.004
0.005
0.007
0.008
0.010
0.023
0.042
0.076
0.001
0.009
(0-2.5)
0.250
2.5-10 tin
X»t
5.259
14.421
0.237
0.899
0.414
1.461
5.325
0.424
0.020
0.026
0.107
4.306
0.015
0.021
0.196
0.000
0.000
0.000
0.007
0.011
0.058
0.000
0.010
0.003
0.000
0.000
0.004
0.000
0.006
0.000
0.017
0.000
0.001
0.174
33.422
369
unc
0.789
2.163
0.047
0.045
0.021
0.073
0.266
0.022
0.005
0.002
0.005
0.217
0.001
0,001
0.010
0.002
0.010
0.000
0.001
0.001
0.003
0.001
0.004
0.001
0.001
0.002
0.002
0.003
0.003
0.007
0.014
0.023
0.000
0.009
(0-6)
0.370
0-10 un
%Mt
5.243
14.397
0.240
0.902
0.414
1.438
5.299
0.419
0.021
0.026
0.107
4.261
0,015
0.021
0.196
0.000
0.000
0.000
0.007
0.011
0.056
0.000
0.009
0.003
0.000
0.000
0.004
0.000
0.006
0.000
0.016
0.000
0.001
0.174
33.286
unc
0.890
2.460
0.059
0.107
0.051
0.143
0.560
0.048
0.007
0.007
0.017
0.429
0.005
0.006
0.027
0.002
0.009
0.000
0.003
0.004
0.010
0.001
0.006
0.003
0.003
0.003
0.005
0.005
0.007
0.014
0.027
0.047
0.001
0.024
(0-10)
0.440
Total
Measuredd}
Xtrt
5.243
14.397
0.240
0.902
0.414
1.438
5.299
0.419
0.021
0.026
0.107
4.261
0.015
0.021
0.196
0.000
0.000
0.000
0.007
0.011
0.056
0.000
0.009
0.003
0.000
0.000
0.004
0.000
0.006
0.000
0.016
0.000
0.001
0.174
33.286
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-------
PH Profile Speciation Report
Profile Name
Profile Nurfaer
Data Quality
Paved Road Dust - Riverside, CA
41123
C
Control Device
Reference(s)
Data Source
Hot Applicable
62
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual inpactor. Analyzed using XRF and
flame iohization.
sec Assignments: 113
Mass Fraction Data - Size Interval (urn)
Hass Fraction
Total Partfeulate Hatter
Species
CAS Number Hum Sym
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
, 7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
SO
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
fe
til
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
No
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
-
0-2
Xwt
8
18
0
d
0
1
- 3
0
0
0
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
, 0
0
0
0
.320
.597
.228
.739
.241
.667
.793
.458
.028
.025
.117
.789
.008
.010
.087
.000
.012
.000
,003
.005
.028
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.101
.5 urn
uric
1.248
2.790
0.046
0.037
0.012
0.083
0.190
0.024
0.005
0.002
0.006
0.241
0.001
0.001
0.005
0.003
0.007
0.001
0.001
0.001
0.002
0.002
0.009
0.005
0.005
0.007
0.009
0.011
0.014
0.031
0.058
0.105
0.001
0.007
: (0-2.5)
: 0.250
2.5-10 urn
%wt
7.123
16.470
0.187
0.555
0.232
1.913
3.590
0.496
0.022
0.027
0.119
5.117
0.008
0.010
0.086
0.000
0.000
0.000
0.007
0.014
0.044
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.055
0.000
0.000
0.114
unc
1.068
2.471
0.037
0.028
0.012
0.096
0.180
0.026
0.006
0.002
0.006
0.257
0.001
0.001
0.004
0.002
0.006
0.000
0.001
0.001
0.002
0.001
0.004
0.002
0.002
0.002
0.003
0.003
0.004
0.009
0.017
0.029
0.000
0.006
(0-6)
0.370
0-10 urn
%wt
7.213
16.630
0.190
0.569
0.233
1.894
3.605
0.493
0.023
0.027
0.119
5.093
0.008
0.010
0.086
0.000
0.001
0.000
0.006
0.014
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
0.000
0.000
0.113
unc
1.331
3.019
0.047
0.079
0.032
0.200
0.412
0.058
0.008
0.007
0.018
0.544
0.004
0.004
0.015
0.002
0.006
0.000
0.003
0.005
0.009
0.001
0.006
0.003
0.003
0.004
0.006
0.007
0.008
0.019
0.036
0.063
0.001
0.017
(0-10)
0.440
Total
MeasuredC1>
Xwt
7.213
16.630
0.190
0.569
0.233
1.894
3.605
0.493
0.023
0.027
0.119
5.093
0.008
0.010
0.086
0.000
0.001
0.000
0.006
0.014
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
0.000
0.000
0.113
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
370
-------
PM Profile Speciation Report • continued {profile 41123)
Total Partieulate Hatter •
Total
0-2.S urn 2.5-10 urn 0-10 urn HeasuredCD
Species ,
CAS Number Num Sys Xwt unc %ut unc %ut unc Xut unc
201 DC 7.478 1.127 11.801 0.948 11.475 1.446 11,475 0.000
202 EC Q.419 0.174 0.174 0.051 -0.192 0.113 0.192 0.000
TOTALS: 47.153 48.164 48.088 48.088
se:5;ss£ssssss£S=:sass=BS&ssssffiS=s:ss=ssssss3ssssss=sec==:eass:rssssEasss:sasss£ss=ss=s=:s:sa£:
C1> Estimated / extrapolated.
371
-------
PH Profile Speciation Report
Profile Name Paved Road Dust -
Profile Number 41124
Data Quality C
Sepulveda Tunnel, Los Angeles
,CA
Control Device Hot Applicable
Reference(s) 62
Data Source Surface dust sampled, aerosolized, and recollected with a
Sierra dfchototnous virtual inpactor. Analyzed using XRF and
flame ioniza.tion.
SCC Assignments: 113
Mass Fraction Data - Size Interval (ura3 ; (0-2.5)
Suit
7.336
20.653
0.179
1.204
0.312
1.493
3.076
0.614
0.021
0.039
0.102
5.413
0.009
0.094
0.268
0.002
0.000
0.001
0.025
0.012
0.429
0.000
0.016
0.000
0.001
0.001
0.007
0.000
0.000
0.016
0.158
0.039
0.002
0.425
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
372
-------
PM Profile Speciation Report - continued (profile 41124)
Total Particulate Matter -
Total
0-2.5 un 2.5-10 urn 0-10 urn HeasuredCU
Species •- -•-
CAS Nunber Nun Sym %wt une Xwt une %wt une Xwt une
201 OC 13.780 2.75S 12.805 0.916 12.867 2.169 12.867 0.000
202 EC 1.753 0.581 0.579 0.050 0.653 0.363 0.653 0.000
TOTALS: 52.866 15.644 55.467 55.467
CD Estimated / extrapolated.
373
-------
PH Profile SpeciatIon Report
Profile Name Paved Road Dust -
Profile Number 41130
Data Quality E
Composite
Control Device Not applicable
ReferenceCs) 19,27,28,42,43,44,45,46,48
Data Source Developed from profiles 41101. 41102, 41103, 41104,
41105, 41106, 41107, 41109, and 41110.
SCC Assignments: 113
Mass Fraction Data - Size Interval
-------
PM Profile Specialion Report - continued
-------
PH Profile Speciation Report
Profile Name Paved Road Dust -
Profile Number 41131
Data Quality C
Freeway Composite
Control Device Not Applicable
Reference(s) 62
Data Source Developed from profiles
SCC Assignments 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Par tieu late Hatter -
CAS Nurfcer
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-3E-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31 -5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
aj-^fst^ i ca
Nun Syn
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
202
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Nn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
2r
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
K
0-2
Xut
6.
20.
0.
0.
0.
0.
3.
0.
0.
0.
0.
4.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
q.
0.
0.
0.
0.
o.
471
849
049
615
107
943
615
468
027
020
076
117
018
038
412
000
004
000
006
005
083
002
007
000
000
000
000
000
000
000
026
0.000
0.
0.
17.
0.
56.
001
816
574
451
800
.5 un
unc
0.710
2.854
0.010
0.259
0.083
0.300
0.466
0.076
0.004
0.001
0.018
0.413
0.001
0.006
0.159
0.002
0.038
0.001
0.002
0.001
0.011
0.002
0.006
0.003
0.003
0.004
0.005
0.006
0.007
0.016
0.030
0.054
0.001
0.528
1,666
0.131
41111 and 41112
(0-2.5)
; 0.250
2.5-10 urn
%wt
6.690
19.901
0.046
0.359
0.100
1.354
4.748
0.543
0.004
0.021
0.115
5.765
0.019
0.035
0.388
0.001
0.000
0.000
0.006
0.011
0.130
0.003
0.000
0.000
0.000
0.001
0.008
0.000
0.000
0.000
0.131
0.000
0.000
0.902
14.502
0.401
56.184
unc
0.710
2.415
0.011
0.359
0.100
0.337
0.236
0.050
0.005
0.001
0.007
0,232
0.001
0.001
0.193
0.003
0.043
0.000
0.005
0.002
0.018
0.003
0.006
0.001
0.001
0.002
0.005
0.003
0.003
0,007
0.014
0.022
0.000
0.624
1.289
0.074
*
(0-6)
0.370
0-10 urn
Xwt
6.667
19.999
0.046
0.385
0.101'
1.316
4.627
0.535
0.006
0.021
0.111
5.597
0.019
0.035
0.389
0.001
0,000
0.000
0.006
0.010
0.126
0.003
0.001
0.000
0.000
0.000
0.007
0.000
0.000
0.000
0.121
0.000
0.000
0.892
14.854
0.407
56.282
unc
0.935
3.171
0.014
0.313
0.090
0.327
0.515
0.080
0.005
0.006
0.019
0.557
0.006
0.009
0.177
0.003
0.039
0.001
0.005
0.004
0.022
0.003
0.005
0.002
0.002
0.003
0.006
0.004
0.005
0.010
0.026
0.035
0.001
0.565
2.129
0.105
(0-10)
0.440
Total
HeasuredC1>
Xut
6.667
19.999
0.046
0.385
0.101
1,316
4.627
0.535
0.006
0.021
0.111
5.597
0.019
0.035
0.389
0.001
0.000
0.000
0.006
0.010
0.126
0.003
0.001
0.000
0.000
0.000
0.007
0.000
0.000
0.000
0.121
0.000
0.000
0.892
14,854
0.407
56.282
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Estimated / .trapolated. 376
-------
PM Profile Speciatfon Report
Profile Name Pavsd Road Dust -
Profile number 41132
Data Quality C
Composite- Long Beach,
Control Device Net Applicable
Reference(s) 62
Data Source Developed from profiles
SCC Assignments 113
Mass Fraction Date - Size Interval (urn)
Mass Fraction
Total Participate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
m Estimal
0^C^ 1 C»
Hum Svm
13
14
15
16
17
19
20
22
23
24
25
2o
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
202
red /
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
fe
, Hi
Cu
Zn
Ga
As
Se
Br
Rb'
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
SH
Sb
Ba
La
Hi
Pb
oc
EC
er.tr aes'.
0-2
Xwt
5
15
0
0
0
1
4
0
0
0
0
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Q
0
.398
.316
.252
.789
.337
.241
.014
.337
.027
.023
.087
.830
.013
.025
.264
.001
.006
.000
.006
.002
.033
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.229
19.626
2
54
»«-~^
.213
.069
.5 urn
une
0.611
1.857
0.037
0.213
0.069
0.066
0.213
0.013
0.003
0.002
0.005
0.204
0.001
0.002
0.041
0.001
0.010
0.001
0.001
0.001
0.005
0.002
0.009
0.006
0.006
0.007
0.010
0.012
0.014
0.031
0.059
0.108
0.001
0.073
3.370
0.425
41113 and 41114
: (0-2.5)
: 0.250
2.5-10 urn
%wt
5.431
15.197
0.219
0.717
0.359
1.592
3.838
0.410
0.018
0.029
0.098
4.546
0.014
0.025
0.249
0.000
0.000
0.000
0.009
0.011
0.068
0.000
0.014
0.000
0.000
0.000
0.004
0.000
0.007
0.000
0.088
0.000
0.000
0.218
18.959
1.188
53.308
377
unc
0.577
1.615
0.031
0.186
0.101
0.057
0.136
0.016
0.004
0.001
0.006
0.232
0.001
0.001
0.024
0.001
0.009
0.001
0.000
0.001
0.015
0.001
0.003
0.001
0.001
0.002
0.004
0.003
0.003
0.007
0.016
0.023
0.000
0.066
1.467
0.100
CA
(0-6)
0.370
0-10 urn
Xut
5.429
15.208
0.221
0.722
0.357
1.568
3.849
0.405
0.019
0.028
0.097
4.497
0.014
0.025
0.250
0.000
0.000
0.000
0.009
0.010
0.066
0.000
0.014
0.000
0.000
0.000
0.004
0.000
0.007
0.000
0.082
0.000
0.000
0.219
19.002
1.254
53.356
unc
0.775
2.209
0.043
0.202
0.095
0.154
0.427
0.046
0.007
0.007
0.016
0.460
0.005
0.007
0.043
0.001
0.009
0,001
0.004
0.004
0.016
0.001
0.007
0.003
0.003
0.004
0.007
0.007
0.009
0.019
0.038
0.063
0.001
0.071
2.926
0.319
(0-10)
0.440
Total
Measuredm
%Ht
5.429
15.208
0.221
0.722
0.357
1.568
3.849
0.405
0.019
0.028
0.097
4.497
0.014
0.025
0.250
0.000
0.000
0.000
0.009
0.010
0.066
0.000
0.014
0.000
0.000
0.000
0.004
0.000
0.007
0.000
0.082
0.000
0.000
0.219
19.002
1.254
53.356
unc
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-------
PM Prof!It Speciatfon Report
Profile Name Paved
Profile Number 41133
Data Quality C
Rond Dust -
Hawthorne Composite
Control Device Net Applicable
Reference(s) 62
Data Source Developed from profiles 61115 and 41116
SCC Assignments 113
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.250
Total Participate Hatter -
CAS Hunfcer
7429-9Q-S
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-4
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
SSSBSKSSS::::::
opcfc* 1 t.E»
Hum Sym
13
14
15
16
17
19
20
22
23
24
25
26
23
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
%ut
5
16
0
0
0
: 0
2
0
0
0
0
3
0
0
0
0
0
0
0
. 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.992
.131
.031
.434
.099
.998
.243
.317
.020
.014
.070
.399
.012
.021
.105
.000
.003
.000
.005
.004
.029
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.103
.5 urn
unc
0.676
1.826
0.008
0.214
0,031
0.083
0.621
0.017
0.003
0.004
0.007
0.178
0.005
0.010
0.059
0.001
0.005
0.001
0.003
0.001
0.015
0.001
0.006
0.004
0.004
0.005
0.006
0.007
0.009
0.019
0.037
0.067
0.001
0.077
30.030
2.5-10 urn
%ut
6.953
18.201
0.030
0.291
0.096
1.556
2.477
0.463
0.010
0.018
0.106
4.773
0.012
0.017
0.112
0.000
0.000
0.000
0.006
0.013
0.058
0.001
0.006
0.000
0.000
0.000
0.000
0.000
0.002
0.003
0.092
0.002
0.000
0.091
35.389
unc
1.143
2.568
0.004
0.107
0.038
0.142
0.141
0.055
0.004
0.001
0.005
0.529
0.001
0.004
0.050
0.000
0.004
0.000
0.002
0.001
0.018
0.001
0.003
0.001
0.001
0.002
0.002
0.003
0.003
0.007
0.013
0.022
0.000
0.042
<0-6>
0.370
0-10 urn
%ut
6.894
18.072
0.030
0.299
0.097
1.522
2.462
0.454
0.010
0.017
0.104
4.690
0.012
0.017
0.111
0.000
0.000
0.000
0.006
0.012
0.056
0.001
0.006
0.000
0.000
0.000
0.000
0.000
0.002
0.002
0.086
0.002
0.000
0.092
35.056
unc
1.134
2.756
0.009
0.152
0.037
0.173
0.438
0.062
0.005
0.006
0.016
0.569
0.005
0.008
0.053
0.000
0.004
0.000
0.004
0.004
0.019
0.001
0.005
0.002
0.002
0.003
0.004
0.005
0.006
0.012
0.026
0.041
0.001
0.056
<0-10)
0.440
Total
MeasuredO>
%ut
6.894
18.072
0.030
0.299
0.097
1.522
2.462
0.454
0.010
0.017
0.104
4.690
0.012
0.017
0.111
0.000
0.000
0.000
0.006
0.012
0.056
0.001
0.006
0.000
0.000
0.000
0.000
0.000
0.002
0.002
0.086
0.002
0.000
0.092
35.056
unc
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0,000
0,000
C1> Estimated / extrapolated.
378
-------
PM Profile Spec int ion Report
Profile Name
Profile Number
Data Quality
Paved Road Dust -
41134
C
Burbank Composite
Control Device Not Applicable
Reference(s) 62
Data Source Developed from profiles 41117 omd 41118.
SCC Assignments 113
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.2SO 0.370
Total Particulate Natter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
aptfi; 1 KS
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
202
•C1J Estimated /
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
fe
Ni
Cu
Zn
Ge
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Kg
Pb
DC
EC
0-2.
%wt
4.
12.
0.
0.
0.
0.
4.
0.
286
550
274
368
358
877
742
332
0.022
0.
021
0.071
3.
428
0.010
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
. 0.
0.
0.
0.
0.
10.
0.
40.
033
242
001
007
000
006
000
023
000
000
000
000
000
000
000
000
000
000
000
000
231
647
999
028
5 urn
unc
0.492
1.439
0.051
0.049
0.020
0.049
0.801
0.019
0.003
0.002
0.005
0.193
0.001
0.008
0.025
0.001
0.010
0.001
0.002
0.001
0.004
0.002
0.008
0.005
0.005
0.007
0.009
0.011
0.013
0.028
0.053
0.096
0.001
0.050
1.789
0.216
extrapolated.
2.5-10 urn
%wt
4.974
13.845
0.248
0.702
0.372
1.342
5.359
0.436
0.020
0.029
-0.093
4.449
0.013
0.033
0.245
0.000
0.000
0.000
0.010
0.010
0.052
0.000
0.005
0.002
0.000
0.000
0.005
0.000
0.006
0.000
0.074
0.000
0.000
0.280
15.978
1.778
50.360
379
unc
0.528
1 .469
0.035
0.025
0.017
0.048
0.373
0.017
0.004
0.002
0.003
0.169
0.001
0.007
0.030
0.001
0.011
0.000
0.002
0.001
0.002
0.001
0.005
0.002
0.001
0.001
0.005
0.002
0.006
0.006
0.012
0.020
0.000
0.054
2.163
0.225
0-10 urn
%wt
4.941
13.779
0.249
0.710
0.371
1.319
5.333
0.431
0.020
0.028
0.092
4.399
0.013
0.033
0.245
0.000
0.000
0.000
0.010
0,010
0,051
0.000
0.004
0.002
0.000
0.000
0.005
0.000
0.006
0.000
0.070
0.000
0.000
0.277
15.651
1.730
49.779
unc
0.665
1.884
0.051
0.093
0.046
0.121
0.729
0.047
0.007
0.007
0.014
0.418
0.004
0.010
0.040
0.001
0.010
0.000
0.004
0.004
0.010
0.001
0.006
0.003
0.003
0.004
0.007
0.006
0.009
0.017
0.033
0.057
0.001
0.059
2.296
0.251
(0-10)
0.440
Total
Neasuredm
%ut
4.941
13.779
0.249
0.710
0.371
1.319
5.333
0.431
0.020
0.028
0.092
4.399
0.013
0.033
0.245
0.000
0.000
0.000
0.010
0.010
0.051
0.000
0.004
0.002
0.000
0.000
0.005
0.000
0.006
0.000
0.070
0.000
0.000
0.277
15.651
1.730
49.779
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-------
PM Profile Speciation Report.
Profile Name
Profile Nurfaer
Data Quality
Paved Road Dust
41135
C
- Los Anseles Composite
Control Device Not Applicable
Reference(s) 62
Data Source Developed from profiles 41119 and 41120.
SCC Assignments 113
Mass Fraction Data - Size Interval Cwn) : (0-2.5) (0-6)
Hass Fraction : 0.250 0.370
Total Particulatc Matter -
CAS Nurber
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
*J^» V 1 C3
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
202
C1> Estimated /
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
EC
0-2.5 urn
' Xwt
3
9
d
0
0
0
3
0
0
0
0
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
19
0
45
.675
.919
.373
.898
.311
.652
.243
.305
.028
.048
.078
.210
.029
.053
.428
.000
.010
.000
.002
.000
.021
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
,000
.209
.267
.858
.617
unc
0.782
1.170
0.150
0.056
0.041
0.040
0.366
0.047
0.003
0.018
0.005
1.910
0.019
0.004
0.030
0.001
0.009
0.001
0.001
0.001
0.009
0.002
0.009
0.005
0.005
0.007
0.009
0.011
0.014
0.030
0.056
0.102
0.001
0.073
5.579
0.432
extrapolated.
2.5
%ut
4.297
11,438
0.360
0.810
0.364
1.083
4.060
0.457
0.026
0.071
0.084
5.376
0.041
0.060
0.431
0.000
0.000
0.000
0.006
0.009
0.075
0.000
0.009
0.010
0.000
0.000
0.000
0.000
0.010
0.000
0.070
0.000
0.000
0.241
21.522
1.718
52.628
380
-10 urn
unc
0.563
1.215
0.136
0.029
0.064
0.038
0.345
0.103
0.007
0.032
0.004
0.755
0.029
0.002
0.015
0.001
0.010
0.000
0.000
0.000
0.009
0.001
0.004
0.006
0.001
0.002
0.002
0.003
0.003
0.007
0.021
0.022
0.000
0.066
1.631
0.137
0-10 urn
Xwt
4.266
11.366
0.361
0.814
0.361
1.062
4.022
0.450
0.026
0.070
0.084
5.375
0.041
0.060
0.431
0.000
0.000
0.000
0.006
0.008
0.072
0.000
0.008
0.009
0.000
0.000
0.000
0.000
0.009
0.000
0.067
0.000
0.000
0.240
21.403
1.672
52.283
unc
0.728
1.534
0.140
0.100
0.067
0.097
0.488
0.093
0.009
0.028
0.014
1.333
0.026
0.011
0.053
0.001
0.009
0.000
0.003
0.004
0.014
0.001
0.007
0.007
0.003
0.004
0.005
0.007
0.009
0.018
0.037
0.060
0.001
0.071
3.935
0.296
(0-10)
0.440
Total
HeasuredC1>
%Ht
4.266
11.366
0.361
0.814
0.361
1.062
4.022
0.450
0.026
0.070
0.084
5.375
0.041
0.060
0.431
0.000
0.000
0.000
0.006
0.008
0.072
0.000
0.008
0.009
0.000
0.000
0.000
0.000
0.009
0.000
0.067
0.000
0.000
0.240
21 .403
1.672
52.283
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.opo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-------
W* Profile Speciation Report
Profile Name Paved
Profile Number 41136
Data Quality C
Road Dust -
Anaheim Composite
Control Device Mot Applicable
Reference(s) 62
Data Source Developed from profiles
SCO Assignments 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Partieulate Matte
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Num
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
A8
Cd
In
Sn
Sb
Ba
La
Hg
Pb
>r -
0-2
Swt
4
12
0
1
0
0
3
0
Q
0
0
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
27
.407
.337
,241
.075
.615
.960
.999
.263
.021
.023
.074
.909
.011
.032
.211
.000
.003
.000
.006
.001
.058
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.147
.393
.5 URI
unc
0.586
1.692
0.049
0.134
0.203
0.113
0.891
0.075
0.003
0.002
0.024
0.641
0.003
0.009
0.012
0.001
0.006
0.001
0.001
0.001
0.023
0.002
0.008
0.005
0.005
0.006
0.008
0.010
0.013
0.028
0.052
0.094
0.001
0.020
41121 and 41122.
: CO-2.5) CO-6)
: 0.250 0.370
.••*
2.S-10 urn
Xwt
4.490
12.899
0.211
1.068
0.606
1.390
4.595
0.356
0.018
0.031
0.090
3.861
0.013
0.019
0.187
0.000
0.000
0.000
0.009
0.011
0.095
0.000
0.012
0.001
0.002
0.002
0.005
0.000
0.007
0.000
0.062
0.000
0.001
0.172
30.213
unc
0.769
1.521
0.030
0.169
0.192
0.071
0.731
0.068
0.003
0.005
0.017
0.445
0.002
0.002
0.009
0.001
0.007
0.000
0.002
0.001
0.037
0.001
0.004
0.001
0.002
0.002
0.002
0.002
0.003
0.006
0.046
0.020
0.001
0.006
0-10 un
Xwt
4.484
12.867
0.213
1.069
0.606
1.366
4.561
0.351
0.018
0.031
0.089
3.807
0.013
0.020
0.189
0.000
0.000
0.000
0.009
0.011
0.093
0.000
0.012
0.001
0.002
0.002
0.004
0.000
0.007
0.000
0.059
0.000
0.001
0.170
30.055
unc
0.803
1.944
0.046
0.186
0.197
0.145
0.859
0.076
0.006
0.008
0.023
0.594
0.005
0.008
0.027
0.001
0.006
0.000
0.004
0.004
0,034
0.001
0.007
0.003
0.003
0.004
0.006
0.006
0.008
0.016
0.046
0.055
0.001
0.025
(0-10)
0.440
Total
NeasuredCU
Xwt
4.484
12.867
0.213
1.069
0.606
1.366
4.561
0.351
0.018
0.031
0.089
3.807
0.013
0.020
0.189
0.000
o.ooo
0.000
0.009
0.011
0.093
0.000
0.012
0.001
0.002
0.002
0.004
0.000
0.007
0.000
0.059
0.000
0.001
0.170
30.055
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
•CO Estimated / extrapolated.
381
-------
PH Profile Speeiation Report
Profile Hame Paved Road Oust -
Profile Number 41137
Data Quality C
SCAB Composite
Control Device Not Applicable
Reference(s) SOCA8
Data Source Developed from profiles 41131, 41132, 41133, 41134, 41135,
41123, and 41124.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.250 0.370
Total ParticuUte Hatter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Hum
\
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
Sym
At
Si
P
S
Ct
K
Ca
Ti
V
Cr
Hn
Fe
Hi
Cu
Zn
Ga
As
Se
Er
Kb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
0-2
%ut
5
15
0
, 0
0
1
3
; Q
0
0
0
3
0
0
0
0
0
0
0
0
0
0
0
! o
0
0
0
0
0
0
d
0
0
0
14
.704
.444
.212
.935
.298
.032
.623
.375
.025
.025
.081
.920
.014
.036
.251
.000
.006
.000
.007
.002
.063
.000
.011
.000
.001
.001
.001
.001
.000
.000
.015
.000
.000
.275
.729
.5 urn
unc
0.556
1.296
0.041
0.175
0.058
0.107
0.257
0.033
0.001
0.004
0.006
0.269
0.002
0.007
0.044
0.001
0.006
0.000
0.002
0.001
0.025
0.001
0.010
0.002
0.002
0.002
0.003
0.004
0.004
0.010
0.018
0.033
0.000
0.083
2.023
2.5-
%wt
5.914
16.099
0.184
0.706
0.305
1.470
3.966
0.473
0.017
0.033
0.101
4.927
0.016
0.037
0.246
0.000
0.000
0.000
0.010
0.012
0.121
0.001
0.007
0.002
0.000
0.000
0.004
0.000
0.004
0.003
0.092
0.006
0.000
0.306
15.928
10 urn
unc
0.443
1.191
0.038
0.10S
0.059
0.085
0.332
0.029
0.003
0.006
0.004
0.225
0.004
0.010
0.043
0.001
0.007
0.000
0.002
0.001
0.047
0.000
0.003
0.001
0.001
0.001
0.001
0.001
0.001
0.003
0.013
0.009
0.000
0.093
1.520
0-10 un
Xwt
5.904
16.072
0.186
0.721
0.305
1.443
3.942
0.467
0.018
0.033
0.100
4.859
0.016
0.037
0.246
0.000
0.000
0.000
0.010
0.011
0.117
0.000
0.008
0.002
0.000
0.000
0.003
0.000
0.004
0.002
0.087
0.005
0.000
0.303
15.875
unc
0.737
1.936
0.045
0.157
0.066
0.154
0.474
0.056
0.006
0.009
0.015
0.487
0.006
0.012
0.051
0.001
0.006
0.001
0.004
0.004
0.041
0.001
0.007
0.002
0.001
0.001
0.003
0.002
0.004
0.006
0.019
0.020
0.001
0.091
2.208
(0-10)
0.440
Total
Heasuredt1>
Xwt
5.904
16.072
0.186
0.721
0.305
1.443
3.942
0.467
0.018
0.033
0.100
4.859
0,016
0.037
0.246
0.000
0.000
0.000
0.010
0.011
0.117
0.000
0.008
0.002
0.000
0,000
0.003
0.000
0,004
0.002
0,087
0.005
0.000
0.303
15.875
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
382
-------
PM Profile Speciation Report • continued (profile 41137)
Total Participate Matter -
Total
0-2.5 un 2.5-10 urn 0-10 urn MeasuredCI}
Species •-- —-
CAS Number Nun Sym felt unc Xwt unc Xwt unc %Ut UflC
202 iC 1.116 0.295 0.973 0.2S1 0.985 0.292 0.985 0.000
TOTALS: 48.203 51.963 51.761 51.761
=5wSSS~=S!SSS—==^.£.^«~^~^—«&U^^Si^es—SS£!&aSBSCSis£SSBS=SS3S8s=:££CSB=SwS£
(1> Estimated / extrapolated.
383
-------
PM Profile Speciation Report
Profile Name Road Sand and Salt Mixture
Profile Kunfcer 41401
Data Quality C/0
Control Device Not applicable
RefereneeCs) 43
Data Source Sample sieved and resuspended.
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.250
Total Participate Matter -
Species
CAS Nurrber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7440-45-1
7439-97-6
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
46
47
48
49
50
51
56
58
80
Sym
Be
B
f
Na
Mg
At
Si
P
S
Cl
1C
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Sc
Br
Rb
Sr
Pd
Ag
Cd
In
Sn
Sb
Sa
Ce
Hg
0-2
%wt
13
33
. 0
0
8
1
- 3
0
0
0
0
4
0
0
0
0
0
0
0
d
NA
NA
NA
NA
NA
.453
.403
.393
.977
.375
.425
.735
<
.385
.030
.037
.122
.970
<
.020
.292
.253
<
<
<
<
.016
<
.027
.036
.057
<
<
.032
<
<
<
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
1.345
3.340
0.039
0.105
0.837
0.142
0.373
0.000
0.038
0.000
0.000
0.012
0.497
0.000
0.000
0.029
0.025
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.023
0.031
0.044
0.052
0.058
0.107
0.285
0.000
0.000
2.5-10 urn
%Ht
NA
NA
NA
NA
NA
7.848
20.909
0.260
0.706
8.832
1.194
2.387
<
0.353
0.022
0.025
0.087
3.775
<
<
0.169
0.123
<
<
<
<
<
<
0.021
<
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.785
2.091
0.026
0.071
0.883
0.119
0.239
0.000
0.035
0.000
0.000
0.000
0.377
0.000
0.000
0.017
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<0-6>
0.370
0-10 urn
Xwt
NE
NE
NE
NE
NE
11.033
28.008
0.336
0.860
8.572
1.325
3.153
NE
0.371
0.027
0.032
0.107
4.454
NE
NE
0.239
0.197
NE
NE
NE
NE
NE
NE
0.024
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
1.533
3.878
0.046
0.121
1.198
0.183
0.436
0.000
0.051
0.000
0.000
0.000
0.614
0.000
0.000
0.033
0.028
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<0-10)
0.440
Total
Measured
%wt
NA
NA
NA
NA
NA
8.638
23.964
0.260
0.754
10.095
1.191
2.388
<
0.388
0.023
0.025
0.089
4.059
<
<
0.151
0.052
<
<
<
<
<
<
0.026
<
<
<
<
<
<
<
<
<
une
0.000
0.000
0.000
0.000
0.000
0.864
2.396
0.026
0.075
1.009
0.119
0.239
0.000
0.039
0.000
0.000
0.000
0.406
0.000
0.000
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.027
0.000
0.000
384
-------
PH Profile Speciation Report - continued (profile 41401)
Total Paniculate Matttr •
Total
0-2.5 urn 2.5-10 urn 0-10 um Measured
Species —---
CAS Number Nun Sym Xwt unc Xwt unc %Mt unc %wt unc
7439-92-1
TOTALS:
82
201
202
203
204
Pb
OC
iC
S04
N03
0.253
NA
NA
NA
NA
68.291
0
0
0
0
0
.027
.000
.000
.000
.000
0.107
NA
HA
NA
NA
46.818
0.011
0.000
0.000
0.000
0.000
0.190
NE
m
Hi
NE
58.928
0.028
0,000
0.000
0.000
0.000
0.049
NA
NA
NA
NA
52.152
0.000
0.000
0.000
0.000
0.000
385
-------
386
-------
3.15 NATURAL SOURCES
Natural sources-of participate emissions include sources such as marine
aerosols, volcanic ash, and soil dust. Marine aerosol particulates would be
most significant in coastal areas. Volcanic ash and soil dust would be more
significant in rural areas than urban areas.
387
-------
3S8
-------
PH Profile Speciation Report
Profile Kane Soil Oust -
Profile Number 41301
Data Quality C/E
Des Koines,
IA
Control Device Not applicable
Reference(s) 26
Data Source XRF, C, end C03 analysis of resuspended soils. Each sample
was a composite of 3 subsamples.
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Particulate
Matter
(0-10)
o.oso
Total
CAS Kunber
7440-41-7
7440-42-8
7782-41 -4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
*|^?%* I «#3
Num Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
Be
B
F
Na
Mi
At
Si
P
S
Cl
K
C8
SC
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
AS
Cd
Sn
Sb
Cs
Ba
Ce
3
15
0
0
0
0
10
0
0
0
0
3
0
0
0
0
0
0
0
0
0-2
Xwt
KA
MA
NA
NA
NA
,717
.631
.108
.746
.192
.596
.007
<
.197
.017
.017
.092
.950
<
.006
.027
.044
<
<
.009
<
.006
<
.028
<
<
<
<
.001
<
.033
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
%wt
NA
NA
NA
NA
NA
3.717
15.631
0.108
0.746
0.192
0.596
10.007
<
0.197
0.017
0.017
0.092
3.950
<
0.006
0.027
0.044
<
<
0.009
<
0.006
<
0.028
<
<
<
<
0.001
<
0.033
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NA
NA
NA
NA
NA
3.717
15.631
0.108
0.746
0.192
0.596
10.007
<
0.197
0.017
0.017
0.092
3.950
<
0.006
0^027
0.044
<
<
0.009
<
0.006
<
0.028
<
<
<
<
0.001
<
0.033
<
unc
0.000
0.000
0.000
0.000
0.000
0.186
0.782
0.005
0.037
0.010
0.030
0.500
0.000
0.010
0.001
0.001
0.005
0.198
0.000
0.000
0.001
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.000
Measured
Xwt
NA
NA
NA
NA
NA
3.717
15.631
0.108
0.746
0.192
0.596
10.007
<
0.197
0.017
0.017
0.092
3.950
<
0.006
0.027
0.044
<
<
0.009
<
0.006
<
0.028
<
<
<
<
0.001
<
0.033
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
389
-------
PH Profile Specfation Report - continued (profile 41301)
Total Particulste Hatter -
Total
0-2.5 urn 2.5-10 un 0-10 urn Measured
•Species •- •
CAS Number Nun Sym Xwt unc %ut unc Xwt unc Xwt unc
7439-97-6
7439-92-1
TOTALS:
============
80
82
200
203
204
206
==3X3
Ha
Pb
TC
S04
N03
C03
S3S2SS
0
1
24
62
— ssrssssa
<
.066
.962
NA
NA
.651
.103
=====
0.000
0.000
0.000
0.000
0.000
0.000
33— Sj-SBSJB!
<
0.066
1.962
NA
NA
24.651
62.103
=SJSS===
0.000
0.000
0.000
0.000
0.000
0.000
ssssssss
<
0.066
1.962
NA
NA
24.651
62.103
:========
0.000
0.003
0.098
0.000
0.000
1.233
SKKESSSS
<
0.066
1.962
NA
NA
24.651
62.103
========
0.000
0.000
0.000
0.000
0.000
0.000
======
390
-------
PH Proffie Speciation Report
Profile Name Soil Dust • Seattle, UA
Profile Number 41302
Data Quality C/E
Control Device Not applicable
Reference(sJ 27
Data Source Resuspended through a dichotomous impactor and analyzed by
XRF, INNA, and carbon oxidation.
Mass Fraction Data - Size Interval Cum) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Paniculate Hatter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
»|*st; i tts
Hum Sym
4
-3
9
11
12
13
14
15
16
17
19
20
21
Z2
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
Be
B
f
Ha
Mg
Al
Si
P
s
Cl
K
Ca
Sc
11
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Sr
Rb
Sr
Zr
*.s
Cd
Sn
Sb
Cs
Ba
Ce
0-2
Xwt
1.
11.
27.
0.
0.
0.
0.
0.
Q.
0.
0.
4.
0.
0.
0.
0.
NA
NA
NA
NA
280
120
336
336
380
024
719
864
<
440
039
<
144
989
<
<
008
042
<
<
<
<
<
<
021
<
<
039
<
<
<
<
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.108
0.743
1.780
0.031
0.088
0.035
0.066
0.070
0.000
0.038
0.009
0.000
0.014
0.340
0.000
0.000
0.006
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.008
0.000
0.000
0.055
0.000
0.000
0.000
0.000
0.000
2.5-
%wt
NA
NA
NA
NA
1.280
11.120
27.336
0.336
0.380
0.024
0.719
0.864
<
0.440
0.039
<
0.144
4.989
<
<
0.008
0.042
<
<
<
, <
<
<
0.021
<
<
0.039
<
<
<
<
<
10 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NA
NA
NA
NA
1.280
11.120
27.336
0.336
0.380
0.024
0.719
0.864
<
0.440
0.039
<
0.144
4.989
<
<
0.008
0.042
<
<
<
<
<
<
0.021
<
<
0.039
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.069
0.586
1.437
0.019
0.029
0.009
0.040
0.047
0.000
0.024
0.003
0.000
0.008
0.264
0.000
0.000
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.000
0.000
0.014
0.000
0.000
0.000
0.000
0.000
(0-10)
0,080
Total
Measured
%Mt
NA
NA
NA
NA
1.280
11.120
27.336
0.336
0.380
0.024
0.719
0.864
<
0.440
0.039
<
0.144
4.989
<
<
0.008
0.042
<
<
<
<
<
<
0.021
<
<
0.039
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
391
-------
PH Profile Speciation Report - continued (profile 41302}
Total Paniculate Matter -
CAS Number Nun • Sym
7439-97-6 80
7439-92-1 82
201
202
203
204
Ha.
Pb
OC
EC
S04
N03
0-2
Xut
<
0.107
NA
NA
NA
NA
.5
un
unc
0
0
0
0
0
0
.000
.022
.000
.000
.000
.000
2.5-10 urn
Xut
<
0.107
NA
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
<
0.107
NA
NA
NA
NA
unc
0.
0.
0.
0.
0.
0.
000
008
000
000
000
000
Total
Measured
Xut
<
0.107
NA
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
47.888
47.888
47.888
47.888
392
-------
PK Profile Spec!at ion Report
Profile Name Soil Dust - Visalia, CA
Profile Number 41303
Data Quality D/E
Control Device Not applicable
Reference(s) 31
Data Source 7 soil samples
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Part icul ate
£>_....
CAS Nunfcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
optsi
Num
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
4C
50
51
55
56
58
80
Matter
*ies
Sytn
Be
B
F
Na
Hi
At
Si
p
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
r- -jr
Sn
Sb
Cs
Ba
Ce
Hg
0-2.5 un
Xut
1
0
5
19
0
0
NR
NR
NR
.200
.400
.000
.700
<
.300
.200
1.500
2
0
0
0
0
3
.500
<
.200
.050
.050
.050
.000
<
0.050
0
0
0
0
0
0
.050
.050
<
<
<
•c
.050
<
<
<
<
<
<
<
^ <
,300
.300
.300
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
s CO-2.5)
: 0.020
2.5-10 urn
Xut
NR
NR
NR
1.200
0.400
5.000
19.700
<
0.300
0.200
1.500
2.500
<
0.200
0.050
0.050
0.050
3.000
<
0.050
0.050
0.050
<
<
<
<
0.050
<
<
<
<
<
<
<
<
0.300
0.300
0.300
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.040
0-10 urn
Xut
NR
NR
NR
1.200
0.400
5.000
19.700
<
0.300
0.200
1.500
2.500
<
0.200
0.050
0.050
0.050
3.000
<
0.050
0.050
0.050
<
<
<
<
0.050
<
<
<
<
<
<
<
<
0.300
0.300
0.300
unc
0.000
0.000
0.000
0.060
0.020
0.250
0.985
0.000
0.015
0.010
0.075
0.125
0.000
0.010
0.003
0.003
0.003
0.150
0.000
0.003
0.003
0.003
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
0.011
0.015
(0-10)
0.080
Total
Measured
Xwt
NR
NR
NR
1.200
0.400
5.000
19.700
<
0.300
0.200
1.500
2.500
<
0.200
0.050
0.050
0.050
3.000
<
0.050
0.050
0.050
<
<
<
<
0.050
<
<
<
<
<
<
<
<
0.300
0.300
0.300
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
393
-------
PH Profile Specfation Report - continued (profile 41303}
Total Participate Hatter -
Species
CAS Nunber
7439-92-1
Nun
82
201
202
203
204
Sym
Pb
OC
EC
S04
N03
0-2.5 urn
Xut
0.200
NR
NR
NR
NR
uric
0.000
0.000
0.000
0.000
0.000
2.5-10 ucn
Xut
0.200
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0-10 un
Xut
0.200
NR
HR
NR
NR
unc
0.010
0.000
0.000
0.000
0.000
Total
Measured
Xut
0.200
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
TOTALS;
35.450
35..45Q
35.450
35 .450
354
-------
PM Profile Speciat ion Report
Profile Name Soil Oust - South
Profile Number 41304
Data Quality B/C
Bend,
Indiana
Control Device Hot applicable
Reference(s) 32
Data Source Sample is a mix of 3 subsamples. Total parti cut ate
composition assumed similar to coarse mode.
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Particutate Matter
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
Num
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
Sym
Be
B
F
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
¥
Cr
Hn
Fe
Co
N>
Cu
In
Ga
Ge
As
Se
Br
Rb
Sr
Zr
AS
Cd
Sn
Sb
Cs
Ba
Ce
0-2
Xwt
NA
NA
NA
NA
NA
9.040
29.675
<
7.323
0.743
1.563
1.230
<
0.370
<
0.061
0,136
4.138
<
0.028
<
0.280
<
<
<
<
0.280
<
<
<
<
<
<
<
<
<
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
2.299
7.270
0.000
2.135
0.390
4.680
0.365
0.000
0.129
0.000
0.061
0.074
1.069
0.000
0.051
0.000
0.101
0.000
0.000
0.000
0.000
0.106
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
NA
NA
NA
NA
NA
7.581
30.660
<
0.302
0.171
1.500
2.030
<
0.416
0.016
0.032
0.120
3.535
<
0.006
<
0.071
<
<
<
<
0.003
<
<
<
<
'<
<
<
<
<
<
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
urn
unc
.000
.000
.000
.000
.000
.433
.684
.000
.064
.031
.099
.124
.000
.030
.006
.006
.010
.206
.000
.003
.000
.009
.000
.000
.000
.000
.004
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0-10 urn
Xwt
NE
NE
NE
NE
NE
7.946
30.414
NE
2.057
0.314
1.516
1.830
NE
0,404
HE
0.039
0,124
3.686
NE
0.011
NE
0.123
NE
NE
NE
NE
0.072
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.718
2.399
0.000
0.594
0.101
1.173
0.128
0.000
0.039
0.000
0.016
0.020
0.333*
0.000
0.013
0.000
0.027
0.000
0.000
0.000
0.000
0.028
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
Xwt
NA
NA
NA
NA
NA
7.581
30.660
<
0.302
0.171
1.500
2.030
<
0.416
0.016
0.032
0.120
3.535
<
0.006
<
0.071
<
<
<
<
0.003
<
<
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.433
1.684
0.000
0.064
0.031
0.099
0.124
0.000
0.030
0.006
0.006
0.010
0.206
0.000
0.003
0.000
0.009
0.000
0.000
0.000
0.000
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
395
-------
PH Profile Speefatfon Report - continued (profile 41304}
Total Particulate Hatter -
Total
0-2.5 urn 2.5-10 un 0-10 urn Measured
Species — ——
CAS Nufiber Nun Sym • %ut unc Xwt unc Xut unc Xwt unc
7439-97-6
7439-92-1
80
82
201
202
203
204
Hg
Pb
OC
EC
S04
N03
<
d.143
HA
NA
NA
HA
0.000
0.436
0.000
0.000
0.000
0.000
<
0.083
NA
NA
NA
NA
0
0
0
0
0
0
.000
.016
.000
.000
.000
.000
NE
0.098
NE
NE
NE
NE
0.000
0.109
0.000
0.000
0.000
0.000
<
0.083
NA
NA
NA
NA
0.000
0.016
0.000
0.000
0.000
0.000
TOTALS: 55.010 46.S26 48.634 46.526
396
-------
t>M Profile Spec\otioo Report
Profile Name Soil Oust - Houston
Profile Number 41305
Data Quality 8/0
, TX
Control Device Not applicable
Reference(s) 40
Data Source ietntrained soil dust analyzed by XRF.
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0,020
Total Participate Matter
CAS Ninfcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
0JJIKV 1 C9>
Nun Sym
4
5
?
11
12
13
14
15
16
17
19
20
21
22
•>z
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Be
8
;•
Na
Mg
Al
Si
P
S
Cl
K
Ca
Se
Ti
a
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
AS
Cd
Sn
Sb
Cs
Ba
Ce
Hg
0-2
Xut
NA
NA
NA
NA
NA
5.600
17.200
<
<
<
0.900
7.000
<
0.400
<
<
0.060
2.800
<
<
0.500
0.300
<
<
<
<
<
<
<
<
<
<
<
<
<
. <
<
*
.5
urn
unc
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0.000
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
2.5-10 un
%Ht
NA
NA
NA
NA
NA
5.600
17.200
<
<
<
0.900
7.000
<
0.400
<
<
0.060
2.800
<
<
0.500
0.300
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
2.800
5.300
0.000
0.000
0.000
0.135
1.050
0.000
0.060
0.000
0.000
0.009
0.420
0.000
0.000
0.075
0.045
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.040
0-10 urn
Xwt
NA
NA
NA
NA
NA
5.600
17.200
<
<
<
0.900
7.000
<
0.400
<
<
0.060
2.800
<
<
0.500
0.300
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.754
1.580
0.000
0.000
0.000
0.056
0.438
0.000
0.025
0.000
0.000
0.004
0.175
0.000
0.000
0,031
0.019
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
%wt
NA
NA
NA
NA
NA
5.600
17.200
<
<
<
0.900
7.000
<
0.400
<
<
0.060
2.800
<
<
0.500
0.300
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
*
unc
0.000
0.000
0.000
0.000
0.000
2,800
5.300
0.000
0.000
0.000
0.135
1.050
0.000
0.060
0.000
0.000
0.009
0.420
0.000
0.000
0.075
0.045
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
397
-------
PM Profile Speeiatfon Report - continued (profile 41305*
Total Partfculate Hatter -
Total
CAS Number
7439-9E-1
Htm Sym
82
201
202
203
204
Pb
OC
EC
S04
NOB
0-2
Xut
0.040
NA
NA
NA
NA
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
2.5-10 un
Xwt
0.040
NA
NA
NA
NA
unc
0.006
0.000
0.000
0.000
0.000
0-10
Xut
0.040
NA
HA
NA
NA
0
0
0
0
0
un
unc
.003
.000
.000
.000
.000
Measured
Xwt
0.040
NA
NA
NA
NA
unc
0.006
0.000
0.000
0.000
0.000
TOTALS!
34.800
34.800
34.800
34.800
398
-------
PH Profile Speclation Report
Profile Name : Soil Dust - East Helena, Montana
Profile Number s 41306
Data Quality : B/0
Control Device : Not applicable
Reference(s) : 43
Data Source : Resuspended and analyzed by XRF.
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.020
Total Particulate Matter
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
df^v 1 c.a
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
• 40
50
51
55
56
58
80
Be
B
F
Ha
Mg
At
Si
P
S
Cl
K
Ce
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
CJ
Sn
Sb
Cs
Ba
Ce
H9
0-2
fcrt
NA
NA
NA
1.000
2.000
18.000
48.000
<
0.240
0.200
2.000
1.800
<
0.760
0.030
0.020
0.280
8.500
<
<
0.050
<
. <
<
<
<
<
<
<
<
<
<
<
<
<
<
<
*
.5
0
0
0
0
0
1
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
urn
unc
.000
.000
.000
.200
.700
.000
.000
.000
.150
.080
.100
.100
.000
.060
.020
.020
.030
.500
.000
.000
.030
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
2.5-10 urn
%wt
NA
NA
NA
1.100
1.900
9.100
29.000
<
0.200
0.120
1.800
1.730
<
0.790
0.030
0.030
0.170
6.900
<
<
0.020
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
*
unc
0.000
0.000
0.000
0.100
0.300
O.SOO
1.000
0.000
0.020
0.000
0.100
0.090
0.000
0.040
0.000
0.000
0.000
0.300
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.040
0-10 urn
%Ht
NE
NE
NE
1.075
1.925
11.625
33.750
NE
0.210
0.140
1.850
1.747
NE
0.782
0.030
0.028
0.198
7.300
NE
NE
0.028
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.077
0.214
0.772
2.060
0.000
0.039
0.000
0.101
0.094
0.000
0.043
0.000
0.000
0.000
0.414
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
Xut
NE
NE
NE
1.075
1.925
11.625
33.750
NE
0.210
0.140
1.850
1.747
NE
0.782
0.030
0.028
0.198
7.300
NE
NE
0.028
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
399
-------
PH Profile Speeietion Report. - continued (profile 41306)
Total Participate Hatter -
Total
0-2.5 urn 2.5-10 urn 0-10 im Measured
Species •
CAS Number Kum Sym Xwt unc Xut unc Xwt unc Xwt unc
7439-92-1
82
201
202
203
204
Pb
OC
EC
S04
N03
0.080
HA
NA
HA
NA
0.060
0.000
0.000
0.000
0.000
0.010
NA
NA
NA
NA
0.
0.
0.
0.
0.
000
000
000
000
000
0.028
NE
NE
NE
NE
0.000
0.000
0.000
0.000
0.000
0.028
NE
NE
NE
NE
0.000
0.000
0.000
0.000
0.000
TOTALS: 82.960 53.300 60.716 60.716
4UU
-------
PM Profile Speciation Report
Profile Name Soil Dust - Idaho
Profile Nunber 41307
Data Quality B/D
Control Device Not applicable
Referenee(s) 42
Oats Source Resuspended and analyzed
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31 -5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Sym
Be
B
F
Na
Mg
Al
Si
P
S
Cl
K
Ca
Sc
15
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Ce
Hg
0-2
%Mt
NA
NA
NA
1.000
2.000
18.000
48.000
<
0.240
0.200
2.000
1.800
<
0.760
0.030
0.020
0.280
8.500
<
<
0.050
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
.5 urn
unc
0.000
0.000
0.000
0.200
0.700
1.000
2.000
0.000
0.150
0.080
0.100
0.100
0.000
0.060
0.020
0.020
0.030
0.500
0.000
0.000
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
by XRF,
: (0-2.5)
: 0.020
2.5-10
Xwt
NA
NA
MA
1.100
1.900
9.100
29.000
<
0.200
0.120
1.800
1.730
<
0.790
,0.030
0.030
0.170
6.900
<
<
<
0.020
<
<
<
<
<
<
<
<
<
<
«
<
<
<
<
<
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
urn
unc
.000
.000
,000
.100
.300
.500
.000
.000
.020
.000
.100
.090
.000
.040
.000
.000
.000
.300
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
(0-6)
0.040
0-10 urn
Xwt
NE
NE
NE
1.075
1.925
11.625
33,750
' NE
0,210
0.140
1.850
1.747
NE
0.782
0.030
0.028
0.198
7,300
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.077
0.214
0.772
2.060
0.000
0.039
0.000
0.101
0.094
0.000
0.043
0.000
0.000
0.000
0.414
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{0-10)
0.080
Total
Measured
Xwt
NE
NE
NE
1.075
1.925
11.625
33.750
NE
0.210
0.140
1.850
1.747
NE
0.782
0.030
0.028
0.198
7.300
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
401
-------
PH Profile Special f on Report - continued {profile 41307)
Total Particulat* Matter -
Total
CAS Number
7439-92-1
Nun Sym
82
201
202
203
204
Pb
DC
EC
S04
N03
0-2
Xwt
0.080
NR
NR
NR
NR
.5 un
unc
0.060
0.000
0.000
0.000
0.000
2.5-
Xwt
0.010
NA
NA
NA
NA
10 urn
unc
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.028
NE
NE
Ni
NE
0
0
0
0
0
un
unc
.000
.000
.000
.000
.000
Measured
Xwt
0.028
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
TOTALS: 82.960 53.300 60.688 60.688
402
-------
PM Profile Special ion Report
Profile Name Soil Oust - Creston, Iowa
Profile Nunber 41308
Data Quality B/D
Control Device Not applicable
Reference(s) 26
Data Source Resuspended -soils analyzed by XRF and carbon oxidation.
Mass Fraction Data - Size Interval Cum) : (0-2.5) (0-6)
Mass fraction : 0.020 0.040
Total ^articulate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
ap*»fc» i e»
Him Syra
4
5
9
11
12
13
14
15
16
17
19
20
21
:2
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Be
b
F.
. Na
Mg
Al
Si
P
S
Cl
tc
Ca
Sc
7i
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ca
Ge
As
Se
Br
Rb
Sr
Zr
AS
Cd
Sn
Sb
Cs
Ba
Ce
Hg
0-2
Xwt
3.
13.
0.
0.
0.
0.
NA
NA
NA
NA
NA
109
039
105
824
262
786
15.195
0.
0.
0.
0.
3.
0.
0,
0.
0.
0.
0.
0.
0.
<
199
014
020
072
390
<
006
018
047
<
<
018
<
003
<
047
<
<
<
<
<
<
039
<
002
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
2.5-10 urn
Xwt
NA
NA
NA
NA
NA
3.109
13.039
0.105
0.824
0.262
0.786
15.195
<
0.199
0.014
0.020
0.072
3.390
<
0.006
0.018
0.047
<
<
0,018
<
0.003
<
0.047
<
<
<
<
<
<
0.039
<
0.002
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 um
Xut
NA
NA
NA
NA
NA
3.109
13.039
0.105
0.824
0.262
0.786
15.195
<
0.199
0.014
0.020
0.072
3.390
<
0.006
0.018
0.047
<
<
0.018
<
0.003
<
0.047
<
<
<
<
«
<
0.039
<
0.002
unc
0.000
0.000
0.000
0.000
0.000
0.155
0.652
0.005
0.041
0.013
0.039
0.760
0.000
0.010
0.001
0.001
0.004
0.169
0.000
0.000
0.001
0.002
0.000
0.000
0.001
0.000
0.000
0.000
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.000
0.000
(0-10)
0.080
Total
Measured
Swt
NA
NA
NA
NA
NA
3.109
13.039
0.105
0.824
0.262
0.786
15.195
<
0.199
0.014
0.020
0.072
3.390
<
0.006
0.018
0.047
<
<
0.018
<
0.003
<
0.047
<
<
<
<
<
<
0.039
<
0.002
unc
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
403
-------
PH Profile Specialion Report - continued (profile 41108)
Total Particulate Hatter
Species
CAS Number
7439-92-1
Nun
82
200
203
204
206
Sym
Pb
TC
S04
N03
C03
0-2
Xwt
0.037
1.791
MA
NA,
28.368
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
0.037
1.791
NA
NA
28.368
unc
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.037
1.791
NA
NA
28.363
0
0
0
0
1
un
unc
.002
.090
.000
.000
.418
Total
Measured
Xwt
0.037
1.791
NA
NA
28.368
unc
0.000
0.000
0.000
0.000
0.000
TOTALS:
67.391
67.391
67.391
67.391
s^
.404
-------
PM Profile Specistion Report
Profile Name Soil Dust - Council Bluffs, Iowa
Profile Number 41309
Data Quality B/D
Control Device Not applicable
Referenee(s) 26
Data Source Resuspended and analyzed by XRF and carbon oxidation.
Mass Fraction Data • Size Interval Cun) ; (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Particulate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41 -4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
T440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
o^xsb i «;»
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
I/
t,"t
25
26
27
28
29
30
35
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Be
B
f
Na
Kg
Al
Si
P
S
Ct
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
UQ
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
cs
Ba
Ce
HB
0-2.5 urn
Xut
5.
NA
NA
NA
NA
NA
160
21.693
0.
120
0.629
0.
1.
7.
0.
0.
/\
W >
0.
2.
0.
0.
0.
0.
. 0.
0.
0.
0.
198
138
225
<
287
019
016
068
301
<
006
008
064
<
<
005
<
015
<
026
<
<
<
<
209
<
049
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 m
%ut
NA
NA
NA
NA
KA
5.160
21 .693
0.120
0.629
0.198
1.138
7.225
<
0.287
0.019
0.016
0.068
2,301
<
0.006
0.008
0.064
<
<
0.005
<
0.015
<
0.026
<
<
<
<
0.209
<
0.049
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
%wt
NA
NA
NA
NA
NA
5.160
21 .693
0.120
0.629
0.198
1.138
7.225
<
0.287
0.019
0.016
0.068
2.301
<
0.006
0.008
0.064
<
<
0.005
<
0.015
<
0.026
<
<
<
<
0.209
<
0.049
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.258
1.085
0.006
0.031
0.010
0.057
0.361
0.000
0.014
0.001
0.001
0.003
0.115
0,000
0.000
0.000
0.003
0.000
0.000
0.000
0.000
0.001
0.000
0.001
0.000
D.OOO
0.000
0.000
0.010
0.000
0.002
0.000
0.000
(0-10)
0.080
Total
Measured
%wt
NA
NA
NA
NA
NA
5.160
21 .693
0.120
0.629
0.198
1.138
7.225
<
0.287
0.019
0.016
0.068
2.301
<
0.006
0.008
0.064
<
<
0.005
<
0.015
<
0.026
<
<
<
<
0.209
<
0.049
<
<
une
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.00.0
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
405
-------
PH ProfiIt Speciation Report • continued (profile 41309}
Total Particulote
Hatter
CAS Number
7439-92-1
Hum Syra
82
200
203
204
206
Pb
TC
•S04
N03
C03
Total
0-2
Xwt
0.069
2.295
NA
MA
12.495
.5 un
unc
0.000
0.000
0.000
0.000
0.000
Z.5-10 un
Xwt
0.069
2.295
NA
NA
12.495
unc
0.000
0.000
0.000
0.000
0.000
0-10
%ut
0.069
'2.295
NA
NA
12.495
0
0
0
0
0
urn
unc
.003
.115
.000
.000
.625
Measured
Xwt
0.069
2.295
NA
NA
12.495
unc
0.000
0.000
0.000
0.000
0.000
TOTALS: 54.095 54.095 54.095 54.095
406
-------
PM Profile Spec5ation Report
Profile Name : Soil Dust - Sioux City, Iowa
Profile Number : 41310
Data Quality : B/0
Control Device : Not applicable
Reference(s) : 26
Data Source : Resuspended and aril/zed by XRF and carbon oxidation.
Mass Fraction Data - Size Interval (urn) : (0-2,5) (0-6)
Mass Fraction : 0.020 0.040
Total Paniculate Matter -
CAS Nunfcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
^•SCh. 1 CO
Hum Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
SO
Be
6
f
Na
Mg
Al
Si
P
S
Cl
K
Ca
SC
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Ce
Hg
0-2
Xwt
4
20
0
0
0
1
3
0
0
0
0
3
0
0
0
0
0
0
0
0
NA
NA
NA
NA
NA
.926
.697
.094
.220
.100
.055
.998
<
.319
.021
.017
.153
.011
<
.007
.005
.035
<
<
.005
<
.002
<
.018
<
<
<
<
.001
<
.114
<
<
.5 un
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
Xwt
NA
NA
NA
NA
NA
4.926
20.697
0.094
0.220
0.100
1.055
3.998
<
0.319
0.021
0.017
0.153
3.011
<
0.007
0.005
0.035
<
<
0.005
<
0.002
<
0.018
<
<
<
<
0.001
<
0.114
<
<
unc
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NA
NA
NA
NA
NA
4.926
20.697
0.094
0.220
0.100
1.055
3.998
<
0.319
0.021
0.017
0.153
3.011
<
0.007
0.005
0.035
<
<
0.005
<
0.002
<
0.018
<
<
<
<
0.001
<
0.114
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.246
1.035
0.005
0.011
0.005
0.053
0.200
0.000
0.016
0.001
0.001
0.008
0.151
0.000
0.000
0.000
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.006
0.000
0.000
CO-10)
0.080
Total
Measured
Xwt
NA
NA
NA
NA
NA
4.926
20.697
0.094
0.220
0.100
1.055
3.998
<
0.319
0.021
0.017
0.153
3.011
<
0.007
0.005
0.035
<
<
0.005
<
0.002
<
0.018
<
<
<
<
0.001
<
0.114
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
407
-------
PH Profile Speeiation Report - continued fproffle 41310)
Total Particulate Hatter -
Total
0-2.5 urn 2.5-10 un 0-10 un Measured
Species
CAS Nunber Nun ' Sym Xwt unc %ut unc %ut unc %wt unc
7439-92-1 82
200
203
204
206
Pb
TC
S04
NOB
COS
0.042 0.000 0.042 0.000 0.042 0.002 0.042 0.000
2.313 0.000 2.313 0.000 2.313 0.116 2.313 0.000
NA 0.000 NA 0.000 NA 0.000 NA 0.000
NA 0.000 NA 0.000 NA 0.000 NA 0.000
17.971 0.000 17.971 0.000 17.971 0.899 17.971 0.000
TOTALS: 55.124 55.124 55.124 55.124
408
-------
PM Profile Speciation Report
Profile Name Soil Dust - Cedar
Profile Nurtser 41311
Data Quality C/E
Rapids
Control Device Not applicable
Reference(s) 26
Data Source Resuspended and analyzed
Mass Fraction Data - Size Interval (urn)
Mass fraction
Total Partlculate Hatter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
Num
4
5
9
11
12
13
14
15
16
17
19
20
21
22
M
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
4S
50
51
55
56
58
80
Sym
Be
B
f
Ha
Hg
Al
Si
P
S
ct
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
AS
Cd
Sn
Sb
Cs
Ba
Ce
HS
0-2
%wt
1
7
0
0
0
0
25
0
0
0
0
0
0
0
0
0
0
0
NA
NA
NA
NA
NA
.906
.171
.040
.895
.360
.821
.808
<
.088
.005
.005
.138
.865
<
.005
.003
.029
<
<
.001
<
.002
<
.026
<
<
<
<
<
<
<
<
*
.5 un
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
, I one
by XRF and carbon oxidation.
: (0-2.5) (0-6)
: 0.020 0.040
2.5-10 urn
%wt
NA
NA
NA
NA
NA
1.906
7.171
0.040
0.895
0.360
0.821
25.808
<
0.088
0.005
0.005
0.138
0.865
<
0.005
0.003
0.029
<
<
0.001
<
0.002
<
0.026
<
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.coo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 un
%wt
NA
NA
NA
NA
NA
1.906
7.171
0.040
0.895
0.360
0.821
25.808
<
0.088
0.005
0.005
0.138
0.865
<
0.005
0.003
0.029
<
<
0.001
<
0.002
<
0.026
<
<
<
<
<
<
<
<
*
unc
0.000
0.000
0.000
0.000
0.000
0.095
0.359
0.002
0.045
0.018
0.041
1.290
0.000
0.004
0.000
0.000
0.007
0.043
o.poo
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
Swt
NA
NA
NA
NA
NA
1.906
7.171
0.040
0.895
0.360
0.821
25.808
<
0.088
0.005
0.005
0.138
0.865
<
0.005
0.003
0.029
<
<
0.001
<
0.002
<
0.026
<
<
<
<
<
<
<
<
*
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.QOO
0.000
409
-------
PH Profile Speeiatfon Report - continued (profile 41311)
Total Paniculate
Matter
CAS Number
7439-92-1
Hum Sym
82
200
203
204
206
Pb
TC
504
N03
C03
Total
0-2
Xwt
0.029
3.222
NA
NA
36.189
.5
0
0
0
0
0
un
unc
,000
.000
.000
,000
.000
2.5-10 un
Xwt
0.029
3.222
NA
NA
36.189
unc
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xut
0.029
3.222
NA
NA
36.189
unc
0,001
0.161
0.000
0.000
1.S09
Measured
Xwt
0.029
3.222
NA
NA
36.189
unc
0.000
0.000
0.000
0.000
0.000
TOTALS: 77.608 77.608 77.608 77.608
410
-------
PH Profile Speciation Report
Profile Name Soil Dust - Davenport, Iowa
Profile Number 41312
Data Quality C/E
Control Device Npt applicable
Reference(s) 26
Data Source Resuspended and analyzed py XRF and carbon oxidation.
•i
Mass Fraction Data - Size Interval (urn) :- (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Particulate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
2",
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Sym
Be
B
f
Na
Kg
Al
Si
p
s
Cl
K
Ca
Sc
Ti
V
ur
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Ce
Hg
2
7
0
0
0
0
20
0
0
u
0
1
0
0
0
0
0
0
0-2
Xwt
NA
NA
NA
NA
NA
.333
.958
.057
.663
.314
.602
.428
<-
.163
.009
.011
.070
.502
<
.007
.014
.060
<
<
.008
<
.003
<
.052
<
<
<
<
<
<
<
<
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
NA
NA
NA
NA
NA
2.333
7.958
0.057
0.663
0.314
0.602
20.428
<
0.163
0.009
0.011
0.070
1.502
<
0.007
0.014
0.060
<
<
0.008
<
0.003
<
0.052
<
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NA
NA
NA
NA
NA
2.333
7.958
0.057
0.663
0.314
0.602
20.428
<
0.163
0.009
0.011
0.070
1.502
<
0.007
0.014
0.060
<
<
0.008
<
0.003
<
0.052
<
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.117
0.398
0.003
0.033
0.016
0.030
1.021
0.000
0.008
0.000
0.001
0.004
0.075
0.000
0.000
0.001
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
Xwt
NA
NA
NA
NA
NA
2.333
7.958
0.057
0.663
0.314
0.602
20.428
<
0.163
0.009
0.011
0.070
1.502
<
0.007
0.014
0.060
<
<
0.008
<
0.003
<
0.052
<
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
411
-------
PH Profile Speciation Report - continued (profile 41312)
Total Particulate Hatter -
CAS Nurfcer
7439-92-1
TOTALS:
Nun Sym
82
200
203
204
206
Pb
TC
S04
N03
C03
0-2
Xwt
0
3
37
75
.123
.942
NA
NA
.206
.525
.5 un
une
0,000
0.000
0.000
0.000
0.000
2.5-10 urn
tut
0.121
3.942
NA
NA
37.206
75.525
unc
0.000
0.000
0.000
0.000
0.000
0-10 un
%vt
0.123
3.942
HA
HA
37.206
75.525
unc
0.006
0.197
0.000
0.000
1.860
Total
Measured
Xut
0.123
3.942
NA
NA
37.206
75.525
unc
0.000
0.000
0.000
0.000
0.000
412
-------
PM Profile Speciation Report
Profile Name Soil Oust - Spokane, WA
Profile Number 41313
Data Quality B/D
Control Device Vot applicable
Reference(s) 27
Data Source Resuspended and XRF analysis of fine fraction.
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction ; 0.020 0.040
Total Particulate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
OpCW 1 CO
Hunt Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Be
E
F
Na
Mg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Nt
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
8a
Ce
Hs
0-2
Swt
1
11
27
0
0
0
1
0
0
0
0
5
0
0
0
0
0
NA
NA
NA
NA
.866
.010
.975
.299
.036
.112
.545
.795
<
.442
.025
<
.240
.280
<
.010
.180
.027
<
<
<
<
<
<
.013
<
<
.053
<
<
<
<
<
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.154
0.778
1.935
0.031
0.096
0.045
0.127
0.070
0.000
0.040
0.009
0.000
0.022
0.375
0.000
0.008
0.007
0.007
0.000-
0.000
0.000
0.000
0.000
0.000
0.009
0.000
0.000
0.064
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
X«t
NA
NA
NA
NA
1.866
11.010
27.975
0.299
0.036
0.112
1.545
0.795
<
0.442
0.025
<
0.240
5.280
<
0.010
0.180
0.027
<
<
<
<
<
<
0.013
<
<
0.053
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.154
0.778
1.935
0.031
0.096
0.045
0.127
0.070
0.000
0.040
0.009
0.000
0.022
0.375
0.000
0.008
0.007
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.009
0.000
0.000
0.064
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
%Mt
NE
NE
NE
NE
1.866
11.010
27.975
0.299
0.036
0.112
1.545
0.795
NE
0.442
0.025
NE
0.240
5.280
NE
0.010
0.180
0.027
m
NE
NE
NE
NE
NE
0.013
NE
NE
0.053
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.108
0.615
1.557
0.019
0.034
0.017
0.089
0.047
0.000
0.026
0.003
0.000
0.014
0.295
0.000
0.003
0.009
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.023
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
%wt
NE
NE
NE
NE
1.866
11.010
27.975
0.299
0.036
0.112
1.545
0.795
NE
0.442
0.025
m
0.240
5.280
m
0.010
0.180
0.027
NE
NE
NE
NE
NE
NE
0.013
NE
NE
0.053
NE
NE
NE
NE
NE
NE
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-------
PH ProfiIt Specfation Report - continued Cprofile 41313)
Total Porticulate Natter
Species
CAS Number
7439-92-1
Nun
' 82
201
202
203
204
Sym
Pb
oc
EC
$04
N03
. 0-2
Xwt
0.106
HA
HA
NA
HA
.5 un
une
0.025
0.000
0.000
0.000
0.000
2.5-10 UR
Xwt
0.106
HA
NA
NA
HA
unc
0.025
0.000
0.000
0.000
0.000
0-10
Xwt
0.106
HE
HE
HE
HE
0
0
0
0
0
urn
unc
.010
.000
.000
.000
.000
Total
Measured
%wt
0.106
HE
HI
NE
HE
unc
0.000
0.000
0.000
0.000
0.000
TOTALS: 50.014 50.014 50.014 50.014
e*Kis:sEK**=XKE:rsssssBS=x:ss=aes=a:s:B^
414
-------
PM Profile Speciat ion Report
Profile Name Soil Oust - Boise
Profile Nunber 413U
Data Quality 8/E
, Idaho
Control Device Not applicable
Referenced 5 27
Data Source Resuspended and XRF analysis of fine fraction.
Nass Fraction Data - Size Interval (un) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Participate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
d|^V. W 1 CO
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
&
24
25
26
27
. 28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Be
E
f
Na
Kg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Nt
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Ce
Hg
0-2
Xwt
0
8
30
0
0
0
1
1
0
0
0
3
0
0
0
0
NA
NA
NA
NA
.904
.160
.273
.243
.524
.083
.740
.268
<
.439
.033
<
,097
.406
<
<
.007
.081
<
<
<
<
<
<
.035
<
<
.068
<
<
<
<
<
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.068
0.460
1.660
0.021
0.080
0.030
0.122
0.081
0.000
0.032
0.007
0.000
0.009
0.199
0.000
0.000
0.004
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.007
0.000
0.000
0.040
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
NA
NA
NA
NA
0.904
8.160
30.273
0.243
0.524
0.083
1.740
1.268
<
0.439
0.033
<
0.097
3,406
<
<
0.007
0.081
<
<
<
<
<
<
0.035
<
<
0.068
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 un
Xwt
NA
NA
NA
NA
0.904
a. 160
30.273
0.243
0.524
0.083
1.740
1.268
<
0.439
0.033
<
0.097
3.406
<
<
0.007
0.081
<
<
<
<
<
<
0.035
<
<
0.068
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.048
0.424
1.570
0.013
0.033
0.009
0.092
0.067
0.000
0.023
0.002
0.000
0.005
0.177
0.000
0.000
0.001
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.000
0.000
0.011
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
%wt
NA
NA
NA
NA
0.904
8.160
30.273
0.243
0.524
0.083
1.740
1.268
<
0.439
0.033
<
0.097
3.406
<
<
0.007
0.081
<
<
<
<
<
<
0.035
<
<
0.068
<
<
<
<
<
<
unc
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.OQO
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
415
-------
PH Profile Speciation Report - continued Cproflie 41314)
Total Partfculate Hatter -
Total
CAS Number
7439-92-1
Hum Sym
82
201
202
203
204
Pb
OC
EC
S04
N03
0-2
Xut
0.205
HA
NA
- HA
NA
.5 urn
une
0.022
0.000
0.000
0.000
0.000
2.5-10 urn
Xut
0.205
NA
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xut
0.205
NA
NA
NA
NA
unc
0.012
0.000
0.000
0.000
0.000
Measured
Xwt
0.205
NA
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
TOTALS: 47.566 47,566 47.566 47.566
416
-------
PH Profile Speciation Report
Profile Name Soil Dust • Bakersf ield.
Profile Number 41315
Data Quality D/E
CA
Control Device Not applicable
Reference(s) 31
Data Source Average values from 7 locations.
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.020
Total Particulate Matter •
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
«t»w ' ~°
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
c4
25
26
27
28
29
30
il
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Be
B
f
Na
Mg
Al
Si
P
S
Cl
K
Ca
sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
ua
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
ps
Ba
Ce
Hg
0-2
Xwt
0
0
4
14
0
0
1
1
0
0
u
0
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
NR
NR
.800
.600
.700
.000
<
.500
.200
.500
.800
<
.200
.050
.050
.050
.200
<
.050
.050
.050
<
<
<
<
.050
.050
.050
.050
.050
.050
.050
.050
.050
.200
.200
.200
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.oob
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
NR
NR
NR
0.800
0.600
4.700
14.000
<
0.500
0.200
1.500
1.800
<
0.200
0.050
0.050
0.050
3.200
<
0.050
0.050
0.050
<
<
<
<
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.200
0.200
0.200
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.040
0-10 urn
Xwt
NR
NR
NR
0.800
0.600
4.700
14.000
<
0.500
0.200
1.500
1.800
<
0.200
0.050
0.050
0.050
3.200
<
0.050
0.050
0.050
<
<
<
<
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.200
0.200
0.200
unc
0.000
0.000
0.000
0.040
0.030
0.235
0.700
0.000
0.025
0.010
0.075
0.090
0.000
0.010
0.003
0.003
0.003
0.160
0.000
0.003
0.003
0.003
0.000
0.000
0.000
0.000
0.003
0.003
0.003
0.003
0.003
0.003
0.003
0.003
0.003
0.010
0.010
0.010
(0-10)
0.080
Total
Measured
Xwt
NR
NR
NR
0.800
0.600
4.700
14.000
<
0.500
0.200
1.500
1.800
• <
0.200
0.050
0.050
0.050
3.200
<
0.050
0.050
0.050
<
<
<
<
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.200
0.200
0.200
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
417
-------
PM Profile Speciation Report - continued (profile 41315)
Total Particulate Matter
Species
CAS Hunter
7439-92- 1
Hum
82
201
202
203
204
Sym
Pb
OC
EC
S04
N03
0-2
Xwt
0.200
NR
NR
NR
NR
.5
urn
unc
0
0
0
0
0
.000
.000
.000
.000
.000
2.5-10 urn
%ut
0.200
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0-10 un
%ut
0.200
NR
NR
NR
NR
unc
0.010
0.000
0.000
0.000
0.000
Total
Measured
Xut
0.200
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
TOTALS: 29.050 29.050 29.050 29.050
418
-------
PM Profile Speciat ion Report
Profile Name Soil Dust - Pasedena, CA
Profile Number 41316
Data Quality 0/E -
Control Device Not applicable
Reference(s) 30
Data Source Unspecified analysis of soils.
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.020
Total Particulate Hatter
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Sym
Be
B
F
Na
Mg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
CS
Be
Ce
Hg
0-2
%Ht
' NR
NR
NR
2.500
1.400
8,200
20.000
NR
NR
NR
1.500
1.500
NR
0.400
0.006
NR
0.110
3.200
0.002
0.004
0.008
.5
urn
unc
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
2.5-
Xwt
NR
NR
NR
2.500
1.400
8.200
20.000
NR
NR
NR
1.500
1.500
NR
0.400
0.006
NR
0.110
3.200
0.002
0.004
0.008
< O.QOO <
• NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
0.060
NR
NR
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
0.060
NR
NR
10 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.040
0-10 urn
%wt
NR
NR
NR
2.500
1.400
8.200
20.000
NR
m
NR
1.500
1.100
NR
0.400
0.006
NR
0.110
3.200
0.002
0.004
0.008
<
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
0.060
NR
NR
unc
0.000
0.000
0.000
0.125
0.070
0.410
1.000
0.000
0.000
0.000
0.075
0.075
0.000
0.020
0.000
0.000
0.005
0.160
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
0.000
0.000
(0-10)
0,080
Total
Measured
%wt
NR
NR
NR
2.500
1.400
8.200
20.000
NR
NR
NR
1.500
1.500
NR
0.400
0.006
NR
0.110
3.200
0.002
0.004
0.008
<
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
0.060
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
419
-------
PH Profile Speeiation Report - continued (profile 41316)
Total Paniculate
Hatter
CAS Number
7439-92-1
Hum Sym
82
201
202
203
204
Pb
OC
EC
S04
NOB
Total
0-2.5 urn
Xwt
0.020
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
2.5-10 ura
Xwt
0.020
NR
NR
NR
HR
unc
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
0.020
NR
NR
NR
HR
unc
0.001
0.000
0.000
0.000
0.000
Measured
Xwt
0.020
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
TOTALS: 38.910 38.910 38.910 38.910
SeSKSSSSSXSSSSiSiBSSSSSSSSSSS^
420
-------
PH Profile Speciation Report
Profile Name Soil Dust • Bedford, OR
Profile Number «131B
Data Quality i/C
Control Device Not applicable
Referenced) 4*5
Data Source Composite samples resuspended and samples using a 2-stage
virtual impact or.
Mass Fraction Data • Size Interval Cum) : (0-2. S) (0-6)
Mass Fraction : 0.020 0.040
Total Particulate Natter
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
0|J*:^ I e»
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
e.i
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
.Be
8
F
Ka
Kg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Hi
Cu
Zn
Ga
Ge .
As
Se
Br
Rb
Sr
Zr
* **
*"*»
Cd
Sn
Sb
Cs
ia
Ce
0-Z
Xut
NA
NA
NA
1.500
1.900
9.500
26.600
NA
C.Q9Q
0.070
0.920
1.800
NA
1.000
0.024
0.024
0.160
5.300
NA
0.007
0.030
0.009
NA
<
<
<
<
NA
<
NA
HA
<
NA
<
NA
<
<
.5 urn
unc
0.000
0.000
0.000
0.500
0.600
0.100
1.400
0.000
0.040
0.050
0.330
0.400
0.000
0.100
0.000
0.000
0.070
0.600
0.000
0.003
0.020
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Kwt
1
1
8
2
0
0
1
0
0
0
0
5
0
0
0
NA
NA
NA
.700
.500
.900
.700
NA
.070
NA
.750
.800
NA
.700
.033
.026
.180
.500
NA
.007
.030
.011
NA
<
<
<
<
NA
<
NA
NA
<
NA
<
NA
<
<
unc
0.000
0.000
0.000
0.400
0.300
0.200
1.400
0.000
0.050
0.000
0.160
0.200
0.000
0.200
0.000
0.000
0.050
0.800
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 un
Xwt
NE
NE
NE
1.650
1.600
9.050
8.675
NE
0.075
NE
0.792
1.800
NE
0.775
0.031
0.026
0.175
5.450
NE
0.007
0.030
0.011
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.179
0.188
0.464
1.067
0.000
0.017
0.000
0.101
0.144
0.000
0.071
0.000
0.000
0.023
0.368
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
Xwt
NE
NE
NE
1.650
1.600
9.050
8.675
NE
0.075
NE
0.792
1.800
m
0.775
0.031
0.026
0.175
5.450
NE
0.007
0.030
0.011
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
421
-------
PH Profile Specfatton Report - continued (profile 41318)
Total Paniculate Hatter, -
Total
0-2.5 un 2.5-10 urn 0-10 urn Measured
CAS Number Nun Sym Xwt unc %wt unc Xwt unc Xwt unc
7439-97-6
7439-92-1
80
82
201
202
203
204
Hg
Pb
DC
EC
S04
N03
0
4
0
0
0
<
.011
.400
.600
.100
.100
0.000
0.000
1.700
0.400
0.040
0.040
<
NA
3.700
0.700
0.060
NA
0.000
0.000
0.700
0.700
0.060
0.000
NE
NE
3.873
0.675
0.070
NE
0.000
0.000
0.503
0.204
0.018
0.000
NE
NE
3.875
0.675
0.070
NE
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 54.145 28.367 34.767 34.767
422
-------
PM Profile Speciatfon Report
Profile Name Soil Dust - Portland OR
Profile Number 41319
Data Quality A/C
Control Device Not applicable
Reference(s) 46,54
Data Source Composite of samples which were suspended and sampled with
• 2-stagevirtual impactor with e Method 5 heated probe.
No dilution air. Analysis by XRF, INN A, 1C, and carbon
oxidation.
Mass Fraction Data - Size Interval (on) ; (0-2.5) (0-6)
Mass fraction : 0.020 0.040
Total Participate Matter
Species
CAS Hunter
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
Num
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
7«
40
47
48
50
51
55
Sym
Be
B
F
Na
Mg
Al
SI
P
s
Cl
K
Ca
Sc
Ti
V
Cf
Kn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
C r
Zr
Ag
Cd
Sn
Sb
Cs
0-2
%wt
NA
NA
NA
0.690
1.760
11.700
25.400
<
0.070
<
1.000
0.930
<
0.760
0.025
0.030
0.200
6.800
<
<
0.020
0.041
<
<
<
<
<
<
<
<
<
<
<
<
<
.5 un
unc
0.000
0.000
0,010
0,380
0.620
2.200
3.400
0.000
0.030
0.010
0.280
0.370
0.000
0.240
0.006
0.008
0.090
2.300
0.000
0.004
0.004
0.026
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
Xwt
0
1
1
7
29
2
1
0
0
0
0
4
0
0
0
NA
NA
.002
.300
.200
.200
.700
<
<
<
.200
.400
<
.820
.017
.010
.085
.760
<
.009
.020
.041
<
<
<
<
<
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.500
0.310
1.700
1.500
0.000
0.000
0.010
0.240
0.670
0.000
0.150
0.006
0.006
0.028
0.850
0.000
0.004
0.004
0.026
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 un
Xwt
HE
NE
NE
1.147
1.340
8.325
28.625
NE
m
NE
1.900
1.282
m
0.805
0.019
0.015
0.114
5.270
NE
NE
0.020
0.041
NE
NE
NE
NE
Ni
NE
NE
NE
Ni
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.165
0.189
0.848
1.665
0.000
0.000
0.000
0.126
0.200
0.000
0.081
0.002
0.003
0.025
0.680
0.000
0.000
0.002
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
%wt
NE
NE
NE
1.147
1.340
8.325
28.625
NE
NE
NI
1.900
1.282
NE
0.805
0.019
0.015
0.114
5.270
NE
NE
0.020
0.041
NE
NE
NE
NE
. NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
423
-------
PM Profile Specialion Report - continued (profile 41319)
Total Participate Hatter -
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
Nun Sym
56
58
80
82
201
202
203
204
Ba
Ce
HO
Pb
OC
EC
S04
N03
0-2
Xut
<
<
<
0.006
4.320
0.590
NA
NA
54.342
.5 un
unc
0.000
0.000
0.000
0.002
1.700
0380
0.050
1.000
2.5-10 un
0
4
0
0
0
53
fct
<
<
<
.042
.320
.590
.004
.009
.729
unc
0.000
0.000
0.000
0.011
1.730
0.380
0.001
0.005
0-10 un
Xwt
NE
UE
UE
0.033
4.320
0.590
NE
NE
53.846
unc
0.000
0.000
0.000
0.003
0.644
0.138
0.000
0.000
Total
Measured
Xwt
NE
NE
NE
0.033
4.320
0.590
NE
NE
53.846
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
424
-------
PM Profile Spec)at ion Report
Profile Name Soil Oust - Alabama
Profile Number 41320
Data Quality C/E
Control Device Not applicable
Reference(s) 48
Data Source Resuspended and sampled
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter
CAS Nunfcer
7440-41 -?
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
ajjtrw i B»
Num Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
43
50
51
55
56
58
80
Be
B
F
Na
Mg
Al
Si
P
s
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
CU
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Ce
Hg
0-2
Xwt
NA
NA
NA
1.500
1.900
9.500
26.600
NA
0.090
0.070
0.920
1.800
NA
1.000
0.024
0.024
0.160
5.300
NA
0.007
0.030
0.009
NA
<
<
<
<
NA
<
NA
NA
<
NA
<
NA
<
<
<
,5 urn
unc
0.000
0.000
0.000
0.500
0.600
0.100
1.400
0.000
0.040
0.050
0.330
0.400
0.000
0.100
0.000
0.000
0.070
0.600
0.000
0.003
0.030
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
with a diehotomous sampler.
: (0-2.5) (0-6)
: 0.020 0.040
2.5-10 urn
Xwt
NA
NA
NA
1.700
1.500
8.900
27.000
NA
0.070
NA
0.750
1.800
NA
0.700
0.033
0.026
0.180
5.500
NA
0.007
0.030
0.011
NA
<
<
<
<
NA
<
NA
NA
<
NA
<
NA
<
<
<
unc
0.000
0.000
0.000
0.400
0.300
0.200
1.400
0.000
0.050
0.000
0.160
0.200
0.000
0.200
0.000
0.000
0.050
0.800
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NE
NE
NE
1.650
1.600
9.050
26.900
NE
0.075
NE
0.792
1.800
NE
0.775
0.031
0.026
0.175
5.450
NE
0.007
0.030
0.011
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
Ni
NE
NE
Ni
NE
unc
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.179
.188
.464
.429
.000
.017
.000
.101
.144
.000
.071
.000
.000
.023
.368
.000
.001
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
(0-10)
o.oso
Total
Measured
%wt
NE
NE
NE
1.650
1.600
9.050
26.900
NE
0.075
NE
0.792
1.800
NE
0.775
0.031
0.026
.0.175
• 5.450
NE
0.007
0.030
0.011
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
Ni
NE
NE
NE
N£
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
425
-------
PH Profile Speciation Report - continued (profile 41320)
•»«.*«*•.*••*•*»-•»»•*-»»*•**»*•.,-- »»-».»««•».»••»-»***---««*--»**--•*•».
Total Participate Hatter -
0-2.5 urn 2.5*10 un 0-10 urn
Xwt tine Xut unc %wt
Total
Measured
Species
CAS Kumber Nun Sym
unc
Xwt
unc
7439-92-1
TOTALS:
82
201
202
203
204
Pb
DC
EC
S04
N03
0
4
0
0
0
54
.011
.400
.600
.100
.100
.145
0.000
1.700
0.400
0.040
0.040
NA
3.700
0.700
0.060
NA
52.667
0.000
0.700
0.700
0.060
0.000
NE
3.875
0.675
0.070
NE
52.992
0.000
O.S03
0.204
0.018
0.000
NE
3.875
0.675
0.070
NE
52.992
0.000
0.000
0.000
0.000
0.000
426
-------
PM Profile SpecialIon Report
Profile Nome Soil Oust -•
Profile Hunter 41321
Data Quality C
Laurel HD
Control Device Not Applicable
ReferenceCs) 64,85
Data Source Sieved and resuspended;
SCC Assignments 058
Mass Fraction Dst2 - S:;s Interval (un)
Mass Fraction
Total Paniculate Matter -
CAS Number
7440-42-8
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7782-50-5
7440-09-7
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-66-6
7440-55-3
7440-38-2
7726-95-6
7440-17-7
7440-67-7
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-00-8
7440-19-9
7440-54-2
7440-58-6
7440-29-1
TOTALS;
Nun Sym
5
11
12
13
14
17
19
21
22
23
24
25
26
27
30
31
33
35
37
40
51
55
56
57
58
60
62
64
72
90
B
Na
Mg
Al
Si
Cl
tc
Sc
Ti
V
Cr
Mn
Fe
Co
Zn
Sa
As
Br
Rb
7r
Sb
Cs
Ba
La
Ce
Nd
Sfli
Gd
Hf
tn
0
0
0
n
0
0
2
0
0
0
0
0
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0-2
%wt
.000
.316
.000
.862
.000
.608
.472
.002
.666
,022
.000
.103
.991
.003
.009
.003
.003
.000
.000
,000
.000
.001
.000
.007
.009
.000
.001
,001
.001
.002
.5 un
unc
0.000
0.029
0.000
0.142
0.000
0.045
0.106
0.000
0.183
0.002
0,000
0,005
0.359
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
22.082
analyzed by PGAA and INAA.
5 (0-2.5) (0-6)
: 0.020 0.040
2.5-10 urn
%Mt
0.000
0.275
0.000
11.614
0.000
0.541
2.851
0.002
1.115
0.023
0.000
0,101
5.624
0.002
0,013
0.003
0.002
0.000
0.000
0.000
0.000
0.001
0.000
0.006
0.009
0.000
0.001
0.001
0.001
0.002
22.187
unc
0,000
0.026
0.000
0.163
0.000
0.018
0.145
0.000
0.145
0.002
0.000
0.005
0.281
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.000
0.285
0.000
11.676
0.000
0.558
2.756
0.002
1.003
0.023
0.000
0.101
5.716
0.002
0.012
0.003
0.002
0.000
0.000
0.000
0.000
0.001
0.000
0.006
0.009
0.000
0.001
0.001
0.001
0.002
ura€1>
unc
0.000
0.020
0.000
0.518
0,000
0.030
0.137
0.000
0.093
0.002
0.000
0.006
0.304
0,000
0.002
0.000
0.000
0,000
0.000
0.000
0,000
0.000
0.000
0.001
0.001
0.000
0.000
0.000
0.000
0.000
22.160
(0-10)
0.080
Total
Measured
%Ht
0.007
0.190
3.500
7.892
34.201
0.019
1.799
0.001
0.886
0.009
0.006
0.067
3.798
0.002
0.011
0.002
0.001
0.000
0.012
0.068
0.000
0.000
0.034
0.005
0.007
0.002
0,001
0.001
0.002
0.001
52.524
unc
0.000
0.010
0.350
0.087
1.700
0.001
0.284
0.000
0.115
0.001
0,002
0.002
0.190
0,000
0.001
0.000
0,000
0.000
0.001
0.008
0.000
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
.0.000
C1} Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
427
-------
PH Profile Speciation Report
Profile Name : Soil Dust - Hash ing ton, D
Prof i le Number : 41322
Data Quality : E
.C. area
Control Device : Not Applicable
ReferenceCs) : 64,86
Data Source : Fifty-gram surface sample and one-kg subsurface sample
collected at each of four sites. Analyzed by 1NAA and
SCC Assignments: 058
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Participate Hatter -
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7440-70-2
7440-22-2
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-53-1
7440-64-4
7439-94-3
7440-58-6
7440-25-7
7440-29-1
«p*5S* I C«»
Nun Sym
11
12
13
14
20
21
23
24
25
26
27
30
33
34
35
51
55
56
57
58
62
63
70
71
72
73
90
Ha
Hg
At
Si
Ca
Sc
V
Cr
Hn
Fe
Co
En
AS
Se
Br
Sb
Cs
Ba
La
Ce
Sm
Eu
Yb
Lu
Hf
Ta
Th
0-2.5
%wt
0
0
5
35
0
0
0
0
0
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
q
0
0
.320
.560
.990
.001
.490
.001
.014
.006
.099
.780
.002
.008
.000
.000
.001
.000
.000
.052
.006
.007
.001
.000
.000
.000
.001
.000
.001
unC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Kwt
0.320
0.560
5.990
35.001
0.490
0.001
0.014
0.006
0.099
3.780
0.002
0.008
0.000
0.000
0.001
0.000
0.000
0.052
0.006
0.007
0.001
0.000
0.000
0.000
0.001
0.000
0.001
unC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.320
0.560
5.990
35.001
0.490
0.001
0.014
0.006
0.099
3.780
0.002
0.008
0.000
0.000
0.001
0.000
0.000
0.052
0.006
0.007
0.001
0.000
0.000
0.000
0.001
0.000
0.001
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1PAA.
0.080
Total
Measured
Kwt
0.320
0.560
5.990
35.001
0.490
0.001
0.014
0.006
0.099
3.780
0.002
0.008
0.000
0.000
0.001
0.000
0.000
0.052
0.006
0.007
0.001
0.000
0.000
0.000
0.001
0.000
0.001
unc
0.026
0.120
1.080
7.000
0.150
0.000
0.003
0.001
0.009
0.600
0.000
0.002
0.000
0.000
0.000
0.000
0.000
0.013
0.001
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 46.340 46.340
C1> Estimated / extrapolated.
46.340 46.340
428
-------
PM Profile Speeiation Report
Profile Name
Profile Hunter
Data Quality
Soil Dust -Riverside, CA
41323
C
Control Device Not Applicable
ReferenceCs) 62
Data Source Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 058
Hass Fraction
Data - Size Interval (urn)
Mass Fraction
Total Particulate Hatter -
Spe
CAS Number Hunt
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
;v I CO
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mrv
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
Ir.
Sn
Sb
Ba
La
HS
Pb
0-2
XMt
9
20
0
0
0
1
2
0
0
0
0
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
n
0
0
0
0
0
0
42
.890
.360
.212
.406
.157
.981
.831
.529
.038
.024
.159
.671
.009
.011
.028
.003
.008
.000
.002
.007
.012
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.001
.013
.352
.5 urn
unc
1.484
3.054
0.043
0.020
0.008
0.099
0.142
0.027
0.006
0.002
0.008
0.286
0.001
0.002
0.002
0.001
0.003
0.001
0.001
0.002
0.002
0.002
0.011
0.007
0.007
0.009
0.012
0.014
0.017
0.038
0.071
0.128
0.001
0.004
: (0-2.5)
: 0.020
2.5-10 urn
%wt
9.231
19.190
0.175
0.332
0.179
2.227
2.900
0.556
0.025
0.029
0.150
5.955
0.007
0.007
0.026
0.000
0.000
0.000
0.003
0.016
0.028
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
0.000
0.000
0.030
41.122
unc
1.385
2.878
0.035
0.017
0.009
0.111
0.145
0.029
0.006
0.002
0.008
0.299
0.001
0.001
0.001
0.003
0.002
0.000
0.000
0.001
0.002
0.001
0.003
0.001
0.001
0.002
0.002
0.003
0.003
0.007
0.013
0.022
0.000
0.002
<0-6)
0.040
0-10 urn
Xwt
9.267
19.253
0.177
0.336
0.177
2.213
2.897
0.554
0.026
0.029
0.150
5.940
0.007
0.007
0.027
0.000
0.000
0.000
0.003
0.016
0.027
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
0.000
0.000
0.029
41.189
unc
0.890
1.845
0.022
0.020
0.009
0.109
0.148
0.029
0.004
0.002
0.008
0.300
0.001
0.001
0.002
0.001
0.001
0.000
0.001
0.001
0.002
0.001
0.003
0.002
0.002
0.002
0.003
0.004
0.005
0.010
0.019
0.034
0.000
0.002
<0-10)
0.080
Total
Measuredm
%ut
9.267
19.253
0.177
0.336
0.177
2.213
2.897
0.554
0.026
0.029
0.150
5.940
0.007
0.007
0.027
0.000
0.000
0.000
0.003
0.016
0.027
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
0.000
0.000
0.029
41.189
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{1> Estimated / extrapolated. 429
-------
PH Profile Speciation Report
Profile Name
Profile Number
Data Quality
Soil Dust - Hawthorne, CA
41324
C
Control Device
Reference{s>
Data Source
Not Applicable
62
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual inpactor. Analyzed using XRF and
flame ionizetion.
SCC Assignments: 058
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter
Species
CAS Number Nun Sym
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
3S
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti ,
V
Cr
Kn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
As
Cd
In
Sn
Sb
Ba
La
Hg
Pb
-
0-2
%wt
11
23
0
, 0
0
1
1
0
0
0
0
S
0
0
0
0
0
0
0
0
0
0
0
0
0
, 0
0
0
0
.277
.575
.033
.300
.061
.470
.278
.541
.025
.019
.107
.178
.007
.013
.051
.001
.015
.000
.000
.001
.019
.000
.000
.000
.000
.000
.000
.000
.000
0.020
0
.000
0.000
0
0
.000
.006
.5 urn
unc
1.299
2.717
0.005
0.050
0.026
0.084
0.092
0.038
0.006
0.004
0.007
0.298
0.003
0.005
0.028
0.001
0.007
0.001
0.001
0.002
0.003
0.003
0.012
0.007
0.008
0.009
0.012
0.016
0.018
0.039
0.075
0.136
0.001
0.006
: (0-2.5)
: 0.020
2.5-10 urn
Xwt
10.021
21.218
0.012
0.095
0.020
1.683
1.319
0.581
0.023
0.021
0.129
5.593
0.008
0.005
0.016
0.000
0.000
0.000
0.002
0.013
0.034
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
0.023
0.013
0.000
0.024
unc
1.064
2.251
0.012
0.013
0.001
0.060
0.047
0.031
0.005
0.002
0.005
0.200
0.001
0.001
0.002
0.002
0.001
0.000
0.002
0.001
0.003
0.001
0.003
0.002
0.002
0.002
0.003
0.004
0.005
0.010
0.023
0.034
0.000
0.002
(0-6)
0.040
0-10 UR
Xwt
9.890
20.802
0.011
0.101
0.022
1.622
1.275
0.558
0.023
0.021
0.124
5.417
0.008
0.006
0.018
0.000
0.001
0.000
0.001
0.012
0.032
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
0.026
0.014
0.000
0.023
unc
0.781
1.645
0.006
0.018
0.007
0.077
0.065
0.030
0.003
0.002
0.006
0.262
0.001
0.002
0.007
0.001
0.002
0.000
0.001
0.001
0.002
0.001
0.003
0.002
0.002
0.003
0.003
0.004
0.005
0.011
0.022
0.038
0.000
0.002
(0-10)
0.080
Total
HeasuredC1>
%wt
9.890
20.802
0.011
0.101
0.022
1.622
1.275
0.558
0.023
0.021
0.124
5.417
0.008
0.006
0.018
0.000
0.001
0.000
0.001
0.012
0.032
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
0.026
0.014
0.000
0.023
unc
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
43.997
40.862
40.015
40.015
CU Estimated / extrapolated.
43U
-------
PH Profile Specfatton Report
Profile Name
Profile Number
Data Quality
Soil Dust - Composite
41350 ,
D
Control Device
Reference(s)
Data Source
Not applicable
26,27,30,31,32,40.42,43,45,46,48,54
Developed from profiles 41301, 41302, 41303, 41304, 41305,
41306, 41307, 41308, 41309, 41310, 41311, 41312, 41313,
41314, 41315, 41316, 41318, 41319, 41320, and 41401.
SCC Assignments:
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter -
CAS Hunter
7440-41-7
7440-42-8
7782-41 -4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
«?|MlW 1 CO
Nun Syn?
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
46
47
48
49
Be
B
F
Ha
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
CU
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Pd
As
Cd
In
0-2
Xwt
0.
0.
0.
0.
0.
6.
17.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0,
0.
000
000
000
299
716
289
014
067
525
520
728
843
000
335
014
011
096
010
000
004
035
039
000
000
000
000
016
000
005
000
002
003
008
000
.5 urn
unc
0.000
0.000
0.002
0.195
0.334
0.898
2.261
0.014
0.494
0.215
1.083
0.201
0.000
0.075
0.007
0,016
0.037
0.657
0.000
0.012
0,015
0.025
0.000
0.000
0.000
0.000
0,024
0.000
0.003
0.000
0.005
0,007
0.024
0.012
: <0-2.5)
: 0.020
2.5-
%wt
0.000
0.000
0.000
0.495
0.593
5.547
16.860
0.057
0.293
0.567
0.997
5.518
0.000
0.372
0.016
0.014
0.105
3.325
0.000
0.004
0.054
0.046
0.000
0.000
0.002
0.000
0.002
0.000
0.012
0.000
0.000
0.000
0.003
0.000
10 urn
une
0.000
0.000
0.000
0.176
0.159
0.818
1.576
0.009
0.036
0.203
0.099
0.301
0.000
0.077
0.003
0.002
0.018
0.376
0.000
0.002
0.018
0.013
0.000
0.000
0.000
0.000
0.002
0.000
0.002
0.000
0.000
0.000
0.015
0.000
(0-6)
0.040
0-10 urn
Xwt
0.000
0.000
0.000
0.446
0.624
5.732
16.898
0.059
0.351
0.556
0.930
4.349
0.000
0.362
0.015
0.013
0.103
3.246
0.000
0.004
0.050
0.045
0.000
0.000
0.002
0.000
0.005
0.000
0.010
0.000
0.000
0.001
0.004
0.000
unc
0.000
0.000
0.001
0.069
0.098
0.424
1.092
0.005
0.126
0.079
0.275
0.217
0.000
0.032
0.002
0.004
0.011
0.247
0.000
0.003
0,006
0.007
0.000
0.000
0.000
0.000
0.006
0.000
0,001
0.000
0.001
0,002
0.007
0,003
(0-10)
0.080
Total
Measured
%Ht
0.000
0.000
0.000
0.237
0.126
3.204
11.143
0.041
0.307
0.636
0.689
5.257
0.000
0.171
0,012
0.013
0.056
1.832
0.000
0.008
0.044
0.042
0.000
0.000
0.002
0.000
0.007
0.003
0.014
0.003
0.000
0.003
0.003
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.680
1.389
0.006
0.023
0.232
0.047
0.249
0.000
0.018
0.001
0.001
0.003
0.142
0.000
0.001
0.018
0.011
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
431
-------
PH Profile Special ion Report - continued (profile 41350)
Total Particulate Hatter -
CAS Number
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
. 7439-97-6
7439-92-1
ape c-i es
Hum Sym
50
51
55
56
58
BO
82
200
201
202
203
204
206
Sn
Sb
Cs
Ba
Ce
Hg
Pb
TC
oc
EC
S04
N03
C03
0-2.5 us
Xwt
0
0
0
0
0
0
0
0
0
0
0
0
0
.002
.000
.000
.000
.000
.000
.053
.000
.691
.094
.011
.011
.000
unc
0.013
0.025
0.000
0.065
0.000
0.000
0.103
0.000
0.676
0.156
0.017
0.230
0.000
2.5-10 urn
Xwt
0.000
0.011
0.000
0.016
0.000
0.000
0.041
0.817
0.617
0.105
0.007
0.000
8.257
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.008
0.000
0.457
0.243
0.019
0.001
0.000
0-10 urn
Xut
0.000
0.008
o.ooo
0.012
0.000
0.000
0.044
0.613
0.635
0.102
0.008
0.003
6.193
unc
0.003
0.006
0.000
0.016
0.000
0.000
0.026
0.029
0.207
0.072
0.007
0.057
0,292
Total
Measured
Xut
0.003
0.014
0.003
0.042
0.026
0.026
0.050
0.817
0.000
0.000
0.000
0.000
8.257
unc
0.000
0.000
0.000
0.006
0.000
0.000
0.004
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
31.441
44.753
41.423
33.091
432
-------
PH Profile Speclntion Report.
Profile Name Soil Dust,- SCAB
Profile Muifcer 41351
Data Quality C
Composite
Control Device Not Applicable
Reference(s) 62
Data Source Composite of surface dust samples collected to develop
profile #41323 and #41324.
SCC Assignments: 058
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Particulate Matter •
CAS Nunber
7429-90-1
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92- 1
TOTALS:
*?p*;b. ica
Ul.im Cum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mri
tr~
Ni
Cu
Zn
Ga
As
Se
5r
Rb
SP
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
fcwt
10
21
0
0
0
1
2
0
0
0
0
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
43
.583
.968
.123
.353
.109
.726
.054
.535
.031
.021
,133
.424
.008
.012
.040
.002
.012
.000
.001
.004
.015
.000
.000
,000
.000
.000
.000
.000
.000
.010
.000
.000
.000
.009
.173
.5 urn
unc
1.011
2.095
0.090
0.053
0.048
0.255
0.776
0.026
0.006
0.002
0.026
0.247
0.002
0.003
0.014
0.001
0.004
0.001
0.001
0.003
0.003
0.002
0.008
0.005
0.005
0.006
0.008
0.011
0.012
0.027
0.052
0.094
0.001
0.004
2.5-10 urn
Xut
9.626
20.204
0.094
0.213
0.099
1.955
2.109
0,568
0.024
0.025
0.139
5.774
0.008
0.006
0,021
0.000
0.000
0.000
0.003
0.015
0.031
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
0.037
0.006
0.000
0.027
40.991
unc
0.873
1.827
0.082
0.118
0.079
0.272
0.791
0.021
0.004
0.004
0.010
0.181
0.001
0.001
0.005
0.002
0.001
0.000
0.001
0.002
0.003
0.003
0.002
0.001
0.001
0.001
0.002
0.002
0.003
0.006
0.014
0.020
0.000
0.003
0-10 urn
%ut
9.683
20.310
0.095
0.221
0.100
1.942
2.105
0.566
0.025
0.025
0.139
5.755
0.008
0.006
0.022
0.000
0.001
0.000
0.003
0.014
0.030
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.035
0.006
0.000
0.026
41.125
unc
0.673
1.403
0.047
0.062
0.042
0.170
0.450
0.027
0.003
0.002
0.011
0.264
0,001
0.001
0.005
0,001
0.001
0.000
0.001
0.001
0.002
0.002
0.002
0.001
0.001
0.002
0.002
0.003
0.003
0.007
0.015
0.026
0.000
0.002
(0-10)
0.080
Total
Measured <:!>
Swt
9.683
20.310
0.095
0.221
0.100
1.942
2.105
0.566
0.025
0,025
0.139
5.755
0.008
0.006
0.022
0.000
0.001
0.000
0.003
0.014
0.030
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.035
0.006
0.000
0.026
41.125
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C1> Estimated / extrapolated.
433
-------
PH Profile Specialion Report
Profile Name Marine 'Aerosol
Profile Nunber 43101
Data Quality C/E
Control Device Not applicable
Reference(s) 46
Data Source Estimate - Assumes a Cl:
(except CD retain bulk
SCC Assignments: 114
Mass Fraction Data - Size Interval (un)
Mass Fraction
Total Particulate
Hatter
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
apec i es
Num Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Be
B
F
Na
Kg
Al
Sf
P
s
Cl
K
ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ge
Ge
As
Se
Sr
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Na ratio of 1 and all constituents
sea water ratios.
: (0-2.5) (0-6)
s 0.150 0.510
(0-10)
0.870
Total
0-2.5
%wt
NA 0
NA 0
NA 0
40.000 4
4.800 0
NA 0
Nft 0
NA 0
3.300 1
40.000 10
1.400 0
1.400 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
• < o
< 0
< 0
< 0
0.200 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
urn
unc
.000
.000
.000
.000
.900
.000
.000
.000
.300
.000
.200
.200
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.050
.000
.000
.000
.000
.000
.000
.000
.000
2.5-10 urn
%ut
NA
NA
NA
40.000
4.800
NA
NA
NA
3.300
40.000
1.400
1.400
<
<
<
<
<
<
<
<
<
<
<
<
<
<
0.200
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
4.000
0.900
0.000
0.000
0.000
1.300
10.000
0.200
0.200
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
0.000
0.000
,0.000
0.000
0.000
0.000
0.000
0.000
0-10
%wt
NE
NE
NE
40.000
4.800
NE
NE
NE
3.300
40.000
1.400
1.400
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
Ni
NE
0.200
NE
NE
NE
NE
Ni
Ni
Ni
NE
urn
unc
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.689
.275
.000
.000
.000
.337
.000
.069
.069
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.014
.000
.000
.000
.000
.000
.000
.000
.000
Measured
Xwt
NE
NE
NE
40.000
4.800
NE
NE
NE
3.300
40.000
1.400
1.400
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
0.200
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
D.,000
0.000
0.000
0.000
c.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
434
-------
PM Profile Speciation Report - continued (profile 43101}
Total Particulate Matter
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Nun Sym
56
58
80
82
201
202
203
204
Ba
Ce
H9
Pb
OC
EC
S04
N03
0-2.5
URI
Xwr unc
< 0.
< 0.
< 0.
< 0.
NA 0.
NA 0.
10.000 4.
NA 0.
000
000
000
000
000
000
000
000
2.5-10
urn
%ut unc
< 0
< 0
< 0
<, o
NA 0
NA 0
10.000 4
NA 0
.000
.000
.000
.000
.000
.000
.000
.000
0-10 urn
%ut
NE
NE
NE
NE
NE
NE
10.000
NE
unc
0
0
0
0
0
0
1
0
.000
.000
.000
.000
.000
.000
.034
.000
Total
Measured
%wt
NE
NE
NE
NE
NE
NE
10.000
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 101.100 101.100 101.100 101,100
435
-------
PH Profile Speefation Report
Profile Name Volcanic Ash
Profile Hunter 43301
Data Quality C/D
Control Device Hot applicable
Reference(s) 42
Data Source Resuspended ash.
SCC Assignments 115
Mass Fraction Data - Si» Interval (urn)
Mass Fraction
Total Particulote
f*B.n<
CAS Nunfcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-ts
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
ap<=i
Nun
4
5
9
11
12
13
14
15
16
17
19
20
?1
22
23
24
25
26
27
28
2V
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Hatter
Sym
Be
B
F
Na
Mg
Al
Sf
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
0-2
%wt
NA
NA
NA
3.400
0.800
8.600
32.000
<
0.040
0.060
1.400
2,860
<
0.330
0.010
<
0.050
2.490
<
<
<
<
<
<
<
<
<
, . <
<
<
<
<
<
<
<
0.040
.5 un
unc
0.000
0.000
0.000
0.100
0.020
0.200
1.000
0.000
0,000
0.020
0.040
0.080
0.000
0.000
0.000
0.000
0.000
0.070
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.1)
: 0.485
2,5-10 urn
%wt
NA
NA
NA
3.400
0,800
8.600
32.000
<
0.040
0.060
1.400
2.860
<
0.330
0.010
<
0.050
2.490
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
«
0.040
unc
0.000
0.000
0.000
0.100
0.020
0.200
1.000
0.000
0.000
0.020
0.040
0.080
0.000
0.000
0.000
0.000
0.000
0.070
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.390
0-10 urn
Xwt
NE
NE
NE
3.400
0.800
8.600
32.000
NE
0.040
0.060
1.400
2.860
NE
0.330
0.010
NE
0.050
2.490
NE
NE
NE
NE
NE
NE
NE
NE
NE
Ni
NE
NE
NE
NE
NE
NE
NE
0.040
unc
0.
0.
0.
0.
0.
1.
5.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
o:
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
000
000
609
143
529
041
000
000
027
251
511
000
000
000
000
000
445
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
(0-105
0.553
Total
Measured
Xwt
NE
Ni
NE
3.400
0.800
8.600
32.000
NE
0.040
0.060
1.400
2.860
NE
0.330
0.010
NE
0.050
2.490
Ni
NE
NE
NE
NE
NE
NE
NE
NE
Ni
NE
NE
NE
NE
NE
NE
NE
0.040
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
43C
-------
PH Profile Speciation Report - continued (profile 43301)
Total Paniculate Hatter -
Species
CAS Hunter
7440-45-1
7439-97-6
7439-92-1
Nun
58
80
82
201
202
203
Syra
Ce
Hg
Pb
OC
EC
S04
0-2
• Xwt
<
<
<
NA
NA
NA
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
2.5-
%Ut
<
<
<
NA
NA
NA
10 UK
unc
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
NE
NE
NE
NE
NE
NE
0
0
0
0
0
0
urn
unc
.000
.000
.000
.000
.000
.000
Total
Measured
Xwt
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
204 N03 NA 0.000 NA 0.000 NE 0.000 NE 0.000
TOTALS: 52.080 52.080 52.080 52.080
437
-------
PH Profile Speciation Report
Profile Name Limestone, Crustal
Profile Hunter 43304
Data Quality E
Control Device Hot Applicable
Reference(s) 62,90
Data Source Data taken from Reference 62. For details, consult Reference
90.
SCC Assignments: 115
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Particulate
(*>_<».
CAS Number
7440-33-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-66-6
7726-95-6
7440-24-6
7440-39-3
7439-92-1
TOTALS:
«|jct.
Hum
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
30
35
38
56
82
202
Hatter
I es
Syw
Na
Kg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Zn
Br
Sr
Ba
Pb
se
-
0
4
q
2
0
0
0
0
30
0
0
0
0
0
0-2.5
Xwt
.040
.700
.420
.400
.040
.120
.015
.270
.200
.040
.002
.001
.110
.380
0.002
0
0
0
0
0
11
50
.002
.001
.061
.001
.001
.400
.206
umW
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
%wt
0.040
4.700
0.420
2.400.
0.040
0.120
0.015
0.270
30.200
0.040
0.002
0.001
0.110
0.380
0.002
0.002
0.001
0.061
0.001
0.001
11.400
50.206
um{1} 0-10 un{1}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
fct
0.040
4.700
0.420
2.400
0.040
0.120
0.015
0.270
30.200
0.040
0.002
0.001
0.110
0.380
0.002
0.002
0.001
0.061
0.001
0.001
11.400
50.206
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-105
0.080
Total
Measured
%ut
0.040
4.700
0.420
2.400
0.040
0.120
0.015
0.270
30.200
0.040
0.002
0.001
0.110
0.380
0.002
0.002
0.001
0.061
0.001
0.001
11.400
50.206
unc
0.004
0.470
0.042
0.240
0.004
0.012
0.002
0.027
3.020
0.004
0.000
0.000
0.011
0.038
0.000
0.000
0.000
0.006
0.000
0.000
1.140
<1> Estimated / extrapolated.
438
-------
PM Profile Speciation Report
Profile Nwm : Shale, Crustal
Profile Umber : 43305
Data Quality ; E
Control Device : Not Applicable
Referenced) : 62,90
Data Source ; Data taken from Reference 62. For details, consult Reference
90.
SCC Assignments: 115
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-17-7
7440-24-6
7440-31-5
7440-39-3
7439-92-1
TOTALS:
afjei* i e&
KU'ti SfHi
11
12
13
14
15
16
17
19
20
22
?•*
24
25
26
28
29
30
37
38
50
56
82
202
Ne
MS
Al
Si
P
S
Cl
K
Ca
Ti
*
Cr
Mr,
Fe
Ni
Cu
Zn
Rb
Sr
Sn
Ba
Pb
EC
0-2.5
%Mt
0
1
8.
27
0
0
0
2
2
0
0
.960
.500
.000
.300
.070
.240
.018
.660
.210
.460
.013
0.009
0
4
0
0
0
0
0
0
0
0
1
49
.085
.720
.007
.005
.010
.014
.030
.001
.058
.002
.500
.872
unC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.020
2.5-10
Xwt
0.960
1.500
8.000
27.300
0.070
0.240
0.018
2.660
2.210
0.460
0.013
0.009
0.081
4.720
0.007
0.005
0.010
0.014
0.030
0.001
0.058
0.002
1.500
49.872
un€1>
unc
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.040
0-10
Xut
0.960
1.500
8.000
27.300
0.070
0.240
0.018
2.660
2.210
0.460
0.013
0.009
0.085
4.720
0.007
0.005
0.010
0.014
0.030
0.001
0.058
0.002
1.500
49.872
un»Cl>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
%ut
0.960
1.500
8.000
27.300
0.070
0.240
0.018
2.660
2.210
0.460
0.013
0.009
0.085
4.720
0.007
0.005
0.010
0.014
0.030
0.001
0.058
0.002
1.500
49.872
unc
0.096
0.150
0.800
2.730
0.007
0.024
0.002
0.266
0.221
0.046
0.001
0.001
0.009
0.472
0.001
0.001
0.001
0.001
0.003
0.000
0.006
0.000
0.150
C1> Estimated / extrapolated.
439
-------
PH Proffit Speeiation Report
Profile Kerne Sandstone, Crustal
Profile Umber 43306
Data Quality E
Control Device Not Applicable
Reference(s) 62,91
Data Source Data taken from Reference 62. For details,
91.
SCC Assignments: 115
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.020
Total Particulate
Hatter
CAS Nunfcer
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7439-89-6
7440-39-3
TOTALS:
Hum Sym
11
12
13
14
15
16
19
20
22
26
56
202
Na
H9
Al
Si
P
S
K
Ca
Ti
Fe
Sa
EC
consult Reference
(0-6)
0.040
(0-10)
0.080
Total
0-2.5
%wt
0.334
0.700
2.523
36.580
0.035
0.028
1.087
3.933
0.150
0.981
0,045
1.373
47.769
um{1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
0.334
0.700
2.523
36.580
0.035
0.028
1.087
3.933
0.150
0.981
0.045
1.373
47.769
um{1)
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0
0
2
36
0
0
1
3
0
0
0
1
47
.334
.700
.523
.580
.035
.028
.087
.933
.150
.981
.045
.373
.769
un(1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xwt
0.334
0.700
2.523
36.580
0.035
0.028
1.087
3.933
0.150
0.981
0.045
1.373
47.769
unc
0.067
0.140
0.505
7.316
0.007
0.006
0.218
0.787
0.030
0.196
0.009
0.275
C1> Estimated / extrapolated.
440
-------
PM Profile Specletion Report
Profile Name
Profile Number
Data Quality
Sediment, Crusta I
43307
Control Device : Not Applicable
Reference^} : 62,91
Data Source s Data taken from Reference 62..For details, consult Reference
91.
SCC Assignments: 115
Mass Fraction Data -
Size Interval (urn) :
Mass Fraction ;
(0-2.5)
0.020
(0-6)
0.040
(0-10)
0.080
Total Particulate Matter -
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7439-89-6
opcu i e»
Nun Svm
11
12
13
14
15
16
19
20
22
26
202
Na
Mg
Al
si
p
s
K
Ca
Ti
Fe
EC
0-2.5
%wt
0.
1.
7.
27.
0.
0.
2.
4.
0.
4.
2.
839
598
083
063
057
216
374
211
341
042
129
um{1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
%wt
0.839
1.598
7.083
27.063
0.057
0.216
2.374
4.211
0.341
4.042
2.129
unC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
%ut
0.839
1.598
7.083
27.063
0.057
0.216
2.374
4.211
0.341
4.042
2.129
Total
umC1> Measured
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Xirt
0.839
1.598
7.083
27.063
0.057
0.216
2.374
4.211
0.341
4.042
2.129
unc
0.168
0.320
1.417
5.413
0.011
0.043
0.475
0.842
0.068
0.808
0.426
TOTALS: 49.953 49.953 49.953 49.953
CD Estimated / extrapolated.
441
-------
PM Profile Speeiation Report
Profile Name : Igneous Rock
Profile Nuifcer : 43308
Data Quality : E
Control Device : Not Applicable
Reference(s) : 62,91
Data Source : Data taken front Reference 62. For details, consult Reference
91.
SCC Assignments: 115
Mass Fraction Data -
Size Interval (urn) :
Mass Fraction :
<0-2.5)
0.020
CO-6)
0.040
0.080
Total Participate Matter -
Species
CAS Number
7440-23-S
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7440-09-7
7440-70-2
7440-32-6
7439-89-6
7440-39-3
0-2.5 unCD
Nun Sym Xwt
11
12
13
14
15
19
20
22
26
56
202
Na
Ms
Al
Si
P
K
Ca
Ti
Fe
Ba
EC
TOTALS:
2.849
2.105
8.115
27.618
0.131
2.598
3.632
0.629
5.106
0.054
0.027
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
52.864
2.
5-10
Xwt
2.
2.
8.
27.
0.
2.
3.
0.
5.
0.
0.
849
105
115
618
131
598
632
629
106
054
027
52.864
unCO
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
2.849
2.105
8.115
27.618
0.131
2.598
3.632
0.629
5.106
0.054
0.027
umCI}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
52.864
Total
Measured
Xwt
2.849
2.105
8.115
27.618
0.131
2.598
3.632
0.629
5.106
0.054
0.027
52.864
unc
0.570
0.421
1.623
5.524
0.026
0.520
0.726
0.126
1.021
0.011
0.006
•C1> Estimated / extrapolated.
442
-------
PN Profile Speciat!on Report
Prof ile Name Earth's
Profile Number 43309
Data Quality E
Crust
Control Device Wot Applicable
Reference(s) 62,91
Data Source Data taken from Reference 62. For details, consult Reference
91.
SCC Assignments: 115
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Particulate
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
opci
Nun
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
41
42
47
48
49
50
51
56
57
Matter
lies
Syrn
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
68
As
se
Sr
Rb
Sr
y
Zr
Nb
Mo
Ag
Cd
In
Sn
Sb
Ba
La
0-2.5 um{1>
.%wt
2
2
8
28
0
0
0
2
4
0
0
0
0
5
0
0
0
0
0
0
q
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.360
.330
.320
.200
.105
.026
.013
.090
.150
.570
.014
.010
.095
.630
.003
.008
.006
.007
,002
.000
.000
.000
.009
.038
,003
.017
,002
.000
.000
,000
.000
.000
.000
.043
.003
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
2,360
2.330
8,320
28.200
0.105
0.026
0.013
2.090
4.150
0.570
0.014
0.010
0.095
5.630
0.003
0.008
0.006
0.007
0.002
0.000
0.000
0.000
0.009
0.038
0.003
0.017
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.043
0.003
umt1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
2.360
2.330
8.320
28.200
0.105
0.026
0.013
2.090
4.150
0,570
0.014
0.010
0.095
5.630
0.003
0.008
0.006
0.007
0.002
0.000
0.000
0.000
0.009
0.038
0,003
0.017
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.043
0.003
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
Xwt
2.360
2.330
8,320
28.200
0.105
0.026
0.013
2.090
4.150
0,570
0.014
0.010
0.095
5.630
0.003
0.008
0.006
0.007
0.002
0.000
0.000
0.000
0.009
0.038
0.003
0.017
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.043
0.003
unc
0.708
0.699
2.496
8.460
0.032
0.008
0.004
0.627
1.245
0.171
0.004
0,003
0.029
1.689
0.001
0.002
0.002
0.002
0.001
0.000
0.000
0.000
0.003
0.011
0.001
0.005
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.013
0.001
443
-------
PM Profile Speeiation Report - continued (profile 43309)
Total Parti cut. ate Hatt<
Species
CAS Number
7440-45-1
7440-00-8
7439-97-6
7439-92-1
7440-69-9
TOTALS:
Hum
58
60
80
82
83
202
Eym
Ce
Nd
Kg
Pb
Bi
EC
sr -
•0-2.5 unC1>
%wt
0.
0.
0.
0.
0.
0.
54.
006
003
000
001
000
020
084
une
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xut
0.006
0.003
0.000
0.001
0.000
0.020
54.084
umCU
unc
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.006
0.003
0.000
0.001
0.000
0.020
54.084
umCU
une
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xut
0.006
0.003
0.000
0.001
0.000
0.020
54.084
unc
0.002
0.001
0.000
0.000
0.000
0.006
C1> Estimated / extrapolated.
444
-------
3.16 WOOD COMBUSTION
Wood is burned in industrial/commercial boilers to obtain heat energy
and to alleviate waste disposal problems in the pulp and paper industries.
Residential wood burning is commonly used to supplement conventional heating
systems. In the industrial sector, the burning of wood waste in boilers is
mostly confined to those industries where wood is available as a byproduct. A
variety of boiler configurations is used for burning wood waste. These
include dutch oven configurations, spreader stokers, and tangentially-fired or
cyclone-fired boilers. Residential woodstoves are usually radiating or
circulatory designs constructed from cast iron, heavy gauge sheet metal, or
stainless steel. Emissions from wood combustion are affected by furnace
design and operating conditions, and fuel characteristics such as fuel
composition, moisture content, and effective burning surface area.
445
-------
446
-------
PH Profile Speciation Report
Profile Name Wood Stoves - Pine Fuel
Profile Number 42101
Data duality A/0
Control Device Uncontrolled
Reference(s) 33
Data Source Size-resolved sanples(fine) taken using • dilution tunnel.
XRF and carbon oxidation analysis. Profile based on
emission weighted average of 6 samples.
Mass Fraction Dstc • Sirs Interval (urn) s (0-2.5) (0-6) (0-103
Mass Fraction ; 0.980 0.980 0.980
Total Participate Hatter
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
Nun
4
5
9
11
12
13 •
14
15
16
17
19
20
21
22
23
24
25
26
27
•at
29
30
31
32
33
34
35
37
38
4U
47
48
50
51
55
56
Sym
Be
S
f
Na
Mg
Al
Si
P
S
Cl
K
Ca
Sc
If
V
Cr
Mn
Fe
Co
*!?
Cu
Zn
Ca
Ge
As
Se
Br
Rb
Sr
2r
Ag
Cd
Sn
Sb
Cs
Ba
0-2.5 urn
%ut unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
0.100 0.000
0.100 0.000
1.000 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
2.5-10 urn
%wt unc
NA 0.000
MA 0.000
UA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
0.100 0.000
0.100 0.000
1.000 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0,000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0-10 um
%wt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
0,100 0.020
0.100 0.020
1.000 0.200
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
Total
Measured
%ut unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
0.100 0.000
0,100 0.000
1.000 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
447
-------
PH Proffie Speciatfon Report - continued (profile 42101)
Total Participate Hatter -
Species
CAS Number Nun Sym
7440-45-1 58
7439-97-6 80
, 7439-92-1 82
201
202
203
204
Ce
Hg
Pb
OC
K
S04
N03
0-2
%ut
•;
<
38.700
4.500
NA
NA
.5
0
0
0
0
0
0
0
UR1
unc
.000
.000
.000
.000
.000
.000
.000
2.5-10
Xut
<
<
38.700
4.500
NA
NA
urn
unc
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
0-10 UK
Xwt
<
<
38.700
4.500
NA
HA
unc
0.000
0.000
0.000
7.740
0.900
0.000
0.000
Total
Measured
Xut
«
c
38.700
4.500
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 44.400 44.400 44.400 44.400
448
-------
PM Profile Speciat ion Report
Profile Name Hood Stoves • Average, All Fuels
Profile Number 42102
Data Quality A/D
Control Device Uncontrolled
Reference(s) 33
Data Source Size-resolved samples (fine) taken using a dilution tunnel.
XRF and carbon oxidation analysis. Profile based on
emission weighted average of 41 samples.
Mass Fraction Data - Size
Total Paniculate
Mass
Hatter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
Nun)
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Sym
Be
B
f
Na
Mi
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
2n
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Interval (urn) :
Fraction :
0-2.5 urn
Xwt unc
• NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
1.800 0.000
0.800 0.000
8.000 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0,000
< 0.000
< 0.000
< 0.000
< 0.000
, < 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
(0-2.5)
0.980
2.5-10 urn
Xwt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
1.800 0.000
0.800 0.000
8.000 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
(0-6)
0.980
0-10 urn
Xwt une
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NR 0.000
• NR 0.000
NR 0.000
1.800 0.360
0.800 0.160
8.000 1.600
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
(0-10)
0.980
Total
Measured
%wt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
1.800 0.000
0.800 0.000
8.000 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
-------
PM Profile Specfatfon Report - continued (profile 42102)
Total Participate Matter -
CAS Number
7440-45-1
7439-97-6
7439-92-1
TOTALS:
Hum Sym
58
80
82
201
202
203
204
Ce
Hg
Pb
OC
EC
S04
N03
sss&sxss&ssxs&ssss&s&s^sxss:^
0-2.5 urn
Xwt
<
<
<
35.900
6.400
HA
NA
52.900
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
%wt
<
<
<
35.900
6.400
NA
NA
52.900
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
=============================
0-10 urn
Xwt
<
<
<
35.900
6.400
NA
NA
52.900
========
une
0.000
0.000
0.000
7.180
1.280
0.000
0.000
Total
Measured
Xwt
<
<
<
35.900
6.400
NA
NA
52.900
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
======================
450
-------
PH Profile Speciation Report
Profile Name Hood Stoves - Oak Fuel
Profile Number 42103
Data Quality A/D
Control Device Uncontrolled
Referenee(s) 33
Data Source Size-resolved sanples (fine) taken using « dilution tunnel.
XRF and cartoon oxidation analysis. Profile based on
emission weighted average of 6 sanples.
Mass Fraction Data • Size Interval Curt : (0-2.5) (0-6) (0-105
Mass Fraction : 0.980 0.980 0.980
Total Particular Matter
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
Num
4
5
9
11
12
13
14
15
16
17
19
iO
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Sym
Be
B
F
Na
Mg
Al
Si
p
S
Cl
K
ua
Sc
Ti
V
Cr
Nn
Fe
Co
Uf
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
As
Cd
Sn
Sb
Cs
Ba
0-2.5 urn
%wt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
• NR 0.000
1.600 0.000
1.800 0.000
7.700 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
. < 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
2.5-10 urn
Xwt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
1.600 0.000
1.800 0.000
7.700 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0-10 urn
Xwt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
1.600 0.320
1.800 0.360
7.700 1.540
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
Total
Measured
Xwt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NA 0.000
NR 0.000
NR 0.000
NR 0.000
1.600 0.000
1.800 0.000
7.700 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
« 0.000
< 0.000
< 0.000
451
-------
PM Profile Specialion Report - continued (profile 42103)
Total Particulate Hatter -
Species
CAS Number Hum Sym
Total1'
Measured
0-2.5 urn 2.5-10 urn 0-10 tin
Xwt unc Xut uric Xwt unc Xwt unc
7440-45-'
7439-97-<
7439-92-'
TOTALS:
1 58
i 80
1 82
201
202
203
204
Ce
Hf
Pb
oc
EC
S04
N03
29
7
47
:
<
.200
.200
NA
NA
.500
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<
<
29.200
7.200
NA
NA
47.500
0.000
0.000
0.000
0.000
0.000
0.000
0.000
«
<
29.200
7.200
NA
NA
47.500
xssaslxss
0.000
0.000
0.000
5.840
1.440
0.000
0.000
<
<
29.200
7.200
NA
NA
47.500
0.000
0.000
0.000
0.000
0.000
0.000
0.000
452
-------
PH Profile Speciat ion Report
Profile Name ; Fireplaces - Softwoods
Profile Number : 42201
Data Quality : C/D
Control Device : Uncontrolled
Reference(s) : 34
Data Source : EC and OC analysis of 7 softwood and 14 hardwood tests using
Method 5 train. Potassium values are an average of 3 tests
burning pine and spruce.
Mass Fraction Data • Size Interval (un> s CO-2.5) (0-6)
Mass Fraction : 0.980 0.980
Total Particulate
Matter
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
(0-10)
0.980
Total
0-2
Nun Sym Xwt
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
in
47
48
50
51
55
56
Be
e
F
Na
Mg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
cr
Mn
Fe
Co
Ni
Cu
2n
Ga
Ce
As
Se
Br
RD
Sr
7r
Ag
Cd
Sn
sb
Cs
Ba
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.606
NA
NA
NA
• NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
.5 urn
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
2.5-10 urn
%wt
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.606
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
%wt
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
0.606
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xut
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.606
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
453
-------
PM Profile Speciat ion Report - continued (profile 42201)
Total Participate Matter
Species
CAS Nu*er
7440-45-1
7439-97-6
7439-92-1
Nun
58
80
82
201
202
203
204
Sym
Ce
Hg
Pb
OC
EC
S04
N03
0-2.5 m
Xut
NA
NA
NA
38.000
33.000
NA
NA
unc
0.000
0.000
0.000
6.000
13.000
0.000
0.000
2.5-10
urn
Xut unc
NA
NA
NA
38.000
33.000
NA
NA
0
0
0
6
13
0
0
.000
.000
.000
.000
.000
.000
.000
0-10 urn
Xut
NE
NE
Hi
38.000
33.000
NE
NE
unc
0.000
0.000
0.000
11.391
0.000
0.000
0.000
Total
Measured
Xut
NA
NA
NA
38.000
33.000
NA
NA
une
0.000
0.000
0.000
6.000
13.000
0.000
0.000
TOTALS: 71.606 71.606 71.606 71.606
454
-------
PM Profile Special ion Report
Profile Name Fireplaces - Hardwoods
Profile Number 42202
Data Quality C/0
Control Device Uncontrolled
Reference^ ) 34
Data Source EC and OC analysis of 14 hardwood tests.
are an average of 3 red oak tests.
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.980
Total Particulate
Matter
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440 - 70 -Z
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
afjct. i ea
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
Be
B
F
Na
Hg
Al
Si
P
S
Ct
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ge
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Ce
Potassium values
(0-6)
0.980
(0-10)
0.980
Total
0-2
Xwt
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.030
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
' NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
.5 an
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
*wt
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.030
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
1.030
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xwt
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.030
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
455
-------
PH Profile Speciation Report - continued (profile 42202)
Total Participate
Hatter
CAS Number
7439-97-6
7439-92-1
Total
0-2
Nun Sym Xut
80
82
201
202
203
204
Hg
Pb
OC
EC
S04
N03
NA
NA
46.000
8.000
NA
NA
.5 urn
unc
0.000
0.000
7.000
7.000
0.000
0.000
2.5-10 unt
Xwt
NA
NA
46.000
8.000
NA
NA
unc
0.000
0.000
7.000
7.000
0.000
0.000
0-10
Xut
NE
Ni
46.000
8.000
NE
NE
urn
unc
0
0
13
10
0
0
.000
.000
.514
.028
.000
.000
Measured
%ut
NA
NA
46.000
8.000
NA
NA
unc
0.000
0.000
7.000
7.000
0.000
0.000
TOTALS: 55.030 55.030 55.030 55.030
456
-------
PM Profile Speciation Report
Profile Name Residential Wood
Profile Number 42303
Data Quality A/C
Combustion - Composite
Control Device Uncontrolled
Referencc(s) 45
Data Source Average of 16 samples from 8 sources: 45% fireplaces and
55% wood stoves.
Mass Fraction Data - Siie Interval Cun) : (0-2.53 {0-6}
Mass Fraction : 0.980 0.980
Total Partieulste
Hatter
CAS Number
7440-41-7
7440-42-8
7782-41 -4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-23-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
«»pcw I so
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
2',
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
oe
E
f
Ha
Hg
At
Si
P
s
Cl
K
Ca
3^
Tf
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Qe
As
Se
Br
Rb
Sr
7r
Ag
Cd
Sn
Sb
Cs
Ba
Ce
CO-10J
0.980
Total
0-2
.Xwt
NA
KA
NA
0.083
0.073
0.021
<
<
0.182
0.509
0.860
0.067
NA
<
<
<
<
<
NA
<
<
, 0.037
NA
<
<
<
<
NA
<
NA
NA
<
NA
<
NA
<
<
.5 un
unc
0.000
0.000
0.000
0.012
0.017
0.000
0.000
0.000
0.019
0.031
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-
%Ht
NA
NA
NA
0.083
0.073
0.021
<
<
0.182
0.509
0.860
0.067
NA
<
<
<
<
<
NA
<
<
0.037
NA
<
<
<
<
NA
<
NA
NA
<
NA
<
NA
<
<
10 un
unc
0.000
0.000
0.000
0.012
0.017
0.000
0.000
0.000
0.019
0.031
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 tm
%ut
HE
NE
NE
0.083
0.073
0.021
NE
NE
0.182
0.509
0.860
0.067
NE
NE
NE
NE
NE
NE
NE
NE
NE
0.037
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.024
0.028
0.000
0.000
0.000
0.045
0.111
0.173
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xwt
NE
NE
NE
0.083
0.073
0.021
NE
NE
0.182
0.509
0.860
0.067
NE
NE
NE
NE
NE
NE
NE
NE
NE
0.037
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
457
-------
PH Profile Speciatfon Report - continued (profile 42303}
Total Participate Matter
CAS Number
7439-97-6
7439-92-1
Hum Sym
80
82
201
202
203
204
Ha
Pb
OC
EC
S04
NQ3
0-2.5 urn
Xut
<
<
47.SOO
12.800
0.289
HA
uric
0.000
0.000
13.800
8.400
0.021
0.000
«
2.5-10 urn
Xwt
<
<
47.500
12.800
0.289
HA
unc
0.000
0.000
13.800
8.400
0.021
0.000
0-10
Xwt
NE
NE
47.500
12.800
0.289
Ni
urn
unc
0
0
0
12
0
0
.000
.000
.000
.152
.065
.000
Total
Measured
Xwt
NE
NE
47.500
12.800
0.289
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 62.421 62.421 62.421 62.421
458
-------
PH Profile Speciation Report
Profile Nam
Profile Number
Data Quality
Slash Burning {Conifer-f laming phase)
42305
E
Control Device Not Applicable
Referenced) 87
Data Source Samples collected 20 meters above slash fire over three
ten-minute periods. Analyzed by gas chromatogrephy.
SCO Assignments: 062. 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction ; 0.900 0.960
Total Particulate Matter *
CAS Number
7440-23-5
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7439-92-1
TOTALS!
Num Sym
11
13
14
16
17
19
20
22
23
24
25
26
28
29
30
35
82
201
202
Na
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Br
Pb
OC
EC
0-2.5 urn
Xwt
2
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
36
18
.734
.120
.091
.341
.556
.419
.182
.218
.069
.113
.038
.057
.009
.009
.118
.048
,154
.400
.600
unc
3.664
0.083
0.064
0.147
0.317
0.809
0.231
0.220
0.122
0.194
0.033
0.102
0.006
0.006
0.094
0.021
0.097
11.284
12.462
61.276
2.5-10
Xwt
2.734
0.120
0.091
0.341
0.556
1.419
0.182
0.218
0.069
0.113
0.038
0.057
0.009
0.009
0.118
0.048
0.154
36.400
18.600
61.276
uraC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
%wt
2.734
0.120
0.091
0.341
0.556
1.419
0.182
0.218
0.069
0.113
0.038
0.057
0.009
0.009
0.118
0.048
0.154
36.400
18.600
61.276
um<1J
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
MeasuredC1>
Xwt
2.734
0.120
0.091
0.341
0.556
1,419
0.182
0.218
0.069
0.113
0.038
0.057
0.009
0.009
0.118
0.048
0.154
36.400
18.600
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
61 .276
C1> Estimated / extrapolated.
459
-------
PH Profile Speciation Report
Profile Name Slash Burning (Conifer-smoldering phase)
Profile Nuifcer 42306
Data Quality E
Control Device Not Applicable
ieferenee(s) 87
Data Source Sanples collected 10 meters above slash fire over three
180-minute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Paniculate Hatter -
Species
CAS Hunter
7440-23-5
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7439-92-1
Hum
11
13
14
16
17
19
20
22
23
24
25
26
28
29
30
35
82
201
202
Syra
Ha
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Kn
Fe
Hi
Cu
Zn
8r
Pb
OC
EC
0-2
Xut
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
51
.732
.101
.167
.114
.118
.126
.127
.124
.031
.024
.020
.061
.010
.010
.016
.025
.078
.900
3.400
.5 un
unc
0.483
0.097
0.197
0.066
0.063
0.063
0.103
0.089
0.025
0.016
0.017
0.040
0.006
0.006
0.010
0.013
0.055
8.304
0.782
2.5-10
Xut
0.732
0.101
0.167
0.114
0.118
0.126
0.127
0.124
0.031
0.024
0.020
0.061
0.010
0.010
0.016
0.025
0.078
51 .900
3.400
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.732
0.101
0.167
0.114
0.118
0.126
0.127
0.124
0.031
0.024
0.020
0.061
0.010
0.010
0.016
0.025
0.078
51.900
3.400
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
Heasured{1>
Xwt
0.732
0.101
0.167
0.114
0.118
0.126
0.127
0.124
0.031
0.024
0.020
0.061
0.010
0.010
0.016
0.025
0.078
51.900
3.400
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
57.184
57.184
57.184
57.184
C1> Estimated / extrapolated.
460
-------
PM Profile Speciation Report
Profile Name Slash Burning (Hardwood-flaming
Profile Number 42307
Data Quality E
phase)
Control Device Not Applicable
Referenee(s) 87
Data Source Samples collected 20 meters above slash fire over three
10-fliinute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6}
Mass Fraction : 0.900 0.960
Total Particulate Matter -
CAS Nunfcer
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
0^*31. i «»
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Kn
Fe
Ni
Cu
Zn
Br
AS
Cd
Sn
Pb
oc
EC
0-2
Xwt
0
0
0
1
2
5
0
0
0
0
0
0
0
0
0
0
0
.280
.427
.237
.118
.703
.014
.181
.019
.006
.018
.023
.107
.024
.021
.154
.124
.077
0.169
0
0
60
8
.086
.211
.300
.300
.5 urn
unc
0.434
0.521
0.254
1.219
3.163
6.217
0.398
0.029
0.009
0.043
0.030
0.227
0.054
0.037
0.186
0.104
0.156
0.397
0.169
0.371
1.809
4.731
2.5-10
Xwt
0.280
0.427
0.237
1.118
2.703
5.014
0.181
0.019
0.006
0.018
0.023
0.107
0.024
0.021
0.154
0.124
0.077
0.169
0.086
0.211
60.300
8.300
um{1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.280
0.427
0.237
1.118
2.703
S.014
0.181
0.019
0.006
0.018
0.023
0.107
0.024
0.021
0.154
0.124
0.077
0.169
0.086
0.211
60.300
8.300
unC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
Measured^}
Xwt
0.280
0.427
0.237
1.118
2.703
5.014
0.181
0.019
0.006
0.018
0.023
0.107
0.024
0.021
0.154
0.124
0.077
0.169
0.086
0.211
60.300
8.300
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 79.599 79.599 79.599 79.599
{1} Estimated / extrapolated.
461
-------
PH Profile Spectation Report
Profile Name
Profile Number
Data Quality
Slash Burning (Hardwood-smoldering phase)
42308
£
Control Device Not Applicable
Reference(s) 87
Data Source Samples collected 10 meters above slash fire over three
180 -minute periods. Analyzed by gas chromotography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Particulate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS;
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Br
AS
Cd
Sn
Pb
OC
EC
0-2
Xwt
0
0
0
0
0
0
0
0
0
0
d
0
0
0
0
0
0
0
0
0
61
2
67
.181
.336
.093
.503
.468
.577
.183
.013
.004
.003
.011
.062
.003
.001
.014
.019
.030
.066
.043
.031
.700
.700
.041
.5 urn
unc
0.161
0.407
0.079
0.483
0.2Z5
0.565
0.344
0.013
0.006
0.004
0.013
0.087
0.004
0.001
0.018
0.010
0.034
0.115
0.066
0.041
2.468
0.999
2.5-10
Xwt
0.181
0.336
0.093
0.503
0.468
0.577
0.183
0.013
0.004
0.003
0.011
0.062
0.003
0.001
0.014
0.019
0.030
0.066
0.043
0.031
61.700
2.700
67.041
um£1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.181
0.336
0.093
0.503
0.468
0.577
0.183
0.013
0.004
0.003
0.011
0.062
0.003
0.001
0.014
0.019
0.030
0.066
0.043
0.031
61.700
2.700
67.041
(0-10)
0.990
Total
un{1> HeasuredC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Xwt
0.181
0.336
0.093
0.503
0.468
0.577
0.183
0.013
0.004
0.003
0.011
0.062
0.003
0.001
0.014
0.019
0.030
0.066
0.043
0.031
61.700
2.700
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
67.041
C1> Estimated / extrapolated.
462
-------
PH Profile Speciation Report
Profile Name Slash
Profile Number 42309
Data Quality E
Burning (Ponderosa
Pine-flaming phase)
Control Device Not Applicable
ReferenceCs) 8?
Data Source Saiiiples collected 20 meters above slash fire over three
10 -minute periods. Analyzed by 0as chroma tography.
SCC Assignments: 062, 50300201
Mass Fraction Data * Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Partieulate Hatter •
CAS Nwber
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
Nun Sytn
13
14
15
16
17
19
20
22
23
24
25
?*
28
29
30
35
47
48
50
82
201
202
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Kn
Fe
fl !
Cu
In
Br
Ag
Cd
Sn
FD
oc
EC
0-2
%wt
0
0
0
0
.081
.152
.088
.556
0.554
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
55
10
69
.103
.112
.010
.003
.003
.016
.010
.005
.000
.115
.033
.028
.045
.013
.068
.100
.900
.995
.5 um
unc
0.038
0.082
0.034
0.295
0.332
1.157
0.052
0.010
0.003
0.005
0.007
0.008
0.005
0.000
0.069
0.025
0.018
0.048
0.015
0.063
3.857
5.559
2.5-10
Xwt
0.081
0.152
0.088
0.556
0.554
2.103
0,112
0.010
0.003
0.003
0.016
0.010
0.005
0.000
0.115
0.033
0.028
0.045
0.013
0.068
55.100
10.900
69.995
umm
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
%wt
0.081
0.152
0.088
0.556
0.554
2.103
0.112
0.010
0.003
0.003
0.016
0.010
0.005
0.000
0.115
0.033
0.028
0.045
0.013
0.068
55.100
10.900
69.995
un€1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
Heasuredcn
%wt
0.081
0.152
0.088
0.556
0.554
2.103
0.112
0.010
0.003
0.003
0.016
0.010
0.005
0.000
0.115
0.033
0.028
0.045
0.013
0.068
55.100
10.900
69.995
unc
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
€1> Estimated / extrapolated.
463
-------
PH Profile Speciation Report
Profile Name : Slash Burning (Ponderosa Pine-smoldering phase)
Profile Number : 62310
Data Quality : E
Control Device ; Mot Applicable
Reference(s) : 87
Data Source : Samples collected 10 meters above slash fire over three
180-minute periods. Analyzed by gas chrometography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Partfculate Matter
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
^}«K7V i<*a
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
Al
Si
p
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Hi
Cu
Zn
Br
Ag
Cd
Sn
Pb
DC
EC
0-2.5 urn
Xwt
0.105
0.148
0.048
0.162
0.226
0.501
0.073
0.005
0.002
0.000
0.008
0.057
0.002
0.000
0.025
0.008
0.018
0.014
0.018
0.019
61.000
4.100
66.539
unc
0.069
0.170
O.Q23
0.110
0.167
0.396
0.094
0.008
0.002
0.000
0.008
0.094
0.001
0.000
0.019
0.005
0.013
0.010
0.014
0.013
3.050
1.107
: (0-2.5)
: 0.900
2.5-10
%ut
0.105
0.148
0.048
0.162
0.226
0.501
0.073
0.005
0.002
0.000
0.008
0.057
0.002
0.000
0.025
0.008
0.018
0.014
0.018
0.019
61.000
4.100
66.539
umCI}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.960
0-10 umC1>
%ut
0.105
0.148
0.048
0.162
0.226
0.501
0.073
0.005
0.002
0.000
0.008
0.057
0.002
0.000
0.025
0.008
0.018
0.014
0.018
0.019
61 .000
4.100
66.539
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
Measured^}
%wt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
61
• 4
66
.105
.148
.048
.162
.226
.501
.073
.005
.002
.000
.008
.057
.002
.000
.025
.008
.018
.014
.018
.019
.000
.100
.539
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C1> Estimated / extrapolated.
464
-------
PM Profile Speciat ion Report
Profile Name Slash Burning (Tractor-pi led;f laming phase}
Profile Nwfcer 42311
Data Quality E
Control Device Not Applicable
Reference(s) 87
Data Source Samples collected 20 meters above slash fire over three
10 -minute periods. Analyzed fay gas chronatography.
see Assignments: 062, 50300201
Mass Fraction Data - Size Interval Cum) ; (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Particulete Natter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
Nun Syn
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Br
Ag
Cd
Sn
Pb
OC
EC
0-2
Xwt
0.
0,
0.
0.
0.
3.
0.
0.
0.
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
65.563 65.563 65.563
CO-10)
0.990
Total
Measuredd}
Xwt
0.181
0.348
0.128
0.950
0.921
3.895
0.619
0.018
0.007
0.000
0.045
0.030
0.011
0.007
0.389
0.146
0.172
0.066
0.196
0.234
49.000
8.200
65.563
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO Estimated / extrapolated.
465
-------
PM Profile Speciation Report
Profile Name Slash Burning (Tractor-pi led;smoldering
Profile Number 42312
Data Quality E
phase)
Control Device Hot Applicable
ReferenceCs) 87
Data Source Samples collected 10 meters above slash fire over three
180-tninute periods. Analyzed by gm chronstography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6}
Mass Fraction : 0.900 0.960
Total Particulate
Hatter
(0-10)
0.990
Total
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
apt;i* 1 G&
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Hi
Cu
Zn
Br
Ag
Cd
Sn
Pb
oc
EC
0-2
Xut
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
53
2
.056
.052
.039
.228
.227
.606
.071
.002
.001
.000
.005
.003
.027
.000
.012
.012
.008
.015
.000
.010
.100
.900
.5 urn
unc
0.007
0.024
0.007
0.043
0.018
0.188
0.011
0.002
0.001
0.000
0.003
0.005
0.045
0.000
0.005
0.003
0.010
0.022
0.000
0.004
2.124
1.421
2.5-10
fet
0.056
0.052
0.039
0.228
0.227
0.606
0.071
0.002
0.001
0.000
0.005
0.003
0.027
0.000
0.012
0.012
0.008
0.015
0.000
0.010
53.100
2.900
umm
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
'0.000
0.000
0.000
0.000
0-10
Xwt
0.056
0,052
0.039
0.228
0.227
0.606
0.071
0.002
0.001
0.000
0.005
0.003
0.027
0.000
0.012
0.012
0.008
0.015
0.000
0.010
53.100
2.900
umm
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured <;l>
%ut
0.056
0.052
0.039
0.228
0.227
0.606
0.071
0.002
0.001
0.000
0.005
0.003
0.027
0.000
0.012
0.012
O.OOS
0.015
0.000
0.010
53.100
2.900
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
57.374
57.374
57.374
57.374
Estimated / extrapolated.
466
-------
PM Profile Special ion Report
Profile Name Slash Burning (Crane-pi led;f laming phase)
Profile Nunber 42313
Data Quality E
Control Device Not Applicable
Reference(s) 87
Data Source Samples collected 20 meters above slash fire over three
10-minute periods. Analyzed by gas chromatosraphy.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Participate Natter •
Species
CAS Number
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
Mum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Hi
Cu
Zn
Br
A3
Cd
Sn
Pb
OC
EC
0-2
%wt
0.025
0.016
0.011
0.229
0.196
1.195
0.074
0.001
0.001
0.000
0.019
0.006
0.000
0.001
0.054
0.004
0.005
0.001
0.005
0.007
59.800
2.300
63.950
.5 urn
unc
0.009
0.032
0.004
0.034
0.025
0.215
0.019
0.001
0.001
0.000
0.005
0.004
0.000
0.001
0.020
0.003
0.004
0.002
0.010
0.008
4.186
0.345
2.5-10
%ut
0.025
0.016
0.011
0.229
0.196
1.195
0.074
0.001
0.001
0.000
0.019
0.006
0.000
0.001
0.054
0.004
0.005
0.001
0.005
0.007
59.800
2.300
63.950
umd>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.025
0.016
0.011
0.229
0.196
1.195
0.074
0.001
0.001
0.000
0.019
0.006
0.000
0.001
0.054
0.004
0.005
0.001
0.005
0.007
59.800
2.300
63.950
umd>
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
unc
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
(0-10)
0.990
Total
MeasuredC1>
%wt
0.025
0.016
0.011
0.229
0.196
1.195
0.074
0.001
0.001
0.000
0.019
0.006
0.000
0.001
0.054
0.004
0.005
0.001
0.005
0.007
59.aoo
2.300
63.950
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO Estimated / extrapolated.
467
-------
PH Profile Speciatfon Report
Profile Name Slash Burning (Crane-pi led;srooldering phase)
Profile Number 42314
Data Quality E
Control Device Mot Applicable
Reference(s) 87
Data Source Samples collected 10 meters above slash fire over three
ISO-minute periods. Analyzed by gas chrocnatography.
SCO Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Hass Fraction : 0.900 0.960
Total Particulate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31 -S
7439-91-1
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
Sym
Al
Si
P
S
Cl
K
Ce
Ti
V
Cr
Hn
Fe
Hi
Cu
Zn
Br
Ag
Cd
Sn
Pb
OC
EC
0-2
Xwt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.013
.013
.007
.125
.107
.818
.077
.002
.000
.001
.018
.007
.000
.001
.012
.002
.004
0.004
0
0
60
1
.000
.003
.400
.100
.5 urn
une
0.008
0.012
0.004
0.051
0.046
0.335
0.018
0.001
0.000
0.001
0.006
0.002
0.000
0.001
0.004
0.002
0.005
0.003
0.000
0.002
2.416
0.363
2.5-10
Xwt
0.013
0.013
0.007
0.125
0.107
0.818
0.077
0.002
0.000
0.001
0.018
0,007
0.000
0.001
0.012
0.002
0.004
0.004
0.000
0.003
60.400
1.100
untC1>
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0-10
Xwt
0.013
0.013
0.007
0.125
0.107
0.818
0.077
0.002
0.000
0.001
0.018
0.007
0.000
0.001
0.012
0.002
0.004
0.004
0.000
0.003
60.400
1.100
umC1>
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
Measured^}
Xwt
0.013
0.013
0.007
0.125
0.107
0.818
0.077
0.002
0.000
0.001
0.018
0.007
0.000
0.001
0.012
0.002
0.004
0.004
0.000
0.003
60.400
1.100
une
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 62.714
O> Estimated / extrapolated.
62.714
62.714 62.714
468
-------
PM Profile Speciation Report
Profile Name Slash
Profile Number 42315
Data Quality E
Burning (Chaparral; flaming phase)
Control Device Mot Applicable
Reference(s) 87
Data Source Samples collected 20 meters above slash fire over three
10-minute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Participate Matt
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
er -
0-2.5 urn
Sym %wt
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Br
Ag
Cd
Sn
Pb
OC
EC
0
0
0
Z
4
9
0
0
.261
.699
.209
.297
.323
.896
.581
.015
0.004
0
0
0
0
0
0
0
0
0
0
0
48
9
76
.000
.010
.121
.002
.003
.181
.110
.097
.055
.031
.425
.000
,200
.520
unc
0.227
0.377
0.056
0.850
1.686
3.563
0.308
0.013
0.005
0.000
0.006
0.071
0.001
0.001
0.056
0.057
0.082
0.043
0.024
0.157
3.360
4.784
2.5-10
Sut
0.261
0.699
0.209
2.297
4.323
9.896
0.581
0.015
0.004
0.000
0.010
0,121
0.002
0.003
0.181
0.110
0.097
0.055
0.031
0.425
48.000
9.200
76.520
un{1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Swt
0.261
0.699
0.209
2.297
4.323
9.896
0.581
0.015
0.004
0.000
0.010
0.121
0.002
0.003
0.181
0.110
0.097
0.05S
0.031
0.425
48.000
9.200
76.520
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
Heasuredcn
Xwt
0.261
0.699
0.209
2.297
4.323
9.896
0.581
0.015
0.004
0.000
0.010
0.121
0.002
0.003
0.181
0.110
0.097
0.055
0.031
0.425
48.000
9.200
76.520
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
C1> istimated / extrapolated.
469
-------
PH Profile Speciation Report
Profile Name Slash Burning (Chaparral
Profile Nurtber 42316
Data Quality E
;smolden"ng phase)
Control Device Hot Applicable
Reference(s) 87
Data Source Samples collected 10 meters above slash fire over three
ISO-minute periods. Analyzed by gas chromatogrephy.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2,5) (0-6)
Maes fraction ; 0.900 0.960
Total Particulate
CAS Nunfcer
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
ajjci
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
Hatter
nes
Sym
Al
Si
P
S
Cl
K.
Ca
Ti
V
Cr
Hn
Fe
Hi
Cu
Zn
Er
Ag
Cd
Sn
Pb
OC
EC
*•
0-2
%wt
0
0
0
0
1
3
0
0
0
d
0
0
0
0
0
0
0
0
0
0
63
7
,077
.238
.096
.838
.549
.988
.268
.010
.002
.000
.014
.020
.001
,000
.040
.035
.026
.015
.000
.082
.900
.800
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2,5-10
%wt
0.077
0.238
0.096
0.838
1.549
3.988
0.268
0.010
0.002
0.000
0.014
0.020
0.001
0.000
0.040
0.035
0.026
0.015
0.000
0.082
63.900
7.800
unC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
%wt
0.077
0.238
0.096
0.838
1.549
3.988
0.268
0.010
0.002
0.000
0.014
0.020
0.001
0.000
0.040
0.035
0.026
0.015
0.000
0.082
63.900
7.800
umCl>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
Measurcdc1>
%wt
0.077
0.238
0.096
0.838
1.549
3.988
0.268
0.010
0.002
0.000
0.014
0.020
0.001
0.000
0.040
0.035
0.026
0.015
0.000
0.082
63,900
7.800
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
TOTALS: 78.999
CD Estimated / extrapolated.
78.999
78.999
78.999
470
-------
PM Profile Speciation Report
Profile Name
Profile Nunber
Data Quality
Wood combustion - Las Vegas Valley (1987)
42317
C
Control Device
Reference(s)
Data Source
Hot Applicable .
81,88
Samples collected with two dichotomous samplers. Analyzed
using sequential thermal oxidation and XRF.
SCC Assignments: 006
Mass Fraction Data - Size Interval (im) ;
Mass Fraction ;
Total Participate Natter -
Species
CAS Nunber
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7439-92-1
Nun
13
14
16
17
19
82
200
Sym
Al
Si
S
Cl
K
Pb
TC
0-2.5 urn
Xut
0
0
1
0
0
0
61
.300
.800
.010
.250
.870
.250
.000
unc
0.030
0.080
0.100
0.025
0.100
0.025
10.000
: (0-2.5)
: 1.000
2.5-10 urn
%Ht
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
1.000
0-10 urn
%ut
0.300
0.800
1.010
0.250
0.870
0.250
61.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
1.000
Total
Measured^}
Xwt
0.300
0.800
1.010
0.250
0.870
0.250
61.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 64.480 0.000 64.480
Kssssz:ri=«sffic:E:==ssss==;=:ssss:s:====E==s55==:=sess==:=3!SSS»=:=assas==:sBSSS3:=
<1> Only data In the 0 - 2.5 us range were measured.
64.480
471
-------
PH Profile Speciation Report
Profile Name
Profile Nunber
Data Quality
Residential wood Combustion
42318
C
Control Device
ReferenceCs)
Data Source
Uncontrolled
62,89
Data taken from Reference 62. For details, consult Reference
89.
SCC Assignments: 006
Hess Fraction Data - Size Interval (um) :
Mass Fraction :
Total Participate Matter -
Species
CAS Number
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-66-6
0-2.5 um
»«,»" "y* %
-------
PM Profile Speciation Report
Residential Wood Combustion Composite
Profile Name
Profile Number
Data Quality
42319
Control Device
Referenced)
Data Source
Uncontrolled
Profile represents a composite of Profiles 42317 and 42318
for the elements AL, S, CL, end K.
SCC Assignments: 006
Mass Fraction Data - Size Interval (un) :
Mass Fraction ;
Total Particulate Matter -
CAS Number
7429-90-5
7704-34-9
7782-50-5
7440-09-7
Hum Sym
13
16
17
19
Al
S
Cl
K
0-2
Swt
0.
0.
0.
0.
161
596
380
865
.5 urn
uncCI}
0.000
0.000
0.000
0.000
: CO-2.5)
: 1.000
2.5-10 un
%ut
0.000
0.000
0.000
0.000
uncC1>
0.000
0.000
0.000
0.000
(0-6)
1.000
0-10 urn
Xut
0.161
0.596
0.380
0.865
unc£1>
0.000
0.000
0.000
0.000
(0-10)
1.000
Total
MeasuredC2>
Xwt
0.161
0.596
0.380
0.865
uncm
0.000
0.000
0.000
0.000
TOTALS:
2.002
0.000
2.002
2.002
£13 Uncertainty not evaluated.
€2} Only data in the 0 - 2.5 un range was measured.
473
-------
PH Profile Speciation Report
Profile Name Composite of
Profile Nutter 42330
Data Quality D
Residential
Wood Burning Sources
Control Device Uncontrolled
Reference(s) 34,35,45
Data Source Developed from profiles 42102, 42201, 42202, and 42303.
SCC Assignments
Mass Fraction Data - Size Interval (um) : (0-2.5) (0-6)
Mass Fraction : 0.980 0.980
Total Paniculate Matter -
Species
CAS Humbor
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Sym
Be
B
f
Ha
Mg
Ai
Si
P
s
Cl
K
Ca
Sc
Ti
V
Cr
Hn
fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
0-2
%Mt
0
0
0
0
0
0
.000
.000
.000
.021
.018
.005
0.000
0
0
0
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
,495
.327
.624
.017
.000
.000
.000
.000
.000
.000
.000
.000
.000
.009
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0.000
0
0
0
,000
.000
.000
.5 um
unc
0.000
0.000
0.000
0.006
0.009
0.000
0.000
0.000
0.009
0.015
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.OOQ
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 um
Xwt
0.000
0.000
0.000
0.021
0.018
0.005
0.000
0.000
0.045
0.127
0.624
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.006
0.009
0.000
0.000
0.000
0.009
0.015
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 um
XWt
0.000
0.000
0.000
0.021
0.018
0.005
0.000
0.000
0.495
0.327
2.624
0,017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.009
0.013
0.001
o.ooo
0.000
0.072
0.054
0.382
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.000
0.000
0.000
0.000
0.000
O.OOQ
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.980
Total
Measured
%Ht
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.409
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0,000
0,000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
474
-------
PM Profile Speciat ion Report - continued (profile 42330)
Total Particulete Matter -
Spesies
CAS Munber
7440-45-1
7439-97-6
7439-92-1
Hum
58
80
82
201
202
203
204
Syro
Ce
Hg
Pb
oc
iC
504
N03
0-2
Xwt
0
0
0
41
15
0
0
.000
.000
.000
.850
.050
.072
.000
.5 urn
unc
0.000
0.000
0.000
8.298
8.494
0.011
0.000
2.5-10 un
Xwt
0.000
0.000
0.000
32.875
13.450
0.072
0.000
unc
0.000
0.000
0.000
8.298
8.494
0.011
0.000
0-10 urn
Xwt
0.000
0.000
0.000
41.850
15.050
0.072
0.000
unc
0.000
0.000
0.000
13.941
12.346
0.021
0.000
Total
Measured
Xwt
0.000
0.000
0.000
21.000
10.250
0.000
0.000
unc
0.000
0.000
0.000
4.610
7.382
0.000
0.000
TOTALS!
60.488
47.263
60.488
31.659
475
-------
476
-------
3.17 AGRICULTURAL FIELD BURNING
The amount of participate emissions from agricultural field burning is
dependent on the amount of refuse burned, the moisture content, and the
relationship between wind direction and direction of fire advancement. A,
headfire is a fire which is started at the upwind side of a field and allowed
to advance in the direction of the wind. A backfire is started at the
downwind side and forced to advance in opposition to the wind. Particulate
emissions are typically greater with headfire burns.
477
-------
PH Profile Special ion Report
Profile Name
Profile Number
Data Quality
: Slash Burning
: 42301
: B/C
Control Device : Not applicable
Reference(s) : 59
Data Source ; Mean and standard deviation values of 8 fine particle slash
burning samples obtained from plune at ground level.
Analyzed by AAS, XRF, 1C, and carbon oxidation. 1 smolder
phase and 5 active burn phase samples.
SCC Assignments: 50300201
Mass Fraction Data - Size Interval (urn) \
Mass Fraction ;
Total Particulate Hatter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
V^JtSlt I GO
Mum Sym
11
12
13
14
15
16
17
19
30
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Na
Hi
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
. CO
Hi
Cy
Zn
Ga
Ge
As
Se
Br
Rb
sr
zr
Ag
Cd
Sn
Sb
CS
Ba
0-2
Xwt
0.067
NA
0.455
0.802
<
0.281
0,016
0.442
0.713
<
0.010
<
<
0.080
0.342
<
<
0.001
0.012
<
<
<
<
0.010
<
<
<
<
<
<
<
<
<
.5 urn
unc
0.149
0.000
0.298
0.633
0.000
0.220
0.041
0.202
0.962
0.000
0.017
0.000
0.000
0.095
0.255
0.000
0.000
0.003
0.012
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
; (0-2.5)
: 0.900
2.5-10 urn
Xwt
0.067
NA
0.455
0.802
<
0.281
0.016
0.442
0.713
<
0.010
<
<
0.080
0.342
<
<
0.001
0.012
<
<
<
<
0.010
<
<
<
<
<
<
<
<
<
unc
0.149
0.000
0.298
0,633
0.000
0.220
0.041
0.202
0.962
0.000
0.017
0.000
0.000
0.095
0.255
0.000
0.000
0.003
0.012
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-63
0.960
0-10 urn
Xwt
0.067
NE
0.455
0.802
NE
0.281
0.016
0.442
0.713
NE
0.010
NE
NE
0.080
0.342
NE
NE
0.001
0.012
NE
NE
NE
NE
0.010
NE
NE
NE
Ni
NE
HE
NE
NE
NE
unc
0.192
0.000
0.392
0.827
0.000
0.287
0.053
0,272
1.244
0.000
0.022
0.000
0.000
0.123
0.334
0.000
0.000
0.004
0.016
0.000
0.000
0.000
0.000
0.013
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
Measured
%Mt
0
0
0
0
0
0
0
0
0
0
0
0
0
.067
NA
.455
.802
<
.281
.016
.442
.713
<
.010
<
<
.080
.342
<
<
.001
.012
<
<
<
<
.010
<
<
<
<
<
<
<
<
<
unc
0.149
0.000
0.298
0.633
0.000
0.220
0.041
0.202
0.962
0.000
0.017
0.000
0.000
0.095
0.255
0.000
0.000
0.003
0.012
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.DOO
0.000
478
-------
PM Profile Speciation Report - continued (profile 42301)
Total Participate Matter
Species
CAS Number Nun Sym
7440-45-1 58
7439-97-6 80
7439-92-1 82
200
201
202
203
204
205
Ce
Hg
Pb
TC
OC
EC
S04
N03
NH4
0-2.5 urn
Xwt
0
80
0
1
0
<
<
.006
.604
NA
NA
.637
.056
.708
unc
0.000
0.000
0.009
6.215
0.000
0.000
0.373
1.248
0.452
2.5-10 urn
Xwt
<
<
0.006
80.604
NA
NA
0.637
1.056
0.708
unc
0.000
0.000
0.009
6.215
0.000
0.000
0.373
1.248
0.452
0-10 urn
Xwt,
NE
NE
0.006
80.604
NE
NE
0.637
1.056
0.708
unc
0.000
0.000
0.012
16.692
0.000
0.000
0.493
1.616
0.595
Total
Measured
Xwt
0
80
0
1
0
<
<
.006
.604
NA
HA
.637
.056
.708
unc
0.000
0.000
0.009
6.215
0.000
0.000
0.373
1.248
0.452
TOTALS; 86.242 86.242 86.242 86.242
479
-------
PH Profile Speciation Report
Profile Name Slash Burning
Profile Nwtoer 42302
Data Quality B/D
Control Device Hot applicable
ReferenceCs) 45
Data Source Analysis of 5 filters from 2 slash burns. Samples taken at
ground level in plune.
SCC Assignments: 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5} (0-6)
Mass Fraction : 0.900 0.960
Total Paniculate
Matter
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-3S-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46- a
ajjm» i e&
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Be
B
F
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Kn
Fe
Co
Ni
CU
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
CO-10)
0.990
Total
0-2
. Xwt
NA
NA
NA
0.096
NA
0.144
0.132
NA
0.132
0.258
0.620
0.868
NA
NA
<
NA
0.280
0.064
NA
<
<
0.022
NA
<
<
<
0.021
NA
<
NA
NA
<
NA
<
' NA
.5
un
unc
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.035
.000
.066
.041
.000
.050
.118
.235
.288
.000
.000
.000
.000'
.120
.042
.000
.000
.000
.016
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
2.5-10 urn
Xwt
NA
NA
NA
NA
NA
0.705
0.930
NA
0.990
0.850
1.250
5.500
NA
0.045
<
0.062
1.450
0.430
NA
<
<
0.052
NA
<
<
<
0.112
NA
<
NA
NA
<
NA
<
NA
unc
0.000
0.000
0.000
0.000
0.000
0.205
0.099
0.000
0.438
1.200
0.212
0.600
0.000
0.064
0.000
0.025
0.212
0.156
0.000
0.000
0.000
0.025
0.000
0.000
0.000
0.000
0.067
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NE
NE
NE
NE
NE
0.195
0.205
NE
0.210
0.312
0.677
1.289
NE
NE
NE
NE
0.386
0.097
NE
NE
NE
0.025
NE
NE
NE
NE
0.029
NE
NE
NE
NE
NE
NE
NE
NE
Unc
0.000
0.000
0.000
0.000
0.000
0.217
0.155
0.000
0.421
1.102
0.339
0.937
0.000
0.000
0.000
0.000
0.292
0.157
0.000
0.000
0.000
0.028
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
•- Xut
NE
NE
NE
NE
NE
0.195
0.205
NE
0.210
0.312
0.677
1.289
NE
NE
NE
NE
0.386
0.097
NE
NE
NE
0.025
NE
Ni
NE
NE
0.029
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4&U
-------
PH Profile Speciation Report - continued (profile 42302}
Total Partieulate Matter -
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS;
SCaSSSS—JSSKBS!
-------
PH Profile Speciatfon Report
Profile Dane
Profile Number
Data Quality
Agricultural Field Burning
42304
C/E
Control Device
Reference(s)
Data Source
Wot applicable
46
Average of 10 aircraft plume sanples taken with * 2-stage
virtual impactor with a Method 5 heated probe. No dilution
air. Analysis by XRF, INNA, 1C, and carbon oxidation.
SCC Assignments: 50300201
Mass Fraction Data - Size Interval
Nass Fraction
Total Particulate
^_n.
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
£tf*KSfc
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28"
29
30
31
32
33
34
35
37
38
40
47
48
50
51
Matter
S1ISS
Sym
Be
B
F
Na
Kg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
2r
Ag
Cd
Sn
Sb
0-2
Xwt
NA
NA
0.320
0.240
'<
0.340
0.300
<
1.500
3.100
5.900
0.400
<
0.005
<
0.005
0.004
0.200
<
<
0.110
<
<
<
<
<
0.030
<
<
<
<
<
<
<
.5
(urn) ;
4
urn
: <0
: 0
-2.5)
.900
2.5-10 urn
unc Xwt
0
0
0
0
0
0
0
0
0
2
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.150
.340
,000
.300
.200
.000
.700
.000
.500
.300
.000
.005
.000
.007
.005
.600
.000
.000
.400
.000
.000
.000
.000
.000
.040
.000
.000
.000
.000
.000
,000
.000
NA
NA
0.320
0.240
<
0.340
0.300
<
1.500
3.100
5.900
0.400
<•
0.005
<
0.005
0.004
0.200
<
<
0.110
<
<
<
<
<
0.030
<
<
<
<
<
<
<
unc
0.000
0.000
0.150
0.340
0.000
0.300
0.200
0.000
0.700
2.000
2.500
0.300
0.000
0.005
0.000
0.007
0.005
0.600
0.000
0.000
0.400
o.ooo
0.000
0.000
0.000
0.000
0.040
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.960
0-10 urn
Xwt
NE
NE
0.320
0.240
NE
0.340
0.300
NE
1.500
3.100
5.900
0.400
NE
0.005
NE
0.005
0.004
0.200
NE
NE
0.110
NE
NE
NE
NE
NE
0.030
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.201
0.439
0.000
0.391
0.263
0.000
0.940
2.632
3.388
0.392
0.000
0.006
0.000
0.009
0.006
0.772
0.000
0.000
0.515
0,000
0.000
0.000
0.000
0.000
0.052
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
Measured
Xwt
NE
NE
0.320
0.240
NE
0.340
0.300
NE
1.500
3.100
5.900
0.400
NE
0.005
NE
0.005
0.004
0.200
Ni
NE
0.110
NE
NE
NE
NE
NE
0.030
NE
NE
NE
• NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
482
-------
PM Profile Speciat ion Report - continued (profile 42304)
Total Participate Hatter -
CAS Number
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Nun Sym
55
56
58
80
82
201
202
203
204
Cs
Ba
Ce
Hg
Pb
OC
EC
S04
N03
0-2.5 urn
%Wt
0
35
5
5
0
<
<'
<
<
.030
.600
.800
.000
.890
unc
0.000
0.000
0.000
0.000
0.040
10.750
1.740
4.300
0.900
2.5-10 un
Xwt
<
<
<
<
0.030
35.600
5.800
5.000
0.890
unc
0.000
0.000
0.000
0.000
0.040
10.750
1.740
4.300
0.900
0-10 urn
Xut
NE
m
NE
NE
0.030
35.600
5.800
JS.OOO
0.890
unc
0.000
0.000
0.000
0.000
0.052
0.000
2.473
5.603
1.168
Total
Measured
Xwt
NE
NE
NE
NE
0.030
35.600
5.800
5.000
0.890
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 59.774 59.774 59.774 59.774
483
-------
PH Profile Specietion Report
Profile Name Field Burning - Composite
Profile Nunber 42320
Data Quality D
Control Device Hot applicable
Reference(s) 46,45,59
Data Source Developed from profiles 42301, 42302, and 42304.
SCC Assignments 50300201
Mass Fraction Data - Size Interval : (0-2.5) (0-6)
Mass Fraction : 0,900 0.960
Total Participate Matter
Species
CAS Hunter
7440-41-?
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Sytn
Be
B
F
Na
Kg
Al
Si
P
S
Cl
K
**••
sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
2n
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ea
0-2
Xwt
0.000
0.000
0.10?
0.134
0.000
0.313
0.411
0.000
0.638
1.125
2.321
0.660
0.000
0.005
0.000
0.002
0.121
0.202
0.000
0.000
0,037
0.011
0.000
0.000
0.000
0.000
0.020
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0,000
0.000
.5 un
unc
0.000
0.000
0.087
0.215
0.000
0.247
0.3S4
0.000
0.425
1.157
1.454
0.605
0.000
0.010
0.000
0.004
0.088
0.377
0.000
0.000
0.231
0.012
0.000
0.000
0.000
0.000
0.024
0.000
0.000
"o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
%ut
0
0
0
0
0
.000
.000
.107
.102
.000
0.500
0
0
0
1
2
2
0
0
0
0
0
0
0
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
0
0
,677
,000
.924
.322
.531
,204
.000
.020
.000
.022
.511
.324
.000
.000
.037
.021
.000
.000
.000
.000
.051
.000
.000
.000
.000
.000
.000
.000
.000
.000
unc
0.000
0.000
0.087
0.214
0.000
0.271
0.388
0.000
0.493
1,347
1.453
0.677
0.000
0.038
0.000
0.015
0.134
0,387
0.000
0.000
0.231
0.016
0.000
0.000
0.000
0.000
0,045
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 un
%Mt
0.000
0.000
0.107
0.131
0.000
0.330
0.436
0.000
0.664
1.143
2.340
0.801
0.000
0.006
0.000
0.004
0.157
0.213
0.000
0.000
0.037
0.012
0.000
0.000
0.000
0.000
0.023
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.113
0.277
0.000
0.342
0.506
0.000
0.609
1.629
1.921
0.877
0.000
0.036
0.000
0.014
0.161
0.494
0.000
0.000
0.297
0.018
0.000
0.000
0.000
0.000
0.047
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-10)
0.990
Total
Measured
%Mt
0.000
0.000
0.000
0.022
0.000
0.152
0.267
o.ooo
0.094
0.005
0.147
0.238
0.000
0.003
0.000
0.000
0.027
0.114
0.000
0,000
0.000
0.004
0.000
0.000
0.000
0.000
0.003
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.086
0.000
0.172
0.365
0.000
0,127
0.024
0.117
0,555
0.000
0,010
0.000
0.000
0.055
0.147
0.000
0.000
0.002
0.007
0.000
0.000
0.000
0.000
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
484
-------
Ptt Profile Specfatfon Report - continued (profile 42320)
Total Particulate Matter -
Species
CAS Number
7440-45-1
7439-97-6
7439-92-1
Hum
58
80
82
200
201
202
203
204
205
Sym
Ce
Hg
Pb
TC
OC
EC
S04
N03
NH4
0-2
Xwt
0
0
0
26
31
5
1
0
0
.000
.000
.012
.868
.617
.183
.988
.649
.309
.5 urn
unc
0.000
0.000
0.024
3.588
8.700
2.303
2.492
0.888
0.265
2.5-10 un
%wt
0.000
0.000
0.012
26.868
31.533
5.267
1.922
0.649
O.S69
unc
0.000
0.000
0.024
3.588
8.477
2.002
2.494
0.888
0.415
0-10 URI
%ut
0.000
0.000
0.012
26.868
31 .609
5.191
1.982
0.649
0.333
unc
0.000
0.000
0.031
6.719
12.446
2.933
3.225
1.148
0.456
Total
Measured
Xwt
0.000
0.000
0.002
26.868
0.000
0.000
0.212
0.352
0.236
unc
0.000
0.000
0.005
3.588
0.000
0.000
0.215
0.721
0.261
TOTALS:
72.733
76.173
73.048
28.746
485
-------
486
-------
3.18 MOBILE SOURCES
Because of their widespread use, the internal combustion gasoline
powered engine in mobile applications is a major source of PM emissions.
Automotive PM emissions typically consist of exhaust emissions that occur from
the tailpipe.
487
-------
488
-------
PH Profile Speciation Report
Profile Name Light Duty Vehicles-Leaded
Profile Number 31101
Data Quality C/D
Control Device Uncontrolled
Reference(s) 22
Data Source Assumes 2g Pb/gal fuel and 30% of fuel Pb is emitted as
particles <9um. S04 based on .05% S in fuel and emission
factor estimates. CASS profile No. 54.
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.450 0.580
Total Particulate
Hatter
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
apcw i ca
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Be
B
F
Ne
MS
At
Si
P
S
ct
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ge
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
(0-10)
0.640
Total
0-2
%ut
NA
NA
NA
NA
NA
0.043
0.075
NR
NR
5.400
NR
NR
NR
• NR
NR
NR
NR
0.250
NR
NR
0.004
0.021
NR
NR
NR
NR
8.200
NR
NR
NR
NR
NR
NR
NR
NR
. NR
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
%wt
NA
NA
NA
NA
NA
0.043
0.075
NR
NR
5.400
NR
NR
NR
NR
NR
NR
NR
0.250
NR
NR
0.004
0.021
NR
NR
NR
NR
8.200
NR
NR
NR
NR
NR
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NE
NE
NE
NE
NE
0.043
0.075
NE
NE
5.400
NE
NE
NE
NE
NE
NE
NE
0.250
NE
NE
0.004
0.021
NE
NE
NE
NE
8.200
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xwt
NE
NE
NE
NE
NE
0.043
0.075
NE
NE
5.400
NE
NE
NE
NE
NE
NE
NE
0.250
NE
NE
0.004
0.021
NE
NE
NE
NE
8.200
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
489
-------
PK Profile Special ion Report - continued (profile 31101)
Total Partieulate Hatter
Species
CAS Humber
7440-45-1
7439-97-6
7439-92-1
Num
58
80
82
201
202
203
204
Sym
Ce
H§
Pb
OC
EC
S04
N03
0-2
*wt
NR
NR
21.100
50.100
NA
0.210
NA
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
NR
NR
21.100
50.100
NA
0.210
NA
0
0
0
0
0
0
0
urn
unc
.000
.000
.000
.000
.000
.000
.000
0-10 urn
Xwt
NE
NE
21.100
50.100
NE
0.210
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xwt
NE
HE
21.100
50.100
NE
0.210
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS!
85.403
85.403
85.403
85.403
490
-------
PH Profile Spectation Report
Profile Name Heavy Duty Vehicles
Profile Number 31102
Data Quality C/D
- Leaded
Control Device Uncontrolled
Reference(s) 25
Data Source Mean of 4 samples tested on a chassis dynanometer with
dilution tunnel. Analyzed by XRF and organic extraction.
SCC Assignments:
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction ; 0.450 0.580
Total Particulate
Hatter
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
V^^W 1 ICO
Nun Svflt
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Be
B
F
Na
MS
M
Si
p
s
Cl
K
Ca
Sc
Ti
V
Cr
Hr,
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
ir
Rb
sr
Zr
AS
Cd
Sn
Sb
Cs
(0-10)
0.640
Total
0-2.5
UR
%wt unc
NA 0
NA 0
NA 0
NA 0
NA 0
0.140 0
< 0
0.070 0
« 0
3.500 0
< 0
0.120 0
< 0
< 0
< 0
< 0
0.030 0
3.100 0
< 0
• < o
< 0
0.120 0
< 0
< 0
< 0
< 0
13.840 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
2.5-10
Xwt
NA
NA
NA
NA
NA
0.140
<
0.070
-- <
3.500
<
0.120
<
<
<
<
0.030
3.100
<
<
<
0.120
<
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
urn
unc
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0-10 urn
Xwt
NA
NA
NA
NA
NA
0.140
<
0.070
<
3.500
<
0.120
<
<
<
<
0.030
3.100
<
<
<
0.120
<
< 0.000 <
<
<
13.840
<
<
<
<
<
<
<
<
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000,
.000
.000
<
<
13.S40
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.010
0.000
0.492
0.000
0.017
0.000
0.000
0.000
0.000
0.004
0.436
0.000
0.000
0.000
0.017
0.000
0.000
0.000
0.000
1.946
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
%wt
NA
NA
NA
NA
NA
0.140
<
0.070
<
3.500
<
0.120
<
<
<
<
0.030
3.100
<
<
<
0.120
<
<
<
<
13.840
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000,
491
-------
PH Profile Specfation Report - continued (profile 31102)
Total Paniculate Natter -
0-2.5 tin 2.5-10 um 0-10 un
Total
Measured
CAS Number Nun Sym
Xwt
unc
Xwt
unc
Xwt
Xwt
unc
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
affiSS=XSE3!g==
56
58
80
82
201
202
203
204
8a
Ce
HS
Pb
OC
EC
S04
N03
<
<
30.350
NA
NA
NA
NA
51.270
0
0
0
0
0
0
0
0
==sr
.000
.000
.000
.000 30
.000
.000
.000
.000
51
sssssrrss
<
«
.350
NA
NA
NA
NA
.270
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
ssssssscs
;
<
30.350
NA
NA
NA
NA
51.270
SSSSfSSKS
0.000
0.000
0.000
4.268
0.000
0.000
0.000
0.000
SSSSSSSEE
<
<
30.350
NA
NA
NA
NA
51.270
0.000
0,000
0.000
0.000
0.000
0,000
0,000
0,000
492
-------
PM Profile Specietion Report
Profile Name
Profile Number
Data Quality
Light Duty Vehicles - Leaded
31103
C
Control Device
Reference(s)
Date Source
Wot Applicable
62
Vehicle exhaust gases sampled with a dilution sampler and
constant volune sampling system. Analyzed using XRF and
flame ionization.
SCC Assignments: 035, 036, 037, 038
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Hatter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439' 89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
se
Sr
Rb
Sr
Y
Zr
Mo
Pd
AS
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
%Mt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
21
.642
.786
.167
.000
.262
.051
.092
,004
.002
.001
.987
.111
.012
.026
.148
.031
.009
.000
.183
.005
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.002
.649
.5 urn
unc
0.642
0.460
0.180
1.208
0.262
0.025
0.029
0.002
0.002
0.002
0.612
0.045
0.005
0.006
0.040
0.041
0.698
0.006
2.113
0.046
0.005
0.041
0.022
0.011
0.012
0.015
0.020
0.024
0.029
0.064
0.120
0.220
0.005
7.650
: (0-2.5)
: 0.450
2.5-10 urn
%wt
0.342
0.282
0.122
0.000
0.000
0.013
0.295
0.017
0.004
0.033
1.205
0.849
0.026
0.039
0.392
0.005
0.000
0.007
6.147
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
30.631
yne
0.699
0.201
0.122
2.164
0.336
0.024
0.151
0.021
0.008
0.011
0.304
0.230
0.007
0.008
0.085
0.075
1.262
0.011
2.212
0.087
0.008
0.083
0.028
0.010
0.023
0.014
0.046
0.022
0.040
0.055
0.103
0.190
0.008
6.884
(0-6)
0.580
0-10 urn
%ut
0.599
0.720
0.168
0.000
0.238
0.045
0.107
0.004
0.002
0.006
0.956
0.198
0.013
0.028
0.181
0.024
0.009
0.003
6.021
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
23.122
unc
0.744
0.375
0.165
2.004
0.338
0.028
0.134
0.019
0.008
0.014
0.520
0.211
0.012
0.014
0.090
0.069
1.166
0.011
2.496
0.080
0.007
0.076
0.028
0.011
0.021
0.015
0.041
0.025
0.039
0.065
0.120
0.222
0.010
8.463
(0-10)
0.640
Total
MeasuredCI >
Xut
0.599
0.720
0.168
0.000
0.238
0.045
0.107
0.004
0.002
0.006
0.956
0.198
0.013
0.028
0.181
0.024
0.009
0.003
6.021
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
23.122
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
493
-------
PH ProfUt Specfatfon Report - continued {profile 31103)
Total Partfculate Hatter -
Total
0-2.5 un 2.5-10 urn 0-10 urn MeasuredCO
Species
CAS Nunber Nun Sym Xwt unc %ut unc Xwt unc Xut unc
201 OC 31.374 19.838 3.768 3.309 28.900 14.563 28.900 0.000
202 ec 15.053 2.434 7.220 5.538 12.736 5.198 12.736 0.000
TOTALS: 77.597 51.411 74.088 74.088
lassffisssssSBBSZSSsssasssxKssSBSsSKSBSsKssssBSffiSKSBSsssBESBssssssrssscrssaKSjssssssaKffisrss:
<1> Estimated / extrapolated.
494
-------
PH Profile Spec)at ion Report
Profile Nane
Profile Number
Data Quality •
Light Duty Vehicles • Leaded
31104
C
I'..--' ..:-•....V.F..JS?...
Control Device
Reference(s)
Data Source
Mot Applicable
62
Vehicle .exhaust gases sampled with a dilution sampler and
constant volume sampling system. Analyzed using XRF and
flame ionization.
SCC Assignments: 035, 036, 037, 038
Hass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Paniculate Hatter
Species
CAS Number Hum Sym
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ge
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
sb
Ba
La
Hg
Pb
"
0-2
Xut
0
1
0
0
0
0
0
0
0
0
f
0
0
0
0
0
0
0
10
0
0
0
0
0
0
0
0
0
0
0
0
0
0
17
.670
.588
.435
.022
.051
.133
.102
.003
.004
.001
.345
.020
.014
.031
.109
.038
.182
,000
.365
.000
.000
.001
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.001
.992
.5 urn
unc
1.146
0.641
0.135
0.908
0.155
0.057
0.058
0.009
0.007
0.007
0.878
0.025
0.007
0.009
0.015
0.032
0.505
0.008
1.186
0.068
0.013
0.035
0.072
0.042
0.044
0.058
0.076
0.094
0.115
0.253
0.476
0.863
0.010
1.886
; CO-2.5)
: 0.450
2.5-10 urn
Xut
0.693
0.199
0.070
0.000
0.058
0.028
0.149
0.008
0.007
0.034
0.303
0.065
0.020
0.011
0.084
0.005
0.000
0.005
1.429
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,016
3.706
unc
1.172
0.191
0.165
1.439
0.234
0.023
0.175
0.061
0.025
0.020
0.189
0.064
0.018
0.011
0.078
0.050
0.829
0.009
1.187
0.088
0.010
0.051
0.048
0.028
0.028
0.037
0.048
0.060
0.073
0.160
0.302
0.548
0.017
2.979
CO-6)
0.580
0-10 urn
Xwt
0.492
1.335
0.374
0.016
0.062
0.112
0.103
0.003
0.004
0.007
1.169
0.023
0.014
0.027
0.098
0.031
0.133
0.001
8.445
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
15.056
unc
1.274
0.504
0.174
1.365
0.225
0.047
0.154
0.052
0.022
0.020
0.653.
0.059
0.018
0,013
0.070
0.048
0.780
0.010
1.663
0.087
0.012
0.050
0.065
0.038
0.039
0.051
0.067
0.083
0.101
0.223
0.420
0.764
0.017
3.358
<0-10>
0.640
Total
MeasuredCI)
Xwt
0.492
1.335
0.374
0.016
0.062
0.112
0.103
0.003
0.004
0.007
1.169
0.023
0.014
0.027
0.098
0.031
0.133
0.001
8.445
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
15.056
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
495
-------
PM Profile Speeiatfon Report - continued Cprofile 31104)
Total Partfculate Matter -
Total
0-2.5 un 2.5-10 tin 0-10 un Measuredd}
Species - -—........ ............ ............ .... ...
CAS Htnfcer Hun Eyir, Swt une Xwt unc Xwt unc Xut unc
201 OC 51.847 4.424 13.791 12.36S 4S.9S8 12.029 48.988 0.000
202 EC 1.322 1.030 1.429 2.259 1.297 2.036 1.297 0.000
TOTALS: B6.276 22,110 77.794 77.794
SSSSEESESffiKSSS==22«S=S==SSSSSEeBBS=SSgieSS=CKSffi3SSSSKSS=SffiaSS===SSaSSS=-="=SSKSSS====S:SS:S
C1> Estimated / extrapolated.
496
-------
PH Profile Speciatfon Report
Profile Name Light Duty Vehicles - Leaded Composite
Profile Number 31105
Data Quality C
Control Device Mot Applicable
Reference(s)
Data Source Profile represents
SCC Assignments 035, 036,
Mass Fraction
Data
- Size
Mass
a composite of Profiles 31103 and 31104.
037, 038
Interval
(un)
;
Fraction ;
CO
-2.5}
0.450
CO-6J
0.580
(0-10)
0.640
Total ParticuUte Matter -
Total
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
202
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cy
Zn
Ga
As
Se
Br
Rb
Sr
Y
Er
No
Pd
Ag
Cd
In
sn
Sb
Ba
La
Hg
Pb
OC
EC
. 0-2.
5 un
%wt uncC1>
0.656
1,187
0.301
0.011
0.157
0.092
0.097
0.004
0.003
0.001
1.166
0.066
0.013
0.029
0.129
0.035
0.096
0.000
8.274
0.003
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0,000
0.000
0.002
19.821
41.611
8.188
81 .943
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-
Xwt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
17
8
4
36
.518
.241
.096
.000
.029
.021
.222
.013
.006
.034
.754
.457
.023
.025
.238
.005
.000
.006
.788
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.015
.169
.780
.325
.765
10 un
uneCI}
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 un
Xut
0.546
1.028
0.271
0.008
0.150
0.079
0.105
0.004
0.003
0.007
1.063
0.111
0.014
0.028
0.140
0.028
0.071
0.002
7.233
0.003
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
19.089
38.944
7.017
75.948
uned>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xwt
0.546
1.028
0.271
0.008
0.150
0.079
0.105
0.004
0.003
0.007
1.063
0.111
0.014
0.028
0.140
0.028
0.071
0.002
7.233
0.003
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
, 0.000
0.000
0.000
0.003
19.089
38.944
7.017
75.948
uncm
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{1} Uncertainty not evaluated.
497
-------
PH Profile Spec?ation Report
Profile Name Light Duty Vehicles * Unleaded
Profile Mumber 31201
Data Quality C/D
Control Device Uncontrolled
Reference(s) 22
Data Source CASS Profile No. 53
Mass Fraction Data - Size Interval
Mass Fraction
Total Paniculate Natter
Species
CAS timber
7440-41-7
7440-42-8
7783-41-4
7440-23-5
7439-95-4
7429-90-S
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440- 09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
";40-67-7
M40-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
80
Sym
Be
B
F
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
fia
Ce
Hg
0-2.5
Xut
NA
NA
NA
NA
NA
0.120
0.510
NR
NR
NR
0.044
0.170
NR
NR
NR
NR
0.015
0.110
NR
0.015
0.024
0.080
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
(urn)
urn
unc
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
: (0-2.5)
: 0.890
2.5-10 un
Xut
NA
NA
NA
NA
NA
0.120
0.510
NR
NR
NR
0.044
0.170
NR
NR
NR
NR
0.015
0.110
NR
0.015
0.024
0.080
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.930
0-10 urn
Xwt
Ni
NE
NE
NE
NE
0.120
0.110
NE
NE
NE
0.044
0.170
NE
NE
NE
NE
0.015
0.110
NE
0.015
0.024
0.080
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
Ni
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.970
Total
Measured
%wt
NE
NE
NE
NE
NE
0.120
0.510
NE
NE
NE
0.044
0.170
NE
NE
NE
NE
0.015
0.110
NE
0.015
0.024
0.080
NE
NE
NE
NE
NE
NE
NE
NE
•NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
498
-------
PH Profile Special ion Report - continued (profile 31201)
Total Partieulatt Matter -
Total
CAS Nurber
7439-92-1
Num Sym
82
201
202
203
204
Pb
oc
iC
$04
N03
0-2
Xut
* m
21.100
17.800
50.000
NR
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
2.5-10
%ut
NR
21.100
17.800
50.000
NR
urn
unc
0
0
0
0
0
.000
.000
.000
.000
.000
0-10 urn
Xwt
NE
21.100
17.800
50.000
NE
unc
0.000
0.000
0.000
0.000
0.000
Measured
%yt
NE
21.100
17.800
50.000
NE
unc
0.000
0.000
0.000
0.000
0.000
TOTALS: 89.988 89.988 89.988 89.988
===K== — eK=s = — _ = _E~S__=—==s=_=——=gS___=s==____=s = = _—_c===_—=—S—Se=—— ——«_—_——^^——...^j;.—— —
499
-------
PH Profile Speciation Report
Profile Home
Profile Number
Data Quality
Light Duty Vehicles - Unleaded
31202
C
Control Device
Reference(s)
Data Source
Hot Applicable
62
Vehicle exhaust fases sampled with a dilution sampler and
constant volume sampling system. Analyzed using XRF and
flame ionization.
SCC Assignments: 027, 028, 029, 030
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Partieulate Matter
Species
CAS Number Hum Sym
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Sf
P
s
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Hi
Gu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Kg
Pb
"
0-2
Xwt
0
3
0
3
0
0
0
0
0
0
0
0
0
0
.699
.427
.441
.255
.066
.011
.526
.004
.022
.005
.004
.421
.000
.031
0.592
0
, 0
0
0
0
.001
.000
.000
.249
.000
0.000
0
0
0
0
0
: o
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.001
.364
.5 urn
unc
0.281
1.755
0.164
2.025
0.034
0.008
0.141
0.002
0.011
0.004
0.003
0.124
0.000
0.024
0.263
0.001
0.000
0.000
0.114
0.000
O.OQO
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.138
: (0-2.5)
: 0.890
2.5-10 ura
Xwt
1.129
0.856
0.305
0.534
0.068
0.037
0.448
0.019
0.006
0.037
0.053
1.178
0.020
0.028
0.485
0.002
0.000
0.007
0.109
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
1.139
unc
0.375
0.350
0.088
0.223
0.031
0.011
0.137
0.006
0.003
0.009
0.013
0.309
0.005
0.007
0.149
0.003
0.035
0.003
0.040
0.004
0.004
0.005
0.021
0.013
0.013
0.017
0.022
0.029
0.035
0.077
0.143
0.262
0.003
0.354
(0-6)
0.930
0-10 urn
Xwt
0.815
2.793
0.373
2.830
0.071
0.020
0.479
0.007
0.017
0.013
0.016
0.583
0.005
0.026
0.509
0.001
0.000
0.002
0.200
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.002
0.558
unc
0.473
1.708
0.191
1.919
0.050
0.022
0.210
0.014
0.013
0.020
0.025
0.353
0.014
0.028
0.300
0.005
0.033
0.008
0.120
0.003
0.004
0.005
0.020
0.012
0.013
0.017
0.021
0.027
0.033
0.073
0.136
0.251
0.007
0.391
(0-10)
0.970
Total
Keasuredcn
Xut
0.815
2.793
0.373
2,830
0.071
0.020
0.479
0.007
0.017
0.013
0.016
0.583
0.005
0.026
0.509
0.001
0.000
0.002
0.200
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.558
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5UU
-------
PM Profile Speciation Report - continued (profile 31202)
Total Participate Natter -
Total
0-2.5 urn 2.5-10 un 0-10 urn HeasuredC1>
Species •
CAS Number Nun Sym Xwt unc Xwt unc Xwt unc Xwt unc
201 OC 49,202 9.893 22.208 8.891 41.33114.143 41.331 0.000
202 i.C 38.630 8.106 4.993 3.133 30.076 9.471 30.076 0.000
TOTALS: 97.951 33.666 80.727 80.727
SSSSSSCS&SSESSSSSSeSSSSSSCSSSSSSSSSSSSXSSSSSSSSSSSSSSESSSSSSSSSSSSSSEeSSXSZSSESSSSSSSSSiS^
{1} Estimated / extrapolated.
501
-------
PH Profile Special ion Report
Profile Name ; Light Duty Vehicles » Unleaded
Profile Number : 31203
Data Quality : C
.Control Device ; Hot Applicable
Reference(s) : 62
Data Source : Vehicle exhaust gases sampled with a dilution sampler and
constant volume sampling system. Analyzed using XRF and
flame ionization.
SCC Assignments! 027, 028, 029, 030
Mass Fraction Data - Size Interval (urn) :
Mass Fraction ;
Total Participate Matter -
CAS Nunber
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
op^i* ica
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
3&
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
At
Si
P
S
Cl
K
Ca
Ti
V
Cf
Hn
Fe
Mi
Cu
Zn
Ga
As
?
-------
PH Profile Special ion Report - continued (profile 31203)
Total Participate Matter -
Total
0-2.5 um 2.5-10 m 0-10 m Measured£1>
Species • •—
CAS Nunber Nun Sym Xut unc Xwt unc Xut unc Xut unc
201 OC 92.90? 51.738 29.259 25.589 66,193 54.837 66.193 0.000
202 EC 4.833 6.801 0.000 6.483 2.762 8.826 2.762 0.000
TOTALS: 110.532 32.337 78.945 78.945
=:£sexssi=saaK5£:=ssss8ec£ass=a==sc:sss£=x»ss=s=SASsss:=ssss==:=SBSBS£:=sssss^:£sasB=s:==a&s=s
C1> Estimated / extrapolated.
503
-------
PM Profile Speeistion Report.
Profile Name Light Duty Vehicles - Composite
Profile timber 31230
Data Quality D
Control Device Uncontrolled
Reference(s) 22
Data Source Developed from profiles 31101 and 31201
SCC Assignments
Mass Fraction Data - Size Interval (un) : (0-2.5)
Mass Fraction : 0.670
Total Particulate Matter
Species
CAS Munber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Sym
Be
B
F
Ha
Hg
Al
Si
P
S
Cl
tc
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
•
0-2
Xwt
0.
0.
o".
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
' 0.
0.
0.
0.
0.
0.
0.
0.
0.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
000
000
000
000
054
195
000
000
800
015
057
000
000
000
000
005
120
000
005
009
034
000
000
000
000
733
000
000
000
000
000
000
000
000
000
.5 un
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-
Xwt
0.000
0.000
0.000
0.000
0.000
0.054
0.195
0.000
0.000
1.800
0.015
0.057
0.000
0.000
0.000
0.000
0.005
0.120
0.000
0.005
0.009
0.034
0.000
0.000
0.000
0.000
2.733
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
10 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
i
CO-6)
0.750
0-10 urn
%wt
0.000
0.000
0.000
0.000
0.000
0.054
0.195
0.000
0.000
1.800
0.015
0.057
0.000
0.000
0.000
0.000
0.005
0.1HO
0.000
0.005
0.009
0.034
0.000
0.000
0.000
0.000
2.733
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.009
0.033
0.000
0.000
0.301
0.002
0.009
0.000
0.000
0.000
0.000
0.001
0.020
0.000
0.001
0.002
0.006
0.000
0.000
0.000
0.000
0.458
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-10)
0.800
Total
Measured
Xwt
0.000
0.000
0.000
0.000
0.000
0.047
0.000
0.023
0.000
1.167
0.000
0.040
0.000
0.000
0.000
0.000
0.010
1.033
0.000
0.000
0.000
0.040
0.000
0.000
0.000
0.000
4.613
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
504
-------
PM Profile Specfation Report • continued (profile 31230)
Total Paniculate Natter -
CAS Nunfcer
7440-45-1
7439-97-6
7439-92-1
TOTALS:
Hum Sym
58
80
82
201
202
203
204
Ce
Hg
Pb
OC
EC
S04
N03
0-2.5 urn
.%Mt
0.000
0.000
7.033
23.733
5.933
16.737
0.000
58.463
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xut
0
0
7
23
5
.000
.000
.033
.733
.933
16.737
0
58
.000
.463
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xut
0.000
0.000
7.033
23.733
5.933
16.737
0.000
58.463
unc
0.000
0.000
1.178
3.975
0.994
2.803
0.000
Total
Measured
Xut
0.000
0.000
10.117
0.000
0.000
0.000
0.000
17.090
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
505
-------
PM Profile Specialion Report
Profile Name Light Duty Vehicles - Diesel
Profile Nunber 32101
Data Quality C/D
Control Device Uncontrolled
Reference(s) 20
Data Source Based on 4-stroke engine
0.81% S content
SCC Assignments; 111
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Natter
CAS Nunber
7440-41-7
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-E
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
ape*, i c»
Nun Sym
4
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Be
F
Na
MB
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
0-2.5 urn
%wt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
0.110 0.000
< 0.000
0.032 0.000
0.700 0.000
< 0.000
< 0.000
0.120 0.000
< 0.000
f 0.000
< 0.000
< 0.000
0.250 0.000
0.330 0.000
< 0.000
< 0.000
< 0.000
0.067 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
• < o.ooo
< 0.000
< 0.000
< 0.000
< 0.000
burning No. 2 diesel fuel of
(0-2.5) (0-6)
0.920 0.960
2.5-10 urn
Xwt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
0.110 0.000
< 0.000
0.032 0.000
0.700 0.000
< 0.000
< 0.000
0.120 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.250 0.000
0.330 0.000
< 0.000
< 0.000
< 0.000
0.067 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< O.OOD
< 0.000
0-10 urn
Xwt
NE
NE
NE
NE
0.110
NE
0.032
0.700
NE
NE
0.120
NE
NE
NE
NE
0.250
0.330
NE
NE
NE
0.067
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
1.000
Total
Measured
%wt unc
NA 0.000
NA 0.000
NA 0.000
NA 0.000
0.110 0.000,
< 0.000
0.032 0.000
0.700 0.000
< 0.000
< 0.000
0.120 0.000
< 0.000
< 0.000
< 0.000
< 0.000
0.250 0.000
0.330 0.000
< 0.000
< 0.000
< 0.000
0.067 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
506
-------
PH Profile Speciation Report - continued (profile 32101}
Total Participate
Natter
Total
CAS Nunber
7440-45-1
7439-97-6
7439-92-1
Hum Sym
58
80
82
200
201
202
203
204
Cc
Hg
Pb
TC
OC
EC
S04
N03
0-2
%wt
0
73
21
51
2
<
<
.420
.000
.900
.100
.100
NA
.5 urn
unc
0.000
0.000
0.000
5.700
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
<
<
0.420
73.000
21.900
51.000
2.100
NA
unc
0.000
0.000
0.000
5.700
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NE
NE
0.420
73.000
21.900
51.092
2.100
NE
unc
0.000
0.000
0.000
15.343
0.000
0.000
0.000
0.000
Measured
Xwt
<
<
0.420
73.000
21.900
51.000
2.100
NA
unc
0.000
0.000
0.000
5.700
0.000
0.000
0,000
0,000
TOTALS: 150.129 150.029 150.121 150.029
507
-------
PH Profile Specletion Report
Profile Name Light Duty Vehicles - Diesel
Profile Number 32102
Data Quality C
Control Device Not Applicable
Reference(s) 62
Data Source Vehicle exhaust gases sampled with • dilution sampler and
constant volume sampling system. Analyzed using XRF and
flame ionizaticn.
SCC Assignments: 111
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Kass Fraction : 0.920 0.960
Total Particulate
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
sipci
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
18
39
40
42
46
47
48
49
50
51
56
57
80
82
Hatter
sies
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
HP.
Fe
Ni
Cu
Zn
Ga
te
St
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Co-
in
Sn
Sb
Ba
La
Hg
Pb
0-2
%wt
0.007
0.202
0.026
0.589
0.025
0.005
0.021
0.000
. 0.000
0.000
0.000
0.016
0.000
0.001
0.047
0.000
0.002
0.000
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
.5 urn
unc'
0.004
0.177
0.015
0.168
0.014
0.002
0.014
0.000
0.000
0.000
0.000
0.006
0.000
0.000
0.027
0.000
0.001
0.000
0.001
0.000
0.000
0.000
0.002
0.001
0.001
0.002
0.002
0.003
0.003
0.007
0.013
0.025
0.000
0.013
2.5-10 urn
Xut
0.224
0.444
0.191
1.002
0.176
0.037
0.071
0.014
0.006
0.015
0.021
0.381
0.008
0.008
0.118
0.000
0.000
0.008
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,002
0.143
unc
0.101
0.106
0.064
0.270
0.018
0.016
0.023
0.023
0.009
0.007
0.005
0.130
0.003
0.002
0.068
0.001
0.006
0.003
0.008
0.003
0.003
0.004
0.018
0.012
0.011
0.014
0.019
0.024
0.029
0.064
0.121
0.222
0.002
0.041
0-10 urn
%wt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.023
.217
.038
.617
.034
.007
.025
.001
.001
.001
,002
.035
.001
.002
.053
.000
.001
,001
.006
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.025
unc
0.109
0.207
0.077
0.337
0.047
0.024
0.036
0.025
0.011
0.013
0.014
0.142
0.009
0.009
0.078
0.002
0.006
0.009
0.014
0.003
0.003
0.004
0.017
0.011
0.011
0.014
0.018
0.023
0.028
0.061
0.116
0.214
0.005
0.055
(0-10)
1.000
Total
MeasuredC1>
Xut
0.023
0.217
0.038
0.617
0.034
0.007
0.025
0.001
0.001
0.001
0.002
0.035
0.001
0.002
0.053
0.000
0.001
0.001
0.006
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
508
-------
PH Profile Specialion Report - continued (profile 32102}
Total Participate Natter -
Total
0-2.5 urn 2.5-10 urn 0-10 urn MeasuredC1>
Species —......... ... ....
CAS Number Nun Sym Xut • unc %ut unc Xut unc Xut unc
201 OC 23.635 5.490 38.903 3.484 24.994 7.699 24.994 0.000
202 EC 65.862 12.971 74.030 6.857 67.384 17.496 67.384 0.000
TOTALS: 90.459 115.819 93.468 93.468
~sa:sss=ssssssass:sss~ss2ssss™s2s~assssss=ssssssssssss~s:ss:sss:esssss=s:ssssas:=s:
Cl> Estimated / extrapolated.
509
-------
PH Profile Special ion Report
Profile Name
Profile Nurfcer
Data Quality
light Duty Vehicles - Diesel
32103
c
Control Dtvice
Reference(s)
Data Source
Hot Applicable
62
Vehicle exhaust gases sampled with * dilution sampler and
constant volune sampling system. Analyzed using XRF and
flame ionization.
SCC Assignments: 111
Mass Fraction Data - Size Interval Cum) :
Mass Fraction :
Total Partfeulate Hatter
Species
CAS Number Nun Sym
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
<
Ca
Ti
V
Cr
Hn
Fe
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
in
Sn
Sb
88
La
Hg
Pb
0-2
•Xwt
0.009
0.053
0.026
0.620
0.035
0.013
0.023
0.000
0.000
0.000
0.000
0.002
0.000
0.002
0.037
0.000
0.002
0.000
0.002
0.000
q.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
.5 un
unc
0.007
0.028
0.008
0.239
0.012
0.008
0.014
0.001
0.001
0.001
0.001
0.002
0.001
0.001
0.011
0.001
0.002
0.001
0.001
0.001
0.001
0.002
0.008
0.005
0.005
0.006
o.ooa
0.010
0.012
0.027
0.051
0.094
0.001
0.017
: CO-2.5)
: 0.920
2.5-10 urn
Xwt
0.474
0.780
0.229
0.484
0.427
0.099
0.103
0.034
0.015
0.037
0.051
0.181
0.016
0.028
0.061
0.005
0.000
0.026
0,059
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
0.311
unc
0.248
0.236
0.122
0.187
0.166
0.040
0.037
0.069
0.028
0.009
0.019
0.079
0.008
0.012
0.019
0.006
0.019
0.008
0.019
0.010
0.013
0.016
0.071
0.045
0.045
0.058
0.078
0.097
0.116
0.260
0.489
0.906
0.008
0.092
(0-6)
0.960
0-10 un
Swt
0.040
0.099
0.040
0.612
0.060
0.018
0.028
0.003
0.001
0.002
0.003
0.011
0.001
0.004
0.039
0.001
0.002
0.002
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.042
unc
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.250
.253
.127
.305
.175
.049
.049
.068
.029
.020
.028
.087
.014
.019
.031
.008
.019
.017
.029
.010
.013
.015
.069
.044
.043
.056
.075
.093
.112
.250
.471
.873
.012
.107
(0-10)
1.000
Total
Measured{1>
%Ht
0.040
0.099
0.040
0.612
0.060
0.018
0.028
0.003
0.001
0.002
0.003
0.011
0.001
0.004
0.039
0.001
0.002
0.002
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.042
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.oop
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
510
-------
PH Profile Spcciation Report - continued (profile 32103}
Total Participate Hatter -
Total
0-2.5 m 2,5-10 urn 0-10 on NeasuredC1>
Species • — '
CAS Number Hum Sym %ut one Xwt unc %ut unc %ut unc
201 OC 63,358 2.103 102.175 36.083 47.468 36.367 67.468 0.000
202 EC 62.746 7.051 26.851 8.747 60.160 13.617 60.160 0.000
TOTALS: 106.953 132.456 10S.642 108.642
gssss—aasssgsscassssgggcssssggsss—assssssss—sgssgsgsssaa
<1> Estimated / extrapolated.
511
-------
PH Profile Specfation Report
Profile Name.
Profile Number
Data Quality
Light
32104
C
Duty Vehicles - Diesel Composite
Control Device Mot Applicable
Reference(s)
Data Source Profile represents a composite of Profiles 32102 end 32103.
SCC Assignments 111
HBSS Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.920 0.960
Total Participate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Cvta
spe
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
202
ClftS
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ca
As
Se
Br
Rb
Sr
r
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Kg
Pb
oc
EC
0
0
0
0
0
0
0
' 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Q
0
0
0
0
33
0-2
bt
.008
.128
.026
.605
.030
.009
.022
.000
.000
.000
.000
.009
.000
.002
.042
.000
.002
.000
.004
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.021
.497
64.304
98
.709
.5 urn
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
0.349
0.612
0.210
0.743
0.302
0.068
0.087
0.024
0.011
0.026
0.036
0.281
0.012
0.018
0.090
0.003
0.000
0.017
0.038
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
0.227
70.539
50.441
124.140
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
0.032
0.158
0.039
0.615
0.047
0.013
0.027
0.002
0.006
0.002
0.003
0.023
0.001
0.003
0.046
0.001
0.002
0.002
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.034
36.231
63.772
101.066
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
1.000
Total
Measured
%Mt
0.032
0.158
0.039
0.615
0.047
0.013
0.027
0.002
0.006
0.002
0.003
0.023
0.001
0.003
0.046
0.001
0.002
0.002
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.034
36.231
63.772
101.066
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CU Uncertainty not evaluated.
512
-------
PH Profile Speciation Report
Profile Name Heavy Duty Diesel
Profile Number 32202
Data Quality A/C
Control Device Uncontrolled
ReferenceCs) 41,56
Data Source All 3 size fractions assured similar composition.
SCC Assignments
Mass Fraction Data - Size Interval (urn) : <0-2.5) (0-6)
Mass Fraction : 0.920 0.960
Total Paniculate
r>..u».
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-S
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
ap«»
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
. 28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Matter
-ies
Sym
Be
B
f
Ha
Mg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
"
0-2
%Ht
0
0
0
1
1
0
2
0
0
0
0
0
0
0
0
0
0
0
0
0
NA
.130
<
.800
.900
.000
.600
.150
.700
<
.170
.700
<
.014
<
.002
.039
.600
<
.003
.025
.160
<
<
<
<
.000
<
.014
.004
<
<
<
<
<
.077
.5 urn
unc
0.000
0.020
0.000
0.100
0.150
0.200
0.200
0.020
0.000
0.000
0.030
0.200
0.000
0.004
0.000
0.001
0.004
0.100
0.000
0.001
0.010
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.003
0.001
0.000
0.000
0.000
0.000
0.000
0.003
2.5-10 urn
Xut
NA
0.130
<
0.800
0.900
1.000
1.600
0.150
2.700
<
0.170
0.700
<
0.014
<
0.002
0.039
0.600
<
' 0.003
0.025
0.160
<
<
<
<
0.000
<
0.014
0.004
<
<
<
<
<
0.077
unc
0.000
0.020
0.000
0.100
0.150
0.200
0.200
0.020
0.000
0.000
0.030
0.200
0.000
0.004
0.000
0.001
0.004
0.100
0.000
0.001
0.010
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.003
0.001
0.000
0.000
0.000
0.000
0.000
0.003
0-10 un
%Mt
NE
0.130
NE
0.800
0.900
1,000
1.600
0.150
2.700
NE
0.170
0.700
NE
0.014
NE
0.002
0.039
0.600
NE
0.003
0.025
0.160
NE
NE
NE
NE
0.000
NE
0.014
0.004
NE
NE
NE
NE
NE
0.077
unc
0.000
0.035
0.000
0.196
0.256
0.319
0.393
0.038
0.000
0.000
0.050
0.290
0.000
0.006
0.000
0.001
0.009
0.171
0.000
0.001
0.014
0.032
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.001
0.000
0.000
0.000
0.000
0.000
0.015
(0-10)
1.000
Total
Measured
fcrt
NA
0.130
<
0.800
0.900
1.000
1.600
0.150
2.700
<
0.170
0.700
<
0.014
<
0.002
0.039
0.600
<
0.003
0.025
0.160
<
<
<
<
0.000
<
0.014
0.004
<
<
<
<
<
0.077
unc
0.000
0.020
0.000
0.100
0.15D
0.200
0.200
0.020
0.000
0.000
0.030
0,200
0.000
0.004
0.000
0.001
0.004
0.100
0.000
0.001
0.010
0,010
0.000
0.000
0.000
0.000
0.000
0.000
0.003
0.001
0.000
0.000
0.000
0.000
0.000
0.003
513
-------
PM Profile Speciation Report - continued (profile 32202)
Total Particulate Hatter -
Total
CAS Number
7440-45-1
7439-97-6
7439-92-1
oj^ew tea
Nun Sym
58
80
82
201
202
203
204
Ce
Ha
Pb
OC
EC
S04
N03
0-2
Xut
<
<
1.300
20.900
54.800
4.900
MA
.5 urn
unc
0.000
0.000
0.300
0.000
0.000
0.900
0.000
2.5-10 urn
%ut
<
<
1.300
20.900
54.800
4.900
NA
0
0
0
0
0
0
0
unc
.000
.000
.300
.140
.000
.900
.000
0-10 urn
Xwt
HE
He
1.300
20.900
54.800
4.900
UE
unc
0.000
0.000
0.4S8
0.000
0.000
1.478
0.000
Measured
Xut
<
<
1.300
20.900
54.800
4.900
NA
unc
0.000
0.000
0.300
0.140
0.000
0.900
0.000
TOTALS:
90.988
90.988
90.988
90.988
514
-------
PM Profile Speeiatlon Report
Profile Name
Proffie Number
Data Quality
Heavy Duty Vehicles
32203
C
Diesel
Control Device
Reference(s)
Data Source
Not Applicable
62
Vehicle exhaust gases sampled ttith a dilution sanpler and
constant volume sampling system. Analyzed using XRF and
flame ionization.
SCC Assignments: 040, 041, 042, 043
Mass Fraction Data - Size Interval {urn} :
Mass Fraction :
Total Particulate Matter -
Species
CAS Number
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Num
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37 .
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
p
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
En
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Kg
Pb
0-2
Xwt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.003
.018
.042
.343
.016
.000
.048
.002
.002
.000
.000
.000
.002
.001
.053
.000
0.000
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.009
.000
.000
.000
.000
,000
.000
.000
.000
.5 urn
unc
0.026
0.018
0.009
0.055
0.022
0.010
0.008
0.004
0.003
0.003
0.003
0.008
0.003
0.003
0.017
0.002
0.008
0.003
0.003
0.004
0.005
0.007
0,030
0.018
0.018
0.025
0.032
0.040
0.048
0.109
0.202
0.368
0.003
0.011
i {0-2.5}
; 0.920
2.5-
Xut
1.909
1.417
0.464
0.650
0.622
0.251
0.322
0.061
0.017
0.152
0.112
0.274
0.030
0.059
0.112
0.000
0.000
0.066
0.135
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.023
0.883
10 un
unc
1.598
1.253
0.394
0.782
0.632
0.217
0.246
0.630
0.24S
0.129
0.086
0.282
0.032
0.065
0.109
0.017
0.066
0.051
0.100
0.037
0.048
0.136
0.254
0.166
0.157
0.209
0.278
0.342
0.416
0.933
1.760
3.205
0.033
0.632
(0-6)
0.960
0-10 urn
Xwt
0.137
0.110
0.071
0.347
0.051
0.018
0.069
0.009
0.004
0.011
0.011
0.015
0.004
0.004
0.055
0.000
0.000
0.006
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.008
0.000
0.000
0.000
.0.000
0.000
0.000
0.002
0.081
unc
1.548
1.214
0.386
0.759
0.614
0.214
0.243
0.605
0.238
0.130
0.089
0.276
0.035
0.067
0.111
0.016
0.064
0.055
0.103
0.035
0.046
0.131
0.245
0.160
0.151
0.201
0.269
0.330
0.401
0.900
1.698
3.093
0.035
0.617
(0-10}
1.000
Total
MeasuredC!}
Xwt
0.137
0.110
0.071
0.347
0.051
0.018
0.069
0.009
0,004
0.011
0.011
0.015
0.004
0.004
0.055
0.000
0.000
0,006
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0,081
unc
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
515
-------
PH Profile Speci»tion Report - continued (profile 322033
Total Paniculate Natter -
Total
0-2,5 urn 2.5-10 urn 0-10 urn Measuredd}
Species • ' --
CAS Number Num Sym Xut unc Xwt unc Xut unc %ut ,unc
201 OC 36.046 3.406 67.980 71.384 37.830 68.989 37.830 0.000
202 EC 52.058 4.644 15.840 20.203 50.035 21.021 50.035 0.000
TOTALS: 88.643 91.379 88.890 88.890
*SBaES=BSBSBK==s:sss:sssBBSKsaBss:^sssBSEesescs:5=:5:s===SBKffi*S!SSSSSS==ss=:s:s=:s==::==:s:=x===;=*s
C1> Estimated /.extrapolated.
516
-------
PM Profile Special ion Report
Profile Name
Profile Number
Data Quality
Heavy Duty Vehicles - Diesel
32204
C
Control Device 5 Mot Applicable
ReferenceCs) : 62
Data Source : Vehicle exhaust gases sampled with a dilution sampler and
constant volume sampI ins system. Analyzed using XRF and
flame iomzation.
SEC Assignments: 040, 041, 042, 043
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-1
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
speu i «;»
Hum Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Ha
Pb
0-2
Xwt
0.
065
0.191
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0,
059
349
022
000
033
000
000
000
000
001
000
005
045
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
770
.5 urn
unc
0.033
0.031
0.009
0.027
0.009
0.003
0.006
0.001
0.001
0.001
0.001
0.002
0.001
0.002
0.002
0.001
0.002
0.001
0.001
0.001
0.002
0.002
0.009
0.006
0.006
0.007
0.010
0.012
0.015
0.032
0.060
0.111
0.001
0.004
: (0-2.5)
: 0.920
2,5-10 urn
Xwt
1.653
1.540
0.467
0.167
0.585
0.243
0.307
0.106
0.060
0.052
0.094
0.378
0.026
0.049
0.151
0.002
0.000
0.060
0.146
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.053
0.861
7.300
unc
0.897
1.013
0.329
0.365
0.429
0.178
0.155
0.061
0.039
0.044
0.051
0.254
0.023
0.041
0.088
0.012
0.053
0.038
0.093
0.027
0.032
0.041
0.183
0.119
0.115
0.152
0.193
0.256
0.297
0.659
1.237
2.313
0.032
0.474
(0-6)
0.960
0-10 urn
Xwt
0.117
0.245
0.071
0.342
0.039
0.007
0.042
0.004
0.002
0.002
0.003
0.012
0.001
0.006
0.048
0.000
0.000
0.002
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.028
0.978
unc
0.882
0.995
0.325
0.356
0.421
0.178
0.160
0.066
0.044
0.047
0.057
0.253
0.027
0.045
0.093
0.012
0.051
0.043
0.097
0.026
0.031
0.039
0.176
0.114
0.110
0.146
0.185
0.246
0.285
0.633
1.188
2.221
0.038
0.469
CO-10)
1.000
Total
Measured <:1>
Xwt
0.117
0.245
0.071
0.342
0.039
0.007
0.042
0.004
0.002
0.002
0.003
0.012
0.001
0.006
0.048
0.000
0.000
0.002
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.028
0,978
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
<1> Estimated / extrapolated.
517
-------
PH Profile Speeiation Report
Profile Name
Profile Umber
Data Quality
Diesel Vehicles - Las Vegas Valley (1987}
32205
Control Device Not Applicable
Reference!s) 81
Data Source Samples collected with two dichotomous samplers. Analyzed
using Sequential thermal oxidation and XRF,
SCC Assignments: 040, 041, 042, 043
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
(0-2.5)
0.920
(0-6)
0.960
(0-10)
1.000
Total Participate Matter -
Species
CAS Nunber Nun Syn
Total
0-2.S urn 2.5-10 umC1> 0-10 umCI> MeasuredC1>
%ut unc
Xwt unc
%wt unc
%wt unc
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7439-92-1
TOTALS;
SSStSlSB&XSSi?SSS3S=
13
14
16
17
19
82
200
=====
At
Si
S
Cl
tc
Pb
TC
S==S=3SS8
0
1
0
0
0
0
44
46
:= = = = =
.370
.030
.620
.000
.160
.210
.000
.390
ssss
0.040
0.100
.0.060
0.000
0.030
0.020
4.400
XSKS5SESSS3S
0.370
1.030
0.620
0.000
0.160
0.210
44.000
46.390
SSSSSSSESE
0.000
0.000
0.000
0.000
0.000
0.000
0.000
sssssss;
0.370
1.030
0.620
0.000
0.160
0.210
44.000
46.390
========
0.000
0.000
0.000
0.000
0.000
0.000
0.000
=======
0.370
1.030
0.620
0.000
0.160
0.210
44.000
46.390
========
0.000
0.000
0.000
0.000
0.000
,0.000
0.000
=======
O> Estimated / extrapolated.
518
-------
PH Profile Speciation Report
Profile Name Heavy Duty Vehicles - Diesel Composite
Profile Nwber 32206
Data Quality
Control Device Not Applicable
Reference(s)
Data Source Profile represents a composite of Profiles 32203 and 32204.
SCC Assignments 040, 041, 042, 043
Mass Fraction Data - Size Interval (un) : (0-2.5) (0-6)
Mass Fraction s 0.920 0.960
Total Particulate Matter -
Species
CAS Nunber
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
— " — JSSETS SSXSSX S
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
202
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
2r
Mo
Pd
*a
Cd
In
Sn
Sb
Ba
i-a
Hg
Pb
oc
EC
0-2.5 m
%wt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
36
52
88
.034
.105
.051
.346
.019
.000
.041
.001
.001
.000
.000
.001
.001
.003
.049
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.005
.000
.000
.000
.000
.000
.000
.000
.000
.046
.058
.761
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.OOD
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
%wt
1.781
1.629
0.466
0.409
0.604
0.247
0.315
0.084
0.039
0.102
0.103
0.326
0.028
0.054
0.132
0.001
0.000
0.063
O.H1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.038
0.872
67.980
15.840
91.254
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt uncC1>
0.127
0.178
0.071
0.345
0.045
0.013
0.056
0.007
0.003
0.007
0.007
0.014
0.003
0.005
0.052
0.000
0.000
0.004
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.055
37.830
50.035
88.868
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
1.000
Total
Measured
%wt uneC1>
0.127
0.178
0.071
0.345
0.045
0.013
0.056
0.007
0.003
0.007
0.007
0.014
0.003
0.005
0.052
0.000
0.000
0.004
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.055
37.830
50.035
88.872
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.oob
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Uncertainty not evaluated.
519
-------
PM Profile Speeiation Report
Prof fie Name Leaded/Unleaded Gasoline
Profile Number 33001
Data Quality A/C
Composite - 1977
Control Device Uncontrolled
Reference(s) 41
Data Source Assuned a 39% unleaded and 53% leaded vehicle mix. Based
on AAS, XRF1CAP, INNA, 1C, and carbon combustion of < 5.5
and < 40 urn samples. All 3 size fractions assumed similar.
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.670 0.750
Total Particulate Hatter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-3S-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
^pet | KK
Hum Syrn
4
5
9
11
12
13
14
15
16
17
19
*•»**-
^*>
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Be
B
F
Na
Hg
Al
Si
P
S
Cl
K
Ca
SC
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
8a
0-2
%ut
NA
0.059
0
1
0
0
0
0
1
0
2
0
0
0
0
0
0
9
0
0
0
<
,169
.099
.254
.845
.110
.761
.352
.254
.113
<
.008
<
.001
.135
.507
<
.0
.059
,068
<
<
<
<
.464
<
.010
<
.002
<
<
<
<
.059
.5 an
unc
0.000
0.110
0.000
0.700
0.600
0.900
1.300
0.110
0.000
0.800
0.200
0.700
0.000
0.020
0.000
0.006
0.025
0.600
0.000
0.000
0.030
0.080
0.000
0.000
0.000
0.000
0.900
0.000
0.016
0.000
0.009
0.000
0.000
0.000
0.000
0.020
2.5-10 urn
Xwt
NA
0.059
<
0.169
1.099
0.254
0.845
0.110
0.761
1.352
0.254
2.1,13
<
0.008
<
0.001
0.135
0.507
<
.0
0.059
0.068
<
<
<
<
9.464
<
0.010
<
0.002
<
<
<
<
0.059
unc
0.000
0.110
0.000
0.700
0.600
0.900
1.300
0.110
0.000
0.800
0.200
0.700
0.000
0.020
0.000
0.006
0.025
0.600
0.000
0.000
0.030
0.080
0.000
0.000
0.000
0.000
0.900
0.000
0.016
0.000
0.009
0.000
0.000
0.000
0.000
0.020
0-10 urn
%wt
NE
0.059
NE
0.169
1.099
0.254
0.845
0.110
0.761
1.352
0.254
2.113
NE
0.008
HE
0.001
0.135
0.507
NE
Ni
0.059
0.068
NE
NE
NE
NE
9.464
NE
0.010
NE
0.002
NE
NE
NE
NE
0.059
unc
0.000
0.131
0.000
0.830
0.734
1.067
1.546
0.132
0.000
0.974
0.241
0.901
0.000
0.024
0.000
0.007
0.037
0.716
0.000
0.000
0.037
0.095
0.000
0.000
0.000
0.000
1.910
0.000
0.019
0.000
0.011
0.000
0.000
0.000
0.000
0.026
(0-10)
0.800
Total
Measured
'Xwt
NA
0.059
<
0.169
1.099
0.254
0.845
0.110
0.761
1.352
0.254
2.113
<
0.008
<
0.001
0.135
0.507
<
.0
0.059
0.068
<
<
<
<
9.464
<
0.010
<
0.002
<
<
<
<
0.059
unc
0.000
0.110
0.000
0.700
0.600
0.900
1.300
0.110
0.000
0.800
0,200
0.700
0.000
0.020
0.000
0.006
0.025
0.600
0.000
0.000
0.030
0.080
0.000
0.000
0.000
0.000
0.900
0.000
0.016
0.000
0.009
0.000
0.000
0.000
0.000
0.020
520
-------
PH Profile Speciation Report - continued (profile 33001)
Total Paniculate Matter
Species
CAS Number
7440-45-1
7439-97-6
7439-92-1
Nun
58
80
82
200
202
203
204
Sym
Ce
HS
Pb
TC
iC
S04
N03
0-2.5
Xut
<
<
20.280
56.615
<
5.915
NA
um
one
0
0
0
42
0
3
0
.000
.000
.000
.000
.000
.000
.000
2,1-10 un
Xut
<
<
20.280
56.615
<
5.915
NA
unc
0.000
0.000
0.000
42.000
0.000
3.000
0.000
0-10 um
*Wt
HE
NE
20.280
56.615
NE
5.915
NE
unc
0.000
0.000
0,000
0.000
0.000
3.689
0.000
Total
Measured
Xwt
<
<
20.280
56.615
<
5.915
NA
unc
0.000
0.000
0.000
42.000
0.000
3.000
0.000
TOTALS: 100.139 100.139 100.139 100.139
521
-------
PH Profile Speciation Report
Profile Name Transportation Composite
Profile Hutfaer 33002
Data Quality C/D
- Bedford, OR (19803
Control Device Uncontrolled
Reference^} 45
Data Source Includes emissions from leaded and unleaded gasoline,
dlesel, and tire wear.
Mass Fraction Data - Size Interval : CO-2.53 (0-6)
Mass Fraction : 0.750 0.820
Total Participate Matter
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7440-45-1
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
58
Sym
Be
B
F
Na
Hfl
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Kb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Ce
0-2
Xwt
HA
NA
NA
0.083
0.860
0.140
0.590
NA
3.920
2.350
<
1.170
NA
0.320
<
<
<
1.850
NA
<
<
0.090
NA
<
<
<
5.320
NA
<
NA
NA
<
NA
<
NA
<
<
.5 urn
unc
0.000
0.000
0.000
0.012
0.740
0.130
0.220
0.000
4.950
0.780
0.000
1.550
0.000
0.370
0.000
0.000
0.000
1.790
0.000
0.000
0.000
0.090
0.000
0.000
0.000
0.000
1.810
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
%wt
NA
NA
NA
0.083
0.850
NA
0.280
NA
3.110
1.690
<
0.560
NA
NA
<
<
<
1.130
NA
<
<
0.280
NA
<
<
<
3.670
NA
<
NA
NA
<
MA
<
NA
<
<
unc
0.000
0.000
0.000
0.012
0.730
0.000
0.110
0.000
3.930
0.560
0.000
0.740
0.000
0.000
0.000
0.000
0.000
1.100
0.000
0.000
0.000
0.280
0.000
0.000
0.000
0.000
1.250
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 ym
Xwt
HE
NE
HE
0.083
0.859
NE
0.547
NE
3.808
2.259
NE
1.086
NE
NE
NE
NE
NE
1.751
NE
NE
NE
0.116
NE
NE
NE
NE
5.092
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.020
0.908
0.000
0.226
0.000
5.483
0.900
0.000
1.489
0.000
0.000
0.000
0.000
0.000
1.830
0.000
0.000
0.000
0.256
0.000
0.000
0.000
0.000
2.053
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.870
Total
Measured
%ut
NE
NE
NE
0.083
0.859
NE
0.547
NE
3.808
2.259
NE
1.086
NE
NE
NE
NE
NE
1.751
NE
NE
NE
0.116
NE
NE
NE
NE
5.092
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
522
-------
PH Profile Speefation Report - continued (profile 33002)
Total Particulate Hatter •
Species
CAS Number
7439-97-6
7439-92-1
Nun
80
82
201
202
203
204
Sym
Ha
Pb
OC
EC
S04
N03
0-2.5 urn
<%ut
<
13.800
43.120
26.120
HA
NA
unc
0.000
2.070
8.620
9.660
0.000
0.000
2.5-10 urn
Xwt
<
9.600
38.420
40.960
NA
NA
unc
0.000
1.440
7.680
15.160
0.000
0.000
0-10
Xwt
NE
13.221
42.472
28.167
NE
HE
0
2
12
0
0
0
urn
unc
.000
.988
.191
.000
.000
.000
Total
Measured
Xwt
NE
13.221
42.472
28.167
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 99.733 100.633 99.461 99.461
523
-------
PH Profit* Speeiation Rtport
Profile Name : Transportation Composite
Profile Number : 33003
Data Quality ; c/0
- Portland, OR,
, (1979)
Control Device : Uncontrolled
Reference(s) : 46 •
Data Source * Composite leaded and unleaded exhaust based on tunnel
studies and exhaust measurements. Sampled with a 2-stage
virtual iapactor with a Method 5 heated probe. No dilution
•ir. Analysis by XRF, INNA, 1C, and carbon oxidation.
Mass Fraction Data - Size Interval (urn) : (0-2. S) (0-6)
Mass Fraction : 0.670 0.750
Total Particulate Matter
Species
CAS Nuifcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Sym
Be
B
F
Na
Ha
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Kn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
*9
Cd
Sn
Sb
Cs
0-2
%wt
NA
NA
NA
NA
NA
1.100
0.820
<
0.400
3.000
0.072
1.250
<
<
<
<
<
2.100
<
0.018
0.073
0.350
<
<
<
<
5.000
<
<
<
<
<
<
<
<
.5 urn
unc
0.000
0.000
0.010
0.050
0.500
0.500
0.300
0.000
0.130
1.000
0.029
0.500
0.000
0.100
0.005
0.010
0.016
0.800
0.000
0.003
0.030
0.130
0.000
0.000
0.000
0.000
1.700
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
%wt
NA
NA
NA
NA
NA
1.100
0.820
<
0.400
3.000
0.072
1.250
<
<
<
<
<
2.100
<
0.018
0.073
0.350
<
<
<
<
5.000
<
<
<
<
<
<
<
<
unc
0.000
0.000
0.010
0.050
0.500
0.500
0.300
0.000
0.130
1.000
0.029
0.500
0.000
0.100
0.005
0.010
0.016
0.800
0.000
0.008
0.030
0.130
0.000
0.000
0.000
0.000
1.700
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NE
NE
NE
NE
NE
1.100
0.820
NE
0.400
3.000
0.072
1.250
NE
NE
NE
NE
NE
2.100
NE
0.018
0.073
0.350
NE
NE
NE
NE
5.000
NE
NE
NE
NE
NE
NE
NE
NE
unc
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
2
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.620
.381
.000
.168
.287
.036
.628
.000
.000
.000
.000
.000
.011
.000
.010
.038
.165
.000
.000
.000
.000
.181
.000
.000
.000
.000
.000
.000
.000
.000
CO-10)
0.800
Total
Measured
%Mt
NE
NE
NE
NE
NE
1.100
0.820
NE
0.400
3.000
0.072
1.250
NE
NE
NE
NE
NE
2.100
NE
0.018
0.073
0.350
NE
NE
NE
NE
5.000
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
524
-------
PK Profile Speciation Report - continued (profile 33003}
Total Particulate Hatte
Species
CAS Number Hum Sym
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
56
58
80
82
201
202
203
204
m
Ce
Kg
Pb
oc
EC
S04
N03
r -
0-2.5 un
Xwt
20.
43.
18.
1.
0.
<
<
000
400
970
300
910
98.763
unc
0.000
0.000
0.000
3.000
6.900
6.410
0.400
0.300
2.5-10 urn
Xut
«
<
20.000
43.400
18.970
1.300
0.910
unc
0.000
0.000
0.000
3.000
•6.900
6.410
0.400
0.300
98.763
0-10 urn
Xut
NE
NE
HE
20.000
43.400
18.970
1.300
0.910
98.763
unc
0.000
0.000
0.000
4.S83
0.000
8.230
O.S21
0.387
Total
Measured
Xut
NE
NE
NE
20.000
43.400
18.970
1.300
0.910
98.763
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
525
-------
PM Profile Specfatfon Report
Profile Nettie
Profile Number
Data Quality
Transportation Composite
33004
C
Control Device Hot Applicable
Reference(s) 62
Data Source Developed using steady state vehicle exhaust profiles and
AP-42 tire near factors, relative to vehicle miles traveled
in the Sepulveda Tunnel (Los Angeles).
SCC Assignments: 110
Mass Fraction Data - Size interval (urn) !
Mass Fraction !
Total Parti cut ate
CAS Nurfcer Him
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
13
14
15
16
17
19
20
22
23
?4
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Natter
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
UM,
Fe
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
la
Hg
Pb
-
0-2
Xwt
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.076
.645
.124
.364
.535
.005
.056
.006
.001
.000
.018
.001
.000
.003
.385
.001
.003
.000
.174
.000
.003
.000
.000
.000
.000
.000
.000
.000
.000
.000
.001
.000
.000
.245
.5 urn
unc
0.039
0.924
0.103
0.926
0.473
0.006
0.053
0.004
0.001
0.001
0.016
0.003
0.001
0.002
0.221
0.002
0.008
0.001
0.106
0.002
0.004
0.003
0.013
0.008
0.008
0.010
0.013
0.017
0.020
0.045
0.085
0.155
0.001
0.149
: (0-2.5)
: 0.690
2.5-10 urn
Swt
0.179
0.219
0.255
1.796
1.367
0.017
0.046
0.021
0.004
0.005
0.009
0.027
0.002
0.004
0.913
0.000
0.000
0.004
0.022
0.000
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.000
0.004
0.088
unc
0.123
0.166
0.315
1.875
1.601
0.017
0.030
0.017
0.004
0.004
0.007
0.025
0.002
0.004
0.90S
-0.001
0.007
0.004
0.017
0.002
0.012
0.003
0.011
0.007
0.007
0.009
0.011
0.015
0.017
0.038
0.072
0.134
0.004
0.065
CO-6)
0.770
0-10
%Mt
0.092
0.577
0.145
1.432
0.667
0.007
0.054
0.008
0.001
0.001
0.017
0.005
0.000
0.003
0.469
0.001
0.003
0.001
0.150
0.000
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.001
0.220
umm
unc
0.123
0.797
0.305
1.904
1.530
0.019
0.055
0.019
0.006
0.007
0.017
0.026
0.004
0.006
0.861
0.002
0.009
0.006
0.094
0.002
0.014
0.004
0.015
0.009
0.009
0.012
0.015
0.020
0.023
0.051
0,097
0.179
0.006
0.144
(0-10)
0.820
Total
Measured
Xwt
0.095
0.451
0.159
1.459
0.765
0.007
0.047
0.010
0.001
0.001
0.016
0.007
0.001
0.003
0.532
0.001
0.002
0.001
0.122
0.000
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.001
0.195
unc
0.043
0.585
0.153
0.956
0.724
0.004
0.032
0.006
0.001
0.001
0.014
0.004
0.001
0.002
0.360
0.001
0.005
0.001
0.080
0.001
0.005
0.002
0.007
0.004
0.004
0.005
0.007
0.009
0,011
0.024
0.045
0.082
0.001
0.128
526
-------
PM Profile Speciation Report - continued (profile 330045
Total Participate Natter -
Total
0-2.5 un 2.5-10 un 0-10 unC1> Measured
Species
CAS Number Hum Sym Xwt unc Xwt unc Xwt unc %ut unc
201 OC 52,728 21 ,178 60.260 S3.967 S3.922 55.346 54.14725.247
202 EC 45.404 16.481 27.351 27.084 42.542 29.056 39.907 17.021
TOTALS: 101.778 92.604 100.323 97.936
Cis»~=«is—sssBiseBsssssBSBssssBSffiEjSBsssBasssBsssssssesssB—ssssssaessssesssssBsssssassea!—SESEBBSS
€1} Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
527
-------
PH Profile Specialion Report
Profile Name Transportation Composite
Profile Number 33005
Data Quality C
Control Device Mot Applicable
Reference(s) 62
Data Source Developed using steady state vehicle exhaust profiles and no
tire wear factors included, relative to vehicle miles
traveled in the Sepulveda Tunnel (Los Angeles).
SCC Assignments: 110
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction s 0.690 0.770
Total Participate Hatter
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
HS
Pb
0-2
"Xwt
0.077
0.957
0.057
1.037
0.029
0.008
0.072
0.001
0.001
0.000
0.028
0.001
0.000
0.005
0.053
0.002
0.004
0.000
0.264
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.373
.5 urn
unc
0.051
1.391
0.020
1.182
0.020
0.008
0.079
0.003
0.002
0.002
0.024
0.005
0.002
0.003
0.028
0.002
0.012
0.002
0.152
0.003
0.003
0.004
0.019
0.012
0.012
0.016
0.020
0.026
0.031
0.069
0.129
0.236
0.002
0.207
2.5-10 urn
%wt
0.959
1.484
0.288
0.360
0.374
0.140
0.213
0,059
0.034
0.038
0.078
0.233
0.017
0.030
0.125
0.002
0.000
0.036
0.184
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.030
0.749
unc
0.636
1.075
0.211
0.440
0.272
0.110
0.132
0.044
0.026
0.028
0.041
0.165
0.014
0.024
0.088
0.007
0.061
0.025
0.120
0.014
0.016
0.020
0.090
0.058
0.057
0.075
0.095
0.126
0.146
0.325
0.609
1.138
0.022
0.425
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0-10
Xwt
.217
.041
.094
.930
.084
.029
.094
.010
.006
.006
.036
.038
.003
.009
.064
.002
.003
.006
.251
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.005
.433
umcn
unc
0.595
1.543
0.200
1.082
0.256
0.106
0.144
0.045
0.028
0.030
0.048
0.157
0.016
0.026
0.089
0.007
0.057
0.027
0.175
0.013
0.015
0.019
0.084
0.054
0.053
0.070
0.089
0.118
0.136
0.304
0.569
1.063
0.024
0.439
(0-10)
0.820
Total
Measured
Xwt
0.116
0.843
0.069
0.940
0.046
0.014
0.069
0.004
0.002
0.002
0.031
0.013
0.001
0.006
0.056
0.001
0.004
0.002
0.242
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.002
0.38S
unc
0.054
1.122
0.024
1.058
0.022
0.008
0.058
0.003
0.002
0.002
0.024
0.006
0.001
0.003
0.030
0.002
0.011
0.001
0.134
0.002
0.002
0.003
0.013
0.008
0.008
0.011
0.014
0.018
0.021
0.048
0.089
0.162
0.002
0.206
528
-------
PM Profile Spec i at ion Report - continued (profile 33005)
Total Paniculate Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 umC1> Measured
Species --------- --- ------------ --•• ---- — • --------- • —
CAS Number Hum Sym Xut unc Xwt unc Xwt unc Xwt unc
201 OC 49.809 24. 1S1 74.89039.591 53.78542.511 50.08120.949
202 EC 54.153 19.763 17.275 9.531 48.306 19.932 50.878 18.906
TOTALS: 106.931 97.598 105.4S2 103.807
{1} Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
529
-------
PH Profile Speciation Report
Profile Name
Profile Number
Data Quality
Transportation Composite
33006
C
Control Device
Reference(s)
Data Source
Kot Applicable
62
Developed using Federal test procedure vehicle emission
profiles and California Air Resources Board emission
factors. Tire wear factors are not included.
SCC Assignments: 110
H»ss Fraction Data - Size Interval Cum)
Mass Fraction
Total Partfeulate Matter
Species
CAS Ninber Hum Sym
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
JC
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
2n
Ca
As
Se
Br
Rb
Sp
Y
Zr
Mo
Pd
Ag
Cd
In
Sn '
Sb
Bs
La
Kg
Pb
**
0-2
Xwt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
.332
.908
.155
.799
.102
.018
.150
.003
.COS
.001
.306
.115
.004
.014
.184
.010
.003
.000
.958
.002
.000
.000
.000
.000
.000
.004
.000
.000
.000
.000
.000
.000
.001
.760
.5 urn
unc
0.216
0.407
0.069
0.562
0.085
0.010
0.040
0.002
0.003
0.002
0.207
0.036
0.002
0.006
0.062
0.013
0.216
0.002
0.839
0.014
0.003
0.013
0.015
0.009
0.009
0.012
0.016
0.020
0.024
0.053
0.099
0.180
0.002
2.998
: (0-2.5)
: 0.690
2.5-10 urn
Xwt
0.712
0.554
0.207
0.214
0.096
0.049
0.329
0.023
0.006
0.048
0.796
0.842
0.025
0.038
0.373
0.004
0.000
0.014
3.970
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
19.942
unc
0.513
0.239
0.101
1.388
0.230
0.033
0.126
0.081
0.032
0.020
0.309
0.251
0.008
0.013
0.107
0.048
0.807
0.010
1.870
0.056
0.008
0.056
0.037
0.022
0.025
0.028
0.046
0.046
0.059
0.125
0.235
0.428
0.007
7.523
<0-65
0.770
0-10 umC1>
%ut
0.392
0.852
0.163
0.706
0.101
0.023
0.178
0.006
0.005
0.008
0.384
0.230
0.007
0.018
0.214
0.009
0.003
0.002
2.277
0.002
0.000
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.003
8.850
unc
0.514
0.427
0.117
1.362
0.224
0.036
0.132
0.075
0.030
0.025
0.348
0.253
0.014
0.020
0.126
0.046
0.762
0.013
1.905
0.053
0.008
0.053
0.036
0.022
0.024
0.028
0.044
0.045
0.058
0.123
0.231
0.421
0.011
7.587
(0-103
0.820
Total
Measured
%ut
0.430
0.855
0.163
0.714
0.122
0.028
0.160
0.007
0.005
0.009
0.353
0.192
0.008
0.017
0.188
0.009
0.003
0.004
2.219
0.002
0.000
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.002
8.495
unc
0.229
0.346
0.054
0.539
0.091
0.010
0.040
0.014
0.006
0.002
0.216
0.051
0.003
0.005
0.052
0.013
0.210
0.002
0.983
0.015
0.003
0.013
0.017
0.010
0.010
0.013
0.019
0.022
0.027
0.060
0.111
0.203
0.002
3.765
530
-------
PM Profile Spec i at ion Report • continued (profile 33006)
Total Participate Natter -
Total
0-2. 5 an 2.5-10 urn 0-10 unC1> Measured
Species • - ---- - ------- ------------ ------------ ----- • -------
CAS Number Hum Sym Xut unc Xwt unc %ut unc %wt unc
201 OC 36.474 8.684 16.456 9.962 33.300 12.560 34.722 9.320
202 EC 38.767 7.216 8.743 4.710 34.007 8.798 33.449 6.554
TOTALS: S7,.075 53.4S4 81.743 82.159
<1> Calculated based on methodology described in the Air Emission Species Manual,
Volume 11.
531
-------
PH Profile Speciatfon Report
Profile Name ; Transportation Composite
Profile Number ; 3300?
Data Quality : C
Control Device ; Not Applicable
ReferenceCs) : 6?. ;
Data Source : Developed using Federal test procedure vehicle emission
profiles with no tire wear factors included.
SCC Assignments: 110
Mass Fraction Data - Size Interval CinO
Mass Fraction
Total Particulate Hatter
Species
CAS Nimber Hum Svm
7429-90-5
7440- 2 1-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
TC
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
Al
Sf
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Hi
Cu
2n
Ga
As
Se
>*r
Rb
sr
Y
Zr
Ho
Pd
Ag
cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
0-2.5 urn
%Mt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
A
w
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
34
.032
.093
.049
.379
.026
.002
.051
.002
.002
.000
.035
.009
.002
.002
.060
.001
.000
.000
.224
.000
.000
.000
.000
.000
.000
.008
.000
.000
.000
.000
.000
.000
.000
.779
.831
unc
0.045
0.067
0.050
0,400
0.030
0.009
0.055
0.004
0.003
0.003
0.052
0.010
0.003
0.003
0.062
0.003
0.026
0.002
C.305
0.004
0.005
0.006
0.025
0.016
0.016
0.024
0.028
0.035
0.042
0.094
0.174
0.317
0.003
1.069
40.857
: <0-2.55
: 0.690
2.5-10 urn
Xwt
1.431
1.090
0.367
0.536
0.442
0.179
0.301
0.047
0.013
0.113
0.333
0.429
0.027
0.050
0.182
0.001
0.000
0.047
1.390
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
7.092
50.978
unc
1.945
1.467
0.475
0.894
0.681
0.257
0.329
0.435
0.171
0.155
0.342
0.380
0.034
0.068
0.160
0.019
0.269
0.065
1.689
0.031
0.033
0.095
0.174
0.114
0.107
0.143
0.191
0.235
0.285
0.640
1.208
2.200
0.030
8.239
75.139
<0-65
0.770
0-10
Xwt
0.254
0.251
0.099
0.404
0.092
0.030
0.091
0.009
0.004
0.018
0.082
0.076
0.006
0.010
0.079
0.001
0.000
0.007
0.409
0.000
0.000
0.000
0.000
0.000
0.000
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.003
1.780
37.391
um{1>
unc
1.791
1.352
0.441
0.891
0.628
0.239
0.309
0.399
0.157
0.145
0.321
0.354
0.034
0.065
0.160
0.018
0.248
0.062
1.578
0.029
0.031
0.087
0.161
0.105
0.099
0.133
0.177
0.218
0.264
0.592
1.118
2.036
0.030
7.638
77.257
CO-1QJ
0.820
Total
Measured
Xwt
0.155
0.175
0.075
0.381
0.058
O.C13
0.071
0.008
0.003
0.010
0.054
0.031
0.004
0.005
0.066
0.001
0.001
0.005
0.293
0.000
0.000
0.000
0.000
0,000
0.000
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.002
1.154
36.262
unc
0.161
0.142
0.080
0.400
0.068
0.022
0.078
0.032
0.013
0.012
0.066
0.026
0.005
0.006
0.066
0.003
0.028
0.007
0.386
0.005
0.005
0.009
0.029
0.019
0.018
0.026
0.032
0.040
0.048
0.108
0.200
0.367
0.004
1.484
42,168
532
-------
PM Profile Speciation Report - continued (profile 33007}
Total Paniculate Hatter -
Total.
0-2.5 un 2.5-10 urn 0-10 umC1> Measured
Species .......... - ............. - ........ --• — — ------
CAS Number Nun Sym Xwt unc %ut unc Xut unc %ut unc
202 EC 51.911 59.353 18.052 20.450 46.543 53.729 49.703 56.151
TOTALS: 88.498 83.119 87.646 83.542
C1> Calculated based on methodology described in the Air Emission Species Manual,
Volume II.
533
-------
PK Proffit Speeiation Report
Profile Name
Profile Number
Data Quality
Transportation Composite
33008
C
Control Device
Reference(s)
Data Source
Hot Applicable
62
Developed using Federal test procedure vehicle emission
profiles, AP-42 tire wear factors, and asbestos brake wear
data.
SCC Assignments: 110
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Particulate
Hatter
: (0-2.5)
: 0.690
(0-6)
0.770
0.820
Total
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
• 7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
0-2
Hum Sym %«t
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
At
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
sn
Sb
Ba
La
H9
Pb
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
035
192
053
417
065
002
068
002
002
001
035
046
002
002
087
001
000
000
216
000
001
000
000
000
000
008
000
000
000
000
009
000
000
752
.5 urn
unc
0.043
0.114
0.048
0.384
0.053
0.008
0.057
0.004
0.003
0.003
0.050
0.037
0.003
0.003
0.064
0.003
0.025
0.002
0.290
0.004
0.004
0.006
0.025
0.015
0.015
0.023
0.027
0.033
0.040
0.090
0.168
0.306
0.003
1.018
2.5-10 UB
%wt
0.949
1.927
0.296
0.844
0.677
0.113
0.411
0.034
0.008
0.083
0.216
0.725
0.017
0.032
0.409
0.001
0.000
0.030
0.880
0.000
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.105
0.000
0.012
4.488
unc
1.165
1.217
0.295
0.669
0.547
0.154
0.309
0.275
0.108
0.093
0.201
0.394
0.020
0.041
0.200
0.012
0.170
0.039
0.994
0.020
0.021
0.060
0.110
0.072
0.068
0.091
0.121
0.149
0.180
0.405
0.769
1.392
0.018
4.831
0-10 umC1>
%ut
0.180
0.467
0.092
0.485
0.162
0.020
0.122
0.007
0.003
0.014
0.064
0.154
0.004
0.007
0.138
0.001
0.000
0.005
0.321
0.000
0.002
0.000
0.000
0.000
0.000
0.007
0.000
0.000
0.000
0.000
0.024
0.000
0.002
1.344
unc
1.075
1.137
0.278
0.702
0.511
0.144
0.294
0.253
0.099
0.088
0.193
0.374
0.021
0.040
0.201
0.012
0.157
0.038
0.950
0.019
0.021
0.055
0.103
0.067
0.064
0.086
0.113
0.139
0.169
0.379
0.720
1.303
0.019
4.533
Measured
Xut
0.152
0.370
0.082
0.448
0.127
0.017
0.103
0.009
0.003
0.011
0.052
0.105
0.004
0.005
0.114
0.001
0.001
0.005
0.274
0.000
0.001
0.000
0.000
0.000
0.000
0.006
0.000
0.000
0.000
0.000
0.017
0.000
0.002
1.078
unc
0.147
0.225
0.075
0.375
0.100
0.020
0.084
0.030
0.012
0.011
0.060
0.074
0.005
0.005
0.074
0.003
0.026
0.007
0.352
0.004
0.005
0.008
0.028
0.018
0.017
0.024
0.030
0.037
0.045
0.101
0.188
0.343
0.004
1.354
534
-------
PM Profile Spec fat ion Report • continued (profile 33008)
Total Paniculate Hatter -
Total
0-2.5 urn 2.5-10 urn 0-10 unC1> Measured
Species • T ' —— '•—
CAS Nurcber Nun Synt %ut unc Xwt unc Xut unc Xwt unc
201 OC 35.10638.883 47.056 46.624 37.001 S4.158 36.60138.463
202 EC 50.83156.450 18.70713.564 45.73849.500 47.78851.121
TOTALS: 87.933 78.027 86.364 87.376
SSS3Si:SSS=CSSS:=S=SSSSXBeSSffiXSe£SS8ESSSSS&ttS93eSSSSS£CSSSBKe5B«:S!ESSKSaESSKS=S5CSSSXSSSSSSS
<1> Calculated based on methodology described in the Air Emission Species Manual,
Volume II.
535
-------
PH Profile Speciation Report
Profile Name
Profile Nunfcer
Data Quality
Transportation Composite
33009
C
Control Device Not Applicable
Reference(s) 62
Data Source Samples collected through a vent eight feet above readuay in
Sepulveda Tunnel (Los Angeles) using Sierra Model 244 manual
diehotcnous samplers. Analyzed using XRF and flame
ionization.
SCC Assignments: 110
Hass Fraction Data - Size Interval (um)
Mass Fraction
Total Particulate Hatter
Species
CAS Number Hum Sym
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
"
0-2
Xwt
0
0
0
0
0
0
0
0
0
0
0
2
0
0
0
.338
.383
.293
.731
.363
.019
.125
.004
.000
.004
.134
.218
.010
.112
.247
0.003
0
.039
0.000
1
0
0
0
0
0
Q
0
0
0
0
0
0
0
0
.355
.000
.000
.000
.000
.020
.000
.000
.000
.000
.000
.000
.328
.000
.000
.5 um
unc
0.131
0.225
0.054
0.304
0.324
0.021
0.048
0.011
0.004
0.004
0.017
0.277
0.003
0.014
0.031
0.005
0.082
0.002
0.164
0.011
0.005
0.008
0.026
0.018
0.016
0.021
0.028
0.035
0.042
0.092
0.056
0.318
0.003
: (0-2.5)
: 0.690
2.5-10 um
Xwt
0.816
6.053
0.241
0.092
0.000
0.000
1.327
0.008
0.000
0.018
0.201
11.338
0.056
0.291
0.606
0.003
0.000
0.002
0.269
0.018
0.000
0.000
0.000
0.039
0.000
0.000
0.000
0.000
0.000
0.000
1.077
0.000
0.002
unc
2.154
14.086
0.522
1.643
20.748
0.784
2.719
0.132
0.069
0.047
0.426
23.081
0.111
0.611
1.150
0.012
0.108
0.007
0.634
0.050
0.480
0.015
0.065
0.062
0.037
0.048
0.064
0.080
0.096
0.216
1.905
0.722
0.007
(0-6)
0.770
0-10
Xwt
0.414
1.282
0.285
0.630
0.306
0.016
0.316
0.005
0.000
0.007
0.145
3.664
0.017
0.140
0.304
0.003
0.033
0.000
1.183
0.003
0.000
0.000
0.000
0.023
0.000
0.000
0.000
0.000
0.000
0.000
0.447
0.000
0.000
(0-10)
0.820
Total
unC1> KeasuredC2>
unc
1.982
12.934
0.484
1.531
19.035
0.720
2.498
0.122
0.063
0.045
0.393
21.198
0.103
0.563
1.058
0.012
0.121
0.008
0.620
0.048
0.441
0.015
0.064
0.061
0.036
0.047
0.063
0.079
0.095
0.212
1.753
0.714
0.008
Xwt
0.338
0.383
0.293
0.731
0.363
0.019
0.125
0.004
0.000
0.004
0.134
2.218
0.010
0.112
0.247
0.003
0.039
0.000
1.355
0.000
0.000
0.000
0.000
0.020
0.000
0.000
0.000
0.000
0.000
0.000
0.328
0.000
0.000
unc
0.131
0.225
0.054
0.304
0.324
0.021
0.048
0.011
0.004
0.004
0.017
0.277
0.003
0.014
0.031
0.005
0.082
0.002
0.164
0.011
0.005
0.008
0.026
0.018
0.016
0,021
0.028
0.035
0.042
0.092
0.056
0.318
0.003
536
-------
PH Profile Speciation Report - continued (profile 33009)
Total Particulate Matter -
Total
0-2.5 urn 2,5-10 um 0-10 unC1> WeasuredC2>
. ' Species ' * ............ .........—
CAS Ntitfeer Hum Sym Xwt unc Xwt unc Xut unc Xwt unc
7439-92-1 82 Pb 2.437 0.298 2.049 3.952 2.375 3.651 2.437 0.298
201 OC 38.586 5.550 39.16461.704 38.67757.077 38.586 5.550
202 EC 38.119 4.909 12.656 24.275 34.082 23.124 38.119 4.909
TOTALS: 85.868 76.326 84.357 85.868
Basvssss«:ss:ssa:=ssssescs==xsaEsss=:3:sae£=£e£s=asss=ss£ssaes:sssffiS£s;ss=s:ssK=ssss!sasc==5ss£
•C1} Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
{2} Estimated / extrapolated.
537
-------
PH Profile Speciation Report
Profile dame
Profile Number
Data Quality
Gasoline Vehicles - Us Vegas Valley (1987)
33010
E
Control Device
Reference^}
Data Source
Not Applicable
81
Samples collected with two dichotomous samplers. Analyzed
using Sequential thermal oxidation and XRF.
SCC Assignments: 110
Mass Fraction Data -
Size Interval (un) :
Mass Fraction :
(0-2.5)
0.670
<0-6)
0.750
{0-10)
0.800
Total Participate Hatter -
Total
0-2.5 urn 2.5-10 umCU 0-10 umCI> Measured^}
CAS Hunter
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7439-92-1
spe<
Stlfl
13
14
16
17
19
82
200
:ies
Svin
Al
Si
S
Cl
K.
Pb
TC
0
0
0
0
0
2
5?
Xut
.046
.092
.092
.830
.320
.500
.600
unc
0.005
0.009
0.009
0.083
0.032
0.250
10.000
%wt
0.046
0.092
0.092
0.830
0,320
2.500
57.600
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Xut
0.046
0.092
0.092
0.830
0.320
2.500
57.600
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
%Mt
0.046
0.092
0.092
0.830
0.320
2.500
57.600
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
61.480 61.480 61.480 61,480
C1> Estimated / extrapolated.
538
-------
PH Profile Speciation Report
Profile Name Highway
Profile Mumfaer 33011
Data Quality C
Vehicles
Composite
Control Device Not Applicable
Reference(s)
Data Source Profile represents a composite of Profiles 33004, 33005,
33006, 33007, 33008, and 33009.
SCC Assignments: 110
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.690 0.770
Total Particulate Matter -
CAS Nurtoer
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
»)^SW I K»
Hum Syra
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Hi
Cu
Zn
Ga
As
Se
Br
8b
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
H|
Pb
DC
0-2
Xwt
0
.148
0.530
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
41
.122
,789
.187
.009
.087
.003
.002
.001
.093
.398
.003
.023
.169
.003
.008
.000
.700
.000
.001
.000
.000
.003
.000
.003
.000
.000
.000
.000
.056
.000
.002
.891
.256
.5 urn
unc{1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
%ut
0.841
1.888
0.276
0.507
0.493
0.083
0.438
0,032
0.011
0.051
0.272
0.266
0.024
0.074
0.435
0.002
0.000
0.022
1.119
0.003
0.003
0.000
0.000
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.197
0.000
0,013
5.721
48.134
yncd>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
0.258
0.745
0.146
0.765
0.235
0.021
0.143
0.008
0.003
0.009
0.121
0.695
0.006
0.031
0.211
0.003
0.007
0.004
0.765
0.008
0.001
0.000
0.000
0.004
0.000
0.003
0.000
0.000
0.000
0.000
0.079
0.000
0.002
2.500
42.346
unc<1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.820
Total
Measured
Xwt
0.214
0.513
0.140
0.779
0.247
0.017
0.096
0.007
0.002
0.006
0.107
0.428
0.005
0.025
0.201
0.003
0.008
0.003
0.751
0.001
0.001
0.000
0.000
0.003
0.000
0.003
0.000
0.000
0.000
0.000
0.058
0.000
0.002
2.291
41.733
ync<1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
539
-------
PH Profile Speciation Report - continued (profile 33011)
»»~~»™™~***^~**»*»*^™»*~*»~»*mm»**mm»»mi,*»*mm*~mmm*mmmm + mmmmmmmmmmmm,*****w^m*mi+mmm*m~*
Total Participate Hatter -
Total
0-2.5 urn 2.5-10 urn 0-10 urn Measured
Species --• -— ..i.. - —
CAS timber Nun Sym %wt unc<1> Xyt uncd> Xwt unct1> %wt unc{1>
202 EC 46.531 0.000 17,131 0.000 41.870 0.000 43.307 0.000
TOTALS: 93.018 78.043 90.989 90.951
8SSSSBSSrK3X=SXSSS5&KSSSSSSSSS=£=ffi&S==SSS55SSSSS!KSSSS:SS=:SBESS3ffiS=SS&SSSSKSSXSB==ttaSS=:
CD Uncertainty not evaluated.
540
-------
PM Profile Speciation Report
Profile Name : Transportation Composite
Profile Number : 33020
Data Quality : D
Control Device : Uncontrolled
Refer ence(s) : 41,45,46
Data Source : Developed from Profiles 33001, 33002, and 33003.
SCC Assignments: 110
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.690 0.770
Total Participate Matter -
CAS Nunfcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
OjJV\* 1 WO
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Be
B
f
Ha
Mg
Al
Si
P
s
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ge
Ge
As
Se
Br
Rb
Sr
Zr
AS
Cd
Sn
Sb
Cs
Ba
0-2
Xwt
0
0
0
0
0
0
0
0
1
2
0
1
0
0
0
0
0
1
0
0
0
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
.000
.020
.000
.084
.653
.498
.752
.037
.694
.234
.109
.511
.000
.109
.000
.000
.045
.486
.000
.006
.044
.169
.000
.000
.000
.000
.595
.000
.003
.000
.001
.000
.000
.000
.000
.020
.5 urn
unc
0.000
0.064
0.006
0.405
0.621
0.599
0.781
0.064
2.859
0.866
0.117
1.023
0.000
0.222
0.003
0.007
0.017
1.184
0.000
0.005
0.024
0.102
0.000
0.000
0.000
0.000
1.525
0.000
0.009
0.000
0.005
0.000
0.000
0.000
0.000
0.012
2.5-10 urn
Xwt
0.000
0.020
0.000
0.084
0.650
0.451
0.648
0.037
1.424
2.014
0.109
1.308
0.000
0.003
0.000
0.000
0.045
1.246
0.000
0.006
0.044
0.233
o.ooo
0.000
0.000
0.000
6.045
0.000
0.003
0.000
0.001
0.000
0.000
0.000
0.000
0.020
unc
0.000
0.064
0.006
0.405
0.617
0.594
0.773
0.064
2.270
0.807
0.117
0.655
0.000
0.059
0.003
0.007
0.017
0.858
0.000
0.005
0.024
0.184
0.000
0.000
0.000
0.000
1.324
0.000
0.009
0.000
0.005
0.000
0.000
0.000
0.000
0.012
0-10 urn
Xwt
0.000
0.020
0.000
0.084
0.652
0.491
0.735
0.037
1.651
2.199
0.109
1.479
0.000
0.092
0.000
0.000
0.045
1.448
0.000
0.006
0.044
0,179
0.000.
0.000
0.000
0.000
6.507
0.000
0.003
0.000
0.001
0.000
0.000
0.000
0.000
0.020
unc
0.000
0.076
0.007
0.482
0.745
0.715
0.932
0.076
3.083
1.058
0.140
1.050
0.000
0.193
0.003
0.008
0.022
1.252
0.000
0.006
0.030
0.181
0.000
0.000
0.000
0.000
2.005
0.000
0.011
0.000
0.006
0.000
0.000
0.000
0.000
0.014
CO-10)
0.820
Total
Measured
Xwt
0.000
0.020
0.000
0.056
0.366
0.085
0.282
0.037
0.254
0.451
0.085
0.704
0.000
0.003
0.000
0.000
0.045
0.169
0.000
0.000
0.020
0.023
0.000
0.000
0.000
0.000
3.155
0.000
0.003
0.000
0,001
0.000
0.000
0.000
0.000
0.020
unc
0.000
0.064
0.000
0.404
0.346
0.520
0.751
0.064
0.000
0.462
0.115
0.404
0.000
0.012
0.000
0.003
0.014
0.346
0.000
0.000
0.017
0.046
0.000
0.000
0.000
0.000
0.520
0.000
0.009
0.000
0.005
0.000
0.000
0.000
0.000
0.012
541
-------
PH Profile Speciat ion Report - continued (profile 33020}
Total Paniculate Hitter -
0-2.5 urn 2.5-10 urn 0-10 urn
mmm or *> mm » <••*<• « <• * a, *, » m f> w * *t • <•*••* w> <• •> «• tt> o t
%ut unc Xut unc Xut
Total
Measured
Species
CAS Nurber Nun Sym
unc
%Ht
unc
7440-45-1
7439-97-6
7439-92-1
TOTAtSt
==zn=n======
58
80
82
200
201
202
203
204
======
Ce
Hg
Pb
TC
oc
EC
S04
N03
======
0
0
18
18
28
15
2
0
99
n==sx
.000
.000
.027
.872
.840
.030
.405
.303
.547
=====
0.000
0.000
2.104
24.249
6.375
6.693
1.747
0.173
:=======:
0.000
0.000
16.627
18.872
27.273
19.977
2.405
0.303
99.&4S
========
0.000
0.000
1.921
24.249
5.961
9.503
1.747
0.173
=======:
0.000
0.000
17.805
18.872
28.592
15.814
2.405
0.303
99.593
SSS==S=B
0.000
0.000
3.777
29.030
8.732
10.223
2.118
0.212
ssssssssffi;
0.000
0.000
6.760
18.872
0.000
0.000
1.972
0.000
33.383
========
0.000
0.000
0.000
24.249
0.000
0.000
1,732
0.000
=======
542
-------
PM Profile Speciation Report
Profile Name Tire Wear
Profile Number 34002
Data Quality 0/E
Control Device Uncontrolled
Reference^) 41,46,53
Data Source Composite profile developed from References 41,
SCC Assignments 112
Mass Fraction Data - Size
Total Particulate
Mass
Hatter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Sym
Be
B
F
Na
Hg
Al
si
p
s
ct
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
N?
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
Interval (urn) ;
Fraction t
0-2.5 un
Xwt unc
NR 0.000
NR 0.000
NR 0.000
NR 0.000
NR 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
" < 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
1.000 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
• < 0.000
< 0.000
< 0.000
(0-2.5)
. 0.485
2.5-10 un
Xwt unc
NR 0.000
NR 0.000
NR 0.000
m o.ooo
NR 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
1.000 0.000
< 0.000
< 0.000
< 0,000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
46, and 53.
(0-6)
0
.390
0-10 un
Xwt
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
1.000
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.553
Total
Measured
Xwt unc
NR 0.000
NR 0.000
NR 0.000
NR 0.000
NR 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
1.000 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
< 0.000
543
-------
PH Profile Specialion Report - continued (profile 34002)
Total Particulate Hatter -
Total
0-2.5 urn 2.5-10 un 0-10 urn Measured
Speoies - - -
CAS Number Num Sym Xwt unc Xwt " unc Xwt unc
%ut
unc
7440-45-1 58
7439-97-6 80
7439-92-1 82
201
202
203
204
TOTALS;
Ce
Hg
Pb
or
iC
S04
N03
21.
60.
83.
<
«
750
900
NR
NR
650
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<
<
21.750
60.900
NR
NR
83.650
0.
0.
0.
0.
0.
0.
0.
000
000
000
000
000
000
000
NE
m
NE
21.750
60.900
NE
NE
83.650
0.000
0.000
0.000
0.000
0.000
0.000
0,000
<
<
21.750
60.900
NR
NR
83.650
0.000
0.000
0.000
0.000
0.000
0.000
0.000
544
-------
PM Profile Speciation Report
Profile Mane Tire Wear
Profile Hunter 34003
Data Quality E
Control Device Not Applicable
Reference^) 62,82,83
Data Source Data taken front Reference 62. For details, consult
References 82 and 83.
SCC Assignments: 112
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.390 0.480
Total Particulate Matter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-70-2
7440-32-6
7440-62-2
7439-96-5
7440-50-8
7440-66-6
7726-95-6
7440-24-6
7440-39-3
7439-91-0
opisi; i es»
Hum Sym
11
12
13
14
15
16
17
20
22
23
25
29
30
35
38
56
57
201
202
Na
Mg
Al
Si
P
S
Cl
Ca
Ti
V
Hn
Cu
Zn
Br
Sr
Ba
La
OC
EC
0-2.5
Swt
0.
0.
0.
0.
0.
1.
1.
0.
0.
q.
d.
0.
1.
0.
0.
0.
0.
58.
28.
054
039
074
050
250
989
500
024
016
000
000
000
018
001
010
002
000
300
700
um{1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
O.OS4
0.039
0.074
0.050
0.250
1.989
1.500
0.024
0.016
0.000
0.000
0.000
1.018
0.001
0.010
0.002
0.000
58.300
28.700
umm
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.054
0.039
0.074
0.050
0.250
1.989
1.500
0.024
0.016
0.000
0.000
0.000
1.018
0.001
0.010
0.002
0.000
58.300
28.700
um{1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.550
Total
Measured
%Ht
0.054
0.039
0.074
0.050
0.250
1 .989
1.500
0.024
0.016
0.000
0.000
0.000
1.018
0.001
0.010
0.002
0.000
58.300
28.700
uric
0.013
0.008
0.022
0.050
0.250
0.694
1.000
0.008
0.005
0.000
0.000
0.000
0.047
0.000
0.008
0.002
0.000
15.000
10.000
TOTALS: 92.027 92.027 92.027 92.027
C1> Estimated / extrapolated.
545
-------
PH Profile Speciation Report
Profile Name Brake Lining
Profile Nunfcer 34004
Data Quality £
, Asbestos
Control Device Not Applicable
Refer enceCs) 62,82
Data Source Composition of asbestos brake pads analyzed using neutron
activation.
SCC Assignments: 112
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.390 0.480
Total Particulate Hatter -
Species
CAS Nunfcer
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7782-50-5
7440-70-2
7440-22-2
7440-62-2
7440-47-3
7439-96-S
7439-89-6
7440-48-4
7440-66-6
7440-38-2
7726-95-6
7440-24-6
7440-36-0
7440-39-3
7439-91-0
7440-45-1
TOTALS:
Hum
11
12
13
14
17
20
21
23
24
25
26
27
30
33
35
38
51
56
57
58
Sym
Na
Mg
Al
Si
Cl
Ca
SO
V
Cr
Mn
Fe
Co
Zn
As
Br
Sr
Sb
Bo
La
Cc
0
13
0
10
0
1
0
0
0
0
4
0
0
0
0
0
0
0'
0
0
32
0-2.5
*nt
.032
.800
.215
.800
.145
.895
.001
.001
.098
.043
.000
.007
.310
.001
.000
.041
.000
.922
.000
.001
.312
unC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2,5-10
Xwt
0.032
13.800
0.115
10.800
0.145
1.895
0.001
0.001
0.098
0.043
4.000
0.007
0.310
0.001
0.000
0.041
0.000
0.922
0.000
0.001
32.312
um<1> 0-10 umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Xwt
0.032
13.800
0.215
10.800
0.145
1.895
0.001
0.001
0.098
0.043
4.000
0.007
0.310
0.001
0.000
0.041
0.000
0.922
0.000
0.001
32.312
unc
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.OQO
0.000
(0-10)
0.550
Total
Measured
%wt
0.032
13.800
0.215
10.800
0.145
1.895
0.001
0.001
0.098
0.043
4.000
0.007
0.310
0.001
0.000
0.041
0.000
0.922
0.000
0.001
32.312
unc
0.008
0.200
0.055
2.160
0.015
1.705
0.000
0.000
0.022
0.003
1.095
0.002
0.074
0.000
0.000
0.004
0.000
0.474
O.OOQ
0.000
C1> Estimated / extrapolated.
546
-------
PH Profile Speciation Report
Profile Name
Profile Number
Data Quality
Motor OiI
34005
E
Control Device
Reference(s)
Data Source
Not Applicable
62,84
Data taken from Reference 62, For details, consult Reference
84.
SCC Assignments: 112
Mass Fraction Data - Size Interval Cum) :
Mass Fraction :
Total Partieulate Matter
CAS Number
7439-95-4
7704-34-9
7782-50-5
7440-70-2
7439-89-6
7440-66-6
7782-49-2
7726-95-6
7440-36-0
7440-39-3
9}*ff(. 1 O
Nun Sym
12
16
17
20
26
30
34
35
51
56
«a
s
Cl
Ca
Fe
Zn
Se
Br
Sb
Ba
0-2.5 um{1>
%Ht
0
0
0
0
0
0
0
0
0
0
.023
.430
.017
.103
,000
.082
.003
.000
.021
.099
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: 0.
2.5-10
%Ht
0.023
0,430
0.017
0.103
0.000
0.003
0.000
0.021
0.099
0.099
000
unKU
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
(0-6K2J
0.000
0-10
Xut
0.023
0.430
0.017
0.103
0.000
0.082
0.003
0.000
0.021
0.099
umCU
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10X2}
0.000
Total
Measured
%Mt
0.023
0.430
0.017
0.103
0.000
0.082
0.003
0.000
0.021
0.099
unc
0.040
0.230
0.024
0.109
0.000
0.073
0.001
0.000
0.021
0.156
TOTALS:
0.778
0.795
0.778
0.778
C1> Estimated / extrapolated.
€2> 0.000 indicates the unavailability of mass fraction data for this
profile.
547
-------
PH Profile Specialion Report
Profile Name
Profile Number
Data Quality
Semimetal Disk Brake Pads
54006
Control Device
Reference(s)
Data Source
Not Applicable
62
Sample collected from deposition on wheel of 1986 Acura.
Analyzed using XRF.
SCO Assignments: 112
Species
CAS Number
7439-89-6
7440-50-8
7439-98-7
7440-31-5
7440-39-3
Hum
26
29
42
50
56
Sym
Fe
Cu
Mo
Sn
8a
0-2.5
Xut
45.900
2.260
0.370
0.660
3.450
umm
unc
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
45.900
0.370
0.660
0.660
3.450
unCIl
0
0
0
0
0
unc
.000
.000
.000
.000
.000
0-10
Xwt
45.900
2.260
0.370
0.660
3.450
umC1}
unc
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xwt
45.900
2.260
0.370
0.660
3.450
unc
3.900
0.180
0.050
0.050
0.190
TOTALS? 52.640
C1> Estimated / extrapolated.
51.040
52.640 52.640
ffiC33S===aSSSSK=S=SSSSSKS! =!= ===—
548
-------
3.19 AIRCRAFT
Aircraft engines are primarily reciprocating piston and gas turbine.
Aircraft emissions of concern typically occur during landing/takeoff (LTO)
cycles. Each class of aircraft has its own typical LTO cycle which includes
all of the normal flight and ground operation modes. These operations are
divided into five modes: approach, taxi/idle in, taxi/idle out, takeoff, and
climbout.
549
-------
550
-------
PH Profile Spec!at ion Report
Profile Name Jet Aircraft
Profile Munber 34001
Data Quality D/f
Control Device Uncontrolled
Reference(s) 20
Data Source CASS Profile No. 55.
SCC Assignments
Mass Fraction Data - Size Interval Cum) :
Mass Fraction :
Total Paniculate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2 ,
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
Num
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28 '
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
56
Sym
Be
B
F
Na
Ma
Al
Si
P
S
ct
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
K;
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
Ba
0-2
Xwt
NR
NR
NR
NR
' NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
• NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-2.5)
0.485
2.5-10
Xwt
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
urn
unc
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
{0-6}
0.390
0-10 urn
Xwt
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO-10)
0.553
Total
Measured
Xwt
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
551
-------
PH Profile Speciation Report - continued (profile 34001)
Total Paniculate Hatter -
0-2.5 urn 2.5-10 urn 0-10 urn
Total
Measured
CAS Number Hum Sym
Xwt
unc
Xwt
unc
Xut
unc
Xut
7440-45-1
7439-97-6
7439-92-1
58
80
82
201
202
203
204
Ce
Hg
Pb
oc
iC
S04
N03
NR
NR
NR
25.900
70.100
NR
MR
0
0
0
0
0
0
0
.000
,000
.000
.000
.000
.000
.000
NR
NR
NR
25.900
70.100
NR
NR
0.000
0.000
0.000
0.000
0.000
0.000
0.000
HR
NR
NR
25.900
70.100
NR
NR
0.000
0.000
0.000
4.543
12.296
0.000
0.000
NR
NR
NR
25.900
70.100
NR
NR
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS!
96.000
96.000
96.000
96.000
552
-------
3.20 OTHER SOURCES
This subsection"Includes all the miscellaneous profiles which do not
readily fit into the other source categories.
553
-------
PH Profile Speciation Rtport
Profile Name Residential Space
Profile Nurrtoer 43201
Data Quality D/E
Heating - Coal
Control Device Uncontrolled
Reference(s) 51
Data Source Average of 2 tests. I CAP and AAS analysis of Method 5
samples. Carbon data approximated.
SCC Assignments;
Mass Fraction Data - Size Interval (urn) : (0-2.5} (0-6)
Mass Fraction ; 0.070 0.140
Total Partfculate Hatter -
CAS Winter
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50 -B
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
<3|**7V i Ca
Hum Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Be
B
F
Na
Ms
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
0-2
%Mt
0.
0.
0.
1.
1.
0.
2.
0.
0.
0.
0.
1.
0.
0.
0.
0.
NA
120
<
007
540
275
275
105
NR
<
<
100
<
075
030
007
007
650
007
090
060
300
<
<
0.030
0.
0.
0.
0.
<
<
<
030
<
900
<
105
405
<
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
NA
0.120
<
0.007
0.540
1.275
1.275
0.105
MR
<
<
2.100
<
0.07S
0.030
0.007
0.007
1.650
0.007
0.090
0.060
0.300
<
<
0.030
<
<
<
0.030
<
0.900
<
0.105
0.405
<
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 un
Xut
NA
0.120
<
0.007
0.540
1.275
1.275
0.105
NR
<
<
2.100
<
0.075
0.030
0.007
0.007
1.650
0.007
0.090
0.060
0.300
<
<
0.030
<
<
<
0.030
<
0.900
<
0.105
0.405
<
unc
0.000
0.008
0.000
0.000
0.038
0.089
0.089
0.007
0.000
0.000
0.000
0.147
0.000
0.005
0.002
0.000
0.000
0.115
0.000
0.006
0.004
0.021
0.000
0.000
0.002
0.000
0.000
0.000
0.002
0.000
0.063
0.000
0.007
0.02S
0.000
(0-10)
0.200
Total
Measured
Xwt
NA
0.120
<
0.007
0.540
1.275
1.275
0.105
NR
<
<
2.100
<
0.075
0.030
0.007
0.007
1.650
0.007
0.090
0.060
0.300
<
<
0.030
<
<
<
0.030
<
0.900
<
0.105
0.405
<
unc
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
554
-------
PH Profile Special ion Report - continued (profile 43201)
Total Partieulste Matter -
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
Num Sym
56
58
80
82
201
202
203
204
Ba
Ce
Hg
Pb
oc.
EC
S04
N03
0-2.5 urn
Xwt
0.105
<
<
0.015
40.000
40.000
NA
NA
89.238
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
Xwt
0.105
<
<
0.015
40.000
40.000
NA
NA
89.238
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 um
Xut
0
0
40
40
89
.105
<
<
.015
.000
.000
NA
NA
.238
unc
0.007
0.000
0.000
0.001
2.800
2.800
0.000
0.000
Total
Measured
Xut
0.105
<
<
0.015
40.000
40.000
NA
NA
89,238
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
555
-------
PM Profile Speciation Report
Profile Name Orchard
Profile Number 43302
Data Quality B/D
Heating *
Smudge
Pots
Control Device Not applicable
Referenee(s) 45 :
Data Source Average of 2 samples collected with a 2-stage virtual
impaetor.
SCC Assignments;
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Hass Fraction : 0.230 0.440
Total Paniculate Hatter
CAS Nuifcer
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
^J^b 1 C£»
Hun Syra
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Be
B
f
Na
Mg
Al
Si
P
s
Cl
K
Co
SC
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
0-2
•' Xwt
NA
NA
NA
NA
0.120
0.035
0.060
NA
0.890
<
<
<
NA
<
<
<
<
<
NA
<
<
0.013
<
<
<
<
0.006
NA
<
NA
NA
<
NA
<
NA
.5 urn
unc
0.000
0.000
0.000
0.000
0.071
0.020
0.085
0.000
0.100
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xut
NA
HA
HA
NA
0.120
0.035
0.060
NA
0.890
<
<
<
NA
<
<
<
<
<
MA
<
<
0.013
<
<
<
<
0.006
NA
<
HA
NA
<
NA
<
NA
urn
unc
0.
000
0.000
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
000
071
020
085
000
100
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
006
000
000
000
000
000
000
000
000
0-10 urn
Xut
NE
NE
NE
NE
0.120
0.035
0.060
NE
0.890
Ni
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
0.013
NE
NE
NE
NE
0.006
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.038
0.011
0.045
0.000
0.084
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.620
Total
Measured
Xwt
NE
NE
NE
NE
0.120
0.035
0.060
NE
0.890
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
0.013
NE
NE
NE
NE
0.006
NE
NE
NE
NE
NE
HE
NE
HE
unc
0.000
0.000
0.000
0.000
0.000
6,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
556
-------
P« Profile Special ion Report - continued
-------
558
-------
REFERENCES
1. Cooper, J, A. and J. 6, Watson, Receptor-Oriented Methods of Air
Participate Source Apportionment, Journal of the Air Pollution Control
Association. 30. (10) 1116-1125. (1980).
2. Gordon, 6. E., Receptor Models, Environ. Sci.... Techno!. 14: 792-800.
(1980).
3. U. S. EPA. Technical Considerations in Source Apportionment by Particle
Identification. U. S. Environmental Protection Agency, Publication No.
EPA-450/4-83-016d. 1983.
4. U. S. EPA. Digest of Ambient Participate Analysis and Assessment
Methods. U. S. Environmental Protection Agency, Publication No. EPA-
450/3-78-113. 1978.
5. Gordon, G, E., W. H. Zoller, G. S. Kowalczyk, and S. W. Rheingrover.
Composition of Source Components Needed for Aerosol Receptor Models.
Atmospheric Aerosol Source/Air Quality Relationships. ACS Symposium
Series 167, E. Macias and P. Hopke, Eds. 1980.
6. Watson, J, 6., Jr. Chemical Element Balance Receptor Model Methodology
for Assessing the Sources of Fine and Total Suspended Particulate in
Portland, Oregon. Doctoral Dissertation for the Oregon Graduate Center,
February 1979.
7. Roscie, B. A., D. K. Hopke, S. L. Dattner, and J. M. Jenks. The Use of
Principal Component Factor Analysis to Interpret Particulate
Compositional Data Sets. Journal of the Air Pollution Control
Association. 32:6. (1982).
8. Core, J. E. Receptor Model Technical Series Volume II; Chemical Mass
Balance. U. S. Environmental Protection Agency, Publication No. EPA-
450/4-81-016b. 1981.
9. Ray, S. S. and F. G. Parker. Characteristics of Ash from Coal-Fired
Power Plants. U. S. Environmental Protection Agency, Publication
No. EPA-600/7-77-010. (NTIS No. PB265374). 1977.
10, Taback, H. J., A. R. Brienza, J. F. Macko, and N. Brunetz. Fine
Particle Emissions from Stationary and Miscellaneous Sources in the
South Coast Air Basin. KVB Corporation No. 5806-783. NTIS
No. PB293923. 1979.
11. Lee, R. E., Hilcrist, A. E. Riley, and K. E. MacLeod. Concentration and
Size of Trace Metal Emissions from a Power Plant, a Steel Plant and a
Cotton Gin. Environ. Sci. Techno!. 9:643-747. July 1975.
559
-------
12. Lyons, W. S. Trace Element Measurements at Coal-Fired Steam Plants. CRC
Press, Cleveland, Ohio (Table 8.8), University of Maryland Analysis.
13. Lyons, W. S. Trace Element Measurement at Coal-Fired Steam Plants. CRC
Press, Cleveland, Ohio (Table 10.4).
14. Heisler, S. L. Source Breakdown of the St. Louis Aerosol by the Method
of Chemical and Material Balance. Report to U. S. EPA Grant R802160-Q3-
0. 1975.
15. Kowalczyk, G. S., C. E. Choquette, and G. E. Gordon. Chemical Element
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16. Bolton, N. E., et al. Trace Element Mass Balance Around a Coal-Fired
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1975.
17. National Academy of Sciences. Controlling Airborne Particles. 1979.
18. Germani, H. S., M. Small, W. Zoller, and J. Moyers. Fractionation of
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19. Cooper, J. A. ind C. A. Frasier. Preliminary Source Apportionment of
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State of Alaska, Department of Environmental Conservation by NEA, Inc.
1983.
20. U. S. EPA. Engine-Related Particulate Matter—A Compilation of
180 References. Unpublished, Provided by F. Black, U. S. Environmental
Protection Agency, ESRL, Research Triangle Park, NC. 1981.
21. Core, J. E. Willamette Valley Field and Slash Burning Impact Air
Quality Surveillance Program, Volume 3. State of Oregon, Department of
Environmental Quality. 1979.
22. Cass, Glen R. and Gregory McRae. Source-Receptor Reconciliation of
South Coast Air Basin Particulate Air Quality Data - Draft. Prepared
for California Air Resources Board. 1981.
23. Howes, J. E., W. M. Henry, and R. N. Pesut. Evaluation of Stationary
Source Particulate Measurements Methods - Volume V, Secondary Lead
Smelters. U. S. Environmental Protection Agency, Publication No. EPA-
600/2-79-116 (NTIS No. PB300337). 1979.
24. Schwitzgebel, K., R. Coleman, R. Collins, R. Mann, and C. Thompson.
Trace Element Study at a Primary Copper Smelter, Volume 2. U. S.
Environmental Protection Agency, Publication No. EPA-600/2-78-065b (NTIS
No. PB286991). 1978.
560
-------
25. Dietzmann, H. E., M. A. Parness, and R. L. Bradow. Emissions from
Gasoline and Diesel Delivery Trucks by Chassis Transient Cycle,
ASME 81-DGP-6. 1981.
26. Core, J. E., J. A. Cooper, and R. T. DeCesar. Iowa Source Apportionment
Study. Report Prepared for U. S. Environmental Protection Agency Region
VII by NEA, Inc. 1982.
27. Core, J. E., et al. A Study of Residential Wood Combustion Task 1 -
Ambient Air Quality Impact Analysis. Report Prepared for U. S.
Environmental Protection Agency, EPA Region X by NEA, Inc. 1982.
28. Cooper, J. A. Hissoula. Montana Source Apportionment Study. Final
Report to the State of Montana, Department of Health, NEA, Inc. 1980.
29. Greenburg, R. R., W. H. Zoller, and G. E. Gordon. Composition and Size
Distribution of Particles Released from Refuse Incineration. Environ.
Sci. Techno!. 12:566. (1978).
30. Friedlander, S. K. Chemical Element Balances and Identification of Air
Pollution Sources. Environ.Sci.Technol. 7:3. (March 1973),
31. Leach, J. T., G. Bates, and L. Stanfield. San Joaquin Valley
Particulate Matter Study. Unpublished, 1979.
32. Core, J. E., J. A. Cooper, R. T. DeCesar, and J. E. Houck. South Bend,
Indiana Aerosol Study. NEA, Inc. Unpublished. 1981.
33. Stiles, D. C. Evaluation of an S2 Sampler for Receptor Modeling of
Woodstove Emissions. Proceedings of the 76th Annual Meeting, APCA.
1983.
34. Dasch, J. M. Particulate and Gaseous Emissions from Woodburning
Fireplaces. Environ. Sci. Technol. 16:10. (1982).
3i. Muhlbaier, J. L. A Characterization of Emissions from Wood-Burning
Fireplaces. General Motors Research Laboratory, GMR-3730. 1981.
36. Muhlbaier, J. L. and R. Williams. Fireplaces, Furnaces and Vehicles as
Emission Sources of Particulate Carbon. General Motors Research
Laboratory Report, GMR-3462. 1980.
37. Greenberg, R. R., G. E. Gordon, and W. H. Zoller. Composition of
Particles Emitted from the Nicosia Municipal Incinerator. Environ. Sci.
Technol. 12:11. (1978).
38. Edwards, L. 0., et al. Trace Metals and Stationary Conventional
Combustion Processes. U. S. Environmental Protection Agency,
Publication No. EPA-600/7-80-155 (NTIS No. PB80-216161). 1981.
561
-------
39. Ondov, J. M., et al. Elemental Emissions from a Coal-Fired Power Plant,
Comparison of a Venturi Wet Scrubber System with a Cold-Side
Electrostatic Precipitator. Environ. Sci. Techno!. 13:5. (1979).
40. Stevens, R. K., et al. Mathematical and Empirical Receptor Models:
Quail Roost II. U. S. Environmetal Protection Agency ORD/ESRL, Research
Triangle Park, NC. 1983.
41. Pierson, W. R. and W. D. Brachaczek. Particulate Matter Associated with
Vehicles on the Road II. Aerosol Science and Technology. 2:1. (1983).
42, Cooper, J. A. Potlack Corporation Aerosol Characterization Study.
Final Report to the Potlack Corporation, Unpublished. September 1979.
43, Houck, J. E., et al. East Helena Source Apportionment Study. Report to
the State of Montana by NEA, Inc. 1982.
44. Cooper, 0. A. and J. E. Houck. Butte Montana Source Apportionment
Study, Prepared for State of Montana by NEA, Inc. May 1982.
45. DeCesar, R. T. and J. A. Cooper. Medford Aerosol Characterization
Study. Final Report to the State of Oregon, Department of Environmental
Quality. March 1980.
46. Watson, J. 6. Chemical Element Balance Receptor Model Methodology for
Sources of Fine and Total Suspended Particulate Matter in Portland,
Oregon. Ph.D. Thesis, Oregon Graduate Center. February 1979.
47. Mamuro, Tetsuo, Arika Mizohata, and Torahide Kubota. Elemental
Compositions of Suspended Particles Released from Iron and Steel Works.
Annual Report of the Radiation Center of Osaka Prefecture - Volume 20.
1979.
48. Cooper, J. A., et al. Determination of Source Contributions to Fine and
Coarse Suspended Particulate Levels in Petersville, Alabama. Report to
Tennessee Valley Authority by NEA, Inc. 1981.
49. Cooper, J. A., C. A. Frazier, and J. E. Houck. Seattle-Tacoma Aerosol
Characterization Study (STACS). Draft Final Report to the Puget Sound
Air Pollution Control Agency by NEA, Inc. 1983.
50. Mamuro, Tetsuo and Akira Mizohata. Elemental Compositioning of
Suspended Particles Released in Refuse Incineration. Annual Report of
the Radiation Center of Osaka Prefecture, Volume 19. 1978.
51. Hughes, T. W. and D. DeAngelis. Emissions from Coal-Fired Residential
Combustion Equipment. Proceedings of the 1981 International Conference
on Residential Solid Fuels, J. Cooper and D. Maleik, Eds., Oregon
Graduate Center. 1981.
562
-------
52. Howes, J. E,» J. A. Cooper, and J. E. Houck. Sampling and Analysis to
Determine Source Signatures in the Philadelphia Area. Draft Final
Report to U. S. Environmental Protection Agency, ESRL, Research Triangle
Park, NC. NEA, Inc. 1983.
53. Pierson, W. R. and W. W. Brachaczek. Rubber Chemistry and Technology.
47:1275-1299.
54. Shah, J. J. Measurements of Carbonaceous Aerosols Across the U. S.:
Sources and Role in Visibility Degradation. Ph.D. Thesis, Oregon
Graduate Center. 1981. "
55. Henry, R. C. Stability Analysis of Receptor Models that Use Lease
Squares Fitting. Proceedings, Receptor Model Applied to Contemporary
Pollution Problems, Air Pollution Control Association. October 1982.
56. Sckarlat, A, C. and S. Japar. Optical and Chemical Properties of
Particle Emissions from On-Road Vehicles. Journal of Air Pollution
Control Association. 33:6. (1983).
57. Watson, J. G. and N. F. Robinson. Error Analysis of Mass Balance and
Particle Scattering Budget Models for RESOLVE. Desert Research
Institute, Reno, NV. 1984.
58. Shareef, G. S. Engineering Judgement, Radian Corporation.
September 1987.
59. Cummings, Carol. Personal Communications, State of Oregon Department of
Environmental Quality. October 7, 1983.
60. Bennett, Roy L. and Kenneth T. Knapp. Characterization of Particulate
Emissions from Municipal Wastewater Sludge Incinerators. Environ. Sci.
Techno!. 16(12): 831-836. (1982).
61. DeRosier, R. and L. R. Water!and. Environmental Assessment of Watertube
Boiler Firing a Coal-Water Slurry, Volume I, Technical Results.
Prepared for U. S. Environmental Protection Agency, Publication No. EPA-
6QO/7-86-004a (NTIS No. PB86-159845). February 1986.
62. Cooper, J. A., e_t. aj.., NEA, Inc. PM10 Source Composition Library for
the South Coast Air Basin, Volume I and II. Prepared for the South
Coast Air Quality Management District, El Monte, CA. July 15, 1987.
63. Olmez, I., et. a1. Composition of Particles from Selected Sources in
Philadelphia for Receptor Modeling Applications. Journal of Air
Pollution Control Assoc. 38(11):1392-1402. (1988).
64. Gordon, G. E. and A. E. Sheffield, University of Maryland. University
of Maryland Source Library. College Park, MD. April 27, 1987.
563
-------
65, Davison, R. L,, f£. al. Environ. Sci. Technol. 13:1107-1113. (1974).
66. Norton, G. A., E. L, Dekalb, and K. L. Malaby. Environ.Sci. Technol.
20:604-609. (1986).
67. Baker, G., si. aj.. Emission Characterization of Major Fossil Fuel Power
Plants in the Ohio River Valley. Prepared for the U. S. Environmental
Protection Agency, Office of Research and Development, Research Triangle
Park, NC. 1983.
68. Kaakinen, J. W. Trace Element Study in a Pulverized Coal-Fired Power
Plant. Ph.D Thesis, University of Colorado, Boulder, CO.
69. Kowalczyk, G. S. Emission and Atmospheric Impact of Trace Elements from
a Reconverted Coal-Fired Power Plant. Presented at the 77th Annual
Meeting of the Air Pollution Control Association. San Francisco, CA.
June 24-19, 1984.
70. Markowski, G. R., and R. Filby, Environ. Sci. Technol. 19:796-804.
(1985).
71. Klein, D. H., et. al. Environ. Sci. Technol. 9:973-979. (1975).
72. Mamuro, T., A. Mizohata, and T. Kubota. Elemental Compositions of
Suspended Particles Released from Various Boilers. Annual Report of the
Radiation Center of Osaka Prefecture 20. Shinke-cho, Sakai, Osaka,
Japan. 1979.
73. Henry, W. M., and K. T. Knapp, Environ. Sci. Technol. 14:450-456.
(1980).
74. Greenberg, R. R., et. al. Environ. Sci. Technol. 12:1329-1332. (1978).
75. Houck, J. E., J. A. Cooper, L. C. Pritchett, and T. R. Wasierski.
Revised Particulate Source Profiles, East Helena, Montana. Final Report
to ASARCO, Inc. from NEA, Inc. Beaverton, OR. November 26, 1984.
76. Cooper, J. A., C. A. Frazier, and J. F. Mohan. Harbor Island Lead
Source Apportionment. Final Report to Puget Sound Air Pollution Control
Agency from NEA, Inc. Beaverton, OR. December 28, 1982.
77. Cooper, J. A., et. il. Quantitative Source Apportionment of South Bay's
Particulate Air Quality Using Receptor Modeling Methods. Final Report
to San Diego County Air Pollution Control District from NEA, Inc.
Beaverton, OR. January 30, 1987.
78. Miller, E. A., J. A. Cooper, C. A. Frazier, and L. C. Pritchett. Cubatao
Aerosol Source Apportionment Study. Final Report to CETESB, Sao Paulo,
Brazil, from NEA, Inc. Beaverton, OR. March 1985.
564
-------
79. Cooper, J. A., J. E. Houck, L. C. Pritchett, and C. A. Frazier.
Applications of Receptor Modeling Methods to Source Apportionment of
Arsenic In the Ruston-Tacoma, Washington Airshed: A Feasibility Study.
Final Report to.Puget Sound Air Pollution Control Agency from NEA, Inc.
Beaverton, OR. June 15, 1985.
80. Cooper, J. A., f_t. al. Receptor Modeling Apportionment of PM10 and
Toxic Species in Hayden, Arizona. Final Report to Region IX, U. S.
Environmental Protection Agency, by NEA, Inc. Beaverton, OR.
March 1987.
81. Benedict, R. and M. Naylor, Clark County, NV, Health District. Fine
Particulate Receptor Modeling in Las Vegas Using Combined Gaseous and
Particulate Source Profiles. Presented at the 81st Annual Meeting of
the Air Pollution Control Association, Dallas, TX. June 20-24, 1988.
82. Ondov, J. M., W. H. Zoller, and 6. E. Gordon, Environ. Scl. Techno!.
16:318-328 (1981).
83, Cass, G. R., P. M. Boone, and E. S. Macias. Emissions and Air Quality
Relationships for Atmospheric Carbon Particles in Los Angeles.
Particulate Carbon. AtmosphericLife Cycle, edited by G. T. Wolff and
R, K. Klimisch, Plenum Press, NY. 1982.
84. Ondov, J. M. A Study of Trace Elements on Particulations from Motor
Vehicles. Ph.D. Thesis, University of Maryland. 1974.
81. Thompson, C. M. Elemental Composition and Particle Size Distribution of
Mineral Dust: Field and Laboratory Studies. Ph.D. Thesis, University of
Maryland, College Park, MD. 1985.
86. Thomas, S. C., Size and Composition of Atmospheric Particles in Rural
Areas Near Washington, DC. Ph.D. Thesis, University of Maryland,
College Park, MD. 1977.
87. Ward, D. E. and C. C. Hardy, USDA Forest Services. Organic and
Elemental Profiles for Smoke from Prescribed Fires. Presented at APCA
Specialty Conference, San Francisco, CA. February 1988.
88. Rau, J. A. and J. J. Huntzicker, Oregon Graduate Center, Size
Distribution and Chemical Composition of Residential Wood Smoke.
Presented at the 78th Annual Meeting of the Air Pollution Control
Association. Detroit, MI. June 16-21, 1985.
89. DeCesar, R. T. and J. A. Cooper. Medford Aerosol Characterization study
(MACS). Final Report to Oregon Department of Environmental Quality from
Oregon Graduate Center, Beaverton, OR. February 3, 1981.
90. Mason, B., Principles of Geochemistry, 3rd Edition. John Wiley and
Sons, Inc., New York, NY. 1966.
565
-------
91. West, R. C., CRC Handbook of Chemistry and Physics, CRC Press, Boca
Raton, FL, p. F146, 65th Edition. 1984.
92. Cooper, J. A., it. aj.. Characteristics of Attached Radon-222 Daughters
Under Both Laboratory and Field Conditions with Particular Emphasis Upon
Underground Uranium Mine Environments. Battelle Northwest Laboratories
Report BN-SA-299, Rich!and, WA. December 1973.
93. Cooper, J. A., C. A. Frazier, and J. E. Houck. Seattle-Tecoma Aerosol
Characterization Study (STACS). Final Report to Puget Sound Air
Pollution Control Agency from NEA, Inc., Beaverton, OR. March 1, 1985.
566
-------
APPENDIX A
PM PROFILE LISTING
-------
A-2
-------
TABLE A-l. PROFILE LISTING
Profile
Number
11201
11202
11203
11204
11205
11206
11207
11208
11209
11210
11211
11212
11213
11214
11215
11301
11501
11502
11503
11504
11505
11506
11507
11508
11509
11510
11801
12201
Profile Name
Coal -Fired Power Plant
Coal -Fired Power Plant
Coal -Fired Power Plant
Coal -Fired Power Plant
Coal -Fired Power Plant
Coal -Fired Power Plant
Coal -Fired Power Plant
Coal -Fired Power Plant
Coal -Fired Power Plant
Coal -Fired Power Plant
Coal -Fired Power Plant
Coal -Fired Power Plant
External Combustion - Coal -Fired Composite
Uncontrolled Coal -Fired Power Plant Composite
Coal -Fired Power Plant/ESP Composite
Coal and RDF-Fired Power Plant
Oil -Fired Power Plant
Oil -Fired Power Plant
Oil -Fired Power Plant
Oil -Fired Power Plant
Oil -Fired Power Plant
Oil -Fired Power Plant
Oil -Fired Power Plant
Oil -Fired Power Plant
Oil -Fired Power Plant
Oil -Fired Power Plant Composite
Wood- Fired Boiler
Coal -Slurry Fired Boiler
Page
Number
30
32
34
35
37
38
39
40
41
42
43
44
45
46
47
48
50
52
54
56
58
60
62
64
65
67
68
70
A-3
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
12301
12704
12705
13501
13502
13503
13504
14101
14102
15101
17105
17106
17107
17108
17109
17120
17121
17122
17123
17124
19101
20101
20102
20103
20401
20402
20403
20404
Profile Name
Kerosene-Fired Boiler Composite
Wood-Fired Boiler
Wood-Fired Boiler Composite
Residual Oil Combustion
Heavy Oil -Fired Boiler Composite
Indonesian Oil-Fired Boiler Composite
Oil -Fired Boiler
External Combustion - Waste Oil-Fired Boiler
External Combustion - Liquid Waste-Fired Boiler
External Combustion - Solid Waste-Fired Boiler
Municipal Incinerator (Philadelphia)
Municipal Incinerator Composite
Municipal Incinerator (East Chicago, IN)
Municipal Incinerator (Philadelphia)
Car Shredder
Sewage Sludge Incineration - Composite
Sewage Sludge Incineration
Sewage Sludge Incineration
Sewage Sludge Incineration
Sewage Sludge Incineration
Scrap Copper Incinerator
Aluminum Foundry - Reverberatory Furnace
Secondary Aluminum Plant - Dross Recovery Furnace
Secondary Aluminum - Dross Recovery Furnace
Secondary Lead Smelter - Blast Furnace
Secondary Lead - Sanitary Baghouse
Secondary Lead - Reverberatory Furnace
Secondary Lead - Melting Pot Fugitives
Page
Number
72
73
75
76
78
79
80
81
82
83
295
297
299
300
302
303 !
305
307
309
311
191
193
195
197
198
200
201
202
A-4
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
20405
20406
20501
20S02
20503
21101
21102
21103
21150
21203
21204
21205
21206
21301
21302
21303
21304
21320
21340
21401
21501
22101
22102
22201
22202
22301
23103
23202
24101
Profile Name
Secondary Lead - Melting Pot Stack
Secondary Lead - Yard Dust
Zinc Oxide Kiln
Antimony Oxide Plant - Antimony Roasting
Antimony Oxide Plant - Antimony Roasting
Limestone Dust
Primary Lead Smelting - Ore Concentrate
Primary Lead Smelting - Ore Concentrate Composite
Primary Lead Smelting - Materials Handling Composite
Coke Dust
Coal Oust
Primary Lead Smelting - Speiss Fugitive Dust
Primary Lead Smelting - Soda Flux Fugitive Dust
Copper Ore Crushing
Copper Ore Mill Wastepile
Copper Ore Concentrate
Copper Mining Waste
Copper Ore Processing Composite
Composite of Copper Ore Concentrate and Mining Waste
Feed and Grain Handling Dust
Primary Lead Smelting - Slag Dust
Parti cleboard Dryer
Particleboard Dryer
Wood Products - Sanderdust
Sawdust
Veneer Dryer
Kraft Recovery Furnace
Lime Kiln
Sulfite Recovery Boiler
Page
Number
203
204
205
207
209
225
117
119
121
227
229
123
125
127
129
131
133
135
137
113
139
273
275
277
279
281
283
285
287
A-5
-------
TABLE A-l. PROFILE LISTING (Continued)
Prof i 1 e
Number
25201
25302
25401
25402
25403
25404
25405
25406
25407
25408
25409
25410
25411
25412
25413
25414
25415
25701
25702
25703
26101
26202
26203
26204
26205
26206
26207
26208
26209
Profile Name
Calcium Carbide Furnace
Charcoal Hanufacturing
Silica Hanufacturing
Asphalt Roofing Manufacturing
Paint Spray Booth
Urea Fertilizer Production
Boric Acid Manufacturing
Carborundum Minufacturing
Phosphorous Plant Plume
Fertilizer Production - Phosphate Rock Dust
Ammonium Nitrate - Prill Tower
Ammonium Sulfate Production
Di ammonium Phosphate Plant
Superphosphate Plant
Superphosphate Granulation
Sodium Tripolyphosphate - Cyclone Dust
NPK Fertilizer
Metal Fabrication - Galvanizing (ZnO)
Metal Fabrication - Sandblasting
Metal Fabrication - Welding
Refinery Process Heaters (Gas)
Petroleum Refinery Catalytic Cracker
Petroleum Refinery Catalytic Cracker
Petroleum Refinery Catalytic Cracker
Petroleum Refinery Catalytic Cracker
Coke Calciner
Green Coke Dust
Coke Cooler
Catalytic Cracker Composite
Page
Number
231
89
233
235
291
91
93
237
95
97
99
100
101
103
105
107
109
315
316
317
255
257
259
261
262
264
265
267
269
A-6
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
27102
27201
27203
27204
27205
27501
27502
27503
27601
27602
28201
28202
28301
28302
28303
28304
28305
28306
28307
28401
28601
29101
29102
29201
29202
29203
Profile Name
Glass Furnace
Cement Kiln (Gas-Fired)
Cement Kiln (Coal -Fired)
Portland Cement Dust
Cement Ball Mill
Gypsum Calciner
Gypsum Handling
Gypsum Kiln
Lime Handling
Lime Kiln
Cast Iron Induction Furnace
Cast Iron Cupola
Steel Production - Steel Sinter Plant
Steel Production - Open Hearth Furnace
Steel Production - Basic Oxygen Furnace
Iron Ore Dust - Sinter
Steel Electric Arc Furnace
Steel Desulfurization Baghouse Dust
Steel Production - Basic Oxygen Furnace
Ferromanganese Furnace
Steel Foundry - Steel Heat Treating (Salt Quench)
Aluminum Processing
Aluminum Reduction Potline
Copper Oxide Kiln
Primary Copper Smelter
Primary Copper Reverberatory Furnace -
Page
Number
239
241
243
245
246
247
249
250
251
252
210
212
141
143
145
147
214
148
149
151
216
153
155
218
157
159
29204
Slag Tap
Primary Copper Reverberatory Furnace -
Slag Skim & Pour
160
A-7
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
29205
29206
29207
29208
29209
29210
Profile Name
Primary Copper
Primary Copper
Primary Copper
Slag Tap
Primary Copper
Primary Copper
Primary Copper
Converter
converter
- Secondary Hood
- Secondary Hood
Flash furnace - Matte and
- Process
- Roaster
Reverberal
Stack
;ory Furnace
Page
Number
161
162
163
164
165
166
29211
29301
29302
29303
29304
29305
29306
'29307
29309
29310
29311
29330
29501
29502
31101
31102
31103
31104
31105
Fugitives Composite
Primary Copper Converter - Secondary Hood
Composite
Primary Lead Smelting
Primary Lead Smelting
Primary Lead Smelting
Primary Lead Smelting
Primary Lead Smelting
Primary Lead Smelting
Primary Lead Smelting
Slag Pouring
Blast Furnace
Zinc Fuming
Sintering
Blast Furnace Upset
Zinc Baghouse
Dross Reverberatory Furnace
Sinter Production
Primary Lead Smelting
Primary Lead - Dross Building
Primary Lead - Slag Pour
Primary Lead Smelting - Composite
Secondary Copper Pyrometal - Cathode Charge
Secondary Copper Pyrometal - Regular Charge
Light-Duty Vehicles
Heavy-Duty Vehi cles
Light-Duty Vehicles
Light-Duty Vehicles
Light-Duty Vehicles
Leaded
Leaded
Leaded
Leaded
Leaded Composite
167
168
170
172
174
176
178
180
182
184
185
186
220
221
489
491
493
495
497
A-8
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
31201
31202
31203
31230
32101
32102
32103
32104
32202
32203
32204
32205
32206
33001
33002
33003
33004
33005
33006
33007
33008
33009
33010
33011
33020
34001
34002
34003
34004
Profile Name
Light-Duty Vehicles - Unleaded
Light-Duty Vehicles - Unleaded
Light-Duty Vehicles - Unleaded
Light-Duty Vehicles - Composite
Light-Duty Vehicles - Diesel
Light-Duty Vehicles - Diesel
light-Duty Vehicles - Diesel
Light-Duty Vehicles - Diesel Composite
Heavy-Duty Diesel
Heavy-Duty Vehicles - Diesel
Heavy-Duty Vehicles - Diesel
Diesel Vehicles - Las Vegas Valley (1987)
Heavy-Duty Vehicles - Diesel Composite
Leaded/Unleaded Gasoline Composite - 1977
Transportation Composite - Medford, Oregon (1980)
Transportation Composite - Portland, Oregon (1979)
Transportation Composite
Transportation Composite
Transportation Composite
Transportation Composite
Transportation Composite
Transportation Composite
Gasoline Vehicles - Las Vegas Valley (1987)
Highway Vehicles Composite
Transportation Composite
Jet Aircraft
Tire Wear
Tire Wear
Brake Lining, Asbestos
Page
Number
498
500
502
504
506
508
510
512
513
515
517
518
519
S20
522
524
526
528
530
532
534
536
538
539
541
551
543
545
546
A-9
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
34005
34006
41101
41102
41103
41104
41105
41106
41107
41109
41110
41111
41112
41113
41114
41115
41116
41117
41118
41119
41120
41121
41122
41123
41124
41130
41131
41132
41133
Profile Name
Motor Oil
Semi -metal Disk
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Paved Road Dust
Brake Pads
- Missoula, Montana
- Juneau, Alaska
- Lewiston, Idaho
- Butte, Montana
- East Helena, Montana
- Medford, Oregon
- Portland, Oregon
- Alabama
- Spokane, Washington
- Pasadena Freeway (CA)
- Artesia Freeway (CA)
- Long Beach Boulevard (CA)
- Long Beach, CA
- La Cienega Boulevard (CA)
- Hawthorne, CA
- Victory Boulevard (CA)
- Burbank, CA
- North Main Street (Los Angeles, CA)
- Los Angeles, CA
- South Harbor Blvd (Anaheim, CA)
- Anaheim, CA
- Riverside, CA
- Sepulveda Tunnel (Los Angeles, CA)
- Composite
- Composite
- Long Beach Composite
- Hawthorne Composite
Page
Number
547
548
337
339
341
343
345
346
348
350
352
354
356
357
358
360
361
362
363
365
367
368
369
370
372
374
376
377
378
A-10
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
41134
41135
41136
41137
41201
41203
41204
41205
41220
41301
41302
41303
41304
41305
41306
41307
41308
41309
41310
41311
41312
41313
41314
41315
41316
41318
41319
41320
41321
Profile Name
Paved Road Dust - Burbank Composite
Paved Road Dust - Los Angeles Composite
Paved Road Dust - Anaheim Composite
Paved Road Dust - SCAB Composite
Unpaved Road Dust (Copper Mine)
Unpaved Road Dust - Haul Road
Unpaved Road Dust - East Helena, Montana
Unpaved Road Dust-Riverside, CA
Unpaved Road Dust Composite
Soil Dust - Des Moines, Iowa
Soil Dust - Seattle, Washington
Soil Dust - Visalia, California
Soil Dust - South Bend, Indiana
Soil Dust - Houston, Texas
Soil Dust - East Helena, Montana
Soil Dust - Idaho
Soil Dust - Creston, Iowa
Soil Dust - Council Bluffs, Iowa
Soil Dust - Sioux City, Iowa
Soil Dust - Cedar Rapids, Iowa
Soil Dust - Davenport, Iowa
Soil Dust - Spokane, Washington
Soil Dust - Boise, Idaho
Soil Dust - Bakersfield, California
Soil Dust - Pasedena, California
Soil Dust - Medford, Oregon
Soil Dust - Portland, Oregon
Soil Dust - Alabama
Soil Dust - Laurel, MD
Page
Number
379
380
381
382
327
329
331
332
333
389
391
393
395
397
399
401
403
403
407
409
411
413
415
417
419
421
423
425
427
A-ll
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
41322
41323
41324
41350
41351
41401
42101
42102
42103
42201
42202
42301
42302
42303
42304
42305
42306
42307
42308
42309
42310
42311
42312
42313
42314
42315
42316
42317
42318
Profile Name
Soil Dust - Washington, DC Area
Soil Dust - Riverside, CA
Soil Dust - Hawthorne, CA
Soil Dust - Composite
Soil Dust - SCAB Composite
Road Sand and Salt Mix
Woodstoves - Pine Fuel
Woodstoves - Average, All Fuels
Woodstoves - Oak Fuel
Fireplaces - Softwoods
Fireplaces - Hardwoods
Slash Burning
Slash Burning
Residential Wood Combustion - Composite
Agricultural Field Burning
Slash Burning (Conifer - Flaming Phase)
Slash Burning (Conifer - Smoldering Phase)
Slash Burning (Hardwood - Flaming Phase)
Slash Burning (Hardwood - Smoldering Phase)
Slash Burning (Ponderosa Pine - Flaming Phase)
Slash Burning (Ponderosa Pine - Smoldering Phase)
Slash Burning (Tractor Piled - Flaming Phase)
Slash Burning (Tractor Piled - Smoldering Phase)
Slash Burning (Crane Piled - Flaming Phase)
Slash Burning (Crane Piled - Smoldering Phase)
Slash Burning (Chaparral - Flaming Phase)
Slash Burning (Chaparral - Smoldering Phase)
Wood Combustion - Las Vegas Valley (1987)
Residential Wood Combustion
Page
Number
428
429
430
431
433
384
447
449
451
453
455
478
480
457
482
459
460
461
462
463
464
465
466
467
468
469
470
471
472
A-12
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
42319
42320
42330
43101
43201
43301
43302
43303
43304
43305
43306
43307
43308
43309
44101
44102
44103
44104
Profile Name
Residential Wood Combustion Composite
Agricultural Field Burning Composite
Composite of Residential Wood Burning Sources
Marine Aerosol
Residential Space Heating - Coal
Volcanic Ash
Orchard Heating - Smudge Pots
Coal -Fired Power Plant Flyash
Limestone, Crustal
Shale, Crustal
Sandstone, Crustal
Sediment, Crustal
Igneous, Rock
Earth's Crust
Excavation - El Segundo, CA
Excavation - Haul Road
Rock Crushing
Sandblasting and Plastering
Page
Number
473
484
474
434
554
436
556
84
438
439
440
441
442
443
321
322
323
324
A-13
-------
A-14
-------
APPENDIX B
PM PROFILE CALCULATIONS
-------
B-2
-------
APPENDIX B
PH PROFILE CALCULATIONS
This appendix provides details of the procedures used for calculating
composition data for the 0-10 urn size interval and uncertainty associated with
composition data for the 0-10 um size range. The calculational procedures are
based on the methodologies outlined in the Receptor Model Source Composition
Library and the first edition of the Air Emissions Species Manual, This
appendix also discusses the assumptions used in filling profile data gaps. In
the following calculations, values for the following entries in the profiles
were set to zero: NA (not analyzed), NR (not reported), and < (less than
detection limit). The calculations discussed in this appendix involve
combining composition data reported in the Source Composition Library with
size distribution data compiled primarily from AP-42. An additional
uncertainty is introduced into the calculations since the composition data and
size distribution data were developed for different sources,
In addition to procedures for calculating composition data for the 0-
10 um, a methodology that can be used to estimate composition data for the
2.5-6 um and 6-10 um size intervals is also presented in this appendix.
However, as discussed below, the application of this methodology is limited.
B.I CALCULATION OF COMPOSITION DATA FOR PM10 (0-10 um)
According to the Source Composition Library, page 11-34, PM10
composition is calculated as:
"1J, 0-1.0 * ('2.5J/'iSlj) "1J.O-2.5 + 11 ~ (' 2.5J/riOj) J "lJ,2.3-10
Where:
AU.O-IO - PM10 composition data (weight percent) for species i
in emissions from source J
?2.sj - fraction of mass in the 0-2.5 um size interval in
source J emissions
B-3
-------
F10J - fraction of mass in the 0-10 urn size interval in
source J emissions
Aij,o-2.3 = composition data (weight percent) for fine fraction
(<2.5 urn) for species i in emissions from source J
A*u 2.5-10 * composition data (weight percent) for coarse fraction
(2.5-10 urn) for species i in source J
This equation is derived from the following basic relationship:
NEM1J<0.10 - NEMIJ(0_2.S + NEMIJ(2,5_10 (2)
where NEM is defined as the normalized elemental mass (mass fraction x weight
percent). For example,
NEHu.o.jo - F10J x Au.0_10 (3)
As shown schematically in Figure 1, a plot of NEM versus particle size would
lead to a curve increasing with particle size. Equation (1) is illustrated
below for Profile 17105;
Let:
J = Municipal Incinerator (MI) - Profile 17105
i = Al (aluminum)
F2.s,Mi " 0-26 (see Profile 17105)
FIO.MI = 0.38 (see Profile 17105)
AAI.MI,0-2.5 = 0.819 (see Profile 17105)
AAI.MJ,2.5-10 - 5.827 (see Profile 17105)
Then:
AAI.MI.O-IO " (0.26/0.38) (0.819) + [1 - (0.26/0.38)] 5.827
AAI,MI,o-io = 0.560 + 1.840 = 2.400 percent
B-4
-------
LU
z
Particle Size
Figure 1. Normalized Elemental Size versus Particle Size
B-5
-------
B.2 CALCULATION OF COMPOSITION DATA FOR THE 2.S-6 urn AND 6-10 um INTERVALS
As indicated above, the application of the following methodology for
estimating composition data for the 2.5-6 um and 6-10 um size intervals from
data for the 2.5-10 um size interval is limited. This limitation is largely
due to the fact that the mass fraction data and composition data used in these
calculations are from different sets of data and represent different emission
sources.
Having estimated the PM10 composition and NEM1J(0_10, a simple linear
relationship can be assumed to exist between NEMU>0_2.5 and NEM1J(0.10 over the
size interval 2.5-10 um. The equation for this relationship can be
represented by the following:
(NEH1J(0.10 - NEM1J(0_2.5)
NEMU>0_X = _ (X - 2.5) + NEMIJ(0_2.5 (4)
(10 -2.5)
Where X is the particle size of interest.
Substituting X = 6 um will yield NEMU>0_6 which can be used in the
following equation to solve for AtJ)2_5_6.
NEMUt_ - NEMlJi0_2,5 + NEMIJ>2,5.6 (5)
Similarly, the value for AlJi6_10 can be estimated from Equation (6):
NEM1J>0.10 - NEMU>0.6 + NEMIJ>6.10 (6)
Using the same example data set,
HI 0.10 - NEMAl;HIj0_2.5)
(6 - 2.5) + NEMA1(MI,0_2.S
(10 - 2.5)
= [(0.38 x 2.400) - (0.26 x 0.819)]
___
NEMAlfKI<0_6 = 0.326 + 0.213-0.539
(3.5) + (0.26 x 0.819)
B-6
-------
From Equation (5),
NEMAl>MI)0,6 = NEMAljMI>0_2.5 + NEMAl(Mi(2.5_6
0.539 = (0.26 x 0.819) + (F2.5.6,MI x AA1,MI)2,5.6)
'2.5-6,MI = '6,MI ~ '2.5.MI
FS.MI = 0.31 (see Profile 17105)
F2.s,Mi " 0.26 (see Profile 1710S)
F2,5-6,MI * 0.05
Therefore,
AAi,Mi,2.5-6 " (0.539 - 0.213) / 0.05 = 6.521 percent
Using Equation (6),
NEMA1(MIj0.10 = NEMAliHI(0.6 + NEMAl(MI>6.10
(0.38 x 2.400) - 0.539 + F6_l0(ia X AMjHIi6,10
F - F - F
'6-10, MI ~ '10,MI '6,MI
AAl,Hi,6-io - (0-912 - 0.539) / 0.07 = 5.329 percent
B.3 CALCULATION OF UNCERTAINTY ASSOCIATED WITH COMPOSITION DATA FOR PM10
According to the Receptor Model Source Composition Library, page 11-35,
the uncertainty of the PH10 coiposition data can be calculated by propagation
of errors in quadrature as follows:
— r f a /F^2 2 j-fF /F2^2fi2 2
0"iJ,10 ~ LVHiJ,0-2,5 / '10J/ O F2.SJ "^ \'2.5J / ' 1QJ/ " iJ,0-2.5 ff F10J
x (f / F )2 „ 2 , (A / C \ 2
T \'2.5J / r!OJ/ O AiJ.0-2.5 T V"iJ,2.5-10 / r!OJ/ O F2.5J
(' 2.5J / r 10j) A u,2.5-10 (J
F10J
B-7
-------
Where g 2F2iSJ and cr2F10J denote the variances associated with mass fraction
data for the 0-2.5 urn and 0-10 urn size intervals and a zAiJi0.2.5 and cr 2A1j)2.5-io
represent the variances associated with the composition data for the fine and
coarse size fractions. This equation is illustrated below for Profile 42302:
Let:
J « Slash burning (SB) - Profile 42302
i = K (potassium)
FI.S.SB = 0-90 (see Profile 42302)
FIO.SB - 0-99 (see Profile 42302)
AK,sB,o-2.5 s 0-620 (see Profile 42302)
AK,ss,2.5-io = 1-250 (see Profile 42302)
K,SB,0-2.5 = 0.235 (see Profile 42302)
K,SB,2.5-10 = 0.212 (see Profile 42302)
Since a F2.5,SB and a F10,SB are not available, assume the following:
0T,2.5,SB - 0.1 F2.5,SB = 0.090
0-F10.SB = 0.1 F10,SB = 0.099
Then:
aK»SB,10 » [(0.62/0.99)2 (0.09)2 + (0.90/0.992)2 (0.62)2 (0..099)2
+ (0.90/0.99)2 (0.235)2 + (1.250/0.99) (0.009)2
+ (0.90/0.992)2 (1.250)2 (0.099)2 + (0.90/0.99) (0.212)2]1/2
- [0.0032+0.0032 + 0.0456 + 0.0102 + 0.0129 + 0.0409]l/2
- (0.11599)1/2 - 0.341
B-S
-------
B.4 ASSUMPTIONS USED IN FILLING DATA GAPS
In several profiles from the Source Composition Library, composition
data information for one or two size intervals were not reported. To increase
the usefulness of the profiles, certain assumptions were employed to fill
these data gaps.
If data are reported for a single size interval, assume data for
the other two intervals are the same. Values for the 0-10 um size
interval are also assumed to be the same.
If data for the 0-2.5 um size interval are missing, assume the
data for the 2.5-10 um size interval can be substituted and vice
versa. Values for the 0-10 um size interval are also assumed to
be the same.
If data for the total particulate measured are not reported,
assume the estimated data for the 0-10 um size fraction can be
substituted.
These assumptions are indicated on each profile with appropriate footnotes.
B.5 DEVELOPMENT OF COMPOSITE AND INDUSTRY-SPECIFIC AVERAGE PROFILES
In developing composite profiles, the average composition and
uncertainty data were calculated from the individual profiles for the
following intervals: 0-2.5 um, 2.5-10 um, and total particulate measured.
The uncertainty values were averaged for a given size interval and .a given
species using the following equation:
n
a average " [ a k2 / n]l/2 (8)
k-1
Where:
raverage = average uncertainty associated with a particular
species in a particular size range in the composite
profile
B-9
-------
0"k s uncertainty associated with a particular species in a
particular size range in profile k
n = number of profiles composited.
Calculations involving composition data for the 0-10 urn fraction and
uncertainty information for the 0-10 urn fraction were then completed for the
composite profile.
In developing the industry-specific average profiles, the procedure
described above for the composite profiles was employed.
B-10
-------
APPENDIX C
PARTICLE SIZE DISTRIBUTION DATA
-------
C-2
-------
APPENDIX C
PARTICLE SIZE DISTRIBUTION DATA
This appendix discusses how the particle size distribution data
(i.e., fraction of mass in a given size interval) presented in the PM profiles
in Section 3.0 are compiled. The mass fraction data can be coupled with the
size-specific composition data in a given profile to estimate size-specific
and speciated particulate emissions.
A large proportion of the particle size distribution data are obtained
from Supplement A of AP-42. For about 45 percent of the PM profiles in the
Source Composition Library, mass fraction data were extracted from this
document. For several profiles, only generic particle size distribution data
were identified in Supplement A of AP-42.
Data from other sources were used to characterize those profiles for
which mass fraction data did not exist in Supplement A of AP-42. Table C-l
presents a listing of profiles where the information source for the mass
.fraction data is specified and a data quality indicator is included. The
quality indicators are primarily based on the ratings used in Supplement A of
AP-42 for cumulative size-specific emission factors. The ratings designated
for the size-specific emission factors are assumed to represent the quality
associated with the particle size distribution data.
Data based on generic size distributions in AP-42 are assigned a rating
of "D" whereas the default value is assigned a rating of "E." The default
value represents the overall average of the size distribution data based on
all the profiles. It is used for profiles where no size distribution data
were identified. In cases where engineering judgement was employed in
applying size distribution data for a specific profile to a profile
representing a similar source category, the rating scheme is modified to
reflect this assumption.
Calculation of mass fraction data from the information contained in AP-
42 is illustrated below for Profile 28301 - Steel Production - Steel Sinter
Plant (control device: baghouse). On page 7.5-11 from AP-42,
C-3
-------
TABLE C-l.
Profile
Number
00000
11201
11202
11203
11204
11205
11206
11207
11208
11209
11210
11211
11212
11213
11214
11215
11301
11501
11502
11503
Mass Fraction
Data Quality
I
0
C
E
D
D
D
D '
D
D
D
,c
E
D
C
D
D
C
C
C
Information Source
Default value
AP-42 (Reference 1}
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1}
AP-42 (Reference 1)
AP-42 (Reference 1}
AP-42 (Reference 1}
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1}
AP-42 (Reference 1)
AP-42 (Reference 1)
Based on data from Profiles 11202 and 11211
Based on data from Profiles 11204-11208,
11210, and 11212
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
C-4
-------
TABLE C-l. (Continued)
Profile
Number
11504
11505
11506
11507
11508
11509
11510
11801
12201
12301
12704
12705
13501
13502
13503
13504
14101
14102
15101
Mass Fraction
Data Quality
C
C
C
C
C
C
C
E
C
E
E
E
D
E
E
D
E
E
E
Information Source
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
Based on data from Profiles 11502-11509
AP-42 (Reference 1)
Based on data from Reference 7
Based on AP-42 (Reference 1) data
distillate oil firing
AP-42 (Reference^)
AP-42 (Reference 1)
AP-42 (Reference 1)
Based on AP-42 (Reference 1) data
residual oil firing
AP-42 (Reference 1)
AP-42 (Reference 1)
Based on AP-42 (Reference 1) data
residual oil firing
Based on AP-42 (Reference 1) data
residual oil firing
AP-42 (Reference 1)
for
for
for
for
C-5
-------
TABLE C-l. (Continued)
Prof i 1 e
Number
17105
17106
17107
17108
17109
17120
17121
17122
17123
17124
19101
20101
20102
20103
20401
20402
20403
20404
Mass Fraction
Data Quality
D
E
D •
D
E
C
C,
C
C
C
E
D
D
D
D
D
D
D
Information Source
AP-42 (Reference 1)
Based on data from Profile 17105
AP-42 (Reference 1)
AP-42 (Reference 1)
Default value
Average of data from Profiles 17121
and 17124
Based on data from Reference 5
Average of data from Profiles 17121
and 17124
Average of data from Profiles 17121
and 17124
Based on data from Reference 5
Based on data from Profile 17105
AP-42 (Reference 1)
AP-42 - generic size distribution
(Reference 1)
AP-42 (Reference 1) - generic size
distribution
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
C-6
-------
TABLE C-l. (Continued)
Profile
Number
20405
20406
20501
20502
20503
2110
21102
21103
21150
21203
21204
21205
21206
21301
Mass Fraction
Data Quality
D
E
D
D
D
D
D
D
D
D
D
E
E
D
Information Source
AP-42 (Reference 1}
Based on data from Profile 20403
AP-42 - generic size distribution
(Reference 1)
AP-42 - generic size distribution
(Reference 1}
AP-42 (Reference 1} - generic size
distribution
AP-42 - generic size distribution
(Reference 1)
AP-42 - generic size distribution
(Reference 1)
AP-42 (Reference 1)
Average data based on Profiles 21102,
21103, and 21206
AP-42 - generic size distribution
(Reference 1)
AP-42 - generic size distribution
(Reference 1)
Based on data from Profile 21103
Based on data from Profile 21103
AP-42 - generic size distribution
21302
(Reference 1}
AP-42 - generic size distribution
(Reference 1}
C-7
-------
TABLE C-l. (Continued)
Profile
Number
21303
21304
21320
21340
21401
21501
22101
22102
22201
22202
22301
23103
23202
24101
25201
25302
Mass Fraction
Data Quality
D
D
D
D
D
D
E
E
E
E
D
C
C
C
D
D
Information
Source
AP-42 - generic size distribution
(Reference 1)
AP-42 - generic size distribution
(Reference 1)
Average data for Profil
and 21302
Average data for Profil
and 21304
AP-42 (Reference 1}
AP-42 - generic size di
(Reference 1)
Default value
Default value
AP-42 (Reference 1)
Default value
AP-42 - generic size di
(Reference 1}
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 - generic size di
(Reference 1)
AP-42 - generic size di
(Reference 1)
es 21301
es 21303
stribution
stribution
stribution
stribution
C-8
-------
TABLE C-l. (Continued)
Profile
Number
25401
25402
25403
25404
25405
25406
25407
25408
25409
25410
25411
25412
25413
25414
25415
25701
Mass Fraction
Data Quality
E
D
D
0
E
E
D
D
E
C
D
D
D
D
D,
D
Information Source
Default value
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 - generic size
(Reference 1)
AP-42 (Reference 1)
Default value
AP-42 - generic size
(Reference 1)
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
distribution
generic size
generic size
generic size
generic size
generic size
generic size
generic size
distribution
C-9
-------
TABLE C-l. (Continued)
Profile
Nuiber
25702
25703
26101
26202
26203
26204
26205
26206
26207
26208
26209
27102
27201
27203
27204
Mass Fraction
Data Quality
D
D
D
E
D
D-
D
D
D
D
D
E
D
D
D
Information Source
AP-42 (Reference 1) - generic
distribution
AP-42 (Reference 1) - generic
distribution
size
size
AP-42 - generic size distribution
(Reference 1)
Default value
AP-42 (Reference 1) - generic
distribution
AP-42 (Reference 1) - generic
distribution
AP-42 (Reference 1) - generic
distribution
AP-42 (Reference 1) - generic
distribution
AP-42 (Reference 1) - generic
distribution
AP-42 (Reference 1) - generic
distribution
Based on data from Profiles
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1) - generic
size
size
size
size
size
size
26203-26205
size
27205
distribution
AP-42 (Reference 1) - generic size
distribution
C-10
-------
TABLE C-l. (Continued)
Profile
Number
27501
27B02
27503
27601
27602
28201
28202
28301
28302
28303
28304
28305
28306
28307
28401
28601
Mass Fraction
Data Quality
0
D
D
D
D
D
C
C
E
D
C
E
D
C
B
D
Information Source
AP-42 - generic size
(Reference 1)
AP-42 (Reference 1)
distribution
AP-42 (Reference 1)
distribution
AP-42 (Reference 1)
distribution
AP-42 (Reference 1)
distribution
AP-42 - generic size
(Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 - generic size
distribution
- generic size
- generic size
- generic size
- generic size
distribution
distribution
29101
(Reference 1)
AP-42 (Reference 1)
C-ll
-------
TABLE C-l. (Continued)
Profile
Number
29102
29202
29203
29203
29204
29205
29206
29207
29208
29209
29210
29211
29301
29302
29303
29304
Mass Fraction
Data Quality
D
D
D
D
E
E
E
D
D
D
D
E
E
C
D
D
Information Source : '
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 - generic size distribution
(Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1) - generic size
distribution
AP-42 (Reference 1)
AP-42 (Reference 1)
Based on data from Profiles 29203
and 29204
Based on data from Profiles 2920B
and 29206
Average data from Profiles 29304, 29306,
29307, and 29309
AP-42 (Reference 1)
Based on data for Profile 29302
AP-42 - generic size distribution
29305
(Reference 1)
Based on data from Profile 29302
012
-------
TABLE C-l. (Continued)
Profile
Number
29306
29307
29309
29310
29311
29330
29501
29502
31101
31102
31103
31104
31105
31201
31202
31203
31230
Mass Fraction
Data Quality
D
D
D
D
D
E
D
D
C
C
C
C
C
C
C
c-
D
Information
Source
AP-42 - generic size distribution
(Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
Average data for Profi
and 29306
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 6)
AP-42 (Reference 6)
AP-42 (Reference 6)
AP-42 (Reference 6)
les 29303
generic size
generic size
Based on data from Profiles 31103
and 31104
AP-42 (Reference 6)
AP-42 (Reference 6)
AP-42 (Reference 6)
Average data from Profiles 31101
32101
and 31201
AP-42 (Reference 6)
C-13
-------
TABLE C-l. (Continued)
Profile
Number
32102
32103
32104
32202
32203
32204
32205
32206
33001
33002
33003
33004
33005
33006
33007
33008
33009
33010
33011
Mass Fraction
Data Quality
C
c
C
c
c
c
c
c
c
D
D
D
D
D
D
D
D
D
D
Information Source
AP-42 (Reference 6)
AP-42 (Reference 6)
Based on data from Profiles 32102
and 32103
AP-42 (Reference 6)
AP-42 (Reference 6)
AP-42 (Reference 6)
AP-42 (Reference 6)
Based on data from Profiles 32204
and 32205
AP-42 (Reference 6}
Average data from Profiles 31102, 31201,
and 32101
Based on data for Profile 33001
Based on data from Reference 8
Based on data from Reference 8
Based on data from Reference 8
Based on data from Reference 8
Based on data from Reference 8
Based on data from Reference 8
Based on data from Reference 8
Based on data from Profiles 33004-33009
C-14
-------
TABLE C-l. (Continued)
Profile
Number
33020
34001
34002
34003
34004
34005
34006
41101
41102
41103
41104
41105
41106
41107
41109
41110
Mass Fraction
Data Quality
D
E
E
E
E
E
E'
0
D
D
D
D
0
D
0
D
Information Source
Average data from Profiles 33001, 33002,
and 33003
Default value
Default value
Default value
Default value
Default value
Default value
Extrapolated from data (page 41 of
Reference 2)
Extrapolated from data (page 41 of
Reference 2)
Extrapolated from data (page 41 of
Reference 2)
Extrapolated from data (page 41 of
Reference 2)
Extrapolated from data (page 41 of
Reference 2)
Extrapolated from data (page 41 of
Reference 2)
Extrapolated from data (page 41 of
Reference 2)
Extrapolated from data (page 41 of
Reference 2)
Extrapolated from data (page 41 of
Reference 2)
C-15
-------
TABLE C-l. (Continued)
Profile
Number
41111
41112
41113
41114
41115
41116
41117
41118
41119
41120
41121
41122
41123
41124
41130
41131
41132
41133
41134
41135
Mass Fraction
Data Quality
D
D
D
D
D
D
D
D'
D
D
D
D
D
D
D
D
D
D
D
0
Information Source
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data (page 41 of
Reference 2)
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
Extrapolated from data in Reference 2
C-16
-------
TABLE C-l. (Continued)
Profile
Number
41136
41137
41201
41203
41204
41205
41220
41301
41302
41303
41304
41305
41306
41307
41308
Mass Fraction
Data Quality
D
D
D
D
D
D'
D
D
D
0
D
D
D
D
D
Information
Extrapolated
Extrapol ated
Extrapolated
Reference 2)
Extrapolated
Reference 2)
Extrapol ated
Reference 2)
Extrapolated
Extrapolated
Reference 2)
Extrapolated
Reference 3)
Extrapolated
Reference 3)
Extrapolated
Reference 3)
Extrapolated
Reference 3)
Extrapolated
Reference 3)
Extrapolated
Reference 3)
Extrapolated
Reference 3)
Extrapolated
from
from
from
from
from
from
from
from
from
from
from
from
from
from
from
data
data
data
data
data
data
data
data
data
data
data
data
data
data
data
Source
in Reference 2
in Reference 2
(page
(page
(page
41
41
41
Of
Of
of
in Reference 2
(page
(page
(page
(page
(page
(page
(page
(page
(page
41
28
28
28
28
28
28
28
28
of
of
of
of
of
of
of
of
of
Reference 3)
C-17
-------
TABLE C-l. (Continued)
Profile
Number
41309
41310
41311
41312
41313
41314
41315
41316
41318
41319
41320
41321
41322
41323
41324
Mass Fraction
Data Quality
D
D
D
D
D
D
, D
D
D
D
D
D
D
D
0
Information Source
Extrapolated from data (page 28 of
Reference 3)
Extrapolated from data (page 28 of
Reference 3}
Extrapolated from data (page 28 of
Reference 3)
Extrapolated from data (page 28 of
Reference 3)
Extrapolated from data (page 28 of
Reference 3)
Extrapolated from data (page 28 of
Reference 3)
Extrapolated from data (page 28 of
Reference 3)
Extrapolated from data (page 28 of
Reference 3}
Extrapolated from data (page 28 of
Reference 3}
Extrapolated from data (page 28 of
Reference 3)
Extrapolated from data (page 28 of
Reference 3}
Extrapolated from data in Reference 3
Extrapolated from data in Reference 3
Extrapolated from data in Reference 3
Extrapolated from data in Reference 3
C-18
-------
TABLE C-l. (Continued)
Prof i 1 e
Number
413SO
41351
41401
42101
42102
42103
42201
42202
42301
42302
42303
42304
42305
42306
42307
42308
42309
42310
Mass Fraction
Data Quality
D
D
D
E
E
E.
E
E
D
D
E
D
D
D
D
D
D
D
Information Source
Extrapolated from data (page 28 of ,
Reference 3)
Extrapolated from data in Reference 3
Extrapolated from data (page 41 of
Reference 2)
Based on data from Profile 12704
Based on data from Profile 12704
Based on data from Profile 12704
Based on data from Profile 12704
Based on data from Profile 12704
Extrapolated from data (page 28 of
Reference 3)
Extrapolated from data (page 28 of
Reference 3)
Based on data from Profile 12704
Extrapolated from data (page 28 of
Reference 3}
Extrapolated from data in Reference 3
Extrapolated from data in Reference 3
Extrapolated from data in Reference 3
Extrapolated from data in Reference 3
Extrapolated from data in Reference 3
Extrapolated from data in Reference 3
c-is
-------
TABLE C-l. (Continued)
Profile
Number
42311
42312
42313
42314
42315
42316
42317
42318
42319
42320
42330
43101
43201
43301
43302
43303
43304
43305
43306
Mass Fraction
Data Quality
D
D
D
D
D
D
C
C
C
D
E
D
D
E
E
C
E"
E
E
Information Source
Extrapolated from data in Reference 3
Extrapolated from data in Reference 3
Extrapolated from data in Reference 3
Extrapolated from data in Reference 3
Extrapolated from data in Reference 3
Extrapolated from data in Reference 3
Based on data from Reference 9
Based on data from Reference 9
Based on data from Profiles 42317
and 42318
Average data from Profiles 42301, 42302,
and 42304
Average data from Profiles 42102, 42201,
42202, and 42303
Extrapolated from data (page 48 of
Reference 3)
Based on AP-42, page 1.1-11
Default value
Based on data from Profile 13501
Based on data from Reference 4
Based on data from Profile 41351
Based on data from Profile 41351
Based on data from Profile 41351
C-20
-------
TABLE C-l. (Continued)
Profile
Number
43307
43308
43309
44101
44102
44103
44104
90001
90002
90003
90004
90005
90006
90007
90008
90009
90010
90011
90012
90013
Mass Fraction
Data Quality
E
E
E
E
E
D
D
E
E
E
E
E
E
E
E
E
E.
E
E
E
Information Source
Based on data from
Based on data from
Based on data from
Based on data from
Based on data from
AP-42 (Reference 1)
distribution
AP-42 (Reference 1)
distribution
Default value
Default value
Default value
Default value
Default value
Default value
Default value
Default value
Default value
Default value
Default value
Default value
Default value
Profile 41351
Profile 41351
Profile 41351
Profile 41351
Profile 41351
- generic size
- generic size
C-21
-------
TABLE C-l. (Continued)
Profile Mass Fraction
Number Data Quality Information Source
90014 E Default value
90015 E Default value
90016 E Default value
C-22
-------
particle size distribution data are reported for sintering operations
controlled by baghouse as shown in Table 7,5-2 of AP-42.
Figure 7.5-2 of AP-42 presents the same information graphically. Since
the 0-6 urn size range is not shown in the table, the value for this range can
be obtained from the figure as 0.60. Thus, the lass fraction data required
for calculations in this document data can be summarized as follows:
Particle Size Cumulative Mass Fraction
0-2.1 urn 0.27
0-6 urn 0.60
0-10 urn 0.69
C-23
-------
Table 7.5-2. SIZE SPECIFIC EMISSION FACTORS
Source
Sintering
Windbox
Uncontrolled
Leaving grate
Controlled by wet
ESP
Controlled by
ventyri scrubber
Controlled by
cycl one6
Controlled by
baghouse
Emission
Factor
Rating
B
C
C
C
C
Particle
Size uma
0.5
1.0
2.5
5.0
10
15
d
0.5
1.0
2.5
5.0
10
15
d
0.5
1.0
2.5
5.0
10
15
d
0.5
1.0
2.5
s;o
10
15
d
0.5
1.0
2.5
5.0
10.0
15.0
d
Cumulative
Mass 7, <
Stated size
4*>
4
5
9
15
20C
100
18b
25
33
48
59*>
69
100
55
75
89
93
96
98
100
25C
37b
52
64
74
80
100
3.0
9.0
27.0
47.0
69.0
79.0
100.0
Cumulative mass
emission factor
kg/Mg (Ib/ton)
0.22 (0.44)
0.22 (0.44)
0.28 (0.56)
0.50 (1.00)
0.83 (1.67)
1.11 (2.22)
5.56 (11.1)
0.015 (0.03)
0.021 (0.04)
0.028 (0.06)
0.041 (0.08)
0.050 (0.10)
0.059 (0.12)
0.085 (0.17)
0.129 (0.26)
0.176 (0.35)
0.209 (0.42)
0.219 (0.44)
0.226 (0.45)
0.230 (0.46)
0.235 (0.47)
0.13 ' (0.25)
0.19 (0.37)
0.26 (0.52)
0.32 (0.64)
0.37 (0.74)
0.40 (0.80)
0.5 (1.0)
0.005 (0.009)
0.014 (0.027)
0.041 (0.081)
0.071 (0.141)
0.104 (0.207)
0.119 (0.237)
0.15 (0.3)
C-24
-------
SOURCE CATEGORY/CONTROLS
SINTCH PLANT WINMOV/UNCONTROLLED—
SINTEN PLANT WINMOI/CTCLONCS —
SINTE* PLANT wiNOBOx/SCfluMC* —
SINTER PLANT wiNOBOi/ESP — -
SINTER PLANT WINDSOR/BACHOUSE ——
SINTEH BME*IICN/B*CMOUSC ~—
too
EXTRAPOLATED 8V fXTEMOIMS
THE CURVES OH THE GRAPH
0.5 I.O
Z.3 S.O IO 15
PARTICLE AERODYNAMIC DIAMETER
1 micromtlfrt I
(Colculoltd according to Iht Talk Group
Dynamic* dtfinilion of Airodynamic Diorntltr)
80
60
IM
in
O
u»
in
in
m
40
in
in
•4
2O
Figure 7.5-2. Particle size distribution of sinter plant emissions.
-------
APPENDIX C REFERENCES
1. , AP-42 (GPO 055-000-00251-7), Compilation of Air Pollutant Emission
Factors, Volume I: Stationary Point and Area Sources, Fourth Edition,
U. S. Environmental Protection Agency, Research Triangle Park, NC,
September 1985.
2. Anthropogenic Sources and Emissions of Alkaline Particulate Matter in
Canada (Prepared by Meteorological and Environmental Planning, Ltd. and
Ontario Research Foundation for Air Pollution Control Directorate),
1984.
3. National Inventory of Natural Sources and Emissions of Alkaline
Particulates (Prepared by the Environmental Applications Group, Ltd. for
Environment Canada), 1982.
4. Davison, R. L. et a!., Trace Elements in Fly Ash, Dependence of
Concentration on Particle Size, Environmental Science and Technology,
8(13), pp. 1107-1112, December 1974.
5. Bennett, R. L. and K. T. Knapp, Characterization of Particulate
Emissions from Municipal Wastewater Sludge Incinerators, Environmental
Science and Technology, 16(12), pp. 831-836, 1982.
6. AP-42 (GPO 055-000-00252-5), Compilation of Air Pollutant Emission
Factors, Volume II, Mobile Sources, Fourth Edition, U. S. Environmental
Protection Agency, Research Triangle Park, NC, September 1985
(Appendix L).
7. DeRosier, R. and L. R. Water!and, Environmental Assessment of a
Watertube Boiler Firing a Coal-Water Slurry, Volume I, Technical
Results, U. S. Environmental Protection Agency, Publication No. EPA-
600/7-86-004a (NTIS No. PB86-159845), February 1986.
8. U. S. Environmental Protection Agency. Air Emission Species Manual,
Volume II, Particulate Matter Species Profiles. Publication No.
EPA 450/2-88-003b, Research Triangle Park, NC, April 1988, page 314.
9. Rau, 0. A. and J. J. Huntzicker, Oregon Graduate Center, Size
Distribution and Chemical Composition of Residential Wood Smoke,
Presented at the 78th Annual Meeting of the Air Pollution Control
Association, Detroit, MI, June 16-21, 1985.
C-26
-------
APPENDIX D
INDUSTRY-SPECIFIC AVERAGE PROFILES AND "ZERO" PROFILE
-------
D-2
-------
APPENDIX D
INDUSTRY-SPECIFIC AVERAGE PROFILES AND "ZERO" PROFILE
For several source categories, It was not possible to make profile
assignments based on engineering judgement using the available profiles. In
these cases, industry-specific average profiles were developed from original
profiles representing SCO's within the general Industry group. Sixteen such
profiles with profile numbers beginning with 9 were developed as listed below:
Profile Number Profile Name
90001 Solid Waste - Average
90002 Chemical Manufacturing - Average
90003 Food and Agriculture - Average
90004 Steel Production - Average
90005 Lead Smelters - Average
90006 Metal Mining - General Processes - Average
90007 Primary Metal Production - Average
90008 Secondary Metal Production - Average
90009 Secondary Aluminum - Average
90010 Gray Iron Foundries - Average
90011 Steel Foundry - General
90012 Clay and Fly Ash Sintering - Average
90013 Mineral Products - Average
90014 Petroleum Industry - Average
90015 Pulp and Paper Industry
90016 Industrial Manufacturing - Average
These profiles are presented in this appendix. All of these profiles are
assigned a data quality level of "E" and are recommended for use only if there
Is no other information available.
D-3
-------
Another profile developed in this study using engineering judgement is
Profile 00000; it is an overall average of the profiles in the PM data base.
Its main function is to provide a default value for categories where no
emissions are expected. If participate emissions are reported for such
categories, then Profile 00000 can be used to speciate these emissions if no
other information exists.
D-4
-------
PH Profile Speciation Report
Profile Name Solid Waste
Profile Number 90001
Data Quality E
- Average
Control Device Not Applicable
Reference(s) 58
Data Source Average profile developed from original
representing the source category group
SCC Assignments:
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.130
Total Particulate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
&}*^l* i w
Hum Synt
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Be
B
F
Na
Kg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
0-2
XHt
0
0
0
4
0
0
0
0
2
11
2
0
0
0
0
0
0
0
0
0
0
5
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.775
.710
.585
.000
.000
.150
.150
.500
.384
.000
.097
.000
.018
.042
.314
.000
.007
.090
.900
.000
.000
.010
.000
.083
.000
.000
.000
.013
.058
.443
.084
.002
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
0.000
0.000
0.000
4.775
0.710
0.585
0.000
0.000
E.150
11.150
2.500
0.384
0.000
0.097
0.000
0.018
0.042
0.314
0.000
0.007
0.090
5.900
0.000
0.000
0.010
0.000
0.083
0.000
0.000
0.000
0.013
0.058
0.443
0.084
0.002
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
d.ooo
0.000
0.000
profiles
Sxxxxxxxx.
(0-6)
0.1SS
0-10 un
Xwt
NE
NE
NE
4.775
0.710
0.585
NE
NE
2.150
11.150
2.500
0.384
NE
0.097
NE
0.018
0.042
0.314
NE
0.007
0.090
5.900
NE
NE
0.010
NE
O.OS3
NE
NE
NE
0.013
0.058
0.443
0.084
0.002
unc
0.000
0.000
0.000
0.924
0.137
0.113
0.000
0.000
0.416
2.158
0.484
0.074
0.000
0.019
0.000
0.003
0.008
0.061
0.000
0.001
0.017
1.142
0.000
0.000
0.002
0.000
0.016
0.000
0.000
0.000
0.002
0.011
0.086
0.016
0.000
(0-10)
0.190
Total
Measured
Xwt
0.000
0.000
0.000
4.775
0.710
0.585
0.000
0.000
2. 150
11.150
2.500
0.384
0.000
0.097
0.000
0.018
0.042
0.314
0.000
0.007
0.090
5.900
0.000
0.000
0.010
0.000
0.083
0.000
0.000
0.000
0.013
0.058
0.443
0.084
0.002
unc
0.000
0.000
0.000
1.273
0.813
0.417
0.000
0.000
5.303
3.041
7.071
0.940
0.000
0.090
0.001
0.016
0.044
0.202
0.000
0.004
0.012
0.247
0.000
0.000
0.003
0.000
0.069
0.000
0.000
0.000
0.016
0.033
0.408
0.055
0.003
D-5
-------
PH Profile Speclatlon Report - continued Cproffie 90001)
Total Particulate Hatter -
CAS Nuifcer
7440-39-3
7440-45-1
7439-97-6
7439-92-1
O}J*ZV 1 5.0
Nun Sym
§6
58
80
82
201
202
203
204
Ba
Ce
Hg
Pb
OC
EC
S04
H03
0-2
Xwt
0
0
2
4
0
Q
0
0
.004
.000
.665
.115
.000
.000
.000
.000
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2,5-10 urn
Xwt
0.004
0.000
2.665
4.115
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 un
Xwt
0.004
NE
2.665
4.115
NE
NE
NE
NE
unc
0.001
0.000
0.516
0.796
0.000
0.000
0.000
0.000
Total
Measured
%wt
0.004
0.000
2.665
4.115
0.000
0.000
0.000
0.000
unc
0.007
0.000
6.52?
0.990
0.000
0.000
0.000
0.000
TOTALS:
36.199
36.199
36.199
36.199
D-6
-------
Wl Profile Specistion Report
Profile Name Chemical Manufacturing -
Profile Number 90002
Data Quality E
Average
Control Device Not Applicable
Reference(s) 58
Data Source Average profile developed from original
representing the source category group
SCC Assignments:
Nass Fraction Data - Size Interval (urn) t {0-2. 5)
Mass Fraction : 0.279
Total Paniculate Hatter -
Species
CAS Nunber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
46
47
48
49
50
Sym
Be
B
f
Na
Mi
At
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Nn
Fe
Co
Ni
Cu
Zn
Ca
Ge
As
Se
Br
Rb
Sr
Zr
Pd
Ag
Cd
In
Sn
0-2
%wt
0
19
0
0
0
2
4
0
1
4
2
2
0
0
q
d
0
1
0
0
0
0
0
0
0
0
0
0
0
0
.000
.410
.000
.000
.475
.062
.447
.850
.340
.147
.073
.760
.000
.095
.007
.015
.122
.815
.013
.025
.039
.170
.000
.000
.000
.015
.035
.000
.003
.000
0.005
0
0
0
0
.020
.035
.022
.033
.5 urn
unc
0.000
0.000
0.000
0.000
0.150
0.500
0.500
0.000
0.150
0.300
0.250
0.300
0.000
0.045
0.000
0.000
0.025
0.200
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
%Ht
0.000
19.410
0.000
0.000
0.600
2,862
5.947
0.850
0.940
2.123
1.123
3.610
0.000
0.175
0.010
0.016
0.117
1.865
0.000
0.025
0.031
0.115
0.000
0.000
0.000
0.015
0.015
0.000
0.003
0.000
0.005
0.020
0.035
0.022
0.033
une
0.000
0.000
0.000
0.000
0.150
0.400
5.000
0.000
0.050
0.300
0.300
0.400
0.000
0.000
0.010
0.010
0.015
0.200
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
profiles
301xxxxx.
<0-6)
0.411
0-10 urn
Xwt
HE
19.410
NE
NE
0.558
2.591
5.438
0.850
1.076
2.810
1.445
3.321
NE
0.147
0.009
0.016
0.119
1.848
0.004
0.025
0.033
0.134
NE
NE
HE
0.015
0.022
NE
0.003
NE
0.005
0.020
0.035
0.022
0.033
unc
0.000
2.117
0.000
0.000
0.103
0.383
1.830
0.282
0.114
0.366
0.240
0.428
0.000
0.024
0.004
0.004
0.018
0.242
0.001
0.002
0.003
0.021
0.000
0.000
0.000
0.002
0.006
0.000
0.001
0.000
0.002
0.003
0.004
0.007
0.011
CO-10)
0.505
Total
Measured
Xwt
0.000
19.410
0.000
0.000
0.600
2.862
5.947
0.850
1,090
1.623
1.123
3.610
0.000
0.175
0.010
0.016
0.117
1.865
0.000
0.025
0.031
0.115
0.000
0.000
0.000
0.015
0.015
0.000
0.016
0.000
0.005
0.020
0.035
0.022
0.033
unc
0.000
0.000
0.000
0.000
0.000
0.125
0.770
0,150
0.045
0.015
0.030
0.140
0.000
0.000
0.000
•o.ooo
0.000
0.030
0.000
0.000
0.000
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.007
0.000
0.020
0.030
0.042
0.046
0.055
0-7
-------
PM Profile Speciatlon Report - continued (profile 90002}
Total Paniculate
Hatter
CAS Number
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Sl*SK I «SS*
Hum Sym
51
55
56
58
80
82
201
202
203
204
Sb
Cs
Ba
Ce
H9
Pb
DC
EC
S04
N03
Total
0-2
Xwt
0.025
0.000
0.175
0.000
0.000
0.033
9.175
1.825
3.125
0.350
.5
0
0
0
0
0
0
0
0
0
0
urn
unc
.000
.000
.000
.000
.000
.015
.450
.200
.250
.100
2.5-10 urn
Xwt
0.025
0.000
0.175
0.000
0.000
0.010
9.175
1.825
2.150
0.275
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.450
0.200
0.050
0.000
0-10 urn
Xwt
0.025
ME
0.175
HE
m
0.018
9.175
1.825
2.481
0.300
unc
0.008
0.000
0.058
0.000
0.000
0.006
1.082
0.212
0.255
0.042
Measured
Xwt
0.025
0.000
0.175
0.000
0.000
0.010
9.175
1.825
2.650
0.275
unc
0.105
0.000
0.300
0.000
0.000
0.015
0.000
0.000
0.000
0.000
TOTALS:
54.741
53.602
53.988
53.761
D-8
-------
PM Profile Speciation Report
Profile Name Food and Agriculture - Average
Profile Nunber 90003
Data Quality E
Control Device Hot Applicable
Reference(s) 58
Data Source Average profile developed from original profiles
representing the source category group 302xxxxx.
SCC Assignments:
Mass Fraction Data - Size Interval (urn) : (0*2.5} (0-6}
Mass Fraction : 0.140 0.310
Total Paniculate Hatter -
Species
CAS Nunber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-3S-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
Hum
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Synt
Be
B
f
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
se
Br
Rb
Sr
Zr
A9
Cd
Sn
Sb
Cs
0-2
%wt
0
0
0
0
0
0
15
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.550
.550
.000
.000
.000
,000
.000
.050
.000
.000
.050
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.5 urn
une
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
15.000
0.000
0.000
0.000
0.550
0.550
0.000
0.000
0.000
0.000
0.000
0.050
0.000
0.000
0.050
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
NE
HE
NE
NE
NE
NE
15.000
NE
NE
NE
0.550
0.550
NE
NE
NE
NE
NE
0.050
NE
NE
0.050
NE
HE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.857
0.000
0.000
0.000
0.031
0.031
0.000
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10}
0.490
Total
Measured
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
15.000
0.000
0.000
0.000
0.550
0.550
0.000
0.000
0.000
0.000
0.000
0.050
0.000
0.000
0.050
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-9
-------
PH Profile Speeiation Report - continued Cprofile 90003)
Total Particulate Hatter -
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
apec i us
Num Sym
56
58
80
82
200
202
203
204
Bo
Ce
Kg
Pb
TC
EC
S04
N03
0-2
%ut
0
0
0
0
30
0
0
0
.000
.000
.000
.000
.000
.000
.550
.000
.5 um
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 um
Xut
0.000
0.000
0.000
0.000
30.000
0.000
0.550
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
%wt
NE
NE
m
HE
30.000
NE
0.550
NE
unc
0.000
0.000
0.000
0.000
1.714
0.000
0.031
0.000
Total
Measured
%Ht
0.000
0.000
0.000
0.000
30.000
0.000
0.550
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
46.750
46.750
46.750
46.750
D-10
-------
PM Profile Special ion Report
Profile Name Steel Production
Profile Number 90004
Data Quality E
- Average
Control Device Not Applicable
Reference(s) 58
Data Source Average profile developed from original
representing the source category group
SCC Assignments:
Mass Fraction Data - Size Interval Cum) : (0-2.5)
Mass Fraction : 0.520
Total Particulate
e>i^*b.i
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
a^Kn
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Matter
;ies
Sym
Be
B
f
Ha
Mg
Al
Si
p
S
cl
tc
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
"*
0-2
%wt
0
0
0
0
0
0
4
0
13
0
5
0
0
.000
.000
.000
.000
.000
.000
.950
.000
.315
.000
.000
,550
.000
0.000
0
2
0
11
0
0
0
0
0
0
0
0
0
0
q
0
0
0
0
0
0
.550
.000
.550
.000
.000
.550
.550
.000
.000
.000
.050
.000
.050
.050
.000
.000
.050
.050
.050
.050
.000
.5 urn
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
%Wt
0.000
0.000
0.000
0.000
0.000
0.000
4.950
0.000
8.165
0.000
5.000
0.550
0.000
0.000
0.550
1.275
0.550
13.500
0.000
0.550
0.550
0.000
0.000
0.000
0.050
0.000
0.050
0.050
0.000
0.000
0.050
0.050
0.050
0.050
0.000
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
profiles
303009xx.
{0-65
0.580
0-10 urn
Xut
NE
NE
NE
NE
NE
NE
4.950
NE
11.955
NE
5.000
'0.550
NE
NE
0.550
1.808
0.550
11.660
NE
0.550
0.550
NE
NE
NE
0.050
NE
0.050
0.050
NE
NE
0.050
0.050
0.050
0.050
NE
ync
0.000
0.000
0.000
0.000
0.000
0.000
1.358
0.000
2.086
0.000
0.861
0.095
0.000
0.000
0.095
0.314
0.095
2.078
0.000
0.095
0.095
0.000
0.000
0.000
0.009
0.000
0.009
0.009
0.000
0.000
0.009
0.009
0.009
0.009
0.000
(0-10)
0.600
Total
Measured
%Ht
0.000
0.000
0.000
0.000
0.000
0.000
4.950
0.000
13.315
0.000
5.000
0.550
0.000
0.000
0.550
2.000
0.550
11.000
0.000
0.550
0.550
0.000
0.000
0.000
0.050
0.000
0.050
0.050
0.000
0.000
0.050
0.050
0.050
0.050
0.000
une
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-n
-------
PH Profile Speciation Report - continued (profile 90004)
Total Particulate Hatter -
Total
0-2.5 urn 2.S-10 urn 0-10 un Measured
Species '-—
CAS Number Nun Sym , Xwt unc %wt unc Xwt unc %wt unc
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
56
58
80
82
201
202
203
204
Ba
Ce
Hg
Pb
DC
EC
S04
N03
0
0
0
0
10
0
40
0
.000
.000
.000
.550
.000
.000
.000
.550
90.465
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.550
10.000
0.000
37.500
0.550
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
84.590
m
NE
NE
0.550
10.000
NE
39.340
0.550
88.913
0.000
0.000
0.000
0.095
2.744
0.000
6.739
0.095
0.000
0.000
0.000
0.550
10.000
0.000
40.000
0.550
90.465
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-12
-------
PM Profile Specialion Report
Profile Name Lead Smelters - Average
Profile Number 90005
Data Quality E
Control Device Not Applicable
Reference (s) 58
Data Source Average profile developed from original
representing the source category group
sec Assignments:
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0,677
Total Particulate Matter -
Species ,
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
Hum
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
46
47
48
49
50
Sym
Be
B
F
Na
«a
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Mi
Cu
Zn
Ga
Be
As
Se
Br
Rb
Sr
Zr
PD-
AS
Cd
In
Sn
0-2,5 urn
%ut
0
0
0
0
0
0
1
0
8
1
1
1
0
0
0
0
0
2
0
0
4
11
0
0
10
0
0
0
0
0
0
0
5
0
1
.000
.000
.000
.000
.000
.531
.719
.481
.664
.477
.237
.204
.000
.074
.003
,023
.094
.002
.000
.141
.887
.351
.000
.000
.468
.092
.141
.000
.048
.000
.630
.348
.847
.012
.039
unc
0.000
0.000
0.000
0.000
0.000
0.566
1.232
0.065
1.533
0.549
0.147
0.274
0.000
0.022
0.003
0.004
0.094
1.008
0.000
0.027
1,632
1.633
0.000
o.opo
2.011
0.009
0.056
0.000
0.022
0.000
0.121
0.119
1.003
0.000
0.110
2.5-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.613
2.079
0.422
7.794
1.019
1.127
1.841
0.000
0.085
0.002
0.032
0.147
3.066
0.000
0.148
5.391
12.578
0.000
0.000
5.382
0.066
0.117
0.000
0.079
0.000
0.156
0.239
3.919
0.033
0.930
unc
0.000
0.000
0.000
0.000
0.000
0.420
0.948
0.063
1.514
0.269
0.144
0.453
0.000
0.062
0.002
0.006
0.078
1.165
0.000
0.029
1.681
1.733
0.000
0.000
0.921
0.008
0.050
0.000
0.034
0.000
0.032
0.082
0,770
0.006
0.126
profiles
30301 Oxx.
(0-6)
0.773
0-10 um
Xwt
NE
NE
NE
NE
NE
0.548
1.781
0.464
8.347
1.363
1.203
1,290
NE
0.076
0.003
0.025
0.100
2.162
NE
0,142
4.967
11.662
NE
HE
9.590
0.087
0.135
NE
0.052
NE
0.553
0.329
5.362
0.017
1.027
unc
0.000
0.000
0.000
0.000
0.000
0.598
1.350
0.107
2.299
0.5371
0.324
0.557
0.000
0.057
0.003
0.008
0.107
1.407
0.000
0.053
2.793
3.358
0.000
0.000
3.107
0.020
0.071
0.000
0.038
0.000
0.186
0.134
1.484
0.009
0.299
CO-10)
0.837
Total
Measured
Xwt
0.000
0.000
0.000
0.000
0.000
0.428
1.452
0.393
7.263
1.267
1.088
1.361
0.000
0.072
0.003
0.030
0.117
2.790
0.000
0.150
5.444
11.657
0.000
0.000
6.113
0.083
0.128
0.000
0.066
0.000
0.248
0.268
4.553
0.035
0.929
unc
0.000
0.000
0.000
0.000
0.000
0.411
0.949
0.055
1.367
0.425
0.195
0.353
0.000
0.022
0.000
0.005
0.068
1.292
0.000
0.029
1.745
2.065
0.000
0.000
1.295
0.041
0.064
0.000
0.032
0.000
0.044
0.129
0.855
0^008
0.151
D-13
-------
PH Profile Special ion Report - continued (profile 90005)
Total Partieutate Hatter -
Total
CAS Kunfcer
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Spec i es
Hum Sym
51
55
56
58
eo
82
201
202
203
204
Sb
Cs
Bo
Ce
Kg
Pb
oc
EC
S04
N03
0-2
%ut
1.986
0.000
0.140
0.000
0.105
22.465
0.000
0.000
0.000
0.000
.5 urn
unc
0.899
0.000
0.168
0.000
0.017
3.937
0.000
0.000
0.000
0.000
2.5-10
Xwt
1.499
0.000
0.123
0.000
0.083
20.101
0.000
0.000
0.000
0.000
urn
unc
0.
0.
0.
0.
0.
4.
0.
0.
0.
0.
859
000
232
000
018
201
000
000
000
000
0-10 un
Xwt
1.904
NE
0.136
NE
0.100
21.905
NE
NE
NE
NE
unc
1.093
0.000
0.236
0.000
0.028
6.061
0.000
0.000
0.000
0.000
Measured
Xwt
1.666
0.000
0.129
0.000
0.076
22.148
CI.OOO
0.000
0.000
0.000
unc
1.093
0.000
0.124
0.000
0.015
4.049
0.000
0.000
0.000
0.000
TOTALS:
77.209
69.071
75.330
——s---s:ssa:
69.957
D-14
-------
PK Profile Speciation Report
Profile Name Metal Mining
Profile Number 90006
Data Quality E
- General Processes
- Average
Control Device Not Applicable
Reference(s) 58
Data Source Average profile developed from original
representing the source category group
SCC Assignments:
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.150
Total Particulate
Matter
profiles
303024xx.
(0-6)
0.340
(0-10)
0.510
Total
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
afjci* i t?»
Num Sym
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
Be
B
F
Na
Mg
Al
Si
P
s
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
0-2
'Xut
0
0
0
0
0
14
30
0
5
0
3
0
0
0
0
0
8
0
6
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.859
.907
.510
.206
.087
.086
.762
.311
.038
.040
.093
.043
.032
.080
.495
.000
.283
.006
.025
.000
.021
.000
.000
.000
.000
.032
.030
.011
.009
.079
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
1.581
3.278
0.052
0.701
0.035
0.327
0.080
0.032
0.000
0.000
0.005
0.925
0.005
1.090
0.239
0.000
0.054
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
0.028
0.041
0.043
0.050
0.092
2.5-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
10.243
23.183
0.274
3.824
0.075
2.635
0.967
0.388
0.033
0.029
0.098
7.135
0.027
6.171
1.968
0.013
0.282
0.000
0.020
0.014
0.026
0.000
0.013
0.167
0.005
0.016
0.013
0.010
0.013
0.033
unc
0.000
0.000
0.000
0.000
0.000
1.129
2.537
0.028
0.533
0.019
0.291
0.113
0.040
0.000
0.000
0.009
0.801
0.005
1.109
0.324
0.035
0.050
0.000
0.000
0.000
0.000
0.000
0.000
0.026
0.000
0.000
0.000
0.000
0.000
0.015
0-10 urn
Xut
NE
NE
NE
NE
ME
11.601
25.454
0.344
4.230
0.079
2.768
0.906
0.365
0.034
0.032
0.096
7.402
0.029
6.144
1.829
0.009
0.283
0.002
0.022
0.010
0.024
NE
0.009
0.118
0.004
0.021
0.018
0.010
0.012
0.046
unc
0.000
0.000
0.000
0.000
0.000
0.982
2.089
0.030
0.419
0.013
0.222
0.066
0.026
0.002
0.002
0.006
0.619
0.003
0.652
0.177
0.010
0.031
0.000
0.002
0.001
0.002
0.000
0.001
0.011
0.006
0.008
0.012
0.013
0.015
0.028
Measured
Xwt
0.000
0.000
0.000
0.000
0.000
10.243
23.183
0.274
3.824
0.075
2.635
0.967
0.388
, 0.033
0.029
0.098
7.135
0.027
6.171
1.968
0.013
0.282
0.000
0.020
0.014
0.026
0.000
0.013
0.167
0.005
0.016
0.013
0.010
0.013
0.033
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-15
-------
PH Profile Speciation Report - continued (profile 90006)
Total Participate Hatter
CAS Number
7440-39-3
7439-91-0
7439-97-6
7439-92-1
apcu i e»
Nun Sym
56
57
80
82
201
202
203
204
Ba
La
Hg
Pb
OC
EC
S04
N03
0-2.5 un
Xwt
0
0
0
0
0
0
0
0
.191
.000
.005
.695
.000
.000
.000
.000
unc
0.250
0.000
0.000
0.083
0.000
0.000
0.000
0.000
2.5-10 un
Xwt
0.026
0.000
0.005
0.491
0.000
0.000
0.000
0.000
unc
0.039
0.060
0.000
0.061
0.000
0.000
0.000
0.000
0-10 un
Xwt
0.074
NE
0.005
0.551
NE
NE
NE
NE
unc
0.075
0.018
0.000
0.052
0.000
0.000
0.000
0.000
Total
Measured
Xwt
0.026
0.000
0.005
0.491
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
73.936
58.197
62.531
58.197
D-16
-------
PM Profile Speciation Report
Profile Name Primary
Profile Number 9000?
Data Quality E
Metal Production
• Average
Control Device Not Applicable
Reference(s) 58
Data Source Average profile developed from original profiles
representing the source category group 303xxjoa.
SCC Assignments:
Mass Fraction Data - Size interval (urn) : (0-2,5} (0-6)
Mass Fraction : 0.464 0.575
Total Particulate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
39
40
42
46
47
48
Sym
Be
B
f
Na
Ng
Al
Si
P
s
Cl
K
Ca
So
Ti
V
Cr
Hn
Fe
Co
Ni
CU
Zn
Ga
Ge
As
Se
Br
Rb
Sr
V
Zr
Mo
Pd
Ag
Cd
0-2
Xwt
0
0
1
1
0
4
5
0
7
1
3
1
0
0
0
0
1
4
0
0
3
6
, 0
0
9
0
0
0
0
0
0
0
0
0
2
.000
.010
.302
.163
.150
.268
.635
.302
.093
.750
.122
.318
.000
.092
.102
.391
.114
.635
.000
.174
.251
.192
.001
.000
.923
.081
.119
.034
.037
.000
.003
.000
.298
.178
.810
.5 un>
unc
0.000
0.005
1.453
0.556
1.006
1.986
1.427
0.049
1.394
0.428
0.913
0.290
0.000
0.021
0.010
0.003
0.238
0.905
0.000
0.027
1.179
1.158
0.004
0.000
1.412
0.006
0.065
0.000
0.016
0.000
0.000
0.001
0.084
0.083
0.690
2.5-10 urn
Swt
0.000
0.010
1.207
1.074
0.145
3.963
4.617
0.241
5.603
1.361
2.421
1.596
0.000
0.103
0.069
0.189
1.130
5.618
0.000
0.148
3.466
6.612
0.003
0.000
7.499
0.068
0.109
0.036
0.048
0.000
0.001
0.018
0.074
0.123
1.895
unc
0.000
0.000
0.436
0,154
0.926
1.219
1.084
0.045
1.063
0.192
0.905
0.368
0.000
0.046
0.005
0.006
0.235
0.968
0.000
0.024
1.212
1.210
0.011
0.000
0.634
0.006
0.076
0.000
0.024
0.000
0.000
0.008
0.022
0.056
0.530
0-10 urn
Xwt
0.000
0.007
1.0S2
0.892
0.148
3.695
4.825
0.270
6.389
1.580
2.701
1.328
NE
0.096
0.082
0.292
1.111
4.S97
0.000
0.156
3.270
6.225
0.002
NE
9.496
0.078
0.115
0.035
0.036
NE
0.002
0.013
0.262
0.167
2.579
une
0.000
0.007
1.158
0.631
0.827
1.907
1.260
0.075
1.841
0.487
0.925
0.417
0.000
0.041
0.032
,0.109
0.512
1.293
0.000
0.051
1.934
2.318
0.004
0.000
4.187
0.028
0.073
0.010
0.026
0.000
0.001
0.004
0.128
0.093
1.021
(0»10>
0.644
Total
Measured
Xut
0.000
0.000
1.405
0.379
0.147
3.697
4.398
0.227
6.092
2.224
2.936
1 .427
0.000
0.094
0.073
0.394
1.131
5.266
0.000
0.162
3.497
6.276
0.004
0.000
7.843
0.076
0.110
0.036
0.047
0.000
0.004
0.018
0.119
0.137
2.196
unc
0.000
0.000
0,777
0.000
0.000
0.477
0,714
0.038
1,054
0.302
0.147
0.323
0,000
0.017
0,003
0.004
0.056
1.017
0.000
0.027
1.202
1.437
0.003
0.000
0.891
0.028
0.044
0.000
0.022
0.000
0.000
0.001
0.031
0.089
0.589
D-17
-------
PH Profile Speciation Report - continued (profile 90007)
Total Partfculat*
CAS Number
7440-74-6
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7439-97-6
7439-92-1
7440-69-9
TOTALS:
ope i
Num
49
50
51
55
56
57
58
80
82
83
200
201
202
203
204
Matter
Sym
In
Sn
Sb
Cs
Ba
La
Ce
Hg
Pb
Bi
TC
oc
EC
S04
N03
-
0-2,
Xwt
0.
0.
0.
0.
0.
0.
0.
0.
11.
0.
0,
3.
0.
6.
0.
79.
010
501
981
000
091
000
029
051
682
002
000
216
341
632
416
500
,5 urn
unc
0.018
0.079
0.620
0.000
0.154
0.001
0.000
0.012
2.713
0.007
0.000
1.455
0.243
2.315
0.644
2.5-10 urn
Xut
0.017
0.452
0.734
0.000
0.071
0.000
0.029
0.041
10.490
0.002
0.000
3.011
0.304
5.595
0.394
70.587
unc
0.006
0.087
0.591
0.000
0.162
0.020
0.000
0.012
2.892
0.000
0.000
0.459
0.346
0.269
0.789
0-10 in
Xwt
0.010
0.498
0.931
NE
0.081
0.000
0.029
0.049
11.355
0.001
NE
2.691
0.286
5.850
0.398
73.980
unc
0.008
0.206
0.752
0.000
0.165
0.006
0.010
0.019
4.178
0.005
0.000
1.662
0.312
2.787
0.644
Total
Measured
Xwt
0.018
0.450
0.820
0.000
0.083
0.000
0.029
0.037
1 1 .320
0.000
0.000
2.899
1.002
6.335
0.411
73.819
unc
0.005
0.104
0.752
0.000
0.086
0.001
0.000
0.010
2.788
0.000
0.000
0.696
0.634
1.157
0.020
D-18
-------
PM Profile Spec!atIon Report
Profile Name Secondary Metal Production -Average
Profile Number 90008
Data Quality E
Control Device Not Applicable
Reference(s) 58
Data Source Average profile developed from original profiles
representing the source category group 304xxxxx.
see Assignments:
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Hass Fraction : 0.474 0.567
Total Particulate
Matter
(0-10)
0.633
Total
CAS Hunter
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
0{jcw I t«a
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
46
47
48
49
50
Be
B
F
Ns
Mi
Al
Si
P
s
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Pd
*8
Cd
In
Sn
0-2
Xwt
0
0
0
0
0
0
3
0
1
7
1
1
o
0
0
0
1
5
0
0
4
5
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.630
.542
.439
.229
.067
.364
.671
.961
.112
.000
.072
.008
.237
.291
.704
.005
.312
.610
.732
.000
.000
.133
.034
,024
.003
.001
.000
.006
.005
.077
.003
.210
.5 urn
une
0.000
0.000
0.144
0.139
0.205
0.067
0.117
0.022
0.053
0.399
0.211
2.660
0.000
0.133
0.003
0.404
0.260
0.866
0.000
0.020
0.009
0.035
0.000
0.001
0.002
0.001
0.003
0.001
0.001
0.005
0.000
0.005
0.006
0.000
0.011
2.5-10 urn
%wt
0.000
0.000
0.000
0.630
0.542
0.723
3.653
0.067
1.300
7.218
1.983
1.169
0.000
0.079
0.008
0.246
1.293
5.794
0.005
0.313
4.615
5.738
0.000
0.000
0.134
0.033
0.021
0.003
0.001
0.003
0.006
0.008
0.084
0.003
0.206
unc
0.000
0.000
0.144
0.139
0.205
0.159
0.321
0.038
0.089
0.587
0.399
4.651
0.000
0.232
0.004
0,404
0.260
0.867
0.000
0.020
0.010
0.035
0.001
0.000
0.006
0.002
0.006
0.002
0.003
0.015
0.000
0.015
0.020
0.000
0.105
0-10 urn
%Ht
NE
NE
NE
0.630
0.542
0.470
3.275
0.067
1.365
7.623
1.963
1.118
NE
0.073
0.008
0.241
1.291
5.715
0.005
0.312
4.610
5.730
0.000
NE
0.134
0.034
0.023
0.003
0.001
0.001
0.006
0.005
0.078
0.003
0.210
unc
0.000
0.000
0.196
0.271
0.456
0.249
1.418
0.040
0.250
2,159
0.681
1.872
0.000
0.096
0.005
0.562
0.650
2.351
0.002
0.110
1.062
1.251
0.001
0.001
0.027
0.008
0.005
0.002
0.003
0.012
0.001
0.012
0.035
0.001
0.099
Measured
Xut
0.000
0.000
0.000
0.630
0.542
0.439
3.229
0.067
1.377
7.673
1.961
1.112
0.000
0.072
0.008
0.243
1.291
5.705
0.005
0.311
4.609
5.728
0.000
0.000
0.134
0.034
0.024
0.003
0.001
0.000
0.006
0.005
0.077
0.003
0.210
unc
0.000
0.000
0.000
0.000
0.000
0.016
0.019
0.008
0.197
0.063
0.019
0.030
0.000
0.000
0.000
0.000
0.000
0.029
0.000
0,007
1.563
1.824
0.000
0.000
0.034
0.011
0.003
0.000
0.000
0.000
0.003
0.000
0.007
0.005
0.013
D-19
-------
PH Profile Speeiatfon Report • continued (proffie 90008)
Total Particulate Hatter -
CAS Number
7440-36-0
7440-46-2
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
0-2
Nun Sym Xwt
51
55
56
58
80
82
201
202
203
204
Sb
Cs
Ba
Ce
Hg
Pb
OC
EC
S04
N03
6
0
0
0
0
5
1
0
4
q
.517
.000
.050
.000
.005
.311
.583
.000
.836
.092
.5 urn
unc
1.048
0.000
0.035
0.000
0.001
0.020
0.000
0.000
0.375
0.404
53.876
2.5-10 urn
%Mt
7.420
0.000
0.047
0.000
0.008
5.310
1.583
0.000
4.836
0.092
55.174
unc
2.061
0.000
0.117
0.000
0.004
0.022
0.000
0.000
0.375
0.404
0-10 urn
Xwt
7.125
NE
0.050
NE
0.007
5.310
1.583
NE
4.836
0.092
54.539
unc
1.797
0.000
0.100
0.000
0.003
2.246
0.688
0.000
1.826
0.551
Total
Measured
%Ht
7.440
0.000
0.050
0.000
0.008
5,309
1.583
0.000
4.836
0.092
54.817
unc
0.015
0.000
0.033
0.000
0.000
0.337
0.000
0.000
0.000
0.000
D-20
-------
PM Profile Speeiatfon Report
Profile Name Secondary Aluminum - Average
Profile Number 90009
Data Quality £ . •
Control Device Not Applicable
RefereneeCs) 58
Data Source Average profile developed from original profiles
representing the source category group 304001 xx.
SCC Assignments:
Mass Fraction Data - Size Interval (urn) : (0-2.5) CO-6)
Nass Fraction ; 0.660 0.710
Total Particulate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
a^K: v i *.$>
Num Sym
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Be
B
F
Na
Hg
Al
Si
P
S
Cl
K
Ca
Sc
Tl
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
' Ag
Cd
Sn
Sb
Cs
0-2
%Wt
0
0
0
0
0
0
3
0
1
17
5
1
0
0
0
0
0
3
0
o
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.724
.206
.186
.442
.106
.293
.540
.000
.038
.003
.039
.280
.126
.025
.292
.046
.065
.000
.000
.005
.008
.033
.002
.003
.001
.010
.000
,049
.298
.000
.5 un
unc
0.000
0.000
0.000
0.000
0.000
0.058
0.223
0.048
0.110
0.805
0.346
0.021
0.000
0.002
0.001
0.002
0.001
0,011
0.000
0.002
0.003
0.004
0.001
0.004
0.004
0.001
0.003
0.002
0.002
0.011
0.010
0.013
0.018
0.048
0.000
2.5-10 un
%wt
0.000
0.000
0.000
0.000
0.000
2.429
5.750
0.187
0.980
14.373
5.423
1.882
0.000
0.081
0.005
0.057
0.294
3.659
0.025
0.301
0.077
0.126
0.000
0.000
0.003
' 0.006
0.019
0.000
0.002
0.019
0.030
0.042
0.025
0.176
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.316
0.746
0.081
0.185
1.326
0.719
0.064
0.000
0.011
0.004
0.006
0.005
0.085
0.000
0.007
0.010
0.016
0.003
0.000
0.010
0.004
0.006
0.005
0.006
0.031
0.030
0.040
0.056
0.115
0.000
0-10 urn
%ut
NE
NE
NE
NE
NE
0.909
3.483
0.187
1.391
16.809
5.307
1.577
NE
0.042
0.003
0.041
0.281
3.184
0.025
0.293
0.049
0.071
NE
NE
0.005
0.008
0.031
0.002
0.002
0.003
0.012
0.005
0.046
0.285
NE
unc
0.000
0.000
0.000
0.000
0.000
0.535
1.363
0.096
0.365
3.221
1.467
0.365
0.000
0.015
0.003
0.010
0.065
0.721
0.006
0.065
0.015
0.025
0.003
0.003
0.009
0.004
0.009
0.005
0.006
0.030
0.029
0.039
0.053
0.127
0.000
(0-10)
0.760
Total
Measured
%wt
0.000
0.000
0.000
0.000
0.000
0.724
3.206
0.186
1.442
17.106
5.293
1.540
0.000
0.031
0.003
0.039
0.280
3.126
0.025
0.292
0.046
0.065
0.000
0.000
0.005
0.008
0.033
0.002
0.003
0.001
0.010
0.000
0.049
0.298
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-21
-------
Profile Speciation Report - continued (profile 90009)
Total paniculate Matter -
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
spec i es
Hum Sym
56
58
80
82
201
202
203
204
Ba
Ce
MB
Pb
oc
EC
SQ4
N03
0-2.5 urn
Xwt
0.
0.
0.
0.
6.
0.
8.
0.
018
000
000
065
500
000
000
275
unc
0.080
0.000
0.002
0.006
0.000
0.000
0.000
0.000
2.1-10 urn
Xwt
0.000
0.000
0.000
0.072
6.500
0.000
8.000
0.275
unc
0.245
0.000
0.007
0.016
0.000
0.000
0.000
0.000
0-10 un
Xwt
0.016
NE
NE
0.065
6.500
NE
8.000
0.275
unc
0.230
0.000
0.007
0.020
1.532
0.000
1.886
0.065
Total
Measured
Xwt
0.018
0.000
0.000
0.065
6.500
0.000
8.000
0.275
unc.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
48.678
50.818
48.907
48.678
s—3™sasRS=n=SBSsstss3==ss£ssKBH=ssBSSss;s£:=:saaEss;s;
D-22
-------
PM Profile Speciation Report
Profile Mame Gray Iron Foundries • Average
Profile Number 90010
Data Quality E
Control Device Not Applicable
Reference(s) 58
Data Source Average profile developed from original
representing the source category group
SCC Assignments:
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.835
Total Paniculate Hatter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
Num
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Sym
Be
B
F
Na
US
Al
Si
P
s
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Ft
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Sr
Rb
Sr
Zr
AS
cd
Sn
Sb
CS •
0-2
Xwt
0
0
0
t
0
1
13
0
1
1
3
1
0
0
0
0
3
10
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.650
.000
.200
.050
.000
.150
.695
.100
.250
.000
.270
.007
.038
.100
.350
.003
.067
.190
.865
.000
.000
.013
.001
.015
.017
.000
.000
.000
.006
.000
.185
.000
.5 un
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
0.000
0.000
0.000
1.650
0:000
1.200
13.050
0.000
1.150
1.695
3,100
1.250
0.000
0.270
0.007
0.038
3.100
10.350
0.003
0.067
0.190
1.865
0.000
0.000
0.013
0.001
0.015
0.017
0.000
0.000
0.000
0.006
0.000
0.185
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
b.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
profiles
304Q03xx.
(0-6)
0.905
0-10 un
Xwt
HE
NE
NE
1.650
NE
1.200
13.050
NE
1.150
1.695
3.100
1.250
NE
0.270
0.007
0.038
3.100
10.350
0.003
0.067
0.190
1.865
NE
NE
0.013
0.001
0.015
0.017
NE
NE
NE
0.006
NE
0.185
NE
unc
0.000
0.000
0.000
0.303
0.000
0.217
3.113
0.000
0.297
0.335
0.560
0.229
0.000
0.061
0.001
0.007
0.620
2.068
0.001
0.013
0.037
0.381
0.000
0.000
0.002
0.000
0.003
0.003
0.000
0.000
0.000
0.002
0.000
0.048
0.000
(0-10)
0.925
Total
Measured
Xut
0.000
0.000
0.000
1.650
0.000
1.200
13.050
0.000
1.150
1.695
3.100
1.250
0.000
0.270
0.007
0.038
3.100
10.350
0.003
0.067
0.190
1.865
0.000
0.000
0.013
0.001
0.015
0.017
0.000
0.000
0.000
0.006
0.000
0.185
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-23
-------
PH Profile Specintion Report - continued (profile 90010)
Total Partfculate Natter -
Total
0-2,5 urn 2.5-10 urn 0-10 urn Measured
Species • • - --
CAS Nunfcer Hum Sytn %vrt unc %ut unc %nt one Xwt unc
7440-39-3
7440-45-1
7439-97-6
7439-92-1
TOTALS:
ssiissxssjwsssiK
56
58
80
82
201
202
203
204
Ba
Ce
Ha
Pb
oc
EC
S04
N03
0
0
0
0
0
0
0
0
39
=:===.
.000
,000
.000
.385
.000
.000
.000
.000
.607
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.385
0.000
0.000
0.000
0.000
39.607
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
NE
NE
NE
0.385
NE
HE
NE
NE
39.607
0.000
0.000
0.000
0.074
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.385
0.000
0.000
0.000
0.000
39.607
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-24
-------
PM Profile Speeiation Report
Profile Name Steel Foundry - General
Profile Number 90011
Data Quality E
Control Device Not Applicable
Reference(s) 58
Data Source Average profile developed front original
representing the source category group
SCC Assignments:
Mass Fraction Data - Size Interval Cun) : (0-2.5)
Noss Fraction : 0,765
Total Paniculate Hatter
Species
CAS Hunter
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6 '
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
Nim
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Sym
Be
B
F
Na .
Mg
Al
Si
P
s
Cl .
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
AS
Cd
Sn
Sb
Cs
*
0-2
Xwt
0.
0.
0.
0.
3.
0.
2.
0.
0.
15.
2.
3.
0.
0.
0.
1.
4.
20.
0,
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
000
000
000
630
250
325
500
000
980
925
460
375
000
100
030
325
350
500
000
350
165
625
000
000
000
000
025
000
000
000
000
025
000
000
000
.5 urn
unc
0.000
0.000
0.354
0.339
0.502
0.113
0.148
0.000
0.049
0.552
0.049
0.403
0.000
0,014
0.007
0.990
0.636
2.121
0.000
0.049
0.021
0.085
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
2.5-10 urn
%wt
0.000
0.000
0.000
0.630
3.250
0.325
2.500
0.000
0.975
15.925
2.460
3.375
0.000
0.100
0.030
1.325
4.350
20.500
0.000
1.350
0.165
0.625
0.000
0.000
0.000
0.000
0.025
0.000
0.000
0.000
0.000
0.025
0.000
0.000
0.000
unc
0.000
0.000
0.354
0.339
0.502
0.113
0.148
0.000
0.049
0.552
0.049
0.403
0.000
0.014
0.007
0.990
0.636
2.121
0.000
0.049
0.021
0.085
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
profiles
304007xx.
(0-6)
Q.S35
0-10 urn
2wt
NE
NE
NE
0.630
3.250
0.325
2.500
NE
0.980
15.925
2.460
3.375
NE
0.100
0.030
1.325
4.350
20.500
NE
1.350
0.165
0.625
NE
NE
NE
NE
0.025
NE
NE
NE
NE
0.025
NE
NE
NE
unc
0.000
0.000
0.481
0.492
1.117
0.177
0.709
0.000
0.274
3.608
0.490
1.008
0.000
0.033
0.013
1.378
1.466
5.326
0.000
0.262
0.048
0.200
0.000
0.000
0.000
0.000
0.006
0.000
0.000
0.000
0.000
0.006
0.000
0.000
0.000
(0-10)
0.860
Total
Measured
XHt
0.000
0.000
0.000
0.630
3.250
0.325
2.500
0.000
0.980
15.925
2.460
3.375
0.000
0.100
0.030
1.325
4.350
20.500
0.000
1.350
0.165
0.625
0.000
0.000
0.000
0.000
0.025
0.000
0.000
0.000
0.000
0.025
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-25
-------
PH Profile SpeciatSon Report - continued (profile 90011)
Total Particulate
Hatter
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Nun Sym
56
58
80
82
201
202
203
204
Ba
Ce
Kg
Pb
oc
EC
S04
N03
Total
0-2
%ut
0.275
0.000
0.000
0.405
3.000
0.000
17.250
0.275
.5 urn
unc
0.000
0.000
0.000
0.049
0.000
0.000
0.919
0.990
2.5-10 urn
Sut
0
0
0
0
3
0
17
0
.275
.000
.000
.405
.000
.000
.250
.275
unc
0.000
0.000
0.000
0.049
0.000
0.000
0.919
0.990
0-10 urn
Xut
0.275
NI
NE
0.405
3.000
Hi
17.250
0.275
unc
0.065
0.000
0.000
0.123
0.704
0.000
3.972
1.348
Measured
Xwt
0.275
0.000
0.000
0.405
3.000
0.000
17.250
0.275
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 79.145 79.140 79.145 79.145
D-26
-------
PM Profile Speciation Report
Profile Name Clay and Fly
Profile Number 90012
Data Quality E
Ash
Sintering - Average
Control Device Not Applicable
Reference(s) 58
Data Source Average profile developed from oriainal profiles
representing the source category group 305009xx.
SCC Assignments:
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.333 0,380
Total Psrticulate Matter -
CAS Nunber
7440-41 -7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
74*0-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
a^f w i c;»
Mum Synt
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Be
B
F
Na
Mg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ai
Cd
Sn
Sb
Cs
0-2
%wt
0
0
0
0
1
0
3
c
3
1
1
15
0
0
0
0
0
Q
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.025
.520
.590
.465
.000
.000
.200
.375
.020
.070
.000
.007
.004
.004
.039
.435
.000
.013
.019
.009
.000
.000
.000
.000
.009
.000
.000
.000
.000
.000
.000
.000
.000
.5 urn
unc
0.000
0.000
0.074
0.100
0.884
0.293
3.041
0.000
4.676
1.062
0.816
2.830
0.000
0.020
0.006
0.011
0.029
0.435
0.000
0.008
0.018
0.006
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
XWt
0.000
0.000
0.000
0.345
0.625
1.830
7.450
0.000
0.475
0.975
0.600
13.185
0.000
0.017
0.010
0.002
0.033
0.300
0.000
0.019
0.048
0.000
0.000
0.000
0.000
0.000
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
une
0.000
0.000
0.316
0.125
0.376
3.042
10.646
0.000
0.459
0.539
0.806
6.162
0.000
0.347
0.007
0.009
0.019
0.175
0.000
0.163
0.013
0.010
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 un
Xwt
NE
NE
NE
0.298
0.820
0.382
1.382
NE
0.450
0.495
0.371
13.613
NE
NE
0.003
NE
0.019
0.201
NE
0.011
0.017
0.003
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
Ni
NE
unc
0.000
0.000
0.255
0.132
0.802
2.690
9.745
0.000
4.123
0.996
0.977
2.682
0.000
0.304
0.008
0.009
0.030
0.404
0.000
0.143
0.019
0.007
0.000
0.000
0.000
0.000
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0,542
Total
Measured
%wt
0.000
0.000
0.025
0.275
1.015
0.605
3.200
0.000
2.670
1.330
0.635
12.970
0.000
0.007
0.008
0.004
0.036
0.330
0.000
0.013
0.029
0.002
0.000
0.000
0.000
0.000
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
o.ooo
0.000
•o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-27
-------
CM Profile Speciation Report - continued (profile 90012)
Total Partlculate Hatter -
Species :
CAS Number
7440-39-3
7440-45-1
7439-97-6
7439-92-1
Hum
56
58
80
82
201
202
203
204
Sym
Ba
Ce
Hg
Pb
DC
EC
S04
N03
0-2.5 urn
Xut
0
0
0
0
14
7
9
'1
.000
.000
.000
.004
.350
.435
.600
.085
unc
0.000
0.000
0.000
0.008
5.313
9.195
17.680
1.495
2.5-10 im
Swt
0.000
0.000
0.000
0.000
4,550
13.800
1.265
0.415
unc
0.000
0.000
0.000
0.007
1.717
10.683
1.510
0.490
0-10 urn
Xwt
NE
NE
NE
0.001
2.725
1.392
0.850
0.097
unc
0.000
0.000
0.000
0.009
5.196
12.554
15.612
1.352
Total
Measured
Xut
0.000
0,000
0.000
0.000
13.950
8.635
8.465
0.800
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
59.278
45.949
23.130
54.013
D-28
-------
PM Profile Speciat ion Report
Profile Name Mineral
Profile Munber 90013
Data Quality E
Products
- Average
Control Device Not Applicable
Reference(s) 58
Data Source Average profile developed from original profiles
representing the source category group BOSxxxxx.
SCC Assignments:
Hass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.330 0.444
Total Participate Matter -
Species
CAS Ninber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
42
46
47
48
49
Sym
Be
B
F
Na.
MS
At
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cf
Mn
Fe
CO
Ni
. Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Mo
Pd
Ag
Cd
in
0-2
%wt
0
0
0
1
0
2
8
0
5
2
1
9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.002
.005
.025
.466
.328
.111
.834
.045
.143
.173
.306
.860
.000
.134
.004
.126
.071
.779
.175
.061
.062
.127
.000
,000
.008
.057
.012
.008
.012
,001
.005
.000
.001
.015
.003
.5 urn
unc
0.006
0.015
0.033
0.412
0.377
0.415
3.146
0.030
2.985
1.163
0.587
1.812
0.000
0.019
0.002
0.011
0.014
0.225
0.096
0.029
0.022
0.018
0.000
0.000
0.009
0.001
0.005
0.006
0.004
0.004
0.005
0.007
0.021
0.031
0.016
2.5-10 urn
%Nt
0.002
0.005
0.021
1.435
0.152
1.486
.8.274
0.022
4.636
2.025
1.026
8.957
0.000
0.064
0.003
0.077
0.067
0.599
0.260
0.017
0.082
0.107
0.000
0.000
0.009
0.057
0.003
0.003
0.011
0.001
0.005
0.000
0.001
0.004
0.001
unc
0.000
0.000
0.135
0.053
0.160
1.307
5.346
0.009
2.120
0.933
0.356
2.930
0.000
0.148
0.003
0.004
0.008
0.127
0.090
0.069
0.023
0.010
0.000
0.000
0.000
0.000
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
0-10 urn
Xwt
0.002
0.004
0.016
1.326
0.182
1.362
3.212
0.029
4.569
1.787
0.931
8.893
NE
0.088
0.002
0.091
0.065
0.567
0.233
0.029
0.071
0.108
NE
NE
0.008
0.056
0.005
0.006
0.011
0.000
0.005
0.000
0.000
0.008
0.001
unc
0.005
0.012
0.109
0.842
0.342
1.187
5.945
0.020
3.297
1.401
0.613
1.786
0.000
0.131
0.004
0.032
0.031
0.240
0.141
0.065
0.017
0.031
0.000
0.000
0.004
0.027
0.004
0.006
0.002
0.002
0.004
0.003
0.006
0.010
0.006
(0-10)
0.545
Total
Measured
%wt
0.000
0.000
0.025
0.050
0.185
1.426
7.672
0.027
5.245,
1.834
0.952
10.813
0.000
0.066
0.003
0.172
0.067
0.757
0.164
0.057
0.116
0.122
0.000
0.000
0.009
0.057
0.003
0.006
0.012
0.000
0.006
0.000
0.000
0.008
0.000
unc
0.000
0.000
0.033
0.000
0.000
0.223
0.618
0.019
2.206
0.934
0.216
1.353
0.000
0.012
0.000
0.007
0.002
0.111
0.090
0.011
0.033
0.015
0.000
0.000
0.002
0.001
0.001
0.002
0.001
0.001
0.004
0.001
0.001
0.002
0.004
D-29
-------
PM Profile Speciation Report • continued (profile 90013)
Total Participate Matter -
CAS Munfcer
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7439-97-6
7439-92-1
7440-69-9
vlptZW I CS9
Hum Sym
50
51
55
56
57
58
80
82
83
200
201
202
203
204
206
Sn
Sb
Cs
Ba
La
Ce
Kg
Pb
Bi
TC
OC
EC ;
S04
N03
C03
0-2.5 urn
Xut
0*
0
0
0
0
0
0
0
• 0
0
5
1
14
0
.004
.021
.000
.061
.002
.000
.002
.242
.091
.091
.255
.467
.061
.271
0.000
unc
0.040
0.070
0.000
0.204
0.007
0.000
0.005
0.086
0.302
0.000
2.273
3.922
8.087
0.637
0.000
2.5-10 un
%wt
0.002
0.008
0.000
0.008
0.002
0.000
0.000
0.201
0.091
0.050
3.715
2.624
13.765
0.150
0.786
unc
0.005
0.011
0.000
0.029
0.000
0.000
0.000
0.005
0.000
0.000
0.732
4.555
0.644
0.209
0.000
0-10 urn
Xwt
0.002
0.012
NE
0.023
0.002
NE
0.001
0.173
0.068
0.064
3.130
0.363
12.723
0.087
0.375
unc
0.012
0.022
0.000
0.063
0.006
0.000
0.001
0.105
0.232
0.017
2.510
5.354
7.867
0.577
0.185
Total
Measured
Xut
0.002
0.000
0.000
0.024
0.002
0.000
0.000
0.171
0.000
0.182
5.439
1.692
14.641
0.269
0.849
unc
0.004
0.009
0.000
0.024
0.005
0.000
0.000
0.042
0.000
0.000
0.203
0.092
3.040
0.199
0.000
TOTALS:
54.527
50.819
40.690
53.125
D-30
-------
PM Profile Speciation Report
Profile Name Petroleun Industry - Average
Profile Number 90014
Data Quality E
Control Device Not Applicable
Reference(s) 58
Data Source Average profile developed from original profiles
representing the source category group 306xxxxx.
SCC Assignments:
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Hess Fraction : 0.677 0.645
Total Participate Matter -
Species
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-22-4
7440-43-9
7440-31-5
7440-36-0
7440-46-2
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
40
47
48
50
51
55
Sym
Be
E
f
Na
Hg
AL
Si
P
S
cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Zr
Ag
Cd
Sn
Sb
Cs
0-2
Xwt '
0
0
0
0
0
2
5
0
10
0
0
2
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.484
.898
.000
.056
.000
.019
.518
.000
.059
.000
.275
.025
.399
.000
.289
.027
.278
.001
.000
.000
.276
.025
.001
.028
.025
.000
.000
.001
.001
.000
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.161
0.380
0.052
0.148
0.037
0.001
0.001
0.000
0.037
0.016
0.008
0.002
0.008
0.000
0.001
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.001
0.001
0.001
0.002
0.004
0.000
2.5-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
11.735
25.285
0.000
8^918
0.000
0.059
2.578
0.000
0.059
0.000
0.275
0.025
0.558
1.000
0.304
0.028
0.281
0.003
0.000
0.000
0.279
0.027
0.002
0.028
0.038
0.022
0.009
0.000
0.000
0.000
une
0.000
0,000
0.000
0.000
0.000
1.353
2.989
0.223
0.530
0.129
0.013
0.013
0.000
0.194
0.086
0.039
0.013
0.047
0.000
0.007
0.003
0.002
0.001
0.000
0.005
0.002
0.003
0.003
0.004
0.018
0.016
0.021
0.030
0.057
0.000
0-10 urn
Xut
NE
NE
NE
NE
NE
NE
NE
NE
7.800
NE
NE
2.500
NE
NE
NE
0.275
0.025
0.275
1.000
0.275
0.025
0.275
NE
NE
NE
0.275
0.025
NE
0.025
0.025
NE
NE
NE
NE
NE
unc
0.000
0.000
0.000
0.000
0.000
2.420
5.265
0.201
2.169
0.118
0.016
0.663
0.000
0.174
0.076
0.081
0.013
0.100
0.265
0.073
0.007
0.073
0.001
0.000
0.004
0.073
0.007
0.002
0.007
0.017
0.014
0.019
0.026
0.050
0.000
(0-10)
0.739
Total
Measured
%Mt
0.000
0.000
0.000
0.000
0.000
2.484
5.898
0.000
10.056
0.000
0.019
2.518
0.000
0.059
0.000
0.275
0.025
0.399
1.000
0.289
0.027
0.278
0.001
0.000
0.000
0.276
0.025
0.001
0.028
0.025
0.000
0.000
0.001
0.001
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-31
-------
PH Profile Speciat ion Report - continued (profile 90014}
Total Participate Hatter -
Total
0-2.5 urn 2.5-10 urn 0-10 un Htasured
Specfes ............ .—.... . ._.... ............
CAS Number Nun Sym • Xwt unc Xut unc Xwt unc %trt unc
7440*39-3
7439-91-0
7440-45-1
7439-97-6
7439-92-1
TOTALS:
===========
56
57
58
80
82
201
202
203
204
======
Ba
La
Ce
Kg
Pb
OC
EC
S04
N03
ttSSSSES
0
0
0
0
0
3
0
23
0
51
=====
.000
.123
.000
.000
.029
.500
.000
.500
.275
.112
= = ===:
0.0 OB
0.018
0.000
0.000
0.001
0.000
0.000
0.000
0.000
SSSS&&XSSZ
0.154
0.323
0.000
0.003
0.037
3.500
0.000
23.500
0.275
79.305
.___-___
0.139
0.236
0.000
0.004
0.008
0.000
0.000
0.000
0.000
=======1
NE
NE
HE
Ni
0.025
3.500
NE
23.500
0.275
40.100
========
0.125
0.216
0.000
0.004
0.010
0.928
0.000
6.231
0.073
SSSESSSSIBES
0.000
0.123
0.000
0.000
0.029
3.500
0.000
23.500
0.275
51.112
:= as svtst&s:
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
======
D-32
-------
PM Profile Specfation Report
Profile Name Pulp and Paper Industry
Profile Nunfaer 90015
Data Quality E
Control Device Not Applicable
Reference(s) 58
Data Source Average profile developed from original profiles
representing the source category group 3Q7xxxxx.
SCC Assignments:
Mass Fraction Data - Size Interval (urn) : (0-2, 5) (0-6)
Mass Fraction : 0.486 0.505
Total Particulate Matter -
Species
CAS Nutter
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
Nun
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
39
40
42
46
47
48
Sym
Be
B
F
Na
Mg
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn .
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Y
Zr
MO
Pd
Ag
Cd
0-2
%Mt
0.000
0
0
10
0
0
0
0
5
4
4
0
0
0
0
.000
.237
.775
.091
.090
.182
.026
.670
,104
.799
.424
.000
.003
.009
0.002
d
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.034
.075
.000
.007
.003
.017
.000
.000
.001
.001
.010
.002
.007
.000
.003
.002
.003
.006
.003
.5 urn
une
0.000
0.000
1.096
5.139
0.184
0.161
0.167
0.100
1.152
0.749
3.548
0.100
0.000
0.002
0,003
0.004
0.025
0.100
0.000
0.018
0.006
0.007
0.000
0.000
0.003
0.001
0.004
0.002
0.003
0.001
0.006
0.005
0.007
0.010
0.007
2.5-10 urn
%Mt
0.000
0.000
0.237
10.200
0.146
0.078
0.233
0.026
5.611
3.756
4.359
0.519
0.000
0.003
0.009
0.002
0.017
0.048
0.000
0.007
0.003
0.005
0.000
0.000
0.001
0.001
0.010
0.002
0.007
0.000
0.003
0.002
0.003
0.006
0.003
une
0.000
0.000
0.000
1.443
0.281
0.032
0.092
0.000
0.729
2.122
3.537
0.212
0.000
0.000
0.000
0.000
0.025
0.041
0.000
0.000
0.006
0.001
0.000
0.000
O.OOQ
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xut
• HE
NE
0.212
7.577
0.091
0.061
0.079
0.024
5.135
0.584
4.134
0.305
NE
0.003
0.009
0.002
0.016
0.029
NE
0.007
0.003
0.004
NE
NE
0.001
0.001
0.009
0.002
0.007
0.000
0.002
0.001
0.002
0.005
0.003
une
0.000
0.000
0.986
5.743
0.232
0.150
0.176
0.096
1.998
2.497
4.339
0.240
0.000
0.002
0.005
0.004
0.029
0.097
0.000
0.017
0.007
0.007
0.000
0.000
0.003
0.001
0.006
0.002
0.004
0.001
0.006
0.004
0.006
0.009
0.007
(0-10)
0.608
Total
Measured
%Mt
0.000
0.000
0.358
10.758
0.091
0.122
0.214
0.039
5.609
4.105
4.790
0.433
0.000
0.003
0.008
0.004
0.035
0.079
0.000
0.009
0.003
0.018
0.000
0.000
0.001
0.001
0.009
0.004
0.008
0.001
0.005
0.005
0.005
0.011
0.005
une
0.000
0.000
0.871
4.014
0.000
0.134
0.069
0.085
O.S45
0.165
0.095
0.031
0.000
0.002
0.003
0.004
0.004
0.060
0.000
0.015
0.002
0.005
0.000
0.000
0.003
0.002
0.004
0.003
0.003
0.001
0.010
0.008
0.007
0.012
0.008
D-33
-------
PK Profile Speciat5on Report • continued (profile 90015)
Total Paniculate
Hatter
CAS Number
7440-74-6
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7439-97-6
7439-92-1
9p^v 1 C5»
Nun Sym
49
50
51
55
56
57
58
80
82
200
201
202
203
204
In
Sn
Sb
Cs
Ba
La
Ce
Hg
Pb
TC
OC
1C
S04
N03
Total
0-2
Xwt
0.002
0.008
0.004
0.000
0.016
0.027
0.015
0.000
0.004
0.000
29.735
2.634
20.396
0.374
.5 un
unc
0.011
0.013
0.022
0.000
0.042
0.061
0.045
0.002
0.013
0.000
7.373
1.824
5.818
0.190
2.5-10 urn
Xwt
0.002
0.008
0.004
0.000
0.016
0.027
0.015
0,000
0.004
7.250
23.235
1.647
19.771
0.187
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
6.25S
4.438
0.571
3.964
0.102
0-10 urn
Xwt
0.001
0.008
0.003
NE
0.014
0.025
0.014
0.000
0.004
NE
15.935
0.907
18.678
0.060
unc
0.010
0.013
0.020
0.000
0.038
0.057
0.045
0.002
0.014
6.049
7.750
1.744
8.217
0.208
0
0
0
0
0
0
0
0
0
0
29
2
19
0
Measured
Xwt
.005
.012
.007
.000
.021
.048
.025
,001
.006
.000
.917
.661
.914
.384
unc
0.022
0.015
0.022
0.000
0.038
0.089
0.053
0.002
0.008
0.000
0.620
0.176
3.567
0.065
TOTALS;
79.801
77.463
53.957
79.734
D-34
-------
PM Profile Speeietion Report
Profile Name Industrial Manufacturing
Profile Number 90016
Oats Quality E
- Average
Control Device Not Applicable
Reference(s) 58
Data Source Average profile developed from original profiles
representing the source category group 3xxxxxxx.
SCC Assignments:
Mass Fraction Data • Size Interval Cum) ; (0-2. 5) (0-6)
Mass Fraction : 0.407 0.495
Total Participate Matter -
Species
CAS Nurber
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
Hum
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
39
40
42
46
47
48
Sym
Be
B
F
Na
Hi
Al
Si
P
S
Cl
K
Ca
Sc
71
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ca
Ge
As
Se
Br
Rb
SP
y
Zr
Mo
Pd
Ag
Cd
0-2
Xwt
0
1
0
2
0
2
5
0
4
3
2
2
0
0
0
0
0
3
0
0
2
3
0
0
3
0
0
0
0
0
0
0
0
0
0
,001
.366
.472
.316
.273
.167
.071
.187
.887
.485
.535
.928
.000
.081
,038
.216
.671
.049
.071
.148
,071
.319
.001
.000
.337
.056
.052
.014
.017
.000
.002
.001
.101
.063
.959
.5 urn
unc
0.003
0.007
0.936
1.961
0.617
1.171
1.618
0.051
1.599
0.664
1.458
1.469
0.000
0.065
0.007
0.186
0.182
0.667
0.042
0.023
0.681
0.669
0.002
0.001
0.815
0.004
0.038
0.003
0.009
0.000
0.004
0.003
0.048
0.049
0.399
2.5-10 urn
Xwt
0.001
1.366
0.440
2.199
0.254
2.384
5.505
0.162
4.202
3.040
2.125
2.933
0.000
0.078
0.027
0.141
0.673
3.366
0.086
0.132
2.147
3.451
0.001
0.000
2.530
0.052
0.045
0.014
0.020
0.000
0.003
0.007
0.027
0.046
0.653
unc
0.000
0.000
0.267
0.552
0.559
0.952
2.828
0.052
1.153
0.944
1.447
2.505
0.000
0.133
0.017
0.186
0.181
0.691
0.040
0.035
0.700
0.699
0.007
0.000
0.366
0.003
0.044
0.001
0.014
0.000
0.008
0.005
0.013
0.033
0.306
0-10 urn
Xwt
0.000
1.365
0.384
1.749
0.250
1.784
3.574
0.173
4.369
2.755
2.184
2.767
ME
0.075
0.031
0.177
0.666
3.089
0.081
0.135
2.079
3.322
0.001
NE
3.195
0.055
0.048
0.014
0.017
0.000
0.002
0.005
0.089
0.059
0.880
unc
0.002
0.561
0.771
2.217
0.553
1.310
3.000
0.103
1.992
1.525
1.761
1,203
0.000
0.083
0.024
0.266
0.420
1.318
0.079
0.067
1.219
1.456
0.003
0.001
2.417
0.025
0.043
0.007
0.015
0.000
0.007
0.003
0.074
0.054
0.590
co-io)
0.574
Total
Measured
Xut
0.000
1.362
0.523
1.778
0.254
1.905
4.544
0.160
4.549
3.401
2.337
3.209
0.000
0.074
0.029
0.227
0.676
3.259
0.068
0.144
2.163
3.342
0.001
0.000
2.645
0.054
0.045
0.014
0.021
0.000
0.003
0.008
0.042
0.050
0.753
unc
0.000
0.000
'0.555
1.504
0.000
0.298
•0.535
0.056
1.191
0.451
0.133
0.624
0.000
0.011
0.002
0.004
0.032
0.590
0.040
0.018
0.998
1.178
0.002
0,000
0.515
0.017
0.026
0.002
0.013
0.000
0.004
0.003
0,019
0.052
0.340
D-35
-------
PH Profile Spcciation Report - continued (profile 90016)
Total Paniculate Hatter -
CAS Number
7440-74-6
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7439-97-6
7439-92-1
7440-69-9
apei. i es
Nun ' Syra
49
50
51
55
56
57
58
80
82
83
200
201
202
203
204
206
In
Sn
Sb
Cs
Ba
La
Ce
Hg
Pb
Bi
TC
OC
EC
S04
N03
C03
0-2.5 urn
•Xwt'
0
0
1
0
0
0
0
0
5
0
0
7
0
9
0
0
.006
.216
.705
.000
.067
.009
.012
.019
.063
.018
.544
.359
.894
.858
.297
.000
unc
0.013
0.049
0.600
0.000
0.128
0.023
0.017
0,007
1.567
0.133
0.000
3.057
1.860
4.381
0.507
0.000
2.5-10 un
Xwt
0.008
0.198
1.811
0.000
0.055
0.016
0.012
0.015
4.656
0.018
1.554
6.082
0.967
9.299
0.235
0.152
unc
0.004
0.070
1.005
0.000
0.112
0.046
0.000
0.007
1.670
0.000
2.344
1.718
2.023
1.529
0.502
0.000
0-10 un
Xwt
0.006
0.214
1.815
HE
0.056
0.004
0.012
0.018
4,939
0.014
0.539
4.838
0.421
9.053
0.208
0.072
unc
0.007
0.127
0.932
0.000
0.114
0.046
0.018
0.011
2.624
0.102
2.278
3.283
2.448
5.107
0.522
0.081
Total
Measured
Xwt
0.009
0.198
1.843
0.000
0.058
0.012
0.013
0.014
4.927
0.000
0.561
7.315
1.162
9.770
0.291
0.164
unc
0.015
0.062
0.435
0,000
0.097
0.033
0.020
0.006
1.617
0.000
0.000
0.472
0.374
2.004
0.091
0.000
TOTALS:
66.022
63.188
57.583
Essssssssisasass
63.977
D-36
-------
PH Profile Specialion Report
Profile Name
Profile Umber 00000
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Hatter -
CAS Number
7439-93-2
7440-41-7
7440-42-8
7782-41 -4
7440-23-5
7439-95-4
7429-90-5
7440-21 -3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-18-8
7440-16-6
7440-05-3
apci; i vai
Mum Sym
3
4
5
9
11
12
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
39
40
41
42
44
45
46
Li
Be
B
F
Na
Hi
Al
Si
p
s
Cl
K
Ca
Sc
Ti
V
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Y
Zr
Nb
Ho
Ru
Rh
Pd
0-2
Xwt
0
0
0
0
1
0
4
9
0
2
2
2
2
0
0
0
0
0
2
0
0
1
2
0
0
1
0
0
0
0
0
0
0
0
0
d
0
.000
.000
.586
.219
.652
.389
.443
.491
.152
.972
.631
.108
.614
.000
.194
.061
.103
.337
.758
.031
.126
.056
.233
.002
.000
.476
.025
.353
.007
.014
.000
.002
.000
.002
.000
.000
.045
.5 urn
unc
0.000
0.002
0.016
0.612
1.613
0.520
1.325
1.752
0.050
1.232
1.105
1.470
1.072
0.000
0.066
0.065
0.872
0.130
0.677
0.028
0.870
0.600
1.119
0.864
0.000
1.034
0.864
0.894
0.002
0.010
0.000
0.003
0.000
0.002
0.000
0.000
0.032
(0-2.5)
0.222
2.5-10 urn
Xwt
0.000
0.000
0.585
0.204
1.577
0.367
4.079
8.933
0.140
2.457
2.316
1.760
2.804
0.000
0.207
0.059
0.071
0.345
2.848
0.037
0.113
1.089
2.235
0.002
0.000
1.118
0.023
0.332
0.008
0.017
o.ooo
0.004
0.000
0.007
0.000
0.000
0.013
unc
0.000
0.000
0.010
0.881
0.537
0.983
0.782
2.137
0.108
0.915
1.115
0.984
1.662
0.000
0.098
0.073
0.872
0.122
0.652
0.026
0.871
0.625
0.733
0.006
0.000
0.307
0.003
0.201
0.001
0.014
0.000
0.008
0.000
0.007
0.000
0.000
0.008
(0-6)
0.267
0-10 urn
Xwt
0.000
0.000
0.586
0.181
1.377
0.362
3.819
7.736
0.141
2.632
2.263
1.843
2.399
0.000
0.186
0.058
0.086
0.330
2.648
0.035
0.119
1.057
2.218
0.002
0.000
1.410
0.025
0.346
0.007
0.014
0.000
0.002
0.000
0.006
NE
NE
0.040
unc
0.000
0.002
0.366
0.655
1.535
0.587
1.391
2.490
0.110
1.464
1.235
1.385
0.915
0.000
0.082
0.054
0.616
0.279
1.020
0.052
0.597
0.919
1 .481
0.418
0.000
1.646
0.418
0.555
0.004
0.015
0.000
0.006
0.000
0.005
0.000
0.000
0.048
(0-10)
0.002
Total
Measured
Xwt
0.000
0.000
0.582
0.244
1.407
0.393
4.024
8.673
0.247
2.876
2.624
2.036
2.945
0.000
0.206
0.062
0.130
0.344
3.046
0.029
0.128
1.134
2.392
0.002
0.000
1.175
0.029
0.356
0.008
0.017
0.000
0.003
0.000
0.008
0.000
0.000
0.020
unc
0.000
0.000
0.010
0.363
1.318
0.114
0.949
0.824
0.043
1.052
0.521
0;907
0.487
0.000
0.018
0.001
0.864
0.035
0.608
0.026
0.864
0.785
1.307
0.864
0.000
0.964
0.864
0.868
0.001
0.014
0.000
0.003
0.000
0.003
0.000
0.000
0.012
D-37
-------
PH Profile Speciation Report - continued (profile OUOOO)
Total Particulate Hatter -
Species
CAS Number Nun Sym
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
13494-80-9
7553-56-2
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-10-0
7440-00-8
7440-19-9
7440-53-1
7440-54-2
7440-27-9
7429-91-6
7440-60-0
7440-52-0
7440-30-4
7440-64-4
7439-94-3
7440-58-6
7440-25-7
7440-33-7
7440-15-5
7440-04-2
7439-88-5
7440-06-4
7440-57-5
7439-97-6
7440-28-0
7439-92-1
7440-69-9
7440-29-1
7440-61-1
47
48
49
50
51
52
53
55
56
57
58
59
60
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
90
92
200
201
202
203
204
205
206
Ag
Cd
In
Sn
Sb.
Te
I
Cs
Ba
La
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
Hf
Ta
W
Re
Os
Ir
Pt
Au
Hg
Tl
Pb
Bi
Th
U
TC
OC
EC
S04
N03
NH4
C03
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
0
0
0
2
8
4
5
0
0
1
0-2.5 um
Xwt
.039
.421
.004
.117
.765
.000
.000
.000
.052
.004
.009
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.054
.000
.382
.008
.000
.000
.117
.768
.406
.514
.164
.022
.171
unc
0.052
0.261
0.014
0.041
0.995
0.000
0.864
0.000
0.116
0.016
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.864
0.000
1.739
0.086
0.000
0.000
3.714
3.137
2.335
3.198
0.378
0.073
0.000
2.5-10 um
Xwt
0.031
0.285
0.004
0.103
0.806
0.000
0.001
0.000
0.039
0.007
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
0.000
3.137
0.008
0.000
0.000
2.546
8.187
4.582
5.030
0.134
0.030
1.235
unc
0.034
0.200
0.003
0.049
0.723
0.000
0.000
0.000
0.081
0.032
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.000
1.632
0.000
0.000
0.000
4.016
2.634
2.592
1.563
0.365
0.092
0.000
0-10 um
Xwt
0.037
0.385
0.003
0.114
0.809
NE
0.001
0.000
0.042
0.002
0.009
0.000
0.000
0.000
NE
NE
NE
0.000
0.000
NE
NE
0.000
NE
NE
0.000
0.000
NE
NE
NE
NE
NE
0.054
0.000
3.303
0.006
0.000
0.000
2.085
7.337
3.259
5.046
0.124
0.023
0.909
unc
0.053
0.385
0.007
0.089
0.813
0.000
0.418
0.000
0.095
0.031
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.422
0.000
2.315
0.066
0.000
0.000
5.052
4.481
3.761
3.574
0.397
0.086
0.297
Total
Measured
Xwt
0.033
0.377
0.004
0.162
0.828
0.000
0.002
0.000
0.054
0.006
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
0.000
3.495
0.000
0.000
0.000
2.124
8.321
3.957
6.169
0.162
0.022
1.240
unc
0.057
0.222
0.010
0.067
0.991
0.000
0.864
0.000
0.064
0.023
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.176
0.000
1.811
0.000
0.000
0.000
3.714
0.857
1.299
1.338
0.138
0.045
0.000
TOTALS:
63.099
59.976
55.476 .
62.157
D-38
-------
APPENDIX E
PM PROFILE ASSIGNMENTS
-------
E-2
-------
APPENDIX E
PM PROFILE ASSIGNMENTS
The activities where PM profiles are applied typically employ Source
Classification Codes (SCC's) for point sources and area source codes from the
National Emissions Data System (NEDS) to represent emission source categories.
Ideally, each SCC or area source code would be characterized by an appropriate
PM profile. However, there are a limited number of PM profiles that represent
a relatively small number of source categories. To increase the usefulness of
a given PM profile and to characterize those source categories for which there
are no profiles, PM profile assignments are made using engineering judgement.
Table E-l is a listing of all the SCC's with appropriate profile
assignments. (Refer to "Criteria Pollutant Emission Factors for the 1985
NAPAP Emissions Inventory" [EPA-600/7-87-015] for descriptions of SCC's used
in Table E-l.) Table E-2 is a listing of assignments for area sources. Area
source codes in Table E-2 include a number of sources that were developed by
the National Acid Precipitation Assessment Program (NAPAP). The additional
source codes are those from 65 through 115 (see Table E-3 for descriptions of
area source codes used in this document).
Tables E-l and E-2 use the same format to present the profile
assignments. The first column consists of the point or area source code; the
second column contains the profile assigned to the code. In cases where the
profile assignment is based on engineering judgement, the profile number is
followed by an asterisk (*) to indicate that the profile was originally
developed for another source category. In cases where several profiles and a
composite profile are available for characterizing an SCC, the composite
profile is used in the assignment. The user/reader may wish to evaluate the
individual profiles that make up the composite to determine the most
appropriate profile for his/her particular application.
E-3
-------
TABLE E-l. POINT SOURCE PROFILE ASSIGNMENTS'
Page No.
10/04/89
sec
10100101
10100101
10-100102
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100202
10100203
10100203
10100204
10100205
10100212
10.100217
10100221
10100222
10100223
10100224
10100225
10100226
10100301
10100302
10100303
10100304
10100306
10100401
10100401
10100401
10100401
10100401
10100401
PROFILE
NUMBER
11201*
43303
11201*
11201
11202
11203
11204
11205
11206
11207
11208
11209
11210
11211
11213
11301
11214
11215
11201*
11201*
11212
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11501
11502
11503
11504
11505
11506
QUA!
E
E
E
D
D
D
D
D
D
D
D
D
D
D
D
D
C
C
C
E
E
D
D
D
D
E
D
E
D
D
0
E
D
E
D
D
D
D
D
D
D
D
*PRO_ASSI denotes the profile assignments.
E-4
-------
TABLE E-l. (Continued)
Page No.
10/04/89
sec
10100401
10100401
10100401
10-100401
10100404
10100405
10100406
10100501
10100504
10100505
10100601
10100602
10100604
10100701
10100702
10100801
10100901
10100902
10100903
10101001
10101002
10101101
10101201
10101201
10101301
10101302
10200101
10200104
10200107
10200201
10200202
10200203
10200204
10200205
10200206
10200210
10200212
10200213
10200217
10200219
10200221
10200222
PROFILE
NUMBER
11507
11508
11509
11510
11501*
11501*
11501*
11501*
11501*
11501*
26101*
26101*
26101*
26101*
26101*
11201*
11801*
11801
11801*
26101*
26101*
11801*
17106*
11301
17120*
13501*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
12201
11201*
11201*
11201*
11201*
QUAI
D
D
D
C
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
•E
' E
E
E
E
E
D
E
E
E
E
D
E
D
D
D
D
D
D
D
D
E
D
E-5
-------
TABLE l-l. (Continued)
Page No.
10/04/89
sec
10200223
10200224
10200225
10200226
10200229
10200301
10200302
10200303
10200304
10200306
10200307
10200401
10200401
10200401
10200401
10200402
10200403
10200404
10200405
10200500
10200501
10200502
10200503
10200504
10200505
10200601
10200602
10200603
10200604
10200701
10200704
10200707
10200710
10200799
10200802
10200804
10200901
10200902
10200903
10200903
10200904
10200905
PROFILE
NUMBER
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
13501*
13502
13503
13504
13501*
13501*
13501*
13501*
12301
13501*
13501*
13501*
13501*
13501*
26101*
26101*
26101*
26101*
26101*
26101*
26101*
26101*
26101*
11201*
11201*
12704*
12704
12704*
12705
12704*
12704*
QUA
E
D
D
D
D
E
D
E
0
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E-6
-------
TABLE E-l. (Continued)
Page No.
10/04/89
sec
10200906
10200907
10201001
10201002
10201101
10201201
10201201 •
10201301
10201301
10201302
10201302
10201302
10201401
1Q201402
10201403
10201404
10300101
10300102
10300103
10300205
10300206
10300207
10300208
10300209
10300211
10300214
10300216
10300217
10300221
10300222
10300223
10300224
10300225
10300226
10300305
10300306
10300307
10300309
10300401
10300402
10300403
10300404
PROFILE
NUMBER
12704*
12704*
26101*
26101*
11801*
17106*
15101
17120*
14102
13501*
17120*
14101
26101*
26101*
13501*
13501*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
11201*
13501
13501*
13501*
13501*
QUA!
E
E
E
E
£
E
E
E
E
D
0
D
E
E
D
D
E
E
E
E
D
D
D
D
D
D
D
D
E
D
D
D
0
D
E
D
D
D
C
D
D
D
-------
TABLE E-l. (Continued)
Page No.
10/04/89
sec
10300501
10300502
10300503
10'300§04
10300601
10300602
10300603
10300701
10300799
10300901
10300902
10300903
10301001
10301002
10301201
10301301
10301302
10301303
10500102
10500105
10500106
10500110
10500202
10500205
10500206
10500209
10500210
20100101
20100102
20100201
20100202
20100702
20100901
20100902
20101001
20200101
20200102
20200103
20200104
20200201
20200202
20200203
PROFILE
NUMBER
13501*
13501*
43201*
13101*
26101*
26101*
26101*
26101*
26101*
12704*
12704*
12704*
26101*
26101*
17106*
17120*
13501*
17120*
11201*
13501*
26101*
26101*
11201*
13501*
26101*
12704*
26101*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
QUAI
D
D
E
D
E
E
E
E
E
E
E
E
E
E
E
E
D
E
D
D
E
E
D
D
E
E
E
E
E
f
E
E
E
E
E
E
E
E
E
E
E
E
E-8
-------
TABLE E-l, (Continued)
Page No.
10/04/89
sec
20200204
20200301
20200401
20200402
20200403
20200501
20200901
20200902
20201001
20201002
20300101
20300102
20300201
20300202
20300301
20301001
20301002
20400101
20400102
20400201
20400301
20400302
20400401
20400402
28888801
28888802
28888803
30100101
30100102
30100103
30100103
30100104
30100105
30100106
30100107
30100108
30100109
30100180
30100199
30100305
30100306
30100307
PROFILE
NUMBER
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
34001*
90002*
00000*
00000*
44102
00000*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-9
-------
TABLE E-l. (Continued)
Page No.
10/04/89
sec
30100308
30100301
30100399
30100410
30100501
30100502
30100503
30100504
30100506
30100507
30100508
30100509
30100599
30100601
30100603
30100604
30100605
30100699
30100799
30100801
30100802
30100803
30100804
30100805
30100899
30100901
30100902
30100999
30101011
30101012
30101013
30101014
30101015
30101021
30101022
30101023
30101030
30101099
30101101
30101198
30101199
30101202
PROFILE
NUMBER
00000*
00000*
90002*
90002*
90002*
00000*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
25302
25302*
25302*
90002*
90002*
00000*
90002*
90002*
00000*
00000*
00000*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
00000*
QUA!
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
. E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-10
-------
TABLE E-l. (Continued)
Page No.
10/04/89
8
sec
30101203
30101204
30101205
30101206
30101299
30101301
30101302
30101303
30101304
30101399
30101401
30101402
30101499
30101501
30101502
30101503
30101505
30101599
30101601
30101602
30101603
30101699
30101702
30101703
30101704
30101705
30101706
30101707
30101708
30101799
30101801
30101802
30101803
30101805
30101807
30101808
30101809
30101810
30101811
30101812
30101813
30101814
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
00000*
00000*
00000*
00000*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-ll
-------
TABLE E-l. (Continued)
Page No.
10/04/89
sec
30101815
30-101816
30101817
30101818
30101819
30101820
30101821
30101822
30101827
30101832
30101837
30101838
30101839
30101840
30101842
30101847
30101849
30101852
30101860
30101861
30101863
30101864
30101865
30.101866
30101870
30101871
30101872
30101880
30101881
30101882
30101883
30101884
30101885
30101890
30101891
30101892
30101893
30101894
30101899
30101901
30101902
30101904
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
00000*
00000*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-12
-------
TABLE E-l. (Continued)
Page No,
10/04/89
10
sec
30101905
30101906
30101907
30102001
30102002
30102003
30102004
30102005
30102099
30102101
30102102
30102103
30102104
30102105
30102106
30102107
30102108
30102110
30102111
30102112
30102113
30102120
30102199
30102201
30102301
30102304
30102306
30102308
30102310
30102312
30102314
30102316
30102318
30102319
30102320
30102321
30102322
30102399
30102401
30102402
30102405
30102410
PROFILE
NUMBER
90002*
90002*
90002*
00000*
00000*
00000*
00000*
90002*
90002*
00000*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
27501*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
QUA:
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-13
-------
TABLE E-l. (Continued)
Page No.
10/04/89
11
sec
30102414
30102415
30102416
30102421
30102422
30102423
30102424
30102425
30102426
30102427
30102499
30102501
30102505
30102599
30102601
30102602
30102608
30102609
30102610
30102611
30102612
30102613
30102614
30-102615
30102616
30102617
30102625
30102630
30102699
30102701
30102704
30102705
30102706
30102707
30102708
30102709
30102710
30102711
30102712
30102712
30102713
30102714
PROFILE
NUHBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
25409
90002*
90002*
QUA!
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-14
-------
TABLE E-l. (Continued)
Page No.
10/04/89
12
sec
30102717
30102718
30102720
30102721
30102722
30102723
30102724
30102725
30102727
30102728
30102729
30102730
30102801
30102803
30102803
30102804
30102804
30102805
30102806
30102807
30102820
30102821
30102822
30102823
30102823
30102823
30102824
30102824
30102825
30102825
30102903
30102904
30102905
30102906
30102907
30102908
30102920
30102921
30102922
30102923
30102923
30102924
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
25408*
90002*
25408*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
25413
25412
90002*
25412
90002*
25412
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
25408*
90002*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
D
E
E
E
E
E
E
E
E
C
E
C
E
C
E
E
E
E
E
E
E
E
E
E
D
E
£-15
-------
TABLE E-l. (Continued)
Page No.
10/04/89
13
sec
30J02924
30102925
30103001
30103001
30103002
30103002
30103003
30103003
30103004
30103004
30103020
30103021
30103022
30103023
30103024
30103025
30103099
30103101
30103102
30103103
30103104
30103105
30103199
30103201
30103202
30103203
30103204
30103299
30103301
30103311
30103312
30103399
30103402
30103403
30103404
30103405
30103406
30103410
30103411
30103412
30103414
30103415
PROFILE
NUMBER
25408*
90002*
90002*
25411
90002*
2S411
90002*
25411
90002*
25411
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
QUAI
D
E
E
C
E
C
E
C
E
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-16
-------
TABLE E-l. (Continued)
Page No.
10/04/89
14
sec
30103420
30103425
30103430
30103435
30103499
30103501
30103502
30103503
30103506
30103507
30103510
30103515
30103520
30103550
30103551
30103552
30103553
30103554
30103599
30103801
30103901
30103902
30103903
30104001
30104002
30104003
30104004
30104005
30104006
30104007
30104008
30104009
30104010
30104011
30104012
30104013
30104101
30104102
30104103
30104104
30104199
30104201
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
25404
25404*
25404*
25404*
25404*
25404*
25404*
25404*
25404*
25404*
25404*
25404*
25404*
00000*
00000*
00000*
00000*
00000*
90002*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-17
-------
TABLE l-l, (Continued)
Page No.
10/04/89
li
sec
30104202
30104203
30104204
30104301
30104501
30104501
30104501
30105001
30106001
30106002
30106003
30106004
30106005
30106006
30106007
30106008
30106009
30106010
30106011
30106012
30106099
30107001
30107002
30109101
30109105
30109110
30109151
30109152
30109153
30109154
30109180
30109199
30110002
30110003
30110004
30110005
30110099
30111103
30111199
30111201
30111202
30111299
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
25415
25414
25403*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
00000*
00000*
25407
QUA
E
E
E
E
E
C
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-18
-------
TABLE l-l. (Continued)
Page No.
10/04/89
16
sec
30112001
30112002
30112005
30112006
30112007
30112011
30112012
30112013
30112014
30112017
30112021
30112031
30112032
30112033
30112034
30112037
30112099
30112199
30112401
30112402
30112403
30112404
30112405
30112406
30112407
30112480
30112501
30112502
30112504
30112505
30112506
30112509
3CU12510
30112511
30112512
30112514
30112515
30112520
30112521
30112522
30112524
30112525
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
QUAI
E
E
E
E
E
E
E
E
E
E
E
. E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-19
-------
TABLE E-l. (Continued)
Page No.
10/04/89
17
sec
30112526
30112S27
30112528
30112529
30112530
30112531
30112532
30112533
30112534
30112535
30112540
30112541
30112542
30112543
30112544
30112545
30112546
30112547
30112550
30112551
30112552
30112553
30112555
30112599
30112699
30112701
30112702
30112703
30112720
30112730
30112740
30112780
30113004
30113004
30113005
30113005
30113201
30113205
30113210
30113221
30113222
30113223
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
25410
90002*
25410
90002*
90002*
90002*
90002*
90002*
90002*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
.E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
E
C
E
E
E
E
E
E
E-20
-------
TABLE E-l, (Continued)
Page No.
10/04/89
18
sec
30113224
30113227
30113299
30113301
30113302
30113303
30113380
30113701
30113710
30113799
30114001
30114002
30114003
30114004
30114005
30115201
30115301
30115310
30115311
30115312
30115320
30115321
30115322
30115380
30115601
30115602
30115603
30115604
30115605
30115606
30115607
30115680
30115701
30115702
30115704
30115780
30115801
30115802
30115803
30115821
30115822
30115880
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002* •
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
QUA
E
E
E
E
E
E
E
E
. E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-21
-------
TABLE E-l. (Continued)
Page No.
10/04/89
19
sec
30116701
30116702
30116703
30116704
30116780
30116799
30116901
30116902
30116903
30116904
30116905
30116906
30116980
30117401
30117402
30117410
30117411
30117421
30117480
30117601
30117610
30117611
30117612
30117613
30117614
30117615
30117616
30117617
30117618
30117630
30117631
30117632
30117633
30117634
30117680
30118101
30118102
30118103
30118104
30118105
30118106
30118107
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*-
90002*
90002*
90002*
90002*
90002*
QUA!
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-22
-------
TABLE E-l. (Continued)
Page No.
10/04/89
20
sec
30118108
30118109
30118110
30118180
30119001
30119002
30119003
30119004
30119010
30119011
30119012
30119013
30119014
30119080
30119501
30119502
30119503
30119504
30119505
30119506
30119580
30119701
30119705
30119706
30119707
30119708
30119709
30119710
30119741
30119742
30119743
30119744
30119745
30119749
30119799
30120201
30120202
30120203
30120204
30120205
30120206
30120210
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
QUAl
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
•ter
E-23
-------
TABLE E-l. (Continued)
Page No.
10/04/89
21
sec
30120211
30120280
30120501
30120502
30120503
30120504
30120505
30120506
30120507
30120508
30120509
30120520
30120521
30120522
30120523
30120524
30120525
30120526
30120527
30120528
30120529
30120530
30120531
30120532
30120540
30120541
30120542
30120543
30120544
30120545
30120546
30120547
30120548
30120549
30120550
30120551
30120552
30120553
30120554
30120555
30120580
30120601
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
QUAI
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-24
-------
TABLE E-l. (Continued)
Page No.
10/04/89
22
sec
30120602
30120603
30120680
30121001
30121002
30121003
30121004
30121005
30121006
30121007
30121008
30121009
30121010
30121080
30121101
30121102
30121103
30121104
30121121
30121122
30121123
30121124
30121125
30121180
30125001
30125002
30125003
30125004
30125005
30125010
30125015
30125020
30125021
30125025
30125099
30125101
30125102
30125103
30125104
30125180
30125201
30125301
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-25
-------
TABLE E-l. (Continued)
Page No.
10/04/89
23
sec
30-125302
3012S305
30125306
30125315
30125316
30125325
30125326
30125380
30125401
30125405
30125406
30125407
30125408
30125409
30125410
30125411
30125412
30125413
30125415
30125416
30125417
30125418
30125420
30121499
JO 125801
30125802
30125803
30125805
30125806
30125807
30125810
30125815
30125816
30125817
30125880
30125899
30130101
30130102
30130103
30130104
30130105
30130106
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
QUA:
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
I
E-26
-------
Page No.
10/04/89
TABLE E-l. (Continued)
24
sec
30130107
30130108
30130110
30130135
30130180
30130201
30130202
30130203
30130280
30130301
30130302
30130303
30130304
30130305
30130380
30130401
30130402
30130403
30130404
30130405
30130480
30-130501
30130502
30130503
30130504
30130505
30130580
30180001
30181001
30182001
30183001
30184001
30187001
30187002
30187003
30187004
30187005
30187006
30187007
30187008
30187009
30187010
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-27
-------
Page No.
10/04/89
TABLE E-l. (Continued)
25
sec
30187097
30187098
30187501
30187502
30187597
30187598
30188501
30188502
30188503
30188504
30188505
30188599
30188801
30188802
30188803
30188804
30188805
30190001
30190002
30190003
30190004
30190012
30190013
30190014
30190099
30199998
30199999
30200101
30200102
30200103
30200104
30200199
30200201
30200202
30200203
30200299
30200301
30200401
30200402
30200403
30200404
30200410
PROFILE
NUMBER
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
90002*
13501*
90002*
90002*
13501*
90002*
90002*
90002*
25405
25405
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
QUAI
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-28
-------
Page No.
10/04/89
TABLE E-l. (Continued)
26
sec
30200501
30200502
30200503
30200504
30200505
30200506
30200507
30200508
30200509
30200510
30200511
30200512
30200601
30200602
30200603
30200604
30200605
30200606
30200607
30200608
30200609
30200610
30200611
30200699
30200701
30200702
30200703
30200704
30200705
30200711
30200712
30200713
30200714
30200721
30200722
30200723
30200724
30200731
30200732
30200733
30200734
30200741
PROFILE
NUMBER
21401*
21401*
21401*
21401*
21401
21401
21401*
21401*
21401*
21401*
21401*
21401*
21401*
21401*
21401*
21401*
21401*
21401*
21401*
21401*
21401*
21401*
21401*
21401*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
I
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
I
E
E
E
E-29
-------
Page No.
10/04/89
TABLE E-l. (Continued)
27
.
sec
30200742
30200743
30200744
3020074S
30200751
30200752
30200753
30200754
30200755
30200756
30200760
30200771
30200772
30200773
30200774
30200781
30200782
30200783
30200784
30200785
30200786
30200787
30200788
30200789
30200790
30200791
30200799
30200801
30200802
30200803
30200804
30200805
30200806
30200899
30200901
30200902
30200903
30200904
30200905
30200998
30200999
30201001
PROFILE
NUMBER
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
00000*
90003*
90003*
90003*
90003*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-30
-------
Page No.
10/04/89
TABLE E-l. (Continued)
28
•
sec
30201002
30201003
30201004
30201103
30201104
30201105
30201106
30201199
30201201
30201202
30201203
30201204
30201205
30201206
30201301
30201401
30201501
30201599
30201601
30201699
30201799
30201899
30201901
30201902
30201903
30201904
30201906
30201907
30201908
30201909
30201911
30201912
30201913
30201914
30201915
30201916
30201917
30201918
30201919
30201920
30201999
30202001
PROFILE
NUMBER
90003*
00000*
90003*
00000*
90003*
90003*
90003*
00000*
00000*
00000*
90003*
00000*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
00000*
90003*
90003*
90003*
90003*
00000*
90003*
41350*
QUAI
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-31
-------
Page No.
10/04/89
TABLE E-l. (Continued)
29
sec
30202002
30202101
30202102
30202105
30202106
30202201
30202601
30202801
30203001
30203099
30203103
30203104
30203105
30203106
30203107
30203108
30203109
30203110
30203111
30203201
30203202
30203299
30203399
30203601
30203801
30288801
30288802
30288803
30288804
30288805
30290001
30290002
30290003
30299998
30299999
30300001
30300002
30300101
30300101
30300102
30300102
30300103
PROFILE
NUMBER
41350*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
00000*
00000*
00000*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
90003*
13501*
13501*
26101*
90003*
90003*
90007*
90007*
29101*
29102*
29101*
29102*
29101*
QUA
E
E
E
E
E
E
E
• E
E
E
E
E
E
E
E
E
E
E
E
E
E
' E
E
E
E
E
E
E
E
E
D
D
E
E
E
E
E
E
E
E
E
E
E-32
-------
Page No.
10/04/89
TABLE E-l. (Continued)
30
sec
30300103
30300104
30300104
30300105
30300105
30300106
30300106
30300107
30300107
30300108
30300108
30300109
30300109
30300110
30300110
30300111
30300111
30300199
30300199
30300201
30300302
30300303
30300304
30300305
30300306
30300307
30300308
30300309
30300310
30300311
30300312
30300313
30300314
30300315
30300316
30300399
30300401
30300502
30300502
30300503
30300504
30300505
PROFILE
NUMBER
29102*
29101*
29102*
29101*
29102*
29101*
29102*
29101
29102
29101*
29102*
29101*
29102*
29101*
29102*
29101*
29102*
29101*
29102*
90007*
21204*
21203*
21203*
21204*
11201*
21204*
21203*
21204*
21204*
21204*
21203*
11202*
21203*
90007*
21204*
21204*
21203*
29202*
29209
29202
29202*
29202*
QUA
E
E
E
E
E
E
E
D
D
E
E
E
E
E
E
E
E
E
E
E
D
E
E
D
D
E
E
D
D
D
E
E
E
E
D
E
E
E
. E
E
E
E
E-33
-------
Page No.
10/04/89
TABLE E-l. (Continued)
31
sec
30300506
30300507
30300508
30300509
30300509
30300510
30300511
30300512
30300512
30300513
30300514
30300514
30300514
30300514
30300515
30300515
30300515
30300515
30300516
30300517
30300518
30300521
30300522
30300523
30300524
30300524
30300525
30300526
30300527
30300528
30300599
30300601
30300602
30300603
30300604
30300605
30300610
30300611
30300613
30300614
30300615
30300616
PROFILE
NUMBER
29202*
29202*
29202*
29202*
29209
29202*
29202*
29202*
29207
29202*
29202*
29203
29204
29210
29202*
29205
29206
29211
29202*
29202*
29202*
29202*
29202*
29202*
29202*
29208*
29202*
29202*
29202*
29202*
29202*
28401*
28401*
28401*
28401*
28401*
28401*
28401*
28401*
28401*
28401*
28401*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
C
E
E
E
C
E
E
E
E
E
E
E
D
E
E
E
E
E
D
D
D
D
D
D
D
D
D
D
D
E-34
-------
Page No.
10/04/89
TABLE E-l. (Continued)
32
sec
30300617
30300699
30300701
30300702
30300703
30300704
30300801
30300802
30300804
30300805
30300808
30300809
30300811
30300812
30300813
30300813
30300814
30300815
30300816
30300817
30300818
30300819
30300820
30300821
30300822
30300823
30300824
30300825
30300826
30300827
30300831
30300832
30300833
30300834
30300899
30300901
30300904
30300906
30300907
30300908
30300910
30300911
PROFILE
NUMBER
28401*
28401*
28401
28401*
28401*
28401*
28301*
28301*
28301*
28301*
28301*
28301*
28301*
28301*
28301
28304
28301*
28301*
28301*
28301*
28301*
28301*
28301*
28301*
28301*
28301*
28301*
28301*
28301*
28301*
41220*
41220*
41220*
41130*
90007*
28302
90004*
90004*
90004*
90004*
90004*
90004*
QUAI
D
D
C
D
D
E
E
E
E
E
E
E
E
E
0
D
E
E
E
E
E
E
E
E
E
E
- -.E
E
E
• E
E
E
E
E
E
E
E
E
E
E
E
E
E-35
-------
Page No.
10/04/89
TABLE E-l. (Continued)
33
sec
30300912
30300913
30300913
30300914
3030091S
30300916
30300917
30300918
30300919
30300921
30300922
30300923
30300924
30300925
30300931
30300932
30300933
30300934
30300935
30300936
30300998
30300999
30300999
30301001
30301002
30301002
30301003
30301004
30301004
30301004
30301004
30301005
30301005
30301005
30301005
30301005
30301006
30301007
30301008
30301008
30301008
30301009
PROFILE
NUMBER
90004*
28303
28307
28303*
90004*
28303*
28303*
28302*
28302*
90004*
90004*
90004*
90004*
90004*
90004*
90004*
90004*
90004*
90004*
90004*
90004*
90004*
28306
29304
29302
29305
29307
21102
21103
21150
21206
21101
21102
21103
21150*
21206
90005*
90005*
29303
29306
29330
21205
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
C
C
D
D
D
D
D
D
D
D
D
E
E
C
C
C
E
E-36
-------
Page No.
10/04/89
TABLE E-l. (Continued)
34
sec
30301009
30301010
30301011
30301011
30301011
30301011
30301012
30301012
30301012
30301012
30301013
30301013
30301013
30301013
30301014
30301014
30301014
30301014
30301015
30301016
30301017
30301018
30301019
30301020
30301021
30301021
30301022
30301023
30301024
30301025
30301026
30301099
30301101
30301102
30301199
30301201
30301202
30301299
30301301
30301401
30301402
30301403
PROFILE
NUMBER
29310
90005*
21102
21103
21150
21206
21102
21103
21150
21206
21102
21103
21150
21206
21102
21103
21150
21206
90005*
90005*
90005*
90005*
90005*
90005*
29301
29311
90005*
90005*
90005*
29309
90005*
90005*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
QUA!
E
E
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
E
E
E
E
E
E
E
E
E
E
E
C
E
E
E
E
E
E
E
E
E
E
E
E
E-37
-------
Page No.
10/04/89
TABLE E-l. (Continued)
35
sec
30301499
30302301
30302302
30302303
30302304
30302305
30302306
30302307
30302308
30302309
30302310
30302311
30302312
30302313
30302314
30302315
30302316
30302321
30302322
30302401
30302401
30302401
30302402
30302403
30302404
30302404
30302404
30302405
30302406
30302407
30302408
30302409
30302410
30302411
30303002
30303003
30303005
30303006
30303007
30303008
30303009
30303010
PROFILE
NUMBER
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
9001S*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
21301
21302
21320
90006*
90006*
21303
21304
21340
90006*
90006*
90006*
90006*
90006*
90006*
90006*
90007*
90007*
90007*
90007*
90007*
90007*
90007*
90007*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
I
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-38
-------
Page No.
10/04/89
TABLE E-l. (Continued)
36
sec
30303011
30303012
30303014
30303015
30303016
30303099
30330111
30388801
30388802
30388803
30388804
30388805
30390001
30390002
30390003
30390004
30390011
30390012
30390013
30390014
30390023
30390024
30399999
30400101
30400102
30400103
30400104
30400105
30400106
30400107
30400107
30400108
30400109
30400110
30400111
30400112
30400113
30400114
30400120
30400150
30400199
30400204
PROFILE
NUMBER
90007*
90007*
90007*
90007*
90007*
90007*
21150
90007*
90007*
90007*
90007*
90007*
13501*
13501*
26101*
26101*
13501*
13501*
26101*
26101*
26101*
26101*
21501
90009*
90009*
20101
90009*
90009*
90009*
20102
20103
90009*
90009*
90009*
90009*
90009*
90009*
90009*
90009*
90009*
90009*
28201*
QUA
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
D
D
E
E
E
E
D
E
E
E
E
E
E
D
D
E
E
E
E
E
E
E
E
E
E
E
E-39
-------
Page No.
10/04/89
TABLE E-l. (Continued)
37
sec
30400207
30400208
30400209
30400210
30400211
30400212
30400214
30400214
30400215
30400215
30400217
30400219
30400220
30400221
30400223
30400224
30400230
30400231
30400232
30400233
30400234
30400235
30400236
30400237
30400238
30400239
30400299
30400299
30400301
30400302
30400303
30400304
30400305
30400310
30400315
30400320
30400325
30400330
30400331
30400332
30400333
30400340
PROFILE
NUMBER
19101*
19101
19101*
19101*
19101*
19101*
19101*
29502*
19101*
29501*
19101*
19101*
19101*
19101*
19101*
19101*
19101*
19101*
19101*
19101*
19101*
19101*
19101*
19101*
19101*
19101*
20502
20503
28202
90010*
28201
90010*
90010*
90010*
90010*
90010*
90010*
90010*
90010*
90010*
90010*
90010*
QUAI
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E-40
-------
Page No.
10/04/89
TABLE E-l. (Continued)
38
sec
30400341
30400342
30400350
30400351
30400352
30400353
30400354
30400355
30400356
30400357
30400358
30400360
30400370
30400371
30400398
30400399
30400401
30400401
30400402
30400402
30400403
30400404
30400405
30400406
30400407
30400408
30400409
30400410
30400411
30400412
30400413
30400413
30400414
30400499
30400499
30400499
30400501
30400505
30400506
30400507
30400508
30400509
PROFILE
NUMBER
90010*
90010*
. 90010*
90010*
90010*
90010*
90010*
90010*
90010*
90010*
90010*
90010*
90010*
90010*
90010*
90010*
20401*
20405
20401*
20403
20401
20401*
20401*
20401*
20401*
20401*
20401*
20401*
20401*
20401*
20401*
20404
20401*
20401*
20402
20406
90008*
90008*
90008*
90008*
90008*
90008*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-41
-------
Page No.
10/04/89
TABLE E-l. (Continued)
39
sec
30400510
30400511
30400512
30400513
30400521
30400522
30400523
30400524
30400525
30400526
30400527
30400528
30400599
30400601
30400699
30400701
30400701
30400702
30400703
30400704
30400705
30400706
30400707
30400708
30400709
30400710
30400711
30400712
30400713
30400714
30400715
30400716
30400717
30400718
30400720
30400721
30400722
30400723
30400724
30400725
30400726
30400730
PROFILE
NUMBER
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
28304
28305*
90011*
90011*
28601
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
90011*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-42
-------
Page No.
10/04/89
TABLE E-l. (Continued)
40
sec
30400731
30400799
30400801
30400802
30400803
30400805
30400806
30400807
30400809
30400810
30400811
30400812
30400814
30400818
30400824
30400828
30400834
30400838
30400840
30400841
30400842
30400843
30400851
30400852
30400853
30400854
30400855
30400861
30400862
30400863
30400864
30400865
30400866
30400867
30400868
30400869
30400870
30400871
30400872
30400873
30400874
30400875
PROFILE
NUMBER
90011*
90011*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
00000*
00000*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-43
-------
Page No.
10/04/89
TABLE E-l. (Continued)
41
sec
30400876
30400877
30400899
30400901
30400999
30401001
30401002
30401004
30401005
30401006
30401007
30401008
30401010
30401011
30401099
30402001
30402002
30402003
30402004
30402099
30402201
30402210
30404001
30404901
30405001
30405099
30488801
30488802
30488803
30488804
30488805
30490001
30490002
30490003
30490004
30490011
30490012
30490013
30490014
30490023
30490024
30499999
PROFILE
NUMBER 1
90008*
90008*
20501
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
90008*
13501*
13501*
26101*
26101*
13501*
13501*
26101*
26101* o
26101*
26101*
29203
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
D
D
E
E
E
E
E
E-44
-------
Page No.
10/04/89
TABLE E-l
42
sec
30499999
30500101
30500102
30500103
30500104
30500105
30500110
30500111
30500112
30500113
30500198
30500199
30500201
30500202
30500203
30500204
30500205
30500206
30500207
30500208
30500299
30500301
30500302
30500303
30500304
30500307
30500308
30500309
30500311
30500312
30500313
30500314
30500315
30500316
30500398
30500399
30500401
30500402
30500403
30500404
30500405
30500406
. (Continued)
PROFILE
NUMBER QU
29201*
25402*
25402
25402*
25402*
25402*
25402*
25402*
25402*
25402*
25402*
25402*
90013*
90013*
90013*
90013*
90013*
26101*
13501*
13501*
90013*
90013*
90013*
90013*
26101*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
E-45
-------
Page No.
10/04/89
TABLE E-l. (Continued)
43
sec
30500499
30500501
30500502
30500503
30500504
30500505
30500598
30500599
30500606
30500607
30500608
30500609
30500609
30500610
30500610
30500611
30500612
30500613
30500614
30500615
30500616
30500617
30500618
30500618
30500619
30500619
30500699
30500706
30500707
30500708
30500709
30500710
30500711
30500712
30500714
30500715
30500716
30500717
30500718
30500719
30500799
30500801
PROFILE
NUMBER
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
27201
27201*
27201*
27201*
27205*
27201*
27205*
27201*
27201*
27201*
27201*
27201*
27201*
27201*
27201*
27204*
27201*
27204*
27201*
27203
27203*
27203*
27203*
27203*
27203*
27203*
27203*
27203*
27203*
27203*
27203*
27203*
27203*
90013*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
D
E
0
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-46
-------
Page No.
10/04/89
TABLE E-l. (Continued)
44
sec
30500802
30500803
30500899
30500901
30500902
30500903
30500904
30500905
30500906
30500907
30500908
30500909
30500910
30500999
30500999
30501001
30501002
30501003
30501004
30501005
30501006
30501007
30501008
30501009
30501010
30501011
30501012
30501013
30501014
30501015
30501016
30501017
30501021
30501022
30501023
30501024
30501030
30501031
30501032
30501033
30501034
30501035
PROFILE
NUMBER
90013*
90013*
90013*
90012*
90012*
90012*
90012*
90012*
90012*
90012*
90012*
90012*
90012*
25201
25406
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
QUAI
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-47
-------
Page No.
10/04/89
TABLE E-l. (Continued)
45
sec
30501036
30501037
30501038
30501031
30501040
30501041
30501042
30501043
30501044
30501045
30501046
30501047
30501048
30501049
30501050
30501090
30501099
30501101
30501106
30501107
30501108
30501109
30501110
30501111
30501112
30501113
30501114
30501115
30501120
30501199
30501201
30501202
30501203
30501204
30501205
30501206
30501207
30501208
30501209
30501211
30501212
30501213
PROFILE
NUMBER
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
QUA!
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-48
-------
Page No.
10/04/89
TABLE E-l. (Continued)
46
sec
30501214
30501215
30501221
30501222
30501223
30501224
30501299
30501301
30501399
30501401
30501402
30501403
30501404
30501406
30501407
30501408
30501410
30501411
30501412
30501413
30501414
30501415
30501499
30501501
30501502
30501503
30501504
30501504
30501505
30501506
30501507
30501508
30501508
30501509
30501510
30501511
30501512
30S01513
30501514
30501515
30501516
30501517
PROFILE
NUMBER
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
27102*
27102
27102*
27102*
00000*
00000*
00000*
00000*
27102*
00000*
27102*
27102*
27102*
27102*
27501
27501*
27501*
27501*
27502*
27501*
27501*
27501*
27501*
27502*
27501*
27501*
27501*
27501*
27501*
27501*
27501*
27501*
27501*
QUA
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-49
-------
Page No.
10/04/89
TABLE E-l. (Continued)
47
sec
30501518
30501519
30501520
30501520
30501521
30501522
30501599
30501601
30501602
30501603
30501604
30501605
30501606
30501607
30501607
30501608
30501608
30501609
30501610
30501611
30501612
30501613
30501614
30501615
30501615
30501616
30501617
30501699
30501701
30501702
30501703
30501704
30501705
30501799
30501801
30501899
30501901
30501902
30501903
30501904
30501905
30501999
PROFILE
NUMBER
27501*
27501*
27501
27503
27501*
27501*
27501*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
27601*
90013*
27601*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
27601*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-50
-------
Page No.
10/04/89
TABLE E-l. (Continued)
48
sec
30502001
30502001
30502002
30502003
30502004
30502005
30502006
30502007
30502008
30502009
30502010
30502011
30502012
30502013
30502014
30502015
30502016
30502020
30502099
30502101
30502102
30502103
30502104
30502105
30502106
30502201
30502299
30502401
30502499
30502501
30502502
30502503
30502504
30502505
30502506
30502507
30502508
30502509
30502510
30502511
30502601
30502699
PROFILE
NUMBER
21101*
44103
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
21101*
90013*
90013*
QUA1
D
D
D
D
D
C
D
D
D
D
D
D
D
D
D
D
D
D
D
E
E
E
E
E
E
E
E
E
E
D
D
0
D
D
D
D
D
D
D
D
E
E
E-51
-------
Page No.
10/04/89
TABLE E-l. (Continued)
49
sec
30503099
30503101
30503102
30503103
30503104
30503105
30503106
30503107
30503108
30503109
30503110
30503111
30503199
30503201
30503202
30503203
30503204
30503205
30503206
30503299
30503301
30504001
30504002
30504003
30504010
30504020
30504021
30504022
30504023
30504024
30504025
30504030
30504031
30504032
30504033
30504034
30504036
30504099
30510001
30510002
30510003
30510004
PROFILE
NUMBER
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
QUAL
E
E
E
E
E
E
E
E
' E
E
E
E
E
E
E
E
E
E
E
. E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-52
-------
Page No.
10/04/89
TABLE E-l. (Continued)
50
sec
30510005
30510006
30510007
30510101
30510102
30510103
30510104
30510105
30510106
30510107
30510108
30510196
30510197
30510198
30510199
30510201
30510202
30510203
30510204
30510205
30510206
30510207
30510208
30510296
30510297
30510298
30510299
30510301
30510302
30510303
30510304
30510305
30510306
30510307
30510308
30510396
30510397
30510398
30510399
30510401
30510402
30510403
PROFILE
NUMBER
90013*
90013*
90013*
90013*
90013*
21204
21203
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
21204
21203
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
21204
21203
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
21204
QUA!
E
E
E
E
E
C
D
E
E
E
E
E
E
E
E
E
E
C
D
E
E
E
E
E
E
E
E
E
E
C
D
E
E
E
E
E
E
E
E
E
E
C
E-53
-------
Page No.
10/04/89
TABLE E-l. (Continued)
51
sec
30510404
30510405
30510406
30510407
30510408
30510496
30510497
30510498
30510499
30510501
30510502
30510503
30510504
30510505
30510506
30510507
30510508
30510596
30510597
30510598
30510599
30515001
30515002
30515003
30515004 ,
30515005
30588801
30588802
30588803
30588804
30588805
30590001
30590002
30590003
30590011
30590012
30590013
30590023
30599999
30600101
30600102
30600103
PROFILE
NUMBER
21203
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
21204
21203
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
90013*
13501*
13501*
26101*
13501*
13501*
26101*
26101*
25401
13501*
26101*
13501*
QUAI
D
E
E
E
E
E
E
E
E
E
E
C
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
D
D
E
E
D
D
E
D
E-S4
-------
Page No.
10/04/89
TABLE E-l. (Continued)
52
sec
30600104
30600105
30600106
30600107
30600108
30600199
30600201
30600201
30600201
30600201
30600201
30600202
30600301
30600401
30600402
30600503
30600504
30600505
30600506
30600602
30600603
30600701
30600702
30600801
30600802
30600803
30600804
30600805
30600806
30600807
30600811
30600812
30600813
30600814
30600815
30600816
30600817
30600818
30600819
30600820
30600821
30600822
PROFILE
NUMBER
26101*
26101
26101*
26101*
26101*
26101*
26202
26203
26204
26205
26209
26202*
26202*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
QUA
E
E
E
E
E
E
D
D
D
D
c
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-55
-------
Page No.
10/04/89
TABLE E-l. (Continued)
53
sec
30600901
30600902
30600903
30600904
30600999
30601001
30601101
30601201
30601201
30601401
30601401
30601401
30601599
30609902
30609903
30609904
30609911
30609912
30609913
30609914
30610001
30688801
30688802
30688803
30688804
30688805
30699998
30699999
30700101
30700102
30700103
30700104
30700105
30700106
30700106
30700107
30700108
30700109
30700110
30700199
30700203
30700211
PROFILE
NUMBER
26101*
26101*
26101*
26101*
26101*
90014*
90014*
90014*
26208
90014*
26206
26207
90014*
13501*
26101*
26101*
13501*
13501*
26101*
26101*
90014*
90014*
90014*
90014*
90014*
90014*
90014*
90014*
00000*
00000*
00000*
90015*
90015*
23202
27602
00000*
90015*
90014*
23103
90015*
00000*
00000*
QUA
E
E
E
E
E
E
E
E
D
E
E
D
E
D
E
E
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
E
E
E
C
E
E
E
E-56
-------
Page No.
10/04/89
TABLE E-l. (Continued)
54
sec
30700212
30700213
30700214
30700215
30700221
30700222
30700223
30700231
30700232
30700233
30700234
30700299
30700301
30700302
30700303
30700304
30700401
30700402
30700499
30700501
30700597
30700598
30700599
30700701
30700702
30700703
30700703
30700704
30700705
30700706
30700707
30700708
30700709
30700711
30700712
30700713
30700714
30700715
30700798
30700799
30700801
30700802
PROFILE
NUMBER
00000*
00000*
00000*
00000*
90015*
90015*
90015*
90015*
90015*
90015*
24101
90015*
90015*
90015*
90015*
90015*
00000*
90015*
90015*
90015*
90015*
90015*
90015*
22301
22201
22101
22102
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
QUA
E
E
E
E
E
E
E
E
E
E
C
E
E
E
E
E
E
E
E
E
E
E
E
D
D
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-57
-------
Page No.
10/04/89
TABLE E-l. (Continued)
55
sec
30700803
30700804
30700805
30700806
30700807
30700808
30700896
30700897
30700898
30700899
30701199
30701301
30701399
30702098
30702099
30703001
30703002
30703096
30703097
30703098
30703099
30788801
30788802
30788803
30788804
30788805
30788898
30790001
30790002
30790003
30790011
30790012
30790013
30790023
30799998
30799999
30800101
30800102
30800103
30800104
30800105
30800106
PROFILE
NUMBER
90015*
22202
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
90015*
13501*
13501*
26101*
13501*
13501*
26101*
26101*
90015*
90015*
90016*
90016*
90016*
90016*
90016*
90016*
QUA
E
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
D
D
E
E
E
E
E
E
E
E
E
E
E-58
-------
Page No.
10/04/89
TABLE E-l. (Continued)
56
sec
30800107
30800108
30800109
30800110
30800120
30800121
30800122
30800123
30800197
30800198
30800199
30800501
30800699
30800701
30800702
30800703
30800704
30800705
30800720
30800721
30800722
30800723
30800724
30800799
30890001
30890002
30890003
30890011
30890012
30890013
30890023
30899999
30900198
30900199
30900201
30900202
30900202
30900203
30900204
30900205
30900206
30900207
PROFILE
NUMBER
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
13501*
13501*
26101*
13501*
13501*
26101*
26101*
90016*
90016*
90016*
90016*
90016*
25702
90016*
90016*
90016*
90016*
90016*
QUA:
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E-59
-------
Page No.
10/04/89
TABLE E-l. (Continued)
57
sec
30900208
30900298
30900299
30900301
30900302
30900303
30900304
30901001
30901097
30901098
30901099
30901101
30901102
30901103
30901104
30901199
30901501
30901601
30901604
30901605
30901606
30901607
30902099
30902501
30903004
30903005
30903006
30903099
30904001
30904010
30904020
30906001
30906099
30988801
30988802
30988803
30988804
30988805
30990001
30990002
30990003
30990011
PROFILE
NUMBER
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90001*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
25402*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
13501*
13501*
26101*
13501*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
D
E-60
-------
Page No.
10/04/89
TABLE E-l. (Continued)
58
sec
30990012
30990013
30990023
30999997
30999998
30999999
31000101
31000102
31000103
31000104
31000105
31000199
31000201
31000202
31000203
31000204
31000205
31000206
31000207
31000299
31000401
31000402
31000403
31000404
31000405
31000411
31000412
31000413
31000414
31000415
31088801
31088802
31088803
31088805
31088904
31100199
31100299
31299999
31307001
31307002
31390001
31390002
PROFILE
NUMBER
13501*
26101*
26101*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
00000*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
13501*
13501*
13501*
26101*
26101*
13501*
13501*
13501*
26101*
26101*
90016*
90016*
90016*
90016*
90016*
41350*
41350*
90016*
90016*
90016*
13501*
13501*
QUA
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
0
D
D
E
E
D
D
D
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E-61
-------
Page No.
10/04/89
TABLE E-l. (Continued)
59
sec
31390003
31399999
31400901
31401001
31401002
31401101
31401101
31401102
31401102
31499999
31501001
31501002
31501003
31502001
32099997
32099998
32099999
33000101
33000102
33000103
33000104
33000105
33000198
33000199
33000201
33000202
33000211
33000212
33000213
33000214
33000298
33000299
33000399
33000499
33000599
33088801
33088802
33088803
33088804
33088805
36000101
39000199
PROFILE
NUMBER
26101*
90016*
90016*
90016*
90016*
90016*
17109
90016*
17109
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
90016*
00000*
QUAi
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-62
-------
Page No.
10/04/89
TABLE E-l. (Continued)
60
sec
39000201
39000203
39000289
39000299
39000389
39000399
39000402
39000403
39000489
39000499
39000501
39000502
39000503
39000589
39000598
39000599
39000602
39000603
39000605
39000689
39000699
39000701
39000702
39000788
39000789
39000797
39000798
39000799
39000801
39000889
39000899
39000989
39000999
39001089
39001099
39001299
39001389
39001399
39990001
39990002
39990003
39990004
PROFILE
NUMBER
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
13501*
13501*
26101*
26101*
QUAI
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
E-63
-------
Page No.
10/04/89
TABLE E-l. (Continued)
61
sec
39990011
39990012
39990013
39990014
39990022
39990023
39990024
39999993
39999994
39999995
39999996
39999998
39999999
40100101
40100102
40100103
40100104
40100105
40100106
40100198
40100199
40100201
40100202
40100203
40100204
40100205
40100206
40100207
40100208
40100215
40100216
40100217
40100221
40100222
40100223
40100224
40100225
40100235
40100236
40100251
40100252
40100253
PROFILE
NUMBER
13501*
13501*
26101*
26101*
13501*
26101*
26101*
90016*
90016*
90016*
90016*
90016*
90016*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
QUA
D
D
E
E
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
" E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-64
-------
Page No.
10/04/89
TABLE E-l. (Continued)
62
sec
40100254
40100255
40100256
40100257
40100258
40100259
40100295
40100296
40100297
40100298
40100299
40100301
40100302
40100303
40100304
40100305
40100306
40100335
40100336
40100398
40100399
40100401
40100499
40188801
40188802
40188803
40188804
40188805
40188898
40200101
40200110
40200201
40200210
40200301
40200310
40200401
40200410
40200501
40200510
40200601
40200610
40200701
PROFILE
NUMBER
00000*
00000*
00000*
00000*
00000*
odooo*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
25403
25403*
25403*
25403*
25403*
25403*
25403*
25403*
00000*
25403*
25403*
25403*
25403*
QUAI
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-65
-------
Page No.
10/04/89
TABLE E-l. (Continued)
63
sec
40200706
40200707
40200710
40200801
40200802
40200803
40200810
40200898
40200899
40200901
40200902
40200903
40200904
40200905
40200906
40200907
40200908
40200909
40200910
40200911
40200912
40200913
40200914
40200915
40200916
40200917
40200918
40200919
40200920
40200921
40200922
40200923
40200924
40200925
40200926
40200927
40200928
40200998
40201001
40201002
40201003
40201004
PROFILE
NUMBER
00000*
00000*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
00000*
00000*
00000*
00000*
00000*
.00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
26101*
13501*
13501*
26101*
QUA!
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
• E
E
D
D
E
E-66
-------
Page No.
10/04/89
TABLE E-l. (Continued)
64
sec
40201101
40201103
40201104
40201105
40201111
40201112
40201113
40201114
40201115
40201116
40201199
40201201
40201210
40201301
40201303
40201304
40201305
40201399
40201401
40201402
40201403
40201404
40201405
40201406
40201431
40201432
40201433
40201434
40201435
40201436
40201437
40201438
40201499
40201501
40201502
40201503
40201504
40201505
40201531
40201599
40201601
40201602
PROFILE
NUMBER
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
QUA1
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-67
-------
Page No.
10/04/89
TABLE E-l. (Continued)
65
sec
40201603
40201604
40201605
40201606
40201619
40201620
40201621
40201622
40201623
40201624
40201625
40201626
40201627
40201628
40201629
40201630
40201631
40201632
40201699
40201702
40201703
40201704
40201705
40201721
40201722
40201723
40201724
40201725
40201726
40201727
40201728
40201731
40201732
40201733
40201734
40201735
40201736
40201799
40201801
40201803
40201804
40201805
PROFILE
NUMBER
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
QUA!
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
. E
E
E
E
E-68
-------
Page No.
10/04/89
TABLE E-l. (Continued)
66
sec
40201806
40201899
40201901
40201903
40201904
40201999
40202001
40202002
40202003
40202004
40202005
40202031
40202032
40202033
40202034
40202099
40202101
40202103
40202104
40202105
40202106
40202107
40202108
40202109
40202131
40202132
40202133
40202199
40202201
40202202
40202203
40202204
40202205
40202299
40202301
40202302
40202303
40202304
40202305
40202306
40202399
40202401
PROFILE
NUMBER
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-69
-------
Page No.
10/04/89
TABLE E-l. (Continued)
67
sec
40202402
40202403
40202404
40202405
40202406
40202499
40202501
40202502
40202503
40202504
40202505
40202531
40202532
40202533
40202534
40202535
40202536
40202537
40202599
40202601
40202602
40202603
40202604
40202605
40202606
40202607
40202699
40288801
40288802
40288803
40288804
40288805
40290023
40299995
40299996
40299997
40299998
40299999
40300101
40300102
40300103
40300104
PROFILE
NUMBER
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
25403*
00000*
00000*
00000*
00000*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-70
-------
Page No.
10/04/89
TABLE E-l. (Continued)
68
sec
40300105
40300106
40300107
40300108
40300109
40300110
40300111
40300112
40300113
40300114
40300115
40300116
40300150
40300151
40300152
40300153
40300154
40300155
40300156
•40300157
40300158
40300159
40300160
40300161
40300198
40300199
40300201
40300202
40300203
40300204
40300205
40300207
40300208
40300209
40300210
40300211
40300212
40300213
40300214
40300215
40300216
40300299
PROFILE
NUMBER
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
ooodo*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
. 00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-71
-------
Page No.
10/04/89
TABLE E-l. (Continued)
69
sec
40300302
40301001
40301002
40301003
40301004
40301005
40301006
40301007
40301008
40301009
40301010
40301011
40301012
40301013
40301014
40301015
40301016
40301017
40301018
40301019
40301020
40301021
40301097
40301098
40301099
40301101
40301102
40301103
40301104
40301105
40301106
40301107
40301108
40301109
40301110
40301111
40301112
40301113
40301114
40301115
40301116
40301117
PROFILE
NUMBER
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000* •
00000*
00000*
00000*
00000*
00000*
00000*
ooooo*
ooooo*
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QUA
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E
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E
E
E
E
E
E
E-72
-------
Page No.
10/04/89
TABLE E-l. (Continued)
70
sec
40301118
40301119
40301120
40301130
40301131
40301132
40301133
40301134
40301135
40301140
40301141
40301142
40301143
40301144
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40301152
40301153
40301154
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40301198
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40301203
40301204
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40301206
40301207
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40400104
PROFILE
NUMBER
00000*
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QUA
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E
E
E
E
E-73
-------
Page No.
10/04/89
TABLE E-l. (Continued)
71
sec
40400105
40400106
40400107
40400108
40400109
40400110
40400111
40400112
40400113
40400114
40400115
40400116
40400117
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PROFILE
NUMBER
00000*
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QUA
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E
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E
E-74
-------
Page No.
10/04/89
TABLE E-l. (Continued)
72
sec
40400401
40400402
40400403
40400404
40400405
40400406
40400407
40400408
40400409
40400410
40400411
40400412
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40500304
40500305
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40500411
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40500510
PROFILE
NUMBER
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QUA!
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E
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E
E
E
E
E-75
-------
Page No.
10/04/89
TABLE E-l. (Continued)
73
sec
40500511
40500512
40500513
40500598
40500599
40500601
40500701
40588801
40588802
40588803
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PROFILE
NUMBER
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E
E
E
E
E-76
-------
TABLE E-l. (Continued)
Page No.
10/04/89
74
sec
40600232
40600233
40600234
40600235
40600236
40600237
40600238
40600239
40600240
40600241
40600242
40600243
40600244
40600245
40600246
40600248
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40600257
40600259
40600298
40600299
40600301
40600302
40600305
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40600307
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40600401
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PROFILE
NUMBER
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QUAI
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E
E
E
E
E-77
-------
Page No.
10/04/89
TABLE E-l. (Continued)
75
sec
40700401
40700402
40700497
40700498
40700801
40700802
40700803
40700804
40700805
40700806
40700807
40700808
40700809
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40700898
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40701610
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PROFILE
NUMBER
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QUA
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E-78
-------
Page No.
10/04/89
TABLE E-l. (Continued)
76
sec
40702097
40702098
40703201
40703202
40703203
40703204
40703205
40703206
40703297
40703298
40703601
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PROFILE
NUMBER
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QUA
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E-79
-------
Page No.
10/04/89
TABLE E-l. (Continued)
77
sec
40704007
40704008
40704009
40704010
40704097
40704098
40704401
40704402
40704403
40704404
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PROFILE
NUHBER
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E-80
-------
Page No.
10/04/89
TABLE E-l. (Continued)
78
sec
40705207
40705208
40705209
40705210
40705211
40705212
40705213
40705214
40705215
40705216
40705217
40705218
40705297
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PROFILE
NUMBER
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QUA
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E
E
E
E
E
E
E-81
-------
Page No.
10/04/89
TABLE E-l. (Continued)
79
sec
40706017
40706018
40706019
40706020
40706021
40706022
40706023
40706024
40706097
40706098
40706401
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PROFILE
NUMBER
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QUALITY
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E-82
-------
Page No.
10/04/89
TABLE E-l. (Continued)
80
sec
40717211
40717212
40717297
40717298
40717601
40717602
40717603
40717604
40717697
40717698
40718097
40720801
40720802
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40722097
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40722802
40722803
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PROFILE
NUMBER
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QUA
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E
E
E
E
E
E
E-83
-------
Page No.
10/04/89
TABLE E-l. (Continued)
81
sec
40781202
40781601
40781602
40781603
40781604
40781605
40781699
40782001
40782002
40782003
40782004
40782005
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40784801
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40786001
40786002
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40786099
40786401
40786499
40787201
40787299
40799997
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PROFILE
NUMBER
00000*
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QUA
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E
E
E
E-84
-------
Page No.
10/04/89
TABLE E-l. (Continued)
82
sec
49000102
49000103
49000104
49000105
49000199
49000201
49000202
49000203
49000204
49000205
49000206
49000299
49000301
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49090023
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PROFILE
NUMBER
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17122
17123
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QUAI
E
E
E
E
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E
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D
D
D
D
E-85
-------
Page No.
10/04/89
TABLE E-l. (Continued)
83
sec
50100507
50100508
50100510
50100511
50100512
50100601
50100602
50100603
50.100604
50100701
50100702
50100703
50100704
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50300101
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50300105
50300106
50300107
50300108
50300109
PROFILE
NUMBER
90001*
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QUA]
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E
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E
E
E
E-86
-------
Page No.
10/04/89
TABLE E-l. (Continued)
84
sec
50300201
B0300201
50300201
50300201
50300201
50300201
50300201
50300201
50300201
50300201
50300201
50300201
50300201
50300201
50300201
50300201
50300202
50300203
50300204
50300501
S0300506
50300601
50300602
50300603
50300701
50300801
50300810
50300820
50300901
50390005
50390006
50390010
PROFILE
NUMBER
42301
42302
42304
42320*
42305
42306
42307
42308
42309
42310
42311
42312
42313
42314
42315
42316
90001*
90001*
90001*
90001*
17120*
90001*
90001*
90001*
90001*
90001*
90001*
90001*
90001*
00000*
00000*
00000*
QUA
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E-87
-------
TABLE E-2. AREA SOURCE PROFILE ASSIGNMENTS
Page No.
10/04/89
SCC
001
002
003
004
005
006
006
006
006
007
008
009
010
Oil
012
013
014
015
015
015
016
017
018
019
020
021
022
023
024
025
026
027
027
027
028
028
028
029
029
029
030
030
PROFILE
NUMBER
11201*
43201*
13501*
13501*
26101*
42330*
42317
42318
42319
11201*
11201*
13501*
13501*
26101*
12704*
11201*
11201*
11201*
44101
44104
13501*
13501*
26101*
12704*
26101*
17106*
17106*
17106*
42320*
42320*
42320*
31230*
31202
31203
31230*
31202
31203
31230*
31202
31203
31230*
31202
QUA
E
E
D
D
E
D
D
D
C
E
E
D
C
E
E
E
E
E
E
E
D
D
E
D
E
E
E
E
D
D
D
D
D
D
D
D
D
D
D
D
D
D
E-88
-------
TABLE £-2. (Continued)
Page No.
10/04/89
SCC
030
031
032
033
034
034
034
035
035
03,5
035
036
036
036
036
037
037
037
037
038
038
038
038
039
040
040
040
040
040
041
041
041
041
041
042
042
042
042
042
043
043
043
PROFILE
NUMBER
31203
31230*
31230*
31230*
31230*
25701
25703
31102*
31103
31104
31105
31102*
31103
31104
31105
31102*
31103
31104
31105
31102*
31103
31104
31105
31230*
32202*
32203
32204
32205
32206
32202*
32203
32204
32205
32206
32202*
32203
32204
32205
32206
32202*
32203
32204
QUA
0
E
E
E
E
E
E
D
D
D
C
D
D
D
C
D
D
D
C
D
D
D
C
E
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
E-89
-------
TABLE E-2. (Continued)
Page No. 3
10/04/89
PROFILE
SCC NUMBER QUALITY
043 32205 C
043 32206 C
044 32101* E
045 32202* D
046 34001* E
047 34001* E
048 34001* E
049 11201* E
050 32202* D
051 13501* D
052 31102* E
054 00000* E
055 41220* D
055 41205 0
055 44101* C
056 41220* E
057 41350* E
057 44104* C
058 41350* D
058 41321 D
058 41322 D
058 41323 D
058 41324 D
058 41351 D
059 41350* E
060 42320* E
061 42320* E
062 42320* D
062 42305 D
062 42306 D
062 42307 D
062 42308 D
062 42309 D
062 42310 D
062 42311 D
062 42312 D
062 42313 D
062 42314 D
062 42315 D
062 42316 D
063 43302* D
064 42320* E
E-90
-------
TABLE E-2. (Continued)
Page No.
10/04/89
SCC
071
072
073
074
076
077
078
079
080
081
082
083
084
085
086
087
088
089
090
091
092
093
094
095
096
097
098
099
100
101
102
103
104
105
106
107
108
109
110
110
110
110
PROFILE
NUMBER
90003*
90003*
90003*
90003*
90003*
41350*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
00000*
11201*
11501*
26101*
90016*
90001*
00000*
00000*
00000*
00000*
90002*
90002*
90016*
90013*
90001*
33020
33004
33005
33006
QUA
E
E
E
E
E
E
E
E
E
E
E
E
• E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
E
E
E
E
E
E
E
E
E
E
D
D
D
D
E-91
-------
TABLE E-2. (Continued)
Page No.
10/04/89
SCC
110
no
no
no
no
in
in
111
in
112
112
112
112
112
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
114
115
115
115
115
115
PROFILE
NUMBER
33007
33008
33009
33010
33011
32101
32102
32103
32104
34002
34003
34004
34005
34006
41130
41111
41112
41113
41114
41115
41116
41117
41118
41119
41120
41121
41122
41123
41124
41131
41132
41133
41134
41135
41136
41137
43101
43301
43304
43305
43306
43307
QUALITY
D
D
D
D
C
D
D
D
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
D
D
D
E-92
-------
TABLE 1-2. (Continued)
Page No.
10/04/89
PROFILE
SCC NUMBER QUALITY
115 43308 D
115 43309 D
E-93
-------
TABLE E-3. AREA SOURCE CODE DESCRIPTIONS
Area
Source Code
Category Description
001
002
003
004
005
006
007
008
009
010
on
012
013
014
015
016
017
018
019
020
021
022
023
024
025
026
027
028
029
Distillate Oil
Residual Oil
Natural Gas
Wood
Residential Fuel - Anthracite Coal
Residential Fuel - Bituminous Coal
Residential Fuel - Distillate Oil
Residential Fuel - Residual Oil
Residential Fuel - Natural Gas
Residential Fuel - Wood
Commercial/Institutional Fuel - Anthracite Coal
Commercial/Institutional Fuel - Bituminous Coal
Commercial/Institutional Fuel
Commercial/Institutional Fuel
Commercial/Institutional Fuel
Commercial/Institutional Fuel
Industrial Fuel - Anthracite Coal
Industrial Fuel - Bituminous Coal
Coke
Distillate Oil
Residual Oil
Natural Gas
Wood
Process Gas
On-Site Incineration - Residential
On-Site Incineration - Industrial
On-Site Incineration - Commercial/Institutional
Open Burning - Residential
Open Burning - Industrial
Open Burning - Commercial/Institutional
Light-Duty Gasoline Vehicles - Limited Access Roads
Light-Duty Gasoline Vehicles - Rural Roads
Light-Duty Gasoline Vehicles - Suburban Roads
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
E-94
-------
TABLE E-3. AREA SOURCE CODE DESCRIPTIONS (Continued)
• Area
Source Code
Category Description
030
031
032
033
034
035
036
037
038
039
040
041
042
043
044
045
046
047
048
049
050
051
052
054
055
056
057
058
059
Light-Duty Gasoline Vehicles - Urban Roads
Medium-Duty Gasoline Vehicles - Limited Access Roads
Medium-Duty Gasoline Vehicles - Rural Roads
Medium-Duty Gasoline Vehicles - Suburban Roads
Medium-Duty Gasoline Vehicles - Urban Roads
Heavy-Duty Gasoline Vehicles - Limited Access Roads
Heavy-Duty Gasoline Vehicles - Rural Roads
Heavy-Duty Gasoline Vehicles - Suburban Roads
Heavy-Duty Gasoline Vehicles - Urban Roads
Off-Highway Gasoline Vehicles
Heavy-Duty Diesel Vehicles - Limited Access Roads
Heavy-Duty Diesel Vehicles - Rural Roads
Heavy-Duty Diesel Vehicles - Suburban Roads
Heavy-Duty Diesel Vehicles - Urban Roads
Off-Highway Diesel Vehicles
Railroad Locomotives
Aircraft (Landing and Takeoff) LTO - Military
Aircraft (Landing and Takeoff) LTO - Civil
Aircraft (Landing and Takeoff) LTO - Commercial
Vessels - Coal
Vessels - Diesel Oil
Vessels - Residual Oil
Vessels - Gasoline
Gasoline Marketed
Unpaved Road Travel
Unpaved Airstrip LTOs
Construction
Miscellaneous Wind Erosion
Land Tilling
E-95
-------
TABLE 1-3. AREA SOURCE CODE DESCRIPTIONS (Continued)
Area
Source Code Category Description
060 Forest Wild Fires
061 Managed Burning - Prescribed
062 Agricultural Field Burning
063 Frost Control - Orchard Heaters
064 Structural Fires
071 Beef Cattle Manure Field Application
072 Dairy Cattle Manure Field Application
073 Hog and Pig Manure Field Application
074 Broiler Chicken Manure Field Application
075 Other Chicken Manure Field Application
076 Anhydrous Ammonia Fertilizer Application
077 Beef Cattle Feed Lots
078 Degreasing
079 Drycleaning
080 Graphic Arts (Printing)
081 Rubber and Plastics Manufacturing
082 Architectural Coating
083 Auto Body Repair
084 Motor Vehicle Manufacturing
085 Paper Coating
086 Fabricated Metals
087 Machinery Manufacturing
088 Furniture Manufacturing
089 Flat Wood Products
090 Other Transportation Equipment Manufacturing
091 Electrical Equipment Manufacturing
092 Ship Building and Repairing
093 Miscellaneous Industrial Manufacturing
094 Miscellaneous Industrial Solvent Use
E-96
-------
TABLE E-3. AREA SOURCE CODE DESCRIPTIONS (Continued)
Area
Source Code
Category Description
095
096
097
098
099
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
Miscellaneous Nonindustrial Solvent Use
Minor Utility Sources - Coal
Minor Utility Sources - Oil
Minor Utility Sources - Gas
Minor Point Sources
Publicly Owned Treatment Works (POTWs)
Fugitive Emissions from Synthetic Organic Chemical
Manufacture
Bulk Terminals and Bulk Plants
Fugitive Emissions from Petroleum Refining Operations
Process Emissions from Bakeries
Process Emissions from Pharmaceutical Manufacture
Process Emissions from Synthetic Fibers Manufacture
Crude Oil and Natural Gas Production Fields
Cutback Asphalt Paving Operations
Hazardous Waste Treatment, Storage, and Disposal
Facilities
Transportation Composite
Light-Duty Diesel Vehicles
Tire Wear
Paved Roads
Marine Aerosol .
Volcanic Ash
E-97
-------
the third column entitled "Data Quality" contains a rating of the profile
assignment. If the profile assignment is based on an original profile, the
entry for this column consists of the Profile Data Quality as it appears in
Section 3. If engineering judgement is used, the data quality is lowered one
or more level's, depending on how well the profile represents the "new" source
category.
E-98
-------
APPENDIX F
REACTIVITY FRACTIONS FOR THE ALKALINE
ELEMENTS K, Na, Ca, AND Mg
-------
F-2
-------
APPENDIX F
REACTIVITY FRACTIONS FOR THE ALKALINE
ELEMENTS K, Na, Ca, AND Mg
This appendix discusses, the development and compilation of reactivity
fractions for alkaline participate species (K, Na, Ca, and Mg). Alkaline
particulate emissions such as K, Na, Ca, and Mg can play a role in reducing
the acidity of precipitation produced by some air pollutants. "Reactivity
fraction" in this text refers to the fraction of each of these elements which
is present as an oxide, carbonate, carbide, or hydroxide. These are species
in which the cation is readily dissociated and available for reaction with
acidic solutions. The reactivity fraction would be the portion of the element
which could potentially react with acidic species. The following expression
can be used to estimate the "reactive" emissions rate in size interval Y for a
specific alkaline species Z from source category X:
"Reactive" emissions rateZ)XiY = (total particulate emissions rate,
category X) x [(1/100) x weight percent of Z, category X, size
range Y] x (reactive fraction, category X, species Z)
Total particulate emissions rate can be determined from data in National
Emissions Data System (NEDS). The PM profiles in this document provide the
composition data and this appendix contains the reactive fraction data that
would be required to carry out this calculation.
It should be noted that reactive fraction data have only been developed
for profiles contained in the earlier version of the Species Manual entitled
"Air Emissions Species Manual - Volume II, Particulate Matter Species
Profiles" (EPA-450/2-88-033b). Reactive fraction data have not been assembled
specifically for the PM profiles contained in the document "Addendum to the
Air Emissions Species Manual." The data in this appendix may be able to be
applied to these newer profiles in cases where the source categories/SCC's are
similar.
F-3
-------
In this study, reactivity fractions were developed for the PM profiles
in the Receptor Model Source Composition Library. Where applicable, the
reactivity fractions were taken directly from Reference 1 ("Anthropogenic
Sources and Emissions of Alkaline Particulate Matter in Canada"). The
reactivity data were located by using a computerized literature search and
review of references listed in useful documents. The literature search was
initiated with a preliminary run using the keywords: sodium, calcium,
potassium, magnesium, particulate emission, oxide, hydroxide, and carbonate.
Data bases used include: Biosis Previews, Enviroline, Pollution Abstracts,
CAB Abstracts, Engineering Meetings, CAsearch, and NTIS. In the second phase
of the search, the key words used were sodium, calcium, potassium, magnesium,
emissions, and source category name. NTIS, Enviroline, and Engineering
Meetings were the data bases reviewed.
Approximately 80 references were identified as possibly useful sources.
Half of the sources could be located, but only seven proved useful. Many
references contained information on K, Na, Ca, and Mg percentages but did not
indicate the species or compound with which they were associated. Therefore,
engineering judgement was used in several cases to develop estimates for the
reactivity fractions. Table F-l presents a listing of the PM profiles in the
data base and the reactivity -fractions associated with K, Na, Ca, and Mg. The
"Data Quality" column in this table indicates the confidence levels associated
with the reactivity fractions. The following rating scheme is used here to
assign data quality or confidence levels to the reactivity numbers. This is
the same scheme used in the Canadian report (Reference 1) cited above.
Data Quality Classification:
A - Based on actual source test data for a specific point source.
B - Based on limited number of tests or source measurements for
similar industries.
C - Developed from analytical data on product, feed, or other
secondary material.
D - Based on limited analytical data for category or related category
and where some estimation is involved.
E - Estimate.
F-4
-------
The last column in the table indicates the data source. For cases where no
information was identified, a default value of 0.5 was assigned as indicated
by an asterisk (*).
An attempt was made to develop better numbers for categories with "E"
ratings from the Canadian report. For example, a value of 0.70 reactive
fraction was derived for wood combustion from Reference 4 in this study. This
value is close to the 0.7B value given in the Canadian report.
In another instance, the ferroalloy and the iron/steel industry would
likely have reactivity values near 1.00. Based on Reference 5, this is due to
the high temperatures which would probably produce oxides as the only species.
The Canadian values for ferroalloy manufacture are 1.00 for Ca, Mg, and Na,
and 0.00 for K. The Canadian iron and steel industry values are 0.75, 0.88,
0.98, and 0.84 for Ca, Mg, Na, and K» respectively. These values agree well
with the estimates developed in this report.
F-5
-------
TABtE F-1. REACTIVITY FRACTIOUS
Profile
Hunter
11201
11501
11801
12201
12704
13501
17105
17106
17120
17121
17122
17123
17124
19101
20101
20102
20401
20501
20502
21101
21102
21103
21150
Man*
Coal-Fired Power Plant
Oil-Fired Power Plant
Wood-Fired Boiler with Multicyclone
External Corobustion Boiler - Coal Slurry
Wood-Fired Boiler Kith Wet Scrubber
Residual Oil Combustion
Municipal Incinerator Philadelphia
Municipal Incinerator Composite
Sewage Sludge Incinerator - Composite
Sewage Sludge Incinerator
Sewage Sludge Incinerator
Sewage Sludge Incinerator
Sewage Sludge Incinerator
Scrap Copper Incinerator
Al - Foundry - Reverb. Furnace
Secondary Aluminum Plant
Secondary Pb Smelter
Zn Oxide Kiln
Sb Oxide Plant
Limestone Dust
Primary Pb Smelting Ore Cone.
Primary Pb Smelting Ore Cone. Composite
Primary Pb Smelting Ore Cone. Composite
K
1.00
1.00
0.75
1.00
0.75
1.00
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.50
0.00
0.00
0.50
0.50
0.50
0.00
0.50
0.50
0.50
Co
0.51
0.51
0.75
0.51
0.75
0.51
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.50
0.00
0.00
0.50
0.50
0.50
1.00
0.50
0.50
0.50
Ha
1.00
1.00
0.75
1.00
0.75
1.00
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.50
0.00
0.00
0.50
0.50
0.50
1.00
0.50
0.50
0.50
Kg
1.00
1.00
0.75
1.00
0.75
1.00
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.50
0.00
0.00
0.50
0.50
0.50
1.00
0.50
0.50
0.50
Date
Quality
C
C
E*
C
E
C
E
E
E
E
E
E
E
E
D
D
E
E
E
C
E
E
E
Reference
1
1
1
1
1
1
1
1
1
1
1
1
1
*
1
1
*
*
*
1
«
*
«
-------
TABLE F-1. REACTIVITY FRACTIONS (Continued)
Profile
Number
21203
21204
21205
21206
21301
21302
21303
21304
21320
21340
21401
21501
22101
22102
22201
22202
22301
23103
23202
24101
25201
25302
25401
Name
Coke Dust
Coal Dust
Primary Pb Smelting Species Fug. Dust
Primary Pb Smelting Soda Flux Fug. Dust
Cu Ore Crushing
Cu Ore Hill Uastepile
Cu Ore Concentrate
Cu Mining Waste
Cu Ore Processing Composite
Cu Ore Composite
Feed and Grain Handling Dust
Primary Pb Smelting - Slag Dust
Particle Board Dryer
Particle Board Dryer
Wood Products - Sanderdust
Sawdust
Veneer Dryer
Kraft Recov. Furnace
Lime Kiln
Sulfite Rec. Boiler
Calcium Carbide Furnace
Charcoal Manufacturing
Silica Manufacturing
K
0.50
0.50
0.50
0.50
0.00
0.00
0.00
0.00
0.00
0.00
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.00
0.00
0.00
0.50
0.50
0.14
Ca
0.50
0.50
0.50
0.50
0.00
0.00
0.00
0.00
0.00
0.00
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.00
1.00
1.00
0.50
0.50
0.14
Na
0.50
0.50
0.50
0.50
0.00
0.00
0.00
0.00
0.00
0.00
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.05
1.00
0.05
0.50
0.50
0.14
Hg
0.50
0.50
0.50
0.50
0.00
0.00
0.00
0.00
0.00
0.00
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.00
1.00
0.00
0.50
0.50
0.14
Data
Quality
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
D
E
E
D
Reference
*
*
*
*
5
5
5
5
5
5
*
*
*
*
*
*
*
1
1
1
*
*
2
-------
TABLE F-1. REACTIVITY FRACTIONS (Continued)
i
00
Profile
Number
25402
25403
25404
25405
25406
25407
26101
26202
27102
27201
27203
27501
28201
28202
28301
28302
28303
28305
28401
28601
29101
29102
Home
Asphalt Roofing Manufacturing
Paint Spray Booth
Urea Pert. Production
Boric Acid Manufacturing
Carborundum Manufacturing
Phosphorous Plant Plume
Refinery Process Heaters - Gas
Petroleum Ref. Catalytic Cracker
Glass Furnace
Cement Kiln (Gas- Fired)
Cement Kiln (Coal-Fired)
Gypsum Calciner
Cast Fe Induction Furnace
Cast Fe Cupola
Steel Production - Steel Sinter Plant
Steel Production - Open Hearth Furnace
Steel Production - Basic Oxygen Furnace
Steel Electric Arc Furnace
Ferromanganese Furnace
Steel Foundry - Steel Heat Treating
(Salt Quench)
Al Processing
At Reduction Potline
K
0.30
0.50
0.50
0.00
0.50
0.00
1.00
1.00
0.14
0.00
0.00
0.00
0.85
0.95
0.35
0.85
0.85
0.85
0.00
0.85
0.00
0.00
Ca
0.30
0.50
0.50
0.00
0.50
0.09
0.51
0.51
0.14
0.95
0.95
0.00
0.75
0.75
0.75
0.75
0.75
0.75
1.00
0.75
0.00
0.00
Ha
0.30
0.50
0.50
0.00
0.50
0.00
1.00
1.00
0.14
0.00
0.00
0.00
0.98
0.98
0.98
0.98
0.98
0.93
1.00
0.98
0.00
0.00
Kg
0.30
0.50
0.50
0.00
0.50
0.00
1.00
1.00
0.14
1.00
1.00
0.00
0.88
0.88
0.88
0.88
0.88
0.88
1.00
0.88
0.00
0.00
Data
Quality
D
E
E'
B
E
C
C
C
D
B
B
C
E
E
E
E
E
E
C
E
D
D
Reference
2
*
*
2
*
1
1
1
2
1
1
1
1
1
1
1
1
1
1
1
1
1
-------
TABLE F-1. REACTIVITY FRACTIONS (Continued)
vo
Profile
Number
29201
29202
29301
29302
29303
29304
29305
29306
29307
29309
29330
31101
31102
31201
31230
32101
32202
33001
33002
33003
33020
Name
Cu Oxide Ki In
Primary Cu Smelter
Primary Pb Smelting - Slag Pouring
Primary Pb Smelting - Blast Furnace
Primary Pb Smelting - Zn Fuming
Primary Pb Smelting - Sintering
Primary Pb Smelting - Blast Furnace Upset
Primary Pb Smelting - Zn Baghouse
Primary Pb Smelting * Dross Reverb.
Furnace
Primary Pb Smelting - Sinter Production
Primary Pb Smelting - Zn Process
Composite
Light-Duty Vehicles - Leaded
Heavy-Duty Vehicles - Leaded
Light-Duty Vehicles - Unleaded
Light-Duty Vehicles Composite
Light-Duty Vehicles - Diesel
Heavy-Duty Diesel
Leaded/Unleaded Gas Composite - 1977
Transportation Composite - Medford, OR
(1980)
Transportation Composite - Portland, OR
(1979)
Transportation Composite
K
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.00
0.00
0.00
0.00
0.00
Jo.oo
0.00
0.00 "
0.00
0.00
Ca
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Na
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Mg
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Data
Quality
E
E
E
E
E
E
E
E
E
E
E
E
E
E
'E
E
E
E
E
E
E
Reference
*
*
*
*
*
*
*
*
*
*
*
1
1
1
1
1
1
1
1
1
1
-------
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