EPA-450/3-83-010b
Inorganic Arsenic Emissions from
  Primary Copper Smelters and
          Arsenic Plants —

   Background  Information for
      Promulgated Standards
         Emission Standards and Engineering Division
        U.S. ENVIRONMENTAL PROTECTION AGENCY
             Office of Air and Radiation
         Office of Air Quality Planning and Standards
        Research Triangle Park, North Carolina 27711

                 May 1986

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This report has been reviewed by the Emission Standards and Engneering Division of the Office of Air
Quality Planning and Standards, EPA, and approved for publication. Mention of trade names or commercial
products is not intended to constitute endorsement or recommendation for use. Copies of this report are
available through the Library Services Office (MD-35), U.S.Environmental Protection Agency, Research
Triangle Park, N.C, 27711, or from the National Technical Information Services, 5285 Port Royal Road,
Springfield. Virginia 22161.

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                     ENVIRONMENTAL PROTECTION AGENCY

                     Background Information ana Final
                      Environmental Impact Statement
                       for Primary Copper Smelters
                          and Arsenic Plants
                               Prepared by:
        Tarmer
  irector, Emission Standards and Engineering Division
U. S. Environmental Protection Agency
Research Triangle Park, NC  27711
/(Date)
1.  The emission standards will limit emissions of inorganic arsenic
    from existing and new primary copper smelters and arsenic plants.
    The standards implement Section 112 of the Clean Air Act and are
    based on the Administrator's determination of June 5, 1980 (45 FR
    37886), that inorganic arsenic presents a significant risk to human
    health as a result of air emissions from one or more stationary
    source categories, and is, therefore, a hazardous air pollutant.
    Only one primary copper smelter, located in the State of Texas,
    and one arsenic plant located in Tacoma, Washington, would be
    affected.

2.  Copies of this document have been sent to the following Federal
    Departments:  Labor, Health and Human Services, Defense, Transpor-
    tation, Agriculture, Commerce, Interior, and Energy; the National
    Science Foundation; the Council on Environmental  Quality; members
    of the State and Territorial Air Pollution Program Administrators;
    the Association of Local  Air Pollution Control  Officials; EPA
    Regional Administrators;  and other interested parties.

3.  For additional information contact:

    Mr. Robert L. Ajax
    Standards Development Branch (MD-13)
    L). S.  Environmental Protection Agency
    Research Triangle Park,  NC  27711
    telephone:   (919) 541-5578

4.  Copies of this document may be obtained from:

    U. S.  EPA Library (MD-35)
    Research Triangle Park,  NC  27711

    National  Technical  Information Service
    5285 Port Royal  Road
    Springfield, VA   22161

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                          TABLE OF CONTENTS
                                PART I
          National Emission Standard for Inorganic Arsenic
          Emissions from Primary Copper Smelters
Section
I -1.0   SUMMARY  .................... . .................... . .....   i-i-i
      1-1.1  Summary of Changes Since Proposal  . . ..............   1-1-2
      1-1.2  Summary of Impacts of the Promulgated  Action ......   1-1-3
           1-1.2.1  Alternatives to Promulgated Action .........   1-1-3
           1-1.2.2  Environmental and Health Impacts
                    of Promulgated Action ........... . ..... ......   1-1-3
           1-1.2.3  Energy and Economic Impacts
                    of Promulgated Action ........ . ........ .....   1-1-3
1-2.0   GENERAL COMMENTS ON THE PROPOSED STANDARD  . ____ . ........   1-2-1
      1-2.1  General Opinions in Favor of the Proposed Standard.   1-2-1
      1-2.2  Distinction Between High-and Low-Arsenic  Copper
             Smelter Categories ................................   1-2-1
      1-2.3  New High-Arsenic Copper Smelters  .................   1-2-2
      1-2.4  Applicability of the Standard ................... ...   1-2-2
      1-2.5  Applicability Based on Converter Charging Rate  ____   1-2-4
      1-2.6  Public Hearings  ..................................   1-2-5
      1-2.7  Requests for Technical Assistance .................   1-2-5
      1-2.8  Opportunity for Comment on New Docket  Additions ...   1-2-6
      1-2.9  Enforcement and Reporting  of Violations  ..........   1-2-7
1-3.0   LEGAL AND POLICY ISSUES  ...............................   1-3-1
      1-3.1  Requirements of Section 112 of the Clean  Air Act.     1-3-1
      1-3.2  Selection  of Best Emission Controls ..............   1-3-1
      1-3.3  Reliance on Other Standards to Achieve  Control  ....   1-3-2
      1-3.4  Startups,  Shutdowns,  and Malfunctions   ...........   1-3-4
1-4.0   ARSENIC EMISSION ESTIMATES   ... .........................   1-4-1
                                    v

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                              TABLE OF CONTENTS
                              PART I (Continued)
Section                                                           Page
      1-4.1  ASARCO, Incorporated, Smelters	   1-4-1
            1-4.1.1  Hayden Smelter	   1-4-1
            1-4.1.2  El Paso Smelter 	   1-4-5
      1-4.2  Kennecott Smelters  	   1-4-8
            1-4.2.1  Utah Smelter  	   1-4-8
            1-4.2.2  Hayden Smelter	   1-4-10
            1-4.2.3  McGill Smelter	   1-4-11
      1-4.3  Phelps Dodge Smelters  	   1-4-13
            1-4.3.1  Morenci Smelter  	   1-4-13
            1-4.3.2  Ajo Smelter  	   1-4-14
            1-4.3.3  Hidalgo Smelter	   1-4-15
      1-4.4  General Comment on Emission  Estimates  	  1-4-16
1-5.0   HEALTH RISK ASSESSMENT  	  1-5-1
1-6.0   EMISSION CONTROL TECHNOLOGY  	  1-6-1
      1-6.1  Selection of Best Available  Technology  (BAT)  for
             Specific Smelters  	   1-6-1
            1-6.1.1  BAT for Converter Operations at Kennecott-
                     Utah 	   1-6-1
            1-6.1.2  BAT for Converter Operations at ASARCO
                     Smelters 	   1-6-2
            1-6.1.3  BAT for Furnace Process Emissions at
                     ASARCO-E1  Paso 	   1-6-3
            1-6.1.4  BAT for Furnace Process Emissions at
                     Phelps Dodge-Ajo	   1-6-4
      1-6.2  Furnace Offgas Cooling as  a  Control Option 	   1-6-7
      1-6.3  Determination  of Equivalent  Control Technologies ..   1-6-14
      1-6.4  Work Practices  	   1-6-15
                                  vi

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                           TABLE OF CONTENTS
                           PART I (continued)
Sect i on                                                            Page
       1-6.5  General Comments on Best Emission Controls	  1-6-17
       1-6.6  Additional Control Opportunities  	  1-6-21
1-7.0   COMMENTS ON PROPOSED EMISSION LIMIT	  1-7-1
       1-7.1  Emission Limit Too Stringent  	  1-7-1
       1-7.2  Emission Limit Too Weak  	  1-7-3
1-8.0   COST ESTIMATES AND ECONOMIC IMPACTS	  1-8-1
       1-8.1  Cost Estimates for Proposed Controls 	  1-8-2
             1-8.1.1  ASARCO, Incorporated Smelters  	  1-8-2
             1-8.1.2  Kennecott Smelters	,.  1-8-7
             1-8.1.3  Phelps Dodge Smelters  	  1-8-13
       1-8.2  Comments on Economic Impacts	  1-8-18
             1-8.2.1  Basis for Economic Analysis Unexplained ...  1-8-18
             1-8.2.2  Insufficient Economic Data 	  1-8-19
             1-8.2.3  Economic Impacts Versus Health Risks  	  1-8-19
             1-8.2.4  Financial  Relief for Affected Groups  	  1-8-20
1-9.0   COMPLIANCE PROVISIONS  	  1-9-1
       1-9.1   Panel Approach	  1-9-1
       1-9.2   Operation and Maintenance Requirements	  1-9-2

1-10.0  TEST METHODS AND MONITORING  	  1-10-1
       1-10.1  Proposed Methods 108 and 108A  	  1-10-1
             1-10.1.1  Method 108 More Appropriate for
                       Measuring Arsenic  	  1-10-1
             1-10.1.2  Problems With Methods 108 and 108A  	  1-10-2
             1-10.1.3  Misprint  	  1-10-3

                                 vii

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                            TABLE OF CONTENTS
                            PART I (concluded)
Section                                                          Page
       1-10.2  Proposed Opacity Monitoring Requirements  	    1-10-4
       1-10.3  Waiver of Sampling Requirements  	    1-10-5
I-11.0  REFERENCES	    1-11-1

                                 PART II
                 National Emission Standard for Inorganic
                      Arsenic Emissions from Arsenic
                      Trioxide and Metallic Arsenic
                          Production Facilities
II-l.O  SUMMARY 	    II-l-l
      II-l.l  Summary of Changes Since Proposal  	    II-l-l
      II-1.2  Summary of Environmental, Health, Energy,
              and Economic Impacts  	    II-1-2
II-2.0  SUMMARY OF PUBLIC COMMENTS ON THE PROPOSED STANDARD...    I1-2-1
        II-2.1  Arsenic Emission Estimates  	,	    II-2-1
                II-2.1.1  Arsenic Plant Process Emissions ....    II-2-1
                II-2.1.2  Low-Level Emissions from the
                          Arsenic Plant	    11-2-2
        II-2.2  Comments on Proposed Control  Technology  	    II-2-4
        II-2.3  Operation and Maintenance Requirements   	    11-2-5
        II-2.4  Reporting and Recordkeeping  	    II-2-8
        II-2.5  Need for an Ambient Standard   	    II-2-8
II-3.0  REFERENCES  	    II-3-1
                                 viii

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                             Part III
                            Appendices

APPENDIX A  -  List of Commenters on Proposed Standards for
               High- and Low-Arsenic Primary Copper Smelters..   A-l

APPENDIX B  -  Smelter Arsenic Mass Balances	   B-l

APPENDIX C  -  Inorganic Arsenic Risk Assessments for
               Primary Copper Smelters	   C-l

APPENDIX D  -  Summary of Test Results for Air Curtain"
               Secondary Hood System at ASARCO-Tacoma 	   D-l

APPENDIX E  -  Demonstrated Control Device Performance to
               Achieve the Limit for Converter Secondary
               Emissions	   E-l

APPENDIX F  -  Economic Impact	   F-l

APPENDIX 6  -  Development of Main Stack and Low-level
               Arsenic Emission Rates for the Arsenic
               Plant at ASARCO-Tacoma  	   6-1

APPENDIX H  -  Summary of Test Results for the Arsenic
                   Plant Baghouse at ASARCO-Tacoma  	   H-l

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                                LIST OF TABLES

Title                                                               Page

 4-1      EPA Proposal and Revised Baseline Arsenic
          Secondary Emission Estimates for Converter
          Operations 	   1-4-17

 5-1      Comparison of Risk Estimates Made by the
          Companies and EPA  	   1-5-9

 6-1      Current Control Status of Smelter Process Streams
          where Cooling Could Potentially be Applied   	   1-6-10

 6-2      Estimated Annual Incidence Due to Process Emissions
          at Smelters where Gas Cooling is a Control Option  	   1-6-11

 6-3      Preliminary Estimates of Costs to Apply Gas  Cooling
        •• as a Control Option  	   1-6-12

 8-1      Fugitive Emission Control Costs for Kennecott-Utah ....   1-8-8

 8-2      Annualized Costs and Arsenic Emission Reductions
          Due to Secondary Emission Controls at Kennecott-
          Utah 	'	   1-8-12

 8-3      Cost Estimates for Converter Secondary Arsenic
          Controls	   1-8-17

 C.I      Summary of Quantitative Risk Analyses 	   C-8

 C.2      Combined Unit Risk Estimates for Absolute-Risk Linear
          Models  	   C-9


 C.3      Arsenic Concentrations Near Selected Primary Copper
          Smelters 	   C-12

 C.4      Estimated Arsenic Concentrations Near ASARCO-E1 Paso
          Based  on HEM Calculations 	   C-21

 C.5      Estimated Arsenic Concentrations Near ASARCO-E1 Paso
          Based  on ISCLT and Valley Model  Calculations	   C-22

 C.6      Estimated Arsenic Concentrations Near ASARCO-E1 Paso
          Based  on Building Downwash ISCLT and Valley Model
          Calculations	   C-23

 C.7      Estimated Arsenic Concentrations Near Phelps Dodge-
          Douglas Based  on HEM  Calculations   	  C-24

 C.8      Estimated Arsenic Concentrations Near Phelps Dodge-
          Douglas Based  on ISCLT and  Valley  Model  Calculations...  C-25

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                         LIST OF  TABLES  (continued)

C.9      Estimated Arsenic Concentrations  Near Phelps Dodge-
         Douglas Based on Building  Downwash  ISCLT and Valley
         Model  Calculations  	  C-26

C.10     Revisions of HEM Predicted Maximum  Concentrations
         to Which Individuals are Exposed	  C-29

C.ll     Predicted Maximum Concentrations  to Which  Individuals
         are Exposed Near Two Smelters Based on  ISCLT Site-
         Specific Modeling  ..	  C-30

C.12     Identification of Primary  Copper  Smelters	  C-31

C.13     Primary Copper Smelter Input Data to Exposure Model
         (Assuming Baseline Controls) 	  C-32

C.14     Primary Copper Smelter Input Data to Exposure Model
         (Assuming Best Controls  on Converter Operations)  	  C-36

C.15     Input Data to Exposure Model Low-Arsenic Primary
         Copper Smelters (Assuming  BAT Controls  at  Converter
         Operations and Matte and Slag Tapping Operations) ....  C-40

C.16     Total  Exposure to Inorganic Arsenic Near Primary
         Copper Smelters  	 	  C-44

C.17     Public Exposure Near Primary Copper Smelters Based on
         HEM Calculations	  C-45

C.18     Maximum Lifetime Risks for Primary  Copper  Smelters ...  C-49

C.19     Annual Incidence Estimates for  Primary  Copper Smelters. C-50

D-l      Air Curtain Capture Efficiencies  at ASARCO-Tacoma
         Using Gas Tracer Method  -  January 14, 1983 	  D-5

D-2      Air Curtain Capture Efficiencies  at ASARCO-Tacoma
         Using Gas Tracer Method  -  January 17-19, 1983 	  D-5

D-3      Air Curtain Capture Efficiencies  at ASARCO-Tacoma
         for Special Gas Tracer Injection  Points -
         January 18-20, 1983	  D-6

D-4      Summary of Filterable  and  Gaseous Arsenic  Emission
         Data	  D-9

D-5      Development of Arsenic Emission Factors 	  D-ll
                                    XI

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                         LIST OF TABLES (concluded)
 E-l       EAF  and  AOD  Vessel Fabric Filter Design
          Speciffcations  	 E-4
 E-2       Summary  of Particulate Emission Data for Fabric Filter
          Control  Devices Used for EAF and AOD Vessels 	 E-5
 F-l       Smelter  Ownership, Production and Source Material
          Arrangements 	 F-4
 F-2       United States and World Comparative Trends in Copper
          Production:  1963-1981 	 F-7
 F-3       U.S. Copper  Consumption 	 F-9
 F-4       U.S. Copper  Demand by Market End Uses 	 F-10
 F-5       Average  Annual Copper Prices 	 F-13
 F-6       Increase in  Cost of Producing Copper Due to Arsenic
          Controls for Primary Copper Smelters 	 F-23
 F-7       Maximum  Percent Price Increase for Arsenic Controls
          for  Primary  Copper Smelters 	 F-24
 F-8       Business Segment Return on Sales for Copper Companies..F-27
 F-9       Maximum  Percent Profit Decrease for Arsenic Controls
          for  Primary  Copper Smelters 	 F-29
 F-10      Review of Primary Copper Smelters 	 F-31
 F-ll      Capital  Costs of Arsenic Controls for Primary Copper
          Smelters 	   P-34
 F-12      Number of Employees at Companies That Own Primary
          Copper Smelters	   p-37
 G-l       Low-Level Arsenic Emission Rates for the Arsenic
          Plant at ASARCO-Tacoma	   G-4
 H-l      Summary of Arsenic Plant Baghouse Test Activity  	   H-3
H-2      Summary of Arsenic Plant Baghouse Sample and  Flue
         Gas Data   	   H-5
H-3      Summary of Arsenic Plant Emission Data 	   H-7
H-4      Analytical  Results for  Arsenic  Plant Test Samples ...   H-10
                                xii

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                              LIST OF FIGURES
Title
B-l
B-2
B-3

B-4

B-5
B-6
B-7
B-8
B-9
B-10
B-ll
B-12
B-13
B-14
C-l

C-2
C-3
C-4

D-l
D-2
E-l

E-2
Arsenic Distribution at ASARCO-E1  Paso Smelter
Arsenic Distribution at ASARCO-Hayden Smelter  '.
Arsenic Distribution at Tennessee  Chemical Co.-
Copperhill Smelter  	
Arsenic Distribution at Inspiration  Consolidated  -
Miami Smelter  	
Arsenic Distribution at Kennecott-Utah  Smelter	
Arsenic Distribution at Kennecott-Hayden Smelter  	
Arsenic Distribution at Kennecott-Hurley Smelter  .;	,
Arsenic Distribution at Kennecott-McGill Smelter   	,
Arsenic Distribution at Magma-San Manuel Smelter	
Arsenic Distribution at Phelps Dodge-Ajo Smelter  	,
Arsenic Distribution at Phelps Dodge-Douglas  Smelter  ...
Arsenic Distribution at Phelps Dodge-Hidalgo  Smelter  ...,
Arsenic Distribution at Phelps Dodge-Morenci  Smelter  ...
Arsenic Distribution at Copper Range-White  Pine Smelter  ,
Group 2 Enumeration District/Block Group  (ED/BG)
Interpolation	
Arsenic Monitoring Data, ASARCO-E1  Paso
Arsenic Monitoring Data, ASARCO-Hayden
Predicted Versus Measured Inorganic Arsenic
Ambient Concentrations	
    Tracer Injection Matrix
Tracer Injection Test Ports
Particle Size Distributions of Copper Converter
and EAF Skimming Gas Streams	
Particle Size Distribution of EAF/AOD Vessel  Gas  Streams
During Heat Cycles	
Page
B-3
B-4

B-5

B-6
B-7
B-8
B-9
B-10
B-ll
3-12
B-13
B-14
B-15
3-16

C-14
C-17
C-18

C-20
D-3
D-4

E-6

E-7
                                    xiii

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                        LIST OF FIGURES (concluded)
Title
E-3   Particle Size Distributions of Copper  Converter
      Charging and EAF/AOD Vessel Meltdown Gas  Streams  	  E-9

H-l   Arsenic Plant Gas Flow Schematic — ASARCO-Tacoma  	  H-9
                                   xiv

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                               FINAL EIS
        National  Emission Standards for Hazardous Air Pollutants

PART I  -  NATIONAL EMISSION STANDARD FOR INORGANIC ARSENIC
           EMISSIONS FROM PRIMARY COPPER SMELTERS

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                            1-1.0  SUMMARY

     On July 20, 1983, the U.S. Environmental Protection Agency (EPA)
proposed national emission standards (48 FR 33112) for hazardous air
pollutants (NESHAP) under authority of Section 112 of the Clean Air Act
(III-A-1).  The standards were proposed both for primary copper smelters
processing feed materials containing less than 0.7 percent arsenic (low-
arsenic smelters) and for smelters processing feed materials containing
0.7 percent or greater arsenic (high-arsenic smelters).  There were 19
commenters on the proposed low-arsenic standard, consisting of copper
companies, environmental organizations, a trade union, two States, and
several private citizens.  Some of the commenters also testified at a
public hearing held in Washington, D.C.  The proposed high-arsenic
smelter standard had nearly 700 commenters, most of whom were private
citizens.  Many comments also were received at public hearings in
Tacoma, Washington, and Washington, D.C.

     The public comment period beginning at proposal was originally
scheduled to end on September 30, 1983.  However, the comment period
was first extended to December 10 (48 FR 38009) and then reopened until
January 31, 1984 (48 FR 55880), in order to provide an opportunity for
comment on modeling results being released at that time and other
aspects of the rulemaking (IV-I-1, IV-I-3).  After considering the
comments received during this 6-month period, the Agency reconsidered
the control cost and arsenic emission estimates it had made at proposal,
and made several changes to these estimates based on public comments...
(see Sections 1-4 and 1-8).  These revised estimates (in the form of
responses to comments on the original estimates) were summarized in a
memorandum dated August 31, 1984, which was placed in1;o the docket
(docket No. A-80-40) for the copper smelter arsenic standard (item No.
IV-B-32).  Public comments on the revised estimates were solicited in a
Federal Register notice (49 FR 36877) dated September 20, 1984 (IV-I-4).
Comment letters, all dated November 5, 1984, were received from three
copper companies and one State environmental agency.  Due to time
limitations, the original responses in the response memorandum mentioned
above have been retained largely in their original form for this document,
with modifications as appropriate to accommodate the November comments.

     At the time of proposal, the only existing high-arsenic smelter
(feed material  with arsenic content of 0.7 weight percent or more) was
the ASARCO-Tacoma smelter.  ASARCO announced on June 27, 1984, its
intention to close permanently the Tacoma smelter by June 1985 (IV-D-802)
and subsequently has ceased copper smelting operations at Tacoma.   As a
result of this development, EPA is withholding further action on the
proposed regulation for existing high-arsenic copper smelters and is
including in this document significant comments addressed toward high-
arsenic smelters that also pertain to the remaining smelters.  Comments
pertaining specifically to the high-arsenic smelter category have not
been included.   However, material  related to ASARCO1s arsenic production
plant at Tacoma (which will remain in operation) has also been included
in this document.  (Material  pertaining to the arsenic plant has been
designated as Part II.)   The preamble to the final regulations also
discusses these issues, as well  as several  additional aspects of EPA's
regulatory policy with regard to hazardous air pollutants.  Public

                                1-1-1

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 comments and the Agency's responses served as the primary basis for the
 revisions made to the standard between proposal  and promulgation.

 1-1.1 SUMMARY OF CHANGES SINCE PROPOSAL

      Several changes of varying importance have  been made to the
 standard since proposal.  The standard was changed as a result of
 public comments and the Agency's reanalysis of inorganic arsenic emis-
 sions, health risk, and the reasonableness of applying controls at
 specific smelters.   Significant changes have been made, in particular,
 to the applicability provisions of the regulation, the opacity monitoring
 requirements, and the requirements for control  of fugitive emissions
 from matte and slag tapping operations.  In addition, at the suggestion
 of commenters, requirements for control of excess emissions during
 malfunctions and upsets have been added.

      The standard being promulgated is applicable to new and existing
 primary copper smelters.  The proposed standard  was applicable to  new
 and existing low-arsenic smelters, and a  separate standard was proposed
 for high-arsenic smelters.   Primary copper smelting operations were
 recently suspended  at ASARCO's smelter at Tacoma, Washington.   Since
 this was the only high-arsenic copper smelter, the low-arsenic
 smelter designation is no longer being applied to the remaining domestic
 smelters.  These smelters will now be referred to simply as the existing
.primary copper smelters.  The standard for converter secondary emissions
 now applies to all  converters at a smelter where the total  annual
 average arsenic feed rate to all  converters is 75 kilograms per hour
 (kg/h), or greater  (the cutoff at proposal  was 6.5 kg/h).   With these
 changes, it is projected that the standard will  affect only one existing
 primary copper smelter (ASARCO's smelter  in El Paso, Texas).

      The standard no longer includes   provisions requiring fugitive
 emission controls on matte  and slag tapping operations.   The Agency's
 revised arsenic emission estimates since  proposal  indicate that the
 small  reduction in" public health risk resulting  from matte and slag
 tapping controls does not warrant the imposition of these  controls  at
 any of the existing smelters.

      Provisions have been added to the standard  requiring  that steps
 be taken to minimize emissions during malfunctions and upsets, and
 requiring operation and maintenance of equipment in a manner that  avoids
 preventable malfunctions.

      The proposed standard  required reporting of all  6-minute  average
 opacity levels greater than  the 97.5  percent upper confidence  level of
 a  normal  or log-normal  distribution of the  6-minute average  opacity
 levels monitored during the  emission  test.   This  requirement  has been
 revised  to require  establishment  of reference opacity levels  based  on
 the  highest 1-hour  average  opacity level  monitored during  a  36-hour
 evaluation period.   The evaluation period will include  the  time  period
 during which  the emission test for the  control device is conducted.
 Occurrences of 1-hour average  opacity levels above the  reference
 level  must be  reported as excess  emissions.
                                 1-1-2

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1-1.2  SUMMARY OF IMPACTS OF THE PROMULGATED ACTION

1-1.2.1  Alternatives to Promulgated Action

     Regulatory alternatives were presented in two documents released
at proposal.  Alternatives for high-arsenic copper smelters were
discussed in Section 4 of background information document EPA-450/
3-83-009a (hereinafter referred to as the high-arsenic BID, Volume I,
item III-B-1 in docket No.  A-80-40).  Alternatives for low-arsenic
smelters were discussed in Section 4 of EPA-450/3-83-010a (low-
arsenic BID, Volume I, III-B-2).  The regulatory alternatives for both
source categories were also covered in the preambles to the proposed
standards (48 FR 33112).  These alternatives remain the same.

1.2.2  Environmental and Health Impacts of Promulgated Action

     The final standard affects existing and any new primary copper
smelters.  The EPA projects that the standard will affect only one
existing domestic copper smelter, and that no new domestic copper
smelters will be constructed in the next 5 years.

     The standard will reduce secondary inorganic arsenic emissions
from the affected smelter by about 1 to 4 megagrams (Mg) per year
(1.1 to 4.4 tons per year).  As a result of this emission reduction,
EPA estimates that the number of incidences per year of lung cancer due
to inorganic arsenic exposure for persons residing within 50 kilometers
(31 miles) of the affected smelter will be reduced from 0.38 to 0.29 case
per year.  The standard will reduce the estimated maximum lifetime risk
from exposure to airborne inorganic arsenic near the affected smelter
from (1 x 10-3) to (8 x 10~4).  These estimated health impacts are
based on a number of assumptions and contain considerable uncertainty.
Appendix C of this document discusses the health impact calculations
further.

     Application of the required controls (air curtain secondary hoods
on converters) will increase slightly the amount of solid waste to be
handled by the affected smelter.  This solid waste will consist of
additional dust collected by the currently operated baghouse.  The
additional baghouse catch of 3.6 Mg/yr of arsenic, or 18 Mg/yr of total
dust, will increase the amount collected by the baghouse by only about
5 percent.  This added dust can be handled easily by the smelter and
will not produce any significant environmental impact.  No direct water
pollution impact is created by the standard, because the baghouse
collecting converter secondary emissions at the affected smelter is a
dry collection system.

1.2.3  Energy and Economic Impacts of Promulgated Action

     The standard will increase electrical power consumption at the
affected smelter by approximately 2,000 MW, or 0.1 percent above
current plant energy requirements.

     The capital and annualized costs of complying with the standard are
estimated to be about $1.85 million and $379,000 per year, respectively.

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The primary economic impact associated with the standard is a projected
decrease in profitability for the affected smelter if costs cannot be
passed through in the form of product price increases.   It is estimated
that if control costs are passed through, the standard  will result in a
0.2 to 0.3 percent increase in the price of copper (see Appendix F).
No plant closures are anticipated as a result of the regulation
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        1-2.0  GENERAL COMMENTS ON THE PROPOSED STANDARD

1-2.1  GENERAL OPINIONS IN FAVOR OF THE PROPOSED STANDARD

     Comment:  Tennessee Chemical  Company expressed agreement and
support for the proposed standard, referring to the "non impact" of its
Copperhill, Tennessee copper smelter.  (Tennessee Chemical-Copperhil1
fell well  below the cutoffs for applicability in the proposal.)
(IV-D-140).  Magma Copper Company similarly stated its agreement with
EPA's finding in the proposal  that the existing furnace controls at  ,
Magma's San Manuel smelter constitute best available technology (BAT),
and that additional fugitive emission controls would not be cost effec-
tive (IV-D-619).  The State of Washington Department of Ecology concurred
with EPA's determination that the "very small emitters" among the
low-arsenic copper smelters should be excluded from BAT requirements
(IV-D-622).

     Response:  No response necessary.

1-2.2  DISTINCTION BETWEEN HIGH- AND LOW-ARSENIC COPPER SMELTER CATEGORIES

     Comment:  One commenter noted that no rationale or explanation has
been presented for how EPA selected the cutoff used at proposal to
differentiate between high- and low-arsenic throughput smelters (IV-F-4).

Response:   As discussed in the Federal Register notice of proposed
rulemaking (48 FR 33112), EPA separated the primary copper smelting
industry into two source categories based on the annual average inorganic
arsenic content of the smelter feed material.  From information provided
by the copper smelting industry, EPA determined that the arsenic content
of the feed processed by the ASARCO-Tacoma smelter was an order of
magnitude  greater than that for the other 14 primary copper smelters
located in the United States.   Typically, feed material containing on
the average 4.0 weight percent inorganic arsenic was processed at the
ASARCO-Tacoma smelter at a rate of 940 kilograms of inorganic arsenic
per hour (kg/h).  The second highest average inorganic arsenic content
in the feed material processed at a domestic smelter is 0.5 weight
percent, while the second highest average process rate of inorganic
arsenic is.approximately 265 kg/h.  In addition, unlike at the other 14
smelters,  arsenic is processed in an arsenic production plant at the
ASARCO-Tacoma smelter and sold for commercial use.

     The EPA believes it was reasonable at proposal for purposes of
regulation to separate smelters into two source categories based on the
annual  average inorganic arsenic content in the feed because of the
potential  for significantly higher inorganic arsenic emissions from the
ASARCO-Tacoma smelter than from other smelters.  Consequently, the
benefits associated with the application of specific control technolo-
gies to the ASARCO-Tacoma smelter versus other smelters would be
significantly different when considered in terms of emission and risk
reduction, costs, and energy and other impacts.  Of course, since
ASARCO has recently closed copper smelting operations at Tacoma, all
existing primary copper smelters are now in the same category and the
distinction based on arsenic input is no longer necessary.   Further, as
discussed  in Section 1-2.3, EPA projects that no new domestic smelters

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 will  be constructed in the next  5  years.   Therefore,  the  commenter's
 concern is  no  longer pertinent since  all  smelters  at  this  time  and  in
 the foreseeable future will  be regulated  on  a  common  basis  and  in a
 single  source  category.

 1-2.3   NEW  HIGH-ARSENIC COPPER SMELTERS

      Comment:   The  Friends of the  Earth commented  that  no  reason was
 given in the  Federal  Register notice  of proposed rulemaking  or  the
 background  information documents as to why EPA believed that new smelters
 using high-arsenic  feed  material would not be  built (IV-0-609).

      Response:   The Federal  Register  notice  of proposed rulemaking states
 that  EPA projected  that  no new domestic primary copper  smelters would  be
 built during the next 5  years (48  FR  33124).   This  projection is based on
 EPA's conclusion that annual  copper industry growth in  the  United States
 will  be accommodated  by  existing primary  copper smelting  capacity.
 Neglecting  the  low  copper  production  in 1980 as a  result  of  a smelter
 worker  strike and in  1982  as  a result of  a recession, total  copper pro-
 duction in  the  United States  has averaged 1,380 gigagrams  per year
 (Gg/yr) since 1977.   Current  primary copper  smelting capacity in the
 United  States is about 1,632  Gg/yr.* The  net effect of  potential shut-
 downs and smelter expansions  on total capacity by  1988  is estimated to
 be  a  decline in capacity to -1,435  Gg/yr.   However, the  increase in
 utilization to  a 90 percent rate is not expected to require  new capacity
 based on the lack of  long-term growth in  smelter production  over
 recent  years.   Thus,  EPA does not  expect  any new primary copper smelter
 processing  either high-arsenic or  low-arsenic  feed to be constructed
 in  the  United States  during the next 5 years.

      If a new primary copper  smelter processing high-arsenic  feed is
 built,  the  promulgated standard will apply to  that smelter.   However,
 to  estimate the potential  impacts  and benefits  of the standard, it is
 necessary to rely on  reasonable projections  of possible new  construction.
 Since it was EPA's  best  projection that no new  primary  copper smelters
 would be built, EPA's  analysis at  proposal was  based on application of
 controls  to the existing high-and  low-arsenic  domestic  copper
 smelters.

 1-2.4   APPLICABILITY  OF  THE STANDARD

     Comment:   Phelps  Dodge requested confirmation of its interpretation
 of  the  proposed  procedure  for determining the  applicability of the standard
 to  particular low-arsenic  copper smelters.  As  stated in their comments,
 "It is  the  understanding of Phelps Dodge  that no smelter will be required
 to  install  horizontal  air  curtain secondary hoods over copper converters
 so  long  as  the  converter arsenic charging rate  is less than 6.5 kg/h
 averaged  over a  1-year period (§61.172(c)).  This annual arsenic
 charging  rate will  be  determined for each copper converter once per
 month by  computing  the arithmetic average of the 12 converter arsenic
 charging  rate values  for the  preceding 12-month period  (§61.175
 (d)(4)).  Thus, after  these regulations become effective,  no copper
 smelter will have an established  "annual  arsenic charging  rate"  for its

information for  1982 as reported in Table 2-1 of the proposal BID's,
subtracting the capacity figure for ASARCO-Tacoma.

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converters until  1  full year after the  proposed regulations become
effective.   One year after the regulations become effective, some
smelters will undoubtedly be above the  6.5 kg/h standard while others
will  be below that  regulatory limit.  Those smelters
above the regulatory limit will have the  right to apply for a 2-year
waiver from  compliance pursuant to 42 U.S.C. §7412(c)(B)(ii) and 40 CFR
§61.173(a)(l).  See also. 48 FR 33122.   If at any time during the 2-year
waiver period the annual arsenic charging rate falls  below (and stays
below) the regulatory limit, the smelter  will not be  required to install
horizontal air curtain secondary hoods" [footnote omitted] (IV-D-640).

      Response:  The proposed regulation may not have  been clear in
expressing EPA's  intent concerning the  determination  of applicability
of  some provisions  of the standard to primary copper  smelters.  In
proposed §61.172(c), the cutoff converter arsenic charging rate of
6.5  kg/h appeared to apply to each copper converter at a facility.
The  intention, however, was to apply this cutoff figure to the total
arsenic charging  rate for all of the converters at a  smelter (the
"copper converter department").  Since  proposal, the  charging rate
cutoff has been increased from 6.5 to 75  kg/h (§61.172(a) of the final
standard).   To determine this total charging rate, §61.174(f) specifies
that  the individual computed charging rates be added  together monthly
to obtain the rate  for the entire converter department, and a running
annual average will be calculated using the previous  12 monthly values.

      Another area of the proposed standard that may have created
confusion concerned the requirement in  proposed §61.173(a)(1) for owners
and  operators to  install capture equipment no later than 90 days after
the  effective (promulgation) date of the  regulation,  unless a waiver of
compliance was approved by the Administrator.  This requirement reflects
the  intention of Section 112(c)(l)(B)(1) of the Act,  and is retained in
the  final standard.  Confusion may have arisen because of the additional
provision in §61.172(c) [final  §61.172(a)]'for a 1-year period during
which sampling of the converter charge  is conducted to determine an
average arsenic charging rate for comparison to the regulatory cutoff.
This  requirement for sampling, while intended to apply to all primary
copper smelters, is particularly oriented toward those smelters that
past  sampling determinations show to be operating quite near to the
cutoff figure, or whose projections indicate may increase their converter
arsenic charging rate in the future.  Those smelters  whose historical
data  show to be well above or well  below the cutoff,  and which do not
project any significant change in operations in the foreseeable future,
were expected to recognize their possible applicability status at
promulgation without waiting for the results of the one-year sampling
program.   Smelters with high converter arsenic charging rates should
have  prepare.d to initiate compliance measures when the standard was
promulgated in order to achieve compliance within 90  days of the effective
date.  The waiver referred to under §61.175(a)(4)  [final  §61.174(a)(4)]
is intended to apply to facilities  that cannot be brought into compliance
within the initial 90-day period following the effective date.  Owners
and operators of sources covered under the standard, who require more
than 90 days to bring their sources into compliance, should apply for a
waiver of up to 2 years at the  time the standard is promulgated.
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     To summarize, any facility indicated by historical  sampling data
to process arsenic through its converters at rates well  in excess of
the final regulatory cutoff is presumed by the Agency to be subject to
the control  requirements on converter secondary emissions, and is
expected to take steps, beginning on the effective date, to implement
these requirements for its converters.

1-2.5  APPLICABILITY BASED ON CONVERTER CHARGING RATE

     Comment:  ASARCO felt there was no reasonable basis for establishing
a cutoff value for determining the applicability of converter controls
in terms of the converter arsenic charging rate.  Instead of exempting
converters that are charged at less than 6.5 kg/h, as proposed in
§61.172(c), the cutoff should be set at 6.5 kg/h of estimated converter
baseline fugitive emissions.  The proposed cutoff imposes control costs
far beyond those that can be considered reasonable (IV-D-620).

     Response;  As explained in the proposal notice (48 FR 33143), the
Agency considered emission rates, emission reduction potential, control
costs, and the expected economic impacts of controls on individual
smelters in establishing the reasonableness of requiring controls on
converter operations.  These elements in actuality formed the basis for
the division between smelters for which secondary converter controls
were reasonable and those for which they were not.  An objective,
readily determinable parameter was sought to permit the two groups of
low-arsenic smelters, already established using the criteria mentioned
above, to be distinguished from one another.  The parameter of arsenic
charging rate to the converters was selected because it can be computed
readily  from the arsenic concentration in the matte and the total matte
charging rate to the converters, parameters that can be measured directly.
Further, a smelter may be able to use ores with lower arsenic content
to lower its arsenic charging rate.

     Since proposal, EPA has evaluated the health risks presented by
each primary copper smelter in light of the revised arsenic emission
estimates calculated since proposal (see Section 1-4).  Based on this
analysis, EPA revised the cutoff to distinguish between primary copper
smelters where additional emission control is reasonable and those
where additional emission control imposes costs that far exceed any
public health benefit.  The cutoff has been changed from the proposed
converter arsenic charging rate of 6.5 kg/h to a final rate of 75 kg/h
to reflect this policy.

     The EPA considered the commenter's suggestion to change the cutoff
to 6.5 kg/h of estimated converter baseline fugitive emissions.  This
cutoff rate is equivalent to an emission rate of about 56 Mg/yr; since
the highest estimated value in Table  III-l of the preamble to the pro-
mulgated standards is 13.3 Mg/yr, no  smelter would be covered by
converter control requirements under  the suggested approach.  This
result is not consistent with the findings of EPA's health risk analysis
or with  EPA's stated purpose for the  cutoff.  Therefore, EPA did not
incorporate the commenter's suggestion.
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1-2.6  PUBLIC HEARINGS

     Comment:  Several commenters felt that public hearings on the
proposed standards should have been held in areas at risk from copper
smelter arsenic emissions, and particularly in Arizona, where seven of
the smelters are located (IV-D-151, -224, -241, -301, -346, -549, -573,
-608, -795; IV-F-1, IV-F-2, IV-H-4, IV-H-7).

     Response:  Public hearings on the proposed NESHAP were originally
scheduled in the proposal notice to be held on August 23, 24, and 25, 1983
(Washington, D.C.), and August 30, 1983 (Tacoma, Washington), to provide
interested parties the opportunity to comment on the proposal in person
(III-A-1).  At the request of several commenters who needed more time
to prepare for the hearings, the Tacoma hearing was postponed until
November 2, 3, and 4, 1983, and the Washington, D.C., hearing until
November 8, 1983 (IV-I-1).  Limitations of time and resources prevented
the Agency from conducting any additional hearings.

     The public comment period allowed anyone who could not be present
at the hearings an opportunity to comment on an equal basis with the
participants at the hearings.  The comment period, originally scheduled
to end on September 30, 1983, was first extended to December 10 and
then reopened until January 31, 1984  (IV-I-1, IV-I-3).  It was again
reopened on September 20,  1984 (IV-I-4), in order to receive public
comments on EPA's preliminary revisions to the arsenic emission estimates
and control costs presented at proposal.  Written comments submitted
during these  periods  were  given the same level of consideration in
finalizing the regulation  as those presented at the hearings.

1-2.7  REQUESTS FOR TECHNICAL ASSISTANCE

     Comment:  The Natural Resources  Defense Council (NRDC) questioned
the sincerity of the  Agency's commitment to public  involvement in  the
regulatory development  process because  EPA had turned down requests  for
technical assistance  from  both local  and national environmental groups
(IV-F-1,  IV-F-2).

     Response:  This  environmental organization  requested  in a letter
to the Administrator  that  access  to  EPA contractor  time be granted to
assist them  in reviewing  the  background  information pertaining in
particular to the low-arsenic copper  smelters and the  other  industries
considered in the  proposal.   In  the  same letter, a  postponement of the
public hearings was requested  (IV-D-119).

      In  response  to these  requests  (IV-C-48),  EPA re-emphasized  its
commitment to  providing as much  relevant information as  possible  to  the
citizens  who  are  interested  in and  affected by this rulemaking.   However,
the  Agency expressed  its  view that  the  loan of contractor  support  to
any  group or  coalition  of groups  could  potentially  generate  controversy,
since  it  would be  difficult  to assure equal treatment  and  fairness to
the  various  perspectives  of  the  affected parties.   For this  reason,
direct contractual assistance was not provided to any  of the  parties
that  requested  it.  However,  EPA pointed out  that  the  findings of the
consultants  would  be  made available  as  they were  developed.   Further,

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it was noted that the Agency would Investigate questions and issues
raised by NRDC and others, and in this way would address the concerns
expressed by NRDC.  The commenter was referred to the Puget Sound Air
Pollution Control Agency (PSAPCA) as an information source on smelter
control techniques (in particular regarding the ASARCO-Tacoma high-
arsenic smelter), which was available to represent the perspectives and
interests of the citizens of the area.  Finally, several docket materials
were sent to the commenter at its request (IV-C-3).

     As pointed out in Section 1-2.6, the public hearings were resched-
uled and the comment period was extended and reopened to accommodate
the requests of commenters and to allow the maximum possible public
involvement.

1-2.8  OPPORTUNITY FOR COMMENT ON NEW DOCKET ADDITIONS

     Comment:  Kennecott felt that the public should be given an
opportunity to comment on any new information and data added to the
docket between proposal and promulgation of the standard.  The commenter
was concerned that insufficient review time would be available for the
later docket entries, and they referred to previous instances of court
censure when docket items were entered immediately prior to promulgation
(IV-D-634).  ASARCO and Kennecott commented, in response to EPA's
memorandum containing revised arsenic emission and control cost estimates
(IV-B-32), that if risk estimates for copper smelters are revised
between proposal and promulgation they should be presented for public
comment before a final regulation is issued (IV-D-811, IV-D-812).

     Response:  The EPA's regulatory development procedure is to propose
standards after an open development period in which participation by
all interested parties is encouraged.  All information considered in
the development of the standards, up until standards are promulgated,
is placed into the docket as quickly as it can be indexed, copied, and
distributed to the docket locations.  The Agency realizes that occasion-
ally certain items of information are unavoidably added quite close to
the promulgation date.

     In this rulemaking, a particular effort has been made to enter
docket materials as soon as possible after they became available.
While all nonconfidential docket materials are available for public
review, including copying privileges, time constraints generally
do not allow a formal public review and comment period for materials
added to the docket between proposal and promulgation.  (However,
revised emission and cost estimates were placed in the docket for public
review, and announced by a Federal Register notice, after the general
comment period had ended; see Section 1-1.0).   The Agency's risk
estimates were constantly revised and updated during this period as
revisions were made to arsenic emission estimates and other modeling
input parameters.  It was not possible, within the time constraints of
the regulatory development schedule, to allow an additional formal public
review and comment period for these risk estimates.  However, the
revised risk estimates were placed in the docket and also were sent
directly to ASARCO, Kennecott, Phelps Dodge, and NRDC for their review
before the standard was promulgated.

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1-2.9  ENFORCEMENT AND REPORTING OF VIOLATIONS

     Comment:   The Sierra Club, Grand Canyon Chapter, felt that "stiff
penalties" should be assessed for violations of the provisions of the
standards.  Also, violations should be reported by the companies at the
time the violations occur, instead of in the semiannual  reports to the
Agency required under §61.178(b) and (c) (IV-D-608).

     Response:  The Clean Air Act (42 U.S.C. 7411) as amended,
establishes a mechanism for the Agency to determine the compliance.  •
status of an emission source subject to the provisions of Section 112,
and to assess appropriate penalties against an owner or operator whose
source is found to be in violation of this Section's emission standards.

     Under Section 114(a)(l), the Administrator may require an
owner or operator to maintain records of monitoring and sampling,
and to make this and any other pertinent information available to
the Agency as reasonably required to permit a determination of the
compliance status of the source to be made.

     Section 120 requires the Administrator (or the State in cases
where the authority has been delegated) to assess and collect a
noncompliance penalty against owners and operators of stationary
sources that are in violation of the requirements of Section 112.
Section 120(d)(2) sets the amount of the penalty, which must be no
less than the net economic benefit accruing to an owner as a direct
result of his failure to comply with these requirements.  Finally,
Section 120(d)(5) sets a nonpayment penalty for each quarter during
which failure to pay a noncompliance penalty occurs.  The Administrator
is granted the discretion, in Section 120(a)(l)(c), to exempt any
source found to be out of compliance from assessment of penalty if
the violation is determined to be of a minor nature.  The opportunity
for public hearing is a part of this determination process.  The EPA
believes that this regulatory mechanism, which provides EPA the
authority to collect information that will allow compliance
determinations and to impose penalties that destroy the financial
incentive to pollute, is adequate for encouraging sources to comply
with the standard.

     The proposed standard required a semiannual written report to
the Administrator describing any occurrences of excess opacity or
low air flow rates through the air curtain system.  Reporting
requirements, in general , assist the Agency in the enforcement of
emission standards by providing information concerning the operating
level of control equipment.  The EPA considered, the suggestion to require
reports of violations as they occur, and concluded that the benefits of
reporting at this frequency would be outweighed by the burden created
for owners and operators by the increased paperwork.  The reporting
frequency required in the final regulation  (§61.177(c)(3) and (d)(2))
has been increased, however, to quarterly reporting.  The Agency
believes that this represents a reasonable reporting period that will
not create excessive paperwork for smelter owners and operators.
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                  1-3.0  LEGAL AND POLICY ISSUES

1-3.1  REQUIREMENTS OF SECTION 112 OF THE CLEAN AIR ACT

     Comment:   The New York State Department of Law and the State of
New Mexico commented that EPA has violated Section 112 of the Clean Air
Act requirements by not setting emission standards and by failing to
demonstrate that emission standards are infeasible (IV-D-698, IV-D-810).

     Response:  Section 112 of the Clean Air Act states that national
emission standards must, whenever possible, take the format of a
numerical emission limit.  Section 112(e)(2) recognizes that in certain
instances, numerical emission limits are not possible:  (1) when the
pollutants cannot be emitted through a conveyance designed and con-
structed to emit or capture the pollutant, and (2) when the application
of a measurement methodology is not practicable due to technological
limitations.  In such instances, Section 112(e)(l) authorizes design,
equipment, work practice, or operational standards.

     In developing the standard for secondary inorganic arsenic emissions
from converter operations, EPA considered separately the format of
standards for the capture and collection of emissions.  For the collection
of emissions, EPA set a numerical emission limit because it was feasible.
However, EPA determined that a numerical emission limit for the capture
of secondary inorganic arsenic emissions from converter operations is
not feasible because neither the capture efficiency nor the quantity of
emissions that escape capture by secondary control techniques can be
measured accurately by source testing or quantified by visual observation
techniques (e.g., EPA Reference Method 9 or 22).  In this situation,
equipment, work practice, and operational standards are necessary to
assure effective control.  Therefore, the final regulation specifies
these types of formats to effect capture of converter secondary arsenic
emissions.

1-3.2  SELECTION OF BEST EMISSION CONTROLS

     Comment:  The Chemical Manufacturers Association commented that
when EPA selects BAT for a source category, the Agency should consider
only those control technologies that have been adequately demonstrated
on commercial-scale plants of the type that would be subject to the
control requirements.  The commenter argued that when control technologies
have not been demonstrated on the particular type of source in question,
judgments on emission reductions achievable will be speculative and
unreliable (IV-D-617).

     Response:  The policy set forth in  the Federal Register notice of
proposed rulemaking (48  FR 33116) can be paraphrased as follows:   It
is EPA's judgment that the best  interpretation of Section  112 for  non-
threshold  pollutants is  to establish standards that would control  a
source category at least to the  level that  reflects best available
technology (BAT), and to a more  stringent level if it  is necessary  to
prevent  unreasonable risks.   By  BAT, EPA means the best adequately
demonstrated controls available  considering economic,  energy, and
environmental impacts.   Whether  the estimated  risks remaining after

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application of BAT are reasonable is decided in light of the
Administrator's judgmental evaluation of the estimated maximum lifetime
risk and cancer incidences per year remaining after application of BAT;
the impacts, including economic impacts, of further reducing those
risks; the readily available benefits of the substance or activity
producing the risk; and the availability of substitutes and possible
health effects resulting from their use.

     Since proposal, EPA has eliminated the term "BAT" from this rule-
making and redirected certain aspects of its technology selection and
application policies under Section 112.

     The EPA's standard setting policy for carcinogens regulated under
Section 112 of the Clean Air Act provides for consideration of the
risks, costs, and potential benefits of various levels of control.
Under this policy, it is not necessary that control technology be fully
demonstrated in order to serve as the basis for the standard.  However,
the extent to which a technology has been demonstrated and any uncer-
tainty as to whether it could be effectively applied to a prospective
source category are considered.  In practice, EPA would consider control
technology to be demonstrated if it could be shown to be demonstrated
for a similar source category, but not necessarily for the source
category being regulated.  This means that a system used in an entirely
different industry using a different process from the one being regulated
could be considered best emission control if its performance were
judged to be unaffected by the differences in the processes.  Similarly,
a system used in some segments of the industry being regulated, or in
some parts of the process, but not in others, can be considered best
control for all segments or all parts of the process if investigation
of the relevant variables reveals no reason that it could not be designed,
installed, and operated so that it achieved the same emission control
under all the conditions in which it would be applied.

     In the case of primary copper smelters, the standard requires the
use of emission capture and control equipment that has been used in the
affected industry.  Hence, the commenter's concerns are not pertinent
to this standard.

1-3.3  RELIANCE ON OTHER STANDARDS TO ACHIEVE CONTROL

     Comment;  The NRDC and the States of New York and New Mexico felt
that it was inadequate for EPA to rely on control measures currently in
place, or scheduled to become effective pursuant to SIP's, judicial
consent decrees, or OSHA standards, as a substitute for Section 112
standards.  In the preamble to the proposed standard for primary
copper smelters, EPA concluded that various existing or planned control
measures at several smelters constituted best emission control on
inorganic arsenic emissions.  In these instances, the Agency concluded
that further control measures under Section 112 were not necessary.

     The commenters believe that the requirements of SIP's and consent
decrees do not satisfy the mandate of Section 112 for several reasons.
These other requirements are written in response to Section 110, which
imposes different responsibilities on the Agency than Section 112.

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These standards are oriented toward participate matter and S02 (not
arsenic), they impose selective controls that may be relaxed in response
to improving air quality, and they often suffer from uncertainty about
future compliance.

     OSHA standards take the form of an indoor worker exposure limit,
and so captured emissions are often vented directly to the atmosphere.
These standards also undergo long delays before they are implemented,
may be changed without reference to Section 112, and contain no provi-
sions for citizen suit enforcement.

     In cases where EPA has validly determined that these other types
of requirements are appropriate for the purposes of Section 112, the
commenters felt they should be published and adopted as a Section 112
standard by reference (IV-D-698, IV-D-710, IV-D-810).

     Response: The Agency believes that where standards established
under other authorities are effective in reducing emissions, redundant
standards need not be established by EPA.  The EPA establishes separate
standards when the evidence indicates either that the existing control
measures are unlikely to remain in operation or that they will not be
properly operated and maintained.  The existing controls that EPA
determined to represent best control at several primary copper smelters
are likely to remain in place and be properly operated and maintained
under the regulatory authorities that required those controls.

     The existing process controls at primary copper smelters were
installed primarily in response to SIP's or the judicial consent decrees
worked out with smelters that had been found to be in violation of some
of the requirements of SIP's.  Although intended to reduce emissions of
particulate matter and S02, these controls should also achieve effective
control of arsenic emissions at some smelters.  The efficiency of arsenic
collection depends on the physical conditions (primarily temperature)
affecting gases entering collection equipment and the concentration of
inorganic arsenic in the gas stream.  While the lowest practicable
temperatures will permit the best arsenic collection, the minimum safe
operating temperature is determined by the potential for corrosion
problems caused by acid formation.  Each smelter with existing particu-
late collection equipment was evaluated with respect to the potential
to increase the collection of inorganic arsenic by lowering gas stream
temperatures.  The EPA concluded at proposal that at most smelters no
appreciable additional arsenic collection through this measure was
likely, and so the existing controls were considered to represent the
best emission control.  Following proposal, EPA reexamined the
emission reduction achievable by gas cooling to determine any need for
controls beyond those required by existing standards.  Specifically,
EPA reassessed the potential emission eduction achievable for those
smelters where gas cooling was evaluated as a control option and for
Phelps Dodge-Ajo.  Process emission controls at Phelps Dodge-Ajo were
examined because at proposal the company was negotiating changes to its
consent decree to eliminate the need for oxy-sprinkle smelting and acid
plant controls.  Phelps Dodge has made the decision since proposal to
continue its use of reverberatory furnace smelting at the Ajo smelter.
As a result of this decision, EPA has reevaluated its analysis of the

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need for process  controls at  this  smelter, based on the expected
emission reduction and  the costs of controls.  These reassessments
showed additional process controls would only achieve very small
reductions in risk and would  impose significant costs.  Therefore,
process controls  should not be included in this standard.  This issue
is discussed further in Sections 1-6.1.4, 1-6.2, and 1-8.1.3.2 of this
document.

     It is EPA's  policy not to set redundant regulations where EPA
believes that regulatory duplication would not lead to enhanced
collection of a pollutant beyond the level of existing controls, or
where it would not serve to further ensure that these existing controls
would remain in place or be properly operated and maintained.  NESHAP
regulations are reviewed periodically as new information is obtained
that may affect the stringency or applicability of the standards.   At
the time of review, the standard will be revised if necessary to provide
the appropriate regulatory coverage.  These reviews provide a means of
ensuring that the current controls at a source (regardless of their
regulatory origin) are continuing to perform at the level that satisfies
the requirements  of Section 112.

1-3.4  STARTUPS,  SHUTDOWNS, AND MALFUNCTIONS

     Comment:  A  few commenters felt that the proposed standard
attempted to circumvent Section 112 of the Act; the regulation should
not exempt emissions during startup, shutdown, and malfunctions from
the control requirements.  They further believed that the regulation
should encourage  compliance,  and not provide a means and incentive for
circumvention (IV-D-609, IV-F-4, IV-F-5).

     Response:   The regulation has been revised as it applies to
emissions during  startups,  shutdowns, and malfunctions.   The regulation
includes maintenance requirements,  and requirements for a plan for
curtailment during malfunctions and timely repair of malfunctioning
process and pollution control  equipment.   The regulation also now
explicitly requires that emissions of inorganic arsenic be minimized at
all times.
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                  1-4.0  ARSENIC  EMISSION ESTIMATES

      Three copper companies, ASARCO,  Kennecott, and Phelps Dodge,
  submitted comments  pertaining to EPA's estimates at proposal of the
  baseline arsenic emission rates (i.e., emission rates in the absence
  of  NESHAP controls) at several  of their smelters.  The commenters
  felt in each case that EPA had  overestimated these emissions, and
  hence  overestimated the  risk posed to the  public health in the
  vicinity of these smelters.

      In response to these comments, the Agency revised many of its
  emission estimates  and ran the  Human  Exposure Model (HEM) using the
  new data inputs  to  produce revised estimates of the potential public
  exposure and health risks from  these  smelters.  These copper companies
  again  commented when the revised emission  estimates were placed into
  the docket for public comment (see Section  1-1.0).  (These later comments
  from ASARCO, Kennecott,  Phelps  Dodge  and the State of New Mexico have
  been assigned item  Nos.  IV-D-811, IV-D-812,  IV-D-813, and IV-D-814,
  respectively, in docket  No. A-80-40).  Most of these comments reiterated
  the concerns expressed at proposal, especially in cases where the
  Agency had disagreed with some  of the assertions made by these companies.
  The responses in this section address principally the original comments
  made just after  proposal, with  reference made as necessary to the later
.  group  of comments.  The  smelter arsenic mass balances in Appendix F of
  the proposal BID have also been updated, and these are presented in
  Appendix B of this  document.  Appendix C contains an updated version
  of  the proposal  BID'S Table E-2, showing the plant data inputs to HEM.
  This appendix also  discusses other details  of the modeling efforts
  undertaken since proposal.

  1-4.1   ASARCO,  INCORPORATED, SMELTERS

  1-4.1.1  Hayden  Smelter

      Comment;   ASARCO commented that  the baseline converter  fugitive
  arsenic emissions at its Hayden smelter would, in the modernized smelter,
  be  much lower than  EPA's estimate of  3.4 kg/h (7.5 Ib/h).  At the time
  of  proposal, ASARCO was  starting up a new  INCO flash smelting furnace
  at  the Hayden plant.  ASARCO claimed  in its  comments that the new
  arsenic distribution at  the modernized smelter would lead to a much
  lower  fugitive  emission  rate of arsenic from converter operations than
  EPA had estimated at proposal.

      Since  INCO  tests and estimates show that a  higher percentage
  of  the arsenic  entering  this furnace  in the  charge will be volatilized
  (78 percent versus  EPA's estimate of  49 percent), and thus will not
  enter  the converters in  the matte, a  smaller quantity, 32 kg/h
  (70 Ib/h), will  be  given off  in the converter offgases than  EPA's
  estimate of 45  kg/h (99  Ib/h).

      The emission  factor of  15  percent of  the arsenic contained  in
  the primary offgas  stream,  which  EPA  used  to estimate  potential  (uncon-
  trolled) converter  fugitive  emissions, was claimed to  be  too high under
  the new INCO  furnace configuration.   The sampling conducted  for  EPA  in

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 January 1983, on  the prototype air curtain secondary hood installed on
 the No. 4 converter at ASARCO-Tacoma showed that a 2 percent emission
 factor may be more appropriate for a converter equipped with a high-draft
 primary hood.  Since the primary hoods at the Hayden smelter also will
 be operated under a high draft (potentially even higher than at Tacoma),
 the same fugitive emission factor of 2 percent should be applied at
 Hayden in order to calculate potential converter fugitive emissions.
 ASARCO felt that even the 2 percent factor would be conservative because
 of the Hayden hoods  higher draft and the likelihood of fewer converter
 cycles at Hayden than at Tacoma,  decreasing the chance for the escape
 of fugitive emissions.   In its recent comments on EPA's response memo-
 randum, the company claimed that the Agency's rationale presented in
 the memo for maintaining the 3.75 percent primary hood emission factor
 had relied on the presence of secondary hoods as a determining influence
 in its estimation of this factor.  ASARCO felt that the existence or
 type of secondary hoods is not relevant for estimating potential  fugitive
 emissions from converters.  The company applied its estimated emission
 factor of 2 percent to  the 32 kg/h (70 Ib/h)  figure cited above,  producing
 a potential  fugitive arsenic emission rate estimate of 0.6 kg/h (1.4 Ib/h)
 for the converter operations at its Hayden smelter.

      Finally,  ASARCO claimed that the capture  efficiency of  the existing
 secondary hoods  at the  modernized smelter is  actually 75 to  80 percent
 rather than  the  50 percent estimated  by EPA.   The company,  in its
 comment on EPA's August 1984 memo,  provided records of the sulfur
 balance at the smelter  both before and after modernization.   These
 records indicated that  the sulfur lost (presumably in the  form of
 fugitive emissions)  in  1981-82  when the roasters  and  reverberatory
 furnace were  still  in operation averaged  about 4.5 percent of the total
 input sulfur.  By contrast,  records for 1984 with the oxygen  flash
 furnace in operation show  that  only about 0.02 percent  of  sulfur  intake
 is  now lost,  indicating a  marked  improvement in  fugitive emission
 control  since  EPA s  observations  of the smelter  operation  in  1981.
 ASARCO applied its estimate  of  75 percent capture to  the potential
 fugitive emission  rate of  0.6 kg/h  (1.4 Ib/h)  to  calculate a  converter
 baseline  fugitive emission  estimate of  0.16 kg/h  (0.35  Ib/h).   The
 company  felt that this converter  fugitive emission  level should cause
 the  smelter to be  considered to already  have best emission controls
 installed  (IV-D-620, IV-D-811,  IV-F-1,  IV-F-2).
                                            i
     Response:  The EPA's  reanalysis of the ASARCO-Hayden smelter's
 inorganic arsenic distribution  and new estimates  of converter fugitive
 emissions have resulted in several changes to  the estimates made  by
 the Agency at proposal.

     The Agency's estimate at proposal of 49 percent arsenic volatili-
   ™!? !rom JheTINCO flash furnace was based on an estimate submitted
 to EPA for the INCO furnace planned for the Kennecott-Hurley smelter
 * rSrJ?A;uth? Same value of 49 Percent was applied to the INCO furnace
at ASARCO-Hayden in order to generate a complete arsenic distribution
for the smelter.   This was done because no estimate had been received
from ASARCO.   However,  since ASARCO now claims that a value of 78 percent
volatilization is more appropriate, and this value falls within the
range of data reported in the literature and presented in Table 2-7 of

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Tow-arsenic BID, Volume I, the 78 percent value was used in developing
a revised arsenic balance for the Hayden smelter.  (The higher volatil-
ization rate was accepted because the arsenic content of feedstocks used
at ASARCO-Hayden is more than 1,000 times greater than that of Kennecott-
Hurley and because tests indicate that a higher percentage of arsenic
is generally volatilized in a smelting furnace from higher arsenic
feed materials.)  Values of 8 and 14 percent were used for estimating
the quantities of arsenic from the furnace charge reporting in the slag
and the matte, respectively.  The rate of arsenic volatilization in the
converters was assumed as before to be 50 percent, resulting in an
estimated rate of 32 kg/h (70.2 Ib/h) of arsenic given off in the
converter offgases.

     The EPA's emission factor of 15 percent of the arsenic contained in
the converter primary offgases, used at proposal for estimating potential
converter fugitive emissions, was based on test data collected at the
ASARCO-E1 Paso smelter (page 2-53 of low-arsenic BID, Volume I).
This emission factor is appropriate for converting operations that
utilize converter primary hoods drawing a relatively low draft.  This
is the case at most domestic copper smelters, where low-draft operation
minimizes dilution of S02 concentration in the flue gases being ducted
to acid plants, and hence optimizes acid plant operation.  ASARCO has
claimed that under the new INCO furnace configuration, the furnace
offgas containing 80 percent S02 will be blended with converter offgases
before being sent to an ESP and two acid plants.  These acid plants are
designed to operate at S0£ concentrations of 6.5 and 12 percent.
Therefore, a large quantity of dilution air will be required, and a
portion of this dilution air will be supplied by means of an increased
draft on the converter primary hoods.  As a result, fugitive emissions
should be lower.

     The EPA agrees with ASARCO that converter primary hoods should
capture process emissions more efficiently under high-draft operation
than under lower draft conditions.  Furthermore, the emission factor of
15 percent selected by the Agency at proposal did not take high-draft
operation at ASARCO-Hayden into account.  Therefore, EPA revised the
emission estimate to reflect the expected capture efficiency of high-
draft primary hoods.  Observation and measurement of emissions from
primary hoods at ASARCO-Tacoma show that secondary converter emissions
vary with the hood-converter configuration and the draft.  Fugitive
emission factors for converters at ASARCO-Tacoma are 3.75 percent for
primary hoods in converters Nos. 1 and 2 and 2 percent for converter
No. 4 at Tacoma (IV-B-10, IV-B-30).  The 2 percent emission factor
measured for the Tacoma smelter's No. 4 converter represents the best
operation EPA has observed with regard to primary hood emission
capture.  The EPA has not been made aware of any data collected from
the ASARCO-Hayden operations to establish, the actual emission factor,
and ASARCO has not supplied any such information with its comments.
Therefore, the Agency believes that, when no actual measurements are
available, it is prudent to select an emission factor representative of
high-draft operation, as determined for converter Nos. 1 and 2 at
Tacoma, but not as low as the factor measured for the best system.  For
this reason, a selected emission factor of 3.75 percent has been used
to estimate potential fugitive arsenic emissions from the converters at

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ASARCO-Hayden.   (Note:  The company pointed out some errors of statement
in EPA's memorandum response.  This response had referred to the measured
2 percent emission factor at ASARCO-Tacoma as relating to secondary
hood capture and had termed it an "air curtain factor."  These were
errors of statement drafted into the technical memo, and EPA believes
that when the terminology is corrected to refer to primary hood emission
factors, the logic of its rationale is sound.  The EPA did not intend
in its memo response to imply the existence of any connection between
the presence or  type of secondary hoods and the primary hood capture
efficiency.)

     To support  its estimate of 75 to 80 percent capture efficiency for
the secondary hoods, ASARCO provided a summary of sulfur recovery data
for 10 months in 1981 and 1982 before the smelter was modernized, and
for 8 months in  1984 after modernization was completed.  Inspection of
these data shows that three of the pre-modernization months actually
showed gains in sulfur recovered versus sulfur input in the copper
concentrate (2.0, 3.0, and 7.7 percent).  Also, while the amount of
sulfur lost' for the entire period totalled 4.5 percent, the loss for
individual months ranged from 2.4 to 12.5 percent.  Data for four of
the post-modernization months indicated that recovered sulfur was
greater than input sulfur by 1.2, 3.7, 3.8, and 9.4 percent, while
the losses calculated for the remaining months ranged from 0.5 to
7.9 percent.  These figures show that this method of sulfur accounting
is insufficiently precise to permit any definite conclusions about
fugitive emission control.  Analysis of the data shows that there is no
discernible difference between the mean sulfur recovery values at the
95 percent confidence level (IV-B-36).  Therefore, the submitted data
do not demonstrate that hood capture efficiency was improved during
the smelter modernization.  Furthermore, EPA believes that to develop
revised estimates of hood capture efficiency would require inspection
of the facility and additional information.  Because further reductions
in emission estimates are not likely to affect decisions regarding the
standard, EPA concluded this effort would not be a productive use of
resources and the capture efficiency should not be revised from 50 to
75 or 80 percent.

     The revised volatilization rate of arsenic from the furnace and
the fugitive emission factor for the converters at Hayden discussed
above have been used in calculating estimated inorganic arsenic
emissions from the ASARCO-Hayden smelter.  The revised arsenic distri-
bution (Figure B-2) is presented in Appendix B, and the corresponding
arsenic emission input data for the exposure model  are contained in
Appendix C.  The EPA's estimate of baseline converter fugitive emissions
is now  0.6 kg/h (1.3 Ib/h), which is 17 percent of the proposal  estimate,
and about four times the estimate submitted by ASARCO in its comments.

     Using the above estimates of the capture efficiency of the existing
control system, EPA has determined that further control  of converter
fugitive emissions can be achieved only at a cost that is greatly
disproportionate to the risk reduction achieved.   Therefore, the standard
does not require control of converter fugitive emissions at this smelter,
as it is currently being operated.   Further reductions of the arsenic
emission rate also would not affect the applicability of the standard.
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1-4.1.2  El  Paso Smelter

     Comment:  ASARCO claimed that EPA had overestimated at proposal
the baseline converter fugitive emissions at its El  Paso smelter.
The smelter's converter building evacuation system was credited by
EPA with 75  percent capture efficiency, which is significantly
lower than the potential capture of this type of system.  Emergency
roof ventilators, and a large access door left open to help alleviate
heat and dust accumulation had contributed to this low estimated
efficiency.   However, ASARCO related in its comments that changes  to
the system had been made recently, including the sealing of the roof
ventilators  and the closing of the access door.  The capture efficiency
was now judged by ASARCO to be about 90 percent (IV-D-620, IV-F-1,
IV-F-2).  The State of New Mexico, commenting on EPA's revised arsenic
emission estimates, felt that the recent improvements made to the
building evacuation system at ASARCO-E1 Paso should be detailed and
made mandatory in the NESHAP.  This would ensure that the system
continued to be operated properly and that the 90 percent capture
efficiency was maintained (IV-D-814).

     ASARCO also referred to another improvement at the smelter, the
installation of a new computerized gas management system in the primary
converter hood flue.  The company thought that, because of this system,
EPA should lower its proposal estimate of potential  (uncontrolled)
converter fugitive emissions by decreasing its selected emission factor
of 15 percent.  ASARCO did not, however, provide an alternate estimate
(IV-D-620, IV-F-1, IV-F-2).  In its comments on EPA's response memorandum,
ASARCO took issue with EPA's decision to consider two values for the
primary hood emission factor as likely upper and lower limits of the
actual value.  The company felt that the lower value of 3.75 percent
should be used in EPA's analysis of converter fugitive emissions at the
El Paso smelter (IV-D-811).  The State of New Mexico felt that, since
improved primary hood performance had not been demonstrated at ASARCO-
El Paso following the installation of the computerized gas management
system, EPA should not allow credit for improved capture and should
continue to use the emission factor of 15 percent until the improvement
can be verified '(IV-D-814).

      Response:  The converter building evacuation system at the ASARCO-
El Paso smelter was estimated by EPA at proposal to be approximately   -
75 percent efficient due to the extra building openings that were allowing
fugitive emissions to escape capture.

     The EPA requested clarifying information about the current situation
at the El Paso smelter in a request sent to ASARCO after proposal
(IV-C-418).   In its response (IV-D-789), ASARCO related that in the
past year it had made several changes within the converter building
to reduce employee exposure and minimize fugitive emissions.  These
changes had  included repairing loose siding on the building wall,
closing a crane access door, and expanding the smelter's computerized
environmental monitoring system to manage process gas  flows.  Although
ASARCO stated that heat levels in the building are still excessively
high, it is  likely that the building evacuation system  is now operating
at a level much nearer to its potential capture efficiency than before.
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The EPA also sent contractor representatives to conduct a site visit
to observe performance of the building evacuation system.  During the
site visit, the operation of the computerized gas management system
was discussed and visible emissions observations were made within and
without the building.  The visible emissions observations and evaluation
of the repaired building evacuation system showed that a capture
efficiency of about 90 percent is being achieved.  Thus, for the purposes
of reanalysis of arsenic emissions from this smelter, EPA now is assuming
a capture efficiency of 90 percent for this system.  (Section 1-6.5
contains a further discussion of the building evacuation system.)

     ASARCO described its computerized gas management system for the
copper converters as having three separate functions: tuyere air control,
converter hood pressure control, and handling of offgas (damper control).
These functions work together to control and smooth out pressure and
flow surges inside the converters, in the converter hoods, and in the
exhaust gas handling system between the hoods and the ESP.  The system
senses converter position and gas pressures in various parts of the
gas handling system and adjusts tuyere blowing rates and damper positions
to optimize capture of converter offgases by the converter hoods.
ASARCO believes that the reduced frequency of positive pressures and
the stabilized gas flowrate demonstrate that the computerized gas
management system has reduced fugitive and process emissions.  The EPA
has considered the operation of the El Paso smelter's gas management
system in its reassessment of potential converter fugitive emissions.
Although the capture efficiency of the converter hoods has not been
measured since the system was upgraded, EPA believes that it is likely
to be higher than the efficiency of a similar low-draft primary hood
system without computerized control , and may in fact be similar to a
high-draft system such as the system at ASARCO's Hayden smelter.
However, ASARCO did not provide any test measurements verifying its
claim of a lower potential  fugitive emission factor.  Therefore, the
Agency feels that at this time it cannot select an appropriate factor,
and is retaining the upper and lower limit values of 15 and 3.75 percent
presented in the response memorandum.  The latter value was selected to
correspond to the emission factor applied to the ASARCO-Hayden smelter,
where the primary hoods are operated under a high draft.

     As a result of these considerations, EPA has reviewed its proposal
estimate of 3.2 kg/h (7.0 Ib/h) or 27.5 Mg/yr (130.3 tons/yr)
for baseline converter secondary arsenic emissions at ASARCO-E1  Paso.
This estimate is now expressed as a range, to account for the two
values for primary hood capture efficiency under consideration by the
Agency.  The highest level  of secondary emissions (1.5 kg/h [(3.4 Ib/h]
or 13.3 Mg/yr [14.7 tons/yr]) occurs under the assumed primary hood
fugitive emission factor of 15 percent (85 percent capture efficiency).
If the lower emission factor of 3.75 percent (96.25 percent capture
efficiency) is assumed to apply, the calculated converter secondary
emissions are reduced to 0.4 kg/h (0.9 Ib/h) or 3.4 Mg/yr (3.7 tons/yr).

     The EPA used these emission rate estimates to assess the range
of possible impacts and cost effectiveness of the standard, because
more definitive values based on testing or Agency observations are not
presently available.  These analyses demonstrated that the precise level
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of emission reduction achieved due to operation of this automatic gas
management system would not affect the Agency's decision to require
control of converter fugitive emissions at ASARCO-E1 Paso.

     In response to Mew Mexico's comment about the configuration of the
building evacuation system, EPA reviewed its analysis of the operations
within and the emissions from the converter building at the ASARCO-
El Paso smelter to ensure that the Agency's analyses and decisions were
based on the best information available.  This reassessment included:
(1) an on-site inspection of the converter building ventilation
system, and (2) discussions with ASARCO regarding anticipated future
operation of the system after installation of the converter secondary
hoods and the impact of the computerized gas management system on
fugitive emissions.  The on-site inspection, made in January 1985,
showed that the converter building evacuation system is achieving about
90 percent capture efficiency; EPA believes that if the existing total
flow rate from the converter building is maintained after installation
of the converter secondary hoods, the capture efficiency of the building
evacuation system should not be diminished.  The EPA also recognizes
that the converter secondary hoods could, by altering the dispersion of
emissions and gas flow within the building, affect the performance of
the building evacuation system.  Since the design of the ventilation
system incorporating the converter secondary hoods has not yet been
established, EPA cannot determine what the effects on building flows
will be and whether it is necessary to require maintenance of 90 percent
capture efficiency in the converter building.  The Agency also cannot
determine whether it is necessary or reasonable to maintain 90 percent
capture efficiency in light of uncertainties about the emission factor
for the anode furnace and the converter fugitive emission factor, and
their effect on estimates of fugitive emissions from the building.  To
determine the necessary level of control, it would be necessary to
monitor emissions, air flows, and system changes after installation of
the converter secondary hoods.

     From discussions with ASARCO and review of applicable State (Texas)
requirements, EPA concluded that ASARCO will continue to maintain the
converter building in its present condition if this can be done without
increasing worker exposures and creating unacceptably high temperatures
in the work area (IV-E-79, IV-E-80, IV-E-82).  While it appears likely
that ASARCO will maintain a relatively closed building, neither EPA nor
ASARCO can determine with certainty whether this will be technically
feasible.  Therefore, the standard does not include provisions requiring
maintenance of 90 percent capture efficiency in the converter building
or maintenance of the measures that have been taken by ASARCO to seal
the building.  The standard does, however, require ASARCO or the owner
or operator of any other facility that might be required to install
converter secondary hoods to report any significant changes in the
operation of the emission control system capturing and controlling
emissions from converter operations.   Examples of changes that must be
reported are reductions in air flow through the capture system of more
than 20 percent and an increase in the area of the converter building
that is open to the atmosphere.  Since changes could affect the capture
efficiency achieved by the secondary hoods and the building evacuation
system, EPA will evaluate all such changes.
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 1-4.2   KENNECOTT  SMELTERS

 1-4.2.1  Utah  Smelter

     Comment:   Kennecott supplied a revised arsenic material balance
 for its Utah smelter which it claimed reflected small changes in
 process operations and more accurate assays than had been performed
 previously.  (Kennecott's smelter near Garfield, Utah, was referred to
 as Kennecott-Garfield by EPA at the time of proposal.)  For example,
 the total smelter arsenic input increased to 122 kg/h (269 Ib/h) from
 EPA's proposal  estimate of 115 kg/h (253 Ib/h), as a result of more
 accurate assays on precipitates and residues.  Arsenic input to the
 converters decreased from 19.2 to 14.8 kg/h (42.4 to 32.5 Ib/h) because
 Kennecott now  uses barren flux (flux with essentially no arsenic content)
 in the converters.

     According  to Kennecott, the Noranda flash smelting reactors at
 the Utah smelter  produce a higher grade matte (higher copper content)
 than typically  produced by reverberatory furnaces (70 percent versus
 under 45 percent).  Sinpe arsenic is soluble in copper, a higher
 percentage of  the arsenic in the matte is retained in the blister
 copper produced from the matte, and therefore the amount of arsenic
 volatilized in  the converter is lower.  Kennecott claimed that EPA's
 estimate at proposal of 32 percent volatilized in the converter offgases
 (low-arsenic proposal BID, page F-12) is too high; the figure is
 actually closer to 10 percent.  Kennecott also submitted a revised
 arsenic mass balance for the Utah smelter that shows 1.2 kg/h (2.6 Ib/h)
 of arsenic eliminated in the converter offgases, in contrast to EPA's
 estimate at proposal of 6.2 kg/h (13.7 Ib/h).  The company further
 stated that in-house testing showed the capture efficiency of the
 existing converter fugitive ventilation system to be greater than
 90 percent, indicating that EPA's proposal  estimate of 50 percent was
 too low (IV-D-634).  In later comments on the revised emission estimates
 in EPA's response memorandum (IV-B-32), Kennecott submitted additional
 arguments and  information to demonstrate that these converter secondary
 hoods are achieving a 90 percent capture efficiency (IV-D-812).

     Kennecott estimated baseline arsenic fugitive emissions from
 the roof vents in the smelter building using S02 emissions measurements
 and assuming that the ratio of arsenic to S02 at the roof vents would be
 the same as that measured in the stack gas.   Escaped fugitive arsenic
 emissions were estimated to be 0.06 kg/h (0.13 Ib/h), in contrast to
 EPA's estimate at proposal  of 0.9 kg/h (2.0 Ib/h) (IV-D-634).

     Response:  The arsenic mass balance information used by EPA at
 proposal for developing the arsenic mass balance for the Kennecott-
 Utah smelter was obtained directly from Kennecott in May 1978, and
March 1983 (Section F.5 of BID, Volume I).   The basic changes to this
 balance suggested by Kennecott since proposal  have been accepted by EPA
and incorporated into a revised arsenic balance (see Appendix B).

     After reviewing Kennecott's comments on the proposed standard,
EPA requested that the company supply additional  information (IV-C-416)
to clarify and support their claims, and to  resolve apparent inconsistencies
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with the information previously supplied to the Agency.  Kennecott's
response (IV-D-788) included a technical memorandum addressing the
issue of arsenic volatilization during copper converting at the Utah
smelter.  Several aspects of the converting operation that contribute
to the low arsenic content of the converter offgases were cited.  Among
these is the routine use of oxygen enrichment of the blast air combined
with maximum additions of reverts and copper scrap early in the blowing
phase.  This results in lower average converter operating temperatures
(approximately 1,150°C [2,100°F]), which was claimed to result in lower
arsenic volatilization rates.  In addition, processing higher grade
mattes and mattes with a lower arsenic content (such as those at the
Utah smelter) was said to result in a decreasing rate of arsenic volatil-
ization in converters.  Since EPA found these arguments to be reasonable,
EPA's revised arsenic balance incorporates these comments and shows an
arsenic volatilization rate of 1.2 kg/h (2.6 Ib/h), which represents
only 8 percent of the total arsenic charged to the converters.

     Kennecott's estimate of 0.06 kg/h (0.13 Ib/h) of arsenic fugitive
emissions escaping through the converter building roof vents is not based
on actual arsenic measurements at those vents.  Rather, it is based on
measurements of the vent gas S02, main stack SOg, and main stack.arsenic
content, and the assumption that the roof vent gas arsenic-to-S02
ratio would approximate that for the main stack gas.  Given values for
the measured data, an estimate of the roof vent arsenic emission rate
can then be calculated.  In response to EPA's request after proposal
for clarifying information, Kennecott stated that the stack value for
SOg used in its calculations (8196 kg/h [18,052 Ib/h]) was the annual
average measured value for 1981, stack arsenic was a value from
measurements made in 1982 (1.8 kg/h [4 Ib/h]), and roof vent SOg was
measured in an October 1981, test program (269 kg/h [593 Ib/h)].  The
EPA believes there is no direct evidence to support Kennecott's
assumption that the arsenic-to-SOg ratios in the stack and the
roof vent gas are approximately equal and, in the absence of measure-
ments of vent gas arsenic content, the Agency cannot accept Kennecott's
estimate of 0.06 kg/h (0.13 Ib/h) resulting from this assumption.
Also, this method assumes that all emissions escaping capture by the
primary hood system are either captured by the secondary hoods or
escape out the roof vents.  As stated in the response memorandum,  EPA
believes that a more valid comparison of arsenic-to-S02 ratios
would be between two similar untreated gas streams, such as the roof
vent gas stream and the converter primary hood system offgas stream.
Kennecott's alternate method of estimating fugitive emissions and
secondary hood capture efficiency, submitted with its comments on EPA's
revised estimates, does employ such a comparison, but this alternate
method also does not provide an accurate assessment of hood capture
efficiency.

     While Kennecott's alternate approach to estimating fugitive
emissions escaping from the converter building compares two gas streams
that are more similar than those compared in the company's first
approach, the latter approach assumes again that all of the arsenic not
measured in the roof vents has been captured by the secondary hoods.
This analysis, however, fails to account for all of the likely routes
                                 1-4-9

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of  escape  in  the  building  for converter  arsenic fugitive emissions.
Specifically,  there  is  an  open roof monitor over the  hot metal side of
the building  through which  emissions can escape, as well as crane doors,
windows, and  other smaller  openings.  These additional emission routes
introduce  sufficient uncertainty  into this estimating approach to cause
the Agency to  conclude  that the approach is not sufficiently reliable for
estimating hood capture efficiency.  It  should be noted that if the
emission estimate had been  revised as suggested by Kennecott, there
would have been only a  negligible impact on the estimated risk calculated
for the smelter.  Also, a lowering of the arsenic emission estimates
for Kennecott-Utah would not impact the  regulatory decisions for this
smelter.

     The EPA's estimate at  proposal of the capture efficiency of the
existing converter fugitive ventilation  system was 50 percent.  Kennecott1
estimate of 90 percent  capture efficiency submitted to EPA after proposal
was based  on measurements made in October 1981 of the S02 discharged to
the atmosphere from the smelter building roof vents, and a sulfur balance-
for the converters.  The hourly amount of S02 produced in the converters
was calculated using the amount of matte processed by the converters
(26,400 Mg [29,100 tons]) and its average sulfur content (21.2 percent)
for the month of October 1981.  Assuming that all of the sulfur in the
matte was  oxidized to S02,  and knowing that each mole of sulfur produces
one mole of S02, the production rate of S02 was calculated to be
15,060 kg/h (33,166 Ib/h).  This calculated S02 production and the
measured S0£ emissions  from the converter aisle roof vent fans (210 kg/h
[462 Ib/h]) were used to calculate an estimate for the capture efficiency
of  the converter fugitive ventilation system.  The EPA believes that
this indirect  form of calculation is not sufficient for deriving an
estimate of the capture efficiency of the converter fugitive ventilation
system, and questions whether measurements of S02 can reliably be
substituted for inorganic arsenic measurements because of the potentially
different  behavior of these two substances.  Also, as mentioned in the
previous paragraph, there are other emission routes for S02 in this
building than the roof  vents at which the measurements were taken.
Therefore,  EPA does not feel that all of the secondary S02 unaccounted
for at the  roof vents is captured by the converter secondary hoods, and
believes that the apparent  capture efficiency indicated by this method
is  considerably higher  than the true efficiency.   In addition to these
considerations, observations made on a visit by EPA and contractor
personnel   to the Kennecott-Utah smelter in November 1983, suggested
that a substantially lower  capture efficiency was achieved (IV-B-26).
As  a result, EPA retained its 50 percent estimate of capture efficiency
in  the reanalysis of fugitive emissions from the Kennecott-Utah
smelter.

     The EPA's revised  value for baseline converter fugitive emissions is
0.18 kg/h  (0.39 Ib/h), or 19 percent of its previous estimate at proposal.

1-4.2.2  Hayden Smelter

     Comment:  Kennecott submitted a figure depicting the overall
arsenic material  balance for its Hayden smelter that is similar to
the overall arsenic balance EPA utilized at proposal  (Figure F-6 in
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 low-arsenic proposal BID), except for the estimate of main stack
 emissions.   Whereas EPA's figure showed 3.2 kg/h (7.0 Ib/h)  of arsenic
 exiting through the main stack, Kennecott indicated that this emission
 value should have been only 0.24 kg/h (0.53 Ib/h).   Kennecott repeated
 its objection in comments the company submitted on EPA's response memoran-
 dum (IV-B-32),  but no specific objections to any of EPA's other values
 or assumptions  were stated.   While basically agreeing with EPA's estimate
 of total  fugitive emissions (0.9 kg/h [2.0 Ib/h])  for lack of any more
 detailed information, Kennecott asserted that improvements made to the
 smelter since it shut down in May 1982, would bring about a  substantial
 reduction in fugitive emissions.  In its later set of comments, Kennecott
 supplied a  list of specific improvements to fugitive emission controls,
 and estimated that the improvements would reduce fugitive emissions
 from the Hayden smelter by approximately 50 percent (IV-D-634,  IV-D-812).

      Response:   The arsenic mass balance figure for the Hayden  smelter
 was developed by EPA using data received from Kennecott concerning the
 arsenic feed rate to the smelter,  as well  as several  assumptions about
 the further distribution of arsenic out of roasters,  furnace,  and con-
 verters.  These assumptions  included respective volatilization  rates
 from these  three process steps of 15,  36,  and 70 percent.  Further, as
 indicated in Table 4-4 of low-arsenic proposal  BID,  the hot  ESP (260°C)
 controlling process emissions  from the reverberatory  furnace .(and dis-
 charging  through the main stack) was assumed to control  arsenic at
 40 percent  efficiency.   This  is consistent with Agency  observations of
 arsenic collection by control  devices  in smelter hot  process streams.
 Since Kennecott supplied only  an overall  balance figure,  and not a
 detailed  figure similar  to EPA's BID I  Figure F-6(a),  the Agency cannot
 determine^which of its assumptions  are being objected  to  by  Kennecott.
 Kennecott's suggested main stack arsenic emission rate  of 0.24  kg/h
 (0.53 Ib/h)  appears  to rely on an  assumption of approximately 95 percent
 control  efficiency  for the hot ESP  controlling  furnace  arsenic  emissions,
 although  this was  not stated  by Kennecott.   Since available  emission test
 data for  hot ESP's  (Phelps Dodge-Ajo)  show collection efficiencies of
 about 30  percent,  the Agency believes  that 95  percent control efficiency
 apparently  assumed  by Kennecott for  arsenic  is  much too high.   Since
 Kennecott provided  no documentation  for  its  assumption  of  this  extremely
 low  main  stack  arsenic emission  rate, EPA  is  continuing to base  its
 calculation of  risks  due  to the  Kennecott-Hayden smelter  on  its  calculated
 rate of 3.2  kg/h  (7.0 Ib/h).

     Kennecott's  submittal outlining specific smelter improvements does
 not  conclusively  demonstrate that fugitive emissions have  been  reduced
 by 50 percent from previous levels.  The EPA  has retained  its estimate
 of 0.91 kg/h (2.0  Ib/h) made at  proposal,  because it is based on  reasonable
 assumptions about  current  controls at this smelter.

 1-4.2.3  McGill  Smelter

     Comment:  Kennecott claimed that in 1982 the McGill smelter was
 custom smelting high-arsenic concentrates  from the Butte, Montana,
mine after  the Anaconda smelter  shut down.  The arsenic concentration
of this feed was atypically high for Kennecott-McGill, and this smelter
is not now smelting,  nor does  it have any  plans to smelt in the future,
high-arsenic concentrates  (such as those from the Butte mine).  Kennecott

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 estimated that stack arsenic emissions at the McGill  smelter are about
 5.5 kg/h (12.1 Ib/h) and fugitive emissions are about 1.5 kg/h (3.4 Ib/h).
 At proposal, EPA estimated stack emissions to be 45.8 kg/h (100.9 Ib/h)
 and fugitive emissions to be 5.3 kg/h (11.7 Ib/h) (low-arsenic proposal
 BID, p.  4-14 and F-19).

      Kennecott also felt that EPA had understated at  proposal  the
 degree of arsenic capture at the smelter as,defined under the  baseline
 control  case.  The company referred to anticipated improvements at the
 smelter that would reduce fugitive emissions, but did not specify the
 details  of the improvements (IV-D-634).   In its comments on EPA's
 memorandum containing revised estimates  of smelter arsenic emissions,
 Kennecott repeated that  the controls planned  under State regulations
 should be considered in  defining the baseline emission configuration
 for the  McGill  smelter (IV-D-812).

     Response:  The EPA requested further details  about the McGill  smelter
 operation from Kennecott subsequent to proposal  in a  request  for
 information made under Section 114 of the Act (IV-C-416).   In  its
 response (IV-D-788), Kennecott supplied  a figure  for  the hourly capacity
 feed rate of concentrates to the smelter (680 Mg/day  or 28.4 Mg/per
 hour [750 TPD or 31.25 tons per hour]),  but was  unable to  provide  any
 specific information on  sources, amounts, or  arsenic  content of concen-
 trates that will  be processed at McGill  over  the  next 5 years.   Kennecott
 did  indicate, however, that the smelter  would be  operated  primarily as a
 toll  smelter.  In  order  to  estimate baseline  arsenic  emissions  and the
 impact of NESHAP controls,  EPA made the  assumption that the Kennecott-McGil 1
 smelter  would be processing ore concentrates  similar  in arsenic  content
 to  those processed  by other toll  smelters in  the  Southwest such  as the
 Inspiration Consolidated  Copper Company  smelter at Miami,  Arizona, which
 processes a smelter charge  containing  0.033 percent arsenic (Table 2-3 of
 BID,  Volume I).   This assumption is consistent with Kennecott's  stated
 position in its  response  after proposal  that  the  materials  processed
 at McGill  in  the  future  will  be similar  to  concentrates  processed  at
 other toll  smelters.   The resultant arsenic feed  rate to the smelter
 used  to  develop  the revised arsenic mass  balance  for  Kennecott-McGill
 presented  in  Appendix B  (Figure B-8),  and the new emission  estimates,
 is 9.4 kg/h (20.6 Ib/h).  The  revised  estimates for arsenic emissions
 from  the main stack and  for converter  fugitive emissions are 11.9  kg/h
 (26.2  Ib/h) and  1.2 kg/h  (2.6  Ib/h), respectively.

      In  its request for further  information after  proposal, EPA asked
 for details on the  anticipated  improvements at the McGill  smelter.  The
 company  replied that  it has  undertaken an option  agreement with White
 Pine County,  Nevada,  which  would require  controls  (planned for operation
 by March  1986) to reduce  S0? emissions by 60  percent.   This control
 equipment would  include a single contact  acid plant plus the associated
 hood and  flue capture  systems to achieve  the necessary SO? control.
 Kennecott stated in  its comments on  EPA's revised estimates that these
controls will be required to meet the Nevada SIP  for  SO? regardless of
whether the option  is  exercised.  Since these SO? controls are on  a
definite schedule to  be incorporated at the McGill smelter, the company
believed that emission reduction credit should be assumed in EPA's
revised estimates.  The Agency has considered Kennecott's descriptions
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of the planned controls on S02 emissions at the McGill  smelter, and
believes that at this time insufficient information is  available on the
nature and expected arsenic control efficiency of these controls to
quantify the impact on arsenic fugitive emissions.  In  addition, these
potential controls are considered too far from realization to qualify
for inclusion in the baseline, since the deadline for their installation
is well beyond 90 days after the promulgation of this NESHAP.  This
approach is consistent among all of the smelters, and constitutes a
conservative, reasonable decision in accord with EPA's  goal of minimizing
public health risk.  Therefore, the Agency is continuing to consider
the baseline control situation at this smelter to be represented by the
present control configuration (hot ESP on reverberatory furnaces,
multicyclones on converter process gases, and local capture of matte
and slag tapping emissions) without the new controls.  Further, since
EPA has determined that only a very small risk reduction would result
from the installation of best emission controls at Kennecott-McGill,
and that therefore such controls should not be imposed, the consideration
of additional planned controls in the baseline would have no impact on
the regulatory decision for this smelter.

1-4.3  PHELPS DODGE SMELTERS

1-4.3.1  Morenci Smelter

     Comment:  Phelps Dodge commented that the arsenic  feed rate
to its Morenci smelter, which the company had supplied to EPA in
April  1983, and was used by the Agency at proposal to estimate smelter
arsenic emissions, was an assumed distribution used in  computer modeling
of the smelter that overestimated the actual feed rate.  Similarly, the
figure for arsenic feed rate to the converters was a theoretical
distribution that later was found to be much higher than actual smelter
data indicated.  After proposal, the company examined samples of smelter
material from each year back to 1978 and found that the actual annual
average matte (converter feed) arsenic values ranged from 0.14 to 0.28 kg/h
(0.30 to 0.60 Ib/h), and at no time exceeded 1.7 kg/h (3.7 Ib/h) (IV-C-417,
IV-D-640,  IV-D-785, IV-F-1, IV-F-6).

     Response:  The EPA requested clarifying information from Phelps Dodge
after  proposal (IV-C-417) concerning the company's claim about the
lower arsenic feed rate to the smelter and into the converters.  The
company provided monthly average values for the arsenic content of the
smelter feed in 1983 (IV-D-785); the annual average value was 3.4 kg/h
(7.5 Ib/h).  EPA's previous estimate of 4.4 kg/h (9.6 Ib/h) has been
replaced by this lower value in the updated arsenic mass balance for
the Morenci smelter (Figure B-13 in Appendix B).  The estimated rate
of arsenic input to the smelting furnace now totals 12.6 kg/h
(27.8 Ib/h), which in addition to the 3.4 kg/h (7.5 Ib/h) feed rate  in
the concentrate, includes 8.9 kg/h (19.7 Ib/h) in the dust and 0.27  kg/h
(0.6 Ib/h) in the converter slag recycled to the furnace (slightly
lower than previous estimates).

     In response to EPA's request  for clarifying information on the
feed rates to the converters, Phelps Dodge responded that it had found
in recent  sampling (February 1984) during oxy-sprinkle operation (which
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 EPA had  assumed to be the baseline configuration),  that matte arsenic
 levels will  not increase above levels  reported previously for reverber-
 atory operation, and may actually be  lower.   They pointed out, however,
 that the recent measurements  provide  only tentative values,  and further
 testing  is necessary to  establish consistent values.   The EPA has
 decided  to calculate the arsenic  feed  rate to the converters for the
 updated  arsenic distribution  utilizing the arsenic  percentages suggested
 in  the arsenic mass balance figure submitted by Phelps Dodge after
 proposal  (which reflects the  recent sampling efforts).  These percentages
 are 60 percent of the arsenic input to the furnace  volatil-ized, 26  percent
 slagged, and 14 percent  or 1.7 kg/h (3.8  Ib/h), reporting in the
 matte charged to the converters.

      The EPA has run the exposure model using the lower arsenic emission
 estimates reflected by the revised arsenic distribution.   Modeling  input
 parameters are presented in Appendix  C.

 1-4.3.2   Ajo Smelter

      Comment:   Phelps Dodge claimed that  a "drastic overestimation"  of
 arsenic  emissions  from its Ajo smelter had been made  in the  proposal,
 since EPA relied on data from a limited period unrepresentative of  the
 present  and  future situation  at this smelter.   The  arsenic levels in
 the concentrate feed when tests were  performed in 1976 and 1978
 (0.3 percent)  were the highest levels  recorded in 17  years,  and the
 figure should be corrected to reflect  the current level  of 150 ppm.
 Examination  of the remaining  valuable  ores at the Ajo  mine reveals  that
 the high  arsenic levels  experienced in the past will  not  recur.

      Phelps  Dodge  also referred to two control  measures  at the  Ajo
 smelter,  which they felt EPA  had  overlooked  when the  proposal  was
 developed, and which should further reduce the public  exposure  to
 inorganic arsenic  near the smelter.  These controls  include  the
 installation of fugitive gas  capture systems  for matte and slag tapping,
 and dust  suppression practices  in the  copper concentrate  handling area
 of  the smelter (IV-D-640,  IV-F-1,  IV-F-6).

      Response:   To  quantify the assertion  of  PheTps Dodge concerning
 EPA's overestimation of  the current arsenic  feed  rate  to  the  Ajo smelter,
 EPA requested  further information  from Phelps  Dodge under Section 114
 of  the Act (IV-C-417).   The company responded  that a reasonable  (assumed)
 average concentrate feed  rate to  this  smelter  is  20 Mg  per hour  (22 TPH)
 (IV-D-785).   Combining this value  with the average arsenic content of
 the feed  of  150 ppm,  the  rate at  which arsenic  is fed  (in the concentrate)
 Into  the  smelter is  now  estimated  at 3.0  kg/h  (6.6  Ib/h), compared to
 EPA's previous  estimate  of 46.8 kg/h (103  Ib/h).  (The total   feed,
 including  recycled  materials,  is  now 3.9  kg/h  [8.6 Ib/h], compared to
 the previous  estimate  of  59.4  kg/h  [130.9  Ib/h].)  The  EPA accepted the
 company's  revised arsenic  feed  rate estimate  since the smelter  owner
 is  in the  best  position  to  determine this  quantity on  the basis  of current
measurements.   The  lower  value  of  3.9  kg/h (8.6  Ib/h)  has been  incorporated
 into a revised  arsenic mass balance for the Ajo  smelter (Figure  B-10)
which is  presented  in  Appendix  B.
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     As indicated in Section 4.3.2.10 of low-arsenic BID, Volume I,
the baseline smelter configuration assumed for Phelps Dodge-Ajo at
proposal included an oxy-sprinkle modified reverberatory furnace.  The
arsenic distribution exiting this furnace was assumed to be 76 percent
volatilized, 17 percent slagged, and-7, percent reporting in the matte
(Figure F-10(a) of BID I).  However, since proposal EPA has learned
that the consent decree that would have dictated this furnace conversion
has been amended such that no furnace conversion now will take place.
Therefore/a distribution of arsenic appropriate to the unmodified
reverberatory furnace has been assumed in the revised mass balance.
These percentages are 55 percent of the arsenic volatilized, 25 percent
slagged, and 20 percent reporting in the matte.

     Fugitive emission controls on matte and slag tapping operations
at the Ajo smelter were not overlooked in the development of the proposed
arsenic standards.  Table 4-5 of BID, Volume I, indicates capture
efficiencies of 90 percent for both of these sources of fugitive emissions.
However, these captured emissions from matte and slag tapping are not
collected in control equipment, but ,are vented directly to the main
stack (page 4-29 of BID I).  For this reason, the emission reduction
efficiency for these sources of fugitive emissions is zero.  Therefore,
Table 111-2 in the proposal preamble (at 48 FR 33144) indicates no
difference between potential and baseline secondary emissions from
matte and slag tapping operations at Phelps,Dodge-Ajo.  The risk modeling
did, however, account for the higher release height of the captured
portion (90 percent) of these fugitive emissions.  These controls were
assumed to be in operation for the calculation of baseline arsenic
fugitive emissions at Phelps Dodge-Ajo at the time of proposal and are
retained in the revised emission calculations.  Concerning dust suppression
in the  concentrate handling area, only fugitive emission sources wtthih
the process area of the smelter were considered in estimating total
fugitive emissions,from the smelter.  Thus, no fugitive emission factor
was developed for concentrate handling.

1-4.3.3  Hidalgo Smelter

     Comment:  Phelps Dodge pointed out in its comments on EPA's
revised smelter arsenic emission estimates that, since proposal, the
arsenic feed rate to its Hidalgo smelter had decreased significantly
due to  a change in the smelter's source of copper ore concentrates.
Since present concentrates contain only 0.001 to 0.005 percent arsenic
(0.018  percent assumed at proposal), the arsenic input to the smelter
now averages only 0.4 kg/h (0.9 Ib/h), versus 14 kg/h (30.6 Ib/h)
assumed by EPA at proposal (IV-D-813).

     Response;  The EPA has revised its estimates of the arsenic
emissions from the Hidalgo smelter based on the information submitted
in Phelps Dodge's comments.  The estimates EPA developed at proposal
were based on earlier Phelps Dodge information, including the 0.018 percent
arsenic content figure.  In response to these latest comments, EPA has
selected the midpoint of the suggested range of arsenic contents, or
0.003 percent, as an appropriate figure upon which to calculate new
revised emission estimates.  The resulting arsenic mass balance figure
for Phelps Dodge-Hidalgo is shown as Figure B-12 in Appendix B.  The
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new emission  estimates were  used  in the exposure model to update  the
risk estimates; modeling  input  parameters are  presented in Appendix C.

     Table 4-1 presents the  baseline converter secondary arsenic
emissions estimated  by EPA for  low-arsenic smelters at the time of
proposal, and current EPA estimates for these  emissions revised as a
result of public comments received by the Agency since proposal.  All
of the revised estimates are lower than the proposal figures, with the
exception of the Kennecott-Hayden estimates, which are unchanged.

1-4.4  GENERAL COMMENT ON EMISSION ESTIMATES

     Comment:  The United Steel workers of America (USWA) felt that no
set of emission estimates should be considered  final and definitive.
The regulation should provide for a continuing  examination of arsenic
emissions from all sources at the smelters, in  order to identify
opportunities for additional  control (IV-D-708).

     Response:  The  EPA agrees  with this commenter that estimations of
emissions from a source should  not be considered final, and that
continuing examinations, as circumstances warrant, should be carried
out in order to have up-to-date and accurate emission information
on record.  It was for this reason that the Agency's estimates at
proposal were reevaluated subsequent to the receipt of public comments.
Several emission estimates were revised to reflect new information on
feed arsenic concentrations,  smelter configurations, and process data
(IV-B-32).  Also, the estimates specifically for ASARCO-Tacoma were
continuously revised and released to the public (IV-B-10, IV-C-120,
IV-E-23).  The final  regulation was issued after considering the best
information available.  The regulation will  be  periodically reviewed
after promulgation and changes made as appropriate to account for any
new information relating to arsenic emission sources at primary copper
smelters.
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     Table 4-1.  EPA PROPOSAL AND REVISED BASELINE ARSENIC SECONDARY
               EMISSION ESTIMATES FOR CONVERTER OPERATIONS
                              EPA Estimates of Baseline Secondary
                                  Emissions from Converters
Smelter
ASARCO-Hayden
ASARCO-E1 Paso*
Kennecott-Utah
Kennecott-Hayden
Kennecott-McGill
Phelps Dodge-Morenci
Phelps Dodge-Ajo
Phelps Dodge-Hidalgo
Proposal Estimate
Ib/h
7.7
7.0
2.0
1.8
11.7
1.8
0.7
0.3
kg/h
3.5
3.2
0.90
0.80
5.3
0.80
0.30
0.14
Mg/yr
30.1
27.5
8.0
6.5
45.9
6.9
2.6
1.2
Revised Estimate
Ib/h
1.3
3.4
0.9
0.4
1.8
2.6
0.4
0.13
0.05
kg/h
0.60
1.5
0.40
0.20
0.80
1.2
0.20
0.06
0.02
Mg/yr
5.4
13.3
3.4
1.5
6.5
10.1
1.9
0.52
0.19
*The higher revised estimate for ASARCO-E1 Paso is based on assumption
 of an emission factor for uncontrolled converter fugitive emissions of
 15 percent of the arsenic contained in the converter primary process
 gases.  The lower revised estimate is based on assumption of a 3.75
 percent emission factor.  These two values are presented to assess the
 range of possible impacts; see Section 1-4.1.2).
                                  1-4-17

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                  1-5.0  HEALTH RISK.ASSESSMENT

     Comment:  Phelps Dodge, Kennecott, and ASARCO stated that Section
112 was intended to apply only when emissions pose a significant risk
of increased mortality or serious irreversible, or incapacitating
reversible illness.  Phelps Dodge felt that the evidence presented to  '
EPA has established that arsenic emissions from U.S. primary copper
smelters do not present significant risks.  The evidence that the
companies presented in support of their position included the following:
both community and certain occupational studies do not de.tect lung
cancer risks associated with exposure levels at or greater than those
occurring near primary copper smelters; and the smelter exposure levels
are less than those found in some cities in the U.S. (IV-D-620, IV-D-634,
IV-D-640).

     Response:  As discussed in "Inorganic Arsenic NESHAP:  Responses to
Public Comments on Health, Risk Assessment, and Risk Management" (EP'A-
450/5-85-001), the evidence examined by the Agency has not proven that
primary copper smelters pose insignificant or nonexistent risk to the
exposed public.  (The commenters did not deny that arsenic exposure was
occurring.)  The community and occupational studies were cited to support
the commenter's position, but these studies generally do not have the
statistical power to detect significant increases in lung cancer at the
exposure levels predicted by the Agency's models.  Although they did
not detect increases in risk, these studies could not conclude with a
high degree of statistical confidence that risk increases were not
present.  By applying the best information available and using a scien-
tifically creditable exposure/risk relationship that was based on
occupational data, EPA has estimated (extrapolated) increased lung
cancer risk to the public surrounding the smelters.

     Another part of the companies' comments involved a comparison of
the ambient concentrations caused by smelter emissions with the
highest concentrations measured at other places in the U.S.   According
to EPA's estimates and data banks, the maximum concentrations to which
people may be exposed near smelters range from about 0.01 to 1.0|j.g/m3,
and the highest annual concentrations reliably reported in areas not
affected by smelters were in Ohio and Atlanta, Georgia, at about
0.01 ng/m3.  This comparison indicates that arsenic concentrations in
most areas are well below the predicted and measured concentrations
near copper smelters.

     In the Administrator's judgment,  the primary copper smelters are
posing significant risks, but in light of the magnitude of the estimated
risks and the impacts of requiring further controls, most of those
risks are not unreasonable.

     Comment:  Two commenters who had carefully studied EPA's risk
assessment results criticized the fact that the computerized exposure
model  placed portions of exposed populations at points where people
could not possibly live.   For instance, in the Phelps Dodge-Ajo
smelter analysis,  people had been located in uninhabited areas near
the smelter such as tailings ponds, slag heaps, and waste dumps
(IV-D-640, IV-D-704a).
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      Response:  The EPA is aware that the computer model can assign
 exposed people to unlikely places near a smelter.  This is not a problem
 with the model, but occurs due to the format of the census data.  Of
 necessity, the census data are provided to and used by EPA in a summary
 form so that the computer data storage capability is not overloaded.
 Instead of providing records on the location of each family dwelling,
 the census bureau gathers a number of people (up to 2,000 people) and
 locates this group of people at one point called a "population centroid."
 Of course, most of the people in the group do not actually dwell at
 this population centroid.   The exposure computer program accounts for
 the fact that groups of people do not live at a single point and, using
 a preselected formula that more realistically reflects the actual
 population distribution,  assigns people to nearby points on the concen-
 tration profile grid.  Generally, this approach causes the model estimate
 of the risk to the most exposed person to increase,  since "spreading
 out" the population over  a broader area increases the likelihood that
 people will be placed nearer points of maximum concentration.   After
 the HEM model has made the risk estimates,  EPA staff review the computer
 printouts to insure that the estimation of the risk  to, and the location
 of, the most exposed individual is reasonable.   This judgment is based
 on a study of small scale  U.S.  Geological  Survey (USGS) maps and
 discussions with Agency personnel who have  visited the plants.   In the
 calculation of annual  incidence or aggregate risk for a large  number of
 nearby people,  such careful  checking becomes very difficult.   In cases
 where the Agency has attempted to make such corrections in the  modeling,
 the results have not changed significantly.   The reason for this is
 that the computer simply  locates  people in  a more reasonable  spot where
 the concentrations may be  larger  or smaller than at  the original  location.
 With larger populations,  the corrections  tend to result in about equal
 positive and negative  changes  to  the estimated  risks,  and thus  balance
 each other.   With smaller  populations,  the  Agency reviews the reasonable-
 ness of the  exposure results and,  where deemed  necessary,  makes corrections
 by hand calculations.   Although somewhat  disconcerting  to  several
 commenters,  the Administrator  believes  that the  risk  assessment techniques
 used as a basis for today's  rulemaking  produce  reasonable  exposure and
 risk estimates,  given  all  the  other  uncertainties  that  are  associated
 with the risk assessment process.

      Comment:   One commenter noted  that EPA  assumed  that indoor air
 arsenic concentrations  equaled  the  ambient  concentrations  near  a  house,
 and felt that EPA's  assumption  probably causes overestimation of  exposure
 and risk (IV-D-634).

      Response:   When  developing inorganic arsenic  exposure  estimates,
 the  Agency considered  this possibility.   If  there  are no sources  or  sinks
 for  arsenic  in  a  house, the  long-term concentrations  in  the house  should
 equal  the concentrations measured just  outside the house.  However,
 this  may  not  be  true for some homes.  For example, homes  that have a
 filtered  air  handling  system for  heating and  cooling would  tend  to have
 lower  indoor  arsenic concentrations.  Little  study has  been made of
 the  relationship between indoor and  outdoor arsenic concentrations.
The  limited available data on total  particulate matter  indicate  that
 the  indoor concentrations are somewhat  lower  than ambient concentrations
 but  the difference  is not substantial;  the indoor particulate matter

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levels are about 10  to 30 percent  lower  than  in  the outdoor air.
Whether this ratio applies to homes near arsenic sources  is unknown.
Since people spend some amount of  the  time on  their property outside
the house and since  the available  data do not  indicate  that a correction
for indoor arsenic concentrations  is required, the assumption of equal
arsenic concentrations for both indoor and outdoor air  over a long  term
is reasonable, and probably leads  to conservative health  risk estimates.
The EPA has not made any changes to its  current analysis  to account for
this factor.

     Comment and Response:  Phelps Dodge stated  that the  location
coordinates for its Ajo smelter that EPA presented in low-arsenic
BID, Volume I are inaccurate (IV-D-640).

     In response to  this comment,  EPA  checked  its location data on  a
small-scale USGS map and has made  the  location change (less than a
kilometer shift in position).  The current risk assessment is based on
the new location data.

     Comment and Response:  Several of the primary copper smelter
companies felt that EPA should present a table for each smelter that
provides the distribution of levels of exposure.  (The EPA only showed
this information for all smelters  as a group, not for individual
smelters.)  They said that without this  information, the  public is  not
able to check the accuracy of EPA's exposure assessment (IV-D-621,
IV-D-640, IV-D-704a, IV-F-1).

     As a result of  these comments, EPA  has expanded its  risk assessment
discussion for primary copper smelters and the other source categories
(see Appendix C of this document)  and  has included in each docket
copies of the exposure assessment  computer printouts.

     Comment:  Several commenters  criticized the appropriateness of the
meteorological data EPA used in its dispersion modeling.  One (IV-D-608)
said EPA did not rely on accurate  meteorological studies.  Some commenters
(IV-D-621, IV-D-640, IV-D-704,  IV-F-1) said that, since the Tucson  data
used to model Phelps Dodge smelters in Ajo and Morenci, Arizona, were
from a location over 160 km (100 miles)  from these smelters, the data
are not representative of meteorological conditions at the smelters.   ',
They suggested that local meteorological data be used.   Another (IV-D-704)
said the model, by using the Tucson'data, estimates the highest concen-
trations to be to the northwest and west-northwest of the smelter.
This commenter said data show Ajo's winds to be primarily from the
south,  so the highest concentrations should be directly north of the
smelter.  However,  areas north of  the  smelter are largely uninhabited.
These commenters believed that using the Tucson data caused overestimation
of exposure.  One commenter also felt that assumptions about atmospheric
stability should be avoided,  and instead that soundings should be taken
at various heights to measure stability.

     ASARCO (IV-D-620) also claimed that the Tucson data were not
representative of their smelter at Hayden.   ASARCO said Tucson was over
100 km (60 miles)  from Hayden,  and that Tucson is in a broad valley,
whereas Hayden is mountainous with a narrow valley,  so wind patterns

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 would be different.   ASARCO also commented that the El  Paso smelter is
 on  the other side of a ridge from the meteorological station whose data
 EPA used to model that smelter,  so the data are not representative.   They
 also cautioned that meteorological conditions at the elevation  of a
 tall stack may be different from those at ground level.   Kennecott also
 claimed that the Tucson airport  is located too far from their Hayden
 smelter for the airport data to  be representative of conditions at the
 smelter (IV-D-634).

      Response:  As discussed in  Appendix C, since proposal  EPA  has
 made several  efforts to improve  its estimates of risks  near primary
 copper smelters.   However,  only  the analyses for three  plant sites
 (El  Paso,  Douglas,  and Garfield) were affected by the improvements.   At
 the other primary copper smelter sites,  the Agency was  unable to obtain
 more representative  meteorological data  in a.format that could  be used
 by  EPA's computer models.   These other smelters are generally located
 in  rather sparsely populated areas and are not near a National  Weather
 Service station that collects and records the necessary  surface weather
 observations.   As the commenters point out, the selected surface weather
 observations  (meteorological  data) may not be entirely  representative
 of  the smelter area.   In this case,  the  Agency must use  the best available
 information to perform its  analysis.

      When the  Agency has conducted site-specific analyses  in the past,
 the  more comprehensive analyses  have  not provided significant changes
 in  the risk assessment results.   In  this case,  the commenters suggested
 that the risks are overestimated.   EPA's experience has  shown that,
 when applying  the more local  or  representative meteorological data,  the
 risk estimates may either increase or decrease and because  of the
 complexity of  the dispersion  and exposure models,  the changes are
 difficult to predict in  advance  of completing the new computer  analysis.

      Cgmment:   Several  commenters  (IV-D-620,  IV-D-621,  IV-D-640,
 IV-U-704a,  IV-F-1) felt that  EPA's dispersion  model  overestimates
 ambient arsenic concentrations.   Some (IV-D-621,  IV-D-640,  IV-D-704a,
 IV-F-1)  said EPA  should  have  measured the background arsenic present
 when smelters  were not operating and  compared  this with  ambient arsenic
 concentrations measured  when  the smelters were  operating to  determine
 the  extent to  which  smelters  contribute  to ambient arsenic  levels.
 These  commenters  and  others further felt that EPA  should base its
 exposure estimates on  measured ambient concentrations rather than
 dispersion model  outputs  (IV-D-620).

     Some  commenters  presented ambient monitoring  data and  compared it
 to the  dispersion model  predictions in an  attempt  to  show that  the
 dispersion model  is  inaccurate.   Phelps  Dodge,  for example,  submitted
 ambient  arsenic concentrations measured  with a  high-volume air  sampler
 for  two  periods:  January through April,  1982,  and  January through
April,  1983.   Measurements were  taken  at the Ajo  town plaza.  During
 the  first  period  the Ajo smelter was  operating  normally, while  during
 the  second  period it was closed.   These  data were  used to arrive  at an
estimate of 0.0014 ng/m3 as the  level  of  ambient  arsenic concentration
at the plaza caused by the smelter.  The  commenter  said  that EPA's
model estimated maximum ambient  concentrations  150  times greater, and

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average exposures 40  times  greater,  than  these  measured  concentrations
(IV-D-640,  IV-D-704a).                                        •

     Some  commenters  claimed  that ambient arsenic  levels  in  the  town
of Horenci  are only 10  percent  of 'the  levels  reported  by  EPA  in  the
proposal notice  (IV-D-640,  IV-F-1).  ASARCO submitted  quarterly  concen-
trations of arsenic measured  by  the  company's low-volume  air  sampling
network around El Paso  and  Hayden in 1982 and 1983, and said  the mean
measured concentration  at the Hayden fire station  (near  the  town's popu-
lation center) is 0.14 jj.g/m3.   According  to ASARCO, this  measurement
should be  multiplied  by  1.67  (yielding a  value  of  0.23 (j.g/m3)  to produce
an estimate similar to  that which would be obtained using a  high-volume
air sampler.  ASARCO  pointed  out that EPA's dispersion model  estimates a
concentration of about  0.417 p.g/m3 for this location,  which  is nearly
twice as high as the  adjusted measured concentration (IV-D-620).

     Some  commenters  (IV-D-620,  IV-D-640)  criticized EPA's dispersion
model because it does not consider the effects  of  terrain.  They said the
terrain is  not level  around copper smelters,  in particular Phelps Dodge's
Ajo smelter and ASARCO's Hayden  and  El Paso smelters.  One commenter
added that EPA's background, document for  the  proposed  standard states
that failure of the model to  consider terrain will result in  underestimation
of exposure in areas  with uneven terrain.  The  commenter  said  this is not
always the  case.  He  said measured concentrations  in Hayden were lower
than modeled concentrations (IV-D-620).

     Response;  In response to  these comments, EPA has made  several
changes to  improve or check its  exposure  and risk  estimates.   (See
Appendix C  for a detailed presentation of the current  risk assessment.)
In addition to significantly  reducing some of the  smelters' emission
estimates  (e.g., Phelps Dodge-Morenci and Phelps Dodge-Ajo),  compari-
sons between predicted and measured  values have been made to  demonstrate
the exposure model's  potential  for accurately estimating ambient
concentrations.  Since  it generally  does  not provide a site-specific
analysis that accounts for  local  terrain  features and meteorology and
because there are other sources  that emit arsenic  into the atmosphere,
the exposure model will likely both over- and underpredict measured
concentrations; but,  on the average, the  model should slightly under-
predict the measured  values.  As a result of a computer data base
search, limited ambient arsenic  data near  the ASARCO-Hayden,  Inspiration-
Miami,  Magma-San Manuel, Phelps  Dodge-Ajo, Phelps Dodge-Morenci, and
Phelps-Douglas sites were identified, while for the ASARCO-E1 Paso
site the Agency located a number of arsenic monitoring sites operated
by the State Agency and ASARCO.

     For El Paso, EPA's computer exposure model  consistently underpredicted
concentrations at 20 monitoring  sites (including six company sites).
At eight of these sites, the predicted concentrations were within a
factor of two of the measured data and all but one of the remaining
estimates were within a factor of  ten of  the measured data.   At the one
remaining site,  EPA had underestimated the arsenic concentration by a
factor of 40.   (However, the data at this one site were collected in
one year only and did not meet the air quality guidelines for calculating
a  representative annual average.)  The amount by which EPA's exposure

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 model underpredicted the measured concentrations was higher than what
 EPA would consider a natural background concentration.   In an attempt
 to improve the correlation between predicted and measured concentrations,
 EPA also performed a site-specific analysis of El Paso.  This site-
 specific analysis used on-site meteorology and considered terrain features.
 The site-specific analysis also provided predicted concentrations that
 were lower than the measured concentrations.  There are three possible
 explanations for this underprediction.  First, as the commenters have
 suggested, there is some fraction of the arsenic concentration that
 comes from other sources, such as naturally occurring arsenic in the
 local soil.   Second, studies have shown that pollution  from past plant
 emissions has increased pollutant concentrations in the surrounding
 soil  and this condition allows the reentrainment of arsenic into the
 atmosphere.   Third,  the Agency may have underestimated  current emissions
 from the plant.   Some combination of reentrainment of local  soil and
 underestimation  of the plant's emissions is the suspected but undocu-
 mented cause of  the  underpredictions.

      At the  ASARCO-Hayden and Phelps Dodge-Douglas primary copper
 smelter sites, EPA's analysis indicated that the exposure model  both
 over- and underpredicted the measured concentrations at those monitoring
 sites where  meaningful  comparisons could be made between predicted  and
 measured concentrations.   However, at the State-operated monitors near
 the smelters,  the  calculated long-term concentrations were often based
 on individual  measurements that were below the minimum  detectable level
 (MDL) of the analysis technique.   Rather than  record zeros,  EPA  assumed
 that  the actual  concentration is one-half of the MDL and used that
 value in the analysis.   Thus,  when there are a number of measured
 concentrations below the  MDL in the  data base,  the calculated long-term
 concentration  becomes more uncertain.   When the Agency  considered this
 uncertainty  in the available ambient data  at the Phelps Dodge-Douglas
 and ASARCO-Hayden  sites,  it appeared that the  exposure  model  was  making
 a  reasonable estimate if  not somewhat  of an overprediction of the
 ambient  concentrations.

      At  the  remaining primary  copper smelter sites  (Inspiration-Miami,
 Phelps Dodge-Ajo, Phelps  Dodge-Morenci,  and Magma-San Manuel), much  of '
 the ambient  data showed  concentrations  below the MDL  and, at  best,
 provided only a qualitative  comparison  to  confirm  the model's  predicted
 concentrations.  At  the Phelps  Dodge-Douglas site, EPA  performed  an
 additional site-specific  analysis  similar  to the one  performed for the
 ASARCO-E1  Paso site.  Although  the Agency  believes that the site-specific
 analysis will generally produce at any  site  the  best estimate  of  ambient
 concentrations that  occur  as a  result of a  source's  emissions, EPA's
 human exposure model  provides ambient concentration  estimates  that are
 very  similar to the  site-specific  analysis  results and  the available
 ambient  data.  (See Appendix C  for a detailed discussion of the modeling.)

     There were several primary copper  smelter  sites for which no nearby
ambient  data could be found.  When considering  the results of  the model
 confirmation efforts described above, the Administrator believes  that
 the ambient concentration estimates generated by HEM are reasonable
and represent the best estimates that can be provided within the  limited
resources available.

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     Comment:  Several commenters said that some populations are
exposed to emissions from two or more smelters.  They reasoned that
since the model does not consider the combined effects of the emissions
from plants with overlapping emissions, exposure and risk are under-
estimated.  This possibility could occur with respect to the Hayden
area since two primary copper smelters (owned by ASARCO and Kennecott)
are located in this town.  In this case, there is a potential for the
risk assessment to underestimate the maximum individual risk (IV-D-608,
IV-D-626, IV-F-1).

     Response:  The EPA checked the predicted locations where the
maximum individual risk occurs and added the risk (predicted concentra-
tions) due to the other plant's emissions to the single plant risk
value.  This procedure was used for both plants and the larger value
from those two calculations was then compared to the largest maximum
individual risk calculated in either single source analysis.  Since the
ASARCO-Hayden facility emissions dominate the concentrations, the
additional risk (concentration) from Kennecott-Hayden has been shown to
be small, about 16 percent of the ASARCO-Hayden maximum individual
risk.  The commenters have made a valid point, but the maximum individual
risk estimates that account for the overlapping of the ambient concen-
trations are essentially the same as the maximum individual risk based
on only the ASARCO-Hayden emissions.  The Agency also modified the
exposure model and estimated the risk associated with the combination
of the two plants.  The model substantiated the earlier estimates.
For the annual incidence, the combined smelter exposure assessment
indicated that the town of Hayden's annual incidence is simply the sum
of the annual incidence associated with each plant's operations.

     Comment:  Some commenters said that primary copper smelter risks
were overestimated because EPA has applied a number of conservative
assumptions that lead to worst-case risk estimates (IV-D-617, IV-D-640,
IV-D-704, IV-F-1).

     Response:  The EPA agrees with the commenters that some of the
Agency's assumptions are conservative  (e.g., that the exposed people
remain at their residences for a lifetime).  However, in several cases,
the assumptions are generally not conservative.  For example, the
assumption of flat terrain may result in underprediction of ambient
concentrations for those sources located in areas with local terrain
features elevated above the source.  Upon review of the assumptions and
their associated uncertainties, the Agency cannot determine whether the
inorganic arsenic analysis methodology is conservative, a best estimate,
or an underestimate of actual risks.  Although not able to quantify all
the uncertainties, the Agency believes that its risk assessment
provides reasonable, if not somewhat conservative, estimates and that
these estimates are the best that the Agency can reasonably make.  A
number of commenters have made suggestions for improving the risk
estimates as was mentioned in earlier comments.  The EPA has followed
their suggestions where feasible (e.g., use of nearby ambient data to
confirm the exposure model's prediction).

     Two smelter companies made their own risk calculations, which they
believed to be more accurate than those EPA presented in the low-

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 arsenic  BID  for the proposed standard.   Their  results  are  summarized
 in  Table 5-1.   At two sites (Hayden  and McGill),  EPA's estimated risks
 are very similar to those  estimated  by  the  companies.   At  the  two
 remaining sites (Garfield  and Ajo),  there was  substantially  less agree-
 ment.  The footnotes  to  the table  explain the  reasons  for  the  differences
 in  results.  Since  EPA has decided not  to regulate  any of  these  four
 smelters,  the  companies' lower risk  estimates  have  no  effect on  the
 Administrator's final  decisions.

     Comment:   Phelps Dodge and Boliden Metal 1  of Sweden requested
 that EPA delay  promulgation of the standard until the  upcoming
 epidemiological  studies  by Higgins and  Enterline  are released, in
 keeping  with EPA's  obligation and  commitment to base its regulatory
 decisions  on the most current scientific information as revealed in
 the record.  The public  should then  be  given a  chance  to comment on
 this latest arsenic health risk information (IV-D-616,  IV-D-640).
 The United Steelworkers  of America (USWA) criticized the preliminary
 unpublished findings  from  this study, noting that the  Higgins  finding
 concerning a possible "ceiling" arsenic concentration  level  below which
 there  is no risk of excess lung cancer  mortality  has no statistical
 significance.   USWA also referred  to OSHA's criticisms  that  the  study
 used only  a small subsample of the available cohort and that problems
 exist  with the  study  methodology and the hypothesis that lung  cancer
 risk depends on  the highest 30-day dose, rather than the cumulative
 dose (IV-D-708).

     Response:   Section  112(b)(l)(B) of the Clean Air  Act  specifies
 that emission standards  for hazardous air pollutants must  be
 promulgated no  more than 180  days  after such standards  are proposed
 by  the Administrator.  The  EPA must show good cause for delay  if  this
 deadline  is not  met.   In the  case  of the standard for  the  primary
 copper smelters,  promulgation  of the standard was delayed  to allow
 additional time  for public  input to the  standards development  process.
The  period of public  comment  on the proposed standards  was extended  and
 then reopened such  that  it ended 195 days after proposal.  Public
 comments on EPA's revised  arsenic  emission  and control   cost estimates
after proposal were solicited  by the Agency  in a  separate Federal
Register notice  dated  September 20, 1984 (see Section  1-1.0, Summary).
The Agency believes it provided adequate time for commenters to  submit
 information to  the  record.    Information  submitted to the record  included
discussion of the Higgins  and  Enterline  studies (II-J-13).   These
studies address  the issue  of whether there  is a "threshold" for exposure
to airborne inorganic  arsenic,  below which  there are minimal adverse
health impacts for  humans.

     In developing  proposed standards for sources of inorganic arsenic,
EPA  took the position, shared  by other Federal  regulatory agencies,
that there is no threshold  below which arsenic exposure poses no  cancer
risk (see Section C.I.2).  The Agency feels   this position is reasonable,
considering the  available  information and the fact  that public health
is at stake.   If it were anticipated that there was a good  chance of
these new analyses  conclusively refuting the no-theshold assumption,
this would provide  good cause  for additional delay  in promulgating the
final standards.  However,  EPA does not foresee that the results of

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               Table 5-1.   COMPARISON OF RISK ESTIMATES MADE  BY
                        THE SMELTER COMPANIES AND EPA
Smelter
     Baseline -
Maximum Individual
  Lifetime Risk
    Baseline -
Annual Incidence
   (Cases/yr)

Phelps Dodge-Ajo(a)
Kennecott-Garfield^b)
Kennecott-Hayden
Kennecott-McGill
Company
0-6 x 10"6
0.8-5.0 x 10-6
4.5-27 x 10-4
1.7-13 x 10~3
EPA
2 x ID"4
6 x 10-5
3 x KT4
4 x ID'4
Company
0-0.00044
0.0006-0.003
0.0017-0.025
0.005-0.1
EPA
0.0045
0.14
0.016
0.006
(a)  Phelps Dodge's analysis was based on limited sampling data collected over
     3 months at one site that was located approximately 1 km from the Ajo plant.
     The EPA's analysis was based on air dispersion models that estimate long-term
     (over several years) concentrations.  Based on the company's analysis, EPA's
     exposure model is substantially overpredicting ambient concentrations.

(b)  The EPA's risk analysis considered population exposure out to 50 km while
     Kennecott's analysis went out to 20 km.   There are a significant number of
     people that live between 20 and 50 km from the plant.  This factor may
     account for the difference between EPA's and Kennecott's estimates for
     annual incidence.  The reason for the difference in the maximum individual
     risk estimates is unknown.
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this single study will provide such a refutation.  Therefore, it was not
considered in the public interest to delay promulgation while the study
results were being prepared for release.  New scientific information related
to the health effects of arsenic will be considered in future reviews of
the standard for inorganic arsenic.
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                  1-6.0  EMISSION CONTROL TECHNOLOGY

1-6,1  SELECTION OF BEST AVAILABLE TECHNOLOGY (BAT) FOR SPECIFIC SMELTERS

1-6.1.1  BAT for Converter Operations at Kennecott-Utah

     Comment:  Kennecott maintained that EPA's specification at proposal
of best available technology as air curtain secondary hoods for converter
fugitive emissions conflicts with the previous BAT determination made
for the Kennecott-Utah smelter that was included in the Utah State
regulations.  In 1978, Kennecott installed primary and secondary hooding,
ceiling vents, fans, and ductwork in order to comply with these regulations.
The proposed NESHAP would require that the existing secondary hoods be
torn out and that air curtain hoods be installed in their place.  The
company maintained that to redefine BAT in this way would amount to a
punishment of Kennecott for having in good faith installed BAT, as then
defined, in 1978.  Kennecott feels it is possible that air curtain
secondary hoods would not be as efficient at Kennecott-Utah as "the
present system, and in fact may not be as efficient at this smelter
as they are at the ASARCO-Tacoma smelter.  BAT should not be specified
so precisely when several approaches to capture are available (IV-D-634).

     Response;  The EPA's selection of air curtain secondary hoods as
representing best emission controls on converter arsenic secondary
emissions does not conflict with previous control determinations made
in connection with State plans.  In the case of Kennecott's Utah smelter,
regulations were imposed in 1978 by the State in order to control
emissions of S02 and particulate matter (PM).  These controls were
considered to represent reasonably available control technology (RACT)
for limiting emissions of these pollutants.  The purpose of the controls
was to reduce the smelter's contribution to ambient levels of these two
criteria pollutants so that the national ambient standards could be
attained in the local  region.

     The controls specified in this NESHAP proposal were developed
under separate authority and for another purpose, and thus do not
constitute a redefinition of previous controls developed for copper
smelters.  In the time period since RACT controls on S02 and PM were
installed at the Utah  smelter, EPA has listed inorganic arsenic as a
hazardous air pollutant and primary copper smelters have been determined
to contribute significant quantities of this pollutant to the ambient
air.   The Agency believes that, in order to limit inorganic arsenic
emissions from smelters to the maximum degree possible, the strictest
controls (referred to  now as the best emission controls, and not BAT)
should be applied to sources that pose a significant health risk to
communities.  The application of these controls to a specific source is
determined following an analysis of expected emission reduction, health
risk, and the cost of  controls.  Therefore, controls are imposed where
significant benefit can be derived and where the costs are considered
reasonable.                                                      ..

     Air curtain secondary hoods were specified to control converters
because these are the  best emission controls demonstrated to EPA.
Other control  approaches, if shown to control inorganic arsenic to an

                                 1-6-1

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 equivalent degree, would also be acceptable under the standard (see
 Section 1-6.3).  In the case of the Kennecott-Utah smelter, EPA's
 analysis showed that application of air curtain secondary hoods would
 not achieve any reduction in risks; hence, it is expected that this
 smelter will not be required to install air curtain secondary hoods to
 comply with the standard.

 1-6.1.2  BAT for Converter Operations at ASARCO Smelters

      Comment:   ASARCO made a similar comment to that of Kennecott in
 objecting to the requirement to install air curtain secondary hoods on
 the converters at the company's Hayden smelter.  The existing secondary
 hoods at ASARCO-Hayden were installed less than 4 years ago at a  cost
 of $4.4 million.  These fugitive emission controls at that time were
 considered the best controls available.  ASARCO believes that air
 curtain secondary hoods installed at Hayden would be significantly less
 efficient than the prototype air curtain hood at ASARCO-Tacoma, because
 the dimensions of the Hayden hoods would necessarily be smaller (see
 Section 1-8.1.1.1).   Further, the existing secondary hoods at Hayden may
 be more effective than air curtain hoods would be at this  smelter
 (IV-D-620).   The company repeated these comments pertaining to control
 requirements for its  Hayden smelter following EPA's release of its
 revised arsenic emission and control  cost estimates (IV-D-811).

      Although  ASARCO  also objects to  any requirement for air  curtain
 secondary hoods at its El  Paso  smelter, the company would  consider
 installing these controls, which would reduce fugitive  emissions  and
 help meet OSHA requirements through improved  workplace  conditions.   The
 company stipulated that, before this  decision could be  finalized, EPA
 must make final  its general  design criteria for secondary  hoods and  the
 State of Texas Air Control  Board must  revise  the S02 and opacity
 limitations  on emission points  that would  be  affected by these  converter
 fugitive emission controls.

      ASARCO  does not  oppose the requirement for matte and  slag  tapping
 controls (hood capture followed by collection)  at  its Hayden and  El  Paso
 smelters,  because it  has already begun  these  conversions or has made
 plans  to do  so (IV-D-620).

      Response:   The response  to  this comment  is  similar  to  the  response
 in  Section 1-6.1.1.   The  existing  secondary hoods  at ASARCO-Hayden were
 not  installed  to  control  secondary  emissions  of  arsenic  from converter
 operations,  but  to control  S02  and  particulate  emissions.   Therefore,
 the  secondary  controls  installed  4  years ago  at  the  Hayden  smelter were
 not  then considered,  nor  can  they  now  be considered, to  represent the
 best emission  control  for  inorganic arsenic that escapes capture  by the
 converter  primary  hoods.   Further,  these secondary  hoods are not  designed
 to capture fugitive emissions while the converters  are rolled out for
 charging, skimming, or  pouring  operations.  The only fugitive emissions
 captured are the  secondary emissions generated due  to leaks in the
 primary  hood occurring  while the  primary hood covers the converter
mouth during blowing  periods.   Since the significant level  of fugitive
arsenic  emissions generated during  roll-out activities is not addressed
by the current control system on the converters at ASARCO-Hayden,

                                  1-6-2

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 further control  may  be necessary  to  reduce  public  health  risk due  to
 these  emissions.

     There  is  no requirement  in the  regulation  for air  curtain secondary
 hoods  installed  on converters  at  a regulated  smelter  to achieve the
 same performance levels  as  the prototype  air  curtain  installation  at
 the Tacoma  smelter.   The requirement in §61.172(b)(2) is  for  the owner
 or operator to operate the  converter and  secondary control  system  such
 that capture of  secondary inorganic  arsenic emissions is  optimized.
 This ensures that the particular  installation will  achieve  the best
 performance possible.

     ASARCO further  has  the opportunity under the  equivalency provisions
 of the  Act  to  demonstrate to the  Administrator  that the current system
 can provide a  degree  of  emission  capture, and hence public  health
 protection, that  is  equivalent to the  best  emission controls.   As  discussed
 in the  response  made  to  another ASARCO comment  (see Section 1-6.3), the
 equivalency provisions allow the  Administrator  to  use discretion in the
 consideration  of  plant-specific factors.  An  example of such  a factor
 is the  narrow converter  aisle  at  Hayden,  which  necessitates a  different
 hood design than  the  design used  at  Tacoma.

 1-6.1.3 BAT for  Furnace Process  Emissions at ASARCO-E1 Paso

     Comment:  NRDC questioned EPA's determination  (at 48 FR  33139)
 that the cold  ESP controlling  furnace  process emissions at  ASARCO-El Paso
 represents  the best control on this  source, since  its inorganic  arsenic
 removal efficiency is  approximately  96 percent.  Since ESP's  are capable
 of achieving 99  percent  removal, and baghouses  can  achieve  99.5  percent,
 how can the existing  system be considered an  adequate representation of
 the best emission control (IV-D-710)?

     Response:  The preamble to the  proposed  standard (at 48  FR 33139)
 states  that the smelting furnace offgases at  ASARCO-E1 Paso are  cooled
 to about 105°C (220°F) before  entering the ESP, and that the  average
 inorganic arsenic concentration in the cooled inlet gas stream (0.308
 g/mj) greatly exceeds  the arsenic saturation  concentration  at  1Q5°C
 (0.008  g/mj).  Under these conditions, the arsenic  in the gas  stream
 is essentially all in  the particulate  state and available for  collection
 in the  ESP.  The  EPA judged this control system (spray .chamber/ESP) to be
 properly operated and maintained.   Table 3-10 in proposal  BID.shows
 control efficiencies for  arsenic collection measured in three  sample
 runs made in 1977 to be  95.6,  97.2, and 98.8  percent.   A judgment was
 made concerning the level of control  this system could achieve continuously.
 The lowest  of the three measured efficiencies was selected to  represent
 the continuous performance of  this cold ESP (96 percent).

      In making the determination  that the system controlling  furnace
 arsenic emissions at ASARCO-El  Paso represents the  best control
 available,  EPA considered the economic feasibility of .replacing  this
 system  with  respect to the potential  additional  emission reduction that
might be achieved.  Additional  gas stream cooling measures would not
likely  increase the amount of  inorganic arsenic in  particulate form and
thus  available for collection in  the  ESP.   Further, it would not be

                                 1-6-3

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 reasonable  to  require  the  installation  of  another  ESP  in  place  of  the
 existing  ESP because  the collection  efficiency  of  the  same  type of
 control device would  not likely  be significantly greater  than  the
 current control  levels.  To  install  a baghouse  downstream of the spray
 chamber also would  not be  reasonable because  the cost  would be  dis-
 proportionate  to the emission  reduction that  could be  obtained.  Due to
 these  considerations,  the  existing spray chamber/ESP combination was
 considered  at  proposal to  represent  the most  advanced  level of  control
 for  its specific application,  considering  economic feasibility,  at  the
 ASARCO-E1 Paso smelter.  Should  future  EPA reviews of  this  standard or
 of test data conclude  that additional emission  reduction  benefits are
 achievable  on  this  gas stream, this  determination  of best controls will
 be reconsidered.

 1-6.1.4   BAT for Furnace Process Emissions at Phelps Dodge-Ajo

     Comment:  Phelps  Dodge  commented that EPA  should  not consider the
 cooling of  reverberatory furnace offgases  as  an option for  control of
 inorganic arsenic emissions  at the Phelps  Dodge-Ajo smelter.  [Note:
 EPA  had discussed in the preamble to the proposed  standard  (48  FR
 33140} the  possibility of  including  in  the final standard emission
 limits on process offgas streams at  certain smelters in the event that
 controls  expected to be installed under SIP consent decrees were not
 installed.  In particular, four  smelters,  including Phelps  Dodge-Ajo,
 were intending to install  controls on process emission sources  under
 existing  consent decrees.  However,  at  the time of proposal, there was
 some uncertainty  regarding the final form  of  the consent  decree for the
 Ajo smelter.   The EPA  stated that if this  smelter's consent decree did
 not b'ring about  sufficient process control  of the  smelting  furnace
 offgases, a requirement for  cooling  the offgases prior to control would
 be considered  under the final  regulation.  This measure would allow
 increased collection of particulate  arsenic in  the  existing ESP.]

     The  principal reasons the exercise of this option is felt  by
 the commenter  to  be inadvisable are:   (1)  the suggested temperature of
 the cooled  gas stream  (121°C,  or 250°F) is below the acid dew point,
which would lead  to equipment  damage; (2)  controls  under  the renegotiated
 consent decree would bring the smelter  into compliance with existing
 particulate standards; and (3) stack gas reheating equipment would have
 to be installed  to make stack  dispersion possible.   Phelps Dodge also
 thought that the  costs of  implementing  this control option would be
prohibitive (see  Section 1-8.1.3.2).

     This commenter stated that there is kittle documentation to
demonstrate that  gas cooling would significantly increase the arsenic
collection efficiency of a particulate  control device.   In addition,
tests on the ESP  at Ajo (controlling offgases from  the reverberatory
furnace)  show an  efficiency of about 60 percent, in contrast to EPA's
prediction of 30  percent based on the gas  stream temperature.   This
confirms the uncertainty involved in predicting arsenic collection
efficiency based on the temperature of  the gas stream (IV-D-640).
                                 1-6-4

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     Response:  In order to evaluate the contentions of Phelps Dodge
regarding the technical and cost issues related to process arsenic
controls at the Ajo smelter, EPA after proposal requested that the
company supply additional information to clarify and support its claims
(IV-C-417).  In two separate responses, Phelps Dodge addressed the
issues of gas stream acid dew point (IV-D-785) and the estimated costs
of arsenic controls for the Ajo smelter's reverberatory furnace
(IV-D-790).  The control cost issue has been addressed by the Agency in
Section 1-8.1.3.2.  This response will discuss process controls from the
standpoint of technical feasibility.

     The company's principal technical objection to EPA's discussion of
gas stream cooling concerned the Agency's selection of 121°C (250°F)
as the final cooled gas temperature for the purpose of the analysis.
Phelps Dodge commented that acid dew points encountered in process gas
streams are higher than 149°C (300°F).  To demonstrate this point,
Phelps Dodge supplied two measurements of acid dew point, in the
roaster-reverberatory stack at its Douglas smelter, of 148 and 152°C
(298 and 306°F).  The company also submitted a plot showing the rate of
acid buildup in the gas stream versus detector temperature that indicates
that at 163°C (325°F), the rate of acid buildup is essentially zero in
the process stream at Douglas.

,      The  EPA reviewed the information submitted by Phelps Dodge and
agrees that cooling of process offgasses to 121°C (250°F) at some
smelters could result  in corrosion problems, if the data submitted are
accurate.   However, the EPA does not agree with the commenter that
offgas streams in all smelters necessarily have acid dew points of at
least 149°C (300°F).   In particular, ASARCO-E1 Paso does and the ASARCO-
Tacoma and  Anaconda smelters did, prior to their closures, treat furnace
offgas streams in dry control devices at temperatures of 90 to 110°C
(190 to 230°F) (BID, Vol.  I) without corrosion problems (A-80-40/IV-E-81).
Since the  acid dewpoint of a gas stream depends on the $03 concentration
and the water vapor concentration, the acid dewpoint can vary among
facilities  due to differences in operations and conditions.  Therefore,,
without considerable further investigation and analysis, EPA cannot
determine  whether the dewpoint of offgases at  Ajo are closer to 121°C
(250°F) or 149°C (300°F).  Because the risk posed by furnace process
emissions  at Ajo are now estimated to be very  low and because significant
additional  control would not be achieved by cooling to 121°C (250°F),
such an investigation was  not conducted.

     At proposal , EPA assumed a baseline process configuration for the
Ajo smelter that included, pursuant to the terms of a consent.decree
between Phelps Dodge and EPA, a reverberatory  furnace modified to oxy-
sprinkle smelting.  The  EPA considered gas stream cooling for the possible
case where  this furnace conversion was not carried out.   It was estimated
that 55 percent of the  59.5 kg/h (131 Ib/h)  furnace arsenic input, or
32.7 kg/h  (72 Ib/h), would volatilize from the reverberatory furnace
charge into the process offgases.  The concentration of inorganic
arsenic in the process gas stream would thus  be about 32.7  kg/h (72
Ib/h in a  gas flow of  3960 acmm (,140,000 acfm) (at 315°C, or 600°F)),    ,
or 0.137 g/m3.  Since  the  arsenic saturation  concentration  at this gas
stream temperature is  about 560 g/m3, very little arsenic collection was

                                 1-6-5

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 predicted  for the  hot  ESP  currently controlling  Ajo's  reverberatory
 furnace  particulate  emissions.   However,  in  a  yas stream cooled  to
 1H1°C  (250°F),  the concentration of inorganic  arsenic  would increase  to
 about  0.205 g/m3.  Since the  saturation concentration  at this temperature
 is  only  0.035 g/m3,  the difference of  (0.205 - 0.035)  g/m3 = 0.170 g/m3,
 or  83  percent of the inorganic  arsenic  in the  gas stream, potentially
 would  be available for collection in the  ESP (equivalent to 27.1  kg/h
 [59.7  Ib/h] available  for  collection).  If the ESP collected particulate
 matter at  96 percent efficiency, then  gas stream cooling would be
 predicted  to reduce  inorganic arsenic  emissions  from 32.7 to 6.7  kg/h
 (72 to 14.7 Ib/h), or  80 percent.

     As  discussed  in Section  1-2.3.3.2 of this document, EPA's estimate
 at  proposal  of  59.5  kg/h (131 Ib/h) total  arsenic input to the reverber-
 atory  furnace has  been revised  to 3.9  kg/h (8.6  Ib/h)  based on information
 supplied since  proposal by Phelps Dodge.   The  furnace  would now  volatilize
 55  percent of 3.9  kg/h (8".6 Ib/h), or  2.1 kg/h (4.7 Ib/h) (see Figure B-10
 in  Appendix B).  In  this case,  the concentration of inorganic arsenic in
 the hot  (316°C)  furnace offgases  would be about  0.009  g/m3.  Cooling of
 the gas  stream  to  110°C (230°F)  would  increase the concentration to
 0.0136 g/m3, which is  only slightly greater,  than the saturation  con-
 centration (0.011  g/m3).   Furthermore, it would  be necessary to  cool
 the gas  stream  to  below the dewpoint of water, and thus below the acid
 dewpoint,  to condense  a significant portion,  of the arsenic.

       As discussed in  the  response to  the next comment on gas stream
 cooling  (Section 1-6.2), an examination of the current risk posed by
 furnace  process  emissions  at Phelps Dodge-Ajo  shows it to be very low
 at  0.0034  cancer incidence  per year.   From the standpoint of risk
 reduction,  then, a requirement  for gas stream  cooling  to effect addi-
 tional arsenic  collection  (even  if all the arsenic present could be
 collected)  would not bring  about  a significant reduction in health
 risk.  Based on these  considerations,  EPA has  determined that, in view
 of  the revised  values  for  furnace arsenic  feed rate, as well  as the
 very small  potential  risk  reduction possible,  this control  option
 should not  be specified at  this  time for  the Phelps Dodge-Ajo smelter.

       To support their argument that temperature of the control  device
 is  a poor  indicator  of arsenic collectability, Phelps  Dodge submitted a
 summary  of removal  efficiencies determined in emission testing of two
 ESP's.   These data showed arsenic collection efficiencies of about 50
 to  96  percent at 246°C (475°F) and 96 to  99.5  percent at 188°C (370°F).
 The commenter stated that  the reported efficiencies were based on
 concentration measurements   alone, and acknowledged that accurate flow
measurements were  difficult because of sample port locations  relative
 to  flow  disturbances.  The   EPA reviewed the material  submitted and
 found the  following deficiencies.  First,  the information provided was
 inadequate  to allow review  of the test procedures and assessment of the
accuracy of  the results.   Second, the information provided  indicated
that many of the tests were noniso kinetic  and,  thus,  are likely to be
unacceptable.  Consequently, the submitted data were  judged  by EPA to
be insufficient to  support  the argument that  temperature of the  control
device is a  poor indicator  of arsenic  collectability.
                                 1-6-6

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1-6.2  FURNACE OFFGAS COOLING AS A CONTROL OPTION

     Comment:  The NRDC disayreed with many of EPA's determinations
reyardiny the potential of yds stream cooliny as a control  measure
on process gas streams at several primary copper smelters.   This control
option was not specified for these smelters in the proposed standard
because it would likely require cooling the gas streams below 121°C (230°F),
resulting in the need for corrosion resistance measures that would be
very costly in relation to the amount of arsenic emission reduction
achievable.  In-connection with these determinations, the commenter
made three points.  First, EPA's reliance on arsenic vapor pressure
data for predicting the feasibility of collecting inorganic arsenic
from a gas stream is unsupported because the theory and available test
data are not in agreement.  Available test data cited by NRDC in support
of this assertion included (1) test data reported in the BID (p. 3-7)
that demonstrates a 30 percent arsenic collection efficiency was achieved
by a hot ESP for which no arsenic collection would be predicted based
on vapor pressure of arsenic at the ESP's operating temperature of
315°C  (559°F) and (2)  data discussed in the portion of the proposal
preamble concerning glass manufacturing plants (48 FR 33154) that
indicate appreciable (>90%) arsenic control was achieved by an ESP and
a fabric filter applied to glass furnace offgas streams where no achievable
collection is predicted based on arsenic trioxide vapor pressure.  It
was  suggested that EPA thoroughly examine this issue and attempt to
reconcile the data and theory.

       Second, evidence from emission tests performed at several copper
smelters suggests that the acid dewpoint(s) of smelter offgases may be
lower  than 100-110°C (212-230°F).  Thus, EPA's conclusion that cooling
below  121°C (230°F) would require the use of corrosion resistant
materials in control devices is not supported.  Third, there is no
discussion in the BID on the technical feasibility and cost of using
corrosion resistant materials for control devices which would permit
operating the control device at lower gas stream temperatures and,
thus,  achieving additional arsenic control.  Smelters cited as candidates
for reanalysis of the feasibility of controlling process gas streams
through cooling followed by collection include:  the roaster stream at
Phelps Dodge-Doug 1-as; smelting furnace streams at Kennecott-Hayden,
Magma-San Manuel, Kennecott-McGil 1, Phelps Dodge-Douglas, and Copper
Range-White Pine; and converter process streams at Phelps Dodge-Douglas
and Copper Range-White Pine (IV-D-710, IV-D-810).

       The NRDC felt generally that numerous opportunities for arsenic
control at primary copper smelters had been overlooked in the proposal,
and that the technology considered to represent best control is generally
well below that already in use or reasonably available (IV-D-710,  IV-F-1).

       Response;  After considering the specific points made by the
commenter, EPA reexamined the potential use of gas cooling as a control
measure.  Based on these reviews, EPA concluded that (1) arsenolite
vapor  pressure data are useful for predicting the collectability of
arsenic emissions from copper smelters and (2) additional control  of
process emissions by gas cooling should not be required.  The bases for
these  conclusions are summarized below:

                                 1-6-7

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           liPA reviewed the data cited by NRDC and concluded  that the
 data do not demonstrate any need to reconcile theory and data.   Specifically,
 the collection efficiency achieved by the hot ESP is not surprisiny
 because, as was noted in the BID (p.  3-7), arsenic compounds other than
 arsenic trioxide may be present; and  there are mechanisms other than
 condensation (e.g., adsorption) by which arsenic trioxide may be present
 as particulate matter and, hence, collected.   Although not stated in
 the BID, it is likely that the 30 percent collection efficiency achieved
 by the hot ESP reflects the collection of arsenic bound  in the  ore
 concentrate matrix rather than the collection of condensed arsenic
 trioxide.   Entrained concentrate is not unexpected in this gas  stream
 because the ESP treats offgases from  a reverberatory smelting furnace,
 the charging of which produces substantial  quantities of particulate
 emissions.  Thus, the observed efficiency is  thought to  reflect collection
 of other forms of arsenic.  Furthermore, the  observation of  greater
 than predicted collection efficiency  does not disprove the validity of
 using ars.enolite vapor pressure data  to predict the  potential for
 additional  emission reduction  from gas cooling.  Specifically,  the
 contention that temperature has a significant effect on  the  collectability
 of arsenic is  supported by test data  on the subject  ESP  and  by  test
 data for other smelters.   Emission sampling using in-stack filters
 (315°C [600°F)] followed  by an out-of-stack filter (121°C [250°F])
 showed condensation of arsenic trioxide as  predicted from vapor pressure
 considerations (II-A-14,  p.  51).   In  addition,  review of test data
 presented  in the BID shows outlet arsenic concentrations  for  four
 control  devices that operate at reduced temperatures to  be consistent
 with predicted concentrations.

       The  collection efficiencies  observed  for  inorganic  arsenic  emissions
 from glass  manufacturing  plants  are not considered predictive of collection
 efficiencies  for copper smelter emissions.  As  previously noted,  evidence
 from copper smelters clearly demonstrates  that  arsenic is  present  predomi-
 nantly as.arsenic  trioxide (II-A-14,  p.  51).   The lack of correlation
 between  emission  control  and temperature  at glass  plants  suggests  that
 the  inorganic  arsenic  present  is  not  in  the form  of  arsenic trioxide.

       The  dewpoint  data referred  to by  NRDC in  its comment were  for three
 smelters operating  control  devices at  90-110°C  (190-230°F).  These
 smelters were  treating  either  a combination of  process and fugitive offgas
 streams  or  highly diluted  process offgas  streams  in  the control  devices,
 and  the  combined streams  had very  low  S02 concentrations.  Therefore,  EPA
 sees  no  basis  for concluding,  in  general, that  cooling of  process offgases
 to 100-110°C (212-230°F)  or lower  is reasonable.  Cooling of the gas  	
 stream to 121°C  (250°F) was assumed in  the  analysis  because it was believed
 to represent a  reasonable  estimate of operating temperatures for primary
copper smelter's process  gas streams; although, it was also recognized
 that  acid dew  points may  be higher or lower than  121°C (250°F) at some
 facilities.  An additional consideration was that below 125°C (260°F),
saturation concentrations  are very small and further cooling would achieve
very  little additional emission reduction.  Since no significant emission
reductions were expected,  EPA did not  evaluate the feasibility and costs
of process controls for these smelters.
                                  1-6-8

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     Following proposal, because of the comments on the approach used,
EPA assessed the maximum potential risk reduction achievable by control
of these emission sources.  For this second assessment, the revised
smelter arsenic balances were used to predict arsenic emissions from
process streams, and it was assumed that 100 percent of the arsenic
would be controlled (i.e., the risk was reduced to zero).  The EPA
estimated the health risks associated with process emissions at all
primary copper smelters where gas cooling could potentially be applied
to reduced inorganic arsenic emissions from one or more process streams.
Table 6-1 lists the smelters and process streams considered in this
analysis.  These smelters include the smelters for which gas cooling
was evaluated as a control option at proposal plus Phelps Dodge-Ajo.
The health risk estimates were prepared using HEM, and are summarized
in Table 6-2.

      The EPA has also estimated preliminary annual costs associated with
process stream gas cooling.  For the purpose of these estimates, it was
assumed that gas stream cooling to 121°C (250°F) or below could be
achieved without requiring that special measures be taken to prevent
corrosion problems.  It was also assumed that for process streams at
all smelters except Kennecott-McGill, where converter process emissions
are currently controlled with multicyclones, and Copper Range-White
Pine, where converter process emissions are currently uncontrolled,
existing particulate collectors would not have to be replaced.  For
Kennecott-McGill and Copper Range-White Pine, the estimates include
the annualized cost of a new particulate collector in addition to the
cost of gas cooling for the converter streams.  In addition, for all
smelters the estimates include the cost of reheating the gas streams
back to their original temperatures (current temperatures without
cooling).  The annualized cost estimates are shown in Table 6-3.  It is
important to note that these costs are very preliminary and may not
accurately reflect the true cost of applying gas cooling.  However, EPA
believes these estimates do give a general indication of the relative
magnitude of the costs of applying gas cooling as a control option.

      As can be seen from Table 6-2, the annual incidence associated
with the process emission streams to which gas cooling could potentially
be applied is very low in all cases, with 0.0036 incidence per year
being the highest.  Thus, even if gas cooling could reduce process
stream emissions by 100 percent, the reduction in risk would be very
small.  In addition, the cost of achieving this small reduction in risk
could be significant, as shown in Table 6-3.  These considerations
led EPA to conclude that even if gas cooling to 121°C (250°F) or below
were a feasible control option for process emissions at these smelters,
the costs would be greatly disproportionate to the very small reduction
in risk that could be achieved, and therefore gas cooling should not be
included among the control requirements of this NESHAP.

     Comment:  The State of New York stated that EPA had not adequately
considered the physical behavior of arsenic trioxide (AsgOs) in the
Agency's analysis of the collectability of gas stream arsenic.  This
commenter discussed the special control problems resulting from the
manner in which arsenic sublimes and condenses as the temperature or
arsenic concentration changes.  Since AS203 condenses more slowly than

                                 1-6-9

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          Table 6-1.  CURRENT CONTROL STATUS OF SMELTER PROCESS
            STREAMS WHERE COOLING COULD  POTENTIALLY  BE APPLIED

Smelter
Kennecott-Hayden
Magma-San Manuel
Kennecott-McGill
Phelps Dodge-Douglas

Process Stream(s)
Smelting Furnaces
Smelting Furnaces
Smelting Furnaces
Converters
Roasters
Smelting Furnaces
Converters

Current Control
ESP
ESP
ESP
Multicyclones
ESP
ESP
ESP
Gas Stream
Temperature
(°C)
260
260
316
427
260
343
232
Phelps Dodge-Ajo

Copper Range-
 White Pine
Smelting Furnaces

Smelting Furnaces
Converters
    ESP

    ESP
Uncontrolled
310

190
340
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Table 6-2.  ESTIMATED ANNUAL INCIDENCE DUE TO PROCESS  EMISSIONS  AT  SMELTERS
                    WHERE GAS COOLING IS A CONTROL OPTION
  Smelter
 Process Stream(s)
Annual Incidence
   (Cases/yr)
Kennecott-Hayden

Kennecott-McGill


Magma-San Manuel

Phelps Dodge-Ajo

Phelps Dodge-Douglas
Smelting Furnaces

Smelting Furnaces
  and Converters

Smelting Furnaces

Smelting Furnaces

Roaster, Smelting Furnaces,
   and Converters
Copper Range-White Pine    Smelting Furnaces
     0.0028

     0.0008


     0.0013

     0.0034

     0.0036


     0.0001
                                    1-6-11

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          Table 6-3.  PRELIMINARY ESTIMATES OF COSTS TO APPLY
                    GAS COOLING AS A CONTROL OPTION3
  Smelter
 Process Stream(s)
                                                        Annualized Cost
Kennecott-Hayden
Kennecott-McGill
Magma-San Manuel
Phelps Dodge-Ajo
Phelps Dodge-Douglas
Smelting Furnaces
Smelting Furnaces
  and Converters
Smelting Furnaces
Smelting Furnaces
Roaster, Smelting Furnaces,
  and Converters
Copper Range-White Pine  Smelting Furnaces and
                           Converters
3 1,200,000/yr
$ ll,800,000/yrb

$ 4,700,000/yr
3 1,600,000/yr  ,
310,300,000/yr

$ 2,700,000/yrc
•*
 Annualized costs include cost of reheating gas stream back to stream
 temperature before gas was cooled and, except as noted,  it is assumed
 that the existing particulate control device would not have to be replaced.
)
 Includes cost of new particulate control device for the  converter stream.
 Includes cost of new particulate control device for the  smelting  furnace
 stream.
                              1-6-12

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it sublimes, even a substantial lowering of the gas stream temperature
may not cause this compound to condense out.  As a result, control
methods dependent on A$203 condensation would be ineffective.
     Furthermore, the commenter stated that most of the AS203 condenses
by adsorbing onto the finest particulate matter in the gas stream (under
2 H-m).  Therefore, arsenic controls must be efficient at collecting the
fine particulate fraction.  Some particulate control  devices (such as
ESP's and wet scrubbing systems) are not efficient at collecting fine
particles, or the devices fluctuate in their performance levels.  As a
result of these considerations, the commenter concluded that well-
operated and -maintained fabric filters must be required as minimum
controls for all arsenic sources (IV-D-698).

     Response:   Two conflicting points are made by the commenter:
(1) that emission control dependent on condensation of arsenic is
ineffective and (2) that EPA should require control technologies which
are effective in particulate matter control and in particular EPA
should require use of fabric filter collectors.

      With sources that volatilize arsenic, arsenic emission reductions
can be achieved only by cooling the gas stream to condense the arsenic
and by collecting the condensed particulate matter.  At proposal, EPA
used vapor pressure data for As^s to predict saturation concentrations
of arsenic trioxide and hence condensation of arsenic.  Since proposal ,
EPA has conducted additional emission tests at several source categories
and reviewed the available data.  This investigation has shown that the
data do not completely agree with the theory.  In particular, the test
data for several sources show better collection efficiencies being
obtained at high temperatures than were predicted by theory; or more
condensation than predicted.  This deviation reflects the effects of
other factors-, such as other forms of arsenic in the gas stream and
adsorptive interactions with particulate matter, on the condensation
process.

      In the case of primary copper smelters where arsenic is present
in the form of arsenic trioxide, condensation increases arsenic collec-
tion.  As discussed in response to the preceding comment, available
test data for copper smelters show temperature has a significant effect
on the col lectabil ity of arsenic, and better arsenic emission control
is obtained at lower temperatures.  Therefore, EPA concluded that
arsenic emissions from primary copper smelters can be effectively
controlled by particulate control devices, if the gases are sufficiently
cooled.

      The EPA agrees with the commenter that for a control device to be
effective in reducing arsenic emissions from hot processes, it must be
effective in controlling fine particulate matter.  Inorganic arsenic
emissions from primary copper smelters may be effectively collected
through the use of baghouses (fabric filter collectors), ESP's, or
venturi scrubbers if emissions are sufficiently precooled.  Baghouses
and ESP's are used throughout the primary copper industry for control
of process emissions from converter operations.  The application of
venturi scrubbers at copper smelters is limited to a few instances
where scrubbers are used as part of the gas precleaning system asso-
ciated with the sulfuric acid plant.  Based on test results, the

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 collection  efficiency  of  baghouses,  ESP's,  and  venturi  scrubbers,  when
 applied  to  process  arsenic  emission  sources,  is  essentially  equivalent
 in  performance,  and control  efficiencies  greater than  97  percent can  be
 achieved.   Thus, fine  particulate  emissions of  arsenic  can be controlled
 by  well-designed and properly  operated  baghouse, ESP's, or venturi
 scrubbers.   Consequently, EPA  does not  believe  that  baghouses (i.e.,
 fabric filter  collectors)  should be  specified to the exclusion  of  other
 control  techniques  of  high  efficiency for the particular  emission
 stream (see also Section  1-6.5).

 1-6.3  DETERMINATION OF EQUIVALENT CONTROL  TECHNOLOGIES

      Comment;  ASARCO  objected to the discussion in  the proposal
 preamble  (48 FR  33149) concerning the criteria  by which equivalency of
 alternative control  measures might be demonstrated.  The  EPA stated in
 that discussion  that it would  be reasonable to consider an alternative
 capture  system equivalent to an air  curtain secondary  hood system  if:
 (1) the  results  of  a tracer  study designed  specifically for  that system
 showed an overall average  capture efficiency of  95 percent or greater;
 and (2)  no  visible  emissions were seen  to escape the capture system
 during converter charging.

      The commenter  felt that this proposal  overlooks the  fact that the
 ASARCO-Tacoma  prototype air curtain  secondary hood,  in testing  by  PEDCo
 Environmental  for EPA  (IV-A-4, IV-A-5), achieved somewhat less  than
 95  percent  capture  on occasion (and  the overall   average was  in  fact
 94  percent).   The commenter further  stated  that  the standard derivations
• of  the measurements  were  sufficiently high  that  capture efficiencies
 less than 95 percent could reasonably be  expected to be found in other
 tests.   In  addition, the  same test program  showed average opacity
 observations ranging from 21 percent during cold addition charges to
 14  percent  during matte charges.  Since not even the Tacoma  prototype
 hood achieved  the levels of performance suggested in the preamble
 discussion, there is no justification for requiring alternative systems
 of control  to  satisfy these criteria in order to be accepted by EPA as
 equivalent  systems.  ASARCO further  believes that these criteria fail
 to take into account that air curtain secondary  hoods might  not be as
 efficient at other smelters as they were  found to be at the Tacoma
 smelter (see Sections 1-2.5.1 and 1-2.5.2)  (IV-D-620).

      Response:    Tracer gas injections to test the recovery efficiency
 of the air  curtain system at ASARCO-Tacoma were made on 4 days   in
 January 1983.  The average efficiency measured for 45 gas injections on
 January 14 was  94.0  percent.  However, the  efficiency for 48 injections
 performed on January 17, 18, and 19 averaged somewhat higher at
 96.0 percent (96.9, 93.9,  and 97.3  percent for the 3 days, respectively).
 As the test report points  out (IV-A-4),  these results are subject to a
 _+18 percent error limit, based on uncertainties  of +5 percent in the gas
 injection rate  and +10 percent in the concentration  and gas flow measurements.

      Transmissometer readings during  the testing showed average
 opacities ranging from  9 to 21 percent.   Observations by qualified
 observers indicated that the overall  capture effectiveness was  greater
 than 90 percent (less than 10 percent of the visible fugitives  escaped
 capture by the  air curtain secondary  hood).

                                  1-6-14

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     While these test results are expected to provide guidance to the
Administrator in determining whether an alternate system provides
equivalent control, the criteria discussed in the proposal  preamble
were intended only as examples of performance levels that were foreseen
at proposal as very likely to qualify an alternate system as equivalent.
There is uncertainty in the tracer test efficiencies, and the test
results discussed above are representative of the performance of a
single air curtain installation.  For these reasons, the example criteria
were not intended as definite standards of performance for equivalent
systems, and would not likely be applied to a given situation as minimum
requirements.  Equivalency will be judged on a case-by-case basis for
exactly the reason pointed out by ASARCO, that plant-specific factors
could impact the performance of a smelter's control system, and these
factors may have to be considered in evaluating alternate technologies.

1-6.4  WORK PRACTICES

     Comment:  ASARCO and Phelps Dodge objected to the five work
practices in §61.172(a)(2) and §61.182(a)(2) of the proposed standards
for high- and low-arsenic smelters, and in particular to
§61.172(a)(2)(ii)(C) and §61.182(a)(2)(ii)(C), which state:

     "During skimming, the crane operator shall raise the receiving
ladle off the ground and position the ladle as close to the converter
as possible to minimize the drop distance between the converter
mouth and receiving ladle."

     The commenters felt generally that the specification of work
practices for copper converting operations is outside the scope of
EPA's traditional role, and that they merely repeat the type of practices
that the operators would undertake anyway.  They further felt that such
rules, if adopted, must allow room for operator discretion in their
application.  The commenters believe that the proposed requirement to
hold the ladle off the ground during converter skimming has definite
operational, productivity, and safety drawbacks.  The cranes have many
functions in the smelter operations, and are not necessarily available
at the time skimming occurs (a ladle is usually left on the ground next
to the converter so that a crane can return for it after skimming).
Also, a crane would be subject to an extra heat burden by being forced
to wait in the aisle near the converter during skimming.  This could
lead to extra maintenance and safety problems.  A crane in this situation
would decrease smelter productivity by not being available to perform
its other tasks in the most efficient sequence.  The commenters were
doubtful  that any significant emission reductions would result from the
implementation of the proposed work practices.  Phelps Dodge felt that
the industry should be allowed to establish internal projects to effect
optimization of secondary hood performance.

     ASARCO and Phelps Dodge also responded to EPA's request for comment
in the preamble to the proposed standards (48 FR 33134) on the establish-
ment of minimum time periods for activities called for in some of the
work practices.  They believe that such time periods would be unwarranted
and necessarily arbitrary, and that these operational  restrictions would
affect productivity adversely, increasing the U.S. copper industry's

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 already severe competitive disadvantage (IV-D-620, IV-D-640, IV-F-1,
 IV-F-2).

      The NRDC voiced support for the proposed operational  practices
 (IV-D-710). ..

      Response;  Work practices outlining general  operating guidelines
 for the converter and crane operators  at facilities  utilizing  air
 curtain secondary hoods  were proposed  in order to maximize the capture
 efficiency of this means of arsenic  emission  control.   Observations of
 visible emissions and the effects of various  operating  practices  were
 made during  the testing  performed at the ASARCO-Tacoma  smelter in
 January 1983  (II-A-71, IV-A-4, IV-A-5).   The  visible emissions obser-
 vations revealed that fluctuations in  converter and  crane  operation
 introduce significant variability into the  overall  hood capture efficiency
 and that careful  operations can minimize fume "spillage" and allow
 capture efficiencies of  90 percent and greater.   Specifically, it was
 observed that hood capture efficiency  increased considerably (to  over
 90 percent) during converter skimming  when  the crane operator  held  the
 ladle next to the converter while the  converter was  slowly rolled out
 to the.discharge position.  In contrast, when the ladle was  placed  on
 the ground during skimm'ing and the skimming rate  was  rapid,  capture
 efficiencies  varied widely from 50 to  95 percent.   It was  also observed
 that during matte charging, capture  effectiveness was improved if the
 crane was withdrawn slowly from the  space influenced  by the  action  of
 the secondary hood.   During these observations, the  crane  cables  were
 not observed  to affect the secondary load's capture  efficiency adversely;
 however, the  crane block did  affect  capture of emissions when  it was
 placed in the air curtain path.   Subsequent to these observations,  EPA
 concluded that certain operational work  practices  had the  potential  to
 markedly increase capture effectiveness,  and  hence reduce  emissions,
 although the  potential emission  reduction has  not  been  quantified.

      The EPA  reviewed  the comments on  the effects  of the proposed ladle-
 holding  requirements on  productivity considering  the range of  typical
 converter operations at  copper smelters.  A converter generally completes
 a  cycle  in 8  to  24 hours,  with  slag  blowing comprising  70  to 75 percent
 of the cycle.   The remainder  of  the  cycle is  spent in charging and
 skimming  operations, and  holding  due to  normal process  fluctuations
 within a  smelter.   At  the  end  of  each  slag blowing period, slag is
 skimmed  off the  bath and  returned  to the reverberatory  furnace.
 Typically, the  ladle is  filled  four  or five times during each  slag
 skimming  which  lasts less  than 30 minutes.  Except for  skimming into
 the  first ladle  (which may  be  done when  the crane  is not in the area),
 the  crane is  typically committed  to  skimming a particular converter and
 is  not available  for other  activities regardless of the ladle-holding
 practice  used.  Thus,  it  is EPA's conclusion that the requirement  that
 the  ladle be  held  close to  the converter during skimming could  at  worst
 decrease  productivity  only  slightly.   The question of safety hazards
was  discussed with the USWA industrial  hygienist who was familiar  with
operations at ASARCO-Tacoma.   It was  the industrial hygienist's impression
from discussions with  local union members that in the past, some crane
operators at Tacoma had routinely held  the ladle close to the converter
during skimming (IV-E-72).  It appears  that, despite ASARCO's stated

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objection to this practice, the company has not found it sufficiently
unsafe to forbid it at Tacoma.

     The work practice requirements have been generally retained in
the promulgated standard.  Alternative equipment or operating practices
are permitted under the equivalency provisions of Section 112(e) of
the Clean Air Act, upon demonstration that equivalent capture efficiency
is achieved using these alternate means of control.  The Administrator
will propose preliminary determinations of equivalent work practices in
the Federal Register.  At that time, owners and operators can submit
information and conlinent on any adverse effects of, or recommended
changes to, methods the Administrator considers necessary to achieve
equivalent emission capture.

     Minimum time periods for certain work practice activities have
not been included in the promulgated regulation.  This will  allow
considerable operator discretion in implementing the work practices
in a way that reconciles optimum emission capture with the need to
maintain acceptable productivity levels.  However, minimum time periods
could be included in a future amendment to the regulation, depending
on the results of an evaluation of the effectiveness of the work prac-
tices and the Administrator's judgment concerning the need to specify
time limits.

1-6.5  GENERAL COMMENTS ON BEST EMISSION CONTROLS

     Comment:  The NRDC agreed with EPA that ASARCO had experienced
serious operating problems with the converter building evacuation
system at its El Paso smelter, but felt that this control concept
should be given further consideration by EPA as an alternative to air
curtain secondary hoods (IV-D-710).  The State of New Mexico commented
that EPA had not examined thoroughly whether a properly designed building
evacuation system would in fact capture arsenic more effectively than
an air curtain system (IV-D-810).  The commenters believed that ASARCO1s
problems resulted from design flaws in its particular system rather
than from any essential shortcomings in the evacuation system concept.

     Response:  The EPA agrees with the commenter that the concept of
building evacuation has merit as a control technique for secondary
emissions.  Building evacuation was discussed as an alternative for
controlling converter secondary emissions in the low-arsenic proposal
preamble (48 FR 33141) and BID (Section 3.1.2.7.3).  It was stated that
EPA believes a well-designed and operated building evacuation system
should be capable of achieving at least 95 percent capture of these
emissions.  This level of control is comparable to that achievable with
the air curtain secondary hood technology.  However, as pointed out at
proposal, the building evacuation systems used currently in the
nonferrous metallurgical industry have not demonstrated this level of
control.

     The ASARCO-E1 Paso smelter is the only domestic primary copper
smelter that uses building evacuation currently to control converter
secondary emissions.  At the time of proposal, EPA estimated that due
to the use of roof ventilators which discharge directly to the atmosphere

                                 1-6-17

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and increased building openings  (to alleviate worker exposure to heat
build-up and elevated concentrations of arsenic, lead, and $02)> the
building evacuation system at ASARCO-E1 Paso was achieving approximately
75 percent capture of secondary  emissions.  In their comments, ASARCO
claimed that since EPA's initial estimate of capture efficiency, roof
ventilators in the building have been sealed shut and a new computerized
damper system has been installed in the primary hood flue to reduce
fugitive emissions (see Section  1-4.1.2 of this document).  ASARCO
estimates the efficiency of the  system after these modifications to be
about 90 percent.  During the review of public comments, EPA contractors
visited the El Paso smelter to observe the control achieved by the BE
system (IV-B-35).  During this visit the improvements to the BE system
cited by ASARCO were inspected and visible emissions observations were
made both inside and outside the converter building.  Based on these
observations, it was concluded that 90 percent capture is a reasonable
estimate of the capture efficiency presently being achieved by the
BE system.  However, this is still less than the 94 percent capture
efficiency demonstrated to be achievable with an air curtain secondary
hood.  Furthermore, in their comments, ASARCO stated that the company
is also willing to consider installing air curtain secondary hoods at
the El Paso smelter, in part to  improve workplace conditions and help
meet OSHA requirements (IV-D-620).

     ASARCO1s experience with building evacuation is not presented
as evidence that this technique could not achieve a capture efficiency
comparable to air curtain secondary hoods.  ASARCO's experience
does, however, illustrate some of the problems that can be encountered
in applying building evacuation to a primary copper smelter.

     A building evacuation system would be most effective if integrated
into the design of a new smelter.  However, potential  applications in
the copper smelter industry would be retrofits (similar to El  Paso),
since it is unlikely that new smelters will be built in the foreseeable
future.  To retrofit an existing facility with a building evacuation
system would require that the building be adequately sealed to prevent
the escape of fugitive emissions and that sufficient ventilation (to a
control device) be provided to assure satisfactory working conditions
inside the building.  The effectiveness of the system would also depend
on how well airflow patterns within the building were controlled.

     Assuming an effective retrofit could be accomplished, the
associated costs would likely be very high, particularly the capital
and annualized costs required for the ventilation air handling system.
In general, the technical  and cost requirements associated with retro-
fitting a local  ventilation system such as the air curtain secondary
hood can be more easily met.  In addition, the air curtain secondary
hood has been demonstrated to achieve 94 percent capture efficiency.
Based on these considerations, EPA chose to analyze the air curtain
secondary hood in more depth than building evacuation  as a control
alternative fpr converter secondary emissions.

     The equivalency provisions of Section 112(e)  of the Clean Air Act
(see Sections 1-6.3 and 1-6.4 of this document) allow use of alternative
equipment or procedures such as building evacuation to  comply  with a

                                 1-6-18

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design, equipment, work practice, or operational standard, provided
that will achieve an emission reduction at least equivalent to that
achieved under the standard.  Where such alternative means of compliance
are identified, the Administrator will publish in the Federal Register
a notice permitting the use of the alternative means for compliance
with the standard.  Thus, upon approval, control techniques equivalent
or superior to air curtain secondary hoods may be used to demonstrate
compliance with the standard.

     Comment:  The NRDC questioned the Agency's assertion in the-low-
arsenic proposal preamble (at 48 FR 33142) that baghouses, electrostatic
precipitators, and venturi scrubbers are comparable in terms of secondary
inorganic arsenic emission reduction performance, achieving control
efficiencies "in excess of 97 percent" on secondary offgas streams.
However, the commenter pointed out that baghouses have been demonstrated
to achieve 99.5 percent or higher.  Also, EPA's argument in the same
part of this preamble that control efficiencies are generally lower
for secondary  (low inlet loading) gas streams should be reviewed,
and detailed data should be made available to support it (IV-D-710).

     Response: The Agency made the point at 48 FR 33142 that baghouses,
ESP's, and venturi scrubbers, when applied to process arsenic emission
sources, are equivalent in performance.  It was further pointed out
that, given a  sufficiently high inlet arsenic concentration and a suf-
ficiently low offgas temperature, control efficiencies over 97 percent
percent can be achieved.  These conclusions relating to controls on
process gas streams were based on examination of test results from
these three types of control devices as presented in Section 3 of the
proposal BID's.  For example, the baghouse controlling arsenic emissions
from the multi-hearth roasters at ASARCO-Tacoma collected arsenic at
99.7 percent, and Anaconda's process baghouse achieved an average
efficiency of 98.9 percent.  The cold ESP at ASARCO-E1 Paso achieved an
average control efficiency for arsenic of 97.8 percent.  Finally, the
venturi scrubber used to clean the roaster offgases at Kennecott-Hayden
exhibited an average efficiency of 98.4 percent.  All of these average
control efficiencies are very good, are quite close to one another, and
can be considered for the purposes of a general discussion to be equiv-
alent.  Of course, more detailed characterization of the capabilities
of these three control technologies would have to consider system
operating parameters, gas stream temperatures and grain loadings, particle
size distributions, and other factors that can affect measured efficiencies
of particular  installations.  It should be noted that the baghouse
controlling the arsenic plant at ASARCO-Tacoma was also tested in
September 1978 (Table 3-6 of low-arsenic BID I) and showed efficiencies
of 95.9, 97.7, and 94.5 percent for arsenic in three sample runs.
Tests conducted in September 1983 on the replacement baghouse for the
arsenic plant  showed arsenic collection efficiencies of 99.4, 99.4, and
99.6 percent (see Appendix H, Section H.3).  The Agency believes that,
while baghouse controls can be superior in many applications (such as
when the gas stream temperature and moisture content are within tolerable
limits), they  should not be specified to the exclusion of other control
techniques of  high efficiency.
                                 1-6-19

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     The  statement  In  the  preamble  that  these  three  control  technologies
are comparable  in terms  of secondary  arsenic control  performance was an
opi'nion based on the observation  of these  controls in  many  industry
applications that parallel  the  control of  secondary  emissions at primary
copper smelters.  While  venturi scrubbers  are  capable  of  high control
efficiencies for fine  particulate matter,  the  disadvantages  of  high
operating  costs and water  handling  problems were  cited in the preamble
to highlight their  generally  lower  desirability for  applications where
baghouses  or ESP's  could be used.   The statement  that  control effi-
ciencies are often  lower -for  low  concentration inlet gas  streams is
also based on observations  of the performance  of  control  devices in
many industry applications.   In the case of primary  copper  smelters,
this behavior is seen  when  the  baghouse  test results at three smelters
are examined.  The  baghouses  controlling process  offgases at ASARCO-
Tacoma and Anaconda saw  average inlet arsenic  loadings of 288 and
885 mg/dscm, (0.126 and  0.387 gr/dscf), respectively,  compared  to only
3.27 mg/dscm (0.001 gr/dscf)  in a test of  ASARCO-E1  Paso's  converter
building evacuation system's  baghouse.  The average  control  efficiency
at El Paso was measured  as  96.2 percent, considerably  lower  than the
99.7 and 98.9 percent  percent efficiencies seen at Tacoma and Anaconda
on process gas streams.  These  comparisons reinforce previous observations
that indicate a generally  lower control efficiency of  many  control
devices for inlet streams with  lower  grain loadings.

     Comment:  The State of New Mexico stated  that EPA had  failed to
address the question of  appropriate BAT controls  for new copper smelters,
instead stating merely that no  new  smelters were  projected  to be built
in the first 5 years of  the standards.  This commenter felt  that a
thorough "BAT review"  for  new primary copper smelters  would  result in
additional controls beyond  those  proposed  for existing smelters
(IV-D-810).

     Response;  The response  in Section 1-2.3 explains  EPA's reasons for
believing  that no new  smelters are  likely  to be built  within the next
5 years.   It was for these  reasons  that EPA concluded  that it would not
be a productive use of Agency resources to define control measures for
new smelters that may  never come  into existence.  Should any new primary
copper smelters be constructed and  the converter arsenic feed rate is
above 75 kg/h (164 Ib/h),  the standard would require control of converter
secondary  emissions.   Furthermore,  any new smelter would have to comply
with the requirements  of the  new  source performance  standard for primary
copper smelters (40 CFR  60, Subpart P) which limits  process emissions
from dryers, roasters, smelting furnaces,  and converters.

      The  need for and the applicability of additional  controls depends
to a large degree on knowledge of specific processes and feed materials.
Thus, EPA  believes that  additional  control measures  for new sources
should be  evaluated only when accurate projections of  new construction
can be made.  Since the  standard  for  inorganic arsenic emissions will
be subject to periodic review, EPA  believes that a sufficient mechanism
exists for applying appropriate controls to new facilities in the
primary copper smelter source category if  this should  become
necessary.
                                 1-6-20

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1-6.6  ADDITIONAL CONTROL OPPORTUNITIES

     Comment: Sierra Club, Grand Canyon Chapter,  commented that too
few control alternatives were considered in the proposal,  and stated
that the enclosed hood-baghouse system (such as used at Kennecott-
Hurley) and by-product systems should be considered for application to
each of the smelters (IV-D-608).

     United Steelworkers of America felt that additional controls, at
the level of best available technology, should be required on all
sources of inorganic arsenic (IV-D-708).  The State of New York objected
to EPA's proposal to allow many smelters to continue using their existing
controls, instead of requiring the very best technology available, as
required under Section 112.  This commenter felt that a new proposal
should be issued with more comprehensive controls on all arsenic emission
sources (IV-D-698).

     Response:  It is EPA's belief that significant sources of inorganic
arsenic emissions at primary copper smelters were indeed considered
for regulation during development of the proposal.  In deciding which
emission sources should be regulated, the Agency considered several
factors.  Central to this process was the consideration that it might
become necessary to tolerate a certain degree of residual  health risk
to exposed populations in cases where stringent controls would lead to
unduly harsh economic conditions for a copper company, or where the
ongoing costs to operate and maintain controls would be disproportion-
ately high in relation to the amount of risk reduction achieved.
While some commenters felt that the costs of controlling inorganic
arsenic should not be considered in the development of the regulation,
the Administrator has made the judgment that consideration of costs is
necessary.

     In all of the cases of arsenic emission sources where no new
controls or additional controls were proposed, the Agency had analyzed
the availability of additional controls, the degree of emission
reduction and the reduction in health risk expected if those controls
were applied, as well as the cost to implement the controls, and deter-
mined that further controls would not be reasonable.  For example,
additional controls were considered for process sources (roasters,
furnaces, and converters) at all of the smelters.  For all cases except
the converter primary offgases at Kennecott-McGil1, it was predicted
that additional process controls would not enhance the inorganic arsenic
collection already being achieved at the smelters.  While additional
control could be realized at Kennecott-McGill, EPA's economic analysis
indicated that this smelter would be likely to close if required to
install process controls.  Unfortunately, the financial condition of
domestic copper smelters is currently quite weak due to the condition of
the world copper market.  This fact is highlighted by recent closures
of ASARCO's Tacoma smelter, Kennecott's Utah smelter, and Phelps Dodge's
Ajo smelter.  The EPA believes it is appropriate to consider this
overall industry situation as reflected in the status of individual
smelters when developing this NESHAP.  This situation will be reassessed
in future reviews of the standard.  The Agency feels that the required
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"ample margin of safety" of public health (the determination of which
is left in the Act to the Administrator's judgment) has been provided
through this approach.

     In a manner similar to process controls, the feasibility of
secondary emission controls was examined for each smelter.  At eight of
the smelters, EPA concluded that the cost of converter secondary controls
would be disproportionately high relative to the small arsenic emission
reductions achieved by the controls.  The other six smelters processing
low-arsenic concentrates were covered in the proposed regulation.

     For matte and slag tapping controls, regulation of four smelters was
considered reasonable in light of the emission reductions achieved and
the costs of the controls.  (Based on available information on smelter
arsenic balances, the final regulation is expected to affect only one
smelter.  The regulation also does not require application of matte and
slag tapping controls since they would achieve only negligible risk
reductions and would impose costs that are greatly disproportionate to
the risk reduction achieved.  These changes from the proposed requirements
were made on the basis of information received and analyses performed
after proposal, and are discussed further in Sections 1-1.1, 1-4, and
1-8 of this document, and in the preamble to the promulgated standard.)

     The residual health risk remaining after the best emission controls
were applied was examined and the Agency determined that in several cases
additional controls would not cause a significant reduction in emissions,
and in the remaining cases the smelters would likely face closure.

     Other sources of potential inorganic arsenic emissions include
miscellaneous fugitive sources primarily related to dust handling and
housekeeping practices.   Many of these sources are associated with the
air pollution control system, and requirements for proper operation and
mainatenance of this system"are separately established in Subpart A of
40 CFR 61.  For this reason, explicit requirements relating to dust
handling and maintenance practices were not included in the proposed
standard for primary copper smelters.   The Agency would like to emphasize
that the final standard (and 40 CFR 61, Subpart A) does require proper
operation and maintenance of all control  devices, proper disposal and
handling of collected particulate matter, and proper maintenance of
duct work conveying emissions to the control device.  Other miscellaneous
fugitive emission sources typically account for only a small proportion
of total emissions.   Thus, control  requirements for these sources were
not established.
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               1-7.0  COMMENTS ON PROPOSED EMISSION LIMIT

1-7.1  EMISSION LIMIT TOO STRINGENT

     Comment;  ASARCO and Phelps Dodge felt that the proposed emission
limit of 11.6 mg/dscm (0.005 gr/dscf) of participate matter on captured
converter and smelting furnace tapping secondary emissions is overly
stringent and has not been shown by EPA to be achievable on a continuous
basis.  The proposed emission limit is based on three sample runs on
the converter building baghouse at the ASARCO-E1 Paso smelter.

     ASARCO stated that the proposed emission limit was based on
manifestly inadequate data, since the majority of available data
reflects a failure of baghouses in similar control situations to achieve
the limit.  Furthermore, the company argued that three sample runs are
too few to have statistical significance in setting a standard.  ASARCO
supplied results of particulate emission tests performed on several
baghouses by the company and others which showed that the limit was
rarely achieved.  ASARCO also felt that the lower inlet grain loadings
associated with secondary streams would not allow the limit to be
achieved any more easily, since there is no direct relationship between
inlet and outlet loading levels.  This commenter was concerned that the
existing control devices at the ASARCO-Hayden and other smelters would
not be able to meet this standard, and felt that EPA should establish
an emission limit that existing devices could meet.  The company recom-
mended that the NSPS limit for particulate matter of 50 mg/m3 (0.022 gr/scf)
be adopted instead.

     Phelps Dodge also felt that there is no sound basis for the
standard, stating that EPA had ignored results from several emission
tests in selecting the limit.  The company cited EPA test results
presented in Appendix C of BID, Volume I, showing average particulate
emissions of 46.7 mg/dscm  (0.020 gr/dscf) from the Anaconda baghouse
and 16.5 mg/dscm (0.007 gr/dscf) from the Phelps Dodge-Douglas baghouse.
They also referred to 21 more emission tests the company had performed
between 1977 and 1980 at the Douglas smelter that showed average parti-
culate emissions of 32.7 mg/dscm (over half the tests with results over
11.6 mg/dscm).  The company felt the proposed emission limit is overly
strict in light of the majority of the test data and the fact that the
NSPS limit, is 50 mg/dscm (IV-D-620,  IV-D-640, IV-F-1, IV-F-2).

     Response:  The EPA does not agree with the commenters that the
proposed emission limit is overly stringent so as to be unachievable on
a continuous basis.  In order to select this limit, the Agency reviewed
particulate matter source  test results for control devices judged to
represent the best technology for controlling converter secondary
emissions.  The available  source test data for such control devices
consisted of one series of three test runs conducted in 1978 on the
baghouse treating emissions captured in the ASARCO-E1 Paso converter
building evacuation system.  Emissions of particulate matter in these
runs were 1.1, 2.5, and 11.6 mg/dscm (0.0005, 0.0011, and 0.0051 gr/dscf,
respectively).  These were the only  data available that reflected the
operation of the best control technology on a converter secondary
emission stream.

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      The level  at which an emission standard should  be set,  given  a
 particular body of test data, is  a matter of judgment.  Some argue that
 the best observed control  level  should be selected as  a standard to  be
 imposed on all  control  systems,  while  others argue for the lowest
 control level  or some  intermediate level.  The  EPA selects an emission
 limit based on  the amount  and quality  of available data, and on the
 Agency's judgment concerning  the  capabilities of similar control
 technologies across a  range of similar applications.   In this case,  the
 test run indicating the highest  emissions was selected to allow a
 reasonable margin for  differences  among facilities and control devices,
 and for variations in  sampling procedures and analytical  methods.

      The test  data submitted  by ASARCO were  reviewed by EPA  for compar-
 ison to the data considered in selecting the proposed  emission limit of
 11.6 mg/dscm.   For the  17  tests showing a figure for inlet grain loading,
 the inlet particulate  concentration ranged from  0.3 to 65 g/dscm (0.133
 to  28.40 gr/scf), averaging about  8 g/dscm (3.5  gr/scf).  In contrast,
 inlet concentrations in the testing used in  selecting  the standard
 never exceeded  71 mg/dscm  (0.031 gr/dscf).   Inlet concentrations were
 not shown for the remaining 57 tests or test runs in the data submitted
 by  ASARCO,  and  so the  gas  stream conditions  in these tests cannot  be
 evaluated for their similarity to  EPA's reference data base  from ASARCO-
 El  Paso.   Since the inlet  conditions in these tests were considerably
 different from  those expected  in a  gas  stream containing  converter
 secondary emissions, the performance of these control  devices is not
 considered  indicative of the  expected  performance of well-operated
 devices controlling converter  secondary emissions.  One  test consisting
 of  two  runs  on  the ASARCO-E1  Paso converter  building baghouse performed
 in  1983 showed  outlet concentrations of 85 and 167 mg/dscm (0.037 and
 0.073 gr/scf, respectively).   However,  EPA found in its  review of the
 test report  that  the condition of the  control device was  not reported.
 In  addition, these outlet  concentrations  exceed  the inlet concentrations
 measured  at  the  same baghouse  in the 1978 test program.   These factors
 suggest that the  condition  of  this  baghouse  in 1983 may  have deteriorated
 from the  level  in  1978,  and therefore  did not reflect  the performance
 of  the  best  control  systems necessary  under  this NESHAP.

      Tests were  run  in  1977 on the  spray  chamber/baghouse system at
 the  Anaconda smelter.   (The smelter has  since been permanently closed.)
 This  control system collected  process  gases  from roasting, smelting,
 and  converting operations,  and inlet particulate concentrations to  the
 system  were  found  to average about  14  g/dscm.  Because of these
 high  inlet concentrations,  which are orders  of magnitude higher than
 those  in  a converter secondary capture  system, the results from this
 testing could not  be considered in selecting an  emission limit for  a
 secondary hood system.    The baghouse at the  Phelps Dodge-Douglas smelter
 collects captured  fugitive  emissions from the calcine  discharge operation,
 and  inlet particulate concentrations averaged about 5,800 mg/dscm in the
 EPA testing referred to by  Phelps Dodge.  As in  the case of the Anaconda
 testing, the inlet conditions  to the baghouse are not  representative  of
 the inlet conditions experienced in a converter  secondary control  system.
The conclusion concerning the  test results submitted  by ASARCO is
therefore also applicable to the results cited by Phelps Dodge, that  EPA
does not consider the performance of these control  devices indicative

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of the operation of the best control systems applied to converter
secondary emission streams.

     In arguing that lower inlet grain loadings than reflected in its
submitted baghouse data would not necessarily lead to lower outlet
loadings, ASARCO presented emission data for the arsenic plant baghouse
at its Tacoma smelter indicating that higher outlet loadings tended to
be associated with lower inlet loadings.  The EPA reviewed the data
cited by ASARCO and found the data included one inlet test that was
reported to be biased low owing to loss of part of the sample during
analysis.  When this test is excluded from the data set, the remaining
3 inlet concentrations only vary by 20 percent and the collection
efficiencies varied from 99.95 to 99.97 percent (IV-A-6).  Thus, the
data do not support ASARCO1s argument.  The Administrator agrees that
lower inlet concentrations will not guarantee that the proposed emission
limit will be achieved, and the limit was not selected on this basis.
The EPA believes that the emission test data upon which a standard is
based should insofar as possible reflect the operating conditions and
gas stream characteristics that will exist at the sources expected to
be regulated.  In attempting to confirm the achievability of the selected
limit through an examination of best technology applied to similar
sources, the Agency examined the available test data for electric arc
furnaces (EAF's) used in the steel industry, whose particulate emission
streams have similar size distributions and concentrations to those
of converter secondary emissions.  Emission test data for well-controlled
EAF's show that emission rates below 11.6 mg/dscm are consistently
achieved (EPA-450/3-82-002a), and EPA has established an NSPS emission
limit for this source of 12 mg/dscm (0.0052 gr/dscf).  A more detailed
discussion of the supporting data for the selected limit is contained
in Appendix E.

     The Administrator considered the arguments and data submitted by
these two commenters, and concluded that selecting the NSPS emission
limit of 50 mg/dscm (0.022 gr/dscf) for this NESHAP would not be
appropriate.  (The NSPS limit applies to particulate emissions from ore
concentrate heaters.)  Emission test data for ASARCO-E1 Paso and other
smelters show that uncontrolled converter secondary emission gas streams
often contain less than 50 mg/dscm of particulate matter (average for
three runs in the 1978 testing at El Paso was 50 mg/dscm).  Thus, an
emission limit of 50 mg/dscm would mean that little or no control would
be required on converter secondary emission streams.  The Administrator
decided after evaluating the data and arguments submitted by these com-
menters that the proposed emission limit should not be made less stringent
as suggested.

1-7.2  EMISSION LIMIT TOO WEAK

     Comment;  The NRDC and the State of New Mexico stated their belief
that the selected emission limit is too weak because it is based on the
worst results of three tests on the ASARCO-E1 Paso converter building
baghouse.  The particulate matter emissions from the control device
outlet ranged from 1.1 to 11.6 mg/dscm, the average for the three runs
being 5.1 mg/dscm.  The NRDC enumerated several factors arguing for a
reconsideration of the limit to reflect the level  that can be achieved

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 by  properly operated  state-of-the-art  controls.   First,  the  inlet
 concentrations entering a  baghouse  from a converter air  curtain
 capture  system would  be higher  than those from the El  Paso building
 evacuation system  (and for this  reason a baghouse on an  air  curtain
 system may show better performance).   Also, EPA concedes  (page 3-81
 of  the proposal BID)  that  the tested baghouse is capable  of  achieving
 much higher removal efficiencies  (as high as 99 percent)  than reflected
 by  the proposed emission limit.   Finally, EPA must set the standard at
 a level  that  represents what can  be achieved by the best  technology in
 use; i.e., the best (or at least  the average) of the three tests should
 be  the reference for  setting the  standard (IV-D-710, IV-D-810).

     Response:  As described in the  previous response, EPA took the
 approach of selecting an emission limit that reflects  not the lowest
 level observed in the available test data, but a limit that  allows a
 margin for process fluctuations and  for small variations  in  sampling
 and analytical procedures.  Since the data base for this  limit
 represents testing of a single control device, this consideration
 assumes more  importance than it would if there were more test data
 available.

     In  selecting a regulatory emission limit, the Agency must make a
 judgment concerning the level of emission reduction that control
 devices can meet continuously at the variety of facilities and under
 the different operating conditions  to be found throughout a  particular
 industry.  It should be kept in mind that the performance of any control
 device will fluctuate as  inlet gas stream characteristics and its own
 condition (e.g., wear on filter bags) change over time.  The apparent
 control efficiency can also be affected by small  variations  in sampling
 techniques and analytical  methodology.  This means that a properly
 operated and maintained control  device will  frequently achieve emission
 reductions in excess of the regulatory limit as a result of  these
 fluctuations.  However, the emission limit is selected so that fluctua-
 tions in the direction of  increasing emissions will  seldom if ever
 cause the limit to be exceeded.   As a result, a state-of-the-art  control
 device operated properly would be expected to operate 'much of the time
at a somewhat better level- than  the level  required in the regulation.

     The EPA believes that the selected emission  limit is stringent
enough so that the best control  devices, properly operated and main-
tained, are needed to achieve the limit on a continuous basis.  As a
result, the proposed limit of 11.6 mg/dscm (0.005 gr/dscf) is retained
 in the promulgated standard.   The regulation will  be  reviewed period-
 ically and test results at regulated sources will  be  evaluated to
determine whether any revision to the emission  limit  is appropriate.
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              1-8.0   COST ESTIMATES AND ECONOMIC IMPACTS

     The EPA received several  comments on the control  costs estimated
by the Agency at proposal , and on the economic analysis of the afford-
ability of arsenic controls for low-arsenic primary copper smelters.
The EPA's analysis of the costs and economic impacts of controls on the
copper smelting industry and on individual  primary copper smelters was
contained in Sections 6 and 7  of the background information document
for the proposed standard, BID, Volume I.  ASARCO, Kennecott, and
Phelps Dodge felt that estimated costs for six of their smelters were
underestimated in the proposal, and they supplied their own estimates
of what the costs of the best  emission controls would be under the
NESHAP standard.

     Commenters on EPA's assessment of the economic impacts of controls
generally felt that the depth  of information used in the analysis was
lacking, or that economics should not play a role in regulatory decisions
regarding hazardous air pollutants.  The Agency has retained its exami-
nation of economic impacts in  promulgating the final standard; however,
a revised analysis has been carried out and is presented in Appendix F
of this document.

     Several factors contributed to the higher cost estimates of the
commenters.  Whereas EPA had assumed that the ducting and fans in
existing secondary control systems were salvageable for use in a new
air curtain system, most smelters included a significant added capital
cost for new fans and ductwork (plus a cost for demolition of existing
hoods and ductwork).  Also, several site-specific factors arising from
differences between these smelters and the ASARCO-Tacoma configuration
used by EPA as a basis for costing caused some cost components to be
estimated higher by the commenters.  In estimating a figure for capital
recovery, the three copper companies assumed an interest rate on borrowed
capital of 15 percent and an equipment service life of 15 years (0.1710
capital recovery factor).  EPA's assumption at proposal was a 10 percent
interest rate and a 20-year service life (0.1175 capital recovery
factor).  Since the Agency's calculation methods assume dollars of
constant value in considering  annualized costs, when in fact the economy
was at the time of proposal experiencing an inflation rate of about 5
or 6 percent, the assumed real, pre-tax interest rate of 10 percent was
selected to compensate for this and express annualized costs in terms
of the number of current dollars to be paid out in future annualized
expenditures.  Thus, the nominal equivalent percentage rate is very
close to the 15 percent suggested by the companies.  In the cost
analysis, an equipment service life of 20 years was used because that
is the service life generally  assumed for sheet metal  and it was used by
ASARCO to amortize the cost of installation of launder covers at Tacoma.

     Another factor in favor of the 10 percent interest rate is the
availability of tax-exempt municipal revenue bond issues.  In general,
interest on these issues is well below 10 percent.  Examples are cited
below:

              - $80,000,000 at a weighted average interest of 7.2 percent
       in 1982 and 10.8 percent in 1981,
                                 1-8-1

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     • Phelps Dodge - $97,700,000 at 5.60-6.25 percent for the Douglas
       smelter and $118,000,000 at 7 percent for the Morenci smelter,

     • Magma - Air pollution revenue bonds at 3.675 percent plus or minus
       50 percent of the difference between the prime rate and 5 percent,

     • Kennecott - $122,000,000 at 6.5-7.5 percent and $55,700,000 at a
       variable tax-exempt rate.

     Changing the interest rate from 10 to 15 percent and the equipment
life from 20 to 15 years would increase the annualized cost by 18 to
27 percent.  Cost effectiveness and maximum price effects are affected
in a comparable manner.  However, these changes do not affect the ranking
of the hazards or the regulatory decisions.

     In its evaluation of whether the capital cost estimates submitted
by commenters were reasonable, EPA concluded that the smelter owners
and operators are in the best position to consider the effect on costs
of site-specific factors at each smelter.  The Agency felt that generally
if the companies' cost estimates were based on sound design, engineering,
and cost estimating principles, those estimates would be accepted as
reasonable for the purposes of the updated cost analysis.  The EPA's
revised cost estimates were used in the same way as the estimates at
proposal, to evaluate the affordability of controls and the cost to a
smelter per unit of arsenic emission reduction achieved by the controls.

1-8.1  COST ESTIMATES FOR PROPOSED CONTROLS

1-8.1.1  ASARCO, Incorporated Smelters

     1-8.1.1.1  Hayden Smelter

     Comment:  ASARCO claimed that EPA had greatly underestimated the
capital and annualized costs to install  and operate converter fugitive
emission controls at its Hayden.-smelter.  The EPA's capital  cost estimate
for these controls was based on ASARCO estimates (page 6-14 of BID,
Volume I) of capital  costs to install  air curtain secondary hoods at
ASARCO-Tacoma ($322,200 per converter).   However, because of individual
plant configuration differences, this estimate can serve only as an
approximation when applied to other smelters.  For example, the converter
aisle at the Hayden smelter is approximately 4 meters (13 feet) narrower
than the aisle at Tacoma, necessitating the installation of more expensive
cantilevered hoods above the five Hayden converters.   The company felt
EPA's capital cost estimate of $1.7 million was too low because of such
site-specific differences, and because several  direct and indirect
costs were not included in the estimate.  A major cost item not considered
was the cost for demolition of the existing converter secondary hoods.
ASARCO supplied a capital cost itemization for the installation of five
cantilevered air curtain secondary hoods, totaling $3.66 million.

     ASARCO also estimated the capital  cost of installing air curtain
secondary hoods similar to those at ASARCO-Tacoma, saying that this
estimate indicates how costs could escalate if Tacoma-type hoods were
required for the Hayden smelter.  ASARCO claimed that, in order for

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this installation to be performed, expensive structural  conversion work
(over $8 million additional capital cost) would be necessary to provide
clearance for the hoods in the converter aisle.  This conversion would
include raising the converter aisle crane rail  at least 1.5 m (5 feet).
Another cost to ASARCO would include $6 million for being shut down for
1 month during the installation, making the total capital cost for this
alternate control installation approximately $18 million.

     ASARCO further claimed that EPA's annualized cost estimate was too
low ($408,400 per year versus ASARCO's estimate of $1.35 million per
year for the cantilevered hood installation) because of EPA's assumption
concerning the cost of capital (10 percent interest rate instead of
15 percent), the annualized cost resulting from the $1 million writeoff
for existing control equipment that was not considered ($171,000 per
year), and EPA's failure to include a pro rata share of the cost to
operate the existing ESP ($185,800 per year), into which the captured
secondary emissions would be ducted.  The company claimed that the
inclusion of the shared cost of existing controls was necessary to give
ASARCO credit for being the first to install controls and that EPA's
approach would give industry an incentive to delay installing controls.
In addition, EPA's approach would penalize ASARCO by not providing a
cost credit for the existing secondary hoods which would have to be
scrapped if air curtain type hoods were required (IV-D-620, IV-F-1,
IV-F-2).  ASARCO reiterated its concerns about EPA's cost assumptions
in the comments it made on EPA's response memorandum (IV-D-811).

     Response:  The capital cost itemization provided in Attachment D
of ASARCO's December 9, 1983, comment submittal (IV-D-620) indicated by
general cost category the derivation of the company's total capital
cost estimate of $3.66 million.  In order to evaluate this capital cost
estimate more completely, EPA sought further cost details after proposal
in a request for information sent to ASARCO (IV-C-418).  ASARCO responded
to this request with a more detailed capital cost breakdown that
allowed EPA to evaluate the reasonableness of ASARCO's higher estimate
(IV-D-789).  The capital cost claimed by ASARCO in its comments was
composed essentially of the same cost elements assumed in EPA's estimate
at proposal (as derived from ASARCO's estimates for the Tacoma instal-
lation).  The major part of the difference between EPA's proposal
estimate of $1.7 million and ASARCO's claim of $3.66 million consisted
of direct cost items pertaining to the demolition of the existing
secondary hoods, and to the actual costs of the new air curtain secondary
hood and ductwork structures.  In the Agency's development of a capital
cost estimate, no cost was attributed to the demolition of the existing
hoods.  In addition, no cost for new ducting was assumed because EPA
believed that all existing ducting could be used in the air curtain
installation.  However, ASARCO stated that the existing secondary hoods
and ducting would not be suitable for use in the air curtain capture
system.  The EPA evaluated the claimed costs specific to this site and
determined them to be reasonable for the work proposed to be necessary
for the installation at ASARCO-Hayden.  Finally, the specially designed
cantilevered hoods considered necessary by ASARCO due to space limita-
tions in the converter aisle at the Hayden smelter would be considerably
more expensive than the hoods that were costed for installation at
Tacoma.  These higher direct (hardware) costs also would be reflected

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 in  generally  higher  indirect  costs  (e.g., engineering, contingencies),
 since  indirect  costs are  typically  estimated  as a  proportion  of direct
 costs.

      In  summary,  ASARCO's  higher  capital cost estimate is due  primarily
 to  certain  site-specific  factors  that were not considered in  EPA's cost
 analysis  at proposal.   The EPA  has  evaluated  ASARCO's cost  itemization
 and found these costs  to  be reasonable, considering the requirements of
 this installation.   The alternate control option of raising the crane
 rail and  installing  Tacoma-type hoods at a cost of $18 million is con-
 siderably less  desirable  than the installation of cantilevered hoods
 at  a cost of  $3.66 million, based just on a comparison of the costs of
 the two options.  As a  result of  these considerations, the company's
 capital cost  estimate  of  $3.66 million has been accepted in EPA's
 reanalysis  of the costs of best emission controls for converter opera-
 tions at  ASARCO-Hayden.

     ASARCO's comment  submittal provided a breakdown of total annualized
 costs  for the five air  curtain secondary hoods proposed for the Hayden
 smelter as  follows:  $626,000 capital recovery (on $3.66 million),
 $185,000  operating cost, and $183,000 maintenance cost (5 percent of
 total capital cost), for a  total  annualized cost of $994,000 for the
 first year.   The capital recovery factor of 0.1710 used by ASARCO was
 based on  a  15 percent  interest rate on borrowed capital and a 15-year
 equipment life.  As  stated earlier, EPA used  a capital recovery factor
 which  is  based  on 10 percent interest and 20-year equipment life
 because EPA believes this  represents a reasonable estimate of costs
 that would  be incurred  with installation of converter secondary
 emission  controls.  ASARCO's capital recovery estimate was adjusted to
 EPA's basis, yielding a revised capital recovery cost of $430,000 per
       Since ASARCO's estimates for operating and maintenance costs are
                        they were  accepted and added to the capital
year
considered reasonable,
recovery estimate, to produce a total annualized cost of $798,000 per
year.

     The EPA has reviewed ASARCO's claim, offered in both sets of
comments on EPA's cost analysis for ASARCO-Hayden, that the annualized
costs accruing from writing off the value of the scrapped existing
secondary hoods and from sharing the cost of operating the existing R&R
cottrell (to which converter secondary emissions captured by the air
curtain hoods would be ducted) should be included as part of the NESHAP
cost in EPA's cost analysis.  In EPA's response memorandum, these
claimed cost penalties to ASARCO were disallowed for several  reasons.
In both of these instances, ASARCO is requesting that costs associated
with existing equipment be considered in estimating the cost of new
controls.  The EPA responded in the memorandum that it is not the Agency's
policy to include the cost for book writeoff of existing controls in
estimates of the annualized costs of new controls over baseline costs.
(Such a writeoff would not represent an out-of-pocket expenditure, and
would generate a tax credit for the company.)   The operating costs of
the ESP presently in place are part of the smelter's current budget,
and EPA stated in its response that these costs should not change
significantly if additional  captured emissions were ducted to the
device.  For these reasons, these annualized cost components claimed

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by ASARCO were not Included in EPA's revised cost estimate for ASARCO-
Hayden, and the figure of $798,000 per year was used in the updated
cost analysis after proposal.

     In its comments on EPA's response memorandum, ASARCO maintained
that, while the book writeoff may not represent a current expenditure
and would lead to a tax credit, the company would still be denied full
use of past expenditures and there would still be a significant after-
tax cost to the company.  ASARCO also stated that a portion of the
existing ESP could theoretically be partitioned off and made inoperative
if the new standard was not applicable to the Hayden smelter.  Following
review of ASARCO's arguments, EPA has concluded that changing its decision
to disallow inclusion of the two cost components is not appropriate,
for the following reasons.  Most smelters have various forms of capture
and collection equipment currently installed, and would have to replace
certain segments of the existing control installation if improved
control were required.  In addition, the reduced emissions due to
existing control equipment are considered {i.e., credit is given) in
establishing the baseline emission level for a smelter.  Thus, the
potential emission (and risk) reduction at a currently controlled
facility is smaller than at an uncontrolled facility and, therefore,
the likelihood of the controlled facility being further controlled is
lower.  While the ESP could theoretically be partitioned off, this step
has not been taken under the present control situation, and so the
potential cost savings in the absence of the NESHAP is not being realized.
Furthermore, the potential cost savings can only be determined from a
detailed engineering analysis.  To conduct such an analysis would
result in further delays in issuance of this standard.

     In summary, EPA has maintained its revised annualized cost estimate
of $798,000 per year, as presented in the response memorandum.  This
figure is about twice the estimate of $408,400 per year made by EPA at
proposal.  Since EPA has determined that air curtain secondary hoods
installed on the converters at ASARCO-Hayden would not bring about a
significant reduction of health risk to exposed populations, increasing
the annualized cost estimate would have no effect on the applicability
of this regulation to the ASARCO-Hayden smelter.

     1-8.1.1.2  El Paso Smelter

     Comment:   ASARCO claimed that EPA's capital and annualized control
cost estimates for its El  Paso smelter were understated.   ASARCO
estimated the capital cost of installing air curtain secondary hoods at
$1.85 million,  or 35 percent higher than EPA's estimate of $1.38 million.
Annualized costs were claimed to amount to $727,000 per year, or about
2.3 times EPA's estimate of $307,000 per year.   In its comments after
proposal, the company supplied a breakdown of the capital cost elements
for this project,  stating that,  unlike the situation at its Hayden
smelter, air curtain hoods similar to those at ASARCO-Tacoma could be
installed at the El  Paso smelter without extensive modifications.   In
commenting on  EPA's  revised control  cost estimates,  however, ASARCO
provided a higher capital  cost estimate of $3.5 million.   The company
said it had reconsidered its original  design,  and had modified the fan
configuration  and specified a heavier hood design.   They added that

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operating and maintenance cost estimates would increase proportionately
over the company's original post-proposal estimates.  ASARCO's higher
annualized cost estimate derives from assumptions similar to those used
by ASARCO for the ASARCO-Hayden estimates, including a pro rata share
for operating the converter building baghouse ($247,500 per year)
(IV-D-620, IV-D-811, IV-F-1, IV-F-2).

     Response:  ASARCO provided a capital cost breakdown in Attachment D
of its December 9, 1983, comment submittal (IV-D-620), which indicated
the distribution of its estimated costs among several direct and indirect
cost categories.  In its response to EPA's request for information
after proposal (IV-C-418), the company provided a more detailed breakdown
of estimated capital cost by specific expenditure (IV-D-789).  ASARCO's
estimate of $1.85 million provided after proposal is based on factors
similar to those incorporated in EPA's capital cost figure.  Certain
smelter-specific factors, including demolition and ductwork costs, are
higher in the company's estimate.  The EPA's estimate included the
relatively low figure of $350,000 for additional ductwork, due to the
assumption that existing (building evacuation system) ductwork was
salvageable for use in the new air curtain secondary hood system.
Also, ASARCO made its original cost estimate for this installation in
March 1981, and then escalated the estimate after proposal to reflect a
current dollar value (approximately August 1983) by applying a factor
of 1.19 (using the Engineering News Record index).  The EPA's estimate
was based on January 1982 cost estimates for an installation at ASARCO-
Tacoma, updated to December 1982 dollars.  With regard to ASARCO's
higher capital cost estimate contained in the company's later comment
submittal, EPA in the interest of completing the regulatory development
in a timely fashion could not request from the company further details
about ASARCO's modified control system design.  These details would
have been necessary in order for EPA to complete an analysis of the
reasonableness of ASARCO's estimates.  As a result, the company's
original estimate of $1.85 million has been used in EPA's reanalysis of
converter control costs at the El Paso smelter.  To determine the
appropriateness of the decision not to seek additional details about
ASARCO's modified capital cost figure, EPA examined the impact that the
higher capital cost figure would have on the regulatory decisions
affecting ASARCO-E1 Paso.  The Agency has concluded that using the
higher capital (and resulting annualized) costs would have no impact on
the regulatory action.

     ASARCO's comment submittal provided a breakdown of total annualized
costs for the El Paso smelter's three converter air curtain secondary
hoods, similar to the breakdown provided for annualized costs at the
company's Hayden smelter.  The breakdown for ASARCO-E1 Paso included:
$318,000 capital recovery (on $1.85 million), $105,000 operating cost,
and $56,000 maintenance cost (3 percent of total capital cost), for a
total annualized cost of $479,000 for the first year.  As with the costs
for the Hayden smelter, EPA adjusted the capital recovery portion of
the total  annualized cost for El Paso (from 15 percent interest rate
and 15-year equipment life) to a standard basis representing a 10 percent
interest rate and 20-year equipment life.  This yielded a figure for
capital recovery of $218,000 per year.  Again, as in the case of the
Hayden smelter, the operating and maintenance costs suggested by ASARCO

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were  considered reasonable, and were added to the adjusted capital
recovery figure to produce an updated estimate of total annualized cost
of $379,000 per year  (23 percent  higher than EPA's proposal estimate).
Almost 80 percent of  this increase over the proposal estimate is due to
the higher capital recovery figure occasioned by the 34 percent higher
capital cost estimate.

      The EPA's response to ASARCO's claim that a pro rata share of the
existing converter building baghouse's operation should be assigned to
the costs incurred due to NESHAP  controls is the same as for the case
of the Hayden smelter.  Since the total cost of operating this baghouse
is a  part of ASARCO's current budget (no sections partitioned off),
and would not change  significantly as a result of NESHAP controls, no
incremental costs of  operation should be assigned to the standard.
Therefore, the total  annualized cost of controls cited above, $379,000
per year, is used in  EPA's updated analysis of converter control costs
for the ASARCO-E1 Paso smelter.

1-8.1.2  Kennecott Smelters

      1-8.1.2.1  Utah  Smelter

      Comment:  Kennecott commented that EPA's estimates at proposal of
the costs of installing and operating best fugitive arsenic emission
controls on converter and matte and slag tapping operations at Kennecott-
Utah were understated.  The company felt the major reason for EPA's low
estimate of the costs of converter controls was that the costs of
similar controls at ASARCO-Tacoma were used as a basis, despite the
"striking difference" in size between the two smelters and the fact
that  the Utah smelter has existing secondary controls on converters.
Kennecott supplied its estimate of total capital, operating, and annual-
ized  costs for converter and matte and slag tapping controls.  Total
capital cost was estimated at $18.5 million, versus EPA's proposal
estimate of $7.0 million.   The total annualized cost was estimated to
be $5.8 million per year,  in contrast to EPA's estimate of $1.8 million
per year (IV-D-634).

     Response:  The capital  and annualized cost estimates submitted by
Kennecott in its comments reflected the total costs of best emission
controls on fugitive emissions from both converters and matte and slag
tapping (smelting furnace)  operations.   In order to examine Kennecott s
cost breakdown for each of these control categories independently for
comparison to EPA's separate cost estimates, EPA requested more
detailed cost information after proposal in a request sent to Kennecott
(IV-C-416).   Kennecott responded with a detailed breakdown that allowed
EPA to assess the reasonableness of the company's estimates (IV-D-788).
Table 8-1 summarizes EPA's proposal  estimates and Kennecott's post-
proposal estimates of the costs of the best controls on converter and
matte and slag tapping operations.
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          Table 8-1.  FUGITIVE EMISSION CONTROL COSTS FOR KENNECOTT-UTAH
Cost
Category
Capital
($ million)
EPA Proposal Estimate
Converters Matte,
Slag Tapping
5.2 1.8
Kennecott
Converters
8.8
Estimate
Matte,
Slag Tapping
9.6
 Annualized
($ million/yr)   1.3
0.5
2.8
                                                                    2.9
          The EPA's estimate of the capital  cost of NESHAP converter controls
     was  based on  the assumption that no  new ducting or fans would  be
     required for  the BAT control  installation at the Utah smelter.   Since
     this  smelter  currently uses a secondary ventilation  system for  capture
     of converter  fugitive emissions, it  was assumed that the existing  fans
     and  ducting could  be used  in  the new installation (page 6-14 of BID,
     Volume  I).  Kennecott disagreed that this existing hardware would  be
     adequate for  the new system,  and supplied a  capital  cost estimate  for
     new  ductwork  of $3.15 million.   The  company  also provided a capital
     cost  estimate of $7.23 million  for a 28,300  acmm (1,000,000 acfm)'
     baghouse to control  secondary emissions from converter and matte and
     slag  tapping  operations.   The EPA calculated the proportional cost of
     this  baghouse attributable to the converter  secondary control system
     based on  a 10,000  acmm (330,000 acfm) gas  flow through  this system to
     be $4.1  million, about 8 percent higher than the cost of the 850 acmm
     (300,000  acfm)  baghouse EPA assumed  in  its costing.   This  cost  includes
     the additional  fan capacity necessary to  handle  the  gas  flow to  this
     baghouse.  The  cost  of the  air  curtain  secondary hoods  themselves was
     estimated  by  Kennecott to  be  $1.5 million, slightly  above  EPA's
     $1.4 million  estimate.  The EPA reviewed  Kennecott's  capital cost
     estimates  for accuracy and  adherence to sound  engineering  principles
     and found these  estimates  to  be  reasonable for the installation  at the
     Utah smelter.    Therefore,  Kennecott's figure of  $8.8 million has been
     incorporated  into the  revised costs used  in  EPA's cost analysis  after
     proposal.

         The EPA's  proposal estimate of the annualized cost  of converter
    controls was   revised in a manner similar to those relating to the
    ASARCO smelter controls (Section 8.1.1).  The  figure  for capital
    recovery was  calculated using the assumption of  10 percent interest
    rate and a 20-year service life  (0.1175 capital  recovery factor),
    whereas  Kennecott had assumed 15 percent interest and a  15-year
    service  life   (0.1710 capital recovery factor).  The resulting figure  of
    11.0  million   ($610,000 estimated by EPA at proposal)  per year was added
    to Kennecott's estimate of operating  cost of $1.0 million ($690,000
    estimated by  EPA at proposal)  per year,  to produce a  revised total
    annualized cost for converter fugitive emission controls of $2.0 million
    per year.
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     Kennecott provided a combined estimate of total operating costs
for controls on converter and matte and slag tapping operations, which
EPA divided equally to apply to converter operations and matte and slag
tapping operations.  For maintenance and repair costs, Kennecott included
an allowance of 7 percent of the total capital cost estimate.  In its
response memorandum issued for public comment (IV-B-32), EPA stated
that it considered the 7 percent factor to be reasonable for control
equipment, fans, and the air curtain secondary hoods, and so this factor
was applied to the capital cost estimate for this equipment to calculate
the maintenance and repair allowance.  However, EPA applied a lower
maintenance factor of 1 percent to the total estimated ductwork capital
cost to calculate the maintenance and repair allowance for the new
control system ductwork.  The EPA used a lower figure because it has
found that reasonable maintenance and repair costs for ductwork normally
are somewhat lower than the estimate provided by Kennecott.  Kennecott
responded in comments on the memorandum that the 7 percent estimate for
ductwork represents actual operating experience and should not be
rejected (IV-D-812).  The EPA believes, however, that its estimate is
reasonable and has retained it for the revised cost analysis.  In the
case of the Utah smelter, the decision has been made that secondary
emission controls would not cause a significant risk reduction, and a
higher annualized cost estimate would not affect this decision.  The
revised total operating cost estimate for both converter and matte and
slag tapping operations at Kennecott-Utah is $2.0 million per year, or
$1.0 million per year for each of the two operations.  The total annualized
cost for converter controls, therefore, is estimated at $2.0 million per
year, which includes a $1.0 million per year operating cost ($690,000/yr
at proposal) and a $1.0 million per year capital  recovery cost.

     Kennecott1s capital cost value for matte and slag tapping controls
was considerably higher than EPA's estimate, primarily because Kennecott's
figure included costs for new ductwork and increased fan capacity to
the baghouse.  The EPA's estimate at proposal assumed that only a
baghouse sized for a flow rate of 4,500 acmm (150,000 acfm) and costing
$1.8 million would need to be added into the existing capture system at
Utah (cost includes 200 feet of ducting).  Kennecott's baghouse cost
estimate was based on the assumption that matte and slag tapping controls
would result in a gas flow contribution of 11,300 acmm (400,000 acfm),
at a proportional cost of $3.1 million.  The EPA in its response
memorandum considered this baghouse flow rate capacity to be much
higher than necessary based on the configuration at the smelter, and
used an estimate for the maximum total flow through the local hooding
at the matte and slag tapping locations of 5,700 acmm (200,000 acfm).
This capacity allows one reactor to undergo matte and slag tapping
simultaneously or two reactors to undergo either matte or slag tapping
simultaneously.  Kennecott, in its comments on EPA's response memorandum,
maintained that its sizing of the new baghouse for a 11,900 acmm
(400,000 acfm) capacity was justified because there are times when both
reactors would undergo simultaneous matte and slag tapping, and during
such times a baghouse of this larger capacity would be required to meet
the control  requirements.  The company felt that EPA's estimate
reflected an unwarranted production restriction for the Utah smelter,
and that EPA had rejected Kennecott's figure without presenting any
supporting evidence.  After a consideration of Kennecott's arguments,

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 EPA  still  believes  that  its  assumption  reflects  a  reasonable,  efficient
 production  program  at  this smelter,  and has  retained  its  proportional
 baghouse  cost  estimate for matte  and slag  tapping  of  $2.16 million.   As
 stated  above,  the decision to  not require  converter secondary  emission
 controls  at the  Utah smelter (and to not impose  matte and slag  tapping
 controls  on any  smelter)  would not be affected by  increasing the control
 cost estimates.   (However, EPA would consider this issue  in more depth
 if a regulatory  decision  were  dependent upon this  cost  estimate.)

      The  EPA had  assumed  at  proposal  that  the fans and  ductwork from  the
 existing  matte and  slag tapping capture system would  be salvageable for
 incorporation  in  the new  control  system.   However, Kennecott's  cost
 estimates  indicated that  new ducting and fan capacity would be  required
 in the  new  system.  The EPA  has accepted the fan and  ductwork  costs
 totaling  $5.6 million, adding  this figure  to the baghouse cost  for
 EPA's revised  total capital  cost.  Therefore, EPA's revised estimate  of
 the  total capital cost to install  secondary  emission  controls on matte
 and  slag  tapping  operations  at Kennecott-Utah is $7.8 million.

      The  total annualized cost of matte and  slag tapping controls was
 calculated  as  for converter  controls, producing  a  capital recovery
 figure  of $0.9 million per year and  an  operating cost of $1.3 million
 per  year.   (The  EPA's  proposal  estimates were $0.2 million per  year
 capital recovery and $0.3 million  per year operating  cost.)  These
 revised figures are significantly  higher than the  proposal estimates
 principally because of the added  fan  and ductwork  costs that were not
 included  at proposal.  The total  of  these  estimates,  $2.2 million per
 year, is  EPA's revised annualized  cost  estimate  for the Kennecott-
 Utah  smelter.

      Comment:  Kennecott claimed  that when the corrected annualized
 control costs and annual  inorganic arsenic emission reductions  for its
 Utah  smelter are used  in the calculation of cost effectiveness  of
 smelter controls, the  figure for  secondary controls on converter
 operations  increases to $2 million/Mg controlled (from EPA's proposal
 estimate of $185,400/Mg).  The figure for  fugitive controls on matte
 and  slag tapping operations was estimated  by the commenter to be $1.72
 million/Mg  controlled  (versus  EPA's  proposal estimate of $302,400/Mg).
 The  company's annualized cost  estimate  was $2.8 million/yr for  converter
 controls and $2.9 million/yr for matte  and slag  tapping controls.   The
 emission reduction  resulting from these  controls would be 1.4 Mg/yr
 (converters) and 1.7 Mg/yr (matte and slag tapping) (IV-D-634).

     Response;  The EPA evaluated  Kennecott's estimates of the annualized
costs of control  and the arsenic emission  reduction at the Utah smelter
separately.  Section 4.2.1 discusses the revision  to  EPA's proposal
 estimate of baseline converter secondary emissions, from 8.0 to
 1.5 Mg/yr.  This change led to a smaller amount of emission reduction
due to NESHAP controls, from 7.0 to  1.4 Mg/yr.    The EPA's estimate of
the annualized cost of converter controls was revised after proposal,
as discussed in the previous response,  from $1.3 million/yr to
$2.0 million/yr.   These revised figures of 1.4 Mg/yr and $2.0 million/yr
 produce a revised cost per unit of emission reduction (for converter
controls) of $1.4 million/Mg.

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     Since Kennecott's comments did not address the emission reduction
effected by fugitive controls on matte and slag tapping operations, EPA
has retained its proposal estimate of 1.7 Mg/yr.  However, the annual-
ized cost of these controls was revised from $0.51 million/yr to
$2.2 million/yr, as discussed in the previous response.  These figures.
of 1.7 Mg/yr and $2.2 million/yr produce a revised cost per unit of
emission reduction (matte and slag tapping controls) of $1.3 million/Mg.
Table 8-2 summarizes the estimated annualized costs, NESHAP emission
reductions, and costs per unit of emission reduction discussed in this
response.

1-8.1.2.2  Hayden Smelter.

     Comment:  Kennecott provided its estimates of capital, operating,
and total annualized costs for best emission controls on converter
operations at its Hayden smelter, which were somewhat higher than
EPA's proposal  estimates.  The capital cost estimate was $8.0 million,
the operating cost estimate was $1.2 million per year, and the total
annualized cost estimate was $2.6 million per year.  These estimates
are in contrast to EPA's estimates at proposal  of $6.7 million capital
cost and $2.0 million per year annualized cost.  The cost items cited
by Kennecott were:  new air curtain secondary hoods on each converter,
new ductwork, a new baghouse, two new fans, and a new 61-meter (200-foot)
stack (IV-D-634).

     Response;   The commenter did not supply individual cost estimates
for each of the items, but only an estimate of total capital cost for
the entire control system installation.  Kennecott's capital cost
estimate of $8.0 million for converter secondary controls is 19 percent
higher than EPA's estimate at proposal ($6.73 million), and was accepted
as a reasonable estimate.  A revised figure for capital recovery
($940,000/yr) was calculated using EPA's basis of 10 percent interest
rate and a 20-year service life.  Kennecott's estimated operating cost
($1.2 million/yr) was accepted as reasonable and added to the revised
capital  recovery figure to produce a revised total annualized cost of
$2.14 million per year, 8 percent higher than EPA's estimate at proposal.

     1-8.1.2.3  MeGill Smelter

     Comment:  Kennecott provided estimates of the capital and
annualized costs to install and operate best emission controls on
converter and matte and slag tapping operations at its McGill smelter.
Kennecott estimated the capital  cost as $9.0 million, the operating
cost as $1.4 million per year, and the total annual ized cost as
$2.9 million per year.  These estimates of capital and total annualized
costs were 7 percent and 2 percent lower, respectively, than EPA's
cost estimates  at proposal for Kennecott-McGill.  Cost items cited by
Kennecott as being part of these total costs included converter air
curtain secondary hoods, new secondary hoods at matte and slag tapping
locations, new fans and ducting, a new baghouse, and new stack (IV-D-634)

     Response;   Kennecott's capital  cost estimate was not broken down
to apply to individual cost items, but was provided only as a single
total  figure.  Also, the company's cost estimates represent the total

                                 1-8-11

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Tabln,,f~™  ANNUALIZED  COSTS AND ARSENIC EMISSION REDUCTIONS
    DUE TO SECONDARY  EMISSION CONTROLS AT KENNECOTT-UTAH
Cost and
Emission
Parameters
Annual i zed Cost
(S iiilHon/yr)
Emission
Reduction
(Hg/yr)
Cost per Unit
of Emission
Reduction
(S million/Mg)
Operation
Controlled
Converter
Matte and Slag
Tapping*
Converter
Matte and Slag
Tapping*
Converter
Matte and Slag
Tapping*
EPA Proposal
Estimate
1.3
0.51
7.0
1.7
0.19
0.30
Kennecott
Estimate
After Proposal
2.8
2.9
1.4
1.69
2.0
1.72
EPA Revised
Estimate
2.0
2.2
1.4
1.7
1.4
1.3
                                          operations are "ot
                        1-3-12

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 costs for secondary controls  on  both converter  and  matte  and  slag
 tapping operations,  with  no breakdown of the  individual costs  applicable
 to these two types of controls.   To compare Kennecott's estimates  to
 EPA's estimates  at proposal,  and to assess whether  revisions  to  EPA's
 estimates were appropriate as a  result of the company's comments,  EPA
 separated Kennecott's cost estimate totals into individual  estimates
 for converting operations and for matte and slag tapping  operations.

      As a first  step in this  process,  a value for capital recovery
 was calculated using EPA's basis of 10 percent  interest rate and a
 20-year service  life.  For this  calculation,  Kennecott's  $9.0  million
 capital  cost estimate for all  controls was accepted by EPA  as  being
 reasonable (7 percent lower than EPA's estimate at  proposal).  Since
 Kennecott's estimated annual  operating cost of  $1.4 million per year
 for all  controls was also determined to be reasonable, the  calculated
 capital  recovery figure of $1.06 million per  year was added to this
 operating cost to  produce a revised total annualized cost for  all
 controls of $2.5 million  per  year.

      In  order to apportion the revised annualized cost between
 converter secondary  controls  and matte and slag tapping fugitive
 controls,  EPA retained its proposal  estimate  of $257,000  per year
 as the incremental  total  annualized cost of matte and slag  tapping
 fugitive controls.   This  value was  subtracted from  the revised
 annualized cost  estimate  for  all  controls, producing an annualized
 cost for converter  secondary  controls  only of $2.2  million  per year.

      The revised annualized cost calculated for converter secondary
 controls is  18 percent lower, at $2.2  million per year, than EPA's
 proposal  estimate of $2.7 million per  year.  The same annualized cost
 estimate for  matte and slag tapping  controls of $257,000 per year
 assumed  at proposal  is retained  in  this  updated  cost analysis.  {As
 indicated  in  previous  responses,  controls on fugitive emissions from
 matte  and  slag tapping are not required  in the  final MESHAP.)

 1-8.1.3   Phelps  Dodge  Smelters

      1-8.1.3.1  Morenci Smelter

     Comment:  Phelps  Dodge claimed  that the capital and annualized
 costs of  installing  converter secondary emission controls  at the
Morenci  smelter were underestimated by EPA at the time of proposal.
The company felt that  EPA's estimates did not take into account the
 individual differences among smelters.  Phelps Dodge provided  a capital
 cost estimate of $16.9 million, in contrast to EPA's estimate  of $8.5
million,.to install  controls to meet the proposed NESHAP at the Morenci
 smelter.  This figure  for  controls on five converters includes
$7.5 million for structural  steel, ducts, and fans;  and $9.4 million
 for a gas treatment plant  (ESP's and lime spray  pretreatment) .sized for
three cpnverters blowing  concurrently.  The company  said this  estimate
would increase if a waste  handling system were included,  or  if space
and power constraints proved to be a problem.  Annualized  costs were
estimated by Phelps Dodge  to  be about $5.8 million per year, versus
EPA's $1.9 million  per year  figure.   This estimate consists  of an

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  annual  operating  cost  of $2.9  million  per year  and  a  cost  of  capital  of
  $2.9 million  per  year  (IV-D-640).

      Response:   In order to assess  the  reasonableness of the  Phelps
  Dodge cost estimates for the Morenci smelter, EPA requested a further
  cost breakdown  in a request for  information sent to Phelps Dodge after
  proposal  (IV-C-417).   Phelps Dodge  supplied a capital cost breakdown
  for the actual  costs the company had incurred in installing a secondary
  hood on the No. 7 converter at Morenci  (IV-D-785).  The company pointed
  out that  the design of this hood is similar to  air curtain secondary
  hood systems in its requirement for extensive modifications to existing
  duct and  fan equipment.   Thus, Phelps Dodge indicated that a  requirement
  for air curtain secondary hoods on the converters at Morenci would mean
  that the  existing secondary hooding system would have to be demolished.
  This is in contrast to EPA's assumption at proposal  that the existing
  fans and  ductwork at Morenci would be salvageable for use in a new air
  curtain secondary hood system.   Since the capital costs for the secondary
  hood installed at the Morenci  smelter are actual expenditures incurred
  by Phelps Dodge and the costs  appear reasonable, Phelps Dodge's capital
 cost estimate of $7.5 million  for air curtain secondary hoods on five
 converters at Morenci was used  by EPA in updating its cost estimate.

      Phelps Dodge's other capital  cost component of $9.4 million covers
 the cost of the gas treatment  part of the control system.   The company
 has assumed that a lime injection system to  control  SO? would be required
 and has further assumed that an ESP fabricated of stainless steel  would
 be needed to  minimize corrosion problems.  These systems were considered
 necessary by  Phelps  Dodge because its  studies  showed a predicted acid
 dewpoint of 146°C (294°F) for the converter  fugitive gas stream  at
 Morenci.  The  EPA reviewed the  information  provided  and found  that  the
 predicted acid  dewpoint was  greater than the  reported  operating  tempera-
 ture  during the tests  (IV-D-785).   Owing to the  absence  of  any
 statements regarding  actual  corrosion  problems with  the  fugitive  gas
 system  ductwork at Morenci and  the  possibility for in-situ  formation
 0fK3^  ?ult*te durin9  these tests>  EPA concluded that the  information
 submitted  did not  demonstrate the  need  for corrosion-resistant
 materials  and  lime injection.   Furthermore, EPA  has  observed converter
 secondary control  systems at two  smelters  (ASARCO's  Tacoma  and El  Paso
 smelters), and  has not  found acid-based  corrosion to be  a problem  in
 these systems.   These observations  have  been confirmed in recent conver-
 sations  with ASARCO representatives  (IV-E-80,  IV-E-81).  Concentrations
 of  sulfur  dioxide  are moderate  (several  hundred  to several  thousand
 ppm), and  the moisture  content  and  gas  temperature are near ambient
 levels.  These  gas stream characteristics are similar  to the character-
 istics reported  for the converter fugitive gas system at Morenci.   For
 this reason, EPA believes  that  the converter secondary control system
 can be operated safely above the acid dew point  temperature of the gas
 stream,  so that the expensive lime-injection and corrosion-resistant
 ESP system would not be necessary.  The capital  costs of a baghouse and
a carbon steel  ESP sized  for this system were compared, with the object
of applying the higher of  the two costs to EPA's  revised total capital
cost estimate for this system.   This was done so  that the presumed
 worst case" costs for this facility would be considered in the
Agency s determination of the reasonableness  of controls.  Since an ESP

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fabricated of carbon steel  would cost approximately $2.5 million
(IV-E-65), EPA applied its  proposal  estimate for a fabric filter of
$5.47 million to the calculation of total  capital  cqst.   This fabric
filter cost is added to the estimated cost for five air  curtain
secondary hoods, producing  a revised total system cost estimate of
approximately $13.0 million.  In summary,  the revised capital cost
estimate is higher by $4.5  million than EPA's estimate at proposal.
The largest part of the difference is attributable to demolition and
replacement of existing ductwork.

     As with the cost estimates for the smelters discussed earlier in
this section, EPA calculated the capital  recovery figure from this
revised capital  cost estimate assuming a 10 percent interest rate and a
20-year service life (capital recovery factor 0.1175).  The resulting
capital recovery figure of $1.52 million per year is considerably lower
than the Phelps Dodge estimate of $2.88 million per year, which was
based on a $16.9 million capital cost and  an assumed 15  percent interest
rate and a 15-year service  life.  Phelps Dodge's estimate for electric
power costs ($1.32 million/yr) was adjusted to apply to  a baghouse
rather than an ESP, producing an estimate  of $1.22 million per year.
Maintenance costs were calculated by Phelps Dodge as 5 percent of
capital ($844,000 per year), and operating labor was estimated at
$35,000 per year.  These assumptions for the cost of maintenance and
operating labor were accepted by EPA for its revised estimate, yielding
a lower figure for maintenance and operating labor (based on the lower
total capital cost) of $683,600 per year.   Therefore, after considering
the comments of Phelps Dodge on the cost estimates made  by EPA at
proposal, a revised annualized cost estimate for converter controls at
Phelps Dodge-Morenci of $3.43 million per year has been  calculated.
This figure is about $1.5 million per year higher than EPA's proposal
estimate.  The difference is attributable mainly to higher capital
recovery (due to higher capital cost) and to higher costs to operate
and maintain the system than previously estimated.

     Comment:  Phelps Dodge commented that when the company's estimates
for annualized control costs and annual arsenic emission reductions for
its Morenci smelter are used to calculate  the cost effectiveness of
NESHAP converter controls,  the resulting figure of $21 million/Mg
controlled is well beyond the upper limit of $700,000/Mg cited by EPA
as an approximate cutoff above which controls would not  be reasonable.
The company claimed that the annualized cost of these controls would be
approximately $5.8 million  per year (see previous comment), and that
fugitive arsenic emissions  from the converters would be  reduced by
0.035 kg/h (0.078 Ib/h) or 0.30 Mg/yr (0.33 tons/yr) (IV-D-640).

     Response:  As discussed in previous comments, EPA has evaluated
the company's estimates and made adjustments to the figures used at
proposal to judge the reasonableness (cost of operation  versus emission
reduction achieved) of converter controls.  After evaluating Phelps
Dodge's basis for its annualized cost estimate (previous response), EPA
increased its estimate beyond the estimate at proposal by 80 percent to
$3.43 million per year.  In its response to the comment by Phelps Dodge
on arsenic emission rates from the Morenci smelter (Section 4.3.1), the
Agency lowered its proposal estimate of baseline converter secondary

                                 1-8-15

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 emissions, and  hence the amount of emission reduction calculated to
 be achievable through the use of NESHAP controls on converter
 operations.  The EPA's revised emission reduction estimate is
 1.7 Mg/yr, as opposed to its estimate at proposal of 6.3 Mg/yr.  These
 figures of $3.43 million/yr annualized cost and 1.7 Mg/yr arsenic
 emission reduction were divided to obtain a revised EPA estimate of
 $2.02 million/Nig of arsenic controlled.

      Table 8-3  presents the converter secondary control costs estimated
 by EPA at the time of proposal, cost estimates provided by commenters
 after proposal, and current EPA estimates for these costs revised as
 a result of public comments.  All estimates are higher than at proposal,
 with the exception of the Kennecott-McGill  costs,  which are lower by
 about 18 percent.

 1-8.1.3.2  Ajo Smelter

      Comment:   Phelps Dodge felt that the costs of installing and
 operating a system to cool  the reverberatory furnace offgases and
 collect inorganic arsenic at the Ajo smelter would be prohibitive,  with
 a capital cost of about $3.0 million and an annualized cost of
 $5.0 million per year.   The EPA had discussed in the preamble to the
.proposed standards (48 FR 33140)  the possible need to consider this
 control  option for Phelps Dodge-Ajo,  should specific changes to the
 reverberatory  furnace (conversion to oxy-sprinkle  smelting)  and the
 installation of acid plant controls not be  carried out under a consent
 decree with the State of Arizona.   The EPA's cost  estimates  at proposal
 for this option were $1.5 million capital cost and $1.6 million per
 year annualized cost.   Phelps  Dodge did not provide a  breakdown of  its
 cost estimates (IV-D-640).

      Response:   In order to evaluate  the cost estimates  submitted by
 Phelps Dodge after proposal, EPA  requested  a breakdown  and  rationale
 for these estimates in  an information request sent to  the company
 (IV-C-417).  Phelps Dodge responded with an  itemized  cost breakdown
 indicating capital  costs  totaling about $3.6 million and an annualized
 cost of  approximately $3.6  million  per year  for  the  items considered
 necessary by the company  for this control installation  (IV-D-790).
 Capital  cost items  included an evaporative  cooler,  fiber glass  ducting,
 a  stainless  steel  ESP with  lime spray,  and  flue  burners  for offgas
 reheating.  Annualized cost components included  water, electrical
 power, and natural  gas;  lime treatment;  labor  and maintenance  costs;
 and  capital recovery costs  (at 17.1 percent).  The  company stated that
 these  cost estimates were conservative because they did not consider
 several  items, including  demolition of existing  equipment, costs  of
 electrical and mechanical equipment and  structural  steel for  the  cooler
 engineering costs,  and the costs for a sludge and/or dust treatment
 plant.

     The EPA has addressed in Section  1-6.2  the  issue of applying the
 option of cooling gas streams to increase arsenic collection.  As
 discussed in the first response, the Agency is not presently in a
 position to make a  final determination concerning the technical feasi-
 bility of cooling gas streams to various temperatures without creating

                                 1-8-16

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             Table 8-3.   COST ESTIMATES FOR CONVERTER SECONDARY  ARSENIC CONTROLS
Capital Cost Estimates ($1,000)
Smelter
ASARCO-Hayden
ASARCO-E1 Paso
Kennecott-Utah
Kennecott-Hayden
Kennecott-McGm
Phelps Oodge-
Morend
EPA
Proposal
1.700
1,375
5,200
6,730
8,760
8,530
Company
Comments
3,600
1,850
3,800
3,000
9,000*
16,900
EPA
Revised
3,660
1,850
3,800
3,000
7,150
12,970
Annuallzed Cost Estimates (Sl.onn/vr^
EPA
Proposal
408
307
1,300
1,980
2,700
1,910
Company
Comments
1,350
727
2,800
2,600
2,900*
5,800
EPA
Revised
798
379
2,028
2,140
2,200
3,430
*These cost estimates submitted by Kennecott are for secondary emission  controls on both


 £nnin?rn°Pe£t10nS an<1 "***• J1* s^g  ^P"1"9 °P«™t1ons.  Controls on  matte anS slag
 tapping operations are not required under  the final regulation; see Section  1-1 l
                                         1-8-17

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 a corrosion  potential,  or to accurately predict the  amount of  arsenic
 reduction  that can be expected  in  various  control  situations.
 Section  1-6.2 also reviews the  Agency's estimate of  the  health risk
 associated with the smelting furnace  process  stream  at Phelps  Dodge-
 Ajo.   Table  6-2 indicates that  a very low  annual  cancer  incidence  is
 estimated  to result from this particular emission  stream due to
 inorganic  arsenic (0.0034 incidence per year).   Thus,  even if  all  of
 the arsenic  in this gas stream  were collected before its release to the
 atmosphere,  the reduction in risk  would be so small  as to make this
 control  option'unreasonable.

      For these reasons,  EPA is  not now requiring that gas stream
 cooling  be utilized at the Ajo  smelter to  reduce inorganic arsenic
 emissions.  Also,  in light of the  uncertainty associated with  this
 issue, and since this option would not be  selected regardless  of the
 estimated  costs to implement it, the  Agency is  retaining the control
 cost  estimates developed at proposal  rather than accepting Phelps
 Dodge's  higher estimates.

 1-8.2 COMMENTS ON ECONOMIC IMPACTS

 1-8.2.1  Basis for Economic Analysis  Unexplained

      Comment:   The State of New York  commented  that  EPA's  use  of cost
 considerations is  totally unexplained.   The comments specifically
 noted that EPA did not  indicate what  level  of economic hardship was
 considered sufficient to preclude  regulation, what standards of review
 are used,  and  what financial  information was  considered.   The  commenter
 said  EPA has apparently  accepted wholly  and on  faith the general asser-
 tions of economic  vulnerability made  by  industries in  the  source
 categories the Agency has decided  not to regulate  (IV-D-698).

      Response:   Historically, in the  case  of  nonthreshold  pollutants,
 when  complete  elimination of  a  pollutant is not  practical,  EPA  has used
 cost  considerations  as one  of several   decision tools.  In  this regulatory
 development, no specific level  of  economic  hardship  was  used as a
 criterion.   However,  EPA did  investigate all  of  the  technologies felt
 to be effective from an  engineering standpoint.  The EPA does  not
 accept wholly  and  on  faith  general  assertions of economic  vulnerability
 made  by  industries in the  source categories under investigation.  On
 the other  hand,  EPA  did  not wholly reject  information  merely because it
 was provided by industries  in these source  categories.  Within the time
 and resource constraints  in effect, EPA actively sought  information
 from  any and all parties  likely to have  specific and relevant economic
 and financial  information, and  undertook independent analyses of economic
 impacts.  A  partial  list of information sources that were used includes
 the following:   direct contact with many of the affected plants and
 companies;  contact with  trade associations; a review of  corporate
 annual reports  and reports  to the Securities and Exchange Commission
 (SEC  Form  10-K); review  of  independent cost studies of the  copper
 smelting industry; a review of reports by other government offices,
 such as OSHA; a  literature review of trade publications,  and so forth.
Also,  notices in the Federal Register  and the public comment period(s)
                                 1-8-18

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are additional means that assist in soliciting specific and relevant
information from interested parties.

     The EPA believes that projections are a reasonable means of deter-
mining the economic impact of controls.  Furthermore, the alternative of
making decisions on appropriate control levels in the absence of any
information on the economic and related community consequences is, in
the Administrator's judgment, unreasonable.

1-8.2.2  Insufficient Economic Data

     Comment:  The Sierra Club stated that the proposal should include
sufficient economic data for the public to judge the economic feasibility
and costs of controls, including income figures for all operations at a
smelter such as gold and silver production.  In addition, the actual
costs of plant closure should be detailed for each smelter and compared
to benefits, (e.g., health cost savings) (IV-D-608, IV-F-1, IV-F-2).

     Response:  All of the costs that have been accumulated must be
estimates of future outlays.  These include labor costs which are
subject to union negotiation, utility costs which are subject to public
utility commission regulation, and taxes which change according to
governmental budgets.  Even income from precious metals is subject to
arbitrary allocation among mine, smelter,  and refinery.  Furthermore,
the financial health of the industry depends heavily on the price of
copper, which changes from day to day.

     Shutdown costs are even more variable.  They depend upon union
contract provisions, the generosity of the company over and above
contract considerations, and the geographic location of the plant.  (A
company with a small plant in a large city could be considered to have
less of a "moral obligation" than if the plant were the primary support
for a small, isolated community.)

     In short, costs cannot be estimated with complete accuracy.
Nevertheless, in the interim since proposal the accuracy of EPA's cost
estimates has been considerably improved.   The economic impacts on the
industry based on the revised cost estimates are discussed in
Appendix F.

1-8.2.3  Economic Impacts Versus Health Risks

     Comment:  The Chemical Manufacturers  Association (CMA) commented
on EPA's consideration of economic impacts in assessing the accepta-
bility of residual risks after application of BAT.  The CMA stated that
the language of the July 20, 1983,  Federal Register notice implied that
the only economic impact EPA is prepared to consider at this point is
closure.   The CMA thought that this was an unduly restrictive approach
and that EPA is not justified in requiring large expenditures to  achieve
negligible reductions in health risk.   Consequently, they recommended
that EPA consider a broader range of economic impacts in the analysis
(IV-D-617).
                                 1-8-19

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      Response:   The EPA agrees,  in general,  with CMA that large
 expenditures are not justified when public health risk  is low and
 when the ability to reduce the risk is limited.   In  the case of certain
 facilities,  however, EPA believes that the magnitude of estimated risk
 warrants the implementation of affordable controls that can signifi-
 cantly reduce public exposure  to inorganic arsenic emissions.   Both  the
 proposed and final  standard are  based on the best emission controls
 that are available  and can be  applied without causing plant closure  or
 imposing costs  that far exceed any public health benefit.  A number  of
 considerations  were weighed by EPA in selecting  the  level of the
 proposed standard.   Among these  factors was  the  economic impact of
 further reducing the risks.  The preamble to the proposed standards
 addressed only  the  closure impact since that was the principal
 anticipated  impact  of the identified  beyond  BAT  controls.

      As previously  discussed,  following proposal  EPA revised its
 estimate of  emissions and control  costs at the 14 primary copper
 smelters and reassessed the economic  impact  of the control  costs.  The
 standard was selected considering the magnitude  of the  risks,  the
 costs and availability of further controls and the associated  risk
 reduction potential,  the  environmental  impacts,  and  the potential
 societal  impacts of the alternative control  measures.   Consequently,
 EPA  believes that the standard does not impose control  costs that are
 disproportionate to the risk reduction  achievable.

 1-8.2.4  Financial  Relief for  Affected  Groups

      Comment:   The  Sierra Club also recommended  that EPA consider
 requiring capital investment set-asides which would  be  available for
 smelter capital  improvements when  EPA re-examines  BAT requirements
 after 5 years.   This  would provide smelters  that  otherwise  could not
 afford required  controls  with  a  means of maintaining BAT controls on
 their operations (IV-F-1,  IV-F-2).  The  NRDC suggested  that  some form
 of financial  relief be established to assist communities  that are at
 particular risk  from  smelter arsenic  emissions (IV-F-1).

      Response:   The capital  investment  set-aside  concept appears to be
 similar to the Superfund  monies  used  for  cleaning up hazardous waste
 sites.  However,  the  Superfund was established by an Act  of Congress
 and is  dispensed as needed to  clean up existing sites.  Since there are
 no statutes  governing  capital  investment  set-asides  for  future air
 pollution control,  the  principle cannot be enforced.   Even if it were
 enforceable,  there  is  no way to  determine  the size of the payments to
 be set aside.

     Heretofore, governmental  financial relief has taken  the form of
 removing hazards by digging up contaminated soil  or  relocating the
 residents of  the area.  In the case of air pollution, financial relief
actions are not  clearly definable and funds, private  or public, are
better spent for control of emissions.
                                 1-8-20

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                          1-9.0  COMPLIANCE PROVISIONS
 1-9.1  PANEL APPROACH
      Comment:  ASARCO and Phelps Dodge felt that the panel approach to
 secondary hood performance optimization suggested by EPA in the proposal
 preamble would be costly and time-consuming, and would likely lead to
 disputes.  The companies themselves would naturally want the hoods to
 work well and therefore should be allowed to develop hood operating
 parameters on their own through trial and error.  A list of proposed
 operating parameters could then be submitted to EPA for its approval.
 If,  however,  EPA decides to go ahead with this approach,  the panel
 should contain at least one neutral member to aid the panel in reaching
 agreement (IV-D-620, IV-D-640, IY-F-1, IV-F-2).

      Response:   The potential  use of a panel of observers to evaluate
 hood performance was discussed in the July 20,  1983,  Federal  Register
 notice of proposal  (48 FR 33148).  It was suggested that the panel could
 be composed of three or more persons, including representatives of
 industry, EPA,  and  a local  air pollution  control agency.   The mission
 of this panel  would be straightforward, to assist in  the  optimization
 of a new air  curtain secondary hood's operation, through  observations
 of the hood under various operating conditions.

      The Administrator believes that visual  observations,  although
 subjective, are the most effective way to assess an air curtain hood's
 overall  performance.   This  method is relatively quick,  inexpensive,  and
 uncomplicated  compared to alternative techniques such  as  the  tracer
 mass balance  technique.   The requirements of the standard  do  not preclude
 an owner or operator's conducting studies or performing assessments  on
 the  best operation  of an air curtain secondary  hood.   In  fact,  the
 Administrator  believes that such  studies  would  likely expedite  EPA's
 own  evaluation  of the hood's performance.   However, the final operating
 conditions  should be  determined by the Agency because  the  optimization
 process  is a  further  step in the  development of  the regulation.   This
 part of  the regulation cannot  be  established until  the  equipment required
 under  the standard  is installed and  operating.   The specific  requirements
 that will establish  optimum  capture  of converter secondary  emissions
 will  then be proposed in  the Federal  Register and established after
 consideration of  public  comments.

     The  suggestion of these commenters that the members of the  panel
 would  likely be biased  (and  presumably make  substantially different
 observations as a result of  this  bias) is not considered a  reasonable
 one  by the Agency.  The Administrator would  consider any significant
 discrepancies among observers,   should  they occur, in selecting  the
 optimum operating conditions.   Past experience at ASARCO-Tacoma  indicates
 that the  observations of two observers were  in close agreement,  and EPA
does not  foresee  that  the observations of three  (or more) persons
would be  likely to vary significantly.  In the proposal for public
 comments, the  various  individual observations will be discussed,
providing an opportunity for commenters to state objections concerning
any discrepancies.

                                     1-9-1

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     in summary, EPA still considers the visual observations approach
to hood operational optimization the preferred method, although
this could be carried out either by EPA personnel alone or by
a group from various organizations.

     Comment:  NRDC and USWA expressed their support for the panel
approach, but felt its makeup and function should be expanded.  To
assure balance with respect to the interests represented on the panel
as proposed  (representatives of industry, EPA, and local, air pollution
control agencies), the size of the panel should be increased to include
a representative of the employees and of the public.  Also, the addi-
tional functions of assisting in enforcement and helping to identify
additional control opportunities would be useful additions to the
panel's charter.  The members of the panel from the public and the
union should be compensated for their participation, at least to cover
expenses  (IV-D-708, IV-D-710).

     Response:  The Administrator considered the suggestion to
enlarge the size and expand the charter of the proposed panel , and
determined that this would be beyond the scope of EPA's intentions
when it suggested the panel approach.  The panel was not intended
as an advisory committee, but as a temporary group convened to
accomplish a specific short-term goal.  As stated in the previous
response, EPA views the establishment of operating conditions for air
curtain secondary hoods as part of the regulatory development.  After
examining the options available for accomplishing this end, the Agency
concluded that a group of limited size with a limited mission would be
the most  expeditious means of establishing the best control of converter
secondary emissions at smelters with high potential  arsenic emissions.
Since there will be opportunities for all interested parties to examine
and comment on the proposed optimum conditions for each regulated
primary copper smelter, it is not necessary to enlarge the group and
risk losing efficiency while adding to the expense of the process.

     The  EPA further believes that the functions of enforcement and
identification of control  opportunities should be retained by the
Agency.   Opportunities for control  are determined during development of
the regulation and in subsequent reviews, with sufficient opportunity
for dialogue with concerned parties.  Also, EPA feels it can enforce
the provisions of the regulation at the limited number of facilities
without deputizing other parties.  Since the panel  may contain a
representative of the owner or operator of the facility, an enforcement
role would be inappropriate.

1-9.2  OPERATION AND MAINTENANCE REQUIREMENTS

     Comment:  The Washington State Department of Ecology (DOE)
recommended that requirements for good operation and maintenance for
process controls be included in the final  regulation (IV-D-622).

     Response:  The EPA is in agreement with DOE and' believes that
requirements for maintaining process, conveying, and emission control
equipment in a condition that will  optimize control  of emissions would
be an important feature of the final  regulation.   Therefore,  the final

                                     1-9-2

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standard regulating existing and any new primary copper smelters  (and
arsenic production facilities;  see Section II-2-3),  contains provisions
requiring operating and maintenance practices that will minimize
inorganic arsenic emissions.
                                 1-9-3

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                     1-10.0  TEST METHODS AND MONITORING

1-10.1  PROPOSED METHODS 108 AND 108A

1-10.1.1  Method 108 More Appropriate for Measuring Arsenic

     Comment:   The New Jersey Department of Environmental  Protection
(NJDEP} commented that EPA Reference Method 108 would be a more appro-
priate method  than Method 5 for evaluating emission controls or
compliance with the standards.  The NJDEP noted that Method 5 might not
measure all arsenic emissions since part of the material will be in the
vapor phase in a hot gas stream.  The commenter also recommended that
the material collected in the impingers in the Method 5 train (back-
half catch) be included in the measurement to obtain a valid measure of
total arsenic  emissions (IV-D-641).

     Response:  The commenter1s recommendations for measuring inorganic
arsenic concentrations incorrectly imply that the standard requires a
determination of total arsenic emissions.  The standard for the
collection of secondary inorganic arsenic emissions from primary copper
smelters is based on a total particulate concentration limit, not an
inorganic arsenic limit.  At proposal, EPA considered developing an
emission limit specifically for inorganic arsenic and recognized several
difficulties in developing such a standard.  A numerical emission limit
specifically for inorganic arsenic would have to account for the potential
variability in the inorganic arsenic content of secondary emissions at
copper smelters.  An inorganic arsenic emission limit would only establish
an upper limit on inorganic arsenic emissions; hence, an inorganic
arsenic limit based on current data might not require application of
the best emission controls if other ore concentrates were processed.
Although a percent reduction format would require the application of
best controls  regardless of the level of inorganic arsenic in the feed
materials, high collection efficiency might not be continuously achievable
for the entire range of inorganic arsenic concentrations that could
occur in captured secondary emission gas streams.

     In contrast, there are several advantages to using a total parti-
culate emission limit to regulate inorganic arsenic emissions.  First,
total particulate emissions from primary copper smelter operations
remain relatively constant regardless of the inorganic arsenic content
of the ore concentrate; thus, a total particulate emission limit would
require the use of best emission controls for all ore concentrates
regardless of variations in the fnorganic arsenic content of the feed.
Second, Method 5 can be used to determine compliance.  Method 5 is a
simple, well understood test method, and testing groups already are
equipped to apply this method to gas streams at copper smelters.  For
these two reasons, EPA developed the standard for collection of inorganic
arsenic emissions based on a total particulate emission limit.  Since
determination  of compliance requires measurement of total  particulate
matter, the commenter's suggestions concerning the measurement of
inorganic arsenic have not been incorporated into the final standard.
                                 1-10-1

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  1-10.1.2   Problems With Methods  108 and  108A

      Comment:  ASARCO and Phelps Dodge commented that there are
  several problems with proposed Reference Method 108, Determination
  of Participate and Gaseous Arsenic Emissions, and Method 108A, Deter-
  mination of Arsenic Content in Ore Samples from Nonferrous Smelters
  (IV-D-620, IV-D-640, IV-F-1, IV-F-2).  They felt that sampling methods
  currently  used by the two companies should be accepted by EPA as
  equivalent methods.  The Texas Air Control Board (TACB) also felt that
 Method 108A presents problems.  The following discussion lists the
  problems the commenters believe to be associated with the Methods.

      1.  The sampling train used in Method 108 contains impingers for
  the collection of S02,  with analysis performed using sodium hydroxide
 and a phenophthalein indicator.  This technique is different from the
  traditionally used Method 6, which requires titration with a standard
 barium solution to a thorin indicator end point.   ASARCO felt that
  this new method for sampling S02 had not been adequately field-tested,
 and would likely be an  inaccurate measure of S02  content in the arsenic-
 containing gas stream.   This S02 sampling method  should not be included
 until its accuracy has  been verified.

      2.  The use of a Parr Digestion Bomb in Method 108A to dissolve
 arsenic in samples of matte and slag presents several problems.
 First,  the price of $150 for the bomb  introduces  unnecessary expense
 into the Method.   Second,  the  bomb  must be sealed and accurately
 heated  for 2 hours,  which  is much longer than the digestion period
 in a method currently in use at ASARCO,  which does  not utilize the
 bomb.  Finally,  there are  very  real  safety hazards  associated with the
 Method  and, in fact,  explosions have occurred during its  development.
 This explosion potential appears to  be  related to the use of a
 cellulose  filter in  place  of a  glass fiber filter.   ASARCO  suggested,
 and Phelps Dodge  endorsed,  an alternate  method that does  not require
 the digestion  bomb,  takes  only  20 minutes,  and is safe.   The  TACB
 commented  that the  digestion bomb presents a  safety  hazard  due  to  acid
 under pressure,  and  small  sampling programs might find  that the
 purchase  of multiple  bombs  presents a cost burden  (IY-D-153).

      3.  The atomic absorption  spectroscopy technique (AA)  required in
 both  Methods is  not accurate for  the analysis  of arsenic  in  copper
 Acno^ntrates Contairn'n9 more than 4 percent arsenic,  which  occurred at
 ASARCO-Tacoma.  The ASARCO representative  suggested  a protocol that
 his  company uses  for analyzing  concentrates with relatively high
 concentrations of arsenic  (greater than 2  percent).   The  commenters
 also  pointed to a discrepancy between the  form of AA  used in each of
 the Methods, graphite furnace AA  in Method  108A and arsine generation
 AA  in Method 108.  It was felt  that the two methods should agree in
 terms of the AA method specified, or preferably, that a laboratory
 be allowed  to evaluate and choose the AA technique that best fits
 its sample  matrices and budget  (the graphite furnace accessory is
 four  times  the cost of arsine generation equipment).  The reference
 solution produced in the Methods may not be fully oxidized to the
 pentavalent arsenic necessary for accurate analysis; a technique to
assure full oxidation should be provided in the Methods.  Finally,

                                 1-10-2

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 AA techniques have been found to suffer from interferences in these
 applications.  An alternative procedure to AA was suggested by ASARCO,
 claimed to be less expensive and to have fewer interference problems
 than AA procedures.

      Response:   Since the emission standard for primary copper smelters
 is stated in terms of total  particulate matter, Method 108 for determi-
 ning arsenic emissions applies at this time only to glass manufacturing
 plants (to which an arsenic  emission limit for glass melting furnaces
 applies).  The  S0£ collection and  analysis requirements in Method 108
 have been deleted.  Method 108A for determining the arsenic content of
 ore samples will apply to analysis of matte and slag samples at primary
 copper smelters.

      In Method  108A, two of  the three factors involved in using the
 Parr digestion  bomb (cost and sample dissolution time) are not
 considered to represent excessive  problems.   The price of the digestion
 bomb should not represent an intolerable expense since its cost is  a
 relatively small proportion  of the total  sampling and analytical
 equipment costs.  The problem of an explosion potential  when using
 cellulose filter paper is unique to Method 108 which is not applicable
 to primary copper smelters.   Since little or no arsenic is present  in
 the insoluble particulate matter in emissions from glass furnaces,  the
 digestion procedure was  eliminated from Method 108.

      For samples containing  more than 4 percent arsenic,  acceptable
 accuracy with the AA can be  obtained by appropriately diluting the
 sample (ASARCO's Tacoma  smelter, recently closed,  was the only smelter
 that processed  concentrates  with this level  of arsenic).   Method
 108A has been modified since proposal  to  allow the tester the  option of
 choosing1 between a graphite  furnace and an arsine  generator  for  the
 analysis.   The  potential  errors  that could result  in  the  reference
 solutions because of incomplete  oxidation  of arsenic  to  the  pentavalent
 state  have  been  eliminated by  a  requirement  for  the  stock reference
 solution to  be  heated after  introduction  of  the  acid.  Methods  108  and
 108A require  a mandatory check  for matrix effects  using  the  method  of
 standard additions.   If  this  check  reveals matrix  interferences,  then
 all  samples  must be  analyzed by  standard addition  to  compensate  for
 this difference.

     The  alternative  analytical  procedure recommended  by  ASARCO may be
 potentially approvable as an alternative method.   If ASARCO wishes  to
 use  their recommended alternative  procedure, a clear, easy-to-
 follow,  description  of the procedure  should be submitted  along with any
 rationale or  data  necessary  to show  the validity of the alternative
 method in the particular application.   (The specific information needed
 for evaluation of  the protocols was described  in a letter  to ASARCO
 [IV-C-487J.  After the information  is submitted EPA will evaluate the
 suggested procedure.)

 1-10.1.3  Misprint

     Comment: The last line  of paragraph 5.1 of Method 108A should
read "mg/g," not "g/g" (IV-D-145).

                                 1-10-3

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      Response;
 proposal.
The last line should read "g/g"  as appeared in the
 1-10.2  PROPOSED OPACITY MONITORING REQUIREMENTS

      Comment:   ASARCO and Phelps  Dodge  felt  that  transmissometers
 as  proposed  In §61.176 (§61.175  in  final  regulation)  to  continuously
 measure  outlet stream opacity would not provide a reliable  way  to
 monitor  compliance with the emission limit.   The  commenters  discussed
 several  factors that  argue against  the  use of continuous  opacity moni-
 toring.   First, the accuracy of  these readings depends heavily  on  the
 size  distribution  of  the particulate matter  in the gas stream,  and this
 distribution may vary due to the  blending of gases from  various sources,
 without  the  mass concentration being significantly affected.  Also, the
 opacity  level  to be monitored would generally be  near the lower detection
 limit of the instrument.   ASARCO  referred to frequent maintenance
 problems it  has had with its existing transmissometers.   The  commenters
 suggested the  alternative of keeping control  equipment maintenance
 records  and  performing annual  Method 5  source sampling audits to verify
 compliance (IV-D-620, IV-D-640,  IV-F-1, IV-F-2).

      Response;   As discussed in the preamble to the proposed  standards
 (at 48 FR 33149),  the purpose  of  continuously monitoring  the  emission
 gas streams  is  to  ensure that the equipment  used  to control arsenic
 emissions is properly operated and  maintained to  meet the emission
 standards.   Records from  opacity  monitors would thus  serve as an
 indicator that  the control  equipment was operating as it  was  designed
 and had  operated during  a successful  performance  test.  The opacity
 records  cannot, however,  be  used  to  determine the  compliance  status of
 a source with  respect to  a  numerical  emission limit.  An  emission
 stream showing  a chronically high opacity level would be  a candidate
 for a  Method 5  test to  verify  its compliance status.  The suggestion of
 an  annual  Method 5  test  as a  replacement for opacity monitoring is  not
 considered an acceptable  alternate,  primarily because 1 year  is too
 long a period to wait for  information on the  operating and maintenance
 status of the control  equipment.  More  frequent Method 5  tests  would be
 expensive  as well  as  an  inconvenience for a  facility.

     The  EPA agrees with  the commenters that  significant  fluctuations
 in  the size  distribution  of  particulate emissions  could cause a varia-
 tion  in  the  observed  opacity level.   However, the  opacity increases due
 to  particle  size changes  are expected to be  small   relative to the
 increases  that  would  result  from malfunctioning or poorly maintained
 equipment.   The monitoring requirement  has been revised to include
 provisions that account for minor excursions  in opacity levels and that
 allow  for reestablishment of the opacity limit during any subsequent
 emission test that  demonstrates compliance with the standard.  One-
 hour average opacity  levels would be determined over a period of at
 least 36 hours during which the processes and control  equipment were
 operating normally.   The highest of these 1-hour opacity averages
would be determined,  and 5 percent opacity added to this  level to
create a  reference opacity level.   One-hour average opacity levels
 subsequent to the test in excess of the  reference  level  would indicate
that the  control device may no longer be achieving the particulate

                                 1-10-4

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emission limit.  At this point a Method 5 test would be necessary in
order to determine actual compliance.

     Opacity levels associated with particulate concentrations of
11.6 mg/dscm (0.005 gr/dscf) are likely to be close to or at the
detection limit of transmissometers.  Continuous opacity monitoring was
proposed not as a surrogate compliance method but, as stated in the
proposal preamble, as an indicator of the operation of the emission
control device.  Opacity monitoring has been shown to be a useful means
of indicating significant changes in the level of particulate control
resulting from operation or maintenance practices.  To ensure that
opacity monitoring does serve as an indicator of significant changes in
performance, the monitoring requirement was revised as described above.
The revisions which consider the instrument's imprecision and use a
larger data base are believed to address the special problems presented
by low concentration gas streams.  The EPA believes that reference
opacity levels determined according to the requirements of 61.175(c)
will be useful for evaluating operation and maintenance of the control
device.

     The EPA has found that excessive maintenance and downtime should
not be a problem with state-of-the-art opacity monitoring equipment.
Available information indicates that transmissometers that satisfy
40 CFR 60 Appendix B specifications have repeatedly demonstrated more
than 95 percent availability when properly operated and maintained
(IV-J-59).

1-10.3  WAIVER OF SAMPLING REQUIREMENTS

     Comment:  Magma Copper Company stated that it had no objection
to the proposed requirement, in §61.175(d), (e), and (f), for the
collection and subsequent analysis of daily grab samples of matte,
slag, and total smelter charge to determine initially a smelter's
converter arsenic charging rate and furnace tapping rate with respect
to the cutoff levels for applicability.  However, this commenter felt
that the continued practice could prove burdensome for a smelter that
fell well under the cutoffs.  The company questioned whether the waiver
of emission tests referred to in proposed §61.175(a)(4) [final  §61.174
(a)(4)] could be sought with regard to the sampling requirements for a
smelter that had very low arsenic input rates (IV-D-619).

     Response:  The waiver of emission tests discussed in §61.13, and
referred to in §61.175(a)(4) of the proposed regulation for low-arsenic
copper smelters, applies to sources that are covered by hazardous air
pollutant standards and are required to demonstrate compliance with the
standards through periodic testing of emissions.  Thus, this reference
in the regulation does not refer to the sampling requirements for
demonstrating applicability.

     The EPA agrees that the daily collection and monthly analysis of
grab samples would prove burdensome for a smelter that fell well under
the final applicability cutoff of 75 kg/h (164 Ib/h) converter arsenic
charging rate (the smelting furnace arsenic tapping rate cutoff no
longer applies).  Paragraph 61.174(g) has been included in the final

                                 1-10-5

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regulation to permit an owner or operator to petition  the  Administrator
for a modified sampling schedule if the analyses  performed in  the  first
year of the standard show the source to have a  very  low arsenic
processing rate in relation to the cutoff value.   An example of  a
modified sampling schedule would be weekly,  instead  of daily,  grab
samples being collected to form the composite monthly  samples.
                                1-10-6

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                          1-11.0  REFERENCES*
Item Number in
Docket A-80-40

II-A-71
II-D-43
II-J-13
III-A-1
III-B-1
III-B-2
IV-A-4,  IV-A-5
Vervaert, A. and J. Nolan, U.S. Environmental
Protection Agency and Puget Sound Air Pollution
Control Agency.  Log Book Nos. 1 and 2, Observa-
tions of Converter Secondary Hood Test at ASARCO-
Tacoma.  January 18-22, 1983.

Letter and attachments from Malone, R.A.,
Kennecott Minerals Company, to Farmer, J.R.,
U.S. Environmental Protection Agency.  March 16,
1983.  Response to Section 114 request for
information.

Occupational Exposure to Inorganic Arsenic;
Supplemental Statement of Reasons for Final
Rule, 29 CFR Part 1910.  Occupational Safety and
Health Administration (OSHA).  48 FR 1864.
January 14, 1983.

National Emission Standards for Hazardous Air
Pollutants; Proposed Standards for Inorganic
Arsenic, 40 CFR Part 61.  Proposed rule and
announcement of public hearing.  U.S. Environmental
Protection Agency.  48 FR 33112.   July 20, 1983.

Inorganic Arsenic Emissions from High-Arsenic
Primary Copper Smelters - Background Information for
Proposed Standards (Draft EIS).  U.S. Environmental
Protection Agency.  Research Triangle Park, N.C.
Document No. EPA-450/3-83-009a.  April 1983.

Inorganic Arsenic Emissions from Low-Arsenic
Primary Copper Smelters - Background Information
for Proposed Standards (Draft EIS).  U.S.
Environmental Protection Agency.   Research
Triangle Park, N.C.  Document No.  EPA-4'50/3-83-010a.
April 1983.

Evaluation of an Air Curtain Hooding System for a
Primary Copper Converter,  Volumes I and II.
Prepared by PEDCo Environmental,  Inc., for U.S.
EPA, Research Triangle Park,  N.C.   Document Nos.
EPA-600/2-84-042a and b.  December 1983.
"Appendix A  contains  a  listing  of  public  comment  letters  on  the proposed
 standards.

                                1-11-1

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Item Number in
Docket A-80-40

IV-A-6
IV-A-9
IV-A-10
IV-B-6
IV-B-10
IV-B-26
IV-B-30
IV-B-32
IV-B-35
Arsenic Non-Ferrous Smelter Emission Test Report,
Arsenic Sampler Comparison ASARCO, Incorporated,
Tacoma, Washington.  Prepared by PEDCo Environmental,
Inc., for U.S. EPA, Research Triangle Park, N.C.
EMB Report 83-CUS-20.  January 1984.  pp. 2-33 and
2-34.

Costello, T.V. and Gracey, J.W.  Analysis of the
Effect on the Arsenic Markets if the ASARCO-Tacoma
Primary Copper Smelter Ceases Arsenic Production.
JACA Corporation.  Ft. Washington, PA.  March 1984.

Visible Emissions Converter Secondary Hooding.
Prepared by Radian Corporation, for U.S. EPA,
Research Triangle Park, N.C.  EMB Report 81-CUS-
17.  May 1982.

Letter from Vervaert, A.E., U.S. Environmental
Protection Agency, to Zimmer, C., PEDCo Environmental,
Inc.  August 25, 1983.  Transmittal of main stack
arsenic emission estimates for ASARCO-Tacoma.

Letter and enclosures from Vervaert, A.E., U.S.
Environmental Protection Agency, to Schewe,.
G.F., PEDCo Environmental, Inc.  October 28, 1983.
Technical background on low-level  arsenic emission
estimates for ASARCO-Tacoma.

Memorandum from Whaley, G., Pacific Environmental
Services, Inc., to Docket No. A-80-40.  January
24, 1984.  Report on trip to Kennecott-Utah smelter
on November 1, 1983, to observe secondary emission
capture systems.

Memorandum from Vervaert, A.E., U.S.  EPA, to
Layland, D., U.S. EPA.  April  4, 1984.  Arsenic
dispersion calculations for the ASARCO-Tacoma
primary copper smelter.

Memorandum from PES Low-Arsenic Project Team to
Chaput, L., Standards Development Branch, U.S. EPA.
August 31, 1984.  Revised cost and emission estimates
for low-arsenic smelters.

Memorandum from PES, Inc., to Chaput, L., Standards
Development Branch, U.S. EPA.   April  3, 1985.  Plant
visit to ASARCO, Inc., copper smelter at El  Paso,
Texas.
                                1-11-2

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Item Number in
Docket A-80-40

IV-B-36
IV-C-3
IV-C-48
IV-C-120
IV-C-416
IV-C-417
IV-C-418
IV-C-487
IV-D-119
IV-D-785
Memorandum from Meyer, J», PES, Inc., to Docket
A-80-40.  April 26, 1985.  Statistical Analysis
of Sulfur Recovery Data for ASARCO-Hayden.

Letter and enclosures from Ajax, R.L., U.S.  Environ-
mental Protection Agency, to Hawkins, D., Natural
Resources Defense Council.  August 4, 1983.
Transmittal of BID reference materials requested
by NRDC.

Letter from El kins, C.L., U.S. Environmental
Protection Agency, to Doniger, D.D., Natural
Resources Defense Council.  August 24, 1983.
Response to NRDC's request for delay of public
'hearings :and for technical assistance.

U.S. Environmental Protection Agency, Region X.
News release to the public regarding new data on
arsenic emissions from ASARCO-Tacoma.  October 20,
1983.

Letter and enclosures from Farmer, J.R. , U.S.
Environmental Protection Agency, to Malone,
R.A., Kennecott Minerals Company.  February  15,
1984.  Section 114 request for information.

Letter and enclosures from Farmer, J.R., U.S.
Environmental Protection Agency, to Rice, R.W.,
Phelps Dodge Corporation.  February 15, 1984.
Section 114 request for information.

Letter and enclosures from Farmer, J.R., U.S.
Environmental Protection Agency, to Varner, M.O.,
ASARCO, Inc.  February 15, 1984.  Section 114 request
for  information.

Letter from Curtis, F., U.S. Environmental Protection
Agency, to Robbins, D., ASARCO, Inc.  June 4,  1984.
Information required for alternative method  evaluation.

Letter from Doniger, D.D., Natural Resources
Defense Council, to Ruckelshaus, W.D., U.S.
Environmental Protection Agency.  July 29, 1983.
Request for postponement of public hearings.

Letter from Rice, R.W., Phelps Dodge Corporation,
to Farmer, J.R., U.S. Environmental Protection Agency.
March 2, 1984.  Response to Section 114 request
for  information.
                                1-11-3

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Item Number In
Docket A-80-40
IV-D-788
IV-D-789
IV-D-790
IV-D-802
IV-E-23
IV-E-65
IV-E-72
 IV-E-79
 IV-E-80
Letter and enclosures from Malone, R.A., Kennecott
Minerals Company, to Farmer, J.R., U.S. Environmental
Protection Agency.  March 6, 1984.  Response to
Section 114 request for information.

Letter and attachments from Varner, M.O. , ASARCO,
Inc., to Farmer, J.R., U.S. Environmental
Protection Agency.  March 15, 1984.  Response to
Section 114 request for information.

Letter and attachments from Rice, R.W., Phelps Dodge
Corporation, to Farmer, J.R., U.S. Environmental
Protection Agency.  March 16, 1984.  Response to
Section 114 request for itemization of company cost
estimates.

Letter and enclosures from Lindquist, L.W., ASARCO,
Inc., to Ajax, R., U.S. Environmental Protection
Agency.  June 27, 1984.  Notification of ASARCO's
intention to terminate copper smelting operations at
Tacoma smelter.

Memorandum from Meyer, J., Pacific Environmental
Services, Inc., to meeting attendees at December 20,
1983, meeting with interested parties on proposed
NESHAP.  December 23, 1983.  Handouts containing
modeling results and suggestions for emission control
at ASARCO-Tacoma.

Telecon.  McAdams, T., Pacific Environmental
Services, Inc., with Bump, B., Research-Cottrell.
April 26, 1984.  Cost estimate for ESP control
system.

Telecon.  Wright, M., United Steelworkers of America,
with Meyer, J., Pacific Environmental Services, Inc.
April 23, 1984.  Operating practices with converter
ladle at ASARCO-Tacoma.

Telecon.  McAdams, T., Pacific Environmental Services,
Inc., with Montgomery, L. , Texas Air Control Board.
November 26, 1984.  Operation of the ASARCO-E1  Paso
building evacuation system.

Telecon.  McAdams, T., Pacific Environmental Services,
Inc., with Sieverson, J., ASARCO,  Inc.  November 28,
1984.  Operation of the converter  building  evacuation
system at ASARCO-E1 Paso.
                                 1-11-4

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Item Number in
Docket A-80-40

IV-E-81
IV-E-82
IV-I-1
IV-I-3
IV-I-4
IV-J-59
Telecon.  Robbins, D. and J. Richardson, ASARCO, Inc.,
with McAdams, T., Pacific Environmental Services,
Inc.  November 28, 1984.  ASARCO's experience with
corrosion on pollution control equipment at Tacoma
smelter.

Telecon.  McAdams, T., Pacific Environmental
Services, Inc., with Robbins, D.A., ASARCO, Inc.
December 13, 1984.  Control options regarding the
ASARCO-E1 Paso building evacuation system.

National Emission Standards for Hazardous Air Pollu-
tants; Proposed Standards for Inorganic Arsenic, 40
CFR Part 61.  Amended notice of public hearing and
extension of public comment period.  U.S. Environmental
Protection Agency.  48 FR 38009.  August 22, 1983.

National Emission Standards for Hazardous Air
Pollutants; Proposed Standards for Inorganic Arsenic,
40 CFR Part 61.  Reopening of public comment period.
U.S. Environmental Protection Agency.  48 FR 55880.
December 16, 1983.

National Emission Standards for Hazardous Air Pollu-
tants; Proposed Standards for Inorganic Arsenic,
40 CFR Part 61.  Reopening of public comment period.
U.S. Environmental Protection Agency.  49 FR 36877.
September 20, 1984.

Compilation of Opacity Monitor Performance  Audit
Results.  Prepared by Entropy Environmentalists for
U.S. EPA, Washington, D.C., Document No. EPA-340/
1-83-011.  (January 1983).
                                 1-11-5

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PART II - NATIONAL EMISSION STANDARD FOR INORGANIC ARSENIC
          EMISSIONS FROM ARSENIC TRIOXIDE AND METALLIC
          ARSENIC PRODUCTION FACILITIES

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                            II-l.O  SUMMARY

     On July 20, 1983, EPA proposed a standard in the Federal Register
for primary copper smelters processing feed materials with 0.7 percent
or greater arsenic.  The proposed standards would have affected only
the ASARCO smelter in Tacoma, Washington.  In the notice of proposed
rulemaking, EPA stated that further evaluation of controls to reduce
inorganic arsenic emissions would be conducted at ASARCO-Tacoma.  The
EPA conducted extensive inspections of the smelter and on December 16,
1983, proposed for comment additional control measures that could be
applied to reduce fugitive arsenic emissions from the smelter and the
associated arsenic plant.  Over 650 comment letters were received by
EPA, and many interested parties testified at the public hearings held
in Tacoma, Washington, and Washington, D.C.

     On June 27, 1984, ASARCO announced that it planned to close its
primary copper smelting operations at Tacoma, Washington, by June 30,
1985 (the smelter closed in March 1985) (IV-D-802).  In the same
announcement, ASARCO stated that it will continue to operate the arsenic
trioxide and metallic arsenic production plants at the site and that
the plants will be operated in an environmentally acceptable manner.
From discussions with ASARCO personnel , EPA has found that there is
some uncertainty regarding the process to be used and the future config-
uration of the arsenic trioxide plant.  It appears that ASARCO is
considering several different modifications to its arsenic trioxide
production process, including the use of a wet leaching process or
enclosure of the Godfrey roasters and control of emissions using a
fabric filter collector.  ASARCO expects that these modifications will
significantly reduce arsenic emissions from the facility but, as of
this writing, has not indicated when the changes would be implemented.
Consequently, EPA decided that the proposed fugitive emission control
measures for the arsenic plant should be finalized at this time on the
basis of current information.

     Responses to comments on proposed fugitive emission control
measures for the arsenic plant and issues pertaining to the continued
operation of the arsenic plant are presented in this section.  These
comments are also addressed in the Federal Register notice of final
rulemaking.

II-l.l  SUMMARY OF CHANGES SINCE PROPOSAL

     A number of changes have been made to the arsenic plant require-
ments proposed at 48 FR 55880 on December 16, 1983 (IV-I-3).  These
requirements were modified as a result of public comments and planned
changes in the operations of the only affected facility (ASARCO-Tacoma).
These changes are:  (1) deletion of specific equipment requirements  for
the arsenic plant.  The proposed requirements for modifications to
equipment in the arsenic plant have been removed from the standard.
These modifications are not being required because either the equipment
is in place and likely to remain in place or there is a more cost-
effective means of achieving the emission reduction; (2) modification
of the proposed work practices.  While the proposed requirement for
preparation of an inspection, maintenance, and housekeeping plan has

                                 II-l-l

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 been  retained,  specific  aspects  have  been modified.  The  final require-
 ments for  an  approyable  plan  do  not require  the  inspector to  follow a
 prescribed inspection  route.   In addition, the proposed requirement to
 shut  down  malfunctioning equipment until it  is repaired has been modi-
 fied  to  require the  source  to describe  the time  and actions required to
 curtail  increased  emissions due  to malfunctions; and (3)  clarification
 of  the provisions  for  recordkeeping and reporting and  inclusion of
 minor new  provisions.  The  standard requires quarterly reporting of
 occurrences of  excess  opacity readings, ambient  arsenic monitoring data
 and semiannual  status  reports on pilot  plant studies on alternative
 arsenic  trioxide production processes.

 II-1.2  SUMMARY OF ENVIRONMENTAL, HEALTH, ENERGY, AND  ECONOMIC IMPACTS

      The standard  being  established today affects new  and existing
 arsenic  trioxide and metallic arsenic production facilities.  EPA
 projects that the  standard will  affect  one facility, the  arsenic plant
 at  ASARCO-Tacoma.

      The standard  is expected to reduce emissions due  to  malfunctions
 and upsets  in the  arsenic plant  and to  reduce reentrainment of arsenic-
 containing materials from plant  surfaces.  However, the impact of the
 standard on fugitive emissions from the arsenic  plant  is  difficult to
 quantify because of the  difficulties inherent in estimating fugitive
 emissions, the  unpredictability  of malfunctions, and the  considerable
 uncertainties regarding  the processes and operations that will be used
 at  the facility in the future.   The standard is  based on  application of
 control measures that are necessary and practicable at this time,  and
 not on the application of a risk management approach.

      Application of the  required housekeeping and maintenance provisions
 should have no appreciable solid waste, water,  or energy  impacts on the
 facility.  The annualized cost required to comply with the standard is
 estimated at about $265,000 per year.   The primary economic impacts
 associated with the standard are projected small  decreases in profit-
 ability for the ASARCO-Tacoma arsenic plant,  if costs  cannot be
 passed through.   If costs are passed forward in the form of a price
 increase, it is estimated that the standard would result in less than  a
 5 percent increase in the price of arsenic trioxide.   The ASARCO-
Tacoma facility will  not be forced to close as  a  result of the final
 regulation.
                                 11-1-2

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       II-2.0  SUMMARY OF PUBLIC COMMENTS ON THE PROPOSED STANDARD

 II-2.1  ARSENIC EMISSION ESTIMATES

      Comments were received by EPA throughout the public comment period
 concerning the Agency's proposal estimates of arsenic emissions from
 the ASARCO-Tacoma smelter.   Initially, the comments addressed the
 emission estimates EPA presented in the Federal Register notice of
 proposed rulemaking (48 FR  33125) and the BID for the proposed high-
 arsenic copper smelter standard (EPA 450/3-83-009a).   Several
 commenters,  including ASARCO,  felt that the emission  rates used in
 EPA's analysis significantly overstated the amount of arsenic being
 emitted from the Tacoma smelter.  Other commenters expressed the opinion
 that EPA s emission estimates  did not account for various low-level
 or intermittent sources at  the smelter.

      During  the public comment period, the Agency released to the public
 a  series of  revised emission estimates (refer to  docket references
 IV-B-10, IY-C-120,  and IV-E-23).  In these revised estimates,  EPA
 expanded the list of sources at the smelter for which arsenic emissions
 were estimated.   Additional  comments were received on these  revised
 estimates.   The major focus  of these comments was on  the emission
 estimates for low-level  sources.   Upon reviewing  these comments,
 evaluating the supporting information provided by the commenters,  and
 obtaining additional  information,  EPA developed a completely new set of
 estimates for arsenic emissions  from the  entire smelter.

      However,  due  to  ASARCO's  closing of  the  Tacoma copper smelter and
 the  continuation  of the  operation  of the  arsenic  plant,  the  Agency is
 including in this document only  the  comments  and  responses that deal
 directly with  arsenic emissions  from the  arsenic  plant.   Since  the
 final  configuration of the arsenic  plant  after  this change is  unknown
 as  this  document  is being prepared,  the estimates  of  emissions  from
 this  facility  are not considered  final and  might  be changed.  The  basis
 for  the  revised emission estimates  for the  arsenic plant  is  presented
 in Appendix  G.  Appendix H contains  a  summary of  results  of  the  recent
 EPA  testing  performed  on the arsenic  plant  baghouse.

 II-2.1.1  Arsenic Plant Process Emissions

     Comment:  Several commenters, including ASARCO,  stated  that  the
emission estimates  EPA presented in  the Federal Register  notice of
proposed rulemaking (48 FR 33125) overstated the amount of arsenic
emitted  from the ASARCO-Tacoma smelter (IV-F-3, IV-D-22,  IV-D-254
IV-D-263, IV-D-264, IV-D-326,  IV-D-331, IV-D-332,  IV-D-540,  IV-D-600)
The commenters claimed that,  based on data obtained by ASARCO from
continuous particulate samplers located in various flues vented to the
main stack, EPA overestimated the total main stack arsenic emissions by
a factor of 1.4 to 3.5.  ASARCO claimed that EPA's estimates of stack
emissions overstate actual  emissions from the smelter because EPA's
estimates were derived from:   (1) an inaccurate arsenic material balance
that was based on inaccurate analytical results, and  (2) a 1978 material
balance that  did not reflect current emission controls or the effect of

                                 II-2-1

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curtailments under the supplementary control system (SCS) program
currently being implemented at the smelter to control sulfur oxide
emissions.

     Response;  The EPA's main stack emission estimate presented at
proposal was based on the best information available to EPA at the time
the proposed standard was under development.  The arsenic material
balance used by EPA to derive emission estimates was based on a
material balance developed by ASARCO that represented operations at the
Tacoma smelter for the entire year of 1982 (II-D-42).  The smelter SCS
program was in operation throughout 1982.  Thus, the values of arsenic
input to the various control devices used by EPA do account for the
effects of curtailments under the smelter SCS program.  ASARCO's under-
standing that the EPA emission estimate was based on a material balance
for the year 1978 is incorrect.

     At the time the proposed standard was being developed, the roaster
baghouse was the only control device at the ASARCO-Tacoma smelter for
which test data were available to determine arsenic collection efficiency.
For the other control devices, the arsenic collection efficiency was
estimated on the basis of test data for similar control devices
currently used at the ASARCO-E1 Paso smelter or previously used at the
Tacoma smelter (these estimates are described in docket reference
IV-B-6).  Using this approach, EPA estimated the main stack arsenic
emission value presented in the Federal Register notice of proposed
rulemaking.  This estimate showed that of the total main stack arsenic
emissions, 55 percent is contributed by the reverberatory smelting
furnace and 42 percent by the arsenic plant.  Since over 97 percent of
the main stack arsenic emissions was estimated to be contributed by two
sources based on estimated arsenic collection efficiencies, and in
response to comments EPA received concerning these estimates, EPA
decided to perform additional emission tests at the ASARCO-Tacoma
smelter to obtain more data on the main stack emissions.

     The results of this test program carried out in September 1983,
are presented in Appendix H (as the results relate to the baghouse
controlling emissions from the arsenic plant).  Based on this testing,
the arsenic plant baghouse emits 0.33 pound per hour (0.15 kg/h) of
inorganic arsenic.  At the time of the emission tests, baghouse emis-
sions were ducted to the main stack, together with emissions from
several other control devices at the smelter.  This revised emission
value based on recent testing is only about 2 percent of the value of
16 Ib/h (7.3 kg/h) that EPA used at proposal in its estimation of total
main stack emissions.

II-2.1.2  Low-Level Emissions From the Arsenic Plant

     Comment:  The United Steelworkers of America (USWA) commented that
EPA's proposal estimates of low-level arsenic emissions do not include
all the low-level emission sources observed at the Tacoma smelter by
Union representatives (IV-F-8).  ASARCO stated that EPA's estimates for
many of the low-level sources were overstated at proposal because
control measures implemented by ASARCO as of December 1983, have reduced
emissions below the levels estimated by EPA (IV-D-621).  The Washington

                                 11-2-2

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 State DOE expressed an opinion that low-level fugitive emissions are
 a major cause of the high 24-hour ambient arsenic concentrations that
 have been recorded near the smelter.  (Maintenance and material handling
 at the arsenic plant were cited as activities that contribute to these
 emissions.)  This commenter recommended that these emissions be identified
 and controlled (IV-D-622).

      Response:  Since proposal of the standard,  new information about
 the sources of low-level  arsenic emissions at the ASARCO-Tacoma
 smelter was obtained by EPA during extensive visits to the smelter.   On
 June 21, 22,  and 23, 1983,  a comprehensive inspection of the ASARCO-
 Tacoma smelter was conducted by EPA to identify  potential  sources of
 low-level emissions and to  document the types of control measures or
 practices applied.  From September 12 to 29, 1983, EPA conducted
 emission source testing of  the ASARCO-Tacoma No.  1 Cottrell  and the
 arsenic plant baghouse.  During these periods, EPA monitored the smelter
 processes and, consequently, had the opportunity to observe  on a daily
 basis the process operations,  control  equipment  performance, and worker
 operating and housekeeping  practices at the smelter.   Based  on these
 observations  and an improved understanding of operations at  the Tacoma
 smelter, EPA  revised its  emission rate estimates for  low-level sources
 In October 1983,  EPA placed in the docket for public  comment (IV-B-10)
 a revised and expanded set  of  low-level  arsenic  emission rate estimates
 for sources other than the  converters  at the smelter.   These estimates
 were based on controls in place on the sources during  1982.

      Since 1982,  additional  control  measures have been implemented by
 ASARCO to reduce  arsenic  emissions from the ASARCO-Tacoma  smelter.   The
 U.S.  Occupational  Safety  and Health  Administration (OSHA)  standards  for
 occupational  exposure to  inorganic arsenic (II-J-10)  required ASARCO to
 implement the following actions at the smelter:   (1)  by December 1,
 1978,  respirators  to be worn by workers  exposed  to arsenic concentra-
 tions  over 10 fig/m3;  (2)  by  July 1,  1979,  completion  of "clean"  lunchroom
 and  hygiene facilities; and  (3)  by December 31,  1979,  completion  of
 engineering controls.   Actual  implementation  of  some of the  requirements
 of the OSHA arsenic standard was delayed by litigation  of  the  standard.
 On December 6,  1982,  a  plan  for achieving  compliance with  the  OSHA
 arsenic standard was  agreed  upon  by  ASARCO,  the State  of Washington
 Department of Labor and Industries,  and  the Union  representing  the
 Tacoma  smelter workers  (USWA).   This agreement, referred to  as  the
 "Tripartite Agreement," is in effect through  July  1, 1987, and requires
 that ASARCO implement at  the Tacoma  smelter additional  engineering
 controls  during 1983  and  1984  (IV-D-447).   Also,  since  1982, ASARCO  has
 voluntarily installed new equipment at  the  ASARCO-Tacoma smelter  to
 control arsenic emissions (e.g.,  in  1983, ASARCO installed a pneumatic
 conveyor  system to  transfer  the arsenic  plant Godfrey roaster  calcines
 directly  to the Herreshoff roasters).

     While it  is unclear as  to  how ASARCO's closing of  the copper
 smelter will affect arsenic emissions from  the arsenic plant,  the
 revised low-level emission estimates for the arsenic plant developed
 since proposal are presented in Appendix 6.  Emission estimates are
 presented for  two control situations:  assuming the controls in place
as of December 31, 1982, and assuming the additional control  measures

                                 I1-2-3

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 implemented by ASARCO since that date.  The latter control situation
 includes the addition of the control measures called for in this NESHAP.

      The Administrator agrees with the commenter that fugitive emissions
 (as well as process emissions vented to the baghouse) from the arsenic
 plant at ASARCO-Tacoma should be controlled.  The final  regulation for
 the arsenic plant contains requirements in the form of equipment and
 work practice standards, selected from among those discussed in the
 December 16, 1983,  Federal Register notice of proposal,  48 FR 55880
 (IV-I-3), after consideration of public comments on the  need, feasibility,
 and costs of the requirements.   The requirements are expressed in the
 form of equipment,  work practice, and operational standards because
 these emissions cannot be accurately measured.

 I1-2.2  COMMENTS ON PROPOSED CONTROL TECHNOLOGY

      Comment:   ASARCO and the USWA commented on the proposed controls
 for fugitive emissions from the  arsenic plant (IV-D-703,  IV-D-708a).
 ASARCO felt that the listed control  measures were developed without
 consideration  of the likelihood  of the material  being emitted into the
 ambient air,  their  technical  feasibility or cost,  or the  cost effective-
 ness of the measures in reducing any health risk.   Both  commenters
 expressed opinions  on the proposed requirement  for a dust-tight
 conveying system for arsenic plant materials.   ASARCO felt that:
 (1)  it is not  possible to use an enclosed pneumatic conveying system to
 transfer wet dust (the dust is wetted because  the Godfrey roasters
 cannot accept  dry dust);  and  (2) the present covered belt conveyor
 system is best available  technology.   The USWA  also commented that
 pneumatic conveying would require relocation of  the zig-zag  blender,
 and  recommended as  an alternative that ASARCO be  required to maintain
 the  fullest possible enclosure of the zig-zag blender and belt transfer
 system and to  ensure that leaks  are  promptly identified and  repaired.
 In response to the  proposal  to require  installation  and maintenance of
 a solid refractory  arch on  each  Godfrey  roaster,  both  ASARCO and  USWA
 commented that all  the arches have now  been  installed.

    ,  Response:   The  proposed  additional  control measures  were  based on
 EPA  s  assessment of controls  that could  be used to  reduce  fugitive
 emissions  from the  arsenic  plant.  The  likelihood  of  fugitive  emissions
 being  released to the atmosphere  was  considered by  EPA in  developing
 the  requirements.  The generally  open  configuration of the buildings
 and  EPA  observations  indicate that emissions released  inside the
 structures  housing  the arsenic plant are  likely to  be  released to  the
 atmosphere.  In  some  cases, such  emissions disperse directly to the air
 outside  the buildings.  In  other  cases,  the emissions may  settle on
 supporting  structures and surfaces within the buildings.   These deposits
 of dust  in and around buildings and plant surfaces can be  re-entrained
 during periods of high winds.  In fact, ASARCO has attributed  some
episodes of high ambient arsenic  concentrations to re-entrainment of
 dust from plant and building surfaces.  Similarly, EPA also believes
 that spills of materials can serve as sources of fugitive emissions
 through re-entrainment of dust from building and plant surfaces.  The
 final requirements address all fugitive emission sources at the arsenic
plant operation as these sources  are understood at this time.  In

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developing these control measures, EPA also developed estimates of the
costs and potential emission reduction.  These control measures and
emission reduction estimates were briefly discussed in the meeting held
December 20, 1983 (IV-E-77), and were placed in the docket for public
inspection (IV-E-23).  [In response to comments, these estimates were
revised and the revised estimates were also distributed to the meeting
attendees for comment and to the public docket (IV-C-458).]  As discussed
in Section. 11-1,2, an accurate estimate of the emission reduction
resulting from control measures applied to the arsenic plant cannot be
made at this time.  Nonetheless, EPA believes that the final control
requirements, including best fugitive emission controls, are necessary
for this facility.  The Agency estimates that the annualized cost to
maintain these controls will be about $265,000 per year.  These control
measures were selected based on consideration of the emission reduction
that would be obtained, the technical feasibility, and the estimated
costs.

     The EPA considered the comments on the proposed dust-tight
conveyor and believes that a pneumatic conveyor could be used as proposed
by relocating the zig-zag blender closer to the Godfrey roasters.
However, a more cost-effective approach to this control objective
would be through improved housekeeping and maintenance of the existing
system, as recommended by the USWA.  Since EPA is establishing provi-
sions for a routine maintenance and repair program in this NESHAP, the
proposed requirement for a dust-tight conveyor system in the arsenic
plant is not included in the final regulation.

     The final standard does not include a requirement for refractory
arches over the Godfrey roasters, since EPA judges that these controls
are in place and likely to remain in place.

II-2.3  OPERATION AND MAINTENANCE REQUIREMENTS

     Comment:  The Washington State Department of Ecology (DOE)
recommended that the final regulation include provisions requiring
inspection and maintenance of the equipment used for control of arsenic
emissions throughout the ASARCO-Tacoma smelter (not just of the converter
secondary hood system, as proposed) (IV-D-622).

     ASARCO and USWA commented on EPA's five general objectives,
proposed in the December 16, 1983, Federal Register notice, for an
inspection, maintenance, and housekeeping plan for the Tacoma smelter
(IV-D-703, IV-D-767).  This plan consisted of the following points:

     1.  "No accumulation of material having an arsenic content greater
than 2 percent on any surface within the plant outside of a dust-tight
enclosure."

         ASARCO's comments on this objective of the management plan were:
(1) This requirement can only be interpreted as meaning the entire plant
would have to be placed within an enclosure, and (2) the costs of such
an enclosure would be astronomical.  The USWA commented that dry, dusty
materials with arsenic concentrations well below 2 percent may contribute
significantly to fugitive emissions from the plant, while damp materials

                                 II-2-5

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 with higher arsenic content would not contribute significantly.   In
 other words,  the moisture content is as important a consideration as
 the arsenic content.

      2.   "Immediate cleanup of any spilled material having an arsenic
 content greater than  2 percent."

      ASARCO's comments on this objective were:   (1) There is a house-
 keeping program in place as part  of the OSHA/WISHA arsenic compliance
 requirements, (2)  any clean-up requirements should be  directed toward
 specific sources and  materials and should be handled by  a regulatory
 agency compliance  requirement, and (3)  the objective does not consider
 whether the material  is likely to become airborne.   The  USWA comments
 on this  proposed requirement were the same as their comments on  the
 preceding requirement.

      3.   "Regular  scheduled maintenance of all  smelter process,
 conveying,  and emission control equipment to minimize  equipment
 malfunctions."

      Both ASARCO and  USWA commented that this proposed objective  is
 currently required by the Tripartite  Agreement,  and USWA  further
 commented that it  should also be  included in the final standard.

      4.   "Regular  inspection  to ensure  equipment is operating  properly."

      ASARCO commented that there  is an  inspection  procedure  in place,
 and it is unreasonable  to require the proposed  inspection  routine and
 documentation.   In contrast,  the  USWA agreed with  the  proposed objec-
 tive and  recommended  that the inspector  document general  housekeeping
 in each area  to  ensure  plant  surfaces are kept  free of dry,  dusty
 materials.  Both ASARCO and USWA  commented  that  it  is  unnecessary to
 require the inspector to follow a prescribed route.

      5.   "Repair of malfunctioning or damaged equipment."

      ASARCO commented that they oppose  the  proposed  requirements because
 the  urgency of the repair is  not  related  to  the  quantity of emissions
 to the air or impact  on  air quality.  They also  considered the proposal
 to be unreasonable because  it removed from ASARCO the  discretion and '
 authority to  determine  and  take appropriate  action.  The USWA commented
 that it is not always practicable  or  necessary to shut down operations
 involving material with  more  than  2 percent  arsenic.

     Response;   The rationale  for  requiring  no accumulation of arsenic-
 containing materials and  clean-up  of  spills, as  previously discussed,
 is  that re-entrainment  of part or all of  the material  is possible and
re-entrained material  is  likely to enter  the atmosphere.   The intent
of the proposed  requirement was not, as suggested by ASARCO, to require
enclosure of  the entire plant, which  obviously is not practicable.
 Instead, the intent was to focus attention on control of potentially
significant sources of fugitive arsenic emissions from sources such as
arsenic kitchen pulling or handling of baghouse dust and to exclude
non-arsenic bearing materials.  The EPA considers the USWA's comment

                                 II-2-6

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that the requirement should be limited to dry, dusty materials to be
valid.  Consequently, this objective has been reworded in the final
work practices standard [§61.182(b) (l)(i)] to require cleaning up,
wetting, or chemical stabilization of accumulations of dry, dusty
materials with appreciable arsenic content (greater than 2 percent).
The objective has not been revised as suggested by USWA to include
materials with more than 0.2 percent arsenic because limiting the
requirement to materials with more than 2 percent arsenic essentially
requires clean-up or control of all sources in the arsenic plant.

     The EPA reviewed ASARCO's housekeeping plan submitted to WISHA and
found that its scope was much narrower than intended by the Agency's
proposal.  Thus, at present ASARCO's existing housekeeping program can-
not be considered an adequate substitute for the proposed objective.
The EPA believes that the second objective of the general work practice
plan should be included in the final standard to ensure that prompt
attention is given to clean-up or control of spilled materials
containing greater than 2 percent arsenic.  It is not practicable at
this time to identify in the regulation every potential source of
spills because the exact configuration and full extent of the arsenic
plant operations have not yet been established.  EPA believes that,
unless this requirement is part of the regulation, there will be no
means of ensuring the attendant emission control.  Therefore, the
requirement has been included in the final regulation [§61.182(b)(D
     The third provision (regular scheduled maintenance) is included in
the final standard to establish more explicit requirements than does
the Tripartite Agreement.  Regular maintenance items are not specified
in the regulation, but will be included in the inspection, maintenance,
and housekeeping plan submitted by the owner or operator under the
final regulation.  In the course of regular inspections (see below),
most maintenance needs will be identified and attended to on an as-
needed basis.  Examples include identification and replacement of
defective fabric filter bags, and repair of leaks in dust conveying
equipment.

     The EPA believes that the proposed regular inspection objective
(provision no. 4) is a necessary element of the management plan to
minimize fugitive and excess emissions, and thus is included in the
final standard [§61.182(b)(2)].  The proposed requirement for a
prescribed route, however, is deleted as it is unnecessary as long as
all equipment and areas are inspected.  The regular inspection of
equipment will ensure that impending or actual malfunctions are
detected before preventable emissions occur.  The required checklist
will create a record that can be used to determine possible causes of
higher than normal ambient arsenic concentrations near the plant.
The EPA believes that regular inspection and documentation is necessary
because ASARCO's correspondence with PSAPCA and EPA suggests that
equipment malfunctions and upsets and other causes of higher than
normal emissions presently are not systematically documented.  Further,
during the public hearing in Tacoma, ASARCO representatives confirmed
that they do not have procedures that document all observed emissions
and their causes.  The EPA believes that such documentation is necessary

                                 II-2-7

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to objectively pursue an effective emission control program.  As
suggested by the USWA, the inspection procedure has been expanded to
include observation and documentation of housekeeping practices.  This
inspection procedure and its required documentation will increase
awareness of and emphasis on emission control.

     The EPA considered the comments on the fifth provision and
consequently revised the proposed objective to require the company to
submit a plan, subject to the approval of the Administrator, describing
the actions that will be taken to curtail operations when process upsets
or malfunctions of process, emission control, or material handling
equipment occur that could result in increased emissions of arsenic
[§61.182(b)(5)].  This plan will describe the time required and the
procedures to be used to curtail increased emissions due to malfunctions.
The plan will also describe any technical limitations on curtailments.
This approach will allow sufficient flexibility to consider technical
limitations and to consider whether specific individual malfunctions
would increase emissions of inorganic arsenic to the atmosphere.

II-2.4  REPORTING AND RECORDKEEPING

     Comment:  The Washington State DOE recommended that a requirement
be added to the regulation for the reporting of any upset, breakdown,
or related problem with equipment that would result or might result in
increased emissions of arsenic.  This commenter also suggested that a
log of material handling, repair and maintenance operations, or other
operations that could result in increased arsenic emissions be kept at
the smelter.  (Comments were made with regard to the ASARCO-Tacoma
smelter.) (IV-D-622)

     Response:  As the previous response indicates, the owner or operator
of each affected arsenic production plant is required to submit to the
Administrator a list of potential sources of inorganic arsenic emissions
and a plan describing the actions that would be taken to identify
malfunctions and curtail operations after a malfunction had occurred.
The plan to minimize fugitive emissions also includes provision for the
maintenance of records of regular inspections of process, conveying,
and control equipment.

     The EPA believes that the plan to document the inspection, mainte-
nance, and housekeeping status of the equipment at arsenic plants
addresses the concerns shown by the commenter.  The plan focuses on
prevention of malfunctions and on curtailment of operations until a
malfunction is corrected.  It further requires removal of accumulations
and clean-up of spills of arsenic-containing materials.  These are
considered the best steps that can be taken to minimize fugitive arsenic
emissions from arsenic plants to the maximum extent practicable.

II-2.5  NEED FOR AN AMBIENT STANDARD

     Comment:  A number of commenters, including ASARCO, local govern-
mental agencies (PSAPCA and Washington State DOE), and environmental
and union groups (NRDC and USWA), commented on the need for an ambient
arsenic concentration limit in the vicinity of the ASARCO-Tacoma smelter.

                                 II-2-8

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 (These  comments  and  the  Agency's  response are still considered to be
 applicable  because ASARCO  intends  to continue operation of the arsenic
 plant at  Tacoma.)

     It was  suggested  by one  commenter that the  final standard should
 specify the  monitoring and analytical techniques to be used in measuring
 ambient levels.   PSAPCA  specifically recommended that EPA establish
 24-hour and  annual average arsenic action levels to enforce implemen-
 tation  of a  fugitive emission control program at the ASARCO-Tacoma
 facility  (IV-D-693,  IV-F-3).

     Other commenters  felt that EPA should not establish an ambient
 standard  for arsenic.  The Washington DOE said that while it intends
 to  establish 24-hour and annual average community exposure standards
 to  limit  arsenic  emissions, it did not recommend that EPA adopt an
 ambient,  or  community  exposure, standard.  The DOE believes there is a
 need for  flexibility in  implementing such a standard for the area
 around  the ASARCO-Tacoma smelter.  Hence, in April  1984, the DOE
 adopted interim  ambient  standards and plans to adopt permanent
 standards after  evaluation and study of the causes of high ambient
 arsenic concentrations in the Tacoma area.  The interim standards limit
 maximum 24-hour  ambient  concentrations of arsenic to 2.0 (ig/m3 and
 maximum annual average ambient concentrations of arsenic to 0.3 uq/m3
 (IV-D-622).

     The  USWA and NRDC commented that an ambient standard for carcino-
 gens is inappropriate  and not authorized under the Act (IV-D-708a,
 IV-D-710).   These commenters  argued that an ambient standard is
 inappropriate because  no safe level can be established for zero-
 threshold pollutants.  They do believe, however, that an ambient
 monitoring requirement and an "action level" used as an adjunct to
 enforcement  would be useful and authorized under the Act.  The USWA
 specifically recommended:  (1) that the action level should be achiev-
 able when all controls are working properly and should be revised
 periodically, and (2) that exceedances of the action level  should
 trigger an investigation by the company and a report to EPA.  The USWA
 also recommended that the ambient monitoring requirement include
 provisions requiring ASARCO to study and estimate regularly the fugitive
 emissions from all sources in the plant, and to prepare and implement a
 management plan  for control of fugitive emissions.

     ASARCO commented on the legal authority and recommendations for
 an ambient arsenic standard or,community exposure level.  The company
 believes that the language and legislative history of the Clean Air
 Act show that Section 112 does not empower EPA to set an enforceable
 ambient standard.  ASARCO maintained that the clear thrust  of
 Section 112  is that EPA is responsible for adopting standards  that
 limit continuously the amount of emissions of hazardous  air pollutants
 from individual  sources.   ASARCO argued that an ambient standard would
not be  useful or appropriate because:   (1) ambient  arsenic  concentrations
are presently monitored and will  continue to be monitored;  (2)  ambient
concentrations around a source vary due to factors  other than  emission
rates,  including meteorological  conditions and local  terrain;  (3)  fugi-
tive emissions are already well  controlled;  and (4)  there are  no medical

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criteria that can be used to establish the concentration level and
averaging period of such a standard.  A further argument against an
ambient standard presented by ASARCO was that an ambient standard would
not be an effective means of reducing arsenic emissions.  ASARCO
commented that an ambient standard would have to be achieved by either
emission controls or production curtailments and that EPA would have to
identify sources of emissions causing high ambient arsenic levels and
determine the controls required to attain the standard.  ASARCO pointed
out that, in the case of a 24-hour standard, it would be difficult to
determine what controls should be required because it is not possible
to determine retroactively the causes of high arsenic values.  It was
also argued that maintaining an ambient arsenic standard by intermittent
production curtailment was not feasible.  Curtailment is not considered
a feasible approach to arsenic control because:  (1) there is currently
no real-time monitoring system for arsenic; (2) it is not practicable
because of lack of knowledge about which sources should be curtailed;
and (3) arsenic emission sources require lengthy shutdown periods
before they cease emitting arsenic (IV-D-621).

     Response:  Since an enforceable ambient standard is not being
established in the final standard, ASARCO's comment (that Section 112
of the Clean Air Act does not give EPA the authority to set enforceable
ambient standards) is not pertinent to this rulemaking.  The EPA agrees
that an ambient standard cannot be established for inorganic arsenic
based solely on health effects or risk estimates.  The Agency does
believe, however, that an enforceable ambient limit, which is an
indicator of proper operation and maintenance of emission control
systems and is developed considering all relevant factors, is consistent
with Section 112 and may consider establishing a limit at a later date.
Such a limit would serve as a direct measure of the degree to which
fugitive arsenic emission sources at the arsenic plants were being
controlled.  The EPA intends to review ambient arsenic monitoring data
in the future to determine if additional control measures are needed,
and the standard requires quarterly reporting of ambient monitoring
data to facilitate this review.  Among the measures that would be
considered is an enforceable boundary limit, provided that sufficient
information and data are available to establish a limit.  The enforceable
boundary limit would be used to evaluate the effectiveness of required
control measures and would not impose any additional control requirements.
Similarly, production curtailments would not be required in order for
compliance with the limit to be achieved.  Hence, ASARCO's comments
regarding the utility of an ambient standard are not applicable to the
concept of an enforceable boundary limit.

     Depending on the steps ASARCO takes to reduce emissions in future
operations of the arsenic plant, EPA plans to establish the need for
additional control measures and the need for an enforceable boundary
limit after the effects of the required control actions are assessed.
This assessment will involve a comparison of ambient levels of arsenic
measured near the arsenic plant with ASARCO's records of operation for
the arsenic plant.  The Agency believes that this information will help
to identify operational practices that cause high ambient concentrations,
and the degree to which additional controls might reduce ambient arsenic
concentration levels.   In particular,  exceedances of the DOE standard

                                II-2-10

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would be investigated to determine the cause and to suggest possible
control  measures.  The review may also consider the need for requiring
periodic review of emissions and control measures to ensure the continued
effectiveness of the housekeeping plan.
                                II-2-11

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 Item  Number  in
 Docket  A-80-40
                           11-3.0   REFERENCES*
 II-D-42
 II-J-10
 III-B-1
 IV-A-6
 IV-B-6
IV-B-10
IV-C-120
IV-C-458
 Letter  and attachments  from Varner,  M.O.,  ASARCO,
 Inc., to  Farmer, J.R.,  U.S. Environmental
 Protection Agency.  March  16,  1983.   Response  to
 Section 114 request for information.

 Occupational  Exposure to Inorganic Arsenic;  Final
 Standard, Chapter XVII, 29 CFR  Part  1910.  Occupa-
 tional  Safety and Health Administration.   43 FR
 19584.  May 5,  1978.

 Inorganic Arsenic Emissions from High-Arsenic
 Primary Copper  Smelters - Background  Information
 for Proposed  Standards  (Draft EIS).   U.S.  Environ-
 mental  Protection Agency.  Research  Triangle Park,
 N.C.  Document  No. EPA-450/3-83-009a.  April 1983.

 Emission Test Report, Arsenic Sampler Comparison,
 ASARCO, Inc., Tacoma, Washington.  Prepared by
 PEDCo Environmental, Inc., for  U.S.  EPA, Research
 Triangle Park,  N.C.  EMB No. 83-CUS-20.  January
 1984.

 Letter  from Vervaert, A.E., U.S. Environmental
 Protection Agency, to Zimmer, C. , PEDCo Environ-
 mental, Inc.  August 25, 1983.  Transmittal of
 main stack arsenic emission estimates for  ASARCO-
 Tacoma.

 Letter and enclosures from Vervaert, A.E., U.S.
 Environmental  Protection Agency, to Schewe, 6.F.,
 PEDCo Environmental, Inc.  October 28, 1983.
 Technical  background on low-level arsenic  emission
 estimates for ASARCO-Tacoma.

 U.S. Environmental  Protection Agency, Region X.
 News release to the public regarding new data on
arsenic emissions from ASARCO-Tacoma.  October 20,
 1983.

 Letter and enclosures from Ajax, R.L., U.S.
Environmental  Protection Agency, to Newlands,
J.C., Eisenhower, Carlson, Newlands, Reha, Henriot,
and Quinn.  March 9, 1984.   Transmittal to eight
addressees of several  items related to development
of standard for ASARCO-Tacoma.
*Lists references cited in Section II, including appendices.  Appendix
 A contains a listing of public comment letters on the proposed standards

                                 II-3-1

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 Item Number  in
 Docket A-80-40
 IV-D-447
IV-D-802
IV-E-23
IV-E-77
IV-I-3
 Letter and enclosures from Cant,  S.M.,  Washington
 State Department of Labor and Industries,  to
 Whaley,  G.,  Pacific Environmental  Services,  Inc.
 October  5,  1983.   Transmittal  of  copies of the
 Tripartite Agreement for ASARCO-Tacoma.

 Letter and enclosures from Lindquist, L.W.,
 ASARCO,  Inc.,  to  Ajax,  R.,  U.S. Environmental
 Protection Agency.   June 27,  1984.   Notification
 of ASARCO's  intention to terminate  copper  smelting
 operations  at  Tacoma  smelter.

 Memorandum from Meyer,  J.,  Pacific  Environmental
 Services,  Inc., to  meeting  attendees at December 20,
 1983  meeting with  interested  parties on  proposed
 NESHAP.  December  23,  1983.  Handouts containing
 modeling results and  suggestions for emission
 control at ASARCO-Tacoma.

 Memorandum from Meyer,  J.,  Pacific  Environmental
 Services,  Inc., to  Chaput,  L., U.S. Environmental
 Protection Agency.  January 20, 1984.  Minutes of
 meeting to discuss  modeling results and emission
 control alternatives  for ASARCO-Tacoma with
 interested parties.

 National Emission Standards for Hazardous Air
 Pollutants; Proposed Standards for  Inorganic
Arsenic, 40 CFR Part 61.  Reopening of public
 comment period.  U.S. Environmental Protection
Agency.  48 FR 55880.  December 16, 1983.
                                II-3-2

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        PART III - APPENDICES
             APPENDIX A

   LIST OF COMMENTERS ON PROPOSED
STANDARDS FOR HIGH- AND LOW- ARSENIC
      PRIMARY COPPER SMELTERS
               A-l

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               LIST OF COMMENTERS ON  PROPOSED STANDARDS*
   Docket  Item
     Number*
Commenter and Affiliationb
  IV-D-1;  IV-D-95;  IV-D-677;
  IV-F-10
  IV-D-2;  IV-D-37;  IV-D-90
  IV-D-3
  IV-D-4
  IV-D-5;  IV-D-93;  IV-D-530;
  IV-D-673
  IV-D-6
  IV-D-7
  IV-D-8
  IV-D-9; IV-F-9
 IV-D-10
 IV-D-11;  IV-D-127; IV-D-677
 IV-D-12
 IV-D-13
 IY-D-14
 IV-D-15
 IV-D-16
 IV-D-17
 IV-D-18;  IV-D-19;  IV-D-59;
 IV-D-64;  IV-D-222;  IV-D-445;
 IV-D-602;  IV-D-603; IV-D-620;
 IV-D-621;  IV-D-649; IV-D-691;
 IY-D-702;  IV-D-703; IV-D-714;
 IV-D-716;  IV-D-787; IV-D-792;
 IV-D-793;  IV-F-2C
*A11 items are in Docket A-80-40 unless otherwise noted.
                                A-2
  Susan and Robert Adams

  Ms.  Teresa Doyle
  Mr.  Hugh Kimball
  Ms.  Susan Anderson
 .Ms.  Sheri Reder

  Mr.  Eugene Fujimoto
  Ms.  Marilyn Muller
  Mr.  Craig.D. Hilborn
 Mr.  John  T. Konecki
  Chris Connery and Mary Scott
 Dr.  Robert E. Sullivan
 Mr.  Thomas M. Skarshaug et al_.
 Ms.  Virginia Nichols
 Mr.  Philip H. Abel son
 Ms.  Nathallie Fitzgerald
 Mr. James J. Mason
 Mr. T.C. White
 ASARCO,  Inc.
 Mr. L. W. Lindquist
 ASARCO,  Inc.

-------
   Docket  Item
     Number
 Commenter and  Affiliation13
 IV-D-20
 IV-D-21
 IV-D-22

 IV-D-23

 IV-D-24; IV-D-136

 IV-D-25; OAQPS-79-8/IV-D-3
 IV-0-26
 IV-D-27

 IV-0-28

 IV-D-29

 IV-D-30;  IV-D-283;  IV-D-383
 IV-D-31
 IV-D-32;  IV-D-677
 IV-D-33
 IV-D-34
 IV-D-35; IV-D-593; IV-F-9
 IV-D-36
IV-D-38; IV-F-10
IV-D-39
  Mr.  Duncan  Berry
  Mr.  Terry Sullivan
  Mr.  Hans Zeisel
  The  University of Chicago
   Law School
  Mr.  Hollis  Day
  Day's, Inc.
  The Warnaco Group
  Mr. Harvey  S. Poll
  Puget Sound Air Pollution Control
   Agency
  George and Adriana Hess
 Mr. Steve Burcombe
 Mr. Arnold Cogan
 Cogan & Associates
 Mr.  Frank M. Parker, III
 Southwest Occupational  Health
   Services,  Inc.
 Mr.  John  J.  Sheehan
 United  Steelworkers  of  America
 Mr.  Edward S.  Watts
 Mrs.  Del ores Keating
 Ms.  Sharon Rue
 Ms.  Joy Nelsen
 "A Concerned Citizen"
 Mr.  Ralph K. Garrison
 Ms. Barbara  Jensen
 B. J. Kanagy
Ms. Elise Muller Lindgren
                                 A-3

-------
Docket Item
Number
IV-D-40
IV-D-41
IV-D-42
IV-D-43; IV-D-114; IV-D-438
IV-D-44
IY-D-45
IV-D-46
IV-D-47
IV-D-48
IV-D-49; IV-D-375
IV-0-50
IV-D-51
IY-D-52
IV-D-53
IV-D-54
IV-D-55; IV-D-329; IV-D-687
IV-D-56
IV-D-57
IV-D-58; IY-D-253; IV-D-621;
IY-D-683
IV-D-60
IV-D-61
IY-D-62
IV-D-63; IV-D-435; IV-D-721;
IY-F-11

Commenter and Affiliation15
Ms. Patricia Ives
Ms. Rebecca L. Graves
Jam's and Gregory McElroy
Fred and Sue Campbell
David and Ann Beckwith Boberg
Ms. Susan Konecki
Vernon and Christine Trevellyan
Erica and Michael Meade
Mr. Richard L. Swenson
Ms. Elaine Taylor
Mr. Paul J. Braune
Ms. Hymen Diamond
Ms. Nancy Sosnove
Ms. Terry Patton
Ms. Patricia Bauer
Mr. E. Zahn
Mr. David Burcombe
Mr. Michael Higgins
Mr. Glenn L. Boggs
Mr. Toby Holmes
Ms. Laurie E. Martin
Mr. and Mrs. Donald R. Jopp
Ms. Irene Blackford
A-4

-------
  Docket Item
    Number
Commenter and Affiliation13
IV-D-65
IV-D-66
IV-D-67
IV-D-68
IV-D-69
IV-D-70

IV-D-71
IV-D-72
IV-D-73; IV-D-105; IV-D-302;
IV-D-575
IV-D-74
IV-D-75
IV-D-76; IV-D-117; IV-D-443;
IV-D-757; IV-F-11

IV-D-77
IV-D-78
IV-D-79
IV-D-80; IV-D-677
IV-D-81; IV-D-121
IV-D-82
IV-D-83
IV-D-84; IV-D-677
IV-D-85
 Ms. Ellen Ostern
 Mr. David Parent
 Mr. and Mrs.  Leo A.  Yuckert
 Ms. Mildred Schiffor
 Mr. R.W. Neuser
 Mr. Douglas P.  Coleman
 Coland, Inc.
 Mr. and Mrs.  Al Booze
 Ms. Olivia Watt
 Mr. Robert Krimmel

 Nancy Morgan  and Michael  Barnes
 Mr. Noel Daley
 Mr. Frank W.  Jackson
 Vashon-Maury  Island  Community
   Council
 Ms. Tammi L.  Contris
 Ms. Frances Wotton
 Mr. and Mrs.  Fuller
 Ms. Caroline  Hunter  Davis
 Mr. Robert Lipp
 Mary and Stephen Daniel
 Mr. Stanley C.  Smith
 Norene,  Vince,  and Patricia Gallo
 Mr. Timothy Walsh
 Greenpeace Northwest
                                  A-5

-------
Docket Item
Number
IV-D-86
IV-D-87
IV-D-88; IV-D-109; IV-D-676;
IV-F-11
IV-D-89
IV-D-91
IV-D-92
IV-D-94
IV-D-96
IV-D-97
IV-D-98
IV-D-99
IV-D-100
IV-D-101
IV-D-102
IV-D-103; IV-D-111
IV-D-104; IV-D-677
IV-D-106; IV-D-677
IV-D-107
IV-D-108; IV-D-589
IV-D-110
IV-D-112
IV-D-113
IV-D-115; IV-D-429
IV-D-116; IV-D-433
Commenter and Affiliation13
Ms.
Mr.
Ms.
Mr.
Ms.
Mr.
Ms.
Ms.
Mr.
Ms.
Ms.
Ms.
Ms.
Ms.
Ms.
Ms.
Mr.
Mary Lane
William Breitenbach
Diane Harris
Michael Maskule
Harriet Strasberg
J. Brady
Cheryl Owings
Deborah J. Mills
G. R. Finden
Laura H. Vaughn
Gertrude Quinn
Mona Brady
Rose Owens
Carol Howell
Dana Larson
Dorothy J. Sivertson
Scott Sruly
Terry Graves
Mr.
Ms.
Ms.
Percy W. Lewis
Pat Burke Tischler
Sandra Ellis
Katharine and Theodore Kowalski
Ms.
Rev.
Torn' Beckman
Merry Kogut
-A-6

-------
  Docket Item
    Number
Commenter and Affil iation13
IV-D-118; IV-D-126; IV-F-11
IV-D-119; IV-D-446; IV-D-648;
IV-D-710, 710a, 710b; IV-D-745;
IV-D-749; IV-D-759; IV-F-2C;
OAQPS-79-8/IV-D-33, 33a, 33b
IV-D-120; IV-D-621
IV-D-122; IV-D-723
IV-D-123

IV-D-124; IV-D-670

IV-D-125
IV-D-127
IV-D-128
IV-D-129
IV-D-130
IV-D-131
IV-D-132
IV-D-133; IV-D-485; IV-D-621
IV-D-134
IV-D-135
IV-D-137

IV-D-138
IV-D-139
 Dr. Ruth Weiner
 Sierra Club, Cascade Chapter
 Mr. David D. Doniger
 Natural  Resources Defense
   Council , Inc.
 Dr. Gilbert S. Omenn
 University of Washington
 School  of Public Health and
   Community Medicine
 Ms. Rose Orr
 Ms. Gail L. Warden
 Group Health Cooperative of
   Puget Sound
 Mr. Ted Dzielak
 Greenpeace Northwest
 Mr. Phillip A.M. Hawley
 Robert and Petra Sullivan
 Mr. C.R. Myrick
 Ms. Dana Griffin
 Mrs. S.C. Sandize
 Ms. Kathleen Hobaugh
 Mrs. G.R. Byrski
 Mr. Russell I. Lewis
 Ms. Jenny Binder
 Mrs. John E. Erickson
 Mr. Gene Alberts
 Pacific Sun Ltd.
 George  and Norma Newcomb
 Ms. Sue Hanson
 A-7

-------
  Docket  Item
    Number
Commenter and Affiliation13
IV-D-140; OAQPS-79-8/IV-D-6

IV-D-141; OAQPS-79-8/IV-D-7
IV-D-142
IV-D-143
IV-D-144; IV-D-719
IV-D-145

IV-D-146
IV-D-147
IV-D-148; IV-D-667
IV-D-149; IV-D-621;
OAQPS-79-8/IV-D-2
IV-D-150
IV-D-151; OAQPS-79-8/
IV-D-10
IV-D-152
IV-D-153
IV-D-154

IV-D-155

IV-D-156

IV-D-157

IV-D-158
 Mr. J.W. George
 Tennessee Chemical  Company
 Mr. David C. Roberts
 Mr. Del  Langbauer
 Ms. Diane Kay Davis
 Mr. Noel McLane
 Mr. Paul F. Munn
 City of Toledo
   Dept.  of Public Utilities
 Mr. Jeffrey P. Davis
 Ms. Johanna H. Mason
 Mr. Joe  Geier
 Mr. Douglas Frost,  Ph.D.

 Dr. Douglas A. Smith
 Walter and Dorothy  Pelech

 Ms. Leah Quesenberry
 Mr. Bill  Stewart
 Mr. R.J.  Kirrage
 National  Blower & Sheet Metal  Company
 Mr. Peter K.  Schoening
 Chemical  Proof Corporation
 Mr. C. W.  Bledsoe
 Canal  Industrial  Supply Company
 Mr. Richard  B.  Barrueto
 Carl  F.  Miller & Company
 Frank  and  Deborah Jackson
                                  A-8

-------
   Docket Item
     Number
Commenter and Affiliation13
 IV-D-159
 IV-D-160; IV-0-316; IV-D-453;
 IV-D-577; IV-D-658; IV-D-695
 IV-D-161
 IV-D-162
 IV-D-163
 IV-D-164; IV-D-666
 IV-D-165
 IV-D-166
 IV-D-167
 IV-D-168
 IV-D-169
 IV-D-170
 IV-D-171
 IV-D-172
 IV-D-173
 IV-D-174
 IV-D-175
 IV-D-176
 IV-D-177
IV-D-178
IV-D-179; IV-D-621
IV-D-180
IV-D-181
 Ms. Paula Bond
 Mr. Robert Bloom

 Mr. David Hakala
 Mrs.  Richard Tallman
 Mr. Thomas Jay Allen
 Ms. Mary G.L. Shackelford
 Ms. Mildred E. Blandford
 Ms. Elsie Wood
 Mr. Donald E. White
 Ms. Claudia Hurd
 Ms. B.J.  Hartman
 Mr. Ralph Brock
 Mr. Charles  E. Hochmuth
 Mr. John  F.  Mattes
 Mr. Richard  L. Barney
 Avelino and  Amelita  Soareuas
 Mr. and Mrs.  George  Kahl
 Mr. Harold T. Rock
 Mr. David Walkup
 Mr. Raymond  Garner
Mr. Owen T. Gallagher
Mr. Joe E. Bartosch
Mr. Richard Balles
                                 A-9

-------
   Docket  Item
     Number
 Commenter  and  Affiliation13
 IV-D-182

 IV-D-183

 IV-D-184

 IV-D-185

 IV-D-186; IV-D-352

 IV-D-187

 IV-D-188

 IV-D-189

 IV-D-190

 IV-D-191

 IV-D-192

 IV-D-193

 IV-D-194

 IV-D-195

 IV-D-196

 IV-D-197

 IV-D-198

 IV-D-199

 IV-D-200

 IV-D-201

 IV-D-202

 IV-D-203

IV-D-204

IV-D-205
 Mr. Al  Cook

 Mr. Eric  Zeikel

 Mr. Ben R. Petrie

 Ms. Mary  LaPI ant

 Mr. Lee R. Carl

 Mr. Stanton Neut

 Mr. Stephen J. Romanovich

 Mr. and Mrs. Dennis F. Keating

 Mr. Glenn E.  Enzler

 Mr. and Mrs.  Richard Rader

 Mr. Maurice C. Killenbeck

 Mrs. L.G.  Tallman

 Mr. Warren Mattson

 Mr. Marion Beach

 Mr. Robert L.  Sprague

 Mr. R.  Andress

 Clarence and  Lorene  Borell

 Mr. D.L. Bean

 Mr.  Robert D.  Hughes

 Mr.  and  Mrs.  Roy  Nybeck

 Mr.  John Fuller

Mr.  Norman D. Bond

Mrs. C.W.  Koski

Mr.  Gerald E. Johnson
                                  A-10

-------
Docket Item
Number
IV-0-206
IV-D-207
IV-D-208
IV-D-209
IV-D-210
IV-D-211
IV-D-212
IV-D-213
IV-D-214
IV-D-215
IV-D-216
IV-D-217
IV-D-218
IV-D-219
IV-D-220
IV-D-221
IV-D-223
IV-D-224; OAQPS-79-8/IV-D-11
IV-D-225
IV-D-226
IV-D-227; IV-D-621
IV-D-228
IV-D-229
Commenter and .Affi.1 iation*3
Mr.
Mr.
Mr.
Ms.
Mr.
Mai
Mr.
Mr.
Kenneth R. Leffler
Emil H. Novis
Robert A. Bowman
Shirley Welch
and Mrs. Jay Hensley
Van Nguyen
Harold E. Jorgenson
John Bentson Vale
Mr. Ron Streich
Streich Bros. Engineering
Mr.
Arthur J. Dunaway
Minnie and Al Greco
Doug and Kris ty Funkley
Mr.
Mr.
Mr.
Mr.
Mr.
Ms.
Mr.
Mr.
Mr.
Mr.
Mr.
Joseph Udovich
Robert Zimmerman
William Lobeda
Bill D. Roumel
Arnold Kese
Karen S. Kamp
Ben H. Roseberry
Daniel S. Dean
John C, Larsen
and Mrs. Pete McDonell
Harry D. Maxwell
A-ll

-------
  Docket  Item
    Number
Commenter and Affiliation13
IV-D-230
IV-D-231
IV-D-232
IV-D-233
IV-D-234
IV-D-235
IV-D-236
IV-D-237
IV-D-238
IV-D-239
IV-D-240

IV-D-241; OAQPS-79-8/IV-D-12
IV-D-242
IV-D-243
IV-D-244

IV-D-245
IV-D-246
IV-D-247
IV-D-248
IV-D-249
IV-D-250
IV-D-251
 Mrs. Matt Gunovich
 Mr. Adam S. Kreisman
 Mr. B.K. Arnberg, Jr.
 Mr. Alfred N. Johnson
 Mr. Henry Cox
 Mr. Homer T.  Brown
 Ross and Mildred Rice
 Mr. Joseph M. Stadtler
 Mr. Robert F. Sylvanus
 Mr. Wallace H. Larson
 Mr. Art Alsos
 Carl T. Madsen, Inc.
 Ms. Alice Spears
 Ms. Adah Green
 Mr. Charles E. Allen
 Mr. Robert Z. Primm
 Candid  Photo  Service, Inc.
 Ms. Kathleen  M. Brainerd
 Mr. Raymond R. Webster
 Mr. F.  Willard White
 Thomas  and Rosemary Arnold
 Willis  and Edith Powers
 Mr. & Mrs.  Arthur Keug
 Ms. Eleanor Schaffer
                                A-12

-------
  Docket Item
    Number
Commenter and Affiliation15
IV-D-252

IV-D-254  •
IV-D-255; IV-D-337
IV-0-256
IV-D-257
IV-D-258
IV-D-259
IV-D-260
IV-D-261
IV-D-262
IV-0-263
IV-D-264
IV-D-265
IV-D-266
IV-D-267
IV-D-268; IV-D-518
IV-D-269
IV-D-270
IV-D-271
IV-D-272
IV-D-273
IV-D-274
IV-D-275
 Mr. Frank C. Hansen
 Unico Service & Engineering
 Mrs. Lorette Prettyman
 Mr. Richard Tallman
 P.O. Dougherty
 Mr. Edward R. Kiehlmeier
 Ms. Alta F. Hyde
 Mr. Ernest Cooper
 Mr. Charles Mattheson
 Mrs. Ellen Manweiler
 R.D. Gallagher
 Richman and Forestbyne McNeil
 Mrs. Joe Sunich
 Mr. Ed Michalski
 Ms. Luvina Johnson
 Mr. Michael Mclntyre
 Mr. John Henderson
 Mr. Michael Evans
 Mr. Doss Bridges
 A.  P. Konick
 Ms. Mae Brown
 Mr. Lowell Jorgenson
 Mr. Paul DiMaio
 Frank and Del ores Keating
                                  A-13

-------
   Docket  Item
     Number
Commenter and Affiliation13
 IV-D-276

 IV-D-277

 IV-D-278

 IV-D-279

 IV-D-280

 IV-D-281
     .

 IV-D-282

 IV-D-284

 IV-D-285

 IV-D-286


 IV-D-287


 IV-D-288


 IV-D-289


 IV-D-290


 IV-D-291



 IV-D-292; IV-D-582;  IV-D-668

 IV-D-293

 IV-D-294

IV-D-295

IV-D-296
 E.M. Krisman

 Mr. Jack Stutler

 Erwin and Patricia Myers

 K.S. Hammond

 Mrs. P.M. Larson

 Mr. Frank Diane

 Florence Irvin and John Jurovich

 Mr. William Dearborn

 Mr. Leon Cunningham

 Mr. Richard Lowery
 Electric Motor Service Co.

 Mr. Fred Young
 E.  A. Wilcox Co.

 Mr. Kenneth  Sprong
 Harbison-Walker Refractories

 Mr. C.M.  Bevis
 Bevis &  Assoc., Inc.

 Mr. Laurence Evoy
 Pierce County  Medical

 Mr.  George Leonhard
 Mount Rainier  Council
  Boy Scouts of America

 Mr.  Mike  Cooney

 Mr.  Joseph Prinse

Mr.  Lee Fedderly

Ms. Marge Kunschak

Mr. John Vipond
Girard Wood Products
                                 A-14

-------
  Docket  Item
    Number
Commenter and Affiliation'3
IV-D-297
IV-D-298
IV-D-299
IV-D-300

IV-D-301; OAQPS-79-8/IV-D-13
IV-D-303

IV-D-304
IV-D-305
IV-D-306
IV-D-307

IV-D-308
IV-0-309

IV-D-310
IV-D-311
IV-D-312
IV-D-313
IV-D-314
IV-D-315
IV-D-317
IV-D-318; IV-D-621
IV-D-319; IV-D-621
IV-D-320
 Mr. Kenneth Griswold
 Mr. Robert Laughlin
 Mr. Walter Ivey
 Mr. William Taylor
 Flohr Metal  Fabricators
 Ms. Sally Davidson
 Mr. R.E.  Wendlandt
 Reliable  Steel  Fabricators
 Ms. Roxie Skidmore
 Mr. William Leonard
 Mrs.  Robert Schanzenbach
 Mr. Hugh  Williamson
 Pierce County Medical
 Mr. H. Eugene Quinn
 Mr. B.W.  Truswell
 Wenatchee Silica Products, Inc.
 Mr. Don Zemek
 Mr. Justice  Ashwell
 Harold and Anne Ransom
 Dr. and Mrs.  Robert Knapp
 Dr. Richard  G.  Schoen
 Herbert and  Charlotte Weston
 Mr. John  Susanj
 Mr. Coy Brown
 Mr. Bill  Weston
 Mr. and Mrs.  John  Reed
                                  A-15

-------
  Docket Item
    Number
Commenter and Affiliation^
IV-D-321
IV-D-322

IV-D-323
IV-D-324
IV-D-325
IV-D-326
IV-D-327
IV-D-328
IV-D-330
IV-D-331
IV-D-332
IV-D-333
IV-D-334
IV-D-335
IV-D-336
IV-D-338
IV-D-339
IV-D-340
IV-D-341
IV-D-342

IV-D-343
IV-D-344
IV-D-345
IV-D-346; OAQPS-79-8/IV-D-14
 Ms. Ruth Brown
 Mr. George Austin
 Austin Mac, Inc.
 Mrs. Ivy Blackburn
 Mrs. Robert Kling
 Malcolm and Laurel Ross
 Mr. Floyd Martin
 Mrs. Elizabeth Pedersen
 Ms. Laure Nichols
 Mr. John Dyer
 Mr. Kenneth Taylor
 Mr. and Mrs. Fredrick Young
 Mrs. Robert Guddes
 Charles and Thelma Modie
 Ms. Mary L. Mull in
 Mr. John Daly
 Mr. Arlander Bell
 Mr. Walter Kunschak
 Mr. Donald Angle
 Pete and June Zaferin
 Mr. Allan Weydahl
 Nalco Chemical  Co.
 Ms. Greta Dotson
 Mr. Charles Shaw
 Mr. Frank Puz
 Ms. Shermaine Celine
A-16

-------
   Docket Item
     Number
Commenter and Affiliation*5
 IV-D-347
 IV-D-348
 IV-D-349
 IV-D-350
 IV-D-351
 IV-D-353
 IV-0-354
 IV-D-355
 IV-0-356
 IV-D-357
 IV-D-358

 IV-D-359

 IV-D-360
 IV-D-361
 IV-D-362
 IV-D-363
 IV-D-364
 IV-D-365
 IV-D-366
IV-D-367
IV-D-368
IV-D-369
IV-D-370
 Mr. Warren Harvey
 Mr. Frank Storizic.
 W.  Phelps
 Mrs.  Chris Mortensen
 Mr. Robert Ellener
 Ms. Ella Phillips
 Mrs.  Marjorie McMenamin
 Patrick and Nora Duggan
 Ms. Mary McCormack
 Mr. and Mrs.  Ervin Lee
 Mr. J.M. Will
 Tarn Engineering  Corp.
 Mr. S.  Evan Davies
 S.  Evan Davies & Associates
 Ms. Betty J.  Roberts
 Mr. and Mrs.  Garland Cox
 Ms. Janet Jacobson
 Ms. Frances Coats
 Ms. Ellen  Herigstad
 Mr. Fred  Wise
 D.M. Manning
 Mr. and Mrs. W.  Rieck
 Ms. 01 ga  Williams
Mr. Bill Merrill
Mr. and Mrs. Ray Lunger
                                A-17

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   Docket Item
     Number
Commenter and Affiliationb
 IV-D-371
 IV-D-372
 IV-D-373
 IV-D-374
 IV-D-376

 IV-D-377
 IV-D-378
 IV-D-379
 IV-D-380

 IV-D-381
 IV-D-382;  IV-D-621
 IV-D-384
 IV-D-385
 IV-D-386

 IV-D-387
 IV-D-388

 IV-D-389
IV-D-391
IV-D-392
IV-D-393
IV-D-394
 Mr. William Hanar
 .Mr. Albert DiLoreto, Sr.
 Anne and Grant Whitley
 Mr. Louis Burkey
 Mr. Gerald Copp
 Public Utility District #1
   of Chelan County
 Ms. Eva Malovich
 S.  Behrman
 Mr. Raymond Wall
 Mr. Jim Wilhelmi ,  Jr.
 The Stationers, Inc.
 Mr. George Jowell
 Mr. Floyd Uilliams
 Mr. Michael  Fabb
 Mr. Ken Reaj
 Mr.  William  Cammarano,  Jr.
 Cammarano Bros,  Inc.
 Mr.  M.J.  Burgess
 Mr.  D.S.  Skeie
 Industrial Mineral  Products,  Inc,
 Mr.  P.  McDougal
 G.D. Shipley
 Robert and Jan Van de Mark
 G.S. and Bernice Tallman
Ms.  Mildred Wall
                                  A-18

-------
    Docket  Item
      Number
 Commenter and Affiliation15
 IV-D-395
 IV-D-396
 IV-D-397
 IV-D-398
 IV-D-399
 IV-D-400
 •IV-D-401
 IV-D-402
 IV-D-403

 IV-D-404
 IV-D-405;  IV-D-621

 IV-D-406
 IV-D-407
 IV-D-408
 IV-D-409
 IV-D-410

 IV-D-411
 IV-D-412
 IV-D-413; IV-D-677
IV-D-414; IV-D-677
IV-D-415
IV-D-416
IV-D-417; IV-F-9
  Mr.  James Jacobsen
  M.C.  Teats
  Mrs.  June Gil son
  H.C.  Bauman
  Mr.  Ronald Roman
  Virginia  and  John  Weaver
  Mr. Manfred Bell
  Mr. Edwin  Briggs
  Mr. David  Griffiths
  Cornell, Weinstein & Griffiths
 Ms. Kathryn Keller
 Mr. Theodore Kennard
 B.A.  McKenzie & Co.
 A.J.  and Emily Charap
 Mrs.  Edna Carlson
 S.  Mladervich
 Mr. Glenn Roberts
 Mr. Frank D.  Pupo
 Sam's  Tire Service
 Ms. Carol  Van  Ginhoven
 Mr. Lloyd  Skinner
 Ms. Helen  Gabel
 Mr. Phillip Notermann
 Mr. Charles Wie
 Mr. Charles W. Olsen, Jr.
Mr. James Garrison
A-19

-------
  Docket Item
    Number
Commenter and Affiliation13
IV-D-418
IV-D-419
IV-D-420
IV-D-421
IV-D-422; IV-D-584
IV-D-423
IV-D-424
IV-D-425
IV-D-426
IV-D-427

IV-D-428
IV-D-430
IV-D-431
IV-D-432
IV-D-434
IV-D-436
IV-D-437
IV-D-439; IV-D-662;  IV-D-676
IV-D-440
IV-D-441; IV-D-664;  IV-D-676
IV-D-442
IV-D-443
 Mr. F. Andrew Bartels
 Mr. Philip Volker
 Ms. Patricia Howard
 Ms. Marianne Edsen
 Demelza Costa, et al.
 Robert and Elnora Turver
 Mrs. Cheryl Curtis
 Mr. and Mrs. Harold Feley
 Walt and Kathy Hansen
 Rev. John  Keliner
 Old St. Peter's Church
 Mr. Robert Burns
 01 eta Kerns
 Mr. Jon Fayst
 Mr. John Ellingson
 M.  J. Bunnell
 Mr. 6. Patrick Healy
 Ms. Joan Peterson
 Margie and Jeff Goulden
 Devitt and Debby Barnett
 Dr. John Van Ginhoven
 Mrs. Ray Hund
 Jeanne Snell and Frank Jackson
 Vashon-Maury Island Community
    Council
                                  A-20

-------
  Docket  Item
     Number
Commenter and Affiliationb
IV-D-444
IV-D-447;  IV-D-786

IV-D-448

IV-D-449;  IV-D-620;
IV-D-621;  IV-F-2C
IV-D-45Q
IV-D-451
IV-D-452
IV-D-454
IV-D-455
IV-D-456
IV-D-457
IV-D-458

IV-D-459
IV-D-460
IV-D-461

IV-D-462
IV-D-463
IV-D-464
IV-D-465
IV-D-466
IV-D-467
 Mr. David A. Frew
 Mr. Stephen Cant
 State of Washington Dept. of
   Labor & Industries
 Ms. Anita Fries
 Ohio State Clearinghouse
 Mr. Donald Robbins
 ASARCO, Inc.
 Mr. Ron Johnson
 Mr. Marion Brannon
 Ms. Cora Tolstrup
 Mr. Wayne Vanderflute
 Mr. F.  Steven Doman
 Mr. Mark Peterson
 Mr. Robert Daniel
 Pat Frostad
 Motors  & Controls  Corp.
 Mr. Robert Lawson
 Mr. William Scott
 Mr. Bailey Nieder
 Tacoma  Steel  Supply
 Mr. Hugh Wild
 Ms.  Elaine Thomas-Sherman
 Mr.  Sidney Peyton
 Mr.  Paul  Foslien
 Mr.  Sam  Smyth
 Mr.  Bill  Cope
                                  A-21

-------
   Docket Item
     Number
Commenter and Affiliation*5
 IV-D-468

 IV-D-469
 IV-D-470
 IV-D-471
 IV-D-472
 IV-D-473
 IV-D-474
 IV-D-475
 IV-D-476
 IV-D-477
 IV-D-478
 IV-D-479
 IV-D-480
 IV-D-481
 IV-D-482
 IV-D-483
 IV-D-484
 IV-D-486
 IV-D-487
 IV-D-488
 IV-D-489

 IV-D-490
IV-D-491
 Mr. Albert Behar
 Pierce County Medical
 Ms. Sheila McCanta
 Mr. Edgar E. King
 Ms. Mary Chouinard
 Rose and Floyd Murphy
 Mr. Russell  Johnson
 Ms. Helen Carnahan
 Ms. Lucille  01 sen
 Beatrice and George Peterson
 Mr. and Mrs.  Carroll  Thompson
 Ms. Norma Rozmen
 Ms. Marian Ganz
 Mr. John  Gaul
 Ms. Molly LeMay
 Mr. Joseph Petranovich
 Mr. Rohn  Burgess
 Mr. Jack  McGuirk
 Mr.  John  Watson
 Mrs. Georgann Gallagher
 Ms.  Alvinia Hagen
 Mr.  C. Mark Smith
 Tacoma-Pierce County  Economic
  Development Board
Mrs. Virginia Loomis
Del mer Pitts
A-22

-------
  Docket  Item
    Number
Commenter and Affiliation13
IV-D-492
IV-D-493
IV-D-494
IV-D-495

IV-D-496
IV-D-497
IV-D-498

IV-D-499
IV-D-500
IV-D-501
IV-D-502
IV-D-503
IV-D-504

IV-D-505

IV-D-506
IV-D-507
IV-D-508
IV-0-509
IV-D-510
IV-D-511
IV-D-512
  Mr. Robert Heaton
  Dr. Michael J. Jarvis
  Mr. Kenneth J. Haagen
  Mr. E.P. Stiles .
  Pierce County 'Medical Bureau, Inc.
  Beverly and Lawrence Sawtelle
  Mr. and Mrs. K.W. Mueller
  Ms. Frances Johnson
  InterAcc Co.
  P.  Fischer
  Ms. Betty M. Susan
  Mr. and Mrs. Duane Puyear
  Ms. Marie Bean
  Mr. Thomas G.  Stoebe
  Mr. Malcolm N. Thompson
  United Steelworkers of America
    Local  25
  Ms. Doris Adams
  Smelterman's Federal  Credit Union
  Mr. John Fink
  Mr. Wayne Harkness
  Herb and Shirley Godfrey
  Mr. and  Mrs.  A.R.  Glenn
  Mr. Donald S.  Leinum
  Mr. Paul  A. Schulz
  Gary and Nancy Ackman
                                  A-23

-------
Docket Item
Number
IV-0-513
IV-D-514
IV-D-515
IV-D-516
IV-D-517
IV-D-519
IV-D-520; IV-F-9
IV-D-521
IV-D-522
IV-D-523
IV-D-524; IV-D-554; IV-D-660
IV-D-525
IV-D-526
IV-D-527
IV-D-528
IV-D-529
IV-D-531
IV-D-532
IV-D-533
IV-D-534
IV-D-535
IV-D-536

Commenter and Affiliation15
Mr. Bailey Nieder
Columbia Energy Co., Inc.
Mr. E.T. McGrath
Ms. Beverly M. Migliore
Brown University
Department of Geological Sciences
Mr. Fred H. Smith
Cochrane Northwest, Inc.
Ms. Margaret J. Rowan
Mr. Robert R. Treanton
Pick Foundry Co.
Ms. Rayna Ho Hz
James and Jerry Brandfas
Mr. Jerry Michael Carlson
Mr. Wayne S. Mo en
Mr. Richard L. Franklin
Mrs. E. Gerie Fortier
Ms. Cheryl Kirkwold
Mr. James D. Gray
Mr. and Mrs. Al Wegleitner
Ms. Carol A. Krona
John and Doris Achman
Mr. Robert D. Hall
Mr. and Mrs. W.H. Buzzell
Ms. Ruth M. Johnson
Mr. Howard 0. Huggard
Mr. Kenneth Mensching and Family
A-24

-------
   Docket Item
     Number
 Commenter and Affiliation1*
 IV-0-537
 IV-D-538

 IV-0-539
 IV-D-540
 IV-D-541
 IV-D-542                    :
 IV-0-543
 IV-D-544
 IV-D-545;  IV-D-621

 IV-D-546

 IV-D-547
 IV-D-548
 IV-D-549; OAQPS-79-8/IV-D-15
 IV-D-550

 IV-D-551
 IV-D-552
 IV-D-553
 IV-D-555
 IV-D-556
 IV-0-557
 IV-D-558
IV-D-559
  Mr.  Robert D.  Budd
  Mr.  Gregory B.  Curwen
  Gierke,  Curwen, Metzler & Bobrick
  Mr.  and  Mrs.  Richard Perkins
  Mr.  R.M.  Kennard e* aU
  Mr.  T. Russell  Mager
  Ronald and JoAnn Roberts
  Mr.  and  Mrs.  Austin E.  Atwood
  Ms.  Ruby  M. Martin
  Mr.  Clyde H.  Hupp
  Pierce County Central Labor Council
   AFL-CIO
  Mr.  Mike  D. Perkins
  Don  H. Perkins, Inc.
  Mrs. Leonard Berglund
  Mr.  Marion W. Samuel son
  Mr.  Kenny Scott
  Mr.  W'.E.  Lightfoot
  Coffman Engineers,  Inc.
  Mr.  Robert Reinhart.
  Mr.  Robert F. Griffith
  Mr. W.A.  Palmer
  Mr. and Mrs. Clifford Lakin
  Ms. Stephanie Colony
  Mr. Don H. Hinkley
 Mrs.  Allan Lindstrom
 Mr. Bob L. Marshall
A-25

-------
   Docket Item
     Number
Commenter and Affiliation15
 IV-D-560
 IV-D-561

 IV-D-562
 IV-D-563
 IV-D-564
 IV-D-565
 IV-D-566

 IV-D-567
 IV-D-568

 IV-D-569
 IV-D-570
 IV-D-571

 IV-D-572
 IV-D-573; OAQPS-79-8/IV-D-17
 IV-D-574
 IV-D-576; IV-D-699
 IV-D-578
 IV-D-579; IV-F-9
 IV-D-580
IV-D-581

IV-D-583
 Mr. Kim de Rubertis
 Mr. A.B. Berg
 Industrial Mineral Products, Inc,
 Mr. David A. Pitts
 Mr. Paul E. Miller
 Mr. Duane A. Lindoff
 Mr. Richard Fundly
 Mr. Robert M. He!sell
 Wright Schuchart, Inc.
 Mr. R. Eccles
 Mr. Stephen F.  Politeo
 Lilyblad Petroleum, Inc.
 Mr. Stan Sable
 Ms. Mary Susanj
 Ms. Katherine Spiratos
 Brown  University
 Ms. Gretchen  C. Gerish
 Ms.  Mary E.  Cosaboom
 Ms.  Ellen McComb  Smith
 Mr.  Alf  G.  Anderson
 Adm. James  S. Russell
 Ms.  Laurie  Lehman
 Ms.  Jennifer  Paine
 Dr.  Colleen R. Carey
St.  Luke's Medical Bldg.
Toshio and Suzanne Akamatsu
St. Joseph Hospital
                                  A-26

-------
  Docket Item
    Number
Commenter and Affiliation'3
IV-D-585
IV-D-586
IV-D-587
IV-D-588
IV-D-590
IV-D-591
IV-0-592
IV-D-594
IV-D-595

IV-D-596
IV-D-597
IV-D-598
IV-D-599
IV-D-600
IV-D-601
IV-D-604; IV-D-609

IV-D-605
IV-D-606; IV-D-689
IV-D-607
IV-D-608; OAQPS-79-8/IV-D-18

IV-D-610
 Mr. Frank B. Terrill
 Ms. Lidona Shelley
 Mr. Brent Hartinger
 Ms. Constance Northey
 Mr. Michael  J. Curley
 Ms. Susan M. Hodge
 Ms. Miriam Bishop
 Mr. John Candy
 Mr. Daniel M. Nelson
 Princeton University
   Department of Religion
 Mr. Dwight Hoi combe
 Mr. Bruce Hoeft
 Mr. Lloyd D. Morrell
 Mr. Elliott McLean
 Ms. Betsy Allen
 Mr. Robert A. Erickson
 Mr. Gerald S. Pade
 Friends of the Earth,
   Northwest Office
 Mr. and Mrs. A. Derby
 Chris Combs
 Mr. Floyd 01 es
 Mr. Michael  Gregory
 Sierra Club, Grand Canyon Chapter
 Paul  and Sally Borgen
                                  A-27

-------
    Docket  Item
      Number
 Commenter  and  Affiliation13
 IV-D-611

 IV-D-612

 IV-D-613
 IV-D-614

 IV-D-615

 IV-D-616


 IV-D-617;  OAQPS-79-8/IV-D-19

 IV-D-618

 IV-D-619

 IV-D-620


 IV-D-620;  IV-F-2C

 IV-D-622

 IV-D-623
IV-D-624
 Mr.  Ake  Nygren
 Boliden  Metal 1  AB
   Sweden
 Mr.  Lloyd Oodd
 L-M-D  Electro-Silver Resource
 Ms. Virginia Mitchell
 Mr. James Tracht
 Pennwalt Corporation'
 Mr. Marvin Williams
 Washington State Labor Council
   AFL-CIO
 Mr. Arne Bjornberg
 Mr. Rolf Svedberg
   Boliden Metal 1  AB
   Sweden
 Mr. David F.  Zoll
 Chemical  Manufacturers Assoc.
 Mr. Christopher  DeMuth
 Office of Management & Budget
 Mr. James H.  Boyd
 Newmont Mining Corporation
 Mr.  R.J.  Moore,  F.C.  Schafrick,
 and J.C.  Martin
   Shea  &  Gardner  (for ASARCO)
   Dr.  Ian T.T. Higgins  (for ASARCO)
 Mr.  M.O.  Varner,  C.K.  Guptill ,
 C.R. Counts, and  D.E.  Holt
   ASARCO,  Inc.
 Mr.  Donald Moos
 Washington State
   Department of Ecology
Mr. William Mitchell
Mr. William Woolf
                                  A-28

-------
   Docket  Item
     Number
Commenter and Affiliation13
 IV-D-625; OAQPS-79-8/IV-D-20

 IV-D-626; OAQPS-79-8/IV-D-21

 IV-D-627
 IV-D-628

 IV-0-629
 IV-D-630
 IV-D-631
 IV-D-632
 IV-D-633
 IV-D-634

 IV-D-634; IV-F-2C

 IV-D-635
 IV-D-636
 IV-D-637
 IV-D-638
 IV-D-639
IV-D-640

IV-D-640; IV-F-2C

IV-D-640; IV-F-6C
 Mr.  J.F. McKenzie
 Pacific Gas & Electric
 Mr.  Richard Kamp
 Smelter Crisis Education Project
 Mr.  Thomas C. White
 Mr.  E.E. Ives
 Stearns-Roger Engineering Corp.
 Mr.  Brian Baird
 Mr.  John Thomas
 Mr.  Harmon Rulifson
 Mr.  Robert Matthews
 Mr.  Dennis Crumb!ey
 Mr.  A.V.J. Prather and K.E.  Blase
 Prather, Seeger, Doolittle & Farmer,
   Dr.  S.H. Lamm  (for Kennecott)
 Mr.  R.A.  Malone, Dr.  L.S.  Salmon,
 Dr.  H.A.  Lewis (for Kennecott)
 Mr.  and  Mrs.  LeRoy Annis
 Ms.  Evelyn Hildebrand
 Ms.  Lucy Fitch
 Ms.  Julie Reimer
 Mr.  Larry Jones
 Mr.  Floyd  Hoffman,  R.E.  Johnson,
 and  W.N.  Miller
   Phelps  Dodge Corporation
 Dr.  S.H.  Lamm, Mr.  T.L.  Cogut
 (for Phelps Dodge)
Mr.  F.P.  Mendola
 Phelps Dodge  Corporation
                                  A-29

-------
   Docket Item
     Number
Commenter and Affiliation*5
 IV-D-640; IV-D-704; OAQPS-79-8/
 IV-D-22; OAQPS-79-8/IV-D-32
 IV-D-641; OAQPS-79-8/IV-D-23

 IV-D-642; IV-D-750
 IV-D-643
 IV-D-644
 IV-D-645; IV-D-763; IV-D-770

 IV-D-646; IV-D-708 and  708a;
 IV-D-712; IV-D-767; IV-F-8
 IV-D-647
 IV-D-650

 IV-D-651;  IV-D-653

 IV-D-652

 IV-D-654

 IV-D-655
 IV-D-656
 IV-D-657
IV-D-659
IV-D-661
IV-D-663
 A. Coy and S. Christiansen
 Evans, Kitchel & Jenckes (for
   Phelps Dodge)
 Mr. Steven Kuhrtz
 New Jersey Dept. of Environmental
   Protection
 Ms. Yvonne Thomas
 Ms. Jeanette Wakeman
 Ms. Katherine German
 Dr. Thomas Douglas
 Allied Medical  Examiners
 Mr.  Michael  Wright
 United Steelworkers  of America
 Mr.  Victor Gawley
 Mr.  William  Evan
 Wharton  School  of Finance
   University  of Pennsylvania
 Mr.  James  Nolan
 Puget  Sound Air  Pollution Control
   Agency
 Washington State  Department of
   Social & Health  Services
 Mr.  Doug Sutherland
 Tacoma-Pierce County Board of Health
 Mrs. P.A. Aarrestad
 Mr. Joseph Shopin
Mr. Warner Matson
Mr. Dwight Kipp
Mr. Douglas Branson
David and Marti Lambert
                                  A-30

-------
  Docket Item
    Number
Commenter and Affil iationb
IV-D-664
IV-D-665
IV-D-669
IV-D-671
IV-D-672
IV-D-674
IV-0-675
IV-D-676; IV-D-677; IV-D-777

IV-D-678

IV-D-679
IV-D-680; IV-D-681

IV-D-682; IV-D-773
IV-D-684; IV-D-754;
IV-D-780
IV-0-685
IV-D-686
IV-D-688
IV-D-690
IV-D-692; IV-D-787; IV-D-792;
IV-D-793
IV-D-693; IV-D-764; IV-D-791
 Dr. John Van Ginhoven
 Mrs. Harold Hartinger
 Mr. Bradley Nakagawa, et al.
 Mr. Warren Wotten
 Ms. Annabelle Reed
 James and Debra Mains
 JonLee Joseph
 Sen. Slade Gorton
 U.S. Senate
 Ms. Susan Macrae
 Sierra Club
 Mr. Bernard Clouse
 Mr. Leonard Roberts
 Office of Budget and Management
   Ohio State Clearinghouse
 Mr. Floyd Frost, Ph.D.
 Washington Department of Social and
   Health Services
 Ms. Darcy L. Wright

 Mr. Jon Nuxoll
 Mrs. T.L. Radke
 Ms. Mary Clark  Lee
 Mr. Jack Callinsky
 Mr. Gerald McGrath
 Mr.  Arthur Dammkoehler
 Puget Sound Air Pollution Control
   Agency
                                  A-31

-------
  Docket Item
    Number
Commenter and Affiliation'
IV-D-694

IV-D-696

IV-D-697

IV-D-698; IV-D-731; IV-D-766;
OAQPS-79-8/IV-D-26; OAQPS-79-8
/IV-D-31; OAQPS-79-8/IV-D-34

IV-D-700
IV-D-701


IV-D-704a; OAQPS-79-8/IV-D-28



IV-D-705

IV-D-706


IV-D-707

IV-D-709

IV-D-711


IV-D-713

IV-D-715



IV-D-717; IV-D-722

IV-D-718


IV-D-720

IV-D-724
 Donald and Shirley Ferris

 Ms. Gail  Nordstrom

 Mr. Everett Lasher

 Mr. Robert Abrams
 Ms. Mary Lyndon
   New York State Department of Law

 Sven and Arvi  Halstensen
 Star Electric

 Mr. Jon Hi nek
 Greenpeace, U.S.A.

 Dr. Steven Lamm
 Consultants in Epidemiology &
   Occupational Health, Inc.

 Iskra Johnson

 Mr. John Roberts
 Engineering Plus, Inc.

 Ms. Margaret Wolf

 Mr. Larry Weakly

 Mr. Kurt Blase
 Prather,  Seeger, Doolittle & Farmer

 Mr. Francis Hull

 Mr. Phil  Nelson
 Washington State
   Department of Ecology

 Mr. James Harris

 Ms. Eileen Goldgeier
 Brown University

 Ms. Lizabeth Brenneman

 Mr. William Rodgers, Jr.
 University of  Washington
   School  of Law
                                  A-32

-------
   Docket  Item
     Number
Commenter and Affiliation^
 IV-D-725
 IV-D-726
 IV-D-727
 IV-D-728
 IV-D-729

 IV-D-730
 IV-D-732

 IV-D-733
 IV-D-734
 Mr. Hugh Mitchell
 Mr. Peter Andrews
 Mr. John Calnan
 Mr. Paul Karkainen
 Mr. Timothy Larson
 University of Washington
   Department of Civil  Engineering
 Ms. Debbie Huntting
 Mr. Peter Murray
 Vashon Business Assoc.
 Mr. Dan Schueler
 Joseph and Karen Bartle
IV-D-735
IV-D-736

IV-D-737
IV-D-738; IV-D-751; IV-F-9

IV-D-739

IV-D-740

IV-D-741

IV-D-742
IV-D-743
 Mr.  Frank Hagel
 Mr.  Robert Evans
 Purified Air Systems
 Washington Fair  Share
 Ms.  Jeanne Snel1
 Vashon-Maury Island Community
   Council
 Mr.  Douglas Easter!ing
 University of Wisconsin
   Department of  Psychology
 Mr.  Bruce Mann
 University of Puget Sound
   Department of  Economics
 Dr.  Jesse Tapp
 Seattle-King County Department of
   Public Health
 Mrs.  Anna Marie  Champ! ain
 Mr.  Brian Kameus
                                  A-33

-------
  Docket  Item
     Number
Commenter and Affiliation'3
IV-D-744
IV-D-746
IV-D-747; OAQPS-79-8/IV-D-24

IV-D-748
IV-D-752
IV-D-753
IV-D-755; IV-D-758;
OAQPS-79-8/IV-D-25
IV-D-756
 Ms. Lin Noah
 Kelly Wheat
 Dr. Thomas Godar
 American Lung Association
 Ms. Karen Langbauer
 Mr. Daniel Carlson
 Ms. Kathleen R. Harkins and
 Mr. Vernon W. Harkins
 Dr. W.  Dale Overfield
 Neurology and Neurosurgery Associates
   of Tacoma, Inc., P.S.
 Ms. Penny Perka
IV-D-760; IV-D-774
IV-D-761

IV-D-762

IV-D-765

IV-D-768

IV-D-769
IV-D-771

IV-D-772; OAQPS-79-8/IV-D-16

IV-D-775
 Mr.  Nils  Lucander
 Ms.  Mary-Win O'Brien
 United  Steelworkers  of America
 Mr.  Richard Dale Smith
 Port of Tacoma
 Mr.  G.D.  Schurtz
 Kennecott
 Ms.  Marjorie L.  Williams  and
 Ms.  Fern  Stephan
 Mr.  Lance Neitzel
 Mr.  Jeffrey Morris and
 Ms.  Cheryl  Platt
 Dr.  Philip J. Landrigan
 Centers for Disease  Control NIOSH
  .Robert  A.  Taft Laboratories
 Mr.  Norman  D. Dicks
 Member  of Congress
                                  A-34

-------
   Docket Item
     Number
Commenter and Affiliation*3
 IV-D-776


 IV-D-778


 IV-D-779

 IV-D-782

 IV-D-783

 IV-D-784

 IV-D-785


 IV-D-788


 IV-D-789


 IV-D-790


 IV-D-795; OAQPS-79-8/IV-D-9

 IV-D-800



 IV-D-801

 IV-D-810




IV-D-811


IV-D-812
 Mr. Rod Chandler
 Member of Congress

 Mr. John McCain
 Member of Congress

 Ms. Katherine M. Hayes

 Mr. Ross Schlueter

 Mr. Gary A.  Preston

 Mr. Dave Bateman

 Mr. Richard  W.  Rice
 Phelps Dodge Corporation

 Mr. R.A.  Mai one
 Kennecott

 Mr. M.O.  Varner
 ASARCO,  Inc.

 Mr. Richard  W.  Rice
 Phelps  Dodge  Corporation

 Ms.  Eve  R. Simon

 Mr.  J.D.  Dumelle
 State  of  Illinois
  Pollution Control Board

 Mr.  E.M.  Sterling

 Ms.  Denise Fort
 State of  New  Mexico
  Environmental  Improvement
  Division

Mr.  F.C. Schafrick
 Shea & Gardner  (for ASARCO)

Mr.  K.E. Blase
 Prather, Seeger, Doolittle & Farmer
  (for Kennecott)
                                  A-35

-------
   Docket Item
     Number
Commenter and Affiliation13
 IV-D-813
 IV-D-814
 IV-F-1
 IV-F-2C


 IV-F-3, -4, -5




 IV-F-6C



OAQPS-79-8/IV-D-1


OAQPS-79-8/IV-D-4

OAQPS-79-8/IV-D-5


OAQPS-79-8/IV-D-8


OAQPS-79-8/IV-D-27


OAQPS-79-8/IV-D-29
 Mr. S.J. Christiansen
 Evans, Kitchel  & Jenckes
   (for Phelps Dodge)

 Mr. Gordon Venable
 State of New Mexico
   Environmental  Improvement Division

 Public Hearing  transcript
 Thomas Jefferson Auditorium
   Department of Agriculture
   Washington, D.C.
   November 8, 1983

 Mr. Blake Early
 Sierra Club

 Public Hearing  transcripts
 Bicentennial  Pavillion
   Tacoma, Washington
   November 2-4,  1983

 Mr.  Rolf Svedberg
 Boll den Metal!  AB
   Sweden

 Mr.  Thomas J. Koralewski
 Libbey-Owens-Ford  Company

 Mrs.  Robert D.  Hartwig

 Mr.  H.  E.  Dean
 Plains Cotton Growers,  Inc.

 Mr.  Earl  W.  Sears
 National  Cotton  Council  of  America

 Mr.  J.T.  Barr
 Air  Products  and Chemicals, Inc.

 Dr.  Samuel  Mil ham,  Jr.
 Washington  State Department of Social
  and  Health Services
                                  A-36

-------
  Docket  Item
    Number
Commenter and Affiliation3
OAQPS-79-8/IV-D-30
 Dr. Ian Higgins
 University of Michigan
   School  of Public Health
aThis appendix lists docket comment references cited in Parts I
 and II of this document.

blf no affiliation is indicated, commenter is speaking as a private
 citizen.

cDocket item contains written testimonies submitted by several
 commenters at the public hearings, which are similar to their oral
 presentations.
                                 A-37

-------

-------
          APPENDIX B



SMELTER ARSENIC MASS BALANCES
            B-l

-------
                     SMELTER ARSENIC MASS BALANCES
B.I  INTRODUCTION
     This appendix contains diagrams showing current estimates of the
distribution of arsenic in process materials, dusts, and flue gases at
the 14 primary copper smelters considered "low-arsenic" at proposal.
The distributions represent the baseline control situation, which
includes currently installed controls and controls planned for the near
future, prior to the imposition of any control requirements under this
NESHAP.  These figures are similar to those presented in Appendix F of
low-arsenic BID, Volume I (EPA-450/3-83-010a), but most were revised
since proposal in response to new information submitted by the
respective copper companies.

     The changes made since proposal and the rationale for the changes
are discussed in Section 1-4 of this document.  All assumptions concerning
baseline configurations are unchanged,  except for Phelps Dodge-Ajo
(Figure B-10).  At proposal, oxy-sprinkle smelting was assumed for the
Ajo baseline configuration because this smelter was planning under a
consent decree to convert to this type  of smelting.  Since the smelter
has determined that it will  not now carry out this modification,  EPA
has revised the Ajo mass balance to reflect the operation of the  present
reverberatory furnace configuration.  Other changes were made primarily
because of new information received on  smelter arsenic inputs and the
distribution of arsenic exiting smelting vessels and converters.
                                 B-2

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  ARSENIC INPUT
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                      SETTLING
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                                                           TO STACK
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 INCO
FLASH
FURNACE
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     Figure B-2.   Arsenic  Distribution at  ASARCO-Hayden Smelter
                                        B-4

-------
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                 31.6 LB/HR
REVERTS
0.6  LB/HR
  SLAG TO FURNACE
1 7.7 LB/HR
Figure B-4.   Arsenic Distribution at  Inspiration  Consolidated-Miami  Smelter
                                             B-6

-------
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20.6 LB/HR
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      Figure B-8.   Arsenic Distribution at  Kennecott-McGill  Smelter
                                         B-10

-------
          DUST TO
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     1.21
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                                       0.27 LB/HR
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                                              RECYCLED SLAG
                                              TO REVERB
                          SLAG TO DUMP
                          0.81 LB/HR
   Figure  B-9.   Arsenic  Distribution  at Magma-San  Manuel Smelter
                                       B-ll

-------
           OUST TO
           FURNACE
ARSENIC
           1.4 LB/HR
            0.2 LB/HR
         1.6 LB/HR
               8.6
INPUT
6.6 LB/HR
"  LB/HR
                             3.3 LB/HR
                        DUST TO FURNACE
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               RECYCLED
              "SLAG
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                 SLAG
                 TO DUMP
                 2.2 LB/HR
                                                                   TO STACK
                                                                   3.37 LB/HR
                                                      0.07 LB/HR


                                                             ACID PLANT HASTE
                                                             0.63 LB/HR
SLAG TO
FURNACE
0.4 LB/HR
    Figure B-10.   Arsenic  Distribution  at  Phelps Dodge-Ajo  Smelter
                                            B-12

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                  TO STACK
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                                                      0.2 LB/HR
                        ACID PUNT
                        LIQUID EFRUENT
Figure  B-12.  Arsenic Distribution at Phelps  Dodge-Hidalgo Smelter
                                   B-14

-------
                              OFFGAS TO GAS CLEANING PLANT
                                    FLUX    BLISTER
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                OXYGEN
                SMELTING
                FURNACES
                  (2)
AR|ENIC. INPUT
    SLAG TO DUMP
    7.3 LB/HR
                                           13.7  LB/HR
Figure B-13.   Arsenic  Distribution at  Phelps  Dodge-Morenci  Smelter
                                      B-15

-------
                                               TO  STACK
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           OUST
 ARSENIC
 INPUT
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<   2.14 LB/HR
 1.31 LB/HR ' •
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  FURNACES
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                              SLAG
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                              0.5 LB/HR
                                       REFINERY SLAG 0.131  LB/HR
                                         SODA SLAG 0.026 LB/HR
                                                       SLAG TO
                                                       FURNACES
                                                       0.2 LB/HR
Figure B-14.   Arsenic Distribution  at  Copper Range-White Pine Smelter
                                           B-16

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              APPENDIX C



INORGANIC ARSENIC RISK ASSESSMENT FOR



       PRIMARY COPPER SMELTERS
                C-l

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                   INORGANIC  ARSENIC RISK ASSESSMENT FOR
                    LOW-ARSENIC  PRIMARY COPPER SMELTERS
C.I  INTRODUCTION

C.I.I  Overview

     The quantitative expressions  of  public  cancer risks' presented in this
appendix are based on (1)  a dose-response model that numerically relates
the degree of exposure to  airborne inorganic arsenic to the  risk of getting
lung cancer, and (2) numerical  expressions of public exposure to ambient
ai r concentrations of inorganic arsenic  estimated  to be caused by emissions
from stationary sources.  Each  of  these  factors is  discussed briefly below
and details are provided in the following sections  of this appendix.

C.I.2  The Relationship of Exposure to Cancer Risk
     The relationship of exposure  to  the risk of contracting lung cancer is
derived from epidemiological  studies  in occupational settings  rather than
from studies of excess cancer incidence
methods that have successfully revealed
exposure and cancer for substances such
and ionizing radiation, as  well  as for
 among the public.   The  epidemiological
 associations  between  occupational
 as asbestos,  benzene, vinyl chloride,
inorganic arsenic,  are not  readily
applied to the public sector,  with  its  increased  number of confounding
variables, much more diverse and  mobile  exposed population, lack of consoli-
dated medical records, and almost total  absence of historical exposure data
Given such uncertainties, EPA  considers  it  improbable that any association,
short of very large increases  in  cancer, can  be verified  in the general
population with any reasonable certainty by an epidemiological study.
Furthermore, as noted by the National Academy of  Sciences  (NAS)*, "...when
there is exposure to a material,  we are  not starting at an origin of zero
cancers.  Nor are we starting  at  an origin  of zero carcinogenic agents in
our environment.  Thus, it is  likely that any carcinogenic agent added to
the environment will act by a  particular mechanism on a particular cell
population that is already being  acted  on by  the  same mechanism to induce
cancers."  In discussing experimental dose-response curves, the NAS observed
that most information on carcinogenesis  is  derived from studies of ionizing
radiation with experimental animals and  with  humans which  indicate a linear
no-threshold dose-response relationship  at  low doses.  They added that
although some evidence exists  for thresholds  in some animal tissues, by and
large, thresholds have not been established for most tissues.  NAS concluded
that establishing such low-dose thresholds  "...would  require massive, expen-
sive, and impractical experiments ..."  and  recognized that the U.S. population
"...is a large, diverse, and genetically heterogeneous group exposed to a
large variety of toxic agents."  This fact, coupled with  the known genetic
variability to carcinogenesis  and the predisposition of some individuals to
some form of cancer, makes it  extremely  difficult, if not  impossible, to
identify a threshold.

     For these reasons, EPA has taken the position, shared by other Federal
regulatory agencies, that in the  absence of sound scientific evidence to
                                   C-2

-------
the contrary, carcinogens should  be  considered  to  pose  some cancer  risk at
any exposure level.  This no-threshold presumption is based on the  view
that as little as one molecule of a  carcinogenic substance may be sufficient
to transform a normal cell into a cancer cell.  Evidence  is available from
both the human and animal health  literature that cancers  may arise  from a
single transformed cell.  Mutation research with ionizing radiation in cell
cultures indicates that such a transformation can  occur as the  result of
interaction with as little as a single cluster  of  ion pa-irs.  In  reviewing
the available data regarding carcinogenicity, EPA  found no compelling
scientific  reason to abandon the  no-threshold presumption for inorganic
arsenic.

     In developing the exposure-risk relationship  for inorganic arsenic, EPA
has assumed that a linear no-threshold relationship exists at and below the
levels of exposure reported in the epidemiological studies of occupational
exposure.  This means that any exposure to inorganic arsenic is assumed to
pose some risk of lung cancer and that the linear  relationship between cancer
risks and levels of public exposure  is the same as that between cancer  risks
and levels  of occupational exposure.  EPA believes that this assumption is
reasonable  for public health protection in light of presently available
information.  However, it should be  recognized  that the case for  the  linear
no-threshold dose-response  relationship model for  inorganic arsenic is not
quite as strong as that for carcinogens which interact  directly or  in
metabolic form with DNA.  Nevertheless, there is no adequate basis  for
dismissing  the linear no-threshold model for inorganic  arsenic.   Assuming
that exposure has been accurately quantified, it  is the Agency's  belief
that the exposure-risk  relationship used by EPA at low  concentrations
represents  only a plausible upper-limit risk estimate in  the sense  that the
risk is probably not higher than the calculated level  and could be  much
lower.

     The numerical constant that defines the exposure-risk  relationship
used by EPA in its analysis of carcinogens is called the  unit  risk  estimate.
The unit  risk estimate for an air pollutant is  defined  as the  lifetime
cancer  risk occurring in a hypothetical population in which  all  individuals
are exposed throughout their  lifetimes (about 70 years) to an  average con-
centration  of 1  ug/m-3 of the  agent in the air which they  breathe.  Unit
 risk estimates are used for two  purposes:  (1)  to  compare the  carcinogenic
potency of  several agents with each other, and (2) to give a crude  indication
of the  public health  risk which  might be associated with  estimated  air
exposure to these  agents.

     The unit  risk estimate for  inorganic arsenic  that is used in this
appendix was  prepared by combining the five different exposure-risk numerical
constants developed  from four occupational studies.^  The methodology used
to develop  the unit  risk estimate from the four studies  is described  in C .2
be 1ow.

C.I.3   Public Exposure

     The unit risk estimate  is only one of the factors needed  to produce
quantitative expressions  of public health  risks.  Another factor needed
                                    C-3

-------
is a numerical expression of public exposure,  i.e.,  the  numbers of
people exposed to the various concentrations of  inorganic  arsenic.  The
difficulty of defining public exposure was  noted by  the  National Task
Force on Environmental Cancer and Health  and Lung Disease  in  their 5th
Annual Report to Congress, in 1982.3  They  reported  that "...a  large
proportion of the American population works some distance  away  from their
homes and experience different types of pollution in their.homes, on the
way to and from work, and in the workplace. Also, the American population
is quite mobile, and many people move every few  years."  They also noted the
necessity and difficulty of dealing with  long-term exposures  because of
"...the long latent period required for the development  and expression
of neoplasia [cancer]..."

[The  reader should note that the unit risk  estimate  has  been  changed from
that  value used in the inorganic NESHAP proposal as  a result  of EPA's
analysis of several occupational epidemiological studies that have  recently
been  completed.]

      EPA's numerical expression of public exposure is based on  two estimates,
The first is an estimate of the magnitude and  location of  long-term average
ambient air concentrations of inorganic arsenic  in the vicinity of emitting
sources based on air dispersion modeling using long-term estimates of source
emissions and meteorological conditions.  The  second is  an estimate of the
number and distribution of people living in the  vicinity of emitting sources
based on 19BO Bureau of Census data which "locates"  people by population
centroids in census tract areas.  The people and concentrations are combined
to produce numerical expressions of public  exposure  by an  approximating
technique contained in a computerized model.   The methodology is described
in C.3 below.

C.I.4 Public Cancer Risks
       By combining numerical expressions of public exposure with  the unit
 risk estimate, two types of numerical expressions of public cancer risks are
 produced.  The first, called individual risk, relates to the person  or
 persons estimated to live in the area of highest concentration  as  estimated
 by the computer model.  Individual risk is expressed as "maximum lifetime
 risk."  As used here, the work "maximum" does not mean the greatest  possible
 risk of cancer to the public.  It is based only on the maximum annual average
 exposure estimated by the procedure used.  The second, called aggregate  risk,
 is a summation of all the risks to people estimated to be living within  the
 vicinity (usually within 50 kilometers) of a source and is customarily
 summed for all the sources in a particular category.  The aggregate  risk is
 expressed as  incidences of cancer among all of the exposed population after
 7U years of exposure; for convenience, it is often divided by 70 and expressed
 as cancer incidences per year.  These calculations are described in  more
 detail in C.4 below.

     There are also  risks of nonfatal cancer and other potential health
 effects, depending on which organs receive the exposure.  No numerical
 expressions of such  risks have been developed; however, EPA considers all
 of these risks when making regulatory decisions on limiting emissions of
 inorganic arsenic.

                                    C-4

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C.2  THE UNIT RISK ESTIMATE FOR  INORGANIC ARSENIC^
     The following discussion is  summarized from a more detailed description
of the Agency's derivation of the inorganic arsenic unit  risk estimate as
               "Health Assessment Document for Inorganic  Arsenic" (EPA-600/
found in EPA's
8-83-021F).
C.2.1  The Linear No-Threshold
 •'     Human Data (General)
                               Model  for Estimation of Unit Risk Based on
       The methodologies used to arrive at quantitative estimates of  risk
must be capable of being implemented using the  data  available  in existing
epidemiologic studies of exposure to airborne arsenic.  In order to extrap-
olate from the exposure levels and temporal  exposure patterns  in these
studies to those for which risk estimates  are required, it is  assumed
that the age-specific mortality rate of respiratory  cancer per year per
100,000 persons for a particular 5-year age interval,  i,  can be represented
using the following linear absolute or additive risk model:
                                     lOO.OOOa'O
                                                                   (1)
With this model, a-j is the age-specific mortality rate per year of  respira-
tory cancer in a control population not exposed to arsenic,  a1  is a  parameter
representing the potential of airborne arsenic to cause respiratory  cancer,
and D  is some measure of the exposure to arsenic up to the ith  age  interval.
For example, D might be the cumulative dose in .years-ug/m3,  the cumulative
dose neglecting exposure during the last 10 years prior to the  ith  age  inter-
val, or the average dose in ug/m3 over some time period prior to the ith  age
interval.  The forms to be used for D are constrained by the manner in  which
dose was treated in each individual epidemiologic study.  At low exposures
the extra lifetime probability of  respiratory cancer mortality  will  vary
correspondingly  (e.g., linearly).
     The dose-response data  available  in the epidemiologic studies for
estimating the parameters  in these  models consists primarily of a dose
measure Dj for the jth exposure group, the person-years of observation
the observed number of respiratory  cancer deaths Oj, and
these deaths expected in a control  population with the same
distribution as the exposure group. The expected number Ej
as
                                                                        j,
                                                                        f
                                                         the number Ej  o
                                                            sex and age
                                                            is calculated
                         Ei =
                                      100,000
 where
 gory
       YJi  is
      and the
             the
             jth
number of person-years  of
exposure group (Yj  = I Yj
 observation  in the  ith
;).   This  is  actually a
 (2)

age cate-
simplified
 representation,  because  the calculation also takes account of the change in
 the age-specific incidence  rates with absolute time.  The expected number
 of respiratory cancer deaths for the ith exposure group is
                  E(0j)  =  Z .Yj


                  -  EJ + a'YJ°J
                                      100,OOOa'Dj)/100,000
                                                                    (3)
                                     C-5

-------
under the linear absolute risk model.  Consequently,  E(0j) can be expressed
in terms of quantities typically available from the published epidemiologic
studies.

     Making the reasonable assumption that Oj  has  a Poisson  distribution,
the parameter a' can be estimated from the above equation using the method
of maximum likelihood.  Once this parameter is estimated, the age-specific
mortality rates for respiratory cancer can be  estimated  for  any desired ex-
posure pattern.

     To estimate the corresponding additional  lifetime probability of  res-
piratory cancer mortality, let bi ..... b^ be the mortality rates, in the
absence of exposure, for all cases per year per 100,000  persons for the age
intervals 0-4, 5-9 ..... 80-84, and 85+, respectively; let ai,...,ai8 represent
the corresponding rates for malignant neoplasms of the respiratory system.
The probability of survival  to the beginning of the ith  5-year age interval
is estimated as
                           n  [1 - 5bj/100,000]
                                                                    (4)
Given survival to the beginning of age  interval  i, the  probability of dying
of respiratory cancer during this 5-year interval  is  estimated as
                             i/100,000
                                              (5)
     The probability of dying of respiratory  cancer given survival to age
85 is estimated as ais/big-  Therefore,  the probability of dying of  respir-
atory cancer in the absence of exposure  to arsenic  can be estimated by:
17             i-1
z     C5ai/ioo,qoo)  ii d-5bj/ioo,ooo)3
                                                                       (6)
                                17
                                      -  5bj/100,000)
Here the mortality rates a-j  apply to the  target  population for which risk
estimates are desired, and consequently will  be  different from those in
(l)-(5), which applied to the epidemiologic study cohort.  If the 1976 U.S.
mortality rates (male, female, white, and non-white combined) are used in
this expression, then PQ = 0.0451.

     To estimate the probability P^p of  respiratory cancer mortality when
exposed to a particular exposure pattern  EP,  the formula (6) is again used,
but aj and bj are replaced by a-j(D-j) and  bi(D-j), where Di is the exposure
measure calculated for the ith age interval from the exposure pattern EP.
For example, if the dose measure used in  (1)  is  cumulative dose to the be-
ginning of the ith age interval  in ug/m3-yea rs ,  and the exposure pattern
EP is a lifetime exposure to a constant level of 10 ug/m , then D- =
(i-1) (5) (10), where the 5 accounts for the fact  that each age interval  has
                                   C-6

-------
a width of 5 years.  The additional  risk of  respiratory cancer mortality is
estimated as
                                 PEP  -  P0                           (7)
                                                         2
If the exposure pattern EP is  constant  exposure  to  1  ug/m , then PEP - PO is
called the "unit risk."

     This approach can easily  be modified  to estimate the 'extra probability
of respiratory cancer mortality by a  particular  age due to any specified
exposure pattern.

 C.2.2  Risk Estimates from Epidemiologic  Studies

     Prospective studies of the relationship between  mortality and exposure
to airborne arsenic have been  conducted for the  Anaconda  Montana smelter
and the Tacoma, Washington smelter.  Table C.I summarizes the fit of the
absolute  linear  risk model, to dose-response data  from 4 different studies
at the two smelters.   (See the "Health  Assessment  Document for Inorganic
Arsenic," Chapter  7, EPA-600/  8-83-021F for a detailed'description of
occupational studies.)  Table C.I also  displays  the carcinogenic potencies
a1.   It should be  noted that the potencies estimated  from different models
are  in different units, and are therefore  not comparable.

      The  estimated unit  risk is presented for each fit for which the chi-
square  goodness-of-fit  p-value is greater than 0.01.   The unit  risks derived
from linear models—8  in  all —range from 0.0013 to 0.0136.  The  largest of
these  is  from  the  Ott  et  al. study, which probably is the least  reliable for
 developing  quantitative  estimates, and which also involved exposures to
 pentavalent  arsenic, whereas the other studies involved trivalent  arsenic.
 The  unit  risks  derived from the  linear absolute-risk models  are  considered
 to be  the most  reliable;  although derived from 5 sets of data involving  4
 sets of  investigators  and 2 distant exposed populations, these  estimates
 are  quite consistent,  ranging  from 0.0013 to 0.0076.

      To establish  a  single point  estimate, the geometric mean for data sets
 is obtained within distinct exposed populations, and the final  estimate  is  .
 taken to be the geometric mean of  those values.  This process is illustrated
 in Table C.2.
                                     C-7

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TABLE C.2  COMBINED UNIT RISK ESTIMATES FOR ABSOLUTE RISK LINEAR  MODELS
Exposure Source
Study
Unit Risk
Geometric
Mean Unit    Final  Estimated
   Risk         Unit Risk
Anaconda smelter
Brown & Chu    1.25 x 10"3
Lee Feldstein  2.80 x 10"?
Higgins et al. 4.90 x 10~3
                                                 2.56 x 10-3
                                                              4.29 x 10-3
ASARCO
smelte
r
Ente
Ma
rline
rsh
&
6.81
7.60
x
x
10-3
10-3
7.19
x
10-3
C.3  QUANTITATIVE EXPRESSIONS OF PUBLIC EXPOSURE TO INORGANIC ARSENIC
     EMITTED FROM LOW-ARSENIC PRIMARY COPPER SMELTERS

C.3.1  EPA's Human Exposure Model (HEM) (General)

     EPA's Human Exposure Model is a general model capable of producing
quantitative expressions of public exposure to ambient ai r concentrations  of
pollutants emitted from stationary sources.  HEM contains (1) an atmospheric
dispersion model, with included meteorological data, and (2) a population
distribution estimate based on Bureau of Census data.  The input data  needed
to operate this model are source data, e.g., plant location, height of the
emission  release point, and volumetric rate of release temperature of  the
off-gases.  Based on the source data, the model estimates the magnitude  and
distribution of ambient air concentrations of the pollutant in the vicinity
of the source.  The model is programmed to estimate these concentrations
for a specific set of points within a  radial distance of 50 kilometers from
the source.  If the user wishes to use a dispersion model other than the
one contained in HEM to estimate ambient air concentrations in the vicinity
of a source, HEM can accept the concentrations if they are put into an
appropriate format.

     Based on the  radial distance specified, HEM numerically combines  the
distributions of pollutant concentrations and people to produce quantitative
expressions of public exposure to the pollutant.

C.3.1.1   Pollutant Concentrations Near a Source

     The  HEM dispersion model is a climatological model which is a sector-
averaged  gaussian dispersion algorithm that has been simplified to improve
computational efficiency.5 Stability array (STAR) summaries are the principal
meteorological input to the HEM dispersion model.  STAR data are standard
climatological f requency-of-occurence summaries formulated for use in  EPA
models and available for major U.S. meteorological monitoring sites from
the National Climatic Center, Asheville, N.C.  A STAR summary is a joint
f requency-of-occu rence of wind speed, atmospheric stability, and wind  direc-
tion, classified according to Pasquill's categories.  The STAR summaries in
                                    C-9

-------
HEM usually  reflect five years of meteorological  data for each  of  314 sites
nationwide.  The model produces polar coordinate receptor grid  points
consisting of 10 downwind distances located along each of 16 radials  which
represent wind directions.  Concentrations are estimated by the dispersion
model for each of the 160 receptors located on this grid.  The  radials  are
separated by 22.5-degree intervals beginning with 0.0 degrees and  proceeding
clockwise to 337.5 degrees.  The 10 downwind distances forr-each radial  are
0.2, 0.5, 1.0, 2.0, 5.0, 10.0, 20.0, 30.0, 40.0,  and 50.0 kilometers.  The
center of the receptor grid for each plant is assumed to be the plant center.
Concentrations at other points were calculated by using a log-linear  scheme
as illustrated in Figure C-l.

C.3.1.2  Expansion of Analysis Area

     At proposal, exposure and risk were estimated for people  residing
within 20 kilometers of the smelter.  Some commenters pointed out  that.
since people beyond 20 kilometers are exposed to  some level of  arsenic  due
to a source's emissions, EPA's proposal  analysis  underestimates the total
exposure and risk.  EPA agreed with the commenters and expanded its analysis
out to 50 kilometers.  When applying air dispersion models, the EPA's modeling
guidelines recommend that, because of the increasing uncertainty'of estimates
with distance from the modeled source and because of the paucity of validation
studies at larger distances, the impact may extend out to 50 kilometers, but
the analysis should generally be limited to this  distance from  the source.4
Such site-specific factors as terrain features (complex or flat),  the
objectives of the modeling exercise, and distance to which the  model  has
been validated will determine the appropriate distance (whether greater
than or less than the guideline distance) for which the Agency  should apply
the model.

C.3.1.3  Methodology for Reviewing Pollutant Concentrations

     Before making HEM computer runs, EPA reviewed small-scale  U.S. Geological
Survey topographical maps (scale 1:24000) to verify locational  data for each
arsenic source.  Plants were given accurate latitude and longitude values
which were then incorporated into the HEM program.

     After completing the HEM runs, nearby monitoring sites with ambient
air quality data were identified by a computer search of EPA's  National
Aerometric Data Bank (NADB)  (Table C.3).  At some sites, data collected over
several years along with annual  averages (based on different numbers of
sample sizes for the years monitored) for each year were available.   In these
instances, weighted multi-year averages  were calculated to provide an over-
all mean for each monitoring site.  For purposes  of annual mean calculations,
values measured below minimum detection  limits were considered  by  EPA to be
equal to one half the detection limit.  These ambient arsenic data were then
compared to HEM predicted values in order to gauge the accuracy of the  air
dispersion models' estimates.  As noted  above, HEM predicted values were
based on cencentrations at 160 polar coordinate receptor grid points consisting
of 10 downwind distances located along each of 16 radials which  represented
wind directions.  Because the actual  monitoring site locations  idenitifed
in the NADB retrieval usually did not correspond  to exact grid  point locations,
                                   C-10

-------
a log-linear interpolation scheme (Figure  C-l) was  used  to calculate an
estimated concentration at the site.

C.3.1.3.1  Use of Ambient Data

     Certain criteria were considered in review  of  ambient levels.  Mean
concentration values derived from sample sizes of  less than  25  data points
were disregarded.  When reviewing the available  monitoring data,  it appeared
that monitors situated at distances  greater than 15 km from  the arsenic
source were considered too far from  the source to  guage  air  dispersion
results without interference from other arsenic  sources. Furthermore, at
distances greater than 15 km from the sources, plant impacts were often
predicted to be significantly lower than minimum detection limits.  These
data were not incorporated in the analyses.  A third consideration in
reviewing ambient data concerned the percentage  of  monitored data which
fell below minimum detection limits.  Although some monitoring  sites
registered data with over 90% of the values above  minimum detection levels,
many had about half the data points  or jnore below  such levels and some had
less than 10% above detectable levels.  Instances  where  more than 50% of data
were below MDL were disregarded.  It should :be noted that Table C.3 displays,
in addition to company-collected data, all ambient  monitoring data that
were collected at sites within 15 kilometers of  the source as identified by
EPA's computer search although not all the data  were used in the  final analysis.

C.3.2  ASARCO-E1 Paso

       Predicted (HEM) versus measured data were plotted (Figure  C-2) and a
least squares weighted linear regression analysis  was run based on thirteen
data points  (see Table C.3).  The least squares  regression line (solid 1-ine)
was determined on the basis of a comparison of National  Aero metric Data Bank
monitoring data  (circumscribed dots) and ASARCO  monitoring data (circumscribed
Xs) with ambient concentrations predicted  by the Human Exposure Model.

     The  reader should note that a perfect fit for the  least squares  regression
analysis  results in a line running through the origin at a 45°  angle  (dotted
lines on Figures C-2 to C-3).  This  means  that,  if the HEM model  predicts the
measured data perfectly, then the data points would fall on  the dotted line.
In cases where the HEM model underpredicts concentrations, data points will be
located above the 45° perfect fit line. Likewise,  when  the  HEM model dverpredicts
concentrations, data points will be located below the perfect fit line.  The
 regression line  resulting from our compa rison of predicted and  monitored data
 runs nearly  parallel to the perfect fit line but intersects  the ordinate axis at
a value of approximately 0.09 ug/m3.  This result  is consistent with  the expectation
that air dispersion modeling would underpredict  ambient  concentrations.  The air
dispersion modeling did not consider other local sources of  arsenic such as
naturally-occurring arsenic in the windblown dust and reentrained arsenic
particulate  matter that had settled to the earth from past smelter emissions.
                                    C-ll

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Figure  C-l  Group 2 BG/ED Interpolation
                                                     Al
                                                  	A
Given:
A   -

Al  -

A2  -

R   -
Rl  -

R2  -

Cl  -
C2  -
The angle in radians subtended clockwise about the source from due
south to the BG/ED centroid;
The angle from due south to the radial line immediately counter-
clockwise of A, or passing through A if there is an exact match;
The angle from due south to the radial line immediately clockwise of
Al (A2 is 0 if it is due south);
The distance in km from the source to the BG/ED centroid;
The distance from the source to the largest circular arc of radius
less than R;
The distance from the source to the smallest circular arc of
radius greater than or equal to R;
The natural  logarithm of the concentration value at (Al, Rl);
The natural  logarithm of the concentration value at (Al, R2);
                                      C-14

-------
C3  -  The natural logarithm of the concentration value at  (A2, Rl);
C4  -  The natural logarithm of the concentration value at  (A2, R2);
then:
RTEMP - ln(R/Rl)/ln(R2/Rl);
ATEMP - (A-A1)/(A2-A1);
CA1   - exp(Cl + (C2-Cl)xRTEMP);
CA2   - exp(C3 + (C4-C3)xRTEMP); and
CX    - CA1 + (CA2-CAl)xATEMP,
where CX is the interpolated concentration at  the B6/ED centroid.
                                     C-15  '

-------
C.3.3  ASARCO-Hayden

       Predicted  (HEM) versus measured data were plotted (Figure C-3)  and  a
least squares weighted linear regression analysis was computed based on  a
number of data  points.  The least squares regression line (solid line),
calculated on the basis of NADB monitoring data and ASARCO's own monitoring
data  (circumscribed Xs), was plotted along with the data, points themselves
(circumscribed  dots).  As with the ASARCO-E1 Paso case, a second regression
analysis was  run without incorporating ASARCO monitored data.  The results
remained essentially the same.

C.3.4  Site-Specific Modeling

       In its original risk assessment, EPA did not consider terrain effects
or the effects  of buoyancy of the fugitive emissions escaping from the fur-
nace buildings.  These emissions originate from various sources, including
matte tapping,  converter, and anode furnace operations.  Because the fugitive
emissions are released from openings in the building roofs,  the emissions
can be entrained in the building wake on the leeward side of the furnace
buildings.  At  the same time, since the emissions are wanner than ambient
air, they tend  to rise.  Consequently, after experiencing downwash  initially,
the plume may lift-off, thus lowering ground-level  concentrations downwind.
However, this effect can be offset in the presence  of rising terrain.

     Since the  combined effect of terrain, downwash, and buoyancy on air-
borne arsenic concentrations was unclear, additional dispersion analyses
were carried out for two primary copper smelters.  The smelters examined
were those located at £1 Paso, Texas and Douglas, Arizona.   For the El Paso
analysis, the Industrial Source Complex Long Term (ISCLT) model and the
Valley model were used in conjunction with a joint  frequency distribution
of wind speed,  stability class, and wind direction.  The frequency  distribu-
tion was derived from on-site measurements of wind  speed and wind direction
and concurrent  cloud cover and ceiling height observations made at  El  Paso
International Airport.  The Valley model  was used for receptors above  the
top of the furnace buildings, while the ISCLT model  was  used at all other
receptors.  The Valley model allows the plume to intersect terrain  features
under stable atmospheric conditions, resulting in high concentrations.  For
receptors well above the plume center!ine, the impact of the plume  is  gradu-
ally reduced.   In order to better assess  the impact of buoyancy on  the
dispersion of the furnace building emissions, a modified plume  rise treat-
ment similar to that in the Buoyant Line  and Point  Source  (BLP)  model was
used.  In this treatment, the building emissions are regarded as  a  buoyant
line source having a finite length and width and subject to  an  initial
dilution associated with downwash.  However, because estimates  of the buoy-
ancy of the emissions are highly uncertain,  the analysis was repeated
assuming no buoyancy and therefore no plume  lift-off.  Both  analyses included
an enhancement to the dispersion of the plume due to building downwash, an
enhancement which is a part of  the ISCLT  model.  The two sets of  analyses
were intended to bracket the expected impact of the furnace  building emis-
sions on airborne inorganic arsenic  concentrations.
                                      C-16

-------
FIGURE C-2  Predicted Versus Measured
Inorganic Arsenic Ambient Concentrations
(ASARCO - El Paso, TX)
                                 MODEL
                                 OVERPREDICTION
UNDERPREDICTION
                                  Perfect Fit
                                  Linear Regression
                                  EPA Data
                                  Company Data
 0.2            0.4            0.6
    Predicted Concentration (jtg/m3)
                    C-17

-------
FIGURE C-3  Predicted Versus Measured
Inorganic Arsenic Ambient Concentrations
(ASARCO - Hayden, AZ)
                                      r MODEL          !
                                      I  OVERPREDICTION :
MODEL
UNDERPREDICTION
                                 	 Perfect Fit
                                      Linear Regression
                                  •-»   EPA Data
                                      Company Data
      0.1               0.2

   Predicted  Concentration (/Ag/m3)

                   C-13
                             0.3

-------
     Predicted (ISCLT/Valley) versus  measured  data  were  plotted  (Figure C-4)
and a least squares weighted linear regression analysis  was  run  based on
thirteen data points (see Table C.3).  The least  squares regression line
was determined on the basis of a comparison  of National  Aerometric Data Bank
monitoring data and ASARCO monitoring data with ambient  concentrations
predicted by the ISCLT/Valley model.

     Results obtained from HEM and the two site-specific analyses for El
Paso can be seen in Tables C.4 - C.6*  Table C.4  outlines  arsenic concentrations
estimated by the Human Exposure Model (HEM)  to occur at  16 wind  directions
and eight distances downwind from the El  Paso  plant center.  Table C.5
shows corresponding values based on the standard  ISCLT and Valley models
run in conjunction with a joint frequency distribution of  wind speed,
stability class, and wind direction.   Table  C.6 shows  values based on the
ISCLT and Valley models used in conjunction  with  modified  plume  rise
treatment.  Agreement between the HEM and ISCLT/Valley calculations is
fairly good with differences rarely exceeding  a factor of  2  or 3.  In
regions of higher concentrations, both models  give  nearly  equal  results.
The HEM tends to overpredict slightly in  regions  of lower concentration.

     A nearly identical approach was  taken for the  Douglas,  Arizona analysis.
The ISCLT and Valley models were used in  conjunction with  a  frequency distri-
bution of wind speed, stability class, and wind direction  derived from surface
weather observations at Bisbee/Douglas International Airport.  Two sets of
analyses were conducted, one including the effect of plume buoyancy associated
with fugitive emissions from the furnace  building and the  other  not.  As
before, the two sets of analyses were intended to bracket  the expected impact
of these emissions on airborne inorganic  arsenic  concentrations.

     Results obtained from HEM and the two site-specific analyses for
Douglas can be seen in Tables C.7 - C.9.   Table C.7 outlines arsenic
concentrations estimated by the HEM to occur at 128 points (see  above)
around the Douglas smelter.  Table C.8 shows corresponding values based on
the standard ISCLT and Valley models  run  in  conjunction  with a joint
frequency distribution of wind speed, stability class, and wind  direction.
Table C.9 shows values based on the ISCLT and  Valley models  used in
conjunction with modified plume rise treatment.  In general, the HEM tends
to underpredict slightly when compared to the  ISCLT/Valley model but the
differences between values estimated to occur  around the smelter rarely
exceed a factor of 2 or 3.

     At the  remaining copper smelters where  site-specific  air dispersion
analysis was not performed, .the standard   analysis  (HEM) as  described in
section C.3.1 was used.  Comparison of concentration profiles that were
predicted by HEM and the ISCLT/Valley models and  the comparison  of the two
modeling results to measured ambient concentrations indicate that the
standard HEM analysis produces similar results to the sophisticated air
dispersion models.  Since site-specific analysis  is resource intensive and
was not producing significantly different results from the standard analysis,
acceptable risk estimates for the remaining  smelters were  produced by the
HEM analysis.
                                    C-19

-------
                    FIGURE  C-4  Predicted Versus Measured

                    Inorganic  Arsenic Ambient Concentrations


                    (ASARCO -  El  Paso,  TX)
1.2  "I
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                                             C-26

-------
C.3.5  The People Living Near A Source

       To estimate the number and  distribution of people  residing within 50
kilometers of the smelter,  the HEM model uses the 1980 Master Area Reference
File (MARF) from the U.S. Bureau of Census.  This data base consists of
enumeration district/block  group (ED/BG) values.  MARF contains the population
centroid coordinates (latitude and longitude) and the 1980 population of
each ED/BG (approximately 300,000) in the United States  (50 States plus the
District of Columbia).  HEM identifies the population around each plant, by
using the geographical coordinates of the plant, and identifies, selects,
and stores for later use those ED/BGs with coordinates falling within 50
kilometers of plant center.

     For each of the fourteen smelter locations, a detailed check was made
to determine whether the exposed population as predicted  by the HEM was
located accurately.  A review of U.S. Geological Survey maps revealed some
discrepancies at ten of the smelter sites.  In these cases, the model
placed the populations near sites  which had High ambient  arsenic concentrations
but which clearly did not contain  settlements.  Such sites included tailings
ponds, railroad tracks and locations in  rugged terrain.   For the purpose of
risk and incidence estimation the  distance and bearing of actual exposed
populations were revised (Table C.10).

     For two smelter sites  in El Paso, TX, and Douglas, AZ, the maximum
concentrations to which individuals are exposed were derived originally
from HEM estimated values,  as seen in Table C.10.  To further refine
calculation of exposure and risk,  concentration estimates at those two
sites were modified using values from the ISCLT/Valley models used in the
site-specific analyses described in Section C.3.1.3.1.  These concentration
estimates are summarized in Table  C.ll.                  .

C.3.6  Exposu re5

       The Human Exposure Model (HEM) uses the estimated  ground level
concentrations of a pollutant together with population data to calculate
public exposure.  For each  of 160  receptors located around a plant, the
concentration of the pollutant and the number of people estimated by the
HEM to be exposed to that particula r concentration are identified.  The HEM
multiplies these two numbers to produce exposure estimates and sums these
products for each plant.

      A two-level scheme has been  adopted in order to pair concentrations
and populations prior to the computation of exposure.  The two-level approach
is used because the concentrations are defined on a radius-azimuth (polar)
grid pattern with non-uniform spacing.  At small radii, the grid cells are
usually smaller than ED/BG's; at large  radii, the grid cells are usually
larger than ED/BG's.  The area surrounding the source is  divided into two
regions, and each ED/BG is  classified by the  region in which its centroid
lies.  Population exposure is calculated differently for  the ED/BG's located
within each region.  For ED/BG centroids located between  0.2 km and 3.5 km
from the emission source, populations are divided between neighboring con-
centration grid points.  There are 64 (4 x 16) polar grid points within
                                  C-27

-------
this range.  Each grid point has  a  polar sector defined by two concentric
arcs and two wind direction radials.   Each  of these grid points and respec-
tive concentrations are assigned  to the  nearest ED/B6 centroid identified
from 1980 U.S. Census Bureau data.  Each ED/B6 can be paired with one or
many concentration points.  The population  associated with the ED/BG cen-
troid is then divided among all concentration grid points assigned to it.
The land area within each polar sector is considered in the apportionment.
                                                       * * "

     For population centroids between 3.5 km and  50 km from the source,
a concentration  grid cell, the area approximating a  rectangular shape
bounded by four  receptors, is much  larger than the area of a typical ED/BG.
Since there is an approximate linear  relationship between the  logarithm of
concentration and the logarithm of  distance for  receptors more than 2 km
from the source, the entire population of the ED/BG is assumed to be exposed
to the concentration that is logarithmically interpolated  radially and
arithmetically interpolated azimuthally from the  four  receptors bounding the
grid cell.  Concentration estimates for 96  (6 x  16) grid cell  receptors at
5.0, 10.0, 20.0, 30.0, 40.0, and 50.0 km from the source along each of 16
wind directions  are used as  reference points for this  interpolation.

     In summary, two approaches are used to arrive  at  coincident
concentration/population data points.  For the  64 concentration points
within  3.5 km of the source, the pairing occurs  at  the  polar  grid points
using an apportionment of ED/BG population  by land  area.   For the  remaining
portions of  the  grid, pairing occurs  at the ED/BG centroids themselves
through the  use  of  log-log and linear interpolation.   (For a  more detailed
discussion of the model used to estimate exposure,  see Reference 5.)

C.3.7   Public Exposure to  Inorganic Arsenic Emissions  from Low-Arsenic Primary
        Copper Smelters

C.3.7.1  Sou rce  Data

     Fourteen copper smelters  are  included in the analysis.   Table C.12  lists
the names  and addresses  of  the plants considered, and Tables  C.13-C.15 list
the plant  data used as  input to  the Human Exposure  Model  (HEM) for baseline,
converter  controls  and converter plus matte and slag tapping  controls
scenarios.

C.3.7.2  Exposure  Data

     Table C.16  lists, on  a plant-by-plant basis, the total  number of  people
encompassed  by the  exposure  analysis and the total  exposure.   Total  exposure
 is the  sum of  the  products  of  number of people times the ambient  air concen-
tration to which they are  exposed, as calculated by HEM.  Table C.17 sums,
for the entire source category (14 plants), the  numbers of people  exposed
to various ambient  concentrations, as calculated by HEM.  (Source-by-source
exposure results are provided  in the EPA docket  numbered A-80-40.)
                                    C-28

-------
                                       TABLE C.10  REVISIONS OF HEM PREDICTFn MAYTMMU
                                      CONCENTRATIONS TO WHICH IHDIVlK III EXPOSED
                         Baseline
  Source
  ASAKCO-
   Hayden

  Kennecott-
   Hayden

  Kennecott-
   Hurley

  Kennecott-
   McGi 11

  Kennecott-
  Garfield
               2.8


               4.0x10-1


               4.5x10-2



               9.6x10-1


               1.44x10-2
Phelps-Oodge   7.5x10-2
 Morenci

Phelps-Dodge   2.8x10-1
 Douglas****

Phelps-Oodge   5.0x10-2
 Ajo
                             2


                             6
 Phelps-Dodge   1.22x10-3   909
  Hidalgo

 Copper Range   2.5x10-2     lxlo-2    Ip08xlo_2     Q 3



  1.03x10-1   1.40x10-1   1.48x10-2   1.39x10-1    1.39x10-2     0.3


  1.44x10-2*  l 39x1(1-2   i iqvin-2*  i  oo  ,„  •>           o
             i.jyxiu     1.39x10 «:*  1.38x10-2   l.38xlO-2*    5.0*


  1.87x10-2   2.7x10-2   5.4x10-3    2.7xi0-2    5.2xi0-3      2 Q


 2.8x10-1*   4.5x10-2   4.5xlU-2*    4.5x10-2    4.5x10-2*


 5.0x10-2*   3.9x10-2   3.9x10-2*   3.9xlO-2    3.9x10-2*     ..«


 1.22x10-3*  8.1x10-4   8.lxlO-«*   8.1x10-"   8.1x10-"*     2.4.


 2.5x10-2*   3.5x10-3    3.5x10-3*   3.4xlO-3    3.4x10-3*     ..„


 3.8x10-2*   l.04xlo-2  l.04xio-2.   i.02xl0-2   i.n2xl0-2*   0.2*


 4.5x10-2    7.5x10-2   2.2x10-2     7 i in-2          7



1.32x10-2    1.08x10-2  2.4x10-3    1.05x10-2   2.0xl0-3      0.5
0.2*
          N



          SW



          SM



          NW



         W



         NE*



         NW


         N*
                                                                                                     NW*


                                                                                                     SSE


                                                                                                     SE
                               °f USGS ^ '" «*•«»* of  HEM predicted population 1ocations versus actual
  ^nc"^9ed--HEM r«ults are considered accurate

  ^^^!raftoh&T««r2
                                                  C-29

-------
                                              Table C.ll

                   Predicted Maximum Concentration to Which Individuals Are
                           Exposed at Two Primary Copper Smelter Sites
                              Based on ISCLT1 Site-Specific Modeling
Baseline
Source Cone
ASARCO- 2.7
El Paso
# Of
People
Exposed
<1
Revised
Conc^
2.2x10-1
Population
BAT Converter Controls Location
Cone Revised Cone2
2.7 2.1x10-1
Distance (km)
From Source Direction
1.0 N
Phelps-   1.93 x ID'2
 Dodge-
 Douglas
862
1.64x10-2
0.2
1 Industrial Source Complex Long Terra (Sensitivity)  (See Section C.3.1.3.1)

2 Revisions are based on review of USGS maps for comparison of ISCLT predicted population
  locations versus actual residential sites.
                                                 C-30

-------
                                 TABLE  C.12



           IDENTIFICATION OF LOW-ARSENIC  PRIMARY  COPPER  SMELTERS
Plant Number Code
Plant Name and Addres's
1
2
3
4
5
6
7
8
9
10
11
12
13
14
ASARCO, Inc.
El Paso, TX
ASARCO, Inc.
Hayden, AZ
Kennecott Corp.
Hayden, AZ
Kennecott Corp.
Hurley, NM
Kennecott Corp.
McGill, NV
Kennecott Corp.
Garfield, UT
Phelps-Dodge Corp.
Morenci, AZ
Phelps-Oodge Corp.
Douglas, AZ
Phelps-Dodge Cor.
Ajo, AZ
Phelps-Dodge Corp.
Hidalgo, NM
Copper Range Co.
White Pine, MI
Magma Copper
San Manuel , AZ
Inspiration Consolidated Copper Co.
Miami, AZ
Tennessee Chemical Co.,
Copperhill, TN
                                    C-31

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          TABLE C.16  TOTAL EXPOSURE AND NUMBER OF PEOPLE  EXPOSED
                    (LOW-ARSENIC PRIMARY COPPER SMELTERS)*
     Plant
     Total
   Number of
People Exposed
      Total
     Exposure
(People  -  ug/m3)
1
2
3
4
5
6
7
8
9
10
11
12
13
14
493,000
45,800
45,800
26,300
7,350
810,000
25,500
31,100
6,600
2,560
16,900
211,000
35,700
164,000
6230**
952
256
13
95
2350
46
355***
73
1
7
42
113
54
  * A 50-kilometer radius  was  used for the analysis of low-arsenic primary
    copper smelters.

 ** Value for total exposure calculated on the basis of site-specific analysis
    for ASARCO-E1  Paso,  TX was 2980.

*** Value for total exposure calculated on the basis of site-specific analysis
    for Phelps-Dodge-Douglas,  AZ  was  409.
                                      C-44

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                                       TABLE C.I7
                      PUBLIC  EXPOSURE  FOR LOW-ARSENIC COPPER SMELTERS
                          AS  PRODUCED  BY THE HUMAN EXPOSURE MODEL
            Concentration
           Level
Population
Exposed
(Persons)*
     Exposure
(Persons  -  ug/m3)**
                2.75
                2.5
                1.0
                0.5
                0.25
                0.1
                0.05
                0.025
                0.01
                0.005
                0.0025
                0.001
                0.0005
                0.00025
                0.0001
                0.00005
                0.000025
       1
       1
      22
     124
     664
    3980
   11700
   72500
  265000
  484000
 1100000
 1480000
 1520000
 1570000
 1660000
 1880000
 1920000
         3
         3
        31
        99
       283
       744
      1270
      3270
      6160
      7670
      9790
     10500
     10500
     10600
     10600
     10600
     10600
 *Column 2 displays  the computed value,  rounded to  the  nearest whole number, of the
  cumulative number of people exposed to  the  matching and higher concentration levels
  found in column 1.  For example, 0.5 people would be  rounded to 0 and 0.51 people
  would be rounded to 1.

**Column 3 displays  the computed value of the cumulative exposure to the matching
  and higher concentation levels found in column  1.
                                            C-45

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C 4  QUANTITATIVE EXPRESSIONS OF PUBLIC  CANCER RISKS FROM INORGANIC ARSENIC
     EMITTED FROM LOW-ARSENIC PRIMARY  COPPER  SMELTERS

C.4.1  Methodology (General)

C. 4.1.1  The Two Basic Types of Risk

     Two basic types of risk are dealt with in the analysis.   "Aggregate
 risk" applies to all of the people encompassed by the  particular analysis.
Aggregate  risk can be  related to a single source, to  all  of the  sources in
a source category, or to all of the source categories  analyzed.  Aggregate
 risk is expressed as incidences of cancer among  all of the people  included
 in the analysis, after 70 years of exposure.  For statistical  convenience,
 it is often divided by 70 and expressed as cancer incidences  per year.
 "Individual risk" applies to the person or persons estimated  to  live  in the
 area of the highest ambient air concentrations  and it applies  to the  single
 source associated with this estimate as estimated by the  dispersion model.
 Individual  risk  is expressed as "maximum, lifetime  risk" and  reflects  the
 probability of  getting cancer if one were continuously exposed to  the
 estimated  maximum ambient air concentration for 70 years.

 C.4.1 .2  The  Calculation of Aggregate Risk

      Aggregate  risk  is calculated by multiplying the total  exposure produced
 by  HEM (for a single source, a category of sources, or all  categories of
 sources) by the unit  risk estimate.  The product  is cancer incidences among
 the included  population after 70 years of exposure.  The total exposure,
 as  calculated by HEM,  is  illustrated by the  following equation:
Total Exposure
  N
= Z
                                         (P-jC-j)
 where

       Z  = summation over all  grid points  where  exposure  is calculated

      Pi  = population associated with grid point i,

      C-j  = long-term average inorganic arsenic concentration at grid point i,

      N  - number of grid points to 2.8 kilometers  and  number of ED/BG
           centroids between 2.8 and 50 kilometers  of each source.

 To more clearly represent the concept of  calculating aggregate  risk, a
 simplified example illustrating the concept follows:

                                   EXAMPLE

      This example uses assumptions  rather than  actual  data  and uses only
 three levels of exposure  rather than the large  number produced by  HEM.  The
 assumed unit  risk estimate is  4.29 x 10~3 at 1  ug/nr5  and the assumed
 exposures are:

                                     C-46

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            ambient  ai r
          concentrations
          2

          1

          0.5
          ug/m3

          gg/m3
         number of people exposed
          to given concentration

                 1,000

                10,000

               100,000
The probability of getting cancer if  continuously exposed to the assumed
concentrations for 70 years is  given  by:
   concentration

    2    ug/m3

    1    ug/m3

    0.5  ug/m3
                           unit  risk

                   x       4.29 x  ID"3  (ug/m3)-1

                   x       4.29 x  10-3

                   x       4.29 x  lO'3
                    probability of cancer

                         9 x lO'3

                         4 x 10-3

                         2 x 10-3
The 70 year cancer incidence among the people exposed to  these  concentrations
is given by:
probability of cancer
at each exposure level
number of people at
each exposure level
                                                              after 70 years
                                                                of  exposu re
9
4
2

x
x
X

10'3
io-3
lO'3

x
X
X

1
10
100

,000
,000
,000

9
40
200
TOTAL = 249
 The  aggregate  risk, or total cancer incidence, is 249 and, expressed
 as cancer incidence per year,  is 249  * 70, or 3.6 cancers per year.   The
 total  cancer incidence and cancers per year apply to the total of 111,000
 people assumed to  be  exposed to the given concentrations.

 C.4.1.3  The Calculation  of Individual Risk

      Individual  risk, expressed as "maximum lifetime risk," is calculated
 by multiplying the highest concentration to which the public is exposed, as
 reported by HEM, by the unit  risk estimate.  The product, a probability of
 getting cancer, applies to the number of people which HEM reports as being
 exposed to the highest listed  concentration.  The concept involved is a
 simple proportioning  from the  1 ug/m3 on which the unit  risk estimate is
 based to the highest  listed concentration.  In other words:
        maximum lifetime risk

      highest concentration to
      which people are exposed
                                  the unit risk estimate

                                           1 ug/m3
                                     C-47

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C.4.2  Risks Calculated for Emissions  of Inorganic  Arsenic from Primary
       Copper Smelters

     The explained methodologies for calculating maximum lifetime  risk and
cancer incidences were applied to each copper smelter,  assuming a baseline
level of emissions.  A baseline level  of emissions  means the  level of
emissions after the application of controls  either currently  in place or
required to be in place to comply with curent state or Fede'ral  regulations
but before application of controls that would be required by  a NESHAP.

     Tables C.18 and C.19 summarize the calculated risks. To understand the
relevance of these numbers, one should refer to the analytical uncertainties
discussed in section C.5 below.

C.4.2.1  Control Scenarios

     EPA completed HEM estimates of risk and incidence  for the baseline, or
no-control, case at each of 14 copper smelters (see discussion, Section
C.3.1.3).  Their estimates are outlined in Tables C.ll  and C-.12.   In order
to ascertain the effect on maximum individual lifetime  risk  and on annual
incidence, two pollution control scenerios were also examined.  Using
modified emissions estimates as inputs to the HEM model (Tables C.7 and
C.8), EPA calculated  risk and incidence values (Tables  C.ll  and C.12) for a
control option for converter operations only and a control option  covering
converter and matte and slag tapping operations.  Identical  procedures
were followed in  risk and incidence calculations for the baseline  and
control scenerios.

     For each of the fourteen smelter locations, a detailed  check  was made
to determine whether the location of the most exposed individual was
realistically placed by computer.  A  review of U.S. Geological  Survey maps
revealed some discrepancies at ten of the smelter sites.  In these cases,
the  model placed the populations  near sites which had high  ambient arsenic
concentrations but which clearly  did not contain settlements.  Such sites
included tailings ponds,  railroad tracks and locations in rugged terrain.
For  the purpose  of  risk and incidence estimation the distance and  bearing
of actual exposed populations were  revised.  In all cases where the point
of maximum exposure was changed,  that point  remained the same for  the
control cases as well.

C.5  ANALYTICAL  UNCERTAINTIES APPLICABLE TO THE CALCULATIONS OF PUBLIC
     HEALTH RISKS CONTAINED IN THIS APPENDIX

C.5.1  The Unit  Risk Estimate

     The procedure  used to  develop the unit  risk estimate is described  in
reference 2.  The model used and  its application to epidemiological data
have been the subjects of substantial comment by health scientists.   The
uncertainties are too complex to  be summarized sensibly in this appendix.
Readers who wish to go beyond the information presented in the reference
should see the following  Federal  Register notices:   (1) OSHA's "Supplemental
Statement of Reasons  for  the Final Rule", 48 FR  1864 (January 14,  1983);
                                     C-48

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                               mo ,n TABLE C'18  MAXIMUM LIFETIME  RISK
                               FOR LOW-ARSENIC PRIMARY COPPER  SMELTER  PLANTS


                                      Maximum Individual  Lifetime Risk
Source
— ——————— 	

ASARCO-E1 Paso** (a)
(b)
ASARCO-Hayden
Kennecott-Hayden
Kennecott-Hurley
Kennecott-McGill
Kennecott-Garf ield
Phelps Dodge-Morenci
Phelps Oodge-Douglas***
Phelps Dodge-Ajo
Phelps Oodye-Hidalgo
Copper Range-White Pine
Magma -San Manuel
Inspiration-Miami
Tennessee Copper-
Copperhill
Baseline

1 x 1U-3
6 x 10-4
1 x lO-3*
1.3 x 10-3
3 x 10~4
1.2 x 10-4
4 x lO'4
6 x 10-5
8 x 10-5
1.2 x 10-3
8 x 10-5*
2 x 10-4
5 x 10-6
1.1 X lO-4
1.6 x 10-4
1.9 x 10~4
6 x 10-5
Converter Controls
— ~"~— ~*™— ^ «~_ «_ _ «•»• «
8 x 10-4
5 x 10-4
9 x 10- 4*
1.2 x 10-3
5 x 10-5
5 x 10-5
6 x 10-5
6 x 10-5
2 x 10-5
2 x 10-4
7 x 10-5*
1.7 x 10-4
3 x 10-6
1.5 x 10-5
4 x 10-5
1.0 x 10-4
1.0 x 10-5
Converter & Matte ft 	
	 Slag Tapping Control
8 x 10-4
5 x ID'4
1.2 x 10-3
4 x 10-5
5 x 10-5
6 x 10-5
6 x 10-5
2 x 10-5
2 x UP4
2 x 10-4
3 x 10-6
1.5 x 10-5
4 x 10-5
9 x 10-5
8.6 x lO-6
                                                                 using  ISCLT/Valley model.

insufficient to make HEM exposure/risk ca cula?^n   r  H6XP°!"re' ava11able data are
dividual risk estimate for the Mex[cfn nonunion  ,r     Ude  (:st1mates  indicate that the in-
reported in the above table    Mexl«" P0pulat10n  ls  approx^nately the  same magnitude as


                                                        ex°— . -v.1l.bl. data are in-
risk estimate for the
                                                 C-49

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                                                 TABLE C.19
                       ANNUAL INCIDENCE ESTIMATES FOR ARSENIC PRIMARY COPPER SMELTERS

                                              Annual Incidence
Source
ASARCO-E1 Paso** (a)
(b)
ASARCO-Hayden
Kennecott-Hayden
Kennecott-Hurley
Kennecott-McGill
Kennecott-Garfield
Phelps Dodge-Mo renci
Phelps Dodge-Douylas**
Phelps Dodge-Ajo
Phelps Dodge-Hidalgo
Copper Range-White Pine
Hagma-San Manuel
Inspiration-Miami
Tennessee Copper-
Baseline
0.38
0.20
0.18*
0.058
0.016
0.0008
0.0058
0.14
0.0028
0.022
0.025*
0.0045
0.0001
0.0004
0.0026
0.0069
O.OU33
Converter Controls
0.29
0.18
0.16*
0.050
0.0054
0.0003
0.0015
. 0.14
0.0009
0.0081
0.013*
0.0038
0.0001
0.0002
0.0017
0.0034
0.0006
Converter & Matte &
Slag Tapping Controls
0.29
0.18
0.050
0.0043
0.0003
0.0014
0.14
0.0008
0 .0080
0.0038
0.0001
0.0001
0.0016
0.0023
0.0004
  CopperhiII

 * Represents incidence estimates  calculated  from site-specific analyses using ISCLT/Valley model.
** Althougn EPA recognizes the potential  Mexican  population exposure, available data are insufficient
   to make HEM exposure/risk calculation.  Crude  estimates indicate that the Mexican annual incidence
   is approximately of the same magnitude as  reported  in the above table.
                                                  C-50

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and (2) EPA's "Water Quality Documents Availability" 45 FR 79318 (November
28, 1980).

     The unit risk estimate used  in this analysis applies only to lung
cancer.  Other health effects  are possible; these include skin cancer,
hyperkeratosis, peripheral neuropathy, growth  retardation and brain
dysfunction among children, and  increase in adverse birth outcomes.  No
numerical expressions of  risks relevant to these health effects is included
in this analysis.

     Although the estimates derived from the various studies are quite
consistent, there are a number of uncertainties associated with them.  The
estimates were made from occupational studies  that involved exposures only
after employment age was  reached.  In estimating  risks from environmental
exposures throughout life,  it  was assumed through the absolute-risk model
that the increase in-the  age-specific mortality  rates of lung cancer was a
function only of cumulative exposures, irrespective of how the exposure was
accumulated.  Although this assumption provides an adequate description of
all of the data, it may be  in  error when applied to exposures thaj: begin
very early in life.  Similarly,  the linear models possibly a.re inaccurate
at low exposures, even though  they  provide  reasonable descriptions of the
experimental data.

     The  risk assessment methods  employed were severely constrained by the
fact that they are based only  upon  the analyses performed and reported by
the original authors—analyses that had been performed for purposes other
than quantitative risk assessment.  For example, although other measures of
exposure might be more appropriate, the analyses were necessarily based
upon cumulative dose, since that was the only  usable measure  reported.
Given  greater access to the  data from these studies, other dose measures,
as well as models other than the simple absolute-risk model, could be
studied.  It is possible that  such  wide analyses would indicate that other
approaches are more appropriate  than the ones  applied here.

C.5.2  Public Exposure

C.5.2.1  General
     The basic assumptions implicit in the methodology  are  that all exposure
occurs at people's residences, that people stay  at  the  same location for 70
years, that the ambient air concentrations and the  emissions which cause
these concentrations persist for 70 years, and that the concentrations are
the same inside and outside the residences.  From this  it can be seen that
public exposure is based on a hypothetical premise.  It is  not known whether
this  results in an over-estimation or an underestimation of public exposure.

C.5.2.2  The Public
     The following are relevant to the public  as  dealt  with  in  this analysis:
                                   C-51

-------
     1.  Studies show that all  people  are  not  equally  susceptible to cancer.
There is no numerical recognition  of the  "most susceptible" subset of the
population exposed.

     2.  Studies indicate that  whether or not  exposure to a particular
carcinogen results in cancer may be affected by the  person's exposure to
other substances.  The public's exposure  to other substances is not
numerically considered.                                 • "

     3.  Some members of the public included in this analysis are likely to
be exposed to inorganic arsenic in the air in  the workplace, and workplace
air concentrations of a pollutant are  customarily much higher than the
concentrations found in the ambient, or public air.   Workplace exposures
are not numerically approximated.

     4.  Studies show that there is normally a long  latent period between
exposure and the onset of lung  cancer. This has not been numerically
recognized.

     5.  The people dealt with  in the  analysis are not located by actual
residences.  As explained previously,  people are grouped by census districts
and these groups are located at single points  called the population centroids,
The effect is that the actual locations of residences  with  respect to the
estimated ambient air concentrations  are  not known and that the  relative
locations used in the exposure  model may  have  changed since the 1980 census.
However, for the population sectors estimated  to be  at highest  risk, U.S.
Geological Survey topographical maps were checked to verify that people did
live or could live in locations near the  sources as  modeled predictions
estimated.  Maps in certain instances  were old and the possibility could
not be  excluded that additional areas  near sources have been developed
since publication of the maps.

     6.  Many people dealt with in this analysis are subject to exposure to
ambient air concentrations of inorganic arsenic where they travel and shop
(as in  downtown areas and suburban shopping centers), where they congregate
(as in  public parks, sports stadiums,  and schoolyards), and where they work
outside (as mailmen, milkmen, and construction workers).  These types of
exposures are not numerically dealt with.

C.5.2.3.  The Ambient Air Concentrations
     The following are relevant to the estimated ambient air concentrations
of  inorganic arsenic used in this analysis:

     1.  Flat terrain was assumed in the dispersion model.  Concentrations
much higher than those estimated would result if emissions impact  on  elevated
terrain or tall buildings near a plant.

     2.  The estimated concentrations do not account for the additive impact
of  emissions from plants located close to one another.

     3.  The increase in concentrations that could result from re-entrainment
of  arsenic-bearing dust from, e.g., city streets, dirt roads, and  vacant
lots, is not considered.

                                    C-52

-------
     4.  Meteorological data specific  to plant sites  are  not used  in the
dispersion model.  As explained, HEM uses the meteorological data  from  the
STAR station nearest the plant site.  Site-specific meteorological  data
could result in significantly different estimates,  e.g.,  the estimated
location of the highest concentrations.

     5.  In some cases, the arsenic emission rates  are estimates that are
based on assumptions rather than on measured data.
                                    C-53

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C.6 REFERENCES

1.  National Academy of Sciences,  "Arsenic," Committee on Medical and
    Biological Effects of Environmental Pollutants, Washington, D.C., 1977.
    Docket Number (OAQPS 79-8)  II-A-3.

2.  Health Assessment Document  for Inorganic Arsenic  - Final Report EPA-600/
    8-83-021F March 1984, OAQPS Docket  Number  OAQPS 79-8; 1I-A-13.

3.  U.S. EPA, et.al., "Environmental  Cancer and  Heart and Lung Disease,"
    Fifth Annual Report to Congress by  the  Task  Force on Environmental Cancer
    and Health and Lung Disease, August,  1982.

4.  OAQPS Guideline Series, "Guidelines on  Air Quality Models".  Publication
    Number EPA-450/2-78-027, (OAQPS Guideline  No.  1.2-080).

5.  Systems Application, Inc.,  "Human Exposure to  Atmospheric Concentrations
    of Selected Chemicals."  (Prepared  for the U.S. Environmental Protection
    Agency, Research Triangle Park, North Carolina).  Volume  I,  Publication
    Number EPA-2/250-1, and Volume II,  Publication Number EPA-,1/250-2.
                                     C-54

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               APPENDIX D

       SUMMARY OF TEST RESULTS
FOR AIR CURTAIN SECONDARY HOOD SYSTEM
            AT ASARCO-TACOMA
                 D-l

-------
                        SUMMARY OF TEST RESULTS
                 FOR AIR CURTAIN SECONDARY HOOD SYSTEM
                           AT ASARCO-TACOMA

     From January  14 to 22, 1983, EPA performed a series of  tests to
evaluate the effectiveness of the air curtain secondary hood system
installed on the No. 4 converter at  the ASARCO-Tacoma smelter.  The
test program was designed to achieve two major objectives:
(1) estimation of  capture efficiency of the air curtain secondary hood
system; and (2) characterization of  the captured emissions.  Sample and
analytical procedures were performed by personnel from an EPA contractor
(PEDCo Environmental, Inc.), under the supervision of personnel from the
EPA Industrial Environmental Research Laboratory and the Emission Standards
and Engineering Division.  The complete, two-volume test report is
available in the docket (docket references IV-A-4 and IV-A-5).

D.I  AIR CURTAIN SECONDARY HOOD CAPTURE EFFECTIVENESS

     Three methods were tried to evaluate the air curtain secondary
hood capture effectiveness:  (1) mass balance using sulfur hexafluoride
(SFs) as a tracer; (2) opacity of emissions escaping through the air
curtain; and (3) visual emissions observations.

D.I.I  Gas Tracer Method

     For the gas tracer method, SF^ was injected into the controlled
area of the air curtain at constant, known rates of 30 to 50 cc/min for
periods that ranged from 15 minutes to 2 hours per injection.  Single
point samples of the exhaust gases from the air curtain hood were
collected at a downstream sampling location by pulling samples into 15-
liter, leak-free Tedlar bags for onsite gas chromatographic analysis.
The air curtain capture efficiency was calculated by comparing the SFs
injection mass flow rate with the mass flow rate calculated for the
downstream sampling point.

     Injections of SFs 9as were made at 16 sample points through
4 test ports in adjacent access doors on both sides of the converter
baffle walls.   The locations of the points are shown in Figures D-l and
D-2.  In addition to the efficiency measurements made for the points in
the primary testing area, several tests were performed at injection
points outside of this area (below the converter centerline) in an
attempt to characterize the effective capture area of the air curtain
hooding system, particularly during converter roll-out activities.

     On January 14, 1983, capture efficiencies were determined for
45 injection points in the controlled area.  The calculated mean effi-
ciencies by converter operational mode are presented in Table D-l.
The overall mean capture efficiency for all modes of operation was
93.5 percent.   With the exception of cold additions,  the operating mode of
the converter had little effect on the measured capture efficiency,
which ranged from 92.8 percent during blowing to 95.0 percent during
                                     D-2

-------
                                                                    HO. 4
                                                                  CONVERTER
                                 TOP VIEH
           JET SIDE
  AIR
CURTAIN |
  JET
    GRADE
            BAFFLE
            WALL
                             NO. 4 CONVERTER
                              (FUME SOURCE)
                                  LADLE
                                                      EXHAUST SIDE
BAFFLE
 HALL
                                                                 TO SUCTION FAN
                                                                            LEGEND:
                                                                                    AREA SAMPLED USING
                                                                                    MATRIX TRAVERSE
                   INJECTION LOCATIONS
                   SAMPLE I.D.

                   V SP1 & Z
                   O SP3 - 5
                   • SP7 - 12
                   O SP13 - 73
                                ELEVATION
                Figure  D-l.   SFg  Tracer  Injection  Matrix
                                                D-3

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                                   CONVERTER AISLE FLOOR
                                        O   INJECTION POINTS
Figure  D-2.  Tracer Injection Test  Ports
                       D-4

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      Table D-l.  AIR CURTAIN CAPTURE EFFICIENCIES AT ASARCO-TACOMA
                USING GAS TRACER METHOD - JANUARY 14, 1983

Converter
mode
Matte charge
Cold addition
Blowing
Slag skimming
Idle
TOTAL
Number of
injections
7
3
19
9
7
TfS~
Mean
Efficiency
93.1
102.0
92.8
95.0
93.4
93.5a
 Calculated  overall  mean  efficiency  assumes  the  converter  operation
  consists  of 80 percent blowing and  idle,  15  percent matte charge and
  cold  addition,  and  5  percent  slag skimming.


 slag skimming.   The  port  through which  the releases of  tracer gas were
 made did not have  any  effect on the  calculated efficiency.  However, it
 was found  that  sampling points tested through a  particular port exhibited
 considerable variation, generally recording higher capture efficiencies
 at positions 1  and 2 (exhaust  side)  than at position 3  and 4 (jet side).

     The remaining test series of 48 injections was performed on January
 17-18,  1983.' The  results of this series are summarized in  Table D-2.


     Table D-2.  AIR CURTAIN CAPTURE EFFICIENCIES AT ASARCO-TACOMA
              USING GAS  TRACER METHOD - JANUARY 17-19, 1983

Converter
mode
Matte charge
Cold addition
Blowing
Slag skimming
Copper pour
Idle
TOTAL
Number of
injections
6
3
27
7
4
4
5T~
Mean
Efficiency .
94.2
96.7
96.7
94.3
88.5
100.0
96. 5a
aCalculated overall mean efficiency assumes the converter operation
 consists of 80 percent blowing and idle,  15 percent matte charge  and
 cold addition, and 5 percent slag skimming and copper pour.


                                 D-5

-------
The  overall mean  capture efficiency  for  all  operational  modes was
96.5 percent.   As with  the  data  recorded on  January  14,  the  operating
mode appeared  to  have no significant effect  on  the individual calculated
efficiencies,  which  ranged  from  88.5 percent during  copper pouring  to
96.7 percent during  both blowing and cold additions.   However,  any
consistent, small variations  in  the  efficiencies  for  various modes,  if
they were  present, would be difficult to detect in the relatively small
number of  test runs  (injections)  that were made.  The  error  in  the
calculated air curtain  capture efficiencies  has been estimated  to be
+18  percent.   For this  second test series, it was also found that the
location of the test port had no effect  on efficiency,  while exhaust-
side efficiencies were  found  to  be somewhat  higher than  jet-side
efficiencies.   Test  results from the injection  points  in these  tests
indicate that  on  the average, about  95 percent  of the  gases  and
particulate matter in the area immediately above  the  converter  is
likely to  be captured by the  air curtain secondary hooding system.

      In addition  to  these two test series, a series of special  injection
point tests was conducted in  order to assess the effective capture area
of the secondary  hood system  outside the confines of  the hood.  The
special injection tests were  performed with  the injection probe at a
number of  points  on  the perimeter of the main test area,  such as very
close to the baffle  wall and  below the ladle during  the  matte charging
and  cold addition modes.  Table  D-3  shows the results  of this test
series.

      Table D-3.   AIR CURTAIN  CAPTURE EFFICIENCIES AT ASARCO-TACOMA
                FOR SPECIAL  GAS TRACER INJECTION POINTS  -
                          JANUARY 18-20,  1983

Converter
mode
Matte charge
Cold addition
Blowing
Slag skimming
Copper pour
Idle
TOTAL
Number of
injections
17
6
6
28
4
8
69~
Mean
Efficiency
61.8
61.5
33.0
84.0
80.8
53.8
49.4a
Calculated overall mean efficiency assumes the converter operation
 consists of 80 percent blowing and idle, 15 percent matte charge and
 cold addition, and 5 percent slag skimming and copper pour.
The overall average capture efficiency for the 69 special injection
points was 49.4 percent.  Unlike the first two test series, the capture
efficiency in the special series was sensitive to converter mode.  For
example, the slag skimming and copper pour efficiencies are higher, at

                                  D-6

-------
 84.0 and 80.8  percent, respectively, than  the other modes because of
 the position of  the  ladle  (above  the injection probe) during these modes.

 D.I.2  Opacity Measurement Method

     An opacity  monitor was mounted on  the top of  the air curtain below
 the crane rail in order to obtain information on emissions escaping
 capture by the air curtain and passing  through the slot.  A total of
 86 discrete observations were made with results ranging from 2 to
 54 percent opacity for the major  converter operations.  During slag and
 finish blowing,  no attenuation of the monitor's light beam was observed,
 indicating zero  percent opacity.  The instrument output range was 0 to
 20 milliamps, which  corresponds to 0 to 98.4 percent opacity.  The
 relationship of  the  instrument output to opacity is exponential, with
 5 nrilliamps corresponding  to 50 percent opacity.  Therefore, emissions
 during the test  program were in the lower  end of instrument response.
 No correlation between opacity and capture effectiveness could be made
 because of emissions from  the front of  the air curtain system.

 D.I.3  Visual Emissions Observation Method

     Two observers visually monitored the  air curtain capture effective-
 ness by noting the location, approximate opacity, and duration of
 visible emissions (see Section 1-6.4).  Their estimates of capture
 efficiency were  within 5 to 10 percent of  each other, with only a few
 exceptions.  Most variability in  the estimates occurred for those
 operations involving rapid evolution of emissions over a short period,
 such as roll-in, roll-out, and pouring.  The average of the observations
 for the various  converter  operating conditions displayed the same
 trends as the tracer experiments and indicates a reasonably effective
 capture of fugitives.

 D.I.4  Conclusions

     In summary, the visual observation and tracer recovery data
 indicated that the fugitive emissions capture effectiveness of the
 air curtain secondary hood is greater than 90 percent, averaging about
 94 percent overall.  The capture effectiveness during converter roll-in,
 roll-out, and slag skimming operations is more variable than during
 other converter  modes since fugitive emissions generated during these
 events are more  dependent  upon converter and crane operations.   It was
 also evident from the observations that capture efficiencies of 90 per-
 cent or better are achievable for these events under the proper crane
 and converter operating conditions to minimize fume "spillage"  into the
 converter aisle.

     Thermal  lift plays a significant role in increased collection
efficiencies for fume generated in the lower portion of the control
area.   Also,  the lower tracer recovery efficiencies for the various
converter roll-out modes are indicative of fume spillage outside of
 the control  area.

     It is believed that no practical  correlation can be made  between
opacities recorded by the  observers  and the transmissometer.  The

                                   D-7

-------
transmissometer was mounted perpendicular to the longitudinal axis of
the slot, whereas the position of the observers was such that their
view was parallel to the longitudinal axis of the slot, which resulted
in a considerably longer viewing length through the escaping emissions.
The apparent opacity increases as the path length through the emissions
increases.  Also, when positioned in front of the converter, the overhead
crane interfered with visual observations above the slot area.

D.2  ARSENIC EMISSION DATA

     Table D-4 summarizes the filterable and gaseous arsenic emissions
data for tests conducted by EPA Reference Method 5 and proposed Method
108.  Two sampling trains were used  to obtain the particulate and
arsenic samples.  Sampling was performed for the duration of each
converter cycle tested and during specific converter roll-out modes:
matte charge, slag skim, cold additions, and copper pouring.  Analysis
for filterable and gaseous arsenic was performed at the completion of
the gravimetric particulate determination.

     Arsenic concentrations are reported in milligrams per dry standard
cubic meter (mg/dscm) and grains per dry standard cubic foot  (gr/dscf).
Emission rates are expressed in kilograms per hour and pounds per hour.
The product of the concentration and the volumetric flow rate is the
mass emission rate.  For the total cycle tests  (designated PATC), the
measured flow rate obtained from the sample traverse was used in the
calculations.  For tests conducted during converter roll-out activities
(designated PASM), the average flow  rate obtained from the volumetric
flow evaluation of the high-flow mode was used  because these  tests were
performed at a single point in the duct.

     The filterable arsenic fraction represents material collected in
the sample probe and on the filter,  both of which were heated to
approximately 121°C  (250°F).  The gaseous arsenic fraction represents
material  that passed through the heated filter  and condensed  or was
trapped  in the impinger section of the sample train, which was maintained
at a temperature of 20°C  (68°F) or less.

     During the  total cycle tests, the filterable arsenic concentration
ranged from 1.35 mg/dscm  (0.0006 gr/dscf) to 3.89 mg/dscm (0.0017 gr/dscf),
and the  corresponding mass emission  rate ranged from 0.21 kg/h  (0.47  Ib/h)
to 0.61  kg/h  (1.36 Ib/h).  Gaseous arsenic  concentrations"during Tests
PATC-1 and PATC-3 were 0.28 mg/dscm  (0.0001 gr/dscf) and 0.44 mg/dscm
(0.0002  gr/dscf), respectively.

     During Test PATC-2,  the gaseous arsenic concentration was
5.02 mg/dscm  (0.002 gr/dscf).  The loss of  draft by  the primary hood
caused by operational problems at the  chemical  plant resulted in frequent
releases  of smoke and fumes from the primary hood.  During  this period,
particularly  in  the  converter blow mode, heavy  volumes of smoke escaped
the primary hood system, and some of these  emissions were captured by
the secondary hood.  Sampling continued throughout these intermediate
upsets,  but was  finally stopped when the air curtain control  system
became overwhelmed by continuous and heavy  emission discharge from the
primary  hood.   It appears  reasonable to conclude that  fugitive emissions
                                   D-8

-------







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generated by the malfunctioning primary hood draft contributed to the
higher arsenic concentrations observed during the second cycle test.

     During the specific mode tests, filterable arsenic concentrations
ranged from 4.98 mg/dscm (0.002 gr/dscf) to 9.01 mg/dscm (0.004 gr/dscf),
and corresponding emission rates ranged from 0.99 kg/h (2.18 Ib/h) to
1.98 kg/h (4.35 Ib/h).  Gaseous arsenic concentrations ranged from
0.24 mg/dscm (0.0001 gr/dscf) to 4.72 mg/dscm (0.002 gr/dscf) and the
corresponding emission rates ranged from 0.05 kg/h (0.11 Ib/h) to
0.99 kg/h (2.18 Ib/h).

     Table D-5 presents total arsenic emission factors in units of
pounds of arsenic emitted per ton of copper produced.  The total arsenic
emitted value for each run was calculated by adding the filterable and
gaseous fractions (in milligrams), using this value to calculate the
concentration and mass emission rate (in pounds per hour), and then
multiplying the mass emission rate by the time of the test (in hours).

     Arsenic emission factors for the total cycle tests ranged from
0.03 Ib/ton to 0.20 Ib/ton.  Arsenic emission factors for specific mode
Tests PASM-1 and -2 were 0.07 Ib/ton and 0.12 Ib/ton, respectively.
For Test PASM-3, which was run only during slag skimming operations,
the arsenic emission factor was 0.02 Ib/ton of copper produced.  During
this test, a total of 7.25 ladles of slag were skimmed from the
converter.  Based on information supplied by ASARCO, each ladle contains
12 to 15 tons of slag.  Therefore, between 87 and 109 tons of slag were
skimmed, which yields a skimming emission factor of about 0.025 pound
of arsenic per ton of slag skimmed.
                                  D-10

-------
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-------
             APPENDIX E
DEMONSTRATED CONTROL DEVICE PERFORMANCE
   TO ACHIEVE THE LIMIT FOR CONVERTER
          SECONDARY EMISSIONS
                 E-l

-------
               DEMONSTRATED CONTROL DEVICE PERFORMANCE
                  TO ACHIEVE THE LIMIT FOR CONVERTER
                         SECONDARY EMISSIONS

E.I  INTRODUCTION

     This appendix presents emission  test data on fabric  filter control
device performance in  the steel making industry and compares these
data to secondary (fugitive) emission streams from copper converter
operations.  The EPA has collected test data on the performance of
fabric filters collecting particulate emissions from electric arc
furnaces  (EAF's) and argon-oxygen decarburization (AOD) vessels for
developing new source  performance standards for the steel industry.
The use of fabric filters in the steel industry and design specifications
of these  control devices are discussed in Sections I-E.2  and I-E.3.
Characteristics of particulate emissions from EAF's and AOD vessels are
compared with secondary emission gas  streams from copper  converters in
Section I-E.4.

E.2  APPLICATION OF FABRIC FILTER CONTROL DEVICES IN THE  STEEL INDUSTRYl

     Fabric filter control devices are used in the steel  industry to
control emissions from EAF's and AOD  vessels.  EAF's are  refractory
lined, cylindrical vessels made of heavy welded steel plates and having
a bowl-shaped hearth and removable dome-shaped roof.  Scrap metal is
melted in EAF's by three graphite (or carbon) electrodes  that are
lowered into the vessel through ports in the roof.  AOD vessels are
used in some steel plants to refine steel that was melted in an EAF.
Argon, oxygen, and/or  nitrogen are introduced in various  proportions
and stages of the "heat" to control the metallurgical reactions.  Process
emissions occur during the melting and refining stages and can be
collected through direct-shell evacuation (on EAF's) or close fitting
hoods that are ducted  to fabric filters.  Secondary (fugitive) emissions
occur during the charging and tapping stages.  Secondary  emissions are
collected through hooding or building evacuation systems  and vented
to a fabric filter.  This same control device may also control process
emissions.

E.3  FABRIC FILTER DESIGN SPECIFICATIONS

     Design specifications reported for 21 fabric filter  control devices
used to control particulate emissions from EAF's and AOD  vessels are
presented in Table E-l.  Design parameters presented are: (1) type of
fabric filter (positive or negative pressure); (2) design gas flow; (3)
number of compartments; (4) type of bag; (5) air-to-cloth ratio; (6)
pressure drop; (7) gas temperature; and (8) type of cleaning mechanism.
Not all of the information was available for all plant locations.

     Positive pressure fabric filters force exhaust gas through the
filter media using a fan situated between the collection  duct and the
fabric filter.  Maintenance and filter bag inspection are easier than with
negative pressure units because the bag compartments are  not air-tight
and can be entered while the unit is in service (if the gas is not too
hot for personnel safety).   Particle-laden gas is drawn through the

                                  E-2

-------
  filter bags so that the particles are retained on the fabric;  the
  cleaned air is then vented  to  atmosphere through louvers or vents alonq
  the  top of each compartment.   Negative pressure type fabric filters  use
  a  fan  on the  clean  air  side of the control  device to pull  air  through
  the  bags.   Bag compartments must be kept air-tight,  and  so inspection  for
  defective  bags requires the compartment to  be  taken  off-line   The
  advantage  of  negative pressure fabric filters  is that they require less
  ran  maintenance and less  operating horsepower  than the positive pressure
  type.   New fabric filter  control  devices installed on EAF's are generally
  the  positive-pressure type  because of their  lower capital  costs and  the
  simple  inspection procedures for  detecting damaged bags. 2

  T  u-,  ^e  desi~9n 9as flows of the 21 fabric filters  presented  in
  Inn  nnn    range from 91,000 to 1,750,000 acfm,  with  an average  of  about
  500,000  acfm.   The  filters utilize  a  multiple  compartment  design,  with
  bags constructed of polyester  fabric.  Air-to-cloth  ratios range  from
  1.95 to  5.5, and operating pressure drops across  the  devices range from
  i.z  to 11  inches of water.  Maximum inlet gas  temperatures, available
  for only two plant  locations,  are  210°F  (99°C) and 275°F (135°C)
 Two bag  cleaning methods are used  - reverse air  flow  and mechanical
  shaking   The  reverse air flow mechanism  collapses the filter baqs
 while the shaker mechanism physically shakes the dust off  the bags.

 E.4  GAS STREAM CHARACTERISTICS

      Table E-2  presents a summary of particulate emissions data for
 fabric filter control devices used for EAF's and AOD  vessels.  Eight
 of the fabric filters are the positive pressure type  and three  are
 the negative pressure type.   The outlet concentrations for the  positive
 pressure EAF/AOD fabric filters range from 0.0002 to  0.0046 gr/scf
 nennn;VtnPnenn^Qe ffrlc fjlter outlet concentrations range from
 S  ??l/?nn i   9 gr/Scf'  Hence» fabrtc filter  contro1 devTces  applied
 to EAF/AOD furnaces  have demonstrated the ability to  achieve a  0^005
 gr/dscf emission limit.   The performance of  fabric filters  applied to
 EAF s and AOD  vessels is compared to the performance  of similar  devices
 on  copper converter  secondary gas stream emissions by examining  inlet
 grain loading  data and  the size distributions of the  particulate
 emissions in these two  types of gas streams.

 nf  thfVffll?!nnnleJ Par|1culate  concentrations were measured for  three
        c   /M,°  fabnc fllter contr°l devices and ranged from 0.0408
           gr/s?,f-  The Particulate concentration measured for the
                 ™   copper converter secondary  emission gas stream  was
                .    lnlet  10adlng  t0 the  fabr1c f11ter at the ASARCO-E1
                                lower than
     A summary of particle size distribution data obtained for secondary
emissions from EAF's and AOD vessels and for secondary emissions f?oT *
TSHsAR0™^5 7"S Presented graphically in FiguresE-1 and E-2.5-9
The ASARCO-Tacoma copper smelter data were obtained using an Andersen III
cascade impactor.  This particulate sampling method was alsS used at
                                  E-3

-------
   Table  E-l.   EAF AND ADD VESSEL  FABRIC  FILTER DESIGN  SPECIFICATIONS0
Plant
A
S Ho. 3
3 Ho. 4
C
0
E
F
G
H Canopy
Hoods
I Canopy
Hoods
J
K
L
H
N 1
H 2
0
P
Q
R
S
Fabric
Filter
Pressure
Type
Positive
Negative
Negative
Negative
Positive
Positive
Positive
Positive
Positive
—
«
Positive
Positive
Positive
Positive
Negative

Positive
Positive
Positive
Negative
Design
Gas Flow
(acfa)
460,000
132,000 •
91,000
150,000
425,000
420.000
740.000
400,000
345,000
700,000
945,000
900,000
420,000
1.750,000
450,000
750,000
525.000
600,000
300,000
675,000
230.000
No. of
Compart-
ments
12
14
—
—
—
9
60
6
~
14
—
—
~
—
~
—

—
2
12
~
Type of
Sag
Type S5
Dacron ©
Dacron ®
Dacron ®
Polyester
Polyester
Dacron ®
--
—
—
Dacron®
Nonex®
Polyester
—
—
--
~

Polyester
Dacron ®
Polyester
Dacron®
Air-to-
cloth
ratio
3.2
2.37
2.69
4.5
—
2.82
2.33
2.60
4.1
—
3.1
2.93
2.8
3.4
3.1
5,. 5
1.95
2.65
2.68
3.26
3.62
Pressure
Drop
(In. H?0)
3.5-4.1
4-11
4-11
2-7
5.7
—
—
1.2-2.4
—
—
3-7.5
—
7-9
3-5
8-10
7-8
3 and 7
4-6
2.5-6
6-8
5-10
Gas Type of
Temp. Cleaning
—
Shaker
Shaker
RAF
RAF
Max 99 'C RAF
(210'F)
Shaker
—
—
Shaker
Shaker
Max 135*C RAF
(275'F)
RAF
Shaker
—
—
RAF
Shaker
RAF
RAF
RAF
RAF « Reverse Air Flow

Inforsarion obtained froo Reference 1. Design specifications not available 1n Reference 1 are
Indicated by "--".
                                              E-4

-------
      Table E-2.   SUMMARY  OF  PARTICIPATE  EMISSION  DATA  FOR FABRIC  FILTER
                  CONTROL  DEVICES  USED  FOR  EAF  AND AOD  VESSELSa
                             Average  Inlet
Outlet Concentration
       (gr/scf)


Positive
Pressure
Fabric
Filter
Control
Devices




Negative
Pressure
Fabric
Filter
Control
Devices
ouincii ui a nun
Plant (gr/scf)
A 0.0408
D
E
F
G
H
P 0.1068
Q 0.0731
Q
B No. 3
B No. 4

Q 	

Range
0.0010-0.0021
0.0008-0.0017
0.0015-0.0018
0.0008-0.0011
0.0005-0.0046
0.0026
0.0013-0.0018
0.0002-0.0004
0.0030
0.0005-0.0018
0.0021-0.0029

0.0011-0.0013

Average
0.0014
0.0011
0.0016
0.0009
0.0026
0.0026
0.0015
0.0003
0.0030
0.0011
0.0026

0.0012

aA full description of the plants tested can be found in Reference 1.   Generally
 emissions testing was performed over a full heat cycle using Method 5.   Plants '
 P and Q are based on AOD vessel emissions,  other plants'  emissions are  from
 EAF s.
                                     E-5

-------
                                    ASARCO-Tacoma
                                    Copper Converter Ski inning  (3
                                     O PSSS-1
                                     A PSSS-2
                                     D PSSS-3
                                    Steel Plant A (Ref.  1)
                                      EAF Skinming
                       1.0
                       PARTICLE SIZE,  microns
10.0
Figure  E-l.   Particle Size Distributions  of Copper  Converter
                  and EAF  Skimming  Gas Streams
                                E-6

-------
                                  Steel Plants
                                    O Plant A (meltdown)
                                      Plant N
                                    Q Plant P
                                    O Plant Q
                                  Average of 4 plants
               •1.0

               PARTICLE SIZE, microns
10.0
Figure  E-2.   Particle Size Distributions of  EAF/AOD
        Vessel  Gas Streams During  Heat Cycles
                        E-7

-------
steel plant Q.  At steel plant A, both Pilat and Brinks impactors were
used.  (The sampler types used at plants N and P are not specified in
Reference 1.)  Figure E-l shows the particle size distribution measured
in the air curtain secondary hood during the slag skimming mode at
ASARCO-Tacoma in comparison to EAF slag skimming at steel plant A.
Figure E-2 presents the average particle size distribution from tests
conducted at four steel plants.  The samples were taken during various
phases of a heat cycle at plants N, P, and Q, and during meltdown at
plant A.  The average particle size distribution for the four EAF's and
ADD vessels shown in Figure E-2 also appears in Figure E-3.  In Figure
E-3, the EAF's and AOD vessel gas streams are compared with secondary
emission gas streams from the ASARCO-Tacoma No. 4 copper converter
during charging.

     The particle size data shown in Figure E-l for EAF/AOD vessel and
copper converter slag skimming show that the particle size distribution
for both operations are similar, with about 90 weight percent of the
emissions being composed of particles having diameters of 10 microns or
less.  In Figure E-2, about 80-90 weight percent of the particulate
matter in EAF/AOO vessel gas streams during meltdown is 10 microns or
smaller.  In comparison, from Figure E-3, about 60-80 weight percent of
the particulate matter from the tested copper converter secondary gas
stream during charging was 10 microns or smaller.

E.5  CONCLUSIONS

     Data presented indicate that particulate concentrations in EAF and
AOD vessel offgases are slightly higher than the particulate concentration
levels measured for copper converter secondary emission gas streams.
Also, the particle size data for EAF and AOD vessel gas streams are
similar to those for copper converter secondary gas streams.  Hence,
the characteristics of gas streams from EAF and AOD vessels are similar
to those from copper converters.  The data show that fabric filters
applied to control particulate emissions from EAF's and AOD vessels are
capable of achieving outlet concentrations less than 0.005 gr/dscf.
Therefore, given the similarity between the gas stream characteristics
from copper converters and EAF and AOD vessels, the data support the
achievability of a control level of 0.005 gr/dscf for copper converter
secondary emissions.
                                  E-8

-------
                                                 ASARCO-Tacoma
                                                 Copper Converter Charging (5 tests)  j

                                                   O PSMC-1    O PSMC-4
                                                     PSMC-2    0 PSMC-5
                                                   D PSMC-3
                                                 Average of EAF/AOO
                                                 Vessel Tests     __»_«„_
                                                 (4 steel plants)
1.0
                                                                                   10.0
                                            SIZE, microns
          Figure  E-3.   Particle  Size Distributions of  Copper Converter
                Charging and EAF/AOD Vessel Meltdown Gas Streams
                                          E-9

-------
E.6  REFERENCES

1.    Electric Arc Furnaces and Argon-Oxygen Decarburization Vessels in
      Steel Industry - Background Information for Proposed Revisions to
      Standards.  U.S. Environmental Protection Agency.  Office of Air
      Quality Planning and Standards, Research Triangle Park, North
      Carolina.  EPA-450/3-82-020a.  July 1983.

2.    Fennelly, P.F., and P.O. Spawn.  Air Pollution Control Techniques
      in the Iron and Steel Foundry Industry.  U.S. Environmental
      Protection Agency.  Research Triangle Park, N.C.  EPA-450/2-78-024.
      June 1978.  221 p.

3.    Inorganic Arsenic Emissions from High-Arsenic Primary Copper
      Smelters - Background Information for Proposed Standards.  U.S.
      Environmental Protection Agency, Office of Air Quality Planning
      and Standards.  Research Triangle Park, N.C.  EPA-450/3-83-009a.
      April 1983.

4.    Air Pollution Emission Test:  ASARCO Copper Smelter, El Paso,
      Texas.  January 1978.  U.S. Environmental Protection Agency.
      EMB Report No. 78-CUS-7.  p. 12.  Docket A-80-40; reference
      number II-A-23.

5.    Source Testing Report:  The Babcock and Mil cox Company Electric
      Arc Furnace, Beaver Falls, Pennsylvania.  U.S. Environmental
      Protection Agency.  EMB Test No. 73-ELC-l.  January 1973.  p. 14.
      Docket A-79-33; reference number II-A-1.

6.    Letter from William T. Nicholson, Chapparal Steel, to Reid E.
      Iversen, Environmental Protection Agency.  December 3, 1981.
      Response to Section 114 letter.

7.    Emission Test Report:  AL Tech Specialty Steel Corporation.  U.S.
      Environmental Protection Agency.  EMB Test No. 80-ELC-7.   July
      1981.  Table 5.  Docket A-79-33; reference number II-A-17.

8.    Emission Test Report:  Carpenter Technology Corporation.   Reading,
      Pennsylvania.  U.S. Environmental Protection Agency.  EMB Report
      80-ELC-10.  April  1981.  p. 3-27.

9.    Evaluation of an Air Curtain Hooding System for a Primary Copper
      Converter.  U.S. Environmental Protection Agency.  Industrial
      Environmental Research Laboratory, Cincinnati, Ohio.
      EPA-600/2-84-042a.  Docket No. A-80-40; reference number  IV-A-4.
                                  E-10

-------
   APPENDIX F





ECONOMIC IMPACT
       F-l

-------
                              APPENDIX F

                             ECONOMIC  IMPACT
      This  section  first presents an economic profile of the primary
 copper  industry  in general, and primary copper smelters in particular
 (Section F.I).   The data presented in the economic profile is then used
 in  an economic analysis of the industry (Sections F.2 and F.3).  The
 economic profile focuses on several primary copper smelter industry
 characteristics, such as:  number and location of smelters, copper
 supplies,  copper demand, competition, substitutes, and prices.

 F.I   INDUSTRY ECONOMIC PROFILE

 F.I.I  Introduction

      Copper's utility stems from its qualities of electrical  and
 thermal conductivity, durability, corrosion resistance, low melting
 point,  strength, malleability, and durability.  Principal  uses are in
 transportation, machinery, electronics, and construction.

      The Standard Industrial Classification Code (SIC) definition of
 the primary copper industry is the processes of mining, milling,
 smelting,  and refining copper.  The primary copper smelters are included
 in SIC 3331 (Primary Smelting and Refining of Copper).  Copper-bearing
 ore deposits and substantial amounts of copper scrap provide the raw
 materials  for these processes.

      In addition to producing copper, the industry markets by-product
 minerals and metals that are extracted from the ore deposits,  such as
 silver, gold, zinc, lead, molybdenum, selenium, arsenic, cadmium,
 titanium,  and tellurium.  Many of the companies that own primary copper
 facilities also fabricate copper.  Many of these same companies are
 also  highly diversified and produce other metals, minerals, and fuels.

      The standard under consideration directly affects only one of
the four primary copper processes,  namely smelting.   However,  the other
three related processes are an integral  part of the  ownership  and
economic structures of copper smelters and therefore must  be  considered
in determining industry impact.  Mining and milling processes  supplying
a smelter will be secondarily affected by a smelter  impact because
transportation costs to an alternate smelter will  add a sizeable
                                   F-2

-------
  business cost.   Transportation  costs  for  concentrate  are  significant
  because only  25  to 35  percent of  the  concentrate  is copper and the
  remaining  75  to  65 percent  that is  also being transported is waste
  material.   The same interdependence between  smelter and refinery is not
  as  critical because the  copper  content after leaving  the  smelter is
  typically  98  percent.

       Even  if  there were  no  business dependencies  among the processes
  the  available financial  data for  smelters is aggregated in consolidated
  financial  statements which makes  smelter data difficult to isolate
  Thus, an economic  analysis of copper  smelters must be cognizant of the
  economic connection  backward to the mines and forward through the
  refining stage.

  F.I .2  Market Concentration

      Fifteen pyrometallugical copper smelters exist in the United
  States.  Copper is also produced in limited amounts by various  hydro-
  meta  urgical  methods which by-pass the smelting stage.   These  hydro-
 metallurgical  facilities are not being considered  in the standard
  setting process.   The 15 copper smelters  have a  capacity* of  1  722  600
 megagrams** of copper.   The hydrometallugical processes  have  a'capacity
 of roughly 10 percent of the copper smelters' capacity.          aP<"-"-y

      Table F-l shows that the vast majority  (approximately 89 percent)
 of smelting capacity is located  in the southwestern States of Utah
 Nevada,  New Mexico, Arizona, and Texas, close to copper  mines.   The
 location is largely dictated by  the  need to minimize shipping distances
 of concentrates,  which  are normally  25 percent to  35 percent  copper.

      The 15 U.S.  copper smelters are owned by 7  large  companies.  All
 7 companies are integrated in that,  to various degrees, they  own  some
 mining and  milling  facilities which  produce copper concentrates for the
 smelters.   Several  smelters, apart from the concentrates from their own
 mines, buy  additional concentrates from other mining and milling
 producers,  smelt  and  refine  the  copper, and then sell  it.  This prac-
 tice is  referred  to as  custom smelting. Other smelters process (smelt
 and  refine)  the concentrates, and  return the  blister copper to mine
 owners for  them to  sell,  a practice  referred  to as tolling  Some
 smelters  perform  both toll and custom  smelting.

      It  is general  industry practice for companies to operate their

Xl«  *rtV,S  S6hVi.Ce Ce£-rS at 10W profit mar9ins to th* owned mines.
This  acts to shift  profits of an integrated operator to the mines
±r^epletl°n-a1i10Wan^S ex1st'  Th?s ™*™^es prom to Coverall
??™ Ii?!!;« ?" lmPllcatl?n of.this  P^icy  is that the impact  on  profits
Ihm theT H °°PPer PnC6S 1S frequently  ma"^est at  the mines more
Capacity is not a static measure of a smelter since capacity  can
 procesled 6Xamp1e' accord1n9 to the grade of copper concentrates
  1 megaqran
megagram =1.1 short tons.

                               F-3

-------
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-------
  ,n-,n Ta5 ? «"1    sts the  smelters» their corporate owners, capacities,
  1979 and 1980 production  amounts, and the distribution of integrated
  custom, and toll  smelting.  Total production figures and the correspond-
  ing operating rates shown in Table F-l are compiled from corporate
  reports.  Figures in Table F-l are adjusted to exclude capacity and
  production for the Anaconda smelter, which was closed in 1980.  For
  1979, the table shows a 74.9 percent operating rate.  For 1980, the
  table shows that the industry operated at 59.6 percent of capacity.
  Production was down for 1980 due to an industry strike.  Following the
  strike in 1980, production improved in 1981 to 1,380 gigagrams
  for a capacity utilization rate of 80 percent. 9  Preliminary figures
  for 1982 from the Bureau of Mines show a decline in primary copper
  smelter production to 1,020 gigagrams, for a capacity utilization rate
  of about 59 percent.!0

      The 3 largest companies account for 78 percent of the entire
  smelting capacity.  Phelps Dodge Corporation has the largest smelting
 capacity, followed by Kennecott Corporation and then ASARCO.   The
  remaining 4 companies each have 1 smelter and in order of size are
 Magma (Newmont),  Inspiration,  Copper Range,  and Copperhill  (Cities
 Service).

      The table also  shows  that  73 percent  of total  1980 smelter
 production  was from  concentrate from  integrated arrangements.   Of the
 remaining concentrate,  21  percent was  smelted on  a  toll  basis  and 6
 percent  smelted on a custom  basis.   Three  of the  8  companies process
 only  their  own copper concentrates..

 F.I. 3  Total  Supply

      Copper  resources  are  defined as deposits which can be profitably
 extracted at  a given  price.  Various estimates  of U.S. copper  resources
 show  amounts  ranging  from  61.8 teragrams to 99.1 teragrams.*  The
 capability of  copper  resources to meet future demand is dependent  upon
 several  factors; a principal one  being the rate of growth in demand.
 The U.S. Bureau of Mines estimates that copper demand will grow at an
 annual growth  rate of 3.0  percent to the year 2000 and that 30 percent
 of the demand will be supplied by scrap.  Therefore, the likely primary
 copper demand over this period would be 55 teragrams compared with 92
 teragrams of resources. H  Consequently, U.S. supply appears adequate
 to the year 2000.  Beyond the year 2000, demand is expected to strain
 supply sources.  However, increased uses of old scrap and possible
 exploitation of sea nodules can supplement on-shore mining.  In
mfj1h«H°n'-?11C[0m1niatunzat1on' c°PPer cladding, and other conservation
methods will be more widely used to extend the supply of copper.

     F*1*3/1  Domestic Supply.   Primary refined  copper output alone
does not  depict the entire supply of copper that is  available for

nofnST i" the U?^d StateS*   A large P0rt1on of c°PPer sc°aP does
not need  to be resmelted or re-refined  and is readily available for
 Teragram is 1.1 million short tons.
                                   F-5

-------
consumption.  Copper is a durable material and, if it is unalloyed or
unpainted, etc., it can be reused readily.  Otherwise, it is resmelted
or re-refined as described earlier.  The ready availability of copper
scrap as a secondary source of supply tends to be a stabilizing influ-
ence on producers' copper prices.

     The total supply of copper available for consumption in any one
year is therefore comprised of refined U.S. production, scrap not
re-refined, net imports, and any changes in inventory of primary
refined production from one year to the next.

     The refined copper production in 1981 comprised 70.4 percent of
total copper consumed in the United States; scrap not re-refined
accounted,for 32.0 percent and net refined imports 10.6 percent (total
exceeds 100 percent due to stock changes).12  Between 1970 and 1981,
67 percent of U.S. copper demand, excluding stock changes, was met from
domestic mine production; 21 percent was from old scrap, and 12 percent
from net imports.  During these years, total U.S. demand for copper
averaged 2,012,000 megagrams per year.  Of this amount, 1,337,000
megagrams was from domestic production, 427,000 megagrams from scrap,
and 248,000 megagrams from net imports.

     Another statistic for describing the importance of scrap is to
add the three stages (smelting, refining from scrap, and reuse of
scrap) at which scrap can enter the production process, and compare the
figures to total copper consumption.  In 1981 the percentage of total
consumed copper from scrap was 47.7, roughly the same as in recent
years.

     The 1981 refined copper production level was 1,956,400 megagrams.
Although the average for the past several years has shown some improve-
ment, total refined copper production has not returned to the 1973 peak
level.

     F.I.3.2  World Copper.  According to the Bureau of Mines, the
world reserve of copper in ore is estimated at 494,000 gigagrams of
copper.  In addition, an estimated 1,333,000 gigagrams of copper are
contained in other land-based resources, and another 689,000 gigagrams
in seabed nodules.  The United States accounts for 19 percent of known
copper reserves and 26 percent of other land-based copper resources.13

     The United States is the leading copper producing and consuming
country.  Other major copper mining countries include:  Chile, the
U.S.S.R., Canada, Zambia, Zaire, Peru, and Poland.  Although its copper
mining activity is quite small, Japan is among the three largest
countries in terms of copper smelting and refining.  In 1981 the U.S.
produced 18.8 percent of the world's mine production of copper, 16.5
percent of the smelter production, and 22.2 percent of the refinery
production.  The consumption of the world's refined copper by the U.S.
amounted to about 21 percent.  Table F-2 shows U.S. production, world
production, and the U.S. percent of world production for the years 1963
through 1981.  Although the U.S. is essentially maintaining its consump-
                                   F-6

-------
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-------
tion and production levels, world consumption and production is
increasing.  As a result, the U.S. share of world consumption and
production shows a relative decrease.

     In 1981 world consumption of refined copper rose 9 percent  to
9,440 gigagrams.14  Stocks of refined copper in the market economy
countries increased 5 percent to 1,100 gigagrams.I5

F.1.4  U.S. Total Consumption Of Copper

     Total copper consumed in the United States over the last 12
years has fluctuated considerably but shows an overall upward trend.
However, copper consumption has not returned to its 1973 peak.  This
conclusion is derived from data on copper consumption from refineries
and copper consumption from refineries plus scrap.

     Table F-3 shows each set of data for the years 1970 through
1981.  The 5-year averages in gigagrams for copper consumption from
refineries has increased by 6.9 percent (1972 through 1976 is 1,891.9
and 1977 through 1981 is 2,021.5.).  Five-year scrap consumption has
shown an increase of 5.1 percent, from 848.6 gigagrams for the 1972 to
1976 period, to 892.3 gigagrams for the 1977 to 1981 period.  There are
signs that the consumption of scrap has begun to increase over the last
few years.

     The Bureau of Mines forecasts a long-range overall consumption
growth rate to the year 2000 of 3.0 percent per year.  The combined 3.0
percent growth rate is composed of a 2.4'percent growth rate for
primary copper, and a 4.8 percent growth rate for secondary copper.19

     F.I.4.1  Demand By End-Use.  Refined copper and copper scrap are
further processed in a number of intermediate operations before the
copper is consumed in a final product.  Refined copper usually consists
of one of the following shapes:  cathodes, wire bars, ingots, ingot
bars, cakes, slabs, and billets.  These shapes plus the copper scrap
then go to brass mills, wire mills, foundries, or powder plants for
subsequent processing.  The copper is frequently alloyed and transformed
into other shapes such as sheet, tube, pipe, wire, powder, and cast
shapes.  Ultimately, the copper is consumed in such shapes in five
market or end-use categories.  The Copper Development Association, Inc.
uses the following categories:  building construction, transportation,
consumer and general products, industrial machinery and equipment, and
electrical and electronic products.

     Table F-4 shows the demand for copper in each of these five
markets over the 12-year period 1970 through 1981.  The total figures
for these five markets will not equal the total consumption figures of
Table F-3 due to the effects of stock changes and imports on fully
fabricated copper products.

     A look at the 5-year average demand shows that there has been an
increase in three out of the five markets.  The building industry
                                   F-8

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 market sales showed a gain  of 6.2  percent.   The  transportation market
 shows a gain of 5.0 percent.   An increase  of 9.7 percent  occurred  in
 the electrical  and electronic product  markets.   The  demand  for elec-
 trical  equipment has risen  because of  increased  emphasis  on safety,
 comfort, recreation, and a  pollution-free  environment.  Automation,
 including the use in computers, has also boosted the use  of copper.

      Substitution of other  materials,  coupled with the  recession,  has
 caused the slight drop of less than 1  percent in the consumer and
 general  products markets.   The 1 percent decline in  the industrial
 machinery and equipment market is  largely  due to the impact of the
 recession.

      The Bureau of Mines estimates that  the  most growth in  copper
 demand will  occur in the electrical  and  electronic products industries,
 consumer and general  products, and building  construction.   Copper  is an
 important metal  in electric vehicles.  If  electric vehicles become
 popular, this would be a source of increased  demand  for copper.
 General  Motors  plans to produce an electric  family car for  mass market-
 ing in the mid-19801s.  A conventional  internal combustion automobile
 contains from 6.8 to 20.4 kg  of refined  copper,  whereas electric
 vehicles use much more copper. The Copper Development Association
 estimates range from 45.4 kg  to 90.7 kg, with an  average nearer
 to  45.4 kg.21

      Another potential  area for growth is in  the  solar energy indus-
 try.   Presently, the extent of this  sector is relatively modest,
 consuming approximately 4,500 Mg/yr  of copper in  the U.S.   However,
 consumption  in  this sector  has the potential  to  climb considerably.

      In  addition,  the U.S.  military demand for copper is expected to
 increase.   Increased  military  expenditures will   have a significant
 impact  on copper demand because copper is an  important element in
 modern  electronic  weaponry. During  heavy rearmament periods the mili-
 tary demand  for  the metal has  reached 18 percent of copper mill  ship-
 ments.   Although military demand is not expected to return to the
 record  high  18  percent  level,  analysts do expect a large increase in
 military  requirements  for copper from the low level in 1979 of less
 than 2  percent.zz

     The  demand  picture  in  the United States may receive a boost from
 the federal  government.  The government is  committed  to eventually
 acquire  1.1  gigagrams of copper for its currently depleted strategic
 stockpile.   The previous stockpile was largely depleted in 1968;  the
 final sale was in  1974 after copper prices  had soared.  Further Congres-
 sional action is necessary to implement and fund the  purchase plan.

     F.I.4.2  Substitutes.  Substitutes for copper are readily  avail-
 able for most of copper's end uses.  Copper's most competitive  substi-
tute is aluminum.  Other competitive materials are stainless steel,
 zinc, and plastics.  Aluminum, because of its high electrical conduc-
tivity, is used extensively  as a  copper substitute in high voltage
                                   F-ll

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electrical transmission wires.  Aluminum has not been used as exten-
sively in residential wiring because of use problems, and minimal
savi ngs.

     Aluminum is also potentially a substitute for copper in many  heat
exchange applications.  For example, automobile companies are still
experimenting with the use of aluminum versus copper in car radiators.
When copper prices are high, or copper supply is limited, cast iron  and
plastics are used in building construction as a copper pipe substitute.
A relatively new substitute for copper is glass, which is used in  fiber
optics in the field of telecommunications.

F.I.5  Prices

     Numerous factors influence the copper market, and thus the price
of refined copper.  These factors include:  production costs, long-run
return on investment, demand, scrap availability, imports,- substitute
materials, inventory levels, the difference between metal exchange
prices and the refined price, and federal government actions (e.g.,
General Services Administration stockpiling and domestic price controls).

     Among the many published copper price quotations, two key price
levels are:  1) those quoted by the primary domestic copper producers
and 2) those on the London Metal Exchange and reported in Metals Week,
Metal Bulletin, and the Engineering and Mining Journal.  The producers'
price listed most often is for refined copper wirebar, f.o'.b. refinery.
The London Metal Exchange price, referred to as LME, is also for copper
sold as wirebar. The LME is generally considered a marginal price
reflective of short-term supply-demand conditions, while the producer
price is more long-term and stable and often lags the LME price movement.

     Copper is also traded on the New York Commodity Exchange (Comex).
Arbitrage keeps the LME price and the Comex price close together (with
minor price differences due to different contract terms on the two
exchanges, and a transportation differential).

     Table F-5 shows the LME, the U.S producer price, and the U.S.
producer price adjusted to a 1982 constant price for the years 1970
through 1982.  Data were obtained from U.S. Bureau of Mines publications.

     Several points can be observed from the table with respect to the
LME price versus the U.S. producer price:  (1) the LME price has had
wider swings than the producer price; (2) in the past when both prices
are relatively high, the LME price has been considerably higher than
the producer price, while during relatively low price periods, the
producer price has been moderately higher than the LME price; and  (3)
in recent years a marked change appears to be taking place away from a
two-price system and toward a one-price system, with the difference
between the LME and the U.S. producer price accounted for only by  a
transportation differential.  These earlier situations had reoccurred
repeatedly over the past 20 years.  One other point about the table
should be mentioned, although unrelated to the relationship of the
                                   F-12

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             Table  F-5.   AVERAGE  ANNUAL  COPPER  PRICES23»24,25
                            (cents  per kg)a
 Year
LMEb
U.S Producer Pn'cec
U.S. Producer Price
1982 Constant Priced
1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
1981
1982e
138.6
106.7
106.7
178.0
204.8
123.4
140.6
130.7
136.2
198.2
218.5
174.7
147.4
128.0
114.4
112.6
130.9
170.1
141.2
153.1
147.0
146.3
205.3
225.3
187.2
162.8
290.9
248.7
234.6
256.7
303.8
231.5
239.2
216.2
200.4
259.9
262.0
199.1
162.8
aTo convert from cents/kg to cents/1b, multiply by 0.454.
bLondon Metal  Exchange "high-grade" contract.
CU.S producer price, electrolytic wirebar copper, delivered U.S destinations
 basis.
dAdjusted to 1982 constant price by applying implicit price deflator for
 gross national  product (1972 = 100).
Preliminary.
                                  F-13

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LME to the producer price.
general inflation.
The producer price has not kept pace with
     In theory, the U.S. producer price should be somewhat higher than
the LME price since ocean transport costs must be incurred to get the
refined copper to the U.S.  However, this relationship appears to hold
only during slack price periods.  When LME prices are high, the pro-
ducers do not raise their prices as much, which in theory appears
contrary to profit maximization.  Explanations offered for such behavior
include:  the producers' fear of long-run substitution for copper if
the producers raised the price to the fabricators, high profits for
integrated fabricators while reducing supply to nonintegrated fabri-
cators, past fears of government stockpile sales that would reduce
prices, and fear of the return of government intervention through price
controls.

     The cost of producing copper is one of the elements that influences
the price of copper.  Considerable data exist to validate the point
that the long-run economic cost of producing copper is increasing.26
During the early 1970's the capital costs per megagram of annual
capacity for developing copper from the mine through refining stage
were $2,000 to $2,500, and by the late 1970's had risen sharply to
$7,200 to $7,700.  Estimates are that a price of $2.76 per kg to $3.30
per kg for refined copper would be needed to support such new capital
outlays.

     The above costs are for conventional pyrometallurgical smelting.
The newer smelting processes such as Noranda and Mitsubishi offer some
capital cost savings at that stage due to lower pollution control
costs.  The hydrometallurgical  processes also require less capital.
However, the mining costs are the highest part of overall development
costs for which limited cost saving techniques exist.  The mine develop-
ment costs in the U.S. have risen significantly, largely as a result of
the shifting from higher to lower grades of available copper ores and
sometimes remote locations that require infrastructure costs for towns,
roads, etc.

     In 1979, the Bureau of Mines analyzed 73 domestic copper proper-
ties to determine the quantity of copper available from each deposit
and the copper price required to provide each operation with 0 and 15
percent rates of return.  The Bureau estimates that a copper price of
$4.56 per kg would be required  if all properties, producing and nonpro-
ducing, were to at least break  even.  The average break-even copper
price for properties producing  in 1978, $1.46 per kg, was about equiva-
lent to the average selling price for the year.   At this price, analysts
calculate that only 25 properties could either produce at break-even or
receive an operating profit. Of these properties, only 12 could receive
at least a 15 percent rate of return.

     Annual  domestic copper production, from 1969 to 1978, averaged
1,337,000 megagrams.  According to this study, in order to produce at
this level and receive at least a 15 percent  rate of return, a copper
                                   F-14

-------
 price of $1.81 per kg Is  required.   If the United  States  were  to
 produce the additional  248,000 megagrams  that  were imported  each year
 over this period,  a copper price of $1.94 would  be necessary.27  The
 report concludes that increases in  copper prices are  required  in order
 for many domestic  deposits to continue to produce.

      It has been suggested that long-term potential for higher prices,
 plus the high  cost of new capacity  are significant  reasons for the
 increased purchases several years ago  of  copper  properties by  oil
 companies.   The reasoning is  that oil  companies  need  places  for heavy
 cash flows, and diversification to  other  products  is  desirable.  The
 oil  companies  reportedly  can  wait for  expected copper price  increases
 to  obtain their return.   Further, by purchasing  existing  facilities,
 rather than building new  capacity,  they avoid the escalating new
 capacity costs.  However,  more recently,  some oil companies  seem to be
 rethinking  their investments  in copper.

      As shown  below,  U.S.  oil  (and  gas) companies own or  have major
 interests in many  of  the  largest  domestic  copper producers:

      1.    Amax - Approximately  20 percent  owned  by Standard Oil of
           California

      2.   Anaconda  -  Owned by Atlantic  Richfield Company  (ARCO)

      3.   Cities Service - Also a primary  copper producer

      4.   Copper Range - Owned by Louisiana Land and Exploration
          Company

      5.   Cyprus Pima Mining Company - Standard Oil Company (Indiana)

      6.   Duval - Owned by Pennzoil  Company

      7.   Kennecott - Standard Oil of Ohio (British Petroleum)

These copper producers own or control a large portion  of domestic
copper reserves, mine production, and U.S. refinery capacity.  Their
investment in the copper industry is significant, and  thus they must
expect higher prices and profits in  the future.
                                  F-15

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 F.2  ECONOMIC ANALYSIS

 F.2.1  Introduction

      This section presents the economic analysis of the arsenic NESHAP
 for the 14 primary copper smelters.  The fifteenth primary copper
 smelter (ASARCO-Tacoma) is not discussed in this analysis, because the
 company has announced its intention to close the smelter during 1985.

      Two principal economic effects are analyzed.  First, the ability
 of the smelters to pass pollution control  costs forward to consumers,
 in the form of an increase in the price of copper.  Second, the reduc-
 tion in profits if part or all of the control costs cannot be passed
 forward in the form of price increases but must be absorbed by the
 copper producers.  Section F.2.2 presents  a summary of the results.
 Section F.2.3 presents the methodology.  Section F.2.4 presents the
 impact on prices, Section F.2.5 presents the impact on profits, and
 Section F.2,'6 presents a discussion of capital  availability.

 F.2.2  Executive Summary

      In 1982 the copper producers experienced one of the worst years in
 recent history.   During much of 1982 major segments of the industry
 were closed for sustained periods.   Such a depressed situation cannot
 be used as the foundation to examine the long-term economic effects  of
 the potential  arsenic NESHAP.   Therefore the economic analysis is  based
 on a more normal  condition for the  industry.  However,  even under  more
 typical  conditions for the industry, six smelters  may face significant
 financial  impairment, and two  additional smelters,  Cities  Service-Copper-
 hill  and  Kennecott-McGi11, appear to be likely  closures.   The  control
 costs for the  remaining  six smelters appear affordable.

      If each  smelter  attempts  to  pass control costs  forward  in the form
 of a price increase,  the  price increases would  range  from  0  percent  to
 15.2 percent,  at  an 80 percent capacity utilization  rate,  and  depending
 on the  regulatory alternative.  For Alternative  II the  price increase
 would be  0 for every  smelter,  with  one  exception  (Kennecott-McGill)
 that  would have  a large 15.2 percent  price  increase.  For Alternative
 III  the price  increases would  range from 0.2  percent  to 6.3 percent.
 For Alternative  IV the price increases  are  lower and  would  range from  0
 to 1.3  percent.   For  Alternative  III+IV the  price increases would range
 from  0.2  percent  to 7.6 percent.  Competition will prevent the existence
 of such a  broad variation,  and  therefore partial or complete absorption
 of control costs  is more  likely than  a  full  pass forward of control
 costs.

      If control costs  are  absorbed  and  profit margins reduced, again a
 broad range exists.   At an 80 percent capacity utilization rate and a
ten percent profit margin, for Alternative II the profit decrease would
be 0 for every smelter, with one exception (Kennecott-McGill) that
would result in a  net  loss.  For Alternative III the profit decrease
would range from 2.1 percent to 62.6 percent.  For Alternative IV the
                                   F-16

-------
 profit decrease would be lower and would range from 0 percent  to  12.8
 percent.   For Alternative III+IV the profit decrease would range  from
 2.1 percent to 75.4 percent.

      Although the capital  costs of the control  equipment  are not  minor
 amounts,  for most of the producers the capital  cost would not  present a
 major obstacle.  For two of the producers,  ASARCO and Phelps Dodge,  the
 capital  costs may present some difficulty but should not  be an insur-
 mountable financial  obstacle.

 F.2.3  Methodology

      The  purpose of this section is to explain  in general  terms the
 methodology used in the analysis.   Each of  the  appropriate sub-sections
 explains  the methodology in more detail.   No single financial  indicator
 is  sufficient by itself to  use for decision making purposes about the
 primary copper smelters.  Therefore the methodology relies on  several
 indicators  which in total can  be used  to  draw conclusions  about the
 industry.

      The  methodology has  three major parts.   The  first part is an
 analysis  of price effects.  The analysis  of price effects  introduces an
 upper limit on the problem  and provides a benchmark to make evaluations
 on  a  relatively uncomplicated  basis.   A price increase represents the
 "worst case"  from the viewpoint of a consumer of  copper.   The  second
 major part  of the methodology  is an analysis  of profit effects.  The
 analysis  of profit effects  introduces  a lower limit on the problem and
 is  the "worst case"  from the viewpoint  of the firm.  The individual
 characteristics of each  smelter increase  in  importance and  are incorpor-
 ated  to a greater extent.   The third and  final part  of the methodology
 is  an analysis of the availability  of  capital to  purchase  the control
 equipment.

      Firms  in the copper industry  face  a  wide variety of variables that
 in  the aggregate  determine  the economic viability of the firm generally,
 and a smelter specifically.  The variables can be grouped  into  four
 broad categories.  The categories  are described here separately and in
 a simplified  manner  for discussion  purposes.  However, there is a close
 interrelationship  among the four categories and changes in one  will
 have  implications  for the others.   The four broad categories that
 determine the  economic viability of the smelter are described below.

      1)  Macroeconomic conditions.  The two most prominent variables  in
this  category  are copper prices and copper demand.  By-products and
co-products represent a significant source of revenues for most copper
operations. Therefore in addition to the price of copper,  the price of
by-products and co-products also influence an assessment  of economic
viability.  Common by-products  and co-products of copper  production
include:  gold, silver, molybdenum, and  sulfuric acid.  Other by-products
include selenium, tellurium, and antimony.  For ease of presentation
and in order to present a conservative  analysis,  by-products and
co-products are not considered  explicitly in the analysis.
                                   F-17

-------
      Another important variable,  though  somewhat less visible,  is
 government actions, such as:   federal  and state tax policy;  stockpiling;
 price controls;  tariffs and import quotas;  and international  develop-
 ment loans and trade credits.   The government  variable includes  the
 U.S. Government, as well as foreign governments.  For example,  consider
 that a report by the U.S. Bureau  of Mines has  stated that  at least 40
 percent of the total  mine production of  copper in market economy
 countries was produced by firms in which various foreign governments
 owned an equity  interest.28 The  significance  of government  ownership
 and involvement  in the production of copper is that the forces  of
 supply and demand are distorted by the involvement.

      2)  Environmental  regulations.  Since  roughly 1970, environmental
 regulations have evolved to the point  that  they have become  a major
 variable that must be considered  in the  corporate decision making
 process.  Here again, government  actions are important.

      3)  Corporate organizational  strategy.  This category includes the
 corporation's strategy with respect to variables such as remaining or
 becoming an integrated copper  producer versus  a non-integrated copper
 producer, or perhaps  leaving the  industry entirely.

      Many of the companies  that produce  refined  copper are integrated
 producers;  that  is, they own the  facilities  to treat copper  during each
 of  the four principal  stages of processing:  mining,  milling,  smelting,
 and refining. Also,  several of the producers  are integrated  one
 additional  step  into  the fabrication of  refined  copper.  However, not
 all  companies in the  copper industry are integrated  producers.  There
 are companies that only mine and  mill  copper ore to  produce  copper
 concentrate,  and then have  the  copper  concentrate smelted and refined
 on  a custom basis (the  smelter  takes ownership of the  copper) or on a
 toll  basis  (the  smelter charges a service fee  and returns the copper to
 the owner).   The existence  of both  integrated  and non-integrated
 producers introduces  a  complex  economic  element  into this analysis.
 That  complex  economic element manifests  itself  in  the  choice of
 the appropriate  profit  center to  use in  the  analysis.  This standard
 affects only  one stage  of the production  process  (smelting) in a direct
 way,  but has  indirect effects on  the other stages  (mining,  milling, and
 refining).

      For accounting purposes, integrated  producers  frequently view the
 smelter as  a  cost  center, rather  than  a  profit center.  However, in an
 economic sense the smelter  provides a  distinct contribution to the
 production  process that  ultimately  allows a  profit to be earned,
 although  that profit may be realized for accounting purposes  at another
 stage of  the  production  process such as the mine or refinery.

     4)   Competition.  Mines have long-run flexibility in  deciding
where they will  send their copper concentrate for smelting. Therefore,
copper  smelters  face competition from three sources: other  existing
domestic  smelters, new smelters that may  be built, and foreign smelters,
especially Japanese.  Other competition,  though less direct,  is also
                                   F-18

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 important.  For example, copper scrap and substitutes  such  as  plastic
 and aluminum present competition.

      Japan is a major force among  copper producing  countries in  terms
 of its volume of smelting,  refining,  and fabrication of copper.
 However, Japan does  not have copper ore deposits  of any noteworthy
 size.   Therefore it  must import concentrates  in order  to supply  its
 smelting, refining,  and fabricating facilities.  Japan seeks concen-
 trates from many countries, including the United  States.  Japan's
 ability to be competitive with U.S. smelters   for U.S. concentrates is
 indicated by the contractual  arrangements it  has  established with
 Anamax and Anaconda  to purchase concentrates.   Also, the Japanese
 smelters have approached many other copper mine owners in the  United
 States.  For example,  Cyprus Corporation is reported to have seriously
 considered shipping  concentrates from its Bagdad  mine  to  Japan.

      The cost to transport  concentrates across  the  Pacific Ocean is
 significant.   The fact that Japanese  smelters can compete with U.S.
 smelters, in spite of  the costs to  transport concentrates across the
 Pacific Ocean,  is quite noteworthy.   One factor that explains the
 Japanese ability to  compete is  that Japanese smelters  are newer than
 U.S.  smelters and, in  theory,  should  be more cost competitive.   Other
 factors that operate to the advantage of Japanese smelters, including a
 protective tariff mechanism,  are described  later.

     The existence of  competition for concentrates  introduces what is
 commonly referred  to as  a "trigger" price.  The "trigger" price is that
 price  which triggers or provides an economic incentive  for the supplier
 of  concentrate  to  change  to another smelter and refinery.  If a given
 smelter charges  a  service fee  in excess  of competing smelters,  that
 smelter will  lose  business  and  eventually be forced to cease operations.
 In  the case of  new smelters or  expansions, the new process facilities
 will not be built.   Faced with  an increase in costs, a smelter  could
 respond using one of three  options, or  any combination of the three.
 First,  the  smelter could  pass the costs  forward in the form of  a price
 increase.   Two  important  considerations with respect to a price increase
 are: the prices  of competitors  in the copper business,  and the  elasti-
 city of demand  for the  end  users of copper.  For example, even  if all
 copper producers experience the  same  increase in costs, at some point
 the end  users of copper will consider changing to  a substitute.
 Second,  the smelter  could absorb the cost increase by  reducing  its
 profit margins, thereby reducing its return on investment (ROI).   If
 the smelter's profit margins are reduced significantly  it will  cease
 operation.  Third, the smelter could pass the costs  back to  the mines
 by reducing the price it  is  willing to pay for concentrate.   An import-
 ant consideration in setting the service fee a smelter  charges  for
 custom or toll smelting is that the concentrate may  be  shipped  else-
where,  such as to Japan.  Market conditions suggest  that the option  of
 passing costs back to the mines does not seem  feasible  at this  time,
due to the existence  of excess smelting capacity.
                                   F-19

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     F.2.3.1  Japanese Tariff Mechanism.  One example of foreign
government assistance to the copper industry occurs in Japan.  Japanese
copper producers operate under a system that permits the payment of a
premium for concentrates, which is then recovered through a premium for
refined copper, due to a protected internal market supported by a high
tariff.  Japan imposes high import duties on refined unwrought copper,
while allowing concentrates to be shipped into the country duty-free.
Duty on refined unwrought copper in 1981 was 8.2 percent of the value
of the copper, including freight and insurance, as opposed to a U.S.
customs duty of 1.3 percent of the value of copper.  The import duties
allow Japanese producers to sell their refined copper in Japan at an
artificially high price and still remain competitive with foreign
producers.

     Specifically, copper concentrates and ore imported into Japan are
free of duty.  Refined copper imported into Japan is subjected to a
tariff of 15,000 yen/Mg.29  Using a December 1982, exchange rate of
$0.003623/yen, the tariff was $0.0543/kg.  Refined copper may be
duty-free under the preferential tariff, subject to certain limitations.

     As a result of the tariff situation, Japanese copper producers can
pay a premium to attract concentrates and can recover the premium
through a premium on the price of the refined copper used in Japan.  If
the refined copper is returned to the customer outside of Japan, the
premium on the price of refined copper is not recovered because world
prices would prevail in this case, rather than the protected internal
Japanese producer price.  As a result, the principal interest of the
Japanese copper producers is in producing copper for internal consump-
tion.  Toll smelting in Japan is generally used as a means of balancing
inventories.  The absence of a tariff on ore and concentrates encourages
companies to import ore into Japan.  The presence of a tariff on
refined copper and the costs of holding metal in Japan discourage
companies from importing refined copper into Japan.

     The Japanese tariff on refined copper, combined with the cost of
holding the metal until  users have a demand for it, provides an extra
margin for Japanese copper producers.  The Japanese producers can
charge what the market will bear for their copper and still  remain
competitive with the importers.  The loss incurred by Japanese producers
in charging toll customers low processing rates is covered by the extra
margin of profit realized by charging prices for Japanese refined
copper at competitive import levels.

     Robert H. Lesemann (industry expert, formerly with Metals Week,
now with Commodities Research Unit), in an affidavit for the Federal
Trade Commission, outlined the situation in September 1979:

          It is generally true that operating costs of
          U.S. smelters  are the same as smelters in Japan,
          Korea, and Taiwan.  The competitive advantage
          is without doubt due to the subsidies outlined
          above.  Thus,  while the terms of the Nippon-
                                   F-20

-------
           Amax  deal  have  not  been  revealed, the treatment
           charge  is  likely  well  below  the operating cost
           levels  of  U.S.  smelters.30

      F.2.3.2  Other  Japanese  Advantages.  The tariff mechanism described
 above is  one  example of government  assistance to the Japanese copper
 industry.   Another example  is provided by the Japanese government's
 approval  of a brass  rod production  cartel.  In an effort to  reduce
 stocks and boost  profit margins  for the ailing Japanese brass rod
 industry,  the government  officially approved the formation of a tempor-
 ary  cartel  to cut production.31

      Apart from government  assistance,  other reasons are cited for the
 advantage  of  the  Japanese copper industry over the U.S. copper industry.
 Additional  reasons include:

      • A  high  debt-to-equity  ratio—a  typical Japanese smelter may
        have  a  debt-to-equity  ratio of  0.8 to 0.9.32»33»34

      « Lower labor  rates—Japanese hourly rates in the primary metals
        industry  were estimated  to  be  about two-thirds of the U.S. rate
        in 1978.35

      • By-product credits—the  market  for by-products, sulfuric acid,
        and gypsum is better  in  Japan than in the United States and
        reduces operating costs  significantly.36

 F.2.4  Maximum  Percent Price  Increase

      Insight  into the economic effects  of the arsenic NESHAP can be
 gained  by  examining  the maximum  percentage copper price increase that
 would occur if  all control costs were passed forward.  A complete pass
 forward of  control costs may not be possible in every case, and later
 in the  analysis this  assumption  is  relaxed.  However, the initial
 assumption  that a complete pass  forward is possible in every case
 introduces  a  common  reference point, which then facilitates comparisons
 of various  control alternatives  and scenarios.

      The maximum percentage price increase is calculated using a
 simplified  approach,  for ease of presentation, that divides annualized
 control costs by the  appropriate production and further divides that
 result by the refined price of copper, with the result expressed as the
 necessary percentage  price increase per kilogram.   The above approach
 does  not consider the investment tax credit,  and thus is a conservative
 approach that will tend to overstate the effects of the control  costs.
 The investment tax credit would act to reduce the capital  cost of the
 control equipment  by ten percent.  Other approaches could be used to
determine price increases.  For example, a net present value (NPV)
 approach could be  used.  A net present value approach determines  the
 revenue increases  necessary to exactly offset  the control  costs,  such
that the NPV of the  plant remains constant.   An NPV analysis can
also take into account the investment  tax  credit,  depreciation over the
                                   F-21

-------
 applicable  time  period,  income taxes, operating and maintenance costs,
 and  the  time  value  of money.  Although the NPV approach is a more
 sophisticated calculation, the two  approaches yield similar results.
 Therefore,  the first method is preferable in this particular case due
 to its straightforward nature, ease of presentation, and reasonable
 results.

     Table  F-6 shows the  cost increase, and then Table F-7 shows the
 maximum  percentage  price  increase,  of arsenic controls'for primary
 copper smelters.  The increase in the cost of production is shown for
 two  capacity  utilization  rates, 100 percent and 80 percent.  The
 advantage of  presenting two capacity utilization rates is in the
 conduct  of  sensitivity analysis.  A rate of 100 percent is optimistic,
 but  is useful  here  as a  reference point.  A rate of 80 percent is more
 likely and  as noted in Section F.I  this is the approximate industry
 average  utilization rate  achieved in 1981.  For 1982, the industry
 average  capacity  utilization rate was substantially lower at 59
 percent.  However,  no analysis is shown here of the impact of control
 costs on the  industry at  a 59 percent utilization rate because regard-
 less of  control costs, a  rate of 59 percent is damaging to the industry
 even as  a baseline  condition.  Alternatives II, III, and IV are shown
 as well  as  the combination of III+IV.  The smelters are ranked according
 to the cost of Alternative III+IV (with the exception of Kennecott-
 McGill).  The Kennecott-McGi11 smelter is shown last because it is the
 only smelter  faced with costs under Alternative II.  The purpose of
 showing  the increase in production  cost is to supplement the maximum
 percentage  price  increase that is discussed later.  One advantage of
 reviewing the cost  increase is that it is only dependent on the capa-
 city utilization  rate, and is not affected by the refined price of
 copper.  A  second advantage is that it is not affected by the choice of
 the profit  center.  Several points  should be observed from the cost
 increases:

     1)  The  amount of the cost increases are substantial  for two of
 the  smelters  in particular, Cities Service-Copperhill, and Kennecott-
 McGill.  The  cost increases are substantial  for several reasons.
 First, copper is a commodity, which means that product differentiation
 is not possible and thus competition is based almost exclusively  on
 price.  The copper producers can be characterized as price-takers and
 thus no individual producer controls the marketplace.   Therefore, in an
 industry that  competes based on price, the cost of production becomes
 exceptionally  important.   Second, copper is traded on  an international
 basis and thus domestic producers compete among themselves,  as well  as
 against foreign producers that may not experience the  same  cost in-
creases.   Finally, copper is faced with a significant  threat from
substitutes:  such as,  aluminum and plastic.

     2)  Within a single  alternative, the differences  among  smelters
are substantial.   As described above, copper producers compete princi-
pally on  price.  As a result,  the cost of production is quite important.
Therefore differences  in  costs among smelters of  as  little  as  several
cents per kilogram of  copper are important.
                                   F-22

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      3)  The cost  increases for Alternative  II are 0 in every case with
one exception, Kennecott-McGi11.   For Kennecott-McGi11 the costs for
Alternative II are large.  The cost  increases for Alternative III range
from  a low of 0.4^/kg to a high of 9.4^/kg.  The costs for Alternative
IV are lower, and  range from 0 to  1.9£/kg.   The costs for Alternative
III+IV range from  0.4i£/kg to 11.3jd/kg.

      Table F-7 shows maximum percentage price increases.  The purpose
of reporting the maximum percentage  price increase figures is to add
perspective to the cost increase figures.  Results are shown for two
refined copper prices (187 cents per kg. and 220 cents per kg.), and
for the same two capacity utilization rates  presented earlier, 100
percent and 80 percent.  The same  cases are  shown as were presented
earlier for the cost increases, Alternatives II, III, IV, and III+IV.
The price increase assumes the firm  is an integrated producer.  The
average annual price for refined copper over the past five years, from
1978  to 1982, has  been approximately 187 cents per kg.  The price of
copper is difficult to predict, and  therefore a second price is exam-
ined.  As shown previously in Section F.I, the highest average annual
current dollar price for refined copper was 225.3 cents per kilogram,
achieved in 1980.   (The year 1980 was marked by an industry strike and
reduced production.)  Therefore, 220£/kg is used to represent a price
that, based on the results of past years, appears optimistic.  This
"optimistic" price of 220£/kg is useful as a reference point for
sensitivity analysis and also as an  approximate upper limit to the
range of probable  serious economic effects.  At a price greater than
220^/kg the financial health of the  industry would be improved
dramatically and consequently the effects of the control costs would be
reduced sharply. An alternative "pessimistic" price is not presented
because even the baseline results are highly likely to be damaging
using a pessimistic price, and thus the addition of control costs would
merely reinforce an obvious conclusion.  A ready example of the effects
of a  price significantly below 187^/kg was provided in 1982 when the
average price for  the year was about 163^/kg and large segments of
the industry closed for sustained periods.

     The analysis  of the results for the maximum percentage price
increase figures is similar to the analysis discussed above for the
cost  increase figures.  Once again, for Alternative II only Kennecott-
McGill experiences a price increase.   The price increase is high, 12.1
percent based on a 100 percent capacity utilization rate and a price of
187^/kg.  For Alternative III the maximum price increases range from
0.2 to 5.0 percent.  For Alternative  IV the price increases are lower,
and range from 0 to 1.0 percent.   For Alternative III+IV the price
increases range from 0.2 to 6.0 percent,  with two smelters above 2.2
percent.   The two smelters are Cities Service-Copperhill  at 6.0 percent
and Kennecott-McGi11 at 2.9 percent.   There is some variation in the
price increases among the smelters.  The significance of the variation
in the maximum percentage price increases among the smelters  is that
those smelters with higher price increases would probably be constrained
in the marketplace by those smelters  with lower price increases.   As a
result, at least some of the smelters could quite possibly have to
                                   F-25

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absorb a part of the control  costs.  As mentioned above,  two additional
constraining influences are foreign competition and substitutes.

F.2.5  Maximum Percent Profit Reduction

     Apart from the calculation of maximum percentage price increase,
additional insight into the economic effects of the arsenic NESHAP can
be gained by making the opposite assumption from maximum percent price
increase, that is, zero percent price increase, or complete control
cost absorption.  The assumption of complete control cost absorption
provides a measure of the reduction in profits if the control costs are
absorbed completely.

     Assuming control costs are absorbed, the critical element in an
analysis of profit reduction is the profit margin.  The larger a firm's
profit margin, the greater is the firm's ability to absorb control
costs and earn an acceptable rate of return on investment (ROI), and
thus continue operation.  The profit margin is simply the difference
between price and production cost.  As mentioned in an earlier section,
the central issue becomes the choice of an appropriate profit center
and its corresponding price and cost.  The processing of virgin ore
into refined copper involves four distinct steps:  mining, milling,
smelting, and refining.  Although the four steps are often joined to
form an integrated business unit, they are not inextricably bound
together  in an economic sense.  For example, it  is not uncommon for
mines to  have their concentrate toll smelted and refined.  The diffi-
culty that this variability presents in terms of an assessment of the
effects of the arsenic standard is in the method of assigning the
costs.

     This report  presents an analysis of profit  impacts using two
methods.  The first method assumes copper producers are fully inte-
grated and all have the same costs and thus earn a uniform profit
margin.   The objective of this method is to permit a  ready, and uni-
form, examination of  profit impacts.  With the first method as a
foundation, the second method introduces more smelter specific vari-
ables into the analysis in an effort to focus more sharply on the
complex organizational structure  of the industry.

     F.2.5.1  Method  One.  As mentioned above, the critical element  in
an  examination of profit reduction is the profit margin.  Therefore  an
examination of profit margins for members of the industry is presented
below.  Table F-8 shows the revenues and operating profit (before tax)
for each  of the seven copper producers that own  smelters, for the
period from 1977  to 1982.  Table  F-8 also shows  the percentage profit
margin, which is  operating profit divided by revenues.  The  revenue  and
operating profit  figures are for  the business  segment within the
company that includes copper.  The use of business  segment  information
provides  a closer representation  of the results  for copper than would
the use of the consolidated results for the company.  The reason  for
this is that for  several of the firms  copper represents a relatively
small share of the total company  results.  Although the business
                                   F-26

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           Table F-8.  BUSINESS SEGMENT RETURN ON SALES FOR COPPER COMPANIES*
                                           ($ 103)

Revenues





Year
1977
1978
1979
1980
1981
1982
Operating 1977
Profits 1978
1979


Profit/
Revenues
(percent)

I
i

1980
1981
1982
1977
1978
1979
1980
1981
1982
Average
ASARCO
733,293
849,002
1,339,917
1,440,220
1,153,022
1,074,014
65,919
112,474
225,763
145,286
68,364
35,783
9.0
13.2
16.8
10.1
5.9
3.3
9.7
Cities
Servi ce
184,000
241,500
276,300
224,100
NA
NA
(38,600)
(23,900)
25,400
16,300
NA
NA
(21.0)
(9.9)
9.2
7.3
NA
NA
(3.6)
Copper
Rangeb
NA
64,600
89,300
83,900
72,300
36,400
NA
(6,600)
10,000
1,800
(20,600)
(42,000)
NA
(10.2)
11.2
2.1
(28.5)
(115.4)
(28.2)
Inspiration0
95,676
101,251
136,849
178,004
NA
NA
(9,994)
(6,235)
9,889
(6,563)
NA
NA
(10.4)
(6.2)
7.2
(3.7)
NA
NA
(3.3)
Kennecott
NA
683,000
1,091,400
987,400
539,000
596,000
NA
(100)
164,000
131,400
(99,000)
(187,000)
NA
0
15.0
13.3
(18.4)
(31.4)
(4.3)
Magmad
NA
274,137
381,512
287,581
328,842
221,001
NA
13,601
67,252
11,522
(15,658)
(30,790)
NA
5.0
17.6
4.0
(4.8)
(13.9)
1.6'
Phelps
Dodge
453,184
446,970
618,188
714,591
706,404
426,509
52,831
63,738
159,428
95,439
27,618
(78,104)
11.7
14.3
25.8
13.4
3.9
(18.3)
8.59
Business segments contain other products in addition to copper.
bThe figures are for The Louisiana Land and Exploration Company which
 acquired Copper Range in May 1977.
cAcquired and privately-owned after 1980 by Anglo American Corp. of
 South Africa through a complex arrangement that includes Minerals &
 Resources Corp. (Minorco), Hudson Bay Mining & Smelting Co.,, and Plateau
 Holdings Inc.
dProfit is net income after tax in this case.
eBefore interest and tax.               *
fWould yield 2.3 percent if adjusted to before tax with an effective
 tax rate of 30 percent.
9lmputed profit on intersegment sales for 1977 to 1982  would  yield
 average return of about 9.8 percent.
                                        F-27

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segment Information is a better representation of the results for
copper than the total company results, the business segments contain
other products in addition to copper.  Therefore conclusions must be
drawn accordingly.  The table shows that there is considerable variation
in results, both within a company from one year to the next, as well as
from one company to the next.  The averages range from a loss of 28.2
percent to a high of 9.7 percent.  Rather than a profit, four of the
seven companies show an average loss.

     Table F-9 shows the maximum percentage reduction in the profit
margin for each of the 14 smelters.  This table assumes each smelter is
viewed as part of a fully integrated operation.  Two profit levels are
shown and two capacity utilization rates (100 percent and 80 percent).
The first profit level is based on a refined copper price of 187^/kg
and a 10 percent profit margin, which yields a profit of 18.7jd/kg.
The second profit level is based on an increased price of refined
copper to a level of 220£/kg.  The second profit margin is based on
the original 18.7£/kg. but adds the increase in price as extra profit
while process costs are held constant.  The second profit margin is
51.7ji/kg.  Three considerations suggest the use of the second profit
margin.  The first consideration is the desirability of presenting
sensitivity analysis in general.  The second consideration is that
a profit margin of 51.7£/kg. based on a price of 220^/kg. is a
margin of 23.5 percent, which though clearly high, has been achieved
within recent years by a member of the industry.  Finally, because the
margin is high, it in effect can be viewed as an upper limit, and thus
any smelter that has a
substantial profit reduction in spite of such a favorable profit margin
is in a very vulnerable position at a lower, more likely, profit
margin.

     The same cases discussed earlier are still applicable, the results
on Table F-9 are for Alternatives II, III, IV, and III+IV.  At the
first profit margin (18.7£/kg.), with a 100 percent capacity utiliza-
tion rate for Alternative III + IV, eight smelters have a maximum
profit reduction of 15 percent or less, and three smelters have a
reduction of 15 to 20 percent.  The results show a maximum profit
reduction of greater than 20 percent for three of the 14 smelters
(Kennecott-Hurley, Cities Service-Copperhill, and Kennecott-McGi11) at
the 100 percent capacity utilization rate for Alternative III+IV.  At
the more likely level of an 80 percent capacity utilization rate, six
smelters have a reduction of 15 percent or less, four smelters have a
reduction of between 15 and 20 percent, and four smelters exceed 20
percent (Kennecott-Hayden, Kennecott-Hurley, Cities Service-Copperhill,
and Kennecott-McGi11).  A profit reduction in excess of 20 percent is a
substantial reduction, but when viewed in isolation is not a definite
indicator of closure.  However, a profit reduction in excess of 20
percent, when viewed together with the generally depressed economic
condition of the copper industry, is a cause for concern about the
ability of the four smelters in this category to continue in operation.
Also, Table F-9 shows that of the four smelters between 15 and 20
percent, three smelters have profit reductions in excess of 19 percent,
                                   F-28

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which though  less  than  20  percent,  is  not  appreciably different from 20
percent.   For two  of  the above  smelters  (Cities Service-Copperhill and
Kennecott-McGill)  the profit  reduction is  greater than 30 percent at
the 80  percent capacity utilization rate,  and  greater than 50 percent
for one smelter (Cities Service-Copperhill).   Profit reductions of
greater than  30 percent would seriously  call into question the continued
viability  of  these two  smelters.

     At the second, higher, profit  margin  (51.74/kg.) the profit
reductions are lessened substantially.   Only two smelters have profit
reductions of greater than 10 percent.   However, the Cities Service-
Copperhill smelter continues  to experience profit reductions of greater
than 20 percent.

     F.2.5.2   Method  Two.  Method two  uses method one as a starting
point and  then supplements it with  additional  information, some of
which is qualitative.   Table  F-10 provides an  added means to identify
those smelters  that are most  likely to face the greatest impact.
Method  one assumed that each  smelter was part  of a fully integrated
operation.  However,  not all  smelters  are  integrated to the same
degree, and therefore additional variables are introduced in method two
in order to examine the degree  of integration  for each smelter.  The
significance  of whether a  smelter is analyzed  as part of an integrated
business unit  or analyzed  on  a  "stand  alone" basis is that the financial
effect  of  the  control costs is  greater for a smelter that must "stand
alone", versus  a smelter that is part of an integrated operation.
Additionally,  a smelter plus  a  refinery could  be considered together as
a single business  unit, depending on the individual  circumstances.  For
example, the  production costs associated solely with smelting (excluding
mining, milling, and  refining)  will  vary depending on the individual
smelter but a  representative  figure is approximately 42£/kg.  This
represents about 25 percent of  total production costs from mining
through refining.  Therefore if  the  total  integrated profit presented
earlier of 18.7/4/kg is  apportioned  to each stage of production in
proportion to the  costs associated  with each stage of production the
result  is  th-at  only about  25  percent of the total profit of 18.7/i/kg
is assigned to  the smelter. The net  effect is  that if the control  costs
are charged against only the  smelter's share of the total  profit the
control costs  increase  in  importance.

     Table F-10  starts  by  showing the smelters ranked according to the
profit  reduction described earlier  for Alternative III+IV at the 80
percent capacity utilization  rate .  The size  of the profit reduction
and the rank provides one  indication of the potential  effect of con-
trols.  A caveat that should  be mentioned concerning this indicator is
that it does not take into consideration baseline costs.   The profit
reductions expressed on the basis of a fully integrated operation  were
discussed previously in method one and will not be repeated here.
However, for perspective,  if the smelters are  viewed on a stand alone
basis, rather than as part of a fully integrated operation, the size  of
the profit reductions could at least double.
                                   F-30

-------




























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      A second indicator that  is  presented  to  provide  additional  insight
 into  a firm's possible reaction  to control  costs  is a review  of  any
 major capital commitments to  the smelter that a  firm  has made recently.
 Most  of the firms  with the lower control cost increases have  also
 recently made major capital commitments  to  their  smelters which  in turn
 suggests a stronger commitment to the continued  operation of  a smelter
 than  a firm that has postponed capital expenditures for a smelter.

      A third indicator is provided by a  review of whether or  not a
 smelter has a major integrated mine that supplies much or all  of its
 concentrates.  The presence of a major mine near  a smelter does not
 guarantee that a firm will  consider the  mine  and  smelter as a single
 business unit.  For example,  both the Phelps  Dodge-Ajo smelter and the
 Kennecott-Hayden smelter have been closed  in  spite of the fact that the
 mines located near these two  smelters have  been open.  However, in
 general  a smelter  that is associated  with  a major mine is likely to be
 considered as an integrated operation.

      A fourth indicator is  provided by a review of whether or not a
 smelter is closely associated with a  refinery.  Similar to the situa-
 tion  with a mine,  the existence  of a  refinery closely associated with a
 smelter does not guarantee  that  a firm will consider  the smelter and
 refinery as a single business unit.   However,  in  general this  is likely
 to  be the case because if a closure occurs  at a smelter that  provides
 all,  or a substantial  percentage,  of  the copper supply for a  refinery
 this  will  have serious consequences for the refinery.

      A fifth indicator is provided by the estimates of others  who have
 analyzed the smelters.   The estimates are from four sources as noted in
 the references.  The estimates are based on the overall economic and
 environmental  outlook  faced by the smelters,  and  are  not estimates
 related  specifically to  arsenic  control costs.

      A sixth and final  indicator is provided  by a  review of the recent
 operating  status of  the  smelters.   Those smelters  that have recently
 been  closed  for  sustained periods  of  time are obviously in a vulnerable
 financial  condition  even  in the  absence of arsenic control  costs.
 Therefore  the weak baseline financial condition of those smelters
 reduces  the  affordability of  arsenic  control  costs.  Two smelters are
 involved  in  major modernization  programs, ASARCO-Hayden and  Kennecott-
 Hurley.

 F.2.6  Capital Availability

     The principal  determinant of the financial viability  of a smelter
 is profitability.  However, the amount of capital  needed to  purchase
 control equipment is one of the components  that enters into  an evalua-
tion of profitability.  Most firms prefer to finance  pollution control
equipment with debt, both because debt is less expensive than  equity  in
general, and additionally because debt incurred to purchase  pollution
control equipment is often tax exempt.  Assuming  control equipment  is
financed with debt, as the capital cost of  the control equipment
                                   F-32

-------
increases, the  level  of debt  increases.  An increased debt level means
the fixed costs  required to service the debt  increase and therefore the
level of risk increases.  As  a  result, a discussion of capital avail-
ability will serve to  supplement  an assessment of profitability.

     Table F-ll  shows  the pollution control capital expenditures that
will be necessary for  each firm and for each  smelter.  The component"
parts of the capital  expenditures were explained in detail in an
earlier section  and will not  be repeated here.  The baseline capital
expenditures are presented, as  well as the capital expenditures for
Alternatives II, III,  IV, and III+IV.  Three  firms own more than one
smelter and in those three cases  the total capital costs are shown,
although the firms can make capital budgeting decisions on an individual
smelter basis.   The capital costs for the smelters are not trivial
sums.  However,  all seven companies are major corporations with a large
capital base.  Additionally,  five of the seven companies are owned
wholly, or to a  substantial degree, by significantly larger parent
corporations and thus  are quite likely to have access to the necessary
capital.  The remaining two companies that are not owned by some other
corporation are  ASARCO and Phelps Dodge.

     For these two companies  Table F-ll shows the percent increase in
long-term debt if controls are  added.  For the other companies the
increases are below one percent and are not shown.  The pre-control
debt level is based on a 3-year average (1981 to 1979) debt level for
each company.  Controls are assumed to be financed totally with debt.
The baseline percentage increase in debt is 24 percent for ASARCO and
16 percent for Phelps Dodge.  These increases are considerable.  For
Alternatives II, III,  IV, and III+IV the incremental  increases are
                     In ASARCO's case the increases are 0, 2, 1, and 3
                     ,  In the case of Phelps Dodge the increases are 0,
6, 1, and 7 percent, respectively.  The capital  costs associated solely
with Alternatives II, III, IV,  and III+IV do not, in isolation, suggest
a major capital   availability  problem.  However,  the baseline increase,
taken together with the alternatives, is a considerable increase and
may be a problem for these two  companies.

     An additional  indicator of capital  availability is provided by the
debt rating assigned to a company by one of the major national  rating
services.  Although the rating  is assigned specifically for a company's
debt, the factors that enter into a debt rating  include the overall
financial condition of a company.  Therefore a debt rating is also an
indirect measure of the overall  financial  condition of a company.   In
1982, as well  as 1981 and 1980,  ASARCO1s debt was rated as A3 by
Moody's.40  This is an investment grade rating,  but it is  the lowest
A rating.  In  1982, the debt rating by Moody's for Phelps  Dodge was
lowered to Baa2  from its previous rating in 1980 and  1981  of A.
Although Baa2  is still a relatively strong  rating,  the fact that
it was lowered from 1981 to 1982 is a negative factor and  suggests  that
substantial  increases in the amount of debt held by the company may
present some  difficulties.
generally moderate.
percent respectively,
                                   F-33

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               Table F-ll.   CAPITAL COSTS OF ARSENIC CONTROLS
                               FOR PRIMARY COPPER SMELTERS
                                          ($103)
Alternative
Company
ASARCO


Cities Service
Copper Range
Inspiration
Kennecott




Newmont
Phelps Dodge





Smelter
El Paso
Hayden
Debt Increase3'
Copperhill
White Pine
Mi ami
Garfield
Hayden
Hurley
McGill

Magma
Ajo
Douglas
Hidalgo
Morenci

Debt Increase3
Baseline
46
75,606
75,652
b 24%
0
0
0
0
0
54,044
0
54,044
0
0
0
0
95,294
95,294
16%
II
0
Q_
0%
0
0
0
0
0
0
10,530
10,530
0
0
0
0
0
0
0%
III
1,894
3,660
5,554
2%
4,434
4,434
9,825
8,800
8,000
8,760
9,000
34,560
13,050
6,731
9,825
6,731
12,971
36,258
6%
IV
370
0
"370
1%
893
893
922
7,828
894
952
893
10,567
1,786
894
1,787
894
1,786
5,361
1%
III+IV
2,264
3,660
"5792T
3%
5,327
5,327
10,747
16,628
8,894
9,712
9,893
45,127
14,836
7,625
11,612
7,625
14,747
41,619
7%
aPercent increase in average long-term debt level for the 3 years
 (1981 to 1979) if controls are added as debt.
Increases of less than one percent for a firm are not shown.
                                  F-34

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 F.3  SOCIO-ECONOMIC IMPACT ASSESSMENT

 F.3.1  Executive Order 12291

      The purpose of Section F.3.1 is to address those tests of macro-
 economic impact as presented in Executive Order 12291, and, more
 generally, to assess any other significant macroeconomic impacts that
 may result from the NESHAP.  Executive Order 12291  stipulates  as "major
 rules"  those that are projected to have any of the  following impacts:

      9     An annual  effect on the economy of $100 million or more.

      •     A major increase in costs or prices for consumers; individual
           industries;  Federal,  State,  or local  government agencies;
           or geographic  regions.

      •     Significant  adverse effects  on competition,  employment,
           investment,  productivity, innovation,  or  on  the ability of
           U.S.-based enterprises  to compete with foreign-based  enter-
           prises in  domestic or export markets.

      F.3.1.1  Annualized Control  Costs.   The annualized  control  costs
 for each of the four alternatives is well  below  the $100 million which
 is  the  figure used to  identify  a  major rule.   The annualized control
 costs for  Alternatives II,  III, IV, and  III+IV  are $4.1  million, $29.1
 million, $6.0 million, and  $35.1  million,  respectively.

      F.3.1.2 Regional Effects. Employment  and Competition.  Most of
 the 14  primary  copper  smelters  are located  in the Southwestern  United
 States,  and in  particular,  seven  smelters  are  located  in  Arizona.  As a
 result,  economic impacts would  be concentrated in that geographical
 area.

      A  copper smelter  typically employs  about 500 people.  A smelter
 has  an  indirect  as well  as  a direct  effect  on employment  in its  local
 community.   The  indirect  effect is  twofold; one  part of  it results from
 the  local  business purchases  that  a  smelter makes, and the other part
 results  from the  local consumer purchases by smelter employees  and
 their families.   These expenditures  generate additional employment at
 local firms.  An  estimate of  the  employment multiplier for the  smelting
 industry is  approximately 1.6.

      The domestic  copper producers  compete among themselves, as well  as
 against  foreign copper producers and substitutes such as aluminum and
 plastics.  Any substantial  increase  in costs will put pressure on the
 competitive position of some domestic smelters with  respect to  other
 domestic smelters, and also with respect to foreign  copper producers
 and substitutes.

 F.3.2  Regulatory Flexibility

     The Regulatory Flexibility Act of 1980 (RFA) requires that differ-
ential impacts of Federal regulations upon small  business be identified
                                  F-35

-------
 ential  impacts  of  Federal  regulations upon small business be identified
 and analyzed.   The RFA  stipulates that an analysis is required if a
 substantial  number of small businesses will experience significant
 impacts.  Both  measures must be met, substantial numbers of small
 businesses and  significant impacts, to require an analysis.  If either
 measure is not  met then no analysis is required.  The EPA definition of
 a substantial number of small businesses in an industry is 20 percent.
 The EPA definition of significant impact involves three tests, as
 follows:  one,  prices for small entities rise 5 percent
 assuming costs  are passed forward to consumers; or two,
 investment costs for pollution control are greater than
 of total capital spending; or three, costs as a percent
 small entities  are 10
 for large entities.
                                  or more,
                                  annualized
                                  20 percent
                                  of sales  for
percent greater than costs as  a percent  of sales
     The Small Business Administration (SBA) definition of a small
business for Standard Industrial Classification (SIC) Code 3331,
Primary smelting and refining of copper is 1,000 employees.  Table  F-12
shows recent employment levels for each of the seven companies that own
primary copper smelters.  All seven have more than 1,000 employees.
Therefore, none of the seven companies meets the SBA definition of  a
small business and thus no regulatory flexibility analysis is required.
                                   F-36

-------
              Table F-12.  NUMBER OF EMPLOYEES AT COMPANIES
                           THAT OWN PRIMARY COPPER SMELTERS
       Company
Employees
     Source3
ASARCO, Inc.
Cities Service Co.
Copper Range Co.b
Inspiration Consolidated
  Copper Co.
Kennecott Corp.c
Newmont Mining Corp.
Phelps Dodge Corp.	
  9,800
 18,900
  3,049
  2,180

 35,000
  9,900
  9,678
1982 SEC 10-K p. A3
1980 SEC 10-K p. 6
1980 SEC 10-K p. 22
1980 SEC 10-K p. 2

1980 SEC 10-K p. 10
1982 SEC 10-K p. 5
1982 SEC 10-K p. 1
aSEC 10-K is Securities and Exchange Commission,  Form 10-K.
bCopper Range Co. is a wholly-owned subsidiary of the Louisiana Land  and
 Exploration Company.  Figures are for Louisiana  Land and Exploration.
cPrior to merger with Sohio on March 12, 1981.
                                   F-37

-------
F.4  References
  1.   Review of New Source Performance Standards  for  Primary  Copper
       Smelters — Background Information  Document,  Preliminary Draft.
       U.S. Environmental  Protection Agency.   Research Triangle Park,
       North Carolina.   Publication  No. EPA-February 1983.   p. 3-2.
  2.   ASARCO, Inc., Form  10-K.   December  31,  1980.  p. A2.
  3.   Cities Service Co., Annual  Report 1980.  p.  41.
  4.   The Louisiana Land  Exploration Co.,  Form 10-K.  December 31,
       1980. p. 16.
  5.   Inspiration Consolidated  Copper Company,  Annual Report 1980. p. 2.
  6.   Kennecott Corp.,  Form  10-K.   December 31, 1980.  p. 4.
  7.   Newmont Mining Corp.,  Form  10-K.  December  31, 1980.  p. 3.
  8.   Phelps Dodge  Corp., Form  10-K.   December 31,  1980.  p. 2, 4.
  9.   Butterman,  W.C.   U.S.  Bureau  of Mines.   Preprint from the 1981
       Bureau of Mines Minerals  Yearbook.   Copper,   p. 3.
 10.   Butterman,  W.C.   U.S.  Bureau  of Mines.   Mineral Industry Surveys.
       Copper Production in December 1982.  p.  2.
 11.   Schroeder,  H.  J.  and James A. Jolly.  U.S.  Bureau of Mines.
       Preprint from Bulletin 671.   Copper  - A  Chapter from Mineral
       Facts and Problems, 1980  Edition,  p. 14-16.
 12.   Annual  Data 1982.   Copper Supply  and Consumption.  Copper
       Development Association Inc.   New York,  New York.  p. 6, 14.
 13.   Reference 11,  p.  5.
 14.   Reference 9,  p. 1.
 15.   Reference 9,  p. 5.
 16.    Arthur  D. Little, Inc.  Economic  Impact of Environmental Regula-
       tions on  the United States Copper Industry.  U.S. EPA.  January
       1978.   p. V-8.
 17.    Reference 9, p. 24-29.
 18.    Reference 12,  p.  14.
 19.    Reference 11,  p.  14.
                                  F-38

-------
 20.    Reference  12, p. 18.

 21.    Copper's Hope:  Electric Vehicles.  Copper Studies.  Commodities
       Research Unit, Ltd.  New York.  March 30, 1979, p. 5.

 22.    Copper in  Military Uses.  Copper Studies.  Commodities Research
       Unit, Ltd.  New York, February 15, 1980.  p. 1.

 23.    Butterman, W.C.  U.S. Bureau of Mines.  Mineral Industry Surveys.
       Copper in  1982 - Annual, Preliminary,  p. 2.

 24.    Butterman, W.C.  U.S. Bureau of Mines.  Preprint from the 1980
       Bureau of  Mines Minerals Yearbook.  Copper,  p. 1.

 25.    Schroeder, H. J., and G. J. Coakley.  U.S. Bureau of Mines
       Preprint from the 1975 Minerals Yearbook.  Copper,  p. 2.

 26.    The Capital Cost Picture.  Copper Studies.  Commodities Research
       Unit, Ltd.  New York.  August 18, 1975.  p. 1.

 27.    Rosenkranz, R.D., R.L. Davidoff, and J.F. Lemons, Jr., Copper
       Availability-Domestic:  A Minerals Availability System Appraisal.
       U.S. Bureau of Mines.  1979.  p. 13.

 28.    Sousa, Louis J.  U.S. Bureau of Mines.  The U.S. Copper Industry:
       Problems,  Issues, and Outlook.  Washington, D.C.  October, 1981.
       p. 67.

 29.    Copper Imports on Preferential Tariff.  Japan Metal Journal
       (Tokyo).  December 8, 1980.  p. 3.

 30.    Affidavit of Robert J. Lesemann, Commodities Research Unit/CRI
       and former editor-in-chief of Metals Week, to the Federal  Trade
       Commission.  September 27, 1979.  FTC Docket Number 9089.

 31.    Brass Rod Production Cartel  Starts.   Japan Metal  Journal  (Tokyo).
       July 6, 1981.  p. 1.

 32.    Smelter Pollution Abatement:  How the Japanese Do It.  Engineer-
       ing and Mining Journal.   May 1981.  p. 72.

33.    Rieber, Michael.  Smelter Emission Controls:   The Impact  on
      Mining and The Market For Acid.  University of Arizona, Tucson,
      Arizona.   March, 1982.   p.  5-10.

34.   Custom Copper Concentrates.   Engineering  and Mining Journal.
      May 1982.  p.  73.

35.   Everest Consulting  Associates, Inc.,  and  CRU Consultants,  Inc.
      The International Competitiveness  of the  U.S. Nonferrous Smelt-
      ing Industry and the Clean  Air Act.   Princeton,  NJ.   April 1982.
      p. 9-9.
                                  F-39

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36.   Reference 32.
37.   Reference 33, p. 1-11.
38.   Everest Consulting Associates,  Inc.   The International  Competi-
      tiveness of the U.S. Non-Ferrous Smelting Industry and  the Clean
      Air Act.  Princeton, N.J.  April 1982.  p. 3-17.
39.   Phelps Dodge Corp. 1981 Annual  Report,  p. 8.
40.   Moody's Industrial Manual 1982 Vol.  I, p. 58, Vol. II,  p.  4236.
                                   F-40

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               APPENDIX G
  DEVELOPMENT OF MAIN STACK AND LOW-LEVEL
ARSENIC EMISSION RATES FOR THE ARSENIC PLANT
              AT ASARCO-TACOMA
                   6-1

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      DEVELOPMENT OF MAIN STACK AND LOW -LEVEL ARSENIC EMISSION RATES
                  FOR THE ARSENIC PLANT AT ASARCO-TACOMA

 G.I  INTRODUCTION

      Estimates of inorganic arsenic emissions from the ASARCO-Tacoma
 smelter were presented in the high-arsenic proposal BID, EPA-450/3-83-
 009a (III-B-1).  Since the standard was proposed, EPA has revised these
 emission estimates after making several visits to the smelter, and
 through an extensive test program.  On June 21 through 23, 1983, EPA
 conducted a comprehensive inspection of the smelter to identify poten-
 tial sources of low-level emissions and to document the particular
 control measures and practices already being applied at the smelter
 On September 12 through 29,  1983,  EPA conducted source testing on the
 No. 1 Cottrell and the arsenic plant main fabric filter (referred to as
 the  arsenic plant baghouse").  Results from these tests are presented
 in Appendix H.

      Arsenic emission rates  at ASARCO-Tacoma were estimated for two
 categories of sources:   (1)  main stack emissions, consisting of outlet
 gas streams from six control  devices  used at the smelter that are
 vented to the smelter's 563-ft main stack;  and (2) low-level  emissions
 or those from all  other arsenic emission  points at the smelter.   Main
 stack emission rates were derived  generally from an arsenic material
 balance for the smelter based on actual  smelter operations during 1982
 In the  case of the  arsenic plant,  contributions to main  stack emissions
 were determined from the September 1983,  test results  referred to above.

      Low-level  arsenic  emissions were  estimated for two  groups of
 emission controls.   The first group of controls  consists  of those in
 place at the ASARCO-Tacoma smelter  as  of  December 31,  1982.   The  second
 group includes the  additional  emission controls  that have  been applied
 since that time  or  are  planned under ASARCO-initiated  projects, ASARCO
 actions to comply with  the Tripartite  Agreement (IV-D-447), and ASARCO
 actions to comply with  the final arsenic  NESHAP  standard.

      In light of ASARCO 's recent closure  of  its  copper smelting opera-
 tions at Tacoma, and  its  continuation  of  the  operation of  the  arsenic
 plant (arsenic  trioxide and metallic arsenic  production facilities) on
 the  same site,  EPA  is presenting only  its estimates for arsenic emissions
 from  the arsenic plant.  Therefore, the following  sections discuss main
 stack and  low-level arsenic emissions  only from the arsenic plant.

 G.2  ARSENIC  PLANT EMISSION RATES

 G.2.1  Main Stack Emissions
n^H.     process abases from the arsenic trioxide and metallic arsenic
production operations are vented to a baghouse before being ducted to
tne main stack.  It is not known presently whether the main stack at
the Tacoma smelter will be retained, but the contribution of arsenic

!;ilsl!n!h    -tte*aT"1c Plant Wl11 st111 be vented from this baghouse,
even if the main stack is removed from the site
                                  G-2

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      In September 1983, EPA conducted source tests to determine arsenic
 emissions at the inlet and outlet of the baghouse controlling emissions
 from the arsenic plant.  Test results are summarized in Appendix H
 The results for Run Nos. 1 through 4 show that the average arsenic
 emission level from this baghouse was 0.33 pound per hour (0.15 kg/h).
 Test results for Run Nos. 5 through 7 were not utilized in establishing
 average emissions because of uncertainties about the flow conditions
 during these test runs.  After the copper smelting operation has been
 shut down, emissions from the arsenic plant baghouse are likely to
 change, but neither the magnitude nor direction of any future change
 can be predicted at the present time.

 G.2.2  Low-Level Emissions

      The low-level  emission factors for the arsenic plant are based on
 a detailed arsenic material balance that ASARCO prepared specifically
 for the arsenic trioxide and metallic arsenic production facilities at
 ASARCO-Tacoma (II-D-42).   These low-level  arsenic emissions  are considered
 to consist of contributions from seven separate operations performed in
 connection with running the arsenic plant.   Low-level  emission  rates
 based on controls in place on  December 31,  1982,  and  on  additional
 controls since that date,  are  presented in  Table  G-l.  The methodology
 used to derive these emission  estimates is  described  in  the  paragraphs
 below.   It should be recognized that these  estimates  reflect the present
 configuration at the Tacoma smelter (both  copper  smelter and arsenic
 plant in operation), and  might be  changed after the copper smeltinq
 operation is shut down.                                «-r         3

      G.2.2.1  Raw Material  Handling.   The arsenic plant  material
 balance shows that  a total  of  2,682 Ib/h of  arsenic is handled  during
 the various  flue  dust,  white dust,  Cottrell  dust, and roaster baghouse
 dust transfer operations  performed  in  the arsenic plant.   The assumption
 is that uncontrolled arsenic emissions  from  the handling of  these
 materials  are 0.1 percent  of the arsenic contained in the  materials.
 The transfer operations are performed  inside  the  arsenic plant  building
 using a combination  of  covered  belt  conveyors,  pneumatic conveyor
 systems, and enclosed chutes.  An overall control efficiency of  90
 percent is assumed  for  these controls.  Multiplying 2,682  Ib/h  by
 0.1 percent,  an uncontrolled emission rate of 2.68 Ib/h  was calculated
 Applying  the control efficiency value of 90 percent, a low-level arsenic
 emission rate of 0.27 Ib/h was  calculated for arsenic plant raw material
 handling.

     G.2.2.2  Godfrey Roasters.  In 1983, a construction program was
 completed at the ASARCO-Tacoma smelter to replace the arch on the Mo  5
 Godfrey roaster with a poured solid-refractory arch.  Solid-refractory
 arches  previously had been installed on the No. 4 and No. 6 Godfrey
 roasters.  (The No.  1, No. 2, and No. 3 Godfrey roasters have been
 removed from the arsenic plant.)  Also included in the ASARCO construc-
 tion program was the installation of a water-cooled screw conveyor on
each Godfrey roaster for transfer of the hot calcines from the roaster
TO  represent baseline Godfrey roaster operations for the  estimation  of
arsenic emissions, it is assumed that the solid-refractory arch  was  not
 in place on the No.  5 Godfrey roaster.

                                  G-3

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        .Table  6-1.   LOW-LEVEL ARSENIC  EMISSION RATES FOR
               THE ARSENIC PLANT AT ASARCO-TACOMA
       Low-Level Emission Source
                                      Average  Arsenic
                                   Emission  Rate  (Ib/h)
Controls as of December 31, 1982

  1.  Raw material handling
  2.  Godfrey roasters
  3.  Calcine handling
  4.  Kitchen pulling
  5.  Arsenic trioxide handling
  6.  Metallic arsenic production
  7.  Baghouse dust transfer
Hith Additional Controls
                                      Total
  1,
  2,
  3,
  4.
  5.
  6.
Raw material handling
Godfrey roasters
Calcine handling
Kitchen pulling
Arsenic trioxide handling
Metallic arsenic production
  7.  Baghouse dust transfer
                                           0.27
                                          4.04
                                      Total
                                          1.63
                             6-4

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      To estimate baseline Godfrey roaster emissions, it is assumed that
 0.1 percent of the arsenic vaporized during the roasting process is
 discharged into the arsenic plant building as a result of the transfer
 of hot calcines from the roaster hearth and the leakage of process
 offgases from openings in the roaster roof.  The arsenic plant material
 balance shows that a total of 2,178 Ib/h of arsenic is vaporized in
 the Godfrey roasters.  Multiplying 2,178 Ib/h .by 0.1 percent, the low-
 level arsenic emission rate calculated for the Godfrey roasters is
 2.18 Ib/h.

      G-2-2-3  Calcine Handling.   In late 1983, ASARCO began start-up
 of a pneumatic conveyor system to transfer the Godfrey roaster calcines
 directly to the Herreshoff roasters.   This system replaced the belt
 conveyor system previously used  to handle the calcines.   To represent
 baseline calcine handling operations  for the estimation  of arsenic
 emissions, it is assumed that the belt conveyor system is used for all
 calcine handling.   The belt conveyor  system consists of  a covered belt
 conveyor to an open,  inclined belt conveyor that discharges the calcines
 into a railcar.   No ventilation  is applied along the belt conveyor
 system.   Therefore,  it is assumed that arsenic emissions from the belt
 conveyor system are uncontrolled.

      The arsenic plant material  balance shows that a total  of 504 Ib/h
 of arsenic is  handled  inside  the arsenic plant during the  transfer of
 the Godfrey roaster calcine to the railcar loading station  at the south
 end of the building.   The assumption  is that uncontrolled arsenic
 emissions  from calcine  handling  are 0.1 percent of the arsenic contained
 in the  calcines  loaded  into the  rail cars.  Multiplying 504  Ib/h  by
 0,1 percent, an  uncontrolled  emission  rate of  0.50 Ib/h  was calculated.

      G-2-2'4   Kitchen  Pulling.   Arsenic emissions  from kitchen pulling
 were  calculated using an  emission factor developed  by PSAPCA  (pages 2-40
 and 2-41 of the high-arsenic proposal  BID), which  is  based on  the
 estimate that  0.5 percent of  the arsenic processed  through  the arsenic
 plant is potentially lost during the kitchen pulling operations, and  on
 an  estimate of the capture efficiency achieved by  the local ventilation
 system currently applied.  The kitchen  pulling operation is ventilated
 by  movable  hoods that vent to a  baghouse.  Based on observations of
 kitchen pulling operations during the EPA June 1983, smelter inspection,
 1*.!s.  A  s Jud9me|it: that  the hoods are approximately 90 to 95 percent
 efficient in capturing dust emissions generated during kitchen pulling
 Applying the 0.5 percent emission factor for potential emissions to the
 arsenic rate of 1,523 Ib/h reported in the material balance, and
 assuming that 10 percent of the potential emissions escape capture, the
 low-level arsenic emission rate due to kitchen pulling is calculated
 to be 0.76 Ib/h.

     G.2.2.5  Arsenic Tripxide Handling.  The arsenic plant material
 balance shows that a total of  1,523 Ib/h of arsenic is handled during
 the transfer,  barreling, and railcar loading of arsenic trioxide.  It
 is assumed that uncontrolled arsenic emissions from arsenic trioxide
 handling are 0.1 percent of the total  arsenic trioxide shipped from the
plant.  The arsenic trioxide is transferred inside the arsenic plant
building using a combination of enclosed belt and screw conveyors and

                                  6-5

-------
 pneumatic conveying systems.   An overall  control  efficiency  of  90  percent
 is assumed for these controls.   Multiplying  1,523 Ib/h by  0.1 percent
 an uncontrolled emission rate of 1.52 Ib/h was  calculated.   Applying
 the control  efficiency value  of 90 percent,  a low-level  arsenic emis-
 sion rate of 0.15 Ib/h was  calculated for arsenic trioxide handling.

 .  .   G-2-2.6  Metallic Arsenic  Production.   The arsenic  plant material
 balance shows tnat the average  nourly arsenic input  to the metallic
 arsenic plant is 111 Ib/h.  Input arsenic is in the  form of  purchased
 refined arsenic trioxide that is manually loaded  from  barrels into the
 hoppers of the two metallic arsenic furnaces.  The final product is
 manually removed from the condensers  downstream of the furnaces and
 loaded  into  barrels for shipment.   The material balance  shows that the
 n«n?u/uave!ra9e hourly arsentc output  of the  metallic arsenic plant is
 99 Ib/h.   The EPA based its estimate  of low-level arsenic emissions
 from the  metallic arsenic plant  on  an approximate annual average hourly
 arsenic throughput of 100 Ib/h.   Using the same material handling
 emission  and  control  factors  used for other  sources in the arsenic

                            '        from the metaiiic arsenic piant
h*i;,n          k       °USt Transfer-  ™e arsenic plant material
balance shows that the annual average arsenic content of the off gases
^IK/! ar!enic,k\tcfiens and metallic arsenic production facilities is
Si,,!  ?; J°aCa   !a!u !h! ar\senic Plant baghouse dust transfer emission
value, it is assumed that total uncontrolled arsenic emissions are
O.l percent of the arsenic contained in the collected dust.   An overall
control efficiency of 90 percent is assumed for the baghouse airslide.
Based on source test data, an average of 0.33 Ib/h is vented from the
baghouse.   Therefore, a value of 831.7 Ib/h was calculated for the
HnrnnL0!!^116?*6? ^^   Mult1PW"9 83L7 Ib/h by 0.1 percent,  an
uncontrolled emission rate of 0.83 Ib/h was calculated.   Applying the
£!   I n  ni°!K/uy value°f 90 Percent, a low-level  arsenic  emission
rate of 0.08 Ib/h was calculated for arsenic plant baghouse  dust transfer
                                 6-6

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                 APPENDIX H

SUMMARY OF TEST RESULTS FOR THE ARSENIC PLANT
            BAGHOUSE AT ASARCO-TACOMA
                       H-l

-------
             SUMMARY OF TEST RESULTS FOR THE ARSENIC PLANT
                       BAGHOUSE AT ASARCO-TACOMA

H.I  INTRODUCTION

     From September 12 to 29, 1983, EPA performed a series of emission
tests at the ASARCO-Tacoma smelter (IV-A-6).  The primary objectives of
the test program were:

     1.  To obtain representative arsenic and participate emission
         data at the outlet of the No. 1 Cottrell controlling emissions
         from the No. 2 reverberatory smelting furnace.

     2.  To obtain representative arsenic emission data at the inlet and
         outlet of the fabric filter controlling emissions from the
         arsenic plant.  Testing was to be conducted so as to provide
         arsenic removal efficiency data for this source.

     3.  To obtain data for evaluation of the accuracy of arsenic
         results obtained with the ASARCO continuous sampler compared
         with those obtained with the EPA testing and analytical
         procedures for inorganic arsenic.

     4.  To approximate the arsenic removal efficiency of the No. 1
         Cottrel1.

Sample and analytical procedures.were performed by personnel from an
EPA contractor (PEDCo Environmental, Inc.), under the supervision of
personnel from the EPA Emissions Measurement Branch.  Personnel from
another EPA Contractor (Pacific Environmental Services, Inc.), under
the supervision of personnel from the EPA Industrial Studies Branch,
monitored operating conditions of the processes and control devices
during the testing.

     Due to ASARCO's decision to close the Tacoma copper smelting
facilities and continue to operate only the arsenic plant at Tacoma
(IY-D-802), only the test results for the arsenic plant baghouse  are
presented and discussed in this appendix.

H.2  TEST PROTOCOL

        Table H-l presents a summary of the number and type of tests
performed in the test program.  The actual sequence of test events was
different from the sequence shown because of the arsenic plant production
schedule during the test period.

     Arsenic concentrations and mass emission rates were determined at
the inlet and outlet of a fabric filter (baghouse) controlling emissions
from the arsenic trioxide (AsgOs) and metallic arsenic processes.  All
                                  H-2

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Table H-l.  SUMMARY OF ARSENIC PLANT BAGHOUSE TEST ACTIVITY
Date (1983)
9-14
9-15
9-16
9-17
9-23
9-24
Test (Sample) ID
ABKI-1
AABO-1
ABKI-2
AABO-2
ABKI-3
AABO-3
ABKI-4
AABO-4
ABKI-5
ABMI-1
AABO-5
ABKI-6
ABM I -2
AABO-6
ABKI-7
ABM I -3
Test Location
AsgOs baghouse Inlet
Baghouse outlet
AS203 baghouse inlet
Baghouse outlet
AseOs baghouse inlet
Baghouse outlet
As£03 baghouse inlet
Baghouse outlet
AS2<33 baghouse inlet
Metallic plant baghouse
inlet
Baghouse outlet
As£03 baghouse inlet
Metallic plant baghouse
inlet
Baghouse outlet
AS203 baghouse inlet
Metallic plant baghouse
                       AABO-7
  inlet
Baghouse outlet
                             H-3

-------
tests were made by the sampling and analytical procedures outlined in
Reference Methods 1 through 5va) and proposed Reference Method 108(b).

     The baghouse controls emissions from two process gas streams; one
transports off gases from the AS203 plant and metallic arsenic condensers,
and the other transports off gases from the metallic arsenic process.
The gases exiting the baghouse are conveyed to the main stack.

     Initially, four Method 108 tests were conducted simultaneously at
the AsgOs plant inlet and the baghouse outlet while the metallic plant
was not operating.  Once the metallic plant came back on line, Method
108 tests were performed at the AsgOs and metallic plant inlets and the
baghouse outlet.  A total of three Method 108 tests were conducted
simultaneously at the three test locations (two inlet and one outlet).

     These data were used to characterize arsenic emissions to the main
stack and to estimate the arsenic collection efficiency of the baghouse.
Process operations were closely monitored during each emission test
period, and samples of Godfrey roaster charge material and baghouse
hopper catch were collected and analyzed for arsenic content.

     Section H.3 presents the results of the test program on the
arsenic plant.

H.3  ARSENIC PLANT TEST RESULTS

     Tables H-2 and H-3 summarize pertinent sample, flue gas, and
analytical data for tests performed at the arsenic plant baghouse.
     Initially, four simultaneous tests were conducted at the
(kitchen) inlet and baghouse outlet test locations.  During these tests,
the metallic arsenic plant was not in operation.  For the inlet tests,
designated ABKI (ASARCO Baghouse Kitchen Inlet), the volumetric gas
flow rate averaged 731 dscm/min (26,000 dscfm) with an average gas
temperature of 74°C (165°F) and moisture content of 5.8 percent.  The
flue gas composition was consistent for each test and showed oxygen,
carbon dioxide, arid carbon monoxide results of 19.2, 0.45, and 0.0
percent, respectively.  Concentrations of SOg typically averaged less
than 3,000 ppm or less than 0.3 percent of the total sample volume.
     The uncontrolled arsenic concentration from the As20a plant averaged
7,892 mg/dscm "(3.44 gr/dscf), and the corresponding mass emission rate
was 343 kg/h (757 Ib/h).  Results from Test ABKI-1 are not included
in the group average; results of this test are biased low because of a
loss of sample during analysis.  For the baghouse outlet tests, designated
AABO (ASARCO Arsenic Baghouse Outlet), flow rates averaged 783 dscm/min
(27,700 dscfm) with an average gas temperature of 74°C (165°F) and
moisture content of 5.3 percent.  Average flue gas composition results
were identical to those reported for the kitchen inlet tests.  Outlet
(a)40 CFR 60, Appendix A, Reference Methods 1 through 5, July 1982.

(^Federal Register, Vol. 48, No.  140, July 20, 1983, p. 33166-33177.

                                  H-4

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                                  H-7

-------
 arsenic concentrations  and mass emission rates averaged 3.15 mg/dscm
 (0.0014 gr/dscf)  and  0.15 kg/h  (0.33  Ib/h), respectively.

      Based  on  mass  emission  rate results from this group of tests, the
 arsenic collection  efficiency of the  baghouse was greater  than 99.9
 percent.  Volumetric  flows,  temperatures, moisture contents, and S02
 concentrations measured at each location were comparable.

      When the  metallic  arsenic plant  began operation, the  same test
 sequence was repeated and simultaneous  tests were conducted at three
 test  locations—the kitchen  inlet,  the  metallic plant inlet, and the
 baghouse outlet.  At  the completion of  the first set of simultaneous
 tests (ABKI-5,  ABMI-1,  and AABO-5), preliminary calculations showed a
 flow  imbalance between  the inlet and  outlet test locations.  The
 cumulative  inlet  volumetric  flow was  629 dscm/min (22,200  dscfm) compared
 with  an outlet flow of  841 dscm/min (29,700 dscfm).  The 7,000-dscfm
 flow  imbalance was  attributed to an open flow control damper located in
 a bypass duct,  which  entered the metallic arsenic plant exhaust duct
 downstream  of  both  the  metallic and kitchen inlet test locations (see
 Figure H-l).   This  condition did not  exist during the first series of
 runs  because a  second flow control damper located in the metallic plant
 duct  downstream at  the  bypass duct was  closed.  The flow imbalance
 occurred when  this  second damper was  opened.  The negative pressure
 associated  with the control system served to divert a part of the flow
 from  the kitchen  through the bypass duct and into the baghouse, where
 it was ultimately measured at the outlet test location.

      In addition  to the flow imbalance, the arsenic concentration and
 mass  flow rate  measured at the As£03  inlet test location were signifi-
 cantly less than  that measured during the first set of tests (0.45 gr/
 dscf  and 66 Ib/h  versus 3.44 gr/dscf and 748 Ib/h).   No conclusive
 explanation can be  found to account for the significant difference in
AS203 plant loading.  The arsenic concentration and mass emission rate
 at the baghouse outlet averaged 3.17 mg/dscm (0.0014 gr/dscf) a'nd
 0.15  kg/h (0.35 Ib/h).  These values are essentially identical  to those
measured during the first test series, when only the AS203 plant was
 being operated.

      Since a malfunctioning flow control damper made the inlet mass
emission rate suspect, the arsenic collection efficiency of the baghouse
was recalculated with an adjusted arsenic inlet mass rate for each run.
Results were adjusted by assuming that the  flow imbalance was diverted
 to AsgQs gas.  The  flow difference was assumed to have the same concen-
tration as the kitchen inlet and was added  to the total  inlet mass
rate.   The arsenic  collection efficiency averaged 99.5 percent with
both arsenic processes in operation without a calculation adjustment,
and 99.6 percent with an adjustment.

     Table H-4 summarizes arsenic analytical  results for Godfrey  roaster
charge and baghouse dust samples collected  by ASARCO during each  test.
                                  H-8

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BLOWER ( -
                                     OUTLET
                                 SAMPLE  LOCATION

                                             TO MAIN  STACK
                                                      SLIDE BLIND,OPEN


                                                   WOOD DUCT
                                  P»-2"H20
                               KITCHEN INLET
                              SAMPLE LOCATION
                                            DAMPER
                                          INDICATES
                                            CLOSED
                                                 FLOW DIVERSION
                 METAL  FURNACE  HOODS
       MAIN  FLUE
                                                                      FROM ARSENIC
                                                                        KITCHENS
SLIDE BLIND,CLOSED
                                               - METALLIC       B   n  .„,  „
                                               INLET SAMPLE     P=-0.4"H20
                                                 LOCATION
            Figure H-l   Arsenic Plant Gas Flow Schematic  — ASARCO-TACOMA
                                       H-9

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     Table H-4.  ANALYTICAL RESULTS FOR ARSENIC PLANT TEST SAMPLES
Date
(1983)
9/14

9/15

9/16

9/17

9/23

9/23

9/24

Sample description
Roaster charge
Baghouse dust
Roaster charge
Baghouse dust
Roaster charge
Baghouse dust
Roaster charge
Baghouse dust
Roaster charge 7:00 a.m. - 3:00 p.m.
Baghouse dust 7:00 a.m. - 3:00 p.m.
Roaster charge 3:00 p.m. - 11:00 p.m.
Baghouse dust 3:00 p.m. - 11:00 p.m.
Roaster charge 7:00 a.m. - 3:00 p.m.
Baghouse dust 7:00 a.m. - 3:00 p.m.
Percent
Arsem'ca
37.2
74.5
27.8
73.5
25.3
75.2
32.2
67.7
33.2
75.8
61.6
72.8
47.1
71.8
aPercent arsenic (by weight) determined by the sample preparation and
 analytical techniques described in proposed EPA Method 108.

 Note:  All samples were collected and identified by ASARCO.
                                 H-10

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                                    TECHNICAL REPORT DATA
                             (Please read Instructions on the reverse before completing)
1. REPORT NO.

 EPA/450/3-83-010b
                                                             3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
 Inorganic Arsenic  Emissions from Primary  Copper
 Smelters and Arsenic Plants -
 Background Information for Promulgated  Standards
              5. REPORT DATE

                   May  1986
              6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
                                                             8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
 Office of Air  Quality Planning and Standards
 U.S. Environmental  Protection Agency
 Research Triangle  Park, North Carolina   27711
                                                             10. PROGRAM ELEMENT NO.
              11. CONTRACT/GRANT NO.

                68-02-3060
12. SPONSORING AGENCY NAME AND ADDRESS
 DAA for Air Quality Planning and Standards
 Office of Air  and  Radiation
 U.S. Environmental  Protection Agency
 Research Triangle  Park, North Carolina   27711
              13. TYPE OF REPORT AND PERIOD COVERED

                Final	
              14. SPONSORING AGENCY CODE
                EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
 National emission standards to control  air emissions of inorganic arsenic from new
 and existing  primary copper smelters  and from arsenic trioxide  and metallic arsenic
 production  facilities are being promulgated under Section  112 of the Clean Air Act.
 Part I of this  document contains a  detailed summary of the public comments on the
 proposed standard for primary copper  smelters (48 FR 33112), and Part II on the
 proposed standard for arsenic production facilities (48 FR 55880).  The document also
 contains Agency responses to these  comments and a summary of the changes made to the
 standards between proposal and promulgation.
17.
                                 KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
                                               b.lDENTIFIERS/OPEN ENDED TERMS
                            c. COSATI Field/Group
 Air Pollution
 Hazardous  air  pollutant
 Pollutant  control
 Standards  of performance
 Inorganic  arsenic
 Primary  copper smelters
 Air Pollution
 Stationary sources
 13 B
18. DISTRIBUTION STATEMENT


  Unlimited
19. SECURITY CLASS (This Report)
  Unclassified
21. NO. OF PAGES
  322
20. SECURITY CLASS (Thispage)
  Unclassified
                                                                           22. PRICE
EPA Form 2220-1 (Rev. 4-77)
                       PREVIOUS  EDI TION IS OBSOLETE

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