United States
Environmental Protection
Agency
Office of Air Quality :
Planning and Standards
Research Triangle Park NC 27711
EPA-45O/3-84-009
May 1984
Air
Review of New
Source Performance
Standards for
Secondary Brass
And  Bronze Plants

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                               EPA-450/3-84-009
Review of New Source  Performance
   Standards for Secondary Brass
           And Bronze Plants
           Emission Standards and Engineering Division
           U.S. ENVIRONMENTAL PROTECTION AGENCY
                Office of Air and Radiation
           Office of Air Quality Planning and Standards
           Research Triangle Park, North Carolina 27711

                    May 1984

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This report has been reviewed by the Emission Standards and Engineering Division of the Office of Air
Quality Planning and Standards, EPA, and approved for publication. Mention of trade names or commercial
products is not intended to constitute endorsement or* recommendation for use. Copies of this report are
available through the Library Services Office (MD-35), U.S. Environmental Protection Agency, Research
Triangle Park, North Carolina 27711; or, for a fee, from the National Technical Information Services, 5285
Port Royal Road, Springfield, Virginia 22161.

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                            TABLE OF CONTENTS
Section   Title                                                      Page
1         EXECUTIVE SUMMARY 	 	   1-1
1.1         Regulatory History of Current Standard  	   1-1
1.2         Industry Outlook  	   1-1
1.3         Control Technology	1-2
1.4         Compliance Test Data	1-2
1.5         Economic Considerations Affecting the NSPS  	   1-3

2         INDUSTRY DESCRIPTION	   2-1
2.1         Introduction	2-1
2.2         Background Information  	   2-2
2.3         Brass and Bronze Production	   2-2
2.4         References for Chapter 2	   2-16

3         SUMMARY OF CURRENT STANDARDS  .	3-1
3.1         New Source Performance Standards  	   3-1
3.2         State Regulations 	   3-2
3.3         References for Chapter 3	3-4

4         STATUS OF CONTROL TECHNOLOGY  .  .  .	4-1
4.1         Emissions Potential	"	4-1
4.2         Control Technology  	   4-4
4.3         References for Chapter 4	4-5

5         EMISSION TEST RESULTS  	   5-1
5.1         Analysis of Emission Tests  	   5-1
5.2         Other Atmospheric Emissions 	  	   5-3
5.3         Water Discharges and Solid Waste Generation 	   5-3
5.4         References for Chapter 5	5-3

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                            TABLE OF CONTENTS
Section   Title
6
6.1
6.2
6.3

6.4
COST ANALYSIS	6-1
  Reverberatory Furnaces  	   6-2
  Electric Furnaces	,.   6-2
  Retrospective Analysis of Original Economic Impact
  Projections	6-4
  References for Chapter 6	6-7
7
7.1
ENFORCEMENT ASPECTS 	   7-1
  References for Chapter 7	7-2

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                             LIST OF TABLES
Table 2-1   Brass and Bronze Alloys, Chemical Specifications, and
              Product Characteristics  	  2-3

Table 2-2   End Uses of Brass and Bronze	 .  2-4

Table 2-3   Producers of Brass and Bronze, February 1983 .....  2-5

Table 2-4   Secondary Brass and Bronze Facilities Subject to the
              New Source Performance Standards	  2-7

Table 3-1   Summary of State Regulations for Secondary Brass and
              Bronze Production Processes  	 ...  3-3

Table 5-1   Emission Test Results of Secondary Brass and Bronze
              Facilities	5-2

Table 6-1   Model  Plants	6-3

Table 6-2   Prices for Brass and Bronze Ingots .  .  .  .... .  . .   6-6


                                                                     x


                             LIST OF FIGURES

                                                                    Page

Figure 2-1  Brass  and Bronze Annual  Ingot Shipments,  1971-1982  . .   2-9

Figure 2-2  Schematic of a Typical  Secondary Metal  Blast Furnace
              or Cupola	2-12

Figure 2-3  Schematic of a Stationary Reverberatory Furnace  .  . .   2-13

Figure 2-4  Electric Furnace Types  	   2-15

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                           1.  EXECUTIVE SUMMARY

1.1  REGULATORY HISTORY OF CURRENT STANDARD
     The new source performance standards (NSPS) for secondary brass and
bronze ingot production plants were proposed on June 11, 1973, and
promulgated by the Environmental Protection Agency (EPA) on March 8,
1974 (40 CFR 60, Chapter 1, Subpart M).  The secondary brass and bronze
NSPS applies to reverberatory and electric furnaces of 1,000 kg (2,205 Ib)
or greater production capacity and to blast (cupola) furnaces of 250 kg/h
(550 Ib/h) or greater production capacity that were constructed or
modified on or after June 11, 1973.   The standards state that exhaust
gases discharged to the atmosphere from reverberatory furnaces must not
contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf) and
must not exhibit 20 percent opacity or greater.  The standards also
state that exhaust gases from electric and blast (cupola) furnaces must
not exhibit 10 percent opacity or greater.
     The objective of this report is to review the NSPS for secondary
brass and bronze ingot production plants and to assess the need for
revision on the basis of developments that have occurred since the
original NSPS was promulgated in 1974 and since the last review in 1979.
The following paragraphs summarize the results and conclusions of the
review.
1.2  INDUSTRY OUTLOOK
     In 1973, approximately 258,500 Mg (285,000 tons) of brass and
bronze ingot were produced at 60 plants.  By 1982, production had declined
to 154,200 Mg (170,000 tons), and 37 plants were in operation.   Despite
this decline, five rotary reverberatory furnaces and one electric induction
furnace have been installed since the NSPS was proposed and are therefore
                                  1-1

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 subject to its provisions.   Most of this growth has occurred since the
 NSPS was reviewed in 1979;  only two reverberatory furnaces were reported
 subject to the NSPS in 1979.   No blast (cupola) furnaces have become
 subject to the NSPS.   No furnaces of any type have become subject to the
 NSPS through  modification or reconstruction.
      Growth in the number of affected reverberatory and electric furnaces
 is  expected to continue.   These new furnaces  will  absorb capacity lost
 when plants close;  provide  production flexibility to make plants more
 competitive;  replace outdated,  inefficient  equipment;  and provide production
 facilities near market areas.   No new blast (cupola) furnaces are expected.
 The  notably high  growth projections in the  number of electric induction
 furnaces  reflects  the development of a new  process in  which  brass is
 continuously  cast  from an electric furnace  in the  form of a  strip.
 1.3   BEST DEMONSTRATED CONTROL  TECHNOLOGY (BDT)
      The  original  standard  was  based on  the use  of fabric filter control
 technology to  control  emissions  from reverberatory furnaces  captured
 during  charging and  melting.  No  significant  changes have occurred  in
 control technology  for the  affected sources.   Wet  scrubbers  typically
 are  unable to  provide  the level of control  required  under the  NSPS  and
 have  problems  with water  pollution and solid  waste  generation.   Electro-
 static precipitators  (ESP's) have  difficulty  in  collecting metal  oxides
 because of the  relatively high  resistivity  of such particles.  Therefore,
 fabric filters  continue to  be considered BDT.
      Some  emissions generated during charging and  tapping of  reverberatory
 furnaces  escape capture and control.  No mass  emission data  are  available
 for these  emissions.   However, visible emissions observations made
 during this review indicate that these emissions are not  significant.
Therefore,  no BDT has  been  identified for control of these emissions.
     Compliance test results, State and local  control agency inspection
reports, and unofficial observations made during plant visits in this
review show all operating NSPS facilities are in compliance with the
NSPS.
                                  1-2

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1.4  COMPLIANCE TEST DATA
     The furnaces subject to the NSPS at four of the five plants are the
rotary reverberatory type; the fifth plant has an electric induction
furnace.  One of the rotary furnaces subject to the NSPS has not been
placed in operation and has not been tested for compliance.  The other
four rotary furnaces have been tested and are currently in compliance
with the 50 mg/dscm (0.022 gr/dscf) particulate emission standard and
the 20 percent opacity limit set in the NSPS.  The electric furnace has
been tested and is currently in compliance with the 10 percent opacity
limit set for electric furnaces and the particulate emission rate set
for reverberatory furnaces in the NSPS.
     One electric furnace not currently subject to the NSPS was tested
and found to have a particulate emission rate below the standard set for
reverberatory furnaces.
1.5  ECONOMIC CONSIDERATIONS AFFECTING THE NSPS
     To estimate the economic consequences of the NSPS, model plant
descriptions were developed based on representative NSPS plants to serve
as a basis for estimating costs.   The capital and annualized costs for
the control system for each model plant were estimated using guidelines
in the GARD Manual and information supplied by industry.  Costs were
updated to December 1982 dollars using the Chemical Engineering plant
cost index.
     The average cost effectiveness of particulate matter control  for
reverberatory furnaces is $135 per ton over uncontrolled emission levels,
and the average cost effectiveness of particulate matter control  for
electric furnaces is $1,500 per ton over uncontrolled emission levels.
An analysis of the economic impact of the NSPS on the brass and bronze
industry indicates that the rate of decline in the total industry had
not been accelerated by the NSPS and that the control  cost associated
with the NSPS has resulted in a maximum product price increase of only
0.4 percent.
                                  1-3

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                         2.  INDUSTRY DESCRIPTION

2.1  INTRODUCTION
     On June 11, 1973, the EPA proposed new source performance standards
for the secondary brass and bronze industry.  These standards established
particulate matter emission limits and required testing and reporting of
particulate matter and visible emissions for affected facilities that
were built, reconstructed, or modified on or after June 11, 1973.  The
facilities affected by these regulations are reverberatory, electric,
and blast (cupola) furnaces.
     At the time of NSPS development, there were approximately 60 secondary
brass and bronze ingot production plants operating throughout the United
States with the majority located in the northeast and north central
industrial belts.1  The yearly production of ingot from these plants was
approximately 272,000 Mg (300,000 tons).1  The secondary brass and
bronze industry was selected for NSPS development because individual
facilities can be significant sources of particulate matter emissions.
Uncontrolled reverberatory furnaces can emit as much as 32 kg of particulate
matter per Mg (70 Ib/ton) of metal produced.2  The mass rate of particulate
matter emissions from blast (cupola) furnaces is approximately equal to
that from reverberatory furnaces; the mass rate of particulate matter
from electric furnaces is typically far lower than that from reverberatory
or blast.2  An uncontrolled 45-Mg (50-ton) capacity, rotary reverberatory
furnace is capable of emitting 1,300 Mg/yr (1,440 tons/yr) of particulate
matter.3  The NSPS limits these emissions to approximately 11 Mg/yr
(12 tons/yr).3
     The Clean Air Act Amendments of 1977 require that the EPA Administrator
review NSPS at least every 4 years to assess the need for possible
revision of standards [Section lll(b)(l)(B)].4  This report presents the
                                  2-1

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 findings  of  the  second  review of  the  NSPS  for  the  secondary  brass  arief
 bronze  industry.   The review was  conducted by  examination  of current
 secondary brass  and  bronze  literature,  discussions with  regional EPA
 offices and  State  and local  air pollution  control  agencies,  discussions
 with  emission  control equipment vendors, visits  to new and modified
 secondary brass  and  bronze  facilities,  and discussions with  brass  and
 bronze  ingot trade associations.
 2.2   BACKGROUND  INFORMATION
      Secondary brass and bronze plants  generally produce brass and
 bronze  ingots  weighing  13.6  kg (30  lb).5-9  However, there is a new
 process,  associated with electric induction furnaces, for  continuously
 casting the  product  in  the  form of  rod  rather  than ingot.  This technology
 makes possible the continuous rolling of strip significantly faster than
 by other  processes.  Classically, when  copper  is alloyed with zinc, the
 product is termed  brass, and when copper is alloyed with tin, the  product
 is termed bronze.  Other copper alloys  are  identified by the alloying
 metals such  as aluminum bronze and  silicon bronze.  Table  2-1 lists the
 12 categories  of brass  and bronze that  have been designated by the Brass
 and Bronze Ingot Institute.  The table  also shows subcategories of the
 alloys along with  the chemical specifications and characteristics  of
 each.
     Because of their high strength, workability, corrosion resistence,
 and other desirable physical characteristics, the copper-base alloys are
 used in a wide variety of products  found in the marketplace.   Table 2-2
 lists the principal categories of end uses for brass and bronze.
 2.3  BRASS AND BRONZE PRODUCTION
 2.3.1  Industry Characterization
     Secondary brass and bronze companies are usually small,  individually
 owned firms consisting of one plant.  A few are subsidiary operations  of
 large mining companies or of conglomerates.10
     Currently, 37 secondary brass and bronze plants  are  in operation;
these plants are listed  in Table 2-3.   Of these plants,  five  have  facilities
that are subject to the  NSPS.  Table 2-4 lists  these  five plants  and
gives  a brief description of the affected facilities.   Two of the  five
                                  2-2

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 TABLE 2-2.  END USES OF BRASS AND BRONZE5-10,13
Housing industry

Plumbing and heating equipment
Valves and pipe fittings
Electrical housewares
Lighting and wiring equipment
Ornamentation
Refrigeration machinery
Transportation industry

Engines and turbines
Ai rcraft
Ships and boats
Consumer goods

Electric motors and generators
Musical instruments
Photographic equipment
Office and computing equipment
Military

Ordnance
Signal equipment
Other

Construction and mining equipment
Industrial machinery
Medical equipment
Grave markers
                       2-4

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     TABLE 2-3.  PRODUCERS OF BRASS AND BRONZE,  FEBRUARY  198310,14,15


 1.  American Brass  Incorporated, P.O. Box 185,  Headland, Alabama   36345

 2.  ASARCO Incorporated, San Francisco, California

 3.  The G.A. Avril  Company, Brass & Bronze  Ingot Division, Box 66
     Winton Place Station, 4445 Kings Run Drive, Cincinnati, Ohio   45232

 4.  Bay State Refining Company, Incorporated, P.O. Box 269, Chicopee,
     Massachusetts   01021

 5.  Belmont Smelting & Refining Works, Incorporated, 330 Belmont Avenue,
     Brooklyn, New York  11207

 6.  Bohn Aluminum and Brass, Adrian, Michigan

 7.  Bridgeport Brass, Indianapolis, Indiana

 8.  Brush Wellman Incorporated, 17876 St.  Clair Avenue, Cleveland, Ohio
     44110—El more, Ohio Plant

 9.  W.J. Bullock, Incorporated, Box 539, Fairfield, Alabama  35064

10.  Harry Butter & Company, Incorporated,  151 Mt.  Vernon Street, Dorchester,
     Massachusetts  02125

11.  Cabot Berylco Industries, Incorporated, Alloy Division, P.O.  Box 1462,
     Reading, Pennsylvania  19603

12.  Cerro Metals, Newark, California

13.  Cerro Metals, Bellefonte, Pennsylvania  16823

14.  Chase Brass and Copper, Montpelier,  Ohio

15.  Chase Brass and Copper, Solon,  Ohio

16.  Chicago Extruding Metals, Chicago,  Illinois

17.  Colonial  Metals Company, P.O.  Box 311,  Second & Linden Streets,
     Columbia, Pennslyvania  17512

18.  Federal  Metal  Company,  7250 Division Street, Bedford, Ohio  44146

19.  N.  Kamenske & Company,  Incorporated,  Box 724,  5 Otterson  Court, Nashua,
     New Hampshire  03061

                                                               (continued)
                                    2-5

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                            TABLE 2-3.   (continued")
 20.



 21.



 22.



 23.



 24.

 25.

 26.



 27.

 28.



 29.



 30.



 31.



 32.



 33.

 34.



35.

36.

37.
 Kearny Smelting & Refining Corporation,  936 Harrison Ave.,  Kearny,
 New Jersey  07029

 H.  Kramer & Company,  P.O.  Box 7,  No.  1 Chapman Way,  El  Segundo,
 California  90246

 H.  Kramer &.Company,  1339-1345 W.  21st Street, Chicago,  Illinois
 60608

 R.  Lavin  & Sons,  Incorporated,  3426  S.  Kedzie  Avenue,  Chicago,
 Illinois   60623

 Li barman  S.  Gittlen Metal  Company, Grand Rapids,  Michigan

 Milward Alloy  Incorporated,  Lockport,  New York

 Mishawaka Brass Manufacturing Incorporated,  1928  Mick  Court, Mishawaka,
 Indiana   46544

 National  Metals,  Incorporated,  Box 102,  Leeds,  Alabama   35094

 New  England Smelting Works,  Incorporated,  502  Union  Street, West
 Springfield, Massachusetts   01089

 North American  Smelting Company, Marine  Terminal, Wilmington, Delaware
 19899

 North Chicago  Refining & Smelting Incorporated, 2028 S.  Sheridan Road,
 North Chicago,  Illinois  60064

 Phelps Dodge Industries, Incorporated, Lee Bros., P.O. Box 1229,
 Anniston, Alabama  36201

 River Smelting & Refining Company, P.O.  Box 5755, Cleveland, Ohio
44101

 Roessing Bronze Company, P.O. Box 60, Mars, Pennslyvania  16046

S-G Metals Industries, Incorporated, 2nd & Riverview, Kansas City,
 Kansas  66110

 I. Schumann & Company, 22500 Alexander Road, Bedford, Ohio"  44146

Sipi Metals Corp., 1720 N.  Elston Avenue, Chicago, Illinois  60622

Specialloy Incorporated, 4025 S. Keeler Avenue, Chicago, Illinois
60632
                                    2-6

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         TABLE 2-4.  SECONDARY BRASS AND BRONZE  FACILITIES SUBJECT
                  TO THE NEW SOURCE PERFORMANCE  STANDARD5-9
Plant/location
Furnace type/size
Compliance
  status
Comments
American Brass, Inc.
  Headland, Alabama
2 rotary reverberatory/  In cpmplv
40,000 kg (88,000 Ib)    anceD
               Plant con-
               structed in
               1978
National Metals, Inc.
  Leeds, Alabama'
1 rotary reverberatory/  In complr
1,800 kg (4,000 Ib)      ance
               Furnace
               installed
               in 1977
Federal Metals, Inc.
  Bedford, Ohio
1 rotary reverberatory/  Not in
18,000 kg (40,000 Ib)    operation
               Furnace
               installed
               in 1981
I. Schumann and Co.
  Bedford, Ohio
1 rotary reverberatory/  In compli-
45,400 kg (100,000 Ib)   ance
               Furnace
               installed
               in  1982
Chase Brass and
  Copper
  Solon, Ohio
1 electric induction/    In compli-
10,000 kg (22,000 Ib)    ance
               Plant  con-
               structed  in
               1980
 Compliance with particulate matter and visible emission standards are
 determined by EPA Reference Methods 5 and 9, respectively (40 CFR 60,
.Appendix A).
 Visible emissions not determined during compliance testing.
                                    2-7

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 plants  are new plants (built since the NSPS was  proposed),  and three are
 existing plants that have installed new furnaces.   Four of  the plants
 have reverberatory (rotary)  furnaces,  and the fifth uses an electric
 induction furnace.   All  of the facilities are equipped with baghouses
 for emission  control, and all  operational  facilities are currently
 considered to be complying with the NSPS.5-9
      Even though there has been an increase in the  past 4 years in  the
 number  of affected facilities  subject  to the NSPS,  the industrywide
 production of ingot is declining.16 Figure 2-1  shows  the downward  trend
 in  the  production of brass and bronze  ingot as recorded by  the Bureau of
 Mines in 1983.16  Contacts with regional  EPA offices and State and  local
 air pollution control  agencies revealed that some plants are  closing and
 most are on reduced schedules.17   The  Brass and  Bronze Ingot  Institute
 attributes this  decline  to product substitutions and recently depressed
 economic conditions and  does not expect growth in the  industry in the
 foreseeable future.18   However, additional  affected facilities  are
 expected to be  installed by  viable firms,  despite this  downtrend, to
 absorb  capacity  lost when  other firms  shut down; to  provide production
 flexibility within  a plant;  to replace  outdated, inefficient  equipment;
 and to  provide production  facilities near  market areas.19,20
 2.3.2   Process Description
     The  brass and  bronze  manufacturing  industry basically consists  of
 three operations:  raw materials collection  and preparation, metal melting
 and ingot production,  and  metal product  fabrication.   The NSPS  for
 secondary brass  and bronze facilities  is specific to furnaces  used  in
 raw material  preparation and ingot  production; therefore, fabrication
will not  be discussed  in this  review.
     The  following  sections will discuss raw materials, material preparation,
and  melting as they  relate to  particulate emissions  in the brass and
bronze  ingot  production process.
     2.3.2.1  Raw Materials.    The  raw materials used in the secondary
brass and bronze ingot industry consist mainly of brass and bronze
scrap.  Both  industrial and domestic scrap are used.  Industrial scrap
includes pieces, chips, and shavings of alloy materials, such as those
which result  from product fabrication.   This scrap is free of impurities
                                  2-8

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and requires  little preparation  before  charging  into melting  furnaces.
Domestic scrap  includes  items that  are  being  recycled,  such as  radiators,
cartridge cases,  and  railroad boxes.  This  scrap  usually contains significant
amounts of undesirable materials, such  as oil, grease,  paint, insulation,
and chemicals.  For these  reasons,  domestic scrap may require cleaning
before charging to furnaces.
     2.3.2.2  Materials  Preparation.  The purpose of material preparation
is to produce a charge for the furnace  that will yield  the desired alloy
in the most effective manner.  These processes may be either mechanical,
hydrometallurgical, or pyrometallurgical.  The first two processes are
not considered in this description  since they are not sources of particulate
emissions.
     Pretreatment by pyrometallurgical  "methods" may include any of the
following methods:  sweating, burning,  drying, blasting furnaces, and
cupola.  Use of any of these methods will produce particulate emissions;
however, only blast furnaces and cupolas are subject to NSPS.   A brief
description of each method is given below.
     Sweating furnaces may be used to remove low-melting point metals,
such as lead, solder, and babitt metal.  This is done by heating the
scrap in a furnace, which causes the low-melting components to be separated
from the desirable metals.  Carefully controlled burning is usually
performed for removal of insulation from wire or cable.   Toxic substances
such as polyvinyl  chloride can be released during this process.   Drying
furnaces are used to vaporize substances such as cutting fluids from
machine shop scrap.  The temperature of this operation is critical  since
excessively high temperatures cause unwanted oxidation on the surface of
the metal  chips.21
     The terms "blast furnace" and "cupola" are often used interchangeably.
However, the cupola is used to melt down metals or reduce metal  oxides,
while the blast furnace is used for reduction of metal  oxides  or smelting
virgin ores.   Both furnaces are also used to recover metal  from skimmings
and slags.   Because of the difference in the composition of the interacting
atmosphere,  these reducing operations cannot be done in reverberatory or
refining furnaces.22
                                  2-10

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     In both blast and cupola furnaces, coke is used as both fuel and
reducing agent.  The resulting product (black copper or cupola melt) is
impure and must be refined to produce brass and bronze ingot.  A schematic
of a blast furnace is shown in Figure 2-2.  The blast furnace and cupola
operate on a continuous feed basis with charge material, coke, and
fluxes introduced at the top.  Finished metal is drawn from the bottom,
generally on an intermittent basis.  Slag is usually tapped on a continous
basis through a separate spout at a level immediately above the metal
pouring height.23
     2.3.2.3  Melting.   Brass and bronze are usually heated in large
natural- gas- or oil-fired reverberatory furnaces or electric arc or
induction furnaces.   Indirect-fired furnaces are sometimes used for
specific foundry applications but are not covered under the NSPS because
of their small size and emission potential.
     Any furnace in which the burne'r flames and/or hot gases come in
direct contact with the charged material is considered to be a reverberatory
furnace.   Figure 2-3 is a schematic of a typical stationary reverberatory
furnace.   Reverberatory furnaces may also be the rotating, rocking, or
tilting type.  All reverberatory furnaces operate in the batch mode.
The charge material  and fluxes may be introduced before firing or may be
added periodically throughout the heat.   The fuel burned is either oil
or natural gas.23
     Stationary furnaces are usually larger, 100- to 200-Mg (110- to
220-ton) capacity, than the other types of reverberatory furnaces, which
have capacities ranging from 18.9 to 45 Mg (1.0 to 50 tons).5-8
     In all cases, when the charge attains the proper heat and impurities
have been drawn off into the slag, the molten metal is tested for its
alloy composition.  Adjustments are made as needed, and the metal is
brought to the ideal pouring temperature for the specific alloy by
regulation of the fuel  burners.   At this point, metal pouring begins.24
     Electric furnaces  are mainly used for special purpose alloys.
Major advantages of the electric furnace over fuel-fired furnaces are
better furnace atmosphere control and high-temperature operation.
Temperatures as high as 3300°C (6000°F) are possible for special  processes.
Heating may be accomplished by an arc, by induction, or by resistance
                                  2-11

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    CHARGING DOOR
COKE CHARGES
METAL CHARGES


COKE BED

WIND BOX
SLAG
SPOUT
SUPPORTS
     TUYERES
                                                               TO CONTROL DEVICE(S)
                                                               AND STACK(S)
                                                           STACK ZONE
                                                              PREHEAT ZONE
MELTING ZONE
                                                               •TAPPING
                                                                SPOUT
                Figure  2-2.  Schematic of a typical secondary
                       metal blast furnace or cupola.
                                    2-12

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                                         (O
                                         S_
                                         Ol
                                         0)
                                         s_
                                         (0
                                         in

                                         as

                                         M-
                                         O

                                         CJ

                                         4->
                                         (C

                                         
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(see Figure 2-4).  In all cases, charging and pouring are generally done-
through the top of the furnace.25
     Indirectrfired furnaces (crucible or pot furnaces) are usually
significantly smaller than reverberatory furnaces and are similar in
function to electric furnaces.  Crucibles may be the tilting, pit, or
stationary type and include the small, low-temperature pot furnaces.
Charge materials are introduced through the top of the furnace along
with inert fluxes.  Finished alloys are removed from the furnaces through
the top, either by tilting and pouring or by the use of ladles.   Generally,
crucible furnaces are used to heat metals up to 1300°C (2400°F).   Pot
furnaces are used only for temperatures up to about 760°C (1400°F).27
                                 2-14

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 2.4  REFERENCES FOR*CHAPTER 2

  1.   U.S.  Environmental  Protection Agency.   Air Pollution Engineering
      Manual,  2nd Edition.   Office of Air and Water Programs, Research
      Triangle Park,  N.C.   AP-40  1973.   pp.  269-283.

  2.   U.S.  Environmental  Protection Agency.   Compilation of Emission
      Factors,  Part B.   Office of Air and Waste Management, Research
      Triangle Park,  N.C.   AP-42 1977.   p.  7.9-2.

  3.   Memorandum from Keller,  P., and D.  Atkinson,  MRI,  to Iversen, R.,
      EPArlSB.   May 31,  1983.   Tabular cost memo for secondary brass and
      bronze review.

  4.   United States Congress.   Clean Air Act,  as amended August 1977.
      42 U.S.C.  1857  et  seq.   Washington,  D.C.   U.S.  Government Printing
      Office.   November  1977.

  5.   Letter and attachments  from Horton,  T.,  National Metals, Inc., to
      Farmer,  J.  R.,  EPA:ESED.   May 9,  1983.   Response to Section 114
      information request.

  6.   Letter and attachments  from Singh,  A.,  and Sabatka, M.,  Federal
      Metals,  Inc., to Farmer,  J.  R. ,  EPArESED.   May  9,  1983.   Response
      to Section 114  information request.

  7.   Letter and attachments  from Oberlin,  J.  P., I.  Shumann  and Company,
      to Farmer,  J. R., EPA:ESED.   May  5,  1983.   Response to  Section 114
      information request.

  8.   Letter and attachments  from Sherman,  G. ,  American  Brass, Inc., to
      Farmer, J.  R.,  EPA:ESED.   May 5,  1983.   Response to Section 114
      information request.

  9.   Letter and attachments  from Brown,  L., Chase  Brass  and  Copper Co.,
      to Farmer,  J. R., EPA:ESED.   April 12, 1983.  Response  to  Section  114
      information  request.

10.   Keitz, E.  L.  and K. J. Brooks.  A  Review  of Standards of Performance
      for New Stationary Sources-Secondary Brass and Bronze Plants.
      Prepared for  U.S. Environmental Protection Agency.    Research  Triangle
      Park, N.C.   Publication No.  EPA-450/3-79-011.   June 1979.

11.   Keitz, E.  L.  and K. J. Brooks.  A  Review  of Standards of Performance
      for New Stationary Sources—Secondary Brass and Bronze  Plants.
      Prepared for  U.S. Environmental Protection Agency.    Research  Triangle
      Park, N.C.   Publication No.  EPA-450/3-79-011.   June 1979.   p.  4-7.

12.  Telecon.    Keller, P., MRI, with Maudlin,  R.,  Brass  and Bronze  Ingot
      Institute.  April 21, 1983.   Brass and bronze alloy numbers and
    •classifications.
                                  2-16

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13.  JACA  Corporation.   Retrospective Analysis of the Economic Impact of
     NSPS  in  the  Brass  and  Bronze Industry.   Prepared for U.S.  Environmental
     Protection Agency.   Research Triangle Park,  N.C.   Project
     No. EPA  68-02-3812.  June  1983.

14.  Letter and attachments  from  Butterman,  W.,  U.S.  Bureau of Mines, to
     Hester,  C.,  MRI.   January  31,  1983.   Recent information on copper,
     brass,, and bronze.

15.  Memorandum from  Keller,  P.,  MRI,  to  project file 7704-L.   May 31,  1983.
     Plants in operation.

16.  Letter and attachment  from Bowman, P.  B.,  Brass  and Bronze Ingot
     Institute, to Atkinson,  R. D., MRI.   February 11,  1983.   p.  2.   U.S.
     Bureau of Mines  Brass  and  Bronze  Ingot  Industry  shipment  report.

17.  Memorandum from  Keller  P., MRI,  to project  file  7704-L.   May 31,  1983.
     Plant closings and  reduced schedules.

18.  Telecon.   Maudlin,  R.,  Brass  and  Bronze Ingot Institute,  with
     Hester,   C.,  MRI.  January  26,  1983.   Industry status.

19.  Memo and attachments from  Keller, P., MRI, to Iversen,  R.,  EPA:ISB.
     May 23,   1983.  Report of visit to I.  Schumann and  Company,  Bedford,
     Ohio.

20.  Memo and attachments from  Keller, P., MRI, to Iversen,  R.,  EPA:ISB.
     July 6,   1983.  Report of visit to Chase Brass and  Copper,  Solon,
     Ohio.

21.  Reference 10, p. 4-21.

22.  Reference 10, p. 4-22.

23.  Reference 10, p. 4-24.

24.  Reference 10, p. 4-26.

25.  Reference 1,  p.  272.
                                  2-17

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                       3.  SUMMARY OF CURRENT STANDARDS

3.1  NEW SOURCE PERFORMANCE STANDARDS
3.1.1  Summary of New Source Performance Standards •
     The affected facilities under the NSPS for secondary brass and
bronze ingot production processes are reverberatory and electric furnaces
of 1,000 kg (2,205 Ib) or greater production capacity and blast (cupola)
furnaces of 250 kg/h (500 Ib/h) capacity that were built, modified, or
reconstructed on or after June 11, 1973.1  The term "modified facility"
applies to facilities to which physical or operational changes have
caused an increase in the emission rate of any pollutant.  The term
"reconstructed facility" applies when the replacement cost of components
exceeds 50 percent of the cost of building a comparable new facility
(40 CFR 60).
     Owners and operators of affected facilites are required to control
particulate matter and limit opacity.  The standards state that exhaust
gases discharged to the atmosphere from revereberatory furnaces must not
contain particulate matter in excess of 50 milligrams per dry standard
cubic meter (mg/dscm) (0.022 grains per dry standard cubic feet [gr/dscf]),
and must not exhibit 20 percent opacity or greater.   The standards also
state that exhaust gases from electric and blast (cupola) furnaces must
not exhibit 10 percent or greater opacity.   No mass  emission standard
for electric and blast (cupola) furnaces is included in the NSPS.
3.1.2  Testing and Monitoring Requirements
     The owner or operator of an affected facility is required to  conduct
a performance test and furnish the Administrator with a written report
of the test results.
                                  3-1

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      Test methods to be used to determine compliance with the NSPS are':
      1.   Method 5 for the concentration of particulate matter and the
 associated moisture content;
      2.   Method 1 for sample and velocity traverses;
      3.   Method 2 for velocity and volumetric  flow rate;
      4.   Method 3 for gas analysis;  and
      5.   Method 9 for visible emission  observations.
      For  Method 5,  the sampling time for each  run  must be at  least
 120 minutes,  and the sampling rate must be at  least  0.9 dscm/h  (0.53 dscfm).
 The Administrator may approve shorter sampling times when they  are
 necessitated  by process  conditions.
      Secondary  brass and bronze plants  are not required to  use  continuous
 monitoring systems.
 3.2   STATE REGULATIONS
      Secondary  brass and bronze ingot production plants are currently
 operating in  13 States.   Table  3-1 summarizes  particulate emission
 regulations applicable in  these States  to  new  secondary brass and  bronze
 ingot production  processes in the  absence  of NSPS.   The most  stringently
 expressed State standard is  45  mg/dscm  (0.02 gr/dscf)  (New Jersey),
which is  slightly  lower  than  the 50  mg/dscm (0.022 gr/dscf) limit  for
 reverberatory furnaces established by the  NSPS.  Ohio, Michigan,
 Pennsylvania, and certain  districts  in  California require the use  of
best available  control technology  (BACT) on new sources.  This  requirement
has, in some cases,  resulted  in a  State enforcing more stringent emission
and opacity limits than  those required  by  the  NSPS.2
     Using the  process weight rate equation shown in Table 3-1, a  furnace
with a process weight  rate of 0.9  Mg/h  (1  ton/h) would be allowed  to
emit 1.9  kg/h (4.1 Ib/h) per hour  of  particulate matter.  By comparison,
the NSPS  limits these  emissions to between 0.5 and 0.7 kg (1.0 and
1.5 Ib) per hour (based  on typical air  stream  flow rates  in the secondary
brass and bronze industry).3
     All 13 States limit visible emissions to  less than 20 percent
opacity for new facilities and to 40 percent opacity or less for existing
facilities.  Most States have been delegated enforcement authority for
                                  3-2

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       TABLE  3-1.   SUMMARY  OF  STATE  REGULATIONS  FOR  SECONDARY BRASS
                      AND BRONZE  PRODUCTION  PROCESSES5
State
Alabama
California3
Bay Area
SCAQMDC
Delaware
11 1 inois
Indiana
Kansas
Massachusetts
Michigan
New Hampshire
New Jersey
New York
Ohio3
Pennsylvania3
No. plants
4
2
1
1
6
2
1
3
2
1
1
2
7
4
Regulation
E = 4.1 x po.6?b
E = 4.1 x P°-67
Table 405(a)
Table (Reg. 5, Sec. 4.1, Type 2)
E = 4.1 x P°-67
E = 4.1 x P°-67
E = 4.1 x P°-67
0.06 gr/dscf
E = 4.1 x P°*67
E = 4.1 x po.67
0.02 gr/dscf
E = 4.1 x P°-67
E = 4.1 x P°-67
0.02 to 0.04 gr/dscf (dependent
on air flow)
bRequire best available control technology (BACT) for new source.
 E = allowable emission rate in Ib/h.
CP = process weight rate in tons/h.
 .Reference 7.
 States that have not accepted NSPS delegation.
                                    3-3

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the NSPS for the secondary brass  and  bronze' ingot  production  industry

(see Table 3-1).  Those States that have  not accepted  delegation  of  the

NSPS, Delaware and Kansas, state  that they  do not  have the  money  or

personnel at this time to enforce the NSPS  regulations.4,5

3.3  REFERENCES FOR CHAPTER 3

1.  U.S. Environmental Protection Agency.   Code of Federal  Regulations.
    Title 40, Chapter I, Subchapter 3, part 60.  Washington,  D.C.
    Office of the Federal Register.   July 1,  1981.

2.  Memo from Keller, P., MRI, to Iversen,  R., EPA:ISB.  April 18, 1983.
    Minutes of Meeting with Cleveland Division of  Air  Pollution Control.

3.  Background Information for Proposed New Source Performance Standards,
    Volume 1:  Main Text, U.S. Environmental  Protection Agency Office of
    Air and Water Programs Research Triangle  Park,  N.C.  June 1973.
    61 p.

4.  Telecon.   Keller, P.,. MRI, with Cotter,  J. , Kansas Department of
    Health and Environment.   April 21, 1983.  Enforcement authority.

5.  Telecon.   Keller, P., MRI, with Peronti,  J., Delaware Air Resources.
    April 21, 1983.   Enforcement  authority.

6.  State Air Laws.   Volumes 1, 2, and 3, Environment  Reporter.

7.  Rules and Regulations.   South Coast Air Quality Management District.
    El  Monte, California.   May 1976.   pp. IV-4 and IV-5.
                                  3-4

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                     4.  STATUS OF CONTROL TECHNOLOGY

4.1  EMISSIONS POTENTIAL
4.1.1  Emissions From Materials Preparation
     Pyrometallurgical processes (sweating, wire burning, drying, and using
blast or cupola furnaces) all create air pollutants to some degree.
Sweating is carried out at medium temperatures to remove low melting point
metals such as lead, solder, and babbit metal from radiators and other
scrap.   Metal fume losses are very low; however, fume and combustion
products of antifreeze residues, soldering salts, and hose connections
can be released.1  Discussions with State and local air pollution control
agencies revealed that most companies are eliminating the need for sweating
furnaces by being more selective in scrap selection or by introducing dirty
scrap directly into the melting furnaces.2,3
     The potential fugitive particulate matter emission factor for uncon-
trolled wire burning is 6.88 kg of particulate matter per megagram of scrap
processed (13.75 lb/ton).4  In addition, the emissions from this incinera-
tion process may contain significant amounts of hazardous and/or toxic
substances such as reactive hydrocarbons,  fluorides,  and the combustion
products of common polymers such as polyvinyl chloride.2  Because wire
burning is potentially a large source of particulate  matter emissions as
well as the other pollutants mentioned above, many secondary brass and
bronze  facilities no longer accept this type of scrap.2
     A  heated rotary dryer is often used to vaporize  excess cutting fluids
from machine shop chips or borings.   This  drying operation  creates hydro-
carbon  emissions.   The potential  fugitive  particulate matter emission factor
for rotary dryers is the same as  that for  wire burning;  however,  the nature
                                  4-1

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 of  the  combustion  process  determines  the  degree  to which  tile's e- emissions
 are oxidized.4
      Preparation of  materials  in  blast  furnaces  and  cupolas  results  in
 emissions  that  are similar to  emissions from  the smelting/melting  furnaces
 (discussed in the  next  section).   However,  since blast  furnaces  and
 cupolas are generally used to  concentrate low-grade  scrap, slag, and
 skimming,  emissions'from these sources  have a higher percentage  of
 nonmetallic particles than do  emissions from  smelting/melting  furnaces.
 4.1.2   Emissions From Smelting
     Air pollutants  emitted from  secondary  brass  and bronze  smelting
 furnaces consist of  products of combustion, dusts, and  metallic  fumes.
 The  particulate matter  comprising  the dust  and fume  load  varies  according
 to  the  fuel, alloy composition, type of furnace,  melting  temperature,
 and  other  operating  factors.   In  addition to  fly  ash, carbon,  and
 mechanically produced dust, furnace emissions generally contain  fumes
 resulting  from oxidation and condensation of  the  more volatile elements,
 including  zinc, lead, and  others.  An analysis of the dust collected by
 a secondary brass  and bronze plant baghouse indicated the presence of
 the  following constituents:5
               Component
                 Zinc
                 Lead
                 Tin
                 Copper
                 Chlorine
                 Sulfur
Particulate composition,
   percent by weight
       45.0-77.0
       1.0-12.0
       0.3-2.0
       0.05-1.0
       0.5-1.5
       0.1-0.7
     Zinc and other fumes are 0.03 to 0.5 urn in diameter.5
     Direct-fired furnaces of the reverberatory and rotary type produce
larger quantities of metallic fumes, such as zinc and lead oxide, than
do the indirect-fired furnaces.   This is due to the introduction of the
hot burner flames and gases directly on the charge, resulting in vaporiza-
tion of larger quantities of the lower boiling point metals.   Other
factors causing relatively large concentrations of zinc fumes in furnace
gases are discussed in the following sections.
                                  4-2

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      The  fuel  used  in  the various  furnaces  can  have  important effects  on
 the  types of emissions from  brass  and  bronze  facilities.   The use of oil
 requires  careful  control  techniques  to minimize pollutants such  as
 smoke,  soot, and  unburned fuel  particles.   Gas  is  often more  trouble-free,
 both in minimizing  emissions  and supplying  the  proper  combustion conditions.
      4.1.2.1   Charging.   Charging  emissions are dependent  on  the condition
 of the  scrap,  location of the charging doors, percentage of volatile
 alloy constituents,  and upon  whether the entire charge is  made at the
 beginning of the  heat  or  at  intervals  during  the melt.  Even  if  scrap
 has  been  pretreated  to remove contaminants, particulate and unburned
 hydrocarbon emissions  can still occur  during  charging.  Overhead charging
 doors,  used in stationary reverberatory furnaces (which are being replaced
 by rotary reverberatory furnaces)  permit losses  of hot gases, fly ash,
 and  fume  into  the plant when  charges are loaded at intervals  during  the
 heat.   End and side  charging  doors in  rotary-type furnaces  permit
 significantly  less escape of  furnace gases  during charging.6  All  reverbera-
 tory  furnaces  subject  to  the  NSPS  are  rotary-type furnaces, which  charge
 via  end doors.
      4.1.2.2  Melting.  The furnace  is  closed for the  meltdown process.
 Increased zinc oxide emissions can result from  improper combustion,
 overheating of the charge, and heating  the  charge too  fast.7  The  use of
 nonuniform scrap can also  increase emissions.
      4.1.2.3  Refining.   Refining,  a chemical  process  of purification,
 is that cycle of smelting  in which impurities and other constituents of
 the charge, present  in  excess of specifications, are reduced or  removed.
 Refining methods vary  depending on the  type of furnace, composition of
 the scrap, and the desired alloy, but the basic  approach is the  same for
 all.   The chemicals used  in refining, commonly termed  fluxes,  may be
 gaseous,  liquid,  or solid.  Compressed air  is  the most extensively used.
 flux.  Blowing air into the molten  metal bath  causes a selective oxidation
 of metals in accordance with their  position in the electromotive series.
Air blowing also oxidizes  the remaining impurities.   The metal oxides
are entrapped in the slag  covering  or entrained in the furnace exhaust
gases.  Nitrogen is sometimes used  to remove gases and oxides  or to
mechanically and buoyantly lift foreign matter from the metal  bath.
                                  4-3

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Zinc  is partially oxidized  during  this'process, but this  is an  unavoidable
loss.  Solid fluxes as a whole do  not  contribute to air pollution.
Rather they have a generally beneficial effect on the quality of  stack
emissions by preventing excessive  volatilization losses.8
      4.1.2.4  Alloying.  Alloy modifications are made during the  heating
process by the addition of  virgin  metals or scrap.  This can cause an
increase in fume emissions.  The formation of fumes increases as  the
percentage of volatile constituents increases.  Due to its very low
boiling point, zinc is the  most serious problem, with the rate of zinc
loss  being approximately proportional  to the zinc percentage in the
alloy.7
      4.1.2.5  Pouring.  Physical methods of pouring the molten alloy
into  molds vary; however, in all cases, metal oxide fumes are emitted
when  the hot molten metal is poured through the air.  For a given percentage
of zinc, an increase in temperature of 56°C (100°F) increases the rate
of loss of zinc about three times.7  Other dust may be produced, depending
upon  the type of linings or coverings associated with the mold as it is
filled with hot molten metal.9
4.2   CONTROL TECHNOLOGY
4.2.1  Control of Particulate Matter Emissions During Charging,  Melting, and
       Refining
      Particulate matter emissions  are captured with either side draft
hooding or charging enclosures.   There are three basic types of primary
control equipment used to control  this captured particulate matter from
the exhaust gases of ingot production processes:   wet scrubbers, ESP's,
and baghouses.   Of these, baghouses are BDT for reverberatory,  electric,
and blast (cupola) furnaces.
     Of the 37 secondary brass and bronze plants currently in operation,
3 use only wet scrubbers, 1 uses wet scrubbers and ESP's,  1 uses an ESP,
1 uses wet scrubbers and baghouses, 30 use only baghouses, and 1 minor
source is uncontrolled.   All five  plants having NSPS affected facilities
use only baghouses as the primary means of particulate control  (see
Table 2-4).   The infrequent use of wet scrubbers and ESP's is mainly due
to their inability to remove metal  fumes,  such as zinc oxide,  as efficiently
                                  4-4

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 as  baghouses  can.  Wet  scrubbers  typically  are  unable  to  provide the
 level of  control  required  under the  NSPS  and  have  the  disadvantages  of
 relatively  high power consumption, maintenance  requirements,  and water
 and solid waste pollution.   Electrostatic precipitators have  difficulty
 in  collecting metal  oxides  because of  the relatively high resistivity  of
 such particles.10
     Typical  fabric  filters  used  in  the secondary  brass and bronze
 industry  have volumetric capacities  ranging from 5 to  15  standard cubic
 meters of air per second (10,000  to  25,000  standard cubic feet per
 minute).  The air-to-cloth  ratio  of  baghouses used in  the secondary
 brass and bronze  industry can range  from  1:1.5  to  5:1.  Fabric filters
 typically have particulate  removal efficiencies in excess of  99  percent
 and have  relatively  low pressure  drop  and power requirements.10-15
 Fabric filters are considered best demonstrated technology (BDT)  for the
 control of  particulate emissions  in  the secondary  brass and bronze
 industry.    Fabric filters on affected  facilities are typically made of
     ®
 Nomex  and  cleaned by the shaker  method.
 4.2.2  Control of Particulate Matter Emissions During  Pouring
     The  NSPS does not apply during periods of pouring.   Although specialized
 hooding systems,  made of such materials as  canvas,  are used to capture
 these emissions,  their effectiveness is limited.   This is  because personnel
 need access to the pouring area,  thus preventing the optimum  location of
 hoods.   Observations made during  plant visits indicate the magnitude of
 these uncaptured emissions is not significant.
4.2.3  Control of Unregulated Pollutants
     The NSPS does not include specific limits for each pollutant emitted
 from secondary brass and bronze plants.  Metal oxides such as lead oxide
are the major unregulated pollutants.  Control of metal oxides is
efficiently accomplished with baghouse technology,  which  is currently
BDT for particulate matter emission control.
4.3  REFERENCES FOR CHAPTER 4
 1.   Keitz,  E. L.  and K.  J.  Brooks.   A Review of Standards of Performance
     for New Stationary  Sources—Secondary Brass and Bronze Plants.
     Prepared for U.S.  Environmental  Protection  Agency.  Research Triangle
     Park, N.C.   Publication No.  EPA-450/3-79-011.   June 1979.  p. 4-21.
                                  4-5

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 2.  Telecon.   Keller,  P., MRI,  to Wood,  B.,  Alabama  Air  Pollution Control"
     Commission.   February 24, 1983.   Pretreatment  of scrap  used in
     secondary  brass  and  bronze  facilities  in Alabama.

 3.  Telecon.   Keller,  P., MRI,  to Seaman,  D.,  Cleveland  Division of Air
     Pollution  Control.   February 24,  1983.   Pretreatment of scrap used
     in secondary  brass and  bronze facilities in  Ohio.

 4.  U.S. Environmental Protection Agency.  Compilation of Air  Pollutant
     Emission Factors,  Supplement No.  9,  Third  Edition (including
     supplements 1-7) Office of  Air and Waste Management,  Research
     Triangle Park, N.C.  AP-42.  July 1979.   p.  7.9-7.

 5.  PEDCo Environmental, Incorporated.   Technical  Guidance  for Control
     of Industrial Process Fugitive Particulate Emissions.   Prepared for
     U.S. Environmental Protection Agency.  Research  Triangle Park,  N.C.
     Publication No.  EPA-450/3-77-010.  March 1977.   p. 2-208.

 6.  Midwest Research Institute.  Handbook  of emissions,  Effluents,  and
     Control Practices  for Stationary  Particulate Pollution  Sources.
     Prepared for  Division of Process  Control  Engineering  National  Air
     Pollution  Control Administration, United States  Department of
     Health, Education and Welfare.  Cincinnati,  Ohio.  Contract No.  CPA
     22-69-104.  November 1970.  pp. 402-404.

 7.  U.S. Environmental Protection Agency.  Air Pollution  Engineering
     Manual, 2nd Edition.   Office of Air  and  Water  Programs, Research
     Triangle Park, N.C.  AP-40.  1973.   p. 270.

 8.  Reference  1,  p. 4-40.

 9.  Reference  6,  p. 405.

10.  Reference  7,  p. 282.

11.  Letter and attachments from Horton,  T.,  National Metals, Inc.,  to
     Farmer, J. R., EPArESED.  May 9,  1983.   Response to Section  114
     information request.

12.  Letter and attachments from Singh, A., and Sabatka, M., Federal
     Metals, Inc.,  to Farmer, J. R., EPA:ESED.  May 9, 1983.  Response
     to Section 114 information request.

13.  Letter and attachments from Oberlin, J.  P.,  I.  Schumann and  Company,
     to Farmer, J.  R., EPA:ESED.  May  5,  1983.  Response to  Section 114
     information request.

14.  Letter and attachments from Sherman, G., American Brass, Inc., to
     Farmer, J. R., EPA:ESED.  May 5,  1983.   Response to Section  114
     information request.
                                  4-6

-------
15.   Letter and attachments from Brown, L., Chase Brass and  Copper  Co.,
     to Farmer, J. R., EPA:ESED.  April 12, 1983.  Response  to  Section  114
     information request.
                                 4-7

-------

-------
                          5.   EMISSION TEST RESULTS

 5.1  ANALYSIS  OF EMISSION TESTS
      Since  the NSPS  was  proposed on June 11,  1973,  six facilities in
 five  plants have become  subject to  its provisions.   Two of these plants
 (American Brass,  Inc., and Chase Brass & Copper in  Solon,  Ohio)  were
 constructed since the  NSPS proposal.   Three plants  (National  Metals,
 Inc.,  Federal  Metals,  Inc.,  and I.  Schumann & Company) have installed
 new furnaces.   Particulate emission rates  and visible  emission readings
 from  affected  furnaces at these plants and from one. electric  furnace not
 affected (Chase  Brass &  Copper  in Montpelier,  Ohio)  are given in Table 5-1
 and are discussed below.
 5.1.1  Reverberatory Furnaces
      Furnaces  subject to  the NSPS at  four  of  the five  plants  are the
 rotary reverberatory type.  As  can  be  seen from Table  5-1,  each  of the
 operating furnaces is in  compliance with both  the 50 mg/dscm  (0.022 gr/dscf)
 particulate matter emission standard and the  20 percent visible  emis.sion
 standard.    Plant  visit to  I. Schumann  & Company confirmed  the low opacity
 from their  facility.
 5.2.1  Electric,  Blast, and Cupola  Furnaces
     Currently one electric furnace (at Chase Brass &  Copper) and no
 blast or cupola furnaces are subject to the NSPS.  Table 5-1 shows the
 electric furnace  is in compliance with the 10 percent  opacity limit.   A
plant visit to Chase Brass & Copper (Solon, Ohio) verified the low
opacity of emissions  from this facility.  The particulate emission rate
from this  affected facility is well  below the 50 mg/dscm (0.022 gr/dscf)
emission limit applicable to reverberatory furnaces.   The particulate
emission rate from an electric furnace (at Chase Brass & Copper,  Montpelier,
                                  5-1

-------


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Ohio) not subject to the NSPS  is  also presented.   The  participate emission

rate from this facility is also well below  the  emission  limit  applicable
to reverberatory furnaces.

5.2  OTHER ATMOSPHERIC EMISSIONS

     None of the plants having affected facilities pretreat  the  scrap

before charging.  All five plants use a charging material containing

less than 10 percent lead, two reporting only trace amounts  of lead in

the charging material.   Cadmium, mercury, arsenic, and chromium  are

reported to be present in only trace amounts in charging material  for
all affected facilities.9-13

5.3  WATER DISCHARGES AND SOLID WASTE GENERATION

     No wastewater discharges are produced by the plants having  affected

facilities.   Solid waste products including zinc oxide (baghouse  dust)

at all  affected facilities and slag at one affected facility are  collected
and sold.9-13

5.4  REFERENCES FOR CHAPTER 5

 1.  Telecon.   Moore, B.,  EPArRegion IV,  with Keller,  P., MRI.   February 10,
     1983.   Brass and bronze plants in Region IV.

 2.  Telecon.   Wood,  W.,  Alabama Air Pollution Control  Commission, with
     Keller,  P.,  MRI.   February 14,  1983.   Furnace type,  control  equipment,
     and emission rates  for brass and bronze plants in  Alabama.

 3.  Telecon.   Wood,  W.,  Alabama Air Pollution Control  Commission, with
     Keller,  P.,  MRI.  May 18,  1983.   Opacity data for  American Brass,
     Inc.

 4.  Telecon.   Mr.  Hudo,  Alabama Air Pollution Control  Commission, with
     Keller,  P.,  MRI.  February 14,  1983.   Emission and control  data for
     National  Metals,  Inc.,  Leeds, Alabama.

 5.  Telecon.   Wood,  W.,  Alabama Air Pollution Control  Commission, with
     Keller,  P.,  MRI.  April  14,  1983.  Opacity data  for  National Metals,
     Inc.,  Leeds, Alabama.

 6.   Telecon.   Seaman, D.,  Cleveland Office  of Ohio EPA,  with Keller,  P.,
     MRI.   February 16, 1983.   Emission and  opacity data  for  brass and
     bronze plants  in Ohio.

 7.   Letter and attachments  from  Seaman, D.,  Cleveland  Division of Air
     Pollution  Control, to  Atkinson,  D., MRI.   April 13,  1983.  Source
     test results for I. Schumann  &  Co., and Chase  Brass  and  Copper.
                                  5-3

-------
 8.  Letter and attachments from Majewsky,  D.,  Northwest  Ohio  EPA  to
     Keller, P., MRI.  June 13, 1983.  May  20,  1982,  and  January 14,
     1975, stack test for Chase Brass and Copper  Company  in  Montpelier,
     Ohio.

 9.  Letter and attachments from Sherman, G., American  Brass,  Inc., to
     Farmer, J. R., EPAtESED.  May 5, 1983.   Section  114  information
     request.

10.  Letter and attachments from Morton, T.,  National Metals,  Inc., to
     Farmer, J. R., EPA:ESED.  May 9; 1983.   Section  114  information
     request.

11.  Letter and attachments from Singh, A.,  and Sabatka,  M., Federal
     Metals, Inc., to Farmer, J. R., EPA:ESED.  May 9,  1983.
     Section 114 information request.

12.  Letter and attachments from Oberlin, J.  P.,  I. Schumann & Co., to
     Farmer, J. R., EPA:ESED.  May 5, 1983.   Section  114  information
     request.

13.  Letter and attachments from Brown, L.,  Chase Brass and  Copper Co.,
     to Farmer, J. R. , EPA.-ESED.  April 12,  1983.  Section 114 information
     request.
                                  5-4

-------
                              6.   COST  ANALYSIS
                           «
     The purpose  of  this  chapter  is  to present  updated  capital  and
annualized costs  for control  systems used to  achieve  the  NSPS and to
discuss the cost  effectiveness of any  proposed  changes  to the NSPS.  To
estimate the economic consequences of  the NSPS, model plant descriptions
were developed to serve as a  basis for estimating costs.   The model
plant  descriptions are summarized in Table 6-1  and are  representative of
plants currently  subject  to the NSPS.1-5  No  model plant  description is
presented for blast  (cupola)  furnaces  because none are  currently subject
to NSPS or are expected to become subject in  the future.   The updated
costs, including capital  costs and annualized costs,  of control equipment
for typical affected facilities are also shown  in Table 6-1.  These
costs were updated to December 1982 dollars using the Chemical  Engineering
plant cost index and company  data.1-6
     The capital cost of  a control system includes all the cost items
necessary to design, purchase, and install the particular  device or
system.  The capital cost includes the purchased costs of  the major
control device and auxiliaries such as fans and instrumentation; the
equipment installation cost including  foundations, piping, electrical
wiring, and erection; and the cost of  engineering construction overhead
and contingencies.
     The annualized cost of a control  system is the cost to the company
to own and operate the system.  The annualized costs include direct
operating costs, such as labor, utilities, and maintenance; and capital
related charges, such as depreciation,  interest, administrative overhead,
property taxes,  and insurance.
                                  6-1

-------
 6.1  REVERBERATORY FURNACES
      Most States  use the same process  weight equation to establish  a
 mass  emission  standard of approximately 63.6 mg/dscm (0.028 gr/dscf) for
 reverberatory  furnaces.   Because this  is so  near the level  of the NSPS,
 there is  unlikely to be a discernable  difference in  the  emission rate of
 a  furnace complying with the  typical State limit and an  otherwise identical
 furnace complying with the NSPS.   The  capital  and annualized costs  of
 air pollution  control  equipment  and associated ductwork,  pumps, etc.,
 necessary for  a typical  plant to meet  either the most common SIP or the
 NSPS  are  approximately $514,000  and $190,000,  respectively  (see Table 6-1).
      Because there is  no significant difference in either the emission
 rates  or  control  equipment costs for facilities meeting  the predominant
 State  standard and those complying with  the  NSPS,  there  is  no incremental
 cost  effectiveness.  However,  the cost effectiveness  of  the NSPS and
 predominant State  limit  compared to uncontrolled is  estimated to be
 $135  per  ton based on  the uncontrolled emission factor given in AP-42.7
 6.2   ELECTRIC  FURNACES
     Most States apply the same  process  weight equation  used to determine
 emission  limits for reverberatory furnaces to  also determine emission
 limits for electric furnaces.  Since typical electrical  furnaces process
 brass  and bronze at the  same  rate as typical reverberatory  furnaces,  the
 same predominant State standard  applies, 63.6  mg/dscm (0.028 gr/dscf).
 Because this mass  emission  standard is based on  the  use of  the same
 control technology as the  10 percent visible emission limit  under the
 NSPS,  no  additional  capital expenditures are necessary to meet the  NSPS
 limit  over those necessary  to comply with these  State requirements.
     If the same mass emission limit set by the  NSPS for  reverberatory
 furnaces were  applied to  electric  furnaces, no  additional capital  expendi-
 tures beyond those  necessary for  typical SIP compliance would be required
 since the two  standards would limit emissions  to essentially the same
 level.  The capital  and annualized costs for control  to meet either the
most common SIP or  the NSPS reverberatory limit are approximately $290,000
and $135,000,  respectively  (see Table 6-1).   Because there would be  no
significant difference in either capital costs for air pollution control
equipment or emission rates for identical furnaces under the NSPS  and

                                  6-2

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the predominant SIP, there would be no incremental cost effectiveness.
The cost effectiveness of either the most common SIP or the NSPS reverbera-
tory limit applied to electric furnaces is estimated to be $1,500 per
ton compared to uncontrolled.  This value is based on the AP-42 emission
factor for uncontrolled electric furnaces.7
6.3  RETROSPECTIVE ANALYSIS OF ORIGINAL ECONOMIC IMPACT PROJECTIONS
     The original economic impact analysis of the NSPS, performed in
1973 by the EPA, used a "model plant" approach.  Three reference furnace
sizes were distinguished:  20, 50, and 75 tons.
     Representative income statements for the model plants were developed
in the original analysis using representative values for plant operating
hours, investment requirements, operating costs, and product prices.
The annualized and capital control cost estimates were compared to the
income statement items to estimate impacts in terms of:  the percent
reduction in earnings and cash flow (assuming all costs are absorbed),
the percent increase in prices (assuming all costs are passed on), and
the increase in new plant investment requirements.
     Reductions in earning and cash flow were determined by the addition
of NSPS control costs to the baseline operating costs of each plant and
recalculating earnings and cash flow after tax.  The percent price
increases were estimated through the expression of annualized control
costs as a percent of model plant revenues.
     The findings of the original analysis were that the economic impact
of the NSPS on affected brass and bronze plants would be very small.  If
all costs were to be paid by the firms rather than passed to their
customers in the form of increased prices, earnings would decline by
about 5 or 6 percent while cash flow would decrease about 1 or 2 percent.
More likely, however, prices would be increased, and the extent of such
price increases would be about 0.4 percent.
     A retrospective analysis of the economic impact of the NSPS on the
brass and bronze industry was conducted in 1983 as part of this review.10
The review was conducted to judge the accuracy of the original EPA
analysis and to project future (5-year) economic impacts of the NSPS on
the brass and bronze industry.  New costs were not obtained during the
                                  6-4

-------
review; rather the original EPA estimates were updated using appropriate
indices.
     The findings of this analysis are:
     1.  An analysis of brass and bronze price trends during the 10 years
preceding proposal of the NSPS and extending through the 7 years following
proposal of the standards, indicates that NSPS cost impacts have not
contributed to price escalation in the brass and bronze industry (see
Table 6-2).
     2.  However, the control  costs associated with the standard resulted
in a product price increase of 0.4 percent for typical furnaces.  The
product price impact will remain at this level in the near future (next
5 years),  assuming .that the standard will not be changed from its form
as promulgated in 1974.
     3.  In recent years, the  rate of decline in brass and bronze production
has become smaller,  indicating that the rate of decline in total industry
output has not been accelerated by the NSPS.
                                 6-5

-------
    TABLE 6-2.  PRICES FOR BRASS AND BRONZE INGOTS10
                   (Cents per pound)
Year
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
Current9
32.00
35.14
41.02
50.34
44.79
44.26
51.92
56.35
52.94
51.90
66.02
84.49
65.87
70.03
69.68
72.76
92.75
106.11
Price index
91.3
93.8
96.4
98.8
100.0
102.6
108.5
116.6
118.7
123.5
132.8
171. 9
185.6
195.9
209.0
227.1
259.3
286.4
Constant'
100.38
107.29
121.87
145.92
128.28
123.55
137.05
138.41
127.73
120.36
142.38
140.77
101.64
102.38
95.48
91.76
102.44
106.11
.Prices not adjusted for inflation.11
^Reference 12.
 Prices adjusted for inflation and expressed in 1980
 dollars.13
                          6-6

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 6.4  REFERENCES FOR CHAPTER 6

  1.   Letter and attachments from Sherman, G.,  American Brass, Inc., to
      Farmer,  J.  R.,  EPA:ESED.   May 5, 1983.   Response to Section 114
      information request.

  2.   Letter and attachments from Morton, T.,  National Metals, Inc., to
      Farmer,  J.  R.,  EPA:ESED.   May 9, 1983.   Response to Section 114
      information request.

  3.   Letter and attachments from Singh,  A.,  and M.  Sabatka, Federal
      Metals,  Inc.,  to  Farmer,  J.  R.,  EPA:ESED.   May 9,  1983.   Response
      to  Section 114  information request.

  4.   Letter and attachments from Oberlin, J.  P.,  I.  Schumann  and Co.,  to
      Farmer J.  R. ,  EPA:ESED,  May 5,  1983.  Response to  Section 114
      information request.

  5.   Letter and attachments from Brown,  L.  G.,  Chase Brass  and Copper
      Co., to  Farmer, J.  R. ,  EPA:ESED.  April 12,  1983.   Response to
      Section  114 information  request.

  6.   Economic  Indicators:   Chemical  Engineering.  May 16, 1983.   p.  7.

  7.   U.S. Environmental  Protection Agency.  Compilation  of  Air Pollutant
      Emission  Factors, Third  Edition,  Supplement  No.  9.  Office  of Air
      and Waste Management,  Research Triangle Park,  N.C.  EPA  Publication
      No. AP-42.   July  1979.  p.  7.9-5.

  8.   Memorandum  from Keller, P.,  and  D.  Atkinson, MRI, to Iversen,  R.,
      EPA:ISB.  May 31, 1983.  Tabular cost memo for  secondary brass  and
      bronze NSPS  review.

  9.   R. B.  Neveril, CARD,  Inc.  Capital  and Operation Cost  of Selected
      Air Pollution Control  Systems.   U.S. Environmental  Protection
      Agency.  Research Triangle Park,  N.C.  EPA Publication No.  EPA-450/
      5-80-002.   December 1978.  pp. 3-11  to 3-14, 3-17,  4-36,  4-37
      4-39, 4-22, 4-29, 4-30, 4-35 to  4-37, 4-46, 4-58, 4-50,  4-59, 4-61,
      4-66, 4-73, 5-26, 5-32, B-2.

10.  JACA Corporation.   Retrospective  Analysis of the Economic Impact of
      NSPS in the Brass and Bronze Industry.  Prepared for U.S. Environmental
      Protection Agency.  Research Triangle Park, N.C.  Project No.
      EPA 68-02-3812.   June 1983.

11.  American Metals Market.  "Metal  Statistics 1981."   Page  83.  Average
     annual  prices for 85-5-5-5 brass  ingot.

12.  Council of Economic Advisors.  "Economic Report of the President."
     February 1983.   Producer price index for metals and metal products.
     p. 231.
                                  6-7

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13.   Telecon:  Keller, P., MRI, with Castello, T. , JACA Corp.   July 27, 1983.
     Information concerning the JACA retrospective analysis of the economic
     impact of NSPS in the brass and bronze industry.
                                  6-8

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                           7.   ENFORCEMENT ASPECTS

      All  five  facilities  subject to the NSPS are currently in compliance
 with  the  NSPS  and applied State regulations.   Company personnel  contacted
 on  plant  visits  and in  writing indicated that they have no problems
 complying with the NSPS.   Discussions  with EPA regional  offices  and
 State and local  agencies  indicate that there are no major problems  in
 enforcing the  NSPS for  the secondary brass and bronze industry.1-3
      Of the  five facilities currently  subject to the NSPS,  two are
 located in Alabama and  three  are located in Ohio (see Table 2-4).  Both
 States have  accepted delegation of enforcing the NSPS for the secondary
 brass  and bronze industry.  Plants operating in  Alabama  are required to
 use sound engineering emission  capture practices to control  particulate
 matter emissions.1  New plants  operating in Ohio are required to comply
 with  the  State's  BACT standard  in  addition to  any applicable  NSPS.  In
 accordance with  this standard,  new electric furnaces  in  brass  and bronze
 plants are required to  meet the  50 mg/dscm (0.022 gr/dscf)  mass standard,
 currently  only applied  to  reverberatory  furnaces  under the  NSPS.   New
 facilities are also required by  Ohio to  meet the  opacity  limit evidenced
 during the compliance test, resulting  in a 0 percent  opacity  standard
 for the two operational facilities.2   Ohio  and Alabama personnel  stated
 that continuous monitoring and  reporting are not  necessary at this time.4,5
     The NSPS is written to cover  reverberatory,  electric, and blast
 (cupola) furnaces that  are used  in brass and bronze  ingot production
plants.  One prototype  facility, located in Ohio, uses an electric
 furnace to continuously cast rod instead of batch casting ingot.   The
State of Ohio considers this furnace to be  subject to the NSPS.
     The NSPS does not cover fugitive emissions; however, both Alabama
and Ohio require  specialized hooding for the capture of these emissions,
                                  7-1

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which are ducted to a common baghouse with affected facilities.  Emissions

from these baghouses are required to meet NSPS and State standards.

7.1  REFERENCES FOR CHAPTER 7

1.  Telecon.  Keller, P., MRI, with Wood, B., Alabama Air Pollution
    Control Commission.  April 14, 1983.  Alabama enforcement of NSPS
    and State standards.

2.  Memo from Keller, P., MRI, to Iversen, R., EPA:ISB.  April 18, 1983.
    Minutes of meeting with Cleveland Division of Air Pollution Control.

3.  Telecon.  Keller, P., MRI, with Moore, B.  EPArRegion IV.  February 10,
    1983.   Compliance status of secondary brass and bronze facilities in
    Region IV.

4.  Telecon.  Keller, P., MRI, with Wood, B., Alabama Air Pollution
    Control Commission.  May 12, 1983.   Alabama monitoring and reporting
    requirements.

5.  Telecon.  Keller, P., MRI, with Seaman, D., Cleveland Division of
    Air Pollution Control.   May 13, 1983.  Ohio monitoring and reporting
    requirements.
                                  7-2

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                                    TECHNICAL REPORT DATA
                             (Please read Instructions on the reverse before completing)
1. REPORT NO.
  EPA-450/3-84
                                                             3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
  Review of  New Source Performance Standards  for
  Secondary  Brass and Bronze  Plants
                                                             5. REPORT DATE
             -May TS84
          6. PERFORMING ORGANIZATION CODE
1, AUTHOR(S)
                                                             8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
  Office  of Air Quality  Planning and Standards
  U.S.  Environmental  Protection Agency
  Research  Triangle Park,  N.C.   27711
                                                             10. PROGRAM ELEMENT NO.
          11. CONTRACT/GRANT NO.

             68-02-3817
12. SPONSORING AGENCY NAME AND ADDRESS
  Director for Air Quality Planning and  Standards
  Office  of Air, Noise,  and Radiation
  U.S.  Environmental  Protection Agency
  Research Triangle Park,  N.C.   27711	
                                                             13. TYPE OF REPORT AND PERIOD COVERED
          14. SPONSORING AGENCY CODE
             EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
        This  report presents  the findings  of the second  4-year review of  the new
  source  performance standard for secondary brass and bronze production  plants.
  Information is presented  concerning industry growth, control technology,  compliance
  status,  and the costs  associated with compliance.
17.
                                 KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
                                               b.IDENTIFIERS/OPEN ENDED TERMS
                        c. COSATI F;ieid/Group
  Brass  and Bronze
  NSPS
  Air  Pollution
  Pollution Control
  Emission Standards
  Particulate Matter
Air Pollution Control
13b
18. DISTRIBUTION STATEMENT
  Unlimited
                                               19. SECURITY CLASS (This Report!
                                                 Unclassified
                        21. NO. OF PAGES
                            50
                                               20. SECURITY CLASS IThispage)
                                                 Unclassified
                       I 22. PRICE

                       i
EPA Form 2220-1 (Rev. 4-77)
                       PREVIOUS  EDITION IS OBSOLETE

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