I
                              AP-42
                        Supplement B
                     September 1988
    SUPPLEMENT B
            TO



    COMPILATION
           OF         ;

   AIR POLLUTANT
 EMISSION FACTORS
                       I
                       I
       Volum^ I:
    Stationary Point
   And Area Sources
U.S. ENVIRONMENTAL PROTECTION AGENCY
     Office Of Air And Radiation
 Office Of Air Quality Planning And Standards
 Research Triangle Park, North Carolina 27711

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           ,- In--,, ro u-wcd In The Office Of Air Quality Planning And Standards, U.S. Env.ronmental

,,ol inu-niloil to constiluto cndorM-nu-nl or rorommendal.on lor use.
                                              A I'-12
                                            \ olume I
                                          SupplciiK'iil

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                                                                                          I
                     INSTRUCTIONS FOR INSERTING SUPPLEMENT B

                                    INTO AP-42
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                                                       Major Revision.
Pp.

Pp.
Add
Add
 iii and  iv  replace  same.   New Publications  in Series.
 v  through viii  replace  same.   New  Contents.
 1.1-1 through 1.1-17  replace  same.  Minor Revision.
 1.2-1 through 1.2-7 replace same.  Minor Revision.
 1.10-1 through  1.10-5 replace 1.10-1 through  1.10-7.
 1.11-1 through  1.11-7 replace 1.11-1 and 2.   Major Revision.
 2.1-1 through 2.1-10 replace  2.1-1 through  2.1-6.  Major Revision.
 2.5-1 through 2.^-6 replace 2.5-1 through 2.5-3.  Major Revision.
 4.2.2 7-1 through 4.2.2.7-8 replace 4.2.2.7-1 through 4.2.2.7-3.  Major
  Revision.                             _                            J
pp. 4.12-1 through  4.12-10.   New Section.
                              5.15-1 through
                       	  -'.4-1 through 6.
Q 10 o through 8«15-5 replace same.  Editorial Change!
8.19.2-1 through 8.19.2-6 replace same.  Minor Revision.
8.24-1 through 8.24-11 replace same.   Minor Revision.
pp. 11-1 and 2.   Editorial Change.

                                                             Revision.
                                                              Ma j or

                                                              Major
                                                          °r  ^vision.
                                                          ^vision.
            -       .     . 	  - through 11.1-5.
11.2.1-1 through 11.2.1-8 replace 11.2.1-1 through  11,2.1-6.
  Revision.
11.2.3-1 through 11.2.3-5 replace 11.2.3-1 through  ll.;2.3-6.
  Revision.                                           I -
11.2.6-1 through 11.2.6-5 replace same.  Major Revision.
pp. 11.2.7-1 through 11.2.7-15.  New'Section.
pp. C.3-1 and 2.  New Appendix.

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]l

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                                                                                          1
                              PUBLICATIONS IN SERIES
        Issue
 COMPILATION OF AIR POLLUTANT EMISSION FACTORS (Fourth Edition)
 SUPPLEMENT A
   Introduction
   Section 1.1
   '•        1.2
           1.3
           1.4
        .1.6
           1.7
           5.16
           7.1
           7.2
           7.3
           7.4
           7.5
           7.6
           7.7
           7.8
   '        7.10
   :        7.11
           8.1
           8.3
           8.6
   i        8.10
           8.13
           8.15
           8.19.2
           8.22
   i        8.24
           10.1
   1        11.2.6
  Appendix C.I
   I
  Appendix C.2
                                                           9/85

                                                          10/86
 Bituminous And Subbituminous Coal Combustion
 Anthracite Coal Combustion
 Fuel Oil Combustion
 Natural Gas Combustion
 Wood Waste Combustion In Boilers
 Lignite Combustion
 Sodium Carbonate
 Primary Aluminum Production
 Coke Production
 Primary Copper Smelting
 Ferroalloy Production
 Iron And Steel Production
 Primary Lead Smelting
 Zinc Smelting
 Secondary Aluminum Operations
 Gray Iron Foundries
 Secondary Lead Smelting
 Asphaltic Concrete Plants
 Bricks  And Related Clay Products
 Portland Cement Manufacturing
 Concrete Batching
 Glass Manufacturing
 Lime Manufacturing
 Crushed Stone  Processing
 Taconite Ore  Processing
 Western Surface Coal  Mining
 Chemical Wood  Pulping
 Industrial  Paved Roads                   i
 Particle Size  Distribution Data  And Sized Emission
  Factors For  Selected Sources
 Generalized Particle  Size Distributions
SUPPLEMENT B
  Section 1.1
          1.2
          1.10
   :       1.11
          2.1
   !       2.5
   !       4.2
          4.12
   '       5.15
          6.4
Bituminous And Subbituminous Coal Combustion
Anthracite Coal Combustion
Residential Wood Stoves
Waste Oil Combustion
Refuse Combustion
Sewage Sludge Incineration
Surface Coating
Polyester Resin Plastics Product Fabrication
Soap And Detergents
Grain Elevators And Processing Plants
                                                         9/88
                                     iii

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Section 8.15
        8.19.2
        8.24
        11.1
        11.2.1
        11.2.3
        11.2.6
        11.2.7
Appendix C.3
Lime Manufacturing
Crushed Stone Processing
Western Surface Coal Mining
Wildfires And Prescribed Burning
Unpaved Roads
Aggregate Handling And Storage Piles
Industrial Paved Roads
Industrial Wind Erosion
Silt Analysis Procedures
                                       IV

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                                      CONTENTS            j

                                                          !                Page
  INTRODUCTION	..*... 4	
                         	!'	•	      i
  1.   EXTERNAL COMBUSTION SOURCES	
       1.1    Bituminous Coal Combustion ;".*.*.*	*"	''**	  Ll-l.
       1.2    Anthracite Coal Combustion ...*.*.	!	  1*1~1
   t    1.3    Fuel Oil Combustion	„	.'	"•••••<[	  1.2-1
       1*4    Natural Gas Combustion ...".*.	'	  1.3-1
       1.5    Liquified Petroleum Gas  CombJs'tion'.'.'.'.'.*.'.".'."	  J'*~J
       1.6    Wood Waste Combustion In Boilers	     	**"  \'5~\
       !•'     Lignite Combustion		  1.6-1
   ,    J.8   .Bagasse Combustion In Sugar*Mills".'.'.'.I'.'.'."*	   }*«"}'
       1.9     Residential  Fireplaces	             *	   •8~1
       1.10    Residential Wood Stoves  .....'	   1*9"1
       1.11   Waste  Oil  Combustion	.'.'.'.*.*.*.*.*	" 1'10~1
                                                **********•••••••••••• 1*11 •"!
 2.!    SOLID WASTE  DISPOSAL .*...	
       2.1    Refuse Combustion  i .*.'.*.".*"	>* " *	  2.0-1
   :    2.2    Automobile Body incin;;;;i;;'::::::;-"""-v'v-—  2.1-1
       2.3    Conical Burners		  Z.Z-L
       2.4    Open Burning	 	*	"t	  2.3-1
       2.5    Sewa6e siud|e incin^ion::::::::::::::::'''	j-4-1
                                                        **"****•**•••«  *t • j *~ i.
 3.:   STATIONARY INTERNAL COMBUSTION SOURCES              i
             Glossary Of Terms  	         	" * "|	  3.0-1
             Highway Vehicles		 Vo1'  II
   i          Off riighway Mobile  Sources  ..'.'.".'.'.'.'	2~1
     5.4     Charcoal ...^	m   5.3-1
     5.5     Chlor-Alkali ..*....".*.*.*.*.*.*.".°.*.'„"*.*.*"	••••••.	   5.4-1
     5.6     Explosives	«.....1!!1111	   5.5-1
     5.7     Hydrochloric Acid ....*.".* '.'.•'. .'.'."„"*.*."*	***   5'6-1
   :  5.8     Hydrofluoric Acid	   •••••«	    	   5e7_1
   i  5.9     Nitric Acid  i	..     	.••••••		   5.8-1
                              	•	   5.9-1

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                                                                       Page
6.
 7.
5.10 Paint And Varnish 	 	

5.12 Phthalic Anhydride 	 «' 	
5.13 Plastics 	
5.14 Printing Ink 	 • 	 • 	
5.15 Soap And Detergents 	
5.16 Sodium Carbonate 	 « 	 • 	
5. 17 Sulf uric Acid 	
5.18 Sulfur Recovery 	 • 	
5.19 Synthetic Fibers 	 	 	 •
5.20 Synthetic Rubber 	 	 	 • 	 • • • * 	
5.21 Terephthalic Acid 	 	
5.22 Lead Alkyl 	 '• 	 .........
5.23 Pharmaceuticals Production 	 	 	 ° 	
5.24 Maleic Anhydride 	 	 •••• 	
FOOD AND AGRICULTURAL INDUSTRY 	
6.1 Alfalfa Dehydrating 	 	 • 	
6.2 Coffee Roasting 	 • • • •
6.3 Cotton Ginning 	
6.4 Grain Elevators And Processing Plants ..........

6.6 Fish Processing 	 « 	 	

6. 8 Ammonium Nitrate Fertilizers 	 • 	
6.9 Orchard Heaters 	 	 • 	 - • « 	
6.10 Phosphate Fertilizers 	 	 •. 	 	
6.11 Starch Manufacturing 	 	 	 » 	
6. 12 Sugar Cane Processing 	 	 	 	 	
6.13 Bread Baking 	 • 	
6. 14 Urea 	 	
6.15 Beef Cattle Feedlots 	 	
6.16 Defoliation And Harvesting Of Cotton 	
6.17 Harvesting Of Grain 	 	 • 	 	

METALLURGICAL INDUSTRY 	

7.2 Coke Production 	 	
7.3 Primary Copper Smelting ., 	 - 	 ««••
7.4 Ferroalloy Production 	 	 	 • 	
7.5 Irxrn And Steel Production 	 • 	 •

7.7 Zinc Smelting 	 	 • 	
7.8 Secondary Aluminum Operations 	 	
7.9 Secondary Copper Smelting And Alloying 	
7.10 Gray Iron Foundries 	 	 	 • 	 « 	 •
7.11 Secondary Lead Smelting 	
7.12 Secondary Magnesium Smelting 	 	 « 	
7.13 Steel Foundries 	 	 ••
7.14 Secondary Zinc Processing 	 	 •• 	
7. 15 Storage Battery Production 	
	 5.10-1
C 1 0_1
5 13-1

5 1 S-1

c i 7_i
S 18-1

S ?0-1
•5 21-1




	 6.1-1
f. 1 _i
ft 0_1
6 3-1

6 5-1
6 6-1
A 7-1

69-1
f A 1 0 1
A 11—1


. 6.14-1



ft 1 8—1

	 	 7.1-1
7 2-1


7 "^—1

7 7-1


7 in — 1
7 11—1
719 1
7 1 3-1

	 7.14-1
7 1 S— 1

                                        vi

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                                                          i                Page

  i     7.16    Lead Oxide And Pigment Production	  7.16-1
  i     7.17    Miscellaneous Lead Products	,	'.'.'.'.'.  7'. 17-1
       7.18    Leadbearing Ore Crushing And Grinding	.'.*'.'.'  7*18-1
                                                          I
  8.  .  MINERAL PRODUCTS INDUSTRY .;.....	;	   8  1-X
       8.1     Asphaltic Concrete Plants ..	.....*.'.*.*.".'.*.*.*.".'.*   8*1-1
       8.2     Asphalt  Roofing	;*' **** *'**** "   8*2-1
  '     8.3     Bricks And Related Clay Products	'."*   8*3-1
       8.4     Calcium  Carbide Manufacturing	\   8*4-1
       8.5     Castable Refractories	.*.'.'.*.*.*.*   8*5-1
       8.6     Portland Cement Manufacturing	   8*6-1
       8.7     Ceramic  Cl-ay  Manufacturing	.*.'.*.'.'."   8*7-1
  .     8.8     Clay And Fly  Ash Sintering ,	.......*.'.". *.'.'.   8*8-1
       8.9     Coal Cleaning	„	'.'.'.'.   8*9-1
       8.10    Concrete Batching	*.'.'.'.*.*.*. 1 ".'.I*. 1 *.*. 1  8.10-1
  :     8.11    Glass Fiber Manufacturing .«,...	  8.11-1
       8.12    Frit Manufacturing	*.*.".'.'.!".!  8*12-1
       8.13    Glass Manufacturing	  8 13-1
       8.14,   Gypsum Manufacturing	'.'.'.'.  8*14-1
       8.15    Lime Manufacturing	'.'.'.I  8*15-1
      8.16   Mineral  Wool  Manufacturing	*.	....*. *.*.*.'.*. '.I!  8* 16-1
  ,    8.17    Perlite  Manufacturing	.....*..'.*.*."*.'.*  8*17-1
      8.18    Phosphate Rock  Processing	\  8*18-1
      8.19    Construction  Aggregate Processing	             « IQ-I
      8.20    [Reserved]	........".'.'.".'.'.'*.  8.20-1
      8.21   Coal Conversion	  8 21-1
      8.22   Taconite Ore  Processing  	{.	  g 22-1
  1    8.23   Metallic Minerals  Processing	;	 J."/ 8*23-1
  I    8.24   Western  Surface Coal  Mining  	1 .".*.*.*.*.'.'.'.*.*.". 8i24-l

 9;.    PETROLEUM INDUSTRY	t,	   9 1_i
      9.1    Petroleum Refining	*.l'.1 ".'.'.*.*.*.*.'.".*.".!  9J1-1
      9.2    Natural  Gas Processing	|	.*.*.'.**  9*2-1

 I'O.  WOOD PRODUCTS INDUSTRY .	.!....	  10 1-1
     10.1    Chemical  Wood Pulping	         *"*	  in'l-i
  i    10.2-   Pulpboard	'.'	'.'.'. 1 *.*.'.'.'.'.".'.".*."'.  10*2-1
     10.3    Plywood  Veneer And Layout Operations	  10*3-1
     10.4    Woodworking Waste Collection Operations	!."	'.'.*.  10*4-1

 U.  MISCELLANEOUS SOURCES	„	         n i-j
  !  '11.1    Wildfires And Prescribed Burning	**.**.!.  ll!l-l
  |.   11.2    Fugitive  Dust  Sources	.*.'.*.*.*.*.'  11*2-1
  !   11.3    Explosives Detonation ... „	*]  11*3-1
  1                                                        i
APPENDIX A   Miscellaneous  Data And Conversion Factors	    A-l

APPENDIX B   (Reserved For  Future Use)

APPENDIX C.I   Particle  Size. Distribution Data And Sized Emission
  ]                Factors For Selected Sources	   C.l-1
                                      vii

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                                                                        Page




APPENDIX C.2   Generalized Particle Size Distributions ..............   C.2-J



APPENDIX C.3   Silt Analysis Procedures 	,	   C.3-1
                                      viii

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  1.1   BITUMINOUS  AND  SUBBITUMINOUS COAL COMBUSTION

  L.I.I   General*
                                                         i
  ,
       Coal  is  a complex  combination of organic matter and inorganic ash formed
  over  eons  from successive layers of fallen vegetation.  Coal types are broadly
  classified as anthracite, bituminous, subbituminous or lignite, and classifica-
  tion  is made by  heating values and amounts of fixed carbon, volatile matter,
  ash,  sulfur and  moisture.  Formulas for differentiating coals based on these
  properties are given in Reference 1.  See Sections 1.2 and 1.7 for discussions
  of anthracite and lignite, respectively.

       There are two major coal combustion techniques, suspension firing and
  grate firing.  Suspension firing is the primary combustion mechanism in pulver-
  ized  coal  and cyclone systems.  Grate firing is the primary mechanism in under-
  feed  and overfeed stokers.  Both mechanisms are employed in spreader stokers.

       Pulverized  coal furnaces are used primarily in utility and large industrial
  boilers.   In these systems, the coal is pulverized in a mill to the consistency
  of talcum  powder (i. e., at least 70 percent of the particles will pass through
  a 200 mesh sieve).   The pulverized coal is generally entrained in primary air
  before being fed through the burners to the combustion chamber, where it is
  fired in suspension.  Pulverized coal furnaces are classified as either dry or
  wet bottom, depending on the'ash removal  technique.  Dry bottom furnaces fire
  coals with high ash  fusion temperatures,  and dry ash removal techniques are  •
  used.  In wet bottom (slag tap)  furnaces,  coals with low ash fusion tempera-
  tures are used,  and molten ash is drained  from the bottom of the furnace.
  Pulverized coal  furnaces are further classified by the firing position of  the
 burners, i. e.,  single (front or rear)  wall,  horizontalljr opposed, vertical,
  tangential (corner fired),  turbo or arch  fired.          !

      Cyclone furnaces burn low ash fusion  temperature coal  crushed to  a 4  mesh
 size.  The coal  is fed tangentially,  with  primary  air,  to a horizontal  cylin-
 drical combustion chamber.   In this  chamber,  small  coal  particles  are  burned
 in suspension,.while the larger  particles  are forced  against  the outer wall.
 Because of the high temperatures  developed in the  relatively  small furnace
 volume,  and because of the  low fusion temperature  of  the  coal  ash, much of the
 ash forms  a liquid slag which is  drained from the  bottom  of the furnace through
 a slag tap opening.   Cyclone  furnaces are  used mostly  in jutility and large
 industrial  applications.
•
  ,    In spreader  stokers, a flipping mechanism  throws  the coal  into the furnace
 and onto a moving fuel  bed.   Combustion occurs partly  in suspension and  partly
 on the grate.  Because of significant carbon  in  the particulate, flyash rein-
 jection from mechanical  collectors is commonly employed to  improve boiler
 efficiency. Ash  residue in the fuel bed is deposited in a  receiving pit at the
 end of the  grate.                                        I
 9/88
External Combustion Sources
                                                                          1.1-1

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     9/88

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     In overfeed stokers, coal is fed onto a traveling or vibrating  grate,  and
it burns on the fuel bed as it progresses through the furnace.   Ash  particles
fall into an ash pit at the rear of the stoker.   The term "overfeed   applies
because the coal is fed onto the moving grate under an adjustable gate.   Con-
versely, in "underfeed" stokers, coal is fed into the firing zone from under-
neath by mechanical rams or screw conveyers.  The coal moves in a channel,
known as a retort, from which it is forced upward, spilling over the top of
each side to form and to feed the fuel bed.  Combustion is completed by the
time the bed reaches the side dump grates from which the ash is discharged  to
shallow pits.  Underfeed stokers include single retort units and multiple
retort units, the latter having several retorts side by side.

1.1.2  Emissions And Controls

     The major pollutants of concern from external coal combustion are partic-
ulate, sulfur oxides and nitrogen oxides.  Some unburnt combustibles,, including
numerous organic compounds and  carbon monoxide, are generally emitted even
under proper boiler operating conditions.

     Particulate2-4 - Particulate composition and emission levels are a complex
function of  firing  configuration, boiler operation and coal properties.  Tn
pulverized coal systems, combustion  is  almost complete, and thus participate
largely comprises  inorganic  ash residue.   Tn wet bottom pulverized  coal units
and cyclones,  the  quantity of ash leaving  the boiler  is less than in dry bottom
units,  since some  of  the ash liquifies,  collects  on  the  furnace  walls, and
drains  from  the furnace bottom  as molten slag.   To  increase the  fraction of ash
drawn  off  as wet  slag,  and  thus to  reduce  the flyash  disposal problem, flyash
may be relnjected  from collection  equipment  into slag tap  systems.  Dry bottom
unit ash may also-be  reinjected into wet bottom  boilers  for  the  same purpose.

     Because a mixture of  fine  and  coarse  coal particles  is  fired in spreader
 stokers,  significant  unburnt carbon can be present  in the particulate.   To
 improve boiler efficiency,  flyash  from collection devices  (typically multiple
 cyclones)  is sometimes reinjected  into spreader  stoker furnaces. This  prac-
 tice can  dramatically increase  the particulate loading at the boiler outlet
 and, to a lesser extent, at  the mechanical collector outlet.   Flyash  can also
 be reinjected from the boiler,  air heater and  economizer dust hoppers,   Flyash
 reinjection from these hoppers  does not increase particulate loadings  nearly  so
 much as from multiple cyclones.5
                               n.
      Uncontrolled overfeed and  underfeed stokers emit considerably  less  particu-
 late than do pulverized coal units and spreader  stokers, since combustion  takes
 place in a relatively quiescent fuel bed.   Flyash reinjection  is not  practiced
 In these kinds of stokers.

      Other variables than firing configuration and flyash reinjection can
 affect emissions from stokers.   Particulate loadings will often increase as
 load increases (especially as full load is approached) and with sudden load
 changes.   Similarly, particulate can increase as the ash and fines  contents
 increase.  ("Fines", in this context, are coal particles smaller than about  1.6
 millimeters, or one sixteenth inch, in diameter.)  Conversely, particulate can
 be reduced significantly when overfire air pressures are increased.-^
  1.1-4
                                 EMISSION FACTORS
9/88

-------
      The primary kinds  of  parttculate  control devices  used  for coal combustion
!include multiple cyclones,  electrostatic  precipitators,  fabric filters (bag-
|houses) and  scrubbers.   Some measure of control will even result  from ash
 settling in  boiler/air  heater/economizer  dust hoppers, large breeches and chim-
 ney bases.   To the  extent  possible  from the  existing data base, the effects of
 such settling  are reflected in the  emission  factors in Table 1.1-1.

      Electrostatic  precipitators  (ESP) are the most common  high efficiency
;control device used on  pulverized coal and cyclone units, and they are being
 used increasingly on stokers.   Generally, ESP collection efficiencies are a
 function of  collection  plate area per  volumetric  flow  rate  of flue gas through
 the device.  Participate control  efficiencies of  99.9  weight percent are
;obtainable with ESPs.   Fabric  filters  have recently seen Increased use in both
 utility and  industrial  applications, generally effecting about 99.8 percent
 efficiency.  An advantage  of fabric filters  Is that they are unaffected by high
 flyash  resistivities associated with low  sulfur coals. !  ESPs located after air
Ipreheaters (i.  e.,  cold side precipitators)  may operate  at  significantly reduced
 efficiencies when low sulfur coal is fired.  Scrubbers are  also used to control
.partlculate, although their primary use Is to control  sulfur oxides.  One draw-
back of scrubbers is the high  energy requirement  to achieve control efficiencies
icomparable to  those of  ESPs  and baghouses.2

     Mechanical  collectors,  generally multiple cyclones, are the primary means
 of  control on  many  stokers  and  are  sometimes installed upsteam of high effi-
 ciency  control  devices  in order to  reduce the ash colleption burden.  Depending
on  application and  design,  multiple cyclone  efficiencies can vary tremendously.
Where cyclone  design flow rates are not attained  (which  is  common with under-
feed and  overfeed stokers),  these devices may be  only marginally effective and
may prove little better in  reducing particulate than large  breeching.   Con-
versely,  well  designed  multiple cyclones, operating at the  required flow rates,
can achieve collection  efficiencies on spreader stokers  and overfeed stokers
of  90 to  95 percent.  Even  higher collection efficiencies are obtainable on
Spreader  stokers with reinjected flyash, because of the  larger particle sizes
and increased  parttculate loading reaching the controls.5-6
                                                       I
                                                       I
(    Sulfur Oxldes7~9 - Gaseous sulfur oxides from external  coal  combustion
are largely sulfur  dioxide  (S02) and much less quantity of  sulfur trloxide
(803) and gaseous sulfates.  These  compounds form as the organic and pyritic
^ulfur  in the  coal  is oxidized during the combustion process.   On average,  98
percent of the  sulfur present in bituminous coal  will  be emitted  as gaseous
sulfur  oxides, whereas  somewhat less will be emitted when subbitumlnous  coal
is  fired.  The more  alkaline nature of the ash in some subbituminous coal
causes  some of  the  sulfur to react  to form various sulfate salts  that  are
retained  in the boiler  or in the flyash.  Generally,  boiler size,  firing  con-
figuration and boiler operations have little effect on the percent conversion
of  fuel sulfur  to sulfur oxides.

!     Several techniques are used to reduce sulfur oxides from  coal combustion.
One way is to switch to lower sulfur coals,  since sulfur oxide  emissions  are
proportional to the  sulfur content of the coal.   This  alternative may  not be
possible where lower sulfur coal is  not readily  available or where a different
grade of  coal can not be satisfactorily fired.   In some cases, various cleaning
processes may be employed to reduce the fuel  sulfur content. Physical coal
cleaning  removes mineral sulfur such as pyrite but is  not effective in removing

9/88                      External.Combustion Sources                     1.1-5

-------
 organic sulfur.  Chemical cleaning and solvent refining processes are being
 developed to remove organic sulfur.

      Many flue gas desulfurization techniques can remove sulfur oxides formed
 during combustion.  Flue gases can be treated through wet, semidry or dry
 desulfurization processes of either the throwaway type, in which all waste
 streams are discarded, or the recovery (regenerable) type, in which the SOX
 absorbent is regenerated and reused.  To date, wet systems are the most com-
 monly applied.  Wet systems generally use alkali slurries as the SO* absorbent
 medium and can be designed to remove well in excess of 90 percent of the in-
 coming SOjj.  Particulate reduction of up to 99 percent is also possible with
 wet scrubbers, but flyash is often collected by upsteam ESPs or baghouses, to
 avoid erosion of the desulfurization equipment and possible interference with
 the process reactions.7  Also, the volume of scrubber sludge is reduced with
 separate flyash removal, and contamination of the reagents and byproducts is
 prevented.  References 7 and 8 give more details on scrubbing and other SOX
 removal techniques.

      Nitrogen Oxides 10~1]- - Nitrogen oxides (NOX) emissions from coal
 combustion are primarily nitrogen oxide (NO).  Only a few volume percent are
 nitrogen dioxide '(N02).  NO results from thermal fixation of atmospheric nitro-
 gen in the combustion flame and  from oxidation of nitrogen bound in the coal.
 Typically, only 20 to 60 percent of the fuel nitrogen is converted to nitrogen
 oxides.  Bituminous and subbituminous coals usually contain from 0.5 to 2
 weight percent nitrogen, present mainly in aromatic ring structures.  Fuel
 nitrogen can account for up to 80 percent of total NOx from coal combustion.
       A number of combustion modifications  can be made to  reduce  NOX  emissions
  from boilers.  Low excess  air (LEA)  firing is the most widespread  control
  modification, because it can 'be practiced  in both old and new units  and  in  all
  sizes of boilers.   LEA firing is easy to implement  and has the added advantage
  of increasing fuel use efficiency.   LEA firing is generally effective only
  above 20 percent excess air for pulverized coal units and above  30 percent
  excess air for stokers.  Below these levels, the NOx reduction from  decreased 02
  availability is offset by increased  NOX because of  "increased flame temperature.
  Another NOX reduction technique is simply  to switch to a  coal having a lower
  nitrogen content,  although many boilers may not properly  fire coals  of different
  properties.

       Off-stoichiometric (staged) combustion is also an effective means of
  controlling NOX from coal  fired equipment.  This can be achieved by  using
  overfire air or low NOx burners designed to stage combustion in  the  flame zone.
  Other NOx reduction techniques include flue gas recirculation, load  reduction,
  and steam or water injection.  However, these techniques  are not very effective
  for use on coal fired equipment because of the fuel nitrogen effect.  Ammonia
  injection is' another technique which can be used, but it  is costly.   The net
  reduction of NOX from any of these techniques or combinations thereof varies
  considerably with boiler type, coal  properties and  existing operating practices.
  Typical reductions will range from 10 to 60 percent.  References 10  and  60
  should be consulted for a detailed discussion of each of  these NO^. reduction
  techniques.  To date, flue gas treatment is not used to reduce nitrogen  oxide
  emissions because of its h'ighe.r cost.
1.1-6
                                 EMISSION FACTORS
9/88

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                                                                                         I
     Volatile Organic Compounds And Carbon Monoxide - Volatile organic compounds
(VOC) and carbon monoxide (CO)'are unburnt gaseous combustibles which generally
are emitted in quite small amounts.  However, during startups, temporary upsets
or other conditions preventing complete combustion, unburnt combustible emis-
si,ons may increase dramatically.  VOC and CO emissions per unit of fuel fired
are normally lower from pulverized coal or cyclone furnaces than from smaller
stokers and handfired units where operating conditions are not so well con-
trplled.  Measures used for NOX control can increase CO emissions, so to reduce
the risk of explosion, such measures are applied only to the point at which CO
in the flue gas reaches a maximum of about 200 parts per million.  Other than
maintaining proper combustion conditions,, control measures are not applied to
control VOC and CO.

     Emission Factors And References - Emission factors for several pollutants
are presented in Table 1.1-1, and factor ratings and references are presented
in Table 1.1-2.  The factors for uncontrolled underfeed stokers and hand fired
units also may be applied to hot air furnaces.  Tables l,.l-3 through 1.1-8
present cumulative size distribution data and size specific emission factors
for particulate emissions from the combustion sources discussed above.  Uncon-
trolled and controlled size specific emission factors 'are presented in Figures
1.1-1 through 1.1-6.                                      ,
                         External Combustion Sources
                                                                         1.1-7

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TABLE 1.1-3.   CUMULATIVE PARTICLE SIZE DISTRIBUTION AND  SIZE  SPECIFIC EMISSION

       FACTORS  FOR DRY BOTTOM BOILERS BURNING PULVERIZED  BITUMINOUS  COALa
                     EMISSION FACTOR RATING:
                                         C (uncontrolled)

                                         D (scrubber and ESP controlled

                                         E (multiple cyclone and  baghouse)


    O Jf
2.0A



1.8A




1.6A



1.4A




1.2A



l.OA




0.8A



0.6A




0.4A



0.2A



0
       Scrubber
ESP
                    '   i  I  i 1
                Baghouse




        Uncontrolled





       -Multiple cyclone




i   i  i  i i  i i il     I	|—I I  I I I I
                                                                   l.OA
                                                                        0,2!.

                                                                   0.4A  §£
                                                                   0.2A  2
                                            •Q.1A
0.06A *

     o


0.04A o
     (O
     4-
                                                                    0.02A
                   .2    .4  .6  1     2     4    6   10



                                 Particle diameter (urn)
                                                      20    40 60 100
                                                                    0.01A
0.1A




0.06 A



0.04A






.0.02A






,0.01A





0.006A



0.004A






0.002A






0.001A
     Figure 1.1-1.   Cumulative  size specific emission  factors  for dry bottom

                       boilers burning pulverized bituminous coal.
1.1-8
                                      EMISSION  FACTORS
                                                                                           9788

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                                                                                                  I
 TABLE 1.1-4.
CUMULATIVE PARTICLE SIZE DISTRIBUTION AND SIZE  SPECIFIC  EMISSION

FACTORS FOR WET  BOTTOM BOILERS BURNING PULVERIZED BITUMINOUS COAL3


             EMISSION FACTOR RATING:   E    i

(lira)

' 15
10
6
2.5
1.25
1.00
0.625
TOTAL
Cumulative mass % < stated size
Uncontrolled

40
37
33
21
6
4
2
100
Controlled
Multiple
cyclone
99
93
: 84
61
31
19
e
100
ESP
83
75
63
40
17
8
e
100
Cumulative emission factor0 [kg,
Uncontrolled

1.4A (2.8A)
1.30A (2.6A)
1.16A (2.32A)
0.74A (1.48A)
0.21A (0.42A)
0.14A (0.28A)
0.07A (0.14A)
3. 5 A (7.0A)
Mg (Ib/ton) coal, as fired]
Controlled11
Multiple cyclone
0.69A (1.38A)
0.65A (1.3A)
0.59A (1.18A)
0.43A (0.86A)
0.22A (0.44A)
0.13A. (0.26A)
e
0.7A (1.4A)
•"Reference 61. ESP - electrostatic preclpltator. 	
"Expressed as aerodynamic equivalent diameter.
=A = coal ash weight Z, as fired.
Estimated control efficiency for multiple cyclone, 803!- ESP 99. 22
elnsufflclent data.








ESP
0.023A (0.046A)
0.021A (0.042A)
0.018A (0.036A)
0.011A (0.022A)
0.005A (0.01A)
0.002A (0.004A)
e
0.028A <0.056A)



    OJ to
         3.bA
         Z.BA
         2.1A
         1.4A
        0.70A -
                           Multiple

                           cyclone
                _]	1_
                                            Uncontrolled
                      • 4  .6  1    246     10

                               Particle diameter dun)
                                                  I   I  I
 l.OA


0.9A °
    u
!    ro

0.8A ^



0.7A



 3.6A


0.5A


0.4A



0. 3A




0.2A


6.1 A


 0
                                 20
                                     40' 60 100
                                                          .1A




                                                          -06A




                                                          .04A


                                                          .02A
                                                                          0.01A
                                                                          -006A


                                                                          .004A
    Figure 1.1-2.   Cumulative size  specific emission factors for

                    boilers  burning  pulverized bituminous  coal
                                                                         0.002A
                                                                         0.001A
                                                     wet bottom
9/88
          External Combustion Sources
                                                                                1.1-9

-------
TABLE 1.1-5.
CUMULATIVE PARTICLE  SIZE  DISTRIBUTION AND  SIZE  SPECIFIC EMISSION
 FACTORS  FOR CYCLONE FURNACES BURNING BITUMINOUS  COALa

               EMISSION FACTOR RATING:   E

Particle size'5
(no)


15
10
6
2.5
1.25
1.00
0.625
TOTAL
Cumulative mass % <_ stated size


Uncontrolled

33
13
8
0
0
0
0
100

Controlled
Scrubber
95
94
93
92
85
82
d
100
ESP
90
68
56
36
22
17
d
100
Cumulative emission factor^ [kg/Mg (Ib/ton) coal, as fired]


Uncontrolled

0.33A (0.66A)
0.13A (0.26A)
0.08A (0.16A)
0 (0)
0 (0)
0 (0)
0 (0)
1A (2A)

Controlled6
Scrubber
0.057A (0.114A)
0.056A (0.112A)
0.056A (0.112A)
0.055A (0.11A)
0.051A (0.10A)
0.049A (0.10A)
d
0.06A (0.12A)
ESP
0.0064A (0.013A)
0.0054A (0.011A)
0.0045A (0.009A)
0.0029A (0.006A)
0.0018A (0.004A)
0.0014A (0.003A)
d
0.008A (0.016A)
     "Reference 61.  ESP - electrostatic preclpltator.
     ^Expressed ae aerodynamic equivalent diameter.
     CA - coal ash weight 2, as fired.
     dlnsufflclent data.
     cEntinated control efficiency for scrubber, 94%; ESP, 99.2%.
            *o en
 l.OA

 0.9A

 C.8A


 0.7A

 0.6A

 0.5A

 0.4A

 0.3A

 0.2A

 0.1A

 0
                                                 ESP-
                               I  i i  i i I
                                                             Uncontrolled
                                                             i   i   i i i i i i
0.10ft


0.06A


0.04A

0.02A


0.01A

0.006A

0.004A



0.002A
                                                                          0.001A
                     .1    .2    .4  .6   1    2     46    10
                                         Particle diameter (ym)
                                                             20    40 60  100
        Figure  1.1-3.
         Cumulative size specific emission  factors  for  cyclone
         furnaces burning bituminous  coal
 1.1-10
                                       EMISSION  FACTORS
                                                                                        9/88

-------
  TABLE 1.1-6.
CUMULATIVE  PARTICLE SIZE  DISTRIBUTION AND SIZE SPECIFIC EMISSION
FACTORS FOR SPREADER STOKERS BURNING BITUMINOUS GOAL3
                EMISSION FACTOR  RATING:
                           C (uncontrolled  ;and controlled  for
                              multiple cyclone without flyash
                              reinjection,  and with baghouse)
                           E (multiple cyclone controlled  with
                              flyash reinjection, and ESP
                              controlled)
Particle size1"


15
10
6
2.5

1.25

1.00
0.625
TOTAL
Cumulative mass X < stated size
Uncontrolled

28
20
14
7

, 5

5
4
100
Controlled
Multiple
cyclonec
86
73
51
8

2

2
'
100
Multiple
cyclone^
74
65
52
27

16

14
9
100
ESP
97
90
82
61

46

41
e
100
Baghouse
72
60
46
26

IB

15
1
100

Uncontrolled

8.4
(16.8)
6.0
(12.0)
4.2
(8.4)
2.1
(4.2)
1.5
(3.0)
1.5
(3.0)
1.2
(2.4)
30.0
(60.0)
[kg/Kg (Ib/ton) coal, as fired]
Controlled
Multiple
cyclonec
7.3
(14.6)
6.2
(12.4)
i,3
(8.6)
0.7
(1.4)
0.2
(0,4)
0.2
(0.4)
0.1
(0.2)
8.5
17.0)
Multiple
cycl»ned
4.4
(8.8)

3.9
(7.8)
3.1
(6.2)
1.6
(3.2)
1.0
(2.0)
0.8
(1.6)
0.5
(1.0)
6.0
12.0)
'Expressed aa aerodynaralc equivalent dlaaeter.
=Wlth flyaoh reinjection.
"Without flyash reinjection.
fEntfoated control efficiency for ESP, 99.2Zj baghouse, 99. 8Z.








ESP
0.23
(0.46)
0.22
(0.44)
0.20
(0.40)
0.15
(0.30)
0.11
(0.22)
0.10
(0.20)
e
0.24 £
(0.48)
Baghouse
0.043
(0.086)
0.036
(0.072)
0.028
(0.056)

(0.032)

(0.022)
0.009
(0.018)
0.004
(0.008)
0.06'
(0.12)




                                                              10.0
     •o «
     ^ 8
                         Multiple cyclone with
                         flyash reinjection
                  Multiple cyclone without
                  flyash reinjection
                                                            T 0.2
                                                            U 0.1
                                                        0.10

                                                        0.06

                                                        0.04


                                                        0.02.


                                                        0.01.

                                                        0.006

                                                        0.004


                                                        0.002


                                                        0.001
                             1     2    4  6   10
                               Particle diameter (urn)
      Figure  1.1-4.   Cumulative  size specific  emission factors  for spreader
                      stokers burning bituminous  coal
9/88
          External Combustion Sources
                                                                              1.1-11

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TABLE  1.1-7.
CUMULATIVE PARTICLE SIZE DISTRIBUTION AND SIZE SPECIFIC EMISSION
FACTORS FOR  OVERFEED  STOKERS  BURNING  BITUMINOUS COAL3


EMISSION FACTOR RATING:   C  (uncontrolled)
                            E  (multiple  cyclone' controlled;

(lira)
15
10
6
2.5
1.25
1.00

0.625
TOTAL

Cumulative mass % <. stated size
Uncontrolled
» — ^— — — — — —
49
37
24
14
13
12

c
100

Multiple cyclone
controlled
60
55
49
43
39
39

16
100
Cumulative emission factor
[kg/Mg (Ib/ton) coal, as ftred]
Uncontrolled
3.9 (7.8)
3.0 (6.0)
1.9 (3.8)
1.1 (2.2)
1.0 (2.0)
1.0 (2.0)


8.0 (16.0)
Multiple cyclone
controlled''
2.7 (5.4)
2.5 (5.0)
2.2 (4.4)
1.9 (3.8)
1.8 (3.6)
1.8 (3.6)
0.7 (1,4)

4.5 (9.0)

        "Reference 61.
        bExprc38cd as aerodynamic equivalent diameter.
        cinsufficient data.                           „
        dEstimated control efficiency for multiple cyclone, 80/..
            1,-r
            T3§
            at o
            ^ en

8


7.2


6.4

5.6



4.0


 3.2




 1.6

 0.8

  0
                                           Multiple
                                           cyclone
                                             I  11
                                                   UL
                         .2
                              .4  .6
                     1    Z    4   6  10

                      Particle diameter (urn)
                                                          20
                                                       6.0

                                                       4.0



                                                       2.0



                                                       1.0

                                                       0.6

                                                       0.4
                                                                       0.1
                                                               40 60 100
O (O
L- O
4-* U
C
O en
o z

(U C7)
C -*
                                                                           O I-
                                                                           ss
                                                                       0.2  -;E.S
       Figure  1.1-5.   Cumulative size  specific  emission factors  for
                        stokers burning  bituminous coal
                                                           overfeed
 1.1-12
                                     EMISSION  FACTORS
                                                                                     9/88

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                                                                                             1
 TABLE  1.1-8.   CUMULATIVE  PARTICLE SIZE DISTRIBUTION AND SIZE  SPECIFIC EMISSION

 ;               FACTORS FOR UNDERFEED STOKERS  BURNING BITUMINOUS  COAL*



                            EMISSION FACTOR RATING:   C
Particle size*5

-------
References for Section 1.1

1.   Steam, 38th Edition, Babcock and Wilcox, New York, 1975.

2    Control Techniques for Particulate Emissions from Stationary Sources,
     Volume I, EPA-450/3-8l-005a, U. S. Environmental Protection Agency,
     Research Triangle Park, NC, April 1981.
3.
5.
     ibidem, Volume II.  EPA-450/3-8l-0005b.

     Electric  Utility Steam Generating  Units;   Background  Information for
     Proposed  Particulate Matter  Emission Standard,  EPA-450/2-78-006a,  U.  S.
     Environmental  Protection Agency, Research Triangle Park,  NC,  July 1973.

     W.  Axtman and  M. A. Eleniewski,  "Field  Test Results of Eighteen Industrial
     Coal  Stoker Fired Boilers for Emission  Control  and Improved Efficiency ,
     Presented at the 74th Annual Meeting of the Air Pollution Control Asso-
     ciation,  Philadelphia, PA, June 1981.

6    Field Tasts of Industrial Stoker Coal Fired Boilers for Emission Control
     and Efficiency Improvement - Sites Ll-17, EPA-600/7-81-020a, U. S. Environ-
     mental Protection Agency, Washington, DC, February 1981.

7.   Control Techniques for Sulfur Dioxide Emissions from Stationary Sources,
     2nd Edition, EPA-450/3-81-004, Uo  S. Environmental Protection Agency,
     Research Triangle Park, NC, April  1981.

8    Electric Utility Steam Generating Units:  Background Information for
 *   Proposed SO? Emission Standards, EPA-450/2-78-007a, U. S. Environmental
     Protection Agency, Research Triangle Park, NC, July 1978.
     Environmental Protection  Agency, Washington, DC, February 1981.

9.   Carlo Castaldini and Meredith Angwin, Boiler Design and Operating Vari-
     ables Affecting Uncontrolled Sulfur  Emissions  from Pulverized  Coal Fired
     Steam Generators,  EPA-450/3-77-047,  U. S. Environmental Protection Agency,
     Research Triangle  Park,  NC, December 1977.

     Control Techniques  for  Nitrogen Oxides Emissions  from  Stationary  Sources,
     2nd  Edition,  EPA-450/1-78-001, U. S. Environmental Protection  Agency,
     Research Triangle  Park,  NC, January  1978.

     Review of  NCy Emission  Factors for  Stationary  Fossil  Fuel  Combustion
     Sources, EPA-450/4-79-021,  U.  S.  Environmental Protection  Agency,
     Research Triangle  Park,  NC,  September  1979.

 12.  Standards  of  Performance for  New  Stationary Sources,  36  FR 24876,  December
     23,  1971.

 13  L. Scinto, Primary Sulfate  Emissions from Coal and Oil Combustion, EPA
     Contract Number 68-02-3138, TRW Inc.,  Redondo  Beach,  CA,  February 1980.

 14.   S. T. Cuffe and R. W. Gerstele, Emissions from Coal  Fired Power Plants:
     A Comprehensive Summary. 999-AP-35, U. S. Environmental  Protection Agency,
     Research Triangle Park, NC, 1967.
                                                                           9/88
 10.
 11.
  1.1-14
                                  EMISSION FACTORS

-------
  15>  5leld Testing:   Application of Combustion Modifications To Control NO,
    :   Emissions from Utility Boilers, EPA-b50/2-M-U66,  U.  S. Environmental
    ,   Protection Agency,  Washington, DC,  June 1974.
27.
28.
29.
  16*   •f?°tr,°1 .?5,Ptility B°iler and  Gas Turbine Pollutant  Emissions  by Combus-
    ,   tion Modificatiua .  lha.e 1, EPA-bUU/>-;8-U36a,  U. S.  Environmental	
       Protection Agency,  Washington,  DC,  March 1978.       j

  17*   Low-sulfur Western Coal Use in Existing  Small and Intermediate Size
       Boilers, EPA-600/7-78-153a, U.  S.  Environmental  Protection Agency '
       Washington, DC, July 1978.                           [      "Seit-y>

  18*   Hazardous  Emission Characterization of Utility Boilers. EPA-650/2-75-066
       U. S. Environmental  Protection  Agency, Washington, DC7 July 1975.

  19i   Application of Combustion Modifications  To Control Pollutant Emissions
    ;   p^^°fust^lal B°1T1Terf.~ Phase I»  EPA-650/2-74-078a, U. S. Environmental
       Protection Agency, Washington,  DC,  October 1974.
                                                           I             ,

 20*   ^-StgT TL°^?ln^— El^^t Mass Balances at a Coal Fired-Utility
                                                    Protection Agency,  Washing-
      Environmental Assessment of Coal and Oil Firing in a Controlled industrial
      Boiler, Volume II, EPA-600/7-78-164b, U. S. Environmental Protection -
      Agency, Washington, DC, August 1978.
 22.
 23.
 24.
 25. ;
 Coal  Fired Power Plant Trace Element
 Agency,  Denver,  CO,  September 1975.
                                                ,  u.  S.  Environmental  Protection
 Source Testing  of  puke Power Company.  Plezer  SC   EMB--71-CI-01   US
 Environmental Protection Agency,  Research  Triangle Park, NC,  February  1971.

 J. W.  Kaakinen,  et al.,  "Trace Element Behavior in Coal-fired Power Plants"
 Environmental Science  and Technology.  £(9) :862-869, September 1975.

 !!!!/i!ld Pefformance Tests  o° Koppers Company Precipitators. Docket No.
 OAQPS-78-1, Office Of  Air Quality Planning And Standards, U. S. Environ-
mental Protection  Agency, Research Triangle  Park,  NC, February-March 1974.
26. :
Pow         P                > Sla§ TaP Bol^r Performa^P. Associated with
Power Plant Flyash Disposal, Western Electric Company, Hawthorne Works,
Cnicago, IL, undated.                                •  .

A. B. Walker, "Emission Characteristics for Industrial Boilers"  Air
Engineering, 1(8): 17-19, August 1967.                          ' ^^
   un              °f Coal-fired Controlled Utility Boiler.  EPA-600/
7-80-086, U. S. Environmental Protection Agency, Washington,  DC, April


Steam> 37th Edition,  Babcock and Wilcox,  New York,  1963.
9/88
                          External Combustion Sources
                                                                          1.1-15

-------
30.  Industrial Boiler;  Emission Test Report, Formica Corporation, Cincinnati,
     Ohio, EMB-80-IBR-7, U. S. Environmental Protection Agency, Research Triangle
     Park, NC, October 1980.

31.  Field Tests of Industrial Stoker Coal-fired Boilers for Emissions) Control
     and Efficiency Improvement - Site A, EPA-600/7-78-135a, U. S.  Environ-
     mental Protection Agency, Washington, DC, July 1978.

32.  ibidem-Site C, EPA-600/7-79-130a, May 1979.           .

33.  ibidem-Site E, EPA-600/7-80-064a, March 1980.

34.  ibidem-Site F, EPA-600/7-80-065a, March 1980.

35.  ibidem-Site G, EPA-600/7-80-082a, April 1980.

36.  ibidem-Site B, EPA-600/7-79-04la, February 1979.

37.  Industrial Boilers;  Emission Test Report. General Motors Corporation,
     Parma. Ohio, Volume I, EMB-80-IBR-4, U. S. Environmental Protection Agency,
     Research  Triangle Park,  NC, March 1980.

38.  A Field Test Using Coal;  dRDF Blends in Spreader Stoker-fired Boilers,
     EPA-600/2-80-095, U. S.  Environmental Protection Agency, Cincinnati * OH*
     August 1980.

39.  Industrial Boilers:  Emission Test Report, Rickenbacker Air  Force Base,
     Columbus, Ohio, EMB-80-IBR-6, U. S.  Environmental Protection Agency,
     Research  Triangle Park,  NC, March 1980.

40.  Thirty-day Field  Tests of Industrial Boilers;   Site  1, EPA-600/7-80~085a,
     U.  S. Environmental Protection Agency, Washington, DC, April  1980.

41.  Field Tests  of  Industrial Stoker Coal-fired  Boilers  for Emissions Control
     and Efficiency  Improvement  - Site D, EPA-600/7-79-237a, U. S. Environmental
     Protection Agency, Washington, DC,  November  1979.

42.  ibidem-Site  H,  EPA-600/7-80-112a, May  1980.

43.  ibidem-Site  I,  EPA-600/7-80-136a, May  1980.

44.  ibidem-Site  J,  EPA-600/7-80-137a, May  1980.

45.  ibidem-Site  K,  EPA-600/7-8Q-138a, May  1980.

46.  Regional  Air Pollution Study;   Point Source  Emission Inventory,  EPA-600/4-
     77-014,  U. S. Environmental Protection Agency, Research  Triangle Patk, NC*
     March 1977.

47.  R.  P. Hangebrauck,  et al.,  "Emissions  of Polynuclear Hydrocarbons and
      Other Pollutants from Heat  Generation and Incineration Process", Joutnal
      of the Air Pollution Control Association,  ^4(7):267-273,  July 1964.
 1.1-16
                                 EMISSION FACTORS
                                                                            9/88

-------
 49.
 50.
51.
52.
       Source Assessment:   Coal-fired Industrial  Combustion Equipment  Field  Test.
       EPA-600/2-78-004o,  U.  S.  Environmental  Protection Agency,  Washington   DC~'
       June 1978.                                                            .   '
                    •
                                                           i .
       Source Sampling  Residential  Fireplaces  for Emission Factor Development.
       EPA-450/3-76-010, U.  S. Environmental Protection Agency, Research Triangle
       Park,  NC, November  1975.                             i                  B


       Atmospheric  Emissions  from Coal  Combustion;  An  Inventory-Guide. 999-AP-24,
       U.  S.  Environmental Protection Agency,  Washington,  DC, April 1966.

       Application  of Combustion Modification  To  Control  Pollutant Emissions  from
       Industrial Boilers - Phase II. EPA-600/2-76-086a,  U. S. Environmental -
       Protection Agency, Washington, DC, April 1976.

       Continuous Emission Monitoring for Industrial Boiler! General Motors Cor-
       poration, St. Louis, Missouri, Volume I. EPA Contract Number 68-02-2687
       GCA Corporation, Bedford, MA, June 1980.                               '
 53 '  Survey of Flue Gas Desulfurization Systems;  Cholla £ tation, Arizona
54.
                                                                 ,
      Public Service Company. EPA-600/7-78-048a, U. S. Environmental Protection
      Agency, Washington, DC, March 1978.   v»
                                                '           I          '
      ibidem:  La Cygne Station, Kansas City Power and Light, EPA-600/7-78-048d
      March 1978.                                      ~^~                   '
 56.
 57 j
 58.
 59.'
 60.,
 61.
55r  Source Assessment;   Dry Bottom^Utility Boilers Firing Pulverized Bituminous
  !   Coal, EPA-600/2-79-019, U. S. Environmental Protection Agency,  Washington
     DC, August 1980.                                                         '
                               i

     Thirty-day Field Tests of Industrial Boilers;   Site 3- Pulverized  - Coal
     Fired Boiler,  EPA-600/7-80-085c,  U.  S. Environmental Protection Agency	
     Washington, DC,  April  1980.                           ,,                 '


    •Systematic Field Study of Nitrogen Oxide Emission Control Methods for
     Utility Boilers, APTD-1163,  U.  S.  Environmental  Protection  Agency,  Research
     Triangle Park,  NC,  December  1971.


     Emissions of Reactive  Volatile  Organic Compounds  from Utility Boilers.
     EPA-600/7-80-111, U. S.  Environmental  Protection  Agency, WashingtonDC
     May 1980.                                       '  "   i    '


     Industrial  Boilers;  Emission Test Report,  DuPont  Corporation   Parkers-
     burg,  West  Virginia. EMB-80-IBR-12,  U.  S. Environmental Protection  Agency
     Research Triangle Park,  NC,  February 1982.

     Technology  Assessment  Report for Industrial Boiler Applications:.  NO
     Combustion  Modification.  EPA-600/7-79-178f, U. S.  Environmental Protection
     Agency,  Washington, DC,  December 1979.


     Inhalable Particulate  Source Category Report for External Comfeustion
     Sources, EPA Contract  No.  68-02-3156, Acurex Corporation, Mountain View
     CA, January  1985.                                                      '
9/88
                         External Combustion Sources
                                                                          1.1-17

-------

-------
 1.2  ANTHRACITE COAL COMBUSTION                              •

 1.2.1  General 1-2

    j  Anthracite coal is a high rank coal  with more fixed carbon and  less  vola-
 tile matter than either bituminous, coal  or lignite,  and  it  has  higher ignition
 and ash fusion temperatures.   Because of  its low volatile matter content  and
 slight clinkering,  anthracite is most commonly fired in  medium  sized traveling
 gra|te stokers and small hand  fired units.   Some anthracite  (occasionally  with
 petroleum coke)  is  used in pulverized coal  fired boilers.   It is  also blended
 with bituminous  coal.   None is fired in  spreader stokers.   For  its low sulfur
 content (typically  less than  0.8 weight percent) and minimal  smoking tendencies,
 anthracite is considered a desirable fuel  where readily  available.
                                                          I
    > ^In the United  States,  all anthracite  is mined in northeastern Pennsylvania
 and; is consumed  mostly in Pennsylvania and  several surrounding  states.  The
 largest use of anthracite is  for space heating.   Lesser  amounts are  employed
 for: steam/electric  production;  coke manufacturing, sintering and  pelletizing;
 and; other industrial uses.  Anthracite currently is  only a  small  fraction of
 the! total quantity  of  coal  combusted in the United States.!
                                                          i
 1.2*2   Emissions  And -Controls2--14

      Partlculate  emissions  from anthracite  combustion are a'function of furnace
 firing configuration,  firing  practices (boiler  load,  quantity and location of
 underfire air, sootblowing, flyash  reinjection,  etc.), and  the ash content of
 the  coal.   Pulverized  coal  fired boilers emit  the highest quantity of partic-
 ulate  per unit of fuel  because they  fire the  anthracite  in suspension, which
 results  in a  high percentage  of  ash  carryover into exhaust gases.  Pulverized
 anthracite fired boilers  operate in  the dry  tap  or dry bottom mode, because of
 anthracite's  characteristically high ash fusion  temperature.  Traveling grate
 stokers  and hand  fired  units  produce much less particulate per unit of fuel
 fired, because combustion takes place in a quiescent fuel bed without signifi-
 cant ash carryover into  the exhaust gases.  In general, particulate emissions
 from traveling grate stokers will increase during sootblowing and flyash rein-
jection  and with higher fuel bed underfeed air from forced draft fans.  Smoking
 is rarely  a problem, because of anthracite's low volatile matter content.

    | Limited data are available on the emission of gaseous pollutants from
 anthracite combustion.   It is  assumed from, bituminous coal combustion data that
a large  fraction of the fuel sulfur is emitted as sulfur oxides.  Also, because
combustion equipment, excess air rates, combustion temperatures, etc., are
similar between anthracite and bituminous coal combustion, nitrogen o^ide  and
carbon monoxide emissions are  assumed to  be similar,  too.  Volatile organic
compound (VOC) emissions, however, are expected to be considerably lower,
since the volatile matter content of anthracite is significantly less than that
of bituminous coal.
9/88
External Combustion Sources
                                                                          1.2-1

-------
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-------
       Controls  on  anthracite emissions mainly have been applied to particulate
 matter.  The most efficient particulate controls, fabric filters, scrubbers and
 electrostatic  precipitators, have been installed on large pulverized anthracite
 fired boilers.  Fabric filters and venturi scrubbers can effect collection
 efficiencies exceeding 99 percent.  Electrostatic precipitators typically are
 only 90 to 97  percent efficient, because of the characteristic high resistivity
 of low sulfur  anthracite fly ash.  It is reported that higher efficiencies can
 be achieved using larger precipitators and flue gas conditioning.  Mechanical
 collectors are frequently employed upstream from these devices for large part-
 icle removal.                                                         &  v
                                                           I
    I                                                       [
      Traveling grate stokers are often uncontrolled.   Indeed,  particulate
 control has often been considered unnecessary,  because of anthracite's low smok-
 ing tendencies and of the fact that a significant fraction of  large size flyash
 from stokers is readily collected in flyash hoppers as well  as in the breeching
 and base of the stack.  Cyclone collectors have been employed  on traveling
 grate stokers,  and limited information suggests these devices  may be up to 75
 percent efficient on particulate.  Flyash reinjection,  frequently used in
 traveling grate stokers to enhance fuel  use efficiency,  terids  to  increase
 particulate emissions per unit of fuel combusted.

    ,  Emission factors for pollutants  from anthracite  coal  combustion are  given
 in Table 1.2-1, and  factor ratings  in Table 1.2-2.  Cumulative size  distribution
 data_and size specific emission factors  and ratings for particulate  emissions
 are in Tables 1.2-3  and 1.2-4.   Uncontrolled and  controlled  size  specific emis-
 sion  factors  are presented in  Figures  1.2-1 and 1.2-2.  Size distribution data
 for bituminous  coal  'combustion may  be  used  for  uncontrolled  emissions  from
 pulverized  anthracite fired furnaces,  and data  for anthracite  fired  traveling
 grate stokers may :be used for  hand  fired  units.
             TABLE"1.2-2.  ANTHRACITE COAL EMISSION FACTOR iRATINGS

Furnace type
I
Pulverized coal •
.Traveling grate
stoker
Hand fired units

Particulate
B

B
B

Sulfur
oxides
B

B
B

Nitrogen
oxides
B

B
B

Carbon
monoxide
B

B
B
.
Volatile organics
Nonmethane
C

C
D
Methane
C

C
D
9/88 .
External Combustion Sources
                                                                         1.2-3

-------
    TABLE  1.2-3.   CUMULATIVE PARTICLE SIZE DISTRIBUTION AND  SIZE  SPECIFIC

            EMISSION FACTORS FOR DRY  BOTTOM BOILERS  BURNING PULVERIZED

                                     ANTHRACITE COALa



                               EMISSION  FACTOR RATING:   D


Pur tide olccb
/it-1

IS
10
6
2.5
1.25
1.00
0.625
TOTAL

emulative mass X £ stated size
Uncontrolled

32
23
17
6
2
2
1
100
Controlled
Multiple cyclone
63
55
46
24
13
10
7
100
Baghouse
79
67
51
32
21
18

100
Cumulative emission factorc
[kg/Mg (Ib/ton) bark, as fired)
Uncontrolled

1.6A C3.2A)
1.2A (2.3A)
0.9A (1.7A)
0.3A (0.6A)
0.1A (0.2A)
0.1A (0.2A)
0.05A (0.1A)
5A (10A)
Controlled11
Multiple cyclone
0.63A (1.26A)
0.55A (1.10A)
0.46A (0.92A)
0.24A (0.48A)
0.13A (0.26A)
0.10A (0.20A)
0.07A (0.14A)
1A (2A)
Baghouse
0.0079A (0.016A)
0.0067A (0.013A)
0.0051A (0.010A)
0.0032A (0.006A)
0.0021A (0.004A)
0.0018A (0.004A)
e
0.01A (0.02A)
   •Reference 19.
   °Exprc«ied on aerodynralc equivalent diaaeter.

   CA - coul a»h weight, as fired.
   •lEitlMted control efficiency for nultlple cyclone, 80S.; baghouse, 99.8X.

   einiufflclent data.
          2.0A
           1.6A
      GTS  1.4A
       • -;  l.OA
       •a o

       5i  0.8A

       s€

       IS  0.6A

       S
       =   0.4A


           0.2A


             Q
                                    Baghouse
                             Multiple

                             cyclone
                      •Uncontrolled
              .1
.4  .6    1     2    4   6   10

          Particle diameter (|jin)
                                                       20
                                 J	I  I I I  I I
l.OA



0.9A


0.8A



0.7A


0.6A



0.5A


0.4A


0.3A


0.2A


0.1A
                                                  .
                                                |— Cft
                                                u ^
                                                             40  60  10'J
0.010A




0.009A

      a

0.008A  tj
      M-



0.007A  .llS
      VI S-


0.006A  !"*-
      QJ i/l
        ra


0.005A  2_"
      i—. to


0.004A  £ °
      c en
      O £


0.003A  oS1
      in —-


0.002A  1
      cn


0.001A ™



0
     Figure 1.2-1.   Cumulative size specific  emission  factors for dry  bottom

                       boilers burning pulverized anthracite coal.
1.2.-4
             EMISSION FACTORS
                                                                                          9/88

-------
              ;?*  CUMULATIVE PARTICLE SIZE. DISTRIBUTION AND SIZE SPECIFIC
              FACTORS FOR TRAVELING GRATE STOKERS BURNING ANTHRACITE

                            EMISSION FACTOR RATING:  E
Particle sizeb
/ .._ \
(urn)
15
10
6
2.5
1.25
1.00
0.625
TOTAL
aReference 19.
Cumulative mass %
<^ stated size
Uncontrolled0
64
52
42
27
24
23
d
100

Cumulative emission factor
[kg/Mg (Ib/ton) coal, as fired]
Uncontrolled
2.9 (5.8)
2.4 (4.8)
1.9 (3.8)
1.2 (2.4)
1.1 (2.2)
I
1.1 (2.2)
I
Q
4.6 (9.2)

      ^Expressed  as aerodynamic equivalent diameter.
       May also be used for uncontrolled hand fired units.
      Insufficient data.
                                     _L
                                 1     2    4  6   10  20
                                   Particle diameter (pm)
                                               40  60  100
   Figure

   i
9/88
1.2-2.  Cumulative size  specific emission factors for traveling
        grate stokers burning  anthracite coal.
                        External Combustion Sources
                                                                          1.2-5

-------
References for Section 1.2


1.   Minerals Yearbook. 1978-79, Bureau of Mines, U. S. Department of the
     Interior, Washington, DC, 1981.

2.   Mr Pollutant Emission Factors, APTD-0923, U. S. Environmental Protection
     Agency, Research Triangle Park, NC, April 1970.

3.   steam, 38th Edition, Babcock and Wilcox, New York, NY, 1975.

4.   Fossil Fuel Fired Industrial Boilers - Background Information for Proposed
     Standards, Draft, Office Of Air Quality Planning And Standards, U. S.
     Environmental Protection Agency, Research Triangle Park, NC, June 1980.

5.   R. W. Cass and R. W. Bradway, Fractional Efficiency of a Utility Boiler
     Baghouse;  Sunbury Steam Electric  Station, EPA-600/2-76-077a, U. S.
     Environmental Protection Agency, Washington, DC, March 1976.

6.   R. P. Janaso, "Baghouse Dust Collectors on a Low  Sulfur Coal Fired Utility
     Boiler", Presented at the  67th Annual Meeting  of  the Air Pollution Control
     Association, Denver, CO, June  1974,

7.   J. H. Phelan, et  al., Design and  Operation Experience with  Baghouse Dust
     Collectors for Pulverized  Coal Fired Utility Boilers - Sunbury  Station,
     Holtwood Station, Proceedings  of  the American  Power Conference, Denver,
     CO,  1976.

8.   Source  Test Data  on  Anthracite Fired Traveling Grate  Stokers,  Office  Of
     Air  Quality Planning And  Standards, U.  S. Environmental Protection Agency,
     Research Triangle Park,  NC,  1975.

9.   Source and Emissions informationT on Anthracite Fired  Traveling Grate
     Stokers,  Office  Of  Air  Quality Planning And  Standards, U.  S.  Environmental
     Protection Agency,  Research  Triangle Park,  NC, 1975.

 10.  R. J.  Milligan,  et  al.,  Review of NCy  Emission Factors for Stationary
     Fossil  Fuel  Combustion  Sources,  EPA-450/4-79-021, U.  S.  Environmental
     Protection  Agency,  Research  Triangle Park,  NC, September 1979.

 11.   N.  F.  Suprenant,  et al.,  Emissions Assessment  of  Conventional Stationary
      Combustion Systems.  Volume IV;  Commercial/Institutional  Combustion
      Sources, EPA Contract  No. 68-02-2197,  GCA Corporation,  Bedford, MA,  October
      1980.

 12.   Source Sampling of Anthracite Coal Fired Boilers, RCA-Electronic  Com-
     • ponents, Lancaster, Pennsylvania, Final Report, Scott Environmental
      Technology,  Inc., Plumsteadville, PA,  April 1975.

 13.   Source Sampling of Anthracite Coal Fired Boilers. Shippensburg State
      College, Shippensburg,  Pennsylvania,  Final Report. Scott Environmental
      Technology, Inc., Plumsteadville, PA,  May 1975.
 1.2-6
EMISSION FACTORS
                                                                            9/88

-------
 14.   W.  Bartok,  et  al.,  Systematic Field Study of  NCy Emission Control  Methods
      for Utility Boilers.  APTD-1163,  U.  S.  Environmental  Protection Agency,
      Research Triangle Park,  NC,  December 1971.
                                                          I
 15.   Source  Sampling  of  Anthracite Coal  Fired  Boilers,  Ashland State General
      Hospital, Ashland,  Pennsylvania,  Final  Report,  Pennsylvania Department  of
  I    Environmental  Resources,  Harrisburg, PA,  March  16,  1977.

 16•   Source  Sampling  of  Anthracite Coal  Fired  Boilers.  Norristown State Hospi-
  1    tal,  Norristown, Pennsylvania, Final Report.  Pennsylvania Department  of
      Environmental  Resources,  Harrisburg, PA,  January 19,  1980.

 17.   Source  Sampling of  Anthracite Coal  Fired  Boilers,  Pennhurst Center, Spring
      City, Pennsylvania, Final Report, TRC Environmental  Consultants, Inc.
      Wethersfield,  CT, January 23,  1980.

 18.   Source  Sampling of  Anthracite Coal  Fired  Boilers. Weist Chester  State. West
      Chester, Pennsylvania, Final  Report. Roy  Weston, Inc., West Chester. PA
      April 4, 1977.

 19'.   Inhalable Particulate Source  Category Report  for External Combustion
      Sources. EPA Contract No. 68-02-3156, Acurex  Corporation, Mountain View
      CA, January 1985.
9/88
External Combustion Sources
                                                                          1.2-7

-------

-------
                                                                                          I
 1.10    RESIDENTIAL WOOD STOVES                          !
   ...                      '                       -i
 1.10.1  General1^                                       ;

      Wood stoves are commonly used as space heaters to supplement conventional
 heating systems in residences.   They are increasingly found as the primary
 source of heat, as well.
   '•-'••                   '-                   i           .
      Because of differences in both the magnitude and the composition of
 emissions from wood stoves, four different categories of  stoves should be  con-
 sidered when estimating emissions:
   i

   ;   -  the conventional noncatalytic wood stove

      -  the noncatalytic low emitting wood stove

      -  the pellet fired noncatalytic wood stove

      -  the catalytic wood  stove

      Among these categories,  there  are many variations in wood stove design and
 operation characteristics.                                I
                                                          I

   '   The conventional stove category  comprises  all  stoves without  catalytic
 combustors  and  are not  included  in  the other noncatalytic categories.   Stoves •
 of,many different airflow designs,  such  as updraft, downdraft,  crossdraft, and
 S-flow,  may be  in this  category.

      "Noncatalytic low  emitting" wood stoves are those having  no catalyst  and
 meeting EPA certification standards.

      Pellet  fired stoves are  fueled with pellets  of sawdust, wood products,
 and other biomass materials pressed into manageable shape and size.  These
 stoves  have  a specially  designed or modified grate to  accommodate this  type
 of .fuel.

      Catalytic  stoves are equipped with a  ceramic or metal honeycomb
 material, called  a  combustor or  converter, that is coated with a noble metal
 such  as  platinum  or palladium.   The catalyst material  reduces the ignition
 temperature of  the  unburned hydrocarbons and carbon monoxide in the exhaust
 gases, thus augmenting their ignition and  combustion at normal stove operating
 temperatures.   As these  components of the gases burn, the temperature inside
 the catalyst increases to a point where the ignition of the gases is essen-
 tially self sustaining.

 1.10.2  Emissions3"13

   i  The combustion and  pyrolysis of wood in wood stoves produce atmospheric
 emissions of particulate, carbon monoxide,  nitrogen oxidesy  organic compounds,
 mineral residues, and to a lesser extent, sulfur oxides.  The quantities and
 types of emissions are highly variable and  depend on a number of factors,
 including the stages of  the combustion cycle.  During inital stages of  burning,
after a new wood charge is introduced, emissions increase dramatically,
 primarily of volatile organic compounds (VOC).   After the initial period of
                          External Combustion Sources
1.10-1

-------
high burn rate, there is a charcoal stage of the burn cycle, characterized by a
slower burn rate and decreased emission rates.  Emission rates during this
stage are cyclical, characterized by relatively long periods of low emissions
with shorter episodes of emission spikes.

     Particulate emissions are defined in this document as the total catch
measured by the EPA Method 5H (Oregon Method 7) sampling train.  A small
portion of wood stove particulate emissions includes "solid" particles of
elemental carbon and wood.  The vast majority of the particulate emissions
is condensed organic products of incomplete combustion equal to or less than
10 micrometers in aerodynamic diameter (PMio)«

     Although reported particle size data are scarce, one reference states that
95 percent of the particles in the emissions from a wood stove were less than
0.4 micrometers in size.-*

     Sulfur oxides are formed by oxidation of sulfur in the wood.  Nitrogen
oxides are formed by oxidation of fuel and atmospheric nitrogen.  Mineral
constituents, such as potassium and sodium compounds, are also released from
the wood matrix during combustion.  The high levels of organic compound and
carbon monoxide emissions result from incomplete combustion of the wood.

     Organic constituents of wood smoke vary considerably in both type and
volatility.  These constituents include simple hydrocarbons (Ci-Cy), which exist
as gases or which volatilize at ambient conditions, and complex low volatility
substances which condense at ambient conditions.  These low volatility conden-
sable materials are generally considered to have boiling points below 300°C
(572°F).

     Polycyclic organic  matter  (POM) is  an important component of the
condensable fraction of  wood smoke.  POM contains a wide range of compounds,
including  organic  compounds formed by  the combination of free  radical species
in the  flame zone  through incomplete combustion.  This group contains some
potentially carcinogenic compounds, such as benzo(a)pyrene.

     Emission  factors and their ratings  for wood combustion in residential
wood stoves are presented in Table  1.10-1.

     As mentioned, particulate  emissions are  defined as the total emissions
collected  by EPA Method 5H  (Oregon Method 7).   This method  employs  a heated
filter  followed by three impingers, an unheated filter, and a  final  impinger.
Emissions  data used  to  develop  the  factors  in Table  1.10-1  are from a data
base developed during EPA certification  tests  and from data collected during
field  testing  programs.   See Reference 1 for  detailed discussions of EPA
Methods 5H and 28.

     Note  that the data shown  on  Table 1.10-1 have been  derived  primarily from
laboratory tests.  Review of  some emission  tests of woodstoves in actual  use
indicates  that laboratory tests may underestimate actual  emissions  significantly.
Evaluation of  field  test results  is proceeding, with completion  scheduled for
October 1988.
 1.10-2
EMISSION FACTORS

-------
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-------
References for Section 1.10

 1.  G. E. Weant, Emission Factor Documentation For AP-42 Section 1.10,
     Residential Wood Stoves, EPA Contract No. 68-02-3888, Engineering Science,
     Inc., Gary, NC.  In Printing.

 2.  R. Gay and J. Shah, Technical Support Document For Residential Wood
     Combustion, EPA-450/4-85-012, U. S. Environmental Protection Agency,
     Research Triangle Park, NC, February 1986.

 3.  Residential Wood Heater Test Report, Phase 1, Tennessee Valley Authority,
     Chattanooga, TN, November 1982.

 4.  J. A. Rau and J. J. Huntziclcer, "Composition And Size Distribution of
     Residential Wood Smoke Aerosols", Presented at the 21st Annual Meeting of
     the Air Pollution Control Association, Pacific Northwest International
     Section, Portland, OR, November 1984.

 5.  R. C. McCrillis and R. G. Merrill, "Emission Control Effectiveness Of A
     Woodstove Catalyst And Emission Measurement Methods Comparison", Presented
     at the 78th Annual Meeting of the Air Pollution Control Association,
     Detroit, MI, 1985.

 6.  L. E. Cottone and E. Messer, Test Method Evaluations and Emissions Testing
     For Rating Wood Stoves, EPA-600/2-86-100, U. S. Environmental Protection
     Agency, Research Triangle Park, NC, October  1986.

 7.  K. E. Leese and S. M. Hackins,  Integrated Air Cancer Project - Source
     Measurement, EPA Contract No, 68-02-3992, Research Triangle Institute,
     Research Triangle Park, NC, March  1986.

 8.  Residential Wood Heater Test Report. Phase II. Vol.  1, Tennessee  Valley
     Authority,  Chattanooga, TN, August  1983.

 9.  J. M. Allen, et al., Study Of The Effectiveness Of A Catalytic Combustion
     Device On A Wood Burning Appliance, EPA-600/7-84-04, U.  S.  Environmental
     Protection  Agency, Research Triangle Park, NC, March 1984.

 10.  J. M. Allen and W. M.  Cooke, Control Of  Emissions From Residential Wood
     Burning By  Combustion Modification, EPA-600/7-81-091, U.  S.  Environmental
     Protection  Agency, Research Triangle Park, NC, May  1981.

 11.  R.  S. Truesdale and  J.  G.  Cleland,  "Residential  Stove Emissions  From Coal
     And  Other Fuels Combustion", Presented at the  Specialty  Conference on
     Residential Wood  and Coal  Combustion, Louisville, KY, March 1982.

 12.  R.  E.  Imhoff,  et  al.,  "Final Report On A Study Of The Ambient  Impact Of
     Residential Wood  Combustion  in Petersville,  Alabama", Presented  at  the
      Specialty  Conference on Residential Wood and Coal Combustion,  Louisville,
     KY,  March 1982.
 1-10.-4
EMISSION FACTORS

-------
                                                                                       1
|13.  D. G. Deangelis, et al.t Preliminary Characterization Of Emissions From
     Wood-fired Residential Combustion Equipment. EPA-600/7-80-040, U. S.
     Environmental Protection Agency, Cincinnati, OH, March  1980.
i                                            ""l
l14*  Standards Of Performance For New Stationary Sources:  New Residential Wood
     Heaters, 53 FR 5860, February 26, 1988.           |~"
                         External Combustion Sources
1.10-5

-------

-------
 1.11 WASTE OIL COMBUSTION

 1.11.1   General

      "Waste oil" or "used oil" refers to spent lubricating and  other  in-
 dustrial oils  that  are  recovered for  reuse  as  fuels,  road  oils  and  processed
 oils.  The principal type of  waste oil is used vehicle crankcase  oil  recovered
 by automobile  service stations and waste oil collection depots.   Other  types  of
 waste oil include metal working lubricants, heavy  hydrocarbon fuels,  animal and
 vegetable oils and  fats,  and  industrial  oils,  including those used  as trans-
 former  and other heat transfer fluids.   Common contaminants in  waste  oils
 include metals, halogens,  various  volatile  organic  compounds  (VOC)  and  solvents,
 and sulfur.  Lead is found in appreciable quantities  in used  crankcase  oil
                                                          Many other metals and
because of the use of tetraalkyllead gasoline additives.  	., 	. __0 „
sulfur are introduced directly during formulation of lubricating oils as com-
ponents of additives.  Also, metals can be introduced through abrasion and wear
of  lubricated parts and surfaces.  Halogens are introduced from the use of
organic halides as lead scavengers in gasoline, or through commingling of waste
oils  and cleaning solvents such as perchloroethylene.  Commingling of used oil
and other organic compounds during collection and storage appears to be a
common occurrence, as evidenced by the large number of relatively low molecular
weight organics frequently found in used oils but not present in the original
oils.                           •   •            '          1
  i                                                       I

  ;    In 1983, over 8.7 billion liters (2.3 billion gallons) of automotive and
industrial lubricating oils and other industrial oils wer'e sold.1"2  Of this
total, 4.6 billion liters (1.2 billion gallons) were recovered as used oil and
subsequently reused or disposed of.  The remainder was lost through engine
breakdown during engine operation, end use application, leakage and handling.
Waste oil combustion consumed 2.2 billion liters (0.59 billion gallons), or°
roughly half of the recovered total, up appreciably from j!970 estimates
because of higher fuel costs, past fuel shortages, and the decline of other
outlets for.used oil, such as road oilant or base stock for re-refining.3

  ;   Waste oil may be burned alone or mixed with other fu|el oil,  in most
conventional oil burning combustion systems.  Several problems are associated
with waste oil combustion, including reduced combustion efficiency and the
corrosion and erosion of system components.  However,  the'se problems are not
felt to be serious, and they can be reduced if the waste bil  is blended with
fuel oil or if the used oil is treated to reduce sediment!, water,  light end and
metal content.   Metal emissions can be reduced if a vaporizing burner rather
than an atomizing burner is used in small waste oil space: heaters.
                                                         i
1.11.2  Emissions

  |   Emission factors for uncontrolled waste oil combustibn are presented in
Table 1.11-1.   Lead emissions depend on the oil's  lead  content  and  on  boiler
and burner design and operating conditions.   Because of greatly decreased use
of; lead in gasoline,  the lead content  of  waste oil has  dropped  significantly,
falling from 10,000 parts per million in 1970 to 1,100  parts  per  million in
19,82-83 and to 300 - 500 parts  per million in 1985.2~3   While  further  decreases
9/88
                          External  Combustion Sources
1.11-1

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  t
 are forecast, the current lead content is still appreciably higher than the up
 to 100 parts per million levels found in conventional fuels.   Typically,  50
 percent or more of the lead in waste oil is emitted with flue gas during
 combustion, with the remainder deposited on internal surfaces.3,5-10 However,
 in small space heaters employing vaporizing burners, less than 5 percent  of the
 lead in the waste oil is emitted.3                      !
  1                                     •                 .1
      Cumulative size distribution data and size specific emission factors for
 uncontrolled particulate emissions from waste oil combustion  in commercial  or
 industrial boilers and air atomizing space heaters are presented in Tables
 1.11-2 and 1.11-3.  Uncontrolled size specific emission factors are presented
 in Figures 1.11-1 and 1.11-2.   Particulate emissions are based on the ash
 content of the fuel.   Because  the ash content of  waste oil  is generally higher
 than that found in refined oils, emissions from waste oil combustion will be
 greater.

      Emissions of other pollutants,  such as sulfur dioxide  (SC^) and hydro-
 chloric acid (HC1),  will depend on the respective sulfur  and  chlorine levels in
 the oil.  Because levels of  these precursor materials are generally greater in
 waste  oils than in refined fuel oils,  particularly distillate oil,  waste  oil
 combustion will produce more emissions of SOX and HC1.   In  contrast,  emissions
 of  nitrogen oxides (NOX),  carbon monoxide (CO) and VOCs are similar for both
 waste  and  refined fuels.

 1.11.3  Controls

 Pretreatment - Most  waste  oil  now sold as a fuel  receives some  sort of  physical
 pretreatment (e.  g.,  sedimentation,  filtration, centrifugation,  water and light
 end distillation).   Lead and other trace  element  concentrations  and the ash
 content  of the waste  oil generally will be  lowered  somewhat by  some of these
 pretreatments,  probably  less than 30 percent.   While  lead and ash content
 reduction  will  reduce  emissions  of lead and particulate taatter proportionately,
 its purpose is  to reduce water,  sediment  and  low  boiling  components.  This
 provides a safely handled  fuel  with  combustion  properties; similar to those of
 cpnventional fuels and with  physical properties resembling a  No. 4  fuel.3
 Thus,  criteria  pollutant emissions primarily affected by  overall combustion
 efficiency (carbon monoxide  and VOCs) will  be  similar  to  those from con-
 ventional  fuels."

     Other criteria pollutants,  such as sulfur  and NOX which  depend either
 totally or  partially on the  fuel sulfur and nitrogen contents, will be emitted
 at  levels  consistent with  those  concentrations.  Fuel sulfur  and nitrogen
 levels generally do not decline with pretreatment.  Because waste oil sulfur
 usually contains more  sulfur than  does distillate oil, emission factors for its
 combustion  will be proportionally higher.  Similarly, the higher nitrogen
 content of  the waste oil can be expected  to result in higher  nitrogen oxide
 emissions.  Emissions of chloride will be directly related to  the chlorine
 content of  the  fuel, with 80 to 90 percent of the chloririe emitted as HC.1.8-9
Many chlorinated organics, such as the low molecular weight  chlorinated sol-
vents, will be  removed during pretreatments employing light end distillation.
However, chlorine bearing compounds with vapor pressures similar to those  of
the virgin  base stock (e. g., polychlorinated biphenyls) will  not be removed by
this pretreatment.  Expensive hydrofinishing, or possibly clay contacting
operations, must be used to remove such chlorine.         I
 9/88
External Combustion Sources
                                                                        1.11-3

-------
   TABLE 1.11-2.
CUMULATIVE SIZE DISTRIBUTION FOR UNCONTROLLED
PARTICULATE EMISSIONS AND SIZE SPECIFIC EMISSION FACTORS
FOR COMMERCIAL/INDUSTRIAL BOILERS FIRING WASTE
Particle size^
(tun)
15
10
6
2.5
1.25
1.00
0.625
Cumulative mass %
< stated size
88
84
78
67
57
53
45
Emission factor0
(kg/m3)
6.4(A)
6.1(A)
5.7(A)
4.9(A)
4.2(A)
3.9(A)
3.3(A)
(lb/103 gal)
54(A)
51(A)
48(A)
41(A)
35(A)
32(A)
27(A)
 aReference 1.   A = ash content in fuel.
 ^Expressed as  aerodynamic equivalent diameter.
 CBased on an overall particulate emission factor of 7.3(A)  kg/m3
  [61(A) lb/103 gal].
   TABLE 1.11-3.
CUMULATIVE SIZE DISTRIBUTION FOR UNCONTROLLED
PARTICULATE EMISSIONS AND SIZE SPECIFIC EMISSION FACTORS
FOR AN AIR ATOMIZING SPACE HEATER UNIT FIRING WASTE
Particle size^
(urn)
15
10
6
2.5
1.25
1.00
0.625
Cumulative mass %
< stated size
91
89
82
68
53
48
39
Emission factorc
(kg/m3)
7.0(A)
6.8(A)
6.3(A)
5.2(A)
4.1(A)
3.7(A)
3.0(A)
(lb/103 gal)
58(A)
57(A)
52(A)
44(A)
34(A)
31(A)
25(A)
 aReference 5.  A = ash content in fuel.
 "Expressed as aerodynamic equivalent diameter.
 CBased on an overall particulate emission factor of 7.7(A) kg/m3
  [64(A) lb/103 gal].
1.11-4
              EMISSION FACTORS
                                                         9/88

-------
9/88
               10A


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                          Cumulative size specific part.iculate  emission
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                          firing waste oil.             j
-J	1	1 I I  I I I I	•   ••.
                 0.1
            .1               10   i
       PARTICLE DIAMETER, micrometers
                                                        100
         Figure 1.11-2.    Cumulative size specific particulate emission
                          factors for an air atomizing space heater unit
                          firing waste oil.
 External Combustion Sources
                                                                         1.11-5

-------
Blending - Blending waste fuel and virgin fuel oil generally will reduce emis-
sions of lead, particulate, sulfur dioxide and hydrochloric acid.  Emissions
of these pollutants will be approximately proportional to the respective con-
centrations of lead, ash, sulfur and chlorine in the blended fuel.   NOX emis-
sions may also be reduced, although available data do not support a reduction
estimate.  Emissions of VOC and carbon monoxide, which depend on combustion
efficiency, will not be significantly affected by blending.

Unit Design - There has been an increase in the use of waste oil as a fuel in
small space heaters (those with less than 250,000 British Thermal Units per
hour input).8'10  Two types of burners are employed in these combustion systems,
air atomizing and vaporizing.  The conventional air atomizer injects aerosolized
oil vapor into the combustion chamber, whereas the vaporizing burner operates
through volatilization of heated oil.  In the latter, the vapors are burned,
and a residue is left behind in the vaporizing pot.  The atomizing units emit
at least an order of magnitude more particulate, lead and trace  elements than
do the vaporizing units.  Although levels of VOC and other unburned combustible
emissions appear comparable from both types of units, limited data suggest a
significantly higher level of polycyclic organic matter emitted  from vaporizing
burners.

Control Equipment - Apart  from the measure of control introduced by pretreat-
ment, blending or the use  of vaporizing burners, no additional controls are
being applied to waste oil combustion.  Waste oils  are usually burned in small
devices, for which controls are virtually nonexistent.  Because  greater than
80 percent of the lead bearing particulate is submicron in diameter, only high
efficiency control devices such as fabric filters can provide significant
control.  Mechanical collectors will  achieve  little if any  measurable control,
either of lead  emissions or of the submicron  fraction of the particulate (about
55 percent) emitted  in flue gas.8


References for  Section  1.11

 1.    Composition And Management Of Used Oil  Generated In The United States,
      PB85-180297, National Technical  Information  Service,  Springfield,  VA,
      November 1985.

2.    Waste Oil; Technology, Economics, And Environmental Health  And Safety
      Considerations, U.  S. Department Of  Energy,  Washington, DC, January 1987.

 3.    N.  F.  Surprenant,  et al.,  The  Fate Of Hazardous  And Nonhazardous Wastes  In
      Used  Oil Disposal  And Recycling, DOE/BC/10375-6, U.  S. Department  Of
      Energy,  Bartlesville, OK,  October 1983.

 4.    T.  D.  Coyle and A.  R. Siedle,  "Metals  In Oil:  Occurrence And  Significance
      For Reuse Of  Spent  Automotive  Lubricating Oils", Measurements And  Standards
      For Recycled  Oil  - II,  Special Publication 556,  National Bureau Of
      Standards, Gaithersburg,  MD,  September  1979.

 5.    Final Report  Of The API Task Force  On Oil Disposal,  American Petroleum
      Institute, New York, NY,  May 1970.
 l.H-6                          EMISSION FACTORS                            9/88

-------
 6.
 7,
 8.
 9.
10.
11.
12,
G. A. Chappell, Waste Oil Reprocessing, Project No.'72-5, Esso Research
and Engineering Co., Government Research Laboratory! Linden, NJ, January
1973.                                               '
                                                    l
D. A. Waite, et al., "Waste Oil Combustion: An Environmental Case Study",
presented at the 75th Annual Meeting of the Air Pollution Control
Association, New Orleans, LA, June 1982.
                                                    i
Environmental Characterization Of Disposal Of Waste Oils In Small
Combustors, EPA-600/2-84-150, U. S. Environmental Protection Agency,
Cincinnati, OH, September 1984.

Used Oil Burned As A Fuel, EPA-SW-892, U. S. Environmental Protection
Agency, Washington, DC, August 1980.                 j

R. E. Hall, et al., "Comparison Of Air Pollutant Emissions From Vaporizing
And Air Atomizing Waste Oil Heaters", Journal of the Air Pollution Control
Association. J33_(7) : 683-687, July 1983.

R. L. Barbour and W. M. Cooke, Chemical Analysis Of Waste- Crankcase Oil
Combustion Samples, EPA-600/7-83-026, U. S. Environmental Protection
Agency, Cincinnati, OH, April 1983.
                                                     ,
W. B. Walker and R. Salter, Pollution Of The Environment By The Burning Of
Waste Oils, PB83-004943, National Technical Information Service,
Springfield, VA, September 1980.
 9/88
                          External Combustion Sources
                                                                    1.11-7

-------

-------
                                                                                         1
 2.1   REFUSE COMBUSTION

      Refuse combustion generally means the burning of predominantly  nonhazardous
 garbage  or  other wastes.   Types  of combustion devices useid  to  burn refuse
 include  single chamber units,  multiple chamber units, trench incinerators,  con-
 trolled  air incinerators,  and  pathological incinerators, j These  devices  are
 used to  burn municipal,  commercial,  industrial,  pathological,  and domestic
 refuse.                                                  I            .
  I                                               •
  i                                              •         '
 2il.l  Municipal Waste Combustionl

  i   Mass burn excess  air  combustion is the predominant method of burning
 municipal solid waste  (MSW).   Approximately 70 percent of the  MSW burned is
 burned in mass burn units.   The  term "mass burn" means the  burning of  MSW with-
 out  any  prior processing other than  the removal of bulky items (stoves,  tele-
 phone poles,  etc.)  to  produce  a  more homogeneous fuel,  toss burn units  are
 preferred for disposal of  large  amounts (up to 2700 megagfams  metric tons [3000
 tons] per day)  of MSW.  Some mass burn units coincinerate MSW  and sewage sludge.
 A;second type of municipal waste  combustor is  the  starved air  or  modular
 combustor.   Starved air  combustors are the most common type of combustor because
 they handle smaller amounts  (up  to 450 megagrams [500 tons]  per day) of MSW.
 Another  type  of .municipal waste  combustor  is the refuse-derived  fuel (RDF)
 combustor.   Refuse-derived fuel  combustors burn MSW from which metals  and other
 noncombustible materials have  been removed.   Because  of the processing costs
 associated  with producing RDF, these  units  are not  as  popular  as  mass  burn  or
 starved  units.   Some RDF is  incinerated with coal  or  sewage sludge.

 2^1.2  Process  Description*"^

  1   Mass Burn Combustors - Typically,  an  overhead  crane mixes MSW in  a storage
 pit and  then  moves  it  into a feed  chute.   A hydraulic ram system  under the  feed
 chute charges the waste onto a grate  system.   As the  waste  is moved through the
 combustion  chamber  by  the grate system,  it  passes  through three zones:  a dryout
 zone, where moisture in the waste  is  evaporated; a  combustion  zone; and a burn-
 out zone, where  final  combustion occurs.   The  resulting ash  falls  into a flooded
 ash pit  and is  removed and sent  to a  landfill.  In  some cases, ferrous metals
 ar;e removed from  the ash by magnetic  separation.   The capacity of  individual
 combustors  can  range from 50 to 1000 megagrams of waste p^r  day,  and usually 2
 or 3 units  are  at a site.
          .
  '   Several  types  of  grate systems are  used with mass burn  combustors.  They
 are all  similar in being designed to move  the waste through the combustor and
 to promote  complete combustion.  The  grates  can be  traveling, rocking,  recipro-
 calting,   roller, or rotary designs.  The combustion process  is supplied with
 underfire air,  which is introduced into multiple compartments,  or plenums,
under the stoker grates, and with overfire air from nozzles  or openings above
 the grates.

  j   New mass burn combustors can be expected to have a water wall furnace  to
recover  energy  in the  form of steam.   Many older facilities  have  refractory
 lined walls rather than water walls.   Large mass burn units  are usually field
erected.                                                  !
9/88
Solid Waste Disposal
                                                                          2.1-1

-------
     The air pollution control systems for these combustors are electrostatic
precipitators (ESP), dry fabric filters (FF),  dry scrubbing systems (with
either ESPs or FFs), and wet scrubbers.

     Starved Air Combustors - A typical such unit has separate primary and
secondary chambers.  The primary chamber is fed MSW by a hopper and ram feed
system.  Air is supplied to the primary chamber at substoichiometric levels.
Rams in the primary chamber push residue and break up clinker.  Exhaust gases,
including incomplete combustion products, (mostly carbon monoxide and hydro-
carbons of low molecular weight) pass into the secondary combustion chamber.

     In the secondary combustion chamber, more air is added, and combustion is
completed.  The resulting hot gases, 1000° to 1200°C (1800° to 2200°F), can be
passed through a heat recovery boiler  for energy recovery, and all new starved
air combustors can  be expected to have such systems.  Ashes are quenched and
removed for disposal.  Most existing starved air municipal waste combustors
operate without emission control systems, although some have ESPs or fabric
filters for particulate control.  Starved air combustors generally are available
on the market and  can be installed relatively quickly.

     Refuse-derived Fuel Combustors -  An alternative to direct c'ombustion of MSW
is processing the  waste to produce refuse-derived fuel  (RDF).  The four main
types  of  RDF are  fluff, densified, powdered, and wet pulped.   Fluff RDF  is
prepared  by mechanical shredding of MSW, followed by air classification,
magnetic  separation, or trommeling  to  reduce the noncombustible  content  of  the
waste  stream.   If  multiple shredding  stages are used, fine  RDF is  produced.
Densified RDF is  fine RDF  extruded  in a  pellet mill.  Production of powdered
RDF  requires mechanical, thermal and  chemical processing of shredded MSW that
has  undergone screening and magnetic  separation.   In  the wet  pulping process,
the  pulper is fed  wet MSW  that has been  sluiced  with water.   Noncotnbustibles
are  removed in  a  liquid cyclone,  then the  RDF  is  then mechanically dewatered
to a moisture content of 50 percent.

      Boilers dedicated  to  RDF combustion are  of  basically  the same design as
 those  used for  coal combustion.   Typical configurations  include  suspension,
 stoker,  and fluidized bed  designs.   These boilers may burn up to 900 megagrams
 (1000 tons)  of  RDF per  day.   The  ash  is  quenched and  removed  to  a  landfill.
Most RDF units  use ESPs  for particulate matter control.

 2.1.3  Emissions  And Controls3"^

      Refuse incinerators  have the potential to emit significant quantities of
 pollutants to the atmosphere.  One of these pollutants  is  particulate matter,
 emitted because of the turbulent  movement of the combustion gases  with respect
 to the burning sludge and resultant ash.  Particulate matter is  also produced
 when metals that are volatilized in the combustion zone condense in the exhaust
 gas stream.  Particle sizes and particulate concentrations leaving the ^ciner-
 Itor vary widely,  depending on the composition of the refuse being burned and
 on the type and operation of the incineration process.

      Incomplete combustion of refuse,, through improper incinerator design or
 operating conditions, can result in emissions of intermediate products such as
 volatile  organic  compounds and carbon monoxide.  Other potential emissions
 2.1-2
                                 EMISSION FACTORS                           9/88

-------
 include  sulfur  dioxide,  nitrogen oxides, metals,  acid  gases,  and  toxic  organic
 compounds.                                               ,     •
 !                                                      •  '
     A wide  variety  of  control  technologies  is  used  to control  refuse
 incinerator  emissions.   Currently,  the most  widely used  devices are ESPs,
 fabric filters,  wet  scrubbers and dry scrubbers.  Many control  systems  use  a
 combination  of  these.                                    .••••-
 i    ' ,          .             '           .
 !                                           .1
 '    Electrostatic precipitators  are used  on 75 percent  of  existing municipal
 waste incinerators,  to  control  particulate emissions.   The  efficiency of a
 typical  ESP  can range from 90 to  99 percent,  depending on particle size
 distribution, gas flow  rate  and particle resistivity.    i

     Fabric  filters  generally have  not been  applied  directly  to flue gases  from
 municipal incinerators,  but  rather  are used  as sorbent collectors and secondary
 reactors  for dry and semidry scrubbers.  With upstream scrubbing  of acid gases
 and  sorbent  accumulation on  fabric  materials, fabric filters become a viable
 choice for control of fine particulate as  well as other  pollutants.
                                                         I
 i                                                        I
     Many types of wet  scrubbers  are used  for removing acid gases - spray
 towers,  centrifugal  scrubbers and venturi  scrubbers.   Scrubbers with internals,
 such as  packed beds  and  trays,  are  less commonly used.   In wet scrubbers, the
 exhaust  gas  enters the  absorber and contacts  enough  alkaline solution to satur-
 ate  the gas  stream.  The alkaline solution reacts with th'e acid gases to form
 salts, which are generally insoluble and removable by  sequential  clarifying,
 thickening and vacuum filtering.  The dewatered salts  or sludges  are then used
 as landfill.                                             [

 ,    The  two types of dry scrubbing are dry  injection  and semidry scrubbing.
 In both,   the material collected in  the particle collector is dry.  Dry injection
 is the injection of  a solid  powder  such as lime or sodium bicarbonate into  the
 flue gas  (with a separate water injection).  Acid gas removal occurs in the
 duct and  continues in the dust  collector, as  sorbent and'ash particles,and
 condensed volatile matter are captured.  In a semidry process, also known as
 spray drying or wet/dry  scrubbing,  the sorbent enters  the flue gas as a liquid
 spray, with  sufficient moisture to  promote rapid absorption of acid gases, but,
 because  the moisture evaporates,  only dry solid particles collector.
 i
     Emission factors for municipal waste incinerators are shown in Table 2.1-1.
 Table 2.1-2  shows the cumulative  particle size distribution and size specific
 emission  factors for municipal  waste combustors.  Figures! 2.1-1, 2.1-2 and
 2.1-3 show the cumulative particle  size distribution and |size specific emission
 factors for mass burn,  starved  air  and RDF combustors, respectively.

 2.1.4  Other Types Of Combustion2,5-7                    |
 |                     .                               '
 I    The most common types of combustors have a refractory lined chamber with
 a|grate upon which refuse is burned.  In some newer incinerators,  water  walled
 furnaces   are used.   Combustion  products are formed by heating and burning refuse
 oii the grate.  In most  cases, since insufficient underfir[e air is  provided to
 complete  combustion,  additional air is admitted above the! burning waste  to
 promote complete gas  phase combustion.   In multiple chamber incinerators,  gases
 from the  primary chamber flow to a  small secondary mixing chamber, where more
air is admitted and more extensive oxidation occurs.   As much as 300 percent
 *                                                        i..
9/(88                          Solid Waste Disposal                    .  "  2.1-3

-------
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2.1-4
                                   EMISSION FACTORS
                                                                                  9/88

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9/88

-------
 the top of the pit and to provide air for combustion in the pit.   Low con-
 struction and  operating costs  have Led  to use  of  this  combustor  to dispose of
 materials other than those for which it was  originally designed.   Emission
 factors for trench combustors  used to burn three  such  materials  are given  in
 Taible 2.I.3.8                                             j
                                                          I
   I   Domestic  Combustors - This category includes combustors marketed for
 residential use.   Fairly simple in design, they may  have  single  or multiple
 chambers and usually are equipped with  an auxiliary  burner  to  aid  combustion.

      Flue Fed  Combustors - These  units,  commonly  found in large  apartment
 houses,  are characterized by the  charging method  of  dropping refuse down the
 combustor flue and into the combustion  chamber.   Modified flue fed incinerators
 utilize afterburners and draft controls to improve combustion  efficiency and to
 reduce  emissions.                                                     .

      Pathological  Combustors - These are combustors  used  to dispose of  animal
 remains  and other  organic  material of high moisture  content.   Generally, these
 units are able to  process  23 to 45 kilograms (50  to  100 pounds)  of such waste
 per hour.   Wastes  are  burned on a hearth in  the combustion  chamber.   The units
 are equipped with  combustion controls and afterburners to(ensure good combustion
 and reduced emissions.

 2.1.6  Emissions And Controls2j9
                                                          i
                                                          . i
   :   Operating conditions,, composition  of refuse,  and  basic combustor design
 have  a  pronounced  effect on emissions.   The manner in  which  air is  supplied  to
 the combustion chamber or  chambers has  a significant effect on the quantity of
 particulate emissions.   Air may be  introduced  from beneath,  aside  or  atop  the
 combustion  chamber.   As  underfire air is  increased,  an increase in fly  ash
 emissions occurs.   Erratic refuse  charging causes a disruption of  the com-
 bustion bed and subsequent release of large quantities of particulate.  Large
 amounts  of  uncombusted  particulate  and carbon monoxide also  are emitted for
 an extended period after the charging of batch fed units, because  of  inter-
 ruptions  in the combustion process.   In  continuously fed  units, furnace parti-
 culate  emissions strongly depend  on grate  type.   Use of a rotary kiln and
 reciprocating  grates results in higher particulate emissions than  does use of a
 rocking  or  traveling grate.  Emissions  of  oxides  of sulfur  depend  on  the sulfur
 content  of  the refuse.   Carbon monoxide  and unburned hydrocarbon emissions may
 be significant, and  are  caused by  poor  combustion resulting  from improper
 combustor design or  operating conditions.  Nitrogen oxide emissions increase
 with  increases  in  combustion zone  temperature,  residence  time in the  combustion
 zone before quenching, and excess air rates to the point where dilution cooling
 overcomes the  effect of  increased  oxygen  concentration.6

   !                  '                              ' '     !
 References  for Section 2.1                                          .

 !•  Appendix A;   Characterization of the Municipal Waste 'Combustion Industry,
   i  Radian Corporation, Research Triangle Park,  NC,  October 1986,
   f                                                       i
 2.  Air Pollutant Emission Factors, APTD-0923, U. S. Environmental Protection
   (  Agency, Research Triangle  Park, NC, April  1970.


9/88-                          Solid Waste Disposal                        2.1-9

-------
 3.   Emission Factor Documentation For AP-42  Section 2.1.1;   Municipal  Waste.    .
     Combustion (Draft),  Office Of Air Quality Planning And  Standards,  U.  S.
     Environmental Protection Agency,  Research Triangle Park, NC,  September
     1987.

 4.   C. B.  Sedman and T.  G.  Brna,  Municipal Waste Combustion Study;   Flue  Gas
     Cleaning Technology, EPA/530-SW-87-021d,  U.  S.  Environmental  Protection
     Agency,  Research Triangle Park,  NC,  June 1987.

 5.   Control  Techniques for  Carbon Monoxide Emissions from Stationary Sources,
     AP-65,  U. S. Environmental Protection Agency,  Cincinnati, OH,  March 1970.

 6.   Air Pollution Engineering Manual, AP-40,  U.  S.  Environmental  Protection
     Agency,  Cincinnati,  OH, 1967.  Out of Print.

 7.   J. DeMarco, et al.,  Incinerator Guidelines,  1969, 13TS, U. S. Environmental
     Protection Agency, Cincinnati, OH, 1969.

 8.   J. 0.  Brukle, J. A,  Dorsey and B. T. Riley,  "The Effects of Operating
     Variables and Refuse Types on Emissions from a Pilot-scale Trench >
     Incinerator", Proceedings of the 1968 Incinerator Conference, American
     Society of Mechanical Engineers,  New York, NY,  May 1968.

 9.   Walter R. Nessen, Systems Study of Air Pollution from Municipal
     Incineration, Contract No. CPA-22-69-23,  Arthur D. Little, Incorporated,
     Cambridge, MA, March 1970.

10.   C. V.  Kanter, R. G.  Lunche and A. P. Fururich,  "Techniques for Testing Air
     Contaminants from Combustion Sources", Journal Of The Air Pollution Control
     Association, £(4): 191-199, February 1957.

11.   J. L.  Stear, Municipal Incineration;  A Review of Literature, AP-79,  U. S.
     Environmental Protection Agency, Research Triangle Park, NC,  June 1971.

12.   E. R.  Kaiser, Refuse Reduction Processes in Proceedings of Surgeon
     General's Conference on Solid Waste Management, PHS No. 1729, U. S.
     Public Health Service,  Washington, DC, July 1967.

13.   Unpublished  source  test data on  incinerators, Resources Research,
     Incorporated, Reston, VA, 1966-1969.

14.   E. R. Kaiser, et al., "Modifications To Reduce Emissions From A Flue-fed
     Incinerator", No. 552.2, College of Engineering, New York University, New
     York,  NY, June  1959.

15.   Communication between Resources  Research, Incorporated,  Reston, VA, and
     Division of  Air Quality Control, Maryland State Department of Health,
     Baltimore, MD,  1969.

16.  Unpublished  incinerator test data, Office of Air Quality Planning And
     Standards, U. S.  Environmental Protection Agency, Research Triangle Park,
     NC, 1970.
2.1-10
EMISSION FACTORS
                                                                           9/88

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                                 1  M-
 2.1.2  Other Types  of Combustors

      The most common types  of  combustors  consist of a refractory-lined
 chamber with a grate upon which refuse  is burned.  In some newer
 incinerators water-walled furnaces are  used.   Combusti.,.. products are formed
 by heating  and burning of refuse on  the grate.   In most  cases,  since
 insufficient underfire (undergrate)  air is  provided to enable complete
 combustion,  additional over-fire air is admitted above the burning waste to
 promote complete  gas-phase  combustion.  In  multiple-chamber incinerators,
 gases from  the primary chamber flow  to  a  small  secondary-mixing chamber
 where more  air is admitted, and more complete  oxidation  occurs.  As much as
 300 percent  excess  air may  be  supplied  in order to promote oxidation of
 combustibles.   Auxilliary burners are sometimes installed in the mixing
 chamber to  increase the combustion temperature.   Many small-size incin-
 erators are  single-chamber  units in  which gases  are vented from the primary
 combustion  chamber  directly into the exhaust stack.   Single-chamber
 incinerators  of this  type do not meet modern air pollutioiii codes.
                            1  M-
 2.1.2.1  Process  Description

   |   Industrial/Commercial  Combustors—The  capacities  of  these  units  cover  a
 wide  range,  generally between  50 and 4,000  pounds  (22.7 and  1,800  kilograms)
 per hour.  Of  either  single- or multiple-chamber  design,  these  units  are
 often manually charged  and  intermittently operated.   Some  industrial
 combustors are similar  to municipal  combustors  in  size and design.   Better
 designed  emission control systems include gas-fired afterburners,  scrubbers,
 or  both.

   i   Trench Combustors—A trench combustor  is designed for the  combustion of
 wastes  having  relatively high heat content and low ash content.  The  design
 of ithe  unit is  simple:  a U-shaped combustion chamber  is formed by  the  sides
 and bottom of  the pit, and air is supplied from nozzles (or fans) along the
 top of  the pit.  The nozzles are directed at an angle below the horizontal
 to iprovide a curtain of air across the top of the pit and to provide air for
 combustion in  the pit.  Low construction and operating costs have resulted
 in  the use of  this combustor to dispose of materials other than those for
 which it was originally designed.   Emission factors for trench combustors
 used to burn three such materials  are included in Table 2.1.2-1.
   i                    ,                                  i
   i  Domestic Combustors—This category includes combustors marketed for
 residential use.  Fairly simple in design, they may have  single or multiple
 chambers and usually are equipped  with an  auxiliary burner to aid
 combustion.
   ;                 . '   ..   .               ,               . -I

     Flue-Fed Combustors—These units, commonly found in  large apartment
houses, are characterized by the charging  method of dropping refuse down the
combustor flue and into the  combustion chamber.   Modified flue-fed
 incinerators utilize afterburners  and draft  controls to improve combustion
efficiency and reduce emissions.

   I  Pathological  Combustors—These are  combustors used to dispose of animal
remains and  other  organic material  of high moisture content:.   Generally,
these units  are in a size range of  50 to 100 pounds (22.7  to 45.4 kilograms)
   t
                                                          i

 9/88                         Solid Waste Disposal                     2.1-11

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2.1-12
EMISSION FACTORS
                                                                       9/88

-------
 per hour.   Wastes  are burned  on a  hearth  in  the  combustion chamber.   The
 units  are  equipped with  combustion controls  and  afterburners  to ensure good
 combustion and minimal emissions.   ,

 2.1.2.2  Emissions and Controls1

     Operating conditions, refuse  composition, and basic combustor design
 have a pronounced  effect on emissions.  The  manner in which air is supplied
 to  the combustion  chamber or  chambers has a  significant effect  on the
 quantity of particulate emissions.  Air may  be introduced  from  beneath the
 chamber, from the  side, or from the top of the combustion  chamber.  As
 underfire  air is increased, an increase in fly-ash emissions occurs.
 Erratic refuse charging causes a disruption  of the combustion bed and  a
 subsequent release of large quantities of particulates.  Large  quantities of
 uncombusted particulate matter and carbon monoxide are also emitted for  an
 extended period after charging of batch-fed  units because  of interruptions
 in^the combustion  process.  In continuously  fed units, furnace  particulate
 emissions are strongly dependent upon grate  type.  The use of a rotary kiln
 and reciprocating grates results in higher particulate emissions than the
 use: of a rocking or traveling grate.   Emissions of oxides of sulfur are
 dependent on the sulfur content of the refuse.  Carbon monoxide and unburned
 hydrocarbon emissions may be significant and are caused by poor combustion
 resulting from improper combustor design or operating conditions.  Nitrogen
 oxide emissions increase with an increase in the temperature of the
 combustion zone,  an increase in the residence time in the combustion zone
before quenching, and an increase in the excess air rates to the point where
dilution cooling  overcomes the effect  of increased oxygen concentration.
 9/88
Solid Waste Disposal
                                                                      2.1-13

-------
References for Section 2.1.2

 1.  Air Pollutant Emission Factors. Final Report, Resources Research,
     Incorporated, Reston, VA, prepared for National Air Pollution Control
     Administration, Durham, NC, under Contract Number CPA-2269-119,
     April 1970.

 2.  Control Techniques for Carbon Monoxide Emissions from Stationary
     Sources, U.S. DHEW, PHS, EHS, National Air Pollution Control
     Administration, Washington, DC, Publication Number AP-65, March 1970.

 3.  Air Pollution Engineering Manual, U.S. DHEW, PHS, National Center for
     Air Pollution Control, Cincinnati, OH, Publication Number 999-AP-40,
     1967, p. 413-503.

 4.  J. DeMarco. et al., Incinerator Guidelines 1969, U.S. DHEW, Public
     Health Service, Cincinnati, OH, SW.  13TS, 1969, p. 176.

 5.  J. 0. Brukle, J. A. Dorsey, and B. T. Riley, The Effects of Operating
     Variables and Refuse Types on Emissions from a Pilot-Scale Trench^
     Incinerator, Proceedings of the 1968 Incinerator Conference, American
     Society of Mechanical Engineers, New York, NY, May 1968, p. 34-41.

 6.  Walter R. Nessen,  Systems  Study of Air Pollution from Municipal
     Incineration, Arthur D. Little, Inc.  Cambridge, MA, prepared for
     National Air Pollution Control Administration, Durham, NC, under
     Contract Number CPA-22-69-23, March 1970.

 7.  C. V. Kanter, R. G. Lunche, and A. P. Fururich, Techniques for Testing
     Air Contaminants from Combustion Sources, J. Air Pol. Control Assoc.,
     6(4): 191-199, February  1957.

 8.  J. L. Stear, Municipal Incineration;  A Review of Literature, U. S.
     Environmental Protection Agency, Office of Air Programs, Research
     Triangle Park, NC, OAP Publication Number AP-79, June 1971.

 9.  E. R. Kaiser, Refuse Reduction. Processes  in  Proceedings  of Surgeon
     General's  Conference on  Solid Waste Management, Public Health Service,
     Washington,  DC, PHS Report Number 1729, July 10-20,  1967.

 10.  Unpublished  source test  data on  incinerators, Resources  Research,
     Incorporated, Reston, VA,  1966-1969.

 11.  E. R. Kaiser, et al., Modifications  to Reduce Emissions  from a Flue-Fed
     Incinerator, New York University, College of Engineering, Report
     Number  552.2, June 1959, p.  40 and 49.

 12.  Communication between Resources  Research, Incorporated,  Reston, VA,  and
     Maryland  State  Department  of Health,  Division of Air Quality Control,
     Baltimore, MD,  1969.
   2.1-14                       EMISSION FACTORS                          9/88

-------
13.  Unpublished data on incinerator testing.  U.S. DHEW, iPHS, EHS, National
     Air Pollution Control Administration, Durham, NC, 1970.
  9/88
Solid Waste Disposal
2.1-15

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-------
'2.5  SEWAGE SLUDGE INCINERATION

 2.5.1  Process Description ~
      In sewage sludge incineration,  materials generated by wastewater
 treatment  plants  are oxidized to reduce the volume of solid waste.

      In the first step in the process,  the sludge is dewatered until it is
 15  to 30 percent  solids so that  it will burn without auxiliary fuel.
 Dewatered  sludge  is  conveyed to  a combustion device where thermal oxidation
 occurs.  The unburned residual ash is removed from the combustion device,
 usually on a continuous basis, and disposed.  The exhaust: gas  stream is
 directed to an air pollution control device, typically a wet scrubber.

  ;  ^  Approximately 95 percent of sludge incinerators are multiple-hearth and
 fluidized-bed designs.   Multiple-hearth incinerators are vertically oriented
 cylindrical shells containing from 4 to 14 refractory he,arths  stacked one
 above the  other.   Sludge typically enters  at the  periphery of  the top hearth
 arid is  raked inward  by the teeth on  a rotating rabble arm to a drop hole
 leading  to the second hearth.  The teeth on the rabble arm above the second
 he'arth  are positioned in the opposite direction to move the sludge
 outward.   This outside-in,  inside-out pattern is  repeated  on alternate
 hearths.   Fluidized-bed incinerators also  are vertically oriented
 cylindrical shells.   A bed of sand approximately  0.7-meters (2.5-feet)  thick
 rests on the grid and is fluidized by air  injected through the tuyeres
 located at the base  of  the furnace within  a refractory-lined grid.   Sludge
 is  introduced directly  into the  bed.  Temperatures in a nsuitipie-hearth
 furnace are 320°C (600°F)  in the lower,  ash-cooling hearth;  760° to 1100°C
 (1400° to  2000°F)  in the central  combustion hearths;  and 540°  to 650°C
 (1000° to  1200°F)  in the upper,  drying  hearths.   Temperatures  in a
 fluidized-bed reactor are  fairly uniform,  from 680°  to  820°C (1250°  to
 1500°F).   In both types  of  furnaces, an auxiliary fuel  may be  required
 either during startup or when  the moisture  content  of the  sludge is  too  high
 to  support  combustion.         .

      Electric  (infrared) furnaces are the newest  of  the  technologies
 currently  in use  for  sludge  incineration.   The  sludge is conveyed into one
 end of the  horizontally  oriented  incinerator where  it is first dried and
 thfen  burned  as  it  travels beneath the infrared heating elements.
  i                             '                          ,
  !   Other  sludge  incineration technologies" that are no  longer in widespread
 use include  cyclonic  reactors, rotary kilns, and wet  oxidation reactors.
 Some  sludge  is coincinerated with refuse.

 2.5.2  Emissions and  Controls1'2*4

     Sludge  incinerators have the potential to emit significant quantities
 of;pollutants to the atmosphere.   One of these pollutants is particulate
matter, which is emitted because of  the turbulent movement of the combustion
 gases with respect to the burning sludge and resultant ash.  The particle
 size distribution and concentration  of  the particulate emissions leaving the
 incinerator vary widely, depending on the composition of Che sludge  being
burned and the type and operation of  the incineration process.


 9/88          -                Solid  Waste  Disposal                      2.5-1

-------
     Total particulate emissions are usually highest for a fluidized-bed
incinerator because the combustion gas velocities required to fluidize the
bed result in entrainment of large quantities of ash in the flue gas.
Particulate emissions from multiple-hearth incinerators are usually less
than those from fluidized-bed incinerators because the agitation of ash and
gas velocity through the bed are lower in the multiple-hearth
incinerators.  Electric furnaces have the lowest particulate matter
emissions because the sludge is not stirred or mixed during incineration and
air flows through the unit generally are quite low, resulting in minimal
entrainment.

     Incomplete combustion of sludge can result in -emissions of intermediate
products (e.g., volatile organic compounds and carbon monoxide).  Other
potential emissions include sulfur dioxide, nitrogen oxides, metals, acid
gases, and toxic organic compounds.

     Wet scrubbers are commonly used to control particulate and gaseous
(e.g., S0a» NOx, CO, and VOC's) emissions from sludge incinerators.  There
are two practical reasons for this:  (1) a wastewater treatment plant is a
source of relatively inexpensive scrubber water (plant effluent) and (2) a
system for the treatment of the scrubber effluent is available (spent
scrubber water is sent to the head of the treatment plant for solids removal
and pH adjustment).  The most widely used scrubber types are venturi and
impingement-tray.  Cyclone wet scrubbers and systems combining all three
types of scrubbers are also used.

     Pressure drops for venturi, impingement tray, and cyclone scrubbers are
1 to 40 kPa,.0.4 kPa per stage, and 1 to 2 kPa, respectively.  Collection
efficiency can range from 60 to 99 percent depending on the scrubber
pressure drop, particle size distribution, and particulate concentration.

     Emission factors and emission factor ratings for sludge incinerators
are shown in Table 2.5-1.  Table 2.5-2 shows the cumulative particle size
distribution and size specific emission factors for sewage sludge
incinerators.  Figures 2.5-1, 2.5-2, and 2.5-3 show the cumulative particle
size distribution and size-specific emission factors for multiple-hearth,
fluidized-bed, and electric infrared incinerators, respectively.
    2.5-2
EMISSION FACTORS
                                                                           9/88

-------
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-------
TABLE 2.5-2.  CUMULATIVE PARTICLE SIZE DISTRIBUTION AND SIZE SPECIFIC
          EMISSION FACTORS FOR SEWAGE SLUDGE INCINERATORS3
Particle
size,
microns
15

10

5.0

2.5

1.0

0.625

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Cumulative mass % < stated size
Uncontrolled Controlled
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NA 30 27 7.3 50

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NA 10 22 6.0 25

NA 6.0 20 5.0 18

NA 5.0 17 2.7 15

100 100 100 100 100

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bed.
Infrared.
Cumulative
Uncontrol
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0.30 NA
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40 NA
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2.5-4
EMISSION FACTORS
                                                                      9/88

-------
                  O.I
                 1.0               10
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9/iBB
               Solid Waste Disposal
 2.5-5

-------
1.
2.
3.
REFERENCES FOR SECTION 2.5

    Environmental Regulation and Technology;  Use and Disposal of Municipal
    Wastewater Sludge, EPA-625/10-84-003, U. S. Environmental Protection
    Agency, Cincinnati, OH, September 1984.

    Seminar Publication;  Municipal Wastewater Sludge Combustion Technology,
    EPA-625/4-85/015, U. S. Environmental Protection Agency, Cincinnati,
    OH,  September 1985.

    Written communication from C. Hester, Midwest Research Institute, Gary,
    NC, to J. Crowder, Office of Air Quality Planning and Standards, U. S.
    Environmental Protection Agency, Research Triangle Park, NC, September
    1985.                ^

4   Control Techniques for  Particulate  Emissions From Stationary Sources
    Volume  1, EPA-45/3-81-005a, U.  S. Environmental Protection Agency,
    Research Triangle Park, NC, September  1982.

5.  Draft report.  Emission Factor  Documentation for AP-42 Section  2.5—
    Sewage  Sludge Incineration, Monitoring and Data Analysis Division,
    Office  of Air Quality  Planning  and  Standards, U. S.  Environmental
    Protection  Agency, Research Triangle Park, NC,  September 1987.
     2.5-6
                                  EMISSION FACTORS
                                                                           9/88

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                                                    1 — 8'
 4.2.2.7  Polymeric Coating of Supporting.Substrates ~ j

i      "Polymeric coating of supporting substrates" is defined as a web coating
I process other than paper coating that applies an elastomer or other polymeric
i material onto a supporting substrate.  Typical substrates include woven, knit,
; and nonwoven textiles; fiberglass; leather; yarn; and cord.  Examples of
; polymeric coatings are natural and synthetic rubber, urethane, polyvinyl
| chloride, acrylic, epoxy, silicone, phenolic resins, aitid nitrocellulose.
I Plants have from 1 to more than 10 coating lines.  Most plants are commission
 coaters where coated substrates are produced according to customer
!specifications.  Typical products include rainwear, conveyor belts, y-belts,
 diaphragms, gaskets, printing blankets,  luggage, and aircraft and military
|products.  This industrial source category has been retitled from "Fabric
;Coating" to that listed above to reflect the general use of polymeric coatings
< on substrate materials including but not limited to conventional textile
'fabric substrates.                                    j

      Process description    - The process of applying a polymeric coating to a
 supporting substrate consists of mixing  the coating ingredients (including
 solvents), conditioning the substrate, applying the coating to the substrate,
 drying/curing the coating in a drying oven, and subsequent curing or
 vulcanizing if necessary.  Figure 4.2.2.7-1 is a schematic of a typical
 solvent-borne polymeric coating operation identifying volatile organic
 compound (VOC) emission locations.  Typical plants  have one or two small
 (<38 m  or 10,000 gallons) horizontal or vertical solvent storage tanks  which
 are operated at atmospheric pressure, however, some plants have as many  as
 five.  Coating preparation equipment includes the mills,  mixers,  holding
 tanks,  and pumps used to prepare polymeric coatings for application.   Urethane
 coatings typically are purchased premixed and require Little or no mixing at
jthe coating plant.  The conventional types of equipment:  for applying  organic
tsolvent-borne and waterborne coatings include knife-over-roll,  dip,  and
'reverse-roll coaters.   Once applied to the substrate,  liquid coatings are
>solidified by evaporation of the solvent in a steam-heated or direct-fired
|oven.  Drying ovens  usually are of forced-air convection  design in order to
.maximize drying efficiency and prevent a dangerous  localized buildup  of  vapor
[concentration or. temperature.   For safe  operation,  the  concentration  of
;organic vapors is usually held between 10 and 25  percent  of the lower
jexplosive limit (LEL).   Newer  ovens may  be designed for concentrations of up
jto  50 percent of the LEL through the 'addition of  monitors,  alarms,  and fail-
 safe shutdown systems.   Some coatings require subsequent  curing or vulcanizing
 in  separate ovens.

      Emissions  sources  ~  - The significant  VOC emission  sources  in a
.polymeric coating plant  include the coating  preparation! equipment,  the coating
japplication and flashoff area,  and the drying ovens.  Emissions from  the
 solvent  storage tanks  and the  cleanup area  are normally only a  small
 percentage of the total.

      In  the mixing or  coating  preparation area, VOC's are  emitted  from the
 individual  mixers  and holding  tanks  during  the following operations:  filling
 of  mixers,  transfer  of  the .coating,  intermittent  activities  such as changing
 9/88                     Evaporation Loss Sources
4.2.2.7-1

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                                EMISSION FACTORS
       9/88

-------
 the filters in the holding tanks, and mixing (if mix equipment is not equipped
 with tightly fitting covers).  The factors affecting emissions in the mixing
 area include tank size,  number of tanks, solvent vapor pressure, throughput,
 and the design and performance of tank covers.

      Emissions from the  coating application area result from the evaporation
 of solvent around the coating application equipment during the application
 process and from the exposed substrate as it travels from the coater to the
 drying oven entrance (flashoff).  The factors affecting emissions are the
 solvent content of the coating, line width and speed, coating thickness,
 volatility of the solvent(s), temperature, distance between coater and oven,
 and air turbulence in the coating area..

      Emissions from the  drying oven result from the fraction of the remaining
 solvent that is driven off in the oven.  The factors affecting uncontrolled
 emissions are the-solvent content of the coating and the; amount of solvent
 retained in the finished product.  Fugitive emissions due to the opening of
 oven doors also may be significant in some operations.  [Some plasticizers and
 reaction by-products may be emitted if the coating is subsequently-cured or
 vulcanized.  However,  emissions from the curing or vulcanizing of the coating
 are usually negligible compared to the total emissions from the operation.

 I     Solvent type and  quantity are the common factors affecting emissions from
 all the operations in  a  polymeric coating facility.   The rate of evaporation
 or drying is dependent upon solvent vapor pressure at a given temperature and
'concentration.  The most commonly used organic solvents 'are toluene,  dimethyl
 formamide (DMF),  acetone, methyl ethyl ketone (MEK),  isopropyl alcohol,
 xylene, and ethyl acetate.   Factors affecting solvent selection are cost,
 solvency, toxicity,  availability, desired rate of evaporation, ease of use
 after solvent recovery,  and compatibility with solvent recovery equipment.

 i     Emissions control '  »     - A control system for evaporative emissions
 consists of two components:  a capture device and a  control device.   The
 efficiency of the control system is determined by the efficiencies  of the two
 components.

      A capture device  is  used to contain emissions  from a  process  operation
 and direct them to a stack or to a control  device.   Covers,  vents,  hoods,  and
 partial and total enclosures  are alternative capture  devices  used  on  coating
 preparation equipment.   Hoods and partial and total  enclpsures are  typical
 capture devices for  use  in  the coating application area.   A drying  oven  can be
 considered a capture device because it both contains.and: directs VOC  emissions
 from the process.   The efficiency of  capture devices  is  variable and  depends
 upon"the quality  of  design  and the level  of operation and  maintenance.
         •  •                         -                     i
 ',     A control device  is  any  equipment that has  as its  primary function  the
 reduction of emissions.   Control devices  typically used  in this  industry are
 carbon adsorbers,  condensers,  and incinerators.   Tightly fitting covers  on
 coating preparation  equipment may be  considered  both  capture  and control
 devices.
                                                         i
                                                         i
      Carbon adsorption units  use activated  carbon to  adsorb VOC's from a  gas
 stream; the VOC's  are  later recovered  from  the carbon.  Two  types of  carbon


 9/88                      Evaporation  Loss  Sources       :             ' 4.2.2.7-3

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adsorbers are available:  fixed bed and fluidized bed.  Fixed-bed carbon
adsorbers are designed with a steam-stripping technique to recover the VOC
material and regenerate the activated carbon.  The fluidized-bed units used in
this industry are designed to use nitrogen for VOC vapor recovery and carbon
regeneration.  Both types achieve typical VOC control efficiencies of
95 percent when properly designed, operated, and maintained.

     Condensation units control VOC emissions by cooling the solvent laden gas
to the dew point of the solvent(s) and collecting the droplets.  There are two
condenser designs commercially available:  nitrogen (inert gas) atmosphere and
air atmosphere.  These systems differ in the design and operation of the
drying oven (i.e., use of nitrogen or air in the oven) and in the method of
cooling the solvent laden air (i.e., liquified nitrogen or refrigeration).
Both design types can achieve VOC control efficiencies of 95 percent.

     Incinerators control VOC emissions through oxidation of the organic
compounds into carbon dioxide and water.  Incinerators used to control VOC
emissions may be of thermal or catalytic design and may use primary or
secondary heat recovery to reduce fuel costs.  Thermal incinerators operate at
approximately 890°C (1600°F) to assure oxidation of the organic compounds.
Catalytic incinerators operate in the range of 315° to 430°C (600° to 800°F)
while using a catalyst to achieve comparable oxidation of VOC's.  Both design
types achieve a typical VOC control efficiency of 98 percent.

     Tightly fitting covers control VOC emissions from mix vessels by reducing
evaporative losses.  Airtight covers can be fitted with conservation vents to
avoid excessive internal pressure or vacuum.  The parameters affecting the
efficiency of these controls are solvent vapor pressure, cyclic temperature
change, tank size, throughput, and the pressure and vacuum settings on the
conservation vents.  A good system of tightly fitting covers on mixing area
vessels is estimated to reduce emissions by approximately 40 percent.  Control
efficiencies of 95 or 98 percent can be obtained by directing the captured
VOC's to an adsorber, condenser, or incinerator.

     When the efficiencies of the capture device and control device are known,
the efficiency of the control system can be computed by the following
equation:

    (capture efficiency)x(control efficiency)=(control system efficiency).

The terms of this equation are fractional efficiencies rather than
percentages.  For instance, a system of hoods delivering 60 percent of VOC
emissions to a 90 percent efficient carbon adsorber would result in a control
system efficiency of 54 percent (0.60x0.90=0.54).  Table 4.2.2.7-1 summarizes
the control system efficiencies that may be used in the absence of measured
data on mix equipment and coating operations.
4.2.2.7-4                     EMISSION FACTORS                            9/88

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              TABLE 4.2.2.7-1.  SUMMARY OF CONTROL EFFICIENCIES3
 ;                                                            Overall control
Control technology                                      '     efficiency,  %^

                         Coating Preparation Equipment

Uncontrolled                                            '            0

Sealed covers with conservation vents                              40
          ,.                        '                      >               -   '
Sealed covers with carbon adsorber/condenser           I           95
Coating Operationc
Local ventilation with carbon adsorber/condenser
Partial enclosure with carbon adsorber/condenser
'
i
total enclosure with carbon adsorber/condenser
Total enclosure with incinerator
81
90
93
96
aReference 1.  To be used in the absence of measured data.
 To be applied to uncontrolled emissions from indicated process, area, not
 from entire plant.                                     |
^Includes coating application/flashoff area and drying oven.

     Emissions estimation techniques ' "  - In this diverse industry,
Realistic estimates of emissions require solvent usage data.  Due to the wide
variation found in coating formulations, line speeds, and products, no
meaningful inferences can be made based simply on the equipment present.
 :                          '                             i             '
 !    Plant-wide emissions can be estimated by performing; a liquid material
balance in uncontrolled plants and in those where VOC's are recovered for
reuse or sale.  This technique is based on the assumption that all solvent
purchased replaces VOC's which have been emitted.  Any identifiable and
quantifiable side streams should be subtracted from thisi total .  The general
formula for this is:
 i                   r  solvent  i  t quantifiable  \^r  VOC
.:•                   ^-purchased'  ^-solvent output'
The first term encompasses all solvent purchased including thinners, cleaning
agents, and the solvent content of any premixed coatings^ as well as any
solvent directly used in coating formulation.  From this total, any
quantifiable solvent outputs are subtracted.  These outpiuts may include
solvent retained in the finished product, reclaimed solvent sold for use
outside the plant, and solvent contained in waste streams.  Reclaimed solvent
which is reused at the plant is not subtracted.
 9/88                      Evaporation Loss Sources                    4.2.2.7-5

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     The advantages of this method are that it is based on data that are
usually readily available, it reflects actual operations rather than
theoretical steady state production and control conditions, and it includes
emissions from all sources at the plant.  However, care should be taken not to
apply this method over too short a time span.  Solvent purchases, production,
and waste removal occur in their own cycles, which may not coincide exactly.

     Occasionally, a liquid material balance may be possible on a smaller
scale than the entire plant.  Such an approach may be feasible for a single
coating line or group of lines served by a dedicated mixing area and a
dedicated control and recovery system.  In this case, the computation begins
with total solvent metered to the mixing area instead of solvent purchased.
Reclaimed solvent is subtracted from this volume whether or not it is reused
onsite.  Of course, other solvent input and output streams must be accounted
for as previously indicated.  The difference between total solvent input and
total solvent output is then taken to be the quantity of VOC's emitted from
the equipment in question.

     The configuration of meters, mixing areas, production equipment, and
controls usually will not make this approach possible.  In cases where control
devices destroy potential emissions or a liquid material balance is
inappropriate for other reasons, plant-wide emissions can be estimated by
summing the emissions calculated for specific areas of the plant.  Techniques
for these calculations are presented below.

     Estimating VOC emissions from a coating operation (application/flashoff
area and drying oven) starts with the assumption that the uncontrolled
emission level is equal to the quantity of solvent contained in the coating
applied.  In other words, all the VOC in the coating evaporates by the end of
the drying process.  This quantity should be adjusted downward to account for
solvent retained in the finished product in cases where it is quantifiable and
significant.

     Two factors are necessary to calculate the quantity of solvent applied:
the_solvent content of the coating and the quantity of coating applied.
Coating solvent content can be directly measured using EPA Reference
Method 24.  Alternative ways of estimating the VOC content include the use of
either data on coating formulation that are usually available from the plant
owner/operator or premixed coating manufacturer or, if these cannot be
obtained, approximations based on the information in Table 4.2.2.7-2.  The
amount of coating applied may be directly metered.  If it is not, it must be
determined from production data.  These should be available from the plant
owner/operator.  Care should be taken in developing these two factors to
assure that they are in compatible units.

     When an estimate of uncontrolled emissions is obtained, the controlled
emissions level is computed by applying a control system efficiency factor:

            /•uncontrolledi  r.       ,     •     ,-•-••     i  r  VOC   i
            (    VOC      Jx(l-control system efficLencyJ=(em.tted).
4.2.2.7-6                  .   EMISSION FACTORS                            9/88

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                                                                                         1
      TABLE 4.2.2.7-2.  SOLVENT AND SOLIDS CONTENT OF POLYMERIC COATINGSa
Polymer type
Rubber
Urethanes
Acrylics
Vinylc
i
Vinyl Plastisol
Organisol ,
Epoxies
Silicone
Nitrocellulose
Typical percentage,
% solvent
50-70
50-60
- b ':
60-80
' •• 5 '. .. - , :'•":
15-40
30-40
50-60
70
by weight
% solids
30-50
40-50
50
20-40
95
60-85
60-70
40-50
30
^Reference 1.
 Organic solvents are generally not used in the formulation of acrylic
 coatings.  Therefore, the solvent content for acrylic coatings represents
 nonorganic solvent use (i.e., water).
GSolvent-borne vinyl coating.

As;previously explained, the control system efficiency is!the product of the
efficiencies of the capture device and the control device.   If these values
are not known, typical efficiencies for some combinations of capture and
control devices are presented in Table 4.2.2.7-^1.  It is important to note
that these^control system efficiencies are applicable only to emissions that
occur within the areas served by the systems.  Emissions i-rom such sources as
process wastewater or discarded waste coatings may not be[controlled at all.
   ' -                   '                      -          '"'''j-            "
   ; ^In cases where emission estimates from the mixing area alone are desired,
a slightly different approach is necessary.  Here, uncontrolled emissions will
be!only that portion of total solvent that evaporates during the mixing
process.  A liquid material balance across the mixing area  (i.e., solvent
entering minus solvent content of coating applied) would provide a good
estimate.  In the absence of any measured value,  it may b«  assumed that
approximately 10 percent of the total solvent entering the  mixing area is
emitted during the mixing process,  but this can vary widely.  When an estimate
of uncontrolled mixing area emissions has been made, the controlled emission
rate can be calculated as discussed previously.  Table 4.2.2.7-1  lists typical
overall control efficiencies for coating mix preparation equipment.
   I                               •                       i
     Solvent storage tanks of the size typically  found in this industry are
regulated by only a few States and  localities. Tank emissions are generally
9/88
Evaporation Loss Sources
                                                                      4.2.2.7-7

-------
small (<125 kg/yr).  If an estimate of emissions is desired, it can be
computed using the equations, tables, and figures provided in Section 4.3.2.

REFERENCES FOR SECTION 4.2.2.7

1.  Polymeric Coating of Supporting Substrates—Background Information for
    Proposed Standards, EPA-450/3-85-022a, U. S. Environmental Protection
    Agency, Research Triangle Park, NC, October 1985.

2.  Control of Volatile Organic Emissions From Existing Stationary Sources-
    Volume II;  Surface Coating of Cans. Coils. Paper. Fabrics, Automobiles,
    and Light Duty Trucks, EPA-45072-77-008, U. S. Environmental Protection
    Agency, Research Triangle Park, NC, May 1977.

3.  E. J. Maurer, "Coating Operation Equipment Design and Operating
    Parameters," Memorandum  to Polymeric Coating of Supporting Substrates
    File, MRI, Raleigh, NC,  April 23,  1984.

4.  Control of Volatile Organic Emissions From Existing Stationary Sources-
    Volume It  Control Methods for Surface-Coating Operations, EPA-450/2-76-
    028, U. S. Environmental Protection Agency, Research Triangle Park, NC,
    November  1976.

5.  G. Crane, Carbon Adsorption for VOC Control, U. S. Environmental
    Protection Agency, Research Triangle  Park, NC, January  1982.

6.  D. Moscone, "Thermal  Incinerator  Performance for NSPS," Memorandum, Office
     of Air Quality Planning  and Standards,  U.  S. Environmental Protection
    Agency, Research Triangle  Park, NC, June  11, 1980.

 7.   D. Moscone, "Thermal  Incinerator  Performance for NSPS,  Addendum,"
     Memorandum, Office of Air  Quality Planning and Standards,  U.  S.
     Environmental Protection Agency,  Research Triangle Park,  NC,  July 22,
     1980.

 8.   C.  Beall, "Distribution  of Emissions  Between Coating  Mix Preparation  Area
     and  the Coating Line," Memorandum to  Magnetic  Tape Coating Project File,
     MRI, Raleigh, NC,  June 22, 1984.
 4.2.2.7-8
                               EMISSION FACTORS
                                                                           9/88

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 4.12   POLYESTER RESIN PLASTICS  PRODUCT  FABRICATION

 4.12.1  General Description1"2                          !
                                                        i .
 '                                                        ' '
     A growing  number of  products  are fabricated  from liquid polyester  resin
 reinforced with glass, fibers.and extended with various Inorganic filler
 materials such  as  calcium carbonate, talc,  mica or small glass  spheres.
 These  composite materials are often referred  to as fiberglass reinforced
 plastic (FRP),  or  simply  "fiberglass".   The Society Of The  Plastics  Industry
 designates these materials as "reinforced plastics/composites"  (RP/C).  Also,
 advanced reinforced  plastics  products are now formulated with fibers  other
 than glass,  such as  carbon, aramid and  aramid/carbon hybrids.   In some
 processes, resin products are fabricated without  fibers.  One major product
 using  resins with  fillers but no reinforcing  fibers is^the  synthetic  marble
 used in manufacturing bathroom  countertops, sinks  and related items.  Other
 applications of nonreinforced resin plastics  include automobile body  filler,
 bowling balls and  coatings.

     Fiber reinforced plastics  products  have  a wide range of application in
 industry, transportation,  home  and recreation.  Industrial  uses include stor-
 age tanks, skylights,  electrical equipment, ducting,  pipes,  machine compo-
 nents,  and corrosion  resistant  structural and process  equipment.   In
 transportation,  automobile and  aircraft  applications  are increasing rapidly.
 Home and recreational  items include bathroom  tubs  and showers,  boats  (build-
 ing and repair), surfboards and skis, helmets,  swimming pools and  hot tubs,
 and a  variety of sporting goods.

 j    The thermosetting polyester resins  considered  here are  complex polymers
 resulting from  the cross-linking reaction of  a  liquid  unsaturated  polyester
 with a  vinyl type monomer, most often styrene.  The  unsaturated polyester is
 formed  from the  condensation  reaction of an unsaturated dibasic acid or
 anhydride, a saturated dibasic  acid or anhydride,  and  a polyfunctional
 alcohol.  Table  4.12-1 lists  the most common  compounds, used  for each compo-
 nent of  the polyester  "backbone",  as well as  the principal cross-linking
 monomers.  The  chemical reactions  that form both the unsaturated polyester
 and the cross-linked  polyester  resin are shown  in  Figure 4.12-1.  The emis-
 sion factors presented here apply  to fabrication processes that use the
 finished liquid  resins (as received by fabricators  from chemical manufac-
 turers), and not to the chemical processes used to produce these resins.
 (.See Chapter 5,  Chemical  Process Industry.)

     In order to be used  in the fabrication of products, the liquid resin
must be mixed with a catalyst to initiate polymerization into a solid thermo-
 set.  Catalyst concentrations generally ;range from  1 to 2 percent by original
Weight of resin; within certain limits,  the higher the catalyst  concentration,
 the faster the cross-linking reaction proceeds.  Common catalysts are organic
peroxides,  typically methyl ethyl ketone peroxide or berizoyl peroxide.
Resins may contain inhibitors, to avoid self curing during resin storage,
and promoters, to allow polymerization to occur at lower temperatures.
9/88
Evaporation Loss Sources
4.12-1

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               TABLE  4.12-1.  TYPICAL  COMPONENTS OF RESINS
                     To Form the Unsaturated Polyester
 Unsaturated  Acids
Maleic  anhydride
Fumaric acid
Saturated Acids

Phthalic anhydride
Isophthalic acid
Adipic acid
Polyfunctional Alcohols

Propylene glycol
Ethylene glycol
Diethylene glycol
Dipropylehe glycol
Neopentyl glycol
Pentaerythritol
                       Cross-linking Agents (Monomers)
                              Styrene
                              Methyl methacrylate
                              Vinyl toluene
                              Vinyl acetate
                              Diallyl phthalate
                              Acrylamide
                              2-ethyl hexylacrylate
     The polyester resin/fiberglass industry consists of many small faci-
lities (such as boat repair and small contract firms) and relatively few
large firms that consume the major fraction of the total resin.  Resin
usage at these operations ranges from less than 5,000 kilograms per year
to over 3 million kilograms per year.

     Reinforced plastics products are fabricated using any of several
processes, depending on their size, shape and other desired physical
characteristics.  The principal processes include hand layup, spray layup
(sprayup), continuous lamination, pultrusion, filament winding and various
closed molding operations.

     Hand layup, using primarily manual techniques combined with open
molds, is the simplest of the fabrication processes.  Here, the reinforce-
ment is manually fitted to a mold wetted with catalyzed resin mix, after
which it is saturated with more resin.  The reinforcement is in the form
of either a chopped strand mat, a woven fabric or often both.  Layers of
reinforcement and resin are added to build the desired laminate thickness.
Squeegees, brushes and rollers are used to smooth and compact each layer
as it is applied.  A release agent is usually first applied to the mold
to facilitate removal of the composite.  This is often a wax, which can
be treated with a water soluble barrier coat such as polyvinyl alcohol to
promote paint adhesion on parts that are to be painted.  In many operations,
4.12-2
   EMISSION FACTORS
                                                                         9/88'

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Evaporation  Loss Sources
                                                                                          4.12-3

-------
the mold is first sprayed with gel coat, a clear or pigmented resin mix
that forms the smooth outer surface of many products.  Gel coat spray
systems consist of separate sources of resin and catalyst, with an airless
hand spray gun that mixes them together into an atomized resin/catalyst
stream.  Typical products are boat hulls and decks, swimming pools, bathtubs
and showers, electrical consoles and automobile components.

     Spray layup, or "sprayup", is another open mold process, differing from
hand layup in that it uses mechanical spraying and chopping equipment for
depositing the resin and glass reinforcement.  This process allows a greater
production rate and more uniform parts than does hand layup, and often uses
more complex molds.  As in hand layup, gel coat is frequently applied to the
mold before fabrication to produce the desired surface qualities.  It is
common practice to combine hand layup and sprayup operations..

     For the reinforced layers, a device is attached to the sprayer system to
chop glass fiber  "roving" (uncut fiber) into predetermined lengths and pro-
ject it to merge with the resin mix stream.  The stream precoats the chop,
and both are deposited simultaneously to the desired layer thickness on the
mold surface (or  on the gel coat that was applied to the mold).  Layers are
built up and rolled out on the mold as necessary to form the part.  Products
manufactured by sprayup are similar to those made by hand layup, except that
more uniform and  complex parts can generally be produced more efficiently with
sprayup techniques.  However, compared to hand layup, more resin generally is
used to produce similar parts by spray layup because of the inevitable over-
spray of resin during application.

     Continuous lamination of reinforced plastics materials involves impreg-
nating various reinforcements with resins on an in-line conveyor.  The
resulting  laminate is cured and trimmed as  it passes through the various  con-
veyor zones.  In  this process, the resin mix is metered onto a bottom carrier
film, using a blade to control thickness.   This film, which defines  the pa-
nel's surface, is generally polyester, cellophane or nylon, and may have  a
smooth, embossed  or matte surface.  Methyl  methacrylate is sometimes used as
the  cross-linking agent, either alone or in combination with styrene, to
increase  strength and weather  resistance.   Chopped  glass  fibers free-fall
into the  resin mix and are allowed to saturate with resin, or  "wet out".  A
second  carrier film is applied on  top of the panel  before  subsequent forming
and  curing.  The  cured panel  is then stripped of  its films,  trimmed  and cut
to the  desired length.   Principal  products  include  translucent  industrial sky-
lights  and greenhouse panels, wall and  ceiling  liners for  food  areas,  garage
doors  and cooling tower  louvers.   Figure  4.12-2  shows the  basic elements  of
a continuous  laminating  production line.

     Pultrusion,  which can be thought  of  as extrusion by  pulling,  is used to
produce continuous  cross-sectional  lineals  similar to those  made  by  extrud-
ing metals such  as  aluminum.   Reinforcing  fibers  are pulled  through  a  liquid
resin  mix bath and  into  a  long machined steel  die,  where  heat  initiates an
exothermic reaction to polymerize the  thermosetting resin matrix.   The compo-
site profile  emerges  from the die as  a  hot, constant cross-sectional that
cools  sufficiently to be fed into a  clamping and pulling  mechanism.   The  pro-
duct can then be cut  to  desired  lengths.   Example products include electrical
insulation materials,  ladders,  walkway gratings,  structural supports,  and
 rods and antennas.
  4.12-4
EMISSION FACTORS
                                                                             9/88

-------
          Resin metering device -»
                       /cr^>\
                                              Cure area
                                                     Film .
                                                     rewind
                                 Cross cut saw or shear
                                3 trim
                                  O Q
                                                      (2 	;	' ' Pull rolls
                                                       Inspection area         j
                                                          ,  Stacking device U   i)
       Figure 4.12-2.  Typical  continuous lamination production  process.
       Filament winding is  the  process of laying a band of resin  impregnated
  fibers onto a rotating mandrel  surface in a precise geometric pattern,  and
  curing them to form the product.   This is an efficient method of  producing
 ,cylindrical parts with optimum  strength characteristics, suited  to the
 'specific design and application.   Glass fiber is most often used  for the
  filament, but aramid, graphite, and sometimes boron and various metal wires
  may be used.  The filament  can  be wetted during fabrication, or previously
 jimpregnated filament ("prepreg")  can be used.  Figure 4.12-3 shows the
  filament winding process, and indicates the three most common winding
 (patterns.  The process illustration depicts circumferential winding, while
  the two smaller pictures  show helical and polar winding.  The various wind-
 ;ing patterns can be used  alone  or in combination to achieve the desired
 jstrength and shape characteristics.  Mandrels are made of a wide  variety of
 [materials and, in some applications, remain inside the ^finished product as
 ja liner or core.  Example products are storage tanks, fuselages,  wind
  turbine and helicopter blades,  and tubing and pipe.
                                                              Helical Winding
                                                            Polar Minding
9/88
              Figure 4.12-3.  Typical filament winding process.-'
Evaporation Loss  Sources
4.12-5

-------
     Closed, such as  compression or  injection, molding  operations involve
the use of  two matched dies to define the entire outer  surface of the part.
When closed and filled with a resin  mix, the matched die mold is subjected
to heat and pressure  to  cure the plastic.  For the most durable production
configuration, hardened  metal dies are used (matched metal molding).
Another closed molding process is vacuum or pressure bag molding.  In bag
molding, a  hand layup or sprayup is  covered with a plastic film, and vacuum
or pressure is applied to rigidly define the part and improve surface
quality.  The range of closed molded parts includes tool and appliance
housings, cookware, brackets and other small parts, and automobile body and
electrical  components.

     Synthetic marble casting, a large segment of the resin products indus-
try, involves production of bathroom sinks, vanity tops, bathtubs and
accessories using filled resins that have the look of natural marble.  No >
reinforcing fibers are used in these products.  Pigmented or clear gel coat
can either  be applied to the mold itself or sprayed onto the product after
casting to  simulate the  look of natural polished marble.  Marble casting
can be an open mold process, or it may be considered a  semiclosed process
if cast parts are removed from a closed mold for subsequent gel coat spray-
ing.

4.12.2  Emissions And Controls

     Organic vapors consisting of volatile organic compounds (VOC) are emit-
ted from fresh resin  surfaces during the fabrication process and from the
use of solvents (usually acetone) for cleanup of hands, tools, molds and
spraying equipment.   Cleaning solvent emissions can account for over 36
percent of  the total  plant VOC emissions.^  There also may be some release
of particulate emissions from automatic fiber chopping  equipment, but these
emissions have not been  quantified.

     Organic vapor emissions from polyester resin/fiberglass fabrication
processes occur when  the cross-linking agent (monomer)  contained in the
'liquid resin evaporates  into the air during resin application and curing.-
Styrene, methyl methacrylate and vinyl toluene are three of the principal
monomers used as cross—linking agents.  Styrene is by far the most common.
Other chemical components of resins  are emitted only at trace levels,
because they not only have low vapor pressures but also are substantially
converted to polymers.-*"^

     Since  emissions  result from evaporation of monomer from the uncured
resin, they depend upon  the amount of resin surface exposed to the air and
the time of exposure. Thus, the potential for emissions varies with the
manner in which the resin is mixed,  applied, handled and cured.  These fac-
tors vary among the different fabrication processes.  For example, the
spray layup process has  the highest  potential for VOC emissions because the
atomization of resin  into a spray creates an extremely  large surface area
from which  volatile monomer can evaporate.  By contrast, the emission
potential in synthetic marble casting and closed molding operations is
considerably lowerr because of the lower monomer content in the casting
resins (30  to 38 percent, versus about 43 percent) and  of the enclosed
nature of these molding  operations.  It has been found  that styrene
 4.12-6
EMISSION FACTORS
9/88

-------
 evaporation  increases with  increasing  gel  time, wind  speed  and  ambient
 temperature, and  that increasing  the hand  rolling time  on a hand  layup or
 sprayup  results in  significantly  higher  styrene losses.1  :Thus, production
 changes  that lessen the exposure  of fresh  resin surfaces to the air should
 be effective in reducing these evaporation losses.        j

   ,   In  addition  to production changes,  resin formulation can be  varied to
 affect the VOC emission potential.  In general, a resin with lower monomer
 content  should produce lower emissions.  Evaluation tests with low-styrene-
 emission laminating resins  having a 36 percent styrene  content  found a 60
 to 70 percent decrease in emission levels,  compared to  conventional resins
 (42 percent styrene), with  no sacrifice  in the physical properties of the
 laminate.7  Vapor suppressing agents also  are sometimes adided to  resins to
 reduce VOC emissions.  Most vapor suppressants are paraffin waxes, stearates
 oripolymers of proprietary  composition;,  constituting up to  several weight
 percent  of the mix.  Limited laboratory  and field data  indicate that vapor
 suppressing resins  reduce styrene losses by 30 to 70 percent.^~8

   ,   Emission factors for several fabrication processes using styrene con-
 tent  resins have been developed from the results of facility source tests (B
 Rating)  and laboratory tests (C Rating), and through technology transfer
 estimations (D Rating).1  Industry experts also provided additional infor-
 mation that was used to arrive at the  final factors presented in  Table
 4.12-2.6  Since the styrene content varies over a range of  approximately 30
 to 50 weight percent, these factors are based on the quantity of  styrene
 monomer used in the process, rather than on the total amount of resin used.
 The factors for vapor-suppressed  resins are typically 30 to 70 percent of
 those for regular resins.  The factors are expressed as ranges, because of
 the observed variability in source and laboratory test results and of the
 apparent sensitivity of emissions to process parameters.

     Emissions should be calculated using actual resin monomer contents.
When specific information about the percentage of  styrene is unavailable,
 the representative average values in Table 4.12-3 should be used.  The sam-
ple calculation illustrates the application of the emission factors.
   -'                  '              -                      - I
   l   Sample Calculation - A fiberglass boat building facility
      consumes an average of 250 kg per day of styrene-containing
      resins using a combination of hand layup (75%)  and spray layup
   I   (25%) techniques.   The laminating resins for hand and spray lay-
      up contain 41.0 and 42.5 weight  percent, respectively, of styrene.
   ;   The resin used for hand layup contains a vapor-suppressing agent.
   ,
      From Table 4.12-2,  the factor for hand layup using a vapor-suppresed
      resin is 2 - 7 (0.02 to 0.07 fraction of total  styrene emitted);
   ;   the factor for spray layup is 9  - 13 (0.09  to 0.13 fraction emit-
      ted).  Assume the  midpoints  of  these emission factor  ranges.

   j   Total VOC emissions  are:

   ,      (250 kg/day) [(0.41)(0.045)(0.75)  + (0.425)(0.11)(0.25)]

                            =6.4  kg/day.

 9/88                   Evaporation Loss Sources                     4.12-7

-------
       TABLE 4.12-2.  EMISSION FACTORS  FOR UNCONTROLLED  POLYESTER RESIN
                        PRODUCT FABRICATION PROCESSES3
              (100 x  mass  of  VOC emitted/mass  of monomer  input)
Process
Hand layup
Spray layup
Continuous lamination
Pultrusiond
Filament windings
Marble casting
Closed moldingg
Resin
NVS
5-10
9-13
4-7
4-7
5-10
1-3
1-3
VSb
2-7
3-9
1-5
1 - 5
2-7
1 - 2
1-2
Emission
Factor
Rating
C
B
B
D
D
. B
D
Gel Coat
. NVS
26 - 35
26 - 35
c
c
c
f
c
VSb
8-25
8-25
c
c
c
f
c
Emission
Factor
Rating
D
B
—
—
—
—
— ' ' .
aReference 9.Ranges represent the variability of processes and sensiti-
 vity of emissions to process parameters.  Single value factors should be
 selected with caution.  NVS = nonvapor-suppressed resin.  VS = vapor-sup-
 pressed resin.
^Factors are 30-70% of those for nonvapor-suppressed resins.
cGel coat is not normally used in this process.
"Resin factors for the continuous lamination process are assumed to apply.
eResin factors for the hand layup process are assumed to apply.
*Factors unavailable.  However, when cast parts are subsequently sprayed
 with gel coat, hand and spray layup gel coat factors are assumed to apply.
gResin factors for marble casting, a semiclosed process, are assumed to
 apply.

             TABLE 4.12-3.  TYPICAL RESIN STYRENE- PERCENTAGES
             Resin Application
                                        Resin Styrene Contents
                                              (wgt. %)
             Hand layup
             Spray layup
             Continuous lamination
             Filament winding
             Marble casting
             Closed molding

             Gel coat
                                                   43
                                                   43
                                                   40
                                                   40
                                                   32
                                                   35

                                                   35
4.12-8
              vary by at  least  +5  percentage points.
                               EMISSION FACTORS
9/88

-------
      Emissions from use of gel coat would be calculated in the same manner,
 If the monomer content of the resins were unknown, a representative value
 of 43 percent could be selected from Table 4.12-3 for this process combina-
 tion.  It should be noted that these emissions represent evaporation of
 styrene monomer only, and not of acetone or other solvents used for clean-
 up.
                                                          .  i  ,    • -
     , In addition to process changes and materials substitution, add-on con-
 trol equipment can be used to reduce vapor emissions from styrene resins.
 However, control equipment is infrequently used at RP/C fabrication facili-
 ties, due to low exhaust VOC concentrations and the potential for contami-
 nation of adsorbent materials.  Most plants use forced ventilation techni-
 ques to reduce worker exposure to styrene vapors, but vent the vapors
 directly to the atmosphere with no attempt at collection.  At one contin-
 uous lamination facility where incineration was applied to vapors vented
 from the impregnation table, a 98.6 percent control efficiency was mea-
 sured. 1  Carbon adsorption, absorption and condensation also have been
 considered for recovering styrene and other organic vapors,  but these tech-
 niques have not been applied to any significant extent in this industry.

      Emissions from cleanup solvents can be controlled through good  house-
 keeping and use practices, reclamation of spent solvent, and substitution
 with water based solvent substitutes.


 References for Section 4.12

 1.  M. B. Rogozen,  Control Techniques for Organic Gas Emissions from Fiber-
     glass Impregnation and Fabrication Processes,  ARB/R-82/165, California
     Air Resources Board,  Sacramento, CA,  (NTIS PB82-251109),  June 1982.

 2.  Modern Plastics Encyclopedia,  1986-1987, j>3_ (10A),  October 1986.

 3.  b.  A. Brighton, G.  Pritchard  and G.  A.  Skinner,  Styrene  Polymers;
     Technology and  Environmental  Aspects,  Applied  Science Publishers,  Ltd.,
     London,  1979.

 4.  M.  Elsherif,  Staff  Report,  Proposed  Rule 1162  -  Polyester Resin
     Operations,  South Coast  Air Quality  Management District,,  Rule Develop-
     ment  Division,  El Monte,  CA,  January 23, 1987.

 5.  M.  S.  Crandall,  Extent of  Exposure to  Styrene  in  the Reinforced Plastic
     Boat  Making  Industry,  Publication No.  82-110,  National Institute For
     Occupational  Safety And  Health,  Cincinnati, OH, March  1982.

 6.  Written  communication  from R. C.  Lepple, Aristech Chemical  Corporation,
     Polyester  Unit,  Linden,  NJ, to A. A. MacQueen, U.S.  Environmental  Pro-
     tection  Agency,  Research Triangle Park, NC, September 16,  1987.
                                                            I
 7.   L. Walewski  and  S.  Stockton,  "Low-Styrene-Emission Laminating Resins
     Prove  It in  the Workplace", Modern Plastics, j>2_(8) :78-80, August 1985.
9/88
Evaporation Loss Sources
                                                                     4.12-9

-------
8.  M. J. Duffy, "Styrene Emissions - How Effective Are Suppressed
    Polyester Resins?", Ashland Chemical Company, Dublin, OH, presented
    at 34th Annual Technical Conference, Reinforced Plastics/Composites
    Institute, The Society Of The Plastics Industry, 1979.

9.  G. A. LaFlam, Emission Factor Documentation for AP-42 Section 4.12;
    Polyester Resin Plastics Product Fabrication, Pacific Environmental
    Services, Inc., Durham, NC, November 1987.
 4.12-10
EMISSION FACTORS
9/88

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 5.0.5  SOAP AND DETERGENTS                                j

 5.15.1  Soap Manufacture                                 ;

 Process Description2 - Soap may be manufactured by either batch or continuous
 process, using either the alkaline saponification of natural fats and oils or
 the direct saponification of fatty acids.  The kettle, or full boiled, method
 is, a batch process of several steps, in either a single kettle or a series of
 kettles.  Fats and oils are saponified by live steam boiling in a caustic
 solution, followed by "graining", which is precipitating the soft curds of soap
 out of the aqueous lye solution by adding sodium chloride (salt).  The soap so-
 lution then is washed to remove glycerine and color body impurities,  to leave
 the "nea't" soap to form during a settling period.   Continuous alkaline saponi-
 ficatxon of natural fats and oils follows the same steps as batch processing,
 but it eliminates the need for a lengthy process time.  'Direct saponification
 ofifatty acids is also accomplished in continuous  processes.  Fatty acids
 obtained by continuous hydrolysis usually are continuously  neutralized with
 caustic soda in a high speed mixer/neutralizer to  form soap.
                                                          j
      All soap is  finished for consumer use in such varied forms  as  liquid,
 ponder,  granule,,chip, flake or bar.
   1                             '                          " !
 Emissions And Controls2 - The main atmospheric pollution problem in the manu-
 facture  of soap is odor.   Vent lines,  vacuum  exhausts,  product and  raw material
 storage,  and waste streams  are all potential  odor  sources.   Control of  these
 odors may be achieved by  scrubbing%all exhaust fumes  and, lif necessary,  inciner-
 ating the  remaining compounds.   Odors  emanating from  the  spray dryer may  be
 controlled by scrubbing with an acid solution.
                                                          I     >
   !   Blending,  mixing,  drying,  packaging  and  other physical  operations  all may
 involve  dust emissions.   The production of soap powder  by spray  drying  is the
 largest  single  source  of  dust  in the manufacture of soap.  Dust  emissions from
 other finishing operations "can be controlled  by dry filters  such as baghouses.
 The large  sizes of  the  particulate  from soap  drying mean  that high efficiency
 cyclones  installed in series can give  satisfactory control.

 5.1,5.2  Detergent  Manufacture

 Process Description1"3  -  The manufacture  of spray dried detergent has three
main  processing steps,  slurry  preparation,  spray drying and  granule handling.
Figure 5.15-1 illustrates the various operations.  Detergeidt slurry is produced
by blending  liquid surfactant with  powdered and liquid materials  (builders and
oth^r additives) in a closed mixing tank called a crutcher.   Liquid surfactant
used  in making the  detergent slurry is  produced by the sulfonation, or sulfa-
tioh by sulfuric acid, of either a linear alkylate or a fatty acid, which is
then neutralized with caustic solution  (NaOH).  The blended slurry is held in a
surge vessel for continuous pumping to a spray dryer.  The slurry is "sprayed at
high pressure into  a vertical drying tower having a stream of hot air of from
315° to 400°C (600° to 750°F).  Most towers designed for detergent production
are countercurrent, with  slurry  introduced at the top and heated air introduced
at the bottom.  The detergent granules  thus formed are conveyed mechanically
or by air 'from the  tower  to a mixer, to incorporate additional dry or liquid
ingredients, and finally to packaging and storage.
9/88
                           Chemical Process Industry                     5.15—1

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 5.15-2
                                  EMISSION  FACTORS
                                                                                 9/88

-------
 Emissions And ControlS2-3 - In the batchi   and mix-           d   £    d-

 cr\tc°hrrrs   Fa'br   f-ieriSSi°nS ^ S^*^ at "<*« *°Ppers, mixers'and
 dust emiskons but  1   T *" "^  ^ ^ tO redUC6 °r tO eliminate the
 dust emissions but also to recover raw materials.  Emission factors for parti-
 culate  from spray drying operations are shown in Table 3.15-1.  Table".?"?
 on wh'ghre f      -giVe SiZS sPecific  P^ticulate emission! factors for operations
 on;which  information is available.  There is  also a minor source of volatile
 organics  when the product being sprayed contains organic materials with low
 vapor pressures.   These vaporized  organic materials condense  in  the tower
 exhaust air stream into,droplets or particles.            !

  •   Dry  cyclones  and  cyclonic  impingement: scrubbers are  the  primary  collection
 equipment employed to  capture  the  detergent dust in the  spray dryer exhauster
 return to  process.   Dry cyclones are used., in parallel or in  series,  to collect
 particulate .(detergent  .dust) and to recycle it  back to  the  crutcher  Syclonic
 impinged  scrubbers are  used, in parallel, to collect the particulS  from a
 scrubbing  slurry  and to recycle it to the crutcher.  Secondary collection equip-
 devices ""£«£  -°lleCt  the flne P*rticulate ««* **s escaped^rom  the primary"
 devices.   Cyclonic impingement scrubbers are often  followed by mist eliminators
and dry cyclones are followed by fabric filters  or  scrubber/electrostatic      '
precipitator units.  Conveying, mixing and packaging of detergent granules can
cause dust emissions.   Usually, fabric filters provide the beft control.
    TABLE 5.15-1.   PARTICULATE EMISSION FACTORS FOR DETERGENT SPRAY DRYING*

                         .  EMISSION FACTOR RATING:   B
	 • — • 	 	 	 _. 	 _ 	 	 	 — 	 	 '
i ' i . , : —
! . . ' Particulate
i



Control
device
Uncontrolled
Cyclone*5
Cyclone
w/Spray chamber
w/Packed scrubber
w/Venturi scrubber
w/Wet scrubber
w/We-t scrubber /ESP
Fabric filter
aReferences 4-8. VOC
Efficiency kg/Mg of
(^) product
45
85 7
92 3.5
95 2.5
97 1.5
99 ' 0.544
99.9 0.023
99 o.54
emissions data have not been r^nnrt
Ib/ton of
product
90
14
'
7
1.08
0.046
'.1
-O/-I T n f-V*^*
                                                          _
                           aPPlicable'  ESP = electrostatic precipitator.
        type of primary collector,  such as a cyclone,  is considered integral
   to a spray drying system.         -                     '             =5^-^^-
 9/88
Chemical Process Industry
                                                                        5.15-3

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                                      EMISSION FACTORS
                                                                           9/88

-------
  References  for Section 5.15
           Pollutant  Emission  Factors.  APTD-0923,  U. S. Environmental  Protection
      Agency, Research  Triangle  Park,  NC, April 1970.

   2<  Air  Pollution  Engineering  Manual,  AP-40, U.  S.  Environmental  Protection
   ;   Agency, Research  Triangle  Park,  NC, May  1973.  Out Of  Print.
   -
   ?*  Source Category Survey; Detergent Industry. EPA-450/3-80-030,  U. S, Envi-
   ;   ronmental Protection  Agency,  Research  Triangle  Park,  NG,  June  1980.

   *).  A. H.  Phelps,  "Air Pollution Aspects Of  Soap And Detergent Manufacture"
   :   Journal Of The Air Pollution Control Association, J.7(8):505-507, August
   :   X .7 O / •                                  ,
   i
   5..  R. N. Shreve, Chemical Process  Industries, Third Edition, New York, McGraw-
      Hill, 1967.

   6.  G. P. Larsen, et al.,  "Evaluating Sources Of Air Pollution", Industrial And
   i   Engineering Chemistry. 4JK 1070-1074, May 1953.              ~ -

  V  1°?' McCormick> et al«> "Gas-solid Systems", Chemical Engineer's Handbook.
   1   McGraw-Hill  Book Company,  New York,  1963.           - --

  8.  Communication  from Maryland State  Department Of  Health,  Baltimore   MD
      November 1969.
                                                    .
   i                                         •
  9'  Em*ssion Test Report,  Witco Chemical Corporation.  Patterson. NJ.  EMB-73-
   :   DET-6, U.  S.  Environmental Protection Agency, Research Triangle  Park,  NC
      July  1973.
                                                          i
 10;*  Emission Test Report,  Lever Brothers,  Los Angeles.  CA.  EMB-73-DET-2  U.  S
      Environmental Protection Agency,  Research Triangle  Park, NC,  April 1973.'

 11|*  Emission Test Report,  Procter and Gamble,  Augusta. GA.  EMB-72-MM-10, U.  S.
      Environmental Protection Agency,  Research Triangle "Park,  NC,  June' 1972."

 12 '  Em*ssion Test Report,  Procter and Gamble.  Long Beach.: CA.  EMB-73-DET-4,
   i   U. S.  Environmental  Protection Agency, Research  Triangle Park,  NC, April
      JL y / j *

 13t   Emission Test Report, Colgate-Palmolive, Jeff ersonville.  IN. EMB-73-DET-7
      U. S.  Environmental  Protection Agency,  Research Triangle Park,  NC,  June


 14*;  Emission Test Report.  Lever Brothers, Edgewater, NJ,  EMB-72-MM-9,  U.   S.
     Environmental Protection Agency,  Research Triangle  Park, NC,  June  1972.*
9/88                     Chemical Process Industry        j               5.15-5

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-------
 6.4  GRAIN ELEVATORS AND PROCESSING PLANTS               '

 6.4.1  General1"3                                        I

   |   Grain elevators are facilities at which grains are received, stored, and
 then distributed for direct use, process manufacturing, or export.  They can
 be( classified as either "country" or "terminal" elevators, with terminal
 elevators further categorized as inland or export (marine) types.  Operations
 other than storage often are performed at elevators, such as cleaning, drying
 and blending.  The principal grains handled include wheat; milo, corn, oats
 rice and soybeans.                              .                          '
   I                 .

   j   Country elevators are generally smaller elevators that receive grain by
 truck directly from farms during the harvest season.  These elevators some-
 times clean or dry grain before it is transported to terminal elevators or
 processors.   Terminal elevators dry, clean,  blend and store grain for ship-
 ment to other terminals or processors,  or for export.  These elevators may
 receive grain by truck, rail or barge,  and they have significantly greater
 grain handling and storage, capacities  than do country elevators.  Export
 elevators are terminal elevators that  load grain primarily onto ships for
 export.
                                                          i
      The first step at a grain elevator is the unloading cif the incoming
 truck,  railcar or barge. A truck discharges  its grain into a hopper, usually
 below grade,  from which the grain is conveyed to the main part of  the eleva-
 tor.  Barges  are unloaded by a bucket  elevator (marine leg) that is  extended
 down into the hold.   The main building  at an elevator, where grain is elevated
 and  distributed,  is called  the "headhouse".   In the  headhouse,  grain is lifted
 on one  of the elevator legs and discharged onto the  gallery belt,  which con-
 veys  the grain to the  storage bins,  or  silos.   A "tripper"  diverts grain into
 the  desired bin.   Grain is  often cleaned  and/or dried  before storage.   When
 ready for shipping, grain is  discharged from  bins onto the  tunnel  belt  below,
 which conveys  it  to the scale garner and  on to  the desired  loadout location.
 Figure  6.4-1  illustrates  the  basic elements of  an export terminal  elevator.

   ;  A  grain  processing plant (mill) receives grain  from an elevator  and  per-
 forms various  manufacturing steps that  produce  a finished food  product.
 Examples  of these plants  are  flour mills,  animal feed  mills, and producers  of
 edible  oils,  starch, corn syrup, and cereal products.   The  elevator operations
 of -unloading,  conveying and storing also  are performed  at mills.

 6.4.2  Emissions And Controls*                            !
   i                                                       !
                                                                         1
   t           .                            •
   j  The  only pollutant emitted in significant  quantities from grain eleva-
 tors and  processing operations is particulate matter.   Small amounts of
 combustion products from natural gas fired grain dryers also may be emitted.
Grain elevators and grain processing operations can be considered separate
categories of the industry when considering emissions.
9/88
                                   I
Food And Agricultural Industry                   6.4-1

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                                                                         o

                                                                         B1
                                                                         
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 6.14.2.1   Grain Elevators  - Emissions  of  fugitive  dust  occur whenever quanti-
 ties  of  grain are set into motion during loading, conveying,  transfer,  drying
 or  cleaning  operations  at a grain elevator.   The  emission rate  can be
 affected by  the quantity  of foreign material  in the  grain (dirt,  seeds,
 sticks,  stones, etc., known as  "dockage") and by  the type of  grain.  While  it
 is  difficult to quantify  the effect of dockage, observations  indicate that
 soybeans, oats and sorghum are  usually very dusty, whereas wheat  and corn are
 comparatively clean.4 Total particulate  emission  factors  for  the  principal
 operations at grain  elevators are presented in Table 6.4-1.   Since data dif-
 ferentiating these emission factors by grain  type are  spaicse, all of these
 factors  are  approximate average values intended to apply  to a variety of
 grains.   Tables 6.4-2,  6.4-3 and 6.4-4,  and Figures  6.4-2; 6.4-3  and 6.4-4,
 show  particle size distributions and  size specific emission factors for three
 operations at grain  elevators.                            !

  i    The emission factors  in Table 6.4-1 represent the amount of  dust genera-
 ted per  unit weight  of  grain processed through each  uncontrolled  operation.
 Since the amount of  grain passing through each individual operation is  often
 difficult to determine, it  is sometimes  convenient to  express the emission
 factors  in terms of  the quantity of grain received or  shipped by  the eleva-
 tor.  (It is assumed that  the amounts shipped and received are equal over the
 long  run.)   Therefore,  the  factors in Table 6.4-1 have been modified and are
 expressed in Table 6.4-5  as  a function of the amount of grain received  or
 shipped.  The ratios shown in Table 6.4-5 are approximate values  based  on
 averages for bin turning,  cleaning and drying in each  elevator category.
 However, because operating  practices  at  individual elevators are  different,
 these ratios, like the emission factors themselves, may lack precision
 when  applied to an individual elevator.

  i   The factors in  Tables  6.4-1 and  6.4-5 should not  be  added together in
 order to obtain a single  overall emission factor for a grain elevator
 because, in most elevators,  the emissions from some  operations are controlled
 and others are not.  Therefore, emissions estimations  generally should  be
 undertaken for each  operation and its associated control  device.

      Several methods are available to reduce  or control dust emissions at
 grain elevators.  Since most emissions are generated when air passes swiftly
 through  a mass of grain, measures that slow down grain transfer (conveying)
 rates or that reduce free fall  distances will  reduce emissions.  Bulk grain,
 especially when falling through*the air, should be protected from significant
 air currents or wind sources.  Many operations at elevators are partially or
 totally enclosed (e. g., screw conveyors, drag conveyors, elevator legs) to
 isolate generated dust from the atmosphere.   Hooding in the vicinity of some
 operations (e. g., grain unloading,  conveyor  transfer poiuits) collects gener-
ated dust by creating a negative pressure area (through suction, or air
aspiration) near the center of activity and then ducting the dusty air to a
 control  device.  Recent developments in the control of ship and" barge loading
 operations include the use of "dead boxes" and tent controls.  The dead box
isja baffled attachment on the loading spout  that serves  to reduce the speed
 of[the falling grain before it reaches the open air and strikes the grain
pile.  Aspiration to a control device often accompanies the use of the dead
box.  Large flexible covers connected to the loading spout and aspiration
ducting, called tents,  are used to cover the holds of ships during most of a
loading operation.  The tent must be removed during topping off (usually
9/88
Food And Agricultural Industry
6.4-3

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             TABLE 6.4-1.  TOTAL PARTICULATE EMISSION FACTORS' FOR
                         UNCONTROLLED GRAIN ELEVATORS3

                          EMISSION FACTOR RATING:  B
Type of Operation
Country elevators
Unloading (receiving)
Loading (shipping)
Removal from bins (tunnel belt)
Drying^
Cleaning0
Headhouse (legs)
Inland terminal elevators
Unloading (receiving)
Loading (shipping)
Removal from bins (tunnel belt)
Dryingb
Cleaning0 ;
Headhouse (legs)
Tripper (gallery belt)
Export elevators
Unloading (receiving)
Loading (shipping)
Removal from bins (tunnel belt)
Drying15
Cleaning0
Headhouse (legs)
Tripper (gallery belt)
Total particulate
kg/Mg

0.3
0.2
0.5
0.4
1.5
0.8

.0.5
0.2
0.7
0.6
1.5
0.8
0.5

0.5
0.5
0.7
0.5
1.5
0.8
0.5
Ib/ton

.0.6
0.3
. 1.0
0.7
3.0
1.5

1.0
0.3
1.4
1.1
3.0
1.5
1.0

1.0
1.0
1.4
1.1
3.0
1.5
1.0
^Expressed as weight of dust emitted/unit weight of grain handled by each
 operation.  For inland terminal and export elevators, Reference 5; for dry-
 ing, References 2, 6; for country elevators, Reference 5 and additional test
 data in References 7-10.
^References 6, 11.  Based on 0.9 kg/Mg for uncontrolled rack dryers and 0.15
 kg/Mg for uncontrolled column dryers, prorated on the basis of the distribu-
 tion of these two types of dryers.
Reference 11.  Average of values, from < 0.3 kg/Mg for wheat to 3.0 kg/Mg
 for corn.
6.4-4
EMISSION FACTORS
9/88

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                TABLE 6.4-2.   PARTICLE SIZE DISTRIBUTION AND EMISSION
                        FACTORS  FOR UNCONTROLLED RICE  DRYERS*

                           EMISSION FACTOR RATING:  D
            Aerodynamic particle
               diameter (um)
            Cumulative weight
              < stated size
Emission factor'3
   (kg/Mg)
2.5
6.0
10.0
15.0
Total particulate
References 1, 12.
0.8 0.0012
2.6
7.7
24.5

0.0039
0.012
0.037
0,15C

           Expressed  as cumulative weight  of  particulate < corresponding
            particle size/unit weight of rice  dried.      ~
           cReference  11.
9/8,8,
                     99.9
                   M

                   V
                      10

                      5

                      2
                      1



                     0.1
        UNCONTROLLED
        Height percent
        Emission factor
                                                         0.03
                                                         0.02
                                  5     10   20      50

                               Particle diameter, um
              Figure 6.4-2.  Cumulative  size  distribution and
               emission factors for uncontrolled  rice dryers.
Food And Agricultural Industry
                                                                          6.4-5

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               TABLE 6.4-3.   PARTICLE SIZE DISTRIBUTION AND EMISSION
                 FACTORS  FOR CONTROLLED BARGE UNLOADING/CONVEYING3

                          EMISSION FACTOR RATING:  D
           Aerodynamic particle .
              diameter (urn)
   Cumulative weight %
     < stated size
Emission factor^3
  (kg/Mg)
2.5
6.0
10.0
Total particulate
4.0
11.0
18.0

0.00013
0.00037
0.00054
0.003C
           aReference  13.   Control is by fabric filter.
           ^Expressed  as cumulative weight of particulate ^ corresponding
            particle size/unit weight of grain unloaded/conveyed.
           cTotal mass  emission factor is from Reference 1.
                     99.9  -
                                                        - 600
                               CONTROLLED
                             <  Height percent
                            	 Emission factor
                                  0.5    12

                                Particle diameter, urn
                Figure  6.4-3.   Cumulative size distribution and
          emission factors  for controlled barge unloading/conveying.
6.4-6
EMISSION FACTORS
                9/88

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                 TABLE 6.4-4.  PARTICLE  SIZE DISTRIBUTION ,AND EMISSION
                         FACTORS FOR UNCONTROLLED SHIPLOAEUNG3
                            EMISSION FACTOR RATING:  C
            Aerodynamic particle   Cumulative weight %    Emission factorb
               diameter (urn)

2.5
6.0
10.0
15.0
Total particulate
10.4
27.0
Vu-g/ng,;
0.05
0.13
42.0 0.21
53.0

0.26
0.50C
                          ,       .
            Expressed  as cumulative weight  of  particulate <_ corresponding
             particle size/unit weight of grain loaded onto ships.
            cReference  11.
9/88
                      99.9
                       99
•o

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              TABLE  6.4-5.   TOTAL  PARTICULATE  EMISSION FACTORS FOR
          GRAIN ELEVATORS,  BASED ON AMOUNT OF  GRAIN RECEIVED OR SHIPPED3

                           EMISSION  FACTOR RATING:   C
Typo of Operation
Country elevators
Unloading (receiving)
Loading (shipping)
Removal from bins (tunnel belt) .
Dryingd
Cleaning*
Hcadhouse (legs)
Inland terminal elevators
Unloading (receiving)
Loading (shipping)
Removal from bins (tunnel belt)
Drying*
Cleaning0
Hcadhouse (legs)
Tripper (gallery belt)
Export elevators
Unloading (receiving)
Loading (shipping)
Removal from bins (tunnel belt)
Dryingd
Cleaning6
Headhouse (legs)
Tripper (gallery belt)
Emission factor,
kg/Mg handled1*

0.3
0.2
0.5
0.4
1.5
0.8

0.5
0.2
0.7
0.6
1.5
0.8
0.5

0.5
0.5
0.7
0.5
1.5
0.8
0.5
X























Typical ratio of grain
processed to grain
received or shipped0

1.0
1.0
2.1
0.3
0.1
3.1

1.0
1.0
2.0
0.1
0.2
3.0
1.7

1.0
1.0
1.2
0.01
0.2
2.2
1.1
=























Emission factor,
kg/Hg received
or shipped

0.3
0.2
1.0
0.1
0.2
2.5

0.5
0.2
1.4
0.1
0.3
2.3
0.8

0.5
0.5
0.8
0.01
0.3
1.7
0.6
*>to obtain units of Ib/ton,  multiply factors by 2.0.
cRcfcrence 6.  Average values from a survey of elevators across  the U. S.
 for any individual elevator or group of elevators in the same locale.
dSeo Note b in Table 6.4-1.
eSoc Note c in Table 6.4-1.
                             Can be considerably different
6.4-8
EMISSION FACTORS
9/88

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about 25 percent of  the  total  loading), allowing essentially uncontrolled
emissions  to escape.                                    j
i                                                        i
     Most  elevators  utilize particulate control devices on  at least  some of
their operations.  The traditional form of control at  elevators has  been
mechanical  collectors, or  cyclones.  Cyclones collect  particles larger  than
about 10 microns with only 85  to 95 percent control efficiency, often
producing  visible emissions.   Hence, fabric filters are usually selected in
areas having more stringent control requirements.  Typical  efficiencies for
well operated fabric filters exceed 99 percent, with no visible emissions.
The air aspirated from enclosed equipment and hoods is ducted to a fabric
filter or,  in some cases,  one  or more cyclones.  Rarely are other particulate
control devices, such as wet scrubbers and electrostatic precipitators,
applied at  elevators.  Grain dryers present a different sort of control
problem because of the large volumes of warm, moist air exhausted.  Most
dryers are  enclosed with a continuously vacuumed polyester  or stainless steel
screening  to collect particulate, with the vacuum usually discharged to a
cyclone.  Two principal  dryer  configurations, rack and column, are in use.
The majority of dryers manufactured today are of the column type, which has
considerably lower emissions than the rack type.16
                                                        i
6.4.2.2  Grain Processing  Plants - Several grain milling operations, such as
receiving,  conveying, cleaning and drying, are similar to those at grain
elevators.  In addition  to these, breaking down (milling) the grain or grain
by-products for processing through various types of grinding operations is a
further source of emissions.  The hammermill is the most: widely used grinding
device at feed mills.  Product is recovered from the hammermill with a
cyclone collector, which can be a major source of dust esmissions.  Again,
like elevators, mills use  a combination of cyclones and fabric filters to
conserve product and to  control emissions.  Drying at a grain mill is accom-
plished using several types of dryers, including fluidizied  bed dryers (soy-
bean processing) and flash fired or direct fired dryers (corn milling).
These newer dryer types might have lower emissions than the traditional rack
or column dryers, but data are. insufficient at this time to quantify the
difference.  The grain pre-cleaning often performed before  drying also likely
serves to reduce emissions.  Emission factors for various grain milling and
other processing operations are presented in Table 6.4-6, and the particle
size distribution and size specific emission factor for a roaster operation
are shown in Table 6.4-7 and Figure 6.4-5.  The origins of  these emission
factors are discussed below.        ,

1     Emission factor data  for feed mill operations are sparse.  The factors
for receiving, shipping and handling are based on estimates made by experts
within the feed industry.17  The remaining feed mill factors are based on test
data in References 2, 18 and 19.
i                       "
     The roasting of carob kibble (or pods),  which are ground and used as a
Chocolate substitute, is similar to coffee roasting.  The emission factor and
particle size distribution for this operation were derived from References 20
and 21.
                                                        i
I     Three emission areas for wheat mill processing operations are grain
receiving and handling, cleaning house and milling operations.  Data from
Reference 5 were used to estimate emission factors for grain receiving and

9/88                    Food And Agricultural Industry                  6.4-9

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            TABLE 6.4-6.  TOTAL PARTICIPATE EMISSION FACTORS FOR
                 UNCONTROLLED GRAIN PROCESSING OPERATIONS*

                         EMISSION FACTOR RATING:  D
Type of Operation
Feed mills
Receiving
Shipping
Handling
Grinding
Hamme rail lingb
Flakingb
Crackingb
Pellet cooler^
Carob kibble roasting
Wheat milling
Receiving
Precleaning and handling
Cleaning house
Mill house
Durum milling
Receiving
Precleaning and handling
Cleaning house
Mill house
Rye milling
Receiving
Precleaning and handling
Cleaning house
Mill house
e
Oat milling
Rice milling
Receiving
Precleaning and handling
Drying^
Cleaning and mill house
Emission factor
kg/Mg

1.3
0.5
2.7
O.lc»d
O.lc
_ •[
0.01c»d
0.2C
3.0
0.5
2.5
—•
35.0
0.5
2.5
^
.
0.5
2.5
—
35.0
1.25

0.32
2.5
0.15
—
Ib/ton
2p
.5
1.0
5.5
0 2^* »^*
«. A*i
0.2d
o!4e
6.0
1.0
5.0
~™
70.0
1.0
5.0
"

1.0
5.0
•"•
70.0
2.5

0.64
5.0
0.30
H>
6.4-10
EMISSION FACTORS
9/88

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                            TABLE  6.4-6  (concluded).
Type of Operation
Soybean milling
Receiving
Handling
Cleaning
DryingS
Cracking and dehulling
Hull grinding
Bean conditioning
Flaking
Meal dryer
Meal cooler
Bulk loading
)ry corn milling
Receiving
DryingS
Precleaning and handling
Cleaning house
Degerming and milling
Jet corn milling
Receiving
Handling
Cleaning
Dryingh
Bulk loading

Emission factor
kg/Mg

0.8
2.5
_
3.6
1.7
1.0
0.05
0.29
0.75
0.9
0.14

0.5
0.25
2.5
3.0
-
0.5
2.5
3.0
0.24
—

Ib/ton

1.6
5.0

7.2
3.3
2.0
0.1
0.57
1.5
1.8
0.27

1.0
0.5
5.0
6.0

1.0
5.0
6.0
0.48


                        	*	*•* ^*" • *-"*-o   *•*•*- '-*>*-*«•» i- cuu_ u ucu/ unx u wtsj_y llL.  \
 grain entering  the  plant,  not  necessarily the same as amount of material
^processed by each operation.  Dash = no data.          j
^Expressed as weight of  dust emitted/unit  weight of grain processed.
cWith cyclones.
 Measured on corn processing operations at feed mills.
^Represents several  sources at  one plant,  some controlled with cyclones and
 others with fabric  filters.
fAverage for uncontrolled  column dryers; see Table 6.4-2.
SDryer types unknown.
kFor rotary steam tube dryers.
9/88
Food And Agricultural Industry
                                                                        6.4-11

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               TABLE 6.4-7.  PARTICLE SIZE  DISTRIBUTION AND EMISSION
                   FACTORS FOR UNCONTROLLED  CAROB KIBBLE ROASTERS3

                              EMISSION FACTOR RATING:   E
           Aerodynamic particle
              diameter (urn)
   Cumulative weight
     < stated size
Emission factor^
  (kg/Mg)
2.5
6.0
10.0
15.0
0.6
0.7
2.0
11.5
0.018
0.021
0.060
0.35
           Total particulate
                               3.QC
           aReference 18.
           ^Expressed as cumulative weight  of  particulate _< corresponding
            particle  size/unit weight of carob kibble roasted.
           Reference 21.
                      99.9
                       99
                    S
                    •H
                    V
                    8-5
                       SO
                                UNCONTROLLED
                             —^— Weight percent
                             	Emission factor
                                         I	li  11
                                                          0.10
                             2      5    10    20     50    100

                                 Particle diameter, urn
                Figure 6.4-5.  Cumulative size  distribution and
           emission factors for uncontrolled  carob kibble roasters.
6.4-12
EMISSION FACTORS
                9/88

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 Dandling.   Data for the cleaning house are insufficient to estimate an emis-
 sion faptor,  and information contained in Referenced wias used to estimate the
 emission factor for milling operations.  The large emission factor for the
 milling operation applies to uncontrolled operations.  Almost all of the
 sources involved, however, are equipped with control devices to prevent
 product losses.  Fabric filters are widely used for this purpose.

 ,     Durum and rye milling operations  are similar to those for wheat milling.
 Therefore,  most of these emission factors are assumed equal to those for
 wheat mill operations.                               ,   j

 ;     The grain unloading, handling and cleaning operations for dry corn mill-
 ing are similar to those in other grain mills,  but the subsequent operations
 are somewhat  different.   Also,  some drying of corn received at the mill may
 be  necessary  before storage.  An estimate of  the emission factor for drying
 was obtained  from Reference 2.   Insufficient  information is available to
 estimate emission factors for  degerming and milling.    j

 ,     Information necessary to  estimate emissions from oat milling is unavail-
 able,  and no  emission factors  for other grains  are considered applicable
 because oats  are reported to be dustier than many other grains.   The only
 emission factor data available  are for controlled emissions.

 I     Emission factors for rice  milling are based on those for similar opera-
 tions  in other grain handling  facilities.   Insufficient  information is  avail-
 able  to estimate emission factors  for  drying,  cleaning and mill  house
 operations.                                     -

 ';     Information contained in Reference 2  is  used to  estimate emission  factors
 for soybean mills'.                                      |

 j    Emissions  information on wet  corn milling  is generally unavailable, in
 part because  of  the wide  variety  of products  and the  diversity of  operations.
 Receiving, handling and  cleaning  operations emission  factors  are assumed to
 be  similar to  those for  dry  corn milling.   The  drying emission factor is from
 tests  at a wet  corn milling  plant  producing animal feed.72
 !        .      ,          .      -       . -     - '       •  ' ' \
 :.    Due to operational similarities between  grain milling and processing
 plants  and grain elevators,  the  control methods  used  are  similar.   Both often
use cyclones or  fabric filters  to  control emissions from  the  grain handling
operations (e.g. , unloading, legs,  cleaners,  etc.).   These same  devices are
also often used  to control emissions from other  processing operations.  A
good example of  this is the  extensive use of  fabric filters in flour mills.
However, there are also certain operations within some milling operations
that are not amenable to  the use of these devices.  Therefore, wet scrubbers
have found some  application, particularly where the effluent gas stream has
tiigh moisture  content.  Certain other operations  have been found to be
especially difficult to control, such as. rotary dryers in wet corn mills.  .
The various emission control systems that have been applied to operations
within the grain milling and processing industry are described in Reference
2.                                     '        .'   ' -   •  L
9/88                    Food And Agricultural Industry                 6.4-13
                                                                            a

-------
 References for Section 6.4


 1.   G. A. LaFlam, Documentation for AP-4.2 Emission Factors;   Section 6.4,
      Grain Elevators and Processing Plants, Pacific Environmental Services,
      Inc., Durham, NC, September 1987.

 2.   L. J. Shannon, et al.,  Emissions Control in the Grain and Feed Industry,
      Volume I - Engineering  and Cost Study. EPA-450/3-73-003a, U. S.  Environ-
      mental Protection Agency, Research Triangle Park,  NC, December 1973.

 3.   The Storage and Handling of Grain, PEI, Inc.,  Cincinnati, OH,  for
      U. S. EPA Region V, Contract No. 68-02-1355, March 1974.

 4.   Technical Guidance for  Control of Industrial Process  Fugitive  Particu-
      late Emissions, PEI,  Inc., for U. S.  Environmental Protection  Agency,
      Research Triangle Park,  NC, Contract  No. 68-02-1375,  March 1977.

 5.   P. G. Gorman, Potential Dust Emission from a Grain Elevator in Kansas
      City, Missouri, MRI for U. S. Environmental Protection Agency, Research
      Triangle Park, NC, Contract No. 68-02-0228, May 1974.

 6.   L. J. Shannon, et al.,  Emission Control in the Grain  and  Feed  Industry,
      Volume II - Emission  Inventory, EPA-450/3-73-003b,  MRI for U.  S.
      Environmental Protection Agency, Research Triangle  Park,  NC, September
      1974.

 7.   W. H. Maxwell, Stationary Source Testing of a  Country Grain Elevator at
      Overbrook,  Kansas,  MRI  for U. S. Environmental Protection Agency,
      Research Triangle Park,  NC,  Contract  No.  68-02-1403,  February  1976.

 8.   W. H.  Maxwell, Stationary Source Testing  of a  Country  Grain Elevator at
      Great Bend,  Kansas, MRI  for U.  S.  Environmental Protection Agency."
      Research Triangle Park,  NC,  Contract  No.  68-02-1403, April  1976.

 9.   F.  J.  Belgea,  Cyclone Emissions and Efficiency Evaluation,  (Tests at
      elevators in Edinburg and Thompson, North Dakota),  Pollution Curbs,
      Inc.,  St. Paul,  MN, March 10,  1972.

 10.   F.  J.  Belgea,  Grain Handling Dust  Collection Systems Evaluation for
      Farmer's Elevator  Company, Minot,  North Dakota, Pollution Curbs, Inc.,
      St. Paul, MN,  August 28,  1972.

 11.   M.  P.  Schrag,  et al., Source  Test  Evaluation for Feed and Grain Indus-
      try, EPA-450/3-76-043, U.  S. Environmental Protection Agency, Research
      Triangle Park,  NC, December  1976.

 12.   Emission test  data from Environmental Assessment Data Systems, Fine
      Particle Emission  Information System  (FPEIS),  Series No.  228, U. S.
     Environmental  Protection Agency, Research Triangle Park,  NC, June 1983.

 13.  Air Pollution Emission Test, Burtge Corporation, Destrehan, LA. EMB-
      74-GRN-7, U. S. Environmental Protection Agency, Research Triangle Park,       Jlllti
     NC, January  1974.                                                            ll|||

6.4-14                         EMISSION FACTORS                          9/88

-------
14.   W. Battye and R.  Hall,  Particulate Emission Factors  and Feasibility of
     Emission Controls for Shiploading Operations at Portland,  Oregon Grain
     Terminals,  Volume I,  GCA Corporation,  Bedford,  MA,  June 1979.

15.   Emission Factor Development for Ship and Barge  Loading of  Grain, GCA
 i    Corporation for U. S. Environmental Protection  Agency, Research Triangle
 :    Park,  NC, Contract No.  68-02-3510, October 1984.
 i
16.   J. M.  Appold, "Dust Control for Grain  Dryers,"  in Dust Control for Grain
 I    Elevators,  presented before the National Grain  and Feed Association, St.
     Louis, MO,  May 7-8, 1981.
                                   1 -                    i
17.   Written communication from D. Bossman, American Feed Industry  Associa-
     tion,  Arlington,  VA, to F. Noonan, U.  S. Environmental Protection
     Agency, Research Triangle Park, NC, July 24, 1987.

18.   Written communication from P. Luther,  Purina Mills,  Inc.,  St.  Louis, MO,
     to G.  LaFlam, PES, Inc., Durham,  NC, March 11,  1987,.
 !                                                      ' '
19.   Written communication from P. Luther,  Purina Mills,  Inc.,  St.  Louis, MO,
     to F.  Noonan, U. S. Environmental Protection Agency,, Research  Triangle
     Park,  NC, July 8, 1987.

2*0.   Emission test data from FPEIS Series No. 229, U. S.  Environmental
 ;    Protection Agency, Research Triangle Park, NC,  June 1983.

2.1.   H. J.  Taback, Fine Particle Emissions  from Stationary and Miscellaneous
     Sources in the South Coast Air Basin,  KVB, Inc., Tusstin, CA, for the
     California Air Resources Board, February 1979.
                        • .    .        -      -       •                ':  •
22.   Source Category Survey;  Animal Feed Dryers, EPA-450/3-81-017, U. S.
     Environmental Protection Agency, Research Triangle Park, NC, December
     1981.
 9/88
Food And Agricultural Industry
6.4-15

-------

-------
      About 10 percent of all lime produced is converted to hydrated (slaked)
 lime.  There are  two  kinds of hydrators,  atmospheric  and  pressure.   Atmo-
 spheric hydrators, the  more  prevalent type, are used in continuous mode to
 produce high calcium and normal dolomitic  hydrates.  Pressure  hydrators  on
 the other hand, produce only a completely  hydrated dolomitic lime  and oper-
 ate only in  batch mode.   Generally, water  sprays or wet scrubbers perform
 the hydrating process,  to  prevent product loss.  Following hydration, the
 product may be milled and then conveyed to air separators for further drving
 and removal of coarse fractions.

      In the United States,  lime  plays a major role in chemical and metal-
 lurgical operations.  Two  of the  largest  uses  are  as steel flux  and in
 alkali production.  Lesser uses  include  construction,  refractory and agri-
 cultural applications.                                                  5
                                                        I       "••
 8.15.2  Emissions  And Controls3'5

  i    Potential  air pollutant emission  points  in lime'manufacturing plants
 are shown  in Figure  8.15-1.   Except for gaseous  pollutants  emitted from
 lq.lns,  particulate is the only pollutant of concern from most of the opera-
 tions,                                                  i               r

  I    The largest ducted source of  particulate is  the kiln.  Of the various
 kiln  types,  fluidized beds  have the most  uncontrolled particulate emissions
 because of  the very small  feed size combined with high  air  flow through
 these kilns.   Fluidized bed kilns  are  well controlled for maximum product
 recovery.   The  rotary kiln  is second worst  in uncontrolled  particulate emis-
 sions,  also because of the small  feed  size and  relatively  high air veloci-
 ties  and dust entrainment caused by the  rotating chamber.   The calcimatic
 (rotary hearth)  kiln ranks third  in dust production,  primarily because of
 the larger  feed size and the fact  that,  during  calcination,  the limestone
 remains  stationary relative to the  hearth.   The vertical  kiln has the  lowest
 uncontrolled  dust  emissions,  due  to the  large lump feed,  and the relatively
 low air velocities  and slow movement of material through  the kiln.

  i    Some sort  of  particulate control  is generally  applied to  most kilns.
 Riidimentary  fallout chambers  and  cyclone separators are  commonly used for
 control  of  the  larger particles:    Fabric and gravel bed .filters, wet  (com-
 monly  venturi)  scrubbers,  and electrostatic precipitators are used  for sec-
 ondary  control.
  ;                                                      i

     Nitrogen oxides,  carbon monoxide  and sulfur oxides are all produced  in
 kilns,  although  the last are  the only  gaseous pollutant emitted in  signifi-
 cant  quantities.   Not  all of  the sulfur in  the kiln  fuel  is emitted as  sul-
 fur oxides, since some fraction reacts with the materials in the kiln.  Some
 sulfur  oxide  reduction  is  also  effected by the various equipment used for
 secondary particulate control.                          j

  :  . Product  coolers are  emission  sources only when some of their  exhaust
 gases  are not recycled  through  the  kiln  for use  as  combustion air.   The
10/86                     Mineral Products Industry                  8.15-3

-------
trend is away  from the venting of product-cooler exhaust, however, to maxi-
mize fuel use efficiencies.  Cyclones, baghouses and wet scrubbers have been
employed on coolers for particulate control.

     Hydrator emissions  are  low,  because water sprays or wet scrubbers are
usually installed to  prevent product loss in the exhaust gases.  Emissions
from pressure  hydrators  may  be higher than  from the more  common atmospheric
hydrators, because  the exhaust gases are  released intermittently,  making
control more difficult.

     Other particulate sources in lime  plants  include primary and secondary
crushers, mills,  screens, mechanical  and pneumatic transfer operations,
storage piles,  and  roads.  If quarrying is a part of the lime plant opera-
tion, particulate  may also  result  from drilling and blasting.  Emission
factors for some of these operations are presented in Sections  8.19 and 11.2
of this document.

     Controlled and uncontrolled emission factors and particle  size data for
lime manufacturing are given in Tables  8.15-1 through 8.15-3.   The size dis-
tributions of  particulate emissions from controlled and uncontrolled  rotary
kilns  and uncontrolled  product  loading operations are shown  in Figures
8.15-2 and 8.15-3.
 8.15-4
EMISSION FACTORS
                                                                        10/86

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Mineral Products Industry
                                                                     8115-5

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18.19.2   CRUSHED  STONE PROCESSING                        ',  .   •

8.19.2.1  Process Description!                          '
                                                        i
     Major  rock  types processed by  the rock and crushed stone industry include
limestone,  dolomite, granite, traprock, sandstone, quartz and quartzite.  Minor
types include .calcareous marl, marble, shell and slate.! Industry classifica-
^ions vary  considerably and, in many cases, do not reflect actual geological
Definitions.
i                                                   •

[     Rock and crushed stone products generally are loosened by drilling and
blasting, then are loaded by power  shovel or front end  loader and transported
by heavy earth moving equipment.  Techniques used for extraction vary with the
nature and  location of the deposit.  Further processing may include crushing,
'screening,  size  classification, material handling, and  storage operations.  All
pf these processes can be significant sources of dust emissions if uncontrolled.
Some processing  operations also include washing, depending on rock type and
desired product.

!     Quarried stone normally is delivered to the processing plant by truck and
is dumped into a hoppered feeder, usually a vibrating grizzly type, or onto
screens, as illustrated in Figure 8.19.2-1.  These screens separate or scalp
large boulders from finer rocks that do not require primary crushing, thus
reducing the load to the primary crusher.  Jaw, or gyratory, crushers are
usually used for initial reduction.  The crusher product, normally 7.5 to 30
centimeters (3 to 12 inches) in diameter, and the grizzly throughs (undersize
material) are discharged onto a belt conveyor and usually are transported either
to secondary screens and crushers or to a surge pile for temporary storage.

!     Further screening generally separates the process flow into either two
pr three fractions (oversize, undersize and throughs) ahead of the secondary
crusher.  The oversize is discharged to the secondary crusher for further
reduction, and the undersize usually .bypasses the secondary crusher.  The
fchroughs sometimes are separated, because they contain unwanted fines,  and are
stockpiled as crusher run material.  Gyratory crushers or cone crushers are
commonly used for secondary crushing, althpugh impact crushers are sometimes
found.
!                             ,                 ''''':'

(     The product of the secondary crushing stage,  usually 2.5 centimeters (1
inch) diameter or less,  is transported to secondary screens for further sizing.
Oversize material is sent back for recrushing.   Depending on rock type and
desired product, tertiary crushing or grinding may be-necessary,  usually using
cone crushers or hammermills,  (Rod mills, ball mills and hammer mills  normally
are used in milling operations,  which are not considered a part of the  construc-
tion aggregate industry.)  The product from tertiary crushing may be conveyed
j:o a classifier, such as a dry vibrating screen system,  or to an air separator.
Any oversize is returned to the tertiary crusher for further reduction.  At this
point, end products of the desired grade are conveyed or trucked directly to
finished product bins or to open area stockpiles.

J9/88                      Mineral Products Industry                 8.19.2-1

-------
               FIGURE 8.19.2-1.  Typical stone processing plant.
8.19.2-2
EMISSION FACTORS
                                                                         9/88

-------
   ,   In  certain cases,  stone washing  is  required  to  meet  particular  end  product
specifications  or demands, as with concrete aggregate  processing.  Crushed and
broken stone  normally are not milled  but are  screened  and shipped  to the con-
sumer after secondary or tertiary crushing.

8.19.2.2  Emissions And Controls1"3

     Dust emissions occur from many operations  in stone quarrying  and pro-
cessing.  A substantial portion of these emissions consists of heavy particles
that may settle out within the plant.  As in  other operations, crushed stone
emission sources may be categorized as either process  sources or fugitive dust
sources.  Process sources include those  for which emissions are amenable to
capture and subsequent  control.  Fugitive dust  sources generally involve the
reentrainment of settled dust by wind or machine  movement,I  Factors  affecting
emissions from  either source category include the type, quantity and surface
moisture content of the stone processed;  the  type of equipment and operating
practices employed; and topographical and climatic factors.
   1 '                               '                       !
   I  Of geographic and  seasonal factors,  the  primary variables affecting uncon-
trolled particulate emissions are wind and material moisture content.  Wind
parameters vary with geographical location, season and weather.  It  can  be
expected that the level of emissions from unenclosed sources (principally fugi-
tive dust sources) will be greater during periods of high winds.   The material
moisture content also varies with geographic  location, season and  weather.
Therefore, the  levels of uncontrolled emissions from both process  emission
sources and fugitive dust sources generally will  be greater in arid  regions
of the country  than in  temperate ones, and greater during',the summer months
because of a higher evaporation rate.                                 ,

   ,  The moistur.e content of the material processed can have a substantial
effect on uncontrolled  emissions.  This  is especially evident during mining,
initial material handling, and initial plant  process operations such as  primary
crushing.  Surface wetness causes fine particles  to agglomerate on,  or to adhere
toi the faces of larger stones, with a resulting  dust suppression  effect.  How-
ever, as new fine particles are created  by crushing and attrition, and as the
moisture content is reduced by evaporation, this  suppressive effect  diminishes
and may disappear.  Depending on, the geographic and climatic conditions, the
moisture content of mined rock may range from nearly zero (to several  percent.
Since moisture  content  is usually expressed on a  basis of overall weight per-
cent, the actual moisture amount per unit area will vary with the  size of. the
rock being handled.  On a constant mass  fraction  basis, the per unit area mois-
ture content varies inversely with the diameter of the rock.  Therefore, the
suppressive effect of the moisture depends on both the absolute mass water con-
tent and the.size of the rock product.   Typically, a wet material will contain
1.5 to 4 percent water or more.

     There are  a large  number of material, equipment and operating factors
which can influence emissions from crushing.  These include:  (1) rock type,
(2) feed size and distribution,  (3) moisture  content, (4) throughput  rate, (5)
crusher type, (6) size  reduction ratio,  and (7) fines content.   Insufficient
data are available to present a matrix of rock crushing emission factors
detailing the above classifications and variables.  Data available from which
to .prepare emission factors also vary considerably, for both extractive testing
and plume profiling.   Emission factors from extractive testing are generally

9/88                      Mineral Products Industry                    8.19.2-3

-------
higher than those based upon plume profiling tests, but they have a greater
degree of reliability.  Some test data for primary crushing indicate higher
emissions than from secondary crushing, although factors affecting emission
rates and visual observations suggest that the secondary crushing emission
factor, on a throughput basis, should be higher.  Table 8.19.2-1 shows single
factors for either primary or secondary crushing reflecting a combined data
base.  An emission factor for tertiary crushing is given, but it is based on
extremely limited data.  All factors are rated low because of the limited and
highly variable data base.
           TABLE 8.19.2-1.
UNCONTROLLED PARTICULATE EMISSION FACTORS
FOR CRUSHING OPERATIONS3
Type of crushing"
Primary or secondary
Dry material
Wet materialc
Tertiary dry material*1
Particulate
< 30 urn
kg/Mg (Ib/ton)
0.14 (0.28)
0.009 (0.018)
0.93 (1.85)
< 10 urn
kg/Mg (Ib/ton)
0.0085 (0.017)
-
-
Emission
Factor
Rating
D
D
E
aBased on actual feed rate of raw material entering the particular operation.
 Emissions will vary by rock type, but data available are insufficient to
 characterize these phenomena.  Dash = no data.
^References  4-5.  Typical control efficiencies for cyclone, 70 - 80%;
 fabric filter, 99%; wet spray systems, 70 - 90%.
References  5-6.  Refers to crushing of rock either naturally wet or
 moistened to 1.5 - 4 weight % with wet suppression techniques.
^Range of values used to calculate emission factor is 0.0008 - 1.38 kg/Mg.

     Emission factor estimates for stone quarry blasting operations are not
presented here because of the sparsity and unreliability of available test
data.  While a procedure for estimating blasting emissions is presented in
Section 8.24, Western Surface Coal Mines, that procedure should not be applied
to  stone quarries because of dissimilarities in blasting techniques, material
blasted and  size of blast areas.

     There are no screening emission factors presented in this. Section.  How-
ever, the screening emission factors given in Section 8.19.1, Sand and Gravel
Processing,  should be similar to those expected from screening crushed rock.
Milling of fines is also not included, in this Section as this operation is
normally associated with non construction aggregate end uses and will be covered
elsewhere in the future when information is adequate.

      Open dust source  (fugitive dust) emission factors for stone quarrying and
processing are presented in Table 8.19.2-2.  These factors have been determined
8.19.2-4
   EMISSION FACTORS
9/88

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42 CO CO X
> a cu
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Cfl rH 4-1 CU S-l
T) bO . CO r-f 
jft ca 5*,
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13 S-l CJ d -rl
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SH UH 3 II ft
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0) d 4-1
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04-1 > u ~^ SH
tH cfl D 43 CU
4J 3 IU CU rH 4-1
S-l CT1 i^. _O N-^ frt
-j-ocai suspended pa:
Use of empirical ei
- -J « l-V,J^ T-U1 	 	 	
- -til b.ii.i.0 J-dLIJLC ct£C J
variables can not 1
^Expressed as g/Mg
g/Mg (Ib/ton) of m<
cReference 2.
Reference 3.
Industry





















CO

ca
13

4J
CO
CU
4-1
O
^
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•H
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rH
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mpirical eq
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0)
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Reference 6.
fSee Section 11.2 fc
SNot presented becat
8.19.2-5

-------
through  tests  at  various quarries and processing plants.6~?  The single valued
open dust  emission factors given in Table  8.19.2-2 may be used when no other
information exists.   Empirically derived emission factor equations presented
in  Section 11.2 of this document are preferred and should be used when possible.
Because  these  predictive equations allow the adjustment of emission factors for
specific source conditions, these equations should be used instead of those in
Table  8.19.2-2, whenever emission estimates applicable to specific stone quarry-
ing and  processing facility sources are needed.  Chapter 11.2 provides measured
properties of  crushed limestone, as required for use in the predictive emission
factor equations.

References for Section 8.19.2

1.   Air Pollution Control Techniques for  Nonmetallic Minerals Industry,
     EPA-450/3-82-014, U. S. Environmental Protection Agency, Research
     Triangle  Park, NC, August  1982.           •

2.   P.  K. Chalekode,  et al., Emissions from the Crushed Granite Industry;
     State of  the Art, EPA-600/2-78-021, U. S. Environmental Protection
     Agency, Washington, DC, February 1978.            .

3.   T.  R. Blackwood,  et al., Source Assessment; Crushed Stone, EPA-600/2-78-
     004L, U.  S. -Environmental  Protection  Agency, Washington, DC, May 1978.

4.   F.  Record and W.  T. Harnett, Particulate Emission Factors for the
     Construction Aggregate Industry, Draft Report, GCA-TR-CH-83-02, EPA
     Contract  No. 68-02-3510, GCA Corporation, Chapel Hill, NC, February 1983.

5.   Review Emission  Data Base  and Develop Emission Factors for the Con-
     struction Aggregate Industry, Engineering-Science, Inc., Arcadia, CA,
v     September 1984.

6.   C.  Cowherd,  Jr.,  et al., Development  of Emission Factors for Fugitive Dust
     Sources,  EPA-450/3-74-037, U. S. Environmental Protection Agency, Research
     Triangle  Park, NC, June 1974.

7.   R.  Bohn,  et  al.,  Fugitive  Emissions from Integrated Iron and Steel Plants,
     EPA-600/2-78-050, U. S. Environmental Protection Agency, Washington, DC,
     March 1978.
 8.19.2-6
EMISSION FACTORS
9/88

-------
 8.24  WESTERN  SURFACE COAL MINING

 8.24.1   General1
 »  .        are  12 raaJ°r coal fields in  the western states (excluding the
 Pacific  Coast  and Alaskan  fields),  as  shown  in Figure  8,24-1.   Together
 they account  for more  than 64  percent  of the  surface minable  coal reserves
           COAL TYPE
           LIGNITE
           SUBBITUHINOUSEZ3
           BITUMINOUS
                    1
                    2
                    3
                    4
                    5
                    6
                    7
                    3
                    9
                   10
                   11
                   12
                 Coal field

             Fort Union
             Powder River
             North Central
             Bighorn Basin
             Wind River
             Hams Fork
             Uinta
             Southwestern Utah
             San Juan River
             Raton Mesa
             Denver
             Green River
                                                  Strippable reserves
                                                     (JO6 tons)
    23,529
    56,727
All underground.
All underground
        3
    1,000
      308
      224
    2,318
All underground
All underground
    2,120
9/88
Figure 8.24-1.   Coal  fields of  the western 13.S.3

            Mineral Products Industry
                                                                             8.24-1

-------
in  the  United States.2  The 12 coal fields have  varying  characteristics
which may  influence  fugitive  dust emission rates from mining operations,
including overburden and coal seam thicknesses and structure,  mining equip-
ment, operating procedures, terrain, vegetation, precipitation and surface
moisture, wind  speeds  and  temperatures.  The operations at a typical west-
ern  surface  mine  are shown in Figure 8.24-2.   All operations  that involve
movement of  soil,  coal,  or equipment,  or exposure of  credible  surfaces,
generate some amount of fugitive dust.

     The initial  operation is  removal  of topsoil and  subsoil with large
scrapers.  The  topsoil is  carried by the scrapers to  cover a previously
mined and  regraded area as part of the reclamation process or is placed  in
temporary stockpiles.  The exposed  overburden,  the earth  which  is between
the  topsoil  and  the  coal   seam, is leveled,  drilled and blasted.   Then the
overburden material is removed down to  the coal seam,  usually  by a dragline
or a  shovel  and truck operation.   It is  placed in the adjacent  mined cut,
forming  a  spoils pile.  The  uncovered coal  seajn is  then drilled and
blasted.  A  shovel or front end loader loads the  broken  coal into haul
trucks,  and  it  is taken out of the pit along graded haul roads to the tip-
ple, or  truck dump.   Raw   coal sometimes  may be  dumped onto  a temporary
storage pile and later rehandled by a front end loader or  bulldozer.

     At the tipple, the coal is dumped  into a  hopper  that  feeds  the primary
crusher, then is conveyed through additional coal preparation  equipment
such as  secondary  crushers and screens to the storage area.   If the mine
has open storage piles, the crushed coal  passes through a  coal stacker onto
the pile.  The  piles,  usually worked by bulldozers,  are  subject  to wind
erosion.  From  the storage area,  the coal is conveyed to a train loading
facility and  is put  into   rail cars.  At  a captive mine, coal  will go from
the storage pile to the power plant.

     During mine  reclamation,  which  proceeds  continuously throughout the
life of  the  mine,  overburden  spoils  piles are smoothed and contoured by
bulldozers.  Topsoil  is placed  on the  graded  spoils,  and  the  land is pre-
pared for  revegetation by  furrowing, mulching, etc.  From the  time an area
is disturbed until the new vegetation emerges,  all disturbed areas are sub-
ject to wind erosion.

8.24.2  Emissions            ,

     Predictive  emission factor equations for open dust sources  at western
surface  coal  mines are presented  in  Tables  8.24-1  and  8.24-2.   Each equa-
tion is  for  a single dust  generating activity,  such  as vehicle  traffic on
unpaved roads.  The predictive equation explains  much  of the observed vari-
ance in  emission factors by relating emissions to three sets  of  source pa-
rameters:  1) measures  of  source  activity or  energy  expended  (e.g.,  speed
and weight of a  vehicle traveling  on  an unpaved  road);  2)  properties of the
material being disturbed (e.g., suspendable  fines in  the  surface  material
of an unpaved road);  and 3) climate (in this  case,  mean wind speed).

     The equations may be  used to estimate participate emissions generated
per unit of source extent   (e.g., vehicle  distance  traveled or  mass of mate-
rial transferred).

8.24-2                       EMISSION FACTORS                          9/88

-------
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EMISSION FACTORS
                                                                         9/88

-------




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9/8J8
                            Mineral Products Industry
8.24-5

-------
The equations were developed through field sampling of various  western surface
mine types and are thus applicable to any of the surface coal mines  located  in
the western United States.

     In Tables 8.24-1 and 8.24-2, the assigned quality ratings  apply within
the ranges of source conditions that were tested in developing  the equations,
given in Table 8.24-3.  However, the equations are derated one  letter value
(e. g., A to B) if applied to eastern surface coal mines.
     TABLE 8.24-3.
TYPICAL VALUES FOR CORRECTION FACTORS APPLICABLE  TO THE
 PREDICTIVE EMISSION FACTOR EQUATIONS3
Number
Source Correction of test
factor samples
Coal loading
Bulldozers
Coal

Overburden

Dragline


Scraper

Grader

Light /medium
duty vehicle
Haul truck

Moisture

Moisture
Silt
Moisture
Silt
Drop distance
11 11
Moisture
Silt
Weight
it
Speed
•i

Moisture
Wheels
Silt loading
it tt
7

3
3
8
8
19

7
10
15

7


7
29
26

Range Geometric
mean
6.6 -

4.0 -
6.0 -
2.2 -
3.8 -
1.5 -
. 5 -
0.2 -
7.2 -
33 -
36 -
8.0 -
5.0 -

0.9 -
6.1 -
3.8 -
34 -
38

22.0
11.3
16.8
15.1
30
100
16.3
25.2
64
70
19.0
11.8

1.7
10.0
254
2270
17.8

10.4
8.6
7.$
6.9
8.6
28.1
3.2
16.4
48.8
53.8
11.4
7.1

1.2
8.1
40.8
364
Units


%
%
%
%
m
ft
%
%
Mg
ton
kph
mph

%
number
g/m2
Ib/ac
 aReference !•
      In using the equations to estimate emissions  from sources  found  in a
 specific western surface mine, it is necessary that  reliable values for
 correction parameters be determined for the specific sources of interest,
 if the assigned quality ranges of the equations are  to be applicable.
 For example, actual silt content of coal or overburden measured at a  facility
 8.24-6
                                 EMISSION FACTORS
                                                       9/88

-------
should be  used  instead of estimated values.  In thevevent that site  spe-
cific values  for  correction parameters cannot be obtained, the appropriate
geometric mean values from Table 8.24-3 may be used,  but the assigned qual-
ity  rating  of each emission factor equation is reduced by one level  (e.g.,
A to B).

     Emission factors for open dust sources not covered in Table 8.24-3 are.
in1Table  8.24-4.  These factors were determined through source testing at
various western coal mines.

     The factors in Table 8.24-4 for mine locations I through V were devel-
oped  for  specific geographical areas.  Tables 8.24-5 and  8.24-6  present
characteristics of each of these mines (areas).   A "mine specific" emission
factor should be  used  only if the characteristics of the mine for which an
emissions estimate is  needed  are very similar to  those  of the mine  for
which the  emission factor was developed.  The other  (noaspecific) emission
factors were  developed  at  a  variety of mine types and thus are applicable
to any western surface coal mine.

     As an alternative to the single valued emission  factors  given in Table
8.24-4 for  train  or  truck loading and for truck or scraper unloading, two
empirically derived  emission factor equations are preseiated  in Section
11J2.3 of this  document.  Each equation was developed for a  source opera-
tion  (i.e., batch drop and continuous drop,  respectively),  comprising a
single dust generating mechanism which crosses industry lines.

     Because the  predictive equations  allow emission factor  adjustment to
specific source conditions, the equations should be  used in place of the
factors in Table 8.24-4 for the sources identified above,,, if  emission esti-
mates for a specific western  surface coal mine are needed.  However,  the
generally higher  quality  ratings  assigned to  the equations are applicable
only if 1)  reliable  values  of correction parameters hav« been determined
for the specific sources of interest and 2)  the  correction parameter values
lie  within  the  ranges tested in developing the  equations.   Table 8.24-3
lists measured properties of  aggregate materials  which can be used to esti-
mate correction parameter values  for the predictive  emission factor equa-
tions in  Chapter  11, in the event that site specific valiies are not avail-
able.  Use  of mean  correction parameter values from Table 8.24-3 reduces
the quality ratings  of  the  emission factor equations in Chapter 11 by one
level.
9/88                     Mineral Products  Industry                    8.24-7

-------
       TABLE  8.24-4.
 UNCONTROLLED  PARTICIPATE EMISSION FACTORS  FOR
OPEN  DUST  SOURCES AT WESTERN SURFACE COAL MINES
Source
Drilling


Topsoil removal by
scraper

Overburden
replacement
Truck loading by
power shovel
(batch drop)
Train loading (batch c
or continuous drop)

Bottom dump truck
unloading
(batch drop)










End dump truck
unloading
* (batch drop)
Scraper unloading
(batch drop)
Wind erosion of
exposed areas
Material Mine
location
Overburden
Coal

Topsoil

Overburden

Overburden

, Coal

Overburden
,
Coal









Coal

Topsoil
Seeded land,
, stripped over-
burden, graded
overburden
Any
V

Any
IV

Any

V

Any
III

-V

IV

III

11

I

Any

V

IV
Any

TSP
emission
factorb
1.3
0.59
0.22
0.10
0.058
0.029
0.44
0.22
0.012
0.0060
0.037
0.018

0.028
0.014
0.0002
0.0001
0.002
0.001

0.027
0.014
0.005
0.002
0.020
0.010
0.014
0.0070
0.066
0.033
0.007
0.004

0.04
0.02
0.38
0.85
Emission
Units Factor
Rating
Ib/hole
kg/hole
Ib/hole
kg/hole
Ib/T
kg/Mg
Ib/T
kg/Mg
Ib/T
kg/Mg -
Ib/T
kg/Mg

Ib/T
kg/Mg
Ib/T
kg/Mg
Ib/T
kg/T

Ib/T
k«/Mg
Ib/T
kg/Mg
Ib/T
kg/Mg
Ib/T
kg/Mg
Ib/T
kg/Mg
Ib/T
kg/Mg

Ib/T
kg/Mg
I
MR
(hectareJCyr)
B
B
E
E
E
I
D
D
C
C
C
C

D
D
D
0
E
E

E
E
E
E
E
E
D
D
D
D
.E
E

C
C
C
c
              1  Ronan numerals I through V refer  to specific mine  locations for which the
                corresponding emission factors were developed (Reference 4).  Tables 8.24-4
                and 8.24-5 present characteristics of each of these nines.  See text, for
                correct use of these "nine specific" emission factors.  The other factors
                (froa Reference 5 except for overburden drilling from Reference 1) can be
              .  applied to any western surface coal mine.
              °  Total suspended particulate (TSP) denotes what is  measured by a standard high
                voluae sanpler (see Section 11.2).
                Predictive emission factor equations, which generally provide nore Accurate
                estimates of emissions, are presented in Chapter 11.
8.24-8
             EMISSION  FACTORS
                                                                                                 9/88

-------
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References for Section 8.24                         '
                                                        I         -     .
'1.1  K. Axetell and C. Cowherd, Improved Emission Factors for Fugitive Dust
   |  from Western Surface Coal Mining Sources, 2 Volumes, EPA Contract  No.
   I  68-03-2924,  U.  S. Environmental Protection  Agency,  Cincinnati, OH,
     July 1981.

2.i  Reserve Base of U. S. Coals by Sulfur Content:  Part 2, The Western
     States,  IC8693,  Bureau  of Mines, U. S. Department  of  the Interior,
     Washington, DC,  1975.                              j,     .

3.   Bituminous Coal  and Lignite Production and Mine Operations - 1978,
     DOE/EIA-0118(78),  U.  S. Department of Energy, Washington,  DC,  June
     1980.                                              i
   i             '
4.!  K. Axetell, Survey of Fugitive Dust from Coal Mines', EPA-908/1-78-003,
     U.  S.  Environmental  Protection  Agency,  Denver,  CO, February  1978.

5.   D.  L.  Shearer,  et al.,  Coal Mining Emission Factor Development and
     Modeling  Study,  Amax Coal  Company,, Carter  Mining  Company, Sunoco
     Energy  Development  Company,  Mobil Oil  Corporation,  and Atlantic
     Richfield Company, Denver, CO, July 1981.
9/88
Mineral Products Industry
8.24-11

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                       CHAPTER 11.  MISCELLANEOUS SOURCES
 ;    This chapter contains emission factor information on those source cate-
gories that differ substantially from, and hence cannot be grouped with, the
other "stationary" sources discussed in this publication;  These miscellaneous
emitters, both natural and raanmade, are almost exclusively area sources, with
their pollutant generating process(es) dispersed over large land areas.   Another
characteristic of these sources is the inapplicability, In most cases, of con-
ventional control methods, such as wet/dry equipment, fuel switching,  process
changes, etc.   Instead, control of these emissions,  where possible at  all,  may
include such techniques as modification of agricultural burning practices,
paving with asphalt or concrete, or stabiliation of  dirt roads.  Finally,
miscellaneous sources generally emit pollutants intermittently, when compared
tb most stationary point sources.   For example, a wildfire may emit large
quantities of particulate and carbon monoxide for several hours or even days.
But, when measured against a continuous emitter, such as a sulfuric acid plant,
over a long period of time, its emissions may seem relatively minor.  Effects
on air quality may also be of relatively short duration.
 ;9/88
Miscellaneous Sources
11-1

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1-11.1  Wildfires And Prescribed Burning
j
 11.1.1   General1
i                                   ,           .         .-            •       •

      A wildfire is  a large  scale natural  combustion process  that  consumes
 various  ages, size  and  types  of  flora growing outdoors in a  geographical area.
I Consequently, wildfires are potential sources of  large amounts  of air  pollut-
!ants  that  should be considered when trying  to relate  emissions  to air  quality.
i                                                       '
      The size and intensity,  even the occurrence, of  a wildfire depend
I directly on such variables  as meteorological conditions, the species of vege-
:tation involved and their moisture content, and the weight of consumable fuel
iper acre (available fuel loading).  Once  a  fire begins,, the  dry combustible
imaterial is consumed first.   If  the energy  release  is large  and of sufficient
iduration,  the drying of green, live material occurs,  with subsequent burning
; of this  material as well.   Under proper environmental and fuel  conditions,
(this  process may initiate a chain reaction  that results! in a widespread
(conflagration.

      The complete combustion  of  wildland  fuels (forests, grasslands, wetlands)
irequire  a  heat flux (temperature gradient), adequate  oxygen  supply, and
[sufficient burning  time.  The size and quantity of  wildland  fuels, meteo-
irological  conditions, and topograhic features interact to modify  the burning
'Behavior as the fire spreads, and the wildfire will attain different degrees
.of combustion efficiency during  its lifetime.
'                                        •                  •
      The importance of  both fuel type and fuel loading on the fire process
jean not  be overemphasized.  To meet the pressing  need for this  kind of infor-
imation,  the U. S. Forest Service is developing a  model of a  nationwide fuel
(identification system that  will  provide estimates of  fuel loading by size
I class.   Further, the environmental parameters of  wind, slope and  expected
 moisture changes have been  superimposed on  this fuel  model and  incorporated
(into  a National Fire Danger Rating System (NFDRS).  This system considers
'five  classes of fuel, the components of which are selected on the  basis of
'combustibility, response of dead fuels to moisture, -and whether the living
 fuels are  herbaceous (grasses, brush) or  woody (trees, shrubs).

1      Most  fuel loading  figures are based  on values  for "available fuel," that
 is, combustible material that will be consumed in a wildfire under specific
 weather  conditions.   Available fuel values must not be confused with corres-
ponding  values for  either "total  fuel" (all the combustible  material that
iwould burn under the most severe  weather  and burning  conditions) o.r "potential
jfuel" (the larger woody material  that remains even  after an extremely high
(intensity  wildfire).  It must be  emphasized, however, that the  various methods
;of. fuel  identification  are  of value only  when they  are related  to the existing
[fuel  quantity, the  quantity consumed by the fire, and the geographic area and
 conditions under which  the  fire occurs.                 j
i                           "                    .       '
i      For the sake of conformity  and convenience, fuel loadings  are estimated
;for the  vegetation  in the U.  S. Forest Service Regions are presented in
 Table 11.1-1.  Figure 11.1-1  illustrates  these areas  and regions.
 9/88                        Miscellaneous Sources                       11.1-1

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       TABLE 11.1-1.  SUMMARY OF ESTIMATED FUEL CONSUMED BY WILDFIRES*
National region*5
Rocky Mountain
Region 1:
Region 2:
Region 3:
Region 4:
Northern
Rocky Mountain
Southwestern
Intermountain
Pacific
Region 5:
Region 6:
Region 10:
California
Pacific Northwest
Alaska
Coastal
Interior
Southern
Region 8:
Southern
Eastern
North central
Region 9:
Conifers
Hardwoods
Estimated average fuel loading
Mg/hectare
83
135
67
22
40
43
40
135
36
135
25
20
20
25
25
22
27
ton/acre
37
60
30
10
8
19
18
60
16
60 r
11
9
9
11
11
10
12
      aReference 1.
      *>See Figure 11.1-1 for region boundaries
11.1-2
EMISSION FACTORS
                                                                        9/88

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9/88
                                                                    rH
                                                                    g
                                                                    H
Miscellaneous Sources
                                                                      11.1-3

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  11.1.2  Emissions And Controls1

       It  has  been hypothesized, but  not  proven, that  the nature and amounts of
  air pollutant  emissions are directly related to the  intensity and direction
  (relative  to the wind) of  the wildfire, and are indirectly related to the rate
  at which the fire spreads.  The factors that affect  the rate of spread are
  (1) weather  (wind velocity, ambient temperature, relative humidity); (2) fuels
  (fuel  type,  fuel  bed array, moisture content, fuel size); and (3) topography
  (slope and profile).   However, logistical problems (such as size of the burning
  area)  and  difficulties in  safely situating personnel and equipment close to the
  fire  have  prevented the collection  of any reliable emissions data on actual
  wildfires, so  that it  is not possible to verify or disprove the hypothesis.
  Therefore, until  such measurements are made, the only available information is
  that obtained  from burning experiments in the laboratory.   These data,  for both
  emissions  and  emission factors, are contained in Table 11.1-2.  It must be
  emphasized that the factors presented here are adequate for laboratory  scale
  emissions  estimates, but that substantial errors may result if they are used to
  calculate actual wildfire emissions.

      The emissions and emission factors displayed in Table 11.1-2 are calculated
 using the following formulas:
                                                                             (1)

                                                                             (2)
         Ei  «  F^A = PALA

 where:  Fj  -  Emission factor (mass of pollutant/unit area of
                forest consumed)          ...'     .       .                        '

         Pi  -  Yield for pollutant "i"  (mass  of  pollutant/unit
                mass of forest fuel consumed)

             s  8.5 kg/Mg (17  Ib/ton)  for total particulate

             -  70 kg/Mg (140  Ib/ton)  for carbon  monoxide

             -  12 kg/Mg (24 Ib/ton)  for total  hydrocarbon (as  CH4)

             s  2  kg/Mg (4  Ib/ton)  for nitrogen oxides (NOV)
                               •            -         .     A ,

             s  Negligible  for sulfur  oxides (SOV)
                                               •**

        L    =  Fuel loading consumed  (mass of  forest fuel/unit land
                area burned)

        A    "  Land area burned

        Ei   =-  Total emissions of pollutant "i"  (mass pollutant)

     For example,  suppose  that is is necessary to estimate the total particu-
late emissions  from a  10,000 hectare wildfire in the Southern area (Region 8).
From Table 11.1-1,  it  is seen that the average fuel loading is 20 megagrams per
hectare (9 tons per acre).  Further, the pollutant yield for particulates is
8.5 kilograms per megagram (17 Ib/ton).   Therefore, the emissions are:
11.1-4
                                EMISSION FACTORS
                                                                        9/88

-------
;9/88

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     E - (8.5 kg/Mg of fuel) (20 Mg of fuel hectare) (10,000 hectares)

     E - 1.700,000 kg - 1,700 Mg

     The most effective method of controlling wildfire emissions is,  of course,
to prevent the occurrence of wildfires, by various means at the land  manager's
disposal.  A frequently used technique for reducing wildfire occurrence is
"prescribed" or "hazard reduction" burning.  This type of managed burn  involves
combustion of litter and underbrush to prevent fuel buildup under controlled
conditions, thus reducing the danger"of a wildfire.  Although some air  pollution
is generated by this preventive burning, the net amount is believed to  be a
relatively smaller quantity than that produced by wildfires.

11.1.3  Prescribed Burning1

     Prescribed burning is a land treatment, used under controlled conditions,
to accomplish natural resource management objectives.  It is one of several
land treatments, used individually or in combination, including chemical and
mechanical methods.  Prescribed fires are conducted within the limits of a fire
plan and prescription which describes both the acceptable range of weather,
moisture, fuel and fire behavior parameters and the ignition method to  achieve
the desired effects.  Prescribed fire is a cost effective arid ecologically
sound tool for forest, range and wetland management.  Its use reduces the
potential for destructive wildfires and thus maintains long term air quality.
Also, the practice removes logging residues, controls insects and disease,
improves wildlife habitat and forage production, increases water yield, main-
tains natural succession of plant communities, and reduces the need for pes-
ticides and herbicides.  The major air pollutant concern is the smoke produced.

     Smoke from prescribed fires is a complex mixture of carbon, tars,  liquids
and different gases.  This open combustion source produces particles of widely
ranging size, depending to some extent on the rate of energy release of the
fire.  For example, total particulate and particulate less than 2.5 micrometers
mean mass cutpoint diameter are produced in different proportions, depending on
rates of heat release by the fire.2  This difference is greatest for the highest
intensity fires, and particle volume distribution is bimodal, with peaks near
0.3 micrometers and exceeding 10 micrometers.^  Particles over about 10 microns,
probably of ash and partially burned plant matter, are extrained by the turbu-
lent nature of high intensity fir.es.

     Burning methods differ with fire objectives and with fuel and weather
conditions.^  For example, the various ignition techniques used to burn under
standing trees include 1) heading fire, a line of fire that runs with the wind;
2) backing fire, a line of fire that moves into the wind; 3) spot fires, which
burn from a number of fires ignited along a line or in a pattern; and 4) flank
fire, a line of fire that is lit into the wind, to spread laterally to  the
direction of the wind.  Methods of igniting the fires depend on forest  manage-
ment objectives and the size of the area.  Often, on areas of 50 or more acres,
helicopters with aerial ignition devices are used to light broadcast burns.
Broadcast fires may involve many lines of fire in a pattern that allows the
strips of fire to burn together over a sizeable area.
11.1-6                          EMISSION FACTORS          "               9/88

-------
 i    In discussing prescribed burning, the combustion process is divided into
preheating, flaming, glowing and smoldering phases.  The different phases of
combustion greatly affect the amount of emissions produced.5~7  The preheating
nhase seldom releases significant quantities of material to the atmosphere.
Glowing combustion is usually associated with burning of large concentrations
of woody fuels such as logging residue piles.  The smoldering combustion phase
is a very inefficient and incomplete combustion process that emits pollutants
at a much higher ratio to the quantity of fuel consumed than does the flaming
combustion of similar materials.

     The amount of fuel consumed depends on the moisture! content of the fuel.8~9
For most fuel types, consumption during the smoldering phase is much greatest
when the fuel is driest.  When lower layers of the fuel are moist, the fire
usually is extinguished rapidly.10

 !  •  The major pollutants from wildland burning are particulate, carbon monoxide
and volatile organics.  Nitrogen oxides are emitted at rates of from 1 to 4
grams per kilogram burned, depending on combustion temperatures.  Emissions of
sulfur oxides are negligible. ^~*

 |    Particulate emissions depend on the mix of combustion phase, the rate of
energy release, and the type of fuel consumed^  All of these elements must be
considered in selecting the appropriate emission factor for a given fire and
fuel situation.  In some cases, models developed by the U. S. Forest Service
have been used to predict particulate emission factors s;nd source strength.^
These models address fire behavior, fuel chemistry, and ignition technique, and
they predict the mix of combustion products.  There is insufficient knowledge
at this time to describe the effect, of fuel chemistry on emissions.
' |  •    •'     "     •                     •    •''•-•     i  '•' ''        :
 ;    Table 11.1-3 presents emission factors from various pollutants, by fire
and fuel configuration,  table 11.1-4 gives emission factors for prescribed
burning, by geographical area within the United States.  Estimates of the
percent of total fuel consumed by region were compiled by polling experts
from the Forest Service.  The emission factors are averaiges and can vary by
as much as 50 percent with fuel and fire conditions.  To use these factors,
multiply the mass of fuel consumed per hectare by the emission factor for the
appropriate fuel type.  The mass of fuel consumed by a fire is defined as the
available fuel.  Local forestry officials often compile ^information on fuel
consumption for prescribed fires and have techniques for estimating fuel
consumption under local conditions.  The Southern Forestry Smoke Management
Guidebook^ and the Prescribed Fire Smoke Management Guide^ should be consulted
when using these emission factors.                               ,,         "
 i     •              .           '    •                     j- -;". ! ....... j  '
 '    The regional emission factors in Table 11.1-4 should be used only for
general planning purposes.  Regional averages are based on estimates of the
acreage and vegetation type burned and may not reflect prescribed burning
activities in a given state.  Also, the regions identified are broadly defined,
and the mix of vegetation and acres burned within a givesn state may vary
considerably from the regional averages provided.  Table 11.1-4 should not be
used to develop emission inventories and control strategies.
 !    To develop state emission inventories, the user is
tact that state's federal land management agencies and
tihat conduct prescribed burning to obtain the best information
                             Miscellaneous Sources
 strongly urged to con-
state forestry agencies
        on such activities,
                  11.1-7

-------
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-------
        TABLE 11.1-4.
EMISSION FACTORS FOR PRESCRIBED BURNING
     BY U. S.  REGION

Regional
configuration and
fuel type3
Pacific Northwest
Logging slash
Piled slash
Douglas fir/
Western hemlock
Mixed conifer
Ponderosa pine
Hardwood
Underburning pine
Average for region
Pacific Southwest
Sagebrush
Chaparral
Pinyon/ Juniper
Underburlng pine
Grassland
Average for region
Southeast
Palme tto/gallberry
Underburning pine
Logging slash
Grassland
Other
Average for region
Rocky Mountain
Logging slash
Underburning pine
Grassland
Other
Average for region
North Central and Eastern
Logging slash
Grassland
Underburning pine
Other
Average for region
Percent
of fuelb


42

24
19
6
4
5
100

35
20
20
15
10
100

35
30
20
'10
5
100

50
20
20
10
100

50
30 •
10
10
100
Pollutant0
Particulate
(K/ks)
PM2.5


4

12
12
13
11
30
9.4


8























PM10


5


13
13
13
12
30
10.3

9
9
13
30
10
13.0

15

30
13
10
17
' 18.8

4


30
10
17
11.9

13
10
30
17
14






PM


6

17
17
20
18
35
13.3

15
15
17
35
10
17.8

16
35
20
10
17
21.9

6
35
10
17
13.7

17
10
35
17
16.5
CO


37

175
175
126
112
163
111.1

62
62
175
163
75
101.0

125
163
126
75
175
134

37
163
75
175
83.4

175
75
163
175
143.8
  aRegional areas  are generalized, e. g.,  the Pacific Northwest includes
   Oregon,  Washington and parts of Idaho  and California. Fuesl types
   generally reflect the ecosystems of a  region, but users should seek
   advice on fuel  type mix for a given season of the year.  An average
   factor for Northern California could be more accurately described as
   chaparral, 25%; underburning pine, 15%; sagebrush, 15%; grassland,
   5%; mixed conifer, 25%; and Douglas fir/Western hemlock, 15%.
   Dash = no data.
  bBased on the judgment of forestry experts.
  cAdapted from Table 11.1-3 for the dominant fuel types burned.
9/88
                        Miscellaneous Sources
                                                                          11.1-9

-------
References for Section 11.1

 1.  Development Of Emission Factors For Estimating Atmospheric Emissions  From
     Forest Fires, EPA-450/3-73-009, U. S. Environmental Protection Agency,
     Research Triangle Park, NC, October 1973.

 2.  D. E. Ward and C. C. Hardy, Advances In The Characterization And Control
     Of Emissions From Prescribed Broadcast Fires Of Coniferous Species Logging
     Slash On Clearcut Units, EPA DW12930110-01-3/DOE DE-A179-83BP12869, U. S.
     Forest Service, Seattle, WA, January 1986.

 3.  L. F. Radke, e't al., Airborne Monitoring And Smoke Characterization Of
     Prescribed Fires On Forest Lands In Western Washington and Oregon,
     EPA-600/X-83-047, U. S. Environmental Protection Agency, Cincinnati,  OH,
     July 1983.

 4.  H. E. Mobley, et al., A Guide For Prescribed Fire In Southern Forests,
     U. S. Forest Service, Atlanta, GA, 1973.

 5.  Southern Forestry Smoke Management Guidebook, SE-10, U. S. Forest Service,
     Asheville, NC, 1976.

 6.  D. E. Ward and C. C. Hardy, "Advances In The Characterization And Control
     Of Emissions From Prescribed Fires", Presented at the 77th Annual Meeting
     of the Air Pollution Control Association, San Francisco,  CA, June 1984.

 7.  C. C. Hardy and D. E. Ward, "Emission Factors For Particulate Matter  By
     Phase Of Combustion From Prescribed Burning", Presented at the Annual
     Meeting of the Air Pollution Control Association Pacific Northwest
     International Section, Eugene, OR, November 19-21, 1986.

 8.  D. V. Sandberg and R. D. Ottmar, "Slash Burning And Fuel Consumption  In
     The Douglas Fir Subregion", Presented at the 7th Conference On Fire And
     Forest Meteorology,  Fort Collins, CO, April 1983.

 9.  D. V. Sandberg, "Progress In Reducing Emissions From Prescribed Forest
     Burning In Western Washington And Western Oregon", Presented at the Annual
     Meeting of the Air Pollution Control Association Pacific Northwest
     International Section, Eugene, OR, November 19-21, 1986.

10.  R. D. Ottmar and D.  V. Sandberg, "Estimating 1000-hour Fuel Moistures In
     The Douglas Fir Subregion", Presented at the 7th Conference On Fire And
     Forest Meteorology, Fort Collins, CO, April 25-28, 1983.

11.  D. V. Sandberg, et al. , Effects Of Fire On Air - A State Of Knowledge
     Review, WO-9, U. S.  Forest Service, Washington, DC, 1978. •

12.  C. K. McMahon, "Characteristics Of Forest Fuels, Fires, And Emissions",
     Presented at the 76th Annual Meeting of the Air Pollution Control
     Association, Atlanta, GA, June 1983.

13.  D. E. Ward, "Source Strength Modeling Of Particulate Matter Emissions From
     Forest Fires", Presented at the 76th Annual Meeting of the Air Pollution
     Control Association, Atlanta, GA, June 1983.

11.1-10                         EMISSION FACTORS                        9/88

-------
14.
15.
                                                    i
D. E. Ward, et al. , "Particulate Source Strength Determination For Low-
intensity Prescribed Fires", Presented at the Agricultural Air Pollutants
Specialty Conference, Air Pollution Control Association.  Memphis,  TN.
March 18-19, 1974.                        :          j


Prescribed Fire Smoke Management Guide. 420-1,  BIFC-BLM Warehouse,  3905
Vista Avenue, Boise, ID,  February 1985.
9/88
                       Miscellaneous Sources
                                                                       11.1-11

-------

-------
 11.2.1   UNPAVED ROADS

 11.2.1.1   General

 :     Dust  plumes trailing  behind  vehicles  traveling on unpaved roads  are  a
 familiar sight  in  rural  areas  of  the  United  States.  When  a  vehicle travels  an
 unpaved  road, the  force  of the wheels on the road surface  causes  pulverization
 of surface material.   Particles are lifted and  dropped from  the rolling wheels,
 and  the  road  surface is  exposed to strong  air currents in  turbulent shear with
 the .surface.  The  turbulent wake  behind  the  vehicle continues  to  act  on the
 road  surface  after the vehicle has passed.
 i       "        f
 l'l.2.1..2   Emissions Calculation And Correction  Parameters
 •
 |     The quantity  of dust  emissions from a given  segment of  unpaved road  varies
 linearly with the  volume of traffic.   Also,  field investigations  have shown
 that  emissions  depend  on correction parameters  (average vehicle speed, average
 vehicle weight,  average number of wheels per  vehicle,  road surface texture and
 road  surface  moisture) that characterize the  condition of  a  particular road  and
 the associated  vehicle traffic.1~^

 ;     Dust  emissions from unpaved  roads have  been  found to  vary in direct
 proportion to the  fraction of  silt (particles smaller  than 75  micrometers in
 diameter)  in  the road  surface  materials.1  The  silt  fraction is determined by
 measuring  the proportion of loose dry  surface dust  that passes  a  200  mesh
 sjcreen, using the  ASTM-C-136 method.   Table  11.2.1-1 summarizes measured  silt
 values for industrial and  rural unpaved roads.
 |                      .            ,                          :
      The silt content  of a rural dirt  road will vary with  location, and it
 should be  measured.  As a  conservative approximation,  the silt  content of the
 parent soil in  the area can be used.   However,  tests show  that  road silt  con-
 tjent  is normally lower than in the surrounding parent  soil,  because the fines
 ajre continually  removed by the vehicle traffic, leaving a higher  percentage
 of coarse  particles.
 |                       '    '           .         .   .  -   i
 ;     Unpaved roads have a  hard, generally nonporous surface  that  usually  dries
 quickly after a  rainfall.  The  temporary reduction in  emissions caused by
 precipitation may  be accounted for by  not considering  emissions on "wet"  days
 (more than 0.254 millimeters [0.01 inches] of precipitation).

 :     The following empirical expression may be used to estimate the quantity of
 size  specific particulate  emissions from an unpaved road,  per vehicle kilometer
 traveled (VKT) or  vehicle  mile  traveled (VMT), with a  rating of A:


                                                                (kg/VKT)
 :    E=k(5.9)    —   [ —    —       _       	~\     (ib/VMT)
 !                 \12J  \30/  V3/     W     \36V

9/88                          Miscellaneous Sources      i              11.2.1-1

-------
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EMISSION FACTORS
9/88

-------
 where:   E = emission factor
         k = particle size multiplier (dimensionless)
  I       s = silt content of road surface material (%)
         S = mean vehicle speed,  km/hr (mph)
  |       W = mean vehicle weight, Mg (ton)
  [       w = mean number of wheels
  ,       p = number of days with  at  least 0.254 mm
             (0.01 in.) of precipitation per  year         j

 The  particle size multiplier,  k, in the equation varies  with aerodynamic particle
 size range as follows:                                   :    -

                Aerodynamic Particle Size Multiplier For  Equation
<30 uma
1.0
<30 urn
0.80
j<15 urn
0.50
<10 um <5um
0.36 0.20
^2.5 um
0.095
      The  number  of wet  days  per year, p,  for  the  geographical  area  of  interest
 shpuld  be determined  from local climatic  data.  Figure  11.2.1-1 gives  the
 geographical  distribution of the mean annual  number  of  wet days per year in  the
 United  States.                                            h

  !    The  equation retains the assigned quality rating,  if applied within the
 ranges  of source conditions  that were tested  in developing the equation, as
 follows:
                                                          i
                    Ranges Of Source Conditions For  Equation
Road silt
content
(wgt. %)
4.3 - 20
Mean vehicle weight
Mg
2.7 - 142
ton
3 - 157
.. .
Mean vehicle speed
km/hr
21 - 64
mph r
13 - 40
!
mean no.
of wheels
4-13
Aljso, to retain the quality rating of the equation when addressing a specific
unpaved road, it is necessary that reliable correction parameter values be
determined for the road in question.  The field and laboratory procedures for
determining road surface silt content are given in Referenced.  In the event
thjat site specific values for correction parameters cannot: be. obtained, the
appropriate mean values from Table 11.2.1-1 may be used, but the quality rating
ofithe equation is reduced to B.                          j
                                                          i •
     The equation was developed for calculating annual average emissions, and
thus, is to be multiplied by annual vehicle distance traveled (VDT).  Annual
average values for each of the correction parameters are to be substituted for
the equation.  Worst case emissions, corresponding to dry road conditions, may
be; calculated by setting p = 0 in the equation (equivalent: to dropping the last
9/88
Miscellaneous Sources
11.2.1-3

-------
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11.2.1-4
                                      EMISSION FACTORS
9/88

-------
 term from the equation).  A separate set of nonclimatic correction parameters
 andi a higher than normal VDT value may also be justified for the worst case
 average period (usually 24 hours).  Similarly, in using the equation to calcu-
 late emissions for a 91 day season of the year, replace the term (365-p)/365
 with the term (91-p)/91, and set p equal to the number of wet days in the 91 day
 period.  Also, use appropriate seasonal values for the nonclimatic correction
 par&meters and for VDT.                                    I

 11.2.1.3  Controls

  _    Common control techniques for unpaved roads are paving;, surface treating
 with penetration chemicals,  working into the roadbed of stabilization chemicals
 watering,  and traffic control regulations.   Chemical stabilizers work either by'
 binding the surface material or by enhancing moisture retention.  Paving  as a
 control technique, is often not economically practical.  Surface chemical treat-
 ment;  and watering can be accomplished  with  moderate  to low costs,  but frequent
 ^treatments are required.   Traffic controls,  such as speed limits and traffic
 volume  restrictions,  provide moderate  emission reductions  but  may  be  difficult
 to  enforce.   The control efficiency obtained by speed reduction can be calcu-
 lated using the  predictive  emission factor  equation  given  above.
                                                            i
   _ ! The control  efficiencies  achievable by paving can be  estimated by comparing
 emission factors  for  unpaved and  paved  road conditions,  relative to airborne
 particle size range of  interest.   The  predictive emission  factor equation for
 paved roads,  given in Section  11.2.6,  requires  estimation  of the silt  loading
 on  the  traveled portion of the  paved surface, which  in turn depends on whether
 the pavement  is periodically cleaned.   Unless curbing  is to  be installed,  the
 effects  of  vehicle excursion onto  shoulders  (berms)  also must be taken into
 account  in estimating control efficiency.                   i

     The control  efficiencies afforded by the periodic use  of road stabilization
 chemicals are much more difficult to estimate.  The application  parameters
 which determine control efficiency include dilution ratio, application intensity
 (.mass of diluted  chemical per road area) and application frequency.  Other
 factors  that affect the performance of chemical stabilizers include vehicle
 characteristics (e. g., traffic volume, average weight) and road characteristics
 (e. g.,  bearing strength).

     Besides water, petroleum resin products have historically been the dust
suppressants most widely used on industrial unpaved roads.   Figure 11.2 1-2
presents a method to estimate average control efficiencies associated with
petroleum resins applied to unpaved roads.  Several items should be noted:

    ' 1.   The term "ground inventory" represents the total volume (per
    ,     unit area) of petroleum resin  concentrate  (not solution)
         applied since the start of the dust control~sea'soiu^

     2.   Because petroleum resin products must  be periodically  reapplied
         to unpaved roads,  the  use of a time-averaged control efficiency
         value is  appropriate.   Figure  11.2,, 1-2 presents control  effi-
         ciency values averaged over two common application intervals,
    !     two weeks and one month.   Other application  intervals will
         require  interpolation.
                                                .
 9/88                        Miscellaneous Sources           i           11.2.1-5

-------
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      3.  Note that zero efficiency is assigned until the ground inventory
          reaches 0.2 liters per square meter (0.05 gallons per square yard).

      As an example of the use of Figure 11.2.1-2, suppose that the equation has
 rrv, JfT*:   estimaje an emlssion factor of 2-0 kilograms; per vehicle kilometer
 traveled for particles equal to or less than 10 microns from a particular road.
 Also,  suppose that, starting on May 1, the road is treated with 1 liter per
 square meter of a (1 part petroleum resin to 5 parts water) solution on the
 first  of each month until October.  Then,  the following average controlled
 emission factors are found:
Period
May
June
July
August
September
aFrom Figur
inventory
Ground
Inventory
(L/m2)
0.17
0.33
0.50
0.67
0.83
e 11.2.1-2, < 10
is less than 0.2
Average Control
Efficiency3
f °/ \ '
\ fo j
0
62
68
74-
80
Average Controlled
Emission Factor
(kg/VKT)
2.0
0.76
0.64
0.52
0.40
urn. Zero efficiency assigned if ground
L/m2 (0.05 gal/yd2).
     Newer dust suppressants have been successful  in  controlling emissions  from
unpaved roads.  Specific test results for those chemicals,, as well as 'for petro-
leum resins, are provided in References 14 through 16.                    P


References for Section 11.2.1

 1,  C. Cowherd, Jr. , et al., Development Of Emission Factors For Fugitive  Dust
 2i   R. J. Dyck and J. J. Stukel, "Fugitive Dust Emissions From Trucks On
  i   Unpaved Roads , Environmental Science and Technology: ,10(10) : 1046-1048,
     UCtODG3T 1976»                                        i
                                                          I

 3.   R. 0. McCaldin and K.  J.  Heidel, "Particulate Emissions From Vehicle
     Travel Over Unpaved Roads",  Presented at the 71st Annual Meeting of the
     Air Pollution Control  Association,  Houston, TX, June 1978.

 4. 1   C. Cowherd,  Jr.,  et al. .  Iron And Steel Plant Open Dust Source
 5.
                 " '       -•• -               __~_	~"  "f •***«. **\*.i* i, IS\J\Ai. ^.c A *•*& -L L. J. \
    	Evaluation, EPA-600/2-79-013, U. S. Environmental Protection
Agency, Cincinnati, OH, May 1979.
                                            '
                 Fugit.ive Emissions From Integrated Iron And Steel Plants.
                ,  U. S. Environmental Protection Agency, Cincinnati, OH,
    March  1978
9/88
                            Miscellaneous  Sources
                                                                       11.2.1-7

-------
 6.   R.  Bohn,  Evaluation Of  Open  Dust  Sources  In The  Vicinity  Of  Buffalo, New
     York,  EPA Contract No.  68-02-2545, Midwest  Research Institute, Kansas
     City,  MO, March 1979.

 7.   C.  Cowherd,  Jr.,  and T. Cuscino,  Jr.,  Fugitive Emissions  Evaluation,
     MRI-4343-L,  Midwest Research Institute, Kansas City,  MO,  February 1977.

 8.   T.  Cuscino,  Jr.,  et al., Taconite Mining  Fugitive Emissions  Study,
     Minnesota Pollution Control  Agency,  Roseville, MN, June 1979.

 9.   K.  Axetell and C. Cowherd,  Jr.,  Improved  Emission Factors For  Fugitive
     Dust From Western Surface Coal Mining Sources, 2 Volumes, EPA  Contract
     No. 68-03-2924, PEI, Inc.,  Kansas City, MO, July 1981.

10.   T.  Cuscino,  Jr.,  et al., Iron And Steel Plant Open Source Fugitive Emis-
     sion Control Evaluation, EPA-600/2-83-110,  U. S. Environmental Protection
     Agency, Cincinnati, OH, October  1983.

11.   J.  Patrick Reider, Size Specific Emission Factors For Uncontrolled Indus-
     trial and Rural Roads,  EPA Contract No. 68-02-3158, Midwest Research
     Institute, Kansas City, MO, September 1983.

12.   C.  Cowherd, Jr., and P. Englehart, Size Specific Particulate Emission
     Factors For Industrial And Rural Roads, EPA-600/7-85-038, U. S. Environ-
     mental Protection Agency, Cincinnati, OH,  September  1985.

13.  .Climatic Atlas Of The United States, U. S. Department Of Commerce,
     Washington, DC, June 1968."

14.  G. E. Muleski, et al.. Extended Evaluation Of Unpaved Road  Dust Suppres-
     sants In The  Iron And  Steel Industry, EPA-600/2-84-027,  U.  S. Environmental
     Protection  Agency,  Cincinnati, OH, February  1984.

 15.  C. Cowherd, Jr.,  and J.  S.  Kinsey, Identification. Assessment And Control
     Of Fugitive Particulate  Emissions, EPA-600/8-86-023,  U.  S.  Environmental
     Protection  Agency,  Cincinnati, OH, August  1986.

 16.  G. E. Muleski and C. Cowherd, Jr., Evaluation Of The Effectiveness Of
     Chemical Dust Suppressants  On Unpaved Roads,  EPA-600/X-XX-XXX,  U. S.
     Environmental Protection Agency,  Cincinnati,  OH,  November  1986.
 11.2.1-8
                                 EMISSION FACTORS
                                                                         9/88

-------
 11.2.3  AGGREGATE HANDLING AND STORAGE PILES              |

 11.2.3,1  General                                    -[...'

    !  Inherent in operations that use minerals in aggregate form is the
 maintenance of outdoor storage piles.   Storage piles  are  usually left  uncovered,
 partially because of the need for frequent material transfer into or out of
 storage.                                                  i
                                                             • :
    *                                                       i
    |  Dust emissions  occur at several points in the storage cycle,  such as
 during material loading onto the pile,  disturbances by  strong wind currents,
 and loadout from the pile.   The movement  of trucks and  loading equipment in the
 storage pile area is also a substantial source of  dust.

 11.2.3.2  Emissions  And Correction Parameters

    I  The quantity of dust emissions from  aggregate storage operations  varies
 with the volume of aggregate passing through the storage  cycle.   Also,  emis-
 sions depend on three parameters of the condition  of  a  particular  storage pile:
 age of the pile,  moisture content and  proportion of aggregate fines.
    1                    '       '         '              '!"'••
      When freshly processed aggregate  is  loaded  onto  a  storage pile, its
 potential for dust emissions is at a maximum.   Fines  are  easily  disaggregated
 and| released to the  atmosphere upon exposure to  air currents, either from aggre-
 gate transfer itself or from high winds.   As the aggregate weathers, however,
 potential for dust emissions  is greatly reduced.   Moisture causes  aggregation
 and; cementation of fines  to the surfaces  of larger particles.  Any significant
 rainfall soaks  the interior of the  pile,  and the drying process  is  very  slow.
                                                           i
    !  Silt (particles equal  to or less  than 75 microns in  diameter)  content  is
 determined  by measuring the portion of  dry aggregate material that  passes
 through a 200 mesh screen,  using ASTM-C-136 method.   Table 11.2.3-1 summarizes
 measured silt and  moisture  values  for industrial aggregate materials.

 11.2.3.3  Predictive Emission Factor Equations
    !                 .                                      i
    I  Total  dust  emissions from aggregate  storage piles are contributions of
 several distinct  source activities  within the  storage cycle:
    I  1.   Loading  of  aggregate  onto  storage  piles (batch oricontinuous drop
    !      operations).
          Equipment traffic  in  storage area.          .      [    .
         Wind erosion of pile  surfaces and ground areas  around piles.
         Loadout of  aggregate  for shipment or  for return to the process stream
          (batch or continuous drop operations).            j
2.
3.
4.
     Adding aggregate material to a storage pile or removing it both usually
involve dropping the material onto a receiving surface.   Truck dumping on the
pile or loading out from the pile to a truck with a front end loader are exam-
ples of batch drop operations.  Adding material to the pile by a conveyor
stacker is an example of a continuous drop operation.
 9/88
                        Miscellaneous  Sources
11.2.3-1

-------
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          11.2.3-2
                                                      EMISSION  FACTORS
                                                                                                               9/8.8

-------
      The quantity of particulate emissions generated by either type of drop
 operation, per ton of material transferred, may be estimated, with a rating of
 A,i using the following empirical expression2;
           E = k(0.0016)
           E = k(0.0032)
        (kg/Mg)
        (Ib/ton)
 where:   E  = emission  factor
   :      k  = particle  size  multiplier  (dimensionless)
         U  = mean  wind speed, m/s  (mph)
         M  = material  moisture content  (%)
   i
 The  particle size multiplier, k,  varies with  aerodynamic particle diameter, as
 shown in Table  11.2.3-2.
           TABLE  11.2.3-2.  AERODYNAMIC PARTICLE SIZE MULTIPLIER  (k)
<30 um
0.74
(15 um
0.48
<10 um
0.35
<5
0.
um
20
<2.5 um
0.11
   I  The equation retains the assigned quality rating if applied within the
ranges of source conditions that were tested in developing the equation, as
given in Table 11.2.3-3.  Note that silt content is included in Table 11.2.3-3,
even though silt content does not appear as a correction parameter in the equa-
tion.  While it is reasonable to expect that silt content and emission factors
are; interrelated, no significant correlation between the two was found during
the! derivation of the equation, probably because most tests?: with high silt
contents were conducted under lower winds, and vice versa.i  It is recommended
that estimates from the equation be reduced one quality rating level, if the
silt content used in a particular application falls outside the range given in '
Table 11.2.3-3.
9/8,8
Miscellaneous Sources
                                                                       11.2.3-3

-------
          TABLE 11.2.3-3.  RANGES OF SOURCE CONDITIONS FOR EQUATION 1
Silt
Content
0.44 - 19
Moisture
Content
0.25 - 4.8
Wind Speed
(m/s) (mph)
0.6-6.7 1.3 - 15
     Also, to retain the equation's quality rating when applied to  a  specific
facility, it is necessary that reliable correction parameters be determined for
the specific sources of interest.  The field and laboratory procedures  for
aggregate sampling are given in Reference 3.  In the event that site  specific
values for correction parameters cannot be obtained, the appropriate  mean
values from Table 11.2.3-1 may be used, but, in that case, the quality  rating
of the equation is reduced by one level.

     For emissions from equipment traffic (trucks, front end loaders, dozers,
etc.) traveling between or on piles, it is recommended that the equations for
vehicle traffic on unpaved surfaces be used (see Section 11.2.1).  For  vehicle
travel between storage piles, the silt value(s) for the areas among the piles
(which may differ from the silt values for the stored materials) should be  used.

     Worst case emissions from storage pile areas occur under dry windy condi-
tions*  Worst case emissions from materials handling operations may be  calcu-
lated by substituting into the equation appropriate values for aggregate material
moisture content and for anticipated wind speeds during the worst case  averaging
period, usually 24 hours.  The treatment of dry conditions for vehicle  traffic
(Section 11.2.1), centering on parameter p, follows the methodology described
in Section 11.2.1.  Also, a separate set of nonclimatic correction  parameters  and
source extent values corresponding to higher than normal storage pile activity
may be justified for the worst case averaging period.

11.2.3.4  Controls

     Watering and chemical wetting agents are the principal means for control
of aggregate storage pile emissions.  Enclosure or covering of inactive piles
to reduce wind erosion can also reduce emissions.  Watering is useful mainly to
reduce emissions from vehicle traffic in the storage pile area.  Watering of
the storage piles themselves typically has only a very temporary slight effect
on total emissions.  A much more effective technique is to apply chemical wet-
ting agents for better wetting of fines and longer retention of the moisture
film.  Continuous chemical treatment of material loaded onto piles, coupled
with watering or treatment of roadways, can reduce total particulate  emissions
from aggregate storage operations by up to 90 percent-9


References for Section 11.2.3

1.  C. Cowherd, Jr., et al., Development Of Emission Factors For Fugitive Dust
    Sources, EPA-450/3-74-037, U. S. Environmental Protection Agency, Research
    Triangle Park, NC, June 1974.


11.2.3-4                        EMISSION FACTORS                           9/88

-------
2.
3.
4.
5.
6.
7.
8.
9.
 R.  Bohn,  et  al.,  Fugitive Emissions From  Integrated  Iron And  Steel  Plants.
 EPA-600/2-78-050, U.  S.  Environmental  Protection Agency, Cincinnati, OH
 March  1978.

 C.  Cowherd,  Jr.,  et al., Iron And  Steel Plant Open Dust Source Fugitive
 Emission  Evaluation,  EPA-600/2-79-103, U.  S. Environmental Protection
 Agency, Cincinnati, OH, May 1979.

 R.  Bohn,  Evaluation Of Open Dust Sources  In The  Vicinity Of Buffalo.
 New York, EPA Contract No. 68-02-2545, Midwest Research Institute,  Kansas
 City, MO, March 19799

 C.  Cowherd,  Jr., and  T. Cuscino, Jr.,  Fugitive Emissions Evaluation.
MRI-4343-L,  Midwest Research Institute, Kansas City, MO, February 1977.
                                                  "*  I '
 T.  Cuscino,  et al.. Taconite Mining Fugitive Emissions Study. Minnesota
 Pollution Control Agency, Roseville, MN, June 1979. |

K.  Axetell and C. Cowherd, Jr., Improved Emission Factors For Fugitive
Dust From Western Surface Coal Mining Sources.  2 Volumes,  EPA Contract
No. 68-03-2924, PEI,  Inc., Kansas City, MO, July 1981.
                                                          _•
E.  T.  Brookman, et al.. Determination of Fugitive Coal Dust Emissions From
Rotary Railcar Dumping. 1956-L81-00, TRC,  Hartford, CT, May 1984.

G. A.  Jutze,  et -al,. Investigation Of Fugitive  Dust ISources Emissions And
Control, EPA-450/3-74-036a,  U.  S. Environmental Protection Agency, Research
Triangle Park,  NC, June 1974.
9/88
                        Miscellaneous Sources
                                                                      11.2.3-5

-------

-------
 11.2.6  INDUSTRIAL PAVED ROADS

 11.2.6.1   General
                                                         I

  I    Various  field studies  have  indicated that  dust  emissions  from industrial
 paved roads are  a  major  component  of  atmospheric particulate matter in the
 vicinity of industrial operations.   Industrial  traffic  dust has  been  found  to
 consist  primarily  of  mineral matter,  mostly tracked  or  deposited onto the road-
 way by vehicle traffic itself, when vehicles  enter from an unpaved area  or
 travel on the  shoulder of the  road,  or when material is  spilled onto the paved
 surface  from  open  truck  bodies.
                                                         !
 11.2.6.2   Emissions And  Correction Parameters^-~2
  !
  i    The  quantity  of  dust emissions  from  a given segment jof paved  road varies
 linearly  with  the  volume of traffic.  In  addition, field investigations  have
 shown that emissions  depend on correction parameters (road surface  silt content,
 surface  dust loading  and average vehicle  weight) of  a particular road and asso-
 ciated vehicle traffic.

  I    Dust emissions from industrial  paved roads have been found to  vary  in
 direct proportion  to  the fraction of  silt (particles equal to or less than 75
 microns  in diameter)  in  the road surface  material.  The  silt fraction is deter-
 mined by  measuring the proportion of  loose dry surface dust that passes a 200
 mesh screen, using the ASTM-C-136 method.  In addition,  it has also been found
 that  emissions vary in direct proportion  to the surface  dust loading.  The road
 surface dust loading  is  that loose material which can be collected  by broom
 sweeping  and vacuuming of the traveled portion of the paved road.  Table 11.2.6-1
 summarizes measured silt and loading  values for industrial paved roads.

 11.2.6.3  Predictive  Emission Factor Equations

  :    The  quantity  of  total suspended particulate emissions generated by vehicle
 traffic on dry industrial paved roads, per vehicle kilometer traveled (VKT) or
 vehicle mile traveled (VMT), may be estimated with a rating of B or D (see
 below), using the  following empirical expression^:
         0.022 I
     E - 0.022 I  /	
                                                  (kg/VKX)
                                                  (Ib/VMT)
                                                                            (1)
where:  E = emission factor
        I = industrial augmentation factor (dimensionless) (see below)
  I      n = number of traffic lanes
  I      s = surface material silt content (%)
        L = surface dust loading, kg/km (Ib/mile) (see below)
        W = average vehicle weight, Mg (ton)
9/88
                             Miscellaneous Sources
                                                                       11.2.6-1

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11.2.6-2
EMISSION FACTORS
9/88

-------
  ;    The industrial road augmentation factor (I) in Equation  1  takes  into  account
 higher emissions from industrial roads than from urban roads.   I =  7.0  for  a
 paved industrial roadway which traffic /enters f^oto unpaved areas.   I  =  3.5  for
'an  industrial roadway; w^^^                                     of the  vehicles
 are forced to travel "temporarily ;wiJ:h^                          shoulder.   I =  1.0
 for cases inv. which •: tr-affic^r.^^                                          1.0 and •
 7;0 which best represents conditiohs^fbf" pa^dVtoadl? at a
                                                           certain industrial
facility  should  be used for 1 in the equatiott;   -.-.'••.
  I      -•   /•  ..•   ..;  .  -  '•   ..  ' • ••.;.•% •-••:<-.. ••..**• :•?-,-••<. V-' ;•;•;•'•'.

      The  equation retains the quality rating of B if applied to vehicles
traveling entirely on  paved surfaces (I = 1^.0) and if applied within the range
of  source conditions that were tested in developing the equation as follows:
Silt
content
(%)
5.1-92
Surface loading ;
kg/km . . Ib/mile
42.0 - 2000 >„ U9 - YtiDO"'
/ ^ -\
- • • '• -
No. of
lanes
i2 **4 -
Vehicle weight
Mg tons
^2.7 - 12 3-13
If I is less than 1.0,  the  rating of  the equation drops to D, because of the
subjectivity in the guidelines foT estimating 1.         i
  f                                                               •
     The quantity of particle  emissions in the/finer size ranges generated by
traffic consisting predominately of medium and heavy duty vehicles on dry
industrial paved roads,  per vehicle unit of travel, may be estimated, with a
rating of A, using the  equation:   .
                    0.3
     E = k(3.5)
                                  (kg/VKT)
                                  (lb/VMT)
                                                                             (2)
where:   E  = emission factor            :
         sL = road surface  silt  loading, g/m2  (bz/yd%

  j   The particle size multiplier  (k) above  varies  with aerodynamic size range
as follows:
                           Aerodynamic  Particle Size
                         Multiplier  (k)  For Equation 2
                                 (Dimensionless)
                          <15 urn
                                     OO.tM;
<2,5 urn
                           0.28      0.22
9/88
                             Miscellaneous  Sources
                         11.2.6-3

-------
 To determine particulate emissions for a specific particle size range, use the
 appropriate value of k above.

      The equation retains the quality rating of A, if applied within the range
 of source conditions that were tested in developing the equation as follows:

      silt loading, 2 - 240 g/m2 (0.06 - 7.1 oz/yd2)

      mean vehicle weight, 6 - 42 Mg (7 - 46 tons)

      The following single valued emission factors^ may be used in lieu of
 Equation 2 to estimate particle emissions in the finer size  ranges generated  by
 light duty vehicles on dry, heavily loaded industrial roads,  with a rating of C:
                         Emission Factors For Light Duty
                         Vehicles On Heavily Loaded Roads
                              <15 urn
    <10 urn
                           0.12 kg/VKT
                          (0.41 Ib/VMT)
 0.093 kg/VKT
(0.33 Ib/VMT)
 These emission factors  retain  the  assigned  quality  rating, if applied within
 the range  of  source  conditions that  were  tested  in  developing the factors, as
 follows:

      silt  loading, 15 - 400 g/m2 (0.44  -  12 oz/yd2)

      mean  vehicle weight, 
-------
 '    Although there are relatively few quantitative data on emissions from
controlled paved roads, those that are available indicate that adequate esti-
mates generally may be obtained by substituting controlled loading values into
Equations 1 and 2.  The major exception to this is water flushing combined
with broom sweeping.  In that case, the equations tend to overestimate emis-
sions substantially (by an average factor of 4 or more).
 !                         •                               I '   '
     On a paved road with moderate traffic (500 vehicles per day), to achieve
control efficiencies on the order of 50 percent, requires cleaning of the
surface at least twice per week.4  This is because of the characteristically
rapid buildup of road surface material from spillage and the tracking and depo-
sition of material from adjacent unpaved surfaces, including the shoulders
(berms) of the paved road.  Because industrial paved roads usually do not have
curbs, it is important that the width of the paved road surface be sufficient
for vehicles to pass without excursion onto unpaved shoulders.  Equation 1
indicates that eliminating vehicle travel on unpaved or untreated shoulders
would effect a major reduction in particulate emissions.  An even greater
effect, by a factor of 7, would result from preventing travel from unpaved
roads or parking lots onto the paved road of interest.   |
References for Section 11.2.6

1.  R. Bohn, et al., Fugitive Emissions From Integrated Oron And Steel Plants,
  !  EPA-600/2-78-050, U. S. Environmental Protection Agency, Cincinnati, OH,
  !  March 1978.

2.  C. Cowherd, Jr., et al., Iron And Steel Plant Open Dust Source Fugitive
  I  Emission Evaluation, EPA-600/2-79-103, U. S. Environmental Protection
  i  Agency, Cincinnati, OH, May 1979.

3.  R. Bohn, Evaluation Of Open Dust Sources In The Vicinity Of Buffalo,
    New York, EPA Contract No. 68-02-2545, Midwest Research Institute, Kansas
  i  City, MO, March, 1979.

4;  T. Cuscino, Jr. , et al., Iron And Steel Plant Open Source Fugitive Emission
    Control Evaluation, EPA-600/2-83-110, U. S. Environmental Protection Agency,
    Cincinnati, OH, October 1983.

5;.  J. Patrick Reider, Size Specific Particulate Emission Factors For Uncon-
  !  trolled Industrial And Rural Roads, EPA Contract No. 68-02-3158, Midwest
  j  Research Institute, Kansas City, MO, September 1983.

61  C. Cowherd, Jr., and P. Englehart, Size Specific Particulate Emission
  !  Factors For Industrial And Rural Roads, EPA-600/7-85-038, U. S. Environ-
  i  mental Protection Agency, Cincinnati, OH, September 1985.
 9/88
Miscellaneous Sources
11.2.6-5

-------

-------
11.2.7  INDUSTRIAL WIND EROSION
 '                              '                         i
li.2.7.1  General1-3                                    !
                                                        i

 j    Dust emissions may be generated by wind erosion of open aggregate storage
piles and exposed areas within an industrial facility.  These sources typically
are characterized by nonhomogeneous surfaces impregnated with nonerodible ele-
ments (particles larger than approximately 1 cm in diameter).  Field testing of
coal piles and other exposed materials using a portable wind tunnel has shown
that (a) threshold wind speeds exceed 5 m/s (11 mph) at iL5 cm above the surface
or 10 m/s (22 mph) at 7 m above the surface, and (b) parl:iculate emission rates
tend to decay rapidly (half life of a few minutes) during an erosion event.  In
other words, these aggregate material surfaces are characterized by finite
availability of erodible material (mass/area) referred to as the erosion
potential.  Any natural crusting of the surface binds the erodible material,
thereby reducing the erosion potential.
 !
11.2.7.2  Emissions And Correction Parameters
 t
 i_
 i    If typical values for threshold wind speed at 15 cm are corrected to
typical wind sensor height (7-10 m), the resulting values exceed the upper
extremes of hourly mean wind speeds observed in most areas of the country.  In
other words, mean atmospheric wind speeds are not sufficient to sustain wind
erosion from flat surfaces of the type tested.  However, wind gusts may quickly
deplete a substantial portion of the erosion potential.  Because erosion poten-
tial has been found to increase rapidly with increasing wind speed, estimated
emissions should be related to the gusts of highest magnitude.
 1           •                                            i '
     The routinely measured meteorological variable which best reflects the
magnitude of wind gusts is the fastest mile.  This quantity represents the wind
speed corresponding to the whole mile of wind movement which has passed by the
1!mile contact anemometer in the least amount of time.  Daily measurements of
the fastest mile are presented in the monthly Local Climatological Data (LCD)
summaries.  The duration of the fastest mile, typically about 2 min (for a
fastest mile of 30 mph), matches well with the half life of the erosion
process, which ranges between 1 and 4 min.  It should be noted, hbWever, that
peak winds can significantly exceed the daily fastest mile.
 '           .        ' .        '               .            i            •
 I    The wind speed profile in the surface boundary layer is found to follow a
logarithmic distribution:
where u
 1     u*
 i     z
 :     zo
 ,     0.4
                 u(z) = u*  In z   (z > z0)
                        0.4    z0

wind speed, cm/sec
friction velocity, cm/sec
height above test surface, cm
roughness height, cm
von Karman's constant, dimensionless
                                                                 (1)
The friction velocity (u*) is a measure of wind shear stress on the erodible
surface, as determined from the slope of the logarithmic velocity profile.  The
roughness height (zo) is a'measure of the roughness of the exposed surface as
determined from the y intercept of the velocity profile, i.e., the height at
9/88
                 Miscellaneous Sources
.2.7-1

-------
which the wind speed is zero.  These parameters are illustrated in Figure
11.2.7-1 for a roughness height of 0.1 cm.

     Emissions generated by wind erosion are also dependent on the frequency of
disturbance of the erodible surface because each time that a surface is dis-
turbed, its erosion potential is restored.   A disturbance is defined as an
action which results in the exposure of fresh surface material.  On a storage
pile, this would occur whenever aggregate material is either added to or
removed from the old surface.  A disturbance of an exposed area may also-result
from the turning of surface material to a depth exceeding the size of the
largest pieces of material present.

11.2.7.3  Predictive Emission Factor Equation*

     The emission factor for wind generated particulate emissions from mixtures
of erodible and nonerodible surface material subject to disturbance may be
expressed in units of g/m^-yr as follows:

                                             N

                       Emission factor = k       P          (2)

                                           i = 1

where k  3 particle size multiplier
      N  = number of disturbances per year
      Pi » erosion potential corresponding to the observed (or probable)
           fastest mile of wind for the ith period between disturbances,
           g/m2

The particle size multiplier (k) for Equation 2 varies with aerodynamic
particle size, as follows:

             AERODYNAMIC PARTICLE SIZE MULTIPLIERS FOR EQUATION 2

                   <30 urn    <15 urn    <10 urn    <2.5 urn
                     1.0       0.6       0.5        0.2

This distribution of particle size within the <30um fraction is comparable
to the distributions reported for other fugitive dust sources where wind speed
is a factor.  This is illustrated, for example, in the distributions for batch
and continuous drop operations encompassing a number of test aggregate materials
(see Section 11.2.3).

In calculating emission factors, each area of an erodible surface that is sub-
ject to a different frequency of disturbance should be treated separately.  For
a surface disturbed daily, N = 365/yr, and for a surface disturbance once
every 6 months, N = 2/yr.

Equations 2 and 3 apply only to dry, exposed materials with limited erosion
potential.  The resulting calculation is valid only for a time period as long
or longer than the period between disturbances.  Calculated emissions repre-
sent intermittent events and should not be input directly into dispersion
models that assume steady state emission rates.

11.2.7-2                        EMISSION FACTORS                           9/88

-------

             B
        Figure 11.2.7-1.  Illustration of logarithmic velocity profile.




9/88                         Miscellaneous Sources
                                                                       11.2.7-3

-------
The  erosion potential

               •  -p-58
                          nASlonyfor ^^ ^^                                r

                          (u* - 1^)2*25 <.:;   ;:                           ,  •     ,J

 Threshold friction velocities  for several surface types have been determined
 by field measurements wifh  a portable wind  tunnel.  These values are presented
 in Table 11.2.7-1.  ,-.,           »'  i  ,  -   ^            _         .     ;
                     •  .        •  *      $                             • ;•;•  ••   -"
          TABLE 11.2.7-1.  FIELD PROCEDURE FOR DETERMINTION OF THRESHOLD
                                 FRICTION VELOCITY
Tyler
sieve no.
5 . --;:•

9

16

32

60
Opening Midpoint
(mm) (mm)
,-<,'•'• -.', •''.•'• • •'
• .• . • . • . :'••-'- ... ' ' • . -
'-'•' ^r.^/^-X-'' -••v'";.
. ; ^ ;, ...:;. 3 . ..;
'. .• 2':;-'- - •''/ - .-;• • '..• •;'
'.'• '••''• ''"••'*•' •' '':'''-. v"i.5' '•''
i ' ' •
0.75
0.5
.: • -,:'.. ••:-••'•. .<.:•.. -':-. 0,375.-
''\.:r^^.^."Si:'^; '•''..- '.
u* (cm/sec)
t

100

,72

58

43 .
-'-'"',.,!• • . '. •
-• ,- , ,-,; ' \". - , -» > . . '- '
        FIELD  PROCEDURE  FOR DETERMINATION OF THRESHOLD FRICTION  VELOCITY
           (from a  1952 laboratory procedure published by W.  S. Chepil)

1.  Prepare a  nest of  sieves with the following openings:  4 mm, 2 mm,  1 mm,
    0.5 mm, 0.25 mm.   Place a collector pan below tlm  crhhrj r f taga *5M36
2.  Collect a sample  representing the s,ur,fa;pe layer of loose particles
    (approximately  1  cm in depfch, for ;an >fnc.rusted surface), removing any rocks
                           "*    - '»  *i'v~ t*f^in''^L * "'JS*!!*1 '''''.                   .      '.,,,-
 1+ n -, t                   -•,-,. , ^iift-t'** - *. • ^wfr- '*,  -  ,-.^ , - :                  ••
 1-2.7-4                     >^*EMISSIP^ FACTORS ';            :"".:          9/88

-------
    larger than about 1 cm in average physical diameter.
    sampled should be not less than 30 cm.
                             The area to be
3.  Pour the sample into the top sieve (4 mm opening), a:hd place a lid on the
 t   top.

4J.  Move the covered sieve/pan unit by hand, using a broad circular arm motion
    in the horizontal plane.  Complete 20 circular movements at a speed just
    necessary to achieve some relative 'horizontal motion between the sieve and
    the particles.

5j.  Inspect the relative quantities of catch within each sieve, and determine
 ;   where the mode in the aggregate size distribution lies, i. e. , between the
 •   opening size of the sieve with the largest catch and the opening size of
    the next largest sieve.-  • .

6.  Determine the threshold friction velocity from Figure 1.
 1                       :                  '              I    '
The fastest mile of wind for the periods between disturbances may be obtained
firom the monthly LCD summaries for the nearest reporting weather station that
is representative of the site in question.^  These summaries report actual
fastest mile values for each day of a given month.  Because the erosion
potential is a highly nonlinear function.of the. fastest mile, mean values of
the fastest mile are inappropriate.  The anemometer heights of reporting
weather stations are found in Reference 8, and should be corrected to a 10 m
reference height using Equation 1.
                TABLE 11.2.7-2.  THRESHOLD FRICTION VELOCITIES

;

1 Material
i
Overburden3
Sporia (roadbed
material)3
Ground coala
. (surrounding coal
i pile)
Uncrusted coal pilea
Scraper tracks on
coal pilea>b
Fj.ne coal dust on
< concrete padc
i
a| Western surface coal
b Lightly crusted.
ci Eastern power plant.
Threshold
friction
velocity
(m/s)
1.02
1.33

0.55


1.12
0.62

0.54

mine.


Roughness
height
(cm)
0.3
0.3

0.01


0.3
0.06

0.2




Threshold wind . ,
velocity at 10 m (m/s)
z0 = Actual z0 = 0.5 cm
21 19
27 25

16 10


23
15

11





21
12

10




Ref.
2
2

2


2
2

3


9!/88
Miscellaneous Sources
11.2.7-5

-------
To convert the fastest mile of wind (u+) from a reference anemometer height of
10 m to the equivalent friction velocity (u*), the logarithmic wind speed
profile may be used to yield the following equations

                                u* = 0.053 u+10          (4)

where u*   = friction velocity (m/s)

      u IQ ** fastest mile of reference anemometer for period between
               disturbances (m/s)
                                                     x
This assumes a typical roughness height of 0.5 cm for open terrain.
Equation 4 is restricted to large relatively flat piles or exposed areas with
little penetration into the surface wind layer.

If the pile significantly penetrates the surface wind layer (i.e., with a
height-to-base ratio exceeding 0.2), it is necessary to divide the pile area  .
into subareas representing different degrees of exposure to wind.   The results
of physical modeling show that the frontal face of an elevated pile is exposed
to wind speeds of the same order as the approach wind speed at the top of the
pile.

For two representative pile shapes (conical and oval with flattop, 37 degree
side slope), the ratios of surface wind speed (us) to approach wind speed (ur)
have been derived from wind tunnel studies.^  The results are shown in
Figure 11.2.7-2 corresponding to an actual pile height of 11 m, a  reference
(upwind) anemometer height of 10 m, and a pile surface roughness height (zo)
of 0.5 cm.  The measured surface winds correspond to a height of 25 cm above
the surface.  The area fraction within each contour pair is specified in
Table 11.2.7-3.

The profiles of us/ur in Figure 11.2.7-2 can be used to estimate the surface
friction velocity distribution around similarly shaped piles, using the
following procedure:

1.   Correct the fastest mile value (u+) for the period of interest from the
     anemometer height (z) to a reference height of 10 m (u ^Q) using a
     variation of Equation 1:

                  u+1Q = u+ In (10/0.005)         (5)
                            In  (z/0.005)

     where a typical roughness height of 0.5 cm (0.005 m) has been assumed.
     If a site specific roughness height is available, it should be used.

2.   Use the appropriate part of Figure 11.2.7-2 based on the pile shape and
     orientation to the fastest mile of wind, to obtain the corresponding sur-
     face wind speed distribution (u+ ):
                                     S

                   u+s = Cs) u+10           (6)  ,
11.2.7-6                        EMISSION FACTORS                           9/88

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;   Flow
! Direction
                    Pile A
                               Pile B1
         Figure  11.2.7-2.   Contours  of  Normalized Surface Wind Speeds,  us/ur
  9/88
Miscellaneous Sources
                                                                          11.2.7-7

-------
3.   For any subarea of the pile surface having a narrow range of surface wind
     speed, use a variation of Equation 1 to calculate the equivalent friction
     velocity (u*):

                       0.4 u+
                  u* - 	 = 0.10 UH"
                          25_
                        1*0.5

From this point on, the procedure is identical to that used for a flat pile,
as described above.

Implementation of the above procedure is carried out in the following steps;

1.   Determine threshold friction velocity for erodible material of  interest
     (see Table 11.2.7-2 or determine from mode of aggregate size
     distribution).

2.   Divide the exposed surface area into subareas of constant frequency of
     disturbance (N).
           TABLE 11.2.7-2.  SUBAREA DISTRIBUTION FOR REGIMES OF us/ur
Percent of pile surface area (Figure
Pile subarea
0.2a
0.2b
0.2c
0.6a
0.6b
0.9
1.1
Pile A
5
35
-
48
-
12
••»
Pile Bl
5
2
29
26
24
14
™"
Pile B2
3
28
-
29
22
.. 15
3
11.2.7-2)
Pile B3
3
25
•
28
26
14
4
3.   Tabulate fastest mile values (u+) for each frequency of disturbance and
     correct them to 10 m (U+IQ) using Equation 5.

4.   Convert fastest mile values (U+IQ) to equivalent friction velocities (u*),
     taking into account (a) the uniform wind exposure of nonelevated surfaces,
     using Equation 4, or (b) the nonuniform wind exposure of elevated surfaces
     (piles), using Equations 6 and 7.

5.   For elevated surfaces (piles), subdivide areas of constant N into sub-
     areas of constant u* (i.e., within the isopleth values of us/ur in Figure
     11.2.7-2 and Table 11.2.7-3) and determine the size of each subarea.

6.   Treating each subarea (of constant N and u*) as a separate source,
     calculate the erosion potential (Pj) for each period between disturbances
     using Equation 3 and the emission factor using Equation 2.
11.2.7-8
EMISSION FACTORS
9/88

-------
     Multiply the resulting emission factor for each subarea by the size of
     the subarea, and add the emission contributions of all subareas.  Note
     that the highest 24-hr emissions would be expected to occur on the
     windiest day of the year.  Maximum emissions are calculated assuming a
   i  single event with the highest fastest mile value for the annual period.

The recommended emission factor equation presented above a.ssumes that all of
the erosion potential corresponding to the fastest mile of wind is lost during
the period between disturbances.  Because the fastest mile event typically
lasts only about 2 min, which corresponds roughly to the halflife for the
decay of actual erosion potential, it could be argued that the emission factor
overestimates particulate emissions.  However, there are other aspects of the
wind erosion process which offset this apparent conservatism:
   i                   '                 -              ..     | .'.•".
1.   The fastest mile event contains peak winds which substantially exceed the
   i  mean value for the event.                                          '

2.   Whenever the fastest mile event occurs, there are usually a number of
     periods of slightly lower mean wind speed which contalin peak gusts of the
     same order as the fastest mile wind speed.
                                                          i
   i                   '
Of(greater concern is the likelihood of overprediction of wind erosion
emissions in the case of surfaces disturbed infrequently in comparison to the
rate of crust formation.
                                                          i
11.2.7.4  Example calculation for wind erosion emissions from conically shaped
          coal pile

A coal burning facility maintains a conically shaped surge pile 11 m in height
and 29.2 m in base diameter, containing about 2000 Mg of coal, with a bulk
density of 800 kg/m3 (50 lb/ft3).  The total exposed surface area of the pile
is(calculated as follows:                                 !

          S =  r  r2 + h2

            =3.14(14.6)  (14.6)2 + (ll.O)2

   ':         = 838 m2

Coal is added to the pile by means of a fixed stacker and reclaimed by front-
end loaders operating at the base of the pile on the downwind side.  In addi-
tion, every 3 days 250 Mg (12.5% of the stored capacity of coal) is added back
to the pile by a topping off operation, thereby restoring the full capacity of
the pile.  It is assumed that (a) the reclaiming operation disturbs only a
limited portion of the surface area where the daily activity is occurring,
such that the remainder of the pile surface remains intact, and (b) the top-
ping off operation creates a fresh surface on the entire pile while restoring
its original shape in the area depleted by daily reclaiming activity.

Because of the high frequency of disturbance of the pile, a large number of
calculations must be made to determine each contribution to the total annual
wind erosion emissions.  This illustration will use a single month as an
example.                                                  j
                                                          .i
   i
9/88                         Miscellaneous Sources                     11.2.7-9

-------
Prevailing
Wind
Di recti on
  * A portion of Cg is disturbed daily by reclaiming activities,
area
ID
A
B
Ci + C2
us
Ur
0.9
0.6
0.2
% ..."
12
48
40
Area (m2)
101
402
335
                                       Circled values
                                       refer to us/ur
                                                  838
Figure 11.2.7-3.  Example 1:   Pile surface  areas within each wind speed regime.
11.2.7-10
EMISSION FACTORS
9/88

-------
Step 1:  In the absence of field data for estimating the threshold friction
velocity, a value of 1.12 m/s is obtained from Table 11.2.7-2.

Step 2:  Except for a small area near the base of the pile (see
Figure 11.2.7-3), the entire pile surface is disturbed every 3 days, corre-
sponding to a value of N = 120/yr.  It will be shown that the contribution of
the area where daily activity occurs is negligible so that it does not need to
be treated separately in the calculations.

Step 3;  The calculation procedure involves determination of the fastest mile
fo|r each period of disturbance.  Figure 11.2.7-4 shows a representative set of
values (for a 1 month period) that are assumed to be applicable to the geographic
area of the pile location.  The values have been separated into 3 day periods,
and the highest value in each period is indicated.  In this example, the
anemometer height is 7 m, so that a height correction to 10 m is needed for the
fastest mile values.  From Equation 5,
                        u+10
      In (10/0.005)
  u+7 In (7.0.005)
                        u+io = 1.05 u+7                  I

St|ep 4:  The next step is to convert the fastest mile value for each 3 day
period into the equivalent friction velocities for each surface wind regime
(i. e., us/ur ratio) of the pile, using Equations 6 and 7.  Figure 11.2.7-3
shows the surface wind speed pattern (expressed as a fraction of the approach
wind speed at a height of 10 m).  The surface areas lying within each wind
speed regime are tabulated below.the figure.
      ,                           '
  i                                                       i
The calculated friction velocities are presented in Table 11.2.7-4.  As
indicated, only three of the periods contain a friction velocity which exceeds
the threshold value of 1.12 m/s for an uncrusted coal pile.  These three values
all occur within the Ug/Uj- = 0.9 regime of the pile surface.

Step 5:  This step is not necessary because there is only one frequency of
disturbance used in the calculations.  It is clear that the small area of
daily disturbance (which lies entirely within the Ug/ur = 0.2 regime) is never
subject to wind speeds exceeding the threshold value.
9/88
Miscellaneous Sources
11.2.7-11

-------
                 Local  Climatological  Data
                          MONTHLY SUMMARY
HIND
es
o
*-
X
<
_<
=1
in
UJ
or
13
30
01
10
13
12
20
29
29
22
1 4
29
17
21
10
10
01
33
27
32
24
22
32
29
07
3*
31
30
30
33
34
29
st
•- o.
5*
*-
_l O
r> uj
in uj
uj a.
cr en
H
5.3
10.5
2.4
! 1 .0
1 1 .3
1 1 . 1
19.6
10.9
3.0
14.6
22.3
7.9
7.7
4.5
6.7
13.7
1 1 .2
4.3
9.3
7.5
10.3
17.1
2.4
5.9
11.3
12. 1
8.3
8.2
5.0
3.1
4.9
o
uj
UJ
a.
tn
3 X
ez CL
5 =
15
6.9
10.6
6.0
M.4
1 1 .9
19.0
19.8
1 1 .2
B. 1
15. 1
23.3
13.5
15.5
9.6
8.8
13.8
1 1 .5
5.8
10.2
7.8
10.6
17.3
8.5
8.8
11.7
12.2
8.5
8.3
6.6
5.2
5.5
FASTEST
MILE
o "~
UJQ.
UJ
0. IT
in
16
to
16
17
15
23
18
1 J
1?
16
15
O
16
16
w
9
8
o
»—
c_>
UJ
cr
o
17
36
01
02
13
1 I
30
30
30
13
12
29
17
18
13
1 1
35
3-S
31
35
24
20
32
13
02
32
32
25
32
32
31
25
FOR THE MONTH:
30
—
3.3
	
M.I
	
3 1 29
DATE: 1 1




"
UJ
H-
^
0
22
i
2
3
A
5
6 .
7
8
9
10
1 I
12
13
I 4
15
16
17
18
"19
20
21
22
23
24
25
26
27
25
29
30
ji

    Figure 11.2.7-4.  Daily fastest miles of wind for periods of interest.
11.2.7-12
                           EMISSION FACTORS
9/88

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         TABLE 11.2.7-4.   EXAMPLE 1:   CALCULATION OF FRICTION VELOCITIES

3 Day
period
i ,
[ 1
i 2
j 3
4
: 5
i 6
i 7
i 8
i 9
HO
U+7 u"*"10
(mph)
14
29
30
31
22
21
16
25
17
13
(m/s) (mph)
6.3
13.0
13.4
13.9
9.8
9.4
7.2
11.2
7.6
5.8
15
31
32
33
23
22
17
26
18
14
(m/s) Ug/ur
6.6
13.7
14.1
14.6
10.3
9.9
7.6
11.8
8.0
6.1
1
! u* -
i
0.2
0.13
i 0.27
! 0.28
! 0.29
0.21
i 0.20
0.15
0.24
0.16
0.12
0.1 u+s
0.6
0.40
0.82
0.84
0.88
0.62
0.59
0.46
0.71
0.48
0.37
(m/s)
0.9
0.59
1.23
1.27
1.31
0.93
0.89
0.68
1.06
0.72
0.55
 Steps  6 and  7:  The final set of calculations  (shown in Table 11.2.7-5)
 involves  the tabulation and  summation of emissions for each disturbance period
 and for the  affected subarea.  The erosion potential (P) is calculated from
 Equation  3.
         TABLE  11.2.7-5.  EXAMPLE 1:  CALCULATION OF PM10 EMISSIONS3
3 Day
Pile Surface
Area kPA
period u* (m/s) u* - u*fc (m/s) P (g/m2) ID
f
2 1.23 0.11 3.45
j3 1.27 0.15 5.06
4 1.31 0.19 6.84

• A
A
A
Total PM]
(m2)
101
101
101
0 emissions
(g)
170
260
350
= 780
For example, the calculation for the second 3 day period is:

  j        ?2 = 58(1.23 - 1.12)2 + 25(1.23 - 1.12)

  :           - 0.70 + 2.75 = 3.45 g/m2
  i                                   '             •       i
The PMio emissions generated by each event are found as the product of the
PMio multiplier (k = 0.5), the erosion potential (P), and the affected area
of' the pile (A).
9/08
Miscellaneous Sources
11.2.7-13

-------
As shown in Table 11.2.7-5, the results of these calculations indicate a
monthly PM^o emission total of 780 g.
11.2.7.5  Example calculation for wind erosion from flat area covered with coal
          dust

A flat circular area of 29.2 m in diameter is covered with coal dust left over
from the total reclaiming of a conical coal pile described in the example
above.  The total exposed surface area is calculated as follows:


             S = _ d2 = 0.785 (29. 2)2 = 670 m2
                 4

This area will remain exposed for a period of 1 month when a new pile will be
formed.

Step 1:  In the absence of field data for estimating the threshold friction
velocity, a value of 0.54 m/s is obtained from Table 11.2.7-2.

Step 2:  The entire surface area is exposed for a period of 1 month after
removal of a pile and N = 1/yr.

Step 3:  From Figure 11.2.7-5, the highest value of fastest mile for the
30 day period (31 mph) occurs on the llth day of the period.   In this example,
the reference anemometer height is 7 m, so that a height correction is needed
for the fastest mile value.  From Step 3 of the previous example, U+IQ = 1.05
u-fy, so that u+io = 33 mph.
Step 4:  Equation 4 is used to convert the fastest mile value of 33 mph
(14.6 m/s) to an equivalent friction velocity of 0.77 m/s.  This value exceeds
the threshold friction velocity from Step 1 so that erosion does occur.

Step 5:  This step is not necessary because there is only one frequency of
disturbance for the entire source area.
Steps 6 and 7:  The PM^o emissions generated by the erosion event are
calculated as the product of the PM^o multiplier (k = 0.5), the erosion
potential (P) and the source area (A).  The erosion potential is calculated
from Equation 3 as follows:

               P = 58(0.77 - 0.54)2 + 25(0.77 - 0.54)
                 - 3.07 + 5.75
                 = 8.82 g/m2

Thus the PM^Q emissions for the 1 month period are found to be:

               E = (0.5)(8.82 g/m2)(670 m2)
                 = 3.0 kg
11.2.7-14                       EMISSION FACTORS                           9/88

-------
References  for  Section 11.2.7

1!.   C.  Cowherd  Jr. ,  "A New Approach to  Estimating Wind Generated Emissions
     from  Coal Storage  Piles",  Presented at  the APCA Specialty Conference on
     Fugitive Dust  Issues  in the  Coal Use Cycle,  Pittsburgh,  PA,  April 1983.
2i.  K. Axtell and C.  Cowherd,  Jr. ,  Improved  Emission Factors  for Fugitive Dust
 I   from  Surface Coal Mining  Sources,  EA-600/7-84-048,  U,ST.Environmental
    Protection Agency,  Cincinnati,  OH, March 1984.

31.  G. E. Muleski, "Coal Yard  Wind  Erosion Measurement", j Midwest Research
    Institute, Kansas City, MO, March  1985.

4|.  Update of Fugitive  Dust Emissions  Factors  in AP-42  Section 11.2  -  Wind
 |   Erosion, MRl No.  8985-K, Midwest Research  Institute,;Kansas City,  MO,  1988.
 i                                                        I
5;.  W. S. Chepil, "Improved Rotary  Sieve  for Measuring  State  and Stability
 I   of Dry Soil Structure", Soil  Science  Society of  America Proceedings,
    JL6_:113-117, 1952.
 (                                                        [-
6.  D. A. Gillette, et  al., "Threshold Velocities for Input of Soil
    Particles Into the  Air By  Desert Soils", Journal of Geophysical  Research,
    85(C10):5621-5630.                                :i	

7.  Local Climatological Data, National Climatic Center, Asheville,  NC.

8'.  M. J. Changery, National Wind Data Index Final Report, HCO/T1041-01 UC-60,
    National Climatic Center,  Asheville,  NC, December 197~8.
 i                                                        i
9.  B. J. B. Stunder  and S. P. S. Arya, "Windbreak Effectiveness for Storage
 j   Pile Fugitive Dust  Control:  A Wind Tunnel Study",  Journal of  the  Air
 !   Pollution Control Association,  38:135-143, 1988.
9/88
Miscellaneous Sources
                                                                      11.2.7-15

-------

-------
  t
                                   APPENDIX C.3

                             SILT ANALYSIS PROCEDURES
      Select, the appropriate 8 inch diameter 2 inch deep sieve sizes.
      Recommended standard series sizes are 3/8 inch No. 4, No. 20, No. 40,
      No.  100,  No.  140,  No.  200,  and a pan.   .The No. 20 and the No. 200 are
      mandatory.  Comparable Tyler Series sizes can also be used.  "
  2.   Obtain a  mechanical  sieving device such as  a vibratory shaker or a
  :    Roto-Tap  (without the tapping function).
  3.   Clean the sieyes with compressed air and/or,a soft brush.   Material lodged
  !    in  the  sieve  openings or  adhering to the  sides of  the sieve should be
      removed without  handling  the screen roughly,  if possible.
                                                          I
  4.   Obtain  a  scale with  capacity of  at least  1600 grams, and record its make,
      capacity, smallest increment, date of last calibration,  and accuracy.

  5.   Record  the tare  weight of  sieves and pan,  and check the  zero before every
  I   .weighing.
     After  nesting  the  sieves  in decreasing order of hole size,  and with the
     pan at the bottom,  dump dried  laboratory  sample into the  top  sieve,
     preferably immediately after moisture  analysis.  The sample should weigh
     between 800 and  1600 grams  (1.8 and  3.5 pounds).   Brush fine  material
     adhering  to the  sides of  the container into  the top sieve,  and cover the
     top sieve with a special  lid normally  purchased with the  pan.

 7j.  Place  nested sieves into  the mechanical device, and sieve for 10 minutes.
     Remove pan containing minus  No. 200  and weigh its  contents.   Repeat  the
     sieving in 10 minute intervals until the  difference between two successive
  I   pan sample weights  is less than 3.0  percent  when the tare of  the pan has
     been substracted.   Do not sieve longer than  40  minutes.

 8j.  Weigh each sieve and its  contents, and record the  weight.   Remember  to
  '   check  the zero before every  weighing.
                                                          I
 9»  Collect the laboratory sample, and place  it  in  a separate container  if
  j   further analysis is expected.
  i                                                        i          •        •
10;.  Calculate the percent of  mass  less than the  200 mesh screen (75 micro-
     meters).  This is the silt content.
  U. S. QOVEEHMEHT EKrHOKG OFFICE 1988/526-090/87005
9/88                              Appendix C.3                            C.3-1

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  1. REPORT NO.
   AF  42, Supplement  B
                                     TECHNICAL REPORT DATA
                              (Please read Instructions on the reverse before completing)
 4. TITLE AND SUBTITLE
                              2.
   Supplement B to Compilation of Air Pollutant Emissi6n
     Factors, AP-42,  Fourth Edition
                                                             B. REPORT DATE
                                                               September 1988
                                                             6. PERFORMING ORGANIZATION CODE
 7. AUTHOR(S)
                                                              8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
 U.iS.  Environmental Protection Agency
 Office  of Air And 'Radiation
 Office  Of Air Quality Planning And Standards
 Research Triangle Park, NC 27711
 12. SPONSORING AGENCY NAME AND ADDRESS
 15. SUPPLEMENTARY NOTES


  EPA Editor;   Whitmel M. Joyner
 16. ABSTRACT  ~          ~	
                                                             3. RECIPIENT'S ACCESSION NO.
                                                              10. PROGRAM ELEMENT NO.


                                                              Tl. CONTRACT/GRANT NO.
                                                              1,3. TYPE OF REPORT AND PERIOD COVERED
                                                              14. SPONSORING AGENCY CODE
    ;   In  this Supplement to  the Fourth Edition of AP-42, new  or  revised emissions  data
  are presented for Bituminous  And Subbituminous Coal Combustion;  Anthracite Coal
  Combustion;  Residential Wood  Stoves; Waste  Oil Combustion; Refuse Combustion; Sewage
  Sludge Incineration; Surface  Coating; Polyester Resin Plastics  Product Fabrication;
  Soap And Detergents; Grain  Elevators And Processing Plants;  Lime Manufacturing; Crushed
  Stpne Processing; Western Surface Coal Mining;  Wildfires And Prescribed Burning;
  Unpaved Roads;  Aggregate Handling And Storage Piles; Industrial  Paved Roads; Industrial
  Wind Erosion;  and Appendix  C.3,  "Silt Analysis  Procedures".
17.
                                 KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
  Stationary Sources
  Point Sources
  Area Sources
  Emission Factors
  Emissions
18. DISTRIBUTION STATEMENT
EPA F,orm 2220-1 (Rev. 4-77)   PREVIOUS EDITION is OBSOLETE
                                               XIDENTIFIERS/OPEN ENDED TERMS
                                               19. SECURITY CLASS {ThisReport)
                                               20. SECURITY CLASS (Thispage)
                                                                           c. COSATI Field/Group
                                                                         21. NO. OF PAGES

                                                                              182
                                                                          22. PRICE

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