Wednesday
April 15, 1998
Part II



Environmental

Protection  Agency

40 CFR Parts 63, 261, and 430 National
Emissions Standards for Hazardous Air
Pollutants for Source Category: Pulp and
Paper Production; Effluent Limitations
Guidelines, Pretreatment Standards, and
New Source Performance Standards:
Pulp, Paper, and Paperboard Category;
Final Rule
                              1850

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                     Federal Register/Vol, 63, No.  72-/Wednesday. April  15,  19987Notices
                                                                     18399
Historic Preservation Officer (SHPO), as
required by § 106, National Historic
Preservation Act, and the regulations of
the Advisory Council on Historic
Preservation, 36 CFR 800.4.
  1.-Under Section 4.32(b)(7) of the
Commission's regulations (18 CFR
4.32(b)(7)), if any resource agency,
SHPO, Indian Tribe, or person believes
that the applicant should conduct an
additional scientific study to form an
adequate,  factual basis for a complete
analysis of this application on its merits,
they must file a request for the study.
with the Commission, together with
justification for such request, not later
than 60 days after application is filed,
and must serve a copy of the request on
the applicant.
Linwood A. Watson, Jr.,
Acting Secretary.
[FRDoc. 98-9894 Filed 4-15-98; 8:45 am]
BILLING CODE 6717-01-M
ENVIRONMENTAL PROTECTION
AGENCY

[FRL-5978-3]

Agency Information Collection
Activities: Proposed Collection;
Comment Request; Best Management
Practices for the Bleached Papergrade
Kraft and Soda Subcategory and the
Papergrade Sulfite Subcategory of the
Pulp, Paper, and Paperboard Point  •
Source Category

AGENCY: Environmental Protection
Agency (EPA).         !
ACTION: Notice.

SUMMARY: In compliance with the
Paperwork Reduction Act (44  U.S.C-
3501 et seq.), this notice announces that
EPA is planning to submit the following
proposed and/or continuing Information
Collection Request {ICR) to the Office of
Management andjBudget  (OMB):
Information Collection Request for Best.
Management Practices, Effluent
Limitations Guidelines and Standards,
Pulp, Paper, and Paperboard
Manufacturing Category (40 CFR Part
430). Before submitting the ICR.to OMB
for review and approval, EPA  is
soliciting comment on specific aspects
of the proposed information collection
as described below.               !
DATES: Comments must be submitted on
or before June  15, 1998.
ADDRESSES: Send comments on this
notice in triplicate to Mr.  Troy
Swackhammer, Office of Water,
Engineering and Analysis Division
(4303), U.S. Environmental Protection
Agency, 401 M Street, SW., Washington,
DC 20460. In addition to submitting
 hard copies of the comments, the public
 may also send comments via e-mail to:
 swackhammer.j-troy@epamail.epa.gov.
 Copies of the draft information
 collection request are available at http:/
 /www.epa.gov/OST/pulppaper/.
 FOR FURTHER INFORMATION CONTACT: Mr.
 Troy Swackhammer by voice on (202)
 260-712, by facsimile on 202-260-7185,
 or by e-mail at Swackhammer j-
 troy@epamail.epa.gov.
 SUPPLEMENTARY INFORMATION:

 Regulated entitles
  Entities potentially affected by this
 action are those operations that
 chemically pulp wood fiber using kraft
 or soda methods to produce bleached
 papergrade pulp, paperboard, coarse
•paper, tissue paper, fine  paper, and/or
 paperboard; and those operations that
 chemically pulp wood fiber using
 papergrade sulfite methods to produce
 pulp and/or paper.
  Tide: Best Management Practices for
 the Bleached Papergrade Kraft and Soda
 Subcategory and the Papergrade Sulfite
 Subcategory of the Pulp,  Paper, and
 Paperboard Point Source Category (EPA
 ICRNo. 1829.01).
  Abstract: The Environmental
 Protection Agency (EPA) has established
 Best Management Practice provisions as
 part of final amendments to 40 CFR Part
 430, the Pulp, Paper and Paperboard
 Point Source Category published
 elsewhere in today's Federal Register.
 See 40 CFR Part 430.03. These
 provisions, promulgated  under the
 authorities of Sections 304, 307, 308,
 402, and 501 of the Clean Water Act,
 require that owners or operators of
 bleached papergrade kraft, soda and
 sulfite mills implement site-specific
 BMPs to prevent or otherwise contain
 leaks and spills of spent pulping
 liquors, soap and turpentine and to
 control intentional diversions of these  ;
 materials.
  EPA has determined that these BMPs
 are necessary because the materials
 controlled by these practices, if spilled
 or otherwise lost, can interfere with
 wastewater treatment operations and
 lead to increased discharges of toxic,
 noncpnventional, and conventional
 pollutants. For further discussion of the
 need for BMPs, see Section VT.B.7 of the
 preamble to the amendments to 40 CFR
 Part 430 published elsewhere in today's
 Federal Register.
  The BMP program includes
 information collection requirements that
 are intended to help accomplish the
 overall purposes of the program by, for
 example, training personnel, see 40 CFR
 430.03(c)(4), analyzing spills that occur,
 see 40 CFR 430.03(c)(5),  identifying   :
equipment items that might need to be
upgraded or repaired, see 40 CFR
430.03(c)(2), and performing
monitoring—including the operation of
monitoring systems—to detect leaks,
spills and intentional diversion and
generally to evaluate the effectiveness of
the BMPs, see 40 CFR 430.03 (c) (3),
(c)(10), (h), and (i). The regulations also
require mills to develop and, when
appropriate, amend plans specifying
how the mills will implement the
specified BMPs, and to certify to the
permitting or pretreatment authority
that they have done so in accordance
with good engineering practices and the
requirements of the regulation. See 40
CFR 430.03 (d),  (e) and (f). The purpose
of those provisions is, respectively, to
facilitate the implementation of BMPs
on a site-specific basis and to help the
regulating authorities to ensure
compliance without requiring the
submission of actual BMP plans.
Finally, the recordkeeping provisions
are intended to  facilitate training, to
signal the need  for different or more
vigorously implemented BMPs, and to
facilitate compliance assessment. See 40
CFR430.03(g).
  EPA has structured the regulation to
provide maximum flexibility to the
regulated community and to minimize
administrative burdens on National
Pollutant Discharge Elimination System
(NPDES) permit and pretreatment
control authorities that regulate
bleached papergrade kraft and soda and
papergrade sulfite mills. Although EPA
does not anticipate that mills will be
required to submit any confidential
business information or trade secrets as
part of this ICR, all data claimed as
confidential business information will
be handled by EPA pursuant to 40 CFR
Part 2.
 . An agency may not conduct or
sponsor, and a person is not required to
respond to, a collection of information
unless it displays a currently valid OMB'
control number. The OMB control
numbers for EPA's regulations are listed
in 40 CFR Part 9 and 48 CFR Chapter
15.
Solicitation of Comments
  EPA solicits comments that would
help the Agency to better:
  (i) evaluate whether the proposed
collection of information is necessary
for the proper performance of the
functions of the Agency,  including
whether the information will have
practical utility;
  (ii) 'evaluate the accuracy of the
Agency's estimate of the .burden of the
proposed collection of information,
including the validity of the
methodology and assumptions used;

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 18400
Federal Register/Vol. 63. No.  72/Wednesday,  April 15, 1998/Notices
   (iii) enhance the quality, utility, and
 clarity of the information to be
 collected; and
   (iv) minimize the burden of the
 collection of information on those who
 are to respond, including through the
 use of appropriate automated electronic,
 mechanical, or other technological
 collection techniques or other forms of
 information technology (e.g.. permitting
 electronic submission of responses).
 Burden Statement

   The following discussion describes
 the information collection requirements
 of the BMP  regulations and estimates
 the burden associated with each one.
   Burden means the total time; effort, or
 financial resources expended by persons
 to generate,  maintain, retain, or disclose
 or provide information to or for a
 Federal agency. This includes time
 needed to: review instructions; develop,
 acquire, install, and utilize technology
 and systems for the purposes of
 collecting, validating, and verifying
 information, processing and
 maintaining information and disclosing
 and providing information; adjust the
 existing ways to comply with previously
 applicable instructions and
 requirements; train personnel to be able
 to respond to the collection of
 information: search data sources;
 complete and review the collection of
 information and transmit or otherwise
 disclose the information.
  The BMP  regulations at 40 CFR
 430.03 include the following major
 components: (1) Development, review
 and certification of a BMP plan, which
 should include programs to identify and
 repair leaking equipment, to track
 equipment repairs, to train personnel, to
 report and evaluate spills, to review
 planned mill modifications, and to
 establish wastewater treatment system
 influent action levels (including an
 initial six-month monitoring program)
 in addition to a detailed engineering
 review of the pulping and chemical
 recovery areas; (2) amendment and
 periodic review of the BMP plan; (3)
 reporting of  spills;  (4) additional
 monitoring and reporting; and (5)
 additional recordkeeping. See 40 CFR
 430.03 (c) through (h) and the
 "Technical Support Document for Best
 Management Practices for Spent Pulping
 Liquor Management, Spill Prevention,
 and Control," October 1997, DCN
 14489, EPA-821-R-97-015 (also
 referred to below as the BMP TSD) for
 more detailed information on the
 requirements. The BMP requirements
apply to approximately 95 papergrade
kraft. soda, and sulfite mills.
                  a. Development, Review and
                  Certification of a BMP Plan
 which is included in the annual
 estimates presented in Table 2.
                    Development of a site-specific BMP
                  plan is a one-time initial burden. Plan
                  preparation costs will vary based upon
                  mill complexity. EPA anticipates that
                  mills will use outside consultants under
                  direction of mill personnel to prepare
                  the site-specific BMP plan, including
                  the detailed engineering review. Costs
                  for preparing the BMP Plan, which
                  range from $150,000 to $250,000, are
                  included in the compliance cost
                  estimates developed for the regulation
                  •(see Table 9.2 of the BMP TSD, DCN
                  14489). EPA anticipates mill labor
                  burden of 40. 60, arid 80 hours (at $30
                  per hour) for direction and oversight of
                  the consultant effort for simple,
                  moderately complex, and complex
                  mills, respectively. Review of the initial
                  plan by the senior technical manager
                  and certification by the mill manager is
                  expected to take less than one day of
                  effort (at $40 per hour). These one-time
                  burden estimates associated with the
                  BMP plan are summarized in Table 1  of
                  this notice.
                    As part of the BMP plan development,
                  mills must establish a training program
                  for technical personnel. This training
                  program must include both an initial
                  training effort and an annual refresher
                  training. The burden for initial training
                  is included in the compliance costs
                  referenced above (see Table 9.2 of the
                  BMP TSD, DCN 14489). Burden for
                  annual refresher training is included in
                  the annual estimates presented in Table
                  2 of this notice.

                  b. Amendment and Periodic Review of
                  a BMP Plan

                    Owners or operators must amend
                  their BMP Plans whenever there is a
                  change in mill design, construction,
                  operation or maintenance that
                  materially affects the potential for leaks
                  or spills of spent pulping liquor, soap or
                  turpentine from the  immediate process
                  areas. See 40 CFR 430.03(e)(l). In
                  addition, owners or  operators must
                  complete a review and evaluation of
                  their BMP plans at least once every five
                  years, and amend the plan within three
                  months if warranted. See 40 CFR
                  430.03(e)(2). Any BMP plan
                  amendments also require review by the
                  senior technical manager and
                  certification by the mill manager. See 40
                  CFR430.03(f).
                   EPA anticipates less than 50 hours of
                  mill labor per amendment, and based
                  the ICR burden on an assumption that
                  each mill would need to amend its BMP
                 • plan twice every five years, for an
                  annual burden of 20 hours ($620),
 c. Reporting of Spills

   Reports of spills of spent pulping
 liquor, soap or turpentine not contained
 in the immediate process area must list
 the equipment involved, the
 circumstances leading to. the incident,
 the effectiveness of corrective actions
 taken and plans to implement future
 changes. These reports must be
 maintained by the owner or operator,
 and they need only be submitted to the
• NPDES permit or pretreatment control
 authority upon request.  EPA anticipates
 that the burden of preparing a spill
 report is approximately four hours and •
 can be conducted by a mill engineer at
 $30 per hour.  ICR burden is calculated
 on an annual basis using an assumption
 of 1 spill per mill per month and is
 included in the annual estimates
 presented in Table 2.

 d. Additional Monitoring arid Reporting

  Mills are required to operate
 continuous, automatic monitoring
 systems that the mill determine are
 necessary to detect and control leaks,
 spills, and intentional diversions of
 spent pulping liquor, soap, and
 turpentine. See 40 CFR430.03(c)(3). The
 burden for designing, testing, and  -
 operating the monitoring system,
 expressed in the form of costs, is
 included in the compliance cost
 estimates developed for  the regulation
 (see Table 9.2  of the BMP TSD, DCN
 14489).
  In addition,  all mills with the
exception of new sources are required to
perform two six-month monitoring
programs in order to determine the
characteristics (or action levels) of their
wastewater treatment system effluent.
See 40 CFR 430.03(h). (New sources are
required to perform only one six-month
monitoring program for this purpose.
See 40 CFR 430.03 (h) (5).) All mills are
also required to perform additional
monitoring to revise those  action levels
after any change  in mill  design,
construction, operation,  or maintenance
that materially affects the potential for
leaks  or spills or spent pulping liquor,
soap,  or turpentine from the immediate
process area. See 40 CFR 430.03 (h) (6).
The effort required to implement the
initial monitoring program and perform
the associated  statistical analysis to
establish the action levels is included in
the compliance cost estimates
developed for the regulation, and the
burden to perform monitoring to revise
those  action levels is  included in the
incremental monitoring burden
discussed below.

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                     Federal  Register /Vol. 63, No.  72 / Wednesday;  April 15, 1998/Notices
                                                                     18401
   The regulation also requires all mills
 to conduct daily monitoring of
 wastewater treatment system influent
 for the purpose of detecting leaks and
 spills, tracking the effectiveness of the
 BMPs, and detecting trends in spent
 pulping liquor losses. See 40 CFR
 430.03 (i). EPA estimates the burden
 associated with this monitoring to be
 increnient of 1 additional hour per day
 (at $20/hour) as included in annual
 estimates shown in Table 2 of this
 notice. Costs for monitoring equipment
 were included in the compliance cost
 estimates  developed for the regulation
 (see Table 9.2 of the BMP TSD, DCN
 14489).           ,        •
   Mill operators are required to provide
•their NPDES permit or pretreatment
 control authorities reports of the
 monitoring required by the BMP
 regulation. The reports must include a
. summary of the monitoring results, the :
 number and dates of exceedances of the
 applicable action levels, and brief
 descriptions of any corrective actions
 taken to respond to such exceedances.,
 Submission of such reports shall be at
 the frequency established by the NPDES
 permit or pretreatment control
 authority,! but in no case less than once
 per year. EPA has based, the burden
 estimates on a semi-annual reporting
 frequency and estimates that each-report
 will take 16 hours to complete,
 including both engineer and senior
 technical manager effort (also included
 in Table 2 estimates).
 e. Recordkeeping Requirements
  The regulation requires that certain
 equipment repair records, records of
 employee training, reports of spills
 outside the immediate process area, and
 records of monitoring conducted as part
 Of the BMP program be maintained for
'three years. See 40 CFR 430.03(g). EPA
 expects that the level of effort will
 depend upon mill complexity. Burden
 estimates for recordkeeping are based on
 an incremental level of effort to comply
 with BMP requirements consisting of 2
 to 4 hours per month for the operators/
 shift supervisors over current shift log
 recordkeeping (at $20 per hour), 2 to 4
 hours per months for engineering
 technicians (at $30 per hour), and two
 hours per month for clerical support (at
.$15 per hour). These burden estimates
 are also included in the annual
 estimates presented in Table 2 below.

 f. Total Industry Burden Estimates

  Based on the assumptions listed
 above, EPA estimates the following one-
 time burden associated with mill labor
 for the BMP requirements:
                   TABLE 1.—BURDEN ESTIMATES FOR PREPARING AND CERTIFYING THE BMP PLAN
                                                  [One-time burden]
Process (complexity)
Kraft (simple) 	 	 	 	 	 	 	 	
. Kraft (moderately complex) 	 	 	 .....; 	 	 	 	 	
Kraft (complex) 	 	 	 	 	 	 •. 	 	 	
Sulfite (simple)

, Total 	 	 	 	 	 	 	 " ;. . .

Number of
mills
41
30
13
11

95

Hours (in-
dustry-wide)
1 969
2 040
1,144
528

5680

Dollars ($)
(industry-
wide)
62,320
63600
35,360
16720

178000

  Note: BMP plan development costs that are
contracted out are considered compliance
costs and are not included here; they are
presented in Table 9-2 of the BMP .TSD, DCN
14489.
  Based on the assumptions listed
above, EPA estimates the following
recurring burden associated with mill
labor for the BMP requirements:
        TABLE 2.—BURDEN ESTIMATE.FOR MAINTAINING BMP PLAN, SPILL RECORDS, PERSONNEL TRAINING, ETC,
                                                  [Recurring burden]
Process (complexity) .
Kraft (simple) " 	 	 	 .' 	 : 	
Kraft (moderately complex) . .. 	 	 	 	 •.. .
Kraft (complex) 	 	 	 	 	 	 	 	 	 	 	
Sulfite (simple) 	 ; 	 	 	 	 	 	 	 	 	

Total 	 '.. 	 	 	 	 : 	 	 	 	 	

Number of
mills
41
30
13
11

95

Annual
hours (in-
dustry-wide)
. 22017
1 6 830
7,605
5,907

52,359

Annual dol-
lars ($) (in-
dustry-wide)
487,080
374 400
170,040
130,680

1,162,200

g. Government Burden Estimates

   EPA estimates the initial burden to
state NPDES permitting authorities and
state and local pretreatment control
authorities willbe 950 hours based on
ten hours per facility for the preparation
of new NPDES permit or pretreatment
control mechanism conditions
implementing the BMP regulation. EPA
estimates the recurring incremental  .
burden to these state and local
authorities will be 950 hours per year
based on ten hours per year per facility
for administrative work associated with
reviewing periodic (e.g., annual or semi-
annual) reports of monitoring and
conducting compliance reviews. State
and local labor costs are estimated at
$19,000 per year, based on labor rates of
$20 per hour. EPA estimates that its
incremental labor burden will be 100
hours annually for the BMP regulation
and will incur costs of $3,000 per year,
based on labor rates of $30 per hour.

  Dated: April 3, 1998.
Tudor T. Davies,;
Director, Office of Science and Technology.
[FR Doc. 98-9556 Filed 4-14-98: 8:45 am]
BILLING CODE 6560-50-P

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 18504      Federal Register/Vol. 63, No.  72/Wednesday, April 15, 1998/Rules  and Regulations
 ENVIRONMENTAL PROTECTION
 AGENCY

 40 CFR Parts 63,261, and 430
 [FRL-5924-8]
 RIN 2040-AB53

 National Emission Standards for
 Hazardous Air Pollutants for Source
 Category: Pulp and Paper Production;
 Effluent Limitations Guidelines,
 Pretreatment Standards, and New
 Source Performance Standards: Pulp,
 Paper, and Paperboard Category

 AGENCY: Environmental Protection
 Agency (EPA).
 ACTION: Final rules.

 SUMMARY: This action promulgates
 effluent limitations guidelines and
 standards under the Clean Water Act
 (CWA) for a portion of the pulp, paper,
 and paperfaoard industry, and national
 emission standards for hazardous air
 pollutants (NESHAP) under the Clean
 Air Act (CAA) as amended in 1990 for
 the pulp and paper production source
 category.
  EPA is also promulgating best
 management practices under the CWA
 for a portion of the pulp, paper, and
 paperboard industry, and new analytical
 methods for 12 chlorinated phenolic
 pollutants and for adsorbable organic
 halides (AOX). This action consolidates
 into 12 subcategories what had once
 been 26 subcategories of effluent
 limitations guidelines and standards for
 the pulp, paper, and paperboard
 industry, and revises the existing
 effluent limitations guidelines and
 standards for the Bleached Papergrade
 Kraft and Soda subcategory and the
 Papergrade Sulflte subcategory. The
 revised effluent limitations guidelines
 and standards require existing and new
 facilities within these two subcategories
 to limit the discharge of pollutants into
 navigable waters of the United States
 and to limit the  introduction  of
 pollutants into publicly owned
 treatment works. The NESHAP requires
 existing and new major sources within
 the pulp and paper production source
 category to control emissions using the
 maximum achievable control
 technology (MACT) to control
 hazardous air pollutants (HAP).
  EPA is revising the effluent
limitations guidelines and standards for
 the Bleached Papergrade Kraft and Soda
subcategory  and the Papergrade Sulfite
subcategory  primarily to reduce the
 discharge of toxic and nonconventional
chemical compounds found in the
effluents from these mills. Discharge of
these pollutants into the freshwater,
estuarine, and marine ecosystems may
alter aquatic habitats, affect aquatic life,
and adversely impact human health.
Discharges of chlorinated organic
compounds from chlorine bleaching,
particularly dioxins and furans, are
human carcinogens and human system
toxicants and are extremely toxic to
aquatic life. The final effluent
limitations guidelines and standards for
the Bleached Papergrade Kraft and Soda
and Papergrade Sulfite subcategory are
estimated to reduce the discharge of
adsorbable organic halides (AOX) by
28,210 kkg/year; chloroform by 45 kkg/
year; chlorinated phenolics by 47 kkg/
year; and 2,3,7,8-TCDD (dioxin) and
2,3,7,8-TCDF (furan) by 125 gm/year.
These reductions will permit all 19
dioxin/furan-related fish consumption
advisories downstream of pulp and
paper mills to be lifted.
  EPA is revising the subcategorization
scheme for the effluent limitations
guidelines and standards because the
new scheme better defines the processes
typically found  in U.S. mills and thus
results in what ultimately will be a
streamlined regulation that can be
implemented more easily by the permit
writer. With the exception of the new
effluent limitations guidelines and
standards for the Bleached Papergrade
Kraft and Soda and Papergrade Sulfite
subcategories, EPA is making no
substantive changes to the limitations
and standards applicable to the newly
reorganized subcategories. Those
portions of the existing pulp, paper, and
paperboard effluent limitations
guidelines and standards that are not
substantively amended by this action
are not subject to judicial review; nor is
their effective date affected by this
reorganization.
  The HAPs emitted by facilities
covered by the NESHAP include such
compounds as methanol, chlorinated
compounds, formaldehyde, benzene,
and xylene. The health effects of ,
exposure to these and other HAPs at
pulp and paper  mills can include
cancer, respiratory irritation, and
damage to the nervous system. The final
NESHAP is expected to reduce baseline
emissions of HAP by 65 percent or
139,000 Mg/yr.
  The pollutant reductions resulting •'
from these rules will Achieve the
primary goals of both the CAA and
CWA, which are to "enhance the quality
of the Nation's air resources so as to
promote the public health and welfare
and productive  capacity of its
population" and to "restore and
maintain the chemical, physical, and  •
biological integrity of the Nation's
waters," respectively. These rules will
result in continued environmental
 improvement at reasonable cost by
 providing flexibility in when and how
 results are achieved and, for certain
 mills, by providing incentives to surpass
 baseline requirements.
   Elsewhere in.today's. Federal Register,
 EPA is concurrently proposing NESHAP
 to control hazardous air pollutants from
 chemical recovery combustion sources
 at kraft, soda, sulfite, and stand-alone
 semi-chemical pulp mills.  '
   In another proposed rule published in
 today's Federal Register, EPA is also
 proposing a regulation that would
 require mills enrolled  in the Voluntary
 Advanced Technology Incentives
 Program being promulgated for the
 Bleached Papergrade Kraft and Soda
 subcategory to submit a plan specifying
 research, construction, and other
 activities leading to achievement of the
 Voluntary Advanced Technology
 effluent limitations, with accompanying
 dates for achieving these milestones.
 Second, EPA proposes to authorize
 Bleached Papergrade Kraft and Soda
 subcategory mills under certain.
 circumstances to submit a certification
 based on process changes in lieu of
 monitoring for chloroform. Third,
 although not proposing totally chlorine-
~free (TCF) technologies for new source
 performance standards under the CWA
 for Bleached Papergrade Kraft and Soda .
 subcategory at this time, EPA is
 requesting comments and data regarding
 the feasibility of TCF processes for this
 subcategory, especially the range of
 products made and their specifications.
 In that proposal EPA is also requesting
 comments and data regarding the
 effluent reduction performance of TCF
 processes for this subcategory.
 DATES: In accordance with the Small
 Business Regulatory Enforcement
 Fairness Act of 1996, the regulations
 shall become effective June 15, 1998.
 For compliance dates,  see the,
 SUPPLEMENTARY INFORMATION section
 under the heading "Compliance Dates."
 ADDRESSES: Air Pocicets. The Air
 Dockets are available for public
 inspection between 8 a.m. and 4 p.m.,
 Monday through Friday except for
 Federal holidays, at the following
 address: U.S. Environmental Protection
 Agency, Air and Radiation Docket and
 Information Center (MC-6102), 401 M
 Street SW, Washington, DC 20460,
 Room M-1500, Waterside Mall;
 telephone: (202) 260-7548.
   Water Docket. The complete public
 record for the effluent  limitations
 guidelines and standards rulemaking is
 available for review, Monday through
 Friday except for federal holidays, at
 EPA's Water Docket, Room M2616, 401

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              Federal Register/Vol. 63. No.  72/Wednesday. April  15,  1998/Rules and Regulations       18505
 M Street SW, Washington, DC 20460.
 For access to Docket materials, call (202)
 260-3027. The Docket staff requests that
 interested parties calLbetween 9:00 am
 and 3:30 pm for an'appointment before
 visiting the docket.'               -
   For additional information about the
 dockets, see section  X.A below.
   Background and support documents
 containing technical, cost, economic,
 and health information, as well as EPA's
 response to public comments, are
 available for public use. A listing and
 how to obtain these  background
 documents is provided in section XI in
 this notice.                        ^
 FOR FURTHER INFORMATION CONTACT: For
 questions regarding  air emissions
 standards for chemical wood pulping
 mills, contact Ms. Penny Lassiter,
 Emissions Standards Division (MD-13),
 U.S. Environmental  Protection Agency,
 Research Triangle Park, NC 27711,
 telephone number'(919) 541-5396; or
 Mr. Stephen Shedd,  at the same address,
 telephone number (919) 541-5397. For
 information concerning the final air
 standards for mechanical pulping
 processes, secondary fiber pulping
 processes, and nonwood fiber pulping .
 processes, contact Ms. Elaine Manning,
 at the same Research Triangle Park
 address, telephone number (919) 541-
 5499. For questions on compliance;
 enforcement arid applicability
 determinations, contact Ms. Maria
 Eisemann, Office of Enforcement and
 Compliance Assurance (2223A), U.S.
 Environmental Protection Agency, 401
 M St., S.W., Washington, D.C. 20460, .
 telephone number (202) 564-7106.
  For questions regarding wastewater
 standards, contact Mr. Donald Anderson
 at the following address: Engineering   '
 and Analysis Division (4303), EPA, 401
 M Street, S.W., Washington, D.C. 20460,
 telephone number (202) 260-7189; or
 Ms. Wendy D. Smith at the same
 address, telephone number (202) 260-
 7184.
  For additional information on the
 economic impact analyses, contact Dr.
 William Wheeler, Office of Water,
 Engineering and Analysis Division
 (4303); U.S. Environmental Protection
 Agency, 401 M Street, SW, Washington,
 DC, 20460, (202) 260-7905.
 SUPPLEMENTARY INFORMATION:
 Overview

   The preamble summarizes the legal
 authority for these rules, background
 information, the technical and economic
 methodologies used by the Agency to
 develop these rules, the impacts of the
 rules, regulatory implementation, and
 the availability of supporting
 documents.

 Regulated Entities

   Entities regulated by today's action
 are those  operations that chemically
 pulp and  nonchemically pulp wood and
 nonwood fibers for pulp and paper
 production. EPA projects that
 approximately 490 mills are subject to
 the air regulations promulgated today.
 Of these mills, 155 will be affected by
 MACT standards for mills  that   -
 chemically pulp wood. Within that
 group, 96 are subject to the effluent
 limitations guidelines and standards
 promulgated today. Regulated categories
 and entities include:
Category
Industry '...'. 	

Rule
NESHAP w
Effluent Guidelines 	 	 	

, Examples of regulated entities
Pulp mills and integrated mills (mills that manufacture pulp and paper/paperboard) that
chemically pulp wood fiber (using kraft, sulfite, soda, or semi-chemical methods); pulp
secondary fiber; pulp nonwood fiber; and mechanically pulp wood fiber.
Subset of mills subject to the NESHAP that chemically pulp wood fiber using kraft, sulfite,
or soda methods to produce bleached papergrade pulp and/or bleached paper/paper-
board. , '
   The foregoing table is not intended to
 be exhaustive, but rather provides a
 guide for readers regarding entities
 likely to be regulated by the NESHAP
 and effluent limitations guidelines and
 standards promulgated today. This table
 lists the types of entities that EPA is
 now aware could potentially be
 regulated by this action. Other types of
 entities not listed in the table could .also
 be regulated. To determine whether
 your facility or company is regulated by
 this NESHAP, you should carefully
, examine the applicability criteria in
 § 63.440 of the air rule and the
 applicability criteria in part 63, Subpart
 A of Title 40 of the Code of Federal
 Regulations. To determine whether your
 facility is regulated by the effluent
 limitations guidelines and standards,
 you should carefully examine the
 applicability criteria in § 430.20 and
 § 430.50 of Tide 40 of the Code of  ,
 Federal Regulations.
   If you have questions regarding the
 applicability of the NESHAP or the
 effluent limitations guidelines and
 standards, see the section entitled FOR
 FURTHER INFORMATION CONTACT.
Judicial Review '

  In accordance with 40 CFR § 23.2, the
water portion of today's rule shall be
considered promulgated for the
purposes of judicial review at 1. pm
Eastern time on April 29, 1998. Under
section 509 (b) (1) of the Clean Water Act
(CWA), judicial review of today's
effluent limitations guidelines and
standards is available in the United
States Court of Appeals by filing a
petition for review within 120 days from
the date of promulgation of those
guidelines and standards. Under section
307(b)(l) of the CAA, judicial review of
the NESHAP is available only by   -
petition for review in the U.S. Court of
Appeals for the District of Columbia
Circuit within 60 days of today's
publication of this NESHAP. Under
section 509 (b) (2) of the CWA and
section 307 (b) (2) of the CAA, the
requirements in this regulation may not
be challenged later in civil or criminal
proceedings brought by EPA to enforce
these requirements.
Compliance Dates
  Existing direct dischargers must
comply with limitations based on the
best available technology economically,
achievable (BAT) as soon as such
requirements are imposed in their
.National Pollutant Discharge
Elimination System (NPDES) permits.
The water regulation also establishes
specific deadlines for compliance with
best management practices (BMPs),
which apply to all sources. The new
reporting and recordkeeping
requirements promulgated today are not
effective until the Office of Management
and Budget approves Information
Collection Requests for those
requirements.
  Except as provided in today's BMP
regulation, existing indirect dischargers
subject to today's water regulations
must comply with the pretreatment
standards for existing sources being
-promulgated today by April 16, 2001. In
addition, these dischargers must
continue to comply with the
pretreatment standards for existing
sources for pentachlorophenol and
trichlorophenol.

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18506
Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules and Regulations
  Except as provided in today's BMP
regulation, new direct and indirect
discharging sources must comply with
applicable treatment standards on the
date the new source begins operation.
For purposes of new source
performance standards (NSPS), a source
is a new source if it meets the definition
of "new source" in 40 CFR 430.01 (j) and
if it commences construction after June
15,1998. For purposes of pretreatment
standards for new sources (PSNS), a
source is a new source if it meets the
definition of "new source" in 40 CFR
430.01 (j) and if it commenced
construction after December 17,1993.
  The following compliance dates apply
to the Voluntary Advanced Technology
Incentives Program being codified today
as part of the water regulations for
Subpart B. Each existing direct
discharging mill that enrolls in the
Voluntary Advanced Technology
Incentives Program must comply
immediately with limitations based on
the mill's existing effluent quality or its
current technology-based permit limits
for the baseline BAT parameters,
whichever are more stringent.
Participating mills must also comply
with mill-specific interim milestones by
the dates specified in their NPDES
permits. They must also achieve the
baseline BAT effluent limitations for
dloxin, furan, chloroform, 12 specified
chlorinated organic pollutants and, for
mills enrolled at the Tier II or Tier HI
level, AOX no later than April 15, 2004.
Finally, participating mills must achieve
BAT limitations corresponding to the
most stringent phase of the Voluntary
Advanced Technology Incentives
Program by the dates specified below:
  Voluntary BAT limitations for Tier I
must be achieved by April 15, 2004.
  Voluntary BAT limitations for Tier H
must be achieved by April 15, 2009.
  Voluntary BAT limitations for Tier m
must be achieved by April 15, 2014.
  For new direct discharging mills in
Subpart B, EPA is promulgating
Voluntary NSPS at the Tier H and Tier
in levels. Participating new sources
must achieve NSPS at the selected level
upon commencing operation.
  Compliance dates for the NESHAP are
as follows: Existing sources must
comply with the NESHAP no later than
April 16, 2001 except for the following
cases. Equipment in the high volume
low concentration  (HVLC) system at
existing sources at kraft mills (e.g., pulp
washer systems, oxygen deligniflcation
systems) must comply no later than
April 17, 2006. Bleach plants at existing
source kraft and soda mills participating
in the effluent limitations guidelines
Voluntary Advanced Technology
Incentives Program must comply with
                          the first stage of the NESHAP no later
                          June 15,1998 and with the second stage.
                          no later than April 15, 2004. '
                             Once today's rules take effect on June
                          15, 1998, new sources must comply
                          with applicable MACT requirements
                          upon start-up. For a discussion of the
                          .circumstances under which a source
                          becomes a new source for compliance
                          with new source air emissions
                          standards, see Sections n.B.2.b. and
                          VI.A.1.   '  ,  '

                          Technology Transfer Network

                             The Technology Transfer Network
                          CTTN) is one of EPA's electronic bulletin
                          boards. The TTN provides information
                          and technology exchange in various
                          areas of air pollution control. New air
                          regulations are now being posted on the
                          TTN through the world wide web at
                          "http://www.epa.gov/ttn." For more
                          information on  the TTN, call the HELP
                          line at (919) 591-5384.
                             Information on the water regulations
                          may be accessed through the world
                          wide web at http://www.epa.gov/OST/
                          Rules/#final.

                          Organization of This Document

                          I. Legal Authority
                          n. Scope of This Rulemaking
                            A. EPA's Long-Term Environmental Goals
                            B. National Emission Standards for
                              Hazardous Air Pollutants (NESHAP)
                            C. Effluent Limitations Guidelines and
                              Standards                 •
                          IK. Background
                            A. Prior Regulations, Proposal, Notices'of
                              Data Availability, and Public
                              Participation
                            B. Clean Air Act Statutory Authority
                            C. Clean Water Act Statutory Authority
                            D. Other EPA Activities Concerning the
                              Pulp and Paper Industry
                          IV. Changes in the Industry Since Proposal
                          V. Summary of Data Gathering Activities
                              Since Proposal
                            A. Data Gathering for the Development of
                              Air Emissions Standards
                            B. Data Gathering for the Development of .
                              Effluent Limitations Guidelines and
                              Standards
                          VI. Summaiy of the Major Changes Since
                              Proposal and Rationale for the Selection
                              of the Final Regulations
                            A.-Air Emission Standards
                            B. Effluent Limitations Guidelines and
                              Standards
                          VIE. Environmental Impacts
                            A. Summary of Sources and Level of
                              Control
                            B. Air Emissions and Water Effluent
                              Reductions
                            C. Non-Water Quality Environmental
                              Impacts of Effluent Limitations
                              Guidelines and Standards (BAT, PSES,
                              and BMPs)
                            D. Non-Water Quality Environmental
                              Impacts of New Source Performance
    Standards and Pretreatment Standards
    for New Source (NSPS and PSNS)
VH[. Analysis of Costs, Economic Impacts,
    and Benefits
  A. Summary of Costs and Economic
    Impacts
  B. Overview of Economic Analysis
  C. Costs and Economic Impacts for Air
    Emissions Standards
  D. Costs and Economic Impacts for Effluent
    Limitations Guidelines and Standards
  E. Costs and Impacts for the Integrated
    Rule
  F. Costs and Impacts of Rejected BAT/
    PSES Options for the Bleached
    Papergrade Kraft and Soda Subcategoiy
  G. Benefits
  H. Comparison of Costs and Benefits
  I. Costs and Benefits of Rejected Options
    for the Bleached Papergrade Kraft and
    Soda Subcategoiy—Option B and TCP
  J. Benefit-Cost Comparison Using Case
    Studies
IX. Incentives for Further Environmental
    Improvements
  A. The Voluntary Advances Technology
    Incentives Program
  B. Incentives Available After Achievement
    of Advanced Technology BAT
    Limitations and NSPS
X. Administrative Requirements and Related
    Government Acts or Initiatives
  A. Dockets
  B. Executive Order 12866 and OMB
    Review
  C. Regulatory Flexibility Act and the Small
    Business Regulatory Enforcement
    Fairness Act of 1996 (SBREFA)
  D. Paperwork Reduction Act
  E. Unfunded Mandates Reform Act
•  F. Pollution Prevention Act
  G. Common Sense Initiative
  H. Executive Order 12875
  I. Executive Order 12898
  J. Submission to Congress and the General
    Accounting Office
  K. National Technology Transfer and
    Advancement Act
XI. Background Documents

I. Legal Authority
  These regulations are being
promulgated under the authority of
sections 301', 304, 306, 307, 308, 402,
and 501 of the Clean Water Act, 33
U.S.C. sections 1311, 1314, 1316, 1317,
1318, 1342, and 1361, and sections 112,
114, and 301 of the Clean Air Act, 42
U.S.C. sections 7412, 7414, and 7601.

n. Scope of This Rulemaking
  Today's Cluster Rules consist of
effluent limitations guidelines and
standards for the control of wastewater
pollutants and national emission
standards for hazardous air pollutants.
The final rules issued today are based
on extensive information gathered by
the Agency and on comments received
from interested parties during the
development of these regulations.
  Section VI of this notice discusses the
major changes since proposal and the
rationale for the regulatory decisions

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              Federal Register/Vol.  63,  No. 72/Wednesday, April 15, 1998/Rules  and Regulations      18507
 underlying the rules promulgated today.
 This summary, section highlights the
 technology bases and other key aspects
 of the final rules. More detailed
 descriptions are included in the
 supporting documents listed in section
 XI.
 ,  In addition, the Agency is today
• codifying the subcategorization scheme
 that was proposed for 40 CFR parts 430
 and 431, see 58 FR 66078, 66098-100
 pec. 17, 1993) and is redesignating the
 section and subpart numbers in 40 CFR
 part 430. accordingly.

 A. EPA's Long-Term Environmental
 Goals
   EPA has integrated the development
 of the regulations discussed today to
 provide greater protection of human
 health and the environment, reduce the
 cost of complying with the wastewater
 regulations and air emissions controls,
 promote and facilitate coordinated ,
 compliance planning by industry,
 promote and facilitate pollution
 prevention, and emphasize the
 multimedia nature of pollution control.
   The Agency envisions a long-term
 approach to environmental
 improvement that is consistent with
 sound capital expenditures. This
 approach, which is presented in today's
 notice, stems from extensive discussions
 with.a range of stakeholders. The
 .effluent limitations guidelines and
 standards and air emissions standards
 are only one component of the
 framework to achieve long-term
 environmental goals. The overall
 regulatory framework also includes .
 incentives to reward and encourage
 mills that implement pollution
 prevention beyond regulatory
 requirements. The Agency will continue
 to encourage mill-specific solutions to
 remaining environmental problems
 through water quality-based
 requirements in permits and
 enforcement of those requirements. In
 addition, continuing research on
 minimum impact technologies, such as
 closed-loop and totally chlorine-free
 bleaching processes, will help to
 identify economical ways of furthering
 environmental improvement in this
 industry.     ,
   EPA's long;term goals include
 improved air quality, improved water
 quality, the eliminatiori offish
 consumption advisories downstream of
 mills, and the elimination of
 ecologically significant
 bioaccumulation. An integral part of
 these goals is an industry committed to
 continuous environmental
 improvement—an industry that
 aggressively pursues research and pilot
 projects to identify technologies that
 will reduce, and ultimately eliminate,
 pollutant discharges from existing and
 new sources. A holistic approach to
 implementing these pollution
 prevention technologies would
 contribute tti the long-term goal of
 minimizing impacts of mills in all
 environmental media by moving mills
 toward closed-loop process operations.
 Effective implementation of these
, technologies is capable of increasing
 reuse of recoverable materials and
 energy while concurrently reducing
 consumption of raw materials (e.g.,
 process water, unrecoverable chemicals,
 etc.), arid reducing air emissions and
 generation of hazardous and non-
 hazardous wastes. EPA expects that this
 combination of regulation, research,
 pilot projects, and incentives will foster
 continuous environmental improvement
 with each mill investment cycle. For
 this reason, EPA is including an
 incentives program as part of the
 effluent limitations guidelines and
 standards being promulgated today for
 bleached papergrade kraft and soda
 mills that accept enforceable permit
 limits requiring effluent reductions well
 beyond the rule's regulatory baseline
 (see Section TX). To ensure that today's
 air emission standards do not present
 barriers or disincentives to mills in
 choosing technologies beyond baseline
 BAT, EPA is providing additional time
 to comply with MACT beyond the three-
 year compliance time for certain process
 units. See Sections VI.A.S.b and VI.A.7
 for details on MACT compliance times.
 B. National Emission Standards for
 Hazardous Air Pollutants (NESHAP)
 1. Purpose of the NESHAP
  The main purposes of the Clean Air
 Act (CAA) are to protect and enhance
 the quality of our Nation's air resources,
 and to promote, the public health and
 welfare and the productive capacity of
 the population. See CAA, section
 101(b)(l). To this end, section 112(d) of
 the CAA directs EPA to set standards for,
 stationary sources emitting greater than
 ten tons of any one HAP or 25 tons of
 total HAPs annually (one ton is equal to
 0.908 megagrams). EPA is promulgating
 this NESHAP because pulp and paper
 mills are major sources of HAP
 emissions. Individual mills are capable
 of emitting as much as several hundred
 tons per year (tpy) of HAPs. The HAPs  .
 emitted may adversely affect air quality
 and public health. The HAPs controlled
 by this rule are associated with a variety
 of adverse health effects including
 cancer; a number of other toxic health
 effects such as headaches, nausea, and
 respiratory distress; and possible
 reproductive effects.
   a. Hazardous Air Pollutants. Table II-
 1 lists the 14 HAPs emitted in the
 largest quantities from pulp and paper
 mills. A few HAPs emitted from pulp
 and paper mills have been classified as
 possible, probable, or known human
 carcinogens. These include
 acetaldehyde, benzene, carbon
 tetrachloride, chloroform,      <-  -•
 formaldehyde, and methylene chloride.
 The total reduction in national HAP
 emissions by compliance with the
 NESHAP is estimated to be 139,000
 megagrams per year (Mg/yr).

 TABLE 11-1.—HIGHEST EMITTED HAZ-
   ARDOUS  AIR   POLLUTANTS   FROM
   PULP AND PAPER  MILLS

        Hazardous Air Pollutants
 Acrolein	
 Acetaldehyde	,:,
 o-Cresol	
 Carbon tetrachloride .
 Chloroform	
 Cumene	
 Formaldehyde
Methanol.
Methylene chloride.
Methyl ethyl ketone.
Phenol.
Prppionaldehyde.
1,2,4-
  Trichlorobenzene.
o-Xylene.
  b. Volatile Organic Compounds.
Emissions of volatile organic
comp'ounds (VOC) have been associated
with a variety of health and welfare
impacts. Volatile organic compound
emissions, together with nitrogen oxides
(NOx), are precursors to the formation of
tropospheric ozone. Exposure to ozone
is responsible for a series of health
impacts, such as alterations in lung
capacity; eye, nose, and throat irritation;
malaise and nausea; and aggravation of
existing respiratory disease. Among the
welfare impacts from exposure to ozone
include damage to selected commercial
timber species and economic losses for
commercially valuable crops, such as
soybeans and cotton. The total
reduction in national VOC emissions by
compliance with the NESHAP is
estimated to be 409,000 Mg/yr.
  c. Total Reduced Sulfur Compounds.
Total reduced sulfur (TRS) Compound
emissions are responsible for the
malodors often associated with pulp
and paper production. The total
reduction in TRS compound emissions
estimated as a result of compliance with
this NESHAP is 79,000 Mg/yr, Surveys .
of odor pollution caused by pulp mills
have supported a link between odor and
health symptoms such as headaches,
watery eyes, .nasal problems, and
breathing difficulties.
2. Summary of the NESHAP.
  The MACT standards apply to pulp
and paper mills that have the potential
to emit ten tons per year of any one HAP

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18508      Federal Register/Vol. 63, No. 72/Wednesday, April  15,  1998/Rules and  Regulations
or 25 tons per year of all HAPs (one ton
Is equal to 0.908 megagrams). Potential
to emit is based on the total of all HAP
emissions from all activities at the mill.
  The NESHAP specifies emission
standards for pulping processes and
bleaching processes. The emission
standards for pulping and bleaching
processes provide several options for
compliance, including an alternative
pollution prevention option (the "clean
condensate alternative") for the kraft
pulping process. The standards specify
compliance dates for new and existing
sources, require control devices to be
properly operated and maintained at all
times, and clarify the applicability of
the NESHAP General Provisions (40
CFR part 63, subpart A) to sources
subject to this rule.
  The rule subcategorizes the industry
to specify different emission standards
based on the type  of pulping process
(kraft, sulfite, semi-chemical, soda,
mechanical wood pulping, secondary
fiber pulping, or non-wood pulping) and
bleaching process (papergrade or
dissolving grade).  Mills that chemically
pulp wood using kraft, semi-chemical,
sulfite, or soda processes are referred to
in later sections as MACTI mills. Mills
that mechanically pulp wood, or that
pulp secondary fiber or non-wood
fibers, or that produce paper or
paperboard from purchased pulp are
referred to in later sections as MACT m
mills.
  The emission control requirements for
new and existing sources within each
subcategory are the same, except that
more emission points are covered for
sources subject to the new source
provisions. Where two or more
subcategories are located at the same
mill site and share a piece of equipment,
that piece of equipment would be
considered a part  of the subcategory
with the more stringent MACT
requirements for that piece of
equipment. For example, the foul
condensates from an evaporation set
processing both kraft weak black liquor
and spent liquor from a semi-chemical
process would have to comply with the
kraft subcategory requirements for foul
condensate. This more stringent
requirement is appropriate because
there is no way to isolate the emissions
for each pulping source to determine
compliance separately.
  These standards do not address
emissions from recovery area
combustion sources (referred to in later
sections as MACT It). These sources are
being regulated under a separate
NESHAP, which is proposed elsewhere
in today's Federal Register. A summary
of the specific provisions that apply to
each of the subcategories is given in the
later parts of this section.
  a. Definition of Affected Source. At
chemical wood pulping mills, the
affected source is all emission points in
the pulping and bleaching systems. At
mills that mechanically pulp wood,
secondary fibers, or non-wood
materials, the affected source is all
emission points in the bleaching system.
For kraft mills complying with the clean
condensate alternative, the affected
source is the pulping system, bleaching
system, causticizing system, and
papermaking system.
  b. New Source MACT. New source
MACT applies to: (1) An affected source
that commenced construction or
reconstruction after initial proposal; (2)
pulping or bleaching systems that are
reconstructed after initial proposal; and
(3) new pulping systems, pulping lines,
bleaching systems, and bleaching lines
that are added to existing sources after
initial proposal. The initial proposal
date for mills that chemically pulp
wood is December 17,1993. The initial
proposal date for mills that
mechanically pulp wood, pulp
secondary fibers, or pulp non-wood
materials is March 8,1996.
  Descriptions of equipment in each
subcategory subject to new source
MACT requirements are presented in
later sections of this preamble.
  c.  Compliance Times. The rule
requires existing sources to comply with
the NESHAP no later than April 16.
2001, except for the following cases.
Existing kraft sources are required to
control all the equipment in the HVLC
collection system no later than April 17,
2006. Dissolving-grade mills are
required to comply with bleaching
system standards no later than three
years after publication of the wastewater
effluent limitations guidelines and
standards under 40 CFR part 430,
subparts A and D.
  In addition, the NESHAP sets out a
two-phased standard for existing source
papergrade kraft and soda bleach mills
that elect, under the Voluntary
Advanced Technology Incentives
Program, to control wastewater
discharges to levels surpassing today's
BAT baseline. The first phase for
existing source MACT requires no
increase in the existing HAP emission
levels from the papergrade bleaching
system—i.e., no backsliding—during the
initial period when the mill is working
toward meeting its Voluntary Advanced
Technology BAT requirements. EPA has
determined that immediate compliance
with this requirement is practicable
because the requirement reflects, for
each mill, the performance level it is
presently achieving. Therefore, the
effective date of the first phase
requirements is June 15,1998. The
second phase of existing source MACT
requires the mill either to comply with
BAT for all pollutant parameters at the
baseline level for the Bleached
Papergrade Kraft and Soda subcategory,
or to certify that chlorine and
hypochlorite are not used in the bleach
plant, in order to achieve the MACT
standard for chloroform emission
reduction; it also requires the mill to
apply controls for other chlorinated
HAPs. All such mills that enroll in the
Voluntary Advanced Technology
Incentives Program must comply with
the second phase of existing source
MACT no later than April 15, 2004.
  Once today's rules take effect on June
15, 1998, new sources must comply
with applicable MACT requirements
upon start-up.
  d. Kraft Pulping Standards. For
existing sources, the kraft pulping
standards promulgated today apply to
the following equipment systems: The
low volume high concentration (LVHC)
system, the pulp washing system, the
.oxygen delignification system, decker
systems that do not use fresh water or
Whitewater from papermaking systems
or that use process water with HAP
concentrations greater than or equal to
400 parts per million by weight (ppmw),
and knotter systems and screening
systems that have total system
emissions greater than or equal to 0.05
and 0.10 kilograms of HAP per
megagram of oven-dried pulp (ODP)
produced, respectively (or have total
[i.e., knotter and screening] system
emissions greater them or equal to 0.15
kilograms of HAP per megagram of ODP
produced combined). For new sources,
the kraft pulping standards apply to the
equipment systems listed above for
existing sources, plus  weak liquor
storage tanks, all knotter systems, all
screening systems,, and all decker
systems.
   Sources subject to the kraft pulping
standards must enclose open process
equipment and route all emissions
through a closed-vent system to a
control device. The closed-vent system
must be designed and operated with no
detectable  leaks. The rule provides three
control device options, as follows: (1)
Reduce the HAP content by 98 percent
by weight (or, for thermal oxidizers, to
a level of 20 parts per million volume
 [ppmv] of total HAP, corrected to 10
percent oxygen on a dry basis); (2)
reduce HAPs by using a properly
 operated design thermal oxidizer
 (operated at a minimum temperature of
 1,600  °F and a minimum residence time
 of 0.75 seconds); or (3) reduce HAPs by
 using a boiler, lime kiln, or recovery

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              Federal Register/Vol. 63, No. 72/Wednesday, April 15,  1998/Rules and Regulations      18509
  furnace that introduces all emission
  streams to be controlled with the
  primary fuel or into the flame zone.
    The kraft condensate standards apply
,  to condensate streams generated in the
  following kraft pulping processes:
  Digester system, evaporator system,
  turpentine recovery system, LVHC
,  collection system, and the high volume-
  low concentration (HVLC) collection
  system. The HAP mass loading in the
  condensates from these systems must be
  reduced by 92 percent, based.upon
  performance of steam stripping. The
  NESHAP also includes the following
  four alternative ways to meet the kraft
  condensate standard: (1) Recycle
  applicable condensate, streams to  .
  process equipment that is controlled in
  accordance with the kraft pulping
  standards; (2) reduce the concentration
  of HAP (measured as methanol) in the
  condensate to 330 ppmw for kraft mills
  with bleaching systems, or 210 ppmw
  for kraft mills without bleaching
  systems; (3) remove at least 5.1
  kilograms of HAP (measured as
  methanol) per megagram of ODP
  produced for kraft mills with bleaching
  systems, or remove at least 3.3 kilogram
  of HAP per megagram of ODP produced
  for kraft mills without bleaching
  systems; or (4) discharge pulping
  process condensates to a biological
  treatment system achieving at least 92
  percent destruction of total HAP.
   The pulping process condensates
  must be conveyed to the treatment
  system in a closed collection system
  that is designed and operated to meet
_ the individual drain system
"requirements specified in §§63.960,
  63.961, 63.962, and 63.964 of subpart
  RR. These essentially require that the
  means of conveyance be leak-free. Air
  emissions of HAP from vents on any
  condensate treatment systems (except
  biological treatment systems) that are
  used to comply with the standards must
  be routed to a control device meeting
  the kraft pulping standards.
   All Jhe pulping process condensates
  from the LVHC and HVLC collection
  systems must be treated. However, the
 facility has the option of minimizing the
  condensate volume sent to treatment
 from the digester system, turpentine
 recovery system, and weak liquor feed
 stages in the evaporator system (i.e.,
 condensate segregation). If sufficient
 segregation is not aphieved, then the
 entire volume of condensate from the
 digester system, turpentine recovery
 system, and weak liquor feed stages in
 the evaporator system and the LVHC
 and HVLC collection systems must be
 treated.
   Two options are provided in the rule
 for determining if sufficient segregation  •
 has been achieved. The first option is to
 isolate at least 65 percent of the total
 HAP mass in the total of all condensates
 from the digester system, turpentine
 recovery system, and weak liquor feed
 stages in the evaporator system.
   The second option requires that a   '.'•
 minimum total HAP mass from the high
 HAP-concentrated condensates from the
 digester system, turpentine recovery •
 system, and weak liquor feed stages in
 the evaporator system and the LVHC
 and HVLC collection system
 condensates be sent to treatment.
   e. Clean Condensate Alternative
 Standards for Kraft Pulping. The final
 rule provides an alternative compliance
 option to the kraft pulping standards for
 subject equipment in the HVLC systems.
 This alternative compliance option is
 referred to as the clean condensate
 alternative (CCA). The CCA focuses on
 reducing the HAP concentration in
 process water (such as from the
 digestion and liquor evaporation areas)
 .that is introduced into process
 equipment throughout the mill. By
 reducing the amount of HAP in the
 process water, reductions in HAP
 emissions will also be achieved since
 less HAP will be available to volatilize
 off the process to the atmosphere. To
 demonstrate compliance, the mass
 emission reduction of HAPs achieved by
 the alternative technology must equal or
 exceed that which would have been
 achieved by implementing the kraft
 pulping vent controls.
  Eligibility for this compliance
 alternative is determined on a case-by-
 case basis during the permitting process.
  For purposes  of developing a
 compliance strategy, sources may use
 either emission test data or engineering
 assessment to determine the baseline
 HAP emission reductions that would be
 achieved by complying with the kraft
 pulping vent standard. To demonstrate
 that the alternative technology complies
 with the emission reduction
 requirements of the standards, emission
 test data must be used. Two conditions
 must be met for a CCA compliance
 demonstration:  (1) Owners  and
 operators that choose this alternative
 must first comply with pulping process
 condensate standards before
 implementing the alternative
technology; and (2) the HAP emission
reductions cannot include reductions
associated with any control equipment
required by local, state, or Federal
agencies' regulations or statutes or with
emission reductions attributed to
equipment installed prior to December
 17, 1993 (i.e., the date of publication of.
the proposed rule).
  For purposes of the CCA, the rule
provides an alternative definition of the
 affected source. The alternative
 'definition allows for the CCA to apply
 to process systems outside of the kraft
 pulping system. The expanded source
 includes the causticizing system and the
 papennaking system. The mill must   -
 specify the process equipment within
 the expanded source with which to
 generate the required HAP emissions
 reductions using the CCA. The mass
 emission reduction of HAPs must equal
 or exceed the reduction that would have
 been achieved through application of
 the kraft pulping vent standards. The
 final determination of equivalency shall
 be made by the permitting authority
 based on an evaluation of the HAP
 emission reductions.
   f. Sulfite Pulping Standards. For
 existing sources, the sulfite pulping
 standards apply to the digester system
 vents, evaporator system vents, and the
 pulp washing system. The sulfite
 pulping standards also apply to air
 emissions from the effluent from any
 equipment used to reduce HAP
 emissions to comply with the standards
 (e.g., acid plant scrubber and nuisance
 scrubber). Fpr new sources, the sulfite,
 pulping standards apply to the
 equipment systems listed for existing
 sources, plus Weak liquor tanks, strong
 liquor storage tanks, and acid
 condensate storage tanks.
   Sources subject to the sulfite pulping
 standards for equipment systems must
 enclose open process equipment and
 route all HAP emissions through a
 closed-vent system to a control device.
 The closed-vent system must be
 designed and operated with no
 detectable leaks. The total HAP
 emissions from the equipment systems
 and from the effluent from any control
 device used to reduce HAP emissions
 must meet a mass emission limit or a
 percent reduction requirement.
 Calcium- and sodium-based sulfite
 pulping mills must meet an emission
 limit of 0.44 kilograms of methanol per
 megagram of ODP or achieve a 92
 percent methanol reduction.
 Ammonium-and magnesium-based
 sulfite pulping mills must meet an
 emission limit of 1.1 kilograms of
 methanol per megagram of ODP limit or
 achieve an 87 percent methanol
 removal.      ,
 ' g. Semi-Chemical Pulping Standards.
 For existing sources, the semi-chemical
pulping standards apply to the LVHC
vent system. For new sources, semi-
 chemical pulping standards apply to the
LVHC system and the pulp washing
system.                   /
  Sources subject to the semi-chemical
pulping standards must enclose open
process equipment and route all
emissions through a closed-vent system

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18510
Federal Register/Vol. 63, No. 72/Wednesday, April 15,  1998/Rules and Regulations
to a control device. Positive-pressure
portions of the closed-vent system must
be designed and operated with no
detectable leaks. The rule provides three
control device options, as follows: (1)
Reduce the HAP content by 98 percent
by weight (or, for thermal oxidizers, to
a level of 20 ppmv of total HAP,
corrected to 10 percent oxygen on a dry
basis); (2) reduce HAPs by using a
properly operated thermal oxidizer
(operated at a minimum temperature of
1,600 °F and a minimum residence time
of 0.75 seconds); or (3) reduce HAPs by
using a boiler, lime kiln, or recovery
furnace that introduces all emission
streams to be controlled with the
primary fuel or into the flame zone.
  h. Soda Pulping Standards. For
existing sources, the soda pulping
standards apply to the LVHC vent
system. For new sources, the soda
pulping standards apply to the LVHC
system and the pulp washing system.
  Sources subject to the soda pulping
standards must enclose open process
equipment and route all emissions
through a closed-vent system to a
control device. Positive pressure
portions of the closed-vent system must
be designed and operated with no
detectable leaks. The rule provides three
control device options, as follows: (1)
Reduce the HAP content by 98 percent
by weight (or, for thermal oxidizers, to
a level of 20 ppmv of total HAP,
corrected to 10 percent oxygen on a dry
basis); (2) reduce HAPs by using a
properly operated thermal oxidizer
(operated at a minimum temperature of
1,600 °F and a minimum residence time
of 0.75 seconds); or (3) reduce HAPs by
using a boiler, lime kiln, or recovery
furnace that introduces all emission
streams to be controlled with the
primary fuel or into the flame zone.
  I. Bleaching System Standards. The
bleaching provisions apply to bleaching
systems that use elemental chlorine to
bleach pulp. At kraft, sulfite, and soda
pulping processes, the bleaching system
provisions also apply to bleaching
systems that use chlorinated
compounds to bleach pulp. At
mechanical pulping, non-wood fiber
pulping, and secondary fiber pulping
mills, only bleaching systems that use
elemental chlorine or chlorine dioxide
to bleach pulp are subject to the
NESHAP. Bleaching systems that do not
use chlorine or chlorinated compounds
are considered to be in compliance with
the bleaching system requirements. For
the applicable systems (i.e., bleaching or
brightening in the different
subcategories), the chlorinated HAP
emissions from bleaching systems that
use elemental chlorine or chlorinated
compounds must be controlled. Existing
                          source and new source requirements are
                          the same.
                            Sources subject to the bleaching
                          system standards must enclose process
                          equipment in the bleaching stages and
                          route all emissions through a closed-
                          vent system to a control device that
                          achieves either a 99 percent reduction of
                          chlorinated HAP's (other than
                          chloroform), an outlet concentration at
                          or below 10 ppmv total chlorinated HAP
                          (other than chloroform), or a mass
                          emission limit at or below 0.001 kg of
                          total chlorinated HAP (other than
                          chloroform) per Mg ODP produced.
                          Chlorine may be used as a surrogate for
                          measuring total chlorinated HAP. The
                          closed-vent system must be designed
                          and operated with no detectable leaks.
                            With respect to chloroform emissions
                          from bleaching systems, EPA is closely
                          correlating the air and water standards.
                          This is because EPA is relying on the
                          same process change technology basis to
                          control both  chloroform emissions to air
                          and pollutant discharges to water. Thus,
                          MACT to control chloroform for
                          bleaching systems requires a mill either
                          to meet the applicable baseline effluent
                          limitations guidelines and standards for
                          all pollutants being promulgated today
                          under the Clean Water Act or to certify
                          that chlorine and hypochlorite are not
                          used in the bleaching system.
                            However, EPA at present lacks
                          sufficient information to establish new
                          effluent limitations guidelines ancf
                          standards for dissolving grade mills, and
                          also lacks information to reliably
                          ascertain what a MACT standard for
                          chloroform air emissions would be for
                          this unit operation. (It is not appropriate
                          to set MACT standards for chloroform
                          based on the control technology in use
                          today to comply with current effluent
                          limitations guidelines and standards for
                          dissolving grade mills because these
                          technologies are at the wastewater
                          treatment system, rather than in the
                          bleaching process where the
                          chloroform-emitting Vents are located.)
                          EPA intends to set new effluent
                          limitations guidelines and standards for
                          dissolving grade mills after analyses
                          currently underway by EPA are
                          complete, and is deferring establishing
                          MACT standards for chloroform until
                          these effluent limitations guidelines and
                          standards are established. Therefore,
                          dissolving grade mills will be required
                          to control chloroform air emissions
                          three years after the new effluent
                          limitations guidelines and standards are
                          promulgated.
                            In a related action, EPA is also
                          deferring establishing MACT for
                          chlorinated HAPs other than chloroform
                          from dissolving grade bleaching
                          operations until three years after
 promulgation of new effluent
 limitations guidelines and standards for
 mills performing those operations. The
 Agency is doing so in order to avoid
 imposition of CAA requirements which
 would be inconsistent with, or
 superseded by, forthcoming CWA
 regulations.
  EPA is not aware of any control
 presently in place or any available
 control technology for reducing
 chloroform air emissions at mechanical,
 secondary fiber, and non-wood pulping
 mills. Therefore, MACT for chloroform
 at these mills is no control.  Today's
 water rule does not set new effluent
 limitations guidelines and standards for
 control of chloroform at mechanical,"
 secondary fiber, and non-wood pulping
 mills, but EPA will evaluate whether it
 is appropriate to do so at a later time.
 At that time, EPA will also determine
 whether it is appropriate to revise
 MACT (pursuant to CAA section
 112(d)(6)) in order to control chloroform
 emissions at those mills.
  In addition, EPA is establishing
 MACT in two phases for bleach plant
 emissions from existing source
 papergrade kraft and soda bleaching
 plants which elect, under the Voluntary
 Advanced Technology Incentives
 Program, to control wastewater
 discharges to levels surpassing the
 baseline BAT limitations being
 promulgated today under the CWA.
 Phase one represents the present MACT
 floor for existing sources, i.e., no
 backsliding from existing controls
 during the initial period when a mill is
 working toward meeting its Voluntary
 Advanced Technology BAT
 requirements; phase two requires the
 mill either to meet baseline BAT
 requirements for all pollutants for
 bleached papergrade kraft and soda
 mills or to certify that chlorine and
 hypochlorite are not used in the
. bleaching system. EPA is establishing
 MACT in two phases in order to avoid
 discouraging plants from electing
 environmentally superior levels of
 wastewater treatment represented by the
 Voluntary Advanced Technology
 Incentives Program. These points are
 discussed in detail in section VI.A.7.
  j. Mechanical Pulping Mill, Secondary
 Fiber Pulping Mill, Non-wood Pulping
 Mill, and Papermaking System
 Standards. Mechanical pulping
 (groundwood, thermomechariical,
 pressurized) mills, secondary fiber
 pulping mills, and non-wood pulping
 mills must comply with the bleaching
 system standards described in section
 E.B.2.i. There are no control
 requirements for pulping systems or
 process condensates at these mills. For

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            -Federal Register/Vol. 63. No. 72/Wednesday, April  15,  1998/Rules and Regulations      18511
 papermaking systems, there are no
 control requirements.
   k. Test Methods. The standards
 specify test methods and procedures for
 demonstrating that process equipment
 and condensate streams are in
 compliance with the MACT standards
 or are exempt from the rule. The rule
 also includes provisions to test for no
 detectable leaks from closed-vent
 systems. Because the majority of all
 non-chlorinated HAP emissions from
 process equipment and in pulping
 process condensates is methanol, in
 most cases the owner or operator has the
 option of measuring methanol as a
 surrogate for-total HAP.  For
 demonstrating compliance using
 biological treatment or the CCA, the
 owner.or operator must measure total
 HAP. To demonstrate compliance with
 the concentration limit requirements,
, mass emission limit requirements, and
 percent reduction requirements for
 bleaching systems, chlorine may be
 measured as a surrogate for total
 chlorinated HAP emissions (other than
 chloroform).               -
 '  1. Monitoring Provisions, Sources
 subject to the NESHAP are required to"
 continuously monitor specific process
 or operating parameters for control
 devices and collection systems.       ;
 Continuous emissions monitoring is not
 required, except as an alternative to
 certain control requirements. Parameter
 values are to be established during an
 initial performance test. Alternative ,
 monitoring parameters must be
 demonstrated to the Administrator's
 satisfaction to Comply with the
 standards. As at proposal, excursions
 outside the selected parameter values
 are violations except for biological
 treatment systems. If a biological
 treatment system monitoring parameter
 is outside the established range, a       .
 performance test must be performed.
 The parameters that must be monitored,
 for vent and condensate compliance are
 explained below.
   Mills using a thermal oxidizer must
 install, calibrate, maintain, and operate
 a temperature monitoring device and
 continuous recorder to measure the
 temperature in the firebox or in the'
 ductwork immediately downstream of
 the firebox before any substantial heat
 exchange occurs. Mills using gas
 scrubbers at bleaching systems or sulfite
 processes must install, calibrate,
 maintain, and operate a device to
 monitor and continuously record (l)-pH
 or the oxidation/reduction potential of
 scrubber effluent, (2) vent gas inlet flow
 rate, and (3) scrubber liquid influent
 flow rate. As an alternative to
 monitoring these parameters, mills
 complying with the bleaching system
 outlet concentration option.must install,
 calibrate, maintain, and operate a device
 to monitor arid continuously record the
 chlorine outlet concentration. Mills
 complying with the bleaching system
 outlet mass emission limit option must
 install, calibrate, maintain, and operate
 a device to monitor and continuously
 record the chlorine outlet concentration
 and the scrubber outlet vent gas flow.
 Bleached papergrade kraft and soda
 mills enrolling in the Voluntary
 Advanced Technology Incentives •
 Program in the effluent limitations
 guidelines and standards portion of
 today's rule must monitor the
 application rates,of chlorine and
 hypochlorite to demonstrate that no
 increase in chlorine or hypochlorite use
 occurs between June 15, 1998 and April
 15,2004.
  Mills using steam strippers must
 install, calibrate, maintain, and operate
 a device to monitor and continuously
 record process water feed rate, steam
 feed rate, and process water feed
 temperature. As an alternative to
 monitoring those parameters, mills
 complying with the steam stripper
 outlet concentration option may install,
 calibrate, maintain, and operate a device
 to monitor the methanol outlet
 concentration. In addition to monitoring
 around the stream stripper, mills that
 choose to treat a smaller, more
• concentrated volume of condensate
 rather than the whole volume of subject
 condensates must also continuously
 monitor the condensates to demonstrate
 that the minimum mass or percent of
 total mass is being treated. This practice
 is often referred to as condensate
 segregation. Mills complying with the
 condensate segregation requirements
 shall install, calibrate, maintain, and
 operate monitors for appropriate
 parameters as determined during the
 initial performance test.
  Mills using a biological treatment
 system to treat pulping process
 condensates must monitor on a daily
 basis samples of outlet soluble BODs
 concentration  (maximum daily and
 monthly averages), inlet liquid flow,
 mixed liquor volatile suspended solids
 (MLVSS), liquid temperature, and the
 horsepower of aerator units.
 Additionally, inlet and outlet grab
 samples from each biological treatment
 system unit must be collected and
 stored for 5 days. These samples must
 be collected and stored since some of
 the monitoring parameters (e.g., soluble
 BODs) cannot be determined within a
 short period of time. These samples are
 to be used in conjunction with the
 WATERS emissions model to
 demonstrate compliance if the soluble
 BODs, MLVSS, or the aerator
horsepower monitoring parameters fall
outside the range established during the
initial performance test.
  Monitoring requirements for the
pulping process condensate collection
systems include initial and monthly
visual inspections of individual drain
system components and vent control
devices (if used), and repair of defects.
Additionally, inspection and monitoring
requirements from §63.964 of subpart
RR (National Emission Standards for
Individual Drain Systems) are
incorporated in the final rule.
Monitoring requirements for vent
collection systems are (1) a visual
inspection of the closed-vent system
and enclosure opening seals  initially
and every 30 days,  (2) demonstration of
no detectable leaks initially and
annually for positive pressure systems
or portions of systems, and (3) repair of
defects and leaks as soon as practical.
  For the CCA, EPA is not specifying'
the parameters to be monitored in the
final rule since the types of equipment
that would be used in the CCA are not
known at this time. Consequently, the
final rule specifies that owners or
operators choosing to use the CCA must
conduct an initial performance test to
determine the appropriate parameters
and corresponding parameter values to
be monitored continuously. Rationale
for the parameter selection must also be
provided for the Administrator's
approval.
  m. Reporting and Recordkeeping
Provisions. Sources subject to the
NESHAP are required to comply with
recordkeeping and reporting  provisions
in the part 63 General Provisions, and
other specified requirements in the
NESHAP.
  Sources subject to the rule  are
required to~ keep readily accessible
records  of monitored parameters. The
monitoring records must be maintained
for five years (two years on-site, three
years off-site). For each enclosure
opening, closed-vent system, and
pulping process condensate storage
tank, the owner or operator must record
the  equipment type and identification;
results of negative pressure tests and
leak detection tests; and specific
information on the nature of the defect
and repairs. The position of bypass line
valves, the condition of valve seals,  and
the  duration of the use of bypass valves
on computer controlled valves must also
be recorded.
  Sources subject to the NESHAP are
required to submit the following types
of reports: (1) Initial Notification, (2)
Notification of Performance Tests, (3)
Exceedance Reports, and (4) Semi-
annual Summary Reports. Exceedance
and summary reports are not required

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18512      Federal Register/Vol.  63, No. 72/Wednesday,  April 15, 1998/Rules and Regulations
for emission points that are exempt from
the rule. Kraft mills must also submit,
initially and bi-annually, a non-binding
compliance strategy report for pulping
sources electing to comply with the
eight-year compliance extension
(including the CCA) and for bleaching
sources at bleached papergrade kraft
and soda mills electing to comply with
the Voluntary Advanced Technology
BAT requirements. The compliance
strategy report must contain, among
other information, a description of the
emission controls or process
modifications selected for compliance
and a compliance schedule indicating
when each step toward compliance will
be reached. For mills complying with
the CCA, the report must contain a
description of alternative control
technology used, identify each piece of
equipment affected by the alternative
technology, and estimate total HAP
emissions and emission reductions.
                       C. Effluent Limitations Guidelines and
                       Standards

                       1. Subcategorization and Schedule

                         EPA is replacing the subcategorization
                       scheme under the former effluent
                       limitations guidelines for this industry
                       (in 40 CFR parts 430 and 431) with a
                       revised subcategorization scheme. EPA
                       is redesignating the Builders' Paper and'
                       Roofing Felt category, formerly
                       regulated in 40  CFR part 431, to a
                       subcategory in part 430. This eliminates
                       CFR part 431. The Agency is also
                       redesignating the previous subpart
                       numbers and section numbers, which   .
                       are shown in Table II-2.
                         EPA is making no substantive changes
                       to the limitations and standards for any
                       newly redesignated subcategory except
                       for the Bleached Papergrade Kraft and
                       Soda subcategory (new subpart B) and
                       the Papergrade Sulfite subcategory (new
                       subpart E). The  rationale for changing
                               the existing subcategorization scheme is
                               discussed in the proposal (58 FR at
                               66098-66100), the Development
                               Document for Proposed Effluent
                               Limitations Guidelines and Standards
                               for the Pulp, Paper and Paperboard
                               Point Source Category, also referred to
                               as the proposal Technical Development
                               Document (EPA 821-R93-019), and
                               EPA's response to comments on this
                               issue (DCN 14497, Vol. 1). .
                                 Although the Agency is codifying the
                               revised subcategorization scheme for the
                               whole industry today, EPA will
                               promulgate revised effluent limitations
                               guidelines and standards, as
                               appropriate, for this industrial category
                               in stages consisting of several
                               subcategories at a time. The Agency has
                               labeled these groupings of subcategories
                               as "Phase I," "Phase H," and "Phase
                               HI." The schedule for these phases is
                               explained below and in the following
                               table.
  TABLE 11-2.—FINAL CODIFIED SUBCATEGORIZATION SCHEME (WITH PREVIOUS SUBPARTS NOTED) AND SCHEDULE FOR
                   PROMULGATING EFFLUENT LIMITATIONS GUIDELINES AND STANDARDS (BY PHASE)
  Final codified
    subpart
  Final subcategorization scheme
  Types of facilities covered including previous subcategories (with pre-
              vious 40 CFR part 430 subparts noted)
 Promul-
 gation
schedule
(phase)*
A
B,
D	
Dissolving Kraft  	
Bleached  Papergrade  Kraft  and
  Soda
Unbleached Kraft	
Dissolving Sulfite
F....


G  ...


H....
Papergrade Sulfite	
  Calcium-,  Magnesium-, and  So-
  dium-based pulps.
  Ammonium-based pulps.
  Specialty grade pulps.
Semi-Chemical-	
Mechanical Pulp
Non-Wood Chemical Pulp
Secondary Fiber Deink	
                Secondary Fiber Non-Deink
                Fine and Lightweight Papers from
                  Purchased Pulp.
Dissolving Kraft (F)	
Market Bleached Kraft (G), BCT Bleached Kraft (H), Rne Bleached Kreift
  (I), Soda (P). ,
Unbleached Kraft (A)	;..
  Linerboard
  Bag and Other Products
  Unbleached Kraft and Semi-Chemical (D, V)
Dissolving Sulfite (K)	
  Nitration
  Viscose
  Cellophane
  Acetate
Papergrade Sulfite (J, U)	
  Blow Pit Wash
  Drum Wash
Semi-Chemical (B)	,	
  Ammonia
  Sodium
Groundwood-Thermo-Mechanical  (M),  Groundwood-Coarse,  Molded,
  News (N), Groundwood-Fine Papers (O), Groundwood-Chemi-Mechan-
  ical (L).
Miscellaneous mills not covered by a specific subpart	....
Deink Secondary Fiber (Q)	
  Rne Papers
  Tissue Papers
  Newsprint                                           •  •
Tissue from Wastepaper (T), Paperboard from Wastepaper (E)	.-.	.....
  Corrugating Medium
 * Non-Corrugating Medium
  Wastepaper-Molded Products (W)
  Builders' Paper and Roofing Felt (40 CFR Part 431, Subpart A)
Non integrated  Rne Papers (R)	
  Wood Rber Furnish
  Cotton Rber  Furnish
  Nonintegrated Lightweight Papers (X)
  Lightweight Papers
  Lightweight Electrical Papers
III
                                                                                                           III

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              Federal Register/Vol. 63, No.  72/Wednesday, April 15, 1998/Rules  and Regulations
                                                                      18513
   TABLE 11-2.—FINAL CODIFIED SUBCATEGORIZATION SCHEME (WITH PREVIOUS SUBPARTS NOTED) AND SCHEDULE FOR
              PROMULGATING EFFLUENT LIMITATIONS GUIDELINES AND STANDARDS (BY PHASE)—Continued
Final codified
subpart
L 	 	

Final subcategorization scheme
Tissue, Filter, Non-Woven, and Pa-
perboard from Purchased Pulp.
, Types of facilities covered including previous subcategories (with pre-
' - vious 40 CFR part 4£0 subparts noted)
Non integrated 	 	 	
Tissue Papers (S)
Filter and Non-Woven (Y) '
Paperboard (Z)
Promul-
gation
schedule
(phase)*
II

   * Phase I: Promulgation today; Phases II and III: Promulgation dates to be determined,
   ** Certain parameter limits to be promulgated as part of Phase II.
   a. Bleached Papergrade Kraft and:
 Soda Subcategory and Papergrade
 Sultite Subcategory (subparts B and E).
 Under the consent decree entered in the
 case Environmental Defense Fund and
 National Wildlife Federation v. Thomas,
 Civ. No. 85-0973 (D.D.C,),' and
 subsequently amended, EPA was'
 required to use its best efforts to
 promulgate regulations addressing
 discharges of dioxins and furans from
 104 bleaching pulp mills by June 17,
 1995. Despite making its best efforts,
 EPA was not able to promulgate final
 effluent limitations guidelines and
 standards applicable to those mills by
 that date. However, in today's rule, EPA
 is promulgating effluent limitations
 guidelines and standards for mills in the
 Bleached Papergrade Kraft and Soda
 Subcategory (subpart B) and the
 Papergrade Sulfite Subcategory (subpart
 E), thereby addressing discharges from
 96 of the mills covered by the consent
 decree. Regulating the discharge of
 dioxins and furans from the mills in the
 dissolving kraft and dissolving sulfite
 subcategories remains a very high
 priority; as discussed in more,detail
 below, EPA will promulgate effluent
 limitations guidelines and standards for
 discharges of dioxins and furans from
 those mills as soon as possible.
 ,  b. Dissolving Kraft Subcategory and
 Dissolving Sulfite Subcategory (subparts
 A and D). EPA is evaluating comments
 and preliminary new data received
 since proposal affecting the Dissolving
 Kraft and Dissolving Sulfite
 subcategories. The Agency anticipates
 that the final effluent limitations
 guidelines and standards for these
 subcategories will be based on different"
 technologies than those that served as   '
 the basis for the proposed limitations
 and standards. For example, EPA has
 received data suggesting that oxygen
 deligriification is not a feasible process
 for making some dissolving pulp
•products, particularly high grade
 products. In addition, some use of
 hypochlorite  appears to be necessary to
 maintain product quality for some
 products. Affected companies have
 undertaken laboratory studies and mill
 trials to develop alternative bleaching
 processes and to document the .effects
 on wastewater and air emissions. .The
 Agency expects to receive data on these
 studies and trials as the companies'
 efforts progress.                  •
   Because EPA's record presently is
 incomplete, EPA is not promulgating
 final effluent limitations guidelines and
.. standards for these subcategories now.
 Even; in the absence of these limitations
• and standards, however, EPA
 anticipates that alternative bleaching
 processes developed as a result of these
 studies and trials should contribute to
 substantial reductions in the generation
 and release of pollutants, when    ,
 compared to, current operating practices.
 Among the pollutants EPA expects to be
 reduced are dioxin, furan, and
 chlorinated phenolic pollutants at levels
 comparable to those achieved by
 subpart B mills. The Agency also
 expects to see significant reductions in
 AOX and.chloroform. EPA encourages
 mills in these subcategories to
 expeditiously complete developmental
 work that will facilitate installation of
.alternative process technologies that
 achieve these pollution prevention
 goals.
   As defined today, the Dissolving
 Sulfite Subcategory (subpart D) applies
 to discharges from dissolving sulfite
 mills, including mills that manufacture
 dissolving grade sulfite pulps and
 papergrade sulfite pulps at the same
 site. See 40 CFR 430.40. This definition
 is based on EPA's analysis of data
 collected in the "1990 .National Census
 of Pulp, Paper, and Paperboard
 Manufacturing Facilities." Data from the
 survey indicate that most sulfite mills
 that produce dissolving grade pulp do
 so at a very high percentage (typically
 greater than 85 percent) of their total
 pulp output.it has come to EPA's
 attention, however, that some specialty
 grade papergrade sulfite mills now have
 the capability to produce low
 percentages of dissolving grade pulp.
 EPA does not intend for these mills to
 be regulated under subpart D; rather,
 they are specialty grade sulfite mills
 within the Papergrade Sulfite
 Subcategory (subpart E).
   c. Schedule for the Remaining
 Subcategories. EPA is assessing
 comments arid data received since
 proposal for the remaining eight
 subcategories. These eight subcategories
 are: (1) Unbleached Kraft; (2) Semi-
 Chemical; (3) Mechanical Pulp;  (4) Non-'
 Wood Chemical Pulp; (5) Secondary
 Fiber Deink; (6) Secondary Fiber Non-
 Deink; (7) Fine and Lightweight Papers
 from Purchased Pulp; and (8) Tissue,
 Filter, Non-Woven, arid Paperboard
 from Purchased Pulp. For example, EPA
 has received additional information
 from an industry-sponsored survey of
 secondary fiber non-deink mills. The
 Agency also has received additional
 data from mills in other subcategories,
 including semi-chemical, unbleached
 kraft,  and secondary fiber deink. EPA
 plans to promulgate effluent limitations
 guidelines and standards for these •
 subcategories in the near futurfe. It
 should b,e noted that air emission
 standards are being promulgated today
 for these subcategories.
 2. Best Practicable Control Technology,
 Currently Available (BPT) and Best
 Conventional Pollutant Control
 Technology (BCT) for the Bleached
 Papergrade Kraft and Soda, Subcategory
 and the Papergrade Sulfite Subcategory
  Although the Agency has the statutory
 authority to revise BPT effluent
 limitations guidelines, the Agency is
 exercising its discretion not to revise
 BPT for Subparts B and E at this time.
In addition, none of the technologies
 that EPA evaluated for the purpose of
 setting more stringent effluent
 limitations for the conventional
 pollutants biochemical oxygen demand
 (BOD5) and total suspended solids (TSS)
passed the BCT cost test for either
Subcategory. Therefore, EPA is not
revising BCT effluent limitations
guidelines for Subparts B and E in this
rulemaking.            ,    '

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18514      Federal Register/Vol.  63, No. 72/Wednesday, April 15,  1998/Rules and Regulations
3. Final Regulations for the Bleached
Papergrade Kraft and Soda Subcategory
(Subpart B)
  a. Pollutants Regulated. In this rule,
EPA is promulgating effluent limitations
guidelines and standards for 2,3,7,8-
TCDD ("dioxin"). 2,3,7.8-TCDF
("furan"). 12 specific chlorinated
phenolic pollutants, the volatile organic
pollutant, chloroform, and adsorbable
organic halides (AOX). EPA is also
promulgating new source performance
standards for BOD5 and TSS. As
explained in section VI.B.3 below, the
Agency is not promulgating effluent
limitations guidelines and standards for
chemical oxygen demand (COD) at this
time. EPA is also not promulgating
effluent limitations guidelines and
standards for methylene chloride,
methyl ethyl ketone (MEK), acetone, or
color. See Section VI.B.3.
  b. Best Available Technology
Economically Achievable (BAT). After
re-evaluating technologies for mills in
the Bleached Papergrade Kraft and Soda
subcategory, EPA has determined that
the model technology for effluent
limitations based on best available
technology economically achievable
(BAT) should be complete (100 percent)
substitution of chlorine dioxide for
chlorine as the key process technology,
along with other in-process technologies
and existing end-of-pipe biological
treatment technologies. See Section
VI.B.5.a.
  c. New Source Performance
Standards. The Agency has determined
that the technology basis defining new
source performance standards (NSPS)
for toxics and non-conventional
pollutants is the BAT model technology
with the addition of oxygen
deHgnification and/or extended
cooking. See Section VLB.S.b. EPA is
also promulgating NSPS for the
conventional pollutants BOD5 and TSS.
  As discussed elsewhere in today's
Federal Register, EPA also is soliciting
comment and intends to gather
additional data with respect to totally
chlorine-free processes that may be
available for the full range of market
products. EPA will.determine whether
to propose revisions to NSPS based
upon TCF and, if appropriate, flow
reduction technologies.
  In this rule, NSPS are effective June
15,1998. A source is a new source if it
meets the definition of new source in 40
CFR 430.01 (j) and if it commences
construction after that date.
   d, Pretreatment Standards. The
Agency is promulgating pretreatment
standards for existing sources (PSES)
based on the BAT model technology,
excluding biological treatment. EPA is
 promulgating pretreatment standards for
 new sources (PSNS) based on the model
 technology for NSPS, excluding
 secondary biological treatment. A
 source is a new source for purposes of
 PSNS if it meets the definition of new
 source in 40 CFR 430.01 (j) and if it
 commences construction after the date
 of proposal, i.e., December 17, 1993.
 However, a new indirect discharger is
 not required to meet PSNS for subpart
 B until those standards become
 effective, i.e., June 15,1998.
  e. Voluntary Incentives Program
 Based on Advanced Technology. As
 noted earlier in this notice, EPA's vision
 of long-term environmental goals for the
 pulp and paper industry includes
 continuing research and progress
 toward environmental improvement.
 EPA recognizes that technologies exist,
 or are currently under development at
 some mills, that have the ability to
 surpass the environmental protection
 that would be provided by compliance
 with the baseline BAT effluent
 limitations guidelines and NSPS
 promulgated today. The Agency
 believes that individual mills could be
 encouraged to explore and install these
 advanced technologies. Accordingly,
 EPA is establishing a Voluntary
 Advanced Technology Incentives
 Program for direct discharging mills in
 the Bleached Papergrade Kraft and Soda
 subcategory. This program is discussed
 in Section DC.
 4. Final Regulations for the Papergrade
 Sulfite Subcategory (Subpart E)
  a. Segmentation of Subpart E and Best
 Available Technology Economically
 Achievable (BAT). After assessing
 comments and data received after the
 proposal, EPA is segmenting the
 Papergrade Sulfite subcategory to
 account for production of specialty
 grade pulps and the applicability of
 technologies to ammonium-based
 pulping processes.
  The Agency is segmenting this
 subcategory and establishing BAT
 technology bases set forth below. (EPA
 has established the same segments for
 new source performance standards and
 pretreatment standards for subpart E.)
   (1) For production of pulp and paper  .
 at papergrade sulfite mills using an
 acidic cooking liquor of calcium,
 magnesium, or sodium sulfite (unless
 the mill is a specialty grade sulfite mill),
 the BAT technology basis is totally
 chlorine-free bleaching. EPA is
 promulgating limitations for AOX for
 this segment. See Section VI.B.B.b.
   (2) For production of pulp and paper
. at papergrade sulfite mills using an
 acidic cooking liquor of ammonium
 sulfite (unless the mill is a specialty
grade sulfite mill), the BAT technology
bases for this segment are elemental
chlorine-free (ECF) technologies
(complete substitution of chlorine
dioxide for elemental chlorine, peroxide
enhanced extraction, and elimination of
hypochlorite) and biological wastewater
treatment. EPA is promulgating effluent
limitations for dioxin, furan, and 12
chlorinated phenolic pollutants for this
segment, but is reserving promulgation
of chloroform, AOX, and COD   .
limitations until sufficient performance
data are available. See Section VI.B.G.b.
  (3) For production of pulp and paper
at specialty grade sulfite mills, the BAT
technology bases for this segment are
ECF technologies (complete substitution
of chlorine dioxide for elemental
chlorine, oxygen and peroxide
enhanced extraction, and elimination of
hypochlorite) and biological wastewater
treatment. EPA is promulgating effluent
limitations for dioxin, furan, and 12
chlorinated phenolic pollutants for this
segment, but is reserving promulgation
of chloroform, AOX, and COD
limitations for this segment until
sufficient performance data are
available. See Section VLB.6.b.
  b. New Source Performance
Standards. For each segment identified
above, EPA is establishing NSPS based
on the model BAT technologies selected
for the particular segment. The
pollutants are the same as those
regulated by BAT for the applicable
segment. EPA is also exercising its
discretion not to revise NSPS for BOD5,
TSS, and pH. See Section VI.B.G.c.
  c. Pretreatment Standards. The
Agency is promulgating pretreatment
standards for the segments  identified
above. The pretreatment standards for
existing sources (PSES) control the same
pollutants controlled by BAT for the
particular segment. EPA is  promulgating
pretreatment standards for  new sources
(PSNS) for the same toxic and
nonconventional pollutants controlled
by NSPS for the particular segment. A
source is a new source for purposes of
PSNS if it meets the definition of new
source in 40 CFR 430.0 l(j)  arid if it
commences construction aftear the date
of proposal, i.e., December 17, 1993.
However, a new indirect discharger is
not required to meet PSNS for subpart
E until those standards become
effective, i.e., June 15, 1998. The
technology bases for PSES and PSNS for
the Papergrade Sulfite subcategory are
the same as those chosen for the
particular segments at the BAT and
NSPS levels, respectively, excluding
secondary biological treatment. For the
ammonium-based and specialty grade
segments, EPA is deferring making a
pass-through determination, and hence,

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             Federal Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules and Regulations
                                                                     18515
 promulgating pretreatment standards,
 for chloroform and AOX until it has
 sufficient performance data to set
 limitations and standards for those
 parameters. EPA is promulgating
 pretreatment standards for AOX for the
 calcium-, magnesium-, and sodium-
 based sujfite segment. EPA has made no
 pass-through determination at this time
 for COD for any segment. More details
 are described below in section VI.B.G.d.

 5. Best Management Practices for the
 Bleached Papergrade Kraft and Soda
 Subcategory and the Papergrade Sulflte
 Subcategory                     • •   :
  EPA is codifying best management
 practices (BMPs) applicable to direct-
 and indirect-discharging mills in the
 Bleached Papergrade Kraft and Soda
 and Papergrade Sulflte subcategories. In
 response to comments, EPA changed the
 scope of the BMPs to focus on spent
 pulping liquor, turpentine, and soap
 control and to allow for more flexibility
 in implementation. See Section VI.B.7.
 m. Background

 A. Prior Regulations, Proposal,  Notices
 of Data Availability, and Public
•Participation
  The regulations that EPA developed
 for the pulp, paper, and paperboard
 industry prior to this date are discussed
 in the proposal. See 58 FR at 66089-92.
  In a Federal Register notice published
 on December 17, 1993 (58 FR 66078),
 EPA proposed integrated air and water
 rules that included proposed limitations
 and standards to reduce the discharge of
 toxic, conventional, and
 nonconventional pollutants in
 wastewaters and to reduce emissions of
 hazardous air pollutants from the pulp,
 paper, and paperboard industry. These
 proposed integrated regulations
 subsequently became known as "the
 Cluster Rules." EPA held a public
 hearing in Washington, D.C., on
 February 10, 1994, to provide interested
 persons the opportunity for oral
 presentation of data, views, or
 arguments concerning the proposed
 pretreatment standards. On March 17,
 1994 (59 FR 12567), EPA published a
 correction notice to the proposed rules
 and extended the comment period to
 April 18, 1994.      •
  In the preamble to the proposed rules,
 EPA solicited data on various issues and
 questions related to the proposed
 effluent limitations guidelines and
 standards and air emissions standards.
 The Agency received and added new
 material to the-Air and Water Dockets.
 In a notice of data availability published
 on February 22, 1995 (60 FR 9813), EPA
 announced the availability of new data'
 related to the proposed air emissions
 standards. Those new data are located •
 in Air Docket A-92-40.
   In a second notice of data availability
 published on July 5, 1995 (60 FR
 34938), EPA announced the availability
 of new information and data related to
 the proposed effluent limitations
 guidelines and standards. Those new
 data are located starting at Section 18.0
 of the Post-Proposal Rulemaking
 Record, which is a continuation of the
 proposal record. The Post-Proposal
 Rulemaking Record is located in the
 Water Docket. EPA did not solicit
 comment on the new air and water data
 in either notice.
   On March 8, 1996, EPA published a'
 Federal Register notice pertaining to the
 air portions of the proposed rules and
 announced the availability of
 supplemental information (61 FR 9383).
 The comment period for that notice
 closed on April 8,1996. EPA also
 proposed MACT standards for   ,
 mechanical pulping mills, secondary
 fiber pulping (deinked and non-
 deiriked) mills, and non-wood mills,
 and asked for additional information on
 these mills. Furthermore, EPA
 announced that it was continuing to
 investigate paper machines and that no
 MACT standard for paper machines was
 being proposed at the time. EPA
 acknowledged an industry testing
 program was underway; EPA also
 acknowledged its request to States for
 data on non-wood pulping mills. EPA
 requested additional data on HAP
 emissions from, and control
 technologies for, paper machines to
 supplement information previously
 collected under the MACT process.
   On July 15,1996, the Agency
 published a Federal Register notice
 announcing the Agency's thinking,
 based on preliminary evaluation of the
 supplemented record and stakeholder
 discussions, regarding the technology
 options being considered as a basis for
 final effluent limitations guidelines and
 standards for the proposed Bleached
 Papergrade Kraft and Soda and
 Papergrade Sulfite subcategories (61  FR
 36835). Data were added to the record
 and comments were solicited from
 interestedparties. The comment period
 for that notice closed on August 14,
 1996.
   The Agency has held numerous
 meetings on these proposed integrated
 rules with many pulp and paper
'•industry stakeholders, including a trade
 association (American Forest and Paper
 Association, or AF&PA), numerous
 individual companies, environmental
 groups. States, laboratories, consultants
 and vendors, labor unions, and other
 interested parties. EPA .has added
materials to the Air and Water Dockets
to document these meetings.

B. Clean Air Act Statutory Authority
  Section 112 (b) of the CAA lists 189
HAPs and directs EPA to develop rules
to control all major and some area
sources emitting HAPs. Major sources
are facilities that emit 10 tons of any
single HAP or 25 tons of total HAPs
annually. On July 16,1992 (57 FR
31576), EPA published a list of major
and area sources for which NESHAP are
to be. promulgated. The goal of NESHAP
is to require the implementation of
maximum achievable control
technology (MACT) to reduce emissions
and, therefore, reduce public health
hazards from pollutants emitted from
stationary sources. Pulp and paper
production was listed as a category of
major sources. On December 3,1993 (58
FR 83941), EPA published a schedule
for promulgating standards for the listed
major and area sources. Standards for
the pulp and paper source category were
scheduled for promulgation by
November 1997.
  NESHAP established under section
112 of the Act reflect MACT or:
* * * the maximum degree of reduction in
emissions of the [HAP] ** * that the
Administrator,,taking into consideration the
cost of achieving such emission reduction,
and any nonair quality health and
environmental impacts and energy
requirements, determines is achievable for
new or existing sources in the category or
Subcategory to which such emission standard
applies  *  *  * (See CAA section 112 (d) (2)).

C. Clean Water Act Statutory Authority
  The objective of the Clean Water Act
(CWA)  is to "restore and maintain the
chemical, physical, and biological'
integrity of the Nation's waters." CWA
Section 101 (a). To assist in achieving  ^
this objective, EPA issues effluent
limitations guidelines, pretreatment
standards, and new source performance
standards for industrial dischargers. The
statutory requirements of these
guidelines and standards are
summarized in the proposal. See 58 FR
at 66088-89.

D. Other EPA Activities Concerning the
Pulp and Paper Industry

1. Land Disposal Restrictions Activities
  At the time of proposal, it appeared
that many of the surface impoundments •
used for wastewater treatment in the
pulp and paper industry might become
subject to Resource Conservation and
Recovery Act (RCRA) regulation under
the Land Disposal Restriction (LDR)
program. See 58 FR at 66091. This
program establishes treatment standards
that hazardous wastes must meet before

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 18516      Federal Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules and Regulations
they can be land disposed—placement
in surface impoundments being a type
of land disposal. This requirement
extends not only to wastes that are
identified or listed as hazardous under
the RCRA rules when they are land
disposed, but also to wastes that are
hazardous when generated, cease to be
hazardous as a result of dilution, and
are then disposed.  Chemical Waste
Managementv. EPA, 976 F.2d 2 (D.C.
Cir. 1992). cert denied, 507 U.S. 1057
(1993).
  The pulp and paper industry has
many mills that fit this pattern:
Numerous wastewater streams are
generated, some of them exhibit a
characteristic of hazardous waste
(corrosivity or toxicity in particular), the
streams are commingled before
centralized wastewater treatment
occurs, and, in the course of
commingling, the wastes no longer
exhibit the characteristic, and the
commingled wastewaters are then
treated in a surface impoundment. EPA
actually took action to temporarily defer
applying LDR rules to this type of
situation in the pulp and paper industry
in order to allow unhindered
promulgation of these Cluster Rules. See
61 FRat 15660,15574 (April 8,1996).
  This issue, however, is now moot, at
least for the time being. As discussed in
the April 8,1996, notice partially
withdrawing the LDR Phase IE final
rule, 61 FR 15660, the Land Disposal
Program Flexibility Act of 1996
provides, among other things, that
RCRA characteristic wastewaters are no
longer prohibited from land disposal
once they are rendered nonhazardous,
provided that they are managed in
either a treatment system whose
ultimate discharge is regulated under
the CWA (including both direct and
indirect dischargers), a CWA-equivalent
treatment system, or a Class I
nonhazardous injection well regulated
under the  Safe Drinking Water Act.
Under the Land Disposal Program
Flexibility Act of 1996. the LDR
treatment standards for RCRA
characteristic wastes in the pulp and
paper industry (or any other industry)
do not apply if the characteristic is
removed and the wastes are
subsequently treated in a surface
impoundment that is part of a
wastewater treatment system whose
ultimate discharge is regulated by the
CWA, or if a mill's treatment system
provides wastewater treatment that is
CWA-equivalent.
  It should be noted that the Act
requires EPA to undertake a five-year
study to determine any potential risks
posed by cross-media transfer of
hazardous constituents from surface
impoundments that accept these "de-
characterized" wastes and warrant
RCRA regulation. The findings of this
study, begun by the Agency in April
1996, could eventually result in RCRA
regulations for these units.

2. Land Application of Sludges

  Under the Consent Decree entered in
the case Environmental Defense Fund
and National Wildlife Federation v.
Thomas, Civ. No. 85-0973 p.D.C.), EPA
was required to propose rules under
section 6 of the Toxic Substances
Control Act (TSCA) to regulate the use  ,
of sludge produced from the treatment
of wastewater effluent of pulp and paper
mills using chlorine and chlorine-
derivative bleaching processes (56 FR
21802; Docket OPTS-62100). EPA
published the proposed rules on May
10, 1991. The proposed regulations
sought to establish a final maximum
dioxin and furan soil concentration of
ten parts per trillion (ppt)  toxic.
equivalents CTEQ) and site management
practices for the land application of
bleached kraft and sulfite  mill sludge.
EPA originally planned to promulgate
the rule by November 1992.
  On December 11, 1992,  EPA informed
the plaintiffs of the Consent Decree that
the decision on the promulgation of the
proposed sludge land application rule
was deferred pending promulgation of
the integrated rulemaking for effluent
limitations guidelines and standards
and national emission standards. EPA
reasoned that the effluent  limitations
guidelines and standards and air
emissions standards would have the
potential to result in bleach plant
process  changes that EPA  expected
would result in reduced dioxin and
furan contamination levels in sludge. In
addition, EPA was awaiting the results
of its dioxin reassessment activities.
  In light of the anticipated impact of
the effluent limitations guidelines and
standards and air emissions standards
on reducing dioxin in pulp and paper
mill sludges, as well as reduction in
sludge'dioxin levels from  industry-
initiated improvements, EPA chose to
defer the decision on promulgation of
the final sludge land application rule.
When EPA has determined the final
impact of today's effluent  limitations
guidelines and standards on sludge
dioxin concentration, EPA will re-
evaluate the risk from sludge land
application and will choose the
appropriate regulatory or non-regulatory
mechanism to address the situation.
  Prior to that determination, however,
EPA has taken action to achieve risk
reduction for situations where sludge is
being applied to land.
  While awaiting completion of the
effluent limitations guidelines and
standards, air emission standards and
the dioxin reassessment, EPA has
promoted the establishment of an
industry environmental stewardship
program for the practice of sludge land
application.

3. Hazardous Listing Determination
  Under the consent decree entered in
the case of Environmental Defense Fund
v. Browner, Civ. No. 89-0598 CD .D.C.),
"EPA shall promulgate a listing
determination for sludges from pulp and
paper mill effluent on or before the date
24 months after promulgation of an
effluent guideline regulation under the
Clean Water Act for pulp and paper
mills. This listing determination shall
be proposed for public comment on or
before the date 12 months after
promulgation of such effluent guideline
regulation. However, EPA shall not be
required to propose or promulgate such
a listing determination if the final rule
for the pending effluent guideline
rulemaking (amending 40 CFR part 430)
under the Clean Water Act to regulate
the discharge of dioxins from pulp and
paper mills is based on the use of
oxygen delignification, ozone bleaching,
prenox bleaching, enzymatic bleaching,
hydrogen peroxide bleaching, oxygen .
and peroxide_enhanced extraction, or
any other technology involving
substantially similar reductions in uses
of chlorine-containing compounds. If
EPA concludes that the final effluent
guideline regulation is based on use of
such a process and that, as a result, no
listing determination is required, EPA
shall so inform plaintiff in writing
within 30 days of the promulgation of
the effluent guideline regulation."
  At this time, EPA is assessing whether
the technology bases for the effluent
limitations guidelines and standards
promulgated today would fulfill the
condition described in the Consent
Decree. If so, the Agency would
conclude that a listing determination is
not warranted. If EPA concludes it does
not fulfill the condition, a listing
determination would be conducted.

4. Dioxin Reassessment
  In the spring of 1991, EPA initiated an
effort to reassess the scientific bases for
estimating dioxin risk.  The activities
associated with the dioxin reassessment
before proposal are described in the
proposal. See 58 FR at 66092-93. After
the proposal, in September 1994, EPA
published a public review draft of this
effort, which is commonly referred to as
the EPA Dioxin Reassessment. The draft
reassessment addressed not only the
health effects of dioxin-like chemicals

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             Federal Register/Vol.  63. No. 72/Wednesday. April 15,  1998/Rules and Regulations      18517
 but also diqxin sources and pathways
 for human exposure. Since the draft
 documents were released, EPA received
• thousands of pages of public comments.
 EPA submitted the documents to formal.
 peer, review by the EPA Science
 Advisory Board (SAB). The SAB was
 supportive of the overall reassessment
 effort and endorsed the major
 conclusions of the exposure document
 and chapters one through seven of the
 health document. They did, however,
 believe that additional work was needed
 on the dose-response modeling chapter
 and the risk characterization chapter.
 '  The reassessment is currently being
 revised and updated in response to
 public comments. The two chapters
 singled out by the SAB are being revised
 by specially established panels
 composed of scientists from both inside'
 and outside the Agency. Once the work
 of the special panels is completed these
 two revised chapters will be examined
 by peer review panels, and then
 resubmitted to the SAB for final review.
 EPA currently anticipates completion
 and release of the dioxin reassessment
 in the spring of 1998.

 5. Clean Water Act Section 307(a)
 Petition

   On September 14,1993,  the Natural
 Resources Defense Council and the
 Natural Resources Council of Maine
 filed with EPA on behalf of 57
 individuals and environmental groups a
 petition to prohibit the discharge of
 dioxin by pulp and paper mills. The '
 petitioners ask EPA to accomplish this
 prohibition by prohibiting the use of
 chlorine and chlorine-containing
 compounds as inputs in the
 manufacturing process. The petitioners
 believe that the prohibition is warranted
 by the dangers to human health and the
 environment posed by dioxin. The
 petitioners invoke CWA section
 307(a) (2) for authority for such a
 prohibition.
   Authority for the petition and
 requested prohibition derives from a
 different section of the Clean Water Act
 than today's technology-based effluent
 limitations guidelines and standards.
 However, because the petition raised
 many issues related to the effluent
 guidelines rulemaking, EPA solicited
 comment on the issues raised in the
 petition at the time it proposed effluent
 limitations guidelines and standards for
 the pulp and paper industry. See 58 FR
 at 66174. EPA received thousands of
 pages of comments and expects to issue
 a decision granting or denying the
 petition after completion of the dioxin
reassessment.     -            .
 6. Cooling Tower Intake Assessment
  . EPA is developing regulations under
 section 316(b) of the Clean Water Act,
 which provides that any standard
 established pursuant to Section 301 or
 306 and applicable to a point source
 shall require that the location, design,
 construction, and capacity of cooling
 .water intake structures reflect the best
 technology available for minimizing
 adverse environmental impact. Section
 316(b) applies only to the intake of
 wafer, not the discharge. A primary goal
 of the regulation that EPA is developing
 would be to minimize the destruction of
 fish and other aquatic organisms as they
 are drawn into an industrial facility's
 water intake. EPA plans to conduct
 screening level and detailed surveys to
 estimate the number and type of
•facilities that utilize cooling water-
 intake structures and thus are within the
 scope of Section 316(b). The pulp and
 paper industry uses a significant
 amount of cooling water. EPA intends to
 gather data on pulp and paper facilities
 during the Section 316(b)  rulemaking  •
 through questionnaires and site visits.
 The Section 316 (b) regulation is
 scheduled for proposal in  1999 with the
 final rule due in 2001.

 IV. Changes in the Industry Since
 Proposed
  A description of the pulp and paper
 industry, including manufacturing
 processes, pulping processes, bleaching
 processes, andpapermaking.is included
 in the proposal. See 58 FR at 66095-96.
  The proposed water regulation
 encompassed the entire pulp and paper
 industry of approximately 500 facilities.
The proposed air regulations (MACTI
 and MACT HI) covered approximately
the same number. Under today's action,
approximately 490 mills will be covered
by the final MACT I and MACT ffl rules.
 Of these mills, 155 will be affected by
MACT standards for mills that
chemically pulp wood. A subset of these
mills—96 mills—will be covered by the
final effluent limitations guidelines and
standards promulgated today.
  Since the proposal, some facilities
have modified their processes. There
has been a substantial move toward
elemental chlorine-free (ECF) bleaching,
and mills are continuing to increase
their substitution of chlorine dioxide for
chlorine. Additionally, more mills are
utilizing oxygen delignification and  .
extended cooking than at proposal. All
these developments result in decreased
discharges of dioxins and furans to
receiving waters.
  The U.S. pulp and paper industry's
involvement with totally chlorine-free
(TCP) bleaching has not changed
 substantially since proposal. As was the
 case at the time of proposal, only one
 U.S. mill produces TCP kraft pulp;
 however, this mill is now able to attain
 higher brightness than was achieved at
 the time of the 'proposal.
   The number of companies in the
 industry is constantly changing as new
 companies enter the market and other
 companies leave the industry or merge
' with other companies. In the
 subcategories now designated as
 Subparts B and E, only one mill has
 closed since proposal and one has
 changed subcategories. No new Subpart
 B or E mills have commenced
 construction since the time of proposal.
   For more details on the technology
 status of mills covered by the filial
 Cluster Rules, see the "Supplemental
 Technical Development Document,"
 DCN 14487.

 V. Summary of Data Gathering
 Activities Since Proposal

 A. Data Gathering for the Development
 of Air Emissions Standards
   To develop today's standards,
 extensive data collection and technical
 analyses were conducted. Prior to
 proposal, EPA used information in a
 1990 census of pulp and paper mills, a
 1992 voluntary mill survey, an EPA
 sampling program, site visits at a
 number of mills, and a review of State
 and local regulations to obtain
 information on emissions, emission
 control technologies, and.emission
 control costs for pulp and paper mill
 emission points. After proposal, EPA
 obtained additional information from
 the industry. This information included
 test reports from a variety of testing
 programs, as well as numerous reports,
 studies, and memoranda on other issues
 related to the development of emission
 control requirements. The information ,
 collected before and after proposal was
 used as the technical basis in
 determining the MACT level of control..'
  EPA also used information on pulp
 and paper mill production processes
 available in the general literature and
 information on control-technology
 performance and cost information
 developed under other EPA standards to
 determine MACT.
  Industry commenters indicated that
 they would be completing a
 comprehensive emission testing ..
 program after proposal, and EPA
 considered this information to be vital
 to the development of the final
 regulation. Therefore, EPA agreed to
 consider the new data and issued two
 notices of availability of supplemental
 information on February 22,  1995 (60
 FR9813) and March 8, 1996  (61 FR

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Federal Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules and  Regulations
9383) announcing the information and
offering the likely implications to the
final rule. The opportunity for a public
hearing was offered on the March 8,
1996 action, but no request for a hearing
was received. Public comments on the
March 8,1996 action were accepted
from March 8,1996 to April 8.1996.
Commenters included industry
representatives, States, environmental
organizations, and other members of the
public.
  In the March 8, 1996 supplemental
notice, EPA solicited additional data
and comments on proposed  changes to
the December 17. 1993 proposed rule.
  Data added to Air Docket A-92-40
since the March 8,1996 supplemental
notice are located in section IV of this •
docket. These items include additional
information on sulfite mills  (TV-D1-98,
IV-D1-100), comments on definitions
(TV-D1-97, IV-D1-99, IV-D1-104),
comments on the emission factor
document (IV-D1-102), clarification of
the 1992 MACT survey responses (IV-
Dl-101), and other information.
B. Data Gathering for the Development
of Effluent Limitations Guidelines and
Standards
  EPA has gathered a substantial
amount of new information and data
since proposal in connection with
today's water regulations. Much of this
information was collected with the
cooperation and support of the
American Forest and Paper Association
(AF&PA) and the National Council of
the Paper Industry for Air and Stream
Improvement (NCASI), and with the
assistance of many individual mills in
the United States. Additional
information also has been submitted by
environmental groups. EPA  has
gathered additional information from
pulp and paper mills outside of the
United States, primarily in Canada and
Europe.
  Some of the new information and data
were generated through EPA-sponsored
field sampling or visits at individual
mills in the United States, Canada, and
Europe. Additional sampling data were
voluntarily supplied by many facilities,
and information from laboratory and
pilot-scale studies was shared with the
Agency. In order to clarify comments on
the proposal, the Agency also gathered
information from several surveys
administered by AF&PA and NCASI.
including data on secondary fiber mill
processes, recovery furnace  capacities,
best management practices,  capital and
operating costs, process operations, and
impacts of technology on the recovery
cycle.
  The data gathering activities for this
final rule are summarized in detail in
                          the proposal, see 58 FR at 66096, and in
                          the July 15, 1996, notice of data  '
                          availability, see 61 FR at 36837.
                          VI. Summary of the Major Changes
                          Since Proposal and Rationale for the
                          Selection of the Final Regulations
                          A. Air Emission Standards
                            At proposal, the standards for mills
                          that chemically pulp wood were based
                          on the MACT floor control level. A
                          uniform set of requirements would have
                          applied to all mills that chemically pulp
                          wood using the kraft, sulfite, soda, or
                          semi-chemical process. The proposed
                          standards would have required that,
                          with the exception of some with very
                          low volumetric and mass flow rates, all
                          emission points in the pulping and
                          bleaching area of these mills be
                          controlled. The proposed standards also
                          would have required that all wastewater
                          streams produced in the pulping area of
                          the mill be controlled except for those
                          with a specified low concentration of
                          hazardous air pollutants (HAPs). The
                          proposed control technology basis was
                          to enclose any open process equipment
                          in the pulping and bleaching areas and
                          route all vents and pulping wastewater
                          to a control device. The proposed
                          control technology basis was
                          combustion for pulping area vent
                          sources, scrubbing for bleaching area
                          vent sources, and steam stripping for
                          pulping wastewater.
                            Following proposal, EPA received a
                          large number of comments and data to
                          support the need for subcategories with
                          separate MACT standards for each. After
                          considering the data and comments, the
                          final rule specifies separate MACT
                          requirements for each of the four types
                          of pulping processes subject to the
                          standard. The low volumetric and mass
                          flow rates for pulping and bleaching
                          vents and the low concentration value
                          for pulping wastewater are no longer
                          used to determine applicability  to the
                          standard. Rather, for each subcategory,
                          the standard lists the specific equipment
                          and pulping area condensates that
                          require control.
                            For each subcategory, the Agency
                          determined the MACT floor level of
                          control for existing and new sources,
                          and analyzed the cost and impacts for
                          control options more stringent than the
                          floor. This analysis is presented in
                          chapter 20 of the background
                          information document for the
                          promulgated NESHAP, and is also
                          discussed in the proposal preamble.
                          Based on the results of this analysis, the
                          Agency determined that it was not
                          reasonable to go beyond the MACT floor
                          level of control for sources at kraft,
                          semi-chemicaf, and sulfite pulp mills,
bleaching systems, or kraft cbndensate
systems. The Agency determined that
control beyond the floor at soda mills
was technically feasible and could be
achieved at a reasonable cost. A
discussion of the Agency's decision for
soda mills is presented in the March 8
Supplemental notice and in section
VI.A.5.
  In response to comments received on
the proposed standards, several changes
have been made to the final rule. While
some of these changes are clarifications
designed to make the Agency's intent .
clearer, a number of them are significant
changes to the compliance
requirements. A summary of the
substantive comments and changes
made since the proposal are described
in the following sections. Detailed
Agency responses to public comments
and the revised analysis for the final
rule are contained in the background
information document and docket. See
Section X.A.
1. Definition of Source

  At proposal, EPA defined a single
broad source that was subject to both
existing and new source MACT. That
single source included the pulping
processes, the bleaching processes, and
the pulping and bleaching process
wastewater streams at a pulp and paper
mill. EPA also considered and solicited
comments on the concept of multiple
smaller sources that would be subject to
the existing and new source MACT
requirements.
  In defining the source at proposal,
EPA considered the impact of the
definition on mills making changes to
existing facilities. In general, the
narrower the definition of source, the
more likely it is that changes to existing
facilities would be deemed "new
sources"  under the CAA. With limited
exceptions, these new sources must be
in compliance with new source MACT
standards on the date of startup or June
15, 1998, whichever is later. However,
the CAA and the CWA differ regarding
applicability requirements and
compliance deadlines for new sources.
As such,  EPA was concerned that a pulp
and paper mill planning to construct or
reconstruct a source of HAPs between
proposal and promulgation of these
integrated regulations would find it
necessary" to plan for compliance with
the NESHAP  (required on the date it
becomes effective) without knowing the
requirements of the effluent .guidelines
for the industry. This situation appeared
to be inconsistent with one,objective of
the integrated rulemaking: allowing
facilities to do integrated compliance
planning. EPA thus determined that the

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                                                                     18519
  best solution to these concerns was to
  define a single broad source at proposal.
   In the March 8, 1996 supplemental
  notice, EPA indicated a continuing
  inclination for a broad, single source
  definition. EPA also discussed
  broadening the source definition further
  to include papermaking systems and
  causticizing equipment and solicited
  comments on these additions. EPA's
  reason for considering the addition of
  these'two equipment systems was to
  facilitate implementation of the clean
  condensate alternative for kraft mills.
   Commenters on the proposed
  standards and on the March 8 notice
  largely agreed with the broad, single
  source definition. One commenter
  supported a narrow source definition,
  noting it was inappropriate for new
  construction at an existing source to be
  classified as a modification (and hence
  subject to existing source MACT). The
  commenter further stated that the final
  regulation .should specify a narrow
  source definition for determining
  applicability to new source MACT.
  Some commenters also stated that EPA
  should clarify for the final regulation
  that mill processes not included-in the
  source definition should not be subject
  to future case-by-case MACT
  requirements under CAA section 112(g).
   EPA considered all of the comments
  received on this issue since proposal
  and maintains that the definition of
  source should be broad enough such
  that small changes to an existing mill do
  not trigger new source requirements in
  the NESHAP. However, EPA also agrees
. with the commenter that at some point,
  changes to an existing mill are
 substantial enough that new source
 MACT should apply.
   In considering how best to define the
 source, EPA did not want to define it so
 narrowly that changes to or additions of
 individual pieces of equipment would
 be subject to new source MACT and be
 required to be in compliance with new
 source MACT at startup. In fact.'EPA
 was concerned that to do so could
. discourage mills from implementing  .
 pollution-prevention changes as soon as
1 practicable after promulgation of the
 Cluster Rules. Such changes might
 include replacing an" existing rotary
 vacuum washer system with a low-flow
 washer system or installing an oxygen
 delignification system, both of which, if
 subject to existing source requirements,
 would get the eight-year compliance
 time, discussed later in section VI.A.S.b.
 Once mills are complying with the
 existing source MACT requirements, it
 also did not seem reasonable that they
 should have to tear out and rebuild that
 vent collection system to accommodate
 small equipment changes in the future
 unless those changes occurred along
 with other substantial changes that
 would justify rebuilding the vent
 collection system.
   For the'final regulation, EPA is
 defining the affected source to which ,
 existing MACT requirements apply to
 include the  total of all HAP emission
 points in the pulping and bleaching
 systems (including pulping"
 condensates). In considering how mills
 might engineer their vent collection
 systems and control devices, EPA has
 concluded that the following actions
 occurring after proposal are substantial
 enough that new source MACT
 requirements apply:
   • A pulping or bleaching system at an
 existing mill is constructed or
 reconstructed; or
   • A new pulping line or bleaching
 line is added to an existing mill.
   The proposal date for mills that
 chemically pulp wood is December 17, :
 1993. The proposal date for mills that
 mechanically pulp wood, pulp
 secondary fibers, or pulp non-wood
 materials is March 8, 1996.
   The final regulation also provides for
 an alternative definition of source to
 facilitate implementation of the clean
 condensate alternative. For mills using
 the alternative to comply with the kraft
 pulping standards, the final regulation -
 defines  a single broad source that
 includes the total of all pulping,  bleach,
 causticizing, and papermaking systems.
 A more  detailed discussion of the clean
 condensate alternative is given in
 section VLA.S.d.
   EPA agrees with the commenters that
 certain emission points that are
 excluded from the definition of affected
 source in today's rule, or are subject to
 a determination that MACT for these
 operations is no control, should not be
 required to undergo CAA section 112 (g)
 review.  The  sources that have been so
 identified are wood yard operations
 (including wood piles); tall oil recovery
 systems at kraft mills; pulping systems
 at mechanical, secondary fiber, and non-
 wood fiber pulping mills;  and
 papermaking systems. With regard to
 wood yard operations, tall oil recovery-
 systems, and pulping systems at
 mechanical,  secondary fiber, and non-
 wood fiber pulping mills,  EPA has
 determined that these sources do not
 emit significant quantities of HAPs and
 EPA is not aware of any reasonable
 technologies for controlling HAPs from
these sources. For papermaking systems,
 EPA has not identified any reasonable
 control technology, other than the clean
 condensate alternative, that can reduce
HAP emissions attributable to HAPs
present in the pulp arriving from the
pulping and bleaching systems.
 Additionally, EPA has determined that
 the use of papermaking systems
 additives and solvents do not result in
 significant emissions of HAPs (Air
 Docket A-92-40, IV-B-27). Therefore,.
 based on the applicability requirements
 of section 112(g) [40 CFR 63 part B,
 63.40(b)], the following sources would
 not be required to undergo section
 112(g) review: wood yard operations;
 pulping systems at mechanical,
 secondary fiber, and non-wood fiber
 mills; tall oil recovery systems; and
 papermaking systems.
 2. Named Stream Approach
   At proposal, the rule proposed
. applicability cutoff values (i.e.,
 volumetric flow rate and mass flow rate)
•as a way to distinguish the vent and
 condensate streams that would be
, required to meet the rule. Since
 proposal, the pulp and paper industry
 submitted additional data that allowed
 EPA to better characterize the vent and
•condensate streams that should be
 controlled.
   In the final rule, the applicability
 cutoffs contained in the proposed rule
 have been replaced in favor of
 specifically naming process equipment
 and condensate streams that would be
 required to meet the rule, with the
 exception of decker, knotter, and screen
 systems at existing sources. For these
 systems, the additional industry data
 was used to determine applicability
 cutoffs in the form of HAP emission
 limits'(for knotter and screen systems)
 and HAP concentration limits in process
water (for decker systems) to identify
the systems that should be controlled at
 existing sources. A description of the
vent and condensate streams to be
 controlled is presented in sections
H.B.2, VI.A.3.a, and VI.A.4-7. The
Agency added language in the
•definitions for,the named systems to
make the definitions applicable to
equipment that serves a similar function
as those specifically listed. This
addition was made because there are no
standard names for process equipment.
The EPA's intent was to include the
equipment that function the same as the
equipment specifically .named in the
definitions, even though the mill may
use a different name for that piece of
equipment.                     '
  The different approach used in the
final rule does not significantly change
the number of emission points
controlled from those intended to be
controlled in the proposed rule. The
emission points and condensate streams
that are being controlled in the final rule
are fundamentally the same emission
sources that EPA intended to be
controlled in the1 proposed rule. EPA

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concluded that the revised approach is
easier and less costly to implement, for
both the affected industry and the
enforcement officials, since extensive
emission source testing is not required
to identify the vent and condensate
streams to be controlled.
3. Kraft Pulping Standards
  a. Applicability for Existing Kraft
Sources. In the December 17, 1993
proposal, all pulping system equipment,
with some exceptions, would have been
required to be controlled. The
exceptions were for deckers and screens
at existing sources and small vents
below specified volumetric mass flow
rates and mass loadings. EPA proposed
to require that treatment of all pulping
wastewater streams except those with
HAP concentrations below 500 ppmw
and flow rates below 1.0 liter per
minute.
  In the March 8,1996 supplemental
notice, the Agency presented potential
changes to the kraft mill standards.
These changes included specifically
naming equipment systems and pulping
wastewater subject to the standards. For
existing sources, the named equipment
systems in the supplemental  notice
included: the LVHC system, pulp
washing system, oxygen delignification
system, the pre-washer knotter and
screening system, and weak liquor
storage tanks. The subject wastewater
streams are the pulping process
condensates from the digester,
evaporator, turpentine recovery, LVHC
collection, and the HVLC collection
systems. EPA identified these systems
and condensates to be controlled based
on information presented in responses
to industry surveys available prior to
proposal and on updates and
clarifications to survey responses
submitted by the pulp and paper
industry after proposal. At proposal,
EPA did not have sufficient information
to define these equipment systems.
  At proposal, the Agency solicited
comments on its determination of the
control technology basis for the MACT
floor and for MACT. The proposed
MACT floor level of control at existing
kraft sources was 98 percent reduction
of emissions from the LVHC system,
pulp washing system,  and oxygen
delignification system. In considering
information received after proposal, the
Agency continued to have questions,
which were discussed with
representatives of the pulp and paper
industry, on the data provided in the
survey responses on weak liquor storage
tanks, the knotter and screening system,
and the decker system at existing
sources (Air Docket A-92-40, IV-D1-
101). In the March 8, 1996 notice, the
                          Agency requested further information
                          on whether to distinguish between types
                          or ages of weak liquor storage tanks,
                          methods and costs of controlling them,
                          and the level of control that represents
                          the MACT floor for the different tanks.
                          The Agency also requested data on the
                          type of controls present on knotter and
                          screening systems.
                            Commenters to the March 8 notice
                          provided additional information on the
                          kraft mills  which control vents from
                          knotter system, screen systems, decker
                          systems, weak liquor storage tanks, and
                          oxygen delignification systems. The
                          commenters noted that many of the
                          mills surveyed originally had
                          misinterpreted survey questions for
                          these systems. The commenters
                          concluded that the revised information
                          indicated that less than 6 percent of the
                          knotter and screen systems, decker
                          systems, and weak liquor storage tanks
                          were actually controlled; they
                          concluded, therefore, that the existing
                          source floor for these vents is no
                          control.. Additionally, the commenters
                          asserted that it would not be cost-
                          effective to go beyond the floor to
                          control weak liquor storage tanks
                          because tanks at existing sources would
                          not have the structural integrity to
                          withstand  a vacuum on them caused by
                          the vent collection system. The
                          commenters asserted that, to control
                          emissions, these tanks would either
                          need to be replaced or be retrofitted
                          with expensive add-on controls that
                          would not be cost-effective. One
                          commenter supported using age as a
                          means to indicate structural integrity
                          and, therefore, rule applicability for
                          weak liquor storage tanks. Several
                          commenters disagreed that age was an
                          appropriate indicator.
                          '  The Agency has evaluated the
                          information submitted by the .
                          commenters on the control level for the
                          knotter system.-screen system, decker
                          system, and weak liquor storage tanks.
                          Information submitted by the
                          commenters indicated that of the 597
                          weak liquor storage tanks in the survey
                          only 28 (4.7 percent) actually had
                          emissions  routed to a control device
                          (Air Docket A-92-40, IV-D1-106).
                          Some respondents had previously
                          included other types of controlled tanks,
                          such as washer filtrate tanks, in their
                          totals because EPA's original survey  did
                          not provide a definition of weak liquor
                          storage tanks. The Agency, therefore,
                          has concluded that the MACT floor
                          level of control for weak liquor storage
                          tanks at existing sources is no control.
                          While some tanks are controlled,
                          available information does not support
                          the supposition that age is a good
                          parameter for distinguishing structural
integrity. In addition, the Agency
evaluated the cost of going beyond the
floor to control weak liquor tanks. The
results of EPA's analysis indicated that
a significant cost would be incurred for
a limited emission reduction. This
analysis is presented in Chapter 20 of
the background information document
for the promulgated NESHAP.
Therefore, the Agency agrees with the
commenters that control beyond the
floor is not justified. Weak liquor tanks
at new sources are required to be
controlled.
  The Agency disagrees with the
comments that decker systems are not
controlled at the floor at existing
sources. Information supplied by the
pulp and paper industry indicates there
are 170 decker systems in mills
responding to EPA's industry survey
questionnaires. All the decker systems
are associated with bleached mills. Of
the 170 decker systems, 14 are
controlled (8 percent) (Air Docket A-
92-40, IV-B-16).
  The majority of decker systems
controlled at the floor (10 systems) are
associated with oxygen delignification
systems or are being used as an
additional stage of pulp washing. The
Agency believes that these types of
decker systems are operated similarly to
and have similar emissions as pulp
washers. Decker systems used in this
manner receive contaminated
condensates or filtrates that may be
recycled from other processes, such as
the oxygen delignification system or
combined condensate tanks. The
process water may have a HAP
concentration that would release
significant amounts of HAP to the air
from the air-water interface. The Agency
characterized the emissions from this
source to identify the types of .decker
systems with high emissions.
Information supplied in NCASI
technical bulletin 678 provided a '
relationship between air emissions and
methanol concentrations in process
water used in rotary vacuum drums.
EPA evaluated this relationship and
determined that decker controls and
higher HAP emission rates were
associated with deckers that used
process water with HAP concentrations
greater than or equal to 400 ppmw, or
that did not use fresh water or
"whitewater" from paperrriaiking
systems (Air Docket A-92-40, IV-B-22).
  Therefore, the Agency has determined
that it is appropriate to make a
distinction among types of decker
systems at existing sources for the
purpose of setting the MACT standard.
Decker systems at existing sources using
fresh water or' 'whitewater'' from
papermaking systems, or using process

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             Federal Register/Vol. 63, No. 72/Wednesday, April 15,  1998/Rules and Regulations      18521
 water with HAP concentrations less
 than 400 ppmw, are not required to be
 controlled. Decker systems at new
 sources are required to be controlled
 regardless of the HAP concentration in
 the process water introduced into the
 decker.
   EPA has reviewed available data on
 knotter and screen systems and has
 concluded that these systems are
 controlled sufficiently to establish a
 MACT, floor level of control, and also
 that control more stringent than the
 floor is not warranted. Data used to
 reach this'conclusion include survey
 responses from the 1992 voluntary
 survey, follow-up telephone surveys
 conducted by the National Council of
 the Paper Industry for Air and Stream
 Improvement (NCASI), and emissions
 data from the NCASI 16-mill study.
 Although the data indicate that many of
 these systems are currently controlled to
 some degree, the survey responses were
 not detailed enough in their equipment
 system descriptions and the test data
 were too limited for the Agency to use
 these two sources of information alone
 to develop the MACT control
 requirements. Because these equipment
 systems, nomenclature, and control
 configurations vary across the industry,
 the Agency decided that a HAP
 emissions limit would be the best way
 for mills to determine which systems
 would require control. EPA lacks
 sufficient data, however, to pinpoint
 any single value that represents the
MACT floor. Rather, based on the
 survey and test data, there are a range
 of values from which EPA could choose.
 EPA further considered the costs of
 control in choosing from this zone of
 reasonable values.
 : Of the  171 knotter systems reported in
the 1992 voluntary survey, 12 knotter
systems at 5 mills were reported as
 controlled and ducted into the
noncondensible gas (NCG) collection
system and another 49 knotter systems
at 23 mills were reported as having no
vents. NCASI followed up by telephone
surveys with these 28 mills (Air Docket
A-92-40, IV-D1-101,' IV-D1-112, IV-
D1 -114). The follow-up surveys
indicated a fair amount of misreporting
at these 28 mills. NCASI did not
resurvey for all 171 knotter systems.
Therefore, the following knotter system
floor determination assumes that the
mills riot resurveyed that originally
reported no knotter system controls did
not control any vents.
  From the 28 mills resurveyed, it was
determined .that six knotter systems or
3.6 percent (6/171) route all vents into
the NCG collection system; another two
knotter systems  or 1.2 percent (2/171)
route all knotter hood vents into the
 NCG collection system; another eight
 knotter systems or 4.7 percent (8/171),
 use only pressure knotters; and another
 two knotter systems or 1.2 percent (2/
 171) route all vents to the smelt
 dissolving tank scrubber. Industry
 collected data at seven pressure/open
 (also referred to as pressure/vibrating)
 knotter systems and found the methanol
 emissions to range from 0.005-0.07
 kilograms per megagram of oven-dried
 pulp (OOP) produced, and collected
 data at one pressure knotter system and
 found the methanol emissions to be
 0.0042 kilograms per megagram OOP
 produced. Emissions data are
 summarized in the Chemical Pulping
 Emission Factor Development
 Document (Air Docket A-92-40, IV-A-
 8). Because the pressure knotter system
 emissions were lower than the -
 emissions at the pressure/open systems,
 pressure systems  can be considered a
 type of controlled system. Therefore, 18
 or 10.5 percent (6+2+8+2 = 18/171)  of
 the knotter systems have some level of
 emissions control. The Agency believes
 that this estimate of the number  of
 knotter systems controlled may be
 somewhat low because it is uncertain
 how many of the mills not resurveyed
 may have had the lower emitting
 pressure systems.
   The 1992 voluntary MACT survey
 responses indicated that 96 screening
 systems out of the 199 reported are not
 vented. NCASI resurveyed by telephone
 41 of these 96 mills. Assuming that the
 55 mills not resurveyed look similar to
 the 41, the follow-up survey determined
 that seven percent (6/41 x 96/199) route
 their vents to the NCG collection system
•and 41 percent  (35/41 x 96/199) have
 closed screens that vent through
 auxiliary tanks. Therefore, 48 percent of
 the screening systems have some level
 of control.
   Industry collected data at one closed
"screen system and one open screen
 system. The closed screen system tested
 had methanol emissions of 0.004
 kilograms per megagram of OOP
 produced. The open screen system
 tested had methanol emissions of 0.22
 kilograms per megagram of ODP
•produced.
   The Agency considered how best to
 characterize the average emissions
 limitation achieved by the best
 controlled 12 percent of the knotter
 systems and screen systems given the
 wide variety of control scenarios present
 in the industry. Either collecting and
 controlling vents on an open system or.
 using closed equipment results in lower
 air emissions. The Agency decided to
 select the emissions limitation using the
 test data from, the  closed and open
 equipment systems. The Agency's
 decision is due in part to the fact that
 the technology basis for the effluent
 limitations guidelines and standards
 being promulgated in these Cluster
 Rules at 40 CFR Part 430 for bleached
 papergrade kraft and soda mills include
 closing.the screening areas and
 returning wastewater to the recovery   '
 system. Thus, it is likely that many
 mills will move toward wider use of the
 lower air emitting pressure systems.
   Because there is only one test data
 point for the pressure knotter systems'
 and that emissions value is similar to
 the low end of the range of data points
 for the pressure/open knotter systems,
 the Agency did not believe it would be
 appropriate to set the emission limit
 equal to the one pressure knotter
 system. Similarly, because there is only
 one test data point for closed screens,
 the Agency did not believe it would be
 appropriate to use that single data point
 to set the emission limit for screening
 systems. The Agency could have
 selected any emission limit within the
 range of all available data for knotters
 (i.e., 0.0042 to 0.07 kilograms per ,
 megagram of ODP produced) and
 screens (i.e., 0.004 to 0.22 kilograms per
 megagram of ODP produced). However,
 recognizing the limited data available,
 the Agency also considered the cost
 effectiveness of controlling these
 systems to aid in setting the emission
 limits within the range of reasonable
•values (Air Docket A-92-40, IV-B-21).
  Based on considering all available
 data, the final rule requires that existing
 kraft sources are required to control
 knotter systems with total mass
 emission rates greater than or equal to
 0.05 kilograms of HAP per megagram
 ODP produced. Existing kraft sources
 are required to control screening
 systems with total mass emission rates
 greater than or equal to 0.10 kilograms
 of HAP per megagram ODP produced.
 Since it is often difficult to distinguish
 between the knotter system and
 screening system at mills, a mill may
 also choose to meet a total mass
 emissions limit of 0.15 kilograms of
 HAP per megagram ODP produced
 across the knotting and screening
 combined system. New sources are
 required to control all knotter and
 screen systems, regardless of emissions
 level.
  b. Compliance Times for Kraft Mills.
 In the Marph 8, 1996 supplemental
 notice, the Agency discussed that it was
 considering allowing kraft mills an
 extended compliance time of five
 additional years (eight years total) for
 pulp washing and oxygen
 delignification systems, (61 FR at 9394-
 95). The notice discussed how the
 additional time would encourage the

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maximum degree of overall multi-media
pollution reduction and, in particular,
would avoid discouraging mills from
installing oxygen delignification
equipment to reduce water pollution.
The notice recognized the time
constraints mills would face in trying to
comply with both air and water rules
essentially at the same time and that too
short a compliance time could preclude
mills from considering pollution
prevention techniques with
considerable environmental benefits,
such as oxygen delignification and low-
flow washers. These technologies
reduce the amount of pollutants
discharged into the wastewater. The
March 8,1996 notice also solicited
comment on whether this compliance
extension should be extended only to
mills that commit to install these
technologies (if EPA were to decide not
to include that equipment as part of its
BAT model technology).
  Commenters supported the extension
of compliance time for pulp washing
and oxygen delignification systems at
existing sources. Several commenters
also requested that the compliance time
be extended for weak liquor tanks,
knotter and screening systems, and
other HVLC vent streams because
emissions from these sources will be
transported and controlled by the same
HVLC collection and incineration
system as the pulp washing and oxygen
delignification systems. The
commenters noted that extension of the
compliance period for all HVLC sources
also allows for proper consideration of
the full range of emerging innovative
water and air pollution control options.
Comments were not received on
whether to provide the compliance
extension only to mills that elect to
install more stringent control
technologies than necessary to comply
with the baseline BAT requirements.
  The Agency reviewed the comments
and agrees that vents included in the
HVLC system should be allowed a
similar compliance time as the pulp
washing and oxygen delignification
systems. The majority of emissions and
vent gas flow from equipment
associated with the HVLC vent streams
occur from the pulp washing system
and the oxygen delignification system.
Therefore, the design of the HVLC
collection and transport system would
be significantly influenced by these two
systems. The Agency determined if
.different compliance times were
provided for the components of the
HVLC system, an affected source would
expend significant amounts of capital to
control systems required to comply in
the three-year time frame. The source
would have to re-design the gas
                         transport and control devices five years
                         later to accommodate controlling the
                         washing system and oxygen
                         delignification system. This entire cost
                         could discourage the implementation of
                         low-flow washing systems and oxygen
                         delignification.
                           This would serve as an obvious
                         disincentive to installation of advanced
                         wastewater treatment technology since
                         mills would be understandably
                         reluctant to replace a newly installed air
                         pollution control system. Therefore,
                         EPA concluded that additional
                         compliance time is appropriate and
                         necessary for the remaining equipment
                         controlled by the HVLC collection and
                         transport system as well as the pulp
                         washing system and the oxygen
                         delignification system. See generally 61
                         FR at 9394-95. The final rule thus
                         allows affected sources to control all the
                         equipment in the HVLC system at kraft
                         pulping systems at the same time, not
                         later than April 17, 2006. A mill that
                         installs an oxygen delignification
                         system at an existing source after April
                         17, 2006 must comply with the
                         NESHAP upon commencing operation
                         of that system.
                           Regarding EPA's solicitation of
                         comments on providing a compliance
                         extension to all kraft mills, no negative
                         comments Were received. Therefore,
                         EPA has decided to extend the
                         compliance time for all kraft mills.
                           The final rule includes requirements
                         for kraft mills to submit a non-binding
                         control strategy report along with the
                         initial notification required by the part
                         63 General Provisions. The purpose of
                         the control strategy report is to provide
                         the Agency and the permitting authority
                         with the status of progress towards
                         compliance with the MACT standards.
                         The control strategy report must
                         contain, among other information, a
                         description of the emission controls or
                         process modifications selected for
                         compliance with the control
                         requirements and a compliance
                         schedule. The information  in the control
                         strategy report must be revised or
                         updated every two years until the mill
                         is in compliance with the standards.
                           c.  Condensate Segregation. The
                         proposed standards for process
                         wastewater would have required that all
                         pulping wastewaters that met the mass
                         emission rate and flow rate applicability
                         criteria had to be treated to achieve the .
                         specified control options. Comments
                         and data submitted to EPA indicated
                         that kraft mills typically steam stripped
                         the condensates from the digester,
                         turpentine recovery, LVHC, and HVLC
                         systems, and certain evaporator
                         condensates. The data  also indicated
                         that mills that use steam strippers also
practiced varying degrees of condensate
segregation in order to minimize the
flow rate and maximize the HAP mass
in condensate streams sent to treatment.
  In the March 8, 1996 Federal Register
supplemental notice, EPA presented a
discussion of condensate segregation
and included definitions for condensate
segregation and a segregated condensate
stream. Commenters on the March 8
notice supported the definitions for
condensate segregation and segregated
condensate stream. Commenters also
submitted additional information
suggesting definitions for condensate
segregation and segregated condensate
stream as well as options for
demonstrating compliance with the
condensate segregation requirements.
EPA evaluated the information and
included some of the concep>ts in the
final rule.
  The final rule states that the
condensates from pulping process
equipment at kraft mills must be treated
and allows a number of alternative
methods of complying with the
standards, all of which represent MACT.
The final rule also states that the entire
volume of condensate generated from
the named pulping process equipment
at kraft mills must be treated unless the
volume from the digester, turpentine
recovery, and weak liquor feed stages in
the evaporator systems can be reduced
using condensate segregation. If
adequate segregation (as specified jn the
rule) is performed, only the high-HAP
fraction streams from the digester
system, turpentine recovery system, and
the weak liquor feed stages in the
evaporator system and the non-
segregated streams from the LVHC and
HVLC collection systems must be sent
to treatment.
  Discussions with the pulp and paper
industry after the March 8, 1996
supplemental notice indicated that
some mills might not be able to achieve
the proposed 65 percent mass isolation
with their existing equipment even
though they are achieving high levels of
HAP removal  in the steam stripper
system (Air Docket A-92-40, IV-E-84).
Therefore; the final rule contains two
options for demonstrating compliance
with the segregation requirements. The
first option is to isolate at least 65
percent of the HAP mass in the total of
all condensates from the digester
system, turpentine recovery system, and
the weak liquor feed stages in the
evaporator system (condensate streams
from the LVHC and HVLC collection
systems are not segregated). The second
option requires that a minimum total
HAP mass from the high HAP
concentrated condensates from the
digester system, turpentine recovery

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              Federal Register /Vol. 63, No.  72/Wednesday. April 15,  1998/Rules and Regulations       18523
 system, and the weak liquor feed stages
 in the evaporator system and the total
 LVHC and HVLC collection system
 condensates be sent to treatment. The
 second option was included in the final
' rule because it achieves the same
 objective by sending a large enough
 mass to treatment to meet the floor-level
 control requirements.
  '. For a detailed explanation of the
 concept of condensate segregation
 readers are referred to the docket (Air
 Docket A-92-40, IV-D1-107).
   d. Clean Condensate Alternative. The
 proposed rule did not contain any
 provisions for emissions averaging.
 Industry comments on the proposal
 indicated support for incorporating an
 emission averaging approach in the final
 rule. After the public comment period,
 the pulp and paper industry submitted
 a comparison between an option
 developed by industry and the proposed
 MACT standards. The option formed the
 basis for the clean condensate
 alternative (CCA) in the final  rule. The
 CCA focuses on reducing HAP
 emissions throughout the mill by
 reducing the HAP mass in process water
 streams that are recycled to various
 process areas in the mill. By lowering
 the HAP mass loading in the recycled
 streams, less HAP will be volatilized to
 the atmosphere.
   The March 8, 1996 Federal Register
 supplemental notice presented a
 discussion of the industry's alternative
 (referred to as the "clean water
 alternative" in the notice). In  the March
 8 notice, EPA indicated that while the
 industry's concept was innovative,
 additional information would need to be
 submitted to the Agency to make the
 concept a viable compliance option,
> such as specific design parameters and
 data supporting the relationship
 between condensate stream HAP
 concentrations and HAP emissions from
 process equipment receiving the
 condensates.
  . Design specifications for the CCA
 were not available since no mills to date
 have implemented such a technology.
 However, the test data collected by the
 pulp and paper industry following the
 December 17, 1993 proposal included
 data on vent emissions and process
 water HAP concentrations that were
 used by industry to develop equations
 showing the relationship between HAP
 emissions from specific process.
 equipment (e.g., pulp washers) and the
 HAP concentrations present in the
 process water sent to the equipment.
   EPA evaluated these  data and
 concluded that sufficient relationship
 appears to exist between HAP
 concentrations in recycled process
 wastewater and HAP emissions from
 process equipment, such that the CCA ,
 has .the potential to achieve or exceed
 the requirements of the final standards.
 However, EPA has determined that the
 correlation equations developed by
 industry, because they were derived
 from small data sets, would not be
 sufficient for demonstrating compliance
 or equivalency with the final standards
 at a specific mill. Variability at a
 specific mill, such as types of process
 equipment, operating practices, process
 water recycle practices, and even type of
 wood pulped, can strongly influence the
 relationship between concentration in
 the process water and the process
 emissions.
  The final rule contains provisions for
 using the CCA as a compliance option
 to the kraft pulping standards for the
.subject equipment in the HVLC system.
 An owner or operator must demonstrate
 to the Administrator's satisfaction that
 the total HAP emissions reductions
 achieved using the CCA are equal to or
 greater than the total HAP emission
 reductions that would have been
 achieved by compliance with the kraft
 pulping system standards for equipment
 in the HVLC system. The baseline HAP
 emissions for each equipment system
 and the total of all equipment systems
 in the CCA affected source (which is the
 existing MACT affected source
 expanded to include the causticizing
 and papermaking systems) must be
 determined after compliance with the
 pulping process condensate standards;
 after consideration of the effects of the
 effluent limitations guidelines and
standards in 40 CFR part 430, subpart B;
 and after all other applicable
requirements of local, State, and Federal
 agencies or statutes have been  ,
 implemented. While engineering
assessments or test data may be used to
determine the feasibility of using the
CCA, only test data may be used to
demonstrate compliance with the kraft
pulping system standards using the
CCA.
  e. Biological Treatment. At proposal,
owners or operators using a biological
treatment system to comply with the
MACT requirements for pulping
wastewater would have been required to
measure the HAP or methanol
concentration in the influent and
effluent across the unit every 30 days
and to identify appropriate parameters
to be monitored to ensure continuous
compliance. The proposed standards
would have required that during the
initial performance test, mills collect
samples and analyze them using
Method 304 to calculate a site-specific
biorate constant. That constant, along
with the operating parameters
associated with the biological treatment
 system were to be entered into the
 WATER? (updated to WATERS since
 proposal) emissions model to
 demonstrate that the biological
 treatment system could achieve the
 treatment level required by the
 standards. Those operating parameters
 measured during the initial performance
 test were then to be monitored
 continuously to demonstrate
 compliance.
  EPA acknowledged at proposal that
 industry was collecting information on
 the performance of biological treatment
 systems and monitoring techniques.
 EPA also noted that trie industry was
 investigating the possibility of
 monitoring inlet and outlet soluble
 biochemical oxygen demand (BODs).
 EPA requested comments on applicable
 monitoring parameters for biological  .
 treatment systems and supporting data
 on biorates and corresponding
 parameters for monitoring..
  EPA received a number of comments
 oh testing and monitoring requirements
 for biological treatment systems. The
 industry submitted studies on biological
 treatment systems and on monitoring
 soluble BODS. Discussions were also
 held with the industry representatives
 on this issue.
  In general, commenters objected to
 the proposed requirements to use
 Method 304 to calculate the site-specific
 biorate constants. Commenters felt that
 the laboratory-scale simulation of the
 biological treatment unit, which is
 basically what Method 304 requires,
 does not  accurately reflect the biological
 degradation rates of the full-scale
 system. Cpmmenters also stated that
 according to data collected, performance
 testing to demonstrate .that biological
 treatment systems can meet the
 standards does not appear to be
 warranted given that methanol is highly
 biodegradable. Commenters further
 requested that if they had to conduct a
 performance test, they should also be
 permitted to use the inlet and outlet
 concentration procedures for calculating
 a site-specific biological degradation
 rate (biorate) constant as set forth in
 Appendix C of the Hazardous Organic
 NESHAP (HON). See  59 FR 19402 (April
 22,  1994): Commenters also objected to
 having to demonstrate continuous
 compliance with the operating
 parameters, pointing out that a
 parameter could be exceeded and the    .
biological treatment system could still
be meeting the standards.
 ' Following proposal, industry also
submitted data on soluble BODs across
biological treatment system units.
Industry stated that their data indicated
that as long as the biological treatment,
system was achieving at least 80 percent

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Federal Register/Vol. 63, No.  72/Wednesday, April 15, 1998/Rules  and Regulations
removal of soluble BODs, the biological
treatment system was operating
properly and that the unit would be
meeting the standards. However,
industry argued that soluble BODs
removal should not be a continuous
monitoring parameter that if exceeded,
would indicate a violation of the
standards. Rather, a mill should be
allowed to start measuring methanol
removal across the system to verify
compliance.
  The Agency considered the comments
and data received and agrees that the
provisions in Appendix C of the  HON
are an acceptable alternative to Method
304 for calculating site-specific biorate
constants. However, EPA disagrees with
the commenters on the issue of the need
to conduct performance testing. While
EPA agrees that methanol degrades
more rapidly than many compounds,
there are other HAPs present in the
condensate streams subject to the
standards, and biological treatment
systems can vary widely in their
operation and performance, depending
on their design, maintenance, and even
their geographical location. As such, the
final regulation retains the proposed
requirements for performance testing.
  EPA also became concerned that
allowing the use of methanol as a
surrogate for total HAP may not be
appropriate for this particular treatment
technology. Because methanol is one of
the most difficult HAPs to remove with
a steam stripper (the technology  on
which the standards are based), even
greater removals of total HAP would
occur when a steam stripper is used.
Thus, methanol is a reasonable
surrogate under such conditions. The
opposite is true for biological treatment
systems, where methanol is one of the
easier HAPs to degrade. As such, the
final regulation specifies that a total
HAP removal (not just methanol) of 92
percent be achieved by biological
treatment systems.
  EPA agrees with the cpmmenters that
soluble BODs is an appropriate
monitoring parameter for biological
treatment systems. However, EPA
disagrees with the commenters on their
position regarding the monitoring of
soluble BODs and operating parameters
for demonstrating continuous
compliance. After discussion with the
industry on this issue, EPA has
concluded that soluble BODs and
operating parameters are the most
appropriate means available for
monitoring to demonstrate continuous
compliance (A-92-40, IV-E-87). EPA
understands the concerns raised on this
point, and as such the final regulation
provides flexibility. The regulation
allows mills to establish, through
                          performance testing, their own range of
                          treatment system outlet soluble BODs
                          and operating parameter values to
                          monitor. The final rule also allows  '
                          owners and operators to demonstrate
                          compliance with the standard using the
                          WATERS model and inlet and outlet
                          samples from each biological treatment
                          system unit when the specified
                          monitoring parameters are outside of the
                          range established during the initial
                          performance test.

                          4. Sulfite Standards—Emission Limits
                          for Sulfite Pulping Processes
                            In the March 8, 1996 supplemental
                          notice (61 FR 9383), the Agency
                          presented potential changes to the
                          proposed standards for sulfite pulping
                          processes. EPA had proposed that all
                          pulping equipment at kraft, sulfite,
                          soda, and semi-chemical processes must
                          be enclosed and routed to a control
                          device achieving 98 percent reduction
                          in emissions. In the March 8 notice, the
                          Agency proposed that the MACT floor
                          level of control at existing sulfite
                          processes was control of vents from the
                          digester system,  evaporator system, and
                          pulp washing system. The MACT floor
                          level of control at new sulfite processes
                          would be control of the equipment
                          systems listed for existing sources, plus
                          weak liquor tanks, strong liquor storage
                          tanks, and acid condensate storage
                          tanks. In the March 8 notice, the Agency
                          discussed in detail its preliminary
                          determination that the sulfite standards
                          should instead apply to the total
                          emissions from specific named vents
                          and to any wastewater emissions
                          associated with air pollution control
                          devices used to comply with the rule.
                          For calcium-based sulfite pulping
                          processes, the new proposed emission
                          limit was 0.65 Ib methanol/ODTP and
                          the percent reduction was 92 percent.
                          For ammonium-and magnesium-based
                          sulfite pulping processes, the new
                          proposed emission limit was 1.10 Ib
                          methanol/ODTP, and the percent HAP
                          reduction was 87 percent. The Agency
                          developed applicability cutoffs based on
                          methanol because only methanol
                          emissions data were obtained for all of
                          the equipment systems and wastewater
                          streams considered for control at sulfite
                          mills. The test data from sulfite mills
                          also indicated that for the equipment
                          systems tested for other HAPs, methanol
                          comprised the majority of HAP
                          emissions. Therefore, the Agency
                          believes that the maximum control of
                          HAP emissions will be achieved by
                          controlling methanol as a surrogate.
                            Several commenters objected that the
                          proposed emission limits were not
                          appropriate because they were based on
                          data that only indicated possible levels
of methanol emissions and not a
rigorous assessment of emission rates.
The commenters contended that the
proposed emission limits were derived
from limited data which may not be
representative of the range of mills in
the industry; therefore, they argued, the
limits did not account for variability in
emissions and are not achievable. The
commenters provided the Agency with
emissions test data that illustrated
fluctuations in the methanol mass
emissions over an extended time period
due to variations in products and
process conditions.
  The Agency evaluated the  information
provided by the commenters and
subsequently agreed with the
commenters regarding process
variability at sulfite mills.  The Agency
determined the amount of variability
associated with a 99.9 percent
confidence level in the data supplied by
the commenters (Air Docket A-92-40,
IV-B-20). This amount of variability
(confidence interval), therefore, was
applied to the average emission limits
from the best controlled mills to
develop the final emission limit.
  For ammonium- and magnesium-
based sulfite pulping processes, the
final emission limit is 1.1 kilograms of
methanol per megagram of OOP
produced. After the close of the March
8,1996, Federal Register supplemental
notice comment period, additional
information was provided to the Agency
that indicated that the sodium-based
sulfite pulping process is in use at some
mills (A-92-40, IV-E-94). No emissions
information was available for this
process. However, the Agency
determined, that due to the similarities
in processes between calcium- and
sodium-based sulfite pulping processes,
the same limit developed for calcium-
based mills would be applicable to
sodium-based mills. For calcium- and
sodium-based sulfite pulping processes,
the final emission limit is 0.44
kilograms of methanol per megagram of
OOP produced. Because the variability
is incorporated into the mass emission
limit, these emission limits and
corresponding monitoring parameters
are never-to-be-exceeded values.

5. Soda and Semi-chemical Mill
Standards
  The proposed standards would have
required the  owners or operators of new
or existing kraft, semi-chemical, soda,',
and sulfite mills to comply with the
same emission standards. In the March
8, 1996 notice, EPA proposed to
subcategorize the pulp and paper
industry by pulping type and develop
different MAGT control requirements
for soda and semi-chemical mills based

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             Federal Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules and Regulations
                                                                    18525
on,emission characteristics. Existing
soda and semi-chemical mills would be
required to control the digester and
evaporator systems (LVHC system). New
soda and semi-chemical mills would be
required to control the LVHC and the
pulp washing systems. EPA solicited
comments on this proposed change.
  Information provided by the pulp and
paper industry in survey responses and
after proposal confirmed that the MACT
floor level of control at existing semi-
chemical mills is collection and control
of the LVHC system. The Agency
determined that it was not reasonable to
control other emission points at existing
semi-chemical mills (Air Docket A-92-
40, IV-B-12). Data indicated that the
best-controlled semi-chemical mills
combust LVHC system emissions and
emissions from pulp washing systems.
Therefore, the final rule requires that
existing semi-chemical mills control the
LVHC system, and new semi-chemical
mills cqntrol the LVHC and the pulp
washing systems.
  As discussed in the March 8, 1996
notice, the MACT floor level of control
for soda mills is no control. The Agency
has determined that HAP emissions
from soda mills are similar to kraft mills
(with the exception that TRS
compounds are not emitted from the
soda pulping process) and control of
LVHC system vents is technically
feasible and can be achieved at a
reasonable cost. The Agency has also
determined that controlling additional
vents at existing sources cannot be
achieved at a reasonable cost. However,
controlling the pulp washing system at
new soda mills can be achieved at a
reasonable cost (Air Docket A-92-40,
IV-B-12). Therefore, the final rule
requires that existing soda mills control
the LVHC'system, and new soda mills'
control the LVHC and the pulp washing
system.
6. Mechanical Pulping Mill, Secondary
Fiber Pulping Mill, Non-wood Fiber
Pulping Mill, and Papermaking System
Standards                          ,
  In the March 8, 1996 Federal Register
notice, EPA proposed standards for
pulping and bleaching processes at
mechanical pulping mills, secondary
fiber pulping mills, and non-wood fiber.
pulping mills. As discussed in the
proposal, EPA believes that there are no
air pollution control technologies in use
on these processes except for those
installed on bleaching systems using
chlorine. The March 8 notice proposed
no add-on controls for pulping systems
_(and the associated wastewater), ,,
papermaking systems, and nonchlorine
bleaching systems for these mills.  For
traditional bleaching systems using
 chlorine, the proposed control was
 based on the performance of caustic
 scrubbers. The proposal stated that EPA
 would continue to investigate the use of
 HAP chemicals in papermaking, the
 magnitude of HAP emissions, and the
 viability of chemical substitution to
 reduce HAP emissions from
 papermaking systems..
   Some commenters questioned EPA's ,
 proceeding with the rule in advance of
 the receipt of additional industry data
 that was being collected. The
 commenters cautioned that EPA did not
 have sufficient data on which to base a
 rule. Since the March 8, 1996 Federal
 Register proposal, EPA has received the
 results of the NCASI-sponsored testing
 program from these sources (A-92-40,
 IV-J-80 through IV-J-85). These data
 have been used in the  determination of
 the final standards for these sources in
 today's rule. EPA has concluded that
 sufficient data have been collected to
 include these sources in today's action.
   Commenters agreed with EPA's March.
 8, 1996 proposal for bleaching systems
, at these mills. Comments on the March
 8 proposal supported the conclusion
 that caustic scrubbers  are in use only on
 chlorine and chlorine  dioxide bleaching
 systems. Furthermore, information
 available to EPA indicate that non-wood
 pulping mills typically use chlorine or
 chlorine dioxide bleaching systems. For
 chlorine and chlorine  dioxide bleaching
 systems, EPA determined that scrubbers
 are used to control chlorinated
 compound emissions for process and
 worker safety reasons. Thus, the control
 achieved by this technology represents
 the floor for chlorine and chlorine
 dioxide bleaching systems at these mills
 and is the technological basis for the
• standard in today's rule. As stated in the
 December 17,1993 proposal, EPA
 analyzed more stringent controls, such
 as combustion of bleaching vent gases
 after caustic scrubbing, for bleaching
 systems at kraft, soda, and sulfite mills.
 EPA has'determined that these more
 stringent options are unreasonable
 considering cost and environmental
 impacts. Because of the operational
 similarities of the chlorine and chlorine
 dioxide bleaching systems at non-wood
 fiber mills to those at kraft, soda, and
 sulfite mills, EPA hasjcbncluded that
 combustion following caustic scrubbers
 is also not cost-effective at non-wood
 fiber mills. In addition, data available to
 EPA indicate that HAP emissions from
 chlorine bleaching systems at these
 mills are relatively low. In fact, the data
 show that the three largest non-wood
 pulping mills, of the ten currently in
 operation, use elemental chlorine in
 their bleaching systems and total HAP
 emissions from each of these three mills
is less than five tons of total HAP per
year (Air Docket A-95-31, IV-B-5).
  For chlorine and chlorine dioxide
bleaching systems at mechanical
pulping mills, secondary fiber pulping
mills, and non-wood pulping mills,
today's rule requires the same level of
control required for bleaching systems
at kraft, soda, and sulfite mills. Those
requirements are specified in § 63.445
(a)-(c) of today's rule. However,
§ 63.445 (d)-and (e) do not apply to
these mills since there are no effluent
limitation guidelines for control of
chloroform at mechanical, secondary
fiber, and non-wood fiber pulping mills.
Additional requirements for the control
of chloroform emissions, based on the
effluent limitation guidelines for best
available technology economically
achievable, are required in the standards
for bleaching systems for kraft, soda,
and sulfite mills. However, EPA is not
aware of any controls presently in place
or available for reducing chloroform air
emissions at mechanical, secondary
fiber, and nonrwood pulping mills.
Therefore, MACT is no control for
chloroform air emissions from bleaching
systems at.mechanical, secondary fiber,
and non-wood fiber pulping mills.
  Since the March 8 proposal, EPA has
also determined that while mechanical
pulping, secondary fiber pulping, and .
other non-wood pulpirtg mills do not
typically use chlorine or chlorine
dioxide bleaching, these mills may
brighten the pulp stock through the use
of hypochlorite and non-chlorine
bleaching compounds. However, data
available to EPA indicate that HAP .
emissions from these systems are
relatively low, and that none of the
bleaching systems that use hypochlorite
and non-chlorine compounds have
installed emission controls. Based on
these findings, EPA established the
MACT floor for bleaching systems at
these mills that use hypochlorite and
non-chlorine bleaching to be no control.
EPA considered going beyond the floor
and requiring HAP control through
incineration of vent streams for these
sources but determined that the
minimal level of HAP emission
reductions that would be achieved did
not justify going beyond the floor (Air
Docket A-95-31, IV-B-5).
  In the March 8, 1996 Federal Register
notice, EPA proposed no standards for
papermaking systems. The three
potential sources of HAP emissions
from papermaking systems are HAPs
contained in the pulp stock, HAPs
contained in the Whitewater, and HAPs
from additives and solvents.
Information available to EPA indicated
no papermaking systems are operating
with HAP controls; thus the floor level

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Federal Register/Vol. 63, No. 72/Wednesday,  April 15, 1998/Rules and Regulations
of control for papermaking systems is no
control. EPA evaluated two possible
control options for papermaking
systems: (1) Removal of HAPs from the
pulp stock and Whitewater before the
papermaking system; and (2) control of
papermaking system vent streams.
Analysis of these control options
showed that there are no demonstrated
methods for removing HAPs from the
pulp stock or Whitewater and that
applying HAP control to the vent
streams of papermaking systems is not
cost-effective (Air Docket A-95-31, IV-
B-8). Therefore, EPA is not requiring
HAP control beyond the floor.
  In the March 8. 1996 notice, EPA
indicated that it was investigating the
use of HAP-containing additives in
papermaking systems, the magnitude of
HAP emissions resulting from the use of
papermaking system additives, and the
viability of a MACT standard based on
additive substitution. EPA has
concluded that based on emission test  .
reports and a survey conducted on
additive use, additives do not contribute
significantly to HAP emissions (Air
Docket A-95-31, Item IV-B-6). The
amount of HAPs contained in additives
used by the paper industry for
papermaking systems is relatively low,
an estimated 236 tpy in 1995.
Furthermore, less than 20 percent of
HAPs contained in the additives is
emitted to the air. About 80 percent of
the HAPs remain on the paper or in the
Whitewater. Consequently, total annual
HAP emissions attributable to additives
are an estimated 50 tons per year,
industry-wide. In comparison to the
baseline emission level of 210,000 tons
per year of total HAPs from the entire
pulp and paper industry, the
contribution of HAPs from papermaking
system additives is negligible (Air
Docket A-95-31, IV-B-6).
  In a meeting between EPA and several
representatives of the Chemical
Manufacturers Association (CMA), CMA
stated that members have been working
to reduce HAP and solvent use in
papermaking system additives over the
past 15 years, even in the absence of
regulations. Reductions have been
achieved and CMA expects these efforts
to continue. CMA noted that HAP-free
alternatives may not be possible for all
types of additives, as some HAPs are
critical to product performance. EPA
believes that low-HAP additive
substitution is product-specific and it is
not clear from the available information
that substitution options are technically
feasible (Air Docket A-95-31, IV-E-5).
Therefore, EPA has concluded that a
MACT standard for papermaking
systems based on low-HAP additive
substitution is not warranted.
                           In the March 8, 1996 notice, EPA
                         proposed no standards for pulping
                         systems at mechanical, secondary fiber,
                         or non-wood fiber pulping mills.
                         Information available to EPA indicated
                         that no pulping systems at these mills
                         are operating with HAP controls.
                         Therefore, EPA has concluded that the
                         floor for pulping systems at these mills
                         is no control. EPA evaluated the
                         feasibility of going beyond the floor and
                         requiring HAP controls for these
                         sources. Specifically, EPA investigated
                         the feasibility of routing vent streams
                         from these pulping systems to a
                         combustion device for HAP control.
                         EPA determined that the cost of
                         combusting the vfent streams was not
                         justified by the HAP emission -
                         reductions achieved, and that requiring
                         HAP control beyond the floor was not
                         justified. Furthermore, pulping
                         chemical usage, which correlates with
                         HAP emission levels at kraft, semi-
                         chemical, soda, and sulfite pulping
                         mills, is much lower at non-wood fiber
                         and secondary fiber pulping mills and
                         minimal at mechanical pulping mills;
                         thus the potential for HAP emissions is
                         lower (Air Docket A-95-31, IV-B-7).,

                         7. Bleaching System Standards
                           In the proposed rule, bleaching
                         systems would have been required to
                         control all HAP emissions by 99 percent
                         using a caustic scrubber. In the March
                         8, 1996 supplemental notice, the
                         Agency revised the proposal for the
                         bleaching system requirements based on
                         information and comments received
                         after proposal. The new data indicated
                         that caustic scrubbing reduces
                         emissions of chlorinated HAP
                         compounds (except chloroform), but
                         does not control non-chlorinated HAP
                         emissions; The Agency determined that
                         no other option was feasible to control
                         non-chlorinated HAPs. EPA has
                         determined that reduction of chloroform
                         emissions through the use of additional,
                         add-on air pollution control technology
                         is cost prohibitive. The only feasible
                         option for controlling chloroform
                         emissions is process modification, such
                         as chlorine dioxide substitution and
                         elimination of hypochlorite use.
                           In the March 8 notice, the Agency
                         proposed to require chlorinated HAP
                         emissions other than chloroform to be
                         controlled by 99 percent (with chlorine
                         as a surrogate for chlorinated HAP)
                         based on the performance of a caustic
                         scrubber. As an alternative to the
                         percent reduction standard, the Agency
                         also proposed an emission limit of 10
                         ppmv chlorinated HAP at the caustic
                         scrubber outlet (with chlorine as a
                         surrogate for chlorinated HAP). The
                         Agency also solicited comments on
providing a mass emission limit
alternative to the percent reduction and
the outlet concentration standards.
  Commenters on the March 8, 1996
notice supported the changes to the
scrubber requirements in the proposed
rule. Commenters also expressed
concern that bleaching systems with
new low-flow vent systems would not
be able to meet either the percent
reduction or the outlet concentration
standards. Therefore, they asserted,
these standards would discourage the
use of new low-flow bleaching vent
technologies. Based on this concern, one
commenter advocated a chlorinated
HAP mass emission limit for bleaching
systems of 0.023 Ib of chlorinated HAP
(excluding chloroform) per ODTP
produced. The commenter claimed that
a mass emission limit would not
penalize new low-flow bleaching vent
systems.
  Based on available data, the Agency
has concluded that low-flow bleaching
vent systems can achieve the 99 percent
reduction and the 10 ppmv outlet
concentration requirements for total
chlorinated HAP (other than
chloroform). Based on a review of the
information provided by the commenter
and the available data on bleaching
system emissions, the Agency has
concluded that the commenter's
recommended mass emission limit of
0.023 Ib of chlorinated HAP (excluding
chloroform) per ODTP produced is too
high.  The Agency evaluated the
available data used to develop the
percent reduction and outlet
concentration requirements for
bleaching systems (A-92-40, H-I-24).
From this evaluation, the Agency
determined that a scrubber outlet mass
emission rate of 0.001 kg of total
chlorinated HAP (other than
chloroform) per Mg OOP produced
,(0.002 Ib/ODTP) would provide
reductions equivalent to 99 percent
reduction standard (A-92-40, IV-B-29).
The mass emission limit of 0.001 kg of
chlorinated HAP (other than
chloroform) per Mg ODP produced
represents a mass emission limit
achievable by all units that also
achieved 99 percent reduction of
chlorine. Furthermore, the available
data show that some of the scrubbers
achieving the 99 percent chlorine
reduction standard, and the 10 ppmv
outlet concentration limit, were also
operating on low-flow bleaching vent
systems.
  For the final rule, the Agency has
provided a mass emission limit option
for bleaching systems of 0.001 kg of
chlorinated HAP (excluding chloroform)
per Mg ODP produced (0.002 Ib/ODTP).
The Agency maintains that this option

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              Federal Register/Vol. 63, No. 727 Wednesday, April  15,  1998/Rules and Regulations      18527
  allows more flexibility for sources
  affected by this rule, .does not penalize
  bleaching systems operating with low-
  flow technology, and will provide
  reductions in chlorinated HAP
  emissions (other than chloroform)
  equivalent to the 99 percent reduction
  standard. Therefore, the final rule
  allows sources to comply with the
  bleaching system requirements if they'
  achieve an scrubber outlet mass
  emission limit at or below 0.001 kg of
  total chlorinated HAP (other than
  chloroform) per Mg ODP produced.
  Chlorine may be used as a surrogate for
  measuring total chlorinated HAP.
    After proposal, the Agency also
  evaluated the effect of process
  modifications on chloroform emissions.
  The results of this analysis indicated
  that the technology basis for MACT
  control of chloroform is complete
  chlorine dioxide substitution and
  elimination of hypochlorite as, a
  bleaching, agent. These process
  modifications were determined to
  reduce chloroform emissions
  significantly. At the same time, EPA was
  proposing complete chlorine dioxide
  substitution and hypochlorite
  elimination as the technology bases for
  the effluent limitations guidelines and
  standards under Subparts B and E (see
  58 FR at 66109-11, 14-15). Since the
  control technologies that would be
  installed to comply with effluent
  limitations guidelines and standards
  and MACT would likely be the same for
  these bleached papergrade mills, EPA .
  therefore proposed in the March 8
  notice that chloroform air emissions at
  bleached papergrade mills;be controlled
  by complying with the effluent
  limitations guidelines and standards
  applicable to those mills. No adverse
  comments were received on this
  proposal.
    In the March 8, 1996 notice, the
  Agency solicited comments on whether
  an alternative numerical air emission
  limit for chloroform (i.e., besides
  complying with the effluent limitations
  guidelines and standards) was needed.
  Some commenters contended that a
  numerical air emissions limit for
  chloroform would be unnecessary
,  because the effluent limitations
  guidelines and standards would achieve
  the requisite reductions. The Agency
  did not receive any indication of any
  benefit from a numerical air emission
., limit for chloroform. Additionally, the
  Agency did not have sufficient data and
  did not receive any further data after the
  March 8 notice to develop a numerical
  air emission limit (and hence is finding
.  that a numerical standard is not feasible
  for purposes of CAA § 112 (h)).
  Therefore, the final rule does not
 include a numerical air'emission limit
 for chloroform (see the proposal at 58
 FR 66142 for a discussion on setting
 MACT standards in a format other than
 an emission standard). The Agency is,
 however, providing an alternative
 compliance mechanism in the form of a
 work practice standard of complete
 substitution of chlorine dioxide for
 elemental chlorine and complete
 hypochlorite elimination—the technical
 basis for BAT. (EPA also notes that
 although the Agency's technical
 judgment is that compliance with BAT
 also will result in control of air
 emissions to reflect the MACT level of
 control, the Agency will continue to
 investigate whether this proves correct'
 as the rule is implemented.)"
   Because MACT for new sources is
 equivalent to MACT for existing
 sources, the new source MACT
 standards for bleaching systems require
 compliance with BAT/PSES
 requirements (or implementation of 100
 percent Substitution and elimination of
 hypochlorite). This requirement applies
 even if the mill or bleaching system also
 meets the definition of new source
 under the effluent guidelines limitations
 and standards, and thus is required to
 meet the more stringent new source
 effluent requirements of NSPS/PSNS.
 Although achievement of the NSPS/
 PSNS may result in installation of
 technologies that reduce effluent
 loading beyond what is achieved by 100
 percent .substitution and elimination of
 hypochlorite, EPA is not aware that -
 these advanced technologies will
 provide air emission reductions beyond
 what the BAT/PSES requirements will
 achieve.
   EPA notes that an affected bleached
 papergrade mill must comply with the
 existing source MACT requirements no
 later than April 16, 2001 even if the
 mill's existing Clean Water Act NPDES
 permit does not yet reflect the
 corresponding effluent limitations
 guidelines and standards because its
 existing terms have not expired or it has
 been administratively extended. Put
 another way, even if a mill's existing
 NPDES permit serves as a shield (until
 reissuance) against imposition of new
 limits based on new effluent limitations
 guidelines (see CWA Section 402(k)),
 the MACT requirement for bleached
 papergrade mills to control chloroform
 emissions through compliance with all
 parameter requirements in the effluent
 limitations guidelines and standards
 takes effect to satisfy the requirements
 of the Clean Air Act. Similarly, if a
, bleached papergrade mill's NPDES
 permit is reissued sooner than the
 expiration of the 3-year compliance
 schedule authorized for the chloroform
 MACT requirements and calls for
 immediate compliance with the BAT
 limitations, that deadline would prevail.
 The same principles will apply when
 effluent limitations guidelines and
 MACT standards are promulgated for
 dissolving grade mills. EPA's plans for
 promulgating MACT standards for these
 mills are discussed immediately below.
   An additional issue relating to
 compliance dates concerns bleaching
 systems at existing source papergrade
 kraft and soda mills which have elected,
 under the Clean Water Act portion of
 "this rule, to treat wastewater to levels
 surpassing baseline BAT requirements
 , (such as adding oxygen delignification
 prior to bleaching, and in some cases,
 engaging in additional reduction of
 process wastewater and further
 reductions in chlorinated bleaching
 chemicals used and bleaching system  .
 modifications than are necessary to
 meet BAT baseline limitations). As an
 incentive to make this election, EPA is
 not requiring participating mills to
 achieve compliance with the more
 stringent portions of the "Advanced
 Technology" BAT limitations for six,
 eleven, and sixteen years (for Tiers I, n,
 and HI, respectively) in order to afford
 these mills sufficient time to develop,
 finance, and install the Advanced
 Technologies. In light  of this, the
 Agency is concerned that requiring
 bleached papergrade kraft and soda
 mills to comply in three years with
 MACT standards based on process
 substitution of chlorine dioxide for
. elemental chlorine would discourage
 these mills from electing to participate
 in the Advanced Technology program.
 This is largely because a mill that
 implements process substitution before
 it installs oxygen or other extended
 delignification systems is likely to
 construct more chlorine dioxide
 generating capacity than it ultimately
 will need. A mill thus  compelled to
 invest first in process substitution may
 be very reluctant to abandon a portion
 of that investment soon afterwards in
 order to participate in  the voluntary
 incentives program.
   EPA also believes that requiring
 compliance in three years with a
 chloroform MACT standard based on
 baseline BAT for bleached papergrade
 kraft and soda mills would present
 similar disincentives to achieving
 greater effluent reductions. A mill in
 those circumstances will have made a
 substantially larger capital investment
 than it will need to control chloroform
 once its array of advanced water
 technologies is installed. Also,
 depending on the degree of process
 modifications the mill makes, the mill
 may need a much smaller scrubber for

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18528      Federal  Register/Vol. 63, No. 72/Wednesday,  April 15, 1998/Rules and Regulations
the non-chloroform chlorinated HAPs
and, in some cases, a scrubber may not
be needed at all to meet the MACT
standards for chlorinated HAP
concentration limit. Thus, a mill
otherwise interested in participating in
the Voluntary Advanced Technology
Incentives Program will find itself
diverting capital to environmental
controls that it ultimately will not need,
instead of employing that capital to
make more advanced process
modifications that will benefit both the
water and the air.
  Under these unusual circumstances
where imposition of MACT
requirements could likely result in
foregoing substantial cross-media
environmental benefits, EPA believes
that a two-stage MACT compliance
scheme is justified for existing sources
at bleached papergrade kraft and soda
mills that enroll in the water Voluntary
Advanced Technology Incentives
Program (see 61 FR 9394 for a similar
argument relating to compliance with
MACT for washers and oxygen .
delignification systems). The first stage
is an interim MACT of no backsliding—
which reflects the current level of air
emissions control. The second stage
requires compliance with revised MACT
based on baseline BAT requirements for
all parameters for bleached papergrade
kraft and soda mills. (The second stage
in effect revises MACT to reflect the
control technologies which will be
available at this later date. See CAA
§ 112 (d)(6).) The no-backsliding
provisions apply to the period from June
15,1998 until compliance with the
second-stage MACT standards is
required April 15, 2004. This two-step
alternative is available only to bleached
papergrade kraft and soda mills actually
making the binding decision to comply
with Tier I, n, or DI water limitations.
  EPA believes that providing these
mills six years to comply with secohd-
stage MACT (i.e., baseline BAT
requirements for all parameters) is an
appropriate and logical outgrowth of the
discussions set forth in the March 8,
1996 supplemental MACT notice (61 FR
9393) and the July 15.  1996
supplemental effluent guidelines notice
(61 FR 36835-58). In the March 8
notice, EPA solicited comments on its
preliminary findings that MACT for
chloroform air emissions should be
compliance with baseline BAT.
Commenters agreed with this
preliminary determination. In the July
15 notice, EPA set forth its vision of
more stringent BAT for mills that
voluntarily enter the Advanced
Technologies Incentives program. As
part of that voluntary program under the
water standards, EPA is promulgating a
 requirement that mills in Tiers n and ffl,
 at a minimum, meet all the limitations
 promulgated as baseline BAT no later
 than April 15, 2004. See Section IX.A.
 Thus, more stringent air emission
 controls than stage one MACT will
 likewise be available at this time since
 compliance with these interim BAT
 limitations will result in compliance
. with MACT. For Tier H and Tier HI
 mills, this means that the second stage
 MACT requirement is compliance with
 the baseline BAT limitations by April
 15, 2004. The same is the case for Tier
 I mills, even though under the water
 regulation Tier I mills will be required
 to achieve more stringent limitations at
 that time. EPA is defining MACT to be
 the baseline BAT limitations even in
 this situation because compliance with
 the more stringent AOX limitations and
 other requirements unique to Tier I are
 unnecessary to control chloroform
 emissions at these mills.
  EPA further believes that most plants
 likely to elect to comply with a tier
 option already control air emissions of
 chlorinated HAPs (both chloroform and
 other chlorinated HAPs) through
 application of the MACT technologies
 (process substitution for chloroform and
 caustic scrubbing for the remaining
 chlorinated HAPs). Thus, there will be
 some control of the emissions from
 these bleaching operations during the
 time preceding compliance with the
 second stage of MACT. To ensure that
 there is no lessening of existing
 controls; EPA also is promulgating a no
 backsliding requirement as an interim
 MACT—reflecting current control
 levels. During the extended compliance
 period, mills thus may not increase their
 application rates of chlorine or
 hypochlorite above the average rates
 determined for the three-month period
 prior to June 15, 1998.
  In the March 8 notice, the Agency
 proposed making a distinction between
 requirements for bleaching systems at
 papergrade and dissolving grade mills.
 The Agency solicited data concerning
 chloroform emissions from dissolving
, grade bleaching processes and requested
 comment on ari appropriate chloroform
 MACT for dissolving grade bleaching
 systems. Several commenters suggested
 that a separate MACT standard for
 chloroform be developed for bleaching
 systems at dissolving grade mills. Some
 commenters requested that the Agency
 defer chloroform control requirements
 for dissolving grade mills until effluent
 limitations guidelines and standards are
 established at those mills.
  As stated in the July 15, 1996  Federal
 Register notice (61 FR 36835), EPA is
 evaluating new data on the technical
 feasibility of reducing hypochlorite
 usage and implementing high levels of
 chlorine dioxide substitution on a range
 of dissolving grade pulp products.
 Therefore, EPA is deferring issuing
 effluent limitations guidelines and
 standards for dissolving grade mills
 until the comments and data can be
 fully evaluated. EPA expects to
 promulgate final effluent limitations
 guidelines and standards for dissolving
 grade subcategories at a later date.
  EPA has decided to delay establishing
 these MACT standards for chloroform
 and for other chlorinated HAPs for
 dissolving grade bleaching operations
 until promulgation of effluent
 limitations guidelines and standards for
 those operations, for the following
 reasons. With respect to the MACT
 standard for chloroform, first, as
 explained above and in the March 8
 notice, the control technology basis for
 the effluent limitations guidelines and
 standards and the MACT requirements
 will be the same. Second, at present, the
 Agency is unsure what level of chlorine
'substitution and hypochlorite use is
 achievable for dissolving grade, mills.
 Thus, although EPA has a reasonably
 good idea what the technology basis of
 MACT and effluent limitations
 guidelines and standards is likely to be
 for dissolving grade mills, the precise
 level of the standards remains to be
 determined. Consequently, at: present,
 EPA is unable to establish what the
 MACT floor would be for chloroform
 emissions from bleaching systems at
 these mills, and there is no conceivable
 beyond-the-floor technology to consider.
 EPA will make these determinations
 based on data being developed, and
 then promulgate for these mills effluent
 limitations guidelines and standards
 and, concurrently, MACT standards
 based on those effluent limitations
 guidelines and standards. Covered mills
 would therefore be required to comply
 with the MACT standards reflecting
 performance of the effluent limitations
 guidelines and standards no later than
 three years after the effective date of
 those standards, pursuant to CAA
 section 112(i)(3)(A).
  The basis for delaying MACT
 requirements for chlorinated HAPs
 other than chloroform (again, from
 dissolving-grade bleach operations only)
 differs somewhat. As noted above, the
 technology basis for control of these
 HAPs is use of a caustic scrubber.
 However, when plants substitute
 chlorine dioxide for chlorine and
 eliminate hypochlorite (in order to
 control chloroform emissions and
 discharges to water, as explained
 above), a different scrubber will be
 needed that can adequately control both.
 the chlorine dioxide emissions for

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             Federal Register/Vol.  63,  No. 72 /Wednesday, April 15,  1998/Rules and Regulations      18529
 worker safety reasons and the emissions
 of chlorinated^ non-chloroform HAPs.
 The Agency's concern (shared by the
 commenters who addressed this
 question) is that immediate control of
 the non-chloroform chlorinated HAPs
 could easily result in plants having to
 install and then replace a caustic
 scrubber system in a few years due to
 promulgation of effluent limitations
 guidelines and standards and MACT
 requirements for chloroform. This result
 would be an inappropriate utilization of
 scarce pollution control resources.

 8. Test Methods
  At proposal, the Agency proposed to
 require that Methods 308 and 26A be
 used to test for compliance with the
 provisions of the NESHAP. Method 308
 is used to measure methanol in the vent
 stream. Method 308 had not been
 validated using Method 301 at the time
 the NESHAP was proposed. Method
 26A,is used to measure chlorine in vent
 streams.
  At proposal, commenters objected to
 the rule referencing an unvalidated test
 method (Method 308). The commenters
 also contended that Method 26A should
 not be used for measuring chlorine in
 the bleaching system because chlorine
 dioxide, which is expected to be present
 in bleaching system vents, is listed as a
 possible interferant in Method 26A. The
.commenters suggested using a modified
 Method 26A developed by the pulp and
 paper industry.
  Since proposal, Method 308 was
 revised to incorporate suggestions made
 and data provided by representatives of
 the pulp  and paper industry.
  Since proposal, Method 308 has also
 been validated using Method 301
 validation criteria. The validation was
 conducted by the Atmospheric Research
 and Environmental Analysis Laboratory
 in-EPA's Office of Research and
 Development. The results of the
 validation were reported in the January
 1995 issue of the Journal of the Air and
 Waste Management Association. The
 Agency has also evaluated the
 commenters' claims regarding Method
 26A. The Agency agrees that chlorine
 dioxide is a" potential positive
 interferant to the method (i.e.,
 concentration measurement could
 potentially be higher than actual
 emissions). The final rule includes
 modifications to Method 26A (based on
 an NCASI method) to eliminate
 potential problems with chlorine
 dioxide interference.
 . In March 1997,. industry informed
 EPA that it had not used Method 305 to',
 obtain the methanol steam stripper
 performance data (which was used as
 the basis for the proposed pulping
 process condehsate standards). For the
 liquid sampling analysis, NCASI used a
 direct aqueous injection gas
 chromatography/fiame ionization
 detection (GC/FID) method described in
 NCASI Technical Bulletin No. 684,
 Appendix I. Consequently, the industry
• contends that Method 305 should not be
 specified in the final rule for
 determining compliance with the
 pulping process condensate standards.
 However, the NCASI test method has  •
 not been validated using EPA Method
 301 procedures and it is unlikely that
 the test method validation would be
 completed before promulgation of the  .
 MACT standard.
  The Agency has considered industry's
 argument and has decided to proceed
 with specifying Method 305 in the final
 rule to demonstrate compliance with the
 pulping process condensate standards.
 However, if the Agency approves the
 Method 301 validation procedures for
 NCASI's GC/FID test method, this
 method will be referenced as either an
 alternative or a replacement for Method
 305 (for determining methanol
 concentration only) with a
 supplemental Federal Register notice.
.EPA believes that this course of action
 will adequately address the industry's
 concerns. This decision was reached
 since the Method 301 validation
 procedures for NCASI's GC/FID method
 would likely be completed before kraft
 mills would have to demonstrate
 compliance with the pulping process
 condensate standards.
 9. Backup Control Devices and
 Downtime
  The proposal would have required
 emission limits for the NESHAP to be
 met at all times, except during periods
 of startup, shutdown, or malfunction.
 Allowance for control device or
 collection system downtime was not
 specified in the proposed rule, and the
 need for backup control devices was not
 addressed.
  Commenters asserted that EPA should
 recognize that control technologies on
 which the proposed rule was based are
 not designed to operate 100 percent of
 the time. Therefore, commenters
 requested downtime allowances to
 account for safety related venting and
 periods when the control.device is
 inoperable. Otherwise, the commenters
 asserted that costly backup control
 devices would be necessary to achieve
 compliance with the NESHAP at all
 times. They further contended that the
 environmental benefit for the additional
 cost associated with the backup controls
 would be minimal! Commenters
 recommended a one percent downtime
 for the LVHC system, four percent for
 the HVLC system, and ten percent for
 steam stripper systems. Commenters
 contended thatwhile. most of the LVHC
 systems had backup controls, very few
 of the HVLC systems had backup
 controls. Several commenters added
 that the Part 63 General Provisions do
 not address safety venting and
 downtime necessary for trouble-
 shooting. Another commenter
 contended that the Part 63 General
 Provisions already allow significant
 emissions and should not be further
 weakened.
   Since proposal, EPA has re-evaluated
 the need to incorporate downtime or
 excess emission allowances for LVHC,
 HVLC, and steam stripper systems into
 the final rule. Based on data submitted
 by the pulp and paper industry, EPA
 has concluded that some allowance for
 excess emissions is part of the MACT
 floor level of contr.ol. For the final rule,
 EPA established appropriate excess
 emission allowances to approximate the
 level of backup control that exists at the
 best-performing mills and the associated
 period of time during which no control
 device is available. The excess emission
 allowances in the final rule include
 periods when the control device is
 inoperable and when the operating
 parameter values established during the
 initial performance test cannot be
 maintained at the appropriate level.
   Based on an analysis of the public
 comments and the available data
 regarding excess emissions and the level
 of backup control in the industry, EPA
 has determined that an appropriate
 excess emissions allowance for LVHC
 systems would be one percent of th^
 operating hours on a semi-annual basis
 for the .control devices used to reduce
 HAP emissions. The best-performing
 mills achieve a one percent downtime
 in their LVHC system control devices.
 For control devices used to reduce
 emissions from HVLC systems, EPA has
 concluded that an appropriate excess
 emissions allowance would be four
 percent. The best-performing mills
 achieve a four percent downtime in the
 control devices used to reduce
 emissions from their HVLC system to
 account for flow balancing problems
 and unpredictable pressure changes
 inherent in HVLC systems. For control
 devices used to control emissions from
 both LVHC and HVLC systems, the
 Agency has determined that a four
 percent excess emissions .allowance is
 appropriate. This decision was made
" because the control device would be
 used for the HVLC system, which has
 the higher emissions allowance. For
 LVHC and HVLC system control ,
 devices, the excess emissions
 allowances do not include scheduled

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 18530      Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules and Regulations
maintenance activities that are
discussed in the Part 63 General
Provisions. The allowances address
normal operating variations in the
LVHC and HVLC system control devices
for which the equipment is designed.
The variations would not be considered
startup, shutdown, or malfunction
under the Part 63 General Provisions
(Air Docket A-92-40. IV-D1-103, IV-
Dl-110. IV-D1-115, IV-E-85, and IV-
E-88).
  The appropriate excess emissions
allowance for steam stripper systems
was determined to be 10 percent. The
allowance accounts for stripper tray
damage or plugging, efficiency losses in
the stripper due to contamination of
condensate with fiber or black liquor,
steam supply downtime, and
combustion control device downtime.
This downtime allowance includes all
periods when the stripper systems are
inoperable including scheduled
maintenance, malfunctions, startups,
and shutdowns. The startup, shutdown,
malfunction allowances are included in
the stripper allowances because
information was not available to
differentiate these emissions from
normal stripper operating emissions.
  Regarding the commenters' discussion
of whether the startup, shutdown, or
malfunction provisions of the General
Provisions would cover maintenance
and troubleshooting downtime, EPA has
taken public comment and is currently
revising the requirements of the General
Provisions. Among the changes to the
language, EPA intends to incorporate
safety-related venting requirements into
the General Provisions. However,
scheduled maintenance activities are
not considered by EPA to qualify for
excess emissions allowances. The start-
up, shutdown, and malfunction plan
specified in the General Provisions
should address the periods of excess
emissions that are caused by unforeseen
or unexpected events.
10. Equipment Enclosures, Closed-Vent
Systems, and Control Equipment, and
Condensate Conveyance System
  a. Requirements for Closed-Vent
Systems. At proposal, the Agency
required specific standards and
monitoring requirements for closed-vent
systems. The standards required: (1)
Maintaining a negative pressure at each
opening, (2) ensuring enclosure
openings that were closed during the
performance test be closed during
normal operation, (3) designing and
operating closed-vent systems to have
no detectable leaks, (4) installing flow
indicators for bypass lines, and  (5)
securing bypass line valves. Monitoring
requirements included visual
inspections of seal/closure mechanisms
and closed-vent systems, and
demonstrations of no detectable leaks in
the closed-vent system.
  Commenters to the proposed NESHAP
contended that visual inspections were
not necessary due to durability of the
materials used by this industry to
construct the collection system. In
addition, commenters contended that
leak detections were not necessary since
systems are typically operated at
negative pressure. The commenters also
opposed requirements for seals and
locks on bypass lines because the
bypass lines are installed for purposes
of personnel safety, equipment
protection, and to prevent explosions.
  The Agency evaluated the comments
and has decided to make the following
changes to the closed-vent system
requirements. The Agency agreed with
the commenters that most closed-vent
systems will be under negative pressure.
Any leaks, therefore, would pull air into
the collection system rather than release
HAPs to the atmosphere. Therefore, the
Agency revised the requirement for
demonstration of no detectable
emissions to apply only to portions of
the closed-vent system operated under
positive pressure. The Agency also
agreed that requiring a lock and key-
type seal on bypass lines would be
overburdensome and could potentially
pose a safety hazard. The intention of
the requirements was to prevent
circumvention of the control device by
venting directly to the atmosphere. The
Agency believes that this assurance can
be achieved using car seals or seals that
could easily be broken, to indicate when
a valve has been turned. Proper
recordkeeping is also necessary to
demonstrate proper operation.
Therefore, the Agency revised the
bypass line requirements to allow the
use of car seals but require log entries
recording valve position, flow rate, and
other parameters. The Agency has
modified the enclosure requirements to
allow for short-term openings for pulp
sampling and maintenance.
  The final rule retains the visual
monitoring requirements. The
requirements are necessary to ensure
proper operation of collection systems
and can be conducted at a reasonable  '
cost.
  b. Concentration Limit for
Combustion Devices and Design
Incinerator Operating Parameters. At
proposal, the NESHAP would have
required vent streams to be controlled in
a combustion device that achieves 98
percent reduction of HAPs or outlet
HAP emission concentrations of 20
ppmv corrected to three percent oxygen.
Alternatively, mills could comply with
 the control requirements by routing vent
 streams to a design incinerator operating
 at 1,600 °F and a residence time of 0.75
 seconds, or to a boiler, lime kiln, or
 recovery furnace.         '
   Commenters on the proposed rule
 objected to the 20 ppmv limit at a three
 percent oxygen correction feictor. Some
 commenters claimed that incinerator
 exhaust streams in the pulp and paper
 industry have an oxygen content in
 excess of 10 percent. Therefore, if the
 outlet concentration was corrected to
 three percent oxygen, the concentration
 level would not be achievable. Some
 commenters recommended increasing
. the correction factor to 10 percent
 oxygen.
   The 20 ppmv limit represents the
 performance that is achieved on low
 concentration streams by a well
 designed combustion device. This limit
 was based on previous EPA studies (Air
 Docket A-79-32, Et-B-31). The three
 percent oxygen correction factor at
 proposal was based on stream
 characteristics of other industries, such
 as the synthetic organic chemical
 manufacturing industry. The three
 percent correction factor has been used
.on many previous standards for
 controlling organic pollutants: EPA re-
 evaluated the three percent correction
 factor to ensure that it is appropriate for
 the pulp and paper industry. Test data
 supplied by the industry confirmed
 their comments that the oxygen content
 of the incinerator flue gas is typically
 greater  than ten percent at pulp and
 paper mills. Based on the industry data
 and the thermodynamic  models, EPA
 changed the oxygen correction factor to
 ten percent (Air Docket A-92-40, IV-B-
 19). Therefore, the final rule allows
 combustion devices to be in.compliance.
 if they reduce HAP concentrations to 20
 ppmv at ten percent oxygen.
 Information supplied by the pulp and
 paper industry indicates that many of
 the existing incinerators meet this limit.
   Commenters on the proposed rule'
 objected that the requirements for the
 design incinerator were too stringent
 and that equivalent control could be
 achieved at lower temperatures. Many
 commenters requested that the Agency
 allow incinerators meeting the operating
 conditions in the kraft NSPS of 1,200 °F
 and 0.5 seconds residence time to be
 used.for the NESHAP.
   EPA has decided not to change the
 proposed design incinerator operating
 parameters for the NESHAP because the
 parameters are necessary to meet the
 MACT floor. EPA would first like to
 clarify that the final rule does not limit
 owners or operators of incinerators to
 operate at the specified temperatures
 and residence times. Any control device

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             Federal Register/Vol.  63,  No. 72/Wednesday.  April 15, 1998/Rules and Regulations      18531
that is demonstrated to achieve 98
percent destruction of HAPs will
comply with the rule. Any thermal
oxidizer which reduces HAP emissions
to a concentration of 20 ppmv at ten
percent oxygen will also comply with
the rule. The 98 percent destruction
requirement represents the control level
achieved by well-operated combustion
devices. The 20 ppmv limit represents
the performance achieved by well-
operated combustion devices on low
concentration vent streams.
  Second, EPA has made this part of the
rule as flexible as possible while still
achieving a level of control reflecting
MACT. In the December 17,  1993
proposal and in this final rule, EPA
developed compliance alternatives in
order to reduce the compliance testing
burden. The compliance alternatives
(i.e., operating thermal oxidizers at a
temperature of 1,600 °F and a residence
time of 0.75 seconds) were developed to
ensure that the thermal oxidizers
perform at a level that would meet the
destruction efficiency requirements. The
operating parameters are based on
previous Agency studies that show that
these conditions are necessary to
achieve 98 percent destruction of HAPs.
However, the NSPS operating
parameters (1,200 °F and 0.5 seconds
residence time) do not destroy HAPs to
this extent.
  The purpose of the kraft NSPS was to
reduce emissions of TRS compounds.
EPA has evaluated the temperature and
residence time required by the NSPS to
determine whether the NSPS
temperature and residence time are
sufficient to achieve 98 percent
reduction of HAPs. EPA's  analysis
indicates that while the NSPS
requirements are sufficient to achieve 98
percent destruction of TRS compounds,
kinetic calculations for methanol (the
majority of HAP in pulping vent gases)
show that the NSPS criteria will not
achieve 98 percent reduction of HAPs
(Air Docket A-92-40, IV-B-18).
Additionally, EPA evaluated incinerator
performance data submitted by industry
(Air Docket A-92-40, IV-J-33). The
data indicated that the NSPS operating
parameters were not sufficient for
achieving 98 percent destruction of .
methanoL This conclusion was reached
by EPA since the operating conditions
(i.e., temperature and residence time)  of
the incinerators that, achieved 98
percent methanol destruction were .
greater than the levels specified in the
kraft NSPS. Therefore, the NSPS
specifications will not meet the
requirements of MACT for new and
existing sources.
  c. Condensate Collection System. In
the December 17, 1993 proposal, EPA
proposed to require pulping process
condensate collection systems to be
designed and operated without leaks.
EPA proposed that all tanks, containers,
and surface impoundments storing
applicable condensate streams were
required to be enclosed and all vent
emissions must be routed to a control
device by means of a closed-vent
system. A submerged fill pipe would
have been required on containers and
tanks storing an applicable condensate
stream or any stream containing HAP
removed from a condensate stream. All
drain systems that received or managed
applicable condensate streams would
have been required to be enclosed with
no detectable leaks and any HAP
emissions from vents were required to
be routed to a control device. Several
commenters on the proposed pulp and
paper NESHAP contended that the .
proposed requirements were overly
burdensome and, in some cases,
unnecessary.
  After the pulp and paper NESHAP
was proposed, the Agency promulgated
a separate rulemaking in 40 CFR Part 63,
Subpart RR (National Emission
Standards for Individual Drain
Systems). This rule established emission
control, inspection and monitoring, and
recordkeeping and reporting
requirements for individual drain
systems. The individual drain system
requirements specify that air emissions
from collection systems must be  :
controlled using covers or seals, hard-
piping, or venting of individual drain
systems through a closed-vent system to
a control device or a combination of
these control options. The emission
control techniques specified in the
individual drain system standard (i.e.,
covers/seals and vent combustion) are
common techniques that are applicable
to a variety of wastewater collection
systems, regardless of the type of .
process that produced the wastewater
streams.
  EPA compared the collection system
requirements contained in the proposed
pulp and paper NESHAP with the
individual drain system requirements in
subpart RR. Since the subpart RR  ,
requirements are consistent with the
intent of the proposed standards, EPA
concluded that the requirements of
subpart RR constitute MACT for the
pulp and paper industry. The control
costs presented in the "Pulp, Paper, and
Paperboard Industry-Background
Information for Promulgated Air
Emission Standards, Manufacturing
Processes at Kraft, Sulfite, Soda, Semi-
Chemical, Mechanical, and Secondary
and Non-wood Fiber Mills, Final
EIS"(EPA-453/R-93-050b) were based
on industry estimates for hard-piping
systems. The Agency has concluded that
these costs would be the same or greater
than would be needed for complying
with the requirements of subpart RR.
  The final pulp and paper NESHAP
references 40 CFR Subpart RR for the
standards for individual drain systems
for the pulping process condensate
closed collection system. The Subpart
RR standards provide uniform language
that simplifies compliance and
enforcement.
  The final rule requires tanks to be
controlled as at proposal, but containers
and surface impoundments are not
required to be controlled. Public
comments indicated that containers are
not used in the pulp and paper industry.
The Agency's intention in the proposed
rule was not to require surface
impoundments to be controlled, except
when used as part of the condensate
collection system. After further review
of this issue, the Agency has determined
that mills do not use and are unlikely
to use surface'impoundments as part of
their closed collection system for
condensate streams and therefore that
the language on control of surface
impoundments does not need to appear
in the rule.

11. Interaction With Other Rules
  a. Prevention of Significant
Deterioration/New Source Review (PSD/
NSR). To comply with the MACT
portion of the pulp and paper cluster
rule, mills will route vent gases from
specified pulping and condensate
emission points to a combustion control
device for destruction. The incineration
of these gases at kraft mills has the
potential to generate sulfur dioxide
(SOa) and, to a lesser degree, nitrogen
oxides (NOx). The emission increases of
SOa and NOx may be of such magnitude
to trigger the need for preconstruction
permits under the nonattainment NSR
or PSD program (hereinafter referred to
as major NSR).
  Industry and some States have •
commented extensively that in
developing the rule, EPA did not take
into account the impacts that would be
incurred in triggering major NSR.
Commenters indicated that major NSR
would: (1) Cost the pulp and paper
industry significantly more for
permitting and implementation of
additional SO2 or NOx controls than
predicted by EPA; (2) impose a large
permitting review burden on State air
quality offices; and  (3) present
difficulties for mills to meet the
proposed NESHAP compliance
schedule of 3 years due to'the time
required to obtain a preconstruction
permit. Industry commenters have
stated that the pollution control project

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18532      Federal Register/Vol. 63, No. 72/Wednesday, April. 15, 1998/Rules  and Regulations
(POP) exemption allowed under the
current PSD policy provides inadequate
relief from these potential impacts and
recommended including specific
language in the pulp and paper rule
exempting MACT compliance projects
fromNSR/PSD.
  In a July 1,1994 guidance
memorandum issued by EPA (available
on the Technology Transfer Network;
see "Pollution Control Projects and New
Source Review (NSR) Applicability"
from John S. Seitz, Director. OAQPS to
EPA Regional Air Division Directors),
EPA provided guidance for permitting
authorities on the approvability of PCP
exclusions for source categories other
than electric utilities. In the guidance,
EPA indicated that add-on controls and
fuel switches  to less polluting fuels
qualify for an exclusion from major
NSR. To be eligible to be excluded from
otherwise applicable major NSR
requirements, a PCP must on balance be
"environmentally beneficial," and the
permitting authority must ensure that
the project will not cause or contribute
to a violation  of a national ambient air
quality standard (NAAQS) or PSD
increment, or adversely affect visibility
or other air quality related values
(AQRV) in a Class I area, and that off-
setting reductions are secured in the
case of a project which would result in
a significant increase of a non-
attainment pollutant. The permitting
authority can make these
determinations outside of the major
NSR process.  The 1994 guidance did not
void or create an exclusion from any
applicable minor source preconstruction
review requirements in an approved
State Implementation Plan (SIP). Any
minor NSR permitting requirements in a
SIP would continue to apply, regardless
of any exclusion from major NSR that
might be approved for a source under
the PCP exclusion policy.
  In the July 1,1994 guidance
memorandum, EPA specifically
identified the combustion of Organic
toxic pollutants as an example of an
add-on control that could be considered
a PCP and an  appropriate candidate for
a case-by-case exclusion from major
NSR For the purposes of the pulp and
paper MACT rule, EPA considers that
combustion for the control of HAP
emissions from pulping systems and
condensate control systems to be a PCP,
because the combustion controls are
being installed to comply with NtACT
and will reduce emissions of hazardous
organic air pollutants. EPA also
considers the reduction of these
pollutants to represent an
environmental benefit. However, EPA
recognizes that the incidental formation
of SOa and NOx due to the destruction
of HAPs will occur. Consistent with the
1994 guidance, the permitting authority
should confirm that, in each case, the
resultant emissions increase would not
cause or contribute to a violation of a
NAAQS, PSD increment, or adversely
affect an AQRV.
  The EPA believes that the current
guidance on pollution control projects
adequately provides for the exclusion
from major NSR of air pollution control
projects in the pulp and paper industry
resulting from today's rule. Such
projects would be covered under minor
source regulations in the applicable
state implementation plan (SIP), and
permitting authorities would be
expected to provide adequate safeguards
against NAAQS and increment
violations and adverse impacts on air
quality related values in Federal Class I ,
areas. Only in those cases where
potential adverse impacts cannot be
resolved through the minor NSR
programs or other mechanisms would
major NSR apply.
  The EPA recognizes that, where there
is-a potential for an adverse impact,
some small percentage of mills located
near Class I PSD areas might be subject
to major NSR, i.e., the permitting
authority determines that the impact or
potential impact cannot be adequately
addressed by  its minor NSR program or
other SIP measures. If this occurs, there
is a question whether MACT and NSR
compliance can both be done within the
respective rule deadlines. EPA believes,
however, that the eight year compliance
deadline provided in the final MACT
rule for HVLC kraft pulping sources
substantially mitigates the potential
scheduling problem. The equipment
with the eight year compliance deadline
are the primary sources of the additional
SOa and NOx emissions. The additional
time should be sufficient to resolve any
preconstruction permitting issues.
  While the Agency believes that eight
years is sufficient for kraft mills with
HVLC systems to meet permitting
requirements, industry has raised
concerns that there could be a potential
problem for a few mills in Class I
attainment areas that are required to
comply with the final rule in three
years. The PCP exemption and extended
compliance schedule may not resolve
all NSR conflicts for every mill.
Although too  speculative to warrant
disposition in this rule, EPA is alert to
this potential problem and will attempt
to create implementation flexibility on a
case-by-case basis should a problem
actually occur.
  Commenters requested that the PCP
exclusion also be expanded to actions
undertaken at mills that enroll in the
Voluntary Advanced Technology (AT)
 Incentives Program in the effluent
 limitations guidelines and standards
 portion of today's rule. In the July 23,
 1996 notice on changes to the NSR
 Program (61 FR 38250), EPA solicited
 comments on the appropriate scope of
 the PCP exclusion. EPA also solicited
 comments in the July 15, 1996
 supplemental.pulp and paper effluent
 guidelines notice (61 FR 36857) on
 whether advanced water pollution
 control technologies implemented by
 the pulp and paper industry should be
 eligible for an exclusion from major
 NSR and if so, whether the exclusion
 should be implemented under the
 provisions of the PCP exclusion under
 the NSR proposed regulations. In the
 context of these notices, EPA received
 several comments in favor of extending
 the PCP exclusion to multi-media
 activities, such as those that would be
 undertaken for the Voluntary Advanced
 Technology Incentives Program but
 received little information on
 appropriate criteria for determining the
, relative benefits of reduced v/ater
 pollution to potential coincident
 increases in air pollution.
   The Agency believes that, depending
 on the control technologies selected by
 a mill, the potential exists for an overall •
 environmental benefit to result from
 control strategies implemented under
 the Voluntary Advanced Technology
 Incentives Program. However, unlike
 the MACT rule in today's action, where
 the controls that would be installed to
 reduce hazardous air pollutants are
 fairly well known and the potential
 pollutant tradeoffs within the same
 environmental media are fairly well
 understood, the Agency is less certain
 about the controls that might be
 installed to comply with this Voluntary
 Advanced Technology Incentives
 Program and the potential pollutant
 tradeoffs that may occur across
 environmental media. Therefore, while
 the Agency is continuing to consider'
 extending this PCP status to activities
 undertaken to implement the Voluntary
 Advanced Technology Incentives
 Program, the Agency is not extending
 that status in today's action because the
 Agency currently lacks sufficient
 information to establish a process and
 set of criteria by which a determination
 could be made as to whether these
 advanced control technologies result in
 an overall environmental-benefit at
 individual mills that participate in this
 program. The Agency intends to
 continue discussions with stakeholders
 on a process and set of criteria by which
 a determination could be made as to the
 appropriateness of extending the PCP
 exclusion to controls installed at

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             Federal Register/Vol.  63.  No. 72/Wednesday. April 15, 1998/Rules and Regulations      18533
 individual mills to comply with the
 Voluntary Advanced Technology
 Incentives Program. Because the control
 technologies that could be installed to
 implement the Voluntary Advanced
 Technology Incentives Program may
 vary significantly from one mill to.
 another, mills that want controls
 implemented within the context of the
 Voluntary Advanced Technology
 effluent program to be considered PCP
 will likely need to make a site-specific
 demonstration that such controls result
 in an overall environmental benefit.
 When a mill would need to make such
 a demonstration would depend upon
 that particular mill's compliance
 timeline—dictated by the AT Incentives
 Tier to which they commit and the  time
 necessary to get applicable permits
 approved. While it is not possible at this
 time to identify the criteria .the Agency
 would use for approving a PCP
 exclusion, the Agency would not
 consider projects which result in any
 increases in emissions of highly toxic
 compounds to be an acceptable
 candidate PCP. For example, the Agency
 believes it would not be
. environmentally acceptable to give  the
 PCP exclusion to an activity which
 results in a chlorinated material being
 sent to a boiler that would result !in the
 release of a chlorinated toxic air
 pollutant. The Agency also believes" that
 the public should be provided an
 opportunity to review and comment on
 mill-specific cases where a PCP
 exclusion is being considered for these
 advanced water technologies,
 particularly if there would be a
 potentially significant emissions
 increase of criteria air pollutants such as
 SO2orNOx.                        '
  Since mills must declare within one
 year of promulgation of the cluster rules
 whether they will participate in the
 Voluntary AT Incentives Program, the
 Agency is aware that mills would like
 to know whether a mechanism exists
 whereby they may apply for a PCP
 exclusion among the many factors that
 may influence their participation in this
 incentives program. In order for the
 Agency to proceed further on this issue,
 the Agency again is requesting that  ,
 interested stakeholders submit
 information on the types of control
 technologies that could be installed
 under the Voluntary AT Incentives  ',
 Program along with information on the
 type and potential magnitude of
 collateral air pollutant increases that
 may occur at mills. The Agency requests
 information from stakeholders that
 could be useful for developing a process
 by which mills would apply for the PCP
 exclusion and for setting forth criteria
for determining whether an activity
performed under the Voluntary AT
Incentives Program qualifies for the PCP
exclusion. Given the potentially varying
control strategies that could be adopted
by participating mills, the Agency also
requests information that may be useful
in assessing whether generic guidance
on when a PCP exclusion may be
appropriate should be set forth within
the context of the NSR Reform effort or
whether NSR determinations should
more appropriately be made in the
context of mill-specific applications.
The EPA needs this information within
60 days of the publishing of this notice
to evaluate the information and proceed
with this issue in a useful time period
for mills to make their decisions on
participation in the Voluntary AT
Incentives Program. Stakeholders
should submit information on .this topic
directly to Ms. Penny Lassiter, Emission
Standards Division (MD^IS), U.S.
Environmental Protection Agency,
Research Triangle Park, NC 27711.
  b. Resource Conservation and
Recovery Act (RCRA)/Boilersand
Industrial Furnaces (BIF). One of the
options for  controlling emissions from
pulping process condensates is to steam
strip HAPs, primarily methanol, from
kraft pulping process condensate
streams. After the HAPs are removed,
the vent gas from the steam stripper is
required to  be sent to a combustion
device for destruction. Several
commenters pointed out that some mills
may choose to  concentrate the methanol
in the steam stripper yent gas, using a
rectification column, and bum the
condensate as a fuel.
  However, the concentrated methanol
condensate that would be derived from
the steam stripper'overheads may be
identified as hazardous waste under the
Resource Conservation and Recovery
Act (RCRA) because it exhibits the
ignitability characteristic. See 40 CFR
261.21. Boilers burning such a
hazardous waste fuel would ordinarily
be required to comply with emission
standards set out in 40 CFR Part 266
Subpart H (the so-called BIF regulation,
i.e., standards for boilers and industrial
furnaces burning hazardous waste).
Several commenters recommended
incorporating a "clean fuels" exclusion
into the pulp and paper NESHAP so that
the condensate can be burned for energy
recovery without the combustion unit
also being subject to the RCRA rules.
The "clean fuels" exclusion is a
recommendation from EPA's Solid
Waste Task Force to allow recovery of .
energy from waste-derived fuels that are
considered  hazardous only because they
exhibit the ignitability characteristics
and do not contain significant
concentrations of HAP. For background
information see 61 FR at 17459-69
(April 19, 1996),-where EPA proposed
such an exclusion based on similarity of
waste-derived fuels to certain fossil
fuels.                       -
  The Agency proposed to exclude this
practice from RCRA regulation in the
March 8, 1996 notice and solicited
comments on this determination (61 FR
at 9396). All of the comments supported
granting this exemption. As stated in the
notice, EPA does not believe that RCRA
regulation of the rectification and
combustion of the condensate is
appropriate or necessary. The     ,
rectification practice would not increase
environmental risk, would reduce
secondary environmental impacts, and
would provide a cost savings. Moreover,
the burning of condensate will not
increase the potential environmental
risk over the burning of the steam
stripper vent gases prior to       .
condensation. (See generally 61 FR at
9397.) Finally, consideration of risk
would more appropriately be handled as
part of the section 112(f) residual risk
determination required for all sources
after implementation of MACT •
standards. For these reasons, EPA will
exclude specific sources at kraft mills
that burn condensates derived from
steam stripper overhead vent gases from
RCRA, including condensates from the  •
steam stripper methanol rectification
process. The scope of this exclusion is
limited to that requested by
commenters, combustion at the facility
generating the stream. (Limitation of the
scope of the exclusion to on-site burning
also eliminates questions about whether
RCRA regulation is needed to assure
proper tracking and transport of the
material.)   -•                       ,

B. Effluent Limitations Guidelines and
Standards                       '  '
1. Subcategorization
  The Subcategorization scheme being
promulgated today for effluent
limitations guidelines and standards for
the pulp, paper, and paperboard
industry replaces the sub'categorization
of this industry that dates back to 1974.
EPA's reasons for combining and
reorganizing the 26 old subcategories
(formerly found in Parts 430 and 431)
into 12 new subcategories are set forth
below, in the proposal, see 58 FR at
66098-100, and in "Selected Issues
Concerning Subcategorization" (DCN
14497, Volume 1).
  In reorganizing Part 430 to comport
with the new Subcategorization scheme,
EPA has reprinted in their entirety the
current effluent limitations guidelines
and standards applicable to the newly

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 18534      Federal Register/Vol. 63, No.  72/Wednesday, April 15, 1998/Rules and Regulations
formed subcategories. The only
substantive changes to the current
effluent limitations guidelines and
standards are the BAT limitations,
NSPS. PSES, PSNS, and best
management practices being
promulgated today for the Bleached
Papergrade Kraft and Soda subcategory
(subpart B) and the Papergrade Sulfite
subcategory  (subpart E). In addition,
EPA is promulgating the Voluntary
Advanced Technology Incentives
Program applicable to subpart B. EPA is
making no changes to the BPT and BCT
limitations previously promulgated for
what are now subparts B and E.
Similarly, EPA is retaining the NSPS
promulgated in 1982 in new Subparts B
and E for new sources that commenced
discharge that met the 1982  NSPS after
June 15.1988 but before June 15,1998
provided that the new source was
constructed to meet those standards.
EPA is also retaining, without
substantive revision, the new source
pretreatment standards previously
promulgated for subparts B and E for
facilities constructed between June 15,
1988 and June 15,1998.
  These limitations and standards are
recodified at subparts B and E in the
form of segments corresponding to the
old subcategorization scheme. (In re-
codifying these limitations and
standards, EPA has simplified the text
introducing the limitations tables, but
has not changed the former regulations'
substance.) Direct discharging mills
currently subject to the 1982 NSPS
remain subject to those standards until
the date ten years after the completion
of construction of the new source or
during the period of depreciation or
amortization of such facility, whichever
comes first. See CWA section 306(d).
After such time, the BAT limitations
promulgated today apply for toxic and
nonconventional pollutants. Limitations
on conventional pollutants will be
based on the formerly promulgated
BPT/BCT limitations corresponding to
the BPT/BCT segment applicable to the
discharger or on the 1982 NSPS for
conventional pollutants, whichever is
more stringent
  EPA is making no substantive changes
to the limitations and standards
applicable to any other subcategory.
EPA will promulgate new or revised
effluent limitations guidelines and
standards, as appropriate, for the
remaining subcategories at a later date.
See Table H-2. Until then, the
previously promulgated effluent
limitations guidelines and standards
remain in effect.
  EPA is making one non-substantive
revision in each subpart. Where the
existing regulation includes  a narrative
statement describing the procedure to
calculate the effluent limitations
guidelines and standards for non-
continuous dischargers, e.g., 40 CFR
430.13, 430.15, 430.62(a)-(d), 430.65
(1996 ed.), EPA has performed the
calculations and presented the results in
tables. The resulting effluent limitations
and standards are the same; this
procedure was done simply to
streamline the regulation and to make it
easier to apply for the permit writer.
  In order to ensure that any facilities
that would not have been subject to the
previous subparts will not inadvertently
be subject to limitations and standards
set forth in the newly redesignated
subparts, EPA is using the applicability
language of each previously
promulgated subpart to define the
applicability of the newly redesignated
subparts that consolidate them. For
example, rather than promulgate the
applicability statement proposed for
subpart C, see 58 FR at 66199, EPA has
instead codified as a single applicability
statement, the applicability statements
of former subparts A, D and V, which
new subpart C now comprises. See 40
CFR 430.30.
  The Agency received comments that
the groupings comprising the new
subcategories are unreasonable because
they purportedly ignore distinctions
among facilities that affect their ability
to implement the technologies that form
the basis of the effluent limitations
guidelines and standards promulgated
for subparts B and E. Thus, some
commenters asserted, these facilities
would be unable to meet the same limits
as other mills in the same new
subcategory. EPA considered these
comments in detail where they involved
mills subject to new effluent limitations
guidelines and standards promulgated
today in order to determine whether the
groupings of the mills into subparts B
and E were appropriate. In response to
these comments, EPA segmented
subpart E. See section VI.B.6.a. When
EPA develops the final regulations for
the remaining subcategories, EPA
similarly will consider if it is
appropriate to fine-tune these initial
groupings to better respond to material
differences between facilities.
  EPA also acknowledges that the
subcategorization scheme promulgated
today was developed based on data
received in the "1990 National Census
of Pulp, Paper, and Paperboard
Manufacturing Facilities," and that
there have been changes in the industry
since that data gathering effort. Because
the resubcategorization has no
substantive effect on any mill other than
those with production in subparts B and
E (for whom revised effluent limitations
 guidelines and standards are
 promulgated today), EPA believes that
 changes in the industry affecting the
 remaining subparts are best addressed
 when EPA makes the .decision whether
 to revise the regulations for those
 subcategories.
  a. Bleached Papergrade Kraft and.
 Soda subcategory. The Bleached
 Papergrade Kraft and Soda subcategory,
 for which regulations are. promulgated
 in this rulemaking at 40 CFR part 430
 subpart B, encompasses the former
 subparts G (market bleached kraft), H
 (BCT bleached kraft), I (fine bleached
 kraft), and P (soda). EPA has retained
 the applicability statements associated
 with those former subparts. See 40 CFR
 430.20. EPA intends for this merged
 subcategory to apply to mills that
 chemically pulp wood fiber using a  kraft
 method with an alkaline sodium
 hydroxide and sodium sulfide cooking
 liquor to produce bleached papergrade
 pulp and/or bleached paper/paperboard.
 It also applies to mills that chemically
 pulp wood fiber using a soda method
 with an alkaline sodium hydroxide
 cooking liquor. Principal products of
 bleached kraft wood pulp include
 papergrade kraft market pulp,
•paperboard, coarse papers, tissue
 papers, uncoated free sheet, and fine
 papers, which include business, writing,
 and  printing papers. Principal products
 of bleached soda wood pulp are fine
 papers, which include printing, writing,
 and  business papers, and market pulp.
  b. Papergrade Sulfite subcategory. .
 The Papergrade Sulfite subcategory, for
 which regulations are promulgated in
 this  rulemaking, is defined as 40 CFR
 part 430 subpart E and encompasses
 former subpart J (papergrade sulfite-
 blow pit wash) and subpart U
 (papergrade sulfite-drum wash). EPA
 has retained the applicability statements
 associated with those former subparts.
 See 40 CFR 430.50. EPA intends for  this
 merged subcategory to apply to mills
 that chemically pulp wood fiber using a
 sulfite method, with or without
 brightening or bleaching, using an
 acidic cooking liquor of calcium,
 magnesium, ammonium, or sodium
 sulfites to produce bleached papergrade
 pulp and/or bleached paper/paperboard.
 The provisions of this merged subpart
 apply regardless of whether blow pit
 pulp washing techniques or vacuum or
 pressure drum pulp washing techniques
 are used.

 2. BPT/BCT for the Bleached Papergrade
 Kraft and Soda Subcategory and the
 Papergrade Sulfite Subcategory
  a. Background. EPA proposed to
 revise effluent limitations for the
 conventional pollutants biochemical

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              Federal Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules and Regulations      18535
 oxygen demand (BODs) and total
 suspended solids (TSS) based on the
 best practicable control technology
 currently available (BPT) for all of the
 proposed subcategories, including
 Bleached Papergrade Kraft .and Soda
 and Papergrade Sulfite. As presented in
 the proposal, 58 FR at 66105, EPA
 highlighted several controversial issues
 concerning the BPT limitations, their
 calculation, and their interpretation.,
 EPA also presented a rationale and
 methodology and identified related.
 controversies for establishing
 limitations based on the best
 conventional pollutant control
 technology (BCT).
   b. BPT. In December 1993, the Agency
 proposed to revise BPT for conventional
 pollutants for subparts B and E and
, specifically solicited comment on that
 proposed decision. See 58 FR at 66105-
 06. In response, EPA received comments
 claiming that EPA lacks the legal
 authority to revise BPT once BPT
 effluent limitations guidelines have
 been promulgated. EPA also received
 other comments asserting that the Clean
 Water Act compels EPA to revise BPT.
 Although the Agency believes that it has
 the statutory authority to revise BPT, the
 Agency also believes that it has the
 discretion to determine whether to
 revise BPT effluent limitations
 guidelines in particular circumstances.
 The question of EPA's legal authority is
 not relevant here, however, because
 EPA has decided, in the exercise of its \
 discretion, that it is not appropriate to
 revise BPT effluent limitations
 guidelines for conventional pollutants
 for subparts B and E at this time. Instead
 the current BPT effluent limitations
 guidelines for conventional pollutants
 will continue to apply to these
 subcategories.
   EPA bases this decision on its
 determination that the total cost of,
 applying the proposed BPT model
 technology is disproportionate in this
 instance to the effluent reduction
 benefits to be achieved. See CWA
 section 304(b) (1) (B).. When setting BPT
 limitations, EPA is required under
 section 304 (b) to perform a limited cost-
 benefit  balancing to make sure that costs v
 are not  wholly out of proportion.to the
 benefits achieved. See, e.g.,
 Weyerhaeuser Co. v. Costle, 590 F.2d
 1011 (D.C. Cir. 1978). It therefore
 follows that EPA is authorized to
 perform such balancing when
 determining whether to revise existing
 BPT limitations.
   Mills in subparts B and E have
 significantly reduced their loadings of
 BODs and TSS since promulgation of
 the current BPT effluent limitations
 guidelines in 1977. Although additional
 removals could be achieved if BPT were
 revised, EPA has determined for subpart
 B and, separately, for subpart E that the
 costs of achieving that incremental
 improvement beyond either the current
 BODS and TSS limitations or the current
 long term average for BOD5 and TSS are
 disproportionate to the benefits. A
 single mill might have to spend as much
 as $ 17.4 million in order to upgrade to
 advanced secondary treatment. See the
 Supplemental Technical Development
 Document, DCN 14487. These
 expenditures are particularly significant
 when one considers the cumulative
 costs of this rulemaking; Therefore; EPA
 has decided not to revise BPT
 limitations for conventional pollutants
 for mills in the Bleached Papergrade
 Kraft and Soda subcategory and the
 Papergrade Sulfite subcategory at this  >
 time.                        >    ._
  EPA's decision not to revise BPT
 limitations for subpart B at this time is
 also informed by the Agency's long-term
 goal for this industry: that the industry
 will qontinuously improve its
 environmental performance primarily
 through sound capital planning and
 expenditures. EPA has determined that
 this interplay between potentially more
 stringent revised BPT limitations and
 the industry's long-term environmental
 improvement is an appropriate factor to
 be considered .in this rulemaking with
 respect to BPT. See CWA section
 304(b)(l)(B). It is also consistent with
 the Clean Water Act's overarching
 objective, which calls upon EPA to
 implement the statute's provisions with
 the goal of eliminating the discharge of
 pollutants into the Nation's waters. See
 CWA Section 101(a). In this rulemaking,
 EPA has determined that the baseline
 regulatory requirements—effluent
 limitations guidelines and standards
 and air emissions standards—are only
 one component of the framework to
 achieve long-term environmental goals.
 EPA believes that the mills of the future
 will approach closed loop operations,
 thus achieving minimal impact on the
 aquatic environment. To promote this,
 EPA is promulgating an incentives
 program to encourage subpart B mills to
 implement pollution prevention leading
 to the mill of the future. See Section IX.
  EPA believes that near-term
 investments to achieve more stringent
 BPT effluent limitations for
 conventional pollutants would divert
 limited resources away from
 environmentally more preferable
 investments in advanced pollution
 prevention technologies. Thus, EPA is
 concerned that revising BPT effluent
limitations guidelines at this time could
discourage mills from achieving even
greater environmental results through  "
 the Voluntary Advanced Technology
 Incentives Program. Moreover, EPA
 estimates that, even without revising
 BPT limitations for subpart B, loadings
 of BODs, for example, will decline by
 approximately 20 percent, when mills
 meet the baseline BAT limitations and
 best management practices requirements
 promulgated today. Incidental removals
 are even greater for subpart B mills
 implementing more advanced'
 technologies (e.g., loadings of BOD5 are
 estimated to decline by approximately
 30 percent at the Tier I level; and EPA
 expects substantially greater reductions
 from Tiers n and HI). See Table IX-1.
 EPA also.expects comparable TSS
 loading reductions to occur. See the
 Voluntary Advanced Technology
 Incentives Program Technical Support
 Document, DCN 14488. In short,
 because sufficient additional removals
 of conventional pollutants from subpart
 B mills can be obtained without revising
 BPT at this time, EPA has determined .
 that, on balance, the incremental
 benefits attributable to revised BPT
 limits do not justify the comparatively
 high costs associated with achieving
 those limits. For these additional
 reasons, EPA has decided not to revise
 BPT for conventional pollutants for
 mills in the Bleached Papergrade Kraft
 and Soda subcategory at this time.
  Finally, if additional removals of
 BODs anal TSS are needed to protect
 particular receiving waters, CWA
 section 301 (b) (1) (C) requires mills on a
 case-by-case basis to meet more
 Stringent limitations as necessary to
 achieve applicable water quality
 standards.
  For the foregoing reasons, therefore,
 EPA has decided, in the exercise of its
 discretion, that it is not appropriate to
 revise. BPT limitations for conventional
 pollutants for subparts B and E at this
time. Rather, the BPT effluent
 limitations guidelines promulgated for
former subparts G, H, I, and P (now
Bleached Papergrade Kraft and Soda
 subcategory, subpart B) and former  ,
 subparts J and U (now, Papergrade
 Sulfite subcategory, subpart E) remain
 in effect. These limitations are
recodified at subparts B and E  in the
form of segments corresponding to the
 old subcategorization scheme.  See 40
 CFR 430.22 and 430.52.
  c. BCT Methodology. In considering
whether to promulgate revised BCT
limits for subparts B and E, EPA
 considered whether there are
technologies that achieve greater
removals of conventional pollutants
than the current BPT effluent
limitations guidelines, and whether
those technologies are cost-reasonable
according to the BCT cost test. At

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18536
Federal Register/Vol. 63, No.  72/Wednesday, April  15, 1998/Rules and Regulations
proposal, EPA presented two alternative
methodologies for developing BCT
limitations. The first assumed that BPT
limits would be revised in the final
rulemaking; the alternative analysis was
based on the assumption that BPT limits
would not be revised. See 58 FR at
66106-07. The principal difference
between the two methodologies
involved the BPT baseline that EPA
would use to compare the incremental
removals and costs associated with the
candidate BCT technologies. Because
the Agency is not revising BPT, EPA
used the second alternative to determine
whether to revise the current BCT limits
for subparts B and E.
  d. BCT Technology Options
Considered. For the Bleached
Papergrade Kraft and Soda subcategory,
EPA identified two candidate BCT
technologies for the final rule. These
were: (i) The technology required to
perform at the level achieved by the best
90 percent of mills in the subcategory;
and (ii) the technology required to
perform at the level achieved by the best
50 percent of mills in the subcategory.
  The Papergrade Sulftte subcategory
was not divided into segments for the
purpose of conducting a BCT analysis
because EPA found that treatability of
BODs and TSS in the wastewater
generated by the three segments does
not differ. EPA identified one candidate
BCT technology for the Papergrade
Sulfite subcategory. This was the
technology required to perform at the
average level achieved by three mills in
the subcategory with at least 85 percent
of their production in the segment.
Development of candidate BCT
technology options based on the best 90
and 50 percent of mills, which EPA
used for the Bleached Papergrade Kraft
and Soda subcategory, is not
appropriate for this subcategory because
there are only 11 mills in this
subcategory and only four of these have
at least 85 percent of their production in
the subcategory. The wastewater
treatment performance of three of these
mills was determined to reflect BCT
level performance for the Papergrade
Sulfite subcategory. EPA did not
consider the wastewater treatment
performance of the fourth mill to be
representative of the subcategory as a
whole because it treats wastewater from
liquor by-products manufactured on
site, and thus is unique among
papergrade sulfite mills.
  e. Results of BCT Analysis. EPA
evaluated the candidate BCT
technologies for both the Bleached
Papergrade Kraft and Soda subcategory
and the Papergrade Sulfite  subcategory
and concluded that none of the •
candidate options passed the BCT cost
                          test. For more details, see the
                          Supplemental Technical Development
                          Document, Section 12, DCN 14487.
                          Therefore, at this time, the Agency is
                          not promulgating more stringent BCT
                          effluent limitations guidelines for the
                          newly constituted subparts B and E.
                          Rather, the BCT limitations promulgated
                          for former subparts G, H, I, and P (now
                          Bleached Papergrade Kraft and Soda
                          subcategory, subpart B) and former
                          subparts J and U (now Papergrade
                          Sulfite subcategory, subpart E) remain
                          in effect. These limitations are
                          recodified at subparts B and E in the
                          form of segments corresponding to the
                          old subcategorlzation scheme. See 40
                          CFR 430.23 and 430.53.

                          3. Pollutant Parameters for BAT/NSPS/
                          PSES/PSNS
                           a. Dioxin, Fwan, and Chlorinated
                          Phenolic Pollutants. EPA is
                          promulgating effluent limitations
                          guidelines and standards for 2,3,7,8-.
                          TCDD ("dioxin"), 2,3,7,8-TCDF
                          ("furan"), and 12 specific chlorinated
                          phenolic pollutants for subparts B and
                          E (except for those mills regulated by
                          TCP limitations). For a discussion of
                          EPA's rationale for regulating these
                          parameters, see the proposal, 58 FR at,
                          66102-03 and the proposal Technical
                          Development Document (EPA 821-R-
                          93-019). For a discussion of EPA's pass-
                          through analysis regarding these
                          pollutants, see Section VLB.5.c(2) and
                          VI.B.6.d.
                           b. Volatile Compounds. EPA is
                          promulgating effluent limitations
                          guidelines and standards for chloroform
                          for subpart B. For a discussion of EPA's
                          rationale for regulating chloroform, see
                          the proposal, 58 FR at 66102 and the
                          proposal Technical Development
                          Document (EPA 821-R93-019). EPA is
                          not promulgating effluent limitations
                          guidelines and standards for chloroform
                          for subpart E at this time. For a
                          discussion of EPA's pass-through
                          analysis regarding chloroform, see
                          Section VI.B.5.c(2). For the reasons set
                          forth below and in the Supplemental
                          Technical Development Document, DCN
                          14487, EPA is not promulgating effluent
                          limitations guidelines and standards for
                          the discharge of acetone, methylene
                          chloride, and methyl ethyl ketone
                          (MEK). EPA received no adverse
                          comments in response to its preliminary
                          determination, presented in the July
                          1996 Notice of Availability, 61 FR at
                          36839, not to regulate these pollutants.
                           EPA has reviewed data from both
                          hardwood and softwood mills
                          employing a variety of bleaching
                          processes in an effort to identify factors
                          that contribute to the formation of
                          acetone, methylene chloride, and MEK
in the bleach plant. The bleaching
processes evaluated included bleaching
using elemental chlorine, BAT Option A
(elemental chlorine-free (ECF) bleaching
using 100 percent chlorine dioxide),
BAT Option B (oxygen delignification
plus ECF bleaching using 100 percent
chlorine dioxide), ECF bleaching using
ozone, and totally chlorine-free
bleaching. The ranges of loadings for
each pollutant were similar across the
different bleaching technologies and for
both hardwood and softwood mills. The
average loadings for these pollutants do
not exhibit a performance trend with
regard to the bleaching technologies.
  In the EPA/Industry long-term study,
methylene chloride was found to be a
sample- and laboratory-contaminant in
certain cases. Among the more recent
data reviewed  by EPA, methylene
chloride was detected in the bleach
plant effluent at ten percent of the
sampled mills. Where detected,
methylene chloride was present at low
concentrations. Therefore, because
methylene chloride is infrequently
detected, because its formation  .
processes are not fully understood, and
because the cases in which it is detected
are often attributed to sample and
laboratory contamination, EPA has
decided not to promulgate effluent
limitations guidelines and standards for
methylene chloride in this rulemaking.
  EPA had proposed limitations for
acetone and MEK based on limited data
indicating that these parameters may be
affected by the technology options being
considered. EPA has decided not to
promulgate effluent limitations
guidelines or standards for these
parameters because additional data have
shown that this is not the case.
Moreover, EPA believes that the
limitations and new source performance
'standards being promulgated today for
adsorbable organic halides for subpart B
mills will ensure that mills will
continue to operate their biological
wastewater systems at levels necessary
to achieve very high removals of these
pollutants, thus obviating the need for
separate limitations.
  In view of the efficacy of biological
wastewater treatment in removing
acetone and MEK and the fact that
process changes have no effect on the
levels at which they are generated, EPA
is not convinced that these pollutants
pass through POTWs. Therefore, EPA is
also not setting pretreatment standards
for acetone or MEK for subpart B at this
time.
  With respect to papergrade sulfite
mills, EPA expects that, once
promulgated, the limitations and
standards for AOX based on, among
other things, efficient biological

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              Federal Register/Vol. 63, No. 72/Wednesday,  April 15, 1998/Rules  and Regulations
                                                                    18537
  treatment, will ensure that treatment
  systems are operated at levels necessary
  to obviate the need for separate
  limitations for acetone and MEK.
  Therefore, EPA is deferring its decision
  on whether to regulate acetone and MEK
  until that time.
    c. Adsorbable Organic Halides (AOX).
  EPA is establishing BAT limitations,
  NSPS, and pretreatment standards for
  the control of adsorbable organic halide
  (AOX) discharges from mills in the
  Bleached Papergrade Kraft and Soda
  subcategory. EPA is also establishing
  BAT limitations, NSPS, and
  pretreatment standards to control AOX
  discharges from mills in the calcium-, •
  magnesium-, or sodium-based segment
  of.the Papergrade Sulfite subcategory.
  For a discussion of EPA's pass through
  analysis for AOX discharges from these
  mills, see Sections VI.B.5.c(2), VI.B.6.d,
  and the Supplemental Technical
  Development Document, Section 8, DCN
  14487. As discussed in more detail in
  those sections, EPA is not setting
  effluent limitations guidelines and
  standards for AOX for other mills in
  subpart E at this time.
    AOX is a measure of the total
  chlorinated organic matter in
  wastewaters? At pulp and paper mills,
  almost all of the AOX results from
 " bleaching processes. Even though
•  dioxin and furan are no longer
  measurable using today's analytical
  methods at the end of the pipe at many
  mills, the potential for formation of
  these pollutants continues to exist at
  pulp and paper mills as long as any '
  chlorine-containing compounds
  (including chlorine dioxide) are used in
  the bleaching process. The record.
  demonstrates a correlation between the
  presence of AOX and the amount of
 • chlorinated bleaching chemical used in
  relation to the residual lignin in the
  pulp (expressed as the kappa factor).
  The record further shows that there is a
  correlation between the kappa factor
  and the formation of dioxin and furan.
  Therefore, EPA concluded that reducing
  AOX loadings will have the effect of
  reducing the mass of dioxin, furan, and
  other chlorinated organic pollutants
  discharged by this industry. For further
  discussion of EPA's rationale for
  regulating AOX, see the Supplemental
  Technical Development Document
  (DCN 14487) and response to comments
  on justification for establishing
  limitations for AOX (DCN 14497, Vol. I).
    EPA's decision to regulate AOX is
  also based on the fact that AOX, unlike
  most of the chlorinated organic
  compounds regulated today, is
  comparatively inexpensive to monitor
  for and is easily quantified by
  applicable analytical methods. Thus,
while EPA could have decided to  .-
control the formation of dioxin, furan,
chloroform, and the 12 regulated
chlorinated phenolic pollutants by
requiring mills to monitor for those
pollutants on a daily basis, EPA also
recognizes that testing for those
pollutants is expensive and time
consuming. In contrast, daily
monitoring for AOX as required in
today's rule is considerably less
expensive. See Section VI.B.8.b(4) and
DCN 14487. Additionally, under the
Voluntary Advanced Technology
Incentives Program, enrolled mills are
eligible for reduced AOX monitoring.
See Section DC.B.2 and DCN 14488.
Moreover, the presence of AOX can be
readily measured in mill effluent, in
contrast to the presence of many of the
chlorinated organic compounds
regulated in today's rule, which for the
most part are likely to be present at
levels that cannot be reliably measured
by today's analytical methods. See
Section VI.B.5,a(4). Thus, although EPA
is not required under the Clean Water
Act to consider the environmental or
human health effects of its technology-
based regulations, EPA has also
determined that regulating AOX as part
of BAT, NSPS, PSES and PSNS provides
further assurance that human health and
, the environment will be protected
against the pqtential harm associated
with dioxin, furan, and'the other
chlorinated organic pollutants.
   d. Chemical Oxygen Demand (COD).
The proposed rule included end-of-pipe
BAT limitations and PSES for COD. EPA
continues to believe that COD
limitations can be used to ensure the
operation of processes that minimize.the
discharge of all organic compounds,
including toxic organic compounds that
are not readily biodegraded. .However,
the limited data available at this time do
not adequately characterize other
sources of COD that may be present at
some complex mills, although it appears
that the COD contributed by these
sources may be as great as the COD
contribution from the pulp mill and
bleach plant areas of the mill. These
other sources of COD could include
paper machines, mechanical pulping,
other on-site chemical pulping, and
secondary'fiber processing (including
deinking). See DCN 13958 and DCN
14495. Even if sufficient data were now
available to establish COD limitations
and standards for pulp mill operations
in subparts B and E, EPA does not have
sufficient information at present to
evaluate the other sources of COD and
the performance of control technologies
to limit COD at those sources in order
to set national effluent limitations
guidelines and standards.
   For this reason, EPA is not
establishing final effluent limitations
guidelines and standards for COD at this
time. EPA does, however, intend to
promulgate COD limitations and NSPS
for the Bleached Papergrade Kraft and
Soda and Papergrade Sulfite
subcategories in a later rulemaking. For
this purpose, EPA will gather additional
data to characterize other sources of
COD that may be present at complex
mills subject to subparts B or E. This
, effort will be undertaken concurrently
with data gathering to assess the need
for establishing COD limits for mills
operating in other subcategories (Phase
II rulemaking). EPA believes that this
data-gathering effort will facilitate
setting limits in permits for complex
mills with otheronsite process
operations. EPA will also decide as part
of the Phase n rulemaking whether COD
passes through or interferes with the
operation of POTWs and, therefore,
whether pretreatment standards for COD
would be appropriate for subparts B and
E.
  While EPA does not have sufficient
data to issue national technology-based .
regulations for COD at this time, EPA
strongly urges permitting authorities to
consider including COD limitations in
NPDES permits for Subpart B and E
mills on the basis of best professional
judgment. See 40 CFR 125.3 (c) (3).
Pretreatment authorities should
establish COD local limits if COD passes
through or interferes with the POTWs
within the meaning of the general
pretreatment regulations. See 40 CFR
403.5(c). EPA believes that permitting or
pretreatment authorities should address
COD for the following reasons. Chronic
sublethal toxic effects have been found
to result from the discharge of treated
effluent from bleached and unbleached
kraft, mechanical, and groundwood/
sulfite pulp mills (see DCNs 3984,
13985, 13975,  13976,  13979, and
00012). These chronic toxic effects were
measured as increased liver mixed-
function oxydase activity and symptoms
of altered reproductive capacity in fish
(DCN 60002). This toxicity is associated
at least in part with families of non-
chlorinated organic'materials that are
measured by the existing COD analytical
method. Some of these materials,
including several wood extractive
constituents found in pulping liquors,
are refractory (i.e., resistant to rapid
biological degradation) and thus are not
measurable by the five-day biochemical
oxygen demand (BODs) analytical
method.             -.'•,'
   In order to assist permitting or
pretreatment authorities in developing

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 18538      Federal Register/Vol.  63, No. 72/Wednesday,  April 15, 1998/Rules and Regulations
COD limitations, EPA describes below
various processes that mills can use to
control COD. The major sources of COD
(which includes slowly biodegradable
and non-biodegradable organic material)
at a pulp mill are the pulp mill and
bleach plant areas. Pulping sources of
COD include digester condensates and
spent pulping liquor. Open screening
processes can be a major source of COD
discharges. Spent pulping liquor can
also be lost from the process through
process spills and equipment leaks.
Bleach plant filtrates, the recovery area,
leaks from turpentine processing areas
at softwood mills, and pulp dryers are
examples of other sources of COD at
pulp mills.
  The process changes that form the
basis of the effluent limitations
guidelines and standards promulgated
today include processes that can reduce
discharges of primarily non-chlorinated
organic compounds. These as yet
unidentified refractory organic
compounds have been correlated with
chronic sublethal aquatic toxicity from
pulp mill effluents. By recovering much
of the non-chlorinated organic
compounds prior to bleaching,
discharges of chlorinated organic
compounds also are reduced. For
example, improved brownstock
washing, which is part of the model
technology basis for today's regulations,
can be operated (for the purposes of
achieving COD limitations) to minimize
black liquor carryover to the bleach
plant and thus reduce the formation of
AOX and toxic chlorinated compounds.
Another process technology effective at
reducing organic discharges associated
with pulping liquors is for a mill to
return all water from pulp screening to
the process, termed a closed screen
room.
  EPA intends for the best management
 Practices promulgated today for
 ubparts B and  E to lead mills to retain
spent pulping liquors in the process, to
the maximum extent practicable,
through preventing leaks and spills and
through capturing those leaks and spills
that do occur and returning the organic
material to the recovery system. The
BMPs are also intended to lead mills to
collect intentional diversions of spent
pulping liquors and return those
materials to the process. However, the
BMP regulations do not require that the
contained leaked and spilled material be
recovered in the process, nor are
intentional diversions required to be
returned to the process. In the absence
of COD limitations, significant
quantities of this organic material could
be metered to the wastewater treatment
system. As a result, while the BMP
program will effectively prevent releases
of pulping liquors (and soap and
turpentine) that would upset or
otherwise interfere with the operation of
the wastewater treatment system,
refractory organic material believed to
cause chronic toxic effects could still be
discharged at levels greater than the
levels achievable through optimized
process technologies and effective end-
-of-pipe treatment.  For this additional
reason, EPA believes that COD
limitations established on a best
professional judgment basis would be
appropriate.
  The COD data considered by EPA are
presented in the support document.
Analysis of Data for COD Limitations,
DCN 13958, for this rule. This support
document also presents EPA's estimates
(based on data available today) of the
ranges of COD effluent load believed to
be contributed by other mill operations,
which EPA is supplying as limited
guidance to permitting and pretreatment
authorities. EPA urges permitting
authorities to include—and exercise—
reopener clauses in NPDES permits for
mills subject to Subpart B or E in order
to impose or revise COD effluent
limitations once effluent limitations
guidelines for COD are promulgated.
  e. Color and Other Pollutants. EPA
proposed BAT limitations and PSES for
color for the Bleached Papergrade Kraft
and Soda subcategory only. Commenters
asserted that EPA should not establish
effluent limitations guidelines and
standards for color because it is a
concern more appropriately addressed
in individual permits based on
applicable water quality standards. EPA
agrees with this comment. The potential
for significant aesthetic or aquatic
impacts from color discharges is driven
by highly site-specific conditions and is
best dealt with on a case-by-case basis
through individual NPDES permits or,
when appropriate, through local limits.
Therefore, the Agency is not
promulgating technology-based
limitations or standards for color. See
DCN 14497, Vol. I.
  EPA did not propose effluent
limitations for four pollutants, including
biphenyl, carbon disulfide, dimethyl
sulfone, and mercury, and indicated in
the  Technical Development Document
(at Section 7.3.5) that these four
pollutants were remaining under
consideration for regulation. Based on
limited data available to date, EPA has .
decided not to establish effluent
limitations and standards for these
pollutants. EPA has reached this
decision  because these pollutants are
not found consistently in effluents and
thus they are not directly, related to
pulping and bleaching processes serving
as the basis for BAT and NSPS. EPA
notes that where mercury wa.s found to
be present, the concentrations at which
it was found suggests that a possible
source of this pollutant may be
contaminants of purchased chemicals.
However, the Agency did not obtain any
information or data which would either
clearly identify the source or sources of
mercury or the other pollutants, or
provide a basis for identifying
applicable control technologies or
establishing'effluent limitations.
Therefore, EPA is not developing
effluent limitations and standards.
Individual mills may still receive water
quality based effluent limitations
(Section 301(b)(l)(Q) for any of these
pollutants where necessary to protect
local water quality.
  f. Biocides. EPA is retaining the
current effluent limitations guidelines
and standards for the biocides
pentachlorophenol and trichlorophenol
for former subparts G, H, I, and P (now
Bleached Papergrade Kraft arid Soda
subcategory, subpart B) and former
subparts J and U (now Papergrade
Sulfite subcategory, subpart E). These
limitations and standards are recodified
at subparts B and E. See 40 CFR
430.24(d), 430.25(d), 430.26(b),
430.27(b), 430.54(b), 430.55(c),
430.56(b), 43Q.57(b). For subpart B, the
limitations and standards are presented
in the form of segments corresponding
to the old subcategorization scheme.
(EPA did not need to track the old
subcategorization scheme for subpart E
because the limitations and standards
for former subparts J and U were the
same.) EPA is not codifying any
minimum monitoring frequency for
these pollutants. See 40 CFR 430.02. In
addition, unless the permitting or
pretreatment authority decides
otherwise, EPA expects that mills would
demonstrate compliance with these
limitations at the end of the pipe.
  As before, the regulations continue to
provide that a discharger is not required
to meet the biocides limitations or
standards if it certifies to the permitting
or pretreatment authority that it is not
using these compounds as biocides. See,
e.g., 40 CFR 430.24(d). (These
certification provisions have been
approved by the Office of Management
and Budget under control number 2040-
0033. See 40 CFR 9.1.) EPA notes,
however, that mills using chlorine-
containing compounds in their
bleaching processes are required to meet
separate limitations or standards for
pentachlorophenol, 2,4,5-
trichlorophenol, and 2,4,6-
trichlorophenol in connection with the
new effluent limitations and standards
promulgated today for subparts B and E
regardless whether these compounds are

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              Federal  Register/Vol. 63. No.  72/Wednesday. April 15. 1998/Rules and Regulations      18539
  also used as biocides. See, e.g., 40 CFR
  430.24 (a) (1). (Those compounds are
  included within the list of the 12
  chlorinated phenolic pollutants
 . discussed in Section VI.B.S.a.) EPA is
  requiring dischargers to demonstrate
  compliance with these limitations and
  standards by monitoring for those
  pollutants at the point where the
  wastewater containing those pollutants
  leaves the bleach.plant. See, e.g., 40 CFR
  430.24(e).                 •   '
   EPA believes it is appropriate to.
  codify separate limitations and
  standards for those pollutants, even
  though in. very rare cases a mill may be
  required to comply with both sets. First,
  although for the same pollutants the two
  sets of limitations arise  from different
  chemical applications in different parts
  of the mill. As biocides,
  pentachlorophenol or trichlorophenol
  could be used virtually  anywhere in a
  mill's' industrial process, but were
  typically used as sHmicides in
  Whitewater recirculation systems. In the
  limitations and standards promulgated
  today, however, pentachlorophenol,
  2,4,5-trichlorophenol and 2,4,6-
  trichlorophenol are being regulated
 . because they are found in bleach plant
  wastewater when chlorine-containing
  compounds are used for bleaching.
  Second, EPA expects these pollutants to
'  be reduced to quantities below the
  minimum level of the applicable
  analytical method as a result of bleach
  plant process changes, which is not the
  case when they are used as biocides.
  Thus the different limitations'and
  standards found in subparts B and E for
  these pollutants respond to different
 situations and reflect different model
  process technologies. Finally, EPA
 believes that mills in the Bleached
 Papergrade Kraft and Soda subcategory
 or the Papergrade Sulfite subcategory
 generally do not use pentachlorophenol
 or trichlorophenol as biocides today.
 See the Supplemental Technical
 Development Document, DCN 14487.
 Therefore, EPA expects  that each mill,
 will be able to certify that it is not using
 the  compounds as faiocides and
 therefore will not be subject to the
 biocides-related limitations.
 4. Analytical Methods
   In this rule, EPA is promulgating
 Method  1650 for the analysis of AOX
 and Method 1653 for the analysis of
 certain chlorinated phenolic
 compounds.
   a. Authority. The analytical methods
 in this final rule are promulgated under
 the  authority of CWA sections 301,
 304(h), 307, 308, and 501(a). Section
 301 of the Act prohibits the discharge of
. any pollutant into navigable waters
 unless the discharge complies with an
 NPDES permit issued under section 402
 of the Act. Section 301 also specifies
 levels of pollutant reductions to be
 achieved by certain dates. Section
 304 (h) of the Act requires the EPA
 Administrator to "promulgate
 guidelines establishing test procedures
 for the analysis pf pollutants that shall
 include the factors which must be
 provided in any certification pursuant
 to section 401 of this Act or permit
 applications pursuant to section 402 of
• this Act." These test procedures for the
 analysis of pollutants also assist in the
 implementation of Section 301. Section
 501 (a) of the Act authorizes the
 Administrator to prescribe such
 regulations as are necessary to carry out
 her function under this Act.
   The Administrator has also made
 these test procedures (methods)
 applicable to monitoring and reporting
 of NPDES permits (40 CFR part 122,
 §§ 122.21, 122.41, 122.44, and 123.25),
 and implementation of the pretreatment
 standards issued under section 307 of
 CWA (40 CFR part 403, §§ 403.10 and
 403.12). Section 308 provides authority
 for information gathering.
   b. Background and History. In the
 December 17,1993 proposal, EPA
 referenced^ compendium entitled
 "Analytical Methods for the
 Determination of Pollutants in Pulp and
 Paper Industry Wastewater." This
 compendium contained methods that
 had not been promulgated at 40 CFR
 part 136, but would be applicable for
 monitoring compliance with the
 limitations and standards proposed for
 part 430 at that time. The compendium
 included methods for the analysis of
 CDDs and CDFs '(i.e., dioxin and furans),
 AOX, chlorinated phenolics, and color.
 These methods were proposed for
 promulgation at 40 CFR part 430 to
 support the proposed regulation and
 were included in the docket for the
 proposed pulp and paper rule.
   EPA received more than 200
 individual comments and suggestions
 concerning the proposed analytical
 methods. Some of these were comments
 on the methods not being promulgated
 today. Many of the comments and
 suggestions were technically detailed,
 ranging from suggestions on changing
 the integration time in Method 1650 (for
 AOX) to reducing the spike levels for
 labeled compounds used in Method
 1653 (for chlorinated phenolics). Other
 comments raised questions about EPA's
 approach to technical issues and
 policies regarding the handling of
 analytical data. EPA has included a
 summary of the detailed comments and
 specific responses to those comments in
 the record for today's rule.
   On July 15,1996, EPA published a
 notice of availability that, among other
 things, summarized the changes the
 Agency intended to make to the
 proposed or promulgated analytical
 methods and stated that detailed
 revisions to the methods would be
 added to the record at a later date. See
 61 FR.at 36848-49. In promulgating
 today's rule, EPA has implemented the
 changes identified in the July 1996
 Notice. These changes are summarized
 below and detailed in the response to
 comments provided in the record.
   c. Analytical Methods Promulgated
 Today. EPA has revised the analytical
 methods compendium entitled
 "Analytical Methods for the
 Determination of Pollutants in Pulp and
 Paper Industry Wastewater" to
, incorporate revisions to the methods
 made since proposal. This compendium
 (EPA-821-B-97-001, August 1997)
 contains the analytical methods to be
 used for monitoring compliance with
 the limitations and standards
 promulgated today for subparts B and E.
 The compendium includes Method
 1650 for the determination of AOX and
 Method 1653 for the determination of
 chlorinated phenolics. These two
 analytical methods are being
 promulgated today as appendices to 40
 CFR part 430. They have not yet been
 promulgated at 40 CFR part 136.
   (1) Method 1650: AOX by Adsorption
 and Coulometric Titration
   Method 1650 can be used to  measure
 AOX in water and wastewater. AOX is
 a measure of halogenated organic
 compounds that adsorb onto granular
 activated-carbon (GAC). The method
 involves adsorption of the organic
 halides (chlorine, bromine, iodine) in
 water onto GAC, removal of inorganic
 halides by washing, combustion of the
 organic halides (along with the GAC) to
 form hydrogen halides, and titration of
 the hydrogen halides with silver ions in
 a microcoulometer. The results are
 reported as organic chlorine even
 though other halides may be present
 because chlorine is the halide of
 concern in pulp and paper wastewaters.
 EPA studies have demonstrated a
 Method Detection Limit (MDL) of 6.6
 |ig/L. Based on this MDL and on
 calibration of the-microcoulometer, the
 minimum level (ML) in Method 1650
 has been determined to be 20 (xg/L. The
 minimum level and other performance
 attributes for this method have been
 validated in single laboratory method
 validation studies and by use in data
 gathering for today's final  rule. All
 laboratories that used Method 1650 in
 the data gathering effort calibrated their
 instruments at the ML.

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18540      Federal Register/Vol.  63,  No. 72/Wednesday, April 15,  1998/Rules and Regulations
  Since proposal, EPA has made
changes to Method 1650 to improve the
ease of use and the reliability of this
method. These changes are reflected in
the version of Method 1650 being
promulgated today and they largely
reflect comments and suggestions made
following proposal of the method. In
response to comments, EPA made
several changes to Method 1650,
including: adjustment of the
breakthrough specification to 25 percent
based on  recent data; allowance of a
100- or 25-mL adsorption volume,
provided the sensitivity requirements in
the method are met; provision of greater '
flexibility in allowable glassware sizes;
use of 100-mL volumes of standards for
calibration and other purposes to
conserve  reagents; use of only 2-mm
columns to make the column procedure
more reproducible; adjustment of the
QC acceptance criteria based on an
industry interlaboratory method
validation study; and the addition of a
minimum integration time of 10
minutes to assure that all AOX is
measured. In addition, the format of the
method has been modified to reflect the
standardized format recommended by
EPA's Environmental Monitoring
Management Council (EMMC). For a
more detailed discussion of the changes
made to Method 1650 since proposal,
see DON 14497. Vol. VH.
  EPA disagreed with several comments
on EPA's proposed Method 1650 and
therefore did not make the changes
suggested by commenters. In particular,
EPA disagrees that the method detection
limit (MDL) should be increased to 20
Hg/L to allow for blank contamination.
In EPA's view, blank contamination can.
be controlled to levels well below 20 jig/
L. EPA also disagrees that it should
eliminate Section 8.1.2 of the proposed
method. (Section 8.1.2 contained
provisions for flexibility.) EPA has
received a large number of requests that
analytical methods be "performance-
based," and has attempted to implement
the means for allowing changes in
Section 8.1.2 (Section 9.1.2 in the
version of Method 1650 being
promulgated today). Under Section
8.1.2, the laboratory can make minor
modifications to Method 1650 provided
that the laboratory performs all quality
control (QC) tests and meets all QC
acceptance criteria. In addition, contrary
to a suggestion from a commenter, EPA
has not included examples of cell
maintenance in Method 1650 because
EPA believes that analysts who
maintain the coulometric cell must be
familiar with the cell maintenance
procedures provided by the instrument
manufacturer. For more information on
these issues, see DCN 14497, Vol. VH.
  (2) Method 1653: Chlorophenolics by
In-Situ Derivatization and Isotope
Dilution GC/MS
  Method 1653 can be used to measure
chlorinated phenolic compounds in
water and wastewater amenable to in
situ acetylation, extraction, and
determination by HRGC combined with
low-resolution mass spectrometry
(LRMS). In this method,
Chlorophenolics are derivatized in situ
to form acetic acid phenolates that are
extracted with hexane, concentrated,
and injected into the HRGC/LRMS
where separation and detection occurs.
  EPA studies have demonstrated MDLs
of 0.09-1.39 pg/L for Chlorophenolics in
water. Based on these MDLs and on
calibration of the GCMS instrument,
minimum levels .have been determined
for the 12 chlorinated phenolics in
today's rule. These minimum levels of
2.5 or 5.0 jig/L depend on the specific
compound and have been validated in
single laboratory validation studies and
by use in data gathering for today's final
rule. All laboratories that used Method
1653 in the data gathering effort
calibrated their instruments at the ML.
  Since proposal, EPA has made
changes to Method 1653 to improve the
reliability of the method and to lower
costs of measurements. These changes
are incorporated into the version of the
method being promulgate^ today; they
largely reflect comments and
suggestions made following proposal of
the method.
  In response to comments, EPA made
several specific changes to Method
1653, the most significant of which are
as follows: lowering the spike level of
the labeled compounds to reduce
interferences with trace levels of the
analytes of interest and to lower the cost
of labeled compounds; specifying more
appropriate solvents for the analytical
standards containing labeled and native
analytes; requiring laboratories to add
the labeled compounds to the sample
prior to pH adjustment; restating the
quality control acceptance criteria for
recovery in terms of percent instead of
concentration; and reducing method
flexibility in certain critical areas. In
addition, as with Method 1650, the
method has been revised into the
standardized EMMC format.
  EPA disagreed with several comments
on EPA's proposed Method 1653 and
therefore did not make changes
suggested by commenters. EPA received
comments that Method 1653 has not
been validated adequately. EPA
disagrees. Method 1653 has been
validated in multiple single-laboratory
method validation studies and
extensively validated in field studies for
this final rule. EPA believes that these
extensive studies are more than
adequate to validate Method 1653 for
use in data gathering to support this
final rule and for use in monitoring
under this final rule. EPA also disagrees
with comments that Method 1653 is
inadequate for chlorocatechols. EPA
believes that Method 1653 provides
more reliable data for catechols and the
other Chlorophenolics than any other
method available, and the commenter
provided no suggestions for how
Method 1653 could be improved for
determination of chlorocatechols. EPA
has, therefore, kept chlbrocatechols in
Method 1653. EPA also disagrees with
comments that initial precision and
recovery (IPR) and ongoing precision
and recovery (OPR) tests should be
replaced with initial calibration QCAL)
and calibration verification (VER) tests.
(The ICAL and IPR are different in both
form and function. The calibration test
is for calibrating the analytical system
while the IPR test is conducted to check
performance. The OPR and VER tests
are the same; only the terminology is
different. EPA has retained use of the
OPR terminology to be consistent with
other methods.) EPA also disagrees with
comments that use of labeled
compounds is not worth the benefit and
that all phenols and guaiacols. should be
quantitated against 3,4,5-   .
trichlorophenol. EPA believes that data
gathered to support today's final rule
and in other studies demonstrate that
isotope dilution provides the most
precise and accurate measurement of
Chlorophenolics and other compounds
determined by gas chromatography/
mass spectrometry. EPA also received
comments urging EPA not to allow
modifications to the method. However,
EPA also received a large number of
requests that analytical methods be
"performance-based," and has
attempted to implement the means for
allowing changes to improve detection
and quantitation or to lower costs of
measurements. Limited changes may be
made, except where specifically
prohibited in Method 1653, provided
that the performance tests are repeated
and the results produced by the change
are equivalent or superior to results
produced with the unmodified method.
EPA has also decided to retain the
mention of field duplicates in the
method in the event that a laboratory or
discharger desires to measure sampling
precision. Finally, EPA has not added
the requirement that laboratories should
be forced to overcome emulsions. EPA
believes that nearly all emulsions can be
overcome and provides specific steps in

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             Federal Register/Vol. 63. No. 12 /Wednesday. April 15,  1998/Rules and Regulations      18541

 the method that the laboratory must take
 to break the emulsion. However, EPA
 does not wish to impose such a
 requirement on laboratories in the event
 that a future ^sample is encountered that
 produces an emulsion that cannot be
 broken. If all efforts to break the
 emulsion fail, Method 1653 allows the
 use of a dilute aliquot. For more
 discussion, see Comment Response
 Document, Vol. VH, DCN 14497.
   d. Other Methods, In addition to the
 methods promulgated today, the
 effluent limitations guidelines and
, standards also call for the use of Method
 1613 (for 2,3,7,8-tetrachlorodibenzo-p-
 dioxin (TCDD) and 2,3,7,8-
 tetrachlorodibenzofuran (TCDF)) and
 any of the approved methods for
 chloroform to monitor compliance.
 These methods are 'discussed below.

 (1) Method 1613: CDDs.andCDFs by   ;
 HRGC/HRMS
   Method 1613 uses isotope dilution
 and high-resolution gas chromatography
 combined with high-resolution mass
 spectrometry (HRGC/HRMS) for
 separation and detection of 17 tetra-
 through pcta-substituted dibenzo-p-
 dioxin and dibenzofuran isomers and :
 congeners that are chlorinated at the 2,
 3, 7, and 8 positions. Separate
 procedures are available for the
 determination of these analytes in water
 and solid matrices. In  the procedure, a
 1-L sample is passed through a OA5-]i
 glass fiber filter. The filter is extracted
 with toluene in a Sbxhlet/Dean-Stark
 (SDS) extractor. The aqueous filtrate is
 extracted with methylene chloride in a
 separatory funnel. Extracts from  the SDS
 and separatory funnel extractions are
 combined and concentrated. To remove
 interferences, the combined, - .
 concentrated extract is cleaned up using
 various combinations  of acid and base
 washes, acidic and basic silica gel, gel
 permeation chromatography (GPC),
 high-performance liquid
 chromatography (HPLC), and activated
 carbon. The cleaned up extract is
 concentrated to 20 \iL and a 1-2 [iL .
 aliquot is injected into the HRGC/
 HRMS.
  The MDL determined for TCDD is 4.4
 part-per-quadrillion (ppq). Minimum
 levels for Method 1613 are 10 ppq for
 TCDD and TCDF. These MLs have been
 validated through an interlaboratory
 study and by use in the analysis,of mill
 effluents.
  EPA recently promulgated Method
 1613 for the determination of CDDs and
 CDFs at 40 CFR 136, Appendix A in a
 final rule published on September 15,
 1997 (62 FR 48394). Of the 17 congeners
 that may be measured  with this method,
 only TCDD and TCDF  are regulated
 under this final rule. Method 1613 was
 first proposed for general use in      v
 compliance monitoring and for other '
 purposes at 40 CFR part 136 on
 February 7, 1991 (56 FR 5090) and was
 proposed for use in pulp and paper
 industry wastewaters at 40 CFR part 430
 on December 17, 1993 (58 FR 66078).
 EPA received extensive comments and
 suggestions on both proposals of
 Method 1613; in several cases, the same
 set of comments was submitted. EPA
 updated the final Method 1613 based on
 suggestions and comments received on
 the original proposal (56 FR 5090) and
 on the proposal of Method 1613 for use ,
 at 40 CFR part 430  (58 FR 66078). In the
 docket supporting promulgation of
 Method 1613, EPA provided a listing of
 detailed comments received on both
 proposals of Method 1613, along with
 detailed responses to all of those
 comments. Because Method 1613 was
 promulgated in a final rule prior to
 promulgation of today's final'rule, and
 because EPA received comments and  *
 provided responses in support of that
 final rule, EPA is not promulgating
 Method 1613 as part of today's final
 rule. See the final rule promulgating
 Method 1613 (62 FR 48394) for all
 information concerning that method.   *

 (2) Method 1624: Volatiles by Purge-
 and-Trap and Isotope Dilution GC/MS
  Method 1624 is used for the
 determination of volatile pollutants in
 water and wastewater. It employs a gas
 chromatograph coupled to a mass
 spectrometer (GC/MS) to separate and
 quantify volatile pollutants. Petected
 pollutants are quantified by isotope
 dilution. Samples of water or solids
 suspended in water are purged of   •
 volatile organic pollutants by a stream
 of inert gas into the gaseous phase
 where they are concentrated onto a trap.
 Subsequent heating of the trap
 introduces the concentrated volatile
 organics into a GC/MS for separation
 and quantification.
  With no interferences present,
 minimum levels of  10-50 ng/L can be
 achieved, depending on the specific
pollutant. For chloroform, the minimum
level is 10 |ig/L. This minimum level
has been validated by use.
  When EPA initially proposed today's
rule; it proposed to  regulate four volatile
organic pollutants. Method 1624,
Revision C was proposed for monitoring
the presence of these pollutants in
effluent discharges. Revision C
contained updates and improvements to
Method 1624, Revision B, which was
promulgated October 26, 1984 (49 FR
43234).
  In today's final rule, EPA is regulating
only one of the originally proposed
 volatile pollutants (chloroform); this
 pollutant can be measured by already-
 approved EPA Methods 601, 624, and
 1624B and Standard Methods 6210B
 and 6230B. Therefore, EPA has not
 included Method 1624C in today's final
 rule and has not formally addressed
 .comments concerning Method 1624C.
 EPA will consider comments on Method
 1624C when this version of the method
 is promulgated for general use at 40 CFR
 136 or when the method is further
 revised.

 (3) Other Issues Concerning Analytical,
 Methods Promulgated in Today's Final
 Rule
   The overall comments received from
 the regulated industry and others
 provide suggestions for method
 improvement but, in some cases,
 question EPA's approach to technical
 issues in the methods and the handling
 of data. For example, commenters
 suggested that quality control tests be
 performed at the minimum level (ML),
 that a 3-point calibration should be used
 for labeled compounds in isotope
 dilution methods, and that additional
 QC  tests should be required.
 Commenters also stated that all methods
• must be subjected to interlaboratory
 validation, and that the compliance
 monitoring detection limit (CMDL) and
 compliance monitoring quantitation
 limit (CMQL) should be used in place of
 EPA's method detection limit (MDL)
 and ML, respectively. EPA responded to
 these suggestions by providing specific
 reasons why they are inconsistent with
 the  provisions in other methods, are
 more extensive than required to assure
 reliable results, or that they would not
 substantively alter the conclusions of
 studies and data gathering used to
 support this final rule. The detailed
 responses to these issues are in the
 record for this rule.

 5. Bleached Papergrade Kraft and Soda  .
 Subcategory                      '
   a. BAT. (1) Technology Options
 Considered.
   (a). Options Proposed? The Agency
 considered many combinations of
 pollution prevention technologies as •
 regulatory options to reduce the
 discharge of toxic and nonconventional
 pollutants from bleached papergrade
 kraft and soda mills. These options are
 discussed in the proposal and the
 Notice of Availability published on July
 15, 1996. See 58 FR at 66109-11 and 61
 FR at 36838-39, 36848. Five different
 options were presented in the proposal.
   The.Agency proposed BAT effluent
 limitations guidelines based on an
 option that included the use of oxygen
 delignification or extended cooking

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18542
Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules and Regulations
with elimination of hypochlorite and
complete (100 percent) substitution of
chlorine dioxide for elemental chlorine
as the key process technologies.
Complete substitution of chlorine
dioxide for elemental chlorine and
elimination of hypochlorite is known as
elemental chlorine-free (ECF) bleaching.
EPA's definition of ECF bleaching
includes high shear mixing to ensure
adequate mixing of pulp and bleaching
chemicals, as well as other technology
elements.
  EPA proposed this option because it
believed, based on the record at the
time, that this combination of
technologies was both available and
economically achievable and that no
other available and economically
achievable option resulted in greater
effluent reductions. See 58 FR at 66110.
In the July 1996 Notice, EPA identified
this technology option as Option B. See
61 FR at 36838.
  EPA also considered at proposal
another option based on conventional
pulping—complete substitution of
chlorine dioxide for elemental chlorine,
but without the use of oxygen
delignification or extended cooking (i.e.,
conventional pulping). See 58 FR at
66111. At the time of proposal, EPA was
unable to fully analyze this alternative
because very limited performance data
were available from mills using this
technology. Therefore, EPA solicited
further data and comments, on this
option, Id. In the July 1996 Notice. EPA
published preliminary findings
regarding this option, which it
identified as Option A. See 61 FR at
36838-42.
  The Agency also considered a totally
chlorine-free (TCP) option for the
Bleached Papergrade Kraft and Soda
subcategory at proposal. See 58 FR at
66109. TCF bleaching processes are
pulp bleaching operations that are
performed without the use of chlorine,
sodium hypochlorite, calcium
hypochlorite, chlorine dioxide, chlorine
monoxide, or any other chlorine-
containing compound. EPA  concluded
that TCF was not an available pollution
prevention technology at the time of
proposal because of limited  worldwide
experience with this process and a lack
of data for TCF bleaching of softwood to
full market brightness. To encourage
continuing innovation in the
development of processes to reduce or
eliminate the discharge of pollutants
from the Bleached Papergrade Kraft and
Soda subcategory, however, EPA
proposed alternative BAT limits for
mills adopting TCF processes.
  In the July 1996 Notice, EPA also
described an incentives program that it
was considering for Subpart B mills in
                          order to promote more widespread use
                          of advanced pollution prevention
                          technologies. See 61 FR at 36849-58. As
                          part of this voluntary program, EPA
                          proposed to establish up to three sets of
                          alternative BAT limitations that would
                          complement the compulsory baseline
                          BAT requirements. EPA identified the
                          proposed alternative BAT limitations as
                          Tier I, Tier II, and Tier HI BAT
                          limitations. See 61 FR at 36850. EPA
                          considered basing Tier! limits on BAT
                          Option B technology (if Option A were
                          chosen as the basis for the baseline BAT
                          limitations). The Tier n and Tier IE
                          limitations, in turn, would be based on
                          technologies and processes that EPA
                          expected to achieve substantial
                          reductions in pulping area condensate,
                          evaporator condensate, and bleach plant
                          wastewater flow.
                            (b) Final ECF Options Evaluated. For
                          this final rule, EPA considered two ECF
                          technology options—Option A and
                          Option B—as the basis for BAT effluent
                          limitations. Option A consists of
                          conventional pulping followed by
                          complete substitution of chlorine
                          dioxide for elemental chlorine, as well
                          as the following nine elements:
                           ((i) Adequate chip thickness control;
                            (ii) Closed brownstock pulp screen
                          room operation, such that screening
                          filtrates are returned to the recovery
                          cycle;
                            (iii) Use of dioxin- and furan-
                          precursor-free defoamers (i.e., water-
                          based defoamers or defoamers made
                          with precursor-free oils);
                            (iv) Effective brownstock washing,
                          i.e., washing that achieves a soda loss of
                          less than or equal to 10 kg Na2SO4 per
                          ADMT of pulp (equivalent to
                          approximately 99 percent recovery of
                          pulping chemicals from the pulp);
                            (v) Elimination of hypochlorite, i.e.,
                          replacement of hypochlorite with
                          equivalent bleaching power in the form
                          of additions of peroxide  and/or oxygen
                          to the first extraction stage and/or
                          additional chlorine dioxide in finaL
                          brightening stages;
                            (vi) Oxygen- and peroxide-enhanced
                          extraction, which allows elimination of
                          hypochlorite and/or use of a lower
                          kappa factor in the first bleaching stage;
                            (vii) Use of strategies to minimize
                          kappa factor and dioxin- and furan-
                          precursors in brownstock pulp;
                            (viii) High shear mixing during
                          bleaching to ensure adequate mixing of
                          pulp and bleaching chemicals; and
                            (ix) Efficient biological wastewater
                          treatment, achieving removal of
                          approximately 90 percent or more of
                          influent BODs. These elements are
                          discussed in detail in the Supplemental
                          Technical Development Document, DCN
                          14487. Option B is identical to Option
A, with the addition of extended
delignification (oxygen delignification
and/or extended cooking). EPA also
considered a TCF option, see subsection
(c) immediately below, and, in the
context of the Voluntary Advanced
Technology Incentives Program, three
sets of voluntary alternative BAT
limitations. See Section IX.A.
  In a slight change from the definition
of the proposed BAT option, EPA has
defined Option B not only In terms of
the presence of extended delignification
technology (i.e., oxygen delignification
or extended cooking) but also by the
pre-bleaching kappa number achieved
by extended delignification. Kappa
number is the measure of lignin content
in unbleached pulp and is commonly
used by the industry. Many researchers
have shown (and EPA has confirmed)
strong correlations between the kappa
number of the pulp entering the first
stage of bleaching and the bleach plant
effluent loads of AOX and COD. See
DCN 14497, VoL I. EPA concluded that
merely employing extended
delignification technologies, without
reducing the unbleached pulp kappa
number, is not sufficient to achieve the
low effluent loadings of AOX and COD
characteristic of Option B. Therefore,
EPA has redefined Option B as ECF
with extended delignification resulting
in a'kappa number at or below 20 for
softwoods and below 13 for hardwoods
(see the Supplemental Technical
Development Document, DCN 14487).
EPA found that these kappa numbers
are achievable by virtually all mills that
currently have installed and are
effectively operating extended
delignification technology.
  As part of the nine elements common
to both Option A and Option B,  EPA has
included strategies for minimizing
kappa factor and. dioxin-  and furan-
precursors in brownstock pulp. These
strategies are part of Options A and B
because EPA has determined that they
minimize the generation  of dioxin,
furan, and AOX and, hence, are part of
the model process sequence to achieve
those limitations. See 61  FR at 36848
and the Supplemental Technical
Development Document, DCN 14487.
  Kappa factor, also known as active
chlorine multiple, is the ratio of
chlorine bleaching power to the pulp
•kappa'number. (The kappa factor is
different from the kappa  number
discussed above.) The kappa factor used
on a particular bleach line depends on
the fiber furnish, final product
specifications, pre-bleaching processes
employed, and optimization of
bleaching costs. At the mills whose data
were used to characterize Option A
performance, kappa factors for softwood

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             Federal Register/Vol. 63, No. 72/Wednesday, April 15,  1998/Rules and Regulations
                                                                    18543
 furnish averaged 0.17 and all were less  .
 than 0.2. At the mills whose data were
 used to characterize Option B
 performance, kappa factors for softwood
 furnish averaged 0.23, with all but one
 at less than 0.21. Well-operated and
 maintained mills using comparable
 kappa factors will be capable of
 achieving limitations corresponding to
 Option A or B, respectively. Based on
 certain site-specific factors, such as
 furnish, some mills will be capable of
 achieving today's limitations with
 higher kappa factors. There are
 numerous strategies a mill can employ
 to minimize its kappa factor. See the
 Supplemental Technical Development
 Document, DCN 14487.
  In addition, there are numerous
 strategies a mill can employ to minimize
 precursors of dioxiri and furan
 contained in brownstock pulp. These
 strategies include, but are not limited to,
 improved brownstock washing,
 improved screening to produce cleaner,
 pulp, eliminating compression wood
 (knots) from brownstock pulp, and
Busing only precursor-free condensates in
 brownstock washers. The strategy or
 strategies appropriate for the production,
 of a given pulp depend on the raw
 material (v^ood species and the form it
 takes, i.e., chipsi waste wood, or
 sawdust), process equipment, and the
 specifications of the final pulp product
 (brightness, cleanliness, strength,
 absorbency, and others). For a
 discussion of these strategies, see the
 Supplemental Technical Development
 Document, DCN 14487.
   (c) Totally Chlorine-Free (TCP)
 Bleaching Option Evaluated. The
 Agency received many comments that it
 should continue to investigate TCP
. bleaching because dioxin and furan are
 not generated at any level with TCP
 bleaching, thus assuring that these
 pollutants are not released to the
 environment. The Agency conducted
 two sampling-programs at the one U.S.
 mill that produces TCP bleached kraft
 softwood pulp. EPA collected samples
 of bleach plant filtrates but could not
 collect samples of treated effluent
 because the mill does not employ
 secondary treatment. The Agency also
 conducted a sampling program at a
 Nordic mill that produces hardwood
 and softwood kraft pulp on two bleach
 lines that alternate between ECF and
 TCP bleaching. Samples collected at this
 mill could not be used to characterize
 treated TCP bleaching effluents because
 they are combined with ECF bleaching
 effluents for treatment.
   Both of the sampled TCP softwood
 fiber lines employed oxygen
 delignification followed by multiple
 stages of peroxide bleaching. The
Nordic mill also uses extended cooking,
and was able to reduce the lignin
content of unbleached pulp to a very
low kappa number of four. At the time
of sampling, this mill bleached pulp to
a brightness of 83 ISO. The U.S. mill's
unbleached pulp kappa number was
between seven and ten.  Bleached, pulp
brightness was approximately 79 during
the first sampling episode at the U.S.
mill, but by the time of the second
sampling episode, the mill had
improved its process to  achieve a pulp
brightness of 83 ISO.
  At both mills, chloroform or
chlorinated phenolic pollutants were
•not detected in samples collected by
EPA. At the U.S. mill, dioxin, furan, and
AOX were not detected  above the
analytical minimum level during
sampling fully representative of TCP
operations. The average bleach plant
AOX loading measured  by EPA at the
Nordic mill was 0.002 kg/ADMT
(compared to a long-term average of 0.51
kg/ADMT for Option A). EPA's dioxin
sampling results for the Nordic mill
were surprising. Dioxin was detected at
a concentration just above the minimum
level in one sample of combined bleach
plant filtrate, when the mill was
bleaching without the use of chlorine or
any chlorinated compounds. Furan was
not detected. EPA believes the dioxin
results were unique to the operation of
this mill and does not conclude that
TCP bleaching generates dioxin.
  Neither of the two sampled .mills
produced softwood pulp at full market
brightness. In the last three years,
however, several non-U.S. mills have
reported the production of TCP
softwood kraft pulp at full market
brightness. EPA's data are insufficient to
confirm that TCF processes are
technically available for the  full range of
market products currently served by
ECF processes. See DCN 14497, Vol. I.
Further, EPA's data are insufficient to
define a segment of the Bleached
Papergrade Kraft and Soda subcategory
where TCF processing is known to be
technically feasible and thus could be
the basis of compulsory BAT
limitations. Despite these impediments,
EPA .believes that the progress being
made in TCF process development is
substantial, and that additional data
may demonstrate that TCF processes are
indeed available for the full range of
market products. For this reason, EPA
also evaluated the performance of TCF '
mills in order .to establish alternative
limitations for mills that voluntarily
choose to employ TCF processes. See
Section VI.B.5.a(4).  ,
  (2) Costs of Technology Options
Considered. The Agency estimated the
cost for the Bleached Papergrade Kraft
and Soda subcategory to achieve each of
the technology options considered
today. These estimated costs are
summarized in this section and are
discussed in more detail in several
technical support documents. (See the
BAT Cost Model Support Document,
DCN 13953; Memorandum: Costing
Revisions Made Since Publication of
July 15, 1996.Notice of Data
Availability, DCN 14493; Supplemental
Technical Development Document, DCN
14487; Analysis of Impacts of BAT
Options on the Kraft Recovery Cycle,
DCN 14490; Effect of Oxygen
Delignification on Yield of the Bleached
Papergrade Kraft Pulp Manufacturing
Process, DCN 14491; and the Technical
Support Document for Best Management
Practices for Spent Pulping Liquors
Management, Spill Prevention, and
Control, DCN 14489.)  (For a discussion
of the costs associated with the
Voluntary Advanced Technology
Incentives Program BAT technologies,
see the Technical Support Document,
DCN 14488.) All cost estimates in this
section are expressed in 1995 dollars.
The cost components reported in this
section are engineering estimates of the
cost of purchasing and installing
equipment and the annual operating
and maintenance costs associated with
that equipment. See Section VQI of this
preamble for a discussion of the costs
used in the economic impact analysis.
  Because EPA considers efficient
biological wastewater treatment to be
current industry practice, EPA has not
included its costs in the estimates of
costs of BAT.  See the Supplemental
Technical Development Document, DCN
14487. As discussed in Section VLB.5.C.
below, for PSES for the Bleached
Papergrade Kraft and Soda subcategory,
EPA evaluated the same process change
technology options that it evaluated for
BAT, with the exception of biological
wastewater treatment. As a result, EPA
used the same cost model to estimate
the costs of PSES and BAT. Set forth   ;
below are the total costs for all mills, in
the subcategory (direct and indirect
dischargers) to complete the process
changes that are the technology bases
for the options considered for BAT and
PSES. The costs of complying with  •
today's BMP requirements are also
included.
  (i) Additional Data Gathering and
Analysis Since Proposal. EPA updated
its database of mill process information ,
by reviewing comments on the proposed
rule and the July 15, 1996 Notice, by ,
examining information from publicly
available sources as well as information
gathered by AF&PA and NCASI, and by
contacting mills directly. The Agency
revised the cost estimates it made at

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 18544      Federal Register/Vol.  63,  No. 72/Wednesday, April 15, 1998/Rules and Regulations
 proposal in many ways but retained two
 major assumptions: (1) Mills would
 continue to make the same quantities
 and grades of pulp; and (2) mills already
 using the technology bases for the BAT
 technology options generally would
 incur only monitoring costs to comply
 with regulations based on those options.
 See the Supplemental Technical-
 Development Document, DCN 14487.
  EPA received comments that it
 severely underestimated the costs of its
 proposed option (now identified as
 Option B). Commenters contended that
 this underestimate derived in large part
 from EPA's underestimate of the
 increase in load of black liquor solids
 that will be routed to the recovery
 system after installation of oxygen
 delignification, closing screen rooms,
 improving brownstock washing, and
 recovering additional pulping liquors
 through a best management practices  •
 (BMP) program. In addition to
 underestimating the increase in load,
 commenters claimed that EPA also
 underestimated the costs for recovery
 boilers to accommodate the increased
 load.  Commenters asserted that most
 mills are recovery boiler-limited and, to
 employ the proposed BAT, would have
 to install new recovery boilers at a very
 high cost.
  In response to these and other
 comments on the proposed rule, EPA
 and NCASI undertook several data
 gathering efforts aimed specifically at
 obtaining information to improve EPA's
 cost estimates.  In late 1994. NCASI
 distributed a survey to collect
 information about recovery furnace
 capacity and a second survey about the
 implementation and cost of pulping
 liquor spill prevention and control
 programs (i.e., BMPs).
  Based on this and other information,
 EPA concluded that there is no
 foreseeable set of circumstances where
 implementation of either Option A or B
 would force a mill to replace or even
 rebuild an existing recovery boiler.
 Therefore, EPA strongly disagrees with
 comments that it severely
 underestimated the costs of what is now
 known as Option B. Based on data
 reported in the NCASI survey, almost 60
 percent of the recovery boilers operated
 by the industry have sufficient capacity
 to accommodate the increased loads that
 would result from implementing either
 Option A or B,  in combination with the
 BMP program promulgated today. At
 most of the remaining 40 percent of the
 recovery boilers, any increased thermal
 load can be accommodated through
 improved boiler operation requiring no
 capital expenditures, by increasing pulp
yield by using anthraquinone, or by
reducing the caloric value of the black
 liquor burned in the boiler by using
 oxygen-black liquor oxidation. EPA
 estimates that only one boiler operated
 by a bleached papergrade kraft and soda
 mill would need to be upgraded
 regardless which option is selected as
 the technology basis for today's rule.
 The cost of the upgrade is small in
 comparison to the cost of building or
 replacing a boiler. See the Supplemental
 Technical Development Document, DCN
 14487, and Analysis of Impacts of BAT
 Options on the Kraft Recovery Cycle,
 DCN 14490.
   For the purposes of estimating the
 costs of Option B, EPA estimated costs
 for implementation of oxygen
 delignification (OD) based on the record
 as a whole that shows that OD does not
 have an impact on yield of bleached
 pulp. Although some stakeholders
 asserted that EPA's yield estimates were
 in error, the entire record on yield
 supports EPA's basis for estimating the
 cost of BAT Option B. Some
 commenters asserted that EPA
 overestimated the costs for Option B
 presented in the July 1996 Notice by
 failing to account for the increase in
 yield that would result from
 implementation of OD. Industry
. commenters asserted that OD would
 result in reduced bleached pulp yields.
 In response to these comments,  EPA
 reviewed all available literature reports
 and contacted companies operating
 mills with OD systems. Although some
 laboratory and modeling analyses
 indicate that OD following a modified
 kraft cooking could increase yields by
 one to two percent, EPA found no
 documentation that full-scale OD
 systems are being operated in this
 manner. One of the two U.S. companies ,
 that operate more mills with OD
 systems than any other has found no
 statistical difference in yield measured
 at the end of the bleach plant with the
 installation of OD. The other company
 offered no specific data on yield, but has
 seen no substantial impact on recovery-
 boilers, indicating that no appreciable
 change in yield has been experienced.
 See DCN 14491.
 ,  EPA also collected additional
 information about the costs of process
 equipment and updated its information
 about the costs of chemicals, wood,
 energy, and labor (record sections  21.1.2
 to 21.1.6). EPA used this information to
 revise the cost model spreadsheet. See
 the Memorandum: Costing Revisions
 Made Since Publication of July 15, 1996
 Notice of Data Availability, DCN 14493,
 and BAT Cost Model Support
 Document, DCN 13953. These changes
 are discussed immediately below.
   (ii)  Major Changes Since Proposal.
 Among other changes since proposal,
EPA's cost estimates for Option B now
include the costs for new or incremental
increases in OD systems for mills unable
to achieve the kappa numbers used to'
characterize the Option B technology. In
its July 1996 Notice, EPA described this
change and additional changes to the
cost model. See 61 FR at 36840-41 and
BAT Cost Model Support Document,
DCN 13953.
  In response to comments on the July
1996 Notice, EPA corrected mill-specific
information and made additional
changes to the cost model. See the.
Memorandum: Costing Revisions Made
Since Publication of July 15,1996
Notice of Availability, DCN 14493.
Among those changes was a correction
of errors in the costs of caustic and
hydrogen peroxide that resulted from a
unit conversion error (this error carried
through the proposal and the Notice
cost estimates). As a result of the
changes, including the correction made
to the cost of caustic and hydrogen
peroxide, the net engineering operating
and maintenance (O&M) costs for
Option B for all mills in the Bleached
Papergrade Kraft and Soda subcategory
increased from the savings of $7
million/year presented in the July 1996
Notice, to the $2 million/year increased
costs estimated today. See the
Supplemental Technical Development
Document, DCN 14487.
  For the purpose of estimating the cost
of the regulations, EPA excluded the
costs of process changes that: were either
completed or under .construction as of
mid-1995. EPA incorrectly stated in the
July 1996 Notice that costs for process
changes committed to but not yet under
construction as of mid-1995 were also
excluded from the cost of this
regulation. These latter costs have been
included. See the Supplemental
Technical Development Document, DCN
14487.
  (iii) Final Cost Estimates of the
Options Considered. EPA's final cost
estimates for Option A and E! for the
Bleached Papergrade Kraft and Soda
subcategory (BAT, PSES, and BMPs)
follow in Table VI-1.

TABLE    VI-1.—TOTAL    BLEACHED
  PAPERGRADE"  KRAFT   AND  SODA
  SUBCATEGORY  CAPITAL AND ENGI-
  NEERING  O&M  COSTS  FOR  BAT,
  PSES AND BMPS
            [1995 dollars]

Capital ($ million) 	
Rnal cost
estimates
Option
A
966
Option
B
2,130

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             Federal Register/Vol. 63, No. 72/Wednesday; April 15,  1998/Rules and  Regulations'      18545
 TABLE .   VI-1.—TOTAL    BLEACHED
   PAPERGRADE   KRAFT   AND  SODA
   SUBCATEGORY  CAPITAL AND ENGI-
   NEERING O&M  COSTS FOR  BAT,
   PSES AND BMPs—Continued
              [1995 dollars]

Engineering O&M ($
rnillion/yr) 	 .

Final cost
estimates
Option
A
113
Option
,B
2.02
   For both Option A and Option B, EPA
 excluded costs for the use of dioxin- and
 furari-precursor-free defoamers,
 adequate wood chip size control/and
 efficient biological wastewater treatment
"in its estimates of the costs of the final
 BAT technology options. These
 processes represent current industry
 practice. See the Supplemental
 Technical Development Document, DCN
 14487. However, EPA's estimate of the
 costs of BAT also includes a general
 allowance for increased technical
 supervision and process engineering
 that could be used, in part, to design
 and implement a chip quality control
 program or to improve operation of:
 existing biological wastewater
 treatment. In addition, any mill not
 currently using dioxin- and furan-
 precursor-free defoamers can use them
 without incurring significant costs. See
 the Supplemental Technical
 Development Document, DCN 14487.    .
 EPA evaluated the costs of retrofitting
 U.S. bleached papergrade kraft and soda
 mills to TCP bleaching to provide
 perspective on the likelihood of TCP
 processes being found to be
 economically achievable once they are
 shown to be technically available. EPA
 investigated the costs of two TCP bleach
. sequences. These bleach sequences
 included all common elements that are
 part of Option A and Option B   ,
 (adequate chip thickness control, closed
 brownstock pulp screen room operation,
 use. of dioxin- and furan-precursor-free
 defoamers, effective brownstock
 washing, elimination of hypochlorite,
 oxygen- and peroxide-enhanced
 extraction, use of strategies to minimize
 kappa factor and dioxin- and furan-
 precursors in brown stock pulp, high-
 shear mixing during bleaching, and
 efficient biological wastewater
 treatment). The bleaching sequences
 also include medium-consistency
 oxygen delignification. One TCP bleach
 sequence was based on peroxide
 bleaching (OQPP) and the other was
 based on ozone and peroxide bleaching
 (OZEopQPZP). EPA's final cost estimates
• for TCP bleach sequences for the total
 Bleached Papergrade Kraft and Soda
 subcategory (BAT, PSES, and BMPs) are
 as follows. See the Supplemental
 Technical Development Document, DCN
 14487.

 TABLE    VI-2.—TOTAL   BLEACHED
   PAPERGRADE   KRAFT  AND  SODA
   SUBCATEGORY CAPITAL AND  ENGI-
   NEERING O&M COSTS OF TCP OP-
   TIONS FOR BAT, PSES, AND BMP
  "  '         [1995 dollars]

Capital ($ million) ...
Engineering O&M
($million/yr) 	

Estimated costs
Perox-
ide-
TCF
(OQPP)
3,090
660
Ozone-TCF
(OZEopQPZP)
5,630
849
  (3) Effluent Reductions Associated
with Technology Options Considered.
The Agency estimated the effluent
reductions for the Bleached Papergrade
Kraft and Soda subcategory that will
result from the BAT options it analyzed.
"these estimated reductions are
summarized in this section and are
discussed in more detail in the
Supplemental Technical Development,
Document, DCN 1448'7.
  As discussed in the July 1996 Notice,
EPA recalculated the effluent reduction
benefits using a new baseline of mid-
1995. See 61 PR at 36840. In addition,
EPA revised and simplified the
methodology used to estimate that
baseline (using a model mill approach).
Id. EPA also used a second approach to
estimate the effluent loads of dioxin and
furan using data for individual mills as
compiled in the NCASI 1994 Dioxin
Profile (see DCN 13764). The baseline
calculation methodology revisions,
along with details of the effluent
reduction calculations, are described in
record section 22.6.
  As explained in DCN 14487, after July
1996, EPA again recalculated the
effluent reductions. The baseline
remains mid-1995. As before, EPA used
one-half of the minimum level specified
in 40 CFR 430.01 (i) or one-half of the
reported detection limits to estimate
effluent discharge loadings when
pollutant concentrations were below
minimum levels. EPA considers this a
reasonable approach for estimating mass
loads because the actual concentration
of the sample is too small to measure by
current analytical methods, but is
between zero and the detection limit.
Furthermore, ECF processes use and
generate chlorinated compounds, so
EPA expects that chlorinated
compounds were present (i.e., with a
concentration value greater than zero) in
the samples. Thus, EPA believes that it
is appropriate to substitute a value at
the midpoint between zero ,and the
detection limit (i.e., the upper bound of
the concentration in the sample) for ECF
mills. The methodology was modified
slightly for mills that use TCP bleaching
sequences. Because chlorinated
compounds are riot used and are not
generated by TCP processes, EPA
assumed that TCP mills would
discharge zero kilograms per year of  '
AOX and the individual chlorinated
pollutants rather than an amount
equivalent to one-half the minimum
level or detection limit multiplied by an
appropriate production-normalized flow
rate.
  EPA's revised baselines, which were
again found to be comparable to
NCASI's industry-wide estimates fpr
dioxin and furan, were used to calculate
effluent reductions summarized in •
Table VI-3. The table shows the
estimated baseline and the reduction
from baseline expected if the option
were implemented by all the existing
direct discharging mills in the
subcategory (i.e., those mills to which
BAT will apply). The slightly greater
removals of the bleach plant pollutants  ,
by Option B are a result of the reduced
bleach plant flow found at mills
employing Option B technology.
 TABLE VI-3.—BASELINE DISCHARGES AND ESTIMATED REDUCTIONS OF POLLUTANTS FOR BLEACHED PAPERGRADE KRAFT
                    AND SODA MILLS COMPLYING WITH BAT TECHNOLOGY OPTIONS CONSIDERED3
Pollutant parameter
2,3,7,8-TCDD 	 	 	 1 	
2,3,7,8-TCDF 	 	 	 	 	
Chloroform 	 •. 	
Units
Q/VT
o/vr
kko/vr
Mid-1995
baseline -.'•
discharge
140
105
43.6
Estimated
reductions:
option A
9 88
98 0
35.5
Estimated
reductions:
option B
m R
QQ K
3R fi
Estimated
reductions:
., TCP
H A r\
•inc
43 fi

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 18546      Federal Register/Vol. 63. No.  72/Wednesday, April 15. 1998/Rules and Regulations
 TABLE Vl-s.-
-BASELINE DISCHARGES AND ESTIMATED REDUCTIONS OF POLLUTANTS FOR BLEACHED PAPERGRADE KRAFT
 AND SODA MILLS COMPLYING WITH BAT TECHNOLOGY OPTIONS CONSIDERED «—Continued
Pollutant parameter
12 Chlorinated phenolic pollutants 	
AOX 	

Units
kko/vr
kka/vr

Mid-1995
baseline
discharge
51 7
QO -inn

Estimated
reductions:
option A
423
oo mri

Estimated
reductions:
option B
A A 1
0-7 onn

Estimated
reductions:
TCP
ctf 7
oo qnn

  •Tha TCP calculations assumed that chlorinated pollutants will not be present. For all other calculations, EPA assumed that pollutants reported
 as "not detected" were present in a concentration equivalent to one-half the minimum level specified in 40 CFR 430.01 (i) or one-half of the re-
 ported detection limit.
  The effluent reductions described and
shown above are used in Section VH to
estimate reduced human health and
environmental risk attributable to
today's rules. These estimates also form
the basis for estimating monetized
benefits in Section Vm. •
  (4) Development of Limitations. The
proposed BAT regulations included
limitations for dioxin, furan, 12
chlorinated phenolic pollutants,
acetone, chloroform, methyl ethyl
ketone (MEK), and methylene chloride
(based on BAT process changes); and
limitations for color, COD, and AOX
(based on BAT process changes and
biological wastewater treatment). In
today's rule, EPA is promulgating
limitations for dioxin, furan, 12
chlorinated phenolic pollutants,
chloroform, and AOX. See 40 CFR
430.24 (a) (1). As discussed in Section
VI.B.3. above, EPA is not promulgating
limitations for acetone, MEK., methylene
chloride, or color. EPA intends to
promulgate effluent limitations
guidelines and standards for COD in a
later rulemaking.
  In addition to the new effluent
limitations guidelines and standards for
the Bleached Papergrade Kraft and Soda
subcategory promulgated today and
discussed immediately below, mills in
this subcategory continue to be subject
to existing limitations and standards for
pentachlorophenol and trichlorophenol
(now denominated as supplemental
limitations and standards). These mills
continue to have the opportunity to be
exempt from these supplemental
limitations and standards if they certify
to the permitting or pretreatment
authority that they are not using these
chemicals as biocides. See 40 CFR
430.24(d).
  Except where noted, the following
discussion of BAT limitations also
applies to EPA's procedures for setting
NSPS. PSES, and PSNS for Subpart B.
  (a) Performance Data. EPA revised the
proposed limitations and standards
based on data collected after proposal
(see Pulp and Paper Mill Data Available
for BAT Limitations Development, DCN
13951) and presented the revisions in
                         the July 1996 Notice. See 61 FR at
                         36841-42. Today's.TCDF, chloroform,
                         and AOX limitations and standards
                         have been further revised since the July
                         1996 Notice as a result of the selection
                         of data sets used for the long-term
                         averages, variability factors, and
                         limitations. See DCN 14494, 14496, and
                         Record Section 22.5. The rationale for
                         changes in the data set selections is
                         provided immediately below. See DCN
                         14487.
                          . (i) Dioxin, Furan, and Chlorinated
                         Phenolic Pollutants. For non-TCF mills,
                         EPA had proposed mass-based
                         limitations and standards for furan; 'in
                         July 1996, EPA presented preliminary
                         revised limitations and standards that
                         were concentration-based. EPA has
                         determined that a limitation on the
                         concentration of furan is a more direct,
                         and hence, a more reasonable
                         measurement of the presence of furan
                         than a mass-based limitation would be.
                         When  detected, furan typically is
                         present in the effluent of Subpart B
                         mills that use EGF bleaching at levels at
                         or only slightly above the minimum
                         level specified in the applicable
                         analytical method. In this case, the
                         value of mass-based limitations and
                         standards are predominantly influenced
                         by the variability in the bleach plant
                         effluent flow rate and thus may not be
                         a consistent and reliable measurement
                         of the presence of furan.  Since the July
                         1996 Notice, EPA has used one
                         additional data set to calculate the furan
                         limitation; this data set was from an  .
                         Option B bleach line with a typical
                         unbleached kappa number of 20.
                         Because of this change and because of
                         changes to assumptions used in the
                         statistical analysis and changes to the
                         computer programs,' see Section
                        ,VI.B.5.a(4)(b),  the value of the furan
                         limitations and standards has changed
                         slightly from that presented in the July
                         1996 Notice.
                           EPA has made no changes to the
                         limitations for dioxin and the 12
                         chlorinated phenolic pollutants
                         presented in the July 1996 Notice. Upon
                         further review after the July 1996
                         Notice, EPA discovered that some
sample-specific minimum levels for
some chlorinated phenolic pollutants
were incorrectly entered into the
databases. These values have been
corrected. See DCN 14496, and Record
Section 22.5.
  EPA has determined that TCP
bleaching processes do not result in the
generation of dioxin, furan, chloroform
or chlorinated phenolic pollutants. For
this reason, EPA is not setting
limitations for these pollutants as part of
the voluntary alternative BAT
limitations and standards promulgated
today for mills that certify to the use of
TCP bleaching processes. See 40 CFR
430.24(a)(2).
  (ii) AOX. In the July 1996 Notice, EPA
presented preliminary revised AOX
BAT limitations and NSPS for non-TCF
mills.
  In the July 1996 Notice, EPA
indicated that although it was
presenting revised limitations and
standards it would continue to analyze
data from two mills representing the
performance of BAT Option A. These
data were submitted to EPA by the
industry without sufficient time for the
results to be reflected in the preliminary
limitations and standards presented in
the July 1996 Notice.
  Commenters encouraged EPA to use
the newly acquired data for the two
Option A mills, but also questioned why
certain other data in the record were not
used to develop the preliminary revised
AOX limitations and standards. EPA
continued its analysis of the new data
and obtained new information about
mill operations associated with the
other data addressed by comments. As
a result, EPA added data from the two
Option A mills to the data used to
characterize the performance of Option
A and added data from two other mills
to the data used to characterize the
performance of Option B. EPA
ultimately used data from six mills to
develop the AOX limitations for each
option, including at least one mill for
each option for which long-term
monitoring data (for about one and a
half years) were available. The mills
used to represent each option pulp

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              Federal Register/Vol. 63. No.  72/Wednesday. April  15."1998/Rules and Regulations       18S47

 primarily softwood and most of them
 subsequently bleach the pulp to high
 brightness (i.e., greater than 88 ISO).
 Tables presented in DCN 14494 show
 several statistics for each mill (reflecting
 the mill characteristics during the
 sampling period), including furnish,
 kappa number, kappa factor, brightness,
 type of wastewater treatment system,
 and approximate AOX removal in the
 treatment system. For a discussion of
 EPA's development of pretreatment
 standards for AOX, see section
 ,VLB.5.c(6).         "
   Another factor that has contributed to
 revisions in today's AOX limitations
 and standards is the adjustment for
 autocorrelation in the data. See DCN
 14496. EPA intended that this
 adjustment be made to the preliminary
 AOX limitations presented in the July  .
 1996 Notice; however, comments on
 that notice stated correctly that this
 adjustment had been excluded from the
 calculations. This oversight has been
 corrected in the calculations of today's
 final AOX limitations and NSPS.
   Since proposal, EPA has gathered
 additional data in order to establish a
 final limitation for AOX for TCP
 bleaching processes. See 40 CFR
 430.24(a)(2). EPA sampled at two mills
 with TCP bleaching processes, one U.S.
 mill and one European mill. Analytical
 data from sampling these twt> mills
 during periods representative of TCP
 processes indicate that AOX
 concentrations were consistently below
 minimum levels in bleach plant
 wastewaters. See DCN 14494 and DCN
 14488. Therefore, EPA has concluded
 that TCP bleaching processes are
 capable of achieving concentrations less
,than the minimum level for AOX in
 process wastewaters, whether measured
 at the bleach plant or after secondary
 biological treatment, and is setting AOX
 limitations and standards accordingly
 for TCP bleaching processes. See 40 CFR
 430.24(a)(2).
   (iii) Chloroform. EPA proposed a
 monthly average chloroform limitation
 of 2.01 g/kkg based on sampling results
 from one mill that used extended
 delignification and cpmplete
 substitution of chlorine dioxide for
 elemental chlorine, and that did not use
 hypochlorite during bleaching. Data
 collected by EPA after proposal
 indicated that bleach plant loads of
 chloroform did not differ between mills
 that used conventional pulping (Option
, A) and extended delignification (Option
 B), as long as bleaching was carried out
 without elemental chlorine or
 hypochlorite. However, these data
 indicate that the type of pulp washers
 used in a mill's bleach plant influence
 the partitioning of chloroform between
 the air and effluent. Use of low air flow
 washers results in less emission of
 chloroform to the air and greater loads
 of chloroform in bleach plant effluent
 than use of high air flow washers. See
 DCN 14494. In general, modern low air
 flow washers (such as pressure
 diffusion) also use less water to
 accomplish equivalent washing, i.e.,
 they are more efficient than
 conventional vacuum drum washers
 (high air flow washers). See DCN 14494,
 and DCN 14497, Vol. I. Because of their
 efficient use of water and their potential
 to reduce non-water quality
 environmental impacts, EPA encourages
 industry to use modern low air flow
 washers. For this reason, EPA
 developed revised chloroform
 limitations and standards using only
 data from mills that use low air flow
 washers. In the July 1996 Notice, EPA
 presented a revised bleach plant -
 monthly average chloroform limitation
 of 2.80 g/kkg. This limitation was
 developed using data from four mills
 that did not use 'elemental chlorine or
 hypochlorite during bleaching, and that
 used low air flow bleach plant washers.
   EPA received comments that the
 revised chloroform limitations and
 standards were not consistently
 achievable by mills with the process
, technologies serving as the basis for
 Options A and B. As a result of these
 'comments, EPA re-evaluated the
 chloroform limitations and standards
 presented in the July 1996 Notice.
   EPA has revised the long-term average
 and variability factors used to calculate
 the chloroform limitations and
 standards after considering data from .
 five mills that did not use elemental
 chlorine or hypochlorite during
 bleaching and that used low air flow
 bleach plant washers (data from four of
 these mills were used in the July 1996
 • Notice). In developing the long-term
 average, EPA used data from two mills
 that bleach pulp to a high brightness (88
 to 90 ISO). In developing the variability
' factors, EPA also considered data from
 the other three mills with low air'flow
 washers to obtain a more realistic
 estimate of variability associated with
 operating low air flow washers. Two of
 these mills bleach pulp to a lower
 brightness (8.0 to 85 ISO). EPA believes
 that the resulting limitations and
 standards can be met by all well-
 operated and maintained ECF mills
 regardless of the type of bleach plant •
 washers used. (EPA's revised bleach
 plant monthly average chloroform
 limitation is now 4.14 g/kkg.) The data
 in the record indicate that it is highly
 unlikely that a mill employing
 elemental chlorine or hypochlorite in its
 bleach  plant could comply with the
  chloroform limitations promulgated in
  this rule. See DCN 14494.
    (iv) COD. As discussed in VI.B.S.d.,
  EPA is reserving limitations for COD at
  this time.
    (b) Changes to Statistical
  Methodology. After the July 1996
  Notice, EPA performed a detailed
  review of the results of the statistical
  analyses, the documentation of the
  statistical methodology, the computer
  programs, and the data for all of the
  limitations and standards.  As a result of
  this review, EPA revised the
  assumptions regarding statistical
  analysis of data to ensure that long-term
  averages for TCDF and chloroform were
  greater than or equal to the minimum
  level of the analytical methods. EPA
  made other revisions to the statistical
  assumptions and the computer
  programs that resulted in minor changes
  to the values of the limitations and
:  standards. All of these revisions are
  identified and described in the
  Statistical Support Document for the
  Pulp and Paper Industry: Subpart B,
  DCN 14496. In the record, EPA has also
  provided detailed responses to
  comments about the statistical
  methodology. See DCN 14497, Vol. VI.
    (c) Definition of Limitations -and
  Standards Expressed at Less Than the
  Minimum Level. In today's rulemaking,
  EPA is establishing limitations and
'  standards for Subparts B and E for 12
  chlorinated phenolic pollutants and
  dioxin that are expressed as less than
  the minimum level ("
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18548
Federal Register/Vol. 63, No. 72/Wednesday, April 15,  1998/Rules and Regulations
relative to those analytes. See 40 CFR
430.01 (i). In the proposal and the July
1996 Notice, EPA referred to the ML
limitations as "ND limitations." EPA
has changed the terminology, but not
the concept, in response to comments
that the terminology was potentially
misleading. This section provides a
discussion of ML limitations.
Compliance with the ML limitations is
discussed in Section VI.B.8.c(2).
  EPA expects that future analytical
methods will be more sensitive than
today's methods, and their minimum
levels will have values that are less than
those for the analytical methods
identified today in § 430.01(i). However,
the analytical methods (and their
                          minimum levels) specified in §430.01(i)
                          were used to chemically analyze the
                          wastewaters from mills with the BAT,
                          NSPS, PSES, and PSNS model
                          technologies selected today for Subparts
                          B and E. EPA used the data from these
                          chemical analyses to determine that
                          today's ML limitations Were technically
                          and economically achievable. EPA is'
                          unable to determine, based on the data
                          from these chemical analyses, whether
                          more stringent limitations (that is,
                          limitations with values or associated
                          with minimum levels less than the
                          minimum levels published today in
                          § 430.01) would be technically and
                          economically achievable. To determine
                          whether the technologies are capable of
achieving more stringent limitations,
EPA would need to evaluate data from
chemical analyses using these future
more sensitive methods. Those data
obviously are not available today. Until -
any further revision of today's
limitations and standards for subparts B
and E, the limitations for these analytes
will continue to be associated with the
minimum levels specified today in
Section 430.0 l(i).
  Table VT-4 identifies the analytical
methods used to generate the data for
today's rule. The minimum levels in
this Table are established by the
analytical methods and have; been
validated by use. ,
               TABLE VI-4.—ANALYTICAL METHODS AND MINIMUM LEVELS FOR REGULATED POLLUTANTS
Pollutant
2378-TCDD '
2,3.7,8-TCDF 	 	 	
Trichlorosyringol 	 	 	 	 	
3 4,5-trichlorocatechoI 	 	 	 . ...; 	
3,4,6-trichlorocatechol 	 	
3,4,5-trichloroguaiacoI 	 	 	
3,4,6-trichloroguaiacol 	 .'. 	
4,5,6-trichIoroguaiacoI 	 .. 	 	 	
2,4,5-trichIorophenol 	 	 	 	
2,4,6-trichlorophenol 	 	 	 ....: 	 : 	
Tetrachlorocatechol 	 '. 	
Tetrachloroguaiacol 	 	 	 	 	
2,3,4,6-tetrachlorophenol 	 	 	
Pentachlorophenol 	 	 	
AOX 	 	 	
Method
1613
1613
1653
1653
1653
1653
1653
1653
1653
1653
1653
1653
1653
1653
1650
Minimum
level
10 DO/L-
ID pq/L
2.5 ug/L
5.0 uq/L
5.0 ug/L
2.5 ug/L
2.5 ug/L
2.5 ug/L
2.5 UQ/L
2.5 uq/L
5.0 uq/L
5.0 ug/L
2.5 ug7L
5.0 ug/L
20 ug/L
  (d) Limitations. Table VI-5 presents
the final effluent limitations for Options
A and B for the Bleached Papergrade
                          Kraft and Soda subcategory that are
                          based on in-plant process changes.
                          These limitations are based on data
obtained from bleach plant effluent
prior to mixing with other mill
wastestreams.
       TABLE VI-5.—BLEACHED PAPERGRADE KRAFT AND SODA LIMITATIONS COMPARISON OF OPTIONS A AND B

TCDD (pg/L) 	
TCDF(pg/L) 	
Chlorinated Phenolic Pollutants* (ug/L) 	 	 	
Chloroform (o/kkq) 	 	 	 	
Daily maximum limitation
Option A

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             Federal  Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules and Regulations      18549
monthly average limitation would be
based on the assumption that a mill
would be required to monitor more
frequently than once a month. For the
reasons set forth in (Section
VI.B.8.c(4)(b), EPA believes that one
monthly monitoring event is sufficient;
however, if permitting or pretreatrrient
authorities choose to require more
frequent monitoring for furan, they may
set monthly average limitations and
 standards based on their best
 professional judgment. See, e.g., 40 CFR
 430.24(a)(l), footnote b. Today's rule
 requires mills to monitor for chloroform
 four times per month (i.e., weekly);
 therefore, both daily maximum and
 monthly average limitations are
 presented.
   EPA has, also calculated both daily
 maximum and monthly average
 limitations for AOX based on Option A,
 Option B, and TCP bleaching processes.
 These limitations are presented in Table
 VT-6. Today's rules require AOX to be
 monitored every day during the month.
 See 40 CFR 430.02(a). Annual average
 limitations for AOX apply only to non-
 continuous discharges. The alternative
 TCP effluent limitations.apply only to
 AOX and are expressed as "
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 18550
Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules and  Regulations
is economically achievable for the
Bleached Papergrade Kraft and Soda
subcategory as a whole for several
reasons. When EPA considered the
effect of BAT/PSES compliance in light
of the MACTI rule on subpart B mills,
EPA estimated that the selected BAT/
PSES Option would cause two mill
closures, with related direct loss of 900
jobs and a S275 million decrease in
shipments, and no firm failures that are
likely to result in additional job loss.
(See Section Vffl.F and Table Vffl-4 for
other economic impacts associated with
the selected BAT/PSES option, with and
without MACT I compliance costs.) The
number of closures (two) is less than 3
percent of the affected mills (86) in the
subcategory. The loss of jobs associated
with these closures is about one percent
of subcategory employment. EPA
believes that, even with these projected
impacts, the selected BAT/PSES is
economically achievable for this
subcategory as a whole. When the cost
of the MACT I rule on subpart B mills
is not considered, the selected BAT/
PSES would cause one mill closure and
no firm failures they are likely to result
in additional job loss. See Section
Vffl.E. For confidentiality reasons,
related losses of jobs and shipments
cannot be disclosed in this Federal
Register notice, but are described in the
CBI portion of the record.
  EPA concluded that Option B is not
economically achievable for the
Bleached Papergrade Kraft and Soda
subcategory as a whole. When EPA
considered the effect of BAT/PSES
compliance in light of the MACT I rule
on subpart B mills, EPA estimated that
Option B would cause four mill
closures, with a related direct loss of up
to 4.800 jobs, and a $1.3 billion decrease
in shipments, and one or more firm
failures that are likely to result in
additional job loss. (See Section Vffl.F
and Table VIII-4 for other economic
impacts associated with Option B with
and without MACT I compliance costs.)
EPA estimates that when the cost of the
MACT I rule is not considered, Option
B would cause two mill closures, with
a related direct loss of 900 jobs and a
S275 million decrease in shipments, and
one or more firm failures. See Section
vm.F.1.
  While the increased number of
closures and related job losses
associated widi Option B are strong
indicators of economic unachievability, .
the potential firm failures (i.e.,
bankruptcies) associated with this
Option are particularly problematic. For
each option, EPA's bankruptcy analysis
focuses on whether each affected
company can afford to make the
collective investment required to install
                          the technology upon which the option
                          is based for all of its facilities. The
                          substantially higher capital cost
                          associated with Option B results in the
                          potential failure of one or more firms
                          that Option A  does not cause. In most
                          cases, requirements to raise capital to
                          upgrade each mill to meet Option B
                          limitations and standards may seriously
                         jeopardize some companies' ability to
                          cover interest on the new investments as
                          well as other costs. In other words, some
                          companies with insufficient cash or
                          equity resources to cover the costs of
                          these upgrades may be in jeopardy of
                          bankruptcy. It  takes an event of
                          considerable magnitude to induce
                          bankruptcy in  a firm. The fact that
                          Option B, even when considered
                         .without regard for the  impact of the
                          MACT I rule on this subpart, .is
                          projected to drive one  or more firms into
                          bankruptcy indicates to EPA the
                          significant magnitude of Option B's
                          capital requirements. In EPA's view, the
                          overall effect of Option B on those firms
                          would be substantial. See Section YELP.
                          For a more detailed discussion of EPA's
                          firm failure analysis, see the Economic
                          Analysis, Chapter 6 (DCN 14649).
                            The magnitude of the effects that may
                          arise from large firm bankruptcies is a
                          substantial indicator of the economic
                          unachievability of Option B. The
                          negative effects are indefinite and
                          unquantifiable, but EPA has reason to
                          believe, based  on the recent history of
                          the domestic pulp and paper industry,
                          that they are likely to be significant. The
                          effects include, as examples, stock price
                          turmoil, reduced workforces, and
                          foreign ownership of formerly
                          American-owned assets.  Which impacts
                          occur would depend on the responses of
                          the potentially affected firm(s) to the
                          increased costs. Companies that enter
                          bankruptcy or  near-bankruptcy are more
                          likely to see their stock prices fall,
                          causing substantial loss of investor
                          value and possibly becoming the target
                          of a hostile takeover by a domestic or
                          foreign company. Recent history of
                          hostile or friendly takeovers shows that
                          the acquiring companies subsequently
                          divested themselves of unproductive
                          assets, closed a number of mills and
                          eliminated over 15,000 jobs, affecting
                          both smaller and larger communities,
                          with the most  devastating consequences
                          on the smaller communities. Some
                          companies may downsize some
                          operations without closing any mills,
                          thus potentially causing job losses in
                          communities that depend on the mills
                          direcfly or indirectly for their economic
                          well-being. The potential job losses
                          associated with the likely firm failure(s)
                          represent an unacceptably large portion
of the employment losses associated
with this option for the Bleached
Papergrade Kraft and Soda subcategory.
See DGN 14379, 14382, and 14388
(contained in CBI record). In addition,
weaker companies might be forced to
sell off blocks of assets, or their
corporate existence might be
endangered. Companies may choose to
close marginal plants to avoid the cost
of upgrade or to sell off mills both to '
avoid the costs of upgrade and to raise
capital to upgrade the remaining mills.
Closed mills' equipment could be sold
to overseas companies, who could
initiate low cost pulp or paper
production and gain market share from
U.S. firms as a result. Foreign
companies acquiring U.S. mills might
close or alter those mills to gain market
share (although such behavior is not
necessarily economically efficient).
Substituting foreign for domestic
production means an additional loss of
jobs and income for Americans. See
Economic Analysis, Chapter 6 (DCN
14649).
  EPA also considered the effects of
delaying the implementation of Option
B for five years. EPA acknowledges that
the uncertainties of the pulp and paper
market and the financial circumstances
of individual firms make questionable
the validity of any assumptions
regarding the relative effects of a five-
year delay. EPA's evaluation of delaying
the implementation of Option B for five
years involves consideration of
discounting Option B costs for five
years, the expected industry price and
revenue cycle, and resulting aggregate
costs, closures, and firm failures. EPA
has determined, due to expected effects
of the industry cycle, that deferring the
costs of this technology for five years
would not appreciably reduce the
economic impacts for this subcategory
as a whole compared to immediate
compliance. See Economic Analysis,
Chapter 6 (DCN 14649). For example,
EPA found that under the most likely
scenario (in which the costs of
complying with MACT I are taken into
account), the same number of mills
(four) would be predicted to close even
if implementation of Option B were
delayed for five years. Firm failure
predictions could not be made for five
years hence because the analysis is
based on several financial components,
each of which may change dramatically
and unpredictably in the interim.
  Based on the above discussion, EPA
concludes that only the selected BAT/
PSES technology option—Option A—is
economically achievable today for the
Bleached Papergrade Kraft and Soda
subcategory as a whole. EPA
acknowledges that the number of

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              Federal Register/Vol. 63, No. 72/Wednesday, April  15,  1998/Rules  and Regulations      18551
  predicted closures attributable to Option
  B, when considered without regard for
  the impact of the MACTI rule on
  subpart B mills, is the same as the
  number of predicted closures under
  Option A when MACT I impacts are
  considered. (This is also true for job
  losses and effects on shipments.)
  However, EPA does not believe that
  these impacts alone are a compelling
  decision'basis for this rulemaking. Not
  only would such an analysis fail to
  account for the real-world economic
  impacts of the concurrent MACT I
  rulemaking, but the closures and related
  impacts by themselves fail to express
  the total economic impacts EPA predicts
  for Option B. For the reasons described
  above, EPA concludes that it is
  appropriate to take into account the
  potential firm failures attributable to
  Option B in this rulemaking. Further,
  EPA concludes that it is appropriate in
  this rulemaking to base the economic
  acbievability determination on the total
  economic impacts (the closures and the
  projected firm failures, coupled with
  predicted regional and market impacts)
  of its BAT/PSES options on the
  industry. Those total economic impacts
  constitute the principal and deciding
  difference between the selected BAT/
  PSES technology basis and Option B.
  Based on that conclusion, EPA has
  determined that only  Option A is
  economically achievable for subpart B  •
' as a whole, both when the impacts of
  compliance with the MACT I rule are
  considered and when they are not.
    EPA is also rejecting Option B
  because its capital costs are simply too
  high when compared  to Option A.
  Implementation of Option B would  •
  result in capital costs  that are more than
  $1 billion greater than those associated
  with Option A. EPA believes that this
  consideration is particularly relevant in
  this rulemaking for several reasons.
  First, these Cluster Rules represent the
  fourth, set of effluent limitations
  guidelines and standards promulgated
  for subpart B mills. Since 1977, the
 . industry has incurred substantial capital
  costs to achieve its current level of
 ' pollutant control and  has achieved
  significant pollutant loading reductions.
  This is also the first pulp and paper
  regulation to employ process changes,
  rather than treatment  technologies, as
  the core of its model BAT/PSES
  technology. EPA is authorized, in the
 ' exercise of its discretion, to consider
  these factors as the Administrator deems
  appropriate in selecting BAT. See CWA
  section 304 (b) (2) (B). For all of these
  additional reasons, EPA has concluded
  that Option B is not the best available
technology economically achievable for
subpart B at this time.
  EPA also evaluated the economic
.achievability of TCF process
technologies for subpart B mills. EPA
concluded that the annualized cost of
retrofitting existing sources for TCP is
substantially greater than the
annualized cost of Option B (regardless
which bleaching chemicals 'are used),
with additional impacts ranging from
seven estimated closures and 7,100 job
losses to the potential that a greater
number of firms would be placed in
jeopardy of bankruptcy. See Section
YELP. (When this option is considered
in light of MACT I compliance costs, the
economic impacts would be even
greater. See id.) EPA, therefore,
concluded that TCF bleaching processes
are not economically achievable for the
subcategory as a whole at this time.
Nevertheless, EPA is promulgating
voluntary alternative BAT limitations
and PSES based on TCF bleaching
processes in order to encourage mills to
use this technology whenever possible.
See 40 CFR 430.24(a)(2), 430.26(a)(2).
  EPA determined that Option A is the^
best technology because no other option
that was both available and
economically achievable resulted in
greater reductions in effluent loadings
for dioxin, furan and other significant
pollutants of concern. (See 58 FR at
66110 for other options considered at
proposal.) For a discussion of the
effluent reduction benefits associated
with Option A, see Section VIE. G.
  (6) Point of Compliance Monitoring.,
EPA is requiring mills in subpart B to
demonstrate compliance with BAT
limitations for dioxin, furan,
chloroform, and 12 chlorinated phenolic
pollutants inside the discharger's
facility at the point where the
wastewater containing those pollutants
leaves the bleach plant. EPA is
authorized by the Clean Water Act and
EPA's regulations at 40 CFR 122.44(i),
122.45(h), and 125.3(e)  to specify an in-
plant point of compliance monitoring'
for technology-based limitations.
Hereafter, EPA refers to the BAT
limitations for which compliance must
be demonstrated in-plant as,"in-plant
limitations." As set forth in more detail
below, EPA is establishing in-plant
limitations on bleach plant effluent
because limitations imposed on those
pollutants at the point of discharge are ,
impractical and infeasible as measures
of the performance of process
technologies representing the
technology-based levels of control.
Moreover, in-plant effluent limitations
are consistent with the MACT standards
for chloroform, which independently
require achievement of BAT limitations
 on dioxin, furan, chloroform and the 12
 chlorinated phenolic compounds at the
 bleach plant (in addition to compliance
 with AOX limitations) in order to  -
 ensure that the removals represented by
 the MACT technology floor—complete
 substitution of chlorine dioxide for
 elemental chlorine and elimination of
 hypochlorite—are attained.
 . -Mills using the model BAT
 technology, described in section
 VI.B.5.a(l), are able to achieved the
 bleach plant concentrations of dioxin
 and the 12 chlorinated phenolic  '
 pollutants at levels below the minimum
 levels of currently available analytical
 methods. Furan concentrations, in turn,
 are very near the analytical minimum
 levels. (At the end of the pipe, furan in
 many mills' effluent cannot be detected
 by available analytical methods.)
  'Because only 10 to 40 percent of the
 wastewater discharged by mills in
 subpart B originates in the bleach plant,
 (see the Supplemental Technical
 Development Document, DCN.14487)
 the concentrations of pollutants in the
 final effluent would be one-tenth to two-
 fifths of their concentrations at the
 bleach plant. In the biological
 wastewater treatment system, the
 pollutants may be present but in
 concentrations below the applicable
 analytical minimum levels. When they
 are discharged to receiving streams,
 however, dioxin and furan
 bioaccumulate in aquatic organisms.
 Were EPA to allow compliance
 monitoring of the final effluent, there
 would be no way to determine whether
 the bleach plant effluent has been
 adequately controlled or whether the
 effluent has simply been diluted below
 the analytical minimum level by the
 other flows. Diluting pollutants in this
 manner rather than preventing their
 discharge is inconsistent with achieving
 the removals represented by the
 technology-based levels of control, and
 hence with the purpose of the BAT"
 limitations. It is also inconsistent with
 the goals of the Clean Water Act in
 general. See sections 101 (a) and
 301 (b)(2)(A). While no mill is required
 to install EPA's model BAT technology,
 establishing limitations at the bleach
 plant is the only way EPA can ensure
 that none of these pollutants will be
 discharged at Concentrations greater
 than the levels achievable through
 implementation of the best available
 technology. See E.I. du Pont de
 Nemours & Co. v. Train, 430 U.S. 112,
 129 (1977).
  With respect to the 12 chlorinated
 phenolic pollutants, EPA acknowledges
 that these pollutants could be degraded
by biological treatment of the facility's
 combined wastewater. However, the

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same process technologies necessary to
address dioxin and furan also reduce
the levels of chlorinated phenolic
pollutants to concentrations below
minimum levels at the bleach plant.
Commenters have supplied no data
showing that the chlorinated phenolic
pollutants should or indeed, as a
practical matter, could be segregated
from the dioxin- or furan-bearing
wastestreams in order to utilize a mill's
secondary treatment system fully. Nor is
there any assurance that BAT
limitations for these pollutants, if
monitored at the end of the pipe, would
be achieved by treatment rather than
simply by the effects of dilution. See 40
CFR 122.45(h). Thus, EPA believes that
it is appropriate to require compliance
monitoring for the BAT limitations on
the 12 chlorinated phenolic pollutants
at the point they most easily can be
achieved and measured—at the bleach
plant.
  In the case of chloroform, in-plant
limits are authorized by 40 CFR
122.45(h) because they offset the effects
of dilution, in this case, the occurrence
of uncontrolled volatilization. In other
regulatory contexts, EPA recognizes that
dilution includes not only mixing a
pollutant of concern with other
wastestreams, but also mixing it with
excess air in the form of uncontrolled
volatilization. See 52 FR 25760, 25778-
79 (July 8,1987). Volatilization, like
dilution, does nothing to remove,
destroy, or immobilize pollutants, and
for this reason is not in itself a form of
treatment, id. at 25779. The policy
reasons supporting .that principle in the
hazardous waste context similarly apply
here.
  Finally, EPA is setting effluent
limitations at the bleach plant in order
to avert the non-water quality
environmental impacts caused by the
volatilization of chloroform to the air
and in order to be consistent with its
Clean Air Act determination that the
MACT floor for chloroform consists of
bleach plant process modifications, i.e.,
complete chlorine dioxide substitution
and elimination of hypochlorite as
bleaching agents. Specifically, EPA is
requiring under the Clean Air Act that
chloroform emissions be controlled by
complying with the BAT requirements
for all regulated pollutants. See 40 CFR
63.445(d). Therefore, EPA has
determined under its Clean Air Act
authority that bleach plant
technologies—and bleach plant
limitations on dioxin, furan, chloroform
and the 12 chlorinated phenolics—are
necessary to regulate air emissions of
chloroform. The situation presented
here is very different from the situation
EPA faced when promulgating effluent
                          limitations guidelines and standards for
                          the organic chemicals, plastics and
                          synthetic fibers industrial category in
                          1987. See 52 FR 42522, 42658-62 (Nov.
                          5, 1987). In that rulemaking, the issue
                          before EPA was whether to use in-plant
                          limitations and standards to regulate air
                          emissions of certain volatile and semi-
                          volatile pollutants; EPA chose not to set
                          in-plant requirements for that purpose
                          because it determined that the
                          regulation of such emissions was best
                          accomplished in a Clean Air Act
                          proceeding, which EPA was
                          commencing at that time. See 52 FR at
                          42560-62. In contrast, EPA in this
                          rulemaking integrated its decision-
                          making under the Clean Water Act and
                          the Clean Air Act expressly to address
                          these cross-media issues. Taking into
                          account both the air and water
                          objectives of these Cluster Rules, EPA
                          therefore concludes that it is highly
                          appropriate for EPA to set effluent
                          limitations under the Clean Water Act to
                          correspond to and support its
                          concurrent regulation of air emissions
                          under the Clean Air Act.
                            b. New Source Performance
                          Standards. (1) Background^ The Agency
                          proposed to revise NSPS for the
                          Bleached Papergrade Kraft and Soda
                          subcategory. New mills have the
                          opportunity to incorporate the best
                          available demonstrated technologies,
                          including process changes, in-plant
                          controls, and end-of-pipe treatment
                          technologies.
                            (a) Definition of "New Source". EPA
                          had proposed supplemental definitions
                          of the term "new source," as provided
                          in National Pollutant Discharge
                          Elimination System (NPDES) permit
                          program regulations found at 40 CFR
                          122.2 and 122.29, for the pulp and
                          paper industry only. See 58 FR at
                          66116-17. EPA is codifying a definition
                          of "new source" in  Part 430 for subparts
                          B and E. See 40 CFR 430.0 l(j). The new
                          definition provides that new source
                          performance standards are triggered by
                          new "greenfield" mills, complete
                          replacements of entire fiber lines (e.g.,
                          pulping and bleaching), or the
                          construction of a new source whose
                          processes are substantially independent
                          of an existing source, such as a new
                          fiber line built to supplement an
                          existing fiber line. Specifically excluded
                          from the definition  of new source are
                          existing mills that modify existing fiber
                          lines for purposes of complying With
                          either BAT limitations or PSES, and
                          existing mills that replace entire fiber
                          lines in order to comply with Advanced
                          Technology BAT limitations. For more
                          details, see Section VI.B.8.a(2).
                            (b) Proposed NSPS. EPA proposed
                          NSPS for toxic and  nonconventional
 pollutants for the Bleached Papergrade
 Kraft and Soda subcategory based on the
 combination of both oxygen
 delignification and extended cooking
 followed by 100 percent substitution of
 chlorine dioxide for elemental chlorine
 and elimination of hypochlorite
 (identified at proposal as Option 5). The
 proposed technology bases for NSPS
 also included the other elements
 described as part of BAT in VI.B.5.a(l).
 EPA also proposed NSPS for BOD5 and
 TSS based on the single best
 demonstrated end-of-pipe secondary
 wastewater treatment system. See 58 FR
 at 66116-18, 66197. To encourage
 continuing innovation in the
 development of processes to reduce or
. eliminate the discharge of pollutants
 from the Bleached Papergrade Kraft and
 Soda subcategory, EPA also proposed
 alternative NSPS limits for mills
 adopting TCP processes. See 58 FR at
 66111.
   (2) Options Considered. In addition to
 the option proposed for NSPS, EPA
 considered three other options for the
 technology basis of NSPS for toxic and
 nonconventional pollutants. These
 options "are summarized below. For
 further discussion of these options, see
 the Supplemental Technical
 Development Document, DCN 14487.
 The first alternative option is identical
 to BAT Option B, described above. This
 revised NSPS option includes extended
 delignification (i.e., oxygen
 delignification and/or extended
 cooking) to produce softwood pulps
 with a kappa number of approximately
 equal to or less than 20 (approximately
 13 for hardwoods), followed by
 complete (100 percent) substitution of
 chlorine dioxide for elemental chlorine
 and elimination of hypochlorite for
 bleaching. EPA concluded that there are
 no performance differences between the
 proposed NSPS option and this revised
 option. See the Supplemental Technical
 Development Document, DCN 14487.
   EPA also considered an ECF
 technology used at two U.S. mills
 consisting of oxygen delignification
 followed by ozone bleaching,-enhanced
 extraction, and final chlorine dioxide
 brightening. This technology is used to
 produce pulps of somewhat lower
 brightness than market pulps. Finally,
 the Agency considered a TCF process
 technology that one U.S. mill is
 currently using to produce pulps with
 brightness up to 83 ISO.
 •  For conventional  pollutants, EPA -
 considered the proposed NSPS option
 based on the single best available
 demonstrated end-of-pipe  secondary
 wastewater treatment and a second
 option based on the best available
 demonstrated performance of a

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             Federal Register/Vol. 63. No. 72/Wednesday,  April 15,  1998/Rules and Regulations
                                                                    18553
 secondary wastewater treatment system
 as characterized by the average of the
 best 50 percent of the existing mills in
 the subcategory.
  (3) Option Selected, Pollutants
 Regulated, and Costs. EPA is
 promulgating NSPS for the Bleached
 Papergrade, Kraft and Soda subcategory
 for toxic and nonconventional
 pollutants based on the NSPS option
 equivalent to BAT Option B. EPA has
 determined that Option B technology
 represents the best demonstrated control
 technology, process, operating method,
 or other alternative available at this
 time. The toxic and nonconventional
 pollutants regulated by NSPS are the
 same as those regulated by BAT. For
 further discussion of the NSPS model
 technology, the Supplemental Technical
 Development Document, DCN 14487.
  EPA rejected as possible NSPS
 technologies the technologies that have
 not been demonstrated to achieve full
 market pulp specifications. EPA knows-
•of two ECF bleach lines using ozone-
 based bleaching in the U.S. One line
 uses an OZE0DD bleach sequence to
 bleach hardwood to 83 GE brightness
 (less than 82 ISO). The other line uses
 an OZEoD bleach sequence to bleach
 softwood to 84 ISO, somewhat less than
 full market brightness. EPA collected
 data from this  line that confirm that
 OZEoD bleaching results in-much lower
 water use and  pollutant loadings than
 either  Option A or Option B. Because of
 this level of performance, EPA strongly
 encourages further development of
 ozone-based bleaching sequences—as
 part of either EGF or TCF sequences. It
 is possible that lines using ozone-based
 bleaching sequences will achieve the
 AOX limits promulgated as part of the
 Voluntary Advanced Technology
 Incentives Program, which is described
 in Section IX of this Notice.
  With respect to TCP bleaching
 processes, several non^U.S. mills have
. reported the production of TCF
 softwood kraft pulp at full market
 brightness. However, EPA's data are not
 sufficient to confirm that TCF bleaching
 processes are technically demonstrated
 for the full range of market products
 currently served by the kraft process.
 EPA is also unable to define a segment
 of the Bleached Papergrade Kraft and
 Soda subcategory for which TCF
 bleaching processes are known to be
 technically feasible arid thus could be
 the basis for NSPS. EPA believes that
 progress being made in developing TCF
 bleaching processes is substantial,
 however, and that additional data may
 demonstrate that TCF processes are
 indeed available for the full range of
 market products. To 'this end, elsewhere
 in today's Federal Register Notice, EPA
 is inviting additional data and comment
 on the full range of market
 specifications currently being achieved
 for TCF kraft pulp  (e.g., brightness,
 strength, and cleanliness). EPA will
 evaluate whether the performance of
 this technology will result in greater
 removals than the performance of the
 NSPS technology option being selected
 today. Depending on these findings,
 EPA will determine whether to propose
 revisions to NSPS based upon TCF and,
 if appropriate, flow reduction
 technologies.
  In addition to NSPS relating to the
 Voluntary Advanced Technology
 Incentives Program, which is discussed
 below in this section, EPA is also
 promulgating alternative NSPS for
 Bleached Papergrade Kraft and Soda
 mills voluntarily choosing to use TCF
 technologies. See 40 CFR 430.25 (b) (2).
  For the conventional pollutants BODs
 and TSS, EPA is basing NSPS upon the
 best available demonstrated
 performance of a secondary wastewater.
 treatment system as characterized by the
 average of the best  50 percent of the
 existing mills in the subcategory. EPA
 has determined that the performance of
 the single best mill does not account for
 all sources of process-related variability
 in conventional pollutant generation
 and treatability expected in the entire
 subcategory, including raw materials
 (i.e., furnish), process operations, and
 final products. In selecting the final
 NSPS technology basis for conventional
 pollutants, EPA found it necessary to
 consider the secondary wastewater
 treatment performance of the best 50
 percent of the existing mills in this
 subcategory in order to ensure that the
 resulting standards reflect the full range
 of processes and raw materials to
 produce the full range of products
 coyered'by this subcategory. For further
 discussion, see the Supplemental
 Technical Development Document, DCN
 14487, and DCN 14497, Vol. I and H. '
  EPA is not revising NSPS for pH for
.subpart B; however, for the convenience:
 of the permit writer, EPA has recodified
 the 1982 NSPS for pH as part of the
 table of newly promulgated NSPS for
 toxic, non-conventional, and other '
 conventional pollutants. See 40 CFR
 430.25(b).
  In selecting its model NSPS
 technologies, EPA considered all of the
 factors specified in CWA section 306,
 including the cost of achieving effluent
 reductions. The incremental capital cost
 of complying with  the selected NSPS for
 all pollutants, as compared to the costs
 of complying with  standards based on
 the next best technology, BAT Option A,
 is only 0'.5 to 2.0 percent of the total
 capital cost of constructing either a new
source fiber line at an existing mill or
a new gfeenfield mill. Moreover, the
process technologies that form the basis
for NSPS result in lower pollutant
loadings requiring biological treatment.
Loadings of BODs from a bleach line
employing NSPS will be approximately
30 percent lower than loadings from a
conventional bleach line. Compared to
the cost of treating wastewater from a
conventional bleach line to meet current
BPT/BCf effluent .limitations
guidelines, the cost of treating
wastewater from a NSPS bleach line to
meet NSPS for conventional pollutants
will be the same or lower. Finally, as of
mid-1995 there are 14 existing mills
representing approximately 16 percent
of the bleached papergrade kraft
production that employ the Option B   ,
technology. For these reasons, EPA
concludes that the costs of complying
with NSPS for toxic, non-conventional
or conventional pollutants do not
present a barrier to entry. See the
Supplemental Technical Development
Document, DCN 14487. See also Section
Vm  and Chapter 6 of the Economic
Analysis, DCN 14649.
  The Agency also considered energy
requirements and other non-water
quality environmental impacts for the
selected NSPS option. EPA concluded
that  increased chemical recovery and
reduced energy consumption and
operating costs would occur for this
option. EPA also concluded that non-
water quality environmental impacts
were only marginally different than for
the selected BAT technology option and
are acceptable. Thus, EPA concluded
that  none of the statutory factors
justified selecting a different NSPS
model technology than the one chosen.
See Section VII. See also the
Supplemental Technical Development
Document, DCN 14487.,
  EPA is also promulgating NSPS as
part  of the Voluntary Advanced
Technology Incentives Program with
standards set at the Tier n and'Tier ffl
levels. See 40 CFR 430.25(c). For a
discussion of this program, see Section
IX. A new source may choose to enroll
in the Voluntary Advanced Technology
Incentives Program at the Tier II or Tier
HI NSPS level and therefore to commit
to achieve those standards at the time it
commences operation. Alternatively, a
new source may choose to commence
operation at the compulsory NSPS level
and then later, enroll in the Incentives
Program at the Tier n or Tier in level as
an existing source, or enroll in the
Incentives Program once Tier H or Tier
HI limitations are achieved.
  Finally, EPA notes that the previously
promulgated NSPS for the biocides
pentachlorophenol and trichlorophenol

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continue to apply to all new sources.
See40CFR430.25(d).
  (4) Limitations and Point of
Compliance Monitoring. EPA is
promulgating NSPS for dioxin, furan,
chloroform, the 12 chlorinated phenolic
pollutants, and AOX for Subpart B at
the levels set forth in Tables VI-5 and
                         VI-6 for BAT Option B. See 40 CFR
                         430.25(b)(l). For a discussion of EPA's
                         development of those standards
                         (presented in the context of possible
                         BAT limitations derived from Option B
                         technologies), see Section VI.B.5.a(4).
                         The numerical values of today's NSPS
                         for BODS and TSS for the Bleached
 Papergrade Kraft and Soda subcategory
 have been revised from those provided
 in the July notice. For a discussion of
 these changes, see the Statistical
 Support Document, DCN 14496. The
 final NSPS for BOD5, TSS and pH are
 presented in Table VI-7 below.
     TABLE VI-7.—NEW SOURCE PERFORMANCE STANDARDS FOR CONVENTIONAL POLLUTANTS FOR THE BLEACHED
                                  PAPERGRADE KRAFT AND SODA SUBCATEGORY
                                                     NSPS
Pollutant or
pollutant property
BOD5 	 ; 	 	 	 	 	 -
TSS 	
pH 	 	 	
Continuous
dischargers
Maximum for
any 1 day
(kg/kkg)
4.52
8.47
(1)
Monthly aver-
age (kg/kkg)
2.41
3.86
(1)
Non-
continuous
dischargers
.Annual aver-
age (kg/kkg)
1.73
2.72
(
  1 Within the range of 5.0 to 9.0 at all times.
  EPA is requiring mills to demonstrate
compliance with the NSPS for dioxin,
furan, chloroform and the 12
chlorinated phenolic pollutants inside
the discharger's facility at the point
where the wastewater containing those
pollutants leaves the bleach plant. See
40 CFR 430.25(e). EPA bases this
decision on the reasons discussed in
Section VI.B.5.a(6) for BAT limitations.
EPA is not specifying a point of
compliance monitoring for AOX, BODs,
TSS, pH, or the biocides.
  c. Pretreatment Standards for Existing
Sources (PSES) and Pretreatment
Standards for New Sources (PSNS). (1)
Background. EPA proposed the same
technology option for PSES as it did for
BAT. This proposed option would have
set PSES for the same pollutants
controlled by BAT. For new indirect
discharging facilities. EPA proposed .
that PSNS be set equal to NSPS for the
toxic and nonconventional pollutants.
At proposal, EPA also discussed three
options for implementing the
pretreatment standards. See 58 FR at
66123-25. EPA also solicited comment
on whether pretreatment standards for
BODs and TSS were warranted to ensure
that pass-through of these and other
pollutants (e.g., AOX) did not occur.
  (2) Pass-through Analysis for PSES
and PSNS. EPA promulgates
pretreatment standards for pollutants  .
that pass through or interfere with
POTWs. EPA performed a pass-through
analysis as part of this rulemaking,
which is summarized below. See also
the Supplemental Technical
Development Document, DCN 14487.
EPA has determined for subpart B mills
that dioxin, furan, chloroform, the 12
                         chlorinated phenolic pollutants, and
                         AOX pass through POTWs. Therefore,
                         the Agency is promulgating PSES and
                         PSNS for these pollutants. See 40 CFR
                         430.26(a)(l) and 430.27(a)(l).
                           EPA's record shows that both direct
                         discharging mills and POTWs accepting
                         wastewaters from pulp and paper mills
                         in the Bleached Papergrade Kraft and
                         Soda subcategory operate secondary
                         biological treatment systems. The
                         indirect discharging mills in this
                         subcategory contribute the majority of
                         the pollutant loading and up to 90
                         percent of the flow to these POTWs.
                         (EPA refers to these POTWs as
                         "industrial POTWs.") EPA has reviewed
                         data available in the record for BODs
                         and TSS, among other pollutants, and
                         has determined that the biological
                         treatment systems at these POTWs are
                         comparable to the biological treatment
                         systems operated by direct discharging
                         mills in subpart B. See the
                         Supplemental Technical Development
                         Document, DCN 14487.
                           EPA reviewed all available data in the
                         record to conduct a pass-through
                         analysis. EPA compared the percent of
                         removals achieved by subpart B  mills
                         implementing the BAT technologies to
                         the percent of the same pollutants
                         removed by the industrial POTWs
                         receiving effluent from subpart B mills.
                         EPA's record shows that dioxin and
                         furan are not removed by biological
                         treatment systems and so are not
                         removed by the POTW. Therefore, these
                         pollutants pass through untreated and
                         are discharged to receiving streams,
                         where dioxin and furan bioaccumulate
                        - in aquatic organisms. EPA bases this
                         conclusion on data reported in the"'104-
 Mill Study," which EPA undertook in
 cooperation with industry in 1988/89.
 That study shows that direct
 discharging bleached papergrade kraft
 and soda mills operating secondary
 biological treatment systems (without
 the addition of bleach plant process
 controls) discharge dioxin and furan in
 detectable quantities. When mills in that
 subcategory later implemented bleach
 plant process changes and controls
 comparable to the model BAT
 technologies considered in
 promulgating today's BAT effluent
 limitations guidelines, the data show
 that dioxin and furan discharges
 dropped below the minimum level at
. which those pollutants can be reliably
 measured. This was the case even where
 there was no concurrent change to the
 secondary biological treatment systems.
 (Indeed, EPA's candidate BAT
 technologies assume secondary
 biological treatment systems operating
 at the 1989 level). Because, as discussed
 above, the industrial POTWs receiving
 effluent from bleached papergrade kraft
 and soda mills operate biological
 treatment systems that are comparable
 to those operated by direct discharging
 mills in the "104-Mill Study," EPA
 concluded that subpart B mills
 implementing the selected in-plant BAT
 model technology achieve substantially
 greater reductions of dioxin and furan
 than industrial POTWs can achieve
 from effluent not subject to BAT-level
 process controls. EPA finds that in the
 absence of PSES equivalent to BAT
 levels of control, dioxin and furan
 would pass through POTWs. EPA also
 believes that the presence of these
 pollutants in the POTWs' secondary

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             Federal Register/Vol. 63, No. 72/Wednesday,  April 15, 1998/Rules and Regulations
                                                                   18555
, sludge could possibly interfere with
 their sludge disposal options.
   For chloroform, EPA also evaluated
 the removal efficiencies achieved by
 POTWs by comparing the removals
 achieved by direct discharging mills
 using BAT process technologies to the
 removals achieved .by POTWs receiving
 effluent from subpart B mills. The
 record shows that, without the BAT
 process changes, a very high percentage
 of chloroform volatilizes from
 collection, conveyance, and aeration
 systems. EPA has consistently refused
 in these circumstances to regard such  •
 transfers of pollutants from wastewater
 to air as treatment. See, e.g., 59 FR
 50638, 50665 (Sept. 28, 1993)
 (pesticides chemicals guidelines); 58 FR
 36872, 36886-88 Only 9, 1993) (organic
 chemicals, plastics; and synthetic fibers
 guidelines). Therefore, because of this
 volatilization of chloroform in the     ..
 absence of bleach plant process changes,
 the quantity of chloroform actually
 available to be removed by the POTWs'
 secondary treatment works is less than
 the quantity of that pollutant removed
' by the direct discharger employing BAT.
 Accordingly, EPA concludes that there
 is pass-through of chloroform in the
 absence of pretreatment standards for
 this pollutant, as well as unacceptable
 non-water quality environmental
 impacts from air emissions. For a
 detailed discussion of chloroform
 volatilization, see Section 8.8 of the
 Supplemental Technical Development
 Document, DCN 14487, and the Air
 Docket, No. A-92-40, Item IV-A-8.
   EPA's determination that the
 chlorinated phenolic pollutants pass
 through the POTW is based on data in
 the record showing that the selected
 BAT process technology option (Option
 A) reduces all 12 of the chlorinated
 phenolic pollutants to concentrations
 less than minimum levels for these
 pollutants in bleach plant wastewaters,
 prior to end-of-pipe biological
 wastewater treatment systems. While
 biological wastewater treatment systems
 comparable to POTW treatment systems
 have been found to remove a  portion of
 these chlorinated phenolic pollutants,
 the removals achieved are less than the
 removals achieved by the BAT process
 changes alone. Therefore, because
 overall chlorinated phenolic pollutant
 removals with implementation of the
model BAT technologies are
substantially greater than removals
achieved by POTWs, chlorinated
phenolic pollutants pass through
POTWs.
  EPA has also determined that AOX
passes through. EPA bases this
conclusion on its review of all available
data regarding removals of AOX
achieved by industrial POTWs that
receive a majority of their flow or a
majority of their BODS or TSS loadings
from indirect dischargers covered by
subpart B. Although the data show that
the performance of these POTWs in
removing AOX is comparable to the
performance of end-of-pipe biological
treatment systems operated by direct
dischargers in this subcategory, the data
also show that direct dischargers
meeting limitations based on the model
BAT technology consistently achieve far
greater AOX removals than biological
treatment alone can achieve (e.g., at a
POTW). (See the Supplemental
Technical Development Document, DCN
14487.) Therefore, in the absence of
pretreatment standards analogous to
BAT, the affected POTWs receiving
pulp and paper wastewaters cannot
achieve the same overall removals of
AOX as achieved by direct dischargers
complying with the BAT limitations for
AOX. The same is also true when
considering removals achieved by new
sources complying with NSPS.
Therefore^ contrary to the preliminary
finding in the July 1996 Notice, EPA
concludes that AOX passes through
POTWs and is setting pretreatment
standards for AOX for new and existing
indirect discharging mills. See 40 CFR
430.26(a)and430.27(a).
  The pretreatment standards
promulgated today for AQX are
equivalent to the AOX loadings present
in the bleach plant wastewaters of mills
employing the BAT/NSPS" technologies
prior to biological treatment systems at
direct discharging mills. EPA expects
that removals achieved by indirect
dischargers employing the PSES or
PSNS model technology, in combination
with removals achieved by biological
treatment systems at POTWs, will be
comparable to the removals achieved by
direct dischargers complying with BAT
limitations or NSPS.
  In reviewing the information available
in the record for the pollutants BODs
and TSS, EPA concluded that pollutant
reductions attained by direct
dischargers' biological wastewater
treatment systems and by POTWs
accepting similar wastewaters are .
comparable and that pass-through of
these pollutants does not occur. As a
result, EPA is not promulgating national
PSES or PSNS for BOD5 and TSS for the
Bleached Papergrade Kraft and Soda
subcategory. Other regulatory
authorities may determine^ based on a
site-specific review of treatment system
performance, that locally imposed limits
are necessary to prevent the POTW from
violating its NPDES permit. See 40 CFR;
403.5.
  (3) Options.Considered. In this final
rule, EPA considered the same process
technology options and best
management practices for PSES and
PSNS as it did for BAT and NSPS. In a
change from the proposal, EPA did not
consider for PSES/PSNS the biological
treatment technology that forms part of  ..
the candidate BAT and NSPS
technologies. Since proposal, EPA has
made new findings with respect to the  >
pass-through of BOD5 arid TSS. EPA has
also received comments indicating that
the lack of sufficient land for the
installation of biological treatment at
some indirect dischargers makes such
systems infeasible and unavailable. This
finding, combined with EPA's finding
that biological wastewater treatment
systems at POTWs treating pulp and
paper wastewaters are comparable to the
biological wastewater treatment systems
operated by direct discharging mills in
subpart B, has lead EPA to conclude
that biological wastewater treatment
should not be included as part of the
PSES or PSNS candidate technologies.
  (4) Effluent Reductions. As discussed
in Section VI.B.5 .a. (3) above, after
proposal EPA recalculated the effluent
reductions attributable to its PSES
technology options using a new baseline
of mid-1995. See the Supplemental
Technical Development Document, DCN
14487.             ,
  Table VI-8 shows the estimated
baseline and the reduction from
baseline expected if the presented
options were implemented by all the
existing indirect discharging mills in the
subcategory (i.e., those mills to which
PSES will apply).
 TABLE Vl-^.—BASELINE DISCHARGES AND ESTIMATED REDUCTIONS OF POLLUTANTS FOR BLEACHED PAPERGRADE KRAFT '
  ;    .                       AND SODA MILLS FOR TECHNOLOGY OPTIONS CONSIDERED3
Pollutant parameter
2,3,7,8-TCDD 	 , 	 	
Units
o/vr 	 	 	
Baseline '
' discharge
1.25
Estimated
reductions:
Option A '
0.92
Estimated
reductions:
Option B
1 nn
, Estimated
Reductions:
TCP1
1 OR

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 18556      Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules and Regulations

 TABLE VI-8.—BASELINE DISCHARGES AND ESTIMATED REDUCTIONS OF POLLUTANTS FOR BLEACHED PAPERGRADE KRAFT
                       AND SODA MILLS FOR TECHNOLOGY OPTIONS CONSIDERED3—Continued
Pollutant parameter
2,3,7,8-TCDF 	

12 Chlorinated phenolic pollutants 	
AOX 	
Units
o/vr
kkd/vr
kkg/yr 	
kko/vr 	
Baseline'
discharge
947
4 89
3.58
3.010
Estimated
reductions:
Option A
894
4 28
281
2.100
Estimated
reductions:
Option B
9 04
A. 9R
297
2.600
Estimated
Reductions:
TCP
9 47
- A QQ
3 58
3.O10
  «The TCP calculations assumed that chlorinated pollutants will not be present. For all other calculations, EPA assumed that pollutants reported
as "not detected" were present in a concentration equivalent to one-half the minimum level of the analytical method.
  (5) PSES/PSNS Option Selection. EPA
Is promulgating PSES and PSNS for
dioxin, furan, chloroform, 12
chlorinated phenolic pollutants, and
AOX based on the process technologies
that form the bases for BAT and NSPS,
respectively.
  The Agency considered the age, size,
processes, other engineering factors, and
non-water quality environmental
impacts pertinent to Subpart B mills in
developing PSES/PSNS. None of these
factors provided any basis for
establishing different PSES/PSNS. EPA
has no data to suggest that the
combination of technologies upon
which today's PSES/PSNS are based
results in unacceptable non-water
quality environmental impacts.
  Because the costs of the selected BAT
and PSES model technologies are
attributable solely to process changes,
the costs for an existing indirect-
discharging bleached papergrade kraft
and soda mill to comply with PSES are
comparable to a similar direct-
discharging bleached papergrade kraft
and soda mill. See Section VI.B.5.a(2).
As discussed in Section VI.B.5.a(5), EPA
found PSES based on BAT Option A to
be economically achievable. Similarly,
EPA considered the cost of the PSNS
technology for new mills (based on BAT
Option B) and determined that such
costs do not present  a barrier to entry,
as reflected in the barrier to entry
discussion for NSPS in Section
VLB.5.b(3).
  The rationale for choosing BAT
Option A as the basis for PSES is set
forth in Section VI.B.5.a(5). The
rationale for selecting NSPS Option B as
PSNS is the same as  that provided in
Section VLB.S.b for selecting that model
technology as the basis for NSPS for this
subcategory. Although for the reasons
set forth in those sections EPA is not
selecting TCP bleaching processes as the
model technology for PSES or PSNS,
EPA nevertheless is promulgating
voluntary alternative pretreatment
standards based on TCP bleaching
processes in order to encourage mills to
use those processes when possible. See
40 CFR 430.26(a)(2) and 430.27(a)(2).
  The pretreatment standards for the
Bleached Papergrade Kraft and Soda
subcategory also include best
management practices. See 40 CFR
430.03. These regulations are described
in Section VI.B.7. For a discussion of
the pass through of pollutants
controlled by BMPs, see Section VI.B.7.
In addition, the previously promulgated
PSES and PSNS for former subparts G,
H, I and P for the biocides
pentachlorophenol and trichlorophenol
continue to apply unless the discharger
certifies that it does not use those
compounds as biocides. See 40 CFR
430.26(b) and 430.27(b).
  (6) Limitations. With the exception of
AOX, the limitations promulgated as
PSES for Subpart B are identical to
those promulgated as BAT limitations
for this subpart. See 40 CFR
430.26(a)(l).,For a discussion of the
development of those pretreatment
standards see Section VI.B.5.a(4).
  EPA found that while end-of-pipe
biological treatment systems at
industrial POTWs and at direct
dischargers achieve comparable
removals of AOX, the total AOX
removals achieved by direct discharging
mills are greater because of the process
changes that are part of the model BAT/
PSES technologies. Therefore, EPA has
established AOX pretreatment standards
based on the performance of process
changes alone (biological treatment is
not a component of PSES/PSNS). EPA
has developed AOX limits for PSES
based on bleach plant data for eight
mills that employ the process
technologies incorporated in Option A.
These pretreatment standards are
presented in Table VI-9,
TABLE VI-9.—BLEACHED PAPERGRADE
   KRAFT  AND  SODA  SUBCATEGORY
   PSES AOX LIMITATIONS
Pollutant parameter
AOX 	

Daily
maximum
limitation
(kg/kkg)
2.64

Monthly
average
limitation
(kg/kkg)
1 41

  Similarly, with the exception of AOX,
the PSNS promulgated for Subpart B for
toxic and nonconventional pollutants
are identical to the NSPS promulgated
for this subpart. See 40 CFR
430.27(a) (1). For a discussion of the
development of those pretreatment
.standards, see  Section VI.B.5.a(4). EPA
has developed AOX limits for PSNS
based on bleach plant data for six mills
that employ the process technologies
incorporated in Option B. These
pretreatment standards are presented in
Table VI-10.

TABLE   Vl-10.—BLEACHED  PAPER-
  GRADE  KRAFT   AND  SODA  SUB-
  CATEGORY PSNS AOX LIMITATIONS
Pollutant parameter
AOX 	

Daily
maximum
limitation
(kg/kkg)
1.16

Monthly
average
limitation
(kg/kkg)
0.814

  (7) Point of Compliance Monitoring.
For many of the same reasons set forth
in Section VI.B.5.a(6) above in
connection with EPA's decision to
specify an in-plant point of compliance
monitoring for many of the BAT
parameters, EPA is requiring indirect
discharging mills subject to Subpart B to
demonstrate compliance with
pretreatment standards for dioxin,
furan, chloroform, the chlorinated
phenolic pollutants, and AOX at the
bleach plant. See 40 CFR 430.26(c) 'and
430.27(c). As is the case for direct
dischargers, data for indirect
discharging mills show that standards
imposed at the point of discharge to the
POTW would make it impractical for
the permitting authority to assure that

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              Federal Register/Vol. 63, No.  72/Wednesday, April 15,  1998/Rules and Regulations
                                                                     18557
 the indirect discharger is achieving
 removal of the pollutants as required by
 the pretreatment standards. Moreover,
, EPA is concerned that dioxin and furan,
 even when present in nondetectable
 amounts at the point of discharge to the
 POTW, could pass through the POTW
 and accumulate in the biosolids, thus
 possibly interfering with the beneficial
 reuse of that biosolids material. The
 extent to which sludge can be
 beneficially reused is the subject of a
 separate ongoing rulemaking under
 CWA Section 405. Finally, under EPA's
 regulations, indirect dischargers are
 prohibited from substituting dilution for
 treatment, except where dilution is  .
 expressly authorized by the applicable
 pretreatment standard. See 40 CFR
 403.6(d). (That is not the case here.)
 This prohibition theoretically could be
 enforced on a pollutant-by-pollutant,
 case-by-case basis. However, EPA is -
 concerned that such a solution to the
 effluent's detection and dilution
 problems may impose an unnecessary
 financial and technical burden on
 POTWs.
   At the time of proposal, EPA
 proposed that compliance with PSES/
 PSNS AOX limitations would be
 demonstrated at the point of discharge'
 to the POTW. Since biological treatment
 is no longer part of the model
 technology for PSES/PSNS, AOX
 limitations based upon the performance
 of the PSES/PSNS technology are more
 appropriately set, and compliance
 demonstrated, at the bleach plant, prior
 to mixing with other wastestreams. This,
 will reduce the burden on the
 pretreatment authority in implementing
 the PSES/PSNS limitations, as no
 additional allowance will need to be
 factored into the AOX limitations that
 would apply due to sources of AOX
 beyond the bleach plant. In this respect,
 the decision to establish in-plant points
 of compliance monitoring for all PSES/
 PSNS regulated parameters also furthers
 the goals of the Unfunded Mandates
 Reform Act. For all of these reasons,
 EPA is  establishing in-plant points of
 compliance monitoring for PSES/PSNS
 on a nationwide level.
 6. Papergrade Sulfite Subcategory
   a. Segmentation of the Papergrade
 Sulfite  Subcategory. In this final rule,
 EPA is  dividing the Papergrade Sulfite
 Subcategory into three segments to
 better reflect product considerations, the
 variation in manufacturing processes,
 and the demonstration of pollution
 prevention process changes within the
 category for the purpose of establishing
 BAT, NSPS, PSES, and PSNS, EPA's
 reasons for doing so are discussed in the
 July  1996 Notice, 61 FR at 36844-45,
 and in paragraphs b(l)-(2) below. EPA
 is promulgating final effluent
 limitations guidelines and standards for
 each segment. The three segments are:
   (1) Production of pulp and paper at
 papergrade sulfite mills that use an
 acidic cooking liquor of calcium,
 magnesium, or sodium sulfite, unless
 those mills are specially grade sulfite
 mills.  See 40 CFR 430.5l(c)(l).,Mills in
 this segment are "calcium-, magne- •
 sium-, or sodium-based sulfite mills;"
   (2) Production of pulp and paper at
 papergrade sulfite mills that use an
 acidic cooking liquor of ammonium
 sulfite, unless those mills are specialty
 grade sulfite mills. See 40 CFR
 430.51 (e) (2). Mills in this segment are
 "ammonium-based sulfite mills;" and
   (3) Production of pulp and paper at
 specialty grade sulfite mills, or
 "specialty grade sulfite mills." Specialty
 grade sulfite mills are those mills where
 a significant portion of production is,
 characterized by pulp with a high
 percentage of alpha cellulose and high
 brightness sufficient to produce end
 products such as plastic molding
 compounds, saturating and laminating
 products, and photographic papers. EPA
 considers a significant portion of
 production to be 25 percent or more.
 The specialty grade segment also
 includes those mills where a major
 portion of production is 91 ISO
 brightness and above. EPA considers a
 major portion of production to be 50
 percent or more.
  See 40 CFR 430.51 (c) (3). In order to
 determine whether a sulfite mill belongs
 in the specialty grade segment,
 permitting authorities should consider
 the expected production mix over the
 full permit term. For mills that are
 converting to production in the
 specialty grade segment, EPA expects
 these mills will be subject to these
 limits prior to the time that these mills
 achieve the production mixes described
 above.
  b. BAT. (1) Options Considered. EPA
 had proposed BAT effluent limitations
 for AOX and COD for the entire
 Papergrade Sulfite Subcategory based on
 totally chlorine-free bleaching
' processes. Totally chlorine-free  (TCF)
 bleaching processes are bleaching
 operations that are performed without
 the use of chlorine, sodium or calcium
 hypochlorite, Chlorine dioxide, chlorine
 monoxide, or any other chlorine-
 containing compound. After concluding
 that the proposed technology was not
 demonstrated for the full range of
 products produced by mills using
 ammonium sulfite cooking liquor or for
 specialty grade products, EPA
 segmented the Subcategory and
 considered other BAT options as set
 forth below. EPA also included for all  ,
 segments the performance of existing
 secondary biological wastewater
 treatment as part of the basis for
 nonconventional and conventional
 pollutant effluent limitations and NSPS.
 For a more detailed discussion of these
. options, see the Supplemental
 Technical Development Document, DCN
 14487.
   (i) Calcium-, Magnesium-, or Sodium-
 Based Sulfite Mills. The technology
 option considered for papergrade sulfite
 products made by this segment was TCF
 bleaching, as proposed. See 58 FR at
 66114-15. Existing TCF mills in this
 segment produce the same products
 they had been able to produce using
 elemental chlorine-free (ECF)  bleaching
 processes, at up to 91 ISO brightness.
 Therefore, EPA did'not consider ECF
 bleaching as a technology option for this
 segment, because, while technically
 available and economically achievable,
 it was not the best such technology for
 this segment.
   (ii) Ammonium-Based Sulfite Mills.
 The technology options considered for
 this segment were TCF bleaching and
 ECF bleaching. ECF bleaching is any
 process for bleaching pulps that does
 not employ elemental chlorine or
 hypochlorite. There are numerous
 variations of ECF bleaching processes.
 The ECF process considered for the
 ammonium-based segment includes
 peroxide-enhanced extraction.
   (iii) Specialty Grade Sulfite Mills. The
 technology bases considered for this
 segment were TCF bleaching and ECF
 bleaching. The ECF process considered
 for the specialty grade segment includes
 oxygen- and peroxide-enhanced
 extraction.
   (2) Selection of BAT Technologies. In
 evaluating and selecting BAT
 technologies for the segments in this
 Subcategory, EPA considered the age,
 size, processes, other engineering
 factors, and non-water quality
 environmental impacts pertinent to
 Subpart E mills. None of these factors
 provided a basis for selecting different
 BAT technologies. For each segment,
 EPA selected the best technology   ,
 available to produce the products in
 each segment. Each of the selected BAT
 technologies is economically achievable
 and has no unacceptable adverse non-
 water quality environmental impacts.
 See the Supplemental Technical
 Development Document, DCN 14487.
 The reasons discussed below also
 support EPA's decision to select the
 BAT model technology for each segment
 as the basis for PSES  for that segment.  „
   (i) Calcium-, Magnesium-, or Sodium-
 Based Sulfite Mills. As proposed, EPA
 has concluded that TCF bleaching is the

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 18558      Federal Register/Vol. 63, No.  72/Wednesday, April 15, 1998/Rules and Regulations
appropriate technology basis for BAT
limitations for the calcium-,
magnesium-, or sodium-based segment
of the Papergrade Sulfite subcategory.
CThe following discussion also applies
to PSES.) For this segment, TCP
technology consists of oxygen- and
peroxide-enhanced extraction, followed
by peroxide bleaching, and with all
chlorine-containing compounds
eliminated (e.g., elemental chlorine,
hypochlorite, chlorine monoxide, etc.).
Although still TCP, the bleaching
sequence is a change from proposal,
when TCP bleaching was based on an
oxygen stage with peroxide addition,
foflowed by a peroxide bleaching stage.
This change to the TCP bleaching
sequence reflects the more common
approach to TCP bleaching within this
segment of the Papergrade Sulfite
subcategory and also reflects the
technology basis of the mill from which
TCP performance data have been
collected. EPA also included pulp
cleaning to ensure,that existing product
quality specifications would continue to
be achieved. EPA has selected this
technology because it is technically
available and economically achievable
for mills in this segment.
  In evaluating the technical availability
of TCP processes for this segment, EPA
developed a database of mills in the
United States and Europe that produce
pulp using TCP bleaching technology.
There is at least one mill in the United
States and 13 in Europe using acid
cooking liquors of calcium, magnesium,
or sodium sulfite that are using TCP
bleaching processes. Among them, these
mills produce a full range of paper
products at up to 91 ISO brightness
using TCP bleaching. These mills are
able to produce the same products using
TCP technology that they produced
prior to converting to TCP, with no
negative impact on product quality. EPA
has incorporated pulp cleaners as an
element of TCP technology to ensure
that pulp quality requirements are
maintained. See the Supplemental
Technical Development Document, DCN
14487. For these reasons, EPA
concluded that TCP bleaching is
technically available for the calcium-,
magnesium-, or sodium-based segment.
See the record at section 21.2.1. (As
noted above. EPA has established a
separate segment for specialty grade
sulfite  mills using these cooking
liquors.)
  In order to evaluate the economic
achlevability of TCP bleaching for this
segment, EPA considered the costs that
existing mills would incur to convert to
TCP processes. However, costs for
secondary biological treatment systems
have not been included because these
systems already are in place at direct
discharging mills. (This is true for the
other papergrade sulfite segments as
well.) As part of that analysis, EPA also
included the costs of complying with
today's BMP regulations. Because of the
small size of this segment, EPA is not
disclosing here the estimated capital
costs, operation and maintenance costs,
or post-tax annualized costs for this
segment in order to protect confidential
business information. However, EPA
has determined that no mills are
projected to close and no firms are
projected to fail as a result of today's
BAT limitations and PSES for this
segment. This result obtains both when
the impacts of today's BAT/PSES are
considered together with the impacts of
compliance with the MACTI costs, and
when they are considered alone.
Therefore, EPA has concluded that TCP
bleaching is. economically achievable for
the calcium-, magnesium-, or sodium-
based sulfite pulp segment.  See DCN
14376 and DCN 14388 (both CBI).
  For these reasons, EPA has selected
the model TCP bleaching processes
described above as the basis for BAT
limitations and PSES for the calcium-,
magnesium-, or sodium-based sulfite
pulp segment.
  (ii) Ammonium-Based Sulfite Mills.
EPA had proposed BAT based on TCP
bleaching technology for all mills in the
Papergrade Sulfite subcategory,
including those mills using ammonium-
based acidic cooking liquor. EPA
received comments and data
challenging the applicability of TCP
bleaching to ammonium-based sulfite
mills. After reviewing these comments
and data, EPA concluded that TCP
bleaching is not demonstrated and may
not be feasible for the full range of
products produced by ammonium-based
sulfite mills in the United States. See
DCN 14497, Vol. I. (The following
discussion also applies to PSES for this
segment.)
  This conclusion is based primarily on
the greater difficulty in bleaching
ammonium-based sulfite pulps
(especially those pulps derived from
softwood) without the use of chlorine-
containing compounds compared to
other sulfite pulps, and the inability to
maintain product specifications for
certain products within this segment
using TCP bleaching. TCP bleaching has
not been demonstrated for products
with a high percentage of ammonium-
based sulfite pulp that also require low
dirt count and high strength. Laboratory
scale data submitted by a firm
producing such products indicate that
such products can be produced with
elemental chlorine-free (ECF)
technologies. See DCN 14497, Vol. I,
DCN 14494, and DCN 14118 in the ,
record at Section 21.11.3.
  Therefore, for papergrade sulfite mills'
using an acidic cooking liquor of
ammonium sulfite, EPA is promulgating
BAT limitations and PSES based on an
ECF bleaching technology. The
technology basis for BAT limitations for
this segment is use of dioxin- and furan-
precursor-free defoamers, complete (100
percent) substitution of chlorine dioxide
for elemental chlorine, peroxide-
enhanced extraction, and elimination of
hypochlorite. ECF bleaching also
includes high shear mixing to ensure
adequate mixing of pulp and bleaching
chemicals. This technology basis
reflects the results of laboratory trials
showing the ability to produce the full
range of products manufactured by mills
in the ammonium segment, with
acceptable final product characteristics.
See the record at section 30.11, DCN
14497, Vol. I, and DCN 14494. (The only
exception is specialty grade sulfite mills
using ammonium cooking liqiuors.)
  EPA is also promulgating voluntary
alternative BAT limitations and PSES
based on TCP bleaching processes in
order to encourage mills to use this
technology whenever it is consistent
with their product mix. See 40 CFR
430.54(a)(2) and 430.56(a)(2).
Alternative TCP limitations are also
available for new sources in this
segment.
  In addition to finding that the ECF
bleaching process described above is
technically available for the ammonium-
based segment, EPA has also
determined that it is economically
achievable. In order to evaluate the
economic achievability of ECF
bleaching for  this segment, EPA
considered the costs that existing mills
would incur to convert to the ECF
process under consideration. As part of
that analysis,  EPA also included the
costs of complying with today's BMP
regulations. Because of the small size of
this segment,  EPA is not disclosing here.
the estimated capital costs, operation
and maintenance costs, or post-tax
annualized costs for this segment in
order to protect confidential business
information. However, EPA has
determined that no mills are projected
to close and no firms are projected to
fail as a result of today's BAT
limitations and PSES for this segment.
This result obtains both when the
impacts of today's BAT/PSES are
considered together with the impacts of
compliance with the MACT I costs, and
when they are considered alone.
Therefore, EPA has concluded that ECF
bleaching is economically achievable for
the ammonium-based segment. See DCN
14376 and DCN 14388  (both CBI).

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             Federal Register/Vol.  63, No. 72/Wednesday, April  15,  1998/Rules and Regulations
                                                                     18559
   For the foregoing reasons, EPA has
 selected the model ECF bleaching
 processes described above as the basis
 for BAT limitations and PSES for the
 ammonium-based segment.
   (iii) Specialty, Grade Sulfite Mills
   EPA received comments and data
 indicating that key pulp and product
 characteristics for specialty grade sulfite .
'pulps have not been achieved using TCP
 bleaching technologies. Firms
 producing specialty grade pulps
 indicate that required product
 characteristics are achievable using
 certain ECF bleaching technologies. See
 the record at sections 19.1 and 21.11.6;
 DCN 25502; DCN 20071a8; DCN 14497,
 Vol. I; and DCN 14494. As indicated in
 the July 1996 Notice, EPA has continued
 to monitor research efforts of specialty
 grade pulp producers in the field of
 pollution-rpreventing process changes.
 These research efforts have progressed
to the point where data are available at
 this time to promulgate limitations for
 this segment for dioxin, furan, and
 chlorinated phenolic pollutants. For
 specialty grade sulfite mills, the
 technology basis for limitations is use of
 dioxin- and furan-precursor-free
 defoamers, complete (100 percent)
 substitution of chlorine dioxide for
 elemental chlorine, oxygen- and
 peroxide-enhanced extraction, and
 elimination of hypochlorite. ECF
.bleaching also includes high shear
 mixing to ensure adequate mixing' of
 pulp and bleaching chemicals. This
 technology basis reflects the results of
 laboratory trials showing the ability to
 produce the full range of products
 manufactured by specialty grade mills,
 with acceptable final product
 characteristics. (This discussion also
 applies to PSES for this segment.)
   EPA is also promulgating voluntary
 alternative BAT limitations' based on
 TCF bleaching processes in order to
 encourage mills to use this technology,
 whenever it is consistent with their
 product mix. See 40 CFR 430.54(a) (3)
 and 430.56(a)(3). Alternative TCF
 limitations are also available for new
 sources in this segment.
   In addition to finding that the ECF   .
 bleaching process described above is
 technically available for the specialty
 grade segment, EPA has also determined
 that it is economically achievable. In
 order to evaluate the economic
 achievability of ECF bleaching for this
 segment, EPA considered the costs that
 the one mill currently in this segment
 would incur to convert to ECF       "
 processes. As part of that analysis, EPA
 also included the costs of complying
 with today's BMP regulations. Because
 of the small size of this segment, EPA
 is not disclosing here the estimated
capital costs, operation and
maintenance costs, or post-tax
annualized costs for this segment in
order to protect confidential business
information. However, EPA has
determined that the sole existing mill in
this segment is not projected to close,
nor is its firm projected to fail, as a
result of today's BAT limitations and
PSES for this segment. This result
obtains both when the impacts of
today's BAT/PSES are considered
together with the impacts of compliance
with the MACTI costs, .and when they
are considered alone. Therefore, EPA
has concluded that ECF bleaching is
economically achievable for the
specialty grade segment. See DCN 14376
and DCN 14388 (both CBI).
  For the foregoing reasons, EPA has
selected the model ECF bleaching  -
process described above as the basis' for'
BAT limitations and PSES for the
specialty grade segment.
  (3) Pollutant Parameters Regulated for
Each Segment, (i) Calcium-,
Magnesium-, or Sodium-Based Sulfite
Mills. Because the Agency is
promulgating BAT effluent limitations.
for this segment based on TCF bleaching
technology, the maximum reduction in
the discharge of chlorinated pollutants
from bleaching operations will be
achieved. This is because no chlorine or
chlorine-containing bleaching chemicals
are used and, hence, no chlorinated
pollutants are generated during
bleaching. For this reason, EPA is not.
setting effluent limitations for dioxin,
furan, chloroform, or the 12 specified
chlorinated phenolic pollutants for TCF
bleaching. However, EPA is setting
limitations on AOX (expressed as a level
below the Minimum Level identified in
today's analytical method for AOX) for
mills in the calcium-, magnesium-, or
sodium-based sulfite pulp segment of
the Papergrade Sulfite subcategory in
order to reflect the performance of TCF
bleaching processes. See 40 CFR
430.54(a) (1). EPA is reserving
promulgation of COD limitations for this
segment until such time that sufficient
performance data are available because -
the performance of the BAT technology
basis on this parameter, cannot be
accurately predicted from laboratory-
scale data.                     ;
  (ii) Ammonium-Based Sulfite Mills.
EPA is  promulgating effluent limitations
for dioxin, furan, and 12 chlorinated
phenolic pollutants for the ammonium-
based segment. See 40 CFR 430.54 (a) (2).
EPA is reserving promulgation of
chloroform limitations, AOX
limitations, and COD limitations for this
segment until such time that sufficient
performance data are available because
the performance of the BAT technology
basis on these parameters cannot be
accurately predicted from laboratory-
scale data. One mill is currendy
installing, on a full scale, the
promulgated BAT technology basis. EPA
expects to have data to develop
chloroform, AOX, and COD limitations
for this segment once this installation is
complete, the mill is operating the new
equipment in a routine manner, and
appropriate samples are collected and
analyzed.             .-•••••
   (iii) Specialty Grade Sulfite Mills.
EPA is promulgating effluent limitations
for dioxin, furan, and 12 chlorinated
phenolic pollutants for the specialty
grade segment, based on laboratory scale
data. See 40 CFR 430.54(a)(3). EPA is
reserving promulgation of chloroform,
AOX, and COD limitations for this
segment until such time that sufficient
full scale performance data are available
because the performance of the BAT
technology basis on these parameters
cannot be accurately predicted from
laboratory scale data.
   (4)  Costs. As discussed in the July
1996 Notice, EPA revised its cost
estimates for mills in the Papergrade
Sulfite subcategory by using the revised
bleaching sequences outiined in
paragraph (2) above. EPA also updated
equipment cost curves and unit
operating costs. See 61 FR at 36845. The
detailed basis of these revised cost
estimates are provided in the record.
  The following cost estimates reflect
the total costs that mills in the
Papergrade Sulfite Subcategory are
likely to incur as a result of today's BAT
limitations,  PSES, and BMP regulations,
and are the bases for EPA's economic
impact analyses discussed in paragraph
(2) above. For this subcategory, EPA's
estimated capital costs are $73.8
million, operation and maintenance
costs are $7 million, and post-tax
annualized costs are $9.8 million. (The
general and administrative costs
discussed in Section Vm.B. 1 .c are ,
already included here.) See Section VHI
for additional discussion of cosjs and
economic impacts.
   (5)  Effluent Reductions. EPA has
updated the calculation of effluent
'reductions for each papergrade sulfite
mill,  adjusting the baseline to mid-1995.
EPA used methodology similar to that
used for the Bleached Papergrade Kraft
and Soda subcategory. As a result of the
BAT limitations and PSES promulgated
today, EPA estimates that for the
Papergrade Sulfite subcategory,
discharges of dioxin and furan will be
reduced by seven grams to less than one
gram per year. (EPA expects no .
discharges of dioxin and furan from TCF
bleaching.). Total discharges of
chlorinated phenolic pollutants will be

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 18560      Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules  and Regulations
reduced by 1,770 kilograms to 240
kilograms per year. As a result of the
TCP limitations and PSES on mills in
the calcium-, magnesium-, or sodium-
based sulfite segment and as an
incidental result of implementing the
ECF model technology by direct and
indirect discharging mills in the other
two segments, discharges of AOX will
be reduced by 4,010 metric tons to 370
metric tons per year. For a discussion of
the environmental benefits resulting
from these reductions, see Section
Vffl.G.2, and Chapter 8 of the Economic
Analysis, DON 14649.
  (6) Development of Limitations. All of
the limitations and standards
promulgated today for Subpart E are
expressed as "
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             Federal  Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules and Regulations
                                                                    18561
achieving effluent reductions. The
selected NSPS technologies are
presently being employed at mills in
each segment of this subcategory.
Moreover, the cost of the NSPS
technology is an insignificant fraction of
the-capital cost of a new mill (less than
one percent). Finally, EPA.has
determined that the costs of including
the selected NSPS technologies at a new
source are substantially, less on a per-ton
basis than the costs of retrofitting
existing mills. See Chapter 6 of the
Economic Analysis document (DCN
14649). Therefore, EPA has concluded
that such costs do not present'a barrier
to entry. The Agency also considered
energy requirements and other non-
water quality environmental impacts for
the selected NSPS options and
concluded that these impacts were no
greater than for the selected BAT
technology options and are acceptable.
See the Supplemental Technical
Development Document, DCN 14487-
EPA therefore concluded that the NSPS
technology bases selected for each"  .  .-
segment of the papergrade sulfite
segment constitutes the best available
demonstrated control technology for
that segment.
  d. Pretreatment Standards. EPA is
promulgating pretreatment standards for
new and existing sources for three
segments of the Papergrade Sulfite
subcategory based on the BAT and
NSPS technologies selected for each
segment. In determining PSES, EPA
considered the age, size, processes,
other engineering factors,  and non-water
quality environmental impacts pertinent
to Siibpart E mills. None of these factors
provided a basis for selecting different
PSES technologies. For each segment,
EPA selected the best technology
available to produce the products in
each segment/Each of the selected PSES
technologies is economically achievable
and has no unacceptable adverse non-
water quality impacts. With respect to
PSNS for these segments, EPA
concluded that the selected technologies
represent the best available
demonstrated control technologies that
are capable of producing each segment's
products. EPA also concluded that there
was no barrier to entry for the.reasons
set forth in section VI.B.S.c. above for
NSPS for this subcategory.
  In order to determine which
pollutants to regulate under PSES and
PSNS, EPA used the same pass-through
analysis.it employed for the Bleached
Papergrade Kraft and Soda subcategory
described in section VI.B.5.c(2) above.
EPA concluded that dioxin, furan, and
the 12 chlorinated phenolic pollutants
pass through or interfere with POTW.
operations for the ammonium and
specially grade segments for the reasons
set forth in section VI.B.5.c(2) for
Subpart B. This reasoning applies
because the BAT/PSES model
technologies for Subparts B and E are
both based on ECF process technologies;
the same is also true for the NSPS/PSNS,
technologies (although in neither
subpart does the model pretreatment
technology include secondary biological
wastewater treatment). Based on its
pass-through determination, EPA is
promulgating national pretreatment
standards for new and existing sources
for those pollutants for those segments.
These standards are expressed as
"
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Federal Register/Vol. 63, No. 72/Wednesday, April 15,  1998/Rules and Regulations
systems and to reduce the cost of
process operation through increased
chemical recovery. The BMPs
summarized below are discussed in
detail in the Technical Support
Document for Best Management
Practices for Spent Pulping Liquor
Management, Spill Prevention and
Control, DCN 14489 (hereafter "BMP
Technical Support Document").
  Under this regulation, mills must
implement the BMPs codified at section
430.03(c). BMP requirements for new
and existing direct dischargers apply
when incorporated as special conditions
in NPDES permits, consistent with CWA
sections 304(e) and 402(a). BMP
requirements for new and existing
indirect dischargers are pretreatment
standards; therefore, they are self-
implementing. The BMPs are:
  (l) Return of spilled or diverted spent
pulping liquors, soap, and turpentine to
the pulping and recovery processes to
the maximum extent practicable as
determined by the mill; recovery of such
materials outside the process; or
discharge of spilled or diverted material
at a rate that does not disrupt the
receiving wastewater treatment system;
  (2) Inspection and repair programs to
identify and repair leaking equipment
items;
  (3) Operation of continuous,
automatic spill detection systems that
the mill determines are necessary to
detect and control leaks, spills, and
intentional diversions of spent pulping
liquor, soap, and turpentine. Examples
of such systems are high level monitors
and alarms on storage tanks; process
area conductivity (or pH) monitors and
alarms; and process area sewer, process
wastewater, and wastewater treatment
plant conductivity (or pH) monitors and
alarms;
  (4) Employee training for those
personnel responsible for operating,
maintaining, or supervising the
operation and maintenance of
equipment items in spent pulping
liquor, soap, and turpentine service;
  (5) Preparation of brief reports that
evaluate spills of spent pulping liquor,
soap, or turpentine that are not
contained at the immediate process area
and intentional diversions of spent
pulping liquor, soap, or turpentine that
are not contained at the immediate
process area, (this requirement takes
effect on the date an OMB control
number is issued);
  (6) A program to review any planned
modifications to the pulping and
chemical recovery facilities and any
construction activities in the pulping
and chemical recovery areas before
these activities commence to prevent  '
leaks and spills during construction;
                            (7) Secondary containment for spent
                          pulping liquor bulk storage tanks. As an
                          alternative, mills may substitute an
                          annual tank integrity testing program, if
                          coupled with other containment or
                          diversion structures, in place of
                          secondary containment;
                            (8) Secondary containment for
                          turpentine bulk storage tanks;
                            (9) Curbing, diking, or other means of
                          isolating soap and turpentine processing
                          and loading areas from the wastewater
                          treatment facilities; and
                            (10) Wastewater monitoring to detect
                          leaks and spills, to track the
                          effectiveness of the BMPs, and to detect
                          trends in spent pulping liquor losses.
                            In addition, § 430.03(d) requires each
                          mill to prepare a BMP Plan, based on a
                          detailed engineering review of the mill's
                          pulping and recovery operations, that
                          specifies: (1) The procedures and the
                          practices to be employed by the mill to
                          meet the BMP requirements listed
                          above, as tailored to recognize site-
                          specific conditions; (2) the construction
                          the mill determines is necessary to meet
                          the BMP requirements, including a
                          schedule for such construction; and (3)
                          the monitoring program that will be
                          used to meet the BMP requirements.
                          This requirement takes effect April 15,
                          1999 see 40 CFR 430.03 (j)(l)(i), or the
                          date an OMB control number for this
                          requirement is issued, whichever is
                          later. See 40 CFR430.03(a)(2).
                            Each mill must also certify to the
                          appropriate permitting or pretreatment
                          authority that it has prepared the Plan
                          in accordance with the BMP regulation.
                          See 40 CFR 430.03 (f). The mill is not
                          required to obtain approval of the BMP
                          Plan by the permitting or pretreatment
                          authority. Id. The permitting or
                          pretreatment authority at its discretion,
                          however, may conduct a review of the   .
                          BMP Plan, BMP Plan amendments, and
                          BMP Plan implementation.
                            Finally, section 430.03 (h) requires
                          mills to establish action levels (a
                          measure of daily pollutant loading) that,
                          when exceeded, trigger investigative
                          and corrective action (depending on the
                          action level exceeded) to reduce the
                          wastewater treatment system influent
                          mass loading. This requirement takes
                          effect April 15, 1999 see 40 CFR
                          430.03.(j)(l)(iii), or the date an OMB .
                          control number for this requirement is
                          issued, whichever is later. The purpose
                          of the action levels is to provide a
                          framework for monitoring the
                          performance and effectiveness of BMPs
                          on a continuing basis and to establish an
                          early warning system so that mills can
                          detect trends in spent pulping liquor,
                          soap, and turpentine losses that might
                          not be obvious from other sources.
                          Under the regulation, a mill has
considerable flexibility to choose its
monitoring parameter. For more
discussion of action levels, see the BMP
Technical Support Document, DCN
14489. EPA had considered requiring all
mills to employ specific statistical
action levels. See 61 FR at 36847. EPA
rejected this approach because it was
concerned that such action levels might
fail to trigger appropriate investigative
and corrective actions for some mills,
while being too restrictive for other
mills. Instead, EPA determined that
authorizing mills to choose their own
monitoring parameters and to set their
own action levels better accounts for the
variability in organic loadings at
different mills and differences in
treatment  plant effectiveness and
evaporator capacity, among other mill-
specific factors. This flexibility" thus
ensures that the action levels reflect the
actual performance of mill-specific
BMPs and procedures. In this way, EPA
believes the action levels will better
achieve the spill and leak control
objectives of the BMP requirements.
Exceedances of the action levels will not
constitute violations of an NPDES
permit or pretreatment standard. See 40
CFR 430.03(i) (3). However, a null that
fails to take corrective action as soon as
practicable in response to the
exceedances will be violating its NPDES
permit or pretreatment standard. Id.
  As set forth in § 430.03Q), the
following  deadlines apply:  Existing
indirect dischargers are required to
prepare BMP Plans and implement all
BMPs that do not require the
construction of containment or
diversion structures or the installation
of monitoring and alarm systems no
later than  April 15, 1999. Operation of
any new or upgraded continuous,
automatic monitoring systems that the
mill determines to be necessiary (other
than those associated with construction
of new containment or diversion
structures) must commence no later
than April 17, 2000. The milt must
complete construction and commence
operation  of any spent pulping liquor,
collection-, containment, diversion, or
other facilities, including any associated
continuous monitoring systems,
necessary  to fully implement BMPs by
April 16, 2001. Existing indirect
dischargers must establish the initial
action levels by April 15,1999, and the
revised action levels as soon as possible
after fully implementing the BMPs, but
not later than January 15, 2002. The
requirements to develop the BMP Plan
and to perform other record-keeping and
reporting requirements do not apply
until OMB has approved the associated

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              Federal Register/Vol. 63. No. .72/Wednesday, April  15,  1998/Rules and Regulations       18563
 information collection request. See 40
 CFR430.03(a)(2).
   NPDES permits must require existing
 direct discharging mills to meet the
 same deadlines specified for existing
 indirect dischargers which is calculated
 from the date of publication. See 40 CFR
 430.03Q) (1). If the applicable deadline
 has passed at the" time the NPDES
 permit containing the BMP requirement
 is issued, the NPDES permit must
 require immediate compliance with the
 BMP requirement. Id. EPA believes this
 is appropriate because the record shows
 that mills can implement the
 substantive requirements of the BMPs—
 which are well-known within the
 industry today—without significant
 uncertainty or difficulty. In addition,
 timely implementation will avert the
 adverse environmental effects of
 uncontrolled leaks, spills, and
 intentional diversions. Finally, the
 affected mills have been on notice for
 several years that these requirements
 would likely be imposed and therefore
 should not be prejudiced by prompt
 compliance obligations. EPA expects
 that the compliance date for full
 implementation of the BMP
 requirements will not extend beyond
 five years from the effective date of the
 final rule because EPA expects NPDES
 permits for those mills to be reissued on
 a timely basis; With the exception of the
 requirement to, establish action levels,
 which must occur not later than 12
 months after commencing discharge,
 new direct and indirect discharging
 mills must prepare the BMP Plan and
 implement all BMPs upon commencing
 discharge. See 40 CFR 430.03(j)(2).
  EPA believes it is reasonable to
 require existing indirect dischargers to
 establish revised action levels by
 January 15, 2002 and to require all new
 sources to establish action levels no
 later than 12 months after commencing  '
 discharge. These requirements apply
 only after full implementation of the
 required BMPs and reflect the amount of
 time EPA believes is necessary for mills
'to collect monitoring data regarding the
 effectiveness of these newly
 implemented practices and to perform
 the statistical analysis to develop the
 required action levels. Because the
 required action levels  are intended to
 reflect normal mill operating conditions
 using the BMPs, they cannot be
 established prior to the implementation
 of the BMPs or, in the  case of new
 sources, prior to commencing discharge.
 Fpr a discussion of EPA's basis for the
 other deadlines in this rule, see the BMP
 Technical Support Document, DCN
 14489, '
  The proposed regulations had
 included provisions for leak and spill
 prevention, containment, and control
 through the use of BMPs. See 58 FR at
 66078. The comments received by EPA
 on the^proposed rule and subsequent
 Federal Register notices generally
 supported the use of BMPs, but a
 number of comments challenged EPA's
 compliance cost estimates and claimed
 that certain requirements were too
 prescriptive. In particular, industry
 asserted:
   •  The requirement to develop BMPs
 should be limited to spent pulping
 liquor (e.g., kraft black liquor,,sulfite red
 liquors) and should exclude kraft'green
 and white liquors and fresh sulfite
 pulping liquors;            ;
   •  The proposed regulation was overly
 prescriptive in general and, in
 particular, the requirement for
 secondary containment was
 unnecessary to meet the objectives of
 the proposed regulation;
   •  EPA underestimated the costs  for
 implementing BMPs;
   •  EPA lacks the authority to establish
 BMPs to control pollutants that are not
 identified as toxic under CWA section
 307(a) or hazardous under CWA section
 311; and
   •  EPA lacks the authority to impose
 BMPs on indirect dischargers.
   In response to comments, EPA
 undertook several initiatives to
 understand industry's concerns about
 the proposed BMP requirements; to
 better understand the status of the
 industry with respect to pulping liquor
 management and spill prevention and,
 control; arid to better assess the BMP
 compliance costs. To supplement its
 understanding of industry's spent
 pulping liquor management and spill
 prevention and control practices, EPA
 visited more than 25 chemical pulp
 mills in the United States and 15 mills
 in Canada and Europe following its
 1993 proposal. These mills included
 bleached and unbleached kraft mills
 and papergrade sulfite mills (see Docket
 Sections 21.5.1 and 21.5.3). EPA also
 reviewed the results of the NCASI BMP
 questionnaire distributed to the
 industry. Questionnaire responses were
 received from approximately 70
 bleached and unbleached kraft, soda,
and sulfite mills. Through this NCASI
questionnaire EPA received a
substantial amount of additional
 information about mill practices and
costs for equipment, monitoring
systems, and facility modifications (see
Docket Section 21.1.3). In addition, EPA
held detailed discussions with
stakeholders regarding options for BMPs
and associated costs. Much of this
information was included in the Docket
arid made available to the public in
conjunction with the Notice of Data
 Availability published in the Federal  '
 Register on July 5,1995 (60 FR 34938).
 Additional information related to
 development of-the BMP requirements,
 including changes in the wording and
 organization of the proposed rule, was
 discussed in the July 1996 Notice. See
 61 FR at 36835.
   Based on the information arid data
 received since proposal, EPA revised
 the scope of the BMP requirements to
 focus on control of spent pulping liquor,
 turpentine, and soap. The BMP
 requirements were restructured to allow
 greater flexibility in how BMPs are
 implemented to address site-specific
 circumstances in achieving meaningful
 prevention and control of leaks and
 spills. EPA also reorgariized the
 regulatory text from that presented in
 the record for the July 1996 Notice to
 provide greater ease of use by mill
 operators and permit writers, and to
 clarify the intent of particular BMP
 requirements. The most significant
 changes since proposal are discussed
 below.
   In December 1993, EPA proposed
 BMPs for seven subcategories of the
 pulp, paper, and paperboard industry
 (58 FR at,66078), aU of which-
 chemically pulp wood and non-wood
 fibers. EPA still believes BMPs are
 appropriate for each of these chemical
 pulping subcategories; however, to be
 consistent with the effluent limitations
 guidelines and standards promulgated
 in this final rule, the BMPs promulgated
 today are applicable only to the
 Bleached Papergrade Kraft and Soda
 and Papergrade Sulfite subcategories.
 EPA expects to promulgate BMPs for the
 remaining five chemical pulping
 subcategories [(Subparts' A (Dissolving
 Kraft), C  (Unbleached Kraft), D
 pissolvirig Sulfite), F (Semi-chemical)^
 and H (Non-wood Chemical Pulp)] as it
 promulgates new effluent limitations
 guidelines and standards for these
 subcategories. Until riew regulations for
 Subparts A, C, D, F, and H are
 promulgated, permit writers may wish
 to use the BMP regulations in this rule
 as a guide to issuing permits containing
 BMPs based on best professional
judgment for mills with production
 covered by these other subparts. See
 CWA Section 402(a)(l); 40 CFR
 122.44(k). POTWs may need to impose
 BMPs as local limits to facilities in these
 subcategoriesi See 40 CFR 403.5.
  The BMP provisions in the proposed
 rule were structured to apply to all   .
 pulping liquors. In response to
 comments, EPA has revised the scopeof
 the BMPs and for the final rule  is
 limiting the BMP applicability to spent'
 pulping liquors, turpentine, and soap.
 EPA has determined that spent pulping

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Federal Register/Vol. 63, No.  7.2/Wednesday, April  15, "1998/Rules and  Regulations
liquors contain toxic components and
that these materials, if uncontrolled,
pass through or interfere with the
operation of POTWs and may interfere
with industrial wastewater treatment
systems at mills that discharge directly
to surface waters. EPA has excluded
green, white and other intermediate
pulping liquors (e.g., fresh sulfite
pulping liquors) from this BMP rule
because the data in the record does not
indicate that these materials pass
through wastewater treatment systems.
Turpentine and soap are included in the
BMP rule because, if spilled or lost,
these materials can interfere with
wastewater treatment operations and
lead to increased discharges of toxic,
nonconventional, and conventional
pollutants.
  In December 1993, EPA proposed to
require mills to provide secondary
containment for all pulping liquor bulk
storage tanks. EPA has since determined
that spill prevention can be adequately
achieved for spent pulping liquor bulk
storage tanks by substituting annual
tank integrity testing and other
containment or diversion structures
(e.g., curbs and berms) in place of
secondary containment. The final rule
provides flexibility for mills to choose -
either secondary containment or annual
tank integrity testing, coupled with
other containment or diversion
structures, to comply with this
requirement for spent pulping liquor
bulk storage tanks. See 40 CFR
430.03(c)(7). EPA determined that
secondary containment should be
required at all times for turpentine bulk
storage tanks because of the extreme
toxic effects a turpentine spill would
have on the biological treatment system,
and because the size of turpentine bulk
storage tanks is such that secondary
containment is easily achieved. In fact,
EPA has found that most mills already
provide secondary containment for their
turpentine bulk storage tanks. No
secondary containment is required for
soap bulk storage tanks.
   As discussed in the July 1996 Notice,
EPA also proposed adding a
requirement to the BMP regulation that
would require mills to implement a
monitoring program for the purpose of
detecting leaks and spills, tracking the
effectiveness of the BMPs, and detecting
trends in spent pulping liquor losses.
EPA proposed requiring mills to
monitor wastewater treatment system
influent for a short-term measure of
organic content that can be completed
on a daily basis (e.g., Chemical Oxygen
Demand (COD) or Total Organic Carbon
(TOC)). EPA has promulgated this
requirement (see 40 CFR 430.03 (h) and
(i)), but in response to comments, EPA
                          is also allowing mills to use an
                          alternative parameter related to spent
                          pulping liquor losses that can be
                          measured continuously and averaged
                          over 24 hours (e.g., specific conductivity
                          or color). See 40 CFR 430.03(h)(2) (i). In
                          conjunction with this monitoring, mills
                          are required by today's regulation to
                          establish action levels (using the
                          measure of daily pollutant loading) that,
                          when exceeded, trigger investigative
                          and corrective action, as appropriate, to
                          reduce the wastewater treatment system
                          influent mass loading. See 40 CFR
                          430.03(h)..
                            The proposed rule would have
                          required certification of the BMP plan
                          by a registered professional engineer
                          (P.E.) and approval by'the mill manager.
                          The intent of the proposed P.E.
                          certification was to assure preparation
                          of a comprehensive BMP Plan that is
                          tailored to the site-specific
                          circumstances at the mill. Industry
                          commented that many mills have no
                          registered professional engineers on site.
                          For mills without a P.E. onsite, the
                          proposed requirement would result in
                          the plan being certified by someone not
                          involved with the mill on a daily basis,
                          and someone not responsible for its
                          operation. EPA has determined that
                          requiring certification by a P.E. is
                          unnecessarily prescriptive and may
                          have unintended results. The final
                          regulation deletes the requirement for
                          certification by a registered P.E. and
                          now requires the BMP Plan to be
                          reviewed by the senior technical
                          manager at the mill and approved and
                          signed by the mill manager. See 40 CFR
                          430.03(f).
                            The regulation was proposed to be
                          self-implementing for both direct and
                          indirect dischargers. EPA has revised
                          the regulation to make it clear that
                          BMPs imposed on direct dischargers are
                          not self-implementing, but rather apply
                          only when incorporated into NPDES
                          permits. See 40 CFR 430.03Q). This is
                          consistent with CWA sections 304(e)
                          and 402. The final regulation remains
                          self-implementing for indirect
                          dischargers. Id.
                            The final regulation extends
                          compliance schedules for plan
                          preparation and plan implementation to
                          grant more time for the preparation of
                          the initial BMP Plan and installation of
                          monitoring and alarm systems. Based on
                          information supplied by industry
                          regarding the time required in past
                          efforts to develop spill prevention
                          programs, EPA determined that 12
                          months was reasonable to complete the
                          development of the BMP Plan and
                          includes that deadline in the regulation.
                          Similarly, EPA determined that it is
                          reasonable to require mills to commence
operation of any new monitoring
systems no later than 24 months
following publication of the final rule.
This compliance date provides
sufficient time between BMP Plan .
preparation and operation of new
monitoring systems (i.e., 12 months) to
allow implementation of BMPs in a
rational and effective manner.
  The final BMP regulation is less
prescriptive than proposed with regard
to inspection, repair and log-keeping
requirements: While many of the
elements included in the proposed rule
remain, EPA determined that the
specificity of the language in the
proposed regulation could be redundant
to existing practices in place at some
mills and be unnecessarily burdensome.
EPA believes the language in the final
rule will achieve the same results as it
intended in the proposed rule while
allowing mills to use existing
maintenance and repair traclcing
systems to fulfill the requirement. See
40CFR430.03(c).
  As discussed in the July 1996 Notice,
EPA used the information obtained
since proposal to revise its cost
estimates for BMPs. See 61 FR at 36840.
At proposal, EPA's estimated costs were
based on the reported total project costs
for two older bleached kraft mills to
install spill prevention and control
systems. After adjusting the costs to
reflect the size of a "typical" mill, EPA
then assumed that these costs reflected
the average cost incurred by bleached
papergrade kraft and soda and
papergrade sulfite mills to install BMPs.
EPA then imputed to some mills
compliance costs less than that average
cost depending on the extent EPA  ,
judged they had implemented BMPs
(see Technical Support Document for
Proposed Best Management Practices
Programs: Pulping Liquor Management,
Spill Prevention and Control, November
1993. Docket Section 17.4, DCN 08307).
  EPA improved its estimates of
industry-wide costs for compliance with
the BMP requirements in the final rule,
compared to the cost methodology used
for the proposed regulation. These
changes were discussed in the July 1996
Notice and in the accompanying Draft
Technical Support Document for Best
Management Practices Programs: Spent
Pulping Liquor Management, Spill
Prevention and Control, May 1996 (DCN
13894). EPA's supplemental-mill visits
and the NCASI survey responses have
resulted in a more accurate status of the
existing BMP infrastructure and
programs at mills. This information was
used to create model BMP mill
requirements for each level of mill
complexity and to classify mills by
complexity level. EPA then used data

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              Federal Register/Vol. 63. No. 72/Wednesday, April  15,  1998/Rules and Regulations       18565

  provided by the industry in comments
  and the NCASI survey to develop unit
  costs for major equipment items, facility
  modifications, monitoring systems and
  BMP Plan preparation, rather than using
  the total project costs reported by two
  mills as was done at proposal. Finally,
  EPA incorporated the estimates of net
  operating and maintenance costs of
  BMPs into the BAT/PSES cost model.
  The cost model tracked the impacts of
>  increased pulping liquor recovery on
  the evaporators and chemical recovery
  system and determined the need for
  equipment upgrades resulting from the
  combined effect of BAT/PSES process
  changes and BMPs. The savings from
  reduced load on the wastewater  •
  treatment system and increased
  recovery of fiber, chemicals and energy
  were subtracted from the BMP operating
  costs (i.e., increased evaporation energy,
  tank integrity testing, operator training,
  and O&M costs for new equipment).
    EPA disagrees with comments
  asserting that EPA lacks authority to
  establish BMPs for pollutants'that are
.  nbt identified as toxic under CWA
  section 307(a) or hazardous under CWA
  section 311. First, the non-toxic and
  non-hazardous pollutants controlled by
  these BMPs are found in the same
  wastestreams bearing pollutants
 , specifically identified as toxic
  pollutants or hazardous substances
  under sections 307(a) and 311 and
  implementing regulations. Although
.  reductions of these pollutants are
  significant in environmental effect, their'
  control is incidental to the control of all
  the pollutants subject to section 304(e).
  Second, EPA has independent authority
  under section 402 (a) (1) to establish
  NPDES permit conditions, including
  BMPs, for any pollutant when such
  conditions are necessary to carry out the
  provisions of the statute. See 40 CFR
  122.44(k). This authority operates
  independently of section 304 (e). Indeed,
  when Congress enacted section 304 (e)
  specifically for toxic pollutants and
  hazardous substances, it acknowledged
  that section 402 (a) (1) already provided
  authority for imposing BMPs in NPDES
  permits. See Statement of Sen. Muskie
  (Dec: 15, 1977), reprinted in Legislative
  History of the Clean Water Act of 1977,
  at 453. EPA's authority to establish
  permit conditions under section
  402(a).(I) is very broad. See NRDCv.
  Costle, 568 F.2d  1369, 1380 (D.C. Cir.
  1977). EPA has determined that mills
  without an adequate BMP program,
  such as that codified today, may
  experience undetected'and uncontrolled
  leaks and spillathat could disrupt the
  efficiency of their treatment systems,
  thus resulting in exceedances of the
 BAT limitations and NSPS promulgated
 today for subparts B and E. Moreover,
 the BMPs control pollutants that are not
 explicitly regulated under BAT arid ,
 NSPS. Therefore, EPA determined that
 BMPs applicable to all pollutants in a
 mill's spent pulping liquor, turpentine,
 and soap were necessary in order to
 carry out the purposes of the Clean
 Water Act arid hence are authorized  .
 under section 402 (a) (1) and 40 CFR
 122.44(k). Similarly,,as discussed
 below, BMPs are authorized as  ,
 pretreatment standards for pollutants in
. the spent pulping liquor, turpentine,
 and soap when they pass through or
 interfere with POTW operations.
   Some commenters also objected to
 EPA's decision to establish the BMP
 program by regulation rather than
 deferring to the case-by-case
 determinations of permit writers. EPA
 agrees that a requirement to establish
 and implement BMPs of the type
 fequired by this rule could be imposed
 on a case-by-case basis under CWA
 section 402(a)(l) and 40 CFR 122.44(k).
 However, EPA rejected this approach for
 a number of reasons. First, section
 304(e) expressly authorizes EPA to
 promulgate BMPs by regulation on a
 categorical basis. The spent pulping
 liquors, soap, and turpentine covered by
 these BMPs contain numerous toxic
 pollutants and hazardous substances.
 subject to section 304 (e) and hence may
 be controlled by regulation. Moreover,
 EPA determined that implementing the
 BMP program by regulation is necessary
 to ensure that each pulp and paper mill
 with pulp production in subparts B or
 E implements the type of BMPs that
 EPA has determined are fundamental to
 an effective BMP program for this
 industry. While the BMP regulation is
 intended to provide considerable
 flexibility to mills in designing their
 BMP programs, EPA has also
 determined that the various BMPs
 specified in the regulation  are necessary
 to assure uniform and fair application of
 the requirements. Finally, EPA believes
 that the regulation represents an
 appropriate and efficient use of its
 technical expertise and resources that,
 when exercised at the national level,
 will relieve permit writers  of the burden
 of implementing this aspect of the Clean
 Water Act on a case-by-case basis.
  EPA also disagrees with comments
 asserting that EPA lacks authority to
 impose BMPs on indirect discharges.
 These BMPs are pretreatment standards
 under section 307 (b) and (c).
 Pretreatment standards for new and
 existing sources under section 307 are
 designed to prevent the discharge of
 pollutants that pass through POTWs or
 that interfere with or are otherwise
 incompatible with treatment processes
 or sludge disposal methods at POTWs.
 To determine whether pollutants
 associated with spent kraft and sulfite
 pulping .liquors, soap, and turpentine .
 that are indirectly discharged by mills
 with pulp production in subparts B of
 E interfere with POTW operations or
 pass through untreated, EPA reviewed
 data collected from 1988 through 1992
 at a POTW that receives effluent from a
 bleached papergrade kraft mill. Prior to
 1990-91, the mill had virtually no
 facilities for control and collection of
 spent pulping liquor leaks and spills.
 POTW discharge monitoring records
 show the fully treated effluent exhibited
 consistent chronic toxiciry to Daphnia
 from April 1988 until June 1991. The
 data further show that the toxic effects
 of the POTWs effluent have been
 reduced since implementation by the
 mill of effective spent pulping liquor
 management and spill prevention and
 control. These effluent toxicity effects
 can be related to the wood extractive
 components that are measurable by COD
 and are found in leaks and spills of
 spent kraft and sulfite pulping liquors
 that interfere with the performance of
 biological treatment systems and allow
 toxic pollutants to pass through
 inadequately treated. Indeed, evidence
 of such interference and pass-through
 was found in data from this mill and the
 POTW, which showed higher mass
 effluent loadings for COD, TSS and ,
 BOD5 before the mill implemented a
 BMP program. After the BMP program
 was implemented, mass effluent
 loadings of these pollutants were
 reduced. Data for COD, in particular,
 indicated that short-term interference of
 POTW operations previously observed
 at higher COD levels was being
 mitigated. EPA also bases its pass-
through finding on an incident
 occurring in 1993  at a different mill
where, an intentional diversion of spent
pulping liquor debilitated the mill's '
secondary treatment system and killed
fish in the receiving waters. These data
led EPA to conclude that inadequate
 management and control of leaks and
spills of spent pulping liquor, soap, and
turpentine interfered with POTW
operations and caused pass-through of
pollutants. Because direct discharging
mills using these BMPs achieve very
high removals and because POTWs
cannot achieve similar removals in the
absence of BMPs employed by the
indirect discharger, EPA has determined
that pollutants in spent pulping liquor,
soap, and turpentine, in the absence of
controls on leaks, spills, and intentional
diversions, can cause disruption and
interference and do indeed pass through

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at POTWs. For this reason, EPA is
Including as part of its pretreatment
standards the requirement that indirect
discharging mills implement BMPs in
accordance with this regulation.
8. Regulatory Implementation for
Effluent Limitations Guidelines and
Standards
  a. Applicability of Effluent
Limitations Guidelines and Standards.
Effluent limitations act as a primary
mechanism to control discharges of
  Pollutants to waters of the United
  tales. These limitations are applied to
individual mills through NPDES
permits issued by EPA or authorized
States under section 402 of the CWA. In
addition, the pretreatment standards are
dlrecdy applicable to indirect
dischargers. Once today's regulations
become effective, the effluent
limitations and standards for the
appropriate subcategory must  be
applied in all Federal and State NPDES
permits issued to direct dischargers
affected by this rule. See Section
301 (b)(2), 402(a). This section  describes
the applicability of these limitations and
standards to process and other
wastewaters generated by the mills in
the Bleached Papergrade Kraft and Soda
and Papergrade Sulfite subcategories,
defines new sources subject to today's
NSPS and PSNS, defines non-
continuous dischargers and the
applicable limitations, and describes the
retention of the previously promulgated
limitations and standards.
  (1) Applicability of Limitations to
Process and Other Wastewaters. The
effluent limitations guidelines and
standards for the pulp and paper
industry apply to discharges of process
wastewaters directly associated with the
manufacturing of pulp and paper. See
40 CFR 430.00. EPA proposed a
definition of process wastewater as any
water that, during manufacturing or
processing, comes into direct contact
with or results from the production or
use of any raw material, intermediate
product, finished product, byproduct, or
waste product. The proposed definition
specifically included boiler blowdown;
wastewaters from water treatment and
other utility operations; blowdown from
high rate (e.g., greater than 98  percent)
recycled non-contact cooling water
systems to the extent they are mixed
and co-treated with other process
wastewaters; and stormwaters from the
immediate process areas to the extent
they are mixed and co-treated  with '
other process wastewaters. The
proposed definition specifically
provided that contaminated
groundwaters from on-site or off-site
groundwater remediation projects
                          would not be process wastewaters. EPA
                          proposed to require separate permitting
                          for the discharge of such groundwaters.
                          The proposed definition also
                          specifically excluded certain process
                          materials from the definition of process
                          wastewater. These process materials
                          included: Green liquor at any liquor
                          solids level; white liquor at any liquor
                          solids level; black liquor at any liquor
                          solids level resulting from processing
                          knots and screen rejects; black liquor
                          after any degree of concentration in the
                          kraft or soda chemical recovery process;
                          reconstituted sulfite and semi-chemical
                          pulping liquors prior to use; any
                          pulping liquor at any liquor solids level
                          resulting from spills or intentional
                          diversions from the process; lime mud
                          and magnesium oxiide; pulp stock;
                          bleach chemical solutions prior to use;
                          and papermaking additives prior to use
                          (e.g., alum, starch and size, clays and
                          coatings). The proposed'regulation then
                          would have prohibited the discharge of
                          these materials into POTWs or waters of
                          the United States without an NPDES
                          permit or other authorization.
                            In this final rule, EPA is promulgating
                          a definition of process wastewater
                          applicable to subparts B and E. In
                          response to the comments opposing the
                          exclusion of these process materials,
                          EPA revised the proposed definition of
                          process wastewaters to eliminate the
                          exclusion of the named process
                          materials. See 40 CFR 430.01(m)..The
                          proposed language would have
                          effectively required "closed cycle" ,
                          mills, which was not EPA's intent. The
                          exclusion of contaminated groundwater
                          has been retained. Because the quantity
                          and quality of such groundwaters are
                          likely to be highly variable on a site-
                          specific basis, the Agency concluded
                          that their discharge to surface waters
                          should be regulated separately from, or
                          in addition to, process wastewaters on
                          a case-by-case basis. EPA also has
                          included leachate wastewaters from
                          landfills owned and operated by mills
                          generating wastes associated with
                          manufacturing or processing subject to
                          subparts B and E, where these leachate
                          wastewaters are commingled with other
                          process wastewaters. These leachate
                          wastewaters typically comprise a very
                          small proportion of the total volume
                          received in end-of-pipe wastewater
                          treatment facilities. In cases where the
                          volumes or pollutants found in leachate
                          wastewaters are of concern, permit
                          writers may develop individual permit
                          limitations on a case-by-case basis.
                          EPA's definition continues to define
                          process wastewater in terms of
                          manufacturing or processing. EPA has
                          promulgated a subcategory-specific
definition of process wastewater in
order to clarify the applicability of
subparts B and E and to assist permit
writers and pretreatment authorities in
developing limitations and standards.
The effluent limitations guidelines and
standards promulgated today do not
apply to discharges that are not
associated with manufacturing or
processing. Any mill wishing to
discharge such wastewaters would need
to obtain authorization in an NPDES
permit or individual control mechanism
administered by a POTW.
  EPA's use of the term ' 'during
manufacturing or processing" should
not be taken to exclude wastewaters
generated during routine maintenance,
including maintenance occurring during
a scheduled temporary mill shut-down.
Maintenance wastewaters weire not
explicitly excluded from the definition
of process wastewater at proposal, nor
are they excluded from the definition
promulgated today. Wastewaters
generated during routine maintenance
are a result of pulp manufacturing
processes and as such are included in
the definition of process wasfewater.
  (2) Definition of New Source. In
today's rule, EPA is promulgating a
definition of "new source" applicable to
Part 430, subparts B and E. See 40 CFR
430.01(j). This definition restates the
definition set forth in 40 CFR
122.29(b)(l), but with the additional
reference to certain process changes
that, in and of themselves, would not
cause a mill to become a new source.
See 40 CFR 430.0 l(j) (2). EPA intends
that permit writers will consult the
specific "new source" criteria in Part
430, rather than the more general
criteria set forth in 40 CFR  122:29(b)(l)
and 403 when determining whether
pulp and paper mills  subject to subparts
B or E are new sources. The other
provisions of 40 CFR  122.29 continue to
apply to these-subparts, as do 40 CFR
122.2 and 40 CFR 403.3(k). The
definition of "new source" in Part 430
does not affect the definition of "new
source" for purposes of the NESHAP
portion of these integrated rules.
  EPA is aware that application of the
definitions in Part 122 to pulp and
paper mills in the Bleached Papergrade
Kraft and Soda and Papergrade Sulfite
subcategories has sometimes caused
controversy, leading to disagreement
between the permitting authority and
the facility whether a particular change
at the mill triggers NSPS or PSNS. EPA
is promulgating a definition of "new
source" specifically for subparts B and
E in order to set forth the specific factors
relevant to a new source determination
for covered mills and thus, EPA hopes,
to end the disputes regarding a mill's

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                                                                     18567
 new source status. Indeed, the decision
 to promulgate subcategory-specific
 criteria in this rule is specifically
 contemplated by the general criteria
 codified at 40 CFR 122.29(b)(l). EPA -.
 believes this tailored definition is
 particularly important in view of the
 Voluntary Advanced Technology
 Incentives Program EPA is also
 promulgating today for subpart B mills.
 Through the Voluntary Advanced
 Technology Incentives Program, EPA is
 encouraging mills to install new process
 technologies and even to redesign
 bleach plant operations in order to
 achieve effluent reductions beyond
 those required at the baseline BAT level.
 EPA does not want existing mills that
 voluntarily  choose to participate in the
 Voluntary Advanced Technology
 Incentives Program to be required to
 meet NSPS simply as a consequence of
 that election. Therefore, by
 promulgating a definition of "new
 source" specifically for subparts B and
 E, EPA hopes not only to clarify
 application  of the Part 122 definitions
 but also to provide certainty to subpart
 B mills choosing to participate in the
 Voluntary Advanced Technology
 Incentives Program that they will not
, inadvertently become a new source,
 which would subject them to
 compulsory NSPS.         ,   :
   For the convenience of the permit
 writer, the definition of new source
 being codified in part 430 restates the
 three criteria already codified in
 § 122.29(b) (1). The first criterion
 provides that a source is a new source
 if it is constructed at a site at which no
 other .source is located. Section 430.01
 0)(l)(i); see 40 CFR 122,29(b)(l)(i). As
 applied to part 430, this criterion is
 intended to  ensure that a greenfield mill
 is characterized as a new source and
 hence is subject to NSPS or PSNS.
  The second criterion specified in
 today's definition of new source
 incorporates the language of 40 CFR
 122.29(b)(l)(ii) with two additions.
 First, it provides that a fiber line that
 totally replaces an existing fiber line is
 a new source (unless that fiber line is
 enrolled in the Voluntary Advanced
 Technology Incentives Program).
 Second, it includes a list of
 modifications that would not trigger the
 new" source definition if made by
 subpart B or E mills. See 40 CFR
 430.0 l(j)(l)(ii) and (2). This criterion
 provides essentially that a fiber line that
 is modified to comply with baseline
 BAT effluent limitations or that is
 totally rebuilt to comply with Advanced
 Technology BAT limitations is not a
 new source. (A fiber line is a series of
 operations employed to convert wood or
 other fibrous raw material into pulp. If
 the final product is bleached pulp, the
 fiber line encompasses pulping, de-
 knotting, brownstock washing, pulp
 screening, centrifugal cleaning, and
 multiple bleaching and washing stages.)
  Among the changes specified in the
 regulation that alone do not cause an .
 existing fiber line at a mill to be -
 considered a new source are: Upgrades
 of existing pulping operations; upgrades
 or replacement of pulp screening and
 washing operations; installation of
 extended cooking and/or oxygen
 delignification systems or other post-'
 digester, pre-bleaching delignification
 systems; and bleach plant modifications
 including changes in, methods or
 amounts of chemical applications, new
 chemical applications,  installation of
 new bleaching towers to facilitate
 replacement of sodium or calcium
 hypochlorite, and installation of new
 pulp washing systems.  40 CFR
 430.01fl)(2)(i)-(iv). By expressly
 excluding these process modifications
 from the new source definition, EPA    ,
 thus allows a mill to implement the
 baseline BAT/PSES technologies
 without triggering NSPS or PSNS. EPA
 believes that interpreting process
 modifications that are designed to
 achieve compliance with baseline BAT/
 PSES limitations as an existing source
 modification is consistent with
 Congress' intentions in the Clean Water
 Act concerning the respective roles of
 standards for existing and new sources.
  As discussed in more detail below in
 connection with the third new source
 criterion, EPA believes  it is appropriate
 to define a new fiber line as a new
 source because the construction of the
 new fiber line (whether to supplement
"or replace ah existing fiber line)
 presents the type of pollution
 prevention opportunities customarily •
 represented by NSPS. However, EPA
 believes it is also appropriate to treat the
 replacement fiber line as an existing
 source if that fiber line is enrblled'in the
 Voluntary Advanced Technology
 Incentives Program. See 40 CFR
 430.01 (j) (2) (v). EPA has decided to do
 this because requiring the new fiber line
 to meet  baseline NSPS requirements
would defeat the purpose of the
Voluntary Advanced Technology
Incentives Program by undercutting the
 more environmentally protective
 pollution prevention opportunities and
 limitations associated with that
 program.' In the first place, Advanced
Technology BAT limitations at the Tier
n and Tier HI levels are more stringent
than the baseline NSPS requirements;
EPA's definition of new source thus is
 intended to allow mills to commit to
greater pollutant reductions than EPA
could otherwise compel and to do so
 incrementally while maintaining use of
 the;existing fiber line in the interim.
 Similarly, the Advanced Technology
 BAT limitations at the Tier I level
 promote pollution prevention
 opportunities not necessarily assured by
 NSPS, even though the technology bases
 for NSPS and Tier I are similar. EPA has
 established different limitations for Tier
 I than for NSPS because the regulations
 are intended to achieve different
 objectives. The new source performance
 standards for AOX are more stringent
 because, as a  statistical matter, EPA
 determined that this performance level
 reflects the best demonstrated
 performance by mills using the NSPS
 technology. The Tier I limitations for
 AOX, in contrast, are intended to reflect
 a more inclusive performance level that
 EPA believes  existing mills employing
 extended delignification can achieve, in
 order to encourage more mills to
 implement extended delignification
 technologies.  The Tier I limitations also
 require the recycle of filtrates to  the
 recovery systems and impose
 limitations on the lignin content of
 unbleached pulp, which EPA hopes will
 p'romote the use of particular pollution
 prevention technologies and, in turn,
 encourage mills to.look beyond Tier I to
 the Tier H and Tier m levels. This goal
 contrasts with the objective of NSPS,
 which simply is to compel mills to
 achieve certain discharge levels by any
 combination of technologies the  mill
. selects, and would be defeated if the
 definition of new source would have the
 effect of moving Tier I mills into NSPS.
 Therefore, EPA has decided that, on
.balance, imposing NSPS on mills that
 replace fiber lines for the purpose of
 participating in the Voluntary Advanced
 Technology Incentives Program "would
 discourage rather than encourage the
 long-term goal of achieving even greater
 environmental performance.
   The third criterion appearing in the
 definition of new source in
 § 430.01 (j) (1) (iii) is identical to the third
 criterion at §122.29(b)(l)(iii), and
 provides that  a source is a new source
 if its processes are substantially
 independent of an existing source at the
 same site, tn determining whether
 processes are  substantially, independent,
 the permitting or pretreatment authority
 is directed to consider such factors as
.the extent to which the new facility is
 integrated with the existing plant, and  .
 the extent to which the new facility is
 engaged in the same general type of
 activity as the existing source.  For
 example, if a mill operating in the    .
 Bleached Papergrade Kraft and Soda
 subcategory builds and operates  an
 entirely new fiber line that permanently

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supplements the capacity of an existing
fiber line (and also, incidentally,
increases the total quantity of pollutants
discharged by the mill), the new fiber
line would be considered a new source
subject to NSPS.
  EPA believes it is appropriate to
subject a new fiber line that is
substantially independent of an existing
fiber line to new source performance
standards because a mill designing that
new fiber line has pollution prevention
opportunities akin to those available to
greenfield mills. For example, a mill
would have the opportunity to
incorporate pollution prevention
principles when designing a new fiber
line, including a new flow scheme and
water balance. This new fiber line
would provide the opportunity to take
advantage of pollution prevention
savings attributable to reduced chemical
needs (and costs), increased energy
recovery, the possibility of improving
yield, and other operation and
maintenance improvements.
  EPA notes tiiat a fiber line that is
substantially independent of an existing
fiber line is a new source even if the
new fiber line is enrolled in the
Voluntary Advanced Technology
Incentives Program. EPA believes that
this is appropriate because the
supplemental fiber line increases both
the mill's production capacity and its
discharge of pollution to the
environment However, the fiber line
could qualify for incentives if it is
enrolled in the Voluntary Advanced
Technology Incentives Program for
NSPS at the Tier H or Tier m level.
  As reflected in the July 1996 Notice,
61 FR at 36848, EPA had considered
excluding from the definition of new
source those mills that renovated
existing fiber lines but remained at
existing production levels. In response
to comments, EPA has decided not to
introduce production levels as a factor
in determining new source status. First,
taking production levels into account in
determining whether an existing source
becomes a new source would be a
departure from current practice that
EPA believes is not justified in this case.
EPA believes that the new source status
of a subpart B or E mill should be
determined by the degree of process and
production changes made at a mill's
fiber lines—such as the replacement of
existing digesters and bleach plants
with new equipment—because those
changes, not production levels, present
the real opportunities for pollution
prevention represented by NSPS or
PSNS. Moreover, EPA agrees with
comments stating that mills subject to
subpart B or E frequently undergo
changes in various degrees to increase
                          production levels and that many of
                          these changes do not result in or from
                          substantially independent facilities or
                          the total replacement of existing
                          facilities. See DCN 25538 at 70-72.
                          Therefore, the mere fact that a mill
                          increases its production levels does not
                          mean that it concurrently has the
                          opportunity to install the type of
                          advanced pollution prevention
                          technologies represented by NSPS.
                            (3) Non-Continuous Discharger. EPA
                          is changing the regulatory language
                          defining non-continuous dischargers as
                          it applies to subparts B and E. See 40
                          CFR 430.01 (k) (2). EPA is also
                          republishlng, without change, the
                          current definition.of non-continuous
                          dischargers because it continues to
                          apply to the other subparts in part 430
                          and to the determination of technology-
                          based effluent limitations on
                          conventional pollutants for existing
                          dischargers subject to subpart B or E.
                          See40CFR430.01(k)(l).
                            EPA had proposed a new definition
                          that would have defined as a non-
                          continuous discharger a mill that stored
                          wastewaters for periods of at least 24
                          hours and that released that wastewater
                          on a batch basis. In the final definition
                          applicable to subparts B and E, EPA is
                          retaining die storage component of the
                          proposed (and existing) regulation but is
                          not specifying a minimum 24-hour
                          storage period because EPA determined
                          that it had no particular significance for
                          these subparts. However, as indicated in
                          the July 1996 Notice, 61 FR at 36842.
                          EPA is adding language defining as a
                          non-continuous discharger a discharger
                          that releases stored wastewater on a
                          variable flow or a pollutant loading rate
                          basis. Finally, in this new definition,
                          EPA is clarifying that it applies to
                          storage or release of wastewaters
                          required by the permitting authority for
                          the purpose of protecting receiving
                          water quality, among other purposes.
                          See 40 CFR 430.01 (k) (2). For subparts B
                          and E only, EPA also is eliminating the
                          requirement in the existing regulation,
                          at 40 CFR 430.01 (c) (1996 ed.), for the
                          NPDES authority to include maximum
                          day and maximum 30-day average
                          concentration limitations consistent
                          with BPT, BCT, or NSPS limitations as
                          appropriate. See 40 CFR 430.0 l(k). EPA
                          will defer to the NPDES authority to
                          establish maximum day and maximum
                          30-day average limitations that are
                          necessary to protect receiving water
                          quality. In later final rulemaking phases
                          (see section H, table H-2), EPA intends
                          to adopt for remaining subcategories the
                          same definition for non-continuous
                          dischargers as is being promulgated
                          today for subparts B and E.
  (4) Retention of Previously  '
Promulgated Effluent Limitations
Guidelines and Standards.* As discussed
in more detail in Section VI.B.2, EPA is
not revising BPT or BCT effluent
limitations for conventional p>ollutants
for subparts B and E. Therefore, EPA is
retaining the previously promulgated
limitations for these pollutants and
subparts. See 40 CFR 430.22, 430.23,
430.52, 430.53.
  EPA is also retaining previously
promulgated NSPS for subparts B and E
because new sources that commenced
operation prior to the effective date of
today's NSPS remain subject to the
earlier standards for ten years; beginning
on the date construction of the new
source was completed. CWA section
306(d); see 40 CFR 430.25(a), 430.55(a).
  Finally,  as discussed in more detail in
Section VI.B.S.f, subparts B and E
include previously promulgated end-of-
pipe effluent limitations guidelines .and
standards for pentachlorophenol and
trichlorophenol. EPA is also retaining
the accompanying provisions
authorizing mills tiiat do not use those
chemicals  as biocides to certify this fact
to the permitting or pretreatment
authority with the result that they
would not be subject to those
limitations or standards. Id.
  In addition to today's new regulations
for subparts B and E, EPA is recodifying
the previously promulgated BPT, BCT,
BAT, NSPS, PSES and PSNS for the  '
other subparts of the pulp, paper, and
paperboard category. These limitations
regulate.the discharges, of BOD5, TSS,
zinc, and other analytes. Although EPA
is reorganizing the former subcategories
in accordance with the new subcategory
designations, EPA is not changing these
limitations .and standards. See Section
VI.B.1.
  b. Determination of Effluent
Limitations for Permits. (1) Definition of
Production and Production-Normalizing
Parameters. The Agency has based some
of the effluent limitations guidelines '.
and standards promulgated today on
pollutant concentrations. Others are
mass-based, that is, normalized on the'
basis of an appropriate measure of
production. Limitations and standards
for AOX, chloroform, BODS, and TSS
fall into this category.
  This appropriate measure, of
production is known as the
' 'production-normalizing parameter.''
The current definition of "production-
normalizing parameter" is annual off-
the-machine production (including off-  .
the-machine coating, where applicable)
of pulp, paper, and/or paperboard,
divided by the number of operating days
that year. Most paper and paperboard
production is measured at the off-the-

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              Federal Register/Vol. 63. No. 72/Wednesday, April  15,  1998/Rules and Regulations       1&569
 machine moisture content, while market
 pulp is measured as air-dry metric tons
 (10 percent moisture). EPA is not
 changing this definition of production
 as it applies to the effluent limitations
 and standards for any subcategory in
 Part 430 other-than subparts B and E.
 EPA is also retaining the existing
 definition of production for the NSPS
 for conventional pollutants being
 promulgated today for subpart B and
 subpart E. See 40 CFR 430.01 (n) (1).
  • However, EPA is codifying a new
 definition of production for the AOX
 and chloroform limitations being
 promulgated today for subparts B and E.
 See 40-CFR 430.01(n)(2). Under the new
 specialized definition, the production-
 normalizing parameter to be used by
 permit writers in calculating mass-based
 limitations for chloroform and AOX is
 air-dried metric tons of brownstock pulp
. (10 percent moisture) entering the
 bleach plant at the stage during which
 chlorine or chlorine-containing
 compounds are first applied to the pulp.
 In the case of bleach plants that use
 totally chlorine-free bleaching, the
 production-normalizing parameter used
 to calculate mass-based limitations shall
 be air-dried metric tons of brownstock  •'
 pulp  (1,0 percent moisture) entering the,
 first stage of the bleach plant from
 which wastewater is discharged. Id.
 Production, in turn, is defined as the
 annual unbleached pulp production that
 .enters the bleach plant (at ten percent
 moisture) divided by the number of
 operating days of the bleach plant. Id.
   The Agency had proposed to change
 the current definition of production in
 part 430 by adding the following
 statement: "Production in each of the
 foregoing cases shall be determined for
 each mill based upon the highest annual
 production in the past five years
 divided by the number of operating days
 that year." See 58 FR at 66189. EPA has
 decided not to revise the definition to
 include a new time basis because EPA
 is not revising the current BPT and BCT
 effluent limitations guidelines at this
 time for subparts B  and E. Codifying a
 new time basis for determining
 production of AOX and chloroform
 would have required permit writers to
 apply different time bases for
 determining production for purposes of
 calculating BAT limitations and
 limitations for conventional pollutants.
 In EPA's view, this  would have unduly
 complicated the permitting process. In
 addition, for NSPS, introducing a time
 basis would be illogical because new
 sources do not have five years of data
 from which to determine the one
 highest year.
   (2)  Determination of Permit
 Limitations for Multiple Subcategory
 Mills. For facilities with multiple point
 source categories, sufacategories, and
 segments, the appropriate guidelines for
 each category, subcategory (or subpart),
 and segment are used to determine a
 single permit limit for each pollutant.
 Chapter 5 of the U.S. EPA NPDES
 Permit Writers' Manual (EPA-833-B-
 96-003, December 1996) provides
 guidance in determining permit limits
 in situations when the effluent
 guidelines for one subcategpry regulates
 a different set of pollutants 'than the
 effluent guidelines applicable to another
 ' subcategory. For mill subject to today's
 rule, this situation may arise in setting
 permit limits for AOX when the mill has
 production in multiple subcategories.
   For pollutants regulated today at the
 bleach plant (i.e., dioxin, furan,
 chlorinated phenolic pollutants, and
 chloroform, 'and, for subpart B PSES/
 PSNS, AOX), EPA does not believe that
 multiple guidelines will be relevant.
 The bleach plant is unlikely to be used
 for more than one subcategory (or
 segment in subpart E), and thus, the
 permit limit will be determined by the
 limitations and standards for a'single
 subcategory (or segment).
   There may be instances where a
 pollutant is regulated-under the
 limitations and standards promulgated
 today and the permitting authority also
 wishes to establish limits for that
 particular pollutant have yet to  be
, established. For example, the permitting
 authority might need to use best
 professional judgment to determine end-
 of-pipe limits for AOX for a mill with
 production not only in subpart B or E
 (for which AOX limitations are  being
 promulgated today) but also in another
 subpart (for which no AOX limitations _
 have been promulgated) that generates
 AOX. In these instances, the permitting
 authority would use best professional
 judgment to develop pollutant limits for
 wastestreams and pollutants not
 covered by today's rulemaking and
 apply those limits to determine a proper
 permit limitation for the mill.
   Following promulgation of today's
 rules, EPA will develop and publish
 additional guidance for the pulp and
 paper industry for determining permit
 limitations for facilities with production
 in multiple categories^ subcategories,
 and segments.
   c. Compliance With Effluent
 Limitations. (1) Compliance
 Demonstration for In-Plant Limitations.
 The effluent limitations and standards
 that the Agency is promulgating today
 for dioxin, furan, chloroform, the 12
 chlorinated phenolic pollutants and
 AOX will be applied (depending on the
 subcategory and segment) to the total
 discharge from each physical bleach.
  line operated'at the mill. At most mills,
  wastewaters from acid and alkaline
  bleaching stages are discharged to
  separate sewers. At some mills,
  however, bleach plant wastewaters are
  discharged to a combined sewer
  containing both acid and alkaline
  wastewaters.
    For dioxin, furan, and chlorinated
  phenolic compounds, compliance with
  the effluent limitations and standards
  can be demonstrated by collecting
  separate samples of the acid and
  alkaline discharges and preparing a
  flow-proportioned composite of these
  samples, resulting in one sample of
  bleach plant effluent for analysis.
  However, in determining the
  limitations, EPA used data from acid
  and alkaline bleach plant effluents-that
  had been analyzed separately. (EPA also
  used data from combined sewers.) In a
  comment on Method 1653 (DCN 20095
  A8), the commenter reported problems
  in achieving the Minimum Level in
  Method 1653 for samples of composited
  acid and alkaline filtrates. If necessary
  to achieve the Minimum Level, EPA
  recommends that the facility test the
  effluents separately for reliable
  determination of the chlorophenolics,
,  TCDD, and TCDF.
    For chloroform, however, separate
- samples and analyses of all bleach plant
  filtrates discharged separately are
  required to prevent the loss of.
  chloroform through air stripping as the
  samples are collected, measured, and
  composited or through chemical
  reaction when the acid and alkaline
  samples are combined. If separate acid
  and alkaline sewers do not exist,
  compliance samples must be collected
...from the point closest to the bleach
  plant that is or can be made physically
  accessible.
    (2) Compliance with ML Limitations.
  In today's rulemaking for the Bleached
  Papergrade Kraft and Soda subcategory,
. EPA is establishing limitations and
  standards for 12 chlorinated phenolic
  pollutants and dioxin, and alternative
  TCP limitations and standards for AOX,
  that are expressed as less than the
  Minimum Level ("
-------
18570
Federal  Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules and Regulations
pollution reduction achievable for these
pollutants through the use of BAT,
NSPS. PSES and PSNS technologies for
these subparts. (Section VI.B.5.a(4)
provides a detailed discussion about ML
limitations.) EPA intends for mills
subject to ML limitations to have
pollutant discharges with
concentrations less than the Minimum •
Levels of the analytical methods
specified today in § 430.0 l(i).
  Compliance with the ML limitation
for an analyte can only be demonstrated
by using the method specified in
§ 430.01 (i) for that analyte, or other
methods approved in 40 CFR Part 136
that have Minimum Levels equal to or
less than the minimum level specified
today in §430.01 (i). Mills are not
authorized under this rule to
demonstrate compliance with an ML
limitation codified today by using an  -
analytical method with a minimum
level above the Minimum Level
specified in § 430.01 (i).
  The Minimum Level specified for
each method is the lowest level at
which calibration is performed. See 40
CFR 430.01 (i). Laboratories calibrate
their equipment by using standards (i.e.,
samples at several known
concentrations of each analyte).
Calibration is necessary because
laboratory equipment does not measure
concentrations directly. Rather, the
equipment generates signals or
responses from analytical instruments
that must be converted to concentration
values. The calibration process
establishes a relationship between the
                          signals and the known concentration
                          values of the standards. This
                          relationship is then used to convert
                          signals for samples with unknown
                          concentrations.
                           In the calibration process, one of the
                          standards will have a concentration
                          value'at the Minimum Level for each
                          analyte. Because the minimum levels
                          are the lowest levels for which
                          laboratories calibrate their equipment,
                          measurements below the Minimum
                          Level are to be reported as being "less
                          than Minimum Level," or "
-------
             Federal Register/Vol. 63, No.  72/Wednesday, April 15, 1998/Rules and Regulations      18571
sulfite pulp segment. In cases where
other sources of AOX, such as paper
machines, make the end-of-pipe AOX
limitations in this rule impractical or
infeasible for the purpose of assessing
the contribution of AOX from bleach
plant sources, the AOX limitation may
be imposed on internal waste streams
(i.e., bleach plant effluent) before
mixing with other waste streams,
containing AOX. See 40 CFR 122.45(h).
  (4) Minimum Monitoring Frequencies.
(a) Rationale for Establishing Minimum
Monitoring Frequencies. EPA proposed
specific minimum monitoring
frequencies for pollutants in bleach ,
plant and end-of-pipe effluent
discharges. See 58 FR at 66189.
Although EPA proposed minimum
monitoring requirements for BODs and
TSS limitations established as part of
NSPS, EPA is not specifying such  :   '
requirements in the final rule because •
permit authorities have ample
experience regulating these pollutants
and can determine the appropriate
monitoring frequencies. See Section
VI.A.3 for a discussion Of BODS
monitoring requirements under today's
air rule. See also Section VI.B.7 for a
discussion of monitoring requirements
associated with BMPs.
  The final rule specifies minimum
monitoring frequencies for AOX, dioxin,
furan, chloroform, and chlorinated
phenolic pollutants for non-TCF mills
because of the nature and composition
of the discharges from non-TCF
bleached p'apergrade kraft and soda and
papergrade sulfite mills. See 40 CFR
430.02 (a) and (b). Wastewaters from
these mills have been found to contain
chlorinated organic compounds that are
highly toxic and bioaccumulative (e.g.,
dioxin, furan, and chlorinated phenolic
pollutants). Process-related variability
in generating these pollutants is clearly
reflected in available  data. Therefore,
given the environmental significance of
these pollutants, minimum monitoring
is both necessary and appropriate to
ensure that data are available to
permitting authorities,to have an
adequate basis to verify compliance
with the technology-based effluent
limitations and standards. In  contrast to
discharges of BOD5 and TSS,  receiving
water effects from discharges of these
chlorinated pollutants are not as easily
detected, are not as well understood,
and do not manifest themselves'in a
manner that enables a mill to quickly
become  aware of and  react to releases
that may be harmful to the environment.
  The monitoring requirements
imposed in 40 CFR 430.02 will not take
effect until EPA has obtained approval
of these information collection
requirements from the Office  of
 Management and Budget (OMB) under
 the Paperwork Reduction Act, 44 U.S.C.
 3501, etseq. For monitoring
 requirements applicable to direct
 dischargers, EPA will seek to amend the
 NPDES Discharge Monitoring Report
 ICR No. 229, OMB approval number
 2040-0004, prior to its expiration on
 May 31, 1998. For indirect dischargers,
 EPA will seek to add specified
,• monitoring requirements for indirect
 dischargers^to the National Pretreatment
 Program ICR No. 2, OMB approval
- number 2040-0009, when it expires on
 October 31, 1999. EPA will not seek to
 amend this ICR prior to its expiration
 date because the monitoring
 requirements for indirect dischargers do
 not become effective until April 16,
 2001  for existing indirect dischargers,
 and EPA anticipates no new indirect
 dischargers commencing discharge prior
 to the ICR expiration date.
   (b)  Duration of Minimum Monitoring
 Frequency. The final rule includes
 minimum monitoring frequency
 requirements for demonstrating
 compliance with limitations and
 standards for dioxin, furan, chloroform,
 the 12 chlorinated phenolic pollutants, .
 and AOX for non-TCF mills. See 40 CFR
 430.02(a). Permitting and pretreatment
 authorities retain authority to specify
 more frequent monitoring on a case-by-
 case basis and must specify AOX
 monitoring frequency for TCP mills on
 a best professional judgment basis. The
 minimum monitoring frequencies are
 applicable to mills in Subparts B and E
 for a duration of five years after
 inclusion in NPDES permits for direct
 dischargers. See 40 CFR 430.02(b). For
 existing indirect dischargers, the
 minimum monitoring requirements
 apply until April 17, 2006 which
 reflects a five-year monitoring period '
 following the termination of the three-
 year compliance period authorized by
 CWA Section 307(b) (1). Id. For new
 indirect dischargers, the five year
 minimum monitoring period
 commences upon operation. Id.
  EPA has determined the minimum
 monitoring frequencies established-by
 this rule are necessary to demonstrate
 compliance with the effluent limitations
 guidelines and standards promulgated
 today, particularly considering the
 degree of change that is expected to
 occur to pulping and bleaching
 processes as this rule is implemented. In
 establishing the minimum monitoring ,
 frequencies for the regulated pollutants,
 the Agency has struck a balance
> between the cost of the monitoring
 regimen and the need to ensure that
 sufficient data are consistently available
 to permitting authorities to provide an
 adequate basis to verify compliance
 with the effluent limitations and
 standards and to mills to quickly
 become aware of and react to releases
 that may be harmful to the environment.
  The Agency has selected a minimum
 monitoring frequency of once per month
 for dioxin, furan, and chlorinated
 phenolic pollutants. See 40 CFR
 430.02(a). These pollutants are the most
 toxic and bioaccumulative among those
 regulated yet also are the most costly to
 analyze (total cost pf approximately
 $1,325 per sample; $825 per sample for
 dioxin, furan, and $500 per sample for
 all  12 chlorinated phenolic analytes).
 EPA expects that 12 data points  for each
 pollutant per year, together with daily
 end-of-pipe AOX data and information
 on process conditions from detailed mill
 logs (e.g., unbleached pulp kappa
 numbers, bleach plant kappa factors,
 bleached pulp brightness, etc.) that are
 reviewable upon request, will yield a
 meaningful basis for establishing
 compliance with the promulgated
 limitations through long-term trends
 and short-term variability in dioxin,
 furan, and chlorinated phenolic
 pollutant discharge loading patterns.
  The Agency has selected a minimum
 monitoring frequency of once per week
 for  chloroform. See 40 CFR 430.02(a).
 This minimum monitoring frequency
 has been selected because data available
 indicate there can be considerable
 temporal Variability of this pollutant in
 bleach plant wastewaters. Therefore,
 more data are required to adequately
 assess compliance with the promulgated
 limitations and standards on both a
 long-term and short-term basis. While
 the cost for laboratory analysis of
 chloroform (approximately $270 per
 sample) is much lower than for dioxin,
 furan, and chlorinated phenolic
 pollutants, chloroform sampling
 requirements are more extensive and
 rigorous  (e.g., sampling of all bleach
plant filtrates using special equipment
 and containers to prevent
 volatilization). Weekly data (52 data
 points) and information on process
 conditions from detailed mill logs that
 are  reviewable upon request are
 expected to yield an adequate basis for
 establishing long-term compliance
 trends in chloroform discharge loadings
 and developing process control
 strategies to ensure the short-term
 compliance in chloroform discharge
 loadings.
  The Agency has selected a minimum
 monitoring frequency of once every day
 for AOX for non-TCF mills. See 40 CFR
 430.02(a). This minimum monitoring
 frequency has been selected because
 there can be considerable daily
 variability in chlorinated organic
 discharge loadings to receiving streams

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 18572      Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules  and Regulations
 reflecting both bleach plant discharge
 patterns and secondary biological
 treatment system performance that is
 readily measured at reasonable cost. At
 this time, AOX analysis costs $ 120 per
 sample. This cost is likely to decrease
 after this regulation is promulgated with
 increased capacity at commercial
 laboratories and analytical laboratories
 on-site at many mills. While this bulk
 parameter measures all chlorinated
 organic constituents in wastewater and
 not individual pollutants, daily
 monitoring will provide an essentially
 continuous data stream on a quick
 turnaround basis to mill operating
 personnel and permit compliance '
 authorities to assess and control process
 technologies and manage the
 performance of end-of-pipe biological
 treatment systems.
  The minimum monitoring frequencies
 in this rule as  described above will
 provide sufficient information to
 evaluate mill compliance with the
 promulgated limitations over the long
 term and allow permitting and
 pretreatment authorities to judge
 whether a different frequency of
 monitoring is warranted after the initial
 compulsory period of minimum
 monitoring has been completed. These
 data will prove useful to permitting
 authorities and also to mill operators in
 developing a robust mill-specific
 compliance data base with which to
 analyze the effects of mill processes on
 effluent trends. The five-year duration
 of the minimum monitoring
 requirements is consistent with permit
 issuance cycles, will ease administrative
 burdens on operators and permitting
 authorities, and will provide data useful
 for establishing appropriate monitoring
 requirements during future permit
 renewals.
  Following completion of the
 compulsory five-year monitoring period
 set forth by this rule, the permitting or
 pretreatment authority has discretion to
 adjust monitoring requirements as
 deemed appropriate on a case-by-case
 basis. For those mills consistently
 demonstrating reductions superior to
 those required merely to comply with
 their permit requirements, EPA believes
 that it may be appropriate to allow less
 frequent monitoring to reduce the
 regulatory burden. EPA expects the
 permitting or pretreatment authority
 also to consider the mill's compliance
 and enforcement history in determining
 monitoring frequencies. This avenue for
 relief provides incentives for voluntary
 reductions of pollutant discharges
 through such means as reuse and
recycling. EPA also expects permitting
and pretreatment authorities to consider
whether poor performance, compliance
 or enforcement history, or other site-
 specific factors indicate a need to
 impose more frequent monitoring than
 that specified in this rule.
   EPA has issued interim guidance for
 performance-based reductions of NPDES
 permit monitoring frequencies, which
 may be useful for permit writers and
 pretreatment authorities in determining
 alternative monitoring frequencies at the
 close of the compulsory five-year period
 imposed by this rule. (See Interim
 Guidance for Performance-Based
 Reductions of NPDES Permit
 Monitoring Frequencies, April 1996,
 EPA-833-B-96-001). This document
 provides guidance to permit writers on
 implementing EPA's NPDES regulations-
 regarding appropriate monitoring in
 permits and describes the conditions
 under which reduced monitoring would
 be justified. Pretreatment control.
 authorities also may find this guidance
 useful in setting monitoring frequencies
 for industrial users of POTWs. The
 current guidance applicable to all
 industrial point sources is dated April
 19, 1996, and is subject to revision.
 '  (c) Certification for TCP Bleaching.
 MUls certifying in their permit
 application process that all bleaching
 processes are totally chlorine-free are
 exempted from the minimum
" monitoring frequencies established in
 this rule, provided that analytical data
 routinely submitted as part of the permit
 application confirm the absence of
 chlorinated compounds. See 40 CFR
 430.02. EPA believes it is appropriate to
 exclude TCP mills from the minimum
 monitoring frequencies for chlorinated
 compounds since any process change
 that introduces chlorinated compounds
 to the bleaching process requires
 notification to the permitting authority
 and would result in reopening the
 permit for modification. See, e.g., 40
 CFR 122.21(g)(3), 122.21(g)(7), and
 122.41(1).
   (d) ECF Certification in Lieu of
 Monitoring. In response to comments,
 EPA has considered whether
 certification of ECF bleaching processes
 can be used in lieu of monitoring.
 Because of the effect that operation and
 control of pulping and bleach plant
 processes have on generation of
 chlorinated pollutants, EPA has
 determined that the information
 available at this time does not
 demonstrate that ECF certification alone
 is sufficient to ensure compliance with
 the regulations promulgated today.
 Therefore, this rule does not allow
 certification of ECF bleaching to replace
 monitoring. (See DCN 14497, Vol. I, and
 section VI.B.5 of this preamble for a
 discussion of factors affecting
 chlorinated pollutant generation.)
  Elsewhere in today's Federal Register,
 however, EPA is proposing to allow
 mills to demonstrate compliance with
 chloroform limitations by certifying that
 they use ECF bleaching processes and
 that these processes are operated in a
 manner consistent with certain process
 and related factors. In this notice, EPA
 also is seeking additional chloroform
 data, along with corresponding process
 data, to determine whether am ECF
 certification process for chloroform
 should require certification of certain
 process factors; for example, factors
 relating to residual lignin content,
 chemical application rates, and other
 process variables.
  d. Intake Credits, Upsets, and
 Bypasses. An intake credit is an
 adjustment made to an effluent
 limitation to reflect the presence of a
 pollutant in the discharger's intake
 water beyond what is removed by an
 installed technology that would
 otherwise meet the technology-based
 effluent limitation or standard. EPA's
 regulations concerning intake credits are
 set forth at 40 CFR 122.45 and 40 CFR
 403.15.
  A "bypass" is an intentional diversion
 of waste streams from any portion of a
 treatment facility. An "upset" is an
 exceptional incident in which there is
 unintentional non-compliance with
 technology-based permit effluent
 limitations because of factors; beyond
 the reasonable control of the permittee.
 EPA's regulations concerning bypasses
 and upsets are set forth at 40 CFR
 122.41 (m) and (n).
  e. Variances and Modifications to
 Permits. (1) Variances. Dischargers
 subject to the BAT and PSES limitations
 promulgated in these final regulations
 may apply for a Fundamentally
 Different Factors (FDF) variance under
 the provisions of section 301(n) of the
 CWA. The FDF variance considers those
facility-specific factors that a. permittee
 believes to be uniquely different from
the factors considered by EPA in
 developing an effluent guideline to
 determine whether the effluent
guidelines limitations should be
 inapplicable to the permittee's facility.
An FDF variance is based only on
 information submitted to EPA during
the rulemaking establishing the effluent
limitations, or on information the
applicant did not have a reasonable
opportunity to submit during the
rulemaking process. See CWA section
301(n)(l)(B). If fundamentally different
factors are determined to exist, the
alternative effluent limitations for the
petitioner must be no less stringent than
those justified by the fundamental
difference. See CWA section'
301 (n)(1) (C). The alternative effluent

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             Federal Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules and Regulations      18573
limitation must not result in non-water
quality environmental impacts
significantly greater than those accepted
by EPA in promulgating the effluent
limitations guidelines or pretreatment
standards. See CWA section
301 (n) (1) (D). PDF variance requests,
along with all supporting information
and,data, must be received by the
permitting authority within 180 days
after publication of the final effluent
limitations'guideline or standard. See
CWA section 301(n)(a). The specific
regulations covering PDF variance
requirements and administration are
found at 40 CFR 122.21(m)(l), 40 CFR
Part 125, Subpart D, and 40 CFR 403.13,
'  Dischargers may also apply for a
variance from the BAT limitations on
non-conventional pollutants in these
final regulations under CWA section
301(c) (for economic reasons) and 301(g)
(for water quality reasons). Regulations
for the administration of these variances
are specified in 40 CFR 122.21 (m) (2).
  New sources subject to NSPS or PSNS
are not eligible for variances. See E.I.
DuPontv. Train, 430 U.S. 112,(1977).
   (2) Permit Modifications. It may be
necessary to modify a permit at some
point after it has been issued. In a
permit modification, only the
conditions subject to change are
reconsidered. All other permit
conditions remain in effect unchanged.
A permit modification may be triggered
iri several ways, such as when the
regulatory agency inspects the facility
and finds a need for the modification, or
when information submitted by the
 permittee suggests a need for a
 modification. Any interested person
 may request that a permit modification
 be made. There are two classifications of
 modifications: major and minor. From a ,
 procedural standpoint, they differ
 primarily with respect to the public .
 notice requirements. Major
 modifications require public notice
 while minor modifications do nqt. See
 40 CFR 122.63. Virtually all
 modifications that result in less
 stringent conditions are treated as a
' major modification, with provisions for
 public notice and comment. Conditions
 that would necessitate a major
 modification of a permit are described
 in 40 CFR 122.62. Minor modifications
 are generally non-substantive changes.
 The conditions for minor modification
 are described in 40 CFR  122.63.

 VII. Environmental Impacts

   This section of the preamble describes
 the environmental impacts of the air
 and water regulations being
 promulgated today, and the
 environmental impacts of the MACT n
 regulations being proposed today. These
 impacts are described in terms of
 reductions in air pollution emissions
 expected as a result of the final MACT
 I and proposed MACT n rules, as well
 as 'the reduction in water pollution
 (effluent) discharges expected as a result
 of today's effluent limitations guidelines
 and standards for Subparts B and E. (In
 this-section, all references to MACT I
 include MACT m unless expressly
 noted.) The emissions and effluent
reductions described in this section
generate the quantified and monetized
benefits described in Section Vffl of this
preamble. This section also discusses
the non-water quality environmental
impacts of the effluent limitations
guidelines and standards promulgated
today, including air emissions, energy
requirements, solid waste generation,
water use, and wood consumption.
Sections n.B.2 and VILA describe air
and water pollution control
technologies for each subcategory
regulated today: Kraft, Soda, Sulfite.'and
Semi-chemical mills that are subject to
MACT I and MACT m standards; and
bleached papergrade kraft and soda and
papergrade sulfite mills that are subject
to effluent limitations guidelines and
standards. EPA estimates that the
application of these technologies by the
155 mills regulated by today's air rules,
including 96 of those mills also
regulated by today's water rules, will
substantially reduce air emissions and
water pollution discharges, as described
in Section VII.B.   .

A. Summary of Sources and Level of
Control

  Table VII-1 shows a summary of  '
sources and technology bases/level of
control for the final BAT/PSES effluent
limitations guidelines and standards,
and the final MACT I standards. The
summary of sources and level of control
for MACT n are discussed in the
preamble for the proposed MACT
standards elsewhere in today's Federal
Register.

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18574      Federal Register/Vol.  63,  No. 72/Wednesday, April 15,  1998/Rules and Regulations
            TABLE VIM.—FINAL CLUSTER RULES—SOURCES AND TECHNOLOGY BASES/LEVEL OF CONTROL
Toxic and nonconventional pollutant effluent control (BAT, PSES, and BMP
technology bases) by subcategory
Bleached
papergrade
kraft and soda






EOF: 100%
Substitution
of Chlorine
with Chlorine
Dioxide; ef-
fective
brownstock
washing;
elimination of
hypochlorite;
oxygen-and
peroxide-en-
hanced ex-
traction;
closed
bfown-stock
screening;
and other
processes
discussed at
Section






Papergrade sulfite
Calcium,
magnesium,
and sodium
sulfite
Ammonium
sulfite
Specialty
grade
Selected BAT/PSES





TCF:
Oxygen-
and perox-
ide-en-
hanced ex-
traction;
peroxide
bleaching;
elimination
of all chlo-
rine-con-
taining
com-
pounds;
and im-
proved
pulp clean-
ing.









EOF: 100%
Substi-
tution of
Chlorine
with Chlo-
rine Diox-
ide; perox-
ide-en-
hanced ex-
traction;
elimination
of hypo-
chlorite;
and use of
dioxin-and
furan-pre-
cursor-free
defoamers.









ECF: 100%
. Substi-
tution of
Chlorine
with Chlo-
rine Diox-
ide;
oxygen-
and perox-
ide-en-
hanced ex-
traction;
elimination
of hypo-
chlorite;
and use of
dioxin and
furan pre-
cursor-free
defoamers.







Best Man-
agement
Practices
(BMP), (Sub-
parts B and
E)
Spent
Pulping .
Liquor Spill
Prevention
and Con-
trol.



























Hazardous air pollutant emission control (MACT I and III
levels of control) by subcategory
Kraft
Soda and
semi-
chemical
Sulfite
Control LVHC System Vents





Control Se-
lected
HVLC
Vents and
Named
High HAP
Con-
centrated
Conden-
sate
Streams.










Control Pulp
Washing
System
Vents at
New
Sources.















Control Pulp
Washing
System
Vents, and
Control
Liquor and
Acid Tank
• Vents at
New
Sources.










t
Secondary
and nonwood
fiber, and
mechanical
wood fiber
See Bleach
Plant Block
Below
























Bleach Plant: Control Chlorinated HAP frorh Vents at Stages
That Use Chlorinated Bleaching Chemicals, and Control
Chloroform Emissions by Complying with BAT codified at
40 CFR 430.24(a) and (e) and 40 CFR 430.54(a) and (c) or
by 100% substitution of chlorine with chlorine dioxide and
elimination of hypochlorite.
B. Air Emissions and Water Effluent
Reductions

1. Air Emissions Reductions

  The reductions described in this
section are derived from estimated air
emissions reductions at all 155 pulp and
paper mills in die CAA kraft, soda,
sulfite and semichemical subcategories
that are subject to MACT I and MACT
n standards. These mius include the 96
mills subject to the effluent limitations
guidelines and standards promulgated
today. All references in this section to
MACT I air emissions refer to the
expected effects of implementing both
the air and water portion of the final
Cluster Rules.
  Implementation of the MACT portion
of the Cluster Rules is expected to
significantly decrease HAP emissions.
Table VH-2 presents the environmental
impacts of the Final Cluster Rules (BAT,
PSES, BMPs, and MACT I) and the Final
Cluster Rules in combination with the
MACT n proposed standards.
  The air emission impacts presented in
Table VJJ-2 are calculated based on
mill-specific processes and emission
control information, emission factors,
and control levels summarized in Table
Vn-1. A more detailed discussion of the
calculation of the environmental '
impacts for the final MACT standards is
presented in Chapter 20 of the
Background Information Document
described in Section XI of this
preamble. A detailed discussion of the
environmental impacts of the proposed
MACT n is contained in the docket for
the proposed MACT II standard. As
shown in Table VIJ-2, these final
Cluster Rules not only reduce HAP
emissions from all CAA and CWA
subcategories regulated, but they also
result in decreases of volatile organic
compounds and total reduced sulfur
using industry data updated to 1996.
Emissions of particulate and carbon
monoxide are estimated to increase
under the final rules, but are expected
to decrease when combined with the
proposed MACT II standards. Emissions
of sulfur dioxides, and, to a lesser
degree, nitrogen oxides are estimated to
increase.  Sulfur dioxide emissions are
generated primarily from the
combustion of sulfur-containing
compounds, such as TRS, in the vent
streams at kraft mills. The increases in
carbon monoxide, nitrogen oxide, and
particulate matter air emissions are
primarily from the combustion of air
vents in the pulping area and increased
energy to produce additional steam for
steam strippers and chlorine dioxide for
the bleaching system. However, these
emission increase estimates are likely
overstated because they do not account
for the fact that some mills in sensitive
areas for sulfur dioxide already have
sulfur dioxide controls in place or may
choose alternative controls available in
the final MACT rule that mitigate these

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             Federal Register/Vol.  63,  No. 72/Wednesday, April 15,  1998/Rules and Regulations       18575
 increases. The health effects and
 benefits of these emission reductions
and increases are discussed in Section
VEDLG. 1 of this notice.
             TABLE VII-2.—AIR EMISSION IMPACTS OF PULP AND PAPER RULES (ALL CAA SUBCATEGORIES)
( ' .Air pollutants
Hazardous Air Pollutants 	 	 	 	 	 	 	 	 	 	
Volatile Organic Compounds 	 	 	 : 	 ;
Total Reduced Sulfur 	 	 	 	 	 	 	 	
Particulate 	 	 	 	 	 	 	 	 	 ; 	
Carbon Monoxide 	 	 	 , 	 	 	 	 	 ; 	 	
Nitrogen Oxides 	 	 	 	 	 	 	 	 '. 	 	 	 	
Sulfur Dioxides 	 : 	 t 	 	

Baseline air
emissions
(Mg/year)
. 240,000
900,000
150,000
*NA
NA
NA
NA
Air emission reductions
(Mg/year)
Final cluster
rules
139,000
409,000
« 79,000
b(83)
(8,700)
(5,200)
(94,500)
Final cluster
•rules and pro-
posed MACT II
142,000
440,000
79,000
24,000
49,000
(5,700)
(94,400)
  =» Industry process data was not collected to calculate emissions for these pollutants increases and decreases for these pollutants reflected in
 columns to the right are increases or decreases of these pollutants caused by projected installation of MACT control equipment and secondary
 air emission impacts of BAT, PSES, and BMPs.                                                            .
  b Values in ( ) are estimated emission increases over baseline air emissions.
 2. Water Pollutant Reductions
   Table VH-3 shows the estimated   '
 baseline (as of mid-1995) and the  -
 reductions from baseline expected from
 the BMP requirements being
 promulgated today for the Bleached
 Papergrade Kraft and Soda and
Papergrade Sulfite subcategories.
(Hereafter, references to BAT/PSES    .
impacts include impacts associated with
today's BMP requirements.) Calculation
of these pollutant reductions is
discussed in Sections VI.B.5.a(3) and
VI.B.6.b(5). For a discussion of the
 estimated effluent reduction benefits
 associated with the BAT limitations
 promulgated for the Voluntary
 Advanced Technology Incentives
 Program for the Bleached Papergrade
 Kraft and Soda subcategory, see Section
 DC. A.6 and Table IX-1.
                 TABLE VI1-3.—ESTIMATED POLLUTANT REDUCTIONS FROM BASELINE FOR BAT/PSES
Pollutant parameter
2,3,7,8-TCDD . 	 	 	 '. 	 	 	 	 	 	
2,3,7,8-TCDF 	 	 	 	 	 	 	 	 	 	 	 ...:..
Chloroform 	 	 	 	 ..: 	 	 	
Chlorinated Phenolics 	 	 	 	 	 	 	 	
AOX 	 •. 	 •. 	 	 	

Units
o/vr 	
o/vr 	 	
kko/vr .
kko/vr 	
kkg/yr

Baseline
discharge
for BPK
mills
15
115
48
55
36 300

Estimated
reductions:
Final BAT/
PSES for
BPK mills
11
107
40
45
24200

Baseline dis-
charge for
PS mills
078
67
54
20
4 380

Estimated re-
ductions:
Final BAT/
PSES for PS
mills
0 65
64
52
1 s
A nm

  BPK—Bleached Papergrade Kraft and Soda subcategory.
  PS—Papergrade Sulfite subcategory.
  g—grams.                     ,          .
  kkg—metric ton (1,000 kilograms or 1 megagram (Mg)).
  The air quality impacts shown in
Table VH-2 and the water pollutant
effluent reductions shown above are
used in the following section to estimate
reduced human health and
environmental risk attributable to
today's.rules. These estimates also form
the basis for estimating monetized
benefits in the following section.

C. Non-Water Quality Environmental
Impacts of Effluent Limitations
Guidelines and Standards (BAT, PSES,
'and BMPs)                .'  .

  Sections 304(b)(2)(B) and 306(b)(l)(B)
of the Clean Water Act require EPA to
consider the non-water qualify
. environmental impacts of effluent
limitations guidelines and standards. To
address these statutory requirements,
EPA analyzed the air emissions, energy
requirements, solid waste generation
impacts, arid other environmental
impacts of the compulsory BAT, PSES,
and BMPs being promulgated today for
the Bleached Papergrade Kraft and Soda
and Papergrade Sulfite,subcategories.
The results of this analysis are
presented below. In performing the
analysis, EPA assumed that each mill in
the regulated subcategory would install
the model technologies upon which
today's limitations and standards are
based.

1. Air Emissions

  The air emissions reductions of BAT,
PSES, BMPs, and MACT I, in
combination, are presented in Section
VII.B. 1 above. This section presents the
 estimated air emission impacts of BAT,
 PSES, and BMPs on the 86 mills with
 production in the Bleached Papergrade
 Kraft and Soda subcategory and the 11
 mills with production in the Papergrade
 Sulfite subcategory. (One mill has co-
 located operations in both subcategories
•that separately contribute to the number
 of mills in each subcategory.)
  The control technologies that form the
 basis of effluent guidelines and
 standards promulgated today involve
 changes in the processes used to^
 produce bleached pulp. These changes
 affect the rate at which air pollutants,
 including HAPs, are emitted from the
 pulping and bleaching processes that
 are subsequently controlled by MACT I.
 As shown in Table Vri-4, the process
 changes at bleached papergrade kraft

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18576     Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules  and Regulations
and soda and papergrade sulfite
facilities subject to BAT, PSES, and
BMPs decrease the emissions of some
HAPs but have little impact on others.
For example, the elimination of chlorine
and hypochlorite from bleaching
processes, part of the basis for BAT and
PSES, will reduce the emission of
chloroform in the Bleached Papergrade
Kraft and Soda subcategbry by 66
percent [but will have a much smaller
impact on the emission of methanol.]
The application of the BAT, PSES, and
BMPs promulgated today for the
Bleached Papergrade Kraft and Soda
subcategory will reduce the emission of
total HAPs from the sources controlled
by MACTI from 149,000 Mg/year to
139,000 Mg/yr (7 percent reduction)  "
without taking into account further
reductions achieved by MACT I
controls.
TABLE VII-4.—IMPACT OF BAT, PSES, AND BMP: BLEACHED PAPERGRADE KRAFT AND SODA AND PAPERGRADE SULFITE
                      MILLS AIR EMISSIONS FROM SOURCES SUBJECT TO CONTROL BY MACT I
•f
Air pollutants
Total Hazardous Air Pollutants 	 	
Chloroform 	
Volatilo Organic Compounds 	
Total Reduced Sulfur 	 '. 	

Bleached papergrade kraft
and soda [Mg/year]
Baseline
emissions
149,000
9,510
569,000
100,000
Emission
reductions
from BAT/
PSES/
BMPs
10,000
6,060
11,000
1,300
Papergrade sulfite (all
segments) [Mg/year]
Baseline
emissions
5,190
13
6,020
0
Emission
reductions
from BAT/
PSES/
BMPs
1,930
8
2,270
0
  The process changes that form the
basis of BAT, PSES, and BMP's increase
by approximately 1.5 percent the
amount of spent pulping liquor
combusted by bleached papergrade kraft
mills and papergrade sulfite mills. See
the Supplemental Technical
Development Document, DCN  14487.
HAPs and criteria air pollutants (volatile
organic compounds, particulate matter,
carbon monoxide, nitrogen oxides, and
sulfur dioxides) are generated from
combustion of spent pulping liquor by
bleached papergrade kraft and sulfite
mills. As a result, as shown in Tables
VII-5a and VII-5b, the emission of total
HAPs from spent pulping liquor
combustion sources (i.e., recovery
boilers) will increase by 1.1 percent at
bleached papergrade kraft and soda
facilities and 1.9 percent at papergrade
sulfite facilities above the 1995 baseline.
However, the net increase in HAP
emissions from these combustion
sources (235 Mg/yr) represents 1.1
percent of the HAP emissions from all
sources subject to control by MACT I, E,
and m. Although BAT, PSES, and BMPs
result in a small increase in HAP
emissions from recovery boilers, the
combined effect of the Cluster Rules
(including proposed MACT H) is a net
decrease of 60 percent in total HAP
emissions from all controlled sources.
See Table VH-2.
  TABLE VII-5A.—IMPACT OF BAT, PSES, AND BMP: BLEACHED PAPERGRADE KRAFT AND SODA AIR EMISSIONS FROM
  RECOVERY BOILERS AT BLEACHED PAPERGRADE KRAFT AND SODA MILLS SUBJECT TO PROPOSED MACT II [MG/YEAR]

Hazardous Air Pollutants 	
Volatile Organic Compounds 	 	 	
Total Reduced Sulfur 	
Particulate Matter 	
Carbon Monoxide 	
Nitrogen Oxides 	 "...... 	 	 	
Sulfur Dioxides 	

1995
baseline
emission
19900
19500
2650
31 400
124000
36 100
67 800

Emission
increases
from BAT/
PSES/
1 BMPs
220
213
27
360
1 440
423
784

MACT II
emission
reductions
25
0
o
12 900

o


Net change
after MACT
II"
195
213
27
M 9 *54ftt
1 AATt
423
784

  •Parentheses indicate emissions decreases below baseline.

    TABLE VII-5B.—IMPACT OF BAT, PSES, AND BMP: AIR EMISSIONS FROM RECOVERY BOILERS AT PAPERGRADE
                           SULFITE MILLS SUBJECT TO PROPOSED MACT II [MG/YEAR]




,
Hazardous Air Pollutants 	

1995
baseline
emission

2,110
Emission
increases
from BAT/
PSES/
BMPs
40

MACT II
emission
reductions

N/S

Net change
after MACT
II

40
  N/S—Not Significant.

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             Federal Register/Vol. 63, No. 72/Wednesday, ApriL 15, 1998/Rules and  Regulations
                                                                    18577
   Increases in the emission of criteria
 pollutants are also listed in Table Vfl"-
 5a. The emission of total criteria air
 pollutants from spent pulping liquor
 combustion sources (i.e., recovery
 boilers) at mills in the Bleached
 Papergrade Kraft and Soda subcategory
.will increase by 1.2 percent as a result
 of BAT, PSES, and BMPs and will be
 only slightly mitigated by MACT H
 controls. The increases in nitrogen
 oxides (423 Mg/yr), sulfur dioxides (784 •
 Mg/yr), and carbon monoxide (1440 Mg/
 yr) emissions are minor relative to
 nationwide emissions, which are 19.8
 million Mg/yr for nitrogen oxides, 16.6
 million Mg/yr for sulfur dioxides, and
 83.6 million Mg/yr for carbon monoxide
 (OAQPS, 1995).
   EPA concludes that the technologies
 that form the basis of BAT, PSES, and
 BMPs for bleached papergrade kraft and
 soda and papergrade sulfite mills pose
 no significant adverse impacts to and
 indeed have some benefits for air
 quality. EPA bases this determination
 on the following:

 ^-Total HAP emissions from the sources.
   subject to control by MACT I and
   proposed MACT n from kraft and
   sulfite pulping and bleaching
   processes decrease as a result of BAT,
.   PSES, and BMPs;
—HAP emissions would increase by less
  than one percent from bleached kraft
  combustion sources and increase by
  less than two percent from papergrade
  sulfite combustion sources; and
—The increase in criteria air pollutants
  for the Bleached Papergrade Kraft and
  Soda and Papergrade Sulfite
 . subcategories is minor relative to
  current national industrial emissions.
  EPA examined the effect of BAT
combined with BMPs on the generation
of CO2 by considering the overall mill
carbon balance and the energy balance.
Anthropogenic generation of water
vapor is minuscule relative to
atmospheric recycling and is normally
ignored in greenhouse gas analysis.
Therefore, water vapor is ignored here.
EPA concluded that neither option
would have an impact on the total
emission of greenhouse gasses from
mills due tt> pulping processing. There,
EPA concludes that the increased CO2
emissions attributable to BAT pose no
significant adverse non-water quality
environmental impact.

2. Energy Impacts
  The impacts of BAT, PSES, and BMPs
on the energy use of the 86 mills -with
production in the Bleached Papergrade
Kraft and Soda subcategory and the, 11
mills with production in the Papergrade
 Sulfite subcategory are summarized in
 Table VII-6. The process changes that
 form the basis of the regulations
 promulgated today are estimated to
 result in an increased energy <.
 requirement of 3.70 trillion Btu/yr in oil
 equivalent at the 96 affected pulp and
 paper mills. This represents a 0.82
 percent increase from the current total
 Bleached Papergrade Kraft and Soda
 subcategories energy consumption
 (papergrade sulfite total energy
 consumption is minor relative to
 bleached papergrade kraft) of 499.4
 trillion Btu/yr in oil equivalent (DCN
 14510). The increased energy use is due
 to the increased off-site chemical
 manufacturing electrical demand (met
 by off-site electric generating stations)
 and on-site electrical demand (also met
 by off-site electric generating stations,
 and commonly referred to as  ,  ,
 "purchased energy"). These increased
 demands are partially offset by the
 decreased steam demand (met by on-site
 power boilers and recovery furnaces).
 Oil equivalent is used to express the
 combined effects of changes in thermal
 energy and electric power.lt is based on
 the assumption that marginal changes in
•electric power demand caused by the
 regulation will be supplied by
 conventional condensing-type oil-fired
 power stations. See DCN 14487.
       TABLE VII-6.—ENERGY IMPACTS OF BAT, PSES, AND BMP: BLEACHED PAPERGRADE KRAFT AND SODA AND
                                            PAPERGRAQE SULFITE MILLS
: Energy impacts
On-Site Electricity Demand* 	 ....
Off-Site Electricity Demand* 	 	 	
Steam Demand 	 	 	 	 	 	 	
Total Energy Demand** 	 	 	 	 	
Total Enerav Equivalent 	 .' 	 	 	
Units
Trillion Btu/yr in oil equivalent 	 	
Trillion Btu/yr in oil equivalent 	
Trillion Btu/yr in oil equivalent 	 	 	
Trillion Btu/yr in oil equivalent 	
Number of Households*** 	 	 	
Bleached
papergrade
Kraft •
(2.37)
10.0
(288)
478
' 46.100
Papergrade
sulfite (all
segments)
(00381)
1 tt 05)
(0010)
n 08)
(10.400)
Combined
total
(241)
895
(289)
370
35.700
  Parentheses indicate energy savings.
  'Assumes an overall electrical generating efficiency of 25 percent. (DCN 14797).                  .
  * * Totals do not equal the sum of each line item due to rounding. Refer to Section 11 of the Supplemental Technical Development Document
 which presents detailed energy estimates.
  *** Assumes 103.6 million Btu/household/yr (Energy Information Administration (DOE) 1993).                       •
   The-manufacture of sodium chlorate,
 the raw material used at pulp mills to
 manufacture chlorine dioxide, requires
 much more electrical energy than the
 manufacture of chlorine or other
 commonly used bleaching chemicals.
 As a result, off-site electrical demand
 increases by 8.95 trillion Btu/yr (2.61
 million MWhr/yr)  because of the
 effluent limitations guidelines and
 standards promulgated today. EPA
 estimates of changes in energy demand
 as mills install advanced technologies
 can be found in DCN 14488.
   The total increase in energy demand
 resulting from this rule is equivalent to
the energy required for 35,700
households. Compared to the most
recent data for total national energy
consumption, the rule represents a
0.004 percent increase in energy
demand. EPA concludes that the
technologies that form the basis of BAT,
PSES, and BMPs for bleached
papergrade kraft and soda and
papergrade sulfite mills do not pose  ,
significant adverse impacts in nation-
wide energy demand. '
3. Incidental BODs Removal and Sludge
  The process changes that form the
basis for BAT, PSES, and BMP increase
 by approximately 1.5 percent the
 amount of spent pulping liquor
 collected and combusted by bleached
 papergrade kraft and soda mills. Spent
 pulping liquor is a significant source of
 BODs loadings at these mills. The
 collection and combustion of this spent
 pulping liquor results in an
 approximately 20 percent decrease in
 BODs load into treatment. (EPA expects
 that papergrade sulfite mills will have
 similar trends, but lacks data to
 calculate residuals.) •.
   Sludge is generated as a byproduct of
»the wastewater treatment systems used
 at pulp and paper mills. Primary sludge

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 18578      Federal Register/Vol.  63, No. 72/Wednesday, April  15,  1998/Rules and Regulations
 (i.e.. solids removed during physical
 wastewater treatment processes such as
 sedimentation prior to biological
 treatment) is high in wood fiber and
 volatile solids. Secondary sludge is the
 product of biological treatment in which
 microorganisms consume organic matter
 (BODs) in the wastewater. Secondary
 sludge is a gelatinous mixture of
 bacterial and fungal organisms. Because
 of the reduction in BODs load into
 treatment, the combined application of
 BAT limitations, PSES, and BMPs
 promulgated today will decrease sludge
 generation by 35,900 kkg/yr (39,600
 short tons/yr), which represents a 2
 percent reduction from the mid-1995
 baseline for subpart B and E mills.
   Sludge generated at bleached
 papergrade kraft and soda and
 papergrade sulfite mills may contain
 dioxin and furan if these pollutants
 contaminate the wastewater treated at
 these mills. At proposal, the Agency
 estimated that the mills in these two
 subcategories generated 177 g/yr TEQ
 dioxin and furan in their wastewater
 treatment sludge. Since the proposal,
 industry has significantly reduced the
 level of dioxin and furan in its
 wastewater. The Agency estimates that
 the dioxin and furan content of the
 sludge has decreased similarly, to
 approximately 50 g/yr TEQ. See the
 Supplemental  Technical Development
 Document, DCN 14487.
  The process  changes that form the
 basis of the BAT limitations and PSES
 promulgated today limit the
 concentration of dioxin and furan
 allowed to be discharged to the
 wastewater treatment system. As a
 result, the Agency estimates that when
 fully implemented, the combined
 application of BAT limitations and
 PSES will reduce the present sludge
 loading of dioxin and furan TEQ by 43
 g/yr, approximately an 85 percent
 reduction from current levels. The
 period of time before individual mills
 have reached this level will vary
 somewhat depending on the compliance
 schedule incorporated in the permit and
 the type of treatment system in place at
 each mill. See the Supplemental
 Technical Development Document, DCN
 14487.
   EPA concludes that the technologies
 that form the basis of BAT, PSES, and
 BMPs for the Bleached Papergrade Kraft
 and Soda and Papergrade Sulfite
 subcategories are beneficial from the
 standpoint of solid waste generation.
 The technologies both reduce the
 quantity of solid waste generated and
 also improve its quality by reducing the
 pollutant loading in the sludge
 generated.

 4. Other Environmental Impacts
   Wood consumption at the bleached
 papergrade kraft and soda mills will be
 reduced by up to 0.3 percent by the final
 BAT limitations and PSES promulgated
 today. The wood savings results from a
 reduction in losses of useful fiber
 associated with the recovery of liquor
 spills and improvements in brownstock
 washing and screening of pulp. EPA
 estimates no change in wood
 consumption at mills in the Papergrade
 Sulfite subcategory.
  The control technologies that form the
 basis of the effluent limitations  ,
 guidelines and standards promulgated
 today will reduce bleached papergrade
 kraft and soda mill effluent wastewater
 flows. The greatest reductions would.be
 realized in mills presently discharging
 the highest flows. In 1995, the average
 bleached kraft mill discharged
 approximately 95 m3/metric ton effluent
 (23,000 gallons/metric ton). For a 1,000
 metric ton/day mill, the average effluent
flow is similar to that from a city of
 250,000 people. The effluent limitations
guidelines and standards will reduce
total effluent flow in two ways: (1)
 Closure of brownstock screening
systems, and (2) BMPs. At a mill with
open screening, closure could reduce
total effluent flow by 25 percent. BMP
 implementation could result in further
 effluent flow decreases of two percent.
 EPA estimates a small reduction in
 wastewater effluent flow from mills in
 the Papergrade Sulfite subcategory.
  EPA concludes that the technologies
 that form the basis of BAT, PSES, and
 BMPs for the Bleached Papergrade Kraft
 and Soda and Papergrade Sulfite
 subcategories are beneficial from the
 standpoint of wood use and wastewater
 generation, and will not produce
 significant adverse non-water quality
 environmental impacts.

 D. Non-Water Quality Environmental
 Impacts of New Source Performance
 Standards and Pretreatment Standards
 for New Source (NSPS and PSNS)

  EPA analyzed the projected non-water
 quality environmental impacts of BAT
 for the Bleached Papergrade Kraft and
 Soda subcategory for BAT, PSES, and
 BMPs based on complete substitution of
 chlorine dioxide for chlorine and other
 technology elements. This section
 presents the non-water quality
 environmental impacts of a second
 technology configuration (NSPS and
 PSNS) which is equivalent to BAT,
 PSES, and BMPs with the addition of
 extended delignification (oxygen
 delignification or extended cooking) on '
 a new 1000 tpd bleached papergrade
 kraft fiber line.
  Table VII-7 presents the non-water
 quality environmental impacts of the
 selected technology basis for NSPS and
 PSNS, compared to conventional
 pulping and bleaching technology.
These estimates are based on the same-
calculational methodology described
under BAT and PSES, applied to a 1000
tpd model mill. Based on these
estimates, EPA concludes that the
process technologies that forim the basis
for NSPS and PSNS for the Bleached
Papergrade Kraft and Soda subcategory
pose no significant adverse non-water
quality environmental impacts.
   TABLE VII-7.—NON-WATER QUALITY ENVIRONMENTAL IMPACTS OF NSPS/PSNS FOR THE BLEACHED PAPERGRADE
                                         KRAFT AND SODA SUBCATEGORY
                                                                             1000 tpd fiber line
Wood Consumption 	
Effluent Flow	
BOD to Treatment 	
Sludge Generation	
Carbon Dioxide	
Energy Impacts:
   Total Electricity Demand 	,
   Total Steam Demand 	
   Tola! Energy Demand 	,
Air Emissions:
   Hazardous Air Pollutants	
   Chloroform	
   Volatile Organic Compounds.
                   No Difference.
                   Moderate Decrease.1
                   Decrease by 11,300 kg/day.
                   Decrease by 890 kg/day.
                   Decrease by 21,700 Mg/year.

                   Decrease by 222,600 million BTU/year in oil equivalent.
                   Increase by 60,180 million BTU/year in oil equivalent.
                   Decrease by 162,400 million BTU/year in oil equivalent.

                   Increase by 407 Mg/year.
                   No Difference.
                   Increase by 707 Mg/year.

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             Federal Register/Vol. 63. No. 72/Wednesday. April  15.  1998/Rules and Regulations      18579
    TABLE VI1-7.—NON-WATER QUALITY ENVIRONMENTAL IMPACTS OF NSPS/PSNS FOR THE BLEACHED PAPERGRADE
                                    KRAFT AND SODA SUBCATEGORY—Continued

Total Reduced Sulfur 	 , 	 	 	
Particulate Matter 	 	 	 	 	 	 ..
Carbon Monoxide 	 	 	 	 	 	 	 	
Nitrogen Oxides 	 	 	 	 	 ; 	 	 	
Sulfur Dioxides 	 : 	 '. 	 	 	 	


Increase by 28 Mg/year
Decrease by 12 kg/year
Decrease by 3 Mg/year
Decrease by 28 Mo/year
Decrease by 56 Mg/year

1 000 tpd fiber line






  iSee Section 11.4.1.3 of the Supplemental Technical Development Document, DCN 14487.
  NSPS and PSNS that EPA is .   ,
 promulgating today for the Papergrade
 Sulfite subcategory are equivalent to
 BAT and PSES. Therefore, the NSPS
 and PSNS present no additional non-
 water quality environmental impacts.
    . Analysis of Costs, Economic
Impacts, and Benefits

A. Summary of Costs and Economic
Impacts

 ' . This section presents a summary of
EPA's evaluation of the costs, economic
impacts, and benefits of the Cluster
Rules. A more detailed analysis is
contained in the Economic Analysis for
the National Emission Standards for
Hazardous Air Pollutants for Source
Category: Pulp and Paper Production;
Effluent Limitations Guidelines,
Pretreatment Standards, and New
Source Performance Standards: Pulp,
Paper, 'and Paperboard Category— Phase
1 (DCN 14649; hereafter, the Economic
Analysis).
  Today's action is a significant
departure from prior EPA rulemakings
in that, for one industry, EPA is
considering the ramifications of
implementing two major environmental
statutes with respect to pollution
control, industrial technology and
operations, environmental impacts,
costs, and economic impacts. As noted
in" Section n of this preamble, today's
'rulemaking establishes regulations that
implement elements of both the CAA
and CWA. The objective of this
economic analysis is to provide the
most accurate portrayal possible of the
aggregate costs that the industry will
face by implementing these regulations,
as well as the economic, financial, and
social impacts that EPA estimates will
result from these costs. The economic
impacts of the combined, or joint, costs
of the final CWA (BAT, NSPS, PSES,
PSNS, and BMP)  requirements and the
final and proposed CAA requirements
(MACT I, MACT IE, and proposed
MACT E) are .different than the impacts
that would result from the costs of the
CWA or CAA requirements considered
separately. While EPA presents
separately the CWA and CAA
 compliance costs and the economic
 impacts of those costs in this section,
 the Agency believes the most accurate
 estimation of the economic impacts that
 the pulp and paper industry will
 experience is derived by considering
 total (combined) compliance costs of
 both the CAA and CWA rules. Under
 the CWA, EPA considered the .economic
 impacts of each option by subcategory,
 combining indirect and direct
 dischargers. EPA combined these groups
 .because there are no differences
 between direct and indirect dischargers
 in each sufacategory with respect to
 characteristics of wastewater generated
 or the model process technologies
. considered.
   The compliance costs described in
 this section are EPA's best estimates of
 the actual costs facilities will incur to
 comply with the promulgated and
 proposed rules.
   The total annualized and operation
 and maintenance (O&M) costs differ
 somewhat, from the engineering cost
 estimates shown in Section VI. The
 annual O&M costs shown in this section
 include a general and administrative
 cost of four percent of capital costs,
 which makes these O&M costs
 significantly higher than the engineering
 O&M cost estimates shown in Section
 VI. The annualized costs shown in
 Section VQI are both pre-tax and post-
 tax. Pre-tax costs, because they capture
 total economic losses to society, are
 considered the social costs of the rule
 and are used for examining cost-
 effectiveness (Sections Vffl.D.4 and
 Vin.F. 1) and for comparing the costs
 and benefits of the rule (Section VEI.H).
 Post-tax costs, which represent the  ,
 projected costs to a firm after tax shields
 for depreciation and other factors are
 accounted for, are used in the economic
 achievability determination under the
 Clean Water Act to evaluate facility
 closures,'firm failures, and related
 impacts. Post-tax costs are used in
 Sections VELA, VEI.B, VHI.C, VULE,
 Vm.J, and most of Sections VOID and
 VHI.F.
   EPA's financial and economic
 analyses reflect as accurately as possible
 the information that pulp and paper
                  \
 industry managers will consider in
 making financial decisions. The
 economic impacts described in this
 section (such as facility closures, job
 losses, and reduced shipments) result
 from the total costs that a facility will
 bear (including environmental
 compliance costs) compared to the
 facility's expected revenues. EPA also
 evaluated the aggregate costs for all
 facilities borne by each company to
 determine if each company will be in
jeopardy of bankruptcy as a result of
 aggregate compliance costs.
  In this section* EPA also describes the
 qualitative, quantitative, and monetized
 benefits of environmental improvements
 expected to result from compliance with
 these rules,-and compares these benefits
 to the costs of the rules. EPA identified
 158 mills at proposal with kraft, soda,
 sulfite or semi-chemical pulping
 processes. Of these, EPA how projects
 that 155 mills will bear costs under the
 final MACT I and 149 mills will bear
 costs under the proposed MACT E (six
 mills do. not practice chemical
 recovery). These numbers could change
 over time as mills change processes or
 close operations.
  EPA separately evaluated the
 compliance costs and economic impacts
 of: (1) MACT I for the 155 mills that
 pulp wood using kraft, soda, sulfite, or  .
 semi-chemical pulping processes; (2)
 combined final MACT I and proposed
 MACT E for those mills; and (3)
 proposed MACT n for combustion
 sources at the 149 mills. Although all of
.the regulatory options and alternatives
 under consideration for MACT n are
 evaluated in the EA, only the economic
 impacts related to the proposed
regulatory alternative are presented
here. EPA estimates that there will be no
 economic impacts associated with the
MACT HI regulations, which are
promulgated for mills that practice
mechanical, secondary fiber, or non-
wood pulping or that produce paper or
paperboard from purchased pulp,
because EPA believes that compliance
with MACT ffl requirements will
neither impose costs nor result in
additional emissions reductions. For
this reason, Section VIE presents no

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18580
Federal Register/Vol. 63, No. 72/Wednesday, April  15,  1998/Rules and  Regulations
further analysis of the MACT ffl
regulations.
  EPA separately evaluated the impacts
of the BAT. PSES, NSPS, PSNS, and
BMP requirements for the 86 mills
currently in the Bleached Papergrade
Kraft and Soda subcategory and the 11
mills currently in three segments of the
Papergrade Sulfite subcategory. (One
mill is in both CWA subcategories.)
Both direct and indirect discharging
mills are subject to BMPs. Hereafter,
EPA's reference to BAT/PSES costs
includes the costs of complying with the
final BMP requirements.
  EPA also evaluated the costs and
impacts for the combination of MACT I
and BAT/PSES for the 96 bleached
papergrade kraft and soda and
papergrade sulfite mills that are affected
                          by both rules. EPA also provides an
                          estimate of the economic impacts when
                          the proposed MACT n costs are
                          combined with the MACT I and BAT/
                          PSES costs for these 96 mills. Finally,
                          the economic impacts and costs for all
                          155 kraft, soda, sulfite, and semi-
                          chemical mills affected by air and/or
                          water regulations are reported.
                            EPA also evaluated the impacts of
                          NSPS or PSNS costs for new sources,
                          both singly and in combination with
                          MACT I and proposed MACT n costs.
                            EPA evaluated economic achievability
                          based on the relative magnitude of
                          compliance costs (in the form of total
                          annualized costs) -and the resulting
                          potential facility closures, potential job
                          losses, firm failures (potential
                          bankruptcies), reduced value of .
shipments, balance of trade effects, and
indirect effects (reduced regional and
national output and employment which
reflect the fact that impacts on the pulp
and paper industry will resonate
throughout the economy). Table VHI-1
presents a summary of annualized costs
and projected mill closures for die
various rules and rule combinations.
The level of detail for reporting results
in the preamble (and in the EA) is
sometimes constrained in order to
protect confidential business
information. For that reason facility
closures and job losses, for example, are
not identified for certain combinations
of rules. All of the results are contained
in the confidential portion of the
rulemaking record.
                TABLE VIII-1 .—SUMMARY: COSTS AND ECONOMIC IMPACTS OF CAA AND CWA RULES
Costs and impacts
Pro-Tax Annualized Costs ($ MM)2 	
Post-Tax Annualized Costs($ MM) 	
Mill Closures 	 	 	
Firm Failures 	
Rules
MACTI
(final) (all
mills)
125
82
0
0
MACT II
(proposed)
(all mills)
32
23
0
0
BAT/PSES
(final)
(BPK&PS) i
263
172
1
0
MACT I and
BAT/PSES
(final)
(BPK&PS)
351
229
2
0
MACT I,
BAT/PSES
and MACT
II (BPK&PS)
366
240
3
0
MACT I,
BAT/PSES
and MACT
II (all mills)
420
277
3
0
  1BPK: Bleached Papergrade Kraft and Soda subcategory PS: Papergrade Sulfite subcategory.
  2Pre-Tax costs are not used in determining economic achievability.
  MACT Costs: Total annualized MACT
I costs for 155 facilities in all
subcategories regulated today are $82
million (all annualized costs presented
In Section WH are post-tax costs in 1995
dollars, except where noted). These
costs differ from the engineering MACT
control cost estimates presented in
Section VI, as noted above and in
Section Vin.B.l.c. Total annualized
proposed MACT n costs for all
subcategories that EPA proposes to
regulate are $23 million. No mill
closures, job losses, or firm failures are
projected when either MACT I or
proposed MACT n costs are analyzed
Individually. When the costs for final
MACT I and proposed MACT E are
combined, the (post-tax) annualized
costs are S105 million and result in one
estimated mill closure and losses of up
to 700 jobs. No firm failures are
predicted as a result of the combined
costs of MACT I and MACT H.
  BAT/PSES Costs: EPA estimated
economic impacts for three BAT/PSES
options (Option A, Option B, and TCP)
for all bleached papergrade kraft and
soda mills. Section VI.B.5.a(l) of this
preamble contains a description of each
option. The naming conventions of
Option A, Option B, and TCP, which
                          EPA introduced in that section, are also
                          used here. EPA selected Option A as the
                          technology basis for BAT/PSES for the
                          Bleached Papergrade Kraft and Soda
                          subcategory (see Section VI.B.5.a(5)).
                          For the 11 mills in three segments of the
                          Papergrade Sulfite subcategory, the
                          Agency estimated the economic impacts
                          of one technology for each segment.
                          EPA selected those technologies as the.
                          bases for BAT/PSES.for this subcategory
                          (see Sections VI.B.6.b and d). EPA
                          presents a summary of the economic
                          impacts of the selected BAT/PSES
                          technology bases immediately below. A
                          summary of the economic impacts for
                          the rejected BAT/PSES options in the
                          Bleached Papergrade Kraft and Soda
                          subcategory is presented in Section
                          VUJ.F.
                            Total annualized costs for the selected
                          BAT/PSES for the 96 mills in the
                          Bleached Papergrade Kraft and Soda
                          and Papergrade Sulfite subcategories are
                          $172 million. One mill closure is
                          predicted for the Bleached Papergrade
                          Kraft and Soda subcategory as a result
                          of compliance costs. Estimates of job
                          losses are not presented in order to
                          protect confidential business
                          information. EPA estimates no closures
                          for the Papergrade Sulfite subcategory as
a result of compliance costs. EPA
estimates that no firm failures will
result from BAT/PSES in these
subcategories. Based on current
information, EPA projects that there
may be some new sources, most likely
new fiber lines at existing pulp and •
paper mills. EPA has  identified the per
plant NSPS/PSNS costs for the Bleached
Papergrade Kraft and  Soda and die
Papergrade Sulfite subcategories. EPA
did not have sufficient information to
reliably project the likely number of
new sources (see Section VELD). EPA
also expects that many replacement
fiber lines constructed at Subpart B
mills will be enrolled in the Voluntary
Advanced Technology Incentives
Program and will therefore be existing "
sources rather than new sources. 40 CFR
430.01(j)(2). EPA also conducted a   "
barrier to entry analysis for new sources,
discussed below.
  Combined Costs: The combined
annualized costs for MACT I and BAT/
PSES, affecting 96 bleached papergrade
kraft and soda and papergrade sulfite
mills, are $229 million. As a result of
these costs, two mills in the Bleached
Papergrade Kraft and Soda subcategory
are projected to close with an associated
loss of 900 jobs. See Table VHI-3. No '

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             Federal Register/Vol. 63. No. 72/Wednesday. April 15.  1998/Rules  and Regulations      18581
 mills are projected to close in the
 Papergrade Sulfite subcategory as a
 result of compliance costs. No firm
 failures are predicted.
   The combined annualized costs for
 the proposed and final rules (MACT I,
 BAT/PSES, and proposed MACT n)
 affecting the 96 bleached papergrade
 kraft and soda and papergrade sulfite
 mills are $240 million. With these
 combined costs, three mills are
 projected to close. The associated job
 losses increase with the additional
 projected closure, but the estimate is not
(reported here in order to protect
 confidential business information. No
 firm failures are expected to result from
 the combined costs of MACT I, BAT/
 PSES, and proposed MACT n for these
 mills.
   The annualized costs for the proposed
 and final rules  (MACT I, BAT/PSES,
 and MACT n) applicable to all 155 kraft,
 soda, sulfite, and semi-chemical mills
 are $277 million. With these combined
 costs for all rules and all 155 mills, the
 impacts are unchanged; i.e., three mills
 are projected to close, job losses exceed
 900, and no firm failures are expected.
 B. Overview of Economic Analysis

 1. Revisions in  Analysis From Proposal
   a. Subcategories. Based on the
subcategorization described in Sections  :
n.C.l, VIA and VLB.l. EPA estimated
impacts for four CAA subcategories-—
Kraft, Sulfite, Soda, and Semi-Chemical
Process—and two CWA subcategories—
Papergrade Sulfite and Bleached
Papergrade Kraft and Soda. The
economic analysis, addresses 155 mills
in the CAA subcategories and 96 mills
in the CWA subcategories. The 96 CWA
mills are a subset of the 155 CAA mills.
   b. Options, (1) Air Emissions
Standards. The  selected technology
bases for the MACT I &r3H standards are
discussed fully  in Section n.B.2 of this
preamble. Regulatory options and
alternatives for  MACT n are discussed
in Section IV.F  of the preamble to the '
proposed MACT II standards, which
appears elsewhere in today's Federal
Register, and in the Economic Analysis
(DCN 14649). EPA's economic analysis
presents results for eight regulatory
alternatives. The summary presented
here pertains only to the final MACT I
standard and proposed MACT n
standard.
   (2) Effluent Limitations Guidelines
and Standards.  For the BAT/PSES
analyses for "the Bleached Papergrade
Kraft and Soda subcategory, EPA's
economic analysis addresses three
technology options. The summary
presented in this section of the :
preamble focuses on Option A, the
 selected BAT/PSES option, but a brief
 discussion of the impacts for the
 rejected options appears below in
 Section VHI.F. For the Papergrade
 Sulfite subcategory, EPA's economic
 analysis (and the summary presented
 here) analyzes only the technologies
 selected as the bases for the BAT/PSES
 for each segment. This is because EPA
 identified no technically available
 options for the three papergrade sulfite
 segments other than those considered
 and selected.
   NSPS/PSNS costs for new sources are
 presented in Section VELD.
   c. Methodology. The methodologies
 used by EPA to evaluate economic
 impacts at the time of proposal are fully
 discussed in the Economic Impact and
 Regulatory Flexibility Analysis of the
 Proposed Effluent Limitations
 Guidelines and NESHAP for the Pulp,
 Paper, and Paperboard Industry (EPA-
 821-R-93-021, November, 1993).
 Revisions to these methodologies are
 discussed below and more fully in
 Chapters 3 and 4 of the Economic
 Analysis (DCN 14649).
   As discussed or referenced in the July.
 15, 1996 Notice,  EPA revised
 components of the economic
 methodology to account for recent
 changes that have occurred in the pulp
 and paper industry, including: (1)
 revision of the discount rate; (2)
 integration of market (price change)
 effects into the financial closure model;
 (3) incorporation of new industry cycle
 data into the forecasting methodology;
 (4) adjustment of the starting year for
 the analysis to 1996; (5) incorporation of
 updated mill ownership data in the firm
 failure model; and (6) a revised method
 for calculating annual costs. See 61 FR
 at 36843-44. Each of these methodology
 revisions is briefly discussed below.
  At proposal, EPA used a facility-
 specific cost of capital (an average of
 nine percent real cost of capital) derived
 from responses to a 1989 industry
 survey) that reflected financing costs in
 1989. Real (inflation-adjusted) financing
 costs declined considerably between  .'
 1989 and 1995. For the final rule, EPA
 primarily used an inflation-adjusted
 seven percent cost of capital or discount
 rate in the economic analysis because
 this rate better reflects real industry
 financing costs from 1995 to 1997, and
 the Agency does  not have accurate
 information on current facility-specific
financing costs. Additionally, the Office
of Management and Budget
recommends a seven percent discount
rate to evaluate the social costs of
federal regulations. In Chapter 6 of the
Economic Analysis (DCN 14649), EPA
presents a sensitivity analysis of results
using alternative  discount rates.
   At proposal, EPA used both a
 financial model and a comprehensive
 market model to assess economic
 effects! Much of the information in the
 market model was derived from the
 1989 survey. A number of substantial
 changes have occurred in pulp and
 paper markets since. 1989 that the
 market model does not reflect. EPA
 decided not to update the market model
 (which estimated price increases),
 because an update would have required
 a new survey of every mill and all
 product lines, which would have been
 unnecessarily costly and burdensome to
 mill operators. EPA was also concerned
 that the amount of time required for
 conducting and  analyzing a second
 survey would unnecessarily delay the
 final rule. This would further extend the
 industry's inability to plan and make
 capital investments with certainty
 regarding regulatory requirements.
 Instead, EPA modified the financial
 model to incorporate product supply
 and demand elasticities, which are
 estimates of changes in demand or
 supply in response to price changes.
 The summary of results presented in
 this preamble does not reflect the effects
 of price increases, because such changes
 did not materially affect EPA decisions.
 Chapter 6 of the  Economic Analysis
 (DCN 14649)  presents all of the results.
  The last year of price information
 available at proposal was 1988. Between
 1988 and 1995, the pulp and paper
 industry completed a full industry
 revenue cycle, with revenues peaking in
 1988, fallmg through 1992, and reaching
 historic heights in 1995. For the final
 rule, this newer information was
 incorporated  into the forecasting
 methods for the financial closure model,
 which assumes this seven-year cycle (a
 six-year cycle was used at proposal) of
 falling and rising prices will continue
 into the future. Additionally, the
 starting year for the analysis was
 adjusted to 1996 (from 1989, which was
 used at proposal).
  To identify potential firm failures
 (i.e., bankruptcies) using the Altaian's Z
 financial ratio analysis, EPA obtained
 updated financial information,
 including mill ownership data, for
 publicly held companies. Because
 updated information for privately held
 companies was not available from
 public sources, EPA did not evaluate
 possible failures  among private firms.
To include these companies would have
required a new industry survey.
  A facility-level financial analysis that
was conducted at proposal was
discontinued because EPA was also  .
unable to update facility-level financial
information withouta new survey. The
facility-level analysis is not a

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18582      Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules  and Regulations
component of the Altman's Z analysis,
on which EPA has relied to identify firm
failures for this final rule. While
providing some useful information, the
facility financial analysis was not used
to identify firm-level bankruptcies at
proposal and did not provide the basis
at proposal for making determinations
of economic achievability.
  As noted in Section VELA., EPA
considers general and administrative as
well as variable annual costs in the cost
annualization calculation. At proposal,
general and administrative costs (GAC)
had been calculated as 4 percent of
capital costs plus 60 percent of variable
annual costs. Subsequent analysis
indicated that the engineering estimates
for effluent control already included the
60 percent of variable annual costs. To
remove this double-counting, GAC is
now calculated as four percent of capital
costs for effluent control (see DCN
14086). GAC is added after the
engineering estimates prior to cost
annualization; this explains the
differences between engineering and
economic estimates of operating and
maintenance costs.
  All of the previously discussed
revisions were made in an effort to
conduct an economic analysis of the air
and water regulations that is more
representative of current economic
conditions in the pulp and paper
industry and that provides more
accurate economic impact results.

C. Costs and Economic Impacts for Air
Emissions Standards
  Table Vm-2 presents the engineering
control cost estimates for MACTI and
for the regulatory alternative proposed
for MACT II: $755 million in total
capital costs and $172 million in
annualized costs. A more detailed
discussion of the control costs for the
final MAGT standard, including
emission reductions and cost-
effectiveness, is provided in Chapter 20
of the Background Information
Document. Table Vm-2 also presents
the capital costs and pre-tax and post-
tax annualized costs used in 'the
economic analysis. EPA has determined
that the MACT in standards will impose
no costs; therefore, none is presented
here or in Table Vni-2.
  As noted in Section VIHA. and
Chapter 5 of the Economic Analysis, the
engineering control cost estimates of the
cost of MACT regulations differ from the
costs used in EPA's economic impact
analysis of those standards. The
economic analysis also differentiates
between pre-tax annualized costs and
post-tax annualized costs as discussed
in Section VELA.
                           TABLE vm-2.—ESTIMATES OF THE COST OF AIR REGULATIONS
                                                 [Millions of dollars]
Regulation
MACT 1 ... 	 	 	
MACT 11 . 	
Total Air 	

MACT control cost
estimates
Capital
costs
$496
259
755
Annualized
cost
$130
42
172
Economic analysis MACT cost estimates
Capital cost
$501
258
759
AnnualizEid costs
Pre-tax
$125
32
157
Post-tax
$82
23
105
  Based on the economic analysis, EPA
predicts no firm failures, mill closures,
or associated job losses as a result of the
costs of the MACT rules considered
individually. When the costs of the
MACT rules are combined, EPA projects
one mill closure with up to 700 job
losses. No firm failures are anticipated
for the combined MACT rules.
D. Costs and Economic Impacts for
Effluent Limitations Guidelines and
Standards
l.BPTandBCT
  As explained in Section VI.B.2, EPA
is exercising its discretion not to revise
BPT limitations for conventional
pollutants at this time for Subparts B
and E. In addition, candidate BCT
technologies do not pass the two-part
BCT cost reasonableness test. Therefore,
EPA is not revising the current BCT
limitations for Subparts B and E mills;
as a result, these mills will incur no
incremental BPT or BCT costs.
2. Bleached Papergrade Kraft and Soda
Subcategory
  a. BAT/PSES. For the selected BAT/
PSES (Option A), capital costs are $966
million, O&M costs are $151 million,
and annualized costs are $162 million.
When considering these costs alone, the
economic analysis predicts closure of
one mill as a result of this rule and no
firm failures. Other economic impacts
(e.g., job losses) are reported in the CBI
portion of the rulemaking record.
  b. NSPS and PSNS. EPA considered
the cost of NSPS and PSNS technology
for new source mills in the Bleached
Papergrade Kraft and Soda subcategory.
EPA expects few new source mills or
fiber lines to be constructed that will be
subject to NSPS/PSNS. Even if new
source mills or fiber lines are
constructed that are subject to NSPS/
PSNS, EPA estimates that the selected
NSPS/PSNS would not present a barrier
to entry. EPA estimated the average
incremental capital costs of NSPS/PSNS
compliance (compared to Option A
technology) to be approximately 0.50 to
2.0 percent of the capital cost of
constructing a new source mill or fiber
line and concluded that this cost was
•not sufficient to present a barrier to
entry for proposed entrants, particularly
considering the lower operating costs of
Option B.
3. Papergrade Sulfite Subcategory
  a. BAT/PSES. As explained in Section
VI.B.6.a, EPA is dividing the Papergrade
Sulfite subcategory into three segments.
For BAT/PSES for all three segments
combined, capital costs are $73.8
million, O&M costs are $7 million, and
annualized costs are $9.8 million. No
mills are projected to close as a result
of these compliance costs, and no firms
are projected to fail. There is no
expected loss of jobs, shipments, or
exports.
  b. NSPS/PSNS. EPA considered the
costs of NSPS/PSNS for new source
mills in the Papergrade Sulfite
subcategory. Because NSPS/PSNS
equals BAT/PSES, EPA concluded that
such costs were not sufficient to present
a barrier to entry. First, the cost of the
NSPS/PSNS technology is an       .    .
insignificant fraction of the capital cost
of a new source mill or fiber line (less
than one percent). Also, the costs of
including the selected NSPS/PSNS
technology at a new source mill'are
substantially less on a per ton^ basis than
the costs of retrofitting existing mills.
Moreover, the increased chemical
recovery and reduced operating costs for
the NSPS/PSNS option allow firms to

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             Federal  Register/Vol. 63, No.  72/Wednesday, April 15, 19987 Rules and Regulations      18583
recover the capital cost associated with
the NSPS/PSNS technology.

4. Cost-Effectiveness

   EPA uses a cost-effectiveness ratio of
dollars per toxic pound equivalent
removed (see Economic Analysis (DCN
14649), Chapter 5) to evaluate the
relative efficiency of a technology
option in removing toxic pollutants. The
results reported below are expressed in
1981 dollars, as prescribed by EPA's
cost-effectiveness methodology (DCN
14649). For the Bleached Papergrade
Kraft and Soda subcategory, the cost-
 effectiveness ratio.for both BAT and
 PSES is ,$14 per toxic pound equivalent
 removed. The cost-effectiveness ratios
 for the Papergrade Sulfite subcategory
 are $13 per toxic pound equivalent
 removed for BAT and $45 per toxic
 pound equivalent for PSES. EPA
 considers the selected technology bases
 for the BAT/PSES limits for both  ,
 subcategories to be cost-effective.

 E. Costs and Impacts for the Integrated
 Rules

  EPA estimates that 155 kraft, soda,
 sulfite, and semi-chemical mills will
 incur costs to comply with the CAA
 rules; 96 bleached papergrade kraft and
 soda and papergrade sulfite mills will
 incur costs to comply with the CWA
 rule,- and the same 96 mills will incur
 both CAA and CWA rule costs.  Table
 VflI-3 is a summary of the expected
 costs and impacts for various
 combinations of CAA and CWA rules.
 The losses of jobs, shipments, exports,
 and indirect effects reported in  Table
 VHI-3 are the impacts derived from mill
 closures. Some results are not disclosed
 where confidentiality might be
 compromised.
                      TABLE VIII-3.—COSTS AND ECONOMIC IMPACTS OF CAA AND CWA RULES
Costs and Impacts
Capital Costs ($MM) 	 	 	 	 „ 	
Post-Tax Annualized Costs ($MM) 	
Mill Closures 	 '. 	 	 	
Firm Failures 	 	 	 	
Job Losses (from mill closures) 	 	 	 	 	 	
Decreased Shipments ($MM) 	 '. 	
Decreased Exports ($MM) 	
Direct and Indirect Effects ($MM) 	 	 	 	

Rules
MACTI
(final)
501
82
0
0
0
0
0

MACTII
(proposed)
258
23
0
0
' , 0
0
0

BAT/PSES
(BPK&PS)i
1,039
172
1
0
400
'. 150
19
430
MACT I &
BAT/PSES
(96 mills)
1,394
229
2
0
900
273
19
795
MACTI,
BAT/PSES
& MACT II
(BPK&PS)
(96 mills)
1,524
240
3
0
1,700
479
22
1,393
MACTI,
BAT/PSES
& MACT II
(155 mills)
1,799
277
3
0
1,700
479
22
1,393
  1BPK: Bleached Papergrade Kraft and Soda subcategory.
  PS: Papergrade Sulfite subcategory.
  While no mills are predicted to close
due to MACT I costs alone, and one mill
in the Bleached Papergrade Kraft and
Soda subcategory is predicted to close
due to BAT/PS.ES costs alone, EPA
estimates that two mills in the Bleached
Papergrade Kraft and Soda subcategory
may close as a result of the combined
costs imposed by these rules. The two
predicted closures represent
approximately 2.3 percent of the 86
bleached papergrade kraft and soda
mills and 1.3 percent of all 155 kraft,
sulfite, soda, and semi-chemical mills
affected by this rulemaking. As a result
of these two closures, 900 jobs could be
lost. These jobs represent 0.9 percent of
the jobs in the Bleached Papergrade
Kraft and Soda subcategory. These costs
generate a maximum estimated price
increase: of £.5 percent for any product
(pulp, paper or paperboard). Estimated
losses in the value of shipments are
approximately $273 million, or 0.8
percent of bleached papergrade kraft
and soda shipments, while losses in the
value of bleached papergrade kraft and
soda exports are approximately $19
million, or 0.5 percent.of subcategory ;
exports.    .
  No mills are projected to close in the
CWA Papergrade Sulfite subcategory, or
the CAA soda, sulfite, or semi-chemical
subcategories as a result of either the
; promulgated CAA or CWA regulations
or a combination of both.
  EPA examined the indirect effects, of  •
the final regulations (MACT I, MACT HI
and BAT/PSES) on employment and
output using a national-level input-
output model developed by the U.S.
Department of Commerce. The model
provides multipliers that enable EPA to
estimate national-level impacts based .on
the loss of employment and output from
closing mills. Total projected effects on
the U.S. economy of the combined
MACT I and BAT/PSES are
approximately 5,700 jobs lost and $795
million in lost economic output. While
some local communities could
experience some economic dislocation
as a result of closures, overall national
impacts would be insignificant. For
comparison, the 1995 U.S. gross
domestic product was $7.3 trillion. The
loss is approximately one-tenth of 1
percent of the gross domestic product'
for 1995. EPA also.evaluated regional
(county-level) economic impacts when
determining the economic achievability
of the regulation. For the final MACT I
and BAT/PSES, in the two counties
where mills are projected to close, the"
unemployment rate would increase by
0.4 percent and 0.7 percent respectively.
  In response to public comments, EPA
also estimated the economic impacts
associated with the combined costs of
promulgated and proposed rules. When
the MACT I, BAT/PSES, and MACT H
costs are considered jointly, EPA
projects an additional mill closure with
800 additional jobs lost and further
decreases of $206 million in shipments
and $3 million in exports. The total-
projected effects of the combined MACT
1, BAT/PSES, and MACT H costs are
approximately 10,000 jobs lost and $1.4
billion in lost economic output.

F. Costs and Impacts of Rejected BAT/
PSES Options for the Bleached
Papergrade Kraft and Soda Subcategory

1. Summary of Results

  Table VHI-4 presents costs and
impacts for two options (Option B and
TCF) that EPA evaluated, .but did not
select, as the basis for BAT/PSES for the
Bleached Papergrade Kraft and Soda
subcategory. EPA's rationale for
selecting Option A for BAT/PSES for
this subcategory is presented in Section
VI.B.5.a(5). Table VTfl-4 presents results
in three ways: considering CWA costs
and impacts alone; considering the costs
and impacts of the rejected BAT/PSES
options and MACT I; and considering

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18584
Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules and Regulations
the costs and impacts of the rejected
                         BAT/PSES options, MACT I, and MACT
                         E.
 TABLE Vlll-4.—COSTS AND ECONOMIC IMPACTS OF REJECTED BAT/PSES OPTIONS FOR THE BLEACHED PAPERGRADE
                                       '  KRAFT AND SODA SUBCATEGORY
Costs & Impacts
Capital Costs ($MM) 	
Post-Tax Annualized Costs ($MM) 	
Mill Closures 	 	 	
Firm Failures 	 	 	
Job Losses (from mill closures) 	
Decreased Shipments ($MM) 	
Decreased Exports ($MM) 	
Direct and Indirect Effects ($MM) 	
Rules
Option B
(BAT/PSES)
2,100
216
2
(3)
900
273
19
795
TCP (BAT/
PSES)
3,100
688
7.
(3)
7,100
2,300-
308
. NR
Option B
(BAT/
PSES)+
MACTI
2,600
292
4
(3)
4,800
1,300
24
3,850
TCF + ,
(BAT/
PSES)
MACT I
3,600
764
9
(3)
10,200
3,200
310
NR
Option B
(BAT/PSES)
MACT I &
MACT II
2,700
300
ND1
(3)
ND
ND
ND
ND
TCP, (BAT/
PSES)
MACT I &
MACT II
3,700
772
9
(
10,200
3,200
310
NR
  1 ND: not disclosed to protect confidential business information.
  a NR: not reported.
  * 1 or more.
  Option B: The BAT/PSES capital costs
for Option B for the Bleached
Papergrade Kraft and Soda subcategory
are estimated at $2.1 billion; O&M costs
are S87 million; and annualized costs
are $216 million. These costs result in
two projected mill closures, with direct
impacts of at least 900 jobs lost. $273
million in decreased shipments, $19
million in decreased exports, and one or
more potential firm failures. The firm
failures may also result in thousands of
additional jobs lost (see Section
VLB.5.a(5) and Chapter 6 of the
Economic Analysis, DCN 14649).
Indirect and direct economic loss (i.e.,
losses throughout the economy as a
result of the closed mills) would be
approximately $795 million. The mill
closures are projected to increase county
unemployment rates for the affected
counties by 0.4 percent and 0.7 percent,
respectively.
  EPA also calculated cost-effectiveness
ratios for Option B for this subcategory
(for Option A results, see Section
VIII.D.4, above). For direct dischargers,
the average and incremental (compared
to Option A) cost-effectiveness ratios are
S15 per toxic pound-equivalent and $36
per toxic pound-equivalent, respectively
(1981 dollars). For indirect dischargers,
the incremental cost-effectiveness
(compared to Option A), is $115 per
toxic pound-equivalent.
   Opt/on B and MACT I: The combined
capital costs for Option B and MACT I
for mills in this subcategory are
estimated at $2.6 billion; O&M costs are
$154 million; and annualized costs are
$292 million. MACT I annualized costs
are greater under Option B than under
Option A due to the additions of MACT
controls for oxygen delignification
equipment installed to comply with
                          Option B. With the combined costs of
                          Option B and MACT I, the number of
                          projected mill closures increases to four,
                          and the estimated number of firm
                          failures remains unchanged at one or
                          more. The four closures cause losses of
                          approximately 4,800 jobs, $1.3 billion in
                          shipments, and $24 million of exports.
                          Direct and indirect losses would total
                          nearly $4 billion. The mill closures are
                          also projected to increase county
                          unemployment rates; the range of
                          increased unemployment for the
                          affected counties is from less than 0.5
                          percentage points to nearly 10
                          percentage points (as a hypothetical
                          example, from a baseline county ,
                          unemployment rate of 10 percent to 10.5
                          percent after a closure in County X and
                          from a baseline of 10 percent to 20
                          percent after a closure iri County Y).
                            Option B, MACT I, and MACT'27; The
                          combined capital costs for Option B,
                          MACT I, and proposed MACT n for
                          mills in this subcategory are estimated
                          at $2.7 billion; O&M costs are $153
                          million; and annualized costs  are $300
                          million. With the combined costs of
                          Option B, MACT I, and MACT E, the
                          number of projected mill closures
                          increases (number not disclosed), and
                          the estimated number of firm failures
                          remains unchanged at one or more. The
                          analysis projects additional losses to
                          jobs, shipments, and exports from the
                          additional mill closures  (amounts not
                          disclosed). Direct and indirect losses
                          would also increase, as would the
                          unemployment rates iri the counties in
                          which the mill closures are located.
                            TCP: The capital costs for retrofitting
                          mills in this subcategory for TCP
                          technology are estimated at $3.1 billion
                          for TCP based on peroxide bleaching
                          and $5.6 billion for TCP based on ozone
and peroxide bleaching, respectively.
EPA evaluated mill closures for the TCP
option with the lower capital costs.
O&M costs for this option are $783
million, and annualized costs are $688
million. (TCP annualized costs appear
lower than annual O&M costs because of
tax shields.) EPA estimates that these
costs would result in seven mill
closures, which are associated with
approximately 7,100 job losses. EPA did
not conduct a firm failure analysis or
calculate combined direct and indirect
impacts for this option because the
closures and job losses alone are more
than sufficient indication that the
option is not economically achievable.
EPA estimates, however, that a greater
number of firms would be placed in
financial jeopardy with the costs of this
option, compared to Option B, which
;EPA has already determined is not
economically achievable (See Section
VI.B.5.a(5)).
  TCP and MACT I: The combined
capital costs for TCP and MACT I for
mills in this subcategory are estimated
at $3.6 billion; O&M costs are $851
million, and annualized costs are $764
million. EPA estimates that these costs
would result in nine mill closures and
an associated loss of 10,200 jobs, $3.2
billion in shipments, and $310 million
in exports. EPA conducted no
additional economic analysis for this
combination of costs.
  TCP, MACT I, and MACT II: The
combined capital costs for TCP, MACT
I, and MACT E for mills  in this
subcategory are estimated at $3.7
billion; O&M costs are $849 million; and
annualized costs are $772 million. With
the combined costs of TCP, MACT I,
and MACT E, EPA estimates that the
number of mill closures, job losses, and

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              Federal Register/Vol. 63, No. 72/Wednesday. April 15,  1998/Rules and Regulations      18585
 other impacts remain unchanged. EPA
 conducted no additional economic
 analysis for this combination of costs.

 2. Implications of Results
   The costs of either Option.B or TCP
 are projected to cause one or more firm
 failures (bankruptcies). This is true even
 when the BAT/PSES costs are -
 considered without the compliance
 costs associated with MACTI and/or
 MACT H. Although EPA cannot
 determine the actual outcome of the
 projected failures in terms of lost
 production, closed facilities, and lost
 jobs, the level of displacement would
 almost certainly cause detrimental
 impacts to the U.S. pulp and paper
 industry. Section VI.B.5.a(5) discusses
 EPA's reaction to these projected
 impacts in terms of regulatory decisions.
 See also Chapter 6 of the Economic
 Analysis, DCN 14649. That discussion
 also includes the Agency's findings that
 the rejected BAT/PSES options are not
 economically achievable.
 G. Benefits
   In addition to costs and impacts, EPA
 also estimated the environmental and
 human health benefits of implementing
 the CAA and CWA requirements.
 Section YE of this preamble describes
 the estimated reductions in air
 emissions and effluent discharges. The
 incremental environmental
 improvements noted in Section Vn.B.
 are derived compared to a baseline of
 current emissions and discharges.
 Because current emissions and
 discharges are a function of current
 technology, this is the same baseline
 that was used to establish the costs of
 complying with the rules. To the extent
 the total benefits of the rule can be
 measured, costs can be directly
 compared to benefits.
  EPA is confident that its estimation of
 compliance costs is a full and accurate
 account of such costs; EPA is less
 confident that the estimation of benefits
 is similarly complete. EPA is not
 currently able to quantitatively evaluate
 all human and ecosystem benefits
 associated with air and water quality
 improvements. EPA is  even more
 limited in its ability to assign monetary
 values to these benefits and therefore to
 be able to compare them to costs in a
 standard cost-benefit framework. A
 comparison of costs to  only the limited  .
 monetized subset of benefits severely
 underestimates the true benefits of
 environmental quality improvement and
 compromises the validity of a cost-
benefit analysis. The economic benefit
values described below and in the
Economic Analysis. (DCN 14649) should
be considered a limited subset of the .
 total benefits of these rules, and should
 be evaluated along with descriptive
. assessments of benefits and the
 acknowledgment that even these may
 fall short of the real-world benefits that.
 will result from .the rule.

 1. Air Quality Benefits
   Section yn.B:l of this preamble
 describes the emissions reductions
 expected as a result of implementing
 MACT I and MACT H standards.
 Implementation of the final MACT I
 standard is expected to reduce
 emissions of HAPs, VOCs, and TRS, but
 increase emissions of PM, SO2, CO, and
 NOX. The proposed alternative for
 MACT n is expected to reduce
 emissions for HAPs, VOCs, PM, TRS,
 CO, and SO2, while it is expected to
 create a slight increase in NOx
 emissions. The technology bases for
 BAT/PSES have secondary impacts on
 the level of air emissions. The combined
 effect of MACT I and MACT H for all
 subcategories regulated under the CAA
 is to decrease emissions for all of the
 above mentioned pollutants except NOx
 and SO2. See Table VHI-5 below. EPA
 performed an evaluation of the benefits
 associated with the air regulations based
 on the emission reductions estimated in
 Section Vn.B. 1. The net change in air
 benefits expected to result from the
 changes in emissions will-be a change
 in adverse health effects associated with
 inhalation of the above pollutants as
 well as changes in welfare effects such
 as improved visibility and crop yields,
 and reduced materials soiling and
 corrosion. Chapter 4 of the EA presents
 a detailed description of the
 methodology used to monetize the
 benefits.
  a. Qualitative Description of Pollutant
 Effects. The air rules are designed to
 reduce the emission of HAPs as defined
 in Section 112 of the CAA. Several of
 these HAPs are classified as probable or
 possible human carcinogens. Reducing
the emissions of these pollutants is
expected to reduce the cancer risk of the
exposed population. Other HAPs are not
classified as carcinogens; however, they
have been shown to cause other adverse
health effects such as damage to the eye,
central nervous system, liver, kidney,
and respiratory system when the
concentration of these emissions is
above the health reference benchmark
for human exposure.
  Total reduced sulfur (TRS) emissions
cause the malodorous smell often
associated with areas near pulp and
paper mills.  The MACT standards will '
reduce these effects significantly. ,
Odorant stimulants of the nasal
receptors that are associated with TRS
emissions have been associated with
 marked respiratory and cardiovascular
 responses, however, the association is
 not direct because the perception of the
 odor does not necessarily cause toxic
 effects. The threshold for odor
 detections may occur before the onset of
 toxic effects. However, the absence of
 odor does not guarantee safety since
 some components of TRS emissions can,
 cause fatigue of the olfactory senses, so
 individuals may not perceive an odor on
 some .occasions when toxic effects can
 occur. There are numerous anecdotal
 reports of adverse reactions related to
 odors associated with TRS, including
 headaches, shortness of breath, nasal
 irritation, and, in some cases, nausea
 and sinus congestion.
   VOC and NOX emissions interact in
 the presence of sunlight to create
 ground-level ozone. Recent scientific
 evidence shows an association between
 elevated ozone concentrations and
 increases  in hospital admissions for a
 variety of respiratory illnesses and
 indicates that ground-level ozone not
 only affects people with impaired
 respiratory systems (such as asthmatics),
 but healthy adults and children as well.
 Adverse welfare effects of ozone
 exposure include damage to crops, tree
 seedlings, ornamentals (shrubs, grass,
 etc.), and forested ecosystems. The
 reactions between VOCs and NOX to
 form ozone depend on the balance in
 concentrations of each pollutant found
 in the ambient air. For example, when
 the concentration of NOX is high
 relative to the concentration of VOCs,
 VOC reductions are effective in limiting
 ozone formation, while NOx reductions
 in that situation are ineffective. The
 integrated rule is expected to increase
 NOX emissions, but decrease VOC
 emissions: The increase in NOX is not
 expected to cause significant adverse
 health or environmental impacts
 because the magnitude of this increase
 is much less than the magnitude of the
 VOC emission reduction. The VOC
 reductions are expected to contribute to
 the decrease in ozone concentrations.
  The adverse human health effects
 associated with PM include: premature
 mortality;  aggravation of respiratory and
 cardiovascular disease (as indicated by
 increased hospital admissions and
 emergency room visits, school absences,
work loss days, and restricted activity
days); changes in lung function and
increased respiratory-symptoms;
alterations in lung tissue and structure;-
and altered respiratory tract defense
mechanisms. Populations at greater risk
from exposure are: individuals with
respiratory disease and cardiovascular
disease, individuals with infectious
disease, elderly individuals, asthmatic
individuals, and children. Reduced

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18586      Federal Register/Vol. 63, No.  72/Wednesday, April 15,  1998/Rules and Regulations
welfare is associated with elevated
concentrations of fine particles which
reduce visibility, damage materials, and
cause soiling. The integrated rule will
decrease the adverse effects of PM.
  CO is a colorless, odorless gas that is
toxic to mammals. When inhaled, it
combines with hemoglobin, which
reduces the oxygen-carrying capacity of
blood and results in less oxygen being
transported to vital organs of the body.
This can have detrimental effects on the
cardiovascular, central nervous, and
pulmonary systems. The reduction of '
CO emissions will diminish these
potential effects.
  SO2 oxidizes in water to form both
sulfurous and sulfuric acids. When SO2
dissolves in the water of the respiratory
tract of humans, the resulting acidity is
irritating to the pulmonary tissues,
causing nasal irritation and breathing
difficulties (especially to individuals
with respiratory diseases such as
asthma). When SOz dissolves in the
atmosphere in rain, fog, or snow, the
acidity of the deposition can corrode
various materials and cause damage to
both aquatic and terrestrial ecosystems.
SO2 can also transform into PM2.s, the
effects of which are discussed above.
  b. Monetized Air Quality Benefits.
Table VTH-5 below presents both the
health and welfare benefits described in
this section as well as the emission
reductions identified in Section W.B.l
that are not monetized but are
considered in the evaluation of benefits.
  The benefit transfer method is utilized
to value a subset of the pollutants
discussed above (VOC, SO2, and PM).
This method relies on previous benefit
studies that have been conducted for the
same pollutants that are impacted by the
pulp and paper rulemaking. These
studies provide useful data that can be
transferred across contexts in order to
approximate the benefits of the pulp
and paper emission reductions.
                     TABLE VIII-5.—EMISSIONS REDUCTIONS AND ANNUAL AIR QUALITY BENEFITS
Pollutant
HAPs 	
TRS 	
M£V, 	
VOC 	
PM 	 	 	
CO 	
so* 	
Total 	
Standard
MACTI
Decrease
(Mg)
139,000
79,000
(5,200)
409,000
(83)
(8,700)
(94,500)
Value
($MM)
NE
NE
NE
24-1,055
(1)
NE
(1,064)-0
(1,040H,054
MACT II
Decrease
(Mg)
2,600
(500)
32,600
24,000
58,000
30
Value
($MM)
NE
NE
NE
2-84
300
NE
0.1-0.3
302-384
Combined
Decrease
(Mg)
142,000
79,000
(5,700)
441,000
24,000
49,000
(94,400)
Value
($MM)
NE
NE
NE
26-1,139
299
NE
(1,064)-0.3
(739)-1,438
  NE = not estimated.
  Numbers in parentheses () indicate emissions increases or negative benefits values.
  Numbers in table rounded.
  For VOCs, benefits are valued using
estimates of a range of the average
benefit per Megagram (Mg) derived from
a recent benefit analysis conducted by
EPA in the process of revising the ozone
national ambient air quality standard
(NAAQS) (see docket no. A-95-58:
Regulatory Impact Analysis for the
Paniculate Matter and Ozone NAAQS
and proposed Regional Haze Rule; July
1997). EPA values a range of VOC
benefits reflecting (1) an assumption
that the transfer of benefits must
correlate with the areas that violate the
ozone standard, and (2) an assumption
that recognizes that reductions outside
areas of violation of the ozone standard
can have a positive benefit. Therefore,
the range of values reflects the
application of a range of values for the
average benefit per Mg as they are
applied to (1) the subset of VOC
emission reductions in areas of
violation, and (2) to all VOC emission
reductions expected to be achieved by
the integrated rule. The true value is
likely to fall within this range. Using the
range of values of the average benefit
per Mg for ozone, monetized annual
VOC benefits of MACT I emission '
reductions range from $24 million to
$1,055 million. The lower^end of this
range reflects an assumption of zero
mortality effects associated with ozone
exposure and assumes morbidity
benefits occur only in areas predicted to
violate the ozone standard, while the
upper-end includes mortality estimates
as are calculated for the upper-end of
the range of ozone benefits is included
in the NAAQS RIA and assumes
morbidity benefits occur in all areas. For
the proposed MACT n alternative, total
annual VOC benefits range in value
from approximately $2 million to $84
million. Therefore, total monetized VOC
benefits of the integrated rule are •
approximately $26 million to $1,139
million.
  For PM, a benefit transfer estimate is
obtained from a benefit analysis of PMio
that was prepared to support the
evaluation of the revised PM NAAQS
(see Appendix C of the Regulatory
Impact Analysis for the Particulate   •
Matter and Ozone NAAQS and
proposed Regional Haze Rule; July
1997). The average benefit per Mg
derived from this study is  applied to all
changes in emissions of PM that result
from the integrated rule. Using this
value, the loss in total monetized annual
PM benefits associated with MACT I is
approximately $1 million. The proposed
MACT n alternative achieves a positive
benefit approximately equal to $300
million. Thus the combined value of PM
benefits for the final and proposed pulp
and paper air standards is $299 million.
  For SO2, the EPA transfers a benefit
estimate from a national SO2 strategy
analysis conducted for the evaluation of
the revised PM NAAQS (see docket no.
A-95-54: Regulatory Impact Analysis
for the Particulate Matter and  Ozone
NAAQS and proposed Regional Haze
Rule; July 1997). This analysis shows
that benefit values are higher in the
eastern regions of the country when
compared to the western regions.
Therefore, EPA derives a range of
benefit per Mg values for each segment
of the country. In addition, EPA takes
into consideration the uncertainty
inherent in the estimate of MACT ISO2
emission increases that may result from
the rulemaking. Therefore for MACT I,
EPA values all SO2 emission increases
to obtain a lower bound  estimate of
 (negative) benefits and assumes zero
emission increases due to the likely
effects of mitigating behavior to obtain
an upper bound estimate of 2;ero

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              Federal Register/Vol. 63, No.  72/Wednesday,  April 15, 1998/Rules and Regulations      18587
 disbenefits. For MACT E, all emission
 reductions are valued. Using the range
 of values for the average benefit per Mg
 for SO2 and the assumptions for the
 changes in emissions, monetized annual
 SO2 disbenefits of MACT I range from
 $ 1,064 million down to $0. For the
 proposed MACT II alternative, total
 annual SOz benefits are from
 approximately $0.1 to $0.3 million.
 Therefore, total monetized SOz benefits
 (disbenefits) of the integrated rule are
 approximately ($1,064) million to $0.3
 million.
   Summing the monetized benefits and
 disbenefits for VOC, PM, and SO2
 emission changes provides a range of
 total annual benefits (disbenefits) for
 MACT I of approximately ($ 1,040)
 million to $1,054 million. Aggregate
 annual benefits attributed to MACT n
 range in value from $302 million to
 $384 million. Combining the benefits of
 the final and proposed air standards
 yields a range of total annual benefits
 from approximately ($739) million to
 $1,438 million.
   These benefits are incomplete due to
 EPA's inability to quantify many benefit,
 and disbenefit categories including
 individual health and welfare endpoints
 as well as the benefits and disbenefits of
 controlling entire pollutant categories.
 Pollutant categories that are not
 monetized are HAPs, TRS, CO, and
 NOX.
   c. Uncertainties Associated With Air
 Quality Benefits. Benefit per Mg
 estimates used to monetize PM  and VOC
 emission reductions are uncertain
 because average benefit per Mg values
 do not take into account location-
 specific information such as the
 population exposed. The location-
: specific information is expected to have
 a significant effect on the estimated
 benefits associated with these emission
 reductions. Also, lack of information for
 several benefit categories precludes a
 complete quantification of all benefit
 categories (or disbenefits for pollutant
 increases).   .
 2. Water Quality Benefits
   This section describes environmental
 and human health benefits expected as
 a result of implementing new BAT/
 PSES limits at 92 of the 96 mills in the
 Bleached Papergrade Kraft and Soda
 and Papergrade Sulfite subcategories.
 (EPA estimated benefits for 92 mills
 because it did not have effluent
 discharge .information from 3 mills and
 did not have receiving stream flow data
 for 1 mill). Because,EPA was not able
 to project the number of new sources, •
 EPA attributes no benefits to the final
 NSPS or PSNS regulations. Discharge of
.' toxic, nonconventional, and
 conventional pollutants into freshwater,
 estuarine, and marine ecosystems may
 alter aquatic habitats, affect aquatic life,
 and adversely impact human health. See
 Section Vn.B.2. Chlorinated organic
 compounds from chlorine bleaching,
 particularly 2,3,7,8-tetrachlorodibenzo-
 p-dioxin (TCDD) and 2,3,7,8-
 tetrachlorodibenzofuran (TCDF) are
 human carcinogens and human
 systemic toxicants and are toxic to
 aquatic life. These pollutants are
 persistent, resistant to biodegradation,
 and bioaccumulative in aquatic
 organisms. As of December 1995,' states
 have issued 19-dioxin/furan-related fish
 consumption advisories near 18
 papergrade sulfite and bleached
 papergrade kraft and soda mills (EPA,
 National Listing of Fish Consumption
 Advisories, June 1996).
   EPA's analysis of these environmental
 and human health risk concerns and the
 water-related benefits resulting from the
.final effluent limitations guidelines and
 standards for these two subcategories is
 contained in the "Water Quality
 Assessment of Final Effluent
 Limitations Guidelines for the
 Papergrade Sulfite and Bleached
 Papergrade Kraft and Soda
 Subcategories of the Pulp, Paper, and
 Paperboard Industry" (WQA) (DCN
 14650). ,
•   a. Qualitative Description of Water-
 Related Benefits. The finai EAT
 limitations and PSES promulgated today
 for Subparts B and E will benefit aquatic
 life by reducing the pulp and paper
 industry's discharge of toxic and .
 nonconventional pollutants, including a
 91 percent reduction in TCDD and
 TCDF, a 69 percent reduction in AOX,
 an 83 percent reduction in chloroform,
 and an 82 percent reduction in
 chlorinated phenolic pollutants
 compared to mid-1995 discharge levels.
 Toxic and nonconventional pollutants
 will be reduced to levels below those
 considered to impact biota in many
 receiving waters. Pollution reduction
 numbers are provided in Section
 Vn.B.2. Such impacts include acute and
 chronic toxicity, sublethal effects on
 metabolic and reproductive functions,
 and loss of prey organisms. Chemical
 contamination of aquatic biota may also
 directly and indirectly impact local
 pescivorous wildlife and birds.  ,
   b. Quantitative Estimates of Water-
 Related Benefits. EPA has quantified
 human health and aquatic life benefits
 using a site-specific analysis for baseline
 conditions and for the conditions that
 would result from pollutant removals
 under the rule. The final BAT
 limitations and PSES for Subparts B and
 E would result in a significant reduction
 of dioxins and furans in fish tissues. As
a result, the largest quantifiable and
monetizable water benefit is a reduction
in number of potential excess cancer
cases from the consumption of
contaminated fish by recreational and
subsistence  anglers. The next largest
category of monetized benefits includes
recreational fishing benefits derived
from.lifting of all 19 existing dioxin/
furan-related fish consumption
advisories in waters downstream from
mills in the Bleached Papergrade Kraft
and Soda  and Papergrade Sulfite
subcategories. Removing fish
consumption advisories would be
expected to increase the number of
recreational anglers at sites where
advisories are lifted and to increase
fishing enjoyment by existing anglers.
Three of the 19 receiving streams with
dioxin/furan-related fish consumption
advisories also have advisories in place
for other contaminants (from other
sources) that will not be affected by this
rule. No monetized benefits are
expected to accrue for these streams at
this time.  Quantified, non-monetized
benefits include reduction in
exceedances of aquatic life and health-
based ambient water quality
concentrations.  .
  (1) Fish Consumption Cancer Risks
and Non-cancer Hazards. Upper-bound
individual cancer risk, aggregate risk,
and non-cancer hazards from
consuming contaminated fish are '
estimated  for recreational, subsistence,
and Native American subsistence
anglers. At proposal, concentrations of
carcinogenic and systemic toxicants in
fish were, estimated using two site-
specific models—a simple dilution
model and EPA's draft Dioxin.
Reassessment Evaluation model
(ORE) (DCN 14650). For the final rule,
EPA used  only the DRE model to
estimate TCDD and TCDF levels in fish
below 92 mills discharging into 73
receiving streams, as well-as individual
cancer risks and non-cancer hazards. Of
these mills, two in the Bleached
Papergrade Kraft and Soda subcategory
discharge  through the same pipe and
therefore were treated as a single
discharger. As a result, a total of 91
discharges from 92 mills were evaluated
for the water quality assessment. EPA
continues  to use the simple dilution,
model to evaluate other chlorinated
organics (i.e., three carcinogens and four
systemic toxicants). EPA believes the
DRE approach provides more reliable
estimates of dioxin and furan fate and
transport in the environment for use in
human health assessments. The reasons
for relying exclusively on the DRE for   :
assessing impacts due to dioxin and
furan are explained in greater detail in

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 18588      Federal  Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules  and Regulations
Chapters 4 and 8 of the Economic
Analysis (DCN 14649).
  EPA is also updating fish
consumption rates used to estimate
cancer and non-cancer hazards. At
proposal, EPA used 25 g/day for
recreational anglers, and 145 g/day for
subsistence anglers. The revised
estimates are 21 g/day for recreational
anglers and 48 g/day for subsistence
anglers, based on data provided by the
nationally based "Continuing Survey of
Food Intake by Individuals" (CSFII),
conducted by the U.S. Department of
Agriculture. EPA is also using an
updated fish consumption rate for
Native American subsistence
populations of 70 g/day, based on two
studies (CRIFTC, 1994; Wolfe and
Walker, 1989, in rulemaking record).
This consumption rate represents an
average fish consumption rate for Native
Americans. (See Environmental Justice
Analysis in Chapter 8 of the Economic
Analysis. DCN 14649).
  Projected individual cancer risks
differ among the evaluated mills and
among recreational, subsistence, and
Native American subsistence fishermen
due to the differences in consumption
rates. TCDD and TCDF contribute most
of the estimated cancer risks. The final
BAT/PSES for the papergrade sulfite
and Bleached Papergrade Kraft and
Soda subcategories are projected to
reduce average baseline individual
cancer risks up to about one order of
magnitude for each affected group—
recreational, subsistence, and Native
American subsistence populations. At
both baseline and post-compliance,
Native  American subsistence
populations are at about one order of
magnitude higher risk than recreational
anglers and less than one order of
magnitude higher risk than subsistence
fishermen in this assessment because of
their comparatively higher fish
consumption rates.
  At proposal, EPA estimated exposed
recreational and subsistence fishermen
based on a comparison of creel survey
results to licensed anglers in counties
adjoining pulp mill streams. Based on
these surveys, EPA estimated that 29
percent of county fishermen would use
affected stream reaches and therefore
could be exposed to contaminated fish.
Since proposal, EPA has considered
additional recreational angler survey
information and has determined that a
range of 10 percent to 33 percent of
adjacent county-licensed anglers
provides effective upper and lower
bounds to the fishing effort expected on
most affected stream segments. EPA's
benefit estimation methodology is
described in Chapter 4 of the Economic
Analysis (DCN 14649).
  EPA estimated the reduced annual
cancer cases for combined recreational
and subsistence angler populations as a
result of the final BAT/PSES for the
Papergrade Sulfite and Bleached
Papergrade Kraft and Soda
subcategories. The projected number of
increased cancer cases for this
population under baseline conditions
due to pulp and paper discharges is 0.83
to 2.76 annual cancer cases. EPA
estimates this number would decline to
0.1 to 0.35 excess cancer cases per year
after implementation of the final BAT/
PSES, thus eliminating approximately .
0.73 to 2.41 annual cancer cases!
  For Native American subsistence
fishermen, EPA evaluated an upper
bound total risk at baseline and post-
compliance with the selected BAT/
PSES. EPA assumed that the total
population of the tribes with treaty-
ceded fishing rights near pulp and paper
mills consumed an average of 70 g/
person/day of TCDD/TCDF
contaminated fish. The projected
number of increased cancer cases for
this population under baseline
conditions due to pulp and paper
discharges is 0.14 annual cancer cases.
EPA estimates this number would
decline to 0.008 excess cancer cases per
year after implementation of the final
BAT/PSES.
  With respect to non-cancer benefits,
EPA examined the current discharge of
four pollutants that have reference doses
(RfDs) contained in EPA's Integrated
Risk Information System (IRIS). The
four pollutants are chloroform,
pentachlorophenol, 2,3,4,6-
tetrachlorophenol, and 2,4,5-
trichlorophenol. The RfD represents an
estimate, with uncertainty spanning
perhaps an order of magnitude, of daily
exposure—expressed in milligrams per
kilogram of body weight per day (rag/
kg/day)—that is likely to be without an
appreciable risk of deleterious effects to
a given population during a lifetime.
(EPA notes that this analysis considers
only the contribution of Subpart B and
E pulp and paper current discharge
effluent to the RfD; the contribution
from other sources (background level of
exposure) is not evaluated.)
  For the four pollutants with RfDs in
IRIS, EPA used the simple dilution
model to determine fish tissue
concentrations. EPA then estimated
whether human consumption offish by
recreational, subsistence, and Native
American subsistence populations
exposed to the pollutants below pulp
and paper mills would exceed a
chemical-specific noncancer hazard
quotient of 1.0. Hazard quotients are
based on the relationship between fish
tissue concentrations, fish consumption,
and RfDs. If a hazard quotient exceeds
1.0, adverse effects might occur. None of
the four pollutants with RfDs in IRIS is
estimated to exceed a non-cancer hazard
quotient of 1.0 under baseline or BAT/
PSES conditions for recreational,
subsistence, or Native American
subsistence anglers.
  EPA did not use the reference dose
(RfD) approach to evaluate potential
noncancer effects associated with
dioxin/furan.  The use of an RfD for
dioxin/furan presents special problems.
If EPA were to establish an RfD for
dioxin/furan using the standard
conventions of uncertainty, the RfD
value would likely be one to two orders
of magnitude  below average background
population exposure. As stated above,
the RfD is a level that is likely to be
without an appreciable risk; it is not an
"action level" or exposure level where
non-cancer effects are predicted. Where
the RfD is below background levels, and
where effects  are not readily apparent at
background levels, it is not appropriate
to use the RfD for quantifying; benefits.
•  As an alternative to using Sae RfD,
EPA evaluated potential noncancer
effects of dioxin/furan by comparing the
modeled incremental exposure of
dioxin/furan from fish consumption
(based on results from the DRE model)
to estimated ambient background levels
(i.e., 120 picograms of toxic equivalents/
day (pgTEQ/day)). EPA estimates that
adverse impacts associated with dioxin/
furan exposures may occur at or within
one order of magnitude of average
background exposures. As exposures
increase within and above this range,
the probability and severity of human
noncancer effects most likely increases.
EPA's analysis shows that the estimated
dioxin/furan exposure from pulp and
paper effluent at baseline exceeded
estimated ambient background exposure
by an order of magnitude for two mills,
with the size of the exposed population
ranging from 4,910 to 16,205
recreational and subsistence anglers.
The selected BAT/PSES are projected to
reduce the incremental exposure from
fish consumption to a level that was not
significantly different from estimated
ambient background exposure. The size
of the recreational and subsistence
angler population exposed to dioxin/
furan doses exceeding one order of
magnitude greater than the background
leyel'would be zero under the selected
BAT/PSES.
  For Native American subsistence
populations with treaty-ceded fishing
rights, the maximum dioxin/furan
exposure under baseline conditions is
projected to be 803 pgTEQ/day. Under
the selected BAT/PSES, the maximum
exposure is reduced to 39 pgTEQ/day,

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              Federal Register/Vol. 63. No. 72 / Wednesday.  April 15, 1998/Rules and Regulations      18589
 which is less than estimated background
 levels for the United States.
   (2) Impact of BAT/PSES Controls on
 Dioxin/Furan-Related Fish
 Consumption Advisories. EPA'estimates
 that all 19 dioxin/furan-related fish   ;
 consumption advisories in place
 downstream of papergrade sulfite and
 bleached papergrade kraft and soda
 mills  as of December 1995 would be
 lifted some time after the rule is
 implemented. Recent evidence indicates
 that dioxin/furan fish tissue
 concentrations decline within several
 years  of removing dioxin/furan
 discharges, which is more rapidly than
 previously thought (see Chapter 9 of the
 Economic Analysis, DCN  14649). EPA
 accounts for potential latent dioxin/
 furan contributions from sediment to
 fish tissue by assuming a three-year.lag
 before cancers from fish tissue
 consumption are reduced or dioxin/
 furan-related fish tissue advisories are
 lifted.
   (3) Exceedances of Human Health-
 Based Ambient Water Quality
 Concentrations (AWQCs). EPA also has
 compared the modeled  in-stream
. pollutant concentrations to human
 health water quality criteria or other
 toxic effect values, which are referred to
 as health-based AWQCs. Exceedances of
 health-based AWQCs indicate existing
 human health-based water quality
 problems.
   EPA has analyzed the health-based
 AWQCs for the ingestion of organisms
 and the ingestion of water and
 organisms based on the simple dilution
 model. EPA estimates that no mills
 exceed the health-based AWQCs for
 ingestion of organisms only under
 baseline conditions or under the final
. rule. With respect to the ingestion of
 water and organisms, at baseline, three
 mills exceed AWQCs for two pollutants,
 chloroform and pentachlorophenol (a
, total of four exceedances). Under the
 rule, only one mill exceeds AWQCs (for
 pentachlorophenol).
   EPA did not estimate exceedances of
 AWQCs for dioxin and furan because
 the simple dilution model is not well-
 suited for use in estimating human
 health effects associated with water
 column concentrations of hydrophobic
 chemicals like dioxin and furan. EPA
 did not use the DRE model for this
 analysis for dioxin/furan because results
 of the DRE model  would not be  ,
 comparable with AWQCs.
    (4) Aquatic Life Benefits. EPA used
  the simple dilution approach to estimate
  exceedances of aquatic life AWQCs.
  This is a conservative approach that
  assumes all pollutants' (including dioxin
  and furan) discharged to receiving
  streams are available to the biota.
  Although hydrophobic chemicals such
  as dioxins and furans will be associated
  primarily with suspended particulates
  arid sediments, some concentrations
  will also be found in the water column
  near the discharge point. This is
  particularly true if discharges are
  assumed to be continuous because even
  though the pollutants might eventually
  become associated with suspended
  solids and sediment, they would also be
  present in the water column  in the
  vicinity of the discharge on an ongoing
  basis prior to partitioning. Therefore,
  although it is conservative, EPA believes
- that the simple dilution approach
  provides a reasonable estimate of
  impacts to aquatic life.
   EPA compared modeled in-stream
  concentrations of toxic discharges to
  EPA's aquatic life AWQCs. EPA's
  modeling results show that receiving
  water concentrations for up to four
  pollutants (of 15 pollutants with chronic
  aquatic life AWQCs) at 19 mills exceed
  aquatic life criteria at baseline discharge
  levels  (up to 25 total exceedances). The
  final BAT/PSES for the papergrade
  sulfite and Bleached Papergrade Kraft
  and Soda subcategories are projected to
  reduce these exceedances to one
  pollutant (TCDD) at six mills (six total
  exceedances). On average, the selected
  BAT/PSES will reduce color  of effluent
  by approximately 2.5 percent compared
  to current discharges. This color
  reduction may have some aquatic life or
  recreational benefits depending on the
  natural color of the receiving water, but
  they are not quantifiable of monetizable
  at this time.
  , c. Monetization of Water Quality
  Benefits. Monetized benefits  of the final
  BAT/PSES for mills in the Bleached
  Papergrade Kraft and Soda and
  Papergrade Sulfite subcategories are
  presented in Table VHI-6. EPA has
  monetized the human health benefits
  resulting from elimination of 0.73 to
  2.41 cancer cases per year for the nation
  as a whole (see Sectipn VuT.F.2.b.(l)).
  The projected benefits range from $2
  million to $22 million.
   EPA estimates the value to anglers of
  contaminant-free fisheries as a result of
lifting 16 of the 19 dioxin/furan-related
fish consumption advisories to be $2
million, to $19 million. (Because these
values are based on a benefits transfer
from a study of contamination of the
Great Lakes trout and salmon fishery,
which may differ greatly from some of
the areas affected by this rule, these
values provide only a general sense of
the magnitude of the benefits of the
rule.) Because non-dioxin/furan fish
consumption advisories (PCBs and
mercury) will remain in place on three
streams, EPA did not monetize the
benefits of removing the dioxin/furan
fish consumption advisories on these
streams. EPA also estimates that
recreational fishing would increase on
the 16 streams by  115,000 angling days
to 379,000 angling days post-
compliance. However, the monetary
value of this increase is not estimated  >
because of the difficulty of determining
the extent to which this increased
participation reflects a net increase in
fishing activity or merely a shift from
other locations (see the Economic
Analysis, DCN 14649, Chapter 4).
  Because of dioxin/furan removals due
to compliance with BAT limitations and
PSES, sludge from pulp and paper mills
may be disposed of through land
application, instead of more costly
landfilling or incineration. (Pursuant to
a January 1994 Memorandum of
Agreement between EPA and the
American Forest and Paper Association
(AF&PA), a maximum dioxin/furan
concentration of 50 ppt is allowed for
land application of sludge or a sludge-
derived product. See DCN 14399). Mill
sludge disposal costs could be expected
to decline by $8 million to  $16 million.
EPA estimated these values based on the
reduced tonnage of expected dioxin/
fufan-contaminated sludge, which in
turn was based on the proportional,
reduction of dioxin/furan in effluent
(see the Economic Analysis, DCN 14649,
Chapters).            .    ,
  Total rrumetized water-related
benefits for all the above categories
range from $12 million to $57 million.
  As noted previously, the above
estimates do not include the benefits
that have been identified but not
monetized, such as health effects for
Native American subsistence fishermen,
reduction in AWQC exceedances,
reduction of projected non-cancer
effects and improvements in fish and
wildlife habitat.

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 18590
Federal Register/Vol. 63, No.  72/Wednesday, April  15, 1998/Rules and Regulations
  TABLE VIII-6.—MONETIZED WATER QUALITY BENEFITS OF FINAL BAT/PSES FOR BLEACHED PAPERGRADE KRAFT AND
                                      SODA AND PAPERGRADE SULFITE MILLS
Benefit category
Water-related Benefits
Human health (recreational fish consumption) 	 ; 	
Recreational angling
"Contaminant-free" fishery 	 	
Increased participation 	
Reduced Sludge Disposal Costs 	 	 	
Total Water-related Benefits 	
Final BAT/PSES
(millions 1995$)
$2-$22
$2-$19
+
$8-$16
S12-S57
  + Positive benefits expected but not estimated.
H. Comparison of Costs and Benefits

  This section provides the individual
and combined costs, economic impacts,
and benefits of the proposed and final
CAA and CWA pulp and paper
regulations described in earlier sections.
See Table Vffl-7. The costs and benefits
of the CAA (MACT) rules apply to all
155 kraft, soda, sulfite and semi-
chemical mills subject to final or
proposed MACT requirements, while
the costs and benefits for the final CWA
(BAT/PSES) regulations apply to the 96
                         'mills in the Papergrade Sulfite and
                         Bleached Papergrade Kraft and Soda
                         subcategories.
                           Using the pre-tax annualized cost
                         estimates reported in Section Vni.C, net
                         monetized air-related benefits are
                         , estimated to range between net costs of
                         $1.165 million to net benefits of $929
                         million per year for the final MACT I
                         rule considered in combination with the
                         pre-tax annualized cost estimates for the
                         final BAT/PSES. Pre-tax annualized cost
                         estimates are used as a proxy for the
                         social costs of the rules. Net benefits of
the proposed regulatory alternative for
MACT H are $270 million to $352
million. Thus, the range of net benefits
(disbenefits) of the final and proposed
air quality standards is ($896) million to
$1,281 million.
  EPA did not estimate annual net
benefits for the final BAT/PSES for the
Papergrade Sulfite and Bleached
Papergrade Kraft and Soda subcategories
because so many categories of benefits
are unmonetized that the comparison
would be misleading.
                       TABLE VI11-7.—SUMMARY OF COSTS, ECONOMIC IMPACTS AND BENEFITS



Capital Costs 	
Pre-Tax Annualized Costs* 	
Monetized Annual Benefits 	


Net Annual Benefits (Benefits-Costs) 	

Projected Mill Closures 	
Potential Job Losses (due to mill clo-
sures) 	 	 	
Projected Firm Failures 	
r
MACTI

$501
$125
($1,040)-

$1,054
($1,1 65V-
$929
0

0
0

MACT II

$258
$32
$302-$384


$270-$352

0

0
0

Combined
air rules

$759
$157
($739V-

$1,438
($896)-
$1,281
1

ND
0

Final BAT/
PSES

$1,039
$263
$12-$57


NE

1

ND
0
MAPT 1 anrl
final BAT/
PSES (96

$1 394
$351
($1 028V-

$1,111
NE

2

900
0
MACT I,
MACT II,
and final
BAT/PSES
(96 mills)
$1 524
$366
NE


NE

3

ND
0
MACTI, ,
MACT II,
and final
BAT/PSES
(155 mills)
$1 799
$420
($727>—

$1,495
NE

3

ND
O
  * Pre-tax costs are greater than the post-tax annualized costs shown in Tables VIII-1 and VIII-3.
  Net costs (where costs exceed benefits) are shown in parentheses.
  NE s not estimated.
  ND = not disclosed to protect confidentiality.
  Figures in table reflect rounding.
L Costs and Benefits of Rejected Options
for the Bleached Papergrade Kraft and
Soda Subcategoiy—Option B and TCP
1. Air Benefits
  As noted in Section VTJI.F.l, the
oxygen delignification technology used
as a component of Option B and TCP
increases emissions of certain pollutants
and, hence compliance costs to meet
MACT I standards; the implementation
of additional MACT controls, however,
also increases MACT-related removals.
As a result, both MACT I costs and
benefits increase wh'ere oxygen
delignification is utilized. (As noted
                         above, only VOC, PM, and SO2 benefits
                         are monetized here.) However, because
                         the MACT I technologies control all of
                         the increased emissions associated with
                         oxygen delignification, there is no
                         increased net benefit of the CWA and
                         CAA technologies to ambient air
                         quality. Rather, the net monetized
                         benefits of MACT I in combination with
                         Option B or TCP are equivalent to the
                         monetized benefits of MACT I in
                         combination with the final BAT/PSES.
                         Thus, MACT I benefits associated with
                         reducing VOCs under either Option B or
                         TCP range from $29 million to $1,050
                         million. MACT H VOC reduction
benefits range from $2 million to $84
million. Therefore, total monetized VOC
benefits of the air quality standards
under either Option B or TCP are $31
million to $1,134 million. PM related
disbenefits for MACT I are $1 million,
while MACT E PM benefits aire $300
million for a total PM benefit of
approximately $299 million, for either.
Option B or TCP. SO2 related disbenefits
for MACT I are from $ 1,043 million
down to $0, while MACT H SO2 benefits
are from $0.1 to $0.3 million.
  Total monetized benefits (disbenefits)
for MACT I are ($1,015) million to
$1,049 million under BAT/PSES Option

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             Federal Register /Vol. 63, No. 72/Wednesday, April  15,  1998/Rules and Regulations
                                                                     18591
' B or TCP (see the Economic Analysis,
 DCN 14649, Chapter 8). Aggregate
 annual benefits attributed to MACT n
 range in value from $302 million to
 $384 million. Combining the benefits of
 the final and proposed air quality
 standards yields a range of total annual
 air quality'benefits .(damages) from
 ($713) million to $ 1,433 million.

 2. Water Benefits
   The water quality benefits described
 in this section include benefits for
 rejected BAT/PSES options for the
 Bleached Papergrade Kraft and Soda
 subcategory in combination with
 benefits for the selected BAT/PSES for
 the Papergrade Sulfite subcategory.
 (Benefits for the two CWA subcategories
 were also combined in Section VIILG.2
 for the selected BAT/PSES.) EPA
 estimated the human health benefits
 that could be expected if either of the
 rejected BAT/PSES options for the
 Bleached Papergrade Kraft and Soda
 subcategory—Option B or TCP—were
 implemented. For combined
 recreational and (non-Native American)
 subsistence angler populations using the
 same fish consumption rates EPA used
 for the selected BAT/PSES, Option B is ,
. projected to eliminate approximately
 0.75 to 2.50 annual cancer cases from
 the baseline of 0.83 to 2.76 annual
 cancer cases projected to result from the
 mills' discharges at [mid-1995] levels,
 leaving a residual of 0.08 to 0.26 excess
 cancer cases per year. Here, as in
 Section Vm.G.2.b(l), excess cancer
 cases refers to cancer cases attributable
 solely to pulp and paper dioxin/furan
 discharges. This represents a reduction
 of 90 percent from baseline. The
 monetized value of this reduction is $2
 to $23 million. TCP is projected to result
 in a reduction from the mid-1995
 discharge baseline of 0.83 to 2.76 cases
 to 0.0 cases, which increases the
 benefits from TCP by $0.1 million to
 $2.7 million, compared to Option B.
 Because chlorine or chlorinated
 compounds are not used for bleaching,
 no dioxin formation was attributed to
 the mills under this option. Although
 some background dioxin cancer risk
 would remain that is attributable to
 sources other than current pulp and
 paper discharges, no residual cancer
 risk would remain from bleached
 papergrade kraft and soda mills.
   For Native American subsistence
 fishermen, EPA evaluated cancer risks  ,
 at baseline and under Option B. To
 estimate the maximum potential risk,
 EPA assumed that the entire population
 of the tribes with treaty-ce'ded fishing
 rights near pulp and paper mills would
 consume an average of 70g/person/day
 of TCDD/TCDF contaminated fish. With
 this level of consumption, the projected
 increased number of cancer cases for
 this population at baseline would be
 0.14 cancer cases/year. EPA estimates
 that this number would decline to 0.007
 cancer cases/year if BAT/PSES based on
 Option B were promulgated and to 0.0
 cases/year if BAT/PSES based on TCP
 were promulgated.
   Both Option B and TCP would result
 in the removal of 19 dioxin/furan-
 related fish consumption advisories on
 streams downstream from bleached
 papergrade kraft and soda mills. EPA
 estimates that non-dioxin advisories
 will remain on three of those streams.
 Therefore, here as in Section VHI.G.2.C,
 EPA did not monetize the benefits of
 removing the dioxin/furan fish
 consumption advisories on these
 streams. EPA estimates the value to  .
 anglers of the  16 "contaminant-free"
 fisheries as a result of removing these
 advisories to be $2 million to $19
 million. EPA also estimates that
 recreational fishing would increase on
 these 16 streams by an estimated
 115,000 angling days to 379,000 angling
 days post-compliance. However, the
 monetary value of this increase is not
 estimated because of the difficulty of
' determining the extent to which this
 increased participation reflects a net
 increase in fishing activity or merely a
 shift from other locations. These results
 are the same as those presented for the
 selected BAT/PSES. Because of dioxin
 removals, sludge disposal costs for both
 Option B and TCP could be expected to
 decline by $8 million to $16 million (see
 the Economic  Analysis, DCN 14649,
 Chapters).
   With respect to non-cancer human
 health benefits, none of the four
 pollutants with RfDs is estimated to
 exceed a non-cancer hazard quotient of
 1.0 under baseline or under conditions
 associated with rejected Option B for
 recreational, subsistence, or Native
 American subsistence anglers. The same
 is true for the selected BAT/PSES.
 Similarly, Option B would reduce
 projected health-based AWQC
 exceedances to one facility-for one
 pollutant (pentachlorophenol). Under
 TCP, EPA estimates that there would be
 no exceedances of health-based AWQCs.
 For dioxin, EPA estimates that Option B
 would reduce incremental exposure
 from fish consumption to a level that is
 not significantly different from ambient
 background exposure. Under TCP,
 chlorine and chlorinated compounds
 are not used for bleaching, and therefore
 no dioxin was attributed to mills tinder
 this option.
   With respect to aquatic life benefits,
 EPA's modeling results show that, for
 the four pollutants exceeding chronic
aquatic life criteria at 19 mills'(up to 25
total exceedances), rejected Option B
would reduce these exceedences to one
pollutant (TCDD) at three mills (three
total exceedences). TCF would reduce
these exceedances to zero.
  In addition to the benefits of reducing
dioxin in fish, EPA investigated other
potential benefits associated with
Option B and TCF, including color,
COD, AOX, and chronic sub-lethal
toxicity.
  Increased color in a receiving water
can decrease light penetration there,
thus resulting in shifts of phytoplankton
community structure to undesirable
species, reduced primary productivity
(which can alter the trophic structure of
fish communities), and elevated
receiving stream temperatures. -
However, the actual impact on the
receiving water of reducing color in mill
effluent is highly site-specific and
depends in particular on the natural
color of the receiving water and other
factors. Therefore, the monetized
benefit? will also be site-specific, to the
extent that they can be determined at
all. EPA is not promulgating national
technology-based limitations or
standards for color, but rather has
determined that .the potential aesthetic
or aquatic impacts are best addressed on
a site-specific basis by the permitting or
pretreatment authority where necessary.
See Section VI.B.S.e. Indeed, EPA notes
that about eight mills currently have
limitations for color in their NPDES
permits, and an additional two mills
have current color monitoring
requirements where stream water
quality requires such measures.
  Lowering COD can protect the
receiving water against oxygen
depletion and is likely to reduce non-
chlorinated organic compounds that
cause chronic sub-lethal effects on
aquatic life. Evidence indicates that this
toxicity is associated at least in part
with families of non-chlorinated organic
materials. Severed studies indicate that,
as wastewater COD is reduced, indices
of these chronic toxicity effects,also are
reduced. EPA is deferring regulation of
COD to the individual permitting
process for the time being,  although
EPA intends to promulgate effluent
limitations guidelines, and standards for
COD for Subpart B mills in the future.
See Section VLB.S.d.
'  Although a statistically significant
relationship between AOX and adverse
environmental effects has not been
established, EPA believes that reduction
of AOX (a valid measure of the total
chlorinated organic matter) will result
in water quality benefits. See Section
VI.B.3.C. However, these cannot be
quantified at this time.

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 18592      Federal Register/Vol.  63, No. 72/Wednesday,  April 15,  1998/Rules and Regulations
   Compared to current discharges, the
 incremental benefits associated with OD
 (Option B) include: reduction of color
 (by 40 percent); COD (by 40 percent);
AOX (by 84 percent); and chronic sub-
lethal aquatic toxiciry. TCP would also
reduce color discharges (by 40 percent),
COD (by 40 percent), AOX (by 96   ,
percent) and chronic sub-lethal aquatic
toxicity. The water quality benefits of
the rejected options are shown in Table
vm-8.
 TABLE VIII-8.—MONETIZED WATER QUALITY BENEFITS OF REJECTED BAT/PSES OPTIONS FOR BLEACHED PAPERGRADE
                                  KRA'FT AND SODA & PAPERGRADE SULFITE MILLS
Benefit category
Water-related Benefits
Human health (Recreational fish consumption)
Recreational angling
"Contaminant-free" fishery 	 	 	 .' 	
Increased participation 	 	 	
Reduced Sludge Disposal Costs 	 	 	
Total Monetized Water-related Benefits 	 .'. 	 ; 	
Option B
(millions
1995$)
$2-$23
$2— $19
+
$8-$16
$12-$58
TCF
(millions
1995$)
$2-$25
$2-$19
+
$8— $16
$12-$60
  + Positive benefits expected but not estimated.
  Combined annual air and water
benefits related to Option B for all 155
mills regulated by today's rule,
including final MACT I, proposed
MACT n and BAT/PSES based on
Option B, would total ($701) million to
$1,491 million. Combined annual air
and water benefits related to TCF,
including final MACT I, proposed
MACT H and BAT/PSES based on TCF
would total ($701) million to $1.493
million.
/. Benefit-Cost Comparison Using Case
Studies
  Many benefits are highly site-specific.
At proposal, EPA estimated the costs
and benefits of the pulp and paper rule
at three sites using a case study
approach. EPA has expanded the case
study analysis to incorporate additional
sites. The case studies focus on water
quality benefits, resulting from
installation of BAT/PSES technologies.
with air quality benefits modeled for
case study mills as they are at the
national level (see Section VQ1.G.1,
above). The three case studies at
proposal were (1) the Penobscot River in
Maine, (2) the Wisconsin River in
central Wisconsin, and (3) the lower
Columbia River in Washington and
Oregon. In addition, a qualitative
retrospective case study was conducted
of the Leaf River in Mississippi. These
case studies were selected to provide
geographic representation of the impacts
of the proposed rule, taking data
availability into consideration.
  For the final rule, the three
quantitative case studies were updated
to reflect EPA's revised analysis of costs,
loadings, and human health risks to
sport anglers. In consideration of
environmental justice, EPA also
evaluated health risks to Native
American anglers in the Penobscot and
Columbia River case study areas.
  The four new case studies of
monetized benefits analyze: (4) the
Lower Tombigbee and Mobile River
watersheds in Alabama, (5) the Pigeon
River in North Carolina, (6) the Samoa
Peninsula in California, and (7) the
upper Columbia River in Washington
State and British Columbia, Canada.
These new case studies provide EPA
with the first real empirical evidence of
already-realized benefits that can be
expected from adoption of the final
BAT/PSES limits.  Although a portion of
the water-related benefits estimates in
these newer case studies are based on
actual outcomes from installing
pollution control equipment (i.e., a
retrospective analysis), estimates of the
benefits of MACT standards in these
case studies are prospective, based on
expected future benefits.
  The case studies compare costs and
benefits at specific bleached papergrade
kraft and soda mills in these seven areas
across the country, some of which have
not installed technologies comparable to
the bases for BAT/PSES and some of
which have installed such technologies,
thereby allowing the retrospective
assessment of BAT/PSES costs and
benefits. Where mills have installed
BAT-like technologies, capital
investments may include: 70 percent to
100 percent substitution; oxygen
delignification plus 100 percent
substitution; and/or totally chlorine-free
technologies.
  EPA evaluated control cost estimates
and air benefits for emission controls
necessary to meet the MACT I and n
standards on a prospective basis,
assuming the level of controls currently
existing at mills in the case study areas
as a baseline.
  As with the national-level analysis,
significant water-related benefits are
derived from removal of dioxin/furan
from fish, and air-related benefits from
improved agriculture and health from
reduced ozone emissions. However, the
case studies also address a wider range
of water-related benefits, including
some site-specific recreational benefits
such as surfing, boating, white water
rafting, non-consumptive uses and non-
use benefits that result from improved
color in the receiving water, improved
odor and removal of health advisories.
The case studies provide a more
complete picture of the range of water-
related benefits that may be expected
from the rule, although a number of
identifiable benefits, including
improvements in ecological conditions
and reductions of non-cancer health
effects remain unquantified and
unmonetized.
  Benefits and costs for the case studies
are summarized and compared in Table
VTH-9. The monetized benefits range
from two percent to 387 percent of BAT/
PSES compliance costs. The case study
results indicate that monetized benefits
may be of the same order of magnitude
as costs at individual sites.
  From a water quality perspective, the
case studies provide a cross-section of
mills and receiving waters nationwide,
including fast- and slow-moving
streams, lakes and ocean waters.
  Using receiving water and population
characteristics, EPA attributed benefits
from the case study sites to all bleached
papergrade kraft and soda and
papergrade sulfite mills. As a sensitivity
analysis, EPA used the water quality
benefits from the case studies to
estimate the national level water quality
benefits of the integrated final and
proposed rule for the Bleached
Papergrade Kraft and Soda and
Papergrade Sulfite subcategories.'Based
on the case studies, monetized benefits
from the water rules (Option A) would
be expected to range from $91 million
to $451 million per year, or from 35

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             Federal Register/Vol. 63. No. 72 / Wednesday, April  15,  1998 /Rules and Regulations
                                                                     18593
percent to 170 percent of water-related
costs.
   The case studies were not selected to
 be, and are not necessarily,
representative of national benefits with,
respect to air quality.
   TABLE VIH-9.—COMPARISON OF POTENTIAL ANNUAL BENEFITS TO POTENTIAL ANNUALIZED COSTS FOR SEVEN CASE
                                                   STUDY SITES
                                                [Millions of 1995 dollars]
Site
Water-related
benefits
Air-related benefits'1
MACT 1
MACT II
Total monetized
benefits
Total compli-
ance costs3
                                              ORIGINAL CASE STUDIES
Penobscot River 	 	 	
Wisconsin River 	
Lower Columbia River 	 	

' $0.7-$23
$0 1-$1 5
$1 5-$86

($9 5}-7 7
($16 9)— 15 6
($26 9)— 56 2

$0 1
$2 1
$07

($87) 10 1
($147)— 19 2
fip4. 7\_fiS Z

M
\ 1
•
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18594
Federal Register/Vol. 63, No.  72/Wednesday, April 15,  1998/Rules and Regulations
labeled Tier I, Tier E and Tier IE; the
two NSPS tiers are labeled Tier n and
Tier ffl. Tier HI is the most stringent of
the tiers. Each BAT tier is made up of
an array of increasingly more stringent
enforceable effluent limitations,
culminating in the ultimate performance
requirements for that particular tier. The
NSPS tiers consist entirely of the
ultimate perfbrmance.requirements for
each tier. In addition to the Voluntary
Advanced Technology effluent
limitations and NSPS codified today,
EPA has also  assembled a number of
incentives relating to permitting and
enforcement matters and public
recognition. EPA hopes these incentives
will encourage many mills to develop
and install advanced and even
innovative technologies that will lead
the industry as a whole toward the
elimination of pollutant discharges.
  EPA believes it is appropriate as a
matter of policy to offer mills incentives
to reach beyond the baseline BAT and
NSPS process technologies. Capital
costs associated with the Tier I
technology are substantially greater than
the capital costs of Option A, which is
the technology basis for the baseline
BAT limits. Although over ten years a
mill employing Tier I technologies will
likely save money in operating costs, the
capital outlay involved may discourage
mills from doing more than the
regulatory minimum. For Tiers II and
HI, the costs and risks are even more
acute, when one considers the cost of
research, development, and full scale
commercial trials of technologies in the
early stages of development and
implementation, as well as the
associated uncertainties concerning
possible product impacts. EPA is
interested in encouraging research,
development  and installation of
emerging technologies in order to
motivate the development of these
technologies for broader commercial
applications.  As these technologies
become proven and their efficiencies
publicized. EPA hopes that they will
become—in effect if not as a matter of
law—the industry floor. Thus, EPA
believes it is in the public interest to
encourage mills today to develop
environmentally beneficial technology
and to reward mills that are innovative
and forward-looking in their use of new
and more environmentally effective
technology despite its greater cost.
  EPA received suggestions for an
incentives program from a number of
stakeholders.  From these and other
stakeholder suggestions, EPA has
developed a program, presented below,
that is intended to provide incentives
for further long term environmental
improvements. EPA is incorporating
                          several types of incentives in this
                          program. In addition, because mill-
                          specific factors, including product
                          specifications and existing equipment,
                          will affect the technical approach taken
                          and the environmental goal attainable
                          by an individual mill, EPA is
                          establishing several tiers of Advanced
                          Technology performance objectives,
                          each with limitations and standards
                          specific to the model technology EPA is
                          positing. In order to promote ambitious
                          use of Advanced Technologies, EPA is
                          offering greater incentives for greater
                          reductions in pollutant discharge.
                            EPA recognizes that some mills in the
                          Bleached Papergrade Kraft and Soda
                          subcategory have already installed or
                          have committed to install Advanced
                          Technologies that are achieving or have
                          the potential  to achieve effluent
                          limitations equivalent to the ultimate
                          performance  requirements of one or
                          more of the Voluntary Advanced
                          Technology Incentive Tiers. If these
                          mills accept enforceable NPDES permit
                          limitations at one of the Tier levels, they
                          will qualify for the incentives program
                          at that level. In some instances,
                          therefore, the incentives will actually
                          serve as rewards for effluent reductions
                          already achieved.

                          2. Mechanics of the Incentives Program
                            The Voluntary Advanced Technology
                          Incentives Program for the Bleached
                          Papergrade Kraft and Soda subcategory
                          will supplement the otherwise
                          compulsory baseline BAT and NSPS
                          program. EPA emphasizes that the
                          Voluntary Advanced Technology
                          Incentives Program is entirely
                          voluntary; no mill in Subpart B is
                          required to participate. Rather, mills
                          subject to the baseline BAT limits and
                          NSPS contained in Subpart B may
                          enroll in the incentives program and
                          thus subject themselves to more
                          stringent technology-based limitations
                          corresponding to the Incentives Tier
                          they select. For example, a mill that
                          determines that it can achieve Tier n
                          limits may designate itself as a BAT Tier
                          n mill. A mill with more than one fiber
                          line subject to Subpart B may choose to
                          enroll all or some of its fiber lines in the
                          Voluntary Advanced Technology
                          Incentives Program. A mill wishing to
                          experiment with advanced or even
                          innovative bleaching technologies also
                          may choose different Tiers for different
                          fiber lines. After the mill enrolls in the
                          Voluntary Advanced Technology
                          Incentives Program, the permit writer
                          must place the corresponding BAT
                          limitations in the mill's permit.
                          Achievement of the Advanced
                          Technology BAT limitations thereafter
                          would be compulsory for that mill. A
mill that chooses not to participate in
the program will receive the baseline
BAT limitations or NSPS; similarly, a
mill that chooses to enroll some but not
all of its Subpart B fiber lines in the
Voluntary Advanced Technology
Incentives Program will receive baseline
BAT limitations or NSPS for its non-
participating fiber lines.
  EPA expects that an interested mill
would formally enroll in the Voluntary
Advanced Technology Incentives
Program prior to issuance of its next
NPDES discharge permit. Enrollment
can be made by indicating the mill's
intent on its permit application or
through separate correspondence to the
permitting authority as long as the
signatory requirements of 40 CFR 122.22
are met. However, as discussed in more
detail in Section IX.A.7 below, EPA
assumes that most mills, for practical
purposes, will decide whether to
participate in the Voluntary Advanced
Technology Incentives Program in the
next year in order to assure that they
will have the maximum amount of time
to achieve the various Tier limitations
and to receive the additional.
compliance time for  MACT, established
under these rules for mills enrolled in
the Voluntary Advanced Technology
Incentives Program. Any mill can
voluntarily enter at any tier appropriate
to its individual circumstances. Further,
mills that enter either at Tier I or Tier
n may decide, after making such a
commitment in permits but before
termination of the appropriate
compliance period (i.e., not later than
six years after publication of these
rules—Tier I, or not later than 11 years
after publication of these rules—Tier n),
to commit to the requirements of a more
stringent tier (i.e., Tier n 'or Tier.ffl).
Such mills will be subject to the
deadlines specified in the regulation for
the newly chosen tier.
  Existing dischargers volunteering to
participate in the incentives program
would receive BAT limitations that
become progressively more stringent
over time. Although  applied in stages,
the limitations represent a continuum of
progress that a participating mill
commits, and is required, to achieve. At
the first stage in the continuum are
limitations for the enrolled fiber line
that reflect either a mill's existing
effluent quality or its current
technology-based permit limits for the
BAT parameters, whichever are more
stringent. See 40 CFR 430.24(b)(l). For
the bleach plant parameters, such as
dioxin, existing effluent quality would
be determined at the bleach plant, while
existing effluent quality for AOX would
be determined at the end of fhe pipe
based on loadings attributable to that

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             Federal Register/Vol.  63,  No. 72/Wednesday,  April 15, 1998/Rules, and Regulations      18595
fiber line. Id. The next stage in the
continuum consists of enforceable
interim milestones. Under one set of
milestones, existing dischargers
enrolled in Tiers n or in are required to
meet interim BAT limitations equivalent
to the baseline BAT limitations by April
15,2004. 40 CFR430.24(b)(3). (By that
date, dischargers enrolled are required
to meet the baseline BAT limitations for
all pollutants, except for Tier I; the AOX
limitation for mills enrolled in Tier I is
the ultimate performance requirement
for Tier I. Id.) Under the second set of
milestones, existing dischargers
enrolled in any tier are required to meet
enforceable requirements determined by
the permitting authority based on best
professional judgment; these milestones
would be expressed as narrative or
numeric conditions in the mill's NPDES
permit. 40 CFR 430.24(b) (2). EPA
intends the milestones to reflect each
step in a mill's progress toward
achievement of the Tier's ultimate
performance requirements. Elsewhere in
today's Federal Register, EPA is
proposing to require each participating
mill to submit to its permitting authority
a plan  detailing the steps it plans to take
(with corresponding dates) in order to
meet its applicable BAT Tier
limitations. Under the proposed
regulation, permit writers would be
authorized to use the information in the
milestone plan as  a basis for setting
milestone limitations. The final stage in
the BAT continuum represents the
ultimate Advanced Technology
performance levels for the Tier selected.
40 CFR 430.24(b)(4)(i). As noted above,
the Voluntary Advanced Technology
Incentives Program is also available for
new sources that elect to exceed
baseline NSPS requirements. See 40
CFR 430.25 (c). For new sources (as
defined at 430.01 (j)), the incentives
program begins at Tier II. The ultimate
Tier n and Tier in performance
requirements constitute NSPS for such
mills, with the addition of standards for
conventional pollutants at the baseline
NSPS level. See 40 CFR 430.25(c)(l) and
(2). The NSPS Tier H and Tier m
performance requirements are the same
as the ultimate BAT Tier n and Tier m
performance requirements for BAT. As
required by CWA Section 306, new
sources must comply with the
applicable NSPS upon commencing
operation; therefore, the incremental
approach of achieving progressively
more stringent performance levels
discussed above for existing sources
would  not apply to new sources
enrolled in the incentives program;
  In addition to Voluntary Advanced
Technology BAT limitations and NSPS,
 the NPDES permit of a mill enrolled in
 the Voluntary Advanced Technology
 Incentives Program will need to contain
 all other permit limitations and
 conditions otherwise applicable to the
 mill, including any conventional
 pollutant limitations and standards, any
 water quality-based effluent limitations
 required under CWA Section
 301 (b) (1) (C), and best management
 practices provisions, including those
 promulgated today. Schedules for
 complying with those, requirements, if
 any, are determined by the applicable
 law; nothing in this incentives program
 alters in any way those compliance
 deadlines.        -         ,
   Because mills enrolling in the
 Voluntary Advanced Technology
 Incentives Program are subject to .more
 stringent BAT limitations and NSPS
 than EPA could otherwise compel
 through national effluent limitations
 guidelines, EPA has assembled a
 package of rewards and incentives for
 participating mills. The public
 recognition incentive is available as
 soon as a mill accepts Voluntary
 Advanced Technology BAT limitations
 in its NPDES permit. The reduced
 monitoring incentive applicable to
 dioxin, furan, chloroform and the 12
 chlorinated phenolic pollutants is
 available as soon as participating mills
 achieve those limitations. See 40 CFR
 430.02(c). The reduced monitoring
 incentive applicable to AOX is available
 only after the ultimate Advanced
 Technology performance level for that
 pollutant is achieved. See 40 CFR
 430.02(d) and (e). The remaining
 incentives, including greater permit
 certainty, reduced inspections, and
 reduced penalties, are available only
 after the mill achieves all of the ultimate
 Advanced Technology performance
 levels.
  EPA has decided not to make the
 Voluntary Advanced Technology
 Incentives Program available to indirect
 discharges at this time because it would
 be much more difficult to administer
 than the baseline PSES program and
 therefore would impose substantial
 burden on local governments. Further,
 EPA does not believe that commitments
 by indirect dischargers to reduce AOX
 or flow levels warrants any delay in
 compliance with limitations on dioxin
 and furan due to POTW pass-through
 and biosolids contamination concerns.
 Similarly, EPA has not identified
feasible technologies beyond BAT that
 can significantly reduce .pollutant
 discharges from mills in the Papergrade
 Sulfite subcategory at this time, and so
 is not able to develop an incentives
 program for this subcategory. Moreover,
 stakeholders have offered no specific
suggestions or supporting information
and data upon which EPA reasonably
could develop a program for the
Papergrade Sulfite subcategory.
However, EPA will consider developing
incentive programs for other
subcategories as BAT limitations are
promulgated for those subcategories.

3. The Technology Bases for the
Voluntary Advanced Technology BAT
Limitations and NSPS
   In order to determine the appropriate
Voluntary Advanced Technology BAT
limitations and NSPS, EPA first selected
a model technology for each Tier. For .
Tier I, which applies only to BAT, EPA
determined that the most appropriate
technology was extended delignification
with complete substitution of chlorine
dioxide for elemental chlorine, closing
up wastewater discharges from the fiber
line prior to bleaching, and efficient
biological wastewater treatment. EPA
selected this technology basis because it
is available today (see discussion of
BAT Option B and NSPS technology in
Section VI.B.5.(a)  and (b)), because it is
economically achievable for mills
voluntarily choosing to implement it
(see Section DC.A.6), and because it
represents an important step in the
direction of a minimum impact mill.
  The model technology for Tier n
Voluntary Advanced Technology BAT
limitations and NSPS consists of
extended delignification with complete
substitution of chlorine dioxide for
elemental chlorine, supplemented with
increased use of water conservation
practices, water reuse practices, bleach
plant filtrate recycling practices, and
efficient biological wastewater
treatment. EPA anticipates that Tier n
mills will maximize the capability of
extended delignification technology,
thereby reducing the amount of chlorine
dioxide used in bleaching. The model
Tier n mill also will have highly
effective pulping liquor spill prevention
and control and will have evaporators
that minimize the amount of black
liquor carryover, to allow for extensive
condensate reuse. EPA expects that Tier
n mills also will employ a closed fiber
line prior to bleaching improved water
reuse within the bleach plant, and will
recycle a portion of bleach plant filtrate
back through the fiber line to the
recovery'cycle. The Tier II Advanced
Technology BAT limitations and NSPS
represent the performance demonstrated
by mills that minimize effluent flow and
reduce the formation of chlorinated
organic  compounds using these
technologies and practices. Three mills
in the United States are approaching the
reduced wastewater flow levels
equivalent to Tier n, which leads EPA

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 18596	Federal Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules and Regulations
to conclude that flow reduction
technologies are emerging. Although the
flow volume projected or reported by
these mills excludes pulping area or
evaporator condensates, which EPA
includes within its Tier II flow
limitation, EPA expects that over the
next ten or eleven years condensate
reuse strategies and discharge flow
reduction technologies  will mature to
allow mills to achieve the pulping area
condensate, evaporator condensate and
bleach plant wastewater flow level
being codified today as part of Tier n.
For further discussion of EPA's rationale
for selecting this technology as the basis
for Voluntary Advanced Technology
BAT limitations and NSPS at the Tier E
level, see Section K.A.6.
  The model technology for the Tier ril
Voluntary Advanced Technology BAT
limitations and NSPS represents what
EPA believes can be achieved in 15 or
16 years by mills on the cutting edge of
minimum effluent technology. IrtEPA's
view, such mills will fully reuse
pulping area and evaporator system  ..
condensates, have a closed fiber line
prior to bleaching, and recycle the
majority of bleach plant filtrates back to
the recovery cycle. EPA expects that
these mills will also operate efficient
biological treatment systems. To achieve
this degree of mill closure, in addition
to the level of technology described
under Tier n, EPA expects the model
Tier m mill will have "kidney"
technology to remove metals from
bleach filtrate and chloride from the
mill liquor cycle, and may perform
extensive steam stripping or other
treatment of condensates to allow for
full reuse. Mills that choose to use
ozone delignification may avoid the
need for a chloride removal system. EPA
also expects that the Tier m mills will
have advanced process  control systems
and negligible losses of black liquor
through leaks and spills. Finally, the
model Tier HI mill will  likely have
extended liquid storage capacity as part
of its water recycle and liquor
management systems to help  maintain
the good hydraulic balance required for
low discharge flow operation. While no
U.S. mill today is achieving these
limitations, EPA believes that the
continuing progress being made by mills
toward closed-loop processing will lead
to greater innovation regarding
technologies and practices necessary to
achieve the Tier ffl limitations. For
further discussion of EPA's rationale for
selecting this technology as the basis for
Voluntary Advanced Technology BAT
limitations and NSPS at the Tier ffl
level, see Section K.A.6. For a more
detailed discussion of the technology
 bases for the Voluntary Advanced
 Technology BAT Limitations and NSPS,
 see Voluntary Advanced Technology
 Incentives Program Technical Support
 Document (DCN 14488).

 4. Pollutants Regulated by Voluntary
 Advanced Technology BAT and NSPS
 Limitations
   Except for TCF-based processes, each
 Advanced Technology tier consists of
 limitations for. dioxin, furan,
 chloroform,  and 12 chlorinated phenolic
 pollutants monitored at the bleach
 plant. EPA is not codifying limits for
 these pollutants for TCP processes. As
 discussed in more detail below, each
 Tier also includes AOX limitations
 monitored at the end of the pipe and,
 depending on the Tier, limitations on
 lignin content or wastewater flow. In
 addition, each BAT Tier includes
 limitations on pentachlorophenol and
 trichlorophenol (when used as
 biocides), see 40 CFR 430.24(d), and
 each NSPS Tier includes limitations on
 BOD5, TSS and pH, as well as biocides.
 See 40 CFR 430.25 (c) and (d).
   EPA has chosen to use AOX as a
 performance standard for each of the ,
 three Voluntary Advanced Technology
 BAT tiers because AOX is a measure of
 progress in reducing the total
 chlorinated organic matter in
 wastewaters resulting from the
 bleaching of pulps. In addition, the use
 of AOX rather than other measures of
 organic matter (e.g., BODs) will further
 encourage a  pollution prevention
 approach instead of end-of-pipe
 treatment technologies. The final rule
 establishes minimum monitoring
 frequencies for AOX for each of the
 Tiers, except for TCP fiber lines. See 40
 CFR 430.02(d) and (e). For TCP fiber
 lines, permit writers should determine
 the appropriate monitoring frequency to
 assure continued compliance with the
 AOX limitation.
   In addition to the AOX criterion, EPA
 is establishing BAT limitations
 requirements for Tier I that include
 kappa numbers measured prior to
 bleaching and a narrative limitation
 calling for recycling of all filtrates
 generated prior to the point at which
 that kappa number is measured. See 40
 CFR 430.24(b)(4) (i). The kappa number
 is a measure of lignin content in
 unbleached pulp, and is routinely
 determined by mills. EPA is not
 establishing minimum monitoring
 requirements for kappa numbers in this
 regulation. Permit writers maintain the
 authority to establish monitoring
 frequencies on a best professional
judgment basis.               *
  By meeting the kappa number
 limitations, Tier I mills will achieve
substantial reductions in precursors for
chlorinated organic pollutants found in
lignin beyond reductions achieved by
mills with conventional pulping
processes. See DCN 14488. Some
industry commenters suggested that
EPA simply specify qualifying
Advanced Technologies and require
participating mills to employ one or
more of those technologies in order to
receive incentives. EPA rejected this
approach because it would inhibit
development of equivalent technologies
that EPA cannot foresee today and is
inconsistent with the traditional
performance-based structure of
technology-based effluent limitations
under the Clean Water Act.
Nevertheless, EPA agrees with these
commenters that Tier I mills will in all
likelihood employ extended
delignification technologies or other
technologies that similarly reduce the
kappa number prior to bleaching; EPA,
therefore, is requiring Tier I mills to
achieve specified kappa numbers that
reflect the performance capabilities of
well-operated, extended delignification
systems. In addition, EPA's Tier I limits
reflect EPA's expectation that Tier I ,
mills will be bleaching pulps with less
lignin and,  hence, will realize
significant reductions in the amount of
unrecoverable bleaching chemicals
required to achieve their target
brightness.  By using less bleaching
chemical, Tier I mills will further
reduce the formation and discharge of
chlorinated organic pollutants generated
by bleaching pulps with chlorine-
containing compounds, including
chlorine dioxide. By recycling the
pulping area filtrates, Tier I mills also
will be implementing an important
building block for long-term f low'
reduction goals, and eliminating an
important source of weak black liquor
discharge that would otherwise go to 'the
mill's wastewater treatment plant. See
DCN 14488.
  By defining Tier I with parameter
values (AOX, kappa numbers) and
recycle requirements as presented
above, EPA intends to provide
maximum encouragement to as many
mills as possible to achieve the
performance of at least the initial
threshold of the Advanced Technology
program. Adopting threshold
performance criteria that are too
stringent could discourage mills from
making additional capital investments
beyond those necessary to achieve the
baseline BAT. This could undermine
one goal of the incentives program,
which is to achieve the greatest
environmental results possible
consistent with mills' capital

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             Federal Register/Vol. 63, No. 72/Wednesday, April  15,  1998/Rules and Regulations
                                                                     18597
 investment cycles. Conversely, setting
 threshold criteria at levels that could be
 met by some mills that comply only
 with the baseline BAT limitations and
 that do not employ Advanced
 Technologies could serve as a
 disincentive to invest in Advanced
 Technologies that achieve dramatic
 reductions in pollutant loadings and
 flow. The kappa'numbers defined above
 for Tier I, while at the upper end of the
 range of values achieved by extended
 deligriification technologies,
 nonetheless appear to separate mills
 that employ them from mills that would
 use conventional pulping technologies
 to achieve the BAT limitations. See DCN
 14488.
  EPA is setting the Voluntary
 Advanced Technology BAT limitations
 and NSPS for Tier H and Tier El based
 on a different philosophy than for Tier
 I. EPA believes that Tiers n and TO.
 should reflect a movement toward the
 long-term goal of minimizing impacts of
 mills in all environmental media
 through partially or fully closed loop
 processes. For Tier n, EPA is setting an
 AOX limit based on a long-term average
 (0.10 kg/kkg) that is currently being
 achieved by some of the best mills in
 the industry. See DCN 14488. See 40
 CFR 430.24(b)(4)(i) and 430.25(c)(2). For
 Tier ffl, EPA is setting an AOX limit
 based on a long-term average (0.05 kg/
 kkg) that is being achieved by only a
 very few mills, including one ECF mill.
 SeDCN 14488. Id.  This ECF mill
 achieved the AOX limit only with
 hardwood furnish; moreover, it did so
 without the level of flow reduction
 anticipated for Tier ffl. See DCN 14488.
 It is the Agency's judgment, based on
 trends in ECF technology development
 to date, that with recycle of pulping and
 evaporator condensates and bleach
 plant filtrates necessary to achieve a
wastewater flow of 5 m3/kkg, and
removal of chlorides from the liquor
 cycle, commensurate reductions in the
 mass of chlorinated organic pollutants
 contained in wastewaters discharged
 also are likely to occur. For this reason,
 it is EPA's judgment that the Tier ffl
AOX limit will be achievable by
advanced ECF mills for both hardwood
and softwood furnishes as well as
advanced TCP, mills.      :
  The Tier II and Tier ffl.BAT
limitations and NSPS also include
restrictions on wastewater flow and a
requirement that all pulping-area
filtrates be recycled to chemical
recovery prior to bleaching. See 40 CFR
430.24(b) (4) (i) and 43Q.25 (c) (2). As
discussed above for Tier I, the filtrates
recycle requirement is an important step
toward long-term flow reduction. Flow
reduction and progress toward closed
 loop mill operations1, in turn, are very
 important long-term environmental
 goals because pollutant releases to all
 environmental media would be
 minimized.
   While mills currently measure end-of-
 pipe flow at the point of permitted
 discharges, Tier H and Tier ffl mills will
 be required to establish and maintain
 flow measurement equipment to verify
 compliance with the annual average
 reduced flow limits for those tiers for
 bleach plant and pulping area and
 evaporator condensates. EPA is not
 establishing minimum monitoring
 frequencies for flow in this regulation.
 Permit writers maintain the authority to
 establish monitoring frequencies on a
 best professional judgment basis. See 40
 CFR 430.02.
   Review of currently available data  and
 literature indicates that the numerical
 values for flow set forth to  define Tiers
 H (10 mVkkg) and ffl.(5 itf/kkg) are
 appropriately stringent reduced flow
 targets by comparison to current
 wastewater flow for mills with extended
 delignification technologies. See DCN
 14488. EPA believes it is appropriate to
 include condensates as part of the
 specified wastewater flow volume
 because technologies are available today
 that allow for their recycle  and reuse;
 use of these technologies therefore
 ensures that the cumulative volume of
 wastewater flow is reduced to the
 greatest extent possible. See DCN 14488.
 One technology in particular is the
 "clean condensate alternative," which is
 a viable MACT compliance alternative.
 See 40 CFR 63.447. This alternative
 facilitates the segregation, treatment,
 and reuse/of condensates and thus will
 assist mills in achieving the wastewater
 flow objectives. Inclusion of pulping
 and evaporator condensates in these
 reduced flow targets therefore is
 consistent with the "clean condensate"
 MACT compliance alternative and will
 promote flow reduction through recycle
 and reuse of the greatest possible
volume of process wastewater.
  EPA has the legal authority to
 establish Advanced Technology effluent
 limitations for non-chemical
parameters, such as lignin content
 measurements and flow, and to do so
where appropriate in narrative form. For
Tier I, these limitations take the form of
kappa numbers to measure lignin
content in unbleached pulp and a
narrative requirement to recycle pulping
area filtrates; for Tiers II and ffl, they
take the form of numerical limitations
on process wastewater flows, as well  as.
the narrative requirement to recycle
pulping area filtrates. EPA has the
authority to establish limits for lignin
content in unbleached pulp, for recycle
 of filtrates, and for reduced process
 wastewater flows because each of these
 parameters functions as a restriction on
 the quantities, rates or concentrations of
 chlorinated organic pollutants and other
 pollutants in a mill's wastestream. See
 CWA Section 502(11). Restrictions on
 lignin content of unbleached pulp,
 measured as a kappa number, can be
 used to reduce the presence of
 precursors for chlorinated organic
 pollutants in a mill's wastewater. In
 addition, lignin itself is a material that
 includes polynuclear aromatic
 hydrocarbons; a number of polynuclear
 aromatic hydrocarbons are included in
 EPA's list of priority pollutants. See
 Appendix A to Part 403 (reprinted after
 40 CFR 423.17). Recycling pulping area
 filtrates to the chemical recovery cycle
 prevents the discharge of weak black
 liquor, which includes inorganic
 pulping chemicals and dissolved wood
 substances. The dissolved wood
 substances include polynuclear
 aromatic materials, degraded
 carbohydrates, low-molecular weight
 organic acids, and wood extractives •
 (resins' and fatty acids). The tbxicity of
 the materials contained in black liquor
 is well documented; see the BMP
 Technical Support Document (DCN
 14489). Limits for process wastewater
 flow, in this case pertaining to total
 pulping area and evaporator condensate
 and bleach plant wastewater, move
 mills toward closed loop operations.
 Reductions in flow will have the effect
 of dramatically reducing mass
 loadings—and discharges—of non-
 chlorinated organics such as lignin and
 a variety of chlorinated organics in
 addition to dioxin, furan and the
 chlorinated phenolic pollutants
 specifically regulated today. Because
 those pollutants are far too numerous to
 measure individually (and some have
 not been specifically isolated and
 identified), EPA determined that it was
 impracticable to set mass-based limits
 for all of those pollutants. See DCN
 14488. EPA judged that establishing
flow levels for Tiers II and ffl would be
the best way to control the discharge of
these pollutants.
  For the foregoing reasons, all of these
Advanced Technology performance
 objectives qualify as effluent limitations
under CWA section 502(11). As noted
above, the filtrates recycle limitation is
a narrative limitation. Nothing in the
definition of effluent limitation in CWA
section 502(11) or elsewhere in the
CWA compels that restrictions on the
discharge of pollutants be expressed in
numeric form. See NRDC v. Costle, 568
F.2d 1369, 1380 (D.C. Cir. 1977). In this
instance, EPA determined that the ,

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restriction on filtrates (and hence the
prevention of discharge of toxic
materials) could not be expressed as a
numeric limitation and therefore
expressed that restriction in narrative
form instead.
  For further discussion of the effluent
reductions and environmental benefits
associated with the Advanced
Technology BAT limitations and
standards promulgated for these
parameters, see DCN 14488.
5. Voluntary Advanced Technology
BAT Limitations and NSPS
  The Voluntary Advanced Technology
BAT limitations consist of three
separate components, which together
comprise BAT for the particular Tier.
See 40 CFR 430.24 (b). The first and
third components consist of numeric
effluent limitations for the pollutants
regulated by the Voluntary Advanced
Technology Incentives Program. The
second component consists of
enforceable interim milestones. Under
one set of milestones, existing
dischargers enrolled in Tiers n or HI are
required to meet interim BAT
limitations equivalent to the baseline
BAT limitations by April 15, 2004.
Under the second set of milestones,
existing dischargers enrolled in any tier
are required to meet enforceable
requirements that are developed on a
best professional judgment basis by the
permitting authority; these milestones
are expressed in either narrative or
numeric form. Taken together, these
three components constitute reasonable
further progress toward the national
goal of eliminating the discharge of all
pollutants and for this reason represent
BAT.
  The Voluntary Advanced Technology
NSPS consist of only one stage—the
ultimate performance objectives for the
Tier in question, with the addition of
conventional limitations at the baseline
NSPS level. See 40 CFR 430.25(c). This
Is because new sources, unlike existing
sources subject to BAT, must design and
construct their facilities to achieve
NSPS upon commencing operation;
sequencing limitations to achieve
continuing progress would be
inconsistent with this statutory
mandate.
  a. "Stage 1" BAT Limitations. In the
regulation, EPA has codified the first set
of numeric BAT effluent limitations as
"stage 1" limitations to be applied in
the absence of more stringent WQBELs.
See 40 CFR430.24(b)(l). Although
expressed in this regulation in narrative
form, EPA intends that the permitting
authority will express that limitation in
numeric form for each participating mill
on a case-by-case basis. The "stage 1"
                          limitations thus will be numeric values
                          on dioxin, furan, chloroform, AOX, and
                          12 chlorinated phenolic pollutants that,
                          for each pollutant, are equivalent to the
                          more stringent of either the technology-
                          based limit on that pollutant in the
                          mill's last permit or the mill's current
                          effluent quality with respect to that
                          pollutant. Id. Existing effluent quality
                          for AOX would be determined at the
                          end of the pipe based on loadings
                          attributable to that fiber line; for all
                          other pollutants covered by the
                          Advanced Technology BAT limitations,
                          such as dioxin, existing effluent quality
                          would be determined at the point where
                          the wastewater containing those
                          pollutants leaves the bleach plant. Id.
                          These "stage 1" BAT limits represent
                          the first step in the Advanced
                          Technology BAT continuum and are
                          enforceable against the participating
                          mill as soon as they are placed in the
                          mill's NPDES permit.
                            The purpose of the "stage 1" BAT
                          limits is to ensure that, at a minimum,
                          existing effluent quality is maintained
                          while the mill moves toward achieving
                          the ultimate Voluntary Advanced
                          Technology BAT performance
                          requirements for the Tier selected by the
                          mill. As Advanced Technology permits
                          are reissued for Tier n or Tier HI mills,
                          in particular, new "stage 1" limitations
                          must be established to reflect the
                          improving effluent quality of that mill.
                          Id. Allowing a mill to degrade its
                          effluent quality during development and
                          installation of Advanced Technologies
                          would be inconsistent with the statute's
                          direction that BAT limitations achieve
                          reasonable further progress toward the
                          Clean Water Act's national goals. EPA's
                          "stage 1" limitations, thus, are intended
                          to capture continuously improving
                          effluent quality.
                            EPA had considered, but rejected,
                          attempting to codify the "stage 1" limits
                          in numeric form. First, EPA has no way
                          on this record to quantify and hence
                          codify the existing effluent quality of
                          each mill that is potentially eligible to
                          participate in this program. Nor would
                          such an attempt be wise, because EPA
                          expects that mills considering
                          participating in the Voluntary Advanced
                          Technology Incentives Program will
                          continue  to improve their effluent
                          quality up to and beyond the
                          promulgation date of this regulation
                          and, most likely, up to and beyond the
                          dates that their existing effluent quality
                          is translated into enforceable permit
                          limits. Therefore, even if EPA could
                          codify such "stage 1" limitations today,
                          doing so would likely establish a less
                          stringent  technological floor than the
                          permitting authority would be able to
                          establish  each time an Advanced
Technology permit is issued prior to
achievement of the ultimate Advanced
Technology performance requirements.
  Because the "stage 1" limitations
reflect a level of technology that the mill
is already employing or that was
previously determined to be BAT for
that mill, EPA has determined that the
technology bases for the "stage 1" limits
are both technically available and
economically achievable. EPA has also
determined that they would not impose
any adverse non-water quality
environmental impacts. EPA has
determined that these "stage 1"
limitations are the "best" available
technology economically achievable for
mills participating in the Voluntary
Advanced Technology Incentives
Program because they allow those mills
to focus their resources on the research,
development, testing, and installation of
the technologies ultimately needed to
achieve the Advanced Technology
performance levels. Thus, "stage 1"
limitations reflect "reasonable further
progress toward the national goal of
eliminating the discharge of all
pollutants," as called for~by CWA
section 301 (b) (2) (A). EPA also
considered all of the other statutory
factors specified in CWA section
304 (b) (2) (B) and concluded that nothing
in EPA's analysis of those factors
justifies selecting a different set,of
"stage 1" BAT limitations. For these
reasons, EPA determined that the "stage
1" BAT limitations promulgated today
represent the appropriate first rung of
the Advanced Technology BAT ladder,
that participating mills will have
committed to ascend.
  EPA did not set "stage 1" limits at the
baseline BAT level because baseline
BAT limits are not a logical first step to
meeting the ultimate Advanced
Technology BAT limitations for the
reasons set forth below. See DCN 14488.
First, as a technical matter, mills subject
to such interim limits most likely would
need to install more chlorine dioxide
generator capacity than they ultimately
would use to achieve the Advanced
Technology performance requirements.
(EPA believes most Advanced
Technology mills ultimately will
employ complete substitution of
.chlorine dioxide for elementeil chlorine,
preceded by extended delignification
processes—a sequence that calls for
approximately 30 to 75 percent less
chlorine dioxide than a mill would use
to achieve the baseline BAT
requirements depending on the degree
of extended delignification used.)
Second, as an economic matter, interim
limitations driving a mill to over-design
its chlorine dioxide generator would  •
cause the mill to divert capital away

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 from the processes needed to achieve
 the ultimate Voluntary Advanced
 Technology BAT limitations. That
 diversion of resources undercuts one of
 EPA's principal assumptions regarding
 the economic achievability of the
 ultimate Voluntary Advanced
 Technology BAT limitations: that mills
 would be able to focus their capital and
 other resources.entirely on those
 superior performance levels. Thus, EPA
 was concerned that by compelling
 achievement of baseline BAT
 limitations as "stage 1" limitations, EPA
• would unnecessarily inflate the overall
 cost of achieving the ultimate Advanced
 Technology limitations. This would
 likely cause some mills to conclude that
 they cannot sustain the overall costs  of
 achieving the Voluntary Advanced
 Technology BAT limitations in an
 economically achievable manner. Other
 mills, in turn, might decide to absorb
 the additional costs by diverting
 resources from other environmentally ,-
 beneficial projects that they might have
 voluntarily undertaken. The Clean
 Water Act authorizes EPA to consider
 non-water quality environmental
 impacts and other factors EPA deems
 appropriate in setting BAT limitations.
 See CWA Section.304(b)(2)(B). For these
 reasons, EPA believes that compelling
 a9hievement of the baseline BAT limits
 in the first instance would have had the
 contradictory and unintended effect of
 discouraging participation in the
 program, with the result that fewer mills
 ultimately would be motivated to
 achieve superior environmental
 performance. Finally, as discussed in
 more detail below, EPA is requiring
 mills at the Tier n and Tier m levels to
 achieve interim limitations equivalent
 to baseline BAT by April 15, 2004. See  '
 40CFR430.24(b)(3).   ,
   b. Interim Milestones. As the second
 component of the Voluntary Advanced
 Technology BAT for the three Incentives
 Tiers, EPA is requiring the
 establishment of enforceable interim
 milestones. See 40 CFR 430.24(b) (2)   :
 and (3). EPA believes that interim
 milestones would incrementally benefit
 the environment during the period prior
 to achievement of the ultimate
 Advanced Technology performance
 levels and will ensure that participating
 mills make  reasonable progress toward
' achieving the superior performance
 represented by the various Advanced
 Technology BAT tiers.
   EPA is promulgating two sets of
 enforceable interim milestones. The first
 set requires mills enrolled at the Tier n
 or the Tier m level to achieve
 limitations  equivalent to baseline BAT
 limitations  by April 15, 2004. 40 CFR
 430.24(b) (3). (Mills enrolled at the Tier
 I level are required to achieve those
 limitations as well as the ultimate
 Advanced Technology limitations by
 that date. 40 CFR 430.24(b) (3) and (4)0
 EPA believes that this is a reasonable
 requirement not only because it ensures
.significant environmental progress
 consistent with CWA section 30 1 (b) (2) ,
 but it also reflects the technology
 performance Tier n and Tier IE mills are
 likely to be achieving by that date. Mills
 enrolled in Tier n and Tier m are
 expected to substantially modify
 pulping and bleaching processes (e.g.,
 install extended delignification, ECF, or
 TCP bleaching) to comply with the
 Advanced Technology limitations. EPA
 expects that all Tier n or Tier HI mills
 will install extended delignification and
 complete substitution (ECF) or TCP
 bleaching processes well in advance of
 achieving their wastewater flow
 objectives in order to allow sufficient '
 time to design, install, test and adjust
 their other flow-related processes. In
 EPA's judgment, process changes
 sufficient to achieve baseline BAT
 limitations will occur by April 15, 2004.
 Once these processes are  installed, the
 mill will be achieving or exceeding the
 baseline BAT limitations being required
 by that date. See DCN 14488.
   EPA notes that mills required to
 achieve water quality-based or other
 effluent limitations equivalent to one or
 more of the Voluntary Advanced
 Technology BAT limitations are still
 eligible to enroll in the Voluntary
 Advanced Technology Incentives
 Program and to receive incentives for
 achieving the remaining Voluntary  ,
 Advanced Technology limitations.
 However, the time for complying with
 water quality-based or other equivalent
 effluent limitations would be
 determined by applicable law, not by
. this Voluntary Advanced Technology
 Incentives Program. Therefore, for
 example, if a mill's NPDES permit
 compels immediate compliance with a
 dioxin limitation equivalent to the
 Voluntary Advanced (BAT) Technology
 limitation on dioxin because of water
 quality concerns or other requirements
 of state or federal law, this six-year
 milestone would not be available for
 that dioxin limitation. See' CWA section
   The second set of enforceable interim
 milestones promulgated today applies to
 all mills enrolled in the Advanced
 Technology Incentives Program.
 Although today's rule leaves the type
 and frequency of these milestones to the
 permit writer's best professional
 judgment, see 40 CFR 430.24(b)(2),
 milestones should include intermediate
 pollutant load and wastewater flow
 reductions (for Tier H and Tier m mills)
in addition to research schedules,
construction schedules, mill trial
schedules, or other milestones
appropriate to the advanced technology
and the participating mill. Interim
milestones should be tailored to
circumstances and process technologies
at individual mills.
  In order to facilitate the development
of appropriate interim milestones on a
case-by-case basis, EPA proposes
elsewhere in today's Federal Register to
require all mills enrolling in the
incentives program to submit plans
detailing the strategy the mill will
follow to develop and implement the
technology required to achieve the
chosen incentive tier, as well as the
interim numeric limitations for Tiers II;
and HI. The plan should describe each
envisioned new technology component
or process modification the mill will
need to achieve the Voluntary
Advanced Technology BAT limits. A
master schedule should be included in
the plan showing the sequence of
implementing the new technologies and
process modifications and identifying
critical path relationships within the
sequence. For each individual
technology or process modification, a
schedule should be provided that lists
the anticipated date that associated
construction, installation, or process
Changes will be initiated,  the
anticipated date that those steps will be
completed, and the anticipated date that
the full Advanced Technology process
or individual component will be fully
operational. For those technologies or
process modifications that are not  .
commercially available or demonstrated
on a full scale basis at the time the plan
is developed, the plan should include a
schedule for research (if necessary),
process development, and mill trials.
The schedule for research, process
development, and mill trials should
show major milestone dates and the
anticipated date the technology or
process change will be available for mill
implementation. The plan also would
need to include contingency plans in
the event that any of the technologies or
processes specified in the Milestones
Plan need to be adjusted or alternative
approaches developed to ensure that the
ultimate tier limits are achieved by the
dates in the master schedule. EPA
expects the permitting authority to use
the information contained in those
plans, as well as its own best.
professional judgment, to establish
enforceable interim milestones applying
all statutory factors. EPA also expects
permit writers to include reopener
clauses in the permits to adjust these
milestones including dates to reflect the

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results of research (if necessary), process
development, and mill trials.
  Section 402(a) of the Clean Water Act
authorizes permit writers to establish
permit conditions and limitations on the
basis of best professional judgment as
necessary to achieve the objectives of
the Act. Altiiough EPA is promulgating
BAT limitations under CWA sections
301 and 304, EPA is not—nor could it
today—codify the particular process
development, construction, and testing
milestones that will lead each
participating mill to achieve the
ultimate Voluntary Advanced
Technology performance requirements.
Identifying those milestones is best left
to the judgment of the permit writer,
who will have access to far more mill-
specific information than EPA has
today.
  c. "Stage 2" limitations. The third
component of the Voluntary Advanced
Technology BAT limitations consists of
the "stage 2" limitations. See 40 CFR
430.24(b)(4)(i). These are the only
standards applicable to Voluntary
Advanced Technology NSPS and must
be achieved upon commencing
operation. See 40 CFR 430.25 (c). Also
included in the Voluntary Advanced
Technology NSPS are standards for
dtodn, furan, chloroform, 12
chlorinated phenolic compounds. BODs,
TSS, and pH at the baseline NSPS level.
See 40 CFR 430.25(c)(l). In addition,
standards for pentachlorophenol and
trichlorophenol, when used as biocides,
are part of the Voluntary Advanced
Technology NSPS. See 40 CFR
430.25(d).
  These limitations and standards
represent the ultimate performance
requirements for each Tier. The "stage
2" limitations are as follows:
  (1) Tier I Voluntary Advanced
Technology BAT Limitations ("stage
2"). For Tier I, the ultimate performance
requirement for AOX is a long-term
average (LTA) of 0.26 kg/kkg, measured
at the end of the pipe. 40 CFR
430.24(b)(4)(i). Under this Tier,
Advanced Technology fiber lines at
participating mills must also achieve
reduced lignin content in unbleached
pulps as measured by a kappa number
of 20 for softwoods and 13 for
hardwoods and reported as an annual
average. Id. Finally, Tier I Advanced
Technology fiber lines must recycle to
recovery systems all filtrates up to the
point at which the unbleached pulp
kappa numbers are measured (e.g.,
brownstock into bleaching). Tier I also
includes limitations for dioxin, furan,
chloroform and 12 chlorinated phenolic
pollutants, see 40 CFR 430.24(b)(3).
Limitations on these parameters are
established at the baseline BAT levels
                          because application of Advanced  .
                          Technologies does not appear on this
                          record to justify more stringent
                          limitations.
                            (2) Tier n Voluntary Advanced
                          Technology BAT Limitations ("stage 2")
                          and NSPS. For Tier H, the ultimate.
                          performance  requirement for AOX is an
                          LTA of less than 0.10 kg/kkg, measured
                          at the end of  the pipe. 40 CFR
                          430.24(b)(4)(i) and 430.25(c)(2). In
                          addition, Tier n Advanced Technology
                          fiber lines must recycle to chemical
                          recovery systems all pulping-area
                          filtrates prior to bleaching. Id. Finally,
                          Tier n Advanced Technology fiber lines
                          must also achieve total pulping area
                          condensate, evaporator condensate, and
                          bleach plant wastewater flow of 10 m3/
                          kkg or less reported as an annual
                          average. Id. Tier n mills must also meet
                          (or, in the case of existing dischargers;
                          must continue to meet) limitations for
                          dioxin,  furan, chloroform, and the  12
                          chlorinated phenolic pollutants. See 40
                          CFR 430.24(b)(3) and 430.25(c)(l).
                          Application of the Tier n Technologies
                          does not appear to justify more stringent
                          limitations for these parameters.
                            (3) Tier m Voluntary Advanced
                          Technology BAT Limitations ("stage 2")
                          and NSPS. For Tier m. the ultimate
                          performance  requirement for AOX is an
                          LTA of less than 0.05 kg/kkg, measured
                          at the end of the pipe. See 40 CFR
                          430.24(b)(4)(i) and 430.25(c)(2). In
                          addition, Tier m Advanced Technology
                          fiber lines must recycle to chemical
                          recovery systems all pulping-area
                          filtrates prior to bleaching. Id. Finally,
                          Tier m Advanced Technology fiber lines
                          must also achieve total pulping area
                          condensate, evaporator condensate, and
                          bleach plant wastewater flow of 5 m3/
                          kkg or less reported as an annual
                          average. Id. Tier m mills must also meet
                          (or, in the case of existing dischargers,
                          must continue to meet) limitations for
                          dioxin,  furan, chloroform, and the  12
                          chlorinated phenolic pollutants. See 40
                          CFR430.24(b)(3) and 430.25 (c)(l).
                          Application of the Tier m Technologies
                          does not appear to justify more stringent
                          limitations for these parameters.
                           d. Voluntary Advanced Technology
                          BAT Limitations and NSPS for Mills
                          Employing TCP Processes. In order to
                          encourage mills to employ Advanced
                          Technologies founded on TCF
                          processes, EPA is opening today's
                          incentives program to fiber lines that
                          employ or commit to employ such
                          processes. Existing dischargers that
                          choose to employ TCF processes are
                          subject to the "stage 1" limitations,
                          interim milestones (including the
                          baseline BAT limitations), and the
                          "stage 2" limitations  applicable to the
                          selected tier.  40 CFR 430.24(b) and
430.25 (c). These limitations are
discussed above. However, recently
gathered data from TCF mills indicate
that all TCF mills will be able to achieve
the AOX performance requirements at
any Tier level because end-of-pipe AOX
levels are being reported at below
minimum level. See DCN  14488.
Consequently, the AOX limitations for
TCF fiber lines are expressed as "
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             Federal Register/Vol.  63,  No. 72/Wednesday, April 15, 1998/Rules and  Regulations
                                                                    18601
 Voluntary Advanced Technology
 Incentives Program, call for   ,
 environmental performance far in
 excess of the'performance compelled by
 the baseline BAT.
  EPA chose the parameters and
^limitations unique to the Voluntary
 Advanced Technology Incentives
 Program because they reflect the levels
 of performance EPA believes can be
 achieved over time by mills willing and
 able to invest the resources to develop
 and apply the corresponding Advanced
 Technology processes and practices.
 The Tier I technology is available today
 and does not impose significant non-
 water quality environmental impacts; it
 was not selected as the baseline BAT
 technology because it is not
 economically achievable for the
 subcategory as a whole or any segment
 as is discernible from the record
 available today. See Section VI.B.5.a(5).
 However, for mills willing and able to
 employ that technology, EPA believes
 that limitations based on extended
 delignification, complete substitution,
 and other processes would be
 economically achievable by the year
 2003. EPA believes that the technology
 bases for Tier n, in turn, could be
 technically and economically
 achievable for mills willing to
 participate by the year 2008, and would
 not impose significant non-water quality
 environmental impacts. EPA bases its
 view on the experience of at least three
 U.S. mills that are moving in the
 direction of reduced bleach plant flow.
 See DCN 14488. None of these mills,
 however, is presently achieving the
 "stage 2" flow limits for Tier n because
 those limits include pulping area and
 evaporator coridensate as well as bleach
 plant wastewater flow. Finally, with
 respect to Tier.in, EPA notes that one
 mill in Finland today is achieving flow
 levels close to 5 m3/kkg or less,
 although this mill's flow rates also
 exclude condensates. This mill is able to
 achieve its, current level of performance
 without imposing significant non-water
 quality environmental impacts. In
 addition, mills choosing Tier HI will
 have up to 16 years, and considerable
 flexibility to develop and implement
 appropriate flow control strategies. (For
 a discussion of the timeframes
 associated with achieving the Voluntary
 Advanced Technology BAT Limitations,
 see Section IX.A.7.) While EPA
 recognizes that achievement of the
 "stage 2" limits for Tier m may call for
 considerable creativity and innovation
 by industry participants, EPA believes
 that such spurs to innovation are
 consistent with the Clean Water Act's
 ultimate goal of eliminating the
discharge of pollutants. Finally, EPA
emphasizes that participation in the
Advanced Technology Incentives
Program is purely voluntary-. No mill in
the Bleached Papergrade Kraft and Soda
subcategory is required to commit to
achieve the Voluntary Advanced
Technology BAT limitations at any  '
level.                  •
  The voluntary nature of the Advanced
Technology Incentives Program also
supports EPA's finding that the "stage
2" BAT limitations for the various .
Incentives Tiers will be economically
achievable by the dates specified in the
rule for the mills choosing to achieve
them. See 40 CFR 430.24(b)(4)(ii). The
' 'stage 2" limitations apply only to mills
that designate themselves as Tier I, Tier
n or Tier HI Advanced Technology
performers and that voluntarily accept
the corresponding "stage 2" limits in
their NPDES permits. In other words,
the "stage 2" limitations are BAT for an
Advanced Technology mill only
because that mill announces, by
choosing to participate in the Program
and by its choice, of Tier, that by the
date specified in the rule for the
applicable "stage 2" limits a technology
will be both available and economically
achievable for the purpose of achieving
those limitations. Based on the
experiences of mills that have
voluntarily pursued performance levels
comparable to the "stage 2" limitations
of Tiers I and H, EPA believes that a mill
choosing to pursue those objectives can
do so within its economic capability.
Therefore, EPA believes it is reasonable
to presume that a mill would not subject
itself to enforceable technology-based
limits if achievement of those limits
would exceed the mill's economic
capability. Because the economic
achievability of the "stage 2" limitations
ultimately is evaluated according to the
mill's own choices, EPA concludes that
the "stage 2" limitations are
economically achievable. In addition,
while implementation of these
Advanced Technologies today is beyond
the economic capabilities of many mills
because of the significant capital   .
investments that can be incurred at the
outset, EPA believes that a mill able to
plan for these investments over time
could reduce those investment costs to
some extent, if only by minimizing the
amount of capital the mill would need
to borrow. Moreover,  with additional
time mills will inevitably find ways to
implement these technologies that  ,
reduce costs. More  importantly, it could
make these environmental
improvements in sequence with other
business decisions related to capital
investment, thus reducing the overall
 cost of installing the Advanced        »
 Technologies. Although on this record
 EPA cannot state with confidence what
 the cost of implementing these
 Advanced Technologies would be if
 spread over time (and hence cannot
 make an economic achievability finding
 for the subcategory as a whole or any
 discernible segment relating to those
 Advanced Technologies), EPA
 nevertheless believes that each mill is
 capable of making that judgment and
 assuming the corresponding economic
 risks. This Voluntary Advanced
 Technology Incentives.Program thus
 establishes a structure by which mills
 willing to predict their economic
 fortunes over the next several years and
 to commit to enforceable permit limits
 based on that prediction can do so.
  EPA has considerable discretion
 under CWA section 304 (b) (2) to
 determine whether and when a
 particular technology or process is BAT.
 EPA also has broad authority to
 interpret CWA section 301. In E.I. du
 Pont de-Nemours & Co. v. Train, 430
 U.S. 112 (1977), the Supreme Court
 accorded great deference to EPA in
 promulgating effluent limitations
 guidelines as regulations under section
 301, noting that'' [CWA Section] 101 (d)
, requires us to resolve any ambiguity on
 this score in favor of the
 Administrator." Id. at 128. The Supreme
 Court also found that section 501 (a) .
 supports EPA's broad use of its
 regulatory authority to implement
 section 301. Id. at 132. EPA believes that
 its  decision to promulgate Voluntary
 Advanced Technology BAT limitations
 is authorized by sections 301 and 304.
 Section 301 (b) (2) in particular directs .
 EPA to promulgate BAT limitations that,
 within the constraints of economic
 achievability, "will result in reasonable
 further progress toward the national
 goal of eliminating the discharge of all
 pollutants.'' Section 301 (b) (2) (A). In
 addition, both case law and the
 legislative history interpreting the BAT
 program make it clear that the statute is
 to be used to force technology, within
 the constraints imposed by sections
 301 (b)(2) and 304(b)(2). Promulgation of
 regulations to promote the use of
 Advanced Technologies and, hence,,
 progress toward the elimination of
 pollutant discharges thus is within the
 scope  of the Administrator's 501 (a)
 authorities. See Cleveland Electric
 Illuminating Co. v. EPA, 603 F.2d 1, 6
 (6th Cir. 1979) ("The ultimate
 justification for every regulation and
 guideline pertaining to discharges is its
 effectiveness in promoting the
 achievement of the goals of Congress in
 enacting the 1972 Amendments.")

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18602      Federal Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules and Regulations
  As part of its BAT analysis. EPA
performed a case-study analysis to
determine the potential effluent
reduction benefits derived from the
incentives program. Effluent reductions
were calculated for a hypothetical case-
study mill complying with Voluntary
 Advanced Technology BAT limitations
 at each incentive Tier. This case study
 is discussed in more detail at DCN
 14488. The 1000 metric ton-per-day
 case-study mill operates a softwood and
 a hardwood bleach line of equal size,
 and uses a conventional three-stage
bleach sequence with chlorine on each
line. Table IX-1 presents effluent load
reductions from that case-study mill,
calculated for the baseline BAT (BAT
Option A) as well as each incentive
Tier.
                         TABLE IX-1.—EFFLUENT LOAD REDUCTIONS FOR CASE STUDY MILL
Pollutant
AOX 	
BOD5 	
COD 	
Color 	
Chloroform 	 	
TCDD&TCDF 	
12 Chlorinated Phenolics 	
, Units
kkq/yr . ..
kko/yr
KkO/yr
kko/vr . ..
ko/vr ... .
g/yr 	
kko/vr 	
Baseline
BAT >.
Technology
670
290
6000
2,000
290
49
1.000
Tier I
770
440
11 000
15000
290
49
1.100
Tier II
830
720
13 000
30000
290
50
1 .200
Tier III
840
870
18 000
34 000
290
50
1.200
  Note that for all levels, TCDD, TCDF, chloroform and the 12 chlorinated phenolics will not be detected in the final effluent. The differences be-
tween the levels are the result of technologies employed to reduce discharge flow rates under the incentive Tiers.
  In selecting the technology basis for
each of the Incentives Tiers, EPA also
evaluated the associated non-water
quality environmental impacts, changes
in energy requirements, the age of
facilities and equipment involved,  the
process used, and the engineering
aspects of various types of control
techniques and process changes. See
DCN 14488. Nothing in EPA's analysis
of these factors justified selecting
different BAT technologies than those
identified in section TX.a.3. EPA found
that the technologies that form the  basis
of the Incentives Tiers provide a
significant degree of water conservation,
particularly at Voluntary Advanced
Technology Tiers H and EL EPA also
expects lower secondary sludge
generation rates at Incentives Tier mills
with activated sludge treatment because
of reduction in BODs loads associated
with the Advanced Technologies. The
technology basis of each of the
Incentives Tiers will lead to overall
decreases in energy consumption,
primarily because of replacement of
chlorine dioxide with oxygen-based
delignification and bleaching chemicals.
EPA expects a slight increase in air
emissions (<2 percent) due to increased
recovery of black liquor that will occur
under the Incentives Tiers. However,
these are offset by reductions in air
pollution that derive from the
reductions in overall energy
consumption.
  EPA considered the potential for
cross-media transfer of pollutants
through implementation of the
Advanced Technologies that form the •
basis of the Incentives Tiers. EPA found
no basis to conclude that cross-media
transfer of pollutants would occur. See
DCN 14488 and DCN 14492. However,
 much of the Tier E and Tier m
 technology bases focus on closing mill
 process cycles, which has not yet been
 fully demonstrated. As these
 technologies are fully developed and
 implemented, sufficient engineering
 analyses and testing should be
 performed to assess whether
 unacceptable cross media transfer of
 pollutants are occurring, and whether
 modifications need to be made to avoid
 any unacceptable transfers identified.  '
   For NSPS, EPA has determined that
 Tier n and Tier m technologies
 constitute the  best demonstrated control
 technologies for mills enrolling in those
 tiers. Although EPA cannot say today
 that either of these technology
 sequences is the best demonstrated
 control technology for new sources in
• the Bleached Papergrade Kraft and Soda
 subcategory as a whole, EPA does
 believe that new sources emerging
 within the next 16 years may
 characterize them as such based on their
 own sense of their economic and
 technical  capabilities. Therefore, as with
 existing sources, EPA is promulgating
 this additional array of NSPS in order to
 provide such mills the opportunity to
 pursue voluntarily pollution prevention
 technologies—and to accept
 correspondingly more stringent effluent
 limitations—if business circumstances
 warrant. EPA notes that a mill
 subjecting itself to the Advanced
 Technology NSPS will be shielded from
 more stringent technology-based
 effluent limitations for ten years
 beginning on the date that construction
 is completed. See CWA section 306(d).
 Because these standards are entirely
 voluntary, their promulgation today
 presents no barrier to entry. In addition,
 EPA has determined that achievement
of these standards will not result in any
significant non-water quality
environmental impacts or significant
additional energy requirements. See
DCN 14488. Nothing in EPA's analysis
of the other statutory factors applicable
to NSPS justified selecting different
NSPS technologies.
  EPA also believes it is appropriate to
promulgate limitations for all three
Tiers at the same time it promulgates
the baseline BAT limitations. (The same
rationale applies for today's Voluntary
Advanced Technology NSPS.) By
promulgating all three Voluntary
Advanced Technology BAT Tiers today,
rather than in five-year increments, EPA
hopes to encourage as many mills as
possible to develop and install
Advanced Technologies. On this record,
EPA has determined that its customary
practice of promulgating a single BAT
for similarly situated mills—represented
here by the baseline BAT limitations—
would have the unintended effect of
impeding some mills' progress toward
even greater environmental objectives
than EPA can compel at this time. Thus,
if EPA were to promulgate only baseline
BAT limitations today and not establish
a parallel track for mills converting to
Advanced Technologies, EPA is
concerned that mills might abandon
their voluntary long-term strategies of
superior environmental performance in
favor of compulsory short-term
compliance strategies focused on 'the
baseline BAT. Instead, by promulgating
Voluntary Advanced Technology BAT
limitations at the same time as baseline
BAT limitations, EPA allows interested
mills to consider all technology options
at the outset before they make their
investment decisions  and to design and
install precisely the technologies and

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             Federal Register/Vol. ^3. No. 72/Wednesday,  April 15, 1998/Rules and Regulations      18603
 processes they, will need to meet their
 long-term Advanced Technology
 objectives. Therefore, EPA has decided
 to promulgate all of the Voluntary
 Advanced Technology BAT limitations
 today in order to provide mills with an
 opportunity to push their environmental
 performance beyond the minimum
 prescribed by the baseline BAT and on
 toward the statutory goal of zero
 discharge. Promulgating the various
 Voluntary Advanced Technology Tiers
 today rather than in five-year
 increments also provides some
 predictability regarding the progress
 expected of Advanced Technology mills
 over time. EPA hopes that this
 predictability will encourage greater
 participation in the program and thus
 lead to superior effluent quality. Finally,
 promulgating all three Tiers of
 Advanced Technology BAT Limitations
 today makes sense because it reflects
 EPA's regulatory approach for
 promoting successively greater
 environmental achievements for this
 industry, and because companies
 willing'to commit to achieve the
 increased environmental controls will
 be able to avoid the uncertainties
 inherent in a succession of later
 rulemakings.
  EPA has the authority to promulgate
 the three Tiers of Voluntary Advanced
 Technology BAT limitations today even
 though their ultimate performance
 requirements will not be attained until
 a future date. EPA has the authority
 under CWA section 304(b) (2) and
 304 (m) to revise the baseline BAT
 limitations for the Bleached Papergrade
 Kraft and Soda subcategory whenever
 the Administrator deems it is        '
 appropriate. Thus, EPA would be free in
 5, 10 or 15 years to codify the Voluntary
 Advanced Technology limitations as
 BAT. However, by then, mills
 potentially interested in pursuing
 Advanced Technologies would already
 have been required to meet baseline
 BAT limitations, perhaps using
 technologies not fully compatible with
 more advanced processes. The costs of
retrofitting, or in some cases replacing,
newly installed process technologies to
 achieve more stringent limits might
 prevent EPA from finding that these
technologies are economically
achievable. In addition, participating
mills would lose a long-term planning
horizon, which is very important
because of the significant capital outlays
involved. As a result, EPA was
concerned that failure to promulgate
these Voluntary Advanced Technology
BAT limitations today might
compromise future pollution prevention
opportunities. EPA is authorized to
 consider those opportunities when
 promulgating BAT limitations. EPA
 therefore believes it is appropriate to
 consider these barriers to pollution
 prevention as factors relevant to the
 definition of BAT limitations and the
 timing of their promulgation, see CWA .
 section 304 (b) (2) (B); especially since
 failure to promulgate a Voluntary
 Advanced Technology Incentives
 Program at this time might impede •
 reasonable further progress toward the
 national goal of eliminating discharges
 of all pollutants. See CWA section
 301(b)(2).
  An important component of this
 incentives program is the element of
 choice. Direct discharging mills subject
 to Subpart B may choose whether to
 enroll in the program and, once
 enrolled, may choose the Tier, or
 performance level, that they will
 achieve. In order to codify this
 structure, EPA has promulgated three
 sets of Voluntary Advanced Technology
 BAT limitations for bleached
 papergrade kraft and soda mills and two
 sets of NSPS in addition to the baseline
 BAT and NSPS. In effect, EPA has
 divided Subpart B into segments based
 on the types of bleach plant processes
 mills choose to employ. EPA has
 considerable authority to establish
 segments within an industrial
 subcategory for the purpose of
 promulgating BAT limitations unique to
 those mills. Much like mill-specific
 variances based on fundamentally
 different factors, segments reflect EPA's
 authority to take into account the
 diversity within each industry. See
 Chemical Mrfs. Ass'n v. NRDC,  470 U.S.
 116, 130, 105 S.Ct 1102,  1110 (1985).
 Thus, segmentation, like variances,, is
 not an exception to the standard-setting
 process, but rather a more fine-tuned
 application of it. Id.
  For BAT, EPA has essentially
 established four segments for the
 Bleached.Papergrade Kraft and Soda
 subcategory  (and, similarly, three  •
 segments for NSPS). One segment
 codifies the baseline BAT limitations;
 the other three segments codify Tiers I,
 H and HI of the Voluntary Advanced
 Technology BAT Incentives Program.
 EPA defined the Advanced Technology
 segments to reflect the various types of
 process changes and control techniques
 that mills might employ to achieve
 environmental performance beyond the
 baseline BAT level. The Advanced
Technology segments also reflect the
 cost of achieving progressively greater
 environmental effluent reductions. Any
 one'of those  factors is sufficient under
 CWA section 304(b)(2) to justify a
segment for affected mills. Each mill in
Subpart B must comply with the
 baseline BAT limitations unless it
 designates itself as an Advanced
 Technology mill, in which case it must
 meet the BAT limitations corresponding
 to the Tier—and segment—it chooses.
  Although EPA has identified an array
 of process changes that, if employed,
 could distinguish one Subpart B mill
 from another and.has based its
 Advanced Technology limitations on
 those potential changes, EPA has made
 the Advanced Technology segments
 voluntary. This is because the decision
 whether Advanced Technologyjwocess
 changes are technically feasible and
 economically achievable for a particular
 mill depends on many factors unique to
 that mill that EPA, on the record
 available today, cannot readily discern
 or forecast. Among the more significant
 factors appear to be the mill's current
 bleaching sequence, the physical
 configuration of equipment, the age of
 equipment (and, thus, end-of-life
 issues), the available capacity in
 chlorine dioxide generation and in the
 recovery boiler, arid whether the mill
 uses hardwood or softwood.  See DCN
 14488. See also Paper Task Force,
 Technical Supplement White Papers,
 Record section 20.2.8, DCN 14794, DCN
 14795, and DCN 14796.
  EPA also has important policy reasons
 for .making the Advanced Technology
 BAT limitations voluntary, both in
 terms of the decision to participate and
 in terms of the level of environmental
 performance to be achieved. As
 discussed in greater detail above, EPA .
 believes that mills willing and able to
 employ technologies and processes
 superior to the "baseline" promulgated
 as BAT—and willing to guarantee that
 effort in the form of enforceable
technology-based permit limitations—
should have the opportunity to do so.
By giving mills a choice to exceed
baseline compliance levels, EPA
 implements CWA section 301 (b) (2) 's
direction that BAT limitations "result in
reasonable further progress toward the
national goal of eliminating the
discharge of all pollutants," to the
extent consistent with EPA's findings of
economic achievability, among other
factors. By allowing mills to choose
between baseline BAT limitations and
Voluntary Advanced Technology BAT
limitations at the outset, EPA also wants
to encourage mills to consider all
possible process configurations before'
investing in the baseline BAT
technology. Thus, by codifying multiple
expressions of BAT, EPA has
established a regulatory mechanism that
allows mills to choose greater
environmental performance than EPA
could require on this record and also
authorizes permit writers to

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18604      Federal Register/Vol. 63, No. 72/Wednesday .April 15, 1998/Rules and Regulations
memorialize that choice in the form of
enforceable permit limits.
  Although applied here for the first
time to codify a Voluntary Advanced
Technology incentives Program, the
notion of using segmentation to
determine applicable technology-based
limitations is not new. Indeed, effluent
limitations guidelines and standards
routinely base applicability of
technology-based limitations on a
discharger's particular process or,
treatment technologies. For example,
elsewhere in today's rule EPA is
segmenting the Papergrade Sulfite
subcategory to reflect, among other
things, the type of product the mill
produces. Thus, a papergrade sulfite
mill choosing to produce specialty
products subjects itself to a different set
of limitations than other mills in its
subcategory simply by making that
business decision. EPA also used
segmentation to account for different
treatment configurations when it
promulgated BAT for the organic
chemicals, plastics and synthetic fibers
category. See 40 CFR 414.91, 414.101;
58 FR36872,36881-85 (July 9,1993).
In that rule, EPA established two sets of
BAT limitations for a subcategory of
plants, one set applicable to plants
using end-of-pipe biological treatment
and the other set applicable to plants
using some other treatment technology,
including in-plant waste management
practices. In this rule, the Advanced
Technology segments are intended to
anticipate a mill's business decision to
change its cooking, washing, bleaching,
wastewater recycle, and recovery ,
processes to achieve greater pollutant
reductions than EPA can require as
baseline BAT.  Indeed, by establishing
these segments. EPA hopes to encourage
many mills to choose Advanced
Technologies,  especially those mills that
would need to change their bleaching
and washing processes in any event to
comply with the baseline BAT.
  EPA also notes that it could have
accomplished  the same result for
existing sources on a case-by-case basis
through the Clean Water Act's variance
processes. See Chemical Mrfs. Ass'n v.
NPDC, 470 U.S. at 130,105 S.Ct at 1110.
Advanced Technology mills could have
sought fundamentally different factors
variances under CWA section 301(n); for
non-conventional pollutants, these mills
could have pursued a variance under
section 301(c). Under either section,
mills could have obtained BAT effluent
limitations that are more or less
stringent than the baseline BAT. See
Chemical Mrfs. Ass'n v. NRDC, 470 U.S.
at 116,105 S.Ct at 1105-06 (PDF
variances); EPA v. National Crushed
Stone Ass'n, 449 U.S. 64, 79 n.18 (1980)
(§301(c) variances). However, EPA
rejected implementing the Voluntary
Advanced Technology Incentives
Program through variances for several
reasons. First, the Clean Water Act and
its legislative history indicate a clear
Congressional preference for the use of
subcategories, rather than variances, to
address discernible differences among
regulated entities. By requiring
applications for FDF variances to be
based on information submitted during
the rulemaking process (unless the
applicant lacked a reasonable
opportunity to make such submission),
see section 301 (n) (1) (B), Congress
stressed the need for companies to
participate fully in the guideline
development process to assure that
adequate information is available to
EPA to develop  appropriate
subcategories. See 131 Cong. Rec. S
8013 (June 12, 1985) (Sen. Bentsen); see
also 133 Cong. Rec. H 131,136-37 (Jan.
7,1987) (Rep. Howard) (provision
assures that effluent guidelines "are as
comprehensive  as possible"); 133 Cong.
Rec. S 733, 739  (Jan. 14, 1987) (Sen..
Mitchell) (EPA should accommodate
fundamental differences among
facilities through the establishment of
subcategories). In this rulemaking, many
commenters supplied vast amounts of
information concerning the special
circumstances of facilities aspiring to
become minimum impact mills. As
Congress intended, EPA established the
three Voluntary Advanced Technology
segments in response to that
information rather than deferring
consideration of the issue to the post-
rulemaking variance process.
  Second, as a matter of policy, EPA
believes it is reasonable to employ its
subcategorization, rather than its
variance, authority to implement the
Voluntary Advanced Technology
Incentives Program. By establishing the
Voluntary Advanced Technology BAT
limitations by rulemaking at the same
time it codifies  the baseline BAT
limitations, EPA intends to provide all
direct discharging mills within Subpart
.B the immediate opportunity to push
beyond base level environmental
performance and also to provide with
certainty regarding the stringency and
timing of the limits they would be
expected to meet. In this way, EPA
hopes to encourage many mills to
participate in the program. Use of case-
by-case variance procedures, in contrast,
would introduce delay and uncertainty
into the process, which EPA believes
would discourage industry
participation.
   In summary,  EPA has discretion in
determining whether to account for
industry characteristics through
subcategorization or through the
variance process. Like variances, the
Voluntary Advanced Technology
segments apply only to mills that on
their own initiative seek different BAT
limitations. Unlike variances, however,
the subcategorization scheme
promulgated by EPA assures consistent
and timely implementation of the
Voluntary Advanced Technology
Incentives Program, which EPA believes
is critical to its success. Therefore, for
the reasons explained, EPA's decision to
subcategorize Subpart B was rational
and within  its discretion..

7. Time Frames for Achieving Voluntary
Advanced Technology BAT Limitations

  In order to promote the pollution
prevention  objectives of the Voluntary
Advanced Technology Incentives
Program, EPA has determined, that
existing mills choosing to participate in
that program should receive a
reasonable amount of time to achieve
the Advanced Tier performance levels
they select. See 40 CFR 430.24(b)(4)(ii).
CThese performance levels are codified
in this rule  as "stage 2" BAT
limitations.) The extended timeframes
discussed below are not available for
new sources enrolled in the Advanced
Technology Incentives Program because
the Clean Water Act requires new
sources to comply with applicable NSPS
upon commencing operation. CWA
Section 306 (e). However, new sources
interested in participating in the
Voluntary Advanced Technology
Incentives Program after commencing
operation may nevertheless do so, for
example, by achieving the baseline
NSPS requirements at the time
discharges commence and later
installing additional technologies
necessary to achieve the more stringent
AOX and flow requirements of Tiers n
or ffi. Once limitations equivalent to the
selected advanced Tier performance
levels are placed in the mill's permit
and the mill achieves those limits, it is
eligible to receive the regulatory and
enforcement relief described as
incentives in Section IX.B. below.
  EPA has  determined that reasonable
dates by which existing sources can
achieve Advanced Technology
performance requirements are [April 15,
2004] for Tier I, April 15, 2009 for Tier
n, and April 15,  2014 for Tier in. See
40 CFR430.24(b)(4)(ii). As discussed in
more detail below, these dates assume
an initial start-up year during which
mills subject to Subpart B would decide
whether to enroll in the Voluntary
Advanced Technology Incentives
Program and develop a plan for
complying with the ultimate incentives

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              Federal Register/Vol. 63, No.  72/Wednesday,  April 15, 1998/Rules and Regulations      18605
  BAT limitations. The remaining
  additional time, calculated as 5 years for
  Tier I, 10 years for Tier n, and 15 years
  for Tier m, corresponds to the time EPA
  believes a mill would need in order to
  arrange its financing and to develop,
  install, test, and implement the chosen
  Advanced Technologies at full scale to .
  comply with the ultimate tier limits.
    EPA regards five years as a reasonable
  time frame to achieve the Voluntary
  Advanced Technology BAT limitations
  corresponding to Tier I (including the
  bleach plant BAT effluent limitations).
  When spread over five years, the capital
  costs of those technologies become more
  manageable (although they are still
  significantly higher than the capital
  costs associated with the baseline BAT).
  In addition, the five year period gives
  mills increased flexibility to schedule
  the significant capital investment within
  the mill's normal capital investment
  cycle, i.e., to purchase and install the
  necessary equipment when capital is
  available. Therefore, EPA believes the
  five year period will enable mills to
  participate in the Voluntary Advanced
  Technology Incentives Program that
  otherwise might not have the financial
  resources to make the necessary capital
  investment.
    EPA regards ten years as a reasonable
  timeframe to achieve the Voluntary
  Advanced Technology BAT limitations
  corresponding to Tier n because the
  development and implementation of
  technologies to reduce bleach plant flow
  to 10 m3/kkg pose technical and
  economic difficulties that EPA believes
  would take mills up to ten years to
  resolve. (Once flow levels are reduced,
  EPA expects that mills also will be able
  to achieve the Tier n AOX limitations.)
  Recycling a substantial portion of
  pulping and evaporator condensates and
  bleach plant filtrates, with the attendant
  complexities of total mill water,
  chemical, and energy balances, requires
  considerable time before it can be
  implemented successfully at mill-scale.
  For example, when bleach plant filtrates
  are recycled, problems with scale and
•  corrosion can take many months'to over
  a year to develop and be observed. Once
  identified, fully correcting such
  problems can take significant additional
 time because of the time lag between
  action and observed effect in nearly
  closed systems. In addition to problems
 with scale and corrosion, mills pursuing
 Tier n performance levels may have to
 solve challenges  associated with reusing
 condensates, such as for bleached pulp
 washing. There are a few mills currently
 doing this, but not broad operating
 experience. Consequently, EPA expects
.that Tier II mills will need to invest
 considerable time and effort to research
 and develop solutions to those technical
 problems. In addition to these technical
 challenges, significant capital costs may
 be involved in achieving Tier n limits,
 notably as a result of upgrading full
 pulping and bleaching lines and
 associated evaporator equipment.
 Providing an extended timeframe that
 allows a mill to make such capital
 expenditures on a schedule consistent
 with its planned investment cycle can
 make such large investments
 economically achievable. For example,
 one U.S. mill currently approaching the
 Tier H flow and AOX levels installed
 many of the relevant technologies in
 stages over what probably will be a ten-
 year period, with the last three years
 used for testing and fine-tuning its
 reduced flow processes. Yet even this
 mill still needs to address the technical
 challenges of further reducing
'condensate discharge flow before it is
 fully able to achieve the Tier n BAT
 limits. That mill needed ten years to
 plan;its multi-hundred million dollar
 renovation and pollution prevention
 investment, to arrange appropriate
 financing, to install supporting
 technologies at appropriate intervals
 and to research, develop, test, and refine
 its innovative flow-reducing processes.
 EPA believes that this mill's experience
 is representative of what other Tier n
 mills may encounter as they work to
 achieve the Tier H limitations. See the.
 Voluntary Advanced Technology
 Incentives Program Technical Support
 Document (DCN 14488) for additional
 examples  of why the ten-year timeframe
 is appropriate. Based on these
 experiences, EPA believes that the
 package of technologies underlying the
 Tier n Voluntary Advanced Technology
 BAT limitations will not be technically
 and economically achievable for mills
 aspiring to those performance  levels
 until April 15, 2009. However, EPA
 believes that mills will be able to
 achieve the baseline BAT limitations by
 April 15, 2004, and enforceable interim
 milestones reflecting intermediate levels
 of flow reduction (determined on a case-
 by-case basis) in a period shorter than
eleven years.
  EPA regards 15 years as a reasonable
timeframe to achieve the Voluntary
Advanced Technology BAT Limitations
corresponding to Tier EL As for Tier n,
flow reduction again is the most
difficult and time-consuming task.
However,  because reducing flow for
pulping and evaporator condensates and
bleach plant filtrates to 5 m3/kkg or
even lower approaches a closed mill
configuration, even more technically
difficult and time-consuming tasks must
be successfully completed, necessitating
 five additional years beyond the Tier n
 timeframe. For example, mills would
 probably need to install "kidney"
 technologies to remove metals and
 chlorides in order to control system
 scaling and corrosion problems while
 maintaining product quality and
 minimizing cross-media impacts.
 Successful completion of these tasks at
 individual mills may involve research,
 extensive process development,' and
 mill trials. The types of corrosion and
 scaling problems EPA anticipates could
 take over a year of nearly closed-loop
 operation to identify and several more
 years of experimental modifications to
 mill operations to solve. Extensive time
 is required for such modifications
 because of.the time lag in nearly closed-
 mill systems from changing process
 conditions and observing the steady
 state impact on hydraulic systems,
 liquor systems, and associated mill
 equipment. Mills may also need to
 embark on process development and
 mill trials to achieve treated condensate
 quality that is sufficient to extensively
 reuse condensates, as well as to
 reestablish complex mill water and
 energy balances. For these reasons, EPA
 believes that 15 years is a reasonable
 amount of time for a Tier HI mill to
 perfect existing technologies or invent
 or develop new ones as necessary to
 achieve the Tier HI performance levels.
 However, EPA believes that all mills
 will be able to achieve the baseline BAT
 limitations by [April 15, 2004], and
 enforceable interim milestones
 reflecting intermediate levels of flow
 reduction (determined on a case-by-case
 basis) in a period shorter than 15 years.
  In short, EPA believes that the
 additional 5, 10 and 15 year periods
 provided by the rule are necessary to
 foster investment, research,
 development, and mill trials of
 Advanced Technologies envisioned by
 the specified performance levels.- EPA
 further believes that, by the dates
 specified in the rule, technologies
 necessary to achieve those performance
 levels will indeed be available. See DCN
 14488.
  EPA has concluded that it is
 reasonable to measure the extended
 time periods from the publication date
 of the Cluster Rules rather than from the
 date a participating mill's NPDES
 permit is issued, with the addition of
 one year, at the beginning to afford mills
a meaningful opportunity to consider
participating in the Voluntary Advanced
Technology Incentives Program.  EPA
recognizes that the decision whether to
commit to the Advanced Technology
goals cannot be undertaken lightly. This
is especially so in view of the significant

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capital costs involved and in view of
possible uncertainties regarding the
availability of appropriate cost-effective
technologies and a muTs ability to
maintain product quality. Accordingly,
EPA expects the decision would need to
be made at the corporate rather than the
facility level, which would probably
require corporate-wide consideration of
the firm's financial health, its
environmental objectives and future
marketing strategies, and its overall
long-term plans. Because EPA believes
that many firms in Subpart B have been
pondering these strategic questions
since publication of the proposed rule
in December 1993 and the notice
regarding a possible incentives program
in July 1996. EPA has concluded that
one year is sufficient to allow firms to
make a. decision whether to participate
in the Voluntary Advanced Technology
Incentives Program. If a mill's permit
expires and is reissued before April 15,
1999, the permitting authority should
incorporate Voluntary Advanced
Technology BAT Limitations into that
permit at the mill's request. If the mill
has not yet decided whether to
participate in the Voluntary Advanced
Technology Incentives Program, the
permit writer should incorporate BAT
limitations based on the BAT baseline
and should include a reopener clause so
that the permit can be modified as
necessary to reflect the mill's decision
to participate in the incentives program.
In order to afford that mill a full year to
decide whether to enroll in the
incentives program, EPA believes it
would be appropriate for the permitting
authority to issue a compliance order
expiring April 15,1999 so that the mill
would not be required to comply with
the baseline BAT limitations until after
the election date has passed.
  Some commenters suggested that EPA
measure the Advanced Technology time
periods from the date the first permit
reflecting Voluntary Advanced
Technology BAT limitations is  issued.
EPA rejected that approach and instead
is measuring the  time periods from the
publication date of this rule (plus one
year) for the following reasons. First,
these timeframes reflect EPA's
conclusions regarding the amount of
time that mills would need in order to
achieve the various Voluntary
Advanced Technology Tier performance
levels, once they have committed to
those goals. As discussed in more detail
above, EPA based these conclusions on
record information concerning the
availability of technologies and capital,
among other factors. These factors have
nothing to do with the permitting cycle.
Second, as a matter of policy, EPA
                          wants to promote implementation of
                          advanced technologies as soon as
                          possible; if EPA were to measure the
                          Advanced Technology time periods
                          from the date of permit re-issuance,
                          achievement of the ultimate Tier I
                          performance requirements and the
                          interim baseline BAT limitations for
                          Tiers IE and HI, for example, could be
                          deferred at some mills by as much as ten
                          years from the date of promulgation.
                          Third, EPA was concerned that tying the
                          Advanced Technology time periods to
                          highly variable permit issuance dates
                          would mean that mills with later
                          permits would realize a competitive
                          advantage over similarly situated mills
                          that, merely because of their particular
                          permit cycle, would need to achieve the
                          Voluntary Advanced Technology BAT
                          limitations sooner. Such inequities—
                          whether perceived or real—could
                          discourage some mills from
                          participating in the Voluntary Advanced
                          Technology Incentives Program. Finally,
                          mills in the Bleached Papergrade Kraft
                          and Soda subcategory have been on
                          notice since at least 1993 that EPA was
                          considering basing some portion of its
                          Cluster Rules on extended
                          delignification technologies. (In its 1993
                          proposal, EPA proposed to base BAT
                          limitations on a process that included
                          oxygen delignification and 100 percent
                          substitution of chlorine dioxide for
                          elemental chlorine.) In some cases, that
                          proposal has already influenced
                          investment decisions at some mills.
                            EPA acknowledges that a mill
                          choosing not to participate in the
                          Voluntary Advanced Technology
                          Incentives Program could seek a
                          compliance schedule in an enforcement
                          order that, depending on the date its
                          permit was reissued, could allow that
                          mill to achieve BAT limits (including a
                          less stringent AOX limit) at a later date
                          than Tier I Advanced Technology mills
                          would be required to achieve a more
                          stringent AOX limit and reduced kappa
                          numbers and pulping area filtrate
                          recycling. While EPA agrees with
                          comments characterizing this as unfair
                          to those facilities making the significant
                          commitment to install Advanced
                          Technologies, EPA believes that the
                          likelihood of such inequities is small for
                          the following reasons. First, EPA has
                          determined that this is likely to happen
                          in comparatively few cases. More than
                          80 percent of the permits issued to mills
                          in the Bleached Papergrade Kraft and
                          Soda subcategory will expire before
                          2000. See Record section 21.8.1, DCN
                          14652. Consequently, EPA believes that
                          most Advanced Technology mills will,.
                          receive more time to achieve Tier I
                          limits than other mills would receive to
achieve baseline BAT limits, even with
an enforcement compliance schedule.
Second, when EPA is the permitting
authority, EPA will exercise its
enforcement discretion to refrain from
issuing enforcement compliance
schedules after April 15,  1999 to mills
not participating in the Voluntary
Advanced Technology Incentives
Program. This means that a mill not
participating in the Voluntary Advanced
Technology Incentives Program would
be expected to comply with its baseline
BAT limits by the date its permit
containing those limits is issued, or by
[April 15, 1999], whichever is later. EPA
will also publish guidance urging State
enforcement authorities to do the same.
By limiting the discretionary
enforcement-related compliance
schedules available to baseline BAT
mills, EPA hopes that the additional
time periods specified for Advanced
Technology mills will become a more
meaningful incentive and perhaps may
persuade some mills to participate in
the incentives program rather than
comply immediately with the baseline
BAT limitations.
8. Legal Authority to Promulgate a
Package of Progressively More Stringent
Voluntary Advanced Technology BAT
Limitations

  As described in more detail above, the
Advanced Technology BAT guidelines
for each Tier consists of a range of
successively more stringent limitations
and permit conditions that represent a
mill's progress toward the Tier's
ultimate Advanced Technology
performance requirements. Based on its ,
analysis of today's advanced and, in
some cases, innovative technologies and
its judgment regarding the historically
rapid advance of pollution prevention
processes in this industry, EPA has
determined that those performance
requirements are achievable, as a
technical matter, by the dates specified
in each Tier, and that none of the other
statutory factors in CWA Section
304 (b) (2) (B) justify selecting different
technology bases for Advanced
Technology BAT. EPA has also
determined that those Advanced
Technology performance requirements
are within the economic  capability of
mills choosing today to meet them and
hence are economically achievable for
those mills. EPA bases that
determination primarily  on tvJvo factors.
First, no mill is compelled to enroll in
the Voluntary Advanced Technology
Incentives Program; accordingly, EPA
assumes that mills that choose to
enroll—and voluntarily subject,
themselves to a progression of

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             Federal Register/Vol. 63. No. 72/Wednesday.  April. 15, 1998/Rules and Regulations      18607
successively more stringent, enforceable
permit limits—do so with the
knowledge that they have the economic
as well as technical ability to meet those
limits. Second, the experience of other
mills that voluntarily undertook major
pollution prevention projects informs
EPA that the ambitious performance
requirements are indeed achievable for
participating mills if the incremental
improvements are staggered over time.
  This incremental approach is
authorized by CWA section
301 (b) (2) (A), which expressly requires
BAT to result in reasonable further
progress toward the national goal of
eliminating pollutant discharges. EPA
believes that each of the steps
comprising the three tiers of Voluntary
Advanced Technology BAT Limitations
moves participating mills toward that
national goal. Once a mill enrolls in the
Voluntary Advanced Technology
Incentives Program, it accepts and must
begin immediately to implement a BAT
package consisting of successively more
stringent permit limits and conditions.
Although environmental improvements
are realized only incrementally, the mill
is subject to the total set of limits-
including the ultimate performance
requirements—as soon as its Advanced
Technology permit is written based on
the first increment of that BAT package.
Thus, the mill is continuously subject to
and must comply immediately with the
Advanced Technology BAT package as
it progressively unfolds, including each
interim BAT limitation or permit
condition representing that progress.
  EPA's promulgation of BAT as a
package of progressively more stringent
limitations and conditions is also
consistent with the use of BAT as a      •
"beacon to show what is possible."
Kennecottv. EPA, 780F.2d445, 448  .
(4th Cir. 1985). Thus, while the
compulsory BAT in this rule functions
as the "base level" for the subcategory
as a whole, see E.I. du Pont de Nemours
& Co. v. Train, 430 U.S. 112, 129 (1977),
EPA expects the Voluntary Advanced
Technology BAT limitations to drive
technologies and mills beyond that base
level toward achievement of the goals of
the Clean Water Act. By holding out the
Advanced Technologies as beacons of
progress, EPA believes that today's rule
will encourage more mills to strive
toward EPA's pollution prevention and
reduced flow objectives than might
otherwise do so if EPA promulgated
nothing more than a "base level" BAT.
Moreover, by codifying progressively
more stringent limitations in today's
Advanced Technology BAT package,
EPA promotes a form of technological
progress that is consistent with
Congressional intent that  BAT should
aspire to "increasingly higher levels of
control." See, e.g., Statement of Sen.
Muskie (Oct. 4, 1972), reprinted in A  '
Legislative History of the Water
Pollution Control Act Amendments of
1972 ("1972 Leg. Hist."), at 170. It is
also consistent with the overall goals of
the Act. See CWA Section 101 (a).
Agencies have considerable discretion
to interpret their statutes to promote
Congressional objectives. " '[T]he
breadth of agency discretion is, if
anything, at zenith when the action
*  * * relates primarily to *  * * the
fashioning of policies, remedies and
sanctions, including enforcement and
voluntary compliance programs [,] in
order to arrive at maximum effectuation
of Congressional objectives.'" U.S.
Steelworkers of America v. Marshall,
647 F.2d 1189, 1230-31 n.64  (D.C. Cir.
1980) (upholding OSHA rule staggering
lead requirements over 10 years)
(quoting Niagara Mohawk Power Corp.
v. FPC, 379 F.2d 153,  159 (D.C. Cir.
1967)), cert, denied, 453 U.S.  9113
(1981). In this case, the codification of
progressively more stringent BAT
limitations advances not only the
general goal of the Clean Water Act, but
also the explicit goal of the BAT
program. See Chevron, U.S.A., Inc. v.
NRDC, 467 U.S. 837, 843-44 (1984).
  Moving toward the elimination of
pollutant discharges in stages is also
consistent with overarching structure of
the effluent limitations guidelines
program. Congress originally envisioned
that the sequence of attaining BPT limits
in 1977 and BAT limits in 1983 would
result in "levels of control which    '
approach and achieve the elimination of
the discharge of pollutants." Statement
of Sen. Muskie (Oct. 4, 1972), reprinted
in 1972 Legislative History, at 170. This
two-step approach produced dramatic
improvements in water quality, but did
not achieve the elimination of pollutant
discharges. Therefore, EPA periodically .
revisits and revises its effluent
limitations guidelines with the intention
each time of making further progress
toward the national goal. (This is the
sixth effluent limitations guideline
promulgated for the pulp and paper
industry, and the fourth applicable to
bleached papergrade kraft and soda
mills.) Achieving these incremental
improvements through successive '
rulemakings carries a substantial cost,"
however. The effluent guideline
rulemaking process is highly complex,
in large part because of the massive
record compiled to inform the Agency's
decisions and because of the substantial
costs associated with achieving each
additional increment of environmental.
improvement. By promulgating these
Voluntary Advanced Technology BAT
limitations today as a package of
incremental environmental
improvements, EPA hopes to achieve
the goals that Congress envisioned for
the BAT program at considerably less
cost: one rulemaking that looks both at
the present and well into the future.
Mills willing to surpass today's
compulsory BAT requirements have a
framework to anticipate what could be
tomorrow's subcategory-wide BAT and
to make today's environmental,
financial and engineering judgments
accordingly. Thus/the three-tiered•
incentives program itself represents
reasonable further progress toward the
goal of eliminating pollutant discharges.
At the same time, within each Tier,
mills must make incremental
improvements that also represent
reasonable further progress toward that
national goal. In short, each BAT
increment, whether in the form of the
Tiers themselves or the progressively
more stringent limitations comprising
them, gives contemporary meaning  to
the staging process originally
envisioned by Congress as the means to
achieve the goal of eliminating
discharge of pollutants to the Nation's
waters.
  Finally, like other agencies, EPA has
inherent authority to phase in regulatory
requirements in appropriate cases. EPA
has employed this authority in other
contexts. For example, EPA recently
phased in, over two years, TSCA rules
pertaining to lead-based paint activities.
See 40 CFR 746.239 and 61 FR 45788,
45803 (Aug. 29, 1996). Similarly, the
Occupational Safety and Health
Administration phased in, over 10
years, a series of progressively more
stringent lead-related controls. See 29
CFR 1910.1025 (1979 ed.). Indeed, in
upholding that rule, the U.S. Court of
Appeals for the D.C. Circuit noted that
"the extremely remote deadline at
which the [sources] are to meet the final
[permissible exposure limits] is perhaps
the single most important factor
supporting the'feasibility of the
standard." United Steelworkers of
America v. Marshall, 647 F.2d at 1278. ,
  EPA is aware that CWA sections
301 (b) (2) (C) & (D) require BAT limits to
be achieved "in no case later than three
years after the date^such limits are
promulgated Under section 304(b), and
in no case later than March 31, 1989."
(Section 301 (b)(2)(F), which refers to
BAT limitations for nonconventional
pollutants, also contains the March  31,
1989 date, but uses as its starting point:
the date the limitations are
"established.") This language does not
speak to the precise question EPA
confronts here: whether EPA can

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18608      Federal Register/Vol. 63,  No. 72/Wednesday,  April 15, 1998/Rules and Regulations
promulgate Voluntary Advanced
Technology BAT limitations that are
phased in over time, so that a direct
discharger at all times is subject to and
must comply immediately with the
particular BAT limitations applicable to
them at any given point in time. Section
301 (b) (2) provides no clear direction.
EPA therefore is charged with making a
reasonable interpretation of the statute
to fill the gap. See Chevron, U.S.A., Inc.
v. NRDC, 467 U.S. at 843-44. EPA
believes that subjecting mills who
voluntarily enroll in the Voluntary
Advance Technology Incentives
Program to progressively more stringent
BAT limitations over time best serves
Congress' intent of pushing mills to
achieve reasonable further progress
toward eliminating all pollutant
discharges.  It also ensures that mills
achieve these superior performance
requirements at a pace that makes
technical and economic sense. Finally,
by phasing in these highly stringent—
but elected—controls, EPA hopes to
encourage more mills to surpass the
BAT baseline, with the result that the
environment realizes a far greater
improvement than EPA could expect to
see without this phased approach. For
these reasons, EPA believes it is entitled
to deference in its decision to
promulgate Voluntary Advanced
Technology BAT limits in this manner.
  Several commenters supported the
idea of phasing in compliance with BAT
limitations for the purpose of
minimizing short-term economic
impacts on mills, but urged EPA to
adopt this approach to set baseline BAT
limits based on the model Tier I
Advanced Technology (i.e., BAT Option
B). In other words, these commenters
argued that more stringent baseline BAT
limits based on the Tier I technology
would be economically achievable for
the entire subcategory because affected
mills would have five years to achieve
full compliance. As noted above, EPA
agrees that The Advanced Technologies
that are not economically achievable at
present can become economically
achievable for individual mills that
voluntarily  participate as time passes.
Indeed, Congress recognized as much in
requiring EPA to review its effluent
guidelines and to revise them as
appropriate. See CWA section 304 (b).
However, EPA disagrees that it currently
has sufficient basis on the record
available today to compel  all mills in
the Bleached Papergrade Kraft and Soda
subcategory to meet the more stringent
limits five years from now. In this
rulemaking, the economic achievability
of those more stringent CTier I) limits is
determined by the voluntary investment
decisions of the affected mills; because
of the voluntary nature of the Advanced
Technology Incentives Program, it is the
mills, not EPA, that determine that
particular Advanced Technologies are
available and economically achievable
for them within the time frames ,
provided in this program. In order for
EPA to impose Advanced Technology
limits on the entire subcategory as the
commenter suggests, EPA would need to
find adequate support in the rulemaking
record today that compulsory BAT
limits will be economically achievable
for their entire subcategory five years
from now. EPA cannot make that
determination based on the information
available today. At best, EPA could only
speculate whether some or all of the
mills projected to sustain the most
severe economic impacts if BAT Option
B is selected would be able to avoid
those impacts if compliance with that
BAT is deferred. EPA does not believe
that this type of speculation is a
sufficient basis for compelling
compliance with BAT limits that are not
economically achievable today for the
subcategory as a whole. Moreover, when
EPA estimated the effects of deferring
compliance, subcategory-wide, for five
years in response to these comments,
EPA concluded that the projected
impacts were such that, even then, BAT
Option B would not be economically
achievable for the subcategory as a
whole. See Section VI.B.5.a(5). For these
reasons, EPA concludes that it does not
have a sufficient record basis today to
make Tier I (or BAT Option B)
limitations the compulsory baseline
BAT even if such limits would not be
effective until 2002. See DCN 14392,
and CBI documents DCN 14390 and
DCN 14391.
  EPA could have accomplished the
same results in this rulemaking simply
by deferring the effective dates of the
ultimate Advanced Technology
performance objectives until the dates
specified in the rule for achievement of
the "stage 2" limitations. EPA has the
legal authority to defer the effective
dates of the "stage 2" portion of the
Advanced Technology BAT limitations
in this manner. Subject to the minimum
delays imposed by the APA, 5 U.S.C.
§ 553 (d), and the Small Business
Regulatory Enforcement Fairness Act
(SBREFA), 5 U.S.C. §801, EPA has
inherent authority to determine the
effective date of a rule and to defer the
effective date in appropriate cases. See
ASG Industries, Inc. v. Consumer
Products Safety Comm'n, 593 F.2d 1323,
1335 p.C. Cir. 1979). Nothing in the
Clean Water Act limits this authority
with respect to BAT effluent limitations
guidelines. In contrast to section
306(b)(l)(B), where Congress explicitly
stated that new source performance
standards, "or revisions thereof, shall
become effective upon promulgation,"
the CWA is silent regarding the effective
date of BAT effluent .limitations
guidelines. Having failed to prescribe
when BAT guidelines become effective,
Congress therefore has delegated to the
Agency the authority to choose the
appropriate effective date of the BAT
effluent guideline  limitations it
promulgates, so long as the Agency's
choice is consistent with the goals and
purposes of the Act. See Chevron,
U.S.A., Inc. v. NRDC, 467 U.S. at 843-
44, 861. Under this approach, the "stage
1" limitations would be effective
immediately, and the "stage 2"
limitations would  become effective by
the dates specified in the regulation.
B. Incentives Available After
Achievement of Advanced Technology
BAT Limitations and NSPS
1. Greater Certainty Regarding Permit
Limits and Requirements
  Industry stakeholders have suggested
to EPA that mills could be encouraged
to implement advanced technologies if
they had a reasonable assurance that all
limitations and conditions in their
permits would remain constant over a
specified period of time, once
compliance with the Advanced
Technology limits and standards is
achieved.
. Under this incentive, EPA will issue
guidance to states regarding the
reissuance of NPDES permits held by
mills that achieve all of their- Advanced
Technology BAT limitations or NSPS.
(EPA notes that new sources that accept
permit limitations based on, and
commence operation in compliance
with, Tier E or Tier m NSPS
automatically possess a shield against
more stringent standards of performance
for ten years from the completion of
construction.)
  In its forthcoming guidance, EPA will
address the timing of reissuing
Advanced Technology NPDEiS permits
and the limitations those reissued
permits should contain. Regarding the
reissuance of Advanced Technology
NPDES permits, EPA believes that
permitting authorities could reasonably
conclude that an Advanced Technology
NPDES permit held by a mill meeting
all of its Tier limits is a low priority for
permit reissuance, if there is no new
water quality- or facility-related data or
information that would justify new or
different limits. Under these
circumstances, EPA believes it would be
reasonable for a permitting authority to

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             Federal Register/Vol. 63. No. 727 V/ednesday, April 15, 1998/Rules and  Regulations
                                                                    18609
 conclude that that permit is a lower
 priority for reissuance because the mill
 is voluntarily achieving reductions
 greater than otherwise required by the
 baseline BAT and hence presents a
 lower risk to water quality than other
 mills.
   In its guidance, however, EPA will
 emphasize that an Advanced
 Technology NPDES permit should be
 administratively extended only if die
 permitting authority had provided the
 public with notice (the last time the
 permit was reissued) that it might
 choose to extend the permit
 administratively when it expires. Thus,
 EPA expects the permitting authority to
' notify the public as part of the
 preceding permitting process of the
 circumstances under which it would
 regard the Advanced Technology •
 NPDES permit as a low priority for
 reissuance in the next permitting cycle.
 For example, EPA expects the
 permitting authority to inform the
 public that the permit probably would
 be administratively extended if the
 permittee has achieved all of its
 Advanced Technology limitations, if it
 has filed a timely permit application,
 and if the permitting authority possesses
 no new water quality or facility-related
 data that would justify new or different
 permit  conditions and limits. In
 addition, EPA expects that the permit
 eligible for an administrative extension  .
 would contain BMPs and any water
 quality-based effluent limits necessary
 to achieve applicable water quality
 standards. Thus, EPA would not expect
 any adverse effect on the environment
 during  the period the permit is
 administratively extended, in the
 absence of specific information
 indicating that more stringent water
 quality effluent limits need to be
 imposed.
  The forthcoming guidance will also
 address the types of limitations an     •
 Advanced Technology NPDES permit
 should contain when it is reissued after
 achievement of the Tier limitations. As
 a threshold matter, the permitting
 authority will need to determine if there
 is a need for new or revised water
 quality-based effluent limitations. If
 there is none, EPA encourages
 permitting authorities to promptly
 reissue the NPDES permit with the
 existing water quality-based effluent
 limitations, if any, and the appropriate
 limitations found in 40 CFR Part 430. In
 some cases, the permitting authority
 may receive new facility- or watershed-
 specific information indicating that load
 reductions and, consequently, more
 stringent effluent limits on a pollutant
 in the mill's wastewater are necessary to
 achieve applicable water quality
standards for that pollutant. Under these
circumstances, EPA would urge states to
develop priorities for allocating the
necessary load reductions in a way that
gives preference to Advanced
Technology mills over all other Subpart
B mills, particularly where Advanced
Technology mills contribute a small
portion of the total pollutant loads to
the stream. Moreover, where more than
one Advanced Technology mill
discharges in a watershed, these
priorities would further give preference
first to Tier m mills, then to Tier E, and
finally to Tier I mills.

2. Reduced Effluent Monitoring
  EPA believes that reduced monitoring
provisions.are appropriate for ECF and
TCF mills participating in the Voluntary
Advanced Technology Incentives
Program and is including them in the
today's regulation for mills that achieve
Voluntary Advanced Technology BAT
Limitation's or NSPS, as appropriate. See
40 CFR 430.02(c), (d) and (e). In EPA's
view, consistent and successful
implementation of the Advanced
Technologies through ECF or TCF
processes will make it increasingly less
likely that the pollutants controlled by
the baseline BAT will be present in the
wastewater from Advanced Technology
fiber lines in levels of concern. Because
of these reductions and because
monitoring for these pollutants tends to
be costly, EPA believes it is reasonable
to allow mills achieving the Voluntary
Advanced Technology BAT limitations
or NSPS through ECF or TCF processes
to monitor less frequently for those
pollutant parameters over time after
establishing a reliable baseline of
consistent achievement of those
Advanced Technology BAT limitations
or NSPS. See  40 CFR 430.02(c)-(e). To
qualify for a monitoring incentive, the
mill must certify that the fiber line is
TCF or Advanced ECF either as part of
their permit application or as part of a
report of progress on compliance with
milestones established to achieve their
ultimate Tier  limits. 40 CFR 430.02(c).
  No monitoring incentive is available
for kappa number or flow because no
minimum monitoring frequencies are
being established by this regulation.
EPA encourages permitting authorities
to consider factors such as the reliability
of the Advanced Technology to
consistently achieve or exceed the
applicable limitations and performance
variability in establishing monitoring
frequencies for kappa number and flow
on a best professional judgment basis.
  The monitoring incentive for AOX
applies only when the entire mill is ECF
or TCF. See 40 CFR 430.02 (c) and (d).
Since compliance with AOX most likely
 will be determined at the end of the '
 pipe, the monitoring requirement would
 be governed by the fiber line for which
 most frequent monitoring is required.
   EPA retains the authority to request or
 .obtain specific information that may be
 needed to determine compliance with
 the requirements of this rule. Because
 monitoring relief is specified to be
 available by the date compliance is
 required, even if the limits have not
 been achieved, EPA anticipates that
 permitting authorities will exercise their
 Section 308 authority to extend more
 frequent monitoring for mills that do not
 achieve compliance with their
 limitations.
   EPA relies on section 308(a) of the
 Clean Water Act for authority to
 promulgate this incentive. The reduced
 monitoring for this effluent limitations
 guideline incentive program  is being
 incorporated in the Code of Federal
 Regulations, and is summarized as
 follows:
   a. For TCF fiber lines under Tiers I,
 n, and ffi, no monitoring incentive is
 available because no existing TCF fiber
 line is subject to minimum monitoring
 frequencies established by this rule. See
 40 CFR 430,02(a). EPA  anticipates that
 permitting  authorities will consider the
 monitoring for AOX being imposed on,
 mills in comparable Tiers, and the
 additional assurance of compliance that
 TCF process technologies afford relative
 to AOX, in establishing monitoring
 frequencies on a best professional
judgment basis. For mills that use TCF
 processes part of the time and ECF
 processes for the remainder, EPA would
 aoply the reduced monitoring incentive
 applicable to an ECF process. See 40
 CFR430.02(c), (d) and (e).
  b. For any fiber line enrolled under '
 Tier I, E,  or m for which the mill
 certifies in  its NPDES permit
 application or other communication to
 the permitting authority that  it employs
 exclusively Advanced ECF technologies
 (i.e., extended delignification or other
 technologies that achieve at least the
 Tier I performance levels specified in
 Section 430.24 (b) (4) (i)), the minimum
 monitoring requirements for dioxin,
 furan, chloroform and the 12
 chlorinated phenolic pollutants will be
 suspended 'after one year of monitoring •
 following achievement  of those
 limitations and standards. See 40 CFR
 430.02(c). (These limitations  and
 standards must be achieved no later
 than April 15, 2004. See 40 CFR
 430.24(b) (3).) For AOX, a certifying
 Advanced ECF mill also would be
 permitted to perform weekly instead of
 daily monitoring for one year after
 achievement Of the ultimate Tier BAT
 limit or NSPS for that pollutant. See 40

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 18610      Federal Register/Vol. 63. No. 72/Wednesday, April 15, 1998/Rules and Regulations
 CFR 430.02(d). Monitoring for AOX
 once per month would be permitted for
 Tier IECF mills for four years beyond
 the completion of that one year period.
 See 40 CFR 430.02(e). Tier H ECF mills
 would be permitted to monitor for AOX
 once per quarter for four years beyond
 the completion of that one year period,
 and Tier ffl ECF mills would be
 permitted to monitor for AOX once per
 year for four years beyond the
 completion of that one year period. Id.
 3. Reduced Inspections
   EPA will issue guidance to EPA
 Regional Offices indicating that fiber
 lines enrolled in the Voluntary
 Advanced Technology Incentives
 Program and achieving Voluntary
 Advanced Technology BAT limitations
 or NSPS should be a lower priority than
 other NPDES facilities for routine
 inspections under the CWA. Under this
 incentive, the guidance would
 recommend that fiber lines achieving
 Tier I limits receive routine EPA
 inspections not more than once every
 two years; fiber lines achieving Tier II
 limits receive routine EPA inspections
 not more than twice every five years;
 and fiber lines achieving Tier til limits
 receive routine EPA inspections not
 more than once every five years. This
 incentive reflects EPA's view that mills
 installing and operating Advanced
 Technologies at levels to meet the
 appropriate tier effluent limitations and
 standards are likely to be complying
 with the other permit requirements
 applicable to that fiber line.
 Furthermore, the substantial reductions
 in pollutants and wastewater volumes
 discharged, particularly by mills
 achieving Tier n and Tier IE limitations
 and standards, will have
 commensurately reduced environmental
 impacts. EPA already has redirected
 Federal NPDES inspections away from
 annual inspections of all major
 dischargers to focus on high risk
 facilities in priority watersheds.
 Targeted efforts in these priority
 watersheds focus on such factors as
 facility compliance status and rates,
 location and affected population, citizen
 complaints, etc. Nonetheless, under this
 incentive, EPA reserves the authority to
 conduct multi-media inspections
 without prior notice, and to inspect
 Advanced Technology fiber lines for
 cause, whether or not there is an
 ongoing violation. EPA also reserves its
 right to inspect an Advanced
 Technology mill in connection with
 specific watershed or airshed concerns.
 4. Public Recognition Programs
,   EPA is pleased to have the
 opportunity to implement a program in
which it can recognize facilities for
voluntary activities that achieve further
environmental improvements beyond
those required by the baseline BAT
limitations and NSPS promulgated
today. EPA's intention is to provide for
easily administered and meaningful
public recognition for mills that
participate in the Voluntary Advanced
Technology Incentives Program. EPA •
will accord public recognition to mills
when they formally enroll in the
Program, when they achieve major
interim milestones, and when they
achieve the ultimate Tier performance
requirements. The applicable state
permitting authority also may choose to
separately recognize a pulp and paper
mill for its commitments and
achievements toward further
environmental improvements. The
following paragraphs describe the steps
for public recognition. EPA will issue
additional guidance to facilitate
implementation of this incentive.
  a. Enrolling in the Voluntary
Advanced Technology Incentives
Program. Once a mill has enrolled in the
Voluntary Advanced Technology
Incentives Program, EPA will issue a
letter to each facility acknowledging its
participation and identifying the tier
limits (and fiber line(s) as appropriate)
to which the mill has committed. Each
year EPA will publish a Federal
Register notice identifying mills that
have committed to.the program within
the previous year. The self-selected Tier
will be clearly identified, as will any
other pertinent information. The
Federal Register notice will be made
available on the EPA Internet web site.
  b. Achievement of Milestones. Each
time a mill achieves a major milestone
(particularly those which achieve
reduction in effluent pollutant
loadings), EPA will recognize that mill
in its annual Federal Register notice. In
order to qualify for this recognition,
each mill must notify its permitting
authority and provide supporting
monitoring data or other relevant
documentation. The permitting
authority may choose to visit the site for
verification. EPA, in concert with the
relevant state NPDES programs, also
will then ascertain the status of Clean
Water Act compliance and any other
enforcement actions prior to public
recognition activities.. Any criminal
enforcement activities, particularly
convictions, also will be ascertained.
This information on compliance and
enforcement status will be available for
consideration by EPA senior
management prior to initiation of public
recognition activities. Relevant
information on enforcement and
compliance status also may be shared as
appropriate with senior management of
state permitting agencies that initiate
separate public recognition activities.
Public recognition for achieving
milestones will continue until the date
participating mills are required to
achieve the ultimate Tier performance
requirements.
  c. Achievement of Voluntary
Advanced Technologies BAT
Limitations or NSPS. Mills that achieve
their Advanced Technology BAT
Limitations or NSPS will notify the
permitting authority and submit
supporting monitoring data and other
relevant documentation. The permitting
authority will verify that the Advanced
Technology BAT Limitations or NSPS
have been achieved. The annual Federal
Register notice will identify these
facilities as reaching their goal. EPA also
will participate in an award ceremony at
an appropriate venue (e.g., TAPPI
Environmental Conference).

5. Reduced Penalties
  In recognition of the considerable
capital expenditures that mills
participating in the Voluntary Advanced
Technology Incentives Program will
make to implement Advanced
Technologies and to achieve pollutant
reductions superior to those achievable
through the baseline BAT or NSPS, EPA
will encourage enforcement authorities
to take into account those investments
as appropriate when assessing penalties
against these mills for violations relating
to those Advanced Technologies.
Existing EPA settlement policies
provide consideration of Advanced
Technology investments in this manner.
In EPA's view, if a facility has installed
and is operating the Advanced
Technology in good faith, reports
violations in a prompt manner to  EPA
or the State, and either corrects the
violations in a timely manner or agrees
to and complies with reasonable
remedial measures concurred on by the
primary enforcement authority, then the
enforcement authority would, be
justified in taking the Advanced
Technology investment into account in
determining economic benefit and in
reducing the gravity portion of the
penalty by up to 100 percent. Where the
installation and operation of any
Advanced Technology was more
expensive .than the installation and
operation of the technology underlying
the baseline BAT, the Advanced
Technology facilities would derive no
economic benefit (i.e., zero BEN) from
the violation associated with the
Advanced Technology. This would be
the case even when the Advanced
Technology fails, as long as the design,
operation and installation are within

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 applicable, engineering standards and
 operational procedures are within
 industry norms. The decision whether
 to take such Advanced Technology
 investments into account in determining
 economic benefit would be left to the
-State's discretion when the State is the
 enforcing authority. EPA will issue
 guidance to clarify application of this
 incentive.
  Mills also can take advantage of the
 recently issued audit policy providing
 they meet the criteria specified in that
 policy. See 60 FR 66706 (Dec. 22, 1995).

 X. Administrative Requirements and
 Related Government Acts or Initiatives
 A. Dockets
  The docket is an organized and
 complete file of all the information
 submitted to or otherwise considered by
 EPA in the development of the final
 regulations. The principal purposes of
 the docket are: (1) To allow interested
 parties to readily identify and locate
 documents so that they can intelligently
 and effectively participate in the
 rulemaking process; and (2) to serve as
 the record in case of judicial review,
 except for-intra-agency review materials
 as provided for in section 307 (d) (7) (A). ,
 1. Air Dockets        .,
 • Air Docket No. A-92-40 contains
 information considered by EPA in
 development of the NESHAP for the
 chemical wood pulping mills. Air
 Docket No. A-95-31 contains
 information considered in developing
 the NESHAP for mechanical pulping
 processes, secondary fiber pulping
 processes, and nonwood fiber pulping
 processes. The Air Dockets are available
for public inspection between 8 a.m.
 and 4 p.m., Monday through Friday
 except for Federal holidays, at the
following address: U.S. Environmental
 Protection Agency, Air and Radiation
 Docket and Information Center (MC-
 6102), 401 M Street SW, Washington,
DC 20460; telephone: (202)  260-7548.
The dockets are located at the above
address in Room M-1500, Waterside
Mall (ground floor). All comments
received during the public comment
period on the 1993  proposed NESHAP
are contained in the Pulp and Paper
Water Docket (see following paragraph
for location). Comments received on the
March 8, 1996, supplemental NESHAP
notice at 61 FR 9383 are contained in
Air Dockets A-92-40 and A-95-31.
 2. Water Docket
  The complete public record for the
effluent limitations guidelines and
standards rulemaking, including EPA's
responses to comments received during
 the rulemaking, is available for review
 at EPA's Water Docket, Room M2616,
 401 M Street SW, Washington, DC
 20460. For access to Docket materials,
 caU (202) 260-3027. The Docket staff
 requests that interested parties call
"between 9:00 am and 3:30 pm for an
 appointment before visiting the docket.
  The EPA regulations at 40 CFR Part 2
 provide that a reasonable fee may be
 charged for copying materials from the
 Air and Water Dockets.
  EPA notes that many documents in
 the record supporting these final rules
 have been claimed as confidential
 business information (CBI) and,
 therefore, are not included in the record
 that is available to the public in the Air
 and Water Dockets. To support the
 rulemaking, EPA is presenting certain
 information in aggregated form or is
 masking facility identities to preserve
 confidentiality claims. Further, the
 Agency has withheld from disclosure
 some data not claimed as confidential
 business information because release of
 this information could indirectly reveal
 information claimed to be confidential.
 B. Executive Order 12866 and OMB
 Review                    .

  Under Executive Order 12866, (58 FR
 51735, October  4,  1993), the Agency
 must determine whether the regulatory
 action is "significant" and therefore
 subject to OMB  review and the
 requirements of the Executive Order.
 The Order defines "significant
 regulatory action" as one that "is likely
 to result in a rule that may: (1) Have an
 annual effect on the economy of $ 100
 million or more or adversely affect in a
 material way the economy, a sector of
 the economy, productivity, competition,
jobs, the environment, public health or
 safety, or State,  local, or tribal
 governments or communities; (2) create
 a serious inconsistency or otherwise
 interfere with an action taken or
 planned by another agency; (3)   -
 materially alter the budgetary impact of
 entitlements, grants, user fees, or loan
 programs or the rights and obligations of
 recipients thereof; or (4) raise novel
 legal or policy issues arising out of legal
 mandates, the President's priorities, or
 the principles set forth in the Executive
 Order."
  Pursuant to the terms of Executive
 Order 12866, it has been determined
 that the Cluster  Rules are a "significant
 regulatory action" because they will
have an annual effect on the economy
 of $ 100 million  or more. As such, this
 action was submitted to OMB for
 review. Changes made in response to
 OMB suggestions or recommendations
 are  documented in the public record.
 C. Regulatory Flexibility Act and the
 Small Business Regulatory Enforcement
 Fairness Act of 1996 (SBREFA)

  Under the Regulatory Flexibility Act
 (RFA), 5 U.S.C. 601 etseq., as amended
 by SBREFA, EPA generally is required
 to conduct a regulatory flexibility
 analysis describing the impact of the
 rule on small entities. However, under
 section 605 (b) of the RFA, EPA is not
 required to prepare the regulatory
 flexibility analysis if EPA certifies that
 the rule will not have a significant
 economic impact on a substantial
 number of small entities.
  Pursuant to section 605 (b) of the RFA,
 the Agency certifies that today's final
 CWA rule will not have a significant
 economic impact on a substantial
 number of small entities. In addition,
 EPA also finds that the final CAA rule
 will not have a significant economic
 impact on a substantial number of small
 entities. Small entities, as defined,
 include small businesses, small
 governments, and small organizations.'
 This rulemaking does not affect small
 organizations. For small governments,
 these rules could directly affect
 administration or operating costs, but
 are not expected to result in significant
 impacts (see Section X.E.). Small
 businesses are the'remaining class of
 small entity affected by this rulemaking.
 For small businesses, EPA examined the
 economic impacts of these rules in
 detail and the results of its analysis are
 found in the "Economic Analysis"  (see
 DCN 14649). The following is a brief
 summary of the analysis.
 • Today's CWA final rule will not have ,
 a significant economic impact on a
 substantial number of small entities,
 because of those companies affected by
 the CWA rule, only four are "a small
 business concern" as defined by SB A
 regulations. (The RFA, in general,
 requires use of SBA definitions of small
 businesses; for this regulation, small
 businesses are defined as firms
 employing no more than 750 workers.)
 EPA does not believe this is a
substantial number of small entities as
 that term is used in the RFA. Moreover,.
while all four small business concerns
would experience increased costs of
operation as a result of today's rule, the
 costs Of complying with the rule are also
 not significant. As a measure of the
 economic impact of today's
requirements, on a small entity, EPA
evaluated the costs of the rule relative
to the company's annual revenues. The
cost of the rule only exceeded one
percent of revenues for one of the
facilities and in no case did it exceed
three percent.

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  When the costs of the CWA rule are
considered in combination with the
costs of the final CAA MACTI and
MACT in rules, EPA's conclusion does
not change. EPA's analysis showed that
the combined costs of achieving
compliance with the final air and water
rules will not have a significant
economic impact on a.substantial
number of small entities. As noted
above, the CWA rule affects only four
small entities. Further, the combined
costs of the rules only exceeded one
percent of revenues for one of the four
small entities covered by both the final
air and water rules, and for no small
entity did it exceed three percent. Even
though this is a small cost, because of
the poor pre-existing economic
conditions at one facility, EPA projects
that one facility owned by one of the
small firms may close as a result of the
combined final CWA and CAA rules.
EPA has determined that one closure is
not a significant economic impact on a
substantial number of small business
concerns.
  Though not required by the RFA, EPA
also examined the costs of the final
CWA rule in combination with the costs
of the final MACT I and MACT ffl and
proposed MACT fl" rules. EPA's analysis
showed that the combined costs of
achieving compliance with the final air
and water rules and the proposed
MACT II rule would not have a
significant economic impact on a
substantial number of small entities.  As
stated before, only four small entities
would be affected. The combined cost of
the rules would only exceed one percent
of revenues for two small entities and
for no small entity covered by both the
final air and water rules and the
proposed air rule would it exceed three
percent. Even though this is a small
cost, because of the poor  pre-existing
economic conditions at one facility,
EPA projects that one facility owned by
one of the small firms may close as a
result of the final CWA and final and
proposed CAA rules.
  EPA's assessment of the impacts on
small businesses subject to the final
CAA rules yields similar results. EPA
evaluated the impacts of the costs of the
final MACT I and MACT in rules on
small businesses. Of the companies
affected by the two CAA rules, only 11
meet the SB A definition of "a small
business concern." EPA does not
believe this is a substantial number of
small entities as that term is used in the'
RFA. EPA has also examined the extent
of the impact on those 11 companies
and finds that the costs of complying
with the final MACT I rule and the final
MACT HI rule will not have a significant
economic impact on a substantial
                         number of small entities. In evaluating
                         the costs of the rules relative to the
                         company's annual revenues, EPA's
                         analysis shows that no company is
                         estimated to incur costs in excess of one
                         percent of its revenues as a result of
                         implementing the final MACT I and
                         MACT HI rules. As a consequence, EPA
                         finds that the CAA rule does not have
                         a significant economic impact on a
                         substantial number of small entities.
                           When the costs of the final MACT I
                         and MACT m rules are considered in .
                         combination with the costs of the final
                         CWA rule, EPA's analysis shows that
                         the combined costs of achieving
                         compliance with the final air and water
                         rules is still not a significant impact on
                         a substantial number of small entities.
                         As discussed, only 11 .small business
                         concerns must comply with the CAA
                         rule. Of these, only four will experience
                         additional costs due to the CWA rule..
                         The combined costs of the rules only
                         exceeded one percent of revenues for
                         one small entity covered by both the air
                         and water rules, and for no small entity
                         did it exceed three percent. Even though
                         this is a small cost, because of the poor
                         pre-existing economic conditions at one
                         facility, EPA projects that one facility
                         owned by one of the small firms may
                         close as a result of the combined final
                         CWA and CAA rules.
                           Though not required by the RFA, EPA
                         also assessed the cumulative economic
                         effect on small entities if the proposed
                         MACT rule is adopted. EPA's
                         conclusion that costs to small entities
                         are not great does not change when the
                         costs of the final and proposed MACT
                         rules are combined with the costs of the
                         final CWA rule. The combined cost of
                         the rules would only exceed one percent
                         of revenues for two small entities
                         covered by both the final air and water
                         rules and the proposed air rule,  and for
                         no small entity would it exceed three
                         percent. Even though this is a small
                         cost, because of the poor pre-existing
                         economic conditions at one facility,
                         EPA projects that one facility owned by
                         one of the small firms may close as a
                         result of the combined final CWA and
                         CAA rules.

                         D. Paperwork Reduction Act
                           The information collection
                         requirements in the air emissions rules
                         have been submitted for approval to the
                         Office of Management and Budget
                         (OMB) under the Paperwork Reduction
                         •Act,  44 U.S.C. 3501 etseq. An
                         Information Collection Request  (ICR)
                         document has been prepared by EPA
                         (ICR No. 1657.02), and a copy may be
                         obtained from Sandy Farmer, OPPE
                         Regulatory Information Division; U.S.
                         Environmental Protection Agency
(2137); 401 M St., SW.; Washington, DC
20460 or by calling (202) 260-2740. The
information requirements are not
effective until OMB approves them.
  The information required to be
collected by the air emission rules is
needed as part of the overall compliance
and enforcement program. It is
necessary to identify the regulated
entities who are subject to the rule and
ensure their compliance with, the rule.
The recordkeeping and reporting
requirements are mandatory and are  .
being established under section  114 of
the Clean Air Act.
  There are approximately 490
respondents that are potentially  affected
by the air emission rules. All 490
respondents must submit an initial
applicability notification. Of the 490
affected respondents, there would be an
estimated 155 respondents required to  •
perform additional information
collection. For.the 155 respondents, this
collection of information has an
estimated total annual recordkeeping
and reporting burden averaging 320
hours per respondent during the first
three years after promulgation. For the
155 respondents, the average annualized
cost of the reporting and recordkeeping
burden per respondent is $29,600 for
the first three years following
promulgation.
  The recordkeeping and reporting
burden means the total time, effort, or
financial resources expended by persons
to generate, maintain, retain, or disclose
or provide information to or for a
Federal agency. This includes the time
needed to review instructions; develop,
acquire, install, and utilize technology
and systems for the purposes of
collecting, validating, and verifying
information, processing and
maintaining information, and disclosing
and providing information; adjust the
existing ways to comply with any
previously applicable instructions and
requirements; train personnel to be able
to respond to a collection of
information; search data sources;
complete and review the collection of
information; and transmit or otherwise
disclose the information.
  Specifically, the estimated 155
respondents must submit performance
test notifications, statements of
compliance, and semi-annual reports of
monitored parameters.  The 155
respondents must also conduct
performance tests. If compliance
exceedances occur, respondents must
submit quarterly excess emissions
reports. This information will be used to
demonstrate compliance with the
NESHAP.
  Send comments on the Agency's need
for this information, the accuracy of the

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                                                                     18613
provided burden estimates, and any
suggested methods for minimizing
respondent burden, including through
the use of automated collection
techniques to the Director, OPPE
Regulatory Information Division; U.S.
Environmental Protection Agency
(2137); 401 M St., SW; Washington, DC
20460; and to the Office of Information
and Regulatory Affairs, Office of
Management and Budget, 725 17th St.,
NW, Washington, DC 20503, marked
' 'Attention: Desk Officer for EPA.''
Include the ICR number in any
correspondence.
  The effluent limitation guidelines and
standards promulgated today contain
two distinct information collection
activities, i.e., specified monitoring
requirements, see 40 CFR 430.02, and
development of BMP plans and related
monitoring, see 40 CFR 430.03(c) (4),
(c)(5), (c)(10), (d), (e), (f), (g), (h) and
(i) (4). EPA will seek approval of these
information collection requirements
from the Office of Management and
Budget (OMB) under the Paperwork
Reduction Act, 44 U.S.C. 3501 etseq,,
as follows. EPA will seek to amend the
NPDES Discharge Monitoring Report
ICR No. 229t OMB approval number
2040-0004, expiration May 31, 1998, to
add specified monitoring requirements
for direct dischargers. EPA will seek to
add the specified monitoring
requirements for indirect dischargers by
amending the National Pretreatment
Program ICR No. 2, OMB approval
number 2040-0009, prior to its
expiration on October 31, 1999. EPA
will seek approval of the Best
Management Practices ICR No. 1829.01
for the requirements pertaining to BMP
plans and associated monitoring. EPA's
burden estimates for the BMP ICR are
presented for comment in a document
published elsewhere in today's Federal
Register.
  An Agency may not conduct or
sponsor, and a person is not required to
respond to, a collection of information
unless it displays a currendy valid OMB
control number. The OMB control
numbers for EPA's regulations are listed
in 40 CFR parts 9 and 48 CFR chapter
15.
  In addition, direct discharging mills
continue to be required, under 40 CFR
122.21, to submit certain information as
part of their application for an NPDES
permit. Indirect discharging mills, in
turn, must submit industrial user
reports and periodic reports regarding
compliance with categorical
pretreatment standards under 40 CFR
403.12(b), (d), and (e). The  effluent
limitations guidelines and standards
being promulgated today do not change
those requirements. EPA notes that
 mills that describe their process as TCP
 or ECFunder 40 CFR 122.21(g)(3) or 40
 CFR 403.12(b), (d), or (e) as applicable,
 supply corroborating data if requested
 by the permitting authority under 40
 CFR 122.21(g)(13), and comply With the
 signatory and certification requirements
 in 40 CFR 122.22 or 40 CFR 403.12(1) as
 applicable will be deemed to have
 certified their process as TCP or ECF. In
 addition, direct discharging mills that
 indicate under 40 CFR  122.21 (g) (3) and
 (g)(13) their desire to participate in the
 Advanced Technology Incentives
 Program and comply with the signatory
 and certification requirements in 40
 CFR 122.22 or 40 CFR 122.23,
 whichever is applicable, will be deemed
 to have enrolled in the Advanced
 Technology Incentives Program. In both
 cases, this information will determine
 the types of technology-based effluent
 limitations and standards and the types
 of monitoring requirements^ if any, they
 will receive. OMB has approved the
 existing information collection .
 requirements associated with NPDES
 discharge permit applications and
 industrial user reports under the
 Paperwork Reduction Act, 44 U.S.C.
 3501, et seq. OMB has assigned OMB
 control number 2040-0086 to the
 NPDES permit application activity and
 OMB control numbers 2040-0009 and
 2040-0150 to the reporting and
 certification requirements for industrial
 users. Nothing in today's rule changes
 the burden estimates for these ICRs.
   All information submitted to the EPA
-for which a claim of confidentiality is
 made will be safeguarded according to
 the EPA policies set forth in Title 40,
 Chapter 1, Part 2, Subpart B—
 Confidentiality of Information (see 40
 CFR part 2; 41 FR 36902, September 1,
 1976; amended by 43 FR 39999,
 September 8, 1978; 43 FR 42241,   ,
 September 28, 1978; 44 FR 17674,
 March 23, 1979).
 E. Unfunded Mandates Reform Act
   Title H of the Unfunded Mandates
 Reform Act of 1995 (UMRA), P.L. 104-
 4, establishes requirements for Federal, .
 agencies to assess the effects of their
 regulatory actions on State, local, and
 tribal governments and the private
 sector. Under section 202 of the UMRA,
 EPA generally must prepare a written
 statement, including a cost-benefit
 analysis, for proposed and final rules
 with "Federal mandates" that may
 result in expenditures to State, local,
 and tribal governments, in the aggregate,
 or to the private sector, of $100 million
 or more in any one year. Before
 promulgating an EPA rule for which a
 written statement is needed, section 205
 of the UMRA generally requires EPA to
 identify and consider a reasonable
 number of regulatory alternatives and
 adopt the least costly, most cost-
 effective or least'burdensome alternative
 that achieves the objectives of the rule.
 The provisions of section 205 do not
. apply when they are inconsistent with
 applicable law. Moreover, section 205
 allows EPA to adopt an alternative other
 than the least costly, most cost-effective
 or least burdensome alternative if the
 Administrator publishes with the.final
 rule an explanation why that alternative
 was not adopted. Before EPA establishes
 any regulatory requirements that may
 significantly or uniquely affect small
 governments, including tribal
 governments, it must have developed
 under section 203 of the UMRA a small
 government agency plan. The plan must
 provide for notifying potentially
 affected small governments, .enabling
 officials of affected small governments
 to have meaningful and timely input in
 the development of EPA regulatory
 proposals with significant Federal'
 intergovernmental mandates, and
 informing, educating, and advising
 small governments on compliance with
 the regulatory requirements.
   EPA has determined that today's final
 rules contain a Federal mandate that
 may result in expenditures of $100
 million or more for the private sector in
 any one year. Accordingly, EPA has
 prepared the written statement required
 by section 202 of the UMRA. This
 statement is contained in the Economic
 Analysis for the rule (DCN  14649) and
 other support documents and is
 summarized below. In addition, EPA
 has determined that the rules contain no
 regulatory requirements that might
 significantly or uniquely affect small
 governments and therefore  are not
 subject to the requirement of section 203
 of the UMRA. The reasons for this
 finding are set forth below.
   EPA prepared several supporting
 analyses for the final rules. Throughout
 this preamble and in those supporting
 analyses, EPA has responded to the
 UMRA section 202 requirements.
 Considerations with respect to costs,
 benefits, and regulatory alternatives are
 addressed in the Economic Analysis
 (DCN 14649), which is summarized in
 Section VIQ of this preamble. A very
 brief summary follows.
   The statutory authorities for these
" rules are found in section 112 of the
 CAA and multiple sections of the CWA ,
 (see Section I for a list). In part, these.
> sections of the statutes authorize and
 direct EPA to issue regulations and
 standards to address air emissions and
 effluent discharges.
   EPA prepared a qualitative and
 quantitative cost-benefit assessment of

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the federal requirements imposed by
today's final rules. In large part, the
private sector, not other governments,
wHl incur the costs. Specifically, the
costs of this federal mandate are
compliance costs to be borne by the
regulated pulp and paper mills. In
addition, although some States and local
governments will  incur costs to
implement the standards, these costs to
governments will  not exceed the
thresholds established by UMRA. The
final rules are not expected to result in
significant or unique impacts to small
governments; the requirements are
consistent with established and already-
operating implementation programs.
  EPA estimates that the total
annualized costs for the private sector to
comply with the federal mandate are
S351 million (pre-tax)/S229 million
(post-tax). The mandate's benefits are
primarily in the areas of reduced health
risks and improved air and water
quality. The Economic Analysis (DCN
14649) describes, qualitatively, many
such benefits. The analysis then
quantifies a subset of the benefits and,
for a subset of the  quantified benefits,
EPA monetizes (i.e., places a dollar
value on) selected benefits. EPA's
estimates of the monetized benefits for
the final rules are  in the range of $39 to
$403 million.
  EPA does not believe that there will
be any disproportionate budgetary
effects of the rules on any particular
areas of the country, particular types of
communities, or particular industry
segments. EPA's basis for this finding is
its analysis of economic impacts, which
is summarized in Section VEH of the
preamble and in the Economic Analysis
(DCN 14649). A key feature of that
analysis is the estimation of financial
impacts for each facility incurring
compliance costs.  EPA considered the
costs, impacts, and other effects for
specific regions and individual
communities, and found no
disproportionate budgetary effects.
Although these final rules apply only to
one industry segment, EPA found no
disproportionate budgetary effect. (The
term segment as used in this context
refers to the industrial category of pulp,
paper,  and paperboard, and not to
individual subcategories within that
category; it is used differendy in other
sections of this preamble.) The
Economic Analysis (DCN 14649) also
describes the rules' effect on the
national economy in terms of effects on
productivity, economic growth, and
international competitiveness; EPA
found such effects to be minimal.
Although EPA has determined that
these rules do not contain requirements
that might significantly or uniquely
                          affect any State, local, or tribal
                          governments (see chapter 7), EPA
                          consulted with State and local air and
                          water pollution control officials. These
                          consultations primarily pertained to
                          implementation issues for States and
                          local governments. EPA's evaluation of
                          their comments is reflected in the final
                          rules.
                            For each regulatory decision in
                          today's rules, EPA has selected the
                          "least costly, most cost effective, or least
                          burdensome alternative" that was
                          consistent with the requirements of the
                          CAA and CWA. This satisfies section
                          205 of the UMRA. As part of this
                          rulemaking, EPA had identified and
                          considered a reasonable number of
                          regulatory alternatives. Primarily, the
                          regulatory alternatives are
                          manufacturing processes, air emission
                          controls, wastewater discharge controls,
                          and other technologies. Many of the •
                          alternatives are described above in
                          Section VI; others are described in
                          supporting documents. The Agency's
                          consideration of alternatives also
                          included an incentives program to
                          encourage bleached papergrade kraft
                          and soda mills to commit to pollution
                          prevention advances beyond the
                          requirements of the federal mandate.
                          See Section IX. The Agency's selection
                          from among these alternatives is
                          consistent with the requirements  of
                          UMRA, in terms of cost, cost-
                          effectiveness, and burden. Several
                          sections of the preamble are devoted to
                          describing the Agency's rationale for
                          each regulatory decision (e.g., Sections
                          VI.B.5.a(5) and VI.B.6.b(2)).
                            Finally, EPA has considered the
                          purpose and intent of the Unfunded
                          Mandates Reform Act and has
                          determined that these rules are needed,
                          not only because of the significant
                          pollutant reductions these rules will
                          achieve, see Section VII, but also to
                          satisfy EPA's obligations under the*
                          consent decree in Environmental
                          Defense Fund and Natural Wildlife
                          Federation v. Thomas, see Section
                          n.C.l.a, and EPA's CAA obligations.
                          F. Pollution Prevention Act
                            In the Pollution Prevention Act of
                          1990 (42 U.S.C. 13101 erseg., Public
                          Law 101-508, November 5,1990),
                          Congress declared pollution prevention
                          the national policy of the United States.
                          The Pollution Prevention Act declares
                          that pollution should be prevented or
                          reduced whenever feasible;, pollution
                          that cannot be prevented or reduced
                          should be recycled or reused in an
                          environmentally safe manner wherever
                          feasible; pollution that cannot be
                          recycled should be treated; and disposal
or release into the environment should
be chosen only as a last resort.
  Today's rules are consistent with this
policy. As described in section VI,
development of today's rules focused on
the pollution-preventing technologies
that some segments of the industry have
already adopted. Thus, a critical
component of the technology bases for
today's effluent limitations guidelines
and standards are process changes that
eliminate or substantially reduce the
formation of certain toxic chemicals.
EPA also employs process, changes as
the technology basis for the emission
standards.
G. Common Sense Initiative
  On August 19, 1994, the
Administrator established the Common
Sense Initiative (CS1) Council in
accordance with the Federal Advisory
Committee Act (5 U.S.C. Appendix 2,
Section 9 (c)) requirements. A principal
goal of the CSI includes developing
recommendations for optimal
approaches to multimedia controls for
industrial sectors including Petroleum
Refining, Metal Plating and Finishing,
Printing, Electronics and Computers,
Auto Manufacturing, and Iron 'and Steel
Manufacturing.
  The Pulp and Paper regulations were
not among the rulemaking efforts
included in the Common Sense
Initiative. However, many of the CSI
objectives have been incorporated into
these final rules, and the Agency
intends to continue to pursue these
objectives.
H. Executive Order 12875
  To reduce the burden of federal
regulations on States and small
governments, the President issued
Executive Order 12875 on October 28,
1993, entitled Enhancing the
Intergovernmental Partnership (58 FR
58093). In particular, this executive
order requires EPA to consult: with
representatives of affected State, local,
or tribal governments. While these rules
do not create mandates upon State,
local, or tribal governments, EPA
involved State and local governments in
their development. Because this
regulation imposes costs to the private
sector in excess of $100 million, the
EPA pursued the preparation of an
unfunded mandates statement and the
other requirements of the Unfunded
Mandates Reform Act. The requirements
are met as presented in the unfunded
mandate s section above.
I. Executive Order 12898
  Executive Order 12898 directs federal
agencies to "determine whether their
programs, policies, and activities have

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              Federal Register/Vol. 63, No.  72/Wednesday, April  15,  1998 /Rules and. Regulations      18615
  disproportionally high adverse human
  health or environmental effects on
  minority populations and low-income
  populations." (Sec.3-301 and Sec. 3-
  302). In developing the Cluster Rules,
  EPA analyzed the environmental justice
  questions raised by these rules. EPA
  conducted two analyses in 1996 to
  comply with Executive Order 12898 and
  to determine human health effects on
  minority and low-income populations.
   First, in a comparison of demographic
  characteristics, EPA found that there is
  no significant difference in ethnic
  makeup or income level of counties
  where bleached papergrade kraft and
  soda mills are located when compared
  to the States in which they are located.
  In fact, of the twenty-six States with
  bleached papergrade kraft and soda
  mills, fifteen States actually have lower
  minority populations (as a percentage of
  overall population) in mill counties
  than in the State as a whole, and sixteen
  States have a lower percent African-
  American population in mill counties
  than in their respective states. Fifteen
  States have a slightly larger portion of
  the population living below the poverty
  line in mill counties (15'percent
  average) when compared to the State as
  a whole (14.1 percent average);
  however, when EPA examined the
  results statistically, differences
  examined between mill counties and
  total State populations were not
  significant. Therefore, EPA has
  concluded that the regulatory decisions
  reflected in today's rules will not have
.  a disproportionately high adverse
  human health or environmental effect
  on minority populations or low-income
  populations.
   Second, EPA investigated the fish
  consumption characteristics of Native
  American populations downstream from
  pulp and paper mills. Of the 48 Native
  American tribes downstream from pulp
  mills, eight have special subsistence
 fishing rights. One finding from EPA's
  analysis is that members of five of these
 tribes have elevated risks of contracting
  cancer from consuming fish
  contaminated by dioxin, when
 compared to the general population and
 recreational anglers, because they
 consume fish at higher levels. EPA
 expects the final rule to reduce
 substantially the cancer risks to these
 tribal populations, as discussed in
 Chapter 8 of the Economic Analysis
  (DCN 14649).
 /. Submission to Congress and the
  General Accounting Office
   Under 5 U.S.C. 801 (a) (1) (A) as
 amended by the Small Business
 Regulatory Enforcement Fairness Act of
  1996 (SBREFA), EPA submitted a report
 containing this rule and other required
 information to the U.S. Senate, the U.S.
 House of Representatives and the
 Comptroller General of the General
 Accounting Office prior to publication
 of the rule in today's Federal Register.
 This rule is a "major rule" as defined by
 5 U.S.C. 804(2).

 K. National Technology Transfer and
 Advancement Act
   Under Section 12(d) of the National
 Technology Transfer and Advancement
 Act, the Agency is required to use
 voluntary consensus standards in its
 regulatory and procurement activities
 unless to do so would be inconsistent
 with applicable law or otherwise
 impractical. Voluntary consensus
 standards are technical standards (e.g.,
 materials specifications, test methods,
 sampling procedures, business
 practices, etc.) which are developed or
 adopted by voluntary consensus
 standards bodies. Where available and
 potentially applicable voluntary
 consensus standards are not used by
 EPA, the Act requires the Agency to
 provide Congress, through the Office of
 Management and Budget, an
 explanation of the reasons for not using
 such standards. This section
 summarizes EPA's response to the
 requirements of the NTTAA for the
.analytical test methods promulgated as
 part of today's effluent limitations
 guidelines and standards.
   EPA's analytical test method
 development is consistent with the
 requirements of the NTTAA. Although
 the Agency initiated data collection for
 these effluent guidelines many years
 prior to enactment of the NTTAA,
 traditionally, analytical test method
 development has been analogous to the
 Act's requirements for consideration
 and use of voluntary consensus r
 standards. EPA performed extensive
 literature searches to identify any
 analytical, methods from industry,
 academia, voluntary consensus
 standards bodies and other parties that
 could be used to measure the analytes
 in today's rulemaking. The results of
 this search formed the basis for EPA's
 analytical method development and
 validation in support of this rulemaking.
 Two new analytical test methods are
 being promulgated in today's final rule
 (see Section VI.B.4).
  The first method is EPA Method 1650
 for determination of adsorbable organic
 halides (AOX). Development of Method
 1650 began in 1989 to support data
gathering for regulation of pulp and
 paper industry discharges. This method
was developed by combining various
procedures contained in methods from
voluntary consensus standards bodies
 and other standards developing
 organizations such as German DIN
 standard 38 409, International Standard
 Organization (ISO) Method 9562,
 Scandinavian Method SCAN-W 9:89,
 Standard Method 5320 (published
 jointly by the American Public Health
 Association, the American Water Works
 Association and the Water Environment
 Federation), a method published by
 Environment Canada, EPA's Method
 9020 and EPA's interim Method 450.1.
 The foreign and international methods
 all employed the batch adsorption
 technique for determination of AOX; the
 U.S. methods all employed the column
technique. Nearly all data collected by
 the paper industry and others prior to
 development of Method 1650 were
 gathered using the column technique.
 Method 1650 allows use of both the
 batch and column techniques but
 contains restrictions on the batch
 technique specific to paper industry
 wastewaters, as detailed in the Method
 and as described above in Section VI.B.4
 and in EPA's responses to public
 comments  (DCN 14497, Vol. VII). In
 addition to the differences between
 adsorption techniques,  none of the
 existing methods, including those in
 voluntary consensus standards,
 contained the standardized quality
 control (QC) and QC acceptance criteria
 that EPA requires for data verification
 and validation in its water programs.
 EPA is therefore promulgating the new
 EPA Method 1650. .
  EPA is also promulgating EPA
Method 1653 for determination of
 chlorinated phenolics. Development of
Method 1653 also began in 1989 to
support data gathering for regulation of
pulp and paper  industry discharges.
This method was developed using
National Council of the Paper Industry
for Air and Stream Improvement
 (NCASI) Methods CP85.01 and CP86.01
as a starting point and adding the
necessary standardized  QC and QC
acceptance criteria. EPA Method 1653
and the NCASI methods employ in-situ
derivatization to assure that only
chlorophenolics are derivatized and
measured. The in-situ derivatization
technique allows only chlorophenolics
to be derivatized in the effluent and
leaves behind interfering analytes. This
condition is necessary for accurate
measurement of the relevant analytes.
Voluntary consensus standards methods
were not available for chlorophenolics
by in-situ derivatization. EPA is
therefore promulgating the new EPA
Method 1653.
  Dischargers are also required to
monitor for 2,3,7,8-tetrachlorodibenzo-
p-dioxto (dioxin; TCDD; 2,3,7,8-TCDD),
2,3,7,8-terrachlorodibenzofuran (TCDF;

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18616
Federal Register/Vol. 63, No. 72/Wednesday, April 15,  1998/Rules and Regulations
2.3,7,8-TCDF), chloroform, biochemical
oxygen demand (BOD), and total
suspended solids (TSS). Methods for
monitoring these pollutants are
specified in tables at 40 CFR part 136.
When available, methods published by
voluntary consensus standards bodies
are included in the list of approved
methods in these tables. Specifically,
voluntary consensus standards are
approved for the determination of
chloroform, BOD, and TSS (from the
18th edition of Standard Methods). In
addition, USGS methods are approved
for BOD and TSS.
  For TCDD and TCDF. EPA is
specifying the use of EPA Method 1613,
promulgated at 62 FR 48394 (September
15,1997). This method was developed
to support data gathering for regulation
of pulp and paper industry discharges
and incorporates procedures from EPA,
academia, industry (NCASI and the Dow
Chemical Co.) and a commercial
laboratory. There were no voluntary
consensus standards methods available
for these pollutants by high resolution
gas chromatography (HRGC) coupled
with high resolution mass spectrometry
(HRMS) at the time EPA Method 1613
was developed. Both HRGC and HRMS
are required to separately detect and
measure diojdn and furan isomers at
low concentrations (i.e., low parts per
quadrillion (ppq)). High resolution
techniques are necessary to conduct the
assay in the presence of interfering
analytes. EPA is unaware of the
existence of an HRGC/HRMS method
from a voluntary consensus standards
body for determination of TCDD and
TCDF in the low ppq range in pulp and
paper industry discharges.
XI. Background Documents
  The suirimary of public comments
and agency responses and the
environmental impacts statement for the
NESHAP are contained in the final
Background Information Document
(BID). A paper copy of the final
Background Information Document for
the NESHAP may be obtained from the
U.S. EPA Library (MD-35), Research
Triangle Park, North Carolina 27711,
telephone (919) 541-2777; or from the
National Technical Information
Services, 5285 Port Royal Road,
Springfield, Virginia 22151, telephone
(703) 487-4650. To obtain the final
Background Information Document,
please refer to "Pulp, Paper, and
Paperboard Industry—Background
Information for Promulgated Air
Emission Standards, Manufacturing
Processes at Kraft, Sulfite, Soda, Semi-
Chemical, Mechanical, and Secondary
                         and Non-wood Fiber Mills, Final EIS"
                         (EPA-453/R-93-050b). An electronic
                         copy of the final Background
                         Information Document is available from
                         the Technology Transfer Network
                         described in the SUPPLEMENTARY
                         INFORMATION section of this document.
                           Documents supporting the effluent
                         limitations guidelines and standards
                         may be obtained by contacting the
                         National Technical Information
                         Services, 5285 Port Royal Road,
                         Springfield, Virginia 22151, telephone
                         (703)487-4650. .
                           EPA's technical conclusions
                         concerning the wastewater regulations
                         are detailed in the "Supplemental
                         Technical Development Document for
                         Effluent Limitations Guidelines and
                         Standards for the Pulp, Paper, and
                         Paperboard Point Source Category"
                         (EPA-821-R-97-011, DCN 14487). The
                         Agency's economic analysis is found in
                         the "Economic Analysis for the National
                         Emissions Standards for Hazardous Air
                         Pollutants for Source Category: Pulp and
                         Paper Production; Effluent Limitations
                         Guidelines, Pretreatment Standards, and
                         New Source Performance Standards for
                         the Pulp, Paper, and Paperboard
                         Industry—Phase I," referred to as the
                         Economic Analysis (EPA-821-R-97-
                         012, DCN 14649). This document also
                         includes an analysis of the incremental
                         costs and pollutant removals for the
                         effluent regulations. Analytical methods
                         used in the development of the effluent
                         guidelines are found in "Analytical
                         Methods for the Determination of
                         Pollutants in Pulp and Paper Industry
                         Wastewater," a compendium of
                         analytical methods (EPA 821-B-97-00).
                         The environmental assessment is
                         presented in the "Water Quality
                         .Assessment of Final Effluent
                         Limitations Guidelines for the
                         Papergrade Sulfite  and Bleached
                         Papergrade Kraft and Soda
                         Subcategories of the Pulp, Paper, and
                         Paperboard Industry" (EPA-823-R-97-
                         009, DCN 14650). The statistical  '
                         analyses used in this  rulemaking are
                         detailed in the "Statistical Support
                         Document for the Pulp and Paper
                         Industry: SubpartB"  (DCN 14496). The
                         best management practices program is
                         presented in "Technical Support
                         Document for Best Management
                         Practices for Spent Pulping Liquor
                         Management, Spill Prevention, and
                         Control (DCN 14489), also referred to as
                         the BMP Technical Support Document.
                         The Advanced Technology Incentives
                         Program is presented in the "Technical
                         Support Document for the Voluntary
                         Advanced Technology Incentives
Program," (EPA-821-R-97-014, DCN
14488).

List of Subjects

40 CFR Part 63

  Environmental protection, Air
pollution control, Hazardous
substances. Reporting and
recordkeeping requirements.

40 CFR Part 261

  Hazardous waste, Recycling,
Reporting and recordkeeping
requirements.

40 CFR Part 430

  Paper and paper products industry,
Reporting and recordkeeping
requirements, Waste treatment and
disposal, Water pollution control.
  Dated: November 14,1997.
Carol M. Browner,
Administrator.

  For the reasons set out in the
preamble, title 40, chapter I of the Code
of Federal Regulations is amended as
follows:

PART 63—NATIONAL EMISSION
STANDARDS FOR HAZARDOUS AIR
POLLUTANTS FOR SOURCE-
CATEGORIES

  1. The authority citation for part 63
continues to read as follows:
  Authority: 42 U.S.C. 7401, etseq.

  2. Part 63 is amended by adding
subpart S to read as follows:

Subpart S—National Emission Standards
for Hazardous Air Pollutants from the Pulp
and Paper Industry
Sec.                .
63.440 Applicability.
63.441 Definitions.
63.442 [Reserved]
63.443 Standards for the pulping system at
    kraft, soda, and semi-chemical processes.
63.444 Standards for the pulping system at
    sulfite processes.
63.445 Standards for the bleaching system.
63.446 Standards for kraft pulping process
    condensates.
63.447 Clean condensate alternative.
63.448-63.449  [Reserved]
63.450 Standards for enclosures and closed-
    vent systems.
63.451-63.452  [Reserved]
63.453 Monitoring requirements.
63.454, Recordkeeping requirements.
63.455 Reporting requirements.
63.456 [Reserved]
63.457 Test methods and procedures.
63.458 Delegation of authority.
63.459 [Reserved]

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             Federal Register/Vol. 63, No. 72/Wednesday, April  15,  1998/Rules and Regulations      18617
Table 1 to SubpartS.—General Provisions
Applicability to Subpart S

Subpart S—National Emission
Standards for Hazardous Air Pollutants
from the Pulp and Paper Industry

§63.440  Applicability.
  (a) The provisions of this subpart
apply to the owner or operator of
processes that produce pulp, paper, or
paperboard; that are located at a plant
site that is a major source as defined in
§ 63.2 of subpart A of this part; and that
use the following processes and
materials:
  (1) Kraft, soda, stilfite, or semi-
'chemical pulping processes using, wood;
or
  (2) Mechanical pulping processes
using wood; or
  (3) Any process using secondary or
non-wood fibers.
  (b) The affected source to which the
existing source provisions of this
subpart apply is as follows:
  (1) For the processes specified in
paragraph (a) (1) of this section, the .
affected source is the total of all HAP
emission points in the pulping and
bleaching systems; or
  (2) For the processes specified in
paragraphs, (a) (2) or (a) (3) of this section,
the affected source is the total of all
HAP emission points in the bleaching
system.
  (c) The new source provisions of this
subpart apply to the total of all HAP
emission points at new or existing
sources as follows:
  (1) Each affected source defined in
paragraph (b) (1) of this section that
commences construction or
reconstruction after December 17,  1993;
  (2) Each pulping system or bleaching
system for the processes specified  in
paragraph (a)(l) of this section that
commences construction or
reconstruction after December 17,  1993; •
  (3) Each additional pulping or
bleaching line at the processes specified
in paragraph (a)(l) of this section, that
commences construction after December
17, 1993;
  (4) Each affected source defined in
paragraph (b) (2) of this section that
commences construction or  ;
reconstruction after March 8, 1996; or
  (5) Each additional bleaching line at  .
the processes specified in paragraphs
(a) (2) or (a) (3) of this section, that
commences construction after March 8,
1996.
  (d) Each existing source shall achieve
compliant no later than April 16, 2001,
except as provided in paragraphs (d)(l)
through (d)(3)  of this section.
  (1) Each kraft pulping system shall
achieve compliance with the pulping
system provisions of § 63.443 for the
equipment listed in § 63.443(a) (1) (ii)
through (a)(l)(v) as expeditiously as
practicable, but in no event later than
April 17, 2006 and the owners and
operators shall establish dates, update
dates, and report the dates for the
milestones specified in § 63.455(b).
  (2) Each dissolving-grade bleaching
system at either kraft or sulfite pulping
mills shall achieve compliance with the
bleach plant provisions of § 63.445 of
this subpart as expeditiously as
practicable, but in no event later than 3
years after the promulgation of the
revised effluent limitation guidelines
and standards under 40 CFR 430.14
through 430.17 and 40 CFR 430.44
through 430.47.
  (3) Each bleaching system complying
with the Voluntary Advanced
Technology Incentives Program for
Effluent Limitation Guidelines in 40
CFR 430.24, shall comply with the
requirements specified in either
paragraph (d)(3)(i) or (d)(3)(ii) of this
section for the effluent limitation
guidelines and standards in 40 CFR
430.24.
  (i) Comply with the bleach plant
provisions of §63.445 of this  subpart as
expeditiously as practicable, but in no
event later than April 16, 2001.
  (ii) Comply with all of the following:
  (A) The owner or operator of a
bleaching system shall comply with the
bleach plant provisions of § 63.445 of
this subpart as expeditiously  as
practicable, but in no event later than
April 15, 2004.
  (B) The owner or operator of a
bleaching system shall not increase the
application rate of chlorine or
hypochlorite in kg of bleaching agent
per megagram of ODP, in the  bleaching
system above the average daily rates
used over the three months prior to June
15,1998 until the requirements of '
paragraph (d)(3)(ii)(A) of this section are
met and record application rates as
specified in § 63.454 (c).
  (C) Owners and operators shall
establish dates, update dates, and report
the  dates for the milestones specified in
§63.455(b).
  (e) Each new source, specified as the
total of all HAP emission points for the
sources specified in paragraph (c) of this
section, shall achieve compliance upon
start-up or June 15, 1998, whichever is
later, as provided in §63.6(b) of subpart
A of this part.
  (f) Each owner or operator of an
affected source with affected process
equipment shared by more than one
type of pulping process, shall comply
with the applicable requirement in this ,
subpart that achieves the maximum
degree of reduction in HAP emissions.
   (g) Each owner or operator of an
 affected source specified in paragraphs
 (a) through (c) of this section must,
 comply with the requirements of
 subpart A—General Provisions of this
 part, as indicated, in table 1 to this
 subpart.

 §63.441  Definitions.
   All terms used in this subpart shall .
 have the meaning given them in the
 CAA, in subpart A of this part, and in
 this section as follows:
   Acid condensate storage tank means
 any storage tank containing cooking
 acid following the sulfur dioxide gas
 fortification process.
   Black liquor means spent cooking
 liquor,that'has been separated from the
 pulp produced by the kraft, soda, or
 semi-chemical pulping process.
   Bleaching means brightening of pulp
 by the addition of oxidizing,chemicals
 or reducing chemicals.
   Bleaching line means a group of
 bleaching stages arranged in series such
 that bleaching of the pulp progresses as
 the pulp moves from one stage to the
 next.                ,
   Bleaching stage means all process
 equipment associated with a discrete
 step of chemical application and
 removal in the bleaching process
 including chemical and steam mixers,
 bleaching towers, washers, seal (filtrate)
 tanks, vacuum pumps, and any other
 equipment serving the same function as
 those previously listed.
   Bleaching system means all process
 equipment after high-density pulp
 storage prior to the first application of
 oxidizing chemicals or reducing
 chemicals following the pulping system,
 up to and including the final bleaching
 stage.
   Boiler means any enclosed
 combustion device that extracts useful
 energy in the form of steam. A boiler is
 not considered a thermal oxidizer.
   Chip steamer means a vessel used for
 the purpose of preheating or pretreating
 wood chips prior to the digester, using
 flash steam from the digester or live
 steam.                 .         .
   Closed-vent system means a system
 that is not open to the atmosphere and
 is composed of piping, ductwork,
 connections, and, if necessary, flow-
 inducing devices that transport gas or
-vapor from an emission point to a
 control device.
   Combustion device means an
 individual unit of equipment, including
 but not limited to, a thermal oxidizer,
 lime kiln, recovery furnace, process
 heater, or boiler, used for the thermal
 oxidation of organic hazardous air  '
 pollutant vapors.

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 18618      Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules  and Regulations
   Decker system means all equipment
 used to thicken the pulp slurry or
 reduce its liquid content after the pulp
 washing system and prior to high-
 density pulp storage. The decker system
 includes decker vents, filtrate tanks,
 associated vacuum pumps, and any
 other equipment serving the same
 function as those previously listed.
   Digester system means each
 continuous digester or each batch
 digester used for the chemical treatment
 of wood or non-wood fibers. The
 digester system equipment includes
 associated flash tank(s), blow tank(s),
 chip steamer(s) not using fresh steam,
 blow heat recovery accumulator(s),
 relief gas condenser (s), prehydrolysis
 unit(s) preceding the pulp washing
 system, and any other equipment
 serving the same function as those
 previously listed. The digester system
 includes any of the liquid streams or
 condensates associated with batch or
 continuous digester relief, blow, or flash
 steam processes.
   Emission point means any part of a
 stationary source that emits hazardous
 air pollutants regulated under this
 subpart, including emissions from
 individual process vents, stacks, open
 pieces of process equipment, equipment
 leaks, wastewater and condensate
 collection and treatment system units,
 and those emissions that could
 reasonably be conveyed through a stack,
 chimney, or duct where such emissions
 first reach the environment.
   Evaporator system means all
 equipment associated with increasing
 the solids content and/or concentrating
 spent cooking liquor from the pulp
 washing system including pre-
 evaporators, multi-effect evaporators,
 concentrators, and vacuum systems, as
 well as associated condensers, hotwells,
 and condensate streams, and any other
 equipment serving the same function as
 those previously listed.
  Flow indicator means any device that
 indicates gas or liquid flow in an
 enclosed system.
  HAP means a hazardous air pollutant
 as defined in § 63.2 of subpart A of this
 part.
  High volume, low concentration or
 HVLC collection system means the gas
 collection and transport system used to
 convey gases from the HVLC system to
 a control device.
  High volume, low concentration or
 HVLC system means the collection of
 equipment including the pulp washing,
 knotter, screen, decker, and oxygen
 delignification systems, weak liquor
storage tanks, and any other equipment
serving the same function as those
previously listed.
  Knotter system means equipment
 where knots, oversized material, or
 pieces of uncooked "wood are removed
 from the pulp slurry after the digester
 system anc! prior to the pulp washing
 system. The knotter system equipment
 includes the knotter, knot drainer tanks,
 ancillary tanks, and any other
 equipment serving the same function as
 those previously listed.
  Kraft pulping means a chemical
 pulping process that uses a mixture of
 sodium hydroxide and sodium sulfide
 as the cooking liquor.
  Lime kiln means an enclosed
 combustion  device used to calcine lime
 mud, which consists primarily of
 calcium carbonate, into calcium oxide.
  Low volume, high concentration or
 LVHC collection system means the gas
 collection and transport system used to
 convey gases from the LVHC system to
 a control device.
  Low volume, high concentration or
 LVHC system means the collection of
 equipment including the digester,
 turpentine recovery, evaporator, steam
 stripper systems, and any other
 equipment serving the same function as
 those previously listed.
  Mechanical pulping means a pulping
 process that  only uses mechanical and
 thermo-mechanical processes to reduce
 wood to a fibrous mass. The mechanical
 pulping processes include, but are not
 limited to, stone groundwood,
 pressurized groundwood, refiner
 mechanical,  thermal refiner mechanical,
 thermo-mechanical, and tandem
 thermo-mechanical.
  Non-wood pulping means the
 production of pulp from fiber sources
 other than trees. The non-wood fiber
 sources include, but are not limited to,
 bagasse, cereal straw, cotton, flax straw,
 hemp, jute, kenaf, and leaf fibers.
  Oven-dried pulp or ODP means a pulp
 sample at zero percent moisture content
 by weight. Pulp samples for
 applicability or  compliance
 determinations for both the pulping and
 bleaching systems shall be unbleached
 pulp. For purposes of complying with
 mass emission limits in this subpart,
 megagram of ODP shall be measured to
 represent the amount of pulp entering
 and processed by the equipment system
 under the specified mass limit. For
 equipment that does not process pulp,
 megagram of ODP shall be measured to
represent the amount of pulp that was
 processed to produce the gas and liquid
streams.
  Oxygen delignification system means
the equipment that uses oxygen to
remove lignin from pulp after high-
density stock storage and prior to the
bleaching system. The oxygen
delignification system equipment
 includes the blow tank, washers, filtrate
 tanks, any interstage pulp storage tanks,
 and any other equipment serving the
 same function as those previously
 listed.
  Primary fuel means the fuel that
 provides the principal heat input to the
 combustion device. To be considered
 primary, the fuel must be able to sustain
 operation of the combustion device
 without the addition of other fuels.
  Process wastewater treatment system
 means a collection of equipment, a
 process, or specific technique that  .
 removes or destroys the HAP'is in a
 process wastewater stream. Examples
 include, but are not limited to, a steam
 stripping unit, wastewater thermal
 oxidizer, or biological treatment unit.
  Pulp washing system means, all
 equipment used to wash pulp and
 separate spent cooking chemicals
 following the digester system and prior
 to the bleaching system, oxygen,
 delignification system, or paper
 machine system (at unbleached mills).
 The pulp washing system equipment
 includes vacuum drum washers,
 diffusion washers, rotary pressure
 washers, horizontal belt filters;,
 intermediate stock chests, and. their
 associated vacuum pumps, filtrate
 tanks, foam breakers or tanks, and any
 other equipment serving the same
 function as those previously listed. The
 pulp washing system does not include
 deckers, screens, knotters, stock chests,
 or pulp storage tanks following the  last
 stage of pulp washing.
  Pulping ilne means a group of
 equipment arranged  in series such that
 the wood chips are digested and the
 resulting pulp progresses through a
 sequence of steps that may include
 knotting, refining, washing, thickening,
 blending, storing, oxygen
 delignification, and any other
 equipment serving the same function as
 those previously listed.
  Pulping process condensates means
 any HAP-containing liquid that results
 from contact of water with organic
 compounds in the pulping process.
 Examples of process condensates
 include  digester system condensates,
 turpentine recovery system condensates,
 evaporator system condensates, LVHC
 system condensates,  HVLC system
 condensates, and any other condensates
from equipment serving the same
function as those previously listed.
 Liquid streams that are intended for
 byproduct recovery are not considered
 process condensate streams.
  Pulping system means all process
 equipment, beginning with the digester
system, and up to and including the last
piece of pulp conditioning equipment
prior to the bleaching system, including

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             Federal Register/Vol. 63, No. 72/Wednesday, April  15,  1998/Rules and Regulations
                                                                     18619
 treatment with ozone, oxygen, or
 peroxide before the first application of
 a chemical bleaching agent intended to
 brighten pulp. The pulping system
 includes pulping process condensates
. and can include multiple pulping lines.
   Recovery furnace means an enclosed
 combustion device where concentrated
 spent liquor is burned to recover
 sodium and sulfur, produce steam, and
 dispose of unwanted dissolved wood
 components in the liquor.
   Screen system means equipment in
 which oversized particles are removed
 from the pulp slurry prior to the
 bleaching or papermaking system
 washed stock storage.
   Secondary fiber pulping means a
 pulping process that converts a fibrous
 material, that has previously undergone
 a manufacturing process, into pulp
 stock through the addition of water and
 mechanical energy. The mill then uses
 that pulp as the raw material in another
. manufactured product. These mills may
 also utilize chemical, heat, and
 mechanical processes to remove ink ,
 particles from the fiber stock.
   Semi-chemical pulping means a
•pulping process that combines both
 chemical and mechanical pulping
 processes. The semi-chemical pulping
• process produces intermediate yields
 ranging from 55 to 90 percent.
   Soda pulping means a chemical
 pulping process that uses sodium
 hydroxide as the active chemical in the
 cooking liquor.
   Spent liquor means process liquid
 generated from the separation of
 cooking liquor from pulp by the pulp  \
 washing system containing dissolved
 organic wood materials and residual
 cooking compounds.
   Steam stripper system means a
 column (including associated stripper
 feed tanks, condensers, or heat
 exchangers) used to remove compounds
 from wastewater or condensates using
 steam. The steam stripper system also
 contains all equipment associated with
 a methanol rectification process
 including rectifiers, condensers,
• decanters, storage tanks, and any other
 equipment serving the same function as
 those previously listed.
   Strong liquor storage tanks means all
 storage tanks containing liquor that has
 been concentrated in preparation for
 combustion or oxidation in the recovery
 process.
   Sulfite pulping means a chemical
 pulping process that uses a mixture of
 sulfurous acid and bisulfite ion as the
 cooking liquor.
   Temperature monitoring device
 means a piece of equipment used to
 monitor temperature and having an
 accuracy of ±1.0 percent of the
 temperature being monitored expressed
 in degrees Celsius or ±0.5 degrees
 Celsius (°C), whichever is greater.
   Thermal oxidizer means an enclosed
 device that destroys organic compounds
 by thermal oxidation.
   Turpentine recovery system means all
 equipment associated with recovering
 turpentine from digester system gases
 including condensers, decanters, storage
 tanks, and any other equipment serving
 the same function as those previously
 listed. The turpentine recovery system
 includes any liquid streams associated
 with the turpentine recovery process
 such as turpentine decanter underflow.
 Liquid streams that are intended for
 byproduct recovery are not considered
 turpentine recovery system condensate
 streams.
   Weak liquor storage tank means any
 storage tank except washer filtrate tanks
 containing spent liquor recovered from
 the pulping process and prior to the
 evaporator system.

 §63.442  [Reserved]

 § 63.443  Standards for the pulping system
 at kraft, soda, and semi-chemical
 processes.
  (a) The owner or operator of each
 pulping system using the kraft process
 subject to the requirements of this
 subpart shall control the total HAP
 emissions from the following equipment
 systems, as specified in paragraphs (c)
 arid (d) of this section.
  (1) At existing affected sources, the
 total HAP emissions from the following
 equipment systems shall be controlled:
  (i) Each LVHC system;
  (ii) Each knotter or screen system with
 total HAP mass emission rates greater
 than or equal to the rates specified in
 paragraphs (a)(l)(ii)(A) or (a)(l)(ii)(B) of
 this section or the combined rate
 specified in paragraph (a) (1) (ii) (C) of'
 this section.
  (A) Each knotter system with
 emissions of 0.05 kilograms or more of
 total HAP per megagram of ODP (0.1
.pounds per ton).
  (B) Each screen system with
 emissions of 0.10 kilograms or more of
 total HAP per megagram of ODP (0.2
 pounds per ton).
  (C) Each knotter and screen system
 with emissions of 0.15 kilograms or'
 more of total HAP per megagram of ODP
 (0.3 pounds per ton).
  (iii) Each pulp washing system;
  (iv) Each decker system that:
  (A) Uses any process water other than
 fresh water or paper machine white
 water; or
  (B) Uses any process water with a
 total HAP concentration greater than
 400 parts per million by weight; and
   (v) Each oxygen delignification
 system.
   (2) At new affected sources, the total
 HAP emissions from the equipment
 systems listed in paragraphs (a)(l)(i),
 (a) (1) (iii), and (a) (1) (v) of this section
 and the following equipment systems
 shall be controlled:
   ,(i) Each knotter system;
   (ii) Each screen system;
   (iii) Each decker system; and
   (iv) Each weak liquor storage tank.
   (b) The owner or operator of each .
 pulping system using a semi-chemical
 or soda process subject to the
 requirements of this subpart shall
 control the total HAP emissions from
 the following equipment systems as    ;
 specified in-paragraphs (c) and (d) of
 this section.      .
   (1) At each existing affected sources,
 the total HAP emissions from each
 LVHC .system shall be controlled.
   (2) At each new affected source, the
 total HAP emissions from each LVHC
 system and each pulp washing system
 shall be controlled.
   (c) Equipment systems listed in
 paragraphs (a) and (b) of this section
 shall be enclosed and vented into a
 closed-vent system and routed to a
 control device that meets the
 requirements specified in paragraph (d)
 of this section. The enclosures and
 closed-vent system shall meet the
 requirements specified in § 63.450.
   (d) The control device used to reduce
 total HAP emissions from each
 equipment system listed in paragraphs
 (a) and (b) of this se'ction shall:
   (1) Reduce total HAP emissions by 98
 percent or more by weight; or
   (2) Reduce the total HAP
 concentration at the outlet of the
 thermal oxidizer to 20 parts per million
 or less by volume, corrected to 10
 percent oxygen on a dry basis; or
   (3) Reduce total HAP emissions using
 a thermal oxidizer designed and
• operated at a minimum temperature of
 871 °C (1600 °F) and a minimum
 residence time of 0.75 seconds; or
   (4) Reduce total HAP emissions using
 a boiler, lime kiln, or recovery furnace
 by introducing the HAP emission stream
 with the primary fuel or into the flame
 zone.                    • ,  •"
   (e) Periods of excess emissions •
 reported under § 63.455 shall not be a.
 violation of §63.443 (c) and (d)
 provided that the time of excess  .
 emissions (excluding periods of startup,
• shutdown, or malfunction) divided by
 the  total process operating time in a
 semi-annual reporting period does not
 exceed the following levels:
   (1) One percent for control devices
 used to reduce the total HAP emissions
 from the LVHC system; and

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18620
Federal Register/Vol. 63, No. 72/Wednesday, April 15,  1998/Rules and Regulations
  (2) Four percent for control devices
used to reduce the total HAP emissions
from the HVLC system; and
  (3) Four percent for control devices
used to reduce the total HAP emissions
from both the LVHC and HVLC systems.

§ 63.444 Standards for the pulping system
at sulfite processes.
  (a) The owner or operator of each
sulfite process subject to the
requirements of this subpart shall
control the total HAP emissions from
the following equipment systems as
specified in paragraphs (b) and (c) of
this section.
  (1) At existing sulfite affected sources,
the total HAP emissions from the
following equipment systems shall be
controlled:
  (1) Each digester system vent;
  (ii) Each evaporator system vent; and
  (Hi) Each pulp washing system.
  (2) At new affected sources, the total
HAP emissions from the equipment
systems listed in paragraph (a)(l) of this
section and the following equipment
shall be controlled:
  (i) Each weak liquor storage tank;
  (ii) Each strong liquor storage tank;
and
  (iii) Each acid condensate storage
tank.
  (b) Equipment listed in paragraph (a)
of this section shall be enclosed and
vented into a closed-vent system and
routed to a control device that meets the
requirements specified in paragraph (c)
of this section. The enclosures and
closed-vent system shall meet the
requirements specified in § 63.450.
Emissions from equipment listed in
paragraph (a) of this section that is not
necessary to be reduced to meet
paragraph (c) of this section is not
required to be routed to a control,
device.
  (c) The total HAP emissions from both
the equipment systems listed in
paragraph (a) of this section and the
vents, wastewater, and condensate
streams from the control device used to
reduce HAP emissions, shall be
controlled as follows.
  (1) Each calcium-based or sodium-
based sulfite pulping process shall:
  (i) Emit no more than 0.44 kilograms
of total HAP or methanol per megagram
(0.89 pounds per ton) of ODP; or
  (ii) Remove 92 percent or more by
weight of the total HAP or methanol.
  (2) Each magnesium-based or
ammonium-based sulfite pulping
process shall:
  (i) Emit no more than 1.1 kilograms of
total HAP or methanol per megagram
(2.2 pounds per ton) of ODP; or
  (ii) Remove 87 percent or more by
weight of the total HAP or methanol.
                          §63.445  Standards for the bleaching
                         , system.
                            (a) Each bleaching system that does
                          not use any chlorine or chlorinated
                          compounds for bleaching is. exempt
                          from the requirements of this section.
                          Owners or operators of the following
                          bleaching systems shall meet all the
                          provisions of this section:
                            (1) Bleaching systems that use
                          chlorine;
                            (2) Bleaching systems bleaching pulp
                          from kraft, sulfite, or soda pulping
                          processes that uses any chlorinated
                          compounds; or
                            (3) Bleaching systems bleaching pulp
                          from mechanical pulping processes
                          using wood or from any process using
                          secondary or non-wood fibers, that use
                          chlorine dioxide.
                            (b) The equipment at each bleaching
                          stage, of the bleaching systems listed in
                          paragraph (a) of this section, where
                          chlorinated compounds are introduced
                          shall be enclosed and vented into a
                          closed-vent system and routed to a
                          control device that meets the
                          requirements specified in paragraph (c)
                          of this section. The enclosures and
                          closed-vent system shall meet the
                          requirements specified in § 63.450.
                            (c) The control device used to reduce
                          chlorinated HAP emissions (not
                          including chloroform) from the
                          equipment specified in paragraph  (b) of
                          this section shall:
                            (1) Reduce the total chlorinated HAP
                          mass in the vent stream entering the
                          control device by 99 percent or more by
                          weight;
                            (2) Achieve a treatment device outlet
                          concentration of 10 parts per million or
                          less fay volume of total chlorinated HAP;
                          .or
                            (3) Achieve a treatment device outlet
                          mass emission rate of 0.001 kg of total
                          chlorinated HAP mass per megagram   .
                          (0.002 pounds per ton) of ODP.
                            (d) The owner or operator of each
                          bleaching system subject to paragraph
                          (a) (2) of this section shall comply with
                          paragraph (d)(l) or (d)(2) of this section
                          to reduce chloroform air emissions to
                          the atmosphere, except the owner or
                          operator of each bleaching system
                          complying with extended compliance
                          under § 63.440 (d) (3) (ii) shall comply
                          with paragraph (d) (1) of this section.
                            (1) Comply with the following
                          applicable effluent limitation guidelines
                          and standards specified in 40 CFR part
                          430:
                            (i) Dissolving-grade kraft bleaching
                          systems and lines, 40 CFR 430.14
                          through 430.17;
                            (ii) Paper-grade kraft and soda
                          bleaching systems and lines, 40 CFR
                          430.24(a)(l)  and (e), and 40 CFR 430.26
                          (a) and (c);           ,
  (iii) Dissolving-grade sulfite bleaching
systems and lines, 40 CFR 430.44
through 430.47; or
  (iv) Paper-grade sulfite bleaching
systems and lines, 40 CFR 430.54(a) and
(c), and 430.56(a) and (c).
  (2) Use no hypochlorite or chlorine
for bleaching in the bleaching system or
line.

§63.446 Standards for kraft pulping
process condensates.
  (a) The requirements of-this section
apply to owners or operators of kraft
processes subject to the requirements of
this subpart.
  (b) The pulping process condensates
from the following equipment systems
shall be treated to meet the
requirements specified in paragraphs
(c), (d), and (e) of this section:
  (1) Each digester system;
  (2) Each turpentine recovery system;
  (3) Each evaporator stage where weak
liquor is introduced (feed stages) in the
evaporator system;
  (4) Each HVLC collection system; and
  (5) Each LVHC collection system.
  (c) One of the following combinations
of HAP-containing pulping process
condensates generated, produced, or
associated with the equipment systems
listed in paragraph (b) of this section
shall be subject to the requirements of
paragraphs (d) and (e) of this section:
  (1) All pulping process condensates
from the equipment systems specified in
paragraphs (b)(l) through (b)(5) of this
section.  ,
  (2) The combined pulping process
condensates from the equipmient
systems specified in paragraphs (b) (4)
and (b) (5) of this section, plus pulping
process condensate stream(s)  that in
total contain at least 65 percent of the
total HAP mass from the pulping
process condensates from equipment
systems listed in paragraphs (b) (1)
through (b)(3) of this section.
  (3) The pulping process condensates
from equipment systems listed in
paragraphs (b)(l) through (b)(5) of this
section that in total contain a.total HAP
mass of 3.6 kilograms or more of total
HAP per megagram (7.2 pounds per ton)
of ODP for mills that do not perform
bleaching or 5.5 kilograms or more of
total HAP per megagram (11.1 pounds
per ton) of ODP for mills that perform
bleaching.
  (d) The pulping process condensates
from the equipment systems listed in   ,
paragraph (b)  of this section shall be
conveyed in a closed collection system
that is designed and operated to meet
the requirements specified in
paragraphs (d)(l) and (d)(2) of this
section.
  (1) Each closed collection system
shall meet the individual drain system

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             Federal Register/Vol.  63,  No. 72/Wednesday. April 15. 1998/Rules and Regulations      18621
 requirements specified in § 63.960,
 63.961, and 63.962 of subpart RR of this
 part, except for closed vent systems and
 control devices shall be designed and
 operated in accordance with
 §§63.443(d) and 63.450, instead of in
 accordance with § 63.693 as specified in
 §63.962 (a)(3)(ii), (b)(3)(ii)(A), and
                      '
   (2) If a condensate tank is used in the
 closed collection system, the tank shall
 meet the following requirements:
   (i) The fixed roof and all openings
 (e.g., access hatches, sampling ports,
 gauge wells) shall be designed and
 operated with no detectable leaks as  •
 indicated by an instrument reading of
 less than 500 parts per million above
 background, and vented into a closed-
 vent system that meets the requirements
 in § 63.450 and routed to a control
 device that meets the requirements  in
 §63.443(d);and
   (ii) Each opening shall be maintained
 in a closed, sealed position (e.g.,
 covered by a lid that is gasketed and
 latched) at all times that the tank
 contains pulping process condensates or
 any HAP removed from a pulping
 process condensate stream except when
 it is necessary to use the opening for
 sampling, removal, or for equipment
 inspection, maintenance, or repair.
   (e) Each pulping process condensate
 from the equipment systems listed in
 paragraph (b) of this section shall be
 treated according to one of the following
 options:
   (1) Recycle the pulping process
 condensate to an equipment system
 specified in § 63.443 (a) meeting the
 requirements specified in § 63.443(c)
 and (d); or
   (2) Discharge the pulping process
 condensate below the liquid surface of
 a biological treatment system meeting
 the requirement specified in paragraph
 (e) (3) of this section; or
  (3) Treat the pulping process,
 condensates to reduce or destroy the
 total HAP's by at least 92 percent or
 more by weight; or
  (4) At mills that do not perform
 bleaching, treat the pulping process
 condensates to remove 3.3 kilograms or
 more of total HAP per megagram (6.'6
 pounds per ton) of ODP, or achieve  a
total HAP-concentration of 210 parts per
million or less by weight at the outlet of
the control device; or
  (5) At mills that perform bleaching,
treat the pulping process condensates to
remove 5. 1 kilograms or more of total
HAP per megagram (10.2 pounds per
ton) of ODP, or achieve a total HAP
concentration of 330 parts per million or
less by weight at the outlet of the
control device.
  .(f) Each HAP removed from a pulping
 process condensate stream during
 treatment and handling under
 paragraphs (d) or (e) of this section,
 except for those treated according to
 paragraph (e)(2) of this section, shall be
 controlled as specified in § 63.443(c)
,and(d).
  (g) For each steam stripper system
 used to comply with the requirements
 specified in paragraph (e)(3) of this
 section, periods of excess emissions
 reported under § 63.455 shall not be a
 violation of paragraphs (d), (e), and (f)
 of this section provided that the time of
 excess emissions (including periods of
 startup, shutdown, or malfunction)
 divided by the total process operating
 time in a semi-annual reporting period
 does not exceed 10 percent.
  (h) Each owner or operator of a new
 or existing affected source subject to the
 requirements of this section shall
 evaluate all new or modified pulping
 process condensates or changes in the
 annual bleached or non-bleached ODP
 used to comply with paragraph (i) of
 this section, to determine if they meet
 the applicable requirements of this
 section.
  (i) For the purposes of meeting the
requirements in paragraphs (c).(2). (e)(4),
 or (e) (5) of this section at mills
 producing both bleached and
unbleached pulp products, owners and
operators may meet a prorated mass
standard that is calculated by prorating
the applicable mass standards
 (kilograms of total HAP per megagram of
ODP) for bleached and unbleached
specified in paragraphs (c) (2), (e) (4), or
 (e)(5) of this section by the ratio of
annual megagrams of bleached and
unbleached ODP.

§ 63.447  Clean condensate alternative.
  As an alternative to the requirements
specified in § 63.443(a)(1) (ii) through
(a) (1) (v) for the control of HAP .
emissions from pulping systems using
the  kraft process, an owner or operator
must demonstrate to the satisfaction of
the  Administrator, by meeting all the
requirements  below, that the total HAP
emissions reductions achieved by this
clean condensate alternative technology
are  equal to or greater than the total
HAP emission reductions that would
have been achieved by compliance with
§63.443(a)(l)(ii) through (a)(l)(v),
  (a) For the purposes of this section
only the-following additional
definitions apply.
  (1) Clean condensate alternative
affected source means the total of all
HAP emission points in the,-pulping,
bleaching, causticizing, and
papermaking systems (exclusive of HAP
emissions attributable to additives to
 paper machines and HAP emission
 points in the LVHC system).           ,
   (2) Causticizing system means all
 equipment associated with converting
 sodium carbonate into active sodium
 hydroxide. The equipment includes
 smelt dissolving tanks, lime mud
 washers and storage tanks, white and   .
 mud liquor clarifiers and storage tanks,
 slakers, slaker grit washers, lime kilns,
 green liquor clarifiers and storage tanks,
 and dreg washers ending with the white
 liquor storage tanks prior to the digester
 system, and any other equipment
 serving the same function as those
 previously listed.
   (3) Papermaking system means'all
 equipment used to  convert pulp into
 paper, paperboard,  or market pulp,
 including the stock storage and
 preparation systems, the paper or
 paperboard machines, and die paper
 machine white water system, broke
 recovery systems, and the systems
 involved in calendering, drying, on-
 machine coating, slitting, winding, and
 cutting.
   (b) Each owner or operator shall
 install and operate a clean condensate
 alternative technology with a
 continuous monitoring system to reduce
 total HAP emissions by treating and
 reducing HAP concentrations in the
 pulping process water used within the
 clean condensate alternative'affected
 source.
   (c) .Each owner or operator shall
 calculate HAP emissions on a kilogram
 per megagram of ODP basis and measure
' HAP emissions according to the
 appropriate procedures contained in
 §63.457.
   (d) Each owner or operator shall
 determine the baseline HAP emissions
 for each equipment system and the total
 of all equipment systems in the clean
 condensate alternative affected source
 based on the following:
   (1) Process and air pollution control
 equipment installed and operating on or
 after December 17, 1993, and
   (2) Compliance with the following
 requirements that affect the level of
 HAP emissions from the clean
 condensate alternative affected source:
   (i) The pulping process condensates
 requirements in § 63.446;
   (ii) The applicable effluent limitation
 guidelines and standards in 40 CFR part
 430, subparts A, B, D, and E; and
   (iii) All other applicable requirements
 of local, State, or Federal agencies or
 statutes.
   (e) Each owner or operator shall
 determine the following HAP emission
 reductions from .the baseline HAP
 emissions determined in paragraph (d)
 of this section for .each equipment
 system and the total of all equipment

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18622      Federal Register/Vol. 63, No.  72/Wednesday, April 15, 1998/Rules  and Regulations
systems in the clean condensate
alternative affected source:
  (1) The HAP emission reduction
occurring by complying with the
requirements of § 63,443(a) (1) (ii)
through (a) (1) (v); and
  (2) The HAP emissions reduction that
occurring by complying with the clean
condensate alternative technology.
  (f) For the purposes of all
requirements in this section, each owner
or operator may use as an alternative,
individual equipment systems (instead
of total of all equipment systems) within
the clean condensate alternative affected
source to determine emissions and
reductions to demonstrate equal or
greater than the reductions that would
have been achieved by compliance with
§ 63.443(a) (1) (ii) through (a) (1) (v). =
  (g) The initial and updates to the
control strategy report specified in
§ 63.455(b)  shall include to the extent
possible the following information:
  (1) A detailed description of:
  (i) The equipment systems and
emission points that comprise the clean
condensate alternative affected source;
  (ii) The air pollution control
technologies that would be used to meet
the requirements of § 63.443 (a) (1) (ii)
through (a)(l)(v);
  (iii) The clean condensate alternative
technology to be used.
  (2) Estimates and basis for the
estimates of total HAP emissions and
emissions reductions to fulfill the
requirements paragraphs (d), (e), and (f)
of this section.
  (h) Each owner or operator shall
report to the Administrator by-the
applicable compliance date specified in
§63.440(d) or (e) the rationale,
calculations, test procedures, and data
documentation used to demonstrate
compliance with all the requirements of
this section.

§§63.448-63.449  [Reserved]
§ 63.450  Standards for enclosures and
closed-vent systems.
  (a) Each enclosure and closed-vent
system specified in §§ 63.443(c),
63.444 (b), and 63.445(b) for capturing
and transporting vent streams that
contain HAP shall meet the
requirements specified in paragraphs (b)
through (d) of this section.
  (b) Each enclosure shall maintain
negative pressure at each enclosure or
hood opening as demonstrated by the
procedures specified § 63.457(e). Each
enclosure or hood opening closed
during the initial performance test
specified in § 63.457(a) shall be
maintained in the same closed and
sealed position as during the
performance test at all times except
when necessary to use the opening for
sampling, inspection, maintenance, or
repairs.
  (c) Each component of the closed-vent
system used to comply with
§§63.443(c), 63.444(b), and 63.445(b)   ,
that is operated at positive pressure and
located prior to a control device shall be
designed for and operated with no
detectable leaks as indicated by an
instrument reading of less than 500
parts per million by volume above
background, as measured by the
procedures specified in § 63.457(d).
  (d) Each bypass line in the closed-
vent system that could divert vent
streams containing HAP to the
atmosphere without meeting the
emission limitations in §§ 63.443,
63.444, or 63.445 shall comply with
either of the following requirements:
  (1) On each bypass line, the owner or
operator shall install, calibrate,
maintain, and operate according to
manufacturer's specifications a flow
indicator that provides a record of the
presence of gas stream flow in the
bypass line at least once every 15
minutes.  The flow indicator shall be
installed in the bypass line in such a
way as to indicate flow in the bypass
line; or
  (2) For bypass line valves that are not
computer controlled, the owner or
operator shall maintain the bypass line
valve in the closed position with a car
seal or a seal placed on the valve or
closure mechanism in such a way that
valve or closure mechanism cannot be
opened without breaking the seal.

§§63.451-63.452 [Reserved]

§63.453  Monitoring requirements.
  (a) Each owner or operator subject to
the standards specified in §§ 63.443 (c)
and (d), 63.444(b) and (c), 63.445(b) and
(c), 63.446(c). (d), and (e), 63.447(b) or
§ 63.450(d), shall install, calibrate,
certify, operate, and maintain according
to the manufacturer's specifications, a
continuous monitoring system (CMS, as
defined in § 63.2 of this part) as
specified in paragraphs (b) through (m)
of this section, except as allowed in
paragraph (m) of this section. The CMS
shall include a continuous recorder.
  (b) A CMS shall be operated to
measure the temperature in the firebox
or in the ductwork immediately
downstream of the firebox and before
any substantial heat exchange occurs for
each thermal oxidizer used to comply
with the requirements of § 63.443 (d) (1)
through (d)(3). Owners and operators
complying with the requirements in
§ 63.443 (d) (2) or (d) (3) shall monitor the
parameter specified and for the
 temperature and concentration limits
 specified.
   (c) A CMS shall be operated to   ,
 measure the following parameters for
 each gas scrubber used to comply with
 the bleaching system requirements of
 § 63.445 (c) or the'sulfite pulping system
 requirements of §63.444(c).
   (1) The pH or the oxidation/reduction
 potential of the gas scrubber effluent;
   (2) The gas scrubber vent gas inlet
 flow rate; and
   (3) The gas scrubber liquid influent
 flow rate.
   (d) As an option to the requirements
 specified in paragraph (c) of this
 section, a CMS shall be operated to
 measure the chlorine outlet
 concentration of each gas scrubber used
 to comply with the bleaching system
 outlet concentration requirement
 specified in § 63.445 (c) (2).
   (e) The owner or operator of a
 bleaching system complying with 40
 CFR 430.24, shall monitor the chlorine
 and hypochlorite application rates, in  kg
 of bleaching agent per megagram of
 ODP, of the bleaching system during the
 extended compliance period specified
 in§63.440(d)(3).
   (f) A CMS shall be operated to
 measure the gas scrubber parameters
 specified in paragraphs (c) (1) through
 (c) (3) of this section or those site
 specific parameters determined
 according to the procedures specified in
 paragraph (n) of this section to comply
 with the sulfite pulping system
 requirements specified in §63.444(c).
   (g) A CMS shall be operated to
 measure the following parameters for
 each steam stripper used to comply with
 the treatment requirements in
 §63.446(e) (3), (4), or (5):
   (1) The process wastewater feed rate;
   (2) The steam feed rate; and
   (3) The process wastewater column
, feed temperature.
   (h) As an option to the requirements
 specified in paragraph (g) of this
 section, a CMS shall be operated to
 measure the methanol outlet
 concentration to comply with the steam
 stripper outlet concentration
 requirement specified in § 63.446 (e) (4)
 or(e)(5).
   (i) A CMS shall be operated to
 measure the appropriate parameters
 determined according to the procedures
 specified in paragraph (n) of this section
 to comply with the condensate
 applicability requirements specified in
 §63.446(c).
   (j) Each owner or operator using a
 biological treatment system to comply
 with § 63.446(e) (2) shall perform the
 following monitoring procedures.

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              Federal Register/Vol.  63, No. 72/Wednesday, April 15, 1998/Rules and Regulations.      18623
   (1) On a dally basis, monitor the
 following parameters for each biological
 treatment unit:
   (i) Composite daily sample of outlet
 soluble BODs concentration to monitor
 for maximum daily and maximum
 monthly average;
   (ii) Mixed liquor volatile suspended
 solids;
   (iii) Horsepower of aerator unit(s);
   (iv) Inlet liquid flow; and
   • (v) Liquid temperature.
   (2) Obtain daily inlet arid outlet liquid
 grab samples from each biological
 treatment unit to have HAP data
 available to perform quarterly percent
 reduction tests specified in paragraph
 0) (2) (ii) of this section and the
 compliance percent reduction tests
 specified in paragraph (p)(l)(i) of this
' section. Perform the following •
 procedures with the liquid samples:
   (i) Store the samples for 5 days as
 specified in § 63.457(n). The 5 day
 storage requirement is required since
' the soluble BODs test requires 5 days to
 obtain results.  If the results of the
 soluble BOD5 test are outside of the
 range established during the initial
 performance test, then the archive
 sample shall be used to perform the
 percent reduction test specified in
 §63.457(1).
   (ii) Perform the percent reduction test
 procedures specified in § 63.457(1)
 within 45 days after the beginning of
 each quarter as follows.
   (A) The percent reduction test
 performed in the first quarter (annually)
 shall be performed for total HAP and the
 percent reduction obtained from the test
 shall be at least as great as the total HAP
 reduction specified in § 63.446(e) (2).
   (B) The remaining quarterly percent
 reduction tests shall be performed for
 methanol and the percent reduction
 obtained from the test shall be at least
 as great as the methanol reduction
 determined in the previous first-quarter
 test specified in paragraph (j)(2)(ii) (A) of
 this section.
   ,(C) The parameter values used to
 calculate the percent reductions
 required in paragraphs (j)(2)(ii)(A) and
 (j) (2) (ii) (B) of this section shall be
 parameter values measured and samples
 taken in paragraph  (j)(l) of this section.
   (k) Each enclosure and closed-vent
 system used to comply with § 63.450(a)
 shall comply with the requirements
 specified in paragraphs (k) (1) through
 (k) (6) of this section.
   (1) For each enclosure opening, a
 visual inspection of the closure
 mechanism specified in § 63.450(b)
shall be performed at least once every
 30 days to ensure the opening is
 maintained in the closed position and
sealed.
    (2) Each closed-vent system required
•  by § 63.450(a) shall be visually
  inspected every 30 days and .at other
  times as requested by the Administrator.
  The visual inspection shall include
  inspection of ductwork, piping,
  enclosures, and connections to covers
  for visible evidence of defects.
    (3) For positive pressure closed-vent
  systems or portions of closed-vent
  systems, demonstrate no detectable
  leaks as specified in § 63.450(c)
  measured initially and annually by the
  procedures in § 63.457(d).
    (4) Demonstrate initially and annually
  that each enclosure opening is
.  maintained at negative pressure as
  specified in §63.457(e).
    (5) The valve or closure mechanism
  specified in §63.450(d)(2) shall be
  inspected at least once every 30 days to
  ensure that the valve is maintained in
  the closed position and the emission
  point gas stream is not diverted through
  the bypass line.
    (6) If an inspection required by
  paragraphs (k)(l) through (k)(5) of this
  section identifies visible defects in
  ductwork, piping, enclosures or
  connections to covers required by
  §63.450, or if an instrument reading of
  500 parts per million by volume or
  greater above background is measured,
  or if enclosure openings are not
  maintained at negative pressure, then
  the following corrective actions shall be
  taken as soon as practicable.
   (i) A first effort to repair or correct the
  closed-vent system shall be made as
  soon as practicable but nolater than  5
  calendar days after the problem is
  identified.
   (ii) The repair or corrective action
 shall be completed no later than 15
  calendar days after the problem is
  identified.
   (1) Each pulping process condensate
  closed collection system used to comply
 with § 63.446(d) shall be visually
 inspected every 30 days and shall
 comply with the inspection and
 monitoring requirements specified in
 § 63.964 of subpart RR of this part,
' except for the closed-vent system and
 control device inspection and
 monitoring requirements specified in
 §63.964(a)(2) of subpart RR of this part, •
 the closed-vent system and the control
 device shall meet the requirements
 specified in paragraphs (a) and (k) of
 this section.
   (m) Each owner or operator using a
 control device, technique or an
 alternative parameter other than those
 specified in paragraphs (b) through (1) of
 this section shall install a CMS and
 establish appropriate operating
 parameters to be monitored that
 demonstrate, to the Administrator's
 satisfaction, continuous compliance _
 with the applicable control
 requirements.
   (n) To establish or reestablish, the
 value for each operating parameter
 required to be monitored under
 paragraphs (b) through (j), (1), and (m) of
 this section or to establish appropriate
 parameters for paragraphs (f), (i), and
 (m) of this section, each owner or
 operator shall use the following
 procedures:
   (1) During the initial performance test
 required in §63.457(a) or any
 subsequent performance test,
 continuously record the operating
' parameter;
   (2) Determinations shall be based on
 the control performance and parameter
 data monitored during the performance
 test, supplemented if necessary by
 engineering assessments arid the
 manufacturer's recommendations;
   (3) The owner or operator shall
 provide for the Administrator's approval
 the rationale for selecting the
 monitoring parameters necessary to
 comply with paragraphs (f), (i), and (m)
 of this section; and
   (4) Provide for the Administrator's
 approval the rationale for the selected
 operating parameter value, and
 monitoring frequency, and averaging
 time. Include all data and calculations'
 used to develop the value and a
 description of why the value,
 monitoring frequency, and averaging
 time demonstrate continuous
 compliance with the applicable
 emission standard.
   (o) Each owner or operator of a
 control device subject to the monitoring
 provisions of this section shall operate
 the control device in a manner
 consistent with the minimum or
 maximum (as appropriate) operating
 parameter value or procedure required,
 to be monitored under paragraphs (a)
 through (n) of this section and
 established under this subpart. Except
 as provided in paragraph (p) of this
 section, §' 63.443(e), or § 63.446(g),
 operation of the control device below
 minimum operating parameter values or
 above maximum operating parameter
values established under this subpart or
failure to perform procedures required
 by this subpart shall constitute a
violation of the applicable emission
standard of this subpart and be reported
as a period of excess emissions.
   (p) Each owner or operator of a
biological treatment system complying
with paragraph (j) of this section shall
perform all the following requirements
when the monitoring parameters
specified in paragraphs (j)(l)(i) through
 (j)(l)(iii) of this section are below
minimum operating parameter values or

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18624
Federal Register/Vol.  63,  No. 72/Wednesday, April 15, 1998/Rules and Regulations
above maximum operating parameter
values established in paragraph (n) of
this section.
  (1) The following shall occur and be
recorded as soon as practical:
  (i) Determine compliance with
§63.446(e)(2) using the percent
reduction test procedures specified in
§ 63.457(0 and the monitoring data
specified in paragraph (j)(l) of this
section that coincide with the time
period of the parameter excursion;
  (ii) Steps shall be taken to repair or
adjust the operation of the process to
end the parameter excursion period; and
  (iii) Steps shall be taken to minimize
total HAP emissions to the atmosphere
during the parameter excursion period.
  (2) A parameter excursion is not a
violation of the applicable emission
standard if the percent reduction test
specified in paragraph (p) (1) (i) of this
section demonstrates compliance with
§63.446(e)(2), and no maintenance or
changes have been made to the process
or control device after the beginning of
a parameter excursion that would
influence the results of the
determination.
§63.454  Recordkeeping requirements.
  (a) The owner or operator of each
affected source subject to the
requirements of this subpart shall
comply with the recordkeeping
requirements of § 63.10 of subpart A of
this part, as shown in table 1, and the
requirements specified in paragraphs (b)
through (d) of this section for the
monitoring parameters specified in
§63.453.
  (b) For each applicable enclosure
opening, closed-vent system, and closed
collection system, the owner or operator
shall prepare and maintain a site-
specific inspection plan including a
drawing or schematic of the components
of applicable affected equipment and
shall record the following information
for each inspection:
  (I) Date of inspection;
  (2) The equipment type and
identification;
  (3) Results of negative pressure tests
for enclosures;
  (4) Results of leak detection tests;
  (5) The nature of the defect or leak
and the method of detection  (i.e., visual
inspection or instrument detection);
  (6) The date the defect or leak was
detected and the date of each attempt to
repair the defect or leak;
  (7) Repair methods applied in each
attempt to repair the defect or leak;
  (8) The reason for the delay if the
defect or leak is not repaired within 15
days after discovery;
  (9) The expected date of successful
repair of the defect or leak if the repair
is not completed within 15 days;
                            (10) The date of successful repair of
                          the defect or leak;
                            (11) The position and duration of
                          opening of bypass line valves and the
                          condition of any valve seals; and
                            (12) The duration of the use of bypass
                          valves on computer controlled valves.
                            (c) The owner or operator of a
                          bleaching system complying with
                          § 63.440(d) (3) (ii) (B) shall record the
                          daily average chlorine and hypochlorite
                          application rates, in kg of bleaching
                          agent per megagram of ODP, of the
                          bleaching system until the requirements
                          specified in §63.440(d)(3)(ii)(A) are met.
                            (d) The owner or operator shall record
                          the CMS parameters specified in
                          § 63.453 and meet the requirements
                          specified in paragraph (a) of this section
                          for any new affected process equipment
                          or pulping process condensate stream
                          that becomes subject to the standards in
                          this subpart due to a process change or
                          modification.

                          §63.455   Reporting requirements.
                            (a) Each owner or operator of a source
                          subject to this subpart shall comply
                          with the reporting requirements of
                          subpart A of this part as specified in
                          table 1 and all the following
                          requirements in this section. The initial
                          notification report specified under
                          § 63.9 (b) (2) of subpart A of this part
                          shall be submitted by April 1.5,1999.
                            (b) Each owner or operator of a kraft
                          pulping system specified in
                          § 63.440 (d)(l) or a bleaching system
                          specified in § 63.440(d)(3)(ii) shall
                          submit, with the initial notification
                          report specified under § 63.9(b) (2) of
                          subpart A of this part and paragraph  (a)
                          of this section and update every two
                          years thereafter, a non-binding control
                          strategy report containing, at a
                          minimum, the  information specified  in
                          paragraphs (b)(l) through (b) (3) of this
                          section in addition to the information
                          required in § 63.9 (b) (2) of subpart A of
                          this part.
                            (1) A description of the emission
                          controls or process modifications'
                          selected for compliance with the control
                          requirements in this standard.
                            (2) A compliance schedule,  including
                          the dates by which each step" toward
                          compliance will be reached for each
                          emission point or sets of emission
                          points. At a minimum, the list of dates
                          shall include:
                            (i) The date by which the major
                          study(s) for determining the compliance
                          strategy will be completed;
                            (ii) The date by which contracts for
                          emission controls or process
                          modifications will be awarded, or the
                          date by which  orders will be issued for
                          the purchase of major components to
accomplish emission controls or process
changes;
  (iii) The date by which on-site
construction, installation of emission
control equipment, or a process change
is to be initiated;
  (iv) The date by which on-site
construction, installation of emissions
control equipment, or a process change
is to be completed;
  (v) The date by which final
compliance is to be achieved;          '
  (vi) For compliance with paragraph
§63.440(d)(3)(ii), the tentative dates by
which compliance with effluent
limitation guidelines and standards
intermediate pollutant load effluent
reductions and as available, all the dates
for the best available technology's
milestones reported in the National
Pollutant Discharge Elimination System
authorized under section 402 of the
Clean Water Act and for the best
professional milestones in the Voluntary,
Advanced Technology Incentives
Program under 40 CFR 430.24 (b)(2);
and
  (vii) The date  by which the final
compliance tests will be performed.
  (3) Until compliance is achieved, '
revisions or updates shall be made to
the control strategy report required by
paragraph (b) of this section indicating
the progress made towards completing
the installation of the emission controls
or process modifications during the 2-
year period.
  (c) The owner or operator of each
bleaching system complying with
§ 63.440(d) (3) (ii) (B) shall certify in the
report specified under §63.10(e)(3) of
subpart A of this part that the daily
application rates of chlorine and
hypochlorite for that bleaching system
have not increased as specified in
§ 63.440(d) (3) (ii) (B) until the
requirements of § 63.440(d) (3) (ii) (A) are
met.                             • —
  (d) The owner or operator shall meet
the requirements specified in. paragraph
(a) of this section upon startup of any
new affected process equipment or
pulping process condensate stream that
becomes subject to the standards of this
subpart due to a process change or
modification.

§63.456  [Reserved]

§ 63.457 Test methods and procedures.
  (a) Initial performance test. An initial
performance test is required for all
emission sources subject to the
limitations in §§63.443, 63.444, 63.445,
63.446, and 63.447, except those
controlled by a  combustion device that
is designed and operated as specified in
§63.443(d)(3)or(d)(4).
  (b)  Vent sampling port locations and
gas stream properties.  For purposes of

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             Federal Register/Vol. 63, No. 72/Wednesday, April  15,  1998/Rules  and Regulations
                                                                     18625
 selecting vent sampling port locations
 and determining vent gas stream
 properties, required in §§ 63.443,
 63.444, 63.445, and 63.447, each owner
 or operator shall comply with the
 applicable procedures in paragraphs
 (b) (1) through (b) (6) of this section.
   (1) Method 1 or 1A of part 60,
 appendix A, as appropriate, shall be
 used for selection of the sampling site
 as follows:
   (i) To sample for vent gas
 concentrations and volumetric flow
 rates, the sampling site shall be located
 prior to dilution of the vent gas stream
 and prior to release to the atmosphere;
   (ii) For determining compliance with
 percent reduction requirements,
 sampling sites shall be located prior to
 the inlet of the control device and at the
 outlet of the control device;
 measurements shall be performed
 simultaneously at the two sampling
 sites; and
   (iii) For determining compliance with
 concentration limits or mass emission
 rate limits, the sampling site shall be
 located at the outlet of the control
 device.
   (2) No traverse site selection method
 is needed for vents smaller than 0.10
'meter (4.0 inches) in diameter.
   (3) The vent gas volumetric flow rate
 shall be determined using Method 2,
 2A,  2C, or 2D of part 60, appendix A,
 as appropriate.
   (4) The moisture content of the vent
 gas shall be measured using Method 4
 of part 60, appendix A.
   (5) To determine vent gas
 concentrations; the owner or operator
 shall collect a minimum of three
 samples that are representative of
 normal conditions and average the
 resulting pollutant concentrations using
 the following procedures.
   (i) Method 308 in Appendix  A of this
 part shall be used to determine the
 methanol concentration.'
   (ii) Except for the modifications
 specified in paragraphs (b) (5) (ii) (A)
' through (b) (5) (ii) (K) of this section.
 Method 26A of part 60, appendix A '
shall be used to determine chlorine
concentration in the vent stream.
   (A) Probe/Sampling Line. A separate
probe is not required. The sampling line
shall be an appropriate length of 0.64
cm (0.25 in) OD Teflon® tubing. The
sample inlet end Of the sampling line
shall be inserted into the stack in such
a way as to not entrain liquid
condensation from the vent gases. The
other end shall be connected to the
impingers. The length of the tubing may
vary from one sampling site to another,
but shall be as short as possible in each
situation. If sampling is conducted in
sunlight, opaque tubing shall be used.
Alternatively,- if transparent tubing is
used, it shall be covered with opaque
tape.
   (B) Impinger Train. Three 30 milliliter
(ml) capacity midget impingers shall be
connected in series to the sampling line.
The impingers shall have regular
tapered stems. Silica gel shall be placed
in the third impinger as a desiccant. All
impinger train connectors shall be glass
and/or Teflon®.
   (C) Critical Orifice. The critical orifice
shall have a flow rate of 200 to 250 ml/
min and shall, be followed by a vacuum
pump capable of providing a vacuum of
640 millimeters of mercury (mm Hg). A
45 millimeter diameter in-line Teflon®
0.8 micrometer filter shall follow the
impingers to project the critical orifice
and vacuum pump.
   (D) The following are necessary for
the analysis apparatus:
   (1) Wash bottle filled with deionized
water;      .
   (2) 25 of 50 ml graduated burette and
"stand;
   (3) Magnetic stirring apparatus and
stir bar;                j  ,
   (4) Calibrated pH Meter;
   (5) 150-250 ml beaker or flask; and
   (6) A 5 ml pipette.
   (E) The procedures listed in
paragraphs (b) (5) (ii) (E) (1) through
(b) (5) (ii) (E) (7) of this section shall be
used to prepare the reagents.
   (1) To prepare the 1 molarity (M)  .
potassium dihydrogen phosphate
solution, dissolve 13.61 grams (g) of
potassium dihydrogen phosphate in
water and dilute to 100 ml.
  (2) To prepare the 1 M sodium
hydroxide solution (NaOH), dissolve 4.0
g of sodium hydroxide in water and
dilute to 100 ml.
  (3) To prepare the buffered 2 percent
potassium iodide solution, dissolve 20 g
of potassium iodide in 900 ml water.
Add 50 ml 'of the 1 M potassium
dihydrogen phosphate solution and 30
ml of the 1 M sodium hydroxide
solution. While stirring solution,
measure the pH of solution
electrometrically and add the 1 M
sodium hydroxide solution to bring pH
to between 6.95 and 7.05.
  (4) To prepare the 0.1 normality (N)
sodium thiosulfate solution, dissolve 25
g of sodium thiosulfate, pentahydrate, in
800 ml of freshly boiled and cooled
distilled water in a 1-liter volumetric
flask. Dilute to volume. To prepare the
0.01 N sodium thiosulfate solution, add
10.0 ml standardized 0.1 N sodium
thiosulfate solution to a 100 ml
volumetric flask, and dilute to volume
with water.                  ,
  (5) To standardize the 0.1 N sodium
thiosulfate solution, dissolve 3.249 g of
anhydrous potassium bi-iodate, primary
standard quality, or 3.567 g potassium
iodate dried at 103 +/—2 degrees
Centigrade for 1 hour, in distilled water
and dilute to 1000 ml ito yield a 0.1000
N solution. Store in a glass-stoppered
bottle. To 80 ml distilled water, add,
with constant stirring, 1 ml
concentrated sulfuric acid, 10.00ml
0.1000 N anhydrous potassium bi-
iodate, and 1 g potassium iodide. Titrate
immediately with 0.1 n sodium
thiosulfate titrant until the yellow color
of the liberated iodine is almost'
discharged. Add 1 ml starch indicator
solution and continue titrating until the
blue color disappears. The normality of
the sodium thiosulfate solution is
inversely proportional to the ml of
sodium thiosulfate solution consumed:
                                   Normality of
                                 SodiumThiosulfate
                                                    ml Sodium Thiosulfate Consumed
   (6) To prepare the starch indicator
 solution, add a small amount of cold
 water to 5 g starch and grind in a mortar
 to obtain a thin paste. Pour paste into
 1 L of boiling distilled water, stir, and
 let settle overnight. Use clear supernate
 for .starch indicator solution.
   (7) To prepare the 10 percent sulfuric
 acid solution, add 10 ml of concentrated
sulfuric acid to 80 ml water in an 100
ml volumetric flask. Dilute, to volume.
'   (F) The procedures specified in
paragraphs (b)(5)(ii)(F)(J) through
(b) (5) (ii) (F) (5) of this section shall be  ,
used to perform the sampling.
   (1) Preparation of Collection Train.
Measure 20 ml buffered potassium
iodide solution into each of the first two
impingers and connect probe,
impingers, filter, critical orifice, and
pump. The sampling line and the
impingers shall be shielded from
sunlight.
  (2) Leak and Flow Check Procedure.
Plug sampling line inlet tip and turn on
pump. If a flow of bubbles is visible in
either of the liquid impingers, tighten
fittings and adjust connections and

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 18626      Federal Register/Vol. 63, No. 72/Wednesday, April  15, 1998/Rules and Regulations
 impingers. A leakage rate not in excess
 of 2 percent of the sampling rate is
 acceptable. Carefully remove the plug
 from the end of the probe. Check the
 flow rate at the probe inlet with a
 bubble tube flow meter. The flow
 should be comparable or slightly less
 than the flow rate of the critical orifice
 with the impingers off-line. Record the
 flow and turn off the pump.
   (3) Sample Collection. Insert the
 sampling line into the stack and secure
 it with the tip slightly lower than the
 port height. Start the pump, recording
 the time. End the sampling after 60
 minutes, or after yellow color is
 observed in the second in-line impinger.
 Record time and remove the tubing from
 the vent. Recheck flow rate at sampling
 line inlet and turn off pump. If the flow
 rate has changed significantly, redo
 sampling with fresh capture solution. A
 slight variation (less than 5 percent) in
 flow may be averaged. With the inlet
 end of the line elevated above the
 impingers, add about 5 ml water into
 the inlet tip to rinse the line into the
 first impinger.
  (4) Sample Analysis. Fill the burette
 with 0.01 N sodium thiosulfate solution
 to the zero mark. Combine the contents
 of the impingers in the beaker or flask.
 Stir the solution and titrate with
 thiosulfate until the solution is
 colorless. Record the volume of the first
 endpoint (TN. ml). Add 5 ml of the 10
 percent sulfuric acid solution, and
 continue the titration until the contents
 of the flask are again colorless. Record
 the total volume of titrant required to  go
 through the first and to the second
 endpoint CTA, ml). If the volume of
 neutral titer is less than 0.5 ml, repeat
 the testing for a longer period of time.
 It is important that sufficient lighting be
 present to clearly see the endpoints,
 which are determined when the
 solution turns from pale yellow to
 colorless. A lighted stirring plate and a
 white background are useful for this
 purpose.
  (5) Interferences. Known interfering
 agents of this method are sulfur dioxide
 and hydrogen peroxide. Sulfur dioxide,
 which is used to reduce oxidant
 residuals in some bleaching systems,
 reduces formed iodine to iodide in the
 capture solution. It is therefore a
 negative interference for chlorine,  and
 in some cases could result in erroneous
 negative chlorine concentrations. Any
 agent capable of reducing iodine to
 iodide could interfere in this manner. A
 chromium trioxide impregnated filter
will capture sulfur dioxide and pass  ,
 chlorine and chlorine dioxide.
Hydrogen peroxide, which is commonly
used as a bleaching agent in modern
bleaching systems, reacts with iodide to
 form iodine and thus can cause a
 positive interference in the chlorine
 measurement. Due to the chemistry
 involved, the precision of the chlorine
 analysis will decrease as the ratio of
 chlorine dioxide to chlorine increases.
 Slightly negative calculated
 concentrations of chlorine may occur
 when sampling a vent gas with high
 concentrations of chlorine dioxide and
 very low concentrations of chlorine.
   (G) The following calculation shall be
 performed to determine the corrected
 sampling flow rate:
                 760  A273+t
Where:
Sc=Corrected (dry standard) sampling flow
    rate, liters per minute;
Su=Uncorrected sampling flow rate, L/min;
BP=Barometric pressure at time of sampling;
PW=Saturated partial pressure of water
    vapor, mm Hg at temperature; and
t=Ambient temperature, °C.

   (H) The following calculation shall be
performed to determine the moles of
chlorine in the sample:

  Cl2Moles = 1/8000 (5 TN - TA ) x N^
Where:
TN=Volume neutral titer, ml;
TA=Volume acid titer (total), ml; and
N-rhio=Normality of sodium thiosulfate titrant.

   (0 The following calculation shall be
performed to determine the
concentration of chlorine in the sample:
                    SC X tg
Where:
Sc=Corrected (dry standard) sampling flow
    rate, liters per minute;
ts=Time sampled, minutes;
TN=Volume neutral titer, ml;
TA"=Volume acid titer (total), ml; and
NThio=Normality of sodium thiosulfate titrant.

  0) The following calculation shall be
performed to determine the moles of
chlorine dioxide in the sample:

 C102 Moles = 1/4000(TA -T^xN^

Where:
TA=Volume acid titer (total), ml; _
TN=Volume neutral titer, ml; and
NThio=Normality of sodium thiosulfate titrant.

  (K) The following calculation shall be
performed to determine the
concentration of chlorine dioxide in the
sample:

  „_          6010(TA-TN)xNThio
  CIO, ppmv = - ^ - z+ - ^-
                         -
 Sc=Corrected (dry standard) sampling flow
    rate, liters per minute;
 ts=Time sampled, minutes;
 TA=Volume acid titer (total), ml;
,TN=Volume neutral titer, ml; and
 NThio=Normality of sodium thiosulfate titrant.

   (iii) Any other method thai: measures
 the total HAP or methanol concentration
 that has been demonstrated to the
 Administrator's satisfaction.
   (6) The minimum sampling time for
 each of the three runs per method shall
 be 1 hour in which either an  integrated
 sample or four grab samples shall be
 taken. If grab sampling is used, then the
 samples shall be taken at approximately
 equal intervals in time, such  as 15
 minute intervals during the run.'
   (c) Liquid sampling locations and
properties. For purposes of selecting
 liquid sampling locations and for
 determining properties of liquid streams
such as wastewaters, process waters,
and condensates required in §§ 63.444,
63.446, and 63.447, the owner or  ,
operator shall comply with the
following procedures:
   (1) Samples shall be collected using
the sampling procedures specified in
Method 305 of part 60, appendix A;
   (i) Where feasible, samples shall be
taken from an enclosed pipe prior to the
liquid stream being exposed to the
atmosphere; and
   (ii) When sampling from an enclosed
pipe is not feasible, samples shall be
collected in a manner to minimize
exposure of the sample to the
atmosphere and loss of HAP compounds
prior to sampling.
   (2) The volumetric flow rate of the
entering and exiting liquid streams shall
be determined using the inlet and outlet
flow meters or other methods
demonstrated to the Administrator's
satisfaction. The volumetric flow rate
measurements  to determine actual mass
removal shall be taken at the  same time
as the concentration measurements;
   (3) To determine liquid stream total
HAP or methanol concentrations, the
owner or operator shall collect a
minimum of three samples that are
representative of normal conditions and
average the resulting pollutant
concentrations using one of the
following: '
   (i) Method 305 in Appendix A of this
part, adjusted using the following
equation:
Where:
Where: *
C=Pollutant concentration for the liquid
   stream, parts per million by weight.

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             Federal Register/Vol.  63,  No. 72/Wednesday,  April 15,  1998/Rules and Regulations,
                                                                       18627
 Ci=Measured concentration of pollutant i in
    the liquid stream sample determined
    using Method 305, parts per million by
    weight.
 fhii=Pollutant-specific constant that adjusts
    concentration measured by Method 305
    to actual liquid concentration; the fm for
    methanol is 0.85. Additional pollutant
    fm values can be found in table 34,
    subpart G of this part.
• n=Number of individual pollutants, i,
    summed to calculate total HAP.
   (ii) Any other method that measures
 total HAP concentration that has been
 demonstrated to the Administrator's
 satisfaction.
   (4) To determine soluble BOD5 in the
 effluent stream from a biological
 treatment unit used to comply with
 §§ 63.446(e) (2) and 63.453Q), the owner
 or operator shall use Method 405.1, of
 part, 136, with the following.
 modifications:
   (i) Filter the sample through the filter
 paper, into-Erlenmeyer flask by
 applying a vacuum to the flask sidearm.
 Minimize the time for which vacuum is
 applied to prevent stripping of volatile
 organics from the sample. Replace filter
 paper as often as needed in order to
 maintain filter times of less than
 approximately 30 seconds per filter
 paper. No rinsing of sample container or
 filter bowl into the Erlenmeyer flask is
 allowed.
  • (ii) Perform Method 405.1 on the
 filtrate obtained in paragraph (c)(4) of
 this .section. Dilution water shall be
 seeded with 1 milliliter of final effluent
 per liter of dilution water. Dilution
 ratios may require adjustment to reflect
 the lower oxygen demand of the filtered
 sample in comparison to the total BODs.
 Three BOD bottles and different
 dilutions shall be used for each sample.
   (d) Detectable leak procedures. To
 measure detectable leaks for closed-vent
 systems as specified in § 63.450 or for
 pulping process wastewater collection
 systems as.specified in §63.446(d)(2)(i),
 the owner or operator shall comply with
 the following:
   (1) Method 21, of part 60, appendix A;
 and
   (2) The instrument specified in
 Method 21 shall be calibrated before use
 according to the procedures specified in
 Method 21 on each day that leak checks
 are performed. The following calibration
 gases shall be used:             ,
   (i) Zero air (less than 10 parts per
 million by volume of hydrocarbon in
 air); and
   (ii) A mixture of methane or n-hexane
 and air at a concentration of
 approximately, but less than, 10,000
 parts per million by volume methane or
 n-hexane.
   (e) Negative pressure procedures. To
 demonstrate negative pressure at
 process equipment enclosure openings
 as specified in §63.450(b), the owner or
 operator shall use one of the following
.procedures:
   (1) An anemometer to demonstrate
 flow into the enclosure opening;
   (2) Measure the static pressure across
 the opening;
   (3) Smoke tubes to demonstrate flow
 into the enclosure opening; or
   (4) Any other industrial ventilation
 test method demonstrated to the
 Administrator's satisfaction.
   (f)  HAP concentration measurements.
 For purposes of complying with the
 requirements  in §§63.443, 63.444. and
 63.447, the owner or operator shall
 measure the total HAP concentration as
 one of the following:
   (1) As the sum of all individual
 HAP's; or
   (2) As methanol.
   (g) Condensate HAP concentration
 measurement. For purposes of
 complying with the kraft pulping
 condensate requirements in § 63.446,
 the owner or operator shall measure the
 total HAP concentration as methanol
 except for the purposes of complying
 with the initial performance test
 specified in §63.457(a) for §63.446(e)(2)
 and as specified in §63.4530)(2)(ii).
 '  (h) Bleaching HAP concentration
 measurement. For purposes of
 complying with the  bleaching system
 requirements  in § 63.445, the owner or
 operator shall measure the total HAP
 concentration as the sum of all
 individual chlorinated HAP's or as
 chlorine.
   (i)  Vent gas stream calculations. To
 demonstrate compliance with the mass
 emission  rate, mass  emission rate per
 megagram of ODP, and percent
 reduction requirements for vent gas
 streams specified in §§ 63.443, 63.444,
 63.445, and 63.447,  the owner or
 operator shall use the following:
   (1) The total HAP mass emission rate
 shall be calculated using the following
 equation:
            = K
 Where:
. E=Mass emission rate of total HAP from the
    sampled vent, kilograms per hour.
 K2=Constant, 2.494xlO-« (parts per million
    by volume) -l (gram-mole per standard •
    cubic meter) (kilogram/gram) (minutes/
    hour), where standard temperature for
    (gram-mole per standard cubic meter) is
    20 °C.
 (^Concentration on a dry basis of pollutant
    j in'parts per million by volume as
    measured by the test methods specified
    in paragraph (b) of this section.
 Mj=Molecular weight of pollutant j, gram/
    gram-mole.
Qs=Vent gas stream flow rate (dry standard
    cubic meter per minute) at a temperature
    of 20 °C as indicated in paragraph (b) of
    this section.
n=Number of individual pollutants, i,
    summed to calculate total HAP.

   (2) The total HAP mass emission rate
per megagram of ODP shall be
calculated using the following equation:
Where:
F=Mass emission rate of total HAP from the
    sampled vent, in kilograms per
    megagram of ODP.
E=Mass emission rate of total HAP from the
    sampled vent, in kilograms per hour
    determined as specified in paragraph
    (i)(l) of this section.
P=The production rate of pulp during the
    sampling period, in megagrams of ODP
    per hour.                       %

  (3) The total HAP percent reduction
shall be calculated using the following
equation:
Where:
R=Efficiency of control device, percent.
Ei=Inlet mass emission rate of total HAP from
...  , the sampled vent, in kilograms of
    pollutant per hour, determined as
    specified in paragraph (i)(l) of this
    section.
E0=Outlet mass emission rate of total HAP
    from the sampled vent, in kilograms of
    pollutant per hour, determined as
    specified in paragraph (i) (1) of this
    section.

   (j) Liquid stream calculations. To
demonstrate compliance with the mass
flow rate, mass per megagram of ODP,
and percent reduction requirements for
liquid streams specified in § 63.446, the
owner or operator shall use the
following:
   (1) The mass flow rates of total HAP
or methanol entering and exiting the
treatment process shall be calculated
using the following equations:
               K
Where:
Eb=Mass flow rate of total HAP or methanol
    in the liquid stream entering the
    treatment process, kilograms per hour.
Ea=Massflow rate of total HAP or methanol
    in the liquid exiting the treatment
    process, kilograms.per hour.

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18628
Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules and Regulations
K«Density of the liquid stream, kilograms per
    cubic meter.
Vw-Volumetric flow rate of liquid stream
    entering the treatment process during
    each run i, cubic meters per hour,
    determined as specified in paragraph (c)
    of this section.
Vij»Volumetric flow rate of liquid stream
    exiting the treatment process during each
    run 1, cubic meters per hour, determined
    as specified In paragraph (c) of this
    Section.
Cbt-Concentration of total HAP or methanol
    in the stream entering the treatment
    process during each run i, parts per
    million by weight, determined as
    specified in paragraph (c)  of this section.
Cri«Concentration of total HAP or methanol
    In the stream exiting the treatment
    process during each run i, parts per
    million by weight, determined as
    specified in paragraph (c)  of this section.
n«Number of runs.

  (2) The mass of total HAP or methanol
per megagram ODP shall be calculated
using the following equation:
Where:
F-Mass loading of total HAP or methanol in
    the sample, in kilograms per megagram
    of ODP.
E,-Mass flow rate of total HAP or methanol
    in the wastewater stream in kilograms
    per hour as determined using the
    procedures in paragraph (j)(l) of this
    section.
P«"The production rate of pulp during the
    sampling period in megagrams of ODP
    per hour.
  (3) The percent reduction of total HAP
across the applicable treatment process
shall be calculated using the following
equation:
Where:
R-Control efficiency of the treatment
    process, percent.
Et,»Mass flow rate of total HAP in the stream
    entering the treatment process, kilograms
    per hour, as determined in paragraph
    ())U) of this section.
E.-Mass flow rate of total HAP in the stream
    exiting the treatment process, kilograms
    per hour, as determined in paragraph
    (j)(l) of this section.
  (4) Compounds that meet the
requirements specified in paragraphs
0) (4) (i) or (4) (ii) of this section are not
required to be included in the mass flow
rate, mass per megagram of ODP, or the
mass percent reduction determinations.
  (i) Compounds with concentrations at
the point of determination that are
below 1 part per million by weight; or
  (ii) Compounds with concentrations
at the point of determination that are
                           below the lower detection limit where
                           the lower detection limit is greater than
                           1 part per million by weight.
                             (k) Oxygen concentration correction
                           procedures. To demonstrate compliance
                           with the total HAP concentration limit
                           of 20 ppmv in  § 63.443(d) (2), the
                           concentration measured using the
                           methods specified in paragraph (b)(5) of
                           this section shall be corrected to 10
                           percent oxygen using the following
                           procedures:
                             (1) The emission rate correction factor
                           and excess  air  integrated sampling and
                           analysis procedures of Methods 3 A or
                           3B of part 60, appendix A shall be used
                           to determine the oxygen concentration.
                           The samples shall be taken at the same
                           time that the HAP samples are taken.
                             (2) The concentration corrected to 10
                           percent oxygen shall be computed using
                           the following equation:
                                                10.9
                                            20.9 -%O2d

                           Where:
                           Cc=Concentration of total HAP corrected to
                               10 percent oxygen, dry basis, parts per
                               million fay volume.
                           Cm=Concentration of total HAP dry basis,
                               parts per million by volume, as specified
                               in paragraph (b) of this section.
                           %02d=Concentration of oxygen, dry basis,
                               percent by volume.
                             (1) Biological treatment system
                           percent reduction calculation. To
                           determine compliance with an open
                           biological treatment system option
                           specified in § 63.446(e)(2) and the
                           monitoring requirements specified in
                           § 63.453(j)(2), the percent reduction due
                           to destruction in the biological
                           treatment system shall be calculated
                           using the following equation:
                           R=fbioXlOO
                           Where:
                           R=Destruction of total HAP or methanol in
                               the biological treatment process, percent.
                           fbio=The fraction of total HAP or methanol
                               removed in the biological treatment
                               system. The site-specific biorate
                               constants shall be determined using the
                               procedures specified and as limited in
                               appendix C of part 63.
                             (m) Condensate segregation
                           procedures. The following procedures
                           shall be used to demonstrate
                           compliance with the condensate
                           segregation requirements specified  in
                           §63.446(c).
                             (1) To demonstrate compliance with
                           the percent mass requirements specified
                           in § 63.446(c)(l), the procedures
                           specified in paragraphs (m)(l)(i) through
                           (m) (1) (iii) of this section shall be
                           performed.
                             (i) Determine the total HAP mass of
                           all condensates from each equipment
 system listed in §63.446 (b)(l) through
 (b) (3) using the procedures specified in
 paragraphs (c) and (j) of this section.
   (ii) Multiply the total HAP mass
 determine in paragraph (m)(l)(i) of this
 section by 0.65 to determine the target
 HAP mass for the high-HAP fraction
 condensate stream or streams.
   (iii) Compliance with the segregation
 requirements specified in § 63.446(c) (1)
 is demonstrated if the condensate
 stream or streams from each equipment
 system listed in § 63.446 (b) (1)-through
 (b) (3) being treated as specified in
 § 63.446(e) contain at least as much total
 HAP mass as the target total HAP mass
 determined in paragraph (m)(l)(ii) of
 this section.
   (2) To demonstrate compliance with
 the percent mass requirements specified
 in §63.446(c)(2), the procedures
 specified in paragraphs (m)(2)(i) through
 (m) (2) (ii) of this section shall be
 performed.
   (i) Determine the total HAP mass
 contained in the high-HAP fraction
 condensates from each equipment
 system listed in §63.446 (b)(l) through
 (b) (3) and the total condensates streams
 from the equipment systems listed in
 §63.446(b)(4) and (b)(5), using the
 procedures specified in paragraphs (c)
 and (j) of this section.
   (ii) Compliance with the segregation
 requirements specified in § 63.446(c)(2)
 is demonstrated if the total HAP mass
 determined in paragraph (m) (2) (i) of this
 section is equal to or greater than the
 appropriate mass requirements specified
 in§63.446(c)(2).
   (n) Biological treatment system
 monitoring sampling storage. The inlet
 and outlet grab samples required to be
 collected in § 63.4530) (2)  shall be stored
 at 4° C (40° F) to minimize the
 biodegradation of the organic
 compounds in the samples.

 § 63.458  Delegation of authority.
   (a) In delegating implementation and
 enforcement authority to a State under
 section 112(d) of the CAA, the
 authorities contained in paragraph (b) of
 this section shall be retained by the
 Administrator and not transferred to a
 State.
   (b) Authorities which will not be
 delegated to States:
 ,  (1) Section 63.6(g)—Use of an
 alternative nonopacity emission
 standard;
   (2) Section 63.453(m)—Use of an'
 alternative monitoring parameter;
   (3) Section 63.457(b)(5)(iii)—Use of an
 alternative test method for total HAP or
 methanol in vents; and
   (4) Section 63.457(c)(3)(ii)—Use of an
 alternative test method for total HAP or
• methanol in wastewater.

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           Federal Register /Vol. 63, No.  72/Wednesday, April  15, 1998/Rules and Regulations
18629
§63.459 [Reserved]
                 TABLE 1 TO SUBPART S—GENERAL PROVISIONS APPLICABILITY TO SUBPART Sa
Reference
63.1(a)(1)-(3) 	
63.1 (a)(4) 	
63.1 (a)(5) 	 	
63.1(a)(6)-(8) 	
63.1 (a)(9) 	 ...; 	
63.1(a)(10) 	
63.1(a)(11)-(14) 	
63.1 (b)(1) 	 	 	
63.1(b)(2)-(3) 	
63.1(c)(1H2) 	
63.1 (c)(3) 	 	 	
63.1(c)(4M5) 	 	 .
63.1 (d) 	
63.1 (e) 	
63.2 	
63.3 	
63.4(a)(1) 	 	
63.4(a)(3).
63.4(a)(4) 	 	 	 	
63.4(a)(5) 	 ..„.„..
63.4(b) 	
63.4(c) 	
63.5(a) 	
63.5(b)(1) 	 	 	
63.5(b)(2) 	
63.5(b)(3) 	 	
63.5(b)(4)-(6) 	
63.5(c) 	 	 „...
63.5(d) 	 	
63.5(e) 	 .-=.... 	
63.5(1) 	 	
63.6(a) 	
63.6(b) 	 	 	
63.6(c) 	
63.6fd) .
63.6(e) 	
63.6(f) 	
63.6(g) 	
63.6(h) 	 	 	 	
63.6(i) 	
63.6(i) 	
63.7 	 	 	
63.8(a)(1) 	
63.8(a)(2) 	
63.8(a)(3) 	 	 	
63.8(a)(4) 	 	
63.8(b)(1) 	
63.8(b)(2) 	
63.8(b)(3) 	
63.8(C)(1) 	
63.8(c)(2) 	
63.8(c)(3) 	 	
63.8(c)(4) 	 ;.
63.8(C)(5) 	 	 	
63.8(C)(6) 	
63.8(C)(7) 	 	
63.8(c)(8) 	
63.8(d) 	 	
63.8(e) 	
63.8(f)(1H5) 	 	
63.8{f)(6) .< 	 	 	
63.8(g) 	
63.9(a) 	 	 	
63.9(b) 	 .........
63.9(c) 	 	 	 	 .
63.9(d) 	 	
63.9{e)
63.9(f) 	
Applies to
Subpart S
Yes.
Yes 	
No 	 	 	
Yes.
No 	
No 	 ...
Yes.
No 	 	 	
Yes.
Yes
No 	 ......
Yes
No 	 	 	
Yes.
Yes.
Yes
Yes.
No 	
Yes.
Yes.
Yes
Yes.
Yes.
No 	
Yes.
Yes.
No .., 	
Yes
Yes.
Yes.
Yes
No 	
No 	
No
Yes
Yes
Yes;
No ...., 	
Yes
Yes
Yes
Yes
Yes
No
Yes
Yes.
No 	 	
Yes.
Yes.
Yes
Yes.
No 	 	
No 	
Yes.
Yes
Yes.
Yes.
Yes
Yes
No 	
Yes
Yes
Yes .
Yes
No
Yes
No 	 	
Comment

Subpart S (this table) specifies applicability of each paragraph in subpart A to subpart S
Section reserved , >

Section reserved
Subpart S and other cross-referenced subparts specify calendar or operating day

Subpart S specifies its own applicability


Section reserved. -• •

Section reserved.




Section reserved.


.


Section reserved.


Section reserved

'


Subpart S specifies compliance dates for sources subject to subpart S
Subpart S specifies compliance dates for sources subject to subpart S •
Section reserved • •

~*.',' ' ' ' '

Pertains to continuous opacity monitors that are not part of this standard




v •
Section reserved


Subpart S specifies locations to conduct monitoring

• •


Subpart S allows site specific determination of monitoring frequency in § 63 453(n)(4)
Pertains to continuous opacity monitors that are not part of this standard






Subpart S does not specify relative accuracy test for CEM's



standard.


Pertains to continuous ODacitv monitors that are not nart nf ihis stnnHarH

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18630
Federal Register/Vol. 63, No. 72/Wednesday, April  15,  1998/Rules and  Regulations
              TABLE 1 TO SUBPART S—GENERAL PROVISIONS APPLICABILITY TO SUBPART S*—Continued
Reference
63.9(g)(1) 	
63.9{a)(2) 	
63.9(q)(3) 	
63.9(h) 	
63.9(0 	 	
63.9{j) 	
63.10(a) 	
63.1 0(b) 	
63.1 0(c) 	
63.10(d)(1) 	
63.10(d)(2) 	
63.10{d)(3) 	
63.10(d){4) 	
63.10{d)(5) 	
63.10{e)(1) 	
63.10{e){2)fi) 	

63.10(e)(3) 	
63.10(e)(4) 	
63.10(f) 	
63.11-63.15 	
Applies to
Subpart S
Yes.
No 	
No 	
Yes.
Yes.
Yes.
Yes.
Yes.
Yes.
Yes.
Yes.
No 	
Yes.
Yes.
Yes.
Yes.
No 	
Yes.
No 	
Yes.
Yes.
Comment

Pertains to continuous opacity monitors that are not part of this standard.
Subpart S does not specify relative accuracy tests, therefore no notification is required for an alternative.







'
Pertains to continuous opacity monitors that are not part of this standard.




Pertains to continuous opacity monitors that are not part of this standard

Pertains to continuous opacity monitors that are not part of this standard.


  •Wherever subpart A specifies "postmark" dates, submittals may be sent by methods other than the U.S. Mail (e.g., by fax or courier). Submit-
tals shall be sent by the specified dates, but a postmark is not required.    ,                *
  3. Appendix A of part 63 is amended
by adding Method 308 in numerical
order to read as follows:
Appendix A to Part 63—Test Methods
*    *    *    *    *

Method 308—Procedure for
Determination of Methanol Emission
From Stationary Sources
1.0  Scope and Application
  1.1   Analyte. Methanol. Chemical
Abstract Service (CAS) No. 67-56-1.
  1.2  Applicability. This method
applies to the measurement of methanol
emissions from specified stationary
sources.
2.0  Summary of Method
  A gas sample is extracted from the
sampling point in the stack. The
methanol is collected in deionized
distilled water and adsorbed on silica
gel. The sample is returned to the
laboratory where the methanol in the
water fraction is separated from other
organic compounds with a gas
chromatograph (GC) and is then
measured by a flame ionization detector
(FID). The fraction adsorbed on silica
gel is extracted with an aqueous
solution of n-propanol and is then
separated and measured by GC/FID.
3.0  Definitions [Reserved]
4.0  Interferences [Reserved]
5.0  Safety
  5.1   Disclaimer.  This method may
involve hazardous materials, operations,
and equipment. This test method does
                          not purport to address all of the safety
                          problems associated with its use. It is
                          the responsibility of the user of this test
                          method to establish appropriate safety
                         , and health practices and to determine
                          the applicability of regulatory
                          limitations before performing this test
                          method.
                            5.2  Methanol Characteristics.
                          Methanol is flammable and a dangerous
                          fire and explosion risk. It is moderately
                          toxic by ingestion and inhalation.

                          6.0 Equipment and Supplies
                            6.1  Sample Collection. The
                          following items are required for sample
                          collection:
                            6.1.1  Sampling Train. The sampling
                          train is shown in Figure 308-1 and
                          component parts are discussed below.
                            6.1.1.1  Probe. Teflon®,
                          approximately 6-millimeter (mm) (0.24
                          inch) outside diameter.
                            6.1.1.2  Impinger. A 30-milliliter (ml)
                          midget impinger. The impinger must be
                          connected with leak-free glass
                          connectors. Silicone grease may not be
                          used to lubricate the connectors.
                            6.1.1.3  Adsorbent Tube. Glass tubes
                          packed with the required amount of the
                          specified adsorbent.
                            6.1.1.4  Valve. Needle valve, to
                          regulate sample gas flow rate.
                            6.1.1.5  Pump. Leak-free diaphragm
                          pump, or equivalent, to pull gas through
                          the sampling train. Install a small surge
                          tank between the pump and rate meter
                          to eliminate the pulsation effect of the
                          diaphragm pump on the rotameter!
                            6.1.1.6  Rate Meter. Rotameter, or'
                          equivalent, capable of measuring flow
rate to within 2 percent of the selected
flow rate of up to 1000 milliliter per
minute (ml/min). Alternatively, the
tester may use a critical orifice to set the
flow rate.
  6.1.1.7  Volume Meter. Dry gas meter
(DGM), sufficiently accurate to measure
the sample volume to within 2 percent,
calibrated at the selected flow rate and
conditions actually encountered during
sampling, and equipped with a
temperature sensor (dial thermometer,  .
or equivalent) capable of measuring
temperature accurately to within 3 °C
(5.4 °F).
  6.1.1.8  Barometer. Mercury (Hg),
aneroid, or other barometer capable of
measuring atmospheric pressure to
within 2.5 mm (0.1 inch) Hg. See the
NOTE in Method 5 (40 CFR part 60,
appendix A), section 6.1.2.
  6.1.1.9  Vacuum Gauge and
Rotameter. At least 760-mm (30-inch)
Hg gauge and 0- to 40-ml/m:ln rotameter,
to be used for leak-check of the
sampling train.
  6.2  Sample Recovery. The following
items are required for sample recovery:
  6.2.1  Wash Bottles. Polyethylene or
glass, 500-ml, two.
  6.2.2  Sample Vials: Glass, 40-ml,
with Teflon®-lined septa, to store
impinger samples (one per sample).
  6.2.3  Graduated Cylinder. 100-ml
size.
  6.3  Analysis. The following are
required for analysis:
  6.3.1  Gas Chromatograph. GC with
an FID, programmable temperature
control, and heated liquid injection
port.

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             Federal Register/Vol. 63, No. 72/Wednesday, April 15; 1998/Rules and  Regulations
                                                                      18&31
  6.3.2  Pump. Capable of pumping
100 ml/min. For flushing sample loop.
  6.3.3  Flow Meter. To monitor
accurately sample loop flow rate of 100
ml/min.
  6.3.4  Regulators. Two-stage
regulators used on gas cylinders for GC
and for cylinder standards.
  6.3.5  Recorder. To record, integrate,
and store chromatograms.
  6.3.6  Syringes. 1.0-and 10-
microliter (1) size, calibrated, for
injecting samples.
  6.3.7  Tubing Fittings. Stainless steel,
to plumb GC and gas cylinders.
  6.3.8  Vials. Two 5.0-ml glass vials
with screw caps fitted with Teflon®-
lined septa for each sample.
  6.3.9  Pipettes. Volumetric type,
assorted sizes for preparing calibration
standards.'
  6.3.10  Volumetric Flasks. Assorted
sizes for preparing calibration
standards.
  6.3.11  Vials. Glass 40-ml with
Teflon®-lined septa, to store calibration
standards (one per standard).

7.0  Reagents and Standards
 ~ Note: Unless otherwise indicated, all
reagents must conform to the specifications
established by the Committee on Analytical
Reagents of the American Chemical Society.
Where such specifications are not available,
use the best available grade.
  7.1 Sampling. The following are
required for sampling:
  7.1.1  Water. Deionized distilled to
conform to  the American Society for
Testing and Materials (ASTM)
Specification D 1193-77, Type 3. At the
option of the analyst, the potassium
permanganate  (KMnCXO test for
oxidizable organic matter may be
omitted when  high concentrations of  ,
 organic matter are not expected to be
 present. >  .  .. .
   7.1.2  Silica Gel. Deactivated
 chromatographic grade 20/40 mesh'
 silica gel packed in glass adsorbent  .
 tubes. The silica gel is packed in two
 sections. The front section contains 520
 milligrams (mg) of silica gel, and the
 back section contains 260 mg.
   7.2  Analysis. The following are
 required for analysis:
   7.2.1  Water. Same as specified in
 section" 7.1.1.
   7.2.2  n-Propanol. 3 Percent. Mix 3
 ml of n-propanol with'97 ml of water.
   7.2.3  Methanol Stock Standard.
 Prepare a methanol stock ^standard by
 weighing 1 gram of methanol into a 100-
 ml volumetric flask. Dilute to 100 ml
 with water.
   7.2.3.1  Methanol Working Standard.
 Prepare a methanol working standard by
 pipetting 1 ml of the methanol stock
 standard into a 100-ml volumetric flask.
 Dilute the solution to 100 ml with
 water.
   7.2.3.2  Methanol Standards For
Jmpinger Samples. Prepare a series of
 methanol standards by pipetting 1, 2, 5,
 10., and 25 ml of methanol working
 standard solution respectively into five
 50-ml volumetric flasks. Dilute the
 solutions to 50 ml with water. These
 standards will have 2, 4, 10, 20, and 50
 pg/ml of methanol, respectively. After
 preparation,  transfer the solutions to 40-
 ml glass vials capped with Teflon®
 septa and store the vials under
 refrigeration. Discard any excess
 solution.
   7.2.3.3  Methanol Standards for
 Adsorbent Tube Samples. Prepare a
 series of methanol standards by first
 pipetting 10  ml of the methanol working
 standard into a 100-ml volumetric flask
and diluting the contents to,exactly 100
ml with 3 percent n-propanol solution.
This standard will contain 10 jig/ml of
methanol. Pipette 5, 15, and 25 ml of
this standard, respectively, into four 50-
ml volumetric flasks. Dilute each
solution to 50 ml with 3 percent n-
propanol solution. These standards will
have 1,3, and 5 jig/ml of methanol,
respectively. Transfer all four standards
into 40-ml glass vials capped with
Teflon®-lined septa and store under
refrigeration.  Discard any excess
solution.
  7.2.4  GC Column. Capillary column,
30 meters (100 feet) long with an inside
diameter (ID) of 0.53 mm (0,02 inch),
coated with DB 624 to a film thickness
of 3.0 micrometers, (nm) or an
equivalent column. Alternatively, a 30-
meter capillary column coated with
polyethylene glycol to a film thickness
of 1 urn such  as AT-WAX or its
equivalent.
  7.2.5  Helium. Ultra high purity.   .
  7.2.6  Hydrogen. Zero grade.
  7.2.7  Oxygen. Zero grade.   "
8.0  Procedure

  8.1  Sampling. The following items
are required for sampling:
  8.1.1  Preparation of Collection
Train. Measure 20 ml of water, into the
midget impinger. The adsorbent tube
must contain 520 mg of silica gel in the
front section and 260 mg of silica gel in
the backup section. Assemble the train
as shown in Figure 308-1. An optional,
second impinger that is left empty may
be placed in front of the water-
containing impinger to act as a    <
cOndensate trap. Place crushed ice and
water around the impinger.
BILUNG CODE 6S60-5O-P

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 18632     Federal  Register/Vol. 63, No. 72/Wednesday, April 15,  1998/Rules and Regulations
                       UNHEATED
                       TEFLON
                       LINE
SLICAGEL
TUBE
(520(2SOmg)
                                 Figure 308.1. Sampling train schematic
BILLING CODE 656O-50-C

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             Federal Register/Vol. 63. No. 72/Wednesday. April  15,'  1998/Rules and Regulations
                                                                     18633
   8.1.2  Leak Check. A leak check prior
 to the sampling run is optional;
 however, a leak check after the sampling
 run is mandatory. The leak-check
 procedure is as follows:
   Temporarily attach a suitable (e.g., 0-
 to 40-ml/min) rotameter to the outlet of
 the DGM, and place a vacuum gauge at
 or near the probe inlet. Plug the probe
 inlet, pull a vacuum of at least 250 mm
 (10 inch) Hg, and note the flow rate as
 indicated by the rotameter. A leakage
 rate not in excess of 2 percent of the
 average sampling rate is acceptable.
   Note: Carefully release the probe inlet plug
 before turning off the purhp.

   8.1.3  Sample Collection. Record the
 initial DGM reading and barometric
 pressure. To begin sampling, position
 the tip of the Teflon® tubing at the
 sampling point, connect the tubing to
 the impinger, and start the pump.
 Adjust the sample flow to a constant
 rate between 200 and 1000 ml/min as,
 indicated by the rotameter. Maintain
 this constant rate (±10 percent) during
 the entire sampling run. Take readings
 (DGM, temperatures at DGM and at
 impinger outlet, and rate meter) at least
 every 5 minutes; Add more ice during
 the run to keep the temperature  of the
 gases leaving the last impinger at 20 °C
 (68 °F) or less. At the conclusion of each
 run, turn off the pump, remove the
 Teflon® tubing from the stack, and
 record the final readings. Conduct a leak
 check as in section 8.1.2. (This leak
 check is mandatory.) If a leak is  found,
 void the test run or use procedures
 acceptable to the Administrator  to
 adjust the sample volume for the
 leakage.
   8.2 Sample Recovery. The following
 items are required for sample recovery:
   8.2.1  Impinger. Disconnect the
 impinger. Pour the contents of the
 midget impinger into a graduated l
 cylinder. Rinse the midget impinger and
• the 'connecting tubes with water, and
 add the rinses to the graduated cylinder.
 Record the sample volume. Transfer the
 sample to a glass vial and cap with a
 Teflon® septum. Discard any excess
 sample. Place the samples in an ice
 chest for shipment to the laboratory.
   8.2.2.  Adsorbent Tubes. Seal the
 silica gel adsorbent tubes and place
 them in an ice chest for shipment to the
 laboratory.

 9.0  Quality Control

 .  9.1  Miscellaneous Quality Control
 Measures. The following quality control
 measures are required:       .  . • •
Section
8.1.2,
8.1.3,
10.1.
10.2 	
Quality control
measure
Sampling equip-
ment leak
check and
calibration.
GC calibration ..
Effect
Ensures accu-
rate measure-
ment of sam-
ple volume.
Ensures preci-
sion of GC
analysis.
  9.'2  Applicability. When the method
is used to analyze samples to
demonstrate compliance with a source
emission regulation, an audit sample
must be analyzed, subject to availability.
  9.3  Audit Procedure. Analyze an
audit sample with each set of
compliance samples. Concurrently
analyze the audit sample and a set of
compliance samples in the same manner
to evaluate the technique of the analyst
and the standards preparation. The
same analyst, analytical reagents, and
analytical system shall be used both for
the compliance samples and the EPA
audit sample.
'  • 9.4  Audit Sample Availability.    I
Audit samples will be  supplied only to
enforcement agencies for compliance
tests. Audit samples may be obtained by
writing: Source Test Audit Coordinator
(MD-77B),  Air Measurement Research
Division, National Exposure Research
Laboratory, U.S. Environmental
Protection Agency, Research Triangle
Park, NC 27711; or by calling the Source
Test Audit  Coordinator (STAC) at (919)
541-7834. The audit sample request
must be made at least 30 days prior to
the scheduled compliance sample .
analysis.
  9.5  Audit Results. Calculate the
audit sample concentration according to
the calculation procedure provided in
the audit instructions included with the
audit sample. Fill in the audit sample
concentration and the analyst's name on
the audit response form included with
the audit instructions.  Send one copy to
the EPA Regional Office or the
appropriate enforcement agency and a
second copy to the STAC. The EPA
Regional office or the appropriate
enforcement agency will report the
results of the audit to the laboratory
being audited. Include this response
with the results of the compliance
samples in  relevant reports to the EPA
Regional Office or the appropriate
enforcement agency.
10.0  Calibration and Standardization
  10.1   Metering System. The following
items are required for the metering
system:
  10.1.1  Initial Calibration.
  10.1.1.1  Before its initial use in the
field, first leak-check the metering
system (drying tube, needle valve,
pump, rotameter, and DGM) as follows:
Place a vacuum'gauge at the inlet to the
drying tube, and pull a vacuum of 250
mm (10 inch) Hg; plug or pinch off the
outlet of the flow meter, and then turn
off the pump. The vacuum shall remain.
stable for at least 30 seconds. Carefully
release the vacuum gauge before
releasing the flow meter end.
   10.1.1.2  Next, remove the drying
tube, and calibrate the metering system
(at the sampling flow rate specified by
the method) as follows: Connect an
appropriately sized wet test meter (e.g.,
1 liter per revolution (0.035 cubic feet
per revolution)) to the inlet of the drying
tube. Make three independent
calibrations runs, using at least five
revolutions of the DGM per run.
Calculate the calibration factor, Y (wet
test meter calibration volume divided by
the DGM volume, both volumes
adjusted to the same reference
temperature and pressure), for each run,
and average the results. If any Y-value
deviates by mbre than 2 percent from
the average, the'metering system is
unacceptable for use. Otherwise, use the
average as the calibration factor for
subsequent test runs.
   10.1.2 Posttest Calibration Check.
After each field test series, conduct a
calibration check as in section 10.1.1
above, except for the following
variations: (a) The leak check is not to
be conducted, (b) three, or more
revolutions of the DGM may be used,
and (c) only two independent runs need
be made. If the calibration factor do.es
not deviate by more than 5 percent from
the initial calibration factor (determined
in section 10.1.1), then the DGM
volumes obtained during the test series
are acceptable. If the calibration factor
deviates by more than 5 percent,
recalibrate the metering system as in
section 10.1.1, and for the calculations,
use the calibration factor (initial or
recalibration) that yields the lower gas
volume for each test run.
   10.1.3 . Temperature Sensors.
Calibrate against mercury-in-glass
thermometers. -
  10.1.4  Rotameter. The rotameter
need not be calibrated, but should be
cleaned and maintained according to  .
the manufacturer's instruction.
   10.1.5  Barometer. Calibrate against a
mercury barometer.
   10.2  Gas Chromatograph. The
following procedures are required for
the gas chromatograph:
   10.2.1  Initial Calibration. Inject 1 ul
of each of the standards prepared in
sections 7.2.3.3  and 7.2.3.4 into the GC
and record the response. Repeat the
injections for each standard until two
successive injections agree within 5
percent. Using the mean response for

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18634
Federal Register/Vol. 63, No. 72/Wednesday, April 15,  1998/Rules and Regulations
each calibration standard, prepare a
linear least squares equation relating the
response to the mass of methanol in the
sample. Perform the calibration before
analyzing each set of samples.
  10.2.2 Continuing Calibration. At
the beginning of each day, analyze the
mid level calibration standard as
described in section 10.5.1. The
response from the daily analysis must
agree with the response from the initial
calibration within 10 percent. If it does
not, the initial calibration must be
repeated.
11.0  Analytical Procedure
  11.1  Gas Chromatograph Operating
Conditions. The following operating
conditions are required for the GC:
  11.1.1  Injector. Configured for
capillary column, splitiess, 200 °C (392
°F).
  11.1.2 Carrier. Helium at 10 ml/min.
  11.1.3 Oven. Initially at 45 °C for 3
minutes; then raise by 10 °C to 70 °C;
then raise by 70 °C/min to 200 °C.
  11.2  Impinger Sample. Inject 1 ul of
the stored sample into the GC. Repeat
the injection and average the results. If
the sample response is above that of the
highest calibration standard, either
dilute the sample until it is in the
measurement range of the calibration
line or prepare additional calibration
standards. If the sample response is
below that of the lowest calibration
standard, prepare additional calibration
standards. If additional calibration
standards are prepared, there shall be at
least two that bracket the response of
the sample. These standards should
produce approximately 50 percent and
                          150 percent of the response of the
                          sample.
                            11.3  Silica Gel Adsorbent Sample.
                          The following items are required for the
                          silica gel adsorbent samples:
                            11.3.1  Preparation of Samples.
                          Extract the front and backup sections of
                          the adsorbent tube separately. With a
                          file, score the glass adsorbent tube in
                          front of the first section of silica gel.
                          Break the tube open. Remove and
                          discard the glass wool. Transfer the first
                          section of the silica gel to a 5-ml glass
                          vial and stopper the vial. Remove the
                          spacer between the first and second
                          section of the adsorbent tube and
                          discard it. Transfer the second section of
                          silica gel to a separate 5-ml glass vial
                          and stopper the vial.
                            11.3.2  Desorption of Samples. Add 3
                          ml of the 10 percent n-propanol solution
                          to each of the stoppered vials and shake
                          or vibrate the vials for 30 minutes.
                            11.3.3  Inject a 1-jil aliquot of the
                          diluted sample from each vial into the
                          GC. Repeat the injection and average the
                          results. If the sample response is above
                          that of the highest calibration standard,
                          either dilute the sample until it is in the
                          measurement range of the calibration
                          line or prepare additional calibration
                          standards. If the sample response is
                          below that of the lowest calibration
                          standard, prepare additional calibration
                          standards. If additional calibration
                          standards are prepared, there shall be at
                          least two that bracket the response of
                          the sample. These standards should
                          produce approximately 50 percent and
                          150 percent of the response of the
                          sample.
12.0  Data Analysis and Calculations
  12.1  Nomenclature.
Caf=Concentration of methanol in the
    front of the adsorbent tube, jig/ml.
Cab=Concentration of methanol in the
    back of the adsorbent tube, ug/ml.
Ci=Concentration of methanol in the
    impinger portion of the sample
    train, ug/ml.
E=Mass emission rate of methanol, ug/
    hrdb/hr).
Mtot=Total mass of methanol collected
    Lruthe sample train, (ig,
Pbar=Barometric pressure at the exit
    orifice of the DGM, mm Hg (in. Hg).
Pstd=Standard absolute pressure, 760
    mm Hg (29.92 in. Hg).
Qstd=Dry volumetric stack gas flow rate
    corrected to standard conditions,
    dscm/hr (dscf/hr),
Tm=Average DGM 'absolute temperature, '
    degrees K (°R).
Tstd=Standard absolute temperature, 293
    degrees K (528 °R).
Vaf=Volume of front half adsorbent
    sample, ml.
Vab=Volume of back half adsorbent
    sample, ml.
Vi=Volume of impinger sample, ml.
Vm=Dry gas volume as measured by the
    DGM, dry cubic meters (dcm), dry
    cubic feet (dcf).
Vm(Std)=Dry gas volume measured by the
    DGM, corrected to standard
    conditions, dry standard cubic
    meters (dscm), dry standard cubic
    feet (dscf).
  12.2  Mass of Methanol. Calculate the
total mass of methanol collected in the
sampling train  using Equation 308-1.
                                                         3ab       Equation 308-1
    12.3  Dry Sample Gas Volume, Corrected to Standard Conditions; Calculate the  volume of gas sampled at standard
conditions using Equation 308-2.

                                            V  Y T  P
                                   Vm(std)= m  XstdJrbar         Equation 308 -2 .

    12.4  Mass Emission .Rate of Methanol. Calculate the mass emission rate of methanol using Equation 308-3.
                                  •p „
                                    _ MtotQsd
                                       V,
                                                                 Equation 308-3
                                        m(std)
13.0  Method Performance [Reserved]
14.0  Pollution Prevention [Reserved]
15.0  Waste Management [Reserved]
16.0  Bibliography

  1. Rom, JJ. "Maintenance,
Calibration, and Operation of Isokinetic
Source Sampling Equipment." Office of
Air Programs. Environmental Protection
                          Agency. Research Triangle Park, NC.
                          APTD-0576 March 1972.
                            2. Annual Book of ASTM Standards.
                          Part 31; Water, Atmospheric Analysis.
                          American Society for Testing and
                          Materials. Philadelphia, PA. 1974. pp.
                          40-42.
                            3. Westlin, P.R. and R.T. Shigehara.
                          "Procedure for Calibrating and Using
                          Dry Gas Volume Meters as Calibration
Standards." Source Evaluation Society
Newsletter. 3(1) : 17-30, February 1978.
  4. Yu, K.K. "Evaluation of Moisture
Effect on Dry Gas Meter Calibration."
Source Evaluation Society Newsletter.
5(1) :24-28. February 1980.
  5. NIOSH Manual of Analytical
Methods, Volume 2. U.S. Department of
Health and Human Services National
Institute for Occupational Safety and
Health. Center for Disease Control. 4676

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               Federal Register/Vol. 63. No. 72/Wednesday. April 15,  1998/Rules and Regulations       18635
 Columbia Parkway, Cincinnati, OH
 45226. (available from the
 Superintendent of Documents,
 Government Printing Office,
 Washington, DC 20402.)
   6. Pinkerton, J.E. "Method for
 Measuring Methanol in Pulp Mill Vent
 Gases." National Council of the Pulp
 and Paper Industry for Air and Stream
 Improvement, Inc., New York, NY.
 17.0  Tables, Diagrams, Flowcharts,
 and Validation Data
   [Reserved].
 PART 261—[AMENDED]

   1. The authority citation of part 261
 continues to read, as follows:         .
   Authority: 42 U.S.C. 6905, 6912(a), 6921,
 6922, and 6938.
.   2. Section 261.4 is amended by
 adding paragraph (a) (15) to read as
 follows:

 §261.4  Exclusions.
   (a) * *  *  ,
   (15) Condensates derived from the
 overhead gases from kraft mill steam
 strippers that are used to comply with
 40 CFR 63.446(e). The exemption
 applies only to combustion at the mill
 generating the condensates.
 *    *     *  ,   *    *
   1. Part 430 is revised to read as
 follows:                •

 PART 430—THE PULP,  PAPER, AND
 PAPERBOARD POINT SOURCE
 CATEGORY

 General Provisions
 Sec.
 430.00 Applicability.
 430.01  .General definitions.
 430.02 Monitoring requirements.
 430.03 Best management practices (BMPs)
     for spent pulping liquor, soap, and
     turpentine management-spill
     prevention, and control.
 Subpart A—Dissolving Kraft Subcategory
 Sec.
 430.10 Applicability; description of the
     dissolving kraft subcategoiy.
 430.11  Specialized definitions.
 430.12 Effluent limitations representing the
     degree of effluent reduction attainable by
     the application of best practicable
     control technology currently available
     (BPT).
 430.13 Effluent limitations guidelines
     representing the degree of effluent
     reduction attainable by the best
     conventional pollutant control
     technology (BCT).
 430.14 Effluent limitations representing the
     degree of effluent reduction attainable by
     the application of best available
   ,  technology economically achievable
     (BAT).
 430.15  New source performance standards
     (NSPS).
 430.16  Pretreatment standards for existing
     sources (PSES).
 430.17  Pretreatment standards for new
     sources (PSNS).

 Subpart B—Bleached Papergrade Kraft and
 Soda Subcategory
 Sec.
 430.20  Applicability; description of the
     bleached papergrade kraft and soda
     Subcategory.
 430.21  Specialized definitions.
 430.22  Effluent limitations representing the
     degree of effluent reduction attainable by
     the application of best practicable
     control technology currently available
     (BPT).       • ,    .
 430.23  Effluent limitations representing the
     degree of effluent reduction attainable by
     the best conventional pollutant control
     technology (BCT).
 430.24  Effluent limitations representing the
     degree of effluent reduction attainable by
     the application of best available
     technology economically achievable
     (BAT).
 430.25  New source performance standards
     (NSPS).
 430.26  Pretreatment standards for existing
     sources (PSES).
 430.27  Pretreatment standards for new
    sources (PSNS).
 430.28  Best management practices (BMPs):

 Subpart C—Unbleached Kraft Subcategoiy
 Sec.
 430.30  Applicability; description of the
    unbleached kraft subcategory.
 430.31  Specialized definitions.
 430.32  Effluent limitations representing the
    degree of effluent reduction attainable by
    the application of best practicable
    control technology currently available
     (BPT).
 430.33  Effluent limitations representing the
    degree of effluent reduction attainable by
    the best conventional pollutant control
    technology (BCT).
 430.34  Effluent limitations representing the
    degree of effluent reduction attainable by
    the application of best available
    technology economically achievable
     (BAT).
 430.35  New source performance standards
     (NSPS).
 430.36  Pretreatment standards for existing
     (PSES).
 430.37  Pretreatment standards for new
    sources (PSNS).

 Subpart D—Dissolving Sulfite Subcategory
 Sec.
 430.40  Applicability; description of the
    dissolving sulflte subcategory.
 430.41  Specialized definitions.   •
 430.42  Effluent limitations representing the
    degree of effluent reduction attainable by
    the application of best practicable
    control technology currently available
     (BPT).
•430.43  Effluent limitations representing the
    degree of effluent reduction attainable by
    the best conventional pollutant control
    technology (BCT).
430.44  Effluent limitations representing the
    degree of effluent reduction attainable by
    the application of best available
    technology economically achievable
    (BAT).
430.45  New source perfbnmance standards
    (NSPS).
430.46  Pretreatment standards for existing
    sources (PSES).
430.47  Pretreatment standards for new
    sources (PSNS).

Subpart E—Papergrade Sulfite Subcategory
Sec.
430.50  Applicability; description of the
    papergrade sulfite subcategory.
430.51  Specialized definitions.
430.52  Effluent limitations representing the
    degree of effluent reduction attainable by
    the application of best practicable
    control technology currently available
    (BPT).
430.53  Effluent limitations representing the
    degree of effluent reduction attainable by
    the best conventional pollutant control
    technology (BCT).
430.54  Effluent limitations representing the
  '  degree of effluent reduction .attainable by
    the application of best available
    technology economically achievable
    (BAT).
430.55  New source performance standards
    (NSPS).
430.56  Pretreatment standards for existing
    sources (PSES).
430.57  Pretreatment standards for new
    sources (PSNS).
430.58  Best management practices (BMPs).  -

Subpart F—Semi-Chemical Subcategory
Sec.
430.60  Applicability; description of the
    semi-chemical subcategory.
430.61  Specialized definitions.
430.62  Effluent limitations representing the
    degree of effluent reduction attainable by
    the application of best practicable
    control technology currently available
    (BPT).
430.63  Effluent limitations representing the
    degree of effluent reduction attainable by
    the best conventional pollutant control
    technology (BCT).
430.64  Effluent limitations representing the
    degree of effluent reduction attainable by
    the application of best available   .  ,
    technology economically achievable
    (BAT): '  ,   .   •
430.65  New source performance standards
    (NSPS).
430.66  Pretreatment standards for existing
    sources (PSES).
430.67  Pretreatment standards for new
    sources (PSNS).

Subpart G—Mechanical Pulp Subcategory
Sec.
430.70  Applicability; description of the
    mechanical pulp subcategory.
430.71  Specialized definitions.
430.72  Effluent limitations representing the
    degree of effluent reduction attainable by
    the application of best practicable
    control technology currently available
    CBPT).

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18636
Federal Register/Vol. 63,  No.  72/Wednesday, April  15, 1998/Rules  and Regulations
430.73  Effluent limitations representing the
    degree of effluent reduction attainable by
    the best conventional pollutant control
    technology (BC1).
430.74  Effluent limitations representing the
    degree of effluent reduction attainable by
    the application of best available
    technology economically achievable
    (BAT).
430.75  New source performance standards
    (NSPS).
430.76  Pretreatment standards for existing
    sources (PSES).
430.77  Pretreatment standards for new
    sources (PSNS).

Subpart H—Non-Wood Chemical Pulp
Subcategory

Sec.
430.80  Applicability; description of the
    non-wood chemical pulp subcategory.
430.81  Specialized definitions.
430.82  Effluent limitations representing the
    degree of effluent reduction attainable by
    the application of best practicable
    control technology currently available
    (BPT). [Reserved]
430.83  Effluent limitations representing the
    degree of effluent reduction attainable by
    the best conventional pollutant control
    technology (BCT). [Reserved]
430.84  Effluent limitations representing the
    degree of effluent reduction attainable by
    the application of best available
    technology economically achievable   '
    (BAT). [Reserved]
430.85  New source performance standards
    (NSPS). [Reserved]
430.86  Pretreatment standards for existing
    sources (PSES). [Reserved]
430.87  Pretreatment standards for new
    sources (PSNS). [Reserved]

Subpart I—Secondary Fiber Deink
Subcategory
Sec.
430.90  Applicability; description of the
    secondary fiber deink subcategory.
430.91  Specialized definitions.
430.92  Effluent limitations representing the
    degree of effluent reduction attainable by
    the application of best practicable
    control technology currently available
    (BPT).
430.93  Effluent limitations representing the
    degree of effluent reduction attainable by
    the best conventional pollutant control
    technology (BCT).
                            430.94  Effluent limitations representing the
                                degree of effluent reduction attainable by
                                the application of best available
                                technology economically achievable
                                (BAT).
                            430.95  New source performance standards
                                (NSPS).
                            430.96  Pretreatment standards for existing
                                sources (PSES).
                            430.97  Pretreatment standards for new
                                sources (PSNS).

                            Subpart J—Secondary Fiber Non-Deink
                            Subcategory
                            Sec.
                            430.100  Applicability; description of the
                                secondary fiber non-deink subcategory.
                            430.101  Specialized definitions.
                            430.102  Effluent limitations representing
                                the degree of effluent reduction
                                attainable by the application of best
                                practicable control technology currently
                                available (BP1).
                            430.103  Effluent limitations representing
                                the degree of effluent reduction
                                attainable by the best conventional
                                pollutant control technology (BCT).
                            430.104  Effluent limitations representing
                                the degree of effluent reduction
                                attainable by the application of best
                                available technology 'economically
                                achievable (BAT).
                            430.105  New source performance standards
                                (NSPS).
                            430.106  Pretreatment standards for existing
                                sources (PSES).
                            430.107  Pretreatment standards for new
                                sources (PSNS).

                            Subpart K—Fine and Lightweight Papers
                            From Purchased Pulp Subcategory
                            Sec.
                            430.110  Applicability; description of the
                                fine and lightweight papers from
                                purchased pulp subcategory.
                            430.1.11  Specialized definitions.
                            430.112  Effluent limitations representing
                                the degree of effluent reduction
                                attainable by the application of best
                                practicable control  technology currently
                                available (BPT).
                            430.113  Effluent limitations representing
                                the degree of effluent reduction
                                attainable by the best conventional
                                pollutant control technology (BCT).
                            430.114  Effluent limitations representing
                                the degree of effluent reduction .
                                attainable by the application of best
                                available technology economically
                                achievable (BAT).
                            430.115  New source performance standards
                                (NSPS).
430.116  Pretreatment standards for existing
    sources (PSES).
430.117  Pretreatment standards for new  •
    sources (PSNS).

Subpart L—Tissue, Filter, Non-Woven, and
Paperboard From Purchased Pulp
Subcategory
Sec.
430.120  Applicability; description of the
    tissue, filter, non-woven, and paperboard
    from purchased pulp subcategory.
430.121  Specialized definitions.
430.122  Effluent limitations representing
    the degree of effluent reduction
    attainable by the application of best
    practicable control technology currently
    available (BPT).
4:30.123  Effluent limitations representing
    the degree of effluent reduction
    attainable by the best conventional
    pollutant control technology (BCT).
430.124  Effluent limitations representing
    the degree of effluent reduction
    attainable by the application of best
    available technology economically
    achievable (BAT).-
430.125  New source performance standards
    (NSPS).
430.126  Pretreatment standards for existing
    sources (PSES).
430.127  Pretreatment standards for new
    sources (PSNS).-

Appendix A to Part 430—Methods 1650 and
1653
  Authority: Sections 301, 304, 306,  307,
308, 402, and 501 of the Clean Water Act. as
amended, (33U.S.C.  1311, 1314, 1316, 1317,
1318,1342, and 1361), and Section 112 of the
Clean Air Act, as amended (42 U.S.C. 7412).

General Provisions

§430.00  Applicability.

  (a) This part applies to any pulp,
paper, or paperboard mill that
discharges or may discharge process
wastewater pollutants to the waters of
the United States, or that introduces or
may introduce process wastewater
pollutants into a publicly owned
treatment works.

  (b) The following table presents the
subcategorization scheme codified in
this part, with references to former
subpart designations contained in the
1997 edition of 40  CFR parts 425
through 699:

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              Federal Register/Vol. 63. No. 72/Wednesday. April  15,  1998/Rules and  Regulations       18637

  SUBCATEGORIZATION SCHEME WITH REFERENCES TO FORMER SUBPARTS CONTAINED IN THE.JULY. 1, 1997 EDITION OF
                                           40 CFR PARTS 425 THROUGH 699
 Final codi-
 fied subpart
  Final subcategorization scheme
                      Types of products covered in the subpart
 A
 B
 D

 E
 F
 G
H
I-
J .
Dissolving Kraft	
Bleached Papergrade  Kraft and
  Soda.
             Unbleached Kraft
Dissolving Sulfite
Papergrade Sulfite	;...'.	
—Calcium-, Magnesium-, or  So-
  dium-based pulps.
—Ammonium-based pulps.
—Specialty grade pulps.
Semi-Chemical	
Mechanical Pulp	
Non-Wood Chemical Pulp ...
Secondary Fiber Deink	
Secondary Fiber Non-Deink
            Fine and Lightweight Papers from
              Purchased Pulp.

            Tissue, Filter, Non-woven, and Pa-
              perboard from Purchased Pulp.
 Dissolving pulp at kraft mills (Fa)
.Market pulp at bleached kraft mills (Ga); paperboard, coarse paper, and tissue paper at
  bleached kraft mills (H<>); pulp  and fine papers at bleached kraft mills (la); and pulp and
  paper at soda mills (Pa).
 Pulp and paper at unbleached kraft mills, including linerboard or bag paper and other mixed
  products  (A<>); pulp and paper using the unbleached kraft-neutral sulfite semi-chemical
  (cross recovery) process (D=>); and pulp and paper at combined unbleached kraft and semi-
  chemical  mills,  wherein the spent semi-chemical cooking liquor is  burned within the  un-
  bleached kraft chemical recovery system (\A>).
 Pulp at dissolving sulfite mills for  the following grades: nitration, viscose, cellophane, and  ac-
  etate (K=>). .-.'..
 Pulp and paper at papergrade sulfite mills where blow pit pulp washing techniques are used
  (Ja) and pulp and paper at papergrade sulfite mills where vacuum or pressure drums  are
  used to wash pulp (Ua).


 Pulp and paper at semi-chemical mills using  an ammonia base or a sodium base (Ba).
 Pulp and paper at groundwood chemi-mechanical mills (L»); pulp .and paper at groundwood
  mil|s through the application of the thermo^mechanical  process (Ma);  pulp and coarse
  paper, molded pulp products, and  newsprint at groundwood mills.(Na); and pulp-and fine
  paper at groundwood mills (Oa).
 Pulp and paper at non-wood chemical pulp mills.
 Pulp and paper at deink mills including fine papers, tissue papers, or newsprint (Q»).
 Paperboard from wastepaper from noncorrugating medium furnish or from corrugating me-
  dium furnish (E»); tissue paper from wastepaper without deinking at secondary fiber mills
  (T<>); molded products from wastepaper without deinking (W*); and builders' paper and roof-
  ing felt from wastepaper (40 CFR Part 431, Subpart A*).
 Fine Papers at nonintegrated mills using wood fiber furnish or cotton fiber furnish (Ra); and
  lightweight papers at nonintegrated mills or lightweight electrical papers at noninteprated
  mills (X*).                                                              a
Tissue papers at nonintegrated mills (Sa); filter and non-woven papers at nonintegrated mills
  (Ya); and paperboard at nonintegrated mills (Z=>).
  "This subpart is contained in the 40 CFR parts 425 through 699, edition revised as of July 1,1997.
§430.01  General definitions.
  In addition to the definitions set forth
in 40 CFR part 401 and 40 CFR 403.3,
the following definitions apply to this
part:   '          .
  (a) Adsorbable organic halides (AOX).
A bulk parameter that measures the total
mass of chlorinated organic matter in
water and wastewater.
  (b) Annual average. The mean
concentration, mass loading or
production-normalized mass loading of
a pollutant over a period of 365
consecutive days (or such other period
of time determined by the permitting
authority to be sufficiently long to
encompass expected variability of the
concentration, mass loading, or.
production-normalized mass loading at
the relevant point of measurement).
  ,(c) Bleach plant.  All process
equipment used for bleaching beginning
with the first application of bleaching
agents (e.g., chlorine/chlorine dioxide,
ozone, sodium or calcium hypochlorite,
                             or peroxide), each subsequent extraction
                             stage, and each subsequent stage where
                             bleaching agents are applied to the pulp.
                             For mills in Subpart E of this part
                             producing specialty grades of pulp, the
                            • bleach plant includes process
                             equipment used for the hydrolysis or
                             extraction stages prior to the first
                             application of bleaching agents. Process
                             equipment used for oxygen
                             delignificatipn prior to the application
                             of bleaching agents is not part of the
                             bleach plant.  ,
                               (d) Bleach plant effluent. The total
                             discharge of process wastewaters from
                             the bleach plant from each physical
                             bleach line operated at the mill,
                             comprising separate acid and alkaline
                             filtrates or the combination thereof.
                               (e) Chemical oxygen demand (COD).
                             A bulk parameter that measures the
                             oxygen-consuming capacity of organic
                             and inorganic matter present in water or
                             wastewater. It is expressed as the
                             amount of oxygen consumed from a
                             chemical oxidant in a specific test.
                                         (f) Elemental chlorine-free (ECF). Any
                                       process for bleaching pulps in the
                                       absence of elemental chlorine and
                                       hypochlorite that uses exclusively
                                       chlorine dioxide as the only chlorine-
                                       containing .'bleaching agent.
                                         (g) End of the pipe. The point at
                                       which final mill effluent is discharged
                                       to waters of the United States or
                                       introduced to a POTW.
                                         (h) Fiber line. A series of operations
                                       employed to convert wood or other
                                       fibrous raw material into pulp. If the
                                       final product is bleached pulp, the fiber
                                       line encompasses pulping, de-knotting,
                                       brownstock washing, pulp screening,
                                       centrifugal cleaning, and multiple
                                       bleaching and washing stages.
                                         (i) Minimum level (ML). The level at
                                       which the analytical system gives
                                       recognizable signals and an acceptable
                                       calibration point. The following
                                       minimum levels apply to pollutants in
                                       this part.

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18638      Federal  Register/Vol. 63, No. 72/Wednesday,  April 15, 1998/Rules  and Regulations
Pollutant
2378-TCDD . 	
2,3,7.8-TCDF 	 ; 	 	 	 -....
Trichlorosyringol 	 .. 	 	
3,4,5-TrichlorocatechoI 	 	 	
3,4,6-Trichlorocalechol 	 : 	
3 4 5-Trichloroguaiacol


2|4|5-Trichtorophenol 	 	 	
2 4l6-Trichl0ropnenol 	 • 	
Tetracnlorocatechol 	
Tetrachlorogualacol 	 	 ••—
234 6-Tetrach!orophenol 	 	 	

AOX 	 	 	 	 	 . 	
Method
1613
1613
1653
1653
1653
1653
1653
1653
1653
1653
1653
1653
1653
1653
1650
Minimum level
10 pg/La
10 pg/La
2.5 ug/Lb
5.0 ug/Lb
5.0 ug/Lb
2.5 ug/Lb
2.5 ug/Lb
2.5 ug/Lb
2.5 ug/Lb
2.5 ug/Lb
5.0 ug/Lb
5.0 ug/Lb
2.5 ug/Lb
5.0 ug/Lb
20 uq/Lb
  "PIcograms per liter.
  bMterograms per liter.
  (j) New source. (1) Notwithstanding
the criteria codified at 40 CFR
122.29(b)(l), a source subject to-subpart
B or E of this part is a "new source" if
it meets the definition of "new source"
at 40 CFR 122.2 and:
  (i) It is constructed at a site at which
no other source is located; or
  (ii) It totally replaces the process or
production equipment that causes the
discharge of pollutants at an existing
source, including the total replacement
of a fiber line that causes the discharge
of pollutants at an existing source,
except as provided in paragraph (j)(2) of
this section; or
  (iii) Its processes are substantially
independent of an existing source at the
same site. In determining whether these
processes are substantially independent,
the Director shall consider such factors
as the extent to which the new facility
is integrated with the existing plant; and
the extent to which the new facility is
engaged in the same general type of
activity as the existing source.
  (2) The following are examples of
changes made by mills subject to
subparts B or E of this part that alone
do not cause an existing mill to become
a "new source":
  (i) Upgrades of existing pulping
operations;
  (ii) Upgrades or replacement of pulp
screening and washing operations;
  (iii) Installation of extended cooking
and/or oxygen delignification systems
or other post-digester, pre-bleaching
delignification systems;
  (iv) Bleach plant modifications
including changes in methods or
amounts of chemical applications, new
chemical applications, installation of
new bleaching towers to facilitate
replacement of sodium or calcium
hypochlorite, and installation of new
pulp washing systems; or
  (v) Total replacement of process or
production equipment that causes the
discharge of pollutants at an existing
source (including a replacement fiber
line), but only if such replacement is
performed for the purpose of achieving
limitations that have been included in
the discharger's NPDES permit pursuant
to§430.24(b).
  (k) Non-continuous discharger. (1)
Except as provided in paragraph (k) (2)
of this section, a non-continuous
discharger is a mill which is prohibited
by the NPDES authority from
discharging pollutants during specific
periods of time for reasons other than
treatment plant upset control, such
periods being at least 24 hours in
duration. A mill shall not be deemed a
non-continuous discharger unless its
permit, in addition to setting forth the
prohibition described above, requires
compliance with the effluent limitations
established for non-continuous
dischargers and also requires
compliance with maximum day and
average of 30 consecutive days effluent
limitations. Such maximum day and
average of 30 consecutive days effluent
limitations for non-continuous
dischargers shall be established by the
NPDES authority in the form of
concentrations which reflect wastewater
treatment levels that are representative
of the application of the best practicable
control technology currently available,
the best conventional pollutant control
technology, or new source performance
standards in lieu of the maximum day  •
and average of 30 consecutive days
effluent limitations for conventional
pollutants set forth in each subpart.
  (2) A mill is a non-continuous  '
discharger for the purposes of
determining applicable effluent
limitations under subpart B or E of this
part (other than conventional limits for
existing sources) if, for reasons other
than treatment plant upset control (e.g.,
protecting receiving water quality), the
mill is prohibited by the NPDES
authority from discharging pollutants
during specific periods of time or if it
is required to release its discharge on a
variable flow or pollutant loading rate
basis.
  (1) POTW. Publicly owned treatment
works as defined at 40 CFR 403.3 (o).
  (m) Process wastewater. For subparts
B and E only, process wastev/ater is any
water that, during manufacturing or
processing, comes into direct contact
with or results from the production or
use of any raw material, intermediate
product, finished product, byproduct,  or
waste product. For purposes of subparts
B and E of this part, process wastewater
includes boiler blowdown; wastewaters
from water treatment and other utility
operations; blowdowns from high rate
(e.g., greater than 98 percent)  recycled
non-contact cooling water systems  to
the extent they are mixed and co-treated
with other process wastewaters;
wastewater, including leachates, from
landfills owned by pulp and paper mills
subject to subpart B or E of this part if
the wastewater is commingled with
wastewater from the mill's
manufacturing or processing facility;
and storm waters from the immediate
process areas to the extent they are
mixed and co-treated with other process
wastewaters. For purposes of this part,
contaminated groundwaters from on-site
or off-site groundwater remediation
projects are not process wastewater.
  (n) Production. (1) For all limitations
and standards specified in this part
except those pertaining to AOX and
chloroform: Production shall be defined
as the annual off-the-machine
production (including off-the-machine
coating where applicable) divided by
the number of operating days during
that year. Paper and paperboard
production shall be measured at the off-
the-machine moisture content,-except
for subpart C of this part (as it pertains
to pulp and paperboard production at

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             Federal Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules  and Regulations
                                                                      18B39
unbleached kraft mills including
linerboard or bag paper and other mixed
products, and to pulp and paperboard
production using the unbleached kraft
neutral sulfite semi-chemical (cross
recovery) process), and subparts F and
J of this part (as they pertain to
paperboard production from wastepaper
from noncorrugating medium furnish or
from corrugating medium furnish)
where paper and paperboard production
shall be measured in air-dry-tons (10%
moisture content). Market pulp shall be
measured in air-dry tons (10%
moisture). Production shall be
determined for each mill based upon
past production practices, present
trends, or committed growth.
  (2) ForAOX and chloroform ,
limitations and standards specified in
subparts B and^E of this part: Production
shall be defined as the annual
unbleached pulp production entering
the first stage of the bleach plant
divided by the number of operating days
during that year. Unbleached pulp
production shall be measured in air-
dried-metric-tons (10% moisture)  of
brownstock pulp entering the bleach
plant at the stage during which chlorine
or chlorine-containing compounds are
first applied to the pulp. In the case of
bleach plants that use totally chlorine
free bleaching processes, unbleached
pulp production shall be measured in
air-dried-metric tons (10% moisture) of
brownstock pulp entering the first stage
of the bleach plant from which
wastewater is discharged. Production
shall be determined for each mill based
upon past production practices, present
trends, or committed growth.
   (o) TCDD. 2,3,7,8-tetrachlorodibenzo-
p-dioxin.
   (p) TCDF. 2,3,7,8-tetrachlorodibenzo-
p-furan.
   (q) Totally chlorine-free (TCP)
bleaching. Pulp bleaching operations
that are performed without the use of
chlorine, sodium hypochlorite, calcium
hypochlorite, chlorine dioxide, chlorine
monoxide, or any other chlorine-  •
containing compound.
   (r) Wet Barking-. Wet barking
operations shall be defined to include
hydraulic barking operations and wet
drum barking operations which are
those drum barking operations that use
substantial quantities of water in either
water sprays in the barking drums or in
a partial submersion of the drums in a
"tub" of water.

§430.02 Monitoring requirements.

  This section establishes minimum
monitoring frequencies for certain
pollutants. Where no monitoring
frequency is specified in this section or
where the duration of the minimum  .
monitoring frequency has expired under
paragraphs (b) through (e)  of this
section, the permit writer or
pretreatment control authority shall
determine the appropriate monitoring •
frequency in accordance with 40 CFR
122.44(i),or 40 CFR part 403, as
applicable.
% (a)BAT,NSPS,PSES,andPSNS
monitoring frequency for chlorinated
organic pollutants. The following
monitoring frequencies apply to
discharges subject to subpart B or
subpart E of this part:
CAS number
1198556 	
2539175 	
2539266 	
2668248 	
32139723 . ..
56961207 . ..
57057837 . ..
58902 	
60712449 	
87865 	
88062 	
95954 	
1746016 	 	
51207319 .....
67663 	
59473040 	
,' Pollutant
Tetrachlorocatechol 	 	 	 	 	 	 	
Tetrachloroguaiacol 	 	 	 '....-. 	 ; 	 '. 	 	 ..'.. ..
Trichlofosyringol 	 	 	 '. 	 	 	
4,5,6-trichIoroguaiacol 	 	 	 	 	 .'. 	
3,4,6-trichIorocateohol ..; 	 	 	 	 	 	
3,4,5-trichlorocatechol 	 	 	 	
3,4,5-trichloroguaiacol 	 	 	 	 	 	 	 	 	
2,3,4,6-tetrachlorophenol 	 	 	
3,4,6-trichloroguaiacol 	 	 	 	
Pentachlorophenold 	 	 	 	 	
2,4,6-trichlorophenold 	 	 	 	
2,4,5-trichlorophenold 	 	 	
2378-TCDD
2,3,7,8-TCDF 	
chloroform0 	 	 	 	 	 	 	 ; 	
AOXf 	 	 	 	 	 	 	 	 	
Minimum monitoring frequency
Non-TCP*
Monthly .....
Monthly
Monthly
Monthly 	
Monthly 	
Monthly
Monthly
Monthly 	
Monthly
Monthly .
Monthly 	
Monthly
Monthly
Monthly
Weekly . .
Daily 	
TCP"
(")
w
•(•)
(<=)
(°)
(•)
(«)
(")
(-)
{")
(•)
(•)
(")
(c)
(c)
None specified.
  a Non-TCP: Pertains to any fiber line that does not use exclusively TCP bleaching processes.
  >>TCF: Pertains to any fiber line that uses exclusively TCP bleaching processes, as disclosed by the discharger in its permit application under
40 CFR 122.21(g)(3) and certified under 40 CFR 122.22 or, for indirect dischargers, as reported to the pretreatment control authority under 40
CFR 403.12 (b).(d), or (e).
  c This regulation does not specify a limit for this pollutant for TCP bleaching processes.                                   .
  d Monitoring frequency does not apply to this compound when used as a biocide. The permitting or pretreatment control authority must deter-
mine the appropriate monitoring frequency for this compound, when used as a biocide,  under 40 GFR 122.44(i) or 40 CFR Part 403, as applica-
ble.
  eThis regulation does not specify a limit for this pollutant for Subpart E mills.                      '              .-
  This regulation does not specify a limit for this pollutant for the ammonium-based or specialty grade sulfite pulp segments of Subpart E.
  (b) Duration of required monitoring
forBAT,NSPS,PSES,andPSNS.The
monitoring frequencies specified in
paragraph (a) of this section apply for
the following time periods:
  (1) For direct dischargers, a duration
of five years commencing on the date
the applicable limitations or standards
from subpart B or subpart E of this part
are first included in the discharger's
NPDES permit;
  (2) For existing indirect dischargers,
until April 17, 2006;
  (3) For new indirect dischargers, a
duration of five years commencing on
the date the indirect discharger
commences operation.
  (c) Reduced monitoring frequencies
for bleach plant pollutants under the
Voluntary Advanced Technology
Incentives Program. The following
monitoring frequencies apply to mills
enrolled in the Voluntary Advanced
Technology Incentives Program
established under subpart B of this part
for a duration of five years commencing
after achievement of the applicable BAT
limitations specified in § 430.24(b) (3) or
NSPS specified in §430.25 (c)(l) for the
following pollutants, except as noted in
footnote f:

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 18640      Federal Register/Vol.  63. No.  72/Wednesday, April  15, 1998/Rules and Regulations
CAS
number
1198556 ...
2539175 ...
2539266 ...
2668248 ...
32139723
56961207
57057837
58902 	
60712449
87865 	
88062 	
95954 	
1746016 ...
51207319
67663 	
Pollutant
Tetrachlorocatechol 	
Tetrachloroguiacol 	 .-......'. 	
Trichlorosyringol 	
4,5,6-trichloroguaiacol 	 	 	
3,4,6-trichlorocatechol 	 j 	
3,4,5-trichlorocatechol 	
3,4,5-tn'chloroguaiacol 	
2,3,4,6-tetrachlorophenol 	 . 	
3,4,6-trichloroguaiacol 	 . 	 	
Pentachlorophenol c 	 	 	
2,4,6-trichlorophenole 	 .' 	
2,4,5-trichlorophenol0 	
2,3,7,8-TCDD 	
2,3,7,8-TCDF 	
Chloroform 	 .'. 	 	 	
Minimum monitoring frequency
Non-ECF a
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly

Monthly
Monthly
Monthly
Monthly
Monthly
Weekly 	
Advanced
' ECFw
Monthly
Monthly
Monthly
Monthly ,
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
TCF=
(d)
(d)
.(")
(d)
(d)
(d)
(d)
(d)
(d)
(d)
(d)
(d)
(d)
(d)
(d)
  »Non-ECF: Pertains to any fiber line that does not use exclusively ECF or TCP bleaching processes.
  *• Advanced ECF: Pertains to any fiber line that uses exclusively Advanced ECF bleaching processes, or exclusively ECF and TCP bleaching
processes as disclosed by the discharger in its permit application under 40 CFR 122.21 (g)(3) and certified under 40 CFR 122.22. Advanced ECF
consists of the use  of  extended delignification or other technologies that  achieve at least the Tier  I  performance levels  specified in
§430.24(b)(4)(i).
  «TCF: Pertains to any fiber line that uses  exclusively TCP bleaching processes, as disclosed by the discharger in its permit application under
40 CFR 122.21 (g)(3) and certified under 40 CFR  122.22.
  •"This regulation does not specify a limit for this pollutant for TCP bleaching processes.
the permitting authority will be suspended after one year of monitoring. The permitting authority must determine the appropriate monitorina fre-
quency for these pollutants beyond that time under 40 CFR 122.44(i).
  (d) Reduced monitoring frequencies
for AOX under the Voluntary Advanced
Technology Incentives Program (year
one). The following monitoring
                                          frequencies apply to direct dischargers
                                          enrolled in the Voluntary Advanced
                                          Technology Incentives Program
                                          established under Subpart B of this part
                                                      for a duration of one year after
                                                      achievement of the applicable BAT
                                                      limitations specified in §430.24(b)(4)(i)
                                                      or NSPS specified in §430.25(c)(2):
CAS
number
59473040
Pollutant
AOX 	 	 	
Non-ECF,
any tier"
Daily 	 :
Advanced ECF,
any tierb
Weekly 	
TCP,
any tierc
None specified.
  •Non-ECF: Pertains to any fiber line that does not use exclusively ECF or TCP bleaching processes.
  >>Advanced ECF: Pertains to any fiber line that uses exclusively Advanced ECF bleaching processes or exclusively ECF and TCP bleaching
processes, as disclosed by the discharger in its permit application under 40 CFR 122.21(g)(3) and  certified under 40 CFR 122.22. Advanced
ECF consists of the use of extended  delignification or other technologies  that achieve at least the Tier I performance  level:; specified in
  CTCF: Pertains to any fiber line that uses exclusively TCP bleaching processes, as disclosed by the discharger in its permit application under
40 CFR 122.21 (g)(3) and certified under 40 CFR 122.22.
  (e) Reduced monitoring frequencies
for AOX under the Voluntary Advanced
Technology Incentives Program (years
two through five). The following
monitoring frequencies apply to mills
                                          enrolled in the Voluntary Advanced
                                          Technology Incentives Program
                                          established under Subpart B of this part
                                          for a duration of four years starting one
                                          year after achievement of the applicable
                                                      BAT limitations specified in
                                                      §430.24(b)(4)(i) or NSPS specified in
                                                      §430.25(c)(2):
CAS
number
59473040
Pollutant
AOX 	
Non-ECF
any tier"
Daily 	
Advanced ECF—
tier I"
Monthly 	
Advanced ECF—
tier II b t
Quarterly 	
Advanced ECF—
tier Ilio
Annually 	
TCP—
any tierc
None specified.
   Non-ECF: Pertains to any fiber line that does not use' exclusively ECF or TCP bleaching processes.
  *• Advanced ECF: Pertains to any fiber line that uses exclusively Advanced ECF bleaching processes or exclusively ECF and TCP bleaching
processes, as disclosed by the discharger in its permit application under 40 CFR 122.21 (g)(3) and  certified under 40 CFR 122.22. Advance^
     consists of the use of extended  delignification or  other technologies	     	  ~~
ECF
§430.24(b)(4)(i).
                                     that achieve  at least the Tier I  performance levels specified in

    uses exclusively TCP bleaching processes, as disclosed by the discharger in its permit application under
under 40 CFR 122.22.

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             Federal Register/Vol. 63, No. 72/Wednesday, April  15,  1998/Rules and Regulations
                                                                     18641
§430.03  Best management practices
(BMPs) for spent pulping liquor, soap, and
turpentine management, spill prevention,
and control.
  (a) Applicability. This section applies
to direct and indirect discharging pulp,.
paper, and paperboard mills with pulp
production in subparts B (Bleached
Papergrade Kraft and Soda) and E
(Papergrade Sulfite).
  (b) Specialized definitions. (1) Action
Level: A daily pollutant loading that
when exceeded triggers investigative or
corrective action. Mills determine action
levels by a statistical analysis of six
months of daily measurements collected
at the mill. For example, the lower
action level  may be the 75th percentile
of the running seven-day averages (that
value exceeded by 25 percent of the
running seven-day averages) and the
upper action level may be the 90th
percentile of the running seven-day
averages (that value exceeded by 10
percent of the running seven-day
averages).
.  (2) Equipment Items in Spent Pulping
Liquor,  Soap, and Turpentine Service:
Any process vessel, storage tank,
pumping system, evaporator, heat
exchanger, recovery furnace or boiler,
pipeline, valve, fitting, or other device
that contains, processes, transports, or
comes into contact with spent pulping
liquor, soap, or turpentine. Sometimes
referred to as "equipment items."
  (3) Immediate Process Area: The
location at the mill where pulping,
screening, knotting, pulp washing,
pulping liquor concentration, pulping
liquor processing, and chemical
recovery facilities are located, generally
the battery limits of the aforementioned
processes. "Immediate process area"
includes spent pulping liquor storage
and spill control tanks located at the
mill, whether or not they are located in
the immediate process area.
  (4) Intentional Diversion: The planned
removal of spent pulping liquor, soap,
or turpentine from equipment items in
spent pulping liquor, soap, or
turpentine service by the mill for any
purpose including, but not limited to,
maintenance, grade changes, or process
shutdowns.
  (5) Mill: The owner or operator of'a
direct or indirect discharging pulp,
paper, or paperboard manufacturing
facility subject to this section.
  (6) Senior Technical Manager: The  .
person designated by the mill manager
to review the BMP Plan. The senior
technical manager shall be the chief
engineer at the mill, the manager of  '
pulping and chemical recovery
operations, or other such responsible
person designated by the mill manager .
who has knowledge of and
responsibility for pulping and chemical
recovery operations.
  (7) Soap: The product of reaction
between the alkali in kraft pulping
liquor and fatty acid portions of the
wood, which precipitate out when water
is evaporated from the spent pulping
liquor.
  (8) Spent Pulping Liquor: For kraft
and soda mills "spent pulping liquor"
means black liquor that is used,
generated, stored, or processed at any
point in the pulping and chemical
recovery processes. For sulfite mills
"spent pulping liquor" means any
intermediate, final, or used chemical
solution that is used, generated, stored,
or processed at any point in the sulfite
pulping and chemical recovery
processes (e.g., ammonium-, calcium-,
magnesium-, or sodium-based sulfite
liquors).
  (9) Turpentine: A mixture of terpenes,
principally pinene, obtained by the
steam distillation of pine gum recovered
from the condensation of digester relief
gases from the cooking of softwoods by
the kraft pulping process.  Sometimes
referred to as sulfate turpentine.
  (c) Requirement to implement Best
Management Practices. Each mill
subject to this section must implement
the Best Management Practices (BMPs)
specified in paragraphs (c) (1) through
(10) of this section. The primary
objective of the BMPs is to prevent leaks
and spills of spent pulping liquors,
soap, and turpentine. The secondary
objective is to contain, collect, and
recover at the immediate process area,
or otherwise control, those leaks, spills,
and intentional diversions of spent
pulping liquor, soap, and turpentine
that do occur. BMPs must be developed
according to best engineering practices
and must be implemented in a manner
that takes into account the specific
circumstances at each mill. The BMPs
are-as follows:
  (1) The mill must return spilled or
diverted spent pulping liquors, soap,
and turpentine to the process to the
maximum extent practicable as
determined by the mill, recover such
materials outside the process, or
discharge spilled or diverted material at
a rate that does not disrupt the receiving
wastewater treatment system.
  (2) The mill must establish a program
to identify and repair leaking equipment
items. This program must include:
  (i) Regular visual inspections (e.g.,
once per day) of process areas with
equipment items in spent pulping
liquor, soap, and turpentine service;
  (ii) Immediate repairs of leaking
equipment items, when possible.
Leaking equipment items that cannot be
repaired during normal operations must
be identified, temporary means for
mitigating the leaks must be provided,
and the leaking equipment items
repaired during the next maintenance
outage;
  (iii) Identification of conditions under
which production will be curtailed or
halted to repair leaking equipment items
or to prevent pulping liquor, soap, and
turpentine leaks and spills;  and
  (iv) A means for tracking repairs over
time to identify those equipment items
where upgrade or replacement may be
warranted based on frequency and
severity of leaks, spills, or failures.
  (3) The mill must operate continuous,
automatic monitoring systems that the
mill determines are necessary to detect
and control leaks, spills, and intentional
diversions of spent pulping liquor, soap,
and turpentine. These monitoring
systems should be integrated with the
'mill process control system and may
include, e:g., high level monitors and •
alarms on storage tanks; process area
conductivity (or pH) monitors and   r
alarms; and process area sewer, process
wastewater, and wastewater treatment
plant conductivity (or pH) monitors and
alarms.
  (4) The mill must establish a program
of initial and refresher training of
operators, maintenance personnel, and
other technical and supervisory
personnel who have responsibility for
operating; maintaining, or supervising
the operation and maintenance of
equipment items in spent pulping
liquor, soap, and turpentine service. The
refresher training must be conducted at
least annually and the training program
must be documented.
  (5) The mill must prepare a brief
report that evaluates each spill of spent
pulping liquor, soap, or turpentine that
is not contained at the immediate
process area and any intentional
diversion of spent pulping liquor, soap,
or turpentine that is not contained at the
immediate process area. The report   -
must describe the equipment items
involved, the circumstances leading to
the incident,-the effectiveness of the
corrective actions taken to contain and
recover the spill or intentional
diversion, and plans to develop changes
to equipment and operating and
maintenance practices as necessary to
prevent recurrence. Discussion of the
reports must be included as part of the'
annual refresher training.
  (6) The mill must establish a program
to review any planned modifications to
the pulping and chemical recovery
facilities and any construction activities
in the pulping and chemical recovery
areas before these activities commence.
The purpose of such review is to
prevent leaks and spills of spent

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 18642       Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules  and Regulations
 pulping liquor, soap, and turpentine
 during the planned modifications, and
 to ensure that construction and
 supervisory personnel are aware of
 possible liquor diversions and of the
 requirement to prevent leaks and spills
 of spent pulping liquors, soap, and
 turpentine during construction.
   (7) The mill must install and maintain
 secondary containment (i.e.,
 containment constructed of materials
 impervious to pulping liquors) for spent
 pulping liquor bulk storage tanks
 equivalent to the volume of the largest
 tank plus sufficient freeboard for
 precipitation. An annual tank integrity
 testing program, if coupled with other
 containment or diversion structures,
 may be substituted for secondary
 containment for spent pulping liquor
 bulk storage tanks.
   (8) The mill must install and maintain
 secondary containment for turpentine
 bulk storage tanks.
   (9) The mill must install and maintain
 curbing, diking or other means of
 isolating soap and turpentine processing
 and loading areas from the wastewater
 treatment facilities.
   (10)  The mill must conduct
 wastewater monitoring to detect leaks
 and spills, to track the effectiveness of .
 the BMPs, and to detect trends'in spent
 pulping liquor losses. Such monitoring
 must be performed in accordance with
 paragraph (i) of this section.
   (d) Requirement to develop a BMP
 Plan. (1) Each mill subject to this
 section must prepare and implement a
 BMP Plan. The BMP Plan must be based
 on a detailed engineering review as
 described in paragraphs (d)(2) and (3) of
 this section. The BMP Plan must specify
 the procedures and the practices
 required for each mill to meet the
 requirements of paragraph (c) of this
 section, the construction the mill
 determines is necessary to meet those
 requirements including a schedule for
 such construction, and the monitoring
 program (including the statistically  .
 derived action levels) that will be used
 to meet the requirements of paragraph
 (i) of this section. The BMP Plan also
 must specify the period of time that the
 mill determines the action levels
 established under paragraph (h) of this
 section may be exceeded without
 triggering the responses specified in
 paragraph (i) of this section/
   (2) Each mill subject to  this section
 must conduct a detailed engineering
 review of the pulping and chemical
 recovery operations—including but not
 limited to process equipment, storage
tanks, pipelines and pumping systems,
loading and unloading facilities, and
other appurtenant pulping and chemical
recovery equipment items in spent
 pulping liquor, soap, and turpentine
 service—for the purpose of determining
 the magnitude and routing of potential
 leaks, spills, and intentional diversions
 of spent pulping liquors, soap, and
 turpentine during the following periods
 of operation:
   (i) Process start-ups and shut downs;
   (ii) Maintenance;
   (iii) Production grade changes;
   (iv) Storm or other weather events;
   (v) Power failures; and
   (vi) Normal operations.
   (3) As part of the engineering review,
 the mill must determine whether
 existing spent pulping liquor
 containment facilities are of adequate
 capacity for collection and storage of
 anticipated intentional liquor diversions
 with sufficient contingency for
 collection and containment of spills.
 The engineering review must also
 consider:
   (i) The need for continuous, automatic
 monitoring systems to detect and
 control leaks and spills of spent pulping
 liquor, soap, and turpentine;
   (ii) The need for process wastewater
 diversion facilities to protect end-of-
 pipe wastewater treatment facilities
 from adverse effects of spills and
 diversions of spent pulping liquors,
 soap, and turpentine;
   (iii) The potential for contamination
 of storm water from the immediate   .
 process areas; and
   (iv) The extent to which segregation
 and/or collection and treatment of
 contaminated storm water from the
 immediate process areas is appropriate.
   (e) Amendment of BMP Plan.  (1) Each
 mill subject to this section must amend
 its BMP Plan whenever there is a change
 in mill design, construction, operation,
 or maintenance that materially affects
 the potential for leaks or spills of spent
 pulping liquor, turpentine, or soap from
 the immediate process areas.
   (2) Each mill subject to this section
 must complete a review and evaluation
 of the BMP Plan five years after  the first
 BMP Plan is prepared and, except as
 provided in paragraph (e)(l) of this
 section, once every five years thereafter.
 As a result of this review and
 evaluation, the mill must amend the
 BMP Plan within three months of the
 review if the mill determines that any
 new or modified management practices
 and engineered controls are necessary to
 reduce significantly the likelihood of
 spent pulping liquor, soap, and
 turpentine leaks, spills, or intentional
 diversions from the immediate process
 areas, including a schedule for
implementation of such practices and
controls.
  (f) Review and certification of BMP
Plan. The BMP Plan, and any
 amendments thereto, must be reviewed
 by the senior technical manager at the
 mill and approved and signed by the
 mill manager. Any person signing the
 BMP Plan or its amendments must
 certify to the permitting or pretreatment
 control authority under penalty of law
 that the BMP Plan (or its amendments)
 has been prepared in accordance with
 good engineering practices and in
 accordance with this regulation. The
 mill is not required to obtain approval
 from the permitting or pretreatment
 control authority of the BMP Plan or any
 amendments thereto.
    (g) Record keeping requirements. (1)
 Each mill subject to this section must
 maintain on its premises a complete
 copy of the current BMP Plan and the
 records specified in paragraph (g)(2) of
 this section and must make such BMP
 Plan and records available to the
 permitting or pretreatment control
 authority and the Regional
 Administrator or his or her designee for
 review upon request.
    (2) The mill must maintain the
 following records for three years from
 the date they are created:
1    (i) Records tracking the repairs
 performed in accordance with the repair
 program described in paragraph (c)(2) of
 this section;
    (ii) Records of initial and refresher
 training conducted in accordance with
 paragraph (c) (4) of this section;
    (iii) Reports prepared in accordance
 with paragraph (c)(5) of this section; and
    (iv) Records of monitoring required by
 paragraphs (c)(10) and (i) of this section.
    (h) Establishment of wastewater
 treatment system influent action levels.
 (1) Each mill subject to this section must
 conduct a monitoring program,
 described in paragraph (h)(2) of this
 section, for the purpose of defining
 wastewater treatment system influent
 characteristics (or action levels),
 described in paragraph (h)(3) of this
 section, that will trigger requirements to
 initiate investigations on BMP
 effectiveness and to take corrective
 action.
   (2) Each mill subject to this section
 must employ the following procedures
 in order to develop the action levels
 required by paragraph (h) of this
 section:
   (i) Monitoring parameters. The mill
 must collect 24-hour composite samples
 and analyze the samples for a measure
 of organic content (e.g., Chemical
 Oxygen Demand (COD) or Total Organic
 Carbon (TOC)). Alternatively, the mill
 may use a measure related to spent
 pulping liquor losses measured
 continuously and averaged over 24
 hours (e.g., specific conductivity or
 color).

-------
              Federal Register/Vol. 63, No.  72/Wednesday. April 15. 1998/Rules and Regulations      18643
    (ii) Monitoring locations. For direct
  dischargers, monitoring must be
  conducted at the point influent enters
  the wastewater treatment system. For
  indirect dischargers monitoring must be
  conducted at the point of discharge to
  the RQTW. For the purposes of this
  requirement, the mill may select
  alternate monitoring point(s) in order to
  isolate possible sources of spent pulping
  liquor, soap, or turpentine from other
  possible sources of organic wastewaters
  that are tributary to the wastewater
  treatment facilities (e.g., bleach plants,
  paper machines and secondary fiber
  operations).
    (3) By the date prescribed in
  paragraph (j)(l)(iii) of this section, each
  existing discharger subject to this
  section must complete an initial six-
  month monitoring program using the
  procedures specified in paragraph (h)(2)
  of this section and must establish initial
  action levels based on the results of that
  program. A wastewater treatment
  influent action level is a statistically
  determined pollutant loading
  determined by a statistical analysis of
 six months of daily measurements. The
 action levels must consist of a lower
 action level, which if exceeded will
 trigger the investigation requirements
 described in paragraph (i) of this
 section, and an upper action level,
 which if exceeded will trigger the
 corrective action requirements
 described in paragraph (i) of this
 section.
   (4) By the date prescribed in
 paragraph (j)(l)(vi) of this section, each
 existing discharger must complete a
 second six-month monitoring program
 using the procedures specified in
 paragraph (h)(2) of this section and must
 establish revised action levels based on
' the results of that program. The initial
 action levels shall remain in effect until
 replaced by revised action levels.
   (5) By the date prescribed in
 paragraph (j)(2) of this section, each new
 source subject to this section must
 complete a six-month monitoring
 program using the procedures specified
 in paragraph (h) (2) of this section and
 must develop a lower action level and
 an upper action level based on the
 results of that program.
   (6) Action levels developed under this
 paragraph must be revised using six
 months of monitoring data after any
 change in mill design, construction,
 operation, or maintenance that
 materially affects the  potential for leaks
 or spills of spent pulping liquor, soap,
 or turpentine from the immediate
 process areas.
   ,(i) Monitoring, corrective*action, and  .
 reporting requirements. (1) Each mill
 subject to this section must conduct
 daily monitoring of the influent to the
 wastewater treatment system in
 accordance with; the procedures
 described in paragraph (h)(2) of this
 section for the purpose of detecting
 leaks and spills, tracking the
 effectiveness of the BMPs, and detecting
 trends in spent pulping liquor losses.
   (2) Whenever monitoring results
 exceed the lower action level for the
 period of time specified in the BMP
 Plan, the mill must conduct an
 investigation to determine the cause of
 such exceedance. Whenever monitoring
 results exceed the upper action level for
 the period of time specified in the BMP
 Plan, the mill must complete corrective
 action to bring the wastewater treatment
 system influent mass loading below the
 lower action level as soon as
 practicable.
  . (3) Although exceedances of the
 action levels will not constitute
 violations of an NPDES permit or
 pretreatment standard, failure to take
 the actions required by paragraph (i) (2)
 of this section as soon as practicable
 will be a permit or pretreatment
 standard violation.
   (4) Each mill subject to this section
 must report to the NPDES permitting or
 pretreatment control authority the
 results of the daily monitoring
 conducted pursuant to paragraph  (i) (1)
 of this section. Such reports must
 include a summary of the monitoring
 results, the number and dates of
 exceedances of the applicable action
, levels, and brief descriptions of any
 corrective actions taken to respond to
 such exceedances. Submission of such
 reports shall be at the frequency
 established by the NPDES permitting or
 pretreatment control authority, but in no
 case less than once per year.
   Q) Compliance deadlines. (1) Existing
 direct and indirect dischargers. Except
 as provided in paragraph (j) (2) of this
 section for new sources, indirect
 discharging mills subject to this section
 must meet the deadlines set forth below.
 Except as provided in paragraph (j)(2) of
 this Section for new sources, NPDES
 permits must require direct discharging
 mills subject to this section to meet the
 deadlines set forth below. If a deadline
 set forth below has passed at the time
 the NPDES permit containing the BMP
 requirement is issued, the NPDES
 permit must require immediate
 cpmpliance with such BMP
 requirement (s).
   (i) Prepare BMP Plans and certify to
 the permitting or pretreatment authority
 that the BMP Plan has been prepared in
 accordance with this regulation not later
 than April 15, 1999;
   (ii) Implement all BMPs specified in
 paragraph (c) of this section that do not
 require the construction of containment
 or diversion structures or the
 installation of monitoring and alarm
 systems not later than April 15, 1999.
   (iii) Establish initial action levels
 required by paragraph (h) (3) of this
 section not later than April 15,1999.
   (iv) Commence operation of any new
 or-upgraded continuous, automatic
 monitoring systems that the mill
.determines to be necessary under
 paragraph (c)(3) of this section (other
 than those associated with construction
 of containment or diversion structures)
 not later than April 17, 2000.
   (v) Complete construction'and
 commence operation of any spent
 pulping liquor, collection, containment,
 diversion, or other facilities, including
 any associated continuous monitoring
 systems, necessary to fully implement
 BMPs specified in paragraph (c) of this
 section not later than April 16, 2001.
   (vi) Establish revised action levels
 required by paragraph (h)(4) of this
 section as soon as possible after fully
 implementing the BMPs specified in
 paragraph (c) of this section, but not
later than January 15, 2002.
   (2) New Sources. Upon commencing
dispharge, new sources subject to this   -
section must implement all of the BMPs
specified in paragraph (c) of this
section, prepare the BMP Plan required
by paragraph (d) of this section, and
certify to the permitting or pretreatment
authority that the BMP Plan has been
prepared in accordance with this
regulation as required by paragraph (f)
of this section, except that the action
levels required by paragraph (h) (5)  of
this section must be established not
later than 12 months after
commencement of discharge, based on
six months of monitoring data obtained
prior to that date in accordance with the
procedures specified in paragraph (h) (2)
of this section.

Subpart A—Dissolving Kraft
Subcategory

§ 430.10 Applicability; description of the
dissolving kraft subcategory.

  The provisions of this subpart apply
to discharges resulting from the
production of dissolving pulp at kraft
mills.

§430.11 Specialized definitions.

  For the purpose of this subpart, the
general definitions, abbreviations, and
methods of analysis set forth in 40 CFR
part 401 and § 430.01 of this part shall
apply to this subpart.

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18644      Federal Register/Vol.  63,  No. 72/Wednesday, April  15,  1998/Rules and Regulations
§430.12  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best practicable
control technology currently available
(BPT).
  (a) Except as provided in 40 CFR
125.30 through 125.32, any existing
point source subject to this subpart must
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best practicable
control technology currently available

             SUBPARTA
         [BPT effluent limitations]
                                                                              (BPT), except that non-continuous
                                                                              dischargers shall not be subject to the
                                                                              maximum day and average of 30
                                                                              consecutive days limitations but shall
                                                                              be subject to annual average effluent
                                                                              limitations:
Pollutant or pollutant property
BODS
TSS
pH 	



Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
23.6
37.3
(1)
Average of
daily values
for 30 con-
secutive ,
days
12.25
20.05
(1)
Non-contin-
uous dis-
chargers
6.88
11.02
(
  1 Within the range of 5.0 to 9.0 at all times.


  Oi) The following limitations establish
the quantity or quality of pollutants or
pollutant properties, controlled by this
section, resulting from the use of wet
barking operations, which may be
discharged by a point source subject to
                                       the provisions of this subpart. These
                                       limitations are in addition to the
                                       limitations set forth in paragraph (a) of
                                       this section and shall be calculated
                                       using the proportion of the mill's total
                                       production due to use of logs which are

                                                    SUBPART A
                                                [BPT effluent limitations]
                                       subject to such operations. Non-
                                       continuous dischargers shall not be
                                       subject to the maximum day and
                                       average of 30 consecutive days
                                       limitations, but shall be subject to
                                       annual average effluent limitations:
Pollutant or pollutant property
BODS
TSS
PH 	



Kg/kkg (or pounds per 1,000 Ib) of
product ,
Continuous dischargers
Maximum
for any 1
day
3.2
6.9
(1)
Average of
daily values
for 30 con-
secutive days
1.7
3.75
(1)
Non-continu-
ous discharg-
ers (annual
average)
0.95
2.0
(
  1 Within the range of 5.0 to 9.0 at all times.
   (c) The following limitations establish
 the quantity or quality of pollutants or
 pollutant parameters, controlled by this
 section, resulting from the use of log
 washing or chip washing operations,
 which may be discharged by a point
 source subject to the provisions of this
 subpart. These limitations are in
 addition to the limitations set forth in
 paragraph (a) of this section and shall be
 calculated using the proportion of the
 mill's total production due to use of logs
                                                                              and/or chips which are subject to such
                                                                              operations. Non-continuous dischargers
                                                                              shall not be subject to the maximum day
                                                                              and average of 30 consecutive days
                                                                              limitations, but shall be subject to the
                                                                              annual average effluent limitations:

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              Federal  Register/Vol. 63. No.  72 /Wednesday. April  15.  1998/Rules  and  Regulations       18645
                                                      SUBPART A
                                                 [BPT effluent limitations]
Pollutant or pollutant property
BODS 	 	 	 	 	 	 	 	 ; 	
TSS 	 	 	 	 	 	 	 . -
PH 	 	 	 	 	 ; 	 . 	
Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
0.35
0.70
(1)
Average of
daily values
for 30 con-
secutive
days
0.2
0.4
(1)
Non-contin-
uous dis-
chargers
(annual
average)
0.1
0.2
(
  1 Within the range of 5.0 to 9.0 at all times.
   (d) The following limitations establish
the quantity or quality of pollutants or
pollutant properties, controlled by this
section, resulting from the use of log
flumes or log ponds, which may be
discharged by a point source subject'to
the provisions of this subpart. These
limitations are in addition to the
limitations set forth in paragraph (a) of
this section and shall be" calculated
using the proportion of the mill's total
production due to use of logs which are

              SUBPARTA
         [BPT effluent limitations]
subject to such operations. Non-
continuous dischargers shall not be
subject to the maximum day and
average of 30 consecutive days
limitations but shall be subject to the
annual average effluent limitations:
Pollutant or pollutant property
BOD5 	 	 	
TSS....... 	 	 	 	 	 	 	
PH 	 	 	 	 	 	 	 	 	 	 	 	
Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum for
any 1 day
0.6
1.45
(1)
Average of
daily values
for 30 con-
secutive days
0.35
0.8
(1)
Non-contin-
uous dis-
chargers
(annual
average) '
0.2
0.4
(
  1 Within the range of 5.0 to 9.0 at all times.
§430.13  Effluent limitations guidelines
representing the degree of effluent
reduction attainable by the application of
the best conventional pollutant control
technology (BCT).
  Except as provided in 40 CFR 125.30
through 125.32, any existing point
source subject to this subpart shall
achieve the following effluent
limitations representing the  degree of
effluent reduction attainable by the
application of the best conventional
pollutant control technology (BCT): The
limitations shall be the same as those
specified for conventional pollutants
(which are defined in 40 CFR 401.16) in
§ 430.12 of this subpart for the best
practicable control technology currently
available (BPT).

§ 430.14 Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best available
technology economically achievable (BAT).
  Except as provided in 40 CFR 125.30
through 125.32, any existing point
source subject to this subpart where
chlorophenolic-containing biocides are
used must achieve the following
effluent limitations representing the
degree of effluent reduction attainable
by the application of the best available
technology economically achievable
(BAT). Non-continuous dischargers .
shall, not be subject to the maximum day
mass limitations in kg/kkg (lb/1000 Ib)
but shall be subject to concentration
limitations. Concentration limitations
are only applicable to non-continuous
dischargers. Permittees not using ,
chlorophenolic-containing biocides
must certify to the permit-issuing
authority that they are not using these
biocides:

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18646
Federal Register/Vol. 63, No. 72/Wednesday,  April 15, 1998/Rules and Regulations
                                                   SUBPART A
                                               [BAT effluent limitations]
Pollutant or pollutant properly
PentachlorophBnol 	
Trtchloropheno! 	 	 	
y e wastewater discharged in kgal per ton of product.
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000 Ib) of
product
0.0025
0.016
Milligrams/liter
(0.011)(55.1)/y
(0.068)(55.1)/y
§430.15 New source performance
standards (NSPS).
  Any new source subject to this
subpart must achieve the following new
source performance standards (NSPS),
except that non-continuous dischargers
shall not be subject.to the maximum day
and average of 30 consecutive days
                          effluent limitations for BODS and TSS,
                          but shall be subject to annual average
                          effluent limitations. Also, for non-
                          continuous dischargers, concentration
                          limitations (mg/1) shall apply, where
                          provided. Concentration limitations will
                          only apply to non-continuous
                          dischargers. Only facilities where

                                       SUBPARTA
                                         [NSPS]
chlorophenolic-containing biocides are
used shall be subject to
pentachlorophenol and trichlorophenol
limitations. Permittees not using
chlorophenolic-containing biocides
must certify to the permit-issuing
authority that they are not using these
biocides:
Pollutant or pollutant property
BOD5 	
TSS 	 : 	 	 	 '..
nH ... 	 	 	


Pentachlorophenol 	 	
Trlchlorophenot 	
y » wastewater discharged in kgal per ton at all times.
Continuous dischargers
Maximum
for any 1
day
15.6
27.3
(1)
Average of
daily values
for 30 con-
secutive
days
8.4
14.3
(1)
Non-contin-
uous dis-
chargers
.(annual
average)
4.4
7.5
(
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000lb)of
product
0.0025
0.016
Milligrams/liter
(0.012)(50.7)/y
(0.074)(50.7)/y
                                                                                   Kg/kkg (or pounds per 1,000 Ib) of
                                                                                              product
  •> Within the range of 5.0 to 9.0 at all times.
§ 430.16  Pretreatment standards for
existing sources (PSES).
  Except as provided in 40 CFR 403.7
and 403.13, any existing source subject
                          to this subpart that introduces
                          pollutants into a publicly owned
                          treatment works must: comply with 40
                          CFR part 403; and achieve the following
pretreatment standards for existing
sources (PSES) if it uses chlorophenolic-
containing biocides. Permittees not
using chlorophenolic-containing
biocides must certify to the permit-
issuing authority that they are not using
these biocides. PSES must be attained
on or before July 1, 1984:

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             Federal Register/Vol. 63, No.  72/Wednesday. April  15,  1998/Rules and Regulations      18647


                                      •     .          SUBPARTA
                              '                         [PSES]

Pollutant or pollutant property ' . '
Pentachlorophenol 	 > 	 i 	 .....
Trichlorophenol 	 	 	
y = wastewater discharged in kgal per ton of product.
Maximum for any 1
Milligrams/liter (mg/I)
i • • .,
(0011)(55 1)/y
(0.082K55 1Vv

day
Kg/kkg (or
pounds per
1,000lb)of
product =
00025
0019

  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
 tions.
 §430.17  Pretreatment standards for new
 sources (PSNS).
   Except as provided in 40 CFR 403.7,
 any new source subject to this subpart
 that introduces pollutants into a
publicly owned treatment works must:
comply with 40 CFR part 403; and
achieve the following pretreatment
standards for new sources (PSNS) if it
uses chlorophenblic-containing

             SUBPARTA
                [PSNS]
biocides. Permittees not using
chlorophenolic-cbntaining biocides
must certify to the permit-issuing
authority that they are not using these
biocides;
" . •
Pollutant or pollutant property
• • ' ' . • ' ' • /
Pentachlorophenol 	 	 	 	 L. 	 	 	
Trichlorophenol 	 	 	 	 	
y = wastewater discharged in kgal per ton of product.
Maximum for any 1
, Milligrams/liter (mg/I)
(0.012)(50.7)/v 	 	
(0 089K50 7W

day
Kg/kkg (or,
pounds per
1,000 Ib) of
product3 •
0.0025
0 019

  aThe following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.                           .••'•.'.
 Subpart B—Bleached Papergrade Kraft
 and Soda Subcategory

 § 430.20  Applicability; description of the
 bleached papergrade kraft and soda
 subcategory.
  The provisions of this subpart apply
 to discharges resulting from: the
 production of market pulp at bleached
 kraft mills; the integrated production of
 paperboard, coarse paper, and tissue
 paper at bleached kraft mills; the
 integrated production of pulp and fine
 papers at bleached kraft mills; and the
 integrated production of pulp and paper
 at soda mills.

 § 430.21  Specialized definitions.
   (a) The general definitions,
. abbreviations, and methods iof analysis
 set forth in 40 CFR part 401 and
 § 430.01 of this part apply to this
 subpart.
   (b) Baseline BAT limitations orNSPS
 means the BAT limitations specified in
 §430.24(a) (1) or (2), as  applicable, and
 the NSPS specified in § 430.25(b) (1) or
 (2), as applicable, that apply to any
 direct discharger that is not "enrolled" •
in the "Voluntary Advanced
Technology Incentives Program."
  (c) Enroll means to notify the
permitting authority that a mill intends
to participate in the "Voluntary
Advanced Technology Incentives
Program." A mill can enroll by
indicating its intention to participate in
the program either as part of its
application for a National Pollutant
Discharge Elimination System (NPDES)
permit, or through separate  '
correspondence to the permitting
authority as long as the mill signs the
correspondence in accordance with 40
CFR 122.22.
  (d) Existing effluent quality means the
level at which the pollutants identified
in § 430.24(a) (1) are present in the
effluent of a mill "enrolled" in the
"Voluntary Advanced Technology
Incentives Program."
  (e) Kappa number is a measure of the
lignin content in unbleached pulp,
determined after pulping and prior to
bleaching.
  (f) Voluntary Advanced Technology
Incentives Program is the program
established under § 430.24(b) (for
existing direct dischargers) and
§ 430.25(c) (for new direct dischargers)
whereby participating mills agree to
accept enforceable effluent limitations-
and conditions in their NPDES permits
that are more stringent than the
"baseline BAT limitations or NSPS"
that would otherwise apply, in
exchange for regulatory- and
enforcement-related rewards and
incentives.

§430.22 Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best practicable
control technology currently available
(BPT).

  (a) Except as provided in 40 CFR
125.30 through 125.32, any existing
point source subject to this subpart must
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best practicable
control technology currently available
(BPT):

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18648      Federal Register/Vol. 63, No. 72/Wednesday,  April  15, 1998/Rules  and Regulations
                                                      ,  SUBPART B
                          [BPT effluent limitations for bleached kraft facilities where market pulp is 'produced]
Pollutant or pollutant parameter
BODS 	
TSS 	
pH 	


•
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers .
Maximum for
any 1 day
15.45
30.4
(i)
Average of
daily values
for 30 con-
secutive days
8.05
16.4
W
Non-contin-
uous dis-
chargers
(annual
average)
4.52
9.01
f
 1 Within the range of 5.0 to 9.0 at all times.

                                                        SUBPART B
            [BPT effluent limitations for bleached kraft facilities where paperboard, coarse paper, and tissue paper are produced]
Pollutant or pollutant parameter
BODS 	
TSS 	
DH 	



Continuous dischargers
Maximum for
any 1 day
13.65
24.0
m ..
Average of
daily values
for 30 con-
secutive
days
7.1
12.9
M
Non-contin-
.uous dis-
chargers
(annual
average)
3.99
7.09
r
                                                                                          Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                     product
 1 Within the range of 5.0 to 9.0 at all times.
                                                        SUBPART B
                      [BPT effluent limitations for bleached kraft facilities where pulp and fine papers are produced]
Pollutant or pollutant parameter
BODS 	
TSS 	
pH 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
10.6
22.15
(1)
Average of
daily values
for 30 con-
secutive
days
5.5
11.9
(1)
Non-contin-
uous dis-
chargers
(annual
average)
' 3.09
6.54
(
 1 Within the range of 5.0 to 9.0 at all times.
                                                       SUBPART B
                            [BPT effluent limitations for soda facilities where pulp and paper are produced]
Pollutant or pollutant parameter
BODS 	
TSS 	 	 	 	 	
pH 	 	 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers .
Maximum
for any 1
day
13.7
24.5
(1)
Average of
daily values
for 30 con-
secutive
days
7.1.
13.2
C1)
Non-contin-
* uous dis-
chargers
(annual
average)
3.99
7.25
(
 1 Within the range of 5.0 to 9.0 at all times.

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             Federal Register/Vol. 63,  No.  72/Wednesday, April 15,  1998/Rules and Regulations       18649
    (b) The following limitations'establish the quantity  or quality of pollutants'or pollutant  properties, controlled by
this section,  resulting from the use of wet barking  operations, which  may be discharged by  a point .source subject
to the provisions of this subpart. These limitations  are in addition to the limitations  set forth  in paragraph (a)  of
this section and shall be  calculated using  the  proportion  of the mill's total production due to  use of logs  which
are subject to such operations:                                       ,  -                                       ,


                                               .  ,  ,    SUBPART B

                          [BPT effluent limitations for bleached  kraft facilities where market pulp is produced]
Pollutant or pollutant parameter
BODS 	 	 	 	 	 	 	 : 	 	 ..
TSS 	 	 	 	 	 	 	 	 	 „. 	 	 ..'.
DH 	 	 	 i 	
Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
2.3
5.3
m
Average of
daily values
for 30 con-
secutive days
1.2
2.85
m
Non-contin-
uous dis-
chargers
, (annual
average)
0.70
1.55
<
  1 Withih the range of 5.0 to 9.0 at all times.

                                .                       SUBPART B
            [BPT effluent limitations for bleached kraft facilities where paperboard, coarse paper, and tissue paper are produced]
V
• Pollutant or pollutant parameter
BODS 	
TSS 	
pH 	 	 	



Continuous dischargers


Maximum
for any 1
day

225
575
P)
Average of
daily values
for 30 con-
secutive
days
1 2
3 1
m

Non-contin-
uous dis-
chargers
(annual
average)

0 65
1 70
(
                                                                                        Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                   product
  11 Within the range of 5.0 to 9.0 at all times.
                                                       SUBPART B       .
                      [BPT effluent limitations for bleached kraft facilities where pulp and fine papers are produced]
Pollutant or pollutant parameter
, . * • .
BODS 	 	 	 	 	
TSS 	 	
PH 	 	 	



Continuous dischargers
Maximum for
any 1 day
1.95
5.3
m
Average' of
daily values
for 30 con-
secutive days
1.0
2.85
M
Non-contin-
uous dis-
chargers
(annual
average)
0.55
1.55
(
                                                                                       Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                  product
  1 Within the range of 5.0 to 9.0 at all times.
                                                       SUBPART B
                           [BPT effluent limitations for soda facilities where pulp and papers are produced]
Pollutant or pollutant parameter
BODS 	 	 	 ;.. .
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum for
any 1 day •
2.05
Average of
daily values
for 30 con-
secutive days
1.1
Non-contin-
uous dis-
chargers
(annual
average)
O.fiD

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18650       Federal Register/Vol. 63,  No. 72/Wednesday,  April  15,  1998/Rules and Regulations

                                                SUBPART B—Continued
                            [BPT effluent limitations for soda facilities where pulp and papers are produced]
Pollutant or pollutant parameter
TSS 	
PH 	


Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum for
any 1 day
5.25
P)
Average of
daily values
for 30 con-
secutive days
2.8
(')
Non-contin-
uous dis-
chargers
(annual
average)
1.55
(
  1 Within the range of 5.0 to 9.0 at all times.
  (c) The following limitations establish   which may be discharged by a point
the quantity or quality of pollutants or    source subject to the provisions of this
pollutant parameters, controlled by this   subpart. These limitations are in
section, resulting from the use of log      addition to the limitations set forth in
washing or chip washing operations,      paragraph (a) of this section and shall be
calculated using the proportion of the
mill's total production due to use of logs
and/or chips which are subject to such
operations:
                                                      SUBPART B
                          [BPT effluent limitations for bleached kraft facilities where market pulp is produced]
Pollutant or pollutant parameter
BODS 	
TSS 	
pH 	



Continuous dischargers
Maximum for
any 1 day
0.2
0.6
0)
Average of
daily values
for 30 con-
secutive days
0.1
0.3
.(')
Non-contin-
uous dis-
chargers
(annual
average)
0.1
0.15
(
                                                                                      Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                 product
  1 Within the range of 5.0 to 9.0 at all times..

                                                      SUBPART B
            [BPT effluent limitations for bleached kraft facilities where paperboard, coarse paper, and tissue paper are produced]
Pollutant or pollutant parameter
BODS 	
TSS 	
PH 	



. Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum for
any 1 day
0.25
0.65
(>)
Average of
daily values
for 30 con-
secutive days
0.15
0.35
0)
Non-contin-
uous dis-
chargers
(annual
average)
0.05
0.20
(
  1 Within the range of 5.0 to 9.0 at all times.
                                                      Subpart B
                      [BPT effluent limitations for bleached kraft facilities where pulp and fine papers are produced]
Pollutant or pollutant parameter
BODS 	
TSS 	


Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum for
. any 1 day
0.2
0.55
Average of
daily valu.es
for 30 con-
secutive days
0.1
0.3
Non-contin-
uous dis-
chargers
(annual
average)
0.05
0.15

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              Federal Register/Vol. 63, No. 72 /Wednesday, April 15, 1998/Rules  and Regulations       18651
                                                  Subpart B—Continued
                       [BPT effluent limitations for bleached kraft facilities where pulp and fine papers are produced]
'.'••:'. . .Pollutant or pollutant parameter
pH 	 : 	 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of -
product
Continuous dischargers
Maximum for
any 1 day
0)
Average of
daily values
for 30 con-
secutive days
«
Non-contin-
uous dis-
chargers
(annual
average)
(
   1 Within the range of 5.0 to 9.0 at all times.
                                                       SUBPART B
                            [BPT effluent limitations for soda facilities where pulp and papers are produced]
Pollutant or pollutant parameter
BODS 	
TSS 	 	 	 	 	
pH 	 	 	 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum for
any 1 day
' 0.15
0.5
(')
Average of
daily values
for 30 con-
secutive days
0.1
0.25
'(»)
Non-contin-
uous dis-
chargers
(annual
average)
0.05
; 0.15
(
   1 Within the range of 5.0 to 9.0 at all times.
   (d) The following limitations establish   discharged by a point source subject to    using the proportion of the mill's total
 the quantity or quality of pollutants or
.pollutant properties, controlled by this
 section, resulting from the use of log
 flumes or log ponds, which may be
the provisions of this subpart. These
limitations are in addition to the
limitations set forth in paragraph (a) of
this section and shall be calculated
production due to use of logs which are
subject to such operations:
                                                       SUBPART B
                           [BPT effluent limitations for bleached kraft facilities where market pulp is produced]
Pollutant or pollutant parameter
BODS 	
TSS 	 	 : 	 ;..
PH 	 	 	 1 	 	 	 ....;..; 	 	
Kg/kkg (or pounds per 1,000 Ib) of .
product
Continuous dischargers
Maximum for
any 1 day
0.4
1.15
0)
Average of
daily values
for 30 con-
secutive days
0.2
0.6
0)
Non-contin-
uous dis-
chargers
(annual
average)
0.15
0.35
(
  1 Within the range of 5.0 to 9.0 at all times.

                                                       SUBPART B
            [BPT effluent limitations for bleached kraft facilities where paperboard, coarse paper, and tissue paper are produced]
Pollutant or pollutant parameter
BODS 	 	 	
TSS 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum for
any 1 day
0.45
1.25
Average of
daily values
for 30 con-
secutive days
0.25
O7
Non-contin-
uous dis-
chargers
(annual
average)
0.10
nsR

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18652
Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules and Regulations
                                               SUBPART B—Continued
           [BPT effluent limitations for bleached kraft facilities where paperboard, coarse paper, and tissue paper are produced]
Pollutant or pollutant parameter
PH 	 	 	 - 	 	 - 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum for
any 1 ,day
W
Average of
daily values
for 30 con-
secutive days
, «
Non-contin-
uous dis-
chargers
(annual
average)
(
  1 Within the range of 5.0 to 9.0 at all times.
                                                     SUBPART B
                     [BPT effluent limitations for bleached kraft facilities where pulp and fine papers are produced]
Pollutant or pollutant parameter
BODS 	
TSS 	
PH 	



Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
. for any 1
day
0.35
1.15
(1)
Average of
daily values
for 30 con-
secutive
days
0.2
0.6
(1)
Non-contin-
uous dis-
chargers
(annual
average)
0.10
0.30
(
  •> Within the range of 5.0 to 9.0 at all times.
                                                     SUBPART B
                           [BPT effluent limitations for soda facilities where pulp and papers are produced]
Pollutant or pollutant parameter
BOD5 	
TSS 	
DH 	



Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
0.3
1.1
(1)
Average of
daily values
for 30 con-
secutive
days
0.2
0.55
P)
Non-contin-
uous dis-
chargers
(annual
average)
U10
0.35
(
  'Within the range of 5.0 to 9.0 at all times.
§430.23  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best conventional
pollutant control technology (BCT).
  Except as provided in 40 CFR 125.30
through 125.32, any existing point
source subject to this subpart must
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best conventional
pollutant control technology (BCT). The
limitations shall be the same as those
                           specified in § 430.22 of this subpart for
                           the best practicable control technology
                           currently available (BPT).

                           §430.24 Effluent limitations representing
                           the degree of effluent reduction attainable
                           by the application of best available
                           technology economically achievable (BAT).

                           ,  Except as provided in 40 CFR 125.30
                           through 125.32, any existing point
                           source subject to this subpart must
                           achieve the following effluent
                           limitations representing the degree of
effluent reduction attainable by the
application of the best available
technology economically achievable
(BAT).
  (a) Except as provided in paragraph
(b) of this section—
  (1) The following effluent limitations
apply with respect to each fiber line that
does not use an exclusively TCP
bleaching process, as disclosed by the
discharger in its NPDES permit
application under 40 CFR 122.21(g)(3)
and certified under 40 CFR 122.22:

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              Federal Register/Vol. 63.  No. 72/Wednesday. April  15, 1998/Rules and Regulations       18653
                                                      SUBPART B
Pollutant or pollutant property


TCDD 	 	 	 	 	 . .
TCDF 	 1 	 	 	 	
Chloroform 	 	 	 	 	 	
Trichlorosyringol 	 	 	 .
3,4,5-trichlorocatechol 	 	 	 	 	 	 . . - . •
3,4,6-trichlorocatechol 	
3,4,5-trichloroguaiacol 	 	 	 .- 	 .'. 	 ....: 	
3,4,6-trichloroguaiacol 	 ; 	
4,5,6-trichloroguaiacol 	 : 	 	
2,4,5-trichlbrophenol 	 	 	
2,4,6-trichlorophenol 	 , 	
Tetrachlorocateohol 	 	 '. 	 	 	
Tetrachloroguaiacol 	 	 	 	
2,3,4,6-tetrachlorophenol 	
Pehtachlorophenol 	 	 	 	 	 -.;. 	 	 	 	 	 •

./."
AOX 	 	 	 	 	 	
COD 	 	 	 	 	
BAT effluent limitations
Maximum for
- any 1 day
,
• Continuous .dischargers
Maximum
for any 1
day (kg/kkg)
0.951
•C)
Monthly av-
erage (kg/
kkg) ,
0.623
W
Monthly
average
(")
(b)
4.14(<")
(b)
(b)
(b)
(b)
(")'
(b)
(b)
(")
(")
(b)
; (b)
(b)
Non-contin-
uous dis-
chargers.
Annual av-
erage (kg/
kkg)
0.512
(")
  a"
(<=)
(b)
(<=) '
  ••>"
-------
 18654      Federal  Register/Vol. 63, No. 72/Wednesday, April  15,  1998/Rules and Regulations
  (2) Best Professional Judgment
Milestones: Narrative or numeric
limitations and/or special permit
conditions, as appropriate, established
by the permitting authority on the basis
of his or her best professional judgment
that reflect reasonable interim
milestones toward achievement of the
effluent limitations specified in
paragraphs (b)(3) and (b)(4) of this
section, as applicable.
  (3) Six-year Milestones: By April 15,
2004 all dischargers enrolled in the
Voluntary Advanced Technology
Incentives Program must achieve the
following:
  (i) The effluent limitations specified
in paragraph (a) (1) of this section,
except that, with respect to AOX,
dischargers subject to Tier I effluent
limitations specified in paragraph
(b) (4) (i) of this section must achieve the
AOX limitation specified in that
paragraph; or
   (ii) For dischargers that use
exclusively TCP bleaching processes as
of April 15, 2004, the effluent
limitations specified in paragraph (a) (2)
of this section.
.   (4) (i) Stage 2 Limitations:
                ULTIMATE VOLUNTARY ADVANCED TECHNOLOGY INCENTIVES PROGRAM BAT LIMITATIONS
Tier
Tier 1 	
Tier II 	
Tier III 	
Kappa number (annual average)
20 (softwood furnish) 	
13 (Hardwood furnish)
NA 	
N/A 	 	 	 ....
Filtrate
recycling
(b) 	
(b) 	
(") 	
Total pulping area con-
densate, evaporator
condensate, and bleach
plant wastewater flow
(annual average)
N/A 	 : 	
10 cubic meters/kkg 	
5 cubic meters/kkq 	
AOX (kg/kkg)
Non-TCP"
Maximum
for any 1
day
• 0.58
0.23
0.11
Annual
average
0.26
0.10
0.5
TCP
Maximum
for any 1
day

-------
             Federal Register/Vol. 63, No. 72/Wednesday, April  15, ' 1998 /Rules and Regulations
                                                                       18655
                                                     SUBPART B
  [Supplemental BAT effluent limitations for bleached kraft facilities where pulp and fine papers are produced and soda facilities where pulp and
                                               .  • paper are produced]                       •
Pollutant or pollutant property
Pentachlorophenol 	
Trichlorophenol 	 	
y = wastewater discharged in


kgal per ton of product.
Maximum for any 1 day
kg/kkg (or
pounds per
1,000 ID) of
product
0.0014
0.0088
Milligrams/liter
(0.011) (30.9)/y
(0.068) (30.9)/y
  (e) Pursuant to 40 CFR 122.44 (i) and
122.45(h), a discharger must
demonstrate compliance with the
effluent limitations in paragraph (a) (1)
or (b) (3) of this section, as applicable, by
monitoring for all pollutants (except for
AOX and COD) at the point where the
wastewater containing those pollutants
leaves the bleach plant. The permitting
authority may impose effluent
limitations and/or monitoring
requirements on internal wastestreams
for any other pollutants covered in this
section as appropriate under 40 CFR
122.44(i) and 122.45(h). In addition, a
discharger subject to a limitation on
total pulping area condensate,
evaporator condensate, and bleach plant
wastewater flow under paragraph
(b) (4) (i) of this section,  for Tier II and
Tier III, must demonstrate compliance
with that limitation by  establishing and
maintaining flow measurement
equipment to monitor these flows at the
point or points where they leave the
pulping area, evaporator area, and
bleach plant.
§ 430.25  New source performance
standards (NSPS).
  New sources subject to this subpart
must achieve the following new source
performance standards (NSPS), as
applicable.
  (a) The following standards apply to
each new source that commenced
discharge after June 15, 1988 and before
June 15.  1998..provided that the new
source was constructed to meet these
standards:
                                                     SUBPART B                     .      ,
                 [1982 New Source Performance Standards for bleached kraft facilities where market pulp is produced]
i
vt Pollutant or pollutant property

BODS ,
TSS 	 	 	 :..-: 	 ...
DH 	 	 : 	 	 	 	 	 ..: 	 	 	 	
Continuous dischargers
Maximum
for any 1
day
Average of
daily values
for 30 con-
secutive
.da^s
Non-contin-
uous dis-
chargers
Annual
average
kg/kkg (or pbunds per 1 ,000 Ib) of
product
10.3
18.2
m
. - : 5.5
9.5
m
2.88
5.00
m
  1 Within the range of 5.0 to 9.0 at all times.                      •             .

                                                     SUBPART B                                    .
    [1982 New Source Performance Standards for bleached kraft facilities where paperboard, coarse paper, and tissue paper are produced]
Pollutant or .pollutant property

BODS 	 	 	 	 '. 	 .' 	 ''. 	
TSS 	 	 	 	 	 	 	 : 	 -. 	
PH : 	 •. 	
Continuous dischargers
Maximum
for any 1
day
Average of
daily values
for 30 con-
secutive
days
Non-contin-,
uous dis-
chargers
Annual
average
• /
kg/kkg (or pounds per 1 ,000 Ib) of
product
8.5
14.6
m
4.6
7.6
m
2.41
4.00
rn
  1 Within the range of 5.0 to 9.0 at all times.

-------
 18656       Federal Register/Vol.  63. No. 72/Wednesday. April  15, 1998/Rules and  Regulations
                                                       SUBPART B
  [1982 New Source Performance Standards for bleached kraft facilities where pulp and fine papers are produced and soda facilities where pulp
                                                   ahd paper are produced]  ,
Pollutant or pollutant property

BODS 	 '. 	 	 	 : 	
TSS 	 , ...
OH 	 : 	 : 	 	 	
Continuous dischargers
Maximum
for any 1
day
Average of
daily values
for 30 con-
secutive
days
Non-contin-
uous dis-
chargers
Annual
average
• kg/kkg (or pounds per 1 ,000 Ib) of
product
5.7
9.1
m
i
3.1
4.8
• •' m
1.62
2.53
(f\
  1 Within the range of 5.0 to 9.0 at all times.


  (b) Except as provided in paragraph
(c) of this section—
  (1) The following standards apply
with respect to each new source fiber
line that does not use an exclusively
TCP bleaching process, as disclosed by
the discharger in its NPDES permit
application under 40 CFR 122.21 (g) (3)

              SUBPART B
and certified under 40 CFR 122.22, and
that commences discharge after June 15,
1998:
                                  Pollutant or pollutant property
                                                                                                         NSPS
                                                                                                Maximum for
                                                                                                  any 1 day
                                                                       Monthly
                                                                       average
TCDD 	
TCDF	
Chloroform	,
Trlchlorosyringol 	
3,4,5-trfchlorocatechol	
3,4,6-trichlorocatechol	
3,4,5-trfchloroguaiacol	
3,4,6-trichloroguaiacol	
4,5,6-trichloroguaiacol	
2,4,5-trichlorophenol	
2.4,6-trichlorophenol	
Tetrachlorocatechol	
Tetrachloroguaiacol	
2,3,4,6-tetrachlorophenol
Pentachtorophenol  	
                                                      
-------
              Federal Register/Vol.  63, No.  72/Wednesday; April 15, 1998/Rules  and  Regulations      18657
                                                       SUBPART B
.. • •• Pollutant or pollutant property
AOXd .
1
BODS'1 	 , 	 	
TSS" 	 	 	
pH 	
COD 	 :...





NSPS (TCP)
Continuous dischargers
Maximum for
. any 1 day

-------
18658
Federal Register/Vol. 63, No.  72/Wednesday, April 15,  1998/Rules  and  Regulations
                                               SUBPART B—Continued
             [Supplemental NSPS for bleached kraft facilities where paperboard, coarse paper, and tissue paper are produced]

Trichlofophenol 	
y K vvastewater discharged
Pollutant or pollutant property

in kgal per ton of product.
kg/kkg (or
pounds per
1 ,000 Ib) of
product
0.010

Milligrams/liter
(0.076)(31 .7)/y

                                                                                           Maximum for any 1 day
                                                     SUBPART B
    [Supplemental NSPS for bleached kraft facilities where pulp and fine papers are produced and soda facilities where pulp and paper are
                                                      produced]

Pontachlorophenol 	
Trichlorophenol 	
y « wastewater discharged in
Pollutant or pollutant property


kgal per ton of product.
kg/kkg (or
pounds per
1,000lb)of
product
0.0014
0.0088

Milligrams/liter
(0.014)(25.1)/y
(0.084)(25.1)/y

                                                                                            Maximum for any 1 day
  (e) Pursuant to 40 CFR 122.44(i) and
122.45(h), a discharger must
demonstrate compliance with the
limitations in paragraph (b)(l) or (c)(l)
of this section, as applicable, by
monitoring for all pollutants (except for
AOX. COD. BODS, TSS, and pH) at the
point where the wastewater containing
those pollutants leaves the bleach plant.
The permitting authority may impose
effluent limitations and/or monitoring
requirements on internal wastestreams
for any other pollutants covered in this
section as appropriate under 40 CFR
122.44(1) and 122.45(h). In addition, a
discharger subject to a limitation on
                          total pulping area condensate,
                          evaporator condensate, and bleach plant
                          wastewater flow under paragraph (c) (2)
                          of this section must demonstrate
                          compliance with that limitation by
                          establishing and maintaining flow
                          measurement equipment monitoring
                          these flows at the point or points where
                          they leave the pulping area, evaporator
                          area, and the bleach plant.

                          §430.26  Pretreatment standards for
                          existing sources (PSES).

                            Except as provided in 40 CFR 403.7
                          and 403.13, any existing source subject
                          to this subpart that introduces

                                       SUBPART B
pollutants into a publicly owned
treatment works must: comply with 40
CFR part 403; and achieve the following
pretreatment standards for existing
sources (PSES).
  (a)(l) The following pretreatment
standards apply with respect to each
fiber line operated by an indirect
discharger subject to this section, unless
the indirect discharger discloses to the
pretreatment control authority in a
report submitted under 40 CFR
403.12(b) that it uses exclusively TCF
bleaching processes,at that fiber line.
These pretreatment standards must be
attained on or before April 16, 2001:

Pollutant or pollutant property
TCDD .... 	 	 	 	
TCOF . . . 	 	 	 i 	

Tdchlorosyringol 	 * 	 • 	 	
3 4 5-trichlorocatechoI . .... 	 	 	
3 4 6-trichlorocatechol 	 ; 	 '. 	 	 	
3 4 5-trichloroQuaiacol * 	 	 	 - 	

4 5 6*trichlorogua!acol 	
2 4(5-trich!orophenol 	 	 	
2,4,6'trfchlorophenol 	 	 	 , 	
Telrachlorocatechol 	
TotrachloroQualacol 	 	 	
234 6-tstrachlorophenol 	
Psntachloropnenol 	
AOX.... 	 	 	 : 	
PSES
Maximum for
any 1 day


 Grams per 1,000 kilograms (g/kkg).

-------
              Federal Register/Vol.  63. No. .72/Wednesday. April  15,  1998/Rules and Regulations       18659
   •= Kilograms per 1,000 kilograms, (kg/kkg).                          ;
     (2)  The following 'pretreatment standards  apply with respect to,each  fiber line  operated by  an indirect  discharger
 subject to this  section  if the indirect  discharger discloses  to the pretreatment control authority  in a report  submitted
 under 40 CFR 403.12(b) that it uses exclusively TCP bleaching processes at that fiber line: These pretreatment standards
 must be attained on or before April 16'," 2001:                      '                             \

                                   •                    SUBPART B

Pollutant or pollutant parameter
AOX 	 	 	 	 	
, PSES (T
Maximum for
any 1 day
This regulation does not specify this type of limitation for this pollutant; however, pretreatment control authorities may do so as appropriate.
     (b) The following pretreatment standards apply to all  indirect dischargers, in accordance  with the previous subcat-
 egorization  scheme.  An  indirect discharger is not required to meet these pretreatment  standards if it certifies to the
 pretreatment control  authority that it is not using these compounds as  biocides. In cases  when POTWs find it necessary
 to impose mass effluent limitations, equivalent mass limitations are provided as guidance:

        •                                             SUBPART" B                                      ,
                            [Supplemental PSES for bleached kraft facilities where market pulp is produced]
Pollutant or pollutant property
Pentach'lorophenol 	 	 	 	 	 	 	 	
Trichlorophenol 	 .' 	
y = wastewater discharged in kgal per ton of product.
Maximum for any 1 day
kg/kkg (or
pounds per.
1,000 Ib) of
product,
• 0.0019
0.014
Milligrams/liter
(0.011)(41.6)/y
(0.082)(41.6)/y
                                                      SUBPART B
              [Supplemental PSES for bleached kraft facilities where paperboard, coarse paper, and tissue paper are produced]


Pentachlorophenol 	
Trichlorophenol 	
y = wastewater discharged in kgal

Pollutant or pollutant property


per ton of product.
Maximum for any 1 day
kg/kkg (or
?°OOofb)Pof Milligrams/liter
product
0 001 6 (0 01 1 )(35 4)/y
0012 (0 082) (35 4)/y

                                                      SUBPART B                               '  ,
     [Supplemental PSES for bleached kraft facilities where pulp and fine papers are produced and soda facilities where pulp'and paper are
                                                       produced]
Pollutant or pollutant property , •
Pentachlorophenol 	 	 	 	 ; 	
Trichlorophenol 	 	 	 •
y = wastewater discharged in kgal per ton of product " .
Maximum for any 1 day
kg/kkg (or
pounds per
1,000lb)of
product
0.0014
0.011 •
Milligrams/liter
(0.011)(30.9)/y
(0.082)(30.9)/y
   (c) An indirect discharger must
 demonstrate compliance with the
 pretreatment standards in paragraph
, (a) (1) of th;s section by monitoring at
 the point where the wastewater
containing those pollutants leaves the
bleach plant.
§ 430.27  Pretreatment standards for new
sources (PSNS).
 * Except as provided in 40 CFR 403.7,
any new source subject to this subpart
that introduces pollutants into a
publicly owned treatment works must:

-------
18660
Federal Register/Vol.. 63, No. 72/Wednesday,  April  15,  1998/Rules  and Regulations
comply with 40 CFR part 403; and
achieve the following pretreatment
standards for new sources (PSNS).
                             (a) (1) The following pretreatment
                           standards apply with respect to each
                           fiber line that is a new source, unless
                           the indirect discharger discloses to the

                                        SUBPART B
pretreatment control authority in a
report submitted under 40 CFR 403.12
that it uses exclusively TCP bleaching
processes at that fiber line:
Pollutant or pollutant property
TCDD 	 	 	 	 	 	 	 '. 	 » 	
TCDF 	 , 	 	 	 	 	 	 	 	 	 : 	
Chloroform 	 	 	 	 	 .- 	 	 	 *..... 	 • 	 •• 	
TfichlorosyrinQOI . •• 	
3 4 S'trichlorocatschol 	
3,4,6-triohlorocatechol 	 	 	 	 	 • 	 •' 	 • 	
3 4 5"trichioroQuaia.col 	 • 	 •••• 	
3 4 6-trichlorocjuafacoI . . . 	 	 	 • 	 • 	 • 	
4,5 6-trfchIoroguaiacol 	 	 	 	 	 	 	
2,4 5*trichlorophsnol 	 * 	 	 	 • 	 • 	
2,4,6-trfchlorophenol 	 	 	 	 	 	 	 	 	 	
Totrachiorocatecnol 	 	 	 	 	
TstfSchloroQuaiacol 	 	 	 •• 	 • 	
234 6"t©trachlorophsnoi 	 	 	 	 • 	 • 	

AOX 	 : 	
Maximum for
any 1 day
)
(")'
4.14d
(b)
(»)
(")"
(b)
(b)
(b)
(b)>
(b)
(")
(b)
(b)
(b)
0.814=
                                                                                                      PSNS
  =">This regulation does not specify this type of limitation for this pollutant; however, pretreatment control authorities may do so as appropriate.
  «Picograms per liter.                                 .                 ,
  <• Grams per 1,000 kilograms (g/kkg).                                                                              *
  « Kilograms per 1,000 kilograms (kg/kkg).

    (2) The following pretreatment standards apply with respect to each  new  source fiber line operated by an indirect
discharger subject to  this section if  the  indirect discharger discloses to  the pretreatment control authority in a report
submitted under 40 CFR 403.12(b)  that it uses exclusively TCF bleaching processes at that fiber line:

                                                     SUBPART B


AOX 	

Pollutant or, pollutant parameter

PSNS (TCP)
Maximum for Monthly
any 1 day average

-------
              Federal Register/Vol. 63. No. 72/Wednesday, April 15, 1998/Rules and Regulations       18B61
                                                      SUBPART B
              [Supplemental PSNS for bleached kraft facilities Where paperboard, coarse paper, and tissue paper are produced]
• ( '
Pollutant or pollutant property . •. ' .
Pentachlorophenol 	 	 	 '. 	 	 	
Trichlorophenol 	 	 	 : 	 „:'. 	
y = wastewater discharged in kgal per ton of product.
Maximum for any 1 day
kg/kkg (or
pounds per
1,000lb)of
product
0.0016
0.012
Milligrams/liter ',
(0.012)(31.7)/y
(0.092)(3l'.7)/y
         •   . .                                         SUBPART B .
     [Supplemental PSNS for bleached kraft facilities where pulp and fine papers are produced and soda facilities where pulp and paper are
                                                       .produced]
Pollutant or pollutant parameter
Pentachlorophenol 	 „.. 	
Trichlorophenol 	 	 	 	 	 : 	 	
y = wastewater discharged in kgal per ton of product.
Maximum for any 1 day
kg/kkg (or
pounds per
1,000lb)of
product
0.0014
0.011
Milligrams/liter
(0.014)(25.1)/y
(0.101)(25.1)/y
   (c) An indirect discharger must
 demonstrate compliance with the
 pretreatrrient standards in paragraph   :
-(a)(l) of this section by monitoring at
 the point where the wastewater
 containing those pollutants leaves the
 bleach plant.

 § 430.28  Best management practices
 (BMPs).
   The definitions and requirements set
 forth in 40 CFR 430.03 apply to facilities
 in this subpart.

 Subpart C—Unbleached Kraft
 Subcategory         ,

 §430.30  Applicability; description of the '
 unbleached kraft subcategory.
   The provisions of this subpart are
 applicable to discharges resulting from:
the production of pulp and paper at
unbleached kraft mills; the production
of pulp and paper at unbleached kraft -
neutral sulfite semi-chemical (cross
recovery) mills; and the production of
pulp and paper at combined unbleached
kraft and semi-chemical mills, wherein
the spent semi-chemical cooking liquor
is burned within the unbleached kraft
chemical recovery system.

§430.31 Specialized definitions.

  For the purpose of this subpart, the
general definitions, abbreviations, and
methods of analysis set forth in 40 CFR
part 401 and § 430.01 of this part shall
apply to this subpart.          '  ••
. §430.32  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best practicable
control technology currently available
(BPT).

   Except as provided in 40 CFR 125.30
through 125.32, any existing point
source subject to this subpart must' -
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best practicable
control technology currently available '
(BPT):
                                                     SUBPART C
                                      [BPT effluent limitations' for unbleached kraft facilities]
                                                                                             Kg/kkg (or pounds per 1,000
                                                                                                   Ib) of product
Pollutant or pollutant property
BOD5 	 .• 	 ....: 	 .....:...'. 	 : 	 	 	 	 	 ;.:...- 	 : 	
TSS . . 	 	 	 .....: 	 :.... 	 	 	 ' .
DH 	 	 : 	 : 	 	 	 	 	 .: 	
Maximum for
any 1 day
. 5.6
120
(1)
Average of
daily values
for 30 con-
secutive days
2.8
6.0
. n
  1 Within the range of 6.0 to 9.0 at all times.

-------
 18662      Federal Register/Vol. 63. No. 72/.Wednesday.  April  15, 1998/Rules and Regulations
                                                       SUBPART C
  [BPT effluent limitations for unbleached kraft facilities producing pulp and paper using the unbleached kraft-neutral sulfite semi-chemical (cross
                                                     recovery) process]
Pollutant or pollutant property
BODS 	
TSS 	 	 : 	 	
PH 	 	 	 	 	 	 .....: 	
Kg/kkg (or pounds per 1 ,000
Ib) of product
Maximum for
any 1 day
8.0
12.5
, (1)
Average of
daily values
for 30 con- ;
secutive days
4.0
6.25
0)
  ' Within the range of 6.0 to 9.0 at all times.
                                                       SUBPART C
 (BPT effluent limitations for unbleached kraft facilities where pulp and paper are produced using a combined unbleached kraft and semi-chemical
          process, wherein the spent semi-chemical cooking liquor is burned within the unbleached kraft chemical recovery system]
Pollutant or pollutant property
BODS 	
TSS 	
pH 	 	 	
Kg/kkg (or pounds per 1 ,000
Ib) of product
Maximum for
any 1 day
(•)
(•)
rt
Average of
daily values
for 30 con-
secutive days
W
w
•(•)
  •[Reserved].                                                                                   •          ,

§ 430.33  Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the be«t
conventional pollutant control technology (BCT).

    Except as provided in 40 CFR 125.30 through 125.32,  any existing point source subject to this subpart shall achieve
the following effluent limitations representing the degree  of effluent reduction attainable  by the application of the  best
conventional  pollutant control technology  (BCT). except  that  non-continuous dischargers shall  not  be subject to the
maximum day and  average-of-30-consecutive-days limitations, but shall be subject to annual average effluent limitations:

                                                      SUBPART C
                                      [BCT effluent limitations for unbleached kraft facilities]
Pollutant or pollutant property
BODS 	 '. 	 ! 	
TSS 	
PH 	

1
Kg/kkg (or pounds per 1 ,00"0 Ib) of
product
Continuous
dischargers
5.6
12.0
m
Non-continuous discharg-
ers (annual average)
Maximum
for any 1
day
2.8
6.0
Average of
daily values
for 30 con-
secutive
days
1.9
3.6
  1 Within the range of 6.0 to 9.0 at all times.

-------
             Federal Register/Vol. 63, No. 72'/Wednesday.  April 15, ,1998/Rules and Regulations     , 1&663

                                                      SUBPART C                 ,
  . [BCT effluent limitations for unbleached kraft-neutral sulfite semi-chemical (cross recovery) process and/or a combined unbleached kraft and
    semi-chemical process, wherein the spent semi-chemical cooking liquor is burned within the unbleached kraft chemical recovery systemj
. Pollutant or pollutant property
BODS 	 	
TSS 	
DH 	 	 	
-


Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum .
for any 1
day
8.0
12.5
(n
Average of
daily values
for 30 con-
secutive days
4.0
. 6.25
m
Non-continu-
ous dis-
chargers
(annual
average)
2.9
3.57
m
  1 Within the range of 6.0 to 9.0 at all times.
§430.34  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best available
technology economically achievable (BAT).
  Except as provided in 40 CFR 125.30
through 125.32, any existing point
source subject to this subpart where ,
chlorophenolic-containing biocides are
used must achieve the following
effluent limitations representing the
degree of effluent reduction attainable
by the application of the best available
technology economically achievable
(BAT). Non-continuous dischargers.
shall hot be subject to the maximum day
mass limitations in kg/kkg  (lb/1000 Ib),
but shall be subject to concentration •
limitations. Concentration limitations
are only applicable to non-continuous
dischargers. Permittees not using
chlorophenolic-containing biocides  s
must certify to the permit-issuing
authority that they are not using these
biocides:
                                                      SUBPART C
                                      [BAT effluent limitations for unbleached kraft facilities]

Pentachlorophenol 	 	
Trichlorophenol 	
y=wastewater discharged
Pollutant or pollutant property


in kgal per ton of product.
Kg/kkg (or
pounds per
1,000!b)of
product
0.00058
0.00053

Milligrams/liter
(0.011)(12.6)/y
(0.010H12.6W

                                                                                              Maximum for any 1 day
                                                      SUBPART C
[BAT effluent limitations for, unbleached kraft facilities where pulp and paper are produced using the unbleached kraft-neutral sulfite semi-chemi-
    cal (cross recovery) process and/or a combined unbleached kraft and semi-chemical process, wherein the spent semi-chemical cooking liq-
    uor is burned within the unbleached kraft chemical recovery system]

Pentachlorophenor 	
Trichlorophenol
y=wastewater discharged in kgal
Pollutant or pollutant property


per ton of product.
Kg/kkg (or.
pounds per
1,OOOIb)of
product
0.00064
0.00059

Milligrams/liter
(0.011)(14.0)/y
(0 010H14.0W

                                                                                              Maximum for any 1 day
§ 430.35  New source performance
standards (NSPS). ,
  Any new source subject to this
subpart must achieve the following new
source performance standards (NSPS),
except that non-continuous dischargers
shall not be subject to the maximum day
and average of 30 consecutive days
effluent limitations for BOD5 and TSS,
but shall be subject to annual average
effluent limitations. Also, for non-
continuous dischargers, concentration
limitations (mg/1) shall apply, where
provided. Concentration limitations will
only apply to non-continuous
dischargers. Only facilities where
chlorophenolic-containing biocides are
used shall be subject to
pentachlorophenol and trichlorophenol
limitations. Permittees not using
chlorophenolic-containing biocides
must certify to the permit-issuing
authority that they are not using these
biocides:

-------
 18664       Federal Register/Vol. 63,  No.  72/Wednesday. April  15,  1998/Rules and Regulations
                                                          SUBPART C
                                   [NSPS for unbleached kraft facilities where linerboard is produced]
                                Pollutant or pollutant property
                                                                                             Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                         product
                                                                                           Continuous dischargers
                                                                                           Maximum
                                                                                           for any 1
                                                                                             day
      Average of
     daily values
      for 30 con-
       secutive
        days
        Non-con.tinu-
          ous dis-
          chargers
          (annual
          average)
 BODS
 TSS ...
 pH .....
3,4
5.8
   1.8
   3.0
0.94
1.6
                                                                                                    Maximum for any 1 day
                                                                                                Kg/kkg (or
                                                                                               pounds per
                                                                                               1,000lb)of
                                                                                                 product
              Milligrams/liter
 Pentachlorophenol 	
 Trfchlorophenol	«	
 y « wastewater discharged in kgal per ton at all times.
 0.00058
 0.00053
(0,015)(9.4)/y
(0.013)(9.4)/y
  1 Within the range of 5.0 to 9.0 at all times.
                                                          SUBPART C
                       [NSPS for unbleached kraft facilities where bag paper and other mixed products are produced]
                                Pollutant or pollutant property
                                                                                             Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                         product
                                                                                            Continuous dischargers
                                                                                           Maximum
                                                                                           for any 1
                                                                                              day
      Average of
      daily values
      for 30 con-
       secutive
         days
         Non-contin-
          uous dis-
          chargers
           (annual
          average)
BOD5
TSS...
PH	
 5.0
 9.1
   2.71
    4.8
 1.4
 2.5
                                                                                                    Maximum for any 1 day
                                                                                               Kg/kkg (or
                                                                                               pounds per
                                                                                               1,000lb) of
                                                                                                product
             Milligrams/liter
Pentachloropheno! 	
Trichlorophenol	
y a wastewater discharged in kgal per ton at all times.
 0.00058
 0.00053
  i Within the range of 5.0 to 9.0 at all times.
                                                         SUBPART C
[NSPS for unbleached kraft facilities where pulp and paper are produced using the unbleached kraft-neutral sulfite semi-chemical (cross recov-
    ery) process and/or a combined unbleached kraft and semi-chemical  process, wherein the spent semi-chemical cooking  liquor is burned
    within the unbleached kraft chemical recovery system]
Pollutant or pollutant property
BODS 	 	 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
3.9
Average of
daily values
for 30 con-
secutive
days
2.1
Non-contin-
uous dis-
chargers
(annual
average)
1.1

-------
              Federal Register/Vol.  63. No. 72/Wednesday, April 15,  1998/Rules and Regulations    •   18665


  '                                                SUBPART, C—Continued
 [NSPS for unbleached kraft facilities where pulp and paper are produced using the unbleached kraft-neutral sulfite semi-chemical (cross recov-
    ery) process and/or  a combined unbleached kraft and semi-chemical process, wherein the spent semi-chemical cookina HQuor is burned
    within the unbleached kraft chemical recovery system]                                               ...
                               Pollutant or pollutant property
                                                                                           Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                      product
                                                                                         Continuous dischargers
                                                                                         Maximum
                                                                                         for any 1
                                                                                         ,   day
                  Average of
                 daily values
                  for 30 con-
                   secutive
                    days
                                                                       Non-contin-
                                                                        uous dis-
                                                                        chargers
                                                                         (annual
                                                                        average)
TSS
pH ...
            7.3

             O
                                                                  3.8
                                                                               1.9
                                                                                                .Maximum for any 1 day
                                                                                             Kg/kkg (or
                                                                                            pounds per
                                                                                            1,000lb) of
                                                                                              product
                        Milligrams/liter
Pentachlorophenol >	,	
Trichlorophenol	,	
y = wastewater discharged in kgal per ton at all times.
            0.00064
            0.00059
  '•"Within the range of 5.0 to 9.0 at all times.
§ 430.36  Pretreatment standards for
existing sources (PSES).

  Except as provided in 40 CFR 403:7
and 403.13, any existing source subject
to this subpart that introduces
pollutants into a publicly owned
treatment works must: comply with 40
CFR part 403; and achieve the following
pretreatment standards for existing
sources (PSES) if it uses chlorophenolic-
containing biocides. Permittees not


              SUBPART C
 -.  [PSES for unbleached kraft facilities]
using chlorophenolic-containing  '
biocides must certify to the permit-
issuing authority that they are not using
those biocides. PSES must be attained
on or before July 1, 1984:
..'-.'. • ' •
Pollutant or pollutant property
Pentachlorophenol 	 :. 	 .-. 	 	 	 	 	
Trichlorophenol 	 '. 	 	
y = wastewater discharged in kgal per ton of product.
Maximum for any 1
Milligrams/liter
(0 011)(12 6)/y
(0 010)(12 6)/y

day
Kg/kkg (or
pounds per
1,000 Ib) of
product"
n onnss
0 00053

 . "The following equivalent mass limitations are provided as guidance in cases where POTWs find it necessary to impose mass effluent limita-
tions.                                '                    -                                 .
                                                        SUBPART C
[PSES for unbleached kraft facilities where pulp and paper are produced using the unbleached kraft-neutral sulfite semi-chemical (cross recov-
    ery) process and/or a combined unbleached kraft and semi-chemical  process, wherein the spent semi-chemical cooking liquor is burned
    within the unbleached kraft chemical recovery system]         •

Pollutant or pollutant property
Pentachlorophenol 	 	 ; 	 	 	 	 	
Trichlorophenol 	 	 	 	 	 ..,...: 	
y = wastewater discharged in kgal per ton of product. "
Maximum for any 1
Milligrams/liter
(0011K140VV
(0 010)(14 0)/y '

day
Kg/kkg (or
pounds per
1,000lb)of
product"
0 00064
0 00059

  "The following equivalent mass limitations are provided as guidance in cases where POTWs find it necessary to impose mass effluent limita-
tions.       ,

-------
 18666       Federal  Register/Vol. 63. No. 72/Wednesday.  April  15,  1998/Rules and Regulations
 § 430.37  Pretreatment standards for new
 sources (PSNS).
   (a) Except as provided in 40 CFR
 403.7, any new source subject to this
 subpart that introduces pollutants into a
 publicly owned treatment Works must:
 comply with 40 CFR part 403; and
 achieve the following pretreatment
 standards for new sources (PSNS) if it
 uses chlorophenolic-containing
 biocides. Permittees not using
 chlorophenolic-containing biocides   '
 must certify to the permit-issuing
 authority that they are not using these
 biocides:
                                                       SUBPART C
                                 [PSNS for unbleached kraft facilities where lirierboard is produced]
Pollutant or pollutant property
Pentachlorophenol 	
Trlchlorophenol 	
y * wastewater discharged


in kgal per ton of product.
Maximum for any 1 day
Milligrams/liter
(0.01 5X9 4)/v
(0 013)19 ' 4Vv

Kg/kkg (or
pounds per
1 ,000 Ib) of
product0
0.00058
0.00053
  "The following equivalent mass limitations are provided as guidance in cases where POTWs find it necessary to impose mass effluent limita-
 tions.

                                                       SUBPART C
                      [PSNS for unbleached kraft facilities where bag paper and other mixed products are produced]

Pollutant or pollutant property
Pentachloropheno! 	 , 	
Trlchlorophenol 	 	 	
y « wastewater discharged in kgal per ton of product.
Maximum for any 1
Milligrams/liter
(0 012)(11 4)/y
(0 011)(11 4)/y

day
Kg/kkg (or
pounds per
1,000lb)of
product"
n nnnRR
n nnfVM

  •The following equivalent mass limitations are provided as guidance in cases where PQTWs find it necessary to impose mass effluent limita-
tions.                                                                   ,                                 •

                                                      SUBPART C
[PSNS for unbleached kraft facilities where pulp and paper are produced using the unbleached kraft-neutral sulfite semi-chemical (cross recov-
    ery) process and/or a combined unbleached kraft and semi-chemical process, wherein the  spent semi-chemical cooking  liquor is burned
    within the unbleached kraft chemical recovery system]
Pollutant or pollutant property
Pcntachlorophenol 	
Trichlorophenol 	
y • wastewater discharged in


kgal per ton of product:
Maximum for any 1 day
Milligrams/liter
(0 01 3)(1 1 5)/y
(0 012)(11 5)/y

Kg/kkg (or
pounds per
1,000lb)of
product0
0.00064
0.00059
  "The following equivalent mass limitations are provided as guidance in cases where POTWs find it necessary to impose mass effluent limita-
tions.
Subpart D—Dissolving Sulfite
Subcategory

§ 430.40  Applicability; description of the
dissolving sulfite subcategory.
  The provisions of this subpart are
applicable to discharges resulting from
the production of pulp at dissolving
sulfite mills.

§430.41  Specialized definitions.
  For the purpose of this subpart, the
general definitions, abbreviations, and
methods of analysis set forth in 40 CFR
part 401 and §430.01 of this part shall
apply to this subpart.

§ 430.42  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best practicable
control technology currently available
(BPT).
  (a) Except as provided in 40 CFR
125.30 through 125.32, any existing
point source  subject to this subpart must
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best practicable
control technology currently available
(BPT), except that non-continuous
dischargers shall not be subject to the
maximum day and average of 30
consecutive days limitations but shall
be subject to annual average effluent
limitations:

-------
            Federal Register /Vol. 63.  No.  72/Wednesday.  April 15.  1998/Rules and Regulations       18667
                                    -.,"..''         SUBPART D

                   [BPT effluent limitations for dissolving sulfite pulp facilities where nitration grade pulp is produced]
Pollutant or pollutant property
BODS 	
TSS 	
PH 	


! '
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum for'
any 1. day
41.4
70.65
M
Average of
daily values
for 30 con-
secutive days
21.5
' 38.05
M
Non-contin-
•• uous dis-
chargers
(annual
average)
12.1
20.9
rn
1 Within the range of 5.0 to 9.0 at all times.
                       .                                SUBPART D                     '        ,
                   [BPT effluent .limitations for dissolving sulfite pulp facilities where viscose grade pulp is produced]
Pollutant or pollutant property
BOD5 	 	 	 	 	 , 	 	 	 	 	
TSS . . . 	 	 	 . .
PH 	 	 	 	 „.' 	 : 	 	 	 ..: 	 ..: 	
Continuous dischargers
Maximum for
any 1 day
44.3
70.65
(?)
Average of
daily values
for 30 con-
secutive days
23.0
, 38.05
P)
Non-contin-
uous dis-
chargers
(annual
average)
". 12.9
. 20.9
(')
                                                                                          Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                      product
' Within the range of 5.0 to 9.0 at all times.
                                                       SUBPART D
                  [BPT effluent limitations for dissolving sulfite pulp facilities where cellophane grade pulp is produced]
Pollutant or pollutant property
BOD5 	 	 	
TSS 	
oH 	



Continuous dischargers
Maximum
for any 1
day
48.05
70.65
!M
Average of
daily values
for 30 con-
secutive
days
24.95
38.05
M
Non-contin-
uous dis-
chargers
(annual
average)
14.0
20.9
M
                                                                                           Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                       product
' Within the range of 5.0 to 9.0 at all times.
                                                       SUBPART ,D
                   [BPT effluent limitations for dissolving sulfite pulp facilities where acetate grade pulp is produced]
Pollutant or pollutant property
BODS ....
TSS"
pH 	

'BOD5
2 Within




Continuous dischargers


Maximum
for any 1
day

'50.80
70 65
(2)

Average of
daily values
for 30 con-
secutive
days
'26.40
3805
P)


Non-contin-
uous dis-
chargers
• (annual
average)

'14.83
209
(2)

effluent limitations were remanded (Weyerhaeuser Company, et al v. Costle, 590 F. 2nd 1011; D.C. Circuit 1978).
the range of 5.0 to 9.0 at all times.
                                                                                           Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                       product

-------
 18668      Federal Register/Vol. 63. No.  72/Wednesday. April 15, 1998/Rules and Regulations
   (b) The following limitations establish
 the quantity or quality of pollutants or
 pollutant properties, controlled'by this
 section, resulting from the use of wet
 barking operations, which may be
 discharged by a point source subject to
 the provisions of this subpart. These
 limitations are in addition to the
 limitations set forth in paragraph (a) of
 this section and shall be calculated
 using the proportion of the mill's total
 production due to use of logs which are

              SUBPART P
          [BPT effluent limitations]
 subject to such operations. Non-
 • continuous dischargers shall not be
 subject to the maximum day and
 average of 30 consecutive days
 limitations, but shall be subject to
 annual average effluent limitations:
Pollutant or pollutant property
BODS 	 	 	
TSS 	
pH 	



Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum for
any 1 day
0.7
0.15
(')
Average of
daily values
for 30 con-
secutive days
0.35
0.1
(')
Non-continu-
ous dis-
chargers
(annual
average)
0.2
0.05
(') •
  1 Within the range of 5.0 to 9.0 at all times.
   (c) The following limitations establish
the quantity or quality of pollutants or
pollutant parameters, controlled by this
section, resulting from the use of log
washing or chip washing operations,
which may be discharged by a point
source subject to the provisions'of this
subpart. These limitations are in
addition to the limitations set forth in
paragraph (a) of this section and shall be
calculated using the proportion of the '
mill's total production due to use of logs

             SUBPART D
         [BPT effluent limitations]
and/or chips which are subject to such
operations. Non-continuous dischargers
shall not be subject to the maximum day
and average of 30 consecutive days
limitations, but shall be subject to the
annual average effluent limitations:
Pollutant or pollutant property
BODS 	
TSS 	
PH 	
Kg/kkg (or pounds per 1,000 Ib) of
' product
Continuous dischargers
Maximum '
for any 1
day
0.15
0.15
0)
Average of
daily values
for 30 con-
. secutive
days
0.1
0.1
C)
Non-contin-
uous dis-
chargers
(annual
average)
0.05
0.05
0)
  »Within the range of 5.0 to 9.0 at all times.
  (d) The following limitations establish
the quantity or quality of pollutants or
pollutant properties, controlled by this
section, resulting from the use of log
flumes or log ponds, which may be
discharged by a point source subject to
the provisions of this subpart. These
limitations are in addition to the
limitations set forth in paragraph (a) of
this section and shall be calculated
using the proportion of the mill's total
production due to use of logs which are
subject to such operations. Non-
continuous dischargers shall not be
subject to the maximum day and
average of 30 consecutive days
limitations but shall be subject to the
annual average effluent limitations:

-------
             Federal Register/Vol.  63, No.  72/Wednesday, April  15,  19 98/Rules and Regulations      18669

                                                      SUBPART D
                                                 [BPT effluent limitations]
• Pollutant or pollutant property
BODS 	 	
TSS 	
pH ''. 	




-
Kg/kkg (or pounds per 1 ,000 Ib) of
product -
Continuous dischargers
Maximum
for any 1
day
0.15
0.15
0)
Average of
daily values
for 30 con-
secutive
days
0,1
• ' 0.1
(')
Non-contin-
uous dis-
chargers
(annual
average)
0.05
0.05
"I1)
  ' Within the range of 5.0 to 9.0 at all times.
§430.43  Effluent limitations guidelines
representing the degree of effluent
reduction attainable by the application of
the best conventional pollutant control
technology (BCT).
  Except' as provided in 40 CFR 125.30
through 125.32, any existing point
source subject .to this subpart shall
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best conventional
pollutant control technology (BCT): The
limitations shall be the same as those
specified for conventional pollutants
(which are defined in 40 CFR 401.16) in
§ 430.42 of this subpart for the best
practicable control technology currently
available (BPT).

§430.44  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best available
technology economically achievable (BAT).
  Except as provided in 40 CFR 125.30
through 125.32, any existing point
source subject to this subpart where
chlorophenolic-containing biocides are
used must achieve the following
effluent limitations representing the  ',.
degree of effluent reduction attainable
by the application of the best available
technology economically achievable
(BAT). Non-continuous dischargers
shall not be subject to the maximum day
mass limitations in kg/kkg (lb/1000 Ib)
but shall be subject to concentration
limitations. Concentration limitations
are only applicable to non-continuous
dischargers. Permittees not using
chlorophenolic7containing biocides
must certify to the permit-issuing
authority that they are not using these
biocides:
                                                     SUBPART D         '   -
           [BAT effluent limitations for dissolving sulfite pulp facilities where nitration, viscose, or cellophane pulps are produced]

Pentachlorophenol
Trichlorophenol 	
y = wastewater discharged in kgal
Pollutant or pollutant property , '.


per ton of product.
Kg/kkg (or
pounds per
1 ,000 Ib) of
product
0 0030
0019

Milligrams/liter
(0 011)(660)/y
(0 068) (66 OVv

                                                                                            Maximum for any 1 day
                                                     SUBPART D
                    [BAT effluent limitations for dissolving sulfite pulp facilities where acetate grade pulp is produced]

Pentachlorophenol 	
Trichlorophenol 	
y = wastewater discharged
Pollutant or pollutant property


in kgal per ton of product.
Kg/kkg (or
pounds per
1,000lb)of
product
00033
0.021

Milligrams/liter
(0 01 1 K72 7)/V
(0.068)(72.7)/y

                                                                                            Maximum for any 1 day
§430.45  New source performance
standards (NSPS).

  Any new source subject to this
subpart must achieve the following new
source performance standards (NSPS).
except that non-continuous dischargers
shall not be subject to the maximum day
and average of 30 consecutive days  •
effluent limitations for BOt>5 and TSS,
but shall be subject to annual average •
effluent limitations. Also, for non-
continuous dischargers, concentration
limitations (mg/1) shall apply, where
provided. Concentration limitations will
only apply to non-continuous
dischargers. Only facilities where
chlorophenolic-containing biocides are
used shall be subject to
pentachlorophenol and trichlorpphenol
limitations. Permittees not using
chlorophenolic-containing biocides

-------
 18670       Federal  Register/Vol.  63. No. 72/Wednesday. April 15,  1998/Rules  and Regulations
 must certify to the permit-issuing
authority that they are not using these
biocides:
                                                          SUBPART D

                             [NSPS for dissolving sulfite pulp facilities where nitration grade pulp is produced]
                               Pollutant or pollutant property
                                                                                             Kg/kkg (or pounds per 1,0,00 Ib) of
                                                                                                         product
                                                                                           Continuous dischargers
                                                                                           Maximum
                                                                                           for any 1
                                                                                             day
                                                           Average of
                                                           daily values
                                                           for 30 con-
                                                            secutive  ,
                                                              days
        Non-continu-
          ous dis-
          chargers
           (annual
          average)
 BODS,
 TSS ...
 pH .....
                                                     26.9
                                                     40.8
  14.5
  21.3

    O
 7.59
11.2
                                                                                                   Maximum for any 1 day
                                                                                               Kg/kkg (or
                                                                                              pounds per
                                                                                              1,000lb)of
                                                                                                product
                                                                   Milligrams/liter
Pentachlorophenol  	
Trlchlorophenol	
y s wastewater discharged in kgal per ton at all times.
                                                        0.0030
                                                        0.019
(0.012)(59.0)/y
(0.012)(59.0)/y
  1 Within the range of 5.0 to 9.0 at all times.
                                                         SUBPART D
                             [NSPS for dissolving sulfite pulp facilities where viscose grade pulp is produced]
                               Pollutant or pollutant property
                                                                                            Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                        product
                                                                                           Continuous dischargers
                                                                                          Maximum
                                                                                          for any 1
                                                                                             day
                                                           Average of
                                                           daily values
                                                           for 30 con-
                                                            secutive
                                                              days
        Non-continu-
          ous dis-
          chargers
          (annual
          average)
BODS
TSS...
pH	
                                                    28.7
                                                    40.8
  15.5
  21.3
 8.12
11.2
                                                                                                   Maximum for any 1 day
                                                                                               Kg/kkg (or
                                                                                              pounds per
                                                                                              1,OOOIb)of
                                                                                                product
                                                                   Milligrams/liter
Pentachlorophenol	
Trichlorophenol	
y = wastewater discharged in kgal per ton at all times.
                                                       0.0030
                                                       0.019
(0.012)(59.0)/y
(0.012)(59.0)/y
  1 Within the range of 5.0 to 9.0 at all times.

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              Federal Register/Vol.  63, No.  72 / Wednesday, April  15, 1998/Rules  and  Regulations
                                                                          18671
                                                       SUBPART D
                          [NSPS for dissolving sulfite pulp facilities where cellophane grade pulp is produced]
                              Pollutant ,or pollutant property
                                                                                         Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                    product ',
                                                                                       Continuous dischargers
                                                                                       Maximum
                                                                                       for any 1
                                                                                         day
                                                         Average of
                                                         daily values
                                                         for 30 con-
                                                          secutive
                                                            days
                             Non-contin-
                              uous dis-
                              chargers
                               (annual
                              average)
BODS
TSS ...
PH  	
                                                   31.2
                                                   40.8
                       16.8
                       21.3
                        0)
 8.80
11.2
                                                                                               Maximum for any 1 day
                                                                                           Kg/kkg (or
                                                                                          pounds per
                                                                                          1,000 Ib) of
                                                                                            product
                                                                 Milligrams/liter
Pentachlbrophenol  .•.	
Trichlorophenol	
y = wastewater discharged in kgal per ton at all times.
                                                      0.0030
                                                      0.019
                     (0.012)(59.0)/y
                     (0.076)(59.0)/y
  1 Within the range of 5.0 to 9.0 at all times.
                                              ;         SUBPART D
                           [NSPS for dissolving sulfite pulp facilities where acetate grade pulp is produced]
                                                                                         Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                    product
Pollutant or pollutant property
BODS 	 	 	 	 : 	 	 	 	 	 	 	
TSS 	
pH 	 	 	 	 	 	 	 '. 	 	 	 : 	 	

Continuous dischargers
Maximum
for any 1
• day
39.6
41.1
0)
i
Pentachlorophenol 	 	 	 	 	 •. 	 ; 	 ^..
Trichlorophenol 	 .' 	 	 : 	 	 	 ; 	
y = wastewater discharged in kgal per ton at all times. ,
Average of
daily values
for 30 con-
secutive
- days
21.4
21.5
D
Non-contin-
uous dis-
chargers
(annual
average)
11.2
11.3
(1)
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000lb)of
product
0.0033
0.021
Milligrams/liter
(0.012)(65.7)/y
(Q.075)(65.7)/y ,
  1 Within the range of 5.0 to 9.0 at all times.
§ 430.46  Pretreatment standards for
existing sources (PSES).
  Except as provided in 40 CFR 403.7
and 403.13, any existing source subject
to this subpart that introduces
pollutants into a publicly owned
treatment works must: comply with 40
CFR part 403; and achieve the following
pretreatment standards, for existing.
.sources (PSES) if it uses chlorophenolic-
containing biocides. Permittees not
using chlorophenolic-containing
biocides must certify to the permit-
issuing authoritythat they are not using
these faiocides. PSES must be attained
on or before July 1, 1984:               ,'

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 18672       Federal Register/Vol.  63,  No.  72/Wednesday.  April  15,  1998/Rules and Regulations
                                                        SUBPART D
                 [PSES for dissolving sulfite pulp facilities where nitration, viscose, or cellophane grade pulps are produced]
Pollutant or pollutant property
Pentachlorophenol 	
Trichlorophenol 	
y « wastewater discharged


in kgal per ton of product.
Maximum for any 1 day
Milligrams/liter (mg/l)
(0 011)(660)/y
(0 082)(66 0)/y

Kg/kkg (or
pounds per
1,000lb)of
product"
0.0030
0.023
  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
 tions.

                                                        SUBPART D
                            [PSES for dissolving sulfite pulp facilities where acetate grade pulp is produced]
Pollutant or pollutant property
Pentachlorophenol .
Trichlorophenol 	 	
y s wastewater discharged in kgal


per ton of product.
Maximum for any 1 day
Milligrams/liter (mg/l)
fr\ n-i -twyo ~7\l\i
(0 082)(72 7)/y

Kg/kkg (or
pounds per
1,000 Ib) of
product"
0.0033
0.025
  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.
§ 430.47  Pretreatmont standards for new
sources (PSNS).
  Except as provided in 40 CFR 403.7,
any new source subject to this subpart
that introduces pollutants into a
publicly owned treatment works must:
comply with 40 CFR part 403; and
achieve the following pretreatment
standards for new sources (PSNS) if it
uses chlorophenolic-containing
biocides. Permittees not using
chlorophenolic-containing biocides
must certify to the permit-issuing
authority that they are not using these
biocides:
                                       •     •          SUBPART D                                '
                [PSNS for dissolving sulfite pulp facilities where nitration, viscose, or cellophane grade pulps are produced]

Pollutant or pollutant property
Pentachlorophenol 	 	 	
Trichlorophenol 	 	 	
y = wastewater discharged in kgal per ton of product.
Maximum for any 1
Milligrams/liter (mg/l)
(0012)(59 0)/y
(0 092)(59 0)/y

day
Kg/kkg (or '
pounds per
1,000!b)of
product"
0 0030
n np^

  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.

                                                       SUBPART D
                            [PSNS for dissolving sulfite pulp facilities where acetate grade pulp is produced]
Pollutant or pollutant property
Pentachlorophenol 	 	
Trichlorophenol 	
yswastewater discharged in kgal


per ton of product.
Maximum for any 1 day
Milligrams/liter (mg/l)
(0012)(657)/y
(0091)(65 7)/y

Kg/kkg (or
pounds per
1,000 Ib) of
product"
0.0033
0.025
  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.

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             Federal Register/Vol.  63,  No. 72/Wednesday, April  15,  1998/Rules and Regulations      18673
Subpart E—Papergrade Sulfite
Subcategory

§430.50  Applicability; description of the
papergrade sulfite subcategory.
  The provisions of this subpart apply
to discharges resulting from the:
integrated production of pulp and paper
at papergrade splfite mills, where blow
pit pulp washing techniques are used;
and the integrated production of pulp
and paper at papergrade sulfite mills
where vacuum or pressure drums are
used to wash pulp.       .

§430.51   Specialized definitions.
  (a) Except as provided in paragraphs
(b) and  (c) of this section, the general
definitions, abbreviations, and methods
of analysis set forth in 40 CFR part 401
and § 430.01  of this part apply to this
subpart.
  (b) Sulfite cooking liquor is defined as
bisulfite cooking liquor when the pH of
the liquor is between 3.0 and 6.0 and as
acid sulfite cooking liquor when the pU,
is less than 3.0.
  (c) For this subpart, the segments for
the papergrade sulfite subcategory are
defined as  follows:
  (1) The calcium-, magnesium-, or
sodium-based sulfite pulp segment
consists of papergrade sulfite mills
where pulp and paper are produced
using an acidic cooking liquor of
calcium, magnesium, or sodium sulfite,
unless those mills are specialty grade
sulfite mills;
  (2) The ammonium-based sulfite pulp
segment consists of papergrade sulfite
mills where pulp and paper are
produced using an acidic cooking liquor
of ammonium sulfite, unless those mills
are specialty grade sulfite mills;
  (3) The specialty grade sulfite pulp
segment consists of those papergrade
sulfite mills where a significant portion
of production is characterized by pulp
with a high percentage of alpha
cellulose and high brightness sufficent
to produce end products such as plastic
molding compounds, saturating and
laminating products, and photographic
papers. The specialty grade segment
also includes those mills where a major
portion of production is 91 ISO
brightness and above.

§430.52  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best practicable
control technology currently available
(BPT).

  (a) Except as provided in 40 CFR
125.30 through 125.32, any existing
point source subject to this subpart must
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of, the best practicable
control technology currently available
(BPT):
                                                     SUBPART E
    [Bisulfite liquor/surface condensers; BPT effluent limitations for papergrade sulfite facilities where blow pit washing techniques are used]
Pollutant or pollutant property
, ' *.
BODS 	
TSS 	 :.; 	
PH 	 : 	 	 	 	 	 	 	 	 	 	 	 : 	 	 	
Continuous dischargers
Maximum for
any 1 day
31.8
43.95
m
Average of
daily values
for 30 con-
secutive
days
16.55
23.65
m
Non-contin-
uous dis-
chargers
(annual
average)
9.30
12.99
m
                                                                                      Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                 product
  1 Within the range of 5.0 to 9.0 at all times.

                                                     SUBPART E  •                       '     '
   [Bisulfite liquor/barometric condensers; BPT'effluent limitations for papergrade sulfite facilities where blow pit washing techniques are used]
Pollutant or pollutant property
BODS 	 	 i 	 	 	
TSS ..... 	 	 	 ' ' .
PH 	 : 	 ;..-. 	
Continuous dischargers
Maximum
for any 1
day
34.7
52.2
(i)
Average of
daily values
for 30 con-
secutive days
18.05
28.1
m
Non-contin-
uous dis-
chargers
(annual
average)
10.14
15.44
m
                                                                                      Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                 product
  1 Within the range of 5.0 to 9.0 at all times.

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18674       Federal  Register/Vol. 63,  No.  72/Wednesday,  April  15, 1998/Rules and Regulations
                                                         SUBPART E
   [Acid sulfite liquor/surface condensers; BPT effluent limitations for papergrade sulfite facilities where blow pit washing techniques are used]
Pollutant or pollutant property
BODS 	
TSS 	 	 	
pH 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum for
any 1 day
32.3
43.95
m
Average of
daily values
for 30 con-
secutive days
16.8
23.65
m
Non-contin-
uous dis-
chargers
(annual
average)
9.44
12.99
m
 1 Within the range of 5.0 to 9.0 at all times.

                                                         'SUBPART E                                                        •
 [Add sulfite liquor/barometric condensers; BPT effluent limitations for papergrade sulfite facilities where blow pit washing techniques are used]
Pollutant or pollutant property
BODS 	 	
TSS 	
DH 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
" Maximum for
any 1 day
35.55
52.2
m
Average of
daily values
for 30 con-
secutive
days
18.5
28.1
m
Non-contin-
uous dis-
chargers
(annual
average)
10.39
15.44
m
 1 Within the range of 5.0 to 9.0 at all times.
                                                         SUBPART E
 [Bisulfite liquor/surface condensers; BPT effluent limitations for papergrade sulfite facilities where vacuum or pressure drums are used to wash
                                                             pulp]
Pollutant or pollutant property
BODS 	
TSS 	
DH 	


-
Continuous disphargers
Maximum for
any 1 day
26.7
43.95
m •
Average of
daily values
for 30 con-
secutive days
13.9
23.65
m
Non-contin-
uous dis-
chargers
(annual
average)
7.81
12.99
(n
                                                                                           Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                       product
 1 Within the range of 5.0 to 9.0 at all times.
 NOTE: Limitations above do not apply to mills using continuous digesters.


                                                         SUBPART E

  [Bisulfite liquor/barometric condensers; BPT effluent limitations for papergrade sulfite facilities where vacuum or pressure drums are used to
                                                          wash pulp]


                                                                                            Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                        product
Pollutant or pollutant property
BODS 	
TSS 	


Continuous dischargers
Maximum
for any 1
day
29.4
52.2
Average of
daily values
for 30 con-
secutive
days
15.3
28.1
Non-contin-
uous dis-
chargers
(annual
average)
8.60
15.44

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             Federal  Register/Vol. 63,  No.  72/Wednesday, April  15, 1998/Rules and  Regulations      18673
                                                  SUBPART E—Continued
 [Bisulfite liquor/barometric condensers; BPT effluent limitations for papergrade sulfite facilities where vacuum or pressure drums are used to
                                                         wash pulp]          .
Pollutant or pollutant property
. '* . "•
DH'.-. 	 	 	 	 	 :....... 	 	 	 	 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
i product
Continuous dischargers
Maximum
for any 1
day
n
Average of
daily values
for 30 con-
secutive
days •
m
Non-contin-
uous dis-
chargers
(annual
average)
m
 1 Within the range of 5.0 to 9.0 at all times.
 NOTE: Limitations above do not apply to mills using continuous digesters.     ,             •                            '"
                                                                     \          ''."•'•''       >   •

                                                 ,    -   SUBPART E

 [Acid sulfite liquor/surface condensers; BPT effluent limitations for papergrade sulfite facilities where vacuum or pressure-drums are used to
                                                         wash pulp]
Pollutant or pollutant property
BODS . 	 	
TSS 	 	 	
DH 	 	 : 	
'
. • . • -.

Continuous dischargers
Maximum
for any 1
day
29.75
43.95
P)
Average of
daily values
for 30 con-
secutive days
15.5
23.65
PV
Non-contin-
uous dis-
chargers
(annual
average)
8.71
12.99
: P)
                                                                                           Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                       product
 1 Within the range of 5.0 to 9.0 at all times.
 NpTE: Limitations above do not apply to mills using continuous digesters.                                  '          -           •

                                                        SUBPART E
[Acid sulfite liquor/barometric condensers; BPT effluent limitations for papergrade sulfite facilities where vacuum or pressure drums are used to
                                                          wash pulp]
Pollutant or pollutant property
BOD5 	 	 	 	 	 	 '...... 	
TSS • 	 	 	 	 	 • 	 •
pH 	 -, 	 : 	 -. 	 .--. 	
Continuous dischargers
Maximum
for any 1
day
32.5
52.2
(1)
Average of
daily values
for 30 cbn-
• secutive
days
16.9
28.1
(1)
Non-contin-
uous dis-
chargers
• (annual
average)
9.49
15.44
. (1)
                                                                                            Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                       product
 1 Within the range of 5.0 to 9.0 at all times.                              •            .
 NOTE: Limitations above do not apply to mills using continuous digesters.                ,

                                   ,             ,        SUBPART E                  ,
   [Continuous digesters;  BPT effluent limitations for papergrade sulfite facilities where vacuum or pressure drums are used to wash pulp]
• • ' ,
Pollutant or pollutant property
BOD5 . 	 ; 	
TSS 	 	 	 	 	 	 	 	 	 ...: 	 	 	 	 	 	 	 i 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
38.15
53.75
Average of
daily values
for 30 con-
secutive
days
19.85
28.95
Non-contin-
uous dis-
chargers
(annual
average)
11.15
15.91

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  18676       Federal Register/Vol.  63.  No. 72/Wednesday. April  15,  19987Rules and Regulations
                                                 SUBPART E—Continued
      [Continuous digesters; BPT effluent limitations for papergrade sulfite facilities where vacuum or pressure drums are used to wash pulp]
Pollutant or pollutant property
PH 	 	 	 ; 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
(1)
Average of
daily values
for 30 con-
secutive
days
n
Non-contin-
uous dis-
chargers
(annual
average)
(1)
   1 Within the range of 5.0 to 9.0 at all times.
   (b) The following limitations establish   discharged by a point source subject to
 the quantity or quality of pollutants or
 pollutant properties, controlled by this
 section, resulting from the use of wet
 barking operations, which may be
 the provisions of this subpart. These
 limitations are in addition to the
 limitations set forth in paragraph (a) of
 this section and shall be calculated
 using the proportion of the mill's total
 production due to use of logs which are
 subject to such operations:
                                                       SUBPART E
                   [BPT effluent limitations for papergrade sulfite facilities where blow pit washing techniques are used]
i
Pollutant or pollutant property
BODS 	
TSS 	 , 	
PH 	 ., 	 ;..;..;:;;
Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
2.7
7.5
(1)
Average of
daily values
for 30 con-
secutive
days
1.45
3.95
n
Non-contin-
uous dis-
chargers
(annual
average)
0.80
2.19
(1)
  1 Withfn the range of 5.0 to 9.0 at all times.

                                                       SUBPART E                           '     ,
              [BPT effluent limitations for papergrade sulfite facilities-where vacuum or pressure drums are used to wash pulp]
Pollutant or pollutant property
BODS 	
TSS 	 : 	 	 	
PH 	 	 	 	 	 : 	
Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum for
any 1 day
• 3.05
7.5'
• " (1)
Average of
daily values
for 30 con-
secutive days
1.6
3.95
(1)
Non-contin-
uous dis-
chargers
(annual
average)
0.90
2.19
(1)
  1 Within the range of 5.0 to 9.0 at all times.


  (c) The following limitations establish
the quantity or quality of pollutants or
pollutant parameters, controlled by this
section, resulting from the use of log
washing or chip washing operations.
which may be discharged by a point
source subject to the provisions of this
subpart. These limitations are in
addition to the limitations set forth in
paragraph (a) of this section and shall be
calculated using the proportion of the
mill's total production due to use of logs
and/or chips which are subject to such
operations:

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              Federal Register/Vol.  63.  No.  72/Wednesday, April 15,  1998/Rules and Regulations       18677

                                                       SUBPART E
                   [BPT effluent limitations for papergrade sulfite facilities where blow pit washing techniques are used]
Pollutant or pollutant property
BODS 	 	 	 	 : 	 	 	 	 	 	 	 	 	
TSS 	 	 	 	 	 ,.; 	
pH 	 	 	 	 	 	 	 	 	 	 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
0.15
2.55
0)
Average of
daily values
for 30 con-
secutive days
0.1
1.35
o>
Non-contin-
uous dis-
chargers
(annual
average)
0.05
0.75
(1)
  1 Within the range of 5.0 to 9.0 at all times.

                                                       SUBPART E
              [BPT effluent limitations for papergrade sulfite facilities where vacuum or pressure drums are used to wash pulp]
Pollutant or pollutant property
BODS 	 	
TSS 	 	 	
pH 	





Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
0.35
2.55
(1)
Average of
daily values
for 30 con-
secutive days
0.2
1.35
n
Non-continu-
ous discharg-
ers (annual
average) '
0.1
0.75
C1)
 /1 Within the range ,of 5.0 to 9.0 at all times.
  (d) The following limitations establish   discharged by a point source subject to   using, the proportion of the mill's total
the quantity or quality of pollutants or •
pollutant properties, controlled by this
section, resulting from the use of log
flumes or log ponds, which may be
the provisions of this subpart. These
limitations are in addition to the
limitations set forth in paragraph (a) of
this section and shall be calculated
production due to use of logs which are
subject to such operations:
                                                      SUBPART E  ,
                   [BPT effluent limitations for papergrade sulfite facilities where blow pit washing techniques are used]
'' . • . . -
Pollutant or pollutant property
BODS 	 : 	 	 	 ... 	
TSS 	 '
PH 	 :.: 	 ;......: 	 : 	 ...„....; 	 	
1 Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum for
any iday
0.35
1.7
m
Average of
daily values
for 30 con-
secutive
days
0.2
0.9
m
Non-contin-
uous dis-
, chargers
(annual
average)
0.1
0.5
m
  •> Within the range of 5.0 to 9.0 at all times.

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 18678       Federal Register/VoI. 63.  No. 72/Wednesday,  April 15,  1998/Rules and Regulations
                                                      SUBPART E
              [BPT elfluent limitations for papergrade sulfite facilities where vacuum or pressure drums are used to wash pulp]
Pollutant or pollutant property
\
BOD5 	
TSS 	
PH 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum for
any 1 day
0.7
1.70
(1)
Average of
daily values
for 30 con-
secutive days
0.35
0.9
(1)
Non-contin-
uous dis-
chargers
(annual
average)
0:2
0.5
P.)
  i Within the range of 5.0 to 9.0 at all times.
§ 430.53  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best conventional
pollutant control technology (BCT).
  Except as provided in 40 CFR 125.30
through 125.32. any existing point
source subject to this subpart must
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best conventional
pollutant control technology (BCT). The
, limitations shall be the same as those
 specified for conventional pollutants in
 § 430.52 of this subpart for the best
 practicable control technology currently
 available (BCT).

 §430.54  Effluent limitations representing
 the degree of effluent reduction attainable
 by the application of best available
 technology economically achievable (BAT).
   Except as provided in 40 CFR 125.30
 through 12,5.32, any existing point
source subject to this subpart must
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best available
technology economically achievable
(BAT).
  (a) (1) The following effluent
limitations apply to all dischargers in
the calcium-, magnesium-, or sodium-
based sulfite pulp segment:
                                                      SUBPART E
                               [Production of Calcium-, Magnesium-, or Sodium-based Sulfite Pulps]
Pollutant or pollutant property

AOX 	
COD 	




BAT effluent limitations
Continuous dischargers
Maximum for
any 1 day
Monthly average
Non-continuous dischargers
Maximum for
any 1 day
Annual
average
kg/kkg (or pounds per 1,000 Ib) of product

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              Federal Register/Vol. 63,  No. 72/Wednesday, April 15,  1998 /Rules and Regulations       18679
' ' . . . .
1
AOX 	 , 	
COD 	

Continuous dischargers
. Maximum.
for any 1
day
Monthly
average
Non-continuous
dischargers
Maximum
for any 1
day
Annual
average
kg/kkg (or pounds per 1 ,000 Ib) of product -
(")
(")
(")
(d)
(")
(")
(d)
(«.)
  "These limitations do not apply with respect to fiber lines that use a TCF bleaching process as disclosed by the discharger in its permit appli-
cation urtder 40 CFR 122.21 (g)(3) and certified under 40 CFR 122.22.                                            »       K      HH
  b"
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 18680       Federal Register/Vol. 63. No. 72/Wednesday. April  15,  1998/Rules and Regulations
  d [Reserved].                      •       '
    (ii) The following effluent limitations apply  to  dischargers in  the  specialty grade pulp  segment  with respect to
 each fiber  line that uses  exclusively TCP bleaching processes, as  disclosed  by the discharger in its NPDES  permit
 application under 40 CFR 122.21 (g)(3) and certified under 40 CFR 122.22:

                               SUBPART E—PRODUCTION OF SPECIALTY GRADE PULPS
Pollutant or pollutant property

AOX 	
COD 	

BAT effluent limitations (TCP)
Continuous dischargers
Maximum for
any 1 day
Monthly average
Non-continuous dischargers
Maximum for
any 1 day
Annual
average
kg/kkg (or pounds per 1000 Ib) of product

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              Federal Register/Vol. 63. No. 72/Wednesday.  April 15. 1998/Rules  and  Regulations      18B81
                                                      SUBPART E

                                [Production of Calcium-, Magnesium-, or Sodium-based Sulfite Pulps]
Pollutant or pollutant property

AOX 	 ...< 	 	 	 :: 	 •„ •
COD 	 • 	 	 	 .
NSPS.
Continuous dischargers
Maximum for
'any 1 day
Monthly average
Non-continuous dischargers
Maximum for
any 1 day
kg/kkg (or pounds per 1 ,0.00 Ib) of product

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18682
Federal Register/Vol.  63, No.  72/Wednesday,  April  15,  1998/Rules and Regulations
                      SUBPART E—PRODUCTION OF AMMONIUM-BASED SULFITE PULPS—Continued
Pollutant or pollutant property
COD 	
NSPS (TCP)
Continuous dischargers
Maximum for
any 1 day
W
Monthly average
(«)
Non-continuous d
Maximum for
any 1 day
CO
schargers
Annual
average
(«)
  »"


(c)
(<=)
w
w
w
(°)
(c)
(c)
(c)
(«)
(-)
tinuous
rgers
Annual
average
(or pounds per 1 ,000 Ib) of product
("
("
(")
00
W
(-)
  "These limitations do not apply with respect to fiber lines that use a TCP bleaching process as disclosed by the discharger in its permit appli-
calion under 40 CFR 122.21 (g)(3) and certified under 40 CFR 122.22.
  >>"
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              Federal .Register/Vol.  63, No.  72 /Wednesday, April 15, 1998/Rules and Regulations       18683
     (c) The following standards apply to each new source regardless of when it commenced discharge, unless-it certifies
 to the  permitting authority  that  it is not using these compounds as biocides.  Also,  for non-continuous dischargers,
 concentration limitations  (mg/1) shall apply.  Concentration limitations will only apply to non-continuous dischargers:

                                                       SUBPART E
                                                    [Supplemental NSPS]
Pollutant or pollutant property
Pentachlorophehol 	 	 	 	
Trichlorophehol .:'. 	 .': 	 	 	 	 '. 	 	
"x = percent sulfite. pulp in final product.
y = wastewater discharged in kgal per ton of product.
Maximum for any 1 day
kg/kkg (or pounds per
1 ,000 Ib) of product
•0 00058exp(0 01 7x)
0 0036exp(0 Oi7x)

Milligrams/liter i
((0.01 5)(9.1 2)exp(0.01 7x))/y
((0.094)(9.12)exp(0.017x))/y
   (d) Pursuant to 40 CFR 122.44 (i) and
 122.45 (h), a discharger must
 demonstrate compliance with the
 standards in paragraphs/(b) (2) or (b)(3)
 of this section, as applicable, by
 monitoring for all pollutants (except for
 AOX, COD,  BODS, TSS, and pH) at the
 point where the wastewater containing
 those pollutants leaves the bleach plant.
 The permitting authority may impose
. effluent limitations and/or monitoring
, requirements on internal wastestreams
 for any other pollutants covered in this
 section as appropriate under 40 CFR
 122.4400 and 122.45(h).

 §430.56  Pretreatment standards for
 existing sources (PSES).
   Except as provided in 40 CFR 403.7
,and 403.13, any existing source subject
 to this subpart that introduces,
 pollutants into a publicly owned
treatment works must: comply with 40
CFR part 403; and achieve the following
pretreatment standards for existing
sources (PSES).
  (a) The following, pretreatment
standards must be attained on or before
April 16. 2001.
  (1) The following pretreatment
standards apply to all indirect dis-
chargers in the calcium-, magnesium-,
or sodium-based sulfite pulp segment:
                                                      SUBPART E
                                [Production of Calcium-, Magnesium-, or Sodium-based Sulfite Pulps]
Pollutant or pollutant property
-•''.• :
AOX 	 ; 	 	 	 	 	 	 	 	 	 • . '
PSES
Maximum for
any 1 day
Monthly
average
kg/kkg (or pounds per 1 ,000
Ib) of product
>ML»
(b)
   a"
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18684
Federal Register/Vol.  63, No.  72/Wednesday, April 15, 1998/Rules  and Regulations
    (ii) The following pretreatment standards apply with respect to each new source fiber line, operated  by an indirect
discharger producing ammonium-based sulfite pulps if the indirect discharger discloses to the pretreatment  control author-
ity in a report submitted under  40 CFR 403.12(b) that it uses exclusively  TCP  bleaching processes at  that fiber  line:

                            SUBPART E—PRODUCTION OF AMMONIUM-BASED SULFITE PULPS  .

AOX 	
Pollutant or pollutant parameter

Maximum for
any 1 day
>
Thls regulation does not specify this type of limitation for this pollutant; however, pretreatment control authorities may do so as appropriate.
    (b) The following pretreatment standards  apply to  each indirect discharger, in  accordance with the  previous Subcat-
egorization scheme, unless it certifies to  the pretreatment control authority that  it  is not  using these compounds  as
biocides. In cases when  POTWs find  it necessary to  impose mass effluent limitations,'' equivalent mass limitations are
provided as guidance:                                                                               •

                                                       SUBPART E
                    Pollutant or pollutant property
                                                                                   Supplemental PSES
                                                                                  Maximum for any 1 day
                                                                   kg/kkg (or pounds per
                                                                     1,000 Ib) of product
                                                                                     Milligrams/liter
Pentachlorophenol
                                                   0.00058exp(0.017x) 	  ((0.011)(12.67)exp(0.017x))/y

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              Federal Register/Vol. 63. No. 72/Wednesday.  April 15.  1998/Rules  and  Regulations      18685
                                                SUBPART E—Continued
Pollutant or pollutant property
Trichlorophenol 	 	 	 	 	 ..
x = percent sulfite pulp in final product.
y = wastewater discharged in kgal per ton of product.
Supplemental PSES
Maximum for any 1 day
kg/kkg (or pounds per
1, 000 Ib) of product
0 0043exp(0 01 7x)

Milligrams/liter
((0.082)(12.67)exp(0.017x))/y
    (c)  An indirect  discharger  must demonstrate compliance with  the pretreatment standards  in  paragraphs  (a) (2)  or

 (a) (3)  of this  section, as applicable,  by  monitoring for all  pollutants  at  the  point where r the  wastewater  containing
 those pollutants leaves the bleach plant.    •                          •                     ,                      '

 §430.57  Pretreatment standards for new sources (PSNS).

    Except as provided  in  40  GFR 403.7,  any  new  source subject to this subpart that introduces  pollutants into a

 publicly owned treatment works must: comply with 40  CFR part 403; and  achieve the following  pretreatment standards
 for new sources (PSNS).

    (a) (1) The following pretreatment standards apply to each indirect discharger in the calcium-,

 magnesium-, or sodium-based sulfite pulp segment that is a'new source:

                                  ,*..'.   SUBPART E .

                               [Production of Calcium-, Magnesium-, or Sodium-Based Sulfite Pulps]
Pollutant or pollutant property
AOX 	 	 	 	 	 	 	 	 	 „ 	 , 	 	 	 '
PSNS
Maximum for
any 1 day
Monthly
average
kg/kkg (or pounds per
1,000 Ib) of product

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18686
Federal Register/Vol.  63,  No. 72/Wednesday, April  15, 1998/Rules and Regulations
                            SUBPART E.—PRODUCTION OF AMMONIUM-BASED SULFITE PULPS
                                                                                                     PSNS (TCP)

AOX 	
Pollutant or pollutant parameter

Maximum for
any 1 day
>
>


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             Federal Register/Vol.  63, No.  72/Wednesday, April  15, 1998/Ru'les and Regulations
                                                                        18687
   (c) An indirect discharger jnust
demonstrate compliance with the
pretreatment standards in paragraphs
(a) (2) or (a) (3) of this section, as  -
applicable, by monitoring for all
pollutants at the point where the ,
wastewater containing those pollutants
leaves the bleach plant.

§ 430.58  Best management "practices
(BMPs).
   The definitions and requirements set
forth in 40 CFR 430.03 apply to facilities
in this subpart.
 Subpart F—Semi-Chemical
 Subcategory
 § 430.60 Applicability; description of the
 semi-chemical subcategory.
   The provisions of this subpart are
' applicable to discharges resulting from
 the integrated production of pulp and
 paper at semi-chemical mills.
 §430.61  Specialized definitions.
   For the purpose of this subpart, the
 general definitions, abbreviations, and
 methods of analysis set forth in 40 CFR
 part 401 and § 430.01 of this part shall
 apply to this subpart.

              SUBPART- F
[BPT effluent limitations for ammonia base mills]
 §430.62  Effluent limitations representing
 the degree of effluent reduction attainable
 by the application of the best practicable
 control technology currently available
 (BPT).    .
   Except as provided in 40 CFJR 125.30
 through 125.32, any existing point
 source subject to this subpart must
 achieve the following effluent
 limitations representing the degree of
 effluent reduction attainable by the
 application of the best practicable
 control technology currently available
 (BPT):
  1 Within the range of 6.0 to 9.0 at all times.
                                                      SUBPART F
                                         [BPT effluent limitations for sodium base mills]
                                                                                                 Kg/kkg (or pounds per
                                                                                                  1,000 Ib) of product

Pollutant or pollutant property .



BODS 	 	 	 	 	 	 :. 	
TSS 	 	 	 :... 	 	 	 	 	
PH 	 	 	 	 	 • 	 ; 	 : 	 • 	 • 	

Maximum for
any 1 day


8.0
10.0
(1)
Average
of daily
values for
30 con-
secutive
days
4.0 •
5.0
D
                                                                                                 Kg/kkg (or pounds per
                                                                                                  1,000 Ib) of product
I • ' . • . ' , • , • . ' • • . .
Pollutant or pollutant property . .



BOD5 . 	 ......:.'. 	 	 	 	 	
TSS '
PH - . '

Maximum for
any 1 day


8.7
11.0
1).
Average
of daily
values for
30 con-
secutive
days
4.35
5.5
0)
  1 Within the range of 6.0 to 9.0 at all times.
§ 430.63  Effluent limitations guidelines
representing the degree of effluent
reduction attainable by the application of
the best conventional pollutant control
.technology (BCT).
   Except as provided in 40 CFR 125.30
through 125.32, any existing point
source subject to this subpart shall
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best conventional
pollutant control technology (BCT): The
limitations shall be the  same as those
specified for conventional pollutants
(which are defined in 40 CFR 401.16) in
§ 430.62 of'this subpart for the  best
practicable control technology  currently
 available (BPT), except that non-
 continuous dischargers shall not be
 subject to the maximum day and
 average-of-30-consecutive-days
 limitations, but shall be subject to
 annual average effluent limitations
 determined by dividing the average-of-
 30-consecutive-days limitations for
 BODS by 1.36 and TSS by 1.36.

 §430.64  Effluent limitations representing
 the degree of effluent reduction attainable
 by the application of the best available
 technology economically achievable (BAT).
-  Except as provided in 40 CFR 125.30
 through 125.32, any existing point
 source subject to this subpart where
 chlorophenolic-containing biocides are
 used must achieve the following
 effluent limitations representing the
 degree of effluent reduction attainable
 by the application of the best available   ,
 technology economically achievable
 (BAT). Non-continuous dischargers
 shall not be subject to the maximum day
 mass limitations in kg/kkg (Ib/1,000 Ib),
 but shall be subject to concentration
• limitations. Concentration limitations •
 are only applicable to non-continuous
 dischargers. Permittees not using
 chlorophenolic-containing biocides
 must certify to the permit-issuing
 authority that they are not using these
 biocides:

-------
  18688       Federal  Register/Vol.  63.  No. 72/Wednesday. April 15, 1998/Rules and Regulations
                                                      SUBPART F
Pollutant or pollutant property
Pentachlorophenol 	
Trichlorophenol 	
y a wastewater discharged in kgal per ton of product.
BAT effluent limitations
" Maximum for any 1 day
Kg/kkg (or
pounds per
1,000 Ib) of
product
0.0012
0.00043
Milligrams/liter
(0.029)(10.3)/y
(0.010)(10.3)/y
 § 430.65  New source performance
 standards (NSPS).
   Any new source subject to this
 subpart must achieve the following new
 source performance standards (NSPS),
 except that non-continuous dischargers
 shall not be subject to the maximum day
 and average of 30 consecutive days
 effluent limitations for BODS and TSS,
 but shall be subject to annual average
 effluent limitations. Also, for non-
 continuous dischargers, concentration
 limitations (mg/1) shall apply, where
 provided. Concentration limitations will
 only apply to non-continuous
 dischargers. Only facilities where

           '  SUBPART F
                 [NSPS]'
 chlorophenolic-containing biocides are
 used shall be subject to
 pentachlorophenol and trichlorophenol
 limitations. Permittees not using
 chlorophenolic-containing biocides
 must certify_to the permit-issuing
 authority that they are not using these
 biocides:
                             Pollutant or pollutant property
 BODS
 TSS ...
 pH	
                                                                                     Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                product
                                                                                    Continuous dischargers
                                                                                   Maximum
                                                                                   for any 1
                                                                                      day
                                                  3.0
                                                  5.8
                                                       Average of
                                                       daily values
                                                       for 30 con-
                                                        secutive
                                                          days
                       1.6
                       3.0
                           Non-continu-
                             ous dis-
                             chargers
                             (annual  .
                             average)
0.84
1.6
                                                                                           Maximum for any 1 day
                                                                                       Kg/kkg (or
                                                                                       pounds per
                                                                                       1,000lb)of
                                                                                        product
                                                              Milligrams/liter
Pentachlorophenol 	
Trichlorophenol	
y « wastewater discharged in kgal per ton at all times.
                                                   0.0012
                                                   0.00043
                    (0.041 )(7.3)/y
                    (0.014)(7.3)/y
  1 Within the range of 5.0 to 9.0 at all times.
§ 430.65  Pretreatment standards for
existing sources (PSES).
  Except as provided in 40 CFR 403.7
and 403.13, any existing source subject
to this subpart that introduces
pollutants into a publicly owned
treatment works must: comply with 40
CFR part 403; and achieve the following
pretreatment standards for existing
sources (PSES) if it uses chlorophenolic-
containing biocides. Permittees not


             SUBPART F
using chlorophenolic-containing
biocides must certify to the permit-
issuing authority that they are not using
these biocides. PSES must be attained
on or before July 1, 1984:
Pollutant or pollutant property
Pentachlorophenol 	 ; 	
PSES
Maximum for any 1 clay
Milligrams/liter
(0.032H1 0.SVv 	
Kg/kkg (or
pounds per
1,000lb) of
product"
0.0014

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             Federal Register/Vol.  63,  No. 72/Wednesday, April 15.  1998/Rules and Regulations       18G89

                                               SUBPART F—Continued


Pollutant or pollutant property
Trichlorophenol 	 	 	 	 	 ,.....'. 	 , 	
y = wastewater discharged in kgalper ton of product.
PSES
Maximum for any 1
Milligrams/liter
(0 010)(10 3)/y


day
Kg/kkg (or
pounds per
1,000 Ib) of
product"
0 00043

  aThe following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass equivalent limita-
tions.                                                                       ,
§ 430.67  Pretreatment standards for new
sources (PSNS).
  Except as provided in 40 CFR 4,03.7,
any new spurce subject to this subpart
that introduces pollutants into a
publicly owned treatment works must:
comply with 40 CFR part 403; and
achieve the following pretreatment
standards for new sources (PSNS) if it
uses chlorophenolic-containing

              SUBPART F
biocides. Permittees not using
chlorophenolic-containing biocides
must certify to the permit-issuing
authority that they are not using these
biocides:           •
Pollutant or pollutant property
Pentachlorophenol 	 	 •. 	 	 	
Trichlorophenol 	 ; 	 	 	 	 	 	 	 .„ 	 : 	 ,..
y = wastewater discharged in kgal per ton of product.
PSNS
Maximum for any 1 day
', •
" Milligrams/liter
(0.045X7 3)/v
(0.014)(7.3)/y ..




Kg/kkg (or
pounds per
1,000lb)of
product0
0.0014
0.00043
  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass equivalent limita-
tions.
Subpart G—Mechanical Pulp
Subcategory

§430.70  Applicability; description of the
mechanical pulp subcategory.
  The provisions of this subpart are
applicable to discharges resulting from:
the production of pulp arid paper at
ground wood chemi-mechanical mills;
the production of pulp and paper at
groundwood mills through the
application, of the thermo-mec'hanical
process; the integrated production of
pulp and coarse paper, molded pulp
products, and  newsprint at groundwood
mills; and the  integrated production of '
pulp and fine paper at groundwood
mills.

§430.71 Specialized definitions.
  For the purpose of this subpart, the
general definitions, abbreviations, and
methods of analysis set forth in 40 CFR
part 401 and § 430.01 of this part shall
apply to this subpart.

§ 430.72 Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best practicable
control technology currently available
(BPT).
  (a) Except.as provided in 40 CFR
125.30 through 125.32, any existing
point source subject to this subpart must
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best practicable
control technology currently available
(BPT),  except that non-continuous
dischargers shall not be subject to the
maximum day and average of 30
consecutive days limitations but shall
be subject to annual average effluent
limitations:
          .         .                      ,            SUBPART G
       [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood chemi-mechanical mills are produced]

                                                                                      Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                product
Pollutant or pollutant property
BODS ,
TSS 	 	 	 	 	 	 	 	 	 .....:........ 	 	 	 .." 	
Continuous dischargers
Maximum
for any 1
day
13.5
19.75
Average of
daily values
for 30 con-
secutive
days
7.05
10.65
Non-contin-
uous dis-
chargers
(annual
average)
3.96
5.85

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18690       Federal Register/Vol.  63, No.  72/Wednesday, April 15,  1998/Rules and  Regulations
                                                  SUBPART G—Continued
       [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood chemi-rnechanical mills are produced]
Pollutant or pollutant property
pH 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
(1)
Average of
daily values
for 30 con-
secutive
days
(1)
Non-contin-
uous dis-
chargers
(annual
average)
(1)
 i Within the range of 5.0 to 9.0 at all times.
                                                        SUBPART G
  [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood mills are produced through the application of the
                                                  thermo-mechanical process]
Pollutant or pollutant property
BODS 	
TSS 	 	 	
PH 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
10.6
15.55
. m
Average of
daily values
for 30 con-
secutive
days
5.55
8.35
m
Non-cojrtin-
uous dis-
chargers
(annual
average)
3.12
4.59
W
 1 Within the range of 5,0 to 9.0 at all times.
                                                        SUBPART G
  [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and coarse paper, molded pulp products, and
                                             newsprint at groundwood mills occurs]
Pollutant or pollutant property
BODS 	 	 	
TSS 	
DH 	



Continuous dischargers


Maximum
for any 1
day .

745
1275
m
Average of
daily values
for 30 con-
secutive
days
39
685
m

Non-contin-
uous dis-
chargers
(annual
average)

2 19
376
m
                                                                                           Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                      product
 1 Within the range of 5.0 to 9.0 at all times.

                                                        SUBPART G
   [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and fine paper at groundwood mills occurs]
Pollutant or pollutant property
BODS 	
TSS 	 	 	 : 	 	 	
DH 	 	 	
Continuous dischargers
Maximum
for any 1
day
6.85
11.75
(1)
Average of
daily values
for 30 con-
secutive
days
3.6
6.3
f1)
Non-contin-
uous dis-
chargers
(annual
average)
2.0
3.5
(1)
                                                                                          Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                      product
 1 Within the range of 5.0 to 9.0 at all times.

-------
             Federal  Register/Vol. 63.  No. 72/Wednesday. April 15. 1998/Rules  and Regulations     '.'18691'
  (b) The following limitations establish
the quantity or quality of pollutants or
pollutant properties, controlled by this
section, resulting from the use of wet
barking operations, which may be
discharged by a point source subject to
the provisions of this subpart. These
limitations are in addition to the
limitations set forth in paragraph (a) of
this section and shall be calculated
.using the proportion of the mill's total
production due to use of logs which are
subject to such operations. Non-
continuous dischargers shall not be •
subject to the maximum day and
average of 30 consecutive days
limitations, but shall be subject to
annual average effluent limitations:
                                                    •.  . SUBPART G                                   •
       [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood chemi-mechanical mills are produced]
\
. , Pollutant or pollutant property
t : . • • •
BOD5 	 	 	 .......' .
TSS 	 	 	 	 	 ;. 	 	 	
PH 	 - 	 - 	 - 	 .--..•. 	 - 	 - 	 	 	 	 	
Kg/kkg (or pounds per 1,000 lb),of
product
Continuous dischargers
Maximum
for any 1
day
0.9
2.6
. (1)
Average of
daily values
for 30 con-
secutive
days
0.45
1.45
(1)
Non-contin-
uous dis-
chargers ,
(annual
average)
0.25
0.80
0)
  ' Within the range of 5.0 to 9.0 at all times.
                                                      SUBPART G
  [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood mills are produced through the application of the
                                                thermo-mechariical process]
* ' . ' . ' ' l
Pollutant or pollutant property
BODS 	 	
TSS 	
PH 	



Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
. day
• . • 0.9
2.7
• m
Average of
daily values
for 30 con-
secutive '
days
0.45
1.45
m
Non-contin-
uous dis-
chargers
(annual
average)
0'.3
0.75
m
 1 Within the range of 5.0 to 9.0 at all times.
                                                      SUBPART G
  [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and coarse paper, molded pulp products, and
                                            newsprint at groundwood mills occurs]
1
Ppllutant or pollutant property • -.
BODS 	 	 	 	 	 	 '. 	 :_: 	 ,:.., 	
TSS 	 	 	
PH 	 ; 	


Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
1.15
2.0
(1)
Average of
daily values
for 30 con-
secutive
days
0.55
1.1
m
Non-contin-
uous dis-
chargers
(annual
average)
0.30
0.60
m
 1 Within the range of 5.0 to 9.0 at all times.

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18692
Federal Register/Vol.  63. No.  72/Wednesday, April 15, 1998/Rules  and  Regulations
                                                      SUBPART G
    [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and fine paper at groundwood mills occurs]
Pollutant or pollutant property
BODS 	
TSS 	
oH 	



Continuous dischargers
Maximum
for any 1
day
1.1
1.95
0)
Average of
daily values
for 30 con-
secutive days
0.55
1.1
rn
Non-continu-
ous dis-
chargers
(annual
average)
0.35
0.60
0)
                                                                                       Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                  product
  i Within the range of 5.0 to 9.0 at all times.             ,

    (c) The following  limitations establish  the  quantity or quality  of pollutants or pollutant parameters,  controlled  by
this section, resulting from the use of log washing or chip washing  operations, which may be  discharged by a point
source subject to the provisions of this subpart.  These limitations are in addition to the limitations set forth in paragraph
(a)  of this section and shall be calculated  using the proportion of the mill's  total production  due to use of logs  and/
or chips which  are subject to such operations. Non-continuous dischargers shall  not be subject to the maximum day,
and average of 30 consecutive days limitations, but shall be subject to the annual average effluent limitations:

                                                      SUBPART G
      [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood chemi-mechanical mills are produced]
Pollutant or pollutant property
BOD5 	
TSS 	
oH 	



Continuous dischargers


Maximum
for any 1
day

0.05
0.25
P)
Average of
daily values
for 30 con-
secutive
days
0.05
0.15
(1)

Non-contin-
uous dis-
chargers
(annual
average)

0.05
0.10
0)
                                                                                        Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                   product
  1 Within the range of 5.0 to 9.0 at all times.
                                                      SUBPART G
  [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood mills are produced through the application of the
                                                thermo-mechanical process]
Pollutant or pollutant property
BOD5 	 	 	 - 	
TSS 	 	 	
oH 	 	 	 	
Continuous dischargers
Maximum
for any 1
day
0.05
0.30
(1)
Average of
daily values
, for 30 con-
secutive
days
0.05
0.15
(1)
Non-contin- ,
uous dis-
chargers
(annual
average)
0.05
0.05
(1)
                                                                                        Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                   product
  1 Within the range of 5.0 to 9.0 at all times.

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              Federal Register/Vol. 63, No. 72/Wednesday. April 15. 1998/Rules  and  Regulations       18693
                                  "                     SUBPART G
    [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and coarse paper, molded pulp products and
                                             newsprint at groundwdod mills occurs]
Pollutant or pollutant property
/ " , -
BOD5 	 .'. 	 ; 	
TSS 	
pH 	 	 	 	 	 	 	 	 	 , 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product .
Continuous dischargers
Maximum
for any 1
day
0.15
0.20
(1)
Average of
daily values
for 30 con-
secutive
days
0.05
0.15
(1)
Non-contin-
uous dis-
chargers
(annual
average)
0.05
0.10
(1)
  1 Within the range of 5.0 to 9.0 at all times.

                                                       SUBPART G    :                                  •
    [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and fine paper at groundwood mills.occurs]
.Pollutant or pollutant property
s
BOD5 	 	 	 	
TSS 	 	 	 	
PH 	 : 	 : 	 : 	 ;..;„ 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
0.15
0.2
(1)
Average of
daily values
for 30 con-
secutive
days
0.05
0.15
(1)
Non-contin-
uous dis-
chargers
(annual
average)
0.05
0.10
(1)
  1 Within the range of 5.0 to 9.0 at all times.
    (d)  The  following limitations  establish the quantity  or quality  of pollutants  or  pollutant  properties, controlled by
this section, resulting from  the use of  log flumes or log  ponds, which may be  discharged by  a point source  subject
to the-provisions  of this subpart. These limitations  are in addition  to  the limitations  set forth  in  paragraph (a) of
this section and shall be calculated  using the  proportion' of  the  mill's  total production due  to use  of. logs which
are subject to such  operations.  Non-continuous dischargers shall not  be  subject  to  the  maximum  day and average of
30 consecutive days limitations but shall be subject to the annual average effluent limitations:

                  ,                                    SUBPART G
       [BPT effluent limitations for mechanical pulp facilities where pulp and.paper at groundwood  chemi-mechanical mills are produced]
. Pollutant or pollutant property
BODS 	 	 	 	 	
TSS 	 > 	 	 	
pH 	 	 	 	 	 	 	 .,.. 	 	 	 ;..
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
0.15
0.55
n
Average of
daily values
for 30 con-
secutive
days
/ ' 0.05
0.3
(1)
Non-contin-
uous dis-
chargers
(annual
average)
0.05
0.15
(1)
  1 Within the range of 5.0 to 9.0 at all times.

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18694
Federal Register/Vol. 63, No. 72/Wednesday,  April  15,  19987Rules and 'Regulations
                                                       SUBPART G

  [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood mills are produced through the application of the
                                                 thermo-mechanical process]
Pollutant or pollutant property
BODS 	
TSS 	
OH 	
•


Continuous dischargers
Maximum
• for any 1
day
• 0.15
0.60
P)
Average of
daily values
for 30 con-
secutive
days
0.15
0.35
(1)
Non-contin-
uous dis-
chargers
(annual
average)
0.05
0.15
(1)
                                                                                         Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                    product
  1 Within the range of 5.0 to 9.0 at all times.
                                                       SUBPART G
   [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and coarse paper, molded pulp products, and
                                             newsprint at groundwood mills occurs]

Pollutant or pollutant property
BODS .. 	 i 	
TSS 	 	 	 . 	
DH 	 	 	 	 	 : 	
Continuous
Maximum
for any 1
day'
0.25
0.45
(1)
dischargers
Average of
daily values
for 30 con-
secutive
days
0.1
0.25
(1)

uous dis-
chargers
(annual
average)
0.05
0.15
(1)
                                                                                        Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                    product
  i Within the range of 5.0 to 9.0 at all times.

                                                       SUBPART G
    [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and fine paper at groundwood mills occurs]
Pollutant or pollutant property
BODS 	
TSS 	
DH 	



Continuous dischargers
Maximum
for any 1
day
' 0.2
0.4
(1)
Average of
daily values
for 30 con-
secutive
days
0.05
0.25
(1)
Non-contin-
uous dis-
chargers
(annual
average)
0.05
0.15
(1)
                                                                                         Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                    product
  1 Within the range of 5.0 to 9.0 at all times.

    (e) For those mills  using zinc hydrosulfite as a bleaching agent in  the  manufacturing process, the following effluent
limitations are to  be added to  the  base limitations  set forth  in paragraph (a)  of this  section.  Permittees not  using
zinc hydrosulfite as a bleaching agent must certify to  the permit issuing authority that they are not using this bleaching
compound. Non-continuous dischargers shall  not be .subject to  the maximum day and average of  30 consecutive  days
effluent limitations, but shall be subject to annual average effluent limitations:

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               Federal Register/Vol. 63, No. 72/Wednesday, April 15. 1998/Rules  and  Regulations      18695
                                                       SUBPART G
        [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood chemi-mechanical mills are produced]
1 •. ' Pollutant or pollutant property '
Zinc 	 : 	 	 	 	 	
Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
0.34
Average of
daily values
for 30 con-
secutive
days
'0.17
Non-contin-
uous dis-
chargers
(annual
average)
0.11
                             .               '           SUBPART G
   [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood mills are produced through the application of the
                   • .   .                          thermo-mechanical process]
Pollutant or pollutant property
Zinc 	 	 	 '...... 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
• product
Continuous dischargers
Maximum
for any 1
day
0.26
Average of
daily values
for 30 con-
secutive
days
0.13
Non-contin-
uous dis-
chargers
(annual
average)
0.09
             •  i  :    •                     .             SUBPART G-          -             .
   [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and coarse paper, molded pulp products  and
       . .                          ,           newsprint at groundwood mills occurs]
Pollutant or pollutant property
Zinc 	 , 	 	 	 '.'•.'

Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
i
0.30
Average of
daily values
for 30 con-
secutive
days
0.15
Non-contin-
uous dis-
chargers
(annual
average)
0.10
                                                      SUBPART G
    [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and fine paper at groundwood mills occurs]
Pollutant or pollutant property
" . " /
Zinc 	 	 	 ; 	 	 	 	 	

Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
• Maximum
for any 1
day
0.275
Average of
daily values
for 30 con-
secutive
days
0.135
Non-contin-
uous dis-
chargers
(annual
average)
0.090
§ 430.73  Effluent limitations guidelines
representing the degree of effluent
reduction attainable by the application of
the best conventional pollutant control
technology (BCT).

  (a)(l) The following applies to:
mechanical pulp facilities where the
integrated production of pulp and
coarse paper, molded pulp products,
and newsprint at groundwood mills
occurs: and mechanical pulp facilities
where the integrated production of pulp
and fine paper at groundwood mills
occurs:    ,           - ,.    -
  (2) Except as provided in 40 CFR
125.30 through 125.32, any existing '  ?"
point source subject to this subpart shall
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best conventional

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18696
Federal Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules and Regulations
pollutant control technology (BCT): The
limitations shall be the same as those
specified for conventional pollutants
(which are defined in 40 CFR 401.16) in
§ 430.72 of this subpart for the best
practicable control technology currently
available (BPT).
  (b) [Reserved)

§430.74  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best available
technology economically achievable (BAT).
  (a) The following applies to
mechanical pulp facilities where pulp
and paper at groundwood mills are
produced through the application of the
thermo-mechanical process: mechanical
pulp facilities where the integrated
                           production of pulp and coarse paper,
                           molded pulp products, and newsprint at
                           groundwood mills occurs; and
                           mechanical pulp facilities where the
                           integrated production of pulp and fine
                           paper at groundwood mills occurs:
                           except as provided in 40 CFR 125.30
                           through'125.32, any existing point
                           source subject to this subpart must
                           achieve the following effluent
                           limitations representing the degree of
                           effluent reduction attainable by the
                           application of the best available
                           technology economically achievable
                           (BAT), except that non-continuous
                           dischargers shall not be subject to the
                           maximum day mass limitations in kg/
                           kkg (lb/1000 Ib). but shall be subject to

                                        SUBPART G
concentration limitations. Concentration
limitations are only applicable to non-
continuous dischargers.
Pentachlorophenol and trichlorophenol
limitations are only applicable at
facilities where chlorophenolic-
containing biocides are used. Permittees
not using chlorophenolic-containing
biocides must certify to the permit-
issuing authority that they are not using
these biocides. Zinc limitations are only
applicable at facilities where zinc .
hydrosulfite is used as a bleaching
agent. Permittees not using zinc
hydrosulfite as a bleaching agent must
certify to the permit issuing authority
that they are not using this  bleaching
compound:
  [BAT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood mills are produced through the application of the
                                               thermo-mechanical process]
Pollutant or pollutant property
Pontachlocopheno! .....

Zinc
y * wastewater discharged in



kgal per ton of product.
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000lb)of
product
0.00097
0.00088
0.26
Milligrams/liter
(0.011 )(21.1)/y
(0.010)(21.1)/y
(3.0)(21.1)/y
                                                     SUBPART G
   [BAT effluent limitations for mechanical pulp facilities where the integrated production of pulp and coarse paper, molded pulp products, and
                                           newsprint at groundwood mills occurs]


Pentachlorophenol
Trichlorophenol . ....
21nc 	 	 	 	 	
y = wastewater discharged in kgal

Pollutant or pollutant property



per ton of product.
Maximum for any 1 day
Kg/kkg (or •
?°OOnod?b)Pof MHIigrams/liter
product
0.0011 (0.011)(23.8)/y
0.00099 (0.010)(23.8)/y
0.30 (3.0)(23.8)/y

                                                     SUBPART G
    [BAT effluent limitations for mechanical pulp facilities where the integrated production of pulp and fine paper at groundwood mills occurs


Pentachlorophenol . .
Trichlorophenol
Zinc
y a waslewater discharged in kgal

Pollutant or pollutant property



per ton of product.
Maximum for any 1 day
Kg/kkg (or
?°00nod?b)Pof 'MHIigrams/liter
product
0.0010 (0.011)(21.9)/y
0.00092 (0.010)(21.9)/y
0.27 (3.0)(21.9)/y

  (b) [Reserved]
                           §430.75  New source performance
                           standards (NSPS).

                             (a) The following applies to .
                           mechanical pulp facilities where pulp
and paper at groundwood mills are
produced through the application of the
thermo-mechanical process; mechanical
pulp facilities where the integrated

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              Federal Register/Vol.  63. No.  72/Wednesday. April  15, 1998/Rules and Regulations      18697
production of pulp and coarse paper,
molded pulp products, and newsprint at
groundwood mills occurs; and
mechanical pulp facilities where the
integrated production of pulp and fine
paper at groundwood mills occurs: any
new source subject to this subpart must
achieve the following new source
performance standards (NSPS), except
that non-continuous dischargers shall
hot be subject to the maximum day and
average of 30 consecutive days effluent
 limitations for BODS and TSS, but shall
 be subject to annual average effluent
 limitations. Also, for non-continuous
 dischargers, concentration limitations
 (mg/1) shall apply, where provided-
 Concentration limitations will only
.apply to non-continuous dischargers.
 Pentachlorophenol and trichlorophenol
 limitations are only applicable at
•facilities where chlorophenolic-
 containing biocides are used. Permittees
 not using chlorophenolic-cpntaining

             • SUBPART G
biocides must certify to the permit-
issuing authority that they are not using
these biocides. Zinc limitations are only
applicable at facilities where zinc
hydrosulfite is used as a bleaching
agent. Permittees not using zinc
hydrosulfite as a bleaching agent must
certify to the permit issuing authority
that they are not using this bleaching
compound:
 [NSPS for mechanfcal pulp facilities where pulp and paper at groundwood mills are produced through the application of the thermo-mechanical
                                                         process]                                   •
                             •Pollutant or pollutant property
                                                                                         Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                    product
                                                                                        Continuous dischargers
                                                                                       Maximum
                                                                                       for any 1
                                                                                          day
                                                          Average of
                                                          daily values
                                                          for 30 con-
                                                           secutive
                                                             days
                             Non-contin-
                              uous dis-
                              chargers
                              (annual
                              average)
BODS
TSS ...
pH  .....
                                                     4.6
                                                     8.7
                                                      0)
                        2.5
                        4.6
1.3
2.4
                                                                                               Maximum for any 1 day
                                                                                          Kg/kkg (or
                                                                                          pounds per
                                                                                          1,000lb)of
                                                                                           product
                                                                 Milligrams/liter
Pentachlorophenol
Trichlorophenol	
Zinc	....
y = wastewater discharged in kgal per ton at all times.
                                                     0.00097
                                                     0.00088
                                                     0.17
                    (0.017)(13.8)/y
                    (0.015)(13.8)/y
                    (3.0)(13.8)/y
  1 Within the range of 5.0 to 9.0 at all times.
                                                       SUBPART G
    [NSPS for mechanical pulp facilities where the integrated production of pulp and coarse paper, molded pulp products, and newsprint at
                                           •       groundwood mills occurs]
                              Pollutant or pollutant property
                                                                                         Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                    product
                                                                                       Continuous dischargers
                                                                                       Maximum
                                                                                       for any 1
                                                                                         day
                                                          Average of
                                                          daily values
                                                          for 30 con-
                                                           secutive
                                                             days
                             Non-contin-
                              uous dis-
                              chargers
                             ' (annual
                              average)
BOD5
TSS ...
pH  .....
                                                     4.6
                                                     7.3
                        2.5
                        3.8
                        0)
1.3
2.0
                                                                                              Maximum for any 1 day  .
                                                                                          , Kg/kkg (or
                                                                                          pounds per
                                                                                          1,000lb)of
                                                                                           product
                                                                 Milligrams/liter
Pentachlorophenol
Trichlorophenol	
Zinc	
                                                     0.0011
                                                     0.00099
                                                     0.21
y = wastewater discharged in kgal per ton at all times.
                    (0.016)(16.8)/y
                    (0.014)(16.8)/y
                    (3.0)(16.8)/y
  1 Within the range of 5.0 to 9.0 at all times.

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 18698      Federal Register/Vol.  .63. No.  72/Wednesday. April  15.  19.98/Rules and Regulations
                                                       SUBPART G
             [NSPS mechanical pulp facilities where the integrated production of pulp and fine paper at groundwood mills occurs]
                              Pollutant or pollutant property
                                                                                        Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                   product
                                                                                      Continuous dischargers
                                                                                      Maximum
                                                                                      for any 1
                                                                                        day
                                                         Average of
                                                         daily values
                                                         for 30 con-
                                                          secutive
                                                            days
                             Non-contin-
                              uous dis-
                              chargers
                               (annual
                              average)
 BODS
 TSS ...
 PH 	
                                                    3.5
                                                    5.8
                        1.9
                        3.0
                         0)
0.99
1.58
  0)
                                                                                              Maximum for any 1 day
                                                                                          Kg/kkg (or
                                                                                         pounds per
                                                                                         1,000lb)of
                                                                                           product
                                                                Milligrams/liter
 Pentachlorophenol
 Trichlorophenol	
 Zinc	
y « wastewater discharged in kgal per ton at all times.
                                                    0.0010
                                                    0.00092
                                                    0.19
                    (0.016) (15.4)/y
                    (0.014) (15.4)/y
                    (3.0) (15.4)/y
  1 Within the range of 5.0 to 9.0 at all times.
   (b) (Reserved)

§ 430.76  Pretreatment standards for
existing sources (PSES).
   (a) The following applies to
mechanical pulp facilities where pulp
and paper at groundwood mills are
produced through the application of the
thermo-mechanical process: mechanical
pulp facilities where the integrated
production of pulp and coarse paper,
molded pulp products, and newsprint at
groundwood mills occurs; and
mechanical pulp facilities where the
integrated production'of pulp and fine
paper at groundwood mills occurs:
except as provided in 40 CFR 403.7 and
403.13, any existing source subject to
this subpart that introduces pollutants
into a publicly owned treatment works
must comply with 40 CFR part 403 and
achieve the following pretreatment
standards for existing sources (PSES).
Pentachlorophenol and trichlorophenol
limitations are only, applicable at
facilities where chlorophenolic-

              SUBPART G
containing biocides are used. Permittees
not using chlorophenolic-containing
biocides must certify to the permit-
issuing authority that they are' not using
these biocides. Zinc limitations are only
applicable at facilities where zinc
hydrosulfite is used as a bleaching
agent. Permittees not using zinc
hydrosulfite as a bleaching agent must
certify to the permit-issuing authority
that they are not using this bleaching
compound.  PSES must be attained on or
before July 1, 1984:
 [PSES for mechanical pulp facilities where pulp and paper at groundwood mills are produced through,the application of the thermo-mechanical
                                                        process]

Pollutant or pollutant properly
Pentachlorophenol 	 	 	
Trichlorophenol 	 	 : 	
Zinc 	
y « wastewater discharged in kgal per ton of product.
Maximum for any 1
Milligrams/liter (mg/1)
(0 011) (21 1)/y
(0 010) (21 1)/y
(3 G) (21 1Vv

day
Kg/kkg (or
pounds per
1,0001b)of
product0
0 00097
0 00088
0 26

  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.

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             Federal Register/Vol.  63.  No. 72/Wednesday. April  15,  1998/Rules and Regulations      18B99


               "   ',      '                     '        SUBPARTG
     [PSES for mechanical pulp facilities where the integrated production of pulp and coarse paper, molded pulp products, and newsprint at
                                                 groundwood mills occurs]
Pollutant or pollutant property
Pentachlorophenol 	 	 	 	 	 	 	 , 	 	 	
Trichlorophenol 	 	 	 	 	 	 	 	 	
Zinc 	 ...... 	 -..'. 	 I 	
y = waste,rwater discharged in kgal per ton of product. ,
Milligrams/liter (mg/1)
(0.011) (23.8)/v 	
(0.010) (23.8)/v 	
(3.0) (23.8)/v 	

Kg/kkg (or
pounds per
1,0001b)of
product"
0.001 1
0 00099
030
t •
                                                                                          Maximum for any 1 day
  »The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.        .                                   -••'..    /

                                                     SUBPART G
           [PSNS for mechanical pulp facilities where the integrated production of pulp and fine paper at groundwood mills occurs]

Pentachlorophenol 	 	 	
Trichlorophenol 	
Zinc 	 	 	 	 	
y = wastewater discharged in kgal
Pollutant or pollutant property



per ton of product. ,
i
Milligrams/liter (mg/l)
(0.011 )(21.9)/v 	 	
(0 010)(21 9Vv
(3.0)(21 .9)/y 	

Kg/kkg (or
pounds per
1,000lb)of
• product"
0.0010
000092
0.27

                                                                                          Maximum for any 1 day
  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.
  (b) [Reserved]

§ 430.77  Pretreatment standards for new
sources (PSNS).
  (a) The following applies to
mechanical pulp facilities where pulp
and paper at groundwood mills are
produced through the application of the
thermo-mechanical process; mechanical
pulp facilities where the integrated
production of pulp and coarse paper,
molded pulp products, and newsprint at
groundwood  mills occurs; and
mechanical pulp facilities where the
integrated production of pulp and fine
paper at groundwood mills occurs:
except as provided in 40 CFR 403.7, any
new source subject to this subpart that
introduces pollutants into a publicly
owned treatment works must comply  ,
with 40 CFR part 403 and achieve the
following pretreatment standards for
new sources (PSNS). Pentachlorophenol
and trichlorophenol limitations are only
applicable at facilities where
chlorophenolic-containing biocides are

             SUBPART G
used. Permittees not using
chlorophenolic-containing biocides
must certify to the permit-issuing
authority that they are not using these
biocides. Zinc limitations are only
applicable at facilities where zinc
hydrosulfite is used as a bleaching
agent. Permittees not using zinc
hydrosulfite as a bleaching agent must
certify to the permit issuing authority
that they are not using this bleaching
compound:
 [PSNS for mechanical pulp facilities where pulp and paper at groundwood mills are produced through the application of the Ihermo-mechanical
                                                       process]

Pentachlorophenol
Trichlorophenol
Zinc 	 : 	
y = wastewater discharged in
Pollutant or pollutant property



kgal per ton of, product.
Milligrams/liter (mg/l)
(0 017K13 8)/v
(0015)(138Vv
(3.0)(13.8)/y 	 	 	 	

Kg/kkg (or
pounds per
1,000 Ib) of
product"
0 00097
t 0 00088
0.17

                                                                                          Maximum for any 1 day
  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.                                       •                          ,

-------
 18700      Federal Register/Vol.  63. No.  72/Wednesday. April 15, 1998/Rules  and  Regulations
                                                       SUBPART G
     [PSNS for mechanical pulp facilities where the integrated production of pulp and coarse paper, molded pulp products, and newsprint at
                                                  groundwood mills occurs]

Pollutant or pollutant property
Pentachlorophenol 	 >
Trichloropheno! 	
Zinc 	 :.... .
y a wastewater discharged in kgal per ton of.product.
Maximum for any 1
Milligrams/liter (mg/l)
(0 016)(16 8)/y
(0 014)(16 8)/y
(3 0)(168)/y

day
Kg/kkg (or
pounds per
1,000lb)of
product3
n nnn
0 00099
n 9i

  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.

                                                      SUBPART G         .,
           [PSNS for mechanical pulp facilities where the integrated production of pulp and fine paper at groundwood mills occurs]

Pollutant or pollutant property
Pantachlorophenol 	 	 	
Trichloropheno! 	 .
Zinc 	
y a wastewater discharged in kgal per ton of product.
Maximum for any 1
Milligrams/liter (mg/l)
(0016)(154Vv
(0014)(15 4)/y
(3 OW15 4Vv

day
Kg/kkg (or
pounds per
1,000 Ib) of
product0
0 0010
n nnoQp
0 19

  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.                                                                                                        .
  (b) [Reserved]

Subpart H—Non-Wood Chemical Pulp
Subcategory

§430.80  Applicability; description of the
non-wood chemical pulp subcategory.
  The provisions of this subpart are
applicable to discharges resulting from
the production of pulp and paper at
non-wood chemical pulp mills. This
subcategory includes, but is not limited
to, mills producing non-wood pulps
from chemical pulping processes such
as kraft. sulfite, or soda.

§430.81   Specialized definitions.
  The general definitions, abbreviations,
and methods of analysis set forth in  40
CFR 401 and §430.01 of this part shall
apply to this subpart.
§430.82  Effluent limitations representing
the degree of effluent reduction attainable
by the application of best practicable
control technology currently available
(BPT). [Reserved]

§430.83  Effluent limitations representing
the degree of effluent reduction attainable
by the application of best conventional
pollutant control technology (BCT).
[Reserved]

§ 430.84  Effluent limitations representing
the degree of effluent reduction attainable
by the application of best available
technology economically achievable (BAT).
[Reserved]

§ 430.85  New source performance
standards (NSPS). [Reserved]

§ 430.86  Pretreatment standards for
existing sources (PSES). [Reserved]

§430.87  Pretreatment standards for new
sources (PSNS). [Reserved]

Subpart I—Secondary Fiber Deink
Subcategory

§430.90  Applicability; description of the
secondary fiber deink subcategory.
  The provisions of this subpart are
applicable to discharges resulting from
the integrated production of pulp and
paper at deink mills.

§430.91  Specialized definitions.
  For the purpose of this subpart, the
general definitions, abbreviations, and
methods of analysis set forth in 40 CFR
part 401 and § 430.01 of this part shall
apply to this subpart.

§430.92  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best practicable
control technology currently available
(BPT).
  Except as provided in 40 CFR 125.30
through 125.32,.any existing point
source subject to this subpart must
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best practicable
control technology currently available
(BPT), except that non-continuous
dischargers shall not be subject to the
maximum day and average of 30
consecutive days limitations but shall
be subject to  annual average effluent
limitations:

-------
             Federal Register/Vol. 63,  No. 72/Wednesday,  April 15,  1998/Rules and Regulations   .   18701
                                                      SUBPART I
                                                 [BPT effluent limitations]
• Pollutant or pollutant property ' '
BODS 	 	 	 	
TSS 	
pH 	 ,.: 	



Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum
for any 1>
day
18.1
24.05
n
Average of
daily values
for 30 con-
secutive
days
' 9.4
12.95
0
Non-contin-
uous dis-
chargers
(annual
average)
5.3
7.12
0)
  1 Within the range of 5.0 to 9.0 at all times.
,§430.93  Effluent limitations guidelines
representing the degree of effluent
reduction attainable by the application of
the best conventional pollutant control
technology (BCT).
  Except as provided in 40 CFR 125.30
through 125.32, any existing point
source subject to this subpart shall
achieve the following effluent
limitations representing the  degree of
effluent reduction attainable by the
application of the best conventional
pollutant control technology (BCT): The
limitations shall be the same as those
specified for conventional pollutants
 (which are defined in 40 CFR 401.16) in
 § 430.92 of this subpart for the best
 practicable control technology currently
 available (BPT).           '

•§430.94  Effluent limitations representing
 the degree of effluent reduction attainable
 by the application of the best available
 technology economically achievable (BAT).
   Except as provided in 40 CFR 125.30
 through 125.32, any existing point
 source subject to this subpart where
 chlorpphenolic-containing biocides are
 used must achieve the following
 effluent limitations representing the

               SUBPART I
[Facilities where fine or tissue paper .is produced]
degree of effluent reduction attainable
by the application of the best available
technology economically achievable
(BAT). Non-continuous dischargers
shall not be subject to the maximum day
mass limitations in kg/kkg (lb/1000 Ib)
but shall be subject to concentration
limitations. Concentration limitations
are only applicable to non-continuous
dischargers. Permittees not using
chlorophenolic-contaming biocides
must certify to the permit-issuing     .  -
authority that they are.not using these
biocides:
Pollutant or pollutant property
' ' , . ">
Pentachlorophenol 	 	 	 	 	 	 	 :. 	 , 	 	 ; 	
Trichlorophenol 	 	 	 : 	 : .
y = wastewater discharged in kgal per ton of product. •
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000lb)of
product
0.0030
0.0069
Milligrams/liter
(0.029)(24.4)/y
(0.068)(24.4)/y
                                                                                              BAT effluent limitations
                                                     SUBPARTI
                                           [Facilities where newsprint is produced]


Pentachlorophenol 	
Trichlorophenol 	
•y = wastewater discharged

Pollutant or pollutant property


in kgal per'ton of product.
Maximum for any 1 day
Kg/kkg (or
?POonodfb)Pof Milligrams/liter
product
0 0030 (0 029) (24 4)/y
0 001 0 (0 01 0)(24 4)/y

                                                                                              BAT effluent limitations
§ 430.95  New source performance
standards (NSPS).

  Any new source subject to this
subpart must achieve the following new
 source performance standards (NSPS),
 except that non-continuous dischargers
 shall not be subject to the maximum day
 and average of 30 consecutive days
effluent limitations for BODS and TSS,
but shall be subject to annual average
effluent limitations. Also, for non-
continuous dischargers, concentration

-------
18702       Federal Register/Vol.  63,  No.  72/Wednesday. April  15. 1998/Rules  and Regulations


limitations (mg/1) shall apply, where
provided. Concentration limitations will
only apply to non-continuous
dischargers. Only facilities where
                                           chlorophenolic-containing biocides are
                                           used shall be subject to
                                           pentachlorophenol and trichlorophenol
                                           limitations. Permittees not using

                                                         SUBPART I

                                              [Facilities where fine' paper is produced]
                                                           [NSPS]
chlorophenolic-containing biocides
must certify to the permit-issuing
authority that they are not using these
biocides:
                               Pollutant or pollutant property
                                                                                           Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                      product
                                                                                          Continuous dischargers
                                                                                         Maximum
                                                                                         for any 1
                                                                                            day
                 Average of
                 daily values
                 for 30 con-
                 • secutive
                    days
                                                                                                                 Non-contin-
                                                                                                                  uous dis-
                                                                                                                  chargers
                                                                                                                  (annual
                                                                                                                  average)
 BODS
 TSS ..,
 pH	
            5.7
            8.7
                                                                                                            3.1
                                                                                                            4.6
  1.6
  2.4
                                                                                                   Maximum for any 1 day
                                                                                                 Kg/kkg (or
                                                                                                pounds per
                                                                                                1,000lb)of.
                                                                                                  product
                          Milligrams/liter
 Pentachlorophenol 	
 Trichlorophenol	
 y *• wastewater discharged in kgal per ton at all times.
                0.0030
                0.0069
                                                                                                           (0.045)(15.9)/y
                                                                                                           (0.104)(15.9)/y
  1 Within the range of 5.0 to 9.0 at all times. -
                                                         SUBPART I
                                            [Facilities where tissue paper is produced]
                                                           [NSPS]
                               Pollutant or pollutant property
                                                                                           Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                      product
                                                                                         Continuous dischargers
                                                                                         Maximum
                                                                                         for any 1
                                                                                           day  '
                 Average of
                daily values
                 for 30 con-
                  secutive
                   days
                                                                                                                Non-contin-
                                                                                                                 uous dis-
                                                                                                                 chargers
                                                                                                                  (annual
                                                                                                                 average)
BOD5
TSS...
PH	
           9.6
          13.1

            0)
                                                                                                           5.2
                                                                                                           6.8
2.72
3.58
                                                                                                   Maximum for any 1 day
                                                                                                Kg/kkg (or
                                                                                                pounds per
                                                                                                1,000lb) of
                                                                                                 product
                         Milligrams/liter
Pentachlorophenol	
Trichlorophenol 	„	,	
y 3 wastewater discharged in kgal per ton at all times.
                0.0030
                0.0069
                                                                                                           (0.036)(19.5)/y
                                                                                                           (0.085)(19.5)/y
  1 Within the range of 5.0 to 9.0 at all times.

-------
              federal Registe /Vol. 63. No. 72/Wednesday. April 15. 199 /Rules and Regulations       18703
                                                       SUBPART I
                                            [Facilities where newsprint is produced
                                                         [NSPS]
                              Pollutant or pollutant property
                                                                                        Kg/kkg (or pounds per 1 ,000 Ib) of
                                                                                                   product
                                                                                       Continuous dischargers
                                                                                      Maximum
                                                                                      for any 1
                                                                                         day
                                                                                                 Average of
                                                                                                 daily values
                                                                                                 for 30 con-
                                                                                                  secutive
                                                                                                   days
                                                                                                             Non-contin-
                                                                                                              uous dis-
                                                                                                              chargers
                                                                                                              , (annual
                                                                                                              average)
BODS
TSS ...
PH ......
                                                                                            6.0
                                                                                            12.0
                                                                                                        3.2
                                                                                                        6.3
                                                                                                        0)
1.7
3.3
                                                                                               Maximum for any 1 day
                                                                                             Kg/kkg (or
                                                                                             pounds per
                                                                                             1,000 Ib) of
                                                                                              product
                                                                                                         Milligrams/liter
Pentachlorophenol	
Trichlorophenol 	
y = wastewater discharged in kgal per ton at all times.
                                                                                                 0.0030
                                                                                                 0.0010
                                                                                                       (0.044)(1 6.2)/y
                                                                                                       (0.015)(16.2)/y
  1 Within the range of 5.0 to 9.0 at all times.
§430.96  Pretreatment standards for existing sources (PSES).                                                     -

    (a)  Except as. provided in  40. CFR 403.7  and 403.13, any existing source subject  to  this subpart that  introduces
pollutants  into  a publicly owned  treatment works must comply with 40  CFR part 403 and  achieve the  following

pretreatment  standards for existing sources  (PSES) if it uses  chlorophenolic-containing  biocides. Permittees not  using

chlorophenolic-containing  biocides  must certify to the permit-issuing authority that they are not using these biocides.
PSES must be attained on or before July 1, 1984:

                                                      SUBPARTI             ,
                                        [Facilities where fine or tissue paper is produced]



Pentachlorophenol 	 	
Trichlorophenol 	
y = wastewater discharged in kg





al per ton of product. '
PSES
Maximum for any 1 day
Kg/kkg (or
Milligrams/liter (mg/I) figfi$%
product*

(u.iu<£)(<£4.4)/y 	 0.0033
(n r\tty\(QA A\hi • A nnoA
\\J.\JO£)(4'tA)ly 	 	 	 r 0.0084
tions.
                                                      SUBPART I
                                           [Facilities where newsprint is produced]
Pollutant or pollutant property
• ' . ' ' '
Pentachlorophenol ...
y = wastewater discharged

in kgal per ton of product
PSES
Maximum for any 1 day
Milligrams/liter (mg/l)
(0.032)(24.4)/y 	
(0.010)(24.4)/y 	
Kg/kkg (or
product"
0.0033
0.0010

-------
 18704
Federal Register/Vol. 63, No.  72/Wednesday,  April 15, 1998/Rules and Regulations
§430.97  Pretreatment standards for new sources (PSNS).
    (a) Except as provided  in  40 CFR 403.7,  any new source  subject to this subpart that  introduces  pollutants into
a publicly owned treatment  works must comply with 40 CFR part 403 and achieve the following pretreatment standards
for new sources  (PSNS) if  it uses  chlorophenolic-containing biocides. Permittees not using chlorophenolic-containing
blocides must certify to the permit-issuing authority that they are not using these biocides:

                                                     SUBPARTI
                                          [Facilities where fine paper is produced]
Pollutant or pollutant property
Pentachlorophenol 	
Trichlorophenol 	
y s wastewater discharged


in kgal per ton of product.
Maximum for any 1 day
Milligrams/liter (mg/l)
(0 049)(159)/y
(0 126)(159)/y

Kg/kkg (or
pounds per
1,000 Ib) of
product"
6.0033
0.0084
                                                                                                PSNS
  •The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass equivalent limita-
tions.

                                                     SUBPARTI
                                         [Facilities where tissue paper is produced]
Pollutant or pollutant property
Pentechlorophenol 	
Triohlorophenol 	
y = wastewater discharged


in kgal per ton of product.
Maximum for any 1 day
Milligrams/liter (mg/l)
(0040K195VV
(0 103)(195)/y

Kg/kkg (or
pounds per
1,000 Ib) of
product3
0.0033
• 0.0084
                                                                                                PSNS
  •The Mowing equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass equivalent limita-
tions.

                                                     SUBPARTI
                                          [Facilities where newsprint is produced]    .                   •                .   '
Pollutant or pollutant property
Pentachlorophenol 	
Trtchlorophenol 	 .....
y m wastewater discharged


in kgal per ton of product.
PSNS
Maximum
Milligrams/liter
(0 048)(162)/y
(0015H162W

for any 1 day
(mg/l)
,


Kg/kkg ( or
pounds per
1,OOOIb)of
product3
0.0033
0.0010
  •The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass equivalent limita-
tions.
Subpart J—Secondary Fiber Nort-
Deink Subcategory

§430.100 Applicability; description of the
secondary fiber non-deink subcategory.
  The provisions of this subpart are
applicable to discharges resulting from
the production of: paperboard from
wastepaper; tissue paper from
wastepaper without deinking at
secondary fiber mills; molded products
                          from wastepaper without deinking at
                          secondary fiber mills; and builders'
                          paper and roofing felt from wastepaper.

                          § 430.101  Specialized definitions.
                            For the purpose of this subpart:
                            (a) Except as provided below, the
                          general definitions, abbreviations, and
                          methods of analysis set forth in 40 CFR
                          part 401 and § 430.01 of this part shall
                          apply to this subpart.
  (b) Noncorrugating medium furnish
subdivision mills are mills where
recycled corrugating medium is not
used in the production of paperboard.
  (c) Corrugating medium furnish
subdivision mills are mills where only
recycled corrugating medium is used in
the production of paperboard.

-------
             Federal Register/Vol. 63,  No. 727Wednesday', April  15, 1998/Rules and Regulations
18705
§ 430.1 02  Effluent limitations representing   point source subject to this subpart must  control technology currently available
the degree of effluent reduction attainable    achieve the following effluent            (BPT):
                                        '
(BPT)
  ,..',,    • •        .,  , .  -,, „_,,,,        application of the best practicable
  (a) Except as provided in 40 CFR  .       vv   .                 , .                                            •      .   .
125.30 through 125.32, any existing                             ,                                    .
                                             .  •   .  .  SUBPART J
 [BPT effluent limitations for secondary fiber non-deink facilities where paperboard from wastepaper is produced — noncorrugating medium finish
                        •                               subdivision]
Pollutant or pollutant property
A ,-. -
BODS 	 	 	 	
TSS 	 .......
pH 	 	 	



Kg/kkg (or pounds per
1, 000 Ib) of product
Maximum
for any 1
day
3.0
5.0
(1)
Average of
daily values
• for 30 con-
secutive
days
1.5
2.5
(
  11 Within the range, of 6.0 to 9.0 at all times.
                                                       SUBPARTJ
   [BPT effluent limitations for secondary fiber non-deink facilities where paperboard from wastepaper is produced—corrugating medium finish
                                                       subdivision]
Pollutant or pollutant property
BODS 	 	 	 	 	 	 	 	 	 	 	 „... 	
TSS 	 	 	 ...: 	 	 	 	 	 	
pH 	 	 	 	 	 	 	 	 	 	 .
Kg/kkg (or pounds per
•1, 000 Ib) of product
Maximum
for any 1
day
5.7
9.2
Average of
daily values
for 30 con-
secutive
days
2.8
4.6
  1 Within the range of 6.0 to 9.0 at all times.                                      -
                                     '"'..-          SUBPART J
    . [BPT effluent limitations for secondary fiber non-deink facilities where builders' paper and roofing felt from wastepaper are produced]
•v
Pollutant or pollutant properly
BOD5 ...; 	 	 	 	 . .
TSS 	 , 	 	 	
pH 	 	 	
Setteable Solids 	

	 • 	 • 	 t 	 • 	 : 	 • 	 ••••
Kg/kkg (or pounds per
1 ,000 Ib) of product
Maximum
for any 1
day
5.0
5.0
(1)
(2)
Average of
daily values
for 30 con-
, secutive
days
,3.0
3.0
(
(
  1 Within the range of 6.0 to 9;0 at all times.
  2 Not to exce,ed 0.2 ml/I.                 ,
    (b) Except as provided in  40 CFR 125.30  through 125.32, any existing point source subject to this  subpart must
achieve  the  following effluent limitations  representing the  degree of effluent reduction attainable by the  application
of the best practicable control technology  currently  available (BPT), except that non-continuous dischargers  shall  not
be subject to the maximum day  and average of 30 consecutive days limitations but shall be subject to annual  average
effluent limitations:

-------
 18706      Federal  Register/Vol.  63,  No. 72/Wednesday, April  15,  1998/Rules and  Regulations
                                                     SUBPARTJ
          [BPT effluent limitations for secondary fiber non-deink facilities where tissue from wastepaper is produced without deinking]
Pollutant or pollutant property
BODS 	 	 	
TSS 	
PH 	



Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
13.7
17.05
(1)
Average of
daily values
for 30 con-
secutive
days
7.1
9.2
(1)
Non-contin-
uous dis-
chargers
(annual
average
days)
• 4.0
5.1
(
  1 Within the range of 5.0 to 9.0 at all times.

                                                     SUBPARTJ   »                     ,
    [BPT effluent limitations for secondary fiber non-deink facilities where molded products from wastepaper are produced without cieinking]
Pollutant or pollutant property
BODS 	
TSS 	
PH 	



Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum '
for any 1
day
4.4
10.8
(1)
Average of
daily values
for 30 con-
secutive
days
2.3
5.8
(1)
Non-contin-
uous dis-
chargers
(annual
average
days)
1.3
3.2
(
  1 Within the range of 5.0 to 9.0 at all times.
§430.103  Effluent limitations guidelines
representing the degree of effluent
reduction attainable by the application of
the best conventional pollutant control
technology (BCT).
  (a) Except as provided in 40 CFR
125.30 through 125.32. any existing
point source subject to this subpart shall
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best conventional
pollutant control technology (BCT): The
limitations shall be the same as those
specified for conventional pollutants
(which are defined in 40 CFR 401.16) in
§ 430.102 of this subpart for the best
practicable control technology currently
available (BPT).
  (b) For secondary fiber non-deink
facilities where paperboard from
wastepaper is produced, non-
continuous dischargers shall not be
subject to the maximum day and
average-of-30-consecutive-days
limitations, but shall be subject to
annual average effluent limitations
determined by dividing the average-of-
30-consecutive-days limitations for
BODS and TSS by 1.77 and 2.18.
  (c) For secondary fiber non-deink ,
facilities where builders' paper and
roofing felt from wastepaper are
produced, non-continuous dischargers
shall not be subject to the maximum day
and average-of-30-consecutive-days
limitations, but shall be subject to
annual average effluent limitations
determined by dividing the average-of-
30-consecutive-days limitations for
BODS and TSS by 1.90 and 1.90.

§ 430.104  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best available
technology economically achievable (BAT).
  Except as provided in 40 CFR 125.30
through 125.32, any existing point
 source subject to this subpart where
 chlorophenolic-containing biocides are
 used must achieve the following
 effluent limitations representing the
 degree of effluent reduction attainable
 by the application of the best available
 technology economically achievable
, (BAT). Non-continuous dischargers
 shall not be subject to the maximum day
 mass limitations in kg/kkg  (lb/1000 Ib)
 but shall be subject to concentration
 limitations. Concentration limitations
 are only applicable to non-continuous
 dischargers. Permittees not using
 chlorophenolic-containing biocides
 must certify to the permit-issuing
 authority that they are not using these
 biocides:

-------
              Federal  Register/Vol. 63. No.  72/Wednesday. April  15, 1998/Rules and Regulations       18707
                                                      SUBPART J                            _        '
              [BAT effluent limitations for secondary fiber non-deink facilities where paperboard from wastepaper is produced]


Pentachlorophenol 	 	
Trichlorophenol 	
y = wastewater discharged

. Pollutant or pollutant property


in kgal per ton of product.
Maximum for any 1 day
Kg/kkg (or
?°0UOOdfb)Pof Milligrams/liter
product
o onnsy in fi9QV7 y\i\r
o onmo inrft{Vii7?\/\i

                                                      SUBPARTJ
      [BAT effluent limitations for secondary fiber non-deink facilities where builders' paper and roofing felt from wastepaper are produced]
Pollutant or pollutant property
i ' , • '• '
Pentachlorophenol 	 	 	 .., 	 .
Trichlorophenol 	 k 	 	 	 	 	 ; 	 '. 	
y = wastewater discharged in kgal per ton of product.
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000 Ib) of
product
0.0017
0.00060
Milligrams/liter
(0.029)(14.4)/y
(0.010)(14.4)/y
                                                      SUBPARTJ
         [BAT effluent limitations for secondary fiber non-deink facilities where tissue from wastepaper is produced without deinking]


Pentachlorophenol 	 	
Trichlorophenol 	 	 	
y = wastewater discharged in

Pollutant or pollutant property •


kgal per ton of product.
Maximum for any 1 day
Kg/kkg (or
Wfbfof Milligrams/liter
product •
frnmn in npQy?1? y\iv
o 001 1 in m nups y\i\i

                                  ,                    SUBPART J
    [BAT effluent limitations for secondary fiber non-deink facilities where molded products from wastepaper are produced without deinking]
, •• Pollutant or pollutant property
Pentachlorophenol 	 	 	
Trichlorophenol 	 	 .........
y = wastewater discharged


in kgal per ton of product.
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000lb)of
product
0.0026
0.00088
Milligrams/liter
(0.029)(21.1)/y
(0.010)(21.1)/y
§430.105  New source performance
standards (NSPS).
  Any new source subject to this
subpart must achieve the following new
source performance standards (NSPS),
except that nori-continuous dischargers
shall not be subject to the maximum day
and average of 30 consecutive days
effluent limitations for BODS and TSS,
but shall be subject to annual average
effluent limitations. Also, for non- /
continuous dischargers, concentration
limitations (mg/1) shall apply, where
provided. Concentration limitations will
only apply to non-continuous .
dischargers. Only facilities where
chlorophenolic-containing biocides are
used shall be subject to
Pentachlorophenol and trichlorophenol
limitations. Permittees not using
chlorophenolic-containing biocides
must certify to the permit-issuing
authority that they are not using these
biocides:

-------
18708
Federal  Register/Vol. 63,  No.  72/Wednesday, April  15, 1998/Rules and Regulations
                                                          SUBPART J
   [NSPS for secondaiy fiber non-deink facilities where paperboard from wastepaper is produced—noncorrugating medium furnish subdivision]
                               Pollutant or pollutant property
                                                                                             Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                        product
                                                                                            Continuous dischargers
                                                                                           Maximum
                                                                                           for any 1
                                                                                              day
                                                                                         Average of
                                                                                         daily values
                                                                                         for 30 con-
                                                                                          secutive
                                                                                            days
     Non-contin-
      uous dis-
      chargers
       (annual
      average)
BODS.
TSS ...
pH .....
                                                                                    2.6
                                                                                    3.5
1.4
1.8
 n
0.73
0.95
                                                                                                     Maximum for any 1 day
                                                                                                   Kg/kkg (or
                                                                                                  pounds per
                                                                                                  1,000lb)of
                                                                                                    product
                                                                                                  Milligrams/liter
Pontachtorophenol	
Trfchtorophenol	
y a wastewater discharged in kgal per ton at all times.
                                                                                       0.00087
                                                                                       0.00030
(0.065)(3.2)/y
(0.023)(3.2)/y
  1 Within the range of 5.0 to 9.0 at all times.                                                                               ,

                                                          SUBPARTJ
     [NSPS for secondary fiber non-deink facilities where paperboard from wastepaper is produced—corrugating medium finish subdivision]
                               Pollutant or pollutant property
                                                                                             Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                        product
                                                                                            Continuous dischargers
                                                                                           Maximum
                                                                                           for any 1
                                                                                              day
                                                                                         Average of
                                                                                         daily values
                                                                                         for 30 con-
                                                                                          secutive
                                                                                            days
     Non-contin-
      uous dis-
      chargers
       (annual
      average)
BODS
TSS...
PH	
                                                                                    3.9
                                                                                    4.4
2.1
2.3
 1.1
 1.2
                                                                                                     Maximum for any 1 day
                                                                                                   Kg/kkg (or
                                                                                                  pounds per
                                                                                                  1,000lb)of
                                                                                                    product
                                                                                                  Milligrams/liter
Pentachlorophenol	,
Trtchlorophenol	
y « wastewater discharged in kgal per ton at all times.
                                                                                       0.00087
                                                                                       0.00030
(0.065)(3.2)/y
(0.023)(3.2)/y
  1 Within the range of 5.0 to 9.0 at all times.

                                                          SUBPARTJ
             [NSPS for secondary fiber non-deink facilities where builders' paper and roofing felt from wastepaper are produced]
Pollutant or pollutant property
BODS 	 :..... . .
TSS 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product ,
Continuous dischargers
Maximum
for any 1
day
1.7
2.7
Average of
daily values
for 30 con-
secutive
days
0.94
1.40
Non-contin-
uous dis-
chargers
(annual
average)
0.49
074.

-------
              Federal  Register/Vol.  63. No. 72/Wednesday,  April 15, 1998/Rules and  Regulations       18709
                                                  SUBPART J—Continued
             [NSPS for secondary fiber non-deink facilities where builders' paper and roofing felt from wastepaper are produced]
                               Pollutant or pollutant property
                                                                                            Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                       , product
                                                                                           Continuous dischargers
                                                                                          Maximum
                                                                                          for any 1
                                                                                             day
      Average of
      daily values
      for 30 con-
       secutive
         days
     Non-contin-
      uous 'dis-
      chargers
       (annual
     , average)
PH
                                                                                                    Maximum for any 1 day
                                                                                                  Kg/kkg (or
                                                                                                 pounds per
                                                                                                 1,000 Ib) of
                                                                                                   product
               Milligrams/liter
Pentachlorophenol	,	
Trichlorophenol	
y = wastewater discharged in kgal per ton at all times.
    0.0017
    0.00060
(0.155)(2.7)/y
(0.053)(2.7)/y
  1 Within the range of 5.0 to 9.0 at all times.
                    .                                    SUBPARTJ
                 [NSPS for secondary fiber non-deink facilities where tissue from wastepaper is produced without'deinking]
                               Pollutant or pollutant property
                                                                                            Kg/kkg (or pounds per 1,000 Ib) of_
                                                                                                       product
                                                                                           Continuous dischargers
                                                                                          Maximum
                                                                                          for any 1
                                                                                             day
      Average of
      daily values
      for 30 con-
       secutive
         days
     Non-contin-
      uous dis-
      chargers
       (annual
      average)
BODS
TSS ...
PH  	
 4.6
10.2

  0)
2.5
5.3
1.3
2.8
                                                                                                    Maximum for any 1 day
                                                                                                  Kg/kkg (or
                                                                                                 pounds per
                                                                                                 1,000 Ib) of
                                                                                                   product
               Milligrams/liter
Pentachlorophenol 	;	
Trichlorophenol  ...„	
y = wastewater discharged in kgal per ton at all times.
      0.0030
      0.0011
(0.045)(16.3)/y
(Q.015)(16.3)/y
  1 Within the range of 5.0 to 9.0 at all times.  •

                       •                         '         SUBPARTJ   ,             •
            [NSPS for secondary fiber non-deink facilities where molded products from wastepaper are produced without deinking]
• Pollutant or pollutant properly
BOD5 	 	
TSS 	 	
pH 	 	 	





Continuous dischargers
Maximum
for any 1
day
2.1
4:4
(1)
Average of
daily values
for 30 con-
secutive
days
1.1
2.3
(1)
Non-contin-
uous dis-
chargers
(annual
. average)
0.58
1.21
(
                                                                                            Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                        product

-------
 18710      Federal Register/Vol.  63. No.  72/Wednesday, April 15, 1998/Rules  and  Regulations

Pentachlorophenol 	 . >
Triehlorophenol 	
y a wastewater discharged in kgal per ton at all times.
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000lb)of
product .
0.0026
0.00088
Milligrams/liter
(0.107)(5.7)/y
(0.037)(5.7)/y
  1 Within the range of 5,0 to 9.0 at all times.
 §430.106  Pretreatment standards for
 existing sources (PSES).

    Except as provided in 40 CFR 403.7 and 403.13, any existing source subject to this subpart that introduces pollutants
 into a publicly owned treatment works must: comply with  40 CFR part 403; and achieve the following pretreatment
 standards for existing sources (PSES) if it uses chlorophenolic-containing biocides. Permittees  not  using chlorophenolic-
 containing  biocides must certify to  the permit-issuing authority that they  are  not using  these  biocides.  PSES must
 be attained on or before July 1, 1984:

                                                       SUBPARTJ
                     [PSES for secondary fiber non-deink facilities where paperboard from wastepaper is produced]


Pentachtorophenol 	
Trichlorophenol 	
y = wastewater discharged

Pollutant or pollutant property


in kgal per ton of product.
. Maximum for any 1
Milligrams/liter (mg/l)
(0 032^f7 2Vv
(001 01(7 2Vv

day
Kg/kkg (or
pounds per
1,000 Ib) of
product"
n nnnpfi
0 00030

  •The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.

                                                       SUBPARTJ
             [PSES for secondary fiber non-deink facilities where builders' paper and roofing felt from wastepaper are produced]

Pollutant or pollutant property
(
Pentachtorophenol 	
Trichlorophenol 	 	
y = wastewater discharged in kgal per ton of product.
Maximum for any 1
Milligrams/liter (mg/l)
(0 032)(144)y
tr\ mnvi44V/

day
Kg/kkg (or
pounds per
1,000lb)of
product3
n nmo
n nnnRn

 f »The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.

                                                       SUBPARTJ
                [PSES for secondary fiber non-deink facilities where tissue from wastepaper is produced without deinking]
Pollutant or pollutant property
Pontachlorophenol 	 .....
Trichlorophenol 	
y « wastewater discharged

t 	
in kgal per ton of product.
Maximum for any 1 day
Milligrams/liter (mg/l)
(n cm>\(p*^ y\\t
in mow? y\i\i

Kg/kkg (or
pounds per
1,000lb)of
product a
0.0034
0.0011
  »The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.

-------
              Federal  Register/Vol. 63. No. 72/Wednesday, April 15,  1998/Rules'and  Regulations       18711
                                                      .   SUBPART J
            [PSES for secondary fiber non-deink facilities where molded products from wastepaper are produced without deinking]
                               Pollutant or pollutant property
                                                                                                Maximum for any 1 day
                                                                                            Milligrams/liter (mg/l)
                           Kg/kkg (or
                          pounds per
                          1,000 Ib) of
                           product3
Pentachlorophenol	
Triohlorophenol	•.	
y = wastewater discharged in kgal per ton of product.
(0.032)(21.1)y
(0.010)(21.1)y
0.0028
0.00088
  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.                                                       .                                             '

§430.107  Pretreatment standards for new sources (PSNS).

    Except  as provided  in 40 CFR  403.7, any new  source  subject to this subpart that introduces pollutants  into  a
publicly owned treatment works' must: comply with 40  CFR part 403; and achieve the following pretreatment standards
for new sources  (PSNS)  if it uses chlorophenolic-containing biocides.  Permittees not using  chlorophenolic-containing
biocides must certify to the permit-issuing authority that they are not using these biocides:

                                     .   j,   ' • .  •         SUBPART J                            ,
                      [PSNS for secondary fiber non-deink facilities  where papertooard from wastepaper is produced]
                               Pollutant or pollutant property
                                                                                                Maximum for any 1 day.
                                                                                           Milligrams/liter (mg/I)
                           Kg/kkg (or
                          pounds per
                          1,000lb)of
                           product3
Pentachlorophenol	.'.	  (0.072)(3.2)/y	      0.00096
Trichlorophenol	\.	'.	  (0.023)(3.2)/y	      0.00030
y = wastewater discharged in kgal per ton of product.

  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.       -...-.,..

«       .               .                 :   .               SUBPART J
             [PSNS for secondary fiber non-deink facilities where builders' paper and roofing felt from wastepaper are produced]

                                                                                               Maximum for any 1 day

                              Pollutant or-pollutant property                                                            Kg/kkg (or
                                                                                          Milligrams/liter (mg/l)      ?°000 fbfof
                                                                                                                   product3

Pentachlorophenol	'.	  (0.171)(2.7)/y	       0.0019
Trichlorophenol	,	  (0.053)(2.7)/y	       0.00060
y = wastewater discharged in kgal per ton of product.

  3 Trie following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.                                                                                                               •

                                                         SUBPARTJ
                 [PSNS for secondary fiber non-deink facilities where tissue from wastepaper is produced'without deinking]

                                                                                                 Maximum for any 1  day

                                Pollutant or pollutant property   •     -             .                                     Kg/kkg (or
                                                                                             Milligrams/liter (mg/l)     %$Sot$
                 	                                .          product"

Pentachlorophenol	    . .    (0.049)(16.3)/y       0.0034
Trichlorophenol	:	;	;	]	           (0.015)(16.3)/y       0.0011
y = wastewater discharged in kgal per ton of product.

  3The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.                                                                    ,                                 .

-------
18712
Federal Register/Vol. 63, No. 72/Wednesday,  April 15, 1998/Rules and Regulations
                                                      SUBPART J
           [PSNS for secondary fiber non-deink facilities where molded products from wastepaper are produced without deinking]
Pollutant or pollutant property
Penlachlorophenol 	
Trichlorophenol 	
y = wastewater discharged


in kgal per ton of product.
Maximum for any 1 day
Milligrams/liter (mg/I)
(0.118W5.7W ...
(0.037)(5.7)/y 	 	 	

Kg/kkg (or
pounds per
1,000 Ib) of
product3
0.0028
0.00088
  "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.
Subpart K—Fine and Lightweight
Papers from Purchased Pulp
Subcategory

§430.110  Applicability; description of the
fine and lightweight papers from purchased
pulp subcategory.
  The provisions of this subpart are
applicable to discharges resulting from
the production of: fine paper at
nonintegrated mills; and lightweight
paper at nonintegrated mills.

§430.111  Specialized definitions.
  For the purpose of this subpart:
  (a) Except as provided in paragraphs
(b) and (c) of this section, the general
definitions, abbreviations, and methods
of analysis set forth in 40 CFR part 401
                           and § 430.01 of this part shall apply to
                           this subpart.
                             (b) Cotton fiber furnish subdivision
                           mills are those mills where significant
                           quantities of cotton fibers (equal to or
                           greater than 4 percent of the total
                           product) are used in the production of
                           fine papers.
                             (c) Wood fiber furnish subdivision
                           mills are those mills where cotton fibers
                           are not used in the production of fine
                           papers.
§ 430.112  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best practicable
control technology currently available
(BPT).
  Except as provided in 40 CFR 125.30
through 125.32, any existing point
source subject to this subpart must
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best practicable
control technology currently available
(BPT), except that non-continuous
dischargers shall not be subject to the
maximum day and average of 30
consecutive days limitations but shall
be subject to annual average effluent
limitations:
                                                      SUBPART K
      [BPT effluent limitations for non-integrated mills where fine paper is produced from purchased pulp—wood fiber furnish subdivision]
Pollutant or pollutant property
BOD5 	
TSS 	
PH 	



Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
8.2
11.0
(i)
Average of
daily values
for 30 con-
secutive
days
4.25
5.9
P)
Non-contin-
uous dis-
chargers
(annual
average)
2.4
3.2
(
  1 Within the range of 5.0 to 9.0 at all times.

                                                      SUBPART K
      IBPT effluent limitations for non-integrated mills where fine paper is produced from purchased pulp—cotton fiber furnish subdivision]
Pollutant or pollutant property
BODS 	
TSS 	


Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
17.4
24.3
Average of
daily values
for 30 con-
secutive
days
9.1
13.1
Non-contin-
uous dis-
chargers
. (annual
average)
5.1
7.2

-------
     	Federal  Register/Vol. 63, No. 72 / Wednesday,  April 15,  1998/Rules and Regulations      18713

                                              .  SUBPART K—Continued
      [BPT effluent limitations for non-integrated mills where fine paper is produced from purchased pulp—cotton fiber furnish subdivision]
Pollutant or pollutant property
pH 	 	 	 ......... 	 ....... 	 : 	 	 	 	 	
Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
. m
Average of
daily values
for 30 con-
secutive
days
m
Non-contin-
uous dis-
chargers
(annual
average)
f
  1 Within the range of 5.0 to 9.0 at all times.
                                                    -  SUBPART K          ,
               [BPT effluent limitations for non-integrated mills where lightweight papers are produced from .purchased pulp]
•'
Pollutant or pollutant property
BODS 	
TSS 	
PH 	 	 	



Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
24.1
21.6
- P)
Average of
daily values
for 30 con-
secutive
days
13.2
10.6
(i)
Non-contin-
uous dis-
chargers
(annual
average)
7.37
6.0
(
  1 Within the range of 5.0 to 9.0 at all times.

                                      .               ' SUBPART K                  ••••.'      •
     [BPT effluent limitations for non-integrated mills where lightweight papers are produced from purchased pulp— electrical grade papers
                                                       subdivision
Pollutant or pollutant property •
BODS 	 	 	 	 	 	 	 	 	 .
TSS 	 	 	 : 	 	 	 „.. 	 	 	 .„.
pH 	 	 	

Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
38.0
34.2
(1)
Average of
daily Values
for 30 con-
secutive
days
20.9
16.7
(1)
Non-contin-
uous dis-
chargers
(annual
average)
' 11.7
9.5
(.
  1 Within the range of 5.0 to 9.0 at all .times.
§ 430.113  Effluent limitations guidelines
representing the degree of effluent
reduction attainable by the application of
the best conventional pollutant control
technology (BCT).

  Except as provided in 40 CFR 125.30
through 125,32, any existing point
source subject to this subpart shall
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best conventional
pollutant'control technology (BCT): The
limitations shall be the same as those
specified for conventional, pollutants
(which are defined in 40'CFR 401.16) in
§ 430.102 of this subpart for the best
practicable control technology currently
available (BPT).

§430.114 Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best available
technology economically achievable (BAT).

  Except as provided in 40 CFR 125.30
through 125.32, any existing point
source subject to this subpart where
chlorophenolic-containing biocides are
used must achieve the following
effluent limitations representing the
degree of effluent reduction attainable
by the application of the best available
 technology economically achievable
 (BAT)-Non-continuous dischargers
 shall not be subject to the maximum day
 mass limitations in kg/kkg (lb/1000 Ib)
 but shall be subject to concentration
 limitations. Concentration limitations
• are only applicable to non-continuous
 dischargers. Permittees not using
 chlorophenolic-containing biocides
 must certify to the permit-issuing
 authority that they are not using these
 biocides:

-------
 18714       Federal Register/Vol. 63, No.  72/Wednesday, April  15.  1998/Rules and Regulations
                                                      SUBPART K
      [BAT effluent limitations for non-integrated mills where fine paper is produced from purchased pulp—wood fiber furnish subdivision]
Pollutant or pollutant property
Pentachlorophenol 	
Trichlorophenol 	
y a wastewater discharged in


kgal per ton of product
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000 Ib) of
product
0.0018
0.00064
Milligrams/liter
(0.029)(15.2)/y
(0.010)(15.2)/y
                                                     SUBPART K
      [BAT effluent limitations for non-integrated mills where fine paper is produced from purchased pulp—cotton fiber furnish subdivision]
Pollutant or pollutant property
Pentachlorophenol 	
Trichlorophenol 	
y a wastewater discharged


in kgal per ton of product.
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000lb)of
product
0.0051
0.0018
Milligrams/liter
(0.029)(42.3)/y
(0.010)(42.3)/y
                                                     SUBPART K
               [BAT effluent limitations for non-integrated mills where lightweight papers are produced from purchased pulp]
Pollutant or pollutant property
Pontachkjrophenol 	
Trichlorophenol 	
y « wastewater discharged in kgal per ton of product.
Maximum for any 1 day
KgMg (or
pounds per
1,000lb)of
product
0.0059
0.0020
Milligrams/liter
(0.029)(48.7)/y
(0.010)(48.7)/y
                                                     SUBPART K
     [BAT effluent limitations for non-integrated mills where lightweight papers are produced from purchased pulp—electrical grade papers
                                                      subdivision]
Pollutant or pollutant property
Pontachtorophenol 	
Trichlorophenol 	
y a wastewater discharged


in kgal per ton of product.
Maximum for any 1 day
Kg/kkg (or
pounds per
1 ,000 Ib) of
product
0.0093
0.0032
•«*—,
(0.029)(76.9)/y
(0.010)(76.9)/y
{430.115  New source performance standards (NSPS).
    Any new source  subject to  this subpart  must  achieve the following new  source performance standards (NSPS),
except that non-continuous dischargers shall not be subject to the maximum  day and average of 30 consecutive days
effluent limitations for BOD5 and TSS, but shall be subject to annual average effluent limitations. Also, for non-continuous
dischargers, concentration limitations  (mg/1) shall apply,  where provided.  Concentration limitations will only apply to
non-continuous dischargers. Only facilities  where  chlorophenolic-containing  biocides  are  used  shall  be subject  to
Pentachlorophenol and trichlorophenol limitations. Permittees not using chlorophenolic-containing biocides must  certify
to the permit-issuing authority that they are not using  these biocides:

-------
              Federal Register/Vol. 63, No. 72/Wednesday,  Apftt  15, 1998/Rules and Regulations      18715
                                                        SUBPARTK
             [NSPS for non-integrated mills where fine paper is produced from purchased pulp—wood fiber furnish subdivision]
                              Pollutant or pollutant property
                                                                                          Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                      product
                                                                                         Continuous dischargers
                                                                                         Maximum
                                                                                         for any 1
                                                                                           day
     Average of
     daily values
     for 30 con-
      secutive
        days'
     Non-contin-
      uous dis-
      chargers
       (Annual
      average)
BODS
TSS ...
pH  	
3.5
4.4

 P)
1.9
2.3

 0)
1.0
1.2
                                                                                                  Maximum for any 1 day
                                                                                                Kg/kkg (or
                                                                                               pounds per
                                                                                               1,000lb)of
                                                                                                 product
              Milligrams/liter
Pentachlorophenol	
Trichlorophenol	
y=wastewater discharged in kgal per ton at all times.
   0.0018
   0.00064
(0;047)(9.4)/y
(0.016)(9.4)/y
  1 Within the range of 5.0 to 9.0 at all times.


                                                        SUBPART K

             [NSPS for non-integrated mills where fine paper is produced from purchased pulp—cotton fiber furnish subdivision]
Pollutant or pollutant property ,
BOD5 	
TSS 	 	
pH 	





Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
7.8
9.5
0)
Average of
daily values
for 30 con- '
secutive
days
4.2
4.9
. (1)
Non-contin-
uous dis-
chargers
(annual
average)
2.2
2.6
(
• " "
Pentachlorophenol 	 	 	 	 	
Trichlorophenol 	 	 	 	 	 	 	 -; 	
y = wastewater discharged in kgal per ton at all times.
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000lb)of
product
0.0051
0.0018
Milligrams/liter
(0.039)(31.1)/y
(0.014)(31.1)/y'
  1 Within the range of 5.0 to 9.0 ,at all times.
                                     .:.-.-       SUBPART K
                      [NSPS for non-integrated mills where lightweight papers are produced from purchased pulp]
Pollutant or pollutant property
BODS 	 	 	 	
TSS 	 	 	 	 	 	 	
PH 	 	 	 	 	 ; 	

Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
13.7
12.0
n
Average of
daily values
for 30 con-
secutive
days
6.7
5.2
(1)
Non-contin-
uous dis-
chargers
(annual
average)
4.5
3.2
(

-------
 18716       Federal Register/Vol. 63,  No. 72/Wednesday,  April 15,  1998/Rules and Regulations

Pantachlorophenol 	 '. 	 	 	
Triohtorophenol 	
y • wastewater discharged in kgal per ton at all times.
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000 Ib) of
product
0.0059
0.0020
Milligrams/liter
(0.037)(38.2)/y
(0.013)(38.2)/y
  ' Within the range of 5.0 to 9.0 at all times.
                                                      SUBPART K                               •
       [NSPS for non-integrated mills where lightweight papers are produced from purchased pulp—electrical grade papers subdivision]
Pollutant or pollutant property
BODS 	
TSS 	
pH 	


.


Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
24.1
21.1
(1)
Average of
daily values
for 30 con-
secutive
days
11.7
9.2
. (i)
Non-contin-
uous dis-
chargers
(annual
average)
7.9
5.6
(

Pentachtorophenol 	 : 	
Trtchlorophenol 	
y a wastewater discharged in kgal per ton at all times.
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000lb)of
product
0.0093
• 0.0032
Milligrams/liter
(0.033)(66.8)/y
(0.012)(66.8)/y
  1 Within the range of 5.0 to 9.0 at all times.
§430.116  Pretreatment standards for existing sources (PSES).
    Except as provided in 40 CFR 403.7 and 403.13, any existing source subject to this subpart that introduces pollutants
into a publicly owned  treatment works must: comply with 40 CFR part 403; and achieve the following pretreatment
standards for existing sources (PSES) if it uses chlorophenolic-containing biocides.  Permittees not' using chlorophenolic-
containing biocides  must  certify to the permit-issuing authority that they  are not using these biocides. PSES  must
be attained on or before July 1, 1984:

                                                      SUBPART K
             [PSES for non-integrated mills where fine paper is produced from purchased pulp—wood fiber furnish subdivision]

Pollutant or pollutant property
Penlachtorophenol 	 	 	
Trtchlorophenol 	
y « wastewater discharged in kgal per ton of product.
Maximum for any 1
Milligrams/liter (mg/l)
(0 032)(15 2)/y
(0 010)(15 2)/y

day
Kg/kkg (or
pounds per
1,000lb)of
product"
0 0020
n nnnfid.

  »The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.                                                       •

                                                      SUBPART K
             [PSES for non-integrated mills where fine paper is produced from purchased pulp—cotton fiber furnish subdivision]
Pollutant or pollutant property
Pentachtorophenol 	 	 	
Maximum for any 1 day
Milligrams/liter (mg/l)
(0.032)(42.3)/v 	
Kg/kkg (or
pounds per
1,000lb)of
product0
0.0056

-------
              Federal Register/Vol. 63, No. 72/Wednesday,  April  15,  1998/Rules and Regulations
18717
                                                 SUBPART K—Continued
              [PSES for non-integrated mills where fine paper is produced from purchased pulp—cotton fiber furnish subdivision]
• Pollutant or pollutant property
Trichlorophenol 	
y = wastewater discharged

in kgal per ton of product.
Maximum for any 1 day
Milligrams/liter (mg/l)
(0.010)(42.3)/v ...

Kg/kkg (or
pounds per
1,000lb)of
product3
'. 0.0018
   "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
 tions.                     ,                            ;                '               .•'-••                .

                                                       SUBPART K
                       [PSES for non-integrated mills where lightweight papers are produced from purchased pulp]            '     •     '
»
Pentachlorophenol 	
Trichlorophefiol 	
y = wastewater discharged
Pollutant or pollutant property


in kgal per tori of product.
.Milligrams/liter (mg/l)
(0 032M48 7)/v
(0010H487W

Kg/kkg (or
pounds per
1,000lb)of
product a
0 0065
00032

                                                                                             Maximum for any 1 day
   "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
' tions.       .                .'   •   .    v   •             •     •  '

                                                       SUBPARTK                                 •
                                               •                           •                •                            i
        [PSES for non-integrated mills where lightweight papers are produced from purchased pulp—electrical grade papers subdivision]

Pentachlorophenol 	
Trichlorophenol 	 	 	
y =' wastewater discharged in kgal
Pollutant or pollutant property


per ton of product.
Milligrams/liter (mg/l)
(6.032)(76.9)/y 	 	 	
(0 010K76 9)/v

Kg/kkg (or -
pounds per
1,000lb)of
product*
0.010
0 0032

                                                                                            Maximum for any 1 day
   "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
 tions.
 §430.117  Pretreatment standards for new sources (PSNS).
     Except as  provided in 40  CFR 403.7, any new source  subject to this Subpart that  introduces  pollutants into a
 publicly owned treatment  works must: comply  with  40 CFR part 403;  and achieve the following pretreatment standards
 for new sources  (PSNS)  if it uses chlorophenolic-containing biocides. Permittees not using chlorophenolic-containing
 biocides must certify to the permit-issuing authority that they are not using these biocides:

                                                       SUBPARTK
              [PSNS for non-integrated mills where fine paper is produced from purchased pulp—wood fiber furnish subdivision]

Pentachlorophenol 	 ...
Trichlorophenol 	
y = wastewater discharged
Pollutant or pollutant property -


in kgal per ton of product.
Milligrams/liter (mg/l)
(0 052)(9 4)/y
(0016M94W

Kg/kkg (or
pounds per
1,000lb)of
product »
0 0020
0 0064

                                                                                            Maximum for any 1 day
   aThe following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
 tions.          •                                                                                            ,

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 18718      Federal Register/Vol.  63,  No. 72/Wednesday, April  15,  1998/Rules and Regulations
                                                      SUBPART K
              [PSNS for non-integrated mills where fine paper is produced from purchased pulp—cotton fiber furnish subdivision]
Pollutant or pollutant property ,
Pentachlorophenol 	
Trichloropheno! 	
y a wastewater discharged


in kgal per ton of product.
Maximum for any 1 day
Milligrams/liter (mg/l)
(0 044V31 1 Vu •
(0 014M31 1W

Kg/kkg (or
pounds per
1,000 Ib) of
product »
0.0056
0.0018
       fo"owlng e<1uivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
                                                      SUBPART K
                       [PSNS for non-integrated mills where lightweight papers are produced from purchased pulp]
Pollutant or pollutant property
Pentachlorophenol 	
TricWorophenol 	
y s wastewater discharged


in kgal per ton of product.
Maximum for any 1 day
Milligrams/liter (mg/l)
in nd.iu^tR y\i\i
tnM ww y\i\i

Kg/kkg (or
pounds per
1,000lb)of
product3
0.0065
0.0020
  •The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-


                                                      SUBPART K
       [PSNS for non-integrated mills where lightweight papers are produced from purchased pulp—electrical grade papers subdivision]
Pollutant or pollutant property
Pentachlorophenol 	
Trichlorophenol 	
y m wastewater discharged


in kgal per ton of product.
Maximum for any 1 day
Milligrams/liter (mg/l)
(0 037) (66 8)/y
ICt fl1 PURR RVu

Kg/kkg (or
pounds per
1,000lb)of
product a
0.010
0.0032
  *The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
Subpart L—Tissue, Filter, Non-Woven,
and Paperboard From Purchased Pulp
Subcategory

§430.120  Applicability; description of the
tissue, filter, non-woven, and paperboard
from purchased pulp suhcategory.
  The provisions of this subpart are
applicable to discharges resulting from
the production of tissue papers at non-
integrated mills, filter and non-woven
papers at non-integrated mills, and
paperboard at non-integrated mills. The
production of electrical grades of board
and matrix board is not included in this
subpart.
§430.121  Specialized definitions.
  For the purpose of this subpart, the
general definitions, abbreviations, and
methods of analysis set forth in 40 CFR
part 401 and §430.01 of this part shall
apply to this subpart.

§ 430.122  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best practicable
control technology currently available
(BPT).
  Except as provided in 40 CFR 125.30
through 125.32, any existing point
source subject to this subpart must
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best practicable
control technology currently aivailable
(BPT), except that non-continuous
dischargers shall not be subject to the
maximum day and average of 30
consecutive days limitations but shall
be subject to annual average effluent
limitations:

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              Federal Register/Vol. 63.  No. 72/Wednesday, April  15, 1998/Rules and Regulations       18719
                                                       SUBPART L                          .
                  [BPT effluent limitations for non-integrated mills where tissue papers are produced from purchased pulp]
Pollutant or pollutant property • • .
BODS 	 	 	 	 	 i 	
TSS 	 	 	 ..
PH 	 ,. 	
Kg/kkg (or pounds per 1,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
11.4
10.25
0)
Average of
daily values
for 30 con-
secutive
days
6.25
5.0
P)
Non-contin-
uous dis-
chargers
(annual
average)
3.49
2.84
(
  1 Within the range of 5.0 to 9.0 at all times.

                                 .                   .  SUBPART L
            [BPT effluent limitations for non-integrated mills where filter and non-woven papers are produced from-purchased pulp]
Pollutant or pollutant property
BODS 	 	 	 	 	 	 	
TSS 	 ..„ 	 	 	
pH 	 ;....: 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous dischargers
Maximum
for any 1
day
29.6
26.6
(1)
Average of
daily values
for 30 con-
secutive
•days
16.3
13.0
(1)
Non-contin-
uous dis-
, chargers
(annual
average)
9.1
7.4
(
  1 Within the range of 5.0 to 9.0 at all times.
                             •                       ,SUBPART L
                   [BPT effluent limitations for non-integrated mills where paperboard is produced from purchased pulp]
Pollutant or pollutant property
BODS 	 	 	 	 	 	 	 	 	
TSS 	 	 	 	
pH 	 	 	 .'. 	 	 	 	 	 	 	
Kg/kkg (or pounds per 1 ,000 Ib) of
product
Continuous
dischargers
6.5
5.8
(1)
Non-continuous discharg-
ers (Annual average)
Maximum
for any 1
day
3.6
2.8
(1)
Average of
daily values
for 30 con-
secutive
days
2.0
1.6
(
  1 Within the range of 5.0 to 9.0 at all times.
§430.123  Effluent limitations guidelines
representing the degree of effluent
reduction attainable by the application of
the best conventional pollutant control
technology (BCT).
  Except as provided in 40 CFR 125.30
through 125.32, any existing point
source subject to this subpart shall
achieve the following effluent
limitations representing the degree of
effluent reduction attainable by the
application of the best conventional
pollutant control technology (BCT): The
limitations shall be the same as those  .
specified for conventional pollutants
(which are defined in 40 CFR 401.16) in
§430.122 of this subpart for the best
practicable control technology currently
available (BPT). •

§ 430.124  Effluent limitations representing
the degree of effluent reduction attainable
by the application of the best available
technology economically achievable (BAT).
 ' Except as provided in 40 CFR 125.30
through 125.32, any existing point
source subject to this subpart where
chlorophenolic-containing biocides are
used must achieve the following
effluent limitations representing the
 degree of effluent reduction attainable
 by the application of the best available
 technology economically achievable
 (BAT). Non-continuous dischargers
 shall not be subject to the maximum day
 mass limitations in kg/kkg (lb/1000 Ib)
 but shall be subject to concentration
. limitations. Concentration limitations
 are only applicable to non-continuous
 dischargers. Permittees not using-
 chlorophenolic-containing biocides
 must certify to the permit-issuing
 authority that they are not using these
 bibcides:

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18720
Federal Register/Vol. 63, No. 72/Wednesday, April  15,  1998/Rules and  Regulations
                                                     SUBPART L
                 [BAT effluent limitations for non-integrated mills where tissue papers are produced from purchased pulp]

Pentachtorophenol 	 	 	
Trlchlorophenol 	
y m wastewater discharged in kgal
Pollutant or pollutant property


per ton of product.
Kg/kkg (or
pounds per
1,000lb)of
product
0.0028
0.00096

Milligrams/liter
(0.029)(22.9)/y
(0.010)(22.9Vv

                                                                                             Maximum for any 1 day
                                                     SUBPART L
           [BAT effluent limitations for non-integrated mills where filter and non-woven papers are produced from purchased pulp]
Pollutant or pollutant property
Pentachlorophenol 	 	 	 -. 	 .'.....
Trichlorophenol 	 .•. 	
y = wastewater discharged in kgal per ton of product.
Kg/kkg (or
pounds per
1,000lb)of
product
Oi0072
00025

Milligrams/liter
(0.029)(59.9)/y
(0 01 OU59 9Vv

                                                                                             Maximum for any 1 day
                                                     SUBPART L
                  [BAT effluent limitations for non-integrated mills where paperboard is produced from purchased pulp]

Pentachlorophenol 	
Trichlorophenol 	
y = wastewater discharged in
Pollutant or pollutant property


kgal per ton of product.
Kg/kkg (or
pounds per
1,000lb)of
product
0.0016
0.00054

Milligrams/liter
(0.029X1 2.9)/y
(0.010)(l2.9)/y

                                                                                             Maximum for any 1 day
§430.125  New source performance
standards (NSPS).
  Any new source subject to this
subpart must achieve the following new
source performance standards (NSPS),
except that non-continuous dischargers
shall not be subject to the maximum day
and average of 30 consecutive days
                           effluent limitations for BODS and TSS,
                           but shall be subject to annual average
                           effluent limitations. Also, for non-
                           continuous dischargers, concentration
                           limitations (mg/1) shall apply, where
                           provided. Concentration limitations will
                           only apply to non-continuous
                           dischargers. Only facilities where
chlorophenolic-containing biocides are
used shall be subject to
pentachlorophenol and trichlorophenol
limitations. Permittees not using
chlorophenolic-containing biocides
must certify to the perjnit-issuing
authority that they are not using these
biocides:
                                                     SUBPART L
                        [NSPS for non-integrated mills where tissue papers are produced from purchased pulp]
Pollutant or pollutant property
BODS 	 	 	 .....
TSS 	
pH 	





Continuous dischargers
Maximum
for any 1
day
7.0
6.0.
(1)
Average of
daily values
for 30 con-
secutive
days
3.4
2.6
(1)
Non-contin-
uous dis-
chargers
(annual
average)
2.3
1.6
(
                                                                                      Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                product

-------
             Federal Register/Vol. 63. No. 72 /Wednesday. April 15, 1998/Rules and Regulations       18721
' \
Pentachlorophenol 	 	 	 	 	 	 	 	 	 . 	
Trichlorophenol 	 	 	 	 	 	 	
y = wastewater discharged in kgal per ton at all times.
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000lb)of
product
0.0028
0.00096
Milligrams/liter
(0.035)(19.1)/y
(0.01 2)(1 9.1 )/y
  1 Within the range of 5.0 to 9.0 at all times.
                                                     SUBPART L . .
                  [NSPS for non-integrated mills where filter and non-woven papers are produced from purchased pulp]

                                                                                      Kg/kkg (or pounds per 1,000 Ib) of
                                                                                                 product
Pollutant or pollutant property
BODS 	 	 	 ...:. 	 	 	 	 	 	 	
TSS 	 	 	 	 	 	 	 	 	 	 	
pH : 	 	 	 	 	

Continuous dischargers
Maximum
for any 1
day
17.1
15.0
•P)
• ' •'' . ' •
Pentachlorophenol 	 	 	 	
Trichlorophenol 	 	 	 •„...-. ..
y = wastewater discharged in kgal per ton at all times.
Average of
daily values
for 30 con-
secutive
days
8.3
6.6
0)
Non-contin-
uous dis-
chargers
(annual
average)
5.6
4.0
(
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000lb)of
product
0.0072
0.0025
Milligrams/liter
(0.037)(47,5)/y
(0.013)(47.5)/y
  ' Within the range of 5.0 to 9.0 at all times.
                                                     SUBPART L
                        • [NSPS for non-integrated mills where paperboard is produced from purchased pulp]
r • . ' '
Pollutant or pollutant property
BODS 	 	 ....; 	 '. 	 .'. 	 „.„ 	 , 	 	 	 „..„..„ 	
TSS 	 	 	 „.. 	 	 	 	 	 	 . .
pH 	 : 	 : 	 	 	 	 	 : 	

Kg/kkg (or pounds per 1,000,lb) of
product
Continuous dischargers
Maximum
for any 1
day
4.0
3.5
0)
Average of
daily values
for 30 con-
secutive
days
1.9
1.5
(i)
Non-contin-
uous dis-
chargers
(annual
average)
1.3
0.9
(
' ' .
Pentachlorophenol 	 	 	 	 	 	 	 .., 	 	 	 	 	 	 	 : 	 	 	
Trichlorophenol 	 	 	 	 	 	 	 	 	
y = wastewater discharged in kgal per ton at all times.
Maximum for any 1 day
Kg/kkg (or
pounds per
1,000lb)of
product
0.0016
0.00054
Milligrams/liter
(0.033)(11.2)/y
(0.012)(11.2)/y
  [0 Within the range of 5.0 to 9.0 at all times.

§430.126 Pretreatment standards for existing sources (PSES)l                                                  ,
    Except as prqvided in 40 CFR'403.7 and 403.13, any existing source'subject to this subpart that introduces pollutants
into a publicly owned treatment works must: comply with  40 CFR part 403; and  achieve the following pretreatment
standards for existing sources (PSES) if it uses chlorophenolic-containing biocides. Permittees not using chlorophenolic-

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18722      Federal Register/Vol. 63, No. 72/Wednesday,  April 15,  1998/Rules  and  Regulations
containing  biocides  must certify to the  permit-issuing  authority  that  they are not using  these biocides.  PSES must
be attained  on or before July 1, 1984:

                                                      SUBPARTL
                        [PSES for non-integrated mills where tissue papers are produced from purchased pulp]

Psntachlorophenol 	
Trichlorophenol 	
y = wastewater discharged in kgal
Pollutant or pollutant property


per ton of product.
Milligrams/liter (mg/1)
(0.032)(22.9W .
(0010M229W

Kg/kkg (or
pounds per
1,000lb)of
product3
00031
0 00096

                                                                                           Maximum for any 1 day
  «The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions,

                                                      SUBPART L
                  [PSES for non-integrated mills where filter and non-woven papers are produced from purchased pulp]

Psntachlorophenol 	
Trtchlorophonol 	
y « wastewater discharged
Pollutant or pollutant property


in kgal per ton of product.
Milligrams/liter (mg/l)
(0 032H59 9)/V
(0010M599W

Kg/kkg (or
pounds per
1,000 Ib) of
product3
00080
00025

                                                                                           Maximum for any 1 day
  •The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.

                                                      SUBPART L
                          [PSES for non-integrated mills where paperboard is produced from purchased pulp]
Pollutant or pollutant property
Pontachlorophonol 	
Trichlorophenol


y = wastewater discharged in kgal per ton of product.
Milligrams/liter (mg/l)
(0 032)(12 9)/y
(0.010)(129)/v

Kg/kkg (or
pounds per
1,000lb)of
product3
0.0017
0.00054
                                                                                           Maximum for any 1 day
  •The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.                                                  :
§430.127  Protreatment standards for new sources (PSNS).
    Except as  provided in 40  CFR 403.7,  any  new source subject to this subpart  that  introduces  pollutants  into  a
publicly owned treatment works must: comply with  40  CFR part 403; and achieve the following pretreatment standards
for new sources  (PSNS) if it uses chlorophenolic-containing biocides. •Permittees not using chlorophenolic-containing
biocides must certify to the permit-issuing authority that they are not using these biocides:                        .

                                                      SUBPART L
                        [PSNS for non-integrated mills where tissue papers are produced from purchased pulp]
Pollutant or pollutant property
Pentachlorophenol 	
Trichlorophenol 	
y = wastewater discharged


in kgai per ton of product.
Maximum for any 1 day
Milligrams/liter (mg/l)
(0038)(19 1)/y
(0012)(19 1)/y

Kg/kkg (or
pounds per
1,000lb)of
product3
0.0031
0.00096
  •The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
tions.

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                Federal Register/Vol.  63, No. 72/Wednesday, April 15,  1998/Rules  and Regulations       18723
                                                         .  SUBPART L
                     [PSNS for non-integrated mills Where filter and non-woven papers are* produced from purchased pulp]
Pollutant or pollutant property
Pentachlorophenol 	 .-. 	 	 .
Trichlorophenol 	 ,. 	 	 	 	 	
y = wastewater discharged in kgal per ton of product. .
Maximum for any 1 day
Milligrams/liter (mg/i)
1C] 040U47 *T\fv
(0 013W47 5Vv

Kg/kkg (or
pounds per
1,000 Ib) of
product"
0.0080
0.0025
   "The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to impose mass effluent limita-
 tions.
                                               .            SUBPART L
                            [PSNS for non-integrated mills where paperboard is produced from purchased pulp]
Pollutant or pollutant property '
Pentachlorophenol 	
Trichlorophenol 	
y = wastewater discharged in kgal


per ton of product.
Maximum for any 1 day
Milligrams/liter (mg/l)
(0 037)(1 1 2)/y
(0 012)(11 2)/y

Kg/kkg (or
pounds per
1,000lb)of
product"
0.0017
0.00054
   "The following equivalent mass limitations are provided as guidance in cases when POTWs find It necessary to impose mass effluent limita-
 tions.                                                                          •                      ,
 Appendix A to Part 430—Methods 1650
 and 1653

 Method 1650—Adsorbable Organic Halides
 by Adsorption and Coulometric Titration

 1.0  Scope and Application
   1.1  This method is for determination of
 adsorbable organic halides (AOX) associated,
 with the Clean Water Act; the Resource
 Conservation and Recovery Act; the
 Comprehensive Environmental Response,
 Compensation, and Liability Act; and other
 organic halides amenable to combustion and
 coulometric titration. The method is
 designed to meet the survey and monitoring
 requirements of the Environmental
 Protection Agency (EPA).
   1.2  The method is applicable to the
 determination of AOX in water and
 wastewater. This method is a combination of
 several existing methods for organic halide
 measurements (References 1 through 7).
   1.3-  The method can be used to measure
 organically-bound halides (chlorine,
 bromine, iodine)  present in dissolved or
 suspended form.  Results are reported as
' organic chloride  (C1-). The detection limit of
' the method is usually dependent on
 interferences rather than instrumental
 limitations. A method detection limit (MDL;
 Reference 8) of 6.6 (ig/L, and a minimum
 level (ML; Section 18) of 20 ug/L, can be
 achieved with no interferences present.
   1.4  This method is for use by or under the
 supervision of analysts experienced, in the
 use of a combustion/micro-coulometer. Each
 laboratory that uses this method must
 demonstrate the ability to generate acceptable
.results using the procedures described in
 Section 9.2.
   1.5  Any modification Of the method
beyond those expressly permitted (Section
9.1.2) is subject to application and approval
of an alternate test procedure under 40 CFR '
136.4 and 136.5.

2.0  Summary of Method
  2.1  Sample preservation: Residual
chlorine that may be present is removed by
the addition of sodium thiosulfate. Samples
are adjusted to a pH < 2 and maintained at
0 to 4°C until analysis.
  2.2  Sample analysis: Organic halide in
water is determined by adsorption onto
granular activated carbon (GAC). washing the
adsorbed sample and GAC to remove
inorganic halide, combustion of the sample
and GAC to form the hydrogen halide, and
titration of the hydrogen halide with a micro-
coulometer, as shown in Figure 1.
  2.3  Micro-coulometer.
  2.3.1  This detector operates by
maintaining a constant silver-ion
concentration in a titration cell. An electric
potential is applied to a solid silver electrode
to produce silver ions in the cell. As
hydrogen halide produced from the
combustion of organic halide enters  the cell,.
it is partitioned into an acetic acid electrolyte"
where it precipitates as silver halide. The
current produced is integrated over the
combustion period. The electric charge is
proportional to the number of moles of
halogen captured in the cell (Reference 6).
.  2.3.2  The mass concentration of organic
halides is reported as an equivalent
concentration of organically bound chloride
(ci-).

3.0  Definitions  •
  3.1  Adsorbable organic halides is denned
as the analyte measured by this method. The.
nature of the organo-halides and the presence
of semi-extractable material will influence
the amount measured and interpretation of
results.
  3.2 Definitions for terms used in this
method are given in the glossary at the end
of the method (Section 18).

4.0  Interferences
  4.1 Solvents, reagents, glassware, and
other sample processing hardware may yield
elevated readings from the micro-coulometer.
All materials used in the analysis shall be
demonstrated to be free from interferences
under the conditions of analysis by running
method blanks initially and with each
sample batch (samples started through the
adsorption process in a given eight-hour
shift, to a maximum of 20 samples). Specific
selection of reagents and purification of
solvents may be required.
  4.2 Glassware is cleaned by detergent
washing in hot water, rinsing with tap water
and distilled water, capping with aluminum
foil, and baking at 450°C for at least one hour.
For some glassware, immersion in a chromate
cleaning solution prior to detergent washing
may be required. If blanks from glassware
without cleaning or with fewer cleaning steps
show no detectable organic halide, the
cleaning steps that do not eliminate organic
halide may be omitted.
  4.3 Most often, contamination results
from methylene chloride vapors in
laboratories that perform organic extractions.
Heating, ventilating, and air conditioning
systems that are shared between the
extraction laboratory and the laboratory in
which organic halide measurements are
performed transfer the methylene chloride
vapors to the air in the organic halide
laboratory. Exposure of the activated carbon

-------
 18724       Federal Register/Vol.  63, No. 72/Wednesday,  April  15, 1998/Rules and Regulations
used in the analysis results in contamination.
Separate air handling systems, charcoal
filters, and glove boxes can be used to
minimize this exposure.
  4.4  Activated carbon.
  4.4.1  The purity of each lot of activated
carbon must be verified before each use by
measuring the adsorption capacity and the
background level of halogen (Section 9.5).
The stock of activated carbon should be
stored in its granular form in a glass
container that is capped tightly. Protect
carbon at all times from sources of halogen
vapors.
  4.4.2  Inorganic substances such as
chloride, chlorite, bromide, and iodide will
adsorb on activated carbon to an extent
dependent on their original concentration in
the aqueous solution and the volume of
sample adsorbed. Treating the activated
carbon with a solution of nitrate causes
competitive desorption of inorganic halide
species. However, if the inorganic halide
concentration is greater than 2,000 times the
organic halide concentration, artificially high
results may be obtained.
  4.4.3 Halogenated organic compounds
that are weakly adsorbed on activated carbon
are only partially recovered from the sample.
These include certain alcohols and acids
such as chloroethanol  and chloroacetic acid
that can be removed from activated carbon by
the nitrate wash.
  4.5  Polyethylene gloves should be worn
when handling equipment surfaces in contact
with the sample to prevent transfer of
contaminants that may be present on the
hands.

5.0  Safety
  5.1  The toxicity or carcinogenicity of
each reagent used in this method has not
been precisely determined; however,  each
chemical substance should be treated as a
potential health hazard. Exposure to these
substances should be reduced to the lowest
possible level. The laboratory is responsible
for maintaining a current awareness file of
OSHA regulations regarding the safe
handling of the chemicals specified in this
method. A reference file of material safety
data sheets (MSDSs) should be made
available to all personnel involved in the
chemical analysis. Additional information on
laboratory safely can be found in References
9 through 11.
  5,2  This method employs strong acids.
Appropriate clothing, gloves, and eye
protection should be worn when handling
these substances.
  5.3  Field samples may contain high
concentrations of toxic volatile compounds.
Sample containers should be opened in a
hood and handled with gloves that will
prevent exposure.

6.0  Equipment and Supplies
  Note: Brand names, suppliers, and part
numbers are for illustrative purposes only. •
No endorsement is implied. Equivalent
performance may be achieved using
apparatus and materials other than those
specified here, but demonstration of
equivalent performance that meets  the
requirements of this mediod is the
responsibility of the laboratory.
  6.1  Sampling equipment.
  6.1.1  Bottles: 100- to 4000-mL, amber
glass, sufficient for all testing (Section 8.2).
Detergent water wash, chromic acid rinse,
rinse with tap and distilled water, cover with
aluminum foil, and heat to 450°C for at least
one hour before use.
  6.1.2  PTFE liner: Cleaned as above and
baked at 100 to 200°C for at least one hour.
  6.1.3  Bottles and liners must be lot
certified to be free of organic halide by
running blanks according to this method.
  6.2  Scoop for granular activated carbon
(GAC): Capable of precisely measuring 40 mg
(±5 mg) GAC .(Dohrmann Measuring Cup
521-021, or equivalent).
  6.3  Batch adsorption and filtration
system.
  6.3.1  Adsorption system: Rotary shaker,
wrist action shaker, ultrasonic system, or
other system for assuring thorough contact of'
sample with activated carbon. Systems
different from the one described below must
be demonstrated to meet the performance
requirements in Section 9 of this method.
  6.3.1.1  Erlenmeyer flasks: 250- to 1500-
mL with ground-glass stopper, for use with
rotary shaker.
  6.3.1.2  Shake table: Sybron Thermolyne
Model LE "Big Bill" rotator/shaker, or  ,
equivalent.
  6.3.1.3  Rack attached to shake table to
permit agitation of 16 to 25 samples
simultaneously.
  6.3.2  Filtration system (Figure 2).
  6.3.2.1  Vacuum filter holder: Glass, with
fritted-glass support (Fisher Model 09-753E,
or equivalent).
  6.3.2.2  Polycarbonate filter: 0.40 to 0.45
micron, 25-mm diameter (Micro Separations
Inc, Model K04CP02500, or equivalent).
  6.3.2.3  Filter forceps: Fisher Model 09-
753-50, or equivalent, for handling filters.
Two forceps may better  aid in handling
filters. Clean by washing with detergent and
water, rinsing with tap and deionized water,
and air diying on aluminum foil.
  6.3.2.4  Vacuum flask: 500- to 1500-mL
(Fisher 10-1800, or equivalent).
  6.3.2.5  Vacuum Source: A pressure/
vacuum pump, rotary vacuum pump, or
other vacuum source capable of providing at
least 610 mm (24 in.) Hg vacuum at 30 L/min
free air displacement.
  6.3.2.6  Stopper and tubing to mate the
filter holder to the flask  and the flask to the
pump.
  6.3.2.7 ,  Polyethylene gloves: (Fisher 11-
394-110-B, or equivalent).
  6.4 Column adsorption system.
  6.4.1  Adsorption module: Dohrmann AD-
2, Mitsubishi TXA-2, or equivalent with
pressurized sample and  nitrate-wash
reservoirs, adsorption columns, column
housings, gas  and gas pressure regulators,
and receiving vessels. For each sample
reservoir, there are two adsorption columns
connected in series. A small steel funnel for
filling the columns and a rod for pushing out
the carbon are also required. A schematic of
the column adsorption system is shown in
Figures.  ,
  6.4.2  Adsorption columns: Pyrex, 5 ± 0.2
cm long x 2 mm ID, to hold 40 mg of granular
activated carbon (GAC).
  6.4.3  Cerafelt: Johns-Manville, or
equivalent formed into plugs using stainless
steel borer (2 mm ID) with ejection rod
(available from Dohrmann or Mitsubishi) to
hold 40 mg of granular activated carbon
(GAC). Caution: Handle Cerafelt with gloves.
  6.4.4   Column holders: To support
adsorption columns.
  6.5 .Combustion/micro-coulometer
system: Commercially available as a single
unit or assembled from parts. At the time of
the writing of this method, organic halide
units were commercially available from the
Dohrmann Division of Rosemount Analytical,
Santa Clara, California; Euroglas BV, Delft,
the Netherlands; and Mitsubishi Chemical
Industries, Ltd., Tokyo, Japan.
  6.5.1   Combustion system: Older systems
may not have all of the features shown in
Figure 4. These older systems may be used
provided the performance requirements
(Section 9) of this method are met.
  6.5.1.1  Combustion tube: Quartz, capable
of being heated to 800 to 1000 °C and
accommodating a boat sampler. The tube
must contain an air lock for introduction of
a combustion boat, connections for purge and
combustion gas, and connection to the micro-
coulometer cell.
  6.5.1.2 Tube furnace capable of
controlling combustion tube in the range of
800 to 1000 °C.
  6.5.1.3 Boat sampler: Capable of holding
35 to 45 mg of activated carbon and a
polycarbonate filter,  and fitting into the
combustion tube (Section 6.5.1.1), Some -
manufacturers offer an enlarged boat and
combustion tube for this purpose.  Under a
time-controlled sequence, the boat is first
moved into an evaporation zone where water
and other volatiles are evaporated, and then
into the combustion zone where the carbon
and all other organic material in the boat are
burned in a flowing oxygen stream. The
evolved gases are transported by a non-
reactive carrier gas to the micro-coulometer
cell.
  6.5.1.4 Motor driven boat sampler:
Capable of advancing the combustion boat
into the furnace in a reproducible time
sequence. A suggested time sequence is as
follows:
  A. Establish initial gas flow rates: 160 mL/
min CO2; 40 mL/min O2.
  B. Sequence start.
  C. Hold boat in hatch for five seconds to
allow integration for baseline subtraction.
  D. Advance boat into vaporization^zone.
  E. Hold boat in vaporization zone for 110
seconds.
  F. Establish gas flow rates for combustion:
200 mL/min 02; 0 mL/min CC>2; advance boat
into pyrolysis zone (800°C).
  G. Hold boat in pyrolysis zone for six
minutes.
  H. Return gas flow rates to initial yalues;
retract boat into  hatch to cool and  to allow
remaining HX to be swept into  detector
(approximately two minutes).
  I. Stop integration at 10 minutes after
sequence start.
  Note: If the signal from the detector does
not return to baseline, it may be necessary to
extend the pyrolysis time.The sequence
above may need to be optimized for each
instrument.                      •
  6.5.1.5 Absorber: Containing sulfuric acid
to dry the gas stream after combustion to

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                Federal Register/Vol.  63, No.  72/Wednesday. April  15, 1998/Rules  and Regulations       18725
  prevent backflush of electrolyte is highly
  recommended.
    6.5.2  Micro-coulometer system: Capable
  of detecting the equivalent of 0.2 ng of Cl~
  at a signal-to-noise ratio of 2; capable of
  detecting the equivalent of 1 ng of Cl~ with
  a relative standard deviation less than 10%,
  and capable of accumulating a minimum of
  the equivalent of 500 (ig of Cl~ before a
  change of electrolyte is required.
    6.'5.2.1  Mic'ro-coulometer cell: The three
  cell designs presently in use are shown in
  Figure 1. Cell operation is described in
  Section 2.          ,                     .
    6.5.2.2  Cell controller": Electronics  .
  capable of measuring the small currents
  generated in the cell and accumulating and
  displaying the charge produced by hydrogen
  halides entering the cell. A strip-chart
  recorder is desirable for display of
  accumulated  charge.
   .6.6  Miscellaneous glassware: nominal
  sizes are specified, below; other sizes may be
  used, as necessary!
   6.6.1  Volumetric flasks: 5-, 10-, 25-, 50-,
 '100-, and 1000-mL.
   6.6.2  Beakers: 100-.500-, and 1000-mL.
   6.6.3  Volumetric pipets: 1- and'10-rnL
  with pipet bulbs.
   6.6.4  Volumetric micro-pipets: 10- 20-,
  50-, 100-, 200-, and 500-[iL with pipet control
  (Hamilton 0010, or equivalent).
   6.6.5  Graduated cylinders: 10-, 100-, and
  1000-mL.   ,
••  6.7  Micro-syringes:  10-, 50-, and 100-nL.
   6.8  Balances.
   6.8.1  Top-loading, capable of weighing
  0.1 g.  .                            '
   6.8.2  Analytical, capable of weighing 0.1
  mg.                    .           (
   6.9  pH meter.
   6.10 Wash bottles: 500- to 1000-mL, PTFE
  or polyethylene.
   6.11 Strip-chart recorder: suggested but
  not required—useful for determining end of
  integration (Section 11.4.2).

  7.0  Reagents and Standards
   7.1   Granular activated carbon (GAG): 75
 to 150 ym (100 to 200 mesh); (Dohrmann,
 Mitsubishi, Carbon Plus, or equivalent), with
 chlorine content less than 1 (ig Cl~ per scoop
  (< 25 [ig Cl~ per gram),  adsorption capacity
 greater than 1000 ng Cl~ (as 2,4,6-
 trichlorophenol) per scoop (i-25,000|ag/g),
 inorganic halide retention of less than 1 (ig
 Cl- per scoop in the presence of 10 mg of
 inorganic halide (< 20 ng Cl~ per gram in the
 presence of 2500 mg of  inorganic halide), and
 that meets the other test criteria in this
 method.
   7.2  Reagent water: Water in which
 organic halide is not detected by this method.
   7.2.1  Preparation: Reagent water may be
 generated by:
  1 7.2.1.1   Activated carbon: Pass tap water
 through a carbon bed (Calgon Filtrasorb-300,
 or equivalent).
   7.2.1.2   Water purifier: Pass tap water
 through a purifier (Millipore Super Q, or
 equivalent).                             :
   7.2.2  pH adjustment: Adjust the pH of the
 reagent water to < 2 with nitric acid for all
 reagent water used in this method, except for
 the acetic acid solution  (Section 7.13).
   7.3  Nitric acid (HNO3): Concentrated,
 analytical grade.
   7.4  Sodium chloride (NaCl) solution (100
 Hg/mL of C1-): Dissolve 0.165g NaCl in 1000
 mL reagent water. This solution is used for
 cell testing and for the inorganic halide
 rejection test.
   7.5  Ammonium chloride (NHtCl) solution
 (100  n.g/mLof C1-): Dissolve 0.1509 gNtttCl
 in 1000 mL reagent water.
   7.6  Sulfuric acid: Reagent grade (specific
 gravity 1.84).
   7.7  Oxygen: 99.9% purity.
   7.8  Carbon Dioxide: 99.9% purity.
   7.9  Nitrate stock solution: In a 1000-mL
 volumetric flask, dissolve 17g of NaNOs in,
 approximately 100 mL of reagent water, add
 1.4 mL nitric acid (Section 7.3) and dilute to
 the mark with'reagent water.
   7.10  Nitrate wash solution: Dilute 50 mL
 of nitrate stock solution (Section 7.9) to 1000
 mL with reagent water.
   7.11   Sodium thiosulfate (Na2S2O3)
 solution (IN): Weigh 79 grams of Na2S2O3
 in a 1-L volumetric flask and dilute to the
 mark with reagent water.
   7.12   Trichlorophenol solutions.
   Note: The calibration solutions in this
 section employ 100-mL volumes. For
 determinations requiring a larger or smaller
.volume, increase or decrease the size of the
 volumetric flasks cpmmensurately. For
 example, if a 1-L sample is to be analyzed,
 use 1000-mL flasks (Sections 7.12.3.1 and
 7.12.4)  and 10 times the volume of reagent
 water (Sections 7.12.3.1 and 7.12.4). The
 volume of stock solution added to the"
 calibration solutions and precision and
 recovery (PAR) test solution remain as
 specified (Sections 7.12.3.2 and 7.12.4) so
 that the same amount of chloride is delivered
 to the coulometric cell regardless of the
 volume of the calibration and PAR solutions.
   7.12.1  Methanol: HPLC grade.
   7.12.2  Trichiorophenol stock solution1
 (1.0 mg/mL of C1-): Dissolve 0.186 g of 2,4,6-
 trichlorophenol in 100 mL of halide-free
 methanol.
   7.12:3  Trichlorophenol calibration
 solutions.
   7.12.3.1  Place approximately 90 mL of
 reagent water in each of five 100-mL
 volumetric flasks.
   7.12.3.2  Using a calibrated micro-syringe
 or micro-pipets, add 2, 5, 10, 30, and 80 (jL
 of the trichlorophenol stock solution (Section
 7.12.2) to the volumetric flasks and dilute
 each to the mark with reagent water to
 produce calibration solutions of 2, 5, 10, 30,
 and 80 fig Cl~ per 100 mL of solution (20,
 50,100, 300,  and 800 ng/L).
  7.12.3.3  Some instruments may have a
 calibration range that does not extend to 800
 Hg/L (80 |ig of C1-). For those instruments,
 a narrower dynamic range may be used.
 However, if the concentration of halide in a
 sample exceeds that range, the sample must
 be diluted to  bring the concentration within
 the range calibrated.
  7.12.4  Trichlorophenol precision and
 recovery (PAR) test solution (10 ng/L of Cl~):
 Partially fill a 100-mL volumetric flask, add
 10 [iL of the stock solution (Section 7.12.2),
 and dilute to  the mark with reagent water.
  7.13 Acetic acid solution: Containing 30 to
 70%'acetic acid in deionized water, per the
 instrument manufacturer's instructions.
 8.0  Sample Collection, Preservation^ and
 Storage
   8.1  Sample preservation.
   8.1.1   Residual chlorine: If the sample is
 known or suspected to contain free chlorine,
 the chlorine must be reduced to eliminate
 positive interference that may result from
 continued chlorination reactions. A
 knowledge of the process from which the
 sample is collected may be of value in
 determining whether dechlorination is
 necessary. Immediately after sampling, test  '
 for residual chlorine using the following
 method or an alternative EPA method
 (Reference  12):
   8.1.1.1  Dissolve a few crystals of
 potassium iodide in the sample and add
 three to five drops of a 1% starch solution.
 A blue color indicates the presence of
 residual chlorine.
   8.1.1.2  If residual chlorine is found, add
 1 mL of sodium thiosulfate solution (Section
 7.11) for each 2.5 ppm of free chlorine or
 until the blue color disappears. Do not add
 an excess of sodium thiosulfate. Excess
. sodium thiosulfate may cause decomposition
 of a small fraction of the OX.
   8.1.2  Acidification: Adjust the pH of
 aqueous samples to < 2 with nitric acid.
 Acidification inhibits biological activity and
 stabilizes chemical degradation, including
 to facilitate thorough adsorption.
   8.1.3  Refrigeration: Maintain samples at a
 temperature of 0 to 4° C from time of
 collection until analysis.
   8.2   Collect the amount of sample
 necessary for analysis (Section 11) and all QC
 tests (Section 9) in ah amber glass bottle of
 the appropriate size (Section 6.1.1).
   8.3   Analyze samples no less than three
 days nor more than six months after
 collection.

 9.0  Quality Control
   9.1   Each laboratory that uses this method
 is required to operate a formal quality
 assurance program. The minimum
 requirements of this program consist of an
 initial demonstration of laboratory capability,
 an ongoing analysis of standards and blanks
 as tests of continued performance, and
 analysis of matrix spike and matrix spike
 duplicate (MS/MSD) samples to assess
 accuracy and precision. Laboratory
 performance is compared to established
 performance criteria to determine if the
 results of analyses meet the performance
 characteristics of the method.
   9.1.1  The laboratory shall make an initial
 demonstration of the ability to produce
 acceptable results with this method. This
 ability is demonstrated as described in
 Section 9.2.
   9.1.2  The laboratory is permitted to
 modify this method to improve separations
 or lower the costs of measurements, provided
 that all performance specifications are met.
 Each time a modification is made to the
 method, the laboratory is required to repeat
 the procedures in Sections 9.2.2 and 10 to
 demonstrate continued method performance.
 If the detection limit of the method will be
 affected by the modification, the laboratory
 should demonstrate that the MDL (40 CFR

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18726      Federal Register/Vol. 63, No.  72/Wednesday, April  15,  1998/Rules and Regulations
136, Appendix B) is less than or equal to the .
MDL In this method or one-third the
regulatory compliance level, whichever is
higher.
  9.1.3  The laboratory shall spike 10% of
the samples with known concentrations of
2,4,6-trichlorophenol to monitor method
performance and matrix interferences
(interferences caused by the sample matrix).
This test is described in Section 9.3. When
results of these spikes indicate atypical
method performance for samples, the
samples are diluted to bring method
performance within acceptable limits.
  9.1.4  Analyses of blanks are required to
demonstrate freedom from contamination.
The procedures and criteria for analysis of
blanks are described in Section 9.4.
  9.1.5  The laboratory shall, on an ongoing
basis, demonstrate through the analysis of the
precision and recovery (PAR) standard that
the analysis system is in control. These
procedures are described in Section 9.10.
  9.1.6  The laboratory shall perform quality
control tests on the granular activated carbon.
These procedures are described in Section
9.5.
  9.1.7  Samples are analyzed in duplicate
to demonstrate precision. These procedures
are described In Section 9.6.
  9.2 Initial demonstration of laboratory
capability.
  9.2.1  Method Detection Limit  (MDL): To .
establish the ability to detect AOX, the
laboratory should determine the MDL per the
procedure in 40 CFR 136, Appendix B using
the apparatus,  reagents, and standards that •
will be used in the practice of this method.
An MDL less than or equal to the MDL in
Section  1.3 should be achieved prior to the
practice of this method.
  9.2.2  Initial precision and recovery (IPR):
To establish the ability to generate acceptable
precision and recovery, the laboratory shall
perform the following operations:
  9.2.2.1  Analyze four aliquots of the PAR
standard (Section 7.12.4) and a method blank
according to the procedures in Sections 9.4
and 11.
  9.2.2.2  Using the blank-subtracted results
of the set of four analyses, compute the ,
average  percent recovery (X) and the
standard deviation of the percent recovery (s)
for the results.
  9.2.2.3  The average percent recovery shall
be In the range of 81 to 114 jig/L and  the
standard deviation shall be less than  8 Hg/L.
If X and s meet these acceptance criteria,
system performance is acceptable and
analysis of blanks and samples may begin. If,
however, s exceeds the precision limit or X
falls outside the range for recovery, system
performance is unacceptable. In this case,
correct the problem and repeat the test.
  9.3 Matrix spikes: The laboratory shall
spike a minimum of 1096 of samples  from a
given matrix type (e.g., C-stage filtrate,
produced water, treated effluent) in duplicate
(MS/MSD). If only one sample from a given
matrix type is analyzed, an additional two
aliquots of that sample shall be spiked.
  9.3.1  The concentration of the analytes
spiked into the MS/MSD shall be determined
as follows:
  9.3.1.1  If, as in compliance monitoring,
the concentration of OX is being checked
against a regulatory concentration limit, the
spiking level shall be at that limit or at one
to five times higher than the background  -
concentration determined in Section 9.3.2,
whichever concentration is higher.
  9.3.1.2  If the concentration of OX is not
being checked against a regulatory limit, the
spike shall be at the concentration of the
precision and recovery standard (PAR;
Section 7.12.4) or at one to five times higher
than the background concentration
determined in Section 9.3.2, whichever
concentration is higher.
  9.3.2  Analyze one sample out of each
batch of 10 samples from each site to
determine the background concentration of
AOX. If necessary, prepare a solution of
2,4,6-trichlorophenol appropriate to produce
a level in the sample one to five times the
background concentration. Spike two
additional sample aliquots with spiking
solution and analyze them to determine the
concentration after spiking.
  9.3.2.1  Compute the percent recovery of
each analyte in each aliquot:

    %Recovery= 100(Found-BackgrOUnd)
    where:
         T is the true value of the spike
  9,3.2.2  Compute the relative percent
difference (RPD) between the two results (not
between the two recoveries) as described in
Section 12.4.
  9.3.2.3  If the RPD is less than 20%, and
the recoveries for the MS and MSD are
within the range of 78 to  116%, the results
are acceptable.
  9.3.2.4  If the RPD is greater than 20%,
analyze two aliquots of the precision and
recovery standard (PAR).
  9.3.2.4.1  If the RPD for the two aliquots
of the PAR is greater than 20%, the analytical
system is out of control. In this case, repair
the problem and repeat the  analysis of the
sample batch, including the MS/MSD.
  9.3.2.4.2 If, however, the RPD for the two
aliquots of the PAR is less than 20%, dilute
the sample chosen for the MS/MSD by a
factor of 2-10 (to remain within the working
range of the analytical system) and repeat the
MS/MSD test. If the RPD is  still greater than
20%, the result may not be reported for
regulatory compliance purposes.  In this case,
choose another sample for the MS/MSD and
repeat analysis of the sample batch.
  9.3.2.5  If the percent recovery for both, the
MS .and MSD are less than 78% or greater
than 116%, analyze the precision and
recovery (PAR) standard.
  9.3.2.5.1  If the recovery of the PAR is
outside the 78 to 116% range, the analytical
system is out of control. In this case, repair
the problem and repeat the  analysis of the
sample batch, including the MS/MSD.
  9.3.2.5.2 If the recovery of the PAR is
within the range of 78 to  116%, dilute the
sample, MS, and MSD by a  factor of 2-10 (to
remain within the working range of the
analytical system) and re-analyze. If the
results of the dilute analyses remain outside
of the acceptable range, these results may not
be reported for regulatory compliance
purposes. In this case, choose another sample
for the MS/MSD and repeat the analysis of
the sample batch.
  9.4  Blanks.
  9.4.1  Reagent water blanks: Analyzed to
demonstrate freedom from contamination.
  9.4.1.1  Analyze a reagent water blank
with each batch of samples. The blank must
be analyzed immediately preceding
calibration verification to allow for blank
subtraction and to demonstrate freedom from
contamination and memory effects, and must
include all details of the procedure to be
followed when analyzing samples.
  9.4.1.2  Prepare the reagent water blank
using a volume of reagent water equivalent
to the volume used for sample preparation
(Section 11.1). If using the micro-column
procedure, adsorb the method blank using
two columns, as described in Section 11.
Combust the GAC from each column
separately, as described in Section 11.
  9.4.1.3  If the result from the blank from
the batch method or the sum of the results
from two columns is more than 20 Hg/L,
analysis of samples is halted until the source
of contamination is eliminated and a blank
shows no evidence of contamination at this
level.
  9.4.2  Nitrate-washed GAC blanks:
Analyzed daily to demonstrate that the GAC
is free from contamination.
  9.4.2.1  Nitrate-washed GAC blank for the
batch procedure: Analyze a batch nitrate-
washed GAC blank by adding a scoop of dry
GAC to the assembled filter apparatus
containing the polycarbonate membrane and
washing the GAC with the nitrate wash
solution (Section 7.10) using the procedure
in Section 11.2.6.
  9.4.2.2  Nitrate-washed GAC blank for the
column procedure: Analyze a column nitrate-
washed GAC blank by assembling two carbon
columns in series and washing the columns
with the nitrate wash solution (Section 7.10)
using the procedure in Section 11.3.4.2.
Analyze the GAC in each column separately.
The results of the second analysis must be
within ±0.2 ng Cl~ of the first. A 'difference
greater than 0.2 |ig Cl~ indicates a lack of
homogeneity in the GAC that could introduce
unacceptable variability. If the difference
exceeds this amount, the GAC should be
replaced.
  9.4.3  The result for the reagent water
blank (Section 9.4.1) shall not exceed the
result for the nitrate wash blank (Section
9.4.2.1  or 9.4.2.2) by more than 0.5 (ig Cl~.
  9.5  Granular activated carbon (GAC)
batch testing: Each lot number or batch of
activated carbon received from a supplier is
tested once before use to ensure adequate
quality. Use only GAC that meets the test
criteria below.
  9.5.1  Contamination test: Analyze a scoop
of GAC. Reject carbon if the amount of OX
exceeds 1 pg (25 ng Cl~/g).
  9.5.2  Inorganic chloride adsorption test:
Attempt to adsorb NaCl from 100 mL of a
solution containing 100 mg/L in reagent
water. Wash with nitrate solution and
analyze. The amount of halide should be less
than 1 p.g Cl~ larger than the blank. A larger
amount indicates significant uptake of
inorganic chloride by the carbon. Reject
carbon if the 1 p.g level is exceeded.
  9.6  Samples that are being used for
regulatory compliance purposes shall be
analyzed in duplicate.

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                Federal Register/Vol.  63. No. 72/Wednesday, April  15, 1998/Rules  and Regulations       18727
    9.6.1  The procedure for preparing
  duplicate sample aliquots is described in
  Section 11.5.
    9.6.2  Calculate the RPD by following the
  same procedure described in Section 12:4.
    9.6.3  If the RPD is greater than 20%, the
  analyses must be repeated.
    9.6.4  If the RPD remains greater than
  20%, the result may not be reported for
.  regulatory compliance purposes.
    9.7  The specifications in this method can
  be met if the apparatus used is calibrated
  properly and maintained in a calibrated state.
  The standards used for calibration (Section
  10), calibration verification (Sectiori 9.9), and
  for initial (Section 9.2.2) and ongoing
  (Section 9.10) precision and recovery should
  be identical, so that the most precise results
  will be obtained.
    9.8  Depending on specific program
  requirements, field duplicates may be
  collected to determine the precision of the
 'sampling technique.
    9.9  At the beginning and end of each
  eight-hour shift during which analyses are
  performed, system performance and
  calibration are verified. Verification of
  system performance and calibration may be
  performed more frequently, if desired.
    9.9.1  If performance and calibration are  .
  verified, at the beginning and end of each
  shift (or more frequently), samples analyzed
  during that period are considered valid.
    9.9.2  If performance
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 18728       Federal Register/Vol.  63, No. 72/Wednesday,  April  15, 1998/Rules and Regulations
 prepared for that point, this standard shall be
 analyzed, and the calibration factor (Section
 10.6.3) and calibration linearity (Section
 10.6.4) shall be computed using the new
 calibration point. AU points used in the
 calibration must meet the 80 to 111%
 recovery specification.

 11.0 Procedure

   11.1  Sample dilution: Many samples will
 contain high concentrations of halide. If
 analyzed without dilution, the micro-
 coulometer can be overloaded, resulting in
 frequent cell cleaning and downtime. The
 following guidance is provided to assist in
 estimating dilution levels.
   11.1.1 Paper and pulp mills that employ
 chlorine bleaching: Samples from pulp mills
 that use a chlorine bleaching process may
 overload the micro-coulometer. To prevent
 system overload, the maximum volume
 suggested for paper industry samples that
 employ halide in the  bleaching process is 100
 mL. An adsorption volume as small as 25 mL
 may be used, provided the concentration of
 AOX in the sample can be measured reliably,
 as defined by the requirements in Section
 9.11. To minimize volumetric error, an
 adsorption volume less than 25 mL may not
 be used. If AOX cannot be'measured reliably
 in a 100-mL sample volume, a sample
 volume to a maximum of 1000 mL must be
 used. The sample and adsorption volumes
 are suggested for paper industry samples
 employing chlorine compounds in the
 bleaching process:
Paper or pulp mill stream
Evaporator condensate 	 	 	 	 	
Process water 	
Pulp mill effluent 	 	 	 .-. 	
Paper mill effluent 	
Combined mill effluent 	
Combined bleach effluent 	
C-stage filtrate 	 	
E-slage filtrate 	 	 	 	 	
Sample
volume
.(mL)*
100 0
100 0
30 0
10 0
5 0
1 0
0 5
0.5
Adsorption
volume
(mL)
100
100
50
9<*i
25
25
25
25
  •Assumes dilution to final volume of 100 mL. All sample aliquots (replicates, diluted samples) must be analyzed using the same fixed final vol-
ume (sample volume plus reagent water, as needed).
   11.1.2  Sample dilution procedure.
   11.1.2.1  Partially fill a precleaned
volumetric flask with pH < 2 reagent water,
allowing for the volume of sample to be
added.
   11.1.2.2  Mix sample thoroughly by
tumbling or shaking vigorously.
   11.1.2.3  Immediately withdraw the
required sample aliquot using a pipet or
micro-syringe.
  Note: Because it will be necessary to rinse
the pipet or micro-syringe (Section 11.1.2.5),
it may be necessary to pre-calibrate the pipet
or micro-syringe to assure that the exact
volume desired will be delivered.
  11.1.2.4  Dispense or inject the aliquot
into the volumetric flask.
  11.1.2.5  Rinse the pipet or syringe with
small portions of reagent water and add to
the flask.
  11.1.2.6  Dilute to the mark with pH< 2
reagent water.
  11.1.3 All samples to be reported for
regulatory compliance monitoring purposes
must be analyzed in duplicate, as described
in Section 11.5.
  11.1.4 Pulp and Paper in-process
samples: The concentration of organic halide
in in-process samples has been shown to be
20 to 30% greater using the micro-column
adsorption technique than using the batch
adsorption technique. For this reason, the
micro-column technique shall be used for
monitoring in-process samples. Examples of
In-process samples include: combined bleach
plant effluent, C-stage filtrate, and E-stage
filtrate.
  11.2  Batch adsorption and filtration.
  11.2.1  Place the appropriate volume of
sample (diluted if necessary), preserved as
described in Section 8, into an Erlenmeyer
flask.
  11.2.2  Add 5 mL of nitrate stock solution
to the sample aliquot.
  11.2.3  Add one level scoop of activated
carbon that has passed the quality control
tests in Section 9.
  11.2.4  Shake the suspension for at least
one hour in a mechanical shaker.
  11.2.5  Filter the suspension through a
polycarbonate membrane filter. Filter by
suction until the liquid level reaches the top
of the carbon.
  11.2.6  Wash the inside surface of the
filter funnel with 25 mL (±5 mL) of nitrate
wash solution in several portions. After the
level of the final wash reaches the top of the
GAC, filter by suction until the cake is barely
dry. The time required for drying should be
minimized to prevent exposure of the GAC
to halogen vapors in the air, but should be
sufficient to permit drying of the cake so that
excess water is not introduced into the
combustion apparatus. A drying time of
approximately 10 seconds under vacuum has
been shown to be effective for this operation.
  11.2.7  Carefully remove the top of the
filter holder, making sure that no carbon is
lost. This operation is most successfully
performed by removing the clamp, tilting the
top of the filter holder (the funnel portion)
to one side, and lifting upward.
  11.2.8  Using a squeeze bottle or micro-
syringe, rapidly rinse the carbon from the
inside of the filter holder onto the filter cake
using small portions of wash solution. Allow
the cake to dry under vacuum for no more
than 10 seconds after the final rinse.
Immediately turn the vacuum off.
  11.2.9  Using tweezers, carefully fold the
polycarbonate filter in half, then in fourths,
making sure that no carbon is lost.
  11.3 Column adsorption.
  11.3.1  Column preparation: Prepare a
sufficient number of columns for one day's
operation as follows:
 .11.3.1.1   In a glove box or area free from
halide vapors, place a plug of Cerafelt into
the end of a clean glass column.
 . 11.3.1.2  Fill the glass column with one.
level scoop  (approximately 40 mg) of
granular activated carbon that has passed the
quality control tests in Section 9.
  11.3.1.3  Insert a Cerafelt plug into the
open end of the column to hold the carbon
in place.
  11.3.1.4  Store the columns in a glass jar
with PTFE lined screw-cap to prevent
infiltration of halide vapors from the air.
  11.3.2  Column setup.
  11.3.2.1  Install two columns in series in
the adsorption module.
  11.3.2.2  If the sample is known or
expected to contain particulates that could
prevent free flow of sample through the
micro-columns, a Cerafelt plug is placed in
the tubing ahead of the columns. If a
measurement of the OX content of the
particulates is desired, the Cerafelt plug can
be washed with nitrate solution, placed in a
combustion boat, and processed as a separate
sample.
  11.3.3 Adjusting sample flow rate:
Because the flow rate used to load the sample
onto the columns can affect the ability of the
GAC to adsorb organic halides, the flow rate
of the method blank is measured, and the gas
pressure used to process samples is adjusted
accordingly. The flow rate of the blank,
which is composed of acidified reagent water
and contains no paniculate matter, should be
greater than the flow rate of any sample
containing even small amounts of participate
matter.
  11.3.3.1   Fill the sample reservoir with the
volume  of reagent water chosen for the
analysis (Section 9.4.1.2) that has been
preserved and acidified as described in
Section  8. Cap the reservoir.
  11.3.3.2  Adjust the gas pressure per the
manufacturer's instructions. Record  the time
required for the entire volume of reagent
water to pass through both columns. The
flow rate must not exceed 3 mL/rnin over the
duration of the time required to adsorb the-
volume. If this flow rate is exceeded, adjust
gas pressure, prepare another blank, and
repeat the adsorption.

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               Federal Register/Vol.  63, No. 72/Wednesday,  April  15, 1998/Rules and Regulations
                                                                            18729
   11.3.3.3  Once the flow rate for the blank
 has been established, the same adsorption
 conditions must be applied to all subsequent
 samples during that eight-hour shift, or until
 another method blank is processed,
 whichever comes first. To aid in overcoming
 breakthrough problems, a lower gas pressure
 (and, therefore, flow rate) may be used for
 processing of samples, if desired. If the
 sample adsorption unit is disassembled or
 cleaned, the flow rate must be checked before
 processing additional samples.
   11.3i3.4  Elute the pair of columns with 2
 mL of nitrate wash solution. The flow rate of. ,
 nitrate wash solution must not exceed  3 mL/
 min.
   11.3.3,5  Separate the columns and  mark
 for subsequent analysis.              .  .  •
   11.3.4  The adsorption of sample volumes
 is performed in a similar fashion. Fill the
 sample reservoir with the sample volume
 chosen for the analysis (Section 11.1), that
 has been preserved as described in Section 8.
 All analyses must be performed with this
 volume (sample volume plus reagent water,
 as needed) in order to maintain a flow rate
 no greater than that determined for the blank
 (see Section 11.3.3).
   11.3.4.1'  Use the same gas pressure for
 sample adsorption as is used for the blank.
   11.3.4.2  Elute the columns with 2 mL of
 the nitrate wash solution.
   11.3.4.3  Separate the columns and mark
 for subsequent analysis.
   11.3.5  If it is desirable to make
 measurements at levels lower than can be
 achieved with the sample volume chosen, or
 if the instrument response of an undiluted
 sample is less than three times the
 instrument response of the blank (Section
 12.6.3), a larger sample volume must be used.
   11.4   Combustion and titration.          ^
   11.4.1  Polycarbonate filter and GAC from
 batch adsorption.
   11.4.1.1  Place the folded polycarbonate
 filter containing the GAC in a quartz
 combustion boat, close the airlock, and
 proceed with the automated sequence.
   11.4.1.2  Record the signal from the micro-
 coulometer for a minimum integration time
 of 10 minutes and determine the
 concentration of Cl~ from calibration data,
 per Section 12.
   11.4.2  Columns from column adsorption.
   11.4.2.1  Using the push rod, push the
 carbon and the Cerafelt plug(s) from the first
 column into a combustion boat. Proceed with
 the automated sequence.
   11.4.2.2  Record the signal from the micro-
 coulometer for a minimum integration time
 of 10 minutes and determine the
, concentration of Cl~ for the first column
 from calibration data, per Section 12.
   11.4.2.3  Repeat the automated sequence
 •with the second column.     ;
   11.4.2.4  Determine the extent of
 breakthrough of organic halides from the first
 column to the second column, as described
 in Section 12.
   11.4.3  The two columns that are used for
 the method blank must be combusted
 separately, as is done for samples. 11.5
 Duplicate sample analysis: All samples to be
 reported for regulatory compliance purposes
 must be analyzed in duplicate. This
 requirement applies to both the batch and
column adsorption procedures. In addition, if
it is necessary to dilute the sample for the
purposes of reducing breakthrough or
maintaining the concentration within the
calibration range, a more or less dilute
'sample must be analyzed. The adsorption
volumes used for analysis of undiluted
samples, diluted samples, and all replicates
must be the same as the volume used for QC
tests and calibration (Sections 9 and 10).
  11.5.1   Using results from analysis.of one
sample volume (Section 11.4) and the
procedure in Section 11.1.2, determine if the
dilution used was within the calibration
range of the instrument and/or if
breakthrough exceeded the specification in
Section 12.3.1. If the breakthrough criterion
was exceeded or the sample was not within
the calibration range, adjust the dilution
volume as needed. If the breakthrough
criterion was  not exceeded and the sample
dilution was within the calibration range, a
second volume at the same dilution level
may be used.                 ,      -
  11.5.2   Adsorb the sample using the same
technique (batch or column) used for the first
sample volume. Combust the GAC from the
second volume as described in Section 11.4,
and calculate the results as described in
Section 12. Compare the results of the two
analyses as described in Section 12.4.
  11.5.3   Duplicate analyses are not required
for method blanks, as different dilution levels
are not possible.
  11,5.4   Duplicate analyses of the PAR
standard u£ed for calibration verification
(Section 9.10) are not required.

12.0 Data Analysis and Calculations
  12.1  Batch Adsorption Method: Calculate
the blank-subtracted concentration of
adsorbable organic halide detected in each
sample (in.micrograms of chloride per liter)
using the following equation:

                        (C-B)
Where:
C=^gCl~ from micro-coulometer for the
    sample
B=pg Cl~ from micro-coulometer for the
    reagent water blank (Section 9.4.1)
V = volume of sample in liters
  This calculation is performed for each of
the two dilution levels analyzed for each
sample.
  12.2  Column Adsorption Method:
Calculate the blank-subtracted concentration
of adsorbable organic halide detected in each
sample (in micrograms of chloride per liter)
using the following equation:

                f(C1+C2)-(B1+B2)l
  AOX(//g/L) = LV       '.    	-1±

Where:
Ci=ng Cl ~~ from micro-coulometer for first
    "column from the sample
C2=Hg Cl ~ from micro-coulometer for second
 ...  column from the sample
B i =ng from micro-coulometer for first
    column from the reagent water blank
    (Section 9.4.1)
                                          Bz=Hg Cl - from micro-coulometer for second
                                              column from the reagent water blank
                                              (Section 9.4.1) '
                                          V=volume' of sample in liters
                                            1.2.3  Percent breakthrough: For each
                                          sample analyzed by the column method,
                                          calculate the percent breakthrough of halide
                                          from the first column to the second column,
                                          using the following equation:
                                                                        (C2-B2)]
                                            1 2.3. 1   For samples to be reported for
                                          regulatory compliance purposes, the percent
                                          breakthrough must be less than or equal to  '
                                          25% for both of the two analyses performed
                                          on each sample (see Section 11.5).
                                            12.3.2   If the breakthrough exceeds 25%,
                                          dilute the affected sample further,
                                          maintaining the amount of halide at least
                                          three times higher than the level of blank,
                                          and reanalyze the sample. Ensure that the
                                          sample is also analyzed at a second level df
                                          dilution that is at least a factor of 2 different
                                          (and still higher than three times the blank).
                                            12.4  Relative percent difference  (RPD):
                                          Calculate the relative percent difference
                                          between the results of the two analyses of
                                          each sample, using the following equation:
                                                        200|(AOXi-AOX2)|
                                                     = --^ - -=i
                                                                 +AOX2)]
  12.5  High concentrations of AOX: If the
amount of halide from either analysis
exceeds the calibration' range, dilute the
sample and reanalyze, maintaining at least a
factor of 2 difference in the dilution levels of .
the two portions of the sample used.
  12.6  Low concentrations of AOX: The
blank-subtracted final result from the batch
procedure or the sum of the blank-subtracted
results from the two carbon columns should
be significantly above the level of the blank.
  12.6.1 If the instrument response for a
sample exceeds the instrument response for
the blank by a factor of at least 3, the result
is acceptable.
  12.6.2 If the instrument response for a
sample is less than three times the
instrument response for the blank, arid the
sample has been diluted, analyze a less dilute
aliquot of sample.
  12.6.3 If the instrument response of an
undiluted sample containing AOX above the
minimum level is less than three times the
instrument response for the blank, the result
is suspect and may not be used for regulatory
compliance purposes.. In this case, find the
cause of contamination, correct the problem,
and reanalyze the sample under the corrected
conditions.
  12.7  Report results that meet all of the
specifications in this method as the mean of
the blank-subtracted values from Section 12.1
or 12.2 for the two analyses at different
dilution levels, in |ig/L of Cl~  (not as 2,4,6-
trichlorophenol), to three significant figures.
Report the RPD of the two analyses. For
samples analyzed by the column procedure,  '
also report the percent breakthrough.

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18730       Federal  Register/Vol.  63, No. 72/Wednesday, April 15,  1998/Rules and Regulations
13.0  Method Performance
  The specifications contained in this
method are based on data from a single
laboratory and from a large-scale study of the
pulp and paper industry.
14.0  Pollution Prevention
  14.1 The solvents used in this method
pose little threat to the environment when
recycled and managed properly.
  14.2 Standards should be prepared in
volumes consistent with laboratory use to
minimize the volume of expired standards to
be disposed.
15.0  Waste Management
  15.1 It is the laboratory's responsibility to
comply with all federal, state, and local
regulations governing waste management,
particularly the hazardous waste
identification rules and land disposal
restrictions, and to protect the air, water, and •
land by minimizing and controlling all
releases from fume hoods and bench
operations. Compliance  with all sewage
discharge permits and regulations is also
required.
  15.2 Samples preserved with HC1 or
HiSO* to pH <2 are hazardous and must be
neutralized before being disposed, or must be
handled as hazardous waste. Acetic acid and
silver acetate solutions resulting from cell
flushing must be disposed of in accordance
with all applicable federal, state, and local
regulations.
  15.3  For further information on waste
management, consult '"The Waste
Management Manual for Laboratory
Personnel," and "Less is Better: Laboratory
Chemical Management for Waste Reduction,"
both available from the American Chemical
Society's Department of Government
Relations and Science Policy, 1155 16th
Street N.W., Washington, D.C. 20036.

16.0  References
  16.1  "Total Organic Halide, Methods
450.1—Interim," Prepared by Stephen Billets
and James J. Lichtenberg, USEPA, Office of  .
Research and Development, Physical and
Chemical Methods Branch, EMSL-Cincinnati,
Cincinnati, OH 45268, EPA 600/4-81-056
(1981).
  16.2  Method 9020, USEPA Office of Solid
Waste, "Test Methods for Evaluating Solid   ,
Waste, SW-846," Third Edition, 1987.
  16.3  "Determination of Adsorbable
Organic Halogens (AOX)," "German
Standard Methods for the Analysis of Water,
Waste Water and Sludge—General
Parameters of Effects and Substances,"
Deutsche Industrie Norm (DIN) Method 38
409, Part 14, DIN German Standards Institute,
Beuth Verlag, Berlin, Germany (1987).
  16.4  "Water Quality: Determination of
Adsorbafale Organic Halogens (AOX),"
International Organization for Standard/Draft
International Standardization (ISO/DIS)
Method 9562 (1988).
  16.5  "Organically Bound Chlorine by the
AOX Method," SCAN-W 9:89, Secretariat,
Scandinavian Pulp, Paper and Board Testing
Committee, Box 5604, S-11486, Stockholm,
Sweden (1989).
  16.6  Method 5320, "Dissolved Organic
Halogen," from "Standard Methods for the
Examination of Water and Wastewater,"
5320, American Public Health Association,
1015 15th St. NW, Washington, DC 20005
(1989).
  16.7  "Canadian Standard Method for the
Determination of Adsorbable Organic Halides
(AOX) in Waters and Wastewaters,"
Environment Canada and The Canadian Pulp
and Paper Association (1990).
  16.8  40 CFR Part 136, Appendix B.
  16.9  "Working with Carcinogens,"
DHEW, PHS, CDC, NIOSH, Publication 77-
206, (Aug 1977).
  16.10   "OSHA Safely and Health
Standards, General Industry" OSHA 2206, 29
CFR 1910 (Jar! 1976).
  16.11   "Safety in Academic Chemistry
Laboratories," ACS Committee on Chemical
Safety (1979),
  16.12   "Methods 330.4 and 330.5 for Total
Residual Chlorine," USEPA, EMSL-
Cincinnati, Cincinnati, OH 45268, EPA-4-
79-020 (March 1979).
  16.13   "Validation of Method 1650:
Determination of Organic Halide," Analytical
Technologies Inc., ERCE Contract 87-3410,
November 15, 1990. Available from the EPA
Sample Control Center, DynCorp, 300 N. Lee
St., Alexandria, VA 22314 (703-519-1140).

17.0  Figures
BILLING CODE 6S60-50-P

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       Federal Register/Vol.  63. No.  72/Wednesday. April  15, 1998/Rules and Regulations      18731


           a. Mitsubishi                      b. Dohrmann
                                                   c. Euroglas
    Gases
    Out
Silver
Sensor
Electrode
  Silver/Silver
  Chloride
  Reference
  Electrode
                                        Gases
                                  Silver/Silver
                                  Acetate
  Gases
  In
Plata   -  Electrode
Electrode
Silver
Generator
Electrode
                            _ Gases
                               'In
Silver
Generator
Electrode

Platinum
Electrode
 Generator J
 Electrode
Gases In*
                                              NoSlrer
                     Silver/Silver
                     Chloride
                     Reference
                     Electrode
                  Figure 1.  Microcoulometric Titration Cells (from Reference 7)

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18732    Federal Register/Vol. 63, No. 72/Wednesday, April 15, 1998/Rules and Regulations
                Funnel
                Clamp
                Stein tess-
                SteeI Support


                PTFE Gasket


                Base	
                No. 5
                Stopper.
o
                           Figure 2. Filter Apparatus

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Federal Register/Vol. 63^ No. 72/Wednesday, April 15, 1998/Rules and Regulations     18733
            Sample
            Reservoir
            (I of 4)
                                                            Nitrate Wash
                                                            Reservoir
          GAC Column 1
         GAG Columns
      Figures. Schematic of the Column Adsorption System

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18734     Federal Register/Vol. 63, No. 72/Wednesday, April 15,  1998/Rules and Regulations
                           1235
                                                                                  10
                1. Stripping Device
                2. Sample inlet forAOX
                3. AOXSampte
                4. Furnace
                5. Combustion Tube
                6. Absorberfilledwith H4SO+
                7. THratfoncell
                8. Working electrodes   .
                9. Measuring electrodes
               10. Stiner
               11. Ttaation micro-processor
               12. Gas flow and temperature control device
                           Figure 4. Schematic of an AOX Apparatus
BILLING CODE SSSO-50-C

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                Federal  Register/VoL 63, No. 72/Wednesday, April 15.  1998/Rules  and Regulations       18735
  18.0  Glossary, of Definitions and Purposes
    These definitions and purposes are specific
  to this method but have been conformed to
  common usage as much as possible.
    18.1   Units of weight and measure and
  their abbreviations.
    18.1.1  Symbols.
  °C  degrees Celsius
  jig  microgram
  pL  microliter
  <  less than
  >  greater than
  %  percent                       .
    18.1.2  Alphabetical characters.
  cm  centimeter
  g gram
  h  hour
  ED  inside diameter
  in  inch
  L  liter
  m  meter               .
  mg  milligram
  min  minute
 ' mL  milliliter   •
  mm  millimeter
  N  normal; gram molecular weight of solute
    divided by hydrogen equivalent of solute,
    per liter of solution
  OD  outside diameter
  ppb part-per-billion
•  ppm part-per-million
  ppt  part-per-trillion    i
  psig  pounds-per-square inch gauge
  v/v  volume per unit volume
  w/v weight per unit volume
    18.2  Definitions and acronyms (in
  alphabetical order).
    Analyte: AOX tested for by this method.
    Calibration standard (CAL): A solution
  prepared from a secondary standard and/or
  stock solution which is used to calibrate the
  response of the instrument with respect to
  analyte concentration.-.
    Calibration verification standard (VER):
 The mid-point calibration standard (CS3) that
  is used to verify calibration.
    Field blank: An aliquot of reagent water or
  other reference matrix that is placed in a -
  sample container in the laboratory or the
  field, and treated as a sample in all respects,
  including exposure to sampling site
  conditions, storage, preservation, and all
  analytical procedures. The purpose of the
  field blank is to determine if the field or
 sample transporting procedures and
  environments have contaminated the sample.
   IPR: Initial precision and recovery; four
  aliquots of the diluted PAR standard
 analyzed to establish  the ability to generate
  acceptable precision and accuracy. An IPR is
 performed prior to the first time this method
 is used and any time the method or
 instrumentation is modified.
   Laboratory, blank: See Method blank.
   -Laboratory control sample (LCS): See ,
 Ongoing precision and recovery sample
  (OPR).
   Laboratory reagent blank: See Method
 blank.
   May: This action, activity, or procedural
 step is neither required nor prohibited.
   May not: This action, activity, or
 procedural step is prohibited.
   Method blank: An aliquot of reagent water
 that is treated exactly as a sample including
 exposure to all glassware, equipment,
 solvents, reagents, internal standards, and
 surrogates that are used'with samples. The
 method blank is used to determine if analytes
 or interferences are present in the laboratory
 environment, the reagents, or the apparatus.
   Minimum,level (ML): The level at which
 the entire analytical system must give a
 recognizable signal and acceptable
 calibration point for the analyte. It is
 equivalent to the concentration of the lowest
 calibration standard, assuming that all
 method-specified sample weights, volumes,
 and cleanup procedures have been
 employed.
   Must: This action, activity, or procedural
 step is required.
   OPR: Ongoing precision and recovery
 standard; a laboratory blank spiked with a
 known quantity of analyte. The OPR is
 analyzed exactly like a sample. Its purpose is
 to assure that the results produced by the
 laboratory remain within the limits specified
 in this method for precision and recovery.
•  PAR: Precision and recovery standard;
 secondary standard that is diluted and spiked
 to form the IPR and OPR.
   Preparation blank: See Method blank.
   Primary dilution standard: A solution
 containing the specified analytes that is
 purchased or prepared from stock solutions
 and diluted as needed to prepare calibration
 solutions and other solutions.
   Quality control check sample (QCS): A
 sample containing all or a subset of the
 analytes at known concentrations. The QCS
 is obtained from a source external to the
 laboratory or is prepared from a source of
standards different from the source of
 calibration standards. It is used to check
laboratory performance with test materials
prepared external to the normal preparation
process.
   Reagent water: Water demonstrated to be
free from the analyte of interest and
potentially interfering substances at the
method detection limit for the analyte.
   Relative standard deviation (BSD): The
standard deviation multiplied by 100, .
divided by the mean.
   RSD: See Relative standard deviation.
   Should: This action, activity, or procedural
step is suggested but not required.
   Stock solution: A solution containing an
analyte that is prepared using a reference
material traceable to EPA, the National
Institute of Science and Technology (MIST),
or a source that will attest to the purity and
authenticity of the reference material.
  VER: See Calibration verification standard.

Method 1653—Chlorinated Phenolics in
Wastewater by In Situ Acetylation and
GCMS

1.0  Scope and Application
   1.1  This method is for determination of
chlorinated phenolics (chlorinated phenols,
guaiacols, catechols, vanillins,
syringaldehydes) and other compounds
associated with the Clean Water Act; the
Resource Conservation and Recovery Act;
and the Comprehensive Environmental
Response, Compensation, and Liability Act;
and that are amenable to in situ acetylation,
extraction, and analysis by capillary column
gas chromatography/mass spectrometry
  (GCMS). This method is based on existing
  methods for determination of
  chlorophenolics in pulp and paper industry
  wastewaters (References 1 and 2):
   1.2  The chemical compounds listed in
  Table 1 may be determined in waters and,
  specifically, in in-process Streams and
  wastewaters associated with the pulp and
  paper industry. The method is designed to
  meet the survey and monitoring requirements
•  of the Environmental Protection Agency
  (EPA).
   1.3  The detection limit of this-method is
  usually dependent on the level of
  interferences rather than instrumental
 limitations. The method detection limits
  (MDLs) in Table 2 typify the minimum
 quantity that can be detected with no
 interferences present.
   1.4  The GCMS portions of this method
 are for use only by persons experienced with
 GCMS or under the close supervision of such
 qualified persons.  Laboratories unfamiliar
 with analyses of environmental samples by
 GCMS should run  the performance tests in
 Reference 3 before beginning.
   1.5  Any modification of the method
 beyond those expressly permitted is subject
 to the application and approval of alternative
 test procedures under 40 CFR Parts 136.4 and
. 136.5.

 2.0  Summary of Method
   2.1   A 1000-rnL aliquot of water is spiked
 with stable isotopically labeled analogs of the
 compounds of interest and an internal
 standard. The solution is adjusted to neutral
 pH,,potassium carbonate buffer is added, and
 the pH is raised to  9-11.5. The
 chlorophenolics are converted in, situ to
 acetates by the addition of acetic anhydride.   '
 After acetylation. the solution is extracted
 with hexane. The hexane is concentrated to
 a final volume of 0.5 mL, an instrument
 internal standard is added, and an aliquot of
 the concentrated extract is. injected into the
 gas chromatograph (GC). The compounds are
 separated by GC and detected by a mass
 spectrometer (MS). The labeled compounds
 and internal standard serve to correct the
 variability of the analytical-technique.
  2.2  Identification of a pollutant
 (qualitative analysis) is performed by
 comparing the relative retention time and
 mass spectrum to that of an authentic        '
 standard. A compound is identified when its
 relative retention time and mass spectrum
 agree.      .            .
  2.3  Quantitative analysis is performed in
 one of two ways by GCMS using extracted
 ion-current profile  (EICP) areas: (1) For those
 compounds listed in Table 1 for which
 standards and labeled analogs are available,
 the GCMS system is calibrated and the
 Compound concentration is determined using
 an isotope dilution technique; (2) for those
 compounds listed in Table 1 for which
 authentic standards but no labeled
 compounds are available, the GCMS system
 is calibrated and the compound
 concentration is determined using an internal
 standard technique.
  2.4  Quality is assured through
 reproducible calibration and testing of the
 extraction and GCMS systems.

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18736       Federal Register/Vol. 63,  No.  72/Wednesday, April 15,  1998/Rules and Regulations
3,0  Definitions
  3.1  Chlorinated phenolics are the
chlorinated phenols, guaiacols, catechols,
vanillins, syringaldehydes and other
compounds amenable to in situ acetylation,
extraction, and determination by GCMS
using this method.
  3.2  Definitions for other terms used in
this method are given in the glossary at the
end of the method (Section 20.0).
4,0  Interferences
  4.1  Solvents, reagents, glassware, and
other sample processing hardware may yield
artifacts and/or  elevated baselines, causing
misinterpretation of chromatograms and
spectra. All materials used in the analysis
shall be demonstrated to be free from
interferences under the conditions of analysis
by running method blanks initially and with
each sample batch (samples started through
the extraction process on a given eight-hour
shift, to a maximum of 20). Specific selection
of reagents and  purification of solvents by
distillation In all-glass systems may be
required. Glassware and, where possible,
reagents are cleaned by using solvent rinse
and baking at 450 °C for a minimum of one
hour.
  4.2  Interferences co-extracted from
samples will vary considerably from source
to source, depending on the diversity of the
site being sampled. Industry experience
suggests that high levels of non-chlorinated
phenols may cause poor recovery of the
compounds of interest,  particularly in
samples collected in the vicinity of a source
of creosote, such as a wood-preserving plant
(Reference 1).
  4.3  The internal standard. 3,4,5-
trichlorophenol, has been reported to be an
anaerobic degradation product of 2,3,4,5-
tetrachlorophenol and/or  pentachlorophenol
(Reference 1). When an interference with this
or another compound occurs, labeled
pentachlorophenol or another labeled
compound may be used as an alternative
internal standard; otherwise, the internal
standards and reference compounds must be
used as specified in this method.
  4.4  Blank contamination by
pentachlorophenol has been reported
(Reference 1) to be traceable to potassium
carbonate; it has also been reported that this
contamination may be removed by baking
overnight at 400 to 500 °C.
  4.5  Catechols are susceptible to  ,
degradation by  active sites on injection port
liners and columns, and are subject to
oxidation to the corresponding chloro-o-
bcnzoquinones (Reference 2). A small
amount of ascorbic acid may be added to
samples to prevent auto-oxidation (Reference
2; also see Section 11.1.6). For pulp and
paper industry  samples, ascorbic acid may be
added to treated effluent samples only.
5.0  Safety
  5.1  The toxicity or carcinogenicity of
each compound or reagent used in this
method has not been precisely determined;
however, each chemical compound should
be treated as a potential health hazard.
Exposure to these compounds should be
reduced to the lowest possible level. The
laboratory is responsible for maintaining a
current awareness file of DSHA regulations
regarding the safe handling of the chemicals
specified in this method. A reference file of
materials safety data sheets (MSDSs) should
be made available to all personnel involved
in these analyses. Additional information on
laboratory safety can be found in References
4 through 6.'
  5.2 Samples may contain high
concentrations of toxic compounds, and
should be handled with gloves and a hood
opened to prevent exposure.  ,

6.0  Equipment and Supplies
  Note: Brand names, suppliers, and part
numbers are for illustrative purposes only.
No endorsement is implied. Equivalent
performance may be achieved using
apparatus and materials other than those
specified here, but demonstration of
equivalent performance that meets the
requirements of this method is the
responsibility of the laboratory.
  6.1 Sampling equipment for discrete or
composite sampling.
  6.1.1  Sample bottles and caps.
  6.1.1.1   Sample bottle: Amber glass, 1000-
mL minimum, with screw-cap. If amber
bottles are not available, samples shall be
protected from light
  6.1.1.2  Bottle caps: Threaded to fit
sample bottles. Caps shall be lined with
PTFE.
  6.1.1.3  Cleaning bottles: Detergent water
wash, cap with aluminum foil, and bake at
450°C for a minimum of one hour before use.
  6.1.1.4  Cleaning liners: Detergent water
wash, reagent water (Section 7.4) and solvent
rinse, and bake at approximately 200°C for a
minimum of 1 hour prior to use.
  6.1.1.5  Bottles and liners must be lot-
certified to be free of chlorophenolics by
running blanks according to this method. If
blanks from bottles and/or liners without
cleaning or with fewer cleaning steps  show
no detectable chlorophenolics, the bottle and
liner cleaning steps that do not eliminate
chlorophenolics may be omitted.
   6.1.2  Compositing equipment: Automatic
or manual compositing system incorporating
glass containers cleaned per bottle cleaning
procedure above. Sample containers are kept
at 0 to 4 °C during sampling. Glass or PTFE
tubing only shall be used. If the sampler uses
a peristaltic pump, a minimum length of
compressible silicone rubber tubing may be
used in the pump only. Before use, the tubing
shall be thoroughly rinsed with methanol,
followed by repeated rinsing with reagent
water (Section 7.4) to minimize sample
contamination. An integrating flow meter is
used to collect proportional composite
samples.
   6.2  Extraction apparatus.
   6.2.1  Bottle or beaker: 1500-to 2000-mL
capacity.
   6.2.2  Separatory funnel: 500-to 2000-mL,
glass, with PTFE stopcock.
   6.2.3  Magnetic stirrer: Corning Model
320, or equivalent, with stirring bar.
   6.3  Polyethylene gloves: For handling
samples and extraction equipment (Fisher
11-394-110-B, or equivalent).
   6.4  Graduated cylinders: lOOOrmL, 100-
mL, and 10-mL nominal.
  6.5  Centrifuge: Capable of accepting 50-
mL centrifuge tubes and achieving 3000
RPM.
  6.5.1  Centrifuge tubes.
  6."5.1.1  35-mL nominal, with PTFE-lined
screw-cap.
  6.5.1.2  15-mL nominal, conical
graduated, with ground-glass stopper.
  6.6  Concentration apparatus.
  6.6.1 .  Kuderna-Danish (K-D)
concentrator tube: 10-mL, graduated (Kontes
K-570050-1025, or equivalent) with
calibration verified. Ground-glass stopper
(size 19/22 joint) is used to prevent
evaporation of extracts.
  6.6.2  Kuderna-Danish (K-D) evaporation
flask: 1000-mL (Kontes K-570001-1000, or
equivalent), attached to concentrator tube
with springs (Kontes K-662750-0012).
  6.6.3  Snyder column: Three-ball macro
(Kontes K-503000-0232, or equivalent).
  6.6.4  Snyder column: Two-ball micro
(Kontes K-469002-0219, or equivalent).
  6.6.5  Boiling chips: Approximately 10/40
mesh, extracted with methylene chloride and
baked at 450 °C for a minimum of one hour.
  6.6.6  Nitrogen evaporation apparatus:
Equipped with a water bath controlled at 35
to 40 °C (N-Evap, Organomation Associates,
Inc., South Berlin, MA, or equivalent),
installed in a fume hood. This device may be
used in place of the micro-Snyder column
concentrator in Section 6.6.4 above.
  6.7  Water bath: Heated, with concentric
ring  cover, capable of temperature control
(± 2 °C), installed in a fume hood.
  6.8  Sample vials: Amber glass, 1- to 3-mL,
with PTFE-lined screw-cap.
  6.9  Balances.
  6.9.1  Analytical: Capable of weighing 0.1
mg.
  6.9.2  Top loading: Capable of weighing
10 mg.
  6.10  pH meter.
  6.11  Gas chromatograph: Shall have
splitless or on-column injection port for
capillary column, temperature program with
50°C hold, and shall meet all of the
performance specifications in Section 9.
  6.12  Gas chromatographic column: 30 m
(±5 m) x 0.25 mm (±0.02 mm) I.D. x 0.25
micron, 5% phenyl, 94% methyl, 1% vinyl
silicone bonded-phase fused-silica capillary
column 0 & W DB-5, or equivalent).
  6.13  Mass spectrometer:  70 eV electron
impact ionization, shall repetitively scan
from 42 to 450 amu in 0.95 to 1.00 second,
and shall produce a unit resolution (valleys
between m/z 441-442 less than 10% of the
height of the 441 peak), background-
corrected mass spectrum from 50 ng
decafluorotriphenylphosphine (DFTPP)
introduced through the GC inlet. The
spectrum shall meet the mass-intensity
criteria in Table 3 (Reference 7). The mass
spectrometer shall be interfaced to the GC
such that the end of the capillary column
terminates within 1 cm of the ion source, but
does not intercept the electron or ion beams.
All portions of the column which connect the
GC to the ion source shall remain at or above
the column temperature during analysis to
preclude condensation of less volatile
compounds.
  6.14  Data system: Shall collect and record
MS data, store mass-intensity data in spectral

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                Federal Register/Vol. 63.  No.  72/Wednesday, April  15, 1998/Rules and Regulations       18737
  libraries, process GCMS data, generate
  reports, and compute and record response
  factors.
    6.14.1  Data acquisition: Mass spectra
  shall ,be collected continuously throughout
  the analysis and stored on a mass storage
  device.
    6.14.2  Mass spectral libraries: User-
  created libraries containing mass spectra
  obtained from analysis of authentic standards
  shall be employed to reverse search GCMS  .
  runs for the compounds of interest (Section
  10.2).         '
    6.14:3  Data processing: The data system
  shall be used to search, locate, identify, and
  quantify the compounds of interest in each
  GCMS analysis. Software routines shall be
  employed to compute retention times, and to
  compute peak areas at the m/z's specified
  (Table 4). Displays of spectra, mass
  chromatograms, and library comparisons are
  required to verify results. '
    6.14.4  Response factors and multi-point
  calibrations: The data system shall be used to
  record and maintain lists of response factors
  (response ratios for isotope dilution) and
  multi-point calibration curves (Section 10).
  Computations of relative standard deviation
  (coefficient of variation) are used for testing
  calibration linearity. Statistics on initial
  (Section 9.3.2) and ongoing (Section 9.6) ^
  performance shall be computed and
  maintained.

 •7.0  Reagents and Standards
    7.1  Reagents for adjusting sample pH.
    7.1.1   Sodium hydroxide: Reagent grade, 6
  N in reagent water.
    7.1.2   Sulfuric acid: Reagent grade, 6 N in
  reagent water.
    7.2  Reagents for sample preservation.
    7.2.1  Sodium thiosulfate (Na2S2O3)
 solution (1 N): Weigh 79 g Na2S2O3 in a 1-
 L volumetric flask and dilute to the mark
 with reagent water.
    7.2.2  Ascorbic acid solution: Prepare a
 solution of ascorbic acid in reagent water at
 a concentration of 0.1 g/mL. This solution
 must be prepared fresh on each day when,
 derivatizations will be performed. Therefore,
 do not prepare more than will be used that
 day. (A 50"-mL volume is sufficient for ten
 analyses).
   7.3  Solvents.: Hexane, acetone, and
 methanol. Distilled in glass (Burdick and
 Jackson, or equivalent).
   7.4  Reagent water: Waiter in which the
 compounds of interest and interfering
 compounds are not detected by this method.
   7.5  Reagents for derivatization.
   7.5.1   Potassium carbonate (KzCOs).
   7.5.1.1  Purification: Spread in a shallow
 baking dish, heat overnight at 400 to 500°C.
   7.5.1.2 , Solution: Dissolve 150 g purified
 K2CO3 in 250 mL reagent water.
   7.5.2   Acetic anhydride: Redistilled
 reagent grade.     '
   7.6  Analytical standards.
   7.6.1   Derivatization: Because the
 chlorinated phenolics are determined as their
 acetate derivatives after in situ acetylation,
 the method requires that the calibration
 standards be prepared by spiking the
 underivatized materials into reagent water
 and carrying the spiked reagent water aliquot
^through the entire derivatization and
  extraction procedure that is applied to the
  Held samples.
   7.6.2  Standard solutions: Purchased as
  solutions or mixtures with certification to
  their purity, concentration, and authenticity,
  or prepared from materials of known purity
  and composition. If chemical purity of a
  compound is  98% or greater, the weight may
  be used without correction to compute the
  concentration of the standard. When not
  being used, standards are stored in the dark
  at — 20 to —10 °C in screw-capped vials with
  PTFE-lined lids. A mark is placed on the vial
  at the level of the solution so that solvent
  evaporation loss can be detected. The vials
  are  brought to room temperature prior to use.
   7.6.3 If the chemical purity of any
  standard does not meet the 98% requirement
  above, the laboratory must correct all
  calculations, calibrations, etc., for the
 difference in purity.
   7.7   Preparation of stock solutions:
 Prepare chlorovanillins and
 chlorosyringaldehydes in acetone, as these
 compounds are subject to degradation in
 methanol. Prepare the remaining
 chlorophenolics in methanol. Prepare all
 standards per  the steps below. Observe the
 safety precautions in Section 5.
   7.7.1  Dissolve an appropriate amount of
 assayed reference material in a'suitable
 solvent. For example, weigh 50 mg (±0.1 mg)
 of pentachlorophenol in a 10-mL ground-
 glass-stoppered volumetric flask and fill to
 the mark with methanol. After the       )
 pentachlorophenol is completely dissolved,
 transfer the solution to a 15-mL vial with
 PTFE-lined cap.
   7.7.2  Stock solutions should be checked
 for signs of degradation prior to the
 preparation of calibration or performance test
 standards and  shall be replaced after  six
 months, or sooner if comparison with quality.
 control check standards indicates a change in
 concentration.
   7.8  Labeled compound spiking solution:
 From stock solutions prepared as above, or
 from mixtures, prepare one spiking solution
 to contain the labeled chlorovanillin in
 acetone and a second spiking solution to
 contain the remaining chlorophenolics,
 including the 3,4,5-trichlorophenol sample
 matrix,internal standard (SMIS), in methanol.
 The  labeled compounds and SMIS are each
 at a concentration of 12.5 (ig/mL.
  7.9  Secondary standards for calibration:   -
 Using stock solutions (Section 7.7), prepare
 one secondary standard containing the
 chlorovanillins and chlorsyringaldehydes
 listed in Table 1 in acetone and a second
 secondary standard containing the remaining
 chlorophenolics in methanol. The
 monochlorinated phenol, guaiacol, and
 catechol are included at a concentration of 25
 (ig/mL; the trichlorinated catechols,
 tetrachlorinated guaiacol and catechol,
 pentachlorophenol, 5,6-dicnlorovanillin, and
 2,6-dichlorosyringaldehyde are included at a
 concentration of 100 ng/mL; and the
 remaining compounds are included at a
 concentration of 50 fig/mL, each in their
respective solutions.
  7.10   Instrument internal standard (IIS):
Prepare a solution of 2,2'-difluorobiphenyl
 PFB) at a concentration of 2.5 mg/mL in •
hexane.
    7.11  DFTPP solution: Prepare a solution
  of DFTPP at 50 ng/mL in acetone.
    7.12  Solutions for obtaining authentic
  mass spectra (Section 10.2): Prepare mixtures
  of compounds at concentrations which will
  assure authentic spectra are obtairied.for
  storage in libraries.
    7.13  Preparation of calibration solutions.
    7.13.1   Into five 1000-mL aliquots of
 . reagent water, spike 50, 100, 200, 500 and
  1000 (iL of each of the two solutions in
  Section 7.9. Spike 1.00 mL of each of the two
  labeled compound spiking solutions (Section '
  7.8) into each of the five aliquots.
    7.13.2   Using the procedure in Section 11,
  derivative and extract each solution, and
  concentrate the extract to a final volume of
  0.50 mL. This will produce calibration
  solutions of nominal 5, 10, 20, 50, and 100
  Hg/mL of the native chlorophenolics and a
  constant concentration of 25 (ig/mL of each
  labeled compound and the SMIS (assuming
  100% derivatization and recovery). As noted
  in Section 11.1.6, ascorbic acid is added to
  all samples of final effluents to stabilize
  chlorocatechols, but is not added to samples
  of pulp and paper in-process wastewaters.
  Therefore, it is necessary to prepare separate
  sets of five initial calibration standards with
 • and without the addition of ascorbic acid.
  Also, in the event that the laboratory is
  extracting  final effluent samples by both the
  stir-bar and separately funnel procedures
  (see Section 11.3), initial calibration
 standards should be prepared by both
 methods.
  . 7.13.3  These solutions permit the relative
, response (labeled to unlabeled) and the
 response factor to be measured as a function
 of concentration (Sections 10.4 and 10.5).
   7.13.4  The nominal 50 (xg/mL standard
 may also be used as a calibration verification
 standard (see Section 9.6).
   7.14  Ongoing precision and recovery
 (OPR) standard: Used for determination of
 initial (Section 9.3.2) and ongoing (Section
 9.6) precision and recovery. This solution is
, prepared by spiking 500 pL of each the two
 solutions of the secondary calibration
 standards (Section 7.9) and 1 mL of each of
 the two labeled compound spiking solutions
 (Section 7.8) into 1000 mL of reagent water.
   7.15  Stability of solutions: All standard
 solutions (Sections 7.7 through 7.14) shall be
 analyzed within 48 hours of preparation and
 on a monthly basis thereafter for signs of
 degradation. Standards will remain  •
 acceptable  if the peak area at the quarititation
 m/z relative to the DFB internal standard
 remains within ±15% of the area obtained in
 the initial analysis  of the standard.
 8.0  Sample Collection, Preservation, and
 Storage
   8.1  Collect samples in glass containers
 (Section 6.1) following conventional
 sampling practices (Reference 9)..Aqueous
 samples are collected in refrigerated bottles
 using automatic sampling equipment.
   8.2  Sample preservation.
   8.2.1  Residual chlorine: If the sample
 contains .residual chlorine, the chlorine must
 be reduced to eliminate positive interference
 resulting from continued chlorinatiqn
 reactions. Immediately after sampling, test
 for residual chlorine using the following

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18738      Federal Register/Vol. 63,  No.  72/Wednesday, April 15,  1998/Rules  and Regulations
method or an alternative EPA method
(Reference 10).
  8.2.1.1  Dissolve a few crystals of
potassium iodide in the sample and add
three to five drops of a 1 % starch solution.
A blue color indicates the presence of
residual chlorine.
  8.2.1.2  If residual chlorine is found, add
1 mL of sodium thiosulfate solution (Section
7.2.1} for each 2.5 ppm of free chlorine or
until the blue color disappears.
  8.2.2 Acidification: Adjust pH of all
aqueous samples to <2 with sulfuric acid
(Section 7.1.2). Failure to acidify samples
may result in positive interferences from
continued chlorination reactions.
  8.2.3 Refrigeration: Maintain sample
temperature at 0 to 4 °C from time of
collection until extraction, and maintain
extracts at a temperature of 0 to 4° C from
time of extraction until analysis.
  8.3  Collect a minimum of 2000 mL of
sample. This will provide a sufficient amount
for all testing. Smaller amounts may be
collected if the stream is known to contain
high levels of chlorophenolics.
  8.4  All samples must be acetylated and
extracted within 30 days of collection, and
must be analyzed within 30 days of
acetylation. if labeled compound recoveries
for a sample do not meet the  acceptance
criteria in Table 5 and the 30-day holding
time is not met, a new sample must be
collected.
9.0  Quality Control
  9.1  Each laboratory that uses this method
is required to operate a formal quality
assurance program (Reference 8). The
minimum requirements of this program
consist of an initial demonstration of
laboratory capability, analysis of samples
spiked with labeled compounds to evaluate
and document data quality, and analysis of
standards and blanks as tests of continued
performance. Laboratory performance is
compared to established performance criteria
to determine if the results of analyses meet
the performance characteristics of the
method.   	
  9.1.1 DFTPP spectrum validity shall be
checked at the beginning of each eight-hour
shift during which analyses are performed.
This test is described in Section 9.2.
  9.1.2 The laboratory shall make an initial
demonstration of the ability to generate
acceptable results with this method. This
ability is established as described in Section
9.3*
  9.1.3  The laboratory is permitted to
modify this method to improve separations
or lower the costs of measurements, provided
all performance specifications are met. Each
time a modification is made to the method,
the laboratory is required to repeat the
procedures in Sections 10.3 and 9.3.2 to
demonstrate method performance. If the
detection limits for the analytes in this
method will be affected by the modification,
the laboratory should demonstrate that each
MDL (40 CFR 136, Appendix B) is less than
or equal to the MDL in this method or one-
third the regulatory compliance level,
whichever is higher.
  9.1.4  The laboratory shall spike all
samples with labeled compounds and the
 sample matrix internal standard (SMIS) to
 monitor method performance. This test is
 described in Section 9.4. When results of
 these spikes indicate atypical method
 performance for samples, the samples are,
 diluted to bring method performance within
 acceptable limits (Section 13).
   9.1.5 ' Analyses of blanks are required to
 demonstrate freedom from contamination.
 The procedures and criteria for analysis of a
 blank are described in Section 9.5.
   9.1.6  The laboratory shall, on an ongoing
 basis, demonstrate through analysis of the
 ongoing precision and recovery standard
 (Section 7.14) that the analysis system is in
 control. These procedures are described in
 Section 9.6.
   9.1.7  The laboratory shall maintain
 records to define the quality of data that is
 generated. Development of accuracy
 statements is described in Section 9.4.4 and
 9.6.3.
   9.2   DFTPP spectrum validity: Inject  1 pL
 of the DFTPP solution (Section 7.11) either
 separately or within a few seconds of
 injection of the OPR standard (Section 9.6)
 analyzed at the beginning of each shift. The
 criteria in Table 3 shall be met.
   9.3   Initial demonstration of laboratory
 capability.
   9.3.1  Method Detection Limit.(MDL): To
 establish the ability to detect the analytes in
 this method, the laboratory should determine
 the MDL per the procedure in 40 CFR 136,
 Appendix B using the apparatus, reagents,
 and standards that will be used in the
 practice of this method. MDLs less tihan or
 equal to the MDLs in Table 2 should be
 achieved prior to the practice of this method.
   9.3.2  Initial precision and recovery (IPR):
 To establish the ability to demonstrate
 control over the analysis system and to
 generate acceptable precision and accuracy,
 the laboratory shall perform the following
 operations:
   9.3.2.1   Derivative, extract, concentrate,
 and analyze four 1000-mL aliquots of the
 ongoing precision and recovery standard
 (OPR; Section 7.14), according to the
' procedure in Section 11. Separate sets of IPR
 aliquots must be prepared with the addition
 of ascorbic acid and without.
   9.3.2.2   Using results of the four analyses,
 compute the average percent recovery (X)
 and the relative standard deviation of the
 recovery (s) for each compound, by isotope
 dilution for pollutants with a labeled analog,
 and by internal standard for pollutants with
 no labeled analog and for the labeled
 compounds and the SMIS.
   9.3.2.3  For each compound, compare s
 and X with the corresponding limits for
 initial precision and recovery in Table 5. If
 s and X for all compounds meet the
 acceptance criteria, system performance is
 acceptable and analysis of blanks and
 samples may begin. If, however, any
 individual s exceeds the precision limit or
 any individual X falls outside the range for
 recovery, system performance is
 unacceptable for that compound. In this
 event, correct the problem and repeat the test
 (Section 9.3.2).
   9.4  Labeled compound recovery: The
 laboratory shall spike all samples with
 labeled compounds and the sample matrix
internal standard (SMIS) to assess method
performance on the sample matrix.
  9.4.1  Analyze each sample according to
the method beginning in Section 11.
  9.4.2  Compute the percent recovery (P) of
the labeled compounds and the SMIS using
the internal standard method (Section 14.3)
with 2,2'-difluorobiphenyl as the reference
compound.
  9.4.3  Compare the labeled compound and
SMIS recovery for each compound with the
corresponding limits in Table 5. If the
recovery of any compound falls outside its
warning limit, method performance is
unacceptable for that compound in that
sample. Therefore, the sample is complex.
The sample is diluted and reanalyzed per
Section 13.
  9.4.4  As part of the QA program for the
laboratory, it is suggested, but not required,
that method accuracy for samples be assessed
and records maintained. After the analysis of
five samples for which the labeled
compounds pass the tests in Section 9.4.3,
compute the average percent recovery (P) and
the standard deviation of the percent
recovery (sp) for the labeled compounds
only. Express the accuracy assessment as a
percent recovery interval from P—2sp to P +
2sp for each matrix. For example, if P = 90%
and sp = 10%, the accuracy interval is
expressed as 70 to 110%. Update the
accuracy assessment for each compound on
a regular basis (e.g., after each 20 to 30 new
accuracy measurements).
  9.5  Blanks: Reagent water blanks are
analyzed to demonstrate freedom from
contamination.                  .
  9.5.1  Extract and concentrate a 1000-mL
reagent water blank with each sample batch
(samples started through the extraction
process on the same eight-hour shift, to a
maximum of 20 samples). Blanks associated
with samples to which ascorbic acid is added
must be prepared with ascorbic acid, and
blanks associated with samples to which
ascorbic acid is not added must be prepared
without ascorbic acid. Analyze the blank
immediately after analysis of the OPR
(Section 7.14) to demonstrate freedom from
contamination.
  9.5.2 If any of the compounds of interest
(Table 1) or any potentially interfering
compound is found in an aqueous blank at
greater than 5(ig/L (assuming a response
factor of one relative to die sample matrix
internal standard for compounds not listed in
Table 1), analysis  of samples is halted until
the source of contamination is eliminated
and  a blank shows no evidence of
contamination at this level.
  9.6  Calibration verification and ongoing
precision and recovery: At the beginning of
each eight-hour shift during which analyses
are performed, analytical system performance
is verified for all compounds. Analysis of
DFTPP (Section 9.2) and the nominal 50|ig/
mL OPR (Section  11.1.5) is used to verify all
performance criteria. Adjustment and/or
recalibration, per Section 10, shall be
performed until all performance criteria are
met. Only after all performance criteria are
met may samples and blanks be analyzed.
  9.6.1 Analyze the extract of the OPR
(Section 11.1.5) at the beginning of each
eight-hour shift and prior to analysis of

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                Federal Register/Vol. 63, No. 72/Wednesday,  April 15,  1998/Rules  and Regulations       18739
  samples from the same batch. Alternatively,
  a separate calibration verification may be
  performed using an aliquot of the midpoint
  calibration standard from Section 7.13 (with
  a nominal concentration of SOp, g/mL). This
  alternative may be used to check instrument
  performance on failure of an OPR, or when
  samples extracted with an OPR aliquot are
•  not analyzed within the same eight-hour
  analysis shift.
    9.6.1.1  Retention times: The absolute
  retention time of 2,2'-difluorobiphenyl shall
  be within the range of 765 to 885 seconds,  '
  and the relative retention times of all
  pollutants and labeled compounds shall fall
  within the limits given in Table 2.
    9.6.1.2  GC resolution: The valley height
  between 4,6-dichloroguaiacol and 3,4-
  dichloroguaiacol at rn/z 192 shall not exceed
  10% of the height of the taller of the two
  peaks.
    9.6.1.3  Multiple peaks: Each compound
  injected shall give a single, distinct GC peak..
    9.6.2  Compute the percent recovery of
  each pollutant (Table 1) by isotope dilution
-  (Section 10.4) for those compounds that have
  labeled analogs. Compute the percent
  recovery of each pollutant that has no labeled
  analog by the internal standard method
  (Section 10.5), using the 3,4,5-
  trichlorpphenol (SMIS) as the internal
  standard. Compute the percent recovery of
  the labeled compounds and the SMIS by the :
  internal standard method, using the 2,2'-
  difluorobiphenyl as the internal standard..
    9.6.2.1   For each compound, compare the
  recovery with the limits for ongoing
  precision and repovery in Table 5. If all
  compounds meet the acceptance criteria,
  system performance is acceptable and
  analysis of blanks and samples may proceed.
  If, however, any individual recovery falls
  outside of the range given," system
  performance is unacceptable for that
  compound. In this event,  there may be a
  problem with the GCMS or with the
  derivatization/extraction/concentration
  systems.
   9.6.2.2  GCMS system: To determine if the
  failure of the OPR test (Section 9.6.2.1) is due
  to instrument drift, analyze the current
  calibration verification extract (Section
 , 7.13.4),  calculate the percent recoveries of all
  compounds, and compare with the OPR
  recovery limits in Table 5. If all compounds
  meet these criteria, GCMS performance/
  stability is verified, and the failure of the
  OPR analysis is attributed to problems in the
  derivatizatiori/extraction/concentration of the
  OPR. In this case, analysis of the sample
  extracts may proceed. However, failure of
  any of the recovery criteria in the analysis of
  a sample extract requires rederivatization of
  that sample (Sections 13.3.1 and 13.3.2). If,   '
  however, the performance/stability of the
  GCMS is not verified by analysis of the
  calibration verification extract, the GCMS
  requires recalibration and all extracts
  associated with the failed OPR must be
  reanalyzed.
   9.6.3  Add results that pass the •
 specifications in Section 9.6.2.1 to initial and
 previous ongoing data for each compound.
 Update QC charts to form a graphic
 representation of continued laboratory
 performance. Develop a statement of
 laboratory accuracy for each pollutant and
 labeled compound in each matrix type
 (reagent water, C-stage filtrate, E-stage
 filtrate, final effluent, etc.) by calculating the
 average percent recovery (R) and the standard
 deviation of percent recovery (sr). Express '
 the accuracy as a recovery interval from R-
 2sr to R + 2sr. For example, if R = 95% and
 sr = 5%, the accuracy is 85 to 105%. •
   9.7 The specifications contained in this
 method can be met if the apparatus used is
 calibrated properly, then maintained in a
 calibrated state. The standards used for
 calibration (Section 10) and for initial
 (Section 9.3.2) and ongoing (Section 9.6)
 precision and recovery should be identical,
 so that the most precise results will be
 obtained. The GCMS instrument in particular
 will provide the most reproducible results if
 dedicated to the settings and conditions
 required for the analyses of chlorophenolics
 by this method.
   9.8  Depending on specific program
 requirements, field replicates may be
 collected to determine the precision of the
 sampling technique, and spiked samples  may
 be required to determine the accuracy of the
 analysis when the internal standard method
 is used.

 10.0  Calibration and Standardization
   10.1  Assemble the GCMS and establish
 the operating conditions in Section 12.
 Analyze standards per the procedure in
 Section 12 to demonstrate that the analytical
 system meets the minimum levels in  Table 2,
 and the mass-intensity criteria in Table 3  for
 SOngDFTPP.
   10.2  Mass-spectral libraries: Detection
 and identification of compounds of interest
 are dependent upon spectra stored in user-
 created libraries.
   10.2.1  Obtain a mass spectrum of the
 acetyl derivative of each chlorophenolic
 compound (pollutant, labeled compound,
 and the sample matrix internal standard) by
 derivatizing and analyzing an authentic
 standard either singly or as part of a mixture
 in which there is no interference between
 closely eluting components. That only a
 single compound is present is determined by
 examination of the spectrum. Fragments not
 attributable to the compound under study
 indicate the presence of an interfering
 compound.                     .
  IQ',2.2  Adjust the analytical conditions
 and scan rate (for this test only) to produce
 an undistorted spectrum at the GC peak
maximum. An undistorted spectrum will   .
usually be obtained if five complete spectra
are collected across the upper half of the GC
peak. Software algorithms designed to
 "enhance" the spectrum may eliminate
 distortion, but may also eliminate authentic
• m/z's or introduce other distortion.
   10.2.3  The authentic reference spectrum
 is obtained under DFTPP tuning conditions
 (Section 10.1 and Table 3) to normalize it to
 spectra from other instruments.
   10.2.4  The spectrum is edited by
 removing all peaks in the m/z 42 to 45 range,
 and saving the five most intense mass
 spectral peaks and all other mass spectral
 peaks greater than 10% of the base peak
 (excluding the peaks in the m/z 42 to 45
 range). The spectrum may be further edited
 to remove common interfering m/z's. The
 spectrum obtained is stored for reverse
 search and for compound confirniation. 10.3
 Minimum level: Demonstrate that the
 chlorophenolics are detectable at the
 minimum level (per all criteria in Section
 14). The nominal 5 ng/mL calibration
 standard (Section 7.13) can be used to
 demonstrate this performance.
   10.4  Calibration with isotope dilution:
 Isotope dilution is used when (1) labeled
 compounds are available, (2) interferences do
 not preclude its use, and (3) the quantitation
 m/z (Table 4) extracted ion-current profile
 (EICP) area for the compound is in the
 calibration range. Alternative labeled
 compounds and quantitation m/z's may be
 used based on availability. If any of the above
 conditions preclude isotope dilution, the
 internal standard calibration method (Section
 10.5) is used.
   10.4.1  A calibration curve encompassing
the concentration range is prepared for each
compound to be determined. The relative
response (pollutant to labeled) vs.
concentration in standard solutions is plotted
or computed using a linear regression. The
example in Figure 1 shows a calibration
curve for'phenol using phenol-d5 as the
isotopic diluent. Also shown are the ±10%
error limits (dotted lines). Relative response
(RR) is determined according to the
procedures described below. A minimum of
five data points are employed for calibration.
   10.4.2  The relative response of a
pollutant to its labeled analog is determined
from isotope ratio values computed from
acquired data. Three isotope ratios are used
in this process:
Rx = the isotope ratio measured for the pure
    pollutant. '
Ry = the isotope ratio measured for the
    labeled compound.
Rm = the isotope ratio of an analytical
    mixture of pollutant and labeled
    compounds.             ,-
  The m/z's are selected such that Rx>Ry. If
Rm is not between 2Ry and 0.5RX, the method
does not apply and the sample is analyzed
by the internal standard method.
10.4.3  Capillary columns sometimes
separate the pollutant-labeled pair when
deuterium labeled compounds are used, with
the labeled compound eluted first (Figure 2).
For this case,

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18740       Federal  Register/Vol.  63, No. 72 /Wednesday. April 15, 1998/Rules and Regulations
                         R
_rareami/zl  ^^retention^gof^poiiutant(RT2).


       	, at the retention time of the labeled compound (RTt).
   aream2/zj

    area aln^/z (at RT2)"| as measured in the mixture of the pollutant and
                                 area atm2/z (at RTj J  labeled compounds (Figure 2), and RR = Rr
  10.4.4  When the pollutant-labeled pair is •
not separated (as occurs with carbon-13-
labeled compounds), or when another
labeled compound with interfering spectral
masses overlaps the pollutant (a case which
can occur with isomeric compounds), it is
necessary to determine the contributions of
the pollutant and labeled compound to the
respective EICP areas. If the peaks are
separated well enough to permit the data
system or operator to remove the
contributions of the compounds to each
other, the equations in Section 10.4.3 apply.
This usually occurs when the height of the
valley between the two GC peaks -at the same
m/z Is less than 70 to 90% of the height of
the shorter of the two peaks. If significant GC
and spectral overlap occur, KR is computed
using the following equation:
              factors (RF) for both the pollutants with no
              labeled analog and for the labeled
              compounds and the SMIS. The response
              factor is defined by the following equation:
              (Ry-Rm)(Rx+l)
Where:
R* Is measured as shown in figure 3A,
J?y is measured as shown in figure 3B,
J?m is measured as shown in figure 3C.
  For example, Rx = 46100/4780 = 9.644; Ry
- 2650/43600 - 0.0608; Rm = 49200/48300 =
1.1019: thus. RR = 1.114. 10.4.5 To calibrate
the analytical system by isotope dilution,
analyze a 1-fiL aliquot of each of the
calibration standards (Section 7.13) using the
procedure in Section 12. Compute the RR at
each concentration.
  10.4.6  Linearity: If the ratio of relative
response to concentration for any compound
Is constant (less than 20% coefficient of
variation) over the five-point calibration
range, an averaged relative response/
concentration ratio may be used for that
compound; otherwise, the complete
calibration curve for that compound shall be
used over the five-point calibration range.
  10.5  Calibration by internal standard: The
method contains two types of internal
standards, the sample matrix internal
standard (SMIS) and the instrument internal
standard (IIS), and they are used for different
quantitative purposes. The 3,4,5-
tiichlorophenol sample matrix internal
standard (SMIS) is used for measurement of
all pollutants with no labeled analog and
when the criteria for isotope dilution
 (Section 10.4) cannot be met. The 2,2'-
difluorobiphenyl instrument internal
standard (OS) is used for determination of the
labeled compounds and the SMIS. The
results are used for intralaboratory statistics
 (Sections 9.4.4 and 9.6.3).
   10.5.1   Response factors: Calibration
requires the determination of response
              Where:
              As=the area of the characteristic mass for the
                  compound in the daily standard.
              .Ais=the area of the characteristic mass for the
                  internal standard.
              Cis=the concentration of the internal standard
                  ((ig/mL).
              C,=is the concentration of the compound in
                  the calibration standard Qig/mL).
                When this equation is used to determine
              the response factors for pollutant compounds
              without labeled analogs, use the area (Ais)
              and concentration (Ck) of 3,4,5-
              trichlorophenol (SMIS) as the internal
              standard. When this equation is used to
              determine the response factors for the labeled
              analogs and the SMIS, use the area (Ais) and
              concentration (Cu) of 2,2'-difluorobiphenyl as
              the internal standard.
                10.5.2  The response factor is determined
              for at least five concentrations appropriate to
              the response of each compound (Section
              7.13); nominally, 5, 10, 20, 50, and 100 \ig/
              mL. The amount of SMIS added to each
              solution is the same (25 Hg/mL) so that Ct,
              remains constant. Likewise, the
              concentration of ns is constant in each
              solution. The area ratio (As/At) is plotted
              versus the concentration ratio (Cj/CiJ for
              each compound in the standard to produce
              a calibration curve.
                10.5.3 Linearity: If the response factor
              (RF) for any compound is constant (less than
              35% coefficient of variation) over the five-
              point calibration range, an averaged response
              factor may be used for that compound;
              otherwise, the complete calibration curve for
              that compound shall be used over the five-
              point range.
                 10.6  Combined calibration: By using
              calibration solutions (Section 7.13)
              containing the pollutants, labeled
              compounds, and the internal standards, a
              single set of analyses can be Used to produce
              calibration curves for the isotope dilution
              and internal standard methods. These curves
              are verified each shift (Section 9) by
              analyzing the OPR standard, or an optional
              calibration verification (VER) standard.
              Recalibration is required only if OPR criteria
              (Section 9.6 and Table 5) cannot be met.
11.0  Sample Derivattzation, Extraction, and
Concentration
  The procedure described in this section
uses a stir-bar in a beaker for the
derivatization. The extraction procedures
applied to samples depend on the type of
sample being analyzed. Extraction of samples
from in-process wastewaters is performed
using a separatoty funnel procedure. All
calibrations, IPR, OPR, and blank-analyses
associated with in-process wastewater
samples must be performed by the separatory
funnel procedure.
  Extraction of samples of final effluents and
raw water may be performed using either the
stir-bar procedure or the separately funnel
procedure. However, all calibrations, IPR,
OPR, blank, and sample analyses must be
performed using the same procedure. Both
procedures are described below.
  11.1  Preparation of all sample types for
stir-bar derivatization.
  11.1.1   Allow sample to warm to room
temperature.
  11.1.2   Immediately prior to measuring,
shake sample vigorously to insure
homogeneity^
  11.1.3   Measure 1000 mL (±10 mL) of
sample into a clean 2000-mL beaker. Label
the beaker with the sample number.
  11.1.4   Dilute aliquot(s).
  11.1.4.1  Complex samples: For samples
that are expected to be difficult to derivatize,
concentrate, or are expected to overload the
GC column or mass spectrometer, measure an
additional 100 mL (±1 mL) into a clean 2000-
mL beaker and dilute to a final volume of
1000-mL (±50 mL) with reagent water. Label
with the sample number and as the dilute
aliquot. However, to ensure adequate
sensitivity, a 1000-mL aliquot must always be
prepared and analyzed.
  11.1.4.2  Pulp and paper industry
samples: For in-process streams such as E-
stage and C-stage filtrates and other in-
process wastewaters, it may be necessary to
prepare an aliquot at an additional level of
dilution. In this case, dilute 10 mL (±0.1 mL)
of sample to 1000-mL (±50 mL).
   11.1.5  QC aliquots: For a batch of samples
of the same type to be extracted at the same
time (to a maximum of 20), place two 1000-
mL (±10 mL)-aliquots of reagent water in
clean 2000-mL beakers. Label one beaker as
the blank and the other as the  ongoing
precision and recovery (OPR) aliquot.
Because final effluent samples are treated
with ascorbic acid and in-process wastewater,
samples are not (see Section 11.11.6), prepare
an OPR aliquot and a blank for the final
effluent and a separate pair for the in-process
samples. Treat these QC aliquots in the same
fashion as the associated samples, adding

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                Federal Register/Vol.  63. No. 72/Wednesday. April  15,  1998/Rules and Regulations       18741
  ascorbic acid to the pair associated with the
  final effluents, and not adding ascorbic acid
  to the pair associated with the in-process
  samples.       .
    11.1.6 Ascorbic acid: Added to stabilize
  chlorocatechols. However, for pulp and
  paper industry in-process streams and other
  in-process wastewaters, the addition of
  ascorbic acid may convert chloro-o-quinohes
  to catechols if these quinoneaare present.
  Separate calibration curves must be prepared
  with and without the addition of ascorbic
  acid (Section 7.13.2).
    11.1.6.1   Spike 5 to 6 mL of the ascorbic
 .acid solution (Section 7.2.2) into each final
  effluent sample, and the associated
  calibration standards, IPR and OPR aliquots,
  and blank.
    11.1.6.2   For pulp and paper industry C-
  stage filtrates, E-stage filtrates, and untreated
  effluents, omit the ascorbic acid to prevent
  the conversion of chloro-o-quinones to
  catechols. Prepare calibration standards, IPR
  and OPR aliquots, and blanks associated with
  these samples without ascorbic acid as well.
    11.1.7  Spike 1000 (iL of the labeled
  compound spiking solution (Section 7.8) into
  the sample and QC aliquots. "
    11.1.8  Spike 500 |iL of the nominal 50 \ig/
.  mL calibration solution (Section 7.13.4) into
  the OPR aliquot
    11.1.9  Adjust the pH of the sample
  aliquots to between 7.0 and 7.1. For
  calibration standards, IPR and OPR aliquots,
  and blanks, pH adjustment is not required.
    11.1.10  Equilibrate all sample and QC
  solutions for approximately 15 minutes, with
  occasional stirring.  .
    11.2   Derivatization: Because
  derivatization must proceed rapidly,
  particularly upon the addition of the K2CO3
  buffer, it is necessary to work with one
 sample at a time until the derivatization step
  (Section 11.2.3) is complete.
    11.2.1 Place a beaker containing a sample
 or QC aliquot on the magnetic stirrer in a
 fume hood, drop a clean stirring bar into the
 beaker, and increase the speed of the stirring
 bar until the vortex is drawn to the bottom
 of the beaker.
    11.2.2 Measure 25 to 26 mL of K2CO3
 buffer into a graduated cylinder or other
 container and 25 to 26 mL of acetic acid into
 another.                                '
    11.2.3 Add the K2CO3 buffer to the
 sample or QC aliquot, immediately (within
 one to three seconds) add the acetic
 anhydride, and stir for three to five minutes
 to complete the derivatization.
    11.3  Extraction: Two procedures are
 described below for the extraction of
 derivatized samples. The choice of extraction
 procedure will depend on the sample type.
 For final effluent samples, either of two
 procedures may be utilized for extraction of
 derivatized samples. For samples of in-
 process wastewaters, the separator/ funnel
 extraction procedure must be used. •
   Note: Whichever procedure is employed,  '
 the same extraction procedure must be used
 for calibration standards, IPR aliquots, OPR
 aliquots, blanks, and the associated field
 samples.
   11.3.1 Stir-bar extraction of final
 effluents:
   11.3.1.1  Add 200 mL (±20 mL) of hexane
 to the beaker and stir for three to five
 minutes, drawing the vortex to the bottom of
 the beaker.
   11.3.1.2  Stop the stirring and drain the
 hexane and a portion of the water into a 500-
 to IQOO-mL separatory funnel. 'Allow the
 layers to separate.
   11.3.1.3  Drain the aqueous layer back into
 the beaker.
   .11.3.1.4  The formation of emulsions can
 be expected in any solvent extraction
 procedure. If an emulsion forms, the
 laboratory must take steps to break the
 emulsion before proceeding. Mechanical
 means of breaking the emulsion include the
 use of a glass stirring rod, filtration through
 glass wool, and other techniques. For
 emulsions that resist these techniques,
 centrifugation is nearly 100% effective.
   If centrifugation is employed to break the
 emulsion, drain the organic layer into a
 centrifuge tube, cap the tube, and centrifuge
 for two to three minutes or until the phases
 separate. If the emulsion cannot be
 completely broken, collect as much of the
 organic phase as possible, and measure and  .
 record the volume of the organic phase
 collected.
 ; If all efforts to break the emulsion fail,
 including centrifugation, and none of the
 organic phase can be collected, proceed with
 the dilute aliquot (Section 11.1.4.2).
 However, use of the dilute aliquot will
 sacrifice the sensitivity of the method, and
 may not be appropriate in all cases.
   11.3.1.5 Drain the organic layer into a
 Kuderna-Danish (K-D) apparatus equipped
 with a 10-mL concentrator tube. Label the K-
 D apparatus. It may be necessary to pour the
 organic layer through a funnel containing
 anhydrous sodium sulfate to remove any
 traces of water from the extract.
   11.3.1.6  Repeat the extraction (Section
 11.3.1.1 through 11.3.1.5) two moretimes
 using another 200-mL of hexane for each
 extraction, combining the extracts in the K-
 D apparatus.
   11.3.1.7  Proceed with concentration of
 the extract, as described in Section 11.4.
   11.3.2  Separatory funnel extraction of
 either final effluents or in-process
 wastewaters.
   11.3.2.1  Transfer the derivatized sample
 or QC aliquot to a 2-L separatory funnel.
   11.3.2.2  Add 200 mL (±20 mL) of hexane
 to the separatory funnel. Cap the funnel and
 extract the sample by shaking the funnel for
 two to three minutes with periodic venting.
   11.3.2.3  Allow the organic layer to
 separate from the water phase for a minimum
 of 10 minutes.
   11.3.2.4  Drain the lower aqueous layer
 into the beaker used for derivatization
 (Section 11.2), or into a second clean 2-L
 separatory funnel. Transfer the solvent to a
 1000-mL K-D flask. It may be necessary to
 pour the organic layer through a funnel
 containing anhydrous sodium sulfate to
 remove any traces of water from the extract.
   11.3.2.5  The formation of emulsions can
 be expected in any solvent extraction
procedure. If an emulsion forms, the
 laboratory must take steps to break the
 emulsion before proceeding. Mechanical
means of breaking the emulsion include the
use of a glass stirring rod, filtration through
glass wool, and other techniques. For
 emulsions that resist these techniques,
 centrifugation may be required.
   If centrifugation is employed to break the
 emulsion, drain the organic layer into a .
 centrifuge tube, cap the tube, and centrifuge
 for two to three minutes or until the phases
 separate. If the emulsion cannot be
 completely broken, collect as much of the
 organic phase as possible, and measure and
 record the volume of the organic phase
 collected. If all efforts to break the emulsion,
 including centrifugation; fail and none of the
 organic phase can be collected, proceed with
 the dilute aliquot (Section 11.1.4.2).
 However, use of the dilute aliquot will
 sacrifice the sensitivity of the method, and
 may not be appropriate in all cases.
   11.3.2.6 If drained into a beaker, transfer
 the aqueous layer to the 2-L separatory .
 funnel (Section 11.3.2.1). Perform a second
 extraction using another 200 mL of fresh
 solvent.
   11.3.2.7 Transfer the extract to the 1000-
 mL K-D flask in Section 11.3.2.4.
   11.3.2.8 Perform a third extraction in the
 same fashion as above.
,  11.3.2.9 Proceed with concentration of
 the extract, as described in Section 11.4.
   11.4  Macro concentration: Concentrate
 the extracts in separate 1000-mL K-D flasks
 equipped with 10-mL concentrator tubes.
 Add one to two clean boiling chips to the
 flask and attach a three-ball macro-Snyder
 column. Prewet-the column by adding
 approximately 1 mL of hexane through the
 top. Place the K-D apparatus in a hot water
 bath so that the entire lower rounded surface
 of the flask is bathed with steam. Adjust the
 vertical position of the apparatus and the
 water temperature as required to complete
 the concentration in 15 to 20 minutes. At the
proper rate of distillation, the balls of the
 column will actively chatter but the
 chambers will not flood. When the liquid has
reached an apparent volume of 1 mL, remove
the K-D apparatus from the bath and allow
the solvent to drain and cool for at least 1.0
minutes. Remove the Snyder column and
rinse the flask and its lower joint into the
concentrator tube with 1 to 2 mL of hexane.
A 5-mL syringe is recommended for "this
operation.                    '
  11.5  Micro-concentration: Final
concentration of the extracts may be
accomplished using either a micro-Snyder  '
column or nitrogen evaporation.
  11.5.1   Micro-Snyder column: Add a clean
boiling chip and attach a two-ball micro-
Snyder column to the concentrator tube.
Prewet the column by adding approximately
0.5 mL hexane through the top. Place the
apparatus in the hot water bath. Adjust the
vertical position and the water temperature
as required to complete the concentration in
5 to 10 minutes. At the proper rate of
distillation, the balls of the column will
actively chatter but the chambers will not
flood. When the liquid reaches an apparent
volume of approximately 0.2 mL, remove the
apparatus from the water bath and allow to
drain and cool for at least 10 minutes.
Remove the micro-Snyder column and rinse
its lower joint into the concentrator tube with
approximately 0.2 mL of hexane. Adjust to a
final volume of 0.5 mL.
  11.5.2   Nitrogen evaporation: Transfer the
concentrator tube to a nitrogen evaporation

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Federal Register/Vol. 63,  No. 72/Wednesday, April 15,  1998/Rules and  Regulations
device and direct a gentle stream of clean dry
nitrogen Into the concentrator. Rinse the
sides of the concentrator tube with small
volumes of hexane. and concentrate the
extract to a final volume of 0.5 mL.
  11.6  Spike each extract with 10 nL of the
2,2'-difluorobiphenyl HS (Section 7.10) and
transfer the concentrated extract to a clean
screw-cap vial using hexane to rinse the
concentrator tube. Seal the vial with a PTFE-
llncd lid, and mark the level on the vial.
Label with the sample number and store in
the dark at -20 to -10 °C until ready for
analysis.
12.0  GCMS Analysis
  12.1  Establish the following operating
conditions:
Carrier gas flow: Helium at 30 cm/sec at 50 °C
Injector temperature: 300 °C
Initial temperature: 50 °C
Temperature program: 8 °C/min to 270 °C
Final hold: Until after 2.6-
  dichlorosyrlngaldehyde elutes
  Adjust the GC conditions to meet the '
requirements in Section 9.6.1.1 and Table 2
for analyte separation and sensitivity. Once
optimized, the same GC conditions must be
used for the analysis of all standards, blanks,
IPR and OPR aliquots, and samples.
  12.2  Bring the concentrated extract
(Section 11.6) or standard (Sections 7.13 and
7.14) to room temperature and verify that any
precipitate has redissolved. Verify the level
on the extract (Sections 7.13, 7.14, and 11.6)
and bring to the mark with solvent if
required.
  12.3  Inject a 1-jtL volume of the standard
solution or extract using on-column or
spMess injection. For 0.5 mL extracts, this
1-HL Injection volume will contain 50  ng of
the DFB internal standard. If an injection
volume other than 1 fiL is used, that volume
must contain 50 ng of DFB.
  12.4  Start the GC column temperature
ramp upon injection. Start MS data collection
after the solvent peak elutes. Stop data
collection after the 2,6-
dlchlorosyringaldehyde peak elutes. Return
the column to the initial temperature for
analysis of the next sample.
13.0  Analysis of Complex Samples
  Some samples may contain high levels
(>1000 Hg/L) of the compounds of interest,
Interfering compounds, and/or other
phenolic materials. Some samples will not
concentrate to 0.5 mL (Section 11.5); others
will overload the GC column and/or mass
spectrometer, others may contain amounts of
phenols that may exceed the capacity  of the
derlvatizing agent
  13.1  Analyze the dilute aliquot (Section
11.1.4) when the sample will not concentrate
to 0.5 mL, If a dilute aliquot was not
extracted, and the sample holding time
(Section 8.4) has not been exceeded, dilute
an aliquot of sample with reagent water, and
derlvatize and extract it (Section 11.1.4).
Otherwise, dilute the extract (Section  14.7.3)
and quantitate it by the internal standard
method (Section 14.3).
  13.2  Recovery of the 2,2'-
difluorobiphenyl instrument internal
standard: The EICP area of the internal
standard should be within a factor of two of
                             the area in the OPR or VER standard (Section
                             9.6). If the absolute areas of the labeled
                             compounds and the SMIS are within a factor
                             of two of the respective areas in the OPR or
                             VER standard, and the DFB internal standard
                             area is less than one-half of its respective
                             area, then internal standard loss in the
                             extract has occurred. In this case, analyze the
                             extract from the dilute aliquot (Section
                             11.1.4).
                               13.3  Recovery of labeled compounds and
                             the sample matrix internal standard (SMIS):
                             SMIS and labeled compound recovery
                             specifications have been developed for
                            -samples with and without the addition of
                             ascorbic acid. Compare the recoveries to the
                             appropriate limits in Table 5.
                               13.3.1  If SMIS or labeled compound
                             recoveries are outside the limits given in
                             Table 5 and the associated OPR analysis
                             meets the recovery criteria, the extract from
                             the dilute aliquot (Section 11.1.4) is analyzed
                             as in Section 14.7.
                               13.3.2  If labeled compound or SMIS
                             recovery is outside the limits given in Table
                             5 and the associated OPR analysis did not
                             meet recovery criteria, a problem in the
                             derivatization/extraction/concentration of the
                             sample is indicated, and the sample must be
                             rederivatized and reanalyzed.

                             14.0  Data Analysis and Calculations
                               14.1   Qualitative determination:
                             Identification is accomplished by comparison
                             of data from analysis of a sample or blank
                             with data stored in the mass spectral
                             libraries. Identification of a compound is
                             confirmed when the following criteria are
                             met:
                               14.1.1  The signals for m/z 43 (to indicate
                             the presence of the acetyl derivative) and all
                             characteristic m/z's stored in the spectral
                             library (Section 10.2.4) shall be present and
                             shall maximize within the same two
                             consecutive scans.
                               14.1.2  Either (1) the background corrected
                             EICP areas, or (2)  the corrected relative
                             intensities of the mass spectral peaks at the
                             GC peak maximum shall agree within a factor
                             of two (0.5 to 2 times) for all m/z's stored in
                             the library.
                               14.1.3  The relative retention time shall be
                             within the window specified in Table 2.
                               14.1.4  The m/z's present in the mass
                             spectrum from the component in the sample
                             that are not present in the reference mass
                             spectrum shall be accounted for by
                             contaminant or background ions. If the mass
                             spectrum is contaminated, an experienced
                             spectrometrist  (Section 1.4) shall determine
                             the presence or absence of the compound.
                               14.2  Quantitative determination by
                             isotope dilution: By adding a known amount
                             of a labeled compound to every sample prior
                             to derivatization and extraction, correction
                             for recovery of the pollutant can be made
                             because the pollutant and its labeled analog
                             exhibit the same effects upon derivatization,
                             extraction, concentration, and gas
                             chrbmatography.  Relative response (RR)
                             values for sample mixtures are used in
                             conjunction with calibration curves
                             described in Section 10.4 to determine
                             concentrations directly, so long as labeled
                             compound spiking levels are constant. For
                             the phenol example given in Figure 1
(Section 10.4.1), RR would be equal to 1.114.
For this RR value, the phenol calibration
curve given in Figure 1 indicates a
concentration of 27 (ig/mL in the sample
extract (Co*)-
  14.2. 1  Compute the concentration in the
extract using the response ratio determined
from calibration data (Section 10.4) and the
following equation:
= (An
                                xRR
Where:
Cex = concentration of the pollutant in the
    extract.
An = area of the characteristic m/z for the
    pollutant.
Ci = concentration of the labeled compound
    in the extract.
Ai = area of the characteristic m/z for die
    labeled compound.
RR = response ratio from the initial
    calibration.
  14.2.2  For the IPR (Section 9.3.2) and
OPR (Section 9.6), compute the percent
recovery of each pollutant using 'the equation
in Section 14.6. The percent recovery is used
for the evaluation of method and laboratory
performance, in the form of IPR (Section
9.3.2) and OPR (Section 9.6).
  14.3  Quantitative determination by
internal standard: Compute the concentration
using the response factor determined from
calibration data (Section 10.5) and the
following equation:
               = (As xCis)/(Ais xRF
Where:
Cex = concentration of the pollutant in the
    extract.
As = area of the characteristic m/z for the
    pollutant.
Cjs = concentration of the internal standard
    in the extract (see note below).
AjS = area of the characteristic rn/z for the
    internal standard.
RF = response factor from the initial
    calibration.
  Note: When this equation is used to
compute the extract concentrations of native
compounds without labeled analogs, use the
area (A;s) and concentration (Qs) of 3,4,5-
trichlorophenol (SMIS) as the internal
standard.
  For the IPR (Section 9.3.2) and OPR
(Section 9.6), compute the percent recovery
using the equation in Section 14.6.
  Note: Separate calibration curves will be
required for samples with and without the •
addition of ascorbic acid, and also for both
extraction procedures (stir-bar and separatory
funnel) where applicable.
  14.4  Compute the concentration of the
labeled compounds and the SMIS using the
equation in Section 14.3, but using the area
and concentration of the 2,2'-
difluorobiphenyl as the internal standard,
and the area of the labeled compound or
SMIS as As.
  14.5  Compute the concentration of each
pollutant compound in the sample using the
following equation:

-------
               Federal Register/Vol. 63. No. 72/Wednesday,  April  15, 1998/Rules and  Regulations       18743
 Where:
 Cs = Concentration of the pollutant in the
     sample.    •            .
Ce* = Concentration of the pollutant in the
    extract        ,               .
Vex = Volume of the concentrated extract
    (typically 0.5 mL).
V0 = Volume of the original sample in liters.
                                             14.6  Compute the recovery of each
                                           labeled compound and the SMIS as the ratio
                                           of concentration (or amount) found to the
                                           concentration (or amount) spiked, using the
                                           ^following equation:
                                         Percent recovery =
                 Concentration found
                 Concentration spiked
                                     xlOO
   These percent recoveries are used to assess
 method performance according to .Sections 9
 and 13.   .
   14.7  If the EICP area at the quantitation
 m/z for any compound exceeds the
 calibration range of the system, three
 approaches are.used to obtain results within
 the calibration range.
   14.7.1  If the recpveries of all the labeled
 compounds in the original sample aliquot
 meet the limits in Table 5, then the extract
 of the  sample may be diluted by a maximum
 of a factor of 10, and the diluted extract
 reanalyzed.    l  .  .    .
   14.7.2  If the recovery of any labeled
 compound is outside its limits in Table 5, or
 if a tenfold dilution of the extract will not
 bring the pollutant within the calibration
 range, then extract and analyze a dilute
 aliquot of the sample (Section 11). Dilute 100
 mL, 10 mL, or an appropriate volume of
 sample to 1000 mL with reagent: water and,
 extract per Section 11.
   14.7.3  If the recoveries of all labeled
 compounds in the original sample aliquot
 (Section 14.7.1) meet the limits in Table 5,
 and if the sample holding time has been
 exceeded, then the original sample extract is
 diluted by successive factors of 10, the DFB
'internal standard is added to give a       ,
 concentration of 50 ng/mL in the diluted
 extract, and the diluted extract is analyzed.
 Quantitation of all analytes is performed
 using the DFB internal standard.
   14.7.4  If the recoveries of all  labeled
 compounds in the original sample aliquot
 (Section 14.7.1) or in the dilute aliquot
 (Section 14.7.2) (if a dilute aliquot was
 analyzed) do not meet the limits in Table 5,
 and if the holding time has been exceeded,
 re-sampling is required.
   14.8  Results are reported  for all
 pollutants, labeled compounds, and the
 sample matrix internal standard in standards,
 blanks, and samples, in units of Hg/L.
   14.8.1  Results for samples which have
 been diluted are reported at the least dilute
 level at which the area at the  quantitation m/
 z is within the calibration range (Section
 14.7).
   14.8.2  For compounds having a labeled
 analog, results are reported at the least dilute
 level at which the area at the  quantitation m/
 z is within the calibration range (Section
 14.7) and the labeled compound recovery is
 within the normal range for the method
 (Section 13.3).

 15.0  Method Performance
   15.1  Single laboratory performance for
 this method is detailed in References 1,2,
 and 11. Acceptance criteria were established
 from multiple laboratory use of the draft
 method.
   15.2  A chromatogram of the ongoing
 precision and recovery standard (Section
 7.14) is shown in Figure 4.

 16.0  Pollution Prevention
   16.1  The solvents used in this method
 pose little threat to the environment when
 recycled and managed properly.
   16.2  Standards should be prepared in
 volumes consistent with laboratory use to
 minimize the volume of expired standards to
 be disposed.

 17.0  Waste Management
   17.1   It is the laboratory's responsibility to
 comply with all federal, state, and local
 regulations governing waste management,
 particularly the hazardous waste
 identification rules and land disposal
 restrictions, and to protect the air, water, and
 land by minimizing and controlling all
 releases from fume hoods and bench
 operations. Compliance with all sewage
 discharge permits and regulations is also
 required.
   17.2   Samples preserved with HC1 or
 HzSO4 to pH < 2 are hazardous and must be
 neutralized before being disposed, or must be
 handled as hazardous waste.
   17.3   For further information on waste
 management, consult "The Waste
 Management Manual for Laboratory
 Personnel"', and "Less is Better: Laboratory
 Chemical Management for Waste Reduction",
 both available from the American Chemical
 Society's Department of Government
 Relations and Science Policy, 1155 16th
 Street N.W., Washington, D.C. 20036.

 18.0 References
   18.1   "Chlorinated Phenolics in Water by
 In Situ Acerylation/GC/MS Determination,"
 Method CP-86.01, National Council of the
 Paper Industry for Air and Stream
 Improvement, Inc., 260 Madison Avenue,
New.York, NY 10016 (July 1986).  .
                                            18.2  "6240-Chlorinated Phenolics
                                          (Interim Standard)," Draft Version, U.S.
                                          Environmental Protection Agency,
                                          Manchester Laboratory, Manchester,
                                          Washington.
                                            18.3  "Performance Tests for the
                                          Evaluation of Computerized Gas
                                          Chromatography/Mass Spectrometry
                                          Equipment and Laboratories," USEPA, EMSL
                                          Cincinnati, OH 45268, EPA-600/4-80-025
                                          (April 1980).
                                            18.4  "Working with Carcinogens,"
                                          DREW, PHS, CDC, NIOSH, Publication 77-
                                          206 (August 1977).
                                            18.5  "OSHA Safety and Health
                                          Standards, General Industry," OSHA 2206,
                                          29 CFR1910 (January 1976).
                                            18.6  "Safety in Academic Chemistry
                                          Laboratories," ACS Committee on Chemical
                                          Safety (1979).
                                            18.7   "Intel-laboratory Validation of U. S>
                                          Environmental Protection Agency Method
                                          1625A, Addendum Report," SRI
                                          International, Prepared for Analysis'and
                                          Evaluation Division (WH-557), USEPA, 401
                                          M St. SW, Washington, DC 20460 (January
                                          1985).
                                            18.8  "Handbook of Analytical Quality
                                          Control in Water and Wastewater
                                          Laboratories," USEPA, EMSL, Cincinnati, OH
                                          45268, EPA-600/4-79-019 (March 1979).
                                            18.9  "Standard Practice for Sampling
                                          Water," ASTM Annual Book of Standards,
                                          ASTM, Philadelphia, PA, 76 (1980).
                                            18.10  "Methods 330.4 and 330.5 for Total
                                          Residual Chlorine," USEPA, EMSL,
                                          Cincinnati, OH 45268, EPA 600/4-70-020
                                          (March 1979).
                                            18.11  "Determination of Chlorophenolics,
                                          Special Analytical Services Contract 1047,
                                          Episode 1886," Analytical Technologies, Inc.,
                                          Prepared for W. A. Telliard, Industrial
                                          Technology Division (WH-552), USEPA, 401
                                          M St. SW, Washington, DC 20460 (June
                                          1990).
                                          ., 18.12 . "Determination of Chlorophenolics
                                          by GCMS, Development of Method 1653,"
                                          Analytical Technologies, Inc., Prepared for
                                          W. A. Telliard, Industrial Technology
                                          Division (WH-552), USEPA, 401 M St. SW,
                                          Washington, DC 20460 (May 1991).

                                          19,0  Tables and Figures

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18744       Federal Register/Vol.  63, No.  72/Wednesday;.April 15,  1998/Rules and Regulations
 TABLE 1.—CHLOROPHENOLIC COMPOUNDS DETERMINED BY GCMS  USING ISOTOPE DILUTION AND INTERNAL STANDARD
                                                        TECHNIQUES
                         Compound
                                                                      Pollutant
                                                              CAS registry    EPA-EGD
                                                                                   Labeled compound
                                                                           Analog    CAS registry    EPA-EGD
4-chtorophenol	      106-48-9
2,4-dfchloropbenol 	      120-83-2
2,6-dichlorophenol 	       87-65-0
2,4,5-trichlorophenol —,	       95-95-4
2,4,6-trichlorophenol	       88-06-2
2,3,4,6-tetrachlorophenol	       58-90-2
pentachtorophenol	       87-86-5
4-chtoroguaIaco) 	    16766-30-6
3,4-dfchIorogualacoI	    77102-94-4
4,5-dlchloroguaIacoI	     2460-19-3
4,6-cflchloroguaiacoI	    16766-31-7
3,4,5-trichloroguaiacol 	    57057-83-7
3,4,6-trichloroguaIacol 	    60712-44-9
4,5,6-trichIoroguaiacol 	'.	     2668-24-8
telrachlorogualacol 	     2539-17-5
4-chlorocatechol	     2138-22-9
3,4-dichlorocatechol	     3978-67-4
3,6-dlchIorocatechol	     3938-16-7
4,5-dichlorocatechol	     3428-24-8
3,4,5-trichlorocatechol 	    56961-20-7
3,4,6-trichlorocatechol 	:.	    32139-72-3
telrachlorocatochol	     1198-55-6
5-chlorovanillin	    19463-48-0
6-chtorovanillIn	    18268-76-3
5,6-d!chlorovanillin	    18268-69^1
2-chlorosyringafdehyde	    76341-69-0
2,6-dichIorosyringaldehyde	    76330-06-8
trichlorosyringol	     2539-26-6
             Sample matrix internal standard (SMIS)
3,4,5-trichlorophenoI	      609-19-8
                Instrument internal standard (IIS)
212'-difluorob?phenyl	      388-82r9
                                                                    1001
                                                                    1002
                                                                    1003
                                                                    1004
                                                                    1005
                                                                    1006
                                                                    1007
                                                                    1008
                                                                    1009
                                                                    1010
                                                                    1011
                                                                    1012
                                                                    1013
                                                                    1014
                                                                    1015
                                                                    1016
                                                                    1017
                                                                    1018
                                                                    1019
                                                                    1020
                                                                    1021
                                                                   ,1022
                                                                    1023
                                                                    1024
                                                                    1025
                                                                    1026
                                                                    1027
                                                                    1028
                                                                     184


                                                                     164
                           13C6
                           I3C6
                           13C6
                           13C6
                                        93951-74-7
                          85380-74-1
                         136955-39-0
                         136955-40-3
                         136955-41-4
                                       136955-42-5
                         136955-43-6
                         136955-^4-7
                                             1102
                                1107
                                1108
                                1114
                                1115
                                             1119
                                1122
                                1123
               TABLE 2.—GAS CHROMATOGRAPHY AND METHOD DETECTION LIMITS FOR CHLOROPHENOLICS
  EGD No.'
                 Compound
 Retention
time mean
  (sec) 2 .
 EGD
ref NO.
  RRT
window3
  Minimum
level4 (ng/L)
                                                                                                                    MDL5
1001  	
1003  	
1102  	
1202  	
164 	
1108  	
1208  	
1005  	
1004  	
1016  	:..
1011  	
1009  	
184 	
1010  	
1018  	
1006  	
1123  	
1223  	
1013  	
1024  	
1017  	
1119  	
1219  	
1012  	
1114  	
1214  	
1021  	
1025  	
4-chlorophenol 	
2,6-dichlorophenol 	
2,4-dichlorophenoi-d3	
2,4-dichlorophenol 	
2,2'-difluorobiphenyl (I.S.) ...
4-chloroguaiacol-13C6	
4-chIoroguaiacoI	
2,4,6-trichIorophenol 	
2,4,5-trichlorophenol 	
4-chlorocatechol	
4.6-dichIoroguaiacol	
3,4-dichloroguaiacol	
3,4,5-trichIorophenol (I.S.) ..
4,5-dichloroguaiacol	
3,6-dichlorocatechol	
2,3,4,6-tetrachlorophenol ....
5-chlorovanillin-I3Cs	
5-chtorovanillin 	
3,4,6-trichIoroguaiacol	
6-chIorovanilIin 	
3,4-dichlorocatechol	
4,5-dich!orocatechol-13C6 ....
4,5-dichlorocatechol	
3,4,5-trichloroguaiacol	
4,5,6-trichloroguaiacol-13Cs .
4,5,6-trichloroguaiacol	
3,4,6-trichlorocatechol	
5,6-dlchlorovanillin ....1	
       691
       796
       818
       819
       825
       900
       900
       920
       979
      1004
      1021
      1029
      1037
      1071
      1084
      1103
      1111
      1111
      1118
      1122
      1136
      1158
      1158
      1177
      1208
      1208
      1213
      1246
     184
     184
     164
    1102
     164
     164
    1108
     184
     184
     184
     184
     184
     164
     184
     184
     184
     164
    1123
     184
     184
     184
     164
    1119
     184
     164
    1114
     184
     184
0.651-0.681
0.757-0.779
0.986-0.998
0.997-1.006
      1.000
1.077-1.103
0.998-1.002
0.879-0.895
0.936-0.952
0.961-0.975
0.979-0.991
0.986-0.998
1.242-1.272
1.026-1.040
1.037-1.053
1.050-1.078
1.327-1.367
0.998-1.001
1.066-1.090
1.070-1.094
1.083-1.105
1.384-1.424
0.998-1.001
1.120-1.160
1.444-1.484
0.998-1.002
1.155-1.185
1.182-1.222
        1.25
        2.5

        2.5
        1.25
        2.5
        2.5
        1.25
        2.5
        2.5

        2.5
        2.5
        2.5

        2.5
        2.5
        2.5
        2.5

        2.5
        2.5

        2.5
        5.0
        5.0
1.11
1.39

0.15
0.09
0.71
0.5?
0.59
0.45
0.52

0.52
0.57
0.38

1.01
0.46
0.94
0.60

0.24
0.49

0.25
0.44
0.80

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               Federal Register/Vol.  63.. No. 72/Wednesday,  April  15, 1998/Rules and Regulations     .  18745

         TABLE 2.—GAS CHROMATOGRAPHY AND METHOD DETECTION LIMITS FOR CHLOROPHENOLICS—Continued
   EGD No.1
                                 Compound
                                                Retention
                                               time mean
                                                , (sec)2
          EGD
         ref No.
           RRT
         window3
               Minimum
              level4 (jig/L)
                                                                                                                      MDLs
 1026 ,
 1107 .
 1207 .
 1020 .
 1115 .
 1215 .
 1028 .
 1122 .
 1222 .
 1027 .
2-chlorosyringaldehyde	
pentachlorophenol-13Cs 	
pentachlorophenol .............
3,4,5-trichlorocatechol	
tetrachloroguaiacol-13C6	
tetrachloroguaiacol	
trichlorosyringol	
tetrachlorocatechol-13Cs	
tetrachlorocatechol'.	
2,6-dichlorosyringaldehyde
1255
1267
1268
1268
1289
1290
1301
1365
1365
1378
 184
 164
1107
 184
 164
1115
 184
 164
1122
 184
 1.190-1.230
.1.511-1.561
 0.998-1.002
 1.208-1.238
 1:537-1.587
 0.998-1.002
 1.240-1.270
 1.630-1.690
 0.998-1.002
 1.309-1.349
2.5

5.0.
5.0

5.0
2.5

5.0
5.0
0.87

0.28
0.53

0.23
0.64

0.76
1.13
   1 Four digit numbers beginning with 10 indicate a pollutant quantified by the internal standard method; four digit numbers beginning with 11 in-
 dicate alabeled compound quantified by the internal standard method; four digit numbers beginning with 12 indicate a pollutant quantified by iso-
   2Jhe retention times in this column are based on data from a single laboratory (reference 12), utilizing the GC conditions in Section 11.
   3 Relative retention time windows are estimated from EPA Method 1625.'                              •.          .
   *The minimum level (ML) is defined as the level at which the entire analytical system must give a recognizable signal and acceptable calibra-
 tion  point for the analyte. It is equivalent to the concentration of the lowest calibration standard, assuming that all method-specified sample
 weights, volumes, and cleanup procedures have been employed.                                                       OHW.MWU ocmi^e
   5 40 CFR Part 136, Appendix B; from reference 2.

                                   TABLE 3.—DFTPP MASS INTENSITY SPECIFICATIONS 1
                                             Mass
                                                                                                        Intensity required
51  ..
68  ..
69  ..
70  ..
127
197
198
199
275
'441
442
443
                                                                                  8 to 82% of m/z 198.
                                                                                  Less than 2% of m/z 69.
                                                                                  11 to 91% of m/z 198.
                                                                                  Less than 2% of m/z 69.
                                                                                  32 to 59% of m/z 198.
                                                                                  Less than 1% of m/z 198.
                                                                                  Base peak, 100% abundance.
                                                                                  4 to 9% of m/z 198.
                                                                                  11 to 30% of m/z 198.
                                                                                  44 to 110% of m/z 443.
                                                                                  30 to 86% of m/z 198.
                                                                                  14 to 24% of m/z 442.
  1 Reference 7.
                           TABLE 4.—CHARACTERISTIC M/Zs OF CHLOROPHENOLIC COMPOUNDS
                                                   Compound
                                                                                                                  Primary m/z
4-chlorophenol
2,4-dichlorophenol	
2,4-dichlor6phenol-d3
2,6-dichlorophenol	
2,4,5-trichlorophenol
2,4,6-trichlorophenol
2,3,4,6-tetrachlorophenol
pentachlorophenol
pentachlorophenol-13Cs
4-chloroguaiacol	
4-chloroguaiacol-13C6
3,4-dichloroguaiacol 	
4,5-dichloroguaiacol
4,6-dichloroguaiacol	,
3i4,5-trichloroguaiacol
3,4,6-trichloroguaiacol	'.
4,5,6-trichloroguaiacol	
4,5,6-trichloroguaiacq|-13C6
tetrachloroguaiacol	
tetrachloroguaiacol~13C6 	
4-chlorocatechol 	
3,4-dichlorocatechol
3,6-dichlorocatechol	
4,5-dichlorocatechol
4,5-dichlorocatechoI-13C6 	
3,4,5-trichlorocatechol
3,4,6-trichlorocatechol
                                                                                                           128
                                                                                                           162
                                                                                                           167
                                                                                                           162
                                                                                                           196
                                                                                                           196
                                                                                                           232
                                                                                                           266
                                                                                                           272
                                                                                                           158
                                                                                                           164
                                                                                                           192
                                                                                                           192
                                                                                                           192
                                                                                                           226
                                                                                                           226
                                                                                                           226
                                                                                                           234
                                                                                                           262
                                                                                                           268
                                                                                                           144
                                                                                                           178
                                                                                                           178
                                                                                                           178
                                                                                                           184
                                                                                                           212
                                                                                                           212

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18746
Federal  Register/Vol.  63, No.  72/Wednesday, April  15, 1998/Rules and Regulations
                    TABLE 4.—CHARACTERISTIC M/Zs OF CHLOROPHENOLIC COMPOUNDS—Continued
Compound

tolraohlorocatechol~13C6 	 •'• 	 ••—• 	

5"Ch!orovanilltn""13C6 . 	 • 	 * 	

5 6"d!chlorovanillin 	 • 	 • 	 •• 	 - 	



Sample Matrix Internal Standard (SMIS)
Instrument Internal Standard (IIS)
g^-difluoroblphenyl 	 '. 	 • 	

Primary m/z
248
254
* . 186
192
186
220
216
250
256
196
190

                              TABLE 5.—ACCEPTANCE CRITERIA FOR PERFORMANCE TESTS 1
EGD No.a
1001
1202
1102 .
1003 . — . 	
1004 	 	
1005
1006 	
1207 .................
1107 . 	 . 	
1208 	 „. .
1108 	
1009 	 	
1010 	 .....
1011 	
1012 	
1013 	 „..
1214 	 „„.
1114 	
1215 	 	
1115 ......... 	
1016 .................
1017 	
1018 	
1219 .„. 	 	
1119 	
1020 .................
1021 	
1222 	 	
1122 .................
1223 	
1123 	
1024 	
1025 	
1026 	
1027 	 „
1028 	 	
Compound




2 4 5-trich!oroph9no! 	
2 4 6-trfchtorophenol 	 ." 	
234 6-totiachlorophenol 	
pontachlorophenol ....... 	 . 	 	 	


4-chIoroguaiacol-13C6 	


4l6-dicf)!oroguaiacol 	

3 4 6-trfchlofoguafacol 	

4 5 6-trichloroguaiacol-13C6 ° 	

t3trach!oroo,uaiacol-13C6 	
4-chtorocatechol 	
3,4-dichlorocatechol 	

4 5-dichlorocatechol ... 	 .?. 	 	 	
4,5-dichIorocatechol-13Ce 	

3,4 6-tiichIorocatechol4 	
tetfachlorocatechol 	 	 	
tetrachlorocatechol-13C6 	 •• 	
Srchlorovanillin 	

6-chtorovaniUin 	
5,6-dichlorovanillin 	

2,6-dichIorosyringaldehyde 	
trichtorosyringo! 	

Test
cone.3
(ug/mL)
25
50
25
50
50
50
50
100
25
25
25
50
50
50
50
50
50
25
100
25
25
50
50
50
25
100
100
100
25
50
25
50
100
50
100
50
Initial precision and
recovery sec. 9.3.2
(percent)
s
64
14
54
20
14
20
14
6
21
20
104
18
14
16
16
16
14
48
7
22
48
24
16
8
78
17
17
29
39
20
84
22
9
28
14
18
X
72 144
84-120
64-160
66-148
78-140
72-142
80-132
90-111
58-169
88-120
68-148
80-126
82-121
82-126
78-130
64-152
92-106
66-146
84-115
57 173
76-140
66-154
78-136
84-118
68-144
60-166
74-138
46-234
48-227
94-208
68-160
82-128
67-146
76-130
82-129
76-136
Ongoing
recovery
sec. 9.6
(percent)
40-236
84-118
56-170
58-170
82-128
72-146
82-132
, 84-120
61-157
88-120
64-152
82-126
80-128
86-120
80-134
74-140
88-116
74-140
81-126
65-161
80-124
78-134
84-126
86-122
66-142
72-128
64-149
81-132
63-152
84-118
70-144
80-126
77-140
72-156
60-183
66-174
Labeled compound
and SMIS recovery
sec. 9.4 and 14.6
With
ascorbic
acidP
(%)
58-135
8-143
59-121
48-131
35-120
33-129
14-118
51-126
Without
ascorbic
acidP
(%)
27-143
27 167
43-168
51-139
27-161
0-190
0-184
32-254
                                                 Sample Matrix Internal Standard
184 	
3 4 5-tr!chIorophenoI 	
. 100
47
62-185
68-144
56-116
24-167
  1 Specifications derived from multi-laboratory testing of draft method.
  * Four-digit numbers beginning with 10 indicate a pollutant quantified by the internal standard method; four-digit numbers beginning with 11 indicate a labeled com-
pound quantified by ths internal standard method; four-digit numbers beginning with 12 indicate a pollutant quantified by isotope dilution.
  3 Test concentrations are in units of |ig/mL.
  'Specification derived from isomer.
BILLING CODE 6560-5O-P

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Federal Register/Vol. 63.  No. 72/Wednesday. April 15. 1998/Rules and Regulations      18747



           	1	——:	»
    10 -
    1.0 -
    0.1 -
                                               _t_—	1
                                10     20       50




                              Coneantration (|ig/mL)
100   200
                     The dotted lines enclose a ±10% error window.
                                                                        52-020-21A
          Figure 1.  Relative Response Calibration Curve for Phenol

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18748     Federal Register/Vol. 63, No. 72/Wednesday, April 15,  1998/Rules and Regulations


                      Area at
                      M,/Z
              Area at
               Area at
                                                                    Area at
                                                                    M,/Z
                Figure 2.  Extracted Ion-Current Profiles for Chromatographically
                          Resolved Labeled (M2/Z) and Unlabeld M/Z) Pairs

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Federal Register "/Vol. 63. No. 72/Wednesday, April 15, 1998/Rules and  Regulations     ' 18749

                <3A)

                        •  Aiea= 46100

                                                Aiea=4760
                                                Arsa= 43300
                (30)
                                               Area= 48300
     Figure 3.  Extracted Ion-Current Profiles for (3A) Unlabeled Compound, (SB) Labeled
              Compound, and (3Q Equai Mixture of Unlabeled and Labeled Compounds-

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18750      Federal Register/Vol.  63, No. 72/Wednesday, April 15, 1998/Rules and Regulations
                                                    \J  V V \r
'   13:24            16:48            20:00



             Retention lime (Minutes)
                                                                             23:12
                           Figure 4.   Chromatogram of Chlorophenoiics
BILUNQ CODE 6SEO-SO-C

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Federal Register/Vol.  63, No. .72/Wednesday, April 15,  1998/Rules and  Regulations
                                   18751
 20.0  Glossary of Definitions and Purposes
   These definitions and purposes are specific
 to this method but have been conformed to
 common usage as much as possible.
   20.1  Units of weight and measure and
 their abbreviations          '    '
   20.1.1   Symbols.
 °C  degrees Celsius.
 fiL  microliter
 <  less than
 >  greater than
 %  percent
  • 20.1.2   Alphabetical characters.
 cm  centimeter
 g  gram
. h  hour
 ID  inside diameter  .
 in.  inch             '
 L  liter  .                         '
 M  Molecular ion
 m  meter
 mg  milligram
 min   minute
 mL  milliliteri
 mm   millimeter,
 m/z   mass-to-charge ratio
 N  normal; gram molecular weight of solute
   divided by hydrogen equivalent of solute,
   per liter of solution
 OD  outside diameter
 pg  picogram                            l
 ppb   part-per-billion
 ppm  part-per-million
 ppt  part-per-trillion
 psig   pounds-per-square inch gauge
 v/v  .volume per unit volume
 w/v   weight per unit volume
   20.2 Definitions and acronyms (in
 alphabetical order).
   Analyte: A chiorophenolic tested for by
• this method.
   The analytes are listed in Table 1.
   Calibration standard (CAL): A solution
 prepared from a secondary standard'and/or
 stock solutions and used to calibrate the
 response  of the instrument with respect to
 analyte concentration.
   Calibration verification standard (VER):
 The mid-point calibration standard (CSS) that
 is used to verify calibration. See Table 4.
   Chlorophenolics: collectively, the analytes
 listed in Table 1.
                               CS1, CS2, CSS, CS4, CS5: See Calibration
                             standards and Table 4.
                               Field blank: An aliquot of reagent water or
                             other reference matrix that is placed in a
                             sample container in the laboratory or the
                             field, and treated as a sample in all respects,
                             including exposure to sampling site
                             conditions, storage, preservation, and all
                             analytical procedures; The purpose of the
                             field blank is to determine if the field or
                             sample transporting procedures and
                             environments have contaminated the sample.
                               GC: Gas chromatograph or gas
                             chromatography.
                               HRGC: High resolution GC.
                               IPR: Initial precision and recovery; four
                             aliquots of the diluted PAR standard
                             analyzed to establish the ability to  generate
                             acceptable precision and accuracy. An IPR is
                             performed prior to the first time this method
                             is used and any time the method or
                             instrumentation is modified.    ,
                               K-D: Kuderna-Danish concentrator; a
                             device used to concentrate the analytes in a
                             solvent.
                               Laboratory blank: See Method blank.
                               Laboratory control sample (LCS): See
                             Ongoing precision and recovery standard
                             (OPR). '
                               Laboratory reagent blank: See Method
                             blank.
                               May: This action, activity, or procedural
                             step is neither required nor prohibited.
                               May not: This action, activity, or
                             procedural step is prohibited.
                             '  Method blank: An aliquot of reagent water
                             that is treated exactly as a sample including
                             exposure to all glassware, equipment,
                             solvents,  reagents, internal standards, and
                             surrogates that are used with samples. The
                             method blank is used to determine if analytes
                             or interferences are present in the laboratory
                             environment, the reagents, or the apparatus.
                               Minimum level (ML): The levelat which
                             the, entire analytical system must give a
                             recognizable signal and acceptable
                             calibration point for the analyte. It  is
                             equivalent to the concentration'of the lowest
                             calibration standard, assuming that all
                             method-specified sample weights, volumes,
                             and cleanup procedures have been
                             employed.
   MS: Mass spectrometer or mass
 spectrometry.
   Must: This action, activity, or procedural
 step is required.
   OPR: Ongoing precision and recovery
 standard (OPR); a laboratory blank spiked
 with known quantities of analytes. The OPR
 is analyzed exactly like a sample, Its purpose
 is to assure that the results produced by the
 laboratory remain within the limits specified
 in this method for precision and recovery.
   PAR: Precision and recovery standard;
 secondary standard that is diluted and spiked
 to form the IPR and OPR.
   Preparation blank: See Method blank.
   Primary dilution standard: A solution
 containing the specified analytes that is
 purchased or prepared from stock solutions
 and diluted as needed to prepare calibration
 solutions and other solutions.
   Quality control check sample (QCS): A
 sample containing all or a subset of the
 analytes at known concentrations. The QCS
 is obtained from a source external to the
 laboratory or is prepared from a source of
 standards different from the source of
 calibration standards. It is used to check
 laboratory performance .with test materials
 prepared external to the normal preparation
 process.                 '
   Reagent  water: Waterdemonstrated to be
 free from the analytes of interest and
 potentially interfering substances at the
 method detection limit for the analyte.
   Relative standard deviation (RSD): The
 standard deviation times 100 divided by the
 mean.
   RF: Response factor. See Section 10.5.1.
   RR: Relative response. See Section 10.4.4.
   RSD: See Relative standard deviation.
   Should:  This action, activity, or procedural
 Step is suggested but not required.
   Stock solution: A solution,containing an
 analyte that is prepared using a reference
 material traceable to EPA, the National
 Institute of Science  and Technology (NIST),
 or a source that will attest to the purity and
.authenticity of the reference material.
   VER: See Calibration verification standard.

 [FR Doc. 98-9613 Filed 4-14-98; 8:45 am]
 BILLING CODE 6560-SO-P

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