Reactive Plume Model IV (RPM-IV) User's Guide


              United States
              Environmental Protection
              Agency
              Office of Air Quality
              Planning and Standards
              Research Triangle Park, NC 27711
EPA-454/B-93-012
June 1993
              Air
& EPA
REACTIVE PLUME MODEL IV
                (RPM-IV)
            USER'S GUIDE

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                                 USER'S GUIDE
                     REACTIVE PLUME MODEL IV (RPM-FV)
                          Source Receptor Analysis Branch
                     Office of Air Quality Planning and Standards
                       U.S. Environmental Protection Agency
                        Research Triangle Park, NC 27711

                                September 1992
J67IO 911242

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                                        Notice
    The information in this document has been funded wholly by the U.S. Environmental
    Protection Agency (EPA) under Contract No. 68-D90066 to Systems Applications
    International.  It has been subjected to the Agency's review, and it has been approved for
    publication as an EPA document.  Mention of trade names or commercial products does
    not constitute endorsement or recommendation for use.
»J 12*2,01
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                                     Preface
The Reactive Plume Model (RPM-IV) is a numerical plume model that simulates the
complex interaction of plume dispersion and nonlinear plume photochemistry.  The model
can be used for a single point source or, in some special cases, multiple sources if they
are aligned with the mean wind. The model can be applied to a variety of air pollution
problems involving reactive pollutant species such as NOX, SO2, volatile organic
compounds (VOC), etc,.  If Carbon Bond Mechanism IV (CBM-IV) is used, emissions
must be disaggregated into carbon-bond classes prior to model application.  The RPM-IV
model is best operated during the daylight hours. The model can run on mainframes,
workstations,  or PCs with at least 2 Megabytes of memory. This manual provides the
user with information required to run the version of RPM-IV available on the date of this
publication.
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                                    Contents
    Notice       	                                                ..
    Preface      	" " "	' '	.?
    List of Figures	[	" "	    ™
    List of Tables ....                  	"	    X11
                        	    ix

    1   OVERVIEW OF THE MODEL	
        1.1  Background and Purpose	
        1.2  General Model Concepts	'.'.-'.'.'.'.'.'.'.	    2
        1.3  Scope and Use	    	".	    if
        1.4  Systems Description	.......	    <
        1.5  General Data Requirements of the Model     	    i?
        1.6  Summary of Model Output   	[[[]	    \*
       1.7   Computer Requirements	    i«
       1.8   Example Problems	   	    ;^
       1.9   Past Model Applications	    }jj
       1.10 User's Guide Organization   .'............	    Jo

    2   TECHNICAL DISCUSSION	
       2.1   Plume Configuration	. . . .	   2J
       2.2   Horizontal Dispersion	    	   23
       2.3   Technique for Numerical Solution .  . . . .	   24
       2.4   Chemical Kinetics Mechanism . .	"   28

    3   INPUT DATA	
       3.1   Variables Read by Subroutine INPUT	   35
       3.2   Variables Read by Subroutine CHEMIN	   3q
       3.3   Variables Read  by Subroutine SORCES	   42
       3.4   Variables Read  by Subroutine METIN	    45
       3.5   Variables Read  by Subroutine RESULT	    53

   4   EXAMPLE SIMULATIONS	
       4.1  Test 1: Ambient-Only Simulation (MODE2 = 1)	    58
       4.2  Test 2: Plume-Only Simulation (MODE2 =  2) Using RPM-iV	
       4.3  Test 3: Ambient Simulation  Followed by a Plume Simulation
           (MODE2 = 3) Using RPM-IV	                       ^
       4.4  Test 4: Example Point Source Impact Assessment . . . . . ." . ."  .' ' .' "    61
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        NOTES FOR COMPUTER USERS	    89
        5.1 Input of Initial and Background Concentrations	    89
        5.2 Initial Plume Dimensions	    99
        5.3 Vertical Plume Depth	        90
        5.4 Specification of Wind Speeds	         90
        5.5 Specification of Plume Widths	..........    91
        5.6 Photolysis Rates and the Carbon-Bond Mechanism	 .    91
        5.7 Specification of Background Concentrations	    91
        5.8 Stability of the Numerical Integration Scheme	           92
    References
                                                                            93
    Appendix A: The RPM-IV Front End Software (SETUPRPM)
    Appendix B: The ROM-RPM and UAM-RPM Interface Software
    Appendix C: Output Files for Test Simulations
    Appendix D: Preliminary Model Evaluation
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                                        VI

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                                     Figures
    1

    2
RPM-IV flow diagram	                          6

RPM-IV and RPM-IVSS program, subroutine, and fimction
communication  	                                             n
         Plume cell expansion as a function of downwind distance
         in RPM-IV	
                                                                          22
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                                      Vll

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                                          Tables
     1


     2

     3

     4

     5'

    6

    7

    8

    9

    10
 Carbon numbers of groups of primary organic species
 in CBM-IV	
 CBM-IV photolysis reactions	

 Nitrogen dioxide photolysis rate constants	

 Photolysis reaction rate ratios   . .	

 Structure and format of records read by INPUT  .  .	

 Structure and format of records read by CHEMIN

 Structure and format of records read by SORCES

 Structure and format of records read by METIN

Structure and format of records read by RESULT	

Area source emission rates used in RPM emission injections for Test 4
 30

 31

 32

 33

 38

 41

44

50

54

64
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                                           IX

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                            1  OVERVIEW OF THE MODEL
     1.1   BACKGROUND AND PURPOSE

     The Reactive Plume Model (RPM-IV) is a photochemical plume-segment model that
     simulates the evolution of a photochemical plume by representing the plume as a series
     of cells across the horizontal extent of the plume. The RPM is a Lagrangian model that
     represents an air parcel  of pollutants as It moves downwind, simulating the entrainment
     of ambient (background) air and the resulting chemical transformations within the plume
     Each run of the RPM simulates one air parcel trajectory as it travels downwind.  The
     RPM estimates short-term concentrations of primary pollutants (reactive or inert
     emissions) and secondary pollutants (those formed within point-source plumes).  Different
     chemical mechanisms can  be used within and outside the plume in different model runs
     such as first-order reaction rate approximations to nonlinear chemical systems, different
     levels of condensation of a master mechanism, or different representations of chemical
     reactions (e.g., alternative reaction rate constants).

    RPM-IV includes several improvements over the RPM-H  (Stewart and Liu  1981- Morris
    Stewart, and Liu, 1988). The RPM-IV uses a stiff differential equation solver (a method'
    first proposed by Gear, 1971), which explicitly integrates  all of the reactions in the input
    chemical kinetic mechanism.  The Carbon Bond Mechanism IV (CBM-IV) is the
    mechanism supplied with the RPM-IV, although other chemical mechanisms can be used
    by changing the input file.  A steady-state version of the model, RPM-IVSS  employs
    steady-state approximation  in the solution scheme for several fast-reacting radical species
    and solves.the deferential equations for the CBM-lV using Newton's metfiod. TheS-
    IVSS uses only the CBM-IV mechanism,  which is built into the code in the numerical
    solution procedure-.

    Other recent improvements over RPM-H include:

          Incorporation of the latest Carbon Bond Mechanism IV (CBM-IV), including a
          1991 update to the PAN chemistry and inclusion of an XO2-HO2 reaction;

          The option of having photolysis rate constants calculated;

          Enhanced flexibility with regard to input/output options;
91124r2.04

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          A user-friendly front end (SETUPRPM) that allows RPM input files to be
          developed through a series of questions and answers;  and

          The ability to interface with input and output from the EPA Regional Oxidant
          Model (ROM) (ROM-RPM preprocessor) and Urban  Airshed Model (UAM)
          (UAM-RPM preprocessor).

   This manual fully explains how to use both the RPM-IV and RPM-IVSS as well as the
   front end (SETUPRPM), ROM-RPM, and UAM-RPM preprocessors.
                    MODEL CONCEPTS

   The RPM simulates the chemistry and entrainment processes of a photochemical reacting
   plume.  Thus, information on the meteorological conditions and background (ambient) air
   quality conditions must be input to the RPM.  Key inputs include the description of
   plume expansion as it travels downwind, the concentrations of the background air to be
   entrained by the plume, the rates of the photolysis reactions, and any emission sources
   that lie along the trajectory of the plume. Since the air parcel moves downwind from a
   release point (usually a point source under consideration) independent of x and y UTM
   coordinates, time and distance refer to the time since release and the downwind  distance
   of the air parcel.

   Plume Expansion:  The plume expansion can be defined explicitly by the user by
   specifying the plume width and depths as a function of downwind distance.
   Alternatively, the atmospheric stability and mixing height may be specified as a  function
   of time and the RPM will calculate the plume expansion rates using Pasquill-Gifford-
   Turner (PGT) expansion curves and the wind speed inputs.  The ROM-RPM and UAM-
   RPM preprocessor programs also use PGT dispersion rates to define plume widths and
   depths.

   Ambient Air Quality:  The background (ambient) concentration inputs to the RPM are a
   key Input that may decide whether a source will or will not produce ozone.  Ambient
   concentrations may be input by  the user as a function of time (i.e., time since release of
   the air parcel).  Alternatively, the initial concentrations of the ambient air may be
   specified and  the RPM will perform a simulation of the chemical evolution of the initial
   concentrations through a "box model" or "ambient" air simulation. Background
   concentrations may also be obtained from the ROM or UAM photochemical grid models
   using the ROM-RPM or UAM-RPM preprocessors.

   Photolysis Rates:  Photolysis rates (i.e., chemical reaction rates dependent on sunlight)
   can be either  input by the user or, in the case of the CBM-IV, calculated by the RPM
   using the user-supplied information on location (latitude/longitude) and time of year.
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Emissions: Emissions are input into the RPM as a function of downwind distance. The
emissions are injected into the plume (air parcel) as it passes over the specified downwind
location.
1.3 SCOPE AND USE

1.3.1 Applications

The RPM-IV can be applied to a variety of air pollution problems involving reactive
pollutant species. In the past it has been used primarily for the simulation of point-source
plumes, although it has also been used to analyze some area-source emissions. The
current model can treat several sources at once if they can be assumed to line up along
the plume trajectory. The RPM is a Lagrangian (trajectory) model that necessarily
assumes a coherent air parcel. As such, the model must be considered a screening model
since it cannot adequately simulate all of the atmospheric processes associated with the
dispersion and formation of pollutants (e.g., wind shear and land/sea breezes).
•
The RPM has been successfully used to evaluate the following scenarios:

The impact of point-source emissions on oxidant levels hi downwind urban and
rural areas.

The impact of point-source NOX emissions on downwind NOX concentrations.

The effect of area-source hydrocarbon and NOX emissions on oxidant levels hi
downwind rural and urban areas. .

The impact of point-source SO2 emissions on downwind SO2 concentrations using
a complex chemical kinetics package to account for the chemical conversion of
SO2 to sulfates.

The sensitivity of ozone formation hi a plume to key parameters, including plume
expansion rate, background air quality, photolysis rates, the chemical kinetic
mechanism, and the chemical mechanism solution procedure (i.e., the Gear
method or Newton's method with steady-state approximation).

The model is useful for many types of regulatory studies, such as new source reviews,
prevention of significant deterioration studies, control technology evaluations, alternative
combustion fuel studies, the design of supplementary control systems, formulation and
evaluation of emission control strategies, and visibility impairment studies. As a research
tool, the model is also useful for developing condensed chemical mechanisms, examining
the effects of alternative chemical mechanisms on ozone formation, or analyzing the
effects of steady-state approximation on ozone formation.
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1.3.2 Limitations

The user should be aware of the limitations inherent in the model to avoid its misuse or
misapplication. First, RPM-IV models the chemical evolution of pollutant species
during transport and dispersion, not the physical aspects of the latter. It is capable of
treating complex, nonlinear chemical reaction systems, but does not solve the nonlinear
hydrodynamic equations for fluid flow. Plume advection and dispersion are obtained
from the time-varying input parameters and variables specified by the user. Therefore,
the accuracy of the model's concentration predictions depends on a realistic specification
of dispersion conditions. In this regard, user input has been made flexible to
accommodate varying degrees of data comprehensiveness.

Second, in the current version of the RPM-IV the plume configuration consists of a
vertically well-mixed series of rectangular cells with one-dimensional (cross-plume)
concentration variability. Thus, the user should be cognizant of the assumption of
uniform concentration in the vertical; meteorological conditions should favor the
formation of a well-mixed layer capped jby a temperature inversion, and the downwind
distances of interest should be greater than about 10 stack heights.

Some concerns have been expressed about the possible importance of diffusion-limited
chemistry within the plume. Diffusion-limited chemistry refers to the reduction of
effective chemical reaction rates due to the finite time required to mix reactants across the
plume. This effect is most prominent near the stack, where concentrations are relatively
high and reaction rates relatively fast. Initiating the plume 0.1 to 1.0 km downwind of
the stack would lessen the effect. However, the primary RPM-IV assumption is that, as
the plume expands, ambient pollutants will instantaneously mix within the volume of'each
cell, entering the plume through the outer cell edges. This assumption makes the RPM-
IV more amenable to treating diffusion-limited chemistry than single-cell plume models
(such as the OZIPM or RPM-I). If the diffusion limitation is of concern, the user may
specify more horizontal grid cells, but at the expense of increased computational demands
on the model.

Finally, the RPM is a complex model relying on sophisticated numerical integration
techniques whose accuracies and stabilities are sensitive to many factors. For instance,
use of initial concentrations greater than those for which the chemical kinetics mechanism
was designed can lead to inaccuracies and excessive execution times. Also, the delicate
equilibrium between the errors hi the numerical solution and the optimum time step and
order of the solution approximation can easily be perturbed by introducing transients into
the numerical system, such as discontinuities hi time-dependent input. Normally, the
solution scheme adjusts to a transient by temporarily lowering the order of the solution
approximation and reducing the time step, thereby increasing execution time. Severe
transients, such as those introduced through input errors (e.g., a mistake in the exponent
91124r2.04

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of a mixing height), may lock the model into a very inefficient integration mode, placing
excessive strain on the user's computing resources and patience.

The steady-state version of the model (RPM-IVSS) treats the problem of transients better
than the RPM-IV does but for most applications requires more computer time and has not
been tested as extensively the RPM-IV. The choice of model usually depends on the
number of emission injections specified. The Gear version of the RPM-IV is a
technically superior model because it explicitly solves the chemical kinetics for all
species. However, if there are many emission sources, the steady-state version may be a
better choice.

It is recommended that the user be an experienced air quality analyst who is aware of the
idiosyncrasies of numerical models, particularly those solving stiff systems of equations
(i.e., equations with a broad range of time scales).

1.4 SYSTEMS DESCRIPTION

1.4.1 Main Program Summary

RPM-IV can be.executed independently of any other program or preprocessor. It reads
only ASCH files as input and writes an ASCH output concentration map that can be
routed to a line printer. As an option, the RPM-IV can write a binary (unformatted)
output file to disk that can be later processed with a postprocessor program (supplied by
the user) to obtain graphical representation of the model results (such postprocessing
could also be performed on the ASCH output file). A flowchart for the overall model
system is shown in Figure 1. The model can be run in either the "ambient-only" mode
(i.e., box model chemistry simulation), "plume-only" mode (plume simulation with user-
supplied background concentrations), or ambient followed by plume simulations (i.e., the
user supplies the initial conditions and the ambient mode simulation defines the
background concentrations to be entrained by the plume simulation). An "ambient run"
refers to a computation of the time-dependent background concentrations (e.g., simulation
of a smog chamber experiment).

The main program calls the input routines, initializes the simulation(s), and calls the
integration subroutine repeatedly until the end of the simulation(s). Figure 2 shows the
communication between the main program, the subroutines, and functions.

1.4.2 Subroutines

CHECK determines whether any output is to be printed and calls output subroutines when
necessary. When appropriate, this subroutine also saves concentration values for display
upon completion of the simulation(s).
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                       FIGURE  1.   RPM-IV flow diagram.
80074
88135
91121,

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    Main
  Program


SORCES

METIN



— »*•
-*•
iftk
-to-
UOi-KS

ncp-ROM


PLRISE

TJXTIWT
Key  %
                                                        SIGMAY
                                                        SIGMAZ
                                                          LIN
                                                         XLIN
                                                         XCEPT
                                                         ERFF

t
**

k
_ih.
INTERP

PLOTA

•DUCT TO

4
k
                                                        OUTPT2
                                                         PHOT
                                                       DFSUTY
      FIGURE 2a.  RPM-IV subroutine and function flow chart.

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   Main
  Program
Key
v.nr.ivmi

SORCES

METIN



-if
h

_»
USPK.S

DSPRSN

PLRISE

RSTRCT

PRECHEM1
                                                        SIGMAY
                                                        SIGMAZ


                                                         LIN
                                                         XLIN
                                                        XCEPT
         FIGURE 2b.   RPM-IVSS subroutine and function flow chart.

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ODly 'm
                                      * adulates rates of change of species concentrations
            '
     and their derivatives at daylight times.

     CHEM2A and CHEM2B are used only in RPM-IVSS. They calculate the same chemical
     rates as CHEM does, but for nighttime conditions.  CHEM2A is called except when
     [NO] and [O3] are particularly small.*

     CHEMIN reads data associated with the specific chemical mechanism (i.e., chemical
     reactions, number of species of various types, and initial conditions) from the input file.

     CLLDIM calculates initial cell dimensions and geometric  factors associated with the
     plume cross section (e.g., width, cell centerline, and boundary location factors)  Cell
     dimensions are determined in such a way that each cell contains the same proportion of
     inert mass distributed normally across the plume.

     DEC performs an N x N matrix decomposition.  It is used with the matrix solver (SOL)
     aS £^™^c?n'S method S°lution tedmi
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    DIFSUB is used only in RPM-IV (and not KPM-IVSS). It controls the Gear Package
    (Gear, 1971), which solves a system of ordinary differential equations by the backward
    differentiation formula. This method solves the set of concentration equations by an
    implicit method and is suitable for stiff systems.

    DSPRS calculates the plume widths  or heights (depending on the value of a flag) at
    selected downwind distances. DSPRS accepts time-varying wind speed and stability
    input.  The functions SIGMAY and  SIGMAZ (see Section 1.4.3) are called to determine
    the width and depth parameters.

    DSPRSN performs the same function as DSPRS but accepts only constant stability and
    wind speed input.

    INTTLZ establishes all initial conditions for a simulation.  It is called twice in a model
    run that includes both "ambient" and "plume simulations."

    INJECT injects emissions into the plume as it travels downwind.

    INPUT reads control parameters for the simulation from the RPM input file.

    INTERP performs a linear interpolation in the same manner as the function XLIN (see
    Section 1.4.3).

    UBLU and LBSOL solve the system  of ordinary differential equations, represented by AX
    = B by Cholsky's method.  Decomposition of A into a lower triangular matrix L and an
    upper triangular matrix U is performed by LBLU.  Subroutine LBSOL then solves the
    systems UX = Y and LY = B.

    METIN reads meteorological data (wind speed, plume dispersion, photolysis rate
    information, and background species .concentrations).from the input file.

    OUTPUT prints time, downwind distance, plume dimensions, photolysis rate constants,
    cross-plume average concentrations, and individual cell concentrations  for each species.
    Information can be extracted for specific time intervals and downwind distances.  This
    subroutine also terminates the main program.  OUTPT2 prints maximum concentrations
    for either plume average or individual cell values for selected species..

    PDB evaluates a Jacobian matrix of terms  representing the rate of change of each species
    with respect to all other species.  This matrix is required for the  backward differentiation
    formula used to integrate the ordinary differential equation system.
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     PHOT calculates photolysis rates for the current time step.

     PLOTA prints a graphic display of species concentrations versus time.

     PLRISE calculates plume rise from stack data and meteorological conditions associated
     with each source.

     PRECHEM is used only in RPM-IVSS. It converts the form of the CBM-IV
     implemented in RPM-IV to the form required in RPM-IVSS. PRECHEM1 is an entry
     point in PRECHEM.  It resets photolysis reaction numbers 10 and 11 to be reactions 69
     and 74 in the RPM-IVSS chemistry implementation.

     RATEZ computes the plume expansion rate and the background concentrations at a
     particular time,  and generally provides information necessary to establish the full rate
     equation for species concentrations.

     READEC is a subroutine that performs the transfer of one array to another  Many
     SSSE? ContaiVheir own fast ray £ransfer subroutine, which can be used instead of
     KfcADEC to speed up computations.

     RSTRCT is called  during the initialization procedure to ensure that the initial plume depth
     is restricted to the  layer between the ground and the top of the mixed layer The
     subrouting also calculates the downwind distance at which the plume  touches ground the
     contact downwind distance when the upper extent of the plume reaches the top of the
    mixed layer, and the downwind distanqe at which a vertically uniform pollutant dis-
    tribution is valid.

    RESULT prepares  concentration arrays for graphic display.   RESULT2 saves maximum
    concentration values for output at the end of the run.

    SOL is  used in RPM-IVSS only. It performs a matnx solution (after matrix
    decomposition by DEC) to provide estimates of steady-state radical concentrations.

    SOLAR calculates the solar zenith angle as a function of location and time.

    SOLVER solves a matrix equation after the matrix has been LU decomposed.

    fn^P ^ emissio"s1 <** from the HJP* ^ ^ converts emissions rates expressed
    in g/s to model-compatible units (ppm • m3/s).

    STEM fa used only in RPM-IVSS.  It solves a system of ordinary differential equations
    ^hH^f-    i™d NeWt°n'S method'  This  nui*erical "Shane is a semi-implicit
    method that as an efficient solver of equation systems that are not particularly stiff.

    UNCOUP updates the concentrations of uncoupled species.
91124r2.04
                                       11
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    UPDATE updates the total simulated time and downwind distance after each successfully
    completed tune step.

    WRITEC performs the transfer of data from one array to another.  Like READEC, calls
    to WRITEC can be replaced by any fast array transfer routine in the user's computer.


    1.4.3 Functions

    Seven functions are used in KPM-IV.

          F represents an equation whose roots are used in establishing the plume width and
          other geometric factors.

          ERFF evaluates the error function.

          SIGMAY returns the Pasquill-Gifford horizontal dispersion parameters for a given
          downwind distance and stability using Turner's equations (EPA, 1987).

          SIGMAZ returns the vertical dispersion parameters in a manner analogous to
          function SIGMAY.

          XLIN (or LIN) performs linear interpolation between floating point (integer)
          values.

          XCEPT calculates the x-coordinate of the intersection of two lines.


    1.5  GENERAL DATA REQUIREMENTS OF THE MODEL

    The RPM requires six types of input data:

          Meteorological data
          Background and initial concentrations
          Source emission rates
          Program control parameters
          Photolysis rates
          Chemical mechanism

    Each of these categories is discussed hi turn below.  The RPM is a Lagrangian model
    that simulates an air parcel as it moves downwind. Thus, unless otherwise noted, the
    model uses standard units of meters, minutes, and grams for length  (i.e., downwind
    distance from initialization point), time (i.e., time since release of the air parcel), and
    mass, respectively. Wind speeds are expressed hi meters  per second (m/s) and
    concentrations in parts per million (pprn).  Note that the time (time since initialization)
    and length (downwind distance) are related using the wind speed inputs, thus all inputs
    must be consistent with the wind speed inputs.

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     1.5.1  Meteorological Data

     RPM requires that wind speed data be provided as a function of time (since release of the
     air parcel). The horizontal and vertical dispersion of the plume can be calculated by the
     model based on the user input stability and wind speed using PGT dispersion curves or
     specified by the user in terms of plume widths and depths as a function of downwind
     distance. If the model is to calculate plume widths and depths, the model requires mixing
     depths as a function of downwind distance and time-dependent stability information.


     1.5.2  Background and Initial Conditions

     The user must specify an average initial concentration in the plume parcel for all species
     required by the chemical mechanism.  For many intermediate species produced in the
     HC/NOX photochemistry, an initial condition of zero is acceptable. The user has the
     option of including emissions from the primary source stack in the initial concentrations
     Alternatively,  the model may be initialized without the primary source emissions, which
     may then be accounted for by injecting them into the plume at the beginning of the
     simulations.

     The model imposes a cross-plume Gaussian distribution on any pollutant concentrations in
     excess of the specified background values.  Any species treated by the chemical
     mechanism is assumed to entrain zero mass from outside the plume unless the species is
    also specified as  an entrained or "flowing"  species.  (See Section 3 for detailed guidance
    on setting up the appropriate input records.) The background concentrations may be
    specified by the user as a function of time,  or may be calculated by the model in an
     ambient  mode preceding the plume simulation.


    1.5.3   Source Emission Rates

    If source emissions are to be injected into the plume parcel after initializing the
    simulation (i.e., when the primary plume passes over a secondary source), the user must
    speciry the downwind locations, emission rates, and stack parameters of the additional
    sources.
    1.5.4  Program Control Parameters

    Numerous input data are required by the RPM-IV for program control. These data
    include, among others, input and output option parameters and time variables for the
    numerical algorithm (see Section 3).
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                                          13
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    1.5.5  Photolysis Rates

    Many of the reactions in the CBM-IV are photolytic. Reaction rates depend on many
    factors, including solar radiation.  The simplest option requires only the reaction number's
    of the photolytic reactions hi the CBM-IV and the time and location of the simulation (for
    zenith angle calculation).  Other options allow the user to independently specify zenith
    angles or photolysis rate constants for arbitrary chemical mechanisms.  See Section 3 for
    details.
    1.5.6   Chemical Mechanism

    The chemical mechanism hi RPM is completely specified through input records consisting
    of species names and stoichiometric coefficients of all reactants and products, rate
    constants, and activation energies. In RPM-IV the existing CBM-IV (Gery, Whitten, and
    Killus,  1988) can be modified or a new chemical mechanism can be installed.  The RPM-
    IVSS uses only the CBM-IV chemical kinetics mechanism, though the chemical reaction
    rate coefficients can be modified in the input file.
    1.6  SUMMARY OF MODEL OUTPUT

    RPM-IV provides the following types of output:

          Printout of input data;   •

          Printout of program control parameters;

          Printout of plume concentrations, plume widths and depths, wind speed, NO2
          photolysis rate, and cell geometric factors as a function of time or downwind
          distance;
                                                 «

          Printer-plots of average plume and ambient concentrations as a function of time or
          downwind distance; and

          Printout of plume maximum concentrations.

          Binary (unformatted) file of concentration and other information from the
          simulation.

    Concentrations are printed for each species within each cell as well as the average across
    the plume.  The output options are discussed hi greater detail in Section 3.
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     1.7   COMPUTER REQUIREMENTS

     As currently configured, RPM-IV requires less than a megabyte of core memory.  It does
     not read or write to tape, though storing output on disk is a user option.  Execution time
     can vary substantially depending on many factors, such as wind speed, simulation length,
     number of point source injections, downwind background or initial concentrations,
     number of horizontal cells, and "stiffness" of the differential equation. The model has
     been exercised on a Multiflow TRACE/14 computer (which is approximately 10 to 20
     percent faster than the speed of an IBM 3090/200), IBM-compatible PC/XT with a
     Definicon 780+ accelerator board (approximately equivalent to a VAX/780 or
     Prime/750), the EPA's IBM 9000 mainframe computer, and  an IBM-compatible 486
     using the Lahay Fortran compiler. An RPM-IV simulation of a 10-hour period using six
     horizontal cells requires approximately three minutes on the Multiflow TRACE/7
     computer and approximately 25 minutes on the extended IBM-compatible PC/XT
     computer.  More  detailed information on the run execution times of the RPM-IV and
     RPM-IVSS is provided in Chapter 4.


    1.8 EXAMPLE PROBLEMS

    This manual contains four example problems that illustrate the features of the RPM-IV
    These example problems are described in detail in Chapter 4  and their resultant printer
    output is given in  Appendix C.  The four example problems are as follows.


    Test 1: Ambient-Only Simulation

    This example illustrates how to run the RPM-IV in its "ambient-only"  (i.e., box model
    simulation) mode.  The model is initialized with user-supplied initial concentrations
    location (latitude/longitude), and date (day of year and time of day). It is then used to
    simulate the time evolution of the concentrations assuming no further emission injections
    or influence of concentrations from outside the box;  this type of simulation is  similar to
    that produced within a smog chamber. In this example the photolysis rates are calculated
    internally by the RPM-IV.  Three versions of Test 1 illustrate different features of the
    RPM-IV:

          Test 1.1: The RPM-IV (Gear solution technique) is exercised with the 1991
          CBM-IV chemistry;

          Test 1.2: The RPM-IVSS (steady-state solution technique) is exercised with the
          1991 CBM-IV chemistry; and

          Test 1.3: The RPM-IV is exercised with the original 1988 CBM-IV chemistry.
91124r2.04
                                       15
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    A comparison of tests 1.1 and 1.2 shows the effect of the numerical solution technique on
    ozone formation, whereas comparison of tests 1.1 and 1.3 shows the effect of including
    the updated PAN chemistry and XO2-RO2 reaction on ozone formation.  These tests also
    illustrate how to modify the chemical mechanism input to the RPM-IV.
    Test 2:  Plume-Onlv Simulation
    In this example the RPM-IV and RPM-IVSS are run in the plume-only mode; ambient
    (background) concentrations that are entrained by the plume are provided by the user in
    the input file.  This example illustrates how plume simulations can'be performed by
    specifying the initial concentrations of the plume rather than injecting emissions into the
    plume over time.
    Test 3: Ambient-Only Simulation Followed bv Plume-Onlv Simulation

    This example represents a more common type of application of the RPM.   The user
    specifies the background initial concentrations and the RPM performs an ambient-only
    simulation to obtain a time history of the background (ambient) air.  Then the RPM
    performs a plume-only simulation, injecting the point source emissions into the plume.
    In this test run we also illustrate how SOX chemistry can be added to the chemical
    mechanism (RPM-IV only).
   Test 4; Example Impact Assessment Simulation

   RPM-IV is often used to estimate the ozone formation potential of emissions from a new
   source, a modified source, or an existing source.  This example illustrates the steps
   required to perform such an assessment.
                                                 *
   Test 4 was designed to estimate the potential ozone impacts of a large point source that
   emits NOX emissions.  The hypothetical point source is assumed to be located upwind of "
   suburban regions that have VOC and NOX emissions.  This example illustrates how to use
   multiple emission injections to represent source emissions and how to perform two plume
   simulations, with and without the point source emissions, to estimate the potential
   contribution of a point source emissions to ozone formation.


   1.9 PAST MODEL APPLICATIONS

   The first version of the Reactive Plume Model (RPM) was developed in the late 1970s
   cumulating in the public release of version H of the RPM (RPM-n)  in 1980 (Stewart,
   Yocke, and Liu, 1980). Early applications of the RPM focused on the evaluation of the
91124r2.04
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    model using plume measurement data bases and the use of the model to estimate the
    potential air quality impacts of proposed new sources as part of New Source Review
    (NSR), Prevention of Significant Deterioration (PSD), and Environmental Impact Report
    (EIR) and Environmental Impact Statement (EIS) regulatory processes.  Tesche (1985)
    provides a review of many of these early RPM applications, which are briefly
    summarized below.

    During the development of the first version of the RPM (RPM-I), under sponsorship of
    the California Air Resources Board, the model was evaluated against tracer (SF6)
    measurements collected downwind of the Haynes and Los Alamitos power plants hi
    California (Liu et al., 1976).  This early evaluation focused on the transport and
    dispersion portions of the RPM and indicated that these components of the model perform
    quite satisfactorily.

    The first comprehensive evaluation study of the RPM's predictions of photoreactive
    species was sponsored by the Electric Power Research Institute.  Detailed field
    monitoring of power plant plumes was conducted to determine the behavior of the plumes
    and support a validation study of the RPM (Ogren et al., 1976; Tesche et al., 1976).
    Aerometric measurements were made at the following power plants: Four Corners,
    Farmington,  New Mexico (coal-fired, dry environment); Cunningham, Hobbs, New
    Mexico (gas-fired, dry environment), and Wilkes, Longview, Texas (gas-fired, humid
    environment). The RPM model  estimates were compared with in-plume aircraft
    measurements. The RPM model performance was evaluated for NO, NC^, NOX, O3,
    SO2, and sulfate.  A total of 16 case studies were analyzed; in all cases ozone depletion
    within the plume occurred near the plant followed by a gradual increase in ozone to
    background levels as ambient air was entrained in the plume. Because of the low
    background hydrocarbon concentration levels in the vicinity of these southwestern power
    plants, the plume hydrocarbon-to-NOx ratio never rose high enough to promote in-plume
    ozone formation.  In general, the RPM did a good job in replicating the plume-average
    measurements.  The model's predictions of NO2 and ozone exhibited some sensitivity to
    the input background hydrocarbon concentrations. -

    The RPM-H was also evaluated using data from the Midwest Interstate Sulfur
    Transformation and Transport (MISTT) data base, which included measurements
    downwind of the Labadie Power  Plant near St. Louis, Missouri (Yocke et al., 1979
    1980).  This is the same data set  used in the RPM-IV evaluation described in'Appendix D
    of this  user's guide.

    In the early 1980s the RPM-H was evaluated against measurements collected downwind
    of the Oak Creek power plant in Wisconsin and the Widows Creek power plant in
    Alabama (Stewart and Liu, 1981). Ozone in the plumes downwind from these power
    plants was at  first depleted below ambient background levels and then increased in excess
    of the ambient air. The RPM did an excellent job in replicating the measured plume
91124r2.04
                                        17
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     average ozone, NO, and NO2 concentrations as well as the plume cross section of the
     ozone concentrations.

     The RPM was used to estimate the ozone impacts of the proposed Montezuma coal-fired
     power plant, to be located upwind of the San Francisco Bay Area (Roth et aL, 1981).
     The model was used to simulate the concentrations in plumes from several large power
     plants, and the results were used to estimate boundary conditions for the Urban Airshed
     Model (UAM) regions covering the urban areas of Stockton and Sacramento.

     Also in the early 1980s a steady-state chemistry version of the RPM was developed
     (RPM-nSS) and then evaluated against aircraft measurements  taken downwind of the
     Navajo and Four Corners (New Mexico) power plants as part of the VISSTA study.  The
     RPM-HSS was used to estimate the NO2 impacts of the Four Corners power plant
     (Gutfreund*, Morris, and Yocke, 1984).  The model performance of the RPM-HSS was
     quite good for NO2, NO, ozone, and NC>2/NOX ratios. The RPM-HSS was also used to
    develop a look-up table of NO2/NOX ratios as a function of atmospheric conditions; these;
     ratios were then coupled with the COMPLEX-I Gaussian plume model calculations to
    estimate hourly average NO2 concentrations from the Four Corners power plant using
    several years worth of meteorology.  The resultant analysis went into a submission by the
    state of New  Mexico to EPA.

    The RPM was first  used hi the PSD permitting process hi 1984, when it was used to
    estimate the potential ozone impacts of hydrocarbon emissions from a proposed printing
    plant in the vicinity of Reno, Nevada (Gutfreund et al., 1984).

    The RPM has been  extensively used to evaluate the ozone impacts  of petroleum
    development in the Santa Barbara Channel area of California.  These studies include,
    among others, the assessment of the onshore impacts of drillship emissions (Tesche and
    Morris, 1984), air quality impacts associated with incremental increases in NOX emissions
    from the proposed expansion of the Carpinteria gas plant (Gutfreund and Morris,  1984a),
    and a critique of photochemical modeling for the Lease, Sale 73 Air Quality Impact Study
    (Tesche, 1983).  The most comprehensive and detailed air quality impact study of off-
    shore sources using  the RPM was for the Platform Gail EIS (Gutfreund and Morris,
    1984b, 1985). This was the first study that applied and evaluated the RPM hi an urban
    setting; it also pioneered the nested-plume modeling approach use of the RPM. In the
    nested-plume approach a trajectory is defined and the background (ambient) air quality is
    simulated by the RPM using a wide plume and a gridded emission inventory.  The impact
    of a particular source is then simulated by nesting a narrow plume within the wide
    ambient plume. Background concentrations for the narrow  impact plume are obtained
    from the wide plume simulation.  The Platform Gail study included a comprehensive
    evaluation of the  RPM using surface ozone concentrations measured in Ventura and Santa
    Barbara counties.
9I124r2.04
                                       18
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    During the late 1980s the RPM-n was updated to accept the Carbon Bond Mechanism
    version IV (CBM-IV). The EPA used this updated version of the RPM-n to develop
    VOC/NOX point source screening tables (Scheffe, 1988) for use in determining worst-case
    incremental ozone impacts from VOC/NOX point sources.

    Continued development of the RPM has led to the RPM-IV, described in this manual.
    RPM-IV contains many advantages over older versions, including companion programs to
    interface the model with ROM and UAM output as  well as user-friendly front-end
    program and a steady-state chemistry version (RPM-IVSS). The RPM-IVSS has been
    used to estimate the potential ozone impacts from a  proposed generating station in
    Wisconsin (Ligocki et al.,  1991).  The RPM-IVSS was exercised using the nested-plume
    modeling approach and gridded emission estimates.


    1.10 USER'S GUIDE ORGANIZATION

    This user's guide is organized as follows.  Chapter 2 summarizes the technical
    formulation of the  RPM-IV.  Chapter 3 is more of a systems manual, providing the user
    with a detailed description of the,RPM input file structure and variable definitions.  The
    example simulations are described in Chapter 4, along with step-by-step instructions on
    how to set up an RPM simulation.  Chapter 5  contains some computer notes to the user
    on the operation of the model.

    Procedures for operating the RPM-IV preprocessors  are given in Appendix A and B;
    Appendix A provides information on operating the RPM-IV front-end program
    (SETUPRPM); the ROM-RPM and UAM-RPM interface programs are discussed in
    Appendix B.  Portions of the output files for the test simulations are given in Appendix C
    and a preliminary evaluation of the RPM-IV performance using the MISTT data is
    provided in Appendix D.
91124r2.04
                                       19
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                              2   TECHNICAL DISCUSSION
     2.1   PLUME CONFIGURATION

     The Reactive Plume Model consists of an array of well-mixed reactors or cells across the
     plume (Stewart and Liu, 1981). The configuration of the plume is changed as it travels
     away from its source (Figure 3). Assume that the width and height of cell / can be
     described by two parameters:
    and
                                 hj =
                            (1)

                            (2)
    where w' denotes the width of cell;, W. is the vertical thickness of the plume, and s
    represents the distance downwind of a point source measured along the plume axis
    Based on a mass balance, the governing equation along a wind trajectory s can then be
    expressed as
                                them
                                          ds
                                               uc -  —
1 dhA
  dsl
uc?
                            i = 1,2, ...,N;  j =1,2,  ...,
                                                                                   (3)
    where c/ denotes the concentration of chemical species i in celly, u is the wind speed
    along the plume trajectory, t is the time since emission, and pf represents the net mass
    transfer across the expanding cell boundaries.  In the revised model the total mass of each
    primary pollutant is initially divided equally among M cells.  By allowing the volume of
    each cell to expand as dictated by atmospheric dispersion, cell boundaries can be viewed
    as impermeable for unreactive pollutants.  Thus, only the diffusion of reactive and
    entrained pollutants must be parameterized.  For example, within the framework of a
    Gaussian formulation, and for an elliptically shaped plume, the radii (in transformed
    polar coordinates) of concentric rings containing equal pollutant masses can be shown to
    UC
91I24R2.05
                                         21
-------
                   Concentration distribution
                   across the plume
                   near  the point source
                                                          .Concentration
                                                          distribution
                                                          across the plume
                                                          farther downwind
Plume
trajectory
                                                                       Expansion of
                                                                       equal-mass cells
                               Distance perpendicular to plume trajectory
            FIGURE 3.  Plume  cell expansion as a function of downwind distance in RPM-IV.
83037
88135
-------
                                                                                   (4)
    where rj is the radius of the/th concentric ring, and cr, and az represent the horizontal
    and vertical dispersion coefficients for the plume.  (The transformed polar coordinates are
    given by r, = y /
-------
     The second step is then required to detrain the same amount of pollutant mass, hi the case
     of an inert species, using an approach parallel to the Fickian approximation for turbulent
     diffusion.  The detrainment flux between the/th cell and the (/ +  l)th cell is assumed to
     be equal to the product of an equivalent diffusion coefficient at the cell interface and the
     corresponding concentration gradient,
                                                                                    (8)
    Thus, imposing the condition of no net mass transfer for an inert pollutant species C1,
  F
                                          Ej - DJ = 0
(9)
    would lead to the following recursive formula for computing the equivalent diffusion
    coefficient Kj at the cell interface:
     ,   (c1  - r'\        (rl   rl  ^
1  2 \K \^—L _ K    CJ ~ CJ-i
   & \A.j  	 - &    	
        U+1  - yy.J     Jl(yj- y,.2
                                                                                  (10)
    To initiate the computation, the zero concentration gradient at the plume centerline must
    be invoked; thus, fory = 1, Equation  10 can be solved for JTX as follows:
                                                    dt
                                                                                  (11)
    Once the equivalent diffusion coefficient Kj is. determined for each cell interface,
    Equations 6, 7, and 8 can be used to compute the mass transfer across the cell boundaries
    for reactive pollutants (i # 7).  This calculation will provide the flux term in Equation 3,
    the governing equation for the Reactive Plume Model.


    2.3   TECHNIQUE FOR NUMERICAL SOLUTION

    Equation 3 represents a system  of ordinary differential equations (ODE) whose solutions
    are obtained using numerical integration techniques. The two different versions of the
    RPM use different numerical solution techniques.  RPM-IV uses the Gear technique
    while the RPM-IVSS uses a quasi steady-state relationship for several fast-reacting radical
    species and Newton's Method.
91124R2.05
                                         24
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    2.3.1  Gear Solution Technique

    The Gear algorithm (Gear, 1971) has been selected for the RPM-IV because of its ability
    to accurately treat stiff systems of equations. An ordinary differential equation (ODE)
    system can be considered stiff if it involves both rapidly and slowly varying terms.  The
    stiffness of a system can be measured by the ratio of the maximum to minimum decaying
    time constants inherent in the system.  The  system of equations formulated for RPM-IV
    contains time constants that range from very small (typical of fast radical reactions) to
    large for the diffusive nature of the atmosphere and the formulation of secondary
    pollutants.

    In the Gear method the solution of the ODE system is accomplished by means of a linear,
    multipoint method known as the backward differentiation formula (BDF). Given the
    general form of Equation 3,
                                                                                (12)
                               dt
    where y and/are vectors of length N x 1, the BDF approximation can be represented by

                                 y* " E a< yn • + hby   ,                        (13)
                                     ft

    where yk is an approximation to yft^, and yt = f(yt, tj  is an approximation to y(tt).
    The constants a^ and & are associated with the order q, and h is the time step.  After
    dividing by hb, Equation 13 becomes a  numerical approximation to Equation 12 involving
    only the values of y at yn, yn_lt  ..., vl5 or

                                  y, • T E  Y, r..t  ,                           (i*)
   where
                                    70  =T
91124R2.05
                                         25
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     If we define
     then the solution to Equation 14 can be reduced to solve the nonlinear system
     g(yn) = 0 by successive approximations.

     Newton's method is used to find yn so that g(yn) = 0.  Newton's method is also iterative,,
     The successive approximations to yn from Newton's method, called yn,m) (where
     m = 0, ..., m - 1, and m is the maximum number of iterations allowed), are calculated
     from the following:
    where the derivative of g(yn(m)) is with respect to yn(my  This derivative is the matrix
    y0 1 - J, where J is the Jacobian matrix of v at time /_ , .  Call the matrix g '(y   ») =
                                                                             (m)
    P(m).  Then the calculation of yn is as follows:
                                        E
                                        m-0
    where
          m  =
          »j»  —
the number of iteratives performed
a row vector of constants for the BDF method
the estimated truncation error occurring during step 3 of equation 16.
    The calculation of p;1 8(y«m))  is performed by Cholesky's method, whereby Pm is
    factored into a lower and upper triangular matrix, L and U respectively; then the matrix
    multiplication is equivalent to the multiplications U(yn(m+l) - y   ,) = B and LB =
           which are both simple triangular linear systems.
   At intervals of q + 2 time steps, the Gear algorithm attempts to choose a larger time step
   h, by estimating the local truncation errors at orders q -  1, q, and q + 1.  By allowing
91124R2.05
                                         26
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    the truncation error to be as large as the desired tolerance, the maximum value of h',
    obtained at orders q — 1, q, and q + 1, is chosen as the new time step.

    Because of the extreme complexity of the numerical solution technique, detailed
    flowcharts at the subroutine level are not included in this user's guide.  Questions
    concerning the numerical method may be answered by referring to the original paper by
    Gear (1971) or by contacting Systems Applications International (SAI).
    2.3.2  Steady-State and Newton's Method Solution Technique

    We can make the differential equation system less stiff, depending on individual
    application, by assuming that the fast-reacting radicals are in steady state, i.e., that their
    reactions occur instantaneously.  This results in a set of algebraic expressions where the
    radical species concentrations can be expressed in terms of the concentrations of the other
    species (the state variables).

    The steady-state solution technique  integrates Equation 12 using a method based on the
    trapezoid rule. Again, let yk be the numerical approximation to the exact solution, y(tk),
        yk + fly^i) b6 tne numerical approximation to y(tk).  The calculated solution at time
    tnis
Vn-
 n-i
                                               (In-!
(17)
    This method is implicit, i.e., the solution at tn is dependent upon the rate of change
     y* at tn-  The solution is found by successive iterations of Equation 17 to generate a
    prediction y. and using this y. to calculate  yf.  To increase the rate convergence of
    this iterative process, Newton's method is used on the equation

                                  = y, - y>-i -OU + yj  .
    The solution is found by successive approximations of

                                       .        n ""*
   where
                                             * &
                                             2 dy
                                             (18)
91124R2.05
                                          27
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     The system of Equation 18 is solved by decomposing Pn(m) into a lower and upper
     triangular matrix, then solving for the correction term (DQm in the equation
     Finally,
     2.4  CHEMICAL KINETICS MECHANISM

     The RPM-IV is supplied with inputs for an update of version IV of the Carbon Bond
     Mechanism (CBM-IV) (Gery, Whitten, and Killus,  1988).  Since the chemical mechanism
     for the KPM-IV is an input, alternative chemical mechanisms can be easily used in the
     RPM-IV. The RPM-IVSS is configured with the updated CBM-IV and, at this time,
     cannot be exercised with an alternative chemical mechanism.  The carbon-bond concept
     was developed mainly to simplify chemical kinetics mechanisms used in atmospheric
     modeling (Whitten, Killus, and Hogo, 1980).  Therefore, the simple procedures
  .  developed for earlier versions of the Carbon-Bond Mechanism, as used in the Empirical
     Kinetics Modeling Approach (EKMA), make it possible to update the mechanism without
     extensive revision of its structure.   This mechanism is actually a hybrid of explicit
     chemistry, surrogate approximations, and lumped/generalized chemistry designed to
     simulate the broad features of urban smog chemistry.  Explicit chemistry is used to treat
    the inorganic and carbonyl species plus the chemistries  of formaldehyde, ethene, toluene,
    and xylene. The carbon-bond lumping method is used primarily for paraffins and olefins.

    Each part of the CBM-IV chemistry, such as the inorganic subset or the ethene
    chemistry, conforms to current reviews of studies in the literature and has  been
    extensively tested against smog chamber data on organics/NOx systems, including
    complex mixtures intended as surrogates for urban air samples. In addition, the entire
    CBM-IV  has been used to replicate the results  of a series  of smog chamber experiments
    on automobile exhaust and synthetic automobile exhaust for a variety of conditions.  Most
    of the smog chamber experiments used for CBM-IV testing were performed in the
    outdoor dual-chamber facility of the University of North Carolina, which is a well-
    characterized chamber with extensive analytical capabilities. The CBM-IV has also been
    tested against experimental data from chambers at the University of California at
    Riverside and Battelle Columbus Laboratories.

    The 1988 version of the CBM-IV was updated in 1991 to  include (1) new chemical
    reaction rates and temperature dependence for three reactions involving PAN chemistry,
          n *                       in EKMA is discussed by H°g° a** Gery (1988), Hogo and
         n (1985), Killus and Whitten (1984), and Gipson (1984). The development of the CBM-IV
   is described in detail by Gery, Whitten, and Killus (1988).
91124R2.05
                                        28
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    and (2) the addition of an XO2-HO2 reaction.  The RPM-IV can be exercised with either
    the 1988 or 1991 version of the CBM-IV (or any other chemical mechanism) by simply
    changing the input file.  However, the RPM-IVSS can use only the 1991 version because
    the steady-state solution  involves a complicated algebraic solution for the radical species
    concentrations.  Implementing this latter solution for the 1988 version of CBM-IV would
    involve extensive receding of the program.

    The CBM-IV consists of 34 chemical species, which include nine groups of primary
    organic species  (see Table 1), and 82 chemical reactions. The species MR represents the
    nonreactive part of such  molecular species as benzene, ethane, and acetylene.  The
    concentrations of several species whose concentrations do not  vary (such as O2 and Nj)
    are lumped in with the rate constant.

    The CBM-IV contains 11 photolysis reactions (j-values) that vary with solar zenith angle
    (Table 2). The photolytic rate constants for NO2 are stored in RPM-IV as a function of
    zenith angle and may be  invoked as a user option.  These rates, derived by Jeffries and
    Sexton (1987) and Gery, Whitten, and Killus (1988), are the recommended J-values
    (Table 3). The  default values represent the reaction rate constants at approximately 640
    m above sea level (these  values are more representative of the entire mixed layer).

    Three of the photolysis reactions shown in Table 2 (Reactions  8, 14, and 23) vary with
    zenith angle  in a manner proportional to that of NO2 photolysis.  The photolytic rate
    constants  for these reactions can be described by applying a single multiplication factor to
    the NO2 photolytic constants; for example, the multiplication factor for Reaction 8 is
    0.053.

    Seven of the reactions in  Table 2 have photolysis rates  that vary with zenith angle
    independent of NO2 photolysis.  For four of these reactions (Reactions 9, 38, 39, and 45)
    the default ratios of the photolysis rates to the NO2 photolysis rate are stored in RPM-IV
    as shown  in Table 4.                                                              '

    Photolysis of two of the species shown in Table 2 (OPEN and  MGLY) has a zenith-angle
    dependency similar to that of formaldehyde photolysis to radicals (Reaction 38);
    photolysis of H2O2 has a  zenith-angle dependency similar to that of the photolysis of
    formaldehyde to stable products (Reaction 39). Therefore, for these reactions the zenith-
    angle-dependent ratios given in Table 4 are used as default values and are multiplied by
    the factors given in Table 2. If rates other than those in Table 4 are used, the factors
    given in Table 2 may have to be recalculated to maintain the same absolute rate constant.
91124R2.05
                                        29
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                          TABLE 1.  Carbon numbers
                          (carbon atoms per molecule) of
                          groups of primary organic
                          species in CBM-IV.
                          Carbon
                          Bond             Carbon
                          Group            Number
                          PAR
                          ETH
                          OLE
                          TOL
                          XYL
                          FORM
                          ALD2
                          ISOP
                          NR
1
2
2
7
8
1
2
5
1
9II24R1.05
                                       30
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  TABLE 2.  CBM-IV photolysis reactions.
 Reaction
  Number
        Reaction
                                                       Photolysis Rate
      1
      8
      9
    14
    23
    34
    38
    39
    45
    69
    74
 NO2 + hv -> NO' + O
  O, + hv -> OfP)
  Oj + hv -> O('D)
 NO, + hv -> 0.89 NOz + 0.89 O(*P)
HNO2 + hv -> NO + OH
H2O2 + hv -> 2 OH
FORM + hv -> 2HO2 + CO
FORM + hv -> CO
ALD2 + hv -> X02 + 2H02 + CO +
OPEN + hv -> CA,  + HO, + CO
MGLY + hv -> C20, + H02 + CO
        See Table 3
        0.053 x k,*
       . See Table 4
+ 0.11 NO  33.9 xk,
        0.1975xk,*
        0.189xkM*
        See Table 4
        See Table 4
FORM  See Table 4
        8.40 x k3fi*
        8.96 x k,R*
 * Photolysis rate factors for specifying the ratio of recommended NO, rates (Table 3) and
 HCHO rates (Table 4) must be recalculated if NO2 and HCHO rates other than the
 recommended values are used. That is, new ratios may have to be calculated for these
 species if the reference rate is changed.
91124.02
                                    31
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                       TABLE 3. Nitrogen dioxide (NO2)
                       photolysis rate constants stored
                       in RPM-IV.
                       (Source: Jeffries and Sexton, 1987)
Zenith
Angle
0
10
20
30
40
50
60
70
78
86
Rate
Constant*
0.5893
0.5851
0.5713
0.5470
0.5093
0.4537
0.3740
0.2578
„ 0.1341
0.0242
                       * Units are mur1.
91124,02
                                          32
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                                    3  INPUT DATA
                       ^     J° m° "* "^ * divided rato five ^o"*. each of
                             *ubj°utine:  INPUT, CHEMIN, SORCES, MEIIN, and
                               ** "*" by eadl °f **" «"*»*» can be sununarized
                  reads a section consisting of variables that define the type of plume
           simulation, the duration, the location, the output interval, and other plume
           definition and program flow variables.

                        variables that define the chemical mechanism: (1) the RPM-IV
                      65 *? Pr0dUCt ^^ "* defmed "^ with ^ ^tion rates and
                     dependence; and (2) for the RPM-IVSS, only the reaction rates aS
           temperature-dependent values are used, and these must correspond to the CBM-
           IV.  The initial concentrations of the plume are also defined here.
£QE£ES reads data for emission injections, including stack parameters and
^mission
                                                                           source
          MEON reads meteorological and ambient (background) species concentrations,
          plume expansion rates, and photolysis reaction rates.

                        the parameters governing the^display of the results of the RPM-IV
   3.1  VARIABLES READ BY SUBROUTINE INPUT
                                       ^

91124r2.06
                                      35
-------
            INCOM


            MODE1
   S^chaiacter comment, usually identifying data source or simulation
   information.

   Operating mode:

   1  = Single plume simulation.
   2  « Multiple plume simulation. (Option not available at this time.)
            MODE2    Operating mode:
                       1 - Ambient (i.e., background) simulation only.
                       2 = Plume simulation only.
                       3 = Ambient simulation followed by plume simulation
           MODES"    Operating mode:
          NCELLS


          ISAVE
          TINCR1

          XBEG
                       1 = Near-source simulation, elliptical cross sections.
                             (Not operational.)
                       2 = Near source merging to far source; elliptical cross
                             section merging to uniform vertical mass distribution (not
                             operational).
                       3 = Far source simulation; rectangular cross section
                             (uniform vertical mass distribution).
           HALF      Half plume option:
 T - Calculations are performed on half of the plume
       (symmetry about the centeriine). This option is more
       economical than HALF = F.
 F = Calculations are performed on entire plume.
       Asymmetric plume allowed.

 Number of cells across the plume (far source simulation)
 It must be an even integer between 2 and 10 inclusive.

 Flag indicating whether or not output is to be saved on disk.

 1 = Save output.
 0 = Do not save output.

Interval between successive outputs  (min.).

Initial distance downwind of point source (meters).
9tI24r2.06
                                       36
-------
           XEND

           TBEG

           TEND

           DEFNW

           FACTOR
           HSTART

           HMEST

           HMAX



           TOL

           ALONG


           ALAT

           TZ


           TSTRT

           NYR

          NMTH

          NDAY

          IOUT
  Final distance downwind of point source (meters).

  Beginning time of simulation (min.).

  Ending time of simulation (min.).

  Definition of plume width (in multiples of sigma-y).

  Distance factor for calculating gradients across plume "edge".
  (Currently the parameter is set equal to the width of the outer cells in
  the sample data set. Extensive tests have not been conducted to
  determine the sensitivity of the model to this parameter).

  Initial time step (min.).

 Minimum time step (min.).

 Maximum time step (min.).

 Error bound used hi the ordinary differential equation system solver.

 Tolerance limit for steady-state approximation.

 Longitude of location in degrees (or fraction thereof). Must be
 positive for U.S.A. (i.e., east longitude).

 Latitude of location in degrees (or fraction thereof).

 Time zone at location (5. = Eastern,  6. =  Central, 7. = Mountain
 8, = Pacific standard times).                                   '

 Starting time of simulation hi 24-hour form (6:00 p.m. = 1800).
            »
 Year of simulation (e.g., 1988).

 Month of simulation (1-12).

 Day of simulation (1-31).

 Output option:

 1 =  Output at time intervals given by  TJNCR1.
2 =  Output at user-specified downwind distances.
3 =  Output at both time intervals and  downwind distances.
91124r2.06
                                        37
-------
           NDIST     Number of downwind distances for which output is to be printed.
                      (Not used when IOUT = 1).

           DIST       Array (dimensioned NDIST) containing downwind distances in
                      increasing order (this record should not appear in the input stream
                      unless IOUT = 2).

    The structure of the records read by the INPUT subroutine is shown  in Table 5.
    TABLE 5.  Structure and format of records in the first section of the RPM-IV input
    file, read by the INPUT subroutine.
Record
1
2
3
4
5
6
7
8
9
10
11
12
13
Variables
(INCOM(D,I=1,20)
MODE1 , MODE2,MODE3
HALF
NCELLSJSAVE '
TINCR1 •
XBEG.XEND
TBEG,TEND
DEFNW,FACTR
HSTART,HMIN,HMAX,EPS,TOL
ALONG, ALAT,TZ,TSTRT,NYR,NMTH,NDAY
IOUT,NDIST
(DIST(I),I=a,NDIST) [only if IOUT * 1]
(DIST(D,I=9,10) [only if IOUT * 1, NDIST > 8]
Format Type
(20A4)
(314)
-------
     3.2 VARIABLES READ BY SUBROUTINE CHEMIN


     CHEMIN reads variables in the second section of the input file, which define various
     types of chemical species within the chemical kinetics package, chemical reactions
     chemical reaction rates, and initial concentrations. These variables are as follows:'


           CHMCOM  An 80-character comment relating to the chemical kinetics package
                      being used.                                        v   5
           NRXN


           NDIF



           NSTS


           NUNC


           NINT


           NTOT


           NFLW
          SRK
 Number of chemical reactions.


 Number of differential species (i.e., dependent variables in the
 ordinary differential equation system).


 Number of steady-state species.


 Number of uncoupled species (products only).

 Number of inert or constant species.


 Total number of species (= NDIF + NSTS + NUNC + NINT)

 Number of flowing (entrained) species
          NMRC     Two-dimensional array (MAXRCT,NRXN) containing the names of
                     the reactant species for a given reaction.


          COEFF     Two-dimensional array (MACPRD,NRXN) containing the
                     stoichiometric coefficient for each product species for each reaction.
                                                «

          NMPD     Two-dimensional array (MACPRD,NRXN) containing the name of
                     the product species for a given reaction.
Array (dimensional NRXN) containing the rate constant for the
particular reaction.
         ACTEN     Array (dimensional NRXN) containing the activation energy (K) for
                     the particular reaction.                               *
         MAXRCT  ^f??111"11 number °f reactil« sPecies m 1» chemical reactions
                    (MACRCT = 4).
91124r2.06
                                      39
-------
r
                       MAXPRD   Maximum number of product species in the chemical reactions
                                   (MAXPRD = 4).

                       KEFTMP    Reference temperature (kelvins) for reaction rates in array SRK
                                   (usuaUy 298 K).

                       NAME      Array (dhnensional NTOT) containing the name of input species.

                       YY         Array (dimensional NTOT) containing initial species concentrations
                                   input in the following order:  differential species,  steady state
                                   species, uncoupled species, and inert or constant species.

                       NFLAG     Array (A4, dimensional NTOT) containing a flag indicating whether
                                   the species is emitted from the point source.

                                   T = Species is emitted from the point source.
                                   0 = Species is not emitted from the point source.
                                                                   •
                The structure of the records read by CHEMIN is shown in Table 6. Note that the
                maximum number of reacting species (MAXRCT) and product species (MAXPRD) in a
                chemical reaction input line from RPM-IV is limited to four. Thus, to prescribe a
                chemical reaction with more than four reactants or products in the RPM-IV, the  reaction
                must be split into a series of reactions, each limited to four reactants and products, whose
                sum equals the original desired chemical reaction.
             9U24r2.06
                                                    40
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    3.3   VARIABLES READ BY SUBROUTINE SORCES

    SORCES reads variables in the third section of the RPM-IV input file, which include
    point source location information and emission inventories.  Emission rates may be
    specified in units of ppm • m3/s or g/s. The latter option requires additional information
    on ambient pressure (mb), temperature (kelvins), and the molecular weight of each
    emitted species.  These variables are used in the units conversion.  The variables are as
    follows.

          SRCCOM  80-character comment on the point source.

          NSORCS   Number of point sources to be input (maximum of 10). If
                     NSORCS = 0, no additional input records will be read by subrou-
                     tine SORCES.

          PLROPT   Plume rise option. When set to 2, the model will calculate plume
                     rise for the first injected source.  If this option is exercised, another
                     data record specifying the stack parameters must be inserted next.
                     This record should not be included if PLROPT * 2.

          ISTAB     Stability. This variable should be specified whether or not it is also
                     input through subroutine METIN.  If stability is input through
                     METIN in time-dependent form, the METIN stability input will
                     supersede the SORCES stability input.

          HSTACK   Stack height (m). Not needed if PLROPT * 2.

          DSTACK   Stack diameter (m). Not needed if PLROPT & 2.
                                                *
          VSTACK   Stack exit velocity (m/s).  Not needed if PLROPT *  2.

          TSTACK   Stack gas temperature at exit (°K).  Not needed if PLROPT y& 2.

          TAMB     Ambient temperature at exit (°K).  Not needed if PLROPT & 2.

          DSTNCE   Array containing downwind distance of each point source to be
                     injected (maximum dimension of 10).

          NSPECS    Array containing the number of species emitted for each point source
                     (maximum dimension of 10).
911Z4r2.06
                                      42
-------
           IUNTTS
           PRESS
           TEMP
Array containing the emission rate option for each point source
(maximum dimension of 10).

1 = Units are g/s
2 = Units are ppm • m3/s

Ambient pressure input for a particular point source (mb)  Not
needed if IUNTTS == 2.

Ambient temperature input for a particular point source (Kelvins)
Not needed if lUNTTS =2.
           NAMESP   Two-dimensional array (NSPECS(J),J) containing the name of each
                      emitted species for each point source.

           EMRAT2   Two-dimensional array (NSPECS(J)tJ) containing the emissions rate
                      (in either ppm - m3/s or g/s) for each species and each point source.

           ZMOLWT  Two-dimensional array (NSPECS(J),J) containing the molecular
                      weight of each species for each point source.  Not needed if lUNTTS
                      = 2.

    The structure of the records read by SORCES is shown in Table 7.
91124r2.06
                                        43
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     3.4   VARIABLES READ BY SUBROUTINE METIN

     Subroutine METIN reads data in the fourth section of the RPM-IV input file  which
     consists of meteorological data and ambient species concentrations. A number of optional
     input procedures are included for the user's convenience. Wind speeds are currently
     specified as a function of downwind distance only. Horizontal dispersion may be
     specified by a list of plume widths as a function of downwind distance, or by providing
     stability information and allowing plume width calculations to be calculated by the model
     Vertical dispersion may be specified by providing an array of plume depths at specific
     downwind distances or it can be calculated by the model. If the latter option is Selected
     stability and mixing depth input are required.                                      '

     Photolysis rate constants may be provided in any of several ways.  The model will
     calculate photolysis rates automatically from location  and time information read by
     INPUT PHOT =  T, LDFLT = T). These photolysis rates are for the CBM-IV
     Alternatively, the model will calculate photolysis rates from user-specified time-dependent
     zenith angles (LPHOT = T, LDFLT = F). This option requires additional infonLion
     to identify the photolytic reactions.  Finally, the user  may supply the complete set of
     photolysis rate constants (LPHOT = F, LDFLT  = not applicable)  and  photolytic reaction
     identification. One of the latter two options must be used if a chemical mechanism other
     man CBM-rV. is used.
    3.4.1 METIN Header Records

          METCOM  Array (maximum dimension 20) containing comments relating to
                      meteorological input

          WNDOPT  Wind input option.
                                                  *

                      1 =   User-input array of wind speeds at specific times.
                      2 =   Option not available.

          HDSOPT    Horizontal dispersion option.

                      1  =   User-input array of plume widths at specific downwind
                            distances.
                      2  =   Plume widths are automatically calculated using Pasquill-
                            Gifford dispersion curves.  (Stability information is required.)
91124r2.06
                                        45
-------
          VDSOPT   Vertical dispersion option.

                     1 =  User-input array of plume depths at specific downwind
                           distances.
                     2 =  Plume depths are automatically calculated using Pasquill-
                           Gifford dispersion curves. (Stability information is required
                           unless provided under HDSOPT = 2 option. Mixing depth
                           information is also required.)

          AMBOPT   Ambient concentration option.

                     1 =  Concentrations are input at various times. If MODE2  = 1,
                           the concentrations specified after the initial values are ignored.
                     2 =  Option not available.
   3.4.2 Wind Data
          NWIND    Number of wind speeds to be input (maximum of 10).

          WINDSP   Array (maximum dimension of 10) containing wind speeds in meters
                     per second (m/s).

          WHME    Array (maximum dimension of 10) containing times (in minutes from
                     start of simulation) corresponding to the wind speed input.
   3.4.3 Horizontal Dispersion Data

         NRAD      Number of plume widths to be input (maximum of 30).  Used when"
                     HDSOPT =  1.
                                                 «

         XRAD      Array (maximum dimension of 30) containing downwind distances
                     (meters) corresponding to the plume width input.  Used  when
                     HDSOPT =  1.

         WIDTH     Array (maximum dimension of 30) containing the plume widths
                     (meters).  Used when HDSOPT = 1.

         NSTAB     Number of stability values to  be input (maximum of 30). Used when
                     HDSOPT = 2.
91124r2.06
                                         46
-------
           T1MSTB    Array (maximum dimension of 30) containing times (minutes from
                      start of simulation) corresponding to the stability input data  Used
                      when HDSOPT = 2.
           ISTB
 Array (maximum dimension of 30) containing stability input data
 (1-6, corresponding to PGT stability classes A-F). Used when
 HDSOPT = 2.
     3.4.4 Vertical Dispersion Data Records
           NMDC
           XMIX
          DEPTH
          NMX
          XMX
          DPTH
 Number of plume depths to be input (maximum of 30). Used when
 VDSOPT = 1.


 Array (maximum dimension of 30) containing downwind distances
 (meters) corresponding to the plume depth input data  Used when
 VDSOPT = 1.


 Array (maximum dimension of 30) containing plume depths (meters)
 Used when VDSOPT = 1.

 Number of mixing depths to be input (maximum of 30).  Used when
 VDSOPT  = 2.                                  •


 Array (maximum dimension of 30) containing downwind distances
 (meters) corresponding to mixing depth input.  Used when VDSOPT
 == 2.                            .


Array (maximum dimension of 30) containing mixing depths
(meters). Used when VDSOPT = 2.
    3.4.5 Photolysis Rate Constant Data


         LPHOT     Logical variable for photolysis rate constant specification.

                     T =   Photolysis rates are automatically calculated from solar zenith
                           angles corresponding to user-specified location and time data.
                     F -   User specifies photolysis rates as a function of time.

         LDFLT     Logical variable for determining photolytic reaction input Do not
                     provide if LPHOT  = F.
9I124r2.06
                                       47
-------
          KPHOT
          NPHOT


          KPHOT


          NOTHR
         KOTHR
         NPHTM
         TPHT
         FCTPHT
         NVALS
 T =  Photolysis rates for CBM-IV photolytic reactions are
      automatically calculated. User must supply reaction number
      information.
 F =  User supplies photolysis reaction rates as a function of solar
      zenith angle.

 Array (maximum dimension of 20) of photolytic reaction numbers.
 The order of the reaction numbers must be as follows: (1) NO2 -*,
 (2) 03 -» O3?, (3) 03 -* O^, (4) N03 -, (5) HNO2 -, (6) H2O2 -,
 (7) FORM -" CO, (8) FORM -* radicals, (9) ALD2 -+, (10) OPEN
 -», (11) MGLY -*. Numbers must be provided regardless of LPHOT
 and LDFLT values.

 Number of photolytic reactions (maximum of 20). Provide when
 LDFLT = F and LPHOT = T or when LPHOT = F.

 Array (maximum dimension of 20) containing the photolytic reaction
'numbers. Used for all photolysis rate-constant options.

 Array (maximum dimension 20) containing the number of additional
 photolytic reactions whose rates are proportional to each of the
 NPHOT reactions. Do not provide when LPHOT = T,
 LDFLT = T.

 Two-dimensional array (maximum dimensions (10,20)). Reaction
 numbers of the NOTHR reactions whose photolysis rates are
 proportional to each reaction number KPHOT of the NPHOT
 reactions. Do not provide when LPHOT = T, LDFLT = T.

 Number of photolysis reaction  rates input as a function of time
 (maximum of 10).  Provide only when LPHOT = F.

Array (maximum dimension of 10) containing the NPHTM times
corresponding to the photolysis rate-constant input.  Provide only
when LPHOT = F.

Two-dimensional array (maximum dimensions (10,20)) containing the
NPHTM photolysis reaction rates for each of the NPHOT reactions.
Provide only when LPHOT =  F.

Number of zenith angles (maximum of 11) for which photolysis rates
are specified.  Provide only when LPHOT = T and LDFLT = F.
91124r2.06
                                       48
-------
           ZEN
           RPHT
 Array (maximum dimension of 11) of zenith angles (in degrees).
 Provide only when LPHOT = T and LDFLT = F.

 Two-dimensional array (maximum dimensions (11,11)) containing the
 photolysis rates as a function of zenith angle for the NPHOT
 reactions. Provide only when LPHOT - T and LDFLT = F.
    3.4.6 Ambient Temperature Data

          NTEMP    Number of time-dependent input temperatures (maximum 10).

          TTIME     Array (maximum dimension of 10) containing the times correspond-
                      ing to the temperature input.

          TEMPER    Array (maximum dimension of 10) containing the NTEMP input
                      temperatures.


    3.4.7  Ambient Concentration Data                   *


          NAMBNT  Number (maximum of 10) of sets of ambient concentration input.

          AMBNT   Array (maximum dimension of 10) containing the times at which
                     concentrations are input.
          NTEST
Local variable containing the name of the ambient species to be
input.
          AMBIN     Two-dimensional array with maximum dimensions of (4, 10)
                     containing input ambient species, concentrations at the left, right, top
                     and bottom (in sequence) of the plume.
   The structure of the records read by METIN is shown in Table 8.
91124r2.06
                                       49
-------
 TABLE 8.  Structure and format of records in the fourth section of the RPM-IV
 METIN (record numbers vary depending on choice of options).
                                                   input file, read by
    Record
                                                          Format
                                                           Type
   1
   2
(METCOM(I),I= 1,20)
WNDOPT,HDSOPT,VDSOPT,AMBOPT
Wind Specification Records

  For WNDOPT » 1
  3
  4
NWIND
(WINDSP(I), WnME(I),I= 1,NWIND)
[Use additional records if NWIND > 4]
Horizontal Dispersion Specification Records
  For HDSOPT = 1
  5
  6
  For HDSOPT
  5
  6
NRAD
(XRAD(I),WIDTH(I),I= l.NRAD)
[Use additional records if NRAD >>.4]
NSTAB
CTIMSTB(I),ISTB(I),I= 1,NSTAB)
[Use additional records if NSTAB > 4]
Vertical Dispersion Specification Records

  For VDSOPT = 1 (records define plume depth)
  7                   NMDC
  •8                   (XMDCCD,DEPTH(I),I=1,NMDC)
                      [Use additional records if NMDC  > 4]

  For VDSOPT = 2 (records define mixing depth)
  7                   NMX
  8                   (XMX(I),pPTH(I),I=l,NMX)
                      [Use additional records if NMX > 4]

  For UVSOPT = 2 and HSOPT = 1
  9                   NSTAB
  10                  (TIMSTBa),ISTB(D,I=l,NSTAB)
                      [Use additional records if NSTAB > 4]
(20A4)
(1012)
(14)
(8F10.0)
(14)
(8F10.0)
(14)
(4(F10.0,I10))
                                                          (14)
                                                          (8F10.0)
                                                         (W)
                                                         (8F10.0)
                                                         (14)
                                                         (4(F10.0,I10))
                                                                                   Continued
             91124R2.03
                                              50
-------
TABLE 8.  Continued.
Photolysis Rate Constant Specification Records
  For all options
  11
  12
  LPHOT
  LFLT    [Exclude if LPHOT = F]
  For LPHOT = T and LDFLT = T
  13                 KPHOT(1)
  14                 KPHOT(2)
                    KPHOT(11)

 For LPHOT = T or F and LDFLT = F
 15+               NPHOT
                    KPHOT(1),NOTHR(1)
                    (KOTHR(I, !),!= 1,NOTHR(1)) [Exclude if NOTHR(l) = 01
                    KPHOT(2),NOTHR(2)                       W    J
                    (KOTHR(I,2),I= 1,NOTHR(2)) [Exclude if NOTHR(2) = 0]
(L10)
(L10)
                                                         (14)


                                                         (14)
                                                        (1014)
                                                        (1014)
                                                        (1014)
                                                        (1014)
                    KPHOT(NPHOT),NOTHR(NPHOT)
                    (KOTHR(I,NPHOT),I= 1 ,NOTHR(NPHOT))
                    [Exclude if NOTHR(NPHOT) = 0]

 For LPHOT = T and LDFLT = F
 16 +                NVALS
                    ZEN(1),(RPHT(1,I),I=1,NPHOT)
                    [Continue list of RPHT(1,I) if NPHOT > 7]
                    ZEN(2),(RPHT(2,I),I= 1 .NPHOT)
                    [Continue list of RPHT(2,I) if NPHOT *• 7]
                                                        (1014)
                                                        (1014)
                                                        (14)
                                                        (8F10.0)

                                                        (8F10.0)
For LPHOT=F
17+
ZEN(NVALS),(RPHT(NVALS,I),I= 1,NPHOT)
[Continue list of RPHT(NVALS,I) if NPHOT > 7]


NPHTM
TPHT(1),(FCTPHT(1,I),I== l.NPHOT)
[Continue list of FCTPHT(1,I) if NPHOT > 7]
TPHT(2),(FCTPHT(2,D,I== l.NPHOT)
[Continue list of FCTPHT(2,I) if NPHOT > 7]
                                                                          (8F10.0)
                                                                          (8F10.0)
                                                                          04)
                                                                          (8F10.0)

                                                                          (8F10.0)
                   TPHT(NPHTM),(FCTPHT(NPHTM,D,I= 1,NPHOT)
                   [Continue list of FCTPHT(NPHTM,I) if NPHOT > 7]
                                                       (8F10.0)
                                                                             Continued
                                      51
           91124R1.03
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TABLES. Concluded.
   Record
                                                       Format
                                                        Type
Ambient Temperature Specification Records
   18+
   19+
NTEMP
(TTIME(r),TEMPER(I),I= l.NTEMP)
Ambient Concentration Specification Records
  For AMBOFT « 1
  20+
                         NAME
                         (AMBT(T),I= l.NAMB)
                         NTEST,(AMBIN(I,1),I= 1,4)*
                                                                                (8F10.0)
                                                       (8F10.0)
                                                       (A4.1X.7F10.0)
                         (AMBIN(I,NAMB),I= 1,4)*
                         NTEST,(AMBINa, !),!= 1,4)*
                                                       (5X,4F10.0)
                                                       (A4,1X,7F10.0)
                         (AMBIN(I,NAMB),I= 1,4)*
                                                       (5X.4F10.0)
                         [Total number of records equals NFLW]
*  I - 1 in RPM-IV.
                                          52
              91124R1.03
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     3.5  VARIABLES READ BY SUBROUTINE RESULT

     RESULT reads the fifth and final section of the RPM-IV input file, which contains
     variables that define the data needed to summarize the model simulation results  There
     are several options for specifying summary output.  Plume-average and plume-cell
     maximum concentrations may be displayed or concentration maxima and the
     corresponding times and downwind distances may be listed.  The variables read bv
     RESULT are as follows.                                                J
           NSPEC
 Number of species for which concentration histories will be displayed
 in summary format (maximum of 40).  The summary format consists
 of time series plots and, as a user option, maximum concentration
 tables.
          IPLOT      Code for plotting results.

                      0 =  Plot plume averages as a function of time.
                      1 =  Plot plume maxima as a function of time.
                      2 =  Plot both plume average and maxima as a function of time.
          IPRINT
          IMAXC
         ISPEC
         IFORD
 Code for printing maximum concentrations.
                     0 =
                     1 =
                     2 =
                     3 =
       Do not print maximum concentration.
       Print maximum plume-average concentrations.
       Print maximum cell-average concentrations
       Print both plume-average and cell-average maxima.
 Code for determining conditions under which maximum concentra-
 tions are selected.
                     1 =
                     2 =
                     3 _
      Consider all concentrations.
      Consider concentrations beyond plume touchdown.
      Consider concentrations beyond the "vertically well-mixed"
      critical distance.
Array (maximum dimension of 40) of species names in character
format.

Array (maximum dimension of 40) containing the reciprocal of a
reduction factor influencing the range of the concentration plot
ordinate for each species to be plotted.
91124r2.06
                                     53
-------
                      0 or 1 = No reduction of ordinate range.

                      2 - 99 = Reduction of ordinate range by a factor of approximately
                               1/2 to 1/99.

    The structure of the records read by RESULT is shown in Table 9.
    TABLE 9.  Structure and format of records in the fifth section of the RPM-IV input file, read by
    RESULT.
        Record
Format Type
          1   NSPEC,IPLOT,IPRINT,IMAXC

          2   aSPEC(I),IFORD(I),I=l,NSPEC)
(412)

(15(A4,I2)
91124r2.06
                                       54
-------
                              4  EXAMPLE SIMULATIONS
     This chafer-describes several RPM-IV example runs that illustrate how to run the model
     m several different modes.  The input files for these test runs are shown in this chapter
     but ^e output files are presented in Appendix C. Most of the test runs are demonstated
     using the RPM-IV, although the RPM-IVSS could also be used for most of these
     examples.  However, those examples that involve modifications to the CBM-IV chemistrv
     input cannot be .performed using the RPM-IVSS  since the RPM-IVSS can only be
     exercised with the CBM-IV.                                           y

     The  first three sets of test simulations illustrate how to run the RPM-IV and RPM-IVSS
     for the three types of simulations:  ambient-only, plume-only, and ambient followed by
     plume.  The fourth test is an example of an air quality impact assessment of emissions
     from a point source. This example includes step-by-step instructions for performing such
     an assessment. The emissions data and meteorological conditions are hypothetical and
     should not be used in an actual assessment.
    4.1 TEST 1:  AMBIENT-ONLY SIMULATION (MODE2 = 1)

    This section briefly describes the structure of the input data required for an "ambient-
    only  i.e., background) simulation (MODE2 = 1), as in a box model or smog chamber
    simuktion  Test 1 uses extremely dirty initial concentrations corresponding to the default
    conditions for OZDPM/EKMA derived from conditions in Los Angeles on 21 JuN  1976
    These conditions are not representative of current air quality conditions in Los Angeles or
    elsewhere and are used here only for demonstration purposes.  Test 1 was run three
    different ways:                                                        ««•-*'

          Test 1.1: Using RPM-IV and the 1991 version of the CBM-IV chemistry

          Test 1.2: Using RPM-IV and the 1988 version of the CBM-IV chemistry

          Test 1.3: Using RPM-IVSS and the 1991 version of the CBM-IV chemistry
91124r2.14
                                     55
-------
    The Carbon Bond Mechanism IV (CBM-IV) was released in 1988.*  In 1991 the EPA
    recommended two minor updates: an update to the chemical reaction rates and activation
    energies for three reactions involving PAN, and the inclusion of an XO2-HO2 reaction.
    Since the RPM-IV reads in the chemical mechanism from the input file, both the 1988
    and 1991 versions of the CBM-IV can be demonstrated in this version of RPM.
    However, since the 1991 CBM-IV is "hard-wired" in the RPM-IVSS, only that version of
    CBM-IV can be used in the RPM-IVSS.
    Test 1.1: Using RPM-IV and the 1991 Version of CBM-IV

    Input File

    Many of the input variables read by RPM are not used for an ambient-only simulation.
    These variables include NCELLS, DEFNW, FACTR,  NFLAG, and all plume dimensions
    input beyond the first value. Time-dependent temperatures and wind speeds are used, but:
    time-dependent mixing depth and stability data are not. The species concentrations in the
    second section of the input file (read by CHEMIN) are used as initial values in the
    ambient-only simulation only if NFLAG  5* 1.  If NFLAG = 1, the program replaces
    these values with those specified as background concentrations hi the fourth section of the
    input file (read by METIN). This is an artifact of the  MODE2 = 2 plume simulation,
    which requires both initial plume and ambient concentrations.  For an ambient-only
    simulation it is generally good practice to match all initial concentration values read by
    CHEMIN with the background concentration values read by METIN, and set NFLAG
    = 0.  The sample input stream for this test run is shown in Exhibit 4-1. (All exhibits
    will be found at the end of the  chapter.)

    Note that output is specified for 60-minute intervals (IOUT = 1).  A variable wind speed
    has been specified (NWIND = 2), though this  affects only the relationship of the
    downwind distance to the simulation time for an ambient-only simulation.  Since output
    for specific downwind distances is not desired,  the variable wind-speed information is
    extraneous.  Note that as a consequence of specifying NFLAG = 1 for the inert tracer
    species (TRAC), initial and subsequent concentrations are zero.

    The last two input records contain information for the summary output.  Four species are
    to be displayed (NO2, NO, O3, and FORM).  For this ambient-only simulation the
    second and fourth variables in the second record from the end (TPLOT and IMAXC) are
    not used.  The third variable (EPRINT) signifies that maximum concentrations during the
    simulation are to be tabulated.  Since no emissions are  involved in the simulation, scaling
    the ordinate of the concentration plots is not necessary.  In the last input record (BFORD)
     M. W. Gery, G. W. Whitten, and J. P. Killus.  1988. Development and Testing of the
     Carbon-Bond IV Mechanism for Urban and Regional Modeling. U.S. Environmental Protection
     Agency (EPA-600/3-88-012).
91124r2.14
                                        56
-------
     the integers adjacent to the displayed species names, which specify plot ordinate scaling
     are left blank and therefore read as zero and interpreted by the plotting subroutines as 1
     (i.e., no ordinate reduction).
     Output File

     The entire output for this version of the first example problem (test 1.1) is shown in
     Appendix C-l.  This output at first contains the problem definition (i.e., run mode time
     step selections, length of simulation, location, and time of year) followed by the chemical
     mechanism input, and the initial concentrations. The output data of model input
     parameters is followed by the calculated concentrations for the CBM-IV species and the
     reaction rates for the chemical reactions.  The end of the output file contains time series
     of species concentrations for those species selected in the input and information on the
     maximum concentrations for these same species.


     Test 1.2: Using RFM-IV and the 1988 Version of CBM-IV

     This run is similar to the previous one except that the 1988 version of the Carbon Bond
     Mechanism IV is used.
    Input File

    The input file for test 1.2 using the RPM-IV with 1988 CBM-IV chemistry (Exhibit 4-2)
    is^most exactly the same as for test 1.1 using the 1991 CBM-IV chemistry. The only
    differences are in the CHEMIN section of input, as follows.

          The number of chemical reactions is decreased from 95 to 94 to eliminate the
          XO2-RO2 chemical reaction;

          The older chemical reaction rate constants and activation energies for reactions 46
          47, and 48 are used; and                                                     '
                                                              aBHV> is not
    Output File
   Portions of the output for test 1.2 are shown in Appendix C-2, the output file is very
   similar to test 1.1 (Appendix C-l).                                            y
91124r2.14
                                        57
-------
    Test 1.3: Using RPM-IVSS and the 1991 Version of the CBM-IV

    Input File

    The input file for test 1.3 using RPM-IVSS and the 1991 CBM-IV chemistry is exactly
    the same as that used for the KPM-IV with the 1991 CBM-IV (test 1.1) and is shown hi
    Exhibit 4-1.


    Output File

    Portions of the output file for test 1.3 using the RPM-IVSS are shown in Appendix C-3.


    Discussion of Test 1 Results

    The 1991 updated CBM-IV chemistry affects the estimated ozone formation rate.  The
    peak ozone concentration estimated with the 1991 CBM-IV is 344 ppb and occurs 440
    minutes into the  simulation (Appendix C-l), compared to 373 ppb at 600 minutes (the
    end of the simulation) when the 1988 CBM-IV is used (Appendix C-2). Using either the
    1988 or 1991 CBM-IV, ozone formation slows down to approximately 345 ppb at around
    340 minutes into the simulation.  However, with the 1988 CBM-IV ozone continues to
    increase but at a very slow rate, whereas with the 1991 CBM-IV it holds constant. This
    continued slow ozone formation after around 340 minutes explains the difference in the
    peak ozone concentrations hi the two simulations.

    The effects of the steady-state chemistry numerical solution procedure on the estimated
    ozone (and other species) concentrations is seen by comparing the plots hi Appendices
    C-l and C-3. The peak estimated ozone concentration using the steady-state chemistry
    solution procedure (RPM-IVSS) is 341 ppb at 440 minutes into the simulation (Appendix
    C-3). This is at  the same time and within 1 percent .of the peak ozone produced using the
    full chemistry solution (RPM-IV). For these conditions the steady-state chemistry
    solution procedure appears to work well.


    4.2  TEST 2:  PLUME-ONLY SIMULATION (MODE2 = 2) USING RPM-IV

    The second test was for a plume-only simulation (MODE2 = 2) using the RPM-IV and
    the 1991 CBM-IV chemistry.
91124r2.14
                                       58
-------
     Input File
     The input stream for this simulation is shown in Exhibit 4-3. Printed output is requested
     for five specified downwind distances (TOUT = 2): 10, 20, 50, 100, and 200 kn? The
     plume parameters are 10 cells, a "4 X sigma" plume-width definition, and a diffusion-
     length scale of 1  x the outer cell width. Program controls and chemistry input are the
     same as in test 1.1 using RPM-IV and the 1991 CBM-IV chemistry.  Meteorology input

     ^PT^

     This plume-only simulation illustrates the use of initial plume concentrations to define
     plume concentrations (rather than the emissions "injection" option)  For most
     applications, users will know the point-source emission rates rather than the initial plume
     concentrations. However, in some applications, such as a plume simulation based on
     aircraft measurements,  the initial plume concentrations are known.  Use of initial plume
     'T^'iT totd?fmf Plume concentrations requires identifying the emitted species
     with NFLAG - 1 in the list of initial conditions read by CHEMIN.  Identifying^ species
     as a primary pollutant allows the ambient concentration of the same species to be
     subtracted out when initializing the cross-plume concentration distribution.

     When the  emissions  injection option is not used, the model has no information on stack
     parameters and therefore no knowledge of effective stack height.  Hence the model
     cannot calculate either the plume "touchdown" distance or the distance at which the

     unSer^MnnS * f^f tO * *"**** WeU mixe£L  ™* tofonnatton » available
     under the MODE2 = 2 simulation only if the emissions are injected (i.e.,  NSORCS * 0)
    and suitab e stack  parameters are defined. Unless the user is confident that the calculated
    effective stack height will be within the initial plume depth specified using the VDSOPT
     - 1 option, the option for automatic vertical dispersion calculations (VDSOPT =  2)
    should be selected when injecting emissions in a plume-only simulation (MODE2 = 2)
    The MODE2 - 2 and VDSOPT = 1 options could be used together when the plume  s
    assumed to be confined  within the mixed layer throughout the simulation.  '

    The user should also be aware of the consequences of providing a time-varying set of
    ambient-concentration values, as in this test (see Exhibit 4-3).  Because the computer
    program linearly interpolates between input values,  unrealistic plume deficits can result at
               SS?, m -the °UtpUt Pl°ts fr°m «** test (APPeadbc C-4).  The situation
                           S aUt°matiC ainbient-concentration calculations, as done in test
   The next to last input record in the input stream (Exhibit 4-3) indicates that four species
       ° of JfS ? SUmmaiyf0nn- .e variables MOT. ™NT, and IMA^have
                      T
   a   to te       , H                       that only the plume-average concentrations
   are to be plotted and plume-average maxima tabulated.  Note also that the ordinate ranges
91124r2.14
-------
    of the plots for NO2 and NO have been reduced by 1/3 and 1/5, respectively.  This
    provides a more informative concentration history for pollutants that have high
    concentrations near the source.
    Output file

    The output file for test 2 is shown in Appendix C-4.
    4.3  TESTS: AMBIENT SIMULATION FOLLOWED BY A
    PLUME SIMULATION (MODE2 = 3) USING RPM-IV
                    •
    The third test run illustrates a more common application of the .RPM—an ambient
    simulation is first performed to provide a chemically consistent set of background
    conditions, followed by a plume simulation of the impacts of emissions from a point
    source. This run also illustrates how to add SO2 and sulfate (AERS) chemistry to the
    RPM-IV.
   Input File

   The input stream for test 3 is shown in Exhibit 4-4. This simulation consists of an
   ambient simulation followed by a plume simulation in which emissions are injected at two
   downwind distances. Routine printed output is requested both at 60-minute time intervals
   and at five specified downwind distances (TOUT = 3).  Six horizontal cells are specified.

   For this simulation, the chemistry has been extended by adding two reactions (numbers
   96 and 97) involving SO2 and sulfate aerosol (AERS). Note that the computer code is
   hard-wired to provide some of the AERS output hi units of micrograms per cubic meter
   instead of the normal units of parts per million.  Currently, only AERS is flagged for this
   treatment. The code is unaffected if the species AERS is omitted (as in tests 1 and 2).
   The chemistry modification involves creating the two additional records for the reactions
   and changing the number of differential species (NDIF) from 35 to 37.  In addition, the
   number of entrained species (NFLW) was increased by two to accommodate the two new
   species as background pollutants.

   Meteorological input for this test is somewhat different from test 2.  Horizontal and
   vertical dispersion are automatically calculated by specifying HDSOPT = 2 and
   VDSOPT = 2. Time-varying mixing-depth input is provided by the user.  Emissions
   input for two sources is provided in the emissions injection portion of the input file
   (NSORCS & 0). It is important to note that stack information only from the first source
   is used to calculate plume rise and related variables. The first source should be viewed
   as the source defining the simulated plume (i.e., the primary source). The second
91124r2.14
                                        60
-------
     source, containing sulfur emissions, is to be considered a secondary source of emissions
     that interact fully with the primary source emissions, once injected.  (In a MODE2 = 3
     simulation the primary-source emissions could be specified by initial conditions instead of
     injected emissions.  In that case, any injected emissions would represent secondary
     emissions and the plume-rise option should not be specified.  This is to avoid the
     possibility that the secondary plume's effective stack height exceeds the primary plume's
     depth and to prevent the calculations of plume "touchdown" and other critical distances
     which are strictly applicable to the primary plume.) Other options evident in the input'
     stream read by subroutine SORCES include specifying the emission rates for the first
     injection (in units of ppm-m3/s) and second injection (in units of g/s).

     Summary output is requested for five species only.  Both plume-average and plume-maxi-
     mum concentrations are to be plotted (IPLOT =  2). In addition, the peak plume-average
     and plume-maximum concentrations over the duration of the simulation are to be
     tabulated (IPRINT = 3). Candidate concentrations considered for the peak values must
     be those that are downwind of the distance at which the vertical concentration distribution
     can be considered uniform. Finally, the ordinates of the NO2, NO, O-,, SO, and AERS
     plots are scaled by 1/4, 1/10, 1/1, 1/50, and 1/50, respectively.  Note that ordinate
     scaling is needed only for emitted species, and is turned on either by setting NFLAG =  1
     (for primary source initialization without the injection option) or by specifying species
     injection, which will automatically set NFLAG = 1.


     Output File

     Output from test 3 is shown in Appendix C-5.


    4.4 TEST 4:  EXAMPLE POINT SOURCE IMPACT ASSESSMENT

    This example shows how the RPM can be used in an air quality impact assessment.
    Starting with the definition of the emission source under study,  this example illustrates an
    approach for incorporating background air quality and emission sources into the problem
    and performing a single trajectory simulation (note that an actual impact assessment
    would involve a series of trajectory simulations) to estimate the ozone impacts of the
    source. The conditions used in this example problem are hypothetical and should not be   '
    used in an actual impact assessment.  Furthermore, an RPM impact assessment should
    always include  a detailed analysis on the sensitivity of the modeled impacts to key input
    assumptions, such as initial and boundary conditions.

    In this example we will include area source emissions that occur downwind of the point

    w7te ™±C? T^ eStimad?g ^ * qUaUty  'mp&CtS'  11*» ~ source em^cms
    will Represented by a series of emission injections at various downwind distances
    Since the RPM  ambient simulation does not include emissions, in order to estimate the air
91124r2.14
                                        61
-------
    quality impact of the point source under study we must perform two RPM simulations:
    one with the point source and area source emissions and one without the point source but
    with the area source emissions.  The air quality impact of the point source emissions is
    then obtained by taking the difference between the two simulations.
    Problem Definition

    Input Parameters

    For test 4 we will use the same program flow (output intervals, etc.) and meteorological
    conditions as used in test 3.  All wind speed, mixing height, and stability inputs will
    remain unchanged.  Thus, plume expansion rates (widths and depths) will also remain
    unchanged.  However, we are changing the start day (0800 on July, 15, 1990) and the
    starting location (see below) and time zone (Mountain time).

    Point Source Emissions

    In this example problem we will estimate the air quality impacts of a NOX point source.
    We will assume this source has the following characteristics:

          Stack Height       =     100 m
          Stack Diameter     =    5 m
          Exit Velocity       =    20 m/s
          Exit Temperature    =    350 K
          NOX Emission Rate  =     1000 g/s
          Longitude          =    97.0 deg
          Latitude            =    40.0 deg

    The RPM requires NOX emissions  to be split into NO and NC^ species.! For most sources
    categories NOX emissions are split, on a molar basis, as 95 percent NO and 5 percent
    NO2.  Since NOX emissions are always reported as NO^, then 1000 g/s NOX  is equivalent
    to 21.739 mole/s (molecular weight of NO2 is 46 g/mole).  Thus, we get the  following
    emission rates for input into the RPM:

          NO Emission Rate   =    619.6 g/s (0.95 x 21.739 mole/s X 30 g/mole)
          NO2  Emission Rate  =     50.0 g/s (0.05 x 21.739 mole/s x 46 g/mole)
   Other Source Emissions

   We will assume that the point source is located in a rural area and that the trajectory of
   the plume travels through regions of rural, suburban, and urban emissions as follows: 60
   km rural,  60 km suburban, 40 km urban, 40 km suburban, and 40 km rural.  The
9ll24r2.14
                                        62
-------
     remainder of the trajectory is assumed to be a remote region with no emissions (e *  a
     lake or ocean).  Rural emission rates are assumed to be as follows:

           NOX   = 0.00001 mole/s-km2
           VOCA = 0.00003 mole/s-km2
           VOCB = 0.003 mole/s-km2

     where NO emissions are assumed to be split into NO/NC^ on a 95/5 basis, VOCp, is
     biogenic hydrocarbon emissions and are assumed to be isoprene (ISOP) and VOC  are
     ^^f^^hydr0^nuemiSSiO^S•  ^ ^th^Pog^c VOC emissions are assumed to
     be distributed (on a molar basis) among the CBM-IV species as follows:
ETH
OLE
ALD2
FORM
TOL
XYL
PAR
0.027
0.026
0.039
0.031
0.019
0.022
0.836
                        fepl!sentative of [yPicaI CfiM-IV splits for urban emissions and
    are based on the default values given in EKMA.

    We will assume that suburban and urban emissions are 50 and 1000 times greater than
    rural emissions, respectively.

    These area source emissions need to be input into the RPM as a series of emission
    ZTSt/^S   !?* I0""* emissions> cuirently sussed as emissions per unit
    are^(mole/s-km2 , need to be converted to the g/s format (or ppm-nrVs) required by the
    RPM emission injection input.  To perform this conversion we need to spectfy a

    mTth^ume6 T T1SS/°nS WU1 * u°UeCted f°r *6 Sei** Of ™M ei^sion ^
    into the plume.  We plan to represent the area source emissions using a series of six
    emission injections at downwind distances of 20, 40,  90,  140, 180, and 230 km   Area
                  J'^ ^ ^Semed- °f " """"^ Whose sides «««Pond to the width
                 •   downwind emission injection distance and the distance traveled by the

                 mjectlons'Table 4"J "^ ^ resulting ^^emission
   The emission rates given in Table 4-1 are derived by adjusting the rural emission rates
   for the proper region category, accounting for the spatial coverage of the area source
   region, and applying the CBM-IV splitting factors. For example, the PAR
   tor the third emission injection (90 km downwind) is obtained as follows:
91124r2.14
                                        63
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r
                 TABLE 10.  Area source emission rates (mole/s) used in RPM emission injections for test 4.
Downwind
Distance
Plume Width
Length
Region
Category
20
8
30
Rural
40
11
30
Rural
90
23
60
Suburban
140
33
40
Urban
180
40
40
Suburban
230
49
60
Rural
                  NO
                  NO2
                  ETH
                  OLE
                  ALD2
                  FORM
                  TOL
                  XYL
                  PAR
                  ISOP
 2.3E-3
 1.2E-4
 1.9E-4
 1.8E-4
 2.9E-4
 2.2E-4
"l.4E-4
 1.6E-4
 6.0E-3
 0.7
3.1E-3
1.7E-4
2.7E-4
2.6E-4
4.0E-4
3.1E-4
1.8E-4
2.2E-4
8.3E-3
1.0
6.5E-2
3.5E-3
5.6E-3
5.4E-3
8.3E-3
6.4E-3
3.9E-3
4.6E-3
1.7E-1
4.1
12.5
0.7
1.1
1.0
1.6
1.2
0.8
0.9
33.0
4.0
 8.0E-1
 4.0E-2
 6.5E-2
 6.2E-2
 9.6E-2
 7.4E-2
 4.6E-2
"5.0E-2
 2.0
 4.8
2.8E-2
1.5E-3
2.4E-3
2.3E-3
3.5E-3
2.7E-3
1.7E-3
1.9E-3
7.4E-2
8.8
             91124r2.14
                                                        64
-------
                                                                         or
       VOCA x Suburban Adjust x PAR split x Area (width x length),

       0.00003 mole/s-km2 x 50  x 0.836 X (23 km  x 60 km) =  1.73 mole/s

Note that we can leave the area source emissions rates in units of mole/s as long as we
specify a 1.0 molecular weight in the RPM.
     Initial Concentrations
               concentrations ^ used to defme to6 K"***1 Ptome (CHEMIN) and initial
ambient (METIN) concentrations.  These values are based on the recommended default

  U                        2   **     '                                    of
        l       Poon                             °E  » «**>* V^cBtioa of
        UAM (EPA 1991). Note that the EPA guidance gives CBM-IV species in units of
     ppbC, whereas the RPM (and UAM) require input in terms of ppb.  This conversion was
     made in specifying the initial concentration inputs for this test problem.


     Input Files

     Exhibit 4-5 and 4-6 display the two input files for test 4.  At  the top of the input file are
     the program flow parameters;  these are similar to those specified for test 3 except for a
     change of the latitude and longitude of the source (40 and 97  degrees respectively)  the
     date for the simulation (July 15, 1990), and the time zone (Mountain timeTi.e  8)  The
     program flow date are followed by the  chemical mechanism input; for this test we are
     ,UnH SH   ,* 1991™M:™ without S0* Chemistry.  The end of the chemistry input seSL
     includes the initial plume concentration values.

    There are seven emission injections in this example: the point source and six area source
    injections.   The only difference in the two input files used in this test are the poS  ou
    emissions;  the first rnput file (Exhibit 4-5) specifies the NOX emissions for the source
    whereas the second input file (Exhibit 4-6) has no emission inputs.  Since the RPM
    requires that at least one species be emitted from every point source, specifying an
                             (LE'20) °f a faMy mert substance (c°) ^ virtually no
   The meteorological inputs for test 4 are the same as test 3. The initial ambient

   Sn'ofrm'ut'fue831116 " "" ^ P'Ume «—»»*» *««- «•.«"
91124r2.14
                                        65
-------
    Output files

    The test 4 RPM-IV output files with and without the point source NOX emissions are
    shown in Appendices C-6 and C-7, respectively.  For the sake of brevity, only a portion
    of the output file without the point source emissions (Appendix C-7) is included. The
    incremental ozone impact of the point source emissions is obtained by subtracting the
    concentrations in the output in Appendix C-7 with those hi Appendix C-6.  For ozone,
    we see that the RPM estimates that the NOX emissions have the following impact on
    plume-average ozone (ppb):
          Time
          (min)
           60
          120
          180
          240
          300
          360
          420
          480
          540
          600
With
Point
Sources
 28
 34
 42
 51
 61
 68
 76
 79
 80
 77
Without
Point
Sources
 48
 51
 56
 58
 59
 60
 60
 59
 59
 58
Ozone
Increment
 -20
 -17
 -14
 -7
  2
  8
 16
 20
 21
 19
   Thus, for the hypothetical conditions and sources used in these simulations, the NOX
   point source emissions reduce ozone within the plume during the first 300 minutes (72
   km) of the simulation and then increase ozone within the plume in excess of what would
   have been formed in the air parcel if the NOX emissions were not present. If this had
   been an actual air quality impact assessment,  these modeled effects would have to be
   further analyzed to account for uncertainties in the model inputs as well as the validity of
   assuming a coherent air parcel at such far downwindL distances.


   COMPUTER RUN TIMES FOR THE TEST RUNS

   All test simulations were performed on a Multiflow TRACE 28/300 computer system,
   which is  approximately 38 percent slower than the EPA IBM 3900 mainframe computer.
   In addition, the test problems were also exercised on an IBM-compatible 486 personal
   computer using the Lahey Fortran compiler.  The run times for test 1 (ambient-only
   simulation) on the Multiflow computer were approximately 7 cpu seconds for the RPM-
   IV and 12 cpu seconds for the RPM-IVSS. Multiflow run times for the test 2,  3, and 4.
   simulations were 34, 62, and 1500 cpu seconds,  respectively.  Elapsed run times for tests
   1-4 using the RPM-IV on an IBM-compatible 486 PC with a Lahey Fortran compiler
   were 12, 85, 138, and 196 seconds, respectively.
91124r2.14
                                        66
-------
T
60
60.0
100.0 350000.
0.0 600.0
4.0 1.0
1.E-16 1.
118.250 34
1 0
CHEMISTRY INPUT
95 34 0 0
N02
Q
03 NO
Quo?
nwc
0 N02
0 NO
N02 03
03
03
01D
01D H20
03 OH
03 H02
N03
N03 NO
N03 N02
N03 N02
N205 H20
N205
NO NO
NO N02 H20
NO OH
HN02
OH HN02
HN02 HN02
N02 OH
OH HN03
H02 NO
H02 N02
PNA
OH PNA
H02 H02
H02 H02 H20
H202
OH H202
OH CO
FORM OH
FORM
FORM
FORM 0
FORM N03
ALD2 0
AL02 OH
AL02 N03
ALD2
C203 NO
C203 N02
PAN
C203 C203
C203 H02
OH
PAR OH
PAR OH

E-16 10.0
.058 8.0
	 CARBON BOND
1 14
1. NO 1.
1_<—
03
1. N02
1. NO
1. N03
1. N02
1. N03
1 rt
1 • O
1rt
-------
      N02
      OLE
      OLE
      OLE
      OLE
      OLE
      OLE
      OLE
      OLE
      ETH
      ETH
      ETH
      ETH
      OH
      HO
 ROR
 ROR
 ROR
 ROR
 0
 0
 OH
 OH
 03
 03
 N03
 N03
 0
 0
 OH
 03
 TOL
 T02
 T02
 OH   ORES
 CRES N03
 CRO  N02
 OPEN
 OPEN OH
 OPEN OH
 OPEN 03
 OPEN 03
 OH   XYL
 OH   XYL
 OH   MGLY
 HGLY
 0
 0
OH
OH
03
03
N03
X02
 X02
      ISO?
      I SOP
      ISO?
      I SOP
      1SOP
      1SOP
      I SOP
      NO
      X02
X02N  NO
X02   H02
298.0
TRAC  1.0
TEST  1.0
N02
NO
03
CO
ETH
OLE
ALD2
FORM
TOL
XYL
PAR
I SOP
PAN
H02
0
H205
H202
HN02
01D
PNA
C203
ROR
N03
        2.50E-2
        7.50E-2
        0.00
        1.2
        1.85E-2
        1.75E-2
        2.60E-2
        2.10E-2
       1.271E-2
       1.462E-2
        5.64E-1
        0.00
        0.00
        0.0
        0.0
        0.0
        0.0
        0.0
        0.0
        0.0
        0.0
        0.0
        0.0
1.92
O.OS
1.
1.26
0.4
2.
2.
1.0
0.66
1.82
2.
2.
0.6
1.
1.
0.44
0.9
1.
0.4
1.

1.
2.
2.
0.06
1.38
1.4
2.2
1.
1.
1.2
1.0
2.
2.
2.
0.2
1.
1.



X02 2.2
X02N0.04
H02
ALD20.76
FORM0.04
FORM2.
H02
ALD21.48
CO 0.88
X02 2.
N02 -2.
FORKS. 4
OH •
X02 1.56
FORM0.42
H02 0.08
N02 0.9
CRES1.
CRO 0.6
CRO 1.

C2031.
X02 4.
FORM
ALD21.24
CO 0.16
H02 1.0
PAR 0.6
X02 1.
C2031 .
H02 1.6
CO 0.90
X02 2.
ETH 0.8
FORH0.8
PAR 0.12
X02H
N02



ALD21.88
ROR
H02 0.56
X02N0.44
AL02-2.
FORH0.44
H02 -2.
FORH0.18
PAR
H02 2.
FORH0.22
CO 0.12
X02 0.36
H02 0.9
H02
X02 0.6
HN03

H02 1.
CO 4.

C2031.4
OH 1.52
X02 0.4
T02
C203
H02 1.
ALD21.10
ETH 1.8
FORH1.34
HGLY0.4
ALD21.10
CO 0.88





H02 -4.2
X02 0.6
PAR 0.4
PAR 2.
X02 0.2
PAR
X02H2.
CO 1.4
ALD21 .
H02
CRES0.56
OPEN

H02 0.3


CO
H02 2.

FORM0.06
H02 0.4
CRES1 .6


CO
OLE 1.0
PAR
H02 0.26
C2030»4
ETH 0.4
H02 0.2





PAR 6.855E+04 8.000E+03
6.855E+04 8.000E+03
9.545E+04 0.0
2.200E+04 0.0
CO 2.960E+03 3.240E+02
OH 2.960E+03 3.240E+02
X02 2.100E+04-5.040E+02
2.100E+04-5.040E+02
OH 9.000E-03 2.105E+03
9.000E-03 2.105E+03
ALD2 5.675E+00 0.0
5.675E+00 0.0
X02 5.400E+02 7.920E+02
5.400E+02 7.920E+02
H02 1.192E+04-4.110E+02
2.702E-03 2.633E+03
T02 9.150E+03-3.220E+02
1.200E+04 0.0
2.500E+02 0.0
OPEN 6.100E+04 0.0
3.250E+04 0.0
2.000E+04 0.0
8.400E+00 0.0
C203 2.200E+04 0.0
2.200E+04 0.0
X02 7.500E-03 5.000E+02
MGLY 7.500E-03 5.000E+02
MGLY 1.810E+04-1.160E-MJ2
1.810E+04-1.160E+02
2.600E+04 0.0
8.960E+00 0.0
X02 1.350E+04 0.0
1.350E+04 0.0
X02N 7.100E+04 0.0
ALD2 7.100E1-04 0.0
MGLY 9.000E-03 0.0
OH 9.000E-03 0..0
4.700E+02 0.0
1.200E+04 0.0
2.000E-I-03-1.300E+03
1.000E+03 0.0
8.896E+03-1.300E-I-03
91124r2.43
                                    EXHIBIT 4-1.   Continued.
                                              68
-------
   HN03    0.0
   OH      0.0
   T02     0.0
   CRES    0.0
   OPEN    0.0
   HGLY    0.0
   X02     0.0
   X02N    0.0
   CRO     0.0
   H20  20000.
   EMISSIONS INPUT
     0
   METEOROLOGICAL INPUT
    1111
            0.0
         0.0
1
100.0
TRUE
TRUE
1
8
9
14
23
34
38
39
45
76
84
1
0.0
1
0.0
TEST
N02
NO
03
CO
ETH
OLE
ALD2
FORM
TOL
XYL
PAR
I SOP
PAN
4 0 1

SOO.t














303.0


1.00
2.50E-2
7.50E-2
0.00
1.2
1.8SE-2
1.75E-2
2.60E-2
2.10E-2
1.271E-2
1.462E-2
5.64E-1
0.00
0.00
1
                     6.0
                               600.0
 N02   NO
            03
                  FORM
                                  EXHIBIT 4-1.   Concluded.
9I124r2.43
                                            69
-------
 RPH-1VCCB4 version) TEST#1 AMBIENT SIMULATION
113
T
6 0
60.0
100.0 350000.
0.0 600.0
4.0 1.0
1.E-16 1.
118.250 34.
1 0
CHEMISTRY INPUT
94 34 0 0
H02
0
03 NO
0 N02
0 N02
0 NO
N02 03
03
03
01D
010 H20
03 OH
03 H02
N03
N03 NO
N03 N02
N03 N02
N205 H20
H205
NO NO
HO N02 H20
NO OH
HN02
OH HN02
HN02 HN02
N02 OH
OH HN03
H02 NO
H02 N02
PNA
OH PHA
H02 H02
H02 H02 H20
H202
OH H202
OH CO
FORM OH
FORM
FORM
FORM 0
FORH N03
ALD2 0
AL02 OH
ALD2 N03
ALD2
C203 NO
C203 N02
PAN
C203 C203
C203 H02
OH
PAR OH
PAR OH '
ROR

E-16
058


10.0

0.005 0.005


8.0 0800.0 1975 6 21

	 CARBON BOND
1 14
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
1.
1.
0.89
2.
1.
1.
2.
1.
2.
2.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
1.
1.
1.
2.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
0.79
1.
1.74
-0.22
1.92

NO 1.
03
N02
NO
N03
N02
N03
0
01D
0
OH
H02
OH
N02 0.89
N02
NO 1.
N205 •
HN03
N03 1.
N02
HN02
HN02
NO 1.
N02
NO 1.
HN03
N03
OH 1.
PNA
H02 1.
N02
H202
H202
OH
H02
H02
H02 1.
H02 1.
CO
OH 1.
HN031 .
C2031.
C203
C2031 .
FORH2.
FORH1.
PAN
C2031.
FORH2.
FORH0.79
FORH1.
X02 0.26
PAR 1.52
X02 2.2

MECHANISM VERSION IV

0












0 0.11 NO

N02


N02



OH

N02


N02

N02






CO
CO

H02 1. CO
H02 1. CO
OH

HN03
H02 1. CO 1.
N02 1. H02 1.

N02
X02 2. H02
X02 0.79 H02 0.79
X02 1. H02
X02N0.22 H02 0.22
ROR
ALD21.88 K02 -4.2

JANUARY 1988

1.000E+00 0.0
4.323E+06-1.175E+03
2.664E+01 1.370E+03
1.375E+04 0.0
2.309E+03-6.870E+02
2.438E+03-6.020E+02
4.731E-02 2.450E+02
5.300E-02 0.0
1.000E+00 0.0
4.246E+05-3.900E+02
3.260E+00 0.0
1.000E+02 9.400E+02
3.000E+00 5.800E+02
•3.390E+01 0.0
4.416E+04-2.500E+02
5.901E-01 1.230E+03
1.853E+03-2.560E+02
1.900E-06 0.0
2.776E+00 1.090E+04
1.539E-04-5.300E+02
1.600E-11 0.0
9.799E+03-8.060E+02
1.975E-01 0.0
9.770E+03 0.0
1.500E-05 0.0
1.682E+04-7.130E+02
2.179E+02-1.000E+03
1 .227E+04-2.400E+02
2.025E+03-7.490E+02
5.115E+00 1.012E+04
6.833E+03-3.800E+02
4.144E+03-1.150E+03
2.181E-01-5.800E+03
1.890E-01 0.0
2.520E+03 1.870E+02
3.220E+02 0.0
1.500E+04 0.0
1.000E+00 0.0
1.000E+00 0.0
2.370E+02 1.550E+03
9.300E-01 0.0
6.360E+02 9.860E+02
2.400E+04-2.500E+02
3.700E+00 0.0
X02 1.000E+00 0.0
X02 1.831E+04-2.500E+02
1.223E+04-5.500E+03
2.220E-02 1.400E+04
3.700E+03 0.0
OH 9.600E+03 0.0
2.100E+01 1.710E+03
ALD2 6.015E+02 0.0
6.015E+02 0.0
PAR 6.855E+04 3.000E+03
EXHIBIT 4-2. Input stream for test 1  (ambient-only simulation) using 1988 CBM-IV
chemistry and RPM-IV (test 1.2).
91124r2.43
                                       70
-------
       N02
       OLE
       OLE
       OLE
       OLE
       OLE
       OLE
       OLE
       OLE
       ETH
       ETH
       ETH
       ETH
       OH
       NO
  ROR
  H02
  ROR
  0
  0
  OH
  OH
  03
  03
  N03
  N03
  0
  0
  OH
  03
  TOL
  T02
  T02
  OH   CRES
  CRES  N03
  CRO  N02
  OPEN
  OPEN  OH
  OPEN  OH
  OPEN  03
  OPEN  03
  OH    XYL
  OH    XYL
  OH    MGLY
  MGLY
  0
  0
  OH
  OH
  03
 03
  N03
                      0.08  X02N0.04  ROR
                                     9.545E+04 0.0
6.855E+04 8.000E+03ROR
      NO
      X02
 X02
 X02
 X02N NO
 298.0
 TRAC 1
 TEST 1
 N02
 NO
 03
 CO
 ETH
 OLE
 ALD2
 FORM
 TOL
 XYL
 PAR
 I SOP
 PAN
 H02
 0
 N205
 H202
 HN02
 01D
 PNA
 C203
 ROR
 N03
 HN03
OH
       1SOP
       ISO?
       I SOP
       I SOP
       I SOP
       I SOP
       I SOP
         2.50E-2
         7.50E-2
         0.00
         1.2
         1.85E-2
         1.75E-2
         2.60E-2
         2.10E-2
        1.271E-2
        1.462E-2
         5.64E-1
         0.00
         0.00
         0.0
         0.0
         0.0
         0.0
         0.0
         0.0
         0.0
         0.0
         0.0
         0.0
         0.0 .
         0.0
1.26
0.4
2.
2.
1.0
0.66
1.82
2
2
1
1
0
0
1
0


ALD20.76
FORMO. 04
FORM2.
H02
AL021.48
CO 0.88
X02 2.
NOZ -2.

.*44
.9

.4


1.
2.
2,
0.
1.
1.
2.
1.
.
1.
1.
2.
2.
2.
0.
1.
1 .



,06
,38
,4
,2


2
0



2




FORM3
OH
X02 1
FORMO
H02 0
N02 0
CRES1
CRO 0
CRO 1

C2031 ,
X02 4,
FORM
.4
.56
.42
.08
.9

.6





AL021.24
CO 0.16
H02 1.0
PAR 0.6
X02 1.
C2031 .


H02 1.6
CO 0.90
X02 2.
ETH 0.
FORMO.
PAR 0.
X02N
N02



8
8
12




H02 0.56
X02N0.44
AL02-2.
FORM0.44
H02 -2.
FORMO. 18
PAR
H02 2
FORMO
CO 0
X02 0
H02 0
H02
X02 0
HN03

H02 1,
CO 4,

C2031 .
OH 1.
X02 0.
T02
C203
H02 1.
ALD21 .
ETH 1.
FORM1.
MGLYO.
ALD21 .
CO 0.





.
.22
.12
.36
.9

.6





,4
,52
,4
X02 0.6
PAR 0.4
PAR 2.
X02 0.2
PAR
X02N2.

CO 1
ALD21
H02
CRESO
OPEN


.4
.56

H02 0.3


CO
H02 2.




i
•
FORMO. 06
H02 0.4
CRES1.6
2.200E+04 0.0
CO 2.960E+03 3.240E+02
OH 2.960E+03 3.240E+02
X02 2.100E+04-5.040E+02
2.10GE+04-5.040E+02
OH 9.000E-03 2.105E+03
9.000E-03 2.105E+03
ALD2 5.675E+00 0.0

X02
H02
T02

OPEN



C203

X02
MGLY
MGLY
5
5
5
1
2
9
1
2
6
3
2
8
2
2 	
.675E+00
.400E+02
0.0
7.920E+02
.400E+02 7.920E+02
.192E+04-4.110E+02
.702E-03 2.633E+03
.150E+03-3.220E+02
.200E+04 0.0
.500E+02
.100E+04
.250E+04
.OOOE+04
.400E+00
.200E+04
.200F+04
0.0
0.0
0.0
0.0
0.0
0.0
0.0
7.500E-03 5.000E+02
7.500E-03 5.000E+02
1.810E+04-1.160E+02
1.810E+04-1.160E+02
2.600E+04

10
8
34 '
4
10
88




CO
OLE 1.
PAR
H02 0.
C2030.
ETH 0.
H02 0.





0

X02
8.
.960IM-00
1 .350E+04
1.350H+64
26
4
4
2




X02N
ALD2
MGLY
OH




7.
7.
100I-+04
100E+04
9.000E-03
9.
4.
1.
2.
1.
OOOE-03
700E+02
200E+04
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
OOOE+03-1.300E+03
OOOE+03
0.0
91124r2.43
                                    EXHIBIT 4-2.  Continued.
                                              ?i
-------
 T02     0.0
 CRES    0.0
 OPEN    0.0
 HGLY    0.0
 X02     0.0
 X02M    0.0
 CRO     0.0
 H20   20000.
 EMISSIONS  INPUT
   0
 METEOROLOGICAL INPUT
  1111
   2
 4.0       0.0       6.0
    1
       0.0       3
1
100.0'
TROE
TRUE
1
8
9
14
23
34
38
39
45
76
84
1
0.0
1
0.0
TEST
N02
NO
03
CO
ETH
OLE
ALD2
FORK
TOL
XYL
PAR
ISO?
PAN
4 0 1

500.0














303.0


1.00
2.50E-2
7.50E-2
0.00
1.2
1.85E-2
1.75E-2
2.60E-2
2.10E-2
1.271E-2
1.462E-3
5.64E-1
0.00
0.00
1
600.0
N02   NO    03
                 FORM
                                  EXHIBIT 4-2.  Concluded.
9I124r2.43
                                            72
-------
RPH-IV(CB4 version) TEST#2 PLUME
T
10 0
60.0
100.0 350000.
0.0 600.0
ONLY SIMULATION (NO AMBIENT)
4.0 1.0
1.E-16
118.250
2 5
1.00E+04 2
1.E-16 10.0
34.058 8.0
.OOE+04 5.00E+04 1
CHEMISTRY INPUT 	 CARBON BOND
95 34 0 0 1 14
N02
o
03 NO
0 N02
0 N02
0 NO
N02 03
03
03
010
01D H20
03 OH
03 H02
N03
N03 NO
N03 N02
N03 N02
N205 H20
N205
NO NO
NO N02 H20
NO OH
HN02
OH HN02
HN02 HN02
N02 OH
OH HN03
H02 NO
H02 N02
PNA
OH PNA
H02 H02
H02 H02 H20
H202
OH H202
OH. CO
FORM OH
FORM
FORM
FORM 0
FORM N03
ALD2 0
ALD2 OH
ALD2 N03
ALD2
C203 NO
C203 N02
PAN
C203 C203
C203 H02
OH
PAR OH
PAR OH
ROR
1. NO 1.
In?
03
1. N02
1 un
1. NO
1. N03
1un9
• NUc
1. N03
1 n
I • U
1 mr\
I • U1D
1 n
I • O
2. OH
1un9
• Hue
Inu
8.005 0.005
0800.0 1975 6 21
.OOE+05 2.00E+05
MECHANISM VERSION
0







• Un
0.89 N02 0.89 0 0.11 NO
2. N02
1- NO 1. N02
1 . N205
2. HN03
1. N03 1.. N02
2. N02
2. HN02
1 . HN02
1. NO 1. OH
1. N02
1- NO 1. N02
1 . HN03
1. N03
1- OH 1. . N02
1DU A
• PNA
1. H02 1.
1 un9
I • NUc
1 . H202
1 . H202
? riu
* c. UH
1. H02
1Uf\")
• nUt
1. H02 1.
2. H02 1.
1 rn
1 • LU
1 . OH 1 .
1. HN031.
1. C2031.
1. C203
1 . C2031 .
1- FORM2.
1 . FORM1 .
1 PfiU
I » rt\n
1 . C2031 .
' 2. FORM2.
0.79 FORM0.79
1 . FORM1 .
1.74 X02 0.26
-0.22 PAR 1.52
1.92 X02 2.2
N02


CO
CO
H02 1. CO"
H02 1. CO
OH
HN03
H02 1. CO 1.
N02 1. H02 1.
N02
X02 2. H02
X02 0.79 H02 0.79
X02 1. H02
X02N0.22 H02 0.22
ROR
ALD21.88 HQ2 -4.2



IV MARCH 1991
1.000E+00 0.0
4.323E+06-1.175E+03
2.664E+01 1.370E+03
1.375E+04 0.0
2.309E+03-6.870E+02
2.438E+03-6.020E+02
4.731E-02 2.450E+02
5.300E-02 0.0
1.000E+00 0.0
4 . 246E+05 -3 . 900E+02
3. 260(5+00 0.0
1.000I-+02 9.400E+02
3.000I-+00 5.800E+02
3.390E-KJ1 0.0
4.416E+04-2.500E+02
5.901E-01 1.230E+03
1.853E+03-2.560E+02
1.900E-06 0.0
2.776E+00 1.090E+04
1.539E-04-5.300E+02
• 1.600E-11 0.0
9.799E+03-8.060E+02
1.975E-01 0.0
9.770E+03 0.0
1.500E-05 0.0
1.682E+04-7.130E+02
2.179E+02-1.000E+03
1 .227E+04-2.400E+02
2.025E+03-7.490E+02
5.115E+00 1.012E+04
6.833E+03-3.800E+02
4.144E+03-1.150E+03
2.181E-01-5.800E+03
1.890E-01 0.0
2.520E+03 1.870E+02
3.220E+02 0.0
•1.500E+04 0.0
1.000E->00 0.0
S1.000E+00 0.0
2.370E+02 1.550E+03
9'.300E-01 0.0
6.360E+02 9.860E+02
2 . 400E+04 - 2 . 500E+02
3.700E+00 0.0
X02 1.000E+00 0.0
X02 2.815E+04 1.800E+02
1.374E+04-3.800E+02
2.254E-02 1.350E+04
3.700E+03 0.0
OH 9.600E+03 0.0
2.100E+01 1.710E+03
AL02 6.015E+02 0.0
6.015E+02 0.0
PAR 6.855E+04 8.000E+03
EXHIBIT 4-3. Input stream for test 2 (plume-only simulation) using RPM-IV.
91124r2.43
                                    73
-------
      N02
      OLE
      OLE
      OLE
      OLE
      OLE
      OLE
      OLE
      OLE
      ETH
      ETH
      ETH
     'ETH
      OH
      NO
 ROR
 ROR
 ROR
 0
 0
 OH
 OH
 03
 03
 H03
 K03
 0
 0
 OH
 03
 TOi
 T02
 T02
 OH   CRES
 CRES N03
 CRO  N02
 OPEN
 OPEN OH
 OPEN OH
 OPEN 03
 OPEN 03
 OH   XYL
 OH   XYL
 OH   HGLY
 HGLY
 0
 0
 OH
 OH
 03
03
 N03
X02
X02
      ISOP
      I SOP
      ISOP
      ISOP
      ISOP
      ISOP
      ISOP
      NO
      X02
 X02H  NO
 X02   H02
 298.0
 TRAC  1.0
 TEST  1
 N02
 NO
 03
 CO
 ETH
 OLE
 ALD2
 FORM
 TOL
 XYL
 PAR
 ISOP
 PAH
 H02
 0
 N20S
 H202
 HN02
 01D
 PNA
 C203
 ROR
 N03
 KN03
                1
       0
        4.35E-1  1
        7.92EOO  1
        0.00
        1.2
        1.85E-2
        1.75E-2
        2.60E-2
        2.10E-2
       1.271E-2
       1.462E-2
        5.64E-1
        0.00
        0.00
        0.0
        0.0
        0.0
        0.0
        0.0
        0.0
        0.0
        0.0
        0.0
        0.0
        0.0
0.08
1.
1.26
0.4
2.
2.
1.0
0.66
1.82
2.
2.
0.6
1.'
1.
0.44
0.9
1.
0.
1.

4

X02N0.04
H02
ALD20.76
FORMO. 04
FORM2.
H02
ALD21 .48
CO 0.88
X02 2.
N02 -2.
FORM3.4
OH
X02 1.56
FORM0.42
H02 0.08
N02 0.9
CRES1.

CRO 0.6
CRO 1.

ROR
H02 0.56
X02N0.44
ALD2-2.
FORHO. 44
H02 -2.
FORMO. 18
PAR
H02 2.
FORMO. 22
CO 0.12
X02 0.36
H02 0.9
H02
X02 0
HN03
X02 0.6
PAR 0.4
PAR 2.
X02 0.2
PAR
X02N2.
CO 1.4
ALD21 .
H02
CRES0.56
OPEN
CO
OH
X02
OH
ALD2
X02
H02
T02
6.855E+04 8.000E+03
9.545E+04 0.0
2.200E-K14 0.0
2.960E+03 3.240E+02
2.960E+03 3.240E+02
2.100E+04-5.040E+02
2.100E+04-5.040E+02
9.000E-03 2.105E+03
9.000E-03 2.105E+03
5.675E+00 0.0
5.675E+00 0.0
5.400E+02 7.920E+02
5.400E+02 7.920E+02
1.192E+04-4.110E+02
2.702E-03 2.633E+03
9.150E+03-3.220E+02
1.200E+04 0.0
2.500E+02 0.0
.6
H02
0.3
OPEN
6.100E+04 0.0
3.250E+04 0.0
2.000E+04 0.0
1.
2.
2.
0.
1.
1.
2.
1.
1.
1.
1.
2.
2.
2.
0.
1.
1.

.




06
38
4
2


2
0



2





C2031.
X02 4.
FORM



AL021.24
CO 0.16
H02 1.
0
PAR 0.6
X02 1.
C2031 .
H02 1.
CO 0.
X02 2.
ETH 0.
FORMO.
PAR 0.
X02N
N02





6
90

8
8
12





H02 1
CO 4

C2031
OH 1
X02 0
T02
C203
H02 1
ALD21
ETH 1
FORM1
MGLYO
ALD21
CO 0





.
m

.4
.52
.4


.
.10
.8
.34
.4
.10.
.88





CO
H02

8.400E+00 0.0
2.

FORHO.
H02
0.
CRES1 .


CO
OLE
PAR
H02



1.

0.
C2030.
ETH
H02







06
4
6



0

26
4
0.4
0.





2





C203

X02
HGLY
MGLY



X02

X02N
AL02
MGLY
OH





2.200E+04 0.0
2.200E+04 0.
7.500E-03 5.
7.500E-03 5.
1.810E+04-1.
1.810E+04-1.
2.600E+04 0.
8.960E+00 0.
1.350E+04 0.
1.350E+04 0.
7.100E+04 0.
7.100E-MJ4 0.
9.000E-03 0.
9.000E-03 0.
4.700E+02 0.
1.200E+04 0.
2.000E+03-1.
1.000E+03 0.
8.896E+03-1.
0
OOOE+02
OOOE+02
160E+02
160E+02
0
0
0
0
0
0
0
0
0
0
300E-I-03
0
300E+03
9I124r2.43
                                   EXHIBIT 4-3.  Continued.
                                              74
-------
OH 0.0
T02 0.0
CRES 0.0
OPEN 0.0
HGLY 0.0
X02 0.0
X02N 0.0
CRO 0.0
H20 20000.
EMISSIONS INPUT
0
METEOROLOGICAL INPUT
1111
3
4.0 0.0 6.0
6
100. 48.6 5.E4
2.0E5 4.3E4 3.5E5
4
100.0 100.0 2000.0
TRUE
TRUE
1
8
9
14
23
34
38
39
45
76
84
2
0.0 303.0 600.0
4
0.0 200.0 400.0
TEST 1.00
1.00
1.00
1.00
N02 2.50E-2
4.0E-2
2.4E-3
3.4E-3
NO 7.50E-2
4.0E-3
8.2E-5
3.2E-5
03 0.00
1.9E-1
3.5E-1
3.7E-1
CO 1.2
1.2
1.3
1.3
ETH 1.85E-2
1.1E-2
4.3E-3
2.4E-3
OLE 1.75E-2
2.7E-3
5.1E-5
3.5E-6
ALD2 2.60E-2
2.9E-2
1.9E-2
1.7E-2














300.0

1.3E4
7.0E4

400.0














303.0

600.0































                                     .8.0
                                      1.E5
600.0
2.5E4
                                                        1.5E5     3.5E4

                                      10000.0    500.0   350000.0   500.0
91124r2.43
                                 EXHIBIT 4-3.  Continued.
                                          75
-------
FORM



TOL



XYU



PAR



I SOP



PAH



4 0
H02
2.10E-2
3.1E-2
2.3E-2
2.3E-2
1.271E-2
9.0E-3
4.9E-3
3.8E-3
1.462E-2
3.7E-3
3.3E-4
1.2E-4
5.64E-1
5.1E-1
4.2E-1
3.9E-1
0.00
0.0
0.0
0.0
0.00
1.3E-2
2.4E-2
1 .8E-2
1 2
3NO 503
               FORM
                             EXHIBIT 4-3.  Concluded.
9I124r2.43
                                      76
-------
133
T
6 0
60.0
100.0 350000.
0.0 600.0
4.0 1.0
1.E-16 1.E-16 10.0
118.250 34.058 8.0
1.00E+04 2.00E+04 5.00E+04 1
CHEMISTRY INPUT 	 CARBON BONO
97 36. 0 0 1 16
N02 1. NO ,.
n « _«
0 1. 03
03 NO 1. Mo2
Own? 1 no
HUC 1 . NQ
0 N02 1. N03
0 NO 1. N02
N02 03 1. N03
QT . 4 n
u J 1 . O
03 1 . 010
01D 1 n
1 1 ruuuwwcu






0.005
0800.0 1975
.OOE+05 2.
MECHANISM
0




UIU . 1 0 U
01D H20 2. OH
03 OH 1. H02
03 H02 1. OH
N03 0.89 N02 0.89 0 0.11
N03 NO 2. N02
N03 N02 1. NO 1. N02
N03 N02 1. N205
N205 H20 2. HN03
N205 1. N03 1. NQ2
NO NO 2. N02
NO N02 H20 2. HN02
NO OH 1. HN02
HN02 1. NO 1. OH
OH HN02 1. N02
HN02 HN02 1. N0 1. N02
N02 OH 1. HN03
OH HN03 1. NQ3
"02 NO 1. OH 1. N02
H02 N02 1. PNA
pNA 1. H02 1. N02
OH PNA 1. N02
H02 H02 1. H202
H02 H02 H20 1. H202
H202 J 7 nu
"C.WC. £f Qff
OH H202 1. H02
OH CO 1. H02
FORM OH 1. H02 1.
FORM 2. H02 1.
FORM 1 rn
1 wrxi ' 1 . CO
FORM 0 1. OH 1.
FORM N03 1. HN031.
ALD2 0 1. C2Q31.
ALD2 OH 1. C203
ALD2 N03 1. C2031.
ALD2 1. FORM2.
C203 NO 1. FORM1.
C203 N02 1. PAN
PAN 1 . C2031 .
C203 C203 2. FORM2.
C203 H02 0.79 FORM0.79
OH 1. FORM1.
PAR OH 1.74 X02 0.26
PAR OH -0.22 PAR 1.52
ROR 1.92 X02 2.2
CO
CO
H02 1.
H02 1.
OH
HN03
H02 1.
N02 1.
N02
X02 2.
X02 0.79
X02 1.
X02N0.22
ROR
AL021.88
I»T ruune aimuLAUON-SOX ADDED






0.005
6 21
OOE+05
VERSION IV MARCH 1991
1.000E+00 0.0
4.323E+06-1.175E+03
2.664E+01 1.370E+03
1.375E+04 0.0
2.309E+03-6.870E+02
2.438E+03-6.020E+02
4.731E-02 2.450E+02
5.300E-02 0.0
1.000E+00 0.0
4.246E+05-3.900E+02
3.26CIE-HDO 0.0
1.000E+02 9.400E+02
3.000E+00 5.800E+02
NO 3.390E+Q1 0.0
4.416E+04-2.500E+02
5.901E-01' 1.230E+03
1.853E+03-2.560E+02
1.900E-06 0.0
2.776E+00 1.090E+04
1.539E-04-5.300E+02
• 1.600E-11 0.0
9.799E+03-8.060E+02
1.975E-01 0.0
9.770E+03 0.0
1.500E-05 0.0
1.682E+04-7.130E+02
2.179E+02-1.000E+03
1 .227E+04-2.400E+02
2.025E+03-7.490E+02
5.115E+00 1.012E+04
6.833E+03-3.800E+02
4.144E+03-1.150E+03
2.181E-01-5.800E+03
1.890E-01 0.0
2.520E+03 1.870E+02
3.220I-+02 0.0
-1.500E-I-04 0.0
1.000E+00 0.0
1.000E+00 0.0
CO 2.370E+02 1.550E+03
CO 9.300E-01 0.0
6.360E+02 9.860E+02
2.400E+04-2.500E+02
3.700E+00 0.0
CO 1. X02 1.000E+00 0.0
H02 1. X02 2.815E+04 1.800E+02
1.374E+04-3.800E+02
2.254E-02 1.350E+04
"02 3.700E+03 0.0
H02 0.79 OH 9.600E+03 0.0
"02 2.100E+01 1.710E+03
H02 0.22 ALD2 6.015E+02 0.0
6.015E+02 0.0
H02 -4.2 PAR 6.855E+04 8.000E+03
EXHIBIT 4-4  Input stream for test 3 (ambient-only simulation followed by plume-only
simulation) using RPM-IV.                                          3 F umc umJ
91124r2.43
                                   77
-------
ROR
ROR
ROR
0
0
OH
OH
03
03
H03
H03
0
0
OH
03
TOL
T02
T02
OH
CRES
CRO
OPEN
OPEN
OPEN
OPEN
OPEN
OH
OH
OH
HGLY
0
0
OH
OH
03
03
H03
X02
X02
X02H
X02
S02
S02
298. 0
TRAC
TEST
N02
NO
S02
03
CO
ETH
OLE
ALD2
FORM
TOL
XYL
PAR
I SOP
PAN
H02
0
N205
H202
KN02
oto
PHA
C203


N02
OLE
OLE
OLE
OLE
OLE
OLE
OLE
OLE
ETH
ETH
ETH
ETH
OH
NO

CRES
N03
N02

OH
OH
03
03
XYL
XYL
HGLY

ISOP
ISOP
ISOP
ISOP
ISOP
ISOP
ISOP
NO
X02
NO
H02
OH


1.0 1
1.0
2.50E-2
7.50E-2
2.10E-3
•o.oo
1.2
1.8SE-2
1.75E-2
2.60E-2
2.10E-2
1.271E-2
1 .462E-2
5.64E-1
0.00
0.00
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.08
1.

1.26
0.4
2.
2.
1.0
0.66
1.82
2.
2.
0.6
1.
1.
0.44
0.9
1.
0.4
1.

1.
2.
2.
0.06
1.38
1.4
2.2
1.
1.
1.2
1.0
2.
2.
2.
0.2
1.
1.



1.
1.

























X02N0.04
H02

' AL020.76
FORM0.04
FORH2.
H02
ALD21.43
CO 0.88
X02 2.
N02 -2.
FORM3.4
OH
X02 1.56
FORH0.42
H02 0.08
N02 0.9
CRES1 .
CRO 0.6
CRO 1.

C2031.
X02 4.
FORM
AL021.24
CO 0.16
H02 1.0
PAR 0.6
X02 1.
C2031.
H02 1.6
CO 0.90
X02 2.
ETH 0.8
FORH0.8
PAR 0.12
X02N
N02



AERS
AERS

























ROR


H02 0.56
X02N0.44
ALD2-2.

FORM0.44
H02 -2.
FORM0.18
PAR
H02 2.

FORM0.22
CO 0.12
X02 0.36
H02 0.9
H02
X02 0.6
HN03

H02 1.
CO 4.

C2031 .4
OH 1.52
X02 0.4
T02
C203
H02 1.
ALD21.10
ETH 1.8
FORM1 .34
HGLY0.4
ALD21.10
CO 0.88



































X02 0.6
PAR 0.4
PAR 2.

X02 0.2
PAR
X02N2.

CO 1.4

ALD21 .
H02
CRES0.56
OPEN

H02 0.3


CO
H02 2.

FORM0.06
H02 0.4
CRES1.6


CO
OLE 1.0
PAR
H02 0.26
C2030.4
ETH 0.4
H02 0.2



































CO
OH
X02

OH

AL02

X02

H02

T02


OPEN



C203

X02
MGLY
UGLY



X02

X02N
ALD2
HGLY
OH














4

















6.855E+04 8.000E+03
9.545E+04 0.0
2.200E+04 0.0
2.960E+03 3.240E+02
2.960E+03 3.240E+02
2.100E+04-5.040E+02
2.100E+04-5.040E+02
9.000E-03 2.105E+03
9.000E-03 2.105E+03
5.675E+00 0.0
5.675E+00 0.0
5.400E+02 7.920E+02
5.400E+02 7.920E+02
1.192E+04-4.110E+02
2.702E-03 2.633E+03
9.150E+03-3.220E+02
1.200E+04 0.0
2.500E+02 0.0
6.100E+04 0.0
3.250E+04 0.0
2.000E+04 0.0
8.400E+00 0.0
2.200E+04 0.0
2.200E+04 0.0
7.500E-03 5.000E+02
7.500E-03 5.000E+02
1.810E+04-1.160E+02
1.810E+04-1.160E+02
2.600E+04 0.0
8.960E+00 0.0
1.350E+04 0.0
1.350E+04 0.0
7.100E+04 0.0
7.100E+04 0.0
9.000E-03 0.0
9.000E-03 0.0
4.700E+02 0.0
1.200E+04 0.0
2.000E+03-1.300E+03
1.000E-KI3 0.0
8 . 896E+03 - 1 . 300E+03
1.100E+03-1.800E+02
8.300E-05 0.0







»

















                             EXHIBIT 4-4.  Continued.
91124r2.43
                                     78
-------
   ROR
   AERS
   N03
   HN03
   OH
   T02
   CRES
   OPEN
   HGLY
   X02
   X02N
   CRO
   H20
   0.0
   2.85E-4
  .0.0
   .0.0
   0.0
   0.0
   0.0
   0.0
   0.0
   0.0
   0.0
   0.0
 20000.
  EMISSIONS INPUT
     2
     2   4
       200.0       5.0
       200.0   2   2
  NO   5.136E+04
  N02  2.703E+03
       500.0   4   1   1013.25
  NO        90.0       30.
  N02       10.0       46.
  S02      180.0       64.
  AERS      10.0       96.
  METEOROLOGICAL INPUT
   1221
    1
  4.0        0.0
                     4.0     350.0
                           300.0
                                       298.0
     1
         0.0
     3
  100.0
  TRUE
  TRUE
     1
     8
     9
    14
    23
    34
    38
    39
    45
    76
    84
    2
 0.0
    1
 0.0
 TEST
 N02
 NO
 S02
 03
 CO
 ETH
 OLE
 ALD2
 FORM
 TOL
 XYL
 PAR
 I SOP
 PAN
 AERS
 5233
 N02 4NO
    500.0
              2000.0
                        750.0   300000»0    750.0
   303.0
 1.00
 2.50E-2
 7.50E-2
 2.13E-3
 0.00
 1.2
 1.8SE-2
 1.75E-2
 2.60E-2
 2.10E-2
1.271E-2
1.462E-2
 5.64E-1
 0.00
 0.00
 2.85E-4
             600.0
                       303.0
   1003    S02 50AERS50
91124r2.43
                                   EXHIBIT 4-4.  Concluded.
                                             79
-------
 RPM-IV(CB4 version) TEST#4  EXAMPLE IMPACT ASSESSMENT - WITH POINT SOURCE EMIS
T
6 0
60.0
100.0 350000.
0.0 £00.0
4.0 1.0
1.E-16 1.
97.000 40.
3 5

E-16 10.0 0.005 0.005
000 6.0 0800.0 1990 7 15





1.00E+04 2.00E+04 5.00E+04 1.00E+05 2.00E+05
CHEMISTRY INPUT
95 34 0 0
N02
0
03 NO
0 H02
0 N02
0 NO
N02 03
03
03
01D
01 D H20
03 OH
03 H02
N03
H03 NO
N03 N02
H03 N02
N205 H20
H205
NO NO
NO N02 H20
NO OH
HN02
OH HN02
HN02 HN02 '
N02 OH
OH HN03
H02 NO
H02 N02
PHA
OH PNA
H02 H02
H02 H02 H20
H202
OH H202
OH CO
FORM OH
FORM
FORM
FORM 0
FORM N03
ALD2 0
ALD2 OH
ALD2 N03
ALD2
C203 NO
C203 N02
PAH
C203 C203
C203 H02
OH
PAR OH
PAR OH
ROR
	 CARBON BOND MECHANISM VERSION IV
1 14
1. NO 1. 0
1. 03
1. N02
1. NO
1. N03
1. N02
1. N03
1. 0
1. 01D
1. 0
2. OH
1. H02
1. OH
0.89 N02 0.89 0 0.11 NO
2. N02
1. NO 1. N02 .
1. N205
2. HN03
1. N03 1. N02
2. N02
2. HN02
1 . HN02
1. NO 1. OH
1. N02
1. NO 1. N02
1 . HN03
1. N03
1. OH 1. N02
1. PNA
1. H02 1. N02
1. N02
1 . H202,
1. H202
2. OH
1 . • H02
1 . H02
1. H02 1. CO
2.- H02 1. • CO
1. CO
1. OH 1. H02 1. CO
1. HN031. H02 1. CO
1 . C2031 . OH
1 . C203
1 . C2031 . HN03
1. FORH2. H02 1. CO 1.
1. FORM1. N02 1. H02 1.
1. PAN
1. C2031. N02
2. FORM2. X02 2. H02
0.79 FORM0.79 X02 0.79 H02 0.79
1. FORM1. X02 1. H02
1.74 X02 0.26 X02N0.22 H02 0.22
-0.22 PAR 1.52 ROR
1.92 X02 2.2 ALD21.8S H02 -4.2
MARCH 1991

1.000E+00 0.0
4.323E+06-1.175E+03
2.664E+01 1.370E+03
1.375E+04 0.0
2.309E+03-6.870E+02
2.438E+03-6.020E+02
4.731E-02 2.450E+02
5.300E-02 0.0
1.000E+00 0.0
4.246E+05-3.900E+02
3.260E+00 0.0
1.000E+02 9.400E+02
3.000E+00 5.800E+02
3.390E+01 0.0
4.416E+04-2.500E+02
5.901E-01 1.230E+03
1.853E+03-2.560E+02
1.900E-06 0.0
2.776E+00 1.090E+04
1.539E-04-5.300E+02
1.600E-11 0.0
9.799E+03-8.060E+02
1.975E-01 0.0
9.770E+03 0.0
1.500E-05 0.0
1.682E+04-7.130E+02
2.179E+02-1.000E+03
1.227E+04-2.400E+02
2.025E+03-7.490E+02
5.115E+00 1.012E+04
6.833E+03-3.800E+02
4.144E+03-1.150E+03
2.181E-01-5.800E+03
1.890E-01 0.0
2.520E+03 1.870E+02
"3.220E+02 0.0
1.500E+04 0.0
1.000E+00 0.0
1.000E+00 0.0
2.370E+02 1.550E+03
9.300E-01 0.0
6.360E+02 9.860E+02
2 . 400E+04 - 2 . 500E+02
3.700E+00 0.0
X02 1.000E+00 0.0
X02 2.815E+04- 1.800E+02
1.374E-KJ4-3.800E+02
2.254E-02 1.350E+04
3.700E+03 0.0
OH 9.600E+03 0.0
2.100E+01 1.710E+03
ALD2 6.015E+02 0.0
6.015E+02 0.0
PAR 6.855E+04 8.000E+03
EXHIBIT 4-5.  Input stream for test 4 (example air quality impact assessment) using
RPM-IV with point source emissions.
91124r2.43
                                       80
-------
   ROR
   ROR
   ROR
   0
   0
   OH
   OH
   03
   03
   N03
   N03
   0
   0
   OH
   03
   TOL
   T02
   T02
   OH
   CRES
   CRO
   OPEN
   OPEN
   OPEN
  OPEN
  OPEN
  OH
  OH
  OH
  MGLY
  0
  0
  OH
  OH
  03
  03
  N03
  X02
  X02
  X02N
  X02.
  298.0
  TRAC
  TEST
  N02
  NO
  03
  CO
  ETH
  OLE
 ALD2
  FORM
 TOL
 XYL
 PAR
  I SOP
 PAN
 H02
 0
 N205
 H202
 HN02
 01D
 PNA
 C203
 ROR
 N03
 HN03
 N02
 OLE
 OLE
 OLE
 OLE
 OLE
 OLE
 OLE
 OLE
 ETH
 ETH
 ETH
 ETH
 OH
 NO

 CRES
 N03
 N02

 OH
 OH
 03
 03
 XYL
 XYL
 MGLY

 I SOP
 I SOP
 I SOP
 I SOP
 I SOP
 1SOP
 I SOP
NO
X02
NO
H02
 .0
 .0
   2.0E-3
   0.0
   4.00E-2
   0.35
   0.51E-3
   0.30E-3
   0.56E-3
   2.10E-3
   0.18E-3
   0.10E-3
   1.49E-2
   0.10E-3
   0.01E-3
   0.0
   0.0
   0.0
   0.0
   0.01E-3
   0.0
  0.01E-3
  0.0
  0.0
  0.0
  0.01E-3
0.08 X02N0.04
1. H02
1.26 AL020.76
0.4 FORM0.04
2. FORH2.
2lt««**
•
1.0
0.66
1.82
2
1
1
0
0


•
.'44
.9

0.4
,

,
,
o!
1.
1.
2.
1.
.
1.
1.
2.
2.
2.
0.
.
.




nw
AL021.48
CO 0.88
X02 2.
N02 -2.
FORM3.4
X02 1.56
FORM0.42
H02 0.08
N02 0.9
CRES1

CRO 0.6
CRO 1

C203V
•


XU<£ 4.
!06
,38
,4
,2

2
0


2



I-UKM
AL021.24
CO 0.16
H02 1.0
PAR 0.6
X02 1.
C2031 .
H02 1.
CO 0.
X02 2.
ETH 0.
FORMO.
PAR 0.
X02N
N02


6
90
8
8
12



ROR
H02 0.56
X02N0.44
ALD2-2.
FORM0.44
H02 -2.
FORMO. 18
PAR
H02 2
FORMO
CO 0
X02 0
H02 0
H02
X02 0
HN03

H02 1,
CO 4.
C2031.
-OH 1.
X02 0.
T02
C203
H02 1.
ALD21 .
ETH 1.
FORM1 .
MGLYO.
AL021 .
CO 0.



.
.22
.12
.36
.9

.6
X02 0.6
PAR 0.4
PAR 2.
X02 0.2
PAR
X02N2.
CO
1.4
ALD21.
H02
CRES0.56
OPEN

H02

0.3
CO
OH
X02
6.855E+04 S.OOOE-i-03
9.545E+04 0.0
2.200E+04 0.0
2.960E+03 3.240E+02
2.960E+03 3.240E+02
2.100E+04-5.040E+02
2.100E+04-5.040E+02
OH 9.000E-03 2.105E+03
9. OOOE-03 2.105E+03
AL02 5.675E+00 0.0
X02
H02
T02

OPEN
5
5
5
1
2
9
1
2 	
.675E+00 0.0
.40QE+02 7.920E+02
.400E+02 7.920E+02
-192E+04-4.110E+02
.702E-03 2.633E+03
.150E+03-3.220E-I-02
.200E+04 0.0
.500E+0? o.a
6.100E+04 0.0
3.250E+04 0.0
2.000E+04 0.0


,4
,52
,4

10
8
34
4
10
88



CO
H02
8.400E+00 0.0
2.
FORMO. 06
H02 0.4
CRES1.6
CO
OLE
PAR
C203
X02
MGLY
MGLY
2.200E+04 0.0
2.200E+04 0.0
7.500E-03 5.000E+02
7.500E-03 5.000E+02
1:810E+04-1.160E+02
1.810E+04-1.160E+02
2.600E+04 0.0
8.960E+00 O.n
1.0

H02 0.26
C2030.4
ETH
H02



0.4
0.2



X02

X02N
AL02
MGLY
OH



1.350E+04 0.0
1.
7.
7.
9.
9.
4.
1.
2.
350E+04 0.0
100E+04 0.0
100E+04 0.0
OOOE-03 0.0
OOOE-03 0.0
700E+02 0.0
200(:+04 0.0
OOOE-I-03-1.300E+03
1.000E+03 0,0
8.896E+03- 1 .300E+03
91I24r2.43
                                    EXmBn'4-5.  Continued.
                                              81
-------
OH 0.0
T02 0.0
CRES 0.0
OPEN 0.0
HGLY 0.0
X02 0.0
X02N 0.0
CRO 0.0
H20 20000.
EMISSIONS INPUT
7
2 4
100.0 5.0
200.0 2 1
HO 619.
N02 50.
20000.0 10 1
NO 2.3E-3
N02 1.2E-4
ETH 1.9E-4
OtE 1.8E-4
ALD2 2.9E-4
FORM 2.2E-4
TOL 1 .4E-4
XYL 1.6E-4
PAR 6.0E-3
ISOP 0.7
40000.0 10 1
NO 3.1E-3
N02 1.7E-4 '
ETH 2.7E-4
OLE 2.6E-4
ALD2 4.0E-4
FORM 3.1E-4
TOL 1 .8E-5
XYL 2.2E-4
PAR 8.3E-3
ISOP 1.0
90000.0 10 1
NO 6.5E-2
N02 3.5E-3
ETH 5.6E-3
OLE 5.4E-3
ALD2 8.3E-3
FORM 6.4E-3
TOL 3.9E-3
XYL 4.6E-3
PAR 1.7E-1
ISOP 4.1
140000.0 10 1
NO 12.5
N02 0.7
ETH 1.1
OLE 1.0
ALD2 1.6
FORM 1.2
TOL 0.8
XYL 0.9
PAR 33.0
ISOP 4.0
180000.0 10 1
HO 8.0E-1
N02 4.0E-2
ETH 6.5E-2
OLE 6.2E-2
ALD2 9.6E-2
FORM 7.4E-2
TOL 4.6E-2












20
1013.25
30.0
46.0
1013.25
1.
1.
1.
1.
1.
1.
1.
1.
1".
1.
1013.25
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1013.25
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1013.25
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1013.25
1.
1.
1.
1.
1.
1.
1.
                               350.0     303.0
                              303.0
                              300.0
                              300.0
                              300.0
                              300.0
                              300.0
91124r2.43
                                 EXHIBIT 4-5. Continued.
                                          82
-------
XYL 5.0E-2
PAR 2.0
I SOP 4.8
230000.0 10 1
NO 2.8E-2
N02 1.5E-3
ETH 2.4E-3
OLE 2.3E-3
AL02 3.5E-3
FORM 2.7E-3
TOL 1.7E-3
XYL 1.9E-3
PAR 7.4E-2
ISOP 8.8
METEOROLOGICAL INPUT
1221
1
4.0 0.0
1.
1.
1.
1013.25
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.




                                  300.0
     1
         0.0
     3
  100.0
  TRUE
  TRUE
     1
     8
     9
    14
    23
    34
    38
    39
    45
    76
    84
     2
  0.0
     1
  0.0
  TEST
  N02
  NO
  03
  CO
  ETH
  OLE
  ALD2
  FORM
  TOL
 XYL
 PAR
  ISOP
 PAN
  3233
 N02  4NO  1003
   500.0     2000.0     750.0   300000.0    750.0
  303.0
 1.00
 2.00E-3
 0.0
 4.00E-2
 0.35
 0.51E-3
 0.30E-3
 0.56E-3
 2.10E-3
 0.18E-3
 0.10E-3
 1.49E-2
0.10E-3
0.01E-3
            600.0
                      303.0
91124r2.43
                                   EXHIBIT 4-5.  Concluded.
                                             83
-------
 RPH-WCB4 version) TESW EXAMPLE IHPACT ASSESSMENT - WITHOUT POINT SOURCE EMIS
T
6 0
60.0
100.0 350000.
0.0 £00.0
4.0 1.0
1.E-16 1.
97.000 40.
3 5

E-16 10.0 0.005 0.005
000 6.0 0800.0 1990 7 15





1.00E+04 2.00E+04 5.00E+04 1.00E+05 2.00E+05
CHEMISTRY INPUT
95 34 0 0
M02
0
03 NO
0 N02
0 N02
0 NO
N02 03
03
03
01D
01D H20
03 OH
03 H02
N03
N03 NO
N03 N02
N03 N02
N205 H20
N205
NO NO
NO N02 H20
NO OH
HN02
OH HN02
HN02 HN02
N02 OH
OH HN03
H02 NO
H02 N02
PNA
OH PNA
H02 H02
H02 H02 H20
H202
OH H202
OH CO
FORM OH
FORM
FORM
FORM 0
FORM N03
AL02 0
ALD2 OH
AL02 N03
AL02
C203 NO
C203 N02
PAN
C203 C203
C203 H02
OH
PAR OH
PAR OH
ROR
	 CARBON BONO MECHANISM VERSION IV
1 14
1. NO 1. 0
1. 03
1. N02
1. NO
1. N03
1. N02
1. N03
1. 0
1. 01D
1. 0
2. OH
1. H02
1. OH
0.89 N02 0.89 0 0.11 NO
2. N02
1. NO 1. N02
1 . N205
2. HN03
1. N03 1. N02
2. N02
2. HN02
1 . HN02
1. NO 1. OH
1. N02
1. NO 1. N02
1 . HN03
1. ,N03
1. OH 1. N02
1. PNA
1. H02 1. N02
1. N02
1 . H202
1 . H202
2. OH
1. H02
1. H02
1. H02 1. CO
2. H02 1. CO
1. CO
1. OH 1. H02 1. CO
1. HN031. H02 1. CO
1. C2031. OH
1. C203
1 . C2031 . HN03
1. FORM2. H02 1. CO 1.
1. FORM1. N02 1. H02 1.
1. PAN
1. . C2031. N02
2. FORH2. X02 2. H02
0.79 FORH0.79 X02 0.79 H02 0.79-
1. FORH1. X02 1. H02
1.74 X02 0.26 X02N0.22 H02 0.22
-0.22 PAR 1.52 ROR
1.92 X02 2.2 ALD21.88 H02 -4.2
MARCH 1991

1.000E+00 0.0
4.323E+06-1.175E+03
2.664E+01 1.370E+03
1.375E+04 0.0
2.309E+03-6.870E+02
2.438E+03-6.020E+02
4.731E-02 2.450E+02
5.300E-02 0.0
1.000E+00 0.0
4.246E+05-3.900E+02
3.260E+00 0.0
1.000E+02 9.400E+02
3.000E+00 5.800E+02
3.390E+01 0.0
4.416E+04-2.500E+02
5.901E-01 1.230E+03
1.853E+03-2.560E+02
1.900E-06 0.0
2.776E+00 1.090E+04
1.539E-04-5.300E+02
1.600E-11 0.0
9.799E+03-8.060E+02
1.975E-01 0.0
9.770E+03 0.0
1.500E-05 0.0
1.682E+04-7.130E+02
2.179E+02-1.000E+03
1.227E+04-2.400E+02
2.025E+03-7.490E+02
5.115E+00 1.012E+04
6.833E+03-3.800E+02
4.144E+03-1.150E+03
2.181E-01-5.800E+03
1.890E-01 0.0
2.520E+03 1.870E+02
3.220E+02 0.0
.1.500E+04 0.0
1.000E+00 0.0
1.000E+00 0.0
2.370E+02 1.550E+03
9.300E-01 0.0
6.360E+02 9.860E+02
2.400E+04-2.500E+02
3.700E+00 0.0
X02 1.000E+00 0.0
X02 2.815E+04 1.800E+02
1.374E+04-3.800E+02
2.254E-02 1.350E+04
3.700E+03 0.0
OH 9.600E+03 0.0
2.100E+01 1.710E+03
ALD2 6.015E+02 0.0
6.015E+02 0.0
PAR 6.855E+04 8.000E+03
EXHIBIT 4-6.  Input stream for test 4 (example air quality impact assessment) using
RPM-IV without point source emissions.
9II24r2.43
                                      84
-------
   ROR
   ROR
   ROR
   0
   0
   OH
   OH
   03
   03
   N03
   N03
   0
   0
   OH
 .  03
   TOL
   T02
   T02
   OH
   CRES
   CRO
   OPEN
   OPEN
   OPEN
   OPEN
   OPEN
  OH
  OH
  OH
  MGLY
  0
  0
  OH
  OH
  03
  03
  N03
  X02
 X02
 X02N
 X02
 298.0
 TRAC
 TEST
 N02
 NO
 03
 CO
 ETH
 OLE
 ALD2
 FORM
 TOL
 XYL
 PAR
 I SOP
 PAN
 H02
 0
 N205
 H202
 HN02
 010
 PNA
 C203
 ROR
 N03
 HN03
  N02
  OLE
  OLE
  OLE
  OLE
  OLE
  OLE
  OLE
  OLE
  ETH
  ETH
 ETH
 ETH
 OH
 NO

 CRES
 N03
 N02

 OH
 OH
 03
 03
 XYL
 XYL
 MGLY

 I SOP
 I SOP
 I SOP
 I SOP
 I SOP
 I SOP
 I SOP
NO
X02
NO
H02
 ,0
 ,0
   2.0E-3
   0.0
   4.00E-2
   0.35
   0.51E-3
   0.30E-3
   0.56E-3
    .10E-3
  0.18E-3
  0.10E-3
  1.49E-2
  0.10E-3
  0.01E-3
  0.0
  0.0
  0.0
  0.0
  0.01E-3
  0.0
  0.01E-3
  0.0
  0.0
  0.0
  0.01E-3
0.08

1.26
0.4
2.
2^
i!o
0.66
1.82
.
2.
Of,
•o
1.
1.
0.44
0.9
4
o!4
.
1.
.
p
O.*06
1.38
1.4
2.2
1.
.
1.2
1.0
2.
2.
2.
0.2
4
1 .
«
1 .



X02N0.04
H02
AL020.76
FORM0.04
FORM2.
uno
HUc
ALD21 .48
CO 0.88
X02 2.
N02 -2.
FORM3.4
All
On
X02 1.56
FORM0.42
H02 0.08
N02 0.9
CRES1 .
CRO 0.6
CRO 1.
C2031.
X02 4.
FORM
ALD21.24
CO 0.16
H02 1..0
PAR 0.6
X02 1.
C2031.
H02 1.6
CO 0.90
X02 2.
ETH 0.8
FORM0.8
PAR 0.12
X02N
N02



ROR

H02 0.56
X02N0.44
ALD2-2.
FORM0.44
H02 -2.
FORM0.18
PAR
H02 2.
FORM0.22
CO 0.12
X02 0.36
H02 0.9
H02
X02 0.6
HN03
H02 1.
CO 4.
C2031.4
OH 1.52
X02 0.4
T02
C203
H02 1.
ALD21.10
ETH 1.8
FORM1.34
MGLY0.4
ALD21.10
CO 0.88







X02 0.6
PAR 0.4
PAR 2.
X02 0.2
PAR
X02N2.
CO 1.4
ALD21.
H02
CRES0.56
OPEN
H02 0.3

CO
H02 2.
FORM0.06
H02 0.4
CRES1 .6
CO
OLE 1.0
PAR
H02 0.26
C2030.4
ETH 0.4
H02 0.2







CO
OH
X02
6.855E+04 8.000E+03
9.545E+04 0.0
2.200E+04 0.0
2.960E+03 3.240E+02
2.960E+03 3.240E+02
2.100E+04-5.040E+02
2.100E+04-5.040E+02
OH 9.000E-03 2.105E+03
9.000E-03 2.105E+03
ALD2 5.675E+00 0.0
X02
H02
T02
OPEN


C203
X02
MGLY
MGLY

X02
X02N
ALD2
MGLY
OH





5.675E+00 0.0
5.400E+02 7.920E+02
5.400E+02 7.920E+02
1.192E+04-4.110E+02
2.702E-03 2.633E+03
9.150E+03-3.220E+02
1.200E+04 0.0
2.500E+02 0.0
6.100E+04 0.0
3.250E+04 0.0
2.000E+04 0.0
8.400E+00 0.0
2.20GE+04 0.0
2.200E+04 0.0
7.500E-03 5.000E+02
7.500E-03 S.pOOE+02
1.810E+04-1.160E+02
1.810E+04-1.160E+02
2.600E+04 0.0
8.960E+00 0.0
1.350E+04 0.0
1.350E+04 0.0
7.100E+04 0.0
7.100E+04 0.0
9.000E-03 0.0
9.000E-03 0.0
4.700E+02 0.0
1.200E+04 0.0
2.000E+03-1.300E+03
1.000E+03 0.0
8.896E+03-1 .300E+03
91124r2.43
                                    EXHIBIT 4-6.  Continued.
                                              85
-------
OH 0.0
T02 0.0
CRE5 0.0
OPEN 0.0
HOLY 0.0
X02 0.0
X02H 0.0
CRO 0.0
H20 20000.
EMISSIONS INPUT
7
2 4
100.0 5.0
200.0 1 1
CO 1.E-20
20000.0 10 1
NO 2.3E-3
N02 1.2E-4
ETH 1 .9E-4
OLE 1.8E-4
AL02 2.9E-4
FORM 2.2E-4
TOL 1 .4E-4
XYL 1.6E-4
PAR 6.0E-3
ISOP 0.7
40000.0 10 1
NO 3.1E-3
N02 1.7E-4
ETH 2.7E-4
OLE 2.6E-4
AL02 4.0E-4
FORM 3.1E-4
TOL 1 .8E-5
XYL 2.2E-4
PAR 8.3E-3
ISOP 1.0
90000.0 10 1
NO 6.5E-2
N02 3.5E-3
ETH 5.6E-3
OLE 5.4E-3
ALD2 8.3E-3
FORM 6.4E-3
TOL 3.9E-3
XYL 4.6E-3
PAR 1.7E-1
ISOP 4.1
140000.0 10 1
NO 12.5
N02 0.7
ETH 1.1
OLE 1 .0
AL02 1.6
FORM 1.2
TOL 0.8
XYL 0.9
PAR 33.0
ISOP 4.0
180000.0 10 1
NO 8.0E-1
N02 4.0E-2
ETH 6.5E-2
OLE 6.2E-2
ALD2 9.6E-2
FORM 7.4E-2
TOL 4.6E-2
XYL 5.0E-2













1013
28.
1013
m
•
m
•
•
1.
1.
1.
1.
1.
1013
1.
1.
1.
1. -
1.
1.
1.
1.
1.
1.
1013
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1013
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1013
1.
1.
1.
1.
1.
1.
1.
1.












20
.25

.25










.25










.25










.25










.25








                               350.0    303.0
                              303.0

                              300.0
                              300.0
                              300.0
                              300.0
                              300.0
                                 EXHIBIT 4-6.  Continued.
9II24r2.43
                                          86
-------
PAR 2.0
ISOP 4.8
230000.0 10
NO 2.8E-2
N02 1.5E-3
ETH 2.4E-3
OLE 2.3E-3
ALD2 3.5E-3
FORM 2.7E-3
TOL 1.7E-3
XYL 1.9E-3
PAR 7.4E-2
ISOP 8.8
METEOROLOGICAL
1221
1
4.0 0.0
1
0.0
3
100.0 500.0
TRUE
TRUE
1
8
9
14
23
34
38
39
45
76
84
2
0.0 303.0
1
0.0
TEST 1.00
N02 2.00E-3
NO 0.0
03 4.00E-2
CO 0.35
ETH 0.51E-3
OLE 0.30E-3
ALD2 0.56E-3
FORM 2.10E-3
TOL 0.18E-3
XYL 0.10E-3
PAR 1.49E-2
ISOP 0.10E-3
PAN 0.01E-3
3233
N02 4NO 1003
1.
1.
1 1013.25
1.
1.
1.
1.
1.
1.
1.
1.
. 1.
1.
INPUT




3

2000.0




,









600.0


















                              300.0
                            750.0   300000.0    750.0
                           303.0
                               EXHIBIT 4-6.  Concluded.
91124r2.43
                                        87
-------
-------
                         5   NOTES FOR COMPUTER USERS
    Because of the complexity of the RPM and the limited number of applications of the
    current versions, not all possible user errors in executing the program have been
    identified. This section provides helpful tips on program and data setup.
    5.1
INPUT OF INITIAL AND BACKGROUND CONCENTRATIONS
    The input of initial and background concentrations may be a source of confusion.  The
    program reads species concentrations from two parts of the input deck:  initial
    concentrations are read in subroutine CHEMIN, and background concentrations are read
    in METIN.  The selection of initial concentrations for the model simulation depends on
    which type of simulation is selected.  In most applications the initial .concentrations read*
    by CHEMIN will equal the ambient concentrations read by METIN at time zero
    However, as described next, the initial concentrations can be used to initialize a plume
    with a source's emissions.

    For a plume-only  simulation (MODE2 = 2) the user has  two options for initializing the
    plume concentrations.  In the first option the user must manually divide emissions input
    (mass/time) by initial plume dimensions and wind speed (as indicated in the METIN
    section of the input file), and  add these concentrations,  where appropriate, to the ambient
    concentrations; the resultant values are entered as initial concentrations.  This method
    assumes that the plume contains all emissions from the primary point source at the
    beginning of the simulation.  Emissions from secondary downwind point sources may be
    automatically added to the plume by inserting emission rate data (read from SORCES) at
    the appropriate downwind distance.

    With the second option, all initial concentrations (except TRAC) are set to the values
    given in the background (ambient)  concentration section at time zero.  Then the primary
    emissions may be injected into the plume  a short distance  downwind by placing the
    emissions data in the SORCES section of  the input file.  It is recommended (though not
    required) that plume dimensions at the primary  injection distance (i.e., the first injected
    source) be set equal, to the initial dimensions to prevent dispersion of a plume containing
    only background concentrations. The tracer species (TRAC) need not be injected  as
    long as it is initially set to 1.0 and  no dispersion is allowed upwind of the primal
    injection distance.                                                 v     3
91124r2.07
                                       89
-------
    For a combined background and plume simulation (MODE2 = 3), the program simulates
    background concentrations first, and then uses these concentrations as input to a plume-
    only simulation. Initial concentrations (as read in CHEMIN) are used to initialize the
    simulation unless NFLAG = 1. If NFLAG = 1, the program uses background (ambient)
    concentrations (from MBTIN) at time zero to initialize the ambient simulation.  Either
    option for initializing plume phase is permitted, but if the primary emissions injection
    option is chosen, initial concentration values (CHEMIN) should be set to the initial
    background concentration values (METEN) and the parameter NFLAG becomes
    superfluous.  If NFLAG = 1, the program merely subtracts background concentrations
    from the initial values before initialising the plume cell concentrations.


    5.2  INITIAL PLUME DIMENSIONS

    Initial plume dimensions should be no smaller than those dimensions found at a
    downwind distance of 100 m. Dimensions may be determined from ery and oz curves for
    Pasquill stability types.  If automatic dispersion calculation is chosen CHDSOPT and
    VDSOPT = 2), the initial downwind distance should not be set any smaller than 100 m.
    Initial concentrations that are too large can cause excessive execution time during the
    early portion of the simulation.


    5.3  VERTICAL PLUME DEPTH

    When VDSOPT =  1, the vertical plume depth input may be defined as commensurate
    with the vertical dispersion until the mixing layer  is filled; however, the assumption of
    vertical concentration uniformity must be borne in mind hi the interpretation of results.
    The vertical plume depth may also be based on changes in mixing depths.  When
    VDSOPT = 2, plume depths are automatically calculated, though user-specified mixing
    depth input is still required.  Only when VDSOPT = 2 and NSORCS = 0 can the model
    calculate plume "touchdown" distance, inversion bas'e "contact" distance, and the
    downwind distance at which the vertically uniform concentration assumption can be
    considered valid.
   5.4  SPECIFICATION OF WIND SPEEDS

   If wind speed or temperature is assumed to be constant throughout the simulation, input
   of one set of variables is sufficient.  However, up to 10 sets of values are permitted. The
   model interpolates linearly between the input wind speeds.
91124i2.07
                                       90
-------
     5.5  SPECIFICATION OF PLUME WIDTHS

     To simulate background conditions only (MODE2 = 1), the width of the parcel must be
     held constant.   Therefore only one set of width variables is needed, i.e., XRAD(l),
     WTOTH(l). If more than one set of variables are input, or the dispersion option
     HDSOPT = 2 has been selected, the program will utilize only the first width input (or
     calculated in the case of HDSOPT = 2). For plume simulations, up to 10 sets of width
     values can be used.
    5.6  PHOTOLYSIS RATES AND THE CARBON-BOND MECHANISM

    A major improvement of the RPM-IV over RPM-H is the option allowing automatic
    calculations of photolysis reaction rates, provided the CBM-IV chemistry is used  The
    user need only specify the reaction number corresponding to the photolysis reactions, as
    shown in the sample simulation input (see Chapter 4).  Specifying LPHOT = T and
    LDFLT = T will invoke this option.                                      '

    To supply photolysis rates as a function of zenith angle (LPHOT = J, LDFLT  =  F)
    additional input data are required.  The user must specify the number of photolytic
    reactions and corresponding reaction numbers for bjDth (1) reactions with independent
    photolysis rates and (2) reactions with proportional rates.

    Finally, the user may specify time-dependent photolysis rates in the input file (i e
    independently of zenith angle).  This option also requires identifying the photolytic'
    reactions discussed previously.  We caution against specifying photolysis rate constants
    equal to zero, since this causes excessive execution time.  A value of 10 X 10~4 for
    N02 photolysis is very small, yet large enough for efficient execution times.


    5.7 SPECIFICATION OF BACKGROUND CONCENTRATIONS

    To perform a plume-only simulation with user-supplied background concentrations
    MODE2 is  set to 2 and time-varying ambient concentrations are specified in the data file
    as described in Chapter 3.  Note, however, the consequence of linear interpolation in the
    summary plots of the MODE2  = 2 simulation (see Appendix C).  When plume
    concentrations are close to the background concentration values, linear interpolation
    between the background concentrations may result in unrealistic fluctuation of the plume-
    minus-ambient concentration.
        In ambient-only simulations (MODE2 == 1) the plume is considered a parcel.
91124r2.07
                                       91
-------
    5.8  STABILITY OF THE NUMERICAL INTEGRATION SCHEME

    The stability of the numerical interpolation scheme is sensitive to gradients in some of the
    terms of the ordinary differential equations system.  An instability arising from very steep
    gradients may cause the integration scheme to  "lock" into a very small step size, resulting
    in prohibitively long execution times. If the model gets locked into a prohibitively small
    time step, it will exit the simulation.  However, it is better not to specify a long
    execution time- limit until the scheme is known to be stable with the user's input.  Careful
    scrutiny of the input data is advised.  One or two typographical errors could result in
    steep gradients and subsequent instability. Internal print statements within subroutine
    CHECK can be activated to monitor the evaluation of the integration step size and
    elapsed simulation time.  The inexperienced user should examine this output while
    reproducing one of the sample runs to become familiar with the range of time steps used
    by the integration scheme.
9U24r2.07
                                       92
-------
                                       References
     EPA.  1987. Industrial Source Complex (ISC) Dispersion Model User's Guide-Second
                            V°lUmeL  U'S- ^™^ental Protection Agency (EPA-
     Gear, C W.  1971. The automated integration of ordinary differential equations
           Communication Assoc. Computing Machinery, 14(3): 176-179.

     Gery, M. W., G. Z Whitten, and J. P. Killus.  1988. Development and Testing of the
           Carbon-Bond IV Mechanism for Urban and Regional Modeling. U.S. Environ-
           mental Protection Agency (EPA-600/3-88-012). .                   ™viron

     Gipson  G.  L  1984   User's Manual for OZIPM-2: Ozone Isopleth Plotting mth
                                     2'  U'S' ^vironmental Protection Agency (EPA-
    Gutfreund, P. D  and R. E. Morris.  1984a.  "Air Quality Impact Assessment of
          Emissions from the Proposed Expansion of the Carpinteria Gas Plant of Chevron
          84/1227       Systems Applications, Inc., San Rafael, California (SYSAPP-


    Gutfreund, P. D.  and R  E^Morris.  1984b.  "Air Quality Impact Assessment of
          Emissions  from the Proposed Platform Gail of Chevron U.S.A., Inc."  Systems
          Applications, Inc., San Rafael,  California (SYSAPP-84/178).

    Gutfreund  P. D., and R.  E. Morris. 1985. "Development of RPM-Urban, and
          Performance Evaluation in the Southern California OCS and Urban Environment."
          AIT Pollution Control Association annual meeting (paper 85-23.2).

    Gutfreund, P. D., R^ E. Morris,  L. A. Mahoney, and P. Saxena.  1984.  "Prevention of
          S^antDetenoration Permit Application for the Proposed New Printing Plant
          of R. R. Donnelley and Sons Company to be Located near Reno, Nevada "
          Systems Applications, Inc., San Rafael, California (SYSAPP-84/163).   '
91124r2.08
                                       93
-------
    Gutfreund, P. D., R. E. Morris, and M. A. Yocke.  1984. "The Reactive Plume Model
          —Further Development and Performance Evaluations in Coastal-Urban and Desert--
          Rural Settings."  Systems Applications, Inc., San Rafael, California.

    Gutfreund, P. D., M. A. Yocke, R. E. Morris, J. L. Haney, D. A. Stewart, J. Ames,
          M. A. Samuelson, J. L. Baptista, and M.-K. Liu.  1983. "Assessment of the
          Impact'of Four Corners Nitrogen Oxide Emissions on Ambient Nitrogen Dioxide
          Levels."  Systems Applications, Inc., San Rafael, California (SYSAPP-83/234).

    Hogo, H., and M. W. Gery.  1988.  Guidelines for Using OZIPM-4 with CBM-IV or
          Optional Mechanisms, Volume 1: Description of the Ozone Isopleth Plotting
          Package, Version 4.  U.S. Environmental Protection Agency (EPA-600/8-88-
          073A).

    Hogo, H., and G. Z. Whitten.  1985. Guidelines for Using OZIPM-3 with CBM-X or
          Optional Mechanisms, Volume 1: Description of the Ozone Isopleth Plotting
          Package, Version 3.  U.S. Environmental Protection Agency (EPA-600/3-86-
       •   004A).

    Jeffries, H. E., and K. G. Sexton.  1987.  Technical Discussion Related to the Choice of
          Photolytic Rates for Carbon Bond Mechanisms in OZIPM4/EKMA.  U.S.
          Environmental Protection Agency (EPA-450/4-87-003).

    Killus, J. P., and G. Z. Whitten.  1984. Technical Discussions Relative to the Use of
          Carbon-Bond Mechanism in OZIPM/EKMA.  U.S. Environmental Protection
          Agency (EPA-450/4-84-009).

    Liu, M. K., D. Durran, P. Mundkur, M. Yocke, and J. Ames.  1976.  "The Chemistry,
          Dispersion, and Transport of Air Pollutants Emitted from Fossil Fuel Power
          Plants in California:  Data Analysis  and Emission Impact Model."  Systems
          Applications, Inc., San Rafael,  California (SYSAPP-76/018).

    Liu, M. K., M. A. Yocke, and P. V. Mundkur.  1975.  "Numerical Simulation of Reac-
          tive Plumes."  68th Meeting of American Institute of Chemical Engineers,  Los
          Angeles, California; also Air Series, American Institute of Chemical Engineers
          1976.

    Morris, R. E., D. A. Stewart, and M. A. Yocke.   1988.  "User's Guide to the Reactive
          Plume Model (RPM-n)." Systems Applications International, San Rafael
          California (SYSAPP-88/130).
91124r2.08
                                       94
-------
Ogren, J. A., et al. 1976.  "Determination of the Feasibility of Ozone Formation
                                                                              n
     Roth, P. M., M.-K. Liu, D. A. Stewart, R. E. Morris, and T. C. Myers.  1981
            Evaluation of the Impacts of NOX Emissions from the Proposed Montezuma
           Generating Stations on Oxidant Concentrations in an Arc Between Lodi and
           Stockton."  Systems Applications, Inc., San Rafael, California (SYSAPP-81/065).

     ScheffeJR. D.  1988. VOC/NOX Point Source Screening Tables.  U.S. Environmental
           Protection Agency, Office of Air Quality Planning and Standards  (A-88-04).

     Stewart, D A., and M. K. Liu. 1981. Development and application of a reactive plume
           model.  Atmos. Environ., 15(10/1 1):2377-2393.

     Stewart D. AM. A. Yocke, and M. K. Liu.  1980.  "User's Guide to the Reactive

                               "         AppUcations' **" San Rafae1'  Califoniia
    Tesche, T. W.  1985.  "Formulation and Application of the Reactive Plume Model "
           Systems Applications, Inc., San Rafael, California (SYSAPP-85/151).

    Tesche  T. W., and R. E. Morris.  1983.  "Estimated Onshore Oxidant Impacts from
           Reentry at the Chevron, U.S.A. Caliente Well in the Santa Barbara Channel "
           Systems Applications, Inc., San Rafael, California (SYSAPP-83/101).

    Tesche  T. W., G. Z. Whitten, M. A. Yocke, and M.-K. Liu.  1976. "Theoretical
           Numerical, and Physical Techniques for Characterizing Power Plant Plumes "
          Electric Power Research Institute Topical Report (EPRI EC-44).
                   'I' *?"£• ?d H' H°g°-  198°- ^e^S of Simulated Photochemical
          Smog with Kinetic Mechanisms, Volume I: Final Report: U.S. Environmental
          Protection Agency (EPA-600/3-80-028a).

    Yocke, M. A., D. A. Stewart, J. Johnson, and R. J. Frost  1979  "Evaluation of Plume
          Modeling Techniques for Estimating Short-Term NO2 Concentration Impacts from
                 UICeS'     ^ AppUcations' **" San K^61' California (SYSAPP-
   Yocke, M A., D. A. Stewart, J. Johnson, and R. J. Frost.  1980.  "Volume H
         Evaluation of Short-Term NO2 Plume Models for Point Sources: Data Volume
         Systems Applications, Inc., San Rafael, California (SYSAPP-80/159)
91124r2.08
                                       95
-------

-------
                            Appendix A

                 THE RPM-IV FRONT END SOFTWARE
                           (SETUPRPM)
91124r2.09
-------
-------
  Inputs for an RPM-IV application can be created with either the interactive front end
  program (SETUPRPM) or the ROM-RPM and UAM-RPM interface programs  This
  appendix  covers the front end program.  Appendix B covers the ROM-RPM and UAM-
  RPM interface programs.

  The inputs for RPM-IV are created with the front end program, SETUPRPM  in the
  following order: (1) simulation-control parameters, (2) chemistry, (3) emission source
  parameters, (4) meteorological data such as wind speeds and dispersion specifications  (5)
  photolysis rates as well as ambient temperatures  and concentrations, and (6) parameters
  that control the output of the model.  The subroutines within the front end program that
  correspond to the above six steps are CNTUN, CHEMIN, SORCIN, METIN1,  METIN2
  and RESULTING

  SETUPRPM allows users to create the RPM input file by responding to prompts from the
  program.  It reads the user's keyboard inputs'and generates two output files:

                    The input file for RPM-IV  runs (unit 8 in the front end program).
                    The recommended name is  RPM.IN.

                    A "carbon-copy" of the user's inputs that can be  used to restart the
                    input process in the front end program (unit 9 in  the front end
                    program).  The recommended name is RPMCC.IN.
Filel
File 2
          St°P ^ "P"' process at ™y 13oint and resume kter by renaming the file
 RPMCC.IN as RPMPV.IN and restarting the front end program7 At the beginning of the
 input entry process the program will ask the user whether the input process is a restart
 vSZSFH?, 1S.'YES'' the P10^ wffl read in all input variables from the file
 KPMPV.IN (unit 10 in the program) up to the point where inputs were specified   The
 restart feature has been tested for several but not all conditions.

 Plume width and depth are important parameters when running RPM-IV since these
 variables define the dispersion processes of the plume.  RPM-IV will automatically
 calculate these variables if the variables HDSOPT and VDSOPT are set to  1  The front
 end program will also calculate these variables if the user selects that option and specifies
 (1) a stability profile that changes with time and/or (2) a mixing depth profile that
 changes with downwind distances.  The user then decides whether the plume width and
 depth information is appropriate for the current type of application. If not, the front end
 program offers the option of changing the stability values and thus recalculating plume


In many parts of the front end program  the input values are checked to ensure data
quality.  If the entered  values exceed the limits, the user is shown the values and asked to
91124r2.09
                                    A-l
-------
re-enter. However, due to the complexity of emissions data and the differences in their
order of magnitude, it is impossible to set any limits for checking the emissions data.
Users should exercise their best judgement and take special care in entering the values to
ensure the quality of outputs.
INPUT VALUES

If recommended or default values exist, they are displayed in the front end program.  If a
prompt does not indicate a recommended value, it is necessary for the user to enter an
appropriate answer.  Failing to do so may cause the entry process to abort or cause
RPM-IV to generate erroneous results.  (If the program aborts, the entry process can be
continued through the restart option.)

The 1991 Carbon-Bond Mechanism IV (CBM-IV) chemistry (see Section 2) is currently
implemented in the front end program.  Reactions can be added or eliminated either by
editing the RPM.IN file after it has been created or by modifying the 'BLOCK DATA'
section (subroutine BLKDTA)  of the SETUPRPM program. This section includes
reaction rates,  activation energies, reactant and product species names, and reaction
sequence numbers.

The initial concentrations of the 34 species in CBM-IV are defined hi the subroutine
BLKDTA (variable YY) with units of parts per million (ppm). If necessary, these values
can be changed either before running the front end program (by changing the values in
subroutine BLKDTA) or by modifying the RPM input file created by the front end
program.

Variable ISTDIN in subroutine BLKDTA is the Fortran unit number of the standard input
file of the user's computing system.  As SETUPRPM is designed to be used  on different
computer systems, users must  select the appropriate value for ISTDIN for their
computing system.   That number should be confirmed before  running the front end
program. (Most computers adopt 5 and 6 for the standard input and output file
respectively.)
INPUT STEPS

The procedures for creating an input file for RPM-IV through the front end program are
outlined in Figure A-l.  Exhibit A-l displays a CLIST job control file for running
SETUPRPM on an IBM mainframe computer and Exhibit A-2a shows an example
execution of SETUPRPM.
91124r2.09
                                     A-2

-------
                                                                          SETUPRPM
                                                                  /
                                                                  X     Asks user for
                                                                 /file name (unit 8) - RPM JN
                                                                 \file name (unit 9) - RPMCC JN \
                                                                  N.  (refer to Exhibit A-l)
                           y'  To restart, FRNTEND asks
                          /  user for file name (units 8,9,10)
                          I     Enter the previous file name
                          \  (unit 9) for unit 10 (RPM-IVJN)
                           Xjrefer to Exhibit A-l. A-2)
Prompts user for inputs
 (refer to Exhibit A-l)
                                                                            At the
                                                                         end of each
                                                                     section, user continue
                                                                      or exit the program
                                                                           (refer to
                                                                         Exhibit A-l
                                                                           If the
                                                                       program finishes
                                                                         successfully
                                                                           Is the
                                                                         output file
                                                                     (unit8)forRPM-IV
                                                                       or RPM-IVSS
                                                                          (refer to
                                                                        Exhibit A-l
                    Run RPM-IVSS
                                              Write out two files
                                          unit 8 - input file to RPM-IV
                                         unit 9 - carbon copy for restart
                                           (refer to Exhibit A-3, A-4;
                   Write out two files
               unit 8 - input file to RPM-IV
              unit 9 - carbon copy for restart
                (refer to Exhibit A-5, A-6)
                                                Run RPM-IV
                                                                                          Run RPM-IVSS
                                                FIGURE A-l. Sequence of operations in SETUPRPM.
Je\91124.001
                                                         A-3
-------
 An effort has been made to ensure that the entry process is as self-explanatory as
 possible.  Although the process can be restarted at any point, it is nevertheless important
 that special care be taken in entering the values.

       (1)   The program assumes constant ambient concentrations around the plume
             (i.e., at the left, right, top, and bottom edges of the plume) for each
             individual  "flowing species11 (i.e., ambient species entrained by the plume).
             Those four values do not need to be the same when running the model.
             Modifications can be made in the RPM.IN file after it has been created.

       (2)   RPM-IV can calculate time-variant photolysis rates. Users may specify
             time-dependent zenith angles or use the defaults when running the front
             end program.  To use defaults, answer 'TRUE' to the first two questions
             in the photolysis-reaction entry section (step 5).
 TEST RUN

 Different approaches are needed to execute the SETUPRPM program on different
 computer operating systems.  (1) For the IBM PC, type "FRNTEND" at the DOS prompt
 and start answering all the questions.  (2) For the National Computer Center's IBM main
 frame, a "CLIST" file is needed (Exhibit A-l).  (3) For all other operating systems,  such
 as VMS or UNIX, you must create the necessary  command file or runstream to run the
 program.

 Exhibit A-2a shows how the front end program can be terminated before completing all
 the necessary inputs for a test run of RPM-IV.  Exhibit A-2b demonstrates the restart
 option of the program. After copying the file RPMCC.IN to RPMPV.IN, the user can
 restart the front end program using the carbon copy file to start up where the previous
 session left off.  The inputs from a previous execution of the program were stored in the
 file RPMPV.IN (Exhibit A-3). After the program finishes reading RPMPV.IN, users can
 continue to input the data interactively.  This input file used for the restart option of the
 front end program is shown in Exhibit A-3.

 The final results  are shown in Exhibit A-4 through A-7. The1 results  in Exhibits A-4 and
 A-5 are tailored for RPM-IV, whereas the results  in Exhibits  A-6 and A-7 are for RPM-
 rvss.
9U24r2.09
                                     A-4
-------
  PROC 0
  /*
  WRITE
  WRITE
  READ &NEW
  WRITE
  WRITE
                       WELCOME TO  RPM FRNTEND INTERACTIVE SOFTWARE!

                               IS  THIS A NEW START?
                           PLEASE  TSTPE "  N " FOR NEW START
                                        "P" POP B
                                                R *
                           ENTER THE NAME OF  FILE' 1  (UNIT 8)

                               WILL BE m INPDT  FILE  FOR RP
                               ATH NAME, NOT  ENCLOSED  IN SINGLE QUOTES)
                           (THE RECOMMENDED NAME  IS  RPM. IN)

  READ &FILE1
  WRITE
  WRITE
                           ENTER THE NAME OF  FILE  2  (UNIT 9)
                               ™ C^O^-COPY FILE  FOR FUTURE  RESTART)
                             PATH NAME, NOT ENCLOSED IN SINGLE  QUOTES)
                           (THE RECOMMENDED NAME IS  RPMCC.IN)

  READ &FILE2
  /*             ..        •
  CONTROL NOMSG NOLIST NOFLUSH END(DEND)
  FREE FI(FTOSFOOl)
  FREE FKFT09FOP1)
  FREE FI (FTlOFOOl)
  /*
 DSCHECK &FILE1
  IF &LASTCC=0 THEN DO
    ALLOC FILE (FT08F001) DATASET ( ' &FILE1 ' )  SHR REU

    ATTRIB XX BLKSIZE(6600) LRECL(132) DSORG(PS)  RECFM(F B)
      MC "^(Tr°8F001) DATASET ('&FILE1') USING (XX) NEW +
          SPACE (5, 5)  TRACKS UNIT (DISK) CATALOG

 DSCHECK &FILE2
 IF &LASTCC=0 THEN DO
    ALLOC FILE (FTO 9 FOOD DATASET (' &FILE2 ') SHR REU

    ALLOC FILE (FT09F001) DATASET (' &FILE2 ') USING (XX) NEW +

 FREE ATTRgf?(XX,'5) ™B °NIT(DISK) ^ALOG
 /*
 FREE FKFT08F001)
 FREE FI (FT09F001)
 /*
 IF &NEW EQ N THEN GOTO RUNN
 /*
 /* TO ALLOCATE AN OLD DATA SET FOR USE

    WRITE
    WRITE

                                   THE NAME OF THE OLD FILE:
   READ &FILE3
   ALLOC FI (FTlOFOOl)  DAC&FILE3')  SHR
EXHIBIT A-l. Example of the CIIST frie used on the EPA's NCC IBM mainframe.

91124r2.30                            A~5
-------
/* TO ALLOCATE  INPUT(5)/OUTPUT(6)  TO THE TERMINAL.
/* THESE WOULD  BE THE UNIT NUMBERS THAT YOU ARE WRITTING TO.
/*
RUNN: +-
ALLOC FKFT05F001) DA(*)  REU
ALLOC FKFT06F001) DA(*)  REU
y*
/* ALLOCATE ALL OTHER DATASETS THAT YOU READING FROM OR WRITTING TO
/*
/* TO ALLOCATE  NEW DATA SETS TO WRITE TO
/*
ALLOC FKFT08F001) DA (' &FILE1')  SHR  '
ALLOC FKFT09F001) DAC&FILE2')  SHR
/*
/*:	-	:
CONTROL MSG
/*
/* CALLING THE  EXECUTABLE
/*
CALL 'ZWARTMA.RPM.LOAD(TEST)'
/*
/* FREE THE ALLOCATED DATA SETS
/*
FREE F(FT08F001)
FREE F(FT09F001)
IF &NEW EQ N  THEN GOTO RUNNN
FREE F(FTIOFOOI)
RUNNN: +
WRITE
WRITE
WRITE
WRITE                   THANK YOU  FOR USING RPM FRNTEND
WRITE                          SEE  YOU LATER
WRITE
WRITE
/*
                          EXHIBIT A-1. Concluded.
                                  A-6
91124r2.30
-------
  EX 'MMAS.RPM.CLIST(FRNTEND)
 N
                .WELCOME TO RPM PROTEND INTERACTIVE SOFTWARE!

                         IS THIS A NEW START?
                     PLEASE TYPE " N. " FOR NEW START
                                 " R " FOR RE-START
                    ENTER THE  NAME! OF FILE 1 (UNIT 8)
                  ( THIS WILL BE  THE INPUT FILE FOR RPM RUNS)
              (THE FULL PATH NAME,  NOT ENCLOSED IN SINGLE QUOTES)
                     (THE  RECOMMENDED NAME IS RPM.IN)
 ZWARTMA.RPM.IN
                    ENTER THE NAME OF FILE 2  (UNIT 9)
           (THIS WILL BE THE CORBON-COPY FILE  FOR  FUTURE  RESTART)
              (THE FULL PATH NAME, NOT ENCLOSED  IN SINGLE QUOTES)
                    (THE RECOMMENDED NAME IS  RPMCC.IN)

 ZWARTMA.RPMCC.IN



  ********** WELCOME TO RPM FRONT END !! *************

  THIS IS  A USER-INTERFACE PROGRAM TO CREATE AN INPUT
  SPECIFICATIONS FILE FOR RPM-IV    .


  FOR WRITTEN DOCUMENTATION OF SUPPORT,  PLEASE CONTACT:

    SHAO-HANG CHU (ENVIRONMENTAL SCIENTIST)

    U.S. ENVIRONMENTAL PROTECTION AGENCY

    OFFICE OF AIR QUALITY PLANNING AND STANDARDS,  MD 14

    RESEARCH TRIANGLE  PARK

    (919)  541-5382
    (919)  541-2357 FAX


  PRESS "  ENTER  »  TO CONTINUE!
 ***
     PLEASE READ THE  FOLLOWING  NOTES  BEFORE  YOU CONTINUE
  (1) PRESS ENTER AFTER YOU  FINISH EACH QUESTION
     OR IF YOU WANT TO USE  THE DEFAULT VALUE.


EXHIBIT A-2a. Example of the RPM-IV front end interactive program
SETUPRPM, showing how a run can be successfully terminated before completion
User responses are shown in bold letters.

91124rl.ll
                                  A-7
-------
  (2)  IF YOU INPUT A REAL NUMBER, PLEASE ENTER IT WITH DECIMAL POINT.
 (3)  THIS PROGRAM WILL AUTOMATICALLY GENERATE TWO OUTPUT FILES
           UNIT 8 : INPUT FILE .FOR RPM RUNS
           UNIT 9 : CARBON-COPY FILE FOR FUTURE RE -STARTS
  (4)  SHOULD YOU WANT TO STOP DURING THE MIDDLE OF -AN ENTRY PROCESS,
      FOR AN UNELUDABLE REASON GIVE THE PROGRAM A FALSE ANSWER
      INSTEAD OF ARBITARILY KILLING IT. THIS WAY, YOU MAY RETAIN MOST OF
      THE INPUT THAT YOU HAVE ENTERED IN THE CARBON-COPY FILE.

 YOU CAN THEN,  CONTINUE THE INPUT PROCESS LATER BY DOING THE FOLLOWINGS-
      (A)  RERUN THIS PROGRAM AND SELECT THE RE -START OPTION
      (B)  TYPE IN THE OLD FILE NAME (UNIT 9 OF PREVIOUS RUN)  FOR UNIT 10

 IF  YOU ARE READING FROM AN EXISTING FILE (UNIT 10) ,  TYPE "  T " .
 IF  YOU ARE ENTERING FROM THE TERMINAL,             ,  TYPE "  F " .
F
 PLEASE CHOOSE  THE SYSTEM YOU ARE USING:
     1 - PC
     2 - IBM MAIN FRAME
     3 - VAX
     4 - UNIX
     5 - OTHER
  IS THIS A RESTART OF YOUR PREVIOUS ENTRY PROCESS?
  (ENTER "  T  "  FOR "YES" AND "  F "  FOR "NO")

  PLEASE LEAVE  COMMENTS ABOUT YOUR  CURRENT RUN.
  ENTER  NO  MORE THAN 72 CHARACTERS : front end program test

  PLEASE MAKE A CHOICE:
     (1) DO AMBIENT (I.E.  BACKGROUND)  SIMULATION ONLY
                                          --- ENTER "1"
     (2) DO PLUME  SIMULATION ONLY         --- ENTER "2"
     (3) DO AMBIENT FIRST,  FOLLOWED  BY PLUME SIMULATION
                                          --- ENTER "3"
 THE FOLLOWING PARAMETER VALUES ARE -USED:
     MODE1 3 1:  DO SINGLE  PLUME  (SOURCE)  ONLY
     MODE2 « 3:  DO AMBIENT SIMULATION FIRST,
                 FOLLOWED BY PLUME SIMULATIC5N.
     MODE3 » 3:  DO FAR- SOURCE SIMULATION  WITH RECTANGULAR CROSS - SECTIONS .

  (YOU DO NOT HAVE A CHOICE  ON VALUES OF MODE1  & MODES AT THE PRESENT TIME.)

 IS THE PLUME SYMMETRIC TO  ITS CENTER  LINE?
  (ENTER " T " FOR "YES" AND " F " FOR  "NO")

 HOW MANY CELLS ARE THERE ACROSS A PLUME?
  (ENTER EVEN NUMBERS FROM 2 TO 10 INCLUSIVE, RECOMMENDED VALUE=6)


 DO YOU WANT TO SAVE RPM- IV OUTPUT TO  DISK?
  (" T " FOR YES AND " F " FOR NO)
EXHIBIT A-2a.  Continued.
91124rl.ll
                                  A-8
-------
   ENTER INTERVAL BETWEEN SUCCESSIVE OUTPUTS
  ?(RECOMMENDED VALUE =60.0 MIN.)  --- ENTER IN MINUTES

  60.0
   /nc.r.o«^.^— WANT "^ START YODR SIMULATION DOWNWIND?
   (RECOMMEND VALUE = 100 METERS)   --- ENTER IN METERS

  ioo.o
  WHERE DO  YOU WANT TO TERMINATE YOUR SIMUL. DOWNWIND?
   (RECOMMENDED VALUE = 1000 KM)     --- ENTER IN METERS

  1000.0
  IF TIME "0"  IS  THE TIME WHEN PLUME GETS OUT OF STACK
  WHEN DO YOU WANT TO START SIMULATION?
   (RECOMMENDED VALUE . 0 MIN.)      --- ENTER IN MIN.

  6.0
  HOW LONG  IS  YOUR SIMULATION PERIOD?
  (RECOMMENDED VALUE = 24 HRS)
  ?            ...  ENTER IN HOURS  OR FRACTIONS OF AN HOUR

 24.0
  PLEASE DEFINE PLUME  WIDTH IN MULTIPLES  OF SIGMA-Y-
  (RECOMMENDED  VALUE  = 4  SIGMA-Y)

 4
  THE VALUES YOU HAVE  ENTERED ARE:
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(.8)
(9)
     IS THE PLUME SYMMETRIC TO ITS CENTER LINE?
     HOW MANY CELLS ARE THERE ACROSS A PLUME?
     SAVE RPM-IV OUTPUT TO DISK?   (T-YES  F-NO)
     INTERVAL BETWEEN SUCCESSIVE OUTPUTS
     SIMULATION DOWNWIND TO START  (M) ?
     TERMINATE YOUR SIMULATION DOWNWIND?
     TIME TO START SIMULATION?
     SIMULATION PERIOD? (HOURS)
     PLUME WIDTH IN MULTIPLES OF SIGMA- Y:
        T
        6
        T
   60.000
  100.000
 1000.000
    0.000
   24.000
    4.000
  ENTER THE ITEM NUMBER TO CHANGE (IN INTEGER)
 DO YOU WANT TO SAVE RPM-IV OUTPUT TO DISK?
 ENTER  "0"  FOR NO AND "1"  FOR YES
 0
 THE VALUES YOU HAVE ENTERED ARE:
 (1)
 (2)
 (3)
 (4)
 (5)
 (6)
 (7).
   IS THE PLUME SYMMETRIC  TO ITS CENTER LINE?
   HOW MANY CELLS ARE THERE  ACROSS A PLUME?
   SAVE RPM-IV OUTPUT TO DISK?   (3.-YES,  0-NO)
   INTERVAL BETWEEN SUCCESSIVE  OUTPUTS
   SIMULATION DOWNWIND TO  START (M)?
   TERMINATE YOUR SIMULATION DOWNWIND?
   TIME TO START SIMULATION?
       T
       6
       0
  60.000
 100.000
1000.000
   0.000
EXHIBIT A-2a.  Continued.

91124rl.ll
                                  A-9
-------
 (8)  SIMULATION PERIOD? (HOURS)
 (9)  PLUME WIDTH IN MULTIPLES OF SIGMA-Y:
                                  24.000
                                  4.000
 DO YOU WANT TO CONTINUE OR RE-ENTER SOME OF THE ABOVE VALUES?
  (ENTER "  T " TO CONTINUE,  " F " TO RE-ENTER)
 THE FOLLOWING 6 VARIABLES ARE SET BEFOREHAND.
  (1) FACTR -  1.0

  (2) HSTART=1'.OE-16
  (3) HMIN » l.OE-16
  (4) HMAX = 10.0
  (5) EPS  » 0.005

  (6) TOL  s 0.005
DISTANCE FACTOR FOR CALCULATING
GRADIENTS ACROSS PLUME  "EDGE"
INITIAL TIME STEP, IN MINUTES
MINIMUM TIME STEP, IN MINUTES
MAXIMUM TIME STEP, IN MINUTES
ERROR BOUND USED IN THE ODE
SYSTEM SOLVER
TOLERANCE LIMIT FOR STEADY-STATE APPROXIMATION
 DO YOU WANT TO CONTINUE  WITHOUT CHANGING ANY OF THE ABOVE 6 VALUES?
  (ENTER « T "  FOR "YES" AND "  F " FOR "NO")  -

t
 ENTER LONGITUDE  OF  LOCATION:  IN DEGREES,  POSITIVE IN THE U.S.
  (E.G. : 118.250  DEGREE)
?               •   .  .
118.25
 ENTER LATITUDE OF LOCATION: IN DEGREES,  (NO EQUATOR)
  (E.G. : 34.058 DEGREE)
?
34.058
 ENTER TIME ZONE  AT  LOCATION:
  (5.0 a EASTERN;  6.0 = CENTRAL;  7.0  = MOUNTAIN;  8.0 = PACIFIC)
?
8.0
 ENTER STARTING TIME OF THE SIMULATION DAY:
  (IN MILITARY  HOURS:  6 PM = 1800.0)
?
300.0
 ENTER YEAR OF SIMULATION:  (E.G.  1988)
•>
i'990
 ENTER MONTH OF SIMULATION:  (1 TO 12)
 ENTER STARTING DAY OF SIMULATION:  (1 TO  31)
?
15
 THE VALUES YOU HAVE ENTERED ARE:
 (1) ENTERED LONGITUDE
 (2) ENTERED LATITUDE
 (3) ENTERED TIME ZONE
 (4) ENTERED STARTING TIME  (MILITARY HOURS)
 (5) ENTERED YEAR OF SIMULATION
 (6) ENTERED MONTH OF SIMULATION
 (7) ENTERED STARTING DAY OF SIMULATION
                            118.250
                             34.058
                              8.000
                            300.000
                               1990
                                  7
                                 15
EXHIBIT A-2a.  Continued.
9I124rl.ll
                                  A-10
-------
                                             °F
   YOU HAVE THE FOLLOWING OUTPUT OPTIONS-

        !J! !SS ^LAT TIME IH^RVALS YOU SPECIFIED BEFORE
           OUTPUT AT USER SPECIFIED DOWNWIND DISTANCES



                         ENTER OPTION NUMBER
  YOU HAVE FINISHED DEFINING 'THE OUTPUT OPTIONS.

  YOUR CHOICE ON OUTPUT OPTIONS IS  :           i
  YOU HAVE THE FOLLOWING OUTPUT OPTIONS-
           ssss-s-ss ays-ssis          BETORE
                                                   DISTAHCES-
                   -----  ENTER OPTION NUMBER
 .
                                                   IS
                                            TO
 100.0 500.0 1000.0

  YOU HAVE FINISHED  DEFINING THE OUTPUT OPTIONS.


  YOUR CHOICE ON OUTPUT OPTIONS IS  -           3
                                            OT
  *** YOU HAVE FINISHED DEFINING PARAMETERS TO
     CONTROL THE STREAMLINE OPERATION OF THE RUN ***



  PLEASE PRESS » T " TO CONTINUE OR » F » TO STOP
                 THANK YOU FOR USING RPM FRNTEND
                       SEE YOU LATER
READY
EXHIBIT A-2a. Concluded.


91124rl.ll
                                                   ro
                               A-ll
-------
This is the restart of  FRNTEND.
copy rpmcc.xn rpmrv.in
EX 'MMAS.RPM.CLIST(FRNTEND)'
               WELCOME TO RPM FRNTEND INTERACTIVE SOFTWARE 1

                       IS THIS A NEW START?
                   PLEASE TYPE "  N " FOR NEW START
                                "  R " FOR RE-START
                    ENTER THE  NAME  OF FILE 1 (UNIT 8)
                 ( THIS WILL BE THE  INPUT FILE FOR RPM RUNS)
             (THE FULL PATH NAME,  NOT ENCLOSED IN SINGLE QUOTES)
                    (THE RECOMMENDED NAME IS RPM.IN)
zwar tana. rpm. in
                    ENTER THE NAME  OF FILE 2 (UNIT 9).
          (THIS WILL BE THE  CORBON-COPY FILE FOR FUTURE  RESTART)
             (THE FULL PATH  NAME,  NOT ENCLOSED IN SINGLE QUOTES)
                    (THE RECOMMENDED NAME IS RPMCC.IN)
zwartma.rpmcc.in

                    ENTER THE NAME  OF THE  OLD FILE:  '
             (THE FULL PATH NAME,  NOT ENCLOSED IN SINGLE QUOTES)
                    (THE RECOMMENDED NAME IS  RPMRV.IN)

zwar tana. rpmrv. in


  ********** WELCOME TO RPM FRONT END !! *************

 THIS IS A USER-INTERFACE PROGRAM TO CREATE  AN INPUT
 SPECIFICATIONS FILE FOR RPM-IV


 FOR WRITTEN DOCUMENTATION OF SUPPORT, .PLEASE CONTACT:

   SHAO-HANG CHU (ENVIRONMENTAL SCIENTIST)

   U.S. ENVIRONMENTAL PROTECTION  AGENCY

   OFFICE OF AIR QUALITY PLANNING AND STANDARDS,  MD  14

   RESEARCH TRIANGLE PARK


FIGURE A-2b.  Example of the RPM-IV front end interactive program showing a
restart of the Input process.  This example uses the restart file (RPMPV.IN) obtained
from the run shown  in Exhibit A-2a.  User responses are shown hi bold letters.



91124r2.53
                                  A-12
-------
     (919)  541-5382
     (919)  541-2357  FAX
  PRESS  " ENTER  " TO CONTINUE1
  ***
      PLEASE READ THE FOLLOWING NOTES BEFORE YOU CONTINUE
   (1) PRESS ENTER AFTER YOU FINISH EACH QUESTION
      OR IF YOU WANT TO USE THE DEFAULT VALUE
   I?! H Y°U 1NPDT A REAL NUMBER, PLEASE ENTER IT WITH DECIMAL POINT
   (3) THIS PROGRAM WILL AUTOMATICALLY GENERATE TWO OUTPUT FILES
           UNIT 8 : INPUT FILE FOR RPM RUNS
           UNIT 9 : CARBON-COPY FILE FOR FUTURE RE-STARTS
   (4) SHOULD YOU WANT TO STOP DURING THE MIDDLE OF AN ENTRY PROCESS
      FOR AN UNELUDABLE REASON GIVB THE PROGRAM A FALSE ANSWER

                                                                 -" OT
  YOD
      (B)  TYPE IN THE OLD FILE NAME (UNIT 9 OF PREVIOUS RUN)  FOR UNIT 10
  IF YOU ARE READING FROM AN EXISTING FILE (UNIT 10)   TYPE " T »
  IF YOU ARE ENTERING FROM THE TERMINAL,             ,  TYPE « F " ."
  IS THIS A RESTART OF YOUR PREVIOUS ENTRY PROCESS?
  (ENTER " T "  FOR "YES"  AND "  F «  FOR "NO")

  PLEASE LEAVE  COMMENTS ABOUT YOUR  CURRENT RUN
  ENTER NO MORE THAN 72 CHARACTERS:

  PLEASE MAKE A CHOICE:
     (1)  DO AMBIENT (I.E.  BACKGROUND)  SIMULATION ONLY
                                          - - -  ENTER " 1 "
     (2)  DO PLUME  SIMULATION ONLY         ---  ENTER «2n
     (3)  DO AMBIENT FIRST,  FOLLOWED  BY .PLUME SIMULATION
                                          ---  ENTER "3"

  THE FOLLOWING PARAMETER  VALUES  ARE USED:   "
     MODE1 =1:   DO SINGLE PLUME (SOURCE) ONLY
     MODE2 » 3 :   DO AMBIENT SIMULATION FIRST,
                  FOLLOWED BY PLUME  SIMULATION
     MODE3 =3:   DO FAR- SOURCE SIMULATION WITH RECTANGULAR CROSS - SECTIONS .

  (YOU DO  NOT HAVE A CHOICE  ON VALUES OF MODE1 & MODE3 AT THE PRESENT TIME.)

  IS THE PLUME SYMMETRIC TO  ITS CENTER LINE?
  (ENTER  "  T  " FOR "YES" AND  " F  " FOR "NO")
  HOW MANY  CELLS ARE THERE ACROSS A  PLUME?

  £"S5 S        5££ SS^
  (" T " FOR  YES AND  "  F " FOR NO)
FIGURE A-2b.  Continued
91124r2.53
                                 A-13
-------
  ENTER INTERVAL BETWEEN SUCCESSIVE OUTPUTS
  (RECOMMENDED VALUE » 60.0 MIN.)   	ENTER IN MINUTES
  WHERE DO YOU WANT TO START YOUR SIMULATION DOWNWIND?
  (RECOMMEND VALUE » 100 METERS)    	ENTER IN METERS
  WHERE DO YOU WANT TO TERMINATE YOUR SIMUL. DOWNWIND?
  (RECOMMENDED VALUE • 1000 KM)     	ENTER IN METERS
  IF TIME "0" IS THE TIME WHEN PLUME GETS OUT OF STACK,
  WHEN DO YOU WANT TO START SIMULATION?
  (RECOMMENDED VALUE « 0 MIN.)      	ENTER IN MIN.
  HOW LONG IS YOUR SIMULATION PERIOD?
  (RECOMMENDED VALUE = 24 HRS)
             	 ENTER IN HOURS OR FRACTIONS OF AN HOUR
  PLEASE DEFINE PLUME WIDTH IN MULTIPLES OF SIGMA-Y:
  (RECOMMENDED VALUE 3 4 SIGMA-Y)
  THE VALUES YOU HAVE ENTERED ARE:

 (1)  IS THE PLUME SYMMETRIC TO ITS CENTER LINE?             T
 (2)  HOW MANY CELLS ARE THERE ACROSS A PLUME?               6
 (3)  SAVE RPM-IV OUTPUT TO DISK?   (T-YES,  F-NO)              T
 (4)  INTERVAL BETWEEN SUCCESSIVE OUTPUTS               60.000
 (5)  SIMULATION DOWNWIND TO START  (M)?                100.000
 (6)  TERMINATE YOUR SIMULATION DOWNWIND?             1000.000
 (7)  TIME TO START SIMULATION?                     '    0.000
 (8)  SIMULATION PERIOD? (HOURS)        '                 24.000
 (9)  PLUME WIDTH IN MULTIPLES OF SIGMA-Y:                4.000
  ENTER LONGITUDE OF LOCATION:  IN  DEGREES,  POSITIVE IN THE U.S.
  (E.G.  :  118.250 DEGREE)
  ENTER LATITUDE OF LOCATION:  IN DEGREES,  (NO EQUATOR)
  (E.G.  :  34.058 DEGREE)
  ENTER TIME ZONE AT LOCATION:
  (5.0 s EASTERN;  6.0 > CENTRAL; 7.0 = MOUNTAIN;  8.0 3 PACIFIC)
  ENTER STARTING TIME OF THE SIMULATION DAY:
  (IN MILITARY HOURS:  6 PM = 1800.0)
  ENTER YEAR OF SIMULATION:  (E.G.  1988)
  ENTER MONTH OF SIMULATION:  (1 TO 12)
  ENTER STARTING DAY OF SIMULATION:  (1 TO  31)

  YOU HAVE THE FOLLOWING OUTPUT OPTIONS:
       (1)  OUTPUT ONLY AT TIME INTERVALS YOU SPECIFIED BEFORE
       (2)  OUTPUT AT USER SPECIFIED  DOWNWIND DISTANCES  .
       (3)  OUTPUT AT BOTH TIME INTERVALS AND DOWNWIND DISTANCES.

  PLEASE MAKE YOUR CHOICE ON OUTPUT  OPTIONS:-
                    	  ENTER OPTION NUMBER
  YOU HAVE FINISHED DEFINING THE OUTPUT OPTIONS.

  YOUR CHOICE ON OUTPUT OPTIONS IS :            1

  DO  YOU WANT TO CONTINUE WITHOUT  CHANGING ANY OF THE ABOVE VALUES?
  (ENTER "  T "  FOR "YES"  AND  " F " FOR "NO")

  YOU HAVE THE FOLLOWING OUTPUT OPTIONS:
       (1)  OUTPUT ONLY AT TIME INTERVALS YOU SPECIFIED  BEFORE
       (2)  OUTPUT  AT USER SPECIFIED DOWNWIND  DISTANCES
       (3)  OUTPUT  AT BOTH TIME INTERVALS AND  DOWNWIND DISTANCES.
  PLEASE MAKE  YOUR CHOICE  ON OUTPUT OPTIONS:
                    	  ENTER OPTION NUMBER
EXHIBIT A-2b.  Continued

9lI24r2.53
                                 A-14
-------
                                                ODTPDT IS ro '
   ENTER DOWNWIND DISTANCES (AT WHICH ODTPDT IS 'TO BE PRINTED)
   YOU HAVE  FINISHED DEFINING THE OUTPUT OPTIONS.
   YOUR  CHOICE ON ODTPDT OPTIONS IS •            3
                                        WHICH ODTPDT is T° BE
  DO YOU WANT TO CONTINUE WITHOUT CHANGING ANY OF THE ABOVE VALUES'
   (ENTER " T " FOR  "YES" AND  »  F " FOR "NO")                 v^uas.
  *** YOU HAVE FINISHED DEFINING PARAMETERS TO
      CONTROL THE STREAMLINE  OPERATION OF THE  RUN ***
  *** START DEFINING CHEMISTRY SPECIFICS
                                         ***
  THE DEFAULT CHEMISTRY PACKAGE IS CB-IV, 1991-
  IT HAS THE FOLLOWING CHARACTERISTICS:
  (1)
  (2)
  (3)
  (4)
  (5)
  (6)
       95 TOTAL REACTIONS
       34 SPECIES WHOSE CONCENTRATIONS ARE VARIABLE
       NO STEADY STATE SPECIES
       NO UNCOUPLED SPECIES (I.E. NO PRODUCT-ONLYS)
       1  INERT SPECIES
       14 FLOWING (I.E.  ENTRAINED)  SPECIES
  TYPE IN SOME COMMENTS ABOUT CHEMISTRY: <32 CHARACTERS
 Front end chemistry test.


  COMPLETED WRITING NAMES OF REACTANTS,  PRODUCTS  AND
  VALUES OF REACTION CONSTANTS AND ACTIVIATION ENERGIES
  FOR CB-IV MECHANISM
  ENTER R
 EFERENCE TEMPERATURE FOR REACTION RATES-
  (DEFAULT IS  298  DEGREES KELVIN)    ---  ENTER IN KELVTN
 ?                             "             *
 305.0
 THE REFERENCE TEMPERATURE IS
  PLEASE ENTER " T "  FOR YES
 t
                                 305.000
                               F " FOR NO
CONTINUE?
         1.OOOE+00
 1  TRAC
 4  NO   1.120E-03
 7  ETH  4.640E-04
10  FORM 1.800E-03
13  PAR  1.250E-02
16  HO2  0. OOOE+00
2
5
8
11
14
17
TEST 1. OOOE+00
O3 6.340E-02
OLE 1.420E-04
TOL 1.330E-04
ISOP 3.050E-05
0 0. OOOE+00
                                                                     THE
                                                3   NO2   3.000E-03
                                                6   CO   2.000E-01
                                                9   ALD2  5.600E-04
                                               12   XYL   4.850E-05
                                               15   PAN   0.OOOE+00
                                               18   N2O5  0.OOOE+00
EXHIBIT A-2b.  Continued

91124r2.53
                                  A-15
-------
 19  H2O2  O.OOOE+00
 22  PNA  O.OOOE+00
 25  NOB  O.OOOE+00
 28  TO2  O.OOOE+00
 31  MGLY  O.OOOE+00
 34  CRO  O.OOOE+00
                       20  HNO2 O.OOOE+00     21
                       23  C2O3 O.OOOE+00     24
                       26  HNO3 O.OOOE+00     27
                       29  CRES 1.940E-05     30
                       32  XO2  O.OOOE+00     33
                       35  H2O  2.000E+04
O1D  O.OOOE+00
ROR  O.OOOE+00
OH   O.OOOE+00
OPEN O.OOOE+00
XO2N O.OOOE+00
 ENTER " T  "  IF YOU DO  NOT WANT TO MAKE ANY CHANGE ON
 THE  INITIAL  CONCENTRATIONS;  OTHERWISE, ENTER "  F "
*** YOU HAVE  COMPLETED THE  CHEMISTRY INPUT ***

 DO YOU WANT  TO CONTINUE WITH EMISSION INPUT?
 ENTER  " T  "  FOR YES OR  " F "  FOR NO:  .
 ***** START  INPUT OF EMISSION CHARACTERISTICS  *****
 PLEASE ENTER SOME COMMENTS ABOUT  SOURCE CHARACTERISTICS:
        --- NO MORE THAN  66 CHARACTERS
power plants
 ENTER NUMBER OF POINT SOURCES:
YOU HAVE SPECIFIED    2  POINT SOURCES.
ENTER " T " FOR YES OR " F " FOR NO:
t
                                          IS THIS CORRECT?
 DO YOU WANT TO CALCULATE PLUME RISE?  (NO IS RECOMMENDED)
  (ENTER " T " FOR YES,  " F  " FOR NO)
7
t
 ENTER A STABILITY CLASS:   --- RANGES FROM 1 TO 6

 STABILITY CATEGORIES ARE DEFINED ACCORDING TO
 PASQUILL-GIFFORD DIVISIONS ;
 "1" FOR EXTREMELY UNSTABLE;  "6 "FOR MODERATELY STABLE
 (DEFAULT IS 4 REPPESENTING NEUTRAL STABILITY)
 IF YOU HAVE TIME-VARIANT STABILITIES AS INPUT, USE DEFAULT HERE.
•y
2
CALCULATE PLUME RISE?  (T - YES, F - NO)  : f
STABILITY CATEGORIES  (PASQUILL-GIFFORD DIVISIONS)  :      2

 DO YOU WANT TO GO ON OR RE-ENTER?
 ENTER " T " TO GO ON OR " F  " TO RE-ENTER:
 ENTER STACK HEIGHT:
 (E.G.  100.0 M)
•)
ioo.o
 ENTER STACK DIAMETER:
 (E.G.    5.0 M)
                       ---IN METERS
                        	 IN METERS
EXHIBIT A-2b.  Continued
91124r2.53
                                  A-16

-------
  5.0
   ENTER STACK EXIT VELOCITY-
   (E.G.   20.0 M)
                               	 IN METERS/SECOND
 20.0
  ENTER PLUME EXIT TEMPERATURE-
   (E.G.  422.2 K)
                                   	  IN DEGREES  K
422.2
 ENTER AMBIENT TEMPERATURE AT STACK EXIT:

 (E.G.  298.2 K)          ""  IN DEGREE KELVIN
?
298.2
THE VALUES YOU HAVE ENTERED ARE-
(1) ENTER STACK HEIGHT   (METERS)
    ENTER STACK DIAMETER  (METERS)
    ENTER STACK EXIT VELOCITY   (METERS/SECOND)
    ENTER PLUME EXIT TEMPERATURE   (K)
  (2)
  (3)
  (4)
  (5)  ENTER AMBIENT TEMPERATURE AT STACK EXIT  (K)
                                                OF
        INJECTED?1*"3  DISTANCES WHEIIE EMISSIONS ARE
     (1) ENTER IN METERS
     (2) EACH DISTANCE SHOULD  HAVE A DECIMAL POINT.
 0.0 100.0
                              EMITTED
                                       3  SPKCIKS
                                        s
                                                       100.000
                                                         5.000
                                                        20.000
                                                       422.200
                                                       298.200
   (2) TRY NOT TO EXCEED 8 VALUES EACH LINE "
?  (3) ENTER DUMMY VALUES IF EMISSION-RATE INDEX

1000.0 1000.0
                                                  =,2
    (2)  SAME  RULES AS AMBIENT PRESSURES

303.0 303.5
 YOU HAVE FINISHED THE  EMISSIONS INPUTS PART 1.

THE VALUES YOU HAVE ENTERED  ARE-
                                  EMISSIONS *« TO BE INJECTED:
EXHIBIT A-2b.  Continued

91124r2.53
                                  A-17
-------
 (2) THE NUMBER OF SPECIES  EMITTED BY ALL POINT SOURCES:
  1   2
 (3) INDEX FOR UNITS OF EMISSION RATES  FOR ALL POINT SOURCES:
  1   1
 (4) AMBIENT PRESSURES AT ALL POINT  SOURCES:
 0.100E+04 0.100E+04
 (5) AMBIENT TEMPERATURES AT ALL POINT  SOURCES:
 0.303E+03 0.304E+03

 DO YOU WANT TO GO ON OR RE-ENTER THE  ABOVE VALUES?
 PLEASE ENTER n T " TO GO  ON,  " F "  TO RE-ENTER
 t                                                           .

 ENTER THE NAMES OF ALL EMITTED SPECIES  OF ALL POINT SOURCES:
 (PLEASE TAKE SPECIAL CARE IN  ENTERING THE SPECIES  NAMES)
   (1) 4 CHARACTER SPACE FOR EACH SPECIES NAME
   (2) ONE, LINE FOR EACH SOURCE (MAY HAVE MORE THAN ONE  SPECIES) .
no
no  no2
 ENTER THE EMISSION RATES  OF ALL EMITTED SPECIES AT ALL  POINT  SOURCES;
   (1) SAME UNIT AS WHAT YOU HAVE CHOSEN ABOVE
   (2) TRY NOT TO EXCEED 8 VALUES EACH LINE
   (3) RATES OF SOURCE 2 FOLLOW THOSE  OF SOURCE 1,  AND SO  ON  ...
 ?
 150
 ?
200 350
 ENTER MOLECULAR WEIGHTS OF ALL SPECIES  EMITTED BY  ALL
 POINT SOURCES
   (1) TRY NOT TO EXCEED 8 VALUES EACH LINE
   (2) VALUES OF SOURCE 2  FOLLOW THOSE OF SOURCE 1,  AND  SO ON  ...
   (3) ENTER DUMMY VALUES  IF IUNIT  - 2
 7
30
 ?
30 46
 YOU HAVE FINISHED THE EMISSIONS INPUTS.

THE VALUES YOU HAVE ENTERED ARE:
 (1) THE NAMES OF ALL EMITTED SPECIES OF  ALL POINT SOURCES:

   NO      NO      NO2
 (2) THE EMISSION RATES OF  ALL  EMITTED  SPECIES  OF ALL POINT SOURCES:

  0.2E+03   0.2E+03   0.4E+03
 (3) THE MOLECULAR WEIGHTS  OF ALi EMITTED 'SPECIES OF ALL  POINT  SOURCES:

0.300E+02 0.300E+02 0.460E+02

 DO YOU WANT TO CONTINUE WITHOUT CHANGING ANY  OF THE ABOVE VALUES?
 (ENTER " T " FOR "YES" AND "  F " FOR  "NO")
 *** YOU HAVE COMPLETED EMISSION SPECIFICATION INPUT ***

 DO YOU WANT TO CONTINUE?
 (ENTER " T * FOR YES OR " F " FOR NO)
EXHIBIT A-2b.  Continued

91124r2.S3
                                  A-18
-------
   *****  START INPUT OF METEOROLOGICAL PARAMETERS *****
                              " ODT
 Front end met  input test.

  D0
                                         N§PECIFISD DOWNWIND DISTANCES?
  IF  " 2  ", THE MODEL  WILL CALCULATE IT FOR YOU'
  (DEFAULT VALUE IS  1)
                                                            DISTANCES?
  IF " 2 ", THE MODEL WILL CALCULATE  IT FOR YOU!

                            ENTERED STACK ^FORMATION PREVIOUSLY)
  ENTER NUMBER OF WIND SPEEDS TO BE SPECIFIED AT
  SPECIFIED TIME OF THE SIMULATION PERIOD-
  (NO MORE THAN 10 SPECIFICATIONS)
  ENTER ALL WIND SPEED VALUES:
 ^ (ENTER IN "M/S"; NO MORE THAN 8 VALUES EACH LINE)

 3.0
 •}
 4.0


  ENTER THE TIMES THAT CORRESPOND TO THE WIND SPEEDS
  (MAXIMUM OF 8 VALUES PER LINE)

 0800  1000
  THE  VALUES YOU HAVE ENTERED ARE:
                                       DOWNWIND DISTANCES?
 (2)  SPECIFY PLUME  DEPTHS AT SPECIFIED DOWNWIND DISTANCES'
     ("  1  "  FOR YES,  "  2  " FOR NO)
        2
 (3)  NUMBER  OF  WIND SPEEDS SPECIFIED IN THE SIMULATION

 (4)  ALL WIND SPEED VALUES
 0.300E+01 0.400E+01

                                    WIND SPEEDS yOU ENTERED
EXHIBIT A-2b.  Continued
91124r2.53
                                 A-19
-------
  YOU HAVE CHOSEN TO INPUT  PLUME  WIDTH.
 ENTER NUMBER OF PLUME WIDTHS TO  BE  INPUT:
  (NO MORE THAN 30 VALUES)
?
02
 ENTER DOWNWIND DISTANCES AND PLUME  WIDTH IN FORMAT OF:
 DOWNWIND-DISTANCE; PLUME-WIDTH
  (EACH INPUT LINE CONTAINS  2 VARIABLES)
?
100.0 15.0
?
250.0 30.0
 THE VALUES YOU HAVE ENTERED ARE:
NUMBER OF PLUME WIDTHS TO BE INPUT  .
 2
DOWNWIND-DISTANCES
0.100E+03 0.250E+03
PLUME-WIDTHS
0.150E+02 0.300E+02
 DO YOU WANT TO GO ON OR RE-ENTER THE VALUES?
 PLEASE ENTER " T " TO GO ON, " F "  TO RE-ENTER
t
 **** START INPUT VERTICAL DISPERSION PARAMETERS  ****
 YOU HAVE CHOSEN TO LET THE MODEL CALCULATE PLUME DEPTH  FOR YOU.
 ENTER NUMBER OF MIXING DEPTHS TO BE INPUT:
  (NO MORE THAN 30 VALUES)
?
02
 ENTER MIXING DEPTH VALUES AND CORRESPONDING DOWNWIND DISTANCES
 IN THE FORMAT :  DOWNWIND-DISTANCE  MIXING-DEPTH
  (WITH SPACES BETWEEN EACH VARIABLE; EACH INPUT LINE CONTAINS  2 VALUES)
  (E.G. : 100.0  1250.0)
?
100.0 1250.0
?
250.0 1300.0
 THE VALUES YOU HAVE ENTERED ARE:
NUMBER OF MIXING DEPTHS
 2 •                                 •        *     •
DOWNWIND-DISTANCES
0.100E+03 0.250E+03
MIXING-DEPTHS
0.125E+04 0.130E+04
 DO YOU WANT TO CONTINUE WITHOUT CHANGING ANY OF THE ABOVE  VALUES?
  (ENTER " T " FOR "YES" AND " F " FOR  "NO11)
t

 YOU NEED TO ENTER STABILITY CLASSES FOR MODEL TO CALCULATE PLUME DEPTH.
 ENTER NUMBER OF STABILITY VALUES TO BE INPUT:
  (NO MORE THAN 30 VALUES)
EXHIBIT A-2b.  Continued
91124r2.53
                                 A-20
-------
   ENTER STABILITY VALUES AND CORRESPONDING TIMES IN THE FORMAT:

  ?{WITH SPACES BETWEEN EACH VARIABLE; EACH INPUT LINE CONTAINS 2 VALUES)

  0800  5
   THE  VALUES YOU HAVE ENTERED ARE-
  STABILITY  CLASSES
  O.OOOE-78
  STABILITY  VALUES
  0.800E+03
  CORRESPONDING TIME
  O.OOOE-78
  THE PLOUE RISE  (I.E. EFFECTIVE  STACK  HEIGHT)  IS  CttOJLATED TO BE
 412.240479      METERS.

  **************
  THE FOLLOWING TABLE GIVES YOU VALUES  OF PLUME DEPTH
  AT INDICATED DOWNWIND DISTANCES:
 OWN. DIST.

   .  100.00
     131.03
     162.07
     193.10
     224.14
     255.17
     286.21
     317^24
     348.28
     379.31
     410.34
     441.38
     472.41
     503.45
     534.48
PLM.DEPTH

    14.02
    17.75
    21.28
    24.64
    27.84
    30.92
    33.88
    36.74
    39.51
    42.19
    44.80
    47.34
    49.81
    52.23
    54.59
  PRESS  ENTER TO SEE THE SECOND TABLE
     565.52
     596.55
     627.59
     658.62
     689.65
     720.69
     751.72
     782.76
     813.79
     844.83
     875.86
     906.90
     937.93
     968.96
   1000.00
    56.89
    59.15
    61.36
    63.53
    65.65
    67.74
    69.79
    71.80
    73.78
    75.73
    77.65
    79.53
    81.39
    83.23
    85.03
EXHIBIT A-2b.  Continued

91124r2.53
                                 A-21
-------
  *** YOU HAVE FINISHED DEFINING METEOROLOGICAL PARAMETERS PART-I
      TO CONTROL THE OPERATION OF THE RUN ***


  PLEASE PRESS " T " TO CONTINUE OR " F " TO STOP
 t

  **** START INPUT PHOTOLYSIS PARAMETERS ****

  DO YOU WANT THE MODEL AUTOMATICALLY CALCULATES  PHOTOLYSIS RATES
  ACCORDING TO THE LOCATIONS AND TIMES THAT YOU HAVE SPECIFIED?
  ENTER " T " FOR n YES "  OR " F " FOR " NO "
  IF YOU SPECIFY " NO n, YOU WILL NEED TO SPECIFY THOSE
  RATES AS A FUNCTION OF TIME.
 YOU HAVE  CHOSEN TO LET RPM-IV CALCULATE PHOTOLYSIS RATES ACCORDING TO
EVERYTHING
 THAT  IS HARD -WIRED IN THE MODEL BASED ON CB-IV MECHANISM.
 DO  YOU WANT THEM TO BE CALCULATED ACCORDING TO  THE LOCATION AND TIME
INFORMATION
 THAT  YOU  ENTERED AT THE BEGINNING?
  (IF NOT,  YOU WILL NEED TO INPUT TIME -DEPENDENT ZENITH ANGLES.)
  (ENTER "  T " FOR "YES" AND "  F n FOR "NO")
 PLEASE IDENTIFY YOUR PHOTOLYSIS REACTIONS
 BY ENTERING THE REACTION NUMBERS  IN CB-lV REACTION SEQUENCE:
 (ONE NUMBER EACH LINE)
?
1
?
8
?
9
?
14
?
23
?
34
7                                           *
38
?
39
?
45
?
76
?
84
 THE PHOTOLYSIS REACTIONS YOU ENTERED
 ACCORDING TO THE REACTION NUMBERS IN CB-IV REACTION SEQUENCE ARE
        1         8         9        14        23        34
39        45        76        84
                                                                   38
EXHIBIT A-2b.  Continued

91124r2.53
                                   A-22
-------
                                                OF
             IHPt)T SHBIEHT TEMPERATOHS SPECIFICATIONS "»
                                                       s as,- — >
                   CORRESPONDING AMBIENT TEMPERATURES-
  0800  298.0
   THE  VALUES YOU HAVE ENTERED ARE-
          1
   TIME -VARIANT AMBIENT TEMPERATURES
   TIME
       800.
   CORRESPONDING AMBIENT TEMPERATURES
       298.
  YOU NEED TO INPUT AMBIENT CONCENTRATIONS NOW!
 1000.0
  THE VALUES YOU HAVE ENTERED ARE •
  NUMBER OF SETS OF TIME -DEPENDENT  AMBIENT CONCENTRATIONS.

  THE TIMES TO CHANGE AMBIENT CONCENTRATIONS
 0.100E+04
                         DIFFEREOT
IS RPM-IV (GEAR)  GOING TO BE USED?
" T " FOR YES AND « F " FOR NO

YOU HAVE CHOOSEN TO RUN RPM-IV

IS THIS CORRECT?  (VERY IMPORTANT!)
PLEASE ENTER » T »  FOR YES,  " F »  FOR NO
                                          ^RMATS FOR AMBIENT
 ENTER THE NAME OF THE SPECIES AS WELL AS ITS TIME-

EXmBITA-2b. Continued
91124r2.53
                                  A-23
-------
 DEPENDENT AMBIENT CONCENTRATIONS:
 ENTER NAME OF SPECIES           1
test
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES  :  TEST
?
1.0
 ENTER NAME OF SPECIES           2
no2
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES  :  NO2
?
0.0125
 ENTER NAME OF SPECIES           3
no
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES  :  NO
p
0.01
 ENTER NAME OF SPECIES           4
03
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES  :  O3
?
0.04
 ENTER NAME OF SPECIES           5
CO
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES  :  CO
?
1.0
 ENTER NAME OF SPECIES           6
eth
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES  :  ETH
?
0.0085
 ENTER NAME OF SPECIES           7
ole
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES  :  OLE
?
0.005
 ENT.ER NAME OF SPECIES           8
ald2
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES  :  ALD2
?
0.002
 ENTER NAME OF SPECIES           9
form
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES  : * FORM
?
0.003
 ENTER NAME OF SPECIES          10
tol
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES  :  TOL
•>
6.003
 ENTER NAME OF SPECIES          11
xyl
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES  :  XYL
 .0016
 ENTER NAME OF SPECIES
par
                                12
EXHIBIT A-2b.  Continued

91124r2.53
                                   A-24
-------
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES

6.25
 ENTER NAME OF SPECIES          13
isop
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES

2.5e-5
 ENTER NAME OF SPECIES          14
eras
 ENTER AMBIENT CONCENTRATIONS FOR SPECIES

0.001

 THE VALUES YOU HAVE ENTERED ARE
 THE NAME OF THE SPECIES ENTERED
 TEST   .10E+01
 NO2    .12E-01
 NO     .10E-01
 O3     .40E-01
 CO     .10E+01
 ETH    .85E-02
 OLE    .50E-02
 ALD2   .20E-02
 FORM   .30E-02
 TOL    .30E-02
 XYL    .16E-02
 PAR    .25E+00
 ISOP   .25E-04
 CRES   .10E-02
                                               PAR
                                               ISOP
                                              CRBS
  PLEASE  PRESS  "  T "  TO CONTINUE OR »  F »  TO STOP
  ***' START  INPUT  PARAMETERS  TO  CONTROL RPM-IV OUTPUT
      V CAN  PRINT OUT CONCENTRATION CHANGES  WITH TIME
 AS WELL AS, AT YOUR CHOICE, MAXIMUM CONCENTRATION TABLES
 55                         ""* TO
 ENTER ONE OF THE FOLLOWING NUMBERS FOR YOUR CHOICE-
 0: PLOT PLUME AVERAGES AS A FUNCTION OF TIME
 1: PLOT PLUME MAXIMA AS A FUNCTION OF TIME
 2: PLOT BOTH PLUME AVERAGE AND MAXIMA AS A FUNCTION OF TIME
EXHIBIT A-2b.  Continued

91124r2.53
                                  A-25
-------
   ENTER ONE OF THE FOLLOWING NUMBERS FOR YOUR CHOICE:
  0:  DO NOT PRINT MAXIMUM CONCENTRATION
  1:  PRINT MAXIMUM PLUME -AVERAGE, CONCENTRATIONS
  2:  PRINT MAXIMUM CELL -AVERAGE CONCENTRATIONS
  3:  PRINT BOTH PLUME -AVERAGE AND CELL -AVERAGE MAXIMA
  ENTER ONE OF THE FOLLOWING NUMBERS TO INDICATE HOW YOU WANT MAXIMUM
 CONCENTRATIONS TO BE SELECTED:
     1:  CONSIDER ALL CONCENTRATIONS
     2:  CONSIDER CONCENTRATIONS  BEYOND PLUME TOUCHDOWN.
     3 :  CONSIDER CONCENTRATIONS  BEYOND THE " VERTICALLY WELL -MIXED "
        CRITICAL DISTANCE.
  FOR EACH SPECIES  THAT YOU WANT TO SEE THE OUTPUT,
  YOU HAVE THE  CHOICE  FOR A REDUCTION FACTOR TO EITHER
  ENLARGE  OR REDUCE THE RANGE OF CONCENTRATION PLOT  CORDINATE.
  A VALUE  OF 1  OR 0 WOULD MEAN NO REDUCTION ON ORDINATE;
  A VALUE  OF 2  TO 99 WOULD MEAN REDUCING ORDINATE
  PLEASE ENTER  THE  NAME OF THE SPECIES TOGETHER WITH
  THE REDUCTION FACTOR IN FORMAT:  (NAME; FACTOR)
  {*** PLEASE NOTE  : NAME REQUIRES 4 CHARACTER SPACES.  ***)
  (E.G.  NO2   25)
  (USE SPACES TO SEPERATE NAME & FACTOR)  '
no  25
no2  50
  THE VALUES YOU HAVE  ENTERED ARE:
 (1)  NUMBER OF  SPECIES TO PRINT OUT CONCENTRATION CHANGES
     WITH  TIME  AND  MAXIMUM CONCENTRATION TABLES.  (IF CHOOSEN)
        2
 (2)  PLUME OPTION
      0 :  AVERAGES  AS  A FUNCTION OF TIME
  (3)  PRINT OPTION
      1 :  MAXIMUM PLUME -AVERAGE CONCENTRATIONS
  (4)  MAXIMUM CONCENTRATIONS  SELECTION
      2 :  BEYOND PLUME TOUCHDOWN.
  (5)  SPECIES NAME  & THE CORRESPONDING REDUCTION FACTOR .
     NO     NO2
      25     50
                                            *
 DO  YOU WANT TO CONTINUE WITHOUT  CHANGING ANY OF THE ABOVE VALUES?
  (ENTER "  T "  FOR  "YES"  AND  "  F "  FOR "NO")
 YOU HAVE FINISHED ALL INPUTS NECESSARY TO RUN RPM-IV.
                  THANK YOU FOR USING RPM FRNTEND
                        SEE YOU LATER
READY
FIGURE A-2b.  Concluded.

91124r2.53
                                   A-26
-------
     Front End CNTL Test
        3
      T
        6
        0
      0.600E+02
      0.100E+03
      0.350E+06
      O.OOOE+00
      0.840E+03
      0.400E+01
      F
        118.250
         34.058
      0.800E+01
        300.000
     1990
        7
       15
        1
        ***  Chemistry Input  Starts:  ***
     Front End CHEM Test
      0.298E+03
         F
       3
      2.000E-03
      111
       5
      4.000E-02
      111
      999
            emission input starts ***
Front End -EMIS Test
2
2
4
0.200E+03
0.500E+01
0.400E+01
0.350E+03
0.298E+03
0.200E+03
2 2
2 1
0.100E+04
0.298E+03
NO NO2
NO NO2
0.5E+05
0.9E+02
O.OOOE+00
0.300E+02








0.500E+03


0.101E+04
0.300E+03


0.3E+04
0 .-1E+02
O.OOOE+00
0.460E+02
   EXHIBIT A-3.  Example of RPMPV.IN, created by the front end program and
   used in the restart of the front end program shown hi Exhibit A-2b.
                                   A-27
91124r2.31
-------
      **** meteorology input starts ****

    Front End MET Test
     2
     2
       1
     0.400E+01
     O.OOOE+00
     1
            0.         3
             F

    **** start input vertical dispersion parameters:
     0.100E+03  0.500E+03
     0.200E+04  0.750E+03
     0.300E+04  0.750E+03

    *****  Start input photolysis parameters *****

             T
             T
       1
       8
       9
      14
      23
      34
      38
      39
      45
      76
      84
       2
    "O.OOOE+00  0.303E+03
     0.600E+03  0.303E+03
       1
   EXHIBIT A-3.  Concluded.
                                   A-28
9U24r2.31

-------
  RPM-IV: FRONT END PROGRAM TEST
     133
   T
     6   0
   0.600E+02
   0.100E+03 0.100E+04
0. OOOE+00 0.
0.400E+01 0.
l.OOOE-16 1.
118.000
3 3
0.100E+03 0.
CARBON BOND
95 34 0
N02
O
O3 NO
O NO2
O NO2
O NO
NO2 O3
03
O3
O1D
O1D H2O
O3 OH
O3 HO2
NO3
NO3 NO
NO3 NO2
NO3 NO2
N2O5 H20
N2O5
NO NO
NO NO2 H2O
NO OH
HNO2
OH HNO2
HNO2 HNO2
NO2 OH
OH HNO3
HO2 NO
H02 N02
PNA
OH PNA
HO2 HO2
HO2 HO2 H20
H2O2
OH H2O2
OH CO
FORM OH
FORM
FORM
FORM O
FORM NO3
ALD2 O
ALD2 OH
ALD2 NO3
ALD2
C2O3 NO
C2O3 NO2
PAN
C2O3 C2O3
C2O3 HO2
/"\Y_T
OH
144E+04
100E+01
OOOE-16 1.
34.100
500E+03 0.
MECHANISM


OOOE+01 5.
8.000
100E+04
VERSION IV
0 1 14
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
1.
1.
NO 1.
03
NO2
NO
NO3
NO2
NO3
0
O1D
O
OH
HO2
OH


OOOE-03 5.000E-03
300.0001990 7 15

, MAY 1991 ----FRONT

O












0.89 NO2 0.89 O 0.11 NO
2.
1.
1.
2.
1.
2.
2.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
1.
1.
1.
2.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
0.79
1.
NO2
NO 1.
N2O5
HNO3
NO3 1.
NO2
HNO2
HNO2
NO 1.
N02
NO 1.
HNO3
NO3 -
OH 1.
PNA
HO2 1.
NO2
H2O2
H2O2
OH
HO2
HO2
HO2 1.
HO2 1.
CO
OH 1.
HNO31.
C2O31.
C2O3
C2031.
FORM2.
FORM1.
PAN
C2031.
FORM2.
FORMO . 79
FORM1.

NO2


NO2



OH

NO2


NO2

NO2






CO
CO

HO2 1. CO
HO2 1. CO
OH

HNO3
H02 1. CO 1.
NO2 1. HO2 1.
NO2
X02 2. H02
XO2 0.79 HO2 0.79
XO2 1. HO2
                                                        END CHEMISTRY TEST.
                                                         XO2
                                                         XO2
                                                         OH
 1
 4
 2
 1
 2
 2
 4
 5
 1
 4
 3
 1
 3
 3
 4,
 5.
 1.
 1.
 2.
 1.
 1.
 9.
 1.
.9.
 1.
 1.
 2.
 1.
 2.
 5
 6
 4
 2
 1
 2
3
1
1
1,
2.
9.
6.
2.
3.
1.
2.
1.
2.
3.
9.
2.
 .OOOE+00
 .323E+06
 . 664E+01
 .375E+04
 •309E+03
 438E+03
 731E-02
 300E-02
 OOOE+00
 246E+05
 260E+00
 OOOE+02
 OOOE+00
 .390E+01
 .416E+04
 -901E-01
 .853E+03
 .900E-06
 .776E+00
 .539E-04
 .600E-11
 .799E+03
 .975E-01
 .770E+03
 .500E-05
 . 682E+04
 .179E+02
 -227E+04
.025E+03
.115E+00
.833E+03
-144E+03-
.181E-01-
.890E-01
.520E+03
.220E+02
.500E+04
, OOOE+00
.OOOE+00
 370E+02
 300E-01
 360E+02
 400E+04-
 700E+00
 OOOE+00
 815E+04
 374E+04-
 540E-02
 700E+03
 600E+03
 100E+01
                                                                         0.OOOE+00
                                                                         •1.175E+03
                                                                         1.370E+03
                                                                         0.OOOE+00
                                                                         6.870E+02
                                                                         6.020E+02
                                                                         2.450E+02
                                                                         0.OOOE+00
                                                                         0.OOOE+00
                                                                           900E+02
                                                                         0.OOOE+00
                                                                         9.400E+02
                                                                         5.800E+02
                                                                         a. OOOE+OO
                                                                         2.500E+02
                                                                         1.230E+03
                                                                           560E+02
-3
-2
                                                                         0. OOOE+00
                                                                         1.090E+04
                                                                        •5.300E+02
                                                                         0.OOOE+00
                                                                        •8.-060E+02
                                                                         0.OOOE+00
                                                                         0.OOOE+00
                                                                         0.OOOE+00
                                                                         7.130E+02
                                                                         l.OOOE+03
                                                                         2.400E+02
                                                                         7.490E+02
                                                                         1.012E+04
                                                                         3.800E+02
                                                                          150E+03
                                                                          800E+03
                                                                        0.OOOE+00
   870E+02
 0.OOOE+00
 0.OOOE+00
 0.OOOE+00
 0.OOOE+00
 1.550E+03
 0.OOOE+00
 9.860E+02
•2.500E+02
 0.OOOE+00
 0.OOOE+00
 1.800E+02
 3.800E+02
 1.350E+04
 0.OOOE+00
 0.OOOE+00
 1.710E+03
EXHIBIT A-4.  Example of a final output file,- RPM.EST, to be used as input file RPM-IV.
                                   A-29
91124r2.20
-------
PAR
PAR
ROR
ROR
ROR
ROR
O
O
OH
OH
03
03
NO3
NO3
O
O
OH
O3
TOL
TO2
TO2
OH
CRES
CRO
OPEN
OPEN
OPEN
OPEN
OPEN
OH
OH
OH
MGLY
O
O
OH
OH
O3
O3
NO3
XO2
XO2
XO2N
XO2
OH
OH



NO2
OLE
OLE
OLE
OLE
OLE
OLE
OLE
OLE
ETH
ETH
ETH
ETH
OH
NO

CRES
NO3
NO2

OH
OH
O3
O3
XYL
XYL
MGLY

ISOP
ISOP
ISOP
ISOP
ISOP
ISOP
ISOP
NO
XO2
NO
HO2












































1.74
-0.22
1.92
0.08
1.

1.26
0.4
2.
2.
1.0
0.66
1.82
2.
2.
0.6
. 1.
1.
0.44
0.9
1.
0.4
1.

1.
2.
2.
0.06 '
1.38
1.4
2.2
1.
1.
1.2
1.0
2.
2.
2.
0.2
1.
1.



XO2 0
PAR 1
XO2 2
XO2NO
HO2

ALD20
FORMO
FORM2
HO2
ALD21
CO 0
XO2 2
.26
.52
.2
.04


.76
.04
XO2NO .
ROR
ALD21.
ROR


HO2 0.
XO2NO .
.22

.88



,56
,44
ALD2-2.
HO2 0.22

H02 -4.2



XO2 0.6
PAR 0.4
PAR 2.
ALD2

PAR



CO
OH
XO2
6.015E+02
6.015E+02
6.855E+04
6.855E+04
9.545E+04
2.200E+04
2.960E+03
2.960E+03
O.OOOE+00
O.OOOE+00
8.000E+03
8.000E+03
O.OOOE+00
O.OOOE+00
3.240E+02
3.240E+02
2 . 100E+04 -5 . 040E+02
2 . 100E+04 -5 . 040E+02
.48
.88
.
NO2 -2.
FORM3
OH
XO2 1
FORMO
HO2 0
N02 0
CRES1
CRO 0
CRO 1

C2O31
XO2 4
FORM
ALD21
CO 0
H02 1
PAR 0
X02 1
C2O31
HO2 1
CO 0
XO2 2
ETH 0
FORMO
PAR 0
X02N
NO2



.4

.56
.42
.08
.9
.
.6
.

»
.

.24
.16
.0
.6
.

.6
.90

.8
.8
.12





FORMO.
44
HO2 -2.
FORMO.
PAR
H02 2.

FORMO.
CO. 0.
X02 0.
HO2 0.
HO2
X02 0.
HNO3

HO2 1.
CO 4.

C2O31.
OH 1.
XO2 0.
T02
C2O3
HO2 1.
ALD21.
ETH 1.
FORM1.
MGLYO .
ALD21.
CO 0.





18



22
12
36
9

6





4
52
4



10
8
34
4
10
88





XO2 0.2
PAR
XO2N2 .

CO 1.4

ALD21.
HO2.
CRES0.56
OPEN

H02 0.3


CO
HO2 2.

FORMO. 06
HO2 0.4
CRES1.6


CO
OLE 1.0
PAR
HO2 0.26
C2030.4
ETH 0.4
HO2 0.2





OH

ALD2

XO2

HO2

TO2


OPEN



C2O3

XO2
MGLY
MGLY



X02

XO2N
ALD2
MGLY
OH





9.000E-03
9.000E-03
5.675E+00
5.675E+00
5.400E+02
5.400E+02
2.105E+03
2.105E+03
O.OOOE+00
O.OOOE+00
7.920E+02
7.920E+02
1 . 192E+04 -4 . 110E+02
2.702E-03
9.150E+03-
1.200E+04
2.500E+02
6.100E+04
3.250E+04
2.000E+04
8.400E+00
2.200E+04
2.200E+04
7>500E-03
7.500E-03
1.810E+04-
1.810E+04-
2.600E+04
8.960E+00
1.350E+04
1.350E+04
7.100E+04
7.100E+04
9.000E-03
9.000E-03
4.700E+02
1.200E+04
2.000E+03-
l.OOOE+03
8.896E+03-
0.305E+03
TRAC
TEST
NO2
NO
O3
CO
ETH
OLE
ALD2
FORM
TOL
XYL
PAR
ISOP
PAN
H02
O
N2O5
H2O2
HNO2
O1D
l.OOOE+00
l.OOOE+00
3.000E-03
1.120E-03
6.340E-02
2.000E-01
4.640E-04
1.420E-04
5.600E-04
1.800E-03
1.330E-04
4.850E-05
1.250E-02
3.050E-05
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1









































































































'






























































2.633E+03
3.220E+02
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
5.000E+02
5.000E+02
1.160E+02
1.160E+02
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
1.300E+03
O.OOOE+00
1.300E+03






















91124r2.20
                                 EXHIBIT A-4.  Continued.
                                     A-30
-------
PNA
C2O3
ROR
N03
HN03
OH
T02
CRES
OPEN
MGLY
XO2
XO2N
CRO
H2O
O.QOQE-j-00 1
O.OOOE+00 1
O.OOOE+00 1
O.OOOE+00 1
O.OOOE+00 1
O.OOOE+00 1
O.OOOE+00 1
1.940E-05 1
O.OOOE+00 1
O.OOOE+00 1
O.OOOE+00 1
O.OOOE+00 1
O.OOOE+00 1
2.000E+04 1
  RPM-IV EMISSION INPUT:POWER PLANTS
     2
     2   2
   0.100E+03 0.500E+01 0.200E+02 0.422E+03 0.298E+03
          0.    1   1     1000
  NO        ISO.       30.
        100.    2   1     1000,
  NO        200.       30.
  N02        350.       46.
  RPM-IV METEOROLOGICAL INPUT-
   1121
                        303.
                       304.
                  FRONT END MET INPUT TEST.
    .300E+01
     2
    .100E+03
     2
    . 100E+03
     1
       .800.
          T
0.800E+03 0.400E+01 0.100E+04

0.150E+02 0.250E+03 0.300E+02

0.125E+04 0.250E+03 0.130E+04
    1
    8
    9
   14
   23
   34
   38
   39
   45'
   76
   84
    1
       800.

      1000.
    298
TEST
NO2
NO
O3
CO
ETH
OLE
ALD2
FORM
TOL
XYL
PAR
ISOP
CRES
2 0
l.OOOE+00
1.250E-02
l.OOOE-02
4.000E-02
1 .OOOE+00
8.500E-03
5.000E-03
2.000E-03
3.000E-03
3.000E-03
1.600E-03
2.SOOE-01
2.500E-05
l.OOOE-03
1 2
NO  25NO2 50
91124r2.20
                  EXHIBIT A-4. Concluded.
                      A-31
-------
    FRONT END PROGRAM TEST
             3
     T
             6
     T
     0.600E+02
     0.100E+03
     0.100E+04
     O.OOOE+00
     0.240E+02
     0.400E+01
     0.100E+01
     0.100E-15
     0.100E-15
     0.100E+02
     0.500E-02
     0.500E-02
     0.118E+03
     0.341E+02
     0.800E+01
       300.000
          1990
             7
            15
             1
     F
             3
             3
     0.100E+03 0.500E+03 0.100E+04
     T
        ***  CHEMISTRY INPUT STARTS:  ***
    FRONT END CHEMISTRY TEST.
     0.305E+03
         T
         *** EMISSION INPUT STARTS ***
    POWER PLANTS
             2
     T
             2
     0.100E+03
     0.500E+01
     0.200E+02
     0.422E+03
     0.298E+03
     O.OOOE+00 0.100E+03
       1   2
       1   1
     0.100E+04 0.100E+04
     0.303E+03 0.304E+03
    NO
    NO NO2
       0.2E+03
       0.2E+03   0.4E+03
     0.300E+02
     0.300E+02 0.460E+02
       ****  METEOROLOGY INPUT  STARTS ****
    FRONT END MET INPUT TEST.
             1
             2
             2
     0.300E+01 0..400E+01
     0.800E+03 0.100E+04
             2
     0.100E+03 0.150E+02
     0.250E+03 0.300E+02
   EXHIBIT A-5. Example of a "carbon copy" file, RPMCC.IN, created by the front
   end program.  This file can be reused to generate input file to RPM-IV.
9I124r2.13
                                   A-32
-------
     **** START INPUT VERTICAL DISPERSION PARAMETERS'
              2
      0.100E+03 0.125E+04
      0.250E+03 0.130E+04
              1
           800.         5
      **** START INPUT PHOTOLYSIS PARAMETERS ****
              T
              T
              1
              8
              9
             14
             23
             34
             38
             39
             45
             76
             84
              1
      0.800E+03 0.298E-4-03
              1
      0.100E+04
              T
    TEST
      0.100E+01
    N02
      0.125E-01
    NO
      0.100E-01
    O3
      0.400E-01
    CO
     0.100E+01
    ETH .
     6.850E-02
    OLE
     0.500E-02
    ALD2
     0.200E-02
    FORM
     0.300E-02
    TOL
     0.300E-02
    XYL
     0.160E-02
    PAR
     0.250E+00
    ISOP
     0.250E-04
    CRES
     0.100E-02
          '   2
             0
             1
             2
   NO
   NO2
25
50
91124r2.I3
                            EXHIBIT A-5.  Concluded.

                                   A-33
-------
 RPM-IV: FRONT END PROGRAM TEST
    6   0
  0.600E+02
  0.100E+03 0.100E+04
  O.OOOE+00 0.144E+04
  0.400E+01 0
  l.OOOE-16 1
100E+01
OOOE-16 l.OOOS+01
 34.100     8.000
    118.000
    3   3
  0.100E+03 0.500E+03 0.100E+04
  CARBON BOND MECHANISM VERSION
   95  34   0
 NO2
 O
 O3   NO
 O    NO2
 O    NO2
 O    NO
 NO2  O3
 O3
 O3
 O1D
 O1D  H20
 03   OH
 O3   HO2
 NO3
 NO3  NO
 N03  N02
 NO3  NO2
 N2O5 H2O
 N2O5
 NO   NO
 NO   NO2  H2O
 NO   OH
 HNO2
 OH   HNO2
 HNO2 HNO2
 NO2  OH
 OH   HNO3
 HO2  NO
 HO2  NO2
 PNA
 OH   PNA
 HO2  HO2
 HO2  HO2  H2O
 H2O2
 OH   H2O2
 OH   CO
 FORM OH
 FORM
.FORM
 FORM O
 FORM NO3
 ALD2 O
 ALD2 OH
 ALD2 N03
 ALD2
 C2O3 NO
 C203 N02
 PAN
 C2O3 C2O3
 C2O3  HO2
 OH
5.000E-03 5.000E-03
  300.0001990   7  15
                  IV, MAY 1991	FRONT END CHEMISTRY TEST.
1 14
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
1.
1.
0.89
2.
1.
1.
• 2.
1.
2.
2.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
1.
1. •
1.
2.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
0.79
1.

NO 1.
O3
NO2
NO
NO3
NO2
NO3
0
O1D
0
OH
H02
OH
N02 0.89
NO2
NO 1.
N2O5
HNO3
NO3 1.
NO2
HNO2
HNO2
NO 1.
NO2
NO 1.
HNO3
NO3
OH 1.
PNA
H02 1.
N02
H2O2
H2O2
OH
HO2
HO2
HO2 1.
HO2 1.
CO
OH 1.
HN031.
C2031.
C2O3
C2O31.
FORM2.
FORM1.
PAN
C2O31.
FORM2.
FORMO . 79
FORM1.

O






•





O 0 . 11 NO

NO2


NO2



OH

NO2


NO2

NO2


*>



CO.
CO

HO2 1. CO
HO2 1. CO
OH

HNO3
HO2 1. CO 1.
NO2 1. HO2 1.

NO2
XO2 2. HO2
X02 0.79 H02 0.79
XO2 1. HO2
                                          XO2
                                          XQ2
                                          OH
                              1
                              4
                              2
                              1
                              2
                              2
                              4
                              5
                              1
                              4
                              3
                              1
                              3
                              3
                              4
                              5
                              1.
                              1.
                              2.
                              1.
                              1.
                              9.
                              1.
                              9.
                              1.
                              1.
                              2.
                              1.
                              2.
                              5.
                              6.
                              4.
                              2.
                              1.
                              2.
                              3.
                              1.
                              1.
                              1.
                              2.
                              9.
                              6.
                              2.
                              3.
                              1.
                              2.
                              1.
                              2.
                              3.
                              9.
                              2.
.OOOE+00
.323E+06
.664E+01
.375E+04
.309E+03
.438E+03
.731E-02
.300E-02
.OOOE+00
.246E+05
.260E+00
.OOOE+02
.OOOE+00
.390E+01
.416E+04
.901E-01
.853E+03
.900E-06
.776E+00
.539E-04
.600E-11
.799E+03
.975E-01
.770E+03
.500E-05
.682E+04
.179E+02
.227E+04
.025E+03
.115E+00
. 833E+03
.144E+03
.181E-01
.890E-01
.520E+03
.220E+02
 500E+04
 OOOE+00
 OOOE+00
 370E+02
 300E-01
 360E+02
 400E+04-
 700E+00
 OOOE+00
 815E+04
 374E+04-
 540E-02
 700E+03
 600E+03
 100E+01
 O.OOOE+00
-1.175E+03
 1.370E+03
 O.OOOE+00
-6.870E+02
-6.020E+02
 2.450E+02
 O.OOOE+00
 O.OOOE+00
-3.900E+02
 O.OOOE+00
 9.400S+02
 5.800E+02
 O.OOOE+00
-2.500E+02
 1.230E+03
-2.560E+02
 O.OOOE+00
 1.090E+04
-5.300E+02
 O.OOOE+00
-8.060E+02
 O.OOOE+00
 O.OOOE+00
 O.OOOE+00
-7.130E+02
-l.OOOE+03
-2.400E+02
-7.490E+02
 1.012E+04
-3.800E+02
-1.150E+03
-5.800E+03
 O.OOOE+00
 1.870E+02
 O.OOOE+00
 O.OOOE+00
•O.OOOE+00
 O.OOOE+00
 1.550E+03
 O.OOOE+00
 9.860E+02
 2.500E+02
 O.OOOE+00
 O.OOOE+00
   800E+02
   800E+02
 1.350E+04
 O.OOOE+00
 O.OOOE+00
 1.710E+03
EXHIBIT A-6.  Example of final output file, RPM.DST, to be used in input file to RPM-IVSS.

9I124r2.5l                            A-34
-------
  PAR
  PAR
  ROR
  ROR
  ROR
  ROR
  0
  O
  OH
  OH
  03
  O3
  NO3
  NO3
  0
  O
  OH
  03
  TOL
  TO2
  TO2
  OH
  CRES  NO3
  CRO  N02
  OPEN
  OPEN  OH
  OPEN  OH
  OPEN  O3
  OPEN  O3
  OH   XYL
  OH   XYL
  OH   MGLY
  MGLY
 OH
 OH
 NO2
 OLE
 OLE
 OLE
 OLE
 OLE
 OLE
 OLE
 OLE
 ETH
 ETH
 ETH
 ETH
 OH
 NO

 CRES
 O
 O
 OH
 OH
 03
 O3
 NO3
 XO2
 XO2
ISOP
ISOP
ISOP
ISOP
ISOP
ISOP
ISOP
NO
XO2
 XO2N NO
 XO2  HO2
  0.305E+03
 TRAC
 TEST
 NO2
 NO
 03
 CO
 ETH
 OLE
 ALD2
 FORM
 TOL
 XYL
 PAR
 ISOP
 PAN
 HO2
 O
 N2O5
 H202
 HN02
 01D
 PNA
 l.OOOE+00 1
 l.OOOE+00 1
 3.OOOE-03 1
 1.120E-03 1
 6.340E-02 1
 2.000E-01 1
 4.640E-04 1
 1.420E-04 1
 5.600E-04 1
 1.800E-03 1
 1.330E-04 1
 4.850E-05 1
 1.250E-02 1
 3.050E-05 1
 O.OOOE+00 1
 O.OOOE-fOO 1
 O.OOOE+00
 O.OOOE+00
 O.OOOE+00  1
1.74 XO2 0.26
-0.22 PAR 1.52
1.92 XO2 2.2
0.08 XO2N0.04
XO2N0.22
ROR
ALD21.88
ROR
H02 0.22
HO2 -4.2
ALD2 6.015E-KJ2 O.OOOS*CO
6 . 015B+O2 O . OOOB+QO
PAR 6.855E+04 8.000E+03
6.855E+04 8.000E+03

1
0
2
1
0
1
2
2
1
1
0
0
1
0
1
1,
2,
2
A i
0.
1.
1.
2.
1.
1.
1.
1.
2.
2.
2.
0.
i
A »
.'



.26
.4
!o
.66
.82
.44
.9
.4

'.Of
,38
.4
2
2
0
2





ALD20
FORMO
FORM2
.76
..04
ALD21.48
CO 0.88
XO2 2.
N02 -2.
FORM3.4
XO2 1
FORMO
HO2 0
NO2 0
CRES1
CRO 0
CRO 1
C2031 ,
X02 4.
ALD21.
CO 0.
HO2 1.
PAR 0.
X02 1.
C2031.
HO2 1.
CO 0.
X02 2.
ETH 0.
FORMO.
PAR 0.
WO?




.56
.42
.08
.9
.6
•

.24
,16
,0
6
6
90
8
8
12





H02 0
XO2NO
ALD2-
FORMO
H02 -
FORMO
PAR
HO2 2
FORMO
CO 0
X02 0
HO2 0
HO2
X02 0
HNO3
HO2 1
CO 4,
C2031,
OH 1.
XO2 0.
TO2
C2O3
HO2 1.
ALD21.
ETH 1.
FORM1.
MGLYO .
ALD21.
CO 0.





.56
.44
2.
.44
2.
.18
.22
.12
.36
.9
.6

.4
.52
,4
10
8
34
4
10
38





X02
"- PAR
PAR
0.6
0.4
2.
XO2 0.2
PAR
X02N2 .
CO 1.4
ALD21.
HO2
CRES0.56
OPEN
H02 0.3
CO
HO2
2.
FORMO . 06
HO2 0.4
CRES1 . 6
CO
OLE 1.0
PAR
HO2 0.26
C2030.4
ETH 0.4
H02 0.2










CO
OH
XO2
OH
ALD2
X02
HO2
TO2
OPEN
C203
XO2
MGLY
MGLY
XO2
XO2N
ALO2
MGLY
OH





9.545E+04 O.OOOE+00
2.200E+04
2.960E+03
2.960E+03
2.100E+04
2
9
9
5
5
5
5
1
2
9
1
2
6
3
2
8
2
2,
7,
7,
1,
1.
2.
8.
1.
1.
7.
7.
9.
9.
4.
1.
2.
1.
8.
O.OOOE+00
3.240E+02
3.240E+02
-5.040E+02
. 100S+04 -5 . 040E+02
.OOOE-03 2.105E+03
.OOOE-03 2.105E+03
.675E+00 O.OOOE+00
.675E+00 O.OOOE+00
.400E+02 7.920E+02
.400E+02 7.920E+02
.192E+04-4.110E+02
.702E-03 2.633E+03
.150E+03-3.220E+02
.200E+04 O.OOOE+00
.500E+02 O.OOOE+00
.100E+04 O.OOOE+00
.250E+04 O.OOOE+00
. OOOE+04
.400E+00
.200E+04
O.OOOE+00
O.OOOE+00
O.OOOE+00
.200E+04 O.OOOE+00
.500E-03 5.000E+02
.500E-03 5.000E+02
, 810E+04 -1 . 160E+02
810E+04-1.160E+02
600E+04 O.OOOE+00
960E+00 O.OOOE+00
350E+04 O.OOOE+00
350E+04 O.OOOE+00
100E+04 O.OOOE+00
100E+04 O.OOOE+00
OOOE-03 O.OOOE+00
OOOE-03 O.OOOE+00
700E+02
200E+04
OOOE+03-
OOOE+03
896E+03-
O.OOOE+00
O.OOOE+00
1.300E+03
O.OOOE+00
1.300E+03
 O.OOOE+00
 O.OOOE+00
O.OOOE+00  1
91124r2.51
                         EXHIBIT A-6. Continued.

                             A-35
-------
C2O3
ROR
NO3
HNO3
OH
TO2
CRES
OPEN
MGLY
XO2
XO2N
CRO
H2O
0
0
0
0
0
0
1
0
0
0
0
0
2
.OOOE+00
.OOOE+00
.OOOE+00
.OOOE+00
.OOOE+00
.OOOE+00
.940E-05
.OOOE+00
.OOOE+00
.OOOE+00
.OOOE+00
.OOOE+00
.OOOE+04
1
1
1
1
1
1
1
1
1
1
1
1
1
RPM-IV EMISSION INPUT:POWER PLANTS
   2
   2   2  '
 0.100E+03  0.500E+01  0.200E+02  0.422E+03  0.29SE+03
NO

NO
NO2-
        0.   1
          200.
      100.   2
          200.
          400.
                                   303.
                            304.
                 L     1000.
                     30.
                 L     1000.
                     30.
                     46.
RPM-IV METEOROLOGICAL INPUT: FRONT END MET INPUT TEST.
 1121
 0.300E+01 0.800E+03  0.400E+01  0.100E+04
   2
 0.100E+03 0.150E+02  0.250E+03  0.300E+02
   2
 0.100E+03 0.125E+04  0.250E+03  0.130E+04
   1
      800.         5
         T
         T
   1
   8
   9
  14
  23
  34
  38 .
  39
  45
  76
  84
   1
      800.
                298.
     1000.
TEST  1.OOOE+00
      1.250E-02
NO2
NO
03
CO
ETH
OLE
ALD2
FORM
TOL
XYL
PAR
ISOP
CRES
 2 0
      l.OOOE-02
          1.OOOE+00 1.OOOE+00 1.OOOE+00
          1.250E-02 1.250E-02 1.250E-02
          l.OOOE-02 l.OOOE-02 l.OOOE-02
      4.000E-02 4.000E-02 4.000E-02 4.000E-02
      1.OOOE+00 1.OOOE+00 1.OOOE+00 1.OOOE+00
      8.500E-03 8.500E-03 8.500E-03 8.SOOE-03
      5.000E-03 5.000E-03 5.000E-03 5.000E-03
      2.000E-03
      3.000E-03
                                    3.000E-03
                                    1.600E-03
          2
          3
3.000E-03 3.000E-03
                  OOOE-03 2.000E-03 2.000E-03
                  OOOE-03 3.OOOE-03 3.OOOE-03
                            OOOE-03
                            600E-03
      2.500E-01 2.500E-01 2.500E-01 2.500E-01
      2.500E-OS 2.500E-05 2.500E-05 2.500E-05
1.600E-03 1.600E-03
3.
1.
      1.OOOE-03
     1 2
          1.OOOE-03 1.OOOE-03 1.OOOE-03
NO  25NO2 50
91124r2.51
                               EXHIBIT A-6.  Concluded.

                                    A-36
-------
           FRONT END PROGRAM TEST
                    3              •         "->.
            T
                    6
            T
            0.600E+02
            0.100E+03
            0.100E+04
            O.OOOE+00
            0.240E+02
            0.400E+01
            0.100E+01
            0.100E-15
            0.100E-15
            0.100E+02
            0.500E-02
            0.500E-02
            0.118E+03
            0.341E+02
            0.800E+01
              300.000
                 1990
                    7
                   15
                    1
            F
                    3
                    3
            0.100E+03 0.500E+03 0.100E+04
           T
               ***  CHEMISTRY INPUT STARTS:  ***
          FRONT END CHEMISTRY TEST
           0.305E+03
               T
               ***  EMISSION INPUT STARTS ***
          POWER PLANTS
           0.100E+03
           0.500E+01
           0.200E+02
             422E+03
             298E+03
           O.OOOE+00 0.100E+03
             1   2
             1   1
           0.100E+04 0.100E+04
           0.303E+03 0.304E+03
          NO
          NO  NO2
             0.2E+03
             0.2E+03   0.4E+03
           0.300E+02
           0.300E+02 0.460E-I-02
             **** METEOROLOGY INPUT STARTS ****
          FRONT END MET INPUT TEST.
                   1
                   2
                   2
           0.300E+01 0.400E+01
           0.800E+03 0.100E+04
                   2
           0.100E+03 0.15QE+02
           0.250E+03 0.3QOE+02
91J24r2.52
         EXHIBIT A-7. Example of a "carbon copy" file, RPMCC.IN, created by the front
         end program.  This file can be re-used to generate input file to RPM-IVSS.

                                  A-37
-------
          **** START INPUT VERTICAL DISPERSION PARAMETERS:
                   2
           0.100E+03 0.125E+04
           0.250E+03 0.130E+04
                   1
                800.         5
           **** START INPDT PHOTOLYSIS PARAMETERS ****
                   T
                   T
                   1
                   8
                   9
                  14
                  23
                  34
                  38
                  39
                  45
                  76
                  84
                   1
           0.800E+03 0.298E+03
                   1
           0.100E+04
                   F
          TEST
           0.100E+01
          NO2
           0.125E-01
          NO
           0.100E-01
          03
           0.400E-01
          CO                            '
           0.100E+01
          ETH
           0.850E-02
          OLE
           O.SOOE-02
          ALD2
           0.200E-02
          FORM
           0.300E-02
          TOL
           0.300E-02
          XYL
           0.160E-02
          PAR
           0.250E+00
          ISOP
           0.250E-04
          CRES
           0.100E-02
                   2
                   0
                   1
                   2
         NO
         NO2
25
50
                               EXHIBIT A-7.  Concluded.
9U24r2.52
                                  A-38
-------
                               Appendix B




            THE ROM-RPM AND UAM-RPM INTERFACE SOFTWARE
91124r2.10
-------

-------
    Gridded data produced by the Regional Oxidant Model (ROM) or the Urban Airshed
    Model (UAM) can be converted to the format of the RPM-IV (or RPM-IVSS) input file
    RPM.IN through the interface programs ROM-RPM and UAM-RPM.  Since the interface
    programs convert the outputs from regional-scale grid model simulations to input for a
    Lagrangian dispersion model, the file RPM.IN should be carefully inspected before
    proceeding with the RPM simulation.  Several parameters in RPM.IN, especially those
    regarding output options, have default values in the interface program. These can be
    easily changed hi RPM.IN to suit an application after running the interface program.
    Some other variables in the RPM.IN file generated by the interface programs are defined
    in the interface programs' ran specification file, INTFLE.IN.
    DEFAULTS

    Both the ROM and UAM interface programs have the following default conditions.

    The 1991 Carbon Bond Mechanism IV is the default chemistry mechanism. This default
    chemistry can be modified by changing the values of variables representing reaction
    sequence numbers,  total reaction numbers, reaction rate constants, corresponding
    activation energies, reactant and product  species, etc., in the subroutines BLKDTAOOO
    and DEFAULT.

    The interface programs assume that the user wants the RPM model to automatically
    calculate photolysis rates  according to the time and location calculated by the model.
    Photolytic reaction rates that change with user-specified time and zenith angles can be
    specified in the RPM.IN file.

    The following variables defined in subroutine DEFAULT may be modified by the user
    either in the subroutine or in the RPM.IN file created by the interface programs.
          TSTEP

          NSET


          MSPEC

          TZ
Estimated length of the time step for the model run (in minutes).
Number of time intervals to update the RPM plume width, plume
depth, and ambient concentrations.
Array of names of the flowing species.

Tune zone of the simulation area (see Section 3).
   The following variables are used to control RPM simulations but are not used by the
   interface program (see Section 3 for their definitions).  All of these variables are given
   default values in DEFAULT.
91124r2.10
                                        B-l
-------
          MODE1
          ISAVE
          HMIN
          CNTCOM
          NDIF
          NFLAG
          LDFLT
          IPKENT
MODE2
TINCR1
HMAX
CHMCOM
NSTS
SRCCOM
KPHOT
B1AXC
MODE3
FACTOR
EPS
NFLW
NUNC
METCOM
NSPEC
ISPEC
HALF
HSTART
TOL
NRXN
NINRT
UPHOT
IPLOT
IFORD
    The starting location of a simulation is specified by the variable XBEG, which is defined
    in the input specification file (INTFCE.IN) of the interface programs. This location
    should be a short distance (e.g., 100 m) downwind from the source instead of exactly at
    the stack location to reduce the initial concentration in the plume.  The interface program
    will advance the plume to this location before calculating any plume parameters, such as
    plume width, plume depth, and ambient concentrations.  If XBEG is zero, the interface
    program will automatically reset it to 100.0 meters.
    DETERMINATION OF PLUME LOCATIONS

    The RPM does not need to know the plume location in UTM coordinates or in
    latitude/longitude as the plume travels downwind.  However, the interface program needs
    that information to find appropriate ambient concentrations and temperatures from ROM
    or UAM.  The locations of the plume are determined by the user-specified initial location
    and then by advancing the plume along a trajectory defined by the wind speeds and
    directions obtained from ROM or UAM wind data.

    RPM calculates plume downwind distances by interpolating input wind speeds according
    to time intervals determined by the numerical integration scheme for the chemistry (i.e.,
    CBM-IV). Since these time intervals are not known in advance of running the RPM, the
    user must provide a best estimate of the intervals and input, its value as TSTEP in module
    DEFAULT.  This may create discrepancies in downwind distances calculated by the
    interface program and RPM. To achieve the optimal agreement between the two, the
    interface program should use a time interval that is 'most likely' to be used by RPM to
    obtain plume locations and downwind distances. The default value is currently two
    minutes.  Since both ROM and UAM wind data are output on an hourly basis, the
    interface program has to interpolate the hourly wind data to two-minute intervals.


    THE ROM-RPM INTERFACE

    The ROM-RPM interface program uses ROM output data to create an input file for
    RPM-IV.  The ROM output data base can be accessed through a menu-driven data
    retrieval program in the Gridded Model Information Support System (EPA, 1991) on the
    EPA National Computer Center's IBM (NCC-IBM) 9000 computer system in Research
    Triangle Park, North Carolina.  That retrieval program was specially designed to extract
    ROM output data for UAM simulation.  User-specified information about the UAM
91124r2.10
                                      B-2
-------
            fl?™* 1S emp°yed by ^ retrieval P"*1*"1 to ^omatically
            the specific ROM outputs needed.  The retrieved input data files will then contain
                            timeSandarea-  ^eROM-^ interface program uses those
     t       n        "OH? °f ** maj°r subroutines of to ROM-RPM interface program and
     their relationships. Most of the ROM data files are read by ROMIN; gridded
     concentrations and temperatures are read by GETCONC and GETIMP respectively  The
     ™SS%?- T? *" ""^ 'mm ******* fte (RPM.IN). ThelSLutine
     PLUMECAL calculates variables that define the evolution of the plume (with time) e g
     downwind distances, plume width and depth, and current plume position in UTM
     coordinates.
     Stability Calculation
     Positioning the Plume in the Vertical in ROM

     The vertical position of a plume in ROM is determined straightforwardly by advecting the
     plume center  with vertical wind velocities.   However, vertical wind velocities arT
     generally not  very reliable.  Therefore, we adopted an experimental approach  by
     Schulman and Sore (1980) for adjusting the plume height above ground-
                   ff(t + A*)= H0  - (1 - Cr)  x  {minimum^ T(t
    where
          H(t + A?) = height at plume center at time t"+ A/.
                 //o = effective stack height
          T(t + A/) = terrain height at plume position at time t +
                 TQ = terrain height at stack base.
                 CT = height adjustment coefficient.
                          F
                                                        Agones A, B, C and D and
    This height of the center of the plume is then compared with ROM layer heights at that
    specific hour to decide in which ROM layer the plume center is located  ThL  ROM
    wind speeds concentrations, and temperatures at that layer are extoSed from die
                     «
-------
         MAIN
       PLUMECAL
         ROM1N  J)
f
v-
       GETCONC)
    c
    GETTMP
    c
     MAIN
        RPM.IN
                                 (Ml)  Get default values
                                 (M2)  Get input values
                                 (M3)  Determine how many hours of GMISS
                                       data to read
                                 (PI)   Calculate wind speed, downwind
                                       distances, plume width, plume depth
                                 (P2)   Call every hour throughout RPM
                                       simulation period
                                 (P3)   Determine ambient concentrations of the
                                       plume at the present hour
(Rl)  Skip headers of all UAM files; get to.
      the time when RPM simulation is
      planned to start.
(R2)  Read one hour of UAM data of layer
      heights, winds, cloud fractions, and
      concentrations
                                 (GC)  Get boundary concentrations at the left:
                                       and right edge of the plume from UAM
                                       (gridded) concentrations.
                                     (GT)  Get temperature readings at boundaries
                                           of the plume
                                     (M4) Interpolate hourly values of plume
                                           width, plume depth, wind speeds as
                                           well as ambient concentrations to get
                                           their values at the times to update RPM
                                           input values.
                                     (M5) Finish creating RPM.IN
FIGURE B-l.  Structure and function of major subroutines in the ROM-RPM
interface program.
                                   B-4
-------
     Input and Output Mies
                    iDterfaCe Pr0gram reads fa one mput Parameter ffle and nine GMISS
     output files. Icreates one output ffle for RPM-IV (or RPM-IVSS).  A flow chart of the
     entire process ^shown in FigureB-2.  To run the ROM-RPM interfaceprogramme

     l^hi  ^^^ S6*6 ?6 *** Parameter me (refer to Table B-J ^ structure and
     variable definition).  Next, the user needs to modify the JCL ffle.  Exhibit B-l shows a
     53101)6  J^^COntn>1 "" "OM'MM job. After the job finishes successfully the user
     can run RPM-IV (or RPM-IVSS) with the created output file.

     The 11  files used in the ROM-RPM interface program are:
           Filel
           File 2
           File3
          File 4
          FileS
          File 6
          File?
          FileS
          File 9
         File 10
         File 11
 The input parameter ffle ONTFLE.IN).  Refer to Table B-l for
 more detail.  (Unit 3 in the ROM-RPM program)

 PF115 ffle (layer 1 wind fields) from GMISS output
 (Unit 7 in the ROM-RPM program)

 PF114 ffle (layer 2 wind fields) from GMISS output
 (Unit 8 in the ROM-RPM program)

 PF119 ffle (terrain elevation) from GMISS output.
 (Unit 9 in the ROM-RPM program)

 MF165 file (layer 1-2 interface) from GMISS output
 (Unit 10 in the ROM-RPM program)

 MF166 file (layer 2-3 interface) from GMISS output
 (Unit 11  in the ROM-RPM program)

 MF174 file (layer 1 water vapor) from GMISS output
 (Unit 13  in the ROM-RPM program)

 PF117 file (cloud fraction) from GMISS output.
 (Unit 14 in the ROM-RPM program)

 ROM21 file (ROM species concentration) from GMISS output
 (Unit 15 in the ROM-RPM program)

PF102 file (vertical air profile) from GMISS output
(Unit 16 in the ROM-RPM program)
                                     Wi!1.beuused M the mPut ffle to RPM-IV (or
                     RPM-IVSS). (Unit 4 in the ROM-RPM program)
91124r2.10
                                     B-5
-------
                                                 c
ROM-RPM
                                                        i
                                                User prepares input file
                                                  (refer to Table B-l
                                                   and Exhibit B-3)
                                                        1
                                     User sets up JCUrunstream with:
                                     UnitS - input file to UAM-RPM interface program
                                     Unit 4 -output file from UAM-RPM, to be used as
                                            input file to RPM-IV/RPM-IVSS
                                     Unit? -GMISSoutputPFl 15 file •
                                     UnitS -GMISS output PFl 14 file
                                     Unit 9 -GMISS output PFl 19 file
                                     Unit 10 - GMISS output MF165 file
                                     Unit 11 - GMISS output MF166 file
                                     Unit 13 - GMISS output MF174 file
                                     Unit 14 - GMISS output PFl 17 file
                                     Unit 15 - GMISS output ROM21 file
                                     Unit 16 - GMISS output PF102 file
                                     (refer to Table B-l, Exhibit B-l, B-3)
                     JCL/Runstream
                      or Input Data
                         error
                                           UAM-RPM program writes
                                           out one file (unit 4). To be
                                           used as input file to
                                           RPM-IV/RPM-IVSS
                                           (refer to Exhibit B-2, B-4)
                                                   RunRPM-IV
                                                  orRPM-IVSS
FIGURE B-2. Sequence of operations in the ROM-RPM interface program.
                                 B-6
-------
     Test Run

     The ROM-RPM interface has been tested on both the EPA National Computer Center's
     ffiM 9000 computer and a Multiflow TRACE/14/300 computer. The test case data were
     drawn from the Regional Ozone Modeling for Northeast Transport (ROMNET) program
                    northeastem U'S-  Our test ran used meteorological data from July 21,'
     Exhibit B-l shows the JCL used in generating the input file to RPM-IV through the
     ROM-RPM interface program . Exhibit B-2 shows the log file for the test run
     conducted on the EPA NCC-IBM  9000 machine.  Exhibit B-3 shows the input parameter
     file used in this run. The output file from ROM-RPM interface program (input file to
     RPM-IV) is shown in Exhibit B-4. Exhibit B-5 very briefly shows part of the input data
     files (first 100 records) used for the test run.  The data in these files were extracted from
     the output data of ROM using GMISS.
    THE UAM-RPM INTERFACE
                   mterface Proiram uses output data from UAM to create an input file for
           The structure of this interface is very similar to that of the ROM-RPM interface'
    The only difference is that this interface uses the subroutine GETLEVEL to obtain both'
    the UAM vertical layer index and the ambient temperature where the plume center is
    located.                                                    .
    Stability Calculation

    The UAM stores hourly exposure class information in the input file METSCALAR  This
    mformation is directly used by the front end program to obtain stability classes at each
    Positioning the Plume in the Vertical in UAM

    Since the UAM has gridded surface temperature as input data, those values are used
    together with temperature gradients from the METSCALAR file, to obtain a horizontal
    distribution of the temperature field. By conservation of thennodynamic energy and
    hydrostatic approximation, we then can obtain a vertical wind speed by assuming that
    diabatic heating is negligibly small. This vertical wind speed is used to advect the plume
        All exhibits will be found at the end of this appendix.
91124r2.10
                                        B-7
-------
    to the vertical location of the next hour.
    Input files

    The UAM-RPM interface program reads in one input parameter file and six Urban
    Airshed Model (UAM) files. It creates one input file for RPM-IV (or RPM-IVSS). A
    flow chart of the entire process is shown in Figure B-3.  As in the ROM-RPM interface
    program, the user is first asked to create the input parameter file (refer to Table B-2 for
    structure and variable definition).  Then the user needs to modify the JCL file. After the
    successful completion of the job, the user can run RPM-IV (or RPM-IVSS) with the
    created output file.

    The eight files used in the UAM-RPM interface program are:

         File 1       The input parameter file. Refer to Table B-2 for more detail.
                      (Unit 3 in the UAM-RPM program)

         File 2       Binary file from the UAM input file WIND.
                      (Unit 7 in the UAM-RPM program)

         File 3       Binary file from the UAM input file DIFFBREAK.  '
                      (Unit 8 in the UAM-RPM program)

         File 4       Binary file from the UAM input file METSCALARS.
                      (Unit 9 in the UAM-RPM program)

         File 5       Binary file from UAM input file TEMPERATUR.
                      (Unit 10 in the UAM-RPM program)

         File 6       Binary file from UAM output file AVERAGE.
                      (Unit 11 in the UAM-RPM program)
                                                          •        &
         File 7       Binary file from UAM input file REGIONTOP.
                      (Unit 12 in the UAM-RPM program)

         File 8        Output file.   This will be used as the input file to RPM-IV (or
                      RPM-IVSS). (Unit 4 in the UAM-RPM program)
   Test Run

   The UAM-RPM interface program has been tested on both the EPA National Computer
   Center's ffiM-9000 computer and a Multiflow TRACE/14/300 computer.  The test data
9U24r2.10
                                     B-8

-------
                                                                        c
UAM-RPM
                                                                        User prepares input file
                                                                         (refer to Table B-2
                                                                          and Exhibit B-8)
                                                                               i
                                                            User sets up JCLfrunstream with:
                                                            Units  -input file to UAM-RPM interface program
                                                            Unit4  -ouiput file from UAM-RPM, to be used as
                                                                    input file to RPM-IV/RPM-IVSS
                                                            Unit?  - Binary UAM wind file
                                                            UnitS  -Binary UAM diffusion break file
                                                            Unit 9  - Binary UAM metscalais file
                                                            Unit 10 - Binary UAM temperature file
                                                            Unit 11 - Binary UAM average file
                                                            Unit 12 - Binary UAM regiontop file
                                                            (refer to Table B-2, Exhibit B-6, B-9)
                                           JCL/Runstream
                                            or Input Data
                                               error
                                                                   UAM-RPM program writes
                                                                   out one file (unit 4). To be
                                                                      used as input file to
                                                                     RPM-IV/RPM-IVSS
                                                                   (refer to Exhibit B-7, B-9)
                                                                         Run RPM-IV
                                                                         orRPM-IVSS
                            FIGURE B-3. Sequence of operations in the UAM-RPM interface
                                                                                           program.
ee\91124.002
                                                        B-9
-------
    were drawn from EPA's UAM test base case for the Atlanta, June 3-4, 1984. For more
    information on the UAM Atlanta simulations (EPA, 1990).

    The JCL for the test ran in shown in Exhibit B-6.  Exhibit B-7 is the log file of the test
    run on the NCC IBM-9000 machine. Exhibit B-8 shows the input file (ENTFCE.IN) used
    in the test ran. Exhibit B-9 shows the output file used as input to RPM-IV.  Exhibit B-10
    shows a small part of the ASCII version of the input files used in this test ran.

    Exhibit B-7 includes a warning message because the plume approached the edge of the
    modeling domain. If the test ran were continued, the plume might eventually move out
    of the domain and the ran would terminate.   The user can correct this problem either by
    adjusting the UTM coordinates or by increasing the model domain size to contain as
    much information as desired.
   NOTES TO USERS

   The structure of the input files (INTFC.IN) for the ROM-RPM and UAM-RPM interface
   programs is shown in Tables B-l and B-2 (at the end of the appendix).  Some of the
   variables listed are not currently used, e.g., DELTAX, DELTAY, NX, NY,  but are
   there for future program development. The variables FNAME1 - FNAME9 are not
   necessary on an IBM mainframe machine since JCL files control the opening of the input
   and output files.

   Users of the IBM mainframe should take special care to create the input parameter file.
   All input values should be right justified according to their format requirements; if they
   are not, the IBM mainframe will automatically append zeros to the end of the data. This
   error may not cause the job to abort, yet it will lead to errorneous results.

   Since RPM-IV currently uses  only one ambient concentration at each update time,
   whereas RPM-IVSS takes four (left, right, top, bottom) at each time step, it is necessary
   before  running the interface program to specify which version of RPM is to be used.
   This is controlled by variable  LGEAR in line 1 of INTFCE.IN.

   Before running the interface program, users should make sure that the stack (from which
   the plume is emitted) is within the ROM or UAM domain and that the plume will stay
   within the domain during its trajectory.  A warning message will be printed when the
   plume approaches domain edges. Once the plume moves out of the domain, the interface
   program may terminate for lack of enough ROM/UAM grid points to horizontally
   interpolate various parameters.

   For RPM-IV a time step of 8  to 10 minutes is common for many types of applications.
   For RPM-IVSS a value of 1 to 2 minutes is recommended if a plume-only application is
   ran. It would be sufficient to have 10 updates on  wind speed (i.e., variable NSET) in
91124r2.10
                                       B-10
-------
                                                                                 an
 each simulation.

 Some variables define dimensions of arrays used in the interface program.  The size of
 array 1S defined with Fortran PARAMETER statements at the beginning of each
 subroutine.  The dimension-setting variables are:

       IRMAX      Number of grid cells at the x-direotion in the ROM or UAM
                    domain.
       JRMAX      Number of grid cells at the y-direction in the ROM or UAM
                    domain.
       MAXPT     Number of hours in the intended RPM-IV simulation, including the
                    starting hour.
       MXFLW     Number of flowing species.
       MXSPEC     Total number of species in the chemistry mechanism.


REFERENCES

Schilling  L. L  and J. S. Scire.  1980.  "Buoyant Line and Point Source Dispersion
      Model Users Guide."  Environmental Research and Technology, Inc. (P-7304B)
      (National Technical Information Service, PB81-164642).

EPA. 1990.  User's Guide For The Urban Airshed Model  U.S.  Environmental
      Protection Agency (EPA-450/4-90-007).

EPA. 1991   Gridded Model Information Support System  (GMISS) User's Guide, Volume
      L  U.S. Environmental Protection Agency (EPA-450/4-91-009).
91124r2.10
                                       B-ll
-------
TABLE B-l. Structure and variable definitions of the input parameter file,
INTFCE.IN, of the RPM-ROM interface program. |
Line
1
2
3
4
51
6
7
8
92
103
II4
12
13
14s
15
166
17
187
19

20
21
22s
23
24
25
26
27
28
Contents
LGEAR
NCELLS,DEFNW,IOUT
XBEG, XEND, TBEG1, TEND1
ALONG, ALAT, TZ, TSTRT, NYR, NMTH, NDAY
NDIST
DIST(I),I=1,NDIST
REFTMP
NSORCS
PLROPT, ISTAB
HSTACK, DSTACK, VSTACK, TSTACK, TAMB
DSTNCE(D,NSPECS(I),IUNITS(I),PRESS(I),TEMP(I)
(NAMESP(J,I),EMRAT2(J,I),ZMOLWT(J,I),J= 1 ,NSPECS(I))
WNDOPT, HDSOPT, VDSOPT, AMBOPT
NWIDTH
XWIDTH(I),WIDTH(I),I= l.NWIDTH
NMLX
XMLX(I), DEPTHO), I=1,NMLX
HTMIX
ORGX, ORGY, ZONE1, UTMXOR, UTMYOR, DELTAX,
DELTAY
XPOSST, YPOSST
NX, NY '
FNAME1
FNAME2
FNAME3
FNAME4
FNAME5
FNAME6
FNAME7
Format |
L10
110, 2F10.3
8fl0.3
4F10.3, 314
2014
8F10.3
8F10.3
2014
2014
8F10.3
F10.3, 214, 2F10.3
A4, 1PE10;3, F10.3, 56X
2014 .
2014
8F10.3
2014
8F10.3
8E10.3
8F10.3

8F10.3
8F10.3
A80
A80
A80
A80
A80
A80
A80
                                                                                                         Continued
  Line 5 la used only if IOUT »* 1.
2 Lines 9 through 12 are used only if NSORCS ^ 0.
3 Line 10 is used only if PLROPT - 2.
4 Lines IJ and 12 are repeated for each I (I — 1, NSORCS).
5 Lines 14 and 15 are used only if HDSOPT = 1.
6 Lines 16 and 17 are used only if VDSOPT = 1.
1 Line 18 is used only if VDSOPT - 2.
4 Lines 22 through 30 are not needed for IBM mainframes.
                                                    B-12
91124r2.12
-------
TABLE B-l.
INTFCE.IN,
Line
1
2
3
4
51
6
7
8
92
103
II4
12
13
145
15
166
17
187
19

20
21
228
23
24
25
26
" 27
28
Structure and variable definitions of the input parameter file,
of the RPM-ROM interface program.
Contents
LGEAR
NCELLS,DEFNW,IOUT
XBEG, XEND, TBEG1, TEND1
ALONG, ALAT, TZ, TSTRT, NYR, NMTH, NDAY
NDIST
DIST(I),I=1,NDIST
REFTMP
NSORCS
PLROPT, ISTAB
HSTACK, DSTACK, VSTACK, TSTACK, TAMB
DSTNCE(I),NSPECS(I),IUNrrsa),PRESS(D,TEMP(I)
(NAMESP(J,I),EMRAT2(J,I),ZMOLWT(J,I),J=1,NSPECS(I))
WNDOPT, HDSOPT, VDSOPT, AMBOPT
NWIDTH
XWIDTH(I), WIDTH(I),I= 1 ,NWIDTH
NMIX
XMIX®, DEPTH®, I=1,NMIX
HTMIX
ORGX, ORGY, ZONE1, UTMXOR, UTMYOR, DELTAX
DELTAY
XPOSST, YPOSST
NX, NY
FNAME1
FNAME2 . - ;
FNAME3
FNAME4
FNAME5
FNAME6
FNAME7

Format
L10
110, 2F10.3
8fl0.3
4F10.3, 314
2014
8F10.3
8F10.3
2014
2014
8F10.3
F10.3, 214, 2F10.3
A4, 1PE10.3, F10.3, 56X
2014
2014
8F10.3
2014
8F10.3
8E10.3
8F10.3

8F10.3
8F10.3
A80
A80
A80 *
A80
A80
A80
A80
                                                                                                             Continued
   Line 5 is used only if IOUT ^ 1.
   Lines 9 through 12 are used only if NSORCS yt 0.
   Line 10 is used only if PLROPT = 2.
   Lines 11 and 12 are repeated for each I (I = 1, NSORCS).
   Lines 14 and 15 are used only if HDSOPT = 1.
   Lines 16 and 17 are used only if VDSOPT = 1.
   Line 18 is used only if VDSOPT ='2.
Q
   Lines 22 through 30 are not needed for IBM mainframes.
9II24r2.I2
                                                  B-13
-------
 TABLE B-l.  Continued.
.Variables
HSTACK
DSTACK
VSTACK
TSTACK
TAMB
DSTNCE
Definition
Stack height (m); stack diameter (m); Stack exit velocity (m/s);
stack gas exit temperature (°K); ambient temperature at stack
exit (°K)
Array of downwind distances of each point source to be
Format
Real
Real
                 injected (maximum dimension of 10)
     NSPECS     Array of number of species emitted at each point source            Integer
     lUNTTS     Array of emission rates at each point source:                      Integer
                 1 = Units are g/s
                 2 «« Units are ppm m3/s
      PRESS     Array of ambient pressure at each point source (MB).  Not           Real
              •   needed if IUNTTS = 2.
      TEMP     Array of ambient temperature at. each point source (°K). Not         Real
                 needed if IUNTTS - 2
    NAMESP    The name of each emitted species at each point source       '    Character*4
    EMRAT2    Emission rates (see variable IUNITS)                              Real
    ZMOLWT    Molecular weight of each emitted species (G). Not needed if         Real
                 IUNITS -2.                                      '
    WNDOPT    Wind input option             .                                Integer
                 1 = User-input array of wind speeds at specified times
                 2 = Not available
    HDSOPT     Horizontal dispersion option                                    Integer
                 1 — User-input array of plume widths at specified downwind
                      distances
                 2 = Plume widths are calculated by the model
    VDSOPT     Vertical dispersion option              *  '.  , .                  Integer
                 1 - User-input array of plume depths at specified downwind
                      distances                                     * .
                 2 = Plume depths are calculated by the model
    AMBOPT    Ambient concentration option                                    Integer
                 1 - User-input array of ambient concentrations at specified
                      times; ignored if MODE2 in subroutine DEFAULT =  1
    NWIDTH     Number of input plume widths                                   Integer
    XWIDTH     Downwind distances corresponding to the input plume widths        Real
                 (m) (maximum dimension of 30)
     WIDTH     Input plume widths (m) (maximum dimension of 30)                Real
     NMIX      Number of plume depths to be input                             Integer
     XMIX      Array of downwind distances corresponding to the input plume       Real
                 depths (m) (maximum dimension of 30)
     HTMDC     Maximum limit of mixing height (m).                             Real
                                                                              Continued
91124r2.12
                                            B-14
-------
   TABLE B-l.  Concluded.
Variables Definition
ORGX Relative origin of ROM domain. (Usually = 0 )
ORGY y ''
ZONE1 UTM zone of the study domain. (Both the RPM study region
and the ROM domain must be in the same UTM zone.)
SUS™ Horizontal (X) and vertical (Y) UTM coordinates of a planned
UTMYOR (rectangular) region for RPM simulation (in meters).
DELTAX Horizontal and vertical resolution of the planned RPM study
DELTAY region (in meters). Not used.
XPOSST Starting location, in UTM coordinates (m) of RPM
YPOSST simulation.
NX Number of grid cells of the planned RPM study region Not
NY used
FNAME1 ROM layer 1 horizontal wind data file (PF1 15)*
FNAME2 ROM layer 2 horizontal wind data file (PF1 14)*
FNAME3 ROM terrain data file (PF1 19)*
FNAME4 ROM layer 1 gridded height data file (MF165)*
FNAME5 ROM layer 2 gridded height data file (MF166)*
FNAME6 ROM gridded water vapor concentration in layer 1 (MF174)*
FNAME7 ROM sky-cover fraction data file (PF1 17)*
FNAME8 ROM predicted concentrations of 17 species from layer 1 2
and 3 (ROM21)* y ' '
FNAME9 ROM vertical-interpolated temperature data file (PF102)*
— — — — — — — -
Format
Real
Real
Real
Real
PAal

Integer
Character*80
Character*80
Character*80
Character*80
Character*80
Character*80
Character*80
Character*80
Character*80
* Names in parentheses are ROM data files.
                                         B-15
9U24r2.12
-------
TABLE B-2. Structure and variable definitions of the input parameter file, INTFCE.
program.
Line Contents
1 LGEAR
2 NCELLS,DEFNW,IOUT
3 XBEG, XEND, TBEG1, TEND1.
4 ALONG, ALAT, TZ, TSTRT, NYR, NMTH, NDAY
5l NDIST
6 DIST(I),I^1,NDIST
7 REFTMP
8 NSORCS
92 PLROPT, ISTAB
103 HSTACK, DSTACK, VSTACK, TSTACK, TAMB
II4 DSTNCE(I),NSPECS(I),IUN][TS(I),PRESS(I)",TEMP(I)
12 (NAMESP(J,I),EMRAT2g,I),ZMOLWT(J,I),J = 1 ,NSPECS(T))
13 WNDOPT, HDSOPT, VDSOPT, AMBOPT
145 NWIDTH
15 XWIDTH(I),WIDTH(I),I=1,NWIDTH
166 NMEX
17 XMIXO), DEPTH(I), I=1,NMIX
187 HTMIX
19 ORGX, ORGY, ZONE1, UTMXOR, UTMYOR, DELTAX,
DELTAY
20 XPOSST, YPOSST
21 NX, NY .
22s FNAME1
23 FNAME2
24 FNAME3
25 FNAME4
26 FNAME5
27 FNAME6
1 Line 5 is used only if IOUT ^ 0.
2 Lines 9 through 12 are used only if NSORCS & 0.
3 Line 10 is used only if PLROPT = 2.
4 Lines 1 1 and 12 are repeated for each I (I - 1, NSORCS).
5 Lines 14 and 15 are used only if HDSOPT - 1.
6 Lines 16 and 17 are used only if VDSOPT = 1.
7 Line 18 is used only if VDSOPT = 2.
8 Lines 22 through 27 are not needed for IBM mainframes.
B-16
9I124r2.12
IN, of the RPM-UAM interM
1
Format |
L10 ~~~" 1
110, 2F10.3 I
8fl0.3 I
4F10.3, 314 I
2014 1
8F10.3 1
8F10.3 1
2014 1
2014 1
8F10.3 •
F10.3, 214, 2F10.3 •
A4, 1PE10.3, F10.3, 56X •
2014 I
2014 I
8F10.3 1
2014 1
8F10.3 1
8E10.3 1
8F10.3 I
1
8F10.3 •
8F10.3 1
A80 1
A80 I
A80 1
A80 1
A80 1
A80 |
1








"
-------
  TABLE B-2.  Continued.
      Variables
                                          Definition
       LGEAR

      NCELLS
      DEFNW
        IOUT
       XBEG
       XEND
       TBEG1
      TEND1
      ALONG
   fc
       ALAT
        TZ

      TSTRT
    '   NYR
      NMTH
      NDAY
      NDIST

       DIST

    REFTMP

    NSORCS
    PLROPT


      ISTAB

    HSTACK
    DSTACK
    VSTACK
    TSTACK
     TAMB
    DSTNCE
  = .TRUE, when RPM-IV (Gear) is to be used;
  =.FALSE.when RPM-IVSS is to be used
  Number of cells hi the plume
  Definition of plume width (hi multiples of sigma-y)
  Output option:
  1  = output at tune interval given by TINCR1 hi subroutine
      DEFAULT
  2  = Output at user specified downwind distances
  3  = Output at both of the aboves
  Initial distance downwind of point source (meters)
  Final distance downwind of point source (meters)
  Beginning tune of simulation (mm.)
  Ending time of simulation (mm.)
  Longitude of location in degrees (or fraction thereof).  Must be
  positive for USA (i.e. east longitude)
  Latitude of location in degrees
  Time zone at location (5. = Eastern; 6. = Central; 7. =
  Mountain; 8.  = Pacific standard times).
  Starting time of simulation, in military form (4 p.m. = 1600)
 Year (e.g., 1988)
 Month of simulation (1 - 12)    •
 Starting day of simulation (1-31)
 Number of downwind distances for which output is to be
 printed
 Array of downwind distances in increasing order (maximum
 dimension of 10)
 Reference temperature (°K) for default reaction rates hi
 subroutine BLKDTA.
 Number of point sources.
 Plume rise option:
 2 = Model will calculate plume rise for the first injected
     source
 Stability in Pasquill-Gifford classes (i.e., 1 - 6 ranging from
 extremely unstable to moderately stable; '4' being neutral.
 Stack height (m); Stack diameter (m); Stack exit velocity
 (m/s); stack gas exit temperature (°K); Ambient temperature at
 stack exit (°K)
Array of downwind distances of each point source to be
injected (maximum dimension of 10)
  Format
  Logical

  Integer
   Real
  Integer
  Real
  Real
  Real
  Real
  Real

  Real
 ' Real

  Real
 Integer
 Integer
 Integer
 Integer

  Real

  Real

Integer
Integer


Integer

 Real
                                          B-17
                                                                              Real
                                                                              Continued
9ll24r2.l2
-------
 TABLE B-2. Continued.
     Variables
Definition
Format
     NSPECS     Array of number of species emitted at each point source            Integer
     IUNITS     Array of emission rates at each point source:                      Integer
                 1 = Units are g/s
                 2 « Units are ppm m3/s
     PRESS     Array of ambient pressure at each point source (mb).  Not           Real
                 needed if lUNTTS = 2.
     TEMP     Array of ambient temperature at each point source (°K) needed       Real
                "if lUNTTS = 2
    NAMESP     The name of each emitted species at each point source           Character*4
    EMRAT2     Emission rates (see variable IUNITS)                             Real
    ZMOLWT    Molecular weight of each emitted species (G).  Not needed if        Real
                 IUNITS = 2.
    WNDOPT    Wind input option                                          .   Integer
                 I = User-input array of wind speeds at specified times
                 2 = Not available
    HDSOPT     Horizontal dispersion option                                    Integer
                 1 = User-input array of plume widths at specified downwind
                     distances
                 2 = Plume widths are calculated by the model
    VDSOPT     Vertical dispersion option          ,                            Integer
                 1 = User-input array of plume depths at specified downwind
                     distances
                 2 = Plume depths are calculated by the model
    AMBOPT     Ambient concentration option                                   Integer
                 1 = User-input array of ambient concentrations at specified
                     times; ignored if MODE2  hi subroutine DEFAULT = 1
    NWIDTH     Number of input plume widths          •      .                  Integer
    XWIDTH     Downwind distances corresponding to the input plume widths         Real
                 (m) (maximum dimension of 30)
     .WIDTH     Input plume widths (m) (maximum dimension of 30)                Real
     NMIX      Number of plume depths to be input                             Integer
     XMIX      Array of downwind distances corresponding to the input plume       Real
                 depths (m)  (maximum dimension of 30)
     HTMIX     Maximum limit of mixing height (m).                             Real '
     ORGX      Relative origin of ROM domain. (Usually = 0).                    Real
     ORGY
     ZONE1     UTM zone of the study domain. (Both the RPM study region         Real
                 and the ROM domain must be in the same UTM zone.)
    UTMXOR     Horizontal (X) and vertical  (Y) UTM coordinates of a planned        Real
    UTMYOR     (rectangular) region for RPM simulation, (hi meters)	

                                                                              Continued
91124r2.12
                                          B-18
-------
  TABLE B-2.  Concluded.
Variables
DELTAX
DELTAY
XPOSST
YPOSST
NX
NY
FNAME1
FNAME2
FNAME3
FNAME4
FNAME5
FNAME6
Definition
Horizontal and vertical resolution of the planned RPM study
region (in meters). Not used.
Starting location, in UTM coordinates (meters), of RPM
simulation.
Number of grid cells of the planned RPM study region. Not
used - . .
Unformatted UAM wind input file
Unformatted UAM input file DIFFBREAK
Unformatted UAM input file METSCALAR
Unformatted UAM surface temperature input file
Unformatted UAM average concentration output file
Unformatted UAM input file REGIONTOP
Format
Real.
Real
Integer
Character*80
Character*80
Character*80
Character*80
Character*80
Character*80
91124r2.I2
                                          B-19
-------
 //ZWARRGR  JOB (RTMAAQMSP,B057),ZION,MSGCLASS=F,
 //    PRTY=<2,TIMEs(0,29),NOTIFY=ZWA,REGION=8000K
 /*ROUTE PRINT HOLD
 //*
 //*  STEP1: RPMGEAR
 //*
 //*
 //*
 //RUN   EXEC PGM=ROM2RPM
 //STEPLIB  DD DSNsZWARTMA.RPM.LOAD,DISP=SHR
 //SYSPRINT DD SYSOUTsA
 //FT06F001 DD SYSOUT^,HOLD=YES,DEST=IXDCAL, CHARS =ST12.
THIS IS THE EXECUTABLE FOR ROM-RPM INTERFACE
 II*
 II*
 II*
THE INPUT FILES  (INPUT PARAMETER FILE, GMISS FILES)
 //FT03F001 DD DSN=ZWARTMA.RPM.IN(RRGEAR),DISP=SHR
 //FT07F001 DD DSN=ZWARTMA.RPM.GMISS.PF115,DISP=SHR
 //FT08F001 DD DSN=ZWARTMA.RPM.GMISS.PF114,DISP=SHR
 //FT09F001 DD DSN=ZWARTMA.RPM.GMISS.PF119,DISPsSHR
 //FT10F001 DD DSN=ZWARTMA.RPM.GMISS ,MF165,DISP=SHR
 //FT11F001 DD DSN=ZWARTMA.RPM.GMISS.MF166,DISP=SHR
 //FT13F001 DD DSN=ZWARTMA.RPM.GMISS.MF174,DISP=SHR
 //FT14F001 DD DSN=ZWARTMA.RPM.GMISS.PF117,DISPsSHR
 //FT15F001 DD DSN=ZWARTMA.RPM.GMISS.ROM21,DISP=SHR
 //FT16F001 DD DSN=ZWARTMA.RPM.GMISS.PF102.DISP^SHR
 //*
 //*  THE OUTPUT  FILE
 //*
 //FT04F001 DD DSNsZWARTMA.RPM.OUT(RRGEAR),DISP=SHR
 //*
         B-l.  Example of JCL file for ROM-RPM interface test run on the EPA IBM
9000 computer.  This JCL generates the input file for future RPM-IV run.
                                   B-20
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EXHIBIT B-3. Example of input parameter specification file for ROM-RPM interface
test run. This file generates the input file for future RPM-IV run.
9I124r2.35
                                    B-30
-------
   RPM-II. CB-IVC1991)
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       HN03
       NO
       N02
                                  0.500E-02  0.500E-02
                                   1000.0001980   7 21
       PNA
       H02
       H02
 OH
 H02
 H02.
 PNA
 OH
 H02
 H02
 H202
 OH   H202
 OH   CO
 FORM OH
 FORM
 FORM
 FORM 0
 FORM N03
 ALD2 0
 ALD2 OH
 ALD2 N03
 ALD2
 C203 -NO
 C203 N02
 PAN
 C203 C203
 C203 H02
 OH
 PAR
 PAR
 ROR
 ROR
 ROR
 ROR
0
0
OH
OH
            H20
      OH
      OH
      N02
      OLE
      OLE
      OLE
      OLE
91124r2.36
1 13
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
1.
1.
0.89
2.
1.
1.
2.
1.
2.
2.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
1.
1.
1.
2.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
0.79
1.
1.74
-0.22
1.92
0.08
1.
1.26
0.4
2.
2.
2xamj

NO 1.
03
N02
NO
N03
N02
N03
0
010
0
OH
H02
OH
0 .












N02 0.89 0 0.11
N02
NO 1.
N205
HN03
N03 1.
N02
HN02
HN02
NO 1.
N02
NO 1.
HN03
N03
OH 1.
PNA
H02 1.
N02
H202
H202
OH
H02
H02
H02 1.
H02. 1.
CO
OH 1.
HN031.
C2031 .
C203
C2031 .
FORM2.
FORM1.
PAN
C2031 .
FORM2.
FORM0.79
FORM1.
X02 0.26
PAR 1.52
X02 2.2
X02N0.04
H02
AL020.76
FORM0.04
FORM2.
H02
>le of oi]


N02


N02



OH

N02


N02

N02






CO
CO

H02 1.
H02 1.
OH

HN03
' H02 1 .
N02 1.
N02
X02 2.
X02 0.79
X02 1.
X02N0.22
ROR
ALD21 .88
ROR

H02 0.56
X02N0.44
ALD2-2.
itput file j

1.
•4.
2.

z\
2
&•
4.
5.
1.
4.
3'.',
l.i
3 1
J • 1
NO 3.;
4 <
5,
J • "
1 I
1 • (
1 <
I • .
2,'t
1 *
i •«
1 A
1 • C
9.7
1 C
1 • 3
9.7
1.5
1 i*
1 . u
2.1
i ?
i . t
2.0
5.1
6 8
W • O
4.1
2.1
1 a
I • O
2.5;
3.2;
1 m
i . ji
"1.01
1 01
1 • Vi
CO 2.31
CO 9.3(
6 It
UD
-------
03
03
N03
N03
0
0
OH
03
TOL
T02
T02
OH
CRES
CRO
OPEN
OPEN
OPEN
OPEN
OPEN
OH
OH
OH
HGLY
0
0
OH
OH
03
03
N03
xo2
X02
X02N
X02
OLE
OLE
OLE
OLE
ETH
ETH
ETH
ETH
OH
NO

CRES
N03
N02

OH
OH
03
03
XYL
XYL
HOLY

ISO?
I SOP
1SOP
I SOP
I SOP
ISOP
I SOP
NO
X02
NO
H02


















1.
0.
1.
2.
2.
0.
1.
1.
0.
0.
1.
0.
1.

1.
2.
2.
0.
0
66
82


6


44
9

4





06
1.38















1.
2.
1.
1.
1.
1.
2.
2.
2.
0.
1.
1.



4
2


2
0



2





AL021.48
CO 0.88
X02 2.
N02 -2.
FORH3.4
OH
X02 1.56
FORM0.42
H02 0.08
N02 0.9
CRES1 .
CRO 0.6
CRO 1.

C2031.
X02 4.
FORM
AL021.24
CO 0.16
H02 1.0
PAR 0.6
X02 1.
C2031.
H02 1.6
GO 0.90
X02 2.
ETH 0.8
FORM0.8
PAR 0.12
X02N
N02



FOfiHO.44
H02 -2.
FORM0.18
PAR
H02 2.

FORM0.22
CO 0.12
X02 0.36
H02 0.9
H02
X02 0.6
HN03

H02 1.
CO 4.

C2031.4
OH 1.52
X02 0.4
T02
C203
H02 1.
ALD21.10
ETH 1.8
FORH1.34
HGLY0.4
ALD21.10
CO -0.88





X02 0.2
PAR
X02N2.

CO 1.4

ALD21 .
H02
CRES0.56
OPEN

H02 0.3


CO
H02 2.

FORH0.06
H02 0.4
CRES1.6


CO
OLE 1.0
PAR
H02 0.26
C2030.4
ETH 0.4
H02 0.2





OH 9
9
AL02 5
5
X02 5
5
H02 1
.OOOE-03
.OOOE-03
.675E+00
.675E+00
.400E+02
.400E+02
2.
2.
0.
0.
7.
7.
.192E+04-4.
2.702E-03
T02 9
1
2
OPEN 6
3
2
2.
.150E+03-3.
.200E+04
.500E+02
.100E+04
.250E+04
.OOOE+04
8.400E+00
C203 2
2
X02 7
HGLY 7
UGLY 1
1
2
8
X02 1
1
X02N 7
ALD2 7
HGLY 9
OH 9
4
1
2
1
8
.200E+04
.200E+04
.500E-03
.500E-03
0.
0.
0.
0.
0.
0.
0.
0.
5.
5.
.810E+04-1.
.810E+04-1.
.600E+04
.960E+00
.350E+04
.350E+04
.100E+04
.100E+04
.OOOE-03
.OOOE-03
.700E+02
.200E+04
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.OOOE+03-1.
.OOOE+03
0.
.896E+03-1.
105E+03
105E+03
OOOE+00
OOOE+00
920E+02
920E+02
110E+02
633E+03
220E+02
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+02
OOOE+02
160E+02
160E+02
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
300E+03
OOOE+00
300E+03
0.298E+03
TRAC
TEST
N02
NO
03
CO
ETH
OLE
ALD2
FORM
TOL
XYL
PAR
1SOP
PAN
H02
0
N205
H202
HH02
010
PNA
C203
ROR
N03
HH03
OH
T02
CRES
OPEN
HGLY
X02
X02N
CRO
H20
1 .OOOE+00
1. OOOE+00
1.488E-03
1.557E-04
9.216E-02
2.415E-01
1.049E-03
4.130E-05
1.866E-03
4.876E-03
2.705E-04
1.562E-05
3.656E-02
5.086E-06
0. OOOE+00
0. OOOE+00
0. OOOE+00
0. OOOE+00
0. OOOE+00
0. OOOE+00
0. OOOE+00
O.OOOE+00
0. OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
2.000E+04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0














































































•




































































•










































•




























































































































RPH-II. CB-IVC1991)
1
2

4


0.200E+03 0.500E+01
100.000 2
2


0
















.400E+01 0.350E+03 0.298E+03
1010.
000 300.
000





EXHIBIT B-4.  Continued.
                                     B-32
91124r2.36
-------
  NO   5.000E+03    30.000
  N02  3.000E+02    46.000
  RPM-II, CB-IV(1991) METEOROLOGICAL INPUT

    10
                     °-225E+01 0-101E+03 0.329E+01 0.200E+03 0.411E+01

                     !:?J               OJS4i*01 °-596E+03 °-159E+01
    10
    10
           °-440E+03 0-164E+05 0.725E+04 0.327E+05 0.116E+05
                             SrSES °-135M6 °-206E+05
                    0.164E+05 0.166E+04 0.327E+05 0.186E+04
                                       °-135E+06 °-538E+03
                                                                  0
                                                                  0
  T
    1
    8
    9
   14
   23
   34
   38
   39
   45
   76
   84
   10
  0.200E+01 0.304E+03 0.101E+03 0.299E+03

  !:S£S I3SS S:^^ SSES
   10
                                                         0
                                                                  0
M02

NO

03

CO

ETH

OLE
      f :
                    °-200E*°3 °-299E+03 0.398E+03.0.497E+03 0.596E+03 0.695E+03
                                  1-ooowo 1-00flwo 1-OOOE+0° 1-OOOE+0°
                                  1-635E'03 'M55E-°3 2-640E-°3 8-403E'04
                                  1'495E'04 1-82aw* 1-038E-°4
                                  1-254B-°1 1-203E-°1 1-188E-°1
                                  2'392E'01 2-39AE-°1 3-009E-°1 2-282E-°1
                                  6'466E'04 3-381E-°4 7-641E'04 3-380E-°4
                                  4-499E'05 6-257E-°5 2-902E-°4 1-725E-°4
                                  1'619E-°3 1-286E-°3 1-8Z»-05 l-126E-°3
             S-5.194E-05
          	I4 4.482E-04
ALD2  1.868E-03 1.876E-03
      2.399E-03 3.268E-03
FORM

TOL

XYL


PAR   f.'wI-O2 f'fsli-ol I'SEJf 3'124E'°2 2'821E-°2 3-795E-02 2.454E-02

ISOP  i:SS:g lijS:?? !:gg:" 2-100E'051-09ZE-°5 3-581E-°5 6-201E-°6
 4012
N02 3NO   503  OFORM 0
                        I'gg:g 4-785E-°3 2-997E-°3 3-269E-°3
                        1'SglS 1'459E-°4 1-1*-0*3.61«-04 1.072E-04
                                 7-164E-°6 2-132E-°5
EXHIBIT B-4.  Concluded.
9J 124r2.36
                                           B-33
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  //ZWARRGR  JOB (RTMAAQMSP,B0.57) , ZION,MSGCLASS=F
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  //*•  STEP!:  RPMGEAR
  //*
  //*  THIS  IS THE  EXECUTABLE  FOR ROM-RPM INTERFACE
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  //FT06F001 DD SYSOUT==A,HOLD=YES,DBST=LOCAL, CHARS=ST12

  //*  THE INPUT FILES  (INPUT  PARAMETER FILE, GMISS FILES)
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EOHBIT B-6.  Example of JCL file for UAM-RPM interface test run on the
9000 computer.  This JCL generates the input file for future RPM-IV run.
IBM
91124r2.38
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                                                                   B-47
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 .TRUE.
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EXHIBIT B-8.  Example of input parameter specification file for UAM-RPM interface
test run. This file generates the input file for future RPM-IV ran.
91124r2.40
                                     B-48
-------
   RPM-II, CB-IVO991)
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  OH   HN03          1.     N03
  H02  NO             1      OH  1
  H02  N02            1      pNA   °
  PNA                 1.     H02 1.
  OH   PNA            i.     N02
  H02  H02            1.     H202
  H02  H02  H20       1.     H202
  "202                2.    OH
 OH   H202           1.    H02
 0"   CO             1.    H02
 FORM OH             1.    H02 1.
 FORM                2.    H02 1.
 FORM                1.    co
 FORM 0              1.    OH  1.
 FORM N03             1.    HN031.
 ALD2 0              1      C2031
 ALD2 OH              ii    C203  "
 AL°2 N03             i.    C2Q31.
 A^°2                1..    FORM2.
 C203 NO              1      FORM1
 C203 N02             1[    PAN
 PAN                  1.    C2031.
 C203 C203            2.    FORM2
 C203 H02             0.79  FORMO
 OH                  1.    FORM1
 PAR  OH              1.74  X02 0
 PAR  OH              -0.22 PAR 1
 ROR                  1.92  X02 2.
 R°R                 0.08  X02NO.
 ROR                 1.    H02
 ROR  N02
0    OLE            1.26  ALD20.
0    OLE            0.4   FORMO.
OH   OLE            2.    FORM2.
OH   OLE            2.    H02
                                  0.500E-02 0.500E-02
                                   1200.0001984   6   3
                                  .89  0   0.11  Mb

                                      N02


                                      N02



                                      OH

                                      N02


                                      N02

                                      N02
                                     CO
                                     CO

                                     H02 1.
                                     H02 1.
                                     OH

                                     HN03
                                     H02 1.
                                     N02 1.
CO
CO
CO  1.
H02 1.
                                     N02
                                     X02 2.     H02
                                .79  X02 0.79  H02 0.79
                                     X02 1.     H02
                                 26  X02N0.22  H02 0.22
                                 52  ROR
                                 2    ALD21.88  H02 -4.2
                                 04  ROR
                                76  H02 0.56  X02 0.6
                                04  X02N0.44  PAR 0.4
                                    ALD2-2.   PAR 2.
        1.000E+OQ  O.OOOE+00
        4.323E+06-1.175E+03
        2.664E+01  1.370E+03
        1.375E+04  O.OOOE+00
        2.309E+03-6.870E+02
        2.438E+03-6.020E+02
        4.731E-02  2.450E+02
        5.300E-02  O.OOOE+00
        1.000E+00  O.OOOE+00
       4.246E+05-3.900E+02
       3.260E+00 O.OOOE+00
        1.000E+02 9.400E+02
       3.000E+00 5.800E+02
       3.390E+01 O.OOOE+00
       4.416E+04-2.500E+02
       5.901E-01 1.230E+03
       1.853E+03-2.560E+02
       1.900E-06 O.OOOE+00
       2.776E+00 1.090E+04
       1.539E-04-5.300E+02
       1.600E-11 O.OOOE+00
       9.799E+03-8.060E+02
       1.975E-01 O.OOOE+00
       9.770E+03 O.OOOE+00
       1.500E-05 O.OOOE+00
       1.682E+04-7.130E+02
       2.179E+02-1.000E+03
       1.227E+04-2.400E+02
       2.025E+03-7.490E+02
       5.115E+00 1.012E+04
       6.833E+03-3.800E+02
       4.144E+03-1.150E+03
       2.181E-01-5.800E+03
       1.890E-01 O.OOOE+00
       2.520E+03 1.870E+02
      3.220E+02 O.OOOE+00
       1.500E+04 O.OOOE+00
     •1.000E+00 O.OOOE+00
      1.000E+00 O.OOOE+00
      2.370E+02 1.550E+03
      9.300E-01 O.OOOE+00
      6.360E+02 9.860E+02
      2.400E+04-2.500E+02
      3.700E+00 O.OOOE+00
 X02  1.000E+00 O.OOOE+00
 X02  2.815E+04 1.800E+02
      1.374E+04-3.800E+02
      2.540E-02 1.350E+04
      3.700E+03 O.OOOE+00
 OH    9.600E+03 O.OOOE+00
      2.100E+01  1.710E+03
 ALD2 6.015E+02 O.OOOE+00
     6.015E+02 O.OOOE+00
 PAR  6.855E+04  8.000E+03
     6.855E+04 8.000E+03
     9.545E+04 O.OOOE+00
     2.200E+04 O.OOOE+00
CO   2.960E+03 3.240E+02
OH   2.960E+03 3.240E+02
X02  2.100E+04-5.040E+02
     2.100E+04-5.040E+02
        tottr6ce
                                                                                            « the inpu, file for
9ll24r2.4l
                                                   B-49
-------
03
03
N03
N03
0
0
OH
03
TOL
T02
T02
OH
CRES
CRO
OPEN
OPEN
OPEN
OPEN
OPEN
OH
OH
OH
HGLY
0
0
OH
OH
03
03
N03
X02
X02
X02N
X02
OLE
OLE
OLE
OLE
ETH
ETH
ETH
ETH
OH
NO

CRES
N03
N02

OH
OH
03
03
XYL
XYL
HCLY

I SOP
I SOP
I SOP
I SOP
I SOP
I SOP
I SOP
NO
X02
NO
H02


































1.0
0.66
1.82
2.
2.
0.6
1.
1.
0.44
0.9
1.
0.4
1.

1.
2.
2.
0.06
1.38
1.4
2.2
1.
1.
1.2
1.0
2.
2.
2.
0.2
1:
1.



ALD21 .48
CO 0.88
X02 2.
N02 -2.
FORM3.4
OH
X02 1.56
FORH0.42
H02 0.08
N02 0.9
CRES1 .
CRO 0.6
CRO 1.

C2031.
X02 4.
FORM
ALD21.24
CO 0.16
H02 1.0
PAR 0.6
X02 1.
C2031.
H02 1.6
CO 0.90
X02 2.
ETH 0.8
FORMO. 8
PAR 0.12
X02N
N02



FORMO.
44
H02 -2.
FORHO.
PAR
H02 2.

FORMO.
CO 0.
18



22
12
X02 0.36
H02 0.
H02
X02 0.
HN03

H02 1.
CO 4.
9

6




X02 0.2
PAR
X02N2.

CO 1.4

ALD21 .
H02
CRES0.56
OPEN

H02 0.3


CO
H02 2.
OH 9
9
ALD2 5
5
X02 5
5
H02 1
2
T02 9
1
2
OPEN 6
3
2
8
.OOOE-03
.OOOE-03
.675E+00
.675E+00
.400E+02
.400E+02
2.
2.
0.
0.
7.
7.
.192E+04-4.
.702E-03
2.
.150E+03-3.
.200E+04
.500E+02
.100E+04
.250E+04
.OOOE+04
.400E+00
C203 2.200E+04
2.200E+04
C2031.
OH 1.
X02 0.
T02
C203
H02 1.
AL021 .
ETH 1.
. FORM1.
4
52
4



10
8
34
MGLY0.4
ALD21 .
CO 0.





10
88





FORMO. 06
H02 0.4
CRES1 .6


CO
OLE 1.0
PAR
H02 0.26
C2030.4
ETH 0.4
H02 0.2





X02 7
MGLY 7
MGLY 1
1
2
8
X02 1
1
X02N 7
ALD2 7
MGLY 9
OH 9
4
1
2
1
8
.500E-03
.500E-03
0.
0.
0.
0.
105E+03
105E+03
OOOE+00
OOOE+00
920E+02
920E+02
110E+02
633E+03
220E+02
OOOE+00
OOOE+00
OOOE+00
OOOE+00
O.OOOE+00
0.
0.
0.
5.
5.
.810E+04-1.
.810E+04-1.
.600E+04
.960E+00
.350E+04
.350E+04
.100E+04
.100E+04
.OOOE-03
.OOOE-03
.700E+02
.200E+04
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.OOOE+03-1.
.OOOE+03
0.
.896E+03-1.
OOOE+00
OOOE+00
OOOE+00
OOOE+02
OOOE+02
160E+02
160E+02
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
OOOE+00
300E+03
OOOE+00
300E+03
0.298E+03
TRAC
TEST
N02
NO
03
CO
ETH
OLE
ALD2
FORM
TOL
XYL
PAR
I SOP
PAN
K02
0
N205
H202
HN02
010
PNA
C203
ROR
N03
HN03
OH
T02
CRES
OPEN
MGLY
X02
X02H
CRO
H2O
1. OOOE+00
1. OOOE+00
3.016E-03
1.137E-03
6.316E-02
2.001E-01
4.578E-04
1.447E-04
5.561E-04
1.791E-03
1 .338E-04
4.937E-05
1 .245E-02
3.018E-05
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
1.921E-05
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
O.OOOE+00
1.604E+04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0






























































































































































































•





























































































1






























RPH-II, CB-IVO991)
1
2

4


0.305E+03 0.215E+02
100.000 3
2






0.121E+02 0.406E+03 0
1010.
000 300.
000












.298E+03






EXHIBIT B-9.  Continued.
9M2
-------
  NO  2.279E+02    30.000
  N02  7.050E+00    46.000
  CO  7.209E+00    28.000
  RPM-II, CB-IV(1991> METEOROLOGICAL INPUT
    10
  0.302E+01  0.200E+01 0.280E+01 0.680E+02

  tSSES  KSSS
    10
  8'?]!l*2f  2>4,I3,E+23r °-123E+05 0.566E+04 0.234E+05 0.981E+04 0.355E+05 0
                     SrfJES          °-869E+05 °-217E+os °-108E+o1
                                                 0
                                                          0
    10
   T
    1
    8
    9
   14
   23
   34
   38
   39
   45
   76
   84
   10
                              0.126E+04 0.234E+05 0.125E+04
                                                °-122E+04
                                                                   0

                              °-294E+03 0.134E+03 0.295E+03 0.200E*03
                                       °-398E+03
 N02

 NO

 03

 CO

 ETH

'OLE

 ALD2
       i:JS:S
                !:SSKS
                                      0.266E+03 0.332E+03 0.398E*03
                                  1-00flMO 1-OOOMO 1-OOOMO 1-OOOE+0°
                                         3 2-939E-°3 3-653E"03 2-091E-03
                                         4 3-264E'04 1-8We-°* 6-835E-°5
                                  9-1S5E'02 8-920E-°2 7-068E-°2 5-382E-°2
      i:S2:Si l:Jffi:S! l:gg:S  2-358E-°1  2-424E-°1 2-236E-°1 2-17«-°1
                                  1-372E'03  1-855E-°3 1-WMS 1-927E-°3
                                  2'467E-°4  4-172E-°4 3-369E-°4
                                 2-204E"03  2-426E'03 1-8hVas
                                 3-845E'03  4-357E'03 4-097E-°3 3-851E-°3
                                 9'659E'04  1-067E-°3 5-363E'04 2-509E-°4
               2:50^:0°!
 FORM  1.812E-03
      2.260E-03
 TOL
XYL

PAR

I SOP

CRES
 4012
N02  3NO  503
                                 5-183E-°2 5-717E-°2 3-986E-°2 3-676E-°2
                                 6-630E-°5 8-997E-°5 1-460E-°4 2-986E-°4
                                 1-296E'04 1-036E-°4 3-384E-°5 5-333E-°6
                OFORM 0
EXHIBIT B-9.  Concluded.
9J 124-2.41
                                              B-51
-------
  WIND        INTERPOLATED WIND FIELDS •  ATLANTA -  840603
   1   0  84155   0.00  84156   0.00
        0.00      0.00 16 660000.003665000.00 4000. 4000.  40  40
      0    0   40   40
   84155     0. 84155     1.
     1    10.0 20333.0 23379.5  15546.8 20113.4 16857.7 17397.3
     1WINOX
   0.9049476560+04 0.955751172D+04  0.9810671870+04  0.102319727D+05
   0.1132930860+05 0.1137627730+05  0.1142042190+05  0.1148130860+05
   0.1159650000+05 0.116369375D+05  0.1167935940+05  0.1171969530+05
   0.1195672660+05 0.1201297270+05  0.1204401170+05  0.1207355860+05
   0.1219704690+05 0.122349922D+05  0.1227367580+05  0.1230870700+05
   0.123857773D+05 0.1240466410+05  0.124577383D+05  0.1247818360+05
   0.9912035160+04 0.1029235940+05  0.1071999220+05  0.1088688670+05
   0.114243906D+05 0.114S59141D+05  0.115511445D+05  0.1158792190+05
   0.1169163280+05 0.1173237500+05  0.1179001170+05  0.1185638670+05
   0.1207061720+05 0.1210332030+05  0.1214898830+05  0.1217845310+05
   0.1229000390+05 0.123294062D+05  0.1234508590+05  0.1235917580+05
   0.12S360937D+05 0.1255546090+05  0.126620977D+05  0.9712488280+04
   0.1074259770+05 0.109871641D+05  0.112734961D+05  0.1136337110+05
   0.1158759370+05 0.1163002730+05  0.1164602340+05  0.1166256640+05
   0.1181412500+05 0.1188033590+05  0.1196030470+05  0.1203730080+05
   0.1218640230+05 0.122135742D+05  0.1223799610+05  0.1226662500+05
   0.123668281D+05 0.1238435550+05  0.1241108200+05  0.1248454300+05
   0.1273879690+05  0.982421484D+04  0.9921957030+04  0.1010374220+05
   0.1128184770+05  0.1135475780+05  0.1140675780+05  0.1145758590+05
   0.1167788280+05  0.1170011330+05  0.1173291410+05  0.1177193360+05
   0.1198073440+05  0.1207172660+05  0.1214658980+05  0.1218360550+05
   0.122835781D+05  0.1231305080+05  0.1235114060+05 0.1237602340+05
   0.1247003120+05  0.1255707030+05  0.1257073050+05 0.1266230860+05
   0.1003358200+05  0.1024131640+05  0.1051485550+05 0.104827070D+05
   0.1141317970+05  0.1147456640+05 0.1155255860+05 0.1162804690+05
   0.1178016410+05  0.1182013280+05 0.1184731250+05 0.1188907030+05
   0.1218617580+05  0.122365547D+05 0.122568281D+05 0.122788281D+05
    1239971870+05 0.1242075780+05 0.1244056640+05 0.1244512110+05
    1262401950+05 0.1271896090+05 0.1271854690+05 0.1289704300+05
                    1053135550+05 0.9687394530+04 0.1095076560+05
                    1164042970+05 0.1168855080+05 0.1172556250+05
                    1193977730+05 0.1198252730+05 0.120375039D+05
  	1230831640+05 0.1233629690+05 0.1236676170+05
  0.1248990620+05 0.1249605860+05 0.1253062500+05 0.1256523830+05
  0.127833359D+05 0.1296729690+05 0.1003823050+05 0.101516133D+05
  0.8952000000+04 0.1072135160+05 0.1124295700+05 0.1141602730+05
  0.1170767580+05 0,1175631640+05 0.1181012110+05 0.1185000000+05
  0.1192373050+05 0.1194426560+05 0.1201502730+05 0.120933086D+05
  0.1223769920+05 0.1229633980+05 0.1241610160+05 0.1248148440+05
                  0.126232617D+05 0.1271491410+05 0.1272128120+05
                                                                                0.
                                                                                      50.   150.
 0.
 0	
 0.107755117D+05  0.
 0.1156521480+05  0.
  .1189295310+05  0.
 0.1228176950+05
0.1258264840+05
0.101161094D+05 0.1026234770+05 6	
0.1141079300+05 0.1125901950+05 0.1062334770+05
0.1183416020+05 0.1186798050+05 0.1189015620+05
0.1161455860+05 0.1167651950+05
                                    107207891D+05 0.1112414060+05
                                                  0.1136405470+05
                                                  0.1183411720+05
                                                  0.1177394920+05
  0.1230122660+05  0.124740117D+05  0.1254437110+05  6.1257014450+05
  0.1277544140+05  0.1277243360+05  0.1287189060+05  0.128792773D+05
  0.1094526560+05  0.1129992580+05  0.1143037890+05  0.1131864450+05
  0.9304441410+04  0.1100096870+05  0.1151667580+05  0.1170138280+05
  0.1164205860+05  0.114492461D+05  0.1139266020+05  0.1134746480+05
  0.1152758590+05  0.1158795310+05  0
  0.1254186330+05  0.1260422660+05  0
  0.1291418360+05  0.129182773D+05
  0.1155183980+05  0.115303125D+05  0.114958594D+05
  0.1133333200+05  0.1154608590+05  0.1157362110+05
                  0.1103861720+05  0.1108292580+05
                                 .1166153520+05 0.1174599610+05
                                 .1262342190+05 0.1268545700+05
                                0.131117031D+05 0.102549727D+05
                                                0.1090554300+05
 - - -——————•- — --——• •— • • <«-Tww«>f+r'\t^ w• * i.*iwwt.i i v *~ ww 0• IInZo 16020^05
0.1103505080+05 0.1103861720+05 0.1108292580+05 0.1119715230+05
0.115264844D+05 0.116333555D+05 0.1174877730+05 0.1190254690+05
0.1266524610+05 0.1274006250+05 0.1278797270+05 0.1287574610+05
0.1314432420+05 0.103673750D+05 0.1067000000+05 0.1115630470+05
0.1160167580+05 0.1145046870+05 0.1112141410+05 0.1114782420+05
0.1123897660+05 0.1118169920+05 0.1097996090+05 0.1089988280+05
0.108689336D+05 0.1092233200+05 0.1100100390+05 0.1113103120+05
0.1164317190+05 0.1179451560+05 0.1197582420+05 0.1221359370+05
0.1283375000+05 0.1292093360+05 0.1291553520+05 0.1300518360+05
0.108883203D+05 0.112544375D+05 0.1137763670+05 0.1150560160+05
0.1154539450+05 0.1120772660+05 0.1035048440+05 0.9731035160+04
„ ...^,,	„ ..	0.1072100780+05 0.1070464450+05
                                0.1100813670+05 0.1118141410+05
 0.1080962890+05° 0.
 0.107518867D+05 01
 0.1188590230+05
                 .1075099220+05
                 11084987500+05
	,	 -.1206245700+05 0.1231080860+05 0^1265324220+05 6
0.1295774610+05 0.1304783590+05 0.1305060160+05 0.1320364840+05
0.1139S1367D+05 0.1150144920+05 0.1154823050+05 0.1161500000+05
0.1064291410+05 0.1000292580+05 0.1060912500+05 0.1081964060+05
 0.1080440230+05
 0.1155044140+05
 0.1177677340+05
 0.1212180860+05
 0.1231663670+05
 0.125332617D+05
 0.1121557810+05
 0.116027031D+05
 0.1192303910+05
 0.1220022660+05
 0.1238377340+05
 0.9842683590+04
 0.1140712500+05
 0.1169298440+05
 0.1209537500+05
 0.1229841410+05
 0.1249847270+05
 0.1048685160+05
 0.1152558200+05
 0.1180388280+05
 0.1220266800+05
 0.1239646090+05
 0.1267027730+05
 0.1075446480+05
 0.1167672270+05
 0.1194350000+05
 0.1230285940+05
 0.1247329300+05
 0.1002887500+05
 0.1128526560+05
 0.117747344D+05
 0.121206445D+05
 0.1241134770+05
 0.1265783590+05
 0.1051062890+05
 0.1139757420+05
 0.1189572270+05
 0.1214188670+05
 0.1251089450+05
 0.1283013670+05
 0.1095337500+05
 0.1161108980+05
 0.1177330080+05
 0.1183087110+05
 0.125818672D+05
 0.1307712890+05
 0.115321875D+05
 0.1177593360+05
 0.1134588280+05
 0.1185891020+05
 0.1273517190+05
 0.1052895700+05
 0.9809246090+04
 0.1129056250+05
 0.1127064840+05
 0.1214110160+05
 0.1286500390+05
 0.1137612890+05
 0.1087884370+05
 0.1085926170+05
 0.1125372660+05
 0.1250009370+05
 0.1300904690+05
 0.115441367D+05
 0.1077223830+05
 0.1069097660+05
 0.1135932810+05
  1281423440+05
 0.1084485940+05
0.1163637500+05
0.107340312D+05
 0.1103813280+05
 0.1156783980+05
 0.118379023D+05
 0.1214379690+05
 0.1232312500+05
 0.951075781D+04
 0.113205352D+05
 0.1162623830+05
 0.1198620700+05
 0.1222451950+05
 0.1244448830+05
 0.9975414060+04
 0.1145150000+05
 0.1173101560+05
 0.121237617D+05
 0.1232753120+05
 0.1258333590+05
 0.1071874610+05
 0.1159921480+05
 0.1184534370+05
 0.1222974220+05
 0.1240551560+05
 0.1283567970+05
 0.1122675390+05
 0.117069102D+05
 0.1201166410+05
 0.1233258980+05
 0.125058477D+05
 0.1014986330+05
 0.1139783980+05
 0.1181905080+05
 0.122046992D+05
 0.1244858590+05
 0.1267997660+05
 0.108676445D+05
 0.1155320700+05
 0.1192664450+05
 0.1216986720+05
 0.1252917580+05
 0.128333437D+05
 0.1037083590+05
 0.1171676560+05
 0.1160818360+05
 0.1190217970+05
 0.1263910550+05
 0.101832187D+05
 0.114334961D+05
 0.1175729300+05
 0.1141259770+05
 0.120724727D+OS
 0.1282584770+05
 0.110749492D+05
 0.1045750390+05
 0.1114035940+05
 0.1135617190+05
 0.1243130470+05
 0.1296098050+05
 0.1152369920+05
 0.1055927340+05
 0.1085101560+05
 0.1137582030+05
 0.126754492D+05
 0.1317328120+05
 0.1162030080+05
 0.1103558980+05
 0.1068844140+05
0.1153204300+05
0.1287730080+05
0.1107688670+05
0.1165018360+05
0.1064773440+05
 0.112342734D+05
 0.1157388670+05
 0.1190029300+05
 0.121608242D+05
 0.1234275390+05
 0.9757203120+04
 0.1137405080+05
 0.116560391D+05
 0.1203907420+05
 0.1225451560+05
 0.1246084770+05
 0.1035695700+05
 0.1151842970+05
 0.117666914D+05
 0.1214903910+05
 0.1235745310+05
 0.125982734D+05
 0.1110051950+05
 0.116532773D+05
 0.1190237890+05
 0.1225739450+05
 0.1243540620+05
 0.9973359370+04
 0.113487031D+05
 0.1174057420+05
 0.1209964840+05
 0.1236607810+05
 0.126028320D+05
 0.1039585940+05
 0.1147415620+05
 0.1186183590+05
 0.1225709370+05
 0.124694648D+05
 0.1278753520+05
 0.1027486330+05
 0.1165106640+05
 0.119611133D+05
 0.122006094D+05
 0.1253882030+05
 0.1302212890+05
 0.1112161330+05
 0.1178468750+05
 0.115744023D+05
 0.1204380470+05
 0.1268406640+05
 0.104125547D+05
 0.1019212890+05
 0.117431484D+05
 0.1147220700+05
 0.123673203D+05
 0.128190742D+05
 0.113716562D+05
 0.1116823440+05
 0.110552109D+05
 0.1143446090+05
 0.1260011330+05
 0.1296678910+05
 0.1155324220+05
 0.1111527730+05
 0.1085085160+05
 0.1150677340+05
 0.1278158980+05
 0.105920742D+05
 0.116444023D+05
 0.1098799610+05
 0.1070794140+05
 0.1170758980+05
 0.1295888280+05
0.1134068750+05
0.1136864840+05
0.1061114060+05
EXHIBIT B-lOa.   Example of UAM input file:  hourly, gridded horizontal wind components for each of thJ
UAM layers.
9JI24i2.42
                                                            B-52
-------
                                        3665000.0  4000. 4000.   40  40   5   2   3      0.

                                            1.00
50.   150.
 DIFFBREAK Atlanta  June 3,  1984
  5   0 84755    0. S4J56     I.
       0.0         0.0  16  660000.0
     0   0   40    40
          84155      0.00     84155
    1DIFFBREAK
















. 2367226720+03. 2367322540+03,2367200010+03               '
.2362340390+03.2361381840+03.2360419010+03'
.2339130250+03.2340077970+03.23411 ^Xn^''



 -2360087890+03










 -241693024D+03











      .2339191130+03
      .2384111790+03
      .2395671230+03
      .2362024690+03
      .2329673460+03
      .2360339660+03
      .2432309570+03
      .2371762390+03,
      .2325595250+03.
      .2336136470+03.
      .2396069340+03,
   .2346652680+03
   .2357283940+03
   .2362299650+03
   .2358204190+03
   .2342324370+03
   .2353120420+03
   ,2362864380+03
   ,2361794740+03
   ,2338558650+03
   .2347891080+03
   .2360708920+03
   .2365172120+03
   .2358818820+03
   .2342680510+03
   .2355808110+03
   .2366902770+03
   .2363278050+03
   .2338266600+03
   .2349375920+03
   ,2365080870+03
  .2368135220+03
  .2359051060+03
  .2343000180+03
  .2359259490+03
  .2371732330+03
  .2364319760+03
  .2337778020+03
  .2351192020+03
  .2370797880+03
  .2370895540+03
  .2358805850+03
  .2343234860+03
  ,23638179.00+03
  ,2377365570+03
  ,2364678040+03
  .2336992800+03
  .2353465730+03
  .2378509520+03
  .2372931820+03
  .2358029940+03
  .2343301090+03
  .2370014340+03
  .2383429410+03
  .2364137730+03
  .2335757750+03
  .2356420290+03
  .2389385220+03
  .2373541870+03
  ,2331146090+03
  ,2343049160+03
  2378677060+03
 .2388514250+03
 .2362605900+03
 .2333825380+03
 .2360538020+03
 .2405508880+03
 .2372120510+03
 .2328880770+03
 .2342193300+03
 .2390952610+03
 .2389648740+03
 .2360178680+03
 .2330790410+03
 .2367274930+03
 .2426754910+03
 .2368598180+03
 .2325805970+03
 .2340090790+03
 ,2407497410+03  .
.2384434360+03
.2357108150+03
.2325958250+03
EXHIBIT B-10b.   Diffusion break in the atmnosphere.
91124r2.42
                                                           B-53
-------
 KETSCAURSAtlanta June 3-4,  1984 v2
  0  0  84154   23. 84157    0.
        0.0        0.0  16 660000.0 3665000.0
           84154     23.00    84155     0.00
 TGRADBELOW 0.1040000E-01
 TGRADABOVE-0.2500000E-02
 EXPCUSS  -0.20Q0000E+01
 RAOFACTOR  O.OOOOOOOE+00
 CONCUATER  0.1404400E+05
 ATHOSPRESS 0.1000000E+01
           84155      0.00    84155     1.00
 TGRADBELOW 0.1040000E-01
 TGRADABQVE-0.2500000E-02
 EXPCUSS  -0.2000000E-HJ1
 RADFACTOR  O.OOOOOOOE+00
 COWCUATER  0.1404400E+05
 ATHOSPRESS 0.1OOOOOOE+01
           84155      1.00    84155     2.00
 TGRADBELOW 0.1262000E-01
 TGRADABOVE-0.2500000Er02
 EXPCUSS  -0.2000000E+01
 RADFACTOfi  O.OOOOOOOE+00
 CONCWATER  0.1404400E+05
 ATHOSPRESS 0.1OOOOOOE+01
           84155      2.00    84155     3.00
 TGRADBELOU 0.1800000E-01
 TGRADABOVE-0.2500000E-02
 EXPCUSS  -0.2000000E+01
 RAOFACTOR  O.OOOOOOOE+00
 COHCUATER  0.1404400E+05
 ATHOSPRESS 0.100000CE+01
           84155      3.00    84155     4.00
 TGRADBELOW 0.1800000E-01
 TGRADABOVE-0.2500000E-02
 EXPCUSS  -0.2000000E+01
 RADFACTOft  O.OOOflOOOE+00
 CONCWATER  0.1404400E+05
 ATKOSPRESS 0.1000000E-t-01
           84155      4.00    84155      5.00
 TGRADBELOU 0.18000QOE-01
 TGRADABOVE-0.2500000E-02
 EXPCUSS  -0.2000000E+01
 RAOFACTOR  O.OOOOOOOE+00
 COHCVATER  0.1404400E+05
 ATHOSPRESS O.IOOOtiOOE+01
           84155       5.00    84155      6.00
 TGRADBELOU-0.1000000E-01
 TGRADABOVE 0.5040001E-02
 EXPCUSS  -0.2000000E+01
 RAOFACTOR  0.7099998E-01
 CONCVATER  0.143040CE+05
 ATHOSPRESS 0.100000CE+01
           84155       6.00     84155      7.00
 TGRADBELOW-0.1000000E-01
 TGRADABOVE  0.5910002E-02
 EXPCUSS   0.1000000E+01
 RADFACTOR  0.2450000E+00
 CONCWATER  0.1456400E+05
 ATHOSPRESS  0.1000000E+01
          84155      7.00     84155      8.00
 TGRADBELOW-0.1000000E-01
 TGRADABOVE  0.2990000E-02
 EXPCUSS   0.1 OOOOOOE+01
 RAOFACTOR  0.3950000E+00
 COHCUATER  0.156600CE+05
 ATHOSPRESS  0.1000000E+01
          84155      8.00     84155      9.00
 TGRADBELOW-0.1050000E-01
 TGRADABOVE  0.1910000E-02
 EXPCLASS    0.1000000E+01
 RAOFACTOR   0.4950000E+00
 CONCWATER  0.1529500E+05
 ATHOSPRESS 0.1000000E+01
          84155      9.00     84155     10.00
 TGRADBELOW-0.1050000E-01
 TGRADABOVE 0.1790000E-02
 EXPCUSS   0.2000000E+01
 RADFACTOR  0.5630000E+00
4000. 4000.  40  40
50.   150.
EXHIBIT B-lOc.  Meteorological parameters that are treated as  scalars.


                                                           B-54
91124r2.42
-------
TEMPERATURAtlanta June 3-4. 1984
 f  0  84155  0. 84157   0.
   n  °"S  /«  ?«°  16 660000-°  3665000.0  4000. 4000. 40 40
   U   U  40  40
0.
                                                                    50.  150.
                                            o°-ii!S:si j-gsssrs g-sssra <>•»»««•«
   0.2929998E+03 0.2929998E+03 0.2929998E+03 029300oSl 0 ISSf 2'iS?,ff 21 2'£2fJS8E+03 °-2929998E+03 0.2930000E+03
   0.2929998E+03 0.2930000E+03 0.2930000E+03 0.293000oKol o'zKOOttEai SlPSlnl 2E+  °'2929998E+03 0.2930000E+03
                                                                                  s~i
                                                                                  0.2929998E+03
           0.2929998E+03
           °-2929998E+03 0.2929998E+03
           °-2929998E+03 0.2930000E+03
 'f!f2222E*23 °-2930000E+03 0.2929998E+03
 'S2?^8E+03 °-2930000E+03 0.2929998E+03
 -f!!?^8E+03 °-2930000E+03 0.2929998E+03
 -!!12222E+°3 °-2929998E+03 0.2929998E+03
2'f!12222E+03 °-2929998E+03 0.2930000E+03
           °-2929998E+03 0.2930000E+03
           °'2929998E+03 0.2929998E+03
           °'2930000E*03 0.2930000E+03
           °-29a9998E+03 0.2929998E+03

 -293°°OOE*03 0-2929998E+03 0.2929998E+03
             «i=i
  0.2929998E+03 0.2929998E+03 0.2929998E+03 0 2929998E+O^I 0 "
  0.2929998E+03 0.2929998E+03 0.2929998E+03 0 2929998E+03 o'o
  0.2929998E+03 0.2930000E+03 0.2930000E+03 0 2930000E+03 0 293000 olto
  0.2929998E+03 0.2930000E+03 0.2929998E+03 0 2930000E+03 0 293000oI+2I
  0.2929998E+03 0.2930000E+03 0.2929998E+03 0 2929998E+03 0 292999^1
  0.2930000E+03 0.2929998E+03 0.2930000E+03 0 2929998E+03
  0.2929998E+03 0.2929998E+03 0.2929998E-f03 0 2930000E+03
  0.2930000E+03 0.2930000E+03 0.2930000E*03 0 2929998^03 0
  0.2929998E+03 0.2929998E+03 0.2929998E+03 0 2929998E+03 0
  0.2930000E+03 0.2930000E+03 0.2929998E+03 oiwlwSEtol oo
  0.2929998E*03 0.2929998E+03 0.2930000E*03 0 2930000E+03 0 2929998^1
  0.2929998E+03 0.2929998E+03 0.2929998E+03 0 2929998E+03 0293000ol+oi oo«                         .
                       tssss
                       ISSSSSS                                         S5BB3
                       tsssss
                       tSSSSS
  0.2929998E+03 0.2929998E+03 0.2929998E+03 0 2930000E+03 0 2929991^ 2'fo^2! 21

                                            IH  HI
   iil fcB °IE1 siS sill 111  =
   iil sIEi «1 s:lS
                      SSSBSS
            :^88£S

   P isi n isi                      P



EXHIBIT B-lOd.  Time-varying matrices of temperature at ground level.
 124c2.42
                                           B-55
-------
 AVERAGE   JUNE 3,1984 EVALUATION RUN#1
  1 24  84155   12. 84155   24.
        0.0        0.0  16  660000.0  3665000.0
     0    0   40   40
 HO
 H02
 03
 OLE
 PAR
 TOt
 XYL
 FORM
 ALD2
 ETH
 CRES
 HOLY
 OPEN
 PHA
 NXOY
 PAH
 CO
 MONO
 H202
 HN03
 H€OH
 ETOH
 ISOP
 CLBR
           84155     12.00     84155 -    13.00
    1HO
 .674138078E-03.637855846E-03.611590454E-03.6066S44aOE
 .935182907E-03.995304668E-03.105130021E-02.110293063E
 .131190289E-02.132770278E-02.133724650E-02.134021742E
 .120839104E-02.116072362E-02.110587128E-02.104415463E
 .676776050E-03.682347687E-03.712659908E-03.754278386E
 .617685961E-03.698890071E-03.7S0655770E-03.858598156E
 .121596269E-02.125742052E-02.129347900E-02.132385176E
 .136S44462E-02.134565867E-02.131761422E-02.128120882E
 .883750618E-03.789773418E-03.694699120E-03.613157172E
 .530234S38E-03.447687227E-03.400592340E-03.460148323E
 .100833364E-02.107559841E-02.113712857E-02.119321514E
 .141025987E-02.142316334E-02.142811565E-02.142467441E
 .121343S81E-02.114505412E-02.106648309E-02.977080781E
 .493847998E-03.593080185E-03.681832898E-03.596952159E
 .663672108E-03.768571626E-03.862609595E-03.947779045E
 .132616609E-02.136969611E-02.140706776E-02.143771525E
 .144513324E-02.141254626E-02.136976363E-02.131678302E
 .763335498E-03.618852209E-03.450266991E-03.271657715E
 .455421396E-03.364455162E-03.364433043E-03.364395557E
 .364165986E-03.364127336E-03.364081003E-03.364051200E
 .363881234E-03.363866799E-03.363857718E-03.363850035E
 .363882864E-03.363900792E-03.363909639E-03.363929197E
 .364019768E-03.703006750E-03.656922581E-03.602111919E
 .471591018E-03.537330518E-03.601924723E-03.704129459E
 .965203624E-03.102927722E-02.105669349E-02.107720937E
 .108433934E-02.108195608E-02.105625042E-02.985120889E
 .545872608E-03.460197451E-03.412091147E-03.388238579E
 .276648439E-03.335254241E-03.431499211E-03.539234839E
 .837817322E-03.896286918E-03.944220927E-03.981875928E
 .118707214E-02.123103755E-02.121706561E-02.118882325E
 .904792454E-03.836457592E-03.767073361E-03.691734022E'
 .364013948E-03.765426317E-03.745353987E-03.364537351E'
 .77S125599E-03.773475738E-03.840226421E-03.837393571E-
 .112840114E-02.118782651E-02.121677970E-02.123887486E'
 .122474111E-02.114984205E-02.109343231E-02.102902902E'
 .630275346E-03.586224254E-03.555529958E-03.543024857E-
 .377605436E-03.338546373E-02.320245512E-02.150041841E'
 .988172833E-03.103751663E-02.107751368E-02.114123500E'
 .143586728E-02.138912653E-02.139491283E-02.136210700E-
 .947864726E-03.882135704E-03.818604836E-03.755552901E-
 .869336305E-03.868318602E-03.364586012E-03.325144036E-
 .2B8796425E-02.16322Q940E-02.104744057E-02.101936795E-
 .132960873E-02.136738364E-02.140433083E-02.157625647E'
 .129720848E-02.122806313E-02.115070026E-02.107208081E-
 .730999745E-03.700327568E-03.677437056E-03.363985775E-
 .638699392E-03.714836176E-03.798820751E-03.711100409E-
 .116696837E-02.120293885E-02.125050242E-02.130965654E-
 .173236709E-02.163381174E-02.155218551E-02.147790625E-
4000. 4000.  40  40
                                    0.
                       50.   150.
     -03.630177092E
     -02.115005765E
     -02.133634079E
     -02.976245152E
     -03.634661410E
     •03.931371469E
     •02.134818256E
     •02.123636797E
     •03.573548023E
     •03.564819435E
     •02.124395359E
     •02.141248107E
     •03.875990605E
     •03.510770129E
     •03.102550257E
     •02.146099133E
     •02.125354156E
     •03.436538830E
     •03.364364125E
     •03.364005333E
     •03.363853062E
     •03.363945495E'
     •03.364501495E'
     •03.748429913E'
     •02.109979091E-
     •03.912319403E-
     •03.395572977E'
     •03.582998851E-
     03.101616187E'
     02.117042311E-
     03.616364414E-
     03.303840265E-
     03.883298693E-
     02.127996458E-
     02.962255755E-
     03.364002306E-
     02.134154083E-
     02.118372682E-
     02.128669036E-
     03.708949519E-
     03.485202763E-
     02.105489767E-
     02.155265816E-
     02.999267213E-
     03.914181815E-
     03.707396772E-
     02.137235108E-
     02.139277917E-
-03.677765347E
-02.119253760E
-02.132539310E
-03.903594773E
•03.5803050016
•03.998722389E
•02.136607327E
•02.118302437E
•03.593303936E
•03.669483561E
•02.128927175E
•02.139126787E
•03.762445852E
•03.398955541E
•02.109677203E
 02.147622079E
 02.117982971E
 03.573092140E
 03.364331296E
•03.363973901E
 03.363853062E
 03.363957603E
 03.243391609E
 03.800888287E-
 02.110968668E
 03.844947295E
 03.364022795E'
 03.606740592E-
 02.108340150E-
 02.119279348E-
 03.549037941E-
 03.354436226E-
 03.939966179E-
 02.132546830E-
 03.891256845E-
 03.819426496E-
 02.146734202E-
 02.126077724E-
 02.121881207E-
 03.663011800E-
 03.541683519E-
 02.109622278E-
 02.153791229E-
 03.938882818E-
 03.919192331E-
 03.798899680E-
 02.147318258E-
 02.129910605E-
-03.738993054E
-02.123020494E
-02.130720437E
-03.829249853E
-03.532893697E
-03.106073706E
-02.137711642E
•02.112109375E
•03.6490*92486E
•03.766208395E
•02.132894842E
•02.136086252E
•03.637187855E
•03.267090043E
•02.116223027E
•02.148274936E
•02.109516317E
•03.675965566E
•03.364288455E
•03.363944098E
•03.363857718E
•03.363965053E
•03.292679528E
•03.855294522E
•02.114821433E
•03.782016898E
•03.709649175E'
•03.651505543E-
•02.111967395E'
02.111442222E-
03.500721391E-
03.883266097E-
03.987665029E-
02.129922945E-
03.822255155E-
03.810337020E-
02.118144858E-
02.128740328E-
02.115537620E-
03.631638104E •
03.594770536E-
02.113829458E-
02.152385421E-
03.879407860E-
03.364619074E-
03.909183407E-
02.151480781E-
02.120903715E-
-03
 02
 02
 03
-03
•02
•02
•02
•03
•03
•02
•02
•03
•03,
•02,
•02,
•02,
•03,
•03,
•03,
•03,
•03,
•03,
•03,
 02,
 03,
 03.
 03.
 02.
 02.
 03.
 03.
 03.
 02.
 03.
 03.
 02.
 02.
 02.
 03.
 03.
 02.
 02.
 03.
 03.
 03.
 02.
 02.
.805217074E
.126284081E
•128166284E
.759293325E
.516041415E
.111756870E
.138091622E
.105049019E
.712403795E
.854414189E
.136264367E'
.132115558E'
• 509953126E'
.409095082E'
,122224214E'
.148001360E-
.998641131E'
,615809113E-
.364249805E
,363917090E
.363866799E
363988569E'
,353147974E-
899892068E-
,113830762E-
722347759E-
674549956E-
750149833E-
114795775E-
103654061E-
473502325E-
131053710E-
102746300E-
125727919E
754732639E-
364560867E
102058449E
132417260E
108768791E
613414915E
511323335E
118827005E
144689647E-
820216490E-
341914129E-
103747216E-
173530541E-
112667424E-
-03.«71438766E^
•02.129017280EH
 02.-J24872662E-
 03.704219798E-
 03.549012562E-
 02.116931042EJ
 02.137712341E-
 02.971232075E-
 03.605313107E-
 03.934838550E-
 02.138991512E-
 02.127205858E-
 03.436685514E-
 03.545140589E-
 02.127691776E-
 02.146757113E-
 03. £1887937291-
 03.539778499E-
 03.364212319E-
 03.363900792E-
 03.363872387E-
 03.364005333E-
 03.410914421E-
 03.934466254E-
 02.111343153E-
 03.6.41176477E-
 03.364514766E-
 03.794319436E-
 02.117199658E-
 02.972337555E-
 03.472531887E-
 02.101512694E-CI
 02.106987171E-d
 02.129228318E-0
 03.685173320E-0
 03.317103229E-0
 02.949672656E-
 02.138803967E-
 02.101660611E-C
 03.363991596E-
 03.312793441E-
 02.124041527E-0
 02.133956806E-C
 03.772880856E-0
 03.503307907E-0
 02.112455245E-0
 02.168205239E-0
 02.105247856E-0
EXHIBIT B-lOe.  Average concentration.
                                                           B-56
9U24r2.42
-------
                                       3665000.0  4000. 4000.   40   40    5    2   3

                                       0.00
 REGIONTOP Atlanta June 3-4, 1984
  f  0  84155    0. 84157    1.
        0.0        0.0  16  660000.0
     0    0   40   40
      84155      0.00     84157
    1REGIONTOP
  2']40,0,0.0.0000*04 0.1400000000+04 0.1400000000+04 0.1400000000+04
  0.1400000000+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
  2*;42222OOOD*04 0.1400000000+04 0.1400000000+04 0.1400000000+04
  0.1400000000+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
  Z'lWSSSSSSP*0* 0.1400000000+04 0.1400000000+04 0.1400000000+04
  0.1400000000+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
  0.1400000000+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
  0.1400000000+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
  0.1400000000+04 0.1400000000+04 0.1400000000+04 0
  0.1400000000+04 0.1400000000+04 0.1400000000+04 0
  0.1400000000+04 0.1400000000+04 0.1400000000+04 0
  0.1400000000+04 0.140000000D+04 0.1400000000+04 0
   .1400000000+04 0.1400000000+04 0.1400000000+04 0
   .1400000000+04 0.1400000000+04 0.1400000000+04 0
   .1400000000+04 0.1400000000+04 0.1400000000+04 0.
                   .1400000000+04 0.1400000000+04 0
                                                                                 0.
                                                                                           50.    150.
1400000000+04 0
1400000000+04 0.
                                    .
                     1400000000+04 0.1400000000+04 0
                                                   1400000000+04
                                                   .1400000000+04
                                                   .1400000000+04
                                                   ,1400000000+04
                                                   ,1400000000+04
                                                   , 1400000000+04
                                                   ,1400000000+04
                                                   1400000000+04
                                                   1400000000+04
                                                   1400000000+04
                                                   1400000000+04
                                                   1400000000+04
  0.1400000000+04 0.1400000000+04  0.1466066660+64 0
  0.1400000000+04 0.1400000000+04  0.1400000000+04 0
  0.1400000000+04 0.1400000000+04  0.1400000000+04 0            _
  0.1400000000+04 0.1400000000+04  0.1400000000+04 o!i4666o66oo+04
  0.1400000000+04 0.1400000000+04  0.1400000000+04 0.1400000000+04
  0.1400000000+04 0.1400000000+04  0.1400000000+04 0.1400000000+04
  0.1400000000+04 0  «•""—-——-•  -  	
  0.1400000000+04 0
  0.1400000000+04 0
  0.1400000000+04 0
  0,1400000000+04 0
  0.1400000000+04 0
   1400000000+04
                    .1400000000+04 0.
                    .1400000000+04 0.
                    .1400000000+04 0.
                    .1400000000+04 0.
                    .1400000000+04 0.
                    .1400000000+04 0.
                    .1400000000+04 0,
                                1400000000+04  0.1400000000+04
                                1400000000+04  0.1400000000+04
                                1400000000+04  0
                                1400000000+04  0
                                1400000000+04  0
                                              0
                                              0
                                                   1400000000+04
                                                   1400000000+04
                                                   1400000000+04
                                                   1400000000+04
                                                   1400000000+04
                                  1400000000+04
         — -. ...	_ „ ..1400000000+04
  1400000000+04 0.1400000000+04 0.1400000000+04 0.14o66666oD+04
  1400000000+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
  140000000D+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
0.1400000000+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
0.1400000000+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
                                                  1400000000+04
                                                  1400000000+04
                                                  1400000000+04
  .1400000000+04 0
  .1400000000+04 0
  .1400000000+04 0
  .1400000000+04 0
                    .1400000000+04 0,
                    .1400000000+04 0,
                    .1400000000+04 0,
                    .1400000000+04
                               1400000000+04 0,
                               1400000000+04 0,
                               1400000000+04 0,
                               1400000000+04 0.
                                                    1400000000+04
0
0
0
0
0.140000000D+04 0.1400000000+04 0.1466666000+04 0.1400000000+04
0.1400000000+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
0.1400000000+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
0.140000000D+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
0.1400000000+04 0.1400000000+04 0.1400000000+04 0 1400000000+04
0.1400000000+04 0.140000000D+04 0.1400000000+04 0.1400000000+04
0.140000000D+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
0.1400000000+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
                  1400000000+04 0.1400000000+04 0.1400000000+04
                  1400000000+04 0.1400000000+04 0.1400000000+04
                                                  1400000000+04
                                                  1400000000+04
                                                  1400000000+04
                                                  1400000000+04
                                                  1400000000+04
  0
  0.1400000000+04 0
  0.1400000000+04 0
  0.1400000000+04 0
  0.1400000000+04
              ,1400000000+04 0
              ,1400000000+04 0
               1400000000+04 0,
 0.140000000D+04  0
 0.1400000000+04  0
   1400000000+04                     	
                                   1460060600+64 o
                       	  ,.  ..1400000000+04 0
                   1400000000+04  0.1400000000+04 0
        	  ..  -.1400000000+040.1400000000+040
 iM4™0,0,0000*04  °-1400000000+04  0.1400000000+04 0.1400000000+04
 0.1400000000+04  0.1400000000+04  0.1400000000+04 0.1400000000+04
 0.140000000D+04  0  • """"•"	  -	
 0.1400000000+04  0
   .1400000000+04  0
   ,1400000000+04  0
   ,1400000000+04
        	0
  0.1400000000+04  0
  0.1400000000+04  0
    140000000D+04
    1400000000+04
               1400000000+04  0.1400000000+04  0.1400000000+04
               1400000000+04  0.1400000000+04  0.1400000000+04
                               1400000000+04  0.1400000000+04
                               1400000000+04  0.1400000000+04
                               1400000000+04  0.1400000000+04
                               1400000000+04  0.1400000000+04
                               1400000000+04  0.1400000000+04
                             0.1400000000+04  0.1400000000+04
                             0.1400000000+04  0.1400000000+04
                  1400000000+04  0
                  1400000000+04  0
                  1400000000+04  0
                  1400000000+04  0
                  1400000000+04
                  1400000000+04
                  1400000000+04
0

o.1400000060+64 o.i4ooo6666b"+64 0.1400000660+64 0.1466666660+64
0.1400000000+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
0.140000000D+04 0.1400000000+04 0.1400000000+04 0 '*uuuuuuuo*°'>
0.1400000000+04 0.1400000000+04 0.1400000000+04 0
                                                  .1400000000+04
                                                  .1400000000+04
 0. 40000000D+04 0.1400000000+04 0.1400000000+04 0.1400000665+04
 P,-,140,™?,0,0,0,0*04 °-140000000D+04 0.1400000000+04 0.1400000000+04
 0.1400000000+04 0.1400000000+04 0.1400000000+04 0.1400000000+04
  0
  0
  0
  0
  0
  0
  0
  0
  0
  0
  0
  0
  0
  0
  0,
  0,
  0.
  0,
  0.
  0.
  0.
  0.
  0.
  0.
  0.
  0.
  0.
  0.
  0.
  0
  0
  0
  0
  0
  0
  0,
  0
  0,
 0,
 0,
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0
 0.
 0.
 0.
 0.
 0.
0.
0.
0.
0.
0.
0.
                                                                     .1400000000+04 0
                                                                    '.1400000000+04 0
                                                                     ,1400000000+04 0
  1400000000+04 0
 1.1400000000+04 0
 .1400000000+04 0
 .1400000000+04
 .1400000000+04
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 .
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0,
 ,1400000000+04 0,
 ,1400000000+04 0,
  1400000000+04 0.
 ,1400000000+04 0.
  140000000D+04 0.
  1400000000+04 0.
  1400000000+04 0.
 .1400000000+04 0.
 .1400000000+04 0.
 .1400000000+04 0.
 .1400000000+04 0.
 .1400000000+04 0.
 .1400000000+04 0.
 .1400000000+04  0.
 .1400000000+04  0-
 .1400000000+04  0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0,
 .1400000000+04 0,
 .1400000000+04 0,
 ,1400000000+04 0.
 ,1400000000+04 0.
 ,1400000000+04 0.
 ,1400000000+04 0.
 ,1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400DOOOOD+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04  0.
 1400000000+04  0.
 1400000000+04  0.
 1400000000+04  0.
 1400000000+04  0.
 1400000000+04 0.
1400000000+04 0.
1400000000+04 0.
1400000000+04 0.
1400000000+04 0.
1400000000+04 0.
1400000000+04 0.
1400000000+04 0.
 .1400000000+04 0
 .1400000000+04 0
  1400000000+04
  1400000000+04 0
 .1400000000+04 0
 1.1400000000+04 0
 .1400000000+04
 .1400000000+04
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0,
 .1400000000+04 0,
 .1400000000+04 0,
 .1400000000+04 0.
 ,1400000000+04 0.
 ,1400000000+04 0.
 ,1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 .1400000000+04 0.
 .1400000000+04 0.
 .1400000000+04 0.
 .1400000000+04 0.
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0
 .1400000000+04 0,
 .1400000000+04 0,
 .1400000000+04 0,
 ,1400000000+04 0.
 ,1400000000+04 0,
 ,1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04  0.
 1400000000+04  0.
 1400000000+04  0.
 1400000000+04 0.
 1400000000+04 0.
 1400000000+04 0.
1400000000+04 0.
1400000000+04 0.
1400000000+04 0.
1400000000+04 0.
 .1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
  1400000000+04
  1400000000+04
  1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 . 1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 ,1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 . 1400000000+04
 .1400000000+04
 .1400000000+04
 .1400000000+04
 . 1400000000+04
 .1400000000+04
 ,1400000000+04
 ,1400000000+04
 ,1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 140000.0000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
 1400000000+04
1400000000+04
1400000000+04
1400000000+04
1400000000+04
EXHIBIT B-lOf.  Temporally and spatially varying matrices of region top heights.
91124r2.42
                                                           B-57
-------
-------
                                    Appendix C

                      OUTPUT FILES FOR TEST SIMULATIONS
    C-l Test #1 Using RPM-IV with the 1991 CBM-IV Chemistry

    C-2 Test #1 Using RPM-IV with the 1988 CBM-IV Chemistry

    C-3 Test #1 RPM-IVSS with the 1991 CBM-IV Chemistry

    C-4 Test #2 Using RPM-IV with the 1991 CBM-IV Chemistry

    C-5 Test #3 Using RPM-IV with the 1991 CBM-IV Chemistry

    C-6 Test #4 Using RPM-IV with the 1991 CBM-IV Chemistry
        (with Point Source Emissions)

    C-7 Test #4 Using RPM-IV with the 1991 CBM-IV Chemistry
        (without Point Source Emissions)
Page

C-3

C-27

C-53

C-79

C-l 11

C-181


C-251
91124r2.28
-------

-------
    The output format for all of the test simulations is nearly self-explanatory.  For each test
    run, model output is divided into three sections:  (a) a list of input variables and
    parameters,  (b) time- and/or downwind distance-dependent concentrations and, if
    applicable, plume geometry data, and (c) a summary of plotted and/or tabular'data
    applicable to the entire simulation.  For the sake of brevity, some portions of the output
    files have been deleted.

    The first page  of output from a test run shows the input variables and parameters read by
    subroutine INPUT.  A comment on the units of AERS concentration output is printed
    whether or not AERS is included in the chemistry module.  The next page or two  of
    output (depending on the size of the chemical mechanism) displays data read by
    subroutine CHEMIN.  The following pages of output indicate the meteorological options
    selected and provide information on time- or downwind-distance-dependent input either
    as input by the user or calculated automatically by the model.  The plume dimensions are
    always displayed,  but are  irrelevant in the case of ambient-only simulations (MODE2 =
    1).  Photolysis rate information and ambient concentration input is provided next  In an
    ambient-only simulation the  background Concentrations should match the initial
    concentrations  read by CHEMIN.  Finally, the parameters governing the summary output
    are displayed.  These consist of the IPLOT, IPRINT, and IMAXC options, the list of
    species for which plots are desired, and the reduction factors for plot ordinates.

    The time- and/or downwind  distance-dependent output presents concentrations of all
    species during the course of the simulation.  The output format is different for ambient-
    only and plume-only simulations.  An internal logical variable (in subroutine OUTPUT)
    may be switched on during an ambient-only simulation to provide instantaneous reaction
    rates concurrently  with the time- or distance-dependent output.

    The summary output is controlled by the last two lines in the input file  Plots may be
    requested of any subset of species. For an ambient-only simulation, it only makes  sense
    to request the plume-average plots and table of peak values.  For plume-only simulations
    plume maxima  (consisting  of the cross-plume maximum cell concentrations) may also be'
    plotted or tabulated.
91124H.28
                                          C-l
-------
-------
                                      Appendix C-l

             TEST #1 USING RPM-IV WITH THE 1991 CBM-IV CHEMISTRY
     The first five pages of the test run contain information concerning the specification of the
     input parameters.  These are followed by panels of concentrations and reactions rates for
     each hour of the simulation. Since this test run is an ambient-only simulation the
     information for cell width and depth is not applicable. At the end of the output file are
     the times series plots of concentrations for species requested. The last page of the output
     provides a table of the maximum concentrations for the specified species.  For example
     the maximum ozone concentration was 0.344 ppm and occurred 125 km downwind at  '
     around 1800 LST (i.e., 440  minutes into the simulation)
91124rl.2S
                                         C-3
-------
-------
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                                      Appendix C-2

             TEST #1 USING RPM-IV WITH THE 1988 CBM-IV CHEMISTRY
    Because of the similarity with the previous simulation, only the front and back parts of
    the output file are shown. The lower number of chemical reactions in the 1988 CBM-IV
    (94, compared to 95 in the 1991  CBM-FV) is shown on the second page of output  The
    different reaction rates and activation energies for reactions 46, 47, and 48 are shown on
    page 3.

    The plots and table of maximum  concentrations show that, for these conditions  the 1988
    version of the CBM-IV produces a higher peak ozone concentration (0.373 ppm) than
    does the 1991 CBM-IV (0.344 ppm). Even though ozone forms at about the same rate
    with either version of CBM-IV, with both reaching the same peak about six hours into
    the simulation, the 1988 CBM-IV ozone concentrations continue to climb slowly
    resulting in a slightly higher peak at  the end of the simulation
91124rl.28
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                                   Appendix C-3
           TEST #1 USING RPM-IVSS WITH THE 1991 CBM-IV CHEMISTRY


     ^nSo^t°fo^heUtPUt ^ f° • ^ ambient~only test ran usmS the RPM-IV is almost
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                                      Appendix C-4

             TEST #2 USING RFM-IV WITH THE 1991 CBM-IV CHEMISTRY
     The program control and chemistry summary portion of the output from the plume-only
     test is similar to test 1 (ambient-only simulation) using RPM-IV and 1991 CBM-IV
     except that 10 horizontal cells and the downwind distances where output is requested are
     specified. The  meteorological output section summarizes the prescribed wind speeds
     plume widths, plume depths, temperatures, and water vapor concentrations, as well as the
     time-varying ambient concentrations.  Following a summary of the plotting options
     selected and the plume cell definitions are the tables of initial plume and ambient
     concentrations,kconcentrations at the specified downwind distances, and the plots of
     results.                                                             *

     Each table of plume and ambient concentrations contains the following: some header
     information (time of output, hour of day, plume width and depth,  wind speed, downwind
     distance (fetch) and NO2 photolysis factor); a table of ambient, plume-average plume-
    average minus ambient, and individual plume-cell concentrations for all 34 CBM-IV
    species and water vapor; and some more summary information on the cell characteristics.

    For this test, plots for NO,  NO2, and O3 were requested.  The plots for ozone indicate
    that plume-average ozone concentrations are less  than the ambient until about 65 km
    downwind (240 minutes), at which point plume-average ozone concentrations exceed
    ambient ozone until about 120 km downwind (420 minutes), where they coincide.

    The last page gives information 6n when the plume touches the ground or the inversion
    base, the validity of the uniform vertical assumption, and a table of maximum plume-
    average concentrations.  Since the plume-rise option was not specified and plume widths
    and depths were  input, it is  assumed both the plume touches both the ground and the
    inversion base and  that the vertical uniformity assumption is valid
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                                      Appendix C-5
             TEST #3 USING RPM-IV WITH THE 1991 CBM-IV CHEMISTRY
     Page 4 of the output from this test summarizes the point-source parameters read and
     hvT^rl   Utine SORCES' ^ Plume Widths *"« dePth* "H*** automaticaUy
     S t  ^1^ ?ummanzed m subsequent pages. Note that the plume depth is
     constncted by the mixing height when PGT plume-expansion curves indicate that the
     plume depth would be greater than the mixing height.
     The summary of the specified plotting parameters also contains the calculated effective
     plume height, 238 m agl.  This is followed by a summary of the simulated^nSSt
     conc!n T118'      %**?** °f ^ °UtpUt Consists of *» toble of P1^ and ambient
     concentrations every 60 minutes and at the five downwind distances (for brevity some of
     «us output was removed) and the summary plots and table of maximum concerns
     ±hTth "* Pto? ^^ ^ RPM-IV'S caPabai|y Of estimating wh^ *e plumf
     touches the ground or the inversion base (within 5  km of the source) and when  the
     vertical uniform assumption is valid (at about 26 km downwind).
91124rl.28
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                                     Appendix C-6

              TEST #4 USING RFM-IV WITH 1991 CBM-IV CHEMISTRY-
                          WITH POINT SOURCE EMISSIONS
    Pages 4 and 5 of the output file display the emission injections including the first
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                                   Appendix C-7

             TEST #4 USING RPM-IV WITH 1991 CBM-IV CHEMESTRY-
                      WITHOUT POINT SOURCE EMISSIONS
    This example output is the same as the example in Appendix C-6 except the point source
    emissions are not included. Thus, only a portion of the output file is presented here.
    The maximum plume-average and cell ozone concentration for this simulation is 60 ppb.
91124r2.28
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                               Appendix D




                    PRELIMINARY MODEL EVALUATION
9U24R1.15
-------
-------
     Jlus appendix presents a preliminary model performance evaluation of the RPM-IV usins
     data from the Midwest Interstate Sulfur Transformation and Transport (MOST)
     measurement program.  Several plume measurement data baseTX revSwed for
     appropnateness for performing this preliminary evaluation of the S
     and none were free of deficiencies.  The MISST data set was selected

             Slf lcir ^ for developing »* ***-. * *•"- Si
            meteorological regimes, and it provided data for evaluating the RPM for four

            EST °ZOnf ' *l°2' N°' a"d S°2' at Sh°uld to noted *at the obttive
                       ° chamcterize Plume ™V»r and aerosol transport and
                ra   ^PPr"1^1 ?frforaiance evaluation-) Although some other data
             the 1975-1976 EPRI Four Comers or the 1979 VISTTA data sets) have better-
    defined plume measurements, most of these are from studies of plumes
        em    ** 10Cati°nS With°Ut *«"*«« *«» other sources.
              Ks         r Ms?
dUnng June tteough August 1976. Aircraft traversal
is''
                                                                          st-
                                                                    bv

91124R2.15
                                       D-l
-------
   Note that because the MISST program was collecting data on both the Labadie and St.
   Louis plumes, the measurements from the two plumes were often intermingled.
   Consequently, the plume-average concentrations from the Labadie Power Plant may have
   frequently been corrupted by emissions from St. Louis and other urban areas in the
   region.  Since the RPM inputs included only the emissions from the Labadie Power Plant
   and not the urban emissions from St. Louis and other sources in the region, this
   evaluation study must be considered extremely preliminary.
   INPUT DATA

   A considerable effort was made during the earlier evaluation of RPM-IZ to extract suitable
   meteorological and plume-parameter data from the raw MISTT data base. Table D-l lists
   the plume input data used in that evaluation as well as the current evaluation.  Note,
   however, that in exercising the RPM-IV the photolysis rates were automatically calculated
   by the model rather than chosen from Table D-l.  The RPM-IV was exercised in the
   MODE2 =3 2 configuration (i.e., plume-only simulation) because hydrocarbon, NOX, and
   SO2 data had been provided as background concentrations for all of the scenarios of
   interest.

   The point source consists of the Labadie Power Plant, located, for model input purposes,
   at 91.0° longitude and 38.5° latitude.  Estimates of NOX, SO2, and hydrocarbon
   emissions as well as background measurements are discussed by Yocke and co-workers
   (1979). In particular, the substantial uncertainties hi characterizing the constituents and
   reactivity of the hydrocarbons measured have been noted.  Hence, the  result of the model
   evaluation should be interpreted with both model uncertainties and measurement
   uncertainties in mind.

   The hydrocarbon speciation  shown in Table D-l is representative of the old CBM-n
   species.  The speciation differs somewhat from that hi the 1991 version of the CBM-n
   species.  The CBM-IV represents hydrocarbon compounds more explicitly than the
   CBM-n. The  aromatics species (ARO) in CBM-n has been subdivided in CBM-H into
   two  classes of aromatic species: toluene (TOL) and xylene (XYL).  The CBM-H
   carbonyl species  (CARB) is  represented hi CBM-IV by two classes of aldehydes:  for-
   maldehyde (FORM) and aldehydes with higher molecular weight (ALD2). For the
   present model  evaluation, the measured hydrocarbon concentrations listed in Table D-l
   were transformed into the CBM-IV species using the carbon-conserving method depicted
   in Table D-2.
   MODEL PERFORMANCE EVALUATION

   Each aircraft traversal through the plume during each' measurement day represents a
   plume-average observation data point to be compared with model predictions.  Of the 16
91124R2.15
-------










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                                                   D-6
-------

    ARO
PARn =
OLEn = OLEQ
TOLn = J AR00
                                          - (8)XYLn - CARB0 *  (6)AROQ
88135 11
                                    D-7
-------
   plume measurement scenarios, a total of 28 traversals were conducted.  Our model
   evaluation is therefore restricted to a sample size of 28. Measurements of SO2 and ozone
   were made on all traversals of the MRI and WU aircraft.  The WU aircraft did not
   measure NOX and sometimes the MRI aircraft only measured NOX or NO, in which case
   NO2 "measurements" had to be deduced assuming a photo-stationary state between NO,
   NO2, and ozone.

   This preliminary model performance evaluation is based on the following measures:

         Scatterplots of predicted versus observed SO2, O3,  NO2, NO concentrations;

         Statistical measures of observations, predictions, and residuals (defined as
         observed minus predicted) for the four species; and

         Scatterplots of the residuals versus downwind distance and scenario.


   Ozone Concentrations

   Predicted and observed ozone concentrations are compared hi Table D-3 and Figure D-l.
   As seen in Figure D-l, the RPM-IV does an adequate job  of replicating the plume-
   average ozone concentrations obtained from the  aircraft traversals.  The bias and gross
   (average absolute) error are about the  same, 11 and 13 ppb. The model tracks the trends
   in the observed ozone concentrations quite well, with a correlation coefficient of 0.75.
   Over 85 percent of the predicted ozone concentrations are within a factor of two of the
   observed values.

   One feature noted hi the scatterplot (Figure D-la) is that the model tends to underpredict
   some of the lower observed ozone  concentrations.  An examination of the residuals as a
   function of downwind distance (Figure D-lc) indicates that these underpredictions occur
   at downwind distances closer to the source (< 50 km). Thus the underprediction may be
   due to the fact that measured data were collected during aircraft traversals that moved in
   and out of the ozone-depleted plume (i.e.,  measured both ambient and plume
   concentrations) resulting hi measured "plume-average" ozone concentrations that are
   higher than would have occurred if ambient air had not been included.  Another possible
   explanation for the RPM-IV underprediction of ozone concentrations hi ozone-depleted
   plumes is the assumption that all species concentrations within  an RPM cell are well
   mixed.  Ozone depletion hi a power plant plume is frequently diffusion- rather than
   chemistry-limited, and diffusion-limited reactions are not considered hi the version of
   RPM-IV that was evaluated.
9U24R2.15
-------

Scenario
.
1
1
1
2
2
2
3
3
4
5
5
6
6
7
8
8
9
10
10
11
11
11
12
13
14
15
15
16
	
Date
(July,
1976)
2
2
2
5
5
5
5
5
. 7
7
7
14
14
14
15
15
18
20
20
23
23
23
28
28
30
30
30
30
~"
Downwind
Distance
(bn)
5.0
69.0
120.0
10.0
27.0
46.0
44.0
73.0
85.0
83.0
108.0
23.0
44.0
46.0
29.0
52.0
26.0
21.0
60.0
25.0
125.0
165.0
51.2
27.0
26.8
12.0
23.0
35.0
—————.
^ MM
Concentration (ppb)
Observed
	 „
46.0
34.0
72.7
41.5
48.5
55.5
55.5
57.2
44.0
44.0
43.0
50.0
51.9
76.0
38.7
59.3
55.3
51.3
71.0
42.8
77.5
91.0
0.0
74.8
62.5
72.3
93.2
112.7
— — 	 	 	
Predicted
^""^"™"™"1™"^™^^^^^^™^™™
33.4
47.3
62.3
37.0
47.7
56.2
18.6
50.3
43.5
41.5
45.0
12.9
28.6
59.6
38.9
53.9
53.9
45.3
62.6
6.5
60.0
85.1
0.0
62.1
25.3
75.7
88.9
62.9
— — — — — _ __
Percent
(100*(Pred.-
Obs.)/Obs.)
-27.4
39.1
-14.3
-10.8
-1.6
1.3
-66,5
-12.1
-1.1
-5.7
4.7
-74.2
-44.9
-21.6
0.5
-9.1
-2.5
-11.7
-11.8
-84.8
-22.6
-6.5
N/A
-17.0
-59.5
4.7
-4.6
-44.2
91124r2.16
                                                        D-9
-------
     VARIABLE-OZONE
     BEGINNING DATE...July 1976
     ENDING DATE...July 1976
     OBSERVATION  SOURCE—OZONE
     OBSERVATION  ANALYSIS—RAPS DATA
     THE PREDICTION ALGORITHM...RPM-IV  OZONE
     AVERAGING TIME-ALL HOURS
     STRATITFYING VARIABLE—RAPS DATA SITES
     SAMPLE SIZE—28
             95.00 -
             72.00 -
          JO
          a.
          a.

          a
          UI
          5  48.00 -
          a:
          a.
             24,00 -
                   I  I  I  I   I  I  I  I  I  I  I  I   I  I  I
                          24.00
                   48.00       72.00
                 OBSERVED (ppb)
                                                          96.00
MOMENTS OF THE PROBABILITY DENSITY FUNCTION
     AVERAGE
STANDARD DEVIATION
     SKEWNESS
     KURTOSIS
 OTHER MEASURES
     MEDIAN
  UPPER QUARTILE
  LOWER QUARTILE
  MINIMUM VALUE
  MAXIMUM VALUE
OBSERVED
57.93571
ON 21.73203
0.12314
0.87610
PREDICTED
46.60714
21.54408
-0.23480
-O.34635
55.3000O
 72.30000
 44.0000O
 0.00000
 112.70000
                              47.30000
                               60.00000
                               33.40000
                              0.00000
                                88.90001
                             SKILL OF PREDICTION PARAMETERS
                             CORRELATION COEFFICIENT OF PREDICTED  •

                             ^SBU0SU^1E^ET°HE cb7R5R0ELAT
-------
  VARIABLE...OZONE
  BEGINNING DATE.-.July 1976
  ENDING DATE...July  1976
  OBSERVATION SOURCE...020NE
  OBSERVATION ANALYSIS...RAPS DATA



                                      S'TES
          0.4
         0.30
         0.20
       CQ
      CO
      Q
         0.10
                  -40.00   -24.00   -aOO    800
                       RESIDUAL (OBS-PRED)

            THE BINSIZE EQUALS  8.000
                                24.00    40.00
RESIDUAL ANALYSIS

      AVERAGE
 STANDARD DEVIATION
      SKEWNESS
      KURTOSIS
  OTHER MEASURES
      MEDIAN
   UPPER QUARTILE
   LOWER QUARTILE
    MINIMUM VALUE
    MAXIMUM  VALUE
 11.32857
  15.31332
 0.94604
 -O.O9671

5.90000
  16.40000
 0.50000
 -13.30000
 49.80000
BIAS CONFIDENCE INTERVAL
AT THE 0.050O LEVEL
LOWER  BOUND 1.4885
UPPER  BOUND 21.1686

STD RESIDUAL CONFIDENCE INTERVAL
AT THE  0.0500 LEVEL
LOWER  BOUND 1588510
UPPER  BOUND 387.9745

THE MEASURES OF GROSS ERROR
                                    RESIDUAL COEFFICIENT OF VARIATION/

                                    RATIO OF RESIDUAL TO OBSERVED*!? DEV
                                                             0.7046

-------
   VARIABLE...OZONE
   BEGINNING DATE..July 1976
   ENDING DATE...July 1976
   OBSERVATION SOURCE-OZONE
   OBSERVATION ANALYSIS—RAPS DATA
   THE PREDICTION ALGORITHM...RPM-IV OZONE
   AVERAGING TIME..,ALL HOURS
   STRATITFYING VARIABLE...RAPS DATA SITES
   SAMPLE SIZE...28  •
       o
       LJ
       (A
       CD
          58.6 -
       8  -
       LJ
       cc
          -24.3 -
          -36.0-
50.00      100.00     150.00
  DOWNWIND DISTANCE (KM)
                                                     200.00
              THE LINEAR MODEL PARAMETERS
              THE CORRELATION IS -0.1967
              THE LOWER BOUND  IS  -0.5309
              THE UPPER BOUND  IS  0.1904
              AT THE 0.0500 PERCENT LEVEL
              THE Y-X LINEAR MODEL INTERCEPT IS 57.865
              THE Y-X LINEAR MODEL SLOPE IS -0.502
              THE X-Y LINEAR MODEL INTERCEPT IS 1 5.351
              THE X-Y LINEAR MODEL SLOPE IS -0.077
FIGURE  D-lc.  Analysis of  ozone concentration  residuals (observed minus
predicted)  as a function of  downwind distance.

                                    D-12
-------
VARIABLE...OZONE
BEGINNING DATE...July 1976
ENDING DATE..July  1976
OBSERVATION SOURCE...OZONF
OBSERVATION ANALYSIS  RAPS'DATA





^-N
2
m
o.
Q
CO
LJ
ce

58.6
46.95
36.52
30.96
24.22
19.35
11.33
3.30
-1.57
-8.30
-13.86
-24.29
-35.99
' '.' ' ' ' ' ' 	 '
. m
CD LTJ _ JTJ n
-
' LTJ
•Q m ° m "
"° m -
mm a Ha
— § — ra_M E.m n
b a CD Q „_ _
n.

1 ' ' ' i i i i i i . . i t i , , , , i-
                     SITE
                                     15.00-
                                               2o.00
         THE LINEAR MODEL PARAMETERS
         THE CORRELATION IS 0.2999
         THE LOWER BOUND  IS -0 0825
                     Sit
                             D-13
-------
   Nitrogen Dioxide Concentrations

   NO2 concentrations are compared in Table D-4 and Figure D-2. The model does an
   excellent job of predicting the trends of the observations, with a correlation coefficient of
   0.96. The bias and gross error are approximately 9 and 13 ppb, respectively.
   Approximately 93 percent of the predicted NO2 concentrations are within a factor of two
   of the observed value.

   Although the model effectively predicts the trends of the NO2 observations and shows no
   systematic bias in predicting the lower (<60 ppb) concentrations, it does tend to
   systematically underpredict the higher observed NO2 concentrations.  As seen in Figure
   D-2 and Table D-4, this underprediction occurs in scenarios 1 and 6 and at downwind
   distances ranging from 5 to 69 km.  Whether this underprediction is due to
   unrepresentative measurement traverses, the presence of additional emissions along the
   plume path, incorrect characterization of NO2 formation, or specification of too-fast
   dispersion cannot be determined at this time.
   Nitric Oxide Concentrations

   Predicted and observed NO concentrations for the 16 scenarios are compared hi Table
   D-5 and Figure D-3.  The model exhibits less ability to predict NO concentrations than to
   predict NO2 concentrations.  The model tends to overpredict the NO and underpredict the
   NO2 concentrations, indicating that the model may be underestimating the NO to NO2
   conversion rate.
   Sulfur Dioxide Concentrations

   Almost all observed plume-average SO2 concentrations are underpredicted by the RPM-
   IV (Table D-6 and Figure D-4).  Since, in the absence of clouds, SO^ oxidation is fairly
   slow, this underprediction indicates that either (1) the measurement does not truly
   represent plume-average concentrations (e.g., may be closer to the centerlirie), (2)  there
   are additional SO2 emissions sources not simulated by the model, or (3) excessively fast
   diffusion rates were used in simulating the plume expansion.  The bias (48 ppb)  and gross
   error (62 ppb) tend to be dominated by the few highest observed SO2 concentrations.
   Only about 50 percent of the model predictions are within a factor of two of the
   observations.
9U24R2.1S
-------
•* - -
Scenario
— — — — — _
1
1
1
2
2
2
3
3
4
5
5
6
6
7
8
8
9
10
10
11
11
11
12
13
14 ,
15
15
16
————___
Date
(July,
1976)
2
2
2
5
5
5
5
5 •
7
7
7
14
14
14
15
15
18
20
20
23
23
23
28
28
30
30
30
30
i
Downwind
Distance
(km)
5.0
69.0
120.0
10.0
27.0
46.0
44.0
73.0
85.0
83.0
108.0
23.0
44.0
46.0
29.0
52.0
26.0
21.0
60.0
25.0
125.0
165.0
51.2
27.0
26.8
12.0
23.0
35.0
—
Concentration (ppb)
Observed
————————
159.6
149.2
79.6
26.9
13.4
13.6
64.6
17.8
13.8
13.8
14.4
128.8
81.0
22.6
19.2
17.5
12.4
21.2 -
24.3
3.1
43.4
38.2
25.4
36.5
16.5
25.2
21.1
66.5
"
Predicted
™— •™«™*™™™-^— _
106.0
87.8
55.5
27.0
16.9
15.0
46.6
31.7
26.8
15.5
14.0
75.5
56.0
21.8
16.6
13.5
15.7
19.5
15.5
26.8
30.4
38.9
6.4
32.4
23.8
27.2
20.9
45.7
. —
Percent
(100*(Pred.-
Obs.)/Obs.)
-33.6
-41.2
-30.3
0.4
26.1
10.3
-27.9
78.1
94.2
12.3
-2.8
-41.4
-30.9
-3.5
-13.5
-22.9
26.6
-8.0
-36.2
764.5
-30.0
1.8
-74.8
-11.2
44.2
7.9
-0.9
-31.3
91124r2.16
                                                       D-15
-------
     VARIABLE...N02
     BEGINNING DATE...July  1976
     ENDING DATE.-July  1976
     OBSERVATION SOURCE...N02
     OBSERVATION ANALYSIS-RAPS  DATA
     THE PREDICTION ALGORITHM...RPM-IV N02
     AVERAGING TIME...ALL HOURS
     STRATITFYING VARIABLE..-RAPS DATA SITES
     SAMPLE SIZE...28
            120.00-
             90.00 -
          a.
          Q.
         5  6O.OO
         UJ
             30.00
                                                                          X
                           30.00      60.00      90.001
                                   OBSERVED (ppb)  '
                                         120.00
MOMENTS OF THE PROBABILITY DENSITY FUNCTION
                OBSERVED
      AVERAGE
 STANDARD DEVIATION
      SKEWNESS
      KURTOSIS
  OTHER MEASURES
      MEDIAN
   UPPER QUARTILE
   LOWER QUARTILE
    MINIMUM VALUE
    MAXIMUM VALUE
41.77143
 42.16977
 1.61245
1.47850

22.6000O
 43.4000O
 14.40000
 3.10000
 159.60000
PREDICTED
  33.19285
   23.92922
  1.50916
 1.59737

  26.80000
   38.90000
   15.70000
  6.40000
    106.00000
SKILL OF PREDICTION PARAMETERS
CORRELATION COEFFICIENT OF PREDICTED
VERSUS OBSERVED  0.962
THE BOUNDS OF THE CORRELATION AT THE
CONFIDENCE LEVEL OF 0.050 ARE
LOW BOUND. 0.919 HIGH BOUND 0.983
RATIO OF OVER TO UNDER PREDICTIONS 0.647
PERCENT OF OVER PREDICTIONS
GREATER THAN 200 PERCENT OF THE
OBSERVED  3.571
PERCENT OF UNDER PREDICTIONS
LESS THAN 50 PERCENT OF THE
OBSERVED  3.571
  FIGURE D-2a.   Scatterplot and model performance statistics  for "plume
  average" RPM-IV predicted and observed NO   concentrations  (ppb).

                                        D-16
-------
  VARIABLE...N02
  BEGINNING DATE...July 19.76
  ENDING DATE...July  1976
  OBSERVATION SOURCE...N02
                                 DATA
                  ..^ N02
 iAMPLEFSI2E V£gIABLE-RAPS  DATA SITES
          0.40
         0.30
         0.20
      co
      Q
         0.10
                   •45.00  -27.00   -9.00    9.00
                        RESIDUAL (OBS-PRED)
                                27.00   45.OO
            THE BINSIZE EQUALS  9.000
RESIDUAL ANALYSIS

      AVERAGE
  STANDARD DEVIATION
      SKEWNESS
      KURTOSIS
  OTHER MEASURES
      MEDIAN
   UPPER QUARTILE
   LOWER QUARTILE
    MINIMUM VALUE
    MAXIMUM VALUE
8.57857
 20.22660
 1.16788
0.79661

0.80000
 18.00000
 -2.00000
 -23.7000O
 61.39999
BIAS CONFIDENCE INTERVAL
AT THE O.O500 LEVEL
LOWER BOUND -7.0125
UPPER BOUND 24.1696

STD RESIDUAL CONFIDENCE INTERVAL
AT THE 0.05OO LEVEL
LOWER BOUND 277.1386
UPPER BOUND 676.8778

THE MEASURES OF GROSS ERROR
THE ROOT MEAN SQUARE ERROR IS 21.64
THE AVERAGE ABSOLUTE ERROR IS 13.62
                                      RcAT         OF RELATIVE VARIABILITY
                                     OBSERVATION COEFFICIENT OF VARIATION

                                     RESIDUAL COEFFICIENT OF VARIATION5
                                                              0 4S42
                                     RATIO OF RESIDUAL TO OBSERVED ST DEV
                                                              0.4796
                                   -i 7
-------
   VARIABLE...N02
   BEGINNING DATE.-.July 1976
   ENDING DATE..July 1976
   OBSERVATION SOURCE...N02
   OBSERVATION ANALYSIS—RAPS DATA
   THE PREDICTION ALGORITHM...RPM-IV N02
   AVERAGING TIME—ALL HOURS
   STRATITFYING VARIABLE...RAPS DATA SITES
   SAMPLE SIZE...28
                                       m
                                   -s-
                        -a-
                                                       i
50.00      100.00     150.00'
  DOWNWIND DISTANCE (KM)
                                                     200.00
               THE LINEAR MODEL PARAMETERS
               THE CORRELATION IS -0.0508
               THE LOWER BOUND  IS -0.4161
               THE UPPER BOUND  IS 0.3286
               AT THE 0.0500 PERCENT LEVEL
               THE Y-X LINEAR  MODEL INTERCEPT IS 53.021
               THE Y-X LINEAR  MODEL SLOPE IS -0.098
               THE X-Y LINEAR  MODEL INTERCEPT IS 9.951
               THE X-Y LINEAR  MODEL SLOPE IS -0.026
FIGURE D-2c.   Analysis of N0_  concentration residuals (observed minus
predicted)  as a function of  downwind distance.
                                   D-18
-------
VARIABLE...N02
BEGINNING DATE...July 1976
ENDING DATE...July 1976
OBSERVATION SOURCE...N02
?ur EnR^IION ANALYSIS...RAPS DATA
IwlDASED4CTION ALGORITHM...RPM-IV N02
AVERAGING TIME...ALL HOURS
             VARIABLE...RAPS DATA SITES
       71.08



       55.63


       41.85

       34.51

       25.61

       19.18


       8.58
      -2.02

      -8.45

     -17.35

     -24.69


     -38.47



     -53.92
                  CD

                  D
CD
           LTJ
                            CD
                      D
                       CD
                 a
                    ~Q-
                                               -§-
                      m a
                                       m
                    5.0O
                              i  i  i  i
                              10.00
                                      -i ~i
                       SITE
                                         15.00'
                                                   20.00
          THE LINEAR MODEL  PARAMETERS
          THE CORRELATION IS -0.2927
          THE LOWER BOUND IS -0.6003
          THE UPPER BOUND IS 0.0903
          AT THE 0.0500 PERCENT LEVEL
          THE Y-X LINEAR MODEL  INTERCEPT IS 8 129
          THE Y-X LINEAR MODEL  SLOPE IS -0069
          THE X-Y LINEAR MODEL  INTERCEPT IS 17 912
          THE X-Y LINEAR MODEL  SLOPE IS -1 239
FIGURE  D-2d.  Analysi
predicted, as .     "
                    of
                               D-19
-------
TABLE D-5. Predicted and observed plume average NO concentration (ppbj from the
Labadie Power Plant using aircraft traverses from the MISTT data base.
Scenario
1
1
1
2
2
2
3
3
4
5
5
6
6
7
8
8
9
10
10
11

*11
12
13
14
15
15
16
Date
(July,
1976)
, 2 •
2
2
5
5
5
5
5
7
7
7
14
14
14
15
15
18
20
20
23
23
23
28
28
30
30
30
30
Downwind
Distance
(km)
5.0
69.0
120.0
10.0
27.0
46.0
44.0
73.0
85.0
83.0
108.0
23.0
44.0
46.0
29.0
52.0
26.0
21.0
60.Q
25.0
125.0
165.0
51.2
27.0
26.8
12.0
23.0
35.0
Concentration (ppb)
Observed
36.0
54.7
11.0
14.8
6.6
3.4
18.4
18.8
6.5
6.5
3.1
26.5
16.6
6.8
6.1
4.0
4.3
8.9 -
8.0
51.2
11.0
9.7
22.6
7.9
8.6
6.0
4.8
8.9
Predicted
53.0
37.6
17.6
15.5
7.0
5.3
43.4
4.6
11.1
7.1 .
5.7
81.0
31.2
7.4
7.2
4.5
4.9
8.5
5.1
29.7
9.3
9.0
39.0
9.9
1.1
7.0
4.5
15.7
Percent
(100*(Pred.~
Obs.)/Obs.)
47.2
-31.3
60.0
4.7
6.1
55.9
135.9
-75.5
70.8
9.2
83.9
205.7
88.0
8.8
18.0
12.5
14.0
-4.5
-36.3
-42.0
-15.5
-7.2
72.6
25.3
-87.2
16.7
-6.3
76.4
91124r2.16
                                           D-20
-------
       VARIABLE...NO
       BEGINNING  DATE..July 1976
       ENDING  DATE...July 1976
       OBSERVATION SOURCE...NO
       OBSERVATION ANALYSIS...RAPS DATA
       THE PREDICTION ALGORITHM...RPM-IV NO
       AVERAGING  TIME...ALL HOURS
       STRATITFYING VARIABLE...RAPS DATA SITES
                          20.00
                                    40.00      60.00
                                  OBSERVED (ppb)
           80.00
MOMENTS OF THE PROBABILITY DENSITY FUNCTION
      AVERAGE
 STANDARD DEVIATION
      SKEWNESS
      KURTOSIS
  OTHER MEASURES
      MEDIAN
   UPPER QUARTILE
   LOWER QUARTILE
    MINIMUM VALUE
    MAXIMUM VALUE
SERVED
13.98929
1 3.40346
1 .83470
2.541 1O
8.600OO
1 6.60000
6.10000
3.10000
54.70000
PREDICTED
1 7.24643
18.66O21
1.76588
2.70870
8.50000
17.60000
5.30000
1.10000
81.00001
                                              SKILL OF PREDICTION PARAMETERS
                           AT ™E
LOW BOUND 0.394 HIGH BOUND 0 834
            124°3°
PERCENT OF UNDER PREDICTIONS
    vee-M  IH                 Performance statistics for  "plume
   average  RPM-IV predicted  and observed NO concentrations (ppb).
                                      D-21
-------
                     VARIABLE-NO
                     BEGINNING DATE—July 1976
                     ENDING DATE...July 1976
                     OBSERVATION SOURCE-NO
                     OBSERVATION ANALYSIS...RAPS DATA
                     THE PREDICTION  ALGORITHM-RPM-IV NO
                     AVERAGING TIME—ALL HOURS
                     STRAT1TFYING VARIABLE-RAPS DATA SITES
                     SAMPLE SIZE...28
                             0.80-
                             0.60-
                           g
                           I
                           1
                           3
                             0.40
                             0.20-
                                      -40.00  -24.00   -8.00   8.00
                                            RESIDUAL (OBS-PRED)
                                                  '  24.00   40.00
                                 THE BINSIZE EQUALS  8.000
                     RESIDUAL ANALYSIS

                           AVERAGE
                       STANDARD DEVIATION
                           SKEWNESS
                           KURTOSIS
                       OTHER MEASURES
                           MEDIAN
                        UPPER QUARTILE
                        LOWER QUARTILE
                         MINIMUM VALUE
                         MAXIMUM VALUE
                     -3.25714
                      13.90900
                      -1.59819
                     4.49794

                     -0.70000
                      0.40OOO
                      -6.60000
                      -54.50000
                      21.50000
BIAS CONFIDENCE INTERVAL
AT THE 0.0500 LEVEL
LOWER BOUND -10.6450
UPPER BOUND 4.1307

STD RESIDUAL CONFIDENCE INTERVAL
AT THE 0.0500 LEVEL
LOWER BOUND 131.0519
UPPER BOUND 320.0787

THE MEASURES OF GROSS ERROR
THE ROOT MEAN SQUARE ERROR IS  14.04
THE AVERAGE ABSOLUTE ERROR IS 7.99

VARIOUS MEASURES OF RELATIVE VARIABILITY
OBSERVATION COEFFICIENT OF VARIATION
                        0.9581
RESIDUAL COEFFICIENT OF VARIATION
                        0.9943
RATIO OF RESIDUAL TO OBSERVED ST. DEV.
                        1.0377
91121,
FIGURE D-3b.   Residual  analysis  plot and model performance  statistics  for

 "plume average" RPM-IV predicted and observed NO concentrations (ppb).

                                    D-22
-------
VARIABLE...NO
BEGINNING DATE..July 1976
ENDING DATE..July 1976
OBSERVATION SOURCE.  NO
OBSERVATION ANALYSIS-RAPS DATA
IwfoA?F^CJION ALGORITHM...RPM-IV NO
AVERAGING TIME...ALL HOURS
             VARIABLE...RAPS DATA SITES
    in
    m
    o
    g
    10
  39.7



  29.1


  19.6

  14.6

  8.5

  4.0

  -3.3

 -10.5

 -15.0

-21.1

-26.1


-35.6



-46.2
                                            TT
                   -ff
                                 m
             '  p
                   50.00      10O.OO     -150.00
                      DOWNWIND DISTANCE (KM)
                                            200.00
          THE LINEAR MODEL PARAMETERS
          THE CORRELATION IS O.1558
          THE LOWER BOUND IS -0.2308
          THE UPPER BOUND IS 0.4999
          AT THE 0.0500 PERCENT LEVEL
          THE Y-X LINEAR  MODEL INTERCEPT IS 53 604
          THE Y-X LINEAR  MODEL SLOPE IS 0.438
          THE X-Y LINEAR  MODEL INTERCEPT IS -6 151
          THE X-Y LINEAR  MODEL SLOPE IS 0.055
       «           °f f/oncentration residuals  (observed minus
       as a  function of  downwind distance.
                               D-23
-------
                    VARIABLE... NO
                    BEGINNING DATE...July 1976
                    ENDING DATE...July 1976
                    OBSERVATION SOURCE...NO
                    OBSERVATION ANALYSIS...RAPS DATA
                    THE PREDICTION ALGORITHM...RPM-IV NO
                    AVERAGING TIME-ALL HOURS
                    STRATITFYING VARIABLE-RAPS DATA SITES
                    SAMPLE SIZE...28
o
LJ
                        tn
39.72



29.10


19.62

14.57

 8.45

 4.03


-3.26
§  -
                        a
                        tn
                        Ld
                        CC
 10.55-

 14.97

-21.09

-26.14
                          -35.61
                          -46.24
                                -m
                                                      m
                                                            m
                                     	Ft
                                       ^n
                                                   -Bm.
                                       m

                                           '°
                                                        m
                                        I  I [T] I  I  I  I  I   I  I - I  I  I  I  I  I  I  I  I  I  I
                                         5.00      10.00       15.0O'     20.00

                                            SITE
                                THE LINEAR MODEL PARAMETERS
                                THE CORRELATION IS 0.1280
                                THE LOWER BOUND IS -0.2575
                                THE UPPER BOUND IS 0.4783
                                AT THE 0.0500 PERCENT LEVEL
                                THE Y-X LINEAR MODEL INTERCEPT IS 7.679
                                THE Y-X LINEAR MODEL SLOPE IS 0.044
                                THE X-Y LINEAR MODEL INTERCEPT IS -6.06.3
                                THE X-Y LINEAR MODEL SLOPE IS 0.372
91121*
                  FIGURE D-3d.   Analysis of NO  concentration  residuals (observed minus
                  predicted) as  a function of scenario.

                                                     D-24
-------
  TABLE D-6.  Predicted and observed plume average SOj concentration (ppb) from the
  Labadie Power Plant using aircraft traverses from the MISTT data base.
Scenario
1
1
1
2
2
2
3 '
3
4
5
5
6
6
7
8
8
9
10
10
11
11
11
12
13
14
15
15
16
Date
(July,
1976)
2
2
2
5
5
5
5
5
7
7
7
14
14
14
15
15
18 •
20
20
23
23
23
28
28
30
30
30
30
Downwind
Distance
(km)
5.0
69.0
120.0
10.0
27.0
46.0
44.0
73.0
85.0
83.0
108.0
23.0
44.0
46.0
29.0
52.0
26.0
21.0
60.0
25.0
125.0
165.0
51.2
27.0
26.8
12.0
23.0
35.0
Concentration (ppb)
Observed
189.0
132.7
8.0
145.8
44.0
30.8
30.8
101.8
18.3
18.3
15.0
395.3
426.1
111.6
82.3
52.5
34.7
80.7
46.0
271.5
32.0
24.0
272.3
100.9
104.8
137.7
89.2
32.3
Predicted
123.0
78.7
15.8
64.9
29.1
26.0
118.0
16.5
22.7
13.8
11.2
289.0
158.0
82.8
28.6
20.4
37.6
32.8
29.4
100.0
26.3
14.3
78.8
34.7
43.2
31.8
26.9
117.0
Percent
(100*(Pred.-
Obs.yObs.)
-34.9
-40.7
97.5
-55.5
-33.9
-15.6
283.1
-83.8
24.0
-24.6
-25.3
-26.9
-62.9
-25.8
-65.2
-61.1
8.4
-59.4
-36.1
-63.2
-17.8
-40.4
-71.1
-65.6
-58.8
-76.9
-69.8
262.2
91124r2.16
                                          D-25
-------
      VARIABLE...SO2
      BEGINNING  DATE.-.July  1976
      ENDING DATE-.July  1976
      OBSERVATION SOURCE...S02
      OBSERVATION ANALYSIS...RAPS  DATA
      THE PREDICTION ALGORITHM...RPM-IV S02
      AVERAGING  TIME—ALL HOURS
      STRATITFYING VARIABLE...RAPS DATA SITES
      SAMPLE SIZE...28
                           60.00      120.00      180.00
                                   OBSERVED (ppb)
                                                         240.00
MOMENTS OF THE PROBABILITY DENSITY FUNCTION-

              •  OBSERVED    PREDICTED
      AVERAGE     108.15710     59.68929
                   110.62520     60.27854
                   1.54154     2.10196
                  1.54684     4.93650
STANDARD DEVIATION
     SKEWNESS
     KURTOSIS
 OTHER MEASURES
     MEDIAN
  UPPER  QUARTILE
  LOWER  QUARTILE
  MINIMUM VALUE
  MAXIMUM VALUE
                  80.70000
                   132.70000
                   30.80000
                   8.00000
                   426.10000
31.8000O
  78.80001
 22.70000
11.20000
  289.00000
SKILL OF PREDICTION PARAMETERS
CORRELATION COEFFICIENT OF PREDICTED
VERSUS OBSERVED  0.770
THE BOUNDS OF THE CORRELATION AT THE
CONFIDENCE LEVEL OF 0.050 ARE
LOW BOUND 0.557 HIGH BOUND 0.888
RATIO OF OVER  TO UNDER PREDICTIONS  0.217
PERCENT OF OVER PREDICTIONS
GREATER THAN 20O PERCENT OF THE
OBSERVED  7.143
PERCENT OF UNDER PREDICTIONS
LESS THAN 50 PERCENT OF THE
OBSERVED  42.857
  FIGURE D-4a.   Scatterplot and model performance statistics  for "plume
  average" RPM-IV predicted and observed SCL  concentrations  (ppb).
                                      D-26
-------
 VARIABLE...SO2
 BEGINNING  DATE...July 1976
 ENDING  DATE.-.July  1976
 OBSERVATION SOURCE...S02
 OBSERVATION ANALYSIS...RAPS  DATA
THE PREDICTION ALGORITHM...RPM-IV S02
 AVERAGING  TIME...ALL HOURS
 STRATITFYING VARIABLE-RAPS DATA SITES
 SAMPLE  SIZE...28
         0.40 -
        0.30-
        0.20-
        0.10-
                 -200.00 -120.00  -40.00  -40.00
                       RESIDUAL (OBS-PRED)

            THE BINSIZE EQUALS  40.000
                              120.00  200.00
RESIDUAL ANALYSIS

      AVERAGE
  STANDARD DEVIATION
      SKEWNESS
      KURTOSIS
  OTHER MEASURES
      MEDIAN
   UPPER QUARTILE
   LOWER QUARTILE
    MINIMUM VALUE
    MAXIMUM  VALUE
48.46786
 74.83524
 0.86875
1.23753

32.10000
 66.20000
 4.50000
 -87.20000
 268.10000
                                        BIAS CONFIDENCE INTERVAL
                                        AT THE 0.0500 LEVEL
                                        LOWER BOUND 7.9574
                                        UPPER BOUND 88.9784

                                        STD RESIDUAL CONFIDENCE INTERVAL
                                        AT THE 0.0500 LEVEL
                                     .   LOWER BOUND 3793.7070
                                        UPPER BOUND 9265.6730

                                        THE MEASURES OF GROSS ERROR
                                        THE ROOT MEAN SQUARE ERROR IS 88.03
                                        THE AVERAGE ABSOLUTE ERROR IS 61.83

                                        VARIOUS MEASURES OF RaATIVE VARIABILITY
                                        OBSERVATION COEFFICIENT OF VARIATION
                                                               1.0228
                                        RESIDUAL COEFFICIENT OF VARIATION
                                                               0.6919
                                        RATIO OF RESIDUAL TO OBSERVED ST.  DEV.
                                                               0.6765


FIGURE  D-4b.  Residual analysis plot and  model performance  statistics  for

"plume  average"  RPM-IV predicted  and observed SO,, concentrations  (ppb).

                                     D-27
-------
   VARIABLE...S02
   BEGINNING DATE...July 1976
   ENDING DATE...July 1976
   OBSERVATION SOURCE...S02
   OBSERVATION ANALYSIS-RAPS DATA
   THE PREDICTION ALGORITHM...RPM-IV S02
   AVERAGING TIME...ALL HOURS
   STRATITFYING VARIABLE-RAPS  DATA SITES
   SAMPLE SIZE...28
      Q
      LJ

      £
      i
 279.7



 222.5


 171.6

 144.4

 111.5
  87.7


  48.5


   9.3

 -14.5

 -47.5

 -74.6


-125.6



-182.8
                                     i  i  i  i
                                                        \  ii  i  r
                       LTJ
                m m
                m
              •a  rfi
 m
m
                                I	.CJ...
               J	I
                        I   I  I  I  I
                                       I  I  I  I  I  I  I   I	i
                       50.00      100.00     J 50.00
                         DOWNWIND DISTANCE (KM)
                                             200.00
              THE LINEAR MODEL PARAMETERS
              THE CORRELATION IS -0.2920
              THE LOWER BOUND IS -0.5998
              THE UPPER BOUND IS 0.0911
              AT THE 0.0500 PERCENT LEVEL
              THE Y-X LINEAR MODEL INTERCEPT IS 59.569
              THE Y-X LINEAR MODEL SLOPE IS -0.152
              THE X-Y LINEAR MODEL INTERCEPT IS 77.648
              THE X-Y LINEAR MODEL SLOPE IS -0.559
FIGURE D-4c.   Analysis  of SO™ concentration residuals (observed minus
predicted)  as .a function of downwind distance.
                                   D-28
-------
    VARIABLE...S02
    BEGINNING DATE...July  1976
    ENDING DATE...July  1976
    OBSERVATION  SOURCE...302
    OBSERVATION  ANALYSIS...RAPS DATA
    THE PREDICTION ALGORITHM...RPM-IV S02
    AVERAGING TIME...ALL HOURS
    STRATITFYING VARIABLE...RAPS DATA SITES
    SAMPLE SIZE...28









Q
LJ
CE
Q.
1
1/1
m
o_
g
Q

Ul
CT





279.71

222.53

171.57
144.41
1 1 1 .48
87.68
48.47
9.25
-14.54

-47.47
-74.64



-125.60
-182.77

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                           SITE
               THE LINEAR MODEL PARAMETERS
               THE CORRELATION IS 0.1167
               THE LOWER BOUND IS -0.2682
               THE UPPER BOUND IS 0.4694
               AT THE 0.0500 PERCENT LEVEL
               THE Y-X LINEAR  MODEL INTERCEPT IS 7 175
               THE Y-X LINEAR  MODEL SLOPE IS 0 007
               THE X-Y LfNEAR  MODEL INTERCEPT IS 34 704
               THE X-Y LINEAR  MODEL SLOPE IS 1.826
FIGURE D-4d.   Analysis of SO   concentration residuals (observed minus
predicted) as  a function of scenario.
                                   D-29
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      CONCLUSIONS
      ™             '    **?*' ^ Preliminary evaluation of the RPM-IV has shown that the
      mode  succeeds in replicating measurement of point-source NOX and ozone levels.  The
      model has demonstrated its usefulness for predicting plume concentration levels
      downwind of isolated sources. However, the model is not intended for use in an urban
      environment or in situations with extensive plume overlap, as may have occurred in some
      of Uiese measurements. Under such conditions, it is recommended that a photochemical
      gnd model, such as  the Urban Airshed Model, be used.

     Further evaluation of the RPM-IV using additional plume data bases is recommended to
     determine the strengths and weaknesses of the model and identify areas that need
     improvement.  Although there have been significant technological advances in plume data
     collection by aircraft, no recent plume characterization measurement studies have taken
     advantage of the new technologies.  Furthermore, although the RPM (and other
     photochemical plume models) have been used to assess the ozone impacts from sources
     that emit hydrocarbons and other reactive organic material, very few plume hydrocarbon
     me^urements have been available for evaluating the performance of these models^
     predicting ozone from hydrocarbon sources.  Further evaluation of the RPM-IV with
     better plume measurements is recommended.
    References
                 ' D-A; Stewart' J- Johnson, R. J. Frost.  1979.  "Evaluation of Plume
           Modehng Techniques for Estimating Short-Term NO2 Concentration Impacts from
                   ^   SyStemS APPUcati°ns, Inc. , San Rafael, California (S YS APP-
          o'--       198°-  "Volume H.  Evaluation
          of Short-Term NO2 Plume Models for Point Sources:  Data Volume." Systems
          Applications, Inc., San Rafael, California (SYSAPP-80/159).
91124R2.IS
                                        D-30
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                          (Please read Instructions on the reverse before ^completing)
4. TITLE AND SUBTITLE
                           2.
  Reactive Plume Model IV (RPM-IV) User's Guide
                                                       3. RECIPIENT'S ACCESSION
  Systems Applications Internationsil  (SAI)
                                                       a. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS   	
  Systems Applications International (SAI)
  101  Lucas Valley Road
  San  Rafael, CA 94903
                                                       10. PROGRAM ELEMENT NO.
                                                                                	
                                                       11. CONTRACT/GRANT NO.
 . SPONSORING AGENCY NAME AND ADDRESS
  U.S. Environmental  Protection Agency  (EPA)
  Technical Support Division  (MD-14)
  Office of Air Quality Planning and Standards
  Research Triangle Park, NC  27711
                                                       13. TYPE OF REPORT AND PERIOD COVERED
                                                       14. SPONSORING AGENCY CODE
              IOTES
                           fa I°anua:l  ?°r,the Reaoti™ Plume Model  iv (RPM-
17- KEY WORDS AND DOCUMENT ANALYSIS
a- DESCRIPTORS
Reactive Plume Model (RPM) ,
Photochemical model,
ozone photochemistry,
VOC/NOx point source modeling
IS. DISTRIBUTION STATEMENT
Release Unlimited
b.lOENTIFlERS/OPEN ENDED TERMS

19. SECURITY CLASS (This Report)
20. SECURITY CLASS (This page;
c. COSATI Field, Group
..
21. NO. OP PAGES
22. PRICE
  Form 2220—1 (Rev. 4—77)   PREVIOUS EDITION
                                IS OBSOLETE
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