&EPA
               United States
               Environmental Protection
               Agency
               Office of Emergency and
               Remedial Response
               Washington DC 20460
               Superfund
Office of Research and
Development
Municipal Environmental Research
Laboratory
Cincinnati OH 45268
                             EPA-540/2-84-001  Feb. 1984
Slurry Trench
Construction for
Pollution Migration
Control

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                                  EPA-5W2-84-001
                                  February  1984
         SLURRY TRENCH CONSTRUCTION

                    FOR

        POLLUTION MIGRATION  CONTROL
  OFFICE  OF EMERGENCY AND  REMEDIAL  RESPONSE
OFFICE OF SOLID WASTE AND EMERGENCY RESPONSE
    U.S.  ENVIRONMENTAL PROTECTION AGENCY
            WASHINGTON, DC 20460
MUNICIPAL  ENVIRONMENTAL  RESEARCH LABORATORY
     OFFICE OF RESEARCH AND DEVELOPMENT
    U.S. ENVIRONMENTAL PROTECTION AGENCY
            CINCINNATI, OH 45268

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                           NOTICE
The information in this document has been funded, wholly or
in part, by the United States Environmental Protection
Agency under Contract No. 68-03-3113 to JRB Associates.
It has been subject to the Agency's peer and administra-
tive review and has been approved for publication as an
EPA document.

This handbook is intended to present information on the
application of a technology for the control of specific
problems caused by uncontrolled waste sites.  It is not
intended to address every conceivable waste site problem
or all possible applications of this technology.  Mention
of trade names or commercial products does not constitute
endorsement or recommendation for use.

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                                   FOREWORD
    This is one of a series of reports being published to implement CERCLA,
otherwise known as Superfund legislation.  These are documents explaining the
hazardous response program and, in particular, the technical requirements for
compliance with the National Contingency Plan (NCP), the analytical and
engineering methods and procedures to be used for compliance, and the back-
ground and documenting data related to these methods and procedures.  The
series may include feasibility studies, research reports, manuals, handbooks,
and other reference documents pertinent to Superfund.

    This handbook provides in-depth guidance on the use of slurry walls for
the control of subsurface pollutants.  It describes how these barriers can be
employed for waste site remediation and presents the theory of their func-
tion and use.  It also describes the essential elements of slurry wall feasi-
bility, design, and construction and presents information on site investiga-
tion, associated remedial measures, maintenance and monitoring, and major cost
elements.  The handbook provides governmental and industrial technical person-
nel with the means of evaluating essential aspects of the application of this
technique to the clean-up of uncontrolled hazardous waste sites.  In conjunc-
tion with other publications in this series, it will assist in meeting the
national goal of a cleaner, safer environment.
                                      111

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                                   ABSTRACT
     This report is intended to provide reviewers of remedial action plans
with the necessary background material to evaluate the portions of the plan
dealing with pollution migration control slurry walls.

     A discussion of the early development and use of slurry trench
construction techniques, both in Europe and the United States is given to
acquaint the reader with the history of the technique.

     An in-depth description of the currently held theories regarding the
functions of bentonite slurries, and the various backfill materials is
presented.  Data on filter cake formation, slurry viscosity, thixotropy, as
well as the effects of cement on the functioning of both slurry and backfill
are included.  Failure mechanisms are also discussed.

     Typical slurry wall configurations are described along with the various
other remedial measures appropriate for use in conjunction with slurry walls.

     After the presentation of the fundamentals of slurry wall use, the
procedures for planning a slurry wall installation are given.  These include,
site investigation procedures for characterizing the surface and subsurface
conditions, as well as waste and leachate characterization.  The factors
considered in slurry wall design are then presented, followed by an outline of
accepted construction practices.  The necessary methods to monitor and
maintain a completed slurry wall are also included, along with the factors
that influence costs.

     The handbook concludes with a series of evaluation criteria that
correspond to the stages of a slurry wall installation.  A Glossary of
commonly used terms is also included.

     This report is submitted in fulfillment of Contract No. 68-03-3113 by JRB
Associates under the sponsorship of the U.S. Environmental Protection Agency.
This report covers the period. April 15, 1982, to July 20, 1983, and work was
completed on July 20, 1983.  •
                                       IV

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                                   CONTENTS
FOREWORD	    iii
ABSTRACT	    vi
CONTENTS	    v
FIGURES	    xii
TABLES	    xv
ACKNOWLEDGEMENTS	    xvii

1.   INTRODUCTION	    1-1
1.1  Purpose of This Handbook	    1~1
     1.1.1  Organization and Use	    1"1
1.2  Background	    1~2
     1.2.1  Slurry Trench Construction Techniques 	    1-2
     1.2.2  History of Slurry Trench Construction	    1-3
            1.2.2.1  Technique Development	    1-4
            1.2.2.2  Applications  	    1-4
1.3  Limitations	    1~5
1,4  Summary	    1-7

2.   THEORY OF SLURRY AND BACKFILL FUNCTION	    2-1
2.1  Bentonite	    2~1
     2.1.1  Rationale for Bentonite Use	    2-2
     2.1.2  Bentonite Properties	    2"2
            2.1.2.1  Swelling and Hydration  	    2-2
            2.1.2.2  Dispersion 	    2"3
            2.1.2.3  Thixotropy 	    2-3
     2.1.3  Factors Affecting Bentonite Performance  ..........    2-3
            2.1.3.1  Montmorillonite Content	    2-4
                     a.  Montmorillonite Crystal Structure	    2-4
                     b.  Theory of Clay Hydration and Swelling.  .  .  .    2-6
                     c.  Theory of Flocculation and Dispersion.  .  .  .    2-10
                     d.  Theory of Gelation  and Thixotropy	    2-10
            2.1.3.2  Relative Sodium and Calcium Concentrations  .  .  .    2-12
            2.1.3.3  Bentonite Particle  Size	    2-13
2.2  Bentonite Slurries  .  ,  	  .....    2-13
     2.2.1  Bentonite Slurry Properties  	    2"13
            2.2.1.1  Viscosity	    2~15
            2.2.1.2  Gel Strength	    2-15
            2.2.1.3  Density	    2-17
            2.2.1.4  Filter Cakes  	    2-17
                     a.  Filter Cake Formation and Function	    2-17
                     b.  Desirable Filter Cake Characteristics.  .  .  .    2-19

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                     CONTENTS  (continued)
2.2.2
             2.2.1.5  Resistance to Flocculation  	
             Factors Affecting Bentonite Slurry Performance
       2.2.2.1
                      Filter Cake Performance,
                          Bentonite Concentration
       2.2.2.2
       2.2.2.3
       2.2.2.4
                      c.
                      d.
                      e.
                      f.
                      g-
                      Gel
Bentonite Quality	
Slurry Mixing Methods.  .  .
Filter Cake Formation Time
Strata Characteristics  .  .
Hydraulic Gradient ....
Slurry Contamination .  .  .
Strength 	
                      Density	
                      Chemical  and Physical Additives	
 2.3   Soil-Bentonite Walls 	
      2.3.1   SB Wall Properties	
             2.3.1.1  Low Permeability 	
             2.3.1.2  Resistance  to Hydraulic Pressure
                      and Contaminants 	
             2.3.1.3  Strength  and Plasticity	
      2.3.2   Factors Affecting  SB Wall Performance 	
             2.3.2.1  Design  Criteria	
             2.3.2.2  Backfill  Composition  and Characteristics
                      a.   Native  Clay  and Bentonite  Content.  .
                      b.   Water Content	
                      c.   Contaminants in Backfill Materials  .
             2.3.2.3  Backfill  Placement Methods  	
             2.3.2.4  Post-Construction Conditions 	
                      a.   Hydraulic  Gradient  	
                      b.   Presence of  Contaminants 	
2.4  Cement  Bentonite Slurries	
     2.4.1  CB Slurry Properties	
            2.4.1.1  Differences  in Physical Properties  .  .  .
            2.4.1.2  Differences  in Setting Times 	
            2.4.1.3  Differences  in Filter Cake Permeability.
2.5  Cement Bentonite Walls  	
     2.5.1  CB Wall Requirements	
            2.5.1.1  Strength	.*  '
            2.5.1.2  Durability  	
            2.5.1.3  Cont inuity	
            2.5.1.4  Set Time  	
            2.5.1.5  Permeability 	
     2.5.2  Factors Affecting CB Wall Performance 	
            2.5.2.1  Slurry Constituents	
                     a.   Bentonite Content	
                     b.   Water  Quality	
                     c.   Cement Content	
 Page

 2-20
 2-20
 2-21
 2-21
 2-21
 2-23
 2-23
 2-23
 2-25
 2-25
 2-27
 2-27
 2-28
 2-28
 2-28
 2-28

 2-30
 2-30
 2-30
 2-31
 2-31
 2-31
 2-33
 2-33
 2-35
 2-35
 2-36
 2-36
 2-36
 2-36
 2-37
 2-37
 2-40
 2-40
 2-40
 2-41
 2-41
 2-41
 2-42
 2-42
 2-42
2-42
2-42
2-43
2-43
                               VI

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                          CONTENTS  (continued)
                     d.  Cement Replacements	     2-43
                     e.  Chemical Additives	     2-46
            2.5.2.2  CB Slurry Mixing Methods	     2-46
2.6  Summary	     2-47

3.   SLURRY WALL APPLICATIONS	     3-1
3.1  Configuration	     3-1
     3.1.2  Vertical Configuration	     3-1
            3.1.2.1  Keyed-In  Slurry Walls	     3-1
            3.1.2.2  Hanging Slurry Walls  	     3-3
     3.1.3  Horizontal Configuration	     3-3
            3.1.3.1  Circumferential Wall Placement  	     3-3
            3.1.3.2  Upgradient Wall Placement	     3-5
            3.1.3.3  Downgradient Wall Placement	     3-5
3.2  Associated Remedial Measures and Practices  	     3-12
     3.2.1  Groundwater Pumping 	     3-12
            3.2.1.1  Pumping Systems	     3-17
                     a.  Well  Points	     3-17
                     b.  Extraction/Injection  Wells  	     3-23
                     c.  Skimmer Systems	     3-24
            3.2.1.2  Groundwater Treatment	     3-26
     3.2.2  Collectors and Drainage Systems	     3-26
     3.2.3  Surface Sealing  .  . . .	     3-27
     3.2.4  Ancillary Measures	     3-28
            3.2.4.1  Grouting  	     3-28
            3.2.4.2  Sheet Piles	l    3-32
            3.2.4.3  Synthetic Membrane Liners	     3-33
3.3  Summary	     3-33

4.   SITE INVESTIGATION AND CHARACTERIZATION	     4-1
4.1  Physical Constraints 	     4-1
     4.1.1  Topography	     4-5
     4.1.2  Vegetation Density	     4-5
     4.1.3  Land Drainage Patterns	     4-5
     4.1.4  Availability of Water	     4-5
     4.1.5  Location of Utility Crossings  .  .  . ;.-.	     4-5
     4.1.6  Proximity to Property Lines  . .  .  .  *	     4-6
     4.1.7  Site Accessibility	     4-6
     4.1.8  Presence of Other Man-Made Features  	     4-6
4.2  Subsurface Investigations	     4-7
     4.2.1  Geology	     4-9
     4.2.2  Hydrology	     4-10
     4.2.3  Soils and Overburden	     4-12
4.3  Wastes and Leachates	     4-13
     4.3.1  Effects of Groundwater Contaminants on SB Walls	     4-14
            4.3.1.1  Effects of Groundwater Contaminants
                     on Bentonite Slurries	     4-14

                                      vii

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                         CONTENT  S   (continued)
            4.3.1.2  Effects of Groundwater Contaminants
                     on  the Permeability  of Cut-Off Walls	    4-15
     4.3.2  Compatibility Testing	    4-18
            4.3.2.1  Viscosity Test  	    4-18
            4.3.2.2  Filter-Press  Test	  .    4-19
            4.3.2.3  Examination of  Bentonite Mineralogy	   '4-19
            4.3.2.4  Permeability  	    4-19
4.4  Summary	    4-22

5.   DESIGN AND CONSTRUCTION	    5-1
5.1  Design Procedures and Considerations  	    5-1
     5.1.1  Feasibility Determination 	    5-2
            5.1.1.1  Waste Compatibility	    5-2
            5.1.1.2  Permeability  and Hydraulic Gradient	    5-2
            5.1.1.3  Aquiclude Characteristics	    5-3
            5.1.1.4  Wall Configuration and Size	    5-3
            5.1.1.5  Cost and Time Factors.	    5-3
     5.1.2  Selection of Slurry Wall Type	    5-3
            5.1.2.1  Permeability  and Hydraulic Gradient	    5-4
            5.1.2.2  Leachate Characteristics 	    5-4
            5.1.2.3  Availability  of Backfill Material	    5-4
            5.1.2.4  Wall Strength	    5-5
            5.1.2.5  Aquiclude Depth	    5-5
            5.1.2.6  Site Terrain	    5-5
            5.1.2.7  Cost	    5-6
5.2  Specification Type and Design Components	    5-6
     5.2.1  Differences in Specification Type	    5-6
     5.2.2  Components of Design	    5-7
            5.2.2.1  Scope of Work	    5-7
            5.2.2.2  Construction Qualifications	    5-7
            5.2.2.3  Construction Requirements of the Trench
                     and Wall	    5-7
            5.2.2.4  Materials	    5-8
            5.2.2.5  Equipment	    5-8
            5.2.2.6  Methods.	    5-8
            5.2.2.7  Quality Control and Documentation	    5-9
            5.2.2.8  Drawings.	    5-9
            5.2.2.9  Measurement  and Payment	    5-10
5.3  Slurry Wall Requirements	    5-10
     5.3.1  Location	    5-10
     5.3.2  Depth	    5-11
     5.3.3  Width and Permeability	    5-11
     5.3.4  Continuity and Verticality	    5-11
     5.3.5  Surface Protection	    5-12
     5.3.6  Materials,  Quality Control and Documentation
            Requirements	    5-13
            5.3.6.1  Dry Bentonite	    5-13

                                     viii

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                         CONTENTS   (continued)
                                                                          Page
            5.3.6.2  Clay 	
            5.3.6.3  Water	
            5.3.6.4  Fresh Slurry 	
            5.3.6.5  In-Trench Slurry  	
            5.3.6.6  Backfill Materials  	
            5.3.6.7  Mixed Backfill  	
                     a.  Slump	
                     b.  Density	
                     c.  Shear Strength  	
     5.3.7  Equipment  	
            5.3.7.1  Slurry Mixing	
            5.3.7.2  Trench Excavation	
            5.3.7.3  Backfill Mixing	
            5.3.7.4  Backfill Placement  	
     5.3.8  Facilities	
     5.3.9  Methods  	
     5.3.10 Safety Procedures 	
5.4  Preconstruction Activities  	
     5.4.1  Slurry Wall Design	
     5.4.2  Cost Estimates	
     5.4.3  Bid Package Preparation  	
     5.4.4  Bid Evaluation and Contract  Award  	
5.5  Soil Bentonite Wall Construction  	
     5.5.1  Preconstruction Assessment  and  Mobilization
            5.5.1.1  Plan Layout	
            5.5.1.2  Equipment Requirements 	
            5.5.1.3  Personnel Requirements 	
     5.5.2  Pre-Excavation Site Preparation 	
     5.5.3  Slurry Preparation and Control	
            5.5.3.1  Testing Bentonite  and  Water.  .  .  .
            5.5.3.2  Slurry Mixing and Hydration.  .  .  .
     5.5.4  Slurry Placement	
     5.5.5  Trench Excavation 	
     5.5.6  Backfill Preparation	
            5.5.6.1  Fines Content	
            5.5.6.2  Slump	-:,  .  .  .
            5.5.6.3  Wet Density	  .  .  .
     5.5.7  Backfill Placement	
     5.5.8  Capping  	
     5.5.9  Clean Up Activities  	
5.6  Cement Bentonite Wall Construction  	
5.7  Diaphragm Wall Construction	
5.8  Potential Problems During and After Construction  .
     5.8.1  Unstable Soil 	
     5.8.2  High Water Table	
     5.8.3  Rock in Excavation	
     5.8.4  Sudden Slurry Loss	
•13
•15
•15
•19
•19
•19
•20
-20
•22
-22
•23
-23
•23
-23
•25
-25
•25
-26
•26
-26
-26
-27
-27
-28
-28
-28
•30
-31
-31
-31
•32
-32
-33
-35
-35
-36
-36
-36
-37
-37
•38
-39
•41
-41
•43
-43
-43
                                      IX

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                          CONTENTS  (continued)


                                                                          Page


             5.8.4.1   Pervious  Zones  	    5-43
             5.8.4.2   Pipes  and Conduits  	    5-44
      5.8.5   Slurry Flocculation 	    5-44
      5.8.6   Trench Collapse	    5-44
      5.8.7   Inadequate  Backfill Placement  	    5-45
             5.8.7.1   Sediments in Trench Bottom 	    5-45
             5.8.7.2   Slurry Pockets  in the  Backfill  	    5-47
      5.8.8   Cracking	    5-47
             5.8.8.1   Conso 1 idat ion	    5-48
             5.8.8.2   Hydrofracturing	    5-48
                      a.   Consolidation	»	    5-50
                      b.   Piezometers	    5-50
                     .c.   High  Hydraulic  Gradients	    5-50
             5.8.8.3   Syneres is	    5-51
      5.8.9   Tunnelling  and  Piping	    5-51
             5.8.9.1   Tunnelling 	    5-51
             5.8.9.2   Piping 	    5-53
      5.8.10  Chemical  Disruption 	    5-53
5.9   Summary.	    5-54

6.    SLURRY  WALL MONITORING AND MAINTENANCE	    6-1
6.1   Effectiveness Monitoring  	    6-1
      6.1.1   Basal Stability	    6-2
      6.1.2   Ground Movement	    6-2
      6.1.3   Groundwater Level  and  Chemistry	    6-4
             6.1.3.1   Groundwater Monitoring	    6-4
      6.1.4   In Situ Permeability  Tests	    6-5
      6.1.5   Surface Water Chemistry	    6-6
6.2  Maintenance	    6-6
6.3  Wall Restoration	    6-8
6.4   Summary	    6-12

7.   MAJOR COST ELEMENTS	     7-1
7.1   Introduction	     7-1
     7.1.1  Developing Preliminary Cost Estimates 	     7-2
            7.1.1.1  Cost Estimation Example	     7-3
                     a.   Feasibility Testing	     7-3
                     b.   Temporary Road Construction	     7-4
                     c.   Site Clearing and Preparation	     7-4
                     d.   Slurry Wall Excavation and Installation.  .  .     7-4
                     e.   Site Re-Grading and Revegetation	     7-8
                     f.   Total Costs	     7-8
7.2  Unit Costs	     7-8
     7.2.1  Feasibility  Testing  	     7-10
            7.2.1.1  Geologic and Soils Testing 	     7-10
            7.2.1.2  Hydrologic Testing 	     7-11

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                         CONTENT S  (continued)
                                                                         Page

            7.2.1.3  Backfill Testing 	    7-11
     7.2.2  Construction Activities 	    7-14
            7.2.2.1  Site Clearing	    7-14
            7.2.2.2  Excavation 	    7-15
            7.2.2.3  Backfilling	    7-15
            7.2.2.4  Borrow  	    7-19
            7.2.2.5  Compaction 	    7-19
            7.2.2.6  Grading	    7-19
            7.2.2.7  Hauling	    7-19
            7.2.2.8  Mobilization and Demobilization	    7-22
            7.2.2.9  Site Dewatering	    7-22
     7.2.3  Completed Wall Costs	    7-22
            7.2.3.1  Monitoring 	    7-25
            7.2.3.2  Maintenance	    7 -25
     7.2.4  Materials	    7-28
     7.2.5  Equipment	    7-28
7.3  Summary	    7-28

8.   EVALUATION PROCEDURES	    8-1
8.1  Site Characteristics	    8-1
     8.1.1  Surface Characteristics 	    8-3
     8.1.2  Subsurface Characteristics	    8-4
     8.1.3  Waste Characteristics	    8-6
8.2  Slurry Wall Applications	    8-6
     8.2.1  Wall Configuration and Type	    8-7
     8.2.2  Associated Remedial Measures	    8-7
8.3  Construction Techniques and QA/QC Requirements 	    8-8
8.4  Monitoring and Maintenance 	    8-9
     8.4.1  Monitoring	    8-9
     8.4.2  Maintenance	    8-10
8.5  Costs	    8-10

MEASURING UNIT CONVERSION TABLE	    9-1
GLOSSARY	    10-1
REFERENCES	    H"1
                                      XI

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                                LIST OF FIGURES
Number

 2-1


 2-2


 2-3


 2-4


 2-5

 2-6


 2-7


 2-8



 2-9


 2-10


 3-1

 3-2

 3-3

 3-4


 3-5
Montmorillonite  Crystal  Lattice,  Showing Adsorbed
   Cations  and  Oriented Water Molecules	
Viscosity  and Weight  of Mud  in  Relation  to  Percentage
  of Bentonites  and Native Clays  in  Fresh Water  .  .  .
Bentonite Particles During Hydration,  Gelation,
  Flocculation  and Dispersion  	
Relationship  Between  Filter  Cake Permeability  and  Slurry
  Viscosity 	

Fluid Loss During Filter  Cake  Formation  	  ,
The Effect of Bentonite Concentration on the  Initial
  Fluid Loss During Filter Cake Formation  	
The Effect of Mixing Techniques and Times on Hydration
  of a 5% Suspension of Ca-Exchanged Bentonite.  .  .  .
The Effect of Added Sand on Filtration of a 5% Suspension
  of a Calcium-Exchanged Bentonite  through a  Fine
  Gravel Bed	

Relationship Between Permeability and Quality of Bentonite
  Added to SB Backfill	
Effect of Plastic and Non-Plastic Fines Content on
  Soil-Bentonite Backfill Permeability	
Keyed-In Slurry Wall	

Hanging Slurry Wall  	

Plan of Circumferential Wall Placement
Cut-away Cross-section of Circumferential Wall
  Placement 	
Plan of Upgradient Placement with Drain
Page


 2-5


 2-9


 2-11


 2-16

 2-18


 2-22


 2-24



 2-26


 2-32


 2-34

 3-2

 3-4

 3-6


 3-7

 3-8
                                      XI1

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                          LIST OF FIGURES (continued)
Number
  5-4     Schematic
3-6

3-7
3-8
3-9
3-10
3-11
3-12

3-13

3-14


3-15

3-16

3-17
3-18
4-1

4-2
5-1

5-2
5-3


Cut-away Cross-section of Upgradient Placement
with Drain 	
Plan of Downgradient Placement 	
Cut-away Cross-section of Downgradient Placement 	
Shape of a Drawdown "Cone" 	
Intersection of a Drawdown Cones of Two Adjacent Wells. . .
Schematic of a Well Point Dewatering System 	
The Effect- of Drawdown in the Absence and Presence of a
Slurry Wall 	 	 	
Well Points Located Behind an Upgradient Slurry Wall,
Cut-Away View 	 	 	
Well Points Located Behind an Upgradient Slurry Wall,


Well Points Located Before an Upgradient Slurry Wall. . . .

Skimmer Systems 	 * 	

Bottom Key Grouting 	
Cut-Off Wall-Dike Contact 	
Rotational Viscometer 	

Filter Press Test Apparatus ..... 	
Typical Backfill Profile in Trench with . Irregular
Bottom 	
Typical Slurry Wall Construction Site 	
Cross-Section of Slurry Trench, Showing Excavation and
Backfilling Operations 	
P-T__ „*-.:„ nf r^t^nf-inna 1 rasf--in-Place DiaDhraem Wall. . .

3-9
3-10
3-11
3-15
3-16
3-18

3-19

3-20



3-22
3-25

3-30

3-31
4-20
4 71

5-21

5-29

5-34
5-42
                                      X1X1

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                          LIST OF FIGURES  (continued)


Number
- '

5-5      Trench Collapse, Showing Plane of Weakness (a) and
           Block Slippage (b)
                                                                       Page
6-1     Groundwater Pumping to Reduce Hydraulic Head Pressure
          on a Slurry Wall
6-2     Wall Breach Due to Localized Chemical Attack ........   6-11

8-1     Flow Chart of the Evaluation Procedures for a Pollution
          Control Slurry Wall ................         8_2
                                   xiv

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                                LIST OF TABLES
Number                                                                 ^S6-


 2-1     Comparison of Sodium and Calcium-Saturated

           Montmorillonites	    2~'


 2-2     Specified Properties of Bentonite and Cement Bentonite

           Slurries	    2~14


 2-3     Common Slurry Materials and Additives	    2-29



 2-4     Typical Compositions of Cement Bentonite  Slurries	    2-38



 2-5     Properties of Soil Bentonite  and Cement Bentonite
                                                                       9—"*Q
           Backfills	    L Jy



 3-1     Summary of Slurry Wall Configurations	    3~13



 4-1     Types of Physical Constraints  and Their Effects  on

           Slurry Wall Construction  	    4-2
 4-2      Principal  Sources  of  Available  Geotechnical  Data  	 *   4-8



 4-3      Soil  Bentonite  Permeability  Increases  Due to Leaching

           with  Various  Pollutants	     ^-1<
  4-4     Increase in the  Permeability of Four Brands of Bentonite

            Caused by Leaching  with Various Pollutants 	     4-17



  5-1     Materials Quality Control Program for SB Walls	     5-14



  5-2     Comparison of Selected Properties of Clays 	     5-16



  5-3     Common Slurry Properties and Testing Methods 	     5-18



  5-4     Excavation Equipment  Used for Slurry Trench
                     •                                                  S —^ ft
            Construction	     -> *•*



  5-5     Materials Quality Control Program for Cement/Bentonite

            Walls.	     5-40



  6-1     Potential Problems Related to Slurry Wall Effectiveness

            and Possible Associated Monitoring Methods 	     6-3
                                       xv

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                           LIST OF TABLES (continued)
                                                                        Page
 6-2       Potential  Causes  for Premature  Wall Deterioration and
           Associated  Maintenance  Techniques ............     6-7

 6-3      Possible Restorative Methods  for  Various  Wall  Failure
           Problems  ......................         6-10

 7-1      Estimated Costs for  Feasibility Testing - Example Site  .  .     7-5

 7-2      Estimated Costs for  Temporary Road  Construction -
           Example Site                                                  _
 7-3     Estimated Costs for Site Clearing and Preparation -
           Example Site ......................     7_g

 7-4     Estimated Costs for Slurry Wall Installation -
           Example Site ....................         7_7

 7-5     Estimated Costs for Site Regrading and Revegetating -
           Example Site ......................     7_g

 7-6     Estimated Total Costs - Example Site ...........     7-9

 7-7     Example Unit Costs for Geologic and Soil Testing -
           Example Site ......................     7-12

 7-8     Example Unit Costs for Hydrologic Testing -
           Example Site ......................     7-13

 7-9     Example Costs  for  Slurry Wall Testing ...........    7-14

 7-10     Example Unit Costs for Site Clearing ...........    7-16

 7-11     Example Unit  Costs  for Excavation .............    7-17

 7-12     Example Unit  Costs  for Backfill ..............    7-18

 7-13     Example Unit Costs  for Borrow ...............    7-19

 7-14     Example Unit Costs  for Compaction .............    7-19

 7-15     Example  Unit Costs  for Grading  ..............    7-22

 7-16     Example Unit Costs  for Hauling  ..............    7_21

7-17     Example Unit Costs  for Mobilization and Demobilization  .  .     7-23

7-18    Example Costs for Site Dewatering .............     7-23
                                     xvi

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                          LIST OF TABLES (continued)
Number

 7-19


 7-20


 7-21


 7-22


 7-23

 7-24

 7-25


 7-26


 7-27
Relation of Slurry Cut-Off Wall Costs per Square Foot
  as a Function of Medium and Depth	
Breakdown of Cost Categories for Cut-Off Trench
  Construction 	
Example Ranges of Unit Costs for Cut-Off Wall
  Construction 	
Example Unit Costs for Monitoring Well and Piezometer
  Installation  	
Example Unit Costs for Slurry Maintenance Activities

Example Unit Costs for Materials  	
Example Operating and Rental Costs for Earthworking
  Equipment	

Example Operating and Rental Costs for Concrete and
  Mixing Equipment  	
Example Operating and Rental Costs  for General
  Construction Equipment  	
Page


7-24


7-26


7-26


7-27

7-29

7-29


7-30


7-32,


7-33
                                      xvi i

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                                ACKNOWLEDGEMENTS
      This document was prepared by JRB Associates for EPA1s Office of Research
 and Development in partial fulfillment of Contract No. 68-03-3113, Task 40-2.
 Dr. Walter Grube, of the Municipal Environmental Research Laboratory, Solid
 and Hazardous Waste Research Division, was the EPA Project Officer.  Philip
 Spooner was Task Manager and principal author for JRB.  Other major contribu-
 tors include Roger Wetzel, Constance Spooner, Claudia Furman, Edward Tokarski,
 Gary Hunt, Virginia Hodge, and Thomas Robinson, of JRB.  Preparation of this
 handbook was aided greatly by the constructive contributions of the following
 reviewers:
      Herbert Pahren
      Douglass Ammon
      Jon Herrmann
      Richard Stanford
      Ann Tate
      Dr.  David Daniel
      S.  Paul Miller
      Nicholas Cavalli
      S.  Geoffrey  Shallard
      George  Alther
      T.  Leo  Collins
U.S.  EPA MERL
U.S.  EPA MERL
U.S.  EPA MERL
U.S.  EPA OERR
U.S.  EPA CERI
Civil Engineer
U.S.  Army COE, Waterways Experiment Station
ICOS  Corporation of America
Engineered Construction International,  Inc.
IMC Corporation
General Electric Company
     The  technical  contributions  of  the  following individuals  were  greatly
appreciated:
     John Ayres
     Robert Coneybear
     David D'Appolonia
     Jeffrey Evans
     Donald Hentz
     David Lager
     Christopher Ryan
     Glen Schwartz
     Enzo Zoratto
GZA Corporation
Engineered Construction International, Inc.
Engineered Construction International, Inc.
Woodward-Clyde Consultants
Federal Bentonite
Case International Company
Geo-Con, Inc.
Engineered Construction International, Inc.
Engineered Construction International, Incu
Appreciation is also extended to the numerous other individuals from Federal,
State and industry organizations who were contacted on matters related to this
handbook.
                                     xvi 11

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                                   SECTION 1

                                 INTRODUCTION
1.1  Purpose of This Handbook
     In recent years, an increased effort has been  focused on  the  problems
caused by the improper land disposal of wastes.  The need to clean, up  thou-
sands of these disposal sites, and the need to  site new, more  secure facili-
ties, has resulted in the innovation and adaptation of  a wide  variety  of
engineered measures  to waste sites and their remediation.  One such engineered
measure is the technique of slurry trenching.   By this  method,  a trench of the
desired configuration is excavated using a bentonite and water slurry  to
support the sides.   The trench is then backfilled with  materials having far
lower permeability than the surrounding ground.  The low permeability  cut-off,
or slurry wall, has  been used as part of the remedial efforts  at both  hazard-
ous  and solid waste  disposal sites.  This handbook was  developed so that  the
use  of slurry walls  for pollution control might be better understood.

     This handbook is intended for use by individuals responsible  for  review-
ing  the scientific and technical aspects of slurry walls used  for  the  control
of pollutants.  These individuals, from federal, state  or local governments,
or from private organizations, may use this handbook to become familiar with
what slurry walls can and cannot be expected to do  to help control pollution
migration.

     This handbook is not intended to replace the services of  a qualified
design engineer, nor is it  intended to make inexperienced construction firms
qualified to install slurry walls.  Both the design and installation of slurry
walls are as much an art as a science, and the  state-of-the-art is evolving
rapidly.
     1.1.1  Organization and Use
     This handbook  is organized  primarily  to meet  the  needs  of  individuals
reviewing the  technical  aspects  of  slurry  walls  included  in  proposed  waste
site remedial  action plans.  These  reviewers will  need to become  thoroughly
familiar with  the entire handbook and  probably  some  of the most commonly cited
references as  well.  These reviewers may wish to follow the  suggested review
procedures given in Section 8 of this  handbook,  or use the handbook contents
to develop procedures better suited to their own needs.
                                      1-1

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     Other users of this handbook may be interested in only certain aspects of
slurry wall use, and can refet to sections on:

     •  Background

     •  Theory

     •  Applications

     •  Related Remedial Measures

     •  Site Characterization

     •  Design and Construction

     •  Monitoring and Maintenance

     •  Major Cost Elements.

     These sections cover nearly all aspects of slurry wall use for pollution
control, and show how complex certain of these aspects are.  Where differences
of opinion exist on scientific or technical points, they are reported with as
much documentation as possible.  Nonetheless, the state-of-the-art in slurry
walls for pollution control is rapidly changing.  At this writing,, a committee
of the American Society For Testing and Materials (ASTM) is beginning to
develop new standards for slurry walls which will replace or modify many of
the standards and procedures in use today.  Measuring units used in the slurry
wall industry are commonly expressed in the International System of Units
(S.I.), except for hydraulic conductivity which is expressed in cm/sec.
Therefore, S.I. units are used here.  A conversion table is included following
Section 8.
1.2  Background
     This section provides a brief overview of slurry trench construction;
what it is capable of, what its limitations are, and its history.
     1.2.1  Slurry Trench Construction Techniques
     As stated earlier, slurry trenching is a means of placing a low permea-
bility, sub-surface, cut-off or wall, near a polluting waste source in order
to capture or contain resulting contamination. ~*These walls are described by
the material used to backfill the slurry trench.   Soil-Bentonite (SB) cut-off
walls are composed of soil materials (often the trench spoils) mixed with
small amounts of the bentonite slurry from the trench.  Cement-bentonite (CB)
cut-off walls are excavated using a slurry of Portland Cement and bentonite
which is left to set, or harden, to form the final wall.  Diaphragm walls are
composed of pre-cast or cast-in-place reinforced concrete panels (diaphragms)
installed using slurry trenching.  Each of these, as well as hybrids of the
three, has different characteristics and applications.
                                     1-2

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     In general, SB walls can be expected to have the lowest permeability,  the
widest range of waste compatibilities, and the least cost.  They also offer
the least structural strength (highest compressibility), usually require  the
largest work area, and are restricted to relatively flat topography.

     Cement-Bentonite cut-off walls can be installed at sites where  there is
insufficient work area to mix and place soil-bentonite backfill, and, by
allowing wall sections to harden and then continuing the wall at a higher or
lower elevation, are adaptable to more extreme topography.  Although CB walls
are stronger than SB walls, they are at least an order of magnitude  more
permeable, resistant to*fewer chemicals, and more costly.

     Diaphragm walls are structurally the strongest of the  three types as
well as the most costly.  Provided the joints between panels are installed
correctly, diaphragm walls have about the same permeability as cement-
bentonite and because of a similarity of materials, about the same chemical
compatibilities.  Because of the higher expense and higher  permeability of
diaphragm walls, they are seldom used for pollution control.

     Combinations of these three major backfill types may be included within
the same wall.  For example, a soil-bentonite backfill may  be used for the
majority of a wall, with cement-bentonite being used for a  portion,  such  as a
road or rail crossing, that requires greater strength.  Being able to combine
the various types of walls makes this technique adaptable to a wider range of
site characteristics.

     Depending on the situation in which they are employed, slurry walls  may
be keyed into an underlying, low permeability zone, such as a clay layer  or
bedrock, or, in the case of floating contaminants, may be only deep  enough to
intercept the upper few feet of the water table.  These "hanging" slurry  walls
have been used to capture and recover floating petroleum products at several
locations.

     A number of other construction techniques can be used  with  slurry walls
to widen their range of applicability.  Among these are grouts,  used to help
key the wall into fractured bedrock; and sheet piles, used  to protect the wall
from stream erosion.  Another technique involves placing a  synthetic membrane
within a cement-bentonite wall to lower its permeability and increase its
resistance to attack by certain chemicals.  This is a newly developed
technique and is not yet documented in the literature.  Also, no cost
information is yet available.
     1.2.2  History of Slurry Trench Construction
     Slurry trench construction originated  over  30  years  ago  in  Italy  and  the
United States.  This technique is now in use  throughout the world  to meet  a
variety of engineering needs.
                                     1-3

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           1.2.2.1   Technique  Development
      Slurry  trench  construction  developed  out  of  the  use  of slurries and muds
 in oil well  drilling operations.   The  early  1900"s marked the  first  use of
 clay mud  suspensions in  the drilling of  oil  wells  (Nash  1976).   The  next 20  to
 30 years  involved investigations of slurry properties, such as  thixotropy, and
 experimentation with additives to  control  the  viscosity  of drilling  muds
 (Xanthakos 1979).   In  1929, bentonite  clays  were  first used in  drilling opera-
 tions to  stabilize  deep  wells in unconsolidated materials and  to bring
 cuttings  to  the surface  (Nash 1976).

      In the  late 1930's, Veder,  in Milan,  Italy, developed the  concept  of a
 continuous diaphragm wall constructed  in a slurry-supported trench (U.S.  Army
 Corps of  Engineers  1978).  This  concept  evolved from  a combination of two
 systems already in  use;  the mud-filled borehole, and  the  continuous  bored-pile
 wall  (Xanthakos 1979).   By the late 1940's,  Veder  tested  structural  slurry
 trenches  and used slurry trenches  in construction of  the  Milan  subway (U.S.
 Army  Corps of Engineers  1978, Winter 1976).

     The  U.S. Corps of Engineers also  used slurry trench  construction in the
 late  1940's.  At Terminal Island in California, the Corps constructed a slurry
 trench backfilled with plastic material  to control salt water  intrusion into a
 freshwater zone (Nash  1974).  The  Corps  also installed slurry  trench cut-offs
 under Mississippi River  levees for control of  underseepage and  piping (U.S.
 Army Corps of Engineers  1978).

     The  1950's marked a period of continuous  development and  improvement of
 the slurry trench technique.  These activities were accompanied  by laboratory
 research  into the supporting properties  of bentonite  in excavations  (Veder
 1963).  In the early 1950's, concrete diaphragm walls were installed at dams
 in Italy  to control seepage flow and support vertical loads (U.S.  Army  Corps
 of Engineers 1978).   In  the United States, a soil backfilled cutoff  trench was
 constructed beneath the  Wanapum Dam in 1959; this represented the  first use  of
 this technique in the United States for  seepage control at a major dam  (Meier
 1978, Jones 1978, Wilson and Squier 1969).

     By the mid-19601s,  slurry trench cutoffs had become  an established method
 for use in earth dam construction  as an  alternative to traditional foundation
methods.  A major improvement in slurry  trench cut-off construction  occurred
 in 1969 with the development of a  self-hardening slurry.   This  slurry is
 termed "coulis" and consists of cement,  bentonite and water.  It  is  used  both
 as a stabilizing fluid for trench  construction and as the cut-off  wall.   The
 slurry hardens in place  to form a  continuous, jointless wall (Soletanche
 1977).
          1.2.2.2  Applications
     Early applications of diaphragm walls were as impermeable barriers below
earth dams in sand and gravel, and water barriers to make reservoirs
                                     1-4

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watertight (Veder 1963).  Slurry trench methods were first adopted in pile and
caisson construction and eventually led to the development of cast-in-place
continuous concrete diaphragm walls (Soletanche 1977).

     The use of slurry trench techniques developed in different directions in
Europe and the United States.  Primary uses of slurry trench techniques in
Europe were the construction of structural walls and load bearing foundations
(U.S. Army Corps, of Engineers 1978).  Additionally, European slurry trench
methods generally involved cement-bentonite cut-off walls (Miller and Salzman
1980, Sommerer and Kitchens 1980).  In the United States, slurry trench appli-
cations have been oriented toward earth-filled cut-offs for seepage control
and dewatering purposes (U.S. Army Corps of Engineers 1978).

     In many cases, slurry walls were initially used as temporary structures
with the permanent structure built inside (Regan 1980).  Diaphragm walls were
considered dangerous as permanent structures because of their relative
rigidity, susceptibility to cracking, and ability to induce cracking of earth-
fill due to differential settlement.  However, the development of procedures
and materials to construct jointless, continuous diaphragm walls that are
impermeable and have physical characteristics compatible with earth materials
has led to the use of slurry walls as permanent structures (Soletanche 1977).

     There are many applications for use of slurry walls for seepage control
and for groundwater diversion during site dewatering.  Present applications of
slurry trench construction include:

     •  Retaining structures

     •  Load-bearing elements

     •  Underground facilities, transit stations, tunnels, etc.

     •  Docks and waterfront installations

     •  Cut-offs under dams

     •  Repair of leaky dams

     •  Pollution migration control.

     For pollution control, slurry trenches have been constructed to control
sewage, acid mine wastes, chemical wastes and sanitary landfill  leachate  (Ryan
1980a).  Slurry cut-off walls have also been constructed to control the
lateral movement of oily wastes.  As of 1980, approximately 10 slurry cut-off
walls have been constructed as  spill control barriers (Ryan 1980b).
 1.3  Limitations
      Slurry walls have been  installed  to  retard  the movement  of  groundwater
 and  leachate  at numerous waste  sites.   These walls have  been  constructed  at
 sites having  widely divergent geologic, hydrologic, climatic  and demographic
 characteristics.  Slurry cut-off walls  are  applicable  to numerous situations
                                      1-5

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 involving hazardous wastes.  They  are not, however,  an  answer  to  all  waste
 site problems.

     Slurry cut-off walls are not  impermeable,  and  some leakage  through them
 is inevitable.  Permeability values range  from  less  than 10    cm/sec  for a
 well designed SB wall, to over 10  cm/sec  for a CB  wall.   For  this  reason, and
 the fact that they are usually less costly,  SB  walls  are the most commonly
 applied to waste site remediation.

     A second limitation to the use of  slurry cut-off walls is that exposure
 to the wastes at some sites may cause increases  in  wall permeability.   Wall
 failure may occur if the slurry wall is not  designed  or installed well  enough
 to withstand exposure to the chemical constituents  of the  permeating  solutions
 or the hydraulic gradients at the  site.  Certain chemicals have been  shown to
 have pronounced effects on both bentonite  and Portland  cement, and  even brief
 exposure of some walls to high strength leachates can seriously threaten their
 integrity.

     The use of slurry walls is also limited by  the  need for heavy  construc-
 tion equipment, sufficient maneuvering  area  and  suitable access.  At  some
 disposal sites, the degree of complexity in  the  design  and installation of a
 slurry wall caused by site conditions may  reduce its  viability as a remedial
 alternative.  For example, if a disposal site was located  in a congested urban
 area, the cost of the added design and  construction  effort needed to  deal with
 nearby cultural features or other obstruction,  could  make  some other  alterna-
 tive, such as excavation and secure reburial, more  attractive.

     Slurry walls will seldom, if ever, be the  only  remedial measure  applied
 to a site.  They are usually accompanied by  other measures, such  as surface
 sealing, or drains and collectors, as part of an overall  engineered solution
 to the site's problems.  Some of these measures  can  extend the effectiveness
 of the slurry wall beyond what it would be without  them.   For  example,  if a
 waste site were to be surrounded by a slurry wall,  and  the site dewatered by
 capping and pumping, the net flow of groundwater would  be  toward  the  interior
 of the wall.  In this way, some waste/wall compatibility problems can be over-
 come because the wall is being permeated with groundwater  and  not leachate.
 The amount of leachate in. the enclosed  area  is greatly  reduced, and the life
 expectancy of the wall is increased.  Also,  an extraction  well or drain net-
work can act as a back-up containment measure if, for some reason,  the  wall is
breached.

     Most of the slurry walls that have been installed  for pollution  control
have been in the private sector, and the majority have  been in place  for a
 relatively short time.  In most cases,  the firms for  which these  walls  have
been installed are not willing to provide  the monitoring data  that  are  needed
 to evaluate the performance of pollution control slurry walls.  Slurry  cut-off
walls used in other applications, such as dam projects,  have yielded  enough
data to evaluate short and long term geotechnical performance.  Long  term
 performance of the walls in the presence of  chemical  contaminants,  however, is
not as well documented.  The best indications of the  ability of slurry  walls
 to withstand chemical degradation over  time  comes from  laboratory studies.
                                     1-6

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These studies have begun to better define the range of chemical compati-
bilities but have not, and may never, replace the need for extensive,  site
specific testing and long term monitoring.
1.4  Summary


     This handbook is intended to provide reviewers of  remedial  actions  with
the means of evaluating technical aspects of  slurry walls.  Although  these
groundwater cut-off barriers have been  in use for  decades,  the  last several
years have seen a rapid increase in  their use for  pollution control.   Although
slurry walls are versatile and adaptable control measures,  they  are not  suited
to all waste sites or waste types.
                                      1-7

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                                    SECTION  2

                    THEORY OF  SLURRY AND  BACKFILL  FUNCTION
     During construction of  slurry walls,  a  slurry containing  bentonite is
placed  in the open  trench  to  support  the  trench  walls.   After  excavation is
completed, a mixture of bentonite slurry  and soil,  or  a mixture  of cement,
bentonite, and water is placed  in the  trench to  form the completed wall.  To
become  familiar with slurry  trench construction  techniques,  it is  helpful to
understand several  key theoretical considerations.   These can  best be  pre-
sented  in the five  questions  listed below.

     •  Why is bentonite used in slurries  and cut-off  walls, and how can
        bentonite1s behavior  in slurries  be  explained?

     •  What factors affect bentonite  slurry properties?

     •  What factors affect  soil-bentonite wall  performance?

     •  What factors affect cement bentonite slurry properties?

     •  What factors affect cement-bentonite wall  performance?

     Each of these  questions  is addressed  in this  section.  The  theoretical
aspects of slurry functioning and slurry wall performance are  emphasized.   The
practical applications of  these theoretical  aspects  are  presented  in the
Design  portion of Section  5.


2.1  Bentonite
     Bentonite is a soft, soapy-feeling rock found  in commercial quantities  in
several areas of the United States.  The rock is composed primarily of  the
clay mineral montraorillonite or smectite, as it is  frequently called, with
about 10 percent impurities, such as iron oxides and native sediments (Boyes
1975).  Finely ground bentonite is mixed with water to  form the slurry  that  is
kept in the trench during excavation.  Although there have been attempts  to
use locally available native clays in place of commercial bentonites, the
evidence presented below illustrates why these attempts have not met with
great success.
                                     2-1

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     2.1.1  Rationale for Bentonite Use


     The bentonite performs two functions when used in slurry trench construc-
tion.  First, it coats the sides of the trench with a thin, slippery layer
called a filter cake.  This low-permeability layer minimizes slurry seepage
out of the trench and groundwater seepage into the trench.  It also forms a
plane against which the weight of the slurry can push against the  trench
sides.  The lateral pressure of the slurry against the filter cake on  the
trench walls holds the trench open.  Thus, the first function of the bentonite
in the slurry is to form the filter cake.

     The second function of the bentonite is to maintain  slurry density.  The
bentonite particles must not settle out of the water and  the slurry must hold
in suspension small particles of soil that inadvertantly  fall into the slurry
during excavation.  The density of the bentonite is only  slightly higher than
that of the water.  The density of the trench spoils is,  however, much higher.
When the slurry holds particles of trench spoil in suspension, the density of
the slurry is increased.  The reason the slurry must be denser than water is
that a higher density slurry pushes against the trench walls with greater
force and assists in maintaining trench stability, particularly where
groundwater levels are high (Xanthakos 1979).


     2.1.2  Bentonite Properties


     The major properties of bentonite that are of interest in slurry  trench
construction are:

     •  Swelling and hydration

     •  Extensive dispersion

     •  Thixotropy.

These properties are expressed when bentonite comes in contact with water.


          2.1.2.1  Swelling and Hydration


     When finely ground bentonite  is mixed with water, both the  exterior  and
interior of the particles become wetted.  Water becomes attached  to the sur-
faces of the clay particles in the bentonite through electrochemical  inter-
actions that will be described in  detail later in  this section.  Water also
penetrates the interior of the clay particles and  forces  each clay particle  to
expand in volume, or swell.  In addition, the cations  that are associated with
the clay particles become hydrated.  Thus the water reacts with  both  the
exterior and interior clay surfaces as well as the associated cations.  As  a
result, the bentonite increases in volume.  Dry bentonite can  swell  as much  as
10 to 12 times its original volume when wetted (Case 1982).  This  swelling
                                      2-2

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continues until the bentonite is fully hydrated, which can take as long as a
full week (Boyes 1975).


          2.1.2.2  Dispersion


     The surfaces of the clay particles in bentonite are predominately
negatively charged.  When two of these clay surfaces are in close proximity to
one another, they repel each other due to long-range coulombic  forces (Mustafa
1979).  The causes of  this repulsion will be discussed in Section 2.1.3.1.
The effect of this repulsion is that the clay particles remain  for the most
part dispersed throughout the slurry.  This dispersion allows the intimate
mixture of bentonite and water to be maintained.
          2.1.2.3  Thixotropy


     When a mixture containing 5 percent by weight bentonite  and  95  percent
water is allowed to stand undisturbed  for a few minutes,  it changes  from  a
viscous solution to a gel-like substance.  When agitated  or vibrated,  the gel
reverts to a slurry.  The gel will reform each time  the agitation ceases.
This behavior  is the result of a property called  thixotropy.

     Thixotropy is important in slurry trench construction because the gel
structure is what keeps  the particles  of trench spoils  in suspension in the
slurry.

     Thixotropy is measured by determining how strong of  a gel  structure  is
formed over a  set period of time.  As  the strength of the gel structure
increases and  the speed  of gel formation increases,  the degree  of thixotropy
is said to increase.  The strength of  the gel structure (called the  gel
strength) is measured using a Fann Viscometer.  Measurements  are  taken at 10
seconds and 10 minutes.  In a high quality bentonite, the 10-minute  gel
strength should be only  slightly higher than  the  10  second gel  strength
(Boyes 1975).


     2.1.3  Factors Affecting Bentonite Performance


     Because bentonite is a natural, rather than  manmade  substance,  its
quality, and therefore its performance, is  likely to vary from deposit to
deposit.  Several factors influence  the performance  of  bentonites in slurry
trench construction.  These factors  include:

     •  Montraorillonite  content and  properties
     •  Relative sodium  and calcium  concentrations
                                      2-3

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      •   Fineness  of  grinding  of  the  raw material
      •   Chemical  additives.


           2.1.3.1  Montmorillonite Content


      As  mentioned previously, bentonite contains  about  90  percent  montraoril-
 lonite and  10 percent  impurities  (Boyes 1975).    Montmorillonite,  or  smectite,
 is the crystalline material that  gives  bentonite  its  unique  properties.   To
 understand  the behavior of this mineral,  it  is necessary to  know its  general
 structure  and some of  the interactions  between montmorillonite  crystals,  water
 molecules,  and cations.  A description  of montmorillonite  structure is given
 below, followed by a detailed discussion  of  clay-water  and clay-cation
 interactions as they affect the physical  properties of  raontmorillonite.


               a.  Montmorillonite Crystal Structure


      Crystals of this  clay are composed of three  distinct  layers,  as  shown in
 Figure 2-1.  The outer layers are a  tetrahedral arrangement  of  silicon and
 oxygen molecules.  Some of the silicon  atoms  in these layers have  been
 replaced by aluminum.  Sandwiched between the silica  layers  is  a layer of
 aluminum atoms surrounded by six hydroxyl or oxygen atoms  in an  octahedral
 shape.   Some of the aluminum atoms in this layer  have been replaced by
magnesium.  Because of the substitutions  in  the three layers, unsatisfied
 bonds exist within the crystal, resulting in a high net negative charge.  To
 satisfy  this charge, cations and water molecules  are adsorbed onto the
 internal and external  surfaces of the clay crystals.  These  surfaces  comprise
 the exchange complex of *the clay.  The  types of cations adsorbed on the
 exchange complex have  a great influence on the properties  of the clay (Brady
 1974).

     The characteristics of bentonite slurries are caused  to a  large  extent by
 the properties of the montmorillonite they contain.  As described  previously,
 three sets of properties are particularly relevant to slurry function.  These
 are:

     •  Degree of hydration and swelling

     •  Flocculation and dispersion characteristics
     •  Gel strength and thixotropy.

     The extent to which these montmorillonite properties are expressed varies
considerably,  depending on the types  of cations adsorbed to the  surface of the
clay.   Although numerous  cations and  organic molecules can be adsorbed, two
cations are of primary interest in slurry trenching situations.  These are
sodium and calcium.
                                     2-4

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                                       Figure 2-1.
        Montmorillonite Crystal Lattice, Showing Adsorbed Cations
                           and  Oriented Water Molecules
                                        Outer Limit of Adsorbed
                                          Water Surrounding
                                          Other Clay Crystals
 Oriented
 Water
Molecules
 Cloud of Additional
  Water Molecules
   Less Oriented
 Than Those Directly
Contacting the Crystal
                   Cations
Note: Not to Scale
Source: Based on Grim, 1968
                                           2-5

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     Sodium-saturated montmorillonites behave  quite differently  than  the
calcium-saturated varieties.  These differences  are summarized  in Table 2-1.
Theories governing the reasons for these differences  are  described  in detail
below.
               b.  Theory of Clay Hydration and Swelling


     During hydration of montmorillonite, water molecules  are  adsorbed  to  the
clay crystal surface by the attraction between the hydrogen  atoms on  the water
molecules and the hydroxyls or oxygens on the outer clay surface and  in
between the silicate layers.  This is illustrated in Figure  2-1.  The adsorbed
water is held so strongly by the clay that it may be thought of as a  non-
liquid, or a semi-crystalline substance.  Even the water molecules that do not
directly contact the clay surface are influenced by the montmorillonite
crystals.  This is because the water molecules that are bonded to the clay
surface form partially covalent bonds with a second layer  of molecules.  In
addition, the second layer of water molecules forms partially  covalent  bonds
with a third layer, which bonds to a fourth layer, and so  on.  The water in
these layers surrounding the crystal surface is oriented,  forming what  may be
thought of as a semi-rigid structure (Grim 1968).

     The number of layers of water molecules and the regularity of their
configuration is dependent upon the types and concentrations of cations
associated with the clay.  The cations tend to disrupt water adsorption, and
the degree of disruption depends on the size of the hydrated cation,  its
valence, and its tendency to disassociate with the clay surface during
hydration (Grim 1968).

     Sodium ions disrupt hydration much less than calcium  ions.  For  example,
sodium-saturated montmorillonites have been found to influence the orientation
of water molecules more than 100 Angstroms from their crystal  faces.  This
corresponds to about 40 molecular layers of water.  In contrast, calcium-
saturated montmorillonites have much smaller spheres of influence, on the
order of 15 Angstroms, or about 6 molecular layers of water  (Grim 1968).

     The observable effects of these sub-microscopic interactions are that
sodium montmorillonites adsorb much more water and swell far more than  do
calcium montmorillonites.  As a result, as the amount of sodium on the
exchange complex of montmorillonite increases, the amount  of swelling
increases (Rowell, Payne and Ahmad 1969).  In addition, a  5 percent solution
of highly hydrated sodium montmorillonite has a much higher viscosity than a
5 percent calcium montmorillonite solution.  In fact, a 5  percent solution of
sodium bentonite in water can exhibit a viscosity of 15 centipoise, but it
takes 12 percent calcium montmorillonite in a solution to  obtain the  same
viscosity (Grim and Guven 1978).  This is illustrated in Figure 2-2.
                                     2-6

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                                   TABLE 2-1

          COMPARISON  OF  SODIUM AND CALCIUM-SATURATED MONTMORILLONITES
Parameter
Sodium-Saturated
Montmor i11on i t e
Calcium-Saturated
Montmorillonite
Swelling upon hydration,
  cm /g of clay
Hydration rate, 5%
  solution  (2)
Cation exchange
  Capacity, meq/lOOg.

Degree of thixotropy

Liquid limit

Plastic Limit (4)

Yield in barrels of 15cP
  drilling mud per ton
  of clay (4)

Percentage of clay by
  weight in water to
  produce a 15cP
  colloidal suspension (4)
11 (1)
(Wyoming sodium
bentonite)

Hydrated to~9cP
in 10 min., stabilized
at 9.2cP by 20 min.

3% solution of polymer
treated sodium bentonite
hydrated to 17.2cP in
10 min., then stabilized,
80-150 (3)

high (2)

300-700 (4, 5)

75-97


125
2.5 (1)
(4 base-exchanged
bentonites tested)*

hydrated to  ^13cP in
10 min., stabilized
at  ~14 to 18 cP in
4 hours.*
60-100 (2)

low (6)

155-177 (4)

65-90


18-71
                                     2-7

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                                    TABLE 2-1

           COMPARISON OF SODIUM AND CALCIUM-SATURATED MONTMORILLONITES
                                 Sodium-Saturated         Calcium-Saturated
Parameter                        Montmorillonite          Montmorillonite
Permeability  of  a 9:3
  quartz  to clay mixture-       2.76 x  10                7.2  x  10~7
  (cm/sec) (4)

Permeability  of  a 7:3
  lartz to clay
  (cm/sec) (4)
                                        — If)              -       —R
quartz to clay mixture          5.0 x 10                3.5 x 10
*Base-exchanged bentonites are calcium bentonites  that have been  treated with
 sodium compounds to increase their adsorbed sodium content.  They are
 commonly used in European slurry trenching construction  (Boyes 1975).

References:  (1) Baver, Gardner and Gardner 1972,  (2) Boyes 1975, (3) Grim
 1968 (4) Grim and Guven 1978, (5) Xanthakos 1979, (6) Case 1982.
                                     2-8

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                                      Figure 2-2.
Viscosity  and Weight of Mud in Relation to Percentage of Bentonites
                and Native Clays in Fresh Water
                 8.58.6  8.8   9.0   9.2   9.4  9.6   98   10.0  10.2  TO*
                         Attapulgite
                           Sodium
                        montmorillonite
   Calcium
montmoriHonite
                                    Range of Typical
                                      Native Clays
                    M   30  40  go 93 TO  80  90  100 110
                                    Pounds of Clay per Barrel*
                                15     20      &      *>
                                   Percentage of Day by Weight*
                 200 100 65  50  40 35 30   25     20  18    «  15
                                Yield in Barrels of Mud per Ton of
               •Clay Specific Gravity Assumed to be 2.50.

               Copyright 1978 by Eisevier Scientific Publishing Company. Used with Permission
                                             2-9

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                c.   Theory of Flocculation and Dispers
                                                   ion


                           ;
  are  attracted  to the cations
                                                         of anioas  that

reduced, face-to-face contact ca
        ."  (See
                             can ocur  and
                                     '   "
                                                                        s
                                                  .
                                                  -bf ween
                                              Particles can  form "packets,"
 rst
                          •

.«„
             d.  Theory of Gelation and Thixotropy
suspension to
                                      "  "'  'bility °f the
                                 2-10

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                                                 Figure 2-3.
                    Bentonite Particles During Hydration, Gelation, Flocculation,
                                             and Dispersion
        Dry
                            Flocculation
                                                      Partly Hydrated
                                                                     Breakdown of Get Structure
                                                                       as a Result of Agitation
Dispersion Caused by Phosphates
 Replacing Positive End Charges
      with Negative Ones
Source: Boyes, London 1975

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a "house of cards" structure between positively charged clay particle edges
and negatively charged clay faces, as illustrated in Figure 2-3 (Xanthakos
1979).  In practice, the gelation of the bentonite slurry provides support for
small particles of soil to remain in suspension rather than to sink to the
trench bottom (Boyes 1975).

     'The amount of thixotropy is determined by measuring the gel strength of
the slurry.  The gel strength is "the stress required to break up the gel
structure formed by thixotropic buildup under static conditions" (Boyes 1975).
It is measured using a Fann viscometer, as described in Section 4.  The
difference between the gel strength 10 seconds after agitation and the gel
strength after standing for 10 minutes is a measure of the slurry's thixotropy
(Xanthakos 1979).

     Measurements of 10 minute gel strengths of bentonite slurries can range
from about 5 to 20 Ib/ft  and average 10 to 15 Ib/ft  (Xanthakos 1979).

     The bentonites used during slurry trench construction behave essentially
like the sodium saturated raontmorillonites described above.  The properties of
hydration, flocculation, dispersion and gel strength that are exhibited by the
slurries are a result of the interactions of montmorillonite crystals, water
molecules, and cations.  The ability of a bentonite slurry to perform its
functions during slurry trench construction is dependent on these
interactions.
          2.1.3.2  Relative Sodium and Calcium Concentrations
     Natural sodium bentonite from Wyoming is commonly used  in many of  the
slurry trenching operations in the United States.  These bentonites do  not
contain pure sodium montmorillonite.  One bentonite was reported  to contain
60 percent sodium on its exchange complex, with the remaining sites being held
by calcium and magnesium.  However, the average distribution of cations on
Wyoming bentonite is somewhat different.  Most of  the Wyoming bentonite
currently being sold contains an average of 38 to  50 percent sodium,  15 to
35 percent calcium and 10 to 30 percent magnesium  (Alther  1983).

     High sodium bentonites should be more effective than  the low sodium
grades in many situations.  At sites where a high  concentration of calcium
salts occurs in the soil or groundwater, or where  cement bentonite slurries
will be used, higher sodium bentonites are particularly recommended,  for the
reasons described below.  The detrimental influence of the calcium from the
cement or the groundwater on the sodium bentonite  can be substantial.   This  is
due to the strong attraction between calcium ions  and montmorillonite
crystals.  Because this attraction is so strong, calcium ions can easily
displace sodium ions on the clay.  The ease of replacement of sodium  by
calcium increases as the concentration of calcium  in the solution and on the
clay surface increases.  After about 30 percent of the exchange sites on the
clay surface become occupied by calcium, the bentonite acts  more  like calcium
montmorillonite than the sodium variety (Grim 1968).
                                      2-12

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     Because there are limited quantities of natural  sodium bentonites,  some
areas are forced to use specially treated calcium bentonites  instead.  This
occurs most frequently in Europe.  These calcium bentonites are exposed  to
sodium-containing materials such as sodium hydroxide  to  force  some of  the
calcium ions off of the exchange complex of the montmorillonite and  then
replace them with sodium ions (Grim 1968).  Sodium carbonate,  which  is less
expensive and more effective than sodium hydroxide, is also used  on  some
bentonites (Alther 1983).   As long as there is less  than  30  percent calcium
and at least 50 percent sodium on the exchange complex of  the  montmorillonite,
the material will act essentially like a sodium montraorillonite (Grim  1968;
Shainberg and Caiserman 1971).
          2.1.3.3  Bentonite Particle Size
     This purely physical parameter can  influence  the  performance  of  the
bentonite in a number of ways.  Finely ground bentonite has  a  larger  surface
area per unit weight than coarser bentonite because  as particle  size
decreases, surface area per unit weight  increases.   The increased  surface  area
of the finer particles allows the bentonite to hydrate more  readily and  form  a
gel structure more quickly than coarser  particles  of the  same  bentonite.   Thus
the average particle size of the bentonite can affect  its  performance in the
slurry.  Typically, the types of bentonite that  are  recommended  for slurry
trenching have been pulverized to yield  particles  small enough so  that 80
percent will pass through a number 200 mesh sieve  (Federal Bentonite  1981).
2.2  Bentonite Slurries'
     The Wyoming bentonites most commonly used  in  slurries  are mixed  at  a  rate
of from 4 to 7 percent bentonite in 93 to 96 percent water  (Boyes  1975).   This
muddy mixture stabilizes the sidewalks of the open trench during excavation.
The properties of a well-functioning slurry and  the  factors  that affect
bentonite slurry quality are discussed below.
     2.2.1  Bentonite Slurry Properties
     To maintain trench stability while exhibiting  suitable  flow character-
istics, the slurry must have the proper viscosity,  gel  strength and density.
It must form a thin, tough, low-permeability filter cake rapidly and
repeatedly.  The bentonite slurry supplied to the trench may meet or exceed
the quality standards stated in the specifications, however, slurry
properties are altered during trench excavation and slurry quality may either
improve or degrade during use.  Table 2-2 presents  data on fresh and in-trench
slurries.   As shown in this table, the density, viscosity, gel strength,  and
solids content of the slurry generally increases during excavation, while the
overall water content decreases, due to the increased solids content.  Brief
                                     2-13

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                                                           TABLE 2-2.


                                 SPECIFIED PROPERTIES OF BENTONITE AND CEMENT BENTONITE SLURRIES
S)
I

Parameter
3
Density (g/cra )
(p.c.f.)
Viscosity, apparent
(Seconds Marsh)
(centipose)
Viscosity, plastic
Filtrate Loss, ml
pH
Water Content, %
by weight
Bentonite Content, %
by weight
Other Ingredients, %
by weight
Gel Strengths
10 seconds, Pascal
10 minutes, Pascal
10 minutes ,
lb/100 ft2
(24-72 dynes/era )
Bentonite
Fresh-Hydrated
1.01-1.04 (1,2)
65 (3)
38-45 (1,5)
-15
<20* (7)
<30 (7)
range 15-30 (3)
7.5 to 12 (6)
-93-97 (6)

4-7 (6)

sand~130 (7)
30-50 (7)


55-70 (7)

6 (7)

30-45 (7)
10 (7)
22 (7)
—

         *SpecTHcation  for  construction  of  tremie  concrete  diaphragm  walls.


         References:   (1)  Case  1982,  (2)  Xanthakos  1979,  (3)  Millet  and  Perez  1981,  (4)  US  Army Corps  of  Engineers 1976;
                       (5)  Guertin  and McTigue  1982b,  (6)  Boyes  1975,  (7)  Jefferis  1981a, (8)  Ryan 1976.

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descriptions of slurry viscosity, thixotropy (gel strength) and density are
given below.


          2.2.1.1  Viscosity


     The viscosity of a slurry must be maintained at a level high enough to
assist in stabilizing the trench walls, but low enough to avoid interfering
with trench excavation (Ryan 1976).  Viscosity is a term used to describe a
fluid's resistance to flow.  It is caused by interparticle attraction
(cohesion) and inter-particle friction (Millet & Perez 1981).  In bentonite
slurries, about 80 percent of the viscosity is due to the attraction between
montmorillonite crystal edges and faces.  The remaining 20 percent is due to
friction (Grim and Guven 1978).  Ideally, a fresh bentonite slurry should have
a viscosity equivalent to 40 seconds, as measured on a Marsh cone (D'Appolonia
1980).

     Marsh cone readings, which are used to measure slurry viscosity, do not
really measure viscosity.  Instead they measure a series of interrelated
properties including density, viscosity, and shear strength (Hutchison et.
al., 1975).  The Marsh cone viscometer consists of a standard size funnel.  To
measure slurry viscosity, 1 U.S. quart (946 cm ) of slurry is placed in the
funnel.  The time taken for this quantity to flow through the funnel is the
viscosity in Marsh seconds.  This test indicates the response of the slurry to
conditions found in the trench.  For example, Marsh cone readings less than
40  seconds indicate a slurry that has poor  filter cake formation and
insufficient trench-supporting ability (D'Appolonia 1980a).  Marsh cone
readings also indicate the workability of the slurry.  If too high, the slurry
can become too dense and difficult to work with.  If too low, trench wall
stability may suffer (Ryan 1976).  D'Appolonia (1980a) found that slurry
viscosity has a direct influence on filter cake permeability and is one of the
most crucial slurry characteristics.  The relationship between viscosity and
filter cake permeability is shown in Figure 2-4.
          2.2.1.2  Gel Strength


     The gel strength represents  the  shear  strength  of  the  slurry when it  is
not agitated.  It  is caused by the edge-to-face  linkage of  clay  crystals  in
the slurry.  Gel strengths are measured  using  a  Fann rotational  viscometer, as
described in Section 4.  Typical  values  average  around  15  Ib/ft   (Xanthakos
1979).

     Thixotropy, which is measured as  gel strength,  is  in  essence,  the shear
strength of the slurry.  Stated differently,  it  is the  resistance of the
solids  in the  slurry to movement, or  shearing  (Baver, Gardner  and Gardner
1972).

     It is evident that viscosity and  gel strength are  ways of measuring  the
resistance to movement in liquids and  solids,  respectively.  Because a


                                      2-15

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                        Figure 2-4.
  Relationship between Filter Cake Permeability
                  and Slurry Viscosity
30
20
10
    I
        Water
                  Premium Grade Bentonite
                  16 Hours = Cake Formation Time
                  Hydraulic Pressure From 30 Feet Water = Cake
                    Formation Pressure (Formation Head)
          30
40          50

Slurry Viscosity, sec-marsh
                                             60
80
   Source: D'Appolonia (1980)
                          2-16

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bentonite slurry is a thixotropic suspension, it displays properties of both
solids and liquids, thus the consideration of both slurry properties is
appropriate.
          2.2.1.3  Density
     A fresh slurry of 4-8% bentonite is.only slightly denser than water,
averaging less than 65 Ib/ft  (1.04 g/cm ) (Case 1982, Xanthakos 1979).  As
particles of excavated materials fall into the trench, they become suspended
in the slurry and cause the slurry's solids content and density to increase.
Densities may increase to 85 Ib/ft  (1.34 g/cm ) or higher when excavating in
sandy soils (Shallard 1983).
          2.2.1.4  Filter Cakes
     The filter cakes that are formed on both trench wall are extremely
important both during excavation and possibly after backfilling as well.
formation, function and desirable characteristics of filter cakes are
described below.
The
               a.  Filter Cake Formation and Function
     When trench excavation is initiated, the slurry is pumped  into  the  trench
to maintain a slurry level at or near the initial ground  level  (Millet and
Perez 1981).  As the slurry is introduced into the trench,  it flows  into  pores
in the strata through which the trench is cut.  Leakage of  slurry  into these
voids continues until the flat clay particles in the slurry begin  to
accumulate in layers, which grow large enough to bridge the gaps between  the
soil particles, or until gelation of the slurry within the  pores occurs.
Figure 2-5 illustrates the relatively rapid initial slurry  loss, followed by  a
reduction in the rate of loss.  This reduction is caused  by the formation of  a
layer of clay particles "plastered" on the trench sides,  which  reduces lateral
liquid flow out of the trench and into the adjacent soil.   This layer is
called a filter cake.

     The filter cake is a thin glue-like membrane composed  of closely packed
bentonite particles (Case 1982).  The solids content of the newly  formed
filter cake ranges from 10 to 50 percent, with higher solids contents found in
filter cakes from calcium than from sodium bentonites (Grim and Guven 1978).
The filter cake from a slurry containing 5 percent bentonite typically
contains 15 percent bentonite (Hutchinson et al 1975).  During  active
excavation, the filter cake is usually less than 3 millimeters  thick.  This
thin layer of clay is, however, an effective barrier to water movement as the
permeability of the filter cake can be as low as 10~9 cm/sec (Xanthakos  1979).
                                     2-17

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                   Figure 2-5.
  Fluid Loss During Filter Cake Formation
                           T_ = Time for Initial Cake Formation
Source: Hutchinson, etal. 1975
                      2-18

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     Formation of the filter cake is of critical importance in slurry trench
construction.  This membrane performs numerous functions, including:

     •  Minimization of slurry loss into surrounding soils

     *  Stabilization of the soil that is in contact with the slurry by
        gelling in the soil pores and by plastering the particles against the
        trench walls

     •  Providing a plane on each trench wall against which the hydraulic
        pressure and dead weight of the slurry can act to stabilize the
        excavation.
               b.  Desirable Filter Cake Characteristics
     Desirable characteristics of filter cakes include rapid  formation and re-
formation when necessary, resistance to shearing, and low permeability.
Experience has shown that a thin filter cake is an  indication of a tough,
impermeable membrane, but a thick "flabby" filter cake is likely to  allow high
fluid losses (Boyes 1975).

     Filter cakes must be formed rapidly when the initial soil contact occurs,
in order to avoid excessive slurry losses.  These membranes must resist
mechanical disruption by the backhoe bucket or clamshell during trench
excavation.  If inadvertently scraped off the trench wall during excavation,
the slurry must be of such composition as to allow  rapid formation of a  new
filter cake to avoid possible collapse of the trench.

     A high gel strength is desirable in the filter cake because the gel
structure contributes to shear strength, and the  filter cake  must resist
shearing forces from both the excavation equipment  agitated slurry and the
soil comprising the trench wall.  In addition, high gel strength indicates
rapid formation of a gel structure.  When the slurry penetrates soil pores,
rapid gelation assists in restricting further slurry flow and thus minimizes
slurry losses (Xanthakos 1979).
     A final desirable filter cake characteristic  is  low  permeability.
movement of water through the filter cake  should be minimized  to:
The
        Avoid wetting and thus softening  and  lubricating  unstable  layers  that
        may be present in the soil surrounding  the  trench (Boyes 1975),

        Avoid increasing pore water pressure, because  this  increases  the  total
        stress on the system and reduces  the  angle  of  friction  in  the soil
        surrounding the trench (Hutchinson et al. 1975)

        Maintain the slurry level in the  trench well above  the  groundwater
        level.  This sustains the thrust  of the slurry on the trench  side
        walls by restricting the pressure losses due to filter  cake leakage
        (Xanthakos 1979).
                                     2-19

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          2.2.1.5  Resistance to Flocculation
     In addition to having the proper viscosity, gel strength, density,  and
filter cake characteristics, a slurry should also have a certain  level of
flocculation resistance.

     As noted earlier, flocculation is undesirable in slurries because as  the
clay particles form clumps, their effective hydrated diameters are greatly
reduced. This increases the size and number of the voids available for water
movement, which increases the permeability of the system (Shainberg and
Caiserman 1971).  Using bentonites that contain a high concentration of  sodium
or that are chemically treated to resist flocculation can help reduce the
likelihood of permeability increases due to flocculation.

     Sodium bentonites resist flocculation more effectively  than  calcium
bentonites because the sodium bentonites swell more extensively than the
calcium-saturated types.  Montmorillonites that have 50 percent of their
exchange complex occupied by sodium ions act essentially like pure sodium
montmorillonites (Shainberg and Caiserman 1971).  However, as the sodium
content of the clay decreases, the permeability increases and swelling
decreases proportionately (Rowell, Payne and Ahmad 1969).  After  replacement
of sodium by calcium on the exchange complex of the clay begins,  it can
continue until nearly complete replacement has occurred.  In addition, the
sodium tends to become more easily displaced as the amount of sodium in  the
clay decreases (Grim 1968).  Thus, a large sodium concentration in the clay is
desirable to aid in resistance to flocculation.
     2.2.2  Factors Affecting Bentonite Slurry Performance


     Numerous factors affect the performance of bentonite slurries.  Trench
designers should be aware of these factors to maximize performance and
minimize problems and unnecessary expenditures.  The theoretical  aspects of
slurry performance are given in this section.  The practical applications of
these considerations are discussed in Section 5.

     Among the factors that affect slurry performance are:

     •  Filter cake performance

     •  Gel strength

     •  Density

     •  Use of chemical of physical additives.

     Each of these factors is described below.
                                     2-20

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          2.2.2.1  Filter Cake Performance
     The efficiency of the filter cake in performing its functions depends on
numerous factors.  These include:

     •  Characteristics of the slurry

     •  Characteristics of the strata surrounding the trench

     •  Time allotted for filter cake formation

     •  Hydraulic gradient between the slurry and the groundwater

     •  Presence of contaminants in the spoils or groundwater.

     Bentonite quantity and quality strongly affects filter cake functioning.
Factors such as  the bentonite concentration, the mixing methods used, and the
exchangable sodium percentage influence the filter cake thickness, formation
time, and permeability.

               a.  Bentonite Concentration

     Figure 2-6  shows the effect of increasing the bentonite concentration of
the slurry on the amount of initial slurry loss.  Slurry loss  is reduced
because the higher bentonite concentration allows greater clay particle
interaction.  This results in more rapid  filter cake formation and higher gel
strength in the  soil pores that  are wetted by the slurry.  To  minimize slurry
loss and consequent trench instability, it is recommended that the bentonite
content of the slurry be maintained above 4.5 percent  (Hutchinson et  al.
1975).

               b.  Bentonite Quality

     The quality of the bentonite used in slurries greatly influences filter
cake formation and performance.  Criteria for bentonite quality include  sodium
content, fineness of grinding, and type and effects of chemical treatments.

     The. sodium  content of the montmorillonite determines the  hydraulic
conductivity and resistance to flocculation of the filter cake.  Montmorillo-
nites containing high sodium contents have been found  to swell to a  greater
degree upon hydration than those containing less  sodium.  In addition,
several* researchers have  found a strong correlation between the amount of
swelling and the hydraulic conductivity of the soil (Rowell, Payne and Ahmad
1969, McNeal 1968).  Based on these data, filter  cakes from sodium bentonite
slurries could be expected to have lower  permeabilities than those from
calcium bentonites.  This hypothesis  is supported by tests on  clay membranes
conducted by Shainberg and Caiserman  (1971).

     These researchers found that the hydraulic conductivity of the
montmorillonite  tested was very  sensitive to the  type  of cation adsorbed on
the clay.  In fact, the hydraulic conductivity of the  calcium  montmorillonite
membrane was 14.2 times greater  than  that of the  sodium montmorillonite.
                                      2-21

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                   Figure 2-6.
The Effect of Bentonite Concentration on the
Initial Fluid Loss During Filter Cake Formation
6 -
  0     10    20    30    40    50    60


                   Initial Fluid Loss: cm3


  Source: Hutchinson, et al., 1975
70
80
                     2-22

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 Values for the calcium and sodium montmorillonite clay membranes were 9.3 x
 10   cm/sec and 0.65 x 10   cm/sec,  respectively (Shainberg and Caiserman
 1975).  These values are similar to  the permeabilities reported for filter
 cakes.  In tests of a bentonite slurry in contact with a London clay, for
 example, the permeability of the filter cake was found to be 2.3 x 10   cm/sec
 (Xanthakos 1979).   The size of the dry bentonite particles affects performance
 because the smaller particles hydrate more rapidly and have a larger surface
 area to hydrate and swell than do larger bentonite particles.  The grades of
 bentonite used for slurry wall applications typically have smaller particle
 sizes than do bentonites used for other applications, such as pond sealing.
                c.   Slurry Mixing Methods
      The methods  used  to mix the slurry can also affect the filter cake
 formation.   Bentonite  slurries  with high shear strengths penetrate a shorter
 distance  into  the soil pores before gelation occurs (Xanthakos 1979).   Thus
 high  shear  strength  slurries exhibit faster filter cake formation and  less
 initial  slurry loss.   Figure 2-7 illustrates the difference in 10 minute gel
 strengths between slurries mixed by two different methods.   In this study,
 the slurry  processed  in the  high shear mixer initially manifested a higher
 10 minute gel  strength than  the slurry mixed in the anchor  stirrer. More
 importantly, the  difference  in  gel  strengths did not diminish during the
 period of time the two slurries were compared.   Even 1,400  minutes (23 hours
 and 20 minutes) after  the initial mixing,  the slurry from the high shear mixer
 had a higher gel  strength than  the  other slurry tested (Hutchinson et  al.
 1975).
               d.  Filter  Cake Formation  Time
     The amount of  time allowed  for  filter  cake  formation can influence filter
cake performance.   As  shown  in Figure  2-5,  a  certain period  of time is
required for the  initial  slurry  loss to occur before colloidal packing  at  the
slurry/soil interface  produces the filter cake.   Studies  reported  by
D'Appolonia (1980)  showed that,  at any given  hydraulic  pressure, the filter
cake permeability is a function  of formation  time.   According to Xanthakos
(1979), the filter  cake thickness increases as time  passes.   Boyes (1975)
found that filter cakes formed under quiescent conditions had higher shear
strengths than those formed during agitation  of  the  slurry.   Because formation
time affects filter cake performance so stongly,  D'Appolonia (1980a) recom-
mended that 24 hours should elapse between  slurry trench  excavation and back-
filling to allow complete filter cake  formation  under quiescent conditions.
               e.  Strata Characteristics
     When the strata surrounding the trench contain numerous  large pores,
considerable slurry loss can occur before the filter cake can  form.  In many
                                     2-23

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                            Figure 2-7.

The Effect of Mixing Techniques and Times on Hydration of a
          5% Suspension of Ca-Exchanged Bentonite
       250 '
   01

   *5
   O
               200     400    600     800    1,000   1,200    1,400



                          Time After Initial Mixing: min.



          Source: Hutchinson, et al. 1975
                               2-24

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cases, particles of spoil that were inadvertently mixed with the slurry during
excavation, can assist in clogging soil pores and can reduce the amount of
slurry loss.  However, in gravel beds, which allow water movement rates of
1 to 10 cm/sec, the pores are too large to be easily closed (jefferis 1981a).
Thus slurry loss under these conditions continues until rheological blocking
occurs (Hutchinson et al 1975).

     Rheological blocking is the gradual inhibition of slurry flow due to the
increase in slurry shear strength as gelation progresses (Boyes 1975).  The
effect of this phenomena is a steady but slow decline in fluid loss even in
gravel beds, as shown in Figure 2-8.  In this figure, the time necessary for
filter cake formation in a less permeable stratum is also illustrated.  The
soil layers containing 0.1 percent sand required rheological blocking coupled
with pore space blockage to stop slurry flow.  Even so, deep filtration
occurred before the filter cake formed.  As the permeability of the stratum
was reduced by the addition of sand, the time needed for filter cake forma-
tion, the amount of slurry lost, and the depth of filtration were reduced
(Hutchinson et al 1975).

     The time required for filter cake formation varies from less than
30 seconds  in fine textured soils, to over 3,600 seconds (6 minutes) in
gravel beds.  The depth of penetration as shown in Figure 2-8 depends on the
permeability of the strata.  In strata of very low permeability, slurry loss
has been found to be minimal (Xanthakos 1979).  One set of tests using a
3.2 percent bentonite slurry in contact with a sandstone having permeability
of from 10   to 10   cm/sec showed slurry penetrated into the stone only from
2 to 3 cm (Boyes 1975).
               f.  Hydraulic Gradient
     Hydraulic gradient also  influences  filter  cake  formation  and  performance
(D'Appolonia 1980a).  The difference between  the hydraulic head  of the  slurry
and that of the groundwater should be  as  great  as  possible to  improve  filter
cake characteristics (Guertin  and McTigue 1982b).  A high hydraulic head  in
the trench forces the slurry  to be packed tightly  along  the  soil/slurry inter-
face. This compresses the filter cake  and reduces  leakage (Hutchinson  et  al
1975).
               g.   Slurry Contamination
     Contamination of the  slurry can occur due  to  the  presence  of  salts,
cement, extremely basic conditions  in  the make-up  water  used.   Slurry
contamination can decrease  filter cake  performance.  For example,  slurry
contamination by cement causes portions of the  slurry  to flocculate.   This
leads to the formation of  relatively thick,  permeable, weak  filter cakes, high
fluid losses and low viscosity in the  slurry (Hutchison  et al  1975).   As  the
amount of cement is increased, the  thixotropic  properties of the slurry are
inhibited.  This leads to  lower slurry  viscosity,  lower  gel  strength  and
                                     2-25

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                             Figure 2-8.
 The Effect of Added Sand on Filtration of a 5% Suspension
of a Calcium-exchanged Bentonite through a Fine Gravel Bed
         2,000
         1,500
         1,000
          500  •
Bed Cross-section = 11.5 cm2
Bed Depth = 30 cm
Pressure Drop = 21 kN/m2 (3 Ib/sq. in.
k = 0.3 cm/s
Sand - Buckland 50 FG

    + 0.1% Sand. Deep Filtration
                     Surface Filtration
             + 0.5% Sand
                                                + 1 % Sand
                                               + 10% Sand
              0123456

                               Time T: min

              Source: Hutchinson, et al. 1975
                                2-26

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inhibited filter cake formation (Guertin & McTigue 1982b).  These effects also
occur in cement bentonite slurries, as is discussed in Section 2.4.1.1.  Other
contaminants can also influence slurry and slurry wall properties.  These are
discussed in Section 4.
          2.2.2.2  Gel Strength


     The slurry's gel strength is a measure of its ability to  form a gel
structure.  This gel structure can influence slurry density.   The gel strength
of the slurry allows the fine particle materials that mix with the slurry
during excavation to remain suspended.  At a gel strength of 15 Ib/ft , the
slurry has the ability to suspend average sized coarse  sand particles.  These
particles are up to approximately 1 mm in diameter.  Particles smaller than
this, such as fine sands, silts and clays are likely to remain in suspension,
while larger particles sink to the trench bottom and form a heavy mixture of
slurry, coarse sand, and gravel (Xanthakos 1979).

     As the slurry's gel strength increases, the maximum diameter of particles
it can support will increase.  High gel strength slurries support a large
portion of the soil particles that fall into the trench, while low gel
strength slurries allow more particles to sink to the trench bottom.  As the
concentration of suspended solids in the slurry increases, the slurry becomes
more dense.  Xanthakos (1979) reported slurry density measurements from tests
at several slurry trench construction sites.  These tests revealed that the
sediments that became suspended during excavation increased the slurry density
by an average of about 4 to 5.5 percent.


          2.2.2.3  Density


     The density of the slurry can influence the stability of  the trench wall.
According to Xanthakos (1979), high density slurries resist the pressures
exerted on the trench walls by high water tables and low shear strength soils.
However, slurries that have a low density do not resist these  pressures as
effectively as do the higher density slurries.  Thus the increase in slurry
density that is caused by the slurry's gel structure can contribute directly
to trench wall stability.

     The heavier soil particles that fall into the trench during excavation do
not remain in suspension.  Instead, they fall to the trench bottom and
accumulate there.  The amount of sand accumulation on the trench bottom is
dependent on the coarseness of the strata being excavated and  other factors,
such as the excavation techniques used (Xanthakos 1979).  This sand layer does
not have a direct effect on trench stability, however it may have an impact on
the permeability of the completed cut-off wall, and the ease of backfilling.
The density of the slurry taken from the trench bottom  (i.e.,  the sand layer)
must be at least 15 pcf less than the backfill.  If the slurry is too dense,
it will not be displaced properly by the backfill (D1Appolonia 1980b).
                                     2-27

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           2.2.2.4   Chemical  and  Physical  Additives
      Numerous  chemical  and  physical  additives  have been used in slurries to
 improve  their  viscosity,  gel  strength,  density,  or fluid loss rate (Xanthakos
 1979).   Some of  those additives  are  listed  in  Table 2-3.  It is recommended
 that  the use of  any  slurry  additives be allowed  only with the approval of the
 engineer.   Some  slurry  trench excavation specifications forbid the use of
 chemically  treated bentonites (U.S. Army Corps of Engineers  1975).  One
 problem  with the  use of chemically treated  bentonites is the possibility of
 enhanced interaction with pollutants.   Conversely, certain chemical treatments
 may render  the bentonite  less susceptible to chemical attack.   Slurry/waste
 interactions are  discussed  in Section 4.
2.3   Soil-Bentonite Walls
     SB walls are excavated under a bentonite  slurry  in  a  continuous  trench.
As excavated materials are removed from the  trench, they are mixed  with  slurry
and replaced in the trench a short distance  from  the  active excavation area.
Techniques used during slurry trench construction are described  in  detail  in
Section 5.
     2.3.1  SB Wall Properties


     A properly designed and constructed SB wall exhibits  the  following
properties:

     *  Low Permeability

     •  Resistance to hydraulic pressure and chemical  attack

     •  Low bearing strength and moderate to high plasticity.
          2.3.1.1  Low Permeability
     Permeabilities of completed soil-bentonite cut-offs have been  as  low  as
5.0 x 10   cm/sec, although higher permeabilities are more common (Xanthakos
1979).  Typical permeabilities of SB walls range from over 10"^ cm/sec  in
walls composed primarily of coarse, rather than fine materials, to  less than
10   cm/sec in walls containing over 60 percent clay (D'Appolonia 1980b).
                                     2-28

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                                   TABLE 2-3

                     COMMON SLURRY MATERIALS AND ADDITIVES
Weight materials

Colloid materials
Thinners and dispersing
agents
Intermediate-sized particles

Flocculants and
  polyelectrolytes
Fluid-loss-control agents
Lost-circulation materials
Barite (barium sulfate) or soil (sand)

Bentonite (Wyoming, Fulbent, Aquagel,
Algerian, Japanese, etc.), basic fresh water
  slurry constituent
Attapulgite, for saltwater slurries
Organic polymers and pretreated brands

Quebrancho, organic dispersant mixture
  (tannin)
Lignite, mineral lignin
Sodium tetraphosphate
Sodium humate (sodium huraic acid)
Ferrochrome lignosulfonate (FCL)
Nitrophemin acid chloride
Calcium lignosulfonate
Reacted caustic, tannin (dry)
Reacted caustic, lignite (dry)
Sodium acid pyrophosphate
Sodium hexametaphosphate

Clay, silt^ and sand

Sodium carboxmyethyl cellulose (CMC)
Salts
Starches
Potassium aluminate
Aluminum chloride
Calcium

CMC or other flocculants
Pregelatinized starch
Sand in small proportions

Graded fibrous or  flake materials; shredded
cellophane flakes, shredded tree bark,
plant fibers, glass, rayon, graded mica,
ground walnut shells, rubber trees, perlite,
time-setting cement, and many others.
Reference:  Xanthakos 1979.  Copyright  1979 by McGraw-Hill Books.  Used with
            Permission.

                                     2-29

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          2.3.1.2  Resistance to Hydraulic Pressure  and  Contaminants


     An SB wall that exhibits an extremely low permeability  is  not  effective
 in the long run if it cannot withstand  the hydraulic gradients  induced by  its
 presence or if it disintegrates upon contact with contaminants  at the site.

     Because of its low permeability, the wall can be used to severely
 restrict downgradient water movement.   This causes the water level  on the
 upgradient side of the wall to rise significantly as compared to the
 downgradient side.  This difference in  water levels  is termed the hydraulic
 gradient.  A high hydraulic gradient across the wall is  likely  to develop
 unless groundwater rerouting is accomplished through the use of upgradient
 extraction wells, subsurface drains or  interceptor trenches  (see Section 3).
 Despite the use of these ancillary measures, the wall should be designed to
 withstand significant hydraulic gradients.  The incorporation of a  high
 concentration of clayey materials into  the backfill  improves the wall's long-
 term resistance to hydraulic gradients  up to 200 (D'Appolonia 1980b).  Wall
 design is discussed in Section 5.

     The wall's resistance to degradation by chemical contaminants  is also a
 primary measure of long term performance.  Prior to SB wall  construction,
 extensive testing of the effects of the  site's leachate  on proposed backfill
mixtures should be conducted.  In general, clayey backfill mixtures withstand
 permeation with contaminants more effectively than those that contain less
 clay (D'Appolonia 1980b).
          2.3.1.3  Strength and Plasticity


     The strength of SB cut-off walls is not usually of primary concern when
designing pollution migration cut-offs.  These walls are usually designed  to
be comparable in strength to the surrounding ground (jefferis  1981b).  If
stronger walls are required, coarser material may be added to  the backfill,
although this practice results in an increase in wall permeability  (Millet and
Perez 1981).  In any case, the strength of a soil-bentonite wall is  not
usually relevant in hazardous waste applications, except where traffic must
pass over the wall.  Design of traffic caps is discussed in Section  5.

     The response of the SB wall to lateral earth pressures and earth
movements is an important factor in the design of pollution migration cut-
offs.  If the wall is too brittle, shifts in nearby strata caused by
overloading the surface by stockpiles or heavy machinery can result  in
cracking and subsequent leakage of the wall.  Fortunately, completed SB cut-
off walls behave plastically when stressed.  That is, they undergo plastic
deformation rather than crack (Guertin and McTigue 1982b).  In contrast, CB
walls have higher strength than SB walls and can be brittle and thus more
easily cracked (Millet and Perez 1931).
                                     2-30

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      2.3.2   Factors  Affecting  SB Wall  Performance


      There  are  numerous  factors that can  affect  the  performance  of SB  Walls.
 These can be divided into  four general groups  which  are:

      •  Design  criteria

      •  Backfill  composition and characteristics
      •  Backfill  placement methods

      •  Post-construction  conditions at the  site.


          2.3.2.1  Design  Criteria


      The design criteria that  affect SB wall performance  include wall  width,
 wall  depth,  selection  of appropriate aquiclude,  wall configuration,  and  use of
 ancillary measures.  These criteria are discussed  in Section  5.   The factors
 relating to  backfill preparation and post-construction  conditions are
 described below.


          2.3.2.2  Backfill Composition and  Characteristics


      To  produce a  low-permeability, durable  cut-off  wall,  the backfill must
 contain  a high  concentration of plastic fines  (clays),  a minimal amount  large-
 diameter particles,  and  a  suitable concentration of  bentonite and water.
 Contaminants  in the  soil or water can  also affect  the wall's  performance.


                a.  Native Clay and Bentonite Content


      A primary  requirement for backfill material is  that it contain  a  suitable
 particle size distribution.  For low permeability, this means the backfill
must  have from  20  to 40  percent fine particles,  preferably plastic fines.
Fine  particles  (less than 0.074 mm in  diameter or  passing  a number 200 sieve)
exert  a  significant  influence  on backfill permeability, as shown in  Figure
2-9.   At a given bentonite concentration, the backfill  permeability  will be
 lower  when the  backfill  material contains a  higher proportion of fines.
Conversely,  increasing the bentonite content of  the  backfills tested
significantly reduced  the wall permeability.  The bentonite content  of the
mixed  backfill  should  not fall below 1  percent (D1Appolonia 1980b).  Where the
strength of  the cut-off  wall is of primary concern,  a higher concentration of
coarse and medium  sized  particles are  required.  In  any case, material over
6 inches in diameter are not considered desirable  for use  in backfills
(Federal Bentonite 1981).
                                     2-31

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                             Figure 2-9.
Relationship Between Permeability and Quantity of Bentonite
                       Added to SB Backfill
          10
          10
          10
          10
            -5
          10
          10
          10
          10
                  Clayey Silty Sand
                  w 30 to 50% Fines
                0
                          1
Well Graded
Coarse Gradations
(30-70%  ^ 20 Sieve)
w'10 to 25% NP Fines
        Poorly Graded
        Silty Sand
        w/30-50% NP Fines
                          % Bentonite by Dry Weight of SB Backfill

                Source: D'Appolonia, 1980
                                    2-32

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      D'Appolonia (I980b)  found that plastic fines reduce permeability more
 effectively than nonplastic fines.   This is most likely due to the fact that
 plastic  fines are composed of smaller particles than nonplastic fines.  The
 effect of plastic fines on backfill permeability is shown in Figure 2-10.

      Fine particles,  particularly clays, contribute to low permeability by
 assisting in bridging the pores between larger particles and by contributing
 to the swelling, viscosity, gelation, and cation exchange capacity of the
 backfill (D'Appolonia 1980b, Boyes  1975).  Although these properties find
 their maximum expression in montmorillonite, other clays exhibit these
 characteristics  to a  lesser degree  (Grim 1968).  Thus the clay content of  the
 backfill has a pronounced effect on SB wall permeability.
                b.   Water Content
      The  water  content  of the  backfill  can also influence the SB wall
 performance.  The'amount  of  water  in the  backfill  should be carefully
 controlled  because  the  hydraulic conductivity of sodium montmorillonite has
 been  reported to  increase dramatically  as the water content increases (Low
 1976).  There is  an effective  limit  on  reducing the water content of the
 backfill, however,  because the backfill must  slump sufficiently to allow
 proper  placement.   The  water content of backfills  at ideal slumps is from 25
 to  35 percent (D'Appolonia 1980a).   Even  so,  the excess water in the backfill
 has been  found  to result  in  increased permeability (Jefferis 1981b).

      If the moisture content of the  soil  material  excavated from the trench is
 over  25 percent initially, the addition of bentonite slurry during backfill
 mixing  results  in a very  wet backfill that exhibits high permeability.   To
 remedy  this situation,  D'Appolonia (1980a) suggests spreading the soil
 material  in a thin  lift over the backfill mixing area,  then broadcasting dry
 bentonite over  the  lift at the desired  rate.   The  soil  material is then mixed
 with  the  dry bentonite  prior to the  addition  of the slurry.   This reduces the
 water content of the backfill  while  simultaneously increasing the bentonite
 content.
               c.   Contaminants  in Backfill Materials
     The construction of a low-permeability SB cut  off walls requires  the  use
of soils in the backfill that are  free of deleterious materials.  To be  free
of deleterious materials, the proposed soil source  must not contain signifi-
cant amounts of soi.l organic matter, including plant and  animal debris,  high
calcium materials,  including gypsum, chalk and caliche, or high concentrations
of soluble salts, including sodium chloride,  sodium sulfates or anhydrite.

     In addition to the items listed above, other subsurface materials may be
detrimental to backfill quality.  For example, at some sites where pollution
migration cut-offs have been constructed, the soil  excavated was contaminated
with pollutants.  These pollutants may or may not significantly interfere with
                                     2-33

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                               Figure 2-10.
Effect of Plastic and Non-plastic Fines Content on Soil-Bentonite
                         Backfill Permeability
            80

            70.

            60

            50

            40



            20

            10

             0
Plastic
Fines
                  Non-Plastic or Low
                   Plasticity Fines
        0  10-9

Source: D'Appolonia, 1980
10-e      10-7

   SB Backfill
                                             1Q-6
                           10-5
10-"
                                    2-34

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cut-off wall performance.  D'Appolonia (1980a) suggested preparing a test
mixture to determine compatibility.  He further suggested using the con-
taminated soil if equal in quality to uncontaminated soil, even though the
material may decrease the slurry and backfill performance initially.  This  is
because early exposure of the bentonite to the contaminants reduces the
permeability changes that occur during subsequent exposure to the contami-
nants.  This approach must be balanced against the fact that contaminant
breakthrough may occur earlier.
          2.3.2.3  Backfill Placement Methods


     The mixing and placement of the carefully  selected backfill material  is
of critical importance in the overall performance of the completed wall.   The
bentonite slurry and  soil material must be  combined to  form  a  relatively
homogenous paste with a consistency similar to  that of mortar  or concrete.  It
must flow easily yet  stand on a slope of  about  10:1, and must  be at  least  15
pcf (240 kg/m ) denser than the slurry in the trench (D'Appolonia  1980b).   The
methods used to mix the backfill and the  tests  used to measure its shear
strength, flow characteristics and density  are  described in  Section  5.


          2.3.2.4  Post-construction Conditions
     Once  the backfill has been mixed  and  placed,  the  performance  of  the  wall
 is  dependent on  the  subsurface conditions  surrounding  the wall.   In particu-
 lar, the hydraulic gradient  and the  presence  of  contaminants  can influence the
 wall's  ability to  function properly.


               a.  Hydraulic Gradient


     The difference  in hydraulic  pressure  between  the  upgradient and  down-
 gradient sides of  the trench strongly  influences the trench's durability  as
 well as its  initial  permeability.  Little  data are available  on this  factor;
 however, it  has  been shown that high hydraulic pressures within the trench
 during  filter cake formation result  in a lower permeability filter cake.   The
 long-term  effect of  high  hydraulic pressure differentials across the  trench on
 wall permeability  is, however, likely  to be different  (D'Appolonia 1980b).  A
 large difference in  hydraulic pressure from one  side of the trench to the
 other  is expected  to severely tax the  integrity  of the wall.   Methods used to
 combat  high  hydraulic gradients  include increasing wall thickness  and/or  using
 extraction wells or  subsurface drains  upgradient to assist in equalizing
 hydraulic  pressures  near  the wall.   These  are discussed in Section 5.
                                      2-35

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               b.  Presence of Contaminants
     The resistance of soil-bentonite cut-off walls to permeation  and
destruction by various pollutants is the subject of much current research.
Bentonite is extremely resistant to degradation from  some  substances, but
others cause rapid dehydration and shrinkage of the montmorillonite  particles.
SB wall performance can be severely inhibited by contact with  incompatible
chemical compounds in leachates or wastes.

     The wall can be protected from degradation due to chemical incompatabil-
ity in several ways.  First, waste/wall contact can be minimized by  using
extraction wells or subsurface drains.  Second, contaminated soil  can be used
in the backfill, as described earlier.  Third, the concentration of
non-montmorillonite clay in the backfill can be maximized.

     Non-montmorillonitic native clays are not likely to be as severely
affected by chemical contaminants as are bentonites or native montmorillonitic
clays.  This is because the non-montmorillonitic native clays do not swell as
extensively as montmorillonite when they are hydrated.  Consequently, if they
become dehydrated during chemical interactions, they do not shrink as
extensively as montmorillonite does when it becomes dehydrated.  When
shrinkage is minimized, the associated permeability increase is also
minimized.  Thus the adverse effects of the chemical  interaction can be
decreased.

     Different types of wastes affect the clay in the backfill in  different
ways.  In addition to dehydration and shrinkage, the clay may be dissolved or
its properties can be drastically altered.  Data on chemical compatabilities
of wastes and SB walls are summarized in Section 4.

     The proper design and construction of an. SB wall can  result in  a durable,
low permeability cut-off that withstands high hydraulic gradients  and
permeation with various contaminants.  At some sites, the  use of SB  walls is
not appropriate (see Section 5).  When SB walls cannot be  used CB  walls can be
installed.  These walls are similar to SB walls in that they contain bentonite
and form a relatively low permeability cut-off, but they differ in several
important ways, as described below.


2.4  Cement Bentonite Slurries


     When CB walls are being constructed CB slurries are prepared.   Techniques
used to construct CB walls are described in Section 5.


     2.4.1  CB Slurry Properties


     Ceraent-bentonite slurries normally contain about 6 percent by weight
bentonite, 18 percent ordinary Portland.cement (o.p.c.) and 76 percent water


                                     2-36

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 (Jefferis  1981b).  Typical  ranges of CB  slurry  contents  are  presented  in
 Table  2-5.

     When  bentonite  slurries  are compared  to  CB slurries,  the  differences
 become evident.  Table  2-4  illustrates these  differences.  Most  of  these
 differences  are  due  in  part to  the  effects  of the  calcium  from the  cement  on
 the  sodium montmorillonite  in the bentonite.  The  three  most important
 differences  between  the properties  of CB slurries  and  bentonite  slurries are:

     • Physical properties,  including viscosity and  filter  cake formation
     • Setting  times

     • Filter cake  permeability.


           2.4.1.1  Differences  in Physical  Properties


     Because of  the  calcium in  the  cement,  the  properties  of the sodium
 bentonite  in CB  slurries  are  permanently altered.   For example,  the viscosity
 is higher  due to the flocculation of the slurry and the  higher solids
 concentration, 15  to 30 percent in  CB slurry, opposed  to about 6 percent in
 bentonite  slurries (Millet  and  Perez 1981,  Jefferis 1981b).  The results of
 the  filtrate loss  test  are  also higher.  This indicates  that the time  required
 for  filter cake  formation is  longer and  the permeability of  the  cake formed is
 higher (Hutchinson et al. 1975; Millet and  Perez 1981).  A comparison  of the
 properties of bentonite and CB  slurries  is  presented  in  Table  2-5.
          2.4.1.2  Differences  in Setting Times
     The primary difference between CB and  SB  slurries  that  is  of  practical
importance in slurry trench construction  is  the  fact  that  CB slurries begin  to
harden within 2 to 3 hours after mixing (Case  1982).  This necessitates  the
use of construction techniques different  from  those used during construction
of SB walls, as described below.

     CB walls can be constructed either in  a series of  panels or as  a
continuous trench that is backfilled with a  CB slurry.  When CB panels are
constructed, alternate panels are excavated  under  a CB  slurry,  then  allowed  to
partially set.  When they have obtained a sufficient  shear strength, the
intervening panels are excavated also under  a  slurry.   A portion of  the
initial panel ends are removed during this  second  stage to ensure  continuity
between the initial panels and the intervening ones.

     Another result of the rapid setting  times of  CB  slurries as compared to
bentonite slurries, is the fact that construction  delays can cause problems  in
set up of CB walls.  This is because continued agitation of  the CB slurry
(that is, more than 24 hours) reduces the ability  of  the cement in the slurry
to set.  In fact, 48 hours of agitation can  completely  prevent  setup of  the  CB
wall.  This effect can be off-set by the use of blast furnace slag.  This
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                                   TABLE  2-4

                TYPICAL COMPOSITIONS  OF CEMENT  BENTONITE  SLURRIES
Cons ti tuen t	Percentage  in  Slurry

Bentonite                                            4-7

Water                                               68-88

Cement
  without replacements                               8-25
  when blast furnace slag added, minimums            1-3
  when fly ash added, minimums                       2-7

Blast furnace slag, maximums, if used                7-22

Fly ash, maximums, if used                           6-18
Reference:  Adapted from Jefferis 1981b.
                                     2-38

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                                   TABLE 2-5

                    PROPERTIES OF SOIL BENTONITE AND CEMENT
                              BENTONITE BACKFILLS
Parameter
Soil-Bentonite Backfill
Cement-Bentonite
    Backfill
Density
Water Content, %
  by weight

Bentonite Content, %
  by weight

Other Ingredients, %
  by weight

Strength
Permeability, cm/sec
typically 105-120 p.c.'f, (1)
         1680-1920 kg/m  (l)
25-35(1)
0.5-2 (1)
Fines 10-20 (3)
Pines 20-40 (1)

Plastic.  Very little
strength (4)
normally around 20 p.s.f,
unconfined (5)
minimum reported
5.0 x 10~* (6)
maximum reported
~1 x 10  • (1)
maximum likely 1300
kg/m

  55-70(2)
   6 (2)
Cement 18 (2)
Solids 30-45 (2)

Ultimate strength
Range:  5-55 p.s.i
                                                        Normal strength
                                                        20-45 p.s.i. (8)
1 to 5 x 10
                                                                   -6
(2)
References:

(1)  D'Appolonia 1980b, (2)  Jefferis 1981b,  (3)  Millet and Perez  1981,
(4)  Guerntin and McTigue 1982b, (5)  Ryan  1976,  (6)  Xanthakos  1979,  (7)
Case 1982, (8)  Cavelli 1982.
                                     2-39

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pozzolanic material can  replace up  to 90  percent  of  the  ordinary Portland
cement in the slurry  (Jefferis 1981b).


          2.4.1.3  Differences in Filter  Cake  Permeability


     Although there are  some basic  differences between the use  of bentonite
and CB slurries during trench excavation,  the  critical differences between
these two cut-off wall construction techniques appears in  the  finished cut-off
wall.

     The tub'st important  differences between  SB and CB walls with regard to
pollution migration cut-offs are that SB walls have much lower  permeabilities
and higher resistances to certain pollutantsr than do CB  walls  (Jefferis 1981b;
Xanthakos 1979).  An  important factbr contributing to the  permeability
differences can be seen  by comparing the  permeabilities  of filter cakes from
each walltype.  For  bentonite slurries,  filter cake permeabilities can be as
low as 10   cm/sec, while permeabilities calculated  from filtrate loss tests
on CB slurries ranged from about 1  to 4 x  10    cm/sec (Xanthakos 1979,
Jefferis IJjSlb).  The permeability  of a SB wall installed  in a  dam was tested
at 5 x 10   cm/sec (La Russo 1963).  Samples of aniristal ledges wall were
tested and found to have permeabilities between' 10   and 10  cm/sec.   (Jones
1978).  Other important  differences  between  finished CB  and SB  walls are
listed in Table 2-5.  ' :
2.5  Cement-Bentonite "Walls
     In contrast to SB walls, CB walls are used where  there  is  a  lack of
suitable soils or sufficient backfill mixing areas, or  there  are  excessive
slopes at the site1.  CB walls are also used where  strength, rather  than  low
permeability is the primary consideration (Guertin and  McTigue  1982b).    The
properties of SB and CB walls are compared in Table 2-5.  Appropriate applica-
tions of CB walls for pollution migration control  are described in  Section  5.
Typical compositions of CB slurries were described earlier.   This section
describes normal CB wall characteristics and factors affecting  the  performance
of both CB slurries and CB walls.
     2.5.1  CB Wall Requirements
     The requirements for CB wall performance include

     •  Strength

     •  Durability

     •  Continuity
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      •   Set  time

      •   Permeability.


           2.5.1.1  Strength
      CB wall strength is designed to be slightly greater than that of the
 surrounding ground, and is typically comparable in strength to stiff clay
 (Jefferis 1981b, Millet and Perez 1981).  Although strengths of CB walls can
 range from 10 to 1,000 R.s.i., ultimate strengths are generally about 20 to
 45 psi and are achieved after 28 days (Xanthakos 1979, Cavalli 1982).

      At a hazardous waste site, strength may be required where traffic crosses
 the wall, or where a weak wall may interfere with the stability of nearby
 buildings, storage tanks, or bridge foundations or road or rail subgrades.


           2.5.1.2  Durability


      CB walls appear to be quite durable under most conditions,  as they can
 usually withstand compressive strains of several percent without  cracking
 This  is because  they are not  as brittle as typical concrete walls (Ryan 1976).
 Moreover,  they can withstand  relatively high hydraulic gradients.   A CB wall
 only  2  to  3  feet  wide  can satisfactorily withstand at least 100  feet (30
 meters)  of hydrostatic  head  (Millet  and Perez 1981).   A mixture of 50 kg/m3
 bentonite, 70 kg/m  blast  furnace slag, and  30 kg/m3  cement in  a  CB backfill
 was reportedly not  damaged after 40  days of  exposure  to a head differential of
 200 feet  (Jefferis  1981b).  Despite  the fact that  CB  walls  are  normally quite
 durable   they are not  indestructable,  as hydrofracturing of CB walls  has been
 reported to occur (Millet  and  Perez  1981).   Also,  comparatively little  is
 known of the  permanence  of CB  walls  in  hostile chemical  environments.


           2.5.1.3   Continuity


     Continuity of  CB walls is an  important  factor in  construction of cut-
offs.   Because these walls are sometimes constructed  in  panels rather than  in
a continuous trench, there is a possibility  for unexcavated  portions to  remain
between the panels.  To prevent this, care is  taken during  the excavation of
panels, and the clamshell bucket or backhoe  is moved vertically and
horizontally throughout each slot at the completion of slot excavation.  In
addition, when the connecting area between the  initial and  subsequent panels
is excavated,  a portion of the set panel is removed to ensure that all
intervening soil  has been excavated (Guertin and McTigue 1982b)     If
unexcavated areas are inadvertantly left between panels, leakage can occur.
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          2.5.1.4  Set Time


     The time required for CB walls to harden depends on the presence of set
time retarders, cement replacements, and water/cement ratios, among other
factors.  The speed of set is of interest because of the construction
techniques employed.  During CB wall installation, slow setting of panels can
delay construction.  This is because alternating panels are excavated, leaving
unexcavated areas between each.  After the CB slurries in the first set^of
panels have set, the areas between them can be excavated.  If the slurries
take unduly long to harden, construction can be delayed.  This may occur where
fly ash is used as a cement replacement, because a slurry containing fly ash
may harden very slowly.  The use of blast furnace slag does not delay CB
slurry set up as long as does fly ash (Jefferis 1981b).


          2.5.1.5  Permeability


     The permeability of CB walls is normally about  10"  cm/sec (Case 1982).
This can be decreased by adding blast furnace slag or  additional bentonite.
Jefferis (1981b) reports that permeability can also  be decreased as much as  an
order of magnitude due to consolidation of the completed wall.


     2.5.2  Factors Affecting CB Wall Performance


     Factors  affecting the  performance  of CB walls  include:

     •   Slurry contents,  including  bentonite, water, cement, cement
         replacements

     •   Mixing methods and  speeds.


           2.5.2.1   Slurry  Constituents


     The quality and  quantity of ceraent-bentonite slurry constituents can
 alter  the characteristics  of the slurry and  the completed wall.  Bentonite
 quality, water quality cement content and the use of cement replacements all
 affect  CB slurry and  wall  performance.


                a.   Bentonite Content
      The low permeability and resistance to chemical attack of CB walls are
 contributed by the bentonite in the slurry.  Where very low permeability or
 resistance to aggressive chemicals are required, the bentonite content of  the
 slurry should be increased (Jefferis 1981b).  Increasing the quality of

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bentonite used in the slurry can also help produce a durable  low-permeability
CB wall.

     An important characteristic of high quality bentonite  is  its  sodium
content.  Bentonites with higher sodium contents are particularly  desirable
for use in CB slurries due to the changes in  the bentonite  slurry  caused by
the calcium ions in the cement.

     When cement is added to a bentonite slurry, several  interrelated  changes
occur.  First, calcium ions from the cement begin replacing sodium ions on the
exchange complex of the montmorillonite particles.  This  compresses  the
diffuse double layer surrounding each clay flake and reduces  the net negative
charge on the hydrated particles (See Figure  2-1).  As  the  double  layer
contracts, the pore space between the particles is enlarged,  thus  increasing
the amount of free water in the mixture.  Due to the reduction in  net  negative
charges, the mutual repulsion between the clay particles  decreases,  so the
clay flakes come closer together.  At this point, the large calcium  ions can
serve to link clay particles together, causing them to  flocculate,  or  form
stacks of particles.  These stacks, being much heavier  than dispersed  clay
particles, tend to settle out of the suspension readily.  They also  have a
decreased ability to form a gel structure or  a filter cake  (Case 1982, Boyes
1975).  All of these changes are detrimental  to slurry  quality.


               b.  Water Quality


     Water quality can also influence CB slurry characteristics.   If water
containing calcium ions or dissolved salts is  used to mix with the dry
bentonite, the cement slurry produced exhibits low viscosity,  poor  filter cake
formation and an increased set time (Guertin  and McTigue  1982b).   Specifica-
tions for water quality include:

     •  Hardness of <50 ppm (Xanthakos 1979)

     •  Total dissolved solids content of <500 ppm (U.S.  Army  Corps  of
        Engineers 1975)

     •  Organics content of <50 ppm (U.S. Army Corps of Engineers  1975)

     •  pH of about 7.0 (U.S. Army Corps of Engineers 1975).

Leachate-contaminated water should not be used to mix with  the fresh
bentonite.  If the use of poor quality water  cannot be  avoided, 10 to
12 percent more bentonite than normal may be  required and longer mixing times
are recommended (Xanthakos 1979).
                                     2-43

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               c.  Cement Content


     The cement content of CB slurries is the chief factor controlling the
strength, deformability, and permeability of the finished wall.  Generally,
there is a trade-off in CB walls between strength and permeability, for as the
cement content is increased, a stronger, more brittle wall is formed (Millet
and Perez 1981).  The trade-off is due to the detrimental effects of the
cement on the bentonite.  Higher cement contents allow higher wall
permeabilities, and, although wall strength can be increased by the addition
of coarse materials, these materials also result in increased permeability
(Jefferis 198Ib).

     Due to this trade-off, the ultimate strength of cement bentonite walls is
low, normally ranging from 20 to 45 p.s.i. (Cavalli 1982).  The minimum
reported strength was 5 p.s.i. in a relatively young wall, and the maximum
strength was reported at 55 p.s.i. (Case 1982, Millet and Perez61981).  The
permeability of CB walls is relatively high, usually around 10   cm/sec (Case
1982).  In one completed CB wall tested, the permeability of Shelby Tube
samples was on the order of 10~  to 10   cm/sec., and the strength was
measured at 13 to 15 p.s.i. (Jones 1978).

     The ratio by weight of water to cement in the slurry also affects the
characteristics of CB walls.  Generally higher ratios produce weaker walls.
Typical water cement ratios range from 3:1 to 11:1.  These are much higher
than the ratios  found in concrete mixes.  The reason the cement and water do
not separate (bleed) to a great extent is the presence of the bentonite in the
mixture.  Bentonite absorbs a great deal of water thus minimizing the  free
water in the slurry.  At the same time, the gel structure of the bentonite
particles in the slurry assists in supporting the cement particles and thus
reduces settling and prevents excessive bleeding.  A quality CB slurry should
show bleed rates of less than 1 percent (Jefferis 1981b).
               d.  Cement Replacements


     A fourth slurry constituent that can  affect  CB  slurry  and  wall  perfor-
mance is the use of cement, replacements.   Blast  furnace  slag  and fly ash are
two of the materials that have been used to  replace  a  portion of the cement
used in CB slurries.  Blast  furnace slag can be  used to  replace up to
90 percent of the cement, and fly ash can  replace up to  70  percent (Jefferis
1981b).  The resultant cement replacement  concentrations are  shown in
Table 2-4.

     When using these replacements, two important slurry properties  are
altered.  The slurry's set time is extended, allowing  the slurry to  remain
fluid and workable longer.   Thus construction  schedules  can be  extended and
the risk of problems caused  by delays is reduced. In  addition, the  blast
furnace slag and fly ash that were described by  Jefferis (198lb) did not
damage the bentonite as much as cement does.  Thus the viscosity, gel
strength, and ability to form filter cakes is  less impaired (Jefferis 1981b)


                                     2-44

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 The^mechanisms  by which the cement replacements slow the setting time and
 avoid  bentonite inhibition are described below.

     The  fly ash and blast furnace slag require the presence of lime in order
 to  harden.  ^The lime is not available in the CB slurry until most of the
 cement particles have fully hydrated.  Since the cement does not fully hydrate
 upon exposure to water, the blast  furnace slag and fly ash delay the setting
 time.   This  delay extends  the  period  of CB workability (Jefferis 1981b).

     The  use of these cement replacements is less detrimental to the bentonite
 because blast furnace slag and fly ash do not release calcium ions as rapidly
 as  does cement.   Thus the  mass action effect of calcium ions on the exchange
 complex of the  montmorillonite clay is reduced (Jefferis 1981b).

     Cement  replacements also  affect  the characteristics of the completed
 wall.   These effects include:

     • Reduction in bleeding  rates

     • Maintenance  of setting ability even though agitated for long periods

     • Lowered  permeabilities in  the completed wall

     • Reduced  susceptibility to  chemical attack.

     According  to Jefferis (I981b), the bleeding rates of cement-replaced CB
 slurries  are less than those of typical CB slurries.   This effect is most
 likely due to the fact  that  blast  furnace slag and  fly ash do not inhibit
 bentonite properties as drastically as does cement  (Jefferis 1981b).

     Another effect  of  cement  replacement is a prolongation of setting  time.
 When^CB slurries  are used  without  cement  replacements, they begin to set  up
 within^2  to  3 hours  (Case  1982).   If  the  slurries  are agitated to prevent
 hardening, the  ability  to  set  up will be  diminished and will be lost
 altogether if agitation continues  for 48  hours.   The  addition of blast  furnace
 slag or fly  ash  to the  slurry  allow agitation to be continued for up to seven
 days without  substantial loss  of setting  ability (Jefferis  1981b).

     Blast furnace slag  can  contribute  to low permeability  in CB walls.   When
 conventional  CB walls or CB walls with  fly,ash replacement  are allowed  to set
 for 7  days,  permeabilities of  1 to  5  x  10   cm/sec,  result.   In contrast,  CB
walls  containing  from_2.5  to 7.5 percent  blast furnace slag  exhibited perme-
 abilities of  about 10   cm/sec  after  7  days  of hardening  (Jefferis  1981b).

     A  final effect  of  cement  replacement  on  CB  walls  concerns resistance  to
chemical attack.  Fly ash  replacements  can  effectively increase a CB wall's
chemical resistance, however, blast furnace  slag replacements  cannot (Jefferis
1981b).

     The cement in CB walls is  much more  susceptible  to chemical  attack than
is bentonite.  For this reason, CB walls  are  not normally used  where exposure
to detrimental chemicals is likely.  However  if  CB walls are  required due  to
                                     2-45

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site conditions, the addition of protective agents such as fly ash may be
desirable.
               e.
                   Chemical Additives
     In addition to bentonite, water, cement, and sometimes cement replace
ments, chemical additives can be mixed into CB slurries to alter their
performance.  Several types of additives are used, including deflocculants and
setting time retarders.  Deflocculants include chemicals such as sodium
hexametaphosphate, oxidants, acids, and peptizing reagents which are  added to
break up the floes formed when calcium is added to the slurry (Xanthakos
1979).

     Setting time retarders can be added to extend the period^of CB  slurry
workability.  The use of chemical set retarders has  several disadvantages.
These include the following:

     •  Compared to the amount needed in normal concrete mixes, the  quantity
        of  setting time retarders in CB slurries  is  much greater,  due to  the
        adsorptive effects of the bentonite

     •  Many chemical retardants  lose their effectiveness within 24  hours

     •  Some may actually accelerate setting  after 24 hours

     •  Some may reduce  the  strength of the  finished wall  (Jefferis  1981b).


           2.5.2.2  CB  Slurry Mixing Methods


      The methods  used  to mix the  cement-bentonite slurry also effect the
 performance characteristics  of  the  slurry.   To obtain optimum slurry
 properties, it  is  recommended that  first  the bentonite be  given sufficient
 time and  agitation  to  hydrate fully,  then the slurry be mixed with the cement
 as rapidly as  possible in  a high  shear mixer.  The reasons for using these
 techniques are  explained below.

      If the cement  is  present in the water to which dry bentonite is added,
 the slurry will behave as  if it were mixed in poor quality water, as^described
 above.   Hydration,  swelling, viscosity,  and thixotropy will be inhibited (Case
 1982,  Boyes 1975).   For this reason,  the bentonite must be fully hydrated
 prior to mixing with cement to form a cement-bentonite slurry.

      After the slurry and  cement are mixed, flash stiffening of the  constitu-
 ents occurs.  If agitated continually for another 5 minutes or so,  the mixture
 becomes fluid again.  The speed of mixing has a pronounced effect on slurry
 performance.  For example, CB slurries from low shear (i.e., 50 rpm) mixers
 were compared to slurries from high shear (i.e., 1400 rpm) mixers.   The  high
 shear slurries showed lower bleed rates, a greater  sensitivity to drying
                                      2-46

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problems, lower permeabilities when set, and higher unconfined compressive
strengths when set than those from the low shear mixers (Jefferis I981b) .

     From the discussion above, it is evident that the performance of both the
CB slurry and the completed wall are dependent on both the slurry consti-
tuents, and. the mixing procedures used.  Thus, both of these variables  should
be carefully controlled during design and construction of CB walls.


2.6  Summary


     Bentonite slurries can be used to hold open trenches during the construc-
tion of soil bentonite and concrete walls.  The bentonite used is composed
primarily of the clay mineral sodium montmorillonite, whose properties  deter-
mine the characteristics of the slurry.

     The sodium montmorillonite properties that are important during slurry
functioning include extensive hydration and swelling, nearly complete disper-
sion, and thixotropy.  These charcteristics allow the slurry to  form low
permeability filter cakes on the trench walls.

     The filter cakes are an important component of the slurry trench,  as they
minimize slurry loss and groundwater inflow, plaster the soil grains together
at the soil/slurry interface, increase the shear strength of the soil into
which they flow, and form a plane against which the hydrostatic  force of the
slurry can act to stabilize the trench walls.

     Montmorillonite characteristics also allow the slurry to form a gel
structure when agitation is not occurring.  This gel structure assists  in
suspending small particles of spoil inadvertently dropped into the slurry
during excavation.  The suspended sediments increase the slurry  density and
viscosity and thus indirectly assist in maintaining trench stability. Chemical
additives are used in some slurries to improve the hydration, dispersion, and
viscosity of the mixture.

     Once the excava-t-ion of a slurry trench is complete, the slurry  is  back-
filled using a homogeneous paste composed of soil mixed with bentonite  slurry.
The characteristics of the soil and slurry used, as well as the  water content
and placement methods control the permeability of the completed  wall.

     Cement is added to some bentonite slurries to form a mixture that  will
harden in time and form a cut-off wall.  Because the calcium in  the cement
interferes with the sodium montmorillonite in the bentonite, properties of
cement bentonite slurries differ in some respects from those of  bentonite
slurries.  The most important differences are the facts that CB  slurries
harden to form a CB wall and that the permeability of CB filter  cakes and CB
walls is higher than that of bentonite slurries, filter cakes, and completed
SB walls.

     When CB slurries harden to form CB walls, the relative proportions of
cement, water, bentonite, and cement replacements and chemical additives,

                                     2-47

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along with the mixing methods used, control the characteristics of the
completed wall.

     To determine the suitability of SB or CB walls as a pollution migration
cut-off at a particular site, an in-depth site investigation must be
conducted.  This investigation is described in the following section.
                                     2-48

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                                   SECTION 3

                           SLURRY WALL APPLICATIONS
     The effectiveness of a pollution control slurry wall is determined, in
large part, by its horizontal and vertical configuration as well as the
associated remedial measures applied in conjunction with it at a particular
site.  These are, of course, highly site specific factors.  The site
conditions that determine both configuration and associated measures include
setting, both geologic and geographic waste characteristics, and the nature of
the environmental problems caused by the site.  Although these factors are
site specific, generalizations on applications can be useful in understanding
and evaluating a slurry wall alone, and as part of a total remedial effort.


3.1  Configuration


     Configuration as used here refers to the vertical and horizontal
positioning of a slurry wall with respect to the pollution source location,
and the groundwater flow characteristics.  Although each slurry wall
installation is unique, the vast majority can be described in the terms used
in this section.
     3.1.2  Vertical Configuration


     Vertical configuration refers  to  the depth  of  the  slurry  wall with
respect to both geologic formations  and  the water table.  Based on vertical
positioning, walls are either "keyed"  into a  low permeability  formation  below
the aquifer, or placed to only intercept the  upper  portion of  the aquifer.
This latter type is commonly referred  to as a "hanging"  slurry wall.

     A description of these two general wall  types  and  their uses follows.


          3.1.2.1  Keyed-in Slurry  Walls


     Keyed-in slurry walls are excavated to a confining  layer  below it,  to
contain contaminants that mix with  or  sink to the bottom of  the,aquifer.  This
layer may be a low permeability formation such as a clay or  silty clay or may
be the underlying bedrock (See Figure  3-1).   In  either  case, the connection


                                     3-1

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     Figure 3-1.
Keyed-in Slurry Wall
     3-2

-------
between  the wall  and  the  low permeability  zone  is very important  to the
overall  effectiveness  of  the wall.

      From  a construction  standpoint,  wall  key-in can be very straightforward
or very  complicated.   If  the low  permeability  zone  is some  easily excavated
material,  such  as a clay  layer  or weathered  rock, basic construction quality
control  should  be sufficient to ensure  a good  key-in (see Section 5).   In
cases where the low permeability  zone is hard  bedrock, however,  the excavation
process  may be  much more  complicated  and costly, and may not be  necessary.
In many  cases,  a  sufficient  seal  can  be formed  between the  wall  and the
bedrock  by scraping the rock surface  clean with the excavation equipment.
Depending  on  the  condition of the bedrock, and  the  anticipated hydraulic head
the  connection  must withstand,  the  weight  of the backfill pressing against
bedrock  may form  a sufficiently tight seal that will meet the designed
permeability  requirements (D'Appolonia  1982).
           3.1.2.2  Hanging  Slurry  Walls
     Hanging  slurry  walls  are  so  called  because  they are not  keyed  into a low
 permeability  zone.   This configuration is  used to  control contaminants, such
 as  petroleum  products, which do not mix  with  the groundwater  but  float on top
 of  it.   In  such  cases, the  slurry wall need only extend  into  the  water table
 to  intercept  the contaminants  (see Figure  3-2).  The exact depth  of the wall
 will depend on the thickness of the floating  contaminant layer  and  the
 historically  lowest  water^able eJLevation.  Other  considerations^include the
 extent  to which  the  weight  of  the contaminant might  have depressed  the water
 table,  and  what  effect removal of the contaminants would have on  the water
 table.
      3.1.3  Horizontal Configuration
     Horizontal configuration  refers  to  the  positioning  of  the  wall  relative
to the  location of the pollution  to be controlled  and  the direction  of
groundwater  flow  (gradient).   Based on horizontal  configuration,  slurry walls
may completely surround the pollution source  or be  placed up  or downgradient
from it.

     These configurations and  the  type of  situations to  which each can  apply,
are described below.
          3.1.3.1  Circumferential Wall Placement
     Circumferential placement refers to placing a  slurry wall completely
around the wastes contained within a site.  Although  this requires  a greater
wall length, thus greater cost, than either upgradient or downgradient
placement alone, it does offer some advantages, and is a common  practice.  A
                                     3-3

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                 Figure 3-2.
           Hanging Slurry Wall
                    Leaky
                  Fuel Tank
Extraction
  Weil
Water
Table
                     Floating
                   Contaminant
                    3-4

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circumferential slurry wall, when used with a surface  infiltration barrier
(cap), can greatly reduce the amount of leachate generated within a  site.   If
a leachate collection system is used a waste site can  be virtually dewatered.
This offers the advantages of vastly reduced leachate  amounts and can help
increase the longevity of the wall by reducing the amount of leachate/wall
contact.  As can be seen in Figures 3-3 and 3-4, the direction of flow  is from
the exterior toward the interior.  Consequently, leachate/wall contact  is
minimized while waste containment is maximized.  Figure 3-4 illustrates what
can be achieved in the way of site dewatering.  Walls  used in this fashion
must be very carefully designed.  Because  the head differential  across  the
wall is relatively high in these cases, the backfill will be more prone to
piping and hydrofracturing than if the head difference were lower.   These
problems are discussed in Sections 5.8.8 and 5.8.9.
          3.1.3.2  Upgradient Wall Placement
     Upgradient placement refers to the positioning of a wall on  the
groundwater source side of a waVte site.  This  type of placement  can be  used,
where there is a relatively steep gradient across  the site,  to divert  uncon-
taminated groundwater around the wastes.  In  such  cases, clean groundwater  is
prevented from becoming contaminated while leachate generation is  reduced.  As
can be seen by Figures 3-5 and 3-6, a high gradient is required for Upgradient
placement to be effective.  Unless the groundwater can be. diverted around the
site, and be drained to a lower elevation, it can  flow around and  return to
the same elevation or rise to the surface to  overtop the wall.

     The use of a wall placed only Upgradient of the wastes  is limited in the
types of situations to which it is applicable.  Depending on the  actual  site
setting, and the contaminants involved, an upgradient wall may be  keyed  in  or
hanging.  In either case, drainage and diversion structures  are likely to be
needed to successfully .alter the flow of clean  groundwater.
          3.1.3.3  Downgradient Wall Placement
     Placement of a slurry wall at a site on  the  side opposite  the groundwater
source is referred to as downgradient placement.  This placement configuration
does nothing to limit the amount of groundwater entering  the  site and  so  is
practical only in situations, such as near drainage divides,  where there  is  a
limited amount of groundwater flow from upgradient.  Such a situation  is
illustrated in Figures 3-7 and 3-8.  It should be noted that  this positioning
does not reduce the amount of leachate being  generated, but acts as a  barrier
to contain the leachate so it can be recovered for treatment  or use.   Although
this placement may be used as a keyed-in wall for miscible or sinking  contam-
inants, it is most often used to contain and  recover floating contaminants.
In either case, compatibility between the wastes  and the  wall backfill is
important because contact between the two would be difficult  to avoid.  In
addition, care must be taken in designing a downgradient  wall installation to
                                     3-5

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                   Figure 3-3.
   Plan of Circumferential Wall Placement
Groundwater Flow
                                          Slurry Wall
                                      Extraction Wells
                   3-6

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                         Figure 3-4.

Cut-away Cross-section of Circumferential Wall Placement
              ^gpiMp^-i-iii Wastes O^yJ^
                                  ___—•


                               ^
                                 O^AV.O-xS   .0 „    <.<(
                        3-7

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              Figure 3-5.
Plan of Upgradient Placement with Drain
              3-8

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          Figure 3-6.
   Cut-away Cross-section of
Upgradient Placement with Drain
          3-9

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               Figure 3-7.
  Plan of Downgradient Placement
Groundwater Divide
                                    Extraction Welte
                                       Slurry Wall
                3-10

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                   Figure 3-8.
Cut-away Cross-section of Downgradient Placement
                   3-11

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ensure  the build up  in head behind  the wall does  not  result  in  overtopping  of
the wall by  the contaminated  groundwater.

     The above discussion centers on  slurry walls  used  to  control  the
groundwater  regime in the vicinity  of pollution sources.   However,  slurry
walls,  especially soil-bentonite walls,  are also  used for  the control  of
methane and  other landfill gases (Lager  1982).  It has  been  shown  that both
the water table and  fine, moist soils can be effective  barriers  to  gas
migration (Moore 1977).  This  implies that for gas control,  the  slurry wall
may be  either keyed-in or hanging,  whichever is shallower.   A gas  control
slurry  wall  will be  placed opposite the  waste site in the  direction or
directions of gas migration,  and so could be placed on  only  one  side,  or
completely surrounding the site.  It  should be noted  that  to be  truly
effective in controlling the  gas migration, venting,  and particularly  forced
venting of the gases is recommended (Rovers, Tremblay,  & Mooij  1977).

     In summary, slurry walls  can be  applied to a  pollution  problem in a
variety of ways.  Table 3-1 shows the possible combinations  and  outlines their
typical uses.  It should be remembered that the effectiveness of the completed
slurry  wall  which is a passive measure,  will be dependent  not only  on  its
configuration and proper construction, but on the  other remedial measures used
in connection with it, in particular, active methods  of handling groundwater,
e.g., wells  or drains.


3.2  Associated Remedial Measures and Practices


     The effectiveness of slurry cut-off trenches  can be dramatically
increased by incorporating additional remedial measures into the overall plan
addressing the problem.  Some  of these measures are:

     •  Groundwater  pumping

     •  Surface and  subsurface collection

     •  Surface sealing

     •  Grouting, sheet piling or synthetic membrane  installation.

These measures affect the hydrologic environment at a site,  and  can  result  in
a more  efficient and effective control program.  The  following sections
discuss additional control measures, giving a description, and mentioning
installation considerations"when they are used with slurry walls.  More
detailed discussions of each technology can be found  in the  EPA  "Handbook for
Remedial Action at Waste Disposal Sites", EPA-625/6-82-006,  June 1982.


     3.2.1  Groundwater Pumping


     Groundwater pumping involves the installation of a series of wells or
wellpoints located such that  the cones of depression  formed  while pumping each
                                     3-12

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                                   TABLE 3-1.
                     SUMMARY OF SLURRY WALL CONFIGURATIONS
   Vertical
Configuration
             Horizontal Configuration
                   Circumferential
                     Upgradient
                   Downgradient
Keyed-in
                   Most common
                   and expensive use
Most complete
containment

Vastly reduced
leachate
generation
Not common

Used to divert
groundwater
around site in
steep gradient
situations.

Can reduce
leachate
generation

Compatibility
not critical
Used to capture
miscible or sinking
contaminants for
treatment or use

Inflow not
restricted, may
raise water table

Compatibility very
important
Hang ing
Used for float-
ing contaminates
moving in more
than one direction
(such as on a
groundwater
divide)
Very rare

May temporarily
lower water table
behind it

Can stagnate
leachate but not
halt flow
Used to capture
floating contami-
nants for treatment
or use

Inflow not
restricted, may
raise water
table

Compatibility very
important
                                     3-13

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will intersect.  The result is a locally depressed water table in the area
being pumped.  Pumped groundwater can be treated, if contaminated, and
reinjected.

     There are several ways in which this measure can be applied in concert
with slurry walls.  In a situation where a wall is containing a contaminant
plume, pumping can remove trapped, contaminated groundwater.  This reduces the
concentration of contaminant in contact with the wall.  This may be important
if there exists a possibility of wall degradation due to chemical attack, or
if the recovered contaminants are of some value.

     In another situation where a wall is diverting groundwater flow away from
a waste disposal site, pumping can reduce the hydrostatic pressure exerted
against the wall.  This reduces the rate of flow through the wall, since
Darcy's law states that the rate of flow is dependent on hydraulic gradient
across the wall.  This may be important in situations where a large head
difference is anticipated across the wall.  Reducing the head difference also
reduces the possibility of wall failure through piping.

     Using cut-off walls and pumping concurrently has several advantages.
First, the reliability of the wall is improved by reducing  the probability of
chemical attack or piping.  In many instances, pumping  systems are used to
protect the wall by keeping leachate away from it.  Second, since the  slurry
wall is creating a low permeability boundary, the rate  of pumping needed to
lower the water table elevation or remove contaminants  is reduced.

     When a well is pumped, the elevation of the water  table is lowered in a
cone-shaped manner (see Figure 3-9).  This effect is known  as drawdown.  In
order to lower the water table over a wide area, the drawdown "cones"  for
several wells must intersect (see Figure 3-10).

     Drawdown  is affected by the following factors:

     •  Pumping rate
     •  Permeability and thickness of water bearing zone

     •  Manner of groundwater recharge

     •  Presence of boundaries

     •  Length of pumping time.

The  calculation of drawdown  is one of  the most  important  exercises  in  design-
ing  and installing well points or extraction wells.  The  location  of wells  or
well points,  the depth of the  screen,  and  pumping rate  are  all  variables
determined by  the desired amount of drawdown.  Extensive  geohydrologic testing
of  a site is  usually required  for satisfactory  solution of  the  equations.
                                      3-14

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         Figure 3- 9.
Shape of Drawdown "Cone'
            Well
       Before Pumping
            Well
                 'IT
                    2 T.
                      3 .TA
                            Ti
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                     Figure 3-10.
Intersection of Drawdown Cone of Two Adjacent Wells
                     Drawdown
                     3-16

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           3.2.1.1  Pumping Systems


      There are two types of pumping techniques used for dewatering:  well
 points and extraction wells.  While similar, each technique has special
 applications.
                a.  Well Points
      Well points are made to be driven in place, jet placed by water, or
 installed in open holes.  They consist of a slotted screen, reinforced and
 pointed at one end, and connected to a riser pipe or casing of the same or
 smaller diameter.  The most common practice is to water jet to the desired
 depth,  flush out fines, and leave the coarser material to collect around the
 well point.   The point can then be driven into coarser material.  Once in
 place,  the well points are connected to a header pipe (see Figure 3-11).

      Well points can be from 1.4 inches in diameter up to 6 inches in
 diameter.  The size of a well point is generally determined from experience,
 and is  a^function of the permeability of the aquifer.  Fine-grained materials
 (e.g.,  silts and clays) usually require smaller well points.  Well points are
 not installed to depths greater than 20-25 ft for groundwater pumping purposes
 due to  the fact that suction pumping is ineffective at depths greater than
 20-25 ft.                                              .

      Spacing well points is based on the radius of influence of each well and
 the composite effects required  to achieve the desired drawdown.   Once
 theoretical  drawdowns and spacing are developed using equations, a few well
 points  can be installed and tested to determine actual values,  since equations
 assume  idealized conditions.  Adjustments can be made,  which usually require
 minor decreases in spacing,  thus achieving the desired decline  in water table
 elevation.

      The  location of well points is  complicated by the presence  of the cut-off
 wall  of much less permeability  than  the surrounding material.   The less
 permeable zone  has  a great impact  on the  cone of depression formed by well
 points  (see  Figure  3-12).   Drawdown  is  much  greater near  the wall, because
 rate  of flow is  less through  the wall than through the  surrounding matrix.
 This  reduces  the  area  from which water  can be  drawn during  pumping,  resulting
 in  a  faster  rate  of  drawdown  near  the wall.   This is  useful  since it  requires
 less  pumping  capacity  to  achieve desired  drawdown near  a  slurry  wall  than it
 does  in the  absence  of  such a barrier.

     Locating well points  in  relation to  slurry walls  is  dependent upon
 whether the  slurry wall  is upgradient or  downgradient of  a contamination
 source.  Well points associated  with  upgradient  walls can be  used to  dewater
behind the wall once it  is in place,  or they can  be used  to  reduce  the  water
 table upgradient  of  the wall, reducing  the hydraulic gradient across  the wall.
These situations  are illustrated in Figures 3-13,  3-14, and  3-15.
                                     3-17

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                          Figure 3-11.
        Schematic of a Well Point Dewatering System
Copyright 1975 by Johnson Division, UOP Inc.
Used with Permission
                           3-18

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                      Figure 3-12.
      The Effect of Drawdown in the Absence
           and Presence of a Slurry Wall
           A. Drawdown in Absence of Slurry Wall
Slurry Wall
  SSJ

                                   To Discharge
 /ss
           B. Drawdown in Presence of Slurry Wall
                        3-19

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                              Figure 3-13.
Well Point Located Behind an Upgradient Slurry Wall Cut-Away View
                     A. Before Well Points Are Pumped
          To Treatment and Reinjection
                                  Direction of Row
                             B. After Pumping

                                 3-20

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                              Figure 3-14.
Well Points Located Behind an Upgradient Slurry Wall, Plan View
                    Slurry Wall
      Direction of Flow
                                        Well Points
                                         To Treatment and/or Reinjection
             C. Map View of Slurry Wall and Well Point System
                                     3-21

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                      Figure 3-15.
Well Points Located Before an Upgradient Slurry Wall
Well Point
                    A. Before Pumping
     To Discharge
                     B. After Pumping
                          3-22

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      Well points associated with downgradient walls are commonly used  to
 remove contaminated groundwater trapped by the wall.  Installation can be  such
 that the concentration of contaminants in groundwater near the wall  is sub-
 stantially reduced, lowering the possibility of chemical attack and  removing
 the contaminant from the subsurface environment.

      Groundwater pumped from this type of system must be treated before being
 reinjected.   Treatment systems are discussed in a following section.

      The depth and design of the well points is dependent upon whether the
 contaminant  plume is heavier or lighter than water.  Installation of well
 points downgradient of a site can result in reducing or virtually eliminating
 the flow of  groundwater through the slurry wall.

      Water pumped from the well points can be reintroduced into the subsurface
 environment  by one of several means.  These include:

      •  Reinjection wells or well points
      •  Surface spraying

      •  Recharge trenches.

 Reinjection  wells  or well points are simply wells or well points where
 recovered  or treated water  is pumped back into  the aquifer.   Spraying refers
 to  recharge  using  large area sprayers, much like irrigators  used in arid
 farmland.  Trenches  are simply excavated  ditches where  water  is  allowed to
 infiltrate into the  subsurface.

      Of  the  three methods,  a recharge trench  is  the most  cost-effective.
 Water  is pumped into the  trench  and  infiltrates  into the  subsurface.   The
 trench can be  dug with  a  backhoe and often  requires little or  no maintenance.
 Maintenance, when necessary  involves removing from the  trench  materials that
 may be clogging it,  such  as  accumulated wind blown material or bacteria and
 fungus.  The trench  results  in a local elevation in the water  table,  but since
 water  is infiltrating at  its  own rate, as opposed  to reinjection,  the impact
 is not as severe.  Reinjection wells  or well points  are more costly  to
 install, incur  costs through  operation and maintenance, and may  result  in  a
 substantial  rise in  the local water  table.  Sprayers are  also  costly  to
 operate and maintain, and site considerations (such  as a  need  for  large areas
 of well-drained soil) may prohibit their use.


               b.  Extraction/Injection Wells


     Extraction wells are similar to well points in  that they  lower the water
table by pumping.  They differ from well points  in several ways.  Wells are:

     •  Able  to go much deeper

     •  Not limited to unconfined aquifers

     •  Capable of almost unlimited capacity.
                                     3-23

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     Extraction/Injection wells are installed using one of several^drilling
techniques, depending upon the conditions existing at a site.  In  installing
these wells, a hole is drilled to the desired depth; the hole being of a
diameter larger than that of the well.  The well consists of a screen much
like that used in a well point though usually longer, topped by a  riser pipe
to the surface.  Appropriate size material, e.g., gravel or sand,  is added to
fill the annulus between the well and the drill hole.  Usually, grout or some
other sealant is used to isolate the formation being pumped from other
formations.

     The wells themselves must be of sufficient diameter to house  a submer-
sible pump and to accommodate expected flow.  Casings and screens  must be
sufficient to withstand pressures developed during pumping.

     In  selecting a location for extraction/injection wells drawdown cones and
radii of influence must again be calculated.  In using extraction  wells,
larger capacities can result in  larger radii  of  influence, reducing the  number
of wells needed.  Wells can be placed either  upgradient or downgradient  of a
slurry wall, much like well points,  and will  affect  the water  table in much
the  same way.  Extraction wells  are  suitable  for use in conjunction  with  ^
slurry cut-off walls  if the depth  is beyond the  effective  range  of well  points
or  if high capacities are required.

               c.  Skimmer Systems

      Skimmer  systems  have applicability  in situations where  contaminants are
lighter  than  water and  form  layers  on  top of  the water table.  Systems  have
been developed that  rely  on  a  series of  pumps and  probes  which lower  the water
table  and  pump the  floating  contaminants.  The  probes detect the concentration
of  contaminants  being pumped,  and  automatically shut down or start-up the
system when certain  trigger  concentrations are  reached.   These systems have
been used  successfully to recover  oil or petroleum products which have made
their way  to  the water  table (see  Figure 3-16).   Proponents of these systems
claim that they are  so  sensitive that recovered material is virtually 100%
 free of water, and  can be re-used  as is,  without additional processing (Oil
Recovery Systems, Inc.  1982).

      Skimmer systems are made up of three major components.  They are:

      •  Submersible  pump to create a cone of depression

      •  Probe assembly to prevent the submersible pump from pumping
         contaminants

      •  Recovery unit, which uses its own probe system and pumps  high
         concentrations of contaminants.

      Installation and operation of  the system is relatively straightforward.
 A well  is drilled which intersects  the contaminated layer and water table.
 The well  is cased using a perforated casing  allowing  the  passage  of both
 contaminant and water.  A submersible pump lowers  the water table, causing  the
 contaminants  to migrate to the  recovery  well.   A probe which  differentiates


                                      3-24

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 Water Outlet (After Testing)
                                Figure 3-16.
                          Skimmer Systems
                                A. Floating
                             B. Pump Recovery

Source: Oil Recovery Systems Inc. (Undated)
                                   3-25

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between water and the contaminant is located above the submersible pump and
automatically shuts the pump down when contaminants are detected.  The
recovery unit, also with a probe, pumps the contaminant layer and shuts off
when concentrations fall below a certain level.  Contaminants are stored in a
tank for final disposition, and the pumped water can be reinjected after
testing and treatment.

     There are two types of recovery units; one which "floats"  on top of^the
contaminant layer, and one which pumps from within the layer.   The floating
systems require larger diameter wells, usually over 18" in diameter.  The
pump system can be used in smaller diameter wells but usually not less  than
6 inches in diameter.  The pump recovery units have a higher pumping rate  than
the floating units, and can be used at greater depths.  New units are
available which contain filters to further concentrate the contaminant  during
recovery.

     Skimming recovery systems can be used in  concert with cut-off walls to
effectively remove floating contaminants trapped by a wall.  The wall can
prevent further migration  of  the contaminant,  causing a build-up of  the
material at the well.  Either type of recovery unit can then be used to
recover the "ponded" material.


           3.2.1.2 Groundwater Treatment


     The  type of  treatment system  used  depends on the  contaminants  present.
Treatment  systems may  be  relatively  simple or  quite  complex.   If publicly
owned  treatment  works  (POTW's) are near,  they  may be  used to treat  water but
preliminary  on-site  treatment may  be  necessary in order  to  meet certain limits
 set by the POTW.   Using  an existing facility will substantially reduce the
cost  of treatment.  If the water must be  reinjected,  more complete  on-site
 treatment  may be necessary prior to reinjection.   In any case, treatment
 systems must  be  designed  to meet site-specific situations.   Treatability
 studies should  be conducted to determine  effectiveness of the  treatment system
 options.   Mobile labs and treatment modules are available to  perform on-site
 studies and  treat groundwater.


      3.2.2  Collectors and Drainage Systems


      Collectors  and drainage  systems can be used in conjunction with slurry
 walls to control surface and subsurface waters.  Surface water control
 measures, for example, can be used at a slurry wall site to prevent water from
 infiltrating into the disposal area.  In combination, surface  water controls
 and a slurry wall can often  serve together to curtail leachate generation.
 Surface trenches can be used  as recharge points during the dewatering  of  a
                                       3-26

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 slurry wall  site.   There are numerous types of surface water collectors among
 which are the following:

      •  Dikes and  berms

      •  Ditches, diversions, waterways

      •  Terraces and benches.

      Subsurface drainage systems are designed to intercept and collect shallow
 subsurface water flow.   In conjunction with a slurry wall, as with surface
 water controls, these systems can intercept water before it reaches the
 disposal area,  thus controlling leachate generation.  The interception and
 re-direction of groundwater in the vicinity of a slurry wall may also serve to
 relieve water pressure  on the wall itself.   The basic components of a subsur-
 face  water drainage or  collection system are listed below:

      •  Gravel  trenches or permanent drains
      •  Drain filter material

      •  Basin,  sump or  pit.

      The design and use of surface and subsurface water control  measures  is
 always dependent upon site specific  conditions.   For a more complete dis-
 cussion of these technologies and their applications,  see U.S. EPA (1982).


      3.2.3  Surface Sealing


      Surface  sealing, or capping,  is the process by which surface  areas are
 covered to minimize surface  water infiltration,  control  erosion,  and contain
 contaminated  wastes and volatiles.   A variety of low permeability  cover
 materials  and sealing techniques  are available for such  purposes.

      Surface  sealing can be  particularly important in conjunction  with  slurry
 walls Because one of the major  routes  of infiltration is  vertically along the
 wall  itself^and this could seriously alter  the effectiveness  of  a  wall.   To
 prevent  infiltration, a surface cap  can be  installed which is below grade
 sloping upward  away from the  trench.   This  cap should  be  added after the
 slurry  trench has been  backfilled, and  should  consist  of  low  permeability clay
 or other suitable material.   If  the  area in which  the  trench  lies  is expected
 to accommodate  traffic,  especially if  the wall  is  an initial  step  in a  larger
 remedial action project,  the  surface  cap must  be constructed  to  distribute
weight  and avoid placing a stress directly  upon  the  wall.   To accomplish  this,
 a special  "traffic  cap"  can be  installed.   This  cap  also  is V shaped sloping
up and  away from the  trench,  but  is  backfilled with  alternating  layers  of
clay, gravel, and geotextiles.  The  geotextiles  can  be anchored with soil  away
 from the trench to   provide additional  strength.

     There is a variety of materials  available  for  surface  sealing  purposes.
Fine-grained soils   such as clays  and silty  clays have  low  permeabilities  and
are therefore best   suited  for capping because  they  resist  infiltration  and
                                     3-27

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percolation of water.  Very often different soil types can be blended together
to broaden the grain size distribution and minimize the infiltration capacity
of the soil cover.  Chemical stabilizers, cements, lime, or fly ash can also
be added to cover soils to create stronger and less permeable surface
sealants.  Finally, synthetic membrane liners and asphalt mixtures can also be
used as surface sealants.


     3.2.4  Ancillary Measures


     A site requiring remedial action, is seldom the  ideal setting for any one
remedial technique and in the case of slurry cut-off  walls there are several
additional measures that can be used to  reinforce the integrity of the^ wall.
These techniques include grouting, sheet piling and the use of synthetic
membrane liners.  The following section  will describe these three techniques
and discuss how they can be used in conjunction with  slurry cut-off wall
installations.


           3.2.4.1  Grouting


     Grouting  is  the practice of pressure  injecting a fluid material  into
soil, rock or  concrete so as to decrease the  soil/rock permeability  and/or
strengthen the formation.  Three major types  of  grouting  techniques  are
practiced  in  the  construction industry:

     •   Area  Grouting -  Low  pressure blanket  or  area  grouting performed  to
         seal  and  consolidate soils near  the  surface

     •   High-Pressure Grouting  - Grouting at  depth  to seal fissures  or small
         void  spaces

     •   Contact Grouting -  Injection  of  a slurry at  the outer surface of an
         excavation to  seal  possible passages  for water flow.

      The latter two  are  the  more  commonly used techniques when grouting^is^
necessary as  part of a  slurry  cut-off  wall installation.   One of the principle
elements in  the design of a cut-off wall is the connection between^the wall
 and the underlying aquiclude.   Keying  a  cut-off trench into the existing
 aquiclude requires depth enough to penetrate any weathered zones, pervious
 lenses, desiccation cracks  or  any other  geological features that might allow
 seepage under the cut-off wall.  In many situations  trench excavation can be
 accomplished using standard excavation equipment, however, excavating into
 rock can pose problems.   Even in a situation where the rock mass^is jointed^or
 fractured, it is often next to impossible to excavate without using percussion
 tools or heavier machinery that can further fracture  the rock mass
 (D'Appolonia 1980).   If the trench construction equipment on-site includes a
 crane,  no additional equipment would be needed other  than a chisel and
 clamshell which are suspended from the  end of the crane.  Use^of heavier
 equipment can often be quite costly and time consuming.  Consideration must


                                      3-28

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 also^be  taken  for  the  area surrounding the site in a decision to use heavy
 machinery.   Often  there is a problem with either site access or physical
 constraints  on the site itself and heavy equipment is impractical.   In many
 cases,  as an alternative to using heavier and more expensive equipment and
 attempting  to  advance, the cut-off into the rock, the decision is made to grout
 the interface  between  the cut-off wall and the rock (Figure 3-17).   This can
 be  accomplished by using either one of two grouting techniques.  The a^uiclude
 can be  sealed^during trench excavation,  prior to wall' installation by the
 contact  grouting method or the wall-aquiclude contact can be reinforced after
 the wall has been  emplaced.  The latter case entails the use of high-pressure
 grouting.

      Bottom  key grouting is one application of grout injectioti associated with
 slurry cut-off wall,installations.   Additional practices include grouting one
 or  both  ends of the completed wall  to some existing structure on site and,
 area grouting  of soil  material along sections of a constructed wal'l that need
 extra reinforcement.

      It  is sometimes practical to utilize structures already existing on-site
 as^part  of a pollutant containment  solution.   An example of such a  pre-
 existing structure might be a flood protection wall or dike.  If a  remedial
 action project required the construction of a slurry cut-off wall on
 the river side of  a dike to prevent contaminant migration into the  surface
 waters,  it might be possible to contain  the contaminant  plume using the dike
 as  part  of the containment wall by  grouting the wall-dike contact at one or
 both ends (Figure'  3-18).   There are,  of  course, many factors not discussed
 here that must be  considered before arriving at such a decision, such as the
 permeability of the dike  material,  depth of the contaminant plume,  or
 direction of groundwater flow.   It  might be necessary,  for example,  to grout
 only the  downstream end  of the  cut-off wall  depending upon the areal
 groundwater--flow pattern and contaminant movement.

      Area grouting  of  soil  or  loose material  along  a slurry cut-off wall might
 be  necessary to retard erosional  processes along the length of the  wall.   A
 situation in which  this  type of grouting technique  could be applied, might be
 where a wall has been  installed along a  steep slope.   Erosion rates can be
 significantly  reduced  by  grouting loose  material  surrounding the wall.

     grouting  materials  fall into three  groups:   cement,  bituminous,  and
 chemical.  Some  specific  grout  mixtures  include Portland cement,  sand-cement,
 clay-cement, clay-bentonite, bituminous  emulsions,  sodium silicate,  and
 acrylamide.  The applicability  of each material  is  based on grain size  or
 fissure size,  and  the  anticipated area of  grout  penetration.   The subsurface
 environment must be investigated  thoroughly prior to  the  design  of  a grouting
 program.  Initially, it must be determined with  tests whether or not  a  site
 is,   in^fact,  groutable.  Areas  of extremely low permeability or  great
variability may not be groutable.   Other  tests  and  investigations will  provide
 the  necessary hydrogeologic  information  in order  to  choose  the best-suited
grout or grouts.
                                     3-29

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     Figure 3-17.
Bottom Key Grouting
      Cut-off Wall
       3-30

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                 Figure 3-18.
        Cut-off Wall-Dike Contact
Stream
 Grouted
Wall-Dike
  Tie-In
                3-31

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          3.2.4.2  Sheet Piles


     Sheet piles are typically used to brace trenches and other excavations,
or to support retaining walls and bulkheads (U.S. EPA 1982).  Their main
utility is to hold earth materials in place.  The use of sheet piling in
conjunction with slurry cut-off walls is yet another alternative remedial
measure, in which it can be used as an erosion control.  Examples of this type
of sheet pile utilization, however, have not been identified in the reviewed
literature.  The following is a discussion of sheet piles and their most
common applications, in addition to possible applications in adjunct with
cut-off walls.

     Sheet piles can be fabricated from three materials; wood, precast
concrete, and steel (U.S. EPA 1982).  Wood is generally an  ineffective water
barrier and because slurry cut-off walls are generally constructed at sites
where leachate or groundwater containment is the objective, it would not be
advisable to use wooden structures.  Concrete sheet piles are used primarily
in situations that require a great amount of strength, such as is needed
during dam construction.  Sheet piling strength, in this degree, most likely
would not be a requirement in a leachate containment remedial project.  Steel
sheet piling, in a case where sheet piling was chosen to be an additional
remedial measure, would be, in comparison, the most effective in terms of both
cost and potential for groundwater cut-off.

     Steel sheet pilings are installed by driving the interlocking piles into
the ground with a pneumatic or steamdriven pile  driver.  In some cases, the
piles are pushed into pre-dug trenches (U.S. EPA 1982).  The lengths of piles
range between 4 and 40 feet and their widths range between  15 and 20 inches.
Many steel pile manufacturers offer their own shape of piling and often their
own  form of  interlock.  Steel sheet piling can be used in conjunction with  a
slurry cut-off wall as an erosion control or resistance mechanism.  In slurry
cut-off wall projects where contaminant containment  is of utmost  importance,
and  sheet piles are to be used as erosion controls in a location where there
may  be  leachate or groundwater build up,  it  is crucial  that the piles  are  as
well locked  as possible to minimize seepage  through  the interlocks.  For this
reason, the  pilings should be assembled at  their edge  interlocks  before  they
are  driven into the ground.  When initially  placed in the ground,  sheet piling
is permeable.  The edge  interlocks, which are necessarily loose  to  facilitate
placement, allow water passage.  With  time,  however,  soil particles  are washed
into the pile seams and water cut-off  is  effected  to  a  greater  extent
(U.S. EPA  1982).  The time required  for sealing  to take place  depends  on  the
rate of groundwater flow  and  the  soil  texture  involved.   In very  coarse,  sandy
soils,  the wall may never seal.  Additionally,  steel  sheet  piles  should not be
considered for use  in extremely  rocky  soils.  Even  if enough force can be
exerted  to drive  the piles around  or  through cobbles  and boulders,  the  damage
to the  piles might  render them  ineffective.
                                      3-32

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          3.2.4.3   Synthetic Membrane  Liners
      Synthetic membrane  liners  can  also  be  used  in conjunction with  slurry
cut-off walls and  comprise  the  third  group  of  associated  remedial  measures.
In  certain  situations,  it may be  possible  to reinforce  the  integrity of the
cut-off wall with  the  addition  of a synthetic  liner.  The liner materials  are
available in a variety of compositions with relatively  well  known  chemical
compatibilities.

      Placement of  a  synthetic liner into the ground as  a  vertical  barrier  is  a
relatively  difficult procedure.   The  liner  is  suspended vertically in and
along one side of  a  slurry  filled trench and the trench is  then backfilled.
Placement of a liner within a cut-off wall  does  have  disadvantages.   The liner
material is extremely  heavy and is  stored  and  purchased on  large rolls.
Frequently, suspending  the  liner  vertically in the trench is next  to impos-
sible because of the size and weight  of  the sheet.  Also, once the liner is
successfully placed  in  the  trench,  there is always the  possibility that  a
bottom corner of the liner  will be  uplifted during the  backfilling process
(Villaume 1982).   If this were  to happen, water  might be  permitted to flow
around the  barrier.  Careful inspection  should be enforced  during  the
installation process.

      A possible way  of overcoming problems  that  might arise  due to the weight
and bulk of the liner material  itself, would be  to install  the liner in
smaller sections.  However,  care  must be taken to ensure  that there  is
sufficient overlap of  the sections  so as not to  permit  water seepage.  In
conclusion, the use  of  liners as  secondary  containment  measures can  reinforce
the integrity of the wall and create  additional  protection  against possible
seepage due to chemical  attack  on the backfill material.
3.3  Summary
     The effectiveness of  a  slurry wall, with  respect  to  both  costs  and
technical performance, is  determined  in  large  part by  the configuration
employed.  This configuration  is determined  by the specific  remedial  goals  of
a specific site.  For most uncontrolled  hazardous waste sites,  a  circular,
keyed-in slurry wall offers  the most  complete  containment.   Nonetheless,
slurry walls installed for hazardous  materials containment are  nearly always
used in conjunction with some  other remedial techniques.   These range from
relatively simple measures such as surface sealing,  to complex  groundwater
extraction and treatment systems.  Effective use of  slurry walls  for  waste
site remediation is dependent  on the  selection of the most appropriate
configurations and materials,  and on  the selection of  the other remedial
measures employed with it.
                                     3-33

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                                   SECTION 4

                    SITE INVESTIGATION AND CHARACTERIZATION
     The data from a site investigation are used by a design firm to formulate
specifications for the remedial measures to be implemented at the site.  These
specifications are then used by the firms installing the slurry cut-off wall
and other remedial measures.  Because all later actions are dependent on the
quality and completeness of the site investigation, the effectiveness of the
entire remedial action is directly determined by the thoroughness of the site
investigation.

     This section discusses the types of data that should be acquired during
the site investigation, possible data sources to be researched, and methods
used to conduct field and laboratory analyses.  The physical constraints
imposed by the site1s surficial features are discussed, followed by a
description of subsurface site investigative procedures.  Finally, information
is presented on the procedures used to characterize wastes and leachates and
their effect on wall quality and durability.
4.1  Physical Constraints


     There are a number of physical considerations regarding both the site and
the working area that affect the applicability of slurry wall types and the
techniques used for their construction.  Table 4-1 summarizes the various
physical constraints that may be encountered and must be resolved.  These
constraints include:

     •  Topography

     •  Vegetation density

     •  Land drainage patterns

     •  Availability of water

     •  Location of utility crossings

     •  Proximity of property lines, major residential areas and
        transportation routes
                                     4-1

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                                                     TABLE 4-1.

                                  TYPES  OF  PHYSICAL  CONSTRAINTS  AND  THEIR EFFECTS
                                            ON SLURRY WALL CONSTRUCTION
  Physical Constraints
Possible Affected Areas
Approach Required
  Topography:   Irregular  contours
                Steeply  sloping  terrain
  Necessary equipment

  Site access and work space

  Type of wall selected
  Selection of equipment capable of
  operating in site specific terrain

  Extensive site preparatory work -
  leveling  of areas for site entry and
  work space

  Use of CB wall in panels or diaphragm
  wall
-o
i
   Site  Access  and
    Work  Space:  Site  congestion/
                 traffic
                 Steep terrain
                 Dense vegetation
                 Lack  of  head room
                 Insufficient space
                 for mixing
• Extent of site prepara-
  tion and pre-construction

• Type of equipment selected

• Type of wall selected

• Wall construction process
  Special equipment needs; construction
  of access road; leveling of working
  area; clearing of dense vegetation

  Amount of head room affects type of
  equipment selected or needed to
  relocate obstruction

  Amount of work space affects wall type
  selected; SB wall requires space for
  mixing; CB wall requires less area for
  operations, but it is more expensive;
  SB can be mixed away from trench but
  this approach may mean CB is cheaper
  for Che site
                                                                                                    (continued)

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                                             Table 4-1.  (continued)
 Physical  Constraints
 Site  Access  and
  Work  Space:
  (continued)
Utilities:
            Abandoned  sewers
            Pipelines
            Leakage  from water
              mains, sewers
            Power/telephone cables
 i
UJ
                      Possible Affected Areas
                               Approach Required
                      • Equipment  selection

                      • Construction  process
                       (operations)

                      • Problem  control  methods

                      • Sudden slurry  loss  and
                       possible trench  collapse
                       if unanticipated  pervious
                       zone,  i.e., sewer piping
                       is encountered and
                       ruptured
Cultural Features:
Old foundations
Nearby structures
Overhead structures
* Equipment selection

• Construction process
  (operations)

• Problem control methods
                                                    • Extra time needed for site pre-
                                                      paration and construction

                                                    • Appropriate easement clearances
                               • Special  equipment necessary for
                                 excavation  around piping and
                                 sewer lines;  or need for manual
                                 excavation

                               • Sequence  of trench segment
                                 excavation  may  change  if
                                 utility discovered;  excavate
                                 other areas first

                               • Watermain or  sewer leakage  may
                                 cause slurry  contamination  and
                                 loss  of trench  stability; a control
                                 plan  necessary  at  outset  of project

                               • Sudden slurry loss requires immediate
                                 placement of  solid materials (soil,
                                 debris) into  trench
                                                                       • Foundation  penetration  to  isolate  site

                                                                       • Excavation  around  foundations,  or
                                                                         incorporate foundation  into wall;  if
                                                                         foundation  support needed  CB or dia-
                                                                         graphm may be required
                                                                                                 (continued)

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                                            Table 4-1.  (continued)
Physical Constraints
Possible Affected Areas
                                                                       Approach Required
Cultural Features:
  (continued)
Other:  Availability of water
£.      Time of year; water table
£       fluctuations, temperature
        Subsurface geology; large
        subsurface boulders
        Type of wall backfill
  • Headroom
                                                                       • Special equipment needed  if  breaking
                                                                         old foundations

                                                                       -• Tall equipment,-e.g.,  cranes, may  be
                                                                         restricted

                                                                       • More time may be necessary  for
                                                                         operations

                                                                       • Experienced  problem  control  personnel
                                                                         necessary
                                           Equipment selection

                                           Slurry mixing

                                           Time needed  and
                                           available for project
                                           completion
                                         • Site  preparation

                                         • Problem control methods
                              • Equipment selection  for boulder
                                destruction or excavation

                              • Site may need de-watering system
                                if water table is high or is  expected
                                to rise

                              •SB backfill cannot be mixed in sub-
                                freezing temperatures

                              • CB will not set  in certain temperature
                                ranges

                              • Experienced problem  control-personnel
                                necessary

                              • Transport of water to site if none
                                available
References:  (1) Ryan 1980a, (2) U.S. Army Corps of Engineers 1978,  (3) Xanthakos  1979,  (4) Wetzel  1982,

             (5) Tamaro 1980, (6) Ryan 1980b, (7) Namy 1980.

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     •  Site accessibility

     *  Other man-made features.


     4.1.1  Topography
     Topographic features that should be noted during on site investigation
include the steepness of the slopes on the site, the types of land drainage
patterns present, and the proximity of the site to major bodies of water.
These features can be discerned from topographic maps but should also be noted
during site investigations. -                     >
     4.1.2  Vegetation Density
     Areas having extremely dense vegetation should be expected to require
extra site preparation prior to field investigations or construction
activities.  Dense vegetation can inhibit access and hide important surficial
features such as small outcrops or erosion gullies.  Surveying of the proposed
trench line and location of the bore holes is also delayed by dense
vegetation.                                               '
     4.1.3  Land Drainage Patterns
     As noted previously, land drainage patterns at the site can be
preliminarily assessed using topographic maps.  Additional information on the
presence of erosion gullies, heads of drainageways, and anomolous features
must be obtained during site visits.  Because surficial land drainage patterns
directly affect subsurface water movement, this site feature should be
carefully assessed.


     4.1.4  Availability of Water

     A great deal of water is necessary during slurry cut-off wall
installation.  The source amount, quality of the water available should be
ascertained during the site investigation.
     4.1.5  Location of Utility Crossings
     If water electric, gas, telephone, sewer or other utility lines cross the
site, the exact locations should be determined and marked so that they are
disturbed as little as possible during the site investigation and subsequent
trench excavation.  If these lines cross the excavation site, provisions for
re-routing must be made.
                                     4-5

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     In addition data on the availability of water, sewer, electricity and
telephone service should be noted.
     4.1.6  Proximity to Property Lines
     The location of the site relative to property lines, major residential
areas, and transportation routes is an important element to be considered
during the site investigation.  If existing structures are very close to the
site, the effects of trench excavation on structural stability must be
assessed, and provisions made for interim structural support.  Residential
structures require special provisions, such as noise control and fencing of
the site.  Major transportation routes transecting the site must be re-routed
If the site characteristics make it necessary to consider installing the
slurry cut-off wall close to property lines, permission of nearby property
owners for access road use or land disturbance may be necessary.  These
factors should be noted in the site investigation report.
     4.1.7  Site Accessibility
     In remote areas or extremely congested locations, site access may be a
problem.  Remote areas may require the construction of roads or bridges and
bringing water and other utilities to the site.  Construction in congested
environments may be complicated by access roads, such as driveways or alleys,
or overhanging obstructions, such as signboards or utility lines.  In these
areas, equipment mobility may be seriously hampered.
     4.1.8  Presence of Other Man-made Features
     Certain man-made features can seriously affect the design and instal-
lation of slurry cut-off walls.  These features should be thoroughly
investigated during the site characterization.  Included in this category of
physical site constraints are:  mines, dams, irrigation ditches and tunnels.
The location, size and other characteristics of these man-made features should
be determined during the site investigation.

     Some of the slurry walls installed to date have been placed in sites
having a number of interesting site constraints.  Two examples of the
procedures used are given below.

     During excavation dewatering at a large industrial plant, Ryan (1980b)
reported that the following constraints were identified for this site:

     •  Concrete foundations under site

     •  Tight access conditions throughout site.
                                     4-6

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In addition to these constraints, the owner needed to maintain access across
the site, the foundations had to be penetrated to isolate the site and its
wastes, and it was hoped that the old foundations could be used as much as
possible as part of the wall.  The final solution to this site involved the
following:

     •  Constructing an open-cut along the foundation alignment

     •  Using a hydraulic ram to break the old foundations

     •  Filling the opencut.

After  these procedures were  accomplished, the slurry trench was excavated  to
its design depth and a CB slurry was  installed.

     At  another site, an SB  slurry trench was to be  installed around  a waste
lagoon.  The  installation took place  on  top of a dike which was 20 feet wide.
The base of the backhoe was  14 feet wide so there was no  problem  using the
backhoe  for excavating the trench.  A bulldozer was normally used to  mix and
place  the backfill,-however, since the bulldozer could  not work in the limited
area on  top of the  dike, a crane with a  clamshell bucket  was used for backfill
mixing instead (Wetzel 1982).
4.2   Subsurface  Investigations


      As  an  initial  step  in  obtaining  information on the subsurface conditions
existing at  a  site,  all  available  sources  of hydrogeologic  data should be
gathered.   These include:   geologic and  topographic maps, hydrogeologic
reports,  aerial  photographs, well  drilling logs, and soil surveys.  By
reviewing published  and  other historical data,  a preliminary characterization
of  the site  can  be made  concerning the subsurface environment.   Table 4-2
summarizes  the principal sources  of available geotechnical  data.

      A description  of the hydrogeologic  framework of an area should include a
discussion  of  the following factors:

      •   Structural  attitude and distribution of bedrock and overlying strata

      •   Chemical and physical properties of these strata including mineralogy,
         and permeability

      •   Weathering  of these strata including the degree of  alteration, the
         pattern  and  depth of weathering  and any evidence of incompetent rock

      •   Groundwater regime, including water table depths,  aquifer types, flow
         gradients and groundwater quality

      •   Soil characteristics including soil type and distribution, particle
         size distribution  and permeability.
                                      4-7

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                                  TABLE 4-2.

               PRINCIPAL SOURCES OF AVAILABLE GEOTECHNICAL DATA
Published Data

  1.  U.S.G.S. Surficial Geology Maps
  2.  U.S.G.S. Bedrock Geology Maps
  3.  U.S.G.S. Hydrological Atlases
  4,  U.S.G.S. Basic Data Reports
  5.  State and County Geologic and Hydrologic maps
        and reports.
  6.  National and Local Technical Journals,
        Magazines and Conference Proceedings
  7.  U.S.S.C.S.  Soil Maps

Unpublished Data

  1.  Local test boring and well drilling firms
  2.  Local and State highway departments
  3.  Local water departments
  4.  State well permit records
  5.  State and Local transportation departments
  6.  State and Federal Environmental Agencies
  7.  State and Federal Mining Agencies
  8.  Army Corps  of Engineers
  9.  Local consulting, construction and mining
        companies
 10.  Geologists, hydroleogists, and engineers at
        local universities
 11.  Historical records
 12.  Interviews
Notes:  U.S.G.S. - United States Geological Survey
        U.S.S.C.S. - United States Soil Conservation
                      Service
Reference:  Guertin and McTigue 1982c.
                                      4-8

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     Through  the examination  and  analysis  of  this  information specific  data
gaps can be identified  and  programs of  further  exploration  can be  planned  and
implemented to broaden  or add to  existing  knowledge  of site conditions.

     There are three major  issues  involved in slurry wall design and
construction  that  require an  accurate and  detailed hydrogeologic assessment.
They include  (l) the type of  excavation equipment  to be used (2) the  depth to
which  the trench and subsequent wall will  extend,  and  (3) the extent  to which
soils  found onsite can  be used in  the backfill.  These three issues must be
continuously  considered throughout the  subsurface  investigation in order to
develop an appropriate  and  adequate slurry wall design for  a particular
situation.  The design  of a slurry wall project should progress in stages  as
investigations proceed  and  more detailed subsurface  information is gathered
and analyzed  (Guertin and McTigue  1982c) ,

     The following sections discuss the geologic,  hydrologic and soil data
necessary for the  proper design and construction of  a  slurry wall.
     4.2.1  Geology
     The types of geologic  information needed  to  properly design and  construct
a slurry wall include:  rock depth, rock  locations,  location  of  structural
discontinuities and  the degree  to which weathering  in  each rock  type  has
occurred.

     The existing rock types and the nature  of the  weathered  zone will  often
determine the type of equipment used during  excavation of the trench  (Goldberg
1979).  The depth to which  a trench must  be  excavated  will also  play  a  major
role in determining  the type of equipment necessary  at a  particular site.   The
types of excavation  equipment used during slurry  trench excavation are
described in Section 5.

     The existence of an impervious geologic formation at a particular  site
into which a slurry wall can be keyed is  the geologic  characteristic  that most
strongly influences  the vertical extent of a slurry  wall.   The depth  to such
an aquiclude frequently determines the excavation depth of the trench.  Trench
excavation for a keyed-in wall must extend into the  aquiclude at all  points
along the trench length in  order to avoid seepage zones that  can easily breach
the cutoff (Namy 1980).  The elevation of the  aquiclude1s surface, however,  is
not necessarily constant.   For this reason, the contour of the aquicludes
surface must be carefully mapped.

     The distance that the  cut-off wall must penetrate into the  aquiclude is
determined by the composition and geochemistry of the  impervious layer.  If
the aquiclude is a competent impervious bedrock, a minor  penetration may be
satisfactory.  In contrast, an excavation that is carried  into a clay
formation may employ deeper penetration into the aquiclude as  a  safety  factor
(Millet and Perez 1981).   It should be noted that although the presence of  an
aquiclude is an important consideration in the design  of  a slurry wall, there
are cases in which it is unnecessary to key into an  impervious layer, such  as
                                     4-9

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a scenario involving floating organic wastes, e.g., coal tar residuals.  In
this case it is only necessary to extend the wall to some specified depth
below the base of the waste column.

     Structural discontinuities and anomalous subsurface conditions that might
interfere with either the wall continuity as it is being excavated or the
tie-in with the aquiclude should be identified and methods for dealing with
the discontinuities should be developed prior to excavation activities.  Even
if there is an acute awareness of potential problems, complications can arise
and possible solutions for closures of pervious areas (called windows) in the
wall should be evaluated.

     The site-specific data needed to evaluate an area  for the purposes of
design and construction are seldom available solely from published sources.
Thus the determination of'the character and condition of the existing rock
must be made through site investigative techniques, such as:

     •  Test borings
     •  Test pit excavations

     •  Rock coring
     •  Geophysical surveys
     •  Laboratory analyses.

Detailed descriptions of  these techniques and the  types of data  that can be
collected through their use can be found in ASCE (1976) and Ash  et al  (1974).
     4.2.2  Hydrology
     In addition  to understanding  the  areal  geology,  an  understanding  of the
groundwater system and  its  interactions with surface  water  is  necessary  prior
to designing a  slurry wall  system  for  installation  at a  site.   A detailed
description of  the groundwater  regime  is needed  to  more  clearly define
pollutant migration at  a  site.  Only with  a  thorough  understanding  of
potential plume configurations  can the optimum slurry wall  system be selected
and  implemented.  Evaluations must  also be  made to determine the necessity for
site dewatering during  construction and if so, what the  effects might  be to
surrounding land  and structures.   The  types  of hydrologic  information  that are
typically required to design and construct an effective  slurry wall are:

     •  Determination of  boundary  conditions, e.g., hydraulic  head  distribu-
        tions,  recharge and discharge  zones, locations and  types of boundaries

     •  Determination of  material  constants, e.g.,  hydraulic conductivity,
        porosity, transmissivity,  area extent and thickness of geologic  units,
        location  of geologic units (accomplished during  geologic investiga-
        tion)
                                      4-10

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      •   Analysis  of  ground  and  surface  water  quality,  e.g.,  background water
         quality,  waste  constituent  concentrations,  boundary  conditions of
         wastes.

 As  with  the  initial  stages  of a geological  investigation,  preliminary data
 needed  for determining  the  hydraulic  system at  a site  can  be obtained from
 numerous published and  unpublished  sources  (see Table  4-2).   Those sources
 most  applicable to the  hydrologic  investigation are:

      •   Federal and  state Geologic  Surveys  (USGS)

      •   Soil  Conservation Service  (SCS)

      •   Environmental Protection Agency (EPA)

      •   Local Water  Control Boards  (i.e., state and county)
      •   Drillers  logs

      •   Operators plans  and permits.


 These data could  include reports on the  local geology,  surface  and groundwater
 quantity and  quality, hydraulic  properties  of materials, and location of
 groundwater users.   Based on the amount  and quality of information obtained
 from  these sources,  it may  be necessary  to  perform  an  additional  on-site data
 collection program.  This program could  be  very simple, where existing local
 wells are sampled for water quality and  yield.   An  on-site data collection
 program  may also be  very complex, if  new wells  are  drilled,  geologic  materials
 are sampled,  pump tests are performed,  and  water quality and quantity samples
 are taken and analyzed.  The level  of effort spent  in  field  collection
 programs  should be adequate to  fill the  needed  knowledge gaps so  that a
 working  slurry wall  can be  designed at  a minimum cost.

      Discussions of  the various  methods  and testing techniques  available for
 the accurate definition of  the groundwater  regime at a  site  can be found in
 numerous references, however, a  recommended source  of  information is  Guertin
 and McTigue (1982c).

      In  addition to  the investigation of the movement  and  distribution of
 existing groundwater, it is  equally important to study  groundwater quality.
Water quality has important  influences on selection of  the bentonite  slurry
 and backfill, on the selected equipment  and on  the  environmental  concerns
relative to disposal of uncontarainated groundwater  from extraction wells
 (Guertin and McTigue 1982c).  Depending  upon the suspected or known waste
types at a site, laboratory  analyses  of  groundwater and/or surface water
samples, will involve tests  for  different chemical  constituents.   The  testing
conducted relies entirely on site specific conditions.  These issues  are
discussed in Section 4.3.
                                     4-11

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     Using the data obtained for a site, numerous hydrogeologic and slurry
wall design specifications can be produced.  These could include the
development of:

     •  Potentiometric surface maps and flow nets for the hydrologic  system

     •  Geologic cross-sections with water table levels

     •  Depth and extent required for slurry wall

     •  Type of slurry wall that can be constructed based on contaminant
        compatibility and intended use.

     For each site where a pollution migration cut off wall is  to  be  con-
structed, a detailed hydrologic analysis must be performed to ensure  success.
Failure to perform this analysis could result in walls which allow contami-
nants to migrate past them (i.e., either under or around), walls that
deteriorate because of contaminat interaction or walls that are over  designed
causing increased -costs.


     4.2.3  Soils and Overburden


     Examination of the soil conditions existing at  a  site is another
important part of the subsurface investigation.  Soil  information, in addition
to being required for excavation and construction planning purposes,  is needed
primarily for the backfill design.  The design of the backfill  is  probably the
most important factor in the design of a slurry wall  system  (Case  1982).   The
backfill composition that is selected  for  a particular slurry wall site will
consist of a designated percentage of  small sized particles  called fines.   The
desired particle size distribution of  the  backfill  is  determined during the
design stages of the wall (Case 1982).  It is,  therefore, necessary to
evaluate the presence of fines  in the  area of excavation.  If  sufficient fines
are not available on-site, then a borrow source must  be  identified and plans
for transportation of the material to  the  site  should  be incorporated into the
construction contract.  Additional soil parameters  that  should  be  measured
during a site  soil survey for  the purpose  of designing the backfill material
are the  following:

     •   Soil water content

     •  Permeability
     •  Horizontal and vertical distribution

     •   Chemical properties  (e.g. organic  content)

     •  Gradation  (discussed  above as  percent  of  fines).

If  suitable  soils  are not available  nearby,  a  decision may  be made to use
alternative  backfill.
                                      4-12

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      Though maps and aerial photographs of an area may provide useful  soil
 information, a slurry wall construction project should have on-site subsurface
 soil explorations conducted to obtain the necessary detailed information on
 soil types.  This information is typically obtained through the use of the
 same investigative measures used to obtain hydrogeoiogic information.  These
 include soil borings, test pits, and geophysical investigative methods
 followed by laboratory analyses of the samples collected.  When properly
 correlated, the data obtained by utilizing these techniques, can be used to
 accurately define the type and extent of the soil strata underlying a  site
 area.  Two references are recommended as sources of information regarding soil
 investigative techniques.   They are McCarthy (1977), and Ash et al (1974).

      There are two points with respect to site investigation and character-
 ization that require reiteration.  The first point involves the measures used
 to examine site conditions.  It is important that the subsurface investiga-
 tions involve both direct and indirect methods of exploration,  particularly
 where conditions are suspected to be complex.  Neither of the two types of
 techniques are solely capable of providing all of the information required to
 adequately describe the subsurface environment of a site area.   Their use in
 conjunction with one another,  however, can provide the detail and level of
 certainty necessary to  properly characterize a site.

      The second point is directed towards slurry wall application and
 effectiveness in a particular  situation.   The more thoroughly a site is
 characterized by investigation,  i.e.,  the more detailed information available
 on surface and subsurface conditions,  the more effectively a slurry wall  may
 be designed and employed to control a  pollution problem.   Even  the most
 experienced professionals cannot  properly design and  construct  a slurry wall
 without  having a thorough understanding  of the situation at hand.


 4.3   Wastes and  Leachates
      The  presence  of  organic  or  inorganic  compounds in the groundwater can
have  a detrimental  effect  on  the bentonite slurry used during wall  construc-
tion  as well  as on  the  ability of the  finished wall to restrict  pollutant
migration.  These chemicals can  affect  the physical/chemical  properties  of the
bentonite and  the backfill material, leading  to failure of the wall either
during construction or  during its  operational  lifetime.   Thus, before  a  slurry
wall  is considered  as an appropriate remedial  action at  a site,  the effects  of
the leachate on the bentonite slurry and the  finished wall must  be  determined.
A compatability testing program  is necessary  to provide  the  information  needed
to properly select  the  type of bentonite and backfill  material that should be
used  in the slurry wall construction.

     The following sections outline the effect  that chemicals  have  on
bentonite and backfill material, and laboratory tests  that can be used to
establish the potential effectiveness of the slurry wall.
                                     4-13

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     4.3.1  Effects of Groundwater Contaminants on SB Walls


     Different chemicals can affect the physical/chemical properties of the
bentonite and backfill material, leading to:

     •  Flocculation of the slurry

     •  Reduction of the bentonite's swelling capacity

     •  Structural damage of the bentonite or backfill material.

     These changes can in turn lead to failure of the trench during excavation
and/or increase the permeability of the finished cut-off wall.  These
potential adverse effects on the performance of slurry walls are discussed
further in the following sections.


          4.3.1.1  Effects  of Groundwater Contamination on Bentonite Slurries


     Contaminated groundwater can  come in contact with the bentonite slurry^
during trench excavation or if  it  is used to hydrate the bentonite.  The major
problems  presented by  the contaminants is flocculation of  the  slurry and/or  a
reduction in  swelling  capacity  of  the bentonite, leading to  poor  filter cake
formation and potential collapse of the trench (Alther  [no date],^Xanthakos
1979).  This  is caused usually  by  the presence of high  concentrations  of
electrolytes, such as  sodium, calcium, and  heavy metals, in  the groundwater^
(Matrecon 1980, Alther [no  date]). These ions can  produce several  changes^in
the  betonite/water system  that  will lead to flocculation or  reduced hydration
of the bentonite.

     Monovalent  sodium ions on  the surface  of  the bentonite  can be  readily
exchanged with multivalent  ions,  such  as calcium  or other  metal ions,  con-
tained  in the leachate.   The replacing  multivalent  ions will have^a smaller
radius of hydration  than the sodium ion,  thus  reducing the dimension  of the
double  layer (see Section 2).   This  will  in turn  greatly reduce the swelling
capacity of the bentonite.   (Alther [no  date], D'Appolonia and Ryan,  1979).
Thus the bentonite will not fully hydrate,  and can  settle  out of suspension
 (Alther  [no date]).   Ions in solution can  also compete for available  water
with the clay surface, causing  a decrease  in the  thickness of the water shell
 around  the  clay  particle (Matrecon, 1980).   This  can also  impede the  full
 swelling potential of the bentonite (Metrecon 1980, Hughes 1975).

      These mechanisms will cause  a compression of the double layer of water
 molecules surrounding each clay particle.   This results in a decrease in the
 repulsive interactions between clay particles that can lead to an  increased
 potential for particle aggregation resulting  in flocculation of the bentonite
 suspension (Weber 1972).
                                      4-14

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     4.3.1.2  Effects of Groundwater Contaminants on  the Permeability of
              Cut-off Walls
     Recent  studies have  shown  the effects of  a variety  of  inorganic  and
organic compounds on SB slurry  walls  (D'Appolonia  and Ryan  1979, D'Appolonia
1980a).  As  Table 4-3  illustrates, slurry walls can withstand  the  attack  of a
number of chemicals commonly  found in leachates.   The soil  bentonite  mixtures
utilized in  these studies contained  from 30  to 40  percent  fines.   The results
of a large number of permeability tests utilizing  a wide range  of  pollutants
indicated that a well  graded  soil bentonite  mixture containing  more  than  30
percent fines and about 1 percent bentonite  will show only  a small increase in
permeability when leached with  many  common contaminants  (D'Appolonia  1980a).

     The commercial bra'nds of bentonite used in preparing the  slurry  or
backfill does not seem to have  a significant effect on the  ability of the
bentonite to withstand the effects of leachate or  permeability.  Table 4-4
illustrates  the effects of several different types of chemicals on the
permeability of four brands of  commercially  available bentonite hydrated  with
fresh water.  For the  brands  of bentonite tested,  there  was not a  significant
difference between their  ability to  withstand  the  effects of various  chemicals
(D'Appolonia 1980a).

     Increase in the permeability of  the finished  SB slurry wall can  be caused
by chemical  and physical  changes in  the structure  of the bentonite and
backfill material.  These changes, caused by the compounds  contained  in the
leachate, can affect the  swelling potential  of the bentonite as well  as alter
the structure of the bentonite  and backfill  material.

     Numerous organic  and inorganic  compounds  can, through  a variety  of
mechanisms,  cause bentonite clay particles to  shrink or  swell.  All of these
mechanisms affect the  quantity  of water contained  within the interspatial
layers of the clay structure.   Inorganic salts can, as discussed above, reduce
the double layer of partially bound water surrounding the hydrated bentonite,
thus reducing the effective size of  the clay particles.  (D'Appolonia and Ryan
1979).  Upon disassociation,  organic  bases can be  sorbed into  the  internal
surfaces of  clay particles thus affecting the  interlayer spacings  (Anderson
and Brown 1981).  Neutral-nonpolar and neutral-polar compounds  can replace the
water contained in the clay particle  interlayers,  thus affecting the  size of
the bentonite particle (Anderson and  Brown 1981).  This  can lead to increased
permeability of the finished  slurry wall, possibly resulting in breaching of
the wall.  For example, a decrease in  the amount that hydrated  bentonite  has
swelled increases the  amount of pore  space in.  the  backfill, thus increasing
the permeability of the wall.   In the worst  case,  a large reduction in the
effective particle size can result in  the physical erosion  of  the  soil/
bentonite matrix under the seepage pressure  (D'Appolonia and Ryan  1979).  This
can lead to  piping failure of the wall.  The probability of this type of
failure occurring can be reduced, if  the backfill material  contains at least
20 percent plastic fines (D'Appolonia  1980b).
                                     4-15

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                                  TABLE 4-3.
                     SOIL BENTONITE PERMEABILITY INCREASES
                    DUE TO LEACHING WITH VARIOUS POLLUTANTS

Pollutant
Ca or Mg++ @ 1000 PPM
Ca++ or Mg++ @ 10,000 PPM
NH,N03 @ 10,000 PPM
Acid (pH>l)
Strong Acid (pHll)
HCL (1%)
H2S04 (1%)
HCL (5%)
NaOH (1%)
CaOH (1%)
NaOH (5%)
Benzene
Phenol Solution
Sea Water
Brine (SG=1.2)
Acid Mine Drainage (FeSO,
pH~3)
Lignin (in Ca solution)
Organic residues from
pesticide manufacture
Alcohol
Backfill0
N
M
M
N
M/H*
N/M
M/H*
N
N
M/H*
M
M
M/H*
N
N
N/M
M
N
N
N
M/H
N - No significant effect; permeability increase by about a factor of 2 or
    less at steady state,
M - Moderate effect; permeability increase by factor of 2 to 5 at steady
    state.
H - Permeability increase by factor of 5 to 10.
* - Significant dissolution likely.
  - Silty or clayey sand, 30 to 40% fines.
Reference:  (1) D'Appolonia (I980a), (2) D'Appolonia and Ryan 1979.
                                      4-16

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                                 TABLE 4-4.

                 INCREASE IN THE PERMEABILITY OF FOUR BRANDS
           OF BENTONITE CAUSED BY LEACHING WITH VARIOUS POLLUTANTS
Final Permeability/Initial Permeability
Permeant Slurry National Premium Saline Seal
Ben 125 Brand 100
Lignin in
Ca++ solution 1.9 1.5 2.5
NaCl based salt
solution
(conductivity
170,000) 2.7 1.8 2.7
Ammonium nitrate
(10,000 ppm) 1.8 N/A 2.8
Acid mine drainage
(pH~3) N/A 1.5 1-3
Calcium and
magnesium salt
solution
(10,000 ppm) 2.9 3.2 3.2
Do we 11
Ml 79
1.4
N/A
N/A
N/A
N/A
N/A:  Data not available.

Reference:  D'Appolonia 1980a.
                                     4-17

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      Strong organic and inorganic acids and bases can dissolve or alter the
 bentonite or soil portion of the backfill material, leading to large permea-
 bility increases (D'Appolonia and Ryan, 1979, Alther [no date]).   Aluminum and
 silica,  two of the major components of bentonite, are readily dissolved by
 strong acids or bases,  respectively.  (Matrecon 1980).   Strong bases, though,
 usually produce a greater increase in permeability than acids due to the
 dissolution of silica (D'Appolonia and Ryan 1979).  Laboratory studies
 have shown that a well  graded soil-bentonite backfill containing  more than
 20 percent plastic fines and about 1 percent bentonite  shows only a small
 increase in permeability when exposed to a solution in  the pH range of
 2  to 11  (D'Appolonia and Ryan 1979).

      While a properly designed slurry wall can withstand the effects of many
 chemicals,  it  is essential  to know the long terra effects that the compounds
 found in the groundwater will have on the permeability  of the wall.  Thus it
 is^essential to test any pollutant with the actual backfill material that is
 going to be used.   (D'Appolonia and Ryan 1979).   The following sections
 address  testing methods  which can be used to determine  the impact of leachate
 on SB slurry walls.


      4.3.2   Compatibility Testing


      To  test the compatibility of compounds contained in the groundwater with
 Che material used  in the construction of slurry  walls,  a series of laboratory
 tests  should be  performed.   Since there  are,  as  yet,  no standard  tests  and
 testing  procedures established  for  determining the compatibility  of chemicals
 with  slurry walls; the types  of  tests  and their  associated testing procedures
 can vary^widely between  laboratories.   Through discussions with both private
 and public  laboratories  and  a  review of  the literature,  several quantitative
 testing methods were  identified  as  being applicable.  These include:

      •  Viscosity  test

      •  Filter-press  test

     •  Permeability  test

     •  Examination of Bentonite Mineralogy.

 In performing any of  these tests, representative  samples  of the leachate and
backfill material must be collected.  Procedures  for groundwater  and  soil
 sample collection can be found in several publications,  such as U.S   EPA
 (1981).
          4.3.2.1  Viscosity Test


     The^viscosity of the bentonite slurry can be an important  factor  in
determining the effect of the compounds contained in the groundwater on the
slurry.  Groundwater contaminants can change both the viscosity and gel
                                     4-18

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 strength of a bentonite slurry.  Thus by testing the changes  in slurry
 viscosity caused by the addition of leachate, the effects can be established
 and potential remedial responses can be sought.

      One device that is recommended by the American Petroleum Institute  (API)
 for testing slurry viscosity is the direct indicating viscometer, as
 illustrated in Figure 4-1.  By utilizing this device the plastic viscosity,
 yield point, and apparent viscosity can be easily determined.  The procedures
 for performing this test and the required calculations are outlined in API
 (1982).
           4.3.2.2  Filter-press Test
      The standard filter-press test that is commonly used to evaluate drilling
 mud has been utilized to indicate the effects of leachate on slurry and filter
 cake performance.  In the filter press test, bentonite slurry is introduced
 into a high pressure filter apparatus, as in Figure 4-2.  A pressure is
 applied to the filter apparatus, and the resulting filtrate is collected
 (Xanthakos 1979;  API 1982).   The quantity of filtrate should be within
 established limits.   By introducing a representative quantity of leachate into
 the bentonite slurry before the test is performed, the short-term effects on
 fluid loss can be established.  If there are any detrimental effects, the
 fluid loss will be outside the bounds of the established limits.  The
 procedures and apparatus needed in order to conduct this test are outlined in
 API (1982).
           4.3.2.3  Examination of Bentonite Mineralogy
      An  examination of the mineralogy of the bentonite backfill before and
 after it has  been exposed to  the leachate in the permeameter test could be
 used  to  determine short-term  chemical effects on the clay structure.   By
 utilizing standard laboratory tests,  such as X-ray diffraction the effects of
 the  leachate  on  the clay  structure  can be determined.   This can provide an
 indication of the long-term stability of the bentonite backfill.
          4.3.2.4  Perraeability
     The effect of  leachate on  the  permeability  of  a soil/bentonite  cut-off
wall can be ascertained by several  standard  soil  testing  procedures.   By
comparing the permeability of a soil/bentonite mixture  when  it  is  permeated
with leachate to that obtained when it is permeated  with  water,  a  deter-
mination can be made of the leachate1s potential  affect on the  permeability of
the SB cut-off wall.

     Laboratory procedures for performing permeability  tests can be  divided
into several general categories depending on how  the  level of liquid used  in
                                     4-19

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                        Figure 4-1.
                 Rotational Viscometer
      Scale
         \
Slurry Level
                        Pointer
Copyright 1979 by McGraw-Hill, Inc.
Used with permission.
Helical Torsion Spring



    Splash Guard
                                                              Rotor Sleeve
                                                              Cup
                                     Source: Xanthakos, 1979
                            4-20

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           Figure 4-2.

Filter-Press Test Apparatus
 ,
           Regulated Pressure Source
                 Gas Pressure
             i— Pressure Cell
                 Leach ate (or Slurry)


                 Filter Cake
                 Filter Paper


                 Porous Stone
                 Collection Cup
                 Filtrate
        Source: D'Appolonia & Ryan 1979
            4-21

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the apparatus is maintained during the course of the test, e.g., constant or
falling head permeability tests, and the type of apparatus used to contain the
soil/bentonite sample, e.g., fixed wall or triaxial permeameters.

     Any of the established permeability testing procedures can be utilized,
such as those outlined in OCE (1970).  While all permeability tests can
potentially be affected by a number of problems, the evaluation of the results
of a particular peraeameter test hinges not so much on the type of equipment
utilized but the test and quality control procedures followed during the
study.  Data currently available show that the use of fixed wall or triaxial
type devices does not affect the results of the permeability tests on slurry
trench cut off wall backfill materials (Ayres 1982).  Thus more attention
needs to be paid to the test procedures than the type of equipment used.


4.4  Summary


     Both the feasibility of a slurry wall for remediation at a particular
waste site, and the degree of success with which it is used, are dependent on
thorough investigation and characterization efforts.  These efforts define and
delineate those site-specific factors affecting wall design specifications,
ease of installation, and the overall performance of the  final cut-off.

     There are many physical factors that in some way would constrain the use
of a slurry wall at a given site.  Most of these factors would not preclude
the use of a slurry wall, but would require additional engineering and
construction measures to overcome.  Investigation and characterization of
physical site constraints would reveal and define the need for  such
pre-trenching activities as site grading, or rerouting of  fences, utilities  or
roads.  All of  these  factors could have an impact on construction costs  and  so
must be well characterized.

     A thorough  investigation and characterization  of the  sub-surface
conditions at a  site  is essential to  slurry wall feasibility, design  and
construction.   A detailed delineation of  a site's geology and hydrology  will
help define the  proposed slurry wall depth, and ease of  excavation, and
indicate potential construction problems.  Soils and overburden characteriza-
tions will also  reveal potential excavation and construction problems, but  are
most  important  for determining  the  suitability  of on-site materials  for  use as
backfill material  in  a SB wall.

     The importance of a complete characterization  of site wastes  and  leachate
should not be underestimated.   Several waste  types  have  been shown  to  be
destructive  to  both SB and  CB walls  and could  seriously  affect  their
integrity.  Permeability testing of  proposed backfill materials, with  actual
site  leachate is currently  the most  accurate method for  predicting  the
longevity  of  the wall.
                                      4-22

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     The site investigation and characterization efforts are essential  in
developing a wall design suited to controlling that site's contamination.
They also play a major role in identifying those factors that pose problems
for wall installation and developing methods for dealing with them.
                                     4-23

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                                   SECTION 5

                            DESIGN AND CONSTRUCTION
     This section addresses the design and construction procedures that are
used to install a soil bentonite or cement bentonite wall.  Each step, from
the pre-design stage to the clean up of the site is described.

     First, site specific factors that should be evaluated prior to slurry
wall design are discussed.  These factors affect the feasibility and
conceptual design of slurry wall use at a particular site, and the relative
applicability of the'two slurry wall types.

     Next, slurry wall design types and components are described.  This
description illustrates the various portions of a design package and the types
of data that typically are contained in each.

     Slurry wall construction requirements, including materials, quality
control, equipment, methods, and dimensional parameters are listed in the
third part of this section.

     Following this a brief discussion of preconstruction steps is given.  In
addition to evaluating the site and producing the design, the bid package must
be prepared and bids evaluated before the construction contract can be
awarded.

     Once the contract is awarded, wall construction can begin.  The
techniques used during construction of soil bentonite walls are described in
detail.  CB and diaphragm walls are also discussed.  The final portion of this
section addresses problems associated with slurry trench construction.
Typical solutions to these problems are also discussed.


5.1  Design Procedures and Considerations


     The process of designing a slurry wall requires assessment of site
specific data and consideration of numerous design variables, to determine the
feasibility of a slurry wall and to select the most appropriate wall type for
use at the site.  This section describes these processes.
                                     5-1

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     5.1.1  Feasibility Determination


     Using the data from the site investigations, the designer must determine
the feasibility and applicability of installing a slurry wall at the site.
Factors to consider include:

     •  Potential waste incompatibility

     •  Anticipated hydraulic gradients and maximum allowable permeability  in
        the completed wall

     *  Aquiclude characteristics - depth, permeability, continuity, and
        hardness

     •  Wall placement relative to wastes and leachates

     •  Costs and time considerations.
          5.1.1.1  Waste Compatibility


     Waste and leachate compatibility with proposed  slurry wall backfill
mixtures can be determined using the laboratory tests described in  Section 4.
Where long-term permeability is crucial, clay mineralogy  and geochemical
testing is advisable.  These tests provide an indication  of which proposed
backfill mixtures show the greatest resistance to  long  and short term
permeation by the pollutants at the site.


          5.1.1.2  Permeability and Hydraulic Gradient


     Data on the anticipated hydraulic pressures on  either side of  the  wall
indicate the range of hydraulic gradients to which the  wall may be  exposed.
When projected permeabilities and wall areas are known, the rate of subsurface
movement through the wall, can be determined using Darcy1s law.  Darcy's  law
states that

                                    q s kia

where q is the volume of water flowing through the wall,  k is  the coefficient
of permeability of the wall, i is the hydraulic gradient, and  a  is  the  cross-
sectional wall area  (Mitchell 1976).

     To illustrate how Darcy's law can be used to  estimate a  slurry wall's
effects on groundwater flow at a hypothetical site,  consider  the  following
hypothetical situation:  a proposed slurry wall is designed  to be  164  feet
(50 meters)  long, 82 feet (25 meters) deep,  and 3.2  feet  (1 meter)  thick.  The
hydraulic gradient at the site is estimated  at 2,  and  the wall's  permeability
is designed  to be less than 2.12 x 10~3 gpd/ft2 (1 x 10~7cm/sec).   According

                                     5-2

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to Darcy's law, the amount of water that will move through the wall is 57 gpd
(0.216 m /day.  Before the slurry wall was installed, the permeability of the
same area was about 2.12 gpd/ft2 (1 x 10~4 cm/sec), a low permeability for
undisturbed soils.  The amount of water flowing through3the area each day
prior to slurry wall installation was 57,000 gpd (216 m /day.  Thus, this
particular slurry wall would reduce the volume of water flow through this area
by 99.9 percent.  In areas having higher initial permeabilities, the effect of
the slurry wall would be even greater.


          5.1.1.3  Aquiclude Characteristics


     Another  factor to consider when  evaluating the  feasibility of a slurry
wall is the aquiclude at the site.  Ideally, it should  also be thick,
impermeable,  and  unfractured, and  should be  soft enough for a backhoe  or
clamshell to  excavate a 1- to 3-foot  key-in  to prevent  seepage under the
slurry wall.   In  areas where aquicludes are  very hard,  slurry walls will  be
more expensive  to install or the aquiclude wall union  less certain. Where  the
aquiclude is  thin, discontinuous,  or  fractured, slurry  walls can be expected
to be  less efficient  in pollution migration  control  due to seepage through  the
aquiclude and other remedial measures may be called  for.


          5.1.1.4 Wall Configuration and  Size


     An  early assessment  of  possible  wall  locations  and configurations can
indicate  the  overall  amount  of  wall exposure to wastes  and  leachates,  the
types  and placements  of auxiliary  measures  and  the actual length and  depth of
wall  required.  These factors,  along  with  an estimate of  the  necessary wall
durability,  can assist  designers  in  projecting  the cost of  the  construction
effort.   Detailed data  on wall  applications  and  configurations  are presented
in Section  3.


           5.1.1.5  Cost  and  Time  Factors


      The need for rapid  response  at  some  sites  necessitates an evaluation of
the  construction  time required.  According to Miller (1979)  soil bentonite
slurry walls are  normally installed at a rate of 25 to 100 linear  feet per
day.   Thus,  the wall  described previously could be installed in 2  to 7 days,
assuming the work is  accomplished in a nonhazardous environment.   Hazardous
conditions  can more than double on site work time.


      5.1.2   Selection of Slurry Wall Type


      If it  is determined that a slurry wall is feasible,  the type  of wall
 (SB or CB)  that  is required should be established.  To decide whether a


                                      5-3

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 soil-bentonite or  cement-bentonite  cut-off wall should be installed at a
 particular site,  several factors need to be considered.  The following factors
 affect  the suitability of SB or CB  walls:

      •   Required  permeability and hydraulic pressure

      •   Leachate  characteristics

      •   Availability of backfill material

      •   Required wall strength

      •   Aquiclude  depth

      •   Site  terrain
      •   Cose.


           5.1.2.1  Permeability and Hydraulic  Gradient


      Where low permeability  is required,  SB walls  are  used,  and  the wall width
 is determined  by  the  hydraulic head across the trench.   Case (1982) recommends
 that  the trench should  "have  a width  of  0.5 feet to  0.75 feet  per 10 feet of
 hydrostatic head on  the wall.   Thus,  for  a 100 foot  head loss, wall thickness
 should  range  from  5  to  7.5 feet."  In comparison,  a  CB wall  only 2 to 3  feet
 thick will  stand up  to  the same hydrostatic force  (i.e.,  100 feet).  Deeper
 walls are  generally wider then shallower  ones  because  larger excavation
 equipment  is used  for deep walls  and  this equipment  generally  digs a wider
 trench  (Millet  and Perez 1981).   Generally,  CB walls are designed to be
 narrower than  SB walls  due to  the greater shear strength and the higher  cost
 of cement  bentonite walls (Millet and Perez 1981,  Ryan 1976).


           5.1.2.2  Leachate Characteristics


      SB  walls exhibit a  lower  permeability and  a greater  resistance to
 chemical attack, particularly  to  acids, than CB walls.   For  this reason,  SB
 walls are  favored  for use as pollution migration cut-offs  (Jefferis 1981b and
 Xanthakos  1979).

     Where floating rather than  sinking contaminants are  encountered,  the
 slurry wall does not have to be extended  down  into the  aquiclude.   Instead,  a
 "hanging" wall  is installed.   These walls  are  usually  soil bentonite types.


          5.1.2.3  Availability of  Backfill Material


     In  some sites, the material  excavated  from the  trench is contaminated due
 to contact with polluted groundwater.   This contaminated  soil may be  unsuit-
 able for use in the backfill.  Samples of  this material  should be  mixed with
bentonite slurry and tested to determine  the effects of  the  contaminants  on


                                      5-4

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the SB wall permeability.  Testing of SB wall/leachate compatibility  is
discussed in Section 4.  In some cases, the contaminants will  increase the
permeability of the completed wall, but the increase may be  less  than the
increase that could be caused by the sudden exposure of the  wall  to the
polluted groundwater.  At these sites, it may be advisable to  use  the
contaminated material in the backfill, providing the gradation is  adequate
(D'Appolonia 1980b).  If, however, the contaminated soil is  discovered to be
inappropriate for use as backfill material, a suitable borrow  area should be
found.  Where no such borrow area is available nearby, CB walls may be more
appropriate.
          5.1.2.4  Wall Strength
     Generally, CB walls are used where heavy vertical  loadings  are
anticipated and large lateral earth movements are not expected.  This  is
because CB walls have a higher shear  strength and lower  compressibility than
SB walls.  CB walls are, however, more likely to crack  than relatively plastic
SB walls (Millet and Perez 1981).  If the wall must be  extended  beneath roads,
rail tracks or in close proximity to  existing foundations, CB walls  can be
used.  In addition, CB walls can be used in  localized areas requiring
strength and tied into SB walls for the rest of the trench distance.


          5.1.2.5  Aquiclude Depth


     CB walls are more expensive than SB walls due to the cost of  the  cement.
For this reason, CB walls are not generally  used where  the aquiclude is deep,
or where very long cut-off walls are  required (Ryan 1977).
          5.1.2.6  Site Terrain
      At sites where slopes are steep and the areas  for backfill mixing  are
limited or non-existent, and low permeability is not critical, CB walls  may be
preferred.  In general, SB walls are limited to areas where  the maximum  slope
along the trench line is on the order of 2 percent or less.  At many  sites,
hills can be leveled and depressions backfilled with compacted soil prior  to
trench construction.  The lack of sufficient backfill mixing areas can be
overcome by hauling trench spoils to a central backfill mixing area,  then
hauling mixed backfill back to the trench.  Pug mills can also be used for
backfill mixing.  These operations — site leveling use of pug mills  and
central backfill mixing — result in slower construction rates and higher
costs.

     In contrast to SB walls, CB walls can be constructed in areas of steeper
terrain by utilizing the CB panel construction technique described later in
this section.
                                     5-5

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          5.1.2.7  Cost
     As mentioned earlier, a CB wall is typically more expensive than a SB
wall of the same volume due to the cost of the cement.  Where thick or deep
walls are planned, CB walls will, in most cases, be more expensive than SB
walls.  Where wall thickness can be minimized and very low permeability is not
essential, CB walls be can considered.

     After the type of slurry wall has been selected, the preparation of the
design can begin.


5.2  Specification Types and Design Components


     The objective of the design phase is to produce accurate specifications
for wall construction.  Normally, the design of a slurry wall for pollution
migration control involves producing either a performance type specification
or a materials and methods specification.
     5.2.1  Differences in Specification Types


     Performance specifications consist of the performance  standards which
spell out what the owner or engineer expects to receive  in  exchange  for
payment.  These specifications stipulate the results desired by  the  owner and
leave the achievement of the results the responsibility  of  the contractor.
This type of specification provides the widest latitude  to  the contractor but
still maintains the quality desired for the end product.  Historically,
performance specifications allow innovation on the  part  of  the contractor to
achieve results at reasonable costs.

     The most commonly used measure of slurry wall  performance is  the
permeability of the completed cut-off.  Often, the  maximum  permeability  is
specified at 10~  cm/sec (Lager 1982).  Materials requirements are also
specified.  Most design engineers and bentonite producers use performance type
specifications.

     The materials and methods type of specifications, which are normally used
for major construction projects are typically very  long  because  requirements
for both materials and methods are  spelled out in great  detail.   Although this
type of specification is applicable for slurry trench  installations,  the
general consensus of design and construction firms  with  much slurry trenching
experience is that construction costs are typically increased without
improving the quality of the installation if materials and  methods types of
specifications are used.

      In some situations, this specification type may  be favored over
performance specifications.  For example, where there  are not qualified
bidders for a project or where special structural considerations are involved,


                                     5-6

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a materials and methods type specification may be necessary.  For this reason,
components of both design and performance specifications are described below.


     5.2.2  Components of Design


     In slurry wall designs, the following items are typically addressed:

     •  Scope of work

     •  Construction qualifications

     •  Construction requirements of the trench and slurry wall

     •  Materials

     •  Equipment and facilities

     •  Performance

     •  Clean up

     •  Quality Control and Documentation

     •  Measurement and Payment.

Each of these items are briefly described below.


          5.2.2.1  Scope of Work


     This section describes in general terms what the contractors will be
required to accomplish including material quantities and performance period.


          5.2.2.2  Construction Qualifications


     This should describe the prior experience required of the contractor and
his personnel on site.  This could be expressed in terms of a specific number
of similar jobs, in years of experience in slurry trench construction, or
both.  This requirement is not always stipulated.


          5.2.2.3  Construction Requirements of the Trench and Wall


     Among the items included in this section are the width and depth of the
trench, the aquiclude to be penetrated, and the depth of penetration, the
location, continuity, verticality, and permeability of the completed wall.
The two most important design considerations, which are the selection of the
aquiclude and the design of the backfill, must also be described (D'Appolonia
1980a).
                                     5-7

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          5.2,2.4  Materials


     This section should specify the material standards to be maintained
during construction.  It usually covers water quality, bentonite type, slurry
quality, backfill characteristics, and additives, if any.  Each of these
materials should be separately addressed to ensure compliance with design
requirements for the particular site.


          5.2.2.5  Equipment


     This section should be used to ensure that the contractor has the proper
equipment on site to perform the following:

     •  Trench Excavation

     •  Slurry Mixing
     •  Slurry Placement
     •  Backfill Mixing

     •  Backfill Placement

     •  Site Clean-up.


          5.2.2.6  Methods


     This section describes the acceptable methods of slurry mixing,  trench
wall stabilization, trench excavation, backfill mixing, backfill placement and
clay cap construction.  The design engineer must ensure that the slurry  is
properly hydrated prior to use, that the slurry is pumped into the trench at
the start of excavation, and that sufficient slurry is kept in the trench to
maintain trench wall stability.

     The trench for an SB or CB wall must be excavated so that it is
continuous to the required depth along the specified line of excavation.
Unexcavated areas within the trench are prohibited, as these interfere with
wall integrity.  To ensure continuity in CB panel walls, sufficient overlap
between adjacent panels must be required (Geo-Con, Inc. 1979).

     The consistency of SB backfill material (as measured by slump) must be
specified in order  to maintain the desired flow properties during backfill
placement.  The required backfill properties are described in Section 5.3.2.5.
The method of backfill placement should also be addressed in order to avoid
entrapping pockets  of slurry or pervious materials during backfilling that
interfere with wall performance.  After completion of  the trench backfilling
process, the trench must be protected from desiccation by means of a  clay cap.
Techniques for construction of this cap must be described, particularly  if  the
cap is designed to  withstand traffic loads.
                                      5-8

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section
should also  include  the
                                               * °in tne excavation,
                                                --•
          .2.2.7  Quality Control and Documentation
    The contractor  should be "quir-d to p.rfo»
Wtion and in some i""nce. c.rtxfic.^ on dur, ng   ^ materials used  In

^r.^ ~/S£^ ^•"-•"•h QA/QC procedure8  x   P
the slurry wall contractor.
         5.2.2.8  Drawings
                                                        to estimate the
      .  Any earth-.ovins retired be.ore actual trench con.truction can

      .  A P,an vie» o«  slurry trench with areas .or slurry preparation and

        equipment

      .  A cross  section of the trench to  show depth and location o* any

        utility  or road crossings

      .  Soil boring, locations, and depths.
                                       nay
                                           also be delineated
       The cross
                section of  the trench
                                                 .                   .
                                                 iping- wastewater plping>
   are shown

   given area
                                    5-9

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           5.2.2.9  Measurement and Payment

5.3  Slurry Wall Requirement
  usxng slurry trench nethod          f

  hazardous waste applications will be  to
  water flow to a specific degree"^  ?

       The design factors affectino
  completed CB and SB walls are:

       •   Wall  location

       •   Wall  depth

       •   Wall width

       •   Wall continuity and vertically

       •   Connection to surface structure
      •  Material quality

      •  Methods  and procedures used.
                                                       a logical flow of
                                               "xteri. for cut-off walls
                                              ive..   The objective in most
                                                                      ground
                                      ft=
                                     effectiveness and durability of
 the
 such as
      permeability, continuity
   5.3.1   Location
                                                      ^8th and grade of
the
              s.  Factors affect
locates and hydrogeologic conditfons
                                    a
                                                         and grades  shown

                                                                 '°
                                  5-10

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      5.3.2  Depth


      Slurry wall depth  is  controlled by the depth to the aquiclude.  The
 selection of the aquiclude  is  one  of the  most  important  items in the slurry
 wall design.  Although  several relatively impervious zones may be encountered,
 the aquiclude used as a cut-off wall foundation  should be continuous,
 relatively free of fractures  and other  pervious  zones,  and within the reach of
 currently available excavation equipment.   Selection of  a suitable aquiclude
 is based on the data obtained  during site  investigations, as described in
 Section 4.  Usually the cut-off wall  is extended 2  to 3  feet into the
 aquiclude past the zone of  "pervious  lenses, weathered  zones, desiccation
 cracks or other geological  features  that might permit seepage under the
 cut-off" (D'Appolonia 1980a).   If  the acquiclude to be penetrated is of
 questionable integrity in the  excavation  area, the  base  of the cut-off can be
 grouted to seal pervious zones beneath  the  wall  (D'Appolonia [unpublished]).
 In the case of a hanging slurry wall, the depth  of  the seasonally lowest  water
 table determines wall depth.


      5.3.3  Width and Permeability


      In addition to wall location and depth, the  wall width  and  permeability
 are stipulated  in materials and methods specifications.

      Design width depends on several factors, including:

      •   The  required  cut-off effectiveness

      •   Head  loss  across the wall

      •   The hydraulic  gradient

      •   The  s.ize  of the  available excavating equipment.

      The  permeability  of the completed cut-off is usually  stated  in
 performance  specifications.   For adequate pollution  control,  ie  is necessary
 to  maintain a wall  permeability of  1 x 1CT7  cm/sec or less (D'Appolonia
 1980a).   This permeability  is  achievable using SB walls with high  fines
 contents.  Cement bentonite  walls usually  have  higher permeabilities; on the
 order of  1 x 10~6 cm/sec (Jefferis  1981b).

     The  relationship between  required wall  thickness and hydraulic gradient
 is  given  in Section 5.1.2.6.   Data  on equipment  sizes and excavation depths
 are presented in Section 5.3.7.


     5.3.4  Continuity and Verticality


     The continuity and  verticality  of the  completed wall can significantly
affect wall performance and must be  carefully specified.   Soil bentonite or CB


                                      5-11

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trench walls are excavated in a continuous trench, and continuity is tested by
passing the backhoe bucket or clamshell vertically and horizontally along each
segment before it is backfilled.  When a circumferential slurry wall is
constructed, a segment of the earliest-backfilled trench is reexcavated to
ensure complete continuity.

     In CB panel walls, each panel is excavated under a CB slurry then allowed
to set before excavation of the intervening panels is begun.  The overlap at
each panel joint is dependent on wall depth and the type of equipment used.  A
minimum of 3 feet of each end of each partially set CB panel is excavated when
the intervening panel is excavated.  The intervening panel is allowed to
harden and that particular wall segment is then complete (Geo-Con, Inc. 1979).

     Soil bentonite walls are usually not required to be strictly vertical, as
these walls are seldom,"if ever, used in a load-bearing capacity as part of a
structure.  Verticality can affect wall continuity, particularly at corners.
If one wall is vertical but the other slants outward at the base, a large
unexcavated area may exist in the corners.  For this reason, some specifica-
tions call for nearly vertical walls, or a 5-foot overlap at wall corners
(U.S. Army Corps of Engineers 1975).  Good field quality control will insure a
nearly vertical wall and good continuity.


     5.3.5  Surface Protection


     Another requirement of completed soil bentonite walls that  they be
protected from consolidation and compaction as well as from erosion.  The
completed wall must not be allowed to consolidate unevenly and thus form deep
cracks, or to consolidate enough to  form a seepage path or a depression at  the
ground surface that follows the original trench excavation (Millet  and Perez
1981).  Consolidation is a function  of backfill gradation and water content,
and the ratio of trench width to depth.  In most cases, it can be predicted in
advance and so not cause unforeseen  problems.  Wider walls have  been  found  to
consolidate more than narrow ones, and excessive  fines content  is said  to
result in a greater degree of consolidation.   In trenches wider  than 8  feet,
having a depth from 50  to 90 feet, consolidation was reported  to average  1  to
6  inches (Xanthakos 1979).  One 3-foot wide wall backfilled with material
containing an average of about 60 percent  fines consolidated  about  6-8  inches
over the course of about 6 months. The surface of the  SB wall was dry  and
cracks less than 1 inch wide and a few inches  deep were evident  prior  to
placement of a clay cap (Coneybear 1982).

     To protect the surface of  finished SB walls, clay caps  are  often
installed (Millet and Perez 1981).   These  can  be designed to  support  traffic
by interspersing geotextiles (construction fabric) between  a  series of clay
lifts  and by covering  the  surface with gravel  (Zoratto 1982),    As
consolidation occurs during the  first  few  months  after trench construction,
additional clay layers may be added  (U.S.  Army Corps of Engineers  1975).
                                      5-12

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     5.3.6  Materials, Quality Control, and Documentation Requirements


     The types of materials that are acceptable during slurry trench
construction are often specified in great detail.  Quality requirements for
the following items are commonly listed:

     •  Dry bentonite
     •  Water
     •  Fresh slurry
     •  In-trench slurry
     •  Backfill materials
     •  Mixed backfill.

     Table  5-1  presents a materials  quality  control  program  for  soil  bentonite
walls.  The  types,  frequencies  and results of  the  tests  are  specified.
Additional  requirements are described  below.
           5.3.6.1   Dry  Bentonite
      The  quality of the  dry bentonite should
 by checking  the pH, viscosity and  fluid  loss
 bentonite.   Certification of compliance  with
 the bentonite manufacturer must  be obtained.
 include physical and chemical purity and dry
 number 200 mesh sieve).
be tested frequently, for example
of a slurry made from the
the material specification from
 Other criteria for dry bentonite
fineness (percent passing a
      Another bentonite quality criteria is the type of additives allowed.^
 Additives are reportedly present in most,  if not all, commercial "natural"
 sodium bentonite sold in the U.S.  (D'Appolonia and Ryan 1979).  Among the
 types of additives used in bentonite are peptizers, bulking agents, softening
 agents, dispersatits,  retarders and plugging or bridging agents (Corps of
 Engineers 1975; IMC., [no date]).   Some of these are listed in Table 2-3.
 Although some specifications categorically prohibit the use of additives,
 others require the engineer's prior approval and manufacturer's certification
 of compliance with stated characteristics before the additives can be used
 (U.S. Army Corps of Engineers 1976; Geo-Con Inc. 1979).  Specifications
 requiring approval of additives usually refer to additives other than those
 allowed in "natural" bentonites.
           5.3.6.2  Clay


      At some sites, the use of native clay materials has been attempted.
 There are several drawbacks to the use of other clays in the slurry during
 trench construction.  The primary ones are the difficulty  in meeting  slurry
                                      5-13

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                                                                  TABLE 5-1.
                                            MATERIALS QUALITY CONTROL  PROGRAM  FOR SB WALLS
  Quality
Control Item
                .Subject
                               Standard  Name
                                                     Type of Test
                                                                               Frequency
                                                                                                        Specified  Values
                 Water
Materials
 I
1—'
-p-
                 Additives
                 Bentonite
                              API  Std 13
                              Standard Procedure
                              for  Testing
                              Drilling Fluids
                                                     -pH
                                                     -Total Hardness
                                                     Manufacturer certificate
                                                     of compliance with  stated
                                                     characteristics
                                                    Manufacturer certificate
                                                    of compliance
                                                     Selected soils  obtained
                                                                               Per water
                                                                               source  or-as
                                                                               changes occur
As required to properly
hydrate bentonite  with
approved additives.
Determined by slurry  viscosity
and gel strength teats.

As approved by Engineer
Premium grade sodium  cation
montmorillonite
Slurry






Backfill
Mix
Backfill - from a borrow area approved
Soils by the Engineer
Roll to 1/8" thread
Prepared API Std 13 - Unit Weight
for Place- Standard Procedure - Viscosity 1 set per shift or
ment into for Testing per batch (pond)
the Trench Drilling Fluids - Filtrate Loss
- PH
In Trench API Std 13B1 - Unit Weight
Standard Procedure
for Testing
Drilling Fluids - Slump

- Gradation
At Trench ASTM C 143
Slump Cone Test

1 set per shift at
point of trenching

1 set per 200 cu
yds


35 to 853! passing #20 Sieve
15 to 35Z passing #200 Sieve
Unit Weight 1.03 gm/cc
V 15 centipose of
_ 40 sec-Marsh 9 68"
Loss 15 cc to 25 cc in 30 min
@ 100 psi
pH 8
unit~~weight - 1.03 - 1.36 gm/cc


Slump 2 to 6 inches

65 to 100% passing 2/8" Sieve
35 to 85% passing #20 Sieve
15 to 35% passing #200 Sieve
Reference:   Federal Bentonite 1981.

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specifications and controlling slurry quality (Boyes 1975).  As Table 5-2
shows, a 6 percent solution of commercial montmorillonite gives a viscosity of
15 centipoise (cP).  To obtain an equivalent slurry using typical native
clays, a solution containing about 25 to 36 percent clay would be necessary
unless they are very high in montmorillonite (Grim and Guven 1978).  At this
clay content, the slurry would be denser than is desirable  for trenching
slurries:  dense slurries are detrimental because thay may  not be displaced
properly by the backfill.

     Like montmorillonite, native clays are composed of very small particles
that will pass through a 200 mesh sieve.  Most native clays are found mixed
with larger-sized particles such as silt, sand, and gravel.  These larger
particles are difficult to separate from the clay.  The amount of clay in  the
native deposits normally will vary both horizontally and vertically.  Because
of this variation, it will be difficult to control the clay concentration  in
slurries made from native clays.  A third problem with non-montmorillonitic
native clays is that they are much less thixotropic than montmorillonite.
They may take days to develop a gel structure rather than minutes (Boyes
1975).  For these reasons, typical clays do not perform as well or as
consistently in slurries as montmorillonite; therefore, the use of
non-montmorillonitic clays is not recommended for most applications.
          5.3,6.3  Water


     Water quality must be tested  for each water  source  used.  Tests  include
pH, total hardness and content of  suspected deleterious  substances  (U.S. Army
Corps of Engineers 1976).  Reported water quality requirements include:

     •  Hardness of < 50 ppm

     •  Total dissolved solids content of < 500 ppm

     •  Organics content of < 50 ppm

     •  Other deleterious substances (i.e., oil or leachate) < 50 ppm

     •  pH of about 7.0 (Xanthakos 1979, U.S. Array Corps of Engineers 1975).


          5.3.6.4  Fresh Slurry


     The fresh hydrated bentonite  slurry should have a minimum viscosity of
40 seconds Marsh, a unit weight of about 65 p.c.f.) a pH of from 7  to 10,  a
bentonite content of from 4 to 8 percent (Case 1982, Xanthakos 1979,  Boyes
1975 and Alther 1982).  The factors affecting bentonite  and slurry  quality are
discussed in Section 2.  Common slurry properties and the  tests used  to
measure them are presented in Table 5-3.

     One test that is often conducted on fresh slurries  is the filtrate (or
fluid) loss test (API 1982).  This test is supposed to simulate formation  of
the filter cake (Millet and Perez  1981).  The filtrate test involves  measuring


                                     5-15

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                                                   TABLE 5-2.
                                   COMPARISON OF SELECTED PROPERTIES OF CLAYS
Parameter
Montmorillonite
Kaolinite
Illite
Other Clays or
Sheet Silicates
Amount of water the     200-300% (1)
  dry clay can absorb,
  % of dry weight (1)
Volume change
  due to hydration
  under similar
  conditions

Hydration rate
Particle shape
Theoretical
  Specific surface
  area, m /g

Cation Exchange
  Capacity,
  meq/lOOg

Liquid Limit (%)

Plastic Limit (%)
2-11 cufVg (2)
Water sorption
  continues for
  about 1 week (2)

thin, flat, irregular
  plates (3)
700-800 (2)



60-150 (3)



150-700 (4,5)

65-97 (4)
irregular, flat
  six-sided
  shapes (2)
5-20 (2)



3-15 (2)



29-75 (4)

26-35 (4)
100-200 (2)



10-40 (2)



59-90 (4)

34-43 (4)
                                                            100%
                                  vermiculite >montraorillonite
                                    >beidellite >kaolinite
                                    >halloysite (2)
water sorption for
  most colloidal clays is
  complete in 1 to 3 days (2)

attapulgite-fibrous,
  sepiolite-fibrous,
  most others irregular
  and flat (3)

vermiculite 300-500 (3)
vermiculite 100-150 (2)
  attapulgite/sepiolite
  3-15 (3)

  attapulgite 160-230 (6)

  attapulgite 100-120 (6)

         (continued)

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                                             TABLE 5-2.  (continued)
Parameter
Montmorillonite
                                                 Kaolinite
                  Illite
                Other Clays or
                Sheet Silicates
Shrinkage Limit (%)

Percentage of clay
  by weight in
  water to produce
  a 15 cP colloidal
  suspension

Density of charge
  meq/ra  x 10   (2)

Layer thickness
  in A (6)
Particle density,
  g/cin  (2)
 8.5-15  (6)

^5.5-12  (4)
25-29 (6)
 1.1-1.9                    6-7.5
expansive >10               7.15
   air dry 15
 2.5 Wyoming bentonite  (5)
  2.2  Japanese bentonite (5)
15-17 (6)
                  1,0-2.0
                  10
                                   ~25-36 for typical
                                   native clays  (4)
                                   attapulgite-same  as
                                   montimorillonite  (4)
                vermiculite  3,0-3.3
                vermiculite  14
                muscovite  10
                biotite 10
                halloysite 10

                mica  2.8-3.2 (2)
References:  (1) Case 1982,  (2) Baver, Gardner and Gardner 1972,  (3)  Grim 1968,  (4)  Grim  and  Guven  1978,
             (5) Xanthakos 1979, (6)  Mitchell 1976.

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                                   TABLE 5-3.
                  COMMON SLURRY PROPERTIES AND TESTING METHODS
    Property
                        Definition
                                         Current  test method
Concentration
        Ib  bentonite/100  Ib water
        kg  bentonite/100  kg water
        Ib  bentonite/ft   water
Density
       Mass  of  given volume  of
       slurry
                                                  Mud Balance
Plastic viscosity
 apparent
 viscosity,
 yield stress
                    For a slurry behaving as a
                     Bingham body, the flow
                     law is
                                     Fann V-G viscometer
                          T  - yT
                                     N  D
                                 0
                    where T  = shear stress
                          T  = yield stress
                          .0
                          Np = plastic viscosity
                          D  = rate of shear
                          TD = apparent viscosity
Marsh cone
 gelation
        Time  for  946  cm  (1  U.S.
         quart) or  1500-cm
         volume to  drain
         from a standard  cone or
         time for 500 cm   of the
         500-cm   volume to drain
         from cone  (Japan)
                                                  Marsh funnel viscometer
Initial gel
 strength
        Minimum shear stress  to
         produce flow;  designated
         as T,,
                                                  Rotational viscometer
10-min
 gel strengh
        Shear strength obtained
         by allowing 10 min to
         elapse between stirring
         and reading
                                                  Rotational viscometer
pH
        Logarithm of reciprocal of
         hydrogen-ion concentration
                                                  pH electrometer; pH
                                                  papers usually not reliable
Filtration or
 fluid loss
        Volume of fluid los t in
         given time from fixed
         volume of slurry when
         filtered at given pres-
         sure through standard
         filter
                                                  Filter-press test (but this
                                                   procedure does not permit
                                                   exact estimation);
                                                   stagnation-gradient test
                                                   more appropriate
Filter cake
        Thickness and strength of
         filter cake for standard
         or actual conditions
                                                  Thickness measured  in  fluid-
                                                    loss test,  strength esti-
                                                    mated  from  triaxial tests
Sand content
        Percentage of sand greater
        than 200—mesh in suspension
                                                  API standard  sand-content
                                                    test using a sand-screen  set
Reference:
Xanthakos 1979.
Permission.
                             Copyright  1979 by McGraw-Hill Books.  Used  with
                                      5-18

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the amount of water lost from a 15cP slurry through filter paper when
subjected to a pressure of 100 p.s.i. for 30 minutes (Grim and Guven 1978).
Some controversy exists as to whether or not this test accurately reflects the
ability of the slurry to form a filter cake.

     Despite the fact that the test may serve as a useful indicator, the
filtrate loss test has several innate flaws, including the facts that the
filter paper used has very little similarity to the strata at the slurry/soil
interface, and that the pressures used are not representative of in-place
pressures found in slurry trenches (Hutchison et al. 1975).

     In addition, there is little if any relationship between the results  of
the standard API filtrate loss test and the permeabilities of filter cakes
from the same slurry (D'Appolonia 1980b).  Thus the filtrate loss test  is
regarded by some persons involved in slurry trench construction as
inappropriate for slurry specification (D'Appolonia 1980b, Millet and Perez
1980).
          5.3.6.5  In-Trench Slurry


     The requirements  for the  in-trench  slurry  are  few and  simple.   The
in-trench slurry becomes denser due  to the  suspension  of  soil  particles  in the
slurry.  For the in-trench  slurry, two measurements  are important.   A slurry
sample taken from the  trench bottom  near  the  toe  of  the backfill  should  be at
least 15 p.c.f. less dense  than the  backfill  material,  and  must be  capable of
passing a Marsh funnel.  This  is  to  allow complete  and rapid displacement  of
the  slurry during backfilling  (D'Appolonia  I980b).


          5.3.6.6  Backfill Materials
     The gradation of  the  soil material  used  for  the  backfill must be tested.
For  a  low  permeability cut-off,  at  least 20  to 60 percent  fines should be
presented  (D'Appolonia 1980).  Although  plastic fines yield lower
permeability, non-plastic  fines  will  show a  greater ability to withstand
chemical attack.  Larger particles, such as  cobbles or clay lumps greater than
5  inches across  should be  prohibited  (IMC [no date]).
          5.3.6.7  Mixed  Backfill


     Once the backfill material  has  been selected,  it must be mixed with the
 slurry  in the proper  proportions so  that it  has  the following characteristics

     •   A bentonite content  of  1 to  2  percent

     •   A moisture content of 25 to  35 percent

     •   A fines  content of 20 to 60  percent.


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In addition, the mixed backfill should have a:

     •  Slump from 2 to 7 inches on the ASTM C143-74 "Slump of Portland
        Concrete" Test

     •  Density at least 15 pcf greater than that of the slurry  in  the trench

     •  Shear strength low enough to allow ready flow, and preferably lower
        than that of the filter cake.
               a.  Slump


     A typical backfill used in a pollution migration cut-off wall has a water
content between 25 and 35 percent, a bentonite content ranging from 0.5 to 2
percent and a fines content of from 20 to 40 percent.  The soil excavated from
the trench typically has an initial moisture content of from about 10 to 20
percent (D'Appolonia 1980b).  This moisture aids in mixing the slurry with the
backfill by softening the materials (Coneybear 1982).  When the backfill is
mixed in these proportions, the backfill forms a thick paste that will flow
easily (D'Appolonia 1980b).  The slump of the backfill, which is an expression
of its propensity to flow, is of great practical importance during backfilling
operations.

     If the backfill slumps too much, a very flat backfill slope occurs.  This
interferes with the efficiency of excavation.  Conversely, backfill with too
little slump allows voids and honeycombs to form and may cause entrapment of
pervious materials, leading to the formation of high permeability "windows" in
the finished wall (Millet and Perez 1981).

     When the backfill folds over and traps pockets of slurry, another problem
results.  The slurry does not become mixed with the backfill.  Instead, it
gradually rises to the top of the trench, due to its lower density.  This may
lead to wall weakness in the areas where the slurry pockets were initially.

     To avoid the problems listed above, a slump of 2 to 7 inches is usually
specified (Case 1982).  Figure 5-1 shows a cross-sectional view of a completed
trench, showing the successive layers of a well placed backfill.
               b.  Density


     Backfill densities typically range from 105 to 120 p.c.f.  At  these
densities, the backfill easily displaces the slurry in the trench (D'Appolonia
1980).  Even so, samples of the slurry taken from  the trench bottom should  be
tested for density prior to initiation of backfilling operations.
                                     5-20

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                         Figure 5.1.
Typical Backfill Profile in Trench with Irregular Bottom
        8 + 00
    Source: D'Appolonia 1980
                         5-21

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               c.  Shear Strength


     The shear strength of the backfill must be high enough  to  allow  it  to
stand on a 5:1 to 10:1 slope (Millet and Perez 1981).  Preferably its shear
strength is lower than the shear strength of the filter cake  to avoid
disrupting it.  Data on the relative shear strengths of the backfill  and the
filter cake were not located.  However, Boyes (1975) stated  that the  shear
strength of bentonite filter cakes is greater than that of concrete emplaced
in slurry trenches during concrete panel wall construction, and that  the shear
strength of one filter cake was measured at 0.00051 N/m .

     The fate of the filter cake during backfilling has been  the subject of
controversy.  Some people involved in slurry trench construction feel that the
filter cakes on both of the trench walls remain intact not only during
backfilling but also during subsequent permeation with groundwater.
D'Appolonia (I980b) suggested that the downstream filter cake may degrade
under the influence of high hydraulic gradients across the trench.  The
bentonite particles may then be forced into the soil pores if the soil
permeability is high enough.  Jefferis (1981a) proposed that  the upstream
filter cake would be more likely to decompose and be forced into the  cut-off
wall.  This is because the hydraulic pressure on the upstream side of the wall
is so much higher than the pressure on the downstream side.  Experimental
evidence cited by D'Appolonia (1980b) indicates that, as long as the backfill
contains at least 15 to 20 percent fines, this will not occur.


     5.3.7  Equipment


     Appropriate equipment must be available to accomplish the  following tasks
associated with slurry wall construction:

     •  Slurry mixing

     •  Slurry supply to the trench

     •  Slurry density control
     •  Trench excavation and aquiclude key-in
     •  Backfill mixing

     •  Backfill placement

     •  Hauling of backfill or spoils, if necessary.

     The type and size of this equipment is job dependent and is usually
selected by the contractor rather than specified.
                                     5-22

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          5.3.7.1  Slurry Mixing


     The slurry mixing and placement equipment must be capable of supplying
adequate quantities of slurry during excavation.  For slurry mixing, hydration
and control, the following equipment and facilities are needed:

     •  Mixing apparatus such as a venturi  (flash) mixer or a paddle (high
        vortex) mixer

     •  Pumps, valves, pipes, hoses, fittings and small tools

     •  Slurry hydration and storage ponds  (or paddle mixer for  small jobs)

     •  Slurry cleaning equipment, including airlift pumps, valves, pipes, and
        desanders, or mudshakers, if sand removal is desired.


          5.3.7.2  Trench Excavation
     For trench excavation,  it  is important  to  ensure  the equipment  used  can
maintain a continuous excavation line to the  total depth required.   Table 5-4
lists types of excavation equipment commonly  used  for  slurry  trenching.   If
the aquiclude is composed of a  hard type of rock,  the  backhoe or clamshell may
not be able to rip it out.   In  this type of  situation,  the  slurry wall can be
terminated at the top of the rock layer or special equipment  such as drills or
chisels may be used for key-in.  If rock fractures are noted  during  key-in
excavation, grouting may be  necessary.
          5.3.7.3  Backfill Mixing
     Bulldozers or graders are commonly used  for backfill mixing, although
mechanical batchers or pugmills may be employed at  sites where backfill mixing
areas are not available.  When a single centralized backfill mixing  area  is
planned, sufficient flat area must be set aside for this operation.
          5.3.7.4  Backfill Placement
     Backfill placement equipment normally consists of a bulldozer that  slowly
slides the mixed backfill into the trench at a point slightly  in advance of
the peviously-placed backfill.  (Backfill placement methods are described  in
detail in Section 5.4.6.)  Clamshells are also used at some sites.  At sites
where the trench spoils are unsuitable  for backfill mixing, soils from a
borrow area, along with bentonite slurry, must be hauled to the trench.  To
assist in placement of mixed backfill from trucks a metal  trough-like device
can be used to direct it into the trench at the proper point.  The trough  is
                                     5-23

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                                   TABLE 5-4.
            EXCAVATION EQUIPMENT USED FOR SLURRY TRENCH CONSTRUCTION
Type
Standard
backhoe
Modified
backhoe
Clamshell
Dragline
Rotary drill,
percussion
drill or large
chisel
Trench Width
   (feet)
1-5 (1)
2-5 (1,3)
1-5 (3)
4-10
Trench Depth
   (feet)
50 (2)
80 (2)
>150 (3)
>120
       Comments
Most rapid and least costly
excavation method (1)
Uses an extended dipper stick,
modified engine & counter-
weighted frame; is also rapid
and relatively low cost (1)

Attached to a kelly bar or
crane; needs > 18 ton crane; can
be mechanical or hydraulic (3)

Primarily used for wide, deep
SB trenches (4)

Used to break up boulders and to
key into hard rock aquicludes.
Can slow construction and result
in irregular trench walls (3)
References:  (1) Case 1982, (2) D'Appolonia 1980, (3) Guertin and McTigue
             1982, and (4) Shallard 1983.
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advanced to coincide with the advancing backfill placement  area  (Zoratto
1982).
     5.3.8  Facilities


     The  facilities necessary  for  slurry wall  construction  include  a trailer
or small  building  for supervisory  operations and  quality  control  procedures.
Necessary testing  equipment  includes  a  Fann viscometer, mud balance, moisture
tester  (or  sample  cans, a balance  and an oven), pH meter, sieves, Marsh
funnel, and slump  testing equipment (Xanthakos  1979,  Zoratto 1982).


     5.3.9  Methods


     In a materials and methods  specification,  the methods  to be  followed
during each stage  of construction  are spelled  out in  great  detail.   This
section lists the  steps that are typically described  in the specifications.
Discussions of each step are given in Section  5.4.  The steps for which
methods are described include:

     •  Slurry mixing and hydration

     •  Trench excavation

     •  Backfill mixing

     •  Backfill placement

     •  Protective capping construction

     •  Site clean up.


     5.3.10  Safety Procedures


     At non-hazardous sites, safety procedures  for slurry wall construction
are very  similar to those for most other construction sites.  The personnel
involved  in trench construction at hazardous waste sites must, however, be
protected from exposure to contaminants from the trench spoils, the  wastes or
leachates and the area surrounding the excavation.  Hard hats, as well as
rubber boots, gloves, and protective  coveralls may be required.  Where
volatile  toxins are suspected, air-supplied respirators may be necessary.
Personnel required to use safety equipment include equipment  operators,
inspectors,  QA/QC personnel and all other personnel near the  trench.
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5.4  Preconstruction Activities


     Preconstruction activities typically follow a chronology that includes:

     •  Designing the installation

     •  Estimating the costs
     •  Assembling the bid package and advertising

     •  Evaluating proposals
     •  Awarding the construction contract.


     5.4.1  Slurry Wall Design


     The design of a slurry wasl requires consideration of numerous
site-specific conditions, as described earlier.  The data that are gathered
during the design phase are carefully evaluated and organized to produce the
slurry wall specifications and plans, along with drawings of the site and the
proposed slurry wall.  These documents are used by the owner or engineer and
by potential contractors to estimate the complexity and cost of the slurry
wall construction.  The two types of slurry wall design specifications most
frequently encountered are described in Section 5.2.  The procedures and
considerations involved in slurry wall design were detailed in Section 5.1.


     5.4.2  Cost Estimates


     The designer must develop a cost estimate for slurry trench installation
that can be compared with bids received from potential construction
contractors.  Although a rough figure of $3-5/square  foot of soil bentonite
wall is generally accepted, it is not specific enough for sites where special
problems are anticipated.  To prepare a cost estimate, detailed information  on
costs and cost variation between sites is necessary.  These data are presented
in Section 7.
     5.4.3  Bid Package Preparation


     The bid package consists of a number  of documents  that  will  make up the
eventual contract.  Components of the bid  package  are typically the  following,
which are the  same  topics covered for most construction contracts:

     •  Invitation  to bid

     •  Instructions to bidders

     •  Contractor's bid sheets or proposal
                                      5-26

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     •  The  agreement between owner  and  contractor

     •  Performance bonds  and insurance

     •  General  and special  conditions of  the  contract

     •  Specifications  (general  and  special  technical requirements)

     •  Plans  and  drawings  (Jessup  and  Jessup 1963) .

     The bid package should  give bidders enough information,  both technical
 and  contractual, to prepare  and  submit bids  which accurately  reflect the
 effort  that  will be required to  complete a quality,  cost effective slurry
 wall.

     The bid package is.usually  sent to  prospective  contractors who  have
 responded  to an  advertisement.   In some  cases, only  pre-qualified firms are
 invited to bid.  Bids are  then submitted by  those interested  firms for
 evaluation.
     5.4.4   Bid Evaluation  and  Contract  Award


     Public  works  financed  by Federal, State,  or  local  funds  are  usually
required  to  be awarded  to the lowest  responsible  bidder,  as determined by the
opening and  reading  aloud of sealed bids  at  a  specifically designated  time
(Jessup and  Jessup 1963).   Therefore,' much emphasis  is  placed on  bid prices.

     After proposal  evaluation,  and bid  examination  have  been completed,  the
most qualified firm  submitting  the  lowest bid  is  determined.   The construction
contract  is  then awarded to the  firm  selected  in  the bidding  process.


5.5  Soil Bentonite  Wall Construction


     Following award of the construction  contract, the  selected firm will
proceed with construction of the slurry wall.   The major  activities  include:

     •  Preconstruction Assessment  and mobilization

     •  Site preparation

     •  Slurry preparation  and control

     •  Slurry mixing and hydration

     •  Slurry placement

     •  Backfill preparation

     •  Backfill placement

     •  Site cleanup and demobilization.

Discussions  of these activities  follow.
                                     5-27

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     5.5.1  Preconstruction Assessment and Mobilization


     Three major activities occur during the mobilization phase of slurry
trench construction.   These are:

     •  Layout site plan

     •  Determine the equipment,  type, amounts of materials, and facilities
        required

     •  Determine number and source of personnel required.


          5.5.1.1  Plan Layout


     A preliminary layout is prepared based on drawings supplied by the
engineer.  Once the preliminary layout is developed, a close examination of
the proposed construction site must be performed in order to ensure that all
details of the plan are practical.  After the onsite examination, a final
layout of the worksite can be prepared.  A diagram of a typical slurry wall
construction site is shown in Figure 5-2.


          5.5.1.2  Equipment Requirements


     The specifications and drawings, test boring records, subsurface
exploration reports, and records of utility lines are the first sources of
information for determining equipment, materials and facilities needs.  In
addition, an on-site inspection may be required to gain the detailed
understanding needed for planning the construction activities.

     The major work elements and equipment and facilities typically associated
with each work element are:

     •  Excavation
        -  hydraulic backhoe
        -  mechanically operated clamshell
        -  hydraulically operated kelly-mounted clamshell

     •  Slurry preparation and control
           high speed colloidal batch mixer for small projects
        -  flash mixer for large projects
        -  pumps, valves, pipes and tools
        -  hydration ponds
        -  desanders, hydrocylones or  screens

     •  Slurry placement
        -  pumps
        -  placement hoses and piping


                                      5-28

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                                  Figure 5- 2.
                    Typical Slurry Wall Construction Site
                                  Bentonite
                                   Storage
                                                     Backhoe
                   Backfilled
                    Trench
 Backfill
Placement
  Area
Area of Active
 Excavation
Proposed Line
of Excavation
                                                        \
                                  Slurry
                                 Storage
                                  Pond
                                                          Slurry
                                                          Pumps
                                             Slurry
                                           Preparation
                                           Equipment
                                  Bentonite
                                  Storage
                                                         ooo
                            Water Tanks
Access
 Road
                                        5-29

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     •  Backfill  preparation
           dozer  or grader

     •  Backfill  placement
        -  dozer
        -  mechanically operated clamshell
           trucks and trough

     •  Supervision and quality assurance
        -  shed or trailer
        -  Marsh funnel
        -  mud balance
        -  standard sieves.

     Numerous factors influence the types of equipment required as well as the
final plan layout and the relative difficulty of construction activities.
Some of these factors, along with their potential effects on slurry trench
construction operations are listed in Table 4-1.

     Determining the correct equipment applications for a particular project
is based upon construction requirements and the constraints imposed by the job
site.  For example, choice of excavation equipment depends upon the depth of
the slurry wall and the soil in which the wall is placed.  The maximum exca-
vation depth for a standard backhoe is about 50 feet, but larger, extended
models are available to reach up to 80 feet in depth (D'Appolonia 1980a).
Both clamshell excavation systems will reach depths more than 150 feet, with
the hydraulic model sometimes preferred in more difficult digging conditions
(Guertin and McTigue 1982c) (See Table 5-4).

     Consideration must also be given to site access and obstructions.  Access
roads might limit the size of equipment that can be brought to the site, while
obstructions at the site might preclude the use of some types of equipment.


          5.5.1.3  Personnel Requirements


     When determining the sources of personnel  for use at slurry trench
construction site, two choices  face the construction firm.  The  firm  can send
their own equipment and personnel to the construction site or they can rent
equipment and hire personnel locally.  Most firms will use varying
combinations of each  approach.  For larger jobs and critical  small jobs,  it  is
frequently more efficient to send equipment and personnel directly from  the
construction firm.  Small jobs  can often be handled effectively by using only
specialized company-owned equipment, such as a  extended backhoe  arm,
accompanied by supervisory  personnel.  Other equipment such as bulldozers,
cranes,  clamshells, and  large backhoes can be rented near the job  site.
Laborers and certain  equipment  operators  can be hired locally  for  the specific
job.  However, there  are  no  set rules, and each construction  contractor  will
tailor  his approach on a  site-by-site basis.
                                      5-30

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      Slurry  trench construction  contractors  are  best  able  to  judge  appropriate
equipment and personnel needed at  the  job  site.  However,  site owners  and
their representatives  should  be  aware  of the approach to be taken by  the
construction contractor,  and  should be satisfied that appropriate equipment
and personnel are available at the job site.


      5.5.2  Pre-excavation Site  Preparation


      Once site  planning has been completed,  necessary permits and clearances
have  been obtained, and required utility,  water  and other  services  have been
arranged, preparation  of  the  construction  site can proceed.   The work  site can
then  be cleared if necessary, security fences erected, utility and  water
hook-ups made,  equipment  and  facilities brought  in and set-up, and  construc-
tion  materials  delivered.  At this time, work can proceed  to move or remove
obstructions if necessary.


      5.5.3  Slurry Preparation and Control


      Before excavation begins, the slurry must be prepared.  To do  this,
bentonite and water quality must be tested, hydration ponds must be
constructed, lines laid,  pumps placed, and the mixing area prepared.   The
slurry is then mixed in a venturi of paddle mixer and allowed to hydrate fully
prior to placement in  the trench for SB slurry trench cut-off construction or
mixing with cement for CB cut-off construction.


          5.5.3.1  Testing Bentonite and Water


      Bentonite  quality is critical to  the quality of  the slurry.  Bentonite is
usually shipped to the job site  accompanied by laboratory  test results showing
that  it meets quality criteria.  These criteria  include physical and chemical
purity, pH, gel strength, dry fineness (percent  passing the number 200 sieve)
and filtrate loss.  At the job site, these criteria are checked frequently,
such  as by testing every  truckload of  bentonite  delivered. It is important for
the site owner to require field testing of delivered  bentonite, because
deliveries are occasionally rejected by field testing.  At a minimum, testing
of pH, viscosity and fluid loss should be conducted in the field for bentonite
delivered to the site.  (Quality control tests are described in Section
5.3.2.5.)

      Slurry quality decreases significantly  if the quality of make-up water is
poor.   Make-up water should be relatively low in hardness, near neutral or
slightly higher pH and low in dissolved salts.  Water  suitable for drinking is
not necessarily suitable for mixing with bentonite.  Water of inadequate
quality will result in higher bentonite consumption and a  lumpy slurry that is
difficult to mix and that contains above average amounts of free water.  In
                                     5-31

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some instances, poor quality water can be chemically treated to make it
suitable for mixing (Ryan 1977).


          5.5.3.2  Slurry Mixing and Hydration


     Two types of mixing systems are most frequently used.  These are batch
mixing and flash mixing.  In the batch system, specified quantities of water
and bentonite are placed in a tank and are mixed at high speeds with a circu-
lation pump or paddle mixer.  Mixing continues until hydration is complete and
the batch is ready for use in the trench.  Hydration is usually complete  in a
matter of minutes for the two to five cubic yard batch produced by this
system.  Because of the low output of the batch system, its use is limited to
small jobs.

     The second type of mixing  system is the  flash or venturi mixer.  For this
system, bentonite is fed at a predetermined rate into a metered water stream
as  it is forced through a nozzle at a constant rate.  The  slurry  is  subjected
to  high shear mixing for only a fraction of a second, which is not always
adequate for hydration.  Therefore, the  slurry is often stored until hydration
is  complete.  This is determined by periodically measuring the Marsh Funnel
viscosity.

     When Marsh Funnel viscosity readings stabilize, hydration is considered
complete.  Flash mixing is a process that can be operated  at high production
rates.  Because a majority of cut-off walls require continuous production of
large amounts of slurry, flash  mixing is the  more common of the two  mixing
methods (Ryan  1977).

     The type  of mixing system  used has  been  found  to  affect  the  quality of
the slurry produced.  High  shear  (or high speed batch mixers)  produce  slurries
with higher  gel strengths  (Xanthakos  1979).   Section  2  discusses  the influence
of  gel  strength on  slurry  quality.

     The grade of  bentonite  dictates  the percent  needed for  a given slurry  and
hydration  time.  For example, a grade 90 (bbl/ton)  bentonite  may  have  to be
mixed  at a 6.3  percent  concentration, while  a grade 125 would require  4.5
percent concentration  for  an equivalent  slurry.   Hydration times  for higher
grades  are likewise  lower,  which  may  result  in higher  slurry  production rates
 for a  given  slurry preparation  facility  (Ryan 1977).   However,  the higher cost
of  the  higher  grade  bentonites  requires  that  the  selection of bentonite grade
 to  be made on  a site by site basis.   Frequently  a mud  balance test is  run on
 slurry  from  the hydration  pond  as a quality  control check of  the  bentonite
content.   Viscosity and pH are  also checked  frequently (Cavalli  1982).


      5.5.4  Slurry Placement


      From the hydration pond,  slurry is  pumped on an as needed basis to  the
 open slurry trench.   Slurry level in the trench must be maintained at least

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several feet above the water table and normally within a foot or two of ground
level.  This slurry level is maintained to provide the hydrostatic pressure
necessary to hold open the trench.

     Once a slurry trench installation is underway, backfill and excavation
are being performed simultaneously, with a minimum amount of trench remaining
open under the slurry.  Figure 5-3 illustrates the excavation and backfill
placement operations.  The amount of trench remaining open at any one time
depends on the properties of the backfill material and the characteristics of
the excavation equipment, which are discussed in the following sections.
Samples removed from the trench for QC checks must be representative, that is
they should not be taken only from the top surface of the slurry but should be
taken at various depths in the trench.  Characteristics of the slurry, while
geared toward keeping the trench open during excavation and backfilling, must
also allow displacement by the backfill material.  That is the reason for
maximum as well as minimum values for parameters such as density, viscosity,
and sand content.  Those requirements are listed in Table 5-1.  During the
excavation operation, some of the spoil becomes incorporated in the slurry.
This increases slurry density and sand content.  A high sand content indicates
a high density and a likelihood of problems with eventual displacement of the
slurry by the backfill (D'Appolonia and Ryan 1979).


     5.5.5  Trench Excavation


     Excavation of a slurry  trench proceeds much as any trench excavation
except that only the portion of the trench above slurry level can be visually
inspected for continuity.

     Trench excavation is usually accomplished with appropriately sized back-
hoes with adequate boom length and bucket capacity.  Frequently, boom lengths
are extended by construction contractors  to meet the needs of the trench
installation.  Counterweights are often required to offset the movement
created by the long boom lifting a full bucket from the trench.  The backhoe
is the favored means of excavating a  slurry trench because it is much faster
than other equipment, such as the crane and clamshell.  However, boom lengths
are currently limited to 70  to 90  feet.   For greater depths, the crane and
clamshell are normally used.  Drag lines  have been used in the past, but have
been used rarely for recent  installations (D'Appolonia 1982).

     Trench continuity is critical to a successful installation.  For checking
continuity of slurry trenches, several approaches have been  used.   All of  them
may be employed at a given site to insure that the trenching is continuous
from the ground surface to the aquiclude  key-in.

     The field inspector should have  boring logs and a cross-sectional drawing
of the trench so that visual inspection of excavated material and degree of
extension of the backhoe boom will indicate approximate depth and whether  the
aquiclude has been reached.  Soil boring  data can also be used to quantify  the
aquiclude key-in.  By watching excavated  material  for a change in color or
                                      5-33

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                   Figure 5-3.
Cross-section of Slurry Trench, Showing Excavation
            and Backfilling Operations
                   5-34

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texture, construction personnel  can determine when  the  subsurface  layer  which
is  to be keyed  into  is  reached.

     Sounding of depth  with  a  weighted  line  or  a  rod  should  be  performed
frequently to ensure an even trench bottom and  to detect  any irregularities.
Finished trench depths  should  be recorded  for preparation of a  drawing showing
trench cross section.
     5.5.6  Backfill Preparation
     Standard practice during backfill  preparation  for  soil  bentonite  walls  is
to use excavated material mixed with  slurry  from  the  trench  for  backfill.  In
this case, the  slurry provides moisture necessary for backfill mixing.   When
trench spoils are used, the material  excavated  from the  trench is  usually
placed nearby,  slurry is added and  a  bulldozer  is used  to  track  and  blade  the
material until  it is thoroughly mixed.

     A relatively level working surface is needed for backfill mixing.   At
sites that are  too steep, backfill  mixing areas can be  excavated.  These
should be at least as wide as the width of the  excavating  equipment  track.
Where no backfill mixing areas are  available, batch mixers or pugmills  can be
used, although  these are slower than  using a bulldozer  for backfill  mixing.

     A number of quality control checks are  necessary for  backfill preparation
activities.  These include tests of the:

     •  Fines content

     •  S lump

     •  Wet density

     •  Presence of contaminants.
          5.5.6.1  Fines Content
    ^A key parameter in the design of a backfill is  the  sieve  analysis  and
particularly the amount of fines.  The content of  fines  in  the backfill  is
directly related to the permeability of the  finished SB  wall and  its  ability
to withstand chemical attack.  A standard practice is to perform  permeability
testing in the pre-construction phase to define the  range of acceptable  grain
size distributions that will provide the design permeability.  During
construction, frequent grain size distributions and  less frequent permeability
testing^is performed on the backfill material to ensure  that the  design
permeability requirements will be met by the completed slurry  trench.  Grain
size distributions can be performed in a field laboratory and  are much  less
expensive to run than permeability tests, which are  usually run in a
laboratory.
                                     5-35

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          5.5.6.2  Slump


     Slump cone testing should be performed frequently on backfill material
after mixing to make sure the backfill is wet enough to slump in the trench
without trapping pockets of slurry yet dry enough to displace the slurry
easily.  High slump also indicates a gentler slope of backfill in the trench,
which would require keeping more of the trench open.  A slump of 2 to 6 inches
is adequate .(D1Appolonia 1980).  Additional information on^the slump of the
backfill and its effect on the finished wall can be found in Section 2.
          5.5.6.3  Wet Density


     Mud balance testing should be performed  frequently on  the backfill before
it is placed in the trench.  Mud balance tests indicate the wet density of  the
backfill.  This shows  for certain that  the backfill will or will not  readily
displace the slurry.   The wet backfill  sample used for the mud balance test
can be dried and reweighed  to determine the water content.  A very high water
content can result in  excess water infiltration  into  the trench walls and
excess settlement of the backfill.  The separation of water from an
excessively wet backfill can also dilute the  slurry in the  trench.


     5.5.7  Backfill Placement


     Once  trench excavation has  proceeded  for a  distance  that  will not  result
in backfill material being  re-excavated, backfill placement can begin.  First,
samples of slurry at the base of the  trench  are  collected  and  tested  for  wet
density.   The  slurry should be  at  least 15 pcf less dense  than the backfill
mixture  (D'Appolonia 1980b).  If the  slurry  is too  dense,  it will  not be
displaced  properly during backfill  placement.  The  dense  slurry  or coarse
material on the  trench bottom must  be removed via airlift  pumps,  a clamshell
bucket or  other method.  This slurry  can be  used for  backfill  mixing  or it can
be desanded via desanders,  hydrocyclones or  screens,  and  returned  to  the
trench.

      To  place  the  initial  layer of backfill,  a clamshell  is often used.  The
backfill must  not be  allowed  to drop  freely  through the  slurry,  as this may
cause segregation  of  the  backfill particles  or entrapment of slurry   pockets
within the backfill.   For  this  reason, the clamshell  lowers the initial
grabfull  of backfill  to the trench bottom.   The next  grabfull is placed on top
of  the first,  and  so  on until  the backfill is visible at  the ground  surface.
 Thereafter, the backfill  is pushed into the trench by bulldozers or  graders.
 The  point  of trench backfilling progresses towards the area of active
 excavation (D'Appolonia and Ryan 1979).  Figure 5-2  illustrates this process.

      The slope of the  emplaced backfill is normally  5 to 10:1.  The  distance
 to be maintained between the toe of  the backfill and the area of active
 excavation varies  greatly,  depending on soil types and backfill slopes.

                                      5-36

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Ideally this distance is kept to a minimum  to avert  trench  stability  problems
(D'Appolonia 1980b).  Some specifications have  set the distance  at  from 30  to
200  feet (U.S. Army Corps of Engineers 1975, Ryan 1976).

     Sounding the placed backfill should be conducted to  show  the slope at
which the backfill  is coming to rest, and to indicate possible problems with
trench wall collapse and entrapment of pockets  of slurry.   Depths should be
recorded and plotted on a cross sectional drawing of the  trench.  Trench
excavation and backfilling progress can also be recorded  in this manner.

     When a slurry wall is constructed to entirely surround a waste site, the
excavation must end with enough overlap to  ensure that all  material designated
for  excavation is removed.  The .inspector must  determine  that  the backhoe
bucket is removing backfill materials from  the  full  trench  depth to verify
that the trench is continuous for its entire length.
     5.5.8  Capping


     To protect the  finished SB wall, either  a dessication  cap  or  a  traffic
cap is applied to  the slurry wall surface.

     Once backfill has been completed, cracking  is  soon  observed on  the  top  of
the slurry wall unless it stays, wet;  to complete the  installation,  the  top  i
to 3 feet of wall  is removed to eliminate  the cracks and a  high quality
backfill material  replaces it.  The material  used is usually  required  to have
a high clay content  and to be compacted in  lifts over  the trench.  This  forms
a low permeability cap to protect the cut-off wall  from  excessive  dessication
(U.S. Army Corps of  Engineers 1976).  This  is followed by topsoil  and  seeding
or a gravel layer  to prevent water and wind erosion.

     Where traffic over the wall is anticipated, a  traffic  cap  can be
constructed to reduce the load on the completed cut-off.  To  do this,  lifts  of
compacted clay are interspersed with geotextile  layers.   Gravel can  be used
over the final geotextile layer at the surface.  At one  facility where a soil
bentonite cut-off wall was close to a heavily traveled gravel road,  the  cap
consisted .of an 18-inch thick compacted clay  lift topped by a geotextile
sheet.  This was overlain by another 18-inch  thick  compacted  clay  layer  topped
by another geotextile sheet.  Inches of gravel were placed  over the  final
sheet of geotextile  to distribute the weight  and bear  the load  of  the  vehicles
(Coneybear 1982).


     5.5.9  Clean Up Activities


     After wall construction is complete, the excess slurry and mixed  backfill
must be disposed of  in a manner that avoids erosion and  disruption of  sewer
lines.  The slurry should not be allowed to enter sanitary  or storm  sewer
lines due to the potential for pipe blockage  from the  slurry.   It  also should
not be left as a thick layer on the soil surface, as this may result in


                                     5-37

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excessive ponding of surface water.  One method of slurry disposal would be  to
mix the slurry with dry coarse soil to produce as dry a mixture as possible.
This material could then be either buried or spread in a thin layer over
disturbed areas, then fertilized and seeded.  Any contaminated soil from the
excavation must be disposed of in accordance with site requirements.  All
disturbed areas should be stabilized and site maintenance procedures, as
outlined in Section 6, should be instituted.

     There are a number of differences in construction activities that vary
with construction materials.  The following is a brief summary of cement
bentonite and diaphragm wall construction techniques.
5.6  Cement Bentonite Wall Construction
     The discussion that was presented above is an outline of a  soil bentonite
(SB) cut-off wall construction.  Modifications to the construction  specifica-
tions are necessary when constructing a cement-bentonite (CB) cut-off wall.
These modifications include:

     •  The requirements for backfill materials are eliminated.

     •  A description of the standards for cement and cement storage is  added
        in the materials section.

     •  A description of the CB slurry requirements and the cement/water (C/W)
        ratio to be maintained for desired compressive strength  is  added to
        the materials section.

     •  The methods to be used for tie in of adjacent CB panels  (if used)  are
        addressed in the performance section.

     •  Under the Quality Control section, a requirement is added  for the
        manufacturer's certification of the cement and the testing  of cement/
        water ratio for each batch of mix is required.

     Cement bentonite (CB) slurry walls involve the use of a slurry consisting
of water, bentonite and cement.  The advantages of CB walls are  that backfill
material is not needed and they exhibit some structural strength.   In
addition, by excavating a section (panel) at a time, a CB wall can  be
installed on a site with more extreme topography.

     Two types of CB walls are being used.  The in-place method  involves
simply excavating under a CB slurry and leaving the slurry in place.  The
slurry eventually sets to provide some structural strength.  For the
replacement method, excavation takes place under a bentonite slurry.  Once
excavation of the section of wall is complete, the bentonite slurry is  pumped
out of the trench and the CB slurry is pumped in and allowed to  set.  The
replacement method is used only when setting of the CB slurry could possibly
occur while excavation is being completed.
                                     5-38

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      Cement bentonite slurries begin to set within 2  to 3 hours  after  the
 cement and slurry are mixed.  If the slurries are agitated  for over 48 hours,
 they lose their ability to set (Jefferis 1981b).  For this  reason, when  it
 appears that the excavation of a single CB panel will take  longer  than a day
 or so to complete, cement retarders are added to the  slurry or the replacement
 method is used.  Examples of this situation would be very deep excavations,
 when rock is encountered in the excavation, or when keying  the trench  into
 bedrock.

      Quality control procedures for CB walls are identical  to those for  soil
 bentonite walls.  However, composition of the CB slurry is  more  critical,
 therefore care^must be taken when weighing and mixing components of the
 slurry.  This is because the calcium in the cement causes an irreversible
 decrease in slurry quality, as described in Section 2.  Table 5-5 shows
 typical materials quality control standards for cement-bentonite cut-off
 walls.
 5.7  Diaphragm Wall Construction


      Construction of diaphragm walls also involves the use of bentonite or CB
 slurries,  although these walls are not normally used for pollution migration
 cut-offs,  except where high strength is required.  Diaphragm walls are
 composed  of either precast concrete panels or cast-in-place concrete sections.
 Unlike SB  and CB walls, these walls develop a great deal of strength over time
 and can be used as structural components.  A brief description of the
 techniques used for construction of diaphragm walls is given below.

      Precast concrete panel walls are cast offsite in segments from 1 to 3
 feet thick,  from 10 to 20 feet wide and from 30 to 50 feet long.  The panels
 are lowered  into a trench containing bentonite slurry and secured in place.
 Due to their dimensional limitations, concrete panel walls are usually only
 employed where depths of 50 feet or less  are required (Guertin and McTigue
 1982b).  An  exception to this general rule occurs where a CB slurry is used in
 the trench.   The panel is lowered into the trench and secured, and the CB
 slurry that  remains in place is allowed to set up around the panel.  Using
 this technique,  the trench can be extended lower than 50 feet, and the panel
 suspended  in the CB slurry.   The CB slurry then forms a cut-off both below and
 on  either  side of the diaphragm panel.  The  CB slurry also forms the joints
 between the  panels (Jefferis 1981b).

     Cast-in-place concrete  walls are constructed by excavating a short trench
 (or  slot)  under  a bentonite  slurry.   When the  slot is completed,  the slurry  is
 desanded if  necessary to  reduce  its  density  and to avoid problems with sand
 accumulations  on  the  reinforcing  bars (Guertin and McTigue 1982b).   The
maximum recommended  slurry density is 75  p.c.f.  and the maximum recommended
 sand content  is  5  percent  (Millet  and Perez  1981).

     The reinforcing  bars  are  lowered into place,  then  the concrete is  tremied
 into place, using  a  funnel-like  apparatus  that directs  the concrete  to  the
 trench bottom.  The apparatus  is  raised as the concrete  level  rises.   Slurry


                                      5-39

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                                                 TABLE 5-5.
                        MATERIALS QUALITY CONTROL PROGRAM FOR CEMENT/BENTONITE WALLS
         Subject
Standard    Type of Test     Frequency
                                                                               Specified Values
            Water
            . pH              Per water source
            • Total Hardness  or as changes
            (Ca & Mg)        occur
                                                     As  required  to  properly
                                                     hydrate  bentonite  with
                                                     approved additives.
                                                     Determined by  slurry
                                                     viscosity and  gel  strength
                                                     tests.
Materials   Bentonite
            Cement
API STD 13A   Manufacturer certificate of
              compliance


ASTM C 150    Manufacturer certificate of
              compliance
                                                  Unaltered sodium cation
                                                  montmorillonite
                                                  Portland, Type  1  (Type V or
                                                  Type  II  for  certain  applica
                                                  tions)
Bentonite
Slurry
C-B
Slurry
Prior to API STD 13B - Viscosity
Addition of
Cement
Upon API STD 13B - C/W Ratio
introduction API STD 10B - Viscosity
in the
trench
	 . 	
1 set per shift or V >_ 34 sec-Marsh @ 68°
per batch (pond) pH >_ 8
Each Batch C/W = 0.20
5 per shift V = 40 to 50 sec-Marsh
— • . 	 , 	 . 	 . 	 — 	 —
 Reference:  Federal Bentonite 1981.

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 is pumped out as the concrete is tremied in.  The slurry is then filtered and
 used in the next panel.  This process is illustrated in Figure 5-4.  A
 cast-in-place wall, when set, is composed of a concrete panel sandwiched
 between two bentonite filter cakes.

      These walls are not normally used for pollution migration control due to
 their susceptibility to leakage through panel connections, their high
 permeability relative to SB walls and their greater expense.  In addition,
 relatively minor earth movement can cause leakages through panel connections,
 cracking of the relatively brittle concrete, and differential settlement of
 the panels (Guertin and McTigue 1982b).


 5.8  Potential Problems During and After Construction


      There are several mechanisms or processes that can affect the
 construction or functioning of slurry walls and cause construction delays,
 trench collapse or wall leakage.  These are usually the result of either
 excavation and installation procedures, or unforseen subsurface conditions.

      Wall disruption may occur during excavation and installation and requir-
 ing re-excavation of the slurry trench.  Once the wall is in place, improper
 construction techniques or adverse physical and chemical processes can affect
 the integrity of the wall and its impermeability.  The following discussion
 focuses  on the various problems  that may be encountered and methods used to
 overcome them.  Types of problems include:

      •  Unstable soils

      •  High water tables

      •  Hard rock in excavations

      •  Sudden slurry losses

      •  Slurry flocculation

      •  Trench collapse

      •  Inadequate  backfill placement
      •  Cracking

      •   Chemical disruption.


      5.8.1   Unstable  Soil

      At  some  sites,  the  surface  soils  are too  soft  to  support  heavy construc-
 tion  equipment.  A  work  platform can be  constructed  of  compacted  soil  along
with  the proposed  line  of  trench excavation.   The construction equipment  can
maneuver on  this platform  and  the  trench can be excavated directly  through it.
                                     5-41

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                                                         Figure 5-4.
                            Schematic of Conventional Cast-in-Place Diaphragm Wall
                                       Slurry Supply Pipe
Clamshell Bucket
            a) Excavate Soil and Replace with
                     Bentonite Slurry
                               Tremu
                                Pipe
                      Concrete - * -. -4
                      • •'.- '• v •'• .'••'••
                                        Ill *^M^v "
                                       '. r^ &f.' •

                               "itf«**  ''
             Pour Tremie Concrete to  Displace Slurry,
                    Remove Stop-End Tubes
                                                                                       &
                                                                                                  Bentonite
                                                                                                   Slurry

                                                                                                                   Reinforcing Steel
 b) Place Stop-End Tubes and Reinforcing Steel
           into Fully Excavated Panel
                                                                        Paru:l ti> bt; Concreted
                                                                         St,T< nullify
                                                                                                       with Slurry  Secondary
d) Different Construction Phases

                       Source: Guertin and MuTiyue, 1982

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      5.8.2  High Water Table


      A work platform can also be used to maintain sufficient hydraulic head in
 the slurry trench to offset high groundwater pressures (Namy 1980).  The
 slurry level must be maintained at least several feet above groundwater
 levels, as described earlier.

      When groundwater levels suddenly rise close to the surface, the trench
 may^collapse unless measures are quickly taken.   The U.S.  Army Corps of
 Engineers (1976), recommends in their specifications that, should this occur,
 the contractor should stop excavating and begin backfilling any open trench
 sections as rapidly as possible.  After the groundwater level decreases and
 the wall has set sufficiently,  the hastily backfilled sections can be
 re-excavated and properly backfilled.


      5.8.3  Rock in Excavation


      When a slurry trench must  be excavated through material containing
 numerous or large boulders,  hard rock layers,  or into a hard aquiclude,
 construction delays are likely.   The  use of large equipment such as cranes may
 be  required to remove very large boulders.   Rotary or percussion drills may
 also be used to break up boulders prior to  the use of smaller excavation
 equipment.   All rock fragments  should be removed from the  trench bottom prior
 to  backfilling.

      The presence of boulders near the trench  bottom,  or the presence of an
 unrippable  aquiclude may lead to variations in trench depth and inadequate
 aquiclude key-in.   If trench excavation is  not extended far enough into the
 aquiclude,  the bottom of the slurry wall is inadequately sealed,  and
 underseepage may result.   When  a permeable  layer exists beneath the slurry
 wall, migration of water,  wastes,  or  other  materials is likely to occur
 (D'Appolonia 1980b).   This reduces slurry wall efficiency  and may lead to
 piping  failure,  as described later in this  section.


      5.8.4   Sudden Slurry  Loss


      Occasionally,  slurry  levels  within  a slurry trench will  drop rapidly.
 This  situation,  termed  sudden slurry  loss,  can be  caused when the excavation
 encounters  previous  layers,  such  as gravel  lenses  or subsurface  pipes.


          5.8.4.1  Pervious  Zones  in  Excavation


     When^sand^or  gravel layers are encountered, rapid  slurry  loss  can  occur.
In this situation, lost circulation materials  are used  and  large  quantities of
slurry are pumped  into the trench  to maintain  high slurry  levels.   Factors


                                      5-43

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that can reduce the flow of slurry into pervious soil such as rheological
blocking and filter cake formation, are discussed in Section 2.


          5.8.4.2  Pipes and Conduits


     At some sites, subsurface pipes or other conduits have been encountered
unexpectedly.  This results in rapid loss of slurry from the trench.  Two
methods have been used to plug up the pipes and thereby slow or stop  the^rapid
slurry loss.  The first is applicable only to corrugated metal pipes, which
can be pinched shut, using the excavation tool like a giant pair of pliers.
The second method involves the rapid introduction of lost circulation
materials, including "shredded cellophane flakes, shredded tree bark^ plant
fibers, glass, rayon, graded mi'Ca, ground walnut shells, rubber tires,
perlite, time-setting cement and many others" (Xanthakos 1979).  Coarse  sand
and crushed brick have also been used.  These materials clog the pipe and
allow the slurry to reseal the trench.  In any case, additional fresh slurry
must rapidly be pumped into the trench to avoid the loss of trench wall
stability (Guertin and McTigue 1982b).
     5.8.5  Slurry Flocculation
     This situation may occur when  cement  is  added  to  a bentonite slurry to
 form a CB slurry or when bentonite  slurries come  in contact  with other high
 calcium materials.  Several  approaches  can be taken when the slurry begins to
 form flattened clumps.  Various  thinners or dispersing agents can be added, as
 listed in Table 2-4.  Additional fresh  slurry may be added,  or additional
 bentonite may be added, depending on the severity of the flocculation.  A
 discussion  of  flocculation  and  its  causes  is  presented in Section 2.
      5.8.6   Trench  Collapse


      Trench collapse is  caused by the loss of stability in the trench walls
 during excavation and before backfilling or CB slurry hardening.  Causes of
 trench collapse include:

      •  Insufficient slurry  head above groundwater

      •  Sudden or rapid  loss of slurry due to contact with gravel, large
         pores, fissures,  etc.

      •  Surface runoff into  open cracks

      •  Insufficient agitation of slurry

      •  Overloading of the ground surface with stockpiles or heavy equipment
         in close proximity to the trench.
                                      5-44

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     The underlying causes of trench collapse is the failure of the slurry to
form and maintain a low permeability filter cake.  Factors that interfere with
filter cake formation or functioning were discussed previously.

     Trench collapse can be either total or partial.  Sometimes only partial
collapse occurs, and the material from one wall slips partially into the
trench without bridging the entire trench width, as shown in Figure 5-5.  In
this situation, the trench may still be salvageable.

     If severe collapse of the trench side walls occurs, the trench can be
backfilled as much as possible and left as is.  Another  trench parallel to the
collapsed trench and at least 15 feet away is excavated  using typical slurry
trench construction techniques (Boyes 1975).
     5.8.7  Inadequate Backfill Placement
     Improper placement of the backfill can result  in underseepage,  excessive
consolidation, or wall leakage.  Specific backfill  problems are described
below.
          5.8.7.1  Sediments in Trench Bottom
     The slurry can suspend small particles of sand as well as  silt  and clay
particles due to the shear strength and gel structure of  the  slurry.  Coarse
sand and larger particles are not suspended.  Instead they sink to the trench
bottom and accumulate there.  Excessive accumulations of  heavy  sediments mixed
with slurry can interfere with backfilling if these sediments are close enough
in density to the density of the backfill.  Cuttings from broken boulders  or
gravel can also interfere with backfilling.  The backfill cannot displace
these sediments, so they remain after backfilling as a layer  of sandy or
gravelly slurry beneath the backfill.  Studies of this type of  material have
shown that slurry-laced sand and gravel layers are much more  susceptible to
failure, leakage, and chemical degradation than are backfills containing a
higher percentage of fines (D'Appolonia 1980b).  At many  sites,  the  removal of
the sand from the trench bottom prior to backfilling is not necessary.  This
is because the slurry-encapsulated sand has a lower initial permeability and a
higher density than the backfill.  Thus the sand layer is not likely to
interfere with backfilling operations.

     The ability of a pure sand/bentonite layer to withstand  permeation over
time is, however, questionable.  Even if a sand/bentonite backfill contained
from 2 to 3 percent bentonite by weight, failure could occur  due to  permeation
by calcium-rich solutions (D'Appolonia 1980b).

     This situation is similar to the conditions at the trench  bottom where
bentonite concentrations may be minimal.  Bentonite slurries  usually contain
from 4 to 7 percent by weight bentonite when introduced to the  trench.  As
spoil particles become mixed with the slurry, the slurry  density increases and
                                     5-45

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                        Figure 5-5.
  Trench Collapse, Showing Plane of Weakness (a)
                and Block Slippage (b)
                  ^ * J. - ^ . . , PL -r*J° °
                 •A^^AwAwfc^A^ '•-•*iVXi»/>.;
paPP
V • J"*^ • • fJJ-W*»
J Oi\r,
       nc-.«
 ^^^roCS
  Line of Slurry Visible   QM
at Ground Surface a Few  °
                                  t  Feet from the Trench
                               r-rV  Along Plane of Weakness



                           (a)

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the weight percent of bentonite is consequently reduced.  The slurry is most
dense at the trench bottom due to the presence of the settled sand and gravel
layer.  Thus the weight percentage of bentonite in the slurry at the trench
bottom may conceivably drop to 3 percent or less, leaving the cut-off wall
susceptible to failure should prolonged permeation with cation-rich solutions
occur.

     To prevent piping failures of soil-bentonite cut-off walls, D'Appolonia
(1980) recommends that the backfill contain at least 20 percent fines.  These
fine particles effectively resist intergranular stresses and reduce the
erosion of the bentonite particles from the backfill matrix.  The backfill
should be homogenous, both horizontally and vertically, to avoid piping
failures and underseepage.  Removal of the slurry-encapsulated sediments from
the trench bottom prior to backfilling helps ensure vertical homogeneity and
can contribute to the long term integrity of the cut-off wall.
          5.8.7.2  Slurry Pockets in the Backfill
     If the slump of the backfill is too high, the backfill does not flow to
the trench bottom properly, but folds over itself during backfill placement
and may entrap pockets of slurry.  These slurry pockets remain in the wall and
act like compressible layers with lower resistance to hydraulic gradients and
chemical attack than the surrounding backfill.  Because the slurry is less
dense than the backfill, it gradually rises through the paste-like backfill
until it reaches the trench surface.  There, it is subject to desiccation and
cracking if the clay cap has not yet been placed, or it may interfere with the
connection between the clay cap and the cut-off.  If the amount of entrapped
slurry is excessive, the wall may need to be re-excavated and backfilled.
     5.8.8  Cracking
     It is well known that soils containing an appreciable concentration of
clay can shrink, forming cracks, when allowed to dry.  Even cement bentonite
walls can crack "drastically" when allowed to dry (Jefferis 1981b).  Some
soils can, however, shrink and crack even when nearly fluid enough to flow.
Nash (1976) and Tavenas et al (1975) noted the formation of cracks in silty
clay soil mixtures only slightly dry of their liquid limits.

     These cracks can be caused by several processes, including:

     •  Consolidation

     •  Hydraulic fracturing

     •  Syneresis.
                                     5-47

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          5.8.8.1  Consolidation


     Consolidation of soils occurs when water is squeezed from the soils pores
(Hirschfeld 1979).  This process is accompanied by a decrease in the volume of
the soil mass due to a decrease in the volume of voids in the soil. (Baver,
Baver and Gardner 1972)  The amount of consolidation is maximal in fine-
textured soils and minimal in coarse textured materials (Xanthakos 1979). The
rate of consolidation depends on the soils permeability, the thickness of the
layer being loaded and the magnitude of the soil mass's volume decrease.  In
fine textured soils, consolidation occurs at a much slower rate than in coarse
textured ones.  Most of the consolidation occurs rather quickly, however fine
textured soils can continue slow minor consolidation for several months
(Hirschfeld 1979).  The soil-bentonite backfill in slurry walls has been found
to continue consolidating"for about 6 months, with minimal decreases in volume
thereafter. (Xanthakos 1979)

     The amount of consolidation in slurry walls is limited by the backfill's
arching action along the trench walls and by grain to grain contact in the
backfill (Xanthakos 1979, D'Appolonia 1980b).  The amount of slurry wall
consolidation depends on trench width, as well as on the amount of fines in
the backfill.  As the fines content increases, consolidation increases because
fine particles are more compressible than coarse ones (Mitchell 1976).  Wider
trenches have been found to consolidate more than narrow ones.  An 8-foot wide
trench, for example, was reported by Xanthakos (1979) to have consolidated
from 1 to 6 inches during the first few months after construction.  In
contrast to soil bentonite walls, CB walls consolidate very rapidly (Ryan
1976).

     The process of consolidation in SB walls can produce many small cracks
along shear zones in the soil mass (Mitchell 1976).  Horizontal cracks that
extend through the backfill can also be produced by the arching action
mentioned earlier (Nash 1976).  This cracking can occur even when the backfill
is still quite fluid.  Normally, the backfill contains from 25 to 30 percent
water.  This moisture content is slightly more than the liquid limit of  the
backfill (D'Appolonia 1980a).  When soil is at its liquid limit, it contains
so much water that it will flow under the influence of an applied stress
(Baver, Baver and Gardner 1972).  Even so, Nash (1976) observed the formation
of horizontal cracks in a silty clay backfill that was only slightly dry of
its liquid limit.  The details of Nash's laboratory tests on this soil
material were not given.

     The arching that accompanies consolidation can also  lead to the formation
of another type of cracking due to a phenomenon called hydrofracturing.  The
relationship between hydrofracturing and consolidation is described below.


          5.8.8.2  Hydro frac turing


     When soils or rocks  are subjected to excessive hydraulic pressures,
cracks may form through which the excess water can flow.  The pressure  at


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which this cracking occurs can be less than the effective overburden pressure
on the rock or soil in situ.  This phenomenon has been used by petroleum
geologists to fracture petroleum-containing strata and thereby increase the
yield of oil wells (Bjerrum et al 1972).

     The amount of pressure required to induce fracturing depends on the depth
of the point receiving the pressure, and the ratio of vertical to horizontal
pressures at that point.  If is likely that other factors are also  involved.
Values used by petroleum geologists are 1 psi per foot of depth where the
vertical pressures are less than the horizontal pressures, and 0.64 psi per
foot of depth where the vertical pressures are greater than the horizontal
pressures (Bjerrum et al 1972).

     The cracks caused by this pressure extend vertically where the vertical
pressures are greatest and horizontally where the horizontal pressures are
greatest (Tavenas et al 1975).  These cracks can continue to increase in lengh
as long as the excess head is applied until they reach an area having greater
permeability (Bjerrum et al 1972).  When the pressure is decreased, the cracks
will partially close, but will reopen when the pressure is again increased.
(Tavenas et al 1975)

     The effects of hydrofracturing on the functioning of a slurry  wall can be
severe.  Where the vertical pressure exceeds the horizontal pressure (which is
normally the case) the pressure exerted on the aquiclude can cause  it to
fracture.  The vertical cracks will be immediately filled with slurry if this
occurs during construction.  Continued fracturing can, however, occur during
backfilling.  The backfill is less likely than the slurry to completely flow
in and fill the cracks in the aquiclude, and the aquiclude's permeability may
thus be increased.  The overall effect of this type of fracturing may be
minimal except at sites where the aquiclude is thin and/or overlies a very
permeable strata.

     A more detrimental effect of hydrofracturing may occur where the
horizontal pressures on the wall are greater than the vertical pressures.  If
more than 1 psi of pressure per foot of depth is applied to the wall,
horizontal cracks may form.  These could allow significant amounts  of water or
leachate to flow through the wall.  Hydrofracturing has been reported in both
SB and CB walls (Bjerrum et al 1972 and Miller and Perez 1981).

     The likelihood of slurry wall damage due to hydraulic fracturing is
highest where:

     •  Significant amounts of consolidation occur

     •  Piezometers are installed in the wall to monitor the wall's
        permeability using constant head tests

     •  Large vertical loads are applied to the soils on either side of the
        trench

     •  Large hydraulic gradients are allowed to develop across the wall.
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               a.  Consolidation


     When a great deal of consolidation and subsequent arching occur after
backfilling, the vertical loadings on the wall can be reduced to levels less
than the horizontal loadings.  This allows the wall to become susceptible to
horizontal cracking (Bjerrum et al 1972).  The amount of consolidation can be
minimized by reducing the content of fine particles, in the backfill (Mitchell
1976).  However, when additional coarse material is included in the backfill,
the wall's permeability is likely to be increased (D'Appolonia 1980b).  The
amount of permeability increase expected due to the inclusion of additional
coarse material in the backfill should be weighed against the risk of
hydrofracturing due to the anticipated pressure differential across the
trench.
               b.  Piezometers


     Where piezometers are placed in the wall to test the wall's  permeability,
hydrofracturing may be induced when the excess head is applied.   Hydro-
fracturing due to the use of piezometers occurred when permeability  tests were
being conducted on a series of dikes with soil-bentonite cores that  were
installed in Israel.  The constant head permeability tests were designed so
that the maximum head applied did not exceed the effective weight of the soil
above the piezometer.  However, even at very low hydraulic pressures,
hydrofracturing occured.  This fracturing resulted in a thousand-fold  increase
in the measured permeability (from 10   cm/sec initially to  10    cm/sec after
fracturing) (Bjerrum et al 1972).

     Tests on an in situ, normally consolidated clay were conducted  to see  if
hydrofracturing were caused by arching along the walls of the soil bentonite
cores.  The normally consolidated clay that was not  influenced by arching
along trench walls also fractured under the influence of an  applied  hydraulic
pressure that was less than the effective overburden pressure (Bjerrum et  al
1972).  This indicates that the occurrence of hydrofracturing is  not dependent
upon arching (and consolidation) along the walls of  slurry  trenches.

     When large vertical  loads are applied along the trench  walls,  the
horizontal stresses on the  slurry wall can be greatly  increased.   The vertical
loading can occur due to  placement of stockpiles or heavy equipment  along  the
sides of the trench.  Depending on the other  stresses  acting on  the  wall  at
the site, the horizontal  stress may become greater than  the  vertical stress,
thus making the wall  susceptible  to horizontal hydrofracturing.


               c.  High Hydraulic Gradients


     A  fourth  potential  cause  of  hydrofracturing  is  the  presence of an
excessive hydraulic gradient across  the wall.   If  the  pressure  on the
upgradient wall  exceeds  1 psi  per  foot  of depth,  and the horizontal pressures


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acting on the wall are greater than the vertical pressures, it is quite
possible that horizontal fracturing of the wall could occur.  Excessively high
hydraulic gradients could be induced by:

     •  Failing to provide subsurface drains or extraction wells upgradient of
        the wall

     •  Installing extraction or injection wells too close to the wall

     •  Dewatering a site without deflecting groundwater around the site and
        away from the wall (via drains, ditches or extraction wells).

     For this reason, the proper use,and placement of auxiliary measures, such
as wells, should receive careful attention during the wall's design stages.
          5.8.8.3  Syneresis


     Another process that can result in the  formation of cracks  in  a  slurry
wall is syneresis.  According to Mitchell  (1976) syneresis  is a  "mutual
attraction between clay particles" that causes  the particles "to form closely
knit aggregates with fissures between."  It  is  the contraction that occurs in
a gel that, results in the extrusion of liquid (water).  Syneresis is  often
observed,in gelatin after aging (Mitchell  1976).  Syneresis may  take  place in
slurry walls, however, the extent to which this phenomenon  affects  the
performance of slurry walls is not known.


     5.8.9  Tunnelling and Piping

     Two processes that can result in extensive breaching of a slurry wall are
tunnelling and piping.  Both of these processes involve the formation of
channels through the wall.  However, the causes and  solutions for the two
problems are different.                .


          5.8.9.1  Tunnelling


     Several dams have failed due to formation  of very  large pores  that extend
completely through the dam, from the upstream to the downstream  face. These
failures occurred where the earthen dams were constructed of low to medium
plasticity native clays that contained appreciable amounts  of sodium  montmor-
illonite (Mitchell 1976).  The process by  which the  failures occurred is
termed tunnelling, and it can be described as a series of interrelated steps,
as are listed below.

      1. Differential consolidation of the wet  and dry portions  of  several
         earthen dams led to the formation of stress cracks below the water
         line.
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       2. Water  that  contained  calcium  ions  flowed into the cracks.

       3. Calcium  ions  from  the water replaced  sodium ions  on the exchange
         complexes of  the clay particles  in the  dam. (See  Section 2 for a more
         detailed description  of  cation exchange.)

       4. The calcium ions caused  the clay particles  to decrease  in  size
         (shrink) and  to form  packets, or "floes."

       5. As the clay particles formed  floes, they became less dispersed,  and
         the space formerly occupied by the dispersed clay particles  became
         filled with water.

       6. As the sizes  of water-filled  spaces (pores) increased,  the rate  of
         water movement in  the pores increased.

       7. The increased rate of water movement  allowed the  water  to  carry  more
         particles in  suspension.

       8. As the particle-carrying capacity  of  the water increased,  the  number
         of clay  particles  eroded by the  flowing  water increased.

       9. As the number of clay particles  eroded  from the dams increased,  the
         sizes of the pores in the dams increased.

     10. As the pore space  size increased,  the speed of the  tunnelling  process
         increased until extensive tunnelling had occurred (Mitchell  1976).


     This tunnelling process has been  found to take  place  in earthen  dams and
embankments that had initial permeabilities as low as 10    cm/sec.  One method
that has been used to reduce the  likelihood of tunnelling  is to  mix the soil
with lime prior to dam construction.  This  causes the clay particles  to shrink
and become less easily dispersed before any cracking or particle erosion  can
occur  (Mitchell 1976).

     The risk of tunnelling failures in slurry walls is greatest where  ground-
waters contain high concentrations of calcium.  At these sites the  calcium
ions from the groundwater can  disrupt the soil bentonite backfill and cause
tunnelling failures  that are similar to the ones  experienced with the earthen
dams described above.  High calcium concentrations is groundwater are most
commonly found in sedimentary  aquifers, particularly limestone ones.  Water
from these aquifers can contain over 50 ppm dissolved calcium (Freeze and
Cherry 1979).

     The presence of stress cracks, high hydraulic gradients and permeable
backfills are  not prerequisites for the tunnelling process but these  factors
are likely to  speed  failure rate considerably.  The  causes  of stress  cracking
were described previously.   The hydraulic gradients  across  slurry walls at
hazardous waste sites are not  normally as high as the gradients  across  dams,
so the rate of tunnelling in slurry walls should  be  much slower  than  in
earthen dams.   Another factor  that operates in favor of slurry walls  is their


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low permeability, which is normally 1 to 3 orders of magnitude  less  than  the
minimum permeability of the materials through which tunnelling  had been
reported (Mitchell 1976, D'Appolonia 1980b).  This low permeability  indicates
that the initial rate of water movement through a slurry wall will be much
less than through the earthen dams, consequently the particle carrying
capacity will also be severely restricted, and the erosion rate will be
minimal.

     Despite the fact that tunnelling failures, if they occur in  a SB wall  are
expected to require long time periods to develop, the potential for  slurry
wall disruption due to the presence of calcium ions should be kept in mind
when evaluating the feasibility and design criteria for a slurry  wall
installation at a particular site.

          5.8.9.2  Piping

     Unlike tunnelling, which starts at the  upstream side of the  wall,  piping
begins at the downstream face and proceeds towards the upstream face (Mitchell
1976).  It occurs due to the use of improper backfill materials or procedures.
Variable wall thicknesses, poorly 'mixed backfill, or extensive  quantities of
coarse materials in the backfill can all contribute to piping failure.

     Piping occurs where a high hydraulic gradient causes the rate of water
movement through the wall to increase as the water nears  the downgradient side
of the wall.  If the water movement is rapid enough, it could conceivably
force the downstream filter cake into the pores in the soil along the trench
wall.  As the rate of water movement out of  the wall increases, it can  begin
to erode the easily-dispersed backfill, creating even-larger pores and
allowing the water movement rate to increase further (Anderson  and Brown
1980).  To avoid piping failures, the quality of the filter cake  should be
maximized, as described in Section 2, the backfill materials should  be
properly selected and mixed, the backfill should be carefully placed to avoid
fold-overs and permeable areas, and the hydraulic gradient across the wall
should be monitored and kept within designed levels.
     5.8.10  Chemical Disruption
     Chemical  substances  in  soil  and  groundwater  can affect  the durability of
the  slurry wall once  it is in  place.   Chemical  destruction can affect  the
cement  in CB slurry walls as well  as  the  bentonite  in CB and SB walls.   The
effects of alkali  salts on bentonite  slurries were  described previously.

     The action of the chemicals  on cement  or bentonite  are  similar to  that of
the  tunnelling process.  The cement may become  slurry solubilized and  the
bentonite may  become  entrained in  the solution  as the chemicals eventually
create  a solution  channel through  the wall  into surrounding  soil.  Thus,
chemical destruction  processes may create as well as accelerate the tunnelling
process.  Chemicals may also prevent  the  slurry from forming an adequate
filter  cake along  the sides  of the slurry trench  by interfering in the  slurry
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gelation process.  Additional  information  on  chemical  attack of slurry walls,
and on testing compatibilities  is contained in  Section 4.
5.9  Summary
     Design and construction activities  for  slurry  trenches  for  the  most  part
are relatively simple as long as thorough  site  investigation results are
available and design and construction  firms  involved  are  experienced with
slurry trench construction techniques.   Although many of  the slurry  quality
control procedures are more applicable to  drilling  muds than slurry  walls,
experience has shown that they are adequate  until improved procedures are
developed.  ASTM is studying these procedures and is  expected to make recom-
mendations for changes.  However, trench excavation and backfilling  processes,
which many experienced design and construction  people consider significantly
more important than the slurry testing procedures,  are governed  chiefly by
techniques that are practical and field  proven.  Many depend on  the  physical
dimensions and continuity of the trench  and  backfill  properties  which can be
verified by good field inspection.

     Therefore, when adequate foresight  is used in  the design stages, and good
field inspection is practiced in the construction phase,  existing  slurry
trench construction techniques should result in a quality installation that
meets the criteria of providing a low permeability  barrier to the  migration of
contaminants from waste sites.
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                                   SECTION 6

                    SLURRY WALL MONITORING AND MAINTENANCE
     Upon completing the design, preparation and actual construction of a
slurry cut-off wall, the next concern becomes the continuing effectiveness of
the wall in the subsurface environment.  The main question that arises
subsequent to a wall installation is whether or not the wall material will
remain resistant to the flow of  the substances it is meant to contain.  All
three of the commonly used backfill materials are subject to attack by certain
substances which can lead to an  increase in permeability.  In addition,
failures may result from structural disconformities within the wall.  The
ability to detect and measure these types of performance  failures  is an
important part of the slurry wall installation process.  Performance moni-
toring is essentially the only means of determining the effectiveness of a
cut-off wall over time, and some type of monitoring program should be
instituted at all walls installed for pollution control.

     The following section describes the different types of monitoring instru-
mentation used to evaluate wall  effectiveness and discusses the various
maintenance and restoration techniques which can be used to prevent and remedy
the deterioration or destruction of the wall.
6.1  Effectiveness Monitoring
     It is not possible to provide hard guidelines  for  the  selection of  a
monitoring program at a particular cut-off wall  site.   Such a selection  is
dependent upon two aspects of a project:  (1) the questions remaining  in the
designer's mind after completion of the design and  (2)  those problems  that
were encountered either during or after the construction  phase.  Every slurry
wall design and subsequent installation has individual  problems that are cause
for unanswered questions.  The monitoring program chosen  for a project should
reflect these questions, and the instrumentation selected should act as  tools
for providing data upon which additional judgements can be made.

     Despite the emphasis that must be placed upon  site specific characteris-
tics in selecting a monitoring system, a few general guidelines are
recommended and they are as follows:

     •  A solid knowledge should be attained of  problems  with the wall design
        and of those problems that were encountered during construction.
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     •  A monitoring system should never be solely selected on the basis of
        what was arranged at a similar site.

     •  Selection should be preceded by as thorough an understanding as
        possible with current data, of the nature of contamination, both
        physically and chemically.

     There are basically four types of potential geotechnical problems that
require consideration after a slurry cut-off wall has been installed.  These
relate to the following parameters:

     •  Basal stability
     •  Ground movement behind the wall
     •  Groundwater level and chemistry
     •  Surface water chemistry.

     Table 6-1 summarizes these parameters and possible measurement methods
for each.
     6.1.1  Basal Stability
     A common method of determining the basal stability of an area is to
measure the subsurface horizontal movement, either of the slurry wall itself
or of the ground behind the wall.  The instrument used for this purpose is an
inclinometer (Dunnicliff 1980).  An inclinometer system consists of a pipe
installed in a vertical borehole, with internal longitudinal guide groves.  A
torpedo containing an electrical tilt sensor is lowered down the pipe on the
end of a graduated electrical cable, the orientation being controlled by
wheels riding in the guide grooves.  The electrical cable is connected to a
remote readout device indicating tilt of the torpedo with respect to the
vertical.  Tilt readings and depth measurements allow alignment of the grooved
pipe to be determined.  Charges measured in the alignment of the pipe provide
horizontal movement data (Dunnicliff, 1980).
     6.1.2  Ground Movement
     There are several methods for measuring ground movement behind a cut-off
wall and they are categorized according to the type of movement being meas-
ured.  Horizontal ground movement can be measured using one of the following;
an optical survey, a horizontally installed multi-point extensometer, a
piezometer or an inclinometer system.

     Vertical movement of the ground surface is yet another potential problem
in the vicinity of a slurry wall construction site.  There are two techniques
available that can provide information on this type of movement; the optical
survey and the subsurface settlement gauge.
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                                  TABLE 6-1.
                  POTENTIAL PROBLEMS RELATED TO SLURRY WALL
           EFFECTIVENESS AND POSSIBLE ASSOCIATED MONITORING METHODS
Potential Problem
Parameters
Possible Measurement/
  Monitoring Method
Basal Instability
Horizontal Move-
  ment of Ground
•  Inclinometer
Ground Movement
  Behind Wall
Horizontal Movement
  of Ground
                         Vertical Movement
                           of Ground
•  Optical Survey
•  Inclinometer
•  Horizontally Installed
   Multi-Point Extensometers
•  Piezometer
                       •  Optical Survey
                       •  Subsurface Settlement Gauge
Groundwater
Surface Water
Groundwater Level
                         Pore Pressure
                         Chemistry
Chemistry
•  Observation Well
                       •  Piezometer
                       •  Sampling Wells
   Direct Sampling
Reference:  Dunnicliff 1980
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     In addition to the separate measurement of vertical and horizontal ground
movement, it is also possible to combine instruments and gather both types of
data simultaneously.

     Detailed discussions of all these techniques can be found in Dunnicliff
(1980).

     The parameters discussed thus far are measured in order to determine the
possibility of structural wall failure occurring due to changes in ground
stability in the surrounding area.  Basal instability and ground surface move-
ment are both possible causes for premature wall deterioration.  The moni-
toring of groundwater in the slurry wall area, on the other hand, serves a
slightly different purpose and is probably the most important parameter to be
discussed here.  Data obtained through groundwater monitoring provides infor-
mation on the present efficiency of the wall, instead of on possible reasons
for its future ineffectiveness.
     6.1.3  Groundwater Level and Chemistry


     The slurry cut-off wall is by no means a totally impermeable  structure.
In practice, it is impossible to achieve complete water tightness  (Telling et
al 1978).  There are, however, varying degrees of cut-off efficiency and  the
following section discusses the use of groundwater monitoring and  pump-in
testing methods to assess wall effectiveness.


          6.1.3.1  Groundwater Monitoring


     The major steps necessary in establishing a groundwater monitoring
network at a slurry wall site include the  following:

     •  Measure groundwater contamination  levels

     •  Design well and piezometer placement

     •  Design groundwater sampling and  laboratory analysis program

     •  Data interpretation.

     In assessing wall effectiveness, both the quality of groundwater  prior  to
slurry wall installation and the background level of  the groundwater quality
immediately following wall construction  are of primary importance. A  solid
groundwater background data base is necessary to ensure the validity of  future
comparative studies of sampling and chemical analysis results.   Proper inter-
pretation of chemical analyses conducted on samples taken on opposite  sides  of
a wall is crucial in determining the ability of a wall to contain  a contam-
inant plume.  Differences in groundwater chemistry across a wall can be  one
indication of whether or not the wall is sufficiently containing the
contaminant.
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     Another method of measuring wall efficiency  involves  the relative
hydraulic head drop across the wall.  The hydraulic head difference  is
generally measured using data obtained  from piezometer readings,  although
observation well data can also be used.  Equal numbers of  piezometers or
observation wells are normally placed on each side of the  wall.   Piezometer  or
well depth and distance from the wall will vary depending  upon  the surface and
subsurface characteristics of the site.  The optimal placement  scheme would
entail varying distances and depths to  scan as large an area on either  side  of
the wall as possible.  With data collected over a large area, the formulation
of a detailed groundwater flow diagram  is possible.  Using data obtained  from
piezometer readings, the increase in volume of water inside the cut-off during
a particular time period and the effective permeability can be  computed (U.S.
Army Corps of Engineers 1978).

     The design of a groundwater monitoring system to assess wall effective-
ness at a slurry wall site can involve  either groundwater  monitoring wells or
piezometers where monitoring wells are  installed, the designated  locations
will depend upon the number and extent  of the water-bearing zones to be
monitored.  A single well design is used only in  the case  where one  aquifer
system is to be monitored.  If more than one aquifer or water-bearing zone is
to be monitored, a well cluster system  may be required at  each  well  location.

     The most easily used piezometer design for monitoring a cut-off wall  in
terms of groundwater levels across the  wall is the open standpipe, the
simplest of these being a cased or open observation well.   The  water level is
measured directly with a small probe.   However, the open standpipe does not
function well in impervious soils because of time lag or in partially sat-
urated soils because there is a problem with evaluating pore-air  or  pore-water
effects.  The simplicity, sturdiness, and over-all reliability  of this  type,
however, dictates its use in many situations.

     The electrical piezometer, consisting of a tip with a diaphragm that  is
deflected by the pore pressure against  one face,  is also used at  slurry wall
sites. This type of piezometer is most  suitable for installation  in  quite
impervious and very clayey, plastic materials'.  The remaining two piezometer
types, the hydraulic and pneumatic piezometers are less frequently used for
the purpose of monitoring groundwater levels across a slurry wall and will not
be discussed here.  However, a good source of information  regarding  piezom-
eters and their applications is Wilson  and Squier (1959).   The  choice of a
groundwater sampling method will depend upon the  frequency of sampling, the
number of monitoring wells that have been installed and the specific
conditions at the site.

     The type of laboratory analyses to be performed for samples  will be
dictated by the type of wastes contained at the site.
     6.1.4  In Situ Permeability Tests
     Another means of monitoring wall effectiveness is by conducting in situ
permeability tests.  These involve sinking a vertical hole in the center of
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the wall, and using this backhole for conducting pump-in or slug type
permeability tests.  This procedure is not recommended for two reasons.
First, these tests are designed for use in permeable materials, and may give
erroneous values for low permeability SB backfill.  Second, these tests have
been shown to cause hydraulic fracturing in fine-grained soil materials.  Not
only would this give a falsely high permeability for the wall, it could create
planes of weakness, and lead to wall failure.


     6.1.5  Surface Water Chemistry
     The quality of surface water can be used as indication of cut-off
effectiveness if a contamination problem is located in close proximity to a
surface water body.  An example of such a situation is where a cut-off wall
has been installed to prevent a contaminant plume from entering a stream.  At
this type of site, monitoring the quality of stream water is an important and
necessary part of the monitoring program instituted.  As with groundwater
monitoring, the background water quality must be established in order to
determine the effectiveness of the remedial action program undertaken.  A
location far enough upstream to be unaffected by the site is necessary to
provide the most reliable background data.  The number and location of
sampling points will depend primarily upon the suspected configuration of the
contaminant plume and also the level of criticality judged from knowledge of
the chemical characteristics of the contaminant.  However, there should be a
minimum of three stream sampling sites:

     •  Background upstream

     •  Closest stream point to plume boundary

     •  Location downstream from site.
6.2  Maintenance


     One claim that  is very often  seen  in  the  literature,  concerns  the  number
of advantages that the slurry wall construction method  enjoys  over  competitive
systems.  Among these advantages is  that there is very  little  required
maintenance.  The slurry wall system eliminates the mechanical problems that
are often involved with other remedial  actions, such  as pump breakdowns
electrical power failures risks due  to  worker  strikes,  etc.  There  do exist,
however, other possible causes  for wall deterioration and  there are measures
that can be taken to protect the wall from premature  breakdown (see
Table 6-2).

     A  slurry cut-off wall's maintenance needs are very often  determined
during  the design and installation stages.  Pervious  zones in  slurry walls are
possible, for example, due  to improper  mixing  of  the  backfill, which then
results in pockets of permeable material within the wall.   Failure  to excavate
and subsequently key into  the aquiclude properly, can also be  the cause for
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                                   TABLK 6-2.
                POTENTIAL CAUSES FOR PREMATURE WALL DETERIORATION
                      AND ASSOCIATED MAINTENANCE TECHNIQUES
 Potential Cause for Premature
      Wall Breakdown
Maintenance Method
 Loading pressures
   Traffic capping
   Redistribution of load
 Erosion
                                              Re-vegetation
                                              Capping
 Hydraulic  head
   Groundwater pumping
wall  inefficiencies,  such  as  underseepage.   Proper  design and installation
will  greatly  reduce  the  possibility  that  failures  such as these will  occur.

      Chemical breakdown  of the wall  backfill material  is  another possible
failure mechanism.   However,  if  the  proper  steps are  taken,  during the  design
stages, including extensive compatibility testing,  the chances  of breakdown
are greatly diminished.

      Normal loading  pressures and even  catastrophic events such as earth-
quakes, are not generally  seen as causing problems with slurry  wall stability.
The compressibility  of slurry wall backfill  is designed,  in  most situations,
to allow for deformations  without cracking  (Ryan 1976).   In  addition, slurry
walls tend to retain  sufficient moisture  to  remain  somewhat  plastic.  This is
due to the fact that  some  portion of their  structure  is located below the
water table.  Stress  and strain  forces  that  change  subsurface pressures  would
merely cause the wall material to flow, filling any cracks that might have
otherwise developed  (SCS 1981).  In  the rare case where lesions form  due to
excessive pressures,  grout, of some  type, can be used  to  seal the openings.

     Despite the fact that loading pressures are not generally  a major
concern, the top of a wall should be covered with some  type  of  vegetation  or
capping material to prevent application of concentrated loads (Ryan 1977).
The cover or cap can  also  serve to reduce surface infiltration  and control
runoff and erosion around  a wall particularly if the wall  is  located  along a
steep slope or where  precipitation is normally high.  The  degree  to which  the
wall cover should be maintained depends on the site location, i.e., whether
                                     6-7

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the area is heavily trafficked, and on the physical and chemical nature of the
contaminants.

     The pressure exerted against the outer wall face by a large hydraulic
head can be another cause for gradual wall deterioration.  To counter this
force, groundwater pumping can be used and is quite effective in diminishing
potentially destructive pressures (Figure 6-1).


6.3  Wall Restoration


     The need for wall restoration will arise due to reasons identical to
those that necessitate wall maintenance.  Wall failure can be due to:

     •  Chemical reaction processes between the wall and contaminant

     •  Stress/strain forces causing structural failure

     •  Improper design and/or construction methods.

It will be re-emphasized at the beginning of this discussion that in most
cases, wall failure is due to poor design and construction specifications or
lack of supervision during installation.  Many problems can be avoided
entirely with the proper knowledge and the ability  to utilize it.

     A breach in a wall caused by chemical attack usually originates in one
small area of the wall.  The cause for deterioration can be due  to  one of two
factors:  (1) there exists an area of weakness in the wall, such as the type
produced by inadequate mixing of the backfill material during construction or
(2) the contaminant concentration is greatest at one location, e.g., a
floating solvent layer present in the groundwater column.  In either case, the
bentonite becomes dehydrated in one portion of the  wall which causes an
increase in porosity, as described in Section 2.  These  can result  in a piping
failure and an eventual breach in the wall (Figure  6-2).  In the case where
the cause for the breach is the nature of the contaminant and the wall
material has the permeability  specified  in the design requirements, there  is
little that can be done to permanently restore the  wall.  A slurry  wall is
probably not the proper solution for that particular problem and a  revision of
the engineered solution should be required.

     On the other hand, if a breach is due to a hole in  the wall and the hole
can be located with some accuracy, two restorative  possibilities exist:   (l)  a
synthetic liner can be placed  along one  side of the wall  and  (2) the breached
area can be  re-excavated and re-backfilled.  There  is one  stipulation  that
must be made concerning the second option.   In the  case  of a  soil-bentonite
wall, the soil-bentonite mixture tends to  slide into any re-excavation,
requiring that a long  section  of the trench  be dug  out  and rebuilt  (Ryan
1977).  Cement-bentonite walls, however,  are easily re-excavated by sections.
Failure of a cement-bentonite  wall would actually  stabilize  the  surrounding
soil, making it easy to excavate that  section  of  the  trench  (Ryan  1977).   In
addition, new cement-bentonite slurry  added  to the  breached  section seals  the
wall  to pre-existing segments  (Ryan  1977).


                                     6-8

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                              Figure 6-1.
            Groundwater Pumping to Reduce Hydraulic
                   Head Pressure on a Slurry Wall
                                    Extraction Wells
               Wall
*"*T»"T**""^»»"**/*-**it»" V,**"*"• !**-"*.*- *^
-.*.**.-* -*-*«»* V« -" -*** ••*,•*-**V **
                                6-9

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     Wall failures related to physical stress/strain  forces do not  usually
result in a breach.  Instead, physical stresses can cause cracking, which then
allows leachate seepage through the wall.  As mentioned  in the previous  sub-
section, this type of failure rarely occurs (Ryan 1977).  If it does, however,
there are three restorative actions that can be taken (1) grouting  of the
cracks, (2) the re-excavation and re-backfilling of the wall (if  the wall
material consists of cement-bentonite), or (3) placement of a synthetic  liner.

     The third type of failure is not a failure of a  wall, but failure to
properly construct a wall.  This is due to either inadequate excavation  and
keying into the aquiclude, or poor backfill design and/or mixing.   The most
frequent result of not keying into the underlying aquiclude properly is  the
seepage of leachate under the wall.  This can be remedied by re-excavation and
re-backfilling, if the problem area can be located.   The restrictions for this
procedure are described above.  Wall failure due to permeability  higher  than
the design requirements is a problem that should never occur.  Proper con-
struction supervision and backfill design specifications will prevent this
type of failure.  Table 6-3 summarizes the available  restorative  methods for
various wall failure problems.
                                  TABLE 6-3.
                       POSSIBLE RESTORATIVE METHODS FOR
                         VARIOUS WALL FAILURE PROBLEMS
Mechanism for Wall
Failure
Resulting Problem
Possible Restorative
      Methods
Chemical reaction
  between contaminant
  and wall
Wall breach
   Re-excavation and
   re-backfill
   Second slurry wall
   installation
Stress and strain
  forces
Lesions or cracking
•  Grouting
•  Re-excavation
   and re-backfill
Improper design and
 installation practices
Low wall permeability
  —> contaminant
  penetration rate high

Inadequate key-in
  —> underseepage
   Re-excavation and
   re-backfill
                                                        Grout key-in
                                     6-10

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                  Figure 6-2.
Wall Breach Due to Localized Chemical Attack
     Wall
 Surface


-  Water Level

  Solvent Layer
                    6-11

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6.4  Summary


     The state-of-the-art of slurry wall use  for  pollution  control,  and  of
hazardous waste site remediation, in general is  such  that  few if  any  remedial
measures can be assured of long term effectiveness without  some  degree of
monitoring and maintenance.  Such programs should be planned in  advance  of
wall installation and continue through the design life  of the wall.   A
monitoring program should be tailored to each specific  site and  should be able
to detect significant changes in the wall's ability  to  serve its designed
purpose.  Although slurry walls require little maintenance,  a program should
be established to ensure the wall is not damaged  by  surface activity. If
portions of a slurry wall are damaged or found  to be incapable of serving
their intended role, they may have to be restored by reexcavation and
reinstallation.
                                      6-12

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                                   SECTION 7

                              MAJOR COST ELEMENTS
7.1  Introduction
     The objective of this section is to present unit costs for activities and
items associated with slurry cut-off wall construction.  These costs may be
used to prepare preliminary estimates for trench construction for comparison
with alternative remedial measures at waste disposal sites.  They can also be
used to examine engineering cost estimates provided by contractors.  Slurry
trench construction is a specialized field of expertise, and the expense of
installing a wall is highly dependent upon site conditions.  Because of the
dependence on factors which vary between sites, cost items presented herein
should be used to develop costs for comparison purposes only.  Qualified
contractors experienced in this field should be contacted to provide more
complete, detailed estimates for specific cut-off wall testing, design, and
installation.

     It should be noted that the costs presented here are examples only.  Many
site-specific factors, which could have significant impact on wall costs are
not addressed here.  Health and safety programs for protecting workers in a
contaminated environment, for example, can more than double the time involved
in on-site work.  Additional information on the costs of working in a
hazardous environment can be found in U.S. EPA (1983).  These costs, and
regional price differences must be considered in evaluating overall wall
costs.

     In developing unit costs, information presented in other sections of this
report was used to develop specifications for material and equipment.  These
sections were also used to outline construction activities carried out during
wall installation.  This resulted in a list of items associated with cut-off
wall construction.  Industry representatives were asked to provide costs for
specific items.  This sometimes resulted in a range of costs for a specific
item, along with a number of factors affecting costs.  Industry representa-
tives were contacted whenever an item had specific application to slurry
trenches (e.g. bentonite manufacturers provided costs for several types of
bentonite).  Costs for equipment, materials or activities common to the
construction industry and not significantly affected by factors peculiar to
slurry trenches, were developed using standard sources.  These include Means
(1982), Dodge (1982), and NCE (1981).
                                     7-1

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     The unit costs presented include standard overhead and profit.  This does
not include additional subcontractors overhead and profit.  In several
instances, EPA (1982) provides estimates for construction at hazardous waste
sites.
     7.1.1  Developing Preliminary Cost Estimates


     There are several steps in developing cost estimates from unit costs.
They are:

     1.  Develop conceptual design including type and size of slurry wall.

     2.  Develop plan listing all activities to be conducted as part of the
         job.

     3.  Analyze activities, and determine type of equipment to be used and
         the size of the activity (e.g. number of cubic yards of earth
         excavated).

     4.  Look up unit price for activity and size of equipment.

     5.  Multiply size of activity (step 3) by unit cost (step 4).

     6.  Add costs for each activity.

     7.  Multiply total by contingency fee; usually between 5 and 20%, to
         account for unforeseen difficulties or problems.

     For this report, unit costs are divided into 6 major categories to
facilitate use:

     1.  Feasibility Testing
     2.  Construction Activities
     3.  Slurry Wall Installation
     4.  Maintenance and Monitoring
     5.  Materials
     6.  Equipment.

     In developing a plan for installing a slurry wall, activities can be
divided into four phases:

     1.  Feasibility testing, which includes soil testing and hydrogeologic
         testing for the site, but does not include compatibility testing of
         the wall with local groundwater.

     2.  Site preparation, which consists of all activities ancillary to wall
         installation.  These include site clearing, grading and preparation
         of work areas, excavation of slurry holding ponds and backfill
         preparation areas, and temporary alterations in the site such as road
         construction.


                                     7-2

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     3.   Wall installation, including mobilization and demobilization of
         equipment, labor, shipping and mixing of bentonite, backfill
         preparation, trench excavation and site cleanup.  Wall installation
         costs as provided by contractors are a function of the size and type
         of wal1.

     4.   Site clean-up, including re-grading, re-seeding and security.

     Once this plan is complete, unit costs presented in this section can be
used to develop total estimated costs for the slurry wall installation.

     Cost estimates for associated remedial actions as discussed in
Section 2.4 are not provided in this report.  Assistance in developing costs
for these items can be found in the EPA (1982),
          7.1.1.1  Cost Estimation Example


     An example of the cost estimation process is provided below.

          Based upon preliminary information, a  slurry wall appears
     feasible as a remedial action at a given site.  It is thought that
     the wall must be at least 50 feet deep  to key  into a clay  layer,  and
     that it must be between 700 and 800 feet long.  Local materials will
     be used as a source of fines in the backfill.  Access to the  site
     will be difficult, as no road leads directly to the work area.  The
     nearest access is 1200 feet from the site.  There are few  large
     trees in the work area; which is relatively flat and covered  with
     tall weeds and grasses^  After construction is complete, the  area
     will be graded and revegetated.


     Using this description, a preliminary estimate of costs can be made.
First, a list of activities can be developed.  This list includes:

     •  Feasibility testing

     •  Temporary road construction

     •  Site clearing and preparation

     •  Slurry wall excavation and completion

     •  Site re-grading and revegetation.

     Costs for each activity are described below.


               a.  Feasibility Testing


     Testing is required to determine the continuity and depth  of  the  clay
layer to be keyed into, as well as to obtain data on the type of native

                                     7-3

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material to be used as backfill.  It is estimated that soil borings of between
60 and 70 feet depth be set 50 feet apart in a line along that of the
anticipated trench.  Specific tests to be conducted include:

     •  Sieve analysis, all locations, at 10 feet depth intervals
     •  Atterberg limits, all locations, at 10 feet depth intervals
     •  Permeability tests, all locations, depths of 20, 40, and 60 feet.

Costs are given in Table 7-1.


               b.  Temporary Road Construction


     The road must extend at least 1200 feet from the nearest access.
Vegetation and trees less then 6-inch diameter must be cleared and a gravel
base laid.  It is estimated that the road must be 40 feet wide to accoraodate
heavy equipment.  Costs are presented in Table 7-2.


               c.  Site Clearing and Preparation
     Brush and grass must be cleared to provide working space.  An estimated
10 acres must be cleared, and approximately 3 acres must be regraded to serve
as a backfill preparation and slurry mixing and storage area.  Costs are given
in Table 7-3.
               d.  Slurry Wall Excavation and Installation


     Costs for slurry wall excavation and completion includes all activities
associated with wall installation.  This includes such items as:

     •  Backhoes, dozers, and trucks, including mobilization/demobilization

     •  Bentonite and water
     •  Slurry mixing and preparation including mixers and hoses

     •  Backfill preparation and installation
     •  Site clean-up.

     Costs are derived based upon discussion with industry representatives and
published data.  Cost ranges for some slurry wall installation are shown in
Table 7-4.
                                     7-4

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                                     TABLE 7-1.

               ESTIMATED COSTS FOR FEASIBILITY TESTING - EXAMPLE SITE
Activity
        Costs
    SOIL BORINGS

    14 Sites (700 ft./50 ft. Intervals) x 60 ft. x
      $7.80/ft. - 8.89/ft
    16 Sites (800 ft./50 ft. Intervals) x 60 ft. x
      $7.80/ft. - j8.89/ft

    SOIL TESTS

    Sieve Analysis - 6/site x 14 sites x $40.00 - $70.00
    Sieve Analysis - 6/site x 16 sites x $40.00 - $70.00

    Atterberg Limits - 6/site x 14 sites x $25.00 - $50.00
    Atterberg Limits - 6/site x 16 sites x $25.00 - $50.00

    Split Spoon - 6/site x 14 sites x $15.00
    Split Spoon - 6/site x 16 sites x $15.00

    Permeability Tests - 3/site x 14 sites x $50.00
    Permeability Tests - 3/site x 16 sites x $50.00
                                                                Low
                                                              Estimate
               High
             Estimate
$ 6,552.00  $ 7,468.00

$ 7,488.00  $ 8,534.04
$ 3,360.00  $ 5,880.00
$ 3,840.00  $ 6,700.00

$ 2,100.00  $ 4,200.00
$ 2,400.00  $ 4,800.00

$ 1,250.00
$ 1,440.00

$ 2,100.00
  2,200.00  $ 2,200.00

$15,362.00  $17,368.00
Reference:  Means 1982; Dodge 1982;  and Smith 1982.
                                     7-5

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                                     TABLE 7-2.

           ESTIMATED COSTS FOR TEMPORARY ROAD CONSTRUCTION - EXAMPLE SITE
Activity                                                             Cost
1.  CLEAR AND GRUB
         1200 ft. x 40 ft. x sq.yd./9sq.ft. x $.26/sq.yd.         $ 1,386.00

2.  TEMPORARY ROADWAY - 4" GRAVEL FILL - NO SURFACING
         1200 ft. x 40 ft. x sq.yd./9sq.ft. x $2.91/sq.yd.        $15,520.00

                                                                  $16,906.00
Reference:  Means 1982, and Dodge 1982.
                                  TABLE 7-3.

       ESTIMATED COSTS FOR SITE CLEARING AND PREPARATION - EXAMPLE SITE
Activity                                                               Cost
 1.  CLEAR AND GRUB WITH DOZER
         10 acres x 4840 sq. yds./acre x $.21/sq.yd.                 $10,164.00

 2.  REGRADE AVERAGE 2 FT.  75 H.P. WITH DOZER
         3 acres x 43,560  sq.ft./acre x 2  ft. x
           cu.yds./270 ft.  x $211/cu.yd.                             $20,424.00

                                                                     $30,588.00
 Reference:  Means  1982,  Dodge  1982.


                                      7-6

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                                  TABLE 7-4.

          ESTIMATED COSTS FOR SLURRY WALL INSTALLATION - EXAMPLE SITE
Activity                                                       Cost
1.  SLURRY WALL INSTALLATION
     SOFT TO MEDIUM SOIL
     DEPTH:  60 FT.
     SOIL BENTONITE BACKFILL
         700 ft. x 60 ft. x $4.00 - $8.00/sq.ft.    $168,000.00 - $336,000.00
         800 ft. x 60 ft. x $4.00 - $8.00/sq.ft.    $192,000.00 - $384,000.00
Reference:  Ressi de Cervia 1979.
                                     7-7

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               e.  Site Re-grading and Revegation


     After the wall is complete, the site must be re-graded and revegetated
Typical costs are given in Table 7-5.


               f.  Total Costs
     To arrive at total costs, all items are added.  A general contingency
factor is added to account for unforeseen problems.  This usually is between 5
percent to 20 percent, depending upon the type of work conducted.  A contin-
gency factor of 15 percent is usually more than sufficient.  Total costs are
given in Table 7-6.
7.2  Unit Costs
     Unit costs are presented under the following catagories:

     *  Feasibility testing

     •  Construction activities
     •  Slurry wall installation

     •  Maintenance and monitoring

     •  Materials

     •  Equipment.

     Unit costs are based upon the discussions already presented.  The
presentations here attempt to follow previous discussions as closely  as
possible.

     The use of unit costs to develop estimates is relatively  simple, but  the
result is still only an estimate.  In addition to the variations  inherent  in
estimating costs for such a site specific construction technique  as slurry
cut-off walls, unit prices can vary depending upon a variety of factors.
These include wage rates, labor efficiency, union regulations  and material
costs.  Other factors which may affect costs are weather, season  of year,
contractor management, and unforeseen difficulties.

     Unit costs presented in the following pages give a range  of  equipment
sizes and types which can accomplish the same activity.  Judgement must be
used in deciding what type of equipment may be used.  Unit  costs  are  given for
a wide variety of activities which may be required as part  of  a slurry cut-off
wall.  If a special activity is required and is not included in this  section,
one of the reference sources cited in this Section will probably  contain  the
necessary information.
                                      7-8

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                                   TABLE 7-5.

       ESTIMATED COSTS FOR SITE REGRADING AND REVEGETATING - EXAMPLE SITE
 Activity
 1.   REGRADE  AT AVERAGE 2 FT.  DEPTH WITH 75 H.P.  DOZER


 2.   REVEGETATE AND HYDROSEED,  INCLUDING FERTILIZER
          10  acres  x 4840 sq.yd.  x $.46/sq.yd.
Reference:  Means  1982,  Dodge  1982.
                                                                        Cost
                     $ 7,414.00-
                     $20,424.00
                      $22,264.00

                      $42,688.00
                                  TABLE  7-6.

                     ESTIMATED TOTAL COSTS - EXAMPLE  SITE
Activity
Feasibility Testing
Temporary Road Construction
Site Clearing and Preparation
Slurry Wall Excavation and Completion
Site Re-grading and Revegetation
         15% Contingency
          Cost
$ 17,210.00 - $ 19,480.00
       $16,900.00
       $30,588.00
$192,000.00 - $384,000.00
       $42,688.00	

$299,386.00 - $493,656.00

$ 44,907.00 - $ 74,048.00

$344,294.00 - $567,704.00
                                     7-9

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     7.2.1  Feasibility Testing
     To determine the feasibility of using a slurry cut off wall at a
particular site, three types of tests are conducted.  They are:

     •  Geologic and soils tests

     •  Hydrologic tests

     •  Slurry wall tests.

     The first two catagories provide a characterization of the site while the
last determines the compatibility of the technique with specific site condi-
tions, most notably the effect of the constituents present in  the local^
groundwater upon the slurry cut off wall.  In general, feasibility testing for
a slurry wall can run between 8 to 18 percent of costs (JRB 1979).


          7.2.1.1  Geologic and Soils Testing


     Geologic and soils testing is accomplished using  a drill  rig to extract
samples from various depths.  Any type of drill rig may be used, but one of
the more common  type makes  use of hollow  stem augers to penetrate the  sub-
surface and withdraw samples.  Costs presented here assume the use of  hollow
stem augers.

     Factors which  affect  the cost of geologic and  soils  testing  include:  the
number and type  of  samples,  the depth to  which samples are taken, mobilization
and demobilization  of  equipment, weather  conditions, and  the  presence  of
contamination which may require careful handling  techniques and special equip-
ment.  Based on the presence of contamination, cuttings material^brought  to
the surface by  the  advance of  the auger may  have  to be disposed in  secure
landfills.  Drilling  in contaminated areas can  significantly  affect  the rate
of  sampling as  well as  the overall cost.

      It  is possible that  a good deal of  information is already available  on
many  of  the hazardous  waste sites where  slurry  cut-off walls  are^being
considered.  However,  it  will  still  be  necessary  to conduct  special  testing  to
determine  the  location and extent of the  less  permeable  layer to^be  keyed
into,  and  to  fully  characterize  the  content  of  the overburden which will  be
excavated.  Overburden characterization is  especially  important if native
material  is  to  be used as a source  of fines  for the backfill.  In this
instance,  test  points  relatively  close  together,  both  in^the  horizontal and
vertical  sense, may be necessary.   Where a cement-bentonite backfill is
considered,  soil testing  can be  kept to a minimum but  cannot  be discarded.  It
is  still  important  to know the characteristics  of the key-in  layer,  and^
 information  on the  overburden could prove useful at a later date if additional
remedial  measures are considered.

      In general, test points of between 50 and 150 feet should provide more
 than sufficient information to characterize the subsurface material.  The test
                                      7-10

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borings should extend at least several feet into the impermeable layer to
confirm its suitability.  Costs for geologic and soils tests are given in
Table 7-7.


          7.2.1.2  Hydrologic Testing


     Hydrologic testing is designed to determine the characteristics of
groundwater quality and flow at a site.  Some hydrologic tests involve
altering the condition of the aquifer and measuring the response to the
change.  Others merely monitor the existing conditions.  In any event, it  is
necessary to install wells to conduct these tests.

     Factors which affect*hydrologic  tests are  almost  identical to those which
affect soils tests.  Mobilization and demobilization,  weather  conditions,  type
and  location of sample points and the presence  of contamination all affect the
cost of hydrologic testing.

     Many hazardous waste sites have  been  studied to a degree  that very good
characterizations of the hydrology of the  area  already exist.  Additional
hydrologic  testing may not be required  at very  many sites.  Where more
information is required, existing monitoring wells may be  used to reduce
costs.  Costs  for conducting hydrologic  tests  are given  in Table 7-8.


          7.2.1.3  Backfill Testing


     Tests  conducted to determine probable  performance characteristics  of  a
planned cut-off wall are  important.   Tests  can be carried  out  by one  of
several contractors who specialize  in slurry wall installation.

     There  are two types of  tests carried  out  which are  used  to determine  wall
characteristics:

     •  Compatibility  testing

     •  Permeability testing.

     These  tests determine  the  optimum  mix of  backfill materials  to  maximize
wall strength  and stability  and minimize wall  permeability.   Usually,  samples
of soil and groundwater are  taken  from the site and  used for  the  tests.   These
can be  gathered as part of  the  soil  and hydrologic  testing programs.   The
tests  are  then run using  these  native materials.  Ranges of costs  as provided
by a number of contractors  are  provided in Table 7-9.
                                      7-11

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                                  TABLE 7-7.

               EXAMPLE UNIT COSTS FOR GEOLOGIC AND SOILS TESTING
Activity
 Cost
Soil Borings

     Mobilization and Demobilization
          over 100 miles, additional per mile

     Auger Holes, 2.5" diameter
                    4" diameter

     Cased Borings, 2.5" diameter
                      4" diameter

     Split Spoon Samples, 2 foot drive

Soil Testings
$110.00
$  1.00/Mile

$  6.70/LF - 8.89/LF
$  7.80/LF

$  9.45/L.F. - 11.41/LF
S 16.15/L.F.

$ 15.00 - $50.00 each
Atterberg Limits, Liquid and Plastic Limits
Hydrometer Analysis and Specific Gravity
Sieve Analysis - Washed
- Unwashed
Moisture Content
Permeability, Variable or Constant Head
Proctor Compaction, 4" Standard Mold
$ 25.00
$ 50.00
$ 23.00
$ 40.00
$ 7.00
$ 50.00
$ 80.00
- $90.00

- $70.00
- $15.00

- $95.00
each

each
each


Reference:  Means 1982, Dodge 1982, Smith 1982
                                     7-12

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                                  TABLE 7-8.

                   EXAMPLE UNIT COSTS FOR HYDROLOGIC TESTING
               Activity
                                   Cost
Well Installation

     1.  Boring and well installation, without casing
               2.5" auger
               4" auger
               6" auger
     2.  Casing
               2"
 1
*1
               4" pvc.
               2" steel
               4" steel

     3.  Well Screens  .010" Slot, 10' length
               2" pvc.
               4" pvc.
               2" steel, 5 foot length

               4" steel, 5 foot length
     4.  Submersible pump,.5 gallons/minute
           at 180  ft. lift
                            $  7.23  - $  9.00/foot
                            $11.50  - $14.40/foot
                            $17.34  - $21.60/foot
                            $ 3.00/foot
                            $ 5.00/foot
                              4.50-5.50/foot
                              7.00-9.00/foot
                            $  6.47/foot
                            $ 18.98/foot
                            $144.80 ea. + 26.OO/
                              additional foot
                            $238.70 ea. + 41.10/
                              additional foot
                            $750.00 each
Hydrologic Tests

     5.  Water Quality Tests
           and analysis

     6.  Pump Tests

     7.  Slug Tests
- Includes sampling
                            highly variable
                            depending upon site-
                            specific conditions
References:   (1) JRB 1979,  (2) Smith  1982.
                                      7-13

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                                  TABLE 7-9.
                     EXAMPLE COSTS FOR SLURRY WALL TESTING
         ACTIVITY                            COST
1.  Compatibility tests               $800.00-$!,200.00 each test
2.  Permeability tests                $800.00-$!,200.00 each test


Reference:  Various industry sources.


     7.2.2  Construction Activities

     Construction activities include all activities conducted which are not
directly related to slurry wall installation.  Therefore, such items as slurry
preparation, mixing and introduction into the trench; backfill preparation and
placement; and slurry disposal are not covered in this section.  These items
are covered in a following section.
     Costs for the following activities are included in this section:
     •  Site clearing
     •  Excavation
     •  Backfill (excluding slurry trench backfill)
     •  Borrow
     •  Compaction
     •  Grading
     •  Hauling
     •  Mobilization and Demobilization
     •  Site Dewatering.
     Costs for these activities are shown in Tables 7-10 through 7-18.

          7.2.2.1  Site Clearing
     Slurry wall installation is made easier if a working area is cleared of
trees, shrubs and bushes.  In urban areas, or where other factors may prevent
                                     7-14

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the removal of obstacles, the cost of slurry cut-off wall installation
increases dramatically.  Slurry wall installation or implementation of addi-
tional remedial actions is made easier if a working area can be prepared by
clearing the site of obstructive objects.  In rural areas the predominant
obstack is vegetation, ie, trees, shrubs, bushes, and site clearing can
usually be undertaken with minimal difficulty and at relatively low cost.  In
urban areas, however, where the obstacles are power lines, underground water
lines etc., site clearing is often difficult and as a result slurry cut-off
wall installation and any additional site work increases dramatically.  Costs
for site clearning are shown in Table 7-10.  Costs for clearing a site
containing wastes should not be significantly greater than normal costs,
however, if decontamination of personnel and equipment is required, costs may
rise significantly.
          7.2.2.2  Excavation
     Excavation may be required to prepare the work area.  Slurry may be
stored in excavated ponds to insure complete hydration of bentonite and to
provide a sufficient reserve of slurry.  In addition, "benches" may need to be
cut into hillsides to accomodate excavation equipment.  The type of equipment
chosen is dependent upon the size of the job, the type of excavation and site
conditions.

     Costs for excavation are given in Table 7-11.  Costs will be affected by
the type of material being exhumed, and also by the presence of contaminants.
Contaminated material must be properly disposed, adding to overall costs.  In
addition, decontamination of equipment and health and safety precautions will
slow work, and increase costs.  Rental costs for equipment are presented under
the equipment discussion.  Unit costs provided in Table 7-11 include rental of
equipment.
          7.2.2.3  Backfilling


     Backfilling is required to "fill in" areas to insure level grade for
excavation equipment.  In slurry trench construction, below grade depressions
may need to be filled and compacted to create the level grade.  Backfill may
also be required to fill in slurry ponds after the job is complete.

     Costs for backfilling are presented in Table 7-12.  The presence of
contaminants may influence costs, but not significantly if clean fill is used,
Health and safety precautions and decontamination of equipment may slow the
rate of backfilling operations.
                                     7-15

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                                  TABLE 7-10.
                     EXAMPLE UNIT COSTS FOR SITE CLEARING
                    ACTIVITY

Clear and Grub - Trees

     Light trees to 6" diam., cut and chip

       grub stumps

     Medium trees to 10" diam., cut and chip

       grub stumps


     Heavy trees to 16" diam., cut and chip

       grub stumps


     Trees over 16" diam., using chain saws and chipper

       For machine load, 2 miles haul to dump add


Clearing-Brush

     With brush saw and rake

       by hand

     With dozer, ball and chain, light clearing
       medium clearing
UNIT COSTS ($)
2,125/acre -
  22.00 each
565.06 - 825/acre

2,450/acre -
  31.00 each
1,100/acre -
1130/acre

2,850/acre -
  56.00 each
1,375/acre -
  2260.00/acre

$100.00 ea. -
  128.00 each
$18.00 - 38.00
  each
 ,27/square yard
   (S.Y.)
 ,55/S.Y.

 ,27/S.Y.
 ,31/S.Y.
Reference:  Means 1982, Dodge 1982.
                                     7-16

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                                  TABLE 7-11.
                       EXAMPLE UNIT COSTS FOR EXCAVATION

ASSUMPTIONS:
Medium earth piled or truck loaded
No trucks or haul added
1.

2.

3.

4.

5.

6.



7.

EQUIPMENT AND CAPACITY
Backhoe, hydraulic, crawler mounted
1.0 Cubic Yard
1.5 Cubic Yard
2.0 Cubic Yard
3.5 Cubic Yard
Backhoe, wheel mounted
.5 Cubic Yard
.75 Cubic Yard
Clamshell
.5 Cubic Yard
1.0 Cubic Yard
75 H.P. Dozer, 50' haul
300 H.P. dozer, 50' haul
75 H.P. dozer, 150' haul
300 H.P. dozer, 150' haul
0.75 Cubic Yard Dragline
1.5 Cubic Yard Dragline
Front end loader, track mounted.
1.5 Cubic Yard
2.5 Cubic Yard
3.5 Cubic Yard
4.5 Cubic Yard
Wheel mounted
0.75 Cubic Yard
1.5 Cubic Yard
5.0 Cubic Yard
Shovel
0.5 Cubic Yard
0.75 Cubic Yard
1.5 Cubic Yard
UNIT COST (per

$2.17
$1.96
$1.93
$1.48

$3.76
$2.62

$4.34
$2.93
$1.17
$ .57
$1.43
$1.08
$2.47
$1.76

$ .98
$ .91
$ .72
$ .88

$ .99
$ .84
$ .73

$2.95
$1.66
$1.25
Cubic Yard)

- 2.71
- 2.19
-1.98
- 1.79

- 3.95
- 2.92

- 4.42
- 3.39
- 1.43
- .98
-2.34
- 1.48



- 1.05
- 1.26
- .82
- .99

- 1.30
- .89

- 1.88
-1.39

For soft soil or sand, deduct 15% for heavy soil or clay add 60%.
Reference:  Means 1982, Dodge 1982.
                                      7-17

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                                  TABLE  7-12.
                        EXAMPLE UNIT COSTS FOR BACKFILL
                       ACTIVITY
        UNIT COST
(Dollars Per Cubic Yard)
1.

2.



3.



Backfill by hand, no compaction, light soil
heavy soil
Compaction in 6" layers, hand tamp
roller compaction
air tamp
vibrating plate tamp
Compaction in 12" layers, hand tamp
roller compaction
air tamp
vibrating plate tamp
$8.83 - $11.10
$12.95
7.55 -
3.90 -
5.70
1.55 -
4.56
2.81
4.10
2.63

11.02
4.67

3.76




4.  Dozer backfill, bulk, up to 300"  haul
               Compaction air tamped
                            - 6" - 12" lifts vibrating roller
                            - Sheepsfoot roller

5.  Dozer backfilling, trench, up to  300' haul
               Compaction air tamped
                            - 6" - 12" lifts vibrating roller
                            - Sheepsfoot roller
            0.85 -  1.04
            4.81 Additional
            1.77 Additional
            1.92 Additional

            1.09
            4.92 Additional
            2.11 Additional
            2.39 Additional
REFERENCE:  Means 1982, Dodge 1982.
                                     7-18

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          7.2.2.4  Borrow
     Borrow is material taken from a nearby source to be used as a fill
material on-site.  Borrow can be used as a backfill, and as a source of
material to construct berms, dikes, levees, or ramps.  Borrow can also serve
as a source of fines used in the preparation of cut-off trench backfill.

     Cost for borrow are given in Table 7-13.  These costs assume that a
nearby source of material is available.  If not, costs could rise
substantially.
          7.2.2.5  Compaction
     Backfill or borrow used  for haul  roads,  should be compacted  to  impart
some strength to the material.  This is especially important  if heavy
equipment  is going  to be moving over areas  of loose or uncompacted material.
Unless backfill or  borrow  is  used  at a site,  compaction may not be necessary
Costs  for  compaction are given in  Table 7-14.
           7.2.2.6  Grading
      Slurry  trench  construction requires  a relatively  flat  working  surface.
 In  areas  of  sloping or  uneven  terrain,  graders may be  used  to  level the
 working  area.

      There  are  two  types  of  graders,  self-propelled and those  towed by a dozer
 or  some  other suitable  piece of machinery.  Either can be used,  but large,
 motorized graders are used primarily  for  larger  jobs.   Costs  for various
 graders  are  presented in  Table 7-15.
           7.2.2.7   Hauling
      Hauling material  to the worksite may be a major cost factor if sources of
material  are not  located nearby.   Hauling may be required to bring borrow
material  to a site.  Hauling costs presented in Table 7-16 do not give cost
 for  rail  or truck transportation  of material for great distances (i.e., the
 shipping  of large quantities of bentonite by rail).   Manufacturers should be
 contacted to provide exact  transport costs for these types of material.

      The  selection of  equipment to haul material is  dependent upon several
 factors.   Of primary importance is the quantity of material to be hauled.  For
 larger quantities, a larger capacity trailer should  be used as they are
 usually more efficient.   Limiting the type of equipment used are the physical
 constraints of the roads over which material will be hauled.  Back roads or
                                      7-19

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                                  TABLE 7-13.
                         EXAMPLE UNIT COSTS FOR BORROW
Assumptions:
     Buy and load at pit, haul 2 miles to site, place and spread with 180
     H.P. dozer with no compaction.
         MATERIAL
  UNIT COST
     1.  Bank run gravel
     2.  Common borrow
     3.  Crushed stone 1.5"
         Crushed stone 3/4"
         Crushed stone 1/2"
         Crushed stone 3/8"
     4.  Sand-washed-
             Dead or bank sand
     5.  Select structure fill
     6.  Screened Loam
     7.  For 5 mile haul, Add
 $6 - 6.25/Cubic Yard
 S4.63/C.Y.
 $6.65 - $10.70/C.Y.
 $6.65 - $10.55/C.Y.
$11.88/C.Y.
$12.60/C.Y.
$ 6.26 - $10.15/C.Y.
$ 8.30/C.Y.
$ 6.87 - $8.35
$ 8.80 - $12.35/C.Y.
 $1.40 - $2.30/C.Y.
Reference:  Means 1982, Dodge 1982.
                                  TABLE 7-14.
                       EXAMPLE UNIT COSTS FOR COMPACTION
                  ACTIVITY

1.  Compaction,  Rolling with road roller, 5 tons
                                          10 tons
2.  Sheepsfoot or wobbly wheel roller, 8" lifts
       for select fill
3.  Terraprobe, deep sand
       Mobilization-Demobilization
4.  Vibratory Plate, 8" Lifts, select fill
           UNIT COST

           $45.00/hr
           $55.00/hr
           $ 1.56/C.Y.
           $ 1.31/C.Y.
           $.92 - 1.31/C.Y.
           $4,650.00 - $6,100.00
           SI.55 - $2.56/C.Y.
Reference:  Means 1982, Dodge 1982.
                                     7-20

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                                  TABLE 7-15.

                        EXAMPLE UNIT COSTS FOR GRADING
Assumptions:
     Site excavation and fill, not including mobilization and demobilization
     or compaction
             Activity
Unit Cost (Dollars/Cubic Yard)
1. Dozer 300 foot haul-75 H.P.
* -300 H.P.
2. Scraper, towed, 7 C.Y.-300'
-10001
10 C.Y.-3001
1000'
3. Self propelled scraper, 15 C

25 C

4. Dozer with ripper- 200 H.P.
- 300 H.P.


haul
haul
haul
haul
.Y. 1000'
2000'
.Y. 10001
2000 f








haul
haul
haul
haul


1.06 -
1.08 -
3.53
7.75
1.88 -
1.96 -
1.95
2.64
1.02
1.27
0.49
0.99
2.92
2.11


2.33
3.96







Reference:  Means 1982, Dodge  1982.
                                  TABLE 7-16.

                        EXAMPLE UNIT COSTS FOR HAULING

Activity

1. 6 C.Y. Dump truck, 1 mile round trip
2 mile round trip
3 mile round trip
4 mile round trip
2. 12 C.Y. Dump truck 1 mile round trip
2 mile round trip
3 mile round trip
4 mile round trip
3. 16.5 C.Y, Dump truck 1 mile round trip
2 mile round trip
3 mile round trip
4 mile round trip
4. 20 C.Y. Dump truck 1 mile round trip
2 mile round trip
3 mile round trip
4 mile round trip
5. Hauling in medium traffic, add 20%
Hauling in heavy traffic, add 30%
Unit Cost
(Dollars/Cubic
2.03 -
2.64 -
3.42 -
4.28
1.71 -
1.96 -
2.21 -
2.65 -
1.50
1.85
2.17
2.42
1.31
1.64
2.94
2.19



Yard)
2.28
2.91
3.64

2.00
2.11
2.47
2.96











 Reference:  Means  1982,  Dodge  1982.
                                      7-21

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dirt roads may not stand up to larger trailers.  In addition, weight
restriction on roadways and bridges will limit the size of vehicle.
          7.2.2.8  Mobilization and Demobilization
     Mobilization and demobilization refers to the transportation of vehicles
and equipment to and from the job site.  These are primarily a factor of the
distance from the equipment storage site to the job location.  Mobilization
and demobilization costs for specialized, heavy equipment may be very high.
Average costs for representative pieces of equipment are shown in Table 7-17.
These figures assume a local source of equipment.
          7.2.2.9  Site Dewatering
     Dewatering may be required at sites where excavations intersect the water
table.  It is not anticipated that dewatering will be required during slurry
trench installation as little or no deep excavation is required other than
that of the trench.  Costs for dewatering systems are shown in Table 7-18.


     7.2.3  Completed Wall Costs


     Contractors have provided average costs for completed slurry cut-off wall
construction and installation.  These estimates may vary widely however, based
upon a number of site-specific factors.  Some of these factors are:

     •  Distance bentonite must be transported.

     •  Presence of contamination or high salt content in groundwater
        requiring special bentonite and excavation procedures.

     •  Type of overburden being excavated.

     •  Depth of excavation.

     •  Presence of physical  constraints upon working area (i.e., buildings or
        other structures which must be worked around).

     •  Suitability of native materials for use as backfill constituents.

     •  Type of backfill (either cement or soil-bentonite).

     Ressi di Cervia (1980) developed a chart (Table 7-19) which related
cut-off wall construction costs to type of backfill used, depth of excavation
and soil type present.  Costs are given in terms of square foot of wall since
the width of the excavation is a factor of the excavation equipment.  Although
                                     7-22

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                                  TABLE  7-17.
            EXAMPLE UNIT COSTS FOR MOBILIZATION AND DEMOBILIZATION
                Equipment
    Cost
1. Dozer 105 H.P.
300 H.P.
2. Scraper-towed (include Tractor) 6

3. Self-propelled scraper

4. Shovel, Backhoe or dragline

5. Tractor shovel or front end loader



C.Y.
10 C.Y.
15 C.Y.
24 C.Y.
3/4 C.Y.
1.5 C.Y.
1 C.Y.
2.25 C.Y.
$ 90.00
$125.00
$ 95.00
$130.00
$180.00
$290.00
$130.00
$190.00
$ 90.00
$125.00

Reference:  Means 1982, Dodge 1982.
                                  TABLE 7-18.
                       EXAMPLE COSTS FOR SITE DEWATERING
               De script ion

     1.  Wells - large

         dewatering excavation 10* - 201 deep, 2"
           steel casing
         submersible pump, 6", 1590 GPM

     2.  Wells - small

         dewatering excavation
            4" - 6" with casing
         submersibile 3"-300 GPM
                     4"-560 GPM

     3.  Wellpoints

         Complete installation, operation,
         equipment rental, full and removal
         of system with 2" wellpoints
         100 foot header 6" diameter
         200 foot header 6" diameter
         100 foot header 6" diameter
     cost
$5.00-22.00/Linear Foot
$1250.00/month
$12.95/Linear Foot
$300/month
$400/month
$24,500-$32,000/month
$25,000-$27,000/month
$31,000-$69,000/month
Reference:  Means 1982, Various Other Sources.

                                     7-23

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                                   TABLE 7-19.
                      RELATION OF SLURRY CUT-OFF WALL COSTS
                          PER SQUARE FOOT AS A FUNCTION
                               OF MEDIUM AND DEPTH
                               Slurry Trench Prices    Unreinforced Slurry Wall
                                  in 1979 Dollars       Prices in 1979 Dollars
                             Soil Bentonite Backfill  Cement Bentonite Backfill
                              (Dollars/Square Foot)     (Dollars/Square Foot)
Depth Depth Depth
<_ 30 30-75 75-120
Feet Feet Feet
Soft to Medium Soil
N _< 40 2-4 4-8 8-10
Hard Soil
N 40 - 200 4-7 5-10 10-20
Occasional Boulders 4-8 5-8 8-25
Soft to Medium Rock
N >_ 200 Sandstone, Shale 6-12 10-20 20-50
Boulder Strata 15-25 15-25 50-80
Hard Rock
Granite, Gneiss, Schist* 	 	 	
Depth
£ 60
Feet
15-20
25-30
20-30
50-60
30-40
95-140
Depth
60-150
Feet
20-30
30-40
30-40
60-85
40-95
140-175
Depth
> 150
Feet
30-75
40-95
40-85
85-175
95-210
175-235

Notes:

      N is standard penetration value in number blows of the hammer per foot of
      penentration (ASTM D1586-67)

*Normal Penetration Only

           For Standard Reinforcement add $8.00 per sq. ft.
           For Construction in Urban Environment Add 25% to 50% of Price

Reference:  Ressi di Cervia 1980.
                                     7-24

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costs are given in 1979 dollars, contractors maintain that slurry trench costs
have remained stable because of increased experience and new technology.

     A breakdown of total cut-off wall costs according to several categories
is shown in Table 7-20.  As can be seen, costs for each element may vary
widely.

     Table 7-21 gives examples of costs for several walls as reported in the
literature or otherwise available.  A brief description of site characteris-
tics which may have affected costs is included.  This table also demonstrates
the wide variation in unit costs depending upon site specific factors.
          7.2.3.1  Monitoring
     Once a slurry cut-off wall has been  installed, monitoring should be
conducted to assure that the wall is performing as designed.  If the
monitoring program indicates that the wall  is not containing or isolating
contaminants, maintenance to restore the  integrity of  the wall should be
instituted.

     There are two types of monitoring  systems which are used to indicate  the
integrity of a cut-off walls; wall-stability monitoring and water quality
monitoring.  Effects on wall integrity  due  to ground movement is not
considered a major problem as both SB and CB walls are normally flexible
enough  to withstand typical deformation.  This type of monitoring is usually
important if construction activities place  a major load on the wall.  Since it
is not  expected  that slurry walls associated with hazardous wastes  sites will
be called upon to support major structures, costs are  not provided  for  this
type of monitoring.

     Water quality monitoring will be the most important indicator  of wall
performance:  the wall will either contain  and isolate waste materials  or
migration of constituents will continue.  Water quality monitoring  systems
usually consist  of multiple wells installed at suitable locations up and
downgradient of  a wall.  These walls can  be sampled and analyzed to determine
water quality.   In addition to groundwater monitoring, surface water sources
can also be sampled.  Finally, water levels obtained from piezometers can  be
used as an indicator of wall integrity.

     Table 7-22  presents estimated costs  for monitoring well and piezometer
installation.  Costs for sampling and analysis are highly variable  and  depend
upon the type of parameters analyzed, and therefore, have not been  included.
          7.2.3.2  Maintenance
     Maintenance of  a  slurry wall begins  immediately  after  installation.   The
wall should be capped  with a clay or other  capping material  to  reduce  surface
infiltration and control  erosion.   The  cap  should be  properly graded.
                                      7-25

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                                  TABLE 7-20.
                         BREAKDOWN OF COST CATAGORIES
                        FOR CUT-OFF TRENCH CONSTRUCTION*
                 Activity
                               of Total Costs
     Testing - Hydrologic, Geotechnical,
       and Lab Tests

     Equipment Mobilization

     Slurry Trench Excavation and
       Backfill
                                8% - 18%


                                8% - 18%

                               65% - 83%
* Assumes soil-bentonite backfill with moderate soil conditions and depth not
greater than 40 feet.

Referemce:  EPA 1982.
                                  TABLE 7-21.
          EXAMPLE RANGES OF UNIT COSTS FOR CUT-OFF WALL CONSTRUCTION
                       Unit Cost
                              Conditions
Site I.    (1982)

Site II.   (1981)

Site III.  (1982)

Site IV.  (unk)
$3/sq. ft.

27.00/sq. ft

$5/sq. ft.

$6/sq. ft.
50 ft. x 11,000 ft. SB Backfill

17 ft. x 700 ft. CB Backfill

52 x 3900 ft. SB Backfill

30 ft x 300 ft. SB Backfill
Reference:  Various Industry Sources,
                                     7-26

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                                  TABLE 7-22.
                      EXAMPLE UNIT COSTS FOR MONITORING
                       WELL AND PIEZOMETER INSTALLATION
1.   Monitoring well installation

     Boring  and well installation, without casing
     2.5" auger
     4" auger
     6" auger
     Casing
     2" PVC
     4" PVC
     2" Steel*
     4" Steel

     Screen .010" slot, threaded flush joint
     2" PVC
     4" PVC
     2" Steel , 5-foot length

     4" Steel2, 5-foot width
     Submersible pump, 5 GPM at 180 ft. lift

2.  Piezometer installation
     $ 7.23-9.00/foot
     $11.50-14.40/foot
     $17.34-21.60/foot
     $ 3.00/ft
     $ 5.00/ft
     $ 4.50-5.50/ft
     $ 7.00-9.00/ft
     $ 6.47/ft
     $18.98/ft
$144.80 ea. + 26.10/
       added ft
     238.70 ea. +  91.10/
       added ft

     $750.00/each
     Boring and installation (same as monitoring walls)
     Piezometers, 24" screen, polyethylene               $65.54 each
Reference:  (1)  JRB 1979, (2) Smith 1982.
                                     7-27

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     Other maintenance techniques include grouting, re-excavation of the
trench or installation of a synthetic liner along one side of the wall.  Costs
for maintenance operations are shown in Table 7-23.  Due to the technical
difficulties in installing a synthetic liner near a slurry trench, unit costs
could not be derived for this activity.


     7.2.4  Materials


     Materials essential for slurry cut-off wall construction includes

     •  Slurry consisting of a mixture of bentonite or suitable replacement
        and water

     •  Backfill consisting of a mixture of soil, bentonite and water and/or
        cement.

     In many instances, borrow may be required on-site to serve as a source of
fines or to be used'in support of other construction activities.  Costs are
also incurred for disposal of spoils.

     Supplies of bentonite can be obtained from a number of sources.  Each
vender has available a variety of bentonite types suitable for use in slurry
cut-off walls.  The costs for bentonite will be affected by the location of
the site as transportation is a major expense item.  Costs for bentonite as
well as other materials such as concrete, sand, borrow, rip-rap etc. are also
included in Table 7-24.
     7.2.5  Equipment


     Large construction projects like the installation of a slurry wall
require varied types of equipment.  Contractors usually provide much of this
equipment themselves, especially specialty items like a modified backhoe.  In
some instances, equipment rented locally may prove more cost effective than
shipping the same equipment for large distances.  To provide a means of
comparing equipment costs, the following tables present hourly operating costs
and daily and monthly rental rates for earthwork equipment (Table 7-25), con-
crete and mixing equipment (Table 7-26), and general equipment (Table 7-27).
No estimate of equipment requirements for a typical slurry wall are available
as each project is site-dependent.


7.3  Summary


     The development of costs for a slurry wall installation is an involved
process and is highly site specific.  This section has presented example costs
that may be used to generate estimated total costs.  Care must be taken in
applying these example costs to a specific site.  It is especially important


                                     7-28

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                                  TABLE  7-23.
           EXAMPLE UNIT  COSTS  FOR SLURRY WALL MAINTENANCE ACTIVITIES
      1.
      2.
      3.
       Activity

Grouting - soil stabilization with
phenolic resin
                                                         Unit Cost
                                                         $200.00-465.00/C.Y,
Re-excavation of soil bentonite backfill with
backhoe (Hydraulic crawler 1.5 C.Y. capacity)   $  1.96/C.Y.
re-excavation of cement-bentonite backfill      highly variable

Capping - buy, load, 2-mile haul, grade and spread
Borrow - select fill                            $  6.97 - 8.35/C.Y,
Borrow - topsoil                                $  5.70 - 9.05/C.Y,
Compaction                                      $0.92-$1.31/C.Y.
     4.  Revegetation - hydroseed
                                                $0.46 S.Y.
Reference:  Means  1982, Dodge 1982.
                                  TABLE  7-24.
                      EXAMPLE UNITS COSTS FOR MATERIALS
 1.  Bentonite
       Natural, "untreated"  sodium bentonite
         Bulk rail  (min 30 tons)
         Bulk truck (min 30  tons)
         Bag rail (min 21 tons)
         Bag truck  (min 21 tons)
                                             2
 2.  Cement, Portland, truckload, U.S. average
       Cement Portland, less than truckload U.S. average'
       Portland Cement trucked in Bulk, U.S. average
                           2
 3.  Borrow, bank run gravel
       common borrow
       crushed stone, 3/4"
       sand - washed
       select, structural fill
       screened loam
       topsoil
                                                   $42.00/ton
                                                   $43.00/ton
                                                   $50.00/ton
                                                   $51.00/ton

                                                   $ 4.62/Bag
                                                   $ 5.55/Bag
                                                   $ 3.57/1001bs.

                                                   $ 6.00-$6.25/C.Y.
                                                   $ 4.63/C.Y.
                                                   $ 6.65-$10.55/C.Y,
                                                   $ 6.26-$10.15/C.Y,
                                                   $ 6.87-$8.35/C.Y.
                                                   $ 8.80-$12.35/C.Y,
                                                   $ 9.05/C.Y.
Note:  Does not include transportation costs.

Reference:  (1) Various industry sources:  does not include transportation,
            (2) Means 1982, Dodge 1982.
                                     7-29

-------
                         TABLE 7-25.
EXAMPLE OPERATING AND RENTAL COSTS FOR EARTHWORKING EQUIPMENT
Hourly Operating Rent Rent
(Cost Without Operator) Cost Day Month
1.

2.





3.


4.




5.




6.

7.
8.





9.



Augers for truck/trailer mounting, ver-
tical drilling 4" to 36" diam. 101 travel
Backhoe diesel hydraulic, crawler mounted
5/8 C.Y. capacity
3/4 C.Y. capacity
1 C.Y. capacity
2 C.Y. capacity
3 1/2 C.Y. capacity
Backhoe loader, wheel type
40 to 45 H.P. 5/8 C.Y.
80 H.P, 1 1/4 C.Y.
Bucket, clamshell, all purpose
3/8 C.Y.
1/2 C.Y.
1 C.Y.
2 C.Y.
Bucket, dragline, medium duty
1/2 C.Y.
1 C.Y.
2 C.Y.
3 C.Y.
Compactor roller, 2 drum

Vibratory plate, gas, 13" plate, 1000 Ib blow
Grader, self propelled, 25,000 Ibs .

40,000 Ibs.

55,000 Ibs.

Roller, towed type, vibratory, 2 ton
Sheeps foot self propelled, 140 H.P.
Pneumatic tire, 12 ton


$0.56

$6.55
$9.40
$12.15
$23.70
$43.40

$4.23
$7.65

$0.38
$0.50
$0.69
$1.13

$0.32
$0.44
$0.63
$0.88
$2.12

$0.48
$10.60

$19.15

$25.00

$2.05
$9.95
$7.40


$73

$450
$495
$735
$1075
$1650

$295
$400

$30
$35
$45
$75

$21
$33
$47
$73
$70

$39
$325

$540

$845

$80
$285
$120


$645

$3100
$3500
$3925
$7850
$13,800

$1100
$2075

$270
$335
$415
$680

$180
$290
$425
$605
$735-
1500
$330
$3000-
3450
$4200-
4850
$5100-
7550
$700
$2750
$1100-
1500
                                                            (continued)
                              7-30

-------
                             TABLE  7-25.  (continued)
(Cost Without Operator)
10. Scrapers, towed 7 to 8 C.Y.
Self propelled 14 C.Y.
Self loading 22 C.Y.
11. Tractor, dozer, crawler 75 H.P.
105 H.P.
200 H.P.
300 H.P.
410 H.P.
700 H.P.
12. Loader crawler 1.5 C.Y. 80 H.P.
1.75 C.Y. 95 H.P.
2.25 C.Y. 130 H.P.
5 C.Y. 275 H.P.
13. Truck, dump, tandem, 12 ton payload
3 axle, 16 ton payload
Dump trailer only, 15.5C.Y.
Flatbed, single, 1.5 ton rating
3 ton rating
Off highway, rear dump 25 ton
35 ton
Hourly Operating Rent Rent
Cost Day Month
$2.45
$34.00
$46.00
$6.20
49.50
$17.20
$24.00
$34.50
$60.30
$9.35
$11.10
$14.50
$31.00
$9.85
$14.35
$3.47
$3.34
$3.83
$21.85
$30.25
$115
$1050
$1000
$375
$505
$765
$1025
$1250
$1950
$445
$475
$575
$1100
$325
$410
$73
$45
$56
$4760
$1025
$1025
$8800
$6675
$1850
$3525
$6950
$9000
$11,750
$19,250
$2550
$2925
$3950
$9850
$1625
$2150
$675
$415
$505
$6600
$9300

Reference:  Means 1982, Dodge 1982.
                                     7-31

-------
                                 TABLE  7-26.
     EXAMPLE  OPERATING AND  RENTAL  COSTS FOR CONCRETE  AND  MIXING EQUIPMENT

1.
2.
3.
4.
5.
6.
7.
8.

Bucket, concrete, lightweight 0.5. C.Y.
1 C.Y.
Conveyor, concrete, 10" wide, 26f long
Core driller, electric, 2.5 H.P. 1" - 8"
Grinder
Mixer, powered, mortar and concrete
Pump, concrete, truck mounted
4" line, 80' boom
5" line, 110* boom
Mud jack 47 cubic feet/hour
225 cubic feet/hour
Portable Concrete Batch Plant
Hourly Operating
Cost
$0.12
$0.12
$1.10
bit $0.56
$.82
$1.92
-
$0.99
$2.84
Rent
Day
$17
$20
$64
$39
$35
$26
$640
$450 -
$800
$20
$125
$1,500
Rent
Month
$125
$165
$505
$290
$305
$255
$4,750
$180
$1075
$15,500
Reference:  Means 1982, Dodge 1982.
                                     7-32

-------
                             TABLE 7-27.
EXAMPLE OPERATING AND RENTAL COSTS FOR GENERAL CONSTRUCTION EQUIPMENT

1. Air compressor, portable gas 60 cfm
160 cfm

diesel engine, rotary screw
250 cfm
360 cfm
600 cfm
2. Barricade barrels with flashers
3. Generator, electrical 1.5 kw to 3 kw
5 kw
10 kw
diesel 20 kw
100 kw
4. Hose, water suction with coupling 20' long
2" diameter
4" diameter
8" diameter
discharge hose with coupling, 50' long
2" diameter
4" diameter
8" diameter
5. Light towers, portable with generator
1000 watt
2000 watt
6. Pumps, centrifugal gas pump, 1.5" diameter
2" diameter
3"diameter
6"diameter
diaphragm, gas, single, 1.5" diameter
3 ' diameter
double 4" diameter
Trash, self-priming 4" diameter
7. Trailers, platform, flushdeck, 25 ton
40 ton
3 axle, 50 ton

Hourly Operating
Cost
$3.19
$3.87


$6.20
$9.30
$15.45
-
$0.48
$0.78
$1.85
$3.11
$7.73

-
-
. -

-
.
-

$1.10
$1.63
$0,39
$0.95
$0.95
$1.52
$0.41
$0.86
$1.05
$1.16
$0.93
$1.13
$2.14

Rent Rent
Day Month
$34
$48


$78
$100
$150
$.65
$20
$27
$45
$54
$180

$7
$12
$34

$7
$12
$40

$66
$94
$15
$20
$25
$75
$13
$28
$45
$55
$78
$115
$145

$290
$430-
840

$700
$880
$1325
$5.70
$180 *
$280
$450
$525
$1300

$45
$100
$255

$45
$90
$180

$540
$845
$125
$175
$210
$655
$115
$235
$400
$520
$715
$1025
$1290
(continued)
                                  7-33

-------
                            TABLE 7-27. (continued)
                                           Hourly Operating
                                                 Cost
                                                                  Rent   Rent
                                                                  Day   Month
 8. Water tank, engine-driven discharge, 5000 gallon $8.40
                                      10,000 gallon  $9.95
 9. Decontamination shower cost

10. Pipe, for excavation drainage
    (installation not included)
                                                                $225
                                                                $325
                                             $2,400.00 each
    PVC 13"lengths
    Vitrified clay
                               4"diameter
                               8" diameter

                              12" diameter

                              15" diameter

                               4" diameter

                               8" diameter

                              10" diameter
                              15" diameter
                              24" diameter
 $2.10 -
 $2.59/linear foot  —
 $5.20 -
  5.56/linear foot  —
$10.05
 11.98/linear foot  —
$15.25/linear foot  —
 $3.25 -
 $4.10/linear foot  —
 $4.85 -
 $7.20/linear foot  —
 $6.99 -
 $9.45/linear foot  —
$19.75/linear foot  —
3-6.98/linear foot  —
11. Security fence
    galvanized steel, 12 ga., 2" x 4" mesh with
    posts 5' o.c., 51 high
    12' high, prison grade

12. Snow fence on steel posts 4' high

13. Storage building, bulk, 180; diameter
                                               $3.25/linear foot  —
                                              $32.00/linear foot  —

                                               $3.36/linear foot  —

                                                       $20/s.f.
                                                         floor    —
14. Survey, conventional topographic
    aerial survey including ground control,
                  10 acres
                                                   $165.00-$1150/ —
                                                       acre (total)
                                                  $2200           —
                                                   /acre (total)
                                                    200-600/      —
                                                    acre (total)
                                                    100-2300
                                                    acre (total)
                                                     6700 + 70.00 —
                                                    /acre (total)
15.  Winter protection, reinforced plastic or wood  $0.63/acres
     tarpaulin over scaffold without scaffold cost $0.29/s.f.
        topographic 2 ft. contours 10 acres

                                   20 acres

                                   50 acres
                          $1975
                          $2875
Reference:  Means 1982, Dodge 1982.
                                     7-34

-------
that site specific factors such as excavation obstructions or extremely
hazardous working conditions be considered in costing.  Factors such as these
can double or triple the time spent on-site and can drastically affect total
costs.
                                     7-35

-------

-------
                                   SECTION 8

                             EVALUATION PROCEDURES
     Numerous factors must be taken into consideration in evaluating proposed
remedial actions, just -as numerous factors must be considered in their design
and installation.  To evaluate slurry walls as remedial measures, an under-
standing of the currently accepted theories on the nature and function of the
materials and techniques involved is essential.  The early phases of the
remedial planning process will center on characterization of the nature and
extent of the environmental problems caused by the site in question.  The
later phases will focus on solutions to those problems.  When a slurry wall  is
being considered as a remedial measure for a particular site, an evaluation
must be made on the type and configuration of slurry wall to be used, as well
as the other measures that must be taken to resolve the problems.  In
addition, the proposed construction techniques, quality control measures, and
monitoring and maintenance programs must be evaluated carefully.  Finally, the
costs, both for the slurry wall and the related remedial measures must be
analyzed, keeping in mind the degree of effectiveness or the safety factor
gained for each additional cost incurred.

     Each slurry wall installed for pollution control will be unique in many
respects.  It is essentially impossible to foresee every potential contingency
of each site, however, the major site planning considerations can be listed.
For this reason, this section presents a series of questions indicative of the
type of thought process that should accompany the evaluation procedure.  The
evaluation procedures presented here parallel sections 3 through 7 of this
handbook and are illustrated in Figure 8-1.
8.1  Site Characteristics
     Both the surface and subsurface characteristics  of  a  site  influence  the
design and construction of slurry walls.
                                     8-1

-------
               Figure 8-1.
Flow Chart of the Evaluation Procedures
   for a Pollution Control Slurry Wall






00
I
hJ








Site
Investigation
and
Characterization
and

Wall
Feasibility

























^^^
^^







^

L^
*1


Selection of
Wall Type
and
Configuration




1
f
r ~~^
Selection of
Other
Remedial
Measures
L










1
1
1
1
1
1
J
Selection of
Wall Type
and
Configuration


Wall Design,
Construction,
&QA/QC
A A
1 1
1 1


Wall
Monitoring
and
Maintenance


Walt
Costs
* *
1 1
1 I
r
1
I
I
1
i
L


Other Measure
Design,
Construction,
&QA/QC

-1
1
1
r-
1
_l
r1"
1
i
•1
i
i
L


Other
Monitoring
and
Maintenance

~\
\

1
r
i
I
-j






1
1
1
t
1

1
Walt
Costs


*
1
1
1
' "1
Other
Measure
Costs
J
















•*•






and Durability
of Watt
and Entire
Remedial Action







-------
     8.1.1  Surface Characteristics


     Important surface factors that can affect slurry wall installations
include:

     •  Topography

     •  Soils and vegetation
     •  Property lines, rights-of-way, and utilities

     •  Roads and structures.

     Questions that pertain to a site's surfacial characteristics include the
following:

     1.  Is the topography steep?  If so, CB walls can be used in steeper
         areas.  SB walls can be used where slopes are less than 1 percent, or
         site is graded to near level.

     2.  Is sufficient area available for SB backfill mixing?  If not, back-
         fill can be mixed in mechanical batchers or pugmills, or it can be
         mixed in a central mixing area then trucked to the trench.  This will
         increase costs.

     3.  Is the terrain too rugged to allow access of heavy construction
         equipment?  If so, access roads may need to be constructed prior to
         trench excavation.  This  too will increase costs.

     4.  Is there a preponderence  of rock outcrops or boulders that will
         interfere with trench excavation?  If so, construction delays  should
         be expected and drills and chisels should be available for rock
         fracturing.   In addition, the trench bottom should be cleaned  of rock
         fragments prior to backfilling.

     5.  Are  the soils at the site stable enough  to support heavy construction
         equipment?  If not, a work platform of compacted soil can be
         constructed along the proposed line of the trench.

     6.  Are  the areas to be excavated or used for hydration  ponds and
         backfill mixing free of vegetation?  If  not, these areas must  be
         cleared and the organic matter removed so as not to  contaminate the
         backfill.

     7.  Have all property lines,  rights-of-way and utility lines been
         located?  Have utilities  been re-routed  as necessary?  Have pipes
         such as sewers been closed off to avoid  sudden slurry loss?  These
         procedures should be followed prior to excavation.

     8.  If roads  are  to be crossed during trench excavation, have alternative
         routes been devised?  Has the structural strength of the cut-off in
         the  area of  the road been designed to withstand  traffic  loads?  CB
                                      8-3

-------
         walls, concrete panel, or cast-in-place walls may be used where
         structural support is required.  Alternatively, a "traffic cap" may
         be used.  This cap is composed of compacted clay layers interspersed
         with layers of geotextiles and topped with gravel.

     9.  If structures are nearby, what special design considerations were
         taken?  Can groundwater levels be lowered?  Must nearby foundations
         require reinforcement, such as by grouting or installing tiebacks?
         Are alternative remedial measures more cost effective?
     8.1.2  Subsurface Characteristics
     The subsurface characteristics of a site that affect slurry trench
cut-off design include:

     •  Properties of the subsurface strata

     •  Aquiclude type and location

     •  Groundwater regime.

     Questions pertinent to  a site's subsurface characteristics include the
following:

      1.  Does the material  to be excavated from the trench have a favorable
          gradation?  If not, suitable borrow areas must be located and
          provisions made for excavating the borrow and for hauling it.
          Ideally, the mixed backfill should contain from 20 to 60 percent
          fines.

      2.  Are the spoils contaminated?  If so, will the contaminants interfere
          substantially with trench wall stability, or can the contaminated
          material be used?   It has been suggested that if contaminated spoil
          is equal in quality to other available backfill material, that the
          contaminated soil  be used in the backfill to minimize the detri-
          mental  effects of  later permeation with pollutants.

      3.  Is all  of the backfill contaminated, or are portions still
          uncontaminated? If only portions are contaminated with volatile
          organic chemicals  to the point where they are not usable in the
          backfill, these portions can be disposed of and the uncontaminated
          material can be used.  These materials can be distinguished by using
          an organic vapor detector to "sniff" each backhoe bucket or clam-
          shell load.  The contaminated material can then be dumped into
          trucks  for haulage to disposal sites.  The uncontaminated material
          can be  used in the backfill.

      4.  Do the  spoils contain other materials that may be detrimental to the
          integrity of the backfill?  These materials include organic debris,
          construction debris such as pieces of concrete, and certain minerals
          such as caliche and anhydrite.


                                     8-4

-------
 5.
10,
11
12
Will the trench be excavated through highly pervious zones such as
gravel or coarse sand layers?  If so, stipulations may be made in
the design criteria to require the availability of lost circulation
materials, as listed in Section 5.  In addition, care must be taken
in maintaining high slurry quality to avoid excessive slurry loss
through the pervious layers.  If certain fine grained sands become
sufficiently lubricated, they may suddenly lose their stability and
contribute to trench collapse.

How permeable is the aquiclude?  Are there fissures, desiccation
cracks, or other pervious zones within the aquiclude?  If the
aquiclude has permeable zones, the base of the backfilled trench can
be grouted to decrease the walls permeability.

What is the hardness of the aquiclude?  If it is extremely hard,
removal of the rock for the key-in may be very difficult.  Chisels
or drills may cause the aquiclude to fracture, thus allowing under-
seepage.  In this situation, it may be better to scrape clean the
surface of the aquiclude and install the backfill directly on it.
The weight of the emplaced backfill should be sufficient to ensure
wall integrity.
     How deep is the aquiclude?
     equipment required.
                            This determines wall depth and the
What is the key-in depth required  in  the design?  Normally, it  is
between 2 and 3 feet in rippable aquicludes.

What is the nature of the groundwater contamination?  Are  the con-
taminants the same as those in the wastes or are they substantially
different?  At a minimum, the groundwater should be tested for  pH
and hardness.  If any contaminants are suspected, tests should  be
run to determine their presence and concentrations.  Similar tests
should be conducted on all water sources to be used in the slurry.

What is the depth, volume, flow rate, and flow direction of the
groundwater?  These and other data on the groundwater regime should
be obtained through site investigations as described in Section 4.

If groundwater levels get too high, such as during a flood, what
contingency plans are included in  the design to protect the trench
prior to backfilling?  One set of  specifications recommended that
excavations cease immediately and  that the trench be immediately
backfilled.  After groundwater levels have returned to normal,  the
hastily backfilled portion of the  trench should be re-excavated,
then properly mixed and placed.
                                8-5

-------
     8.1.3  Waste Characteristics
     Before slurry trench cut-offs are selected for use at a given hazardous
waste site, the waste must be carefully characterized and the influences of
the waste on the cut-off determined.  These interactions are described in
Section 4.

     Specific questions regarding waste characteristics are given below.

     1.  What are the types and volumes of wastes known to be deposited at the
         site?  Are other wastes suspected at the site?  Certain types of
         wastes, such as pure xylene have been found to severely damage cut-
         offs.  If only small portions of these wastes are present,  a slurry
         trench cut-off may still be feasible, however if major concentrations
         are present, other methods of isolating the site must be seriously
         considered.

     2.  What, if any, are the known waste interactions?  Are dangers, such as
         explosions or sudden releases of toxic gases, likely?  Safety
         measures and trench wall siting must take  these factors into account.

     3.  How long have the wastes been at the site?  This information can
         contribute to the knowledge of plume characteristics and waste
         degradation, both of which are necessary for proper wall siting.

     4.  How soluble are the wastes and how dense are they?  Immiscible wastes
         of low density can form lenses on the surface of the groundwater.  If
         these are present, skimmers can be used to remove them  from the
         groundwater, thus lowering groundwater pumping and treatment require-
         ments, as described in Section 3.  The presence of floating contami-
         nants also affects wall design, in that aquiclude key-in may not be
         necessary at these sites.  If, however floating contaminants come  in
         contact with the slurry trench cut-off, they are likely to  be at high
         concentrations and thus are  likely to adversely affect  the  wall.
         Waste/wall interactions are described in Section 4.  Similar adverse
         effects may occur if extremely dense wastes  are present.  Under  these
         circumstances, aquiclude key-in may be of  extreme importance.
 8.2   Slurry  Wall Applications
      A critical  evaluation of the type of slurry wall and how it is applied is
 very  important.   Because  slurry walls are rarely used alone, this evaluation
 must  also focus  on  the other remedial measures to be used.
                                      8-6

-------
     8.2.1  Wall Configuration and Type
     All of the factors discussed above must be taken into account when
selecting the location, configuration, and type of cut-off wall.  Questions
regarding wall configuration are listed below.

     1.  Is the wall configuration consistent with what is known about the
         waste types and the groundwater regime at the site?  As described in
         Section 3, walls can be placed downgradient if very limited
         groundwater flow is present; and upgradient if the groundwater can be
         effectively diverted from the site.  Circumferential walls are used
         where maximum containment is required.  In any case, the wall must be
         protected from contact with the wastes that cause increases in wall
         permeability.

     2.  Are surface water diversions (i.e., dikes, ditches, berms, terraces,
         etc.) planned to protect the site from surface runoff?  These
         features are particularly critical  in humid areas and areas with
         sudden, extreme rainfall events.

     3.  Where extremely low permeability is required, are SB walls with a
         high percentage of fines specified?  Are the fines plastic or non-
         plastic?  Research has shown that maximum cut-off effectiveness
         occurs in walls having 20 to 50 percent plastic  fines and 1 to 2
         percent bentonite, with 25 to 35 percent water.

     4.  Where structural strength is required, is the wall designed to take
         the stresses applied?  SB walls are more flexible and lower in
         strength than CB walls.  Cast-in-place and panel walls have the
         highest strength, however they also have the highest permeability and
         cost.

     5.  Are the site factors favorable for  the use of SB walls?  Site
         factors, described previously, include availability of suitable
         backfill and backfill mixing area,  suitable terrain, and low strength
         requirements.
     8.2.2  Associated Remedial Measures


     Cut-offs are seldom used alone  in controlling hazardous waste  sites
types of remedial measures used with cut-offs  include:

     •  Surface Sealing

     •  Groundwater Pumping and Subsurface  Collection

     •  Surface collection and runoff diversion

     •  Measures used to increase wall efficiency.
The
                                      8-7

-------
     Questions useful in evaluating associated remedial measures are listed
below.

     1.  Is surface sealing of the site planned?  This reduces the influence
         of precipitation on the volume of groundwater at the site and thus
         can reduce the hydraulic pressure on the interior of the wall.

     2.  If well points or extraction wells are to be installed, are they
         close enough to the wall to influence wall stability?  This is most
         important during trench excavation.  If drawdown cones intersect the
         wall, the trench wall stability may suffer.

     3.  Is collection and diversion of surface water planned?  If so, this
         water must not be allowed to erode, soften, or otherwise degrade the
         clay cap placed over the completed trench.

     4.  Is the use of other measures, such as grouting, sheet piling, or
         lining the trench with impervious membranes planned?  If so, the
         location, construction considerations, and materials used must be
         compatible-with the slurry, the backfill, and the wastes at the site
8.3  Construction Techniques and QA/OC Requirements
     The most carefully designed remedial action plan will not function
properly if poor construction or QA/QC techniques are used.  These factors
must be carefully considered to ensure efficient wall installation.  Questions
regarding these criteria are given below.

     1.  Are the criteria used for selection of the contractor relevant and
         stringent enough?

     2.  Are the specifications overly stringent?  Experience has shown that
         performance type specifications allow greater opportunity for
         innovation on the part of contractors.  Because slurry  trench
         construction is an evolving technique, there are many facets of the
         technique that are likely to be improved as greater field experience
         is obtained.  For this reason, some leeway in the specifications is
         reasonable and may even be beneficial.

     3.  Do the specifications cover all the important design criteria, such
         as aquiclude selection and key-in, backfill composition and slurry
         viscosity?  These specifications are described in Section 5.
         Theories explaining the importance of these factors are discussed in
         Section 2.

     4.  Are adequate QA/QC and documenation requirements included?  Typical
         requirements are listed in Section 5.
                                     8-8

-------
     5.  Are adequate safety precautions taken during cut-off construction?
         These are particularly important in a contaminated environment,
         especially during excavation.
8.4  Monitoring and Maintenance


     Despite the care taken in design and construction, the overall perfor-
mance of a slurry wall, as well as the other remedial measures, must be
established through a monitoring program.  The nature, extent, and frequency
of the monitoring must be determined for each individual site.  Although
slurry walls require little maintenance, certain measures must be taken to
ensure short and long-term effectiveness.  Section 6 of this handbook presents
these subjects  in detail.
     8.4.1  Monitoring
     The monitoring program must  provide  answers  to  several  geotechnical  and
geochemical performance questions.   Some  important geotechnical  questions
include the following.

     1.  Does  the monitoring  data indicate  that  the  wall  is  continuous and of
         the required permeability?

     2.  Is the  wall stable?   If  not what are the causes,  impacts,  and
         remedies?

     3.  Has the groundwater  regime  been  altered in  the intended manner?   If
         not,  is this due  to  a poorly functioning cut-off, or an incomplete
         initial characterization of groundwater flow?

     Given careful  design  and construction practices, there should be few
geotechnical problems with a  slurry  wall  installation.  Nonetheless, these
performance characteristics must  be  verified.

     Because  the chemistry and geochemistry of a site have a significant
influence  on successful  slurry wall  installation, questions similar to the
following  should be asked.

      1.  Have  the slurry wall and related measures halted or reduced to an
         acceptable level, the spread of contamination by groundwater and
         surface waters?

      2.  Has  leachate/wall contact been prevented?  If not, is there evidence
         of chemical  destruction of the wall?
                                      8-9

-------
      The answering of such questions will help evaluate cut-off effectiveness
 and  durability,  and may alter the character of future site monitoring for that
 site.
      8.4.2   Maintenance


     ^Maintenance  of a slurry wall  primarily involves protecting the upper
 portion  from damage.   Pertinent  questions  include:

      1.   Is  the wall  protected  from cracking by desiccation?

      2.   Is  the wall  protected  from breach by root  penetration?

      3.   Is  the wall  protected  from traffic loading?

      All  of  these are answered by  investigating the integrity and maintenance
 of the capping method used  and  the condition of the vegetation or other
 material  used to  protect  the  cap.


 8.5   Costs
     Costs are a major concern with any project.  The  cost  of  a completed
slurry wall is dependent on a number of factors  including the  square  footage
of the wall, the characteristics of the site,  and the  materials used  for
backfill.  Section 7 presents costs for slurry walls and associated remedial
measures.  Some relevant questions on costs should  include  the following.

     1.  Is the total cost per square foot of  the proposed  slurry wall  within
         the ranges for depth and excavation ease given in  Table 7-19?

     2.  If not, are there site characteristics which  explain  a higher  or
         lower unit cost?

     The quality of the finished product is often related to the cost,  and  it
is important to understand the compromises involved between cost and  quality,
Although the cost for a proposed wall will likely be submitted as a fixed
price lump sum, it is important to have any discrepancy between anticipated
and bid cost adequately explained.  The possibility of an inferior product
exists, particularly if a site has not been well-characterized.

     The nature and extent of the other remedial measures needed to address a
particular site's problems are difficult to generalize simply  because they  are
so site specific.  Again, a compromise must be struck  between  the funds
expended and the degree of pollution control achieved.  Some basic questions
on the related measures used with slurry walls include the  following.

     1.  If costs are critical, where can costs be cut while reducing the
         effectiveness the least?
                                     8-10

-------
     2.  If additional funds are available, where can they be best expended to
         increase the effectiveness or longevity of the remedial program?

     In the majority of cases, the bids for a slurry wall installation will be
quite close to one another.  If a wide discrepancy is found, it should be
explained.  It should be kept in mind that greater costs for a wall do not
necessarily indicate greater effectiveness of the final cut-off.

     This section has provided a summary of the many aspects of slurry walls
that must be examined during evaluation of slurry wall design and instal-
lation.  These factors should be carefully considered to ensure that the
proposed installation will perform its intended purpose over its design life
in a cost-effective manner.

-------

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                         MEASURING UNIT CONVERSION TABLE
S.I. UNITS

inch (in)
foot (ft)
mile (mi)
      LENGTH

      x 2.54
      x 0.3048
      x 1.609
                     METRIC

                = centimeter (cm)
                - meter (m)
                - kilometer (km)
U.S. gallon (gal)
cubic feet (ft )
acre-foot (ac.ft)
       VOLUME

      x 0.0038
      x 0.0283
      x 123.53
                  cubic meter (m"
                  cubic meter
                  cubic meter
square inch (in )
square foot (ft )
acre (ac)
       AREA

      x 6.452
      x 0.09
      x 0.4047
                  square centimeter
                  square meter (m )
                  hectare (ha)
(cm )
ounce (02)
pound (Ib)
short ton
       MASS

      X 28
      x 0.45
      x 0.9
                * gram (g)
                = kilogram (kg)
                = metric ton (t)
                             DENSITY
                                                                                3
Pounds per cubic foot (pcf)  x 0.016         - grams  per cubic centimeter  (g/cm )
gallons per day per .
 square foot (gpd/ft )

Darcy
HYDRAULIC CONDUCTIVITY


                 .-5


      x 8.58 x 10 ^   ™ centimeters per second
x 4.72 x 10 ~"   - centimeters per second (cm/sec)

           -4
                                        9-1

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                                   GLOSSARY
Adsorption complex:  The adsorption complex is the group of substrates in soil
     capable of attracting and exchanging other materials.  Colloidal
     particles account for most adsorption in soils.

Apparent viscosity:  The apparent viscosity of a fluid is the viscosity it
     exhibits under a given rate of shear and is equal to shear stress/rate of
     shear.  This quantity can be measured using a Fann viscometer.

Aquiclude:  An aquiclude is a body of low permeability rock or other earth
     material that does not transmit sufficient groundwater to supply a well
     or a spring.

Aquifer:  An aquifer is a formation, group of formations, or part of a
     formation that contains sufficient saturated permeable material to yield
     significant quantities of water to wells and springs.

Attapulgite:  Attapulgite is a chain-lattice clay mineral having a distinctive
     rod-like shape.  Syn:  Palygorskite.

Backfill:  Backfill is earth or other materials used to replace material
     removed during construction or mining operations.  For slurry walls, the
     backfill is soil-bentonite, cement-bentonite, or concrete.

Bedrock:  Bedrock  is the more or less solid, undisturbed  rock  in place either
     at the surface or beneath superficial deposits of gravel, sand, or soil.

Bentonite:  Bentonite is a light-colored rock consisting  largely of colloidal
     silica and composed mostly of crystalline clay'minerals.  It  is produced
     by the weathering of glassy igneous materials, usually a  tuff or volcanic
     ash.  When wet, it is soft and plastic.

Bleed water:  Bleed water is the water  that  separates  from a cement or
     concrete mixture before and during hardening.

Blowout gradient:  Blowout gradient refers to the hydraulic gradient at which
     a slurry will be forced out of soil or  other voids.

Borrow:   Borrow is soil material taken  from  a distant  source to be used as
     fill material on-site.

Cation exchange capacity:  Cation  exchange capacity refers to  the  sum total  or
     exchangable cations  that  a soil can adsorb.
                                      10-1

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Confined groundwater:  Confined groundwater is under  pressure  significantly
     greater than atmospheric, and its upper  limit  is  the bottom  of  a  bed  of
     distinctly lower hydraulic conductivity  than the  aquifer.

Confining bed:  A confining bed is a body of  less permeable material overlying
     or underlying an aquifer.  "Aquitard" is a commonly used  synonym.  The
     terms "aquiclude" and "aquifuge" are generally considered  obsolete.
     Confining beds have a high range of hydraulic  conductivities  and  a
     confining bed of one area may have a hydraulic conductivity  greater than
     an aquifer of another area.

Capillary fringe:  The capillary fringe is the zone immediately above  the
     water table in which all or some of the  interstices are filled with water
     that is under less than atmospheric pressure and  that is  continuous with
     the water below the water table.  The thickness  of the capillary  fringe
     is greater in fine-grained material than in coarse-grained material.  It
     ranges in thickness from a fraction of an inch to tens of  feet.

Dewatering:  Dewatering is the removal of groundwater  from an  area by  means of
     pumps or drains.

Discharge zone:  Discharge zone is a zone in which  subsurface water, including
     water from both the saturated and unsaturated  zones, is discharged to the
     land surface or to the atmosphere.

Dispersion:  Dispersion is the breaking up of compound particles  into
     individual component particles.  It also refers  to the distribution and
     suspension of fine particles in or throughout a dispersing medium, such
     as water.

Effective porosity:  Effective porosity refers to the  amount of interconnected
     pore space available for transmitting water.

Fann viscometer:  A Fann viscometer is a device used  to measure the viscosity
     of a slurry.  In this device the slurry is sheared between two rotating
     cylinders.  From the results of this test the plastic and  apparent
     viscosities can be calculated.

Filter Cake:   Filter cake refers to the thin, very  low permeability  layer
     formed on porous media by slurry filtration. As the slurry is forced  into
     the pores by the hydraulic head, the slurry particles plug the pores  and
     build up a "cake".

Flocculation:   Flocculation is the aggregation of soils or colloids  into small
     lumps called floes,  which settle from a suspension.

Flow net:  A flow net is a set of intersecting equipotential lines and flow
     lines representing two-dimensional steady-state flow through  porous
     med ia.

Gel strength:   Gel strength is the stress required  to break up  a  gel structure
     formed by thixotropic build up under static conditions.
                                     10-2

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Grout:  Grout is a fluid material that is pressure injected into soil, rock,
     or concrete to seal openings and to lower permeability and/or provide
     additional structural strength.  There are four major types of grouting
     materials:  chemical (silicates and polymers), cement, clay, and
     bituminous.

Hanging wall:  A hanging slurry wall is one that is completed several feet
     into the lowest water table level but is not tied into a low permeability
     zone.  These are used mostly to control floating contaminants.

Head (Hydraulic):  The height above a datum (sea level) to which a column of
     fluid can be supported by the static pressure at that point.

Hydraulic conductivity:  Hydraulic conductivity K, replaces the term
     "coefficient of permeability" and is a volume of water that will move  in
     unit time under a unit hydraulic gradient through a unit area measured at
     right angles to the direction of flow.  Dimensions are LT   with common
     units being centimeters per second.

Hydraulic gradient:  Hydraulic gradient is the change in head per unit of
     distance in the direction of maximum rate of decrease in head.

Keyed-in wall:  A keyed-in slurry wall is one which has been connected along
     its base to a low permeability zone such as a clay layer or hard bedrock.

Leachate:  Leachate is contaminated liquid discharge  from a waste disposal
     site to either surface or subsurface receptors.  It is created by fluid
     percolation through and from waste materials.  The contaminated water
     then moves either into the ground below or as surface runoff or seepage.

Lithologic unit:  A lithologic unit is a stratigraphic unit having a sub-
     stantial degree of lithologic homogeneity consisting of a body of strata
     that is unified with respect to adjacent strata  by possessing certain
     objective physical features observable in the field or subsurface or
     consisting dominantly of a certain rock type or  combination of rock types
     and considered completely independent of time.

Marsh  funnel:  A Marsh funnel is a device used to measure the viscosity  of  a
     slurry.  The Marsh viscosity, in seconds, equals the time it takes  1
     quart (946 cm ) of slurry to pass through the funnel.

Montmorillonite:  Montmorillonite refers to a group of expanding-lattice clay
     minerals characterized by high cation exchange capacity and high swelling
     and shrinking.

Performance:  Used herein to describe a slurry wall's ability to function at
     or above design specifications.

Permeability:  Intrinsic permeability, k, is a property of the porous medium
     and has dimensions .of LT.  It is a measure of the resistance to  fluid
     flow through the medium and is often used to mean the same  thing as
     hydraulic conductivity.
                                      10-3

-------
Permeameter:   A permeameter is an apparatus used in the laboratory to measure
     a material's permeability or hydraulic conductivity.

Piping:  Piping occurs as a result of seepage erosion in which flowing water
     has enough force to erode or carry away soil particles, creating
     localized channels and/or cavities in the soil.

Plasticity:  Plasticity is the quality of having the capacity to be molded or
     altered and the ability to retain a shape attained by pressure
     deformation.

Plastic viscosity:  Plastic viscosity is a measure of the resistance to  flow
     caused by mechanical friction.  It is measured on a Fann viscometer and
     is dependent on solids concentration, size and shape of solids, and the
     amount of shearing within the liquid phase.

Porosity:  Porosity of a rock or soil is its property of containing
     interstices and is the ratio of the volume of interstices to the total
     volume.   It is expressed as a decimal, fraction, or percentage.  Total
     porosity is comprised of primary and secondary porosity.  Porosity  is
     controlled by shape, sorting and packing arrangements of grains and is
     independent of grain size.

Potentiometrie surface:  Potentiometric surface is an imaginary surface
     representing the static head of groundwater and defined by the level to
     which water will rise in a well.  The water table is a particular
     potentiometric surface.

Pozzolana:  Finely divided siliceous or siliceous and aluminous materials used
     to make strong, slow-hardening cements.  Pozzolanic cements are resistant
     to saline and acidic solutions.

Recharge zone:  A recharge zone is a zone in which water is absorbed and added
     to the zone of saturation, either directly into a formation, or
     indirectly by way of another formation.

Rheological blocking:  Rheological blocking refers to the inhibition of  slurry
     flow into a soil or rock body due to the onset of gelation of the slurry
     in the large pores.

Saprolite:  Saprolite is a general term for earth materials formed by the
     disintegration and decomposition of rock in place.  "Saprolitic zone"
     refers to that zone where saprolite is present.

Saturation:  Water saturation is the percentage ratio of the volume of water
     to the volume of void space.

Saturated zone:  The saturated zone is that part of the water-bearing material
     in which all voids are filled with water under pressure greater than
     atmospheric.
                                     10-4

-------
Shear strength:   Shear strength is the maximum internal resistance of a
     substance to movement of its particles due to intergranular friction and
     cohesion.

Slump:  Slump refers to the vertical distance a cone-shaped mass of concrete
     or other plastic material will settle.  It is measured using a slump cone
     as specified in ASTM Book of Standards, Part 14.

Slurry:  Slurry refers both to colloidal suspensions of bentonite in water as
     well as mixtures of Portland cement and water.

Soil gradation:   Soil gradation refers to the frequency distribution of the
     various sized grains that constitute a particular soil.

Specific storage:  Specific storage, S , is defined as the volume of water
     that a unit volume of aquifer releases from storage because of expansion
     of the water and compression of the grains under a unit decline in
     average head within the unit volume.  For an unconfined aquifer, for
     all practical purposes, it has the same value as specific yield.
     Note the dimensions are L  .  It is a property of both the medium
     and the fluid.

Specific retention:  Specific retention of a rock is the ratio of the volume
     of water a saturated rock will retain against the pull of gravity to its
     own volume.

Specific yield:  Specific yield is the water yielded by gravity drainage as
     occurs when the water table declines.  It is the ratio of the volume of
     water yielded by gravity to the volume of rock.  Specific yield is equal
     to porosity minus specific retention.

Storage coefficient:  The storage coefficient, S, or storativity  is defined as
     the volume of water an aquifer releases from or takes  into storage per
     unit surface area of aquifer per unit change in the component of head
     normal to that surface.  Note it is dimensionless.

Structural discontinuity: Structural discontinuity refers  to a sudden or rapid
     change in one or more of the physical properties of a  rock mass.

Thixotropy:  Thixotropy is the property of various gels to  become fluid when
     disturbed, and, later, to regain strength at constant  water  content.

Transmissivity:  Transmissivity, T, is defined as the rate  of flow of water
     through a vertical strip of aquifer one unit wide extending  the full
     saturated thickness of the aquifer under  a unit hydraulic gradient.

Unconfined groundwater:  Unconfined groundwater is water in an aquifer that
     has a water table.

Underseepage:  Underseepage is the passage of water beneath a slurry wall as  a
     result of an inadequate wall aquiclude key-in.
                                      10-5

-------
Unsaturated zone:  The unsaturated zone is the zone between the  land surface
     and the water table.  It includes the capillary fringe.  Characteristi-
     cally this zone contains liquid water under less than atmospheric
     pressure, with water vapor and other gases generally at atmospheric
     pressure.

Viscosity:  Viscosity refers to the ability of a fluid to resist  shearing  or
     flow due to counteracting, internal forces.

Weathering:  Weathering refers to the various chemical and mechanical
     processes acting at or near the earth's surface that bring  about the
     disintegration, decomposition, and comminution of rocks.

Waste Plume:  Waste plume refers to a body of water, either surface or
     groundwater, that is contaminated by toxic or otherwise hazardous
     substances and moves as a coherent mass.

Water table:  The water table is an imaginary surface in an unconfined  water
     body at which the water pressure is atmospheric.  It is essentially the
     top of the saturated zone.
                                     10-6

-------
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                                     11-1

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                                      11-7
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