xvEPA
                                  United States
                                  Environmental Protection
                                  Agency
                           EPA/540/F-94/508
                           August 1994
                                 SUPERFUND INNOVATIVE
                                 TECHNOLOGY EVALUATION
                    Emerging  Technology  Bulletin

         Reductive Photo-Dechlorination (RPD) Process for Safe Conversion
                         of Hazardous Chlorocarbon Waste Streams
                               ENERGIA, Inc. of Princeton, New Jersey
 Technology Description: ENERGIA, Inc.  of Princeton, New
 Jersey has developed a novel technology designated "Reductive
 Photo-Dechlorination" (RPD) for environmentally safe treatment
 of waste streams containing hazardous chlorinated hydrocar-
 bons. This RPD process employs ultraviolet (UV) light in a reduc-
 ing atmosphere and at moderate temperatures to efficiently convert
 chlorocarbon contaminants into valuable hydrocarbons such as
 methane, ethane, ethylene and acetylene and hydrogen chloride.
 The UV light promotes carbon-chlorine bond cleavage and long-
 chain radical reactions with the hydrogenous bath gas leading to
 the thermodynamically and kinetically favored hydrocarbon prod-
 ucts at a conversion rate of 99%+.

 The RPD process is schematically shown in  Figure 1. The pilot-
 scale prototype  consists of five  main units:  (1) Input/Mixer;  (2)
 Photo-thermal Reactor; (3) Scrubber; (4) Separator/Storage; and
 (5) Recycling. Chlorinated waste streams can be introduced in
 one of three ways:  liquid, vapor or adsorbates (to activated
 carbon). Chlorocarbon solvents are fed into  a vaporizer, mixed
 with a reducing gas and passed into the Photo-thermal Reactor.
 Air laden with chlorocarbon vapors is first  passed through a
 separator (condenser) which removes chlorinated materials  as
 liquid. Chlorinated contaminants adsorbed onto activated carbon
            are removed as vapors by purging with a mildly heated reducing
            gas. Then the vapors are passed into the Photo-thermal Reactor.

            The Photo-thermal Reactor is the heart of the RPD technology.
            Here the mixture  is irradiated and heated. The UV light breaks
            the C-CI bond  and the temperature sustains long-chain radical
            reactions. After a suitable residence time, conversion and dechlo-
            rination are fully completed. Hydrogen chloride is scrubbed from
            the mixture which proceeds to  the separator. After separation,
            excess reducing gas is recycled  back to the Input/Mixer. Valuable
            hydrocarbon products are  collected and sold. There is also an
            option for recycling a portion of  the hydrocarbon products as an
            auxiliary fuel to heat up the Photo-thermal Reactor.

            Test Results: 1,1,1-Trichloroethane  is  a representative
            chlorocarbon contaminant. Tests have demonstrated greater than
            99% conversion and complete  dechlorination. Figure 2, clearly
            shows the advantage of RPD (black bars) over Reductive Ther-
            mal (RT) (open bars) treatment  under otherwise identical condi-
            tions. In both cases conversion  is 99%+. However, while the RT
            is limited to 51%+ dechlorination, the RPD exhibits 99%+. It is
            apparent that the  RPD process is capable of safe and efficient
            conversion of chlorinated hydrocarbon contaminants to valuable
            Chlorocarbons
            waste stream
                                                         Reducing gas
                                                           recycle
                                               UV
                                               light
                            Input /
                            mixer
Photo-thermal
  reactor
                                                                 Hydrocarbons
                         Reducing gas
                           make-up
Figure 1. ENERGIA's Reductive Photo-Dechlorination (RPD) process.
                                   Products
                                  storage/sale
                                                                                       Printed on Recycled Paper

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                       100
                        80
                        60
                        40
                        20   •
RT, Conversion = 99%+
Dechlorination = 51%+
                                                            RPD, Conversion = 99%+
                                                            Dechlorination = 99%+
Figure 2. Product selectivity obtained during treatment of 1,1,1-TCA with Reductive Thermal (RT) and Reductive Photo-Dechlorination (RPD).
hydrocarbon products (mainly ethane and methane). Similar fa-
vorable results have been obtained for other saturated and un-
saturated chlorocarbons treated by the RPD process.

Waste Applicability: The RPD Process can be effectively ap-
plied to liquid or gaseous waste streams containing saturated
and  unsaturated  chlorocarbons.  It  was tested for  TCE, TCA,
DCE, DCA, vinyl chloride, ethyl chloride, DCM, and chloroform. It
may also be applicable to PCE, carbon tetrachloride, and chlori-
nated aromatics to be tested.

The  RPD  process is specifically cost-effective for the following
on-site remedial operations:

    (1) In-situ treatment of chlorinated wastes discharged from
        Soil Vapor Extraction (SVE).
    (2) Direct treatment of Off-Gas streams containing
        chlorocarbons.
    (3) On-site regeneration of Activated Carbon saturated with
        chlorocarbons removed by adsorption from waste
        streams.
    (4) Pretreatment of waste streams entering Catalytic Oxida
        tion systems, reducing the chlorine content and thereby
        promoting oxidation and longevity.
    (5) Small-scale, on-site remediations in  R&D and testing
        laboratories, chemical hoods, clean rooms, etc.
  Status: The RPD process has successfully completed the bench-
  top developmental stage and is the basis on which a pilot-scale
  prototype unit is being constructed. A demonstration SITE pro-
  gram will follow after which the RPD technology will be available
  for commercialization. Preliminary cost analysis shows that it is
  extremely competitive with other remedial  processes.  Its  esti-
  mated cost is less than $1/lb. of treated chlorocarbon.

  Business Opportunity: Energia is seeking a joint venture/indus-
  trial partner to cost-share the demonstration project, which will be
  funded,  in-part,  by EPA SITE  program.  Energia  will  consider
  granting an exclusive  license for the emerging RPD  technology
  in exchange for royalties.

  For Further Information:

  EPA Project Manager: Michelle Simon
  U.S. EPA Risk Reduction Engineering Laboratory
  26 West Martin Luther King Drive
  Cincinnati, OH 45268
  513-569-7469 Fax:513-569-7676

  Technology Developer Contact:

  Moshe Lavid  ENERGIA, Inc.
  P.O. Box 470
  Princeton, NJ 08542
  609-799-7970 Fax: 609-799-0312
    United States
    Environmental Protection Agency
    Center for Environmental Research Information
    Cincinnati, OH 45268

    Official Business
    Penalty for Private Use
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                                        EPA
                                  PERMIT No. G-35
    EPA/540/F-94/508

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