United States Environmental Protection Agency Office of Research and Development Washington, DC 20460 Office of Solid Waste and Emergency Response Washington, DC 20460 xvEPA SITE FACTS Location: Salt Lake City, Utah Laboratories/Agencies: U.S. , lAir Force, U.S. EPANational T Risk ManagemenkResearcrT * % Laboratory (NRMRL), U.S. EPA iRegibnS ( „. fr. „ ,, „ Media and Contaminants: > JB4 jet fuel in unsaturated soil JV* r " t V * Treatment: Bioventing -T ~ 1 / !**•« O / 1 J u >!-f 1 Date of Initiative Selection: Spring 1991 1 Objective: To evaluate the - effectiveness of bioventing jet- .. ( _ fuel in deep vadose zone soil Bioremediation Field Initiative Contact: Gregory Sayles,U.S. EPA JNRMRL, 26 West Martin Luther King Drive, Cincinnati, OH 45268 Regional Contact: Robert Stites, U.S. EPA Region 8,' 999 18th Street, Denver, CO 80202-2466 EPA/540/F-95/506C September-1995 Bioremediation Field Initiative Site Profile: Hill Air Force Base Superfund Site Background In 1988, the U.S. Air Force initiated a study at Hill Air Force Base (AFB) to examine the potential of bioventing to remediate JP-4 jet fuel-contaminated soils. Bioventing is the process of supplying oxygen in situ to oxygen-deprived soil microbes by forcing air through contaminated soil at low airflow rates. Because bioventing equipment is relatively noninvasive, this technology is especially valuable for treat- ing contaminated soils at military bases, industrial complexes, and gas stations, where structures and utilities cannot be disturbed. Promising results from the Air Force's initial study prompted the U.S. EPA National Risk Management Research Laboratory (NRMRL) and the Air Force to conduct a field evaluation of bioventing at Hill AFB and at Eielson AFB (see separate fact sheet, EPA/540/F-95/506B). The main objective of the Hill AFB evaluation was to deter- mine the effect of air injection flow rate on the effectiveness of bioventing in stimulating biodegradation while minimizing volatilization. The evaluation also provided an opportunity to gain experience in bioventing large volumes of soil with plumes of fuel that extend deep beneath the surface as well as under roads, under- ground utilities, and buildings. Characterization Prior to bioventing, the Hill AFB site was contaminated with JP-4 jet fuel from a depth of about 35 ft to the ground water 95 ft below the surface. The contaminated soil was a mixture of sand, silty sand, and sand interspersed with gravel and clay. Soil samples taken in September 1991 revealed an average total petroleum hydro- carbon (TPH) level of 890 mg/kg, with TPH levels at some depths reaching 5,000 mg/kg. At most depths, benzene, toluene, ethylbenzene, and xylene (BTEX) levels ranged between about 300 mg/kg and about 800 mg/kg. The area of contamination extended beneath a tool maintenance building, engine storage yard, and fuel storage yard (see Figure 1). Field Evaluation Unlike soil venting or soil vacuum extraction, bioventing uses low airflow rates to stimulate biodegradation while minimizing volatilization of contaminants in soil. Higher airflow rates stimulate faster and more widespread biodegradation but also release more volatile emissions to the surface. To study the tradeoff between the rate and range of biodegradation and the release of volatile emis- sions, the Air Force and NRMRL operated a bioventing system at the Hill AFB site from July 1991 to January 1995, changing the airflow rate about twice a year. They conducted a total of five airflow rate evaluations: one each at 28, 67, 67,40, and 117 ft /min. The 67-ft /min evaluation was repeated to include additional monitoring points added to the site. Each airflow rate evaluation included: • An in situ respiration test—measurement of the rate of oxygen uptake by micro- organisms in the soil to estimate the rate of biodegradation occurring there. Recycled/Recyclable Printed on paper that contains at least 20 percent recycled fiber ------- F-16 Engine TMtC*Ht Tool Storage Yard SMP4 • SMP s Surface Monitoring Point O CW = So!! Vapor Cluster Well Cross-Section Trace <~ Projection of Cluster Well Onto Cross-Section Trace Figure 1. Plan visit) of Hill AFB site. • Surface emissions tests—both dur- ing air injection and while the,air injection system was shut off so that emissions rates could be com- pared. • Soil gas sampling—to monitor oxy- gen, carbon dioxide, TPH, and BTEX levels. Status The Air Force and NRMRL have col- lected and analyzed bioventing per- formance data for each of the four airflow rates. The total rate of biodegra- dation increased with increasing air- flow rates, because the radius of biological activity increased. Surface emissions rates remained about the same with increasing airflow rates. Moreover, surface emissions rates during air injection were not signifi- cantly different from those during bioventing shutdowns. This was an important finding because it indicates that bioventing at the airflow rates evaluated (28 to 117 ft3/min) does not increase emissions of volatilized con- taminants. Final soil sampling conducted in December 1994 revealed that TPH and BTEX levels had declined at all but one soil depth within a 25-ft radius of the injection well. Only at a depth of 90 to 100 ft (at the capillary fringe) did TPH and BTEX levels fail to decline, suggesting that the capillary fringe was not ade- quately aerated. These results help demonstrate the feasibility and effec- tiveness of bioventing at the airflow rates evaluated. TJte Bioremediation Field Initiative was established in 1990 to expand the nation's field experience in bioremediation technologies. The Initiative's objectives are to more fully document the performance of full-scale applications of bioremediation; provide technical assistance to regional and state site managers; and provide information on treata- bility studies, design, and operation of bioremediation projects. The Initiative currently-is performing field evaluations of bioremediation at eight other hazardous waste sites: Libby Ground Water Superfund site, Libby, MT; Park'City Pipeline, Park City, KS; Bendix Corporation/Allied Automotive Superfund site, St. Joseph, MI; West KL Avenue Landfill Superfund site, Kalamazoo, MI; Eielson Air Force Base Superfund site, Fairbanks, AK; Esrambia *Wood Preserving Site, Brookhaven, MS; Rettly Tar and Chemical Corporation Superfund site, St. Louis Park, MN;^n3*Pu6lic Service Company, Denver, CO. To obtain profiles on these additional sites or to be added to the rnitiative^maiUng *" list, caE513-569-7562. For further information on the Bioremediation Field Initiative, contact Fran Kremer, Coordinator, _ Bioremediation Field Initiative, U.S. EPA, Office of Research and Development, 26 West Martin Luther King Drive, Cincinnati, OH 45268; or Michael Forlini/ U.S. EPA, Technology Innovation Office, Office of Solid Waste and Emergency Response, 401M Street, SW, Washington, DC 20460. ' «- ' ' , V ------- |