United States Environmental Protection Agency EPA/540/M5-90/003 February 1990 SUPERFUND INNOVATIVE TECHNOLOGY EVALUATION Demonstration Bulletin In-Situ Steam/Hot-Air Soil Stripping Toxic Treatment (USA) Inc. TECHNOLOGY DESCRIPTION: This technology uses steam and hot air to strip volatile organics from contaminated soil. The treatment equipment is mobile and treats the soil in-situ without need for soil excavation or transportation. The organic contaminants volatilized from the soil are condensed and collected by the process treatment train, resulting in a small volume of concentrated organic liquid waste for transportation, disposal, or recycle. A process tower supports and controls a pair of hollow augers (Figure 1) which are moved vertically through the soil. The augers are rotated synchronously in opposite directions during the treatment process to break up the soil and ensure through-flow of gases. Steam, at 400°F, and compressed air, at 275°F, are piped through the augers to nozzles located on the cutter blades. Heat from the injected steam and hot air vaporizes the volatile organics, and the gas flow carries the contaminants to the soil surface. A steel shroud (a 10' by 6' by 7' box) covers the 7'4" by 4' area of soil undergoing treatment. The suction port of a blower keeps the area underneath the shroud at a COMPRESSOR vacuum to assist the flow of gases from the soil, and to ensure against leakage to the outside environment. The off-gases are pulled by the blower from the shroud to the treatment train, where water and organics are removed by condensation in coolers and carbon adsorption beds. The air is filtered and recycled to the soil by a compressor. Water is removed from the liquid stream with a 4-stage separator followed by batch distillation, and is then recycled to a cooling tower. The condensed organics are collected and held for removal and transportation. WASTE APPLICABILITY: This technology is designed to be used on soil contaminated with volatile organics to a maximum depth of 30 feet. Semivolatiles may potentially be removed by this technology. DEMONSTRATION RESULTS: Demonstration of this technology was conducted at the Annex Terminal site in San Pedro, California, in September 1989 as part of an extensive testing program. Site characterization investigations indicated that the soil was contaminated Organios Treatment/ Disposal Figure 1. Process Flow Diagram. ------- with significant amounts of chlorobenzene, trtchloroethene, tetrachloroethene, phthalates, and other volatile and semivolatile organics. Twelve soil blocks (7'4" by 4') were treated to 5-foot depth during the SITE Demonstration. Pre- and post-treatment composite soil samples were collected from 5-foot vertical corings. Fluorescein dye was added to four blocks to evaluate migration of contaminants from the treated blocks. In addition, air emission monitoring was conducted at the soil surface for potential off-gas emissions. Extensive process operating data were collected, such as steam and air flow rates, and organic concentration in the gases collected in the shroud. Laboratory activities conducted for the Demonstration included analysis of volatile and semivolatile organic compounds, soil physical characteristics, and dye concentrations. The Demonstration showed that: " Removal efficiencies of volatile organic compounds were greater than 90%. * Semivolatile organic compounds were also removed, but at a lower efficiency. * Downward migration of compounds is not significant. * Fugitive emissions around the area being treated and previously treated areas are low. A Technical Evaluation Report describing the complete Demonstration will be available in the Fall of 1990. For Further Information: EPA PROJECT MANAGER Paul R. de Percin USEPA Risk Reduction Engineering Laboratory 26 West Martin Luther King Drive ~ Cincinnati, OH 45268 (513) 569-7797 (FTS 684-7797) United States Environmental Protection Agency Center for Environmental Research Information Cincinnati OH 45268 BULK RATE POSTAGE & FEES PAID EPA PERMIT No. Q-35 Official Business Penalty for Private Use $300 EPA/540/M5-90/003 ------- |