United States Environmental Protection Agency EPA/540/MR-93/508 April 1993 SUPERFUND INNOVATIVE TECHNOLOGY EVALUATION Demonstration Bulletin i Mobile Volume Reduction Unit U.S. Environmental Protection Agency Technology Description: The Volume Reduction Unit (VRU), which was developed by EPA, is a mobile, pilot-scale soil washing system for stand-alone field use in cleaning soil con- taminated with hazardous substances. Removal efficiencies de- pend on the contaminant as well as the type of soil. Soil washing is a water-based ex situ process for mechanically scrubbing soils to remove undesirable contaminants. The pro- cess removes contaminants from soils by either dissolving or suspending them in the wash solution (which is later treated by conventional wastewater treatment methods) or concentrating them into a smaller volume of soil through simple particle size separation techniques. The concept of reducing soil contamina- tion through the use of particle size separation is based on the finding that most organic and inorganic contaminants tend to bind to fine-sized clay and silt particles primarily by physical pro- cesses. Washing processes that separate the particles from the coarser soil particles effectively concentrate the contaminants into a smaller volume. The clean larger fraction can be returned to the site for continued use. Figure 1 provides a diagram of the typical VRU operational setup. (Thei VRU setup at the Demonstration site was modified slightly from this typical setup.) The basic VRU system consists of the following subsystems: • Soil handling and conveying (feed soil) • Soil washing and coarse screening (mini-washer and 100 mesh screen) Makeup Water Tank Slowdown Tank Water Heater Screw Conveyor Carbon Drums Trommel Screen Mini-Washer Steam Boiler Air Compressor Grizzly Electric Generator Screened Soil Fractions Figure 1. Typical VRU operational setup. Printed on Recycled Paper ------- • Hnes/floatables gravity separation (Corrugated Plate Interceptor tank) • Fines flocculation/water clarification and solids disposal (ffoc tank) * Water treatment (10 micron fitter, liquid phase carbon adsorbents, blowdown tank, and water storage tank) * Utilities - electric generator, steam boiler, and compressed air unit. Two vibrating screens continuously segregate the soil into various stea fractions. Mini-washer overflow, containing the coarser sol- Jds, falls onto the first screen. Solids from the first screen overflow are gravity-fed to a recovery drum. The first screen underflow is pumped at a controlled rate to the second screen where it is joined by the mini-washer underflow. The overflow from the sec- ond screen Is gravity-fed to the same recovery drum containing the other washed soils. The second screen underflow drains into a tank with a mixer and is then pumped to a Corrugated Plate Interceptor (CPI). Three streams exit the CPI: materials lighter than water, solids and washwater. Materials lighter than water (ffoatables such as oil) fbw over an internal weir, collect in a compartment wHhin the CPI, and drain by gravity to a drum for treatment and disposal. Solids are discharged by the bottom auger to a recovery drum. Effluent from the CPI overflows into a tank with a mixer to a static mixer located upstream of the floe clarifier's mix tank. Flocculating chemicals such as liquid alum and aqueous poly- oloclrolyte solutions are metered into the static flash mixer tank. The slurry overflows into the floe chamber, where bottom solids are augured to a drum for disposal. Clarified water is pumped from the floe overflow tank through 10-micron filters for fine particle removal and through activated carbon drums for hydro- carbon removal to permit recycle. Waste Applicability: The VRU is a mobile research unit that was developed for treatability studies on soils contaminated With a wide variety of contaminants. It was designed to be ex- tremely flexible in terms of equipment and washwater additives usod. In general, soil washing is effective on soils with a large, coarse sand and gravel fraction contaminated with a wide range of organic, inorganic, and reactive contaminants. Demonstration Results: The Demonstration took place at the former Escambia Treating Company in Pensacola, FL be- tween November 5 and 13, 1992. The 26-acre facility had used pentachlorophenol (POP) and creosote (polynuclear aromatic hydrocarbons or PAHs) to treat wood products from 1943 to 1982. The site is currently undergoing a Superfund cleanup that is being managed by EPA Region IV. During the Demonstration, the VRU operated at a feed rate of approximately 100 Ib/hr and a washwater-to-feed ratio of about 6:1. The physical condition of the washwater was modified with various combinations of surfactant, caustic, and temperature change. Condition 1 (no surfactant and ambient pH and tempera- ture), Condition 2 (surfactant addition and ambient pH and tem- perature), and Condition 3 (surfactant addition, pH of 9-10 and temperature of 150°F). A summary of the preliminary data is shown in Table 1. Table 1. Summary of Preliminary VRU Demonstration Data Condition (%) Average POP removal Average PAH removal Feed soil returned as washed soil Mass balance of total mass Mass balance of PCPs Mass balance of PAHs 1 80 79 96 104 108 87 2 93 84 96 113 60 60 3 97 96 81 98 24 17 An Applications Analysis Report and a Technical Evaluation Report describing the complete demonstration will be available in the Fall of 1993. For Further Information: EPA Project Manager Teri Richardson U.S. Environmental Protection Agency 26 West Martin Luther King Drive Cincinnati, OH 45268 (513) 569-7949 United States Environmental Protection Agency Center for Environmental Research Information Cincinnati, OH 45268 Official Business Penalty for Private Use $300 BULK RATE POSTAGE & FEES PAID EPA PERMIT No. G-35 EPA/540/MR-93/508 ------- |