&EPA
United States
Environmental Protection
Agency
Office of Solid Waste
and Emergency Respnse
(5104)
EPA550-R-00-001
September 2000
www.epa.gov
EPA CHEMICAL
ACCIDENT
INVESTIGATION
REPORT
Accra Pac Group, Inc.
North Plant
Elkhart, Indiana
Chemical Emergency Preparedness and Prevention Office
Printed on recycled paper
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The EPA Chemical Accident Investigation Program
EPA has a responsibility under section 112(r) of the Clean Air Act Amendments of 1990
for the prevention and mitigation of accidental releases. One of the fundamental ways to prevent
accidents is to understand why accidents occur and to apply the lessons learned to prevent future
incidents. Consequently, EPA has a responsibility to investigate and understand why certain
chemical accidents have occurred. A key objective of the EPA chemical accident investigation
program is to determine and report to the public the facts, conditions, circumstances, and causes
or probable causes of chemical accidents that resulted, or could have resulted, in a fatality, serious
injury, substantial property damage, or serious off-site impact, including a large scale evacuation
of the general public. The ultimate goal of the accident investigation is to determine the root
causes in order to reduce the likelihood of recurrence, to minimize the consequences associated
with accidental releases, and to make chemical production, processing, handling, and storage
safer. This report is a result of an EPA investigation to describe the accident, determine root
causes and contributing factors, and identify findings and recommendations.
In the EPA chemical accident investigation report preparation process, companies
mentioned in the report are provided a draft of only the factual portions (no findings, conclusions,
or recommendations) for their review for confidential business information. Federal agencies are
required by provisions of the Freedom of Information Act (FOIA), the Trade Secrets Act, and
Executive Order 12600 to protect confidential business information from public disclosure. As
part of this clearance process, companies often will provide additional factual information that
EPA considers and evaluates for possible inclusion in the final report.
Chemical accident investigations by EPA Headquarters are conducted by the Chemical
Accident Investigation Team (CAIT) located in the Chemical Emergency Preparedness and
Prevention Office (CEPPO) at 1200 Pennsylvania Avenue, NW, Washington, DC 20460, 202-
260-8600. More information about CEPPO and the CAIT may be found at the CEPPO
Homepage on the Internet at "www.epa.gov/swercepp/". EPA also has accident investigation
capability in its ten Regional offices. This Accident Investigation was led by the Region 5 team.
U.S. Chemical Safety and Hazard Investigation Board (CSB)
In 1990, the U.S. Chemical Safety and Hazard Investigation Board (CSB) was created as
an independent board in the amendments to the Clean Air Act. Modeled after the National
Transportation Safety Board, the CSB was directed by Congress to conduct investigations and
report on findings regarding the causes of any accidental chemical releases resulting in a fatality,
serious injury, or substantial property damages. In October 1997, Congress authorized initial
funding for the CSB. The CSB started its operations in January 1998 and has begun several
chemical accident investigations. More information about the CSB may be found at the CSB
homepage on the Internet at "www.chemsafety.gov".
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For those joint investigations begun by EPA and the Occupational Safety and Health
Administration (OSHA) prior to the initial funding of the CSB, the agencies have committed to
completing their ongoing investigations and issuing public reports. Under their existing
authorities, both EPA and OSHA will continue to have roles and responsibilities in responding to
and investigating chemical accidents. The CSB, EPA, and OSHA (as well as other agencies) are
developing approaches for coordinating efforts to support accident prevention programs and to
minimize potential duplication of activities.
Basis of Decision to Investigate
An explosion and fire occurred at the Accra Pac Group, Inc., North Plant Facility located
in Elkhart, Indiana on June 24, 1997. EPA investigated the accident because of the serious
consequences of the incident, the hazardous characteristics of the chemical involved, and the
opportunity for lessons learned and prevention of future accidents. This investigation was
conducted simultaneously with the Indiana Occupational Safety and Health Administration and
the Indiana State Fire Marshall's Office.
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Executive Summary
An explosion and fire occurred at the Accra Pac Group, Inc., North Plant Facility located
in Elkhart, Indiana on June 24, 1997. This incident killed one employee; caused 59 people,
including plant employees, fire department personnel, and residents, to seek medical treatment;
and caused extensive damage to the facility. An evacuation extending to a one-mile radius from
the facility occurred as a result of the explosion and fire.
The Accra Pac facility produces various pressurized containers, most of which are
consumer aerosol products such as hair sprays and deodorants. These pressurized containers
typically consist of a product, such as hair spray or deodorant, and a propellant, usually propane,
to aerosolize the product and form a spray.
The explosion occurred at the building known as the Gas House for line No. 61, which
was one of several such buildings where pressurized containers are filled with propellant. The
pressurized containers are usually filled in two stages. In the first stage, the product is placed in
the container. Since the products are not hazardous chemicals, this is done in the North Plant
Production Building, hereinafter referred to as the Production Building. In the second stage, the
propellant is placed into the container. This is performed in the Gas House.
A conveyor system brings the containers from the Production Building to the Gas House.
Filled containers are then moved by conveyor back to the Production Building for leak and quality
control checks and then on to packaging.
On the day of the explosion, line No. 61 was in the second day of a four-day production
run filling containers with ethylene oxide for use as a sterilant, primarily in hospitals. This
production run is a variation of the regular pressurized container filling. The ethylene oxide
container does not produce an aerosol and has just one chemical - ethylene oxide. The ethylene
oxide container consists of only a can with a crimped sealed cap. There are no valves or internal
mechanisms for spraying. All the filling of ethylene oxide takes place in the Gas House.
Ethylene oxide is a highly reactive and toxic chemical. It is classified by the National Fire
Protection Association (NFPA) as a class 1A flammable liquid, and it is listed by EPA as an
"extremely hazardous substance".
Because of ethylene oxide's toxicity, the Gas House operator is required to wear
protective clothing and use a respirator during ethylene oxide filling. Supplied breathing air is
pumped to the operator's respirator via an air hose.
The ethylene oxide filling operation in the Gas House consists of a feed system where
ethylene oxide liquid from a storage tank is brought through a stainless steel pipe to the Gas
House at 55-65 pounds-per-square-inch-gauge pressure (psig). In the Gas House, ethylene oxide
is fed into the Graco pump, which is a feed-booster pump, where ethylene oxide is pressurized to
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600-650 psig and then sent to the "under-the-cup" filling machine. A small amount of ethylene
oxide is released into the Gas House during the filling and sealing of each container. Hence, the
filling machine meters out approximately 105 grams of ethylene oxide for each 100-gram
container it fills. (The target amount for each 100-gram container is 101.5 - 102.5 gram.) Any
excess ethylene oxide is sent to a reclamation tank located in the Gas House.
The Gas House is also connected to a catalytic oxidizer, ETO-Abator®, to break down
ethylene oxide vapor so that it will not be released into the environment.
About 2:00 p.m. on June 24, the pump that supplied breathing air to the operator in the
Gas House stopped. Unable to breathe without supplied breathing air, the operator was forced to
quickly shut down the filling operation and leave the Gas House.
After the breathing-air pump was fixed, the operator returned to the Gas House to restart
the production line. However, he noticed that an alarm indicating a high level of hydrocarbon
vapor had been triggered. The alarm indicated that the level of hydrocarbon vapor had exceeded
40 percent of the lower explosive limit (LEL). (The Gas House is used primarily for processing
hydrocarbons such as propane and iso-butane. Since ethylene oxide is not a hydrocarbon, the
facility does not know the level of ethylene oxide which would trigger this alarm.) The operator
immediately left the Gas House to check on the instrumentation located in the adjacent
Production Building.
As he exited the Gas House, a large explosion occurred. The deflagration panels on the
Gas House were blown off, the roof bulged and split open, and all the doors were blown off the
Gas House. The operator was thrown a distance of about 10 feet. He suffered an injury to his
shoulder and received cuts and lacerations.
An Accra Pac employee working in the Production Building across from the Gas House
was killed as a result of the explosion. When the Gas House doors were blown off, the door
facing the Production Building impacted the Production Building door and caused that door and
its frame to be dislodged and blown into the Production Building where it struck and killed the
employee.
The EPA Chemical Accident Investigation Team (CAIT) believes that the explosion was
caused by ethylene oxide vapor that had accumulated in the Gas House. The vapor exceeded the
LEL and contacted an ignition source which initiated the explosion. The CAIT identified the
following as root causes and contributing factors in the accident:
Inadequate shut-down procedure - When the breathing air supply to the respirator was
interrupted, there was a hurried shut down of the filling operation. The shut down steps
taken included blocking off the containers on the incoming conveyor and cutting the air
supply used to drive the Graco pump. None of the valves in the ethylene oxide supply
system were closed. In the event of a leak in the system within the Gas House, the
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pressurized ethylene oxide in the storage tanks located outside the Gas House could
discharge into the Gas House.
Location of the reclamation tank - Locating the reclamation tank, which holds up to 20
pounds of ethylene oxide, inside the Gas House violates good industry practice for
minimizing the quantity of hazardous material in an occupied area. A leak in the
reclamation tank system could result in a discharge that would exceed the LEL. Also, the
reclamation tank did not have instrumentation for monitoring the amount of liquid
it contained. Overfilling the tank could lead to over-pressure which in turn could lead to
a rapid release of its contents.
Lack of sufficient barriers or separation spacing between the Gas House and the
Production Building - Per National Fire Protection Agency (NFPA) Code 30, 5-3.2.2
"Where Class 1A liquids or unstable liquids, regardless of class, are handled or processed,
the exposing walls shall have explosion resistance in accordance with good engineering
practice." The Production Building did not provide sufficient explosion resistance to
protect the occupants. The door on the Production Building was blown off its mounting.
The employee in the Production Building was killed when struck by the door.
Insufficient explosion venting to permit adequate pressure release - Pursuant to
determinations using guidelines found in NFPA Code 68, a much larger vent area should
have been provided to allow explosion pressure release without destruction of the
building. The Gas House is designed with deflagration panels. The deflagration panels
are designed to blow out to permit adequate pressure release in the event of an explosion
inside the Gas House. The line No. 61 Gas House's deflagration panels were designed for
use with members of the NEC Group D flammable vapors, of which propane is a member.
The fundamental burning velocity and the rate of explosion pressure rise of ethylene oxide
is over twice that of propane. The explosion vents of the Gas House were barely adequate
for propane. The explosion vents were not adequate for ethylene oxide which is much
more hazardous than propane in terms of explosions.
Inadequate door design - The doors on the Gas House were not permitted to swing
open freely in response to the explosion. There was damage on the door jambs. The
damage indicated that the doors were closed with the latches in the closed position.
NFPA 68, 9-4.1 for venting of deflagrations states that hinged doors should swing
outward and have latches that release under slight internal pressure. If the doors were less
restrained and able to swing open easily, they could have swung open with the explosion
and have been less likely to be blown off, thus reducing the likelihood of injuries and
property damage. The doors opening easily would also limit the pressure buildup in the
Gas House and reduce the explosion blast effect.
Use of electrical equipment that did not meet National Electrical Code (NEC)
requirements - Ethylene oxide is a NEC Class 1, Division 1, Group B material. The Gas
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House did not meet the NEC requirement for working with ethylene oxide. The electrical
equipment in the Gas House could have provided initiation for the explosion.
Based on the root causes and contributing factors of this accident described above, the
CAIT provides the following recommendations to prevent accidents like this one from occurring
in the future at this and other facilities:
Establish safe emergency shutdown devices and procedures for all operations. The
facility must examine situations where a quick shutdown of operations must occur and
ensure that the necessary devices and procedures are in place. Systems and procedures
must ensure that critical steps are followed in their proper order and that critical
equipment is stopped and valves closed to sufficiently isolate the process. For example,
Accra Pac should consider installation of valves in ethylene oxide feed lines that close
automatically when the conveyor line is stopped. Depending on operational
circumstances, such as in restricted or hazardous areas, facilities should consider manual
shutdown devices that can be remotely operated so that employees do not need to enter
hazardous situations.
Relocate the reclamation tank to a location outside the Gas House to reduce the
amount of hazardous material inside the occupied building. In the event of a tank
leak, this would reduce the likelihood of injury to the occupant of the Gas House. Also,
develop a way to monitor the quantity of material in the reclamation tank. This
capability is necessary to avoid overfilling which can lead to an accidental release. Finally,
install a non-return check valve on the reclamation tank. This would minimize any
release should the feed line or any connectors leading to the reclamation tank fail.
• Properly locate and provide sufficient barriers between units that have a potential
for explosion from other processes in accordance with NFPA 30, 5-3.2.2. Units that
are recognized as hazardous with a potential for explosion should be sufficiently spaced
away or provided with blast walls between units such that if an explosion occurs,
employees in other locations are not harmed.
• Provide adequate deflagration venting capability for the Gas House. The Gas House
should have deflagration venting capability that is appropriate for any material that may be
handled.
Evaluate doors to ensure outward swing action and latches that easily release under
slight internal pressure. Doors that are designed to be of minimum weight and that have
latches that easily release (friction, spring loaded, or magnetic devices) will allow the
doors to provide additional over-pressure relief. For personnel safety, the doors should be
designed to remain attached to the building in the event of an explosion.
Limit the electrical equipment in the Gas House to those that meet the NEC rating
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for the type of material being processed. NEC Class I, Group B is required for working
with ethylene oxide.
In addition, the following are recommended to improve safety in the Gas House:
• Ensure the maximum reliability of breathing air systems. The supplied breathing air
system must be designed, maintained, and operated for maximum reliability. In addition,
facilities should consider alarms and backup breathing air supplies to ensure the safety of
workers, and to allow a safe shutdown of the unit as necessary.
• Relocate the feed charge pump (Graco or similar). The feed charge pumps, Graco in
this case, and their associated valving could develop into a source of leakage. Locating the
pump inside an occupied building such as the Gas House could add to the concentration of
ethylene oxide in that occupied area. Locating the pump to a location outside the Gas
House would reduce the likelihood of an explosion as a result of pump leakage. The
controls for the feed charge pump can be located within the Gas House.
• Perform process hazard analysis. A thorough process hazard analysis should be
performed before commencing processing of any hazardous material. A hazard analysis
that addressed the requirements for each of the individual types of process operations
would have identified the conditions that led to the explosion and resultant fatality.
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Table of Contents
1.0 Background 1
1.1 Operations
1.2 Chemical Information
1.3 Process Information
2.0 Description of the Accident 10
2.1 Preparation for Ethylene Oxide Filling
2.2 Events Preceding the Accident
2.3 The Explosion and Fire
2.4 Emergency Response
3.0 Investigation Finding 13
3.1 Potential Sources of Ethylene Oxide
3.2 Potential Sources of Ignition
3.3 Death of Employee
3.4 Gas House Construction
4.0 Accident Scenarios 19
5.0 Root Causes and Contributing Factors of the Accident 21
6.0 Recommendations 23
References 25
Chemical Accident Investigation Team (CAIT) Members 27
Appendix A: Photographs of Damages to Facility and Equipment 29
A-l The Gas House and the Production Building after the explosion and fire
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A-2 Top View of the separation between the Gas House and the Production Building
after the explosion and fire
A-3 Side and bottom view of the ethylene oxide reclamation tank after the explosion
and fire
Appendix B: Vent Area Calculation 35
AppendixC: Material Safety Data Sheet for Ethylene Oxide 37
List of Exhibits
Exhibit 1 Map of the Area Surrounding the Accra Pac Facility 2
Exhibit! Accra Pac Accident Site 4
Exhibit 3 Ethylene Oxide - Simplified Filling Configuration 6
Exhibit 4 Gas House Ethylene Oxide Vapor Recovery and Disposal System ... 7
Exhibit 5 Ethylene Oxide Abater 8
Exhibit 6 Event and Causal Factors Diagram 14
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1.0 Background
The Accra Pac facility in Elkhart, Indiana is located on the corner of Middlebury Street
and Middleton Run. Within a one-mile radius of the facility are industrial sites, businesses, a
trailer park, and single family homes. The St. Joseph River and the Elkhart River are also located
within one-mile of the facility. (See Exhibit 1)
1.1 Operations
Accra Pac has several production lines at the facility. Each production line includes a gas
house. Production line No. 61 is used for general pressurized container filling operations, which
include ethylene oxide filling. Accra Pac first performed ethylene oxide filling in February 1995.
The June 1997 production run was the eighth time that Accra Pac performed ethyl ene oxide
filling. At the time of the explosion, line No. 61 was in the second day of a four-day ethyl ene
oxide filling run.
1.2 Chemical Information
Ethylene Oxide
Ethylene Oxide, C2H4O, is a colorless gas at room temperature with an ether-like odor.
Physical Properties
Boiling Point
Liquid Density at 68 °F
Flash Point (Tag open cup)
Auto-ignition Temperature
Lower Explosive Limit (LEL)
Upper Explosive Limit (UEL)
Ethylene Oxide
51 °F
7.25 Ibs/gal
<0°F
804 °F
3%
100%
(Kirk-Othmer, 1994)
Ethylene oxide is soluble in water and will react with acidified water to produce ethylene
glycol. This water solubility is one of the methods used for disposing of ethylene oxide. Ethylene
oxide is incompatible or reactive with strong acids; alkalis and oxidizers; chlorides of iron,
aluminum, and tin; and, oxides of iron and aluminum.
Ethylene oxide is an irritant to the eyes, nose, and throat. It can cause damage to eyes,
blood, respiratory system, liver, central nervous system, and kidneys. It is also a known human
carcinogen. The Immediately Dangerous to Life and Health (IDLH) concentration is 800 parts
per million (ppm). (National Institute for Occupational Safety and Health, 1990)
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Exhibit 1. Map of the area surrounding the Accra Pac facility.
One Mile Radius
Accra Pac
Facility
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The uses of ethylene oxide include: manufacture of ethylene glycol (antifreeze) and higher
glycols, surfactants, acrylonitrile, ethanolamines, petroleum demulsifiers, fumigants, and an
industrial sterilant. For sterilizer applications, ethylene oxide is typically supplied as pure liquid or
as a mixture with other carriers in cylinders or small canisters under pressure.
1.3 Process Information
Under ambient conditions ethylene oxide is a vapor. In the filling process, ethylene oxide
is processed as a liquid. This can be accomplished through one of two ways. Ethylene oxide can
be cooled and processed at a temperature below its boiling point, or ethylene oxide can be
processed under pressure greater than its vapor pressure. At Accra Pac, filling is done through
the application of pressure.
The ethylene oxide filling process begins in the North Plant Production Building,
hereinafter referred to as the Production Building, where the empty 100-gram containers are
placed in the container holders on the conveyor. The conveyor first moves the empty containers
to a station where a cap is placed on each container. The conveyor then transports the containers
to the Gas House.
The Gas House is a small, custom built, prefabricated metal building located about eight
feet south of the Production Building. The two buildings are linked via a conveyor that loops
through the two buildings. (See Exhibit 2) The ethylene oxide filling takes place inside the Gas
House.
In the Gas House, the containers are placed in filler heads in the under-the-cup filler where
approximately 100 grams of ethylene oxide liquid is pumped into each container. While still in the
under-the-cup filler, the filled containers are sealed by crimping the caps onto the containers.
The sealed containers are then released from the filler heads and transported back into the
Production Building where each container is inspected and quality checked for weight and for
leaks. Containers that pass quality inspection continue on the conveyor to a packaging station
where they are boxed for shipping.
The off-specification containers, either low weight or leaking, are removed from the
conveyor line and placed in a separate 55-gallon drum. The off-specification containers are
eventually removed from the 55-gallon drum and discarded.
During the production run, two 400-pound ethylene oxide storage tanks, located in a
separate building about 20 feet from the Gas House, are used to provide ethylene oxide for the
filling process. Two storage tanks are connected at the same time, as one storage tank becomes
emptied, the feed is switched over to the other while the empty storage tank is replaced with a full
storage tank.
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Nitrogen at 55-65 psig pressure is used to push the liquid ethylene oxide out of the 400-
pound ethylene oxide storage tank into a one-inch diameter stainless steel pipe leading to the Gas
House. The stainless steel pipe enters the Gas House on the west side of the building. (See
Exhibit 3 )
In the Gas House, the stainless steel pipe is connected to a flexible fiber-reinforced plastic
hose through which ethylene oxide is fed into the Graco pump. The Graco pump is a
pneumatically driven, reciprocating pump. The Graco pump raises the ethylene oxide pressure to
600-650 psig. The ethylene oxide then travels through another flexible fiber reinforced plastic
hose to the under-the-cup filler machine.
The under-the-cup filler feeds the ethylene oxide into the containers and seals the
containers by crimping the top. A small amount of ethylene oxide is released into the Gas House
during the filling and sealing of each container. Hence, the filling machine meters out
approximately 105 grams (This amount can be as high as 111 grams.) of ethylene oxide for each
100-gram container it fills. The target amount for each can is 101.5 - 102.5 gram. Any excess
ethylene oxide is sent to a reclamation tank located in the Gas House.
An operator is in the Gas House at all times during production. The operator is there to
monitor filler operations. The appearance of frost on the filler hose is an indication that a filler
seal is leaking. (Any ethylene oxide leaked out would quickly evaporate. The formation of frost
is caused by the evaporative cooling.) If the operator sees signs that the filler seal is leaking, he is
supposed to immediately replace the seal. While working in the Gas House, the operator wears a
protective suit, gloves, and boots. The operator also uses a supplied air type respirator to guard
against inhalation of ethylene oxide. Breathing air is pumped to the respirator through a hose.
Air containing ethylene oxide vapor is drawn from the Gas House through two ground
level vents located on the south side of the building. Once outside, the two vent ducts are joined
together in a manifold that feeds into a catalytic oxidizer type pollution control system known as
the ETO-Abator®, hereinafter referred to as the Abater. (See Exhibit 4 and 5)
The Abater is located about fifteen feet east of the Gas House. There is a fan at the far
end of the Abater that pulls air from the Gas House through the Abater. The Abater works by
catalytic breakdown of any ethylene oxide vapor present to form carbon dioxide and water. This
is an exothermic process. According to the manufacturer, the Abater is designed to operate
below the auto-ignition temperature of ethylene oxide so as to avoid igniting the ethylene oxide
vapor and triggering an explosion. If the temperature in the Abater approached the ethylene
oxide auto-ignition temperature, the power to the conveyer and the filling machine would be
automatically shut off. The Abater is used only during the ethylene oxide filling operation.
The Gas House is also equipped with hydrocarbon detectors and alarms. An audible alarm
and amber flashing light are triggered when the hydrocarbon concentration reaches 20 percent of
the lower explosive limit (LEL). An audible alarm and a red flashing light are
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triggered when concentration of hydrocarbon reaches 40 percent of the LEL. (These detectors
installed to trigger the audible and visual alarms and to actuate the shutdown devices were
calibrated for the specific hydrocarbon propellant normally used in the Gas House. Since the
sensors were not recalibrated for concentrations of ethylene oxide, it cannot be assumed that they
would actuate at concentration levels 20 and 40 percent of the LEL for ethyl ene oxide.)
Alarm activity is automatically recorded. When the 40 percent of LEL alarm sounds, the
power to the conveyer and the filling machine is automatically shut off. The Gas House doors are
also to remain closed during production. There is also an audible alarm that sounds if a door is
left ajar.
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2.0 Description of the Accident
2.1 Preparation for Ethylene Oxide Filling
Prior to beginning ethylene oxide filling, all other processes in the Gas House are
discontinued. Pipelines into the Gas House are vacuum-purged and closed to prevent other
chemicals from contaminating the ethylene oxide. Teflon encapsulated seals are installed on the
under-the-cup filler. For filling ethylene oxide, only three of the nine filler heads on the under-the-
cup filler are used.
The Abater is engaged and the regular ventilation fans in the Gas House are disconnected
to prevent accidental venting of ethylene oxide into the atmosphere.
Two 400-pound storage tanks containing ethylene oxide are placed on the weigh scales
that are used to monitor the amount of ethylene oxide left in the tanks. Nitrogen supply piping
and ethylene oxide delivery piping are connected to the storage tanks and the process line is
pressurized. Nitrogen is used to push liquid ethylene oxide through the piping, and a non-return
check valve is used to prevent back flow into the 400-pound storage tanks.
2.2 Events Preceding the Accident
Accra Pac scheduled the ethylene oxide filling operation to run for ten hours per day for
four days.
Mechanics modified line No. 61 for ethylene oxide filling on Saturday, June 21, 1997.
Before beginning operations, the production crew took ethylene oxide hazard awareness training
that addressed safety and health hazards of ethylene oxide.
Ethylene oxide filling started at 6:00 a.m., on Monday, June 23. When the process line
started, the under-the-cup filler developed leaks around the seals and the process was stopped.
The wrong seals had been installed on the filler heads. The correct seals were installed and the
process was successfully restarted. The process continued until about 9:00 a.m. when a high
catalyst-bed temperature alarm shut the Abater down. The high catalyst-bed temperature may
have been caused by a brief surge of ethylene oxide vapor from seal leakage. After the Abater
cooled down, the process was restarted and continued operating for the remainder of the shift.
On Monday, June 23, Accra Pac also had problems with the pump that supplied breathing
air to the Gas House operator. The pump repeatedly overheated and shut off. Each time the
pump shut off, the production line had to be shut down.
2.3 The Explosion and Fire
On Tuesday, June 24, the employees started the second day of production at about
6:00 a.m. One operator was on duty in the Gas House while other production crew members
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were working in the Production Building. The production crew in the Production Building made
sure that the containers were properly loaded onto the conveyor line. The operator in the Gas
House made sure that the containers arriving from the Production Building were properly filled
and that the equipment in the Gas House was working as intended.
The filling continued until about 2:00 p.m. At about 2:00 p.m., the breathing air pump
overheated and shut off. Not able to breathe without supplied breathing air, the operator quickly
shut down the filling process.
The operator blocked off the portion of the conveyor that supplied empty containers to
the under-the-cup filler. He waited for the filled containers to be transported out of the Gas
House, then shut off the air supply that drives the Graco pump and left the Gas House. The
nitrogen supply valve to the ethylene oxide storage tanks and the ethylene oxide supply valves
were not shut off.
While the air pump was being repaired, the operator and production crew on line No. 61
took a break.
At about 2:30 p.m., after the breathing air pump had been fixed, the operator proceeded to
the Gas House to restart the production line. As the operator approached the Gas House, he
noticed an alarm sounding and thought that it was caused by the Gas House "door ajar" alarm.
As he entered the Gas House, he noticed that the red strobe light for the 40 percent LEL alarm
was flashing. (This implied that the hydrocarbon level in the Gas House had exceeded 40 percent
of the lower explosive limit.) The operator turned to leave the Gas House to check the remote
gas manager/monitor panel inside the Production Building. He took about two steps out of the
Gas House when the explosion occurred. The operator was thrown about 10 feet. He suffered
an injury to his shoulder and also cuts and lacerations.
All three doors to the Gas House were blown off by the explosion. The door on the east
side was propelled across a public street and landed about 225 feet away. The door on the west
side struck a fork lift truck that was about 20 feet away from the Gas House. The door on the
north side struck the door on the Production Building directly across from it. The impact
knocked the Production Building door and its frame off the wall and into the building where it
struck and killed a member of the production crew working there. (See Appendix A-l and A-2)
The deflagration panels located in the Gas House walls blew out as designed and some of
the contents of the Gas House were blown out of the building. The metal roof of the Gas House
also bulged and split open at the ridge seam. The explosion triggered a fire.
The Halon and water deluge systems in the Gas House automatically activated. However,
these fire suppression systems were not designed to prevent an explosion. They were damaged by
the explosion and were not effective in putting out the fire. Plant security immediately called the
local fire department.
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2.4 Emergency Response
The Elkhart police and fire departments, the Elkhart County Local Emergency Planning
Committee (LEPC), and the Indiana State Emergency Response Commission (SERC) responded
to the emergency call. The police department controlled traffic and went door-to-door to
evacuate people within a one-mile radius of the plant. The decision to evacuate was based on the
Emergency Response Guide (US Department of Transportation, 1990) and was done as a
precautionary measure. The LEPC and SERC assisted with emergency response decision making.
The evacuation lasted about five hours.
Fifty-nine persons, including Accra Pac employees, local responders, and some members
of the community sought medical attention, mostly for respiratory distress.
After fighting the fire for about three-and-one-half hours, a fireman in protective gear
entered the Gas House and saw that the fire was being fed by material flowing from a metal pipe,
later identified as the ethylene oxide supply line. The fireman closed a valve, in the Gas House, on
that pipe. The flow of ethylene oxide stopped. Shortly thereafter, around 7:00 p.m., the fire was
extinguished.
After the fire, Accra Pac personnel tested the Production Building area for the presence of
ethylene oxide. No ethylene oxide was detected. No additional testing was conducted beyond
the facility fence line.
The water from the fire fighting effort was collected in the facility's retention pond. An
analysis of this water found no ethylene oxide. Following this analysis, the water was discharged
through the Elkhart city water treatment plant. No fish kill was observed in the portion of the St.
Joseph and Elkhart Rivers within a one-mile radius of the facility.
-12-
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3.0 Investigation Findings
EPA investigators visited the accident site, examined evidence (including tests conducted
on equipment), interviewed witnesses, and reviewed company documents to determine the events
leading to the explosion and fire. An event and causal factor chart was developed. (See Exhibit
6)
Based on physical evidence and information collected from witnesses, it is believed that
ethylene oxide vapor accumulated in the Gas House beyond the LEL followed by contact with an
ignition source initiating the explosion. EPA investigators examined the Gas House for potential
ethylene oxide sources and potential ignition sources.
3.1 Potential Sources of Ethylene Oxide
Two sources are capable of providing sufficient ethylene oxide that could lead to the
accumulation of ethylene oxide vapor beyond the LEL in the Gas House: the ethylene oxide feed
system leading to the under-the-cup filler and the ethylene oxide reclamation tank.
A. The ethylene oxide feed system could be a source for the ethylene oxide
leading to the explosion in the Gas House.
• The valves on the ethylene oxide feed line were left open when the filling process was shut
down. In the event of a leak in the feed line or valves connected to the feed line within the
Gas House, the ethylene oxide in the storage tank would discharge into the Gas House.
• Ethylene oxide has a boiling point of 51 °F. It is processed as a liquid through the
application of pressure. As the temperature of the ethylene oxide increases, the pressure
in the feed line will correspondingly increase. At the time of the explosion, the ambient
temperature was around 93 °F. The feed line was not insulated or cooled. With the filling
operation stopped, the ethylene oxide left in the feed line would eventually reach and even
exceed the ambient temperature since part of the feed line was exposed to direct sunlight.
While the ethylene oxide feed line outside the Gas House was made out of stainless steel,
some of the ethylene oxide feed lines inside the Gas House were flexible fiber reinforced
plastic hoses. These were not as strong as the "hard"(not flexible) stainless steel pipes.
There were also several connections and valves. These fittings are much more susceptible
to leaks.
The flexible lines inside the Gas House were damaged to the point where they could not
be analyzed to determine an exact leak source. The "hard" steel piping was tested and
showed no leaks. It is not clear whether the feed system failed and caused the explosion
and fire or if the explosion and fire caused by ethylene oxide release from the
-13-
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reclamation tank (discussed below) caused the damage to the feed system.
B. The reclamation tank could be a source for the ethylene oxide leading to the
explosion in the Gas House.
• Accra Pac employees reported that on the day of the explosion four 400-pound tanks of
the ethylene oxide had been consumed in the filling operation. For each 100-gram
container filled, approximately 105 grams are metered to assure a complete fill. One
hundred grams is a nominal value. The target value for each container is between 101.5
and 102.5 grams. Records indicate that it is common to have as much as five percent
variations in the amount discharged by the filler head and received by the cans. For each
100-gram container filled, 3 to 9 grams of the excess ethylene oxide may be recovered in
the reclamation tank. Based on this estimate, the reclamation tank could have reached its
capacity and contained up to 20 pounds of ethylene oxide at the time of the explosion.
The reclamation tank had not been emptied since the beginning of the production run.
The Graco pump raises the ethylene oxide pressure to 600-650 psig for filling the
containers. With each container filled, the excess ethylene oxide is drained from the filler
head to the reclamation tank. In the beginning of the process the reclamation tank will be
at ambient pressure while the ethylene oxide in the filler head is around 600 psig. As the
reclamation tank is filled, the pressure in it will increase. Since liquid ethylene oxide is not
compressible, when the reclamation tank becomes liquid full, the pressure in the
reclamation tank will increase rapidly and ultimately approach that in the filler head.
Polyethylene tubing was used to carry excess ethylene oxide from the under-the-cup filler
to the reclamation tank. The polyethylene tubing is much more susceptible to failure than
metal tubes. There is no non-return check valve on the connection of this tubing to the
reclamation tank. If this polyethylene tubing failed or became disconnected, ethylene
oxide would rapidly escape from the reclamation tank.
The ethylene oxide reclamation tank in the Gas House was found to have been crushed by
the force of the explosion. (See Appendix A-3) The tank collapsed from three sides
leaving almost no void volume. Had the reclamation tank been substantially full of liquid,
which is not compressible, the reclamation tank would not have become crushed in the
explosion. The reclamation tank showed no signs of puncture or rupture. Thus, any
release of ethylene oxide would have had to have occurred in the connectors, valves, or
tubing associated with the reclamation tank.
3.2 Potential Sources of Ignition
There were numerous types of equipment in the Gas House and the area surrounding the
Gas House which could be potential sources of ignition. These types of equipment were
examined and evaluated for their potential as sources of ignition. These evaluations included the
-15-
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following:
A. Electrical equipment could have been the ignition source.
The wiring and electrical systems within the Gas House including lights, sensors, and
alarms were rated for a location fitting NEC Class I, Division 1, Group C and D. This
classification is appropriate for most of the filling operations in the Gas House.
However, according to NFPA 70, Article 500, ethylene oxide requires a Class I, Division
1, Group B, which is more stringent.
There were also pieces of electrical equipment located within the Gas House that were
not appropriate for use in Class I, Division 1, Group B locations. This electrical
equipment included the electric drive motor for the filling machine, a computer and video
monitor, and an electrical scale whose seal appeared to have been compromised.
• Two conveyer motors located near the Gas House were not turned off when the operator
left the Gas House. One motor ran the conveyer for incoming containers and the other
for outgoing containers. Since these electrical motors would have been automatically
shut off when the 40 percent LEL alarm was activated, this would reduce their likelihood
as ignition sources.
B. Mechanical equipment could have generated high temperature from friction
to cause ignition.
When the operator left the Gas House, the conveyer system was still running with the
container on the conveyer blocked off from entering the under-the-cup filler. The friction
between the conveyer and the container holders on the conveyer could result in high
temperatures. Again, since the electrical motors would have been automatically shut off
when the 40 percent LEL alarm was activated, this would make them less probable
ignition sources.
• The Graco pump could have become bound or restricted to the point where friction could
have generated temperatures reaching the ignition point. Since the Graco pump had been
deactivated in the shut down process, the pump was thought to be an unlikely source of
ignition.
C. Spark generated from impact could have ignited the ethylene oxide.
The explosion occurred as the operator left the Gas House and the Gas House door
closed. The Abater draws air out of the Gas House at a rate of 1,500 cubic feet per
minute. This would cause the atmospheric pressure inside of the Gas House to be lower
than that outside. The pressure difference could cause the door to slam, and this impact
of the metal Gas House door onto the metal door frame could have generated a spark of
ignition intensity.
-16-
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D. High catalyst bed temperature in the Abater could have ignited the ethylene
oxide.
Even though the Abater was located outside the Gas House, this system was examined
because the chemical reaction involving the catalyst could develop temperatures in excess
of the ethylene oxide ignition temperature. The ignition of the ethylene oxide vapor can
potentially flash back into the Gas House triggering an explosion. The catalyst bed
temperature recorder chart indicated that this equipment was operating properly and
showed that the catalyst bed temperatures were in their normal operating range.
However, the thermocouple in the Abater is not located directly in the catalyst bed. The
location of the thermocouple could result in readings that are less than the temperature
within the catalyst beds and would also result in a delay between when the temperature
change occurred and when the readings appeared. However, the recorded temperature
does not support the Abater as the ignition source. More important, damage to the
Abater resulted from external impact which suggests that the Abater was not the source
of ignition. Also, the Abater internals and the duct piping were examined for evidence of
an internal flashback or flame front and no such evidence was found.
E. Static electricity could produce a charge sufficient to provide ignition.
• During the period preceding the explosion, the conveyer was running while the containers
were blocked off from entering the filler. The friction between the conveyer and the
container holder riding on the conveyer could result in a significant static charge buildup.
However, the weather conditions at the time, high humidity with temperature in the 90's,
would diminish this likelihood.
Also, a jet type leak of ethylene oxide into the air could have been a static electricity
generator. Again, the weather conditions at the time, high humidity with temperature in
the 90's, would diminish this likelihood.
3.3 Death of Employee
The employee working in the Production Building was killed when struck by the
Production Building door and its frame that faced the Gas House. The explosion blew the doors
off the Gas House. The Gas House door facing the Production Building struck the door directly
facing it on the Production Building. The impact knocked the Production Building door and its
frame off the wall. The door and frame then struck and killed the employee working in the
Production Building. According to NFPA 30, 5-3.2.2, "Where Class 1A liquids or unstable
liquids, regardless of class, are handled or processed, the exposing walls shall have explosion
resistance in accordance with good engineering practice." The two buildings are located about 8
feet apart. The two doors are directly opposed and are connected by a short walkway. They did
not have the prescribed resistance to the explosion.
-17-
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3.4 Gas House Construction
Structural members - The metal frame of the Gas House was severely distorted as a
result of the explosion. The metal roof of the Gas House bulged and split along the length
of the Gas House roof ridge seam. The deflagration panels on the Gas House were blown
off.
Doors dislodged - All three doors on the Gas House were blown off. The metal door
jambs on the Gas House were bent outward indicating that the doors had been latched at
the time of the explosion. According to NFPA 68, 9-4.1 for venting of deflagration,
hinged doors should swing outward and have latches that would release under slight
internal pressure.
Blast resistance - The Gas House is considered a low strength structure. According to
information presented in Factory Mutual Document "Series 132 Gas House from BWIKP
Aerofill, J.I. 2WOAO.AF (7146)," dated September 27, 1997, this structure would be
capable of withstanding an internal pressure of 200 psfg (pounds per square foot gauge)
or 1.39psig.
Venting capability -According to calculation methods used in NFPA 68, the vent area
on the Gas House is less than required for processing ethylene oxide. (See Appendix B
for calculation.)
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4.0 Accident Scenarios
Based on the amount of void space in the Gas House, six-and-a-half pounds of ethylene
oxide would be sufficient to place the entire atmosphere inside the Gas House above the LEL. In
order for ethylene oxide vapor in the Gas House to reach LEL, the ethylene oxide release must be
quick and in sufficient quantities to overcome the removal capacity of the Abater. The boiling
point of ethylene oxide is 51°F. At the time of accident, the temperature in the Gas House was
more than 90°F. Since the liquid ethylene oxide is stored under pressure, any leak would result in
a rapid discharge of ethylene oxide which would quickly vaporize to form an explosive mixture.
Furthermore, even though air is drawn through the Gas House and out to the Abater, the
flow through the Gas House does not ensure uniform mixing. This situation would be influenced
by the magnitude and direction of release of the ethylene oxide into the Gas House interior. A
pocket of vapor in the explosive range and occupying a fraction of the space inside the building,
and involving less than 6.5 pounds of ethylene oxide could exist inside the building and be capable
of an explosion.
However, given the impact of the explosion, chances are the explosion involved
significantly larger amounts than a localized LEL concentration of ethylene oxide. (See Exhibit 6)
Scenario 1
Ethylene oxide released into the Gas House from the feed system. The ethylene oxide
is stored as a liquid under pressure in a 400-pound storage tank located in a separate building.
During the shut down, the air supply to the Graco pump driver was shut off. But, the valves on
the feed line leading from the storage tanks were not shut off and the ethylene oxide in the storage
tank remained pressurized with nitrogen at 55-65 psig. Therefore, any leak from the feed line or
filling equipment located in the Gas House would have the potential to allow a large quantity of
ethylene oxide to be released inside the Gas House.
Scenario 2
Ethylene oxide released into the Gas House from the reclamation tank. Based on
interviews with the operator concerning the number of containers that had been filled, it was
estimated that the reclamation tank may have been liquid full. The reclamation tank can hold
about 20 pounds of ethylene oxide. The amount of ethylene oxide vapor required to exceed the
LEL in the Gas House and assuming no forced ventilation is about 6.5 pounds, or about one-third
of the contents of a full reclamation tank.
The mechanism of ethylene oxide release from the reclamation tank is not known. It is,
however, known that the feed line to the reclamation tank was made of polyethylene tubing which
could be a weak link in that part of the process. Also, the feed line to the reclamation tank did
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not contain a non-return check valve which would prevent release from the tank in case of failure
in the line. Furthermore, there was no provision for monitoring the quantity of material in the
reclamation tank. This situation raises the possibility that the reclamation tank could have been
overfilled which could lead to it becoming over-pressured and leading to the release of ethylene
oxide.
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5.0 Root Causes and Contributing Factors of the Accident
Based on evidence collected and analyses performed, the EPA Chemical Accident
Investigation Team (CAIT) identified the following as root causes and contributing factors in the
accident:
• Inadequate shut-down procedure - When the breathing air supply to the respirator was
interrupted, there was a hurried shut down of the filling operation. The shut down steps
taken included blocking off the containers on the incoming conveyor and cutting the air
supply used to drive the Graco pump. None of the valves in the ethylene oxide supply
system were closed. In the event of a leak in the system within the Gas House, the
pressurized ethylene oxide in the storage tanks located outside the Gas House could
discharge into the Gas House.
• Location of the reclamation tank - Locating the reclamation tank, which holds up to 20
pounds of ethylene oxide, inside the Gas House violates good industry practice for
minimizing the quantity of hazardous material in an occupied area. A large leak in the
reclamation tank system could result in a discharge that would far exceed the LEL. Also,
the reclamation tank did not have instrumentation for monitoring the amount of
liquid it contained. Overfilling the tank would lead to over-pressure which in turn could
lead to a rapid release of its contents.
Lack of sufficient barriers or separation spacing between the Gas House and the
Production Building - Per National Fire Protection Agency (NFPA) Code 30, 5-3.2.2
"Where Class 1A liquids or unstable liquids, regardless of class, are handled or processed,
the exposing walls shall have explosion resistance in accordance with good engineering
practice." The Production Building did not provide sufficient explosion resistance to
protect the occupants. The door on the Production Building was blown off its mounting.
The employee in the Production Building was killed when struck by the door.
Insufficient explosion venting to permit adequate pressure release - Pursuant to
determinations using guidelines found in NFPA Code 68, a much larger vent area should
have been provided to allow explosion pressure release without destruction of the
building. The Gas House is designed with deflagration panels. The deflagration panels
are designed to blow out to permit adequate pressure release in the event of an explosion
inside the Gas House. The line No. 61 Gas House's deflagration panels were designed for
use with members of the NEC Group D flammable vapors, of which propane is a member.
The fundamental burning velocity and the rate of explosion pressure rise of ethylene oxide
is over twice that of propane. The explosion vents of the Gas House were barely adequate
for propane. The explosion vents were not adequate for ethylene oxide which is much
more hazardous than propane in terms of explosions.
• Inadequate door design - The doors on the Gas House were not permitted to swing
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open freely in response to the explosion. There was damage on the door jambs. The
damage indicated that the doors were closed with the latches in the closed position.
NFPA 68, 9-4.1 for venting of deflagrations states that hinged doors should swing
outward and have latches that release under slight internal pressure. If the doors were less
restrained and able to swing open easily, they could have swung open with the explosion
and have been less likely to be blown off, thus reducing the likelihood of injuries and
property damage. The doors opening easily would also limit the pressure buildup in the
Gas House and reduce the explosion blast effect.
Use of electrical equipment that did not meet National Electrical Code (NEC)
requirements - Ethylene oxide is a NEC Class 1, Division 1, Group B material. The Gas
House did not meet the NEC requirement for working with ethylene oxide. The electrical
equipment in the Gas House could have provided initiation for the explosion.
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6.0 Recommendations
Based on the root causes and contributing factors of this accident described above, the
CAIT provides the following recommendations to prevent accidents like this one from occurring
in the future at this and other facilities:
• Establish safe emergency shutdown devices and procedures for all operations. The
facility must examine situations where a quick shutdown of operations must occur and
ensure that the necessary devices and procedures are in place. Systems and procedures
must ensure that critical steps are followed in their proper order and that critical
equipment is stopped and valves closed to sufficiently isolate the process. For example,
Accra Pac should consider installation of valves in ethylene oxide feed lines that close
automatically when the conveyor line is stopped. Depending on operational
circumstances, such as in restricted or hazardous areas, facilities should consider manual
shutdown devices that can be remotely operated so that employees do not need to enter
hazardous situations.
• Relocate the reclamation tank to a location outside the Gas House to reduce the
amount of hazardous material inside the occupied building. In the event of a tank
leak, this would reduce the likelihood of injury to the occupant of the Gas House. Also,
develop a way to monitor the quantity of material in the reclamation tank. This
capability is necessary to avoid overfilling which can lead to an accidental release. Finally,
install a non-return check valve on the reclamation tank. This would minimize any
release should the feed line or any connectors leading to the reclamation tank fail.
• Properly locate and provide sufficient barriers between units that have a potential
for explosion from other processes in accordance with NFPA 30, 5-3.2.2. Units that
are recognized as hazardous with a potential for explosion should be sufficiently spaced
away or provided with blast walls between units such that if an explosion occurs,
employees in other locations are not harmed.
• Provide adequate deflagration venting capability for the Gas House. The Gas House
should have deflagration venting capability that is appropriate for any material that may be
handled.
Evaluate doors to ensure outward swing action and latches that easily release under
slight internal pressure. Doors that are designed to be of minimum weight and that have
latches that easily release (friction, spring loaded, or magnetic devices) will allow the
doors to provide additional over-pressure relief. For personnel safety, the doors should be
designed to remain attached to the building.
Limit the electrical equipment in the Gas House to those that meet the NEC rating
for the type of material being processed. NEC Class I, Group B is required for working
-23-
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with ethylene oxide.
In addition, the following are recommended to improve safety in the Gas House:
• Ensure the maximum reliability of breathing air systems. The supplied breathing air
system must be designed, maintained, and operated for maximum reliability. In addition,
facilities should consider alarms and backup breathing air supplies to ensure the safety of
workers, and to allow a safe shutdown of the unit as necessary.
• Relocate the feed charge pump (Graco or similar). The feed charge pumps, Graco in
this case, and their associated valving could develop into a source of leakage. Locating
the pump inside an occupied building such as the Gas House could add to the
concentration of ethyl ene oxide in that occupied area. Locating the pump to a location
outside the Gas House would reduce the likelihood of an explosion as a result of pump
leakage. The controls for the feed charge pump can be located within the Gas House.
• Perform process hazard analysis. A thorough process hazard analysis should be
performed before commencing processing of any hazardous material. A hazard analysis
that addressed the requirements for each of the individual types of process operations
would have identified the conditions that led to the explosion and resultant fatality.
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References
Frank P. Lees. 1996. Loss Prevention in the Process Industries Hazard Identification,
Assessment and Control 7d ed. Oxford, Great Britain: Butterworth-Heinemann.
Kirk-Othmer. 1994. Encyclopedia of Chemical Technology, Fourth Edition. New York: John
Wiley and Sons.
National Fire Protection Association. 1996. NFPA 30, Flammable and Combustible Liquids
Code. Quincy, MA: National Fire Protection Association.
National Fire Protection Association. 1998. NFPA 68, Guide for Venting of Deflagrations.
Quincy, MA: National Fire Protection Association.
National Fire Protection Association. 1999. National Electrical Code Handbook 8th ed. Quincy,
MA: National Fire Protection Association.
National Institute for Occupational Safety and Health. 1990. NIOSH Pocket Guide to Chemical
Hazards. Washington, DC: National Institute for Occupational Safety and Health.
Public Health Service, National Toxicology Program 2000. "Ninth Report on Carcinogens."
U.S. Department of Health and Human Services.
Research and Special Programs Administration. 1990. 1990 Emergency Response Guidebook.
U.S. Department of Transportation.
Factory Mutual. September 27, 1997. "Series 132 Gas House from BWI KP Aero fill, J.I.
2WOaO.AF (7146)"
-25-
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-26-
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Chemical Accident Investigation Team (C AIT) Members
Name
James Entzminger, Lead Investigator
Byron Maggos
George Rancich
David Chung
Armando Santiago
Jim Wescoat
Organization
EPA Region 5
EPA Region 5
EPA Region 5
EPA Headquarters
EPA Headquarters
EPA Headquarters
-27-
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Appendix A: Photographs of Damages to Facility and Equipment
-29-
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-30-
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A-l: The Gas House and the Production Building after the explosion and fire.
Gas House
Opening Left
by the
Deflagration
Panels
North Plant
Production
/ Building
Ethylene
Oxide Abater
:
cS&
..••< *r=- -A
. ... ..-.
-31-
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A-2: Top View of the separation between the Gas House and the
Production Building after the explosion and fire.
Door Opening on
Gas House Facing
the North Plant
Production
Building
Door Opening on the
North Plant
Production Building
North Plant
Production
Building
-32-
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A-3: Side and bottom view of the ethylene oxide reclamation tank after the explosion and fire.
Ethylene Oxide Reclamation Tank
-33-
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-34-
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Appendix B: Vent Area Calculation
According to analysis in NFPA 68, the venting area needed so as not to exceed the limiting
internal pressure is given by the following equation:
A, = C(A,)/(PMd)*
where
A, = vent area (ft2 or m2)
C = venting equation constant characteristic for the fuel
A, = internal surface area of enclosure (ft2 or m2)
Pred = maximum internal pressure that can be withstood by the weakest
structural element not intended to fail (in psi or bar, not to exceed 1.5
psi or 0.1 bar)
The maximum internal pressure for the Gas House is Pred = 1.39 psi.
For propane, n-butane, and isobutane, which are NEC Group D gases, NFPA 68
suggests a constant value of C = 0.17.
The internal area of the Gas House is approximately 960 ft2, A, = 960 ft2
The required vent area, A,, calculated using A, = C(As)/( Pred )* is 138 ft2.
The actual area of the Gas House relief panels is 88 ft2, about 36 percent less than the
amount recommended by NFPA.
Since ethylene oxide is a faster burning chemical than NEC Group D gases, a vent
area even larger than the 13 8 ft2 would be required for ethylene oxide.
-35-
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-36-
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Appendix C: Material Safety Data Sheet for Ethyfene Oxide
-37-
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Material Safety Data Sheet
ETHYLENE OXIDE
Page 1 of
Chemical Division
Balchem Corporation
Routes 6 & 284
P. 0, Box ISO
Slate Hill, New York 10973
Inforrnatfon Telephone (9H) 355-2891
EMERGENCY TELEPHONE (800) 424-9300 (CBEMTREC)
Section I -
Identification
Section 3
PhysicalData
PRODUCT HAMS:
HAMS
Elhylena Oxide
Ethylene Oxide
«OL£CUl>H WEiSHT: 44
CAS NURSES: 7 5 -2! -8
CAS HAMS Oxirane
SYNONYMS: EO, ElO. Dlhydroxirene, 1-2 Epoxyethane,
Dimethylene Oxide, Oxarte, Oxtrane, Artprolens,
A!pha/8el3-0xidoslhans, Qxacydopropane.
pfwaucT USE: Used orirnariiy as a chemical intarmediats
}n the manufacture of anli-freeze, polyester resins.
non-ionic surfactant? and specialty solvents. Used as
a sterilising agent 00055 ElO alone or diluted with an
inert gas) in health cars applications. Used as a
fumigant for the control of microorganisms and insect
infestation in ground spicas and other processed
natural seasoning materials.
<3f TRANSPORT ATiQJl
SHIPPIM6 KATIE:
HAZAAO CLASSIFICATIOH:
UNITTO NATIONS MiriBtR;
EMFRGEHCY BESOOM36 6UIP«
R6POSTAB1.6 QUANTITY:
Ethyfens Oxide
2.3 Poisoo Sas, Flamma&Se Gas
UN 1040
69- •
10 Ib./'4.54 Kg.
Section 2
Hazardous Component information!
COMPONENT
Elhylene O^ida
SSISffl-Bt-5
IOCS
75-21-8
OSHA ACTION LEVEL (8 MR. TWAfc
OSHA W. 8 MR. TWA!
OSHA 13 MINUTE EXCURSION LlniT:
ftjSitt TtV:
CLV-TWA:
IBtH:
1050:
(I-hour)'
0,5 ppm
J ppm
5 ppm, 9
1 ppm, 2 mg/m3
800 ppm
72 mg/kg, Rat-Oral
1460 pprn, Rat-lnh
5748 ppm, Male Rat-lnh.
4439 ppm, Female Rat-lnh.
5029 ppm. Combined Sa,veg
B01LIN6
FBEE2IWG POINT:
SPECIFIC ,6«AvrTY:
VAPOR PRESSURE:
VAPOR CWSITV tAIR-t>.
SOtUBILITT IN WATER (5k
MOUCULAA WEIGHT:
PERCENT VO-ATItES BT
EVAPORATION RATE OuAc-IJ:
PM:
APPEARANCE AND OCOfi:
with sweet ether-like odor
50.9'F CIO.S'C)
-169'F (-I11.7-C)
0.87i
1094 mm Hg
1.5
10055
44 grams/mole
100"
72
7 (neutral)
Colorless liquid or gas
Odor threshold; 700 ppm.
Section 4
Fire and Explosion Data
unrrs M AIR t» er
UPREfL-
LOWES:
100%
3. OS
swam,
HSAITH:
HSACTtVITT:
f LASH POIKT 1TSST
TA6 OPEN CUP;
TAS CtOSCD CUP:
AUTO I GUI TICK TETO>.:
<-0'F f<-)8-C)
-4'F (-20'C)
804'F (429* C)
Carbon dioxide, dry chemical for
small fires. Polymer or alcohol foam for largs fires.
Dilution of ethyiene oxide with 23 volumes of water
renders it non-flammable, A ratio of 100 parts
water to one part ethyiene oxide may be required to
control build up of flammable vapors in closed system.
Water spray can be used to reduce intensity of flames
and to dilute spills to non-flammable mixtures.
HAZARDOUS McwwesiTioN BYPRODUCTS: Carbon monoxide
and carbon dioxide.
SOCIAL HUE FIGHTIHG pwcEDuRES: Wear a NIOSH approved
self-contained breathing apparatus (SCBA) with a
full facepiece operated in the pressure-demand or
positive-pressure mode. Fight fires from expfosion-
proof locations. After fire burns out. flush with water.
-------
Material Safety Data Sheet
ETHYLENE OXIDE
Page 2 of
. Section 4
Fire & Explosion Data, Con't
UNU5UAL FIRE AMJ BPtOSION HAZARDS: Eth/lenS OXl'dS (S
dangerously explosive and flammable over an
extremeiy large range of concentrations in air. Vapors
may travel along surfaces to reach distant, low-lying
sources of Ignition and Dash back.
Section 5
Reactivity Data
STABILITY: Material is stable in closed, airtight,
pressurized containers at room temperature under
normal storage and handling conditions. Potentially
unstable at temperatures above 85'F (29'C). Violently
decomposes at temperatures above 800'F (426'C).
HAZARDOUS POLYHFHIJATIWt Can OCCUT.
INCCnPATIBlLITT (MATERIALS TO AVOID): EO r63ClS with active
catalysts that promote explosive, heat-producing
self-polymerization. These initiators includa potassium;
anhydrous chlorides of tin, aluminum and iron; alcohols;
mercaptans; copper; pure oxidss of iron or aluminum;
magn9slum perchl orate; acids and bases such as KOH and
NaOH.
co«>mo«5 TO Avoit>. Contact wIth incompatible chemicals.
Prevent exposure to any and all sources of ignition such
as heat, flame, lighted tobacco products, electrical or
mechanical sparks, etc.
Section 6
Health Hazard Data
FWTES
EtfTRT;
YfiS
YeS
YSS
YES
SKIW COWTACT;
SKIM ABSORPTION;
EYE CONTACT:
IHHALATIOH:
INSESTION;
EFFFCTS OF ACUTE BgW5«lt TO PHGCTXT:
SKiNOXTACT: Liquid EO In contact with the skin will
evaporate and may cause sufficient cooling to result In
frostbite. Prolonged contact of liquid or aqueous
solutions of EO with skin can cause severe irritation,
blistering, burns, edema, formations of vesclcles and
severe dermatitis. Contact will occur from wearing
contaminated clothing or may arise from EO becoming
trapped under ring or walchband. The reaction may not
appear for several hours after exposure.
SKIM AflsoepTtot Sustained contact with the skin is
unlikely, but can cause headache, dizziness, nausea
and vomiting. Dilute solution may penetrate the
skin, causing a chemical burn.
Section 6
Health Hazard Data, Con't
Ethylene oxide liquid In diluted aqueous
solutions splashed in the eyes can cause severe
irritation and may result In cornea! injury and
permanent eye damage. EO vapors can also cause
eye Irritation.
wLATioHr Elhylsne oxide is a central nervous system
depressant. Acute inhalation can progressively cause;
mucous membrane irritation, headache, vomiting,
cyanosis, drowsiness, weakness, incoordinatlon,
CMS depression, lachrymation, nasal discharge and
salivation, gasping, labored breathing. Delayed
effects include nausea, diarrhea, edema of the lungs,
paralysis, convulsions and death.
Esriwt A highly unlikely route of exposure. Will
causa severe irritation and ulceration of the mouth
and throat, abdominal pain, nausea, vomiting,
collapse and coma.
Of CWONfC ECPO51JKE TQ PRODUCT:
Skin sensfUzation has been reported in
some volunteer subjects.
rEcotcrACT: Some cases of cataract formation have
been reported.
tALATioM: Respiratory irritation, chromosomal
aberrations and peripheral neurctoxlc effects.
numbing sense of smell.
sesTiott A highly unlikely route of exposure.
Excessive overexposure may cause anemia.
gastrointestinal irritation, effects on liver.
kidneys and adrenal glands.
OF rwTBHAU Severe Irritant.
Material Is sensitizing.
CARCINOSEMICITT;
OSHA: Noted as cancer/reproductive hazard.
AcsiH; Classified as suspected human carcinogen.
NIP: Classified as anticipated human carcinogen.
IARC: Classified as probable human carcinogen.
OSHA BESULATED: Y 6 S
TWATocBflcrrr: Teratogenic effects noted In animals
exposed to 100 ppm EO and above.
REPBOOUCTIVE TOXICITT: Reproductive effects have bean
shown in experimental animals exposed to athylene
oxide vapors.
wTAGEwaTf: Chronic exposure has been shown to Induce
chromosomal aberrations.
EMPSOCt AH) FtBST-AlB PBOCE8UB65.-
erieposut Immediately flush eyes, including under the
eyelids, gently but thoroughly with plenty of running
water for at least 15 minutes. Do not wear contact
lenses when working with this material.
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Material Safety Data Sheet
ETHYLENE OXIDE
Pegs 3 of 4
I
Section 6
Health Hazard Data, Con't
SKINEXPOSURE: Immediately remove clothing and shoes.
Wash con lamina ted skin with soap and water For at least
15 minutes. Contact a physician at once. Treat for
possible cryogenic Injury.
IWWLATIOK Remove exposed person to fresh air. If
breathing has stopped, give artificial respiration, then . _
oxygen if needed. Contact physician immediately.
Section 7
Spill, Leak & Disposal Procedures
SPILL/LEAK PROCEDURES: Treat any ethvlene oxide gas
leak as an emergency. If material is released or spilled,
eliminate all ignition sources. Ethylene oxide/air
mixtures may detonate upon ignition. Evacuate all
personnel from tha area except for those engaged in
slopping Ihe leak or-fn clean up. Cleanup personnel must
have protection against contact with, and inhalation of
vapor (see §8).
WASTE MAKAGEMEWT/oisposAL: Suggested method of waste
material disposal Is by incineration in approved liquid
burning hazardous waste incinerator. It is your duty to
dispose of chemical materials in accordance with
applicable Federal, Stale and local regulations regarding
disposal. Return used drums to manufacturer only.
O3HA CSSIONATIONSt
29 CFR S 1910.1047
40 CFR S302.4
UI IS
10 Ib. (4,54 Kg) per
RCRA S300I
SPECIALLY REGULATED SUBSTANCE:
EPA OESI6MATIONS:
KM. HAZARDOUS WASTE Wj
CERCLARtt
Section 8
Special Protection Information
EYEpooTrcrtoft Always wear chemical safety goggles.
If splashing may occur, wear a full face shield as a
supplementary protective measure. Do not wear contact
lenses when working with EO. Follow the eye and face
protection regulations cited 29 CFR 51910,133.
BespiBATwt Wear a NIOSH approved respirator for
maximum use concentrations. For emergency or
nonroutlne usa wear self-contained breathing apparatus
with a full faceplece operated In the pressure-demand
or positive pressure mode. Refer to OSHA respirator
regulations cited at 29 CFR S1910.I34 and 29 CFR S
1910.1047
Section 8
Special Protection Information Con't
OTHER; Wear impervious gloves (OSHA currently
recommends PVC); boots; aprons; head cover; and clean
impervious body-covering clothing to prevent any
possibility of skin contact. All clothing must be flame-
resistant. Launder contaminated clothing and discard
contaminated leather shoes.
»ORKFLACc COMSI DELATIONS: <«« 29 Cfft * l9IO.tO
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Material Safety Data Sheet
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