Thursday
October 30, 1980
Part XI



Environmental

Protection  Agency

Hazardous Waste Management System:
Identification and Listing of Hazardous
Waste, and Interim Status Standards for
Owners and Operators of Treatment,
Storage, and Disposal Facilities; Final,
Interim, and Proposed Regulations

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    ,.  	"  i''  •••                                '                 ,1    Ij  ijj  	"  11 I      I	'

 72024      Federal Register / Vol.45, No. 212 / Thursday, October 30,1980 / Rules and Regulations
 ENVIRONMENTAL PROTECTION
 AGENCY        ,.        	'

 40 CFf* Pjirts 260 and 261

JSW FRt, 1642-4]
 Hazardous Waste Management
 System; General and Identification and
 Listing of Hazardous Waste

 AGENCY: Environmental Protection
 Agency.
 ACTION: Interim final amendment to rule
 «nd request for comments.

 SUMMARY: This regulation amends 40
 CFR 261.4 to provide that a hazardous
 waste that is generated in a product or
 raw material storage tank, transport
 vehicle or vessel or in a manufacturing
 process unit is not subject to regulation
 under 40 CFR Parts  262 through 265 or
 Parts 122 through 124 or the
 requirements of Section 3010 of the
 Resource Conservation and Recovery
 Act (RCRA) until it  is removed from the
 unll in which it was generated,* unless
 the unit !n which it is generated is a
 Surface impoundment or unless the
 hazardous waste remains in the unit for
 more than 90 days after the unit ceases
 to be operated for the purpose of storing
 or transporting product or raw materials
 or manufacturing. This regulation also
 amends 40 CFR 260.10 to modify the
 definition of "generator" so that it
 clearly covers persons who  remove
 hazardous wastes from product or raw
 material storage tanks, transport
 vehicles or vessels, or manufacturing
 process units in which the hazardous
 waslo is generated. Finally,  this
 regulation amends 40 CFR 260.10 to add
 definitions for "transport vehicle" and
 "vessel." The purpose of this
 requirement is to allow persons handling
 hazardous wastes sufficient lead time to
 prepare lo comply with major new
 regulatory requirements. The effect of
 these amendments is to reduce the
 overall costs, economic impact and
 reporting and recordkeeping impacts of
 EPA'8 hazardous waste management
 regulations.
 DATES: Effective Date: For the
 amendment to 40 CFR 281.4  and the.
 definitions of "transport vehicle" and
 "vessel," in 40 CFR 260.10, November 19,
 1980.
  For the amendment to the definition of
 "generator," in 40 CFR 260.10, April 30,
 1081.
  Comment Date: This amendment is
promulgated as an interim final rule. The
Agency will accept comments on it until
December 29,1980.
 ADDRESSES: Comments on the
 amendment should be sent to Docket
 ,Qler)c [Dock"et ..... No. 300 l],"6ffi ce" of ' Sold
 Waste (WH-565), U.S. Environmental
 Protection Agency, 401 M Street SW.,
 Washington, D.C. 20460.
,|i,
 For general information, contact Alfred
 W. Lindsey, Office of Solid Waste, U.S.
 Environmental Protection Agency, 401 M
 Street, §W., Washington, D.C. 2Q460,
 (202) 755-9i85. For information on
 implementation, contact:
 Region I, Dennis Huebner, Chief,
   Radiation, Waste Management
   Branch, John F. Kennedy Building,
   Boston, Massachusetts 02203," (617)
   223-5777
 Region II, Dr. Ernest Regna, Chief, Solid
   Waste Branch, 26 Federal Plaza, New
   York, New York 10007, (212) 264-0504/
   5
 Region III, Robert L Allen, Chief,
   Hazardous Materials Branch,  6th and
   Walnut Streets, Philadelphia,
   Pennsylvania 19106, (215) 597-0980
 Region IV, James Scarbrough, Chief,
   Residuals Management Branch, 345
   Courtland Street, N.E., Atlanta,
   Georgia 30365, (404) 881-3016
 Region V, Karl J. Klepitsch, Jr., Chief,
   Waste Management Branch, 230 South
   Dearborn Street, Chicago, Illinois
   60604,  (312) 886-6148
 Region VI, R. Stan Jorgensen, Acting
   Chief,  Solid Waste Branch, 1201 Elm
   Street, First International Building,
   Dallas, Texas 75270, (214) 787-2645 .
 Region VII, Robert L. Morby, Chief,
   Hazardous Materials Branch, 324 E.
  llth Street, Kansas City, Missouri
   64106,  (816) 374-3307
 Region VIII, Lawrence P. Gazda, Chief,
   Waste Management Branch, 1860
   Lincoln Street, Denver, Colorado
   80203,  (303) 837-2221
 Region IX, Arnold R. Den, Chief,
   Hazardous Materials Branch, 215
   Fremont Street, San Francisco,
   California 94105, (415) 556-4606    "
 Region X, Kenneth D. Feigner, Chief,
   Waste Management Branch, 1200
   Sixth Avenue, Seattle, Washington
   98101,  (206) 442-1260.
 SUPPLEMENTARY INFORMATION:
 I. Amendment to 40 CFR 261.4
   On February 26 and May 19, 1980,
 EPA" promulgated hazardous waste
 regulations in 40 CFR Parts 260 through
 265 (45 FR 12721 et seq. and 45 FR 33066
 et seq.) and on May 19, 1980,
promulgated consolidated permit
regulations in 40 CFR Parts 122 through
124 (45 FR 33289 et seq.). Section 261.2 of
these regulations provides that a solid
waste is any garbage, refuse or sludge;
or any other waste material which is (1)
  discarded or is being accumulated,
  gjored pi? physically,- chemically or
  biologically treated prior to being
  discarded; or (2) has served its original
  intended use and sometimes is
  discarded; or (3) is a manufacturing or
  mining by-product and sometimes is  '
	"discarded. Section 261.3 provides that a
  solid waste becomes a hazardous waste
  when (1) it first meets any of the listing
  descriptions set forth in Part 261,
  Subpart D; or (2) it first becomes a
  mixture  containing a hazardous waste
  listed in Part 261, Subpart D; or (3) it
  first exhibits one or more of the
  characteristics of hazardous waste
  identified in Part 261, Subpart C. Section
  261.1 provides that hazardous wastes
  identified in Part 261 are subject to
  regulation under Parts 262 through 265
  and Parts 122 through 124. The effect of
  these provisions, particularly § 261.3(b),
  is to make hazardous wastes subject to
  regulation at the point where they are
  generated. The point of generation,
  however, may be a product or raw
  material storage tank, transport vehicle
  or vessel, or a manufacturing process
  unit. A literal application of the Part 261
  regulations would mean that such units
  are hazardous waste storage facilities,
  and that their owners and operators
 must comply with the notification
 requirements of Section 3010 of RCRA,
 submit applications for and obtain
 permits under Part 122 and comply with
 the Interim Status Standards of Part 265
 until a permit is issued  or denied. An
 exception to these requirements is
 provided in § 262.34 which states that
 hazardous waste may be accumulated
 on the site of its generation without a
 permit for 90 days or less before it is
 removed and transported off-site for
 treatment, storage or disposal. For such
 accumulation, the owner and operator of
 the unit must notify under Section 3010
 and comply with § 262.34, including
 requirements for containerization,
 labelling, marking, inspection and
 personnel training.
   Many members of the regulated
 community have questioned the
 Agency's intent and wisdom in
 regulating those units in which
 hazardous wastes are first generated.
 These people claim that such units only
 incidentally hold or treat hazardous
 wastes and thus should not be subject to
 the regulations. They contend that such
 hazardous wastes do not pose a hazard
 to human health or the environment
 while they remain in these units.
   Commenters on this issue provided
 several examples of units in which
 hazardous wastes are generated which
 currently appear to be, perhaps
 unnecessarily, subject to the regulations.

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            Federal Register: / Vol.  4& No. 212 /  Thursday,  October 30,  1980" / Rules and Regulations     72025'
 The..bulk" storage4 of crude: oil: and even
 refined petroleum products,. such as:
 gasoline, frequently. produces:a;sludge ,
 or sediment that periodically, must be
 removed. These sludge/ and, sediments' ':
 are solid wastes under § 261.2 and
 frequently may be-hazardous wastes  .
 . either because they are listed (see EPA
 Hazardous Waste Number K052 in
 § 261.32) or because they exhibit one or
 more of the characteristics Of hazardous
 wastes identified in Part 261, Subpart C.
 The generation of sludges'.and residues
 that are hazardous wastes also can
 occur in the storage of other products
 and raw materials.
   Similarly, sludge's and residues are
 frequently produced in tank trucks, rail
 tank cars and the tanks or holds of ships
 and barges that have carried products or
 raw materials (which are-not hazardous
 wastes). These  sludges and residues are
 periodically removed through washing,
 of the tanks of these transport vehicles
 and vessels. They are solid wastes and
 occasionally are hazardous wastes for
 the same reasons stated above. Where
 these sludges and residues are
 hazardous waste's, these vehicles: and. ,
 vessels technically are hazardous waste
 storage facilities subject to regulation
 prior to the removal of the hazardous
 waste.                 •  .       /
   Other examples occur, in a great many
. manufacturing, processes, where
 hazardous wastes are generated in
 .process units, such as distillation
 columns, flotation units,, and discharge ;
 trays of screens and'in associated non-
 wastertreatment process units such as
 cooling towers.  Many of these
 hazardous wastes are listed in {*§ 261.31..
 and 261.32 (e.g., EPA Hazardous Waste
 Numbers K009 and K010 in §* 261.32).   ^
 Others, are hazardous wastes because
 they exhibit one or more characteristics
 of hazardous wastes (see 40 CFRPart
 261, Subpart C). These hazardous
 wastes.reside in these process units for
 some period of time—sometimes .only
 minutes, other times for hours or days—
 and technically cause these units to be
 hazardous waste storage facilities
 suhjectto regulation.   ,
   Except for surface impoundments, and
 non-operating units, EPA did not intend
 to regulate product and raw material
 storage tanks, transport vehicles and
 vessels or manufacturing process units
 in which-hazardous wastes-are.
 generated. As jepresented by the above ;
 examples, most of these units are tanks.
 or tank-like units [e.g., distillation units)
 which are designed and operated to hold
 valuable products or raw.materials in
 storage or transportation, or during;
 manufacturing. Because of their design
 and operation, these units.are. capable- of
holding, and are typicallyoperated to
hold, the hazardous wastes which are
generated in them; until the wastes: are
purposefully removed. Thus, these
hazardous wastes are contained against;
release into the environment (except, of
course.iwhen abnormal circumstances
such as: fire  or, explosion.pccur) and the
risks they pose to humanJhealth-or the
environment.are very low and are only
incidental to the risks posed^by the
valuable product or raw material with
which they are associated.;Based on
these conclusions, EPA believes it is not
necessary, except as;noted below, to
require owners-and operators of; these
units to obtain permits.for these units or
to comply with the requirements of  '
§ 262.34 or Parts 264 or  265: with respect
to these units.       .              "
  Except where the unltis: a surface
impoundment or is not operating, as
discussed below, the Agency believes
that the hazardous waste generated in
such a unit should only be subject to
regulation when it is removed from.the
unit. In most cases, it is only after the
removal of hazardous wastes from these
units that .the waste's have: the; potential
for releasing hazardous constituents into
the environment,and posing a
substantial hazard to human health, or
the environment.  •
  A.s one exception.to the foregoing,
EPA does not believe that surface;
impoundments, in which:hazardous
wastes are generated should be
exempted from the regulations. These
units, by definition (see 40 CFR 26o;iO),
are formed in or constructed of earthen
materials, and often may not be lined;
with impermeable materials: capable of
preventing leaching. Any hazardous
wastes generated:and accumulated or   .
stored in these units will have a much
greater potential to leach, lealcor:
otherwise escape from these units into
the environment than those: hazardous .
wastes generated and contained in the
tanks and tank-like: units discussed
above. Because ofthis greater potential
for release into the/environment, the.
Agency believes that the hazardous
wastes-generated in surface
impoundments may'pose a substantial.
hazard to human health or the
environment and therefore warrant
regulation even while they remain in the
impoundment. Such regulation.will
ensure that the impoundment is properly
constructed, lined, inspected and;
operated, and that groundwater
monitoring is performed.
  As a second exception; to the;
foregoing, EPA.does not believe that
hazardous wastes;generated'in.
manufacturuig.process units,.or product
or raw material storage  tanks, transport
  vehicles'or vessels should be exempted
  from: regulationwhen.theserwastes
  remain in the.units after they have
  ceased tobe operated fbr:the;primary
  purpose of manufacturing: or product or
  raw materials storage or: transportation.  ,
  EPA believes;that when operation  "
  ceases, the incentive .to maintain the
  integrity of the unit to prevent leaks or
•  other unintended releasei of products,
  raw materials or manufacturing
  intermediates into the environment is
  substantially reduced. Consequently, the
  incentive to maintain the unit to prevent'
  leaks or release, of hazardous Wastes
  which may remaui in the unit after
  cessation of operation would also be
  substantially reduced. As stated.above,
  the rationale for exempting hazardous
  waste frpm regulation while it remains
  in the unit  mwhich'it was generated is
  that the unitwillhaye structural    -
  integrity againsirelease's and,will be
  operated to prevent such releases. The
  Agency believes, that this rationale does •
  not hold after cessation of operation.
   EPA recognizes that manufacturing
  units and product and raw material
  storage tanks; transport vehicles and
  vessels are, occasionally taken out of
  operation for temporary periods that
  may range  from days, to months,.and
  sometimes,years,.because of temporary
  declines in business or other, business
  reasons. Units may also be taken out of
  operation for maintetiance'or repair.
  During these temporary shutdowns,
  hazardous  wastes may remain in these/
  units. The Agency also recognizes that
  these units maybe, permanently taken
  out of operation-and'hazardous wastes
  may remamin them for some period'of •
  time after shutdown. Eor both temporary
  and permanent shutdowns, the Agency .
  will allow a reasonable time to remove
  any hazardous wastes thatrremaln in the
  unit after operation ceases. Given the
  presumption that the unit has integrity
  before cessation of operation, the
  Agency believes that a reasonable time  '
  is 90 days. This time also is consistent
  with the 90-day; accumulation period
  allowed under § 262.34. If hazardous
  wastes remain in these units more than
  90 days after Cessation-of operation,
  EPA believes that these; wastes should.
  be fully regulated'and that the units
  should be regulated as-hazardous waste
  storage facilities. Thus, at.that-point, the
 'owner and operator of the-Unit. would
  have to have interim status and comply
  with the Interim Status Standards: of
  Part 265 or  have a permit under Part 122!
  and comply with permit'conditions.
   Based on the fOregoing;assessment;
  EPA, in this"rulemaking:action, is
  amending the'regulations by adding an
  exclusion provision to § 261.4 which

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72026     Federal Register 7  Vol- 45,  No. 212  /  Thursday, October 30, 1980 / Rules and Regulations
 provides that a hazardous waste which
 is generated in a manufacturing process
 unit or an associated non-waste
 treatment unit, or in a product or raw
 material storage tank, transport vehicle
 or vessel is not subject to regulation
 under Parts 262 through 265 or Parts 122
 through 124 or the notification
 requirements of Section 3010 of RCRA
 until It is removed from the unit in which
 it is generated, unless the unit is a
 surface Impoundment or unless the
 hazardous waste remains in the unit for
 more than(90 days after the unit ceases
 to be operated for the purpose of
 manufacturing, or storing or transporting
 product or raw materials.
 II. Definition of Transport Vehicle anil
 Vessel	i
   Xs Jniicated in the above discussion,
 this amendment deals with hazardous
 wastes that are generated in product or
 raw material transport vehicle^ and
 vessels, as well as those generated in
 manufacturing units and product or raw
 material storage tanks. Because the
 terms "transport vehicle" and "vessel"
 4r^ not currently defined in §  260.10, »
."definitions	of these terms are  included	
 in this amendment. These definitions are
 the same as those in the Department of
 Transportation regulations governing
 the'transportation of hazardous
 materials {see 49 CFR 171.8).
 III. Generator Responsibilities and
 Amendment to 40 CFR 260.10
   Many members of the regulated
 community also have asked the
 question: Who is the generator of
 hazardous wastes that are generated in
 manufacturing process units or in
 product or raw material storage tanks,
 transport vehicles or vessels? These
 persons point out that, with respect to
 stationary product and raw material
 storage tanks, it is quite common for one
 person to own and operate the storage
 lank, a second person to own the
 product or raw material being stored,
 and a third person (usually under
 contracT £o»either the first or second
 person) to remove and dispose of
 sludges, sediments and residues that
 may have been formed in the  tank. It
 also is .common for the owner and
 operator of the tanlc to also own the
 stored product or raw material, but to
 hire another person to remove and
 dispose of sediments and residues
 formed in the tanks. There are
 situations, of course, where the three
 parties are one person, or where more
 than three parties are Involved.
   The same scenarios occur with
 respect to tank trucks, rail cars, and
 ships and barges. However, these
 scenarios are commonly complicated by
 two additional practices. Oftentimes
 these transport vehicles or vessels are
 taken to a central facility for removal of
 sediment and residues and attendant
 tank washing or cleaning. Frequently,
 this central facility is owned or operated
 by a person other than the owner or
 operator of the vehicle or vessel and,
 even more frequently, other  than the
 owner of the product or raw material
 that produced the sediment or residue.
 Secondly, the residue or sediment
 cleaned and removed from a vehicle or
 vessel may have been produced by two
 or more products, thus bringing into the
 picture additional parties—'the owners  -
 of two or more products. This situation
 catfalso occur, but is less common, with
 stationary storage tanks.
   With respect to manufacturing units,
 the situation typically is not
 complicated. Usually, the same person
 owns and operates the unit,  owns the
 manufacturing materials that may ,
 generate a hazardous waste and
 removes any hazardous wastes
 generated in the unit. However, there
 are situations where two or more parties
 are involved. One such situation is
 where a second party is periodically
 retained to  clean a unit. Another
 situation is where the hazardous waste
 is produced by the processing of
 materials that are owned by two or
 more persons. This occurs in the
 reclaiming of spent solvents and spent
 catalysts where the reclaimer custom-
 pMcesses batches of spent material
 without taking ownership of the ••
 material.
   The definition of "generator" in
 § 260.10 is "any person, by site, whose
 act or process produces hazardous
 waste identified or listed in Part
 261 * "  *." This definition suggests that
 the operator of a manufacturing process
 unit or a product or raw material storage
 tank, transport vehicle or vessel is a
 generator of a hazardous waste because
 it is his "act" of storage- or
 transportation or his "process" of
 manufacturing that produces the
 hazardous waste. In the case of storage
 or transportation, the act of holding the
 product or raw material enables settling
 of heavy fractions of material to create
 hazardous waste sludges or  sediments
 and enables hazardous waste residues
 to adhere to the tank. In the  case of
 manufacturing processes, the process of
 manufacturing produces the  hazardous
' wastes.	:	
 *  The owner of the product or raw
 material being stored or transported and
 the owner of the materials being
 manufactured also fit the definition of
 "generator" of the hazardous waste
 because their "acts" cause the product
or material to be stored, transported or
manufactured which leads to the
generation of the hazardous wastes.
Additionally, it is constituents in their
product or material that "produce" a
hazardous waste.
  The definition of generator,
particularly when read in conjunction
with the amendment discussed above,
also fits the person removing the
hazardous waste from a manufacturing
process unit or a product or raw
material storage tank,  transport vehicle
or vessel. Although often it is not his
"act or process" that produces the
hazardous waste, it is  his act that
causes the hazardous waste to become
subject to  regulation (except where it is
generated  in a surface impoundment or
remains in a non^operating unit for more
than 90 days after cessation of
operation)..*
  The definition of generator, depending
on the particular factual situation, can
include all of the parties discussed
above. Both the operator of a
manufacturing process unit, or a product
or raw material storage tank, transport
vehicle or  vessel, and the owner of the
product or raw material act jointly to
produce the hazardous waste generated
therein, and the person who removes the
hazardous waste from a tank, vehicle,
vessel or manufacturing process unit
subjects it to regulation. All three
parties are involved and EPA believes
that all three (and any others who fit the
definition  of "generator") have the
responsibilities of a generator.
  Because all three parties contribute to
the generation of a hazardous waste and
because none of the parties stands out
in all cases as the predominant
contributor, the Agency has concluded
that the three parties should be jointly
and severally liable as generators. The
Agency will, of course, be satisfied if
one of the  three parties assumes and
performs the duties of the generator on
behalf of all of the parties. In fact, the
Agency prefers and encourages such
action and recommends that, where two
or more parties are involved, they
should mutually agree to have one party
perform the generator duties. Where this
is done, the Agency will look to that
designated party to perform the
generator responsibilities. Nevertheless,
EPA reserves the right to enforce against
any and all persons who fit the
definition  of "generator" in & particular
caseif the requirements of .Part 262 are
not adequately met, providing such
enforcement is equitable and in the
public interest.
  .Given this cgnclusign,, the Agency
belijivesitjfias&jioSiigatipn.to.giye ,
guidance to the regulated community on
who it prefers to assume the generator

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               Fgderal Register / Vol.  45, No. 212 / Thursday,  October 30,  1980 / Rules and  Regulations     72027
     responsibilities and to whom it will;
     initially look to perform the generator
     duties where more than one. party is
     involved and where EPA-does not know*
     which party, by -mutual agreement, is •
     appointed to carry put the generator     •
     duties, or where no party has been so
     designated. In the: case of hazardous
   .  wastes generatediin a"stationary
     product or raw material storage tank,
     EPA will initially look to tlie operator of
     the tank to perform the generator
     responsibilities. EPA believes=that this
     party is in the  best-position to.perform
     the,generator responsibilities. The
     operator typically"is,on-site and Can   -"
     determine when a tank contains sludges
     or residues that may be hazardous'
     wastes'. He certainly knows or ought to
     know when these sludges and residues-
     are being removed and, itherefore, when
     they become: subjecttb-Eegulatibn, if:
     they are a hazardous waste. Because he
     is typically on-site* he is in a good
     position to carry out those duties of a:
     generator which-practically must be.
     performed on-site. These'include
     determining'whether a hazardous waste'
     exists {& 262.11), initiating a manifest for
     off-site shipment (Part 262, Subpart B)
     and performing the pre-transportation '
     requirements of packaging, labeling and
     marking (Part 262, Subpart C).
      For hazardous wastes generated in a
  •   manufacturing process unit, EPA will
     initially look;to the operator of the unit
     to fulfill the generator duties for the
'     same reasons: described above.
      For hazardous.wastes generated in a
     product or raw material transport
     vehicle, or vessel.which are removed at a
     central faculty which is operated7 to
     remove'sedlments and residues from
     such vehicleS;Or vessels, the Agency will
     initially look to the" operaforof the
     central facility to perform the generator
     duties. Following the reasoning outlined
     above, the Ageftcy believes that .the _
     operator of a central facility is the party
     best able to perfbrm the generator
     duties. Where  hazardous  wastes
     generated in product or raw material
     transport vehicles or vessels are npt
     removed at a central facility, the'Agency
     will look to the operator of the vehicle
     or vessel to perform the generator
     duties.     '.',":•            .
      As .discussed above, the person who
     removes hazardous waste from a
   ^  manufacturing process unit or a product
   '  or raw materials ;sterage tank, transport
     vehicle or vessel will be jointly and
     severally liable, along with the owoier
     and operator of the tank, vehicle, vessel
    •;Or unit and the owner of the product or
     raw material, as a.generator. To clarify
     that such persons are included in the
     definition of generator, the Agency, in
 this rulemaking action, is amending the
 definition of "generator" in §, 260.10 by
 addihg'a final clause so that the
 definition reads,"* * * any person, by
 site, whose'act or process produces a
 hazardous waste'identified or: listed'in
 Part 261,of this Chapter or whose act:
 first causes a hazardous'waste to
 become subject to regulatipn".":

 IV. Accumulation of Hazardous Wastes
   A number of questions have been
.asked1 about whether unhazardous
 wastes removed from product -or raw
 material-storage tanks; transport
 vehicles or vessels or manufacturing-
 process units "can be accumulated on-
 site without a permit for up to 90 days
 after removal and prior;to off-site
 transport in accordance with §262.34
 Because today's amendment to §261.4
 subjects such hazardous wastes to  ,,
 regulation only after they are removed
 from such tanks, vehicles, vessels pr
 units and because there often will be a
 need to. accumulate the removed wastes
 until a sufficientquantitjrcan be
 obtained for off-site transport,vthe
 Agency believes that the 90-day
 accumulation provisions of §262.34
 should be available: to the generators of
 these hazardous wastes; except where
 these wastes are generated in a; surface
 impoundment ot the wastes remain in
 the unit mtire than 90 days following  >
 cessation of operation of the unit
^ This allowance: of 90-day
 accumulation: iivithout a permit is
 available" to any of the persons who. are
 generators, even though the party
 accumulating the waste on-site may not
 own or operate the site: This allowance
 only applies where the accumulation
 occurs on the site where the removal of
 hazardous waste from the tank, vehicle,
 vessel  or unit takes place; all of the
 other conditions and requirements of
 § 262.34 must, of course, be met. The,S0-
 day:accumulation period staj-ts when
 the hazardous waste is removed from"
 the tank, vehicle, vessel or unit, except
in the case where, a tank, vehicle, vessel
or unit ceases to be operated for its
primary purpose, in which case the
period  starts when operation ceases;

V. Notification and EPA Identification
Dumber Requirements
  A number of questionSfhave been
asked about how the notification
requirements of Section.3010 of RCRA.
and the EPA Identification Number
requirements of §262,112 apply to;
generators of hazardous wastes
generated in manufacturing process .
units or product or raw material storage
tanks, transport vehicles or vessels.
Today's amendment to,§261.4 provides
that such wastes (not including;those.
•  generated in surface, impoundments or
  retained for more than: go days in non-
  operating units) are not subject to
  regulation, including.section 3010    '
  notification,, until they exit the units in
  which they are generated. Thus, only
  those wastes that are removed during a
  future, notification: period are subject to
  notification.     ...
    Section 262:12, though, required that a
  generator must not treat, store," dispose'
  of,'transport or offer for transportation a
  hazardous waste without haying1 an EPA
  Identification Number. Section 260.10
  defines a "generator" to be a person "by
  site" who generates wastes. Therefore a~
  generator must have a: separate" EPA
  Identification Numbei>'for,'each site at
- which he'generates hazardous wastes.
  Where two: or, more personsiare
  generators,-, as, discussed.ahove, the
  person who performs the duties of a
  generator'mustrhave and:use; an EP.A
 . Identification Number for the site, at
  which hazardous.wastes are removed
  from a tank, vehicle, vessel or unit.,
  Thus,,i£"the operator of tfie. tank, vehicle,
.  vessel or unit performs the generator
  duties,,he must have an EPA
  Identification Number for the facility
  and can use.that'number with respect tbj
  the management of'all: of his hazardous
  waste generated'at thatfacility; If the
  owner of the product; or raw material
  performs the'duties; of the generator, he;
  must have and use an EPA" identification
  Number for the site at which the
 hazardous waste-is generated;.if he"
  owns products being stored or
 processed:at: several sites, .he must have
  and use:a separate EPA Identification:
 Number.for each site.,If the person who
 removes hazardous. wastes:from.tanks:
 or units performs the generator duties,
 he must have:a separate EPA.
 Identification Number,for-:each site.at
 which!he performs these duties.
 VI. Effective Date
   Section 30lti(b) of RGRA provides that
 EPA's hazardous waste regulations and
 revisions thereto take effect six months
 after their promulgation. The  purpose of
• this requirement is. to allow persons
 handling hazardous wastes sufficient
 lead time to prepare to eomply!with-
.majbr new regulatory requirements: For
 the amendment to § 261v4 promulgated
 today, however, the Agency believes,
 that  an effective date.six months after
 promulgation would cause, substantial"
 and unnecessary disruption hvthe,
 implementationiof the regulations and
 would be: counterproductive: for. the:
 regulated community and: the public.;
 The regulatory provisions that these
 amendments modify take effect on
 November, 19,1980. In the absence of the
 effectuation of these amendments*.

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72028
Federal Register / Vol. 45. No. 212 / Thursday, October 30, I98o" /  Rules and Regulations
operators of a large number of product
and raw material storage tanks,
transport vehicles and vessels, and
manufacturing process units in which
hazardous wastes are generated would
have to prepare to operate these
facilities as hazardous waste storage
facilities on and after November 19,
10^0. This would involve preparation
and submission of a Part A permit
application, preparatlori of a
contingency plan and implementation of
a number of administrative and
operational practices required by Part
205 for hazardous waste storage
facilities, the Agency believes it makes
little sense to allow these requirements
promulgated on May 19 to become
effective on November 19,1980, and
then have them substantially modified
on a subsequent date, i.e., the six-month
effective date for these amendments.
  The amendment to § 261.4 in effect
suspends regulation of certain facilities
by clarifying when certain hazardous
wastes are first subject to the hazardous
waste regulations. This lessening of
regulatory requirements surely is not the
type of revision to regulations that
Congress had in mind when it provided
a six-month delay between the
promulgation and the effective date of
revisions to regulations. Consequently,
the Agency is setting an effective date of
November 19,, I960,	for the jamendment	
to § 261.4 promulgated in this
rulernakmg action,
  The definitions of "transport vehicle"
and ''vessel" are necessary for an
understanding of the amendment to
| 261.4 and consequently they too have
an effective date of November 19,1980.  ,
  EPA is making the amendment to the
definition of "generator" effective six
months after promulgation, as provided
In Section 30lb(b) of RCRA. Although
many persons who remove hazardous
wastes from manufacturing units or from
product or raw material storage tanks,
vehicles or* vessels, recognized that in
certain situations they fell within the
May 19,1980, definition of generators,
the amendment to the definition will
probably make some additional persons
generators. These people undoubtedly
deserve the six month lead time that
Congress provided in Section 3010(b).
All persons who fit the May 19
definition of "generator" must comply
with all applicable generator
requirements on November 19,1980.
Only those persons who are made
generators by today's amendment to the
definition have an additional six months
before they must cbmply with Part 262
requirements.
                             VII. Regulatory Impacts
                               The effect of these amendments is to
                             reduce the overall costs, economic
                             impact and reporting and recordkeeping
                             impacts of EPA's hazardous waste
                             management regulations. This is
                             achieved by removing from regulation as
                             storage facilities product and raw
                             materials storage tanks, transport
                             vehicles and vessels, and manufacturing
                             process units that generate hazardous
                             waste. The Agency is unable to estimate
                             these cost and impact reductions
                             because it does not have an estimate of
                             the number of such tanks and units that
                             otherwise would be regulated. For the
                             reasons already discussed,
                             notwithstanding these cost and impact
                             reductions, the Agency believes that
                             human health and environmental
                             protection will not be reduced by this
                             action.
                             VIII. Request for Comments
                               The Agency invites comments on all
                             aspects of these amendments  and on all
                             of the issues discussed in this preamble,
                             including the interpretation of  '
                             "generator," the allowance of 90-day
                             accumulation to all generators, and the
                             notification and EPA Identification
                             Number requirements. EPA is providing
                             a 60-day comment period.
                               The Agency also invites comments on
                             whether the amendment should also
                             apply to hazardous wastes generated in
                             product or raw material containers other
                             than transportation vehicles and vessels
                             (see ,| 260.10 for definition of the term
                             "containers"). The Agency has not
                             applied this amendment to such
                             hazardous wastes because it is not
                             aware that significant amounts of
                             hazardous wastes are generated in
                             product or raw material containers
                             (exclusive of transportation vehicles or
                             vessels).
                               The Agency recognizes that a wide
                             variety of situations exist in the real
                             world, and it is anxious to make its
                             regulations and regulatory
                             interpretations reasonable, *
                             understandable, and capable  of
                             implementation. The Agency can only
                             do this by learning of situations where
                             the regulations do not work well.
                            ,   Dated: October 24,1980.                '
                             Douglas M. Costle,
                             Administrator.
                               Title 40 of the Code of Federal
                             Regulations is amended as follows:
                               1. Add the following paragraph (c) to
                             § 261.4:
                                               Jt
                             §261.4  Exclusions.
                             ft    *     *    A    *
                                (c) Hazardous wastes which are
                             exempted from certain regulations. A
 hazardous waste which is generated in a
 product or raw material storage tank, a
 product or raw material transport
 vehicle or vessel, or in a manufacturing
 process unit or an associated non-
 waste-treatment manufacturing unit, is
 not subject to regulation under Parts 262
 through 265 and Parts 122 through 124 of
 this chapter or to the notification
 requirements of Section 3010 of RCRA
 until it exits the unit in which it was
 generated, unless the unit is a surface
 impoundment,  or unless the hazardous
 waste remains in the unit more than 90
 days after the unit ceases to be operated
 for manufacturing, or for storage or
 transportation or product or raw
 materials.

 §260.10  [Amended]
   2. Amend the definition of
 "Generator" in § 260.10  to read as
 follows:
 *    *    *   V*    *
   Generator means any person, by site,
 whose act or process produces
 hazardous waste identified or listed in
 Part 261 of this chapter or whose act
 first causes a hazardous waste to
 become subject to regulation.
 *    »    *    *    *
   3. Add the following definitions to
 § 260.10:
 *****             '  ,
   "Transport vehicle" means a motor
 vehicle or rail car used for the
 transportation of cargo by any mode.
• Each cargo-carrying body (trailer,
 railroad freight car, etc.) is a,separate
 transport vehicle. "Vessel" includes
 every description of watercraft, used or
 capable of being used as a means of
 transportation on the water.
 [FR Doc. 80-33808 Filed 10-29-80; 8:45 am)
 BILLING CODE 6560-30-M

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                Federal'Kegrster; //ybl.,45, .No> 212- /•' Thursday; QctoBep 30/1980: /> Proposed
ENVIRONMENT^!: PRQTEGTION
AGENCY'

40'CFHtPart 281*       .

[SWFRO-163SS13J?  .::••..•..••-

Hararcfous'Waste Management! ~"~
System^ldehtificatfoniatKiaJsting-of;
HazardousWastes:

AGENCY; EnvironmentarProtection •-
Agency;     .
ACTION: Proposed rule.

SUMMARY: Pursuant to'Se^tion-3001 of?
the Resource^Goirservatibn'and
Recovery'A!ctlofr1976r as' amended'
(RCRA), thVEhvifonmental Protection
Agency is'proposing'tb amendine
characteristic :of Extraction Procedure
(EP) toxicity (40X3FR 261.24; 45'FR'
33122] !tb "apply; to 'hexavalent chromium;
instead'of-'tfatal'cKromium. Ttie effect of:
am'endlng;thV EP toxicity'characteristic-
will ,be't6"n"aTrQw th'e'scope:of the'-EP"'
characteristic;' makihyit "applicable tb'a
more limited category of •chromium-
containing"wa-stes; Th'ese'wastes1 will
then be subject ta"the~mana"geirrent:    ;
standards-issued" by 'EPAjirrder Sectionst
3002 throxtgh-3006"srrd;3010 of RCRA ,
(Parts 262;throughl'265V 122 through 124  .
of this Ghapter:atid-45FR 12746); Assart-
of this propxfsal; the'Agencyls'proposihg*
a new'analyticalmethVdfbr use•irr
analyzi^g; wa:ste"extracts' fbrthe'
presence of nexavalent'chromium:
DATES: ERA-will:accept public.  .
comments on the proposed amendment
untirDecemHer .30^ 19$0r Any, person
may request,a h'earifigpn'th'is proposal'.
by'filing"a request with Jphn'P.'L'ehman,.
whose address, appears below, by
November 2D;M98"Ot'the request'musf '
contain the information prescribed'in
§ 260.20(d) of this chapter.
ADDRESSES: Comments'should'be
addressed*td 'Docket"Glerlci Office' of»
Solid. Wa.ste [WH*-562],,U.fS.-
Environmental Protection -Agency; 401 Mil
Street;,SW;, Washington; D.G. 20460.
Reqyests for: healing should ,b"e
addressed to JphnP;,Lehman,Director;.
Hazardous: and Industrial Waste
Division, Office: of Solid Waste [WH-
565], ILS. Environmental-protection
Agency, Washington, D.C -20460.
Communications, should lidentify/the •
regulatory 'docket number; "Section 3001
chromium standard."
  The public docket for this proposed
rulemaking iSilbcatedinrRoofli 2711,-U.!S.
Environmental Protection- Agencyr 401 M:
St.VSW:.%Wash'iiigton; D.d. 20460 an'djis;
available fbr.viewing.ffom 9:00"a.m.-ta,
4:00 n,m.-, Monday; thEoughiEriday,.
excluding holidays;
FOR FUfiTHER- INFORMATION CONTACT;
Matthew AvStfausf 0fffce=of:'SpHd;
Waste [WH-565], U.Sr Ehyirqnmental"
                        '
Washington? i5,G; 20460;. (202} 755--9i87; .
SUPPLEMENTARY INFORMATION: The
Environmental Protection •Agencyiis'
proposing^ today, to'iamend ^the
characteristic .of -£P" tbxicity, (4o:GFR'
261.24,- ,4S"ER"33122):tb apply; to .
hexavalent xKromiiim instead=of total*
cHromium. TKis.preamb'le.describes tKe
reasons, for : th'isrproposed'am'endment.v
the precise.standard being, proposed,
and a proposed'new, analytical method:
for distinguishihgjbetweenJri- and.
hexavalent .chromium;

IlBasis For a Distinction' in the
Hazardous Waste Management
Regulations Between Thef Different '
Valence States of 'Ghromium-
.  On Ktay 19 and; Jiily,16,_:1980; EPA
publislied'itsdnitial'regulations-
implementing-Section,3001-of.the
Resource-Cbnservatibn^ind Recovery,
Act of i976lRCRA;);  as. amended (see, 45,
FR 330845and 47832). These regulations,
define.the scop.e.-ofia comprehensive
Federal and State-program to ^effectively
control-themanagementoffhazardbus.
wastes..
  Under the'se-regulations,- a, solid waste"
becomes ,subj ect to , the. hazardous ^waste
management .system.in. either of .two..
ways: the.speclfic.wasteJslisteddhPart'
261 Subpart D (45 FR 33122-33124), , or
exhibits any of the characteristics of
hasiardous'waste identified in Subpart'G
(45 FR 33121^122)? Thff-criteria for listing'
hazardous wastesrand".the;characteristic
of EP-toxicity 'are ;based..upon. the; total
chromium" present ".ihsthejwastecand'in
the waste extract respectively,' without ;
differentiating the :type:'af 'chromium
presentT.These;regtilations*thus:spBcify,
"chrpmium.:a]rd:cqmpounds,i hhO-Sv" as:
hazardbusrconstituents ;f Or purposesrof
listing-hB2"ardouSi.wa"stes;(iise:Ap"p;en"dix.
VJILto:Part261,',45;ERCat 33132); .and'"
specify a~maximvim:concentrationr;level .
for "chromium" 'wherrideutifying; waistes *
by, means of, 'the;EP toxicity;   '
characteristic:.(See;|s 261.24^ 45 ER'at
33122i) A-numb"er,rof wastes listed in the
May and  July ragulation's'-contain •
chromium -as a. constituent?of concertf
(specifically EPA-Hazardous Waste Nosi
F006, K002-008, K048^05i; K05'3*058,'
K061-063; K069; K074,' Kg78rp82, K086,
and Kp9,OfQ92!)« Addifibnal wastes-raire
exi3ect^ditb;beidentified"«s hazardous
Because -they fairtherEP 'tbxicityj.
characteristic idr"ch"romium.
  (Shromium; however ."i.occars- in-a"1 • • ••' •' •
number-tifivalence^tates, of wKich':the:-
trivalent^GrifUI)) and.the"hexavslents
(Cr (Vi))^are,environmentallyr
significanti17Theas'if.;they'
contam:hexavalent toKromium.-
  The Agency, has reviewed these'*
,comm"ents7carefully,' and'has-'conducte'd
its-own" investiga'tibn-of'this'questibn in-'
promulgatingithe=regulatibns"and-in •
response1 to "the1 comme'ntsv W& believe'
that-th&;toxioity'an'd'envifo'nm'ental'fate"
of'tf iValent chromium merits further:
study, and'we tatend'tb investigate-
these-questibns'furth'er. It'is'iour7
conclusion, However;- that at the present^
time the hazardous:wa:ste management5
regulatibns"sKould;be amended" to'-reflect'
a distirrction'b'etween''trivalent'and':
hexavalent cKrbmium; I;he:principal'  .:.
points 'ofidistiftctioffbetweert the'two
types of chromium"which we'believe-
justify this regulatory.'amendm'ent^aTe^
the differifigtdxtGities andHhe differing-:
potentials-fbr'migratioH'and'mobility of'
chromium (III)-and .chrqmiuffl'(yi), -and '•
therapp'arentlow likelihood that;
trivalent"cHromium-will;oxidize to;
hexavalefat'chromium under most? .
plausibly-occurrihg" types ;ofiimproper!
waste TnanageMertt^Theseidistinctions;
are. discussed in more ;detai.l !belbw..

A. DJstmctipnsJh tHe. Environtnental
Hazards.Eosedtiy/Tfivalentand'
Hexavalent.CJfromium
  It is generally agreed among;the:
scientific,'cbmmunity.*thatthe;available
data'showrthatrtrivalent .chromiumrfsi
less toxicthantheiHexavalent form; The;
carcinogenicity of rvarrous: hexavalent:
chromium compounds in human ;and.
.animal models has been well
documented (NASi 1974;' NIO'SH;: 1975;
U.S. EPA, 1978). EPA's'Carcinogen"
Assessment iGfoup (GAG) has?
determin'ed:thatithereiis:substantiali
evidence that hexavalentichromium:
compoundstaf e carcinogenic tanan.
Data onithe;carcin"ogenicity»of, tnvalent.
chromium:aTedriade'qua.te: There ;have".
been no epidemlolagical!studies:om
woTkersrusing;trivalent:chromium' .
compounds; iatsishowed^aiweak-i
carciHbgenic:respon"seit03chromium'"(ni)
  1 ChMmiuntvaleneeiBtateS of>-r?Cto;+.Oli&ve3 :
been reported, tut Most of?thesetarg'toor ynstable:to.»
be of!significance ih-bipjogical and environmental.
processes. See generally, V.S.:'BPAf'WatSi<-IfSlated"
Environntentol-fati'offlS&ffiority.PalliMtits-.ViA.
I, EPAi440/4i784)2Sa (1978)-.'

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      72030        Federal Register  / Vol. 45, No. 212 / Thursday, October 30, 1980 / Proposed Rules
      acetate. (Hueper and Payne, 1962;
      Mallont. J974).
        It fs further agreed that only
      hexavalent chromium presently is
      known to pose a serious threat of
      mutagenicity. Chromuim compounds
      induce chromosomal abberrations in
      human and animal leukocytes, and
    ,  mutations in bacteria and yeasts (EPA,
      1978; PetrilU and deFlora, 1977,1978;
      Nakumoro, 1978). in these studies,
      trivalent chromium compounds have a
      weak response, while hexavalent
      compounds show significantly higher
      activity.
        Acute and chronic toxicity problems
      associated with exposure to hexavalent
      chromium include penetrating skin
      ulcers, perforation of the nasal septum,
      |nfianit^ation of the larynx, as well as
      Sarnage to Kidneys and lungs. (Casarett
      and Doull, 1979; WAS, 1974; NIpSH,
      1975; BovettetaL, 1977.) these effects
'     do not occur  upon exposure to
      chromium (III). Hie only well-
      documented adverse consequence of
      exposure  to trivalent chrome is allergic
   *  dermatitis (also a property of
      Hexavalent chromium compounds)
      (Casarett and Doull. 1979)*
        Various direct applications of
      Irivalent chromium to humans are
      actually considered to be desirable.
      Trivalent  chromium is required for
      proper metabolic functioning. It serves
      as a cofactor for the action of insulin,
      and is necessary for normal glucose
      utilization (Toepfer, et al., 1977). The
      Food and Drug Administration also has
      approved thejise of trivalent chromium-
      containing pigments in cosmetics. (21
      CFR 73.2326 and 73.2327.) No such
      applications of hexavalent chrome have
      been approved, nor are they considered
      to be beneficial.
       Thus, at the present time, there are
      well-recognized distinctions between
      the human health and environmental
      hazards posed by tri- and hexavalent
      chromium.
      B. Ptfigratory Potentials of Trivalent and
      Hexavalont Chromium
       Trivalent chromium appears to have
      significantly lower migratory potential
      than hexavalent chromium, and to have
      significantly less mobility should it
      migrate from a waste matrix. Most
      trivalent chromium salts are virtually
      insoluble. Trivalent chromium,
      moreover, is strongly adsorbed by clays
      and by organic soil materials (U.S. EPA,
      1978, Bartlett, 1976; and Griffin, 1979),
      decreasing the possibility of exposure
      via a groundwater exposure pathway
      even If migration occurs. In contrast,
      ' * Viirimit aquatic species likewise are more'
     «u»cc|itil!r to I'ic hexavaicrtl form of chromium,
hexavalent chromium salts are very
soluble and therefore have high
migratory potential,
  Groundwater and leachate monitoring
data submitted by various leather
tanners appear to confirm the relative
immobility of trivalent chromium under
normally-occurring waste disposal
conditions. (See, e.g., Comments of
Tanners' .Qouncil of.America, August 18,
1980, pp. 7-13; Comments of Dr. Robert
M. Lollar, Technical Director of Tanners'
Council, August 12,1980, pp. 6-7.) In
addition, the Agency has obtained
groundwater and leachate monitoring
data from sites accepting large
quantities of tannery waste (which
wastes contain high concentrations of
trivalent chrome), in some cases for long
periods of time (from 20 to 86 years).
These sites show no evidence of
chromium contamjnaJlQnpf	
groundwater. (Comments of Berwick
Sewer District, June 30,1980; Comments
of Irving Tanning Co., July 15,1980.)
Groundwater contamination did not
occur even in cases of prolonged worst-
case management of trivalent chromium-
containing wastes (see Comments of
Wolverine World Wide, Inc., August 15,
1980, Attachment 1, pp. 2, 9-13
(improperly sited landfill with high
water table and permeable soil co-
disposfng tannery wastes with other
industrial wastes without any particular
precautions still does not show evidence
of trivalent chromium groundwater
contamination)).
C. Potential of Trivalent Chromium to
Oxidize to Hexavalent Chromium
  In developing the present regulatory
regime based upon total chromium, the
Agency was aware of the differing
potentials for hazard of tri- and
hexavent chromium, and also of their
differing migratory potentials. Our
concern was that trivalent chromium,
under waste management conditions,
could oxidize to the hexavalent form,
which would render,it highly mobile and
toxic. (See, e.g., U.S. EPA, Listing
Background Document for Leather
Tanning and Finishing Industry, pp. 733-
34, May 2,1980.) Further analysis
indicates, however, that such oxidation
is not likely to occur under most waste
management practices. Although the
oxidation of trivalent chromium can
occur on a theoretical basis (Carlin,
1965; U.S. EPA, 1977), oxidation is
unlikely to occur'in normal land
disposal situations. Thus, oxidation does
not take place except under alkaline and
aerobic conditions (Robertson, 1975).
Even then, the rate of oxidation is very
slow unless manganese dioxide is
present (Schroeder and Lee, 1975). These
conditions are not ordinarily found in
landfill or impoundment disposal
situations, since these are typically
anaerobic environments. (Ham, 1979.)
Monitoring data submitted in comments
likewise supports the conclusion that
oxidation of trivalent chromium is
unlikely when these wastes are land
disposed. (See Comments of Alley,
Young & Baumgartner, Inc., July 11,1980;
Comments of Salz Leathers, Inc., July 14,
1980, exh. B.)3            '     .
  Given the relatively low toxicity of
trivalent chromium, its low migratory
potential, and the lack of indication of
potential for oxidation under usual land
disposal conditions, the Agency does
not believe that land disposal of
trivalent chromium-containing wastes in
common landfill or impoundment
situations poses a present or potential
hazard to human health or the
envirqnnjentvia soil migration  to
groundwater. We therefore believe it
necessary to recognize a distinction
between tri- and hexavalent  chromium-
containing wastes when land disposed.
  Our research indicates, however, that
trivalent-chromium oxidizes to  the
hexayalent form when materials
containing chromium (III) are
incinerated or similarly treated by a
destructive oxidation process. The
incineration ash will certainly be
contaminated with chromium (VI)
(Comments of Tanners' Council of •
America, supra, p. 6), and we expect
that hexavalent chromium will  be
present in incinerator emissions as well
(U.S. Dept of the Interior, 1979). As a
result, we believe that chromium-
bearing wastes [i.e., wastes containing
both valence types) continue to require
Subtitle C regulation when managed by
incineration or similar processes. Our
contemplated regulatory approach for
these wastes is described in Part II. C
below.

D. Impact of the Proposed Distinction
On Other Regulatory Programs
  We note, at this point, that certain
other of the Agency's regulatory
programs regulate on the basis  of total
chromium. Our porposed action involves
only the hazardous waste management
program, and is based on a perceived
distinction in the substantiality of
hazard posed by tri- and hexavalent
chromium-containing Wastes when
disposed on land.
  Different considerations underly the
Agency's other programs. For example,
  3 Ultraviolet light-sensitized oxidation of trivalent
chromium has been demonstrated under laboratory
conditions (Stephens, 1977). This oxidation did not
take place, however, when lake water was tested.
In any case, we do not believe that these
experimental conditions reflect those normally
occurring in a waste disposal environment.

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               Federal Register  / Volt 45y No. 21g/'Thursday;. Qctobief 30? 1980  /  IfropoSfed'Rotes?        72031'
the National Interim Primary Drinking-
Water standards are for total.chromiumv
This is because prertreatment'of-
drihkirig, water;by chlb.rihation 'may
result in oxidation.of trivalent
chromium. .(Guidelines Jor Caffardian-
Water Quality^ 1978; Sorg;,1979;U;S;,f
EPA, 1976.) Total chromiunvis thus th'e
appropriate parameter; (0.S. EPA, 1976.)
  All chromium'compourids also -are1-
regulated as toxic under the,Glean,
Water, Act (CWA). In part, this reflects,
the Gong5essiohal -determination to .list -.
all chromium compounds as;toxic;
pollutants- under CWA,Seetion'307fa)(T).
In addition, the Administrator Kas"a
great deal of flexibility in'making listing;
(or delistjng) determinations under"
CWA,Sectibn,307. He  is to consider a
•series *bf.enumerated factors, ,tb. assign
appropriate weight to  eacti, .andto-
arrive at a final determination by
balancing"the;different elements. "Hie:
identification'processcunderrRCRA is:
much less -flexible rand'is to some extent
more stringent,' in ligtit of. the*
significantly moteimpactive;
consequences of a RCRA hazardous
waste' determination. .Thus, .wastes .are
not to be identified'as hazardous .unless
they are capable of posing: a'-.
"substantial" hazard to human-healtlror
the environment. In light of these
differing statutory "schemes; regulatory
action affectmg,chrbmiuiH-containiiig
wastes Basrno'direct b'earing'Brf the*
status of.chromium as a'toxic pollutant
under CWA Section 3107[a):   "

n. Regulatory, Action
A. Propo'saLTo. Amend the"
Characteristic of'EP. Toxieity
  In.order to, reflect the differing;
environmental hazards posed by.
trivalent and hexavalent chromium--
containing wastes.wheft-disposed on
land/the:Agencyds;proposingto amend
the extraction procedure to'apply-tt^
hexavalent chrome1 instead of tb total
chromiunf. We -are nat,' however,"
prpposifig'tb change'thVfflaxiirium"
concentration level'of Hexavalent'
phromium in the ,EP" extract,. whicH
would consequently remain at iS.Omg/l.,
Thisrlevel isbased.on.the:National
Interim Primary Drinking Water:,
Standard,- which iwa's'established to
reflect'the known toxieity of the=
hexavalent form:4 (Sorg,'l1979r U.S. EMi
1976*.) 6C3ther countties:arrd"
organizations also have adopted'thia.
  * The maximum concentration le Vel of the EB
toxieity characteristic, of course, is established at.
two orders of magnitude above the Drinking Water
Standard.*            :        '       '
  6 Asinoted'above; th'e standard also establishes a"
margin of%afety in light.of oxidation of^chrorriium'as"'
a resul(of-'drinking-'water".tfeatrhenttSofgri979J.:.
levelfbr chromium in drinkihg;wateri
and have indicated-'explicitly-.tiiat the"-
standard is'fdr hexavalent 'chromiurrl.
(WHrg; 197S
(describing Japan'sJdrihkihg water •
standard, for hexavalent cKromium).)'
Since the undetlying drinking;water
standard in fact reflects human health
and environmental dangers" of
hexavalent chromium," we feel justified
in retaining thisrstarrdard-when-
regulating solely oil theibasis of
hexavalent chrome,
  We5stresslhat:urider;our proposal, all
wastes are to.be.*tested'for:the
characteristic of EP'tbxicity based on:
hexavalent chromium^wHen the
amended characteristipisiihalized. We •
wish particularlyto'clarify this:point
because of otlier regulatory; action taken
today delisting- certain chromium-  ,
bearing wastes and'g?antihg:temporary
exclusions from hazardous .waste status
for other such wastes'(published
elsewhere in-Part XLof this.issue).
  All .of:these wastes.will be. subject to.
the amended EP toxieity characteristic:
and generators of these Wastes
consequently willihave"to'test'"their   :
wa'ste extracts for the presence of'
hexavalent 'chxontium:

B. Proposed Analytical Method
DistingaisMng'Between At'-and*
Hexava'lent'Chromiaar-
  The groRosal to amend;tKe; ER-tbxicity
characteristic: to apply only, to?
hexavalentfchromitttnj'eqpirefcthatithere';
be an analytical method which    E
distingtiishes between' tHese;tw0;
valence'states.EPA's^Qffice.ofiTResearch"'
and'Develbpnrenthas'developed'sucK'a
procedure. The method (fully described
in Appendix A to:this,preamble)'js
based bn.the.separatipn-of, hexavalent
chromium from solution by  the
coprecipitation of lead chromate.with
lead sulfateiat a pH'of 3.5.The
precipitate isTcesolubilizedinnitric'aGid
and quantified by atomic absorption7
spectroscopy. Since trivalent chromium
does not'pireciptate'imder'such
conditionsjjhe metKod'bffers a means.of
determinutg the "presence and*       ,
concentration of .the hexavalent state in
admixture with the trivalent form.'
Comments, are solicited onsthe":
app lication of this method to EP
extracts.-
  This method h'as- been ;evaluated%smg
efflients containing higK concentrations
of OTganic'niaterial, samples'where"
malrix interferences have been t
encoiuitered with the more.usual'
chelation/exteaction procedures.- Further
evaluation presently is being conducted '
with a wide,variety/bfindustriahwastes
and EP. extfacts;,Theprocedttte.will;be;
finally promulgated after review of '1
 coniments&ndJafterfa'ma'dequate
 supportive5data5baseiis:available,.

 C. InGiherajtipnsofXjKromium-Cpniaining,
 Wastes •   i  .-.--.'  ,V  '.",     . , .. ,,,',.  -.
   The ;Agertcy;contemplatesiregula ting  •
 wastes/which,containbQth-tri--and;i  ; ;.
 hexavalent chromium in one
 circumstance,'6 namely;when-a;-     .
 chromium-?bearing wasteiSr incinerated;
 orjdestructively'oxidized by/a similar!"-
 process.-.Such'contrplis'necessary,   •
 because trivalent chromium .'oxidizes to.1
 hexavalent chromium during.
 incinerationj (U.'S. ,Dept.:of ylnteriorr.
 1979). •Inciherated-'wastesicontaining;
 trivalent chromium:thus:should be.
 regulated as if^they>contain>hexavalent.
 chromium. TherAgencyrmtends.-in the
 near;,future;"tb-adop;tiappropriater
 regulations under Parts_ 261 and 266
 regulating'th"ese*types:of.chromium--:  .
 bearing wastes: Regttlatbryjaotion'is-
 beingjdeferred-at .the-pjceseitt timev
 however, due-to -themeed tdimplement
 other parts .-of the hazardbus.waste
 management program; .and also because'
 uichieration of trivalent chromium^-
 containing wastes does .not appear to be
 widespread,7 limiting th'e possibility of"
 environmental .insult during this interim
 period. Furthermore, the Agency needs'
 more :time to develop regalaf dry
 standards to apply to facilifies -
 iaeinerating trivalent chromium^
 containing wastes. For these  reasons,
 we areniotrBrop:OBing.;aay,standards";for
 inoineratioii" of;!trivalent "chromium^      r
 eontalningTVastes at'Oiis tim'e,
   EPA is, however, anxrous'tb'obtaiir
 comments  on this contemplated
 approach. We specifically solicit  '
 comments  to the following questions: •
   lv When incineration of chromium1-
 containing.wastescauses.oxidation.oL
   'There also is.one.other situation whore wastes
 might be regulated'based on total chromiumfThe
 Agency.still has some concern that trivalent,
 chromium from waste disposal sites could migrate
 to public water systems where it would be oxidized
 during chlorinatibn toJhe hexavalent state: We>
 believe the likelihood of this occurring to :be remote
 in Ught of the,low migratory-potential of trivalent,
. chromium. However, should'migration of .trivalent
 chromium from 'improper waste disposal-occur 1rT
 concentrations,sufficient to interfere substantially,
 with treatment of public water systems, or
 otherwise cause public health concerns, we view
 ouEimrriinent hazar'd'authbrity'.urider Sectfon'70031
 of RCRA as sufficient to enjoin further"
 contamination. We are:also prepared in this••>
 circumstance 16 exercise our listing Authority.; under.
 Subtitle C to address the particular site creating the.
 problem.,
   'For example, the tanningjndustryi'fl.priricipal, •
 generator ofirivalent chromium-bearirig,wastes,,
 does'not'presentlyjiricinerate^any of:its wastes,.
 although-arfewinaividual tanHertes.'and'aie   '  . . .•
 Tanners'-'Council ;irigollab'oration-with'th^ 17.$."'
 Bureau of Mines are investigating the feasibility of
 waste incineration. (U.S. Dept. of Interior,-197a) •
 Several POTWrdoY-hbwever? use the-Ztinpro".
 process to iricinerate'tannery-sludges.

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 72032
Federal  Register / Vol. 45, No. 212 / Thursday,  October 30, 1980 /  Proposed Rules
 Irivaleot chromium to hexavalent
 chromium, will this pxidizeS hexavalent
 Chromium be emitted to the air as a
 result of incineration or will it remain in
 the incinerator ash? How effective are
 available stack scrubbing devices in
 removing any chromium from the off-
 gases?
   2, If chromium-bearing wastes are to
 be regulated as hazardous when
 Incinerated or whqn subjected to similar
 destructive oxidation processes, what
 concentration of chromium should be .
 present in the waste to trigger regulatory
 controls? What is the correlation
 between concentrations of total
 chromium tn a waste, and
 concentrations of hexavalent chromium
 in incinerator emissions? Do conditions
 of incineration or pyrolysis affect this
 ratio?  .	  ,  	,,  	 '.".;	.' '..
   jj,, Whut management standards
 should be applied to facilities
 Incinerating chromimum-bearing wastes
 during the interim status period? Are
 subparts A. B, C, D. E. G, H, and O of the
 Part 205 interim status standards
 appropriate?
"  Dated: October 27,1980,  	"	'  	   	''
 Douglas M. Costle,
 Adminwlralor,                -
   It is proposed to amend Title 40 CFR
 Part 261 as follqws,!	
 §281.24 (Amended)
   1. In | 261.24. Characteristic ofEP   f
 Toxicfiyf amend by revishig the entry
 lor EPA Hazardous Waste Dumber D007
 Table \ as follows:
   EPA b*ziKttow
   vM» rtornbw
   ConltmintM
 Maximum
 oonoentra-
   lion
• (irtttlararns
  pwfeer)
 COOT.
              »., Chrornkm (Vl)_,
   2. In Appendix II to Part 261EP
 Toxicily Test Procedure, revise
 Analytical Procedures for analyzing
 Extract Contaminants as follows: '
 Analytical Procedures For Analysing Extract
 Contaminants
   The teat methods for analyzing the extract
 are ifs follows;	
   {1 j For arsenic, barluml cadmium, lead,
 mercury, selenium, silver, endrin, lindane.
 methoxyehlor. loxaphone. 2,4-D [2,4-
 diclilorophenoxyncetic add], or 2, 4, 5-TP [2,
 4,8-irlehlorophenoxyproptonie acid]: "Test
 Methods for the Evaluation of Solid Waste,
 Physical/Chemical Methods." Solid Wate
 Information, U.S. Environmental Protection
   'Note: BM KR Doc. 80-33871 published til the end
 of ih!» P
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                Federal! Register I, Vol. 45^  No'.  212 // Thursday,  October, 30f. 1980 /,  Propose-d; Rules       '.  72033.
 be exercised not to take the pH below 3. If
.thepH is inadvertently lowered to <3,10%
 NH.,OH (7.6) should be used to readjust the
 pHtoS.5 ±0.3.  '       '         :.'••'•
   9.2  Pipet a 10 ml aliquot'bf the adjusted "'
 sample into a centrifuge tube (6.1.2). Add 100
 ul of the lead'nitrate solution (7.1), stopper
 the tube, mix the sample and allow to stand
 for 3 minutes.                  .
   9.3  After the formation of lead chromate,
 to help retain Cr(IH) complex in solution, add
 0.5 ml glacial acetic acid (7.5), stopper and
 mix.
   9.4  To provide adequate lead sulfate for
 coprecipitatioh add 100 ul of ammonium
 sulfate solution (7.2), stopper and mix.
   9.5  Place the stoppered centrifuge tube in
 the centrifuge, making sure that the tube is  .
 properly counterbalanced. Start the
 centrifuge and slowly increase the speed to
 2000 rpm in small increments over a period of
 5 minutes.
   Note.;—The speed, of the centrifuge must be
 increased slowly to insure complete
 coprecipitation.
   9.6  After centrifuging remove the tube and
 withdraw and discard the supernate using the
 apparatus detailed .in Figure 1. As the pasteur
 pipet is lowered into the tube the supernate is
 sucked over into the-filtering flask. With care
 the supernate can be withdrawn to within
 approximately 0.1 ml above the precipitate.
   9.7  To the remaining precipitate add 0.5
 ml concentrated HNO3 (7.4), 100^1 30% HaO2
 (7.7) and lOOftl calcium nitrate solution (7.3).
 Stopper the tube and mix using a vortex
 mixer to disrupt the precipitate and solubilize
 the lead chromate. Dilute to 10ml, mix and
 analyze in the same manner as the
 calibration standard (8.2).
   10. Verification
   10.1  For every sample matrix analyzed
• verification is necessary to determine that
 neither a reducing condition nor chemical
 interference affecting precipitation is present.
 This must be accomplished by analyzing a
 second 10 ml aliquot of the pH-adjusted
 filtrate that has been spiked with Cr(VI) (7,7).
 The amount of spike added should double the
 concentration found in the original aliquot.
 Under no circumstance should the increase
 be of less than 30ftg CrfVTj/1. To verify the
 absence of an interference the spike recovery
 should be between 85% and 115%.  	
   10.2  If the addition of the spike extends
 the concentration beyond the calibration
 curve the analysis solution should be diluted
 with blank solution, and the calculated
 results adjusted accordingly.
   10.3  If the result of verification indicates a
 suppressive interference, the sample should
 be diluted and reanalyzed.                 .
   11. Analytical Notes         ^
   11.1  Nitrogen should not be used as a
 purge gas because of possible CNband
 interference.              '    ' L;
   11.2 The use of pyrolytic graphite should
 be avoided when possible, since in some
 situations an enhancement effect has been
 reported.                          "7
   11.3  Pipet tips have been'Teported to be a
 possible source of contamination.
   11.4  The method of standard addition
 should be%used hi accordance With the   •
 general methods given in the manuah"Test
 Methods for Evaluating-Solid Waste,": SW-  •
. 846.                ••'"'.-'•••'      '
 BILLING CODE 6560-30-M

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72034	Federal Register  /  Vol. 45, No. 212 /  Thursday, October 30, 1980  /  Proposed Rules
                          ::::, ;:,,""FIGURE	"i
           r Fi.ct 10-SHOi 8:15 *ra|


BILLING CODE CKO-30-C
                                                                                                   »    in   i i      j  i
                                                                                                   ii    i in IIH'H i "

                                                                                                      1    ill'!    '"l
                                          II IIJl	iilillill]	llijjlli

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             Federal Register / Vol. 45, No. 212  /  Thursday, October 30, 1980  /  Rules.'and .Regulations,     -72035
 ENVIRONMENTAL PROTECTION
 AGENCY
 40 CFR Part 261

 [SW FRL 1639-1b] •
 Hazardous Waste Management
 System: identification and Listing of
 Hazardous Wastes

 AGENCY: Environmental Protection
 Agency.
 ACTION: Interim Final Rule and Request
 for Comments.

 SUMMARY: This rule amends § 261.4 of
 the Resource Conservation and
 Recovery Act (RCRA) hazardous waste
 management regulations by temporarily
 excluding from hazardous waste status
 wastes which presently are deemed
 hazardous solely due to the presence of
 chromium, but contain trivalent
 chromium exclusively (or nearly
 exclusively), are generated from
 processes which use trivalent chromium
 exclusively (or nearly exclusively), and
 are typically and frequently managed in
 non-oxidizing environments. Specific
 wastes excluded under this standard are
 tannery wastes listed as hazardous in
 § 261.32 (EPA Hazardous Waste Nos.
 K053 to K058); waste leather scrap from
 the leather tanning industry, the shoe
 manufacturing industry and other
 leather product manufacturing
 industries; and wastewater treatment
 sludges from the production of TiO2
 pigment using chromium-bearing ores by
 the chloride process listed as hazardous
 in § 261.32 (EPA Hazardous Waste No.
 K074). ^                       '
   Othe? wastes also may be temporarily
 excluded if they meet the standard set
 out above. To be eligible for a temporary
 exclusion, a waste generator or group of
 generators must petition the Agency to
 grant their waste a temporary exclusion
 and show why their waste meets the  .
 temporary exclusive standard. Petitions
 will be processed under the procedures
 set forth in § 260.20 of the hazardous
 waste regulations. Generators of wastes
 already determined to be within the  '
 temporary exclusion need not file
 petitions.
   This amendment is taken in
 conjunction with two other regulatory
 actions. The first is a proposal to amend
 the characteristic of EP toxicity to apply
;only to hexavalent chromium. These
 temporary exclusions will remain in
 effect only until that proposed
 amendment is acted upon finally. The
 second regulatory action is a final
 delisting pficerteiin, chromium-bearing
 waste streams. The termporary
 exclusion provision is necessary to  .
 allow these delistings to have their
 intended effect, and therefore is being
 adbpted as an interim final regulation.
 DATES: Effective Date: This amendment,
 in the form published today, is interim
 final Agency action. It becomes effective
 on November 19, i960.
   EPA will accept public comments on
 this interim final regulation until
 December 30,1980. Any person may
 request a hearing pn this interim final
 rule by filing a request with John P.
 Lehman, whose address appears below,
 by November 20,1980. The request must
 contain the information prescribed in
 § 260.20(d) of this chapter.
 ADDRESSES: Comments should be sent
 to Docket Clerk, Office of Solid Waste
 (WH-562), U,S. Environmental
 Protection Agency, 401 M Street, SW., .
 Washington, D.C. 20460,
 Requests for hearing should be
 addressed to John P.'Lehman, Director,
 Hazardous and Industrial Waste
 Division, Office of Solid Waste  (WH-
 565), U.S. Environmental Protection
 Agency, Washington, D.C. 20460.
 Communications should identify the
 regulatory docket number "Section
 3001/Temporary Exclusion."
   The public docket for this interim final
 rule is located in Room 2711, U.S.
 Environmental Protection Agency, 401 M
 St., SW., Washington, D.C. 20460 and is
 available for viewing from 9 a.m. to  4
 p.m., Monday through Friday, excluding
 holidays;

 FOR FURTHER INFORMATION CONTACT:
 Matthew A.-Straus, Office of Solid: :  •
 Waste (WH-565), U.S. Environmental
 Protection Agency, 401 M St., SV\f.,
 .Washington, D.C., (202) 755-9187,

 SUPPLEMENTARY INFORMATION:

 I. Temporary Exclusion From Subtitle C
 Regulation for Certain Chromium-'
 Bearing Wastes
•   The Agency today has proposed to
 amend the characteristic of EP toxicity
 in 40 CFR 261.24 to apply to hexavalent .
 rather than to total chromium (published
 elsewhere in Part XI of this issue of the
 Federal Register). The Agency also has
 taken final regulatory action today with
 respect to a number of hazardous was'te
 listings (published elsewhere in  Part XI
 of this issue), including the delisting of
 certain trivalent chromium-bearing
 waste streams. The present action is
 necessary to allow these other actions
. to have their intended effect; Thus, until
 the characteristic of EP 'toxicity is
 amended finally, all wastes remain
 subject to the existing standard based
 upon total chromium. We are concerned
 that the characteristic as it now  stands
 identifies as hazardous certain trivalent
 chromium-bearing; wastes which are
 unlikely to create a substantial present
 or potential hazard-to human health or
 the environment when mismanaged,
  imposing significant regulatory burden  .
  without achieving any statutory
  purpose. A temporary exclusion for this
  limited class of wastes is needed to
  prevent this result.
   We consequently will exclude
  temporarily from hazardous waste
  status certain chromium-bearing wastes.
  It must be. emphasized that this
  exclusion will apply only insofar as the
  wastes would be hazardous because
  they fail the EP toxicity characteristic
  for chromium or because they are listed
  solely because of their chromium  .
  content. If they are hazardous for any
 - other reason [i.e., they fail the EP
  characteristic for any constituent but
.  chromium, fail any other characteristic,
  or are listed for any other reason) they
 remain in the RCRA control system. The
 factors which must be present for a
  chromium-bearing waste to qualify for.
  this temporary exclusion are:

 —The waste contains trivalent
   chromium exclusively (or nearly
   exclusively);
 —The waste is generated from an.
   industrial process which uses trivalent
   chromium exclusively (or nearly
   exclusively), which process does not
   generate hexavalent chromium; and
 —The waste is typically and frequently
   managed in non-oxidizing
   environments.
   If a generator or an industry-wide
 group of generators can demonstrate
.that its (or-their) wastes  satisfy these
 prerequisites,, the Agency; will grant the
 waste a temporary exclusion'and the
 waste will not require subtitle C
 management during an interim period.
 When the amended  EP'toxicity
 characteristic becomes fin&l, this
 temporary exclusion will no longer be in
 effect, and waste generators will have to
 analyze their EP extracts for the
 presence of hexavalent chromium.
'•   Our basis for selecting these factors
 and our views as to how these factors,.
 will be applied are as follows. In light of
 our decision to distinguish between tri-
 and hexavalent chromium for purposes
 of subtitle C regulation, wastes
 containing exclusively or nearly
 exclusively trivalent chromium may well
 not be hazardous. There  is, however, a
•problem in demonstrating the absence of
 hexavalent chromium, due to the present
 lack of ah analytical method which
 distinguishes between trivalent and
 hexavalent chromium at low ppm
 conceriFrations in waste extracts. (The
 Agency today proposed adoption of
 such a method,' but'is undertaking.  •
 further  study of the method before final
promulgation.) In evaluating requests for
 temporary exclusions, we therefore will
 Regard waste and waste extract

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 72036    Federal Register; /  Vol. 45, No. 212 / Thursday,- October 30;1980 / Rules and Regulations
 analytical data for chromium (VI) as
 highly relevant, but not as
 determinative. We also.contemplate that
 generators will demonstrate.'the.absence
 of hexavalent chromium by using
 process chemistry information, i.e.,
 showing that the industrial process
 generating the waste dbes.notgenerate,
 hexavalent chromium, so that
 hexayalent chromium .will not be found
 In tile wastes or will Be present only in
 minimal concentrations. * In .addition to
 process information, leachate and
 groundwater monitoring data and EP"
 extract analyses are highly probative,
 since if chromium is shown to be
 present in substantially Immobile form,:
 the likelihood is that it is present in the.
 trfvalent state.
   We also believe that.at present there
 is no adequate assurance that
 chromium-bearing wastes do not
 contain potentially harmful
 concentrations of hexayalent chromium'
 unless the industrial process itself is
 trivalent chromium-based. Although we
 are aware that the standard method of
 treatment of hexavalent chromium-
 contuining wastewaters is to reduce the
 chromium and to precipitate it as
 chromium (IE) ^hydroxide, we believe
 that this process is" of ten incomplete,
 absent a strong economic incentive to;
, fully reduce all chromium present.
 Certainly, we believe it would be highly
 imprudent to exclude from regulation
 these wastes, even temporarily, absent
 much greater assurance that they do not
 contain potentially dangerous amounts
 of hexavalent chromium.
   Finally, to assure that any trivalent
 chromium which migrates from the
 waste will not oxidize tp the hexayalent
 state, we will require that the wastes" be"
 managed typically and frequently in
 non-oxidizing environments. A non-
 oxidizing environment is one in which
 there is either a relative lack of oxygen
 or one which contains reducing agents
 sufficiently strong to cause reduction of
 the contaminant in question. These
 conditions ordinarily are present in
 landfills and surface impoundments.
 (Ham, R, A.» et al., 1978, Background
 Study on the Development of a Standard
 Leaching Test.)
   The, Agency believes that .site
 monitoring data is particularly
 Important in demonstrating that
 chromium-bearing wastes are being
 managed in non-oxidizing environments.
 Thus, a demonstration by means of
 leachate and groundwater monitoring
 data that chromium remains essentially
                              ••
 immobile in its. actual management
 environmentindicates that chromium;
 remains in the insoluble and strongly,
 adsorbed trivalent state, and therefore is
 not being oxidized (see e'&, Cbmments
 of Berwick .Sewer: District, July 16,1980;
 Comments' of Alley, .Young &
 Baumgartner, July 11-, ,1980 where
 appropriate leachate;and'groundwater
 monitoring data is;presented).

 n. Wastes Meeting.tEe Temporary
 Exclusion Factors
   We are presently aware of three
 groups of wastes meeting the temporary
 exclusion factors. The first group, are the
 tannery wastes listed as'hazardous in
 § 261.32 (EPA HazardourWaste Nos;
 K053-058), and any other waste scrap
 leather generated by theleather tanning
 industry. As shown" in the comments of
 many individual" tanners'and the
 comments of the Tanners' Council of
 America, these wastes contain nearly
 exclusively trivalent'chromium. The
 industrial process generating the waste
 likewise utilizes trivalent chromium.
• Hides, in fact, cannot be tanned
 successfully with hexavalent chromium.
 Tanners thus either use" trivalent
 chromium as a: tanning agent, or, should
 trivalent chromium be unavailable, use?
 hexavalent chromium- and reduce'it so
 that the tanning'process can be
 completed. In either case, there appears
 to be an overwhelming commercial:
 incentive to keep hexayalent chromium
 out of the process and hence oufrof the
 process wastes.:
   These wastes furthermore ordinarily
 are managed in non-oxidizing landfill  —
 environments.  We therefore believe that
 an adequate showing has been made to
 justify the temporary "exclusion of these,
 wastes due to their chromium content.2'
   The second group of wastes within the
 temporaryexclusion is waste leather
 scrap from the shoe manufacturing;andt
 other leather product manufacturing1
 industries.?These wastes:are
 substantively identical to tannery-
 wastes (being composed of the same
 trivalent chromium-tanned hides'
 involved in tha tanning process), and;so"
   1 Hexmvatenl chromium concentrations below 5
 tng/1 carUtnlv will be considered minimal. This
 level U based on the maximum concentration level
 for lipxitvn'ciit chromium to be contained In (he
 •mended cKaracteriat!c oTEP toxtctty.
   'Since these wastes were listed for reasons in.
 addition to their chromium concentrations, the
 temporary exclusion for chromium does not by.itself.
 remove them from the hazardous waste
 management system. We are,* however, delisting
 tannery wastes f6r these "additional factors in an
 action taken elsewhere in today's Federal Register.
 The net result of these actions will be that these,
 tannery wastes will no longer be listed, will not be
 considered hazardous if they fail the EP toxicity
 characteristictortotal .chromium, but will be:
 hazardous if they, fail the EP toxicity characteristic
 for any other constituent, or fail any other
 characteristic:
   'These wastes'were not listed, but some way fail'
 the.test for thc-characteristiorof EP toxicity for
 chromium.
contain.trivalent .chromium exclusively
or nearly exclusively. These wastes also
are ordinarily managed in landfills, .and
so are unlikely to be oxidized.
  The third group of wastes:within the
temporary exclusion are wastewater
treatment sludges from the production of
TiOi (titanium dioxide) pigment using
chromium bearing ores by the*chloride
process PEP A Hazardous Waste No.
K074). The chromium in the process
effluent is ;trivalent, .arising-directly from
the entirely trivalent component, of the
rutile or ilmenite ores-used:as a raw
material. At no.stage'ofthe
manufacturing;process.is:there;an
opportunity for:oxidfatibn;ofthe;trivalent
chromium; The resultant :sludges" thus
am expected  to: contain only trivalent;
chromium. (See Commments;of E.I. du
Pbnt de;Nemours & C67, September 15, «
1980, pp. 8-10 describing the TiOs
manufacturing .process;. and .showing"
that onlychromium.(m) is"present;:
leachate;data submitted in these:
comments likewise tends to show that
only Wvalent'ehromiumJs .present.);
These1. wastes,are;uBua:lly disposed of in"
landfills', or !by oceaff dumping.-. One plant
uses a luied lagoon and :oHe;use8 deepr
well-injection, (UiS. ,EEA Hazardous
Waste ;Usting Background Document,
July'T1,1980,.ppi 8^*-89.):These"disposal.
situations do not offer/opportunity for'
the oxidation' of "&e;ohromiunv
component. (Ham, 1979; Fukal,,R.f 1967,
Valency State of Chromium in Sea
Water, Nature 213:901),
IH. Procedures for Obtaining a
Temporary Exclusion
  The temporary exclusion-is,not;limited
to the wastes discussedispecifically in
Part II above. .Other wastes also may
meet the temporary exclusion .factors.
and'will be"excluded.if a proper
showing as made;to the. Agency..
Eligibility for a temporary exclusion;
may be requested.by'filing a:petition for
rulemaking under §"2e0.20(a). Petitions
may be filed  by individual.generators,,or.
on.an:industryfwide>basis. Each petition
must demonstrate, why'the. wastes in
question meet the temporary exclusion
standards. Petitions then will be ~
processed by the Agency- in;accprd: with
the procedures set forth in § 260.20 (c)-J
(e). Itshould  be;notedithfft'igenBrators of:
the wastes which alreadyhave;been
determined to be;withitt:the temporary
exclusion (/;e;, the.wastes discussed in
II. above) are not required to;petition the
Agency.
IV. Interim Final Promulgation
  The temporary exclusion for this
limited class  of chromium-bearing
wastes is being promulgated in interim
final form. Thus, the: three/types of
                        . '.I:'
                                                                                            /*

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            Federal Register /Vol. 45.  No. 212  / Thursday, October  30, 1980 / Rules and Regulations    72037
  wastes now within the temporary
  exclusion are no longer subject to the
  hazardous waste regulations based on  .
  their chromium content. The provision" .
  also is final for purposes of the 90-day
  petition deadline under Section 7006.
.  The public will, however, have an
  additional opportunity to comment on
  the provision before it is published as a
  "final final" regulation.
    The Agency does not take this        •
 , procedural course lightly, but believes
  that unusual circumstances justify our
  action. First, many affected persons
  effectively have had the opportunity to
 : comment on the substance of the
  provision by virtue of their comments on
  the interim final portions of the May 19  •
  and July 16 regulations, principally the
 . hazardous waste listings in § 261.32.
  Thus, much of the data supporting
  today's action was supplied in
  comments submitted by the tanning'
  industry and (to a lesser extent) the
  titanium dioxide production industry.
  We therefore believe that the policy
  underlying the prior notice  and comment
 / requirement has been substantially
  satisfied here.
    Second, as already noted, immediate
  action is necessary to give effect to final
  regulatory action taken today delisting
  waste 'streams from the tanning and
 TiOa production industries. These:
  delisting actions present no prior notice
  and comment issues because .the listings
  themselves were not yet promulgated in
 ' final form. However, certain of the      ;
  delisted Wastes might still fail the EP for
  total chromium, and would consequently
  remain in the system until the EP
  toxicity characteristic is amended
 finally. Immediate promulgation of the
  temporary exclusion consequently is
 necessary to allow the delistings to have
  their intended consequence.
   Finally, we believe that use of
 advance notice and comment
 procedures would be impracticable and
 contrary to the public interest, and
 therefore that good cause exists for^
 adopting these regulations in interim   -
 final form (see 5 U.S.C. 553(b)(B)).
 Although the "good cause" exception is '.
 narrow, courts have emphasized'that
 "(i)t is an important safety value to be
 used where delay would do real harm."
 U.S. Steel Corp, v. EPA, 595 F.2d 207, 214
 -(5th Cir., 1979). We believe delay in
 promulgating the temporary exclusion
 could cause significant harm to the
 regulated community, particularly to  the
 tanning industry. The tanners have
 indicated that there is a severe shortage
 of hazardous waste landfill  capacity,  ,
 especially in New England where many
 tanneries are located, so that disposal
 costs will increase very substantially
  even if hazardous waste management is
  required for only a short period. (See,
  e.g.. Comments of A. C. Lawrence
  Leather Co., July 10,1980.) Courts have
  approved immediate promulgation of
  rules in like circumstances where failure
  to implement regulations would cause
  severe market'dislocations. See De
  Rieuxv. Five Smiths, Inc., 499 F.2d 1321,
  1332 (TECA), cert, denied 419 U.S. 896
 ; (1974) (promulgation of government
  price controls); Reeves v. Simon, 509
  F.2d 455, 458-159 (TECA 1974), cert.
  denied, 420 U.S. 991 (1975) (gasoline
  station fuel allocation regulations). The
  same principle applies here.
,   Dated: October 27,1980.
  Douglas M. Cos tie,
  Administrator.
,   Title 40 CFR Part 261 is revised as
  follows:            '
   1. In § 261.4, Exclusions, paragraph-
 "(b}(6) is added to read as follows:

  §261.4  Exclusions.
.  * -•''- * '   *    *'  ;  *
   (fa) * * *
   (6) (i) Wastes which fail the test for
  the Characteristic of EP toxicity because
  chromium is present or are listed in
  SubpartD due to the presence of
"chromium, which do not fail the test for
  the characteristic of EP toxicity for any
  other constituent or are not listed due to
\ the presence of any other constituent,
  and which, do. not fail the test for any
 other characteristic, if it is shown by a
 waste generator or by waste generators
.that:,   /  ,
   (A) The chromium in the waste is
 exclusively (or nearly exclusively)
 trivalent chromium; and
   (B) The waste is  generated from an
• industrial process which uses trivalent
 chromium exclusively (or nearly
 exclusively) and the process does not
 generate hexavalent chromium; and
   (C) The waste is typically and
 frequently managed in non-oxidizing
 environments.
   (ii) Specific wastes which meet the
 standard in (i)(A), (B) and (C) (so long as
 they do not fail the test for the
 characteristic of EP toxicity, and do not
 fail  the test  for any other characteristic)
 are                               '
   (A) Chrome (blue) trimmings
 generated by the following
 subcategories of the leather tanning and
 finishing industry; hair pulp/chrome
 tan/retan/ wet finish; hair save/chrome
 tan/retan/wet finish; retan/wet finish;
no beamhouse; through-the-blue; and
shearling.
   (B) Chrome (blue) shavings generated
by the following subcategories of the
leather tanning and finishing industry:
hair pulp/chrome tan/retan/wet finish;
  hair save/chrome tan/retan/wet finish;
  retan/wet finish; no beamhouse;
  through-the-blue; and shearling,
    (C) Buffing dust generated by the
  following subcategories of the leather
  tanning and finishing industry: hair
f  pulp/chrome tan/retan/wet.finish; hair
  save/chorme tan/retan/wet finish;
  retan/wet finish; :no beamhouse;
  through-the-blue.
    (D) Sewer screenings generated by the
.  following subcategories of the leather
  tanning and finishing iridustry: hair
  pulp/chrome tan/retan/wet finish; hair,
1- save/chrprne.tan/retan/wet finish; \'\  *
  retan/wet finish; no^beamhpjise;   ,  v
 \.through-the-blue;_andsheairling.   ";
    (E) Wastevvater" treatment sludges.,  ', ',
'•-  generated, by the following',,     ,,
 •subcategpries of t^e leather,tanning and
  finishing industry: hair pulp/chrome
  tan/retan/wet finish; hair save/chrome
  tan/retan/xyet- finish; retan/vvret finish;
  no. beamhous,e;: through-the-blue; and "
  shearling.  .,             ,       .-':.'.••
  .  (F) Wastewater treatment sludges
  generated by the following..'.  ...
, subcategories of the. leather tanning and
  finishing industry: hair pulp/chrome   •
  tan/retan/wet finish; hair save/chrome
  tan/retan/wet finish; and through-the-
  blue.  .....'-.-
    (G) Waste scrap leather from the,
  leather tanning industry, the shoe  .
  manufacturing industry, and .other
  leather product manufacturing
  industries.  .     ;       •...-,       '
 .  (H) Wastewater.treatment sludges
  from the production of TiO2 pigment'"
  using chromium-bearirig ores by the
"chloride process.
  [FR Doc. 80-33868 Filed 10-29-80; 8:45 am]
  BILLING CODE 6560-3Q-M
 40 CFR Part 261

 tSW FRL 1639-1c]

 Hazardous Waste Management
 System; Identification and Listing of
 Hazardous Wastes

 AGENCY: Environmental Protection
 Agency.       .             '
 ACTION: Final action amending interim
 final regulation.

 SUMMARY: This regulation removes from
 the list of regulated hazardous wastes
 the wastes from the leather tanning
 industry and the titanium dioxide
. production industry which were listed
 as hazardous in interim final form in the
 Federal Register on May 19,1980 (45 FR
 33124) and July 16,1980 (45 FR 47834).
 The preamble also discusses why other
 listed waste streams containing
 chromium will still be listed due to the
 presence of chromium. This action is

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72038
                                                             I

Federal Register / Vol. 45. Islo. 212 / Thursday,  Octotier 30,  1980 / Rules and Regulations
being talcen as a result of'other
regulatory action tak'en concerning tlie
regulation of chromium-bearingjwastes
under the hazardous waste managment
progrsin !& documents published
elsewhere In this Part XI of this Federal
Register.
EFFECTIVE DATES: This action is
effective on publication.
ADDRESSES: The public docket for this
regulation is located in Room 2711, U.'S.
Environmental Protection Agency, 401M!
St., S.W., Washington, D.Cl 20460, and.is"
available for viewing from 9 a.m. to 4
p,m., Monday through Friday, excluding
holidays.
FOR FURTHER INFORMATION CONTACT:
Matthew A. Straus, Office of Solid
Waste (WH-565), U.Sl Environmental
Protection Agency, 401M St., S.W.,
Washington, D.C. 20460, (202] 755-9187.
SUPPLEMENTARY INFORMATION:1'''
I. Decision To Delist Wastes From Tiba
Production and From the Leather
Tanning and Finishing Industry
  In other regulatory action taken today,
the Agency has indicated that its
principal regulatory concern'in
regulating chromium-bearing wastes
under the hazardous waste management
program is hexavalent rather than total
chromium. The Agency consequently
has revicwed'all of the interim fihal'and
proposed waste listings iii 40 CFR Part
2S1» Subpart D which listed'chromium as
a waste constituent of concern, and
reevaluated these wastes tar determine if
they should continue to be listed due to
the presence of chromium. We have
decided that two groups of wastes;  those
from  titanium dioxide production by the
chloride process, and those from" leather
tanning and finishing, no longer should
be listed due to chromium. We have
further determined that leather tanning
and finishing industry wastes also:
should not be listed for any other basis
at the present time. We consequently
are deflating both groups of wastes.1
  We also reviewed aft of pur other
listings of chromium-bearing wastes,
(except for those wastes for which the
comment period has been extended),
We Believe that all of these other
wastes are likely to contain significant
concentrations of hexavalent chromium,
and therefore we are not amending our
inilMHstirigs. We note further that
many of these wastes are listed for
constituents other than chromium, and
our actions today do not in any way
affect these additional bases for listing.2
  'Wenlso are removing any reference to Uiesc
 wnslte from Appendix VII to Part 281.
  •We *l»o note that the Agency may choose not to
 finalize the listing of certain of these waste streams
 fur Independent reasons when finalizing the May 19
 Interim final Kit of hazardous wastes.
                             A. Wastes Generated From
                             Production
                             '  On July 16,1980, the Agency adopted
                             as an interim final listing, under 40 CFR
                             § 261.32 wastewater treatment sludges:
                             from TiOz production via the chloride
                             process (see 45 FR at 47834). On
                             reevaluation, we havejdecided not-to list
                             this waste stream because it is derived
                             from a trivalent chromium-based
                             process and contains trivalent chromium
                             exclusively  or virtually exclusively. The
                             titanium dioxide production process.
                             results in a waste stream, which contains.
                             chromium (HI) chloride. The presence of
                             this compound results from the fact that
                             the rutiie and ilmenite ores used as raw
                             materials can contain as much as"-45%
                             chromium (ill) oxide. The chromium-
                             bearing waste; stream: from this process •
                             thus contains chromium only in the
                             fri valent form, and the resulting   .
                             wastewater sludges:, therefore are not:
                             expected to contain any hexavalent
                             chromium.
                             B. Wastes Generated by the Leather
                             Tanning and Finishing Industry
                               The Agency's May 19 interim final
                             waste listings included seven waste
                             streams generated by the leather
                             tanning and'fihishing industry (EPA
                             Hazardous.Waste Numbers KO53^-059),
                             These wastes: weralisted-for the
                             presence o£ chromium, chromium and
                             lead, and (ih.the case of the wastewater,
                             treatment sludges generated by plants in;
                             certain subcategories)" chromium and
                             reactivity. With respect to chromium,,
                            . the Agency has determined that these"
                             wastes contain exclusively or virtually
                             exclusively trivalent chrome and
                             therefore do not warrant'listing on this
                             basis. The leather tanning process
                             depends on the chemical reaction of
                             trivalent chromium with the free amine.
                             and hydroxyl groups on the hides'
                             protein chains. This reaction will nott
                             occur if hexavalent chromium is used,.so
                             that there is a very strong commercial
                             justification for the absence of
                             hexavalent chromium in these wastes.
                             Although it is true that if the trivalent
                             tanning agent is" not readily or
                             economically available, tanneries :use,
                             hexavalent chrome as a starting
                             material, the chromium is  then reduced'
                             to the trivalent state either before use  in;
                              the tanning process or in situ during .the "
                              tanning process (a "two bath" process
                             now largely obsolete); Both economics
                              and the recognized .dangers inherent in
                              the unnecessary risk in handling,
                              hexavalent chromium serve to assure  .
                              the conversion to the trivalent form.?. ,
 The wastes resulting from the tanning
 process; therefore, are overwhelmingly
 inthe.trivalent.state-. lir addition;
 leachate and groundwater monitoring
 data submitted" by individual tanners
 indicate" that the; chromiunrcontaihed in
 these wastes has low migratory;
 potential under most waste, management
 conditions; and also that it has:very
 limited mobility should migration occur,
 confirming that these  wastes contain
 chrome (III), rather than the highly
 mobile hexavalent chromium;
   Certain tanning wastes; were listed
 because of the presence of lead.
 Substantial data submitted by industry
 indicate convincingly, however, that ,
 lead is not typically used in the tanning
 process, nor is it found in process".
 wastes; in-regulatorily significant
 amounts:or concentrations. We  •
 consequently believe'continued listing
 on this: basis is" inappropriate;
 Furthermore, these wastes remain
 subject to  the EP tbxicity characteristic,
 so that those wastes containing
 excessive  concentrations of .lead will
 still be.brought into the hazardous waste
 management system.
   Two; wastewater treatment sludges
 were listed as hazardous due to:
 reactivity, more specificallybecause of
 the possibility of release-of harmful
 concentrations of hydrogen sulfide; gas-
 under usual waste management,
 conditions. .Historical waste
 management'datsr submitted.by industry
 indicates; .However,,that.harmful release
 of hydrogen;sulfide does.not occur
 typically and frequently, in rwaste
 management practice. Rather, this  .
 problem is'more likely to occur during
 the tanning process, prior to waste
, generation. (Comments of Robert M,
 Lollar, Technical Director, Tanners'
 Council of "America, August 12,1980.),
   We have.determined to delist these
 sludges for reactivity. We again note,
 however, that the wastes remain subject
 to the reactivity characteristic,,so that
 these wastes should be deemed
 hazardous if harmful hydrogen sulfide
 generation occurs, or has occurred,
 during waste, management. For example,:
 if a generator is aware of prior
 dangerous release of hydrogen-sulfide in
 managing these-sludges, for example
 from storing these sludges in enclosed.
 tanks, EPA must befnotified that the
 wastes are. reactive, and the wastes
 must be managed pursuant to  Subtitle'C
 regulatory controls. We also note,that
 the Agency is working :to quantify the
 present provision in the reactivity
 characteristic governing hydrogen .
 sulfide.and^ydrogen.cyanide-generating
                                'Thus, in one tanning facility, visited byjhe
                              Agency, when trivalent chromium is not available, a
                              twenty percent'excess of reductont is added to the
 hexavalent chromium to ensure that reduction will
 go to completion.

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                                     «*                     -                           '

            Federal Register  /  Vol. 45, No.  212 / Thursday, .October  30, 1980 / Rules and Regulations     72039
  wastes (§ 261.23(a}(5)), and that these
  sludges will be subject to the revised
  characteristic when promulgated.
   EPA is also investigating the
  possibility that these tannery wastes
  may be hazardous for reasons other
  than those for which they were listed
  originally. A possible source of waste
  contamination is use of hexavaleht
  chromium-containing chrome pigments,
  and of benzidine and benzidine
  congener dyes in the finishing process.
  For example, dyes derived from the
  chemicals benzidine, 3,3'-
  dimethylbenzidine, and 3,3'-
  dimethoxybenzidine comprise
  approximately one fourth of the 3.1 kkg
'  of dyes used by the tanning industry
  (MRI, 1979, "A Preliminary Materials
  Balance for Dyes and Pigments from
  Benzidine and Three Benzidine
 Derivatives." EPA Contract No. 68-01-
 3896, Draft Final Report, August .31,
 1979), and may be present in these
 wastes. We are concerned about the
 potential carcinogenicity of the'dyes
  themselves, and about the possible
 reduction of the dyes in the waste
 streams by heat, light, and chemical
 reducing agents, or their metabolism In
 vivo to the carcinogenic parent  .„
 compounds benzidine, 3,3'-
 dimethylbenzidine and 3,3'-
 dimethoxybenzidine. In addition, certain
 biocides*(notably phenolic derivatives) ,
 are used in the tanning process, and
 may contaminate process wastes. The
 Agency solicits information as to these
 practices, as to concentrations of these
 materials and their breakdown products
 in process wastes, and as to whether the
 wastes thereby should be considered to
 be hazardous.
 II. Retention of Chromium as a Waste
 Constituent of Concern in Other"
 Hazardous Waste Listings
  Certain of the other May IS and July
 16 interim final and proposed waste
 listings are of wastes containing
 chromium as a waste constituent of
 concern. (See 45 FR 33123-124, 33137;
and 45 FR 47833-834, 47836): We have
reevaluated these listings to determine if
the wastes should continue to- be listed
due to the presence of chromium.4 It is • .
our conclusion that all of these
chromium-bearing waste streams should •
continue to be listed as hazardous due
to chromium content because all derive
from processes which use or produce a
waste stream which contains
hexavalent chromium. The basis for,our
conclusion is set out below.
  4 This discussion does not apply to chromium-
containing waste streams for which the comment
period has been extended. Industrial painting
wastes, paint manufacturing wastes, and wastes
from ferroalloys production are in this category.
     The chromium-containing waste
   streams we have listed in interim final
   form or have proposed for listing are
   generated iii the manufacture, of
   inorganic pigments (EPA Hazardous
   Waste Nos. K002-008), in petroleum
   refining (EPA Hazardous Waste Nos.
   K048-Q51), in the manufacture of iron
   and, steel (EPA Hazarous Waste Nos,
   KQ61-063), in secondary lead smelting
   (EPA Hazardous Waste No. K069), in
   electroplating (EPA Hazardous Waste
   No. F006), and in ink formulation (EPA
   Hazardous Waste No. K086), The
   chrome pigment process wastes are
   believed to contain hexavalent
   chromium because the production
   process requires the use of chromates,
   which are necessarily hexavalent
   chromium-containing compounds.
   Electroplating industry wastes likewise
   derive from processes using chromates,
   and so also are expected to contain
   hexavalent chromium. Ghromate (Cr
   (VI)) pigments are constituents of the   ;
   listed ink formulations, so that process
   wastes also should contain hexavalent
   chromium.
 '    The various listed petroleum refining
   wastes likewise use,chromates, in this
   case as corrosion inhibitors in cooling
   towers. The listed wastes from this-
   industry are all derived from cooling
   tower wastewater streams, and thus are
   expected to contain hexavalent
   chromium.
     The iron and steel industry and
   secondary lead industries generate
   chromium-containing emission control
   dusts.and sludges. These production
   processes involve oxidative processes
   occurring at elevated  temperatures,
   conditions known to cause oxidation of
   chromium (III) to chromium (VI). Spent
   pickle liquor, another listed waste from
   the steel industry, likewise is generated
   in oxidizing conditions (the pickling
   operation itself), and so will contain
   chrome (VI).
    We are aware that treatment of
  chromium-containing wastewaters most
  often consists of the reduction of
  hexavalent chromium to the trivalent
  state and the subsequent precipitation" of
  chromium (III) hydroxide. If the    .  ^.--:
^.reduction is not carried out to
  completion, however,  the hexavalent
  chromium may be entrained in the
  chromium (III) hydroxide^precipitate.
  Further, in light of the  large
 , concentrations of chromium present in
  these wastewater streams, and the very
 small concentrations of the carcinogen
 hexavalent chromium  needed to make a
 treatment sludge hazardous, we do not
 believe that the chromium in these
 wastewater streams will be fully       .,
 reduced, so that these  wastes remain •
  capable of causing substantial harm if
  mismanaged.
   Dated: October 27,198(£
  Bouglas M. Costle,
  Administrator.
   Title 40 CFR, Part 261 is amended by
  deleting from the lists of hazardous
  wastes contained in § 261.32 the
  following waste streams:

  § 261.32  [Amended]   ,
  KOS3—Chrome (blue] trimmings generated by
   the following subcategories of the leather
   tanning and finishing industry: hair pulp/
   chrome tan/retan/wet finish; hair.save/
   •chrome tan/retan/wet finish; retan/wet
   finish; no beamhouse; through-the-blue;
   and shearling.    ..•"-..
 K054—Chrome [blue] shavings generated by
  ' the following subcategories of the leather
   tanning and finishing industry: hair pulp/
   chrome tan/retari/wet finish; hair save/
   chrome tan/retan/wet finish; retan/wet
   finish; no beamhouse; through-the-blue;
   and shearling.
 K055—Buffing dust generated by the
   following subcategories of the leather
   .tanning and finishing industry: hair pulp/
   chrome tan/retan/wet finish; hair save/
   chrome .tan/retan/wret finish; retan/wet
   finish; no beamhouse; through-the-blue.
 K056—Sewer screenings.generated by the
   following subcategories of the leather-
   tanning and finishing industry: hair pulp/
   chrome tan/retan/wet finish; hair save/
   chrome  tan/retan/wet finish; retan/wet
   finish; no beamhouse; through-the-blue;
   and shearling.         .       ;
 K057—Wastewater treatment sludge
   generated by the following subcategories of
   the leather tanning and finishing industry:
   hair pulp/chrome tan/retan/wet finish; hair
   save/chrome tan/retan/wet finish; retan/
   wet finish; no beamhouse; through-the-blue;
   and shearling.     .   .
 K058—Wastewater treatment sludges
  generated by the following subcategories of
  the leather tanning and finishing industry:
  hair pulp/chrome tan/retan/wet finish; hair
  save/chrome tan/retan/wet finish; and
  through-the-blue.
 K059—Wastewater treatment sludges
  generated by the following subcategory of
  the leather tanning and finishing industry:
  hair save/non-chrome tan/retan/wet
  finish.
 K074---Wastewater treatment sludges from
  the production of TiO2 pigment using
  chromium-bearing ores by the chloride
  process.   •'.
 (PR Doc. 80-33869 Piled 10^29-BO; 8:45 amj
 BILLING CODE 6560-30-M
40CFRPart265    .
[SW FRL 1623-7]

Interim Status Standards for Owners
and Operators of Hazardous Waste
Treatment, Storage, and Disposal
Facilities

AGENCY: Environmental Protection  >,
Agency (EPA);   '     ;:  -  .-••••..,... ,

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               f ' ui i iiiai'liiiii wni ...... niiiiiijiiliiiiiiiiiii 'i ' ,i:;i in,1 ...... mi ..... irii
                                    !!!!! iim ..... i, lib!! m ir .'IIII
                                                         v:?i;Ss Six" a
                                                                                                                           - I
5*2040    Federal Register /-' Vfol! 45;, ftoi 21# /! TffursdHyi Ofctober 30;"iJJSff' ff RAiles- aadl Regula'tibns
ACTION: Revisions to final rule and
Interim final rule.
               .1,~:  ..".'in BUI„- , ,,,'i „,,; ;>
SUMMARY: The Resource Conservation.
and Recovery Act (RCRA'J'hazardbus
waste regulations, as promulgated May
13,1980; in §§ 205.112(a) and 265.142(a)
require owners or pperatbrs'of all1
hazardous waste facilities" to Have"
closure plans, as well as cost estimates
based on these plans, on the effective
date of the regulations. AUhe same.
time, owners or opera tors of hazardous
waste disposal facilities are also
required in §§ 285.118(a) and 265.144(a)
to have post-closure plans and
associated cast estimates.
  The Agency is amending these
regulations to allow the.owners  or
operators of all hazardous waste
facilities to have up to six months after
the effective date of these regulations to
prepare a written closure plan, post
closure plan (if applicable], and cost
estimates for closure and post-closure (if
applicable).
  The Agency is extending the. period
for preparing closure and post-closure.
plans for disposal facilities because
planning for closure and post-closure at
these facilities is; an extremely
important activity. Because these plans
are so Important, the Agency believes
that  It should provide owners or
operators more time to prepare them so
that  they will be well thought out.
EFFECTIVE DATE November 19,1980:
FOR FURTHER INFORMATION CONTACT:
Lawrence G..Hue, Office of "Splid'Waste
(WH-S65J, OlS. Environmental
Protection Agency, 401M Street, S.W.,
Washington, D.C. 20460, (202) 755-9190.
SUPPLEMENTARY INFORMATION:

I. Authority
  This amendment is issued'under the.
authority of Sections 1006, 2002(a), and
3004 of the Solid Waste Disposal Act, as
amended by the Resource Conservation
and Recovery Act of 1976 (RCRA), as
amended, 42 U.S.C.  6905,6912{a), and
6924; '                _ '[
II. Background
  The RCRA hazardous waste
regulations, as promulgated May 19,.
1960,45 FR 33064 et seg. In Sections
265.112(aj and 265.142(a) require owners
or operators of all hazardous'waste
facilities to have closure plans, as well
as cost estimates based on these plans,
on the effective date of the regulations.
(November 19",  1980)! At tne.same,time,,
owners or operators of "hazardous., waste
disposal facilities are also required'in
|§ 265.118(a) and 265.144(a) to have
post-closure plans and associated cost"
estimates. The amendments;to.tKe
 regulations EPA is promulgating today
 modifj* these requirements,
   Thq amendedJrsgalations-allow the
 owner or operatbroPa'Hazardous waste
 facility up to-May.19,1081" (six months
 after the effective?date of theses
 regulations) to prepare a written";clbsure
_plan, post-closure plan for a disposal
 facility, and cost estimates for closure
 and post-closure; for.'a disposal facility..
 An owner or'operator of a facilitywho"'
 decides to'close his.faciUty within this
 six-month period must nevertheless"
 submit a closure "plan and post-closure
 plan for a disposal facility atleast'lBO
 days before the date he expects to begin
 closure as required in 40'CFR Part 265,
 Subpart G,.§§ 265.112(c) and 265,lT8(c)J,
   The Agency is extending the.period'
. for preparing clbsure and post-closure,
 plans for disposal facilities because
 planning for closure and post-closure  at
 these facilities is an extremely -
 important activity. Because these plans
 are so important, the: Agency believes
 that it should^provide.owners or
 operators more:time":to prepare themsa
 that they will be well thought out..
   As a necessary consequence of-  .
 extending.the time, for preparing7closure
 and post-closure plans for facilities, EPA
 is extending the time for preparing-
 closure and post-closure cost estimates.
 for facilities; Cost estimates must.be
 based on the closure and post-closure
 plans, so they cannot be prepared until'
 the plans have-been prepared.
   The Office ofManagement and Budget
 recently approved EPA-'s Part 264 and
 265 reporting requirements under the"
 Federal Reports Acton the condition
 that EPA extend until May 19,1981,.the.
 deadline by which disposal facilities
 (landfills,;land treatment facilities",.and'
 surface impoundments which intend to;
 close as landfills) must prepare closure
 and post-closure monitoring and'
 maintenance plans. The Agency is
 convinced that owners  or operators of
 all facilities, given an additional six
 months, wilLbe able to  prepare better
 plans and more accurate" cost estimates.
 For this reason; and.to'avoid confusion.
 as to when these.plans  are required,,
 EPA is granting the time "extension" to all
 facilities.
   Dated: October 27,; 1980.,
 Douglas M. Costle,
 Administrator:
   For the reasons described above, Title
 40 of th&Gode of Federal Regulations is
 amended as follows:

 §.265.112  [Amended],
   1. In § 265.1l2la)*, iir;theiirstsentettce,
 replace the phrase' "Oh;the effective
 date of these regulations" with the
 phrase: "0n May 19,1981."
§265;1i8  [Amended]
  2": Er§"'265;lT8{a);iiri thd first sentence,
replace'the;phrase'"Oh the effective.
date of theserregplktions" with .the"
phraser"Oh Maj;-l£r,;l'981i"

§265,142.  [Amended]
  3v In §",2651142(&); in the first sentence,
replaceLthe-phrase "Oh:the effective
date-of thes'e regulations" with the
phrase: "GnMay 19,; 1981."

§265.144  [Amended]
  4. In § 265.144(a), in the first sentence;
replace the phrase" "On the effective
date of these regulations" with the
phrase: "On-Msy. 19,1981."
[FR D6c: 80-33870 Ffled 10-2S-80; p:45.am]
BILLING' CODE 6560-30-M
40 CFR Part 261

[WH-FRL 1648-4]

Hazardous" Waste Management
System: Identification and Listing of
Hazardous Waste

AGENCY: Environmental Protection
Agency (EPA);                 '
ACTION: Technical amendment; final.'  .
rule.

SUMMARY: In its.regulations'on the:
identification and listing:qf hazardous"
waste, the EhyironmetitarPrDtection
Agency (EPA) iff afaetidlng'the section
"Analytical Procedures for Analyzing;
Extract Contaminants" iii Appendix II of
Part 261. This amendment merely,
clarifies" confusiMg-rsfeEences to: two sets
of'analytical'methods, each of which,
delineates  the same methods insofar as
theiapplicability"of.the:subject.section of
Appendix:!!: Therefore;.this;ameniimietit-
does not change: the substance: of:
AppendixIIi
EFFECTIVE DATE: This;action is effective
immediately.
FOR FURTHER INFORMATION CONTACT:
David Friedman, Office^ofSolid Waste
(WH-565), U.S. Environmental
Protection Agency* 401 M Street, S.'W.,
Washington, D;C. 20460, (202) 755>-9187.
SUPPLEMENTARY INFORMATION: The'
section on  "Analytical Procedures" for
Analyzihg^Extract Contaminants" in
Appendix ffof"Part',281 promulgated on
May 19i 1980 (45-FR at 33126) referenced
certain water and wastewater'analytical
methods and implied that these methods
shpuld'be used in'analyzing"EP Toxicity
Procedure  extracts; That section als'o
referenced "Test Methods forthe"
Evaluation of Solid: Waste, .Physical/
Chemical'Methods'1 and implied that
these methods should be used to
analyze these-same'extracts. These

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            Federal Register / Vol.  45,  No. 212 /Thursday, October 30, 1980 /Rules and Regulations     72041
 references to two sets of references
 have confused the regulated community
 and have generated many inquiries to
 the Agency for clarification. Because the
 latter reference incorporates and
 clarifies for use in analyzing EP extracts
 the methods described in the former
 references, EPA is today promulgating
 the following technical amendment to
 change the subject section of Appendix
. II so that only the latter reference is
 used.              .      "   .
   Dated: October 24,1980.  '
 Douglas M. Costle,
 Administrator.                        .
  .Title 40 of the Code of Federal
 Regulations is amended by deleting the
 existing language under the section of
 Appendix II of Part 261 titled
 "Analytical Procedures for Analyzing
 Extract Contaminants" and substituting
 the following language:
  The test methods for analyzing the extract
 are as follows:
  (1) For arsenic, barium, cadmium,   v
 chromium, lead, mercury, selenium, silver,
 endrin, lindane, methoxychlor, toxaphene,
 2,4-D[2,4-dichlorophenoxyacetic acid] or
 2,4,5-TP [2,4,5-trichlorophenoxypropionic
 acid]: 'Test Methods for the Evaluation of
 Solid Waste, Physical/Chemical Methods,"
 [SW-846], U.S. Environmental Protection
 Agency, Office of Solid Waste, Washington,   •
 D.C. 20460.      ,    .,               i    .
  (2) [Reserved]                   ''•"-',
  For all analyses, the methods of standard
 addition shall be used for quantification of
 species concentration.                •
 (FR Doc. 80-33871 Filed 10-29-80; 8:45 $m\
 BILLING CODE 6560-29-M

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United States
Environmental Protection
Agency
Washington DC 20460
      Postage and Fees Paid
      Environmental Protection Agency
      EPA-335
Official Business
Penalty lor Private Use $300
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