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                               Wednesday
                               November 12,. 1980
                              Part VI!



                              Environmental

                              Protection  Agency

                              Hazardous Waste Management System;
                              Identification and Listing of Hazardous
                              Waste—Finalizing. the Lists of Hazardous
                              Wastes (§§261.31 and 261.32) and
                              Proposal To Amend § 261.32

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 74884      Federal Register / Vol. 45, No. 220  / Wednesday, November 12,1980 / Rules and Regulations
ENVIRONMENTAL PROTECTION
AGENCY

40 CFR Part 261
[SWH-FRL 1664-7]

Hazardous Waste Management
System; Identification and Listing of
Hazardous Waste

AGENCY: U.S. Environmental Projection
Agency.
ACTION; Final rule and interim final rule.

SUMMARY: Pursuant to Section 3001 of
the Resource Conservation and
Recovery Act of 1976, as amended
(RCRA), the Environmental Protection
Agency (EPA) today is finalizing the
listings of eighty hazardous wastes from
nonspecific sources (§ 261.31) and
specific sources {§ 281.32). These listings
were proposed and promulgated in
interim final form in the Federal Register
on May 19,1980 (45 FR 33123-33127.
33138-33137). In addition, EPA is
deleting four wastes from its interim
final hazardous waste list,* and
deferring final action on two wastes
listed in interim final form on May 19,
1980, and on three wastes proposed for
listing on May 19.
  EPA also is finalizing Appendices VII
and VIII to this Part. These appendices
list, respectively, the toxic constituents
of concern in each listed waste, and the
toxic constituents whose presence in a
waste is sufficient cause to list a waste
as hazardous unless mitigated by other
factors enumerated in § 261.11(a)(3).
  Finally, EPA is clarifying § 261.30(d)  of
the regulations to indicate more clearly
that the Agency may in the future
establish lower small quantity generator
exclusion limits for certain hazardous
wastes listed in §§ 261.31 and 261.32.
DATES: Effective Dates: Waste listings
promulgated in interim final form on
May 19,1980 which are finalized today
become effective on November 19,1980.
  Waste listings which" were proposed
on May 19 for inclusion in the hazardous
waste lists, become effective on May 12,
1981.
  See Supplementary Information for
further details.
ADDRESSES: The public docket for this
regulation is located in Room 2711, U.S.
Environmental Protection Agency, 401  M
Street SW., Washington. D.C. 20460. and
is available for viewing from 9:00 a.m. to
4:00 p.m., Monday through Friday,
  'Seven additional wastes promulgated in interim
finwl form on May 19.1980 were removed from the
till of hazardous wastes on October 30.1980 (45 FR
72037).
'excluding holidays. See Supplementary
Information for further details.
FOR FURTHER INFORMATION CONTACT:
Matthew A. Straus, Office of Solid .„
Waste (WH-565), U.S. Environmental
Protection Agency, 401M Street, SW.,
Washington. D.C. 20460, [202] 755-9187.
SUPPLEMENTARY INFORMATION:

Dates
  Waste listings promulgated in, interim
final form on May 19,1980 which are
finalized today become effective on
November 19,1980. Wastes in this
category are § 261.31 Hazardous Waste
Nos. FOQ1-012, F014-015, F019 and
§ 261.32 Hazardous Waste Nos. K002-
Oil. K013-034, K036-052, K060-062, and
K064-069.
  Waste listings which were proposed
on May 19 for inclusion in the hazardous
waste lists (§ 261.32), become effective
on May 12,1981. Wastes in this category
are distillation light ends from the
production of phthalic anhydride from
ortho-xylene {Hazardous Waste No.
K093), distillation bottoms from the
production of phthalic anhydride from
ortho-xylene (Hazardous Waste No.
K094), distillation bottoms from the
production of 1,1,1-trichloroethane
(Hazardous Waste No. K095); heavy
ends from the heavy ends column from
the production of 1.1,1-trichloroethane
(Hazardous Waste No. K096), vacuum
stripper discharge from the chlordene
chlorinator in the production of
chlordane (Hazardous Waste No. K097),
untreated process wastewater from the
production of tqxaphene (Hazardous
Waste No. K098), untreated wastewater
from the production of 2,4-D (Hazardous
Waste No. K099), and waste leaching
solution from acid leaching of emission
control dust/sludge from secondary lead
smelting (Hazardous Waste No. KlQO).
  For those waste listings promulgated
in interim final form on May 19 which
are not being finalized, the effective -
date is still November 19,1980. These
waste listings take effect as interim final
regulations. Wastes in this category are
bottom sediment sludge from the
treatment of wastewaters from wood
preserving processes that use creosote
and/or pentachlorophenol (§ 261.32
Hazardous Waste No. K001), and
wastewater treatment sludges generated
in the production of creosote (§ 261.32
Hazardous Waste No. K035).
Compliance Dates:
a. Notification
1. Finalized Waste Listings Promulgated
in Interim Final Form on May 19, 1980
  Persons who generate, transport, treat,
store, or dispose of any hazardous
 waste listed in interim final form on
 May 19,1980, which waste listing is now
 being finalized in substantively
 unaltered form are not required to notify
 as a result of today's action. We dp not
 consider such action to be a "revision"
 of the  Section 3001 regulations within
 the meaning of Section 3010(b). All such
 persons of course, should have already
 notified by or before August 18,1980.
   There is one possible exception. We .
 have altered the listing description of   ,
 § 261.32 hazardous waste No. K027
 ("centrifuge and distillation residues
 from toluene diisocyanate production")
 to indicate clearly that wastes from both
 the centrifuge and distillation columns
 are included within the scope of the
 listing. Although we believe that the
 listing background document clearly
 reflected our intent to include both types
 of residues, we recognize that  some
 persons generating only distillation
 column residues from this process may
 not have notified based on the May 19,
 1980 listing description. We dp not
 intend to penalize any such individual
 for failure  to notify. Therefore, any
 person generating, transporting, treating,
 storing, or disposing of distillation
 column residues from toluene
 diisocyanate production who has not
 already notified EPA should now do so.
 (As explained below, we also  do not
 intend to bar such persons from
 eligibility for interim status.)
   One further clarification. The Agency
• has added one new listing description in
 its final list of hazardous wastes from
 nonspecific sources (§ 261.31), namely
 "wastewater treatment sludges from the
 chemical conversion coating of
 aluminum" (Hazardous Waste No.
 F019). This waste previously was
 included within the scope of § 261.31
 Hazardous Waste No. F006, which
 listing was promulgated in interim final
 form on May 19,1980. Persons who
 generate, transport, treat, store, or
 dispose of waste F019 are not required
 to notify as a result of today's  action.
 Such persons  should already have
 notified the Agency that they handle
 waste F006.

 2. Finalized Waste Listings Which Were
 Proposed on May 19, 1980

   Persons who generate, transport, treat,
 store,  or dispose of wastes which were
 proposed for listing on May 19,1980,
 which are today being finalized
 (§ 261.32, wastes K093-100), are not
 required to notify so long as they
 previously notified the Agency that they
 handle a hazardous waste and received

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         Federal Register /Vol. 45, No. 220!  / Wednesday, November 12,  1980  /  Rules  and  Regulations  74885
• an I.D. number.* Persons who have not
 previously notified EPA and who now
 generate or handle these wastes must
 now notify EPA of their activities under
 Section 3010 no later than February 10,
 1981i Notification instructions are set
 forth in 45 FR 12746 (February 26,1980)..
 3. Waste Listings Taking Effect as
 Interim Final Regulations
   Persons who generate/transport, treat,
 store, or dispose of waste* which were
 promulgated in the May interim final list
 and are taking effect as-interim final
 regulations (namely § 261.32.Hazardous
 Waste Nos. K001 and K035) are not
 required to notify again since all such
 persons should have already notified by
 or before August 18,1980.

 b. Other Compliance Dates
   Beginning on November 19,1980,
 persons handling wastes listed in final  •
 or interim final form in § § 261.31 and
 261.32 which listings were promulgated
 in interim final form on May 19,1980,
 must comply with all applicable
 standards for hazardous waste
 generators, transporters, and owners  or
 operators'of hazardous waste
 management facilities set forth in 40
 GFR Parts 262 through 265 and 122
 through 124.
   Beginning on May 12,1981, persons
 handling wastes listed in final form in
 § § 261.31 and 261.32 which were
 proposed for inclusion on May 19,1980
 must comply with all applicable
 standards for hazardous waste
 generators,  transporters, and owners or
 operators of hazardous waste
 management facilities set forth in 40
 CFR Parts 262 through 265 and 122
 through 124.
  The owners or operators "of all
 existing hazardous waste management
 facilities which treat, store or  dispose of
 wastes listed in these regulations.which
 were proposed for inclusion on May 19,
 1980, and who wish to qualify for
 interim status under Section 3005(e) of
 RCRA, must file a notification by
 February 10,1981, unless they have
 notified previously (as described in a. 2.
 above), and must file a permit
 application  by May 12,1981 (see 40 CFR
 § 122.23(a) (1) and (2)). •
  Owners or operators of facilities who
 have  qualified for interim status and
 wish  to manage wastes listed in the final
 regulations which wastes were proposed
 for listing on May 19,1980 must submit
  'Our authority for this action is the recent
amendment to Section 3010(a) of RCRA contained
in the Solid Waste Disposal Act Amendments of
1980 (P.L. 98-452, (October 21.1980)), which
amendment leaves the requirement for notification
following revision of the Section 3001 regulations to
the discretion of the Administrator.
 an amended permit application-by May
 12,1981 (see 40 CFR § 122.23(c)(l)).
 Owners or operators of facilities with
 interim status who do not comply with
 these requirements are precluded from
 managing these wastes after May 12,
 1981.                  '• •
   Persons handling distillation residues
 from toluene diisocyanate production
 {§ 261.32 Hazardous Waste No. K027)
 who have not notified the Agency of
 their activities, and (in the case of
 existing facilities) have not filed a
 permit application, and who failed to   .
 take these actions due to reliance on the
 listing description of this waste which
 was promulgated on May 19,1980, must
 comply with all applicable standards for
 hazardous waste generators,
 transporters, and owners or operators of
 hazardous waste management facilities
 set forth in 40 CFR Parts 282 through 265
 and 122 through 124 by May 12,1981.
   The owners or operators of existing
 facilities which treat, store, or dispose of.
 this waste which have not already
 qualified for interim status and who
 wish to qualify for interim status, must
 file a notification by February 10,1981,
 provided that the failure to notify and
 file a permit application was due to
 reliance on the listing description of this-
 waste which was promulgated on May
 19,1980.

Address Information Continued
   Among other things, the docket will
 contain background documents which
 explain, in more detail- than the
 preamble to this regulation, the basis for
 many of its provisions. These
background documents are not available
 immediately but are expected to become
 available within the next two  weeks.
The Agency believes it important to
provide notice on the final waste listings
 to the regulated community  as soon as
possible before November 19,1980 and
 so is publishing this regulation slightly
in advance of the availability  of revised
background documents.
I. Penalization of  § § 261.31 and 261.32
Hazardous Waste Lists

   On May 19,1980, as part of its final
and  interim final regulations
implementing Section 3001 of RCRA,
EPA published a list of hazardous
wastes  (Subpart D of Part 261) which
included 85 wastes from manufacturing
processes (§§ 261.31 and 261.32, 45 FR
33123-33124). These lists were published
in interim final form to allow the public
an opportunity to comment on
additional data the Agency had
collected on these wastes since the
close of the initial public comment'
period on the proposed Subtitle C
 regulations (43 FR 58957-58959,
 December 18,1978).
   At the same time, the Agency- also
 proposed for comment eleven additional
 hazardous waste listings (45 FR 33136—
 33137, May 19,1980). All of these wastes
 were identified by the Agency in the
 course of developing the necessary
 technical data: to support the May 19,
 1980, interim final hazardous waste list.
   The Agency received a large number
 of comments on both the interim final
 and proposed hazardous waste listings.
 We have evaluated these comments
 carefully and responded in detail in the
-respective listing background
 documents. We are setting forth in this
 preamble our disposition of the listings
 published in interim final and proposed
 form on May 19,1980 and also
 summarizing the basis for our actions as
 to each of these listings.

 A. Wastes for Which No Comments
 Were Received and No Changes Were
 Made to the Hazardous Waste Listings
 or Respective Background Documents
   No comments were received on thirty-
 five of the hazardous waste listings
 published on May 19,1980. In addition,
 the Agency is not making any
 substantive changes to either the
 hazardous waste listings or to the
 respective background documents as a
"result of its evaluation of these listings.
 Included in this category are wastes
 from the production of organic
 chemicals, pesticides, explosives,
 ferrous and nonferrous metals, and
 wastes from the petroleum refining
 industry. We therefore are promulgating
 all of these listings as final regulations.*

 B. Wastes for Which Modifications
 Were Made to the Respective Listing
 Background Documents as a Result of
 Independent Agency Re-Evaluation
   For sixteen other hazardous waste
 listings, the Agency decided to revise
  "No comments were received challenging the
 hazardousness of certain wastes generated during
 primary copper, lead, and zinc production
 (Hazardous Waste Nos. K064-OS8). However.
 challenges have been raised as to the Agency's
 authority to regulate these wastes as weil as certain
 wastes from metal recovery operations (Hazardous
 Waste Nos. F013-015), based upon a recent -
 amendment to RCRA contained ir. the  Solid Waste
 Disposal Act Amendments of 1380 f?-jb. L. 96—452
 (October 21.1930)) which prohibit EPA from
 regulating, under Subtitle C of RCRA. solid wastes
 from the extraction, beneficiaiion and  processing of
 ores and minerals until certain studies and  •
 rulemaking are completed. The Agency is uncertain
 about whether the-scope of the statutory
 amendment covers the aforementioned listed
 wastes. Therefore, it is going ahead with the
 finalization of these listed wastes in this action, but
 with the understanding that, in a separate
 rulemaking action, it might void these final listings.
 in whole or in part, by promulgation of an exclusion
 under I 261.4(bJ to implement the statutory
 amendment.                            ,

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              *             '              ** ' •        >

 74886  Federal Register / Vol. 45, No.  220 / Wednesday,  November 12, 1980 / Rules and Regulations'
 the respective listing background
 documents largely as a result of our own
• re-evaluation of these documents, rather
 than because of public comment. The
 substantive points addressed in the
 revised background documents are: (1)
 retention of chromium as a hazardous
 waste constituent, (2) removal of
 chemical tars as a hazardous waste
 constituent, and (3) removal of quinones
 as a hazardous waste constituent. No
 wastes were deleted from the hazardous
 waste list due to these revisions, but
 chemical tars and quinones have been
 deleted as constituents of concern from
 a number of these waste streams.
   (1) Relent/on of Chromium as a
 Hazardous Waste Constituent—In a
 previous rulemaking action, the Agency
 has indicated that its principal
 regulatory concern in regulating
 chromium-bearing wastes under the
 hazardous waste management program
 is hexavalent chromium rather than
 total chromium (see 45 FR 72029,
 (October 30,1980)). In that action, we
 proposed to amend the characteristic of
 EP toxicity to apply to hexavalent
 chromium rather than total chromium,
 temporarily excluded certain bivalent
 chromium-containing wastes from
 Subtitle C regulation, and deleted (from
 § 281.32) wastes from the leather
 tanning and finishing industry and  from
 the production of titanium dioxide by
 the chloride process.
   In taking these actions, we also
 reviewed all of the other interim final •
 and proposed waste listings which listed
 chromium as a waste constituent of
 concern, and re-evaluated these wastes
 to determine if they should continue to
 be listed due to the presence of
 chromium. These chromium-containing
 wastes are generated in electroplating
 operations (5  261.31 Hazardous Waste
 No. F006), in the manufacture of
 inorganic pigments (§ 261.32 Hazardous
 Waste Nos. K002-K008), in petroleum
 refining operations (§ 261.32 Hazardous
 Waste Nos. K048-K051), in the iron and
 steel industry (§ 261.32 Hazardous
 Waste Nos. K061-K063), and in
 secondary lead smelting (§ 261.32
 Hazardous Waste No. K069 and a
 proposed listing). The Agency has
 concluded that all of these chromium-
 bearing wastes should continue to be
 listed as hazardous due to their
 chromium content because all derive
 from processes which use or produce a
 waste which contains hexavalent
 chromium, and all are expected to
 contain significant concentrations of
 hexavalent chromium. The basis for this
 conclusion is explained in the preambles
 to our respective interim final and final
 actions dealing with chromium.(see 45
FR at 72035-72039) (October 30,1980).
We also have revised the respective
listing background documents to
indicate why we believe these wastes
contain hexavalent chromium in
significant concentrations.*
  (2) Removal of Chemical Tars as d
Toxic Constituent—The Agency listed
chemical tars as hazardous constituents
of concern in three waste streams:
distillation light ends and distillation
bottoms from the production of phthalic
anhydride from naphthalene (Hazardous
Waste Nos. K023 and K024), and
centrifuge and distillation residues from
toluene diisocyanate production
(Hazardous Waste No. K027). In re-
evaluating the toxicity of chemical tars,
the Agency believes that insufficient
data is currently available to consider
chemical tars as suspect carcinogens or
otherwise toxic. Therefore, the Agency
has removed chemical tars as  a
constituent of concern for these waste
streams. We also have deleted chemical
tars as constituents from Appendix VII
to Part 261, and from the list of toxic
chemical constituents in Appendix VIII
to Part 261.
  (3) Removal of Quinones as a
Hazardous Waste Constituent—The
Agency listed quinones as a hazardous
constituent of concern in waste stream
No. K094 (distillation bottoms  from the
production of phthalic anhydride from
ortho-xylene). In re-evaluating the
toxicity of these compounds, the Agency
believes that insufficient data  is
currently available regarding the acute
and chronic effects of the higher
molecular weight quinones and their
derivatives to support designating them
as toxic constituents of a waste. The
Agency would only expect to find the
higher molecular weight quinones in
Waste K094, based on the process
chemistry. Therefore, the Agency has
removed  quinones as a constituent of
concern for this waste stream. We also
have deleted quinones as a constituent
from Appendices VII to Part 261, and
from.the list of toxic chemical
constituents in Appendix VIII  to Part
261.
  Existing toxicological data do,
however, support the listing of
benzoquinone and isomers, and these
compounds will therefore be added to
Appendix VIII of Part 261.  Since the
Agency's health effects document on
quinones (Appendix A to the hazardous
waste listing background documents)
described the toxic effects of these
compounds, we are not reproposing
their inclusion.
C. Wastes far Which Comments Were
Received But No Changes Were Made
to the Hazardous Waste Listings
  The Agency received comments
disputing the hazardousness of or
challenging aspects of the Agency's
rationale for listing certain wastes from
iron and steel manufacture (§ 261.32  '
Hazardous Waste No. K062), and from
the production of acrylonitrile
(Hazardous Waste Nos. K011, K013,
K014),. carbon tetrachloride (Hazardous
Waste No. K016), epichlorohydrin
(Hazardous Waste No. K017), ethyl
chloride (Hazardous Waste  No. K018),
ethylene dichloride and vinyl chloride
(Hazardous Waste Nos. K019-K020),
fluoromethanes (Hazardous Waste No.
K021); phenol/acetone from cumene
(Hazardous Waste No. K022), 1,1.1-
trichloroethane (Hazardous  Waste Nos.
K028-K029), 2,4,5-T (Hazardous Waste
No. K042), 2,4-D (Hazardous Waste No.
K043), explosives (Hazardous Waste
Nos. K044-K045 and K047), and certain
spent halogenated and non-halogenated
solvents and the still bottoms from the
recovery of these solvents (Hazardous
Waste Nos. F001-F004). In evaluating
these comments, the Agency did not
agree with the substantive criticisms,
and did not modify the listing
description or the constituents which
form the basis for listing' the waste.* The
applicable background documents now
have been revised to respond to each
comment.**
D.. Wastes for Which Comments Were
Received Which Resulted in
Modifications to the Hazardous Waste
Listings and to the Applicable
Background Documents
  Comments also were submitted on
§ 261.31 hazardous wastes F005, F006,
F007-F012 and § 261.32 hazardous
wastes K027 and K061. EPA has
carefully reviewed these comments and
concluded that the listing description or
basis for listing (or both) should be
changed. These amended hazardous
waste listings are discussed below.
More detailed discussion of the reasons
for amending the listings or  the basis for
listing is contained in^the applicable
background documents.
  (1) Spent Non-Halogenated Solvents
(Hazardous Waste No. F005)—In our
listing of spent non-halogenated
  *As explained later in this preamble, however,
some of these wastes are being deleted from the
hazardous waste list for reasons other than whether
they contain trivalent or hexavalent chromium.
  *The various listing descriptions of spent solvents
(Hazardous Wastes Nos. F001-004) have, however.
been amended to correct grammatical errors. The
listing description of waste F005 is be-ing amended
similarly.-
  *'A summary of our responses are not possible
here due to the number and diversity of comments.

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              Federal Register / Vol. 45, No. 220 '/• Wednesday, November 12, 1980  /Rules  and  Regulations  74837
      solvents and still bottoms from the
      recovery of those solvents, we listed the
      solvents methanol and methyl isobutyl
      ketone as both toxic and ignitable. After
      reviewing the comments, we now
      believe that these solvents were '
      erroneously listed as toxic. Methanol
      has a very low oral toxicity (Sax, N.
      Irving, Dangerous Properties of
      Indvstrial Materials, Fifth edition. Van
*     Nostrand Reinhold Co., 1979) and in fact
      is a government-approved food additive.
      The principal chronic effects of methyl
,     isobutyl ketone are eye and throat
      irritation and gastrointestinal upset. The
      Agency, therefore, will no longer list
      either solvent as a toxic waste.
      However, spent methanol and spent
      methyl isobutyl ketone will continue  to
     be listed as ignitable wastes under
     Hazardous Waste No. F003 (rather than
     F005),-since both are highly flammable.
     ,  (2) Wastewater Treatment Sludges
     from Electroplating Operations '
     (Hazardous Waste No. F006)—A
     number of commenters argued that the
     listing "wastewater treatment sludges
     from electroplating operations" was
     overbroad, including a number of
     processes which would not generate a
     hazardous waste because the hazardous
     waste constituents of concern—
     chromium, cadmium, nickel and
     cyanides—are not used in these
     processes and thus would not be
     expected to be present in  the sludges.
       The Agency agrees with these
     commenters and has therefore modified
     this listing "to exclude wastes generated
     by the following electroplating
     processes: (1] tin plating on carbon steel,
     (2) zinc plating (segregated basis] on
  -.  carbon steel, (3) aluminum or zinc-
     aluminum plating on carbon steel, (4) all
     cleaning/stripping associated with tin,
     zinc and aluminum plating on carbon
     steel, (5) sulfuric acid anodizing of
     aluminum, and (6) chemical etching and
     milling of aluminum.
       The Agency also made one further
     change to the listing of electroplating
     wastewater treatment sludges. Certain
     comments challenged the listing of
     wastewater treatment sludges from the
     chemical conversion coating of
     aluminum. We disagree, largely because
     this plating process is both cyanide and
     hexavalent chromium-based. However,
     we believe that these sludges will not
     contain cadmium and nickel, two of the
     constituents of concern in other listed
     electroplating wastewater treatment
     sludges. We therefore are adopting in
     final form a separate listing designation
     for wastewater treatment sludges from
     the chemical conversion coating of
     aluminum (Hazardous Waste No. F019)
    and indicating in Appendix VII that the
  waste constituents of concern are
  complexed cyanides and hexavalent
  chromium.
    (3) Spent Waste'Cyanide Solutions
  and Sludged (Hazardous Waste Nos.
  F007-F012)—A number of commenters
  have indicated that the Agency, in
  listing wastes F007 to F012,
  inadvertantly  included wastes generated
  by processes that do not use cyanide
  salts or complexes, the sole constituent
  of concern for these wastes.*
   In determining to list these wastes, the
  Agency intended only to include wastes
  that may contain cyanide salts or
  complexes.because cyanide compounds
  are used in the process generating these
  wastes. Therefore, the hazardous waste
  listing  description has been modified to
  make it clear that only those processes
 which  use cyanide salts or complexes
  are covered by the listing.
   We also received comments that
 solutions and sludges from precious
 metals electroplating and metal heat
 treating operations presently included
 within  the scope of Hazardous Waste
 Nos. F007-F012 are not solid wastes
 because they are not "sometimes
 discarded" within the meaning of- § 261.2
 of the regulations. These solutions and
 sludges are instead always sent to metal
 recovery operations due to the value of
 the contained precious metals.
   We agree with the commenter that
 these materials are not "solid wastes"
 under the current definition. We
 therefore are revising our listing .
 description of wastes F007 to F012 to
 exclude solutions and sludges
 specifically generated by precious
 metals  electroplating and metal heat
 treating operations.*
   (4) Wastes from the Production of
 Toluene Di/socyanate (Hazardous
 Waste No. K027J—&. Clarification of
 Listing—One commenter indicated that
 the listing of "Centrifuge residue from
 toluene diisocyanate production"
 needed clarification since the listing
 background document described both
 centrifuge and-distillation residues as
 hazardous wastes, while the waste
  'This same comment was also made for
Hazardous Waste No. F013, "Flotation tailings from
selective flotation from mineral metals recovery
operations." In response to other comments,
however, this particular listing has been deleted
from the hazardous waste list. See Section E for a
more detailed discussion.
  "We note, however, that we may in the future
revise the definition of solid waste ($ 261.2), and
that these materials may be included as solid
wastes under a revised dafinition. Should the
definition be amended so as to include this  type of
material, we do not intend to repropose a hazardous
waste listing, since this listing has already been
proposed and promulgated in interim final form, and
the opportunity for public comment has teen
utilized fully.
  listing description in § 281.32 specified
  only centrifuge residues.
    The Agency agrees that a clarification-
  is needed, and has amended the final
 , listing description to clarify that wastes
  generated from both centrifuge and
  distillation units iii the production of
  toluene diisocyanate are included. We
  believe that the original listing
  background document clearly reflected
  our intent to include residues from both
  centrifuge and distillation columns
  (since the wastes appear to be virtually
  identical in composition as explained in
  the initial listing background document),
  and therefore  are not reproposing any.
  aspect of this listing.
   b. Deletion of Certain Bases for
  Listing—We are deleting chemical tars
  (benzidimidazapone) as a waste
  constituent of concern because of
  insufficient-data as to their toxicity.
   (6) Emission Control Dust/Sludge  -
 'from Electric Furnace Steel Production
 (Hazardous Waste No. K061)—One
 commenter indicated that it is  unclear if
 the listing of "Emission control dust/
 sludge from the electric furnace
 production of steel" applied only to
 primary steel production or to both
 primary steel producers and to foundries
 using steel scrap in their electric furnace
 production.
   In listing this waste stream, we
 intended only to include wastes from
 primary steel production. This intent is
 reflected in the listing background
 document, which refers throughout to
 primary steel production. We are
 uncertain whether foundry electric
 furnace emission control dusts and
 sludges are sufficiently similar in
 composition to warrant inclusion in the
 same listing, so we are evaluating the
 protential hazardousness of foundry
 industry wastes in separate actions.
 (See 44FRat 49404 (August 22,1979),
 and 45 FR 47836 (July 16,1979)
 (proposing various waste streams from
 the foundry industry).)

 K Wastes for Which Comments Were
 Received Which Resulted in Deletion of
 the Wastes From the Hazardous Waste
 List
  Certain of the wastes listed in interim
 final form were deleted from the list as a
 result of industry commer.t.'Our basis
 for removing these wastes are discussed
 below and in the respective listing
 background documents. It must be
 emphasized, however, that it is still the
 responsibility of the generator of these
 wastes to evaluate the wastes to see if
 they exhibit any of the characteristics of
 hazardous waste.
  (1) Flotation Tailings From Selective
Flotation From Mineral Metals
Recovery Operations (§ 261.31

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  74888 Federal Register  /  Vol. 45,  No. 220  / Wednesday, November 12, 1980 / Rules xand Regulations '
 Hazardous Waste No. F013}—In
 response to comments, the Agency has
 removed waste F013 from the hazardous
 waste list. It appears that the Agency
 overestimated the amount"of complexed
 cyanides present in the waste.  '
 Specifically, reliable analytical data
 Indicate that concentrations of
 complexed cyanides in this waste
 stream are very low and are present in a
 stable form, so that migration of free
 cyanides from this waste is unlikely to
 occur, and in any case would be quite
 unlikely to occur hi significant
 concentrations. We thus do not believe
 that this waste would pose a substantial
 hazard to human health and the
 environment if improperly managed.
   (2) Dewatered Air Pollution Control
 Scrubber Sludges from Coke Ovens and
 Blast Furnaces (§ 261.31 Hazardous
 Waste No, F016)—In response to
 comments, the Agency also has removed
 "waste F016 from the hazardous waste
 list. As with flotation tailings, the
 Agency overestimated the amount of
 complexed cyanides contained in these
 wastes. Data also indicate that the
 cyanide present in this waste stream has
 low migratory potential. Therefore, the
 Agency does not believe that this waste,
 if improperly managed, would be
 capable of presenting a substantial
 hazard to human health and the
 environment.
   (3) Still Bottoms from the Final
 Purification of Acrylonitrile in the
 Production of Acrylonitrile (§ 261.32
 Hazardous Waste No. K012J—ln. re-
 assessing the ultimate disposition of this
 particular waste, the Agency has
 learned, after contacting all the
 producers, of acrylonitrile, that this by-
 product is always used as an
 intermediate product in the
 manufacturing process.lt therefore is
 not a solid Waste, as that term currently
 is defined (see § 281.2(c)(3)). Therefore.
 waste K012 has been removed from the
 hazardous waste list.*
   (4) Sludge from Lime Treatment of
* Spent Pickle Liquor from Steel Finishing
 Operations (§ 261.32 Hazardous  Waste
 No. K063}—We have decided to  revise
 our regulatory approach  to this waste
 stream. Several comments indicate that
 this waste may not be hazardous,
 particularly if the lime treatment process
 is conducted effectively. At the same
 lime, however, insufficient data was
 submitted to warrant a conclusion that
 these wastes will typically and
 frequently not be hazardous. Our
 concern is that these wastes derive from
 a hazardous waste (spent pickle liquor
 from steel finishing (K062)) which may
 contain high concentrations of lead and
 chromium. These heavy metals not only
 will be present hi the treated sludge, but
 will be found there in even more
 concentrated form. Since the waste is
 generated in large volumes, the potential
 for hazard appears substantial if
 uncontrolled leaching occurs. A number
 of damage incidents caused by
 improperly neutralized spent pickle
 liquor treatment sludges bear out our
 concern.
  Under these circumstances, we have
 decided that these waste sludges still
 should be regulated as hazardous, but to
 delete these wastes from the hazardous
 waste list, and instead to rely on the
 provisions of §  261.3 to bring these
 wastes within the hazardous waste
 management system. Since these lime
 treatment sludges are generated from
 the treatment of a listed hazardous
 waste (K062), they are considered to be
 hazardous wastes (§ 261.3(c}(2)).
 Further, they remain hazardous wastes
 until they no longer.meet any of the
 characteristics of hazardous waste and
 are delisted (§ 261.3(d)(2)).
  The delisting provision (§ 260.22)
 requires petitioners to consider a range
 of factors in showing why a waste does
 not meet the criteria for listing
 contained in § 281.11 (a)[3).  Since our
 chief concern with these lime treatment
 sludges is whether-they will leach
 significant concentrations of lead and
 chromium, we will consider delisting
 petitions for these wastes to be
 adequate if petitioners show that
 concentrations of lead and chromium in
 EP. waste extracts are significantly less
 than the maximum concentration levels
 for lead and chromium contained in
 § 261.24, without requiring consideration
 of the other delisting factors. We also
 will consider an industry-wide
 rulemaking petition to exclude  these
 wastes from, RCRA Subtitle G
 jurisdiction if industry presents'
 representative data showing the wastes
 are not hazardous.*

F. Wastes for Which No Final Action
 Will Be Taken By November 19, 1980
  Five of the wastes  listed in interim
 final and proposed form will not be
 finalized before the effective date of the
 regulations (November 19,1930).
Included are wastes generated  from the
wood preserving industry, wastes from
 the production of creosote, and wastes
from the production of methomyl. Our
  •A* we indicated earlier in this preamble, the
 Agency !> contemplating revising the definition of
 "solid wailo" contained in § 281.2. which may have
 (ho effect of making these materials subject to
 Subtitle C regulation.
  'Persona who generate, transport, treat, store or
dispose of these Time treatment sludges are not
required to notify the Agency of this activity,
provided an appropriate notice already was filed
with respect to waste No. KCB3.
  reasons for delaying final action on"
  these waste listings are discussed
  below:
    (1) Wastes, From the Wood Preserving
  Industry'(I 261.32 Hazardous Waste No.
  K001 and a proposed listing)—The
  American Wood Preservers Institute
  argued that the listing of wastes
  generated from the wood preserving
  industry (bottom sediment-sludge from
  the treatment of wastewaters from wood
  preserving processes that use creosote
  and/or pentachlorophenol (Hazardous
•  Waste No. K001) and wastewater from
  wood preserving-processes that use
  creosote and/or pentachlorophenol (a
  proposed  listing)), was not adequately
  supported by the available data and
  argued further that regulation of these
  wastes should be deferred pending
  completion of the Agency's Rebuttable
  Presumption  Against Registration
  (RPAR) evaluation of creosote and
  pentachlorophenol.
    With respect to the proposed listing of
  process wastewater, we have decided
  not to finalize this listing in order to take
  more time to  evaluate data contained in
  industry comments. With respect to the
  interim final listing of wastewater
•  treatment bottom sediment sludges, the
  Agency believes this listing is supported
  by our present data. EPA also does not
  beiieve it  should defer regulation of
  these wastes under RCRA until
  completion of the RPAR process, since
  that process is conducted pursuant to a
  statutory standard different from
  RCRA's, and moreover does not
  consider the composition of wood
  preserving manufacturing process
  wastes or their potential to cause
  substantial hazard if mismanaged.
    We have decided, however, to allow
  additional opportunity for comment on
  the interim final listing of bottom
 'sediment sludges (as well as on  the
  proposed listing of .process wastewater).
  Since the close of the comment period,
  the Agency has identified additional
  data which we believe further supports
  and strengthens our position. We have
  revised the listing background document
  to incorporate this informaton as well as
  additional information on process
  wastewater. In order to get the benefit
  of industry comment, we are re-opening
  the comment  period on this additional
  data and on the revised listing
  background document.
   The listing  of bottom sediment
  wastewater treatment sludges will still
  take effect on November 19,. 1980 as an
  interim final'regulation. We see no
  prejudice in this action since the
  industry has had (and utilized) several
  opportunities, for comment, and we
  believe that the additional data further
  supports .the listing of waste stream

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            Federal Register / Vol.  45,  No. 220  / Wednesday,  November 12, 1980 / Rules and Regulations  74889
    KOOl. As stated above, the proposed
    listing of process wastewater will not be
    finalized at this time, and so will not
    become effective'until finalized.
      (2) Wastes from the Production of
    Creosote (% 261.32 Hazardous Waste No.
    K035 one? a proposed listing)—One
    commentor argued that many of the
    statements made in the listing
    background document on creosote
a   production applied to unlisted waste
    streams or reflected incorrect
    information regarding the production
    process. In evaluating these comments,
*   we now believe it more appropriate to
    speak of an  integrated coke oven
    production process, of which the listed
    waste stream, wastewater treatment
    sludge from creosote production, is one
    of the integrated process wastes. We
    intend to propose in the near future an
    expanded listing to include wastes from
    by-product coke making production. At
    the same time, however, we believe that
    the listing background document,  as
    revised to respond to comments,
    adequately supports the listing of
    creosote production wastewater   •
    treatment sludges, and we therefore are
    allowing this listing to take effect on
    November 19,1980 as an interim final
    regulation.
      We are evaluating more data
    concerning the proposed listing of
    creosote production process.
    wastewater, and believe tentatively that
    this waste stream is more accurately
    viewed as part of an integrated
    production process. We therefore will  '
    not finalize our proposal at this time.
      (3)  Wastewater From the Production
    ofMethomyl (proposed listingJ—The
    two manufacturers of methomyl
    objected to the inclusion of this waste
    stream in the hazardous waste list.
    Among other things, they argued that
    methomyl, a principal constituent in the
    waste and the primary basis for listing,
    is not persistent in water, and so is
    unlikely to remain in process
    wastewater in significant
    concentrations.* Since the Agency has
    not had an opportunity to fully evaluate
    all of the available data on methomyl's
    persistence, we have decided to delay
    final action  on this particular listing. The
    Agency expects to make a final decision
    on wastes from methomyl production
    within the next several months.
II. Finalization of Appendices VII and
    to Part 261
A. Appendix VII          •
  Appendix VII to Part 261 sets forth the
hazardous constituents for which each
of the wastes in § § 261.31  and 261.32 are
listed. This appendix has been revised  .
to reflect changes made in the
underlying listings, and is  being
finalized in this revised form.
B. Appendix VIII
  Appendix. VIII to Part 261 contains a
list of chemical constituents which have
been shown, in scientific studies to have
toxic, carcinogenic, mutagenic or
teratogenic effects on humans or other
life forms. A solid waste will be listed as
a toxic hazardous waste if it contains
any of these designated constituents,
unless, after consideration of a number
of factors, the Administrator concludes
that the waste is not capable, of posing a
substantial present or potential hazard
to human health or the environment
when improperly managed
(§ 261.11(a)(3)).
  The Agency has received a number of
comments on this Appendix which
resulted in modifications to the list of
toxic constituents, and also has made a
number of changes to the listed
constituents'as a result of independent
revaluation. These changes are
summarized below.*

A. Constituents Which Were
Inadvertently Omitted From the List of
Toxic Constituents
  The Agency identified a number of
toxic chemicals which were indicated as
being toxic either in the respective
listing background documents, or in
§ § 261.24, 261.33, or Appendix VH to
Part 261rbut were omitted inadvertantly
from Appendix VIII. We are correcting
these omissions by. adding these toxic
constituents to Appendix VIII.
B. Constituents for Which Comments
Were Received Which Resulted in the
Deletion of the Constitutent From the
List of Toxic Constituents
   As indicated earlier in this  preamble,
the Agency has re-evaluated the toxicity
of the solvent methanol and methyl
isobutyl ketone, and has determined
that they should not be listed as toxic
wastes. We therefore are deleting
methanol and methyl isobutyl ketone
from Appendix VIII.
      'Pyridene and methylene chloride are also
    included as a basis for listing this waste. However,
    as a result of comments, the Agency learned that
    pyridine is not expected to be present in the waste
    while methylene chloride is only expected to be
    present in the wasfewater from one of the two
    plants.
  •When the Agency finalizes § 261.33 of the
regulations, additional compounds also may be
removed from Appendix VIII. However, none of the
chemicals which may be deleted from § 261.33 are
constituents of wastes listed in §§ 261.31 and 261.32,
so we believe it appropriate to wait until we act on
I 261.33 to make the corresponding changes to
Appendix VIII.
 C. Constituents for Which No
. Comments Were Received But
 Modifications Were Made To The List
 of Toxic Constituents
  Finally, in reviewing the list of toxic
 constituents, the Agency has made
 several minor changes to this list to
 correct typographical errors, to remove
 duplications, and to clarify the identity
 of listed chemicals.
 III. Technical Amendment to § 261.30(d)
   § 261.30(d) indicates that certain
 wastes listed in §§ 261.31 and 261.32 are
 subject to 'small quantity limitations less
 than the 1000 kg per month level
 established in § 261.5(a). The Agency
 has not, as yet, designated any such
 wastes.
   A number of commenters found  this
 provision confusing. For purposes  of
 clarification, the Agency is therefore
 modifying the language of § 261.30(d) to
 indicate that no wastes presently are
 subject to this provision, but that wastes
 listed as acutely hazardous in §§ 261.31
 and 261.32 in the future may be subject
 to lower limitation levels.
 IV. The Status of Other Listed Wastes
 and Wastes Which the Agency Intends
 to List
   To better inform the regulated
 community, the Agency adds a brief
 summary to its other listing activity
 [current and prospective) under the
 Subpart D regulations. Regulations at
 issue are the list of 361 commercial
 chemical products and manufacturing
 chemcial intermediates in § 261.33
 (promulgated hi interim final form on
 May 19,1980 (45 FR 33124-33126)), the
 interim final and proposed list of wastes
 from nonspecific and specific sources
 published on July 16,1980 (45 FR 47832-
 47836), and the wastes mentioned  in
 Appendix B of the May 19,1980
 preamble to the hazardous waste
 regulations (45 FR 33118-33119) which
 the Agency indicated would be
 promulgated in final form by Fall, 1980.
   The Agency expects to promulgate
 final or interim final listings according to
 the following time table:

 A.  List of Commercial Chemical
 Products (§ 261.33)
   The Agency expects to finalize the list
 of commercial chemical products and
 manufacturing chemical intermediates
 before the November 19,1980,effective
 date of these regulations. We anticipate
 removing ethylenediamine (Hazardous
 Waste No. P053), N-
 nitrosodiphenylamine (Hazardous
 Waste No. P083), oleyl alcohol
 condensed with 2 moles ethylene oxide
 (Hazardous Waste No. P086), and  1,2-

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74890  Federal Register /  Vol. 45,  No. 220  / Wednesday,  November  12", 1980 /  Rules  and Regulations
propahediol (Hazardous Waste No.
P100) from the § 261.33(e) and (f) lists.
Most questions of interpretation of
§ 261.33 will be deferred, however, until
issuance of a regulatory interpretation
memorandum which is expected by the
end of the year.
(July 18, 1980)
  The Agency contemplates finalizing
these listings in December, 1980. The
effective date of these listings is January
16, 198.1.
rAnnenHixB Listings
C. Appendix a Listings
  Due to other priorities, the Agency
will not promulgate these listings by the
fall of this year, but does expect to take
final action by the Spring of 1981.

V.  Economic Environmental and
Regulatory Impacts:
  In accordance with Executive Order
11821, as amended by Executive Order
11949 and Executive Order 12044, EPA
                                                has prepared an Economic Impact
                                                Analysis and a Regulatory Analysis of
                                                the hazardous waste program
                                                promulgated on May 19, 1980. The effect
                                                of today's action reduces the overall
                                                cost economic impact and reporting and
                                                recording impact of EPA's hazardous
                                                being reduced. Since this action will
                                                decrease the regulatory impact of the
                                                Subtitle .G regulatory program, we have
                                                not prepared a new Economic Impact
                                                Analysis or Regulatory Analysis. The
                                                Agency has also voluntarily prepared an
                                                Environmental Impact Statement on the
                                                program under the National
                                                Environmental Policy Act, 42 U.S.C. 4321
                                                et  seq
                                                  Dated: November 4, i960.
                                                Douglas M. Cbstle,
                                                Administrator.
                                                   Title 40, Part 261 of the Code of
                                                Federal Regulations is finalized as
                                                follows:
     1.  § 261.31  (Hazardous waste from nonspecific sources) is revised  to  read as
 follows:
 § 261.31   Hazardous waste from nonspecific sources.
 IfxtoJSY »nd EPA hazafdota waste  «
            No.   •
                                                Hazardous waste
                                                                                   Hazard code

    F008
    F01 1
    cm? ,
                           The foBowing spar* halogenated solvents -used in deceasing: tetrachtor-
                              oeffiyferw, Irichtoroethylene, meihytene chloride, 1,1,1-trichloroelhane,
                              carbon tetrachloride, and chlorinated fluorccarbons; and sludges from
                              tha recovery of these solvents in degreasing operations.
                           Tha following spent natogenated solvents: tetrachloroethylene, meihytene
                              chlorids, Wchloroetnylene, 1,1,1-Wchloroetnane. chtorobenzene, 1,1,2-
                              «cNoro-tA2-Wuloroethane,     orthc-dichotorobenzene,      and
                              ticfctoofluofcnwtnane; and the still bottoms from the recovery of these
                              solvent*.
                           Tha foSowing spent non-natogenated solvents: xyiene. acetone, ethyl ace-
                              law, ethyl benzene, ethyl ether, methyl tsobutyl ketone, n-butyl alcohol,
                              cyctohexinone, and methanol; and the scH bottoms from the recovery
                              of thesa solvents.            .'
                           The following spent non-hatogenated solvents: cresols and cresylfe acid,
                              and nitrobenzene; and the si* bottoms from the recovery of these eol-
                                  -
                           The following spent non-hatogenated solvents: toluene, methyl ethyl ketone,
                              carbon disurSde. feobutanol, and pyridine; and the still bottoms from the
                              recovery of thesa solvents.
                          . Wastewater treatment sludges from electroplating operations except from
                              tha fofcwing processes: (1) sulfuric add anodizing of aluminum; (2) tin
                              plating on carbon steel; (3) zinc plating (segregated basis) on carbon
                              staer; (4) aluminum or zinc-aluminum plating on carbon steel: (5) clean-
                              ing/stripping associated with tin, zinc and aluminum plating on carbon
                              steel; and (6) chemical etching and mining of aluminum.
                           Wastawater Irealment sludges from the chemical conversion coating of alu-
                              minum.
                           Spent cyanide plating bath solutions from electroplating  operations (except
                              (or precious metals electroplating spent cyanide plating bath solutions).
                           Plating bath sludges from the bottom of plating baths  from electroplating
                              operations whare cyanides are used In the process (except for precious
                              metcls electroplating plating bath sludges).
                          . Spent striping and cleaning bath solutions from electroplating operations
                              where  cyanWes are used in the process (except for  precious metals
                              electroplating spent stripping and cleaning bath solutions).
                          . Ouenchmg bath sludge from oi) baths from metal heat  treating operations
                              where  cyanides are used in the process (except for  precious metals
                              heat-treating quenching bath sludges).
                           Spent cyanide solutions from salt bath pot cleaning from metal heat treating
                              operations (except for precious metals heat treating spent cyanide so-
                              lutions from salt bath pot cleaning).
                          . Quenching v/astewater treatment sludges  from metal heat treating oper-
                              ations  where cyanides are used in the process (excspt  for precious
                              metals heat treating quenching wastewater treatment sludges).
                           Cyanidation wastewater treatment tailing pond  sediment from  mineral
                              metals recovery operations.
                           Spent cyanida bath solutions from mineral metals recovery operations ------
                                                                                    CO
                                                                                    (T)
                                                                                    (T)
                                                                                     (I, T)
                                                                                     (T)
                                                                                     (T)

                                                                                     (R. T)

                                                                                     (R, T)
                                                                                     (R, T)
                                                                                     (R, T)
                                                                                     (R, T)
                                                                                     (T)
                                                                                     fT)

                                                                                     (R, T)
     2.  § 262.32  (Hazardous  wastes  from  specific sources)  is revised  to read  as
 follows:               •    ,                '    .                       ;

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          federal Register. / Vol. 45, No. 220 / Wednesday, November 12. 1980 / Rules and Regulations    74891
- § 262.32  Hazardous wastes from specific sources.
 Industry and EPA hazardous waste..
          No.
                                        Hazardous waste
                                                                     Hazard code
Wood Preservation:
K001 	 	 	 	
Inorganic Pigments:
K002 	 	
K003 	 '......... 	
K004 	 	 „.
K005. ..........................................
K006 	
K007 	
K008 	 _....-..........„. 	
Organic Chemicals:
K009 	 	 	
K010
K01 1 	 _ 	
K013
K014 	 _ 	
K01 5 	 _ 	 „ 	
K016 	 _ 	
K01 7 	 	 _....
K018.
K01 9 	 ...................
K020 	 ; 	 , 	
K021
K022 	
K023 	 _ 	
K024 	 	 „ 	 .:. 	
K093
K094 	 	 	 	 _ 	
K025 .
K026 	 _._ 	 „
K027 	 ....... 	 .„. 	 „
K028 ................_..„........ 	 ...„
K029 	 	 	 :. 	
K095 ........... 	 „.....,...._. 	
K096 	 	 	
K030 	 „ 	 _ 	 _.
Pesticides:
K031 	 	
K032_...._....« 	 ._._ 	 „..„.
K033 	 „.. 	 . 	 . 	
K034 	 	 _ 	 _. 	
K097 ......; 	 „ 	
K03S 	
K036 	 _ 	
K037 . .
K038
K039 	
K040
X041
KC98 	
K042 	
K043
K099
Explosives;
K044 . .
K045 	 _ 	
K046 	 _ 	 	 	
K047
Petroleum Refining:
K048 	 ,. 	

KOSO 	 _. 	 . 	 .......
KOS1 	 „_ 	 	 _. 	 	
K052 	 .........................
Bottom sediment sludge from trie treatment of wastewaters from wood pre-
serving processes that use creosote and/or pentachlorophenol. •
Was'tewater treatment sludge from trie production of chrome yeKow and
orange pigments.
Wastewater treatment sludge from the production of motybdate orange pig-
ments.
Wastewater treatment sludge from the production of zinc yellow pigments....
Wastewater treatment sludge from the production of chrome green pig-
• merits.
Wastewater treatment sludge from the production of chrome oxide green
pigments (anhydrous and hydrated).
Wastewater treatment sludge from the production of iron blue pigments 	
Oven residue from the production of chrome oxide green pigments — 	
Distillation bottoms from the production of acetaldehyde from-ethylene. 	
Distillation side cuts from the production of acetaldehyde from ethylene 	
Bottom stream from the wastewater stripper in the production of acryloni-
trile.
Bottom stream from the acetonitriie column in the production of acrylonitrile.

lonitrile.
Heavy ends or distillation residues from the production of carbon tetrachlo-
ride.
Heavy ends (still bottoms) from the purification column in the production of
eptehlorohydrin.
Heavy ends from the fractionation column-in ethyl chloride production.. 	
Heavy ends from the distillation of ethylene dichloride in ethylene dichloride
production.
production.
Distillation bottom tars from the production of phenol/acetone from cumene
Distillation light ends from the production of phthalic anhydride from naph-
thalene.
Distillation bottoms from the production of phthalic anhydride from naphtha-
lene.
xylene.
. 'xylene.
benzene.
Stripping still tails from the production of methyl ethyl pyridines 	 	 	
Centrifuge and distillation residues from toluene diisocyanate production 	
Spent catalyst from the hydrochlorinator reactor in the production of 1,1,1-
trichloroethane.
Waste from the product steam stripper in the production of 1,1,1-trichlor-
oethane.
Distillation bottoms from the production of 1,1,1-trichloroethane 	 	 	
Heavy ends from the heavy ends column from the production of 1,1,1-trich-
loroethane.
Column bottoms or heavy ends from the -combined production of trichlor-
oethytene and perchloroethylene.
By-product salts generated in the production of MSMA and cacodylic acid....
Wastewater treatment sludge from the production of chlordane 	 	
Wastewater and scrub water from the chlorination of cyclopentadiene in the
production of chlordane.
Filter solids from the filtration of hexachlorocyclopentadiene in the produc-
tion of chlordane.
of chlordane.

foton.

Filter cake from the filtration of diethylphosphorodithioic acid in the produc-
tion. of phorate.

Untreated process wastewater from the production of toxaphene 	
Heavy ends or distillation residues from the distillation of tetrachtoroben-
zene in the production of 2.4,5-T.

Wastewater treatment sludges from the' manufacturing and processing of
explosives.
Spent carbon from the treatment of wastewater containing explosives 	
Wastewater treatment sludges from the manufacturing, formulation and .
loading of lead-based initiating compounds.
Dissolved air flotation (DAF) float from the petroleum refining industry 	

Heat exchanger bundle cleaning sludge from the petroleum refining industry
API separator sludge from the petroleum refining industry 	
Tank bottoms (leaded) from the petroleum refining industry 	 	 	 -...-
(T)"'
CD
(T)
(T)
m
(T)
(T)
(T)
.(T)
CO
(RT)
(R, T)
(T)
(T)
(T)
m
(T) '
m
(T)
(T)
(T)
m
(T)
m«
{T} *
m'
rn
(RT)
m
en
m*
or
CO
(T)
m
(T) -
m
m«-
(T)*"

(T)
m
m
(T)
CO
or
m
m
(T)"
(R)
(R)
(T) -
(R)
(T)
(T)
(T)
(T)
(T)

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                                         •"                                                       '.

  74892  Federal  Register  / Vol. .'45,  No.  220  /  Wednesday, November 12, 1980  /  Rules  and ..Regulations'
 Irxfciuy and EPA hazardous was!*
              No.
                                                      Hazardous waste
                                                                                              Hazard coda
tan and Steefc
KWm, ,
kMl ..,,.._.„„.,._...
K"^?,,!, , ,-. , „,„
Primary Coppen
KGW ^-_.«.....

M 	 „..•. 	 Ammonia still Brrw sludge from coking operations 	 	 ......„,

furnaces. ,
HWW.HWM..MM Acid plant blowdown slurry/sludge resulting from the thickening of blow-
down slurry from primary copper production.
(T)
n
(C.T)
m
 Primary U*t
 Primary Zinc
     K068™__
 Secondary Lead:
                              Surface impoundment solids contained in and dredged from  surface im-   (T)
                                  poundments at primary lead smelting facilities.

                              Sludge from treatment of process wastewater and/or acid plant blowdown   (T)
                                  from primary zinc production.
                              Electrolytic anode slimes/sludges from primary zinc production	_	   (T)
                              Cadmium plant laachale residue (Iron oxide) from primary zinc production—   (T)

                              Emission control dust/sludge from secondary lead smelling	_	   (T)
                              Waste leaching solution from acid leaching of emission control dust/sludge   (T)*
                                  from secondary lead smelting.
     •Tim* watts listings take affect on (sot months after publication).
     "TIWW wasti listings Uko etfect on November 19.1980 as interim lira! regulations.
   3. Appendix VII (Basis of Listing
 Hazardous Wastes) of Part 261, is
 revised to read as follows:
   EPA
   oos
  waste
   No.
               Hazafdou* constituents lor which listed
          TaMeWoroamylane, meihyMrw chloride tricMoro-
            athytens.  1.1.1-trtcMoroilhifl*.  carbon  tetra-
            cMonde. cMormaicd tluorocarbons.
KQ02 ,-
KC03,,.
X004_
KC05.-™
KC07.
KC03 ,
K009,

KOIO.
KOU ,
K013 ,
K014..
KOI5.

K01S,
KOI7.
            kxc-«!ity!ene, l.l.l-tr-cHsrcatharte, chloroben-
            zone, 1,J,2.lnchkxo-1,2.2-ln!!uorce!nane, orthc-
            dichtoiooaniefie. tncn!orofluoromeifcane.
          NA,
          C(»5Ci$ and crasyKc acid, nilrobenzena.
          ToHMne. maihyl ilhyt ketona,. carbon disuHide.
            Isobuianol, pyridine.
          Cadmium, hexavalont chromium,  nickel, cyanide.
            (comp4ex*d),
          Htxavaioftt chromium, cyanide (comptexed).
          Cyanide (tatu).
          Cyanide (salts).
          Cyankf* (salts).
          Cyanide (uHl).
          Cyanide (salts).
          Cyanide (compfcxed).
          Cyanide (complejiad).
          Cyan-do (salts).
          Ptniachtorophenol, phenol,  2-chlorophenol.  p-
            cnlorc-flXfesot, 2.4-dtafllhySphanyl, 2,4-dinitro-
            pfwnot,  trichioirophancls,  ;eirachtorophenols,
            2,4.o7nttroptMnol. creosote, cruysene. naphtha-
            lene,   Suoranthene.   benzo(b)lluoranthene.
            benzo{a>pyfene.       ind«no(lA3racene, acen-
            aphthalene.
          Kcjava'cnt chromium, lead.
          Kaiavaiont cnronw.ii, tead.
          Hs?iva;«m chfonwm.
          H«>ava!«m chtomium, lead.
          HeMrvMnl ctxommm.
          Cyan«i» (ccrrpicxcd). hexavaient crxormum,
          H«sava!i m criror.um.
          CniocVocya
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          -"Federal Register / Vol. 45, No. 220 / Wednesday, November 12,1980  /  - Proposed Rules
                                                                       74893
 ENVIRONMENTAL PROTECTION
 AGENCY
 40 CFR Part 261

 (SWH-FRL ,1664-8)

 Hazardous Waste Management
 System; Identification and Listing of
 Hazardous Waste
 AGENCY: Environmental Protection
 Agency.
 ACTION: Proposed Rule.

 SUMMARY: Pursuant to Sections 3001 and
 7004-of the Resource Conservation and
 Recovery Act (RCRA), as amended, and
 in response to a petition for rulemaking
 filed by Envirex, Inc., the Environmental
 Protection Agency today is proposing to
 amend the listings of two of the
 hazardous wastes generated by the
 petroleum refining industry which the
 Agency promulgated in -"final-final"
 form in another section of today's
-Federal Register. The amendment would
 list as hazardous' wastes all sludges
 from primary and secondary oil/solids/
 water separation in the petroleum
 refining industry. If this action becomes
 effective, the scope of the hazardous
 waste listing for wastes from petroleum
 refining operations will be broadened,
 making additional petroleum refining
 wastes subject to the management
 standards issued by EPA under Sections
 3002 through 3006 and 3010 of RCRA (40
 CFR Parts 262 through 265 and 122
 through 124 and 45 FR 12746 (February
 26,1980)).
 DATES: EPA will accept public comment
 on this proposal until January 12, 1981.  -
 Any person may request a hearing on
 this proposal by filing a request by
 December 3, 1980.
 ADDRESSES: Comments should be
 addressed to the Docket Clerk, Office of
 Solid Waste (WH-562), U.S.
 Environmental Protection Agency,
 Washington, D.C. 20460.
 Communications should identify the
 regulatory docket number which is
 "Petroleum Refining-Section 3001." The
 public docket  for this proposed
 rulemaking is  located in Room 2711, U.S.
 Environmental Protection Agency, 401 M
 Street, SW., Washington, D.C. 20460 and
 is available for viewing from 9:00 a.m. to
 4:00 p.m., Monday through Friday,
 excluding holidays.
 Hearings requests should be addressed
 to John P. Lehman, Director, Hazardous
 and Industrial Waste Division. Office of
 Solid Waste (WH-565), U.S.
 Environmental Protection Agency,
 Washington, D.C. 20460. The request
 must contain the information prescribed
 in 40 CFR § 260.20(d).
 FOR FURTHER INFORMATION CONTACT;
 Mr. Matthew A. Straus, Office of Solid
 Waste (WH-565), U.S. Environmental
 Protection Agency, 401M Street, SW.,
 Washington, D.C, 20460, (202) 755-9187.
 SUPPLEMENTARY INFORMATION: On May
 19,1980, as part of its initial regulations
 implementing Section 3001 of RCRA,
 EPA published in interim final form  a
 list of hazardous wastes (Subpart D  of
 this Part), which included five  wastes
 generated by the petroleum refining
 industry (§ 261.32,45 FR 33123). Among
 the listed petroleum refining industry
 wastes were "Dissolved air flotation
 (DAF) float from the petroleum refining
 industry (K048)" and "API separator
 sludge from the petroleum refining
 industry (K051)". These wastes are
" generated as a  result of treatment of
 wastewater from petroleum refineries.
 These, particular listings were
 promulgated in "final-final" form in
 another section of today's Federal
 Register.
   On September 5,1980, the Agency
 received a rulemaking petition from
 Envirex, Inc.* requesting that the'
 Agency amend these two listings (i.e. of
 wastes K048 and K051) to read
 "Secondarjr (emulsified) oil/solids/
 water separator sludge in the petroleum
 refining industry" and "Primary oil/
 solids/water separation sludge in the
 petroleum refining industry",
 respectively.
   The petitioner does not dispute the
 listings of DAF and API separator
 sludges. Quite the  opposite. The
 petitioner argues that the May 19 listing
 descriptions  are in fact under-inclusive.
 The fault, according to the petitioner, is
 that the listings are specific to  particular
 types of equipment, namely the DAF
 and API separator. In fact (again
 according to  the petitioner), any
 petroleum refinery sludge resulting from
 primary and  secondary oil/solids/water
 separation will be comparably
 composed regardless of the type of
 equipment used in the separation step.
 For example, the petitioner pointed out
 that other processes, such as induced air
 flotation, parallel plate flotation
 separators, and dual media filters,
 perform the same function as the DAF
 and form a similar solids residue.
 Likewise, the API separator is  only one
 of the many equipment types which
 function as a primary oil/solids/water
 separator (other processes producing
 similar sludges include corrugated plate
 separators, inclined plate separators,
 storm equalization lagoons and ballast
water-holding tanks.)* The petitioner
therefore requests that these two listings
be modified to prevent unfair
discrimination and possible adverse
competitive consequences.
  In reviewing and evaluating the
petition, the Agency agrees that the
listings must be modified to reflect the
hazardous character of the wastes
themselves, rather than the type of
equipment or process generating the
waste. More specifically, the Agency is
tentatively persuaded that the present
listing is too narrow since it specifies
API separator sludge and DAF float,
thereby omitting other petroleum wastes
with similar compositions generated
from processes and equipment other
than API separators and DAF
equipment. To adjust the scope of these
listings, therefore, the Agency is
proposing to amend the listing to the
description recommended by the
petitioner. The hazardous constituents
of concern in these wastes are
chromium and lead.

Economic, Environmental and
Regulatory Impacts:

  In accordance with Executive Order
11821, as amended by Executive Order
11949 and Executive Order 12044, EPA
has prepared'an Economic Impact
Analysis and a Regulatory Analysis of
the hazardous waste program. EPA does
not believe that this proposed rule is a
major action for the purposes of *
Executive Order 12044, so that
preparation of a revised Economic
Impact Analysis is not required.
Furthermore, most of the costs to
generators for management of these
wastes are already covered in the
Economic Impact Analysis and
Regulatory Analysis cited above and
made available for public review. EPA
requests, however, that any data
commenters have on the generation
rates of the wastes listed in the
proposal, current management costs and
practices for these wastes, and the costs
or economic impact of the proposed
regulations be sent toUhe Docket Clerk
at the address indicated above. The
Agency has also voluntarily prepared  an
Environmental Impact Statement on the
program under the National
Environmental Policy Act. 42 U.S.C. 4321
et seq.      ^
  Dated: November 4,1980.
Douglas M. Costle,
Administrator.
  * Envirex, Inc. is a manufacturer of sewage.
 water, waste treatment and water conditioning
 equipment for many uses, including applications in
 the petroleum refining industry.
  "The petitioner cited "Development Document for
Effluent Limitations. Guidelines and Standards for
the Petroleum Refining Point Source Category" (EPA
No. 440/7-79/014-6) in support of the above
comments on process waste identification.

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 74894      Federal Register / VoL 45. No. 220 / Wednesday, November"l2.1980 / Proposed Rules
 PART 261—IDENTIFICATION AND
• LISTING OF HAZARDOUS WASTES

 §261.32 -[Amended]
   It is proposed to amend Title 40 CFR,
 Part 261, by amending 261.32 as
 follows:*
   1. Change the hazardous waste listing
 (K048), "Dissolved air flotation (DAF)
 from the petroleum refining industry" to
read "Secondary (emulsified) oil/solids/
water separator sludge from the
petroleum refining industry."
   2. Change the hazardous waste listing
(KOS1), "API separator sludge from the
petroleum refining industry" to read
"Primary oil/solids/water separation
sludge from the petroleum refining
industry."
|FR Doc 60-4K14 Filed U-7-UO: ii:is am)
HtUMKJ CODE 65W-30-M

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