Thursday
December 11, 1986
Part II
Environmental
Protection Agency
40 CFR Parts 260, 261, 262, 264, 265,
268,270, and 271
Hazardous Waste Management System:
Land Disposal Restrictions; Proposed
Bute
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44714 Federal Renter / Vol. 51. No. 238 / Thursday. December 11. 1986 / Proposed Rules
ENVIRONMENTAL PROTECTION
40 CFR Part* 260, 261, 262, 264, 265,
268, 270, and 271
ISWH-FRL 3089-6]
Hazardous Waste Management
System: Land Disposal Restrictions
AGENCY: Environmental Protection
Agency (EPA).
ACTION: Proposed rule.
SUMMARY: The Environmental Protection
Agency is today proposing to codify the
statutory land disposal prohibition
levels for a list of hazardous
constituents known as the "California
List" wastes. EPA is taking this action in
response to the requirements of the
Resource Conservation and Recovery
Act (RCRA), enacted through the
Hazardous and Solid Waste
Amendments of 1984 (HSWA).
Section 3004{d) of RCRA prohibits the
land disposal of hazardous wastes
containing the California list
constituents in concentrations at or
above specified levels after July 8, 1987.
This section of the Act also authorizes
EPA to substitute more stringent
concentration levels where necessary to
protect human health and the
environment Today's action proposes to
codify the statutory concentration levels
for all California waste categories, and
requests comment on an alternative
approach that would lower the
restriction levels for some or all of the
"California List" metals. Treatment
standards are proposed for hazardous
wastes with a pH less than or equal to
two. those containing polychlorinated
biphenyls at greater than 50 ppm, and
those containing halogenated organic
compounds in total concentration
greater than 1000 mg/kg. This action
also proposes methods for determining
compliance with the regulatory
requirements. In addition, this proposal
includes discussion of treatment
technologies which are capable df^--
reducing the concentration'of the
California list wastes tobelbw their
respective restriction levels.
DATE Comments on this proposed rule
must be submitted on or before January
28, 1987. A public hearing is scheduled
for January 14, 1987, 9:00 a.m. to 4:30
p.m.
ADOBE**!* The public must send an
original and two copies of their
comments to EPA RCRA Docket (S-212)
(WH-582), Environmental Protection
Agency, 401 M Street SW., Washington,
DC 20460. Place the Docket Number F-
88-LDR4-FFFFF on your comments. For
additional details, see the "OSW
Docket" section in SUPPLEMENTARY
INFORMATION. The public hearing will be
held at the following location: Marriott
Crystal Gateway Hotel, 1700 Jefferson
Davis Highway. Arlington, VA (703-920-
3230). A block of rooms has been
reserved at the hotel for the convenience
of attendees requiring overnight
accommodations. Please make
reservations by calling the hotel
directly. Special room rates of $72.00
single and $87.00 double have been
established.
Anyone wishing to make a statement
at the hearings should notify, in writing,
Ms. Geraldine Wyer, Public
Participation Officer, Office of Solid
Waste (WH-562), U.S. Environmental
Protection Agency. 401M Street SW.,
Washington, DC 20460. Persons wishing
to make oral presentations must restrict
them to 15 minutes and are encouraged
to have written copies of their complete
comments for inclusion in the official
record.
FOR FURTHER INFORMATION CONTACT:
For general information contact the
RCRA Hotline, Office of Solid Waste
(WH-562), U.S. Environmental
Protection Agency, 401M SL SW;,
Washington, DC 20460, (800) 424-9346
(toll-free) or (202) 382-3000 locally.
For information on specific aspects of
this proposed rule, contact: Stephen
Weil, or Richard Dailey, Office of Solid
Waste (WH-562B), U.S. Environmental
Protection Agency, 401M SL SW.,
Washington, DC 20480, (202) 382-4770.
SUPPLEMENTARY INFORMATION:
OSW Docket
The OSW docket is located in the
EPA RCRA Docket Room .
(subbasement), 401 M. SL SW.,
Washington, DG 20460. The docket is
open from 9:30 to 3:30, Monday through
Friday, except for public holidays. To
review docket materials, the public must
make an appointment by calling Mia
Zmud at (202) 475-9327 or Kate Blow at
(202) 382-4675. The public may copy a
maximum of 50 pages from any
•regulatory docket at no cost Additional
copies cost &20 per page. .
Table of Contents—California Ust
I. Background.
A. Congressional Mandate
B. Criteria for Selection of California List
Constituents
H. Summary of Today's Proposal
A. Proposed Approach.
B. Testing/Recordkeeping and Waste
Analysis Requirements '
C. Best Demonstrated Available Treatment
(BDAT) Technologies
D. Prohibition of Dilution and/or
Evaporation as Treatment
B. Nationwide Variances From the Ban
. Effective Date
F. Petition Procestes
G. Prohibition on Storage
H. Facilities Operating Under a Permit or
Interim Status
I. Treatability Variances
m. Scope and Applicability
A. RCRA Section 3004(d) Requirements
1. Definition of California List Constituents
2. Physical Form Requirement
3. Hazardous Waste Requirement
4. Concentration Levels Prohibited From
Land Disposal
B. Impact of RCRA Section 3004(c) Liquids
in Landfills Prohibition
C Exemption for Treatment in Surface
Impoundments
IV. Regulatory Approach for California List
Wastes
A. Testing and Recordkeeping
• Requirements •
1. Definition of a Liquid
2. Leachate Generation Method
3. Determination of Concentration Levels
4. Recordkeeping
B. Cyanides
1. Definition of'-Free Cyanide"
2. Dissociation of Complex Cyanides
3. Proposed Approach ;
4. Alternative Approaches
a California List Metal*,, . • "
1. Characterization • .7-
2. Two Approaches to Limit the Lang*
Disposal of California List Metals -
D. Corrosives . .
1. Characterization of Corrosive Wastes
2. Effect of Corrosives on Liners
3. Proposed Approach and Rationale for
the Statutory Level
4. Treatment Standards
E. Polychlorinated Biphenyls (PCBs)
1. RCRA Section 30M(d)(2)(D) -
Requirements
2. Existing Regulation of PCBs
3. Relationship Between HSWA and
Existing Regulations
4. Treatment Technologies (BDAT)
5. Nationwide Variance From Statutory
Effective Date
F. Halogenated Organic Compounds .
(HOCs)
1. RCRA Section 3004{d)(2)(E)
Requirements.
2. Relationship to RCRA Section
3004{d)(2)(D) Prohibition on PCBs
3. Treatment Technologies (BDAT)
4. Nationwide Variance From Statutory
Effective Date •
G. Applicable Treatment Technologies
, 1. Proposed BDAT Treatment Technologies
2. Other Applicable Treatment
Technologies
H. Comparative Risk and Available
Treatment Alternatives
I. Dilution Prohibition
J. Evaporation Prohibition
K. Facilities Operating Under a Permit or
Interim Status ' ' ' •
1. Minor Modifications
2. Reconstruction Limits'
L. Procedures for Obtaining a Variance
From Treatment Standards .
V. Alternative Capacity and Ban Effective
Date
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Federal Register / Vol. '51, No. 238 / Thursday. December 11. 1986 / Proposed Rales • •.. 44715'
A. Agency Authority With Respect to '•'..-
Effective Dates : • .
B. Regional and National Capacity
C. Nationwide Variance and the Case-by-
Case Extension
D. Determination of Capacity Requirements
by Waste Treatability Croup
E. Definition of Available Capacity
F. Definition of Alternative Treatment
Capacity .
G. Definition of Alternative Recovery and
Disposal Capacity
H. Estimation of Capacity
1. Current Surplus Capacity
2. Planned Capacity
I. Time to Develop Capacity and Length of
Variance
J. Wastes for Which Treatment Standards
Have Not Been Established
1. Incineration Capacity
2. Capacity for Other Treatment
K. Alternative Treatment Capacity
Required for California List Wastes
1. Quantities of Wastes Land Disposed
2. Quantities Requiring Alternative
Capacity
VI. State Authority
A. Applicability of Rules in Authorized
States . .
B. Effect on State Authorizations
.C. State Implementation
VIL Effects of the Land Disposal Restrictions
Program on Other Environmental
Programs •
VIII. Regulatory Requirements
A. Regulatory Impact Analysis '
1. Cost and Economic Impact Methodology
2. Cost and Economic Impacts
3. Benefits and Cost-Effectiveness of
Restricting Land Disposal of California
List Wastes
B. Regulatory Flexibility Analysis
C. Review of Supporting Documents and
Request for Public Comments
1. Review of Supporting Documents
2. Request for Comments
IX. References
I. Background . .
A. Congressional Mandate
According to Section 3004(d) of the
Hazardous and Solid Waste
Amendments of 1984 (HSWA}. effective
32 months after the date .of enactment
the land disposal of liquid hazardous
wastes containing certain"metalsrfree
cyanides, polychlorinatedbiphenyls
(PCBs), corrosives with *}JH of tess'than
or equal to 2X), and liquid and non-liquid .
hazardous wastes containing • •'• •
halogenated-organic compounds (HOCs)
is prohibited unless the waste complies
with treatment standards established by
the Environmental Protection Agency
(EPA) under section 3004(m), or a
petition has been approved, based on a
showing that, to a reasonable degree of
certainty, when such wastes-are placed
in a land disposal unit that "there will
be no migration of hazardous
constituents from the disposal unit or
injection zone for as long as the wastes
remain hazardous" (section 3004(d)(l)).
The list of California wastes and their
respective restriction levels that are
shown below were taken directly from
the statute:
(A) Liquid hazardous wastes, including free
liquids associated with any solid or sludge,
containing free cyanides at concentrations
greater than dr equal to 1000 mg/1.
(B) Liquid hazardous wastes, including free
liquids associated with any solid or sludge,
containing the following metals (or elements)
or compounds of these metals (or elements) -
at concentrations greater than or equal to
those specified below:
(i) Arsenic and/or compounds (as As) 500
mg/1;
(ii) Cadmium and/or compounds (as Cd)
100mg/l;
(iii) Chromium (VI and or compounds (as
Cr VI)) 500 mg/1;
(iv) Lead and/or compounds (as Pb) 500
mg/h .
(v) Mercury and/or compounds (as Hg) 20
mg/1;
fvi) Nickel and/or compounds (as Nij 134
mg/1;
(vii) Selenium and/or compounds (as Se)
100mg/L
(viii) Thallium and/or compounds (as Tl)
130 mg/1;
(C) Liquid hazardous waste having a pH
less than or equal to two (2.0).
(D) Liquid hazardous wastes containing'
polychlorinated biphenyls at concentrations
greater than or equal to 50 ppm. •
(E) Hazardous wastes containing
halogenated organic compounds in total
concentration greater than or equal to 1.000
mg/kg.
Collectively, these specific hazardous
waste categories are referred to as the
California list since the State of
California developed regulations to
restrict the land disposal of wastes
containing these constituents. Congress
incorporated the California list into the
provisions of HSWA primarily because
California had conducted studies which
demonstrated that wastes containing
these constituents may be harmful to
human health and the environment (B. •
Rep. No. 284,98th Cong* 1st Sess., 17
(1983)).
Congress intended the California list
prohibitions as a starting point in
carrying put the congressional mandate
to minimize land disposal 'of hazardous •
waste; (H.R. Rep. No. 198, Part 1,98th
Cong., 1st Sess; 34 (1983)). Congress*
intent in specifying threshold levels for
the land disposal of California list
wastes was to avoid time-consuming
litigation over the selection of
appropriate levels (H.R. Rep. No. 198,
Part I, at 34). While the legislation
adopted the regulatory concentration •
levels developed by the State of --
California, section 3004(d)(2) of RCRA
authorizes the Agency to substitute
more stringent levels-where necessary '
to protect human health and the
environment
5. Criteria for Selection of California
List Constituents
In developing its list of specific
categories of-hazardous wastes*
California sought to restrict those
wastes that were known to create
substantial risks to human health and
the environment when land disposed.
The State of California therefore
identified hazardous constituents that
are known to he highly toxic, persistent
bioaccumulative, 'mobile and corrosive.
For example, high concentrations of free
cyanides can be lethal to humans and to
animals, and sublethal concentrations
may cause gastrointestinal and
neurological disturbances. Additionally,
there is the potential for the formation of
highly toxic hydrogen cyanide gas. The
available evidence regarding
polychlorinated biphenyls suggest that
certain levels of exposure can cause
birth defects, reproductive problems,
liver malfunctions, digestive' .' 1 ;
disturbances, and skin problems. Some,
evidence suggests that PCBs may.be .
carcinogenic. Many of the halogenated'
organic compounds are carcinogenic.
mutagenic, or teratogenic, while others
cause damage to the liver, lungs, and .
kidneys. Corrosives are' of concern
because they may harm human skin,
mobilize toxic constituents when co-
disposed with other wastes, and damage
land disposal containment systems. In
doses exceeding the trace quantities
necessary to living organisms, the listed
metals can be acutely or chronically
toxic. They are potentially mobile, and
have been found to bioaccumulate in
livestock, burls, aquatic organisms, and
humans (California Department of .
Health Services, 1982).
In developing threshold levels for
these hazardous constituents, California
attempted to establish thresholds which
would prohibit the hind disposal of
wastes that may pose substantial risk to
human health and the environment A
number of considerations were involved
iri making mese determinations, - :
including toxfcityto living organisms, •
advene effect* tm the environment, and:
physical/chemical interactions in the
tend disposal environment For example,
California detennmedthat liquid
cyanide wastes containing greater man
1,000 mg/F cyanide could create
dangerous emission* of hydrogen
cyanide gas above land" disposal
facilities; Since hydrogen cyanide gas is
known to be extremely hazardous to
humans, the cyanide concentration
threshold was set at 1,000 mg/1 to lessen
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m
I
the possibility of fonnlng hydrogen
cyanide gas.
With respect to metals, California
developed a health-based threshold
level using the National Interim Primary
Drinking Water Standard and a 10,000-
fold attenuation factor to take into
account dispersion and dilution which
generally occur when these constituents
migrate to ground water. For nickel and
thallium, however, a threshold level was
derived from application of an
attenuation factor of 10,000 applied to
the Water Quality Criteria for these two
metals.
California also restricts from land
disposal liquid wastes having pH less
than or equal to 2.0. These restrictions
are based solely on the ability of these
wastes to mobilize and react with other
wastes and to breach or impair
containment mechanisms such as drums
and liners.
The level set for polychlorinated
biphenyls was based primarily on
considerations of consistency. The EPA
regulates the disposal of polychlorinated
biphenyls under the Toxic Substances
Control Act of 1976 (TSCA). Under
TSCA regulations codified in 40 CFR
761.60, liquid PCBs.at concentrations
between SO ppm and 500 ppm may be
landfilled if first absorbed. Therefore,
be consistent with existing federal
regulations.
Regarding HOCs, California
established the 1,000 mg/kg level based
on a combination of factors, including
the toxidty of the compounds, the
estimated volume of wastes that would
be brought into the restrictions system,
and the available capacity for handling
such wastes.
IL Summary of Today's Proposal
A. Proposed Approach-
The Agency is proposing to codify the
statutory levels for the California list as
set forth in section 3004{d) of the
Hazardous and Solid Waste
Amendments to the Resource
Conservation and Recovery Act
The Agency is also proposing two-
changes to the list The first change in
the proposed codificattahwould require
that the statutory level for cyanides
(1,000 mg/1) apply to total cyanide
rather than/res cyanide as specified in
the statute. This proposed change, which
is discussed more fully in.section IV. R,
Is being considered because of a lack of
consensus within, the literature on the
definition of "free" cyanide, and
because complexed cyanide (total
cyanide) may convert to free cyanide-
under certain conditions that may exist
in the environment The alternative is to
adopt an intermediate definition based
on an analytical method that would at
necessity capture more than just "free"
cyanides but would not capture, "total"
cyanides. The Agency is also requesting
comment on whether isocyanides should
be included as restricted cyanide-
containing California list wastes.
The Agency is also proposing to
define the universe of halogenated
organic compounds (HOCs) as those
that are listed or identified as hazardous
under 40 CFR Part 261, or listed as a
hazardous constituent under 40 CFR
Part 281, Appendix Vffl including PCBs.
An alternative approach under
consideration would not require that the
HOCs be limited to Appendix Vm, but
would bring any RCRA hazardous waste
containing halogenated organic
compounds (including polymers such as
polyvinyl chloride) above 1,000 mg/kg
within the scope of the prohibition,
regardless of the degree of hazard
associated with the HOC. The Agency is
soliciting comment cm this approach.
The Agency has considered an
approach that would lower the statutory
levels for those metals for which
Extraction Procedure (EP) toxidty
characteristic levels exist (i.e., arsenic,
cadmium, chromium, lead, mercury,
selenium) to the EP levels. While the .
Agency currently is rejecting this
approach, which is discussed in Section
IV.C. of today's proposal, the Agency is
requesting comment on this and other
possible alternatives. The Agency also
solicits comment on whether the
statutory levels should be lowered for
wastes other than those for which the
EPA has established EP levels.
B. Testing/Recordkeeping and Waste
Analysis Requirements
The-Agency is proposing analytical
procedures and- methods for the.
identification of wastes that are subject
to the California list land disposal
restriction rales. The tests EPA is
proposing to require in order to
implement this program are: (1) The
Paint Filter Liquids test to datcnaU*
whether a waste is a liquid or a non-
liquid, and: (2) the Toxidty
Characteristic Leaching Procedure
(TCLP) in order to provide a leachate
from which it can be determined
whether the particular California list
constituent exceeds the restriction level
Additionally, the Ageacy recommends
several reference works that may.be
used as guidance iq determining
appropriate qualitative/quantitative
analytical methods far California list
constituents. The Agency is also
proposing several approaches for which
part or parts of the waste must be
analyzed for hazardous constituents. All
of the above, including references for
analytical guidance, are described in
more detail in Section IV.A. The
regulatory framework for the above.
(except for the Paint Filter Li quids Test)
was published in the Federal Register in
the solvents and dioxins final rule
November 7,19S6 (51FR 40672), and is
to be codified at 40 CFR 268.7.
The Agency is also proposing (with
some minor changes) that those
California list wastes for which
treatment standards have been
established must comply with the basic
certification and recordkeeping
requirements established by the
solvents and dioxins rule, published in
the Federal Register in November 7,
1986, and which are to be codified at 40
CFR 268.7. The Agency is asking for
comment on some changes to these
requirements that are specific to the '
California list restrictions. The Agency
is also proposing to require certification
and recordkeeping for all wastes.
potentially subject to the California list
provisions.
C. Best Demonstrated Available
Treatment (BOAT) Technologies-.
In today's notice, the Agency defines
BOAT as the application of specified - -
technologies (see Section IV.GJ 18-
restricted wastes containing HOCs,
PCBs, and corrosives (wastes with a pH
of less than two). For PCB-containing
wastes, BOAT is proposed to be
incineration, or thermal destruction in
high-efficiency boilers, or other
"equivalent methods" in accordance
with the requirements promulgated
under the Toxic Substances Control Act
(TSCA) at 40 CFR,761.60 and 761.70.
Best demonstrated available technology
for California list wastes containing
HOCs atgreaterthan 156 (including both
liquids and organic and inorganic solids
and sludges) is proposed to be .
incineration ^accordance with the
requirements of 4O CFR 284343 for
permitted facilities or 2B&343 for intern
status facilities. For non-liquid
hazardous wastes containing greater
than 1000 mg/kg HOCs and less than 1%
total organic carbon, the Agency is
proposing that BOAT be incineration as
described above. BOAT treatment for
corrosive wastes is proposed to be
defined as Jieutralization to a pH of
greater than two. .
The Agency is not proposing BOAT
for HOCeontoimng liquid wastes-.
betweenWOO ppmandlftOOOppm.
While technologies sach as bfeiogical
treatment carbon adsorption, and steam
stripping are generally appticabte:
treatment technologies for some
halogenated organic wastes (such as
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Federal Register / Vol. 51, No. 238 / Thursday, December 11, 1986 / Proposed Rules
44717
halogehated solvents) at these
concentrations, the Agency, at this time,
does not have adequate data to specify
which, if any, of these treatments would
be applicable to all HOC-containing
wastes, nor is it able to define operating
parameters or technologies based on
performance standards.
The Agency is not proposing BOAT
for other California list constituents at
this time. This notice does include a
discussion of treatment technologies for
California list metals and cyanides
which, when used, may .reduce the
concentrations of those constituents in
liquid hazardous wastes to below their
respective statutory levels (see Section
IV.G.). These technologies may become
the basis for BDAT when the Agency
sets treatment standards for the metal-
bearing and cyanide-bearing wastes
under the Schedule for Final Land
Disposal Restrictions which was
published in the Federal Register at 51
FR19300, May 28,1980.
D. Prohibition on Dilution and/or
Evaporation as Treatment
The Agency today proposes to amend
the 5 268.3 prohibition on dilution as
treatment (51 FR 40639, November 7,
1986) to prohibit dilution as a means of
achieving the statutory concentration
levels and prohibit dilution as a means
of circumventing the effective date of a
prohibition under Subpart C. A detailed
discusssion of the dilution prohibition is
found in Section IV. L
The Agency is also considering a
prohibition on evaporation for purposes
of the S 268.4 treatment in surface
impoundments exemption from the land
disposal prohibitions. A discussion of
the evaporation prohibition is found
under Section IV. J.
E. Nationwide Variances From the Ban
Effective Date
As discussed earlier, today's notice
proposes several treatment technologies
that are to be considered BDAT for the
purposes of establishing treatment
standards for the restricted HOC and
PCB-containing waster. Incineration
required as BDAT for the HOC* and •
PCBs is also required to treat solvent-
containing and dioxin-containing wastes
(51 FR 40572). It has been estimated that
the available incineration capacity will
be exhausted by the treatment of both
solvent-containing and dioxin-
containing wastes. Therefore, the
Agency is proposing (under the
authority granted in section 3004(h)(2))
to grant two-year nationwide variances
to the ban effective date for HOC-
containing and PCB-containing
California list wastes. A discussion of
the ban effective dates and the
nationwide variances is found in
Sections V. A and LJ,Wj,g
F. Petition Processes
Today's notice proposes to adhere to
the regulatory framework established by
the Solvents and Dioxins Final Rule of
November 7,1986 for (1) granting
extensions of the ban effective date on a
case-by-case basis, and, (2) the land
disposal of wastes not meeting a
relevant treatment standard. These two
petition processes'are codified at
§ S 268.5, and 268.6, respectively.
G. Prohibition on Storage
Today's notice proposes to treat
storage of the California list wastes in
the same way as other restricted wastes.
as noted in the solvents and dioxins
final rule (see 51 FR 40572, November 7,
1986). In that final rule, the Agency
prohibited storage except for the
purposes of accumulating such
quantities as are necessary to facilitate
proper recovery, treatment, or disposal.
The Agency has established in the
regulation a rebuttable presumption that
such storage is necessary (the burden of
proof is on the Agency to show that it is •
not necessary). Storage of restricted
wastes for longer than one year is
allowed provided that the owner/
operator is able to demonstrate that the
* additional time is required solely to
accumulate quantities of waste that
facilitate the treatment and disposal of
restricted wastes. These requirements
are codified at 40 CFR 268.50.
H. Facilities Operating Under a Permit
or Interim Status
The Agency is proposing two
amendments to Part 270 to give
treatment and storage facilities more
flexibility in handling restricted wastes.
Fust, the Agency is proposing to allow
permitted faculties to use the minor
modification process to obtain approval
to change their facilities to free* or store
restricted wastes in tanks or containers
as necessary to comply with the Part 268
land disposal restrictions. Second, EPA
is proposing' to allow interim status
facilities to expand then* operations by
more than 50 percent to treat or store
restricted wastes in tanks or containers
as necessary to comply with the Part 288
land disposal restrictions. (See Section
rv.j.}. These modifications would cover
all restricted wastes, and not just
California list wastes.
/. Treatability Variances
The Agency is requesting comment on
a simplified (non-rulemaking) procedure
for granting treatability variances. (See
Section IV.L. in this notice.)
III. Scope and Applicability
A. RCRA Section 3004(d) Requirements
The RCRA section 3004(d) provisions
prohibit the land disposal of hazardous
wastes containing California list
constituents above specified
concentrations. With the exception of
halogenated organic compounds
(HOCs); the restricted wastes are
liquids. In order to be subject to the
section 3004(d) provisions, a given waste
must meet each of the four criteria
discussed in this section: (1) The waste
must contain a constituent specified in
the California list provisions in section
3004(d) or have a pH less than or equal
to two (2.0); (2) the physical form of the
waste must be a liquid (except for
HOCs); (3) the waste, containing the
California list constituent must be listed
or identified as hazardous under RCRA
section 3001 (as implemented in 40 CFR
Part 261); and (4) the waste must contain
a concentration of one or more
California list constituents at or above
the levels specified.^ section 3004(d) (or
more stringent levels that may.be
promulgated by. EPA).
1. Definition of California List'
Constituents —
The California list metals are easily
detilled with reference to the periodic
table of elements. The requirement
applies both to individual constituents
and to the relevant metal portion of any
compounds containing California list
metals. The Agency is proposing that
wastes having a pH less than or equal to
two (2.0) are to be determined using the
method specified for determining the
characteristic of corrosivity at 40 CFR
, 261.22. The proposed definition of PCBs
is consistent with an existing definition
in the PCB regulations promulgated
under the Toxic Substances Control Act
(TSCA) at 40 CFR 7613. HOCs are
defined to include any halogenated
organic compounds either identified or
listed as hazardous under 40 CFR Part
281 or listed as a hazardous constituent
under 40 CFR Part 261, Appendix VIH.
An alternative definition being :
considered would not limit HOCs to
those specified in Part 261. Cyanides are
defined as any substance that can be
shown as having a resonance structure
containing a carbon-nitrogen triple
bond. More detailed definitions of
wastes containing cyanides. PCBs, and/
or HOCs are provided later in the
preamble sections addressing those •
constituents.
2. Physical Form Requirement
Except for HOCs (which are
prohibited from land disposal in both
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Federal Regular / Vol. si. No. 238 / Thursday. December 11. 1986 / Proposed Rutea
liquid and non-liquid form), RCRA
section 3004(d) prohibits the land
disposal of California list wastes only it
such wastes exist in liquid form.1 For
purposes of determining whether a given
waste is a liquid, the Agency is
proposing to require that the Paint Filter
Liquids Test (Method 9095 in EPA
Publication SW-846) be used. On April
30,1985 (50 FR 18370), EPA promulgated
a final rule requiring use of the Paint
Filter Liquids Test in determining
whether a waste sample contains free
liquids. Today's proposal is consistent
with this existing requirement
The California list wastes are
determined to be liquids, and, therefore,
potentially subject to the section 3004(d)
prohibitions, at the point of disposal.
While this differs from the final solvents
and dioxins rule, which requires that
wastes are determined to be restricted
from land disposal at the point of
generation (see 51 FR 40572, November
7.1988), EPA believes that determining
whether the California list wastes are
liquid or non-liquids at the point of
disposal is consistent with
congressional intent
Except for the HOC wastes, which are
prohibited in both liquid and non-liquid
form, Congress was concerned with the
land disposal of California list
constituents only in their liquid or
mobile form. Therefore, a liquid
hazardous waste containing a California
list constituent may be treated so as to
render the waste a non-liquid and
subsequently land disposed without
being subject to the restrictions hi
section 3004(d). It should be noted that
RCRA section 3004(c) (as codified at 40
CFR 264.314 and 285.314) requires that
bulk or non-containerized liquid
hazardous waste* be rendered non-
liquid by means other than by the use of
absorbent* prior to placement in a
landfilL
3. Hazardous Waste Requirement
RCRA section 3004{d)(2J state* that
the California list land disposal
prohibition "applies to the following--
hazardous wastes listed or identified
under section 3001." According to the
plain language of this provision, section
3004(d) applies only to those wastes
which are listed as hazardous under 40.
1 EPA wtU addnM non-l!q«id fora* of the
California 1IU wutc* (except PCBt. which are not
currently regulated u RCRA. hazardous wutei) at
later date* in accordance with urn cchedvfe
finallad on May 2*. 1068 (51 FR 18300). Uiiad
wailei containing metals In a non-liquid matrix will
be addressed pursuant to tho various time frame* in
lha find schedule and noo-Uqidd waste* Identified
by chancteriiUc will be addressed no later than
May 8,1990. hi accotdance with the proviitoni in
RCRA lection 3004(gM and the final schedule.
—^_.^_MH«
CFR Part 281 or exhibit one or more of
the characteristics of hazardous waste
identified in Part 281 (i.e. ignitability.
corrosivity, reactivity, or toxicity), and
which also contain a California list
constituent as defined above.
4. Concentration Levels Prohibited From
Land Disposal
The California list prohibitions in
RCRA section 3004(d) establish certain
concentration levels above which there
is a strong statutory presumption against
land disposal. The only circumstances in
which California list wastes may be
land disposed in concentrations above
the levels specified in section 3004{d) (or
those more stringent levels as may be
promulgated by EPA) are those cases
where the waste meets a treatment
standard established under section
3004(m) or, as provided for in section
3004(d)(l), a petition has been granted
based on a demonstration that "to a
reasonable degree of certainty, there
will be no migration of hazardous
constituents from the disposal unit or
injection zone for as long as the wastes
remain hazardous." (See the solvent! -
and dioxins rule final at 51FR 40572,
November 71888. for a more complete
discussion of the petition process.)
Although RCRA specifies allowable
concentration levels for each of the
California list constituents, the statute
directs EPA to establish more stringent
concentration levels when necessary to
protect human health and the
environment This requirement applies
when the Administrator has sufficient
evidence to show that there is a
substantial threat to humans and the
environment when wastes containing
statutory concentrations of California
list compounds are land disposed. The
Agency recognizes that the California
list prohibitions were only intended as •
starting point in minimising reliance on
land disposal Land disposal of listed or
characteristic waste* containing these
constituent* will be reevaluated
according to the Agency's final schedule
for promulgating land disposal
restrictions (51 FR 19300).
Considering the factor* specified by
Congress. EPA acknowledge* that many
of the California list constituent* may be
toxic, persistent, bioaccusnulative.
mobile and corrosive. EPA believe*,
however, that the primary purpose of
the statutory concentration limits is to
control the timing of EPA'a review of the
wastes containing the California list
constituents. The statutory
concentration limits were not intended
to distinguish wastes that are
appropriate for land disposal from those
that are not. Indeed, the legislative
history indicate* that no presumption i*
to be drawn that tea* concentrated
wastes are less hazardous. See KR.
Rep. No. 196,98th Cong., 2d Ses*., Part 1,
at 34 (1983). Rather, the statutory
thresholds were intended to require EPA
to consider under section 3004(d) those
wastes containing constituent
concentration* that are dearly "highly
toxic," while allowing the remainder of
the wastes to be reviewed according to
the schedule in section 3004(g). See S.
Rep. No. 284,98th Cong., 2d Ses*. 17
(1983). Thus, the constituent
concentrations of wastes that fall below
the California list levels still may be of
concern. In the context of this statutory
structure and legislative history, EPA
believes that in order to show that more
stringent concentration limits are
necessary to protect human health and
the environment, EPA should show that
wastes containing concentrations of
constituents below the statutory
thresholds are of such concern mat they
should be considered on an accelerated
schedule rather than under the schedule
in section 3004(g). EPA does not have
such data for any of the California Bit
wastes. For this reason, the Agency^*
proposing to defer to the statutory levels
for the California list wastes. These"
wastes will be addressed as part of the
schedule for restricting wastes for land
disposal and establishing BOAT (51 FR
19300).
However, as noted in the summary of
today's notice, the Agency is requesting
comment on an approach that would
substitute more stringent concentration
level* for at least those metal-bearing
waste* for which EPA h«* already
established EP toxicity limit*. Although
EPA doe* not have data to suggest that
lower level* (such a* the EP toxicity
levels) for the CaHIbmia list metal* are
necessary to avoid substantial risk* to
human health end tte environment
when waste* are dtepoud te hazardous
waste disposal fadatiea, the Agency i*
concerned with the-taxkity and
p existence of torn* metal* when placed
in othOT type* of land disposal fecHitie*
and. therefore, reqaest* comment and
data on possible hazard* posed by these
compound* in Subtitle GJacilaie*. In
establishing the EP toxicity terete, EPA
modeled « mismanagement scenario
involving co-dispo*al of waste* toaa
actively decomposing municipal landfill
overlying a grouad Water aquifer {45 FR
33110, May 1ft I960). Given the- .
additional technological requirements
for RCRA hazardous waste dicpoeal
facilities, diapoaatof waste* below the
statutory level* may not pose such a
severe threat as to warrant
consideration of such wastes in this
-------
fesfaal
«KdL a.
./ afauadap, December aa. CTO6 / ftopoged fhg»
rularndking rather thanomdsr aeotinn
30Q4fe).
5. /mpocf of the RCRA SetHion -300t(dJ
Liquids in Landfills Prohibition
•Effective "Mays. 1985,,'RCRA section
3004fc)fr) prohibits theplacemertt-rif
bulk omon-containerizEdiliquid
hazardous waste or free liquids
corrtained'in 'hazardous waste '{Whether
or not absorbents 'have 'been added) in
any landfHL'THis Statutory prohibition
was codffied'byEPA.in TO CFR 284.314
and.265.314 onjuljr I5,1985;(SOFR
28702), and.it extends to .liquid
California list wastes, liquid wastes. that
meet treatment standards promulgated
under 8£Krtion3flW{nl)thut wihimi:haxe
-
no longer a RCRA hazardoustwaflte.^nd
those subject to a successful petition
granted under 49 CTR Part 268.
Furthermore, even.where.the waste is no
longer hazardous, section 30Q4(q](3)
(also codified at 15 28*314 and265314>
prohibits its plaoement.pn most casaa)
in a hazardous waste landfill. Because
these prohibitions apply to the same
category of wastes that are the major
focus of the.Calffornia list prohibitions
(i.e. liquid hazardous wastes), today's
proposed rule will impose additional
requirements an Subtitle C landfill
operations only to .the extent that such
landfills. dispose of nonJiquid hazardous
wastes containing greater than 1,000
mg/kg HOCs. Therefore, the primary
impact of .the California Hat prohibitions
is on landtdfflpoaalin fadlilties other
than landfilfa.fe.g.rsurface
impoundments).
C. Exemption forTtfeatmentJn Surface
Impoundments
Restricted wastes.may.bejjlaced.in
treatment^urlaceimpnunrimeTita.under
certain conditions as auihorized'by
RCRA sections 3005(0(1^) (A) and (B)
and.implemented'in 40'CFR.28&4.«? .*P .incliirip
tfit» r
because .these tan -no longarprohihited
wastes andmDuldibetdiBposad.in.anather
surface dmpoundmant.
ListWastw
A. Testing(and,RecQtdkBeping
RstpiiiBtnBnts
1. Definition of a'liiquid
Exceptiortthfl halngenated.ofganic
that alLofttheuKaetea thottaieiteibe
restriotadifconnlflndidiapoaalaiBteithar
liquids orMinaflUfifinng
comment (on
a. Analysis nfdftBiRamt JUherJuguiA
. Me State tofCalifaniia.
to detemdneiff a-xesstea aiUqmti.
identifies theJaaarinusicaiatiiiiBnisiitf
concern tbjramatyamgamiy the JMnt
Fiiter,Linuid8lEejitffinrate.rSinae-
Cpngaess adtg«tBri(thed^WA land*
disposal ae8triuBuuBinfago%)froBt-
Cauframa'jiprogram, She Agency _'
considetedanaijwnjg'oillynheiPaint"
Filter XntiffltMte toidetennine wAether
the restriction levels were exceeded.
The 'Agoncyj* notipropoiing^his
approach
congressinnaliaonoHni^bainillie
and tha
that may be entrained in thewnte
matrix, and which' may leach out over reaianB'ftBt
teHHJ? wroi^fcaBlfar 'M wclL'rfaB..
possibility •flnH'6ra»g-conaUtueiU8,^faen
fnt^'o*
Congresses-well. 'Pherefbre.'flie Agency
today proposes *th€it the Toxhrtty
-------
44720
Federal Register / Vol. 51. No. 238 / Thursday. December 11. 1986 / Proposed Rules
14
i
i
Characteristic Leaching Procedure be
used on wastes that have been defined
as liquids by the Paint Filter Liquids
Test and to generate a leachate from
which it may be determined if those
wastes exceed the California list
restriction levels. In the TCLP,
depending upon the percent solids
content of the waste, an initial liquid
filtrate and the test-generated leachate
may be combined for both qualitative/
quantitative analysis. The procedure is
designed so that potentially mobile
constituents are likely to leach from the
waste matrix and be present fa the
collected leachate. Thus, the potentially
mobile fraction of the constituents fa the
waste are considered
c. Total constituent analysis. A third
approach considered by the Agency is
the total constituent analysis. This
approach, which would be the most
conservative of the three, would analyze
the entire waste sample for constituents
of concern, and may more directly
account for the effects of direct
exposure (e.g., dermal exposure or
Inhalation). However, the Agency does
•not believe that direct exposure is a
significant problem for these wastes
following land disposal fa a properly
operated land-disposal facility and
therefore, believes that this approach is
not necessary.
d Analytical methods. The Agency is
recommending that the methods found
fa 'Test Methods for Evaluating Solid
Waste: Physical/Chemical Methods,"
SW-«4a, 2nd ed, July 1982, as amended
be used for the qualitative and
quantitative analysis of hazardous
wastes containing the California list
constituents of concern whenever such
tests are necessary as proposed fa
today's notice.
4. Recordkeeping
Today's notice proposes to adopt
where applicable, the recordkeeping and
certification requirements that have
been established fa the regulatory
framework fa the solvents and dioxfas
final rule for implementation ofthw •
California list landdisposal restrictions
rule. (See 51 PR 40572, November 7,
1986.) The Agency is also considering •
modifying those requirements to require
periodic testing by generators. The •
California-list prohibitions also differ for
solvents and dioxfas fa that wastes
meeting the threshold level can continue
to be kind disposed regardless of
whether a treatment standard has been
met Wastes rendered non-liquid (except
HOCs) can be land disposed as well
The recordkeeping and certification
requirements will be modified to
account for this difference.
B. Cyanides
According to section 3004(d)(2),
effective 32 months after the enactment
of the Hazardous and Solid Waste
Amendments of 1984, "liquid hazardous
wastes . . . containing free cyanides at
concentrations greater than or equal to
JOOO rag/I" are subject to the land
disposal restrictions. In order to
characterize the wastes that will be
subject to section 3004{d)(2), the Agency
must define the term "free" cyanides.
However, a review of the literature
indicates that there is no widely
accepted definition of the term.
Therefore, for the purposes of this
rulemaldng, EPA considered using a
very narrow definition of "free"
cyanides as that cyanide present as CN*
and as molecular HCN. However,
complex cyanides are known to
dissociate to form CN' and HCN under
conditions that may exist in the
environment Because of this
phenomenon, cyanide-containing wastes
that would be exempt from the land
disposal restrictions if the Agency were
to use the narrow definition could
produce "free" cyanide after disposal.
Because of the potential dissociation
of complex cyanides and the difficulty hi
defining the term "free" cyanides the
Agency is proposing to take a
conservative approach by assuming that
any liquid hazardous waste" containing
free or bound cyanide may be subject to •
the requirements of section 3004(d)f2}.:
The Ageacy'sf approach is described in
more detail below: : . , • . ;
1. Definition of "Free" Cyanide
There is .currently no regulatory
definition for "free" cyanide, not is there
a commonly accepted definition based
on an analytical method According to
Standard Methods for the Examination
of Water and Wastswater (16th edition,
1985) (Ref. 4), free and potentially
dissociable cyanides may be estimated
as weak add dissociable cyanides or as
cyanides amenable to chlorination, with
the exception of certain industrial
wastes (e.g^ steel industry and .
petroleum refining wastes and pulp and,
paper effluents) that cantata substance* '
that may interfere with the latter test >
The definition of "free cyanide" in The
Annual Book of ASTMStandatda (1984}
(Ref. 5) is similar, and refers to the •
cyanide ion that is determined by
titration with silver nitrate without
pretreatment for complex dissociation.
Other-methods include the colorimetric
method using chloramine-T and the
cyanide-selective electrode test method.
Both Lowenheim (1978) (Ref. 8) and
Cherry (1982) (Ref. 6) used the definition
approved by the American Society of
Testing and Materials (ASTM) fa B374,
Standard Definitions of Terms Relating
to Electroplating:
Free cyanide:
True: "The actual concentration of cyanide
radical (QN- or HCN) or equivalent alkali
cyanide, not compounded in complex ions
with metals in solution."
Calculated: "The concentration of cyanide
or alkali cyanide, present in solution in
excess of that calculated as necessary to
form a specified complex ion with a metal or
metals present in solution."*
Analyticak "The free cyanide content of a
solution as determined by a specified -
analytical method."
According to Electroplating, the
definition of "free cyanide" is not .
straightforward:'
Free cyanide is "intended to represent the
concentration of cyanide ion beyond that
required to form the metal-cyanide complex
in question. Therefore, its determination
requires a knowledge of the formula of the
metal-cyanide complex, and this is not
always known with any certainty . . .
Therefore, since we do not know-how much
of the total cyanide is tied up with tEe metal.
we cannot know how much of it is free.
Hence, where possible, it it preferable to
specify, and determine, total cyanide; if free
cyanide must be known, the formula of the
complex is chosen arbitrarily, as the most
probable of the several possibilities." ' .
(Lowenheim, 1978.)
' The various definitions provided
above support the Agency's Assertion
that currently there is no commonly :
accepted definition of "free cyanides."
2. Dissociation of Complex Cyanides .
Some complex cyanides (e.g., cyanide
salts, cyanogens) can be converted to
free cyanides •under certain chemical
conditions that can exist in the
environment According to Standard
Methods (1985) and Kelada et al. (1978)
(Ref, 7), silver and nickel cyanide
complexes dissociate slowly, while the
strong metal cyanide complexes of
cobalt gold; iron, and platinum -\o not
dissociate readily. However, dilute '.
.solutions of.iron cyanide dissociate .
rapidly.upon exposure to ultraviolet ...
light, producing free and simple .
cyanides; Kelada etal. (1978) analyzed
solutions, of nitriles, various motal
cyanide complexes, and other
potentially cyanide-forming materials
for free and simple cyanides. The
researchers detected free cyanide in
cadmium and nickel cyanide complex
solutions and in the cyanohydrins. In
that study, free cyanide was not :
detected in the nitrile, cyanate, and
thiocyanate solutions.
-------
fierfarai fagkter / IfaL m, Jfa. SM ,/ Ihaiaday, ,DBceafrer ta. $966 / PaposeA Brim -45721
3.
Because wf -tire potential for -complex
cyanides 'to -dissociate •and'because -of
1he dffictttty'in definfaig'tte tenn "free"
cyanides. *e Agency iritendsto talce a
conservative approach -by assuming-that
all cyanide-containing or '.potentially
cyanide-forming wastes may contain
free cyanides. Therefore, any-waste
con taming -a compound ihat'can be
shown to have >a -resonance -structure
with a carbeiwu'trogen triple bond is
potentially affeti ted %y section
3004(dH2J,:mduding wales that contain
free cyanides, comptexed cyanide*, and
cyanide salts.lsocyannles'contam-a'trne
cyanide triple 'bond. Because of their
toxicity-and-reactivrty, the Agency'is
proposing to also include isocyam'des'in
the definition rf cyanides, and requests
comment on this approach, .
To determine .whetheria'.cyanitie-
containing waste i« subject to the land
disposal restrictions under section
3004{d)CZ), the Agency proposes thai the
owner/operator of a disposal facility
must analyze the waste using -the
Toxicity Characteristic Leaching
Procedure (TCLP) with a zero-headspace
extractor. The owner/operator must .
then determine the concentration of
cyanide in the leachate. For this
purpose, the Agency recommends using
Method «010 for Total Cyanide in Test
Methods for Evaluating Solid Wastes,
Physical/ Chemical Methods." EPA
Publication No. SW-848.
4. Alternative Approaches
Because-strong metal cyanide
complexes do not appear to dissociate
in the environment, we are also
proposing and requesting comment on
several alternative analytical methods
that eould be used for the-purposes of
defining cyanide concentration>inthia :
rulemaking: .....
1. Cyanides detectable as "Weak and
Dissociable Cyanide," Method «2FL
Standard Methods; .
2. Cyanide amenable 'to«h1ormattaii.
3.
by direct Otralionwithoat'diBtiUation
(see
w
cyanides by causing dis«9ociation>pnor
to measuring the.solution'cyanide
strength. One or more of 1hese tests may
provide faavoie accucaieidetenninatnin
of thepptentnilTmidiflsociatiQniof
than \wouM.atatalcyHnideiest.
Specifically. ;me Agency lequeats
comments CTI its ptopaaedinterpxetathm
of section .3004f d)(2) and .on the
alternatives to Vthat 'interpretation
discussed above. The Agencyfllso
requests .comment -on Ihe analytical
method that should'be used to
determnw Ihe cyamo^ concentrttion-in
the tearbate'of:a waste !Tor»melpurp oses
df 'this flection. The ?Vgency -also solicits
comments -on the dissociation of
comp'lex cyanides and data
demonsterting the-extent to which free
cyanides «re present :m-wastes
containing complex cyanides.
C. California 'List -Metats
1. Characterization
The i9844iSWA amendments (to
prohibit;(amongiertherrthinga) theiand
disposal of iKnuidihaaardaus waatea
containing-concentBalions of certain
metak^zeater >than AT equal .tD.-apeoifkd
levels unless the waste comphes iwith
EPA-establkhed tnatmentatandaidiior
is the subjactiof a successful petition.
This group of metals-is shown below-m
Table!.. . .
Table 1.— California List Itfetals and
Concentrations
Arsenic and/or compounds (as As)— 500
mg/i.,. ..-•-. i ...•-• . .,
Cadmium and/or £empoundai(aa'Gd}—-
lOOirag/1
Chromium-(VI and/or compounds fas Or
VI))-500ing/l
Lead and/or compounds (as Pb) — 500
mg/1
Mercury and/or compounds (as Hg) — 20
mg/1
Nickel and/or compounds (as NQ— 134
Selenium and/or compounds (a« Se)—
100ang/l
Thallium and/or compounds (as ,T3)—
130 mg/1
These metaU^weieaeleotedbetsauxe
their effeoto .have, been.been -widely
studied and >their toxicitieBffineiaUjr
recognized. Additional discinaion^onihe
tnarim'rip« of thmm n-ji
persistence m.the enviionmmit and
their accunence.in wastes.'is -presented
in the hnAgwmnd dnmimMit .fnr.thU
propond rule.
2. Two Approaches "to Umit the TLand -
Disposal of CalifomiaiiiatMBtak
The Agency has consideredtwp
approaches to Jimitmg-fln land disposal
approache*
&. Proposed approach: codifiGBtionjjf
statutory Javek-io3bs abwnoe-of data
showing.itiU necessary to lower Ihe
statutory conceiilBUiiuitK'liiiflts, the
Agency jsioday.pioposingtoicodlfyithe
statutory tend jdisposaliestricUcnitevels
found in section.3a)4(d)(2).
point jaainatknialiBi8B«t'to'piohibit!tne
land disposal of hazardous wastes. The
Agency,may aubau'tutejnore -ateingeilt
reatrian'ons levels; jhaweiser. the Aganpjr
is authorized ;tolo»rer;thB.Califo»mflltot
irestdctiao lexela anlytf&A. detesmines
that.the statutory levels.are^not
protective of hitman haalth griff fhft
environmpn^ In orfler.tnjirfunn'lgata
reattictionlevels .thai ace lower than
those provided in the statute, the
Agency must have adequate data
indicating that, considering the
persistence, loxicity,. mobility and
potential for bioaccumuhttitm of Ihe
Califomia'list metals, wastes-betowtim
statutory Tcstriction teveh are of such
concern that they should'be considered
in this nilemaleing rather'than later
pursuant to the schedule esta%h«hed ,
under section JflW(g]. However, at>thij
tme.'tae Agency ladcsiadeqnate data to
indicate that such a determination,is
necessary. Therefore, .the .Agency is
projBoaing toxodify the land disposal.,.
restrictionjules foriheiGalifojaajaJiit..
wastes at,the8tatutary,kwel«,.an3 ..
(EP) toxicity characteristic levels. As
discusaed.earh'er, Congress authorizes
the Administrator to establish standards
below those specified in the California
liat if he concludes that lower levels are
necessary to-protect human health .or
the environment Intirder to make these
findings, ihe Agency must conclude that
the concentrations ottfaemetals should
be reduced to -some lower leveL:
determine Ihe-Ci>iicenlntliuii3 'JOT metals
that would-be-protective, ^nd:be-able to
provide a rational basis fer-auch a
reduction.
The extraction procedure hwdcity
charactenstic (EP) has been defined H -m
maadmum contamfnant conceBtratipn
level which, wmm axoeeded, •wtilvender
vtn Hiilil nU^ir
of these waste* Jna:saait»jriandfill'or;
^
juuliibitad*
meet tha'toi
preseBt.a>hazuri to>homan
-------
44722 Federal Register / Vol. 51, No. 238 / Thursday, December 11, 1986 / Proposed Rules
.
substantial present or potential hazard
to human health or the environment
when it is improperly treated, stored,
transported, disposed of or otherwise
managed."
The EP toxicity values were based on
the National Interim Primary Drinking
Water Standards (NIPDWS) (see 40 FR
59566). The NIPDWS, which must be met
by public drinking water systems, are
considered to be the levels at which
chronic exposure to drinking water
contaminants will not cause adverse
health effects. However, the Agency
does not have adequate data to
demonstrate that land disposal of the
California metals at concentrations
below the statutory levels poses a
degree of hazard that necessitates
accelerating the schedule for
consideration of wastes below the
statutory level.
The EP levels were developed by
using a scenario that was based on the
co-disposal of the metal-bearing wastes
with municipal waste in a Subtitle D
facility. Since they are lower than the
statutory levels, they-are more
conservative than the statutory levels.
However, it is not dear that lowering
the levels to the EP levels is required to
protect human health and the
environment for a waste disposed of in
a Subtitle C hazardous waste disposal
facility.
The Agency is soliciting comment and
data that would support lowering the
restriction levels for metals to the EP
levels or to concentrations other than
the EP levels for the California list
metals. The Agency has not promulgated
EP toxidty characteristic levels for
nickel and thallium. Since the Agency
has no data that would support lower
levels for these metals to any other
level, one approach-would be to adhere
to the statutory requirements. Another
approach would be to follow the
apparent rationale used by California
which, since no NIPDWS standards had
been developed, multipHeH the-Ambient
Water Quality Criteria (AWQC) for
nickel and thallium by a factor of 10,000.
Since the EP level* for the California list
metal* are 100 times less than the
statutory requirements, the Agency, in
.order to be consistent, would also
consider lowering the restriction: levels
for nickel and thallium to 1.34 and 1.30
mg/L respectively, if this approach were
to be adopted. The Agency solicits
comments or data that would support
this approach or that Would suggest a
different approach.
D. Corrosives
1. Characterization of Corrosive Wastes
Congress mandated that liquid
hazardous waste having a pH less than
or equal to two be prohibited from land
disposal effective 32 months from the
date of enactment of the HSWA. The
EPA has identified the principal
corrosive hazardous waste as EPA
hazardous waste D002. D002 wastes are
hazardous by virtue of exhibiting the
characteristic of corrositivity. Corrosive
wastes are generated primarily by the
Chemical and Allied Products Industry
(SIC 28) and the Primary Metal and
Fabricated Metal Products Industries
(SICs 33 and 34). Additionally, many
corrosive wastes also contain other
California list constituents, such, as
metals and cyanides. An example of
such a corrosive waste is hydrofluoric
acid etch from the semiconductor
industry. Similarly, EPA hazardous
waste K011 was identified as a potential
California list waste for both its
potential acidic nature and the
occurrence of cyanide.
2. Effect of Corrosive!] on Liners
Corrosive wastes are acutely toxic
and damaging to living tissue. However,
in addition to hazards associated with
toxicity, corrosive wastes also present
risks to human health and the
environment as a result of their
reactivity with other wastes and liner
materials. The Agency has conducted
studies to assess the impact of these
wastes may result in the formation of
reaction of acids with codisposed
wastes may result in the formaiton of
toxic and flammable gases and in the
solubilization of toxic substances from
the waste matrix Acidic wastes may
also degrade clay liners and contribute
to the mobility- of other hazardous
constituents, in the environment, but are
not generally incompatible with
synthetic liner materials, (refs: Goldman
and Tatsch, May 1985) (Ref. 13), While
these data are not pH-specific, they
indicate, nonetheless, that strong adds
are potentially hazardous or may
contribute to increased hazards from
other materials when land disposed.
3. Proposed Approach and Rationale for
the Statutory Level
EPA is proposing to impose the
statutory level of leas than or equal to a
pH of two (2.0). This level is consistent
with EPA's current approach to defining
waste as hazardous based on the
characteristic of corrosivity, and in the
absence of data indicating that weaker
acids present a hazard to human health
and the environment when disposed of
in a Subtitle C facility, EPA is not
considering modifying the statutory
level at this time. The Agency is
requesting comment on pH-spedfic data
regarding the effects of corrosive wastes
on both clay and synthetic liners and
codisposed wastes.
4. Treatment Standards
The Agency is proposing that
treatments which neutralize corrosive
wastes to above two (2.0) are
considered to be BDAT treatment for the
characteristic of corrosivity. Wastes so
treated will no longer be considered
California list wastes (in fact, wastes
with a pH of above two are not
considered characteristically hazardous,
and may be land disposed in a Subtitle
D facility).
The Agency requests comment on
whether this type of treatment should be
codified as a treatment-method
(§ 268.42), or performance-based .
standard (S 268.41).
E. Polychlorinated Biphenyls (PCBs)
1. RCRA section 3004(d)(2)(D)
Requirements
Effective July 8,1987, RCRA section
3004(d)(2)(D) prohibits the land disposal
of liquid hazardous wastes containing
polychlorinated biphenyls at
concentrations greater than or equal to
SOppm.
a. Definition of polychlorinated
biphenyls (PCBs). For the California list
restrictions, the Agency is proposing to
define PCBs consistent with the
definition in 40 CFR 761.3. That
provision defines PCBs for purposes of
regulation under the Toxic Substances.
Control Act (TSCA) as "any chemical
substance that is limited to the biphenyl
molecule that has been chlorinated to
varying degrees or any combination of ..
substances which contain such
substance." In addition, inadvertently
generated PCBs are defined as "the total
PCBs calculated folio wing division of
the quantity of monochlorinated
biphenyls by 50 and dichlorinated
biphenyls by 5." This, was inserted in the -
TSCA regulations in recognition that
monochlorinated biphenyls are less
toxic and persistent than dichlorinated
biphenyls, which are themselves less
toxic and persistent than
polychlorinated biphenyls with greater
than two chlorines.
In the absence of an alternative
definition of PCBs specified hi RCRA.
EPA believes that it is reasonable to
adopt the existing definition as stated in
the TSCA regulations. The-definition is
intended to account for differing degrees
of hazard assodated with different
compounds. Such a determination
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Federal Renter / .Vol
appear* to be consistent with the intent
of Congress in section 3004{dJ to
concentrate on wattes that are known
to create substantial risk Moreover, the
Agency believes that an alternative
definition would add confusion to an
already complex and overlapping
framework for regulating PCBs. An
alternative definition being considered
would not employ the use of division
factors for inadvertently generated
PCBs. Under this definition, PCBs would
be defined as "the biphenyl molecule
that has been chlorinated to any
degree." EPA does not believe that this
interpretation is consistent with the
intent of Congress.
b. Hazardous waste requirement.
Since PCBs are not listed as hazardous
wastes under RCRA, PCB-containing
wastes are only subject to the section
3004(d)(2](D) prohibition if they are
mixed with wastes which are listed as
hazardous under 40 CFR Part 261 or
exhibit one or more of the
characteristics of hazardous waste
identified in Part 261.
For example, transformers often
contain both PCBs and hazardous
constituents listed at 40 CFR Part 261,
Appendix VIE. However, if the waste
containing these constituents is not a
listed or characteristic hazardous waste,
the section 3004(d)(2)CD) prohibition will
not apply. For example, some
transformers contain isomere of
tetrachlorobenzene and
trichlorobenzene. Although several of
these isomers (e.g. 1.2,4,5-
tetrachlorobenzene and 1,2,4-
trichlorobenzene) are listed as
Appendix VTH hazardous constituents,
EPA has not listed wastes containing
these isomers as hazardous where the
source of the waste is a spent dielectric
fluid. Consequently, these PCB-
containing spent dielectric fluids will be
subject to the section 3004{d)(2)(D) land
disposal prohibition only if they are
mixed with a listed hazardous waste or
if they exhibit a characteristic identified
in Part 281.
c. Proposed approach. The prohibition
in section 3004{d)(2)(D>applietonIy to
liquid hazardous waste*containing- • -
PCBs at concentrations greater thto or
equatto5Oppm.EPAi»proposingto -
codify the 50 ppm prohibition specified
in HSWA. This level is consistent with
the comprehensive PGB regulations
existing under the Toxic Substances
Control Act (TSCA). and EPA does not
have information to suggest that a
different level is necessary.
2. Existing Regulation of PCBs
Regulations promulgated pursuant to
TSCA currently address the land
disposal of PCB wastes. The TSCA
requirements at 40 CFR Part 751 vary
depending on the concentration of PCBs
in the waste and % physical form in
which the waste is disposed, i.e.,
whether the waste is disposed in bulk
. liquid form, as a containerized liquid, or
as a non-liquid. Disposal of PCBs at
concentrations below SO ppm are not
regulated under TSCA unless they were
created by diluting a higher
concentration of PCB or are used in
specified ways, i.e. as a sealant coating,
dust control agent, pesticide carrier, or
as a rust prevention agent on pipes..
Uquid PCBs at concentrations greater
than or equal to SO ppm but less than 500
ppm may be incinerated or burned in a
high efficiency boiler. This may also be
land disposed pursuant to the TSCA
regulations, but with certain limitations.
some of which are summarized below.
Liquid wastes containing PCBs at
concentrations greater than or equal to
500 ppm must be incinerated according
to TSCA regulations or disposed of by
any other approved alternate methods
(40 CFR 761.60(e)) that can achieve a
level of performance equivalent to the
technical standards set in 40 CFR 761.70.
Such wastes cannot be land disposed
without prior treatment
3. Relationship Between HSWA and
Existing. Regulations
Several provisions in HSWA impose
restrictions on the land disposal of PCB
wastes which are not contained in the
existing TSCA or RCRA regulations. The
TSCA regulations at 40 CFR 761.1(e}
clearly state that where there is an
inconsistency between TSCA and RCRA
standards, the more stringent
regulations govern. In addition, the
legislative history to an unrelated
provision (H, R. Rep; No. 198, Part 1.98th
Cong., 1st Sess. 56 {1983}) suggests that
allowing the more stringent provisions
to govern is also consistent with
Congress'understanding of the
regulatory scheme.
a. Disposal of bulk liquids containing
PCBs. Under 40 CFR 761.75(bK8)(ii). bulk
liquids containing PCBs at
concentrations below 500 ppm may be
disposed in a TSCA approved landfill' '
stabilized to eliminate the presence of
free liquids prior to final disposal. This k
regulation is superseded in part by •
RCRA section 3804(G)(1) (codified at 40
CFR 284.314 and 265.314) which
prohibits the placement of bulk liquid
hazardous-wastes in landfills even
where absorbents have been added.
Therefore, if the bulk liquids containing,
PCBs are unhazardous waste or are
mixed with a RCRA hazardous waste,
the resulting liquid waste is prohibited :
from being placed in any landfill.
regardless of the concentration of PCBs
(even if below SO ppinjr unless the waste
is rendered non-liquid by means other
than the use of absorbents (e.g. chemical
stabilization and certain types of
solidification). However, if the
concentration is greater than or equal to
50 ppm, all types of land disposal are,
prohibited under RCRA section
3004(d)(2)(D).
Even where the PCB-containing waste
is not a RCRA hazardous waste, section
3004(c)(3) of RCRA (which is codified at
40 CFR 264.314 and 265.314) prohibits
liquid wastes from being placed in a
hazardous waste landfill that is
regulated under RCRA unless the only
reasonably available alternative is
placement in a landfill or surface
impoundment which contains or may
reasonably be anticipated to contain'
hazardous waste and such disposal will
not present a risk of contamination of
any underground source of drinking
water. However, because the TSCA
regulations at 40 CFR 761.75(b)(8)(ii)
require the elimination of free liquids
from wastes containing greater than or
equal to SO ppm PCBs prior to placement
in a landfill, obtaining an exemption: • •
under section 3004(c)(3) will not jelieves
an owner or operator of the obligation to
solidify such, wastes prior to landfilling.
b. Disposal of containerized liquids
containing PCBs. The TSCA regulations
allow containerized liquids with less
than 500 ppm PCBs to be disposed of in
an approved landfill if each container is
surrounded by an amount of inert
sorbent material capable of absorbing
all of the liquid contents of the
container. RCRA section 3004{c)(2)
directs EPA to promulgate regulations
minimizing the disposal of containerized
liquid hazardous wastes in landfills and
to minimize the presence of free liquids
in containerized hazardous waste to be
disposed of in landfills; Until such
regulations are promulgated, existing
RCRA regulations a*40 CFR284.314 and
285.314 apply to the disposal of
containerized liquid hazardous wastes.
Those regulations require the waste to
either be placed in very-small
containers, such as an-ampule, or •
require any free standing liquid to be
eliminated through.solidification.
mixture with absorbents, decantation, or
other methods: '-. '••'••• - .
Where the containerized liquid
hazardous waste is mixed With PCBs
and the PCBs are present hi'
concentrations greater than or equal to
50 ppm, section 3004(d)(2)(DJ supersedes
the existing RCRA regulations
mentioned above and all types of land
disposal are prohibited; If the
concentration of PCBs in the
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44724 Federal Register / Vol. 51, No. 238 / Thursday, December 11. 1986 / Proposed Rules
s>
»•»'
1
I
containerized liquid hazardous waste is
below 50 ppin, the RCRA regulations for
disposal of liquid wastes at 40 CFR
264.314 and 265.314 apply. Where the
containerized liquid PCS waste is not
mixed with a RCRA hazardous waste,
the TSCA regulations requiring that
each container be surrounded by
absorbents apply to land" disposal in
TSCA approved landfills. RCRA section
3004{c)(3), however, prohibits the
disposal of such liquids in RCRA
hazardous waste landfills in most cases
despite the fact that PCBa are not
regulated as hazardous under RCRA and
are containerized in this instance.
4. Treatment Technologies (BOAT)
EPA is proposing to establish
treatment standards for liquid
hazardous wastes containing greater
than or equal to 50 ppm PCBs. The
Agency has determined that thermal
treatment (he* treatment in incinerators
or high efficiency boilers) of PCBs
pursuant to the requirements set forth in
40 CFR 761.60 and 761.70 is generally the
best demonstrated available technology
for such wastes. As described in The
Solvent and Dioxin Final Rule (§ 268.42)
(51FR 40572. November 7.1988), the
Agency proposes to allow, Upon
approval by the Administrator, the use
of alternate methods that can achieve a
level of performance equivalent to the
high efficiency boiler standards at
§ 761.60 or the incinerator standards at
§ 761.70. See section IV.G for a further
discussion of PCB treatment
technologies.
5. Nationwide Variance From Statutory
Effective-Data , ,
EPA has determined that then is
inadequate thermal treatment capacity
for the liquid hazardous wastes
containing PCBs subject to today's
proposed prohibitions,'therefore the
Agency is- proposing a 2-year,
nationwide variance1 from the'starutory
effective date. See U&t V for a further
discussion of capacity determinations.
F. Halogenated Organic Compounds
(HOCsJ -
1. RCRA Section 3004(d)(2)(E)
Requirements
Effective July 8,1987, RCRA
§ 3004(d)(2)(E) prohibits the land
disposal of hazardous wastes containing
halogenated organic compounds in total
concentration greater than or equal to
1,000 mg/kg.
a. Definition af Halogenated Organic
Compounds (HOCs). HOC* am
compounds containing a carbon and a
halogen in the molecular formula.
Halogens include the five nonmetallic
elements in Group VHA of the periodic
table: Fluorine (F), chlorine (Cl), bromine
(Br), iodine (I), and astatine (At). For
purposes of the RCRA section
3004(d)(2)(E) land disposal prohibition,
the Agency proposes that the definition
of HOC would require the compound to
contain a carbon-halogen bond. The
Agency believes that compounds
lacking such a bond, but that have a
halogen attached to an atom such as
nitrogen, which is subsequently bonded
to carbon (e.g., aniline hydrochloride) is
not a true organohaline compound. The
proposed carbon-halogen definition of
HOCs presents a potential problem in
that it would include a number of
polymerized compounds that are
generally considered non-hazardous
because of their relative immobility.
However, EPA doen not believe that
Congress meant to include in the,
prohibition every possible HOC such as
polymers that, comprise solid plastics
and vinyls. Instead, EPA believes that
Congress was concerned with
constituents that are .mobile (e.g.,
liquids) and/or potentially hazardous to
human health and the environment
Therefore, the Agency is proposing to
limit the definition of HOCs included
under the section 3004(d)(2)(E)
prohibition to those HOCs which are
identified or listed as either hazardous
wastes under 40 CFR Part 261 or as
hazardous constituents under Part 261.
Appendix Vin. The prohibition
paragraph in section 3004(d)(l) supports
this approach in its explicit concern for
the migration of "hazardous
constituents" from the land disposal unit
or injection zone for as long as the
waste remains hazardous. The term
"hazardous constituent" it a term of art
referring to compounds listed in
Appendix VOL As previously stated, the
Agency is today proposing that organic
compounds containing a halogen atom
that is not bound directly to a carbon
atom (such as die organic salt aniline
hydrochloride} would not be included in
the universe of restricted halogenated
organic compounds. However, the
Agency solicits comment and data on
this proposal, and on a possible
alternative to that definition, which
would include compounds where the
chlorine is not directly attached to a
carbon atom, but attached to an atom
such as nitrogen or sulfur, which is
subsequently attached toa carbon atom.
An alternative interpretation would
bring all hazardous waste* containing
HOCs under the section 3004{d)(2)(E)
prohibition regardleso of. whether the,
HOC was identified or listed as a.
hazardous-waste or hazardous
constituent This approach may be more
suitable to halogenated wastes that are
determined to b* liquids under die Paint
Filter Liquids Test (and therefore are
more likely to be mobile in die
environment), but this approach would
bring many innocuous non-liquid HOCs
(e.g., plastics) within the scope of the
California list prohibitions. The Agency
does not believe that Congress intended
to regulate theie HOCs, but solicits
comments on the definition of HOCs
covered under die section 3004(d)(2)(E)
land disposal prohibition.
Unlike die other constituents specified
in the section 3O04(d) prohibitions,
HOCs are prohibited in either liquid or
non-liquid form. Because HOCs are the
only California list wastes for which
Congress specified both liquid and non-
liquid wastes for prohibition, die
Agency must identify a practical test
method for detecting HOCs and
determining the concentration of tiieae
constituents in non-liquid hazardous
waste. The Agency is proposing to
require use of the Toxicity.
Characteristic Leaching Procedure
(TCLP) to generate die analyte for both
liquid and non-liquid hazardous wastes.
However, EPA is soliciting comment on
other methods for defining and r •.'
evaluating non-liquid Wastes fotHOCs.
b. Hazardous waste requirement,
Wastes containing HOCs are only
subject to the section 3004(d](2)(E)
prohibition if the waste is listed as
hazardous under 40 CFR Part 261 or
exhibits one or more of the
characteristics of hazardous waste
identified in Part 281. However, the
waste listing or characteristic need not
be related to the HOC content of the
hazardous waste for it to be covered.
c. 1,000 ing/Jig requirement, The
prohibition in section 3004(dK2HEJ
applies only to hazardous wastes
containing HOCs in total concentration
greater than or equal to 1,000 mg/kg.
Although EPAis proposing to codify the
1.000 mg/kg prohibition specified in
RCRA. d» Agency will be evaluating
each HOC regulated as hazardous under
Part 281 in accordance with the final
schedule for implementing land disposal
restrictions (SI FR 19300). At that time,
prohibitions oa land disposal and
treatment standard* will be established
to tiie extent necessary for individual
HOCs or groups of related HOCs.
2. Relationship to RCRA section
3004fdK2)(DJ Prohibition on PCBa
RCRA section 3004{d)(2)fD} prohibits
the land disposal of liquid hazardous
wastes containing PCBs at •
concentrations greater man or equal to
50 ppm. EPA interprets-this provision as
placing an upper limit of 50 ppm on the
concentration of PCBs that may be
''I
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Federal Register / Vol. 51, No. 238 / Thursday/December 11, 1988 / Proposed Rules '' 44725
contained in a hazardous waste
containing HOCs which is land
disposed. The limitation of 50 ppm,
however, is only applicable to liquid
hazardous wastes containing PCBs,
therefore a non-liquid hazardous waste
containing PCBs at concentrations
above 50 ppm may be land disposed
without violating the section
3004(d)(2)(E) prohibition on HOCs as
long as the total concentration of HOCs
does not exceed 1,000 rag/kg. For
example, a non-liquid hazardous waste
containing 200 mg/kg (ppm) PCBs and
700 mg/kg (ppm) other HOCs can be
land disposed because the 50 ppm
prohibition does not apply to non-liquids
and because the 900 mg/kg total HOC
concentration does not exceed the 1,000
mg/kg threshold specified in HSWA
section 3004(d)(2)(E).
If the total concentration of HOCs in
either a liquid or non-liquid hazardous
waste is greater than or equal to 1.000
mg/kg, the waste is prohibited from land
disposal even if the concentration of
PCBs is below 50 ppm. For example, a
liquid hazardous waste containing 25
mg/kg (ppm) PCBs and 980 mg/kg HOCs
other than PCBs is prohibited from land
disposal under section 3004(d)(2)(E)
despite the fact that the section
3004(d)(2)(D) prohibition on PCBs would
allow up to 50 ppm PCBs to be land
disposed. Abo, a non-liquid hazardous
waste containing 400 mg/kg (ppm) PCBs
and 700 mg/kg HOCs other than PCBs is
prohibited from land disposal despite
the fact that existing regulations
promulgated under TSCA would allow
such non-liquid PCB wastes to be
disposed in an approved landfill.
3. Treatment Technologies (BOAT)
. EPA is proposing to establish
treatment standards for most hazardous
wastes containing HOCs in total
concentration greater than or equal, to
1,000 mg/kg. Incineration is proposed as
BOAT for many of these wastes. The
Agency is not proposing BDATfor :
wastewaters with less-than 10% TOC.
See Section IV.Gfor further discussion
of these technologies. j.,_ _ - ...... '_-. '.
4. Nationwide Variance From Statutory
Effective Date" • - .
EPA has determined that therein
inadequate treatment capacity for the
HOC wastes covered by today's
proposed treatment standards.
therefore, the Agency is proposing a 2-
year nationwide variance from the
statutory effective date foe HOCs for
which BOAT has been proposed. See
Unit V for a further discussion of
capacity determinations.
G. Applicable Treatment Technologies
The following section discusses
treatment standards for the California
list wastes. EPA is proposing BOAT for
HOC-containing hazardous wastes
(except for HOC-containing
wastewaters), for PCB-containing
hazardous wastes, and for corrosive
hazardous wastes. Where BOAT is not
proposed, this section includes a
discussion of those technologies that
may serve as the basis for setting BOAT
when wastes containing these
constituents are addressed later in
accordance with the final schedule,
promulgated at 51FR19300.
1. Proposed BOAT Treatment
Technologies
a. Halogenated organic compounds.
Technologies applicable to hazardous
wastes containing HOCs in
concentrations greater than 1000 mg/kg
are similar to those identified for
solvent-containing hazardous wastes
F001-F005. These technologies include
incineration, batch distillation, thin film
evaporation, fractionation, biological
degradation, activated carbon
adsorption, and steam snipping.
As explained hi the November 7,1988
Final Solvents and Dioxins rule (Si FR
40572). EPA believes that data front the
solvents rulemaklng under section 3004
support a determination that
incineration represents the best
demonstrated available technology for
most organic liquid and organic and
inorganic sludges and solids (e.g.. soils).
In that mlemaking EPA also found that
wastewater treatment technologies.
such as biological treatment activated
carbon, and steam stripping should be
the basis for determining performance ••
standards for solvent-containing
wastewaters containing less than 1%
total organic carbon or less than 1%
F001-F005 solvents.
However, die wide variety of wastes
included within the term "halogenated' .
organic compounds." even as limited
along the lines proposed by EPA in this
notice, and the wid* variation in their
physical properties and waste matrices,
makes it impractical for EPA to develop
wastewater treatment standards •-:•-••• :-
expressed either as concentration levels
or a* treatment technologies at thistime;
EPA will be addressing alTof the waste*
included in today's HOC proposal
(except for the solvent- and dloxin-
containing wastes for which EPA has
already established concentration-based
treatment standards on November 7,
1986) pursuant to the schedule published
in the Federal Register on May 28,1986
(51 FR 19300).
EPA has identified the incineration as
the treatment technology that is BOAT
for all hazardous waste containing
HOCs in concentrations greater than
1000 mg/kg except wastewaters, and is
proposing to promulgate treatment
standards for HOCs expressed as a
specified technology under 40 CFR
268.42. Treatment technologies specified
as a method, however, are only
applicable to those HOCs that are not
covered by other Agency rulemakings
under $ $ 268.41, 268.42, or 268.43. For
example, a waste containing only F001
trichloroethylene (an organic hazardous
waste containing the halogen chlorine)
is already subject to a concentration-
based treatment standard which was
published hi the Federal Register on
November 7,1986 and is to be codified
at 40 CFR 268.41. As discussed in that
final rule, the Agency prefers to
establish concentration-based treatment
standards rather than treatment
standards expressed as specified
technologies because EPA believes that
this approach will provide the regulated
community with greater flexibility in
meeting treatment standards and will •
encourage the development of more
efficient and innovative technologies. In
order to maintain this flexibility. EPA
intends that any treatment standards
established for individual HOCs will
supercede today's proposed standards.
which are expressed as specified
technologies. Therefore, the FOOl
trichloroethylene waste mentioned
above need only be treated in ,
accordance with § 268.41. In other
words, the waste must be treated to the
specified level and the technologies
specified in S 268.42 do not necessarily
have to be utilized in reaching this level:
However, if the waste also contains an
HOC for which no treatment standard is
established, the specified concentration
level for trichloroethylene must be
achieved and the method specified for
the other HOC must be utilized; at least
with respect to that portion of the waste
which i»not FOOl trichloroemylene. This
would allow the separation of the waste
in order to provide flexibility hi meeting:
the trichloroethylene levei However, as
a practical matter, the Agency:* •.;
anticipates that &i most casecwute
managers-wtB treat the entire waste
usingthemethbds spedfied-iB 1268=42.
Since the California list was intended
only as a starting^poinHn prohibiting
land disposal and the group of
California list wastes known as HOCs is
very broad and diverse, die- Agency may
revise die treatment standards
established under section 3004fd) when
it develops further data to support-
treatment standards-for individual
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44726
Federal Register / Vol. 51. No. 238 / Thuraday. December 11. 1986 / Propped Rule.
i*
HOCa In future rulemakinga under
section3004(g).
For hazardous wastes containing
HOC« with a total organic carbon (TOC)
content of greater than 1%, including
liquids organic and inorganic solids and
sludges, and non-liquid HOC-containing
hazardous wastes at greater than or
equal to 1000 mg/kg BDAT is proposed
to be incineration in accordance with
the requirements of 40 CFR 264.343 or
265.343. Because of the wide variety of
chemical compounds that are included
as HOCs (even in the limited universe of
HOCs that the Agency has proposed).
EPA does not believe that it can set
treatment standards for HOC-containinn
wastewaters.
Application of technologies such as
biological treatment, activated carbon
adsorption or steam stripping may be
effective for these materials, but a
generalizatf on.that one or all of them
constitutes BDAT for the wide variety of
chemicals included as HOCs is not
possible. EPA intends to pursue the
applicability of these technologies to
specific wastes in much greater detail in
subsequent rulemakings for the wastes
scheduled to be considered under
section 3004{g). As part of those
regulations, EPA plans to develop
concentration-based treatment
standards and reduce reliance on
treatment standards defined as use of a
specific technology or group of
technologies.
EPA's analysis of available capacity
for treatment of F001-F005 solvent
wastes indicates that virtually all
available incineration capacity and
organic wastewater treatment capacity
will be used up in complying with the
solvent regulations promulgated on
November 7,19S& Based on this
analysis and on the similarity of
treatment required, EPA is proposing a
two-year national variance for HOCs
requiring Incineration. However,
bocauit EPA i* no t able to specify
BDAT for HOC-conUining wastewaten.
the Agency fs notable to propose an.
extension of the effectiv* date, which
must be baaed on an estimate of the
earliest dat* by which treatment'~~ """
capacity capable of-meetfa^tbe
treatmant standard caa.bc raade-
available. EPA requests comment on it*
proposal of incineration as BDAT for jdl-
. HOCa except wastewaters. The Agency
also requests comment and data
relevant to its proposal to extend the
effective dates for these wastes. Finally.
EPA requests comment on its decision
not to propose BDAT for HOC-
containing wastewaters and the related
interpretation that it must not extend the
effective date when it does'not establish
BDAX.
b. Potychlorinated bfphenyls. The
Agency is proposing to establish BDAT
for liquid hazardous wastes containing
greater than or equal to 50 ppm PCBs as
thermal treatment pursuant to the
technical requirements in 40 CFR 781.60
(high efficiency boiler standards) and
§ 761.70 (incinerator standards). Note
that the TSCA regulations require the
incineration of liquid PCB wastes in
concentrations greater than or equal to
500 ppm. Such wastes cannot be treated
in high efficiency boilers. EPA is not
proposing to modify this determination
in today's proposal.
Under the PCB regulations at
§ 761.60(e), any person who is required
to thermally treat PCB wastes may
obtain approval to use alternate
equivalent methods ao long as such
methods do not present an unreasonable
risk of injury to health or the
environment
EPA will also accept such petitions for
equivalent treatment for mixed PCB/
Hazardous wastes. (Note that this is not
the same as the variance from the
treatment standard as described in the
November 7,1986 final rule for solvents
and dioxins). Such petitions should be
submitted to the Administrator, with
copies to the Director, Exposure
Evaluation Division. Office of Toxic
Substances and to the Chief. Waste
Treatment Branch, Office of Solid
Waste.
The Agency recognizes that its
regional offices have developed a
certain degree of expertise in evaluating
alternate treatment methods for PCB
wastes. However, the PCB wastes
subject to today's proposal an mixed
with hazardous wastes and, in many
cases, may contain as little as SO ppm
PCBsandssmuchas200,000-300,OOa(or
20-30%) ppm as hazardous-waste*
regulated under RCRAvSmc* many-of *
these, wastes may not fa* comprised of
predominantly PCBs, tfce Agency
believes that EPA headquarters is better
suited to handle petitions for these
mixed wastes at the present tana.
a Corrosive wastes. BDAT for liquid
hazardous wastes with a, pH less than or
equal to ZO (corrosives} is proposed to-
be neutralization to a pH above two.
When the pH of th&waate-is above 2.0. ~
it wiH no longer be subject to-the;
California list land disposal
prohibitions. Further, it will not be
regulated as hazardous under RCRA
Subtitle C, if it is hazardous solely
because it exhibits the characteristic of
corrosivity. Therefore, BwrJralization-of •-
corrosive wastes to levels above * pH of
2.0 is appropriate for purposes of the
California list prohibitions, and the
Agency proposes to consider such
treatment BDAT for the purposes of the
land disposal restrictions; •
2. Other Applicable Treatment
Technologies
In this section, EPA presents available
data on treatment for those California
list wastes for which the Agency lacks
sufficient data to establish BDAT. The
Agency solicits comment and data that
would support establishing BDAT for
these wastes.
a. Cyanides. While not proposed as
BDAT under today's approach, the
treatment most often used for cyanides
is alkaline chlorination. This treatment
consists of adding chlorine gas, under
alkaline conditions, to convert cyanides
to cyanates. The cyanates can then be
converted to carbon dioxide and
nitrogen by adding sodium hydroxide.
Two alternative treatments are
chlorination by sodium hydroxide and
chlorination by sodium hypochlorite.
Available data indicate that these
treatments can reduce cyanide
concentrations from as much as 12JOOQ
ppm to as low as 5 ppm. However* the
effectiveness of alkaline chlorination
depends on the extent to which other
constituents of the waste are monr
readily oxidized than cyanide. Incases
where mere are competing constituents,
the addition of chlorine in amounts
consistent with normal operating
practice may not result in optimal levels
of cyanide oxidation. The presence of
metals, which will complex cyanides
into metsJIocyanides. may also affect
the performance of cyanide- oxidation.
At this time, the Agency doesnot
have adequate data to define BDAT
either as a concentration-based
standard or as a treatment technology
for th» wide variety of cyanide wastes
included Hi m»CahT0rnia list It abo
should/Denoted that solidification to
crow** liquid cyanide wastes to non-
liquid«y«Bi6Vwastes meets- th*
statutory nxpimueat to exclude wast*
from consideration under today's-
pn»pos*d rule. While this method of
treatment may satisfy the reqtrirenwi's
of this proposed rulemaking. generator-
are cautioned that performance __ -- -
standards that Witt be~esboUsaed under
later rohm*Hngp are likely to be based
on more effective tedmologies such as
alkaline chkorinaikm. _-•.-. .: -• .
mestoftsnaimtie^toiiqaktiiazardoas
wasteseaatemn^&lifonii&hstMtais
is rheairit n si l|iil«Hap. P
, .
chreaftaat ie«<>,"Bick«tanJ *sieiiluin» fit*
most commo»fBagents are sodium, or
calcium hydroxide. When duomhna is
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Fadarai gagjate- / Vrf: 51. No. 23& / Thnrgday. December 11. 1966 / Proposed Rofe. 44&F
present as.hexavalent«bzoadum (Cr VI},
it is first reduced to; trivalent chromium
(Cr 10} by using sulfur dioxida at low pH
levels. Arsenic, mercury and thallium
generally require the use of sulfide to
effect precipitation. Frequently, these
wastes are treated by filtration to
remove fine particles that did not settle
out in the clarifier. The precipitated
material is often dewatered and/or
stabilized with lime, kiln dust, portland
cement or other materials after removal
from the clarifier ot the filter in order to
further reduce the mobility of the waste.
Given the variety of wastes that may
be covered by this category, and the
lack of adequate data on the
performance of stabilized materials, the
Agency does not believe that it is in a
position to specify BDAT at this time.
While it is known that precipitation is
frequently used as treatment for these
types of wastes, EPA's analysis of the
available stabilization data indicate that
waste matrix effects can play a
substantial role in the type and quantity
of stabilizing agents needed. In
particular, the overall organic content
and the presence of oils and chlorinated
solvents win influence the effectiveness
of moat stabilization processes.
EPA does not have adequate data to
characterize all waste streams that the
California list metals restrictions may
cover at this time, and because of the
role that composition of the waste
stream play* in the effectiveness of the
treatment EPA cannot at this time
establish BDAT either as a
concentration-based standard or as a
treatment technology or series of
technologies. Unlike the case for
incineration of HOC*, "normal**
operation of the system may not result
in substantial treatment
H. Comparative Risk and Available
Treatment Alternative*
As EPA recognized in establishing*
framework for implaMnting.the
statutorily mandated land disposal;
restrictions. Congress did not intend that
risks to human health-aoctthe-
environment beiacroaae&a* * result:of
such restrictions. Tc4«hjiptav«nt these -
increased-risksv die Agency conducted
comparative risk asaeaameatft forth*
first category of waste* subject to the
land disposal restriction*. i.Ci certain
dioxin-containing and solvent-
containing hazardous- wastes. (See the
solvent* and dioxins final rule of
November 7,1988 51FR 48572. which
establishes the framework for
implementing the land disposal
restrictions).
The Agency is conducting
comparative risk assessments in
conjunction with establishing section
3004(nt} treatment standards for several
of the California list waste*. The
methodology being employed is similar
but not identical to that utilized in the
November 7,1986 solvents and dioxins
final rule. The RCRA Risk-Cost Analysis
(WET) Model continues fo be the
primary tool for assessing comparative
risks; however, the WET Model has
been revised on the basis of detailed
case studies performed for the
November 7,1986 final rule and public
comments responding to the Agency's
approach in mat rulemaking.
Results of the comparative risk
analysis will not be used to allow
continued land disposal of hazardous
waste. Instead, treatment technologies
that are determined to pose greater risks
than land disposal of untreated wastes
will be considered "unavailable" as a
basis for establishing the section
3004(m] BDAT treatment standard for
the waste. If the best or most efficient
treatment technology for a waste is
determined to be riskier than land
disposal, the decision to classify it as
unavailable will have a direct impact on
the level or method established as the
section 3004(m) treatment standard. The
treatment standard, which must be
based on the capabilities of the beat
demonstrated available treatment
technologies for a waste, would then be
based upon the capabilities of the best
demonstrated treatment technology mat
does not pose greater risks than land
disposal To the extent that the next
best treatment technology performs less
efficiently than the best technology (in
terms of the fate of its residual* in the
environment}, the resulting section
3004(m} treatment standard wffl be less-
stringent
As noted in the November 7,1986 final
rule, Ueatment technologie* classified a*
"unavailable" doe to their greater risk*
may, however, continue to be ased by
waste managers to comply with
treatment standard* expressed ar
constituent concentrations* According.
EPA intends to develop svfficiem
regulatory control* or prohibftkms over
the design and operation-of these
technologie* to ensure that theirnsein
complying with concentration-based
treatment standard* doe* not revolt in
increased risks to Banian beahb and tn»
environment The analyses coadactedto
support of these comparative risk
assessments wiB provide • basis for
developing suck controls or prohibition*
however they wiB most likely need to be
augmented by additional data. Where,
as in today's proposed rule, the section -
3004(m} treatment standards are
expressed as specific methods which
must be utilized, a determination-to-
classify a treatment alternative as
unavailable will prohibit tfee nwrof that
technology; far complying wift the BDAT
standards applicable to the restricted
wastes in question.
Preliminary results indicate that the
best demonstrated treatment method*
for PCS* and other HOCs are not dearly
riskier than land disposal Whenever
treatment is less risky or it is uncertain
that a given treatment technology or
treatment train is clearly riskier than
land disposal, as in today's proposed
rule concerning California list wastes.
the Agency will consider the treatment
available for determining BDAT and wtB
develop the necessary data to snpyurt -
any additional regulatory controls which
may be appropriates.
A comparative risk assessment for the
corrosive wastes subject to today's
proposal was not performed because the
Agency'* establishment of a BDAT
standard at the statutory threshold dees
not impose any new requirements1 for
treatment In both cases, hi order to be
rendered non-hazardous, liquid
hazardous wastes having a pH less than
or equal to two (2.0) must be treated to a
level above 2.0 before being land-
disposed. Therefore, EPA believe* that a
comparative risk assessment for '
corrosives is not necessary for tHr
California Hat restrictions; However, the
Agency is requesting comments and
data on whether neutralization is riskier
than land disposal of corrosive wastes.
/. Dilution Prohibition
In establishing a framework for
implementing the eongressionally
mandated land disposal prohibition*,
EPA proMbiteda* a dHntion substitute
for adequate treatment of restricted -
waste* (51 FR 40572, November 7, 1986}.
In the November 7, 1966 Federal Register
notice, the Agency promulgated a final
rule (to be codified at 4OCFR 268.3V
which prohibits the regulated
community from dSnting restricted
waste* "as * substitute for adequate
treatment to achieve compliance with
SubpartUof tfifepart"
Snbpart D ef«T CFR Ftet 2B8I
estabttshw treatment stHndard»for
restricted: westra>pnrs8snfctDElGCRA.
section 3604(m}: Subpatt C identifies
those wastes- that are prehibHiHiC
land dspoaeJ
with the respective effective e%ter of '
such prohibition*. Since me dimtfoff
proBiDition pronMugsteu orrrvovenioer*7^ *
1988 is only appfieabfe to waste* treated
"to achieve mmpifauut wHfr9nbpart •
TT, the ptohibitiOTdee* not apply to
concentration feBtt* established under-
section 3604fd%The Agency beBevw
that this is contrary to-congressional
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Federal Register / Vol. 51, No. 238 / Thursday, December 11. 1986 / Propoaed Rules
intent as expressed in H. R. Rep. No.
198. Part 1,88th Cong., 1st Sesa. 34-35
(1983), which states that;
The (Energy and Commerce] Committee
Intends that dilution to a concentration less
than the specified [California List] thresholds
by the addition of other hazardous waste or
any other material during waste handling.
transportation, treatment, or storage, other
than dilution which occurs as a normal part
of a manufacturing process, will not be
allowed; such hazardous waste would still be
prohibited from land disposal.
Therefore, EPA is today proposing to
amend the § 288.3 dilution prohibition to
include dilution to avoid a prohibition in
Subpart C of Part 288 (e.g., dilution to
below the restrictions levels for the
California list wastes). In addition,
section 288.3 as amended covers those
situations where wastes are diluted in
order to circumvent the effective date of
a Subpart C prohibition on land
disposal. Capacity determinations are
based on estimates of quantities of
waste at the point of generation.
Allowing dilution to a lower
concentration in order to qualify for a
nationwide variance undermines this
determination. As stated in the
preamble to the November 7,1988 final
rule, section 288.3 is intended to prohibit
dilution as a means of circumventing the
requirements imposed by the land
disposal prohibitions. EPA does not
intend to prohibit dilution which is
necessary to facilitate proper treatment.
/. Evaporation Prohibition
The Agengy is soliciting comment on
the issue of whether evaporation should
be prohibited as a means of treatment
under the 40 CFR 288.4 treatment in
surface impoundment exemption. The
Agency is considering this action
because of its particular concern that •
the hazardous constituents in wastes be
treated to reduce toxicity or mobility,
and not Just moved from one media to
another. This prohibition is not intended
to cover evaporation that occurs along
with other treatment, such as an active
biological treatment process with. <
mechanical aeration. Where the"'5
restricted liquid hazardous waste .
contains volatile or semi-volatile
constituents, evaporation, whether as a
dewatering process or a constituent
reduction process, would result in the
volatile components being transferred to
the air. This may increase the mobility
of the toxic constituent and may
increase the associated risk. ' -
The Agency is requesting comment on
the risks posed by treatment processes
that simply transfer hazardous
constituents from one environmental
component to another.
K. Facilities Operating Under a Permit
or Interim Status
The Agency is proposing to amend
Part 270 to give facilities more flexibility
to handle restricted wastes. First, the
Agency is proposing to add a new
paragraph (p) to § 270.42 to allow
permitted facilities to use the minor
modification process, under certain
conditions, to obtain approval to change
their facilities to treat or store restricted
wastes in tanks or containers as
necessary to comply with Part 268 land
disposal restrictiona. Second, EPA is
proposing to amend § 270.72(e) to allow
interim status facilities to expand their
operations by more than 50 percent (in
terms of capital expeditures) to treat or
store restricted waste in tanks or
containers as necessary to comply with
Part 268 land disposal restrictions.
These changes are in addition to the
amendment to 5 270.42, promulgated in
the November 7,1988 final rule
establishing land disposal restrictions
for solvents and dioxin-containing
wastes, that allows permitted treatment
facilities to use the minor modification
process, under certain conditions, to
manage restricted wastes not previously
listed hi their permits.
1. Minor Modifications
Under the current rules, permitted
facilities desiring to change their
operations to treat or store restricted
wastes in tanks or containers are
required to seek approval to make these
changes through the major permit
modification process of $ 270.41 with the
exception of facilities treating new
wastes in accordance with 9 270.42(o).
(See 5140752, November 7,1986.) The
major modification procedures, which
are the same as the permit issuance
procedures, require & draft pennit
public notice and comment an
opportunity for a public hearing, and
administrative approval before the
owner or operator is allowed to make
the requested changes. These
procedures are time consuming and
could seriously delay treatment of
restricted wastes in accordance with
Part 268. In addition, the major permit
modification process may seriously
inhibit the ability of facilities to add
short-term storage capacity to handle
restricted wastes as treatment proceeds.
In contrast under fi 270.42, minor
modifications to a pennit can be made
by the permitting authority upon consent
of the permittee without formal notice
and comment procedures. The Agency
believes that the major modification
process may seriously reduce the
flexibility .needed by facilities to
respond to the land disposal restrictions
in a timely fashion. Given the critical
need to expand treatment capacity for
restricted wastes and the significant
environmental benefits that result from
treatment instead of land disposal EPA
believes that expanding the current
minor modification provisions to
provide greater flexibility for the
treatment or storage of restricted wastes
is necessary and appropriate.
The Agency is proposing that owners
or operators seeking to use the proposed
minor modification process of
§ 270.42(p) comply with three
conditions. First the owner or operator
must submit a complete major permit
modification application pursuant to
S§ 124.5 and 270.41. Second; the
applicant must demonstrate that
changes in a unit to treat or store
restricted wastes hi tanks or containers
is necessary to comply with the hind
disposal restrictions of Part 268. Third,
the applicant must ensure that such unit
complies with the applicable Part 264
standards pending final administrative
disposition of the major permit
modification request For example, any
tanks used to treat or store restricted-
wastes would be subject to the tank
system standards of Part 284, Subpart J,
which include secondary-containment -
requirements (see 51FR 25422, July 14,
1986). The authorization to continue in
operation with the changes terminates
upon final administrative disposition of
the major modification request or the
termination of a pennit
In proposing this amendment to
S 270.42, the Agency recognizes that the
Part 124 public participation
requirements will be deferred until a
permittee's major modification request
is processed. However, EPA believes
that this approach represents a
reasonable balance between its policy
in favor of public participation and the
need to provide facilities mating^
restricted wastes with the flexibility to
respond to this land disposal restrictions
in a timely and effective manner.
The proposed change to the minor
modifications requirements does not
apply to storage or treatment other than
in containers or tahksTEPA beHeVes that
the addition of other treatment
processes, such as incineration, is likely
to raise issues that would be best
addressed through the major
modification process. However, the'
Agency is exploring these issues as part
of an overall review of the permit ;
modification regulations. The EPA is
now conducting regulatory negotiations
on pennit modifications? (announced on
July 16,1986 hi the Federal Register (51
FR 25739)) and expects to issue a
proposed rule during the next year. The
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Federal Register / Vol. 51. No. 238 / Thursday, December 11, 1988 / Proposed Rate*
44723
Permit Modification Negotiating
Committee wffllre invited to submit
comments on today's proposed rule.
Furthermore; the language in today's
proposal is hot intended to limit the
Permit Modification Negotiating
Committee's independent consideration
of changes in the overall permit
modification process. Rather, the
Agency has proposed to amend § 270.42
at this time because of the need to
ensure that the provisions are in place
when land disposal restrictions on the
California list wastes become effective.
If adopted, these permit modification
provisions would be used until the
permit modification process is further
amended.
2. Reconstruction Limits
The Agency is also proposing to allow
interim status facilities to modify their
operations to treat or store restricted
wastes in tanks or containers as
necessary to comply with the land
disposal restrictions of Part 268, without
being required to obtain a permit even if
such facility modifications amount to
"reconstruction." Under existing 40 CFR
270.72(e). EPA prohibits any
modifications to an interim status
facility that amount to the
reconstruction of the facility. For the
purposes of this prohibition, EPA
considers reconstruction to occur when
the capital value of the changes to the
facility exceeds fifty percent of the
capital costs of a comparable new
hazardous waste management facility.
EPA believes that the current
regulations generally provide
. reasonable flexibility to interim status
facilities to comply with the land
disposal restrictions. Under certain
circumstances, however,'an owner or
operator of an interim status facility that
manages restricted wastes may need to
expand the facility by more than SO
percent (in terms of cost) to comply with
the Part 268 land disposal restrictions. In
these circumstances under the existing
regulations, the owner or operator
would have to delay the change* or
discontinue operations until the changes
could be approved in connection-with
the issuance of a permit EPA believes
that in light of the Knitted availability of
hazardous waste treatment faculties, the
time-consuming process necessary for
permitting, and the clear evidence of
congressional intent to allow interim
status facilities to make the specific '
changes necessary to comply With new
regulatory requirements, this result
would be unacceptable.
To address this problem, F^A is
proposing to amend § 27O.72ie} to allow
owners or operators to modify interim
status facilities to handle wastes
restricted from land disposal necessary
to comply with Part 288 without being
subject to the fifty percent capital
expenditure limitjn 1270J2(eJ. Under
the proposed regulation, interim status
facilities would be required to file a
revised Part A application prior to such
changes. The applicant would have to
demonstrate that the changes were
necessary to comply with the hind
disposal restrictions of Part 268. In
addition, the only allowable changes
would be for treatment or storage in
containers or tanks. EPA believes that
the addition of other processes that
amount to reconstruction, such as
incineration, is likely to raise issues that
would be addressed best through the
permitting process.
Facilities allowed to expand their
operations by more than 50 percent (in
terms of cost) under the proposed
change would be subject to Part 265
standards. For example, any tanks used
to treat restricted wastes would be
subject to the tank system standards of
Part 265. Subpart J. which include
secondary containment requirements (51
FR 25422. July 14,1988).
L. Procedures for Obtaining a Variance
From Treatment Standards
As a result of comments on the
Agency's proposed BDAT standards, the
Agency has provided a procedure to
allow interested parties to obtain a
variance from the treatment standards.
See 40 CFR 268.44, 51 FR 40572
[November 7,1986). This procedure may
be used by those whose wastes cannot
be treated to meet the treatment
standard issued by EPA. Essentially, the
Agency will establish a separate
treatment standard for, a waste if the
interested party presents data which, if
properly considered by the Agency at
the time the standards were .
promulgated, would have required that a
separate subcategory be created for.the
waste. The procedure allows the Agency
to fine-tune the regulations by
considering the full range of current
practices to which the treatment
standards should apply.
Section 288.44 establishes a variance
procedure in the form of a ruleinaking
that amends the regulatory treatment
standards each time a variance is
granted. The preamble to that rule lists a
number of factors that the Agency
believes will be relevant to the variance
application. However, as noted in the
preamble to the final rule, the Agency
believes that the statute does not
preclude establishing a more '
streamlined variance procedure. The
Agency has construed the statute to
allow the setting of treatment standards
applicable to specific treatabjlity groups;
the same result could be achieved by
issuing a variance in a case where EPA
did not have sufficient data to establish
treatability groups at the time of the
final rule.
EPA received comments both for and
against providing a more streamlined
petition procedure but did not have
enough time before die final rule was
issued to consider these comments
carefully. EPA therefore requests further
comments on the advisability of
modifying the current procedure.
Specifically, are there disadvantages
that would outweigh the benefits of a
simplified procedures? Should the
Agency allow any interested party to
apply? Should the procedure allow the
Agency to adjust the treatment
standards to be more stringent as well
as less stringent? Should the Agency
establish a deadline for applications,
e.g., 3 or 6 months, after, the effective
date of the treatment standards that
apply to the waste?. What public notice
procedures should apply? Are the
factors cited in the preamble to the final
rule published on November7r 1986; the
appropriate factors for the Agency to
consider? EPA also solicits comments on
any other relevant aspect of the
treatability variance procedure.
V. Alternative Capacity and Ban
Effective Date
RCRA section 3004(h)(2) states that
the Agency may grant a nationwide
variance of up to 2 years from the
statutory effective date if adequate
alternative treatment recovery, or
disposal capacity which protects human
health and the environment is not
available. Congress, however, intends
for the land disposal restrictions to "go
into effect immediately upon
promulgation whenever and wherever
possible." (S. Repi No. 284; 98th Cong.,
1st Sess. 19 (1963?.) The legislative
history also states that "[t]he Agency
should expend every effort to assure
that unsafe practices are terminated as
quickly as possible." Therefore,
"[ejxtensions based on capacity.
shortfalls should be infrequently
granted. Given consistent regulatory and
economic incentives, .adequate capacity
will be quickly developed* (S. Rep. No.
284,98th Cong,. 1st Sess. 19 (1983}.) EPA
will .consider several factors when:
calculating alternative capacity and
when determining the length of any
variance from the effective dates
mandated by RCRA^These factors,
which were alscuised for determination
of alternative capacity for the solvent*
and dioxuis rule, are-discussed below* -.
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'44730 ' Federal Register / Vol. 51, No. 238 / Thursday. December 11, 1986 / Proposed Rules
1
A. Agency-Authority With Respect to
Effective Dates
EPA will develop estimates of
treatment capacity needed versus
capacity available to determine if
current capacity for alternative
treatment, recovery, and disposal
technologies is adequate to manage
restricted wastes. These estimates will
be developed from currently available
data on capacity requirements and
technology capacity. '
If capacity is available, the
restrictions will go into effect ,
immediately. If capacity is not available.
RCRA section 3004(h](2) requires that
the effective date of the restrictions
shall be established on the basis of the
earliest date on which adequate
alternative treatment, recovery, or
disposal capacity which protects human
health and the environment becomes
available. Establishment of the ban
effective date will not be affected by the
processing of petitions under RCRA
section 3004 (d). (e), and (g). The
interaction between the variance to the
effective date and the case-by-case
extension under section 3004(h)(3) la
discussed later in this unit
B. Regional and National Capacity
The Agency will determine both the
quantity of retricted waste generated
and the capacity of alternative
treatment, recovery, and disposal
technologies on a nationwide basis. If
there is a significant shortfall in
capacity to treat all of the restricted
waste, the Agency will extend the
effective date of the restrictions. If
national capacity is sufficient, the
restrictions will become effective
immediately. If national capacity is only
slightly lacking. EPA may grant case-by-
case effective date extensions while
allowing the nationwide restrictions to
go into effect immediately.,
C. The Nationwide Variance and the-
Case-by-Case Extension • ' •
In case's where EPA has not grantsdra
nationwide variance,-it i*,Bot precluded
from granting caae-by-CMe"e5ective
date extensions. For instance, if
alternative capacity exists to manage
moit of the restricted wastes, but
appears tb be slightly inadequate, the
Agency might choose not to grant a
nationwide variance. In these cases, it is
more desirable to grant case-by-case
extensions to specific applicants who
lack alternative capacity than to allow
everyone, even those for whom1 .
alternatives are available, to continue to
land disposa of their wastes. This- - • •
approach is consistent with
congressional intent to restrict land
disposal at the earliest possible time.
For the same reasons, EPA may grant
a variance of less than 2 years, even
though some facilities may require more
time to be completed. These facilities
could be completed under a case-by-
case extension, if all applicable criteria
are met without allowing continued
land disposal nationwide.
D. Determination of Capacity
Requirements by Waste-Treatability.
Group
In general, EPA will develop
' treatment technologies for waste groups
derived from the physical/chemical
characteristics of the banned wastes.
Where possible, EPA will also
determine the quantified of wastes that
require specific treatment or recovery
methods by waste treatability group.
These treatability groups will enable
EPA to compare required capacity
(capacity demand) with available
capacity (capacity supply). The
quantities of wastes land disposed'will
be grouped according to the description
of their characteristics. In addition, EPA
will consider other increases in capacity
demand generated by emergency and
remedial responses. EPA also will
include, to the extent possible, the
impact of other final rulemakings such
as the regulation of small quantity
generators, that have occurred since
EPA's capacity data were collected.
E. Definition of Available Capacity.
In estimating available capacity, the
Agency will consider (1) current on-line
facilities, which include permitted
facilities and facilities operating under
RCRA interim status and (2) planned
faculties and capacity extensions that
will be on-line by the time the ban goes
into effect
• Current on-line facilities consist of off-
site and on-site fadlitieii, as well as
stationary and mobile facilities. They
are facilities that have been approved to
. operate and accept pertinent wastes.
under current regulations by applicable
Federal, State, and local agencies. • ',
Facilities operating under RCRA interim
status meet these criteria, and therefore
will be included in the capacity
determmation. " . '
F, Definition of Alternative Treatment
Capacity , ._
RCRA section 3004(h)(2) states that a
variance from the effective date of a
land dispooalrestriction "shall be •
established on the basis of the .earliest
• date on which adequate alternative
treatment recovery, or disposal •
capacity which protects human health
and the environment will be available."
In general, all treatment technologies *
that are capable of meeting the-
treatment standards established.under
3004(m), are considered to be available '
treatment capacity under the above
standard.
Section 3004(m) directs EPA to
establish standards based on treatment
that will minimize long- and short-term
threats to human health and the • .
environment The Agency believes that
this "minimize" standard generally will
be met by technologies classified as .
BOAT (best demonstrated achievable
technology). •'
In most cases, treatment levels or
methods based on BDAT are expected
to fully protect human health and the
environment Accordingly, technologies
that form the basis for such standards
are candidates for the capacity
evaluation, undertaken pursuant to
3004(h) (2) and (3).
G. Definition of Alternative Recovery .
and Disposal Capacity .
In assessing available capacity, the
Agency will consider the capacity of all
on-line recovery and disposal facilities
"that are more protective than existing
land disposal methods" (see 51FR '**
40599). Planned facilities, including*
expansion of existing faculties, also will
be considered where appropriate. On-
line facilities are defined as those.
facilities that have received approval
from applicable Federal, State, and local
agencies to operate a recovery or
disposal facility for the waste in
question or for a similar waste.
However, alternative land disposal
methods te.g., deep well Injection) will
not be considered as available capacity
for restricted wastes unless EPA has
determined that such methods of ::;
disposal 'are fully protective of human
health and the environment f0r the :
waste in question. This question will
arise frequently in the context of "'
assessing underground injection as . •
alternative capacity. RCRA section
30Q4(f) allows the Agency until August
1968 to study the disposal by deep well
injection of solvents, dioxms, ana
California List wastes and tb promulgate
any necessary regulations banning these
wastes from deep weQ injection. This
deadline occurs after the mandated'
deadlines for ban decisions concerning
disposal of these wastes by other land
disposal methods. For wastes scheduled
for later banning, the Agency will make
decisions to ban from deep Well
injection concurrently with decisions, to
ban from other land disposal methods.
Accordingly; in evaluating the capacity
of alternative protective disposal •
methods for these wastes prior to a •
-------
/ Vol. 51. No. 238 / Thursday, December 11. 1986 / Proposed Rules
decision under section 3004(0, EPA will
not consider underground .injection to be
available disposal capacity, since the
Agency will not have determined
whether .the injection of such wastes is
fully protective of human health and the
environment.
fi. Estimation of Capacity
EPA will estimate the annual unused
or surplus capacity of alternative
treatment recovery, and disposal
facilities that are available nationwide
to manage wastes restricted from land
disposal. This nationwide capacity
(capacity supply) will then be compared
with quantities of banned waste
generated annually nationwide
(capacity demand).
Surplus capacity will be expressed as
the throughput capacity, the volume of
waste that can be treated per year.
Since data on actual unused throughput
may be difficult to obtain in some
instances, EPA may need to use other
available information to calculate this
value, such as the difference between a
practical maximum design capacity and
the capacity currently utilized, to
calculate capacity. In turn, practical
maximum design capacity represents the
theoretical maximum design capacity,
minus an estimate of die amount of
potential operating time lost to normal
maintenance.
Frequently, treatment and recovery
technologies consist of a series of unit
processes. In these cases, treatment
system capacity will be based on the
capacity of the unit operation within
that system that is most likely to limit
the capacity of the whole system, if any.
This would occur, for example,, if a large
metals precipitation system contained a
much smaller capacity .for ntimmhim
reduction. In this case, the capacity for
trivalent chromium precipitation (which
does not require reduction) would be
much greater than foe hexavalent
chromium precipitation that would
require reduction. . . ,\ .". .
For this proposal capacity estimates
are based on currently-available
information, primarily the 1981OSW .
RIA Mail Survey. Tluu&gency is
currently working on a new survey of.
commercial and.priy.ate treatment
facilities and will use the results of this
survey when they become available to
calculate capacity, for future <
rulemakings..
1. Current Surplus Capacity
Current surplus capacity is defined as
present capacity that is not being;
utilized. Surplus capacity can be any of
the following: , .: -.-....,...
(a) Commercially, available.
(b) Private capacity, which.can be
used to process additional wastes . ,
produced by the owner.
(c) Private, where the owner will be
willing and able to accept wastes from
other generators, i.e^ to provide
commercial services.. . :
EPA will assume that commercial
facilities are willing to. accept wastes
that they are capable of treating. In
cases where commercial capacity is
inadequate, EPA will consider the
likelihood that available private
capacity not needed to process
additional waste produced by the owner
will be converted to commercial
capacity. Due to limited information on
the availability of private capacity, EPA
has only considered commercial
capacity for this proposal The Agency
solicits comment on the assumptions
used in this analysis (i.e., willingness of
commercial faculties to treat California.
list wastes), and also asks for comment
and data on private capacity; Data
received during the comment period will
be included in the final rule.
2. Planned Capacity
EPA's general methodology calls for
EPA to use, if possible, planned capacity
estimates in determining available
capacity. If EPA finds that current
capacity is insufficient for a particular
waste, it evaluates the potential for the
development of planned facilities and -
capacity by the statutory ban effective
date. If a national variance is granted.
planned capacity is considered in
determining the length of a variance.
Planned facilities and capacity will be
considered available only if EPA •
determines that, by the time the .ban
goes into effect, the facility will be on-
line. However, EPA has not included.
planned capacity for this proposal due
to lack of data. EPA is developing new.,
data on planned capacity. Because these
data are not expected to be available in
time for promulgation of this nde, the
Agency solicits comment on planned .
capacity not considered in this proposal
/. Time to Develop Capacity and Length
of Variance
According to RCRA section 3004(h)(2),
if the Agency determines that sufficient
capacity currently exists, or if the .
necessary additional capacity can be
developed by the time of the mandated
ban date for each waste, the ban will go
into effect on that date. If not, a :
variance of up to 2 years may be granted
at the same time that the final rule is
promulgated. The length of. the variance
will depend oft the time required to
provide alternative capacity that meets
the criteria described above. EPA's ;
analysis of tune .to provide capacity ; .
indicates that treatment requiring a
permit will require at least two years to
develop. Treatment not requiring a, .
permit (such as treatment in'gb-iday
accumulation tanks) can be provided in
as quickly as 6 months, depending on
the complexity of .the facilities to be
constructed.
/. Wastes for Which Treatment
Standards Have Not Been Established-
Where EPA does not have sufficient
information to establish treatment
standards for a waste, the prohibition on
land disposal for that waste will :
generally be immediately effective. EPA
believes that, considering the. criteria
described below, the Agency .will
generally not be able to establish a .
nationwide variance .for such wastes. As
noted above, the purpose of the variance
is to allow time for alternative .• •
protective capacity to develop. If. the
Agency cannot determine what specific
type of treatment is needed for a waste
(as is the case for metals .and cyanides
in this proposal), it will not be able to
define the capacity needs for-that waste.
For this proposed ndemaking, EPA has
been able to calculate alternative
capacity for wastes containing HOCs,
PCBs, and corrosives because it has
been able to specify a technology as
BOAT. However, it has not made BOAT
determination for cyanides and metals.
Therefore, it cannot estimate the
capacity needed or available to treat
these wastes. •••
However, EPA has included hi the
preamble and in the docket information
on the capacity of various treatment
technologies that may be used to treat
metals and cyanides to below the
threshold concentrations triggering the
applicability of today's rule. Our review
of these data suggests that BOAT, when
developed, may be significantly, more .
stringent than these threshold
concentrations. In the interim, however.
generators will be able to utilize the
capacity of all of these alternative
treatment, technologies in cor"?!yip5
with the standards. If EPA receivea"or
develops, sufficient Information to,.
establish BOAT for these wastes, the .
information in the .docket on the specific
technologies meeti^ the definition or..:,
performance identified as BOAT will be
used to determine whether a variance is
needed. The Agency invites comment on
its analysis of the statutory. •,• .
requirements andean its capacity
information. This unit describes EPAs
estimates of the^mused capacity that is.
currently available to treat'banned •
wastes by these-methods. :
-------
44732
Fetkrai Megfrfrr / Vol. si. No. 2» / Thnndiy. December 11. 1966 / Proposed tales
1. Incineration Capacity
The Agency has already determined
for the purpose of the solvents
nilemaking November 7. 1988(51 FR
40572) that inadequate capacity exists to
incinerate the solvent-bearing wastes.
Since this same incineration capacity
must be used to dispose of HOC- and
PCB-contaiiiing hazardous wastes it
follows that there is no capacity
available for these wastes at this time.
2. Capacity for Other Treatment
Although the Agency is not proposing
BOAT for cyanides and the metals, the
treatment methods that the Agency
believes are applicable are rhtM^Sr^l
precipitation, chromium reduction and
cyanide oxidation. All of these
treatment methods are referred to as
tank treatment under the RCRA TSDF
regulation.
The OSW RIA mail survey is
currently EPA's only source of
information concerning the unused '
capacity for these treatment methods.
The survey provides information on tank
treatment capacity at both commercial
and private facilities, although the data
at wastewater treatment facilities
exempted from RCRA requirements are
somewhat limited. As discussed above,
EPA will consider only commercial
wastewater treatment capacity in mis
proposed rulemaking. For each facility,
the survey provided information on ,
each tank used for treatment types of
wastes managed in tanks, and total tank
treatment capacity for the facility. Using
this information, EPA estimated this
capacity for the specific types, of tank
treatment The estimated available
capacities for tank treatment are:
(1) Chemical precipitation— 165X10*
gaL
(2) Chromium reduction— 35X10* gaL
(3) Cyanide oxidation— 65X10*
Thus; the total capacity available to
treat the metal and cyanide
^
hazardous wastes restrictedfromland
disposal under section 3084(dl in
commercial treatmentfatiliBe* if ____
approximately 285 miffiongaironsJ ~
Although it has no- specie data to
substantiate its position, me Agency •
believes that ttra relative case of
constructing new SOnlay aroummatioir
facilities that may simultaneously
provide neutralization solidification
capacity (or utilization of the- extensive
capacity in existfcytmitB)- argues that
there will be much mote than- 265 nriffibn
gallons of capacity available by July at-
1967. We believe that with, the notice
provided today, generators' will be abfe
to develop the- relatively simple
treatment facilities- needed to meet the
threshold concentrations that establish
applicability of titis date to waste*
containing metals, cyanides, orpH lew.
than 2. In fact we believe extensive use
of solidification already is occurring to
meet EPA's regulations limiting the
disposal of liquids in landfills. As a
result we believe this regulation only
may reinforce the nee'd for facilities to
continue to use existing solidification
capacity. EPA solicits comment on these
judgments and'data on the capacity to
treat these wastes.
K. Alternative Treatment Capacity
Required for California List Wastes'
1. Quantities of Wastes Land Disposed
EPA has estimated the total quantities
of California list wastes which are land
disposed annually, based primarily on
data provided La the OSW RIA Mail
Survey of Treatment Storage, and
Disposal Faculties regulated in 1981
[Ref. 12). Complete analysis of the data
is provided in the background document
to support today's proposed rule (Ref. 1J.
These estimates required four
conservative assumptions because of
the limited characteristics provided by
the survey. First EPA assumed all:
waste* identified in the 1981 survey
containing metals or cyanides described
as liquids or sludges were liquids using
the paint filter test Only those cyanide
and metal wastes described specfficalljr
as solids were assumed to not be
classified as- liquids by mis test and
exemption from mis proposed
regulation. EPA believes that many of
wastes that are described as sludges by
generators contain free liquids and are
actually liquids Daccd on EPA'* test
definition. • • ' .-..•••••••
Second, in order to estimate die-
quantity of corrosive- wastes that were
acidic rather than basic, EPA also-
assumed that all corrosive wastes mat
were not specifically described as basic
were acidic with a pH of less- than or
equal to 2 and subject to this rule. Third,
EPA assumed that all mefal* wastes-
identified as nrmtaiujjig chromium
contain chromium in the hexavaleot
oxidation state and are subject to
regulation,
Finally, EPA has assumed mat to*
concentrations- of constituents of alt
wastes identified by waste codes
associated with the California list
constituents are in excess of die
threshold levels set by any of the
option* in today's proposed rule.
Therefore, die entire universe of these
California list waste* would be
considered subject to die proposed
restrictions.
The following table indicates, me
distribution of die total quantities of
waste* diat were estimated to be , .
corrosive waste* (pH <2) or to conlaift
total cyanides, hatogenated organic;
Cr, Pb, Mi, Hg, Se, Tl). The quantitjnof
liqiriii motnl waahm rjintnining •
hexavalent chromium (Cr+6) is
presented separately because of die
frequent requirement for treatment
separate from other metals to reduce it
to bivalent chromium to facilitate
precipitation as a hydroxide. Figures in
the following table do not include the •
quantities of those California list wastes
that are deep wettinjected. ••••••
SUrtKaknpoundMM
Ota
Lmdipplc
•ToM tad dhpoMd..
318 .
'•at
TO*
tot*
'MSt
. SIS
22.1
tw
SlJt
ISA
t,OBf»
8f»
HOC
SZ3
The total quantity of wastes-. . . .
rnntnining HflfTa in thi« (MKmaf»
include* both, solid or liquid wastes,
consistent with thastatanry, '•,.",
requiramants for HOCs.Howavajv thia-
quantity, doe* not include- those waste*
containing hriogcnated wasteaolvealm
or dioxin* dut have already beea
addressed previously in a> final .
regulation specific to those-wastea. It
also does not include mixed RCRA/PCB
wastes.' E^An
estimated^
million gallon* o£ mix*
t?&
\tK&
waste* that are both liquid and that,
exceed SO.ppm. are landdisposed per
year.. ,-•:••
F4Ktt*ta**?IB*tC8IXmtly •
wast
generators and generated ftom reinedtet
or removal action* anticipated to>b«
-------
Federal Register / VoL 51, No. 238 / Thursday, December 11, 1988 / Proposed Rules 4473&
taken under CERCLA or RCRA
corrective action, these have not been
included in the total quantity estimates.
However, EPA does not anticipate that
significantly large quantities result from
any of these sources. Small quantity
generators produce less than 1% of all
wastes generated and were responsible
for less than 1% of the waste solvents
EPA considered in the previous
rulemaking. CERCLA responses and
RCRA corrective actions generally
produce wastes that contain less than
the statutory concentrations of waste
constituent, but can include acid wastes.
EPA will attempt to develop estimates
for all these wastes prior to
promulgation of today's proposed rule.
2. Quantities Requiring Alternative
Capacity
In order to estimate the alternative
treatment capacity required to address
the volumes of California list wastes
given in the previous section and to
determine the effective date for the land
disposal restrictions, these wastes must
be assigned to potential alternative
treatment methods. The technologies
identified in this section are those which
EPA believes will generally be used to
treat these California list wastes.
EPA believes that neutralization
generally will be used for acidic liquid
wastes. EPA does not believe that
capacity will be an issue for waste
solely requiring neutralization. Such
neutralization can be done rapidly in
tanks or even in pipes. However, EPA's
limited waste characterization data
suggest that the majority of the acidic
corrosive wastes also contain significant
concentrations of metals that will need
treatment to meet the constituent
concentrations established by any the
options on today's proposed rule.
Therefore, EPA is assuming that all
acidic wastes also will require chemical
precipitation or solidification. This is a
conservative assumption because some
acidic wastes will require only
neutralization. To the extent that
neutralization could.be used for these
wastes, EPA recognizes thaFifhas
overestimated the capacity requirements
for chemical precipitation or
solidification.
EPA also believes that all liquid
wastes identified as metal wastes
(containing As, Cd, Cr, Pb, Ni, Hg. Se.
Tl) will require chemical precipitation,
and wastes that contain hexavalent
chromium (Cr+6) will require additional
chemical reduction. For the purpose of
estimating capacity needt ZPAhas
assumed wastes containing cyanide will
require chemical oxidation of the
cyanide. Alternatively, solidification to
meet the paint filter test definition of
non-liquid may be used for metals or
cyanides.
EPA has assumed that all wastes
identified as containing HOCa or PCBs
will require incineration. EPA also has
estimated, based on its economic impact
assessment that the majority of the
California list wastes treated in surface
impoundments .will continue to be
treated in these impoundments after
compliance with RCRA section
3005(j)(ll) (A) and (B). However, EPA
has assumed that wastes treated in
these impoundments will be treated by
alternative methods (in tanks, by
solidification, etc.), on an interim basis
while the impoundments are retrofitted
to meet the minimum technology
requirements of section 3004(o) as
specified in section 3005 Q)(ll).
The information presented below
represents the Agency's best estimate of
the volumes of California list wastes
thatmay require alternative treatment
capacity. However, EPA is unable to
determine the incremental capacity
required for any wastes other than the
HOC and PCB wastes. .
CMHofM o» gtforal
Mrtato wtttM wfthout
CywwfewaslM
*•*
capably
6745
1SS4
898
7542
458
VL State Authority
A. Applicability of Rules in Authorized
States
Under section 3006 of RCRA, EPA
may authorize qualified States to
administer and enforce the RCRA
program within the state. Following
authorization, EPA retains enforcement
authority under sections 3008,3013, and
7003 of RCRA, although authorized
states have primary enforcement
responsibility. The standards and
requirements for authorization are found
in 40 CFR Part 271.
Prior to HSWA. a state with final
authorization administered its
hazardous waste program in lieu of EPA
administering the federal program in
that state. The federal requirements no
longer applied in the authorized state,
and EPA could not issue permits for any
facilities that the state was authorized
to permit When new, more stringent
federal requirements were promulgated
or enacted, the state was obliged to
enact equivalent authority within
specified time frames. New federal
requirements did not take effect in an
authorized state until the state adopted •
the requirements as state law.
In contrast, under RCRA section
3006(g) (42 U.S.C. 6926(g)), new
requirements and prohibitions imposed
by HSWA take effect in authorized
states at the same time that they take
effect in nonauthorized states. EPA is
directed to carry out these requirements
and prohibitions in authorized states,
including the issuance of permits, until
the state is granted authorization to do
so. While states must still adopt HSWA-
reiated provisions as state law to retain
final authorization, HSWA applies in
authorized states in the interim.
Today's rule is proposed pursuant to •
sections 3004 (d) through (k), and (m), of
RCRA (42 U.S.C. 6924). Therefore, it will
be added to Table 1 in 40 CFR 271.1{j),
which identifies the federal program
requirements that are promulgated
pursuant to HSWA and take effect in all
states, regardless of their authorization
status. States may apply for either
interim or final authorization for the
HSWA provisions in Table 1, as
discussed hi the following^section.
When this rule is promulgated. Table 2
hi 40 CFR 271.1(j) will be modified also
to indicate that this rule is a self-
implementing provision of HSWA.
B. Effect on State Authorizations
As noted above, EPA will implement
today's proposal in authorized states
until their programs are modified to
adopt these rules and the modification is
approved by EPA. Because the rule is
promulgated pursuant to HSWA, a state
submitting a program modification may
apply to receive either interim or final
authorization under RCRA section
3006(g)(2) or 3008(b), respectively, on the
basis of requirements that are
substantially equivalent or equivalent to
EPA's. The procedures and schedule for
state program modifications for either
interim or final authorization are
described in 4OCFR 271.21. It should be
noted that HSWA interim authorization
will expire on January 1.1983 (see40
CFR271.24(c)).
Section 271£l{ej(2) requires that
states that have final authorization must
modify their programs to reflect federal
program, changes,««i«l must
subsequently submit the modification to
EPA for approval. The deadline for the
state to modify its program for this
proposed regulation will be determined
by the date on which this regulation is
promulgated in final form. If final rule
promulgation occurs before July 1,1987.
state program modifications must be
made by July 1,1989. if only regulatory
changes are necessary, or July 1,1990 if
statutory changes are necessary. If this
-------
44734
F«d«tat Begbtar / Vot ffit. Mm 238- / Tfaunday; December t* 1986 / Proposed Rafa»
nils is promulgated in. final form after
July 1, 1987, state program modification*
must be made by July 1*1991. if only
regulatory changes are necessary or luly
1, 1992, if statutory changes are
necessary. These deadlines can.be
extended in exceptional cases (see
§ 271.21(e)(3)).
States with authorized RCRA
programs may have requirements
similar to those in today's proposal.
These state regulations have not been
assessed against the federal regulations
being proposed today to determine
whether they meet the tests for
authorization. Thus, a state is not
authorized to implement these
requirements in lieu of EPA until the
state program modification is approved.
Of course, states with existing standards
may continue to administer and enforce
their standards as a matter of state law.
In implementing the federal program.
EPA will work with states under
agreements to minimize duplication of
efforts. In many cases, EPA will be able
to defer to the states in their efforts to
implement their programs rather-than
take separate actions under federal
authority.
States that submit official applications
for final authorization less than 12
months after the effective date of these
regulations may be approved without
including equivalent standards.
However, once authorized; a state must
modify its program to include standards
substantially equivalent or equivalent to
EPA's within the time periods discussed
above.
C. State Implementation
There are three unique- aspects of
today's proposal wHcfr affect state
implementation- and impact state-actions
on the regulated cotnmunityr
1. Under PartaOK-Subpart C, EPA is
proposing- land disposal restrictions- for
all generatnrssndidkpcwerffof certans
types of hazardous wastes border to
the regulatioastunder thi
state requirements ess bennies*
stringent than federal requieuouUfc.
date of land di»p<»»ipca&itttis*»far ant
to two years if-itis;m*ndta*fetfanMSi
insufficient alternative- traatment
capacity. Under & 2S&?, caserby-case
extensions o£up;mte>
allow the asosaics:o£penni(xni
applicants whoscwastesfiBilktasaaip^r
with, one as mar* of thcMPHSA
rmrirfrnrMintalif ilJsiiis. Tiul nlsj
successfully deraaastntes nacdfhcthe
permit; tttmttmimtmA fim ifip/fofff lUmjtnmmlt
fTrtHirf ^T*?rrSSfr Sn^MBBHn8nHt
ThttAsjcscjr candBBtadiSBi analysis of
mepotaBnaUttftnx.daanadlfar.
rfirmniir (nrinnriiiiiipiaj.i
Impacts of Land Disposal Restrictions*
on Ocean Dumping and Ocean
Incineration of Solvents. Dioxins, and
California- Us* Wastes." (Refr U.S. EPA,
1986) This assessment was based' on * •
methodology to score and rank waste
streams for relative acceptability for
ocean disposal, supplemented with an>
analysis of cost factors and capacity
constraint*.
The scoring/ranking methodelogjri
based on technical'requirements (e.g.,
physical form and heating value) and1
MPRSA environmental criteria (e.g*.
constituent concentrations, toxichy,
solubility, density, and persistence of
the waste) associated with ocean
disposal of hazardous waste. The
capacity analysis assumed that those
wastes least acceptable for ocean
disposal will be treated or disposed of
by land-based methods. The cost
analysis assumed that additional land-
based treatment capacity would be built
to treat waste streams for which the
costs of land-based treatment would be
less than the costs of ocean disposal
(including on land transportation to &
port located on the East coast}.
analysis indicated that, as a resultof the
land disposal restrictions, ./
approximately 21X3 milling gallons pec"
year of hazardous wastes containing
HOCs, 15.1 - iffion gallons per year of
liquid t"»imTdo"t og^ffs con*a'"'ng
metals, and &2 million: gallons peryear
of liquid hazardous wastes containing;
PCBs potentially could create- demand
for ocean: dumping and ocean-based
incineration. Such demands result hem
capacity shortfalls o£ load-based
treatment gnemecatieB sad- chemical
predBitelten]haadta*M}advely lower
cost of oceaa dumping and oeesarbsssd
incinenstiesv tskte«Bits accaant th*
costs •£transyoctatfs»oa:lan«L1lKse
resiilte estimate ta*dMMne\ mat sorb
revised tn nHmirthn IssiiiMi nf pemils
fcr wastes. Aatdtesiet cgmpfrjr »dlfc
»*™-** T—r'rnriTnmifil rrihirio. hnroisM
the ana^sisdU se> ttlm into seauuA
teehaleai
criteria.
The Agency expanded the oost/f-
capadrjri
wastes mvtdai
requicenNnt»o
criteria* Ike resvitsefthat ssn^ni*
restrictions oat land «fi«p"T»l of solvent.
dioxiiu and California list wests*. The
results are described is "Assessment of
regal aOcasvCe«^iiMtjitsoneiqita» .
PCB-caiitamrine WasterfM mimost
-------
Federal Rgguter / Vol. 51. No. 238 / Thursday. December 11. 198» / Proposed Rnjea 44735"
gallon, pet year) identified by the cost/
capacity analysis would be acceptable
for ocean-based incineration, baaed on
technical requirements and the proposed
ocean incineration regulations. The
other potential waste stream candidates
(HOC-containing wastes, liquid metal-
containing wastes, and the remaining
PCB-containing wastes) would fail one
or both of the technical requirements for
ocean-based incineration (i.e. physical
form and heating value).
vm. Regulatory Requirements
A. Regulatory Impact Analysis
Executive Order 12291 requires EPA
to assess the effect of contemplated
Agency actions during the development
of regulations. Such an assessment
consists of a quantification of the
potential benefits and costs of the rule,
as well as a description of any
beneficial or adverse effects that cannot
be quantified in monetary terms. In
addition. Executive Order 12291 requires
that regulatory agencies prepare an
analysis of the regulatory impact of
major rules. Major rules are defined as
those likely to result in:
1. An annual cost to the economy of
$100 million or more: or
2. A major increase in costs or prices
for consumers or individual industries;
or
3. Significant adverse effects on
competition, employment investment
innovation, or international trade.
The Agency has performed an
analysis of the proposed regulation to
assess the economic effect of associated
compliance costs. Total coats of
proposed restrictions on affected wastes
are expected to amount to
approximately $100 million. The
proposal thus constitutes a major rule
under Executive Order 12291. and EPA
has prepared a formal regulatory impact
analysis, of today's proposal
The remainder of Unit Vffl describee
the economic .analyst* performed by
EPA in support of today's proposed rule
affecting all California HstJwaste*
idenHfied in section 3004fd)(2) of RC5RA.
1. Cost and Economic Impact
Methodology
EPA has assessed the coats and- ""
potential economic effects of thir
proposeoVnrie'and of major regulatory
alternatives to it.
EPA is proposing to codify the. levels
specified by Congress in section
3004(d)(2) of RCRA.Jn addition to-
assessing the proposed regulationv me
Agency has examined major regulatory
alternatives to it In this preamble, EPA
presents results for the proposed rule
only. Each of the alternatives is
explored in detail in the regulatory
impact analysis. The methodology for
establishing total costs and economic
impacts of the rule has three steps. First
EPA estimates the population of
facilities and waste management
practices which will be affected. Next
total social costs of the regulation are
derived by adding costs for individual
facilities. Finally, economic impacts on
affected facilities are assessed.
a. Affected population and practices.
The affected population is the total
number of hazardous waste treatment
storage and disposal facilities (TSDFs)
and generators land disposing of
California list wastes either directly at
the generation site or indirectly through
the purchase of off-site commercial land
disposal services. Four distinct types of
plants comprise this population: non-
commercial TSDFs, which generate and
dispose of their own wastes; commercial
TSDFs, which manage wastes generated
elsewhere; generators that send large
quantities of wastes off-site for •
management; and small quantity
generators, who generate between 100
and 1000 kg of hazardous waste per.
month. Waste management practices for
each of these groups are assessed to
identify current costs of managing
wastes and incremental cost increases
attributable to today's rule.
The number of facilities that land
dispose affected wastes was determined
using the EPA's 1981 Regulatory Impact
Analysis Mail Survey.* Waste quantities
and management costs for facilities
responding to the Mail Survey are
scaled up to represent the national
population by means of weighting
factors developed for the survey. EPA
estimates mat 495 facilities comprise the
total national population of commercial
and non-commercial faculties tend
disposing of California list wastes on-
site, excluding facilities disposing of
PCS containing waste. This estimate is
.based on 1981-survey data adjusted for
intervening regulatory requirements.
Because the 1981 survey was a
statistical sample and not a census,...
updating it with more current ->•—~"
information available to the Agency'
from other sources is difficult Based on
'these sources, however, EPA believes
that mis estimate may overstate the
actual number of TSDFs now land
disposing of California list waste.
1 EPA conducted tha HI* Mail Survey at
hazardous waate generators and TSDFa to
determine wwte management pnctfcM In 19SI.
Faculties that bandied to* thn MOO kilogram, of -
waste per.BOnth won not r*g*iated la MSI and
thua an not Included in the data, fat man
information see the "National Survey of Hazardoua
Watte Generator* and Treatment Storage and
Diapasa) Facilities Raguteled under ROTA in 1981."
EPA estimates that an additional 3£79
plants generate more than l.OOff
kilograms per month of wastes that are
sent off-site for management The waste
is disposed of by either non-commercial
TSDFs (e.g. owned by the firm
generating the waste but at a different
location] or by a commercial TSDF.
Generators of less than 1,000
kilograms per month were not included
in the 1981 survey because they were
considered exempt at that time.
However, the 1984 amendments to the
Solid Waste Disposal Act direct EPA to
lower the exemption for small quantity ,
generators (SQGs) from 1.000 to 100
kilograms per month by March 31,1988,
so SQGs generating between 100 and
1000 kilograms of waste per month for
off-site disposal are also included hi the
affected population. The Agency
estimates that SQGs add 2,131 plants to
the affected population. Plant and waste
specific data on this group are derived
from EPA's Small Quantity Generator
Survey.'
Because of the design of the Mail
Survey, generators of PCBs mixed-with
hazardous wastes regulated under •
RCRA were not represented in it. Data
on this group have been developed more
recently, end-indicate approximately 63
generators of mixed PCB/RCRA
hazardous wastes.4
EPA's characterization of
management practices for these groups
includes the cost of compliance with
regulations which have taken effect
since the 1981 survey was conducted. In
particular, EPA adjusted waste
management practices reported to
reflect compliance with the provisions of
40 CFR Part 28* of RCRA. m making this
adjustment, the Agency assumes
faculties elect the least costly legal
methods of compliance. This adjustment
defines not only current management
practices and costs associated with
them, but also the number of waste
streams in the-sffected population. For
example; for 55 facilities, the costs of
land disposing'of certain wastes are
driven sonigh by regulations predating
this proposal that other management.
modes are less likely to resolve disposal
of these wastes and, therefore that
these wastes are no longer part of die
population of waste streams thatmay be
afferted by any restriction* on land
disposal. No aggregate modtteliaw
been.d8veloped.for.the population of
» Offlee of SoM-WMtft Tftrthmar SmaltQuantity
Ha««io«ia.Wae4« Generator Swvey," February
1885.
4 Office of Solid Wtsi* "Characteriulfen of
Mixed PCB/RCRA Hazardous Waatea." Febraan
1985.
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44736
Federal Register / Vol. 51. No. 238 / Thursday. December 11. 1986 / Proposed Rules
treatment, storage and disposal facilities
andI small quantity generators, examined
in this analysis. Instea'd, individual case
observations in the data sources have
been weighted to represent the national
population of wastes and management
practices. For generating plants
disposing of large quantities of
California list wastes off-site, "model"
plants representing average, maximum
and minimum waste quantities were
developed to assess the range of
potential economic effects. For
generators of mixtures of PCBs and
RCRA hazardous wastes, economic
effects were assessed using "model"
plants representing typical waste
quantity and plant size characteristics.
b. Development of costs. Once waste
quantity, type and method of treatment
are known for the affected population,
EPA developed estimates of costs of
compliance for individual facilities. The
analysis detailed in this section is based
on cost estimates for surveyed facilities
representing the affected population.
Wastes amenable to similar types of
treatment were grouped to identify
economies of scale available through co-
treatment and disposal.
EPA developed current waste
management costs by adjusting 1981
waste management practices to reflect
compliance with regulatory
requirements predating restrictions on
land disposal. Estimated costs for
disposal in surface impoundments
assume compliance with Part 264 of
RCRA, which requires surface
impoundments to have double liners and
leachate collection systems between
liners, subject to certain exemptions.
This assumption could lead to an
overestimate of current disposal costs
and. thus, to an underestimate of
incremental costs for surface
impoundments exempted from these
requirements. Existing requirements
under RCRA are also considered in
developing coats for disposal in landfills
and waste piles. • .
Facilities face several possible option* -
if they may no longer landdispose of "~ •
their wastes. EPA applies the samT' —
rationale in predicting: facility-choice ~
among these options a« it does in
establishing the affected population:
facilities are assumed to elect the least
costly method of complying with the
requirements of this proposal. Costs of
compliance are derived by predicting
the minimum-cost method of compliance
with land disposal restrictions for each
facility and calculating the increment
between that and current disposal costs.
As in the analysis of current costs,
economies of scale in waste
management are considered.
Shipping costs for wastes sent off-site
tor management are also considered. In
the development of current waste
management costs, the transportation
distance assumed for off-site waste
treatment and/or disposal is 100 miles.
Most plants now sending wastes off-site
do so for disposal. Although the likely
effect of restrictions will be to require
pretreatment in addition to disposal, the
Agency has not increased the assumed
transportation distance. This assumes
that plants now sending wastes off-site
for disposal only can also purchase
treatment services from the same
commercial facilities. But even if the
assumption of no increase in
transportation distance does not
accurately predict the effects of this
rule, our examination of the sensitivity
of results to this assumption found that
varying the assumption in travel
distances, even by as much as a factor
of eight, has a minimal effect on results.
This is because many plants that send
wastes off-site send small amounts, and
thus economies of scale (reflected in per
unit prices of waste disposal at large
commercial facilities) outweigh even
major increases in shipping costs.
EPA developed facility-specific
compliance costs in two components,
which are weighted and then summed to
estimate total national costs of the
proposal. The first component of the
total compliance cost is incurred
annually for operation and maintenance
(O&M) of alternative modes of waste
treatment and disposal. The second
component of the compliance cost is a
capital cost which is an initial outlay
incurred for construction and
depreciable assets. Capital costs are
restated as annual values by adjusting
them into equivalent yearly payments
using a capital recovery factor based on
a real cost of capital of 7 percent These
annualized capital costs are then added
to yearly O&M costs to derive an annual
equivalent cost The result is EPA's
estimate of the impact of the regulation
on annual firm cashflow.
c. Economic impact analysis..
i. Non-commercial TSDFs and SQGa. -
Economic impacts on non-commercial
TSDFs and SQGs are assessed in
several steps.-First a general screening
analysis compares facility-specific
incremental costs to financial
information about firms, disaggregated
by Standard Industrial Classification
(SIC) and number of employees per
facility. This comparison generates, two
ratios, which are used to identify,
facilities likely to experience adverse
economic effects. The first is a ratio of
individual facility compliance costs to
costs of production. A change exceeding
five percent is considered to imply a .
substantial adverse economic effect on a
facility. The second is a "coverage"
ratio, relating cash from operations to
costs of compliance. For this ratio, a
value of less than 20 is considered to
represent a significant adveree effect
The coverage ratio is the more stringent
of the two ratios, but exceeding the
critical level in either one suggests that
a facihty is likely to be significantly
affected. Both of these ratios implicitly
assume that facilities will be unable to
pass on compliance costs to consumers
. of their products and services in the
form of higher prices. This analyst*
considers only pre-tax costs, because
census data are stated in before-tax
terms.
Once facilities experiencing adverse
economic effects are identified using the
two screening ratios, more detailed
financial analysis is performed to verify
the results and to focus more closely on
affected facilities. For this subset of
facilities, the coverage ratio is adjusted
to allow a portion of costs to be passed
through. Economic effects on individual
facilities are examined assuming, that
product price increases of one and five
percent are possible. Those facilities for
which, the coverage ratio is still legs
than two are considered likely to close.
ii. Commercial TSDFs. Commercial
TSDFs are defined here as those
facilities which accept fees in exchange
for management of wastes generated
elsewhere. For this group of facilities,
there exists no Census SIC from which
to draw financial information. Two SICs
which we might use as proxies, 4953 and
4959, do not distinguish between
financial data for hazardous waste
treatment firms and for firms managing
municipal and solid waatea.
Consequently, our analysis of economic
effects on commercial facilities is
qualitative. This analysis includes an
examination of the quantity of waste •
each facility receives from the waste
group restricted by today's proposal.
EPA also examines the ability of each
facility to provide the additional
treatment required once these
restrictions are promulgated, and thus to
retain or expand that portion of its
business generated by restricted wastes.
iii. Generators of large quantities of
wastes. EPA's analysis of the economic
effects of this proposal on generating
plants disposing of large quantities of
affected wastes off-site assumes that
commercial facilities can entirely pass-
on to .them the costs of compliance with
this regulation in the form of higher:.
prices for waste management services.
Because of data limitations in the Mail
Survey, EPA has not developed plant-
i
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Federal Register / Vol. 51, No. 238 / Thursday December 11, 1988 / Proposed Roles
specific waste characterization,
treatment methods, and compliance
costs for generators, as it has for TSDFs.
Our analysis of the economic effects of
the proposed regulation on this group
uses RIA Mail Survey data to develop
model plants generating average.
maximum and minimum waste
quantities. This allows EPA to assess
the range of possible effects on
generating plants.
2. Costs and Economic Impacts
Total costs of regulating California list
wastes qualify today's proposal as
major under Executive Order 12291,
since total annualized costs of
restricting land disposal of these wastes
are estimated at $97 million. These costs
are not adjusted for the effect of
taxation, which is merely a transfer
from one sector of the economy to
another. Costs are stated in 1985 dollars.
The proposed regulation and
alternatives will affect entities in a
variety of four-digit SICs, including
chemicals and allied products,
petroleum products, and metals
industries. Among non-commercial
TSDFs, three sectors account for
approximately 81 percent of all land
disposal restriction compliance costs
likely to be incurred by sectors land
disposing of California list wastes. SIC
28, chemicals and allied products, alone
accounts for 40 percent Two other
sectors also contribute significant
amounts, although much less: SIC 33.
primary metals, accounts for 16 percent;
and SIC 34, fabricated metal products,
accounts for 5 percent In the aggregate,
non-commercial TSDFs account for 65
percent of the costs of .this proposed
rule. Commercial TSDFs, included
predominantly in SIC 4953, account for
the balance; .
Economic effects have been assessed
for both non-commercial and
commercial facilities. Non-commercial
facilities are those that generate and
manage their own wastes, as distinct
from facilities that accept fees in
exchange for management and disposal
of wastes generated by others. Of 457
(weighted) non-commercial faeilitie*
nationally, 84 may experience financial
distress because of this rule, and 9 of,.
these appear likely to close. Five of the 9
likely closures belong to die chemical
industry (SIC 28). and the primary (SIC
33)'and fabricated metals (SIC 34)
Lndustries. Employment effects
associated with these 9 closures amount
to 188 jobs lost
We estimate that 38 commercial
facilities incur incremental costs as a
result of the restriction, on land disposal
of California list wastes. Forty-two
percent of these commercial facilities
offer a range of hazardous waste .
management services, including land-
based disposal, storage and treatment.
The increased demand this rule will
create for highly-priced treatment
services may actually strengthen the
financial position of these firms by
allowing them to increase market share.
For the 16 percent of commercial
facilities that offer solely land-based
management of restricted wastes, on the
other hand, the increased emphasis on
treatment prior to land disposal may
prove economically disadvantageous. It
was not possible to characterize the
remaining 42 percent of commercial
facilities based on services offered.
Turning to effects on generators, EPA
found that based on average waste
quantities, the 187 sectors generating
California list waste include 3,279
plants. Of these. 133 plants may
experience significant financial distress
based on costs imposed by restrictions
on land disposal. This represents nearly
four percent of all the waste-generating
plants that may face increased waste
management prices. Most significantly
affected plants belong to either the
chemical or primary or fabricated
metals products industries. Based on
further analysis, 14 of the 133 distressed
plants appear likely to close.
Employment effects associated with
these closures amount to 264 jobs.
Total annualized national costs for the
2,131 small quantity generators of
California list wastes are $5.1 million.
Based on engineering estimates of prices
for off-site waste management services,
costs for SQGs generating the maximum
of 1,000 kilograms per month of nothing
but hazardous wastes named in the
California list would incur less than
$13,200 annually in incremental
compliance costs. Economic ratios for
all plants in each 4-digit sector
represented in the SQG survey were
examined, and in 66 cases plants
seemed likely to experience aome
financial distress, and two of tnese
plants appear likely to close. Thus.
restricting land disposal of California
list wastes may have substantial
adverse economic effect on
approximately 3 percent of aQ '
generators of small quantities of'wastes.
Economic effects on generators of
mixed PGB/RCRA wastes are also not
expected to be significant, although
because of data limitations no plant-
specific analysis could be undertaken.
Further information on economic effects
on all groups mentioned above is
available in the regulatory impact
analysis supporting this proposed rule.
3. Benefits and Cost-effectiveness of
Restricting Land Disposal of California
The regulatory impact analysis
performed by the Agency evaluated
three regulatory alternatives for
restricting the land disposal, of ,
California list wastes. As with the
discussion of cost and economic
impacts, this preamble presents results
associated with the proposed approach,
to codify the statutory levels for the
California list as set forth in section
3004(d).
The benefits of today's proposal were
evaluated by considering the reduction
in the number of cases of human health
effects that result from treating
California list wastes with alternative
technologies rather than management by
current land disposal practices.
Predicting potential human health
effects entails estimating quantitatively
the consequences of human exposure to
disease causing agents. Human health
risk is the probability of injury, disease,
or death over a defined time period. To
estimate risks of baseline and J
alternative technologies, the analysis
characterizes wastes, technologies,
releases, environmental transport, and
dose-responses, based largely on-
comparative risk assessment
methodologies. The analysis includes an
evaluation of individual risk due to
chronic exposure, where the risk
determination accounts for, the dose, the
chronic risk per unit dose, a factor that
distinguishes between, the dose-
response for carcinogens and other
types of substances. The analysis also
weights the cases by the relative
severity of the toxic effect The
individual risk is- converted into a
number of cases using estimates of the
population exposed. For each
combination of California list waste,
technology,, and environment, the model
derives estimates of the total number, of
people affected by the waste
management practice.
In assessing the benefits of the
proposed approach, the analysis, is
limited to reductions in human health
effects attributed to a reduction in
exposure to the: toxic, constituents in
these wastes. Aa a result ;the benefits of
the land disposal restrictions for
California list wastes may be
underestimated. Other benefit
considerations such as improvements in
environmental quality were not
quantified. Furthermore, the assessment
may underestimate-benefits since the.
effects of the comparative risk analysis
were not included. Therefore,: negative
benefits resulting from a technology •
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44738 Federal Register / Vol. 51. No. 238 /Thursday. December 11. 1986 / Proposed Rules
considered riskier than- land disposal
(which, would be designated not
available as an alternative to land
disposal) were included in the analysis.
Although this assessment does not
estimate potential increases in risk from
increased transportation and handling
of California list wastes, an initial
analysis indicates that increases are not
likely to be significant.
Based on this benefits analysis,
implementing the statutory levels and
defining BOAT technologies for HOCs
and PCBs are estimated to result in a net
reduction in health risks equal to 2853 '
weighted cases (e.g.. cancer, fetal
toxicity, decreases in reproductive
capacity, etc.) over seventy years, or a
33.9 percent reduction from baseline
practices. As mentioned earlier, the total
increase in annualized cost of restricting
land disposal of California list wastes is
estimated at $97 million. .This yearly
incremental cost represents a 250
percent increase in costs over current
land disposal practices. Division of the
total increase in annualized cost by the
annualized reduction in health risks.
40.75 cases, determines that the cost of
the proposed regulatory approach is
S2.38 million per case avoided.
B. Regulatory Flexibility Analysis
Pursuant to the Regulatory Flexibility
Act. 5 U.S.C. 801 etseq., whenever an
agency is required to publish a notice of
rulemaking for any proposed or final
rule, it must prepare and make available
for public comment a regulatory
flexibility analysis that describes the
effect of the rule on small entities (i.e..
small businesses, small-organizations,
and small governmental jurisdictions).
This analysis is unnecessary, however,
if the agency's administrator certifies
that the rule will not have a significant
economic effect on a substantial number
of small entities.
EPA has examined the rule's potential
effects on small businesses as required
by the Regulatory Flexibility Act and"
has concluded-that today's proposed "
rule will not have a significant economic •
effect on a substantial number of small-
entities. As a result of this finding. EPA
has not prepared a formal Regulatory
Flexibility Analysis document in support
of this rule. The following discussion •
summarizes the findings oh which the
conclusions above are based. More
detailed information is available in the
record and in technical background
documents prepared in support of this
rulemaking.
EPA evaluated the economic effect of
the proposed rule on small entities,
defined here as firms employing fewer
than 50 people. Because of data
limitations, this small business analysis
excludes generators of large quantities
of California list wastes. The "small
business" population examined
therefore includes only two groups: all
treatment, storage and disposal facilities
employing fewer than 50 persons, and
all small quantity generators that are
also small businesses. 158 TSDFs are
small businesses. Of these. 5 exceed
threshold values on the cost of
production ratio, a figure that represents
3 percent of this small business
population.
Of the total of 2,131 small quantity
generators examined in this analysis,
the vast majority (1,914 or 97 percent of
the total population of SQGs) are also
small businesses. A total of 5 SQGs (or
less than one percent of all small
businesses) exceeded threshold values
on the cost of production ratios.
According to EPA's guidelines for
conducting Regulatory Flexibility
Analysis, if over 20% of the population
of small business are likely to
experience financial distress based on
the costs of a rule, then the Agency is
required to consider that the rale will
have a significant effect on a substantial
number of small entities and must
perform a formal Regulatory Flexibility
Analysis.6 Economic impacts on small
entities are not expected to exceed three
percent of the total small business
population, and thus EPA has not
prepared a formal RFA.
C. Review of Supporting Documents and
Request for Public Comments
1. Review of Supporting Documents
The primary source of information on
current land disposal practices and
industries affected by the proposed
regulation is EPA's National Survey of
Hazardous Waste Generators and
Treatment, Storage and Disposal
Facilities. Waste stream.
characterization data and engineering
costs of waste management are based
on the Mail Survey, and on reports by
the Mitre Corporation, "Composition of
Hazardous Waste Streams Currently
Incinerated," (April 1983), andU.S, EPA,
. "The RCRA RisbCost Analysis Model;'
(March 1984). The survey of small
quantify generators has been the major -
source of data on this group. Data used.
to characterize generators of mixed
PCB/RCRA hazardous wastes were
taken from an EPA study. •*•"•>.
"Characterization of MiXetfFCB/RCRA
Hazardous Wastes," (Febrearrl985L
For financial and value of shipment
information for the general screening
analysis, 1982 Census data were used,
• See U.S. EPA. "Guideline! for Compliance with
the Regulatory Flexibility Act." February 1982.
adjusted by 1983 Annual Survey of
Manufactures data. Producer price
indices were also used to restate 1983'
dollars in 1985 terms.
2. Request for Public Comments
EPA recognizes mat due to constraints
of time and data availability, this
analysis has significant limitations.
Specifically, EPA requests comment on
the following:
a. EPA would like to refine the
assumption that costs imposed on
commercial hazardous waste facilities
can entirely be passed through in the
form of higher prices. The Agency
requests any estimates of typical profit
margins in the commercial hazardous
waste industry, data on waste
management fees, and on the percent
price increase in waste management
fees that may force substitution on.
generators.
b. The Agency requests public
comment and data on the feasibility o£ .
small business waste recycling; -
reclamation, or in-process reduction. .
c. The Agency requests comment and -
data on the technical feasibility of, and -
costs associated with, waste '
segregation; . ~t-
IX. References
Background Document* ''•••'.'
(1) U.S. EPA. "Background Document for
Land Disposal Restriction* of Hazardous
Waste* Listed in section-30M(d) of the '"
Resource Conservation and Recovery Act-
US. EPA, OSW. Washington. DC. 1988
(2) U.S. EPA. "Comparative Risk
Assessment of Selected California List
Wastes for the RCRA Land Disposal
Restrictions." US, EPA. OSW. Washington.
DC, 196ft - •-.'.-.."
Regulatory Impact Anafyai* . .
(3) U.S. EPA. "Regulatory Analysis of
Proposed Restriction* on Land Disposal of
California List Wastes." U.a EPA, OSW.
Washington. DC, 1969 •'• •
Other References _ .._..-, ,. .
(4) American Public Health Association.
American Water Work* Association. Water
Pollution Control F»derano«.5/o«farrf - ,
Method* for thiExononaiion of Water ami
Wastawataf.-ltiOiMUtoef.l9m ' .
• (5) American Society of Testing and
Material*,AnnuafBaoAofASTM Standards.
Philadelphia, PA, Mi* -
(6) Cherry, KP* 1082, Plating Waste
rreotoiwjt Ann Arbor Science •
(7)Kelada. NJR, Lue-Mins; C. and LordL
D.T.. 1978; "Cyanide Spede* and
Thiocyanate Methodology to Water an* -
Wastewater." Chapter ao, IK Cheaiittryof
Wastewaier Technology. Ann Arbor Science
(8) Lowenheia. RA,,wn. electroplating.
Sponsored by the American Electroplating
Society. McGraw-Hill Book Company. New
York.NewYork
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Federal Register / Vol. 51. No» 238 / Thursday. December 11. 198B / Proposed Rules - 44739
(9) U.S. EPA. "Assessment of Impacts of
Land Disposal Restrictions on Ocean ,
Dumping and Ocean Incineration of Solvents,
Dioxins, and California List Wastes." U.S.
EPA, OSW, Washington. DC, 1986
(10) U.S. EPA. "Characterization of Mixed
PCB/RCRA Hazardous Wastes." U.S. EPA,
OSW, Washington, DC, 1985
(11) U.S. EPA. "National Small Quantity
Hazardous Waste Generator Survey." U.S.
EPA, OSW, Washington, DC, 1985
(12) U.S. EPA. "National Survey of
Hazardous Waste Generators and Treatment,
Storage and Disposal Facilities Regulated
Under RCRA in 1981." U.S. EPA, OSW,
Washington, DC, 1984
(13) Goldman, L.J. and Tatsch, C.E.,
"Compatibility of Corrosive Acids with
Codisposed Wastes," 1985
List of Subjects in 40 CFR Parts 260,
261,262,264,265,268,270, and 271
Adminstrative practice and:
procedure, Confidential business
information, Environmental protection,
Hazardous materials, Hazardous
materials transportation. Hazardous
waste, Imports, Indian lands, Insurance,
Intergovernmental relations. Labeling,
Packaging and containers, Penalties,
Recycling, Reporting and recordkeeping
requirements. Security measures, Surety
bonds, Waste treatment and disposal,
Water pollution control, Water supply.
Dated: November 28,1986.
L«« M. Thomas,
Administrator.
Therefore, it is proposed that Chapter
I of Title 40 be amended as follows:
PART 260—HAZARDOUS WASTE
MANAGEMENT SYSTEM: GENERAL
1. The authority citation for Part 260
continues to read as follows:
Authority: Sees. 1006,2002(a), 3001 through
3007, 3010.3014,3015..3017,3018. and 3019,
Solid Waste Disposal Act as amended by the -
Resource Conservation and Recovery Act of
1976, as amended (42 U.S.C: 6905,6912(a),
6921 through 6927, 6930,6934,6935,6937,6938,
and 6939).
2. In § 260.11, paragraph (a)
introductory text is revised to read as
follows: • _
§260.11 Reference«.._
(a) When used in Parts 260 through ,
268 of this chapter, the following
publications are incorporated by
reference: '•••'• '
PART 268—LAND DISPOSAL
RESTRICTIONS
1. The authority citation for Part 268
continues to read as follows;
Authority: Sees. 100ft, 2002(a). 3001. and
3004 of the Solid Waste Disposal Act, as
amended by the Resource Conservation and
Recovery Aet of 1976, as amended (42 U.&C.
6905,6912(3), 6921, and 6924).
2. The Table of Contents for Subpart'C
is amended by adding an entry for
5 268.32 to readjas follows:
Subpart C—Prohibitions on Land Disposal
* *'•' • * ' * *
268.32 Waste specific prohibitions—
California list wastes.
Subpart A—General
3. Section 268.3 is revised to read as
follows:
§268,3 Dilution prohibited as • substitute
for treatment
No generator, transporter, handler, or
owner or operator of a treatment,
storage, or disposal facility shall in any
way dilute a restricted waste or the
residual from treatment of a restricted
waste as a substitute for adequate
treatment to achieve compliance with
Subpart D of this part, to circumvent the
effective date of a prohibition in Subpart
C of this part, or to otherwise avoid a
prohibition in Subpart C of this part
4. In 5 268.4, paragraph (a)(2) is
revised and paragraph (b) is added to
read as follows:
§268,4 Treatment surface impoundment
exemption.
(a) * * *
(2) The residues of the treatment are
analyzed, as specified in § 268.7, to
determine if they-meet the applicable
treatment standards in Subpart D of this
part, or, where no treatment standards
have been established for the waste, the
applicable prohibition levels specified in
Subpart C of this part. The sampling
method, specified in the waste analysis
plan under 5 264.13 at § 265.13, must be
designed such that representative •
samples of the sludge and the
supernatant are tested'separately rather
than mixed, to form homogeneous • • •
samples. The treatment residues
(including any liquid waste) that do not
meet the treatment standards
promulgated under Subpart Oof this
part, or the applicable prohibition levels
promulgated under Subpart C of this.
part (where no treatment standards
have been established), or which are not
delisted under § 280.22 of this chapter,
must be removed at least annually.
These residues may not be placed in any •
other surface impoundment for
subsequent management. If the volume
of liquid flowing through the
impoundment or series of impoundments •
annually is greater than the volume -to-
the impoundment or impoundments, .this
flow-through constitutes removal of the
supernatant for the purpose of this
requirement. The procedures and
schedule for the sampling of
impoundment contents, the analysis of ";
test data, and the annual removal of ' "
residue which does not meet the' Subpart
D treatment standards, or Subpart G : •
prohibition levels where no treatment •
standards have been established, must •
be specified in the facility's'wdstB
analysis plan as required under § 264.13
or S 265.13 of this chapter.
* * * * • *'
(b) Evaporation of hazardous
constituents is not considered treatment
for purposes of an exemption under this
section.
5. In § 268.5, paragraph (a)(2) is
revised to read as follows:
§2683 Procedure* for case-by-case
extension* to an effective da.te.
(a) * * *
(2) He has entered into a binding
contractual commitment to construct or
otherwise provide alternative treatment,
recovery (e.g., recycling), or disposal
capacity that meets the treatment
standards specified in Subpart D or,
where treatment standards have not
been specified, such disposal capacity is
protective of human health and the
environment.
Subpart C—Prohibitions on Land
Disposal
6. In Subpart C. § 268.32 is added to
read as follows:.
§268.32 Waste specific prohibitions—
California list wastes.
(a) Effective July 8,1987, the following
liquid hazardous wastes are prohibited
from land disposal (except in injection
wells): '••'..'••
(1) Liquid hazardous wastes, including
free liquids associated with any solid.or
sludge, containing cyanides at
concentrations greater than or equal to
i,000mg/l;
(2) Liquid hazardous wastes, including
free liquids associated .with any solid or
sludge, containing the following metals
(or elements) or compounds of these
metals (or elements) at concentrations .
greater than or equal to those specified
below: . .
(i) Arsenic and/or compounds (as As)
500mg/l; : ;-=..:
(ii) Cadmium and/or compounds (as
Cd)100mg/l; ....; -.,..'. :
(iii) Chromium- (VI and/or compounds
(asCrVI))5p0.mg/l;
(iv) Lead and/or compounds (as Pb) •
500mg/l; • •:
(v) Mercury and/or compounds (as
Hg)20mg/l; • • ' • . .
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44740
Federal Register / Vol 51. No. 238 / TTiursday. December 11, 1986 / Proposed Rules
(vi) Nickel and/or compounds (as Nil
134mg/l;
(vii) Selenium and/or compounds fas
SD)100mg/l;and l
(viii) Thallium and/or compounds fas
Tl)130mg/l;
(3) Liquid hazardous wastes having a
pH less than or equal to two (2.0); and
(4) Liquid hazardous wastes
containing halogenated organic
compounds in total concentration
greater than or equal to 1,000 mg/kg but
less than 1%.
(b) The requirements of paragraph (a)
of this section do not apply if:
(1) The wastes are treated to meet the
standards of Subpart D of this part; or
(2) The wastes are disposed at a
facility that has been granted a petition
under § 288.6; or
(3) An extension has been granted
under § 26S.5; or
(4} The wastes are treated in surface
impoundments pursuant to 9 288.4.
(c) The requirements of paragraph (a)
of this section do not apply until
November 8,1988 where the wastes are
contaminated soil or debris resulting
from a response action taken under
section 104 or 106 of the Comprehensive
Environmental Response.
Compensation, and Liability Act of 1980
or a corrective action required under
RCRA Subtitle C.
(d) Effective July 8, 1989, the following
wastes are prohibited from land
disposal (subject to any regulations
promulgated with respect to disposal in
injection wells]:
(1) Liquid hazardous wastes
containing polychlorinated biphenyls at
concentrations greater than or equal to
50 ppm;
(2} Non-liquid hazardous wastes
containing halogenated organic
compounds in total concentration
greater than or equal to 1.000 mg/kg;
(3) Liquid hazardous wastes
containing halogenated organic
compounds in total concentration
greater than or equal to 196.
(e) The requirements of paragraph (d)
of this section do not apply ifc
(1) The wastes are treated to meefTne
standard* of Subpart D of (his part; or
(2) The wattes are disposed at a
facility that has been granted a petition
under 5 288.6; or
(3) An extension has been granted
under 1288.5; or
(4) The wastes are treated in surface
impoundments pursuant to § 288.4.
(f) To determine whether or not the,
waste is a liquid under paragraphs (a) or
(d) of this section, the following test
must be used: Method 9095 (Paint Filter
Liquids Test) as described in 'Test
Methods for Evaluating Solid Wastes,
Physical/Chemical Methods," EPA
Publication No. SW-648 (incorporated
by reference, see S 260.11(a)).
Subpart D—Treatment Standard*
7. Section 268.42 is amended by
adding paragraphs (a)(l) and (a)(2) and
by revising paragraph (b) to read as
follows:
§268.42 Treatment standards expressed
as specified tectinotogien.
(a) * * *
(1) Liquid hazardous wastes
containing polychlorinated biphenyls
(PCBs) at concentrations greater than or
equal to 50 ppm but less than 500 ppm
must be incinerated in accordance with
the technical requirements of 40 CFR
761.70 or burned in high efficiency
boilers in accordance with the technical
requirements of 40 CFR 781.60. Liquid
hazardous wastes containing
polychlorinated biphenyls (PCBs] at
concentrations greater than or equal to
580 ppm must be incinerated in
accordance with the technical
requirements of 40 CFR 781.70.
(2) Non-liquid hazardous wastes
containing halogenated organic
compounds (HOCs) in total
concentration greater than or equal to
1.000 mg/kg and liquid hazardous
wastes containing HOCs in total
concentration greater than or equal to
1% must be incinerated .in accordance
with the requirements of S 264.343 or
§285.343.
(b) The applicant must submit
information demonstrating that his
treatment method is in compliance with
all federal, state, and local requirements
and will not present an unreasonable
risk to human, health or the environment.
The applicant must submit information
demonstrating that his treatment method
will not present an unreasonable risk to
human health or the environment On
the basis of such information and any
other available information, the
Administrator may approve the use of
the alternative treatment matting if he
finds that the alternative treatment
method provides a level of performance
equivalent to that achieved by methods
specified in paragraph (a) of this section.
Any approval must be stated in writing
and may contain such provisions and
conditions as the Administrator deems
appropriate. The person to whom such
certification is issued must comply with
all limitations contained in such a'
determination.
8.40 CFR 268.43 is added to read as
follows:
§261.43 Treatment standards expressed
as waste concentration*.
(a) Liquid hazardous wastes having a
pH less than or equal to two (2.0) must
be treated in order to raise the pH of the
waste to a level above two (£0).
(b) [Reserved]
PART 270—EPA-ADUINISTEREO
PERMIT PROGRAMS: THE
HAZARDOUS WASTE PERMIT
PROGRAM
1. The authority citation of Part 270
continues to read as follows:
Authority: Sec*. 1006.2002.3006.3007.301ft
and 700* of me Solid Waste Disposal Act «s
amended by the Resource Conservation and
Recovery Act of 1976, as emended (42 US.C.
6905.6912.6025,6927.6039 and 6974).
Subpart D-Changes to Permits
2. In 5 270.42. paragraph (p) is added
to read as follows:
§270.42 Mnormodmcatfons of permits,
* * • » *
(p) Allow changes at a permitted
facility to treat or store in containers or
tanks hazardous wastes subject to land
disposal restrictions imposed by Part
268, provided that the permittee:
requests a major permit modification
pursuant to S1243 and S 270.41;
demonstrates in the major permit ~
modification request that the treatment
or storage is necessary to comply with
the land disposal restrictions of Part 280;
and ensures that the added units comply
with the applicable Part 284 standards
pending final administrative disposition
of the major permit modification
request The authorization to make
changes conferred herein shall terminate
upon final administrative disposition of
the permittee's major modification
request under i 270.41 or termination of
the permit under 127O43.
3. In 1270.72. paragraph (e) is revised
to read as follows:
§270.72 Changes during interim statue.
****** ,
(e) In no event shall changes be made
to an HWM facility during interim -*chw
which amount to reconstnctioB of uVs
facility. Reconstruction ocean when the
capital investment in the changes to the
facility exceeds fifty percent of the
capital cost of a comparable entirely
new HWM facility. Changes prohibited
under this paragraph do not include
changes to treat or storentcoatatoen or
tanks hazardous wastes subject la land
disposal restrictions imposed under Part
268, provided that such changes are
made solely for the purpose of
complying with Part 288.
[FR Doc. 88-27305 Filed 12-10-88; &4SamJ
B4LUMQ CODE 65(0-60-11
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