Monday
 December 11, 1999
Part  VI



Environmental

Protection  Agency

40 CFR Parts 261, 271, and 302
Hazardous Waste Management System;
Identification and Listing of Hazardous
Waste CERCLA Hazardous Substance
Designation; Reportable Quantity
Adjustment; Rnal Rule

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50968
               ft** ««- /  yol.  M. No. „ , Monda, „_,., ^ i9m / ^ ^ g____
     irtVIRONMENTAL PROTECTION
     AGENCY

     40 CFR Parts 261,271, and 302

     lSWH-fHL-3*30-«; EPA/0*W-«Mt-01t|

     Haxardoyt Watt* Manaotmtnt
     Sy»ttm: Jdtntmcatten and Usjttng of
    &SSSZSEZZ "RClAlSSrdott,
    SuDitanc* Designation; Rtport-M*
    Quantity Adjustment

    AGENCY: Environmental Protection
    Agency.
    *cno*c Final rule.	

    SUMUAAY: The Environmental Protection
    Agency (EPA) today is amending its
    regulations under the Resource
    Conservation and Recovery Act (RCRA)
    by listing as hazardous one generic
   category of waste generated during the
   manufacture of chlorinated aliphatic
   hydrocarbons by free radical catalyzed
   processes having carbon chain lengths
   ranging from one to five (EPA
   Hazardous Waste No. F025). EPA is also
   responding to comments on another
   generic category of waste (that was
   promulgated as an interim final rule on
   February 10.1984) generated by the

  No. F024); the Agency is also finalizing
  this listing: w thout substantive change.
  3Sn# ?* 'l8^1?8 descriP«°n has been
  clarified. In addition, the Agency is
  finalizing the addition of two toxicants
  to Appendix VIII of part 281. The effect
  of this regulation is that these wastes
  will be or will continue to be subject to
  regulation, respectively, as hazardous
  under 40 CFR parts 281-268.288.270.
  271. and 124. This action, however, does
  not apply to wastes generated during the
  production of chlorinated aliphatic
  hydrocarbons that were previously
  listed as hazardous on May 19,1980.
   In addition, the Agency is also making
 final amendments to CERCLA
 regulations In 40 CFR part 302 that ars
 related to today's final hazardous waste
  Isting. In particular. EPA is making final
 the designation as hazardoua substances
 Jnder CERCLA all of the wastes made
 final in today's rule and the final
 reportable quantities that would be
 applicable to those wastes.
                                       Maiifw1 (K°°m.2427) f08-305'' «"
                                       M street, SW.. Washington. DC 20480.
                                        The public must make an appointment
                                       by calling (202) 475-9327 to review
                                       docket materials. Refer to "Docket
                                       number F-89-CCAF-FFFFF" when
                                       making appointments to review my
                                       background documentation for this
                                       rulemaking. The public may copy a
                                       maximum of 100 pages of material from
                                       any one regulatory docket at no cost:
                                      additional copies cost $0.15 per page.
                                      Copies of the non-CBI version of th«
                                      listing background document Health
                                      and Environmental Effects Profiles
                                      (HEEPs). and not readily available
                                      references are available for viewing and
                                      copying only in the OSW docket Copies
                                      of materials relevant to the  CERCLA
                                      portions of this rulemaking are
                                      contained in Room 2427. U.S. EPA. 401
                                      M St.. SW.. Washington. DC 20480. The
                                      docket is available for inspection from
                                     9:00 a.m. to 4:00 p.m. Monday through
                                     Friday. As provided in 40 CFR part 2. a
                                     reasonable fee may be charged for
                                     copying services.
                                     %* SJU"?1 iMromtA-no* CONTACT:
                                     The RCRA/Superfund Hotline, at (800)
                                     424-9348 or at (202) 382-3000. For
                                     technical information, contact Mr. John
                                     Austin, y sting Section. Office of Solid
                                     Waste (OS-JJ33). .t  (202) 382-4789. For
                                     technical Information on the  CERCLA
                                     final rule, contact Ms. Ivette Vega.
                                     Response Standards and Criteria
                                    ff^ft — — —«, •*  t    •/ * **9\"J119V UIVIVK
                                    (OS-210). Both are available at US.
                                    Environmental Protection Agency. 401
                                           . Washington. DC 20480.
       •-*•****.«,»« wi9* 4 JIB UflUljJ
pA Hazardous Waste No. F025
becomes effective on June 11.1990; the
amended listing for EPA Hazardous
Waste No. F024 becomes effective June
11* 1990.
AotHWMtS: The RCRA docket is
located at the following address, and is
open from fi to 4, Monday through
Friday, excluding Federal holidays: EPA
  Outline
  I. Legal Authority
• U. Background
  m. Summary Of The Final Regulation
  IV. Response to Comment.
   A. Clarification of the Scope of the Listint
   a Applicability of Rule* to Wastes That
    Are Recycled
   n Ef0?0**1 to u»' Condensable Light Ends
   O. Evaluation of the Hazardous Properties
    of the Wastes
 V. Relation to Other Regulations
   A. Proposed Toxicity Characteristic
   "• Land Oispoial Reitrlctions
 VL Test Methods for Compounds Added to
    Appendices VII  and Vffl
 vn. Compounds Added to /
 VTIL CERCLA Designation.
    Quantities
                                             These regulations are being
                                           promulgated under the authority of
                                           sections 2002(a) and 3001 (b) and (e)(2)
                                           of the Solid Waste Disposal Act. as
                                           amended. 42 U.S.C. 6912(a) and 8921{b)
                                           and (e)(2) (commonly referred to as
                                           RCRA). and section I02(a) of the
                                           Comprehensive Environmental
                                           Response. Compensation, and Liability
                                           Act of 1980, 42 U.S.C. 9602(aJ.

                                           II. Background
    XMW**UUDV
IX State Authority
  A. Applicability of Rules in Authorized
    States
  a Effect on State Authorizations
X. Compliance Dates
  A. Notification
  a Permitting
XI. Regulatory Impact Analysis
XIL Regulatory Flexibility Act
Xin. Paperwork Reduction Act
    Pursuant to section 3001 of subtitle C
  of the Resource Conservation and
  Recovery Act (RCRA). this notice
  finalizes the listing of two generic
  categories of wastes generated during
  tilt manufacture of chlorinated aliphatic
  hydrocarbons as hazardous wastes. The
  following discussion provides a brief
  overview of regulatory actions affecting
  the wastes being finalized today.
    On August 22.1979 (44 FR 49402), the
  Agency proposed, among other things, to
  list as hazardous, by generic description
  a number of wastes generated from the
  production of chlorinated aliphatic
  hydrocarbons. On May 19.1980. EPA
  promulgated an interim final rule which
  listed as hazardous  a number of wastes
  from the production of specific
  chemicals within the general class of
  chlorinated aliphatic hydrocarbons:
  however, the generic listing was not
 promulgated at that  time (see 45 FR
 33064).
   Then, on February 10.1984 (see 49 FR
 5308-5315), the Agency, in two separate
 actions, proposed the listing of one
 generic category of waste and made an
 interim final listing of a second generic
 category of waste generated during the
 manufacture of chlorinated aliphatic
 hydrocarbons • by free radical
 catalyzed processes,  which have carbon
 chain lengths ranging from one  to and
 including five ("Cl-CS").* The category

  ' "Chlorinated aliphatic hydrocarbon." (alio
known is "chlorinated aliphatic.") refer, to a claw
oTariaiiic compound* "Hydrocarbona" are organic
compound, (molecule*) compoMd tolely of the
ato»a hjrdiusau and carbon. -Alinhai,^- de.ignate.
                                                                          Jfc-ThSSir0 ?!!iCf?0•
                                                                          J™g*' "J""* <* «"Pl« eovaleni (not aromatic)
                                                                          i^^ rl*c «"?'»«« hydrocarbon, ar. included
                                                                          to Ate claat.) "Chlorinated" mtana thai lome of the
                                                                          2'dn?"»_itom» -« *• "•liphalic hydrocarbon"
                                                                          Mve DMocotralcaily repUcad with chlorma aiomi
                                                                          •t one or more different poaiUow.
                                                                          . -_ "-"-«" uuonnaiM aliphatic hydrocarbon.
                                                                          •re not produced In lignificant quantity in the Lr S.
                                                                          "yneseneric chemical reaction process*.
                                                                          •dffl«B«el by diaae listing*. Second, and more
                                                                          Imjoruntlj. the higher molecular weight
                                                                              T?   paraffin manufacturing proce»ie.
                                                                          typteauy do not produce .ignificant amount, of
                                                                          organic re.iduala.

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           Federal Register / Vol. 54. No.  238 / Monday, December 11. 1989 /  Rules and Regulations
                                                                       50969
 o! wastes that became effective a»
 interim final regulations, and thus has
 been in effect as EPA Hazardous Waste
 No. F024 since August 10.1984. included
 distillation residues, heavy ends. tars.
 and reactor clean-out wastes (49 FR
 5308-5312). Today's notice provides the
 Agency's response to a number of
 comments that were received on the
 interim final rule. Only minor changes to
 the F024 listing are being made in
 response to these comments.
   The proposed listing included light
 ends, spent Filter and filter aids, and
 desiccant wastes (49 FR 5313-5315).
 With the  exception of light ends, today's
 notice finalizes the proposed listing of
 these residuals as EPA Hazardous
 Waste No. F02S. The category of light
 ends has  been narrowed in scope in this
 final rule to include only those light ends
 that have been condensed. These
 listings also do not include wastes from
 those processes that generate
 chlorinated aliphatic waste that EPA
 listed specifically in 198Q—namely EPA
 Hazardous Waste Nos. K018. K018,
 K019. K020. K028, K029. K030, K095. and
 K096.
  The basis for both of these actions
 was a determination by the Agency that
 the proposed and interim final
 wastestreams contained a wide range of
 potentially carcinogenic, mutagenic.
 teratogenic, or otherwise chronically or
 acutely toxic chlorinated and non-
 chlorinated organic compounds, which
 are listed  below:

 Table 1—Toxicants of Concern
 Chloromethane
 Dichloromethane
 Trichloromethane
 Carbon tetrachloride
 Chloroethylene
 l.l-Dichloroethane
 1,2-Dichloroethane
 trans-1.2-Dichloroethy!ene
 1,1-Dichloroethylene
 1,1,1-Trichloroethane
 1,1.2-Trichloroe thane
 Trichloroethylene
 1,1,1,2-Tetrachloroe thane
 1.1,2,2-Tetrachloroethane
Te trachloroe thy lene
 Pentachloroethane'
 Hexachloroe thane
3-Chloropropene
Epichlorohydrin
Dichloropropane
Dichloropropene
2-Chloro-1.3-butadiene
Hexachloro-l,3-butadiene
 Hexachlorocyclopentadiene
Benzene
 Chlorobenzene
 Dichlorobenzenes
 1.2,4-Trichlorobenzene
Tetrachlorobenzene
 Pentachloro benzene
 Hexachlorobenzene
 Toluene
 Naphthalene
   One or more of these toxicants are
 typically present in each waste a I
 significant concentrations, although
 each waste does not contain all of the
 individual toxic constituents of concern.
   The Agency originally inferred the
 presence of these toxicants from
 knowledge of free radical reaction
 chemistry and from manufacturing
 process conditions. In conjunction with
 this theoretical predictive methodology,
 the Agency obtained representative
 samples and confirmed the presence of
 these contaminants through chemical
 analysis. These hazardous constituents
 are mobile and persistent, and can reach
 environmental receptors in harmful
 concentrations if these wastes an
 mismanaged. (See the preambles to the
 interim final and proposed rules it 49 FR
 5308 and 9313 for • more detailed
 explanation of our basis for listing these
 wastes as hazardous.)
  On November 8,1984, the Hazardous
 and Solid Waste Amendments of 1984
 (HSWA) were enacted. These
 amendments had far-reaching
 ramifications for EPA's hazardous waste
 regulatory program. Section 3001(e)(2),
 which was ona of the many provisions
 added by HSWA, directed EPA to make
 a decision on whether or not to list
 under subsection (b)(l) several wastes,
 including chlorinated aliphatics. as
 hazardous. By finalizing these two
 chlorinated aliphatics waste listings, the
 Agency is fulfilling its mandate under
 section 3001(e)(2) of RCRA.*
  HSWA prohibits the land disposal of
 hazardous wastes. It also requires the
 Agency to set levels or methods of
 treatment that substantially diminish the
 toxicity of the waste or substantially
 reduce the likelihood of migration of
 hazardous constituents from the waste
 so that threats to human health and the
 environment are minimized. Wastes that
 meet the  treatment standards are not
 prohibited and may b« land disposed. A
 treatment standard is based on the
performance of the best demonstrated
 available technologies (BOAT) to treat
 the waste. For a waste identified or
listed after HSWA was enacted, the
Agency has six months to determine
 specific treatment standards which the
waste must achieve prior to land
disposal BOAT standards for waste
  9 Throughout the remainder of thi» notice, all
reference* to th* final listing of thtM two
chlorinated aliphatic* waitet mean th* final lilting
of wait* F024. which wa§ promulgated t* an interim
final rule, and the final listing of th* propoMd wait*
F023.
 F024 were promulgated on June 23.1989.
 In the Land Disposal Restrictions for the
 Third Third of Scheduled Wastes
 Proposed Rule, the Agency is proposing
 BOAT standards for waste F025.

 HI. Summary of the Final Regulation
   This regulation finalizes the listing as
 hazardous the following wastes
 generated from the production of
 chlorinated aliphatic hydrocarbons by
 free radical catalyzed processes, having
 a carbon content ranging from one to
 and including five, with varying
 amounts and positions of chlorine
. substitution:
   •  F024—Process wastes, including but
 not limited to, distillation residues.
 heavy ends. tars, and reactor clean-out
 wastes, from the production of certain
 chlorinated aliphatic hydrocarbons by
 free radical catalyzed processes. These
 chlorinated aliphatic hydrocarbons are
 those having carbon chain lengths
 ranging from one to and including five.
 with varying amounts of positions of
 chlorine substitution. (This listing does
 not include wastewaters, wastewater
 treatment sludges, spent catalysts, and
 wastes listed in  i 281.31 or i 261.32.)
   •  F025—Condensed light ends, spent
 filters and filter aids, and spent
 desiccant wastes from the production of
 certain chlorinated aliphatic
 hydrocarbons, by free radical catalyzed
 processes. These chlorinated aliphatic
 hydrocarbons are those having carbon
chain lengths ranging from one to and
including five, with varying amounts
and positions of chlorine substitution.
  The major commercial products
produced by the free radical catalyzed
chemical manufacturing processes of
C1-C5 chlorinated aliphatic
hydrocarbons (from which the listed
residual wastes are generated) irdude
but are not limited to the following
products:

Table 2—Major Commercial Products
Carbon tetrachloride
1-Chlorobutane (/7-Butyl chloride)
Chloroethane (Ethyl chloride)
Chloroform (Trichloromethane)
2-Chloro-1.3-butadiene (Chloroprene)
Chloromethane (Methyl chloride]
2-Chloro-2-methylpropane (/-Butyl
  chloride)
3-Chloro-2-methylpropene (Methallyl
  chloride)
3-Chloropropene (Allyl chloride)
Dichlorobutadiene
Dichlorobutenes
1,4-Dichlorobutyne
1,2-Dichloroethane (Ethylena dichloride)
Dichloromethane (Methyler.e dichloride)
1,2-Dichloropropane
1.3-Dichloropropene

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 50970   Federal Register / Vol. 54. No. 236  /  Monday. December 11. 1999 / Rules and  Regulations
 Hexachlorocydopentadiene
 Tclrachloroethylen* (Perchloroethylene)
 1.1,1-Tridrioroe thane
 1.1,2-TrlchIoroathane
 Trfchloroethylene (1.1.2-
   Trichloroethene)
 1.2,3-Trichloroproptnt
 1,2,3-Trichloropropene
 Vinyl chloride (Chloroethene)
 VInylldene chloride (1.1-Dichloroethene)
   EPA has evaluated the wastes
 generated from the production of these
 products against the criteria for listing
 hazardous wastes (40 CFR 261.11(a){3)),
 and has determined that they typically
 contain high concentrations of the
 constituents of concern listed in Table 1.
 that the toxicants on mobile and
 persistent in the environment thai these
 wastes have been mismanaged in the
 past, and that many of the toxicants in
 (he wastes are regulated by other EPA
 regulations, as well as by  regulations of
 other government agencies. The Agency,
 therefore, believes that these wastes are
 capable of posing a substantial present
 or potential threat to human health or
 the environment when improperly
 treated, stored, transported, disposed of.
 or otherwise managed, and thus are
 hazardous wastes.
  Additional information on the hazards
 of theie wastes and the toxicant
 constituents of these wastes may be
 found in the listing background
 document and the Health and
 Environmental Effects  Profiles, available
 as described in the "ADDRCSSES"
 section.
  With respect to the proposed listing of
 light ends, the Agency  also included a
 discussion of its authority under RCRA
 to regulate uncondensed and
uncontainerized gases, which are liquids
at standard temperature and pressure.
The notice did not propose that the light
ends must be condensed: however,
under the proposal the light ends would
have been subject to the applicable
regulations, even when they remain in
the gaseous state. Based on further
analysis, the Agency now  believes that
our authority under RCRA is limited to
 the regulation of only containerized or
condensed gases.
  The Agency also added  two
componunds, 2-chloro-1.3-butadiene
(chloroprene) and 3-chloropropene (allyl
chloride), to Appendix Vin of Part 281.
the list of hazardous constituents
identified by the Agency as exhibiting
toxic, carcinogenic, mutagenic, or
teratogenic effects on humans or other
life forms. (See 49 FR 5311, February 10,
19S4.)

IV. Response to Comments
  EPA received comments on all aspects
of the interim final and proposed
 regulations. The comments were
 submitted by generators of these wastes.
 an association which represents such
 generators, and public interest groups.
 The Agency has evaluated these
 comments carefully, and has modified
 the regulation, as well as the supporting
 documentation, as appropriate. This
 notice finalizes both the interim final
 and proposed regulations of February
 10,1984. This section presents some of
 the major comments as well as EPA's
 response to many of the comments
 received on both of these actions. In
 addition to material in this preamble.
 the Agency's response to these
 comments is also set forth in the revised
 listing background document available
 in the public docket for this rulemaking
 at EPA Headquarters—see
 "ADDRESSES" section.
A. Clarification of Scope of the Listing
  A number of commenters objected to
 the Agency listing these wastes as a
generic class. In particular, the following
comments were made:
  1. Before challenging the Agency's
substantive decisions, several
commenters argued that the Agency
lacks the legal authority to list wastes
genetically, citing the House Committee
Report which states "*  * * the
Administrator shall promulgate
regulations identifying and specifically
listing those hazardous wastes subject
to this title." (See H.R. Rep. No. 94-1491.
94th Cong.. 2nd Seas, at 50.) One
commenter, however, supported such an
approach, arguing that a waste-by-waste
listing would be very inefficient and
probably incomplete.
  EPA has no doubt as to the legality of
its authority to list wastes genetically,
and has already responded to such
challenges (see preamble to part 261.45
FR 33114. May 19,1980).
  2. A number of commenters expressed
concern that a generic listing would
create an inequitable situation for those
persons who generate a waste that
would be included in the generic class.
but which may not be hazardous.
  In reviewing the available data, the
Agency found in all instances that
wastes that would be included in the
listing description contained significant
levels of one or more of the hazardous
constituents of concern that would
cause die Agency to consider the waste
hazardous. In fact the Agency carefully
reviewed the various generic production
processes to ensure that no waste was
mistakenly included in the listing. As
discussed in the listing background
document, the concentrations of the
toxicants of concern were many orders
of magnitude above the levels
associated with human health concerns.
In addition, the solubilities of the
hazardous constituents of concern were
also many orders of magnitude above
the same levels. Thus, only a small
fraction of the hazardous constituents
present in the wastes need migrate and
reach environmental receptors to pose a
substantial hazard to human health and
the environment
  The Agency used these data in
combination with a methodology based
on free radical chemical mechanisms to
predict that significant concentrations of
toxicants would be present in all of the
wastes from these generic processes. In
no instance did the Agency receive any
comment refuting, or even questioning.
the validity of this predictive
methodology: nor was any analytical
data provided by the commenters that
would refute the listing. We, therefore.
disagree with the commenters. It ahould
be noted, however,  that if a person does
generate or manage a waste that
contains insignificant levels of the
various hazardous constituents (i.e.. that
person believes that the waste it
nonhazardous}, then the person may
petition the Agency to delist this waste
on a case-by-case basis. See 40 CFR
2OX20 and 260.22.
   3. Several commenters argued that an
efficient delisting procedure was not
available for the exclusion of wastes in
the generic class which do not have the
hazardous properties  for which they
were listed. They commented further
that even if an efficient procedure were
available, no guidance was available as
to the criteria, such as concentration
levels of hazardous constituents, used to
determine if a waste was no longer
hazardous.
  As discussed above, the Agency does
not believe that the wastes listed in
today's rule would,  without treatment.
qualify as nonhazardous.
Notwithstanding, the Agency
acknowledges that there were tome
historical problems with the delisting
program. Since 1984, these problems
have mostly been resolved at the staff
has gained experience with the program
and guidance has been developed (see
Petitions to Delist Hazardous Wastes: A
Guidance Manual April 1985. EPA/530-
SW-85-003) to assist the regulated
community in preparing delisting
petitions.
  4. Several commenters objected to
including in the listing description for
EPA Hazardous Waste No. F024 the
phrase "including but not limited to."
The commenters argued that the phrase
is ambiguous, overly broad, and in
conflict with the language from H.R.
Rep. No. 94-1491, which states that the
Agency should promulgate regulations

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                             / Vol. 54. No. 236 / Monday. December 11. 1988/  Rales and Regulations
                                                                       50£
 identifying aad specifically lilting
 wastes. In addition, the commenters
 claimed that no hazard criteria can be
 used in evaluating the waste if the
 waste is not even identified.
   The Agency disagrees with the-
 commenters. The listing is sufficiently
 specific. The listing description clearly
 states that all waste* from the subject
 process (except those that are
 specifically excluded) are covered by
 the listing; the process is identified
 unambiguously in both the Federal
 Register notice and in the listing
 background document (i.e., the support
 documentation provides a detailed
 description that explains the sources in
 the process from  which the wastes are
 generated). Likewise, we have carefully
 explained our basis for defining these
 wastes as hazardous—namely, that
 these wastes are  hazardous after
 considering the concentration of the
 toxicants in the waste, their propensity
 to migrate and persist as well as other
 relevant criteria in f 28141(a)(3). As
 discussed in the February 10.1984 rule.
 many of these toxicants also are
 bioaccumulative,  increasing the risk of
 exposure to higher levels of toxicants.
 The Agency has evaluated a large
 number of waste streams that contacted
 the raw materials, intermediates, or
 product streams. These wastes contain
 significant amounts of the hazardous
 constituents of concern. No commenters
 provided any data refuting this
 information. Also, as is discussed more
 fully in the background document any
 wastes generated from new or modified
 processes not discussed specifically in
 the background document are expected
 to generate wastes similar to F024. If
 wastes generated  by new or modified
 processes are significantly different
 then a generator may always submit a
 delisting petition to the delisting
 program. The Agency,  therefore,
perceives no general difficulties with
 including the phrase "including but not
limited to" in the listing description.
  5. One commenter believed that listing
all spent filters, filter aids, and
desiccants unduly penalized
manufacturers by  requiring RCRA
permits  when they decontaminate these
materials and return them to the
process. Another commenter argued that
wastes (La., spent desiccants, filters, or
filter aids) which do not come into
contact with or derive from the product
line (but which are derived from the
production process) should not be
included in the generic listings.
  With regard to the first point although
the Agency believes it important to
encourage the recycling of hazardous
waste, the Agency is guided by the
 principle in RCRA that the paramount
 and overriding statutory objective of
 RCRA is protection of human health and
 the environment The statutory policy of
 encouraging recycling is secondary and
 must give way if it is in conflict with the
 principal objective. See SO FR 618,
 January 4.1985. In addition, where
 Congress wished to further the recycling
 objective it said so explicitly. See RCRA
 section 3014 (recycled oil). Indeed, there
 have been a number of instances of
 environmental damage {/.&.
 groundwater contamination) caused by
 improper storage of hazardous wastes
 awaiting reclamation. See Appendix A
 at 50 FR 658 for a summary of damage
 incidents resulting from the recycling of
 hazardous wastes. It should be noted.
 however, that once the filters.
 desiccants. etc.. are reclaimed and
 returned to the process as usable
 products, these filters, desiccants. etc..
 are no longer considered wastes, and so
 are not subject to the RCRA subtitle C
 regulations. See 40 CFR 281.3(c)(2); see
 also 50 FR 634. January 4.1965. Permits
 are required for storage prior to
 reclamation. See 40 CFR 281.B(c).
  As to the other commenter'* point the
 Agency agrees that if a waste generated
 from the generic process does not come
 into contact with or derive from the
 product line (or any raw materials or
 wastes),  the waste should not be
 included in the listing description for
 waste FOZS. However, the Agency is not
 aware nor was any information
 provided by the commenter of how a
 waste, which is derived from the
 production process, would not come into
 contact with the raw materials,
 intermediates, or wastes.
  6. A number of commenters agreed
 with the Agency that wastewaters
 derived from these processes should not
 be included in the listing. (One
 commenter, however, argued that both
 wastewaters and the wastewater
 treatment sludges should be listed: see
 next comment for details.) The
 commenters believe that the wastewater
 exclusion would not function as such.
 however, since any de minimi's losses
 that leak or spill-from the process would
 be washed into the wastewater
 treatment system and would cause the
 wastewaters to be hazardous via the
 mixture rule. They, therefore,
 recommend that the listing be modified
 to specifically exclude those de minimi's
 losses that become mixed with the
 wastewaters.
  The Agency agrees with the
commenters that wastewaters and
wastewater treatment sludges should
not be listed (see 49 FR 5308, February
10,1964, for our basis on this
 determination): however, if waste F024
 and F02S is leaked or spilled and then
 washed into the wastewater treatment
 system, the Agency believes that the
 wastewater should be hazardous by the
 mixture rule. The Agency explained in a
 previous rulemaking its reasons for
 excluding and including within the
 hazardous waste system mixtures of
 certain listed wastes and solid wastes
 such as wastewaters (see 48 FR 56582.
 November 17.1981). In particular, in that
 rule, the Agency exempted from the
 mixture rule certain wastewater
 mixtures where the listed hazardous
 wastes will be present in such low
 concentrations that they do not pose a
 substantial hazard to human health or
 the environment and often will be
 treated in the plant's chemical,
 biological, or physical wastewater
 treatment system.
  The Agency believes that only the
 spent solvents (wastes F001-F005.) listed
 in f 28141, the commercial chemical
 products listed in f 261.33, and
 wastewaters resulting from laboratory
 operations (where the wastewater
 coming from the laboratory is a small
 percentage of flow into the wastewater
 treatment system) should be covered by
 the wastewater mixture exemption
 because they are seldom principal
 wastestreams and often are discharged
 in smell quantities into wastewaters as
 a practical way of managing them. On
 the other hand, the Agency believes that
 the other hazardous wastes listed in
 ! 261.31 (including the F024 and F025
 wastes being listed in this rulemaking)
 and those listed in I 261.32 typically are
 generated in large volumes relative to
 the non-hazardous wastewaters
 generated at the same plant and. if
 mixed with the wastewater. often
 constitute a significant portion of the
 wastewater mixture, thereby causing the
 mixture to pose a substantial hazard to
 human health or the environment.4
  Moreover, as the Agency noted in
 exempting mixtures of small quantities
 of spent solvents and wastewater from
 the mixture rule, it is not always
 possible to collect and segregate spent
 solvents. For example, small spills or
 incidental losses from various
 degreasing or maintenance operations
 around the plant are often difficult to
 prevent or control, even  where careful
  4 Sever*! of tha hazardous constituent! in wastes
F024 tod FIOS «rt also lilted spent solvents.
However. proc*u wssus (such a* FQ24 and fOCS]
when solvents were used as rescunti or
Ingredients In the formulation of commercial
caemicol products in not covered by the F001-FOOS
spent solvent Uatings (see SO FR S331S. December 31.
1965}. Thtrsfasv. (hi ousting waitewattr mi \;ure
exemption aoes not apply to these listed WQL'.C*.

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 50972    Federal  Renter / Vol. 54.  No. 236 / Monday. December 11. 1969 / Rules and  Reflations
 operating procedures are followed. Such
 small quantities of spent solvents
 sometimes drain or are washed into
 vvastewater sewer systems: in certain
 circumstances, it is also reasonable to
 discharge these small quantities into the
 nearest sewer connected to the
 wastewater treatment system. 46 FR at
 56584. In contrast. EPA believes that in a
 well-designed and managed
 manufacturing plant for chlorinated
 aliphatic hydrocarbons, it is not
 unreasonably difficult to prevent small
 amounts of wastes from leaking or
 spilling into the wastewater system.
 Unlike the widespread prevalence of
 spent solvents throughout the plant
 F024 and F025 wastes are principal
 waste streams and will be removed from
 discrete process units and confined and
 managed as hazardous wastes when
 this rule is finalized. For all these
 raasons. EPA believes that it would be
 unwise and unnecessary to  create an
 additional exemption to the mixture rule
 f.'-r mixtures of F024 and F025 wastes
 and wastewater.
  The regulated community may
 pMition for an exclusion of any
 hazardous waste mixture on a
 generator- or waste-specific basis
 (which would require representative
 tlata from the industry). At this time, the
 Agency does not have sufficient
 information to make such •  generic
 exclusion with the confidence that
 public health and the environment
 would still be protected; therefore, we
 firs not modifying the rules.  Another
 approach  that  the Agency is considering
 to address this situation is to establish
 ds minimis regulatory levels for
 hazardous constituents in listed
 hazardous waste, including hazardous
 waste mixtures and residues.
  7. One commenter stated that the
 Agency had sufficient data to list
 wastewater and wastewater treatment
 sludges at the time of the proposed and
 interim final rules. Such evidence was
 said to include ten damage cases from
 wastewater treatment lagoons described
 in the listing background document
  Although many incidents of
 •-antamination of ground water by
Chlorinated organic* have been
documented as a result of storing or
 treating wastewaters in unlined surface
 impoundments, the Agency has been
able to document only two incidents
which could be tied definitively to the
manufacture of C1-C5 chlorinated
 aliphatic hydrocarbons. The incidents
 cited by the commenter provide
 evidence of the migratory potential of
 the hazardous  constituents of concern in
 aqueous waste. However, the Agency
 does not have sufficient data at this time
 to characterize wastewater streams.
 which may be highly variable in regard
 to constituent concentrations. If the
 Agency obtains more data, it will be
 able to fully evaluate wastewaters and
 wastewater treatment sludges from
 these processes to determine if they
 should be listed. Notwithstanding the
 possibility of any such future
 determination, EPA believes that
 today's action satisfies the requirement
 in RCRA section 3001(e)(2) to make •
 determination of whether or not to list
 chlorinated aliphatic*. Any future
 listings would be pursuant to EPA'*
 general authority to list hazardous
 wastes under section 30Ol(b).
   S. One commenter believed that the
 listing of light ends would be redundant
 since most of the constituents of these
 waste* are currently regulated under
 S  261.33(0-
   The  commenter is apparently
 confused. The listing of commercial
 chemical products under | 28143(f) does
 not apply to process waste streams.
 Rather, these listings cover unused
 commercial chemical products, which
 become wastes when disposed or are
 intended for disposal. Commercial
 chemical product* consist of the pure
 grade of the chemical any technical
 grades of the chemical and all
 formulations in which the chemical is
 the sole active ingredient in a
 formulated product Listing under
 i 281.31 covers wastes that are
 generated during certain generic
 production processes, such as the
 manufacture of chlorinated aliphatic
 hydrocarbons. Thus, the listing of light
 ends in waste F02S would not be
 redundant with already listed wastes.
B. Applicability of Rules to Wastes That
are Recycled
  Several commenters pointed out that
 several of the wastes may be sold as
raw material* and, therefore, are not
wastes. By listing them, they believed
 that there would be an unwarranted
burden imposed on the sale of these
residuals, even if necessary permitting
and delisting procedures were complied
with, thus encouraging customers to buy
 other feedstocks. Several other
commenters requested that the Agency
refrain from listing these wastes until it
makes  final its recycle/reuse rules.
  The Agency agrees with the
commenters that in many cases light
ends from the manufacture of C1-C5
chlorinated aliphatic hydrocarbons are
products and are sold as such. However,
this is not always the case. If. in fact
light ends are sold a* products, then the
January 4.1985 definition of solid waste
regulations deal with the question of
which materials being recycled (or held
 for recycling) are solid and hazardous
 wastes. See SO FR 614. Among other
 things, the rule states that materials
 used or reused as an ingredient in an
 industrial process to make new products
 (provided the material* are not being
 reclaimed), or used or reused as
 effective substitutes for commercial
 products (again without being
 reclaimed), are not solid wastes. (See 40
 CFR 281.2(8). 50 FR 664. and also
 preamble discussion at 50 FR 837.) If
 these residue* (regardless of whether
 they are listed) are recycled in this
 manner, they are not considered solid
 waste* and therefore by definition are
 not hazardous wastes. See 40 CFR 261.3.
 However, these materials may still be
 solid and hazardous wastes if: (1) They
 are used/reused in a manner
 constituting disposal or used to produce
 products that are applied to the land: (2)
 they are burned for energy recovery or
 used to produce a fuel; (3) they are
 reclaimed: or (4) they are accumulated
 speculatively. See 40 CFR 261.2(e).
 (Since the recycle/reuse rules have
 already been promulgated, the second
 comment is moot.)

 C Proposal to List Condensable Light
 Ends

  Several commenters objected strongly
 to the Agency's proposal to list light
 end* which are in the gaseous state but
 condensable by currently feasible
 technology to liquids at ambient
 temperature and pressure. The following
 arguments were offered.
  Several commenters stated that the
 Agency  does not have authority under
 RCRA to regulate gaseous process
 emissions, since these are not solid
 wastes (i.e.. they are not "contained
gaseous material") as stated in the
definition of solid waste. See RCRA
section 1004(27). One commenter,
however, supported the Agency by
saying the proposal to regulate
condensable light ends does not reflect
in any way upon previous Agency policy
applicable to contained gaseous
materials, since these condensable light
ends are not gaseous materials in the
first place. Some commenters expressed
the opinion that circumvention of
regulation under RCRA by heating
wastes to the gaseous state could be
prevented by current permitting
procedures.
  Other commenters claimed that the
fact that the Agency had previously
listed light end* which were generated
in the gaseous state did not empower
the Agency to take similar action at a
later date. One commenter also stated
that the  reason the phthalic anhydride
listing of wastes K023 and K093 was not

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Federal
                              / Vo|. 54. No.  236 / Monday. December 11. 1999 / Rule, and Relation.
  questioned in 1980 was became, at that
  time, it was assumed that the listing
  only applied to the light end* in the
  condensed state. One cotmnenler further
  argued that the phthalic anhydride light
  ends listing was not analogous, since the
  phthalic anhydride light ends contained
  maleic anhydride and phthalic
  anhydride, which was emitted from the
  process as participates.
    In addition, commenters objected to
  regulation under RCRA of gaseous
  emissions for other reasons, including
  that permitting would have a significant
  economic impact: that there currently
  are no standards for flares (and
  subsequently, permitting would be
  difficult); that regulation of fugitive
  emissions of gaseous liquids from valves
  and pipes might follow regulation of
  gaseous light ends under RCRA: that
  condensation of light ends to ambient
  temperature could cause equipment
  corrosion: and that the Agency had not
  adequately characterized these gaseous
  emissions.
   In its proposal, the  Agency explained
  that it believed that the exclusion from
  RCRA of gaseous materials that are not
 contained applied only to "true gases"—
 namely, those which are not capable of
 beiag condensed and which remain
 gaseous at standard temperature and
 pressure. Our concern was that a plant
 could evade regulation by designing a
 process to keep the process emissions in
 a gaseous state. See 49 FR 5314,
 February 10.1984. Such a result could
 create human health and environmental
 concerns. For example, in the Bhopal
 incident a volatile liquid (methyl
 isocyanate) escaped confinement from a
 storage tank in a situation analogous to
 the storage of condensed light ends.
  Upon reconsideration of this issue
 (with the benefit of the comments
 received on the proposed rulemaJdng),
 EPA now believes our authority to
 identify or list a waste as hazardous
 under RCRA is limited to containerized
 or condensed gases (i.a.. section 1004(27)
 of RCRA excludes all other gases from
 the definition of solid wastes and thus
 cannot be considered hazardous
 wastes).*
turn* incinerator* {eoaUiaaa at U» nr«ambli to *&•
incineration regulation*) nnuln*4n •fiaet Sea 47
FR 27S30. June 24, iflSiPuuM incinerator* an
installed •• air pollution control derice* panaaat to
regulation* under thaOen Air AefctiMycreveed
to destroy «aMous«miuioa* 6m vaitoM
industrial pncejM*. £PAcooclu4«d *"', in
general RCRA standard* Jo not apply to turn*
incinerators because lbe Input («ii uumuuinemed
ga«) is not • •otWwiste acoordin to (be definition
«e« forth in | .281.2.
                               EPA. therefore, has decided not to
                             regulate these uncondensed light ends.
                             In the case of chlorinated aliphatic
                             hydrocarbon manufacture, the Agency
                             knows that manufacturers typically
                             employ condensation devices in
                             conjunction with distillation equipment
                             since the condensable fraction of these
                             emissions is either a valuable product or
                             recyclable feedstock material. If the
                             light ends are condensed and reused to
                             make new products or effective
                             substitutes for commercial products.
                             they will not be considered solid or
                             hazardous wastes, as long as they have
                             not been reclaimed and they do not
                             meet the criteria specified in i 28li(e).
                             See 50 FR 637. If every disposed (prior to
                             any such reuse),  however, these
                             condensed light ends would be
                             considered a solid waste and subject to
                             today's listing. Consequently, our
                             decision should not present an
                             environmental concern.
                              Although we agree with the
                            commenter that heating wastes to the
                            gaseous state is subject to regulation
                            under RCRA as treatment of hazardous
                            waste,  the Agency believes that  it
                            cannot use its current permitting
                            procedures to mandate the production
                            process design of a manufacturing
                            facility so that it generates a waste as e
                            liquid instead of (for example) installing
                            some internal heating mechanism that
                            generates the same liquid waste  in the
                            gaseous state. RCRA jurisdiction does
                            not provide tfais kind of control over
                            manufacturing processes. Of course.
                            thermal three taient after a material
                            becomes a hazardous waste is fully
                            regulated under RCRA.
                             The Agency also agrees with the
                            commenters that citing the phthalic
                            anhydride light ends bating raises •
                            substantial questions with respect to
                            establishing precedents. We have,
                            accordingly, deleted references to it in
                            the listing description and preamble.
                            D. Evaluation of the Hazardous
                            Properties of the Waste*

                             Other comments expressed specific
                            concerns with the Agency's evaluation
                            of the hazardous properties of the
                            wastes,  either through its toxicological
                            evaluations of individual hazardous
                            constituents, its projection of
                            concentration levels of constituents in
                            the wastes, or its analysis of the ability
                            of the constituents to migrate from the
                            wastes.
                             1. Two commenters stated that  some
                           of the conclusions reached by the.
                           Agency do not accurately reflect die
                           present state of knowledge of the
                           oncogenic properties of the constituents
                           in these  wastes. They commented that
  the Agency did not attempt to clarify the
  level of risk (of carcinogens) or to
  provide substantiation of its conclusions
  that the Carcinogen Assessment Croup
  (GAG) assessment documents on which
  the Agency relied are consistent with
  "current levels of knowledge and
  existing data": they also stated that the
  Agency should have used weight of
  evidence characterizations in its
  assessment of the potential hazards of
  these compounds. In particular, the
  commenters asserted that the Agency
  should not have judged constituents to
  be "potential human carcinogens" when
  the evidence for carcinogenicity for
  several of these chemicals would fall
  into "Group 3: chemicals * * * which
  *  * * cannot be classified as to their
  carcinogenicity to humans."
   The agency's judgment on  the
  potential carcinogenic and toxic effects
  resulting from continued low-level
  exposure to the constituents of concern
  are outlined in the Health and
  Environmental Effects Profiles for each
  constituent of concern. The major health
  concerns are summarized in the listing
  background document The commenter
 gave no specific criticism that EPA's
 facts do not "reflect the present state of
 knowledge," (other than that noted
 above) and did not  provide any
 additional data or other information to
 challenge the basis  for EPA's decision to
 list We are, therefore, unable to
 respond to this criticism. (It should be
 noted that the Agency has reviewed
 more recent studies addressing these
 constituents, and finds that this
 information corroborates the Agency's
 original decision to  list This information
 has been summarized and placed in the
 docket.)
   With respect to the "weight-of-
 evidence" argument, the Agency
 promulgated guidelines for carcinogenic
 risk (see 51 FR 32858. September 24.
 1988) which incorporates an assessment
 of the quality of experimental data for
 the overall hazard assessment for
 carcinogens. These guidelines specify
 the following five classifications:
 Croup A—Human carcinogen (sufficient
    evidence from epidemiologic studies)
 Group B Probable human carcinogen
  Croup Bi—Limited evidence of
    carcinogenicity In  human*
  Group &—A combination of sufficient
    evidence in animals and inadequate or
    no evidence in human*
 Group C—Possible human carcinogen
    (limited evidence of carcinogenicity in
    the absence of human data)
Group D—Not classifiable a* to human
    carcinogenicity (inadequate human and
    animal evidence of carcinogenicity or no
    data available)

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      50974
               ,                  «l testa in
               t »p«let or in both adequate
         epidemfologicind «nim«l ttudies).

     in rrn,m8rCy,?!8ards «8ents classified
     !?, Gro"P 'A or B as suitable for
     Sh-.- ivVtsk "»«w"«nt The
     suitability of Group C agents for
     quantitative risk assessment requires a
     case-by-case review because some
     Croup C agents do not have a data base
     of sufficient quality or quantity to
     perform a quantitative carcinogenicitv
     nsk assessment. The weight-of-evidence
     basis was used to eliminate Group D
    and E constituents from further
    consideration as carcinogens.
      Application of these guidelines shows
    that benzene and vinyl chloride are
    considered "carcinogenic to humans".
    the wefght of evidence for
   •iT  r  ii8   uuy iailini «nio class A. For
   the following hazardous constituents of
   concern, the weight of evidence for
   carcinogenicity is considered to fall into
   class B2. Thus, these compounds are
   considered to be probably carcinogenic
   to humans:
   Carbon tetrachloride
   \£M chloroa.lhan« (Elhylene dichloride)
   !£!!te"*«» (MWhyhne chloride)  '
   • nu tnvuiu* uuenzcno
   •"Jph4.rf.sxachlorocydohex.no
   Wnwia-Hexachlorocyclohexane
   T«'rachIoroethen«(PerchIoro8thyl6ne)
   Trichoro«thene(Trichloroethylene)
   Tnehloromslhane (Chloroform)

    The following constituents of concern
  are considered to be possible human
  carcinogens (class C):

  ?;!«ln' fvin>'li
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           Federal Register / VoL 54. No. 236 / Monday. December 11. 1989 / Rules  and Regulation*
                                                                     50977
 EPA's intention that the hazardous
 waste listings would continue to
 complement the TC Once promulgated.
 the TC might capture wastes generated
 by the chlorinated aliphatics industry
 that are not covered by wastes F024 or
 F02S. Such wastes could include
 wastewaters and wastewater treatment
 sludges.

 B. Land Disposal Restrictions
   HSWA mandated land disposal
 restrictions for wastes listed prior to the
 enactment of HSWA under a specific
 schedule (see 51 FR19300. May 28,
 1986). If the Agency failed to prohibit the
 wastes within the period specified, the
 wastes were restricted from land
 disposal. Waste F024, which was interim
 final effective August 10,1984. was
 included in the second third to be
 evaluated for land disposal restrictions.
 The final rule promulgating treatment
 standards for the second thirds wastes
 included treatment standards for waste
 F024 (see 54 FR 26594. June 23,1989).
  Although the Agency listed
 Hazardous Waste No. F024 under an
 interim final rule prior to the enactment
 of HSWA, the Agency nonetheless took
 comment on that action. Today's action
 responds to comments received on that
 interim final rulemaking and finalizes
 our determination under HSWA 3001(e)
 to list Hazardous Waste No. F024.
 Today's action on F024, which does not
 alter the listing or its substances, but
 only clarifies its description, does not
 alter the Agency's June 23,1989
 determination in regard to the land
 disposal restriction.
  Furthermore, HSWA also requires the
 Agency to make a land disposal
 prohibition determination for any
 hazardous waste that is newly identified
 or listed in 40 CFR part 281 after
 November 8,1984 within six months of
 the date of identification or listing
 (RCRA section 3004(g)(4), 42 U.S.C.
6924(g)(4)). In the Land Disposal
 Restrictions for the Third Third of
Scheduled Wastes Proposed Rule, the
Agency  is proposing a treatment
standard for Hazardous Waste No. F025.
VI. Test Methods for Compounds Added
to Appendices VII and Vm
  Most of the substances designated in
 this final rule as hazardous constituents
are currently listed in table 1 of
appendix III of 40 CFR part 281, which
designates the test methods that can be
used when characterizing wastes for the
purpose of delisting.
  On October 1.1984 (49 FR 38788). the
Agency proposed several changes to the
RCRA hazardous wastes regulations,
including the addition of new methods
to SW-846. After evaluating the
 comments, the Agency decided not to
 promulgate the October 1.1984 proposal.
 Instead, the Agency revised SW-840 to
 incorporate many of the suggestions
 made in the comments, which wen
 made available in the Third Edition of
 SW-848 (40 FR 8072. March 18,1987). On
 January 23.1989 (54 FR 3212). the
 Agency proposed, among other things.
 new and revised methods in the Third
 Edition of SW-848. the first update
 package to the Third Edition, and
 expansion of table 1 of Appendix III of
 40 CFR part 281. Once finalized, these
 methods may be used to determine
 whether a sample contains a given
 Appendix VII or VIII toxic constituent
 However, until the Third Edition of SW-
 846 is made final, the Second Edition as
 amended by Updates I and It and the 47
 methods that were finalized September
 29,1989 (54 FR 40280), remain as the
 approved methods for meeting
 regulatory requirements under substitle
 C of RCRA.
   These methods are in 'Test Methods
 for Evaluating Solid Waste: Physical/
 Chemical Methods." SW-846,3rd ed.,
 September, 1986, as amended: available
 from Superintendent of Documents,
 Government Printing Office,
 Washington. DC 20402. (202) 783-3238,
 Document No.: 955-001-00000-1.

 VTI.-Compounds Added to Appendix
 vm
  On February 10.1984 (49 FR 5311), the
 Agency made interim final the addition
 of two compounds. 2-chloro-l,3-
 butadiene (chloroprene) and 3-
 chloropropene (allyl chloride), to
 Appendix Vm of part 261. the list of
 hazardous constituents identified by the
 Agency as exhibiting toxic,
 carcinogenic, mutagenic, or teratogenic
 effects on humans or other life forms.
 These are two of the hazardous
 constituents for which wastes F024 and
 F025 are listed. No comments were
 received on this rule. Therefore, these
 two compounds will remain listed on
 Appendix VHL However, in a notice of
 technical corrections to § 261.33 and
Appendix Vffl (53 FR 13382. April 22.
 1988), the Agency inadvertently deleted
 allyl  chloride from Appendix VIII. In
 today's action, EPA is making a
 technical correction to once again
 include allyl chloride in Appendix VUL
Vlfl. CERCLA Designation and
 Reportable Quantities
  All listed hazardous wastes, as well
as any solid waste that meets one or
more of the characteristics of a
hazardous waste (as defined in 40 CFR
261.21 through 261.24), are hazardous
substances as defined at section 101(14)
of CERCLA. CERCLA hazardous
 substances are listed in Table 302.4 at 40
 CFR 302.4. along with their reportable
 quantities (RQs). CERCLA section 103(a)
 requires that persons in charge of
 vessels or facilities from which a
 hazardous substance has been released
 in a quantity that is equal to or greater
 than its RQ immediately notify the
 National Response Center of the release
 (at (800) 424-8802 or in the Washington.
 DC metropolitan area at (202) 428-2675).
 In addition, section 304 of the Superfund
 Amendments and Reauthorize tion Act
 of 1986 (SARA) requires the owner or
 operator of a facility to report the
 release of a hazardous substance to the
 appropriate State emergency response
 commission (SERC) and to the local
 emergency planning committee (LEPC)
 when the amount released equals or
 exceeds the RQ for the substance.
  According to the "mixture rule"
 developed in connection with the Clean
 Water Act section 311 regulations and
 also used for notification under
 CERCLA and SARA (50 FR 13463. April
 4,1985), the release of mixtures must be
 reported when the amount released
 equals or exceeds the RQ for the waste.
 unless the concentrations of the
 constituents of the waste are known.
 When the concentrations of the
 individual constituents of a hazardous
 waste are known, the release of the
 hazardous waste would need to be
 reported to the NRC and to the
 appropriate LEPC and SERC when the
 RQ of any of the hazardous constituents
 is equaled or exceeded. RQs of different
 hazardous substances are not additive
 under the mixture rule (except for
 radionuclides, see 54 FR 22536, May 24.
 1989), so that spilling a mixture
 containing half an RQ of one hazardous
 substance and half an RQ of another
 hazardous substance does not require a
 report
  On August 10.1984. the effective date
 of the interim final rule, waste stream
 F024 became a CERCLA hazardous
 substance with a  statutorily imposed
 one pound RQ. A one pound final
 adjusted RQ for waste stream F024 was
 promulgated on August 14.1989 (54 FR
 33426). As concerns F025. when today's
 rulemaking becomes effective, waste
 stream F025 will automatically become
 a CERCLA hazardous substance by
 virtue of its listing under RCRA. Under
 section 102(b) of CERCLA. a hazardous
 substance has a statutorily imposed RQ
 of one pound unless or until adjusted by
 regulation. In order to coordinate the
 RCRA and CERCLA rulemakmgs with
 respect to new waste  listings, the '
Agency today is adding waste F025 to 40
CFR 302.4. the codified list of CERCLA

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   50975
   hazantoes substances. and tain* iU
   9UtutorTRQofos»ioand,
   IX. State Authority

      Under section 300& of RCRA. EPA
    may authorize qualified State* to
    administer and enforce the RCRA
    program within the Stale. (See4OCFR
    port Zn for the standard* and
    requirement* for authorization.)
    Following authorization, EPA retains
    enforcement authority under section
    3008, 301X and 7003 of RCRA. allhouaji
    authorised State* have; primary   ^^
    enforcement responsibility.
    u,   ,  to *•**•*«*>«» «nd Solid
    Waste Amendments of 1864 (HSWAfc a
    State with final RCRA authorization
    administered it* authorized hazardous
    waste program in lieu of EPA. The
   Federal requirement* no longer applied
   in the authorized State, and EPA could
   not Issue permits for any facilities in the
   State that the State was authorized to
   permit When new, more stringent
   Federal requirement* were prosaufcated
   or enacUd. the Stats wa* obliged to
   enact equivalent authority within
   specified time frame*. New Federal
   requirements did not take effect fn an
   authorized State until the State adopted
   the requirement* aa State law.
    fff% r*rtntv«*4 •*«J__	**  	
                                          and that take effect in all States.
                                          regardless of their authorization state*.
                                          States may appty fa, eiAtr ^^^
                                          final aaJhonzation for lac HSWA
                                          provisions Identified to Tabte I. a*
                                                                     _ -
                                          these hazardous wastes that have
                                          previously Botifiad EPA or an authorized
                                          Stata ofhazardoBS wa*te activities and
                                          ha w received «• JdemiffcsMofi number.
                                         The Agetiejr beHeres that most, if not
                                         a». pewonswho manege these waste*
    B. Effect on Stale Authorization*

     PunuwUtoHSWA.today'areleis)
    immediately effective hi both authorized
    and non-authorized States. EPA wiH
    implement the rale hi authorized Slates.
    until they modify their program to^
    reflect these Federal •tandardiiand 0»
   modification is approved by EPA.        7i" I£^w"*^* a""B aa Iater maa Marc
   Beca«»* the rale is nromalxafa*?          *? 2^££S£S£thrilleB P«rroant to
   puraaant to Ih. HSWAVstST          Z%*S™«***' Notification
   "lonurans: a pragram modification may
                                                                              h»        11        wmer an
                                                                             therefore will not have to re-notify.
                                                                             However, any penon who generates.
                                                                              ransport*. treat*, ttores. or disposes of
                                                                             lh«« wwtes that ha. not pnvio^ty
                                                                             notified and received an identification
                                                                             number, that person must notify EPA or
                                                                             an authorized State no later than March
                                                     ery. on the barf of
                                       regulation* that an nbstsnliatty
                                       equfvalent or fully eqvtv.tem to EPA'*.
                                       The procedure* and schedule for Stale
     . 42 U.S.C. 8028fgJ, ne»r
requirement* and prohibitions
  f%,  .      «        **"C\»i ui fluulon2Vi
   »"*,** ™ game tfnw mat *ey take
  effort in non-authorized State*. EPA is
  directed to implement these
  requirement* and prohibition* in
  authorized States-, inchidmg the issuance
  of permits, until the State modifies ft*
  program to reflect the Federal standard*
  and applfe* for and is granted
  authorization.
   As noted above, both F024 and F02S
  waste* are li*ted today pursuant to
 suction 3001(e)(2J of HSWA. ZninaDv
 F034 w*« listed pursuant to RCRA on aa
 Interim final basis. Howsver. on
 November a. 1984. Congreas.^uctsd
 HSWA. which amended RCRA. Among
 other thing*, these amendments require
 EPA to decide whether or net to bat
 chlorinated aliphatic* as hazardous
 waste* under HSWA (see section
 300l(eK2tf. Therefore, toe Agaacy is
 finalizing the FQZ4 Bating; as  wefl a* Ida
 F02S Hating, under HSWA. Thisfinal
 rulemaking does not change the
 substance or the effective date f Atoms*
 10.19S4J of the F024 interim finsTrul./
 Therefore, today's rule has been added
 !? T^e * I0 * 2"-50X **** identifies
 the Federal program requirements that
are promulgated pursuant to the HSWA,
  .. S?l1*"1 ^-^^K2) reqafres that
  States that haw* final RCRA
  authorization smi modify tfw^.
  program* to reflect Federal program
  changes end most •ubseooently nborit
  Uie modification to EPA for approval
  State program modification*, lot the F029
  waste* must be made by Jury 1. 1991, if
  only regulatory change* are necesaary.
  or Jury t M9Z: if •tatntory changes are
  necessary. These deadKnas caabc
  extended (see f 27I.21(eJf9n:
   State, with final RCRA artftorfestkm
  were required to adept the FBM hsnac
  in accordsHcewitn 1 2nja(ejf2>. Sim
  £d£! fiMl Hstin« ""^ "* HSWAfar
 the F024 waste* make* no «*stanti«
 changes from the interim final Hatfrig.
                                     uterus* wmsres nave already been
                                     approved need not further revise its
                                     program or submit additional change* as
                                     HSW   m                * 1U
                                     nawA. Rather, any sach nreviou*rv
                                     approved State will be deemed^

                                                     '
A. Notification

  Under the Solid Waste Oispeeal
Amendment* of i960, (Pub, L 98-4521
    Wa* 8lveit fte °tfon  ground water monitoring ami
                                     financial responsibility requirements, [f

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            Federal Register / Vol. 54. No. 236 /  Monday. December 11. 1969 / Rules  and Regulations
                                                                                   50977
 the facility fails to do so. interim status
 will terminate on that date.
   All existing hazardous waste
 management facilities (as defined in 40
 CFR 270.2) that treat, store, or dispose of
 F024 and F025 and that are currently
 operating pursuant to interim status
 under section 3005(e) of RCRA. must file
 with EPA an amended part A permit
 application by June 11.1990. in
 accordance with f 270.72(a).
   Under current regulations, a
 hazardous waste management facility
 that has received a permit pursuant to
 section 3005 is not able to treat, store, or
 dispose of F024 or F025 when the rule
 becomes effective on June 11.1990. until
 a permit modification allowing such
 activity has occurred in accordance with
 S 270.42(g). Note that EPA has recently
 amended  the permit modification
 procedures for newly listed or identified
 wastes. For more details on the permit
 modification procedures, see 53 FR
 37912 etseq. (September 28.1988).

 XL Regulatory Impact Analysis
  Under Executive Order  12291. EPA
 must determine whether a regulation is
 "major" and. therefore, subject to the
 requirement of a Regulatory Impact
 Analysis. The total additional incurred
 cost for disposal of the wastes added by
 this rule, is less than $38,000,  well under
 the $100 million constituting a major
 regulation. This insignificant cost is
 partly due to the  fact that  waste F024
 has been regulated as hazardous since
 1984 and therefore there should be no
 additional cost to comply with this rule.
 The cost for waste F025 results from
 minimal compliance requirements as
 these wastes are  being handled as if
 they were  hazardous (primarily due to
 their containing similar toxic
constituents as F024) by most of the
generators, who have interim status or
part B permits. These generators will
incur minimal increased costs for permit
modifications, chemical analysis, and
recordkeeping. This cost is much less
                                        than the estimated cost of SIS million
                                        stated in the proposed rule. This cost
                                        was based on conservative assumptions
                                        including that these wastes would be
                                        managed for the first time as hazardous.
                                          Since EPA does not expect that the
                                        amendments promulgated here will have
                                        an annual effect on the economy of $100
                                        million or more, result in a measurable
                                        increase in cost or prices, or have an
                                        adverse impact on the ability of U.S.-
                                        based enterprises to compete in either
                                        domestic or foreign markets, these
                                        amendments are not considered to
                                        constitute a major action. As such, a
                                        Regulatory Impact Analysis is not
                                        required.
                                           Regulatory Flexibility Act
                                         Pursuant to the Regulatory Flexibility
                                       Act 5 U.S.C sections 601-612. whenever
                                       an agency is required to publish a
                                       general notice of rulemaking for any
                                       proposed or final rule, it must prepare
                                       and make available for public comment
                                       a regulatory flexibility analysis that
                                       describes the impact of the rule on small
                                       entities (i.e.. small businesses, small
                                       organizations, and small governmental
                                       jurisdictions). No regulatory flexibility
                                       analysis is required, however, if the
                                       head of the agency certifies that the rule
                                       will not have a significant economic
                                       impact on a substantial number of small
                                       entities.
                                         The hazardous wastes listed here are
                                       not generated by small entities (as
                                       defined by the Regulatory Flexibility
                                       Act), and the Agency received no
                                       comments that small entities will
                                       dispose of them in significant quantities.
                                       Accordingly. I hereby certify that this
                                       regulation will not have a significant
                                       economic impact on a substantial
                                       number of small entities. This
                                       regulation, therefore, does not require a
                                       regulatory flexibility analysis.
                                       XHL Paperwork Reduction Act
                                        This rule does not contain any
                                       information collection requirements
                                                      subject to OMB review under the
                                                      Paperwork Reduction Act of 1980. 44
                                                      U.S.C. 3501 et aeq.

                                                      List of Subjects

                                                      40CFR Part 281

                                                       Hazardous materials. Waste
                                                      treatment and disposal. Recycling.

                                                      40 CFR Part 271

                                                       Administrative practice and
                                                      procedure. Confidential business
                                                      information. Hazardous materials
                                                      transportation. Hazardous waste. Indian
                                                      lands. Intergovernmental relations.
                                                     Penalties, Reporting and recordkeeping
                                                     requirements, Water pollution control.
                                                     Water supply.

                                                     40 CFR Part 3O2

                                                       Air pollution control. Chemicals.
                                                     Hazardous materials. Hazardous
                                                     materials transportation/Hazardous
                                                     substances. Intergovernmental relations.
                                                     Natural resources. Nuclear materials.
                                                     Pesticides and pests. Radioactive
                                                     materials. Reporting and recordkeeping
                                                     requirements, Superfund. Waste
                                                     treatment and disposal, Water pollution
                                                     control.
                                                       Dated: November 29,1989.
                                                     William ICKailly.
                                                     Adihiniitntor.
                                                       For the reasons set out in the
                                                     preamble, title 40 of the Code of Federal
                                                     Regulations is amended as follows:

                                                     PART 261—IDENTIFICATION AND
                                                     LISTING OF HAZARDOUS WASTE

                                                       1. The authority citation for part 261
                                                     continues to read as follows:
                                                      Authority: 42 U.S.C. 6905. 6912(a). 6921.
                                                     6922, and 6938.

                                                     {261.31  [Amended]
                                                      2. In S 281.31. revise the listing
                                                     description for EPA hazardous waste
                                                     No. F024 to read as follows:
   Industry and EPA
  nazardom wast* No.
                                                      Hoaidoua
                                                                                                        Hazard cod*
F024
WSMM. induing but not hnitad to. dMMMn nwduM.
                      «*"«* hydmcarton. b
                                                                         tart, and reactor
                                                                                                  from
                                                                      *rom
                                                  « 1261.31 or 1 281.32.).
  3. In } 261.31, add" the following waste
stream:

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 50978    Federal Resbter / Vol. 54. No. 235 / Momfcy.  December «. 1989 / Rufes and Regulations
              NO.
 F02S                "•• ' ' ....... * *l" — — 1 — ' "— ' —••'—-'•'•—• T - "nfcrrt num Irim ti> ualm Hi ur mMi Uilu.lmJ CD
                     •'["•I'll T—-mtTrt hr ' — •~*~*  ' T  ' fTrm TtaM cWrtMMrt iiptntr tiydMcMton •» lu
                           ct«*l fcngft* raogina tan on» to  vrt inducing tM. •«» wyng wnountt «M pe^Hoot 
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            Federal Register / Vol. 54. No. 236 /  Monday. December  11. 1969 /  Rules and  Regulations    50979
                          TABLE 302.4.—LIST OF HAZARDOUS SUBSTANCES AND REPORTABIE QUANTITIES
Hazardous substance
F02S
Condensed Kght ends, spam Mars and Mar aide.
and spent deaiccant waataa from the producton of

priatic nydrocarbona are those having carbon
chain lengths rangng from one to and indudng
five, wrtri varying aniounta and positions of chto*
rine substitution.
CASRN






Salutary
RO
•1
Code-
4
HCRA
No.
F02S
Final RO
Category
X
Pounds (kg)
"1(0.454)
• Indicates the statutory sourca aa defined by 4 below.
1 Indicates that the statutory source for designation of this Kazan*
                                                           ubatanca undar CERCtA to CWA sactton 311(bK4).
    »indicata* that tha statutory sourca for designation of into hazardous substance undar CE9CIA to CWA aactton »7
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