Wednesday
 November 14, 1990
Part VI


Environmental

Protection Agency

Department of Energy Waste Isolation
Pilot Plant; Notice of Final No-Migration
Determination
               Printed on Recycled Paper

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 47709       > "Federal 'Register  /  Vol. 55.  No.220* /  Wednesday/Noveniber  14, 1990 / Notices  '
 ENVIRONMENTAL PROTECTION
 AGENCY

 tFRL-3860-1]

 Conditional No-Migration
 Determination for the Department of
 Energy Waste Isolation Pilot Plant
 (WIPP)

 AGENCY: Environmental Protection
t Agency.
 ACTION: Notice of final no-migration
 determination.

 SUMMARY: In response to a petition from
 the Department of Energy (DOE), the
 Environmental Protection Agency (EPA)
 is today making a determination of no
 migration for placement of hazardous
 waste at DOE's Waste Isolation Pilot
 Plant (WIPP), located near Carlsbad,
 New Mexico. Today's determination
 imposes several conditions on such
 placement and is for a maximum often
 years. As a result of this determination,
 DOE may place a limited amount of
 untreated hazardous waste subject to
 the land disposal restrictions of the
 Resource Conservation and Recovery
 Act (RCRA) in the WIPP for the  •
 purposes of testing and experimentation.
 DOE submitted a petition to EPA for a
 no-migration determination iri March
 1989; EPA proposed to grant the petition
 in April 1990. After a careful review of
 public comments on the proposal, EPA
 has concluded that DOE has
 demonstrated, to a reasonable degree of
 certainty, that hazardous constituents
 will not migrate from the WIPP disposal
 unit during the testing period proposed  .
 by DOE, and that DOE has otherwise
 met the requirements of 40 CFR 268.6 for
 the WIPJP. The approved petition  •
 requires DOE to remove the hazardous
 wastes from the underground repository;
 if it cannot demonstrate the long-term
 acceptability of the disposal site by the
 end of the test period.
 EFFECTIVE DATE: November 14,1990.
 ADDRESSES: The public docket for this
 determination is available for public
 inspection in Room M2427, U.S..
 Environmental Protection Agency, 401M
  Street SW, Washington, DC, 20400,
 Monday through Friday, excluding
  Federal holidays. Members of-the public-
  may make an appointment; to review
  docket materials by calling (202) 475-
  9327. Copies of docket materials may be
• made at no cost, with a maximum of 100
  pages of material from any one
  regulatory docket, Additional copies .are.
  $0.15 per page.
  FOR FURTHER INFORMATION CONTACT:
  General questions about the regulatory
  requirements under RCRA should be
  directed to the RCRA/Superfund Hotline
.at 800^24-9346 (toll free) or 202-382-
 3000 (local). V'"   '•-'          ;       :
   Specifi&questions about the issues-
 discussed in this notice should be   .
 directed to Matthew Hale, Office of
 Solid Waste (OS-341), U.S. .
 Environmental Protection Agency,.401M
 Street SW, Washington, DC 20460, at
 202-382-4746.          .    ,  .:•';,...
 SUPPLEMENTARY INFORMATION: "

 Preamble Outline •                  '  '  .
 I. Background  ,             .        • -..'
   A. RCRA Land Disposal Restrictions
   B. Regulatory Status of Mixed Waste •
   C. WIPP Project       '•         -  '  -
   D. Regulatory Status of the WIPP
 II. DOE Petition jand EPA Proposed
     Determination             ''.''.•'
 HI. Summary of EPA Determination
 IV. Discussion of EPA Determination and
   .  Conditions Of Determination  ".'•''.-.
   A. No-Migratibn Finding     /•''
   B. Conditions pf Determination ;    •'   '
   1. Limitation to Testing and  '.',,•
     Experimentation         '••"'*...,.
   2. Limitation on Volume       ' >.'.
   3. Waste Retrieval         r     .    •.
   4. Waste Retrievability
   5^ Carbon Ads.orption Device   •    .
   6. Air Monitoring Plan        ; '      .  ;
   7. Waste Analysis
   8.-Reporting Requirements           .  '-*•
 V. Discussion-of Majorlssues    ' ,.-••••:•
   A. Appropriateness of "Exemption" for •  ,
     DOE  -   .;">'••             '.'v  '
   B. Timing of EPA Decision
   C. Scope of Determination
   D. EPA Oversight over the Test Phase
   E. Site Suitability   ;             .
   P. Conditional Determination
 •  G. Definition {>f No Migration  .
  ;. H. Definition t?f-Unjt:JBdundary       ;
:  • I. Waste Characterisation      :    *••''•'•
'  J. RetrievabilitJ L          '   •
   , K. Human Intrusion
, VI. Conditions, of No-Migration.       ,
     Determination     -        • ,

 •I.-Background-      •

 A. RCRA Land Disposal.Restrictions ,/.

   The Hazardous and Solid Waste - .* i
 Amendments j(HSWA) of 1984, which  .
  amend the Resource Conservation and
 Recovery Act (RCRA), imposed    •,;
  substantial He"w requirements on the
  land disposal,of hazardous waste. In'  '•.;
  particular, the amendments prohibit ;the
  continued land disposal of hazardous
  wastes, unless either (1) the wastes, meet
 . treatment standards specified by EPA,
  or (2) the Administrator determines that
  the prohibition is not required in order -
  to protect human health and-the       » •
  environment. [This latter determination
  must be based on a demonstration by
  the owner/op'erator of the facility    ,  .
  receiving the [waste "that there-will be
  no migration bf hazardous constituents
  from the disposal unit or injection zone'- ••
  as long as the wastes remain -,.   ...'-.:-
  hazardous." {RCRA sections 3004(d)(l),
 (e)(l), and (g)(5),) The Department of
 Energy (DOE) has chosen to comply
 With the land disposal restrictions for
 certain transuranic (TRU) wastes to be
 shipped for testing and-experimentation
 ;at its Waste Isolation Pilot Plant (WJPP)
 by pursuing the second option.. Today's
 notice approves, with conditions, DOE's
 petition for the WIPP site.
   EPA first promulgated standards and
 procedures for review of no-migration
.petitions under 40 GFR 268.6 in
 November 1986. These regulations^
 ; which apply to land disposal units other ...
 .than underground injection wells, codify
 the statutory standard-for no-migration
 '.findings, specify the information
 required in no-migration petitions, and
 .establish"EPA's procedures  for
 "approving of denying petitions
 (November 7,1986, 51 FR 40572). EPA
; .amended these regulations on August
 17,1988 (53 FR 31138) to add further
 procedural requirements and
 standards.* EPA is now developing
 additional no-migration standards to
 •clarify or expand on certain parts of the
 current regulations. The Agency expects
•'-to propose these standards-in the near
 future. In conjunction with this proposal,
' EPA has also developed draft no-
 migration guidance, a copy  of which is
.' available in the docket for this
 rulemakirig.       •                   .
   To date, EPA has received 31 no-
 . migration petitions submitted in
 accordance with 40 CFR 268.6. Today's
 notice, which addresses disposal of
 mixed radioactive and hazardous waste
 in a mined -salt bed, is the Agency's first
 decision on any of these petitions under
 § 268.6. The other § 268.6 petitions,    ;
 which primarily address land treatment
'•'-' operations," are currently under Agency
 • review. In addition, EPA has received
 approximately 65 no-migration petitions
 for underground injection wells under 40
•" CFR part 148. Of these, 30 have been
 'approved, 26 are still under review, and
 a number of others have been
 .withdrawn.

 -.•B. Regulatory Status of Mixed Wastes

 '  -Tjie hazardous wastes that are subject
  to today's notice are "mixed wastes."
 Mixed wastes are defined as a mixture
 of hazardous wastes regulated under  .'
 ' Subtitle C of RCRA and radioactive
'  w&stes regulated under the Atomic
  Energy Act (AEA). Because section 1004
  of RCRA excludes "source," "special
  nuclear," and "byproduct materials," as
  defined under the Atomic Energy Act,
    ?QnJu)y26,1988, EPA also promulgated .
  standards under 40 CFR part 148 for no-migration
 " determinations for underground injecti6n wells (53
 .FR 28122).     - -   •           .'-.-•

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                  Federal Register / Vol. 55, No.  220 / Wednesday, November 14,  1990 /Notices
   from the definition of RCRA "solid
   waste," there has been some confusion
   in the past as to the scope of EPA's
   authority over mixed waste under
   RCRA. EPA clarified this question in a
   Federal Register notice on July 3,1986.
    EPA's clarification stated that the -
   section 1004 exclusion applies only to
   the radioactive portion of mixed waste,
   not to the hazardous constituents.  -
   Therefore, a mixture of "source,"
"*  "special nuclear," or "byproduct
   materials" and  a RCRA hazardous
   waste must be managed as a hazardous
   waste, subject to the requirements of
  RCRA subtitle C (that is, RCRA
  standards for the management of
  hazardous waste). EPA's oversight
  under RCRA, however, extends only to
  the hazardous waste components of the
  mixed waste, not to the source, special
  nuclear, or byproduct materials
  themselves. The exempted radionuclides
  are instead addressed under the AEA.2
  DOE subsequently confirmed and
  clarified this interpretation in the
  Federal Register on May 1,1987.
  Sections I.D and V.A of this notice
  further discusses the relationship
  between the. AEA standards and the no-
  migration finding.
   EPA's July 3,1986 interpretation went
  into effect immediately in states not
  authorized to administer the RCRA
 hazardous waste program—that is, in
 the ten states and territories where EPA
 directly regulates hazardous waste
 under the Federal RCRA regulations. At
 the same time, the July 3,1986 notice
 informed authorized states that they
 were required to apply for and receive
 authorization from EPA to regulate
 mixed waste under RCRA. To date,
 twenty-three states and territories
 (including New Mexico, where the WIPP
 is located) have obtained authority to
 regulate mixed waste under the state
 RCRA hazardous waste programs. Thus,
 mixed wastes are currently regulated as
 hazardous under Federal RCRA
 requirements in thirty-three states and
 territories.                     ...

 C. WIPP Project       .        _ •

   Today's notice'addresses mixed
waste that DOE intends to ship for
testing and experimentation to the WIPP
site near Carlsbad, New Mexico, during
a preliminary test phase. At the site, the
waste will be placed in a mined
underground repository, located in a salt
bed approximately 2,150 feet below the

  2 This interpretation, however, does not preclude
EPA from requiring data on radionuclide content of
wastes where necessary to carry out EPA's
authorities under RCRA—for example, to ensure
protection of personnel carrying out RCRA
inspection or oversight sampling.
   earth's surface. Over an approximately
   five-year period, DOE plans to test and
   evaluate the behavior of the waste in
   the repository, as well as the
   characteristics of the surrounding
   formation, to determine the site's
   acceptability for the long-term disposal
   of radioactive waste. Today's no-  .
   migration determination requires DOE
   to remove the waste from the repository
   if the site proves to be unacceptable for
   long-term disposal.
    Over the long-term, the WIPP
   repository has been designed as a
   permanent disposal site for transuranic
   (TRU) radioactive wastes resulting from
  nuclear weapons production at ten DOE
  sites around the country.3 TRU wastes
  are defined as wastes contaminated
  with alpha-emitting radio'nuclides with
  an atomic number greater than 92 (that
  is, heavier than uranium) hi
  concentrations of greater than 100
  nanocuries per gram of waste. In
  addition, TRU wastes by definition have
  half-lives of more than twenty years,
  although the actual half-lives of
  radionuclides in waste to be placed in
  the WIPP are often hundreds or
  thousands of years. The TRU wastes
  targeted for the WIPP consist of a
  variety of materials, including tools,
  equipment, protective clothing, rags,
  graphite, glass, and other material
  contaminated during the production and
  reprocessing of plutonium; contaminated
  organic and inorganic sludges;
  contaminated process and laboratory
  wastes; and contaminated items from
  decontamination and decommissioning
  activities at DOE facilities. As TRU
 wastes, these wastes are distinguished
 from high-level radioactive waste, such
 as used reactor fuel, and low-level
 radioactive waste. Other disposal
 strategies are being developed for high-
 level and low-level radioactive wastes.
   The land in the area of the WIPP is
 owned by the Federal  government and
 administered by the Bureau of Land
 Management. The four-mile by four-mile
 plot of land overlying the repository has
 been temporarily withdrawn from public
 use by the Department of Interior; it is
 now under the control of DOE. Before
 DOE can bring waste to the site,
 however, either Congress or the
 Department of Interior must take new
  3 The DOE facilities that intend to send TRU
waste to the WIPP are Idaho National Engineering
Laboratory, Idaho Falls, Idaho; Rocky Flats Plant,
Golden, Colorado; Los Alamos National Laboratory,
Los Alamos, New Mexico; Argonne National
Laboratory, Argonne Illinois; Savannah River Plant,
Aiken, South Carolina; Oak Ridge National
Laboratory, Oak Ridge, Tennessee; Hanford
Reservation, Richland, Washington; Mound Plant,
Miamisburg, Ohio; Lawrence Livermore Natidnal
Laboratory, Livermore, California; and Nevada Test
Site, Mercury, Nevada.
   land withdrawal action. The repository
   is designed to hold TRU wastes that are
   currently stored at the DOE generating
   facilities, as well as new TRU wastes
   that will be generated over the next 25
   years. The underground waste disposal
   area of the WIPP, when completed, will
   cover 100 acres, with a total design
   capacity of 6.45 million cubic feet (or
   approximately 850,000 drums of waste).
  To date, 15 acres of underground
   disposal rooms have been mined.
  -  Although DOE has conducted
  extensive studies of the WIPP site and
  the repository performance,
  uncertainties still remain. For example,
  concerns have been raised over the
  possibility that gas generated
  underground at the WIPP could, over the
  long term, build up to unacceptable
  pressures, leading to possible releases
  from the repository. To address this and
  other questions, DOE plans  to conduct
  testing and experimentation over the
  next several years. This testing will
  include in-situ experiments with actual
  TRU wastes underground, as well as
  other investigations. These in-situ tests
  would initially involve wastes
  amounting to approximately 0.5 percent
  of the total repository capacity. From
  these tests, DOE hopes to gather data
  that will allow it to'demonstrate
  compliance  with EPA's'standards'for
  disposal of radioactive materials (40
  CFR part 191 subpart B) and long-term
  no-migration of RCRA hazardous
  constituents, as well as in identifying
  any engineering modifications that may
  be necessary to meet these standards.
  DOE is also  considering the need for an
  "operations  demonstration" during the
 test period. The purpose of this
 demonstration, which might involve up
 to an additional three to eight percent of
 the total WIPP capacity, would be to
 show DOE's operational readiness to
 ship waste to the WIPP and to place it
 underground. (Today's approval does
 not cover placement of wastes for the
 purposes of the "operations
 demonstration." DOE would have to
 submit for EPA's consideration an
 amendment to its no-migration petition;
 any EPA decision on such an
 amendment would be proposed in the
 Federal Register, with opportunity for
 public comment.)
   As a condition to today's approved
 petition, DOE must remove all     .
 hazardous wastes from the repository if
 it is unable to meet EPA standards for
 permanent disposal of hazardous and
 radioactive wastes at the conclusion of
 the test period.4 However, if the WIPP
  * Under 40 CFR 268.6(a)(S), petitioners seeking a
no-migration demonstration must provide sufficient
                               Continued

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47702
                Federal Register  /Vol. 55. No. 220
proves acceptable as a permanent    ;
repository, and if DOE successfully
petitions EPA for a long-term no-
migration determination, DOE will then
be able to begin full-scale disposal of
waste at the site; Drums, metal boxes,
and metal canisters of waste will be
snipped to the WIPP from the generating
sites and placed in underground rooms.
Under current plans, the rooms will be
backfilled with crushed salt and sealed.
After an operating period of
approximately 25 years, DOE plans to
seal the shafts of the mine with cement-
clay plugs and compacted salt and
decommission the facility. After
decommissioning, the salt of the Salado
Formation will creep inward and is
expected to encapsulate the waste
within 60 to 200 years,
  Access to the WIPP site will be
restricted. The Department of Interior
temporarily withdrew the lands on the
WIPP site from public use in 1983,
allowing DOE to begin construction of
the facility. Before DOE can bring waste
to the site, however, either Congress or
the Department of Interior must take
new land withdrawal action. In
addition, DOE and the State of New
Mexico have agreed to prohibit in
perpetuity all subsurface mining,
drilling, and resource exploration
unrelated to the WIPP project at the
WIPP site. As a further protection, the
Federal government has acquired the
entire surface and subsurface estate at
the WIPP site. Finally, to discourage
drilling in the vicinity of the repository
in the distant future, DOE intends to
place permanent warning markers at the
site.
D. Regulatory Status of the WIPP
   The WIPP is located in the State of
New Mexico, which received
 authorization for mixed waste on July
 25,1990. (See 55 FR 28397, July 11,1990.)
 As an "existing" hazardous waste
 management facility at the time of New
 Mexico's authorization for mixed waste,
 the WIPP is eligible for RCRA interim
 status. Facilities "in existence" (which
 include facilities under construction) at
 the time a waste is identified as  •
 hazardous under RCRA can obtain
 interim status if their owner/operators
 submit a part A application to EPA or
 the appropriate state. If DOE submits an'
 application to New Mexico and secures
 interim status, it will be legally
 authorized to receive mixed Waste at the
 Information to assure the Administrator that the
 disposal unit will comply with other applicable
 Federal. Stale, and local laws. Therefore, if the
 WIPP cannot comply with radioactive disposal
 standards undcr-40 CFR part 191. it would not
 satisfy the conditions for a long-term no-migration
 dolcrmimilion.
                                       WIPP—subject of course to the land
                                       disposal restrictions. The WIPP must
                                       also comply with the1 RCRA interim
                                       status standards, codified at 40 CFR part
                                       265, and eventually obtain a RCRA
                                       permit under'40 CFR parts 264 and 270.
                                         The interim status requirements of
                                       part 265 establish general facility
                                       standards! For example, the WIPP is
                                       required under these standards to have
                                       a waste analysis plafr for its mixed
                                       waste, a contingency plan describing
                                       procedures that DOE will take in the
                                       case of an emergency, and a closure
                                       plan describing how the facility will be
                                       closed. In addition, the State of New
                                       Mexico has recently'requested that DOE
                                       submit 'to it the RCRA partB permit'
                                       application for the WIPP; this
                                       application must be submitted no later
                                       than six months after the State's
                                       request, or by February 28,1991. The
                                       RCRA permit for the WIPP (if granted)
                                       will establish detailed operating,
                                       closure, arid post-closure conditions in
                                       accordance with 40 CFR part 264,
                                       subpart X. (As a geological repository,
                                       the WIPP is regulated under the RCRA
                                       category of subpart JX "miscellaneous
                                       units.") The permit's scope would
                                       extend to all facility! activities related to
                                       mixed waste.      ;
                                          Several commenters on EPA's
                                       proposed decision oh the WIPP
                                       expressed confusion over the
                                       relationship between a no-migration
                                        decision by EPA and a RCRA permit
                                       issued by the State. In explanation, EPA
                                       notes that its no-migration
                                        determination is relatively narrow in
                                        scope, only addressing the question of
                                        whether hazardous Constituents will or
                                        will not migrate from the underground
                                        repository. To ensure no-migration,
                                        EPA's determination imposes certain
                                        conditions (e.g., a volume limitation and
                                        retrievability of waite); these conditions
                                        will be enforced by EPA. On the other
                                        hand, the State  RCRA permit is
                                        significantly broader than a no-
                                        migralion finding, since it will impose
                                        the full technical arid general facility
                                        standards of 40 CFR part  264, and it will
                                        apply to the above-ground operations as
                                        well as operations Underground. The
                                        permit may include certain requirements
                                        already imposed under EPA's  no-
                                       . migration determination, or it may
                                        establish more stringent requirements, if
                                        the State of New Mexico  determines
                                        that they are necessary. The State
                                        permit will be issued under State
                                        procedures, which include public notice,
                                        comment, and an opportunity  for a
                                        public hearing.  The!conditions of the
                                        permit will be enforced by the State.
                                           As discussed earlier, EPA's authority
                                        under RCRA over waste destined for the
WIPP extends only to mixed hazardous ,
and radioactive waste, and it is further
limited to the hazardous components of
the mixed waste. The potential release
of radioactive material from the WIPP is
addressed under the Atomic Energy Act
(AEA). EPA has promulgated standards
under the AEA limiting releases
associated with the disposal of
radioactive wastes. These standards,
which are codified at 40 CFR part 191,
consist of two parts: Subpart A dealing
with releases during the operational
phase of a permanent disposal facility,
and subpart B, dealing with long-term  ;
releases after decommissioning. Under
these regulations, a facility is not
defined as a disposal site until it has
been designated as a permanent
resposjtory and removal is not
contemplated; since this decision will
not be made for the WIPP until after the
test phase, the WIPP is not legally
subject to the part 191 standards. Under
an agreement with the State of New
Mexico, however, DOE has agreed to
comply with the subpart A standards,
beginning with the initial receipt of
waste at the WIPP—that is, before the
facility has been designated as a
permanent repository. The subpart
standards also do not yet apply to the
WIPP because they have been remanded
to'EPA by the U.S. Court of Appeals at
the First Circuit, and therefore are not in
effect at this time. DOE, however, has
agreed with the State of New Mexico to
demonstrate compliance with the
remanded standards (if final standards
have not been developed) before a final
decision is made to dispose of waste
permanently in the repository. This
 decision will be made on the basis of
 data gathered during the test phase at
 the WIPP.
   Finally, EPA emphasizes that today's
 finding addresses only the specific
 question of whether hazardous
 constituents will or will not migrate
 from the WIPP as long as the waste
 remains hazardous. Issues raised by the
 transportation of waste to the WIPP site,
 or by handling and possible treatment of
' waste before it reaches the WIPP, are
 beyond the scope of EPA's legal
 authority in evaluating no-migration
 petitions, and thus are not addressed in
 this notice.
 II. DOE Petition and EPA Proposed
 Determination

   The mixed waste DOE intends to ship
 to the WIPP for testing includes solvent-
 contaminated wastes, which became
 subject to the land disposal restrictions
 on November"8,1986, and characteristic
 wastes (containing heavy metals such as
 lead), which became subject to the land

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Federal Register f
                                          55, No. 22O /  Wediiesday* Movembep 14,. MSI
disposal restriction® on August &i 1890^.
(However, It' should be noted that EPA
granted a two>-yeaF national capacity.'
variance to mixed1 eharaeferis.tis wastes.
deferring'the effective date-of the
disposal prohibitionnratil; May  8i.iaS2
{June 1,1S90,55 FR 22520).); In addition,
some mixed wastes are likely to include
wastes that are hazardous under EPAx'a
new toxieity characteristics rule (;5& FR
11798^ although the- Agency has not yet
promulgated fend disposal1' restrictions
for these waste?.
  To- comply withr the fond disposal
restrictions, DOE has sought to
demonstrate to EPA, in a non^nigration
petition submitted in March 1989! that
placement of these wastes untreated5 in
the WIPP repository will not lead to
migration of hazardous constituents
beyond the disposal unit boundary-., fit  .
response to EPA concerns, DOE
provided additional supporting material.
after its initial submission,, including
addenda in October 1989 and January
1990. DOE's final petition was bound
into eight volumes in March, 1S9Q |DOE/
WIPP 88-003, Revision 1} and is,
included in. the docket for this
rulemakingi.
  After careful review of DOE's petition
as well as information from; numerous
other sources, EPA proposed in the
Federal Register of April S, 1990 to grant
DOE's petition with eertate conditions.
(See 55 FR 13668 for a more detailed1
discussion of the information provided
by  DOE and of the basis for EP&'s
proposed decision.) Under EPA'a
proposal, DOE would be allowed; to
place untreated mixed, waste in. the-.   -
WIPP repository within- the scope of the
testing aad experimentation activities •
described in the petition^ EPA's; proposal
would not have allowed' DOET to coiwfc.ct
its  proposed operations demonstration,
nor would it have aHawed DOE, to-
•ctiuduet two pilot-room tests, which had
originally been; suggested bjp EPA, if the
testing failed to show thai the WIPP
could meet the no-migration; standard's:
for; the loEgterm, disposal a£ mixed; ,.  , ,
waste, DOE would be- required t&.'"  .
remove the waste from the underground;
repository. The proposal also included
the following conditions: £1} The waste
must be placed to the- WIPP tat a   .
retrievabtefoBmt |2J DOE must provide
annual written reports on the test phase-
progress! to EPA;, £$! a carbow absorption,
device capable of achievtog,a 9-5 per.eeB*
efficiency, must be installed ia  the
discharge system of the bin experiment
rooms; f4)j BOB-must implement a .
specific air. monitoring plan; {5J0QE
must certify, thai it has. seeurest control
of the sarfaee and subsurface estate at.
the.-WIPP site-before wastes ears- be
                        placed in t&e repository;. <* and f6f during
                        the test phase, DOE: must provide-
                        detailed waste characterization and  .
                        analyses on the waste emplaced in the
                        WIPP.
                          EPA provided'a-SO-day public
                       •comment period on-its proposed       :
                        determf nation and held' pubKc hearings
                        in Carlsbad, Albuqqerqtte, and Santa Fe,
                        New Mexico, during the comment
                        period'. The Agency received 103 written
                        comments GIT its proposal from both1
                        individuals' and organizations, and more
                        than 300 people testified at the three
                        hearings. Today's decision is based on a-
                        carefuJreviewofthe public's comments;
                        and clarifying: information provided by
                        DOE, as well as EPA's further
                        evaluation of the suitability of tfte site
                        based on a field visit to foe WWP site on
                        July28,199&.                   •  '-
                        IJL Summatg of EPA. Detersninatiott
                          After a review of DOE's- petition,
                        supporting informatibn; and publie •
                        coroiaent,. EPA finds that DOE has
                        demonstrated! to-a reasonable degree of
                        certainty, that hazardous constituents
                        will not migrate- front the WIPP
                        repository as a result of its planned test
                        activities, as required by.the statute and'
                        regulations at 40 CFR 268ift This
                        determination is based on the condition;
                        that DOE only place hazardous waste-
                        within' the scope of the test phase
                        operations described' in its no-migratioB
                        petition and its performance assessment
                        test pfan. Consistent with the
                        determination, EPA i» approving DOE's
                        no-migration petition for Use WIPP for
                        the test phase operations, subject iff the-
                        conditions laid out irc section-. VT of this
                        notice; H should be noted1 that tifte
                        proposed operations'demonstration and'
                        pilot roora tests--cannot be coHducted:
                        under the terms- of today's decision.
                       . Before these activities eoufd'be carried5
                        out, DOE xvouFd1 have to submit an •   ' '
                        amendment to its no-migration petifion,.
                        which EPA would evaluate; EPA would:
                        then propose- a decision for comment.
                        before a final decision would be made.  '..
                          'EPA's action today allows DOE to-
                        place untreated' mixed waste subject ta
                        the RCRA land disposal resMctions in
                       ^ the WIPP for testing and?
                        experimentation to determine whether1
                        the site is appropriate for the fong-term;
                        disposal of mixed waste (that is,,
                        whether disposal at the site wiE:  .
                        conform with standards- for t&e '
                        permanent disposal of hazardous.
                        wastes); Only the waste specified by
                        DO&ia is petition may be placed in the
WlPPuwier ti&fis determfriatioa.8'TBte
quastity/ 0f waste Slat may be piacerf in
the WIPPia BmJted1 to 8v50G dhimsv ort
percent of tfte facility's SnaF capacity/.
DOE may not begin permanent disposal
of the mixed waste subject to the RCRA
land disposal: prohibitions at the site
and must remove att waste from the
underground repository if it cannot
demonstrate no migration of hazardoas
constituents esrerthe long terro. pas
additros to ERA^s Eeqairemen* that
hazardoua ,v/aste be removed from, the
respositary, DOE has also committed tot
carry out such a removal in a; consent
agreement with-the State of New
Mexfco.J
  In iBakiHy its no-migration finding;
EPA Goncentnafed ow whether, release*
of non-radioactive hazardous:
constituents fronr the repository mfgh*
occur during: the test phase, to doing sot
EPA addressed afI possible routes of
release, bat focused in particular on tfte
potential for volatile organic
constituents.released during testing to
migrateeut of the WEPP umtftroagfetfee
ventilation exhaust shaft. Because of'the
nature of fee tests-that will be
conducted to the WJPP and their..
relatively short duratioiii EPA has:
concluded that releases of hazardous  -
constituents from the unit through brine,
salt, or other geological media ;a
implausible during the test phase.
  The ratrievability of waste placed in
the WIPP during the test phase is; centrait
to EPA's finding. TheEefojEe».EKft,haa
reviewed bo& fee technical feasibility
of retrieval and the praetlcabihty of
DOB's-retrieval pfasLEPAhasi •-' ;
concluded, fea* retrieval of wastes i;om
the WIPP cans be accomplished safely4
and that DOE's commitsneat to
retrieving; the wastes and taking: it
above ground,, if it proves necessary, is
satisfactory^ Finally^ EPA considered tost
general design, construction* aad mine
maintenanee program at the WIPP and;
has concluded that the mine is well-
designed and will remain stable daring
  8 In its no-migta lion petition, DOE Mfentified
listed saJvenfa anti EP'iExtractraH Procedure):
characteristic wastea as hazardous, under RGRA, in
addition, some of the waste described1 fii DOES
petition- may now be hazardous under the EPA'ff
recentljt premnlg»(ed 'Eoxicity Gharacteristies. PEC]
rule (55 FR 11798), El'A has not i^tppomulfiated .
treatment standards fotTC wastes;, however, it ia
                          ? DOE re«:RSly secured the.ksLou!9!aBding:
                        nline^a^Eease afthe WlPFsilfe, thereby satisfyfhg
                        this condition-. Affa- rastiJIv.^^ has-eliminate^tfeia
                        coniJHfoin In. its feiaMetermioa'acm:
standards-have been proroulgatBd,TG waatea   .
piaead in tha. WIPP wiil be subject tuthe.biMl,
disposal restrictions. Because EPA.'a review, of  .
DOE's petition considered* potentiat migration- of
hazarrfpus constttwents from at! of ttie- waste DOE
identified aaschedateditur the WIPR.todajf'ffaa- ,
migratior. determination applies ta wastes thataf*
hazardoiia. under the TC rule, as weli as, solvents:
and EPofiaractertsttcs- wastes, a» tong as the waste*
were included in the petition.

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 47704
•Federal Register / Vol. 55, No. 220 ./Wednesday. November 14, 1990  /Notices
 the test period and well beyond..The
 specific conditions of today's finding are
 discussed in the following section and
 listed in summary form in section VI of
 this notice.
   Although EPA's granting of DOE's
 petition is specifically based on a
 finding of no-migration of hazardous
 constituents from the unit during the test
 phase, EPA has thoroughly reviewed
 available information'on the expected
 long-term performance of the WIPP
 repository. Given the geological stability
 of the area; the depth, thickness, and
 very low permeability of the salt
 formation in which the repository has
 been mined; and the properties of rock
 salt as an encapsulating medium, EPA
 believes that the WIPP is a promising
 site for the permanent disposal of mixed
 waste. To be sure, a number of
 uncertainties related to the long-term
 performance of the WIPP remain—for
 example, the extent  and effects of gas
' generation, the. effects  of brine inflow
 into the repository, and the influence of
 a "disturbed rock zone" around the
 mined repository. DOE will be
 Investigating these uncertainties in the
 test phase at the WIPP, and it will
 review whether technical modifications
 to the repository design or the waste are
 necessary to ensure compliance with the
 regulatory standards.
   It should be remembered that today's
 decision is only for the disposal of
 mixed waste during the test phase for
 testing and experimentation to
 determine whether the site is
 appropriate for the long-term, disposal of
 mixed wastes. Before DOE may move
 from the test phase to full-scale
 operations, it must petition EPA again
 and demonstrate no migration over the
 long term—that is, it must successfully
 address current uncertainties about
 long-term WIPP performance.
 Information gathered by DOE during the
 test phase will be central to such a
 demonstration. Any EPA decision to
 approve (or deny) a no-migration
 petition for permanent disposal at the
 conclusion of the test phase will be
 made with full opportunity for public
 comment, as prescribed in 40 CFR
 268.6{g).
   Further technical details regarding
 EPA's final decision are provided in a ' •
 background document. In addition,
 major issues raised by public
 commenters are discussed in section V
 of today's notice, as well as in a
 response to comments document. Both
 the background document and the
 response to comments document-are
 available in the public docket for this
 action.
                        IVr Discussion of EPA Determination
                        and Conditions of Determination
                        A No-Migration Finding
                          To make a no-migration
                        determination, sections 3004 (d)(l),
                        (e)(l), and (g){5) of RCRA require EPA to
                        find that "there will be no migration of
                        hazardous constituents from the
                        disposal unit or injection zone as long as
                        the wastes remain hazardous." As EPA
                        explained in the preamble to its
                        proposed decision, it interprets this
                        requirement to mean that constituents
                        listed in appendix VIII of 40 CFR part
                        261 cannot migrate at hazardous levels
                        from the disposal unit during the time.
                        that hazardous waste is present in the
                        unit. If the hazardous waste Within the
                        unit becomes non-hazardous or if it is
                        removed from the unit, further migration
                        from the unit ceases to be an issue. In
                        the case of the WIPP, DOE will have to
                        remove all hazardous waste from the
                        underground repository if it cannot
                        demonstrate the long-term acceptability
                        of the site; therefore, the effective period
                        of EPA's finding is the test phase. Thus,
                        EPA's decision today is based on the
                        conclusion that the Appendix VIII
                        constituents will not migrate at
                        hazardous levels from the underground
                        repository during the test phase and that
                        DOE will remove all hazardous waste
                        from the unit if testing cannot show that
                        the site meets long-term no-migration
                        standards.
                           EPA's no-migration finding for the
                        WIPP test phase.falls into several
                        categories: Migration of hazardous
                        constituents under anticipated test
                        conditions in the repository; short-term
                        stability of the repository; feasibility of
                       . retrieval; possible effect of accidents
                        and spills; and effectiveness of controls
                        against human intrusion during the test
                        phase. These aspects of EPA's
                        determination are discussed below.
                          '. No migration of hazardous
                        'constituents beyond the unit boundary.
                        In the proposal, EPA explained in some
                        detail its definition of the unit boundary
                        for the WIPP'and its standards for
                        determining whether, a constituent
                        migrating from the unit is "hazardous." •
                        The proposed unit boundary was the
                        Salado Formation at the WIPP site,
                        bounded by the four-mile by four-mile
                        land withdrawaji area,  except that, for
                        'air emissions during operations, the unit
                        boundary was the point where the air
                         exhaust ventilation shaft met the
                         surface. EPA's  definition of the unit
                         boundary in today's decision is largely
                         unchanged from the proposal; however,
                         in response to public comment, it has
                         slightly modified the unit definition  as it
                         applies to air emissions. In the final
                         decision, the unjt referes to that portion
of the Salado Formation that falls within
the WIPP land withdrawal area:
specifically, any movement of
constituents above "hazardous" levels
into overlying or underlying formations,
or beyond the lateral boundaries of the
land withdrawal area would constitute
migration. This unit boundary would
apply to migration via air emissions
during operations as well as via ground
water of other routes after closure of the
unit. (This issue is discussed in more
detail in section V.H of today's notice.)
EPA's definition of "hazardous" levels
of migration remains unchanged from
the proposal. As. discussed below in
section V.G, EPA  is relying on "health-
based levels" to define migration—that
is, levels that would be hazardous to a
person exposed at the unit boundary for
an entire lifetime.
  The no-migration standard applies to
all possible routes of release from the
unit. EPA, however, has concluded that
migration of hazardous constituents out
of the unit during the test period is
implausible by any route other than air.
Waste will be containerized during the
test period, and even if it were released
from a container, there is no possibility
that waste could migrate from the unit
by ground water or directly through the
salt rock within the test period. No
commenters questioned this conclusion,
which EPA discussed in the proposal.
  Potential for Migration via Air
Emissions. For air emissions during the
test period, EPA's finding is based on a
careful review of possible releases from
the bin-scale and alcove-tests DOE is
planning to conduct during the test
period. For reasons described below,
EPA has concluded that any releases
from  the alcove-scale tests will be
negligible. Therefore, it has focused its .
attention on the bin-scale tests. In these
tests, headspace gases will be vented  '
into the bin discharge system whenever
the bins become pressurized through a •
pressure relief valve installed on each
bin. The gases will then be passed on to
the exhaust shaft. Because the purpose
 of the experiments is to gather data on '
 the gas generation potential for the  •
various types of wastes intended for
 disposal at the WIPP, the rate of gas
 generation and thus the amount of
 hazardous constituents expected to be:
 released can only be estimated- Because
 of this uncertainty, DOE has proposed
 and EPA's decision today requires the
 inclusion of a carbon canister in the bin
 gas discharge system to remove any
 volatile organic constituents released
 from the .bins. This carbon adsorption
 control device must be designed to
 achieve a control .efficiency of at least
 95 percent. As  explained in its proposal,

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Federal Register f
      Nte-...2aa /'
                                                                  , fe-vember
                                                                                            ffefes.
EPA has taken this- eonteot device Htfo
  air emissions^
    For its as
  coneesfratiosB-ofi'gdktsle oj^aaier
  con
  at DOE'is Rocky Flats Bask arafc stored
  at the I^aba> National1 Engjaeezisg:     •
  Laborafesj;. As dessm&edi.Bfc &e WJFP
  able: t& pmvide- little er »a icfapniatiea
  oasas  "
  contra! naeasaEessfer these data.
  Therefope^ EPA views the anal^tieat
  being semfesuantitati.ife, Nevertheless,,
  even if these data undeEestiraate. tha  ,
  constituent CQiussntratians % as, muck .
  as. an, order of magnitude,, tEe
  noncentrattQa o£ eonstitueuta at the unit
  boundary are stiE expected to be belaw
  heaMt-&ased;levefe,           •
    The" results of EE&'a assessment aJK
 ' showoi in Tidfe 1 beSam along, wit&,
  levelsairegaMorj? eoiiGeyou     ,   ..'-.'.
 ,  EPA eaasasvatrweljt assumed that
 both
 24(t EPA. tfeesa3si:m«d -aa. average gaa
. geHBJcatfQn.Eate?a£5,m6le&pei cfruza-per;
 year» a figmse tBat EKJEe&aracteiaizes, aa
 represeafiHg. tB.e ^ipec bouiai of tie-
 range of erexfif>re gas. generation rates-
                                    '
 Waste. Tests; January 19865, S/SNffa^-
 0462J: Eacft bm ssn heltf t&e eqni^aleaft
 ,of six .drum vqlinnesiaf waste.  '. ••'. '""".•
 Therefore; EKJE's; upper fionnd* ^s
 g^ne^ati^^f^:: rate- is erpinsafenf te a' total
 gas geHeratjoir rate frwn- aH24a
 experfiHentaP 6ms afoiff caMcr meters
 per day. BOFftas- specifier? tlie general
 veirtstettesr pate tfifs^te ftsr pe^esRoiy
 as 4^09QSG^we fee* permrasfe,. wisiefc
. is eqaJvafeBttetTmiffisiyeniifenieteFa
 per day. "ffijseirf&e- w^ame rfairf*
 exhsasteJ a*aie»e!»&»u»esftali.awf fis
 .available to mfeeiwiftaRy gases-'refease
 from tlie bin- dfee&arge- systeRr. TRe-
 resuftfesy offirtien- faeferat ffie e*6ansf
                                                                               arid.rockfeffi darfi^^ ratfeettesf pfr
                                                                                                             for
                                                     Pi teeafetrfate Ae
                                                                               inspected while thef tests arenndeiwayi
                                          .„ __ _  	r^   e peart ceSeehtrafons;
                                        (with the carbes adsorption contra!
                                       sev«* efders 0f magaiftsde; feefowr aay
                                       other level dE'iegHlatery eoaeenr. TE
                                       figure* fepiesefrf fee bfer-scafe tests-
                                       alone; howesrer,
                                                                             wiBrstew &&wie foef'tate ef Creep' GP
                                                                             FinaHjfv D€)l'inteBdfeipfflrtlcrf% tebac
                                                                             seejrsE afee^c* voSr cra^etf salt to- •
                                      .                    t           .
                                      provided5 date to- shew ;ffia*e«Bn whe»
                                       testafeeyes wSlfeeffKetf wiffi
                                       off' walls- Between' ibeliscftfiB'- antd1 tifte-
                                      • romee wsdfe,. sw ^feat twsm- Gfoanre- does?
                                       nof Hnpfege- COT jflte- feacfeffiTetf' drums'.
                                       These modifiiBalSiEHis-easare^fte  •   '  '
                                       suceessfel ratpfeval of t&e dram^ &DRI  •
                                       the alcoves, at tfee coRefiisfenv of tfte test
                                            i. ifft pFOTfe
                                                                        ,
                                      tSw con eerrtraf Ions &*• fte «»dteasf- shaft
                                      weriSf be1 two1 to- ef^ft eidteEs- of
                                                                                        expressed* concern tfeaf
                                       feaastlfe,
                                               e&efew^BB-teveisroFregQfefery   IPAeaaaof asstraieirenKroaPfeiitSH«FT
                                      coraeefBr.           ....           •    •   mfgratipir finding^ "Eltese coanaenters
                                        Because.the alcove; experiments        	"
                                        the' exhaust shaft front tSft £Sbeve fcm» •
                                                -ff fiactorof 'a* feas* fiiree- to
                                        than" this wiee1 t&e afeoAfFestaie- sesfeitf af
                                        the start of the>.exper&BeRfe,
                                          EPA reeognfees1 Aa8 ffier aeftiaf &6r gas
                                                                             of the tesf afco#es
                                                                             removal — an rssaedisEiissediin the •
                                                                             prevfsHKseetftrre. FfBa^t^Sieg argued*
                                                                             that reftieval fronr bacRfiHed alcoves
                                                                             has not been- dfemonstEatetf anj tftat
                                                                                                            '
moles* per draai per-yeiK: HfoWever; even
if t&era*e-wer«rs%nificairtfyMgfier,
                           sdai'y  -'
                                                                             underground during retrfevaF.ma^ have
                                                                             inlterent.Trstcs'. •        ?•- ••   *   . "
                                                                               HRff has eoncfuafetf titeet POE"a Wkste
                                                                             Retrieval; Ptan^ ito eontfnWaSfoni wlthf
                                                                             mock reMevafc; demonstrates fftat     :
                                                                      for
                                      95 pejee&f 'eiltcierrey', ifierefbrei EKS.   '
                                      findmft^ D0E'&*s' efeHKHissfratedl'to a
                                      F&astwia&fe disgree of eertamtj,;,t!tat
                                      hazardous- eons^Beirt* wiff noi* m^afe
                                      beyoratf; ffierrepos jtoty batrndkr^1
                                      the
                                      tongten»,,salterBepwfiCb6
                                                              e site. Bi tfie:
                                                                         ,
                                       ntajiBr aspect^ of theretriessal procesa
                                       are addressed in tfte plaA, including-  -,
                                       radiofegfeaE andtftazardbiis w-asfe
                                       cdnfaminatBstf eontoF,. dhinr anrfbfn
                                       handffng; overpaeRiDg;proced\iresibr  .
                                       corrode^ ortJama^d'drumsi.Greaft HP/ of
                                       centamftiatibHi.andlback^retrfevaJ'.
                                       Whife refease orfea&age of hazardous . .
                                       eoristftuents ftom eoHtaiheKS.wi0fii:ffie;'
                                                                             ce
                                      In the short femr, Roweves; saR? creep —
                                      which can lead te localized feaetnrihg;
                                      and Foefc faff— r mtrst &e mitiga fed to
                                                              egvuruiinenf.
                                                           Bcien greatfy
                                              e.' Such events are adequately
                                      addressed by- emergency sesponse  '
                                      pEocedafes dteffnerffot t&e WlFtT. The ', •
                                      specifics' of t&e various, emergeBejf
                                      response procedures are'
                                                               : fs-.tfee
                                      experiment!^ arear. Tte meist' sfgmfcant
                                      roofs afaffttest
                                      fBoms-wB &e-r
                                     • alone slrdiiMpiaerFent excessive cracfeng-
                                      the Waste ^^.,i,-
                                      while EPA- agrees :-vmflx Gemmenf era tfiat
                                      a fire ois; expfostoft wpnldE mafie. retrfesfaiE
                                      more dJffieu^th&Agjgncy fs'Triiposihg:   •
                                      additional conditions to' m£afln6;e l&e • . ;
                                     • potehfitatfor/sucfi aa. event; {See. sestfoa,
                                      V.I.T of roxfay's notfce for a defaiTed'

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 47706
Federal Register / Vol. 55, No.  220-/ Wednesday," November 14,  1990 / Notices
 description of this point.) Thus.'
 adequate safeguards have been imposed
 and will be implemented in the event of
 an accidental release of hazardous
 constituents.
   It should be noted that the Waste
 Retrieval Plan is backed by successful
 mock retrieval demonstrations, although
 EPA recognizes that mock retrieval
 demonstrations performed thus far at:
 the WIPP did not include removal of
 waste from the alcoves themselves.
 Other aspects of the removal process,  .
 however, were simulated in the retrieval
 demonstration. Mock retrieval
 experiments on backfilled alcoves and
 on bins will be performed before any
 waste is placed in the WIPP.  .
   EPA agrees with commenters that
 shuffling of the waste during the
 retrieval process could increase the risk
 of a release; however, safe movement of
 the waste containers is technically
 feasible, and EPA has concluded that
 DOE's routine container-management
 procedures are adequate. Furthermore,
 any removal activities will be conducted
 under the oversight 6t the State of New  .
 Mexico, either during RCRA interim
 status or under permit conditions, which
 will ensure an appropriate level of care.
 Finally, the Environmental Evaluation
 Group, an independent group
 established by Congress to provide
 review of the WIPP project, provides
 oversight over waste management and
 safety aspects.of WIPP operations,
 including removal.        •
 .  A number of commenters raised the
 possibility  of drum corrosion during the
 test phase,  which, c'puld lead to spillage'
 and complicate retrieval. EPA has
 concluded,  however, that the potential
 for significant drum corrosion during the
 test phase is limited .and will not
 substantially affect the retrieval of
 wastes. While it is true that salt is very
 corrosive, the rate of corrosion of the
 drums being stored in the repository is
 expected to be low. This'is because
 several key factors affecting the rate of
 drum corrosion allow for favorable drum
 storage conditions. In particular, the rate
 of corrosion is affected by the
 composition of the brine contacting the
 drums. That is, corrosion proceeds most
 rapidly if the brine is unsaturated and
 contains dissolved oxygen. However..
 the brine in the WIPP repository is both1
 saturated with salt and contains low
levels of dissolved oxygen;.therefore,
drum corrosion would be inhibited. .
Moreover, the rate of corrosion is     -
 directly affected fay the amount of brine
 contacting the drums. Sjnce the
repository is expected to remain dry
during the'test period and'thus there,w.ill
be minimal drum-brine contact, EPA
                        does not expect the drums to corrode
                        significantly. For ithese reasons, EPA has
                        concluded that the useful drum life in
                        the WIPP will exceed the period of this
                        determination, including retrieval time,
                        and it sees no reason to question DOE's
                        statement that the drums will maintain
                        integrity, for twenty years.
                          In addition, EPA notes that containers
                        at the WIPP will be subject to
                        monitoring and inspection procedures
                        required under RCRA 40 CFR part 265
                        (and, once a permit has been issued,
                        under 40 CFR part 264]. These
                        requirements will be adminstered by the
                        New Mexico Environmental •
                        Improvements Division, with EPA
                        oversight. If any questionable drums
                        were identified, mitigative measures-—
                        such as overpacking—could be
                        undertaken. To be sure, drums that are
                        sealed in the alcoves during the alcove
                        tests cannot be routinely inspected.
                        However, under DOE's test plan, these
                        tests are expected to last approximately
                        five years. Thus, inspection would be
                        possible well within the useful life of the
                        drum.           '
                          Finally, as EPA discusses in this and
                        the following section, spillage from
                        drums (however unlikely) can be
                        contained and cleaned up, and corroded
                        drums can be overpacked. Thus, EPA
                        disagrees with commenters that drum
                        corrosion might prevent the safe
                        removal of drums from the -WIPP, if
                        removal-proves necessary..
                         Limited effect of accidents and spills.
                        Numerous commenters argued that
                        accidents or spills at the WIPP site
                        would complicate retrieval of wastes or
                        might lead to migration. EPA agrees that
                        accidents or spills, might complicate
                        retrieval, but it ha's nevertheless
                        concluded that the cleanup of spills and
                        the removal of contaminated material
                        from the WIPP is technically feasible.
                        The'WIPJP Retrieval Plan outlines DOE's
                        planned approach to the removal of .
                        contaminated maferial; in addition, the
                        feasibility of .safe Removal of such
                        material was demonstrated in DOE's
                        mock retrievals. Moreover, neither EPA
                        nor public commenters identified .any '  -
                        spill situations that by themselves
                        would lead to a release from the
                        repository.
                         EPA has addressed the possibility of
                        fire or explosion in the WIPP by new
                        waste characterization requirements in
                        today's decision. Under these
                        requirements, DOE must test every
                        container shipped to the WIPP for
                        flammable gases. If flammable gases are
                        identified, the waste cannot be placed in
                        the repository. .Therefore,  under the
                        terms of.EPA's determination, explosion
                        or fire in the WIPP is not a credible
 event. (After DOE has developed a
 greater body of data .on wastes shipped
 to the WIPP, it is likely that waste
 characterization requirements
 addressing flammability can be relaxed.
 However, this could only take place
 through a modification of the
 determination, with opportunity for
 public comment.)
   Effectiveness of controls against
 human intrusion. During the period
 covered by today's determination, DOE
 will maintain active control over the
 WIPP site, and unauthorized access will
 be prohibited. Furthermore, the site will
 be operating under RCRA interim status
 and permit conditions, administered by
 the State of New Mexico, and therefore
 will have to comply with the RCRA
 security requirements. These
 requirements include prevention of
 Unknown entry of persons or livestock
 to- the active portion of the facility.
 Finally, DOE has secured all mineral
 leases at  the WIPP site, eliminating the
 possibility of the disturbance of the
 repository as a result of mining or  •
 drilling. For these reasons, the Agency
 has concluded that migration resulting
 from human intrusion will not occur
 during the term of the determination.

 B. Conditions of Determination

 1: Limitation to Testing and
 Experimentation

   In EPA's proposed finding, it limited
 activities involving mixed waste at the
 WIPP repository to the testing  and
 experimentation described  in DOE's
 petition and referenced documents. The
 Agency has retained this condition in its
 final determination. Consequently, DOE
 will be  restricted to. its planned test
, phase activities, as described in the,
 "WIPP Test Phase Plan: Performance
 Assessment," Revision O (DOE/WIPP
 89-011, April 1990). Before DOE could
 conduct activities beyond the scope of
 this test plan, it would have to petition
 EPA to  modify its no-migration finding.
   Several commenters on the proposal
 expressed uncertainty about what
 specific activities would fall under the
 definition of "testing and
 experimentation"; in addition, the
 commenters asked for clarification of
 when DOE would have to notify EPA of
 changes from activities described in the
 performance assessment test plan.
   With respect to the first point, DOE
 could conduct in the repository only
 those tests-or experiments designed to
 provide data to demonstrate the long-  .
 term acceptability of the WIPP; Thus,
 DOE's planned "operations
 demonstration" has been explicitly
 excluded  from the allowed activities;  :

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                 Federal Register / Vol. 55, No. 220 / Wednesday/November 14. 1990 / Notices          47707
  other nontesting activities would
  similarly be excluded. For clarification,
.  EPA has modified this condition, which
  originally read "placement of waste for
  the primary purpose of conducting an
  operations demonstrated is prohibited
  under this variance *• *  *," by dropping
  the word "primary." Several
  commenters suggested that the inclusion
  of the word "primary" amounted to an
  invitation to DOE to conduct a full-scale
  operations demonstration with the
  excuse that some testing was also going
  on. This was not EPA's intention, and
  therefore it has modified the condition
  accordingly. EPA, however, stresses that
  it does not understand this condition as
  preventing DOE from incidentally
  testing some operational aspects of its
  system when it places waste
  underground for permissible testing.
  Such activity, in EPA's view, would not
  constitute an "operations   •
  demonstration" in the sense that DOE as
  well as DOE critics have used the
  phrase up to this point. In addition, EPA
  recognizes that some mixed wastes
  might be generated'underground as 8.
  result of legitimate experimentation or
  air monitoring in the WIPP repository.
  These wastes, which might no longer
  have any experimental purposes, could
 .nevertheless be stored in the repository
  until a final determination on the site
  was made. Because  the materials were
  originally placed in the WIPP for
  permissible testing, continued storage of
  the wastes in the repository would be
  consistent with the terms of EPA's
  decision.
   With respect to the second point, tests
  and experiments 'conducted under
  today's determination would have to be
  consistent with the activities described
  in DOE's performance assessment test
 plan and its no-migration petition. For
  example, where substantially different
 wastes or waste containers are used,
 where waste volumes were increased
  above 0.5 percent (but less than one
 percent), or where tests outside DOE'sr
 planned three-phase bin and alcove--  '
 scale tests are  contemplated, DOE
 would be required to notify EPA and, if
 the changes might affect the basis of ...
 EPA's finding, seek a modification to
 that finding. The only exception to this
 would be those wastes that are
 described in DOE's no-migration,      ••
 petition that are modified through
 various treatment technologies; because
 the composition of these wastes, if
 changed, would contain fewer toxic
 constituents, the Agency does not
 believe it would have to be notified
 before the wastes could be placed in the
 repository. EPA does note, However,
 that the pilot-room tests originally
 suggested by EPA and now  '       :
 contemplated by DOE, would be
 excluded under today's decision,
 because they go substantially beyond
 the program described in DOE's test
 plan and furthermore are inconsistent
 with other conditions of the  :
 determination (e.g., the volume limit and
 retrievability of wastes).            ,   ,

 2. Limitation on Volume
 .  In its proposed determination, EPA
 did not set a specific limit on the amount
 of mixed waste that DOE could place in
 the repository, during the test phase.
 Instead, EPA argued that, because of the
• experimental nature of the test phase,
 DOE needed a reasonable degree of
 flexibility in carrying out its    '
 experimental program. Although several
 commenters supported EPA's approach,
 many opposed'it, arguing that it was
 open-ended and allowed DOE to expand
 the scope of the test phase indefinitely.
 Although EPA continues to believe that
 its no-migration finding, as proposed;
 significantly restricts the nature of DOE
 activities during the test phase, the
 Agency nonetheless understands the
 concerns of the commenters. Therefore,
 it has decided to place a volume
 limitation of 8,500 drums or 1 percent of
 the total projected WIPP volume on
 wastes that can be placed in the
 repository under this determination.
   In setting a volume limit, EPA notes  •
 that DOE's "WIPP Test Phase Plan"
 called for bin and alcove-scale testing of
 waste amounting to 0.5 percent of the
 projected WIPP capacity, while in
 Congressional testiiaony, DOE indicated
 that bin, alcove, and pilot-room tests
 might require waste amounting to
 approximately 2 percent of the WIPP
 capacity. Because EPA has determined
 that the pilot-room tests, as currently
 planned, could not be conducted under
 the proposed no-migration finding, it
 believes that the 2 percent volume limit
 would be inappropriate. At the same  •  .
 time, EPA also believes that limiting
 DOE to the amounts specified in the
 current test plan might not provide
 sufficient flexibility for DOE to modify
 those plans, particularly in response to
 comments from reviewing organizations.
 Consequently, EPA has decided to  .
impose a limit of 1 percent of total WIPP
. capacity (or 8,500 drums); a figure that
provides some flexibility to DOE and at
the same time gives the public
assurance of an opportunity to comment
if significant increases over DOE's
proposed waste volumes are needed.
   EPA emphasizes that it is not basing
the 1 percent limit on any technical
determination of how much waste
would be necessary for DOE to carry
out an adequate testing program. Rather,
 EPA in effect is defining a limit that it
 would consider to be a significant
 departure from the activities described
 in DOE's. no-migration petition and its
 final test plan. Before DOE could exceed
 that limit, it would have to repetition
 EPA, and any EPA approval of an
 expanded test program would have to
 undergo public comment. EPA also
 emphasizes that the 1 percent figure
 represents an upper limit on the amount
 of waste that may be placed in the WIPP
 under today's determination. This limit
 would not override the condition that
 waste could be placed in the WIPP only
 for testing and experimentation within
 the scope of DOE's test plan. Waste
 would not be allowed in the repository
 for purposes other than testing and
 experimentation, even if the volume of
 waste involved did not exceed the:l
 percent limit.        •           ;
   Many commenters also suggested that
 EPA shorten the proposed ten-year
 expiration date for petition approval.
 EPA has not adopted this suggestion,
 because, as it discussed in the proposed
 decision, it believes such a limit might
 artificially constrain legitimate testing.
 EPA does not believe the difference
 between five years (the projected length
 of DOE's test phase) and ten years is
 significant hi terms of the likelihood of
 release of hazardous constituents from
 the repository. Furthermore, it has
 concluded that this difference in time
 will npt significantly effect
 retrieyability; However, EPA,
 acknowledges that the timing  and  '."'-..
 procedures for removal of waste if DOE
 is not able to demonstrate the long-term
 acceptability of the WIPP at the;close of
 the ten-year period was not clear in the
 proposed finding. Therefore, the Agency
 has amended the conditions of the
 finding to address this concern. This
 issue is discussed below.
 3. Waste Retrieval
   The  requirement that DOE retrieve
 wastes from the repository if it cannot
 demonstrate the long-term acceptability
 of the site remains unchanged from, the
 proposal. As discussed above  in section
 IV.A,'EPA has found such retrieval to be .
 feasible within the general parameters
 of the plans,submitted with the petition. .
 In addition, EPA has added a clause
 spelling out in more detail the  timing of
 retrieval. Under this requirement, DOE
 must submit to EPA a specific  retrieval
 schedule no later than six months after
 it is determined that the WIPP cannot
 meet the long-term disposal standards,
 or six months before the expiration of
 the petition approval (i.e., 10 years after
petition approval), whichever comes
first. This schedule would have to detail

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477D8	Federal Register /  VoL  55. No. 220 /'IWednesday, November 14, 1990 /
retrieval procedures and include a
schedule for the removal of the waste as
rapidly as technically feasible. Before
retrieval took place, the plan would be
subject to public comment and EPA
approval
4.WasteRetrievability

  DOE is required to place all waste in
the repository in a readily retrievable
manner. This condition is unchanged
from the proposal. By "readily
retrievable," EPA means adoption of the
specific measures identified in DOE's
petition to maintain room stability {i.e.,
room sizing, rock bolting), the use of
easily retrieved waste containers'(eg.,
boxes, bins, and drums), and the
absence of backfilling—except in alcove
tests where standoff walls will be used.
(EPA notes that testing in pilot-scale
rooms, which the Agency originally
suggested and DOE is now considering,
would not be allowed under this
condition, because—as currently
planned—they would involve backfilling
of waste in the pilot rooms without
standoff walls. DOE would have to seek
a modification of the no-migration
finding, with opportunity for public.
comment, before conducting such tests.)
5. Carbon Adsorption Device
  Today's decision requires DOE to
install a carbon adsorption control
device in the bin discharge system of
each room designed to achieve a 95
percent control efficiency. The Agency
believes a 95 percent control efficiency
is readily achievable. (See 55 FR 25454.) •
The design must be based on a total
design gas volume consisting of a design
gas generation value of at least 5 moles
per drum per year from the bins and the
volume of gas used to purge the bin
exhaust manifold. EPA also wishes to
clarify that the design value for the
frequency of carbon replacement must
be verified by testing and modified as
needed to prevent breakthrough from
occurring. The testing must consist of
measurements of the adsorption
capacity of carbon for the bin exhaust
gases, as described in the petition. EPA
is also requiring DOE to maintain design
records, including any test data, and
operating records in the facility,
operating record, as described in the   '  •
notice of the proposed decision. (See 55
FR 13063, Section IV.J.) Records must be
maintained for the term of today's
determination (Le., ten years from
today'a date), or three years after the
creation of the records, whichever is
longer. In addition, the records must be
maintained during the course of any
enforcement action for which they are
relevant
   EPA is not requiring DOE to perform
 testing to verify the control efficiency of
 the carbon bed. However, DOE must
 monitor the bin exhaust manifold to
 show that no migration above health-
 based levels occurs at the unit
 boundary. This must be further
 confirmed by monitoring at the exhaust
. shaft. Although the 5 moles per drum per
 •year design value for gas generation is
 believed to be conservative, the overall
 'average rate of gas generation fromTRU
 wastes is not known with certainty; this
 is the purpose of the bin and alcove
 tests. Hie control [efficiency actually
 achieved will be higher or lower
 depending on the.rale at which gas is
 generated during the tests. However,
 even if gas generation rates were to be
 as high as 25 moles per drum per year,
 the design would Still achieve the no-
 migration standard.

 6. Air Monitoring plan
   EPA is requiring air monitoring for
 activities conducted under today's no-
 migration finding to confirm that there is
 no migration of hazardous constituents
 above health-based levels beyond the
 unit boundary. As described in its notice
 of proposed decision (55 FR 13068), EPA
 has concluded that the only possible
 migration pathway during the test phase
 is through the exhaust shaft. Therefore,
 in accordance with the requirements of
 40 CFR 268.6(c), tile Agency is requiring
 DOE to implement the air monitoring
 plan submitted with its petition, subject
 to the clarifications, modifications,  and
 reporting requirements described in the
 notice of proposed ilecision, except as
 noted below.
   In its proposed decision, EPA solicited
 comment on whether additional
 monitoring should be conducted in the
 underground repository with portable
 explosimeters to detect any buildup of
 methane, hydrogen, or other flammable
 gases. No comments were received in
 favor of portable explosimeters.
 Therefore, EPA has decided not to
 require their use. At the same time,
 however,' EPA has determined that only
 by testing individual waste containers to
 be placed in the WIPP can it be  assured
 that no- fire or explosion hazard exists.
 Thus, EPA is including an additional
 condition requiring such testing, as •
 described in section IV.B.7.a of today's
 notice.         |
   EPA also solicited comment on
 whether to allow a reduction in
 monitoring frequency from weekly to
 monthly. EPA received no comments on
 this question and has decided to retain a
 weekly minimum monitoring frequency.
 Furthermore, EPA solicited comment on
 whether other constituents, in addition
 to the five constituents proposed, should
 be targeted for routine quantitation. No
 comments were received on this
 question; therefore, EPA has decided to
 retain the five target constituents listed
 in the notice of proposed decision, with
 provisions for targeting additional
 constituents, as described in the
 proposal.
   In the proposal; EPA spelled out a
 variety of quality assurance and quality
 control requirements, making mention of
 the "Report on Minimum Criteria to
 Assure Data Quality," Since that time,
 EPA has revised this report and has •
 retitled it "Quality Assurance and
 Quality Control" (August 1990), a copy
 of which has been placed in the docket
 to .this rule. Therefore, EPA is requiring
 DOE to follow the requirements of the
 revised report, in addition to adhering to
 the specific quality control requirements
 described in the DOE monitoring plan
 and EPA's notice of proposed decision.
 EPA wishes to clarify that it intends the
 "method limit of quantitation," the term
 used in the notice of its proposed
 decision, to be synonymous with the
 term "method detection limit," or MDL,
 used in the report,  "Quality Assurance
 and Quality Control" In addition, EPA
 is requiring DOE to maintain
 documentation of all aspects of quality
 assurance and quality control, as
 described in Jhe revised report, in the
 WIPP facility operating record; this
 documentation must be available for
 inspection by  the Agency. The records
 must be maintained for the term of
 today's determination or three years
 after they are  created, whichever is
 longer. In addition, the records must be
 maintained during the course of any
 enforcement action for which  they are •
. relevant   •
   Initial monitoring results underground
 at the WIPP have revealed significant
 background levels  of 1,1,1-
 trichloroetfaane and carbon
 tetrachloride.7 The levels measured can
 interfere with  the evaluation of accuracy
 if the approach described in the notice
 of proposed decision is used. Therefore,
 EPA is changing the method by which
 relative accuracy is determined. Instead
 of computing accuracy based on a
 matrix spike alone (as the relative
 difference between the concentration
 recovered from the sampler and the
 concentration of the targeted analyte as
 determined from the known
 concentration in the audit gas cylinder],
 the computation should be adjusted for
  7 Significant levels of methylene chloride were
 also detected in back&nund samples. However,
 laboratory contamination it the most likely
 explanation for the measured levels of methylene
 chloride.

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                Federal Register / Vol. 55, No. 220 ;/ Wednesday, November 14, 1990 / Notices
                                                                      47709
 the actual background concentration
 measured in a matrix duplicate at the
 time the matrix spike is collected.
 Therefore, DOE must'collect and
 analyze both a matrix spike and a
 concurrent matrix duplicate,   •
   EPA further solicited comment on
 what specific quality assurance (QA)
 objectives it should require for data
 acceptability. DOE requested that EPA
 allow less accurate measurements at
 concentrations near the detection limit.
 The data provided by DOE, however,
 gave no basis for establishing an
 alternative QA objective for accuracy,
 due to high background levels. Because
 of this, and because EPA is.not requiring
 data that are below the method
 detection limit (MDL) to be used in the
 evaluation of relative accuracy (the
 MDL is generally considerably higher •
 than the limit of sensitivity of the
 analytical procedure), EPA has
 concluded that the plus or minus 10
 percent requirement can be achieved.
 Therefore, no change is being, made to
 the QA objectives established in the
 notice of proposed decision.
   Finally, EPA proposed to require
 calibration of the ventilation exhaust
 fans on a quarterly basis. In its
 comments on the proposal, DOE
 interpreted this to mean a full dynamic
 calibration, .which it argued is needed
 only on a yearly basis. EPA means to
 require only a check on the fan
 calibration on a quarterly basis, using
 the methods' described in the notice of
 proposed decision. EPA agrees that a
 full calibration is needed only on a
 yearly basis.
   Several commenters expressed
 concern that EPA is allowing monitoring
 at the top of the exhaust shaft instead of
 at the entrance to the shaft. They argued
 that EPA should require DOE to monitor
 the entrance and exit of the shaft to
 demonstrate EPA's statement that there
 will be no difference between
 measurements. EPA disagrees with  :
 these commenters. Even if, as suggested
 by one commenter, the integrity of the
 concrete shaft liner, were compromised,
 it is inconceivable that any depletion of
 concentrations of hazardous
 constituents could be detected, given the
 large volume of air that the exhaust
 shaft is designed to handle during
 operation. EPA's  overriding concern
 regarding the specific location of the
 exhaust.shaft monitoring station is that
 it be situated so as to enable ready
 access for operation and maintenance
 purposes. Indeed, EPA views ready
 accessibility as one of a number of
 important quality assurance objectives.
. Therefore, EPA .continues to accept
monitoring at the top of the exhaust
shaft.
7. Waste Analysis
  a. Flammability. EPA received a .
number of comments that flammable
gases could build up in waste
containers, creating a fire and explosion
hazard. After reviewing these comments
and new information made available
during the public comment period, EPA
has concluded that, while a fire or
explosion is unlikely, the possibility of
accidental ignition of flammable gases
in waste containers  cannot be ruled out.
Were a fire or explosion to occur, as a
result of accidental ignition of
flammable gases in die void space of a
waste container, retrieval.could be much
more difficult, should retrieval become
necessary. Moreover, .such an event
could itself cause migration above
hazardous levels beyond the
uniboundary.
  For these reasons, EPA believes that
no waste container should be emplaced
in the underground repository if it
contains flammable mixtures of gases in
any layer of confinement, or mixtures of
gases that could become flammable
when mixed with air. To assure a
sufficient margin of safety, EPA defines
any mixture as potentially flammable if
it exceeds 50 percent of the lower
explosive limit (LEL) of the mixture in
air.
  To ensure that individual waste .,
containers have met the prohibition on,
flammable gases, the Agency is
requiring that every waste container be
tested for hydrogen, methane, and  .
volatile organic compounds (VOCs) as a
class. Given the heterogeneity of the
waste package, the Agency is also
requiring that headspace sampling be
representative of the entire void space
of the waste container. EPA expects that
all layers of confinement in a container
will have to be sampled until DOE can
demonstrate to the Agency, based on
the data collected, that sampling of all
layers is either unnecessary or can be
safely reduced. The  testing of wastes
that exhibit high rates of radiolysis
should be performed-a relatively short
time before the container is actually
emplaced underground. Otherwise,
hydrogen levels could build up to
flammable levels following sample
collection and analysis. Therefore, DOE
must determine, and document, the
length of time that headspace gases can
be expected to remain below flammable
levels (i.e., 50 percent of the mixture-
LEL) after sampling has been performed,
for both newly generated and
retrievably stored wastes, and to ensure
that the waste containers are emplaced
in the WIPP within that time.
   If testing reveals the presence of     •
 significant levels of flammable VOCs,
 DOE must perform an explicit flame test
 to determine if a flammable mixture.can
 be formed with air; Significant levels of
 flammable VOCs are defined as
 measured concentrations (excluding
 methane) of 500 parts per million or
 greater. If testing shows that VOCs are
 insignificant, i.e., below 500 parts per
 million, DOE may determine the lower
, explosive; limit of the mixture from the
 lower explosive limits of methane and
 hydrogen using the Le Chatelier formula,
 as described in Section V.I.a of today's
 notice..     '
   All testing must satisfy the quality
 assurance and quality control'
 requirements described in EPA's report
 "Quality Assurance and Quality
 Control" (August 1990) and must meet
 quality assurance  objectives of plus or
 minus 10 percent on precision and
 accuracy. DOE must also maintain
 records.on all testing performed and,
 other documentation needed to comply
 with this condition at the generating site
 or in the WIPP facility operating record.
 These records must be available for
•inspection by EPA, and must include
 documentation of all aspects of quality
 assurance and quality control, as
 described in the above-referenced
 document. Records must be maintained
 for the term of today's decision, or three
 years after they are generated,
 whichever is longer. They also must be
 retained for the duration or any
 enforcement action related to this part
 of today's decision.     ,  .
   b. RCRA Constituents—-Short-term
 characterization. In response to
 comments regarding the accuracy of the
 waste composition estimates-provided
 by DOE in its no-migration petition, EPA
 is modifying its proposal to require that
 DOE analyze headspace gases in
 containers that are shipped to the WIPP
 and compare the results of this analysis
 to the estimated values provided in the
 no-migration petition. Since it was the
 values in the petition that EPA       ,
 evaluated in today's decision, DOE must
 ensure that the analytical data derived
 from the actual test-phase wastes are
 similar to the petition estimates. Wastes
 that are not compositionally similar may •
 not be placed in the WIPP.
   (1) Bin-scale tests. DOE must compare
 actual measurements of headspace
 concentrations of volatile organics in
 each of the drums  containing wastes to
 be used in the bin-scale tests to the
 headspace concentrations reported in
 DOE's petition. The comparisons must
 be made in terms of both maximum and
 mean concentrations; (EPA considers
 only headspace concentrations to  be

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  	            *                                         '                           '
 47710          Federal Register / Vol. 55. No. 220 / Wednesday, November 14, 1990 / Notices
 necessary because migration through air
 was determined to be the only viable
 route of migration during the test phase.)
   The comparison of the maximum
 concentrations is designed to ensure
 that the wastes to be emplaced in the
 WIPP are in fact similar to the wastes
 described in the petition. In its proposed
 decision, EPA noted concerns with the
 precision and accuracy of some of the
 analytical data in the petition and took
 this uncertainty into account during its
 evaluation. To address concerns over
 the quality of its data, DOE will be
 conducting an extensive
 characterization program on wastes to
 be shipped to the WIPP for the bin-scale
 and alcove tests under greatly improved
 quality assurance/quality control (QA/
 QC) procedures. (See e.g., DOE's Pre-
 Test Waste Characterization Plan,
 Revision 6, in the docket to today's
 decision.) Because of improved data
 quality. EPA expects these new data to
 differ somewhat from those contained in
 the petition. However, the Agency
 believes that the measured maximum
 concentrations identified in individual
 drums in DOE's pretest waste
 characterization program should be
 generally comparable to the maximum
 values reported in the petition.
  There are no established criteria for
 quantitatively defining "comparability"
 in this context. EPA, however, has
 concluded that, if the measured
 headspace concentration in a given
 drum are no more than a factor of two
 over the maximum reported for the drum
 in the petition, the wastes are
 reasonably comparable. In selecting a  •
 factor of two, EPA notes that some
 differences between the new data and
 that contained in the petition are
 expected. This is because me new data
 will represent a larger sample and
 analytical results may be more accurate.
 (As noted in EPA's proposal, the
 precision and accuracy of the analytical
 data in the petition were not always
 well documented.) For these reasons,
 EPA has concluded that It is reasonable
 to expect some concentrations will be
 measured that will exceed the maximum
 values reported in the petition. EPA,
 however, also believes that the data
 should not be significantly different and
concludes that a factor of two __
 represents a reasonable expectation.   ' «
  Accordingly, DOE may place the
 contents of individual drums into bins
 for the bin-scale tests if the'measured
 headspace concentrations do not exceed
 the reported maximums by more than a
 factor of two.8 Testing and vertification
 must be completed before the waste is
 shipped to the WIPP. If the measured
 concentration of any of the pertinent
 hazardous constituents in a drum
 headspace exceeds |b.e allowable
 maximum, the contents of the drum from
'which the sample was'collected cannot
 be shipped to or emplaced in the WIPP,
 unless DOE subsequently treats the
 waste so as to reduce headspace.
 concentrations to below the maximum
 levels. Alternatively; DOE may petition
 EPA to modify the conditions of its
 determination. Any such modification
 would require public comment. Further,
 DOE must maintain records of all
 relevant test data atlthe generating site
 or the-WIPP for the tprm of today's'
 determination, or flujee years after the
 data are generated, whichever is longer.
 In addition, records ftmst also be
 retained for the duration of any
 enforcement action for which they are
 relevant.
   The maximum allowable
 concentrations for hazardous
 constituent by waste type (the maximum
•reported concentrations multiplied by
 two) are presented in Table 2,

           .—MAXIMUM HEADSPACE
           CONCENTRATIONS
            Iln volume percent]
Constituent
t.
Carbon j
tetrachloride 	 j
Methylene
chloride 	 ..... 	 J
1.1.1-
Ttich1oroethane.J
Trichtoroethy)Bne_.j
1.1,2-Trichtoro-
trifluorosthane...-
Type:
i '
O.OS !

,0.44
• t .
1.88
•0^38 ,

0.05
JT

0.16

0.84;

5.68
0.34:

1.62,
Type

O.S8 i

0.50

2.12
O.28

5.74;
Type
IV

8.18

1.42

14.96
0.28

20.80
  EPA's no-migration finding for air
releases was based lipon the mean
headspace concentrations of volatile
constituents reported by DOE.
Accordingly, EPAias concluded that
comparison of the new, pre-test.
characterization data with the mean
concentrations reported in the petition is
also necessary to ensure that EPA's
estimates of volatile emissions are valid
for the actual test-phase wastes. In .
determining a reasonable factor for this
comparison, EPA considered the "safety
margin" indicated by; the no-migration
demonstration. For tbe constituents of
concern, this safety margin ranges from
approximately eleven to well over
sixteen million, varyipg by constituent.
EPA has no reason to believe that the
  * A» with tho condition related to flammabllity
discuited onnrfouiljr. DOE must demonstrate that
(ample* collected /or these analyses are
 headspace concentrations for 1,1,1-
 trichloroethane arid l,l,l-trichloro-l,2,2-
 trifluoroethane (with safety factors of
 six and seven orders of magnitude,
 respectively) could be high enough to
 alter the no-migration finding. For the
 other constituents (carbon tetrachloride,
 methylene chloride, and
 trichloroethylene), the safety factors are .
 lower (one, two, and two orders of
 magnitude, respectively). EPA, therefore,
 has concluded that DOE must compare
 the new headspace data for these
 constituents to the mean values reported
 in the petition.8 To ensure that the no-
 migration finding remains valid for these
 constituents,' EPA is requiring that the
 mean values for the test phase wastes
 cannot exceed ten times the mean
 values reported in the petition.
  •EPA is confident that the factor of ten
 (back-calculated from the modeling for
 carbon tetrachloride) is sufficiently
 conservative for all three of the
 constituents. Even though no additional
 safety factor has been added for carbon
 tetrachloride, EPA notes that the  .
 modeling upon which the calculation
 was based contains several
 conservative assumptions (e.g., that both
 test rooms are filled to capacity). EPA
 also notes that, during the test phase,
 emissions will be monitored and it will
 be clear well in advance if emission
 levels are approaching the no-migration
 limits, and corrective measures could be
 taken. Therefore, EPA is comfortable
 with a safety factor of ten for the
 comparison of the mean values.
  DOE must compare the predicted
 mean values (multiplied by ten) against
 the average of the measured
 concentrations of the headspaces of all
 drums of a single waste type used to
 make up each bin. That is, the mean
 from the population of drums going to
 each bin (by waste type) must be
 compared with the reported mean for
 that waste type. If the calculated mean
exceeds the reported mean by more than
 a factor of ten, that bin cannot be
 emplaced at the WIPP under today's
decision. Testing and verification must
be completed before the waste is
shipped to or emplaced in the WIPP. As
with comparisons of maximum
concentrations, DOE most maintain
records of all relevant test data at the
generating site or at the WIPP facility
for the term of today's determination, or
for three years after generation,
whichever is longer.
  The allowable average concentrations
for each waste type in drums to be used
representative of the entire headspace within the
drum, including the headspace within inner bags.
                                                                               0 See footnote 8.

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Federal Register / Vol. 55, No. 22O / Wednesday, November 14, 19SO / Notices
                                                                                                                   47711
 in a single bin are presented in Table
 3.10

       TABtE 3.—MEAN HEADSPACE
            CONCENTRATIONS
             tin volume percent!
Constituent
Carbon
tetraehfowte 	
Methytene
chloride..™™ 	
Trichloroethy|ena_.
Type

0.24

0.39
0.25
T

0.26

0.42
0.28
T

0.30

0.33
0.29
T

6.90

O.93
0.38
   (2} Alcove tests. EPA has found
 emissions from the alcove tests to be
 inconsequential in comparison to the
 bin-scale tests. Accordingly, EPA is not
 requiring testing of the headspaee of
 drams used in the alcove tests to
 demonstrate comparability with
 reported concentrations in DOE*s
 petition. * * Before any drums can be
 shipped to the WIPP for alcove tests,
 however, DOE roust verify (by waste
 type), through results of the bin-scale
 tests conducted up to, that point, that the
 measured mean concentrations for
 specific hazardous constituents do not
 .exceed the reported mean values by
 more than a factor of ten. (See Table 3.)
 (This condition would hot require DOB
 to conduct all bin-scale tests before the
 alcove tests could proceed; however,
 based on discussions with DOE, EPA  ,
 believes that most of the bin-scale tests
 will be conducted before the alcove;
 tests begin.} EPA is also not requiring
 DOE to test the drums to determine
 maximum concentrations for specific
 hazardous constituents, because it     ;
 believes that sufficient data will; have  i
 been compiled from tests conducted in  .
 bin-scale drums to determine if there is
 a concern. In this regard, EPA notes that
 the drums for both, the bin-scale and the
 alcove tests will be randomly selected
 from the population of each appropriate
 waste type. Therefore, there is no reason
 to believe that the wastes usedin the
 alcove tests will be any more or less   -
 accurately characterized  by the data in
.the petition than will be the wastes used
 in the bin-scale tests. For this reason,
  10 The allowable concentrations are the reported
mean concentrations foreash waste type multiplied
by ten. In calculating the mean headspaee
concentrations, EPA used one-bait the detection
limit indicated in the no-migration petition to  '
represent concentrations where the constituent .was
not detected.      .   "    '              '
•'  la Although today's decisions doe?not require:
DOE tocharaeterize RCRA constituents in the
drums to be used in the afcove testa, DOS has
informed EPA that it intends to test same statistical
number of drums that are to be used in the alcove
test. In addition, as discussed earlier, DOE tviR be
requited to test the headspaee of drums used in the
alcove testa fortlamroability.
                         EPA has concluded that the data
                         collected from the drums selected for the
                         bin-scale tests can be appropriately
                         extrapolated to the drums, for the alcove
                         tests.
                           c. RCRA Constituents—Long-term
                         characterization. In its proposed
                         decision, EPA expressed some concern
                         over the limited waste characterization
                         data provided by DOE hi support of its
                         petition. While EPA concluded that the
                         data were sufficient for the no-inigration
                         demonstration for the test phase, it also
                         believed that further characterization
                         was required, before any finding could
                         be made for the operational and post-
                         closure phases. EPA believes that this
                         farther characterization will be
                         necessary both to further confirm DQE*s
                         estimates of waste composition and to
                         ensure that the wastes are sufficiently'
                         similar to allow the results of test-phase
                         experimentation to be extrapolated to
                         the wastes that DOE wishes to emplaee
                         at the  WIPP in the operational phase.
                         That is, the Agency wished to ensure
                         that the test-phase wastes are
                         accurately represented by the estimates
                         and are representative of the  remainder
                         of the  wastes.12 In addition, more
                         accurate source term data may prove
                         necessary, EPA believes, in long-term
                         modeling exercises. Toward these ends,
                         the Agency proposed to require DOE to
                         report all characterization data that will
                         be  collected*
                          After carefully reviewing public
                         comments, EPA continues to believe
                         that the data provided by DOE in its
                         petition are sufficient for its finding with
                         respect to the WIPP test phase, ivhere
                         air emissions are the major concern
                         (especially given the standards on
                         headspaee concentrations and
                         fiammabslity imposed in today's
                         decision}. The additional waste
                         characterization data under  .
                         development by DOE during the test
                         phase  will be important for any review
                         of a subsequent no-migration petition for
                         operational and post-closure periods,
                         where  groundwater migration and other
                         issues  may arise; however, the data are
                        not needed for today's decision.
                         . iz By "representative," EPA is referring to those
                        factors that should contribute to migration of
                        hazardous constituents. The purpose of the test-   -
                        phase experiments is to evaluate gas-generation
                        processes and providesdatabase of information  •
                       • that can be used to predict gas generation potential.
                        of the waaies that are planned to be emptaced
                        during the operational phase. Thus, the issue of
                        whether the test-phase wastes are "representative"- •
                        deals with whether the results olE the test-phase-•
                        experiments can be extrapolated to the remaining
                        wastes. To that end. DOE's approach is based upon
                        an "envelope" or "bounding" concept wherein  ' .
                        wastes whose characterization (for gas-generation :
                        potential)is within that envelope would be
                        considered "represented" by the test-phase wastes.
  Accordingly, EPA has not included    • *
  detailed requirements-for .•waste   .     •
  characterization of the test-phase  •   •
  wastes (beyond the headspaee
  concentrations and flammability limits)
  or of wastes generated at the ten DOE
  sites as a condition for today's final
  decision. However, DOB is developing
  waste characterization plans, including '
  sample collection, preservation, and
  analytical procedures, to demonstrate
  the extent to which Ihe test phase
  wastes are representative of Ihe other
  wastes from the ten sites, and to confirm
 •the actual levels of RCRA .constituents
  in headspaee gases and sludges. If
  certain wastes that are generated at the.
  ten sites are not represented (as defined
  in footnote 12J by the wastes that were
  tested during the test phase, they conld'
  not be shipped to the WIPP without
  further Agency evaluation, including the
  possibility for. public comment or
  treatment of the waste.
   Over the past several months, EPA—-
  and the state of New Mexico—has
  reviewed a number of documents
  concerning DOE's pre-test waste
  characterization plans. EPA will
  continue to provide comments to DOE to
  assist DOE in' evaluating whether the
  waste  characterization data that DOE
  will be collecting are sufficient to make
  a long-term finding for the WIPP. If
  adequate data are not collected, EPA
 will not be 'in a position to approve any
 no-migration petition for the operational
 and post^closure phases, if DOE submits
 such a petition. Af a minimum, the
 wastes .should be analyzed for the
 following constituents:  •
 Acetone
 Benzene
 Brottiofonn
 BotanoJ
 Nitrobenzene1
 13A2-Tetraehlbioethane
 Tetrachioroethytene
 Toluene
 2-Butanone'
 Carbon tetraehloride  .
 Chloroform  ,
 Chlorobenzene
 Cyciehexane "  ,
 1,1-Dichloroethane
 1,2-Dichloroethane
 1,2-Dichloroethene
 cis-l,2-DiEhIoroethane
 Ethyl benzene'
 Ethyl ethe>
 Formaldehyde
Hydrazine
Methanol
Methytene .chloride
4-Methjif-2-pentanene
M.l-Tricbknnethane
Trichloioetbylene ...
!,13-TrichoForo-lA2- '
  trifTuoroethane
1,3,5-Trimethylbenzene
o-Xylerie
p-Xytene
Cadmium
Chromium
Lead
Murcury
Selenium .
Sihref •  . • •
 Testing for these constituents; should   •
 include'headspaee analysis of all waste
 types for the,.org,anic compounds, as
 well as total analysis of the sludges for.
 both the organic compounds-and= the
 .metals.1? Since these date are not  •
'  1:> As .indicated in Section l.Doft
 the state of New Mexicoia responsible for enforcing
                                Continued

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 47712
                                   I

Federal Register •/ Vol. 55. No. 220 / Wednesday. November 14,  1990 / Notices
 necessary for today's finding, but rather
 will be evaluated as part of a
 subsequent review of a petition for the
 operational and post-closure periods (if •
 DOE chooses to aubmit such a petition).
 EPA has concluded that the specifics of
 this testing should not constitute a
 condition in today's decision.
 8. Reporting Requirements
   Reporting requirements associated
 with EPA's final no-migration
 determination are unchanged from the
 proposal—that is, annual written reports
 are required on the status of DOE's
 performance assessment during the test
 phase—except that the final
 determination requires that DOE send
 reports to EPA's Region VI office in
 Dallas, Texas, as well as to the EPA   *
 Office of Solid Waste at EPA
 headquarters. Because Region VI will
 have direct enforcement authority over
 the WIPP, EPA believes that it  is
 important for reports to go directly to
 the regional office as well as to EPA
 headquarters.
 V. Discussion of Major Issues
  ,EPA received more than 400
 comments on its proposal, some
 supporting EPA's proposed decision and
 others opposing it. Commenters raised a
 wide variety of issues, including the
 general scope of EPA's review and its
 proposed decision; the suitability of the
 site; the consistency of EPA's proposed
 approach with the statutory no-
 migration standards;  adequacy of waste
 characterization; the feasibility and
 likelihood of retrieval; the impact of
 possible human intrusion; and many
 other issues. The major issues raised by
 the public are discussed below  as well
 as in other sections of this notice. These
 and the other issues raised by
 commenters are also  discussed in detail
 in a Response to Comment document
 prepared by EPA. This document is
 available in the public docket to this
 decision.
A. Appropriateness of "Exemption"for
DOE
  A number of commenters criticized
EPA for proposing to grant to DOE what
 they regarded as an "exemption" from
 the hazardous waste regulations for its •
WIPP operations. They questioned why
EPA would grant an "exemption" or
"variance" to DOE for radioactive
wastes, given the risks of this material.
Numerous commenters also questioned
RCRA Interim status standards at the WIPP and for
Issuing a RCRA permit to the facility. In carrying out
these responsibilities, the State may require
additional or more stringent waste characterization
requirements.
                        DOE's record at other sites, and argued
                        that DOE shbuld be required to comply
                        with all applicable regulations—without
                        special "exemptions" or "variances"—
                        before it was allowed to place waste in
                        the WIPP repository for any purposes.
                         EPA stresses that it is not granting an
                        "exemption" to DOE from the hazardous
                        waste regulations. This action, however,
                        is a "variance" only in a very narrow
                        sense. HSWA establishes two routes by
                        which a regulated party may dispose of,
                        waste in compliance with the land
                        disposal restrictions: It may pretreat
                        wastes according to specified treatment.
                        standards, or it may dispose of the
                        waste in a unit that meets the stringent
                        no-migrationjstandard. DOE has chosen
                        the second route of complying with
                        these restrictions—an option that is in
                        some respects the more stringent of the
                        two. For exaipple, if DOE were to
                        choose treatment as its approach, DOE
                       would no longer be required to
                        demonstrate jthat no hazardous
                        constituents would migrate from the
                       WIPP before pie treated waste (which
                       might still rerhain hazardous) could be
                       placed underground. In any  case, EPA
                       reemphasizes that its action today in no
                       way exempts: DOE from the  hazardous
                       waste regulations; instead, it is a
                       determination by EPA that the.
                       placement of untreated mixed waste in
                       the WIPP during the test phase complies
                       with the statutory and regulatory
                       restrictions oh land disposal under
                       RCRA. Furthermore, it should be noted
                       that the WIPP must also comply with the
                       other hazardous wastes standards of
                       RCRA, as well as other applicable
                       standards. Other standards applicable
                       to the WIPP are described in Section I.D
                       of this notice.
                         EPA recognizes the concerns of many
                       commenters over acknowledged
                       problems at other DOE sites. EPA,
                       however, does not believe that problems
                       at other sites should rule out approval of
                       a no-migration petition for the WIPP.
                       The issue at hand is whether there will
                       be any migration of hazardous
                       constituents from the WIPP disposal
                       unit. EPA has carefully and
                       independently reviewed all the
                       information from other sources. As a
                       consequence of this review, EPA has
                       concluded that DOE has demonstrated,
                       to a reasonable degree of certainty, that
                       hazardous constituents will not migrate
                       from  the disposal unit, under the
                       conditions prescribed in Section VI of
                       this notice.   |
                       B. Timing of EPA Decision
                         A number of commenters expressed
                       concern about what they considered to
                       be EPA's undue haste in proposing to
                       grant DOE's no-migration petition for
 the WIPP, and they criticized EPA's
 tentative schedule for a final decision.
 They suggested that EPA may have
 taken undue shortcuts in the regulatory
.process, or that DOE's petition was
 given an insufficient level of technical
 review.
   EPA disagrees with these
 commenters. The Agency deliberated on
 DOE's original petition for more than a
 year before its proposed no-migration
 determination for the WIPP in April
 1990, and it spent an additionalfive
 months in the review of public
 comments before reaching a final
 decision. In the course of this review,
 EPA conducted a complete and thorough
 evaluation of DOE's petition, material   •
 provided by DOE in support of its
 petition, independent studies of the
 WIPP, arid public comments on the
 proposed no-migration determination. In
 addition, EPA staff conducted three
 investigatory visits to the WIPP site. The
 results of EPA's review are summarized
 in today's notice and in the Agency's
 proposed decision in April 1990.
 Technical details are provided in EPA's
 Response to Comments Document and
 its Background Document, both of which
 are available in the docket for this
 rulemaking.
   EPA acknowledges that it placed a
 high priority on the review of DOE's
 WIPP petition. The Agency disagrees,
 however, that it took any undue
 shortcuts in the review or omitted any
 significant procedural steps. EPA's
 decision was made in full accord with
 the procedures for no-migration
 determinations, codified at 40 CFR 269.6;
 and with EPA's procedures for site- •
specific decisions under RCRA. EPA
modeled its procedures for handling the
WIPP no-migration petition (as well as  •
other no-migration petitions now under
review) on its procedures for handling
RCRA delisting petitions. These
procedures ensure a thorough and
complete Agency review, with public
notice and full opportunity for public
comment.

C. Scope of Determination •
  In its proposed no-migration
determination for the WIPP, EPA noted
that it did not consider the release and
possible risks associated with
radioactivity; rather, its review ;
addressed the release of hazardous
constituents from the disposal unit. EPA
pointed out in its proposal that the
statutory language on no-migration
referred to the release of hazardous
constituents, which do not include
radionuclides, and risks of radioactivity
from the materials DOE is placing in the
WIPP fall within the scope of the Atomic

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                Federal Register /Vol. 55,  No. 22O  /  Wednesday, November 14, 199O / Noticer
                                                                      47713
 Energy Act rather than RCKA. The
 Agency further noted tbafrisks   .    ,-
 associated with transportation lay
 outside the scope of its no-migration  ;
 review. Finally. EPA did not seek to
 determine, whether the approach
 proposed by DOE—that is. deep
 geologic disposal of TRU wastes at  the
 WIPP site—was the best possible
 alternative for handling that waste.
 Despite EPA's explanation of the scope
 of its no-migration review, numerous
 commenters raised issues related to
 radioactivity, transportation, and
 alternatives to the WIPP. EPA
 understands that concerns of these
 commenters; however, its continues to.
 believe these concerns lie outside the i
 scops of its legal authority and are •   ;:
 better-addressed in ether forums.     ;.;
  Radioactivity was a major concern of
 many eoinmenters. A number, in      ;•,
 particular, argued that, since EPA's    ~
 charge is to protect human health and ;
 the environment, it must address the  ; •
 release of radionuclides in any
 evaluation of the non-migration
 potential of -waste from-the WIPP. EPA,
 however, believes feat the potential for .
 radioactive releases from source, special
 nufctear, and byproduct material is not
 within the scope of :the non-migration
 determination. First, as EPA explained
, in its proposed no-migration finding for
 the WIPP. the Agency's authority 'over"
 mixed wastes under RCRA. extends only
 to the hazardous components of the
 waste, not to the radionuclides
 exempted from RCRA. (EPA explained
 this positios more fully in its mixed
 waste clarification notice of July 3,1986,
 5.3 FR 37945, See;a!so.Section LB, above).
 Second, release of'radionuclides is not
 within the specific mandate'of the no-
 migration language in RCRA or the
 regulatory standards codified at 40 CPR
 268.6. Under the statute, EPA may not
 find a method of disposal protective of
 human health unless "* * - * it has been
 demonstrated to.the Administrator, to a
 reasonable degree of certainty, that
 there will be no migration of hazardous
 constituents from the disposal unit * * *
 for as long as. the waste remains  ,
 hazardous." Hazardous constituents are
 a term of art under the statute, referring
 to compounds listed in 48 CFR part  201,
 appendix VIII. No type of radionuclide
 is listed in the appendix. Moreover, EPA
 regulations at 40 CFR,r26#.6 do riot
 contemplate evaluation of the
 radioactive risks of .a given ,qmt.
  EPA acknowledges that it has a
 general authority and responsibility
 under RCRA and other acts to protect.
 human .health and the environment and
 that this standard is an overriding
 consideration in any no-migration; •" . v
 decision, including a decision regarding
 the WIPP. The Agency believes,     . .
 however, that the standards issued by'..
:EPA under the-Atomic Energy Act and1
 the Clean Air Act are the proper  ' •
 standards for protection of homah
 health -and the environment for radiation
 risks at the-WIPP site. Air emissions  !
 from the WIPP during the-test phase will '
 have to comply with the Clean Air Act
 standards for radioactive releases in 40
 CFR part 61 and (under agreement with'
 the State of New Mexico) with AEA
 standards issued tinder 40 CFR part 191
 subpart A. In chapter 6 of its Final
 Safety Analysis Report, DOE calculated
 radionuclide emissions from the WIPP
 according to EPA-approved models to
 document compliance with Clean Air •
•Act and AEA standards. DOE is also
 preparing a NESHAP notice of
 anticipated start-up to file with EPA, in
 accordance with Clean Air Act
 standards*. Finally, long-term releases of
 radionuclides will be controlled under
 AEA disposal standards codified at 4(>
 CFR part 191 subpart B. These
 regulations, which were specifically  :
 designed to address potential •
 radioactive releases, are the appropriate
 authority for addressing any s'ueh:   •
 releases at fee WIPP site.  '
  . EPA also aeknowledges^pulilie '
 concerns about transportation safety
 and agrees that it is important for.DOE  •
 to take every necessary measure to
 ensure the safety of shipments to the
 WIPP. The question of transportation
. risks, however, lies outside the scope of.
 EPA's no-migration authority, and
 therefore the Agency has not addressed
 them in its review* Instead, overall  .   •
 issues of transportation safety for the -•  •
 WIPP project are addressed-ander the
 National Environmental Policy Act
 (NEPA) through the Environmental
 Impact Statement process and by the -
 Nuclear Regulatory Commission, which
 by agreement with DOE has oversight
 over shipping containers-and-the waste
 form during transportation.
   Finally, EPA has reviewed comments
 suggesting that alternatives other than
 the WIPP—for example-, Iqngrterm .  •',:•..
 storage of TRU wastes at'the sites of  ;'••
 generation—should be chosen for     ;
 management of TRU wastes. The
 Agency continues to  believe that deep
 geological burial is ,a promising strategy
 for the disposal of radioactive waste.
 But, in any case, the question of whether
 acceptable alternatives to the WIPP:  •   ••
 exist, or whether other approaches
 might be preferable, lies outside the
 scope of ERA's review.Under the  •  -.'
 statute, DOE may place untreated mixed
 waste in the WIPP repository if it can
 meet the .statutory standards for-nb    •
 migration:- Alternative approaches to' •'.
 deep geological burial are more•- •••• • / - -  •
. appropriately addressed luiderthe---' '"> -
 NEPA process.    "  -.'  -'H;. , .-.--.• ..••  •

' D..EPA Oversight Over the Test PKnse,
   Several commenters of EPA's   - •,
. proposed determination argued that
 EPA should assert direct oversight over"  .
 the testing and experimentation during
 the test phase. For example, some
 commenters argued that, before any'
 waste was placed in the repository, EPA
 should rttake a finding that in-sita testing
• at the repository was both necessary
 and sufficient. Others identified what •
 they considered to be flaws in DOE*8
 test pJans—e.g., sealing the alcoves in
 the alcove-scale tests—and argued that
 EPA should--not allow waste tab*
 placed in the repository before those
 flaws were addressed.       ;
   Although EPA believes that DOE has.
 generally laid out A reasonable test
 program for the WIPP.it disagrees with •
• commenters who argue that the Agency
 must find, as part pi today's      ..  •
 determinatMHi, that DOE's test plans are
 necessary and sufficient; Thequestion -
 before EPA & whether there will be any
 migration of hazardous coTistitirents  '•
 beyond the unit boundary for as long as' .
' the waste remains hazardous, riot
. whether alternatives to in-site-testing
 are available,' or 'whether DOE'S testing"
 program has shortcomings. If DOE can- :
 demonstrate-no migration for the-test
 pha se, which EPA concludes it has
 done,-then,it has met the-statutory •  ; .'.   ,
 standard for placement of untreated
 hazardous wastes in the WIPP.
   At the same time, the results of the
 test phase wiB be critical in review of a
 no-migration petition for longr-term    ' • '.
 disposal at the WIPP, if DOE chooses to
 submit one. EPA^ therefore, has put DOE
 on^notice1 that data from the bin and
 alcove tests, must be of good quality. For
 example, if the adequacy of alcove seals
 cannot be demonstrated, any data       .
 derived from the alcove tests will be of .
 questionable value. Similarly, it is
•essential for the long-term finding that
 DOE adequately characterize test waste
 for RCRA constituents. Toward this-endv.
 EPA.has described in somedetail in
 section I V.B.7 of this notice the types'
 and quality of data on waste
 characterization it expeets-to .see is any
 petition forlong-term-disposal.  > . ', :'•'••;
 Howeven for the.reasdns discussed  •    •
 above* the Agency-has concluded that il
 is' not appropriate to address the scope   '
•-or details of DOE*s.test plans in today's. -.
 decision-^except insofar-as they involve •
 possible migration of waste from-the  :  -
 disposal unit or the retxieyabilityof the
•waste." .  • '  ' -     •''•:•'•'. ••"•'•• •'•'  " v .

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  47714
Federal  Register / Vol. 55. No.  220 / Wednesday.  November 14, 1990  /  Notices
  E. Site Suitability
    In reaching its proposed
  determination, EPA reviewed more than
  300 studies of the WIPP site, not only by
  DOE and its contractors, but also by
  independent researchers and groups
  such as the U.S. Geological Survey and
  the Environmental Evaluation Group.
  The overwhebning^conclusion that EPA
  drew from these studies is that the WIPP
  has been located in a remarkably stable
  formation, and that it is a promising site
  for the permanent disposal of •
  radioactive waste. Although there
  remain some questions about the site,
  which DOE will be addressing during
  the test phase, EPA expressed its
  conclusion that the site was sufficiently
  well characterized for the test phase to
  proceed. Thus, EPA agreed with the .
  National Academy of Sciences and
  DOE's Blue Ribbon Panel that it makes
  sense to begin testing in the WIPP
  repository as soon as regulatory
  requirements are satisfied.
   Several commenters on the petition,
  however, raised issues associated with
  the suitability of the WIPP site.
  Commenters, for example, expressed
  concern about the possibility of karst
 formation In the vicinity of the WIPP
 site and the general role of dissolution
 processes in the area; the assumed
 existence of a pressurized brine pool
 below the repository; and the rate of
 brine inflow into the repository. These
 issues are discussed briefly below and
 ore addressed in more detail in EPA's
 Response to Comment document for this
 rulemaking.
   A number of commenters expressed
 concern that the WIPP landscape had
 the characteristics of a karst terrain. A
 karst terrain is a kind of topography that
 is typically formed over limestone,
 dolomite, or gypsum through dissolution
 processes; it is usually characterized by
 closed depressions or sinkholes; caves,
 and underground drainage. The
 Implication for the WIPP, according to
 commenters, is that contamination from
 the repository if it reached the overlying
 Rustler formation, could be transported •
 rapidly to the accessible environment.
 Commenters also suggested that ground
 water in overlying karst formations
 might attack the repository shaft seals,
 after closure, and enter the Salado
 Formation—the salt bed in which the     ;
 WIPP repository has been constructed.
This might lead to dissolution of the
 halite, allowing a potential pathway for
 migration  past the unit boundary.
  The,commenters argument that the
 WIPP area is karstic is based primarily
 on the presence of several
 acknowledged and alleged dissolution
 features in the WIPP area. These include
                        sinkholes in.Nash J}raw, several
                        kilometers from the WIPP site;
                        dissolution featured identified in the
                        WIPP 33 drill hole, just outside the site
                        boundary; and "Barrows Bathtub," a
                        depression about one kilometer from the
                        proposed underground disposal area.
                        Such features; according to commenters,
                        demonstrate that the WIPP site is found
                        in a mature karst area and that wastes
                        can be expected to leak from the WIPP
                        shortly after closure.
                         As a result of commenters' concerns,
                        EPA reevaluated the question of karst in
                        reaching its final decision. This
                        reevaluation included a field
                        investigation of the WIPP site, in the
                        company of one of the commenters. The
                        tour covered the most important
                       features that the commenters believed
                       were karstic in the vicinity of the WIPP.
                       The closest of these was approximately
                       one kilometer from the surface buildings
                       at the facility. On the basis of this
                       review, EPA has concluded that karst is
                       not now an issue at. the WIPP, and is
                       unlikely to become ;one for many
                       thousands of years; if ever.
                         EPA recognizes the presence of some
                       localized; surface dissolution features in
                       the general area of |the WIPP,
                       particularly in Nash Draw. This is not
                       surprising/given th4t the geologic units
                       within the area are 'composed of rock
                       that would be susceptible to dissolution
                       under the correct hydrologic and
                       geochemical conditions. However,
                       evidence suggests that these are ancient
                       features and that current rates of
                       dissolution are extremely slow. For
                       example, dissolution rates at the Nash
                       Draw have been estimated at one-third
                       of a foot every one thousand years, rates
                       that would not threaten the WIPP
                       repository for millions of years. In
                       addition,' the widespread occurrence of
                       caliche—a surface feature indicating
                       arid conditions  and limited surface
                       dissolution-^-rin the WIPP area suggest
                       the stability of the surface landscape
                       over at least the last 10,000 years. At the
                       same time, borings.drilled at and near
                       the WIPP site have failed to encounter
                       solution channels indicative of a karst
                       environment. Finally, it should be noted
                       that the Salado Formation lies 260
                      meters below the surface, shielded by
                      relatively impermeable rocks. Thus, the
                      repository horizon is isolated from any
                      ongoing dissolution, process. The fact
                      that the Salado Fpnnation in the area of
                      the WIPP has remained largely
                      unaffected by dissolution processes over
                      its 225-million-year history is evidence'
                      of its stability. .•.-.;-    •  .
                       ' Numerous commenters -also expressed
                      concern about thte presence and possible
                      effects of pressurized brine in the
  Castile formation underlying the Salado.
  One bore hole in the immediate vicinity
  of the repository—WIPP 12—
  encountered a large brine pocket in the
  Castile. Geophysical measurements
  suggest that this pocket extends
  underneath the repository itself,
  Commenters expressed the concern that
  this brine might, in the long run, threaten
  the WIPP through dissolution processes
  or, if a bore hole were drilled at some
  future date through.the repository into
  the brine pocket, pressurized brine
  might force contamination to the
  surface.
    After reviewing the comments and
  other data in the record, EPA continues
  to believe that the brine pockets in the
  Castile formation—although  they
  contain a substantial amount of fluid—
  do not offer a significant threat to the
  repository. Castile  deformation, which
  led to the formation of the brine pockets,
  was initiated millions of years ago in
  association with major tectonic tilting of
  strata in the Delaware Basin. The region
  is tectonically inactive' at-present,
  implying that new development of major
  Castile features is not occurring. In
  addition, the brine pool is completely
  saturated with respect to halite and
 therefore has no potential to dissolve
 the surrounding host rock. Since the
 Castile and Salado  Formations are
 hydrologically distinct, there  is no
 credible hydrologic connection between
 the two formations. Finally, because of
 restrictions on access, there is no
 realistic possibility  of a borehole
 reaching brine pockets below the
 repository during the, test period.
 Therefore, this issue does not arise for
 today's determination. DOE's
 performance assessment, however, is
 addressing the possible effects of such a.
 borehole after repository closure.
   A number of commenters also
 expressed concern about the effects of
 brine inflow into the repository and the
 validity of permeability values used for
 the Salado Formation. EPA has
 reviewed the information pertinent to
 this discussion and believes that, while
 a good understanding of brine inflow
 into the repository exists, additional
 studies must be conducted to        .
 understand the true  nature of brine     ,
 inflow and to quantify inflow, in a
 manner more indicative of facility
 conditions. These tests will be
 performed during the WIPP test phase.
They will be important in any  decision
 on the long-term acceptability of the
WIPP site. Brine inflow, however, will
not be a problem during the test phase
and thus is not an issue for today's
decision.      '

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                Federal Register  /  Vol. 55, No. 220 / Wednesday,  November 14, 1990'/  Notices
                                                                       47715
   Finally, commenters expressed
 concern that DOE's petition and EPA's
 proposed decision did not fully address
 the long'term closure scenario expected
 at the repository. Commenters cited
 data predicting high rates of gas  '
 generation and argued that this gas
 might delay or prevent creep closure of
 the repository. As a worst case, gas •
 generation exceeding lithostatic  ,
 pressure might fracture surrounding salt
 or threaten the seal system of the   ;
 repository. In fact, DOE, EPA, and other
 groups have recognized that the issue of
 gas generation, and its relation to   ,
 repository performance, must be
 adequately addressed before permanent
 disposal of waste takes place at the
 WIPP. The major purpose of DOE's in-
 situ tests in the WIPP with actual,
 wastes is to explore the issue of gas
 generation. Today's decision will allow
 these  tests to proceed. The Agency
 believes that the end of the test phase is
 the appropriate time for it to 'make a
 determination'of whether the repository
 is or is not suited for long-term disposal,
 since the results of the experiments  "
 performed, during the test phase will
 help quantify gas generation "rates; :as
 well as identify different initigatlve  .
 measures if the rates prove
 unacceptable.        •           ,'.,..

 F. Conditional Determination
   Several commenters took issue with
 EPA's "conditional" approach in its
 proposed decision. EPA's proposed?
' determination was based, on: (1) The .
 finding that hazardous constituents  '
 would not migrate from the disposal unit
 during the test period, and (2) the
 requirement that DOE remove the waste
 at the conclusion of the test period
 unless it could demonstrate that there
 would be no migration over the long-
 term. According to commenters, this
 approach is inconsistent with the
 statute, which requires a finding that
 hazardous gpnstituents will not migrate
 from the unit as-long as the waste
 remains hazardous. The commenters
 argued that, under the statutory
 standard, DOE should be required to
 demonstrate that hazardous,waste
 permanently place in the repository :
 would not migrate from the unit before
 DOE could place any waste ,•   •   .-, ;•
 underground, even temporarily. EPA,
 however, continues to believe that its
 proposed approach is consistent with
 the statute and has not amended its  • ;;
 finding.
   As commenters point out, RCRA
 specifies that'hazardous constituents  .
 must not migrate from the unit .for as
 long as the waste remains hazardous.
 The phrase, "from'the unit" is a key
 element of this standard. If the waste is
 removed from the unit at the end of the
 test period, migration of hazardous
 constituents from the uiu't after that time
 is clearly impossible, because there are  :
 no longer any hazardous constituents in
 the unit to migrate. Consequently, in the
 case of temporary placement, for    -
 example during the WIPP test phase, the
 appropriate question is whether
 hazardous constituents will migrate  •
 during the-period of temporary
 placement. (As discussed elsewhere in
 today's notice, EPA has concluded that
 hazardous constituents will not migrate
 from the unit during the test phase.) At
 the same time, of course, it is important
 to see that removal at the'end of the test
 period is reasonably assured. EPA judge
 DOE's no-migration petition-for the .-
 WIPP on these grounds. (See Section ' ,
 V.G for discussion of this point.)      . .
   One group of commenters argued
 further that, if EPA were to continue
 with its "conditional!' approach, it,
 should review DOE's test plan to ensure
 that in-situ testing at the WIPP was  .
 necessary to demonstrate Iong4erjtn no
 migration and that the specific tests to
 be .conducted would be sufficient.';   ' /. •.
 Although EPA has commented on; DOE's,
 test plan, EPA disagrees, with these  ..
 commenters on the type of EPA review
 that is necessary. On the, basis of its. ,.
 review, EPA has  concluded that DdE's
 test plan is well designed and the testing
 will yield important information on,the ,-•
 long-term performance of tlble repository.
 EPA, hdweveivhas not an4 b.felieve.s tha.t
 it shduld not formally analyze: DOE's in-
 situ testing at the WIPP to determine
 whether it is necessary of sufficient, and.
 it does not believe such an analysis is
 within the scope  of a no-migration •
 review. As long as DOE can
 demonstrate that hazardous constituents
 will not migrate from the disposal Unit, it
 is legally entitled to place prohibited
 waste in the WIPP, There is'ndthing in
 the statute that further compels a  •
 petitioner to demonstrate that placement
 in the unit is "necessary."
 G. Definition of No Migration
   Sections 3004 (d}(l). (e)(l), and (g)(5)
 of RCRA state that land disposal is •'  f  .•
 prohibited, unless "it has been  ••
 demonstrated to  the  Administrator, to a
 reasonable degree of certainty, that
 there will be no migration of hazardous  ••
 constituents from the disposal unit or
 injection zone as long as.the waste
• remains hazardous." In its proposed no-
 migration decision on the WIPP, EPA
 adopted the same interpretation of this
 standard as it had in its no-migration '•••
 regulations for underground injection
 wells; that is, the Agency interpreted the
 standard to prohibit  the migration of   .
 hazardous constituents in
 concentrations 'high enough to render
 the waste hazardous.-(See 53 FR 28122, •
 July 26,1988.) Critics of this approach  .-
 argued that Congress clearly meant that
 not a single molecule of a hazardous   •
 constituent couid migrate from the. unit,
 as long as the waste remaining in the
 unit was'hazardous. Under this . -• >   ,;'
 standard, DOE's WIPP nojmigration-    ,
 petition.could not have been approved,
 because at least some molecules of
 volatile organics listed as hazardous
 constituents will migrate via-the air   '
 route during operations—--although most
 likely-at several orders of .magnitude   • -•
 below levels of detection!        .'•'••
   In today's decision, EPA is retaining
 its proposed definition of "rib migratibn":
 of hazardous constituents. As explained
 in detail in the preamble to the* proposed
 decision, EPA believes that this.  ' '
 approach is fully consistent with the  ' -
 language of the statute and is protective
 of human health and the environment.,
 EPA=also notes that its interpretation of
 "no migration" was recently/upheld in-a
 decision on the underground injection
 Well rules by die U.S. Court of Appeals
 for the District of Columbia.5 (NRD.C v.
 £P4'No. Slip. Op. (D.C. Cir. 1990)0 ¥  ';„.'
 this decision, the Court accepted EPA's
 argument that "no migration of •
 hazardous constituents *;'.*• * for as long",
 •as the waste remains hazardous" may
 be read tp:mean no migration of-.  ,y
 constirttents above hazardous (or
 health-based) levels. As .a. result, EPA ,;.'.;
 has decided to retain the .same standard
 in its finai decision on the WIPP'  : ..    ,,
 petition.     ,  ,
 H. befinition of Unit Boundary     .
   In today's finding, EPA Has slightly.. ,
 modified its-definition of-the disposal • .
 unit boundary in response to;publio ,
 comments. In the propos£l,.EPA defined ,
 the unit boundary (or point of   ,
 compliance) for. .groundwater migration.
 as the Salado Formation, laterally ,
 bounded by the limits of the four-mile by
 four-mile land withdrawal area. For air
 emissions during operations of the, .
 WIPP, EPA defined the unit boundary  as
 the point where the air shaft metthe/ -
 surface.,L  •  , .  ,  -.,.:•'/  .;•-.'   ,-: ;.  •
   Numerous Sommeriters expressed .-•-
; concern about the extent -of .the unit •-.. •
 boundary for groundwater, arguing that;
 it might; allow broad areas of ••   •••   •
 contamination underground;- they. ; ••'  ,
 objected to EPA arguing that there
 Would be no migration from the unit
 even if the hazardous constituents ^'••'-.  •
 moved tip to two miles laterally.- Several
 commenters suggested that the unit
 boundary in no case should be greater
 than the mined repository,-and should  •
 probably be less. One group of

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 47716
^ Federal Register /. Vol. 55. No.  220 / .Wednesday,  November ifl, 1990 /  Notices
 commenters also pointed to what they
 believed was an inconsistency between
 the unit boundary for air and for
 groundwater. They argued that the unit
 boundary should be the same in both
 cases and that the unit boundary for air,
 therefore, should be no farther than the
 top of the Salado. After reviewing these
 comments, EPA has decided to retain its
 definition of the lateral boundary of the '
 unit (i.en the boundary of the land
 withdrawal area within the Salado
 Formation), but to define the boundary
 for air emissions as the top of the Salado
 Formation.
  *EPA has rejected commenters
 suggestion that the unit boundary be
 defined as the mined area (or some
 smaller area). As the. Agency explained
 in detail in its proposed finding, it
 believes that, in the context of a
 geological repository, some credit
 should be given for the surrounding
 formation in which a-waste is placed.
 The purpose of placing waste in a
 geologic repository is to isolate it from
 the general environment; it is not to
 prevent any movement of waste,
 however slight, within that formation. In
 fact, some lateral movement of waste
 into the surrounding formation can be
 an inevitable, and desirable, aspect of
 repository performance—as it is in the
 case of the WIPP. A no-migration
 standard that prohibited any lateral
 movement would run counter to the
 concept of a geological repository,
 without providing for any additional
 environmental protection or protecting
 against any meaningful release.
  In taking this general position, EPA
 believes that it is being consistent with
 the Intent of Congress, for example-as
 expressed in the Senate Report on the
 1984 HSWA amendments: "In
 determining appropriate confinement
 from which migration shall not be
 allowed to occur, the term disposal unit
 or injection zones should be construed
 * '* * !n terms of the  overall integrity of
 the disposal practice, keeping in mind,
 in particular, the potential for
 contamination of ground-water or
 surface water resources" (S. Rep. No.
 284 98th Cong. 1st Seas, at 15). Wastes
 confined to the boundaries of the unit,
 as defined in EPA's final determination,
 would remain more than 1,000 feet from
 the nearest unconfined ground water.
EPA also notes that its position is
consistent with the recent court decision
on its no-migration rules for
underground injection walls. (NRDCy.
EPA No. Slip. Op. (D.C. Cir. 1990).) In
 this decision, the court supported EPA's
position that the term injection zone
(which for underground injection wells
is analogous to the unit) includes
                         confining material surrounding ,the
                         porous formation into which the waste
                         is actually injected. Similarly, EPA
                         believes it is. appropriate to consider at
                         least a portion of the confining salt at
                         the WIPP as ipart of the unit.
                           Ciritics of fiPA's proposed definition
                         of the WIPP unit suggested no
                         alternative boundaries, other than
                         somewhere within the furthest extent of
                         the mined area. As discussed above,
                         EPA has rejected this alternative. In the
                         absence of any rationale for an
                         intermediate;boundary between the'
                         mined area and the proposed boundary,
                         EPA has decided to retain the proposed
                         approach. EPA emphasizes that the
                         WIPP unit, vulder this definition, is fully
                         isolated from the surrounding
                         environment! If waste remains within
                         the unit bouridary, no meaningful
                         movement of waste will have occurred,
                         and no contamination of ground-water
                         resources will result. Further, although
                         there will undoubtedly be some lateral
                        migration of contaminated material
                         along markerj beds within the salt
                        formation,,all projections indicate that
                        this migration will be very limited, in no
                        way approaching the boundaries of the
                        unit. (The mojjt likely route of migration,
                        instead, would be up the closed shafts to
                        overlying formations.) Therefore,
                        extensive underground'movement of
                        waste is not expected, regardless of the
                        definition of unit
                          In the, case of air migration, EPA
                        recognizes thatits. proposed definition
                        caused some confusion. To address
                        commenters' concerns, EPA has
                        amended the Unit definition for air
                        during operations, placing the boundary
                        at the top of the Salado Formation. The
                        issue of where DOE should monitor to
                        demonstrate compliance at that point,
                        however, is a ^different question. (See
                        section IV.B.6 for a discussion of this
                        point!)       '  -

                        /. Waste Characterization
                                    i
                        1. Flammabilijty
                          In evaluating the potential for release
                        of hazardous constituents in its
                        proposed decision, EPA considered the
                        potential for fjre and explosion at the
                        WEPP. The Agency noted that the Waste
                        Acceptance Criteria (WIPP-WAC)
                        prohibits explosives and compressed
                        gases in TRU Wastes and requires that
                        pyrophoric materials be rendered safe
                        by mixing them with chemically stable
                        materials, such as concrete or glass, or
                        be processed to render them
                        nonhazardous. In addition, the Nuclear
                        Regulatory Commission requires that all
                        waste containers, be equipped with one
                        or more carbon composite filters
                        designed to prevent pressure buildup or
 the accumulation of flammable gases
 prior to shipment to the 'WIPP, as
 specified in "TRUPACT-II Authorized
 Methods for Payload Control"
 (TRAMPAC).1* EPA suggested that
 these requirements, in conjunction with
 the maintenance of general ventilation
 in the underground repository, make the
 possibility of fire or explosion extremely
 unlikely.13
   EPA continues to believe that a fire or
 explosion is unlikely. It acknowledges,
 however, the concerns of commenters
 that flammable gases could build up in
 waste containers, creating a fire and
 explosion hazard. The Agency has
 reanalyzed the available information
 and has concluded that the accidental
 ignition of flammable'gases in waste
 containers cannot be ruled out, given the
 available data on waste
 characterization. At the same time, EPA
 has concluded that spontaneous
 combustion within as individual waste
 container, i.e., without an ignition
 source, is not credible.16
   Were a fire or explosion to occur as a
 result of accidental ignition of
 flammable gases in the void space of a
 waste container, retrieval could become
 more difficult, should retrieval be
 necessary. Moreover, such an event
 could itself cause migration of
 hazardous constituents above health-
 based levels beyond the unit boundary.
 For  these reasons, EPA has concluded
 that no waste container should be
 emplaced in the underground repository
,if it  contains flammable mixtures of
 gases in any layer of confinement, or
 mixtures of gases that could become
 flammable when'mixed with air. To
 assure a sufficient margin of safety, EPA
 considers any mixture to  be potentially
 flammable if it exceeds SO percent of the
 lower explosive limit (LEL) of the
 mixture in air.
   EPA,  consequently, is requiring DOE
 to ensure that individual waste
 containers have met the prohibition of
 flammable gases. DOE must implement
 this  provision by testing each waste
 drum or individual container for
 hydrogen, methane, and volatile organic
 compounds (VOCsJ as a class. EPA is
  14 The Agency notes that TRAMPAC also sets
limits on the thermal wattage, i.e., decay heat of
individual waste containers to control the rate of
generation of hydrogen gas by radlolysis (DOE,
Safety Analysis Report for the TRUPACT-II
Shipping Package, Appendix 1.3.7. revision 2, June
1989).
  15 The Agency notes that the WIPP-WAC also
place restrictions on the total quantity of fissile
material in a waste container to ensure criticality
  16 See the conclusions in the Sandia National
Laboratory memorandum from Siezak and Lappin to
Marcer and Fredrickson, January 5,1990.

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                Federal Register / Vol. 55. No.  220 / Wednesday. November 14, 1990 / Notices
establishing this condition because it
does not judge available process
knowledge to be sufficiently reliable or
accurate to allow a determination on the
flammability hazard of individual waste
packages.
  EPA recognizes that headspace testing
of every drum or individual container on
a continuing basis may pose a
significant burden on DOE. Without  •
sufficient data, however, EPA feels
compelled to require that DOE conduct
testing, given the potential
consequences of a fire or explosion.
Once sufficient data have been
collected, however, EPA will consider
the extent to which continued testing is
necessary. Test data may well show
that flammable gases are only present at
levels well below the lower explosive
limit, either for certain wastes (e.g.,
TRUCON content code or item
description code) or from particular. .
generating sites. If the test data in fact
show that no fire or explosion hazard
exists, DOE should submit the data to
EPA and request that the testing
requirement be modified accordingly.
Any change in the terms of this
condition will be made under the
procedures of 40 CFR 268.6(e),.which
include public notice and opportunity
for comment.
   EPA is also requiring that headspace
 sampling be representative of the entire
 void  space of the waste container.
 Initially, the Agency believes that each •
 individual layer of confinement within
 the Container will have to be sampled,
 given the limited data available for    .
 inner bags. EPA, however,  expects that
 once DOE accumulates  enough data, it
 may  be able to 'show that for most
 package configurations  in which bags
 are twisted and taped, similar levels of
. flammable gases will be found in all
 layers of confinement.17 However, it is
 anticipated that the occurrence of
 detectable quantities of free liquids, as
 determined by real-time radiography of,
 visual inspection, will continue to
 indicate the need to sample the layer in
 which it occurs, unless DOE  can
 demonstrate otherwise.
   EPA also believes that testing of
 wastes that exhibit high rates of
 radiolysis should be conducted within a
 relatively short time period of when, the
 container is actually placed
 underground. Otherwise, hydrogen
 levels could build up to flammable
 levels following sample collection and
 analysis. DOE has accumulated
considerble data on radiolysis rates for
various materials in TRU wastes. DOE
used such data in its application to the
Nuclear Regulatory Commission for a
certificate of compliance for the
TRUPACT-H shipping package to
determine the length of time a waste
drum must, aspirate (i.e., vent) before it
can be shipped after retrieval from
storage.18 Similarly, EPA is requiring
DOE to determine, and document, the
length of time during which headspace
gases can be expected to remain below
flammable levels (i.e., 50 percent of the
mixture LEL) after sampling has been
performed, for both newly generated
and retrievably stored wastes, and to
ensure that waste containers! are
emplaced at the WIPP within that time.
  If testing reveals the presence of
significant levels of flammable VOGs,
an explicit flame test must be performed
to determine if a flammable mixture can
be formed with air. American Society
for Testing and Materials (ASTM)
Method E 681-85, "Concentration Limits
of Flammability of Chemicals," or   •
equivalent, are.acceptable test methods.
Significant levels of flammable VOCs
are indicated by measured
concentrations (excluding methane) of
500 parts per million of greater, as
propane, as determined by gas • "...
chromatography.and flam'e ionizatibn
detection (GC/FID) or of 500 parts.per
million or greater, by volume, as
determined by gas chroma.tpgraphy and
mass spectrometry (GC/MS.) i9 If
testing shows that VOCs are
insignificant, i.e., below 500 parts per
million,' the lower explosive limit of the
mixture may be determined from the
lower explosive limits of methane and
hydrogen using the Le Chatelier formula
 as follows: If LELi, and LELa are the
 lower explosive limits of hydrogen and
 methane, resepctively, and Ci and Cz
 are the measured concentrations of
 hydrogen and methane, respectively,
 expressed as volume percent, then if the
 fraction, Ci/LEL> and Gz/LELa sum to 0.5
 or greater, die mixture is considered to
 be flammable when mixed with air.20
   »' EPA notes that DOE intends to open up and
 . disassemble the drums selected for the bin-scale
 tests for visual inspection. Therefore, this
 requirement should hot increase radiation exposure
 to workers.
   18 DOE, TRUPACT-II Content Codes (TRUCON},
 DOE-WIPP 89-004, Revision 3, July 1989, and DOE,
 Safety Analysis Report for the TRUPACT-II .
 Shipping Package, Appendix 1.3.7, Revision Z, June
 1989.
   18 For purposes Of determining concentration
 levels using GC/MS, only noncdmbustible
 compounds may be excluded from the sunj total of
 non-methane VOC. e.g., carbon tetrachloride;  -
 tetrachloroethylene, chloroform, and bromoform.
   20 The lower explosive limits of hydrogen and  .
 methane are 4.0 and 5.0 percent, respectively, in air
 (Bureau of Mines, "Fiammability Characteristics of
 Combustible Gases and Vapors," Bulletin 627,13.65).
2. RGRA Constituents  .

  In its proposal, EPA expressed some
concern with the quality of the .waste
characterization data provided by DOE
in support of its petition. However, given
the nature of the wastes, the safety   . ,
margins between predicted emission:.;   :
levels and health-based levels, arid
required controls on air emissions, EPA: -
concluded that the information provided
by DOE (based primarily upon process
knowledge) was sufficient to
demonstrate, to a reasonable degree of ;
certainty, no migration of hazardous
constituents during the test phase, Many
commenters, nevertheless, criticized the
quality, and completeness of DOE's
waste characterization information and •
DOE's approach to waste    •      :
characterization. Several commenters '
noted the critical role played by waste
characterization in the prediction of no ,
migration arid stressed that-EPA needed
accurate waste descriptions, supported
:by detailed analysis, to evaluated
potential 'evironmental impacts of waste
disposal. In-responding to these
coiiiments, EPA has differentiated
between short-term issues (relevant to
today's decision for the test phase) and
• longrterm issues (relevant to a' decision -,
for the operational and post-closure  .
phases, should DOE submit a petition :
for these phases).               .-'•!•'•'
   a. Short-term issues. Many of the ;
commenters expressed concern with the •:
Agency's acceptance of waste;
characterization data based-primarily '.,
upon process knowledge. Commenters
stated that, in the  case of the WIPP,
waste characterization requirements
have not been met.
 /5 EPA disagrees with the commenters'
 position that DOE's waste
 characterization information is
 insufficent for-a no-migration
 determination for  the test phase. DOE's
 analysis of the wastes'incuded an
 evaluation of the materials and
 processes from which .the wastes were
 generated as.well as actual chemical • •
 analysis of the wastes. In the former
 case-, DOE provided flow diagrams and
 narrative descriptions of the processes
 that generated all,128 of the identified
 waste Content Codes as well as an
 identification of the RCRA hazardous
 constituents used  in the process. DOE
 also provided estimated concentrations
 for each of the hazardous-constituents -
 expected in the wastes. This was  ......
 designed to be a conservative  '•  •  •
 characterization, in which it was
 assumed that any hazardous
 constituents that were used in a process
 would be present  in the resulting waste
 stream,-regardless of known physical

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                         Register /  Vol. 55. No. 220 /Wednesday. November 14, 1990 / Notices
 processes that would reduce the
 likelihood that the constituents would in
 fact be present (e.g., volatilization). EPA
 notes that no comments were received
 indicating that wastes from the.
 processes described by DOE would be
 expected to be compositionally different
 from the DOE-estimated compositions.
   The bulk of the analytical data
 presented by DOE to corroborate the
 conclusions of the above-described
 characterization were focused on the
 only viable route of release during the
 test phase—namely, through the air. For
 this characterization, DOE provided
 results from over 200 headspace
 analyses, representing all four of the
 identified waste types; these samples
 were analyzed for numerous gases,
 including nine organics. Other analyses
 for which results were reported included
 Toxlcity Characteristic and Extraction
 Procedure leaching tests, total volatiles,
 and total metals. While these analyses
 were not typically conducted on all four
 of the waste types, EPA notes that these
 tests are not directly relevant for
 characterizing the most likely route of
 release during the period that is subject
 to today's decision (i.e., the test phase).
   Additionally, EPA in its proposal
 considered the "safety margin"
 indicated by calculations of air
 emissions. That is, even if the
 concentrations of hazardous
 constituents were significantly
 underestimated, the no-migration
 standard would still be met during the
 test phase.*1 Additional assurances are
 provided by the air monitoring systems
 that will be operated to allow detection
 of emissions. Based upon the safety
 margin indicated by these factors;-the
 Agency concludes that the level of
 waste characterization is acceptable for
 the test phase. Nevertheless, to ensure
 that the wastes to be used in the
 binscale tests are similar in composition
 to those described in the no-migration
 petition. EPA is requiring that DOE test
 the headspace of the wastes shipped to
 the WIPP (as a measure of the waste
 constituents' propensity to migrate
 through air) and compare the results to
 the values provided in DOE's no-
 migration petition. This comparison
 must be conducted and the waste must
 be found to be compositionally similar
 before the waste can be sent to and
 emplaced in the WIPP; if the waste is
 not similar to the estimated
•concentrations provided in the no-
 migration petition, the waste cannot be
 shipped to the WIPP unless it is
  11 The safety factor assumes that an explosivity
hazard U not present. To ensure against such a
hazard. EPA placed «n additional condition on the
dectilan (XCB icctlon IVJ3.7J.
modified compositionally, such that it is
compositionally similar. The details of
this comparison are described in section
IV.B.7.b of today's notice.'
  Other commenters stated that, to the
extent that DOE has provided any
laboratory analysis of wastes intended
for the WIPP, if is solely headspace
analysis (i.e., ahalysis of the
constituents' concentrations in,the air
under the lid of the drum) used as a
surrogate for th'e waste in the drum.
These commenters maintained that
headspace analysis, while extremely
useful for homogeneous phases,  is
limited, at best^ for analyzing
heterogeneous (wastes such  as those
intended for th£ WIPP. In the opinion of
these commenters, headspace analysis
is unreliable as a surrogate for direct
analysis of liquids and solids in  drums
due to uneven partitioning of
constituents.
  The Agency recognizes that there are
limitations on the  utility of headspace
analysis as a surrogate for analysis of
waste composition. Certainly headspace
analysis is not Appropriate for all
evaluations for; all waste types. In some
cases, however,, headspace analysis is
the most relevant  measurement.  For
purposes of the test-phase
determination, headspace analysis is
primarily used ui the evaluation  of gas
generation and explosivity hazards.
Since it is the composition of the gas
that is of conceal, analysis of the
headspace (/.a, the actually evolved
gas) is the mos| appropriate parameter
to consider. If concentrations in  the
waste were used for the explosivity
evaluation, the [composition of the
evolved gas would be modeled, or
predicted, rather than actually   ,
measured.     [ •  -
  EPA agrees with the commenters'
concerns regarding the validity of a
single headspace sample (under  the lid)
as representative of potentially evolved
gases from heterogeneous wastes. This
is especially problematic when the
drums contain several inner layers of
confinement, as do the drums that will
be emplaced in; the WIPP. Specifically,
questions exist as to whether the
headspace benfeath the lid is
compositionally different from the
headspace in the inner layers, .EPA is
addressing this issue hi the context of
the testing condition related to
headspace analysis. In that condition,
EPA is requiring that DOE take
representative samples of the headspace
(which may require, in some cases, for
DOE to take samples from inner  bags)
and analyze them  to confirm its
assertion that the headspace beneath
the lid is, in fact, representative of the
total evolved gas within the drums.
  EPA also agrees that headspace
analysis is not a suitable surrogate for
direct analyses of the waste for     '
purposes of evaluations where the total
composition is a factor. However, for
volatile organic constitutents, EPA
believes that headspace  analysis can be
a useful tool for determining whether the
constituents are'present. That is, if a
volatile constituent is present in the
waste, it is reasonable to assume that it
will also be present in the headspace.
Accordingly, results from headspace
analyses were used to confirm the
presence of volatile hazardous
constituents, not to quantify their
concentrations in the wastes.
  Several commenters argued that
DOE's quality assurance/quality control
of waste characterization data was
deficient. Others noted that DOE had
been unable to provide adequate
sampling plans and sample handling
procedures for analytical work. EPA
raised similar concerns with DOE's
procedures, but, for the reasons
described in the proposal and further
elaborated upon above, the Agency has
concluded that the data are sufficient for
the test phase demonstration. At the
same time, EPA advises DOE that it
expects additional analytical data to
support a long-term demonstration,
where significantly greater quantities of
waste are involved and routes of
possible migration are not limited to
release of volatiles to the air during
operations.
  b. Long-term issues. EPA notes that
the "safety margin" for the long-term
showing {i.e., the operational and post-
closure phases) has not been
determined. For. that reason, the Agency
believes that additional waste
characterization data are needed to
reduce the uncertainties before a
decision on a long-term no-migration
determination can be made. EPA,
however, has decided not to make such
testing a condition of today's decision,
because the collection of such data is
not relevant to the decision during the
test phase; EPA, however, expects DOE
to develop and implement waste
characterization plans, including
appropriate sample collection,
preservation, and analytical procedures,
that will allow a demonstration of the
extent to which the test phase wastes
are representative of the other wastes
from the ten generating sites and that
allows greater precision in  estimating
potential for long-term migration (e.g.,
through routes such as ground water). If
such data are not collected, EPA will not
be in a position to approve a no-   •

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                Federal Register / Vol. 55, No.  220 / Wednesday. November 14, 1990./  Notices          47719
migration petition for the operational
and post-closure phases, if DOE submits
such a petition. EPA's expectations
related to these data are presented in
Section IV.B.7.b of today's notice.
  Many commenters expressed
concerns regarding the extent to which
the wastes that will be used for the test
phase are representative of the other
wastes that DOE wishes to emplace at
the WIPP during the operational phase.
It was  stated by many commenters that,
for the test phase, adequate waste
characterization is vital to assure that
tests will be performed on
representative wastes. Commenters
pointed out that almost 70 percent of the
wastes proposed for storage do not yet
exist. They asked what controls and
safeguards were in place to ensure that
these future wastestreams are
adequately represented by existing
wastes.
  The Agency agrees with commenters'
concern that the use of representative
wastes in the test phase will be critical
to the success of any DOE no-migration
petition for the later (operational and
post-closure) phases. More specifically,
the test-phase wastes must be
sufficiently representative of the other
wastes that DOE wishes to emplace at
the WIPP to allow extrapolation of data
from the test-phase experiments to the
behavior of the other wastes.22 This
issue is, in fact, the basis for the
selection of wastes that will be used in
the test phase experiments. The
selection process will be based upon
those parameters that contribute to gas
generation and is designed to identify
wastes that represent the spectrum of
expected values for those parameters.
Since waste selection and
characterization, as part of the design of
the experiments, is the responsibility of
DOE, EPA believes that it is DOE's
responsibility to establish and
implement procedures to demonstrate
that the wastes are, in fact, sufficiently
representative.
  Many commenters also argued that
EPA's proposed decision did not clearly
establish whether all waste analysis
data would be provided to EPA prior to
emplacement of any waste or whether
the data would be provided
incrementally as waste is being
emplaced. These commenters stated
that they had serious concerns if the
Agency is proposing to allow DOE to
  22 It should be noted that, if one or more wastes
that are generated at any of the DOE sites are not
"represented" by the test wastes, these wastes
could not be sent to the WIPP without further
evaluation. However, this would not invalidate the
testing for all other wastes that are generated at the
ten DOE sites and are represented by the test
wastes.
provide waste analysis data
simultaneously with waste
emplacement. They argued that waste
analysis should be provided to the
Agency not only before the waste is put
into the 'ground, but before EPA can
make a decision about a no-migration
variance. They believed that this
condition would allow EPA
independently to asses the quality of the
data. In the opinion of some
commenters, delivering waste analysis
information while the waste was "riding
the Carlsbad elevators" would
essentially render EPA's independent
technical review of the data
inconsequential.
  EPA is not requiring that DOE submit
the analytical data on the test waste for
EPA review before the test wastes are
emplaced. Much of the analytical work  .
to be conducted by DOE is related to the
eventual demonstration of no-migration
over the long term. Since EPA will
evaluate these data as part of any
subsequent petition for the later phases,
EPA disagrees with the commenters'
statement that this evaluation will be
"inconsequential." Rather, it will be a
critical element of that evaluation.
  EPA, however, is requiring DOE
during the test phase to .evaluate
headspace data before waste is placed
in the repository, as described earlier.
For example, DOE must evaluate the
explosivity-related testing before
shipping test wastes to the WIPP.
Similarly, DOE must compare the
analytical results of newly conducted
headspace analyses to the waste
characterization data in the no-
migration petition before the waste is
emplaced in the underground repository.
Because the standards for both the
flammability and the RCRA constituent
analyses are objective and
straightforward, EPA does not believe
that Agency review of the data before
placement is necessary.
  The flammability and RCRA
constituent requirements, described in
detail in section IV.B.7, will address
many of the commenters' concerns with
the accuracy of the data. These
requirements will also ensure that the
wastes emplaced during the test phase
are. in fact, the wastes characterized by
DOE in the petition and evaluated by
the Agency and the public.

/. Retriev.ability
  Commenters  also raised concerns
about whether waste would ever be
retrieved from the WIPP if it were
placed in the repository, regardless of
the technical feasibility of retrieval.
Some questioned DOE's commitment  to
retrieval, even if the WIPP site proved
unacceptable. Others argued that, even
if DOE were willing to remove the   '
waste, no other site would accept it, and
therefore the waste would not be
retrieved. Several commenters.argued
that DOE should identify a permitted
site ready to receive retrieved waste
before any waste should be allowed
underground.
  EPA believes that it has placed
adequate safeguards in today's
determination to ensure that DOE in fact
removes the hazardous waste from the
repository, if it cannot demonstrate the
repository's long-term acceptability.
Condition 3 in Section VI of today's
determination explicitly requires
retrieval of wastes if DOE cannot
demonstrate compliance with the
standards of 40 CFR Part 268 before the
expiration of the petition approval.
Failure on the part of DOE to remove
wastes under these circumstances
would constitute a violation of the terms
of EPA's determination, leading to
possible enforcement action by EPA. In
addition, citizens could sue DOE under
section 7002 to enforce retrieval of
waste from the repository.
  Because of this condition, EPA has not
found it necessary to require DOE to
identify a specific site where waste
retrieved from the WIPP would be
stored, or to require that a permit be
granted for storage of retrieved waste
before any waste is placed underground.
Furthermore, EPA questions whether
any such condition would be useful,
given that wastes would probably not
be removed (if removal proved
necessary) for a five-to-ten year period.
Current predictions on the best storage
site for the waste up to ten years in the
future would be at best open to
question, and valuable permitting.
resources would be expended on a site
that might never receive the waste.

K. Human Intrusion
  Commenters generally accepted that
DOE could maintain institutional
controls over the test period to preclude
human intrusion. One group of
commenters, however, argued that EPA
must consider the possible effects of
human intrusion in the distant future
before allowing the placement of any
waste for testing. These commenters
expressed particular concern about
potential mineral resources at the WIPP
site, and the possibility that knowledge
of the site would disappear after
decommissioning. Other commenters.
argued that permanent markers should
be erected at the WIPP site once the
facility is closed, and information
regarding the type and location of the
markers should be published.

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                                      ..•             , I

                 «••••.! Register  /:Vo1- 55,  No, 220  /Wednesday. November 14, 1990  / Notices
  ..EPAgenerally believes,that the issue
 of human intrusion is a long-term
 question, .not relevant to the short-term
 operation of the WlPP during the test
 and operational phases. In the short--
 term, DOE management of the site and
, RCRA permit controls will ensure  .  •
 limited access. Long-term issues would
 be addressed at the time a petition is
 considered for permanent disposal. For
 this reason, EPA disagrees with
 commenters who argue that it must
 consider human intrusion in the distant
 future before allowing any testing at the
 WIPP.                •   '
  , More generally, EPA believes that, in
 the context of RCRA no-migration
 decisions, it should address the question
 of human intrusion by considering the
 likelihood of the intrusion, and imposing
 controls to make such intrusions
 unlikely. EPA agrees that permanent
 markers will be necessary (in fact, they
 are required under 40 CFR part 191
 subpart B) and that information on the
 markers should be published. These
 issues will be addressed in any no-
 migration decision allowing permanent
 disposal.
  In its final determination, EPA has
 removed one proposed condition related
 to human intrusion. In the proposal, EPA
 required that "DOE certify to EPA that it
 has secured control of the entire surface.
 and subsurface estate at the WIPP site,"-
 This condition is now moot,'because
 DOE has now secured control over Jail'
 oil and gas and mineral leases at the
 site. EPA has placed documentation of •
 this fact  in the record for this
 rulemaking. Thus, because the condition
 has been satisfied, EPA has dropped it
 from its final determination.

 VI. Conditions of No-Migration
 Determination                    '

  As  a condition of granting DOE's no-
 migration petition, EPA is requiring that
 the following conditions by met by DOE:
  (1) No wastes subject to this
 determination may be placed in the
 WIPP repository for purposes other than
 testing or experimentation to determine
 the long-term acceptability of the WIPP;
In accordance with 40 CFR 288.6(e],
 DOE must notify EPA before it conducts
any testing or experimentation not
within the scope of the "WIPP Test
Phase Plan: Performance Assessment,"
April  1990 (DOE/WIPP 89-011, Revision
O), as further explained in Section
IVJ3.1 of this notice. Placement of waste
for thp purpose of conducting an
operations demonstration is prohibited.
  (2) Wastes placed in the repository
may not exceed 8,500 drums or 1 percent
of the total capacity of the repository, as
currently planned.
   (3) All wastes placed in the WIPP
 must be remoWd if DOE cannot
 demonstrate compliance with the
 standards of $0 CFR 268.6, before the
 expiration of this petition approval, with
 respect to permanent disposal of mixed
 waste in the repository. DOE must
 submit-a detailed schedule for retrieval
 of the waste, jhncluding times for
 completing rejtriev.al as quickly as
 reasonably feasible, no later than six
 months after a determination that the
 repository cannot meet standards for
 long-term disposal under 40  CFR 268.6 or
 six months before the expiration of this
 petition approval,'whichever occurs '
 first.       . I  .            ".-.•.
   (4) All wastes placed in the WIPP
 must be placed in a readily retrievable
 manner, as described in section iV.B.4 of
 thisnotice.
   (5) DOE mu'st install and operate a
 carbon adsorption device designed, to
 achieve a control efficiency of 95
 percent in the; discharge, system of the
 bin experiment rooms. DOE  must
 monitor the control device outlet      :
 airstream in accordance with the •
 monitoring plan described in section
 rv.K of EPA's [proposed decision (55 FR ,
 13089) as amended by section IV.B.7 of
 today's notice^ and it must maintain
 design and operating records as ,    . :
 described in section IV.J of EPA's
 proposed decision, as amended by -
 sectionTV.B.6!of today's notice. Records
 must be maintained at the WIPP facility
 for the term of this determination or for
 three years after they'are created,   '  •
 whichever is longer. Records must also
 be maintained during the course of any
 enforcement actions for which they are
 relevant;  .'[-..      -  '•.   '•....
   (6) DOE must implement the air
 monitoring plan described in section
 IV.K of EPA's (proposed decision (55 FR
 13089). as amended in section IV.B.7 of
 today's notice, Records,must be
 maintained at the, WIPP facility for the
 term of this determination or for three
 years after they are created,  whichever
 is longer. Records must be maintained
 during the course of any enforcement
 action for .which they are relevant..
   (7) Conditions relating to waste
 analysis:     :            ;
   (a) DOE must ensure that each waste
 container emplaced underground at the '
 WIPP has no layer of confinement which
 contains flammable mixtures of, gases or
 mixtures of gases that could become
 flammable when mixed with air. This
 prohibition must be implemented by ;
 analytical testing of a representative
'sample  of headspace'gases from each
 waste drum of individual container, as
 described in- sedtion IV.B.7.a  and V.F.l.a
 of today's notice.
   (b) DOE must analyze representative
 samples of the headspaces of containers
 to be usedjn the bin-scale test and
 compare these results to the estimated
 compositions provided in its petition for
 each waste type, as detailed in IV.B.7.b
 of today's notice. If the waste is not
 compositionally similar, as defined in
 Tables 2 and 3 in IV.B.7.b, that waste
 cannot be shipped to the WIPP until the
 waste has been treated or modified such
 that it is compositionally similar to the
 estimates provided'in the no-migration
 petition. In addition, as prescribed in
 IV.B.7.b, DOE must demonstrate the
 comparability of bin-scale wastes to
 wastes described in DOE's petition
 before placing waste in the WIPP for the
 alcove tests.
   .(c) Waste analysis records must be
 maintained for the term of .this
 determination or for three years after
 generation, whichever is longer. Records
 must also be maintained during the
 course of any enforcement action for
 which they are relevant. The records
 may be maintained at .the generating site
 or at the WIPP facility^ ''.
   (8) DOE must provide to the EPA
 Office of Solid Waste and EPA Region .
 VI annual written reports  on the status
 of DOE's performance assessment
 during the test phase. These reports
 must include: A description of the tests
 to date and their  results, modifications
 to the test plan, a summary of DOE's
 current understanding of the repository's
 performance, waste characterization
 data from pre-test waste     *
 characterization,  and an annual
 summary of air monitoring data required
 in Item 6 above.      ,      .      .
   Beyond these specific conditions, the
 wastes placed by DOE in the WIPP and
 DOE's activities under this Variance
. must be consistent with those described
 in the petition. Under § 268.6(e), DOE
 must notify EPA of "any changes in
 conditions at the  unit and/or
 environment that significantly depart
 from the conditions described in the
 Variance .and affect the potential for
 migration of hazardous' constituents
 from the unit*  *  *  ."If the change is
 planned, EPA must be notified in writing
 30 days in advance of the change; if it is
 unplanned^-EPA must be notified within •
 ten days.              ,    :
   Under § 2G8.6(f), if DOE determines
 that there has been migration of
 hazardous constituents from the
 repository in violation of part 268, it
 must suspend receipt of prohibited
 wastes at the unit and notify, EPA
 within ten days of the determination.
 Within 60 days, EPA is required to
 determined whether DOE may continue
 to receive prohibited waste in the unit

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                Federal Register / Vol. 55, No.  220 /Wednesday. November  14, 1990 / Notices
and whether the variance should be
revoked.
  Finally, under § 268.6(h), the term of
today's petition approval runs for ten
years, that is until November 14, 2000.
  Dated: October 31,1990.
Don R. Clay,
Assistant Administrator for Solid Waste and
Emergency Response.    ' •
{FR Poo. 90-26836 Filed 11-13-90; 8:45 am]
BILLING CODE 6560-50-M .

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