&5WFR-87-011
Thursday
July 9, 1987
Part II
*    •                  .

Environmental

Protection  Agency

40 CFR Parts 264 and 270
List (Phase 1) of Hazardous Constituents
for Ground-Water Monitoring; Final Rule

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<  • f«M
va?#;.fc *;.*•'•<
                               /  Vol. 52.  Nc. 1.51  / Thursday, July 9, 1087 / Rules and Regulations
      i JUMgNTTAH PROTECTION
40 <-,*a Fasts* 7.S4 and 270

[FSL is 199-3]

Us* (Phase 1) of Hazardous
Constituents for Ground-Water
Monitoring
AGENCY: U.S. Environmental Protection
Agency.
ACTION; Final rule. _

SUMMARY: The Environmental Protection
Agency is today amending its
regulations concerning gound-water
monitoring with regard to screening
suspected contamination at land based
hazardous waste treatment, storage, and
disposal facilities. The amendments
-«place current requirements to analyze
for all Appendix VIE constituents with
new requirements to analyze for a
specified core list of chemicals plus
those chemicals specified by the
Regional Administrator on a site-
specific basis. The Agency proposed
today's amendments on July 24. 1986.
DATES: These- final regulations- become
effective on September 28, 1987 which is
six months from the date of
promulgation, as RCRA Section 3010(b)
requires.
ADDRESSES: The official record for this
rulemaking (Docket No. F-87-AX9F-
FFFFF] is located in the RoomMLClDO,
U.S. Environmental Protection. Agency,
 •)1M Street SW.. Washington. DC  '
£0460, and Is available for viewing from
3:00 a.m. to 4:00 p-.rnw Monday tlirough
Friday, excluding legal holidays. Call
{202) 475-9327 for appointments. The
public may copy a maximum of 50 pages
3 f material from any one regulatory
docket at no cost Additional copies cost
$.20/page.
FCR FURTHER INFORMATION CONTACT:
For general information about this
rulemaking contact the RCRA Hotline,
Office of Solid Waste (WH-562). U.S.''
Environmental Protection Agency, 401 M
Street, SW., Washington. DC 20460 (800)
424-9346 (toll free) or (202) 382-3000 in
the Washington, D.C. metropolitan area.
  For information on specific aspects of -
this rule contact: Jerry R. Carman, Office
of Solid Waste (WHr-seSE), U.S.
Environmental Protection Agency, 401 M
Street, SW.. Washington, DC 20460 (202)
382-4658.
                           33. Origin of Today's Pica! Ru!e
                         IV. issue* Diseuaae-i in Proposed Rale
                           A. Borderline Chemicals
                           B. Dioxia
                           C. Ground-Water Chemistry
                           D. Discretionary Additions
                           E. Ordering of Appendix IX
                           F. Representatives of Categories
                         V. Analytical Methods
                         VI. Nature of List
                         VII. State Authority
                           A. Applicability of Rules in Authorized   '
                             States
                           B. Effect on State Authorization
                         VIII. Effective Date
                         IX. Executive Order No. 12291 and Regulatory
                             Impact Analysis
                         X. Regulatory Flexibility Act
                         XL Supporting Documents
                         XIL List of Subjects in 40 CFR Part 264 and
                             270
SUPPLEMENTARY INFORMATION:
Preamble Outline
L Authority
tt. Summary of Today's Final Rule
HI. Background
 A. Regulatory Framework
                         L Authority
                          • These regulations are being
                         promulgated under the authority of
                         Sections 2002(a). 3001,3004, and 3005 of
                         the Solid Waste Disposal Act, as
                         amended. 42 U.S.C. 6912,6921.6924. and
                         6925 (commonly referred to as RCRA).
                         II. Summary of Today's Final Rule
                           Today's rule creates a new list of.
                         analytes for RCRA: Appendix IX to 4Q-
                         CFR Part 264. This list is required only .-.
                         for ground-water monitoring at RCRA  ~ •
                         land based hazardous waste disposal
                         units. This final rule, in concert with the
                         regulations already in place, will require
                         that an analysts of aU the constituents fn'
                         Appendix DC to Part264 be performed...
                         OB the ground water taken from weQs _
                         surrounding those units. This analysis
                         takes place when ground-water
                         contamination is first detected, and men
                         again once per year (see 40 CFR Part
                         264.SubpaxtF).
                         liL Background

                         A Regulatory Framework         '•  ...
                           Subtitle C of the Resource
                         Conservation and Recovery Act of 1978
                         (RCRA) creates a comprehensive
                         program for the safe management of
                         hazardous waste. Section 3004 of RCRA
                         requires owners and operators of
                         facilities that treat, store, or dispose of
                         hazardous waste to comply with  .
                         standards established by EPA that are
                         "necessary to protect human health.and...
                         the environment;" Section 3005 provides
                         that owners and operators of certain
                         facilities that apply for a permit and
                         comply with applicable notice
                      ""requirements may operate until a permit
                         determination is made. Facilities in this
                         category are said to be operating under
                         "interim'status". Owners and operators
                         of interim status facilities also must
                         comply with standards set under Section
                         3004.
   SPA promulgated standards for
 protecting ground water from releases of
 hazardous wastes from treatment,
 storage, and disposal units at interim
 status facilities in 1980 [45 FR 33154
 (May 19,1980)). codified in 40 CFR Part
 265, Subpart F, and permitted facilities
 in 1982 (47 FR 32274 (July 23.1982)),
 codified in 40 CFR Part 264. Subpart F.
 Both programs require owners and
 operators to sample ground water at  "*
 specified intervals to determine whether
 or not hazardous wastes or constituents
 from the facility are contaminating
 ground water. As explained in more
 detail below, these sampling procedures
 have generated criticism.
   The regulations promulgated on May
 19,1980 set forth criteria for identifying
 "hazardous" waste. To assist in this
 identification process. EPA developed a
 list of chemicals". . .  . that have been
 •shown in reputable scientific studies to
 have toxic, carcinogenic, mutagenic, or
 teratogenic effects on humans or other
 life forms . . . ." (45 FR 33107, May 19,
 198GJ~This list was published as
 Appendix VIII to Part 261 of the
 regulations.
  . The Appendix VIII list is actually a
 'composite of several other lists. It
 includes chemicals identified as priority
 pollutants under the Clean Water Act.
 chemicals identified by the Department
 of Tnnsportation as hazardous to
. transport, chemicals for which EPA's
 Carcinogen Assessment Group (CAG)
-•ha» Faboratory evidence of    ;
 carcinogenicity, and chemicals which
 theNIOSH Registry of Toxic Effects of
 Chemical Substances lists as having
 high acute toxicity (numerically low
 LD»J.
   The principal purpose of the list is to
 define a universe of chemicals of
 concern. Wastes would be matched
 against the list to see if they contained
 any chemicals from this universe. If so.
 they would be considered for listing as
 "hazardous".
   Appendix VIII deliberately included
 many/listings that are large categories of
 chemicals. Chemicals were listed on
 Appendix VIII as they would exist in a
 pure state, as opposed to the forms they
 would be expected to take after being -
. dispersed in the environment. For waste
 identification purposes these
 characteristics of Appendix VIII may
 not present a problem. In looking for
 hazardous waste, EPA emphasized
 breadth of coverage. No attempt was
 made to examine factors such as
 amount of production or environmental
 fate in compiling Appendix VIII.
 although the hazardous waste listing
 regulations require EPA to consider such
 factors before listing a waste because it

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            Federal Register / Vol. 52, Kw. 135 / T^rsda^, juiy 9, -198? / Rales aisd Regulations      25§i3
contains an Appendix ₯111 ahessica! (see
40 CFR 2Sl.ll(a')(3j). As & result,
Appendix VII! contains both prevalent,
r.:ebile, and toxic chemicals that present
major risks in ground water at
hazardous waste sites {e.g.,
triehloroethylene), as well as chemicals
which do not present such risks (e.g.,
aflatoxins) because of factors such as
low prevalence or instability in water.
  Qn Juiy 26,1982, EPA promulgated
RCRA regulations that implemented a
strategy for ground-water protection for
land-based hazardous waste
management units operating under
RCRA permits. Ones ground-water
contamination is suspected, the strategy •
requires an analysis to determine the
nature of the contamination. This • •  -
information is used to assess the
problem, determine the appropriate  •';.
remedy, determine when the remedy "is-
effective, and insure that no new
problems arise during the time the  '.
remedy is being applied. In an attempt
to be comprehensive, the regulations
required that contaminated ground.. -.  •
water be analyzed for all constituents
contained in Appendix Vffl to Part 281.
  While appropriate for hazardous .-.-•• .
waste listing purposes, the Appendix  , - •
VIII list has presented a number of 7
problems when used for purposes of ".".'
ground-water monitoring. These include
practical analytical problems such as ",. *
listings which are large categories of •_*; -.'
chemicals, the dissociation or acjpal -~ ••
decomposition of many Appendix VTTI
constituents when placed in water, and
the lack of analytical standards or
analytical screening methods for many
constituents.     • • '-   - -• '.  - /-."'•.  -
  EPA .has been aware of potential
analytical problems with "Appendix
VIII analysis" for some time. At the tune
of promulgation of the. 1982 regulations,.
EPA acknowledged that it lacked
analytical methods for nine of the •
Appendix VIII constituents {see 47 FR
32296, July 26,1982). When owners and
operators of hazardous waste facilities
began to attempt Appendix VIE •
analyses,:however, EPA teamed that
analysis would be extremely difficult or
impossible for a larger number 'of
constituents. '-     •
  EPA took several actions intended to
mitigate the problems. For example, EPA
recommended the use of enforcement
discretion for some of the most •   •-   -
intractable problems it had identified at
the time. .Also, in 1984.- EPA proposed to
eliminate 22 Appendix VIII constituents
from the ground-water-analysis
requirements (see 49 FR 38786, October
1,1984).  .
  Comments on the October 1984
proposal raised questions about a -  .
number of additional analytical....
 problems. Also, EPA gathered further
 information from interactions between
 RCRA permitting authorities, RCRA"   ?
 facility owners and operators, and
 analytical laboratories. SPA's owa
 experience with grasmd-water analyses
 for its ground-water monitoring task
 force and its analytical methods
 development work confirmed many of
. these problems. These experiences™—"*•*•
 demonstrated to EP&tsiaf analytical
 problems with Appeadix Vffl were far
 more serious than previously believed. It
 became dear that a major change was'
 required.
 ft Origin of Today's Final Rule.
   In response to this need. EPA...
 convened a meeting on December 10-13,
 1985. of some 30 technical experts
 representing EPA and State offices and
 laboratories. Many of these experts had
 advanced degrees in chemistry aad/qr
 substantial laboratory experience. Over
 four days, they evaluated all of
 Appendix VIII with regard to the  • • •
 feasibility of analysis of the various  .
 constituents. They identified a list of
•specific chemicals, derived from :.-.•-••- .
 Appendix VUL which they considered -
 generally suitable for ground-water -
 analyses at afl facilities. They .: '-•:'•
 recommended that 25 chemicals,
 routinely analyzed in ground water by
 the Superfund office, be added to the list
 for analysis.     "'.'•".    •..',',.  ,  -  •"
. •  The results of this meeting, and •
 subsequent work by the Agency, were
 summarized in a Notice of Proposed, •
 Rulemaking on July 24,1986 (see 40 CFR
 26632). Today, EPA is finalizing that  .
 proposal. The reasoning behind, the final
 rule is the same as that discussed In the
 proposal. Appendix IX to Part 264 is
 made  up of those compounds on
 Appendix VDI to Part 261 for which it is
 feasible to analyze in ground-water
 samples, plus 17 chemicals routinely
 monitored in the Superfund program.
   Fifteen of the 17 chemical entities
 included from the Superfund program
 are organic chemicals, the other 2 (tin
 and cobalt) are metals. These 17 exhibit
 varying, but significant, degrees of
 toxicity. All of them have the potential
 to adversely effect human health or the
 environment, and are therefore of value
 for monitoring at RCRA facilities. The
 docket for this rulemaking contains
 information, or references to publicly
 available information, that demonstrates
• the toxic or hazardous potential of these
 Superfund additions.   	
•  One of the Superfund compounds
 (benzoic acid) which was on the
• proposed Appendix IX is not on the final
 Appendix IX because there is currently
 no acceptable screening method for it-
 Benzoic acid requires a derivatization •
 before ii will yield itself to gas
 chromotographic analysis. The Test of
 the Superftmd additions to Appendix IX
 are readily aasenable to analysis.
   The other 7 Superfund items that were
 a par* of the proposed Appendix IX and
 are not a part of the final Appendix, are
 relatively noa-toxic inorganics. These
 are addressed below under "Ground-
 Water Chemistry",            "" '
   The majority of the data evaluated for
 this rule are contained in background  •
 documents for the July 24,1986,   ~
 Proposed Rulemaking. However, during •
 the public comment period of this - •
 proposed rulemaking, EPA received
 more data concerning the feasibility of
 •analyzing certain Appendix VIII
 constituents in ground water. This 'data
 was evaluated on December 11,1988, at
 a meeting of analytical experts. A list of
 the attendees of this meeting, the new "
 data received by EPA since the
 proposal, and the group's decision
 concerning the feasibility of analysis,
 are contained in background     .  •
 documentation for this rale.

 IV. Issues Discussed in Proposed Rule •" -•

   in addition to solicitaiing comment on
 EPA's overall approach, the July 24,1986
 Notice of Proposed Rulemaking, raised
 six specific issues for comment The    .
 following is a brief descriptioa of these
 issues, the  comments received on -each, .
 aad the Agency's response to those   '  -
 'comments.

 A. Borderline Chemicals  • -     . 7' ;„ .

   In the July 24.1986 proposal EPA>  :."
 listed 48 chemicals for which the  ..--•;..
 Agency had conflicting data pertaining
 to their analytical feasibility. A few..."  .
 coramentors supplied new data or an  '
 opinion about these compounds. The
 new data was evaluated at the
 aforementioned December 11,1988  -
 meeting of analytical experts. A
 decision was made as to whether or not
 each chemical belonged on the final..
 Appendix IX based  on the criteria.   •
 discussed in the proposal (see 51 FR
 26835-36). In sum. five of the  compounds
 not on the proposed Appendix IX, but
 listed as borderline, have been added to
 the final Appendix IX because it was
 determined that they were amendable to
 the analytical screening methodologies.
 Likewise, thirteen of the borderline
. chemicals that were on the proposed
. Appendix IX have been removed from"
 the final list because new data had
 demonstrated that they were not
 suitable for screening analysis. The
 background documentation for this final '
 rule elaborates upon those-decisions.    •


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             Federa1  Register /  Vol. 52,  No. 131 / Thursday, July 9. 1987 /Rules
B, Dioxin
   Although, the proposed Appendix IX
contained polychlorinated dibenzo-p-
i.,,:xm3. the proposed rulemaking
 ^.jstioned whether requiring the
 ,;• ;tlysis of these dioxins presents a
human health or environmental risk in
Haelf. Several of the comments EPA
received during the public comment
,-ji.uit agreed that requiring these
analyses did pose a threat to human
health or the environment However,
none of the commentors supplied any
new data concerning this issue.
Therefore, given that dioxin analyses
t.re currently performed in a number of
laboratories with seemingly little
adverse effects, and that numerous other
 ""ghly toxic chemicals are commonly
 •vorked within laboratories, the Agency
has concluded that requiring dioxin
analysis probably does not constitute a  .
significant envronmental hazard in
 tself. Therefore, since it is feasible to
 :,ialyze for these dioxins in ground
 .vater, they remain on Appendix DC It
should also be noted that many  '
commentors thought that dioxins should
.iot be on Appendix IX because they are
rarely, if ever, found in ground water.

C. Ground-Water Chemistry

   In the July 24,1988 proposal, EPA'
discussed the presence of some
constituents on the proposed Appendix
 JX lltat were generally non-toxic- These
  hemical species were either derived
 from Appendix Vffl (e.g^ sodium from.
sodium cyanide) or were part of the
Superfund additions. The Agency
proposed to include thesespecies on
 Appendix DC because their analyses
 TOV ides information on ground-water
 jiiamistry and movement Many
commentors argued that such •
constituents should not be included on
Appendix IX if they do not pose a
significant hazard. The Agency agrees
with these commentors on this issue and
hai deleted these constituents from
Appendix IX. The following table
 contains those constituents that while
no t part of Appendix IX, are valuable
 for the characterization of subsurface
 environmental chemistry. It is'important
 to note that while these constituents are
 unlikely to pose a significant hazard in
 themselves, the Regional Administrator
 does have the authority to require      •••*
' monitoring for them on a case-by-case
 basis if such analyses are necessary to
 protect human health and the
environment (see "Discretionary
Additions", below)!
                                                      TABLE i
Aluminum 	 _..
Bicarbonate/
Carbonate.
Boron 	 „...
Calcium 	
Chloride 	

Fluoride.. 	
Hydrogen ion

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            'Federal Register / Vol. 52. No.  131 /Thursday. July 9.'1987 / Rules and  Regulations       25945
constituents are present in ground-water
samples containing unknown amounts
of unidentified chemicals. With this rule,
EPA believes this goal has been met. In
order to facilitate the analysis of these
compounds, the Agency has included
two additional columns in the regulatory
list besides those columns that identify
th
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25948       Federal Register / Vol. 52. No. 131  / Thursday. July 9. 1087 / Rules  and Regulations
regulations being promulgated today to
determine whether they meet the tests
for authorization. Thus, a State is not
authorized to carry out these
requirements in lieu of the Agency until
the State requirements are approved. Of
course. States with existing standards
may continue to administer and enforce
their standards as a matter of State law.
   States that submit official applications
for final authorization less than 12
months after the effective date of these
standards are not required to include
standards equivalent to these standards
in their application. However, the State
must modify its program by the
deadlines set forth in §271.21(e). States
that submit official applications for final
authorization 12 months after the
effective date of those standards must
Include standards equivalent to these
standards in their application. 40 CFR
271.3 sets forth the requirements a State
must meet when submitting its final
authorization application.

Vm. Effective Date
   Pursuant to Section 3010(b) of RCRA,
 today's amendments will be effective
 six months after promulgation.
 IX. Executive Order No. 12291 and
 Regulatory Impact Analysis
   Under Executive Order 12291. the
 Agency must judge whether a regulation
 is "major" and. therefore, subject to the
 requirement of a Regulatory Impact
 Analysis. As stated in the proposed rule
 on July 24,1988. the Agency does not
 believe these conforming changes will
 result in an annual effect on the '
 economy of $100 million or more: a
 major increase in costs of prices of  .
 consumers, individual industries,
 Federal, State, or local government
 agencies, or geographic regions: or
 significant adverse effects on
 competition, employment, investment
 productivity, innovation, or In domestic
 or export markets. The Agency believes
 that today's rule is not a mojor rule
 under Executive Order 12291 and
 therefore, has not prepared a Regulatory
 Impact Analysis (RIA). This regulation
 was submitted to the Office of
 Management and Budget for review as
 required by Executive Order 12291.
 X. Regulatory Flexibility Act
    Under the Regulatory Flexibility Act.
 (5 U.S.C. 601 et seq.), the Agency must
 prepare a regulatory flexibility analysis
for all regulations that may have a
significant impact on a substantial
number of small entities. The Agency
conducted such an analysis on the land
disposal regulations and published a
summary of the results in the Federal
Register, Vol. 48. No. 15 on January 21.
1983. Today's conforming regulation
does not impose significant additional
burdens. In addition, they do not impose
any requirements beyond those required
for permitting facilities under Part 264.
Therefore, pursuant to 5 U.S.C. 601(b), I
certify that this regulation will not have
a significant economic impact on a
substantial number of small entities.

XI. Supporting Documents

  The docket (see "Addresses") for this
rulemaking contains the new data EPA
received concerning the analytical
feasibility of these compounds since the
time the proposed rule was published in
the Federal Register. The docket also
contains a chemical-by-chemical
summary of any compounds that were
re-examined since the time of the
proposal, as well as a report of the
aforementioned December 11,1988
meeting of analytical experts. The
background document "Summary of
Appropriate Methods for Appendix DC*
(see "Analytical Methods") is also
available in the docket.

XH. Lists of Subjects in 40 CFR Parts 264
and 270 .

   Hazardous materials, Reporting and
Recordkeeping Requirements, Waste
Treatment and Disposal, and Water
 Supply, Administrative Practice and
 Procedure, Ground Water,
 Environmental Monitoring.
   Dated: June 19,1987.
 Lee M. Thomas,
 Administrator.

   For the reasons set out in the
 preamble. Title 40 of the Code of Federal
 Regulations is amended as follows:

 PART 264—AMENDED

   1. The authority citation for Part 284 is
 revised to read as follows:
   Authority: Sees. 1006, 2002(a), 3001. 3004.
 and 3005 of the Solid Waste Disposal Act. as
 amended, 42 U.S.C. 6905, 6912(a), 6924 and
 6925.
    2. Section 264.98 is amended by
 revising paragraphs (h)(2), (h)(3)
introductory text and (h)(4)(i)
introductory text to read as follows:

§ 264.98 Detection monitoring program.
*****

  (h)***
  (2) Immediately sample the ground
water in all monitoring wells and
determine whether constituents
identified in the list in Appendix IX of
Part 264 are present and. if so, at what
concentration.
*****
  (3) Establish a background value for
each constituent that has been found at
the compliance point under paragraph
(h)(2) of this section, as follows:
*****

  (4)*  * *
  (i) An identification of the
concentration of each constituent found
in the ground water at each monitoring
well at the compliance point:
 *****

  3. Section 284.99 is amended by
revising paragraph (f) to read  as follows:

 §264.99 Compliance monitoring program.
 *****
   (f) The owner or operator must
 analyze samples from all monitoring
 wells at the compliance point to
 determine whether constituents
 identified in the list in Appendix  IX to
 Part 264 of this chapter are present and,
 if so, 'Si what concentration. The
• analysis must be conducted at least
 annually to determine whether
 additional Appendix IX constituents are
 present in the uppermost aquifer. If the
 owner or operator finds constituents
 from Appendix  IX in the ground water
 that are not already identified in the
 permit as monitoring constituents, the
 owner or operator must report the
 concentration of these additional
 constituents to the Regional
 Administrator within seven days after
 completion of the analysis.
 Appendix VII and VIII [Reserved]

   4. A new Appendix' 'II and Appendix
 VIII are added to Part 264 and reserved
 as follows:
   Appendix VII (reserved)
   Appendix VTII (reserved)

   5. A new Appendix IX is added to Hart
 264 as follows:

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Federal Register j Vol. 52, No. 131 / Thursday. July 9, 1987 / Rules and Regulations
25947
                 APPENDIX IX—GROUND-WATER MONITORING LIST l
Common name 2
Acenaphthene 	 .'. 	
Acenaphthylene 	 < 	 •. 	
Acetone . 	 '. 	
Acetophenone 	 	 	
Acetonitrile; Methyl cyanide 	 	 	

Acrolein ... 	 	 	
Acrylonitrile 	 '. 	 ...;. 	 	 	
Aldrin.. 	 	 	
Ally! chloride 	 	 	
4-Aminobiphenyl .................................................
Aniline . ......; 	 „. 	 	 	 	 	 	
Anthracene [[[ ..
Antimony [[[
Aramite 	 ..„....'.......»..........,.„............... „..,
Arsenic[[[
Barium 	 .... 	 ....^..-, ....... n.m. ....,..'. 	 	 	
Benzene .. '.. • 	 	 . , * _
Benzo[a]anthracene; Benzanthracene .„„..„.
Benzo[b]fluoranthene ....................................

Benzo[ghi]perylene 	 : 	 	
Benzo[a]pyrene 	
Benzyl alcohol 	 ......................
Beryllium 	 ;....'. 	 : 	 	 	 ,.'; 	 	
alpha-BHC 	 . . .
beta-BHC 	 	
delta-BHC . '. 	 » 	
gamma-BHC; Lindane 	 , 	
Bis(2-chloroethoxy)methane 	
Bis(2-chloroethyl)ether 	
Bis(2-chloro-1-methylethyl) ether; 24!'-Di-
chlorodiisopropyl ether
Bis(2-ethylhexyl) phthalate 	
Bromodichloromethane 	
Bromoform; Tribromomethane 	

CASRN3
83-32-9
208-96-8
67-64-1
98-86-2
75-05-8
53-96-3
107-02-8
107-13-1
309-00-2
107-05-1
92-67-1
62-53-3
120-12-7
(Total)
140-57-8
(Total)
(Total)
71-43-2
56-55-3
205-99-2
207-08-9
191-24-2
50-32-8
100-51-6
(Total)
319-84-6
319-85-7
319-86-8
58-89-9
111_91_1
111-44-4
108-60-1
117-81-7
75-27-4
75-25-2

Chemical abstracts service index name *
Acenaphthylene 1 2-dihydro- •-
Acenaphthylene ..
2-Propanone
Ethanone 1-phenyl-
Acetonitrile 	
Acetamide, N-9H-f luoren-2-yl- 	
2-Propenal
2-Propenenitrile 	
1 4*5 8-Dimethanonaphthalene 1 ,2 3 4 1 0 1 0-hexachloro-
1,4,4a,5,8,8a-hexahydro- (1tx,4a,4a/},5a,8a,8a/J)-
1-Propene, 3-chloro- 	 	 	
£1 ,1 '-BiphenyO-4-amine 	
Benzenamihe
Anthracene 	 '. 	
Antimony . .
Sulfurous acid 2-chloroethyl 2-[4-(1 1-
dirnethylethyl)phenoxy]-1 -methylethyl ester
Arsenic...™........................................™. 	 _ 	 „..,. . .
Barium .'...-[[[_............ 	 ...........
Benzene
Benz[a]anthracene 	 „ 	 ......
BenzEeldcephenanthrylene .
Benzotklfluoranthene ....
Benzo[ghi]perylene
Benzo[a]ovrene . .. '._ 	
Benzenemethanol
Beryllium 	 	
Cyclohexane 12345 6-hexachloro- (1a 2a 3/3 4tt 5/J 6/3)-
Cyclohexane 12345 6-hexachloro- (1 a 2/3 3cc 4/3 5a 6/3)-
Cyclohexane, 1, 2,3,4 ,5,6-hexachloro-,(1a,2a 3a,4^,5a,6^)-

Ethane, 1 1'-Cmethylenebis (oxy)3bis£2-chloro-
Ethane, 1,1'-oxybis[2-chloro-
Propane, 2,2'-oxybis[1-chloro- 	
1 ,2-Benzenedicarboxylic acid bis(2-ethylhexyl)ester
Methane, bromodichloro-
Methane, tribromo- 	

Sug-
gested
meth-
ods5
8100
8270
8100
8270
8240
8270
8015
8270
8030
8240
8030
8240
8080
8270
8010
8240
8270
8270
8100
8270
6010
7040
' 7041
8270
6010
7060
7061
6010
7080
8020
8240
8100
8270
8100
8270
8100
8270
8100
8270
8100
8270
8270
6010
7090
7091
8080
8250"
onpn
8250
PtriRn
8250
8080
8250
8270
8270
8010
8270
8060
8270
8010
8240
8010
82^0
POL
(/j.g/L)6
200
10
• -200 -
.10
100
10
100
10
5 ,
• 5 '
5
5

-------
25948
Federal Register / Vol. 52. No. 131  / Thursday. July 9. 1987 / Rules and Regulations
                       APPENDIX IX-^ROUND-WATER MONITORING LIST 1— Continued
Common name a

Butyl benzyl phthalate; Benzyl butyl phthal-
ata

Carbon disulfkte ....... — 	



Chlofobenzene«.™.......-...™.............— •— 	
p-Chloro-m-cresol 	 	
Chloroethane; Ethyl chloride 	 	
2-CMoronaphthaJene 	 ..—».. 	
z-untoropnofioi „.._......._.-...—....... 	 ........
4-CWofophonyl phenyl ether 	 ......

Cobalt 	 ...- 	 	

oXJresol 	 . 	

2.4-O; 2,4-Dfchlorophenoxyacetic acid 	 —
4 4'-ODD 	
4,4'-DDE 	 .„___.. ...™~ 	 - 	 ..... 	
4 4'-DOT
Dialtate ........«—..—• .....—. ............... 	 	 	
Dibonzta,Manthracene~. 	 .. — 	
Dtbonzofuran ..„.—......... .... 	
Dibromochtoromethane; Chlorodibromo-
methane
1 ,2-Dibromc-3-chloropropane: DBCP 	
1,2-Oibromoetnane: Ethylene dibromide 	

o-Dichlorobenzene 	 • 	

CASRN3
101-55-3
85-68-7
(Total)
75-15-0
56-23-5
57-74-9
106-47-8
108-90-7
510-15-6
59-50-7
75-00-3
67-66-3
91-68-7
95-57-8
7005-72-3
126-99-8
(Total)
218-01-9
(Total)
(Total)
108-39-4
95-48-7
106-44-5
57-12-5
94-75-7
72-54-8
72-55-9
50-29-3
2303-16-4
53-70-3
132-84-9
124-48-1
96-12-8
~~-f 06^93-4
84-74-2
95-50-1
Chemical abstracts service index name*

1.2-Benzenedicarboxylic acid, butyl phenylmethyl ester.: 	

Methane tetrachloro-...........— . 	 •• — •— •• 	 _..._._™.._...
4.7-Methano-1H-indene, I^AS.ej.S.S-octacrHoro-
2,3.3a,4,7.7a-hexahydro-
Benzenamine. 4-chloro- 	 ... — ~ 	 ...................... 	 ••••—

Benzeneacetic acid. 4-chloro^-(4• 	
Naphthalene, 2-chloro- 	 » 	 -— —

1 ,3-Butadten8, 2-chloro- ....... — . — ..««.-.—. — :..*«.«««.«-»«.««*...

CoDoer 	 	 	 	 	 .,..«...«..«—«-««««-*.«.«—


Phenol, 4-methyl- ............. — . — ............ — -. 	 ..—..... 	 ...


Benzene 1,1'-{2.2-dichlorQethylidene)bis[4-cWoro- 	 . —
Benzene 1,l'-{dichloroethylidene)bis[4-chioro-. 	 . — . —
Benzene 1 . 1 '-(2.2,2-trichloroethy Iidene)bis{4-chtofO- 	
Carbamothiotc acid, bis(l-methyiethyl)- , S- (2,3-dichloro-2-
propenyl) ester




1 ,2-Benzenedicarboxylic acid, dibutyl ester 	
Benzene 1 ,2-dichloro- 	

Sug-:,
gested
meth-
ods"
8270
• 8060
8270
6010
7130
.7131
8240
8010
8240
8080
8250
8270
8010
8020
8240
8270
8040
8270
8010
8240
8010
8240
8120
. 8270
8040
8270
8270
8010
8240
6010
, 7190
7191
8100
8270
6010
7200
7201
6010
7210
. 8270
8270
8270
9010
8150
8080
8270
8080
8270
8080
8270
8270
• 8100
8270
8270
, 8010
8240
8010
8240
, 8270
8010
8240
8060
8270
8010
8020
8120
8270
PQLe
10
5
10
40
50
1
5
1
5
0.1
10
20
2
> 2
5.
10
5 '•
20
.5
10
0.5
5
10
10
5
10
10
50
5
70
500
10
200
10
70
500
<; 10
* 60
. 200
10
10
40
10
0.1
10
0.05
10
0.1
10
10
200
10
10
1
5
100
5
10
10
5
5
10
2
5
10
10

-------
Federal Register / Vol. 52, No. 131 / Thursday, July 9, 1987 / Rules and Regulations
25949
            APPENDIX IX—GROUND-WATER MONITORING LIST »—Continued
Common fiame2

p-Dichlorobenzene . ..
3,3'-Dichlorobenzidine.................... 	 	 	
trans*1 4-Dichloro-2-buten©
Oichlorodifluoromethane
1 1 -Dichtorocthans

1,1-Dichloroethylene; Vinytidene chloride........
trans- 1 2-DichloroGthytene •
2 4-Dichlorophenol
2 6-Dichlorophenoi r ww.
1 2-Dichlofopropane J* '
cis-1 3-Dichloropropen6* " '* ~ "

r^lrirm •'••" '' ' ' "' •"•'•' '"'
:,.- ./...- ;. ..*-... . .
Diethy! phthalate .„....._...„..................................
O.O-Dtethyl O-2-pyrazinyt phosphorothioate;
Thionazin - ; ' •"
Dimethoate .„......„_.."....... _._.«.'™.l.-.;.... ...........
p-{Dime?hylamino)azobenzene...^...i...™-.. 	
7 1 2'Dirn8thyibenzr.a3anthracene
3 S'-Dimethytbenzidine
alpha, alpha-Dimethylphenethylamine 	
2 4-Dimethylphenol
Dimethyl phthalate
fYt-Dirtitrobenzene . '
4 6-Dinitrc-o-cresol 	 	 	 	

2 4-Dinitrotoluene 	
2 6-Dinitrotoluene
Dinoseb; . DNBP; 2-sec-Butyl-4,6-dinitro-
phenol
Di-n-octyl phthatate '. ' .'....»....... 	 	 	
1 '4-Dioxane ' ' " ' ' " *


Endosulfan l_. 	 .............................................

CASRN3
541-73-1
106-46-7
. 91-94-1
110-57-6
75-71-8
: , 75-34-3
107-06-2
75-35-4
156-60-5
	 120-83-2
.... 87-65-0
78-87-5
10061-01-5
10061-02-6.
..-- 60-S7-1
84-66-2
- 297-97-2
60-51-5
60-11-7
57-97-6
119-93-7
122-09-8
105-67-9
131-11-3
99-65-0
534-52-1
51-28-5
121-14-2
606-20-2
88-85-7
117-84-0
123-91-1
122-39-4
298-04-4
959-98-8
Chemical abstracts service index name4
Benzene 1 ,3-dichloro- ...._...__.. 	 ..........
Benzene 1 4-dichloro- 	 	 	
[1,1'-Biphenyl3-4,4'-diamine, 3,3'-dichloro- 	 .......

Methane dichlorodifluoro- 	 	 ...



Ethene 1 2-dichloro- (E)- 	 ........... 	 ; 	 	
Phenol 24-dichlorc-...™...™................«....— .••——•«•'•"•—••••••—•••
Phenol 2 6-dichloro- ..........................—.••••• -......;.........................
Propane 1 2-dichloro- ..........................._.............-....... 	 ~.
1-Propene 1 3-dichloro-, (Z)-.......™...................-..™...«.....~.......
1-Propene 1 3-dichloro-, (E)- 	 . 	 » 	 . 	 ..
2.7:3.6-DimethanonaphthC2,3-b]oxtrene, 3,4,5,6,9,9-hex-
achloro-1 a,2,2a,3,6,6ai7,7a-octahydro-, (1 ao^^,2ao,3/?
,6/3,6ao,7/S.7aa)- . • . '
1,2-Benzenedicarboxylic acid, diethyl ester 	
Phosphorothioic acid, O.O-diethyl O-pyrazinyl ester. 	 	
Phosphorodithioic acid, O,O-dimethyt S-[2-(methylamino)-2-
oxoethyl] ester ' ...
BenzeriarnifieTTW-aimethyl-4=(phenylazo}-.--» — 	 	

Berizeneethanamine, a,a-dimethyl- 	 . — '. 	 '. — .-.
Phenol 2 4-dimethyl- 	 ...................
1 2-Benzenedicarboxylic acid, dimethyl ester.. .......................

Phenol 2-methyl-4,6^jinitro- 	 „........„ 	





1 4-Dioxane 	 	 	
Benzenamine N-phenyl- 	 	
Phosphorodithioic acid, O.O-diethyl S-[2-(ethylthio)- S-E2-
ethyljester .
6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-hex-
achloro-1 ,5,5a,6,9,9a-hexahydro-, 3-oxide, (3a,5a/3,6a,9a
Sug-
gested
meth-
ods5
' 8010
8020
8120
8270
8010
8020
8120
8270
8270
8240
8010
8240
8010
8240
8010
8240
8010
8240
8010
8240
8040
8270
8270
8010
8240
8010
8240
8010
8240
8080
8270
8060
8270
8270
8270
8270
8270
8270
8270
8040
8270
8060
8270
8270
8040
8270
8040
8270
8090
8270
8090
8270
8150
8270
8060
8270
8015
8270
8140
8270
8080
8250
POL
(M3/U6
. >- .-V . ,:
5
10
10
2
5
15
10
20
5
10
-. "5
1
••••'. 5
0.5
5
"••' 1 '
5
1
5
5
10.
10;
0.5
' ,,5; '
20
5
•-. . 5.--
5
'•'-•' 0.05
10
5
.10
10
10
;io;
.10 :
10
5
10
5
10
10
150
50
150
' 50
0.2
" 10
0.1
10
. . - 1
10
30
10
150
10
2
10
0.1
10

-------
25950       Federal  Register / Vol. 52. No. 121  /  Thursday. July 9. 1987  /  Ruiei  and Regulations
^^'••••••••^•••••••••••••••••••••••••••••••••••MHMi^^
APPENDIX IX— GROUND-WATER MONITORING LIST l— Continued
Common name 2 ! CAS RN 3
!
E "> Josulfan II ._ 	 „.....„ 	
Endosulfan sulfate 	 „ .
Encnn,_......._ _.„ 	 	 	 „ _
Endnn aldehyde 	 „ 	
Ethyibenzene 	 _ 	
Ethyi methacrylate 	 	 _ 	 „
Ethyl meihanesulfonate 	
Famphw 	 	 	 ,.„„„„„„ „.,., , . ,„
Fluoranthene „....._ 	
Fluorena.... „. 	 _....._._ 	 _ 	
Hoptachlor.... .._.....„„ 	
Heptachlor epoxide ......_....._. 	
Hex&chtorobenzene... .„.,...._ 	
Hexachtorobutadiene 	 	 	
Hoxachlorocydopentadiene 	 	
Hoxachtofoethane___.»._._m,..._.....«.._ 	
Hexachlorophene 	 	 	 	
Hoxachkxopropena 	 _
2 Hexanone 	 .......... 	 _......
lndano(1,2,3^ri)pyrRno ..., „„ , „ „
Isotxjtyf alcohol
IsQdrjfl. ,..„ 	 .,,...„„ ,„„„„„
IspphOfOnfl,, ..,.,.,„.,..... .,,^,,,., ,„„„
Isosafrole .„„„.„ 	 	
Keponn,, „„,....., 	
Ln;irf ,„„..„ 	 	 ,.„.„„!_,„, , ,
Mofcury ...,..„_.„...„_..,„.„.. 	
Mothacryionitiile 	 	 	
Methapyrilono... 	 „ 	
Mothoxychlor™.™™.......™ 	
Methyl bromide; Bromomethane 	
Methyl chloride; Chloromethane 	
'
••
3-Mothylcholanthrene 	 	 _ 	
Methyfene bromide; Dibromomethane 	
Mothytene chloride; Dichloromethane 	
' 33213-65-9
1031-07-8
72-20-8
7421-93-4
100-41-4
97-63-2
62-50-0
52-85-7
206-44-0
86-73-7
75-44-8
1024-57-3
118-74-1
87-68-3
77-47-4-
67-72-1
70-30-4
1888-71-7
591-78-6
- 193-39-5
78-83-1
465-73-6
78-59-1
120-58-1
143-50-0
fTotal)
(Total)
126-98-7
91-80-5
72-43-5
74-83-9
74-87-3
56-49-5
74-95-3
75-09-2
Chemical abstracts service index name «
6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-hex-
achloro- 1 ,5,5a.6,9,9a-hexahydro-, 3-oxide,
(3a,5aa,6/3.90.9aa)-
6,9-Metfiano-2,4,3-benzodioxathiepin. 6,7,8.9, 1 0. 1 0-hex-
achloro- 1 ,5,5a,6,9,9a-hexahydro-, 3,3-dioxide.
2,7:3,6-amethanonaphth[2,3-b]oxirene, 3,4.5,6,9,9-hex-
aohloro-1 a,2,2a,3,6,6a,7,7a-octahydro-. (1 ao.
2p,2a0,3a,6a. 6a#.7y3,7aa)-
1,2,4-Methenocyclopenta[cdipentalene-5-carboxaldehyde.
2,2a3,3,4,7-hexachlorodecahydro-, (1 ot.2^,2a0,4/3
,4a^.5/3,6aj3,6b/3,7R*)-
Benzene, ethyi- 	 _...
2-Propenolc acid 2-methyl- ethyl ester
Methanesulfonic acid ethyl ester .
Phosphorothioic - acid, O-f.4-
C(dimethylamino)sulfonyl]phenyl]-O,0-dimethyl ester
Fluoranthene
9H-Ruorene.
4,7-Methano-1H-indene. 1,4,5.6,7,8,8-heptachkxo-
3a.4.7.7a-tetrahydro-
2.5-Methano-2H-indenoC1 ,2-b]oxirene, 2.3.4,5,6,7.7-hep-
tachloro-1a,1b,5.5a,6,6a,-nexahydro-, (1ao,1b^^a.5a
,5a/3,6/3.6aa)
Banzane, hAvacft'OTO- .,..., 	 _...
1,3-Butadiefie, 1 ,1 ,2,3,4,44w(xachl. 	 	 „.-„-„-„ ,
V,3-CyclopefitadienQ, 1 2,3 4 5 5-hexachtoro-
Ethflna, hflxqcliloro-. .....:. 	 	 	 ......„.„,..,.,,...,.
Phenol. 2.2'-methylenebis[3,4,6-trichloro- 	 ; 	
1-Propena, 1,1,2,3^,3-hex9Chlor(>. ....,..„....,.„,„,.„,. ..
2-Hexanorte_ 	 „ „ - 	 —
lndemj[1,?,3-
-------
Register / Vol. 52. Me. 131 /  Thursday. July 9, 1987 / Rules and Regulations      25951
     APPENDIX IX—GROUND-WATER MONITORING LIST '—Continued
Common name7
Methyl ethyl ketone; MEK 	
Methyl iodide; lodomethane 	 	 	
Methyt methacrylate 	 „ 	 „ 	 _ 	
Methyl methanesuifonate 	 	
2-Methylnaphthatene 	
Methyl parathion; Parathion methyl 	 „ 	
4-Methyl-2-pentanone; Methyl isobutyl
ketone :
Naphthalene 	 	 	 	 _.....
1 ,4-Naphthoquinone 	 	 	 „„...„..... 	 _
1-Naphthylamine.._.................._... 	 	
2-Naphthylamine ' 	 ..... 	 „ 	 ...
Nirkftl 	 .... 	 , 	 ', 	

O-NHroflni|ing 	 . „
m-Nitmanilinf .„.,„„,„,„.„„„„,„.,„ „„ „ ,
p-NitroanHinfl ...........,.,,.,•,,, ,
Nrtn^)^07t>nfl ._...... 	 ....,,,...,....,,..,,.,...,,.,1
o-Nitrophenol 	 .' 	 ; 	 lliu •„„ „ „;, >
p-Nitroph«?no}.. ...:..l 	 ...:/.:. ,!,;.!.~,y!J..,,,,,,,,,.liiL,i
4-Nitroquin6Une 1-oxide !„„„.„..„;..„....„.....„...
N-NitrosodMVbutyfaminQ™™"™™™™;^™.. ' ..
N-Nftrosodielhylamine...: 	 ^ 	
N-Narosodimsthylamine™.......m«...._._... 	 :.:..
N-Witrosodiphsnyiamine „.!„..„ ..!._.. "_T
N-Ni'ffosodipropylarntne; Dt-rvpropylnitrosa-
minfl • ' '"... ' ;'"''
hi-Nitrosomethyletnylamine-......;..........™; ........
N-Nftrosomorphofine ...„..„ 	 „.";....„ 	 ;... 	
N-Nitrosopiperidtne...™..:....'..-...".... 	
N-Nitrosopynrolidine-..-.:: 	 ^ • ....; 	 ... 	
5-Nitro-o-toluicCne _. ............ ...............................
Pansthion,.. .._._..- 	 ,-..! 	 	 	 .,,,,,..
Potychlon'nated biphenyls; PCBs. 	 ..'. 	 '. 	
Pofychlorinated dibenzo^p-dioxins; PCDDsv. 	
PotycWorinated dibenzofurans; PCDFs 	 '.
Pentachlorobenzene..«.-J™...—..~r.~........."....
Pentachioroethane ...... •.;.."....... • „. '
Pentachloronitrobenzene. 	 ;.. 	 _ 	 	
Pentachlorophenoi... 	 -..._ 	
Phenacetin..- ............ 	 ; 	 .„.. ..
Phfin^nthrene,-,',,,,,, ...,,.„',,,. ,, .„,„
Phenol 	 _.„ _ 	 L.... 	 	 	 : 	
p-Phenylenediamine 	 -'....:....:;.•. 	 .'.„.'.....;...
. Phorate.I.l~; 	 .'~™ 	 J 	 ; 	 ^_ 	 _~.__^ 	 	
2-PicoMne i^,,,^,^,;,,-,.,^,,!,, ..._,,___,,,„,,,
PrortBfTwte ,. ,.i,, ,;....-..,,. , ,-,'-•-'"-- ,',,if,r ' "
Proptonttrile;-Ethyl cyanide— ; ' •. ' ' *
Pyfftjne ": " •',-'-'--- —:'-'-' '•.".- -.-..'....„',

CASRN*
78-93-3
74-88-4
80-62-6
66-27-3
91-57-6
298-00-0
108-10-1
91-20-3
130-15-4
134-32-7
91-59-8
(Total)

88-74-4
99-09-2
100-01-6
98-95-3
' 88-75-5
" 100-02-7
56-57-5
024-16-3
55-18-5
62-75-9
86-30-8
621-64-7
10595-95-6
59_g9_2
100-75-4
930-55-2
99-55-8
56-38-2
See Note 7
See NoteS
See Note 9
• 608-93-5
76-01-7
82-68-8
87-86-5
62-44 2
85-01-8
108-95-2
106-50-3
298-02-2
109-06-8
23950-58-5
107-12-0
- 129-00-0
110-86-1

Chemical abstracts service index flame 4
2-Butanone ...... ..-.~ .. 	 ........ .
Methane, iodo- 	
2-Propenoic acid, 2-methyl-, methyl ester
Methanesulfontc acid, methyl ester 	 „ .„
Naphthalene 2-methyt-._«- 	 _ „..
Phosphorothioic acid, O,O-dimethyl O-(4-nitrophenyl) ester ...
?-Pentanons 4-methyl-.. 	 ,,...,....,,....,.,.,,, ..^^^^ ^ ^
Naphthalene 	 «... 	 ; ...: 	
1 4-Naphthaienedtone . ... .
1-Naphthalenamine »«. . .... .... . « 	
2-Naphthahanamine .• ... 	 	
Nickel . . 	 _ 	 	

Benzenamine, 2-nitro............... 	 : 	 .-. 	 	 	
BwTenarfHfx? 3-nflnv..'. ....;...-....- 	 	 	 	 	 	
Ben/pnjwnme, 4-nrtro- 	 	 	 	 ,1, , '
Benzene, nitro-...: 	 : 	 	 	 ; 	 	 	 '. 	 	 	
Phenol 2-nttro- -' . „ . .' 	 « 	
Phflnot 4-nftro- 	 	 -- ....... .. 	 	 	 	 	
QtHnofine 4-nitay, 1-oxkJft ..........— 	 .' 	 	 	 ,,,,..,., 	
1-Bistanamine, N-butyt-N-nHrono--'..-...... 	 	 	 .'..
Ethanamine, N-etnyl-N-nftrosc- .»»....»^... 	 . 	 .... 	 .............
Methanamtne, N-methy(-N-nJtroso- _......_ ....„_................_.„.
Beruenanww N-nitroso-N-phenyW..: 	 ; u.,,.... 	 , 	 _ 	
1-Propanamirt9, N-nrtroso-N-propyl- ....._................... 	
Fthanamin6 N-m@thyl-N-nitroso* • . '. •» 	
Morpholine 4-nrtroso-" .....'...' . "...
Pipofidinfl, 1-nitroso-....: 	 '. 	
Pyrrolidine 1 -nitrosc— . .• 	 	 «..»«.'. ........ .......
Benzenarriine, 2-rnetr(y<-5-nilro-__.~.._._.. ...._._...__.........
PhosphofOthcoic acid, O O-di6thy(-O-(4-nttrophenyl) ester '
1 I'-Biphenyl chloro derivatives ~~~~. 	 ;.. .' 	 '. 	
Dibenzotb elI1 41dioxint chtoro derivatives ' ... .
Dibenzofuraiv cWoro derivatives «_*...' «. " . . ' . :.~~~,~.~~
Benzene, ppfitachloro- 	 '.. 	 .'. 	 	 	 	
Ethane p^jntachloro- ' » * • . ' ' . .
Benzene pentachloronitro- ... 	
Ph^noii pfintgchioro- ' '
Acetamide, N-(4-ethoxyfrfienyl) 	 	 	 _ 	 	 	 	 	
Phf^nanthrene ;
Phenol • „ . ..
1 ,4-Benzenediamine .....:........ 	 „...;'„....•„ 	 ............'....._
Phosphorodithioic acid,- O,O-diethyl S-C(ethyltWo)methytl
ester • . •
Pyridine, 2-*nethy>-^.~«___: 	 ^__\ 	 .....__..___......._..„.._„
Rf»n7^mir!*> a fuHir-h)iW-{} i-dimoft>yf-?-prif*yny'f-
Propanenitrite ••' .~ ~ ' _ . . '.•••„. ^. . ..„...;..
•Pyririine...- •..„.•";--..:. '-!-," ... : .

Sug- \
nested
meth-
ods5
8015
8240
8010
8240
8015
8240
8270
8270
8140
8270
8015
8240
8100
8270
8270
8270
8270
6010
7520
8270
8270
. 8270
8090
8270
8040
8270
8040
8270
8270
8270
8270
8270
8270
827O
8270
8270
8270
8270
8270
8270
8080
«250
• 8280
8280
8270
• 8240
8270
8270
8040
8270
8270
8100
8270
8040
8270
8270
8140
8270
8240
8270
8270-
8015'
8240
8100
8270
.. 8240
8270
POL
(fig/U*
10
100
40
5
2 • •
5
10
10
0.5
10
•• . > 5 •'
. 50
200
10
10
10
10
50
400
50
50
• •• 50 . . •
40
10
' ' 5 '
10
• to •••••-
:; 50
, -jo
- .'•• 10
10
- . 10.
• 10
.-,•<•. 10 •
, 10 -
10
10 v
10
- 10, _
to .
50
100
0.01
.-..' 0.01
•• 10- •
5
10
10
5
50
10
200
10
1
10
10
•-.-: • • 2 .
10
• - 5
... 10
... 10
60
. 5
. 200 "
- 10
•'"-•'••. 5 '
10

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25952       Federal Register /Vol. 52. No. 131  / Thursday. July 9, 1987 / Rules and  Regulations


                             APPENDIX IX—GROUND-WATER MONITORING LIST l—Continued
Common name2
Safrola 	 _ 	 „ 	 	
Selenium 	 	 .
Silver 	 _...» 	 - 	 ........ 	 _.
Silvex; 2.4.5-TP 	 	 „ 	 „ 	
Styrene.,.-. 	 „ 	 - 	 - 	
Sulfide 	
2,4 5-T; 2 4 5-Trichlorophenoxyacetic acid ..
2,3,7,8-TCDD; 2.3,7,8-Tetrachlorodibenzo-p-
dioxin
1 ,2,4,5-TetrachlorobenzeriQ 	 _...„....
1.1,1 ,2-Tetrachtoroe thane 	 . 	
1 ,1 ,2, 2-TetrachIoroe thane. 	 	 „..
TetrachJoroettiylene; PercWoroethylene;
Tetrachloroethene
2.3,4.6-Tetrachlorophenol..... 	
Tetraothyl dithtopyrophospnate; Sulfotepp —
Thallium... ......_ 	 _....„ 	 „.„ 	
Tin
Toluene .................. . ..„ ............... ...„..._.......
o-Toluidine .... ...—....„_._.._.„......_„.......„....
Toxapti ofia ....„.....„........._„.....„._...._......«.........
1,2,4-Trichlorofaenzene .............. ................
1,1,1-TricWoroethane; Methytehtoroform..... 	
I.l.sj-Trichiofoflthafw 	 	 	 ;.. 	
Trichloroethylehe; TricWoroethene 	 .: — ; 	
Trichlofonuorome thane 	 : — 	 ™ 	
2.4.5-Trichlorophenol 	
2.4,6-Trichlorophenol 	 	
1,2,3-TrlchJoropropane 	 	 	 	
O.O.O-Triethyl phosphorothioate. — 	
sym-Trinitrobenzene .................................. 	
Vanadium ._._......,.....................„... 	 .• 	
Vinyl acetate 	 _...••
Vinyl chloride....- 	 	 	 	 	
Xyiene (total) 	 	 ;: 	
Zinc. ................................. 	 	 _.„ .

CAS RN 3
94-59-7
(Total)
(Total)
93-72-1
• 100-42-5
18496-25-8
93-76-5
.1746-01-6
95-94-3
630-20-6
79-34-5
127-18-4
58-90-2
3689-24-5
(Total)
(Total)
108-88-3
95-53-4
8001-35-2
120-82-1
71-55-8
79-00-5
79-01-6
75-69-4
95-95-4
88-06-2
96-18-4
126-68-1
•99-35-4
(Total)
•108-05-4
75-01-4
1330-20-7
(Total)

Chemical abstracts service index name *
1 3-Benzodioxole 5-(2-propenyl)- 	

Silver™ 	 « 	 - 	
Propanoic acid, 2-(2,4,5-trichlorophenoxy)- 	
Benzene, ethenvl- 	 .•. 	
Sulfide 	

Dibenzo[b,e] C1 ,4]dioxin, 2.3,7.8-tetracnloro- 	
Benzene, 124 5-tetrachloro- ............... ...~............~-..- 	
Ethane, 1,1,1,2-tetrachloro- 	 .._ 	 .„.....„.. 	
Ethane, 1 ,1 ,2,2-tetrachlorc- ....... 	 .....„._....._...........„.,«._......
Ethene, tetrachloro-.... ....................................... ..........™_.~.......
Phenol, 2,3,4,6-tetrachloro-..~.......~— .......................... ......~.
Tniodiphosphoric acid (C(HO)iP(S)]jO), tetraethyl ester
Thallium ._..............................................„..„....................-. 	
Tin . . „_ ........ 	 . ™ - ..
Bsnzons, methyl- 	 	 	 	 	 	 	 	 	 	 	 	
Benranamina, 2-ffiethyl-. „.„'„. u. .'.,.. 	 	 	 	 	
Toxaphene .„_.'....._..... ..._.««.._......_«..-.~.~..._. -...;.........._
Benzene, 1 ,2,4-trichloro- .~~..............~.~.~.~~....~.~~~^....~~~~
Ethane 1 1,1-trichloro- ,;.. 	 ,*T,,,,, :,„,..„„„„„
Ethaiw 1 1 2-trichloro- ..." , ..... ,........".. 	 .'.;.: 	 	 	 	 	
* • *
Ethens, trichloro- 	 ^^.^^.^....^....^^.................'.'.i.....^..^....'....
• Methane, trichlorofluoro- .....-.««....«.-....«..;».....««;«...»..»«««.
Phenol, 2,4,5-trichloro- ..**.....M.H*......»»«HH«..».»**M«*M...«.*H.«».
PhenoJ, 2,4,6-trichloro-.^.......,................™...™-..... ......««.««.««.
Prooane. 1 .2.3-trichloro- 	 	
Phosphorothioic acid, O.O.O-trietnyl ester — ;....... — ... 	 ...
Benzene 1 3 5-trinitro- « . ..»........H...»..»..»...M....'....H
Vanadium ..........._....................... 	 	
Acetic acid, ethenyl ester 	 ....................„..„......„.„......_..........
Ethene chlorc— . . . ...«...». 	 	 	 	
Benzene, dimethyl- [[[
Zinc : • .... 	 	 	

Sug-
gested
meth-
ods5
8270
6010
7740
7741
6010
7760
8150
8020
8240
9030
8150
8280
8270
8010
8240
8010
8240
8010
8240
8270
8270
6010
7840
7841
7870
8020
8240
8270
8080
8250
8270
8240
8010
8240
8010
8240
8010
8240
8270
8040
8270
8010
8240
8270
8270
6010
7910
7911
8240
8010
8240
8020
8240
6010
7950
PQL
0*g/U8
10
750
20
20
70
100
2
1
5
10.000
2
0.005
10
5
5
0.5
5
0.5
5
10
10
400
1,000
10
8.000
2
5
10
2
10
10
5
0.2
5
1
S
10
5
10
5
10
10
5 '.
10
10
80
2.000
40
5
2
10
5
5
20
50
    'Tho regulatory requirements pertain only to the list of substances; the right hand columns (Methods and PQL) are given for informational
purposes only. See also footnotes 5 and 6.
    E Common names are those widely used  in government regulations, scientific publications, and  commerce; synonyms exist  for many
chemicals.
    3 Chemical Abstracts Service registry number. Where "Total" is entered, all species in the ground water that contain this element are
included.        ,                                                                               .
    * CAS Index names are those used in the 9W Cumulative Index.
    s Suggested Methods refer to analytical procedure numbers used in EPA Report SW-846 'Test Methods for Evaluating Solid Waste", third
edition, November 1986. Analytical details can be found in SW-846 and in documentation on file at the agency. CAUTION: The methods listed are
representative SW-846 procedures and may not always be the most suitable method(s)  for monitoring an analyte under the regulations.
    9 Practical Quantitation Limits (PQLs) are the lowest concentrations of analytes in ground waters  that can  be reliably determined within

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             Federal Register  /  Vol.

                                                                                                                 25S53
~~~            Trant fiaure CAUTION- The PQL values in many cases are based only on a general estimate for the method and not on a






The PQL shown is an average value for PCDF congeners.-  -            '
 PART 270—AMENDED

   1. The authority citation for Part 270 is
 revised to read as follows:
   Authority: Sees. 1006, 2002(a), 3001,3004,
 and 3005, of the Solid Waste Disposal Act, as
 amended. 42 U.S.C. 6905,6912(a), 6924 and
 6925.
  2. Section 270.14 is amended by
revising paragraph (c)(4)(ii) to read as
follows:
§ 270.14  Contents of Part B: general
requirements.
  (4) *
  (ii) Identifies the concentration of
each Appendix IX, of Part 264 of this
chapter, constituent throughout the.
plume or identifies the maximum
concentrations of each Appendix IX
constituent in the plume.
[PR Doc. 87-14658 Filed 7-8-87; 8:45 ami
BILLING CODE 6560-50-lt

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