PB97-963104
                                EPA/541/R-97/006
                                November 1997
EPA   Superfund
       Explanation of Significant Difference
       for the Record of Decision:
       Groveland Wells (No. 1 & 2 Site),
       (Source Control Operable Unit), (O.U. 2),
       Groveland, MA
       11/15/1996

-------

-------
       FINAL EXPLANATION OF SIGNIFICANT DIFFERENCES

INTRODUCTION

This document constitutes a Final Explanation of Significant Differences ("BSD") between
the remedial actions as specified in the Record of Decision ("ROD") and those now
planned under this ESD. It also documents the conditions that give rise to its need.

Site Name. Location, and Description

Site:                Source Control Operable Unit
                    Groveland Wells Nos. 1 & 2 Site

Site Location:       Groveland, Massachusetts

Site Description: The Groveland Wells Nos. 1 and 2 Site contains nearly 850 acres
mostly located in the western part of the Town of Groveland. Both of the town's
municipal wells, i.e., Stations Nos 1 & 2, were closed in 1979 when high concentrations of
trichloroethene ("TCE"), a volatile organic compound ("VOC"), were discovered.

The closure of the wells resulted in investigations that revealed the presence of an
extensive groundwater contaminant plume, containing principally TCE, that is migrating
toward the Merrimack River. Highest TCE contaminant concentrations have been found
near the Valley Manufactured Products Company/Groveland Resources Corporation
("Valley/GRC") property which is located at 64 Washington Street, Groveland,
Massachusetts.

In addressing the cleanup of the groundwater contamination, the Groveland Site was
divided into operable units. The apparent source of the groundwater contamination is the
Valley/GRC property, hence the property is considered the Source Control Operable Unit
for the Groveland Site.  Remediation of the remainder of the migrating contaminant plume
is being addressed under the Management of Migration Operable Unit.  This Final ESD is
for the Source Control Operable Unit, i.e., the Valley/GRC  property.

The Valley/GRC property consists of approximately 1.5 acres of land on the southwest
corner of the Groveland Site. This property has one 29,000 square foot building and
several subsurface waste disposal systems for dispersal of liquid effluent into the
environment.

Valley Manufactured Products Company, Inc., which operates on the GRC property, is a
 screw machine products manufacturer and finisher.  During the period 1963 to 1974,
waste oil and solvent (including TCE) was released by Valley onto the property, including

-------
TCE product which escaped from an underground storage tank. Additional releases
resulted from spills or leaks into the subsurface disposal systems and use of waste oil
containing TCE as a defoliant.

A more complete description of the Groveland site, the Valley/GRC property, and
remediation systems proposed for both operable unhs, can be found in the "ROD Decision
Summary, Groveland Wells Nos. 1 & 2 Site, Valley Site Organics Source-Control
Operable Unit, Groveland, Massachusetts" dated September 30, 1988 and in the
"Management of Migration Record of Decision Summary, Groveland Wells Nos. 1 & 2
Site" dated September, 1991.
Identification Of Lead And Support Agencies

Lead Agency;       United States Environmental Protection Agency (EPA)
   Contact:          Robert J. Leger
                    Remedial Project Manager
                    (617) 573-5734

Support Agency;    Massachusetts Department of Environmental Protection (MA DEP)
   Contact:          Jay Naparstek
                    Assistant Deputy Division Director
                    (617) 292-5697

Citation Of The Comprehensive Environmental Response. Compensation And
Liability Act Of 1980 ("CERCLA") Section 117© That Requires The ESP

Section 117O of CERCLA sets forth the circumstances for which an ESD is required.
Specifically, Section 117© provides: "After adoption of a final remedial action plan -
(1) if any remedial action is taken, (2) if any enforcement action under section 106 of this
title is taken, or (3) if any settlement or consent decree under sectioft 106 of this title or
section 122 of this title is entered into, and if such action, settlement or decree differs in
any significant respects from the final plan, the President or the State shall publish an
explanation of the significant differences and the reasons such changes were made."

 The EPA has determined that certain changes in the remedial action significantly differ
 from the remedial action originally selected in the September 30, 1988 ROD for the Site.
 This document describes these differences and the reasons why these changes to the
 remedy described in the ROD are necessary.

-------
Summary Of The Changes In The Selected Remedy Which Require An ESP

EPA's issuance of this ESD is necessary because of changes in the remedy for the cleanup
of contamination in groundwater, as originally specified in the ROD.  The changes involve
eliminating the requirement to design, install, operate and maintain a groundwater
treatment system on the Valley/GRC property, using aeration (air stripping) and carbon
adsorption to treat contaminated groundwater. Groundwater will still be extracted from
the Valley/GRC property but will not be treated on the property.  Instead, the extracted
groundwater will be transferred (piped) to a Management of Migration treatment facility
to be located adjacent to the Valley/GRC property. This property is presently owned by
the Archdiocese of Boston. The contaminated groundwater will subsequently be treated
with ultraviolet light/oxidation treatment.

As anticipated in the ROD, a groundwater recovery system will be designed, installed,
operated and maintained on the Valley/GRC property. However, the changes discussed in
this ESD eliminate the requirement to design, install, operate and maintain a groundwater
recirculation system.

These changes do not fundamentally alter the remedy selected in the ROD. Considering
the new information that has been developed and the changes that have been made to the
selected remedy, the EPA and the MA DEP believe that the remedy remains protective of
human health and the environment, complies with Federal and State requirements that are
applicable or relevant and appropriate to this remedial action, and is cost-effective.  In
addition, the revised remedy utilizes permanent solutions and alternative treatment (or
resource recovery) technologies to the maximum extent practicable for this site.

Public Information Meeting. Comment Period  And Announcement Of Statement
That The ESD Will Become Part Of The Administrative Record File

The EPA held a public information meeting on the proposed ESD on August 13, 1996 in
the Groveland Town Hall, at 183 Main Street, Groveland, Massachusetts.  The EPA also
provided a public comment period pursuant to Section 300.825(b) df the National Oil and
Hazardous Substances Pollution Contingency Plan ("NCP"), in order to ensure full
community involvement.  The comment period on the proposed ESD lasted 14 days,
commencing August 13,  1996, and ending August 27, 1996. The proposed ESD, this
final ESD, a transcript of the public meeting, significant public comments, and  responses
to comments, are included in the Administrative Record File for the Site.

Addresses Of Locations Where The Files Are Available And Hours Of Availability
 Of The Files

 Information pertinent to EPA's decision making process in publishing this ESD is available
 for public review at information repositories at the following locations:

-------
      EPA Records Center
      90 Canal Street, First Floor
      Boston, Massachusetts
      (617) 573-5729 Hours:
      Mon-Fri: 10:00 a.m. - 1:00 p.m.
               2:00 p.m. - 5:00 p.m.
      Closed 1st Friday of each month.

      Langley-Adams Library
      185 Main Street
      Groveland, Massachusetts
      (508) 372-1732
      Hours:
      Mon & Wed:  12:00 p.m. - 5:00 p.m.
                    6:30 p.m. - 8:30 p.m.
      Tues & Thurs: 10:00 p.m. - 5:30 p.m.
      Fri:           12:00 a.m. - 5:00 p.m.

EL    SUMMARY OF SITE HISTORY. CONTAMINATION PROBLEMS. RESPONSE
      HISTORY1 AND SELECTED REMEDY

      Site History and Contamination Problems

      The EPA placed the Groveland Site on the National Priorities List ("NPL") in 1982
      because the contamination in the municipal wells constituted a threat to public health and
      the environment. The NPL listing resulted in the initiation of studies that investigated the
      nature and extent of groundwater contamination, potential sources of the contamination
      and the pathways by which the municipal wells were contaminated. These investigations
      identified three possible sources of contamination in the Groveland Site area: (1) the A.
      W. Chesterton Company; (2) the Haverhill Municipal Landfill; and (3) the Valley/GRC
      property.
                                                                f
       1.     A remedial investigation ("RI") was performed on the Chesterton property in 1984
             and 1985 pursuant to a Resource Conservation and Recovery Act ("RCRA")
             Administrative Order. The RI determined that contamination was confined to the
             Chesterton property boundary and appeared not currently connected to
             groundwater contaminant plume area or the Stations Nos. 1 &  2 area.
             Remediation of contamination on the Chesterton property is being dealt with using
             corrective action and closure activities under RCRA authority.

       2.     The Haverhill Landfill was originally named as a potential source of contamination
             which forced closure of Station Nos.  1 & 2. The Landfill was subsequently placed

-------
      on the NPL in October 1984 as a separate site from the Groveland Wells site.
      Cleanup of the Haverhill site is being addressed under a separate CERCLA action.

3.     The EPA performed aquifer-wide Management of Migration ("MOM") RI work in
       1984 and 1985 and completed supplemental MOM RI work in 1990 and 1991.
      The RIs investigated the nature and extent of groundwater contamination,
      potential sources of the contamination and the pathways by which the municipal
      wells were contaminated.  The results of these activities revealed that an extensive
      groundwater plume, containing principally TCE and 1,2-Dichloroethene ("1,2-
      DCE"), is migrating toward the Merrimack River. The groundwater contaminant
      plume extends approximately 3,900 feet north from the Valley/GRC property,
      paralleling Johnson Creek. Highest contaminant concentrations were found near
      the Valley/GRC property, with concentrations decreasing with increased distance
      from Valley/GRC.

4.      The Valley/GRC property is considered the Source Control Operable Unit for the
       Groveland Site.  According to Valley employee accounts, as much as 3000 gallons
       of waste oil and solvent (including TCE) were released on the Valley/GRC
       property during the period 1963 to 1974. Of this amount, five to seven hundred
       gallons of TCE escaped from an underground storage tank. The balance of the
       releases came from spills or leaks into the subsurface disposal systems and use of
       waste oil containing TCE as a defoliant.

       Studies at the Groveland Site have shown that TCE released at the Valley/GRC
       property has migrated into the aquifer below the property and has extended
       beyond the boundary of the property to other areas of the Groveland Site.

Response History

 1.     Source Control Operable Unit To remediate contamination within the boundary
       of the Valley/GRC property, the EPA issued a first Record of Decision (the
       "Source Control ROD") for the Groveland Site in Septembe* of 1988. The Source
       Control ROD required cleanup of the organic chemical contamination source at
       the Valley/GRC property and approved an innovative technology consisting of soil
       vapor vacuum extraction system ("VES") to treat VOC-contaminated soil. The
       ROD also approved the installation of a groundwater recovery, treatment and
       reinjection system to treat VOC-contaminated groundwater located directly under
       the Valley/GRC property.

       Pursuant to a Second Amended Administrative Order issued on March 11, 1992,
       under CERCLA § 106(a), Valley designed a full scale soil vapor vacuum
       extraction system ("VES") and a groundwater recovery, treatment and reinjection
       system for use on its property. The EPA approved the Final (100%) Remedial

-------
      Design submission on August 24, 1992.  However, on October 8, 1992, Valley
      informed the EPA that they would no longer be able to comply with the
      Administrative Order. On November 2,  1992, the EPA issued a Notice of Failure
      to Comply with the Administrative Order.

      During a site visit to the Valley/GRC property on December 17,  1992, Valley
      informed the EPA that all of the necessary soil vapor vacuum extraction wells and
      vapor probes had been installed in accordance with the approved 100% design,
      and that the VES system is presently operating continuously 24-hours a day. On
      January 20, 1993, the EPA issued a Second Notice of Failure to Comply with the
      Administrative Order for failure to submit monthly progress reports concerning the
      VES system's progress to date in terms of sampling, monitoring, and performance
      data; the amount of contaminants removed to date; and estimates of contaminants
      remaining in the soil. However, the EPA is assuming that the PRP will continue to
      address subsurface soil contamination until subsurface soil cleanup goals are
      achieved.

      Because of non-compliance with the Administrative Order, further remedial
      design/remedial action activities related to groundwater remediation at the Valley
      Site is being accomplished by the EPA using Fund monies. The EPA has engaged
      a contractor to perform  the remedial design work for the groundwater recovery
      and treatment system.

      The Source Control ROD also required  that all drains and lines to the Brite-dip
      subsurface disposal system be effectively sealed and disconnected. In a letter dated
      March 21, 1991, Valley/GRC certified to the EPA that all drains and lines to the
      Brite-dip surface disposal system had been sealed.

2.     MOM Operable Unit  In September 1991, the EPA signed a Record of Decision
      requiring cleanup of the groundwater contaminant plume and on May IS, 1992 the
      EPA issued an Administrative Order requiring the potentially responsible parties
      ("PRPs", i.e., Valley/GRC) to remediate the groundwater contamination.

      On June 22, 1992 the PRPs responded that they would not be able to comply to
      the requirements of the  Order and on August 19, 1992 the EPA issued a Notice of
      Failure to Comply with  the Administrative Order.  The EPA is now using
      Superfund monies and has engaged Metcalf and Eddy to perform the remedial
      design work.

ESP for the Management of Migration Operable Unit ROD

Attached to this document is a  summary of information on the Management of Migration
("MOM') Operable Unit. The information recently gathered on this portion of the site has

-------
given rise to the selection of a remedy which is significantly different from the remedy that
was originally selected in the MOM ROD, dated September 1991. The attached MOM
ESD discusses activities that were taken to obtain recent groundwater contaminant
information for the site. The results of these studies show declines in TCE-contaminant
concentrations in wells located north of Main Street.  Reductions in the TCE levels were
also observed in some of the other wells that were sampled south of Main Street.

Declines in TCE-contaminant levels in some of the wells sampled has caused the EPA to
consider reducing the amount of groundwater that will need to be extracted and treated.
The EPA has decided to re-design the extraction system and to treat the more highly
contaminated portion of the groundwater contaminant plume located at Mill Pond and
south of Mill Pond. The remainder of the groundwater contaminant plume will be
remediated by natural attenuation.  ,

Summary Of The Remedy As Originally Described In The ROD

The Record of Decision ("ROD"),  signed September 30,  1988, described each of the
alternatives evaluated in remediating the contamination on the Site, and described in detail
the chosen alternative for each contaminated media of the Valley/GRC property as
follows:

Soil - design, install, operate and maintain a VES system in the vadose (unsaturated) zone
which will intercept laterally and vertically all  areas of subsurface soil contamination so as
to attain soil cleanup goals in an efficient and expeditious manner. The VES will use
carbon adsorption for vapor treatment. Carbon adsorption or equivalent treatment will
also be used for the treatment of separator water before being discharged downgradient of
the site.

The area of attainment for the soil  cleanup goals is everywhere on the Valley site unless it
is determined that a contaminant level in soil has been achieved that is not contributing to
groundwater contamination above cleanup goals. (The Valley Site means the Valley/GRC
property and all property adjacent  to but outside the boundaries of Ihe Valley/GRC
property where soil contamination is above cleanup levels in the unconsolidated zone
 above the water table elevation during the operation of the groundwater treatment
facility).

 Groundwater -  design, install, operate and maintain a groundwater
 recovery/recirculation system in overburden and bedrock. This system will intercept
 contaminated groundwater on the site in all downgradient directions (east and south) and
 recirculate a portion of treated effluent upgradient of the site to accelerate removal of
 saturated zone soil contamination.  Recovery/recirculation shall be at high rates that will
 attain the groundwater cleanup goals everywhere on the Valley/GRC property at every

-------
point in the aquifer. (The Valley/GRC property means the property owned by Groveland
Resources Corporation, located at 64 Washington Street, Groveland, Massachusetts).

Design, install, operate and maintain a groundwater treatment system using aeration (air
stripping) and carbon adsorption to treat the contaminated groundwater from the recovery
system. The extracted groundwater would be pre-treated to remove inorganic compounds
and then passed through an air stripping chamber to remove VOCs.

Approximately 30 gallons per minute ("gpm") is anticipated to be recovered from the
Valley/GRC property.  Optimum recovery rates would be developed through on-site pump
tests and other studies during remedial design.  A portion of the groundwater that passes
through the air stripper (approximately 1.5 gpm of the total 30 gpm) would be filtered
through activated carbon to remove residual contaminants and then discharged
downgradient of the Valley/GRC property.

Drains and Lines - effectively seal and disconnect all drains and lines to the Brite-dip
subsurface disposal system.

DESCRIPTION OF SIGNIFICANT DIFFERENCES AND THE BASIS FOR
THOSE DIFFERENCES

Summary Of The Information That Gave Rise To Significant Differences From The
Selected Remedy As It Was Originally Specified

As anticipated in the Source Control ROD, on-site pumping tests and other studies were
performed during remedial design in an effort to evaluate optimum groundwater recovery
rates.  Accordingly, during the period March 25-April 13, 1994 a pumping well was
drilled and installed by EPA's contractor on the Valley/GRC property.  Prior to drilling the
pumping well, a test boring was advanced in the same location to collect samples for
lithologic description, grain size analysis and determination of the presence of pure phase
organic compounds  The purpose of these activities was to obtain on-site field data for
the aquifer beneath the Valley/GRC property in the vicinity of the proposed extraction
system.

On June 19, 1994 a report was submitted by EPA's contractor detailing the results of the
aquifer yield investigation. It appears that the maximum amount of water that the aquifer
will yield beneath the Valley/GRC property, with and without reinjection, is approximately
 6 gpm and 3 gpm, respectively. The relatively low yield of the aquifer is primarily due to
 two (2) reasons: (1) the aquifer in the unconsolidated zone above the bedrock, is relatively
 thin, i.e., only about IS feet thick; and (2) the soils within most of the aquifer are fine-
 grained and poorly sorted resulting in a low permeability, i.e., the ease with which water
 will pass through the soils.

-------
It is estimated that a yield of at least 10 gpm would be needed to justify building a
groundwater treatment facility on the Valley/GRC property. The low yield of the aquifer
is insufficient to justify building such a facility.  In addition, because of the low
permeability of the soils, reinjection of water upgradient will not significantly increase the
aquifer yield to justify building a treatment facility.

Although there appears to be insufficient water to justify building a groundwater treatment
facility on the Valley/ GRC property, the EPA has decided to pursue extracting
contaminated groundwater at this location. The extracted groundwater will be treated at
the Management of Migration treatment facility.  Extracting contaminated groundwater
beneath the Valley/GRC property will accelerate the restoration of groundwater to
drinking water standards and will also lower the groundwater table, subsequently exposing
more contaminated soils to the SVE system which is presently being  operated by the
PRPs.

In conclusion, the relatively thin water bearing zone and low soil permeability has resulted
in an unanticipated low yield from the aquifer beneath the Valley/GRC property. These
recent findings has caused the EPA to eliminate the requirement to design, install, operate
and maintain a groundwater treatment system and a groundwater reinjection system.

Change In Technology

All groundwater extracted from the Valley/GRC property will be transferred (piped) to the
Management of Migration treatment facility. The contaminated groundwater will
subsequently be treated with ultraviolet light/oxidation ("UV/Oxidation") treatment. This
is a change in technology from the air aeration (air stripping) and carbon adsorption
treatment specified in the Source Control ROD.

The UV/Oxidation treatment process is actually a two-step process.  First, hydrogen
peroxide or ozone is added to the water. Subsequently, UV radiation photolyzes (breaks
down) the ozone or hydrogen peroxide. This results in the formation of highly reactive
hydroxyl ("OH") free radicals. These radicals are important becausfrthey are stronger
oxidizing agents than either ozone or hydrogen peroxide alone. These hydroxyl radicals
then oxidize (take away hydrogen by combining with oxygen) the organic contaminants in
the extracted groundwater. Once the organics are completely oxidized, the reaction
products would consist of carbon dioxide and water.

The UV/Oxidation process has been known for at least 10 years and has been evaluated
under the EPA Superfund Innovative Technology Evaluation ("SITE") program. The
 process is still considered an innovative technology, mostly because  of the small size and
 number of the existing full-scale treatment units.

-------
Two SITE project evaluations of the UV/Oxidation process revealed that high removal
efficiencies can be achieved for VOCs present in groundwater.  Both demonstrations
attained 99% removal efficiencies for TCE.  Treatability testing for the MOM treatment
facility has confirmed the feasibility of the UV/Oxidation process for this site and the EPA
has subsequently derived design parameters for treating contaminated groundwater for the
Groveland site.

The remedy provides for on-site destruction of organic contaminants in groundwater and
is a treatment process for organic contaminants that produces virtually no waste residuals.
Use of this technology eliminates possible adverse impacts of organic contaminant
transport off-site or cross-media contamination. Use of this technology permanently
destroys (not merely reduces) virtually all organic contaminants in the extracted
groundwater.

Remediation of the contaminant plume under the MOM operable unit is accomplished by
designing, installing, operating and maintaining a groundwater  extraction and treatment
system. The groundwater treatment system using UV/Oxidation is discussed above.  The
groundwater extraction system consists of a series of extraction wells located to pump and
treat the more-concentrated portions of the groundwater'contaminant plume. An
anticipated flow of approximately 145 gpm will be withdrawn from the aquifer and treated
at a MOM facility.

The added flow from the Valley/GRC property will be transferred to a MOM treatment
facility via a buried conduit from the Valley/GRC extraction wells to the treatment facility
that will be located adjacent to the Valley building. The addition of an anticipated flow of
approximately 3 gpm from the Valley/GRC property, to the anticipated flow of 145 gpm
to the MOM treatment facility, will not be significant. The flow from the Valley/GRC
property contains highly contaminated water however, and this has been designed into the
MOM treatment facility.

The EPA has performed a preliminary cost estimate for modifying both treatment facilities.
Adding contaminated water from the Valley/GRC property to  a MOM facility results in an
increase of approximately $400,000 to the life of the project. This should be compared
with $1,000,000, i.e., the cost to build and  operate a groundwater treatment facility on the
Valley/GRC property.  (The above cost excludes the costs associated with installation of
 extraction wells, pumps and associated operation and maintenance of this equipment on
the Valley/GRC property.)

 Therefore, combining the flows from the Valley/GRC property with the MOM
 contaminated groundwater, and treating the groundwater at a single facility, yields a net
 savings of about $600,000 less than the cost of building two (2) separate treatment
 facilities.
                                     10

-------
IV.   SUPPORTING AGENCY COMMENTS

      The Massachusetts Department of Environmental Protection ("MA DEP") believes that
      the UV/Oxidation has the potential to remediate the groundwater contamination on the
      Valley/GRC property and encourages the combining of contaminated groundwater into
      one treatment facility. A final determination from the MA DEP, which concurs with the
      remedial activities outlined in this ESD, is found in the Administrative Record File.

V.    AFFIRMATION OF THE STATUTORY REQUIREMENTS

      Considering the new information that has been developed and the change that has been
      made to the selected remedy, the EPA and MA DEP believe that the remedy remains
      consistent with the requirements of the ROD in that it remains cost effective and mitigates
      and minimizes damage to and provides adequate protection of public health, welfare, or
      the environment.

VL   PUBLIC PARTICIPATION ACTIVITIES

      Notice That Administrative Record Is Available For Review

      In addition to the public information meeting which was held on August 13, 1996, the
      proposed ESD and this final ESD, accompanied by any supporting information and
      analysis, is available for public review and can be found in the Administrative Record File.
       See Section I of this ESD for the addresses of the locations where this ESD is kept and
      maintained.
 By:
     Linda M. Murphy, Director     (^/               Date of Issuance
    Office of Site Remediation and Restoration
                                          11

-------

-------

-------

-------