— United States %- ? Environmental Ifrotection Agency _ '- ._-- Prevention, Pesticides And Toxic Substances - (7503W). EPA -733-B-94-001 December 1994 wERA Chemicals Registered For Active Ingredients Under FIFRA 25 15 to" ' 5 :0 --• " .. -_ -": ,- J , - s • 1 .--•" ? ' '•:[ / :| - ; n 1" Tt 1 '• IT ':. 1 - - -•; , ,- •a~ 1 ; ; - |" | ,- 1 .. _ I 1 ' I"! j: _- :• ' 'H !" ^:L >' ::: ' ,. \ -. i - | - " |] — , !•! I - 1-: '•; fl ;i 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 "' 4 ~. - Recycled/Recyclable Prtnted on paper thai contains at least 50% recycled fiber ------- ------- CHEMICALS REGISTERED FOR THE FIRST TIME AS PESTICIDAL ACTIVE INGREDIENTS UNDER FIFRA Economic Analysis Branch Biological and Economic Analysis Division OFFICE OF PESTICIDE PROGRAMS U.S. ENVIRONMENTAL PROTECTION AGENCY December 1994 ------- CHEMICALS REGISTERED FOR THE FIRST TIME AS PESTICmAL ACTIVE INGREDIENTS UNDER FIFRA The purpose of this report is to provide a summary of chemicals registered for the first time as pesticidal active ingredients under the Federal Insecticide, Fungicide, and Rodenticide Act, as amended in 1988. Data have been assembled on registrations of new active ingredients by date registered, trade name, common name, initial registrant, and type. Registration of new chemicals for pest control is one indicator of technological progress in the pesticide industry. Presented in Table 1 is a summary of all first-time chemicals registered as pesticides, by calendar year and type, covering the period 1971 through March, 1994. Table 2 summarizes data presented in Table 1 for the 24-year period (1971-94) in terms of totals, ranges (highest year, lowest year), and an annual average. Sources of these data are current records of the Agency on a chemical-by-chemical basis for the period 1971-94. Certain chemicals are registered for more than one use (e.g., insecticides and nematicides). Detailed definitions of the "pesticide-use types" are presented in Appendix III. Chemical-bv-chemical registration identifications are presented in Table 3 of this report. The last column, "Pesticide Type", shows that the majority of the newly registered chemicals fall under "Others". This rubric encompasses: attractants, antifoulants, algicides, antimicrobials (sterilizers, tuberculocides, disinfectants, virucides, fungistats, and algicides), biological fungicides and insecticides, chemical ripeners, dessicants, defoliants, feeding deterrents, fumigants, miticides (acarcides), preservatives, plant growth regulators, pheromones, and repellents. Note that only partial reporting is available for 1994. Chemicals first registered under both conditional and unconditional circumstances are identified in this table. Chemical Code numbers are presented, in square brackets, in Table 3 for all first-time registered chemicals from 1971 to March 1994. Appendix II shows the chemical names by reference number. Appendix I contains three bar charts and three pie charts that show the total first-time registrations for new active- ingredient pesticides for the calendar years 1991-1993. The remainder of Appendix I consists of additional bar charts demonstrating the trend in first-time registered pesticidal active ingredients by type for calendar years 1977-93. The charts present the trend for annual new registrations by type and totals for the same period. During the 24-year period from 1971 through 1994, an average of 14 chemicals per year (Tables 1 and 2), were registered as active ingredients. The total number of chemical active- ------- ingredient combinations registered was 330 during the same period. Insecticides and herbicides were by far the most commonly registered (totalling 190 uses), followed by fungicides (42 uses) and bactencides/slimicides (34 uses). Only ten nematicides and six rodenticides were registered during the past 24 years (Table 2). As many as 35 new chemicals were registered in a given calendar year (1975). The fewest new registrations occurred in different years (1971/4 uses- 1978/5 uses; 1977 and 1990/6 uses; and 1976/9 uses), Table 2. The data on new registration of chemicals during the last 24 years do not show trends, up or down, in the number of new registrations. This report is updated once a year to reflect new registrations each calendar year In future we will add economic data on number of acres treated with the newly registered chemicals and their share of the market. For additional information, please contact: Jihad A. Alsadek, Ph.D. Economic Analysis Branch Biological And Economic Analysis Division (703) 308-8140 Acknowledgments The author would like to acknowledge the valuable assistance of: • Mr. Charles Cook of OPP/PMSD/ISB for his excellent work in reconciling the REFS data base, the basis for this report, with the PPIS data, base • Mr. Larry Chloupek of OPP/RD/RSB for his provision of the annual New Active Ingredients list of chemicals • Mr. Edward Brandt, Acting Section Chief, and Mr. Robert Esworthy Branch Chief, of OPP/BEAD/EAB for their editorial • Dr. Arnold Aspelin of OPP/BEAD/EAB for the seminal work that launched this report • Drs. Douglas Sutherland, George Keitt, and Mr. Rafael Prieto of OPP/BEAD/BAB for checking the correctness of pesticide types vis-a-vis insecticides, herbicides and antimicrobials, respectively • Mr. Charlie Colledge of OPP/PMSD/SB for checking the remaining pesticide types not found in REFS, The Farm Chemical Handbook (1992 and 1993) and the Pesticides Manual in the PPIS database ------- Mrs. Ruby West, Messrs. Frank Ellis and Rafael Prieto of OPP/BEAD/BAB, Mrs. Rosemary Biancardi of OPP/BEAD/EAB, and Mrs. Sherry Click of OPP/BEAD/PES for their help in 'designing the report's cover and processing other aspects thereof APPENDIX I CHARTS Three bar charts and three pie charts show total first-time registrations, by pesticide type, for new active ingredient pesticides for calendar years 1991-93. 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I f rf OO 3 "H- 03 \S re § I re 5* (TO D * W — O 0 0 0 t— * Ul U) w ^ u, >— I " o VO )— * D to ^ u, H- ^ 0 o to 1 — * ^0 to to to »— * o I* t— * D O o u> o o o o LO C^\ ^y\ o oo ON to 0 o o to oo oo 50 n >-< IP |l (T a SI s re a- S' s a era SI a || O" Q| re SI a 0 a. re g_ SI a 2 re Total New Als Registered1 i re" ------- -o o I £ I OA | Q I Js; aJ 3 *w> o o> M W S n ^ O s >- •"* o o o o o o o 2 > en cs in cs c> cs o cs "*J ^ jn i""; T— 1 Os c*** en en ' J •'l' " > CS "3 3 C C ^^ 9 T—^ ------- Table 3: New Chemicals1 First Registered under FIFRA, by Date, Name, Registrant and Type, 1971-Date. DATE REGISTERED TRADE NAME COMMON NAME8 CHEMICAL CODE [...] REGISTRANT PESTICIDE TYPJB^fi:^: CALENDAR 1971 5/13/71 6/30/71 9/20/71 12/6/71 Florel Plant Growth Dipel Skane M-8 Bladex Ethephon [099801] B.T. Subsp. Kurstaki [006402] Octhilinone [099901] Cyanazine [100101] Rhone Poulenc FMC Rohm & Haas Shell PGR I B,F H CALENDAR 1972 1/5/72 1/17/72 2/9/72 2/16/72 2/16/72 4/2/72 4/6/72 4/22/72 7/12/72 7/12/72 8/1/72 8/9/72 8/23/72 9/13/72 9/20/72 9/28/72 10/11/72 10/11/72 Residol-Plus Scent-Off Paarlan Supracide Outfox Thuricide Nemacur Mesurol Amical 77 Amical 48 Monitor Sencor Plictran Metasol J-26 XD-7287L Dowpon NF Giv-gard BNS Kerb Coconut Oil [218700] Oil of Orange, Bergamot Oil, Trans- Alpha- Ionone,Geraniol[040517, 129029, 129030,597501] Isopropalin [100201] Methidathion [100301] Cyprazine [100401] Bacillus Thurengiensis (Berlinger) [006402] Fenamiphos [100601] Methiocarb [100501] 1 [101001] 2 [101002] Methamidophos [101201] Metribuzin [101101] Cyhexatin [101601] 3 [101301] 4 [101801] Dalapon [028901] 5 [101401] Pronamide [101701] West Chemical Plantabbs Blanco Ciba-Geigy Gulf Southern Agriculture Mobay Mobay Abbott Abbott Chevron Mobay Dow Merck Dow Dow Givaudance Rohm & Haas I RP H I H I N I F,B,P F,B,P I H I F B,F,AL,P,S H,PGR F,AL,S,P H ------- DATE REGISTERED TRADE NAME COMMON NAME3 CHEMICAL CODE [...] REGISTRANT PESTICIDE TYPE" CALENDAR 1973 1/4/73 1/16/73 2/15/73 2/22/73 3/30/73 4/9/73 4/13/73 5/10/73 5/23/73 6/15/73 6/21/73 8/14/73 8/21/73 9/13/73 10/23/73 11/1/73 11/2/73 11/20/73 Nellite Topsin-M Landrin A-Rest Solution Sancap Technical AMEX- 820 Torak Japanese Beetle Bait Orthene Cleary's Turf Fungicide Devrinol XD-7603 Busan 52 Lursect Muscamone Tolban Nopcocide DS-649 Hocut CA Diamidafos [102101] Thiophanate-Methyl [102001] 6 [102400, 102401, 102402] Ancymidol [108601] Dipropetryn [104401] Butralin [106501] Dialifor [102501] 2-Phenethylpropionate [102601] Acephate [103301] Thiophanate-Ethyl [103401] Napromide [103001] 7 [102801] 8 [102901,051704] Putrescent-Whole Egg Solids [105101] (Z)-9-Tricosene [103201] Profluralin [106601] 9 [103101] 10 [105601] Dow Pennwalt Shell Dow Elance Ciba-Geigy Rhone-Poulenc Ag. Hercules Ellicsco Chevron W.A. Cleary Stauffer Dow Buckman MGX Thuron Ciba-Geigy Nopco Aenreco N F I PGR H H,PGR I I(PH) I(PH) F H F,B F RP I(PH) H B,F B CALENDAR 1974 1/1/74 1/14/74 1/21/74 3/15/74 4/4/74 Pirimor Esbiol TM Intermediate 3336 Norflurazon Technical Surflan Vydate Pirimicarb [106101] Esbiothrin [004003,004004] Norflurazon [105801] Oryzalin [104201] Oxamyl [103801] ICI MGK Saridoz Blanco DuPont I I H H N,I ------- DATE REGISTERED 4/5/74 4/11/74 5/13/74 6/12/74 7/22/74 8/7/74 8/29/74 9/27/74 10/3/74 10/21/74 1 1/6/74 11/15/74 12/11/74 TRADE NAME Roundup Prefox Basagran Troysan 192 Tenox IBP-2 Grain Pr. Spike RH-787 Cidial Smite EP-475 Bioban P-1487 DE-488 Counter COMMON NAME8 CHEMICAL CODE [...] Isopropylamine Glyphosate [103601] Etiolate [103702] Bentazon-Sodium Salt [103901] 11 [104001] Isobutyric Acid [101502] Tebuthiuron [105501] Pyrinuron (Vacor) [104501] Phenthoate [104901] Sodium Azide [107701] Desmedipham [104801] 12 [100801,100802] T-Butylhydroperoxide [?] Terbufos [105001] REGISTRANT Monsanto Gulf BASF Troy Chem. Co. Farmers Union Central Exchange Elanco Rohm & Haas Thompson- Hayward PPG Industries NOR-AM CSC Betz American Cyanamid PESTICIDE TYPEb H H H AM F H R I F,H,N H P,S F,B I,N CALENDAR 1975 1/20/75 1/23/75 2/3/75 2/7/75 2/13/75 2/13/75 2/27/75 3/4/75 3/10/75 Visco 1152 Bolero Vendex Sustar (7182-3) Basalin Gardoprim Modown Altosid Polaris 13 [107601] Thiobencarb [108401] Fenbutatin-Oxide [104601] Diethanolamine Fluoridamid [105701] Fluchloralin [108701] Terbuthylazine [080814] Bifenox [104301] Methoprene [105401] Glyphosine [103602] Nalco Chevron Shell 3M BASF Ciba-Geigy Mobil Zoecon Monsanto S H I PGR H H H I(GR) CR 10 ------- DATE REGISTERED 3/13/75 3/20/75 3/25/75 3/28/75 3/31/75 4/24/75 5/23/75 6/23/75 7/7/75 7/9/75 7/25/75 7/29/75 8/4/75 8/12/75 9/16/75 9/18/75 9/19/75 10/16/75 10/17/75 10/23/75 10/24//75 TRADE NAME Potable-Aquatablets Sumithion Probe Cosan 265 U-36,059 Primicid Visco P-25-F Ficam Avenge T.B.Q Germicidal Detergent Mark II Prowl Dow Corning 5700 Krenite Asulox Troysan KK-108A Plondrel S-2539 Forte Biomet 204 4WC3 17 Asulam, Technical COMMON NAME8 CHEMICAL CODE [...] Tetraglycine-Hydroperiodide [046923] Fenitrothion [105901] Methazole [106001] 14 [106801] Amitraz [106201] Pirimiphos-Ethyl [108101] 2-Nitro- 1 -Butylphosphate [056902] Bendiocarb [105201] Difenzoquat Methyl Sulphate [106401] Hyamine 3500, Ethoxylated Cocoamine [069105,079097] Silver Chloride [072506] Pendimethalin [108501] X9-5700 [107401] Fosamine Ammonium [106701] Sodium Asulam [106902] 15 [107801] Ditalimfos [106301] 16 [069005] Triphenyltin Fluoride [083602] 17 [067321] Asulam [106901] REGISTRANT Wisconsin Pharrnacal Co. Sumitomo Velsicol Cosan Chemical Corp. Upjohn Co. ICI Nalco Fisons American Cyanamid Vestal Labs Electrolux Corp. American Cyanamid Dow Corning Corp. DuPont Rhone-Poulenc Troy Chem. Co. Dow Chemical Co. Sumitomo M&T Nalco Rhone-Polenc PESTICIDE TYPE" B,AM I H I,F I I B I H B,S,AM,P,M B H AM PGR H AL F I H,AF,AL B H 11 ------- DATE REGISTERED 10/30/75 11/13/75 12/2/75 12/22/75 12/22/75 TRADE NAME Nuosept 95 Velpar Elcar Enstar Epic Algaecide COMMON NAME8 CHEMICAL CODE [...] 18 [107004] Hexazinone [107201] Nuclear Polyhedrosis Virus Of Heliothis Zea [107301] Kinoprene [107501] 19 [169138] REGISTRANT Auls America, Inc. DuPont Sandoz Zoecon Epic Chem. Co. PESTICIDE TYPEb S,P H I I(GR) B CALENDAR 1976 1/1/76 1/1/76 1/12/76 3/10/76 4/6/76 5/6/76 6/3/76 6/9/76 8/11/76 Hydro-Giene Cobex Funginex Destun Dibromantin Dimilin Steri-Chem DM 40 Uniquat CB-50 Biocontrol-1 Cuprous Iodide [108301] Dinitramine [102301] Triforine [107901] Perfluidone [108001] 20 [006317] Diflubenzuron [108201] 21 [083202] 22 [046621] NPH Tussock Moth [107302] Water Science U.S. Borax EM Labs 3M Filter International Thompson- Haywood Thompson Research Lonza USDA B H F H S,P,M I(GR) B M,P I(PH) CALENDAR 1977 4/1/77 4/7/77 4/19/77 5/24/77 8/30/77 12/7/77 Metolachlor, Technical BK LFI 2 Kathon WT Ronstar Zardex Nortron Metolachlor [108801] 23 [046924] 24 [107103,107104] Oxadiazon [109001] Cycloprate [115601] Ethofumesate [110601] Ciba-Geigy Pennwalt Rohm & Haas Chipman Zoecon Fisons H B S,P,AM H I H CALENDAR 1978 2/9/78 Gossyplure 25 [114103] Conrel I 12 ------- 1 •' ~^ ~ — 7 — T— — — J>^feS-l^ REGISTERED 2/22/78 4/12/78 7/7/78 12/22/78 1/4/79 1/23/79 1 2/14/79 2/27/79 3/9/79 3/13/79 4/7/79 4/11/79 4/19/79 5/8/79 5/17/79 5/28/79 6/12/79 6/29/79 8/20/79 8/20/79 8/27/79 11/2/79 -i — — TRADE NAME Embark Gypchek Cytex - [ ======; = COMMON NAME* CHEMICAL CODE [...] Mefluidide [114002] NPH [107301] Cytokinin [116801] Tributyltin-Methacrylate [83120] •" B" —•! REGISTRANT 3M USDA A&P Research Courtalds CALENDAR 1979 Galltrol-A Iprodione Bolstar Embark (2-S) Promalin Pydrin Atrinal Pounce/Ambush Fumi-Cel Garlon Goal Plant Pin lidomil Bag-A-Bug Disparlure Grandlure Bayleton Talon Agrobacterium Radiobacter [114201] 26 [109801] Sulprofos [111501] Diethanolamine Mefluidide [114002] 27 [116901, 116902] Fenvalerate [109301] Dikegulac Sodium [109601] Permethrin [109701] Magnesium Phosphide [066504] Triethylammonium Triclopyr [116001] Oxyfluorfen [111601] Butoxycarboxim [113001] Metalaxyl [113501] (R,Z)-5-(Idecenyl) dihydro-2(3H)-furanone [?] 28 [114301] 29 [112401,112402,112403,112404] Triadimefon [109901] Brodifacoum [112701] AG Biochem Chipman- Rhodia Mobay 3M Abbott DuPont Agri. Products Hoffman- LaRoche FMC/ICI Degeschin Dow Rohm & Haas Henley Ciba-Geigy Baker Chemical Hercon Hercon Mobay CI 1 PESTICIDE TYPE* PGR I PGR AF,B F F I H,PGR PGR I PGR I I(FU) H H T P I(PH) I(PH) (PH) 7 R 13 ------- DATE REGISTERED TRADE NAME COMMON NAME8 CHEMICAL CODE [..;] REGISTRANT PESTICIDE TYPEb CALENDAR 1980 2/22/80 2/26/80 3/31/80 4/2/80 4/10/80 4/17/80 5/9/80 8/20/80 8/22/80 10/29/80 12/5/80 Propetamphos Milban Hoelon Metasol D Blazer Fix Noloc Amdro Amaze (Oftanol) Nomate Shootgard Maki Propetamphos [113601] Dodemorph Acetate [110401] Diclofop-Methyl [110902] Dazomet, Sodium Salt [035607] Sodium Acifluorfen [114402] Mepiquat Chloride [109101] Nosema Locustae [117001] Hydramethylnon [118401] Isofenphos [109401] 30 [?] Bromadiolone [112001] Sandoz Mallenckrodt American Hoechst Calgon Rohm & Haas BASF Sandoz American Cyanamid Mobay Conrel Chempar I F H B,F,M H PGR I I I PH R CALENDAR 1981 2/11/81 2/24/81 3/6/81 3/25/81 4/14/81 5/1/81 5/11/81 7/28/81 8/3/81 8/14/81 8/24/81 9/9/81 Ronilan N-Maleimide Hefty Dog and Cat Repellent De Vine Bollex N-Trap Elm Bark Beetle Aquashade Mycar 1 Baguacil Tilt (OGA-64250) Ultrafresh DM-50 Accel Vinclozolin [113201] 31 [113701] Cinnamic Aldehyde [040506] Phytophthora Palmivora [111301] 32 [118501] 33 [?] 34 [110303] Hirsutella Thompsonii [?] 35[?] Propiconazole [122101] Tributyltin Maleate [083118] 36 [110001] BASF Abbott Mobile Abbott U.S. Soil Conrel Aquashade Abbott Labs. ICI Ciba-Geigy Thompson Shell F P RP H FD PH AL I D F BF PGR 14 ------- DATE REGISTERED 9/28/81 11/3/81 11/5/81 11/6/81 11/17/81 TRADE NAME Nem-a-Tak Embark (2-L) - Fruit Builders Fish Oil Paradox COMMON NAME8 CHEMICAL CODE [...] Fosthietan [113301] Mefluidide, Potassium Salt [114003] Tributyltin-Methacrylate [?] Fish Oil [112401] Paradox [114901] REGISTRANT American Cyanamid Co. 3M M&T Chemicals Fruit Builders, Inc. Rousell PESTICIDE TYPEb N,I PGR AF RP S CALENDAR 1982 1/15/82 1/18/82 2/1/82 2/3/82 2/3/82 2/8/82 2/12/82 2/19/82 4/13/82 Pay Off Intersept Nomate Suppress 2 Prevex Previcur N Oust Antor Marstat PN Luretape/Bagworm Flucythrinate[118301] 37 [129079, 129080] (E)-4-Tridecen-l-Yl, Acetate (Z)-4-tridecen-l-Yl [?] Propamocarb [119302] Propamocarb hydrochloride [119302] Sulfometuron Methyl [122001] Diethatyl-Ethyl [?] 38 [129079,129080] 39 [123401] American Cyanamide Interface Co. Albany Int. Norm-Am Nor- Am DuPont BFC Chemicals Che m mar Associates Hercon I AM,F I(PH) F F H H D I(PH)* * Initial 3(C)(5) registration paperwork completed by USDA. 5/24/82 6/25/82 6/29/82 6/30/82 7/23/82 7/26/82 Poast Dropp Curacron College Glean Fungisol Sethoxydim [121001] Thidiazuron [120301] Profenofos [011401] Colletrichum Gleosporoides Spores [?] Chlorsulfuron [118601] DEBC [115001] BASF NOR-AM Ciba-Geigy Upjohn DuPont J.J. Mauget Co. H D,PGR I H H F 15 ------- DATE REGISTERED 8/9/82 8/13/82 10/14/82 10/21/82 1 1/8/82 1 1/24/82 TRADE NAME Epibloc Harvade VEL 4359 50W Bromethalin Bait Requat Metronidazole COMMON NAME" CHEMICAL CODE [...] 40 [117101] Dimethipin [118901] Dicamba, Aluminum Salt [129042] Bromethalin [112802] 41 [169160] 42 [120401] REGISTRANT Pestoon Systs.Inc. Uniroyal Velsicol Chemical Corp. Elanco Wm. G. Roessler Searle & Co. PESTICIDE TYPE" R PGR,DF H R AM S CALENDAR 1983 2/18/83 2/25/83 3/18/83 3/25/83 4/4/83 4/20/83 5/27/83 7/18/83 8/2/83 8/25/83 9/21/83 11/28/83 Pro-Drone, MV-678 Neochek-S Nomate-Bl ockai de Mavrik Aquaflow Mandate Fusilade 4E Prime + Fungaflor Aliette Belclene 310 Cosan 145 Sonalan 43 [119501] Preserve [107304] Decatriene [125901] Fluvalinate [109302] Octanoic Acid & Decanoic acid [128919,128955] Fluazifop-Butyl [122805] Flumetralin [123001] Imazalil [111901] Fosetyl-AL [123301] Dimethametryn [080815] 44 [123702] Ethalfluralin [113101] Stauffer U.S.D.A.Forest Service Albany International Zoecon Corp. Ecolab ICI Ciba-Geigy Janssen R&D Inc. Rhone-Poulenc Ciba-Geigy Cosan Chem. Co. Elanco I(PH) I I(PH) I B H H F F H F H CALENDAR 1984 1/29/84 2/10/84 2/15/84 Triacon Larvin Arosurf MSF 45 [116201] Thiodicarb [114501] Arosurf [124601] Biochem. Rsch. Union Carbide Sherex PGR I I 16 ------- DATE REGISTERED 5/2/84 5/23/84 6/12/84 7/31/84 8/2/84 9/12/84 9/25/84 11/9/84 11/13/84 1/9/.85 1/23/85 2/21/85 3/8/85 5/9/85 6/6/85 7/1/85 7/9/85 9/6/85 10/2/85 10/3/85 1/16/86 2/10/86 TRADE NAME Periplanone-B Altozar Cymbush/Ammo Arsenal Bronopol or Onyxide 500 Dantochlor Actellic Quintox Rubigan COMMON NAMEa CHEMICAL CODE[...] Lure & Kill Roach & Ant Killer with Sex Lure [124801] Hydroprene [486300] Cypermethrin [109702] Izamethapyr, Isopropylamine salt [128829] 46 [216400] Hydantoin [128826] Pirimiphos-Methyl [108102] Cholecalciferol [202901] Fenarimol [206600] REGISTRANT Hercon Environmental Co. Zoecon' Corp. ICI/FMC American Cyanamid Boots Glyco Inc. ICI Bell Labs Elanco PESTICIDE TYPEb I(A) I(GR) I H AM,S AM,AF,S I R F CALENDAR 1985 Flea Killer Plus PP005 2E Herbicide Magna CP-1 GlycoServe Larvadex Premix Clipper 50WP Reldan Margosan-0- Concentrate Scout X-TRA Talstar Linalool S-Methoprene [105402] Fluazifop-P-Butyl [122809] Potassium Cresylate [128870] MDM Hydantoin, DMDM hydantoin[ 11550 1,1 15502] Cyromazine [121301] Paclobutrazol [125601] Chlorpyrifos-Methyl [059102] Azadirachtin, Neem [121701] Tralomethrin [121501] Bifenthrin [128825] Linalool [128838] Johnson Zeneca Magna Technologies Glyco Inc. Ciba-Geigy ICI Americas Dow Vikwood Roussel-Uclaf FMC Pet Chemicals I(GR) H AM AM,S I(GR) H(PGR) I I I I I CALENDAR 1986 Standak Tandem Aldoxycarb [110801] Tridiphane [123901] Union Carbide Dow Chemical I, N H 17 ------- DATE REGISTERED 2/20/86 3/20/86 3/20/86 1 3/21/86 1 3/24/86 13/27/86 1 3/28/86 J4/4/86 4/18/86 14/25/86 I 9/15/86 1 12/3/86 12/29/86 TRADE NAME Zoecon RF-316 Scepter Herbicide Scepter Sonar Hybrex Command Ally Classic Affirm, Avid, Agri-Mek Harmony YEA Isomate-M Asana XL COMMON NAME8 CHEMICAL CODE [...] (7S)-Hydroprene [128966] Imazaquin [128840] Ammonium Imazaquin [128848] Fluridone [112900] Fenridazone-Potassium [119001] Dimethazone [125401] Metsulfuron-Methyl [122010] Chlorimuron-Ethyl [128901] Abamectin (Avermectin B,) [122804] Thifensulfuron-Methyl Pinnacle [128845] Chitosan [128930] Pheromone Dispensers [128906,128907,128908] Esfenvalerate [109303] REGISTRANT Sandoz American Cyanamid American Cyanamid Blanco Products Rohm & Haas FMC E.I. Dupont E.I. Dupont Merck & Co., Inc. MSD Aged Div. DuPont Natural Ag.~ Benthic Labs, Inc. Biocontrol, Ltd, Australia * DuPont CALENDAR 1987 1/2/87 1 1/30/87 I 3/18/87 3/23/87 1 3/23/87 Enstarll Growth Regulator Whip, Furore Cobra Lontrel Arsenal S-Kinoprene [107502] Fenoxaprop-Ethyl [128701] Lactofen [128888] Clopyralid [117403] Imazapyr [128821] Sandoz Agro. American Hoescht Agro- Vet Co. PPG Industries, Inc. Dow Chemical American Cyanamid PESTICIDE TYPEb I(GR) H H H(Aquatic) HA H H H I(MI) H PGR PH I(GR) KGR) H H H H 18 ------- DATE REGISTERED 4/7/87 4/10/87 6/25/87 8/5/87 8/7/87 9/2/87 10/6/87 10/16/87 12/30/87 1/29/88 2/17/88 3/3/88 4/11/88 4/25/88 . 4/29/88 5/12/88 TRADE NAME Stirrup Reflex Triumph, Miral LN-2 Busan 1024 Moth-Away Bromine Chloride Baythroid ENQUIK (N-Tac) =========== COMMON NAME" CHEMICAL CODE[...] Farnesol, Nerolidol [128910,128911] Fomesafen [123802] Isazophos (CG A- 12223) [126901] Liquid Nitrogen [128934] 47 [128889] Mint Herbs, Rosemary Herbs, Thyme Herbs, Clove (Crushed) [128892,128893,128894] Bromine Chloride [020504] Cyfluthrin [128831] Urea Sulfate [128961] ====^=^ REGISTRANT Fermon Chemicals, Inc. ICI Plant Protection Div. Ciba-Geigy Corp. Blizzard Systems Buckman Labs. Inc. Sun-Ray Ind. Great Lakes Chemical Corp. Ethyl Corporation Miles Unocal CALENDAR 1988 Sharp Shooter Weed and grass killer Nematrol Dagger G Assert Buctril 4 Propel San Diego (M- ONE) Potassium Salts Of Acids [079021,217500] Ground Sesame Stalks [128970] Pseudomonas fluorescens [006440] AC 222,293 [128842] Bromoxynil Heptanoate [128920] Lactic Acid [128929] Bacillus Thuringiensis [128946] Safer, Ltd. Bob McBrayer Co. Ecogen, Inc. American Cyanamid Co. Rhone-Poulenc Brae Agricultural Service Mycogen.Inc. 1 (I PESTICIDE TYPEb PH H I I B FD,RP S T H,D H N BF H H PGR KM) 19 ------- OATE REGISTERED 5/13/88 6/10/88 9/7/88 12/12/88 1/13/89 2/2/89 2/17/89 2/22/89 3/7/89 3/8/89 p/10/89 1 3/23/89 U/13/89 M/24/89 4/28/89 6/16/89 6/30/89 17/31/89 19/11/89 FRADE NAME Karate Assure/DPX-6202 Glyphosate- Trimesium Int. Trident COMMON NAME" CHEMICAL CODE [...] Lambda-Cyhalothrin [128897] Quizalofop-Ethyl[128711] Glyphosate [417300] Bacillus Thuringiensis tenebrionis [006405] REGISTRANT [CI Agrochemicals Co. E.I. DuPont de Nemours Monsanto Sandoz CALENDAR 1989 Force Rally Ixjndax Gutless Pursuit Pursuit Herbicide Apollo GX-071 Savey Confront Baytan Prolan Express Binab T Tech. Muscalure Tefluthrin [128912] Myclobutanil Systhane [128857] Bensulfuron Methyl Ester [128820] Flurprimidol [125701] Imazethapyr [128922] imazethapyr, Ammonium Salt [128923] Clofentezine [125501] Sulfluramid [128992] Hexythiazox [128849] Triclopyr [116001] Triadimenol [127201] Isoxaben [125851] Tribenuron-Methyl [128887] Trichoderma Harzianum ATTC [128903] (E)-9-Tricosene [103202] CI Agrochemicals Co. Rohm & Haas E.I. Dupont de vfemours BLANCO American Cyanamid American Cyanamide NORAM Griffin Dupont Dow Mobay BLANCO E.I. Dupont de Nemours Binab, USA Denka PESTICIDE TYPEb I(MI) H H I(M) F H PGR H H I(MI) I I(MI) H F H H BF I(PH) 1 20 ------- IDATE : --i^--'1 REGISTERED 9/21/89 9/21/89 12/22/89 1/9/90 5/11/90 6/29/90 7/9/90 11/21/90 1 1/27/90 2/5/91 2/28/91 6/18/91 6/27/91 6/27/91 7/3/91 TRADE NAME Cutluss Bioinsecticide Cordon Bioinsecticide Danitol Touchdown Beacon, Rifle Accent Grape Berry Moth Pheromone WRC GL-21 Kodak F-STOP Foil Isomate C Dimension MVP M-ONE Plus ' XE-1019D rechnical Drtho Prunit Tree 3rowth Regulator 3-3307 1 COMMON NAME" CHEMICAL CODE [...] B.T. Kurstaki (EG 2371) [006423] B.T. Kurstaki (EG 2348) [006424] Fenpropathrin [127901] CALENDAR 1990 Sulfosate [128501] Primisulfuron-Methyl [128973] Nicosulfuron (DPX-V9636) [129008] 11-Tetradecenyl Acetates [128980,129019] Gliocladium Virens G-21 [129000] Trichoderma -Harzianum [119202] CALENDAR 1991 EC 2424 [006422] Pheromone [001509,001510,129028] Dithiopyr [128994] B.t.Var. Kurstaki encapsulated delta endotoxin of [006409] B.t.Var. Sandiego encapsulated delta endotoxin of [006410] Uniconazole (Sumagit) [128976] =p======= REGISTRANT Ecogen Ecogen Sumitomo Chemical Company ICI American Ciba-Geigy Ag. Div. DuPont Ag. Prod. locontrol, Ltd. W. R. Grace Eastman Kodak Ecogen Biocontrol, Ltd. Monsanto Co. Mycogen Corp. I Mycogen Corp. Sumitomo Chemical Co., Ltd. 1 11 PESTICIDE TYPEb I(M) I(M) I(MI) H H H PH BF BF I(M). PH H BI BI PGR 21 ------- 'DATE FSISTERED i/91 8/8/91 1 8/15/91 J8/21/91 18/27/91 10/4/91 10/24/91 1 12/28/92 1 1/28/92 2/7/92 2/27/92 ~ 3/26/92 1 6/1/92 |7/ 10/92 1 ======= FRADENAME FIREBRAKE ZB Tiller Herbicide NA Steris 20-D S2703 Forte A 815/NF- 1 14/Procure Triflumidazole Trifmine Procure Terraguard Blue Circle Select Rydex/Endurance Sandofan/Recoil CGA 131036 Fury Insecticide GUS 2000 Biofungicide Concentrate, Kodial ======*. COMMON NAME" CHEMICAL CODE [...] Zinc Borate [128859] Lagenidium Giganteum [129084] Fenoxaprop-Ethyl [?] Bacillus Sphaericus [119801] Sodium Perborate monohydrate, acetylsalicylic acid [011105,129061] Cyphenothrin(BSI) [129013] Triflumizole [128879] Pseudomonas Cepacia Type Wisconsin [006419] CALENDAR 1992 Clethodim[121011] Prodiamine [110201] Oxadixyl [126701] Triasulfuron (Amber) [128969] Zeta-Cypermethrin [129064] Bacillus Subtilis [129068] REGISTRANT 624 U.S. BORAX RESEARCH CORP. CA Dept. Of Health Services. Hoechst Celanese NA Steris Corp. Sumitomo Chemical Co., Ltd. Nippon Soda Co., Ltd. Uniroyal Chemical Co., Inc. Stine Microbial Products Chevron Chemical Co. Sandoz Crop Protection Corp. Sandoz Ltd. Ciba-Geigy Ag. Div. Ciba-Geigy Ltd. FMC Corp. Gustafon Inc. PESTICIDE 1 rYPEb BI H B BF I F BF,N H H F H I BF 22 ------- DATE REGISTERED 8/19/92 8/20/92 9/8/92 9/17/92 10/13/92 10/23/92 12/9/92 2/10/93 2/11/93 3/5/93 4/13/93 4/21/93 5/11/93 5/11/93 6/17/93 6/29/93 8/5/93 TRADE NAME Econosan Acid Sanitizer Xentari Agree Frostban Facet Tough Scimitar ============== COMMON NAME8 CHEMICAL CODE [...] Decanoic Acid [128955] Bacillus Thuringiensis Var. Aizawai [006403] Bacillus Thuringiensis Aizawai Strain GC-91 [006426] Pseudomonas Syringae 742 RS [006411,006438,006439] Quinclorac [128974] Pyridate [128834] Cyhalothrin [128867] ====== REGISTRANT West Agro. Abbott Laboratory Ciba Geigy Corporation Frost Technology Inc. BASF Agrolinz, Inc. Zeneca CALENDAR 1993 Roach-Repel Cimectacarb (Promo/Vision) Frontier Herbicide Mycostop Biofungicide Rootall Spod-X Wettable Powder Bio Path Enzone Ignite ISC lerbicide BMP- 123 Cinnamomum [129066] Trinexapac-Ethyl [112602] Dimethenamid [129051] Streptomyces Griseoviridis [129069] S-Phenyl Indolbutanethiolate [128958] Spodoptera Exigua NPV [129078] Metarhyzium Anisopliae Strain ESF1 [129056] Sodium Tetrathiocarbonate [128904] Glufosinate-Ammonium [128850] Bacillus Thuringiensis Subsp. Kurstaki HD-263 [006407] R.C.G., Inc. Ciba-Geigy Sandoz Agro. Kemira Agro. OY Gro Tech. Incorpo rated Crop Genetics International Eco Science Corporation, Roussel Uclaf Corp. Unocal Hoechst Becker Microbial Product, Inc. 1 "|| PESTICIDE TYPE" B I(M) I(M) BF H H I RP.FD GR H BF PGR I(M) BI I(MI),F,N H I(M) 23 ------- ======== DATE REGISTERED 8/9/93 1 8/26/93 1 9/8/93 9/30/93 10/4/93 10/20/93 10/20/93 1 1/29/93 1 12/22/93 1 2/28/94 1 3/2/94 1 3/10/94 3/11/94 |3/18/94 ========= TRADE NAME Prostar, Folistar Bioban CS-1246 Fungisol Sinesto B Dr. Biosedge Broadstrike DTEA Antimicrobial Dormex Sentinel Turf Fungicide =========================== COMMON NAME8 CHEMICAL CODE [...] Flutolanil [128975] Oxazolidine [128909] Methyl 2- Benzimidazolecarbamate [128872] Coco Alkyl Trimethyl ammonium chloride [129012] Puccinia cunaliculate lagerheim [129085] Flumetsulam [129016] 2-(Decylthio)Ethanamine hydrochloride [128963] Hydrogen Cyanamide [014002] Cyproconazole [128993] CALENDAR 1994 Anti-Foulant C- 9211M Deltamethrin Tech. NAF-46 Harness. NTN 33893 48 [128101] Striker [978051] Hexaflumuron [118202] Acetochlor [121601] Imidacloprid [129099] REGISTRANT Nor-AM Chemical Co. Angus Chemical Co. J.J. Mauget Co. Akzo Chemical Incorporated Tifton Innovation Corporation Dow Elanco Dow Chemical Co. SKW Trostberg Ag. Sandoz Agro, Inc. Rohm & Haas Roussel Uclaf Dow Elanco Zeneca, Inc., Monsanto Agri. Co., Acetochlor Reg. Partnership Miles PESTICIDE TYPE" P P F F H H AM,S,M PGR F AF I I(PH) H 1 24 ------- DATE REGISTERED TRADE NAME COMMON NAME" CHEMICAL CODE [...] REGISTRANT PESTICIDE TYPE" 1. Fifteen new ai chemicals have been dropped because they do not have registered products (AIB, Torelle, Edolan U, IF-21, Kathon 886, Lignasan BLP, Nibroxane, Nomage, Luretape, Nomate' Vantage, Erythrosine B, Doo Not, Capsicum, Mon 4620, Clandosan 618). [..] Chemical code number, and [?] Chemical code number is missing. - Not available. * Kennedy Consultants in U.S. ** Registration application withdrawn by company before completion. a See Appendix II for numbered entries. b See Appendix III for explanation of pesticide-use types. 25 ------- APPENDIX II Chemical Names bv Reference Number No known common names existed for these chemicals at the time of initial registration. Their chemical names are listed below by reference number. 1. P-Chlorophenyl Diiodomcthyl Sulfone. 2. Diiodomethyl P-Tolyl Sulfone. 3. Potassium N-[(Nitroethyl)Benzyl] Ethylenediamine. 4. 2,2-Dibromo-3-nitrilopropionamide. 5. Beta-Bromo-Beta-Nitrostyrene. 6. 3,4,5-Trimethylphenyl Methylcarbamate and 2,3,5-Trimethylphenyl Methylcarbamate. 7. 2,3,5-Trichloro-4-(Propylsulfonyl)Pyridine. 8. Potassium N-Hydroxymethyl-N-Methyldithiocarbamate+2-Mercaptobenzothiazole, Sodium Salt. 9. 3,3,4,4,-Tetrachlorotetrahydrothiophene-l, 1-Dioxide. 10. Hexahydro-l,3,5-Tris(2-Hydroxypropyl)-s-Triazine. 11. 2-[(Hydroxymethyl)Amino]-2-Methyl-l-Propanol. 12. 4(2-Nitrobutyl)Morpholine and 4,4'-(2-Ethyl-2-Nitrotrimethylene) Dimorpholine. 13. 3-Alkoxy*-2-hydroxypropyl trimethyl ammonium chloride*(100%C12-C)14.1,r(2- Butylene)Bis(Triaza-l-Azoniadamantane. 14. l,r-(2-Butenylene)bis(3,5,7-triaza-l-azoniaadamantane chloride). 15. 3-Iodo-2-PropynylButylcarbamate. 16. 3-Phenoxybenzyl D-Cis and Trans-2,2-Dimethyl-3-(2- Methylpropenyl)CyclopropaneCarboxylate. 26 ------- 17. Alkyl(60%C14,30%C16,5%C12,5%C18)Dimethylbenzyl Ammonium Chloride+Alkyl(68%C12,32%C14).Dimethyl Benzyl Ammonium Chloride+N-(2- Cyanoethyl)-N'-Alkyl(C6-C18)-l,3-Diaminopropane. 18. 5-(Hydroxymethyl)-l-Aza-3,7-Dioxabicyclo(3.3.0) Octane + % Hydroxypoly[Methyleneoxy(74%C2,21 %C3,4%C4,1 %C5)] Methyl-l-aza-3,7- Dioxabicyclo(3.3.0)Octane 19. Tris(2-Hydroxyethyl)Benzyl Ammonium Chloride and Alkyl(70%C12,24%C14,5%C16,l%C10)Dimethyl Benzyl Ammonium Chloride 20. l,3-Dibromo-5,5-Dimethylhydantoin. 21. Tripropyltin Methacrylate. 22. 2-(Coco Akyl)-l-Benzyl-l-(Hydroxyethyl)-2-Imidazolinium Chloride. 23. Poly(Oxyethylene)Ethanol Monoesters of 5-(or 6-)Carboxy-4-Hexyl-2-Cyclohexane-l- Octanoic Acid-Iodine Complex. 24. 5-Chloro-2-Methyl-3(2H)-Isothiazolone, and 2-Methyl-3(2H)-Isothiozolone. 25. 7,11-Hexadecadien-l-Ol, Acetate, (Z,E)-, 7,11-Hexadecadien-l-Ol, Acetate, (Z,Z)- 7,11-Hexadecadien-l-Ol, Acetate. 26. 3-(3,5-Dichlorophenyl)-N-(l-Methylethyl)-2,4-Dioxo-l-ImidazolidineCarboxamide. 27. N-(Phenylmethyl)-lH-Purin-6-Amine. I 28. Cis-7,8-Epoxy-2-Methyloctadecane. 29. (E)-(3,3-Dimethylcyclohexylidene)Acetaldehyde+(Z)-(3,3- Dimethylcyclohexylidene) Acetaldehyde+(Z)-2-(3,3- Dimethylcyclohexylidene)Ethanol+(IR-Cis)-l-Methyl-2-(l-Methylethenyl)Cyclobutane Ethanol. 30. (Z)-6-Dodecenyl Acetate, (E)-6-Dodecenyl Acetate. 31. N-(2-Methyl-l-Naphthyl)Maleimide. 32. Methyl Alpha-Eleostearate;Methyl Ester of (E,Z,E)9,ll,13-Octadecatrienoic Acid. 27 ------- 33. (2)-ll-Hexadecenal, (Z)-9-Tetradecenal, or (-)-a-Cubebene;(-)-4-Methyl-3-Heptanol;-A- Multistriatin. 34. Aquashade. 35. Poly(IminoimidocarbonyliminoimidocarbonyliminohexamethyleneHydrochloride). 36. N-(Phenylmethyl)-9-(Tetrahydro-2H-Pyran-2-Yl)-9H-Purin-6-Amine. 37. Phosphoric Acid, Mono(2-Ethylhexyl)Ester, Phosphoric Acid, Mono(2- Ethylhexyl)Ester'(Compounds With Diethanolamine-N-Coco Alkyl Derivatives), Phosphoric Acid, Bis(2-Ethylhexyl)Ester(Compounds With Diethanolamine-N-Coco Aklyl Derivatives). 38. Dodecyl Bis(Hydroxyethyl)Dioctyl Ammonium Phosphate and Dodecylbis(Hydroxyethyl)Octyl Hydrogen Ammonium Phosphate. 39. 1-Methylbutyldecanoate. 40. 3-Chloro-l,2-Propanediol[Alpha-Clorohydrin,Alpha-Monochlorohydrin, 3-Chloro-l,2- Dihydroxypropane, 3-Cgloropropylene Glycol. 41. N,N-Didecyl-N-Methyl-3-(Trimethoxysilyl)Propanaminium Chlorides. 42. 2-Methyl-5-Nitriomidazole-l-Ethanol. 43. l-(8-Methoxy-4,8-Dimethylnonyl-4(l-MethylethyI)Benzene. 44. Methanol, [[[2-(Dihydro-5-Methyl-3(2H)-Oxazolyl)-l-Methyl] Ethoxy] Methoxy] Methoxyl]. 45. -1-Triacontanol. 46. 2-Bromo-2-Nitropropane-l ,3-Diol. 47. Methyl-3,5,7-Triaza-l-Azoniatricyclodecane Chloride. 48. 4,5-Dichloro-2-Octyl-3(2H)-Isothiozolone. 28 ------- APPENDIX III EXPLANATION OF PESTICIDE-USE TYPES A - Attractant AF - Antifoulant AL - Algicide AM - Antimicrobial (Sterilizer, Tuberculocide, Disinfectant, Virucide, Fungicide/Fungistat, Algicide) B - Bactericide BF - Biological Fungicide BI - Biological Insecticide CR - Chemical Ripener D - Desicant DF - Defoliant F - Fungicide FD - Feeding Deterrent FU ~ Fumigant GR - Growth Regulator H - Herbicide HA - Hybridizing Agent I - Insecticide M ~ Molluscicide MI - Miticide (acaricide) N - Nematicide P - Preservative PGR- Plant Growth Regulator i 29 ------- PH - Pheromone R - Rodenticids RP - Repellent S - Slimicide 30 ------- ------- ------- |