Statistical Support Document for Proposed Effluent Limitations Guidelines and Standards for the Metal Products and Machinery Industry


vvEPA
             United States
             Environmental Protection
             Agency	
            Office of Water
            (4303)
EPA 821-B-00-006
October 2000
Statistical Support Document
for Proposed Effluent
Limitations Guidelines and
Standards for the Metal
Products and Machinery
Industry

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Statistical Support Document for Proposed Effluent Limitations
               Guidelines and Standards for the
           Metal Products and Machinery Industry
                        Prepared for:

             U.S. Environmental Protection Agency
               Office of Science and Technology
               Engineering and Analysis Division
            1200 Pennsylvania Ave., NW (MC 4303)
                   Washington, DC 20460
                        Prepared by:

         Science Applications International Corporation
           Environmental and Health Sciences Group
      Health and Environment Studies and Systems Division
                   11251 Roger Bacon Drive
                      Reston, VA 20190
                        October 2000

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ACKNOWLEDGMENTS AND DISCLAIMER
       This report has been reviewed and approved for publication by the Engineering and Analysis
Division, Office of Science and Technology. This report was prepared with the support of Science
Applications International Corporation under the direction and review of the EPA's Office of Science
and Technology. Neither the United States Government nor any of its employees, contractors,
subcontractors, or their employees makes any warranty, expressed or implied, or assumes any legal
liability or responsibility for any third party's use of, or the results of such use of, any information,
apparatus, product, or process discussed in this report, or represents that its use by such third party would
not infringe on privately owned rights.

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ABSTRACT
       This document describes the statistical methodology used to develop effluent limitations for the
Metal Products and Machinery Industry. It also presents tables of the data used to develop limits.

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                                       Table of Contents

1. Overview of Organization and Contents of Document  	1-1

2. Analytical Data Collection Efforts and Definition of Options   	2-1
       2.1  EPA Wastewater Sampling  	2-1
       2.2  Definition of Subcategories and Technology Options	2-2
               2.2.1  Subcategorization Summary  	2-2
               2.2.2  Technology Options Selected  	2-3

3. Description of Data Conventions	3-1
       3.1  Data Review	3-1
       3.2  Data Types  	3-2
       3.3  Data Aggregation  	3-2
               3.3.1  Data Aggregation Across Multiple Grab Samples	3-2
               3.3.2  Aggregation of Field Duplicates	3-3

4. Statistical Methodology:  Modified Delta-Lognormal Model	4-1
       4.1  Basic Overview of Delta-Lognormal Distribution	4-1
       4.2  Motivations for Modifications to the Adapted Delta-Lognormal Model  	4-4
               4.2.1  Modification of the Discrete Spike	4-4

5. Estimation Under the Modified Delta-Lognormal Model  	5-1
       5.1  Facility-Specific Estimates	5-3
               5.1.1  Estimation of Facility-Specific LTAs  	5-4
               5.1.2  Estimation of Facility-Specific VFs  	5-4
                      5.1.2.1  Estimation of Facility-Specific 1-day VFs	5-4
                      5.1.2.2  Estimation of Facility-Specific 4-day VFs	5-5
       5.2  Pollutant-Specific Estimates	5-8
               5.2.1  Estimation of Pollutant-Specific  LTAs	5-8
               5.2.2  Estimation of Pollutant-Specific  VFs	5-9
                      5.2.2.1 Estimation of Pollutant-Specific 1-day VFs	5-9
                      5.2.2.2 Estimation of Pollutant-Specific 4-day VFs	5-9
       5.3 Transfers  	5-9

6. Derivation of the Proposed Limitations	6-1
       6.1  Steps Used to Derive Concentration-Based Limitations   	6-1
       6.2  Proposed Limitations	6-1
               6.2.1  Daily Concentration-based Limitations  	6-1
               6.2.2 Monthly Concentration-based Limitations	6-1
       6.3  Total Organics Parameter (TOP)	6-2
       6.4 Production-based Limits for Steel Forming and Finishing  	6-4

7. Glossary of Terms	7-1

List of Abbreviations and Acronyms
Table of Direct and Indirect Episodes

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Appendices

A.  Daily Effluent Data Listing	  A-l
B.  Effluent Data Summary Statistics  	  B-l
C.  Facility-level Long-term Averages and Variability Factors	  C-l
D.  Pollutant-level Long-term Averages, Variability Factors, and Limitations	  D-l
E.  Effluent Limitations	  E-l
F.  Production-based Limits for the Steel Forming and Finishing Subcategory	  F-l

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CHAPTER 1
OVERVIEW OF ORGANIZATION AND CONTENTS OF DOCUMENT

This document describes the statistical analyses of pollutant concentrations in effluent wastewater from
metal products and machinery facilities. EPA used these statistical analyses in developing the effluent
limitations guidelines and standards in the rulemaking for the Metal Products and Machinery Industry
(MP&M). Details of all statistical analyses conducted and data used in the analyses to support the
effluent limitations guidelines and standards for the MP&M are provided. This document is organized
into six chapters, a glossary of terms (chapter 7), and five appendices. The following list summarizes
the content of each chapter and appendix.

Chapter 1: Overview
— Describes the organization of the document and summarizes the contents of each chapter and
appendix.

Chapter 2: Analytical Data Collection Efforts and Definition of Options
— Provides an overview of the analytical data collection efforts and defines the technology options.

Chapter 3: Description of Data Conventions
— Presents data conventions and describes data aggregation and review procedures.

Chapter 4: Statistical Methodology
— Formulates the modified delta-lognormal distribution that EPA used to derive the proposed
limitations.

Chapter 5: Estimation under the Modified Delta-Lognormal Distribution
— Describes the estimation of long-term averages (LTAs) and variability factors (VFs) at the facility
and pollutant levels.

Chapter 6: Derivation of the Proposed Limitations
— Describes the derivation of the proposed limitations.

Chapter 7: Glossary of Terms
— Defines technical terms used in this document.

Appendix A: Daily Effluent Data Listing
— Provides a listing of effluent daily data by subcategory and option for regulated pollutants.

Appendix B: Effluent Data Summary Statistics
— Provides summary statistics by subcategory and option for the data from each facility used to
characterize the treatment in the regulated options.

Appendix C: Facility-Level Long-Term Averages and Variability Factors
— Summarizes facility-specific LTAs and VFs by subcategory and option.
1-1

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Appendix D: Pollutant-Level Long-Term Averages, Variability Factors, and Limitations
—  Presents pollutant-level LTAs, VF estimates, and concentration-based limitations by subcategory
    and option.

Appendix E: Effluent Limitations
—  Summarizes the daily and monthly limitations by treatment, subcategory, and pollutant.

Appendix F: Production-based Limits for the Steel Forming and Finishing Subcategory
—  Lists  the daily and monthly production-based limitations by pollutant and manufacturing process for
    the Steel Forming and Finishing subcategory.
                                             1-2

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                                       CHAPTER 2
      ANALYTICAL DATA COLLECTION EFFORTS AND DEFINITION OF OPTIONS
2.1 EPA Wastewater Sampling

Pollutant concentration data collected during EPA wastewater sampling efforts and facility supplied
data are the basis of estimates for this effluent guideline. Data from 54 sampling episodes were used to
derive pollutant-specific  concentration-based limitations for the following subcategories: General
Metals, Metal Finishing  Job Shops, Non-Chromium Anodizing, Printed Wiring Boards, Oily Wastes,
Railroad Line Maintenance, Shipbuilding Dry Docks, and Steel Forming and Finishing.

EPA collected influent and effluent data from wastewater treatment systems at MP&M facilities during
Phase I (1990-1993) and Phase II (1995-1999) data collection efforts.  EPA used these data to develop
limitations for all eight subcategories.  Table 2-1 provides  a summary of the number of episodes and
facilities used for limitation development by subcategory. Because EPA sampled a number of facilities
two or more times, the number of facilities differs from the number of episodes shown in  Table 2-1.

                                         Table 2-1.
         Number of Facilities and Sampling Episodes Used for Limitation Development
Subcategory
General Metals
Metal Finishing
Job Shops
Non-Chromium
Anodizing
Printed Wiring
Boards
Oily Wastes
Railroad Line
Maintenance
Shipbuilding Dry
Dock
Steel Forming and
Finishing
Number of Facilities
Phase I
13
2
0
0
1
0
0
13
Phase II
15
4
2
3
3
1
3
15
Overall
28
6
2
3
4
1
3
28
Number of Sampling Episode
Phase I
14
2
0
0
1
0
0
14
Phase II
15
8
2
3
4
1
3
15
Overall
29
10
2
3
5
1
3
29
                                            2-1

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2.2 Definition of Subcategories and Technology Options

This section defines the subcategories and technology options selected by EPA for this proposed rule.
EPA has divided the MP&M point source category into eight subcategories: General Metals, Non-
chromium Anodizing, Metal Finishing Job Shops, Printed Wiring Boards, Steel Forming and
Finishing, Oily Wastes, Railroad Line Maintenance, and Shipbuilding Dry Dock.

Sections 2.2.1 and 2.2.2 below describe the subcategories and technology options.

2.2.1 Subcategorization Summary

General Metals
MP&M facilities that discharge metal-bearing wastewater (with or without oil-bearing wastewater) that
do not belong to the Printed Wiring Board, Non-Chromium Anodizing, Metal Finishing Job Shops, or
Steel Forming and Finishing subcategories. General Metals facilities usually perform manufacturing or
heavy rebuilding of metal products, parts, or machines.

Non-Chromium Anodizing
Facilities that perform aluminum anodizing without the use of chromic acid or dichromate sealants in
their operations.

Metal Finishing Job Shops
Job shops that perform one or more of the following: electroplating, electroless plating, anodizing,
coating (chromating, phosphating, passivation, and coloring), chemical etching and milling, and
printed circuit board manufacture. A job shop is defined as "a facility which owns not more than 50
percent (on an annual area basis) of the materials undergoing metal finishing" (40 CFR 433).

Printed Wiring Board
MP&M wastewater discharges from the manufacture, maintenance, and repair of printed wiring
boards.

Steel Forming and Finishing
Facilities that perform MP&M operations or cold forming operations on steel wire, rod, bar, pipe, or
tube. Limits for the Steel Forming and Finishing subcategory were generated using data from the
General Metals subcategory because data were unavailable for the Steel Forming and Finishing
subcategory.

Oily Wastes
MP&M facilities that discharge only oil-bearing wastewater and do not belong to any other MP&M
subcategories.

Railroad Line Maintenance
Facilities that perform routine cleaning and light maintenance on railroad engines, cars, and car-wheel
trucks and similar parts or machines. These facilities only perform MP&M unit operations defined as
oily only and/or washing of final product.
2-2

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Shipbuilding Dry Dock
Process wastewater generated in or on dry docks and similar structures such as building ways, graving
docks, marine railways, and lift barges at shipbuilding facilities (or shipyards).

2.2.2 Technology  Options Selected

In developing its technology options, EPA determined that a different set of wastewater treatment
technologies was appropriate for facilities that performed unit operations that produced primarily
metal-bearing wastewater than for those facilities that performed unit operations that produced
primarily oily wastes. EPA concluded that the following subcategories typically produce metal-bearing
wastewater (with or without associated oily-bearing wastestreams)  and evaluated metals control
technologies for these subcategories:  General Metals, Metal Finishing Job Shops,  Non-Chromium
Anodizing, Printed Wiring Boards, and Steel Forming and Finishing.  For the remaining  subcategories
(Oily Wastes, Railroad Line Maintenance, and Shipbuilding Dry Dock), EPA evaluated oily
wastewater treatment technologies. EPA fully describes all of the  technology options considered for
each subcategory in Section 9 of the MP&M Technical Development Document.

Table 2-2 displays the selected technology options by  subcategory and according  to whether the option
applies to existing  sources or to new sources.

                                           Table 2-2
                          Selected  Technology Options by Subcategory
Subcategory
General Metals
Metal Finishing Job Shops
Non-Chromium Anodizing
Printed Wiring Boards
Steel Forming and Finishing
Oily Wastes
Railroad Line Maintenance
Shipbuilding Dry Dock
Selected Option for Existing
Sources
Option 2
Option 2
Option 2
Option 2
Option 2
Option 6
Option 10
Option 10
Selected Option for New
Sources
Option 4
Option 4
Option 2
Option 4
Option 4
Option 6
Option 10
Option 10
The following provides a brief description of the technologies included in each of the selected options.

Option 2
In-process flow control and pollution prevention, segregation of wastewater streams, preliminary
treatment steps as necessary (including oils removal using oil-water separation by chemical emulsion
breaking), chemical precipitation using lime or sodium hydroxide, and sedimentation using a clarifier.
                                              2-3

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Option 4
In-process flow control and pollution prevention, segregation of wastewater streams, preliminary
treatment steps as necessary (including oils removal by ultrafiltration), chemical precipitation using
lime or sodium hydroxide, and solids separation using a microfilter.

Option 6
In-process Flow Control, Pollution Prevention, and Oil-water separation by chemical emulsion
breaking.

 Option 10
In-process Flow Control, Pollution Prevention, and Oil-water separation by Dissolved Air Flotation.
All of the selected options described above include the following in-process pollution prevention and
water conservation technologies:

•      Flow reduction using flow restrictors, conductivity meters, and/or timed rinses, for all flowing
       rinses,  plus countercurrent cascade rinsing for all flowing rinses;
•      Centrifugation and 100 percent recycling of painting water curtains; and
•      Centrifugation and pasteurization to extend the life of water-soluble machining coolants
       reducing  discharge volume by 80 percent.
                                                2-4

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                                         CHAPTER 3
                          DESCRIPTION OF DATA CONVENTIONS
This chapter discusses the types of data in the MP&M analytical database and the hierarchy and
procedures for aggregating multiple sampling observations within a sampling day.

3.1 Data Review

EPA's Sample Control Center (SCC) thoroughly reviewed and validated the EPA wastewater sampling
data in the analytical database.  During this review, the integrity of each sample was assessed to ensure
that all specifications of the sampling protocol were met.  In addition, engineers reviewed the data and
determined that some samples should be excluded from the analyses.  Samples with flags of T', which
indicate one of the following conditions, were excluded from analyses.

•      data for a treatment unit that is not a technology option
•      data for a treatment system that was not operated at a proper pH for removal of targeted metals
•      data for a treatment system with poor solid removal
•      data for a treatment system that did not remove most of the pollutants targeted by the treatment
       system for removal and processed on site
•      data associated with a process upset or improper sampling techniques that may impact treatment
       effectiveness or data quality
•      data associated with specific analytes not detected in all raw wastewater influent samples to a
       treatment system
•      data associated with specific analytes not detected in most raw wastewater influent samples to a
       treatment system and when detected, detected at low concentrations
•      data associated with specific analytes with average raw influent concentration less than or equal
       to 10 times the minimum level of detection
•      data associated with specific metal analytes that were not processed at the site
•      data associated with specific analytes that may not have been present in a treatment system due
       to dilution from poor water use practices
•      data associated with a treatment chemical associated with the treatment system when the
       chemical was not removed by the system comparably to other targeted pollutants
•      data associated with specific analytes detected in the raw influent to a treatment system at low
       concentrations when compared to other MP&M sites or other metals processed on-site
•      data for a treatment system when the concentrations of all targeted pollutants in the raw influent
       are low

Also during the data review, some samples were qualified with a greater than (>) sign, indicating that
the reported concentration value is considered a lower limit of the actual value.  This is because the
reported concentration was outside the range of the analytical method.  Some samples were labeled
with a 'B' flag, indicating a pollutant was  detected at below the minimum level of detection (sensor
point). In both cases,  the reported concentration values rather than the censored values were used for
all computations.
                                              3-1

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3.2 Data Types

The MP&M analytical database, developed from the data reviewed and validated by SCC, contains the
following three different types of samples delineated by certain qualifiers in the database:

Non-censored (NC): a measured value, i.e., a sample measured above the level at
which the detection decision was made.

Non-detect (ND): samples for which analytical measurement did not yield a
concentration above the sample-specific detection limit.

Right-censored (RC): these samples were qualified with a greater than (>) sign,
signifying that the reported value is considered a lower limit of the actual
concentration.

3.3 Data Aggregation

Aggregation of MP&M analytical data occurred at two levels. The first level aggregated pollutant
concentration data from multiple grab samples collected from a given sampling point over a specified
period of time. Multiple grab samples were collected when physical compositing of the samples was
impractical. The second level aggregated data from field duplicate samples. This section identifies the
levels of aggregation and the methods applied to data at each level. Conventions for handling censored
and non-censored data during the aggregation process are also provided.

3.3.1 Data Aggregation Across Multiple Grab Samples

Multiple grab samples are samples collected from a given sampling point over time. These samples are
assigned different sample numbers. Multiple grab samples were collected when the concentration of
pollutants was expected to vary during the course of sampling or when samples could not be physically
composited. Within the MP&M database, Hexane Extractable Material (HEM) and Silica Gel Treated-
Hexane Extractable Material (SGT-HEM) were reported as concentrations from multiple grab samples
taken during one-day sampling periods. Sampling procedures require HEM and SGT-HEM to be
collected as grab samples. If composited, most of the measurable amount of these analytes would
remain on the composite jar due to their oily nature. Since LTAs and limitations were based on daily
concentrations, multiple observations on a single day at the same sample point were averaged.
Averaging analyte concentrations from multiple grab samples mathematically composites the data from
the samples. The following table shows how multiple grab samples were aggregated within each
sampling day/sample point combination.
3-2

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                                          Table 3-1.
                         Method for Averaging Multiple Grab Samples
If Observations are:
A11NC
A11ND
NC and ND
Label of "Average"
NC
ND
NC
Value of "Average"
• NC/n
Maximum Detection Limit
(• NC, + • DL,)/n
       n =  number of grab samples per day
       DL = sample detection limit
       NC = detected sample

3.3.2 Aggregation of Field Duplicates

Another type of data aggregation for the MP&M data was performed when flags in the database
identified field duplicate samples.  Field duplicates are samples collected for a particular sampling point
at approximately the same time, assigned different sample numbers, and flagged as duplicates for a
single episode number/sampling point.  Duplicates were collected for purposes of quality
assurance/quality control. Table 3-2 presents the methods used to aggregate duplicates.

                                          Table 3-2.
                        Method for Averaging Field Duplicate Samples
If Observations are:
Both NC
Both ND
NC and ND
Label of "Average"
NC
ND
NC
Value of "Average"
• NC/2
Maximum Detection Limit
(NC + ND)/2
  NC = detected sample
  ND = sample detection limit

If multiple grab and field duplicate samples were collected from the same sampling point, the
concentration data from field duplicate samples were averaged first, then the data from the resulting
duplicate sample averages were averaged as a composite sample.
Listings of summary statistics following aggregation of grabs and field duplicates are presented
Appendix B.
in
                                             3-3

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CHAPTER 4
STATISTICAL METHODOLOGY: MODIFIED DELTA-LOGNORMAL MODEL
4.1 Basic Overview of Delta-Lognormal Distribution

The lognormal distribution is often appropriate for modeling effluent data. However, the presence of
NDs and very low concentration measurements in the MP&M effluent data led to the consideration of a
modification to the lognormal distribution in modeling such data for several reasons. First, the
lognormal model assumes that all concentration values are positively-valued. Second, the actual values
of NDs are not known, though each ND has a concentration somewhere between zero and the reported
detection limit. In this sense, ND measurements represent, in statistical terms, what are known as
censored samples.

In general, censored samples are measurements for which the exact value is not known but is bounded
either by an upper or lower numerical limit. Non-detects qualify in this framework as left-censored
samples, which have an upper bound at the detection limit and a lower bound at zero. To model NDs
as left-censored samples under a strictly lognormal density model, it is necessary to assume that the
exact (but unknown) values of these measurements follow the same lognormal distributional pattern as
the rest of the detected measurements and that they are positively-valued (i.e., greater than zero).

Therefore, two reasonably simple modifications to the lognormal density model have been used by
EPA for several years. The first modification is known as the classical delta-lognormal model (Figure
4-1), first used in economic analysis to model income and revenue patterns (see Aitchison and
Brown1). In this adaptation of the simple lognormal density, the model is expanded to include zero
amounts. To do this, all positive amounts are grouped together and fit to a lognormal density. Then
all zero amounts are segregated into another group of measurements representing a discrete
distributional "spike" at zero. The resulting mixed distribution, combining a continuous density
portion with a discrete-valued spike, is known as the delta-lognormal distribution. The delta in the
name refers to the percentage of the overall distribution contained in the spike at zero, that is, the
percentage of zero amounts.
. Aitchison, J. and Brown, J.A.C. (1963) The Lognormal Distribution. Cambridge University Press, pages 87-99.

4-1

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Figure 4-1.
Delta-lognormal Model
NorvDeteds
Detects
Researchers at EPA (see Kahn and Rubin, 1989) further adapted the classical delta-lognormal model
("adapted model") to account for ND measurements in the same fashion that zero measurements were
handled in the original delta-lognormal. Instead of zero amounts and non-zero, positive amounts, the
data consisted of NDs and detects. Rather than assuming that NDs represented a spike of zero
concentrations, these samples were allowed to have a single positive value, usually equal to the
minimum level of the analytical method (Figure 4-2). Since each ND was assigned the same positive
value, the distributional spike in this adapted model was located not at zero, but at the minimum level.
This adaptation is appropriate since it is known that the NDs are some value greater than zero. This
adapted model was used in developing limitations for the Organic Chemicals, Plastics, and Synthetic
Fibers (OCPSF), Pesticides Manufacturing and Centralized Wasted Treatment rulemakings.

Figure 4-2.
Adapted Delta-lognormal Model
Detects
NorvDeteds
0 5101520
In the adapted delta-lognormal model, the delta again referred to those measurements contained in the
discrete spike, this time representing the proportion of ND values observed within the data set. By
using this approach, computation of estimates for the population mean and variance could be done
4-2

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easily by hand, and NDs were not assumed to follow the same distributional pattern as the detected
measurements. The adapted delta-lognormal model can be expressed mathematically as follows:
                  Pr (U [(log(w) - \i)/o]       if  0 < u < D
 6 + (1-6) O frlogCD) -  jiyol    if   u = D
 &  .  f 1  & \ ft\ T/i ^ _/'. A    .. \ /«. T    _'.r   _. *^ r\
                                6  + (1-6) 0> l(log(w) -  |iyo]    if  u > D
(4.1)
where • represents the true proportion of NDs (or the probability that any randomly drawn
measurement will be an ND) , D equals the minimum level value of the discrete spike assigned to all
NDs, •  (•) represents the standard normal cumulative distribution function, and • and • are the
parameters of the lognormal density portion of the model.  This model assumes that all non-detected
values have a single detection limit D.

It is also possible to represent the adapted delta-lognormal model in another mathematical form, one in
which it is particularly easy to derive formulas for the expected value and variance of the model.  In
this case, a random variable distributed according to the adapted delta-lognormal distribution can be
represented as the stochastic combination of three other independent random variables. The first of
these variables is an indicator variable, Iu, equal to one when the measurement u is an ND and equal to
zero when u is a detected value. The second variable, XD, represents the value of an ND measurement
(discrete). In the adapted delta-lognormal, this variable is always a constant equal to the concentration
value assigned to each ND (i.e., equal to D in the adapted delta-lognormal model).  In general,
however, XD need not be a constant, as will be seen below in the modified delta-lognormal model.
The final random variable, Xc, represents the value of a detected measurement and is distributed
according to a lognormal distribution (continuous) with parameters •  and • .

Using this formulation, a random variable from the adapted delta-lognormal model can be written as

                                                                                               (4.2)
and the expected value of U is then derived by substituting the expected value of each quantity in the
right-hand side of the equation.  Because the variables Iu, XD, and Xc are mutually independent, this
leads to the expression

                   E(U) =  dE(XD)+(\-^)E(Xc) = 6D + (l-6)exp(n + 0.5 o2)                   (4.3)

where again •  is the probability that any random measurement will be ND  and the exponentiated
expression is the familiar mean of a lognormal distribution. In a similar fashion, the variance of the
adapted delta-lognormal model can be established by squaring the expression for U above, taking
expectations, and subtracting the square of E(U) to get

  Var(U) = E(U2) - [E(U)}2 =  ?>Var(XD) + (\-?>)Var(Xc) +  6(l-6)[E(XD)-E(Xc)]2.              (4.4)

Since, in the adapted delta-lognormal formulation, XD is a constant, this  expression can be reduced to
the following:

    Var(U)  =  (1 - 6)exp(2n +o2)[exp(o2) - (1 - 6)]  + 6(1 -6)D[D - 2exp(n + 0.5o2)].                (4.5)

                                              4-3

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In order to estimate the adapted delta-lognormal mean and variance from a set of observed sample
measurements, it is necessary to derive sample estimates for the parameters • , • , and • .  •  is
typically estimated by the observed proportion of NDs in the data set.  •  and • are estimated using the
log values of the detected samples where •  is estimated using the arithmetic mean of the log-detected
measurements, and • is estimated using the standard deviation of these same log values; NDs are not
included in the calculations.  Once the parameter estimates are obtained, they are used in the formulas
above to derive the estimated adapted delta-lognormal mean and variance.

To calculate effluent limitations and/or standards,  it is also necessary to estimate upper percentiles
from the underlying data model.  Using the delta-lognormal formulation above in equation (4.1), letting
U. represent the 100*» * percentile of random variable U, and adopting the standard notation of zs for
the s* percentile of the standard normal distribution, an arbitrary delta-lognormal percentile can be
expressed  as the following:


                  U. =
                    a
                          expGi+o za/1_6)   if    (l
                                D          if   6+(l-6)((logCD)-n)/o) >cc                  (4.6)
                         exp(n+o za_6/1_6)  if   6+(l-6)((log(Z>)-n)/o) 
-------
ND samples have varying detection limits, the spike of the delta-lognormal model has been replaced by
a discrete distribution made up of multiple spikes.  Each spike in this modification is associated with a
distinct detection limit observed in the MP&M database. Thus,  instead of assigning all NDs to a
single, fixed value, as in the adapted model, NDs can be associated with multiple values depending on
how the detection limits vary (Figure 4-3).

                                           Figure 4-3.
                            Modified Adapted Delta-lognormal Model
                                                 Detects
         0 5101520
In particular, because the detection limit associated with an ND sample is considered to be an upper
bound on the true value, which could range conceivably from zero up to  the detection limit, the
modified delta-lognormal model used here assigns each ND sample to its reported detection limit.

Once each ND has been associated with its reported detection limit, the discrete  "delta" portion of the
modified model is estimated in a way similar to the adapted delta-lognormal distribution,  only now
multiple spikes are constructed and linked to the distinct detection limits observed in the data set.  In
the adapted model, the parameter  •  is estimated by computing the proportion of NDs.  In the modified
model, • again represents the proportion of NDs, but is divided into the  sum of  smaller fractions, • (,
each representing the proportion of NDs associated with a particular and  distinct detection limit.  Thus
it can be written  as
                                                                                                (4.7)
If Dj equals the value of the 1th smallest distinct detection limit in the data set, and let the random
variable X represent a randomly chosen ND sample, then the discrete distribution portion of the
modified delta-lognormal model can be mathematically expressed as
                                       Pr(XD
-------
                                                                                                    (4.9)
It is important to recognize that, while replacing the single discrete spike in the adapted delta-
lognormal distribution with a more general discrete distribution of multiple spikes increases the
complexity of the model, the discrete portion with multiple spikes plays a role in limitations and
standards development identically parallel to the single spike case and offers flexibility for handling
multiple observed detection limits.
                                                4-6
-------
                                        CHAPTER 5
          ESTIMATION UNDER THE MODIFIED DELTA-LOGNORMAL MODEL
Once the modifications to the adapted delta-lognormal distribution are made, it is possible to fit a wide
variety of observed effluent data sets to the modified model.  Multiple detection limits for non-
detects(NDs) can be handled. The same basic framework can be used even if there are no ND values
or censored data.

Combining the discrete portion of the model with the continuous portion, the cumulative probability
distribution of the modified delta-lognormal model can be expressed as follows, where Dk denotes the
largest distinct detection limit observed among the NDs and the first summation is taken over all those
values, Dj, that are less than u.
                   Pr(UD,
                                                                                            (5.1)
Again combining the discrete and continuous portions of the modified model, the expected value of the
random variable U can be derived as a weighted sum of the expected values of the discrete and
continuous lognormal portions of the distribution. This follows because the modified delta-lognormal
random variable U can be expressed again as a combination of three other independent variables, that
is,
                                                                                            (5.2)
where this time XD represents a random ND from the discrete portion of the model, Xc represents a
random detected measurement from the continuous lognormal portion, and Iu is an indicator variable
signaling whether  any particular random measurement is detected or not.  Then the expected value and
variance of U have forms somewhat similar to the adapted delta-lognormal model, namely

                                        D  +  (l-6)exp([i+0.5o2)
                                                                                            (5.3)
                 Var(U)  =
	 	 	 -r ^1 U^CAp^p, -r U AGAp^J )
6

+ 6(1-6)
"£6£> 1
' exnCu + 0 Sn2^
6
2

                                                                                            (5.4)
where
    D(
                j      = detection limit for the 1th ND value
                 detection limit for the jfcND value, where i < j
                 proportion of NDs with detection limit = D(
                                             5-1
-------
               = proportion of NDs with detection limit = Dj
               = proportion of all NDs
               = mean log concentrations of non-censored (NC) values
               = standard deviation of log NC values.
Example:

Consider a facility that has 10 samples with the following concentrations:
Sample
number
1
2
3
4
5
6
7
8
9
10
Measurement
Type
ND
ND
ND
ND
NC
NC
NC
NC
NC
NC
Concentration (mg/L)
10
15
15
20
25
25
30
35
35
40
Then the mean and variance of the log NC values are calculated as follows:
                                     V- =
                                          1=1
                          (2*ln(25)  + ln(30)  +  2*ln(35) + ln(40))
                                             6
3.44
                                              5-2
-------
-  (2*(ln(25)-3.44)2) + (ln(30)-3.44)2  + 2*(ln(35)-3.44)2)  +(ln(40)-3.44)2)
J
                                                                                   .0376.
The ND components of the variance equation are:

Dj =  10, % =  1/10
D2 =  15, -2 =  1/5
D3 =  20, -3 =  1/10.

As such, the variance for this example is:
Var(x)


(exp(.

1 ^
10*



0376)-!

1(10- 15)2 + — *— (10-20)2 +
5 10 10
2
5

)+ 2L_2\


( 1 *ioV
I 10 J




-[1*15^
15 ;
2
5
!*_L(15-20)2 , .
5 10 + I-2 lexDPta
\ ^/
44 +.0376)

+ (-*2°) 1
^ ' pynH -1-1 +0 St 0^76^


2
QS R


5.1 Facility-Specific Estimates

For the purposes of estimating facility-specific LTAs and VFs, EPA chose to divide the MP&M data
sets into two groups based on their size (number of samples) and the type of samples in the subset,
because the computations differ for each group. The groups were defined as follows:

    Group 1:  Less than 2 NC (detectable) samples or less than 4 total samples. Specifically, Group 1
              contained all data subsets with all NDs or only one detect. Sample-specific detection
              limits were substituted as the values associated with non-detectable samples.

    Group 2:  Two or more NC (detectable) samples and  4 or more total samples. Sample-specific
              detection limits were substituted as the values  associated with non-detectable samples.

A listing of the daily data can be found in Appendix A.
                                              5-3
-------
5.1.1 Estimation of Facility-Specific LTAs
Data from both Group 1 and 2 were included for the computation of LTAs.  The LTAs were calculated
as the arithmetic average of the samples. Appendix B lists the summary statistics by subcategory,
analyte, and option.

5.1.2 Estimation of Facility-Specific VFs

EPA developed 1-day and 4-day VFs  for all regulated pollutants using Group 2 data only.  Group 1
data were insufficient for estimating variability.  Upper percentiles and VFs for Group 1 could not be
computed using the modified delta-lognormal methodology.

For Group 2, the estimates of the parameters for the lognormal portion of the data were calculated
using maximum likelihood estimation in the  log-domain.  Upper percentiles and VFs were calculated
using these estimated parameters.  Calculation of these VFs is described in Section 5.1.2.1 and
5.1.2.2.

5.1.2.1  Estimation of Facility-Specific 1-day VFs

The 1-day VFs are a function of the LTA and the 99th percentile.  The 99th percentile of each data
subset was calculated using the modified delta-lognormal methodology by first defining D0 = 0, • 0 = 0,
and Dk+1 =  •  as boundary conditions, where D( equals the 1th smallest detection limit, and • (is the
associated proportion of NDs at the 1th detection limit.  A cumulative distribution function, p, for  each
data subset was computed as a step function ranging from 0 to 1. The general form for p, for a given
value c, is
p  =
                    i=0
                                     log(c) - (1
                                                                                          (5.5)
where •  is the standard normal cumulative distribution function. The following steps were completed
to compute the estimated 99th percentile of each data subset:

  1.  k values of p at c = Dm, m = 1,.. .k were computed and labeled pm.

  2.  The smallest value of m, such that pm • 0.99, was determined and labeled as pj.  If no such m
     existed, steps 3 and 4 were skipped and step 5 was computed instead.

  3-  P* = Pj - *j was computed.

  4.  Ifp*  < 0.99, thenP99 = D,,
     else if p* • 0.99, then
                          0.99 -
                            (1-6)
                                       6
                                                                                           (5.6)
                                              5-4
-------
  5.   If no such m exists, such that pm • 0.99 (m = l,...k), then
         P99 = exp
                         ,-1
                            0.99 - 6
                             (1-6)

The daily VF, VF1, was then calculated as
 (5.7)
                                        VF1 =
                                                  99
                                                E(U)
(5.8)
where
                                          (l-6)exp(|l+0.562).
5.1.2.2 Estimation of Facility-Specific 4-day VFs

Since Since EPA is assuming for costing purposes that some of the pollutants will be monitored weekly
(approximately four times a month) , EPA calculated a VF for monthly averages based on the
distribution of 4-day averages. In order to calculate the 4-day VF, the assumption was made that the
approximating distribution of • 4, the sample mean for a random sample of four independent
concentration values, also is derived from this modified delta-lognormal distribution, with the same
mean as the distribution of the concentration values. The mean of this distribution of 4-day averages is
                                                                                               (5.9)
where E(X4)D denotes the mean of the discrete portion of the distribution of the average of four
independent concentration values (i.e., when all observations are not detected), and E(X4)C denotes the
mean of the continuous lognormal portion of the distribution.

First, it is assumed that the probability of detection (• ) on each of the four days is independent of that
on the other days, and the non-detected values are therefore not correlated; consequently, • 4 = • 4.
Also, because

                                        E(X4)D  =  E(XD)
then
                                                                                               (5.10)
                                     r=l
and since £(• 4)  = E(U), then
                                              5-5
-------
                                       E(U)-,
                                           (1-54)
                                                        -0.5o2
The expression for • 24 was derived from the following relationship:

            Var(U4)  = b,Var((X4)D)  + (1 - 64)FaK(^4)c) + 64(1-
Because
                                 Var(Xn)
                                                  = E(XD),   and
then
             Var(U4) = 64
                          Var(XD)
This further simplifies to
|4/i »4\
U ° )
462
v^ 6A
[^5 ~6J
— T V1 u /c
q>(H4 + 0.5o24)
                                                                + o24) [exp(o24)
and furthermore,
                                               - 62(1 - 84)
exp(o24) -
Then, from (5.10) above,

                 (E(C/4)-63E
exp(p,4 + 0.5o24) = -
                                                          /=!
                                                                                             (5.11)
                                                                                             (5.12)
                                                                                             (5.13)
                                                                                             (5.14)
                                                                                             (5.15)
                                                                                        (5.16)
                                             - 63E
                       (1-64)
                                            (1-64)
                                                                                             (5.17)
and letting
                                             5-6
-------
                                                      2   =
                                             then,  exp(n4 + 0.5o24) =
                                                                      (1-64)
                                                                                       (5.18)
Furthermore,

1 +


Var(U\ ' ! t fi /) ^
4 [,=1 (1-64)J
(1-54)T12
(1-64)2
                                                                                                (5.19)
Since Var(»
  o24  = log
       Var(U)/4, then, by rearranging terms,


                          (1-64)62E  EWA-^y)
                                                                        1=1
                       4T1
                                       4if
                                                                                           (5.20)
Thus, estimates of • 4 and • 4 were derived by using estimates of • 1;...*k (sample proportion of NDs at
observed detection limits D1;...Dk), •  (MLE of logged values), and • 2 (MLE logvariance multiplied
     n
by
    n-l
to reflect estimation from sample) in the equations above.
In finding the estimated 95th percentile of the average of four observations, four NDs, not all at the
same detection limit, an average can be generated that is not necessarily equal to D1; D2	or Dk.
Consequently, more than k discrete points exist in the distribution of the 4-day averages.  For example,
the average of four  NDs at k = 2 detection limits are at the following discrete points with the associated
probabilities:
                       1
                       2
                       3
                       4
                       5
                                          j +3^)74
66 ^
4°l023
In general, when all four observations are not detected, and when k detection limits exist, the
multinomial distribution can be used to determine associated probabilities; that is,
                                               5-7
-------
                              Pr
                                      r=l
                                                      4!
                       -H6"'.
                                                           (5.21)
where u( is the number of non-detected measurement in the data set with the D( detection limit.
The number of possible discrete points, k*, for k= 1,2,3,4, and 5 are given below:
                             k
                             1
                             2
                             3
                             4
                             5
k
1
5
15
35
70
To find the estimated 95th percentile of the distribution of the average of four observations, the same
basic steps (described in Section 5.1.2.1) as used for the 99th percentile of the distribution of daily
observations were followed, with the following changes:

  1.   Change P99 to P95, and 0.99 to 0.95.
  2.   Change Dm to Dm*, the weighted averages of the detection limits.
  3.   Change »j to »j*.
  4.   Change k to k*,  the number of possible discrete points based on k detection limits.
  5.   Change the estimates of • , •  , and • to estimates of •4, • 4, and • 4, respectively.

Then, the estimate of the 95th percentile 4-day mean VF is:
                               VF4
                                        95
                                      E(U)
                       E(U).
Appendix C displays facility-level LTAs,  1-day VFs, and 4-day VFs by subcategory, analyte, and
option.
5.2 Pollutant Specific Estimates

5.2.1  Estimation of Pollutant-Specific LTAs

After  estimating the facility-specific LTAs for each pollutant and option by subcategory, as described
in section 5.1.1, pollutant-specific LTAs were calculated.  Pollutant-specific LTAs provide one number
for all facilities within a subcategory and option. Within each subcategory and option combination, the
pollutant-specific LTAs were calculated as the median of the facility-specific LTAs for that pollutant.
The median is the midpoint of the values ordered (i.e., ranked) from smallest to  largest.  If there is an
                                               5-8
-------
odd number of values (with n = number of values),  then the value of the (n+ l)/2 ordered observation is
the median. If there is an even number of values, then the two values of the n/2 and [(n/2) + 1] ordered
observations are arithmetically averaged to obtain the median value.

5.2.2 Estimation of Pollutant-Specific VFs

Pollutant-specific VFs, the ratio of the 99th percentile to the mean, provide estimates of the average
variability across facilities.

5.2.2.1  Estimation of Pollutant-Specific  1-day VFs

Facility-specific VFs were estimated for each pollutant by technology option and subcategory, as
described in section  5.1.2.1.  A pollutant-specific 1-day VF was the mean of the facility-specific  daily
VFs  for that pollutant in the subcategory and option combination.

5.2.2.2  Estimation of Pollutant-Specific 4-day VFs

Facility-specific 4-day VFs were estimated for each pollutant by technology option and subcategory, as
described in section  5.1.2.2.  A pollutant-specific 4-day VF was the mean of the facility-specific  4-day
VFs  for that pollutant in the subcategory and option combination. The pollutant-specific 4-day VFs
were used to calculate 4-day limitations, as discussed in Chapter 6.

Appendix D displays pollutant-specific LTAs, 1-day VFs, and 4-day VFs by subcategory, analyte, and
option.

5.3  Transfers

A transfer occurs when all data from the original subcategory are combined with all data from the
specified transfer subcategory or when there are no data from the original subcategory so it is
necessary to use, or  transfer,  data from another subcategory.  Limits are then calculated using these
combined data.  In most cases, EPA applies transfers when there are insufficient data in a particular
subcategory for the calculation of an LTA or VF.  However,  in certain cases, EPA applies data
transfers even when  sufficient data are available to calculate the limit for the specific pollutant within
the original subcategory.  Table  5-1 lists the transfers applied to the MP&M data by subcategory,
analyte, and option.

                                           Table 5-1.
                                           Transfers
Target
Subcat
AND
Target Chemical
MANGANESE
NICKEL
OIL AND GREASE (AS HEM)
Option
2
2
2
Data Used for Limits
LTA VF
GENL
GENL
GENL
GENL
GENL
GENL
                                               5-9
-------
Target
Subcat

GENL
MFJ
Target Chemical
ZINC
AMENABLE CYANIDE
CYANIDE
LEAD
MOLYBDENUM
OIL AND GREASE (AS HEM)
TIN
TOTAL SULFIDE
TOTAL ORGANIC CARBON
(TOC)
TOP
AMENABLE CYANIDE
CADMIUM
CHROMIUM
COPPER
CYANIDE
LEAD
MANGANESE
MOLYBDENUM
NICKEL
Option
2


4
4
4
2
4
2
4
4
2
4

4
4
4

4
4
2
4
4
Data Used for Limits
LTA VF
GENL
GENL, MFJ
GENL,MFJ,DRYD
PWB (option 4)
GENL (option 2)
GENL (option 2)
GENL
GENL
OILY
OILY
GENL (option 2)
DRYD, GENL, MFJ,
OILY, PWB, RRL
DRYD, GENL, MFJ,
OILY, PWB, RRL
(option 2)
GENL, MFJ
GENL
GENL
GENL
GENL,MFJ,DRYD
PWB (option 4)
GENL
GENL
GENL (option 2)
GENL
GENL
GENL, MFJ
GENL, MFJ, DRYD
PWB (option 4)
GENL (option 2)
GENL (option 2)
GENL
GENL, PWB
OILY
OILY
GENL (option 2)
DRYD, GENL, MFJ,
OILY, PWB, RRL
DRYD, GENL, MFJ,
OILY, PWB, RRL
(option 2)
GENL, MFJ
GENL
GENL
GENL
GENL, MFJ, DRYD
PWB (option 4)
GENL
GENL
GENL (option 2)
GENL
5-10
-------
Target
Subcat

OILY
PWB
Target Chemical
OIL AND GREASE (AS HEM)
SILVER
TIN
TOTAL ORGANIC CARBON
(TOC)
TOTAL SULFIDE
TOTAL SUSPENDED SOLIDS
TOP
ZINC
TOP
AMENABLE CYANIDE
CHROMIUM
COPPER
CYANIDE
LEAD
OIL AND GREASE (AS HEM)
MANGANESE
Option
2
4
4
4
4
2
4
4
2
4
4
6

2
4
2
4

2
4
2
4
4
Data Used for Limits
LTA VF
GENL
GENL (option 2)
GENL
GENL
MFJ (option 2)
OILY
OILY
GENL
DRYD, GENL, MFJ,
OILY, PWB, RRL
DRYD, GENL, MFJ,
OILY, PWB, RRL
(option 2)
GENL
DRYD, GENL, MFJ,
OILY, PWB, RRL
GENL, MFJ
GENL
GENL
GENL
PWB
GENL,MFJ,DRYD
GENL
PWB
GENL
GENL (option 2)
GENL (option 4)
GENL
GENL (option 2)
GENL
GENL, PWB
MFJ (option 2)
OILY
OILY
GENL
DRYD, GENL, MFJ,
OILY, PWB, RRL
DRYD, GENL, MFJ,
OILY, PWB, RRL
(option 2)
GENL
DRYD, GENL, MFJ,
OILY, PWB, RRL
GENL, MFJ
GENL
GENL
GENL
PWB (Tin)
GENL,MFJ,DRYD
GENL
PWB (Tin)
GENL
GENL (option 2)
GENL (option 4)
5-11
-------
Target
Subcat

RRL
Target Chemical
NICKEL
TOTAL ORGANIC CARBON
(TOC)
TOTAL SULFIDE
TOTAL SUSPENDED SOLIDS
TOP
ZINC
BOD 5-DAY (CARBONACEOUS)
OIL AND GREASE (AS HEM)
TOTAL SUSPENDED SOLIDS
Option
4
4
2
4
2
4
2
4
2
4
10
10
10
Data Used for Limits
LTA VF
GENL (option 4)
PWB (option 2)
OILY
OILY
GENL
GENL
DRYD,GENL,MFJ,
OILY, PWB, RRL
DRYD,GENL,MFJ,
OILY, PWB, RRL
(option 2)
GENL
GENL
RRL
RRL
RRL
GENL (option 4)
PWB (option 2)
OILY
OILY
GENL
GENL
DRYD,GENL,MFJ,
OILY, PWB, RRL
DRYD,GENL,MFJ,
OILY, PWB, RRL
(option 2)
GENL
GENL
DRYD, RRL
DRYD, RRL
DRYD, RRL
5-12
-------
                                         CHAPTER 6
                     DERIVATION OF THE PROPOSED LIMITATIONS

This chapter describes the derivation of the proposed daily and monthly limitations.  Limits were
calculated as the product of a model long-term average and a model variability factor (VF).  This
chapter describes the methods used to derive the proposed daily and monthly concentration-based
limitations.

6.1 Steps Used to Derive Concentration-Based Limitations

The derivation of the concentration-based daily and monthly maximum limitations used the pollutant-
specific LTAs and respective VFs.

The following steps were used to derive the concentration-based limitations.  Appendix E provides, by
option and subcategory, listings of the concentration-based pollutant-level limitations with the LTAs
and VFs used to derive the proposed limitations.

Step 1:   The facility-specific LTAs and 1-day and 4-day VFs were calculated for all facilities.
         Calculation of VFs was performed when the facility had four or more observations with two
         or more distinct detected values.

Step 2:   For each option in the subcategory, the median of the facility-specific LTAs and the mean of
         the facility-specific 1-day and 4-day VFs were calculated to provide pollutant-specific LTAs
         and 1-day and 4-day VFs.

Step 3:   The daily limitations  for a pollutant were calculated using the product of the pollutant-
         specific LTA and the pollutant-specific 1-day VF.  Monthly average limitations were
         calculated using the product of the pollutant-specific LTA and the pollutant-specific 4-day
         VF.

6.2 Proposed Limitations

6.2.1 Daily Concentration-Based Limitations

For each technology option and subcategory, pollutant-specific daily maximum concentration-based
limitations were calculated as the product of the pollutant-specific daily long-term average and the
pollutant-specific daily variability factor.

6.2.2 Monthly Concentration-Based Limitations

For each technology option and subcategory, monthly or 4-day pollutant-specific  daily maximum
concentration-based limitations were calculated as the product of the pollutant-specific daily  long-term
average and the pollutant-specific 4-day variability factor.
                                              6-1
-------
6.3 Total Organics Parameter (TOP)
EPA defined a Total Organics Parameter (TOP) as the sum of all quantifiable concentration values
greater than the nominal quantitation value of the organic pollutants. Table 6-1 below lists the
components of TOP and their nominal quantitation limits.

                                         Table 6-1.
                     Calculation of Total Organics Parameter (TOP) Limit

Total Organic Parameter Pollutants
that are also POCs
Acrolein
Benzoic acid
Carbon disulfide
Dibenzofuran
Dibenzothiophene
Isophorone
n-Hexadecane
n-Tetradecane
Aniline
Chloroform (trichloromethane)
Methylene chloride (dichloromethane)
Chloroethane (ethyl chloride)
1 , 1 -Dichloroethane
1,1,1 -Trichloroethane
(methylchloroform)
1,1-Dichloroethylene (vinylidene
chloride)
Tetrachloroethylene (perchloroethylene)
Trichloroethylene
Biphenyl
p-Cymene
Ethylbenzene
Toluene
N-Nitrosodimethylamine
N-Nitrosodiphenylamine
Chlorobenzene
2,6-Dinitrotoluene
CAS
Number
107-02-8
65-85-0
75-15-0
132-64-9
132-65-0
78-59-1
544-76-3
929-59-4
62-53-3
67-66-3
75-09-2
75-00-3
75-34-3
71-55-6
75-35-4
127-18-4
79-01-6
92-52-4
99-87-6
100-41-4
108-88-3
62-75-9
86-30-6
108-90-7
606-20-2
Nominal
Quantitation
Limit (mg/L)
0.05
0.05
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.05
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.05
0.02
0.01
0.01
Pollutant has data in
the LTA database for
Option 2

&
X*
X

X
X
X

X


X
X
X
X
X




                                            6-2
-------

Total Organic Parameter Pollutants
that are also POCs
Phenol
4-Chloro-m-cresol (parachlommetacresol
or 4-chloro-3- methylphenol)
2,4-Dinitrophenol
2,4-Dimethylphenol
2-Nitrophenol (o-nitrophenol)
4-Nitrophenol (p-nitrophenol)
Acenaphthene
Anthracene
3 ,6-Dimethylphenanthrene
Fluorene
Fluoranthene
2-Isopropylnaphthalene
1 -Methylfluorene
2-Methylnaphthalene
1 -Methylphenanthrene
Naphthalene
Phenanthrene
Pyrene
Benzyl butyl phthalate
Dimethyl phthalate
Di-n-butyl phthalate
Di-n-octyl phthalate
Di(2-ethylhexyl) phthalate
Sum of nominal quantitation limits for
pollutants that are not in the LTA
database
CAS
Number

108-95-2
59-50-7

51-28-5
105-67-9
88-75-5
100-02-7
83-32-9
120-12-7
1576-67-6
86-73-7
206-44-0
2027-17-0
1730-37-6
91-57-6
832-69-9
91-20-3
85-01-8
129-00-0
85-68-7
131-11-3
84-74-2
117-84-0
117-81-7



Nominal
Quantitation
Limit (mg/L)
0.01
0.01

0.05
0.01
0.02
0.05
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01



Pollutant has data in
the LTA database for
Option 2

X





X

X
X

X
X
X
X
X
X
X




X
0.47


* x indicates that the pollutant has data in the LTA database for Option 2.

EPA used the following steps to calculate the limit for TOP:

•   Determine the LTA for each organic component.
•   Sum the component LTAs.
•   Multiply the total LTA by the mean VF across the individual organics.
•   Add in the sum of nominal quantitation limits for pollutants that are not in the LTA database.
                                              6-3
-------
6.4 Production-based Limits for Steel Forming and Finishing



EPA calculated production-based limits for the Steel Forming and Finishing subcategory as follows:



         Xms.     Yeal    8.3454 L x Ib   short ton                   Ib                   ke
Limit  =	 x	x —-6	x	= 0.00000417^7	= 0.00000417^7^
     pn     L    short ton  106galxmg  2x1000/6                1000/6               kkg



where X is the concentration-based limit in mg/L and Y is the production value in gallons per ton.  The

production-based limits for Steel Forming and Finishing are listed in Appendix F.
                                             6-4
-------
                                         CHAPTER 7
                                   GLOSSARY OF TERMS
Censored value: a measurement value known to be in a certain range but for which the exact value is
unknown (or deliberately ignored).

Daily maximum limit: daily effluent discharge limit on the amount of pollutant that may be discharged
in a single day. In calculating this limit, EPA uses statistical methodologies that account for reasonable
excursions from the long-tern average in a well-designed and operated treatment system. Numerically,
for MP&M, the daily maximum is usually estimated as the product of the pollutant-specific LTA and
the pollutant-specific daily Variability Factor (one-day VF).

Detection limit: the sample-specific value representing the lowest concentration that can be reliably
distinguished from zero.

Expected value: the expected value of a function of variate values is its mean value in repeated
sampling.2

Facility-specific Long-Term Average: average treated pollutant levels achieved over a period of time
by the facility. For MP&M, the facility-specific LTA is usually computed as the arithmetic mean of all
individual pollutant measurements in a given facility.

Facility-specific Variability Factor: a ratio that expresses the relationship between the average
treatment performance level from the facility and an upper bound on large values that would be
expected to occur only on rare occasions in a well-designed and operated treatment system.

Field Duplicates: one or more samples collected for a particular sampling point at the same time, or
approximately the same time, assigned different sample numbers, and flagged as duplicate for a single
episode number.

Four-day Variability Factor: a four-day average of the facility-specific or pollutant-specific
variability factors.

Grab samples: one or more samples collected for a particular sampling point over time, assigned
different sample numbers, and not physically composited.

Limitation:  any restriction, including schedules of compliance, established by a State or the
Administrator  on quantities, rates, and concentrations of chemical, physical, biological, and other
constituents which are discharged from point sources into navigable waters, the waters of the
contiguous zone, or the ocean. (CWA Sections 301 (b) and 304(b).)
       2 Kendall, M.G., and W.R. Buckland, 1982. A Dictionary of Statistical Terms.  4th Edition.
Longman Group Ltd.  New York; 213 p.

                                              7-1
-------
Lognormal distribution: a distribution whose set of values in logarithmic scale follow a mathematical
function known as the normal distribution. The lognormal distribution is often appropriate for modeling
environmental data.

LTA: Long-term average. For purposes of the effluent guidelines, average pollutant levels achieved
over a period of time by a facility, subcategory,  or technology option. LTAs are used in developing the
limitations  and standards in a proposed or final regulation.

Minimum  level: the lowest concentration that can be reliably measured by the analytical method.

MLE: Maximum Likelihood Estimate. The value of an estimate of a population parameter that
maximizes  the likelihood of the sample.

Monthly average limit: monthly effluent discharge limit on the amount of pollutant that may be
discharged  on average during a month period. In calculating this limit, EPA uses statistical
methodologies that account for reasonable excursions from the long-tern  average in a well-designed and
operated treatment system. Numerically, for MP&M, the monthly average limit is usually estimated as
the product of the pollutant-specific LTA and the pollutant-specific monthly Variability Factor (four-
day VF).

Mutually independent: two events are  independent if the probability of one is not affected by the
occurrence of the other.

Non-censored (NC): a measurement result reported  as a numerical value.

Non-detect (ND): samples below the level that can be reliably measured by the  analytical method. This
is also known, in statistical terms, as left-censored; i.e., value having an upper bound at the sample-
specific detection limit and a lower bound at zero.

One-day Variability Factor: daily average of the facility-specific or pollutant-specific variability
factors.

Parameter: Numerical descriptive values that characterize populations of measurements; e.g., a
population  mean value.

Pollutant-specific Long-Term Average:  average pollutant levels achieved by the facility. For MP&M,
the pollutant-specific LTA is computed  as the median of the facility-specific LTAs.

Pollutant-specific Variability Factor: expresses the relationship  between the average pollutant level
and an upper  bound on large pollutant values that would be expected  to occur only on rare occasions in
a well-designed and operated treatment system. In mathematical terms, for MP&M this  is the median
of the facility-specific variability factors for that pollutant.

Right-censored (RC): samples qualified with a greater than (>) sign, signifying that the reported
value is considered a lower limit of the actual concentration.
                                              7-2
-------
Single-valued probability mass: a statistical term sometimes used to describe the magnitude of a
probability or the relative frequency of observations located at a particular variate value, as distinct
from being distributed over a mathematically continuous range.

Variability Factor: used in calculating a limitation (or standard) to allow for reasonable, normal
variation in pollutant concentrations when processed through well designed and operated treatment
systems. Variability factors account for normal fluctuations in treatment. By accounting for these
reasonable excursions about the long-term average, EPA's use of variability factors results in
limitations that are generally well above the actual long-term averages.

Weighted sum: a sum of quantities to which have been attached a series of weights in order to make
proper allowance for their relative importance.1
        1 Kendall, M.G., and W.R. Buckland. 1982. A Dictionary of Statistical terms. 4th Edition.
Longman Group Ltd. New York; 213 p.

                                               7-3
-------
                     LIST OF ABBREVIATIONS AND ACRONYMS
ANO: Non-Chromium Anodizers




CN: Cyanide




DRYD: Shipbuilding Dry Dock




GENL: General Metals




LTA:  Long-term average




MFJ:  Metal Finishing Job Shops




NC: Non-censored




ND: Non-detect




OILY: Oily Only




PWB: Printed Wiring Board




RC: Right-censored




RRL:  Railroad Line Maintenance




SFF: Steel Forming and Finishing




VF: Variability Factor
-------
Table of Direct and Indirect Episodes
1197A
4011
4079
4274
4277
4278
4279
4310
4330
4384
4415
4417
4438
4460
4460A
4470
4471
4737
4761
4762
4788
4805
4806
4807
4811
4817
4828
4833
4834
4847
4851
4854
4855
4856
4866
4867
4869
4871
4872
4876
4877
4882
4883
4891
4892
4893
4894
4904
6048
6178
6179
6186
6187
Indi
Indi
Indi
Indi
Indi
Indi
Indi
Indi
Indi
Indi
Indi
Indi
Indi
Indi
Indi
ect
ect
ect
ect
ect
ect
ect
ect
ect
ect
ect
ect
ect
ect
ect
Indirect
Indirect
Direc
,t
Indirect
Indirect
Indirect
Direct
Indirect
Direc
,t
Indirect
Indirect
Indirect
Direct
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
Indirect
-------
Appendix A. Daily Effluent Data Listing
                                                         EPA
                                                       Sampling
                                                        Episode
                                           Existing
           TOTAL SUSPENDED SOLIDS
                                           Existing
                                              A-l
-------
Appendix A. Daily Effluent Data Listing (continued)
                                                                                            36.00000
                                                                                             6. 00000
                                                                                           136.00000
                                                                                           107.00000
                                                                                          1000.00000
                                                                                            62.30000
                                                                                            96.60000
                                                                                            60.00000
                                                                                            15.50000
                                                                                            29.50000
                                                                                            25.00000
                                                                                           192.00000
   DRYD       OIL AND GREASE  (AS HEM
   DRYD       TOTAL SUSPENDED SOLIDS
                                                                                            38.00000
                                                                                            21.00000
                                                                                             7.00000
                                                                                             5.00000
                                                                                            18.00000
                                                                                            11.00000
                                                                                            17.00000
                                                                                            37.50000
                                                                                            41.00000
                                                                                            44.50000
                                                                                            50.00000
                                                                                           102.00000
                                                   A-2
-------
Appendix A. Daily Effluent Data Listing (continued)
             *1,1-DICHLOROETHYLENE
                                                  Existing
             *1-METHYLFLUORENE
             *1-METHYLPHENANTHRENE
                                                  Existing
                                                  Existing
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
             *2-ISOPROPYLNAPHTHALEN
             *2-METHYLNAPHTHALENE
                                                  Existing
                                                  Existing
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
   6ENL       *3,6-DIMETHYLPHENANTHR
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
   6ENL       *4-CHLORO-M-CRESOL
   6ENL       *ACENAPHTHENE
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
   6ENL       *BENZOIC ACID
   6ENL       *BIPHENYL
                                                  Existing
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                     A-3
-------
Appendix A. Daily Effluent Data Listing (continued)
                                       117817      Existing
                                                                                                 0.13031
                                                                                                 0.05682
                                                                                                 0.13764
                                                                                                 0.10484
                                                                                                 0.00999
                                                                                                 0.01030
                                                                                                 0.01059
                                                                                                 0.01075
                                                                                                 0.00999
                                                                                                 0.00999
                                                                                                 0.00999
                                                                                                 0.00999
                                                                                                 0.00999
                                                                                                 0.00999
                                                                                                 0.01000
                                                                                                 0.01000
                                                                                                 0.01000
   6ENL       *CARBON BISULFIDE
   6ENL       *CHLOROFORM
                                                                  788
   6ENL       *DIBENZOTHIOPHENE
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
   6ENL       *ETHYLBENZENE
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
   6ENL       *FLUORENE
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
   6ENL       *N-HEXADECANE
                                                                                                 0.00999
                                                                                                 0.00999
                                                                                                 0.05499
                                                                                                 0.00999
                                                                                                 0.00999
                                                                                                 0.01000
                                                                                                 0.01000
                                                                                                 0.00999
                                                                                                 0.01030
                                                                                                 0.01059
                                                                                                 0.01615
                                                                                                 0.00999
                                                                                                 0.01632
                                                                                                 0.00999
                                                                                                 0.00999
                                                                                                 0.00999
                                                                                                 0.00999
                                                                                                 0.00999
                                                                                                 0.00999
                                                     A-4
-------
Appendix A. Daily Effluent Data Listing (continued)
             *N-HEXADECANE
                                                 Existing
             *N-TETRADECANE
                                                 Existing
             ^NAPHTHALENE
             *PHENANTHRENE
                                                 Existing
                                                 Existing
                                                 Existing
6179
6179
6179
4471
4471
4471
4471
4737
4737
4737
4737
4737
4805
4805
4851
4851
4851
4851
4851
4876
4876
4876
4876
4876
4892
4892
4892
4892
4892
6179
6179
6179
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
6179
6179
6179
4851
4851
4851
1
2
3
1
2
3
4
1
2
3
4
5
1
2
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
ND
ND
ND
NC
ND
NC
NC
ND
ND
ND
ND
ND
ND
ND
NC
NC
ND
NC
NC
ND
ND
ND
ND
ND
ND
ND
NC
ND
NC
ND
ND
ND
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
                                                                                             0.02350
                                                                                             0.00999
                                                                                             0.01591
                                                                                             0.05649
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0. 05499
                                                                                             0.00999
                                                                                             0. 00999
                                                                                             0.01000
                                                                                             0.01000
                                                                                             0.03607
                                                                                             0.01174
                                                                                             0.01059
                                                                                             0.02707
                                                                                             0.01386
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.01000
                                                                                             0.01000
                                                                                             0.01399
                                                                                             0.01000
                                                                                             0.04196
                                                                                             0.01000
                                                                                             0.01000
                                                                                             0.01000
                                                   A-5
-------
Appendix A. Daily Effluent Data Listing (continued)
New Source or EPA
CAS Existing Source Sampling
Subcategory Analyte Number Trt. Option Episode
6ENL *PYRENE 129000 Existing 4851
4851
6ENL *TOLUENE 108883 Existing 4737
4737
4737
4737
4737
4851
4851
4851
4851
4851
6ENL AMENABLE CYANIDE C025 4807
4807
4807
4807
4807
4817
4817
4817
4817
4828
4828
4828
4828
4828
4834
4834
4834
4834
4834
4847
4847
4847
4847
4904
4904
4904
4904
4904
6048
6048
6048
6048
6048
6186
6186
6186
6186
6186
6ENL CADMIUM 7440439 Existing 1197A
1197A
4277
4277
4277
4277
4277
4415
4415
4415
4460
Sample
Day
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
1
2
3
4
5
1
2
3
4
5
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
2
3
1
2
3
4
5
2
3
4
1
NC/ND
ND
ND
ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
NC
NC
ND
NC
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
ND
NC
ND
ND
NC
NC
NC
NC
NC
NC
NC
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
NC
NC
Concentration
(mg/L)
0.01075
0.00999
0.00999
0. 00999
0.00999
1.17472
0. 69257
0.03442
0. 01968
0.01872
0. 01603
0.01840
0.01999
0. 01999
0. 01999
0.01999
0.01999
0. 57499
0.81000
0.20000
0. 57999
0. 03500
0.15999
0. 06300
0. 03799
0. 02400
0. 01999
0.01999
0.01999
0. 01999
0. 01999
0.00999
0.01049
0.00999
0. 00999
0. 16249
0.07349
0. 14300
0.13400
0. 08200
0.01999
0. 03700
0. 00499
0. 00499
0. 01400
0. 04899
0.02250
0. 01750
0.10999
0. 10999
0.07999
0. 06100
0.23000
0.20200
0. 07789
0. 14000
0.21899
0. 00499
0. 00499
0.00549
0. 02060
                                         A-6
-------
Appendix A. Daily Effluent Data Listing (continued)
                                         Existing
                                7440473
                                         Existing
6048
6048
6048
4882
4882
4882
4882
4882
1197A
1197A
1197A
4011
4011
4011
4079
4079
4079
4310
4310
4310
4330
4330
4330
4330
4330
4384
4384
4384
4384
4384
4415
4415
4415
4417
4417
4417
4417
4417
4438
4438
4438
4460
4460
4460
4470
4470
4470
4470
4470
4811
4811
4811
4811
4811
4817
4817
4817
4817
3
4
5
1
2
3
4
5

2
3
1
2
3
1
2
3
2
3
4
1
2
3
4
5
1
2
3
4
5
2
3
4
1
2
3
4
5
1
4
5
1
2
3
1
2
3
4
5
1
2
3
4
5
1
2
3
4
NC
NC
NC
NC
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
NC
NC
ND
NC
NC
NC
NC
0. 94199
0. 76499
0. 80099
0.00725
0. 00500
0.00560
0. 00730
0.01020
0.02700
0. 65600
1.23000
0. 75599
0.72600
1. 13000
0. 63499
1. 82000
0. 45600
0. 39500
1.77000
4. 65000
0. 06599
0. 13112
0.04343
0. 05015
0. 04301
0. 60299
0.78549
0. 53200
0.59299
0. 41100
0.01480
0. 01960
0.11200
0. 01989
0.01329
0. 02920
0.00980
0. 02160
0. 09899
0. 09099
0. 08799
1. 33000
1.21000
0. 98400
0.10832
0. 06859
0.05547
0. 08252
0. 07164
0. 00800
0.00800
0. 00965
0.00910
0. 00800
0.05759
0. 03144
0.08049
0. 02170
                                            A-7
-------
Appendix A. Daily Effluent Data Listing (continued)
6ENL CHROMIUM 7440473 Existing 4817
4833
4833
4833
4833
4833
4847
4847
4847
4847
4847
4871
4871
4871
4871
4871
4904
4904
4904
4904
4904
New 4807
4807
4807
4807
4807
4854
4854
4854
4854
4854
4882
4882
4882
4882
4882
6ENL COPPER 7440508 Existing 4277
4277
4277
4277
4277
4737
4737
4737
4737
4737
4806
4806
4806
4806
4806
4807
4807
4807
4807
4807
4817
4817
4817
4817
4817
4833
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
NC
ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
0.27149
0. 03689
0.02814
0. 06750
0.08910
0. 11800
0. 37999
0.20100
0.19400
0.18999
0.54299
0.00999
0.01064
0.00999
0.00999
0.00999
0.01695
0. 01205
0.01059
0. 02190
0.01224
0.08500
0. 01540
0.03680
0. 02480
0.01700
0. 01425
0.01705
0. 01700
0.00980
0. 01195
0.01590
0. 03305
0. 08675
0. 09540
0. 46800
0.63800
0. 70099
0.61000
0. 46200
0.38499
0. 50690
0.03990
0. 02166
0.23477
0. 07300
1.07000
0.26499
0. 30099
0 92599
0.48399
1. 31500
1.43000
1. 36000
0.71499
0. 42649
0.19949
0. 14949
0.15399
0.25999
0.42849
0. 10999
                                         A-8
-------
Appendix A. Daily Effluent Data Listing (continued)
6ENL COPPER 7440508 Existing 4833
4833
4833
4833
4834
4834
4834
4834
4834
4847
4847
4847
4847
4847
4904
4904
4904
4904
4904
New 4807
4807
4807
4807
4807
4854
4854
4854
4854
4854
4882
4882
4882
4882
4882
6ENL CYANIDE 57125 4274
4274
4274
4279
4279
4279
4279
4279
4384
4384
4384
4384
4384
4460A
4807
4807
4807
4807
4807
4817
4817
4817
4817
4817
4828
4828
4828
4828

3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
2
3
4
1
2
3
4
5
1
2
3
4
5
2
1
2
3
4
5
1
2
3
4
5
1
2
3
4
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
NC
ND
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
NC
NC
ND
NC
ND
NC
NC
NC
NC
0. 12649
0. 09785
0.13150
0. 17550
0.07720
0. 04769
0.05189
0. 04540
0.07959
0. 11800
0.10000
0. 10300
0.03539
0. 04639
0. 03705
0.03999
0.03135
0. 04915
0. 07365
0.12700
0. 04160
0.04180
0. 06630
0.09290
0. 33050
0.03940
0. 00800
0.03405
0. 00800
0 . 06605
0. 02055
0.01680
0. 01240
0. 01265
0. 00999
0.00999
0.00999
0.00999
0. 00999
0.00999
0.00999
0.00999
0. 46299
0. 69400
0. 99199
0. 75800
0. 94499
0.01999
0. 02099
0. 02800
0. 04699
0.01999
0.01999
0. 57499
0.81000
0.20000
0.61000
0. 01999
0. 06199
0. 18000
0.09250
0.07599
                                         A-9
-------
Appendix A. Daily Effluent Data Listing (continued)
New Source or EPA
CAS Existing Source Sampling
Subcategory Analyte Number Trt. Option Episode
6ENL CYANIDE 57125 4828
4834
4834
4834
4834
4834
4847
4847
4847
4847
4891
4891
4891
4891
4891
4904
4904
4904
4904
4904
6048
6048
6048
6048
6048
6186
6186
6186
6186
6186
6ENL LEAD 7439921 Existing 1197A
1197A
1197A
4761
4761
4761
4762
4762
4762
4762
4762
4834
4834
4834
4834
4834
4871
4871
4871
4871
4871
6ENL MANGANESE 7439965 Existing 4762
4762
4762
4762
4762
4807
4807
4807
4807
Sample
Day
5
1
2
3
4
5
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
2
2
3
1
2
3
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
NC/ND
NC
ND
ND
ND
ND
ND
NC
NC
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
NC
NC
ND
ND
ND
ND
ND
ND
ND
ND
NC
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
Concentration
(mg/L)
0. 04899
0.01999
0.01999
0. 01999
0. 01999
0.01999
0.01899
0. 01049
0. 00999
0.00999
0.07150
0. 04399
0.05600
0.10999
0.15999
0. 17499
0.11699
0. 32550
0. 30899
0. 35899
0. 17499
0. 30000
0.18999
0. 17000
0.20000
0. 12999
0.20000
0.20999
0.23999
0.20000
0.20000
4. 97000
0.46999
0.01200
0. 01200
0.01200
0. 02480
0.02480
0. 02480
0.02480
0. 02480
0.02439
0. 01600
0.01810
0. 01860
0.02559
0. 00870
0.01305
0. 01099
0. 00609
0. 00829
0. 16500
0.09690
0. 16799
0.13400
0. 12999
0.03015
0. 04670
0.03970
0. 07095
                                        A-10
-------
Appendix A. Daily Effluent Data Listing (continued)
   6ENL       MANGANESE
                                                  Existing
                                                  Existing
   6ENL       NICKEL
                                                                 1197A
                                                                 1197A
                                                                 1197A
                                                                 4277
                                                                 4277
                                                                 4277
                                                                 4277
                                                                 4277
                                                                 4438
                                                                 4438
                                                                 4438
                                                                 4470
                                                                 4470
                                                                 4470
                                                                 4470
                                                                 4470
                                                                 4761
                                                                 4761
                                                                 4761
                                                                 4762
                                                                 4762
                                                                 4762
                                                                 4762
                                                                 4762
                                                                 4807
                                                                 4807
                                                                 4807
                                                                 4807
                                                                 4807
                                                                 4811
                                                                 4811
                                                                 4811
                                                                 4811
                                                                 4811
                                                                 4817
                                                                 4817
                                                                 4817
0.07100
1.39000
0.20900
0.17299
0.18000
0.16099
0.18000
0.19699
0.37799
0.51800
0. 34799
0.33860
0.22931
0.14263
0.22362
0.22212
0.22499
0.31900
0.25400
0.23199
0.12399
0.15800
0.21099
0.30399
0.28749
0.35400
0. 31949
0.21999
0. 13799
0.05665
0.05970
0.06340
0.03725
0.01799
0.02089
0.02844
0.02820
                                                    A-ll
-------
Appendix A. Daily Effluent Data Listing (continued)
6ENL NICKEL 7440020 Existing 4817
4817
4833
4833
4833
4833
4833
4834
4834
4834
4834
4834
4847
4847
4847
4847
4847
4871
4871
4871
4871
4871
4904
4904
4904
4904
4904
6048
6048
6048
6048
6048
New 4807
4807
4807
4807
4807
4854
4854
4854
4854
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
NC
NC
NC
ND
ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
0.04720
0. 04735
0.19200
0. 01600
0.01600
0. 01600
0. 01600
0.48399
0.31000
0.21600
0.21199
0. 43000
0.04320
0. 03109
0.02730
0. 06100
0. 10999
0. 69749
0.62050
0. 60199
0.53600
0. 80199
0. 02600
0. 02600
0.02600
0. 02600
0. 02600
0. 13500
0.51800
0.27000
0.28400
0. 52499
1. 58000
0.48000
0. 55000
0.54100
0. 60500
0.10100
0. 01705
0.01600
0. 01600
  6ENL      OIL AND GREASE (AS HEM
                                          Existing
                                                                                 0.02165
                                            A-12
-------
Appendix A. Daily Effluent Data Listing (continued)
                                                 Existing
   6ENL       TIN
                                                 Existing
                                                                4737
                                                                4737
                                                                4737
                                                                4737
                                                                4737
                                                                4761
                                                                4761
                                                                4761
                                                                4762
                                                                4762
                                                                4762
                                                                4762
                                                                4762
                                                                4806
                                                                4806
                                                                4806
                                                                4806
                                                                4806
                                                                4807
                                                                4807
                                                                4807
                                                                4807
                                                                4807
                                                                4817
                                                                4817
                                                                4817
                                                                4817
                                                                4817
                                                                4833
                                                                4833
                                                                4833
106.50000
 71.50000
 71.50000
108.00000
 75.00000
 51.00000
 46.00000
 52.00000
172.00000
180.00000
182.00000
172.00000
147.00000
 29.30000
 12.90000
  9.30000
 37.00000
 20.40000
 16.20000
 23.65000
 27.45000
 10.25000
  8.90000
 16.40000
 17.40000
 21.60000
 25.70000
 31.75000
 10.00000
 12.00000
 34.00000
                                                    A-13
-------
Appendix A. Daily Effluent Data Listing (continued)
New Source or EPA
CAS Existing Source Sampling
Subcategory Analyte Number Trt. Option Episode
6ENL TOTAL ORGANIC CARBON ( C012 Existing 4833
4833
4834
4834
4834
4834
4834
4871
4871
4871
4871
4871
4904
4904
4904
4904
4904
6ENL TOTAL SUSPENDED SOLIDS C009 Existing 1197A
1197A
1197A
4011
4011
4011
4079
4079
4079
4277
4277
4277
4277
4277
4384
4384
4384
4384
4384
4415
4415
4415
4417
4417
4417
4417
4417
4438
4438
4438
4470
4470
4470
4470
4470
4737
4737
4737
4737
4737
4761
4761
4761
4762
4762
4762
Sample
Day
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5

2
3
1
2
3
1
2
3
1
2
3
4
5
1
2
3
4
5
2
3
4
1
2
3
4
5
1
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
NC/ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
NC
NC
NC
NC
NC
NC
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
ND
NC
NC
NC
NC
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
Concentration
(mg/L)
10.
10.
87.
7 7 .
90.
67.
42.
117.
86.
117.
90.
101.
10.
10.
10.
10.
10.
32.
20.
28.
22.
28.
30.
5.
5 .
9.
14.
14.
17.
10.
17.
23.
50.
32.
68.
55.
1.
1.
1.
12.
10.
7 ,
4.
2 .
7 ,
8 .
5 .
32.
10.
10.
22.
14.
12.
20.
14.
35.
38.
25.
24.
17.
14.
13.
16.
.00000
. 00000
.10000
. 90000
.70000
. 60000
.00000
. 50000
. 60000
. 00000
.80000
. 00000
.00000
. 00000
.00000
. 00000
.00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.50000
. 50000
.00000
. 50000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
                                        A-14
-------
Appendix A. Daily Effluent Data Listing (continued)
6ENL TOTAL SUSPENDED SOLIDS C009 Existing 4762
4762
4807
4807
4807
4807
4807
4811
4811
4811
4811
4811
4817
4817
4817
4817
4817
4833
4833
4833
4833
4833
4834
4834
4834
4834
4834
4871
4871
4871
4871
4871
4904
4904
4904
4904
4904
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
NO
NO
NC
NO
NC
NC
ND
NC
ND
ND
NC
ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
NC
ND
NC
NC
NC
NC
NC
NC
ND
ND
NC
NC
16.
13.
6.
16.
7 .
8 .
4.
4.
4.
4.
4.
4.
8 .
4.
21.
18.
8 .
6.
7 .
17.
5.
5.
7 .
44.
4.
14.
4.
T
8 .
6.
4.
4.
4.
4.
4.
8.
7 .
. 00000
. 00000
. 00000
.00000
. 50000
. 00000
. 00000
.00000
. 00000
. 00000
. 00000
00000
00000
00000
00000
00000
00000
50000
00000
50000
50000
50000
00000
00000
00000
00000
00000
00000
00000
00000
00000
00000
50000
00000
00000
50000
50000
   6ENL      ZINC
                                             Existing
                                                                                        0.04100
                                                                                        0.01999
                                                                                        0.02180
                                                                                        0.04690
                                                                                        0.04160
                                                                                        0.01260
                                                                                        0.01530
                                                                                        0.07039
                                                                                        0.05759
                                                                                        0.54100
                                                                                        0.15000
                                                                                        0.21299
                                                                                        0.17299
                                                                                        0.07779
                                                                                        0.21199
                                                A-15
-------
Appendix A. Daily Effluent Data Listing (continued)
New Source or EPA
CAS Existing Source Sampling
Subcategory Analyte Number Trt. Option Episode
6ENL ZINC 7440666 Existing 4470
4470
4470
4470
4470
4737
4737
4737
4737
4737
4761
4761
4761
4762
4762
4762
4762
4762
4807
4807
4807
4807
4807
4811
4811
4811
4811
4811
4817
4817
4817
4817
4817
4871
4871
4871
4871
4871
4904
4904
4904
4904
4904
New 4807
4807
4807
4807
4807
4854
4854
4854
4854
4854
4882
4882
4882
4882
4882
Sample
Day
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
NC/ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
NC
ND
ND
ND
NC
NC
NC
NC
ND
NC
NC
ND
ND
ND
NC
NC
NC
NC
ND
Concentration
(mg/L)
1.79270
1. 18100
0. 98581
1. 59270
1.35062
0. 38565
0. 09262
0. 06555
0.05569
0. 08816
0. 13600
0.20149
0. 14000
0. 26899
0. 16300
0.22400
0. 17299
0. 17499
0.13750
0. 16550
0.19400
0. 09745
0.05070
0. 05559
0.04684
0. 06289
0. 05214
0. 04729
0.44749
0. 30050
0.19599
0. 41100
0.30950
0.20350
0.21500
0. 13899
0. 12600
0. 14100
0.01499
0. 01844
0.01499
0. 01499
0.01499
0. 05760
0. 05840
0.03980
0. 04520
0.00020
0. 01965
0.01700
0. 00800
0. 00800
0. 00800
0.02840
0. 02955
0.06715
0. 04610
0.01100
                                        A-16
-------
Appendix A. Daily Effluent Data Listing (continued)
             *1,1-DICHLOROETHYLENE
                                                 Existing
             *1-METHYLFLUORENE
             *1-METHYLPHENANTHRENE
                                                 Existing
                                                 Existing
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
             *2-ISOPROPYLNAPHTHALEN
             *2-METHYLNAPHTHALENE
                                                 Existing
                                                 Existing
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
   MFJ        *3,6-DIMETHYLPHENANTHR
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
             *ACENAPHTHENE
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
             *BENZOIC ACID
                                                 Existing
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                   A-17
-------
Appendix A. Daily Effluent Data Listing (continued)
                                       117817      Existing
                                                                                                0.13031
                                                                                                0.05682
                                                                                                0.13764
                                                                                                0.10484
                                                                                                0.00999
                                                                                                0.01030
                                                                                                0.01059
                                                                                                0.01075
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.01000
                                                                                                0.01000
                                                                                                0.01000
             *CARBON BISULFIDE
             *CHLOROFORM
                                                                  788
             *DIBENZOTHIOPHENE
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
             *ETHYLBENZENE
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
             *N-HEXADECANE
                                                                                                0.00999
                                                                                                0. 00999
                                                                                                0.05499
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.01000
                                                                                                0.01000
                                                                                                0. 00999
                                                                                                0. 01030
                                                                                                0.01059
                                                                                                0.01615
                                                                                                0.00999
                                                                                                0.01632
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                    A-18
-------
Appendix A. Daily Effluent Data Listing (continued)
             *N-HEXADECANE
             *N-TETRADECANE
             *NAPHTHALENE
             *PHENANTHRENE
                                                 Existing
4471
4471
4471
4471
4737
4737
4737
4737
4737
4805
4805
4851
4851
4851
4851
4851
4876
4876
4876
4876
4876
4892
4892
4892
4892
4892
6179
6179
6179
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
6179
6179
6179
4851
4851
4851
1
2
3
4
1
2
3
4
5
1
2
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
NC
ND
NC
NC
ND
ND
ND
ND
ND
ND
ND
NC
NC
ND
NC
NC
ND
ND
ND
ND
ND
ND
ND
NC
ND
NC
ND
ND
ND
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
                                                                                              0. 02350
                                                                                              0. 00999
                                                                                              0.01591
                                                                                              0.05649
                                                                                              0.00999
                                                                                              0.00999
                                                                                              0.05499
                                                                                              0.00999
                                                                                              0.00999
                                                                                              0.01000
                                                                                              0.01000
                                                                                              0.03607
                                                                                              0. 01174
                                                                                              0.01059
                                                                                              0.02707
                                                                                              0.01386
                                                                                              0.00999
                                                                                              0. 00999
                                                                                              0.00999
                                                                                              0.00999
                                                                                              0.00999
                                                                                              0.01000
                                                                                              0.01000
                                                                                              0.01399
                                                                                              0.01000
                                                                                              0.04196
                                                                                              0.01000
                                                                                              0.01000
                                                                                              0. 01000
                                                   A-19
-------
Appendix A. Daily Effluent Data Listing (continued)
                                                                 4851
                                                                 4851

                                                                 4737
                                                                 4737
                                                                 4737
                                                                 4737
                                                                 4737
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
ND
ND
             AMENABLE CYANIDE
                                                                 4807
                                                                 4807
                                                                 4807
                                                                 4807
                                                                 4807
                                                                 4817
                                                                 4817
                                                                 4817
                                                                 4817
                                                                 4828
                                                                 4828
                                                                 4828
                                                                 4828
                                                                 4828
                                                                 4834
                                                                 4834
                                                                 4834
                                                                 4834
                                                                 4834
                                                                 4847
                                                                 4847
                                                                 4847
                                                                 4847
                                                                 4904
                                                                 4904
                                                                 4904
                                                                 4904
                                                                 4904
                                                                 6048
                                                                 6048
                                                                 6048
                                                                 6048
                                                                 6048
                                                                 6186
                                                                 6186
                                                                 6186
                                                                 6186
                                                                 6186
           0.01999
           0. 01999
           0. 01999
           0.01999
           0.01999
           0. 57499
           0.81000
           0.20000
           0. 57999
           0.03500
           0.15999
           0. 06300
           0. 03799
           0.02400
           0.01999
           0.01999
           0.01999
           0.01999
           0.01999
           0.00999
           0.01049
           0.00999
           0.00999
           0. 16249
           0.07349
           0.14300
           0.13400
           0.08200
           0.01999
           0.03700
           0. 00499
           0.00499
           0. 01400
           0.04899
           0.02250
           0.01750
           0.10999
           0.10999
                                                    A-20
-------
Appendix A. Daily Effluent Data Listing (continued)
                                      7440473
                                                 Existing
                                                 Existing
                                                                                               0.00700
                                                                                               0.03260
                                                                                               0.01950
                                                                                               0.00700
                                                                                               0.36421
                                                                                               0.50753
                                                                                               0.57599
                                                                                               0.18008
                                                                                               0.83379
                                                                                               0.33649
                                                                                               0. 18850
                                                                                               0.47499
                                                                                               0.23600
                                                                                               0.05000
                                                                                               0.12600
                                                                                               0.38199
                                                                                               0.14100
                                                                                               0.28200
                                                                                               0.62599
                                                                                               0.16949
                                                                                               0.47850
                                                                                               0.39599
                                                                                               0.03550
                                                                                               0.32899
                                                                                               0.08709
                                                                                               0.06080
                                                                                               0.09901
                                                                                               0.12349
                                                                                               0.17476
                                                                                               0.03440
                                                                                               0.09288
                                                                                               0.17599
                                                                                               0.59600
                                                                                               0.35850
                                                                                               0.40700
                                                                                               0.30399
                                                                                               0. 46349
                                                                                               0.25299
                                                                                               0.22100
                                                                                               0.65299
                                                                                               0.43900
                                                                                               0.42050
                                                                                               0.20800
                                                                                               0.27700
                                                    A-21
-------
Appendix A. Daily Effluent Data Listing (continued)
New Source or EPA
CAS Existing Source Sampling
Subcategory Analyte Number Trt. Option Episode
MFJ CYANIDE 57125 4384
4460A
4807
4807
4807
4807
4807
4817
4817
4817
4817
4817
4828
4828
4828
4828
4828
4834
4834
4834
4834
4834
4847
4847
4847
4847
4891
4891
4891
4891
4891
4904
4904
4904
4904
4904
6048
6048
6048
6048
6048
6186
6186
6186
6186
6186
MFJ LEAD 7439921 Existing 4788
4788
4788
4788
4788
6178
6178
6178
6187
6187
6187
MFJ MANGANESE 7439965 Existing 4278
4278
4278
4278
4279
Sample
Day
5
2
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
1
2
3
4
1
NC/ND
NC
NC
NC
NC
NC
ND
ND
NC
NC
ND
NC
ND
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
NC
NC
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
Concentration
(mg/L)
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0 .
0.
0.
. 94499
.01999
. 02099
. 02800
. 04699
.01999
. 01999
.57499
. 81000
.20000
. 61000
01999
06199
18000
09250
07599
04899
01999
01999
01999
01999
01999
01899
01049
00999
00999
07150
04399
05600
10999
15999
17499
11699
32550
30899
35899
17499
30000
18999
17000
20000
12999
20000
20999
23999
20000
16550
12749
15199
24449
19599
03500
07000
05499
08449
04450
07500
18099
16599
11500
17200
03500
                                        A-22
-------
Appendix A. Daily Effluent Data Listing (continued)
                                              Existing
                                                                                         0.31700
                                                                                         1.57000
                                                                                         0.59600
                                                                                         0.31799
                                                                                         0.47674
                                                                                         0.48102
                                                                                         0.36305
                                                                                         0.05809
                                                                                         0.52745
                                                                                         0.69050
                                                                                         0.79000
                                                                                         0.74849
                                                                                         0.67949
                                                                                         0.34200
                                                                                         0.31499
                                                                                         0.20499
                                                                                         0.53399
                                                                                         0.46500
                                                                                         0.18199
                                                                                         0.30500
                                                                                         0.23350
                                                 A-23
-------
Appendix A. Daily Effluent Data Listing (continued)
                                                               EPA
                                                            Sampling
                                                            Episode
                                               Existing
                                                                                           0.26262
                                                                                           2.86580
                                                                                           0.01129
                                                                                           0.03229
                                                                                           0.02425
                                                                                           0.01118
                                                                                           0.01300
                                                                                           0.17700
                                                                                           0.26899
                                                                                           0.23049
                                                                                           0.32199
                                                                                           0.16400
                                                                                           0.08735
                                                                                           0.35199
                                                                                           0.11450
                                                                                           0.25499
                                                                                           0.04634
                                                                                           0.01689
                                                                                           0.01614
                                                                                           0. 01775
                                                                                           0.01620
                                                                                           0.02209
                                                 A-24
-------
Appendix A. Daily Effluent Data Listing (continued)
   OILY       *1,1-DICHLOROETHYLENE      75354      Existing
   OILY       *1-METHYLFLUORENE
   OILY       *1-METHYLPHENANTHRENE      832699     Existing
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
   OILY       *2-ISOPROPYLNAPHTHALEN     2027170     Existing
   OILY       *2-METHYLNAPHTHALENE       91576      Existing
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
   OILY       *3,6-DIMETHYLPHENANTHR     1576676     Existing
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
   OILY       *ACENAPHTHENE
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
   OILY       *BENZOIC ACID
   OILY       *BIPHENYL
                                      92524      Existing
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                    A-25
-------
Appendix A. Daily Effluent Data Listing (continued)
                                       117817      Existing
                                                                                                0.13031
                                                                                                0.05682
                                                                                                0.13764
                                                                                                0.10484
                                                                                                0.00999
                                                                                                0.01030
                                                                                                0.01059
                                                                                                0.01075
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.01000
                                                                                                0.01000
                                                                                                0.01000
   OILY       *CARBON BISULFIDE
   OILY       *CHLOROFORM
                                                                  788
   OILY       *DIBENZOTHIOPHENE
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
   OILY       *ETHYLBENZENE
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
   OILY       *FLUORENE
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
   OILY       *N-HEXADECANE
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.05499
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.01000
                                                                                                0.01000
                                                                                                0.00999
                                                                                                0.01030
                                                                                                0.01059
                                                                                                0.01615
                                                                                                0.00999
                                                                                                0.01632
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                    A-26
-------
Appendix A. Daily Effluent Data Listing (continued)
             *N-HEXADECANE
                                                Existing
             *N-TETRADECANE
                                                Existing
             ^NAPHTHALENE
             *PHENANTHRENE
                                                Existing
                                                Existing
                                                Existing
6179
6179
6179
4471
4471
4471
4471
4737
4737
4737
4737
4737
4805
4805
4851
4851
4851
4851
4851
4876
4876
4876
4876
4876
4892
4892
4892
4892
4892
6179
6179
6179
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
6179
6179
6179
4851
4851
4851
1
2
3
1
2
3
4
1
2
3
4
5
1
2
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
ND
ND
ND
NC
ND
NC
NC
ND
ND
ND
ND
ND
ND
ND
NC
NC
ND
NC
NC
ND
ND
ND
ND
ND
ND
ND
NC
ND
NC
ND
ND
ND
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
                                                                                             0.02350
                                                                                             0.00999
                                                                                             0.01591
                                                                                             0.05649
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0. 05499
                                                                                             0.00999
                                                                                             0. 00999
                                                                                             0.01000
                                                                                             0.01000
                                                                                             0.03607
                                                                                             0.01174
                                                                                             0.01059
                                                                                             0.02707
                                                                                             0.01386
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.01000
                                                                                             0.01000
                                                                                             0.01399
                                                                                             0.01000
                                                                                             0.04196
                                                                                             0.01000
                                                                                             0.01000
                                                                                             0.01000
                                                   A-27
-------
Appendix A. Daily Effluent Data Listing (continued)
                                                              4851
                                                              4851
ND
ND
             OIL AND GREASE (AS HEM
                                               Existing
                                               Existing
             TOTAL SULFIDE
             TOTAL SUSPENDED SOLIDS
                                                                                         100.00000
                                                                                          40.00000
                                                                                          36.00000
                                                                                           6.00000
                                                                                          40.00000
                                                                                          35.00000
                                                                                          49.00000
                                                                                          48.00000
                                                                                          34.00000
                                                                                          12.50000
                                                                                          10.00000
                                                                                          13.00000
                                                                                          18.00000
                                                                                          15.00000
                                                                                          20.00000
                                                 A-28
-------
Appendix A. Daily Effluent Data Listing (continued)
                                                        EPA
                                                      Sampling
                                                      Episode
Sample
 Day
           TOTAL SUSPENDED SOLIDS
                                           Existing
                                            A-29
-------
Appendix A. Daily Effluent Data Listing (continued)
             *1,1-DICHLOROETHYLENE
                                                 Existing
             *1-METHYLFLUORENE
             *1-METHYLPHENANTHRENE
                                                 Existing
                                                 Existing
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
             *2-ISOPROPYLNAPHTHALEN
             *2-METHYLNAPHTHALENE
                                                 Existing
                                                 Existing
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
   PWB        *3,6-DIMETHYLPHENANTHR
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
             *ACENAPHTHENE
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
             *BENZOIC ACID
                                                 Existing
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                   A-30
-------
Appendix A. Daily Effluent Data Listing (continued)
                                       117817      Existing
                                                                                                0.13031
                                                                                                0.05682
                                                                                                0.13764
                                                                                                0.10484
                                                                                                0.00999
                                                                                                0.01030
                                                                                                0.01059
                                                                                                0.01075
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.01000
                                                                                                0.01000
                                                                                                0.01000
             *CARBON BISULFIDE
             *CHLOROFORM
                                                                  788
             *DIBENZOTHIOPHENE
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
             *ETHYLBENZENE
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
             *N-HEXADECANE
                                                                                                0.00999
                                                                                                0. 00999
                                                                                                0.05499
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.01000
                                                                                                0.01000
                                                                                                0. 00999
                                                                                                0. 01030
                                                                                                0.01059
                                                                                                0.01615
                                                                                                0.00999
                                                                                                0.01632
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                    A-31
-------
Appendix A. Daily Effluent Data Listing (continued)
             *N-HEXADECANE
                                                Existing
             *N-TETRADECANE
                                                Existing
             ^NAPHTHALENE
             *PHENANTHRENE
                                                Existing
                                                Existing
                                                Existing
6179
6179
6179
4471
4471
4471
4471
4737
4737
4737
4737
4737
4805
4805
4851
4851
4851
4851
4851
4876
4876
4876
4876
4876
4892
4892
4892
4892
4892
6179
6179
6179
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
6179
6179
6179
4851
4851
4851
1
2
3
1
2
3
4
1
2
3
4
5
1
2
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
ND
ND
ND
NC
ND
NC
NC
ND
ND
ND
ND
ND
ND
ND
NC
NC
ND
NC
NC
ND
ND
ND
ND
ND
ND
ND
NC
ND
NC
ND
ND
ND
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
                                                                                             0.02350
                                                                                             0.00999
                                                                                             0.01591
                                                                                             0.05649
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0. 05499
                                                                                             0.00999
                                                                                             0. 00999
                                                                                             0.01000
                                                                                             0.01000
                                                                                             0.03607
                                                                                             0.01174
                                                                                             0.01059
                                                                                             0.02707
                                                                                             0.01386
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.01000
                                                                                             0.01000
                                                                                             0.01399
                                                                                             0.01000
                                                                                             0.04196
                                                                                             0.01000
                                                                                             0.01000
                                                                                             0.01000
                                                   A-32
-------
Appendix A. Daily Effluent Data Listing (continued)
                                                                 4851
                                                                 4851

                                                                 4737
                                                                 4737
                                                                 4737
                                                                 4737
                                                                 4737
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
ND
ND
             AMENABLE CYANIDE
                                                                 4807
                                                                 4807
                                                                 4807
                                                                 4807
                                                                 4807
                                                                 4817
                                                                 4817
                                                                 4817
                                                                 4817
                                                                 4828
                                                                 4828
                                                                 4828
                                                                 4828
                                                                 4828
                                                                 4834
                                                                 4834
                                                                 4834
                                                                 4834
                                                                 4834
                                                                 4847
                                                                 4847
                                                                 4847
                                                                 4847
                                                                 4904
                                                                 4904
                                                                 4904
                                                                 4904
                                                                 4904
                                                                 6048
                                                                 6048
                                                                 6048
                                                                 6048
                                                                 6048
                                                                 6186
                                                                 6186
                                                                 6186
                                                                 6186
                                                                 6186
           0.01999
           0. 01999
           0. 01999
           0.01999
           0.01999
           0. 57499
           0.81000
           0.20000
           0. 57999
           0.03500
           0.15999
           0. 06300
           0. 03799
           0.02400
           0.01999
           0.01999
           0.01999
           0.01999
           0.01999
           0.00999
           0.01049
           0.00999
           0.00999
           0. 16249
           0.07349
           0.14300
           0.13400
           0.08200
           0.01999
           0.03700
           0. 00499
           0.00499
           0. 01400
           0.04899
           0.02250
           0.01750
           0.10999
           0.10999
                                                    A-33
-------
Appendix A. Daily Effluent Data Listing (continued)
4274
4274
4274
4279
4279
4279
4279
4279
4384
4384
4384
4384
4384
4460A
4807
4807
4807
4807
4807
4817
4817
4817
4817
4817
4828
4828
4828
4828
4828
4834
4834
4834
4834
4834
4847
4847
4847
4847
4891
4891
4891
4891
4891
4904
4904
4904
4904
4904
6048
6048
6048
6048
6048
6186
6186
6186
6186
6186
2
3
4
1
2
3
4
5
1
2
3
4
5
2
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
ND
ND
ND
ND
ND
ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
NC
NC
ND
NC
ND
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
NC
NC
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
. 00999
.00999
.00999
.00999
. 00999
00999
00999
00999
46299
69400
99199
75800
94499
01999
02099
02800
04699
01999
01999
57499
81000
20000
61000
01999
06199
18000
09250
07599
04899
01999
01999
01999
01999
01999
01899
01049
00999
00999
07150
04399
05600
10999
15999
17499
11699
32550
30899
35899
17499
30000
18999
17000
20000
12999
20000
20999
23999
20000
                                        A-34
-------
Appendix A. Daily Effluent Data Listing (continued)
PWB LEAD 7439921 New 4855 1
4855 2
4855 3
4855 4
4855 5
PWB MANGANESE 7439965 Existing 4866 1
4866 2
4866 3
4866 4
ND
ND
ND
ND
ND
NC
NC
NC
NC
0. 02100
0.02100
0. 02100
0.02100
0. 02100
0.21199
0.23549
0.28949
0. 66600
                                 7440020
                                           Existing
                                 7440315
                                           Existing
                                           Existing
                                             A-35
-------
Appendix A. Daily Effluent Data Listing (continued)
                                                          EPA
                                                        Sampling
                                                        Episode
Sample
 Day
                                            Existing
                                            Existing
                                            Existing
                                              A-36
-------
Appendix A. Daily Effluent Data Listing (continued)
             *1,1-DICHLOROETHYLENE
                                                 Existing
             *1-METHYLFLUORENE
             *1-METHYLPHENANTHRENE
                                                 Existing
                                                 Existing
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
             *2-ISOPROPYLNAPHTHALEN
             *2-METHYLNAPHTHALENE
                                                 Existing
                                                 Existing
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
   SFF        *3,6-DIMETHYLPHENANTHR
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
             *ACENAPHTHENE
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
             *BENZOIC ACID
                                                 Existing
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                                4851
                                                   A-37
-------
Appendix A. Daily Effluent Data Listing (continued)
                                       117817      Existing
                                                                                                0.13031
                                                                                                0.05682
                                                                                                0.13764
                                                                                                0.10484
                                                                                                0.00999
                                                                                                0.01030
                                                                                                0.01059
                                                                                                0.01075
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.01000
                                                                                                0.01000
                                                                                                0.01000
             *CARBON BISULFIDE
             *CHLOROFORM
                                                                  788
             *DIBENZOTHIOPHENE
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
             *ETHYLBENZENE
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
                                                                 4851
             *N-HEXADECANE
                                                                                                0.00999
                                                                                                0. 00999
                                                                                                0.05499
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.01000
                                                                                                0.01000
                                                                                                0. 00999
                                                                                                0. 01030
                                                                                                0.01059
                                                                                                0.01615
                                                                                                0.00999
                                                                                                0.01632
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                                                                0.00999
                                                    A-38
-------
Appendix A. Daily Effluent Data Listing (continued)
             *N-HEXADECANE
                                                Existing
             *N-TETRADECANE
                                                Existing
             ^NAPHTHALENE
             *PHENANTHRENE
                                                Existing
                                                Existing
                                                Existing
6179
6179
6179
4471
4471
4471
4471
4737
4737
4737
4737
4737
4805
4805
4851
4851
4851
4851
4851
4876
4876
4876
4876
4876
4892
4892
4892
4892
4892
6179
6179
6179
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
4851
6179
6179
6179
4851
4851
4851
1
2
3
1
2
3
4
1
2
3
4
5
1
2
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
ND
ND
ND
NC
ND
NC
NC
ND
ND
ND
ND
ND
ND
ND
NC
NC
ND
NC
NC
ND
ND
ND
ND
ND
ND
ND
NC
ND
NC
ND
ND
ND
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
                                                                                             0.02350
                                                                                             0.00999
                                                                                             0.01591
                                                                                             0.05649
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0. 05499
                                                                                             0.00999
                                                                                             0. 00999
                                                                                             0.01000
                                                                                             0.01000
                                                                                             0.03607
                                                                                             0.01174
                                                                                             0.01059
                                                                                             0.02707
                                                                                             0.01386
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.00999
                                                                                             0.01000
                                                                                             0.01000
                                                                                             0.01399
                                                                                             0.01000
                                                                                             0.04196
                                                                                             0.01000
                                                                                             0.01000
                                                                                             0.01000
                                                   A-39
-------
Appendix A. Daily Effluent Data Listing (continued)
New Source or EPA
CAS Existing Source Sampling
Subcategory Analyte Number Trt. Option Episode
SFF *PYRENE 129000 Existing 4851
4851
SFF *TOLUENE 108883 Existing 4737
4737
4737
4737
4737
4851
4851
4851
4851
4851
SFF AMENABLE CYANIDE C025 4807
4807
4807
4807
4807
4817
4817
4817
4817
4828
4828
4828
4828
4828
4834
4834
4834
4834
4834
4847
4847
4847
4847
4904
4904
4904
4904
4904
6048
6048
6048
6048
6048
6186
6186
6186
6186
6186
SFF CADMIUM 7440439 Existing 1197A
1197A
4277
4277
4277
4277
4277
4415
4415
4415
4460
Sample
Day
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
1
2
3
4
5
1
2
3
4
5
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
2
3
1
2
3
4
5
2
3
4
1
NC/ND
ND
ND
ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
NC
NC
ND
NC
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
ND
NC
ND
ND
NC
NC
NC
NC
NC
NC
NC
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
NC
NC
Concentration
(mg/L)
0.01075
0.00999
0.00999
0. 00999
0.00999
1.17472
0. 69257
0.03442
0. 01968
0.01872
0. 01603
0.01840
0.01999
0. 01999
0. 01999
0.01999
0.01999
0. 57499
0.81000
0.20000
0. 57999
0. 03500
0.15999
0. 06300
0. 03799
0. 02400
0. 01999
0.01999
0.01999
0. 01999
0. 01999
0.00999
0.01049
0.00999
0. 00999
0. 16249
0.07349
0. 14300
0.13400
0. 08200
0.01999
0. 03700
0. 00499
0. 00499
0. 01400
0. 04899
0.02250
0. 01750
0.10999
0. 10999
0.07999
0. 06100
0.23000
0.20200
0. 07789
0. 14000
0.21899
0. 00499
0. 00499
0.00549
0. 02060
                                        A-40
-------
Appendix A. Daily Effluent Data Listing (continued)
  SFF      CADMIUM
1197A
1197A
1197A
4011
4011
4011
4079
4079
4079
4310
4310
4310
4330
4330
4330
4330
4330
4384
4384
4384
4384
4384
4415
4415
4415
4417
4417
4417
4417
4417
4438
4438
4438
4460
4460
4460
4470
4470
4470
4470
4470
4811
4811
4811
4811
4811
4817
4817
4817
4817
2
2
3
1
2
3
1
2
3
2
3
4
1
2
3
4
5
1
2
3
4
5
2
3
4
1
2
3
4
5
1
4
5
1
2
3
1
2
3
4
5
1
2
3
4
5
1
2
3
4
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
NC
NC
ND
NC
NC
NC
NC
0. 02700
0. 65600
1.23000
0.75599
0. 72600
1.13000
0. 63499
1.82000
0. 45600
0.39500
1. 77000
4. 65000
0. 06599
0.13112
0. 04343
0.05015
0. 04301
0. 60299
0.78549
0.53200
0. 59299
0.41100
0. 01480
0.01960
0. 11200
0.01989
0. 01329
0.02920
0. 00980
0.02160
0. 09899
0. 09099
0.08799
1.33000
1.21000
0. 98400
0. 10832
0.06859
0. 05547
0.08252
0. 07164
0.00800
0. 00800
0. 00965
0. 00910
0. 00800
0. 05759
0.03144
0. 08049
0.02170
                                         A-41
-------
Appendix A. Daily Effluent Data Listing (continued)
SFF CHROMIUM 7440473 Existing 4817
4833
4833
4833
4833
4833
4847
4847
4847
4847
4847
4871
4871
4871
4871
4871
4904
4904
4904
4904
4904
New 4807
4807
4807
4807
4807
4854
4854
4854
4854
4854
4882
4882
4882
4882
4882
SFF COPPER 7440508 Existing 4277
4277
4277
4277
4277
4737
4737
4737
4737
4737
4806
4806
4806
4806
4806
4807
4807
4807
4807
4807
4817
4817
4817
4817
4817
4833
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
NC
ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
0.27149
0. 03689
0.02814
0. 06750
0.08910
0. 11800
0. 37999
0.20100
0.19400
0.18999
0.54299
0.00999
0.01064
0.00999
0.00999
0.00999
0.01695
0. 01205
0.01059
0. 02190
0.01224
0.08500
0. 01540
0.03680
0. 02480
0.01700
0. 01425
0.01705
0. 01700
0.00980
0. 01195
0.01590
0. 03305
0. 08675
0. 09540
0. 46800
0.63800
0. 70099
0.61000
0. 46200
0.38499
0. 50690
0.03990
0. 02166
0.23477
0. 07300
1.07000
0.26499
0. 30099
0 92599
0.48399
1. 31500
1.43000
1. 36000
0.71499
0. 42649
0.19949
0. 14949
0.15399
0.25999
0.42849
0. 10999
                                        A-42
-------
Appendix A. Daily Effluent Data Listing (continued)
SFF COPPER 7440508 Existing 4833
4833
4833
4833
4834
4834
4834
4834
4834
4847
4847
4847
4847
4847
4904
4904
4904
4904
4904
New 4807
4807
4807
4807
4807
4854
4854
4854
4854
4854
4882
4882
4882
4882
4882
SFF CYANIDE 57125 4274
4274
4274
4279
4279
4279
4279
4279
4384
4384
4384
4384
4384
4460A
4807
4807
4807
4807
4807
4817
4817
4817
4817
4817
4828
4828
4828
4828

3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
2
3
4
1
2
3
4
5
1
2
3
4
5
2
1
2
3
4
5
1
2
3
4
5
1
2
3
4
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
NC
ND
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
NC
NC
ND
NC
ND
NC
NC
NC
NC
0. 12649
0. 09785
0.13150
0. 17550
0.07720
0. 04769
0.05189
0. 04540
0.07959
0. 11800
0.10000
0. 10300
0.03539
0. 04639
0. 03705
0.03999
0.03135
0. 04915
0. 07365
0.12700
0. 04160
0.04180
0. 06630
0.09290
0. 33050
0.03940
0. 00800
0.03405
0. 00800
0 . 06605
0. 02055
0.01680
0. 01240
0. 01265
0. 00999
0.00999
0.00999
0.00999
0. 00999
0.00999
0.00999
0.00999
0. 46299
0. 69400
0. 99199
0. 75800
0. 94499
0.01999
0. 02099
0. 02800
0. 04699
0.01999
0.01999
0. 57499
0.81000
0.20000
0.61000
0. 01999
0. 06199
0. 18000
0.09250
0.07599
                                        A-43
-------
Appendix A. Daily Effluent Data Listing (continued)
New Source or EPA
CAS Existing Source Sampling
Subcategory Analyte Number Trt. Option Episode
SFF CYANIDE 57125 4828
4834
4834
4834
4834
4834
4847
4847
4847
4847
4891
4891
4891
4891
4891
4904
4904
4904
4904
4904
6048
6048
6048
6048
6048
6186
6186
6186
6186
6186
SFF LEAD 7439921 Existing 1197A
1197A
1197A
4761
4761
4761
4762
4762
4762
4762
4762
4834
4834
4834
4834
4834
4871
4871
4871
4871
4871
SFF MANGANESE 7439965 Existing 4762
4762
4762
4762
4762
4807
4807
4807
4807
Sample
Day
5
1
2
3
4
5
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
2
2
3
1
2
3
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
NC/ND
NC
ND
ND
ND
ND
ND
NC
NC
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
NC
NC
ND
ND
ND
ND
ND
ND
ND
ND
NC
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
Concentration
(mg/L)
0. 04899
0.01999
0.01999
0. 01999
0. 01999
0.01999
0.01899
0. 01049
0. 00999
0.00999
0.07150
0. 04399
0.05600
0.10999
0.15999
0. 17499
0.11699
0. 32550
0. 30899
0. 35899
0. 17499
0. 30000
0.18999
0. 17000
0.20000
0. 12999
0.20000
0.20999
0.23999
0.20000
0.20000
4. 97000
0.46999
0.01200
0. 01200
0.01200
0. 02480
0.02480
0. 02480
0.02480
0. 02480
0.02439
0. 01600
0.01810
0. 01860
0.02559
0. 00870
0.01305
0. 01099
0. 00609
0. 00829
0. 16500
0.09690
0. 16799
0.13400
0. 12999
0.03015
0. 04670
0.03970
0. 07095
                                        A-44
-------
Appendix A. Daily Effluent Data Listing (continued)
                                                  Existing
                                                  Existing
                                                                 1197A
                                                                 1197A
                                                                 1197A
                                                                 4277
                                                                 4277
                                                                 4277
                                                                 4277
                                                                 4277
                                                                 4438
                                                                 4438
                                                                 4438
                                                                 4470
                                                                 4470
                                                                 4470
                                                                 4470
                                                                 4470
                                                                 4761
                                                                 4761
                                                                 4761
                                                                 4762
                                                                 4762
                                                                 4762
                                                                 4762
                                                                 4762
                                                                 4807
                                                                 4807
                                                                 4807
                                                                 4807
                                                                 4807
                                                                 4811
                                                                 4811
                                                                 4811
                                                                 4811
                                                                 4811
                                                                 4817
                                                                 4817
                                                                 4817
0.07100
1.39000
0.20900
0.17299
0.18000
0.16099
0.18000
0.19699
0.37799
0.51800
0. 34799
0.33860
0.22931
0.14263
0.22362
0.22212
0.22499
0.31900
0.25400
0.23199
0.12399
0.15800
0.21099
0.30399
0.28749
0.35400
0. 31949
0.21999
0. 13799
0.05665
0.05970
0.06340
0.03725
0.01799
0.02089
0.02844
0.02820
                                                    A-45
-------
Appendix A. Daily Effluent Data Listing (continued)
SFF NICKEL 7440020 Existing 4817
4817
4833
4833
4833
4833
4833
4834
4834
4834
4834
4834
4847
4847
4847
4847
4847
4871
4871
4871
4871
4871
4904
4904
4904
4904
4904
6048
6048
6048
6048
6048
New 4807
4807
4807
4807
4807
4854
4854
4854
4854
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
NC
NC
NC
ND
ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
0.04720
0. 04735
0.19200
0. 01600
0.01600
0. 01600
0. 01600
0.48399
0.31000
0.21600
0.21199
0. 43000
0.04320
0. 03109
0.02730
0. 06100
0. 10999
0. 69749
0.62050
0. 60199
0.53600
0. 80199
0. 02600
0. 02600
0.02600
0. 02600
0. 02600
0. 13500
0.51800
0.27000
0.28400
0. 52499
1. 58000
0.48000
0. 55000
0.54100
0. 60500
0.10100
0. 01705
0.01600
0. 01600
           OIL AND GREASE (AS HEM
                                          Existing
                                                                                 0.02165
                                            A-46
-------
Appendix A. Daily Effluent Data Listing (continued)
                                                 Existing
                                                 Existing
                                                                4737
                                                                4737
                                                                4737
                                                                4737
                                                                4737
                                                                4761
                                                                4761
                                                                4761
                                                                4762
                                                                4762
                                                                4762
                                                                4762
                                                                4762
                                                                4806
                                                                4806
                                                                4806
                                                                4806
                                                                4806
                                                                4807
                                                                4807
                                                                4807
                                                                4807
                                                                4807
                                                                4817
                                                                4817
                                                                4817
                                                                4817
                                                                4817
                                                                4833
                                                                4833
                                                                4833
106.50000
 71.50000
 71.50000
108.00000
 75.00000
 51.00000
 46.00000
 52.00000
172.00000
180.00000
182.00000
172.00000
147.00000
 29.30000
 12.90000
  9.30000
 37.00000
 20.40000
 16.20000
 23.65000
 27.45000
 10.25000
  8.90000
 16.40000
 17.40000
 21.60000
 25.70000
 31.75000
 10.00000
 12.00000
 34.00000
                                                    A-47
-------
Appendix A. Daily Effluent Data Listing (continued)
New Source or EPA
CAS Existing Source Sampling
Subcategory Analyte Number Trt. Option Episode
SFF TOTAL ORGANIC CARBON ( C012 Existing 4833
4833
4834
4834
4834
4834
4834
4871
4871
4871
4871
4871
4904
4904
4904
4904
4904
SFF TOTAL SUSPENDED SOLIDS C009 Existing 1197A
1197A
1197A
4011
4011
4011
4079
4079
4079
4277
4277
4277
4277
4277
4384
4384
4384
4384
4384
4415
4415
4415
4417
4417
4417
4417
4417
4438
4438
4438
4470
4470
4470
4470
4470
4737
4737
4737
4737
4737
4761
4761
4761
4762
4762
4762
Sample
Day
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5

2
3
1
2
3
1
2
3
1
2
3
4
5
1
2
3
4
5
2
3
4
1
2
3
4
5
1
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
NC/ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
ND
ND
ND
NC
NC
NC
NC
NC
NC
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
ND
ND
NC
NC
NC
NC
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
Concentration
(mg/L)
10.
10.
87.
7 7 .
90.
67.
42.
117.
86.
117.
90.
101.
10.
10.
10.
10.
10.
32.
20.
28.
22.
28.
30.
5.
5 .
9.
14.
14.
17.
10.
17.
23.
50.
32.
68.
55.
1.
1.
1.
12.
10.
7 ,
4.
2 .
7 ,
8 .
5 .
32.
10.
10.
22.
14.
12.
20.
14.
35.
38.
25.
24.
17.
14.
13.
16.
.00000
. 00000
.10000
. 90000
.70000
. 60000
.00000
. 50000
. 60000
. 00000
.80000
. 00000
.00000
. 00000
.00000
. 00000
.00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.50000
. 50000
.00000
. 50000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
                                        A-48
-------
Appendix A. Daily Effluent Data Listing (continued)
SFF TOTAL SUSPENDED SOLIDS C009 Existing 4762
4762
4807
4807
4807
4807
4807
4811
4811
4811
4811
4811
4817
4817
4817
4817
4817
4833
4833
4833
4833
4833
4834
4834
4834
4834
4834
4871
4871
4871
4871
4871
4904
4904
4904
4904
4904
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
NO
NO
NC
NO
NC
NC
ND
NC
ND
ND
NC
ND
ND
ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
NC
ND
NC
NC
NC
NC
NC
NC
ND
ND
NC
NC
16.
13.
6.
16.
7 .
8 .
4.
4.
4.
4.
4.
4.
8 .
4.
21.
18.
8 .
6.
7 .
17.
5.
5.
7 .
44.
4.
14.
4.
T
8 .
6.
4.
4.
4.
4.
4.
8.
7 .
. 00000
. 00000
. 00000
.00000
. 50000
. 00000
. 00000
.00000
. 00000
. 00000
. 00000
00000
00000
00000
00000
00000
00000
50000
00000
50000
50000
50000
00000
00000
00000
00000
00000
00000
00000
00000
00000
00000
50000
00000
00000
50000
50000
                                             Existing
                                                                                       0.04100
                                                                                       0.01999
                                                                                       0.02180
                                                                                       0.04690
                                                                                       0.04160
                                                                                       0.01260
                                                                                       0.01530
                                                                                       0.07039
                                                                                       0.05759
                                                                                       0.54100
                                                                                       0.15000
                                                                                       0.21299
                                                                                       0.17299
                                                                                       0.07779
                                                                                       0.21199
                                               A-49
-------
Appendix A. Daily Effluent Data Listing (continued)
New Source or EPA
CAS Existing Source Sampling
Subcategory Analyte Number Trt. Option Episode
SFF ZINC 7440666 Existing 4470
4470
4470
4470
4470
4737
4737
4737
4737
4737
4761
4761
4761
4762
4762
4762
4762
4762
4807
4807
4807
4807
4807
4811
4811
4811
4811
4811
4817
4817
4817
4817
4817
4871
4871
4871
4871
4871
4904
4904
4904
4904
4904
New 4807
4807
4807
4807
4807
4854
4854
4854
4854
4854
4882
4882
4882
4882
4882
Sample
Day
1
2
3
4
5
1
2
3
4
5
1
2
3
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
NC/ND
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
ND
NC
ND
ND
ND
NC
NC
NC
NC
ND
NC
NC
ND
ND
ND
NC
NC
NC
NC
ND
Concentration
(mg/L)
1.79270
1. 18100
0. 98581
1. 59270
1.35062
0. 38565
0. 09262
0. 06555
0.05569
0. 08816
0. 13600
0.20149
0. 14000
0. 26899
0. 16300
0.22400
0. 17299
0. 17499
0.13750
0. 16550
0.19400
0. 09745
0.05070
0. 05559
0.04684
0. 06289
0. 05214
0. 04729
0.44749
0. 30050
0.19599
0. 41100
0.30950
0.20350
0.21500
0. 13899
0. 12600
0. 14100
0.01499
0. 01844
0.01499
0. 01499
0.01499
0. 05760
0. 05840
0.03980
0. 04520
0.00020
0. 01965
0.01700
0. 00800
0. 00800
0. 00800
0.02840
0. 02955
0.06715
0. 04610
0.01100
                                        A-50
-------
Appendix B.  Effluent Data Summary Statistics
                                                             EPA          Number
                                                            Sampling  Sample   of
                                                            Episode   Size   NDs
                                               Existing
             TOTAL SUSPENDED SOLIDS
                                               Existing
                                                        B-l
-------
Appendix B. Effluent Data Summary Statistics (continued)
Subcategory  Analyte
                                                             EPA
                                                           Sampling
                                                            Episode
             OIL AND GREASE (AS HEM)     C036       Existing
             TOTAL SUSPENDED SOLIDS     0009       Existing
                                                                       5
                                                                       5
                                                                      10
                                                                       5
                                                                      12
                                                        B-2
-------
Appendix B.  Effluent Data Summary Statistics (continued)
Subcategory  Analyte
                                                                    EPA
                                                                 Sampling
                                                                  Episode
               *1,1-DICHLOROETHYLENE
                                         75354      Existing
               *1-METHYLFLUORENE
                                         1730376     Existing
               *1-METHYLPHENANTHRENE
                                                                   4805
                                                                   4851
                                                                  --ALL-
               *2-ISOPROPYLNAPHTHALENE     2027170     Existing
                                                                   4851
                                                                  --ALL-
               *2-METHYLNAPHTHALENE
               *3,6-DIMETHYLPHENANTHRENE   1576676     Existing
                                                                   4851
                                                                  --ALL-
                                         59507      Existing
                                                                   4876
                                                                  --ALL-
              *ACENAPHTHENE
                                                                   4851
                                                                  --ALL-
               *BENZOIC ACID
                                         65850      Existing
                                                                   4817
                                                                  --ALL-
                                         92524      Existing
                                                                   4851
                                                                  --ALL-
              *CARBON DISULFIDE
                                                    Existing
                                                    Existing
               *DIBENZOTHIOPHENE
                                                    Existing
                                                                   4851
                                                                  --ALL-
               *ETHYLBENZENE
                                                    Existing
                                                                   4851
                                                                  --ALL-
                                                              B-3
-------
Appendix B.  Effluent Data Summary Statistics (continued)
                                       86737     Existing        4851
                                                              —ALL--
              *N-HEXADECANE
                                       544763    Existing
              *N-TETRADECANE
                                       929594    Existing
                                                                              20
              *NAPHTHALENE
                                                Existing
                                                Existing
              *PHENANTHRENE
                                                Existing
                                                Existing
                                                               4851
                                                              —ALL--
                                                Existing
             AMENABLE CYANIDE
                                                                         5
                                                                         5
                                                                         10
                                                          B-4
-------
Appendix B. Effluent Data Summary Statistics (continued)
                                        7440473    Existing
                                                                            5
                                                                            5
                                                                            5
                                                                            5
                                                                            5
                                                                           71
0.
0.
0.
2 .
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
.6376
.8706
. 9703
.2716
. 0667
.5848
. 0488
.0187
. 0926
. 1746
. 0773
.0085
. 0925
.0679
. 3015
.0101
. 0147
.3438
0
0
0
1
0
0
0
0
0
1
0
0
0
0
0
0
0
0
. 65600
.75599
. 63499
.77000
. 05015
.59299
. 01960
.01989
. 09099
.21000
. 07164
.00800
. 05759
.06750
.20100
.00999
. 01224
. 07164
0.02700
0.72600
0.45600
0.39500
0.04301
0.41100
0.01480
0.00980
0.08799
0. 98400
0.05547
0.00800
0.02170
0.02814
0.18999
0.00999
0.01059
0.00800
1.
1.
1.
4.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
4.
.23000
.13000
. 82000
.65000
. 13112
.78549
. 11200
.02920
. 09899
.33000
. 10832
.00965
.27149
.11800
. 54299
.01064
. 02190
.65000
                                                  Existing
                                                                            5
                                                                           15
0
                                                                                               0.00999
                                                                                               0.00999
                                                                                                  5800
                                                                                               0.01999
                                                                                               0.02099
                                                                                               0.57499
                                                                                               0.07599
                                                                                               0.01999
                                                                                               0.01024
                                                                                               0.07150
                                                                                                 30899
                                                                                               0.18999
                                                                                               0.20000
                                                                                               0.07375
0
0 . 00999
0 . 00999
0.46299
0.01999
0.01999
0.01999
0.04899
0.01999
0.00999
0.04399
0.11699
0.17000
0.12999
0.00999
0.00999
0.00999
0.99199
0.01999
0.04699
0.81000
0.18000
0.01999
0.01899
0.15999
0.35899
0.30000
0.23999
0.99199
                                                  Existing
                                                            B-5
-------
Appendix B. Effluent Data Summary Statistics (continued)
                                              Existing
             MANGANESE
                                                            4807
                                                           —ALL--
                                                            4806
                                                            4904
                                                           --ALL--
o
0
0
0
0
0
0
1
0
4
0
0
0
5
0
10
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
. 5566
. 1781
. 4146
.2312
.2660
.2057
.2637
. 0470
.0344
. 0512
.3304
. 0545
.6515
. 0260
. 3464
.2292
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.20900
. 18000
.37799
.22362
.25400
.21099
.28749
. 05665
.02844
. 01600
.31000
. 04320
.62050
. 02600
.28400
. 19200
0.07100
0.16099
0.34799
0.14263
0.22499
0.12399
0.13799
0 . 01799
0.02089
0.01600
0.21199
0.02730
0.53600
0.02600
0.13500
0.01600
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
.39000
. 19699
.51800
. 33860
.31900
. 30399
.35400
. 06340
.04735
. 19200
.48399
. 10999
. 80199
. 02600
.52499
. 39000
             OIL AND GREASE (AS HEM)
                                     7440224    Existing
                                     7440315    Existing
                                                            4807
                                                           —ALL--
                                                                      5
                                                                      5
                                                                     10
                                                                      5
                                                                      5
                                                                      5
                                                                     18
                                                       B-6
-------
Appendix B.  Effluent Data Summary Statistics (continued)
Subcategory   Analyte
                                                                  4807
                                                                 --ALL--
              TOTAL SUSPENDED SOLIDS      C009       Existing
5 086.
3 0 49.
5 0 170.
5 021.
5 017.
5 0 22.
5 315.
5 073.
5 0 102.
5 5 10.
48 8 57.
3 026.
3 026.
3 2 6 .
5 014.
5 045.
3 3 1.
5 1 7.
3 0 6.
5 0 17.
5 024.
3 0 22.
5 014.
5 1 8.
5 3 4.
5 2 11.
5 0 8.
5 2 14.
5 0 5.
5 2 5.
83 16 14.
5 0 22.
5 4 4.
10 4 13.
. 5000
.6666
. 6000
.7800
.2900
.5700
.2000
. 0600
. 5800
. 0000
.2270
.6666
.6666
.3333
. 4000
. 6000
. 0000
. 0000
.6666
. 7000
. 0000
. 0000
. 4000
.3000
. 0000
.8000
. 4000
. 6000
. 8000
.7000
. 1747
. 0000
. 1000
.0500
75
51
172
20
16
21
10
7 7
101
10
35
28
28
5
14
50
1
T
7
14
20
24
14
T
4
8
6
~-i
6
4
10
23
4
8
. 00000
.00000
. 00000
.40000
.20000
.60000
. 00000
. 90000
. 00000
.00000
. 50000
.00000
. 00000
. 00000
. 00000
.00000
. 00000
.00000
. 00000
.50000
. 00000
.00000
. 00000
.50000
. 00000
.00000
. 50000
.00000
. 00000
.50000
. 00000
.00000
. 00000
.75000
71.
46.
147 .
9 .
8 .
16.
10.
42.
86.
10.
8 .
20 .
22 .
5.
10.
23 .
1.
2.
5.
10.
12 .
17.
13.
4 .
4 .
4 .
5.
4 .
4 .
4 .
1.
13.
4 .
4 .
.50000
.00000
.00000
.30000
. 90000
.40000
.00000
.00000
.60000
.00000
. 90000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.50000
.00000
.00000
.00000
.00000
.00000
.50000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
108.
52.
182.
37.
27.
31.
34.
90.
117.
10.
182.
32.
30.
9.
17.
68.
1.
12.
8.
32.
38.
25.
16.
16.
4.
21.
17.
44.
8.
8 .
68.
30.
4.
30.
. 00000
.00000
. 00000
.00000
. 45000
.75000
. 00000
.70000
. 50000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 50000
.00000
. 00000
.50000
. 00000
.00000
. 50000
.00000
                                                                                                0.03050
                                                                                                0.02180
                                                                                                0.07039
                                                                                                  17299
                                                                                                1.35062
                                                                                                0.08816
                                                                                                0.14000
                                                                                                  17499
                                                                                                0.13750
                                                                                                0.05214
                                                                                                  30950
                                                                                                0.14100
                                                                                                0.01499
                                                                                                0.13825
0
0
0
0 . 01999
0.01260
0.05759
0 . 07779
0.98581
0.05569
0.13600
0.16300
0.05070
0.04684
0.19599
0.12600
0.01499
0.01260
0.04100
0.04690
0.54100
0.21299
1.79270
0.38565
0.20149
0.26899
0.19400
0.06289
0. 44749
0.21500
0.01844
1.79270
                                                             B-7
-------
Appendix B. Effluent Data Summary Statistics (continued)
                                                         EPA
                                                      Sampling Sample
                                                       Episode  Size
                                                       —ALL--
                                                                 15
                                                    B-8
-------
Appendix B.  Effluent Data Summary Statistics (continued)
                                                                    EPA
                                                                 Sampling
                                                                  Episode
              *1,1-DICHLOROETHYLENE
                                         75354      Existing
              *1-METHYLFLUORENE
                                         1730376    Existing
              *1-METHYLPHENANTHRENE
                                                                   4805
                                                                   4851
                                                                  --ALL-
              *2-ISOPROPYLNAPHTHALENE     2027170    Existing
                                                                   4851
                                                                  --ALL-
              *2-METHYLNAPHTHALENE
               *3,6-DIMETHYLPHENANTHRENE   1576676    Existing
                                                                   4851
                                                                  --ALL-
                                         59507      Existing
                                                                   4876
                                                                  --ALL-
              *ACENAPHTHENE
                                                                   4851
                                                                  --ALL-
              *BENZOIC ACID
                                         65850      Existing
                                                                   4817
                                                                  --ALL-
                                         92524      Existing
                                                                   4851
                                                                  --ALL-
              *CARBON DISULFIDE
                                                   Existing
                                                   Existing
              *DIBENZOTHIOPHENE
                                                   Existing
                                                                   4851
                                                                  --ALL-
              *ETHYLBENZENE
                                                   Existing
                                                                   4851
                                                                  --ALL-
                                                              B-9
-------
Appendix B. Effluent Data Summary Statistics (continued)
                                                Existing
                                                               4851
                                                              —ALL--
              *N-HEXADECANE
                                       544763    Existing
              *N-TETRADECANE
                                       929594    Existing
                                                                              20
              *NAPHTHALENE
                                                Existing
                                                Existing
              *PHENANTHRENE
                                                Existing
                                                Existing
                                                               4851
                                                              --ALL-
                                                Existing
             AMENABLE  CYANIDE
                                                                          5
                                                                          5
                                                                         10
                                       7440473   Existing
                                                         B-10
-------
Appendix B.  Effluent Data Summary Statistics (continued)
                                      7440473    Existing
                                      7440508    Existing
                                                                                                               0.00999
                                                                                                               0.00999
                                                                                                               0.99199
                                                                                                               0.01999
                                                                                                               0.04699
                                                                                                               0. 81000
                                                                                                               0.18000
                                                                                                               0.01999
                                                                                                               0.01899
                                                                                                               0.15999
                                                                                                               0.35899
                                                                                                               0.30000
                                                                                                               0.23999
                                                                                                               0.99199
             MANGANESE
                                      7440224    Existing
                                                                         3
                                                                        11
                                      7440315    Existing
             TOTAL ORGANIC CARBON (TOC   C012      Existing
                                                         B-ll
-------
Appendix B.  Effluent Data Summary Statistics (continued)
                                                           EPA
                                                        Sampling  Sample
                                                         Episode   Size
                                            Existing
                                                         —ALL--
                                            Existing
                                                     B-12
-------
Appendix B.  Effluent Data Summary Statistics (continued)
Subcategory  Analyte
                                                                    EPA
                                                                 Sampling
                                                                  Episode
              *1,1-DICHLOROETHYLENE
                                         75354      Existing
              *1-METHYLFLUORENE
                                         1730376    Existing
              *1-METHYLPHENANTHRENE
                                                                   4805
                                                                   4851
                                                                  --ALL-
              *2-ISOPROPYLNAPHTHALENE     2027170    Existing
                                                                   4851
                                                                  --ALL-
              *2-METHYLNAPHTHALENE
               *3,6-DIMETHYLPHENANTHRENE   1576676    Existing
                                                                   4851
                                                                  --ALL-
                                         59507      Existing
                                                                   4876
                                                                  --ALL-
              *ACENAPHTHENE
                                                                   4851
                                                                  --ALL-
              *BENZOIC ACID
                                         65850      Existing
                                                                   4817
                                                                  --ALL-
                                         92524      Existing
                                                                   4851
                                                                  --ALL-
              *CARBON DISULFIDE
                                                   Existing
                                                   Existing
              *DIBENZOTHIOPHENE
                                                   Existing
                                                                   4851
                                                                  --ALL-
              *ETHYLBENZENE
                                                   Existing
                                                                   4851
                                                                  --ALL-
                                                             B-13
-------
Appendix B.  Effluent Data Summary Statistics (continued)
                                                                   EPA
                                                                Sampling
                                                                 Episode
                                                                  4851
                                                                 —ALL--
              *N-HEXADECANE
                                         544763     Existing
              *N-TETRADECANE
                                         929594     Existing
                                                                                  20
              *NAPHTHALENE
                                                   Existing
                                                   Existing
              *PHENANTHRENE
                                                   Existing
                                                   Existing
                                                                  4851
                                                                 --ALL-
                                                   Existing
              OIL AND GREASE  (AS HEM)     C036       Existing
                                                                  4737
                                                                  4851
                                                                 --ALL-
                                                                  4851
                                                                  4877
                                                                 --ALL-
 5
 5
10
                                                                             3
                                                                             5
                                                                             5
                                                                            18
                             202.00000  480.00000
                             131.00000  260.00000
                             313.00000 1270.00000
                             206.50000  329.00000
                             131.00000 1270.00000
              TOTAL SULFIDE
                                         1849625    Existing
              TOTAL SUSPENDED SOLIDS     C009       Existing
                                                            B-14
-------
Appendix B. Effluent Data Summary Statistics (continued)
            TOTAL SUSPENDED SOLIDS     0009     Existing       4876      5
                                                                4
                                                                21
                                                  B-15
-------
Appendix B.  Effluent Data Summary Statistics (continued)
                                                                    EPA
                                                                 Sampling
                                                                  Episode
              *1,1-DICHLOROETHYLENE
                                         75354      Existing
              *1-METHYLFLUORENE
                                         1730376    Existing
                                                                   4851
                                                                  --ALL-
              *1-METHYLPHENANTHRENE
                                                                   4805
                                                                   4851
                                                                  --ALL-
              *2-ISOPROPYLNAPHTHALENE     2027170    Existing
                                                                   4851
                                                                  --ALL-
              *2-METHYLNAPHTHALENE
               *3,6-DIMETHYLPHENANTHRENE   1576676    Existing
                                                                   4851
                                                                  --ALL-
                                         59507      Existing
                                                                   4876
                                                                  --ALL-
              *ACENAPHTHENE
                                                                   4851
                                                                  --ALL-
              *BENZOIC ACID
                                         65850      Existing
                                                                   4817
                                                                  --ALL-
                                         92524      Existing
                                                                   4851
                                                                  --ALL-
              *CARBON DISULFIDE
                                                   Existing
                                                   Existing
              *DIBENZOTHIOPHENE
                                                   Existing
              *ETHYLBENZENE
                                                   Existing
                                                                   4851
                                                                  --ALL-
                                                             B-16
-------
Appendix B.  Effluent Data Summary Statistics (continued)
                                       86737     Existing        4851
                                                              —ALL--
              *N-HEXADECANE
                                       544763    Existing
              *N-TETRADECANE
                                       929594    Existing
                                                                              20
              *NAPHTHALENE
                                                Existing
                                                Existing
              *PHENANTHRENE
                                                Existing
                                                Existing
                                                               4851
                                                              --ALL-
                                                Existing
             AMENABLE CYANIDE
                                                               4855
                                                              --ALL-
                                                         B-17
-------
Appendix B.  Effluent Data Summary Statistics (continued)
                                                                  EPA
                                                                Sampling
                                                                Episode
0
                                                                                                0.00999
                                                                                                0.00999
                                                                                                   5800
                                                                                                0.01999
                                                                                                0.02099
                                                                                                0.57499
                                                                                                0.07599
                                                                                                0.01999
                                                                                                0.01024
                                                                                                0.07150
                                                                                                  30899
                                                                                                0.18999
                                                                                                0.20000
                                                                                                0.07375
0
0 . 00999
0 . 00999
0.46299
0.01999
0.01999
0.01999
0.04899
0.01999
0.00999
0.04399
0.11699
0.17000
0.12999
0.00999
0.00999
0.00999
0.99199
0.01999
0.04699
0.81000
0.18000
0.01999
0.01899
0.15999
0.35899
0.30000
0.23999
0.99199
              MANGANESE
                                        7439965    Existing
                                        7440020    Existing
                                                                            5
                                                                            5
                                                                            10
                                        7440315    Existing
                                                                 4855
                                                                --ALL-
                                                            B-18
-------
Appendix B. Effluent Data Summary Statistics (continued)
             BOD 5-DAY  (CARBONACEOUS)   COOS      Existing
             OIL AND GREASE  (AS HEM)    C036      Existing
             TOTAL SUSPENDED SOLIDS     C009      Existing
                                                      B-19
-------
Appendix B.  Effluent Data Summary Statistics (continued)
                                                                    EPA
                                                                 Sampling
                                                                  Episode
              *1,1-DICHLOROETHYLENE
                                         75354      Existing
              *1-METHYLFLUORENE
                                         1730376    Existing
                                                                   4851
                                                                  --ALL-
              *1-METHYLPHENANTHRENE
                                                                   4805
                                                                   4851
                                                                  --ALL-
              *2-ISOPROPYLNAPHTHALENE     2027170    Existing
                                                                   4851
                                                                  --ALL-
              *2-METHYLNAPHTHALENE
               *3,6-DIMETHYLPHENANTHRENE   1576676    Existing
                                                                   4851
                                                                  --ALL-
                                         59507      Existing
                                                                   4876
                                                                  --ALL-
              *ACENAPHTHENE
                                                                   4851
                                                                  --ALL-
              *BENZOIC ACID
                                         65850      Existing
                                                                   4817
                                                                  --ALL-
                                         92524      Existing
                                                                   4851
                                                                  --ALL-
              *CARBON DISULFIDE
                                                   Existing
                                                   Existing
              *DIBENZOTHIOPHENE
                                                   Existing
              *ETHYLBENZENE
                                                   Existing
                                                                   4851
                                                                  --ALL-
                                                             B-20
-------
Appendix B.  Effluent Data Summary Statistics (continued)
                                      86737     Existing       4851
                                                              —ALL--
              *N-HEXADECANE
                                      544763     Existing
              *N-TETRADECANE
                                      929594     Existing
                                                                              20
              *NAPHTHALENE
                                                Existing
                                                Existing
              *PHENANTHRENE
                                                Existing
                                                Existing
                                                              4851
                                                              —ALL--
                                                Existing
             AMENABLE CYANIDE
                                                         B-21
-------
Appendix B. Effluent Data Summary Statistics (continued)
                                        7440473    Existing
                                                                            5
                                                                            5
                                                                            5
                                                                            5
                                                                            5
                                                                           71
0.
0.
0.
2 .
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
.6376
.8706
. 9703
.2716
. 0667
.5848
. 0488
.0187
. 0926
. 1746
. 0773
.0085
. 0925
.0679
. 3015
.0101
. 0147
.3438
0
0
0
1
0
0
0
0
0
1
0
0
0
0
0
0
0
0
. 65600
.75599
. 63499
.77000
. 05015
.59299
. 01960
.01989
. 09099
.21000
. 07164
.00800
. 05759
.06750
.20100
.00999
. 01224
.07164
0.02700
0.72600
0.45600
0.39500
0.04301
0.41100
0.01480
0.00980
0.08799
0. 98400
0.05547
0.00800
0.02170
0.02814
0.18999
0.00999
0.01059
0.00800
1.
1.
1.
4.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
4.
.23000
.13000
. 82000
.65000
. 13112
.78549
. 11200
.02920
. 09899
.33000
. 10832
.00965
.27149
.11800
. 54299
.01064
. 02190
.65000
                                                  Existing
                                                                            5
                                                                           15
0
                                                                                               0.00999
                                                                                               0.00999
                                                                                                  5800
                                                                                               0.01999
                                                                                               0.02099
                                                                                               0.57499
                                                                                               0.07599
                                                                                               0.01999
                                                                                               0.01024
                                                                                               0.07150
                                                                                                 30899
                                                                                               0.18999
                                                                                               0.20000
                                                                                               0.07375
0
0 . 00999
0 . 00999
0.46299
0.01999
0.01999
0.01999
0.04899
0.01999
0.00999
0.04399
0.11699
0.17000
0.12999
0.00999
0.00999
0.00999
0.99199
0.01999
0.04699
0.81000
0.18000
0.01999
0.01899
0.15999
0.35899
0.30000
0.23999
0.99199
                                                  Existing
                                                           B-22
-------
Appendix B. Effluent Data Summary Statistics (continued)
                                              Existing
             MANGANESE
                                                           4807
                                                          --ALL--
o
0
0
0
0
0
0
1
0
4
0
0
0
5
0
10
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
. 5566
. 1781
. 4146
.2312
.2660
.2057
.2637
. 0470
.0344
. 0512
.3304
. 0545
.6515
. 0260
. 3464
.2292
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.20900
. 18000
.37799
.22362
.25400
.21099
.28749
. 05665
.02844
. 01600
.31000
. 04320
.62050
. 02600
.28400
. 19200
0.07100
0.16099
0.34799
0.14263
0.22499
0.12399
0.13799
0 . 01799
0.02089
0.01600
0.21199
0.02730
0.53600
0.02600
0.13500
0.01600
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
.39000
. 19699
.51800
. 33860
.31900
. 30399
.35400
. 06340
.04735
. 19200
.48399
. 10999
. 80199
. 02600
.52499
. 39000
             OIL AND GREASE  (AS HEM)
                                    7440224    Existing
                                    7440315    Existing
                                                           4807
                                                          —ALL--
                                                                     5
                                                                     5
                                                                     5
                                                                    18
                                                      B-23
-------
Appendix B.  Effluent Data Summary Statistics (continued)
Subcategory   Analyte
                                                          4807
                                                         --ALL--
            TOTAL SUSPENDED SOLIDS      C009      Existing
5
3
5
5
5
5
5
5
5
5
48
3
3
3
5
5
3
5
3
5
5
3
5
5
5
5
5
5
5
5
83
5
5
10
2
5
3
5
5
5
3
5
5
5
5
5
5
58
0
0
0
0
0
o
3
0
0
5
8
0
0
2
0
0
3
1
0
0
0
0
0
1
3
2
0
2
0
2
16
0
4
4
1
0
0
0
0
0
0
0
0
0
0
0
4
5
86.
49.
170.
21.
17.
22 .
15.
73.
102.
10.
57 .
2 6 .
26.
6 .
14.
45.
1.
7 ,
6.
17.
24.
22 .
14.
8.
4.
11.
8.
14.
5 .
5.
14.
22
4.
13.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
. 5000
.6666
. 6000
.7800
.2900
.5700
.2000
. 0600
. 5800
.0000
.2270
.6666
.6666
.3333
. 4000
. 6000
. 0000
. 0000
.6666
. 7000
. 0000
. 0000
. 4000
.3000
. 0000
.8000
. 4000
. 6000
. 8000
.7000
. 1747
. 0000
. 1000
.0500
. 0305
.0276
.2229
. 1651
. 3805
.1375
. 1591
.2007
. 1290
.0529
. 3329
. 1649
. 0156
.2455
75
51
172
20
16
21
10
7 7
101
10
35
28
28
5
14
50
1
T
7
14
20
24
14
T
4
8
6
~-i
6
4
10
23
4
8
0
0
0
0
1
0
0
0
0
0
0
0
0
0
. 00000
.00000
. 00000
.40000
.20000
.60000
. 00000
. 90000
. 00000
.00000
. 50000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.50000
. 00000
.00000
. 00000
.50000
. 00000
.00000
. 50000
.00000
. 00000
.50000
. 00000
.00000
. 00000
.75000
. 03050
.02180
. 07039
.17299
. 35062
.08816
. 14000
.17499
. 13750
.05214
. 30950
.14100
. 01499
.13825
71.
46.
147 .
9 .
8 .
16.
10.
42.
86.
10.
8 .
20 .
22 .
5.
10.
23 .
1.
2.
5.
10.
12 .
17.
13.
4 .
4 .
4 .
5.
4 .
4 .
4 .
1.
13.
4 .
4 .
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
0.
0.
0.
0 .
.50000
.00000
.00000
.30000
. 90000
.40000
.00000
.00000
.60000
.00000
. 90000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.50000
.00000
.00000
.00000
.00000
.00000
.50000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
. 01999
.01260
.05759
.07779
. 98581
.05569
.13600
.16300
.05070
.04684
.19599
.12600
.01499
.01260
108.
52.
182.
37.
27.
31.
34.
90.
117.
10.
182.
32.
30.
9.
17.
68.
1.
12.
8.
32.
38.
25.
16.
16.
4.
21.
17.
44.
8.
8 .
68.
30.
4.
30.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
1.
. 00000
.00000
. 00000
.00000
. 45000
.75000
. 00000
.70000
. 50000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 00000
.00000
. 50000
.00000
. 00000
.50000
. 00000
.00000
. 50000
.00000
. 04100
. 04690
. 54100
.21299
. 79270
.38565
.20149
.26899
. 19400
.06289
. 44749
.21500
. 01844
.79270
                                                                    5
                                                                   15
                                                     B-24
-------
Appendix C. Facility-level Long-term Averages and Variability Factors
Subcat.
ANO
AND


ANO













ANO
ANO
ANO









Analyte New Source EPA
or Sampling
Existing Episode
Source Trt.
Option
ALUMINUM Existing 4856
4869
MANGANESE Existing 4762
4807
4871
4904
NICKEL Existing 1197A
4277
4438
4470
4761
4762
4807
4811
4817
4833
4834
4847
4871
4904
6048
OIL AND GREASE (AS HEM) Existing 4737
4871
TOTAL SUSPENDED SOLIDS Existing 4856
4869
ZINC Existing 1197A
4277
4415
4417
4470
4737
4761
4762
4807
4811
4817
4871
4904
Episode Sample Number
Subcat. Size of
Nds
ANO 5 0
ANO 5 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 3 0
GENL 5 0
GENL 3 0
GENL 5 0
GENL 3 0
GENL 5 0
GENL 5 0
GENL 5 1
GENL 5 0
GENL 5 4
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 5
GENL 5 0
GENL 5 0
GENL 5 5
ANO 5 0
ANO 5 2
GENL 2 1
GENL 5 0
GENL 3 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 3 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 4
Mean Long-term
Detection Average*
Limit
3
1
0
0
0
0
0
0
0
0
0
0
0
0. 01799 0
0
0.01600 0
0
0
0
0.02600 0
0
13
6.13633 6
4.00000 16
0.01999 0
0
0
0
1
0
0
0
0
0
0
0
0.01499 0
.37400
.66350
.13878
.04963
.09170
.01327
.55667
.17819
.41466
.23126
.26600
.20579
.26379
.04700
.03442
.05120
.33040
.05452
.65159
.02600
.34640
.60000
.13633
.60000
.40000
.03050
.02764
.22299
.16515
.38057
.13753
.15916
.20079
.12903
.05295
qqogO
.16490
.01568
Daily
VF
1.
4.
1.
1.
2'
1.

1.

2.
2 .
1.
2 .

2 .
3 .
1.

3.
1.
1.
6 .
3 .

2.
1.
4.

1.
3.
1.
1.

. 98
. 48
. 64
.08
. 35
.22
. 18

. 95

. 11
.24
. 93
. 16

.26
. 16
.41

.15
.51
. 74
. 92
. 30

. 41
.69
. 45

. 60
.00
. 32
. 02
. 71

4-day
VF
1.29
1. 85
1.20
1.31
1. 11
1.35
1. 06

1.28

1. 32
1.35
1. 36
1.33

1.35
1. 56
1.13

1.56
1.16
1.22
2.38
1. 59

1. 39
1.21
1. 84

1. 19
1.53
1. 10
1.29
1.22

* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                     C-l
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
                                              EPA     Episode   Sample   Number      Mean       Long-term       Daily    4-day
                                            Sampling   Subcat.    Size      of      Detection    Average*         VF     VF
                                            Episode                     Nds      Limit
          OIL AND GREASE (AS  HEM)    Existing  4891        DRYD      5       3        5.48333      6.22000      1.71      1.19
                                                        DRYD      5       0         .          11.76667      1.82      1.25

          TOTAL  SUSPENDED SOLIDS     Existing  4805        DRYD      2       0
                                                        DRYD      5       0
* Cases where LTA is missing and VF is not indicate only VF transfer.
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat.
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL

6ENL
6ENL
6ENL
6ENL

6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL


6ENL


6ENL
6ENL
6ENL
6ENL
Analyte New Source
or
Existing
Source Trt.
Option
*1,1-DICHLOROETHYLENE
*1,1-DICHLOROETHYLENE
*1-METHYLFLUORENE
*1-METHYLFLUORENE
*1-METHYLPHENANTHRENE
*1-METHYLPHENANTHRENE

*2-ISOPROPYLNAPHTHALENE
*2-ISOPROPYLNAPHTHALENE
*2 -METHYLNAPHTHALENE
*2 -METHYLNAPHTHALENE

*3,6-DIMETHYLPHENANTHRENE
*3,6-DIMETHYLPHENANTHRENE
*4-CHLORO-M-CRESOL
*4-CHLORO-M-CRESOL
*ACENAPHTHENE
*ACENAPHTHENE
*BENZOIC ACID
*BENZOIC ACID
*BIPHENYL
*BIPHENYL
*BIS (2-ETHYLHEXYL) PHTHAL


*BIS (2-ETHYLHEXYL) PHTHAL


*CARBON DISULFIDE
*CARBON DISULFIDE
*CHLOROFORM
*CHLOROFORM
Existing
New
Existing
New
Existing
New

Existing
New
Existing
New

Existing
New
Existing
New
Existing
New
Existing
New
Existing
New
Existing


New


Existing
New
Existing
New
EPA
Sampling
Episode
4737
4737
4851
4851
4805
4851
4805
4851
4851
4851
4851
6179
4851
6179
4851
4851
4876
4876
4851
4851
4817
4817
4851
4851
4471
4851
4876
6179
4471
4851
4876
6179
4867
4867
4788
4788
Episode Sample Number
Subcat. Size of
Nds
6ENL 5 5
6ENL 5 5
OILY 5 5
OILY 5 5
DRYD 2 2
OILY 5 5
DRYD 2 2
OILY 5 5
OILY 5 5
OILY 5 5
OILY 5 0
RRL 3 3
OILY 5 0
RRL 3 3
OILY 5 5
OILY 5 5
OILY 5 0
OILY 5 0
OILY 5 5
OILY 5 5
6ENL 4 1
6ENL 4 1
OILY 5 2
OILY 5 2
OILY 4 0
OILY 5 5
OILY 5 5
RRL 3 3
OILY 4 0
OILY 5 5
OILY 5 5
RRL 3 3
PWB 5 0
PWB 5 0
MFJ 3 0
MFJ 3 0
Mean
Detection
Limit
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.

0.
0.
0.


0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.




00999
00999
01032
01032
01000
01032
01000
01032
01032
01032
01000

01000
01032
01032


01032
01032
05000
05000
00999
00999
01032
00999
01000
01032
00999
01000




Long-term
Average*
0.00999
0.00999
0.01032
0.01032
0.01000
0.01032
0.01000
0.01032
0.01032
0.01032
0.04864
0.01000
0.04864
0.01000
0.01032
0.01032
0.52609
0.52609
0.01032
0.01032
0.30052
0.30052
0.01239
0.01239
0.10740
0.01032
0.00999
0.01000
0.10740
0.01032
0 . 00999
0.01000
0.74799
0.74799
0.19603
0.19603
Daily 4-day
VF VF









1.80 1.24
1.80 1.24



6.55 2.31
6.55 2.31


7.59 2.53
7.59 2.53
1.36 1.15
1.36 1.15
2.36 1.38


2. 36 1. 38


4.55 1.87
4.55 1.87


* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                    C-3
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat.
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL





6ENL






6ENL





6ENL






6ENL
6ENL
6ENL
6ENL
6ENL
6ENL

6ENL
6ENL
Analyte
*DIBENZOTHIOPHENE
*DIBENZOTHIOPHENE
*ETHYLBENZENE
*ETHYLBENZENE
*FLUORENE
*FLUORENE
*N-HEXADECANE





*N-HEXADECANE






*N-TETRADECANE





*N-TETRADECANE






*NAPHTHALENE
*NAPHTHALENE
*P-CYMENE
*P-CYMENE
*PHENANTHRENE
*PHENANTHRENE

*PYRENE
*PYRENE
New Source
or
Existing
Source Trt.
Option
Existing
New
Existing
New
Existing
New
Existing





New






Existing





New






Existing
New
Existing
New
Existing
New

Existing
New
EPA
Sampling
Episode
4851
4851
4851
4851
4851
4851
4737
4805
4851
4872
4876
4877
6179
4737
4805
4851
4872
4876
4877
6179
4471
4737
4805
4851
4876
4892
6179
4471
4737
4805
4851
4876
4892
6179
4851
4851
4851
4851
4851
6179
4851
6179
4851
4851
Episode Sample Number
Subcat. Size of
Nds
OILY 5 5
OILY 5 5
OILY 5 4
OILY 5 4
OILY 5 5
OILY 5 5
6ENL 5 5
DRYD 2 2
OILY 5 4
OILY 3 2
OILY 5 5
OILY 5 4
RRL 3 3
6ENL 5 5
DRYD 2 2
OILY 5 4
OILY 3 2
OILY 5 5
OILY 5 4
RRL 3 3
OILY 4 1
6ENL 5 5
DRYD 2 2
OILY 5 1
OILY 5 5
DRYD 5 3
RRL 3 3
OILY 4 1
6ENL 5 5
DRYD 2 2
OILY 5 1
OILY 5 5
DRYD 5 3
RRL 3 3
OILY 5 0
OILY 5 0
OILY 5 5
OILY 5 5
OILY 5 5
RRL 3 3
OILY 5 5
RRL 3 3
OILY 5 5
OILY 5 5
Mean
Detection
Limit
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.


0.
0.
0.
0.
0.
0.
0.
0.
01032
01032
00999
00999
01032
01032
01899
01000
01022
00999
00999
00999
01000
01899
01000
01022
00999
00999
00999
01000
00999
01899
01000
01059
00999
01000
01000
00999
01899
01000
01059
00999
01000
01000


01032
01032
01032
01000
01032
01000
01032
01032
Long-term
Average*
0.01032
0.01032
0.01032
0.01032
0.01032
0.01032
0.01899
0.01000
0.01140
0.01210
0.00999
0.01098
0.01000
0.01899
0.01000
0.01140
0.01210
0.00999
0.01098
0.01000
0.02647
0.01899
0.01000
0.01987
0.00999
0.01719
0.01000
0.02647
0.01899
0.01000
0.01987
0.00999
0.01719
0.01000
0.04658
0.04658
0.01032
0.01032
0.01032
0.01000
0.01032
0.01000
0.01032
0.01032
Daily 4-day
VF VF



















4.15 1.80

3.22 1. 58

5.81 2. 10

4.15 1.80


3.22 1. 58

5.81 2. 10

1.92 1.27
1.92 1.27







* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                    C-4
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat . Analyte




New Source
or
Existing
Source Trt.
Option
EPA
Sampling
Episode


Episode
Subcat .



Sample
Size



Number
of
Nds


Mean
Detection
Limit


Long-term
Average*



Daily
VF



4-day
VF



 6ENL      *TOLUENE
                                    Existing  4737
                                             4851
6ENL
OILY
 6ENL      *TOLUENE
 6ENL      AMENABLE CYANIDE
6ENL
OILY

6ENL
6ENL
MFJ
6ENL
6ENL
6ENL
6ENL
MFJ
 6ENL

 6ENL
 6ENL      COPPER
                                    Existing  4277
                                             4737
                                             4806
                                             4807
                                             4817
                                             4833
                                             4834
                                             4847
 6ENL      COPPER
 6ENL      CYANIDE
                                                         6ENL
                                                         6ENL
                                                         6ENL
                                                         6ENL
                                                         6ENL

                                                         6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
MFJ
3
3
3
3
5
5
3
5
3
3
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
3
5
                                                                                                0.63767
                                                                                                0.87066
                                                                                                0.97033
                                                                                                2.27167
                                                                                                0.06674
                                                                                                0.58489
                                                                                                0.04880
                                                                                                0.01876
                                                                                                0.09266
                                                                                                1.17467
                                                                                                0.07731
                                                                                                0.00855
                                                                                                0.09254
                                                                                                0.06793
                                                                                                0.30159
                                                                                                0.01012
                                                                                                0.01475
                                                            1. 43


                                                            1. 12

                                                            1.25
                                                            1. 45
                                                            1.21
                                                                                                                      1. 74
                                                                                                                      1.21
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                           C-5
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
                                                EPA
                                     or       Sampling
                                  Existing    Episode
                                 Source Trt.
                                   Option
                                                                           Mean
                                                                        Detection
                                                                          Limit
                                                    Daily
                                                      VF
4-day
VF
                                                           6ENL
                                                           6ENL
                                                           6ENL
                                                           6ENL
                                                           MFJ
                                                           6ENL
                                                           6ENL
                                                           DRYD
                                                           6ENL
                                                           6ENL
                                                           MFJ
 6ENL

 6ENL
LEAD

MANGANESE
6ENL
6ENL
6ENL
6ENL
6ENL

PWB

6ENL
6ENL
6ENL
6ENL
 6ENL

 6ENL
                                              4807
                                                           6ENL
                                                           6ENL
                                                           6ENL
                                                                                                              1. 49
                                                                                                              1.11
 6ENL
          MOLYBDENUM
                                                           6ENL
                                                           6ENL
                                     Existing
           OIL AND GREASE (AS HEM)
                                     Exis
                                     Exis
                                              4807
                                              4854
                                              4807
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL

                                                GENL
                                                GENL

                                                GENL
                                                GENL

                                                GENL
                                                GENL
                                                GENL
                                                GENL

                                                GENL
                                                                                                  0.55667
                                                                                                  0.17819
                                                                                                  0.41466
                                                                                                  0.23126
                                                                                                  0.26600
                                                                                                  0.20579
                                                                                                  0.26379
                                                                                                  0.04700
                                                                                                  0.03442
                                                                                                  0.05120
                                                                                                  0.33040
                                                                                                  0.05452
                                                                                                  0.65159
                                                                                                  0.02600
                                                                                                  0.34640
                                                                                                               1.51
                                                                                                                        1.16
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                            C-6
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat.
6ENL
6ENL

6ENL








6ENL








6ENL
6ENL
6ENL

















6ENL

6ENL




Analyte New Source EPA
or Sampling
Existing Episode
Source Trt.
Option
TIN Existing 4817
4834
TIN New 4807
4855
TOTAL ORGANIC CARBON ( TOC Existing 4737
4761
4762
4806
4807
4817
4833
4834
4871
4904
TOTAL ORGANIC CARBON (TOC New 4737
4761
4762
4806
4807
4817
4833
4834
4871
4904
TOTAL SULFIDE Existing 4877
TOTAL SULFIDE New 4877
TOTAL SUSPENDED SOLIDS Existing 1197A
4011
4079
4277
4384
4415
4417
4438
4470
4737
4761
4762
4807
4811
4817
4833
4834
4871
4904
TOTAL SUSPENDED SOLIDS New 4807
4882
ZINC Existing 1197A
4277
4415
4417
4470
4737
Episode Sample Number
Subcat. Size of
Nds
GENL 5 0
GENL 5 0
GENL 5 5
PWB 5 0
GENL 5 0
GENL 3 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 3
GENL 5 0
GENL 5 0
GENL 5 5
GENL 5 0
GENL 3 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 3
GENL 5 0
GENL 5 0
GENL 5 5
OILY 5 0
OILY 5 0
GENL 3 0
GENL 3 0
GENL 3 2
GENL 5 0
GENL 5 0
GENL 3 3
GENL 5 1
GENL 3 0
GENL 5 0
GENL 5 0
GENL 3 0
GENL 5 0
GENL 5 1
GENL 5 3
GENL 5 2
GENL 5 0
GENL 5 2
GENL 5 0
GENL 5 2
GENL 5 0
GENL 5 4
GENL 2 1
GENL 5 0
GENL 3 0
GENL 5 0
GENL 5 0
GENL 5 0
Mean Long-term
Detection Average*
Limit
0
0
0.01840 0

86
4 9
170
21
17
22
10.00000 15
7 3
102
10.00000 10
86
49
170
21
17
22
10.00000 15
73
102
10.00000 10
7
7
26
26
5.00000 6
14
45
1.00000 1
2.00000 7
6
17
24
22
14
4.00000 8
4.00000 4
6.00000 11
8
4.00000 14
5
4.00000 5
22
4.00000 4
0.01999 0
0
0
0
1
0
.05998
.81520
.01840

.50000
. 66667
.60000
. 78000
.29000
.57000
.20000
.06000
.58000
.00000
.50000
.66667
.60000
.78000
.29000
.57000
.20000
.06000
.58000
.00000
.10000
.10000
.66667
. 66667
.33333
.40000
.60000
.00000
.00000
. 66667
.70000
.00000
.00000
.40000
.30000
.00000
.80000
.40000
.60000
.80000
.70000
.00000
.10000
.03050
.02764
.22299
.16515
.38057
.13753
Daily
VF
3.
2.

1.
1.
1.
3 .
2 .
1.
5.
1.
1.

1.
1.
3.
2.
1.
5 .
1.
1.

4.
4.


1.
2 .

3.

2 .
2.

1.
2 .

3.
2.
7 ,
2.
2'
2.

3.

2 .
1.
4.
.85
. 14

.58
.61
.22
.20
.80
. 82
.15
. 97
. 37

. 61
.22
.20
. 80
.82
. 15
. 97
. 37

.25
.25


. 62
. 52

.11

.87
. 84

. 27
. 67

.54
. 74
.06
. 00
.33
.10

. 30

.41
. 69
.45
4-day
VF
1.72
1. 32

1.18
1.19
1.07
1. 57
1.48
1.24
1. 95
1.28
1.12

1. 19
1. 07
1.57
1. 48
1.24
1. 95
1.28
1. 12

1.80
1. 80


1. 19
1.42

1. 60

1.50
1. 49

1. 09
1.47

1.67
1. 47
2.40
1.29
1.37
1.31

1.59

1.39
1.21
1. 84
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                    C-7
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat . Analyte




New Source
or
Existing
Source Trt.
Option
EPA
Sampling
Episode


Episode
Subcat .



Sample
Size



Number
of
Nds


Mean
Detection
Limit


Long-term
Average*



Daily
VF



4-day
VF



                                 Existing
                                                     6ENL
                                                     6ENL
                                                     6ENL
                                                     6ENL
                                                     6ENL
                                                     6ENL
                                                     6ENL

                                                     6ENL
                                                     6ENL
                                                     6ENL
* Cases where LTA is missing and VF is not indicate only VF transfer.
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat.
MFJ
MFJ
MFJ
MFJ
MFJ
MFJ

MFJ
MFJ
MFJ
MFJ

MFJ
MFJ
MFJ
MFJ
MFJ
MFJ
MFJ
MFJ
MFJ
MFJ
MFJ


MFJ


MFJ
MFJ
MFJ
MFJ
Analyte New Source
or
Existing
Source Trt.
Option
*1,1-DICHLOROETHYLENE
*1,1-DICHLOROETHYLENE
*1-METHYLFLUORENE
*1-METHYLFLUORENE
*1-METHYLPHENANTHRENE
*1-METHYLPHENANTHRENE

*2-ISOPROPYLNAPHTHALENE
*2-ISOPROPYLNAPHTHALENE
*2 -METHYLNAPHTHALENE
*2 -METHYLNAPHTHALENE

*3,6-DIMETHYLPHENANTHRENE
*3,6-DIMETHYLPHENANTHRENE
*4-CHLORO-M-CRESOL
*4-CHLORO-M-CRESOL
*ACENAPHTHENE
*ACENAPHTHENE
*BENZOIC ACID
*BENZOIC ACID
*BIPHENYL
*BIPHENYL
*BIS (2-ETHYLHEXYL) PHTHAL


*BIS (2-ETHYLHEXYL) PHTHAL


*CARBON DISULFIDE
*CARBON DISULFIDE
*CHLOROFORM
*CHLOROFORM
Existing
New
Existing
New
Existing
New

Existing
New
Existing
New

Existing
New
Existing
New
Existing
New
Existing
New
Existing
New
Existing


New


Existing
New
Existing
New
EPA
Sampling
Episode
4737
4737
4851
4851
4805
4851
4805
4851
4851
4851
4851
6179
4851
6179
4851
4851
4876
4876
4851
4851
4817
4817
4851
4851
4471
4851
4876
6179
4471
4851
4876
6179
4867
4867
4788
4788
Episode Sample Number
Subcat. Size of
Nds
6ENL 5 5
6ENL 5 5
OILY 5 5
OILY 5 5
DRYD 2 2
OILY 5 5
DRYD 2 2
OILY 5 5
OILY 5 5
OILY 5 5
OILY 5 0
RRL 3 3
OILY 5 0
RRL 3 3
OILY 5 5
OILY 5 5
OILY 5 0
OILY 5 0
OILY 5 5
OILY 5 5
6ENL 4 1
6ENL 4 1
OILY 5 2
OILY 5 2
OILY 4 0
OILY 5 5
OILY 5 5
RRL 3 3
OILY 4 0
OILY 5 5
OILY 5 5
RRL 3 3
PWB 5 0
PWB 5 0
MFJ 3 0
MFJ 3 0
Mean
Detection
Limit
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.

0.
0.
0.


0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.




00999
00999
01032
01032
01000
01032
01000
01032
01032
01032
01000

01000
01032
01032


01032
01032
05000
05000
00999
00999
01032
00999
01000
01032
00999
01000




Long-term
Average*
0.00999
0.00999
0.01032
0.01032
0.01000
0.01032
0.01000
0.01032
0.01032
0.01032
0.04864
0.01000
0.04864
0.01000
0.01032
0.01032
0.52609
0.52609
0.01032
0.01032
0.30052
0.30052
0.01239
0.01239
0.10740
0.01032
0.00999
0.01000
0.10740
0.01032
0 . 00999
0.01000
0.74799
0.74799
0.19603
0.19603
Daily 4-day
VF VF









1.80 1.24
1.80 1.24



6.55 2.31
6.55 2.31


7.59 2.53
7.59 2.53
1.36 1.15
1.36 1.15
2.36 1.38


2. 36 1. 38


4.55 1.87
4.55 1.87


* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                    C-9
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat.
MFJ
MFJ
MFJ
MFJ
MFJ
MFJ
MFJ





MFJ






MFJ





MFJ






MFJ
MFJ
MFJ
MFJ
MFJ
MFJ

MFJ
MFJ
Analyte
*DIBENZOTHIOPHENE
*DIBENZOTHIOPHENE
*ETHYLBENZENE
*ETHYLBENZENE
*FLUORENE
*FLUORENE
*N-HEXADECANE





*N-HEXADECANE






*N-TETRADECANE





*N-TETRADECANE






*NAPHTHALENE
*NAPHTHALENE
*P-CYMENE
*P-CYMENE
*PHENANTHRENE
*PHENANTHRENE

*PYRENE
*PYRENE
New Source
or
Existing
Source Trt.
Option
Existing
New
Existing
New
Existing
New
Existing





New






Existing





New






Existing
New
Existing
New
Existing
New

Existing
New
EPA
Sampling
Episode
4851
4851
4851
4851
4851
4851
4737
4805
4851
4872
4876
4877
6179
4737
4805
4851
4872
4876
4877
6179
4471
4737
4805
4851
4876
4892
6179
4471
4737
4805
4851
4876
4892
6179
4851
4851
4851
4851
4851
6179
4851
6179
4851
4851
Episode Sample Number
Subcat. Size of
Nds
OILY 5 5
OILY 5 5
OILY 5 4
OILY 5 4
OILY 5 5
OILY 5 5
6ENL 5 5
DRYD 2 2
OILY 5 4
OILY 3 2
OILY 5 5
OILY 5 4
RRL 3 3
6ENL 5 5
DRYD 2 2
OILY 5 4
OILY 3 2
OILY 5 5
OILY 5 4
RRL 3 3
OILY 4 1
6ENL 5 5
DRYD 2 2
OILY 5 1
OILY 5 5
DRYD 5 3
RRL 3 3
OILY 4 1
6ENL 5 5
DRYD 2 2
OILY 5 1
OILY 5 5
DRYD 5 3
RRL 3 3
OILY 5 0
OILY 5 0
OILY 5 5
OILY 5 5
OILY 5 5
RRL 3 3
OILY 5 5
RRL 3 3
OILY 5 5
OILY 5 5
Mean
Detection
Limit
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.


0.
0.
0.
0.
0.
0.
0.
0.
01032
01032
00999
00999
01032
01032
01899
01000
01022
00999
00999
00999
01000
01899
01000
01022
00999
00999
00999
01000
00999
01899
01000
01059
00999
01000
01000
00999
01899
01000
01059
00999
01000
01000


01032
01032
01032
01000
01032
01000
01032
01032
Long-term
Average*
0.01032
0.01032
0.01032
0.01032
0.01032
0.01032
0.01899
0.01000
0.01140
0.01210
0.00999
0.01098
0.01000
0.01899
0.01000
0.01140
0.01210
0.00999
0.01098
0.01000
0.02647
0.01899
0.01000
0.01987
0.00999
0.01719
0.01000
0.02647
0.01899
0.01000
0.01987
0.00999
0.01719
0.01000
0.04658
0.04658
0.01032
0.01032
0.01032
0.01000
0.01032
0.01000
0.01032
0.01032
Daily 4-day
VF VF



















4.15 1.80

3.22 1. 58

5.81 2. 10

4.15 1.80


3.22 1. 58

5.81 2. 10

1.92 1.27
1.92 1.27







* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                   C-10
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat . Analyte




New Source
or
Existing
Source Trt.
Option
EPA
Sampling
Episode


Episode
Subcat .



Sample
Size



Number
of
Nds


Mean
Detection
Limit


Long-term
Average*



Daily
VF



4-day
VF



                                   Existing  4737
                                            4851
6ENL
OILY
                                                        6ENL
                                                        OILY
 MFJ       AMENABLE CYANIDE
                                                        6ENL
                                                        6ENL
                                                        MFJ
                                                        6ENL
                                                        6ENL
                                                        6ENL
                                                        6ENL
                                                        MFJ
                                                       MFJ
                                                       MFJ
                                                       MFJ
                                                       MFJ
 MFJ

 MFJ
6ENL

MFJ
MFJ
MFJ
MFJ
MFJ
MFJ
                                                        6ENL
                                                        6ENL
                                                        6ENL
                                                          1. 74
                                                          1.21
                                                       MFJ
                                                       MFJ
                                                       MFJ
                                                       MFJ
                                                       MFJ
                                                       MFJ
 MFJ       COPPER
                                                        6ENL
                                                        6ENL
                                                        6ENL
 MFJ       CYANIDE
 MFJ       LEAD
                                   Existing
6ENL
MFJ
6ENL
6ENL
6ENL
6ENL
MFJ
6ENL
6ENL
DRYD
6ENL
6ENL
MFJ

MFJ
MFJ
MFJ
                                                                                                         1.73
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                        C-ll
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
                                               EPA
                                             Sampling
                                             Episode
                                                       Episode   Sample
                                                                of
                                                                Nds
                        Detection
                          Limit
                                                                                                   Daily
                                                                                                    VF
                                                            4-day
                                                            VF
 MFJ

 MFJ
 MFJ

 MFJ


 MFJ
 MFJ

 MFJ

 MFJ

 MFJ

 MFJ


 MFJ
LEAD

MANGANESE
          NICKEL
                         New

                         Existing


                         New


                         Existing
                                    New
                                             4807
                                             4807
                                             4854
          OIL AND GREASE  (AS HEM)     New


                                    Existing
SILVER

TIN

TIN


TOTAL ORGANIC CARBON (TOC  Existing

TOTAL ORGANIC CARBON (TOC  New

TOTAL SULFIDE              Existing

TOTAL SULFIDE              New

TOTAL SUSPENDED SOLIDS      New


                          Existing
PWB

MFJ
MFJ
MFJ
MFJ

GENL

GENL
GENL

GENL
GENL

MFJ
MFJ
MFJ
MFJ
MFJ

GENL
GENL

GENL
GENL

MFJ
MFJ
MFJ

GENL
                                                          GENL
                                                          PWB
GENL
GENL

MFJ
MFJ
MFJ
MFJ
MFJ
MFJ
MFJ
MFJ

GENL
GENL
GENL
                                                                                                             1.51
1. 49
1.11
                                                                                                                      1.49
                                                                                                                      1. 11
                                                                                                                      1.16
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                           C-12
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
                                  New
                                                 EPA
                                      or       Sampling
                                   Existing     Episode
                                 Source Trt.
                                    Option
                                                         Episode  Sample
                                                                  of
                                                                 Nds
                                               Detection
                                                 Limit
                                                                                                                Daily    4-day
                                                                                                                  VF      VF
 OILY

 OILY

 OILY


 OILY

 OILY


 OILY

 OILY

 OILY

 OILY

 OILY

 OILY




 OILY

 OILY

 OILY

 OILY

 OILY

 OILY
 OILY

 OILY

 OILY


 OILY
*1,1-DICHLOROETHYLENE      Existing

*1-METHYLFLUORENE          Existing

*1-METHYLPHENANTHRENE      Existing


*2-ISOPROPYLNAPHTHALENE

*2-METHYLNAPHTHALENE


*3,6-DIMETHYLPHENANTHRENE

*4-CHLORO-M-CRESOL

*ACENAPHTHENE

*BENZOIC  ACID

*BIPHENYL

*BIS(2-ETHYLHEXYL) PHTHAL




*CARBON DISULFIDE

*CHLOROFORM

*DIBENZOTHIOPHENE

*ETHYLBENZENE

*FLUORENE

*N-HEXADECANE
Existing

Existing

Existing

Existing

Existing

Existing
           *N-TETRADECANE
*NAPHTHALENE

*P-CYMENE

*PHENANTHRENE


*PYRENE
                      6ENL

                      OILY
                      DRYD
                      OILY
OILY
RRL

OILY

OILY

OILY

6ENL

OILY

OILY
OILY
OILY
RRL

PWB

MFJ

OILY

OILY

OILY

6ENL
DRYD
OILY
OILY
OILY
OILY
RRL

OILY
6ENL
DRYD
OILY
OILY
DRYD
RRL

OILY

OILY

OILY
RRL
                                     Existing
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                            C-13
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
                                Nevv
                                              EPA
                                    or       Sampling
                                 Existing    Episode
                                Source Trt.
                                  Option
                                                      Episode   Sample
                 of
                Nds
Detection
  Limit
                                                                                                           Daily
                                                                                                            VF
                                                           4-day
                                                           VF
                                   Existing  4737
                                            4851
6ENL
OILY
          OIL AND GREASE (AS  HEM)    Existing  4851
                                            4877
OILY
OILY
                                                        OILY
                                                        OILY
                                                        OILY
                                                        OILY
          TOTAL  SULFIDE
                                                        OILY

                                                        OILY
                                                        OILY
                                                        OILY
                                                        OILY
                                                        OILY
                                                  1.47
                                                           1.15
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                         C-14
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat.
PWB
PWB
PWB
PWB
PWB
PWB

PWB
PWB
PWB
PWB

PWB
PWB
PWB
PWB
PWB
PWB
PWB
PWB
PWB
PWB
PWB


PWB


PWB
PWB
PWB
PWB
Analyte New Source
or
Existing
Source Trt.
Option
*1,1-DICHLOROETHYLENE
*1,1-DICHLOROETHYLENE
*1-METHYLFLUORENE
*1-METHYLFLUORENE
*1-METHYLPHENANTHRENE
*1-METHYLPHENANTHRENE

*2-ISOPROPYLNAPHTHALENE
*2-ISOPROPYLNAPHTHALENE
*2 -METHYLNAPHTHALENE
*2 -METHYLNAPHTHALENE

*3,6-DIMETHYLPHENANTHRENE
*3,6-DIMETHYLPHENANTHRENE
*4-CHLORO-M-CRESOL
*4-CHLORO-M-CRESOL
*ACENAPHTHENE
*ACENAPHTHENE
*BENZOIC ACID
*BENZOIC ACID
*BIPHENYL
*BIPHENYL
*BIS (2-ETHYLHEXYL) PHTHAL


*BIS (2-ETHYLHEXYL) PHTHAL


*CARBON DISULFIDE
*CARBON DISULFIDE
*CHLOROFORM
*CHLOROFORM
Existing
New
Existing
New
Existing
New

Existing
New
Existing
New

Existing
New
Existing
New
Existing
New
Existing
New
Existing
New
Existing


New


Existing
New
Existing
New
EPA
Sampling
Episode
4737
4737
4851
4851
4805
4851
4805
4851
4851
4851
4851
6179
4851
6179
4851
4851
4876
4876
4851
4851
4817
4817
4851
4851
4471
4851
4876
6179
4471
4851
4876
6179
4867
4867
4788
4788
Episode Sample Number
Subcat. Size of
Nds
6ENL 5 5
6ENL 5 5
OILY 5 5
OILY 5 5
DRYD 2 2
OILY 5 5
DRYD 2 2
OILY 5 5
OILY 5 5
OILY 5 5
OILY 5 0
RRL 3 3
OILY 5 0
RRL 3 3
OILY 5 5
OILY 5 5
OILY 5 0
OILY 5 0
OILY 5 5
OILY 5 5
6ENL 4 1
6ENL 4 1
OILY 5 2
OILY 5 2
OILY 4 0
OILY 5 5
OILY 5 5
RRL 3 3
OILY 4 0
OILY 5 5
OILY 5 5
RRL 3 3
PWB 5 0
PWB 5 0
MFJ 3 0
MFJ 3 0
Mean
Detection
Limit
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.

0.
0.
0.


0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.




00999
00999
01032
01032
01000
01032
01000
01032
01032
01032
01000

01000
01032
01032


01032
01032
05000
05000
00999
00999
01032
00999
01000
01032
00999
01000




Long-term
Average*
0.00999
0.00999
0.01032
0.01032
0.01000
0.01032
0.01000
0.01032
0.01032
0.01032
0.04864
0.01000
0.04864
0.01000
0.01032
0.01032
0.52609
0.52609
0.01032
0.01032
0.30052
0.30052
0.01239
0.01239
0.10740
0.01032
0.00999
0.01000
0.10740
0.01032
0 . 00999
0.01000
0.74799
0.74799
0.19603
0.19603
Daily 4-day
VF VF









1.80 1.24
1.80 1.24



6.55 2.31
6.55 2.31


7.59 2.53
7.59 2.53
1.36 1.15
1.36 1.15
2.36 1.38


2. 36 1. 38


4.55 1.87
4.55 1.87


* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                   C-15
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat.
PWB
PWB
PWB
PWB
PWB
PWB
PWB





PWB






PWB





PWB






PWB
PWB
PWB
PWB
PWB
PWB

PWB
PWB
Analyte
*DIBENZOTHIOPHENE
*DIBENZOTHIOPHENE
*ETHYLBENZENE
*ETHYLBENZENE
*FLUORENE
*FLUORENE
*N-HEXADECANE





*N-HEXADECANE






*N-TETRADECANE





*N-TETRADECANE






*NAPHTHALENE
*NAPHTHALENE
*P-CYMENE
*P-CYMENE
*PHENANTHRENE
*PHENANTHRENE

*PYRENE
*PYRENE
New Source
or
Existing
Source Trt.
Option
Existing
New
Existing
New
Existing
New
Existing





New






Existing





New






Existing
New
Existing
New
Existing
New

Existing
New
EPA
Sampling
Episode
4851
4851
4851
4851
4851
4851
4737
4805
4851
4872
4876
4877
6179
4737
4805
4851
4872
4876
4877
6179
4471
4737
4805
4851
4876
4892
6179
4471
4737
4805
4851
4876
4892
6179
4851
4851
4851
4851
4851
6179
4851
6179
4851
4851
Episode Sample Number
Subcat. Size of
Nds
OILY 5 5
OILY 5 5
OILY 5 4
OILY 5 4
OILY 5 5
OILY 5 5
6ENL 5 5
DRYD 2 2
OILY 5 4
OILY 3 2
OILY 5 5
OILY 5 4
RRL 3 3
6ENL 5 5
DRYD 2 2
OILY 5 4
OILY 3 2
OILY 5 5
OILY 5 4
RRL 3 3
OILY 4 1
6ENL 5 5
DRYD 2 2
OILY 5 1
OILY 5 5
DRYD 5 3
RRL 3 3
OILY 4 1
6ENL 5 5
DRYD 2 2
OILY 5 1
OILY 5 5
DRYD 5 3
RRL 3 3
OILY 5 0
OILY 5 0
OILY 5 5
OILY 5 5
OILY 5 5
RRL 3 3
OILY 5 5
RRL 3 3
OILY 5 5
OILY 5 5
Mean
Detection
Limit
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.


0.
0.
0.
0.
0.
0.
0.
0.
01032
01032
00999
00999
01032
01032
01899
01000
01022
00999
00999
00999
01000
01899
01000
01022
00999
00999
00999
01000
00999
01899
01000
01059
00999
01000
01000
00999
01899
01000
01059
00999
01000
01000


01032
01032
01032
01000
01032
01000
01032
01032
Long-term
Average*
0.01032
0.01032
0.01032
0.01032
0.01032
0.01032
0.01899
0.01000
0.01140
0.01210
0.00999
0.01098
0.01000
0.01899
0.01000
0.01140
0.01210
0.00999
0.01098
0.01000
0.02647
0.01899
0.01000
0.01987
0.00999
0.01719
0.01000
0.02647
0.01899
0.01000
0.01987
0.00999
0.01719
0.01000
0.04658
0.04658
0.01032
0.01032
0.01032
0.01000
0.01032
0.01000
0.01032
0.01032
Daily 4-day
VF VF



















4.15 1.80

3.22 1. 58

5.81 2. 10

4.15 1.80


3.22 1. 58

5.81 2. 10

1.92 1.27
1.92 1.27







* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                   C-16
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat . Analyte




New Source
or
Existing
Source Trt.
Option
EPA
Sampling
Episode


Episode
Subcat .



Sample
Size



Number
of
Nds


Mean
Detection
Limit


Long-term
Average*



Daily
VF



4-day
VF



                                   Existing  4737
                                             4851
          AMENABLE  CYANIDE
6ENL
OILY

6ENL
OILY

6ENL
6ENL
MFJ
6ENL
6ENL
6ENL
6ENL
MFJ
                                   Existing  4277
                                             4737
                                             4806
                                             4807
                                             4817
                                             4833
                                             4834
                                             4847
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
3
3
3
3
5
5
3
5
3
3
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
                                                                                               0.63767
                                                                                               0.87066
                                                                                               0.97033
                                                                                               2.27167
                                                                                               0.06674
                                                                                               0.58489
                                                                                               0.04880
                                                                                               0.01876
                                                                                               0.09266
                                                                                               1.17467
                                                                                               0.07731
                                                                                               0.00855
                                                                                               0.09254
                                                                                               0.06793
                                                                                               0.30159
                                                                                               0.01012
                                                                                               0.01475
                                                            1. 45
                                                            1.21
                                                                                                                     1. 74
                                                                                                                     1.21
 PWB       COPPER

 PWB       CYANIDE
PWB

6ENL
MFJ
6ENL
6ENL
6ENL
6ENL
MFJ
6ENL
6ENL
DRYD
6ENL
6ENL
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                          C-17
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
                                                EPA
                                             Sampling
                                              Episode
                                                        Episode   Sample
                                                                 of
                                                                Nds
                                              Detection
                                                Limit
                                                                                                   Daily
                                                                                                     VF
                                                                                  4-day
                                                                                  VF
 PWB

 PWB
 PWB

 PWB

 PWB

 PWB
CYANIDE

LEAD
LEAD

MANGANESE

MANGANESE

NICKEL
                      MFJ

                      GENL
                      GENL
                      GENL
                      GENL
                      GENL

                      PWB
                                                          PWB
                                                          PWB
 PWB      NICKEL
          OIL AND GREASE  (AS HEM)
                                              4807
                                              4854
                                                GENL
                                                GENL
                                                          GENL
                                                          GENL
                                                                                                             1.51
                                                                                                                       1.16
 PWB
                                    Existing
                                                          PWB
                                                          PWB
 PWB

 PWB
                          New

                          Existing
                                                          PWB
                                                          PWB
 PWB


 PWB

 PWB

 PWB


 PWB
                                                PWB
                                                PWB
TOTAL SULFIDE

TOTAL SULFIDE

TOTAL SUSPENDED SOLIDS
Existing

New

New


Existing
                                                GENL
                                                GENL

                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                GENL
                                                          GENL
                                                          GENL
                                                          GENL
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                           C-18
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
                                             EPA     Episode
                                           Sampling   Subcat.
                                            Episode
ample   Number     Mean
Size      of     Detection
        Nds      Limit
Daily    4-day
 VF     VF
                                                       DRYD
                                                       DRYD
                                                       DRYD
                                                       RRL
                                                       DRYD
                                                       DRYD
                                                       RRL
          TOTAL SUSPENDED SOLIDS
                                                       DRYD
                                                       DRYD
                                                       DRYD
                                                       RRL
* Cases where LTA is missing and VF is not indicate only VF transfer.
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat.
SFF
SFF
SFF
SFF
SFF
SFF

SFF
SFF
SFF
SFF

SFF
SFF
SFF
SFF
SFF
SFF
SFF
SFF
SFF
SFF
SFF


SFF


SFF
SFF
SFF
SFF
Analyte New Source
or
Existing
Source Trt.
Option
*1,1-DICHLOROETHYLENE
*1,1-DICHLOROETHYLENE
*1-METHYLFLUORENE
*1-METHYLFLUORENE
*1-METHYLPHENANTHRENE
*1-METHYLPHENANTHRENE

*2-ISOPROPYLNAPHTHALENE
*2-ISOPROPYLNAPHTHALENE
*2 -METHYLNAPHTHALENE
*2 -METHYLNAPHTHALENE

*3,6-DIMETHYLPHENANTHRENE
*3,6-DIMETHYLPHENANTHRENE
*4-CHLORO-M-CRESOL
*4-CHLORO-M-CRESOL
*ACENAPHTHENE
*ACENAPHTHENE
*BENZOIC ACID
*BENZOIC ACID
*BIPHENYL
*BIPHENYL
*BIS (2-ETHYLHEXYL) PHTHAL


*BIS (2-ETHYLHEXYL) PHTHAL


*CARBON DISULFIDE
*CARBON DISULFIDE
*CHLOROFORM
*CHLOROFORM
Existing
New
Existing
New
Existing
New

Existing
New
Existing
New

Existing
New
Existing
New
Existing
New
Existing
New
Existing
New
Existing


New


Existing
New
Existing
New
EPA
Sampling
Episode
4737
4737
4851
4851
4805
4851
4805
4851
4851
4851
4851
6179
4851
6179
4851
4851
4876
4876
4851
4851
4817
4817
4851
4851
4471
4851
4876
6179
4471
4851
4876
6179
4867
4867
4788
4788
Episode Sample Number
Subcat. Size of
Nds
6ENL 5 5
6ENL 5 5
OILY 5 5
OILY 5 5
DRYD 2 2
OILY 5 5
DRYD 2 2
OILY 5 5
OILY 5 5
OILY 5 5
OILY 5 0
RRL 3 3
OILY 5 0
RRL 3 3
OILY 5 5
OILY 5 5
OILY 5 0
OILY 5 0
OILY 5 5
OILY 5 5
6ENL 4 1
6ENL 4 1
OILY 5 2
OILY 5 2
OILY 4 0
OILY 5 5
OILY 5 5
RRL 3 3
OILY 4 0
OILY 5 5
OILY 5 5
RRL 3 3
PWB 5 0
PWB 5 0
MFJ 3 0
MFJ 3 0
Mean
Detection
Limit
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.

0.
0.
0.


0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.




00999
00999
01032
01032
01000
01032
01000
01032
01032
01032
01000

01000
01032
01032


01032
01032
05000
05000
00999
00999
01032
00999
01000
01032
00999
01000




Long-term
Average*
0.00999
0.00999
0.01032
0.01032
0.01000
0.01032
0.01000
0.01032
0.01032
0.01032
0.04864
0.01000
0.04864
0.01000
0.01032
0.01032
0.52609
0.52609
0.01032
0.01032
0.30052
0.30052
0.01239
0.01239
0.10740
0.01032
0.00999
0.01000
0.10740
0.01032
0 . 00999
0.01000
0.74799
0.74799
0.19603
0.19603
Daily 4-day
VF VF









1.80 1.24
1.80 1.24



6.55 2.31
6.55 2.31


7.59 2.53
7.59 2.53
1.36 1.15
1.36 1.15
2.36 1.38


2. 36 1. 38


4.55 1.87
4.55 1.87


* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                   C-20
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
                                                EPA
                                     or       Sampling
                                  Existing    Episode
                                 Source  Trt.
                                   Option
                                                        Episode   Sample   Number
                                       of     Detection
                                       Nds       Limit
                                                                          Daily
                                                                            VF
                                                             4-day
                                                             VF
           *DIBENZOTHIOPHENE

           *DIBENZOTHIOPHENE

           *ETHYLBENZENE

           *ETHYLBENZENE

           *FLUORENE

           *FLUORENE

           *N-HEXADECANE
           *N-HEXADECANE
           *N-TETRADECANE
           *N-TETRADECANE
           *NAPHTHALENE

           *NAPHTHALENE

           *P-CYMENE

           *P-CYMENE

           *PHENANTHRENE


           *PHENANTHRENE


           *PYRENE

           *PYRENE
Existing

New

Existing

New

Existing

New

Existing
                                    Existing
Existing

New

Existing

New

Existing


New


Existing

New
OILY

6ENL
DRYD
OILY
OILY
OILY
OILY
RRL

6ENL
DRYD
OILY
OILY
OILY
OILY
RRL

OILY
6ENL
DRYD
OILY
OILY
DRYD
RRL

OILY
6ENL
DRYD
OILY
OILY
DRYD
RRL

OILY

OILY

OILY

OILY

OILY
RRL

OILY
RRL

OILY

OILY
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                           C-21
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
                                                EPA
                                              Sampling
                                              Episode
                          Mean
                        Detection
                          Limit
             Daily
              VF
4-day
VF
                                                          6ENL
                                                          OILY
 SFF      AMENABLE CYANIDE
6ENL
OILY

6ENL
6ENL
MFJ
6ENL
6ENL
6ENL
6ENL
MFJ
                                    Existing
 SFF

 SFF
                                    Existing
                                              4882
6ENL
6ENL
6ENL
6ENL
6ENL

6ENL

6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
0.63767
0.87066
0.97033
2.27167
0.06674
0.58489
0.04880
0.01876
0.09266
1.17467
0.07731
0.00855
0.09254
0.06793
0.30159
0.01012
0.01475
                                                                                                              1. 37

                                                                                                              1. 81
                                                                                                                        1.41
 SFF      CHROMIUM
 SFF      COPPER
                                    Existing
6ENL
6ENL
6ENL

6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
6ENL
 SFF      COPPER
                                                          6ENL
                                                          6ENL
                                                          6ENL
                                                          6ENL
                                                          MFJ
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                           C-22
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat. Analyte New Source EPA
or Sampling
Existing Episode
Source Trt.
Option
SFF CYANIDE 4384
4460A
4807
4817
4828
4834
4847
4891
4904
6048
6186
SFF LEAD Existing 1197A
4761
4762
4834
4871
SFF LEAD New 4855
SFF MANGANESE Existing 4762
4807
4871
4904
SFF MANGANESE New 4807
SFF MOLYBDENUM Existing 4806
4904
SFF MOLYBDENUM New 4806
4904
SFF NICKEL Existing 1197A
4277
4438
4470
4761
4762
4807
4811
4817
4833
4834
4847
4871
4904
6048
SFF NICKEL New 4807
4854
SFF OIL AND GREASE (AS HEM) Existing 4737
4871
SFF SILVER Existing 1197A
4277
4807
4817
Episode Sample Number
Subcat. Size of
Nds
GENL 5 0
GENL 1 0
GENL 5 2
GENL 5 2
MFJ 5 0
GENL 5 5
GENL 4 2
DRYD 5 0
GENL 5 0
GENL 5 0
MFJ 5 0
GENL 3 1
GENL 3 3
GENL 5 5
GENL 5 1
GENL 5 0
PWB 5 5
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 0
GENL 3 0
GENL 5 0
GENL 3 0
GENL 5 0
GENL 3 0
GENL 5 0
GENL 5 0
GENL 5 1
GENL 5 0
GENL 5 4
GENL 5 0
GENL 5 0
GENL 5 0
GENL 5 5
GENL 5 0
GENL 5 0
GENL 5 2
GENL 5 0
GENL 5 5
GENL 3 0
GENL 5 3
GENL 5 1
GENL 5 0
Mean
Detection
Limit


0.01999
0. 11000

0. 01999
0. 00999




0.20000
0. 01200
0.02480
0. 01600

0.02100













0.01799

0.01600



0.02600


0.01600
6. 13633
0. 00499
0. 00060

Long-term
Average*
0.77039
0.01999
0.02719
0.44300
0.09189
0.01999
0.01237
0.08829
0.25709
0.20700
0.19599
1.88000
0.01200
0.02480
0.02054
0.00942
0.02100
0.13878
0.04963
0.09170
0.01327
0.12990
0.72319
0.03153
0.72319
0.03153
0.55667
0.17819
0.41466
0.23126
0.26600
0.20579
0.26379
0.04700
0.03442
0.05120
0.33040
0.05452
0.65159
0.02600
0.34640
0.75120
0.03434
13.60000
6.13633
0.33933
0.01035
0.03198
0.06180
Daily
VF
1. 94

2.60
2. 18
2.80

2.63
2. 92
2.74
1. 66
1.67


1. 55
1.88

1. 64
2. 08
1.35
2.22
2.21
2. 84
1.32
2.84
1. 32
1.18

1. 95

2.11
2.24
1. 93
2. 16

2.26
3.16
1. 41

3. 15
2. 75
6.80
1.51
5.89
4. 02
4. 08
4-day
VF
1.27

1. 41
1. 60
1.48

1.39
1. 51
1.47
1.20
1.20


1. 18
1.26

1.20
1. 31
1.11
1. 35
1. 34
1. 49
1.11
1. 49
1. 11
1.06

1.28

1.32
1. 35
1.36
1. 33

1. 35
1.56
1. 13

1. 56
1. 47
2.33
1.16
2.13
1. 84
1.76
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                   C-23
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat. Analyte




New Source
or
Existing
Source Trt.
Option
EPA
Sampling
Episode


Episode
Subcat .



Sample
Size



Number
of
Nds


Mean
Detection
Limit


Long-term
Average*



Daily
VF



4-day
VF



                                                           GENL
                                                           GENL
                                                           GENL
                                                           PWB
                ORGANIC CARBON (TOC   Existing  4737
                                              4761
                                              4762
                                              4806
                                              4807
                                              4817
                                              4833
                                              4834
                                              4871
                                              4904
                      GENL
                      GENL
                      GENL
                      GENL
                      GENL
                      GENL
                      GENL
                      GENL
                      GENL
                      GENL
           TOTAL ORGANIC CARBON (TOC  New
                                                           GENL
                                                           GENL
                                                           GENL
                                                           GENL
                                                           GENL
                                                           GENL
                                                           GENL
                                                           GENL
                                                           GENL
                                                           GENL
           TOTAL

           TOTAL

           TOTAL
Existing  4877

New       4877

Existing  1197A
          4011
          4079
          4277
          4384
          4415
          4417
          4438
          4470
          4737
          4761
          4762
          4807
          4811
          4817
          4833
          4834
          4871
OILY

GENL
GENL
GENL
GENL
GENL
GENL
GENL
GENL
GENL
GENL
GENL
GENL
GENL
GENL
GENL
GENL
GENL
GENL
GENL
26.66667
26.66667
 6.33333
14.40000
45.60000
 1.00000
 7.00000
 6.66667
17.70000
24.00000
22.00000
14.40000
 8.30000
 4.00000
11.80000
 8.40000
14.60000
 5.80000
 5.70000
                                                                                                               3.11
           TOTAL SUSPENDED SOLIDS
Existing  1197A
          4277
          4415
          4417
          4470
GENL
GENL

GENL
GENL
GENL
GENL
GENL
GENL
                                                                                                                         1.31
                                                                                                                         1.59
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                            C-24
-------
Appendix C. Facility-level Long-term Averages and Variability Factors (continued)
Subcat . Analyte




New Source
or
Existing
Source Trt.
Option
EPA
Sampling
Episode


Episode
Subcat .



Sample
Size



Number
of
Nds


Mean
Detection
Limit


Long-term
Average*



Daily
VF



4-day
VF



                                 Existing
                                                     6ENL
                                                     6ENL
                                                     6ENL
                                                     6ENL
                                                     6ENL
                                                     6ENL
                                                     6ENL

                                                     6ENL
                                                     6ENL
                                                     6ENL
* Cases where LTA is missing and VF is not indicate only VF transfer.
                                                     C-25
-------
Appendix D. Pollutant-level Long-term Averages, Variability Factors, and Limitations
Subcat.
ANO
ANO
ANO
ANO
ANO
ANO
DRYD
DRYD
GENL
6ENL

GENL

GENL

GENL
GENL

GENL

GENL

GENL

GENL

GENL

GENL

GENL

GENL

GENL

GENL

Analyte New Source or
Existing Source
Trt. Option
ALUMINUM
MANGANESE
NICKEL
OIL AND GREASE (AS HEM)
TOTAL SUSPENDED SOLIDS
ZINC
OIL AND GREASE (AS HEM)
TOTAL SUSPENDED SOLIDS
AMENABLE CYANIDE
CADMIUM

CHROMIUM

COPPER

CYANIDE
LEAD

MANGANESE

MOLYBDENUM

NICKEL

OIL AND GREASE (AS HEM)

SILVER

TIN

TOTAL ORGANIC CARBON ( TOC

TOTAL ORGANICS PARAMETER

TOTAL SULFIDE

TOTAL SUSPENDED SOLIDS

Existing
Existing
Existing
Existing
Existing
Existing
Existing
Existing

Existing
New
Existing
New
Existing
New

Existing
New
Existing
New
Existing
New
Existing
New
Existing
New
Existing
New
Existing
New
Existing
New
Existing
New
Existing
New
Existing
New
Number of
^ Episodes
(LTA)
2
4
15
2
2
13
2
3
8
5
1
17
3
9
3
13
5
1
4
1
2
2
15
2
2
2
4
1
2
1
10
10
42
42
1
1
19
2
Number of
Episodes
(VF)
2
4
10
1
2
9
2
2
5
2
1
9
3
9
3
9
2

4
1
2
2
10
2
1
1
3
1
2
1
8
8
12
12
1
1
12
1
Median
LTA
(mg/L)
2
0
0
9
12
0
9
30
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9
9
0
0
0
0
37
37
2
2
7
7
12
13
. 6
.07
.24
. 9

.16
. 0

.04
.08
.01
.10
.04
.18
.08
.09
.02
.03
. 07
.13
.38
.38
.24
.40
. 9
. 9
.05
.02
.44
.02


.3
.3
.1
.1


Mean Mean
Daily 4-day
VF VF
3.3 1.6
1.9 1.3
2.2 1.4
1.6 1.2
4.4 1.8
2.4 1.4
1.8 1.3
2.8 1.5
3.4 1.7
2.0 1.3
1.8 1.3
2.7 1.5
4.8 2.0
3.2 1.6
5.9 2.2
2.4 1.4
1.8 1.3
1.6 1.2
1.9 1.3
2.3 1.4
2.1 1.3
2.1 1.3
2.2 1.4
4.7 1.9
1.6 1.2
1.6 1.2
4.7 2.0
3.0 1.8
3.0 1.6
1.6 1.2
2.4 1.4
2.4 1.4
3.9 1.8
3.9 1.8
4.3 1.8
4.3 1.8
2.9 1.5
2.1 1.4
Daily
Limitation
(mg/L)
8
0
0
15
52
0
16
81
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
15
15
0
0
1
0
87
8 7
9
9
31
31
34
28
,2
.13
.50


.38


.14
.14
. 02
.25
.17
.55
. 44
.21
. 04
.04
.13
.29
. 7 9
. 79
.50
. 88


.22
. 05
. 4
. 03


. 0
.0




4-day
Limitation
(mg/L)
4
0
0
12
22
0
11
44
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
12
12
0
0
0
0
50
50
4
4
13
13
18
18
. 0
.09
.31


.22


. 07
.09
.01
.14
.07
.28
.16
.13
.03
.03
.09
.18
.49
.49
.31
.75


.09
.03
. 67
. 03


.3
.3




                                              D-l
-------
Appendix D. Pollutant-level Long-term Averages, Variability Factors, and Limitations (continued)
Subcat.
GENL

MFJ
MFJ

MFJ

MFJ

MFJ
MFJ

MFJ

MFJ

MFJ

MFJ
MFJ

MFJ

MFJ

MFJ

MFJ

MFJ
MFJ

OILY
OILY
OILY
OILY
OILY
PWB
Analyte New Source or Number of
Existing Source Episodes
Trt. Option (LTA)
ZINC

AMENABLE CYANIDE
CADMIUM

CHROMIUM

COPPER

CYANIDE
LEAD

MANGANESE

MOLYBDENUM

NICKEL

OIL AND GREASE (AS HEM)
SILVER

TIN

TOTAL ORGANIC CARBON ( TOC

TOTAL ORGANICS PARAMETER

TOTAL SULFIDE

TOTAL SUSPENDED SOLIDS
ZINC

OIL AND GREASE (AS HEM)
TOTAL ORGANIC CARBON (TOC
TOTAL ORGANICS PARAMETER
TOTAL SULFIDE
TOTAL SUSPENDED SOLIDS
AMENABLE CYANIDE
Existing
New

Existing
New
Existing
New
Existing
New

Existing
New
Existing
New
Existing
New
Existing
New
New
Existing
New
Existing
New
Existing
New
Existing
New
Existing
New
New
Existing
New
Existing
Existing
Existing
Existing
Existing

13
3
8
4
1
6
3
6
3
13
3
1
4
1

2
5
2
2
3
1
1
1
1
1
42
42
1
1
2
8
3
2
4
42
1
5
8
Number of
Episodes
(VF)
9
3
5
2
1
3
3
3
3
9
1

2
1
2
2
4
2
1
1
1
1
1
1
1
12
12
1
1
1
4
3
2
3
12
1
4
5
Median
LTA
(mg/L)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9
0
0
1
0
51
51
2
2
7
7
13
0
0
17
282
2
7
20
0
.16
.04
.04
.05
.01
.31
.04
.34
.08
.09
. 07
.03
.05
.13
.38
.38
.39
.40
. 9
.04
.02
.3
.02


.3

.1
.1

.11
.04


.3
.1

.04
Mean Mean
Daily 4-day
VF VF
2.4 1.4
2.2 1.5
3.4 1.7
4.5 1.9
1.8 1.3
4.3 1.8
4.8 2.0
4.0 1.8
5.9 2.2
2.4 1.4
1.8 1.3
1.6 1.2
5.0 2.0
2.3 1.4
2.1 1.3
2.1 1.3
3.7 1.7
4.7 1.9
1.6 1.2
4.5 1.9
3.0 1.8
1.5 1.2
1.6 1.2
1.6 1.2
1.6 1.2
3.9 1.8
3.9 1.8
4.3 1.8
4.3 1.8
2.1 1.4
3.3 1.6
2.2 1.5
1.6 1.2
2.3 1.4
3.9 1.8
4.3 1.8
3.3 1.6
3.4 1.7
Daily
Limitation
(mg/L)
0
0
0
0
0
1
0
1
0
0
0
0
0
0
0
0
1
1
15
0
0
1
0
78
7 8
9
9
31
31
2 8
0
0
27
633
9
31
63
0
.38
. 08
. 14
.21
.02
.3
. 17
. 3
. 44
.21
.12
. 04
.25
.29
. 79
. 7 9
. 5
.88

.15
. 05
. 8
.03


. 0
. 0



. 35
.08


.0


.14
4-day
Limitation
(mg/L)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
12
0
0
1
0
59
59
4
4
13
13
18
0
0
20
378
4
13
31
0
.22
.06
.07
.09
.01
.55
.07
.58
.16
.13
.09
.03
.10
.18
.49
.49
.64
.75

.06
.03
.4
.03


.3




.17
.06


.3


. 07
                                              D-2
-------
Appendix D. Pollutant-level Long-term Averages, Variability Factors, and Limitations (continued)
Subcat.
PWB

PWB

PWB
PWB

PWB

PWB

PWB
PWB

PWB

PWB

PWB

PWB
PWB

RRL
RRL
RRL
SFF
SFF

SFF

SFF

SFF
SFF

SFF

Analyte New Source or
Existing Source
Trt. Option
CHROMIUM

COPPER

CYANIDE
LEAD

MANGANESE

NICKEL

OIL AND GREASE (AS HEM)
TIN

TOTAL ORGANIC CARBON ( TOC

TOTAL ORGANICS PARAMETER

TOTAL SULFIDE

TOTAL SUSPENDED SOLIDS
ZINC

BOD 5-DAY (CARBONACEOUS)
OIL AND GREASE (AS HEM)
TOTAL SUSPENDED SOLIDS
AMENABLE CYANIDE
CADMIUM

CHROMIUM

COPPER

CYANIDE
LEAD

MANGANESE

Existing
New
Existing
New

Existing
New
Existing
New
Existing
New
New
Existing
New
Existing
New
Existing
New
Existing
New
New
Existing
New
Existing
Existing
Existing

Existing
New
Existing
New
Existing
New

Existing
New
Existing
New
Number of
^ Episodes
(LTA)
17
3
g
1
13
5
1
1
1

2
2
2
1

2
42
42
1
1
2
13
3
1
1
1
8
5
1
17
3
9
3
13
5
1
4
1
Number of
Episodes
(VF)
9
3
9

9
2

1
1
2
2
1
2
1
2
2
12
12
1
1
1
9
3
2
2
2
5
2
1
9
3
9
3
9
2

4
1
Median
LTA
(mg/L)
0
0
0
0
0
0
0
0
0
0
0
9
0
0
53
53
2
2
7
7
13
0
0
5
6
11
0
0
0
0
0
0
0
0
0
0
0
0
.10
.04
.18
.01
.09
.02
.03
.41
.13
.08
.40
. 9
.08
.06


.3
.3
.1
.1

.16
.04
.2
.3

.04
.08
.01
.10
.04
.18
.08
.09
.02
. 03
.07
.13
Mean Mean
Daily 4-day
VF VF
2.7 1.5
4.8 2.0
3.2 1.6
1.6 1.2
2.4 1.4
1.8 1.3
1.6 1.2
3.1 1.6
2.3 1.4
3.7 1.7
4.7 1.9
1.6 1.2
4.0 1.8
1.6 1.2
2.0 1.3
2.0 1.3
3.9 1.8
3.9 1.8
4.3 1.8
4.3 1.8
2.1 1.4
2.4 1.4
2.2 1.5
6.5 2.3
1.8 1.3
2.8 1.5
3.4 1.7
2.0 1.3
1.8 1.3
2.7 1.5
4.8 2.0
3.2 1.6
5.9 2.2
2.4 1.4
1.8 1.3
1.6 1.2
1.9 1.3
2.3 1.4
Daily
Limitation
(mg/L)
0
0
0
0
0
0
0
1
0
0
1
15
0
0
101
101
9
9
31
31
2 8
0
0
34
11
30
0
0
0
0
0
0
0
0
0
0
0
0
.25
. 17
. 55
.01
.21
.04
. 04
. 3
.29
.30
. 88

. 31
. 09


. 0
.0



. 38
.08



.14
.14
. 02
.25
.17
.55
. 44
.21
. 04
.04
.13
.29
4-day
Limitation
(mg/L)
0
0
0
0
0
0
0
0
0
0
0
12
0
0
67
67
4
4
13
13
18
0
0
12
7
16
0
0
0
0
0
0
0
0
0
0
0
0
.14
.07
.28
.01
.13
. 03
.03
.64
.18
.14
.75

.14
. 07


.3
.3



.22
.06

.6

.07
.09
.01
.14
. 07
.28
.16
.13
.03
. 03
.09
. 18
                                              D-3
-------
Appendix D. Pollutant-level Long-term Averages, Variability Factors, and Limitations (continued)
                                   New Source or   Number  of   Number of    Median   Mean    Mean      Daily       4-day
                                  Existing Source  Episodes   Episodes      LTA    Daily    4-day    Limitation  Limitation
                                    Trt. Option      (LTA)        (VF)       (mg/L)    VF      VF       (mg/L)       (mg/L)
                                     Existing
                                     New
                         1.3
                         1.3
           NICKEL

           OIL  AND GREASE (AS HEM)
10
 2
 1
 1
                                     Existing
                                     New
                                                   10
                                                   10
                         1.4
                         1.4
                                     50
                                     50
           TOTAL OR6ANICS PARAMETER    Existing
                                     New
                                               4 .3
                                               4 .3
           TOTAL SULFIDE
                                     Existing
                                     New
          7.1
          7 .1
        4 .3
        4 .3
         31
         31
           TOTAL SUSPENDED SOLIDS      Existing
                                     New
12
 1
12
13
1.5
1.4
34
28
18
18
                                     Existing
                                     New
                         1.4
                         1.5
                                                        D-4
-------
Appendix El. Effluent Limitations (mg/L) for Existing Source Treatment Options
Analyte
ALUMINUM
AMENABLE CYANIDE
BOD 5-DAY
CADMIUM
CHROMIUM
COPPER
CYANIDE
LEAD
MANGANESE
MOLYBDENUM
NICKEL
OIL AND GREASE (AS
SILVER
TIN
TOTAL ORGANIC CARBON
TOTAL ORGANIC S
TOTAL SULFIDE
TOTAL SUSPENDED SOLIDS
ZINC
GENL GENL
Daily Monthly
--
0.14
--
0. 14
0.25
0.55
0.21
0.04
0.13
0.79
0 . 50
15
0.22
1.4
87
9. 0
31
34
0 . 38
--
0 . 07
--
0.09
0. 14
0.28
0.13
0.03
0.09
0.49
0.31
12
0.09
0 . 67
50
4.3
13
18
0.22
MFJ MFJ PWB PWB AND AND DRYD
Daily Monthly Daily Monthly Daily Monthly Daily
--
0.14
--
0.21
1.3
1.3
0.21
0. 12
0.25
0.79
1.5
52
0.15
1.8
78
9. 0
31
60
0.35
8.2 4.0
0.07 0.14 0.07
--
0.09
0.55 0.25 0.14
0.58 0.55 0.28
0.13 0.21 0.13
0.09 0.04 0.03
0.10 1.3 0.64 0.13 0.09
0.49
0.64 0.30 0.14 0.50 0.31
26 52 26 52 26 16
0 . 06 --
1.4 0.31 0.14
59 101 67
4.3 9.0 4.3
13 31 13
31 60 31 60 31 81
0.17 0.38 0.22 0.38 0.22
DRYD OILY OILY RRL RRL SEE SEE
Monthly Daily Monthly Daily Monthly Daily Monthly
--
0.14
34 12
0.14
0.25
0.55
0.21
0.04
0.13
0.79
0 . 50
11 27 20 11 7.6 15
0.22
1.4
633 378 — — 87
9.0 4.3 — — 9.0
31 13 -- -- 31
44 63 31 30 16 34
0.38
--
0 ,
--
0,
0 ,
0 ,
0,
0,
0 ,
0 ,
0,
12
0 ,
0,
50
4 ,
13
18
0,

. 07

.09
.14
. 2 8
.13
.03
. 09
.49
.31

. 09
. 67

.3


.22
                                                         E-l
-------
Appendix E2. Effluent Limitations (mg/L) for New Source Treatment Options
Analyte
ALUMINUM
AMENABLE CYANIDE
BOD 5-DAY
CADMIUM
CHROMIUM
COPPER
CYANIDE
LEAD
MANGANESE
MOLYBDENUM
NICKEL
OIL AND GREASE (AS
SILVER
TIN
TOTAL ORGANIC CARBON
TOTAL ORGANIC S
TOTAL SULFIDE
GENL GENL MFJ MFJ PWB PWB AND AND DRYD
Daily Monthly Daily Monthly Daily Monthly Daily Monthly Daily
--
0.14
--
0.02
0.17
0.44
0.21
0.04
0.29
0.79

15
0.05
0.03
87
9. 0
31
8.2 4.0
0.07 0.14 0.07 0.14 0.07
--
0.01 0.02 0.01
0.07 0.17 0.07 0.17 0.07
0.16 0.44 0.16 0.01 0.01
0.13 0.21 0.13 0.21 0.13
0.03 0.04 0.03 0.04 0.03
0.18 0.29 0.18 0.29 0.18 0.13 0.09
0.49 0.79 0.49
--
12 15 12 15 12 15 12 16
0.03 0.05 0.03
0.03 0.03 0.03 0.09 0.07
50 78 59 101 67
4.3 9.0 4.3 9.0 4.3
13 31 13 31 13
DRYD OILY OILY RRL RRL SEE SEE
Monthly Daily Monthly Daily Monthly Daily Monthly
--
0.14
34 12
0.02
0.17
0.44
0.21
0.04
0.29
0.79
--
11 27 20 11 7.6 15
0.05
0.03
633 378 — — 87
9.0 4.3 — — 9.0
31 13 -- -- 31
--
0 . 07
--
0.01
0 . 07
0. 16
0.13
0.03
0. 18
0.49

12
0 . 03
0. 03
50
4.3
13
TOTAL SUSPENDED SOLIDS   28




ZINC                  0.
                           18
                                 28
                                                                              44
                                                                                     63
                                                                                           31
                                                           E-2
-------
Appendix Fl. Production-based Limits for the Steel Forming and Finishing Subcategory
   Existing Source  Limits
                                              Manufacturing
                                               Operation
    TOTAL  SUSPENDED SOLIDS
    OIL AND  GREASE  (AS HEM)
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
    TOTAL  ORGANICS PARAMETER
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                        F-l
-------
Appendix Fl.  Production-based Limits for the Steel Forming and Finishing Subcategory
(continued)	
                                                  Manufacturing
                                                    Operation
                                               Acid Pickling
                                               Alkaline Cleaning
                                               Continuous Annealing
                                               Hot Dip Coating
                                               Pressure Deformation
                                               Lubrication
                                               Mechanical Descaling
                                               Painting
                                               Electroplating
                                               Acid Pickling
                                               Alkaline Cleaning
                                               Continuous Annealing
                                               Hot Dip Coating
                                               Pressure Deformation
                                               Lubrication
                                               Mechanical Descaling
                                               Painting
                                               Electroplating
    AMENABLE CYANIDE
                                               Electroplating
                                               Electroplating
    MANGANESE
                                               Acid Pickling
                                               Alkaline Cleaning
                                               Continuous Annealing
                                               Hot Dip Coating
                                               Pressure Deformation
                                               Lubrication
                                               Mechanical Descaling
                                               Painting
                                               Electroplating
                                               Acid Pickling
                                               Alkaline Cleaning
                                               Continuous Annealing
                                               Hot Dip Coating
                                               Pressure Deformation
                                               Lubrication
                                               Mechanical Descaling
                                               Painting
                                               Electroplating
                                                        F-2
-------
Appendix Fl. Production-based Limits for the Steel Forming and Finishing Subcategory
(continued)	
                                                   Manufacturing
                                                     Operation
                                                Hot  Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
    TOTAL  SULFIDE
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                        F-3
-------
Appendix F2. Production-based Limits for the Steel Forming and Finishing Subcategory
                                                 Manufacturing
                                                   Operation
    TOTAL  SUSPENDED SOLIDS
    OIL AND  GREASE  (AS HEM)
    TOTAL  ORGANICS PARAMETER
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                        F-4
-------
Appendix F2.  Production-based Limits for the Steel Forming and Finishing Subcategory
(continued)	
                                                Manufacturing
                                                  Operation
                                               Acid Pickling
                                               Alkaline Cleaning
                                               Continuous Annealing
                                               Hot Dip Coating
                                               Pressure Deformation
                                               Lubrication
                                               Mechanical Descaling
                                               Painting
                                               Electroplating
                                               Acid Pickling
                                               Alkaline Cleaning
                                               Continuous Annealing
                                               Hot Dip Coating
                                               Pressure Deformation
                                               Lubrication
                                               Mechanical Descaling
                                               Painting
                                               Electroplating
    AMENABLE CYANIDE
                                               Electroplating
                                               Electroplating
    MANGANESE
                                               Acid Pickling
                                               Alkaline Cleaning
                                               Continuous Annealing
                                               Hot Dip Coating
                                               Pressure Deformation
                                               Lubrication
                                               Mechanical Descaling
                                               Painting
                                               Electroplating
                                               Acid Pickling
                                               Alkaline Cleaning
                                               Continuous Annealing
                                               Hot Dip Coating
                                               Pressure Deformation
                                               Lubrication
                                               Mechanical Descaling
                                               Painting
                                               Electroplating
                                                        F-5
-------
Appendix F2. Production-based Limits for the Steel Forming and Finishing Subcategory
(continued)	
                                                 Manufacturing
                                                   Operation
                                                Hot  Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
    TOTAL  SULFIDE
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                Acid  Pickling
                                                Alkaline Cleaning
                                                Continuous Annealing
                                                Hot Dip Coating
                                                Pressure Deformation
                                                Lubrication
                                                Mechanical Descaling
                                                Painting
                                                Electroplating
                                                        F-6
-------