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Section 6.0 - Water Use and Wastewater Characterization
Table 6-16
Summaries of the Raw Wastewater Characterization Data for Each
Subcategory
Subcategory
Truck/Chemical
Rail/Chemical
Barge/Chemical & Petroleum
Truck/Petroleum
Truck/Food
Rail/Food
Barge/Food
Barge/Hopper
Number of Priority Pollutants
Detected
55
43
45
10
7
4
' 9 .
9
Number of Pollutants Detected
204
180
159
67
76
45
68
57
Subcategory
Truck/Chemical
Rail/Chemical
Barge/Chemical
& Petroleum
Truck/Petroleum
Truclt/Food
Rail/Food '
Barge/Food
Barge/Hopper
Range of Pollutant Concentrations (mg/L) - " .", J"v *
BOD^
320 to 6,000
260 to 4,200
120 to 26,000
48 to 110
160 to 5,200
NQ
890 to 6,800
17
COB
830 to 16,000
810 to 20,000
130 to 200,000
580 to 740
380 to 5,600
34,000
540 to 12,000
640
TOC ,
160 to 3,200
150 to 3,300
30 to 53,000
28 to 210
86 to 2,500
13,000
1,600 to
3,300
61
\TSS s
38 to 4,800
230 to 1,400
55 to 15,000
130 to 360
28 to 800
27
260 to 2,000
1,400
HEM
6.0 to 5,300
56 to 5,200
37 to 220,000
22 to 1,200
5.2 to 270
ND
75 to 1,100
ND
S&ErHEMk
5.0 to 450
18 to 750
21 to 98,000
5.0 to 410
5.0 to 26
ND
5.0 to 140
ND
ND-Not detected.
NQ - Not quantitated due to matrix interference.
BOD5- Biochemical oxygen demand (5-day).
COD - Chemical oxygen demand.
TOC - Total organic carbon.
TSS - Total suspended solids.
HEM - Hexane extractable material.
SGT-HEM - Silica-gel treated hexane extractable material.
6-64
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Section 6.0 - Water Use and Wastewater Characterization
Key:
-Primary Path
Secondary Path
Recycle & Reuse Stream
Solution
Make-Up
ir
Source
Water
A L
Fresh
Water
1 w
1 *•
TEC Interior
Cleaning:
Chemical Solution
A
if
TEC Interior
Cleaning: Water
A
Exterior Cleaning
Water
V
Hydrotesting Water
1
1
*
Contract Haul to
Treatment Works
A
'
Discharge to U.S.
Surface Waters
t
Discharge to
Treatment Works
*
1
I
fc> b
*
Msposal by:
Evaporation
Land Application
Deep-Well Injection
Incineration
Figure 6-1. Water Use Diagram for TEC Operations
6-65
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7.0
Section 7.0 - Pollutants Selected for Regulation
POLLUTANTS SELECTED FOR REGULATION
EPA conducted a study of Transportation Equipment Cleaning Industry (TECI)
wastewaters to determine the presence or absence of priority, conventional, and nonconventional
pollutant parameters. Priority pollutants parameters are defined in Section 307(a)(l) of the Clean
Water Act (CWA). The list of priority pollutant parameters, presented in Table 7-1, consists of
126 specific priority pollutants listed in 40 CFR Part 423, Appendix A. Section 301(b)(2) of the
CWA obligates EPA to regulate priority pollutants if they are determined to be present at
significant concentrations and it is technically and economically feasible. Section 304(a)(4) of
the CWA defines conventional pollutant parameters, which include biochemical oxygen demand
(BOD5), total suspended solids (TSS), total recoverable oil and grease (now referred to as hexane
extractable material or HEM), pH, and fecal coliform. These pollutant parameters are subject to
regulation as specified in Sections 304(b)(l)(A), 304(a)(4), 301(b)(2)(E), and 306 of the CWA.
Nonconventional pollutant parameters are those that are neither priority nor conventional
pollutant parameters. Sections 301(b)(2)(F) and 301(g) of the CWA give EPA the authority to
regulate nonconventional pollutant parameters, as appropriate, based on technical and economic
considerations.
This section presents the methodology used to select pollutants for regulation for
the TECI and includes the following topics:
• Section 7.1: The pollutants considered for regulation in the TECI;
• Section 7.2: The pollutants of interest for the TECI;
• Section 7.3: The pollutants effectively removed by EPA's regulatory
options;
• Section 7.4: Pollutant selection criteria for regulation for direct
dischargers;
• Section 7.5: Pollutant selection criteria for regulation for indirect
dischargers; and
7-1
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Section 7.0 - Pollutants Selected for Regulation
Section 7.6: References.
7.1
Pollutants Considered for Regulation
The Agency considered 4 conventional, 125 priority, and 348 nonconventional
pollutant parameters for potential regulation in the TECI. The nonconventional pollutants
include organics, metals, pesticides, herbicides, dioxins, and furans that do not appear on the list
of conventional or priority pollutants. The Agency analyzed TECI wastewater for these
pollutants during EPA's sampling program, which is discussed in Section 3.4.
7.2
Pollutants of Interest for the TECI
The first step in considering a pollutant for regulation was to determine if it is a
pollutant of interest for the TECI on a subcategory-by-subcategory basis. Pollutants of interest
were identified based on the raw transportation equipment cleaning (TEC) wastewater
characterization data (presented in Section 6.0). EPA considered the following two general
criteria to identify pollutants of interest:
1. The frequency of detection in subcategory wastewater characterization
samples; and
2. The average raw wastewater concentration at those facilities sampled for
treatment performance.
The first criterion indicates that the presence of the pollutant is representative of
the subcategory, rather than an isolated occurrence. The second criterion ensures that the
pollutant was present at treatable levels where EPA evaluated treatment performance.
Application of these two general criteria are described in Sections 7.2.1 through 7.2.4.
If wastewater characterization samples were collected at two or more facilities
within a subcategory, EPA considered pollutants detected at least two times in wastewater
7-2
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Section 7.0 - Pollutants Selected for Regulation
characterization samples as pollutants of interest for that subcategory. If wastewater
characterization samples were collected at only one facility within a subcategory, then only one
detect was required for consideration as a pollutant of interest. Where EPA sampling data shows
that a pollutant concentration is below the detection limit at all sampled facilities within a
subcategory, that pollutant is excluded from consideration as a pollutant of interest in that
subcategory.
EPA considered an average pollutant concentration of at least five times the
pollutant method detection limit to be a treatable level. To determine the average pollutant
concentration within each subcategory, EPA averaged both the detected and the nondetected
concentrations (nondetected concentrations were assumed to be equal to the pollutant detection
limit). For subcategories with treatment performance data from more than one facility, pollutants
present at treatable levels in the wastewater of at least one facility were considered pollutants of
interest for that subcategory.
EPA used a different approach for pesticide and herbicide pollutants because of
the relative toxicity of these pollutants. EPA considered a single detection of the pollutant in
wastewater characterization samples, regardless of the number of facilities sampled, sufficient to
consider the pollutant as a pollutant of interest. Also, the average raw wastewater concentration
at those facilities sampled for treatment performance only had to be greater than the method
detection limit for consideration as a pollutant of interest.
7.2.1
Truck/Chemical, Rail/Chemical, and Barge/Chemical &
Petroleum Subcategories
Wastewater characterization samples were analyzed for all 477 pollutants
considered for regulation. The same selection criteria were applied separately to the analytical
data available for the Truck/Chemical, Rail/Chemical, and Barge/Chemical & Petroleum
Subcategories to identify pollutants of interest. These include:
7-3
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Section 7.0 - Pollutants Selected for Regulation
For non-pesticide/herbicide pollutants, the pollutant was detected in at
least two TEC wastewater characterization samples.
For pesticide/herbicide pollutants, the pollutant was detected in at least
one TEC wastewater characterization sample.
For non-pesticide/herbicide pollutants, the average raw wastewater
concentration was at least five times the method detection limit.
For pesticide/herbicide pollutants, the average raw wastewater
concentration was greater than the method detection limit.
7.2.2
Truck/Food, Rail/Food, and Barge/Food Subcategories
Wastewater characterization samples were analyzed for all 477 pollutants
considered for regulation. Available characterization data for food grade facilities include five
days of sampling at a Barge/Food Subcategory facility, one day of sampling at a Truck/Food
Subcategory facility, and one day of sampling at a Rail/Food Subcategory facility.
EPA used wastewater treatment system performance data collected at one
Barge/Food facility to represent all three food grade subcategories. Samples collected at this one
facility were only analyzed for 190 pollutants including all 176 semi volatile organics and 14
classical pollutants. Volatile organics, pesticides, herbicides, dioxins, furans, metals, and six
classical pollutants (adsorbable organic halides, total cyanide, amenable cyanide, surfactants,
total sulfide, and volatile residue) were not analyzed because these analytes were not detected at
significant levels in wastewater characterization samples. The following selection criteria were
applied to identify pollutants of interest for the food grade subcategories. These include:
The pollutant was detected in at least one TEC wastewater characterization
sample; and
The average raw wastewater concentration was at least five times the
method detection limit.
7-4
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7.2.3
Section 7.0 - Pollutants Selected for Regulation
Truck/Petroleum and Rail/Petroleum Subcategories
In its analysis of facilities that cleaned tanks that last transported petroleum
cargos, EPA sampled one facility in the Truck/Petroleum Subcategory. Samples collected during
this sampling episode were analyzed for 318 pollutants including all 57 volatile organics, 176
semivolatile organics, 70 metals, and 15 of the 20 classical pollutants. Pesticides, herbicides,
dioxins, and furans were not analyzed because they were not expected to be present at significant
levels in wastewater characterization samples based on an engineering assessment of the cargos
cleaned and the cleaning processes used at these facilities. Five classical pollutants (adsorbable
organic halides, surfactants, total phenols, total sulfide, and volatile residue) were not analyzed
in this subcategory.
This one facility sampled in the Truck/Petroleum Subcategory treated only final
rinse wastewater on site. Initial rinses and other TEC wastewaters were contract hauled for off-
site treatment and were therefore not included in the sampling performed by EPA. There was no
additional data provided by the industry on raw TEC wastewater characteristics; therefore,
sampling data obtained from the Centralized Waste Treatment (CWT) Industry were also used to
characterize TEC wastewater for the Truck/Petroleum and Rail/Petroleum Subcategories (see
Section 3.5.1 for a discussion of the CWT data).
The only criterion used to identify pollutants of interest for the Truck/Petroleum
and Rail/Petroleum Subcategories was that the pollutant was detected at least once in samples of
the influent to wastewater treatment at either the TEC facility or the CWT facility. The second
criterion, developed to ensure that the pollutant was present at treatable levels, was not applicable
because EPA primarily considered zero discharge options for these Subcategories based on 100
percent recycle/reuse of TEC wastewater.
7-5
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7.2.4
Section 7.0 - Pollutants Selected for Regulation
Truck/Hopper, Rail/Hopper, and Barge/Hopper Subcategories
The Agency used the sampling data collected at one Barge/Hopper facility to
represent all three hopper subcategories. Samples collected during this sampling episode were
analyzed for 453 pollutants, 24 fewer than the usual 477 pollutants. These 24 pollutants include
the 17 dioxins and furans, 5 classical wet chemistry parameters (adsorbable organic halides,
surfactants, total phenols, total sulfide, and volatile residue), and 2 volatile organics (m-xylene
and o- + p-xylene). With the exception of the xylenes, these pollutants were not analyzed
because they were not expected to be present in TEC wastewater based on an assessment of the
cargos cleaned and the cleaning processes used by facilities in these subcategories. M-xylene
and o- + p-xylene were not analyzed because the laboratory inadvertently analyzed for m- + p-
xylene and o-xylene instead, which were not detected. The same selection criteria were applied
to the Truck/Hopper, Rail/Hopper, and Barge/Hopper Subcategories to identify pollutants of
interest. These include:
The pollutant was detected in the single TEC wastewater characterization
sample;
For non-pesticide/herbicide pollutants, the average raw wastewater
concentration was at least five times the method detection limit; and
For pesticide/herbicide pollutants, the average raw wastewater
concentration was greater than the method detection limit.
7.3
Pollutants Effectively Removed
The second step in considering a pollutant for regulation was to determine if a
pollutant of interest was effectively removed by one or more of the wastewater treatment
technology options evaluated for each subcategory and discharge type (i.e., indirect and direct).
(The options considered for each subcategory are discussed in Section 9.0). This criterion
ensures that EPA does not select for regulation pollutants that are not removed or controlled by
the technology options considered by the Agency. In developing the technology options, EPA
7-6
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Section 7.0 - Pollutants Selected for Regulation
attempted to identify pollutant control technologies or combinations of pollutant control
technologies that control all of the pollutants of interest for each subcategory.
EPA determined if a pollutants was effectively removed by analyzing the percent
reduction achieved by the technology option. This criterion ensures that the pollutant was
demonstrated to be controlled by the technology option. The criterion was applied to the base
technology option and to each incremental technology option individually. For example, EPA's
criterion for hypothetical pollutant X for indirect dischargers for Subcategory Y was at least a
50% reduction in the pollutant concentration. Technology A removed the pollutant X by 20%.
Technology B removed the pollutant X by 30%, and Technology C removed the pollutant X by
80%. Pollutant X is effectively removed for Subcategory Y indirect dischargers because it was
removed by at least 50% by Technology C. Specifically, pollutant X is a pollutant effectively
removed only for the regulatory options that include Technology C.
EPA used a different approach, however, for pesticide and herbicide pollutants
because of the relative toxicity of these pollutants. EPA considered pollutants with percent
reductions greater than zero to be pollutants effectively removed. These pollutants were often
detected at concentrations close to their sample detection limits and were commonly treated to
nondetectable levels by pollutant control technologies. Because of analytical limitations, it is
difficult to determine the actual percent reduction of these pollutants. However, EPA considered
a reduction from levels above the detection limit in the untreated wastewater to nondetect levels
in treated effluent to represent treatment of these pollutants.
EPA considered the following two criteria to identify pollutants effectively
removed for all subcategories except for the Truck/Petroleum and Rail/Petroleum Subcategories:
For non-pesticide/herbicide pollutants, the average pollutant concentration
was at least five times the method detection limit in the influent to the
proposed technology option.
7-7
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Section 7.0 - Pollutants Selected for Regulation
For pesticide/herbicide pollutants, the average pollutant concentration was
greater than the method detection limit in the influent to the proposed
technology option.
For non-pesticide/herbicide pollutants, the pollutant was reduced by at
least 50% by the proposed technology option.
For pesticide/herbicide pollutants, the pollutant was reduced by greater
than 0% by the proposed technology option.
Note that EPA did not analyze for dioxins and furans in treated wastewater samples at facilities
sampled to assess wastewater treatment performance. Although EPA believes that these
pollutants may be removed by the control technologies (based on nondetect levels measured in
limited final effluent wastewater characterization samples), the Agency did not consider these
data to be sufficient to consider dioxins and furans as pollutants effectively removed.
EPA believes that concentrations of dioxins and furans above the detection limit
in untreated wastewater samples were isolated, site-specific instances, and that dioxins and
furans typically are not present in concentrations above the detection limit in TEC wastewaters.
Where dioxins and furans are present, EPA has concluded that these pollutants are either
predominantly partitioned in the oil phase of the wastewater or are associated with the suspended
solids, and therefore will be detected at only trace levels, if at all, in TEC wastewater.
Tables 7-2 through 7-6 present the pollutants effectively removed by the proposed
technology option by subcategory and discharge type as follows:
Table 7-2: Pollutants Effectively Removed for Truck/Chemical
Subcategory Direct Dischargers;
Table 7-3: Pollutants Effectively Removed for Rail/Chemical
Subcategory Direct Dischargers;
Table 7-4: Pollutants Effectively Removed for Rail/Chemical
Subcategory Direct Dischargers (NSPS);
7-8
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Section 7.0 - Pollutants Selected for Regulation
Table 7-5: Pollutants Effectively Removed for Barge/Chemical &
Petroleum Subcategory Direct Dischargers; and
Table 7-6: Pollutants Effectively Removed for Truck/Food, Rail/Food,
and Barge/Food Subcategory Direct Dischargers.
For the Truck/Petroleum and Rail/Petroleum Subcategories, EPA primarily
considered zero discharge options for these subcategories based on 100% recycle/reuse of TEC
wastewater. Because a zero discharge option eliminates discharge of pollutants (i.e., complete or
100% removal), EPA considered all pollutants of interest for these subcategories to be pollutants
effectively removed.
7.4
Pollutant Selection Criteria for Direct Dischargers
The pollutants selected for regulation for each Subcategory were chosen from the
list of pollutants effectively removed discussed in Section 7.3 and listed in Tables 7-2,7-3, 7-4,
7-5, and 7-6 at the end of this section. From these lists, EPA selected a subset of pollutants to
establish numerical effluent limitations. Due to the wide range of cargos transported in tanks
cleaned by TEC facilities, and due to the limited amount of data available, it would be very
difficult to establish numerical limitations for all of the pollutants which may be found in TECI
wastewaters. Additionally, monitoring for all pollutants effectively removed is not necessary to
ensure that TECI wastewater pollution is adequately controlled, since many of the pollutants .
originate from similar sources, have similar treatabilities, and are expected to be removed by the
same mechanisms and treated to similar levels.
Therefore, rather than set effluent limitations for all pollutants detected in EPA's
wastewater characterization and wastewater treatment effectiveness sampling episodes, EPA
attempted to select a group of pollutants that were frequently detected in TECI wastewater and
whose control through a combination of physical and chemical treatment processes would lead to
the control of a wide range of pollutants with similar properties. Compounds selected for
regulation were selected to be representative of the various groups of compounds found to be
7-9
-------
Section 7.0 - Pollutants Selected for Regulation
effectively treated in each of the regulated subcategories. Specific compounds selected vary for
each of the subcategories, but include compounds from various groups including metals,
conventionals and organics. Organic compounds were selected to be representative of the
various groups of organic compounds detected (hydrocarbons, organohalogens, carboxylic acid
derivatives, phthalic acid esters, etc.). In addition, priority pollutants which were detected at
treatable levels and were demonstrated to be effectively removed were selected for regulation.
Pollutants determined to be effectively removed were selected for regulation
based on the following criteria:
EPA selected pollutants that were detected most frequently in TECI
wastewater. Generally, this meant that a pollutant had to be detected at
least four times in wastewater characterization samples for the
Truck/Chemical and Barge/Chemical & Petroleum Subcategories, and at
least three times in the Rail/Chemical Subcategory. Priority pollutants
which were effectively removed and were present at significant
concentrations in wastewaters, but were not detected at the frequencies
described above, were also considered for regulation.
EPA selected pollutants that were detected at significant concentrations in
raw wastewater at those facilities sampled for treatment performance.
Generally, the average pollutant concentration in raw wastewater had to be
at least 10 times the method detection limit (MDL) to be considered for
regulation. Priority pollutants that were effectively removed and that were
detected frequently in the industry, but whose average concentration was
less than 10 times the MDL, were also considered for regulation.
EPA did not select pesticides or herbicides for regulation.
EPA did not select chemicals that are used in wastewater treatment
operations of the proposed treatment technology option.
EPA did not select pollutant parameters that were not considered toxic.
EPA is not proposing to establish limits for pesticides or herbicides in any
subcategory for several reasons. First, pesticides were generally found at very low levels in raw
wastewater. Second, the treatment technologies sampled and proposed by EPA were found to
7-10
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Section 7.0 - Pollutants Selected for Regulation
incidentally remove pesticides and herbicides from the wastewater. The proposed treatment
technologies in each subcategory treated most pesticides and herbicides to non-detect levels in
the effluent. Therefore, especially considering the high cost of pesticide/herbicide monitoring,
EPA has determined that it is unnecessary to set nationally-applicable discharge standards for
specific pesticides or herbicides.
EPA is also not proposing to establish limits for phenol in any subcategory.
Based on the small number of direct dischargers present in the industry, EPA feels that local
permitting authorities can decide whether establishing discharge limitations based on water
quality considerations is appropriate. For indirect dischargers, phenol is readily biodegradable
and is not expected to pass through a publicly-owned treatment works (POTW).
For direct discharging facilities, EPA is proposing to regulate the conventional
pollutant oil and grease but is not proposing to regulate the nonconyentional pollutant total
petroleum hydrocarbons. The analysis for oil and grease quantifies the total amount of oil and
grease present in the wastewater, and includes both petroleum based oils and greases as well as
edible oils from vegetables or fish. Total petroleum hydrocarbons, however, quantifies only the
petroleum based fraction. EPA believes that it is unnecessary to establish effluent limitations for
both oil and grease and total petroleum hydrocarbons because the petroleum component present
in the wastewater is a subset of the total oil and grease measurement. EPA therefore concluded
that establishing effluent limitations for both oil and grease and total petroleum hydrocarbons
would be redundant for direct discharging facilities.
Based on the methodology described above, EPA feels that it has selected
pollutants for regulation in each subcategory which will provide adequate control for the wide
range of pollutants which may be found in TECI wastewaters. Listed below are the pollutants
selected for regulation in each subcategory. Note that the Agency has chosen not to regulate
direct dischargers in the Truck/Hopper, Rail/Hopper, Barge/Hopper, Truck/Petroleum, and
Rail/Petroleum Subcategories.
7-11
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7.4.1
Section 7.0 - Pollutants Selected for Regulation
Pollutants Selected for Regulation for Truck/Chemical Direct
Dischargers
EPA is proposing to establish BPT, BCT, BAT and NSPS limitations for the
Truck/Chemical Subcategory. The following pollutants were not selected for regulation because
they are not present at treatable concentrations or are not likely to cause toxic effects: alpha
terpineol, benzene, benzoic acid, benzyl alcohol, chloroform, dimethyl sulfone, n-decane,
-triacontane, o-cresol, p-cresol, p-cymene, trichchloroethene, 2-methylnaphthalene, 2-
chlorophenol, 2-isopropylnaphthalene, boron, copper, mercury, phosphorus, silicon, tin, and
titanium.
The following pollutants were not selected for regulation because they are
commonly used in the industry as wastewater treatment chemicals: aluminum, iron, and
manganese.
The following pollutants were not selected for regulation because they are likely
to be volatilized in the treatment system and are therefore not considered to be treated by the
proposed technology: acetone, 1,2-dichloroethane, ethylbenzene, methyl ethyl ketone, methyl
isobutyl ketone, methylene chloride, tetrachloroethene, toluene, 1,1,1-trichloroethane, m-xylene,
o- + p-xylene, and naphthalene.
The following pollutants were not selected for regulation because they are
controlled through the regulation of other pollutants: n-docosane, n-eicosane, n-hexacosane, n-
octadecane, n-tetracosane, and n-tetradecane.
EPA is therefore proposing limitations for BODS TSS, oil and grease (HEM),
chromium, zinc, COD, bis (2-ethylhexyl) phthalate, di-n-octyl phthalate, n-dodecane, n-
hexadecane, styrene, and 1,2-dichlorobenzene.
7-12
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Section 7.0 - Pollutants Selected for Regulation
7.4.2
Pollutants Selected for Regulation for Rail/Chemical Direct
Dischargers
For the Rail/Chemical Subcategory, EPA is proposing to establish BPT, BCT,
BAT and NSPS limitations. The following pollutants were not selected for regulation because
they are not present at treatable concentrations or are not likely to cause toxic effects: acetone,
benzoic acid, carbazole, dimethyl sulfone, ethylbenzene, o-+p xylene, 1-methylphenanthrene, 2-
methylnapthalene, naphthalene, n-octacosane, styrene, and n-triacontane.
The following pollutant was not selected for regulation because it are commonly
used in the industry as a wastewater treatment chemical: aluminum.
The following pollutant was not selected for regulation because it is likely to be
volatilized in the treatment system and are therefore not considered to be treated by the proposed
technology: m-xylene.
The following pollutants were not selected for regulation because they are
controlled through the regulation of other pollutants: n-docosane, n-eicosane,.n-hexacosane, n-
octadecane, and n-tetracosane.
EPA is therefore proposing to regulate BOD5 TSS, oil and grease (HEM), COD,
n-dodecane, n-hexadecane, n-tetradecane, anthracene, pyrene, fluoranthene, and phenanthrene.
7.4.3
Pollutants Selected for Regulation for Barge/Chemical &
Petroleum Direct Dischargers
For the Barge/Chemical & Petroleum Subcategory, EPA is proposing to establish
BPT, BCT, BAT and NSPS limitations. The following pollutants were not selected for
regulation because they were present only in trace amounts, are not present at treatable
concentrations, or are not likely to cause toxic effects: acenaphthylene, acrylonitrile, anthracene,
7-13
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Section 7.0 - Pollutants Selected for Regulation
benzole acid, chloroform, methylene chloride, 2,3,-benzofluorene, n-octacosane, mercury,
osmium, ruthenium, silicon and titanium.
The following pollutants were not selected for regulation because they are
commonly used in the industry as wastewater treatment chemicals: aluminum, iron, magnesium,
and manganese.
The following pollutants were not selected for regulation because they are likely
to be volatilized in the treatment system and are therefore not considered to be treated by the
proposed technology: acetone, benzene, ethylbenzene, methyl ethyl ketone, methyl isobutyl
ketone, toluene, m-xylene, o-+p-xylene, acenaphthene, biphenyl, fluorene, naphthalene,
phenanthrene, and styrene.
The following pollutants were not selected for regulation because they are
controlled through the regulation of other pollutants: 3,6-dimethylphenanthrene, n-hexacosane,
n-hexadecane, 1-methylfluorene, 2-methymaphthalene, and pentamethylbenzene.
EPA is therefore proposing to regulate BOD5, TSS, oil and grease (HEM), COD,
cadmium, chromium, copper, lead, nickel, zinc, 1-methylphenanthrene, bis (2-ethylhexyl)
phthalate, di-n-octyl phthalate, n-decane, n-docosane, n-dodecane, n-eicosane, n-octadecane, n-
tetracosane, n-tetradecane, p-cymene, and pyrene.
7.4.4
Pollutants Selected for Regulation for Truck/Food, Rail/Food,
and Barge/Food Direct Dischargers
EPA is proposing to establish BPT, BCT, and NSPS limitations for the
Truck/Food, Rail/Food, and Barge/Food Subcategories for BOD5, TSS, and oil and grease
(HEM).
7-14
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7.5
Section 7.0 - Pollutants Selected for Regulation
Pollutant Selection Criteria for Indirect Dischargers
Section 307(b) of the CWA requires the Agency to promulgate pretreatment
standards for existing sources (PSES) and new sources (PSNS). To establish pretreatment
standards, EPA must first determine whether each BAT pollutant under consideration passes
through a POTW, or interferes with the POTW's operation or sludge disposal practices.
The Agency evaluated POTW pass-through for the TEC pollutants of interest for
all subcategories where EPA is proposing to regulate priority and nonconventional pollutants. In
determining whether a pollutant is expected to pass through a POTW, the Agency compared the
nation-wide average percentage of a pollutant removed by well-operated POTWs with secondary
treatment to the percentage of a pollutant removed by BAT treatment systems. A pollutant is
determined to "pass through" a POTW when the average percentage removal achieved by a well-
operated POTW (i.e. those meeting secondary treatment standards) is less than the percentage
removed by the industry's direct dischargers that are using the proposed BAT technology.
This approach to the definition of pass-through satisfies two competing objectives
set by Congress: 1) that wastewater treatment performance for indirect dischargers be equivalent
to that for direct dischargers, and 2) that the treatment capability and performance of the POTW
be recognized and taken into account in regulating the discharge of pollutants from indirect
dischargers. Rather than compare the mass or concentration of pollutants discharged by the
POTW with the mass or concentration of pollutants discharged by a BAT facility, EPA compares
the percentage of the pollutants removed by the BAT treatment system with the POTW removal.
EPA takes this approach because a comparison of mass or concentration of pollutants in a POTW
effluent to pollutants in a BAT facility's effluent would not take into account the mass of
pollutants discharged to the POTW from non-industrial sources, nor the dilution of the pollutants
in the POTW effluent to lower concentrations from the addition of large amounts of non-
industrial wastewater.
7-15
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Section 7.0 - Pollutants Selected for Regulation
To establish the performance of well-operated POTWs, EPA primarily compiled
POTW percent-removal data from previous effluent guidelines rulemaking efforts, which have
established national POTW percent-removal averages for a broad list of pollutants. These
guidelines have used the information provided in "The Fate of Priority Pollutants in Publicly
Owned Treatment Works", commonly referred to as the 50 POTW Study. For those pollutants
not found in the 50 POTW study, EPA used data from EPA's National Risk Management
Research Laboratory's (RREL) treatability database. These studies were discussed previously in
Section 3.0.
In order to perform the TEC pass-through analysis, EPA was able to use percent
removal rates generated for the rulemaking efforts from the Metal Products and Machinery
(MP&M) Industry (1), the Centralized Waste Treatment (CWT) Industry (2), the Industrial
Laundries Industry (3), and the Pesticide Manufacturing Industry (4).
In order to determine removal rates for total petroleum hydrocarbons, EPA
applied the methodology developed for the Industrial Laundries proposal (3), which determined
an average POTW removal rate of 65 percent. The Agency is in the process of reviewing this
methodology and removal rate.
For indirect dischargers, EPA did not conduct the pass through analysis on the
conventional pollutant oil and grease because of a POTWs ability to treat the non-petroleum
based oils and greases, such as animal fats and vegetable oils. EPA instead conducted the pass
through analysis only on total petroleum hydrocarbons. Total petroleum hydrocarbons quantifies
the petroleum based fraction of oil and grease which may not be treated as effectively in a POTW
as with the BAT treatment technology. In cases where EPA has demonstrated that the proposed
BAT treatment technology will achieve greater removals for the petroleum fraction of oils and
grease, (i.e., total petroleum hydrocarbons), EPA is proposing to establish pretreatment standards
for total petroleum hydrocarbons.
7-16
-------
Section 7.0 - Pollutants Selected for Regulation
Based on the criteria described above, EPA selected pollutants for regulation for
each of the subcategories proposed for regulation. Note that the Agency has chosen not to
regulate indirect dischargers in the Truck/Hopper, Rail/Hopper, Barge/Hopper, Truck/Petroleum,
Rail/Petroleum, Truck/Food, Rail/Food, and Barge/Food Subcategories.
The following sections give the results of the pass-through analysis for each
subcategory. The pass-through analysis was not conducted for the conventional pollutants
(BOD5, TSS, pH, and oil and grease) proposed to be regulated for direct dischargers because
conventional pollutants are not regulated under PSES and PSNS. Pollutants in each subcategory
and technology option that were demonstrated to pass-through a POTW were considered for
regulation. The results of the pass-through analysis for the Truck/Chemical, Rail/Chemical, and
Barge/Chemical & Petroleum Subcategories are listed in Tables 7-7, 7-8, and 7-9.
7.5.1
Pollutants Selected for Regulation for Truck/Chemical Indirect
Dischargers
EPA is proposing to establish PSES and PSNS limitations for the Truck/Chemical
Subcategory. Based on the pass-through analysis, EPA determined that the following pollutants
passed through a POTW and is therefore proposing to establish pretreatment standards for
chromium, zinc, COD, bis (2-ethylhexyl) phthalate, di-n-octyl phthalate, n-dodecane, n-
hexadecane, styrene, and 1,2-dichlorobenzene.
7.5.2
Pollutants Selected for Regulation for Rail/Chemical Indirect
Dischargers
For the Rail/Chemical Subcategory, EPA is proposing to establish PSES and
PSNS limitations. Based on the pass-through analysis, EPA determined that the following
pollutants passed through a POTW and is therefore proposing to establish pretreatment standards
for total petroleum hydrocarbons (SGT-HEM), COD, n-hexadecane, n-tetradecane, and
fluoranthene.
7-17
-------
7.5.3
Section 7.0 - Pollutants Selected for Regulation
Pollutants Selected for Regulation for Barge/Chemical &
Petroleum Indirect Dischargers
For the Barge/Chemical & Petroleum Subcategory, EPA is proposing to establish
PSNS limitations only. Based on the pass-through analysis, EPA determined that the following
pollutants passed through a POTW and is therefore proposing to establish pretreatment standards
for total petroleum hydrocarbons (SGT-HEM), COD, cadmium, chromium, copper, lead, nickel,
zinc, 1-methylphenanthrene, bis (2-ethylhexyl) phthalate, di-n-octyl phthalate, n-decane, n-
docosane, n-dodecane, n-eicosane, n-octadecane, n-tetracosane, n-tetradecane, p-cymene, and
pyrene.
7.6
References
1.
2.
3.
4.
U.S. Environmental Protection Agency. Development Document for Proposed
Effluent Limitations Guidelines and Standards for the Metals Products and
Machinery Phase I Point Source Category. EPA821-R-95-021, April 1995.
U.S. Environmental Protection Agency. DevelopmentDocumsnt for Proposed
Effluent Limitations Guidelines and Standards for the Centralized Waste
Treatment Industry. EPA 821-R-95-006, January 1995.
U.S. Environmental Protection Agency. Development Document for Proposed
Pretreatment Standards for Existing and New Sources for Industrial Laundries
Point Source Category. EPA 821-R-97-007, November, 1997.
U.S. Environmental Protection Agency. Development Document for Effluent
Limitations Guidelines and New Source Performance Standards for Pesticide
Chemical Manufacturers. EPA 821-R-93-016, September 1993.
7-18
-------
Section 7.0 - Pollutants Selected for Regulation
Table 7-1
Priority Pollutant List (a)
1 Acenaphthene
2 Acrolein
3 Acrylonitrile
4 Benzene
5 Benzidine
6 Carbon Tetrachloride (Tetrachloromethane)
7 Chlorobenzene
8 1,2,4-Trichlorobenzene
9 Hexachlorobenzene
10 1,2-Dichloroethane
11 1,1,1-Trichloroethane
12 Hexachloroethane
13 1,1-Dichloroethane
14 1,1,2-Trichloroethane
15 1,1,2,2-Tetrachloroethane
16 Chloroethane
17 Removed
18 Bis (2-chloroethyl) Ether
19 2-Chloroethyl Vinyl Ether (mixed)
20 2-Chloronaphthalene
21 2,4,6-Trichlorophenol
22 Parachlorometa Cresol (4-Chloro-3-Methylphenol)
23 Chloroform (Trichloromethane)
24 2-Chlorophenol
25 1,2-Dichlorobenzene
26 1,3-Dichlorobenzene
27 1,4-Dichlorobenzene
28 3,3'-Dichlorobenzidine
29 1,1-Dichloroethene
30 1,2-Trans-Dichloroethene
31 2,4-Dichlorophenol
32 1,2-Dichloropropane
33 1,3-Dichloropropylene (Trans-1,3-Dichloropropene)
34 2,4-Dimethylphenol
35 2,4-Dinitrotoluene
36 2,6-Dinitrotoluene
37 1,2-Diphenylhydrazine
38 Ethylbenzene
39 Huoranthene
40 4-Chlorophenyl Phenyl Ether
41 4-Bromophenyl Phenyl Ether
42 Bis (2-chloroisopropyl) Ether
43 Bis (2-chloroethoxy) Methane
44 Methylene Chloride (Dichloromethane)
45 Methyl Chloride (Chloromethane)
46 Methyl Bromide (Bromomethane)
47 Bromoform (Tribromomethane)
48 Dichlorobromomethane (Bromodichloromethane)
49 Removed
50 Removed
51 Chlorodibromomethane (Dibromochloromethane)
52 Hexachlorobutadiene
53 Hexachlorocyclopentadiene
54 Isophorone
55 Naphthalene
56 Nitrobenzene
57 2-Nitrophenol
58 4-Nitrophenol
59 2,4-Dinitrophenol
60 4,6-Dinitro-o-Cresol (Phenol, 2-methyl-4,6-dinitro)
61 N-Nitrosodimethylamine
62 N-Nitrosodiphenylamine
63 N-Nitrosodi-n-propylamine (Di-n-propylnitrosamine)
64 Pentachlorophenol
65 Phenol
66 Bis (2-ethylhexyl) Phthalate
67 Butyl Benzyl Phthalate
68 Di-n-butyl Phthalate
69 Di-n-octyl Phthalate
70 Diethyl Phthalate
71 Dimethyl Phthalate
72 Benzo(a)anthracene (1,2-Benzanthracene)
73 Benzo(a)pyrene (3,4-Benzopyrene)
74 Benzo(b)fluoranthene (3,4-Benzo fluoranthene)
75 Benzo(k)fluoranthene (11,12-Benzofluoranthene)
76 Chrysene
77 Acenaphthylene
78 Anthracene
79 Benzo(ghi)perylene (1,12-Benzoperylene)
80 Huorene
81 Phenanthrene
82 Dibenzo(a,h)anthracene (1,2,5,6-Dibenzanthracene)
83 Indeno(l,2,3-cd)pyrene (2,3-o-Phenylenepyrene)
84 Pyrene
85 Tetrachloroethylene (Tetrachloroethene)
86 Toluene
87 Trichloroethylene (Trichloroethene)
88 Vinyl Chloride (Chloroethylene)
89 Aldrin
90 Dieldrin
91 Chlordane (Technical Mixture & Metabolites)
92 4,4'-DDT(p,p'-DDT)
93 4,4'-DDE (p,p'-DDX)
94 4,4'-DDD (p,p'-TDE)
95 Alpha-endosulfan
96 Beta-endosulfan
97 Endosulfan Sulfate
98 Endrin
99 Endrin Aldehyde
100 Heptachlor
101 Heptachlor Epoxide
102 Alpha-BHC
103 Beta-BHC
104 Gamma-BHC (Lindane)
105 Delta-BHC
106 PCB-1242 (Arochlor 1242)
107 PCB-1254 (Arochlor 1254)
108 PCB-1221 (Arochlor 1221)
109 PCB-1232 (Arochlor 1232)
110 PCB-1248 (Arochlor 1248)
111 PCB-1260 (Arochlor 1260)
112 PCB-1016 (Arochlor 1016)
113 Toxaphene
114 Antimony (total)
115 Arsenic (total)
116 Asbestos (fibrous)
117 Beryllium (total)
118 Cadmium (total)
119 Chromium (total)
120 Copper (total)
121 Cyanide (total)
122 Lead (total)
123 Mercury (total)
124 Nickel (total)
125 Selenium (total)
126 Silver (total)
127 Thallium (total)
128 Zinc (total)
129 2,3.7,8-Tetrachlorodibenzo-p-Dioxin
Source: Clean Water Act
(a) Priority pollutants are numbered 1 through 129 but include 126 pollutants since EPA removed three pollutants from the list (Numbers 17,
49, and 50).
7-19
-------
Section 7.0 - Pollutants Selected for Regulation
Table 7-2
Pollutants Effectively Removed for Truck/Chemical Subcategory
Direct Dischargers for Proposed BPT, BCT, BAT, and NSPS Option 2
CAS
Number
1CAS
Number
' Analyte ' ' ';
Volatile Organics - '" ' „ / /, '-"-'
67641
71432
67663
107062
100414
78933
108101
ACETONE
BENZENE
CHLOROFORM
1,2-DICHLOROETHANE
ETHYLBENZENE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
75092
127184
108883
71556
79016
108383
136777612
METHYLENE CHLORIDE
TETRACHLOROETHENE
TOLUENE
1 , 1 , 1 -TRICHLOROETHANE
TRICHLOROETHENE
M-XYLENE
O- + P-XYLENE
Semivolatile Organics - ?
98555
65850
100516
117817
95578
95487
106445
99876
124185
95501
67710
117840
629970
ALPHA-TERPINEOL
BENZOICACID
BENZYL ALCOHOL
BIS(2-ETHYLHEXYL) PHTHALATE
2-CHLOROPHENOL
O-CRESOL
P-CRESOL
P-CYMENE
N-DECANE
1,2-DICHLOROBENZENE
DIMETHYL SULFONE
DI-N-OCTYL PHTHALATE
N-DOCOSANE
112403
112958
630013
544763
2027170
91576
91203
593453
108952
100425
646311
629594
638686
N-DODECANE
N-EICOSANE
N-HEXACOSANE
N-HEXADECANE
2-ISOPROPYLNAPHTHALENE
2-METHYLNAPHTHALENE
NAPHTHALENE
N-OCTADECANE
PHENOL
STYRENE
N-TETRACOSANE
N-TETRADECANE
N-TRIACONTANE
Organo-Phosphorus Pesticides . , '"
2642719
86500
56724
97176
298044
AZINPHOS ETHYL
AZINPHOS METHYL
COUMAPHOS
DICHLOFENTHION
DISULFOTON
2104645
21609905
150505
22248799
EPN
LEPTOPHOS
MERPHOS
TETRACHLORVENPHOS
Organo-Halide Pesticides - _
319857
58899
BETA-BHC 1133213659
GAMMA-BHC || 1031078
ENDOSULFANH
ENDOSULFAN SULFATE
7-20
-------
Section 7.0 - Pollutants Selected for Regulation
Table 7-2 (Continued)
- GAS
Number
5103742
510156
50293
2303164
60571
''", '^
Analyte ' ;/- *-,/;,
GAMMA-CHLORDANE
CHLOROBENZELATE
4,4'-DDT
DIALLATE
DffiLDRIN
: OAS
; ' ^Namber , \
.1836755 .
82688
122349
5915413
- ' / Analyte ; , ' v'"Jl
NTIROFEN
PENTACHLORONITROBENZENE
SBVLAZINE
TERBUTHYLAZINE
Phenoxy-Acid Herbicides N , ^ ' ', - , - ' * {
94757
94826
75990
88857
94746
2,4-D
2,4-DB (BUTOXON)
DALAPON
DINOSEB
MCPA
7085190
1918021
93765
93721
MCPP
PICLORAM
2,4,5-T
2,4,5-IP
Metejs ' ^ '<,,,"••"',,'' '- " ^ >, '-/
7429905
7440428
7440473
7440508
18540299
7439896
7439965
ALUMINUM
BORON
CHROMIUM
COPPER
HEXAVALENT CHROMIUM
IRON
MANGANESE
7439976
7723140
7440213
7440315
7440326
7440666
Classical Pollutants - \ ' -,!'.,
7664417
59473040
C002
C004
16984488
COOS
AMMONIA AS NITROGEN
ADSORBABLE ORGANIC HALIDES
(AOX)
BOD 5-DAY (CARBONACEOUS)
CHEMICAL OXYGEN DEMAND
(COD)
FLUORIDE
NITRATE/NITRITE
U014
C012
C020
14265442
C036
C009
MERCURY
PHOSPHORUS
SILICON
TIN
TITANIUM
ZINC
- ^ ys\. J ^
SURFACTANTS (MBAS)
TOTAL ORGANIC CARBON (TOC)
TOTAL PHENOLS
TOTAL PHOSPHORUS
HEXANE EXTRACTABLE
MATERIAL
TOTAL SUSPENDED SOLIDS
7-21
-------
Section 7.0 - Pollutants Selected for Regulation
Table 7-3
Pollutants Effectively Removed for Rail/Chemical Subcategory
Direct Dischargers for Proposed BPT, BCT, and BAT Option 1
CAS
Number
Analyte
' CAS
Number
f •! V'
X J
Analyte
Volatile Organics ' / *
67641
100414
ACETONE I! 108383
ETHYLBENZENE || 136777612
m-XYLENE
o--t-p-XYLENE
Semivolatile Organics > ^'" '''*,'",'?'„,', /',
120127
65850
86748
67710
629970
112403
112958
206440
630013
544763
91576
ANTHRACENE
BENZOICACID
CARBAZOLE
DIMETHYL SULFONE
N-DOCOSANE
N-DODECANE
N-EICOSANE
ELUORANTHENE
N-HEXACOSANE
N-HEXADECANE
2-METHYLNAPHTHALENE
832699
91203
630024
593453
85018
108952
129000
100425
646311
629594
638686
1-METHYLPHENANTHRENE
NAPHTHALENE
N-OCTACOSANE
N-OCTADECANE
PHENANTHRENE
PHENOL
PYRENE
STYRENE
N-TETRACOSANE
N-TETRADECANE
N-TRIACONTANE
Organo-Phosphorus Pesticides ~- - * ~
78342
22248799
34643464
DIOXATfflON
TETRACHLORVINPHOS
TOKUTHION
52686
327980
512561
TRICHLORFON
TRICHLORONATE
TRIMETHYLPHOSPHATE
Organo-Halide Pesticides - " -\ '/",;' ''"""" -~" '''" "v -"/s#' ";-(
30560191
15972608
1861401
319857
319868
58899
23184669
2425061
786196
5103719
1861321
ACEPHATE
ALACHLOR
BENEFLURALIN
BETA-BHC
DELTA-BHC
GAMMA-BHC
BUTACHLOR
CAPTAFOL
CARBOPHENOTfflON
ALPHA-CHLORDANE
DACTHAL (DCPA)
60571
1031078
7421934
465736
21087649
1836755
72560
1918167
139402
122349
8001501
DffiLDRIN
ENDOSULFAN SULFATE
ENDRIN ALDEHYDE
ISODRIN
METRIBUZIN
NTTROFEN
PERTHANE
PROPACHLOR
PROPAZINE
SIMAZINE
STROBANE
7-22
-------
Section 7.0 - Pollutants Selected for Regulation
Table 7-3 (Continued)
s CAS
Number
72548
50293
2303164
•• * ^ * , ^'^
%s , ~* f 'i^'* * .? ^e*
Anaiyte;> l_ ;
4,4'-DDD
4,4'-DDT
DIALLATE
!-,-C^\ ,
Number
5902512
43121433
1582098
' * i *' ' " '," A ' ' ' '•~-"'X%,';> ^
s ^ * ^ "" ', S ^ \ ' '^ '$^%
A ; ,,AMaiyte,- ,1 , '-i."^i
TERBACEL
TRIADIMEFON
TRIFLURALIN
Phenoxy-Acid Herbicides N '"''-,"' V \i ' ' - ?- % V,
94757
75990
120365
2,4-D
DALAPON
DICHLOROPROP
88857
93765
DINOSEB
2,4,5-T
Metals, , / ,.,-'( '-~''' ' .'/',- .1'^ ,'$ ? -"",^ .„ -/ • ''' >:\. >\ Vs- , S^ ,/V "- ' <"- >
7429905
ALUMBSIUM ||
"Classical Pollutants^ , ' -f ///-'- v/> ;;,/ *"-'\ •• , v _ ,_ ^ '^;%,
-------
Section 7.0 - Pollutants Selected for Regulation
Table 7-4
Pollutants Effectively Removed for Rail/Chemical Subcategory
Direct Dischargers for Proposed NSPS Option 3
CAS
Number
1CAS
Number; ;
Volatile Organics , ' ,,'
67641
100414
78933
ACETONE
ETHYLBENZENE
METHYL ETHYL KETONE
108383
136777612
J ';',;' * ,?
, , Analyte , s ;
' ' " f ** <.*- f S s •- '/ X'
M-XYLENE
O- + P-XYLENE
Semivolatile Organics ,, r ' ^ , f / ,- '......' \
120127
65850
86748
106445
95807
67710
629970
112403
112958
206440
630013
544763
ANTHRACENE
BENZOICACID
CARBAZOLE
P-CRESOL
2,4-DIAMINOTOLUENE
DIMETHYL SULFONE
N-DOCOSANE
N-DODECANE
N-HCOSANE
FLUORANTHENE
N-HEXACOSANE
N-HEXADECANE
91576
832699
91203
630024
593453
85018
108952
129000
100425
646311
629594
638686
2-METHYLNAPHTHALENE
1-METHYLPHENANTHRENE
NAPHTHALENE
N-OCTACOSANE
N-OCTADECANE
PHENANTHRENE
PHENOL
PYRENE
STYRENE
N-TETRACOSANE
N-TETRADECANE
N-TRIACONTANE
Organo-Phosphorus Pesticides ' " -'".'',"-, ^ /-< s '- " * ' ^
78342
22248799
34643464
DIOXATfflON
TETRACHLORVINPHOS
TOKUTHION
52686
327980
512561
TRICHLORFON
TRICHLORONATE
1RIMETHYLPHOSPHATE
Organo-Halide Pesticides , " - " ," , - ' - f^ ,"
30560191
15972608
1912249
1861401
319846
319857
319868
58899
314409
1689992
23184669
2425061
ACEPHATE
ALACHLOR
ATRAZINE
BENEFUJRALIN
ALPHA-BHC
BETA-BHC
DELTA-BHC
GAMMA-BHC
BROMACBL
BROMOXYNIL OCTANOATE
BUTACHLOR
CAPTAFOL
1031078
72208
53494705
7421934
55283686
2593159
60168889
1024573
465736
33820530
72435
21087649
ENDOSULFAN SULFATE
ENDRIN
ENDRIN KETONE
ENDRIN ALDEHYDE
ETHALFLURALIN
ETRIDIAZOLE
FENARIMOL
HEPTACHLOR EPOXIDE
ISODRIN
ISOPROPAUN
METHOXYCHLOR
METRIBUZIN
7-24
-------
Section 7.0 - Pollutants Selected for Regulation
Table 7-4 (Continued)
CAS
Number
133062
786196
5103719
5103742
510156
2675776
1861321
72548
72559
50293
2303164
117806
115322
60571
959988
Analyte - -, '
CAFTAN
CARBOPHENOTfflON
ALPHA-CHLORDANE
GAMMA-CHLORDANE
CHLOROBENZELATE
CHLORONEB
DACTHAL(DCPA)
4,4'-DDD
4,4'-DDE
4,4'-DDT
DIALLATE
DICHLONE
DICOFOL
DIELDR1N
ENDOSULFANI
1?fienoxy-Aci4 Herbicides
94757
75990
94826
1918009
120365
88857
2,4-D
DALAPON
2,4-DB (BUTOXON)
DICAMBA
DICHLOROPROP
DINOSEB
CAS'?
'Number
2385855
1836755
40487421
82688
61949766
72560
1918167
139402
122349
8001501
5902512
5915413
43121433
1582098
-',
94746
7085190
1918021
93765
93721
'* -f < ^ •• v ^ Jff
- s Analyte \ * '' '-1
MIREX
NITROFEN
PENDIMETHALIN
PENTACHLORONITROBENZENE
(PCNB)
CIS-PERMETHRIN
PERTHANE
PROPACHLOR
PROPAZINE
SIMAZINE
STROBANE
TERBACIL
TERBUTHYLAZINE
TRIADIMEFON
TRIFLURALIN
; ' , '\
MCPA
MCPP
PICLORAM
2,4,5-T
2,4,5-TP
Metals \ ' " ' ''' > t \
7429905
7440393
7440473
7440473
ALUMINUM
BARIUM
CHROMIUM
COPPER
7439896
7723140
7440326
7440666
IRON
PHOSPHORUS
TITANIUM
ZINC
Classical Pollutants , /
7664417
59473040
C002
C004
16984488
COOS
C037
AMMONIA AS NITROGEN
ADSORBABLE ORGANIC HAUDDES
BOD 5-DAY (CARBONACEOUS)
CHEMICAL OXYGEN DEMAND
FLUORIDE
NITRATE/NrrRITE
SGT-HEM
U014
C012
C020
14265442
C036
C009
SURFACTANTS (MBAS)
TOTAL ORGANIC CARBON
TOTAL PHENOLS
TOTAL PHOSPHORUS
HEXANE EXTRACTABLE
MATERIAL
TOTAL SUSPENDED SOLIDS
7-25
-------
Section 7.0 - Pollutants Selected for Regulation
Table 7-5
Pollutants Effectively Removed for Barge/Chemical & Petroleum
Subcategory Direct Dischargers for Proposed BPT, BCT, BAT, and NSPS
Option \
CAS
Number
1CAS
Number
Analyte N -,,
Volatile Organics , ,-,,,, \ '; T r;
67641
107131
71432
67663
100414
78933
ACETONE
ACRYLONTTRILE
BENZENE
CHLOROFORM
ETHYLBENZENE
METHYL ETHYL KETONE
108101
75092
108883
108383
136777612
METHYL ISOBUTYL KETONE
METHYLENE CHLORIDE
TOLUENE
M-XYLENE
O- + P-XYLENE
Semivolatile Organics , - " > , ' ' ' '" \
83329
208968
120127
243174
65850
92524
117817
99876
124185
1576676
117840
629970
112403
112958
86737
ACENAPHTHENE
AOBNAPHTHYLENE
ANTHRACENE
2,3-BENZOFLUORENE
BENZOICACE)
BIPHENYL
BIS(2-ETHYLHEXYL) PHTHALATE
P-CYMENE
N-DECANE
3,6-DIMETHYLPHENANTHRENE
DI-N-OCTYL PHTHALATE
N-DOCOSANE
N-DODECANE
N-EICOSANE
FLUORENE
630013
544763'
1730376
91576
832699
91203
630024
593453
700129
85018
108952
129000
100425
646311
629594
N-HEXACOSANE
N-HEXADECANE
1-METHYLFLUORENE
2-METHYLNAPHTHALENE
1-METHYLPHENANTHRENE
NAPHTHALENE
N-OCTACOSANE
N-OCTADECANE
PENTAMETHYLBENZENE
PHENANTHRENE
PHENOL
PYRENE
STYRENE
N-TETRACOSANE
N-TETRADECANE
Phenoxy-Acid Herbicides ;
75990
DALAPON ||
Metals -
7429905
7440439
7440473
7440508
18540299
7439896
7439921
ALUMINUM
CADMIUM
CHROMIUM
COPPER
HEXAVALENT CHROMIUM
IRON
LEAP
7439976
7440020
7440042
7723140
7440188
7440213
7440326
MERCURY
NICKEL
OSMIUM
PHOSPHORUS
RUTHENIUM
SILICON
TITANIUM
7-26
-------
Section 7.0 - Pollutants Selected for Regulation
Table 7-5 (Continued)
CAS
Number
7439954
7439965
V *
Analyte
MAGNESIUM
MANGANESE
CAS-"
Number
7440666
Analyte " " ' /
ZINC
pg&i^iil|i|S10ibnts ' - _ , ', , "'' "<- - , -,-' "V, -„ -. \ - ;?- ' ;:'t*i
59473040
7664417
C002
C004
COOS.
U014
ADSORBABLE ORGANIC HALEDES
(AOX)
AMMONIA AS NITROGEN
BOD 5-DAY (CARBONACEOUS)
CHEMICAL OXYGEN DEMAND
(COD)
NITRATE/NTTRITE
SURFACTANTS (MBAS)
C012
C037
C020
14265442
C036
C009
TOTAL ORGANIC CARBON (TOC)
SGT-HEM
TOTAL PHENOLS
TOTAL PHOSPHORUS
HEXANE EXTRACTABLE
MATERIAL
TOTAL SUSPENDED SOLIDS
7-27
-------
Section 7.0 - Pollutants Selected for Regulation
Table 7-6
Pollutants Effectively Removed for Truck/Food, Rail/Food, and Barge/Food
Subcategory Direct Dischargers for Proposed BPT, BCT, and NSPS Option 2
CAS
Number
11 CAS
Analyte j Number
Semivolatile Organics
65850
95487
BENZOIC ACID II 142621
O-CRESOL || 108952
Analyte t
s >
/ " J y
HEXANOIC ACID
PHENOL
Classical Pollutants " \ / ' , /
7664417
C002
C004
16887006
C010
C012
AMMONIA AS NITROGEN
BOD 5-DAY (CARBONACEOUS)
CHEMICAL OXYGEN DEMAND
(COD)
CHLORIDE
TOTAL DISSOLVED SOLIDS
TOTAL ORGANIC CARBON (TOG)
C037
C020
14265442
C036
C009
SGT-HEM
TOTAL PHENOLS
TOTAL PHOSPHORUS
HEXANE EXTRACTABLE
MATERIAL
TOTAL SUSPENDED SOLIDS
7-28
-------
Section 7.0 - Pollutants Selected for Regulation
Table 7-7
Pass-through Analysis for the Truck/Chemical Subcategory
Pollutant
COD
Chromium
Zinc
Bis (2-ethylhexyl) Phthalate
Di-n-Octyl Phthalate
n-Dodecane
n-Hexadecane
Styrene
1 ,2-Dichlorobenzene
BATBereeaiTtemoval
94
80
97
90
95
99
97
98
97
POTW Percent Removal
• 82
67
78
60
83
95
71
94
89
'PassVThrough -
Yes
. Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Table 7-8
Pass-through Analysis for the Rail/Chemical Subcategory
Pollutant
COD
Total Petroleum Hydrocarbons
(SGT-HEM)
Anthracene
Fluoranthene
n-Dodecane
n-Hexadecane
n-Tetradecane
Phenanthrene
Pyrene
BAT Percent Removal ,
88
75
72
87
83
99
97
87
85
POTWPercentRemoval
82
65
96
42
95
71
71
95
95
'Pass>Throughr
Yes
Yes
No
Yes
No
Yes
Yes
No
No
7-29
-------
Section 7.0 - Pollutants Selected for Regulation
Table 7-9
Pass-through Analysis for the Barge/Chemical & Petroleum Subcategory
Pollutant
COD
Total Petroleum Hydocarbons
(SGT-HEM)
Cadmium
Chromium
Copper
Lead
Nickel
Zinc
1-Methylphenanthrene
Bis (2-ethylhexyl) Phthalate
Di-n-Octyl Phthalate
n-Decane
n-Docosane
n-Dodecane
n-Eicosane
n-Octadecane
n-Tetracosane
n-Tetradecane
p-Cymene
Pyrene
Average BAT Percent
Removal
98
>99
97
98
98
95
96
93
>99
>99
>99
>99
>99
>99
>99
>99
>99
>99
>99
99
Average POTW Percent
Removal
82
65
90
67
84
92
51
78
. 95
60
83
9
88
95
92
71
71
71
99
95
Pass Through
Yes
Yes
Yes
Yes
Yes
Yes
. Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
7-30
-------
Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
8.0
POLLUTION PREVENTION AND WASTEWATER
TREATMENT TECHNOLOGIES
This section describes technologies that are used by the Transportation Equipment
Cleaning Industry (TECI) to prevent the generation of wastewater pollutants or reduce the
discharge of wastewater pollutants. Various combinations of these technologies were considered
as the basis for the proposed effluent limitations guidelines and standards for the industry (see
Section 9.0).
Three major approaches are used by the TECI to improve effluent quality:
(1) cleaning process technology changes and controls to prevent or reduce the generation of
wastewater pollutants; (2) flow reduction technologies to decrease wastewater generation and
increase pollutant concentrations, thereby improving the efficiency of treatment system pollutant
removals; and (3) end-of-pipe wastewater treatment technologies to remove pollutants from
transportation equipment cleaning (TEC) wastewater prior to discharge. These approaches are
discussed in the following sections:
• Section 8.1: Pollution prevention controls used by the TECI;
• Section 8.2: Flow reduction technologies used by the TECI;
• Section 8.3: End-of-pipe wastewater treatment technologies used by the
TECI; and
• Section 8.4: References used in this section.
8.1
Pollution Prevention Controls
EPA has defined pollution prevention as source reduction and other practices that
reduce or eliminate pollution at the source. Source reduction includes any practices that reduce
the amount of any hazardous substance or pollutant entering any waste stream or otherwise
released into the environment, or any practice that reduces the hazards to public health and the
8-1
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
environment associated with the release of such pollutants. Data gathered from the Detailed
Questionnaire shows that approximately 27% of TEC facilities currently practice water pollution
prevention, and approximately 61% of TEC facilities currently practice heel pollution prevention.
The principal pollution prevention controls applicable to the TECI are the use of dedicated tanks,
heel reduction, and reduction in the amount or toxicity of chemical cleaning solutions. These
pollution prevention controls are discussed in the following subsections.
8.1.1
Use of Dedicated Tanks
Tank cleanings are performed for two primary purposes: (1) to prevent
contamination of materials from one cargo shipment to the next and (2) to facilitate inspection
and repair. Certain segments of the TECI, such as shippers and carriers, frequently use tanks
dedicated to hauling a single cargo (e.g., gasoline) that require no, or less frequent, cleaning
between loads. Benefits from the use of dedicated tanks include:
• Reduced costs as a result of fewer tank cleanings;
• Reduced waste management and disposal costs because heel removal and
disposal are not required;
• Elimination of the generation of tank cleaning wastewater and associated
pollutant discharges; and
• Reduced tank cleaning wastewater treatment costs and/or sewerage fees.
Impediments to the use of dedicated tanks include:
Product purity concerns that necessitate cleaning to prevent contamination
of subsequent cargos; and
Financial loss due to inefficient equipment allocation (i.e., dedicated tanks
are precluded from use to transport other cargos).
8-2
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
8.1.2
Heel Reduction
Heel is the residual cargo remaining in a tank or container following unloading,
delivery, or discharge of the transported cargo and is the primary source of pollutants in TEC
wastewater. Measures may be taken before, during, and after the tank cleaning process to reduce
the amount of heel that enters the wastewater stream. These heel reduction measures are
described later in this section.
Excessive heels are also an important economic consideration for the TECI. For
example, many cargos are valuable, and any product waste represents a significant loss. In
addition, profits from transporting product and/or cleaning tanks can be offset by large heel
disposal costs. As a result, the TECI has a strong economic incentive to minimize heels.
Heel generation occurs during the unloading of a tank. Since tank unloading
frequently does not occur at the TEC facility, the carrier, shipper, or consignee may have a more
direct control over heel generation than the TEC facility that will ultimately clean the tank and
dispose the heel. TEC facilities can develop a heel minimization program that identifies the
sources of heels and institutes practices that discourage heel generation by carriers, shippers, and
consignees.
Tank cleaning facility personnel cite education of, and communication among, the
carrier, shipper, and consignee as critical components of an effective heel minimization program.
Carriers, shippers, and consignees may not be aware of the problems associated with excess heels
and may not understand how heel minimization best serves their interests. An effective heel
minimization program is best implemented as a partnership among the carrier, shipper,
consignee, and tank cleaning facility and may include the following components:
Drivers should be trained to identify excess heels;
Drivers should perform pre- and post-trip inspections and discuss with the
consignee methods for reducing excess heels;
8-3
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
If excess heel is not resolved with the consignee, the driver should report
excess heel to the driver's.manager. Drivers should document heel issues
or problems including offloading conditions which may have caused
excess heel;
Carriers should provide data to the shipper on amounts of heels;
Facilities should consider heel management options other than disposal,
such as redelivering the product to the consignee or drumming the heel
and returning it to the shipper or consignee;
Facilities should evaluate any company policies that punish or fine drivers
for excess heel to ensure that the policies do not encourage illicit heel
disposal;
Drivers should consider inviting shippers to accompany them during
product delivery to gain a first hand perspective and understanding of
factors impacting heel volumes;
Facilities may refuse or reject tanks for cleaning if excessive heel is
present;
Facilities may charge an extra fee per amount of heel received as an
incentive to minimize heel;
Facilities may refuse to accept particular cargos for one or more of the
following reasons: federal, state, local, or other environmental permit
limitations; safety considerations; facility cleaning capabilities; and/or
facility wastewater treatment system capabilities;
The heel minimization programs, pollution prevention plans, and tank
cleaning standard operational procedures should be written and carefully
followed by all personnel involved in heel generation and management;
and
Personnel should undergo ongoing training so that changes in the heel
minimization program and new procedures and policies will not be
overlooked.
Implementation of an effective heel program can provide significant
environmental and economic benefits. In order to achieve the environmental and economic
benefits associated with heel reduction, TEC facilities should employ appropriate heel reduction
8-4
-------
Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
techniques in addition to implementing an effective heel minimization program. Heel reduction
techniques are discussed in the following paragraphs.
During tank cleaning operations, some TEC facilities incorporate procedures to
remove as much heel as possible so that it can be segregated from the tank cleaning wastewater.
One procedure, used particularly for tanks that last transported petroleum products, is to steam
the inside of the tank to lower the viscosity of the heel. The steamed tank is then drained to
remove additional heel. Similarly, tanks, drains, and fittings may be preheated with steam or hot
water to facilitate product draining. Another procedure applicable to certain cargos is for tank
cleaning personnel to enter the tank and manually squeegee heel toward the valve openings.
(Physically entering a tank may not be advisable in many circumstances. Personnel must be
trained in health and safety procedures and a confined space entry permit may be required.)
A third procedure is to perform a hot or cold water prerinse (subsequent to
primary heel removal via draining) to enhance heel removal. This procedure uses a short burst of
water (e.g. 5 to 10 seconds) to remove heel from the tank interior. The prerinse wastewater
(containing residual heel) is drained and managed separately from tank cleaning wastewater.
Note that some facilities perform tank prerinses solely as a means to increase the useful life of
tank cleaning solutions (by minimizing solution contamination with heel) rather than as a TEC
wastewater pollution prevention procedure. These facilities do not manage the prerinse
wastewater separately from the other tank interior cleaning wastewaters.
After tank cleaning is complete, facilities employ various heel management
practices (such as reuse, recycle, or disposal) so that heel is managed separately from tank
interior cleaning wastewater. Reuse and recycle may be accomplished by any one of several
methods. One method is to return the heel to the consignee. Some heels can be reused at the
TEC facility. For example, fuel and fuel oil heels can be used in TEC facilities' on-site boilers or
in their own transportation equipment. Heels comprised of soaps, detergents, solvents, acids, or
alkalis may be reused by TEC facilities for tank cleaning, neutralization, or wastewater treatment.
8-5
-------
Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
Many food grade heels can be recycled as animal feed. Some heels, such as fertilizers, can be
segregated, stored, and sold as product.
Heel that cannot be recycled or reused can be managed separately from tank
interior cleaning wastewater. The most common method of heel disposal is land disposal. This
practice is most often performed with petroleum and coal product heels and dry-bulk cargo heels.
Heels may also be hauled to a privately owned treatment works, federally owned treatment
works, centralized waste treatment works, ballast water treatment facility, or hazardous waste
treatment, storage, and disposal facility, all of which are frequently better equipped to treat these
wastes.
8.1.3
Reduction in the Amount and Toxicity of Chemical Cleaning
Solutions
Many cargo types require the use of chemical cleaning solutions in the tank
cleaning process. In addition to the contaminants contained in the heel removed by chemical
cleaning solutions, the chemicals used in the solutions may themselves be toxic. These chemical
cleaning solutions are a significant source of pollutants in TEC wastewater. By reducing the
amount and toxicity of chemical cleaning solutions used in the tank cleaning process, tank
cleaning facilities can reduce the contribution of cleaning solutions to the total wastewater
pollutant concentrations. These pollution prevention procedures include recirculating and
reusing cleaning solutions, disposing cleaning solutions separately from tank interior cleaning
wastewater, and using less toxic cleaning solutions. These measures are described further in the
following paragraphs.
The majority of TEC facilities that discharge chemical cleaning solutions with
their tank cleaning wastewater recycle and reuse the solutions at least once prior to discharge.
Recycle and reuse is usually achieved through the use of automated cleaning systems or cleaning
solution recirculation loops that allow reuse of the cleaning solutions until their efficacy
diminishes below acceptable levels. This reduces the amount of additional chemical cleaning
8-6
-------
Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
solution required for each tank cleaned; instead, smaller amounts of make-up solution are
periodically added to replace solution lost in the final rinse or to boost efficacy. As previously
mentioned, a hot or cold water prerinse may also be used to extend the useful life of a chemical
cleaning solution, thereby reducing the total amount of chemical cleaning solution needed for
tank cleaning.
Another method of reducing the introduction of chemical cleaning solutions to the
wastewater streams is to capture the spent solutions and dispose them off site at a treatment
facility that is better equipped to treat these concentrated chemical wastes than on-site
wastewater treatment systems. Off-site disposal can be combined with the recirculation and
reuse of cleaning solutions (described above) to reduce the need for fresh cleaning solution and
to minimize the amount of cleaning solutions that enter the facility wastewater treatment system.
Many facilities in the TECI substitute less toxic cleaning solutions, where
appropriate, to reduce the amount of toxic pollutants that are introduced to the wastewater
stream. Typically, presolve solutions are the most toxic chemical cleaning solutions and are least
compatible with facility wastewater treatment systems. Presolve usually consists of diesel fuel,
kerosene, pr some other petroleum-based solvent and is used to clean hardened or caked-on
products that are not easily removed by other cleaning processes. In many cases, presolve may
be substituted by acidic or caustic solutions to which detergent "boosters" (e.g., glycol ethers or
esters) are added to improve their effectiveness. At some facilities, chemical cleaning solutions
may be eliminated by using steam cleaning or hot or cold water washes for water-soluble cargos
or by extending the process time of cleaning steps that do not use toxic cleaning solutions.
As in the case of heel reduction, these methods to reduce the amount and toxicity
of chemical cleaning solutions benefit from written cleaning process standard operating
procedures and pollution prevention plans that are carefully followed by cleaning personnel.
Facilities should also conduct ongoing training for cleaning personnel to insure that the
procedures contained in these resources will be practiced at all times.
8-7
-------
Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
8.2
Flow Reduction Technologies
This section describes technologies that can reduce the volume of wastewater
discharges from TEC facilities. Flow reduction offers the following benefits: (1) increased
pollutant concentrations which increase the efficiency of the wastewater treatment system;
(2) decreased wastewater treatment system equipment sizes, resulting in reduced treatment
system capital and operating and maintenance costs; and (3) decreased water and energy usage.
Data gathered from the Detailed Questionnaire shows that approximately 45% of TEC facilities
currently practice flow reduction/water conservation. Flow reduction technologies applicable to
the TECI serve to reduce the amount of fresh water required for tank cleaning through cleaning
process modifications and/or recycling and reusing process wastewaters in TEC or other
operations. These flow reduction technologies are presented in the following subsections.
8.2.1
High-Pressure, Low-Volume Cleaning Equipment
The use of high-pressure, low-volume cleaning equipment is one of the most
effective tools for reducing water use. The most common type of this equipment is spinner
nozzles, which are nozzles designed to rotate around both vertical and horizontal axes to create
an overlapping spray pattern that cleans the entire interior of the tank. Spinner nozzles are
inserted through the main tank hatch and operated at pressures between 100 pounds per square
inch (psi) and 600 psi to deliver hot or cold water rinses and a variety of cleaning solutions for
tank cleaning final rinses. Spinners can be operated using pulsing pump technology where water
is delivered in bursts of a few seconds, further reducing the volume of water. Washing with
high-pressure, hand-held wands with stationary nozzles achieves the same result as washing with
high pressure spinner nozzles but requires facility personnel to manually direct the wash solution
across the interior surface of the tank.
8-8
-------
Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
8.2.2
Monitoring TEC Water Use
Cleaning personnel can monitor the amount of water required for tank cleaning so
that the minimum amount of water is used to clean each specific tank and cargo type. One
approach is to inspect each tank to determine the state and amount of residual cargo remaining
and thereby determine the duration and amount of water required for cleaning. A more general •
approach is to have a predetermined water use and cleaning time for each tank type and cargo
combination based on previous tank cleaning experience.
8.2.3
Equipment Monitoring Program
The implementation of an equipment monitoring program can significantly reduce
fresh water requirements by eliminating water waste. Pumps, hoses, nozzles, water storage
tanks, and cleaning solution tanks may develop leaks and require prompt attention by facility
personnel. Preventative maintenance, periodic inspection, and prompt repair of leaks can help
ensure that no unnecessary water waste occurs.
8.2.4
Cleaning Without Use of Water
Dry cleaning processes (i.e., cleaning processes that do not require water) are
effective for removing some cargos, particularly dry-bulk goods and viscous liquids. Some dry
cleaning processes require cleaning personnel to enter the tank and shovel or sweep dry-bulk
cargos, or mop or squeegee liquid cargos to remove as much residual material as possible.
Mechanical devices may also be used to vibrate hoppers to improve heel removal. Depending on
the effectiveness of these dry cleaning processes, the need for subsequent tank cleaning with
water may be eliminated. At a minimum, these techniques will reduce the amount of water and
cleaning solution required for tank cleaning.
8-9
-------
Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
8.2.5
Cascade Tank Cleaning
Facilities that primarily clean tanks used to transport the same cargos (e.g.,
petroleum facilities) often operate "cascading" tank cleaning processes. In these processes, the
most contaminated TEC process wastewater is used for initial tank rinses, with initial tank rinse
wastewater routed to disposal. Clean water, or relatively clean TEC process wastewater, is used
for final tank rinses, with final tank rinse water reused as an initial tank rinse when cleaning
subsequent tanks. Through this process, wash water is used at least twice prior to discharge or
disposal.
8.2.6
Wastewater Recycle and Reuse
In addition to cascading tank cleaning processes, TEC facilities may incorporate
other methods of water recycle and reuse to reduce or eliminate the need for fresh process water.
Wastewater streams most commonly recycled and reused for TEC operations include tank
interior cleaning wastewater, hydrotesting water, uncontaminated stormwater, and noncontact
cooling water. If hydrotesting water, uncontaminated stormwater, and noncontact cooling water
are segregated from tank interior cleaning wastewater, these wastewaters do not require extensive
treatment prior to recycle and reuse.
Tank interior cleaning wastewater generated by cleaning tanks used to transport
petroleum products can typically be reused as tank interior cleaning water after treatment by
oil/water separation and activated carbon treatment. Wastewater generated by cleaning tanks that
last transported chemical products generally requires more extensive treatment prior to reuse as
source water in TEC operations. Final tank rinse water may also be used as cleaning solution
make-up water.
Tank hydrotesting wastewater may be reused as future hydrotesting water by
pumping to a storage tank between tests. Because hydrotesting usually requires that the entire
8-10
-------
Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
tank be filled (approximately 5^000 gallons for an intermediate sized tank truck), the reuse of
hydrotest wastewater can save substantial volumes of fresh water.
8.3
End-of-Pipe Wastewater Treatment Technologies
End-of-pipe wastewater treatment includes physical, chemical, and biological
processes that remove pollutants from TEC wastewater prior to discharge to a receiving stream
or POTW. Many TEC facilities use.pretreatment, primary treatment, biological treatment, and/or
advanced treatment for end-of-pipe treatment of wastewater. [See Table C-6 of the Data Element
Dictionary for the Detailed Questionnaire (1) for the specific technologies included within these
technology classifications.] Typical end-of-pipe treatment currently used by the TECI includes
pretreatment and primary treatment. TEC facilities that operate biological and/or advanced
treatment units are commonly those that practice extensive water and wastewater recycle and
reuse or discharge directly to U.S. surface waters.
The following subsections describe the major wastewater treatment technologies
used by the TECI. Each subsection includes a general description of how the technology works
and what types of pollutants the technology treats. The number of TEC facilities that use each
treatment technology is presented in the following table. The numbers of facilities presented in
this table have been adjusted using statistical scaling factors and therefore represent the entire
industry rather than only the surveyed facilities. The following subsections describe each of
these technologies in the order that they appear in the table.
" £ <*&
Treatment Technology <^f
/?<& j>
Gravity Settling
pH Adjustment
Equalization
Oil/Water Separation
Sludge Dewatering
;v> lWa1jrer,of;< " Utilize the Treatment Technology ' %
393 (57%)
303 (44%)
289 (42%)
251 (36%)
195 (28%)
8-11
-------
Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
Treatment Technology
Dissolved Air Flotation
Coagulation/Flocculation
Filtration
Clarification
Biological Oxidation
Chemical Precipitation/Separation
Grit Removal
Chemical Oxidation
Activated Carbon Adsorption
Membrane Filtration
Number of Faculties <% of Discharging Facilities) That
Utilize the Treatment Technology y -
175 (25%)
169 (24%)
166 (24%)
157 (23%)
60 (9%)
43 (6%)
30 (4%)
16 (2%)
4 (<1%)
1 (<1%)
83.1
Gravity Settling
Gravity settling, or sedimentation, removes suspended solids from TEC process
wastewater by maintaining wastewater in a quiescent state so that contaminants can separate by
density. Gravity settling is utilized by more than half of the TEC facilities (57%). During
gravity settling, wastewater is typically collected in a tank or catch basin, where it is detained for
a period of time, allowing solids with a specific gravity higher than water to settle to the bottom
of the tank and solids with a specific gravity lower than water to float to the surface. The
effectiveness of gravity separation depends upon the characteristics of the TEC wastewater and
the length of time the wastewater is held in the treatment unit. Properly designed and operated
gravity separation units are capable of achieving significant reductions of suspended solids and
5-day biochemical oxygen demand in many TEC wastewaters.
Some facilities add chemicals, such as lime or polymers, to aid in the settling of
solids. The solids that settle out or float to the surface may be removed from the unit
continuously using automatic scrapers or skimmers. Alternatively, the units may be periodically
shut down and the solids removed manually.
8-12
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
8.3.2
pH Adjustment
Adjustment of pH is a process in which chemicals are added to a wastewater to
make it acidic or basic or to neutralize acidic or basic wastewaters. Of the total TEC facilities,
44% utilize pH adjustment. A pH adjustment system normally consists of a small tank in which
the wastewater pH is adjusted by mixing and chemical addition under the control of a pH meter.
To adjust the pH of the wastewater, either caustic or acidic chemicals are added to the mixing
tank. Because many treatment technologies used in the TECI are sensitive to pH fluctuations, pH
adjustment may be required as part of an effective treatment system. Some treatment
technologies require a high pH (e.g., chemical precipitation), while others require a neutral pH
(e.g., biological oxidation). In addition, the pH of the final effluent from these technologies must
often be adjusted prior to discharge to meet permit conditions for wastewater discharge.
8.3.3
Equalization
Equalization involves homogenizing variable wastewaters over time to control
fluctuations in flow and pollutant characteristics, thereby reducing the size and cost and
improving the efficiency of subsequent treatment units. Approximately 42% of TEC facilities
incorporate equalization in their wastewater treatment processes. Equalization units include
tanks which are often equipped with agitators (e.g., impeller mixers and air spargers) to mix the
wastewater and to prevent solids from settling at the bottom of the unit. Chemicals may also be
added to the equalization units to adjust pH, as necessary, for further treatment.
Equalization units can allow downstream treatment units to be sized and operated
on a continuous-flow basis, because they can minimize the variation in the characteristics of
untreated wastewaters. This reduces the probability of treatment system upsets and allows
treatment systems to be optimized for a narrower range of influent wastewater characteristics.
The amount of residence time required by an equalization unit to achieve optimum effects is
dependent upon the specific characteristics and daily flow patterns of the wastewater.
8-13
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
8.3.4
Oil/Water Separation
Oil/water separation uses the difference in specific gravity between oil and water
to remove free or floating oil from wastewater. More than one-third of TEC facilities (36%) use
oil/water separation as a method of removing varying levels of oil and grease.
The most common mechanism for oil removal is an oil skimmer. Some skimming
devices work by continuously contacting the oil with a material, such a belt or rope, onto which
the oil readily adheres. As the material passes through the floating oil layer, the oil coats the
surface of the material. The oil-coated material then passes through a mechanism that scrapes
the oil from the material into an oil collection unit. Another type of skimming device uses
overflow and underflow baffles to skim the floating oil layer from the surface of the wastewater.
An underflow baffle allows the oil layer to flow over into a trough for disposal or reuse while
most of the water flows underneath the baffle. This is followed by an overflow baffle, which is
set at a height relative to the first baffle such that only the oil-bearing portion will flow over the
first baffle during normal operation.
A standard oil/water separator utilized by the TECI is an American Petroleum
Institute (API) oil/water separator. A typical API oil/water separator is rectangular and
constructed with surface skimmers for oil removal and a bottom sludge rake or sludge auger for
solids removal. It is designed such that lighter floating matter rises and remains on the surface of
the water until removed, while the liquid flows out continuously under partitions or through deep
outlets. Figure 8-1 presents a diagram of an API oil/water separator.
Another common type of oil/water separator used by the TECI is a coalescing
oil/water separator, which is used to remove oil droplets too finely dispersed for conventional
gravity separation and skimming technology. These units are comprised of a series of corrugated
and/or inclined plates or tubes arranged parallel to one another and transverse to the flow of
water. The plates and rubes are often built of materials that attract oil away from the water, such
as polypropylene, ceramic, or glass. As the oil droplets impinge on the. surfaces of the plates or
8-14
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
tubes, they coalesce into a layer of oil that flows or is pumped from the unit. Figure 8-2 presents
a diagram of a coalescing oil/water separator.
Due to the complex nature of TEC wastewater and the presence of detergents and
high-pH chemicals, oils may form a stable emulsion which does not separate well in a gravity or
coalescing separator. Stable emulsions require pH adjustment, the addition of chemicals, and/or
heat to break the emulsion. The method most commonly used by the TECI to perform oil/water
separation on stable emulsions is acid cracking. Acid cracking entails the addition of sulfuric or
hydrochloric acid to the tank containing the oil mixture until the pH reaches 1 or 2. A coagulant
may also be added during acid cracking to aid in oil/water separation. After the emulsion bond is
broken, the free oil floats to the top of the tank where it is removed by a skimming device.
8.3.5
Sludge Dewatering
Sludge dewatering reduces sludge volume by decreasing its water content.
Various methods of this particular process are employed by 28% of the TECI. Sludge dewatering
may involve simple techniques such as the use of sludge drying beds, or it may be accomplished
through more complicated mechanical techniques, including filter presses, rotary vacuum filters,
and centrifuges. The decrease in sludge volume achieved through sludge dewatering
substantially reduces the cost for sludge disposal and allows for easier sludge handling.
8.3.5.1
Sludge Drying Bed
The sludge drying bed process involves applying sludge to land, collecting the
supernatant after solids settle, and allowing the sludge to dry. The sludge cake may then be
scraped manually or by a front-end loader and dumped into a truck. Disadvantages to using a
sludge drying bed are potential odor problems, large land area requirements, and the cost of labor
to remove the dried cake. The main components of a sludge drying bed include watertight walls
extending above the surface of the bed; an opening in the wall for entrance of a front-end loader
to scrape up the sludge cake; drainage trenches filled with a coarse sand bed supported
.on a
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
gravel filter with a perforated pipe underdrain; paved areas on both sides of the trenches with a
slope for gravity drainage; and a sludge inlet and supernatant draw-off (2). The supernatant
collected from the sludge may be returned as influent to wastewater treatment. Depending on
sludge content and climate conditions for evaporation, sludge drying times may range from
several days to weeks.
8.3.5.2
Plate-and-Frame Filter Press
The most widely used filter press is referred to as the plate-and-frame filter press.
A filter press uses positive pressure provided by a mechanical device, such as a hydraulic ram, to
drive water contained in the sludge through a filter medium. This type of unit comprises a series
of recessed plates that are affixed with a filter medium (e.g., filter cloth) and are stacked together
on a horizontal shaft. The plates form a series of spaces separated by the filter media and are
otherwise sealed to withstand the internal pressures created during the filtration cycle. As the
sludge is forced through the system, the water passes through the filter medium and is discharged
through the filtrate port while the solids become trapped within the spaces, forming a dewatered
cake against the filter medium.
When the cycle is over, the plates are separated, and the dewatered cake is
released from the spaces into a collection bin. Removing the cake from the filter media is often
performed manually by an operator. The filter press filtrate that results from the dewatering is
usually piped back to the beginning of the treatment system. Figure 8-3 presents a diagram of a
plate-and-frame filter press.
8.3.5.3
Rotary Vacuum Filter
A rotary vacuum filter consists of a cylindrical drum with a filter medium, such as
cloth or wire mesh, around its perimeter. The drum is horizontally suspended within a vessel and
is partially submerged in the sludge. The drum is rotated and the filter surface contacts the
sludge within the vessel while a vacuum is drawn from within the drum. This draws the water
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
through the filter medium toward the axis of rotation and discharges it through a filtrate port.
The solids become trapped against the filter medium, forming a dewatered cake around the
outside of the drum. The dewatered cake is continuously scraped from the drum into a collection
bin. Figure 8-4 presents a diagram of a rotary vacuum filter.
8.3.5.4
Centrifuge
Another method of sludge dewatering is centrifuging. Centrifuge designs are
based on the principal of centrifugal force. To settle and separate higher density solids from
wastewater, sludge is spun or rotated in the centrifuge, collected on the inner wall of the
mechanism, and then scraped from the walls of the centrifuge. Certain wastewater treatment
chemicals may be added to sludge in the centrifuge to bring additional pollutants out of solution
and form an insoluble floe (e.g., as in chemical precipitation) that is also separated by the
centrifugal forces.
8.3.6
Dissolved Air Flotation
Flotation is the process of influencing suspended particles to rise to the
wastewater surface where they can be collected and removed. Dissolved air flotation is utilized
by approximately 25% of TEC facilities in their treatment systems. During flotation, gas bubbles
introduced into the wastewater attach themselves to suspended particles, thereby reducing their
specific gravity and causing them to float. Flotation processes are utilized because they can
remove suspended solids that have a specific gravity slightly greater than 1.0 more quickly than
sedimentation.
Dissolved air flotation (DAF) is one of several flotation techniques used for
wastewater treatment to extract free and dispersed oil and grease, suspended solids, and some
dissolved pollutants from process wastewater. In DAF, two modes of operation may be
employed to pressurize wastewater. In recycle pressurization, air is injected into a portion of
recycled, clarified effluent and dissolved into a wastewater stream in an enclosed tank or pipe,
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
pressurizing the wastewater. In full flow pressurization, all of the influent wastewater is injected
with air in a surge tank and is pumped to a retention tank under pressure to dissolve the air into
the wastewater.
When the wastewater enters the flotation tank, the pressure is reduced, which
causes fine air bubbles to be released. These bubbles make contact with the suspended particles
via two separate mechanisms. The first mechanism involves the use of a flocculant, which
causes rising air bubbles to be trapped inside flocculated masses as they increase in size. The
second mechanism involves the intermolecular attraction between the solid particle and the air
bubble, which causes the solid to adhere to the bubble. In either mechanism, the low density of
the air bubble causes it to rise to the surface of the flotation tank with the flocculated or adhered
solids attached.
DAF units are equipped with rakes that scrape the floe from the surface and into a
sludge collection vessel, where it is subsequently pumped to a dewatering unit and later disposed.
A sludge auger may be included in the DAF unit to remove solids that have settled to the bottom
of the tank. Units are typically operated on a continuous basis and incorporate chemical mix
tanks (if flocculants are used), flotation vessels, and sludge collection tanks in a single enclosed
unit. Figure 8-5 presents a diagram of a DAF unit with pressurized recycle.
83.7
Coagulation/Flocculation
Coagulation and flocculation are processes that cause suspended solids in
wastewater to coalesce. The coalesced particles tend to settle out of the wastewater more quickly
than particles that have not undergone coagulation/flocculation. Approximately 24% of TEC
facilities use coagulation/flocculation.
Coagulation consists of the addition and rapid mixing of a "coagulant", the
destabilization of colloidal and fine suspended solids, and the initial aggregation of those
particles. Flocculation is the slow stirring to complete aggregation of those particles and form a
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
floe which will in turn settle by gravity (3). After rapid mixing, coagulant aids, such as
polyelectrolytes, are often added to reduce the repulsive forces between the charged particles.
Flocculation may also be accomplished by adding such materials as lime or sodium silicate to
form loose agglomerates that carry the fine particles down with them. These settled solids form a
sludge; therefore, coagulation/flocculation is typically followed by clarification to remove solids
(see Section 8.3.9).
8.3.8
Filtration
Filtration is used to remove solids from wastewater by passing the wastewater
through a material that retains the solids on, or within, itself. The percentage of TEC facilities
that use filtration (excluding membrane filtration, which is discussed separately in Section
8.3.15) is 24 percent. A wide variety of filter types are used by the TECI including media filters
(e.g., sand, gravel, charcoal), bag filters, and cartridge filters. A filter press (see Section 8.3.5)
may be used for in-line wastewater filtration. The flow pattern of filters is usually top-to-bottom;
however, upflow filters, horizontal filters, and biflow filters are also used.
The complete filtration process typically involves two phases: filtration and
backwashing. As the filter becomes saturated with trapped solids, the efficiency of the filtration
process decreases. As the head loss across the filter bed (i.e., measure of solids trapped in the
filter) increases to a limiting value, the end of the filter run is reached, and the filter must be
backwashed to remove the suspended solids in the bed. During backwashing, the flow through
the filter is reversed so that the solids trapped in the media are dislodged and can exit the filter.
The bed may also be agitated with air in order to aid in solids removal. The backwash water is
then recycled back into the wastewater feed stream.
The type of filter used depends on various factors such as the operating cycle (i.e.,
whether the wastewater is being filtered continuously or in batches) or the nature of the solids
passing through the filter. The filter type can also be determined by the filtration mechanism
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
(i.e., whether the filtered solids are stopped at the surface of the medium and accumulate to form
a filter cake or are trapped within the pores or body of the filter).
8.3.9
Clarification
Clarification involves holding wastewater in a quiescent state so that
contaminants can separate by density. Clarification uses the same principles for treatment as
gravity settling but differs from gravity settling in that it is typically used after
coagulation/flocculation and/or biological treatment. Approximately 23% of the TECI use
clarification in their wastewater treatment systems.
Clarifiers consist of settling tanks and are commonly equipped with a sludge
scraper mounted on the floor of the clarifier to rake sludge into a sump for removal. The bottom
of the clarifier may also be sloped to facilitate sludge removal. Clarification can be used as either
a pre-or post-treatment step for various operations to aid in removing settleable solids, free oil
and grease, and other floating material. Clarifiers are often referred to as primary or secondary
sedimentation tanks. Primary clarification is used to remove settleable solids from raw
wastewater or wastewater treated by coagulation/flocculation. Secondary clarification is
normally used in activated sludge systems to remove biomass. A portion of the sludge biomass
is often recycled from the secondary clarifier back to the activated sludge biological oxidation
unit (see Section 8.3.10). Figure 8-6 presents a diagram of a clarifier.
8.3.10
Biological Oxidation
Biological oxidation is a reaction caused by biological activity which results in a
chemical combination of oxygen with organic matter to yield relatively stable end products such
as carbon dioxide and water (3). Approximately 9% of the TECI uses biological oxidation to
treat wastewater. In wastewater treatment, this is most commonly accomplished with an
activated sludge treatment system, but aerated lagoons, trickling filters, and rotating biological
contactors (RBCs) can also be used to perform biological oxidation of wastewater.
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
An activated sludge treatment system normally consists of an aeration basin, a
secondary clarifier, and a sludge recycle line. Equalization of flow, pH, temperature, and
pollutant loading is necessary to obtain consistent, adequate treatment. A settling tank may.be
used to remove settleable solids prior to aeration. An aerobic bacterial population is maintained
in the aeration basin where oxygen, recycled sludge, and nutrients (usually nitrogen and
phosphorus) are added to the system. Prior to the aeration basin, oxygen may also be added to
wastewater in preaeration tanks. Oxygen is normally supplied by aerators that also provide
mixing to help keep microorganisms in suspension. The activated sludge-wastewater mixture, or
"mixed liquor," is then sent to a secondary clarifier that controls the amount of suspended solids
discharged and provides recycled sludge back to the aeration basin to keep an optimal
concentration of acclimated microorganisms in suspension.
Sludge produced by these systems generally consists of biological waste products
and expired microorganisms and is typically discharged from the clarifier. However, under
certain operating conditions, this sludge may accumulate in the aeration basin and may require
periodic removal. Figure 8-7 presents a diagram of an activated sludge system.
8.3.11
Chemical Precipitation/Separation
Chemical precipitation/separation is a process that renders dissolved pollutants
insoluble and uses the resulting phase differential to separate pollutants from wastewater.
Approximately 6% of TEC facilities use chemical precipitation/separation. During chemical
precipitation processes typical in the TECI, insoluble solid precipitates are formed from the
organic or inorganic compounds in the wastewater through the addition of chemicals and/or pH
adjustment. Sedimentation or filtration then separates out the solids from the wastewater.
Chemical precipitation is generally carried out in four phases:
1. Addition of the chemical to the wastewater;
2. Rapid (flash) mixing to homogeneously distribute the chemical;
3. Slow mixing to promote particle growth by flocculation; and
4. Sedimentation or filtration to remove the flocculated solid particles.
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
Chemical precipitation systems normally consist of a rapid mixer, a chemical feed
system to add the precipitation agent, a flocculation tank, and a sedimentation tank. In batch
chemical precipitation systems, the treated wastewater is held in the unit long enough to allow
the solids to settle out. The water is then pumped from the unit, and the resulting sludge is
removed for further dewatering and subsequent disposal.
Precipitation agents, such as polyaluminum chloride, ferric chloride, and lime,
work by reacting with pollutant cations (e.g., metals) and some anions to convert them into an
insoluble form for subsequent removal by gravity settling. The pH of the wastewater also affects
how much pollutant mass is precipitated, as pollutants precipitate more efficiently in different pH
ranges. Figure 8-8 presents a diagram of a batch chemical precipitation unit.
8.3.12
Grit Removal
Grit removal is the process of eliminating heavy, suspended material from
wastewater. Grit removal is only used by 4% of TEC facilities. Grit removal differs from
gravity settling/clarification in that it is typically performed in a smaller tank and has a shorter
retention time. Removal is accomplished using a settling chamber and a collection mechanism,
such as a rake. Grit chambers may also be aerated to remove floatable solids. This unit
operation is performed to prevent excess wear on pumps, accumulations in aeration tanks and
clarifiers, and clogging of sludge piping (3).
8.3.13
Chemical Oxidation
Chemical oxidation is used in wastewater treatment to destroy priority pollutants
or other organic pollutants by oxidizing them with an oxidizing agent. Approximately 2% of
TEC facilities use chemical oxidation. Chemical oxidation systems consist of a tank, a mixer,
and a chemical feed system to add the oxidizing agent. During the chemical oxidation reaction,
one or more electrons are transferred from the oxidizing chemical (electron donor) to the targeted
pollutants (electron acceptor), causing their destruction. An oxidant often used by the TECI is
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
hydrogen peroxide. Other oxidants used in industry include chlorine, ozone, and potassium
permanganate.
8.3.14
Activated Carbon Adsorption
Activated carbon removes organic constituents from wastewater by physical and
chemical forces that bind the constituents to the carbon surface and internal pores. Activated
carbon adsorption is widely used in the treatment of industrial wastewaters because it adsorbs an
extensive variety of organic compounds. However, less than 1% of TEC facilities currently use
activated carbon adsorption. The term "activated carbon" refers to carbon materials, such as coal
or wood, that are processed through dehydration, carbonization, and oxidation to yield a material
that is highly adsorbent due to a large surface area and a high number of internal pores per unit of
mass. In general, organic constituents possessing certain properties (e.g., low water solubility
and high molecular weight) and certain chemical structures (e.g., aromatic functional groups) are
amenable to treatment by activated carbon adsorption.
An activated carbon adsorption system usually consists of a column of bed
containing the activated carbon. The most common form of activated carbon for wastewater
treatment is granular. Powdered activated carbon is used less frequently for wastewater
treatment due to the difficulty of regeneration, reactor system design considerations, and its
tendency to plug more easily than granular activated carbon, although it may be used in
conjunction with biological treatment systems.
The carbon adsorption capacity (i.e., the mass of the contaminant adsorbed per
mass of carbon) for specific organic contaminants is related in part to the characteristics of each
compound. Competitive adsorption of mixed compounds has a major effect on adsorption (i.e.,
the carbon may begin preferentially adsorbing one compound over another compound and may
even begin desorbing the other compound). Process conditions, process design factors, and
carbon characteristics also affect adsorption capacity.
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
When the adsorption capacity of the carbon is exhausted, the spent carbon is
either disposed or regenerated; the choice is generally determined by cost. Carbon may be
regenerated by removing the adsorbed organic compounds from the carbon through steam
regeneration, thermal regeneration, or physical/chemical regeneration. The most common
methods to regenerate carbon used for wastewater treatment are thermal and steam regeneration.
These methods volatilize the organic compounds that were adsorbed onto the carbon.
Afterburners are required to ensure destruction of the organic vapors. A scrubber may also be
necessary to remove particulates from the air stream. Physical/chemical regeneration uses a
solvent, which can be a water solution, to remove the organic compounds.
8.3.15
Membrane Filtration
Membrane filtration is a term applied to a group of processes that use a pressure-
driven, semipermeable membrane to separate suspended, colloidal, and dissolved solutes from a
process wastewater. Less than 1% of TEC facilities use membrane filtration. During operation,
the feed solution flows across the surface of the membrane. "Clean" water permeates the
membrane by passing through pores in the membrane, leaving the contaminants and a portion of
the feed behind. The clean or treated water is referred to as the permeate or product water
Stream, while the stream containing the contaminants is called the concentrate, brine, or reject
stream. The size of the pores hi the membrane is selected based on the type of contaminant to be
removed. The pore size will be relatively large for the removal of precipitates or suspended
materials, or very small for the removal of inorganic salts or organic molecules. Figure 8-9
presents a diagram of membrane filtration unit.
For industrial applications, the product water stream will either be discharged or,
more likely, recycled or reused. The reject stream is normally disposed, but if the reject is of
suitable quality, it can also be recycled or reused. Types of membrane filtration systems
available include microfiltration, ultrafiltration (UF), and reverse osmosis (RO). The
applicability of each of these membrane filtration technologies to the TECI is discussed below.
8-24
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Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
8.3.15.1
Microfiltration
Microfilters are generally capable of removing suspended solids and colloidal
matter with diameters of greater than 0.1 microns and are commonly made from woven polyester
or ceramic materials. The systems can be operated at feed pressures of less than 50 pounds per
square inch gauge (psig). The feed stream does not require extensive pretreatment, and the
membrane is relatively resistant to fouling and easily cleaned. Microfilters are capable of
recovering up to 95% of the feed stream as product water.
8.3.15.2
Ultraffltration
Ultrafiltration is similar to microfiltration except that a UF membrane has smaller
pores. The "tightest" UF membrane is typically capable of rejecting molecules having diameters
of greater than 0.001 microns. The system operates at a feed pressure of 50 to 200 psig. UF
systems are capable of recovering from 90 to 95% of the feed as product water.
8.3.15.3
Reverse Osmosis
Reverse osmosis systems differ from microfiltration and ultrafiltration systems in
that they have the ability to reject dissolved organic and inorganic molecules. RO systems are
generally capable of removing particles with diameters less than 0.001 microns. RO membranes
are commonly made from cellulose acetate; however, polysulfone, polyamide, or other polymeric
materials may also be used. Reverse osmosis systems can be operated at feed pressures of 250 to
600 psig. RO membranes are very susceptible to fouling and may require extensive pretreatment
of wastewater to remove wastewater constituents that can cause fouling. Oxidants (which may
attack the membrane), particulates, oil, grease, and other materials that could cause a film or
scale to form, plugging the membrane, must be removed by pretreatment. Reverse osmosis
systems are capable of recovering up to 50 to 90% of the feed stream as product water. The
dissolved solids concentration in the feed determines the percent recovery that can be obtained as
well as the required feed pressure to operate the system.
8-25
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8.4
Section 8.0 - Pollution Prevention and Wastewater Treatment Technologies
References1
1.
2.
3.
Eastern Research Group, Inc. Data Element Dictionary for Part A. of the U.S.
Environmental Protection Agency 1994 Detailed Questionnaire for the
Transportation Equipment Cleaning Industry. April 4, 1997 (DCN T10271).
Viessman, Warren, Jr. and Mark J. Hammer. Water Supply and Pollution
Control. Fifth Edition. Harper Collins College Publishers. New York, NY, 1993.
Reynolds, Tom and Paul Richards. Unit Operations and Processes in
Environmental Engineering. PWS Publishing. Boston, MA, 1996.
' For those references included in the administrative record supporting the proposed TECI rulemaking, the
document control number (DCN) is included in parentheses at the end of the reference.
8-26
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8-35
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-------
Section 9.0 - Development of Control and Treatment Options
9.0
DEVELOPMENT OF CONTROL AND TREATMENT
OPTIONS
This section describes the combinations of pollution prevention practices, water
conservation practices, and end-of-pipe wastewater treatment that EPA configured as technology
options for consideration as bases for the Transportation Equipment Cleaning Industry (TECI)
effluent limitations guidelines and standards.
• Best practicable control technology currently available (BPT);
• Best conventional pollutant control technology (BCT);
• Best available technology economically achievable (BAT);
• New source performance standards (NSPS);
• Pretreatment standards for existing sources (PSES); and
• Pretreatment standards for new sources (PSNS).
Technology bases for each option for each regulation were selected from the
pollution prevention and wastewater treatment technologies described in Section 8.0. Sections
9.2 through 9.7 discuss the regulatory options that were considered for each of the regulations
listed above, including the technology bases and the rationale for developing each option.
9.1
Introduction
The proposed regulations establish quantitative limits on the discharge of
pollutants from industrial point sources. The applicability of the various limitations EPA is
proposing for the TECI is summarized below:
v
BPT
BAT
BCT
NSPS
Direct
Discharge
•
•
•
•
. Indirect
Discharge >
Existing
- Source
•
•
•
New
Source
t/
Conventional
Pollutants .
•
•
•
Priority {raitf;
Nonconventional
Pollutants '
•
•
•
9-1
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Section 9.0 - Development of Control and Treatment Options
PSES
PSNS
Direct
Discharge
Indirect
Discharge
•
•
Existing
Source
•
New
Source
•
Conventional
Pollutants
Priority and,'
, Nonconventional
Pollutants
•
•
All of these regulations are based upon the performance of specific technologies but do not
require the use of any specific technology. The regulations applicable to direct dischargers are
effluent limitations guidelines which are applied to individual facilities through National
Pollutant Discharge Elimination System (NPDES) permits issued by EPA or authorized states
under Section 402 of the Clean Water Act (CWA). The regulations applicable to indirect
dischargers are standards and are administered by local permitting authorities (i.e., the
government entity controlling the publicly-owned treatment works (POTW) to which the
industrial wastewater is discharged. The pretreatment standards are designed to control
pollutants that pass through or interfere with POTWs.
9.1.1
Common Elements of All Options
Technology options for all subcategories have two common elements.
1. Good Heel Removal and Management Practices. The benefits of good
heel removal and management practices include the following:
— Prevent pollutants from entering the wastewater stream (Let,
maximum removal of heel prior to tank cleaning minimizes the
pollutant loading in the tank interior cleaning wastewater stream);
— Provides a potential to recover/reuse valuable product; and
— May reduce wastewater treatment system capital and annual costs
due to reduced wastewater pollutant loadings.
The components of good heel removal and management practices are discussed in detail in
Section 8.1.2.
9-2
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Section 9.0 - Development of Control gnd Treatment Options
Based on responses to the Detailed Questionnaire, the majority of transportation
equipment cleaning (TEC) facilities currently operate good heel removal and management
practices. Because of the many benefits of these practices, and a demonstrated trend in the TECI
to implement these practices, EPA believes that the TECI will have universally implemented
good heel removal and management practices prior to implementation of TECI effluent
guidelines. Therefore, EPA is allocating no costs or pollutant reductions for this component of
the technology option bases.
2. Good Water Conservation Practices. The benefits of good water
conservation practices include the following:
— Reduced water usage and sewage fees;
— Improved wastewater treatment performance and efficiency
because influent wastewater pollutant concentrations will be
higher; and
— Reduced wastewater treatment system capital and annual operating
and maintenance (O&M) costs due to reduced wastewater flows.
The components of good water conservation practices are discussed in detail in Section 8.2.
End-of-pipe wastewater treatment cannot achieve complete removal of pollutants.
There is a lowest concentration that wastewater treatment technologies have been demonstrated
to achieve. As shown in the equation below, pollutant loadings in wastewater are dependent
upon wastewater pollutant concentration and on wastewater flow.
C x PNF
PNPL =
264,170
(1)
where:
PNPL =
{~* —
PNF =
Production normalized pollutant load, g/tank
Concentration, ug/L
Production normalized flow, gallons/tank
9-3
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Section 9.0 - Development of Control and Treatment Options
Equation (1) demonstrates that optimal pollutant reductions are achieved using a combination of
good water conservation practices and end-of-pipe wastewater treatment.
In developing effluent guidelines limitations and standards for the TECI, the EPA
included good water conservation practices as a component of the technology bases for all
regulatory options. The Agency considered good water conservation practices to be represented
by the median tank interior cleaning wastewater volume discharged per tank cleaning (including
non-TEC wastewater streams not easily segregated) for each subcategory. This wastewater
volume is referred to as the "regulatory flow" for each subcategory. Table 9-1 at the end of this
section presents the subcategory-specific regulatory flows for existing facilities. Development of
the subcategory-specific regulatory flows is described in the following subsection.
Since good water conservation practices are defined by the median subcategory
flow, 50% of existing TEC facilities currently operate good water conservation practices. For the
remaining 50% of TEC facilities, EPA considered a variety of control technologies depending
upon the extent of flow reduction required at a given facility to achieve the median subcategory
flow. For the truck and rail subcategories, with the exception of hoppers, the control
technologies include the following:
For facilities with current flow to regulatory flow ratios greater than 1 and
less than or equal to 1.5:
— Facility water use monitoring, and
— Personnel training in water conservation.
For facilities with current flow to median subcategorv flow ratios greater
than 1.5 and less than or equal to 2:
— Facility water use monitoring,
— Personnel training in water conservation, and
Two new spinners and spinner covers.
9-4
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Section 9.0 - Development of Control and Treatment Options
For facilities with current flow to median subcategorv flow ratios greater
than 2:
— Facility water use monitoring,
— Personnel training in water conservation, and
— New tank interior cleaning system(s)1.
For the hopper subcategories, the control technologies include the following:
For facilities with current flow to regulatory flow ratios greater than 1:
— Facility water use monitoring, and
— Personnel training in water conservation.
For the barge subcategories, the control technologies include the following:
For facilities with current flow to regulatory flow ratios greater than 1:
— Facility water use monitoring,
— Personnel training in water conservation, and
— Contract hauling of heel.
In calculating compliance cost estimates (see Section 10.0), EPA assumed that the
flow reduction technology options are sufficient to achieve the regulatory flow for all facilities
based on the selection criteria described above. Additional details concerning EPA's flow
reduction methodology, the flow reduction control technologies, and application of the flow
technologies are included in the TECI cost model documentation contained in the rulemaking
record.
1 New tank interior cleaning system(s) include(s) solution tanks, controls, pumps, piping, catwalks, stairways, rails,
and spinners.
9-5
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9.1.2
Section 9.0 - Development of Control and Treatment Options
Development of Subcategory-Specific Regulatory Flows
Waste streams considered in developing the regulatory flows include TEC
wastewater. TEC wastewater includes the following waste streams:
Water and steam used to clean tank and container interiors;
Prerinse cleaning solutions;
Chemical cleaning solutions;
Final rinse solutions;
Tank or trailer exterior cleaning wastewater;
Equipment and floor washings; and
TEC-contaminated stormwater.
The following waste streams were not considered in developing the regulatory flows:
• Bilge and ballast waters;
• Non-TEC process wastewaters;
• Sanitary wastewater;
• Tank hydrotesting water; and
• Wastewater generated from rebuilding or maintenance activities.
Subcategory-specific regulatory flows were calculated based on responses to the
Detailed Questionnaire. EPA first reviewed wastewater streams discharged by each facility and
classified these streams as described above. EPA then calculated a facility-specific production-
normalized flow expressed in gallons of wastewater discharged per tank cleaned based on the
TEC wastewater flow rate and the annual number of tanks cleaned. Facilities that clean tanks
representing multiple modes of transportation (e.g., road, rail, or inland waterway) or that clean
both tanks and closed-top hoppers are considered multi-subcategory facilities. For the purpose of
developing the subcategory-specific regulatory flows, these facilities were assigned a primary
subcategory, and the flow contribution of any secondary subcategory was not considered in the
analysis.
For each subcategory, using the facility-specific production-normalized flows and
the corresponding facility-specific survey weighting factors, EPA performed a statistical analysis
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Section 9.0 - Development of Control and Treatment Options
to determine the median wastewater volume generated per tank cleaned. Detailed information
concerning calculation of the regulatory flows is included in the Statistical Support Document
(1).
9.2
Best Practicable Control Technology Currently Available
(BPT)
EPA proposes BPT effluent limitations for the Truck/Chemical, Rail/Chemical,
Barge/Chemical & Petroleum, Truck/Food, Rail/Food, and Barge/Food Subcategories. The
proposed BPT effluent limitations would control identified conventional, priority, and
nonconventional pollutants when discharged from TEC facilities to surface waters of the U.S.
Generally, EPA determines BPT effluent levels based upon the average of the best existing
performances by plants of various sizes, ages, and unit processes within each industrial category
or subcategory. In industrial categories where present practices are uniformly inadequate,
however, EPA may determine that BPT requires higher levels of control than any currently in
place if the technology to achieve those levels can be practicably applied.
In addition, CWA Section 304(b)(l)(B) requires a cost assessment for BPT
limitations. In determining the BPT limits, EPA must consider the total cost of treatment
technologies in relation to the effluent reduction benefits achieved. This inquiry does not limit
EPA's broad discretion to adopt BPT limitations that are achievable with available technology
unless the required additional reductions are "wholly out of proportion to the costs of achieving
such marginal level of reduction." See Legislative History, op. cit. p. 170. Moreover, the inquiry
does not require the Agency to quantify benefits in monetary terms. See e.g. American Iron and
Steel Institute v. EPA, 526 F. 2d 1027 (3rd Cir., 1975).
In balancing costs against the benefits of effluent reduction, EPA considers the
volume and nature of expected discharges after application of BPT, the general environmental
effects of pollutants, and the cost and economic impacts of the required level of pollution control.
In developing guidelines, the CWA does not require or permit consideration of water quality
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Section 9.0 - Development of Control and Treatment Options
problems attributable to particular point sources, or water quality improvements in particular
bodies of water. Therefore, EPA has not considered these factors in developing the limitations
being proposed today. See Weyerhaeuser Company v. Costle. 590 F. 2d 1011 (D.C. Cir. 1978).
EPA identified relatively few direct discharging facilities for most subcategories
in the TECI as compared to the number of indirect discharging facilities. However, the Agency
concluded that direct discharging facilities are similar to indirect discharging facilities in terms of
types of tanks cleaned, types of commodities cleaned, water use, and wastewater characteristics.
With respect to existing end-of-pipe wastewater treatment in place, direct discharging facilities
typically operate biological treatment in addition to physical/chemical treatment technologies
typically operated by indirect discharging facilities.
9.2.1
BPT Options for the Truck/Chemical Subcategory
BPT options for the Truck/Chemical Subcategory include the following
technology bases in addition to the common technology option elements discussed in Section
9.1.1.
Option 1: Equalization, Oil/Water Separation, Chemical Oxidation, Neutralization,
Coagulation, Clarification, Biological Treatment, and Sludge Dewatering
Option 2: Equalization, Oil/Water Separation, Chemical Oxidation, Neutralization,
Coagulation, Clarification, Biological Treatment, Activated Carbon Adsorption,
and Sludge Dewatering
The purpose and design bases of the components of these technology options are described
below. These technologies are also described in further detail in Section 8.3.
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Equalization
Purpose:
Section 9.0 - Development of Control and Treatment Options
Reduce wastewater variability and accumulate wastewater to optimize subsequent
treatment system size arid operating costs.
Design Basis: Minimum 12-hour residence time. Includes aerators/mixers to homogenize
wastewater.
Oil/Water Separation
Purpose: Removal of entrained oil and grease.
Design Basis: Vertical tube coalescing separator with rotary oil skimmer. Includes demulsifier
chemical additive, oil storage tank, and sludge storage tank.
Chemical Oxidation. Neutralization. Coagulation, and Clarification
Purpose: Chemical Oxidation - chemically oxidize pollutants using oxidants such as
hydrogen peroxide.
Neutralization - adjust wastewater pH.
Coagulation - destabilize (reduce repulsive interaction) particle suspension using
electrolytes to aggregate suspended matter.
Clarification - settle and remove agglomerated coagulated solids.
Design Basis: Turn-key treatment system consisting of four reaction tanks in series plus a
clearwell. Includes chemical feed systems, mixers, control system, and sludge
storage tanks.
Biological Treatment
Purpose: Biologically decompose organic constituents.
Design Basis: Activated sludge biological treatment system with a 4.6-day residence time.
Includes two preaeration tanks in series and a sludge storage tank.
Activated Carbon Adsorption
Purpose: Wastewater polishing.
Design Basis: Two carbon columns in series with nominal carbon change-out frequency of once
per month. Includes carbon charge of 250 Ib/gpm/vessel.
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Section 9.0 - Development of Control and Treatment Options
Sludge Dewatering
Purpose: Reduce sludge volume by removing water.
Design Basis: Plate-and-frame filter press. Generates dewatered sludge at 32.5% solids.
EPA is proposing to establish BPT effluent limitations based on Option 2.
Agency data indicate that a treatment train consisting of physical/chemical treatment for the
removal of metals and toxics, biological treatment for the removal of decomposable organic
material, and activated carbon adsorption for removal of residual organics and toxics represents
the average of the best treatment in the industry. As noted above, all existing direct discharging
facilities in this subcategory currently employ equalization, coagulation/clarification, biological
treatment and activated adsorption. Although no direct discharging facilities were given credit in
EPA's costing model for a coalescing plate oil/water separator, this technology is common and
demonstrated practice in the industry to improve the overall efficiency of the treatment system.
EPA has included the use of oil/water separation in its cost estimates to the industry in order to
ensure that the biological system performs optimally.
EPA's decision to base BPT limitations on Option 2 treatment reflects primarily
two factors: 1) the degree of effluent reductions attainable and 2) the total cost of the proposed
treatment technologies in relation to the effluent reductions achieved.
No basis could be found for identifying different BPT limitations based on age,
size, process, or other engineering factors. Neither the age nor the size of the TEC facility will
directly affect the treatability of the TEC wastewaters. For Truck/Chemical facilities, the most
pertinent factors for establishing the limitations are costs of treatment and the level of effluent
reductions obtainable.
The estimated compliance costs for Option 2 are $104,000 in O&M annual costs
and $134,000 in total capital costs.
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9.2.2
Section 9.0 - Development of Control and Treatment Options
BPT Options for the Rail/Chemical Subcategory
BPT options for the Rail/Chemical Subcategory include the following technology
bases in addition to the common technology option elements discussed in Section 9.1.1.
Option 1: Oil/Water Separation, Equalization, Biological Treatment, and Sludge Dewatering
Option 2: Oil/Water Separation, Equalization, Dissolved Air Flotation (with Flocculation
and pH Adjustment), Biological Treatment, and Sludge Dewatering
Option 3: Oil/Water Separation, Equalization, Dissolved Air Flotation (with Flocculation
and pH Adjustment), Biological Treatment, Organo-Clay/Activated Carbon
Adsorption, and Sludge Dewatering
The purpose and design bases of the components of these technology options are described
below. These technologies are also described in further detail in Section 8.3.
Oil/Water Separation
Purpose: Removal of entrained oil and grease.
Design Basis: API separator with slotted pipe surface oil skimmer, fabric belt skimmer for
entrained thin oils, and bottom sludge rake. Includes oil storage tank and sludge
storage tank.
Equalization
Purpose: Reduce wastewater variability and accumulate wastewater to optimize subsequent
treatment system size and operating costs.
Design Basis: Two tanks in parallel, each with minimum 24-hour residence time. Includes
aerators to homogenize wastewater.
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Section 9.0 - Development of Control and Treatment Options
Dissolved Air Flotation
Purpose: Removal of entrained solid or liquid particles.
Design Basis: Dissolved air flotation unit with recycle pressurization system. Includes chemical
addition systems for polymers (coagulants and flocculant) and pH adjustment,
sludge collection tank, and pre-fabricated building.
Biological Treatment
Purpose: Biologically decompose organic constituents.
Design Basis: Activated sludge biological treatment system with a 4.6-day residence time.
Includes two preaeration tanks in series and a sludge storage tank.
Organo-Clav/Activated Carbon Adsorption
Purpose: ' Wastewater polishing.
Design Basis: Two columns in series - organo-clay followed by carbon - with nominal carbon
change-out frequency of one vessel per month and nominal organo-clay change-
out frequency of one vessel every two months. Includes organo-clay charge of
1.44 ftVgpm/vessel and carbon charge of 1.44 ftVgpm/vessel.
Sludge Dewatering
Purpose: Reduce sludge volume by removing water.
Design Basis: Plate-and-frame filter press. Generates dewatered sludge at 32.5% solids.
Includes sludge storage tank.
EPA is proposing to set BPT regulations for the Rail/Chemical Subcategory based
on technology Option 1. EPA's decision to base BPT limitations on Option 1 treatment reflects
primarily two factors: 1) the degree of effluent reductions attainable and 2) the total cost of the
proposed treatment technologies in relation to the effluent reductions achieved.
No basis could be found for identifying different BPT limitations based on age,
size, process, or other engineering factors. Neither the age nor the size of the TEC facility will
directly affect the treatability of the TEC wastewaters. For Rail/Chemical facilities, the most
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Section 9.0 - Development of Control and Treatment Options
pertinent factors for establishing the limitations are costs of treatment and the.level of effluent
reductions obtainable.
EPA has selected Option 1 based on the comparison of the three options in terms
of total costs of achieving the effluent reductions, pounds of pollutant removals, economic
impacts, and general environmental effects of the reduced pollutant discharges.
EPA estimates that implementation of Option 1 will cost $103 dollars per pound
of pollutants removed. Although this projected cost per pound appears to be high, EPA has used
a very conservative cost approach to project costs to the industry. The one facility in EPA's cost
model is already projected to meet the proposed effluent limitations due to the low effluent levels
achieved at this facility, which average 8 mg/L of BOD5. However, because EPA's proposed
treatment technology includes oil/water separation, the cost model has assumed that this facility
will incur additional costs to install this treatment. Additionally, EPA has given no credit to any
facility for current monitoring practices. Therefore, EPA has assumed that all monitoring
requirements will result in an increase in costs to the industry. In reality, this facility will likely
not need to install additional treatment to meet the proposed limits, and some of the monitoring
costs assumed by EPA will not be an additional cost burden to the industry.
The technology proposed in Option 1 represents the average of the best
performing facilities due to the prevalence of biological treatment and sludge dewatering.
Although no direct discharging facilities were given credit in EPA's costing model for oil/water
separation, this technology is common and demonstrated practice in the industry to improve the
overall efficiency of the wastewater treatment system. EPA has included the use of oil/water
separation in its cost estimates to the industry in order to ensure that the biological system
performs optimally.
Finally, EPA also looked at the costs of all options to determine the economic
impact that this proposal would have on the TECI. EPA expects the financial and economic
profile of the direct dischargers to be comparable to that of the estimated 38 indirect dischargers.
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Section 9.0 - Development of Control and Treatment Options
EPA anticipates that the economic impact, in terms of facility closures and employment losses,
due to the additional controls at BPT Option 2 and 3 levels would be comparable to that
estimated in EPA's assessment for indirect dischargers, potentially leading to six facility closures
and the associated loss of over 400 employees. The annual cost per facility for BPT Option 1 is
projected to be $12,900 less than the technology evaluated for PSES which caused six facility
closures. Therefore, EPA has concluded that the costs of BPT Option 1 are achievable and are
reasonable as compared to the removals achieved by this option.
The estimated compliance costs for Option 1 are $42,000 in O&M annual costs
and $113,000 in total capital costs.
9.2.3
BPT Options for the Barge/Chemical & Petroleum
Subcategory
BPT options for the Barge/Chemical & Petroleum Subcategory include the
following technology bases in addition to the common technology option elements discussed in
Section 9.1.1.
Option 1: Oil/Water Separation, Dissolved Air Flotation, Filter Press, Biological Treatment,
and Sludge Dewatering
Option 2: Oil/Water Separation, Dissolved Air Flotation, Filter Press, Biological Treatment,
Reverse Osmosis, and Sludge Dewatering
The purpose and design bases of the components of these technology options are described
below. These technologies are also described in further detail in Section 8.3.
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Section 9.0 - Development of Control and Treatment Options
Oil/Water Separation
Purpose:
Removal of low to moderate amounts of insoluble oil.
Design Basis: Gravity separator with 6.4-day residence time for wastewater equalization and oil,
water, and solids separation. Includes two separation tanks in series with an oil
removal pump and an oil storage tank.
Dissolved Air Flotation
Purpose: Removal of entrained solid or liquid particles.
Design Basis: Dissolved air flotation unit with influent pressurization system. Includes sludge
storage tank.
Filter Press
Purpose: Wastewater filtration.
Design Basis: In-line plate-and-frame filter press for wastewater filtration. Generates dewatered
sludge at 32.0% solids. Includes diatomaceous earth mix tank and wastewater
effluent storage tank.
Biological Treatment
Purpose: Biologically decompose organic constituents.
Design Basis: Activated sludge biological treatment system with a 4.6-day residence time.
Includes two preaeration tanks in series, a clarifier, and a sludge storage tank.
Reverse Osmosis
Purpose: Wastewater polishing.
Design Basis: Reverse osmosis system including unit with membranes, influent wastewater
storage tanks, and flooded suction tank.
Sludge Dewatering
Purpose: Reduce biological treatment sludge volume by removing water.
Design Basis: Sludge is dewatered in in-line wastewater plate-and-frame filter press described
above.
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Section 9.0 - Development of Control and Treatment Options
EPA estimates that implementation of Option 1 will cost $0.35 per pound of
pollutants removed, and has found that cost to be reasonable. Additionally, the Agency
concluded that reverse osmosis is not commonly used in the industry, and therefore Option 2
does not represent the average of the best treatment. Finally, EPA also looked at the costs of all
options to determine the economic impact that this proposal would have on the TECI. EPA's
assessment showed that implementation of BPT is projected to result in no facility closures and
no employment losses. Therefore, EPA has concluded that the total costs associated with the
proposed BPT option are achievable and are reasonable as compared to the removals achieved by
this option.
The estimated compliance costs for Option 1 are $1,900,000 in O&M annual costs
and $3,200,000 in total capital costs.
9.2.4
BPT Options for the Truck/Food, Rail/Food, and Barge/Food
Subcategories
BPT options for the Truck/Food, Rail/Food, and Barge/Food Subcategories
include the following technology bases in addition to the common technology option elements
discussed in Section 9.1.1.
Option 1: Oil/Water Separation
Option 2: Oil/Water Separation, Equalization, Biological Treatment, and Sludge Dewatering
The purpose and design bases of the components of these technology options are described
below. These technologies are also described in further detail in Section 8.3.
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Section 9.0 - Development of Control and Treatment Options
Oil/Water Separation
Purpose: Removal of low to moderate amounts of insoluble oil.
Design Basis: Gravity separator with 6.4-day residence time for wastewater equalization and oil,
water, and solids separation. Includes two separation tanks in series with an oil
removal pump and an oil storage tank.
Equalization
Purpose: Reduce wastewater variability and accumulate wastewater to optimize subsequent
treatment system size and operating costs.
Design Basis: Eight-day residence time. Includes aerators/mixers to homogenize wastewater.
Biological Treatment
Purpose: Biologically decompose organic constituents.
Design Basis: Activated sludge biological treatment system with a 4.6-day residence time.
Includes two preaeration tanks in series and a sludge storage tank.
Sludge Dewatering
Purpose: Reduce biological treatment sludge volume by removing water.
Design Basis: Plate-and-frame filter press for wastewater filtration. Generates dewatered sludge
at 32.0% solids. Includes diatomaceous earth mix tank.
Based on Screener Questionnaire results, EPA estimates that there are 19 direct
discharging facilities in the Truck/Food, Rail/Food, and Barge/Food Subcategories. However,
EPA's survey of the TECI did not initially identify any direct discharging facilities through the
Detailed Questionnaire sample population.
Because all types of facilities in the food subcategories accept similar types of
cargos which generate similar types of wastewater in terms of treatability and toxicity, EPA has
tentatively determined that the same treatment technology can be applied to all three (truck, rail
and barge) food subcategories. The wastewater generated by the food subcategories contains
high loadings of biodegradable organics, and few toxic pollutants. EPA conducted sampling at a
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Section 9.0 - Development of Control and Treatment Options
direct discharging Barge/Food facility which EPA believes to be representative of the entire
population.
Based on the data collected by EPA, raw wastewater contained significant levels
of organic material in the raw wastewater, exhibiting an average BOD5 concentration of 3,500
mg/L. Therefore, EPA concluded that some form of biological treatment is necessary to reduce
potential impacts to receiving waters from direct discharging facilities and EPA anticipated that
all direct discharging facilities in these subcategories would have some form of biological
treatment in place. All existing facilities which responded to the Screener Questionnaire
indicated that they did, in fact, have a biological treatment system in place. Therefore, EPA
proposes to establish BPT based on Option 2 for the Truck/Food, Rail/Food, and Barge/Food
Subcategories
EPA projects no additional pollutant removals and no additional costs to the
industry based on EPA's selection of Option 2 because all facilities identified by EPA currently
have the proposed technology in place.
EPA estimates zero compliance costs for Option 2.
9.2.5
BPT Options for the Truck/Petroleum and Rail/Petroleum
Subcategories
EPA did not develop or evaluate BPT Options for the Truck/Petroleum and
Rail/Petroleum Subcategories for the following reasons: (1) all direct discharging facilities
previously identified by the Agency are no longer in operation; (2) EPA is not aware of any new
facilities that have recently begun operations; and (3) EPA believes that permit writers can more
appropriately control discharges from these facilities, if any, using best professional judgment.
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9.2.6
Section 9.0 - Development of Control and Treatment Options
BPT Options for the Truck/Hopper, Rail/Hopper, and
Barge/Hopper Subcategories
BPT options for the Truck/Hopper, Rail/Hopper, and Barge/Hopper Subcategories
include the following technology bases in addition to the common technology option elements
discussed in Section 9.1.1.
Option 1: Gravity Separation
The purpose and design bases of the components of this technology option are described below.
This technology is also described in further detail in Section 8.3.
Gravity Separation
Purpose: Removal of suspended solids.
Design Basis: Gravity separator with 4-day residence time for wastewater equalization and
solids separation. Includes two separation tanks in series.
EPA is not proposing to establish BPT regulations for any of the hopper
Subcategories. EPA concluded that hopper facilities discharge very few pounds of conventional
or toxic pollutants. This is based on EPA sampling data, which found very few priority toxic
pollutants at treatable levels in raw wastewater. Additionally, very little wastewater is generated
from cleaning the interiors of hopper tanks due to the dry nature of bulk materials transported.
Therefore, nationally-applicable regulations are unnecessary at this time and direct dischargers
will remain subject to limitations established on a case-by-case basis using best professional-
judgement.
9.3
Best Conventional Pollutant Control Technology (BCD
BCT limitations control the discharge of conventional pollutants from direct
dischargers. Conventional pollutants include BOD, TSS, oil and grease, and pH. BCT is not an
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Section 9.0 - Development of Control and Treatment Options
additional limitation, but rather replaces BAT for the control of conventional pollutants. To
develop BCT limitations, EPA conducts a cost reasonableness evaluation, which consists of a
two-part cost test: 1) the POTW test, and 2) the industry cost-effectiveness test.
In the POTW test, EPA calculates the cost per pound of conventional pollutants
removed by industrial dischargers in upgrading from BPT to a BCT candidate technology and
then compares this to the cost per pound of conventional pollutants removed in upgrading
POTWs from secondary to tertiary treatment. The upgrade cost to industry, which is represented
in dollars per pound of conventional pollutants removed, must be less than the POTW
benchmark of $0.25 per pound (in 1976 dollars). In the industry cost-effectiveness test, the ratio
of the incremental BPT to BCT cost, divided by the BPT cost for the industry, must be less that
1.29 (i.e. the cost increase must be less than 29 percent).
EPA is proposing to establish effluent limitations guidelines and standards
equivalent to the BPT for the conventional pollutants covered under BPT for all subcategories.
In developing BCT limits, EPA considered whether there are technologies that achieve greater
removals of conventional pollutants than proposed for BPT, and whether those technologies are
cost-reasonable according to the BCT Cost Test. In each subcategory, EPA identified no
technologies that can achieve greater removals of conventional pollutants than those proposed for
BPT that are also cost-reasonable under the BCT Cost Test, and accordingly EPA proposes BCT
effluent limitations equal to the proposed BPT effluent limitations guidelines and standards.
9.4
Best Available Technology Economically Achievable (BAT)
The factors considered in establishing a BAT level of control include: the age of
process equipment and facilities, the processes employed, process changes, the engineering
aspects of applying various types of control techniques to the costs of applying the control
technology, non-water quality environmental impacts such as energy requirements, air pollution
and solid waste generation, and such other factors as the Administrator deems appropriate
(Section 304(b)(2)(B) of the Act). In general, the BAT technology level represents the best
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Section 9.0 - Development of Control and Treatment Options
existing economically achievable performance among facilities with shared characteristics. BAT
may include process changes or internal plant controls which are not common in the industry.
BAT may also be transferred from a different subcategory or industrial category.
EPA is proposing BAT effluent limitations for the Truck/Chemical,
Rail/Chemical, and Barge/Chemical & Petroleum Subcategories based upon the same
technologies evaluated and proposed for BPT. The proposed BAT effluent limitations would
control identified toxic and nonconventional pollutants discharged from facilities. EPA did not
identify any additional technologies beyond BPT that could provide additional toxic pollutant
removals and that are economically achievable. EPA is not proposing to establish BAT
limitations for the Truck/Food, Rail/Food or Barge/Food Subcategories because EPA found that
food grade facilities discharge very few pounds of toxic pollutants not amenable to treatment by a
POTW.
9.5
New Source Performance Standards (NSPS)
New Source Performance Standards under Section, 306 of the CWA represent the
greatest degree of effluent reduction achievable through the application of the best available
demonstrated control technology for all pollutants (i.e. conventional, nonconventional, and toxic
pollutants). NSPS are applicable to new industrial direct discharging facilities, for which
construction has commenced after the publication of proposed regulations. Congress envisioned
that new treatment systems could meet tighter controls than existing sources because of the
opportunity to incorporate the most efficient processes and treatment systems into plant design.
Therefore, Congress directed EPA, in establishing NSPS, to consider the best demonstrated
process changes, in-plant controls, operating methods, and end-of-pipe treatment technologies
that reduce pollution to the maximum extent feasible.
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9.5.1
Section 9.0 - Development of Control and Treattnent Options
NSPS Options for the Track/Chemical Subcategory
EPA has not identified any more stringent treatment technology option which it
considered to represent NSPS level of control applicable to Truck/Chemical facilities in this
industry. Further, EPA has made a finding of no barrier to entry based upon the establishment of
this level of control for new sources. Therefore, EPA is proposing that NSPS for the
Truck/Chemical Subcategory be established equivalent to BPT for conventional, priority, and
nonconventional pollutants.
9.5.2
NSPS Options for the Rail/Chemical Subcategory
EPA evaluated BPT Options 2 and 3 as a basis for establishing NSPS more
stringent than the BAT level of control being proposed today. The cost implications anticipated
for new sources are not as severe as those projected for existing sources. By utilizing good heel
removal and management practices which prevent pollutants from entering waste streams, and
good water conservation practices in the design of new facilities, treatment unit size can be
substantially reduced and treatment efficiencies improved. As .a result, costs of achieving BPT
Options 2 and 3 can be significantly reduced by new sources. BPT Option 2 and 3 technologies
have been demonstrated at an existing zero discharge Rail/Chemical facility. EPA anticipates no
barrier to entry for new sources employing these technologies at lower cost. Furthermore, based
on an analysis of benefits for existing sources, significant environmental differences would be
anticipated between Options 1 and 2 and Option 3 for new sources. Therefore, EPA is proposing
to establish new source performance standards for the Rail/Chemical Subcategory based on BPT
Option 3. Option 3 consists of flow reduction, oil/water separation, equalization, dissolved air
flotation (with flocculation and pH adjustment), biological treatment, organo-clay/activated
carbon adsorption, and sludge dewatering.
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Section 9.0 - Development of Control and Treatment Options
9.5.3
NSPS Options for the Barge/Chemical & Petroleum
Subcategory
EPA evaluated BPT Option 2 as a basis for establishing NSPS more stringent than
the proposed BAT level of control. EPA rejected BPT Option 2 as a basis for NSPS for the same
reasons this additional technology was rejected for BAT. Even though the cost implications for
new sources are not as severe as those projected for existing sources, the cost and economic
implications of BPT Option 2 do bear upon the determination that reverse osmosis technology is
inappropriate for consideration as part of the best available technology for the control of
pollutants for this subcategory.
Reverse osmosis was not considered to be the best available technology due to the
small incremental removals achieved by this option, the lack of additional water quality benefits
potentially achieved by this option, the potential issue of disposing the liquid concentrate created
by treatment, and the high level of pollutant control achieved by the proposed "BAT option.
Therefore, EPA is proposing that NSPS for the Barge/Chemical & Petroleum
Subcategory be established equivalent to BPT for conventional, priority, and nonconventional
pollutants.
9.5.4
NSPS Options for the Truck/Food, Rail/Food, and Barge/Food
Subcategories .
EPA has not identified any more stringent treatment technology option which it
considered to represent NSPS level of control applicable to food subcategory facilities in this
industry. Further, EPA has made a finding of no barrier to entry based upon the establishment of
this level of control for new sources. Therefore, EPA is proposing that NSPS for the food
subcategories be established equivalent to BPT for conventional pollutants.
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9.5.5
Section 9.0 - Development of Control and Treatment Options
NSPS Options for the Truck/Petroleum and Rail/Petroleum
Subcategories
EPA did not develop or evaluate BAT options for these subcategories for the
following reasons: (1) all direct discharging facilities previously identified by the Agency are no
longer in operation; (2) EPA is not aware of any new facilities that have recently begun
operations; and (3) EPA currently believes permit writers can more appropriately control
discharges from these facilities, if any, using best professional judgement. EPA is therefore
proposing not to establish NSPS for the Truck/Petroleum and Rail/Petroleum Subcategories.
9.5.6
NSPS Options for the Truck/Hopper, Rail/Hopper, and
Barge/Hopper Subcategories
EPA is not proposing to establish NSPS regulations for any of the hopper
subcategories. EPA concluded that hopper facilities discharge very few pounds of toxic
pollutants, and contain very few priority toxic pollutants at treatable levels in raw wastewater.
Additionally, very little wastewater is generated from cleaning the interiors of hopper tanks due
to the dry nature of bulk materials transported. Therefore, nationally-applicable regulations are
unnecessary at this time and direct dischargers will remain subject to limitations established on a
case-by-case basis using best professional judgement.
9.6
Pretreatment Standards for Existing Sources (PSES)
Pretreatment standards are designed to prevent the discharge of toxic pollutants
that pass through, interfere with, or are otherwise incompatible with the operation of POTWs, as
specified in Section 307(b) of the CWA. PSES are technology-based and analogous to BAT
limitations for direct dischargers.
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9.6.1
Section 9.0 - Development of Control and Treatment Options
PSES Options for the Truck/Chemical Subcategory
PSES options for the Truck/Chemical Subcategory include the following
technology bases in addition to the common technology option elements discussed in Section
9.1.1.
Option 1: Equalization, Oil/Water Separation, Chemical Oxidation, Neutralization,
Coagulation, Clarification, and Sludge Dewatering
Option 2: Equalization, Oil/Water Separation, Chemical Oxidation, Neutralization,
Coagulation, Clarification, Activated Carbon Adsorption, and Sludge Dewatering
The purpose and design bases of the components of these technology options are described
below. These technologies are also described in further detail in Section 8.3.
Equalization
Purpose:
Reduce wastewater variability and accumulate wastewater to optimize subsequent
treatment system size and operating costs.
Design Basis: Minimum 12-hour residence time. Includes aerators/mixers to homogenize
wastewater.
Oil/Water Separation
Purpose: Removal of entrained oil and grease.
Design Basis: Vertical tube coalescing separator with rotary oil skimmer. Includes demulsifier
chemical additive, and oil storage tank.
Chemical Oxidation. Neutralization, Coagulation, and Clarification
Purpose: Chemical Oxidation - chemically oxidize pollutants using oxidants such as
hydrogen peroxide.
Neutralization - adjust wastewater pH.
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Section 9.0 - Development of Control and Treatment Options
Coagulation - destabilize (reduce repulsive interaction) particle suspension using
electrolytes to aggregate suspended matter.
Clarification - settle and remove agglomerated coagulated solids.
Design Basis: Turn-key treatment system consisting of four reaction tanks in series plus a
clearwell. Includes chemical feed systems, mixers, control system, and sludge
storage tanks.
Carbon Adsorption
Purpose: Wastewater polishing.
Design Basis: Two carbon columns in series with nominal carbon change-out frequency of once
per month. Includes carbon charge of 250 Ib/gpm/vessel.
Sludge Dewatering
Purpose: Reduce sludge volume by removing water.
Design Basis: Plate-and-frame filter press. Generates dewatered sludge at 32.5% solids.
EPA is proposing to establish pretreatment standards based on Option 2 based on
the additional removals achieved by this option. EPA has determined that Option 2 is
economically achievable and results in no facility closures or projected employment losses.
The estimated compliance costs for Option 2 are $24,700,000 in O&M annual
costs and $53,600,000 in total capital costs.
9.6.2
PSES Options for the Rail/Chemical Subcategory
PSES options for the Rail/Chemical Subcategory include the following
technology bases in addition to the common technology option elements discussed in Section
9.1.1.
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Section 9.0 - Development of Control and Treatment Options
Option 1: Oil/Water Separation
Option 2: Oil/Water Separation, Equalization, Dissolved Air Flotation (with Flocculation
and pH Adjustment), and Sludge Dewatering
Option 3: Oil/Water Separation, Equalization, Dissolved Air Flotation (with Flocculation
and pH Adjustment), Organo-Clay/Activated Carbon Adsorption, and Sludge
Dewatering
The purpose and design bases of the components of these technology options are described
below. These technologies are also described in further detail in Section 8.3.
Oil/Water Separation
Purpose: Removal of entrained oil and grease.
Design Basis: API separator with slotted pipe surface oil skimmer, fabric belt skimmer for
entrained thin oils, and bottom sludge rake. Includes oil storage tank and sludge
storage tank.
Equalization
Purpose: Reduce wastewater variability and accumulate wastewater to optimize subsequent
treatment system size and operating costs.
Design Basis: Two tanks in parallel, each with minimum 24-hour residence time. Includes
aerators to homogenize wastewater.
Dissolved Air Flotation
Purpose: Removal of entrained solid or liquid particles.
Design Basis: Dissolved air flotation unit with recycle pressurization system. Includes chemical
addition systems for polymers (coagulants and flocculant) and pH adjustment,
sludge collection tank, and pre-fabricated building.
Organo-Clav/Activated Carbon Adsorption
Purpose:
Wastewater polishing.
Design Basis: Two columns in series - organo-clay followed by carbon - with nominal carbon
change-out frequency of one vessel per month and nominal organo-clay change-
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Section 9.0 - Development of Control and Treatment Options
out frequency of one vessel every two months. Includes organo-clay charge of
1.44 ftVgpm/vessel and carbon charge of 1.44 ftVgpm/vessel.
Sludge Dewatering
Purpose: Reduce sludge volume by removing water.
Design Basis: Plate-and-frame filter press. Generates dewatered sludge at 32.5% solids.
Includes sludge storage tank.
EPA is proposing to establish pretreatment standards for the Rail/Chemical
Subcategory based on Option 1. EPA estimates that this option does not result in any facility
closures or employment losses to the industry. Option 2, however, was projected to result in six
facility closures and is demonstrated not to be economically achievable.
The estimated compliance costs for Option 1 are $1,400,000 in O&M annual costs
and $4,400,000 in total capital costs..
9.6.3
PSES Options for the Barge/Chemical & Petroleum
Subcategory
PSES options for the Barge/Chemical & Petroleum Subcategory include the
following technology bases in addition to the common technology option elements discussed in
Section 9.1.1.
Option 1: Oil/Water Separation, Dissolved Air Flotation, and Filter Press
Options 2: Oil/Water Separation, Dissolved Air Flotation, Filter Press, Biological Treatment,
and Sludge Dewatering
Option 3: Oil/Water Separation, Dissolved Air Rotation, Filter Press, Biological Treatment,
Reverse Osmosis, and Sludge Dewatering
The purpose and design bases of the components of these technology options are described
below. These technologies are also described in further detail in Section 8.3.
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Section 9.0 - Development of Control and Treatment Options
Oil/Water Separation
Purpose: Removal of low to moderate amounts of insoluble oil.
Design Basis: Gravity separator with 6.4-day residence time for wastewater equalization and oil,
water, and solids preparation. Includes two separation tanks in series with an oil
removal pump and an oil storage tank.
Dissolved Air Flotation
Purpose: Removal of entrailed solid or liquid particles.
Design Basis: Dissolved air flotation unit with influent pressurization system. Includes sludge
storage tank.
Filter Press
Purpose:
Wastewater filtration.
Design Basis: In-line plate-and-frame filter press for wastewater filtration. Generates dewatered
sludge at 32.0% solids. Includes diatomaceous earth mix tank and wastewater
effluent storage tank.
Biological Treatment
Purpose: Biologically decompose organic constituents.
Design Basis: Activated sludge biological treatment system with a 4.6-day residence time.
Includes two preaeration tanks in series, a clarifier, and a sludge storage tank.
Reverse Osmosis
Purpose: Wastewater polishing.
Design Basis: Reverse osmosis system including unit with membranes, influent wastewater
storage tanks, and flooded suction tank.
Sludge Dewatering
Purpose: Reduce biological treatment sludge volume by removing water.
Design Basis: Sludge is dewatered in in-line wastewater plate-and-frame filter press described
above.
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Section 9.0 - Development of Control and Treatment Options
In the Agency's survey of the industry, EPA identified only one facility
discharging to a POTW in this subcategory. Therefore, EPA does not propose to establish PSES
limitations for the Barge/Chemical & Petroleum Subcategory. However, EPA is proposing to
establish PSNS limitations.
9.6.4
PSES Options for the Truck/Food, Rail/Food, and Barge/Food
Subcategories
PSES Options for the Truck/Food, Rail/Food, and Barge/Food Subcategories
include the following technology bases in addition to the common technology option elements
discussed in Section 9.1.1.
Option 1: Oil/Water Separation
Option 2: Oil/Water Separation, Equalization, Biological Treatment, and Sludge Dewatering
The purpose and design bases of the components of these technology options are described
below. These technologies are also described in further detail in Section 8.3.
Oil/Water Separation
Purpose: Removal of low to moderate amounts of insoluble oil.
Design Basis: Gravity separator with 6.4-day residence time for wastewater equalization and oil,
water, and solids separation. Includes two separation tanks in series with an oil
removal pump and an oil storage tank.
Equalization
Purpose: Reduce wastewater variability and accumulate wastewater to optimize subsequent
treatment system size and operating costs.
Design Basis: Eight-day residence time. Includes aerators/mixers to homogenize wastewater.
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Section 9.0 - Development of Control and Treatment Options
Biological Treatment
Purpose: Biologically decompose organic constituents.
Design Basis: Activated sludge biological treatment system with a 4.6-day residence time.
Includes two preaeratiori tanks in series and a sludge storage tank.
Sludge Dewatering
Purpose: Reduce biological treatment sludge volume by removing water.
Design Basis: Plate-and-frame filter press for wastewater filtration. Generates dewatered sludge
at 32.0% solids. Includes diatomaceous earth mix tank.
In the Agency's engineering assessment of pretreatment of wastewaters for the
Truck/Food, Rail/Food, and Barge/Food Subcategories, EPA considered the types and
concentrations of pollutants found in raw wastewaters in this subcategory. As expected, food
grade facilities did not discharge significant quantities of toxic pollutants to POTWs. In addition,
conventional pollutants present in the wastewater were found at concentrations that are amenable
to treatment at a POTW. As a result, EPA is proposing not to establish pretreatment standards
for any of the food subcategories.
9.6.5
PSES Options for the Truck/Petroleum and Rail/Petroleum
Subcategories
PSES options for the Truck/Petroleum and Rail/Petroleum Subcategories include
the following technology bases in addition to the common technology option elements discussed
in Section 9.1.1.
Option 1: Equalization, Oil/Water Separation, and Chemical Precipitation
Option 2: Zero Discharge Based on Equalization, Oil/Water Separation, and Activated
Carbon Adsorption Followed by Total Wastewater Recycle/Reuse
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Section 9.0 - Development of Control and Treatment Options
The purpose and design bases of the components of these technology options are described
below. These technologies are also described in further detail in Section 8.3.
Equalization
Purpose:
Reduce wastewater variability and accumulate wastewater to optimize subsequent
treatment system size and operating costs.
Design Basis: Minimum 12-hour residence time. Includes aerators/mixers to homogenize
wastewater.
Oil/Water Separation
Purpose: Removal of entrained oil and grease.
Design Basis: Vertical tube coalescing separator with rotary oil skimmer. Includes demulsifier
chemical additive, oil storage tank, and sludge storage tank.
Chemical Precipitation
Purpose: Removal of dissolved metals and entrained solid or liquid particles.
Design Basis: Batch chemical precipitation unit including chemical feed systems, agitator,
control system, pH adjustment, and sludge storage tank.
Activated Carbon Adsorption
Purpose: Wastewater polishing.
Design Basis: One 200-lb carbon column with nominal carbon change-out frequency of at least
one vessel per 17,000 gallons of treated wastewater. Includes initial carbon
cartridge of 200 Ib/vessel.
EPA estimates that there are 38 facilities in the Truck/Petroleum and
Rail/Petroleum Subcategories. EPA estimates that these facilities discharge a total of 28 pound
equivalents to the nation's waterways, or less than one pound equivalent per facility.
Additionally, EPA estimates that the total cost to the industry to implement PSES would be
greater than $600,000 annually. The estimated costs to control the discharge of these small
amounts of pound equivalents were not considered to be reasonable. Based on this analysis, EPA
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• Section 9.0 - Development of Control and Treatment Options
preliminarily concluded that there is no need to develop nationally applicable regulations for
these subcategories due to the low levels of pollutants discharged by facilities in these
subcategories.
Based on these factors, EPA proposes not to establish pretreatment standards for
the Truck/Petroleum or Rail/Petroleum Subcategories.
9.6.6
PSES Options for the Truck/Hopper, Rail/Hopper, and
Barge/Hopper Subcategories
PSES options for the Truck/Hopper, Rail/Hopper, and Barge/Hopper
Subcategories include the following technology bases in addition to the common technology
option elements discussed in Section 9.1.1.
Option 1: Gravity Separation
The purpose and design bases of the components of this technology option are described below.
This technology is also described in further detail in Section 8.3.
Gravity Separation
Purpose: Removal of suspended solids.
Design Basis: Gravity separator with 4-day residence time for wastewater equalization and
solids separation. Includes two separation tanks in series.
EPA estimates that there are 42 indirect discharging hopper facilities. EPA
estimates that these facilities discharge a total of 3.5 pound equivalents to the nation's
waterways, or less than one pound equivalent per facility. Additionally, EPA estimates that the
total cost to the industry to implement 3?SES would be greater than $350,000 annually. The
estimated costs to control the discharge of these small amounts of pound equivalents were not
considered to be reasonable.
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Section 9.0 - Development of Control and Treatment Options
EPA is not proposing to establish BAT limits for any priority pollutant in the
hopper subcategories. EPA did, however, look at the levels of pollutants in raw wastewaters and
concluded that none were present at levels that are expected to cause inhibition of the receiving
POTW. Based, on these factors, EPA proposes not to establish pretreatment standards for the
Truck/Hopper, Rail/Hopper, or Barge/Hopper Subcategories
9.7
Pretreatment Standards for New Sources (PSNS)
Section 307 of the CWA requires EPA to promulgate both pretreatment standards
for new sources and new source performance standards. New indirect discharging facilities, like
new direct discharging facilities, have the opportunity to incorporate the best available
demonstrated technologies including: process changes, in-facility controls, and end-of-pipe
treatment technologies.
9.7.1
PSNS Options for the Truck/Chemical Subcategory
EPA is proposing to establish pretreatment standards for new sources in the
Truck/Chemical Subcategory equivalent to the PSES standards.. In this subcategory, EPA
identified no technology that can achieve greater removals than PSES. Therefore, EPA is
proposing pretreatment standards for those pollutants which the Agency has determined to pass
through a POTW equivalent to PSES.
9.7.2
PSNS Options for the Rail/Chemical Subcategory
EPA evaluated PSES Options 2 and 3 as more stringent levels of control that may
be appropriate for new indirect sources. The cost implications anticipated for new sources are
not as severe as those projected for existing sources. By utilizing good heel removal and
management practices which prevent pollutants from entering waste streams, and good water
conservation practices in the design of new facilities, treatment unit size can be substantially
reduced and treatment efficiencies improved. As a result, costs of achieving PSES Option 2 and
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Section 9.0 - Development of Control and Treatment Options
3 can be significantly reduced at new facilities. All of the technologies considered have been
demonstrated at an existing zero discharge rail/chemical facility. EPA anticipates no barrier to
entry for new sources employing these technologies at lower cost.
Therefore, EPA is proposing PSNS for those pollutants which the Agency has
determined to pass through a POTW based on PSES Option 3. PSES Option 3 consisted of
oil/water separation, equalization, dissolved air flotation (with flocculation and pH adjustment),
organo-clay/activated carbon adsorption, and sludge dewatering.
9.7.3
PSNS Options for the Barge/Chemical & Petroleum
Subcategory
Although the Agency is not proposing to establish PSES for the Barge/Chemical
& Petroleum Subcategory, EPA did evaluate best available technologies for PSNS. EPA
evaluated the PSES Options for determining levels of control that may be appropriate for new
indirect sources.
EPA is not proposing to establish PSNS based on PSES Option 3 because reverse
osmosis was not considered to be the best demonstrated technology due to the small incremental
removals achieved by this option, the lack of additional water quality benefits potentially
achieved by this option, the potential issue of disposing the liquid concentrate created by
treatment, and the high level of pollutant control achieved by the proposed BAT option.
EPA is proposing to establish PSNS based on PSES Option 2 because of the
removals achieved through this option. The raw wastewater in this Subcategory contains
significant amounts of decomposable organic materials. These materials may not be treated as
efficiently as the proposed technology option in a conventional POTW because a POTW may not
be acclimated to this particular wastewater stream. In this instance, pretreatment based on
biological treatment may be appropriate because the pollutant parameters that pass through, or
which may be present at levels that cause interference, will receive additional treatment not
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Section 9.0 - Development of Control and Treatment Options
achieved by the POTW. Several pollutants were determined to pass through a POTW and are
therefore proposed for PSNS regulation in the Barge/Chemical & Petroleum Subcategory.
9.7.4
PSNS Options for the Truck/Food, Rail/Food, and Barge/Food
Subcategories
Based on the PSES analysis, EPA preliminarily concluded that there is no need to
develop nationally-applicable regulations for these subcategories due to the low levels of toxic
pollutants discharged by facilities in these subcategories.
EPA has not identified any more stringent treatment technology option which it
considered to represent PSNS level of control and is therefore proposing not to establish PSNS
for any of the food subcategories.
9.7.5
PSNS Options for the Truck/Petroleum and Rail/Petroleum
Subcategories
Based on the PSES analysis, EPA preliminarily concluded that there is no need to
develop nationally-applicable regulations for these subcategories due to the low levels of
pollutants discharged by facilities in this subcategory. EPA proposes not to establish PSNS for
the Truck/Petroleum or Rail/Petroleum Subcategories.
9.7.6
PSNS Options for the Truck/Hopper, Rail/Hopper, and
Barge/Hopper Subcategories
Based on the PSES analysis, EPA preliminarily concluded that there is no need to
develop nationally-applicable regulations for these subcategories due to the low levels of
pollutants discharged by facilities in this subcategory. EPA proposes not to establish PSNS for
the Truck/Hopper, Rail/Hopper, and Barge/Hopper Subcategories.
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Section 9.0 - Development of Control and Treatment Options
9.8
References1
1.
U.S. Environmental Protection Agency, Office of Water. Statistical Support
Document of Proposed Effluent Limitations Guidelines and Standards for the
Transportation Equipment Cleaning Category. EPA-821-B-98-014, May 1998.
1 For those references included in the administrative record supporting the proposed TECI rulemaking, the
document control number (DCN) is included in parentheses at the end of the reference.
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Section 9.0 - Development of Control and Treatment Options
Table 9-1
Subcategory-Specific Regulatory Flow
Subcategory
Truck/Chemical
Rail/Chemical
Barge/Chemical & Petroleum
Truck/Food
Rail/Food
Barge/Food
Truck/Petroleum
Rail/Petroleum
Truck/Hopper
Rail/Hopper
Barge/Hopper
Regulatorjrllow s-
' ' {gallons/tank)^
605
2,091
4,857
790
4,500
4,500
193
193
144
267
712
. 9-38
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10.0
Section 10.0 - Costs of Technology Bases for Regulations
COSTS OF TECHNOLOGY BASES FOR REGULATIONS
This section describes the methodology used to estimate the implementation costs
associated with each of the regulatory options under consideration for the Transportation
Equipment Cleaning Industry (TECI). Section 9.0 describes in detail the regulatory options and
the technologies used as the bases for those options. The cost estimates presented in this section,
together with the pollutant reduction estimates described in Section 11.0, provide a basis for
evaluating the regulatory options and determining the economic impact of the proposed
regulation on the TECI. The results of the economic impact assessment for the regulation are
found in the Economic Assessment (EA) for the TECI proposed rulemaking (1).
EPA used the following approach to estimate compliance costs for the TECI:
EPA mailed Detailed Questionnaires to a statistical sample of
transportation equipment cleaning (TEC) facilities (discussed in Section
3.2.3). Information from the 93 facilities that responded to the
questionnaire, discharge TEC wastewater, and are not covered by other
effluent guidelines (see Section 3.2.3.4) was used to characterize industry-
wide TEC operations, operating status, and pollutant control technologies
in place for the baseline year (1994). EPA also used information from
Screener Questionnaire responses (discussed in Section 3.2.2) and other
sources for four direct discharging facilities to characterize the baseline'for
direct dischargers in two industry subcategories (see Section 10.1.2).
EPA collected and analyzed field sampling data to determine the pollutant
concentrations of untreated wastewater in the TECI (discussed in
Section 6.0).
EPA identified candidate pollution prevention and wastewater treatment
technologies and grouped appropriate technologies into regulatory options
(discussed in Section 9.0). The regulatory options serve as the bases of
compliance cost and pollutant loading calculations.
EPA performed sampling episodes at best performing facilities to
determine pollutant removal performance for the identified technologies
(see Section 11.0).
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Section 10.0 - Costs of Technology Bases for Regulations
EPA developed cost equations for capital and operating and maintenance
(O&M) costs for each technology included in the regulatory options
(discussed in Section 10.2.4) based on information gathered from TEC
facilities, wastewater treatment system vendors, and technical literature,
and on engineering judgement.
EPA developed and used a computerized cost model to estimate
compliance costs (discussed in Section 10.3) and pollutant loadings
(discussed in Section 11.0) for each regulatory option.
EPA used output from the cost model to estimate total annualized costs,
cost-effectiveness values, and the economic impact of each regulatory
option on the TECI (presented in the EA).
EPA estimated industry-wide costs for the various subcategories and
technology options by estimating compliance costs at 93 model sites and
then using statistically calculated weighting factors to extrapolate the
results to the estimated 692 TEC facilities that fall within the scope of the
rule.
EPA estimated facility compliance costs for 24 unique technology options.
Table 10-1 lists the number of technology options for which EPA estimated facility compliance
costs.
The following information is discussed in this section:
• Section 10.1: Development of model sites;
• Section 10.2: Methodology used to estimate compliance costs;
« Section 10.3: Design and cost elements for pollutant control
technologies;
• Section 10.4: Summary of estimated compliance costs by regulatory
option; and
• Section 10.5: References.
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Section 10.0 - Costs of Technology Bases for Regulations
10.1
Development of Model Sites
This section describes the development of the key inputs to the TECI cost model:
model sites and pollutant control technologies.
10.1.1
Model Site Development
The Agency used a model site approach to estimate regulatory compliance costs
for the TECI. A model site is an operating TEC facility whose data were used as input to the
TECI cost model. A total of 93 facilities were used as model sites for the cost analysis because
each meets the following criteria:
The facility discharges TEC process wastewater either directly to surface
waters or indirectly to a publicly-owned treatment works (POTW); and
The facility supplied sufficient economic and technical data to estimate
compliance costs and assess the economic impacts of these costs. Such
data include daily flow rate, operating schedules, tank cleaning production
and types of tanks cleaned, existing treatment in place, and economic
status for the base year 1994.
As discussed in Section 3.2.3, EPA mailed Detailed Questionnaires to a statistical
sample of TEC facilities. EPA evaluated each of the 176 respondents to determine whether the
facility would be potentially affected by the regulatory options considered by the Agency and
would therefore incur costs as a result of potential proposed regulations. Eighty-three facilities
would not incur costs because:
The facility is subject to other Clean Water Act final or proposed
categorical standards and thus would not be subject to the limitations and
standards under the proposed approach for this guideline (34 facilities); or
The facility is a zero or alternative discharging facility (i.e., does not
discharge TEC wastewater either directly or indirectly to a surface water)
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Section 10.0 - Costs of Technology Bases for Regulations
and thus would not be subject to the limitations and standards for this
guideline (49 facilities).
Each of the 93 facilities is considered a "model" facility since it represents a larger
number of facilities in the overall industry population as determined by its statistical survey
weight. The Statistical Support Document (2) discusses in detail the development of the survey
weights. These facilities represent an estimated industry population of 692 facilities that
discharge either directly to surface waters or indirectly to a POTW. EPA selected a facility-by-
facility model approach to estimate compliance costs, as opposed to a more general modeling
approach, to better characterize the variability of processes and resultant wastewaters among
TEC facilities.
Although EPA estimated regulatory compliance costs on a facility-by-facility
basis, EPA made certain engineering assumptions based on information from standard
engineering costing publications, equipment vendors, and industry-wide data. Thus, for any
given model facility (or facilities represented by the model facility), the estimated costs may
deviate from those that the facility would actually incur. However, EPA considers the
compliance costs to be accurate when evaluated on an industry-wide, aggregate basis.
10.1.2
Supplemental Model Site Development
EPA reviewed the 93 model facilities and identified direct dischargers in two
subcategories (Barge/Chemical & Petroleum and Barge/Hopper), but none in the remaining
subcategories. To assess the need to develop limitations and standards for direct dischargers for
the remaining subcategories, EPA reviewed the Screener Questionnaire sample population to
identify direct discharging facilities that would be subject to these regulations. This review
identified the following direct dischargers by subcategory:
Truck/Chemical (three facilities in sample population);
Rail/Chemical (one facility in sample population);
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Section 10.0 - Costs of Technology Bases for Regulations
• Truck/Food (two facilities in sample population); and
• Barge/Food (one facility in sample population).
EPA decided to estimate compliance costs for direct dischargers in the
Truck/Chemical and Rail/Chemical Subcategories for the following reasons:
Regulatory options considered for direct and indirect dischargers differ
(i.e., regulatory options for direct dischargers include biological treatment
while those for indirect dischargers do not); and
Dissimilar regulatory options may result in significantly different
estimated compliance costs.
Technical information required to estimate compliance costs for these facilities
was obtained from the Screener Questionnaire responses, telephone conversations with facility
personnel, and facility NPDES permits.
Note that the estimated compliance costs for these direct dischargers are not added
to the costs estimated for the 93 model sites (described in Section 10.1) to obtain industry-wide
cost estimates. Statistically, compliance costs for these direct dischargers are included within the
industry-wide cost estimates based on the 93 model facilities. Therefore, EPA used estimated
compliance costs for these direct dischargers only to characterize this segment of the industry
further and to evaluate whether limitations and standards for these facilities are warranted. .
EPA estimates that the compliance costs for direct dischargers in the food grade
subcategories will be zero or insignificant for the following reasons:
All facilities identified by EPA currently operate biological treatment and
are believed to currently achieve the proposed limitations; and
EPA assumes that current NPDES permits for these facilities require
frequent monitoring for pollutant parameters regulated by this guideline
(i.e., BOD5, TSS, and oil and grease). Therefore, these facilities will not
incur additional monitoring costs as a result of this proposed rulemaking.
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Section 10.0 - Costs of Technology Bases for Regulations
Based on this assessment, EPA believes that developing model sites in the TECI
cost model for direct discharging food grade facilities is not necessary.
10.1.3
Pollutant Control Technology Development
EPA evaluated Screener and Detailed Questionnaire responses to identify
applicable pollution prevention and wastewater treatment technologies for the TECI and to select
facilities for EPA's TECI site visit and sampling program. EPA conducted 39 engineering site
visits at 38 facilities to collect information about TEC processes, water use practices, pollution
prevention practices, wastewater treatment technologies, and waste disposal methods. Based on
the information gathered from these site visits, EPA sampled untreated and/or treated wastewater
streams at 18 facilities. Sections 3.3 and 3.4 discuss in more detail the engineering site visit and
sampling program conducted as part of the TECI rulemaking.
In most cases, the specific pollutant control technologies costed, including
equipment, chemical additives and dosage rates, and other O&M components, are the same as
those operated by the facilities whose sampling data are used to represent the performance
options, with adjustments made to reflect differences in wastewater flow rates or other facility-
specific conditions. For example, BPT options for the Truck/Chemical Subcategory include
oil/water separation and are specifically based on a vertical tube coalescing separator similar to
that characterized during wastewater sampling. Therefore, EPA's estimated compliance costs are
based upon implementation of a vertical tube coalescing separator. EPA chose this approach to
ensure that the technology bases of the regulatory options can achieve the proposed limitations
and standards and that the estimated compliance costs reflect implementation of these technology
bases. EPA believes this approach overestimates the compliance costs because many facilities
can likely achieve the proposed limitations and standards by implementing less expensive
pollution prevention practices, substituting less expensive alternative equipment, or utilizing
equipment in place that EPA did not assess as equivalent to the technology basis (see
Section 10.2.5 for more detail on treatment-in-place credits).
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Section 10.0 - Costs of Technology Bases for Regulations
EPA emphasizes that the proposed regulations do not require that a facility install
or possess these technologies, but only that the facility comply with the appropriate effluent
limitations and standards.
10.1.4
Model Sites with Prodmction in Multiple Subcategories
Some model facilities have production in more than one subcategory. For
example, a facility that cleans both tank trucks and rail tank cars that last transported chemical
cargos has production in both the Truck/Chemical and Rail/Chemical Subcategories. To simplify
compliance costs and pollutant reduction estimates, EPA assigned each multiple-subcategory
facility a primary subcategory. For these facilities, compliance costs and pollutant reduction
estimates for all facility production are assigned to the primary subcategory. This methodology
may bias the subcategory cost and pollutant reduction estimates on a facility-by-facility basis;
however, EPA believes that subcategory costs and pollutant reduction estimates are accurate on
an aggregate basis (i.e., individual facility biases are offset within each subcategory in aggregate).
This simplification is necessary because the technology bases of the regulatory
options differ for each subcategory. EPA considered an alternative approach that included
designing separate treatment systems for subcategory-specific wastewater based on the
subcategory regulatory options. However, to comply with the proposed regulations, a facility can
implement any technology it chooses, provided it achieves the effluent limitations. Installation
of two (or more) separate treatment systems is not a practical or cost-effective solution to comply
with the proposed regulations. Therefore, EPA rejected this alternative approach.
Compliance costs and pollutant reduction estimates for individual facilities that
clean multiple tank types are based on the assumption that facilities will install and operate the
technologies chosen as the technology basis for each facility's primary subcategory. EPA does
not have data available demonstrating that the technologies costed to treat each primary
subcategory will effectively treat wastewaters from all potential secondary Subcategories. For
example, EPA does not have data available on the performance of the Truck/Chemical
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Section 10.0 - Costs of Technology Bases for Regulations
Subcategory, technology basis in treating Rail/Chemical Subcategory wastewater. However, EPA
believes that the costed technology for the Truck/Chemical Subcategory option will control all
pollutants of concern in all TEC wastewaters generated by each facility because the control
technologies included in the different technology bases use similar pollutant removal
mechanisms (e.g., chemical/physical treatment, secondary biological treatment, and advanced
treatment for wastewater polishing).
For these reasons, EPA believes that its costing methodology for multiple-
subcategory facilities is appropriate and adequately represents the compliance costs and pollutant
reductions estimated at these facilities.
10.2
Costing Methodology
To accurately determine the impact of the proposed effluent limitations guidelines
and standards on the TECI, EPA estimated costs associated with regulatory compliance. The
Agency developed a cost model to estimate compliance costs for each of the regulatory options
under BPT, BCT, BAT, PSES, PSNS, and NSPS. EPA used the cost model to estimate costs
associated with implementation of the pollutant control technologies used as the basis for each
option. Again, the proposed regulations do not require that a facility install and possess these
technologies but only that the appropriate facility effluent limitations and standards be achieved.
10,2.1
Wastewater Streams Costed
Based on information provided by the sites in their Detailed Questionnaire (or
Screener Questionnaire in the case of the four direct dischargers without a Detailed
Questionnaire), follow-up letters, and telephone calls, EPA classified each wastewater steam at
each site as TEC interior cleaning wastewater, other TEC commingled wastewater stream, or
non-TEC wastewater. The following additional questionnaire data were used to characterize
wastewater streams:
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Section 10.0 - Costs of Technology Bases for Regulations
• Flow rate;
• Production rate (i.e., types and number of tanks cleaned); and
• Operating schedule.
EPA first reviewed wastewater streams discharged by each facility and classified
these streams as interior cleaning wastewater or other commingled wastewater stream. Facilities
that clean tanks representing multiple modes of transportation (e.g., road, rail, or inland
waterway) or that clean both tanks and closed-top hoppers are considered to have multiple
wastewater streams. However, as discussed in Section 10.1.4, these facilities are assigned a
primary subcategory, and the TECI cost model costs the flow contribution of wastewater from
any secondary subcategory as primary subcategory wastewater.
For costing purposes, TEC wastewater consists of tank interior cleaning
wastewater and other -commingled wastewater streams not easily segregated. Examples of
interior cleaning wastewater are water, condensed steam, prerinse cleaning solutions, chemical
cleaning solutions, and final rinse solutions generated from cleaning tank and container interiors.
Examples of other commingled waste streams not easily segregated are tank or trailer exterior
cleaning wastewater, TEC-contaminated stormwater, boiler blowdown, safety equipment
cleaning wastewater, bilge and ballast waters, and other non-TEC wastewater streams that are
commingled with TEC wastewaters. Incidental and non-TEC wastewater streams are included in
developing the compliance costs because these streams are difficult or costly to segregate and
treat separately from TEC wastewater.
Wastewater streams not considered in developing compliance costs include
sanitary wastewater; tank hydrotesting wastewater; and repair, rebuilding, and maintenance
wastewater. These wastewater streams are not costed for treatment because they fall under the
scope of another rulemaking or they do not fall within the scope of the TECI rulemaking, and
they are generally easily segregated from TEC wastewaters.
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Section 10.0 - Costs of Technology Bases for Regulations
10.2.2
Influent Pollutant Concentrations
The concentration of each pollutant in each model site TEC wastewater stream
was estimated using field sampling pollutant loadings data for wastewater discharged by tank
type. Section 3.4 discusses the field sampling program. These data are used with Detailed or
Screener Questionnaire flow, tank cleaning production, and operating data to calculate the
influent concentrations. Section 11.0 describes these calculations in more detail.
10.2.3
Cost Model Development
EPA developed a computerized design and cost model to estimate compliance
costs and pollutant reductions for the TECI technology options. EPA evaluated the following
existing cost models from other EPA effluent guidelines development efforts to be used as the
basis for the TECI cost model:
Metal Products and Machinery (MP&M) Phase I Industries Design and
Cost Model; and
Pharmaceuticals Industry Cost Model.
EPA incorporated modified parts of both models in the TECI cost model.
The TECI cost model contains technology "modules," or subroutines; each
module calculates direct capital and annual costs for installing and operating a particular
wastewater treatment or pollution reduction technology. In general, each module is exclusive to
one control technology. For each regulatory option, the TECI cost model combines a series of
technology modules. There are also module-specific "drivers" (technology drivers) that operate
in conjunction with the technology modules. These drivers access input data, run the
corresponding modules, and populate output databases. The technology drivers are bound
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Section 10.0 - Costs of Technology Bases for Regulations
together by primary drivers, which run the technology drivers in the appropriate order for each
regulatory option.
EPA adapted the MP&M cost model drivers for the TECI cost model with the
following modifications:
Costs are tracked by subcategory. The MP&M cost model was not
designed to develop separate costs and loads by subcategory.
All data values calculated by the cost model are stored in an output
database file. This allows the cost model user to examine the importance
of each calculated value for each technology module.
The input data to the cost model include production data (i.e., types and number
of tanks cleaned), wastewater flow, existing technology in place, operational hours per day, and
operational days per year. EPA obtained the flow rates, operating schedules, production data, and
existing treatment-in-place data from Detailed Questionnaire responses from each facility (and
other data sources for supplemental facilities, as discussed in Section 10.1.2). These data
comprise the input data for the technology modules. Each module manipulates the input data
(stored in data storage files) to generate output data (stored in different data storage files), which
represent costs incurred by implementing the costed technology. The output data storage files
become the input data storage files for subsequent technology modules, enabling the cost model
to track operating hours per day and da>ys per year, flows, and costs for subsequent modules.
10.2.4
Components of Compliance Costs
EPA used the TECI cost model to calculate capital costs and annual O&M costs
for each technology and to sum the capital and O&M costs for all technologies at each facility.
Capital costs comprise direct and indirect costs associated with the purchase, delivery, and
installation of pollutant control technologies. Annual O&M costs comprise all costs related to
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Section 10.0 - Costs of Technology Bases for Regulations
operating and maintaining the treatment system for a period of one year, including the estimated
costs for compliance monitoring of the effluent. O&M costs typically include the following:
• Operational labor;
• Maintenance and repair labor;
• O&M materials;
• Chemicals, filters, and other items consumed in the routine operations of
the treatment system;
• Utilities such as water usage and electricity required to power the
treatment system;
• Removal, transportation, and disposal of any waste solids, sludges, oils, or
other wastes generated by the treatment system; and
• Analytical monitoring.
10.2.4.1
Capital Costs
The TECI cost model uses the cost equations listed in Table 10-2 to estimate the
direct capital costs for purchasing, delivering, and installing equipment included in the
technology bases for each regulatory option. Where possible, cost sources (i.e., vendors) provide
all three cost components for varying sized equipment. Where a vendor quote is not available,
literary references or estimates based on engineering judgement are used to estimate direct capital
cost. Direct capital costs consist of the following:
• Purchase of treatment equipment and any accessories;
• Purchase of treatment equipment instrumentation (e.g., pH probes, control
systems);
• Installation costs (e.g., labor and rental fees for equipment such as cranes);
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Section 10.0 - Costs of Technology Bases for Regulations
Delivery cost based on transporting the treatment system an average of 500
miles;
Construction of buildings or other structures to house major treatment
units (e.g., foundation slab, enclosure, containment, lighting and electricity
hook-ups); and
Purchase of necessary pumps (e.g., for wastewater transfer, chemical
addition, sludge handling).
Direct capital costs consist of technology-specific equipment capital costs that are
estimated by the TECI cost model. Indirect capital costs are not technology-specific and are
instead represented as a multiplication factor that is applied to the direct capital costs in the post-
processing portions of the TECI cost model. Indirect capital costs typically include the
following:
Purchase and installation of necessary piping to interconnect treatment
system units (e.g., pipe, pipe hangers, fittings, valves, insulation, similar
equipment);
Engineering costs (e.g., administrative, process design and general
engineering, communications, consultant fees, legal fees, travel,
supervision, and inspection of installed equipment);
Secondary containment and land costs;
Excavation and site work (e.g., site clearing, landscaping, fences,
walkways, roads, parking areas);
Construction expenses (e.g., construction tools and equipment,
construction supervision, permits, taxes, insurance, interest);
Contingency (e.g., allocation for unpredictable events such as foul
weather, price changes, small design changes, and errors in estimates); and
Contractors' fees.
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Section 10.0 - Costs of Technology Bases for Regulations
For each technology, EPA accounted for indirect capital costs by applying a cost
factor related to the purchased, shipped, and installed capital cost. The total capital investment
(direct and indirect capital cost) is obtained by multiplying the direct capital cost by the indirect
capital cost factor. Table 10-3 (at the end of this section) presents the components of the total
capital investment, including the indirect capital cost factor used by the cost model.
Capital cost equations relate direct capital cost to equipment design parameters,
such as wastewater flow. Equipment component designs are generally based upon the equipment
operated by the facilities whose sampling data are used as the basis for the technology options.
To relate the design of the equipment operated by the sampled facility to that required by the
costed facilities, the TECI cost model typically uses a "design equation." For example, a
sampled facility with a nominal wastewater flow rate of 50 gpm operates a 65-gpm dissolved air
flotation (DAF) unit. The design equation developed for the DAF unit is:
DAFGPM = INFGPM x f — 1 = INFGPM x 1.3
I 50]
(1)
where:
DAFGPM
INFGPM
DAF unit nominal capacity (gpm)
Influent flow rate (gpm)
In this example, the equipment design parameter for the DAF unit is the facility's wastewater
flow rate, and the equipment costing parameter is the DAF unit's nominal capacity.
Cost equations are used throughout the TECI cost model to determine direct
capital costs. For a given equipment component, a cost curve is developed by plotting different
equipment sizes versus direct capital costs. Equipment sizes used to develop the cost equations
correspond to the range of sizes required by the costed facilities based on an influent flow rate or
volume requirement. The cost/size data point pairs are plotted and an equation for the curve that
provides the best curve fit for the plotted points with the least standard error is calculated. The
equations calculated to fit the cost curves are most commonly polynomial, but may be linear,
exponential, or logarithmic.
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Section 10.0 - Costs of Technology Bases for Regulations
Because of the variability in wastewater flow rates at TEC facilities, equipment
design equations estimate that some facilities would require very small pieces of equipment. In
some instances, EPA determined that very small equipment is either not commercially available
or not technically feasible. In these cases, the facility is costed for the smallest equipment size
that is both commercially available and technically feasible. For wastewater streams requiring
equipment with a capacity above the maximum-sized unit commercially available and technically
feasible, multiple units of equal capacity are designed to operate in parallel.
10.2.4.2
Annual Costs
Annual cost components include costs for operational labor, maintenance and
repair labor, operating and maintenance materials, electricity, treatment chemicals, filter
replacements, disposal of treatment system residuals, and monitoring.
Annual costs typically are not estimated using cost curves. Operational,
maintenance, and repair labor are estimated as a labor time requirement per equipment
component or a fraction of the total operational hours per day and operational days per year for
the costed facility. Labor time is converted to a constant labor cost used throughout the TECI
cost model. The TECI cost model uses the wage rate specified in The Richardson Rapid System
Process Plant Construction Estimating Standards (3) for installation workers in 1994 ($25.90 per
hour) for all required labor to install, operate, and maintain the systems associated with the
technology bases. Electricity costs are based on operating time and required horsepower, which
are converted to electricity costs using a standard rate used throughout the TECI cost model. The
TECI cost model uses the average cost for electricity of $0.047 per KW-hr from the MP&M cost
model (4). Chemical addition feed rates, filter replacements, and wastewater treatment residual
generation rates are generally based on wastewater flow rate. These rates are converted to costs
using unit cost data (e.g., $/weight) provided by chemical vendors and waste disposal facilities.
The TECI cost model uses water rates from the 1992 Rate Survey of Water and Wastewater
conducted by Ernst and Young (5). The water rate is adjusted from the 1992 rate of $2.90 per
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Section 10.0 - Costs of Technology Bases for Regulations
1,000 gallons to the 1994 rate of $2.98 per 1,000 gallons using the capital investment index
discussed later in this section.
Table 10-4 presents the O&M unit costs used by the cost model and includes
references for the origin of each cost.
EPA adjusted water fees and monitoring costs calculated by the cost model to
1994 dollars because all facility-specific information in the questionnaire database is from 1994.
This adjustment allows direct comparison between financial data reported in the Detailed
Questionnaire and calculated compliance costs for each facility. Costs are adjusted based on the
Chemical Engineering (CE) Plant Cost 1994 annual index and the index value for the year in
which costs were originally reported using the following formula (6):
where:
AC = OC
368.1^
OClJ
(2)
AC =
OC =
OCI =
Adjusted cost, 1994 dollars
Original cost, dollars
Original cost year index
10.2.5
Treatment-in-Place Credit
EPA evaluated facility responses to the Detailed Questionnaire to determine
whether pollutant control technologies are currently in place. These facilities are given credit for
having "treatment in place" to ensure that EPA accurately assesses the baseline (1994) costs and
pollutant loadings. Where appropriate, these treatment credits are used to develop cost estimates
for system upgrades instead of costing for new systems. No costs beyond necessary additional
compliance monitoring are estimated for facilities currently using pollutant control technologies
with sufficient capacity equivalent to a regulatory option.
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Section 10.0 - Costs of Technology Bases for Regulations
EPA reviewed questionnaire data for each model facility to assess the types of
end-of-pipe technologies in place at each site (e.g., oil/water separation, biological oxidation).
EPA identified end-of-pipe technologies on site that, based on technical consideration, are
considered equivalent to technologies included in the TECI technology options. For example,
belt filter presses are considered equivalent to plate-and-frame filter presses for sludge
dewatering. EPA also identified technologies that are not considered equivalent, and for which
no credit for treatment in place is given. For example, oil/water separator skimmers are not
considered equivalent to vertical tube oil/water coalescers. Site-specific assumptions regarding
treatment in place at model sites are included in the administrative record for this rulemaking.
EPA used operating schedule data and site-specific technology specifications from
the Detailed Questionnaire responses to assess the capacity of the end-of-pipe technologies in
place at the model sites. EPA assumed that each model site operates the technologies in place at
full capacity at baseline (i.e., currently). Therefore, EPA used the operating schedule and
capacity of each technology as reported in the questionnaire to define its maximum operating
capacity. EPA uses the maximum operating capacity to assign facilities full or partial treatment-
in-place credit. Partial treatment-in-place credit is assigned to facilities judged to not have
enough treatment capacity in place.
Facilities receiving full treatment-in-place credit for a given technology are not
expected to incur additional capital or O&M costs. However, the facility may incur additional
costs for items not directly associated with the unit, such as monitoring costs. Facilities receiving
partial treatment-in-place credit incur additional capital and O&M costs under the proposed
regulatory options for an additional unit to treat the wastewater flow that is above the existing
unit's capacity.
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Section 10.0 - Costs of Technology Bases for Regulations
10.2.6
Calculation of Baseline Parameters
As discussed in the previous section, EPA determined the treatment in place for
the costed facilities. Before running the cost model for any of the technology options, a baseline
run of the model is performed to determine the following:
• Baseline (1994) annual costs incurred by each model site;
• Baseline non-water quality impacts, such as electricity usage, sludge and
solid waste generation, and waste oil generation; and
• Baseline pollutant loadings.
The baseline values for annual costs, non-water quality impacts, and pollutant loadings are
subtracted from the costs calculated for each technology option to estimate the incremental costs
of compliance with each regulatory option. EPA uses the incremental costs, non-water quality
impacts, and pollutant loadings to represent economic and environmental impacts of the
rulemaking.
10.2.7
Contract Haul in Lieu of Treatment
For some facilities and regulatory options, particularly those with low flow rates,
contract hauling is less expensive than performing on-site treatment. For those facilities, EPA
estimates compliance costs based on contract hauling wastewater for off-site treatment instead of
the technology bases for the particular regulatory option.
To assess contract hauling in lieu of treatment, EPA compares the net present cost
of contract hauling the wastewater to be treated to the net present cost of treating that wastewater
on site for each regulatory option (assuming 7% interest and a 15-year equipment life span for all
capital equipment). Capital and annual costs estimated for contract hauling wastewater include a
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Section 10.0 - Costs of Technology Bases for Regulations
wastewater storage tank, repair labor, O&M materials, and transport and off-site disposal of the
wastewater.
10.3
Design and Cost Elements for Pollutant Control Technologies
10.3.1
Cost Model Components
The TECI cost model consists of several programming components, which can be
grouped into four major categories:
• Model shell programs;
• Primary model drivers;
• Data storage files; and
• Technology drivers and modules.
The model shell includes programs that create the various menus and user interfaces that accept
user inputs and pass them to the appropriate memory storage areas. The primary model drivers
are programs that access technology drivers in the appropriate order for each option and process
the model-generated data. Data storage files are databases that contain cost model input and
output data. Information typically stored in data storage files includes:
How, production, and operating data associated with each wastewater
stream;
Pollutant concentrations associated with each wastewater stream; and
Facility-specific data regarding existing technologies in place (discussed in
Section 10.2.5).
Technology drivers and modules are programs that calculate costs and pollutant
loadings for a particular pollutant control technology. EPA developed cost modules for the water
conservation practices and wastewater treatment technologies included in the regulatory options
for the TECI.
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Section 10.0 - Costs of Technology Bases for Regulations
The technology drivers perform the following functions, as applicable, for each
technology costed for a facility:
• Locate and open all necessary input data files;
• Store input data entered by the user of the model;
• Open and run the appropriate technology modules; and
• Calculate and track the following types of information generated by each
technology module:
— Total direct capital costs,
— Total direct annual costs,
— Electricity use and associated cost,
Water use and associated cost,
— . Sludge generation and associated disposal costs,
— Solid waste generation and associated disposal costs,
— Waste oil' generation and associated disposal costs,
— Effluent flow rate, and
— Effluent pollutant concentrations.
The following table lists the treatment technologies that are modeled in the cost
model. Sections 10.3.2 through 10.3.21 discuss the technology modules.
CostMedole J
t^S S *s « > V-
Flow Reduction
Equalization
Oil/Water Separation (Vertical Tube Coalescing)
Oil/Water Separation (API)
Oil/Water Separation (Gravity)
Gravity Separation
Chemical Oxidation, Neutralization, Coagulation, Clarification
Dissolved Air Flotation (DAF) (with pH Adjustment and Chemical Addition)
DAF (No Chemical Addition)
Chemical Precipitation
- Section jfaaajlbee - ^
10.3.2
10.3.3
10.3.4
10.3.5
10.3.6
10.3.7
10.3.8
10.3.9
10.3.10
10.3.11
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Section 10.0 - Costs of Technology Bases for Regulations
Cost Modiile
Filter Press (For Wastewater Clarification and Sludge Dewatering)
Biological Treatment
Activated Carbon Adsorption (Vessels)
Activated Carbon Adsorption (Canisters)
Organo-Clay/Activated Carbon Adsorption
Reverse Osmosis
Sludge Dewatering
Contract Haul of Wastewater in Lieu of Treatment
Compliance Monitoring
Waste Hauling
Section Number *
10.3.12
10.3.13
10.3.14
10.3.15
10.3.16
10.3.17
10.3.18
10.3.19
10.3.20
10.3.21
10.3.2
Flow Reduction
In this module, EPA estimates costs for a facility to install wastewater reduction
technologies in order to reduce the volume of wastewater generated per tank cleaned. The flow
reduction module design is based on the ratio of the current volume of wastewater generated per
tank cleaned to the target volume of wastewater generated per tank cleaned. The target volume of
wastewater generated per tank cleaned is the "regulatory flow" as discussed in Section 9.1. The
module compares the regulatory flow to the current flow and costs facilities for different flow
reduction technologies based on their subcategory and/or the magnitude of their ratio of
regulatory flow to current flow (the "flow ratio"). Facilities with a flow ratio less than or equal
to 1 (i.e., facilities generating less than the regulatory flow of wastewater per tank cleaned) are
not costed in the flow reduction module.
Where the TECI cost model reduces facility wastewater flow rates through
volume reduction, specific capital and O&M costs are estimated to account for the costs those
facilities would incur to implement flow reduction technologies and practices. Because of the
variation in tank types and cleaning practices between subcategories, the costs for implementing
flow reduction technologies are different for each subcategory.
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Section 10.0 - Costs of Technology Bases for Regulations
EPA bases the implementation costs for flow reduction on data received in
response to the TECI Detailed Questionnaire, technologies and practices observed during site
visits and sampling episodes at TEC facilities, information received from vendors on the flow
reduction technologies, and technical literature. However, EPA does not have information
available for every costed facility to determine the extent to which flow reduction is achievable
and the exact equipment components and changes in standard operating procedures necessary to
achieve the flow reductions estimated by the cost model. Although the cost model estimates
costs incurred and wastewater volume reduction achieved by flow reduction, the costs and flow
reductions may not be completely accurate for every costed facility due to limitations in the
available data. However, EPA believes that the cost model accurately estimates the flow
reduction and associated costs for the industry as a whole.
Capital and annual costs for the following equipment and practices listed below
are included in the flow reduction module:
Replacement tank cleaning system (Truck/Chemical, Rail/Chemical,
Truck/Food, Rail/Food, Truck/Petroleum, and Rail/Petroleum
Subcategories);
Two spinners - one high flow for cleaning solution and one low flow for
rinse (Truck/Chemical, Rail/Chemical, Truck/Food, Rail/Food,
Truck/Petroleum, and Rail/Petroleum Subcategories);
Excess heel disposal (Barge/Chemical & Petroleum, Barge/Food, and
Barge/Hopper Subcategories); and
Cleaning crew training and wastewater flow rate monitoring for all
Subcategories.
Annual costs include tank cleaning crew training, wastewater flow rate monitoring, and off-site
excess heel disposal for the Barge/Chemical & Petroleum, Barge/Food, and Barge/Hopper
Subcategories. Annual costs for operating a replacement tank cleaning system and spinners are
assumed to equal baseline costs for operating existing tank cleaning systems; therefore, no
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Section 10.0 - Costs of Technology Bases for Regulations
additional annual costs are calculated in the cost module for implementing these technologies.
The flow reduction module does estimate additional capital costs for the Barge/Chemical &
Petroleum and Barge/Food Subcategories because EPA determined that additional capital
equipment is not necessary at these facilities to dispose of excess heel. However, the flow
reduction module includes costs for the annual labor crew training and wastewater flow rate
monitoring associated with disposal of excess heel.
The flow reduction module uses information from responses to the Detailed
Questionnaire on current wastewater generation per tank and the number of tanks cleaned along
with the regulatory flow (described in Section 9.0) to estimate the annual cost credits (i.e.,
negative annual costs) for savings from reduced water usage. The total volume of water saved is
shown by the following equation:
WS = (CWG x NT) - (RFWG x NT) (3)
where:
WS
CWG
NT
RFWG
Water savings (gallons/year)
Current wastewater generated per tank cleaned (gallons)
Number of tanks cleaned per year
Regulatory flow wastewater generated per tank cleaned
(gallons) (see Table 9-1 for specific regulatory flows)
The volume of water saved is then multiplied by the cost of fresh water (as described in Section
10.2.4.2) to estimate monetary savings from reductions in wastewater use.
10.3.3
Equalization
In this module, EPA estimates costs for a facility to install and operate an
equalization tank(s) to accumulate wastewater in order to reduce wastewater variability and to
optimize the size, effectiveness, and operating costs for the subsequent treatment units. The
required equalization tank size depends on a minimum wastewater residence time. Minimum
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Section 10.0 - Costs of Technology Bases for Regulations
residence times vary by subcategpry (details provided in Section 9.0) based on the ratio of
equalization tank size to total wastewater flow rate as observed during EPA sampling episodes
and site visits. The equalization module calculates the costs necessary to operate an equalization
unit as well as to adequately mix wastewater.
Capital and annual costs for the following equipment are included in the
equalization module:
• Equalization tank(s); and
• Aerators/mixer(s).
Annual costs include operational labor, maintenance and repair labor, O&M materials, and
electricity. The costs associated with the equalization tank(s) are based on tank volume
necessary to perform adequate equalization of TEC wastewater, as observed during EPA site
visits and sampling episodes. The costs associated with the aerator/mixer(s) are based on the
motor horsepower required to adequately mix the wastewater in the equalization tank, as
observed during EPA site visits and sampling episodes.
10.3.4
Oil/Water Separation (Vertical Tube Coalescing)
In this module, EPA estimates costs for a facility to install and operate a vertical
tube coalescing oil/water separator to remove entrained oil and grease. The oil/water separation
module calculates the costs necessary to treat wastewater using a vertical tube coalescing
separator and a demulsifier that is added to the wastewater to aid in oil separation. The module
also calculates the costs for removing, storing, and disposing of floating oil and settled solids.
Capital and annual costs for the following equipment are included in the vertical
tube coalescing oil/water separator module:
A demulsifier feed system (including a metered-flow pump and
demulsifier);
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Section 10.0 - Costs of Technology Bases for Regulations
• An influent wastewater transfer pump;
• An oil/water separator unit (including a water level probe and control
system);
• An oil storage tank;
• A sludge transfer pump; and
• A sludge storage tank.
Annual costs include operational labor, maintenance and repair labor, O&M materials,
electricity, raw materials (i.e., demulsifier), and oil and settled solids disposal. The oil/water
separator observed during EPA site visits and sampling episodes at TEC facilities is sized with
25% excess capacity due to fluctuations in daily wastewater flows. EPA likewise estimates
vertical tube coalescing oil/water separator costs based on a unit with a capacity that exceeds
daily wastewater flow rates by 25%.
The demulsifier feed system costs are based on the feed rate of demulsifier
observed during EPA site visits and sampling episodes. The costs associated with the
wastewater transfer and sludge transfer pumps are based on the horsepower necessary to pump
wastewater and sludge at the flow rates estimated by the oil/water separator module.
The waste oil storage tank and sludge storage tank costs are based on tank
volume. The oil storage tank is sized to hold the volume of oil collected over 10 operating days,
and the sludge storage tank is sized to hold the volume of sludge collected over a period of one
month.
EPA assumes that floating oils will be disposed off site once every 10 facility
operating days and settled solids will be disposed off site once per month, based on observations
made during site visits and sampling episodes. Waste disposal costs are calculated separately in
the waste haul module (see Section 10.3.21). The oil/water separator module calculates the
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Section 10.0 - Costs of Technology Bases for Regulations
amount of oil to be disposed using the difference between the influent and effluent average total
oil and grease concentrations per day. The oil/water separator module calculates the amount of
sludge to be disposed using the difference between the influent and effluent average total
suspended solids concentrations per day. EPA assumes that the waste oil stream comprises 95%
oil and the settled solids stream comprises 4% solids, based on assumptions used in the MP&M
cost model.
10.3.5 Oil/Water Separation (American Petroleum Institute [API]
Separator)
In this module, EPA estimates costs for a facility to install and operate an API
oil/water separator to remove entrained oil and grease. The module calculates costs necessary to
operate an API separator with a slotted pipe surface oil skimmer, a fabric belt skimmer for
entrained thin oils, and a bottom sludge rake. The module also calculates the costs to remove,
store, and dispose of skimmed oils and settled solids.
Capital and annual costs for the following equipment are included in the API
oil/water separator module:
• An API oil/water separator;
• A wastewater transfer pump;
• An oil storage tank; and
• A sludge storage tank.
Annual costs include operational labor, maintenance and repair labor, O&M materials,
electricity, and disposal of residual oil and settled solids. The API oil/water separator costs are
based on the ratio of API oil/water separator nominal capacity to wastewater flow rate observed
during EPA site visits and sampling episodes at TEC facilities. The unit nominal capacity is four
times that needed to accommodate facility average daily wastewater flow rates to account for
fluctuations in daily wastewater flow and to allow for ample wastewater residence. The unit uses
two motors, a scraper/skimmer motor, and an oil collection belt skimmer motor. Electricity costs
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Section 10.0 - Costs of Technology Bases for Regulations
are based on motor horsepower necessary to operate the scraper/skimmer and oil collection belt
skimmer.
The wastewater transfer pump costs are based on the influent wastewater flow rate
for each facility. The pump is designed to operate at a flow rate of one-half the stated maximum
capacity of the pump. Electricity costs are based on motor horsepower necessary to transfer
wastewater at the flow rates estimated by the oil/water separator module.
The waste oil storage tank and sludge storage tank costs are based on tank
volume. The oil storage tank and the sludge storage tank are sized to hold the volume of oil and
the volume of sludge, respectively, collected over a period of one month.
EPA assumes that floating oils and settled solids will be disposed off site once per
month (provided sludge dewatering is riot costed as part of the regulatory option) based on
observations made during site visits and sampling episodes. Waste disposal costs are calculated
separately in the waste haul module (see Section 10.3.21). The API oil/water separator module
calculates the amounts of oil and sludge to be disposed based on the ratios of the oil and sludge
generation rates to the facility wastewater flow rates observed during EPA site visits and
sampling episodes at TEC facilities. If sludge dewatering is costed, the sludge is costed to be
pumped from the sludge storage tank to the filter press (the costs for the sludge pump are
included in the sludge dewatering module). EPA assumes that the waste oil stream comprises
95% oil and the settled solids stream comprises 4% solids, based on assumptions used in the
MP&M cost model.
10.3.6
Oil/Water Separation (Gravity)
In this module, EPA estimates costs for a facility to install and operate a gravity
oil/water separator to remove floating oils from raw wastewater. The module also calculates the
costs necessary to remove, store, and dispose of floating oils. For the food subcategories, no oil
disposal costs are incurred because EPA assumes oil will be recycled to animal feed and/or soap
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Section 10.0 - Costs of Technology Bases for Regulations
product manufacturing based on practices observed during EPA site visits and sampling episodes
at TEC facilities. The module calculates the costs for removing, storing, and disposing of settled
solids for the food subcategories but not for the Barge/Chemical & Petroleum Subcategory,
because EPA assumes gravity oil/water separators at Barge/Chemical & Petroleum facilities will
generate a negligible amount of settled solids based on observations made during EPA site visits
and sampling episodes.
*»
Capital and annual costs for the following equipment are included in the gravity
oil/water separation module:
• A gravity oil/water separator;
• Two wastewater transfer pumps (only one for Barge/Chemical &
Petroleum);
• An oil transfer pump;
• An oil storage tank (Barge/Chemical & Petroleum only);
• A sludge transfer pump (food subcategories only); and
• An oil/water separator effluent pump (Barge/Chemical & Petroleum only).
Annual costs include operational labor, maintenance and repair labor, O&M materials,
electricity, and residual disposal costs. The gravity oil/water separator costs are based on tank
volume designed to provide a wastewater residence time of 6.4 days, as observed during EPA
site visits and sampling episodes at TEC facilities.
The wastewater transfer pumps and oil transfer pump costs are based on the
respective wastewater and oil flow rates estimated by the oil/water separator module. The pumps
are designed to operate at an average flow rate of one-half the stated maximum flow-rate capacity
of the pump. Electricity costs are based on the pump motor horsepower necessary to transfer
wastewater and oil at the flow rates estimated by the oil/water separator module. The sludge
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Section 10.0 - Costs of Technology Bases for Regulations
transfer pump costs are based on the horsepower necessary to pump sludge at the flow rates
estimated by the oil/water separator module. The effluent wastewater pump costs are based on
effluent wastewater flow rate. Electricity costs are based on the motor horsepower necessary to
pump wastewater to the subsequent treatment unit.
Oil and sludge management practices are based on practices observed during EPA
site visits and sampling episodes at TEC facilities. For the Barge/Chemical & Petroleum
Subcategory, oil is collected in a tank and assumed to be hauled off site every 5 days. Oil storage
tank costs are based on the tank volume necessary to hold the oil generated over a 5-day period.
For the Truck/Food, Rail/Food and Barge/Food Subcategories, oil is pumped directly from the
gravity oil/water separator tank for off-site disposal twice per year. Sludge is collected either
directly from the gravity oil/water separator tank and hauled off site for disposal once per month
or pumped to a sludge storage tank (included in the biological treatment module) for subsequent
on-site sludge dewatering. Waste disposal costs are calculated separately in the waste haul
module (see Section 10.3.21). The oil and sludge volumes generated (where applicable) are
calculated based on the ratios of the oil and sludge generation rates to the facility wastewater
flow rates observed during EPA site visits and sampling episodes at TEC facilities. EPA
assumes that the waste oil stream comprises 95% oil and the settled solids stream comprises 4%
solids, based on assumptions used in the MP&M cost model.
10.3.7
Gravity Separation
In this module, EPA estimates costs for a facility to install and operate a gravity
separator to remove suspended solids from raw wastewater. The gravity separator module
calculates the costs necessary to treat wastewater using a gravity separator that allows solids to
settle to the bottom of the unit. The module also calculates the costs for removing, storing, and
disposing of settled solids.
Capital and annual costs for the following equipment are included in the gravity
separation module:
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Section 10.0 - Costs of Technology Bases for Regulations
• A gravity separator tank;
• Two wastewater transfer pumps; and
• A sludge transfer pump (if sludge generation is less than 1,265 gallons per
month).
Annual costs include operational labor, maintenance and repair labor, O&M materials,
electricity, and residual disposal costs. The gravity separator tank costs are based on a tank
volume designed to provide a wastewater residence time of 4 days, as observed during EPA site
visits and sampling episodes at TEC facilities.
The wastewater transfer pump costs are based on influent wastewater flow rate.
The pumps are designed to operate at a flow rate of one-half the stated maximum flow rate
capacity of the pumps. Electricity costs are based on motor horsepower necessary to transfer
wastewater at the flow rates estimated by the gravity separator module. The sludge transfer
pump costs are based on motor horsepower necessary to transfer sludge at the flow rates
estimated by the gravity separator module.
EPA assumes that settled solids will be disposed off site once per month based on
observations made during site visits and sampling episodes at TEC facilities. Waste disposal
costs are calculated separately in the waste haul module (see Section 10.3.21). The sludge
volume generated by the gravity separator is calculated based on the ratios of the sludge
generation rates to the facility wastewater flow rates observed during EPA site visits and
sampling episodes at TEC facilities. Sludge is assumed to accumulate in the bottom of the
gravity separator tank. If the monthly sludge generation is less than 1,265 gallons, it is more
economical for a facility to pump the sludge into drums for disposal. Otherwise, a vacuum truck
(provided by the sludge disposal company) would be used to remove the sludge. EPA assumes
the settled solids stream comprises 4% solids, based on engineering literature.
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10.3.8
Section 10.0 - Costs of Technology Bases for Regulations
Chemical Oxidation, Neutralization, Coagulation, and
Clarification
In this module, EPA estimates costs for a facility to install and operate a turn-key
treatment system consisting of four reaction tanks in series and a clearwell. Treatment steps
include: chemical oxidation to oxidize organic pollutants using hydrogen peroxide; neutralization
to adjust wastewater pH; coagulation to destabilize suspended matter using polyalum chloride
(an electrolyte); and clarification to settle and remove agglomerated solids using a polymer
flocculant. The module calculates costs necessary for the turn-key treatment system, including
the reaction tanks, clearwell, chemical feed systems, mixers, control system, and two sludge
storage tanks. The module also calculates the costs to collect solids from the bottom of the
clarifier and pump the sludge into a sludge storage tank in preparation for dewatering.
Capital and annual costs for the following equipment are included in the chemical
oxidation, neutralization, coagulation, and clarification module:
• Four reaction tanks;
• Two sludge storage tanks;
• A clearwell;
• Five chemical feed systems;
• Two mixers;
• An influent wastewater pump;
• A sludge pump (sized at 20 gpm); and
• A control system.
Annual costs include operational labor, maintenance and repair labor, O&M materials, and
electricity. The turn-key package system costs are based on the nominal wastewater flow rate
capacity of the unit. The turn-key package system observed during EPA sites visits and sampling
episodes at TEC facilities is sized with 25% excess capacity due to fluctuations in daily
wastewater flows. EPA likewise estimates turn-key package system costs based on a unit with a
capacity that exceeds daily wastewater flow rates by 25%. Electricity costs for the mixers,
chemical feed systems, and sludge pump are based on motor horsepower necessary to operate the
turn-key unit.
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10.3.9
Section 10.0 - Costs of Technology Bases for Regulations
DAF (with pH Adjustment and Chemical Addition)
In this module, EPA estimates costs for a facility to install and operate a DAF unit
designed to remove entrained solid or liquid particles. The module calculates the costs necessary
to operate a DAF unit with a recycle pressurization system, chemical addition systems for
polymers (coagulants and flocculant) and pH adjustment, and a sludge collection tank. The
module also calculates costs for a pre-engineered building to enclose the treatment unit.
module:
Capital and annual costs for the following equipment are included in the DAF
A wastewater transfer pump;
A chemical treatment tank system;
A polymer mixing tank system;
A polymer dilution tank system;
A DAF unit;
An air compressor;
A sludge storage tank; and
A pre-engineered building.
Annual costs include operational labor, maintenance and repair labor, O&M materials,
electricity, and chemical costs. The DAF unit observed during EPA site visits and sampling
episodes at TEC facilities is sized with 30% excess capacity due to fluctuations in daily
wastewater flows. EPA likewise estimates DAF unit costs based on a unit with a capacity that
exceeds daily wastewater flow rates by 30%. The unit uses two motors: a surface skimmer motor
and a pressurization motor pump. Electricity costs are based on motor horsepower necessary to
operate the surface skimmer and pressurization pump.
The wastewater transfer pump costs are based on influent wastewater flow rate.
Pumps are designed to operate at a flow rate of one-half the stated maximum capacity of the
pump. Electricity costs are based on motor horsepower necessary to transfer wastewater at the
influent wastewater flow rates.
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Section 10.0 - Costs of Technology Bases for Regulations
The chemical treatment tank system consists of a treatment tank, mixer, pH probe,
acid metering pump, and caustic metering pump. The treatment tank costs are based on the ratio
of tank volume to wastewater flow rate observed during EPA site visits and sampling episodes at
TEC facilities. The mixer costs are based on tank volume and motor horsepower necessary to
operate the mixer. The pH probe and acid metering pump costs are the same for every facility.
The caustic metering pump costs are based on tank volume. Sulfuric acid (93%) and sodium
hydroxide (50%) are added to the wastewater. The volume of chemicals added is based on the
ratio of chemical addition to wastewater flow rate observed during EPA site visits and sampling
episodes at TEC facilities.
The polymer mixing tank system consists of a mixing tank, a mixer, and two
metering pumps. The tank costs are based on the ratio of mixing tank volume to wastewater flow
rate observed during EPA site visits and sampling episodes at TEC facilities. The mixer costs
are based on tank volume and motor horsepower necessary to operate the mixer. The metering
pump cost is the same for every facility. The polymer dilution tank system consists of the same
components as the polymer mixing tank system except it includes only one metering pump.
Polymer addition rates are based on the ratio of polymer addition to wastewater flow rate
observed during EPA site visits and sampling episodes at TEC facilities.
The sludge storage tank costs are based on the ratio of sludge storage tank volume
to wastewater flow rate observed during EPA site visits and sampling episodes at TEC facilities.
Sludge is collected in the storage tank before being dewatered. Costs for sludge dewatering are
estimated in the sludge dewatering module (see Section 10.3.18). The DAP unit sludge
generation rates are based on information gathered during EPA site visits and sampling episodes
at TEC facilities with DAF units.
The pH adjustment and DAF units are housed in the pre-engineered building to
provide protection from poor weather conditions. The pre-engineered building costs are based
on the square footage of building space needed to house the DAF unit and associated equipment.
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Section 10.0 - Costs of Technology Bases for Regulations
Since differences in the sizes of equipment housed in the pre-engineered building are minor,
costs for all facilities are estimated for the same building size.
10.3.10
DAF (without Chemical Addition)
In this module, EPA estimates costs for a facility to install and operate a DAF unit
designed to remove entrained solid or liquid particles. The module calculates the 'costs necessary
to operate a DAF unit and collect solids for disposal off site (for facilities with treatment in place
but no sludge dewatering on site) or for on-site sludge dewatering.
Capital and annual costs for the following equipment are included in this DAF
module:
• A DAF unit; and
• A sludge storage tank.
Annual costs include operational labor, maintenance and repair labor, O&M materials,
electricity, and residual disposal (if sludge dewatering costs are not included). The DAF unit
costs are based on the ratio of DAF unit capacity to wastewater flow rate observed during EPA
site visits and sampling episodes at TEC facilities. Electricity costs are based on the motor
horsepower necessary to operate the DAF unit.
A sludge storage tank is only included in baseline options where a facility does
not operate sludge dewatering on site. A sludge storage tank is sized to hold the volume of
sludge collected over a period of one month. Waste disposal costs are calculated separately in
the waste haul module (see Section 10.3.21). The sludge storage tank costs are based on volume.
The DAF module calculates the amount of sludge to be disposed based on the ratio of DAF
sludge generation rate to wastewater flow rate observed during EPA site visits and sampling
episodes at TEC facilities. EPA assumes that the DAF sludge comprises 4% solids, based on
assumptions used in the MP&M cost model.
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Section 10.0 - Costs of Technology Bases for Regulations
10.3.11
Chemical Precipitation
EPA conducted an abbreviated cost review to determine the feasibility of
installing and operating chemical precipitation treatment at facilities in the Truck/Petroleum and
Rail/Petroleum Subcategories. Based on the results of this review and information currently
available to EPA, the Agency believes that this technology does not provide adequate and/or
cost-effective treatment of TEC wastewaters at facilities in the Truck/Petroleum and
Rail/Petroleum Subcategories. EPA does not currently have sampling data for chemical
precipitation units operated at TEC facilities. All cost estimates for chemical precipitation
treatment of TEC wastewater are based on chemical precipitation costs developed for EPA's
Industrial Laundries Effluent Limitations Guidelines program.
In this module, EPA estimates costs for a facility to install and operate a chemical
precipitation unit to remove dissolved rnetals and entrained solid or liquid particles from raw
wastewater. The cost estimate includes the costs necessary to perform batch chemical
precipitation treatment and to remove, store, and dispose of settled sludge.
Capital and annual costs for the following equipment are included in the chemical
precipitation unit module:
• A mixing/settling tank;
• Three chemical feed systems;
« An agitator;
• An effluent pump;
• A sludge pump;
• A sludge holding tank; and
• A control system.
Annual costs include operational labor, maintenance and repair labor, O&M materials,
electricity, chemicals, and settled solids disposal. The chemical precipitation unit operates in
batch mode, and EPA assumes that the system treats one batch per day (i.e., treatment of one
day's wastewater). Electricity costs for agitators, chemical transfer pumps (polyalum chloride,
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Section 10.0 - Costs of Technology Bases for Regulations
anionic polymer, and cationic polymer), and the effluent pump are based on motor horsepower
necessary to operate the unit and chemical or wastewater transfer rates needed to operate the unit.
Sludge is collected from the chemical precipitation sludge storage tank once per
month. Sludge disposal costs are the same throughout the TECI cost model. The sludge
generation rate is estimated using the difference between the influent and effluent average total
suspended solids concentrations. EPA assumes that the precipitation sludge stream comprises
5.7% solids, based on engineering literature.
10.3.12 Filter Press (for Wastewater Clarification and Biological
Treatment Sludge Dewatering)
In this module, EPA estimates costs for a facility to install and operate a single
filter press for two operations: wastewater clarification and biological treatment sludge
dewatering. During wastewater treatment operating hours, the filter press functions as a
wastewater clarifier. Following wastewater treatment operating hours, the filter press dewaters
sludge from biological treatment. The module calculates the costs necessary to filter and store
wastewater before being discharged or pumped to subsequent treatment units. The module also
calculates annual costs associated with sludge dewatering. The filter press is designed to treat
one batch of wastewater per day and one batch of biological treatment sludge per day.
Capital and annual costs for the following equipment are included in the filter
press module:
• An influent pump and compressor;
• A diatomaceous earth precoat tank;
• A diatomaceous earth precoat pump and compressor;
• A filter press; and
• An effluent storage tank.
Annual costs include operational labor, maintenance and repair labor, O&M materials,
electricity, and residual disposal. Based on observations made during EPA site visits and
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Section 10.0 - Costs of Technology Bases for Regulations
sampling episodes, EPA assumes that both operations generate equal daily volumes of dewatered
sludge. Dewatered sludge volumes are based on the ratio of dewatered sludge generation rate to
wastewater flow rate observed during EPA site visits and sampling episodes at TEC facilities.
The filter press volume is based on and equal to the volume of dewatered sludge from just one of
the operations. Waste disposal costs are calculated separately in the waste haul module (see
Section 10.3.21) and are based on the total volume of dewatered sludge from both filter press
operations. EPA assumes the dewatered filter cake volume comprises 32% solids, based on
engineering literature.
The influent pump and precoat transfer pump costs are based on influent
wastewater flow rate. Electricity costs for the pumps are based on motor horsepower necessary
to transfer wastewater and polymer at the flow rates estimated by the filter press module.
The diatomaceous earth precoat tank costs and effluent storage tank costs are
based on tank volumes recommended by filter press vendors. The amount of diatomaceous earth
necessary to treat wastewater and biological treatment sludge is based on the ratio of
diatomaceous earth usage rate to wastewater flow rate observed during EPA site visits and
sampling episodes at TEC facilities.
10.3.13
Biological Treatment
In this module, EPA estimates costs for a facility to install and operate a
biological oxidation unit used to decompose organic constituents. The module calculates costs
necessary for operating an aerobic biological treatment unit consisting of two preaeration tanks, a
post-treatment clarifier, and a sludge storage tank. A portion of the sludge is recycled by
pumping the sludge from the clarifier to the second preaeration tank. Sludge is also pumped
from the clarifier into a sludge storage tank for subsequent dewatering.
Capital and annual costs for the following equipment are included in the
biological treatment module:
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Section 10.0 - Costs of Technology Bases for Regulations
• Wastewater transfer pumps;
• Two preaeration tanks;
• Diffusers/blowers;
• A biological reactor tank;
• A clarifier;
• A sludge storage tank;
• A sludge pump; and
• A biological treatment effluent discharge pump.
Annual costs include operational labor, maintenance and repair labor, O&M materials,
electricity, and residual disposal. The biological reactor capital and annual costs are based on a
tank volume designed to provide a wastewater residence time of 4.6 days, as observed during
EPA site visits and sampling episodes at TEC facilities. Annual additions of microorganisms to
the biotreatment unit is based on the ratio of microorganism addition rate to wastewater flow rate
observed during EPA site visits and sampling episodes at TEC facilities.
The wastewater transfer pump costs are based on influent wastewater flow rate.
Electricity costs for the pumps are based on motor horsepower necessary to transfer wastewater
at the influent flow rate. The diffuser/blower costs are based on the ratio of air flow rate to
wastewater flow rate observed during EPA site visits and sampling episodes at TEC facilities.
The preaeration and sludge storage tank volumes are based on the ratio of tank
volume to wastewater flow rate observed during EPA site visits and sampling episodes at TEC
facilities. The sludge and effluent discharge pump costs are based on motor horsepower
necessary to transfer sludge and wastewater at the flow rates estimated by the biological
treatment module.
The clarifier is used to settle sludge following the biological digestion in the
biological reactor. Clarifier costs are based on the ratio of clarified volume to wastewater flow
rate observed during EPA site visits and sampling episodes at TEC facilities.
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Section 10.0 - Costs of Technology Bases for Regulations
10.3.14
Activated Carbon Adsorption (Vessels)
In this module, EPA estimates costs for a facility to install and operate an
activated carbon adsorption system used as a tertiary treatment technology applicable to waste
streams following treatment by chemical oxidation, neutralization, coagulation, and clarification.
The module calculates costs necessary for operating two activated carbon columns in series.
Spent carbon is assumed to require off-site disposal once per month.
Capital and annual costs for the following equipment are included in the granular
activated carbon module:
• A wastewater transfer pump; and
• Two carbon adsorption filters.
Annual costs include operational labor, maintenance and repair labor, O&M materials,
electricity, chemicals (media changeout), and residual disposal. The capital and annual costs
associated with the carbon adsorption filters are based on the ratios of activated carbon system
size and carbon usage rate to wastewater flow rate observed during EPA site visits and sampling
episodes at TEC facilities.
The costs associated with the wastewater transfer pump are based on influent
wastewater flow rate. Electricity costs are based on motor horsepower necessary to operate the
carbon adsorption system.
One column of spent activated carbon is assumed to be changed out once each
month. Media change-out costs include costs for labor and fresh media. Spent carbon is
assumed to be sent off site for regeneration. Residual disposal costs include costs for waste
shipping and media disposal. For cost estimating purposes, EPA assumes that TEC facilities
typically operate an average of 265 days per year. Costs are adjusted for facilities operating less
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Section 10.0 - Costs of Technology Bases for Regulations
than 265 days per year by multiplying "typical" residual disposal costs by a factor consisting of
actual operating days divided by 265.
10.3.15
Activated Carbon Adsorption (Canisters)
In this module, EPA estimates costs for a facility to install and operate an
activated carbon adsorption system for wastewater polishing followed by total recycle/reuse of
TEC wastewater in TEC operations. The module calculates the costs necessary for disposal of
spent carbon canisters.
Capital and annual costs for the following equipment are included in the carbon
canisters module:
An influent pump; and
Carbon canisters.
Annual costs include operational labor, maintenance and repair labor, O&M materials,
electricity, replacement carbon canisters, and residual disposal costs. The activated carbon
canister usage rate is calculated using wastewater flow rates, pollutant concentrations, and
estimated carbon adsorption capacities for the pollutants in the wastewater. Annual carbon
canister costs include labor to remove the spent carbon canister and install the new canister,
transportation, and disposal of the spent carbon.
Influent pump costs are based on influent wastewater flow rate to the system.
Electricity costs are based on motor horsepower necessary to transfer influent wastewater.
10.3.16
Organo-CIay/Activated Carbon Adsorption
In this module, EPA estimates costs for a facility to install and operate an organo-
clay adsorption unit followed by a granular activated carbon unit for wastewater polishing. The
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Section 10.0 - Costs of Technology Bases for Regulations
module calculates costs to operate two columns in series (organo-clay followed by activated
carbon) with nominal carbon change-out frequency of one vessel per month and nominal organo-
clay change-out frequency of one vessel per two months.
Capital and annual costs for the following equipment are included in the organo-
clay/activated carbon adsorption module:
• A wastewater transfer pump;
• An organo-clay vessel; and
• A granular activated carbon vessel.
Annual costs include operational labor, maintenance and repair labor, electricity, chemicals
(media), and residual disposal. The costs associated with the organo-clay vessel and granular
activated carbon vessels are based on the ratio of filter media volume to influent flow rate
observed during EPA site visits and sampling episodes at TEC facilities.
The costs associated with the wastewater transfer pump are based on influent
wastewater flow rate. The pump is designed to operate at a flow rate of one-half the stated
maximum capacity of the pump. Electricity costs are based on motor horsepower necessary to
transfer influent wastewater.
The design media change-out frequency is once per month for granular activated
carbon, and once every two months for organo-clay, based on information provided by treatment
system vendors. Spent carbon is assumed to be sent off site for regeneration or disposal and
spent clay is assumed to be sent off site for incineration. Media change-out costs include costs
for labor and fresh media. Residual disposal costs include costs for waste shipping and media
disposal.
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Section 10.0 - Costs of Technology Bases for Regulations
10.3.17
Reverse Osmosis
In this module, EPA estimates costs for a facility to install and operate a reverse
osmosis unit for wastewater polishing. The module calculates costs necessary for wastewater
storage prior to entering the reverse osmosis unit, and the reverse osmosis unit itself. The reverse
osmosis unit is operated as a double pass unit. After the first pass through the reverse osmosis
unit, the wastewater is transferred to a storage tank. When the storage tank is nearly full, the
wastewater is pumped for a second pass through the reverse osmosis unit prior to discharge.
Concentrate from the reverse osmosis unit is recycled to the first biological treatment preaeration
tank.
Capital and annual costs for the following equipment are included in the reverse
osmosis module:
• Two reverse osmosis wastewater storage tanks;
• A reverse osmosis flooded suction tank; and
• A reverse osmosis unit.
Annual costs include operational labor, maintenance and repair labor, electricity, and membrane
and pretreatment filter replacement costs. The reverse osmosis unit capital costs are based on
influent wastewater flow rate. Electricity costs are based on motor horsepower necessary to
operate the unit at the flow rate estimated by the reverse osmosis module. Membrane and filter
replacement costs are based on influent wastewater flow rate and information provided by
treatment technology vendors. EPA estimates that membranes require replacement every five
years, and the pretreatment filter cartridges must be replaced every two months.
The reverse osmosis wastewater storage tanks and flooded suction tank costs are
based on the ratio of tank volume to wastewater flow rate observed during EPA site visits and
sampling episodes at TEC facilities.
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10.3.18
Section 10.0 - Costs of Technology Bases for Regulations
Sludge Dewatering (Plaite-and-Frame Filter Press)
In this module, EPA estimates costs for a facility to install and operate a plate-
and-frame filter press. The module calculates costs .necessary to operate a plate-and-frame filter
press to dewater sludge that is generated by wastewater treatment units.
For the Truck/Chemical Subcategory, EPA assumes that facilities will use a
portable pump to pump sludge from the sludge storage tanks into the filter press. Because EPA
includes a portable purnp in the oil/water separator module (see Section 10.3.4), costs are not
included for an additional pump in the sludge dewatering module for the Truck/Chemical
Subcategory.
Capital and annual costs for the following equipment are included in the plate-
and-frame filter press module:
• A plate-and-frame filter press;
• Sludge transfer pumps (Rail/Chemical, Truck/Food, Rail/Food, and
Barge/Food Subcategories);
• Sludge storage tank (PSES Option 1 for the Rail/Chemical Subcategory);
• Precoat (diatomaceous earth) tank (for dewatering biological treatment
sludge); and
• Precoat transfer pump and compressor (for dewatering biological
treatment sludge).
Annual costs include operational labor, maintenance and repair labor, O&M materials,
electricity, chemical costs (diatomaceous earth), and residual disposal costs. The filter press
capital and. annual costs are calculated using the ratio of sludge generation rate to wastewater
flow rate observed during EPA site visits and sampling episodes at TEC facilities, as well as
technical literature on sludge and filter cake solids contents. In general EPA assumes that the
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Section 10.0 - Costs of Technology Bases for Regulations
press operates one batch per day; therefore, the press volume generally equals the estimated daily
volume of filter cake generation. However, for the Truck/Chemical and Rail/Chemical
Subcategories, EPA performed an optimization analysis to determine filter press volume versus
the number of batches per day based on the filter cake generation rate and operational days per
year. EPA assumes that the filter press will operate no more than two batches per day. The cost
for hauling dewatered sludge is estimated separately in the waste haul module (see Section
10.3.21) and is based on the calculated volume of dewatered sludge generated. EPA assumes
that the dewatered sludge comprises 32 to 33% solids, based on engineering literature.
The sludge transfer pump costs are based on motor horsepower necessary to
transfer sludge at flow rates estimated by the sludge dewatering module. The precoat transfer
pump costs are based on influent wastewater flow rate. Electricity costs are based on motor
horsepower necessary to transfer polymer at flow rates estimated by the sludge dewatering
module.
The diatomaceous earth precoat tank costs are based on tank volumes
recommended by filter press vendors. The amount of diatomaceous earth necessary is based on
the ratio of diatomaceous earth usage rate to wastewater flow rate observed during EPA site
visits and sampling episodes at TEC facilities.
10.3.19 Contract Hauling of Wastewater in Lieu of Treatment
In this module, if contract hauling in lieu of treatment is appropriate, capital and
annual costs for a wastewater holding tank are included in the module. Annual costs include
maintenance and repair labor, O&M materials, transportation, and disposal of wastewater. EPA
assumes that wastewater would be accumulated in a holding tank and then disposed off site every
three months. Holding tank costs are based on the tank volume needed to contain all of the
wastewater generated by a facility over a three-month period.
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Section 10.0 - Costs of Technology Bases for Regulations
Transportation disposal costs are based on gallons of wastewater to be disposed.
EPA uses quotes from nation-wide vendors to estimate costs for contract hauling wastewater off
site. EPA estimates a cost of $0.44/gallon (7) to contract haul wastewater off site.
10.3.20
Compliance Monitoring
This practice is included in all of the proposed regulatory options for all
subcategories. Regulatory options were not developed by EPA for BPT, BCT, BAT, and NSPS
for facilities in the Truck/Petroleum and Rail/Petroleum Subcategories.
In this module, EPA estimates annual compliance monitoring costs for all TEC
facilities. The annual cost calculated by the model for compliance monitoring included
laboratory costs to analyze wastewater volatile and semivolatile organics, metals, and classical
pollutants. For indirect dischargers, EPA estimates costs for facilities to monitor monthly for all
regulated pollutants! For direct dischargers, EPA estimates costs for facilities to monitor weekly
for classical pollutants and monthly for volatile and semivolatile organics and metals. However,
for the food subcategories direct dischargers, EPA estimates costs for facilities to monitor weekly
for classical pollutants, with no monitoring for any other pollutants, because EPA is regulating
only these pollutants in the food grade subcategories. The costs for each .type of analysis per
sample were obtained from a laboratory contracted by EPA on past wastewater sampling efforts.
The table below shows the monitoring costs used in the cost model.
•• •. ' •. * ?*•"' '"^'Jsv^V^ ''•,{•••.„ ' s
Analytical Method * "' ;
•>''.'*' •'•>•>' "^ v „ •••, \ .• ^ w v *•• •• •"
Method 1624 - Volatile Organic Compounds
Method 1625 - Semi-Volatile Organic Compounds
Method 1 620 - Metals
Methods 405.1, 410.4, 335.1, 1664, 150.1, 415.1, 420.2 - Classical
Pollutants
laboratory Fee /
', V<$19J>4)^' XJ
$459
$1040.40
$598
$177
' '^ /
' >3J
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Section 10.0 - Costs of Technology Bases fot Regulations
10.3.21
Waste Hauling
In this module, where applicable, EPA estimates annual waste hauling costs for
oil (95% oil), undewatered sludge (approximately 4% solids), and dewatered sludge
(approximately 32% solids) for all TEC facilities. The cost model calculates annual costs for
waste hauling, including labor and transportation. Cost rates are obtained from nation-wide
vendors. Undewatered sludge disposal costs are based on using either a vac-truck or multiple
drums, depending on the volume to be disposed. Dewatered sludge costs include an annual roll-
off box rental.
10.4
Summary of Costs by Regulatory Option
Table 10-5 summarizes estimated BPT, BCT, and BAT compliance costs by
regulatory option. Table 10-6 summarizes estimated PSES compliance costs by regulatory
option. Costs shown include capital and O&M costs (including energy usage) totaled for each
subcategory for all discharging facilities. All costs represent the estimated incremental
compliance costs to the industry. The capital costs shown in Tables 10-5 and 10-6 represent the
direct capital costs estimated by the technology modules plus the indirect capital costs discussed
in Section 10.2.4.1. The annual costs shown in Tables 10-5 and 10-6 represent the direct annual
costs estimated by the technology modules plus the compliance monitoring and waste hauling
costs discussed in Sections 10.3.20 and 10.3.21.
10.5
References1
1.
U.S. Environmental Protection Agency, Office of Water. Economic Analysis for
the Proposed Effluent Limitations Guidelines for the Transportation Equipment
Cleaning Industry. EPA-821-B-98-012, May 1998.
1 For those references included in the administrative record supporting the proposed TECI rulemaking, the
document control number (DCN) is included in parentheses at the end of the reference.
10-46
-------
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
Section 10.0 - Costs of Technology Bases for Regulations
U.S. Environmental Protection Agency, Office of Water. Statistical Support
Document for the Proposed Effluent Limitations Guidelines for the Transportation
Equipment Cleaning Industry. EPA-821-B-98-014, May 1998.
The Richardson Rapid System Process Plant Construction Estimating Standards.
Volume 4: Process Equipment, 1994.
Eastern Research Group, Inc. Standard Annual Cost Rates Used in the TECI Cost
Model. Memorandum from Melissa Cantor, Eastern Research Group, Inc. to the
TECI Rulemaking Record, April 22,1998 (DCN T09977).
Eastern Research Group, Lie. Flow Reduction Cost Module Documentation for
the Transportation Equipment Cleaning Cost Model. May 1998 (DCN T09753).
"Economic Indicators." Chemical Engineering. September 1995, page 168.
Eastern Research Group, Inc. Contract Haul Cost Module Documentation for the
Transportation Equipment Cleaning Cost Model. May 1998 (DCN T09754).
Eastern Research Group, Inc. Monitoring Cost Module Documentation for the
Transportation Equipment Cleaning Cost Model. May 1998 (DCN T09852).
Eastern Research Group, Inc. Equalization Cost Module Documentation
Transportation Equipment Cleaning Cost Model Truck/Chemical Subcategory.
May 1998 (DCN T09730).
Eastern Research Group, Inc. Oil/Water Separation Cost Module Documentation
for the Transportation Equipment Cleaning Cost Model Truck/Chemical
Subcategorv (Direct Dischargers). May 1998 (DCN T09734).
Eastern Research Group, Inc. Oil/Water Separation Cost Module Documentation
for the Transportation Equipment Cleaning Cost Model Truck/Chemical
Subcategorv (Indirect Dischargers). May 1998 (DCN T09731).
Eastern Research Group, Inc. Chemical Oxidation/Neutralization/Coagulation/
Clarification Cost Module Documentation for the Transportation Equipment
Cleaning Cost Model Tmck/Chemical Subcategory (Direct Dischargers). May
1998 (DCN T09735).
Eastern Research Group, Inc. Chemical Oxidation/Neutralization/Coagulation/
Clarification Cost Module Documentation for the Transportation Equipment
Cleaning Cost Model Tmck/Chemical Subcategory (Indirect Dischargers). May
1998 (DCN T09732).
10-47
-------
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
Section 10.0 - Costs of Technology Bases for Regulations
Eastern Research Group, Inc. Sludge Dewatering Cost Module Documentation
for the Transportation Equipment Cleaning Cost Model Truck/Chemical
Subcategorv (Direct Dischargers! May 1998 (DCN T09726).
Eastern Research Group, Inc. Sludge Dewatering Cost Module Documentation
for the Transportation Equipment Cleaning Cost Model Truck/Chemical
Subcategorv (Indirect Dischargers! May 1998 (DCN T09723).
Eastern Research Group, Inc. Biological Treatment Cost Module Documentation
for the Transportation Equipment Cleaning Cost Model Truck/Chemical
Subcategorv (Direct Dischargers). May 1998 (DCN T09736).
Eastern Research Group, Inc. Activated Carbon Adsorption Cost Module
Documentation for the Transportation Equipment Cleaning Cost Model
Truck/Chemical Subcategorv. May 1998 (DCN T09733).
Eastern Research Group, Inc. Oil/Water Separation Cost Module Documentation
for the Transportation Equipment Cleaning Cost Model Rail/Chemical
Subcategorv (Direct Dischargers'). May 1998 (DCN T09741).
Eastern Research Group, Inc. Oil/Water Separation Cost Module Documentation
for the Transportation Equipment Cleaning Cost Model Rail/Chemical
Subcategorv (Indirect Dischargers'). May 1998 (DCN T09737).
Eastern Research Group, Inc. Equalization Cost Module Documentation for the
Transportation Equipment Cleaning Cost Model Rail/Chemical Subcategorv.
May 1998 (DCNT09738).
Eastern Research Group, Inc. pH Adjustment/Dissolved Air Flotation Cost
Module Documentation for the Transportation Equipment Cleaning Cost Model
Rail/Chemical Subcategorv (Direct Dischargers'). May 1998 (DCN T09742).
Eastern Research Group, Inc. pH Adjustment/Dissolved Air Flotation Cost
Module Documentation for the Transportation Equipment Cleaning Cost Model
Rail/Chemical Subcategorv (Indirect Dischargers). May 1998 (DCNT09739).
Eastern Research Group, Inc. Sludge Dewatering Cost Module Documentation for
the Transportation Equipment Cleaning Cost Model Rail/Chemical Subcategorv
(Direct Dischargers! May 1998 (DCN T09727).
Eastern Research Group, Inc. Sludge Dewatering Cost Module Documentation for
the Transportation Equipment Cleaning Cost Model Rail/Chemical Subcategorv
(Indirect Dischargers'). May 1998 (DCN T09724).
10-48
-------
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
Section 10.0 - Costs of Technology Bases for Regulations
Eastern Research Group, Inc. Biological Treatment Cost Module Documentation
for the Transportation Equipment Cleaning Cost Model Rail/Chemical
Subcateeorv (Direct Dischargers). May 1998 (DCN T09743).
Eastern Research Group, Inc. Organo-Clav/Granular Activated Carbon Cost
Module Documentation for the Transportation Equipment Cleaning Cost Model
Rail/Chemical Subcategorv. May 1998 (DCN T09740).
Eastern Research Group, Inc. Primary Oil/Water Separation and Dissolved Air
Flotation Cost Module Documentation for the Transportation Equipment Cleaning
Cost Model Barge/Chemical Subcategorv. May 1998 (DCN T09744).
Eastern Research Group, Inc. Filter Press Cost Module: Sludge Dewatering
Documentation for the Transportation Equipment Cleaning Cost Model
Barge/Chemical Subcategorv (Baseline). May 1998 (DCN T09851).
Eastern Research Group, Inc. Filter Press Cost Module: Wastewater and Sludge
Documentation for the Transportation Equipment Cleaning Cost Model
Barge/Chemical Subcategorv (Direct Dischargers'). May 1998 (DCN T09728).
Eastern Research Group, Inc. Filter Press Cost Module: Wastewater and Sludge
Documentation for the Transportation Equipment Cleaning Cost Model
Barge/Chemical Subcategorv (Indirect Dischargers). May 1998 (DCN T09725).
Eastern Research Group, Inc. Biological Treatment Cost Module Documentation
for the Transportation Equipment Cleaning Cost Model Barge/Chemical
Subcategorv. May 1998 (DCN T09745).
Eastern Research Group, Inc. Reverse Osmosis Cost Module Documentation for
the Transportation Equipment Cleaning Cost Model Barge/Chemical Subcategorv.
May 1998 (DCN T09746).
Eastern Research Group, Inc. Equalization Cost Module Documentation for the
Transportation Equipment Cleaning Cost Model Food Subcategories. May 1998
(DCN T09748).
Eastern Research Group, Inc. Oil/Water Separation Cost Module Documentation
for the Transportation Equipment Cleaning Cost Model Food Subcategories. May
1998 (DCN T09749).
Eastern Research Group, Inc. Biological Treatment Cost Module Documentation
for the Transportation Equipment Cleaning Cost Model Food Subcategories. May
1998 (DCN T09750).
10-49
-------
36.
37.
38.
39.
40.
41.
42.
43.
Section 10.0 - Costs of Technology Bases for Regulations
Eastern Research Group, Inc. Sludge Dewatering Cost Module Documentation
for the Transportation Equipment Cleaning Cost Model Food Subcategories. May
1998(DCNT09729).
Eastern Research Group, Inc. Equalization Cost Module Documentation for the
Transportation Equipment Cleaning Cost Model Truck/Petroleum and
Rail/Petroleum Subcategories. May 1998 (DCN T09853).
Eastern Research Group, Inc. Oil/Water Separation Cost Module Documentation
for the Transportation Equipment Cleaning Cost Model Truck/Petroleum and
Rail/Petroleum Subcategories (Indirect Dischargers). May 1998 (DCN T09751).
Eastern Research Group, Inc. Activated Carbon Adsorption Cost Module
Documentation for the Transportation Equipment Cleaning Cost Model
Truck/Petroleum and Rail/Petroleum Subcategories. May 1998 (DCN T09752).
Eastern Research Group, Inc. Abbreviated Cost Analysis for Compliance with
Option 1 for the Truck/Petroleum and Rail/Petroleum Subcategories.
Memorandum from Melissa Cantor, Eastern Research Group, Inc. to the TECI
Rulemaking Record, April 23,1998 (DCN T09759).
Eastern Research Group, Inc. Gravity Separator Cost Module Documentation for
the Transportation Equipment Cleaning Cost Model Hopper Subcategories. May
1998 (DCN T09747).
Eastern Research Group, Inc. TECI Cost Model Annual Cost Factors for Pumps.
Memorandum from Melissa Cantor, Eastern Research Group, Inc. to the TECI
Rulemaking Record, October 10, 1997 (DCN T04654).
Eastern Research Group, Inc. TECI Cost Model Annual Cost Factors for Tanks.
Memorandum from Melissa Cantor, Eastern Research Group, Inc. to the TECI
Rulemaking Record, March 27,1998 (DCN T09976).
10-50
-------
Section 10.0 - Costs of Technology Bases for Regulations
Table 10-1
Number of Costed Technology Options for Each TECI Subcategory
Swbcategoi$; - ;- / •' -^ '"I
Truck/Chemical
Rail/Chemical
Barge/Chemical & Petroleum
Truck/Food
Rail/Food
Barge/Food
Truck/Petroleum
Rail/Petroleum
Truck/Hopper
Rail/Hopper
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4
6
3
2
2
2
1
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1
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10-59
-------
Section 10.0 - Costs of Technology Bases for Regulations
Table 10-3
Components of Total Capital Investment
Item
1
2
3
4
5
6
Component
Equipment capital costs (including required
accessories), installation, delivery, electrical and
instrumentation, enclosure, and pumping
Piping
Secondary containment/land costs
Excavation and site work
Indirect costs including: engineering and
supervision, construction expenses, contractor's
fee, and contingency
Total Capital Investment (equals fixed capital
investment)
- Cost '<~ >' "";>
Direct Capital Cost
10% of item 1
10% of item 1
3.5% of item 6
20% of item 6
Sum of items 1 through 5 =
1.57 x Direct Capital Cost
Source: Transportation Equipment Cleaning Design and Cost Model.
10-60
-------
Section 10.0 - Costs of Technology Bases for Regulations
Table 10-4
Operation and Maintenance Unit Costs Used by the TECI Cost Model
Item
Cost®1994)/
Cost Equafion ($1994) t
Activity _ ' .
Contract hauling of bulk
wastewater
Disposal of waste oil (95% oil,
5% water)
Nonhazardous dewatered
sludge disposal
Nonhazardous undewatered
sludge disposal
Laboratory fee for volatile
organic compounds
Laboratory fee for semivolatile
organic compounds
Laboratory fee for metals
Laboratory fee for classical
pollutants .
$0.44/gallon
$0.37/gallon
$141.01/yd3 + $4,176/yr for
roll-off box rental
$0.53-$3.58/gallon
(based on volume)
$459/analysis
$1040.40/analysis
$598/analysis
$177/analysis
Tracfice/,
'Eeclmology: *
X-
Reference
- '* _ V>
v s/s '
Contract Haul
Contract Haul
Contract Haul
Contract Haul
Compliance Monitoring
Compliance Monitoring
Compliance Monitoring .
Compliance Monitoring
(7)
(7)
(7)
(7)
(8)
(8)
(8)
(8)
Chemicals ,' ,' , / ';', \^ " \" VC' v, ' r ''-..^ ^ ;_ \^Y~. ,:^
Activated carbon (annual
media change-out and
regeneration)
Biological treatment microbes
Activated carbon canister
(annual change-out and
regeneration)
Demulsifier
Diatomaceous earth
Organo-clay/activated carbon
adsorption (annual media
change-out)
Organo-clay/activated carbon
disposal (organo-clay
incineration and activated
carbon regeneration)
A = 0.00112(ACV)2 +
11.663(ACV) + 11058.543
$2.84/lb
$842.70/canister
$33.36/gallon
$0.76/lb
A = -1.785(FMV)2 +
946.009(FMV) - 450.496
A=!61.429(FMV) +
8464.083
Activated Carbon
Adsorption
Biological Treatment
Activated Carbon
Adsorption
Oil/Water Separator
Filter Press, Sludge
Dewatering
Organo-Clay/Activated
Carbon Adsorption
Organo-Clay/Activated
Carbon Adsorption
(17)
(16, 25, 31,
35)
(39)
(10, 11,
38)
(14, 23, 28,
29, 30, 36)
(25)
(26)
10-61
-------
Section 10.0 - Costs of Technology Bases for Regulations
Table 10-4 (Continued)
Item
Hydrogen peroxide
Magnesium hydroxide
Polyalum chloride
Polymer
Polymer 7032
Polymer 7181
Polymer 7622
Sodium hydroxide (50%)
Sulfuric acid (93%)
Cost($1994)/
CostEquafion ($1994)
$0.45-$0.69/lb
$0.26-$0.36/lb
$2.53-$4.28/gallon
$2.65-$3.00/lb
$1.10/lb
$4.45/lb
$1.25/lb
$1.689/gallon
$0.095-$0.28/lb
$1.09 I/gallon
Practice/
Technology
Chemical Oxidation,
Neutralization, Coagulation,
Clarification
Chemical Oxidation,
Neutralization, Coagulation,
Clarification
Chemical Oxidation,
Neutralization, Coagulation,
Clarification
Chemical Oxidation,
Neutralization, Coagulation,
Clarification
DAF
DAF
DAF
pH Adjustment
Chemical Oxidation,
Neutralization, Coagulation,
Clarification, and
pH Adjustment
Labor Costs "
Flow reduction training
Pump operational labor
Pump maintenance labor
Oil/water separator (vertical
tube coalescing) operational
labor
Oil/water separator (vertical
tube coalescing) maintenance
labor
A = (FPT-REG)(0.5)(25.9) for
truck and barge tank type
(where A k 34188 for the
Barge/Chemical and
Barge/Food Subcategories and
A ^10360 for the
Barge/Hopper Subcategory)
A=(FPT-REG)(0.5)(25.9)/(1 .7)
for rail tank type
A = (0.05)(DPY)(25.9)
A = (0.005)(DPY)(HPD)(25.9)
A = (0.05)(DPY)(25.9)
A = (0.005)(HPD)(DPY)(25.9)
+ ((48)(25.9))
Flow Reduction
All
All
Oil/Water Separator
Oil/Water Separator
Reference
(12, 13)
(12, 13)
(12, 13)
(12, 13)
(21, 22)
(21,22)
(21, 22)
(21, 22)
(12, 13, 21,
22)
"
(5)
(42)
(42)
(10, 11,
38)
(10, 11,
38)
10-62
-------
Section 10.0 - Costs of Technology Bases for Regulations
Table 10-4 (Continued)
Item
Tanks with mixers maintenance
labor
Tanks without mixers
maintenance labor
Tank(all) repair labor
Filter press operational labor
DAF operational labor
DAF maintenance and repair
labor
Chemical oxidation,
neutralization, coagulation,
clarification operational labor
Chemical oxidation,
neutralization, coagulation,
clarification maintenance and
repair labor
Activated carbon unit repair
labor
pH probe maintenance and
repair labor
Organo-clay/granular activated
carbon unit repair labor
Reverse osmosis operational
labor
Reverse osmosis maintenance
labor
Oil/water separation (API)
maintenance labor
" ,\ '€6st($1994}/, * ' ' •
CojtfjEquation ($1994) :
A = 103.6 -207.2
(based on tank volume)
A = 414.4 -828.8
(based on tank volume)
A = (0-01X0)
A = (BPY)(12.95) -
(BPY)(25.9)
(based on filter press volume)
A = (1)(DPY)(25.9) -
(2)(DPY)(25.9)
(based on chemical addition)
A = (0.01)(C) - (0.02)(C)
(based on chemical addition)
A = (HPD)(DPY)(25.9)
A = (32)(25.9)
A = (0.01)(C)
A = (2X0.01X0)
A = (0.01)(C)
A = (DPY)(25.9)
A = 414.4
A = 414.4
's ^ractiee/^,, ^ /;
'Technology, ,
Equalization,
pH Adjustment,
Filter Press,
DAF,
Biological Treatment,
Sludge Dewatering
All
All
Filter Press,
Sludge Dewatering
DAF
DAF
Chemical Oxidation,
Neutralization, Coagulation,
Clarification
Chemical Oxidation,
Neutralization, Coagulation,
Clarification
Activated Carbon
Adsorption
pH Adjustment
Organo-Clay/Activated
Carbon Adsorption
Reverse Osmosis
Reverse Osmosis
Oil/Water Separation
s f f f
Reference*'
(9, 14, 20,
21, 22, 23,
28, 29, 30,
31, 33, 36,
37,43)
(43)
(43)
(14, 15, 23,
24, 28, 29,
30, 36)
(21, 22,
27)
(21, 22,
27)
(12, 13)
(12, 13)
(17)
(21,22)
(25)
(32)
(32)
(18, 19)
Material and Replacement Costs '''„",-' „-""""'' \
Pump materials
Chemical oxidation/
neutralization/coagulation/
clarification materials
A = (0.01)(C)
. A = (0.01)(C)
All
Chemical Oxidation,
Neutralization, Coagulation,
Clarification
(42)
(12, 13)
10-63
-------
Section 10.0 - Costs of Technology Bases for Regulations
Table 10-4 (Continued)
Item
Demulsifier pump materials
Oil/water separator (vertical
tube coalescing) materials
Filter press materials
DAF (with chemical addition)
materials
Annual costs for a building
pH probe materials
Filter press precoat storage
tank materials
Reverse osmosis membrane
replacement
Cost($1994)/
Cost Equation ($1994)
A = 15
A = 8-25
(based on wastewater flow)
A = (0.01)(C)
A = (0.01)(C)
A = (0.035)(C)
A =185/0.75
A = (0.01)(C)
A = -1.409(GPM)2 +
142.64(GPM) + 707.27
General Costs
Electricity usage fee
O&M labor rate
Water usage fee
$0.047/ kilowatt-hour
$25.90/hour
$2.98/1,000 gal of water
Practice/
Technology
Oil/Water Separation
Oil/Water Separation
Filter Press
Sludge Dewatering
DAF
DAF
pH Adjustment
Filter Press,
Sludge Dewatering
Reverse Osmosis
x
All
All
Flow Reduction
Reference
(10, 11,
38)
(10, 11,
38)
(14, 15, 23,
24, 28, 29,
30, 36)
(21, 22)
(21, 22)
(21,22)
(14, 23, 28,
29, 30, 36)
(32)
4
(4)
(3)
(5)
A - Annual costs ($1994/year).
ACV - Activated carbon vessel volume (cubic feet).
BPY - Filter press batches per year.
C - Direct capital equipment costs ($1994).
DPY - Operating days per year.
DAF - Dissolved Air Flotation.
FMV - Filter media vessel volume (cubic feet).
FPT - Flow per tank (gallons).
GPM - Flow rate (gallons per minute).
HPD - Operating hours per day.
REG - Subcategory regulatory flow per tank (gallons).
X - Tank volume (gallons).
10-64
-------
Section 10 - Costs of Technology Bases for Regulations
Table 10-5
Cost Summary of Regulatory Options for BPT/BATYBCT (a)
Subcategory
Barge/Chemical
Barge/Chemical
Rail/Chemical
Rail/Chemical
Rail/Chemical
Truck/Chemical
Truck/Chemical
Truck/Food (b)
Truck/Food (b)
Barge/Food (b)
Barge/Food (b)
Barge/Hopper
n
Option 1
1 .
2
1
2
3
1
2
1
2
1
2
1
21?^ iSapitaTCost
f <• £) „, (Ptousamdp$1994)
$3,200
$4,800
$113
$272
$282
$134
$134
$0
$0
$0
$0
$160 (c)
OfcMGost^ " * j
CThousand^r (itf$1994))*'|
$1,900
$2,100
$42
$72.9
$29.9
$104
$104
$0
$0
$0
$0 .
$480 (c)
Source: Output from the Transportation Equipment Cleaning Industry Design and Cost Model.
(a) Costs are based on monthly monitoring for regulated toxic pollutants and weekly monitoring for conventional
pollutants (see (c)).
(b) All direct dischargers in these subcategories currently operate oil/water separation, equalization, and biological
treatment and are expected to meet the pollutant discharge long-term averages without incurring any additional
capital or annual costs.
(c) Costs are based on only monthly monitoring for all pollutants.
10-65
-------
Section 10 - Costs of Technology Bases for Regulations
Table 10-6
Cost Summary of Regulatory Options for PSES (a)
Subcategory
Barge/Chemical
Barge/Chemical
Barge/Chemical
Rail/Chemical
Rail/Chemical
Rail/Chemical
Truck/Chemical
Truck/Chemical
Barge/Food
Barge/Food
Rail/Food
Raiiypood
Thick/Food
Truck/Food
Barge/Hopper
Rail/Hopper
Truck/Hopper
Rail/Petroleum and
Truck/Petroleum (b)
Option
1
2
3
1
2
3
1
2
1
2
1
2
1
2
1
1
1
2
Capital Cost
(Thousand $1994)
$110
$320
$430
$4,400
$10,500
$11,000
$43,500
$53,600
$0
$30.2
$4,710
$41,100
$13,400
$55,300
$0
$0
$310
$1,800
O&MCost
(Thousand $/yr (in $1994))
$220
$240
$220
$1,400
$1,600
$2,600 .
$15,400
$24,700
$30.6
$61.6
$2,520
$3,340
$3,500
$5,510
$26
$28
$390
$830
Source: Output from the Transportation Equipment Cleaning Design and Cost Model.
(a) Costs are based on monthly monitoring of all regulated pollutants.
(b) Rail/Petroleum and Truck/Petroleum Subcategories are combined for reporting purposes.
10-66
-------
Section 11.0 - Pollutant Reduction Estimates
11.0
POLLUTANT REDUCTION ESTIMATES
This section describes EPA's estimates of industry pollutant loadings and
pollutant reductions for each of the Transportation Equipment Cleaning Industry (TECI)
technology options described in Section 9.0. The Agency estimated pollutant loadings and
pollutant reductions from TEC facilities in order to evaluate the impact of pollutant loadings
currently released to surface waters and publicly-owned treatment works (POTWs), to evaluate
the impact of pollutant loadings released to surface waters and POTWs following
implementation of each proposed TECI regulatory option, and to assess the cost-effectiveness of
each TECI regulatory option in achieving these pollutant loading reductions. Untreated, baseline,
and post-compliance pollutant loadings and pollutant reductions were estimated for the pollutants
effectively removed for each TECI subcategory. The identification of pollutants effectively
removed is discussed in Section 7.0. Untreated, baseline, and post-compliance pollutant loadings
are defined as follows:
Untreated loadings - pollutant loadings in raw transportation equipment
cleaning (TEC) wastewater. These loadings represent pollutant loadings
generated by the TECI, and do not account for wastewater treatment
currently in place at TEC facilities.
Baseline loadings - pollutant loadings in TEC wastewater currently being
discharged to POTWs or U.S. surface waters. These loadings account for
wastewater treatment currently in place at TEC facilities.
Post-compliance loadings - pollutant loadings in TEC wastewater that
would be discharged following implementation of each regulatory option.
These loadings are calculated assuming that all TEC facilities would
operate wastewater treatment technologies equivalent to the technology
bases for the regulatory options evaluated.
The following information is presented in this remainder of this chapter:
Section 11.1 presents the general methodology used to calculate TECI
pollutant loadings and pollutant reductions;
11-1
-------
Section 11.0 - Pollutant Reduction Estimates
Section 11.2 presents the general methodology used to estimate untreated
pollutant loadings in TEC wastewaters;
Section 11.3 presents methodology, used to estimate untreated production
normalized pollutant loadings (PNPLs) in TEC wastewaters for multiple
subcategory facilities;
Section 11.4 presents the estimated untreated pollutant loadings for the
TECI;
Section 11.5 presents the estimated baseline pollutant loadings for the
TECI;
Section 11.6 presents the estimated post-compliance pollutant loadings for
the TECI;
Section 11.7 presents the estimated pollutant loading reductions achieved
by the TECI following implementation of each regulatory option; and
Section 11.8 presents references for this section.
11.1
General Methodology Used to Calculate Pollutant Loadings
and Pollutant Reductions
la general, pollutant loadings and pollutant reductions were calculated for the
TECI using the following methodology:
1. Field sampling data were analyzed to determine pollutant concentrations in
untreated TEC wastewaters.
2. These concentrations were converted to untreated production normalized
pollutant loadings (PNPLs) for each TECI subcategory using the sampled
facility production data (i.e., the number of tanks cleaned), wastewater
flow rates, and operating data.
3. Untreated PNPLs were used in the TECI cost model (see Section 10.0) to
estimate the loading of each pollutant in each model facility untreated TEC
wastewater stream.
11-2
-------
Section 11.0 - Pollutant Reduction Estimates
4. Model facility daily untreated pollutant loadings were converted to
untreated influent concentrations using facility flow data and a conversion
factor.
5. Model facility untreated pollutant loadings and statistically generated
weighting factors were used to calculate untreated wastewater pollutant
loadings for the TECI and each TECI subcategory.
6. Treated effluent concentrations, or treatment effectiveness concentrations,
that are achieved by treatment technologies that comprise each TECI
regulatory option were developed using analytical data collected during
EPA's TECI sampling program (see Section 7.0).
7. The TECI cost model calculated the pollutant loadings and pollutant
loading reductions achieved at baseline. For facilities that have existing
treatment, the cost model compared the untreated TEC wastewater influent
concentrations to the treatment effectiveness concentrations achieved by
existing treatment, and determined the pollutant reductions achieved by
the existing treatment.
8. The baseline pollutant concentrations were converted to baseline pollutant
loadings using facility flow rates and a conversion factor.
9. TECI and TECI subcategory baseline pollutant loadings were calculated
for each regulatory option using the model facility baseline pollutant
loadings and statistically generated weighting factors,
10. The TECI cost model calculated the post-compliance pollutant loadings
and pollutant reductions achieved by each regulatory option. As discussed
in Section 9.0, each TECI regulatory option is comprised of a set of
pollutant control technologies. For each facility, the cost model compared
the pollutant concentrations in the wastewater influent to the regulatory
option treatment unit to the treatment effectiveness concentration achieved
by the treatment unit, and determined the pollutant reductions achieved.
11. The post-compliance pollutant concentrations were converted to post-
compliance pollutant loadings using facility flow rates and a conversion
factor.
12. TECI and TECI subcategory post-compliance pollutant loadings were
calculated for each regulatory option using the model facility post-
compliance pollutant loadings and statistically generated weighting
factors.
11-3
-------
Section 11.0 - Pollutant Reduction Estimates
13. For each model facility, the pollutant reductions achieved by each
regulatory option were calculated by subtracting the post-compliance
pollutant loadings from the baseline pollutant loadings.
14. TECI and TECI subcategory pollutant reductions achieved by each
regulatory option were calculated using the model facility pollutant
reductions and statistically generated weighting factors.
11.2
General Methodology Used, to Estimate Untreated Pollut
Loadings
The Agency used analytical data collected during EPA's TECI sampling program
to calculate untreated PNPLs for pollutants effectively removed by the regulatory options
evaluated for each TECI subcategory (Section 7.0 contains a discussion of pollutants effectively
removed). The following table lists the number of wastewater characterization samples
collected and analyzed for each TECI subcategory:
Subcategory
Truck/Chemical
Rail/Chemical
Barge/Chemical & Petroleum
Truck/Petroleum
Rail/Petroleum
Thick/Food
Rail/Food
Barge/Food
TYuck/Hopper
Rail/Hopper
Barge/Hopper
Nnmber of Uiitreated'Wastewater
Characterization Samples Collected
10
5
10
5
0
1
1
5
0
0
1
Number of Faculties -,
Sampled
5
2
3
1
0
1
1
1
0
0
1
Note that although some analytical data were available from facility responses to
the Detailed Questionnaire, these data were not useable for one or more of the following reasons:
(1) the data provided represented samples collected at a variety of treatment system
influent/effluent points that may not correspond to the technology options considered as the bases
11-4
-------
Section 11.0 - Pollutant Reduction Estimates
for regulation; (2) the data provided were an average estimated by the facility over one or more
sampling days, rather than individual analytical results as required for statistical analyses; and
(3) analytical quality assurance/quality control (QA/QC) data were not provided, prohibiting an
assessment of the data quality.
For each facility sampled, data on facility production (i.e., number of tanks
cleaned per day), cargo types cleaned, TEC wastewater flow rate, operating hours per day, and
operating days per year were collected. These data were used in conjunction with the untreated
wastewater analytical data to calculate PNPLs for each subcategory using the methodology
described below.
EPA first calculated PNPLs for each untreated wastewater sample collected at
each facility using the following equation:
C=xcf XF
where:
Q
cf
F
CD
Pollutant i in waste stream
Pollutant loading generated per tank cleaned (milligram/tank or
microgram/tank, depending on the pollutant)
Pollutant concentration in TEC wastewater characterization sample
(milligram/liter or microgram/liter, depending on the pollutant))
Conversion factor, (liters per gallon)
Daily flow rate (gallons/day); gallons per year calculated by
multiplying the flow in gallons per day by the number of operating
days per year
Number of tanks cleaned per day; the number of tanks cleaned per
year was calculated by multiplying the number of tanks cleaned per
day by the number of operating days per year
11-5
-------
Section 11.0 - Pollutant Reduction Estimates
Certain pollutants were not detected above the sample detection limits in some
wastewater samples. Because both nondetect and detect results represent the variability of
pollutant concentrations in TEC wastewater, both results were included in calculating PNPLs.
For nondetect results, EPA assumed the pollutant concentration was equal to the sample
detection limit for that pollutant. EPA based this assumption on the expectation that the
pollutant was present in TEC wastewater, albeit at a concentration less than the sample detection
limit.
If duplicate samples or multiple grab samples (e.g., for HEM and SGT-HEM
analyses) of untreated wastewater were collected at a facility, EPA calculated the daily average
PNPL for each pollutant at that facility using the following equation:
N
where:
J
N
DL: =
j=Sample 1
~
(2)
Daily average pollutant loading generated per tank cleaned
(milligram/tank or microgram/tank, depending on the pollutant)
Pollutant i in waste stream
Pollutant loading generated per tank cleaned for sample
(milligram/tank or microgram/tank, depending on the pollutant)
Counter for number of duplicate or grab samples collected
Number of duplicate or grab samples collected
In cases where EPA collected samples from the same sampling point at the same
facility over multiple sampling days, EPA calculated a facility average PNPL using the following
equation:
DayN
FLi =
j=Day
N
(3)
11-6
-------
where:
N
Section 11.0 - Pollutant Reduction Estimates
Facility-specific average pollutant loading generated per tank
cleaned (milligram/tank or microgram/tank, depending on the
pollutant)
Pollutant i in waste stream
Pollutant loading generated per tank cleaned on Day j
(milligram/tank or microgram/tank, depending on the pollutant)
Daily average pollutant loading generated per tank cleaned on Day
j (milligram/tank or microgram/tank, depending on the pollutant)
Counter for number of days of sampling at a specific facility
Number of sampling days at a specific facility
Finally, EPA calculated average subcategory PNPLs by averaging the applicable
average facility-specific PNPLs as shown in the equation below. This methodology ensured that
pollutant data from each sampled facility was weighted equally in calculating the subcategory
PNPLs, regardless of the number of wastewater samples collected at each facility.
Facility N
where:
PNPLj =
N
PNPL. = j=Facilityl
1 N
(4)
Subcategory average production normalized pollutant loading
generated per tank cleaned (milligram/tank or microgram/tank,
depending on the pollutant)
Pollutant i in waste stream
Facility-specific average pollutant loading generated per tank
cleaned (milligram/tank or microgram/tank, depending on the
pollutant)
Counter for number of facilities sampled for a specific subcategory
Number of facilities sampled for a specific subcategory
11-7
-------
Section 11.0 - Pollutant Reduction Estimates
Additional information on the calculation of untreated PNPLs for each TECI
subcategory can be found in reference 1.
11.3
Multiple Subcatesorv Facility PNPLs
Some modeled facilities have production in more than one subcategory. For
example, a facility that cleans both tank trucks and rail tank cars that last transported chemical
cargos has production in both the Truck/Chemical and the Rail/Chemical Subcategories. To
simplify compliance cost and pollutant reduction estimates, EPA assigned each multiple
subcategory facility to a single primary subcategory. As a result of this simplification, EPA
modeled control of all TEC wastewater generated by multiple subcategory facilities using the
technology options evaluated for the facility's primary subcategory (rather than segregating and
treating the waste streams in separate wastewater treatment systems). EPA accounted for
untreated TEC wastewater pollutant loadings from other secondary subcategories by using the
PNPLs from secondary subcategory wastewater for those pollutants that were also pollutants
effectively removed for the primary subcategory. Estimation of pollutant reductions for multiple
subcategory facilities is described in greater detail in the rulemaking record.
11.4
TECI Untreated Pollutant Loadings
TECI untreated pollutant loadings represent the industry pollutant loadings before
accounting for pollutant removal by treatment technologies already in place at TEC facilities.
The Agency estimated untreated pollutant loadings generated by model facilities using the
untreated PNPLs developed for each stream type (i.e., PNPLs for tank trucks cleaned at
Truck/Chemical Subcategory facilities, etc.) and the number of tanks cleaned per year at each
model facility.
The model facility untreated wastewater pollutant loadings were then weighted
using statistically-derived weighting factors for each model facility. The weighted model facility
loadings were then summed to estimate untreated pollutant loadings for each subcategory and the
11-8
-------
Section 11.0 - Pollutant Reduction Estimates
entire TECI. Tables 11-1 through 11-15 present total industry untreated pollutant loadings by
pollutant for each subcategory.
11.5
TECI Baseline Pollutant Loadings
TECI baseline loadings represent the pollutant loadings currently discharged by
TEC facilities to U.S. surface waters or to POTWs after accounting for removal of pollutants by
existing on-site treatment. Section 10.0 describes the assessment of the treatment in place at
each model TEC facility. The model facility baseline pollutant loadings were calculated as the
difference between the model facility untreated wastewater pollutant loadings calculated as
described in Section 11.4 and the pollutant reductions achieved by treatment in place at each
TECI model facility.
The model facility baseline pollutant loadings were then weighted using the
statistically-derived weighting factors for each model facility. The weighted model facility
baseline loadings were then summed to estimate the baseline pollutant loadings for the entire
TECI. Tables 11-1 through 11-15 present the total industry baseline pollutant loadings by
pollutant for each subcategory.
11.6
TECI Post-Compliance Pollutant Loadings by Regulatory
Option
TECI post-compliance pollutant loadings represent the pollutant loadings that
would be discharged following implementation of the regulatory options. Model facility post-
compliance pollutant loadings were calculated using the following steps. First, model facility
baseline pollutant loadings were calculated as described in Section 11.5. Second, these loadings
were converted to baseline pollutant effluent concentrations for each model facility using the
baseline pollutant loadings, the facility process wastewater flow, and a conversion factor. Third,
the baseline pollutant effluent concentrations were compared to the effluent concentrations
achieved by each regulatory option. Finally, the lower of these concentrations was used along
11-9
-------
Section 11.0 - Pollutant Reduction Estimates
with the facility flow and an appropriate conversion factor to determine the model facility post-
compliance pollutant loadings for each regulatory option.
The model facility post-compliance pollutant loadings were then weighted using
the statistically-derived weighting factors for each model facility. The weighted model facility
post-compliance pollutant loadings were then summed to estimate the post-compliance pollutant
loadings for the entire TECI. Tables 11-1 through 11-15 present the total industry post-
compliance pollutant loadings by pollutant for each subcategory.
11.7
TECI Pollutant Loading Reduction Estimates
The pollutant loading reductions represent the pollutant removal achieved through
implementation of the regulatory options. Therefore, the pollutant loading reductions are the
difference between the post-compliance pollutant loadings and the baseline pollutant loadings for
each regulatory option considered. Estimated pollutant loading reductions achieved by each
regulatory option are described below by regulation and are shown in Tables 11-1 through 11-15.
11.7.1
BPT
The following table summarizes pollutant loading reductions for each TECI
regulatory option considered for BPT. Note that EPA did not develop or evaluate BPT options
for the Truck/Petroleum and Rail/Petroleum Subcategories because the Agency is not aware of
any direct discharging facilities in these subcategories. In addition, although EPA developed a
BPT option for the Truck/Hopper and Rail/Hopper Subcategories, pollutant reductions for this
option were not estimated for these subcategories because none of the model facilities in these
subcategories are direct dischargers.
11-10
-------
Section 11.0 - Pollutant Reduction Estimates
•• "iSubcategory
rruck/Chemical
Rail/Chemical
Barge/Chemical &
Truck/Food,
Rail/Food and
Jarge/Food
Barge/Hopper
Option '
1
2
.1
2
3
1
2
1
2
1
su
"i^';
'EODgia^^-f
20
20
1.7
1.7
1.7
490,000
600,000
0(b)
0(b)
NC
~~^'i - ' - : - *-'"
<-V'^ ',,' ' " , *,\
A '<•••-•'' f j ^
i^B&i&iidffig?'
^3R.eduction ''s '
? '"'(pffaadsfyealcy '
75
75
10
2,200
2,400
750,000
860,000
0(b)
0(b)
8,600
^ .,
j CHI and Grrease '
(HEM) Loading
' - Seduction '
^(pounds/year;)
240,000
240,000
540
610
610
5,100,000
5,100,000
0(b)
0(b)
NC '
' '-*s^ \f f^^
^,Pnority;- ^
, •, Pollutant %
- Loading
• Reduction •
(pomids/year) -
5
5
2.1
4.8
5
27,000
29,000
0(b)
0(b)
1.8
Nbnconyentiona
- > %oHufa^ ;t
^ '•"s.lboaOiiis s ^
Reduction ,^
t >(jpoiinds^yeaE)€
'
-------
Section 11.0 - Pollutant Reduction Estimates
11.7.3
BAT
BAT options developed and evaluated by EPA are identical to those developed
and evaluated for BPT. Therefore, BAT pollutant loading reductions are identical to the BPT
pollutant loading reductions for priority and nonconventional pollutants discussed in
Section 11.7.1.
11.7.4
PSES
The following table summarizes pollutant loading reductions for each TECI
regulatory option considered for PSES.
Subcategory
Truck/Chemical
Rail/Chemical
Barge/Chemical & Petroleum
Truck/Food
Rail/Food
Barge/Food
Truck/Petroleum
Rail/Petroleum
T^uck/Hopper
Option
1
2
1
2.
3
1
2
3
1
2
1
2
1
2
1
2
1
2
1
Priority Pollutant Loading
Seduction {pounds/year)
56,000
97,000
370
390
1,030
1,200
3,500
3,500
5.5
470,000
0
130,000
0
890
NC
410
NC
<1
1.4
Nonconventional Pollutant Loading
Reduction (pounds/year) (a)
107,000
620,000
23,000
33,000
14,000
10,200
17,000
17,000
2,300
120,000,000
0
33,700,000
0
222,000
NC
7,500
NC
27
2,200
11-12
-------
Section 11.0 - Pollutant Reduction Estimates
Subcategory '
Rail/Hopper •
Barge/Hopper
> *: V
"Option
1
1
,JMoR^olM^I*ading '
RediiefloB (pounds/year)
. 0
<1
NonconyentiorialPofluta^t Loading '*
"s < Reduction (pounds/year) (a)
0
250
(a) The loading reductions presented exclude reduction of COD, TDS, TOC, and TPH.
NC - Pollutant loading reductions not calculated because the regulatory options were not fully evaluated by EPA (see Section
9.0).
Tables 11-5 through 11-15 present the PSES pollutant loading reduction estimates
for all pollutants and regulatory options for the following subcategories:
Truck/Chemical Subcategory (Table 11-5);
Rail/Chemical Subcategory (Table 11-6);
Barge/Chemical & Petroleum Subcategory (Table 11-7);
Truck/Food Subcategory (Table 11-8);
Rail/Food Subcategory (Table 11-9);
Barge/Food Subcategory (Table 11-10);
Truck/Petroleum Subcategory (Table 11-11);
Rail/Petroleum Subcategory (Table 11-12);
Truck/Hopper Subcategory (Table 11-13);
Rail/Hopper Subcategory (Table 11-14); and
Barge/Hopper Subcategory (Table 11-15).
11.8
References1
1.
Eastern Research Group, Inc. Development of Transportation Equipment
Cleaning Industry Production Normalized Pollutant Loadings. Memorandum
from Grace Kitzmiller, Eastern Research Group, Inc. to the TECI Rulemaking
Record. May 6, 1998 (DCNT09981).
•l For those references included in the administrative record supporting the proposed TECI rulemaking, the
document control number (DCN) is included in parentheses at the end of the reference.
11-13
-------
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11-31
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8
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05
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11-32
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11-33
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11-35
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1
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vo
00
CO
CO
o
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to
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10
>o
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CO
00
10
VO
VO
1
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V
V
V
V
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1—4
V
V
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V
1836755
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oo
ON
V
V
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1—4
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CO
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1
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V
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V
V
V
V
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CO
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CO
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11-36
-------
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12
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0
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V
V
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V
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34643464
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V
V
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V
V
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43121433
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CO
cs
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V
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V
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V
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t— <
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V
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1582098
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5
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11-37
-------
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V
V
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V
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V
V
V
V
V
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V
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V
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V
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V
V
V
V
V
V
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1-H
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V
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V
V
V
V
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1-H
V
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1031078
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V
V
V
V
V
V
1-H
V
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7421934
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T-H
V
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V
V
V
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00
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CO
CO
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1
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11-38
-------
1
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ON
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ON
ON
vo
ON
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ON
00
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ON
1
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1
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11-40
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11-41
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ON
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o
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vo
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V
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V
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ON
3
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1
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11-42
-------
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o
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11-46
-------
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o
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o
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o
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§
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o
o
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o
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o
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o
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o
o
0
o
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1
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o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
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1
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11-47
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11-48
-------
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1
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ON
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£
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o
>o
en
o
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en
o
en
vo
ON
oo
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en
1
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oo
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oo
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^.
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ON
ON
F-
|| Magnesium
0,
ON
O
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ON
ON
>D
VO
ON
ON
§
Manganese
0,
en
o
CM
en
01
en
t-~
00
ON
§
|| Molybdenum
11-49
-------
I
rt *• B SS
ii!ji
Option 1
Wastewater
Pollutant
Loading
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K
IP
b
•1
Z
a
£
0-
ci
0
cl
CN
7723140
Phosphorus
—
0
*— «
»— «
7440097
1
0
8
O
i— (
7440235
1
o
CO
0
*— 1
7704349
Ui
1
CO
V
0
V
V
7440257
1 Tantalum
•n.
0
in
>n
7440315
_e
V
0
V
V
a
to
1 Titanium
V
o
V
V
7440337
| Tungsten
V
0
V
V
7440622
|| Vanadium
V
0
V
V
7440677
Zirconium
§
in
0
o
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o
in
1
>5
1
IB
|| TOTAL Nonconven
-
1
Gfl
1
j
01
0
«.
«
2027170
JH
1 2-Isopropylnaphthale
01
o
01
ol
r- *
2-Methylnaphthalene
oo
0
oo
00
I
« Acetone
CO
0
CO
CO
CO
vo
|| Benzoic Acid
V
o
V
V
<3\
s
V
o
V
V
00
O
I Diphenyl Ether
— '
o
T— (
r— t
| Hexanoic Acid
o
CO
CO
CO
oo
CO
T— 4
I
e
f-
o
CO
CO
1
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!
f^
o
r.
^
1-H
0
I
B
1 Methyl Isobutyl Keto
»H
O
rH
1— 1
CO
T— (
g
s
I n-Hexacosane
11-50
-------
I
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i
I
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I
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1,1 !ȣ
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111 ft
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1
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f— 1
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0
>n
0
0
o
VI
1
cn
o
C
T— I
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VO
r— 1
cn
cn
|l n-Octadecane
cn
0
vo
cn
t-
cn
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VO
^
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cn
vo
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1
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1
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V
O
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V
vo
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VO
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cn
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5
o
^
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vo
1
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a
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o
VO
VO
1
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o
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oo
0
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136777612
1
o
vo
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VO
06
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00
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T-H
o
(0
g
Pentamethylben
01
o
01
fs
01
20324338
&
1
8
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cn
CO
O
cn
CO
cn
oo
i
00
o
Vinyl Acetate
vo
iH
O
i-T
o
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6
1
£
|| TOTAL Nonco
11-51 .
-------
0)
c
6
I
S
"8-
I
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Other Nonconv
en
CO
O
O
en
oo
O
en
oo
7664417
1
Ammonia as Ni
oo
o
VD
OO
VO
OO
16984488
Fluoride
S-
0
0
S
1
1
o
Nonconventi
|| TOTAL Other
snrejniio.1
| Other Priority
V
o
V
»— t
V
1
| Total Cyanide
V
o
V
l-H
V
fl
3
a
Priority Poll
1 TOTAL Other
1
&
1
s
V
o
V
V
7440360
|| Antimony
V
o
V
V
7440382
i
V
o
t— 4
V
V
r-
r— t
t-
Beryllium
V
0
V
V
7440439
Cadmium
p
0
o
en
O
en
7440473
1 Chromium
0
'
1
£•
I
£
11-52
-------
1
I
o
^-^
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1
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^^^
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1
1
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1
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CN
^
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s
\o
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o\
CO
o
o\
CO
o\
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1
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4-Chloro-3-Methylphe
o
CO
O
0
CO
0
CO
CM
S
Benzene
V
0
V
V
t-
*— i
00
i
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Bis (2-ethylhexyl) Phtl
CO
IN
0
S
a
••*
Ethylbenzene
«
^"
o
o\
^
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CM
O
Methylene Chloride
P-;
^
o
^
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CO
§
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1
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0
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O
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1
1
l-H
cs
Q
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oi
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1
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§
o
8
•
t— i
CO
00
CO
CO
o
Toluene
•**
o
"1
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S
vo
o
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Trichloroethylene
i
0
§
"
!
S
TOTAL Priority Orgi
ti
c
=3
G
S
s
s .
o
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j
S
=3
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§
£
9
GO
•S
I
I
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1
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S
o.
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&
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jllJfl
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T||j| g,^
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I
£
:-4-»-
..-.-• J
.' >*:-
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o
VO
«n
*
•a
5
«
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| 5-Day Biochemical Oxyg
90
O
CO
t-4
*
Oil and Grease (HEM)
0
*
| Total Suspended Solids
i
I
i
oo
CO
o
oo
CO
CO
2
| Chemical Oxygen Deman
CO
o
CO
o\
*
|| Total Dissolved Solids
o
*
1 Total Organic Carbon
V
0
V
V
*
5C
f;;
CO
c
Total Petroleum Hydroca!
i
i
•a
{
e
V
0
V
V
7429905 .
Aluminum
V
o
V
V
7440393
•c
c?
n
V
o
V
V
7440428
1
V
o
V
V
7440702
|| Calcium
V
o
V
V
7440484
•4-J
I
V
0
V
V
18540299
|| Hexavalent Chromium
CO
o
co
CO
7439896
c
V
O
V
V
7439954
1 Magnesium
V
o
V
V
| 7439965
Manganese
V
o
V
V
| 7439987
Molybdenum
V
o
V
V
| 7723140
((Phosphorus
11-54
-------
o
M
IS
•*-» C4 •£
!I!fi
jilfi
4"»^jS twt CS ^Q
-
in
z
•C8
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•s
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§
I
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V
0
V
V
2027170
tu
c
|| 2-Isopropylnaphthale
V
0
V
V
vo
VI
|| 2-Methylnaphthalene
o
OV
C5
vo
|| Acetone
V
o
V
V
S?
CO
VO
|| Benzoic Acid
V
o
V
V
Ov
I
S
V
o
V
V
00
S
0
1 Diphenyl Ether
V
0
V
V
T— 1
1 HexanoicAcid
V
0
V
V
S3
1
i
V
0
V
V
00
§
£
"?,
"?,
1
V
O
V
V
o
oo
O
o
IS
1 Methyl Isobutyl Keto
V
o
V
V
CO
S
0
CO
vo
1 n-Hexacosane
V
o
V
V
oo
1 n-Decane
V
o
V
V
1
CO
VO
I
c
11-55
-------
&
O
U
n
Octadecane
c
V
o
V
V
oo
1
Bicosane
c
V
o
V
V
en
vo
Tetracosane
a
V
o
V
V
a
a
8
Tetradecane
c
V
0
V
V
VO
oo
g
en
vo
Triacontane
a
V
o
V
V
en
vo
1
Hexadecane
c
V
o
V
V
1
1—4
Dodecane
a
V
o
V
V
o
t-~
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Docosane
a
V
o
V
V
136777612
§
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f
o
V
o
V
V
o
1
1
u
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V
o
V
V
20324338
ft
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U
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1
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t-
V
o
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V
1
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>
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1
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1
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OTAL Other
H
11-56
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-------
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1
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1
fin
1
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o
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V
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11-57
-------
01
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l||li
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1
a
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S
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V
O
V
.
V
1
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V
o
V
V
r-
o
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o
I Methylene Chi
V
0
V
V
8
5!
|| Naphthalene
V
o
V
V
§
2
1
04
V
o
V
V
1—4
S
>•*
|| Tetrachloroeth
V
o
V
V
CO
oo
oo
2
|| Toluene
V
o
V
V
o
c
S
I Trichloroethyh
V
o
V
V
"2
1
,i;
£"
,^j
|| TOTAL Prior
I
1
o
u
3
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1
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§
I
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g
^
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11-58
-------
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1
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o
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1
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'
;
;
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1
I
s
P3
C3
S
oo
rf
CO
§
VO
c~
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Chemical Oxygen De
--
^ '
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^
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3
1
oo
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T-H
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1— <
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o
o
o
s
s
o
en
1
en
I
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o
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s
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o
o
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1
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en
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^
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o
1
e
t»f
o
9
0
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<^'
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I
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TOTAL NonconvenI
-
-
•" '
s
ss
Jx
f
s
*
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\
V
V
T— <
V
V
1-H
S
s
1
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t-H
V
r—t
en
VI
1-1
I
1 Chromium
CS
2
o
en
vo
VO
VO
o
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Tf
TH
t^
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TT
in
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&b
1
3
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11-59
-------
T-t
CD
3
S
••
2
>
rt«§
stl.»«
lllll
1 1 a g>—
ei
z
1
S3
S
|| Bulk : Gonventldiuils ;
o
o
vo
o
VO
o
s
1 Total Suspended Solids
1
1
;"3r
O
VO
«
8
.a
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1 Chemical Oxygen Demai
*
1
o
J
o
in
JQ
&
7429905
|| Aluminum
0
en
en
en
S
1—4
7440702
|| Calcium
0
o
oo
o
CO
VO
en
7439896
1
0
1— 1
V
V
!2
7439965
|| Manganese
o
»— t
V
V
V
7440326
1 Titanium
o
9
,
I
CO
3
i
| TOTAL Nonconventior
-
i»
1
£
O
T-H
V
*— I
V
V
7440417
1
u
0
V
V
1—4
V
7440473
Chromium
o
V
1—4
V
V
• 7440666
M
H
e
V
V
TH
I TOTAL Priority Metal
11-60
-------
1
PH
O
8
co
i
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a
0
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1
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in
o
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8
in
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i~^*
CO
2
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Total Suspended S
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^
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f
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1
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Chemical Oxygen
\ '
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\ : :
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^
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f
1
1
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g
o\
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o
o
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0\
O
O
o
g
s
p~
0
5
Calcium
o
cs
cs
§
O
en
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^
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03
0\
t-
lo
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Manganese
T— <
V
»—i
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V
^
8
r.
Titanium
1
1
1
en
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TOTAL Nonconv
''- ,
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11-61
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-------
Section 12.0 - Non-Water Quality Impacts
12.0
NON-WATER QUALITY IMPACTS
Sections 304(b) and 306 of the Clean Water Act require EPA to consider the non-
water quality environmental impacts of effluent limitations guidelines and standards. Therefore,
EPA evaluated the effects of the Transportation Equipment Cleaning Industry (TECI) proposed
regulatory options on energy consumption, air pollution, and solid waste generation. Sections
12.1 through 12.3 discuss these impacts and Section 12.4 lists references for this section.
Reference 1 summarizes the results of these analyses. In addition to these non-water quality
impacts, EPA considered the impacts of the proposed rule on noise pollution and water and
chemical use and determined these impacts to be negligible.
12.1
Energy Impacts
Energy impacts resulting from the proposed regulatory options include energy
requirements to operate wastewater treatment equipment such as aerators, pumps, and mixers.
The Agency evaluated the annual increase in electrical power consumption for each regulatory
option relative to the estimated current industry consumption for wastewater treatment.
Flow reduction technologies (a component of the proposed regulatory options)
reduce energy requirements by reducing the number of operating hours per day and/or operating
days per year for wastewater treatment equipment currently operated by the TECI. For some-
regulatory options, energy savings resulting from flow reduction exceed requirements for
operation of additional wastewater treatment equipment, resulting in a net energy savings for
these options.
Based on EPA's proposed options (see Section 9.0), the Agency estimates a net
increase in electricity use for the TECI as a result of the proposed rale would be approximately 6
million kilowatt hours per year. In 1990, the total U.S. industrial electrical energy purchase was
approximately 756 billion kilowatt hours (2). EPA's proposed options would increase U.S.
industrial electrical energy purchase by 0.0008 percent. Therefore, the Agency concludes that the
12-1
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Section 12.0 - Non-Water Quality Impacts
effluent pollutant reduction benefits from the proposed technology options exceed the potential
adverse effects from the estimated increase in energy consumption.
12.2
Air Emission Impacts
Transportation equipment cleaning (TEC) facilities generate volatile and
semivolatile organic pollutants, some of which are also on the list of Hazardous Air Pollutants in
Title 3 of the Clean Air Act Amendments of 1990. Air emissions from TEC facilities occur at
several stages of the equipment cleaning process. Prior to cleaning, tanks which have transported
volatile materials may be opened and vented with or without steam in a process called gas
freeing. At some facilities, tanks are filled to capacity with water to displace vapors to the
atmosphere or to a combustion device. Tanks are then cleaned, typically using either heated
cleaning solutions or hot water. For recirculated cleaning solutions, pollutants may be volatilized
from heated cleaning solution storage tanks. For TEC wastewater, pollutants may volatilize as
the wastewater falls onto the cleaning bay floor, flows to floor drains and collection sumps, and
conveys to wastewater treatment. TEC wastewater typically passes through treatment units open
to the atmosphere where further pollutant volatilization may occur.
EPA performed a WATERS (3) model analysis to determine the quantity of air
emissions that would result from the proposed treatment technology options. Reference 4
describes EPA's model analysis in detail. EPA estimates that the maximum increase in air
emissions would be 148,000 kilograms per year. EPA therefore concluded that the incremental
air emissions resulting from the proposed wastewater treatment technology options are a small
percentage of the total air emissions generated by TEC facilities.
12.3
Solid Waste Impacts
Solid waste impacts resulting from the proposed regulatory options include
additional solid wastes generated by wastewater treatment technologies. These solid wastes
consist of wastewater treatment residuals, including sludge, waste oil, spent activated carbon, and
12-2
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Section 12.0 - Non-Water Quality Impacts
spent organo-clay. These impacts are discussed below in Sections 12.3.1 through 12.3.4
respectively.
12.3.1
Wastewater Treatment Sludge
Wastewater treatment sludge is generated in two forms: dewatered sludge (or
filter cake) generated by a filter press and/or wet sludge generated by treatment units such as
oil/water separators, chemical precipitation/coagulation, coagulation/clarification, dissolved air
flotation, and biological treatment. The Agency evaluated impacts of the increased sludge
generation for each regulatory option relative to the estimated current industry wastewater
treatment sludge generation.
Many facilities that currently operate wastewater treatment systems do not
dewater wastewater treatment sludge. Storage, transportation, and disposal of relatively large
volumes of undewatered sludge that would be generated after implementing the TECI regulatory
options is less cost-effective than dewatering sludge on site and disposing the greatly reduced
volume of resulting filter cake. However, following implementation of these regulations, EPA
believes TEC facilities would install sludge dewatering equipment to handle increases in sludge
generation. For these reasons, EPA estimates net decreases in the volume of wet sludge
generated by the industry and net increases in the volume of dry sludge generated by the industry.
Based on responses to the Detailed Questionnaire, most TEC facilities currently
dispose wastewater treatment sludge in nonhazardous landfills. Sludge characterization data
provided by industry and collected during EPA's TECI sampling program confirm that
wastewater treatment sludge generated by the TECI is nonhazardous as determined by the
Toxicity Characteristic Rule under the Resource Conservation and Recovery Act. Compliance
cost estimates for the TECI regulatory options are based on disposal of wastewater treatment
sludge in nonhazardous waste landfills.
12-3
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Section 12.0 - Non-Water Quality Impacts
The Agency concludes that the effluent benefits and the reductions in wet sludge
from the proposed technology options exceed the potential adverse effects from the estimated
increase in wastewater treatment sludge generation.
12.3.2
Waste Oil
EPA estimates that compliance with this regulation will result in an increase in
waste oil generation at TEC sites based on removal of oil from wastewater via oil/water
separation. The Agency evaluated the impacts of the increased waste oil generation for each
regulatory option relative to the estimated current industry waste oil generation. The increase in
waste oil generation is attributed to the removal of oil from TEC wastewaters prior to discharge
to publicly-owned treatment works or surface waters. This increase reflects a transfer of oil from
the wastewater to a more concentrated waste oil, and does not reflect an increase in overall oil
generation at TEC sites.
EPA assumes, based on responses to the Detailed Questionnaire, that waste oil
will be disposed via oil reclamation or fuels blending on or off site. Therefore, the Agency does
not estimate any adverse effects from increase waste oil generation.
12.3.3 Spent Activated Carbon
Spent activated carbon is generated by the following regulatory options:
Truck/Chemical Subcategory - BPT Option 2;
Truck/Chemical Subcategory - PSES Option 2;
• Rail/Chemical Subcategory - BPT Option 3;
• Rail/Chemical Subcategory - PSES Option 3;
• Truck/Petroleum Subcategory - PSES Option 2; and
• Rail/Petroleum Subcategory - PSES Option 2.
Treatment of TEC wastewater via these technology options will generate 16,940,000 pounds
(8,470 tons) annually of spent activated carbon. EPA assumes that the spent activated carbon
12-4
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Section 12.0 - Non-Water Quality Impacts
will be sent off site for regeneration rather than disposed of as a waste. Possible air emissions
during regeneration are minimal. Therefore, the Agency does not estimate any adverse effects
from activated carbon treatment technologies.
12.3.4
Spent Organo-Clay
Spent organo-clay is generated by the following options:
• Rail/Chemical Subcategory - BPT Option 3; and
• Rail/Chemical Subcategory - PSES Option 3.
Treatment of TEC wastewater via these technology options will generate 236,000 pounds (118
tons) annually of spent organo-clay. EPA assumes that the spent organo-clay will be disposed as
a nonhazardous waste. The Agency concludes that the effluent benefits from the proposed
technology options exceed any potential adverse effects from the generation and disposal of spent
organo-clay.
12.4
References1
1.
2.
3.
4.
Eastern Research Group, Inc. Summary of the Results of Non-Water Quality
Impacts Analyses. Memorandum from Michelle DeCaire, Eastern Research
Group, Inc. to the TECI Rulemaking Record. May 26, 1998 (DCN T10300).
U.S. Department of Commerce. 1990 Annual Survey of Manufacturers, Statistics
for Industry Groups and Industries. M90 (AS)-l, March 1992.
U.S. Environmental Protection Agency, Office of Air Quality Planning and
Standards. Wastewater Treatment Compound Property Processor and Air
Emissions Estimator (WATERS), Version 4.0. U.S. Environmental Protection
Agency, Research Triangle Park, NC, May 1, 1995.
Eastern Research Group, Inc. WATERS Analysis of Air Emission Impacts of
TECI Regulatory Options. May 1998 (DCN T04660).
1 For those references included in the administrative record supporting the proposed TECI rulemaking, the
document control number (DCN) is included in parentheses at the end of the reference.
12-5
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-------
Section 13.0 - Implementation of Proposed Effluent Limitations Guidelines and Standards
13.0
IMPLEMENTATION OF PROPOSED EFFLUENT
LIMITATIONS GUIDELINES AND STANDARDS
Using annual average production information supplied by the facility and the
effluent guidelines, the permitting authority will establish numerical discharge limitations for the
facility and specify monitoring and reporting requirements. For direct discharging facilities, the
effluent limitation guidelines are applicable to the final effluent discharged to U.S. surface
waters. For indirect discharging facilities, pretreatment standards are applicable to the final
effluent discharged to a publicly-owned treatment works.
For the proposed regulations, the production rate is defined as the number of tanks
cleaned annually divided by the number of days that the facility performs transportation
equipment cleaning (TEC) operations during that year. Facility production in each subcategory is
used with the subcategory production normalized mass effluent limitations guidelines and
standards to calculate facility-specific permit limitations. Permitting authorities must determine
production based on past production practices, present trends, or committed growth. Permitting
authorities have typically used average production over the past five years to represent past
production practices. In certain circumstances, however, evaluating production for the past five
years may not be appropriate. For example, if a facility significantly increased the number of
tanks cleaned within the past two years, permitting authorities should average the production for
only the past two years.
EPA has structured the proposed regulation in a building-block approach. This
means that the applicable permit limitations for facilities with production in more than one
subcategory will be the sum of the mass loadings based upon production in each subcategory and
the respective subcategory effluent limitations guidelines. Examples of facilities that fall under
one and more than one subcategory are provided below.
13-1
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Section 13.0 - Implementation of Proposed Effluent limitations Guidelines and Standards
Examolel:
Facility 1 cleaned 1,000 tank trucks in 1996. 1996 was the highest production
year in the past five years and during that year the facility performed TEC operations 250 days.
Of these 1,000 tanks, 500 (50%) last transported petroleum cargos, 300 (30%) last transported
food grade cargos, and 200 (20%) last transported chemical cargos. From the definitions
provided in Section 5.2, all production at facility 1 falls under Subcategory A - Truck/Chemical
(i.e., facilities that clean tank trucks and intermodal tank containers where 10% or more of the
total tanks cleaned at that facility in an average year contained chemical cargos). The production
rate for the purpose of calculating limitations is:
PROD
PRODRATE =
OPDAYS
(1)
where:
PRODRATE =
PROD
OPDAYS
Production rate, tanks/day
Highest number of tanks cleaned annually in the past five
. years, tanks/year
Number of TEC operating days in the calendar year used
for PROD, days
Using Equation 1:
1.000 tanks/year
250 days/year
= 4 tanks/day
As an example, from Table 2-4, the BPT effluent guidelines for biochemical oxygen demand
(BOD5) and total suspended solids (TSS) for the Truck/Chemical Subcategory are:
Subcategory
"Ruck/Chemical
Daily Maximum
(grams/tank.)
BODS
145
TSS
281
Monthly Average '',
(grams/tank) ,
BOB5
67.6
TSS
115
13-2
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Section 13.0 - Implementation of Proposed Effluent Limitations Guidelines and Standards
Permit limitations are calculated as follows.
Daily Maximum BOD5:
145 grams/tank x 4 tanks/day = 580 grams BOD5/day
Daily Maximum TSS:
281 grams/tank x 4 tanks/day = 1,124 grams TSS/day
Monthly Average BOD5:
67.6 grams/tank x 4 tanks/day = 270.4 grams BOD5/day
Monthly Average TSS:
115 grams/tank x 4 tanks/day = 460 grams TSS/day
Example 2:
Facility 2 cleaned 1,000 rail tank cars and 500 tank barges in 1996. 1996 was the
highest production year in the past five years and during that year the facility performed TEC
operations 250 days. Of the 1,000 rail tank cars, 950 (95%) last transported food grade cargos
and 50 (5%) last transported chemical cargos. Of the 500 tank barges, 300 (60%) last transported
chemical cargos and 200 (40%) last transported petroleum cargos. From the definitions provided
in Section 5.2, production at facility 2 falls under both Subcategory E - Rail/Food (i.e., facilities
that clean rail tank cars where 10% or more of the total tanks cleaned at that facility in an average
year contained food grade cargos, so long as that facility does not clean 10% or more of tanks
containing chemical cargos) and Subcategory C - Barge/Chemical & Petroleum (i.e., facilities
that clean tank barges or ocean/sea tankers where 10% or more of the total tanks cleaned at that
facility in an average year contained chemical and/or petroleum cargos).
13-3
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Section 13.0 - Implementation of Proposed Effluent Limitations Guidelines and Standards
Using Equation 1, the production rate for the purpose of calculating limitations is:
1,000 tanks/year
250 days/year
= 4 tanks / day Rail / Food Subcategory production
500 tanks/year _ 2 tanks / day B arge / Chemical & Petroleum
250 days/year = Subcategory production
As an example, from Tables 2-6 and 2-8, respectively, the BPT effluent guidelines for BOD5 and
TSS for the Barge/Chemical & Petroleum and Rail/Food Subcategories are:
Subcategory
Barge/Chemical & Petroleum
Rail/Food
Daily Maximum
(grams/tank)
BODS
18,300
945
TSS
9,540
3,830
- Monthly Average
(grams/tank)
B03>5
8,600
412
TSS
6,090
1,460
Permit limitations are calculated as follows.
Daily Maximum BOD5:
18,300 grams/tank x 2 tanks/day = 36,600 grams/day
945 grams/tank x 4 tanks/day = 3,780 grams/day
36,600 + 3,780 = 40,380 grams BOD5/day
Daily Maximum TSS:
9,540 grams/tank x 2 tanks/day = 19,080 grams/day
3,830 grams/tank x 4 tanks/day = 15,320 grams/day
19,080 + 15,320 = 34,400 grams TSS/day
13-4
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Section 13.0 - Implementation of Proposed Effluent Limitations Guidelines and Standards
Monthly Average BOD5:
8,600 grams/tank x 2 tanks/day = 17,200 grams/day
412 grams/tank x 4 tanks/day = 1,648 grams/day
17,200 + 1,648 = 18,848 grams BOD5/day
Monthly Average TSS:
6,090 grams/tank x 2 tanks/day = 12,180 grams/day
1,460 grams/tank x 4 tanks/day = 5,840 grams/day
12,180 + 5,840 = 18,020 grams TSS/day
13-5
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Section 14.0 - Analytical Methods
14.0
ANALYTICAL METHODS
Section 304(h) of the Clean Water Act directs EPA to promulgate guidelines
establishing test procedures (analytical methods) for analyzing pollutants. These test procedures
are used to determine the presence and concentration of pollutants in wastewater, and are used
for filing applications and for compliance monitoring under the National Pollutant Discharge
Elimination System (NPDES) found at 40 CFR Parts 122.41(j)(4) and 122.21(g)(7), and for the
pretreatment program found at 40 CFR 403.7(d). Promulgation of these methods is intended to
standardize analytical methods within specific industrial categories and across industries.
EPA has promulgated analytical methods for monitoring pollutant discharges at
40 CR Part 136, and has promulgated methods for analytes specific to given industrial categories
at 40 CFR Parts 400 to 480. In addition to the methods developed by EPA and promulgated at
40 CFR Part 136, certain methods developed by others1 have been incorporated by reference into
40 CFR Part 136.
The analytical method for Oil and Grease and Total Petroleum Hydrocarbons
(TPH) is currently being revised to allow for the use of normal hexane in place of Freon 113, a
chlorofluorocarbon (CFC). Method 1664 will replace the current Oil and Grease Method 413.1
found in 40 CFR 136. In anticipation of promulgation of method 1664, data collected by EPA in
support of the TECI effluent guideline utilized method 1664. Therefore, all effluent limitations
proposed for Oil and Grease and TPH in this effluent guideline are to be measured by Method
1664.
For this proposed rule, EPA intends to regulate certain conventional, priority, and
nonconventional pollutants as identified in Section 7.0. The methods proposed for monitoring
the regulated pollutants are briefly discussed in the following sections:
1 For example, the American Public Health Association publishes Standard Methods for the Examination of Water
and Wastewater.
14-1
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Section 14.0 - Analytical Methods
Section 14.1: Semivolatile Organic Compounds;
Section 14.2: Metals;
Section 14.3: Hexane Extractable Material and Silica-Gel Treated Hexane
Extractable Material;
Section 14.4: Chemical Oxygen Demand;
Section 14.5: Biochemical Oxygen Demand; and
Section 14.6: Total Suspended Solids.
Section 14.7 lists the references used in this section.
14.1
Semivolatile Organic Compounds
Semivolatile organic compounds are analyzed by EPA Method 1625, Revision C
(1). In this method, samples are prepared by liquid-liquid extraction with methylene chloride in a
separator/ funnel or continuous liquid-liquid extractor. Separate acid and base/neutral extracts
are concentrated and analyzed by high resolution gas chromatography (HRGC) combined with
low resolution mass spectrometry (LRMS). The detection limit of the method is usually
dependent upon interferences rather than instrument limitations. With no interferences present,
minimum levels of 10,20, or 50 ug/L (ppb) can be achieved, depending upon the specific
compound.
14.2
Metals
Metals are analyzed by EPA Method 1620 (2). This method is a consolidation of
the EPA 200 series methods for the quantitative determination of 27 trace elements by
inductively coupled plasma (ICP) and graphite furnace atomic adsorption (GFAA), and
determination of mercury by cold vapor atomic absorption (CVAA). The method also provides a
semiquantitative ICP screen for 42 additional elements. The ICP technique measures atomic
14-2
-------
Section 14.0 - Analytical Methods
emissions by optical spectroscopy. GFAA measures the atomic absorption of a vaporized
sample, and CVAA measures the atomic absorption of mercury vapor. Method detection limits
(MDLs) are influenced by the sample matrix and interferences. With no interferences present,
compound-specific MDLs ranging from 0.1 to 75 Aig/L (ppb) can be achieved.
14.3
Hexane Extractable Material and Silica-Gel Treated Hexane
Extractable Material
Hexane Extractable Material (HEM; formerly known as oil and grease) and Silica-
Gel Treated Hexane Extractable Material (SGT-HEM; formerly known as total petroleum
hydrocarbons) are analyzed by EPA Method 1664 (3). In this method, a 1-L sample is acidified
and serially extracted three times with ri-hexane. The solvent is evaporated from the extract and
the HEM is weighed. For SGT-HEM analysis, the HEM is redissolved in n-hexane and an
amount of silica gel proportionate to the amount of HEM is added to the HEM solution to
remove adsorbable materials. The solution is filtered to remove the silica gel, the solvent is
evaporated, and the SGT-HEM is weighed. This method is capable of measuring HEM and
SGT-HEM in the range of 5 to 1,000 mg/L (ppm), and may be extended to higher concentrations
by analysis of a smaller sample volume..
14.4
Chemical Oxygen Demand
Chemical oxygen demand (COD) is a measure of the oxygen equivalent of the
organic matter in a sample that is susceptible to oxidation by a strong chemical oxidant. COD is
measured by EPA Methods 410.1, 410.2, 410.3, and 410.4 (4). These methods are incorporated
by reference into 40 CFR Part 136. In Methods 410.1,410.2, and 410.3, the organic and
oxidizable inorganic substances in an aqueous sample are oxidized by a solution of potassium
dichromate in sulfuric acid. The excess dichromate is titrated with standard ferrous ammonium
sulfate using orthophenanthroline ferrous complex (ferroin) as an indicator. Method 410.1
covers COD concentrations in the range of 50 - 2,000 mg/L (ppm) whereas Method 410.2 covers
14-3
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Section 14.0 - Analytical Methods
COD concentrations from 5 - 50 mg/L. Method 410.3 is intended for high levels of COD in
saline waters and is generally not applicable to TEC wastewaters.
In Method 410.4, COD is determined colorimetrically after digestion of the
organic matter in a sample using hot chromic acid solution. Note that highly colored samples
may interfere with the colorimetric determination of COD, in which case Methods 410.1 or 410.2
are used.
14.5
Biochemical Oxygen Demand
Biochemical oxygen demand (BOD5) is a measure of the relative oxygen
requirements of wastewaters, effluents, and polluted waters. BOD5 is measured by EPA Method
405.1 (4). The BOD5 test specified in this method is an empirical bioassay-type procedure that
measures dissolved oxygen consumed by microbial life while assimilating and oxidizing the
organic matter present. The standard test conditions include dark incubation at 20 °C for a five-
day period, and the reduction in dissolved oxygen concentration during this period yields a
measure of the biological oxygen demand. The practical minimum level of determination is 2
mg/L (ppm).
14.6
Total Suspended Solids
Total suspended solids (TSS) is measured using EPA Method 160.2 (4). In this
method, a well-mixed sample is filtered through a pre-weighed glass fiber filter. The filter is
dried to constant weight at 103 -105°C. The weight of material on the filter divided by the
sample volume is the amount of TSS. The practical range of the determination is 4 - 20,000
mg/L (ppm).
14-4
-------
14.7
Section 14.0 - Analytical Methods
References1
1.
2.
3.
4.
U.S. Environmental Protection Agency. Method 1625. Revision C: Semivolatile
Organic Compounds by Isotope Dilution GCMS. June 1989 (DCN T10220).
U.S. Environmental Protection Agency. Method 1620: Metals by Inductively
Coupled Plasma Atomic Emission Spectroscopv and Atomic Absorption
Spectroscopv. September 1989 (DCN T10224).
U.S. Environmental Protection Agency. Method 1664: n-Hexane Extractable
Material (HEM) and Silica Gel Treated n-Hexane Extractable Material (SGT-
HEM) by Extraction and Gravimetrv COil and Grease and Total Petroleum
Hydrocarbons). EPA-821-B-94-004b, April 1995. (DCN T10227).
U.S. Environmental Protection Agency. Methods for Chemical Analysis of Water
and Wastes. EPA-600/4-79-020, March 1983. (DCN T10228).
1 For those references included in the administrative record supporting the proposed TECI rulemaking, the
document control number (DCN) is included in parentheses at the end of the reference.
14-5
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-------
Section 15.0 - Glossary
15.0
GLOSSARY
Administrator - The Administrator of the U.S. Environmental Protection Agency.
Agency - The U.S. Environmental Protection Agency.
Ballast Water Treatment Facility - A facility which accepts for treatment ballast water or any
water which has contacted the interior of cargo spaces or tanks in an ocean/sea tanker.
Baseline Loadings - Pollutant loadings in TEC wastewater currently being discharged to
POTWs or U.S. surface waters. These loadings take into account wastewater treatment currently
in place at TEC facilities.
BAT - The best available technology economically achievable, as described in Sec. 304(b)(2) of
the Clean Water Act.
BCT - The best conventional pollutant control technology, as described in Sec. 304(b)(4) of the
Clean Water Act.
BMP - Best Management Practice. Section 304(e) of the Clean Water Act gives the
Administrator the authority to publish regulations to control plant site runoff, spills, or leaks,
sludge or waste disposal, and drainage from raw material storage.
BOD5 - Five day biochemical oxygen demand. A measure of biochemical decomposition of
organic matter in a water sample. It is determined by measuring the dissolved oxygen consumed
by microorganisms to oxidize the organic matter in a water sample under standard laboratory
conditions of.five days and 20° C, see Method 405.1. BOD5 is not related to the oxygen
requirements in chemical combustion.
BPT - The best practicable control technology currently available, as described in Sec. 304(b)(l)
of the Clean Water Act.
Builder/Leaser - A facility that manufactures and/or leases tank trucks, closed-top hopper tank
trucks, intermodal tank containers, rail tank cars, closed-top hopper rank tank cars, inland tank
barges, closed-top hopper barges, and/or ocean/sea tankers, and that cleans the interiors of these
tank after equipment has been placed in service.
CAA - Clean Air Act. The Air Pollution Prevention and Control Act (42 U.S.C. 7401 et. seq.),
as amended, inter alia, by the Clean Air Act Amendments of 1990 (Public Law 101-549, 104
Stat. 2399).
Cargo - Any chemical, material, or substance transported in a tank truck, closed-top hopper
truck, intermodal tank container, rail tank car, closed-top hopper rail car, inland tank barge,
15-1
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Section 15.0 - Glossary
closed-top inland hopper barge, ocean/sea tanker, or a similar tank that comes in direct contact
with the chemical, material, or substance. A cargo may also be referred to as a commodity.
Carrier-Operated (Carrier) - A facility that owns, operates, and cleans a tank fleet used to
transport commodities or cargos for other companies.
Centralized Waste Treater (CWT) - A facility that recycles, reclaims, or treats any hazardous
or nonhazardous industrial wastes received from off site and/or wastes generated on site by the
facility.
Centralized Waste Treaters Effluent Guideline - see proposed 40 CFR Part 437, 60 PR 5464,
January 27,1995.
CFR - Code of Federal Regulations, published by the U.S. Government Printing Office. A
codification of the general and permanent rules published in the Federal Register by the
Executive departments and agencies of the federal government.
Closed-Top Hopper Rail Car- A completely enclosed storage vessel pulled by a locomotive
that is used to transport dry bulk commodities or cargos over railway access lines. Closed-top
hopper rail cars are not designed or contracted to carry liquid commodities or cargos and are
typically used to transport grain, soybeans, soy meal, soda ash, fertilizer, plastic pellets, flour,
sugar, and similar commodities or cargos. The commodities or cargos transported come in
direct contact with the hopper interior. Closed-top hopper rail cars are typically divided into
three compartments, carry the same commodity or cargo in each compartment, and are generally
top loaded and bottom unloaded. The hatch covers on closed-top hopper rail cars are typically
longitudinal hatch covers or round manhole covers.
Closed-Top Hopper Truck - A motor-driven vehicle with a completely enclosed storage vessel
used to transport dry bulk commodities or cargos over roads and highways. Closed-top hopper
trucks are not designed or constructed to carry liquid commodities or cargos and are typically
used to transport grain, soybeans, soy meal, soda ash, fertilizer, plastic pellets, flour, sugar, and
similar commodities or cargos. The commodities or cargos transported come in direct contact
with the hopper interior. Closed-top hopper trucks are typically divided into three compartments,
cany the same commodity or cargo in each compartment, and are generally top loaded and
bottom unloaded. The hatch covers used on closed-top hopper trucks are typically longitudinal
hatch covers or round manhole covers. Closed-top hopper trucks are also commonly referred to
as dry bulk hoppers.
Closed-Top Hopper Barge - A self- or non-self-propelled vessel constructed or adapted
primarily to carry dry commodities or cargos in bulk through inland rivers and waterways, and
may occasionally carry commodities or cargos through oceans and seas when in transit from one
inland waterway to another. Closed-top inland hopper barges are not designed to carry liquid
commodities or cargos and are typically used to transport corn, wheat, soy beans, oats, soy meal,
animal pellets, and similar commodities or cargos. The commodities or cargos transported come
15-2
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Section 15.0 - Glossary
in direct contact with the hopper interior. The basic types of tops on closed-top inland hopper
barges are telescoping rolls, steel lift covers, and fiberglass lift covers.
COD - Chemical oxygen demand. A nonconventional, bulk parameter that measures the
oxygen-consuming capacity of refractory organic and inorganic matter present in water or
wastewater. COD is expressed as the amount of oxygen consumed from a chemical oxidant in a
specific test, see Method 410.1.
Commercial Facility - A facility that performs 50 percent of their cleanings for commercial
customers. Many of these facilities perform 90 percent or more commercial cleanings.
Commodity - Any chemical, material, or substance transported in a tank track, closed-top
hopper truck, intermediate bulk container, rail tank car, closed-top hopper rail car, inland tank
barge, closed-top inland hopper barge, ocean/sea tanker, or similar tank that comes in direct
contact with the chemical, material, or substance. A commodity may also be referred to as a
cargo.
Consignee - Customer or agent to whom commodities or cargos are delivered.
Contract Hauling - The removal of any waste stream from the facility by a company authorized
to transport and dispose of the waste, excluding discharges to sewers of surface waters.
Conventional Pollutants - The pollutants identified in Sec. 304(a)(4) of the Clean Water Act
and the regulations thereunder (i.e., biochemical oxygen demand (BOD5), total suspended solids
(TSS), oil and grease, fecal coliform, and pH).
CWA - Clean Water Act. The Federal Water Pollution Control Act Amendments of 1972 (33
U.S.C. 1251 et seq.), as amended, inter alia, by the Clean Water Act of 1977 (Public Law 95-
217) and the Water Quality Act of 1987 (Public Law 100-4).
Daily Discharge - The discharge of a pollutant measured during any calendar day or any 24-hour
period that reasonably represents a calendar day.
Dairy Products Processing Effluent Guideline - see 40 CFR Part 405.
Detailed Questionnaire - The 1994 Detailed Questionnaire for the Transportation Equipment
Cleaning Industry.
Direct Capital Costs - One-time capital costs associated with the purchase, installation, and
delivery of a specific technology. Direct capital costs are estimated by the TECI cost model.
Direct Discharger - A facility that conveys or may convey untreated or facility-treated process
wastewater or nonprocess wastewater directly into surface waters of the United States, such as
rivers, lakes, or oceans. (See Surface Waters definition.)
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Section 15.0 - Glossary
Discharge - The conveyance of wastewater to: (1) United States surface waters such as rivers,
lakes, and oceans, or (2) a publicly-owned, privately-owned, federally-owned, centralized, or
other treatment works.
Drum - A metal or plastic cylindrical container with either an open-head or a tight-head (also
known as bung-type top) used to hold liquid, solid, or gaseous commodities or cargos which are
in direct contact with the container interior. Drums typically range in capacity from 30 to 55
gallons.
Dry Bulk Cargo - A cargo which includes dry bulk products such as fertilizers, grain, and coal.
EA - Economic assessment. An analysis which estimates the economic impacts of compliance
costs on facilities, firms, employment, domestic and international market, inflation, distribution,
environmental justice, and transportation equipment cleaning customers.
Effluent - Wastewater discharges.
Effluent Limitation - Any restriction, including schedules of compliance, established by a State
or the Administrator on quantities, rates, and concentrations of chemical, physical, biological,
and other constituents which are discharged from point sources into navigable waters, the waters
of the contiguous zone, or the ocean. (CWA Sections 301(b) and 304(b).)
Emission - Passage of air pollutants into the atmosphere via a gas stream or other means.
EPA - The U.S. Environmental Protection Agency.
Facility - A facility is all contiguous property owned, operated, leased, or under the control of the
same corporation or business entity. The contiguous property may be divided by public or
private right-of-way.
Federally-Owned Treatment Works (FOTW) - Any device or system owned and/or operated
by a United States Federal Agency to recycle, reclaim, or treat liquid sewage or liquid industrial
wastes.
Food Grade Cargo - Food grade cargos include edible and non-edible food products.
Specific examples of food grade products include but are not limited to: alcoholic beverages,
animal by-products, animal fats, animal oils, caramel, caramel coloring, chocolate, corn syrup
and other com products, dairy products, dietary supplements, eggs, flavorings, food
preservatives, food products that are not suitable for human consumption, fruit juices, honey,
lard, molasses, non-alcoholic beverages, salt, sugars, sweeteners, tallow, vegetable oils, vinegar,
and water.
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Section 15.0 - Glossary
FR - Federal Register, published by the U.S. Government Printing Office, Washington, D.C. A
publication making available to the public regulations and legal notices issued by federal
agencies.
Hazardous Air Pollutants (HAPs) - Substances listed by EPA as air toxics under Section 112
of the Clean Air Act.
Heel - Any material remaining in a tank or container following unloading, delivery, or discharge
of the transported cargo. Heels may also be referred to as container residue, residual materials or
residuals.
Hexane Extractable Material (HEM) - A method-defined parameter that measures the presence
of relatively nonvolatile hydrocarbons, vegetable oils, animal fats, waxes, soaps, greases, and
related materials that are extractable in the solvent n-hexane. The analytical method for Oil and
Grease is currently being revised to allow for the use of normal hexane in place of Freon 113, a
chlorofluorocarbon (CFC). Method 1664 (Hexane Extractable Material) will replace the current
Oil and Grease Method 413.1 found in 40 CFR 136.
Independent - A facility that provides cleaning services on a commercial basis, either as a
primary or secondary business, for tanks which they do not own or operate.
Indirect Capital Costs - One-time capital costs that are not technology-specific and are
represented as a multiplication factor that is applied to the direct capital costs estimated by the
TECI cost model.
Indirect Discharger - A facility that discharges or may discharge pollutants into a publicly-
owned treatment works (POTW).
Industrial Waste Combusters Effluent Guidelines - see proposed 40 CFR Part 444, FR 6325,
February 6, 1998.
In-house Facility - A facility that performs less than 50 percent of their cleanings for
commercial clients. In-house TEC facilities primarily clean their own transportation equipment
and have very few commercial clients. Most of these facilities perform less than 10 percent of
their total cleanings for commercial clients.
Inland Tank Barge - A self- or non-self-propelled vessel constructed or adapted primarily to
carry commodities or cargos in bulk in cargo spaces (or tanks) through rivers and inland
waterways, and may occasionally carry commodities or cargos through oceans and seas when in
transit from one inland waterway to another. The commodities or cargos transported are in direct
contact with the tank interior. There are no maximum or minimum vessel or tank volumes.
Inorganic Chemicals Manufacturing Effluent Guidelines - see 40 CFR Part 415.
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Section 15.0 - Glossary
Intermediate Bulk Container (BBC or Tote) - A completely enclosed storage vessel used to
hold liquid, solid, or gaseous commodities or cargos which are in direct contact with the tank
interior. Intermediate bulk containers may be loaded onto flat beds for either truck or rail
transport, or onto ship decks for water transport. IBCs are portable containers with 450 liters
(119 gallons) to 3000 liters (793 gallons) capacity. IBCs are also commonly referred to as totes
or tote bins.
Inter-modal Tank Container - A completely enclosed storage vessel used to hold liquid, solid,
or gaseous commodities or cargos which come in direct contact with the tank interior.
Intermodal tank containers may be loaded onto flat beds for either truck or rail transport, or onto
ship decks for water transport. Containers larger than 3000 liters capacity are considered
mtermodal tank containers. Containers smaller than 3000 liters capacity are considered IBCs.
MP&M - Metal Products & Machinery Effluent Guidelines, new regulation to be proposed in
2000.
New Source - As defined in 40 CFR 122.2 and 122.29, and 403.3(k), a new source is any
building, structure, facility, or installation from which there is or may be a discharge of
pollutants, the construction of which commenced (1) for purposes of compliance with New
Source Performance Standards, after the promulgation of such standards under CWA Section
306; or (2) for the purposes of compliance with Pretreatment Standards for New Sources, after
the publication of proposed standards under CWA Section 307(c), if such standards are thereafter
promulgated in accordance with that section.
Nonconventional Pollutant - Pollutants that are neither conventional pollutants nor priority
toxic pollutants listed at 40 CFR Section 401.
Nondetect Value - A concentration-based measurement reported below the sample-specific
detection limit that can reliably be measured by the analytical method for the pollutant.
Nonprocess Wastewater - Wastewater that is not generated from industrial processes or that
does not come into contact with process wastewater. Nonprocess wastewater includes, but is not
limited to, wastewater generated from restrooms, cafeterias, and showers.
Non-Water Quality Environmental Impact - An environmental impact of a control or
treatment technology, other than to surface waters.
NPDES - The National Pollutant Discharge Elimination System authorized under Sec. 402 of the
CWA. NPDES requires permits for discharge of pollutants from any point source into waters of
the United States.
NRDC - Natural Resources Defense Council.
NSPS - New source performance standards, under Sec. 306 of the CWA.
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Section 15.0 - Glossary
Ocean/Sea Tanker - A self- or non-self-propelled vessel constructed or adapted to transport
commodities or cargos in bulk in cargo spaces (or tanks) through oceans and seas, where the
commodity or cargo carried comes in direct contact with the tank interior. There are no
maximum or minimum vessel or tank volumes.
OCPSF - Organic Chemicals, Plastics, and Synthetic Fibers Manufacturing Effluent Guideline,
see 40 CFR Part 414.
Off Site - "Off site" means outside the bounds of the facility.
Oil and Grease (O&G) - A method-defined parameter that measures the presence of relatively
nonvolatile hydrocarbons, vegetable oils, animal fats, waxes, soaps, greases, and related
materials that are extractable in Freon 113 (l,l,2-trichloro-l,2,2-trifluoroethane). The analytical
method for Oil and Grease and Total Petroleum Hydrocarbons (TPH) is currently being revised
to allow for the use of normal hexane in place of Freon 113, a chlorofluorocarbon (CFC).
Method 1664 (Hexane Extractable Material) will replace the current Oil and Grease Method
413.1 found in 40 CFR 136. In anticipation of promulgation of Method 1664, data collected by
EPA in support of the TECI effluent guideline utilized Method 1664. Therefore, all effluent
limitations proposed for Oil and Grease and TPH in this effluent guideline are to be measured by
Method 1664.
On Site - "On site" means within the bounds of the facility.
Operating and Maintenance (O&M) Costs - All costs related to operating and maintaining a
treatment system for a period of one year, including the estimated costs for compliance
wastewater monitoring of the effluent.
Petroleum Cargo - Petroleum cargos include the products of the fractionation or straight
distillation of crude oil, redistillation of unfinished petroleum derivatives, cracking, or other
refining processes. For purposes of this rule, petroleum cargos also include products obtained
from the refining or processing of natural gas and coal. For purposes of this rule, specific
examples of petroleum products include but are not limited to: asphalt; benzene; coal tar; crude
oil; cutting oil; ethyl benzene; diesel fuel; fuel additives; fuel oils; gasoline; greases; heavy,
medium, and light oils; hydraulic fluids, jet fuel; kerosene; liquid petroleum gases (LPG)
including butane and propane; lubrication oils; mineral spirits; naphtha; olefin, paraffin, and
other waxes; tall oil; tar; toluene; xylene; and waste oil.
Petroleum Refining Effluent Guidelines - see 40 CFR Part 415.
PNPL - Production Normalized Pollutant Loading. Untreated wastewater pollutant loading
generated per tank cleaning.
Point Source Category - A category of sources of water pollutants.
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Section 15.0 - Glossary
Pollutants Effectively Removed - Non-pesticide/herbicide pollutants that meet the following
criteria are considered effectively removed: detected two or more times in the subcategory
influent, an average treatment technology option influent concentration greater than
or equal to five times their analytical method detection limit, and a removal rate of 50 percent or
greater by the treatment technology option. Pesticide/herbicide pollutants that meet the
following criteria are considered effectively removed: detected in the subcategory influent one or
more times at a concentration above the analytical method detection limit, and a removal rate of
greater than zero by the treatment technology option. All pollutants effectively removed were
used in the environmental assessment and cost effectiveness analyses.
Pollution Prevention - The use of materials, processes, or practices that reduce or eliminate the
creation of pollutants or wastes. It includes practices that reduce the use of hazardous and
nonhazardous materials, energy, water, or other resources, as well as those practices that protect
natural resources through conversation or more efficient use. Pollution prevention consists of
source reduction, in-process recycle and reuse, and water conservation practices.
Post-Compliance Loadings - Pollutant loadings in TEC wastewater following implementation
of each regulatory option. These loadings are calculated assuming that all TEC facilities would
operate wastewater treatment technologies equivalent to the technology bases for the selected
regulatory options.
POTW - Publicly-owned treatment works, as defined at 40 CFR 403.3(o).
PPA - Pollution Prevention Act. The Pollution Prevention Act of 1990 (42 U.S.C. 13101 et
seq., Pub. Law 101-508), November 5,1990.
Prerinse - Within a TEC cleaning process, a rinse, typically with hot or cold water, performed at
the beginning of the cleaning sequence to remove residual material from the tank interior.
Presolve Wash - Use of diesel, kerosene, gasoline, or any other type of fuel or solvent as a tank
interior cleaning solution.
Pretreatment Standard - A regulation that establishes industrial wastewater effluent quality
required for discharge to a POTW. (CWA Section 307(b).)
Previously Regulated Facility - Any TEC facility that has major process wastewater streams
that are covered by other effluent guidelines. TEC operations are usually a very small part of
their overall operation. These facilities include organic chemical manufacturers (OCPSF
Effluent Guideline), centralized waste treaters (CWT Effluent Guideline), dairies (Dairies
Effluent Guideline), and incinerators (Incinerators Effluent Guideline).
Priority Pollutants - The pollutants designated by EPA as priority in 40 CFR Part 423,
Appendix A.
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Section 15.0 - Glossary
Privately-Owned Treatment Works - Any device or system owned and operated by a private
company that is used to recycle, reclaim, or treat liquid industrial wastes not generated by that
company.
Process Wastewater - Any water which, during manufacturing or processing, comes into direct
contact with or results from the production or use of any raw material, intermediate product,
finished product, byproduct, or waste product.
PSES - Pretreatment standards for existing sources, under Sec. 307(b) of the CWA.
PSNS - Pretreatment standards for new sources, under Sec. 307(b) and (c) of the CWA.
Rail Tank Car - A completely enclosed storage vessel pulled by a locomotive that is used to
transport liquid, solid, or gaseous commodities or cargos over railway access lines. A rail tank
car storage vessel may have one or more storage compartments, and the stored commodities or
cargos come in direct contact with the tank interior. There are no maximum or minimum vessel
or tank volumes.
RCRA - Resource Conservation and Recovery Act (PL 94-580) of 1976, as amended (42 U.S.C.
6901, et. seq.).
RREL - Risk Reduction Engineering Laboratory.
Screener Questionnaire - The 1993 Screener Questionnaire for the Transportation Equipment
Cleaning Industry.
Shipper-Operated (Shipper) - A facility that transports or engages a carrier for transport of
their own commodities or cargos and cleans the fleet used for such transport. Also included in
the scope of this definition are facilities which provide tank cleaning services to fleets that
transport raw materials to their location.
SIC - Standard industrial classification. A numerical categorization system used by the U.S.
Department of Commerce to catalogue economic activity. SIC codes refer to the products, or
group of products, produced or distributed, or to services rendered by an operating establishment.
SIC codes are used to group establishments by the economic activities in which they are engaged.
SIC codes often denote a facility's primary, secondary, tertiary, etc. economic activities.
Silica Gel Treated Hexane Extractable Material (SGT-HEM) - A method-defined parameter
that measures the presence of mineral oils that are extractable in the solvent n-hexane and not
adsorbed by silica gel. The analytical method for Total Petroleum Hydrocarbons (TPH) and Oil
and Grease is currently being revised to allow for the use of normal hexane in place of Freon
113, a chlorofluorocarbon (CFC). Method 1664 (Hexane Extractable Material) will replace the
current Oil and Grease Method 413.1 found in 40 CFR 136. In anticipation of promulgation of
Method 1664, data collected by EPA in support of the TECI effluent guideline utilized Method
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Section 15.0 - Glossary
1664. Therefore, all effluent limitations proposed for Oil and Grease and TPH in this effluent
guideline are to be measured by Method 1664.
Source Reduction - Any practice which reduces the amount of any hazardous substance,
pollutant, or contaminant entering any waste stream or otherwise released into the environment
prior to recycling, treatment, or disposal. Source reduction can include equipment or technology
modifications, process or procedure modifications, substitution of raw materials, and
improvements in housekeeping, maintenance, training, or inventory control.
Surface Waters - Waters including, but not limited to, oceans and all interstate and intrastate
lakes, rivers, streams, mudflats, sand flats, wetlands, sloughs, prairie potholes, wet meadows,
playa lakes, and natural ponds.
Tank - A generic term used to describe any closed container used to transport commodities or
cargos. The commodities or cargos transported come in direct contact with the container interior,
which is cleaned by TEC facilities. Examples of containers which are considered tanks include
but are not limited to: tank trucks, closed-top hopper trucks, intermodal tank containers, rail tank
cars, closed-top hopper rail cars, inland tank barges, closed-top inland hopper barges, ocean/sea
tankers, and similar tanks (excluding drums and intermediate bulk containers). Containers used
to transport pre-packaged materials are not considered tanks, nor are 55-gallon drums or pails.
Tank Truck - A motor-driven vehicle with a completely enclosed storage vessel used to
transport liquid, solid or gaseous materials over roads and highways. The storage vessel or tank
may be detachable, as with tank trailers, or permanently attached. The commodities or cargos
transported come in direct contact with the tank interior. A tank truck may have one or more
storage compartments. There are no maximum or minimum vessel or tank volumes. Tank trucks
are also commonly referred to as cargo tanks or tankers.
TECI - Transportation Equipment Cleaning Industry.
Total Annualized Cost - The sum of annualized total capital investment and O&M costs. Total
capital investment costs are annualized by spreading them over the life of the project. These
annualized costs are then added to the annual O&M costs.
Total Capital Investment - Total one-time capital costs required to build a treatment system
(i.e., sum of direct and indirect capital costs).
Totes or Tote Bins - A completely enclosed storage vessel used to hold liquid, solid, or gaseous
commodities or cargos which come in direct contact with the vessel interior. Totes may be
loaded onto flat beds for either truck or rail transport, or onto ship decks for water transport.
There are no maximum or minimum values for tote volumes, although larger containers are
generally considered to be intermodal tank containers. Totes or tote bins are also referred to as
intermediate bulk containers or IBCs. Fifty-five gallon drums and pails are not considered totes
or tote bins.
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Section 15.0 - Glossary
TPH,- Total petroleum hydrocarbons. A method-defined parameter that measures the presence
of mineral oils that are extractable in Freon 113 (l,l,2-trichloro-l,2,2-trifluoroethane) and not
adsorbed by silica gel. The analytical method for TPH and Oil and Grease is currently being
revised to allow for the use of normal hexane in place of Freon 113, a chlorofluorocarbon (CFC).
Method 1664 (Hexane Extractable Material) will replace the current Oil and Grease Method
413.1 found in 40 CFR 136. In anticipation of promulgation of Method 1664, data collected by
EPA in support of the TECI effluent guideline utilized Method 1664. Therefore, all effluent
limitations proposed for Oil and Grease and TPH in this effluent guideline are to be measured by
Method 1664.
Transportation Equipment Cleaning Facility - Any facility that generates wastewater from
cleaning the interior of tank trucks, closed-top hopper trucks, rail tank cars, closed-top hopper
rail cars, intermodal tank containers, inland tank barges, closed-top hopper barges, ocean/sea
tankers, and other similar tanks (excluding drums and intermediate bulk containers).
Transportation Equipment Cleaning Wastewater - Washwaters which have come into direct
contact with the tank or container interior including prerinse cleaning solutions, chemical
cleaning solutions, and final rinse solutions. In addition, wastewater generated from washing
vehicle exteriors and equipment and floor washings for those facilities are covered by the
proposed guidelines.
Treatment Effectiveness Concentration - Treated effluent pollutant concentration that can be
achieved by each treatment technology that is part of a TECI regulatory option.
Treatment, Storage, and Disposal Facility (TSDF) - A facility that treats, stores, or disposes
hazardous waste in compliance with the applicable standards and permit requirements set forth in
40 CFR Parts 264, 265, 266, and 270.
TSS - Total suspended solids. A measure of the amount of particulate matter that is suspended
in a water sample. The measure'is obtained by filtering a water sample of known volume. The
particulate material retained on the filter is then dried and weighed, see Method 160.2.
Untreated Loadings - Pollutant loadings in raw TEC wastewater. These loadings represent
pollutant loadings generated by the TECI, and do no account for wastewater treatment currently
in place at TEC facilities.
U.S.C. - The United States Code.
Zero discharge facility - A facility that does not discharge pollutants to waters of the United
States or to a POTW. Also included in this definition are discharge or disposal of pollutants by
way of evaporation, deep-well injection, off-site transfer to a treatment facility, and land
application.
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