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vvEPA
Development Document for
Proposed Effluent Limitations
Guidelines and Standards for
the Centralized Waste
Treatment Industry
               Volume II
               (EPA821-R-98-020)
                Carol M. Browner
                Administrator

                J. Charles Fox
                Assistant Administrator, Office of Water

                Tudor T. Davies
                Director, Office of Science and Technology

                Sheila E. Frace
                Acting Director, Engineering and Analysis Division

                Elwood H. Forsht
                Chief, Chemicals and Metals Branch

                Jan S. Matuszko
                Project Manager

                Timothy E. Connor
                Project Engineer

                Maria D. Smith
                Project Statistician

                December 1998
                U.S, Environmental Protection Agency
                Office of Water
                Washington, DC 20460

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                                            TABLE OF CONTENTS
Volume 1:

Chapter 1      BACKGROUND	1-1

       l.o    LEGAL AUTHORITY	l-l

       1.1    LEGISLATIVE BACKGROUND 	l-l
              1.1.1  Clean Water Act  	1-1
                    1.1.1.1 Best Practicable Control Technology Currently Availabl
                           (BPT)~Sec.304(b)(l) of the CWA	1-1
                    1.1.1.2 Best Conventional Pollutant Control Technology (BCT)-Sec
                           304(b)(4) of the CWA	1-2
                    1.1.1.3 Best Available Technology Economically Achievable (BAT)~
                           Sec. 304(b)(2) of the CWA	1-2
                    1.1.1.4 New Source Performance Standards (NSPS)~Sec.306ofthe
                           CWA	1-2
                    1.1.1.5 Pretreatment Standards for Existing Sources (PSES)-
                           Sec.307(b) of the CWA	1-3
                    1.1.1.6 Pretreatment Standards for New Sources (PSNS)-Sec.307(b)
                           of the CWA	1-3
              1.1.2  Section 304(m) Requirements and Litigation	1-3
              1.1.3  The Land Disposal Restrictions Program:	1-3
                    1.1.3.1 Introduction to RCRA Land Disposal Restrictions (LDR)	1-3
                    1.1.3.2 Overlap Between LDR Standards and the Centralized Waste
                           Treatment Industry Effluent Guidelines	1-5

       1.2    CENTRALIZED WASTE TREATMENT INDUSTRY EFFLUENT GUIDELINE
              RULEMAKING HISTORY	1-5
              1.2.1  January 27,1995 Proposal	1-5
              1.2.2  September 16,1996 Notice of Data Availability	1-6


Chapter 2     DATA COLLECTION  	2-1

       2.1    PRELIMINARY DATA SUMMARY	2-1

       2.2    CLEAN WATER ACT SECTION 308 QUESTIONNAIRES	2-2
              2.2.1  Development of Questionnaires	2-2
              2.2.2  Distribution of Questionnaires  	2-3

       2.3    WASTEWATER SAMPLING AND SITE VISITS	2-3
              2.3.1  Pre-1989 Sampling Program	2-3
              2.3.2  1989-1997 Site Visits	2-4
              2.3.3  Sampling Episodes	2-4
                    2.3.3.1 Facility Selection	2-4
                    2.3.3.2 Sampling Episodes		2-5
                    2.3.3.3 Metal-Bearing Waste Treatment and Recovery Sampling ... 2-10
                    2.3.3.4 Oily Waste Treatment and Recovery Sampling	2-10

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                     2.3.3.5 Organic-Bearing Waste Treatment and Recovery Sampling . 2-11
              2.5.4   1998 Characterization Sampling of Oil Treatment and Recover
                     Facilities	2-11

       2.4    PUBLIC COMMENTS TO THE 1995 PROPOSAL AND THE 1996 NOTICE OF DATA
              AVAILABILITY	2-11

       2.5    ADDITIONAL DATA SOURCES	2-13
              2.5.1   Additional Databases	2-13
              2.5.2   Laboratory Study on the Effect of Total Dissolved Solids on Metal
                     Precipitation	2-13

       2.6    PUBLIC PARTICIPATION	2-14


Chapter 3     SCOPE/APPLICABILITY OF THE PROPOSED REGULATION	3-1

       3.1    APPLICABILITY	  	3-1
              3.1.1   Facilities Subject to 40 CFR (Parts 400 to 471)	3-1
              3.1.2   Pipeline Transfers (Fixed Delivery Systems)	3-4
              3.1.3   Product Stewardship	3-5
              3.1.4   Solids, Soils, and Sludges	3-7
              3.1.5   Sanitary Wastes	:	3-8
              3.1.6   Transporters and/or Transportation Equipment Cleaners	3-8
              3.1.7   Publicly Owned Treatment Works (POTWs)	3-8
              3.1.8   Silver Recovery Operations from Used Photographic and X-Ray
                     Materials	3-9
              3.1.9   High Temperature Metals Recovery	3-10
              3.1.10  Landfill Wastewaters	'.	3-11
              3.1.11  Industrial Waste Combustors	3-11
              3.1.12  Solvent Recycling/Fuel Blending  	3-12
              3.1.13 Re-refining	3-12
              3.1.14  Used Oil Filter RecycUng	3-13
              3.1.15 Marine Generated Wastes  	3-13
              3.1.16  Stabilization	3-14
              3.1.17  Grease Trap/Interceptor Wastes  	3-14


Chapter4     DESCRIPTION OFTHE INDUSTRY	4-1

       4.1    INDUSTRYSIZE	4-1

       4.2    GENERAL DESCRIPTION	4-2

       4.3    WATER USE AND SOURCES OF WASTEWATER	4-4

       4.4    VOLUME BYTYPE OF DISCHARGE	'4-5

     .  4.5    OFF-SITE TREATMENT INCENTIVES AND COMPARABLE TREATMENT	4-6

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Chapter 5     INDUSTRY SUBCATEGORIZATION	5-1

       5.1    METHODOLOGY AND FACTORS CONSIDERED AS THE BASIS FOR
             SUBCATEGORIZATION	5-1

       5.2    PROPOSED SUBCATEGORIES 	5-2

       5.3    SUBCATEGORY DESCRIPTIONS	5-2
             5.3.1  Metal-Bearing Waste Treatment and Recovery Subcategory	5-2
             5.3.2  Oily Waste Treatment and Recovery Subcategory	5-3
             5.3.3  Organic Waste Treatment and Recovery Subcategory  	5-3

       5.4    MIXED WASTE SUBCATEGORY CONSIDERATION	5-4


Chapter 6     POLLUTANTS  OF CONCERN FOR THE CENTRALIZED WASTE
             TREATMENT INDUSTRY	6-1

       6.1    METHODOLOGY	6-1

       6.2    POLLUTANTS OF CONCERN FOR THE METALS SUBCATEGORY	6-24

       6.3    POLLUTANTS OF CONCERN FOR THE OILS SUBCATEGORY	6-25

       6.4    POLLUTANTS OF CONCERN FOR THE ORGANICS SUBCATEGORY	6-27

       6.5    REFERENCES	6-27


Chapter 7     POLLUTANTS  SELECTED FOR REGULATION	7-1

       7.1    TREATMENT CHEMICALS	7-1

       7.2    NON-CONVENTIONAL BULK PARAMETERS 	7-1

       7.3    POLLUTANTS NOT DETECTED AT TREATABLE LEVELS	7-1

       7.4    POLLUTANTS NOT TREATED  		7-6

       7.5    VOLATILE POLLUTANTS	7-6

       7.6    POLLUTANTS SELECTED FOR PRETREATMENT STANDARDS AND
             PRETREATMENT STANDARDS FOR NEW SOURCES (INDIRECT DISCHARGERS) . 7-15
             7.6.1  Background	7-15
             7.6.2  Determination of Percent Removals for well-Operated POTWs	7-16
             7.6.3  Methodology for Determining Treatment Technology Percent
                   Removals 	7-21
             7.6.4  Pass-Through Analysis Results	7-21
                   7.6.4.1 Pass-Through Analysis Results for the Metals Subcategory .7-21
                   7.6.4.2 Pass-Through Analysis Results for the Oils Subcategory ... 7-24

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                      7.6.4.3 Pass-Through Analysis Results for the Organics
                             Subcategory	7-26

       7.7    FINAL LIST OF POLLUTANTS SELECTED FOR REGULATION	7-27
              7.7.1   Direct Dischargers 	7-27
              7.7.2   Indirect Dischargers	7-34
Chapter 8     WASTEWATER TREATMENT TECHNOLOGIES	8-1

       8.1    TECHNOLOGIES CURRENTLYW USE	8-1

       8.2    TECHNOLOGY DESCRIPTIONS 	8-3
              8.2.1   Best Management Practices	8-3
              8.2.2   Physical/Chemical/Thermal Treatment	8-3
                      8.2.2.1  Equalization	8-3
                      8.2.2.2  Neutralization	8-5
                      8.2.2.3  Flocculation/Coagulation	8-5
                      8.2.2.4  Emulsion Breaking	8-8
                      8.2.2.5  Gravity Assisted Separation  	8-10
                             l.      GRAVITY OIL/WATER SEPARATION	8-10
                             2.      CLARIFICATION	8-10
                             3.      DISSOLVED AIR FLOTATION	8-13
                      8.2.2.6  Chromium Reduction	8-15
                      8.2.2.7  Cyanide Destruction	8-16
                      8.2.2.8  Chemical Precipitation  	8-19
                      8.2.2.9  Filtration	8-24
                             1.      SAND FILTRATION	8-24
                             2.      MULTIMEDIA FILTRATION	8-25
                             3.      PLATE AND FRAME PRESSURE FILTRATION	8-26
                             4.      MEMBRANE FILTRATION	8-28
                                    A.     ULTRAFILTRATION	'	8-28
                                    B.     REVERSE OSMOSIS		8-28
                             5.      LANCY FILTRATION	8-30
                      8.2.2.10 Carbon Adsorption	8-33
                      8.2.2.11 lonExchange	8-35
                      8.2.2.12 Electrolytic Recovery	8-36
                      8.2.2.13 Stripping	8-39
                             1.      AlRSTRIPPING	8-39
                      8.2.2.14 Liquid Carbon Dioxide Extraction	8-41
              8.2.3   Biological Treatment 	8-41
                      8.2.3.1  Sequencing Batch Reactors	8-43
                      8.2.3.2  Attached Growth Biological Treatment Systems 	8-45
                             1.      TRICKLING FILTERS	8-45
                             2.      BlOTOWERS	8-47
                      8.2.3.3  Activated Sludge	8-47
              8.2.4   Sludge Treatment and Disposal	8-51
                      8.2.4.1  Plate and Frame Pressure Filtration  	8-52
                      8.2.4.2  Belt Pressure Filtration	8-54
                      8.2.4.3  Vacuum Filtration	8-54
                      8.2.4.4  Filter Cake Disposal 	8-57


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             8.2.5   Zero or Alternate Discharge Treatment Options	8-57

       8.3    REFERENCES	8-58


Chapter 9     REGULATORY OPTIONS CONSIDERED AND SELECTED FOR
             BASIS OF REGULATION	9-1

       9.1    ESTABLISHMENT OFBPT	9-1
             9.1.1   Rationale for Metals Subcategory BPT Limitations	9-2
             9.1.2   Rationale for Oils Subcategory BPT Limitations	9-6
             9.1.3   Rationale for Organics Subcategory BPT Limitations	9-11
       9.2    BEST CONVENTIONAL TECHNOLOGY (BCT)	9-13

       9.3    BEST AVAILABLE TECHNOLOGY (BAT)	9-13

       9.4    NEW SOURCE PERFORMANCE STANDARDS (NSPS)	9-14

       9.5    PRETREATMENT STANDARDS FOR EXISTING SOURCES (PSES)	9-15

       9.6    PRETREATMENT STANDARDS FOR NEW SOURCES (PSNS)	9-16


Chapter 10    LONG-TERM AVERAGES, VARIABILITY FACTORS, AND
             LIMITATIONS AND STANDARDS	10-1

       10.1   FACILITY SELECTION	10-1

       10.2   SAMPLE POINT SELECTION	10-2
             10.2.1  Effluent Sample Point	10-2
             10.2.2  Influent Sample Point	:... 10-2
             10.2.3  Special Cases	10-3

       10.3   DETERMINATION OF BATCH AND CONTINUOUS FLOW SYSTEMS	10-3

       10.4   DATA SELECTION	10-5
             10.4.1  Data Exclusions and Substitutions	10-5
                    10.4.1.1 Operational Difficulties  	10-5
                    10.4.1.2 Treatment Not Reflective ofBPT/BCT/BAT Treatment	10-5
                    10.4.1.3 Exclusions to EPA Sampling Data Based Upon the
                          Availability of the Influent and Effluent	10-6
                    10.4.1.4 More Reliable Results Available	10-6
                    10.4.1.5 Data from the Facilities Which Accept Waste from More
                           than One Subcategory	10-7
                    10.4.1.6 Substitution Using the Baseline Values	10-7
             10.4.2  Data Aggregation	10-7
                    10.4.2.1 Aggregation of Field Duplicates  	10-8
                    10.4.2.2 Aggregation of Grab Samples and Multiple Daily Values .. 10-9
                    10.4.2.3 Aggregation of Data Across Streams ("Flow-
                           Weighting") 	  10-10

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       10.4.3  Data Editing Criteria	  10-11
              10.4.3.1 Long-Term Average Test	  10-12
              10.4.3.2 Percent Removal Test	  10-12
              10.4.3.3 Evaluation of Self-Monitoring Data	  10-13

10.5   DEVELOPMENT OF LONG-TERM AVERAGES	  10-13
       10.5.1  Estimation of Facility-SpeciGc Long-Term Averages	  10-14
       10.5.2  Estimation of Pollutant-Specific Long-Term Averages	  10-14
       10.5.3  Substitutions for Long-Term Averages	  10-14
              10.5.3.1 Baseline Values Substituted for Long-term Averages	  10-14
              10.5.3.2 Arsenic Long-Term Average for Metals Subcategory
                     Option 4	  10-15

10.6   DEVELOPMENT OF VARIABILITY FACTORS	  10-15
       10.6.1  Basic Overview of the Modified Delta-Lognormal Distribution ..  10-15
       10.6.2  Discrete Portion of the Modified Delta-Lognormal Distribution .  10-18
       10.6.3  Continuous Portion of the Modified Delta-Lognormal
              Distribution	  10-18
       10.6.4  Estimation Under the Modified Delta-Lognormal Distribution ..  10-19
       10.6.5  Estimation of Facility-Specific Variability Factors	  10-21
              10.6.5.1 Facility Data Set Requirements 	  10-21
              10.6.5.2 Estimation of Facility-Specific Daily Variability Factor   10-21
              10.6.5.3 Estimation of Facility-Specific Monthly Variability
                     Factors	  10-22
              10.6.5.4 Evaluation of Facility-Sped fie Variability Factors 	  10-28
       10.6.6  Estimation of Pollutant-Specific Variability Factors 	  10-29
       10.6.7  Estimation of Group-Level Variability Factors	  10-29
       10.6.8  Transfers of Variability Factors	  10-29

10.7   LIMITATIONS  	  10-31
       10.7.1  Steps Used to Derive Limitations	  10-32
       10.7.2  Example	  10-33

10.8   TRANSFERS OF LIMITATIONS	  10-34
       10.&1  Transfer of Oil and Grease Limitation for Metals Subcategory
              for Option 4 to Option 3	,	  10-34
       10.S.2  Transfers of Limitations from Other Rulemakings to CWT
              Industry	  10-35
              10.8.2.1 Transfer ofBOD5 and TSS for the Organics  Subcategory  10-35
              10.8.2.2 Transfer of TSS for Option 4  of the Metals Subcategory .  10-38

10.9   EFFECT OF GROUP AND POLLUTANT VARIABILITY FACTORS ON
       LIMITATIONS	  10-38

10.10  ATTACHMENTS	  10-39

10.11  REFERENCES	  10-40

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Chapter 11    COST OF TREATMENT TECHNOLOGIES	11-1

       ll.i    COSTS DEVELOPMENT.	l l-l
              11.1.1  Technology Costs  	11-1
              11.1.2  Option Costs	11-2
                     11.1.2.1 Land Requirements and Costs  	11-2
                     11.1.2.2 Operation and Maintenance Costs	11-3

       11.2    PHYSICAL/CHEMICAL WASTEWATER TREATMENT TECHNOLOGY COSTS	11-5
              11.2.1  Chemical Precipitation	11-5
                     11.2.1.1 Selective Metals Precipitation-Metals Option 2 and
                            Metals Option 3	11-5
                     11.2.1.2 Secondary Precipitation-Metals Option 2 and Metals
                            Option 3	11-6
                     11.2.1.3 Tertiary Precipitation and pH Adjustment-Metals
                            Option 3	11-8
                     11.2.1.4 Primary Chemical Precipitation-Metals Option 4	11-9
                     11.2.1.5 Secondary (Sulfide) Precipitation for Metals Option 4  ..  11-12
              11.2.2  Plate and Frame Liquid Filtration and Clarification	  11-13
                     11.2.2.1 Plate and Frame Liquid Filtration Following Selective
                            Metals Precipitation	  11-14
                     11.2.2.2 Clarification for Metals Options 2, 3, and 4	  11-14-
              11.2.3  Equalization	  11-17
              11.2.4  Air Stripping	'	  11-18
              11.2.5  Multi-Media Filtration	  11-19
              11.2.6  Cyanide Destruction	  11-20
              11.2.7  Secondary Gravity Separation	  11-21
              11.2.*  Dissolved Air Flotation	  11-22

       11.3    BIOLOGICAL WASTEWATER TREATMENT TECHNOLOGY COSTS	  11-25
              11.3.1  Sequencing Batch Reactors	  11-25

       11.4    SLUDGE TREATMENT AND DISPOSAL COSTS	  11-26
              11.4.1  Plate and Frame Pressure FiltrationSludge Stream	  11-26
              11.4.2  Filter Cake Disposal	  11-29

       11.5    ADDITIONAL COSTS	  11-30
              11.5.1  Retrofit Costs	,	  11-30
              11.5.2  Monitoring Costs	  11-31
              11.5.3  RCRA Permit Modification Costs	  11-32
              11.5.4  Land Costs	  11-33

       11.6    REFERENCES	  11-43

       11.7    SUMMARY OF COST OF TECHNOLOGY OPTIONS	  11-44
              11.7.1  BPT Costs	  11-44
              11.7.2  BCT/BATCosts	  11-44
              11.7.3  PSES Costs	  11-44

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Chapter 12   POLLUTANT LOADING AND REMOVAL ESTIMATES	12-1

       12.1   INTRODUCTION	12-1

       12.2   DATASOURCES	12-1

       12.3   METHODOLOGY USED TO DEVELOP CURRENT LOADINGS ESTIMATES	12-2
             12.3.1  Current Loadings Estimates for the Metals Subcategory	12-2
                    12.3.1.1 Raw Loadings for the Metals Subcategory  	12-4
                    12.3.1.2 Primary Precipitation with Solids-Liquid Separation
                           Loadings 	12-4
                    12.3.1.3 Secondary Precipitation with Solids-Liquid Separation
                           Loadings 	12-5
                    12.3.1.4 Technology Basis for the Proposed BPT/BAT/PSES
                           Option 4 Loadings	12-5
                    12.3.1.5 Selective Metals Precipitation (NSPS/PSNS Proposed
                           Option 3) Loadings	12-5
             12.3.2  Current Loadings Estimates for the Oils Subcategory	12-5
                    12.3.2.1 Issues Associated with Oils Current Performance
                           Analyses	12-9
                    12.3.2.1 Random Assignment of Seven Emulsion Breaking/Gravity
                           Separation Data Sets	  12-31
             12.3.3  Organics Subcategory Current Loadings	  12-33

       12.4   METHODOLOGY USED TO ESTIMATE POST-COMPLIANCE LOADINGS 	  12-35

       12.5   METHODOLOGY USED TO ESTIMATE POLLUTANT REMOVALS	  12-41

       12.6   POLLUTANT LOADINGS AND REMOVALS	  12-41


Chapter 13   NON-WATER QUALITY IMPACTS	13-1

       13.1   AlRPOLLUTION	13-1

       13.2   SOLID WASTE	13-3

       13.3   ENERGY REQUIREMENTS	,	13-5

       13.4   LABOR REQUIREMENTS	13-5


Chapter 14   IMPLEMENTATION	14-1

       14.1   APPLICABLE WASTE STREAMS	14-1

       14.2   DESCRIPTION OF SUBCATEGORY	14-2
             14.2.1  Metals Subcategory Description 	14-2
             14.2.2  Oils Subcategory Description	14-2
             14.2.3  Organics Subcategory Description 	14-3

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       14.3   FACILITY SUBCATEGORIZATION IDENTIFICATION	14-3

       14.4   ON-SITE GENERATED WASTEWATER SUBCATEGORY DETERMINATION	14-7
             14.4.1  On-site Industrial Waste Combustors, Landfills, and
                    Transportation Equipment Cleaning Operations	14-7

       14.5   SUBCATEGORY DETERMINATION m EPA QUESTIONNAIRE DATA BASE	14-7
             14.5.1  Wastes Classified in the Metals Subcategory - Questionnaire
                    Responses	  14-14
             14.5.2  Wastes Classified in the Oils Subcategory - Questionnaire
                    Responses	  14-14
             14.5.3  Wastes Classified in the Organics Subcategory - Questionnaire
                    Responses	  14-14

       14.6   ESTABLISHING LIMITATIONS AND STANDARDS FOR FACILITY DISCHARGES  14-15
             14,6.1  Existing Guidance for Multiple Subcategory Facilities	  14-16
                    14.6.1.1 Direct Discharge Guidance  	  14-16
                    14.6.1.2 Indirect Discharge Guidance	  14-19
             14.6.2  CWT Facilities Also Covered By Another Point Source
                    Category	  14-26


Chapter 15   ANALYTICAL METHODS AND BASELINE VALUES	15-1

       15.1   INTRODUCTION	15-1

       15.2   ANALYTICAL RESULTS  	15-1

       15.3   NOMINAL QUANTITATION LIMITS	15-2

       15.4   BASELINE VALUES	15-2

       15.5   ANALYTICAL METHODS	15-5
             15.5.1  Methods 1613,1624,1625,1664 (Dioxins, Organics, HEM)	15-5
             15.5.2  Method413.1  (Oiland Grease)	15-5
             15.5.3  Method 1620  	15-5
             15.5.4  MethodSS.Ol	15-6
             15.5.5  Methods D4658 and 376.1 (Total Sulfide) 	15-7
             15.5.6  Methods 410.1, 410.2, and 410.4 (COD andD-COD)	15-7
             15.5.7 Method 420.2 (TotalPhenols)	15-7
             15.5.S  Method 218.4 and 3500D (Hexavalent Chromium)	15-8
             15.5.9  Methods 335.2 and 353.2 (Total Cyanide and Nitrate/Nitrite)	15-8
             15.5.10 Remaining Methods	15-8

       15.6   ANALYTICAL METHOD DEVELOPMENT EFFORTS	15-8

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LIST OF DEFINITIONS	Definitions-1
LIST OF ACRONYMS	 Acronyms-1
INDEX  	 Index-1
Volume 2:

Appendix A   POLLUTANT GROUPS
A-l
Appendix B   LISTING OF CHARACTERIZATION DATA FROM
           NON-HAZARDOUS OILS FACILITIES	
B-l
Appendix C   LISTING OF DAILY INFLUENT AND EFFLUENT
           MEASUREMENTS	
C-l
Appendix D   FACILITY-SPECIFIC COMPLIANCE COSTS	D-l
AppendixE   ATTACHMENTS TO CHAPTER 10	 E-l
Appendix F   LISTING OF POLLUTANTS OF CONCERN AND CAS NUMBERS ... F-l

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                Appendix
                   A
   POLLUTANT GROUPS

GROUP
ALCOHOLS, ALIPHATIC
ALIPHATIC CARBOXYLIC ACID
AMIDES
AMINES, ALIPHATIC
ANILINES
AROMATIC CARBOXYLIC ACIDS
AROMATICS
1
BROMOETHANES
BROMOMETHANES
CARBON DISULFIDE
CHLOROANILINES
CHLOROBENZENES I
CHLOROBENZENES II
CHLOROETHANES I
CHLOROETHANES II
POLLUTANT
ALPHA-TERPINEOL
BENZYL ALCOHOL
HEXANOIC ACID
N,N-DIMETHYLFORMAMIDE
ETHYLENETfflOUREA '
N-NITROSOMORPHOLINE
ANILINE
CARBAZOLE
BENZOIC ACID
BENZENE
ETHYL BENZENE
M-XYLENE
O+P XYLENE
P-CYMENE
PENTAMETHYLBENZENE
STYRENE
TOLUENE
1,2-DIBROMOETHANE
DIBROMOCHLOROMETHANE
TREBROMOMETHANE
CARBON DISULFIDE
DIMETHYL SULFONE
2,3-DICHLOROANILINE
CHLOROBENZENE
1 ,2-DICHLOROBENZENE
1 ,2,4-TRICHLOROBENZENE
1 ,4-DICHLOROBENZENE
1,1-DICHLOROETHANE
1 ,2-DICHLOROETHANE
1,1,1-TRICHLOROETHANE
1,1,1 ,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1 , 1 ,2,2-TETRACHLOROETHANE
1 ,2,3-TRICHLOROPROPANE
1,3-DICHLOROPROPANE
HEXACHLOROTHANE
PENTACHLOROETHANE
CAS NO
98555
100516
142621
68122
96457
59892
62533
86748
65850
71432
100414
108383
136777612
99876
700129
100425
108883
106934
124481
75252
75150
67710
608275
108907
95501
120821
106467
75343
107062
71556
630206
79005
79345
96184
142289
67721
76017
A-l

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GROUP
CHLOROETHENES I
CHLOROETHENES II



CHLOROMETHANES



CHLOROPHENOLS












ETHERS, ALIPHATIC
ETHERS, AROMATIC

KETONES, ALIPHATIC I

KETONES, ALIPHATIC H


KETONES, AROMATIC
METALS












POLLUTANT
VINYL CHLORIDE
1,1-DICHLOROETHENE
TETRACHLOROETHENE
TRANS-1,2-DICHLOROETHENE
TRICHLOROETHENE
BROMODICHLOROMETHANE
CHLOROFORM
METHYLENE CHLORIDE
 TETRACHLOROMETHANE
2,3,4,6-TETRACHLOROPHENOL
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
3,4-DICHLOROPHENOL
3,4,5-TRICHLOROCATECHOL
3,4,6-TRICHLOROGUAIACOL
3,6-DICHLOROCATECHOL
4-CHLOROPHENOL
4,5-DICHLOROGUAIACOL
4,5,6-TRICHLOROGUAIACOL
5-CHLOROGUAIACOL
6-CHLOROVANILLIN
PENTACHLOROPHENOL
DIETHYL ETHER
DIBENZOFURAN
DIPHENYL ETHER
2-BUTANONE
2-PROPANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ISOPHORONE
ACETOPHENONE
ALUMINUM
BARIUM
BERYLLIUM
CADMIUM
CHROMIUM
COBALT
COPPER
IREDIUM
IRON
LEAD
LITHIUM
MAGNESIUM
MANGANESE
CAS NO
75014
75354
127184
156605
79016
75274
67663
75092
56235
58902
95954
88062
95772
56961207
60712449
3938167
106489
2460493
2668248
3743235
18268763
87865
60297
132649
101848
78933
67641
591786
108101
78591
98862
7429905
7440393
7440417
7440439
7440473
7440484
7440508
7439885
7439896
7439921
7439932
7439954
7439965
A-2

-------
GROUP




METALS (Coirt.)







NONE

















NON-METALS



N-PARAFFESFS







PAHS

POLLUTANT
MERCURY
MOLYBDENUM
NICKEL
SILVER
STRONTIUM
THALLIUM
TIN
TITANIUM
VANADIUM
YTTRIUM
ZINC
ZIRCONIUM
AMENABLE CYANIDE
AMMONIA AS N
BODS
CHLORIDE
COD
FLUORIDE
HEXAVELENT CHROMIUM
NITRATE/NITRITE
OIL + GREASE
SGT-HEM
TDS
TOC
TOTAL CYANIDE
TOTAL PHENOLS
TOTAL PHOSPHORUS
TOTAL SOLIDS
TOTAL SULFIDE
TSS
IODINE
PHOSPHORUS
SELENIUM
SULFUR
N-DECANE
N-DOCOSANE
N-DODECANE
N-EICOSANE
N-HEXACOSANE
N-HEXADECANE
N-OCTADECANE
N-TETRADECANE
1-METHYLFLUORENE
1-METHYLPHENANTHRENE
CAS NO
7439976
7439987
7440020
7440224
7440246
7440280
7440315
7440326
7440622
7440655
7440666
7440677
C-025
7664417
C-002
' 16887006
C-004
16984488
18540299
C--005
C-007
C-037
C-010
C-012
57125
C-020
14265442
C-008
18496258
C-009
7553562
7723140
7782492
7704349
124185
629970
112403
112958
630013
544763
593453
629594
1730376
832699
A-3

-------
GROUP



PAHS (Cont.)













PHENOLS





PHTHALATES



POLYGLYCOLMONOETHERS

PYRIDINES

SEMI-METALS



SULFIDES AROMATIC
POLLUTANT
2-METHYLNAPHTHALENE
2-PHENYLNAPHTHALENE ;
2,3-BENZOFLUORENE
3,6-DIMETHYLPHENANTHRENE
ACENAPHTHENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(A)PYRENE
BENZO(B)FLUORANTHENE
BENZO(K)FLUORANTHENE
BIPHENYL
CHRYSENE
FLUORANTHENE
FLUORENE
NAPHTHALENE
PHENANTHRENE
PYRENE
2-CHLOROPHENOL
2,4-DIMETHYLPHENOL
4-CHLORO-3-METHYLPHENOL
O-CRESOL
P-CRESOL
PHENOL
BIS(2-ETHYLHEXYL)PHTHALAT
BUTYL BENZYL PHTHALATE
DIETHYL PHTHALATE
DI-N-BUTYL PHTHALATE
TRIPROPYLENEGLYCOL METHYL
ETHER
2-PICOLINE
PYRIDINE
ANTIMONY
ARSENIC
BORON
SILICON
DffiENZOTHIOPHENE
CAS NO
91576
612942
243174
1576676
83329
120127
56553
50328
205992
207089
92524
218019
206440
86737
91203
85018
129000
95578
105679
59507
95487
106445
108952
117817
85687
84662
84742
20324338

109068
110861
7440360
7440382
7440428
7440213
132650
A-4

-------
                                                                                    Appendix
                                                                                            B
           LISTING OF CHARACTERIZATION DATA FROM
          	            NON-HAZARDOUS OILS  FACILITIES
The following table defines the column headings used in this Appendix.
 Column Heading
                        Definition
 Analyte Name
 Cas Number
 Facility ID
 Sample
 Amount

 Detection Limit

 Method
 Procedure

 Unit
 SCC Data Qualifier
                        Pollutant (or analyte) name
                        Chemical Abstract Service (CAS) registry number for the analyte
                        Each facility has been assigned an unique 1-character identifier
                        Number assigned to the sample that EPA collected
                        Detected value of the pollutant concentration (if there is a value in this column, then no
                        value is given in the Detection Limit column)
                        Sample-specific detection limit associated with the non-detected measurement (if there
                        is a value in this column, then no value is given in the Amount column)
                        Analytical method that the laboratory used to measure the pollutant
                        This field is blank in all cases. It was included to show that none of the samples were
                        biphasic. If biphasic samples had been included the value would have been either
                        'aqueous' or'organic' corresponding to the phase.
                        Unit associated with the Amount or Detection Limit. The possible values are:
                                UG/L = micrograms per kilogram
                                MG/L = milligrams per kilogram
                                UG/KG = micrograms per kilogram
                        This field is blank except in two cases when the values are:
                                B =     indicates that the pollutant measured by Method 1620 was detected
                                       with a concentration value less than the minimum level, but above the
                                       instrument detection limit (see chapter 15 for further discussion)
                                > =     indicates that a value was reported as being greater than the upper
                        	calibration limit of the analysis the analysis.	
Sample Information
Sample Numbers
                       Description
                       Effluent from Oil/Water Separation
                       Effluents from Separate Oil/Water Separation Units
                       Effluent from Emulsion Breaking/Gravity Separation
                       Effluent from Emulsion Breaking/Gravity Separation
                       Effluent from Oil/Water Separation
                       Effluent from Emulsion Breaking/Gravity Separation*
                       Effluent Samples from Oil/Water Separation*
44074,44075, and 44076  Effluent Samples from Emulsion Breaking/Gravity Separation
44077                 Influent Wastewater (Represents Wastewater in 3 Subcategories and Out-of-scope Wastewater)
44085                 Effluent from Emulsion Breaking/Gravity Separation
* Units for sample points 44013,44014, and 44015 are presented in ug/kg in the first section and converted to ug/L in
the following section titled, Episode 5052 and 5053 converted results.
.43125 and 43127
43131 and 43132
43139
43146
43153
44013*
44014 and 44015*
                                          Appendix B-l  

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-------
                           SAMPLE 44013 Converted Results
ANALYTE                        SAMPLE

ACENAPHTHENE                   44013
ACETOPHENONE                   44013
ALPHA-TERPINEOL                44013
ANILINE                        44013
ANTHRACENE                     44013
BENZO (A) ANTHRACENE             44013
BENZO (A) PYRENE                 44013
BENZO (B) FLUORANTHENE           44013
BENZO (K) FLUORANTHENE           44 013
BENZOIC ACID                   44013
BENZYL ALCOHOL                 44013
BIPHENYL                       44013
BIS(2-ETHYLHEXYL) PHTHALATE    44013
BUTYL BENZYL PHTHALATE         44013
CARBAZOLE                      44013
CHRYSENE   '                    44013
DI-N-BUTYL PHTHALATE           44013
DIBENZOFURAN                   44013
DIBENZOTHIOPHENE               44013
DIETHYL PHTHALATE              44013
DIMETHYL SULFONE               44013
DIPHENYL ETHER                 44013
ETHANE, PENTACHLORO-           44013
ETHYLENETHIOUREA               44013
FLUORANTHENE                   44013
FLUORENE                       44013
HEXACHLOROETHANE               44013
HEXANOIC ACID                  44013
ISOPHORONE                     44013
N-DECANE                       44013
N-DOCOSANE                     44013
N-DODECANE                     44013
N-EICOSANE                     44013
N-HEXACOSANE                   44013
N-HEXADECANE                   44013
N-NITROSOMORPHOLINE            44013
N-OCTADECANE                   44013
N-TETRACOSANE                  44 013
N-TETRADECANE                  44013
N.N-DIMETHYLFORMAMIDE          44013
NAPHTHALENE                    44013
O-CRESOL                       44013
P-CRESOL                       44013
P-CYMENE                       44013
PENTACHLOROPHENOL              44013
PENTAMETHYLBENZENE             44013
PHENANTHRENE                   44013
PHENOL                         44013
AMOUNT

34.54
514.10

.

.
.

524.86
38.34
31.28
113.68













.
19,851.08

192.54
351.88
775.30
610.30
340.20
1,071.20
108.82
3,705.00
515.50
363.86

41.88
74.26
747.02
37.04
.


397.52
DETLIMIT
20


20
20
20
20
20
20



."
20
40
20
20
20
20
20
20
20
40
40
20
20
20

20


.


.




20


.

100
20
20
.
UNIT 3
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
rSOLII
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
                                    Appendix B-32

-------
                      Sample  Point  44013  Converted Results
ANALYTE                             SAMPLE

PYRENE                              44013
PYRIDINE                            44013
STYRENE                             44013
TRIPROPYLENEGLYCOL METHYL ETHER     44013
1-METHYLFLUORENE                    44013
1-METHYLPHENANTHRENE                44013
1, 2 -DICHLOROBENZENE                 4 4 013
1,2,4-TRICHLOROBENZENE              44013
1, 4 -DICHLOROBENZENE                 44 013
2-METHYLNAPHTHALENE                 44013
2-PHENYLNAPHTHALENE                 44013
2-PICOLINE                          44013
2 , 3 -BENZOFLUORENE                   44013
2, 3 -DICHLOROANILINE                 44013
2,3,4,5-TETRACHLOROPHENOL           44013
2,4-DIMETHYLPHENOL                  44013
2,4,5-TRICHLOROPHENOL               44013
2,4,S-TRICHLOROPHENOL               44013
3 , 6 - DIMETHYLPHENANTHRENE            44013
                                                    AMOUNT
              DETLIMIT

                  20
                  20
                  20
                 198
                  20
                  20
                  20
                  20
                  20
                  20
                  20
                 100
                  20
                  20
                  40
                  20
                  20
                  20
                  20
UNIT
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug'/L
ug/L
ug/L
ug/L
%SOLIDS
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
                 Sample Points 44014 and 44015 Converted Results
  ANALYTE                        SAMPLE

  ACENAPHTHENE                  . 44014
  ACENAPHTHENE                   44015
  ACETOPHENONE                   44014
  ACETOPHENONE     .              44015
  ALPHA-TERPINEOL                44014
  ALPHA-TERPINEOL                44015
  ANILINE                        44014
  ANILINE                        44015
  ANTHRACENE                     44014
  ANTHRACENE                     44015
  BENZO (A) ANTHRACENE             44014
  BENZO (A) ANTHRACENE             44015
  BENZO (A) PYRENE                 44014
  BENZO (B) FLUORANTHENE           44014
  BENZO (K) FLUORANTHENE           44014
  BENZOIC ACID                   44014
  BENZOIC ACID                   44015
  BENZYL ALCOHOL                 44014
  BENZYL ALCOHOL                 44015
  BIPHENYL                       44014
  BIPHENYL                       44015
  BIS(2-ETHYLHEXYL)  PHTHALATE    44014
                                                 AMOUNT
   67.76
1,508.38

  413.04
  813.80
   35.12
            DETLIMIT
                        UNIT   %SOLIDS
20
120
20
120
.
120
20
120
20
120
20-
120
20
20
20
.
100
.
120
20
.

ug/L
ug/L .
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1
1
1
l
1
1
1
l
1
l
l
1
1
1
1
1
1
1
1
1
1
1
                                 Appendix B-33

-------
               Sample Points 44014 and 44015 Converted Results
ANALYTE                        SAMPLE
BIS(2-ETHYLHEXYL) PHTHALATE    44015
BUTYL BENZYL PHTHALATE         44014
BUTYL BENZYL PHTHALATE         44015
CARBAZOLE                      44014
CARBAZOLE                      44015
CHRYSENE                       44014
CHRYSENE                       44015
DI-N-BUTYL PHTHALATE           44014
DI-N-BUTYL PHTHALATE           44015
DIBENZOFURAN                   44014
DIBENZOFURAN                   44015
DIBENZOTHIOPHENE               44014
DIBENZOTHIOPHENE               44015
DIETHYL PHTHALATE              44014
DIETHYL PHTHALATE              44015
DIMETHYL SULFONE               44014
DIMETHYL SDLFONE               44015
DIPHENYL ETHER                44014
DIPHENYL ETHER       '         44015
ETHANE, PENTACHLORO-           44014
ETHANE, PENTACHLORO-           44015
ETHYLENETHIOUREA               44014
ETHYLENETHIOUREA               44015
FLUORANTHENE                   44014
FLUORANTHENE         "          44015
FLUORENE                       44014
FLUORENE                       44015
HEXACHLOROETHANE               44014
HEXACHLOROETHANE               44015
HEXANOIC! ACID                 44014
HEXANOIC ACID                 44015
ISOPHORONE                     44014
ISOPHORONE                     44015
N-DECANE                        44014
N-DECANE                        44015
N-DOCOSANE                     44014
N-DOCOSANE                     44015
N-DODECANE                     44014
N-DODECANE                     44015
N-EICOSANE                     44014
N-EICOSANE                     44015
N-HEXACOSANE                   44014
N-HEXACOSANE                   44015
N-HEXADECANE                   44014
N-HEXADECANE                   44015
N-NITROSOMORPHOLINE            44014
N-NITROSOMORPHOLINE            44015
  AMOUNT
2,103.50
   38.02
   423.24
 1,056.56
   262.74
   101.34
 3,378.40
   196.80
 5,922.00
   136.86

    79.54

   210.84
59,480.00
'LIMIT UNIT %SOLIDS
.
20
120
40
240
20
120
20
120
20
120
20
120

120
20
120
20
120
40
240
40
240
20

20
120
20
120

.
20
120
20
120
.



.
120

120

.
20
120
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1
1
1
1
1
1
l
1
1
1
1
1 _
1
1
l
1
1
1
1
l
1
1
l
1
1
l
l
1
1
l
l
1
l
1
1
l
l
1
1
1
1
l
l
1
1
l
l
                                 Appendix B-34

-------
ANALYTE
                        Sample Points 44014 and 44015 Converted Results

                                   SAMPLE          AMOUNT    DETLIMIT    UNIT %SOLIDS
N-OCTADECANE                       44014
N-OCTADECANE                       44015
N-TETRACOSANE                      44014
N-TETRADECANE                      44014
N-TETRADECANE                      44015
N,N-DIMETHYLFORMAMIDE              44014
N,N-DIMETHYLFORMAMIDE              44015
NAPHTHALENE                        44014
NAPHTHALENE                        44015
0-CRESOL                           44014
0-CRESOL                           44015
P-CRESOL                           44014
P-CRESOL                           44015
P-CYMENE                           44014
P-CYMENE                           44015
PENTACHLOROPHENOL                  44014
PENTACHLOROPHENOL                  44015
PENTAMETHYLBENZENE               '44014
PENTAMETHYLBENZENE             ,    44015
PHENANTHRENE                       44014
PHENANTHRENE                       44015
PHENOL                             44014
PHENOL                             44015
PYRENE                             44014
PYRENE                             44015
PYRIDINE                           44014
PYRIDINE                           44015
STYRENE                            44014
STYRENE                        '    44015
TRIPROPYLENEGLYCOL METHYL ETHER    44014
TRIPROPYLENEGLYCOL METHYL ETHER    44015
1-METHYLFLUORENE                   44014
1-METHYLFLUORENE         	       44015
1-METHYLPHENANTHRENE               44014
1-METHYLPHENANTHRENE               44015
1,2-DICHLOROBENZENE                44014
1, 2-DICHLOROBENZENE                44015
1,2,4-TRICHLOROBENZENE             44014
1,2,4-TRICHLOROBENZENE             44015
1,4-DICHLOROBENZENE                44 014
1,4-DICHLOROBENZENE                44015
2-METHYLNAPHTHALENE                44014
2-METHYLNAPHTHALENE                44015
2-PHENYLNAPHTHALENE                44014
2-PHENYLNAPHTHALENE                44015
2-PICOLINE                         44014
2-PICOLINE                         44015
397.04
2,232.00
280.68
58.72
15,838.00



504.00


190.28
182.06






21.18
1,519.64
1,322.00
2,150.00

849.72
.



2,759.34

.










.








.
20
120
20

20
120
.
.
20
120
100
100
20
120
.

.

20

20
120
20
120

1188
20
120
20
120
20
120
20
120
20
120
20
120
20
120
100
500
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1
1
l
1
1
1
l
1
1
1
1
1
l
l
1
1
l
1
1
1
l
1
1
1
1
1
l
1
1
1
1
l
l
1
1
1
l
1
l
1
l
1
1
1
l
1
1
                                 Appendix B-3 5

-------
              Sample Points 44014 and 44015  Converted Results

         ANALYTE             SAMPLE          AMOUNT    DETLIMIT
2,3-BENZOPLUORENE            44 014
2,3-BENZOFLUORENE            44015
2, 3 -DICHLOROANILINE          44 014
2,3-DICHLOROANILINE          44015
2,3,4,6-TETRACHLOROPHENOL    44014
2,3,4,6- TETRACHLOROPHENOL    44015
2,4-DIMETHYLPHENOL           44014
2,4-DIMETHYLPHENOL           44015
2,4,5- TRICHLOROPHENOL        44014
2,4,5-TRICHLOROPHENOL        44015
2,4, 6 -TRICHLOROPHENOL        44 014
2,4, 6-TRICHLOROPHENOL        44015
3,6-DIMETHYLPHENANTHRENE     44014
3,6-DIMETHYLPHENANTHRENE     44015
4-CHLORO-3-METHYLPHENOL      44014
4-CHLORO-3-METHYLPHENOL      44015
 47.82
100.94
 20
120
 20
120
 40
 40

120
 20
 20
 20
 20
 20
120

 20
UNIT
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%SOLIDS

   1
   1
   1
   1
   1
   1
   1
   1
   1
   1
   1
   1
   1
   1
   1
   1
                              Appendix B-36
                                                                                            _

-------
                                                                                   Appendix
                                                                                            c
                                     LISTING OF  DAILY INFLUENT
                             AND EFFLUENT  MEASUREMENTS
Column
Heading
Definition
Subcategory    The subcategories are listed in the following order:
Number 1               'CYANIDE' = cyanide subset of the metals subcategory
                       'METALS' = metals subcategory
                       'OILS' = oils subcategory
                       'ORGANICS' = organics subcategory

Option,        The options are listed in the following order:
(SELECT)              Cyanide subset: options 1 and 2
                       Metals subcategory: options 1A (arsenic data only), 3,4
                       Oils subcategory: options 8 and 9
                       Organics subcategory: option 4

ID            Identification number of the facility where the sample was collected. The identification numbers that
              start with 'E' indicate that the data were obtained from the EPA sampling episodes. The identification
              numbers that have only three digits (e.g., 602) indicate that the facility provided the data

Effl Samp Pt    Effluent Sample Point

Analyte Name  Pollutant (or analyte) name. In some cases, the name was truncated. The full name is available in
              Appendix D by referencing the CAS number.

Sample Date    Date that the sample was collected

CasJMo       Chemical Abstract Service (CAS) registry number for the analyte

ML           Baseline value described in chapter 15 and used in LTA test (see section 10.4.3.1)

Effl Amount    If 'Effl Meas type' is 'NC', this value is the measured (detected) pollutant concentration at the effluent
              sample point Otherwise, if 'Effl Meas type' is 'ND,' this value is the sample-specific detection limit for
              the non-detected measurement.

Effl Meas type  Identifies whether the 'Effl Amount' was detected (non-censored ('NC')) or non-detected ('ND')

Infl Amount    If 'Infi Meas type' is 'NC', this value is the measured (detected) pollutant concentration at the influent
              sample point Otherwise, if 'Infl Meas type' is 'ND', this value is the sample-specific detection limit for
              the non-detected measurement.

Infl Meas type  Identifies whether the 'Infl Amount' was detected (non-censored ('NC')) or non-detected ('ND').

Infl Samp Pt    Influent Sample Point

Use_Data     If the result is 'Y', then the data passed the LTA test described in section 10.4.3.1. If the result is 'N',
              then the data failed the LTA test.

Fac. Eff Mean  The effluent long-term average calculated as described in chapter 10.

Fac. InfMean  The influent long-term average calculated as described in chapter 10.

Regulate        If the result is 'N,' then EPA did not propose limitations for the pollutant If the result is ' Y', EPA may
               or may not have proposed limitations and standards for this pollutant If the result is ' Y' and
               Use_Data='Y' and the facility's percent removals were greater than or equal to zero, then the facility
               data set pollutant was used in developing group variability factors.	
                                          Appendix C-l

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                                                          Appendix

                                                                D

          FACILITY-SPECIFIC COMPLIANCE COSTS

    This appendix presents EPA's estimate of costs to individual CWT facilities to comply with the
    applicable proposed limitations and standards. Chapter 11 of this document details the procedures
that EPA used to derive these cost estimates.
                            Appendix D - 1

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RCRA Costs
Plant # RCRACosts 1989$
9
11
16
17
22
36
37
49
59
60
64
67
71
72
75
76
80
81
88
89
90
98
99
100
103
104
105
118
119
125
129
130
132
133
134
135
138
144
173
30,000
0
0
0
30,000
30,000
0
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
0
Plant # RCRACostsl989$
184
203
216
230
231
255
256
257
279
284
288
294
296
298
302
323
367
378
388
398
409
449
450
451
452
700
707
708
724
731
733
738
740
744
746
753
754
764

30,000
0
30,000
0
0
30,000
30,000
30,000
30,000
30,000
30,000
30,000
0
30,000
0
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
30,000
0
0
0
30,000
30,000
30,000
0
0
0
0
30,000
0
30,000

Plant # RCRA Costs 1989$
776
777
787
789
793
795
803
804
805
814
815
817
818
819
821
839
840
843
848
850
851
852
869
875
876
883
902
907
912
924
928
930
933
936
937
945
950
951

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
30,000
0
0
0
0
30,000
30,000
0
30,000
30,000
0
0
0
0
30,000
30,000
0
0
0
0

Appendix D-18

-------
                                                                               Appendix
                                                                                      E
                                   ATTACHMENTS TO CHAPTER 10
     This Appendix presents Attachments 10-1 through 10-7 which supplement Chapter 10 - Long-Term
     Averages Variability Factors, and Limitations and Standards.  Attachment 10-1 presents the results of data
editing criteria.  Attachment 10-2 provides pollutant-specific  long-term averages  and  variability factors.
Attachment 10-3 provides the facility-specific long-term averages and variability factors. Attachment 10-4
shows the group variability factors. Attachment 10-5 provides the proposed limitations for each subcategory.
Attachment 10-6a presents group and pollutant variability factors listed by pollutant within each subcategory
and option. Attachment 10-6b presents group and pollutant variability factors listed by group within each
subcategory and option .  Finally, Attachment 10-7 provides limitations generated using pollutant and group
variability factors.
                           Chapter 10,  Attachments,  page 1

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                                                            Appendix
                           LISTING OF POLLUTANTS OF
                          CONCERN AND CAS NUMBERS
   This listing provides the pollutant name associated with each Chemistry Abstract Service (CAS) number. In other
   appendices and attachments in this document and in the record for the proposed.rulernaking, the complete CAS number
is provided with a truncated pollutant name. This listing can be used to identify the untruncated pollutant name.

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                                                 LIST OF DEFINITIONS
A

Administrator - The Administrator of the U.S. Environmental Protection Agency.

Agency - The U.S. Environmental Protection Agency.

Average Monthly Discharge Limitation - The highest allowable average of "daily discharges" over
a calendar month, calculated as the sum of all "daily discharges" measured during the calendar month
divided by the number of "daily discharges" measured during the month.

B

BAT - The best available technology economically achievable, applicable to effluent limitations to b
achieved by July 1, 1984, for industrial discharges to surface waters, as defined by Sec. 304(b)(2)(B)
oftheCWA.

BCT - The best conventional pollutant control technology, applicable to discharges of conventional
pollutants from existing industrial point sources, as defined by Sec. 304(b)(4) of the CWA.

BPT - The best practicable control technology currently available, applicable to effluent limitations to
be achieved by July 1,1977, for industrial discharges to surface waters, as defined by Sec. 304(b)(l) of
the CWA.
Centralized Waste Treatment Facility - Any facility that treats and/or recovers or recycles any
hazardous or non-hazardous industrial waste, hazardous or non-hazardous industrial wastewater, and/or
used material from off-site.

Centralized Waste Treatment Wastewater - Wastewater generated as a result of CWT activities.
CWT wastewater sources may include, but are not limited to: liquid waste receipts, solubilization water,
used oil emulsion-breaking wastewater, tanker truck/drum/roll-off box washes, equipment washes, air
pollution control scrubber blow-down, laboratory-derived wastewater, on-site industrial waste combustor
wastewaters, on-site landfill wastewaters, and contaminated stormwater.

Clean Water Act (CWA) - The Federal Water Pollution Control Act Amendments of 1972 (33 U.S.C.
Section 1251 et seq.X as amended by the Clean Water Act of 1977 (Pub. L. 95-217), and the Water

                                      Definitions-1

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Quality Act of 1987 (Pub. L. 100-4).

Clean Water Act (CWA) Section 308 Questionnaire - A questionnaire sent to facilities under the
authority of Section 308 of the CWA, which requests information to be used in the development of
national effluent guidelines and standards.

Commercial Facility - A CWT facility that accepts off-site generated wastes, wastewaters or used
material fiom other facilities not under the same ownership as this facility. Commercial operations are
usually made available for a fee or other remuneration.

Contaminated Storm Water - Storm water which comes in direct contact with the waste or waste
handling and treatment areas.

Conventional Pollutants - Constituents of wastewater as determined by Sec. 304(a)(4) of the CWA,
including, but not limited to, pollutants classified as biochemical oxygen demand, total suspended solids,
oil and grease, fecal coliform, and pH.

CWT - Centralized Waste Treatment.

n

Daily Discharge - The discharge of a pollutant measured during any calendar day or any 24-hour period
that reasonably represents a calendar day.

Detailed Monitoring Questionnaire (DMQ) - Questionnaires sent to collect monitoring data from 20
selected CWT facilities based on responses to the Section 308 Questionnaire.

Direct Discharger - A facility that discharges or may discharge treated or untreated wastewaters into
waters of the United States.

E

Effluent Limitation- Any restriction, including schedules of compliance, established by a State or the
Administrator on quantities, rates, and concentrations of chemical, physical, biological, and other
constituents which are discharged from point sources into navigable waters, the waters of the contiguous
zone, or the ocean.  (CWA Sections 301(b) and 304(b).)    .

Existing Source - Any facility from which there is or may be a discharge of pollutants, the construction
of which is commenced before the publication of the proposed regulations prescribing a standard of
performance under Sec. 306 of the CWA.
                                         Defmitions-2

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Facility - All contiguous property owned, operated, leased or under the control of the same person or
entity                                   .

Fuel Blending - The process of mixing waste, wastewater, or used material for the purpose of
regenerating a fuel for re-use.

H
                          *
Hazardous Waste - Any waste, including wastewater, defined as hazardous under RCRA, TSCA, or
any state law.

High Temperature Metals Recovery (HTMR) - A metals recovery process in which solid forms of
metal containing materials are processed with a heat-based pyrometallurgical technology to produce
remelt alloy which can then be sold as feed material in the production of metals.
In-scope - Facilities and/or wastewaters that EPA proposes to be subject to this guideline.

Indirect Discharger - A facility that discharges or may discharge wastewaters into a publicly-owned
treatment works.

Intercompany - Facilities that treat and/or recycle/recover waste, wastewater, and/or used material
generated by off-site facilities not under the same corporate ownership. These facilities are also referred
to as "commercial" CWTs.

Intracompany Transfer - Facilities that treat and/or recycle/recover waste, wastewater, and/or used
material generated by off-site facilities under the same corporate ownership.  These facilities are also
referred to as "non-commercial" CWTs.
LTA - Long-Term Average.  For purposes of the effluent guidelines, average pollutant levels achieved
over a period of time by a facility, subcategory, or technology option. LTAs were used in developing
the limitations and standards in today's proposed regulation.

M

Marine-generated Waste - Waste, wastewater, and/or used material generated as part of the normal
maintenance and operation of a ship, boat, or barge operating on inland, coastal, or open waters.
                                        Defmitions-3

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Metal-bearing Wastes - Wastes and/or used materials that contain metal pollutants from manufacturing
or processing facilities or other commercial operations. These wastes may include, but are not limited
to, the following: process wastewater, process residuals such as tank bottoms or stills, and process
wastewater treatment residuals such as treatment sludges.

Minimum Level - the lowest level at which the entire analytical system must give a recognizable signals
and an acceptable calibration point for the analyte.

Mixed Commercial/Non-commercial Facility - Facilities that treat and/or recycle/recover waste,
wastewater, and/or used material generated by off-site facilities both under the same corporate ownership
and different corporate ownership.

N

National Pollutant Discharge Elimination System  (NPDES) Permit - A  permit to discharge
wastewater into waters of the United States issued under the National Pollutant Discharge Elimination
system, authorized by  Section 402 of the CWA.

New Source- Any facility from which there is or may be a discharge of pollutants, the construction of
which is  commenced after the proposal of regulations prescribing a standard of performance under
section 306 of the Act and 403.3(k).

Non-commercial Facility - Facilities that accept waste from off-site for treatment and/or recovery from
generating facilities under the same corporate ownership as the CWT facility.

Non-contaminated Stormwater - Storm water which does not come into direct contact with the waste
or waste handling and treatment areas.

Non-conventional Pollutants - Pollutants that are neither conventional pollutants nor priority pollutants
listed at 40 CFR Section 401.

Non-detect Value - the analyte is below the level of detection that can be reliably measured by the
analytical method. This is also known, in statistical terms, as left-censoring.

Non-water Quality Environmental Impact - Deleterious aspects of control and treatment technologies
applicable to point source category wastes, including, but not limited to air pollution, noise, radiation,
sludge and solid waste generation, and energy used.

NSPS - New Sources Performance Standards, applicable to  industrial facilities whose construction is
begun after the publication of the proposed regulations, as defined by Sec. 306 of the CWA.
                                        Definitions-4

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 o

 OCPSF - Organic chemicals, plastics, and synthetic fibers manufacturing point source category. (40
 CFR Part 414).

 Off Site - Outside the boundaries of a facility.

 Oily Wastes - Wastes and/or used  materials that contain oil and grease from manufacturing or
 processing facilities or other commercial operations. These wastes may include, but are not limited to,
 the following: spent lubricants,  cleaning fluids, process wastewater, process residuals such as tank
 bottoms or stills and process wastewater treatment residuals, such as treatment sludges.

 Oligopoly - A market structure with few  competitors, in which each  producer  is aware of his
 competitors' actions and has a significant influence on market price and quantity.

 On Site - The same or geographically contiguous property, which may be divided by a public or private
 right-of-way, provided the entrance and exit between the properties is at a crossroads intersection, and
 access is by crossing as opposed to going along the right-of-way. Non-contiguous properties owned by
 the same company or locality but connected by a right-of-way, which it controls, and to which the public
 does not have access, is also considered on-site property.

 Organic-bearing Wastes - Wastes  and/or used materials that  contain organic  pollutants from
 manufacturing or processing facilities or other commercial operations. These wastes may include, but
 are not limited to, process wastewater, process residuals such as tank bottoms or stills and process
 wastewater treatment residuals, such as treatment sludges.

 Outfall - The mouth of conduit drains and other conduits from which a facility effluent discharges into
 receiving waters.

 Out-of-scope - Out-of-scope facilities are facilities which only perform centralized  waste treatment
 activities  which EPA has not proposed to be subject to provisions of this guideline., Out-of-scope
 operations are centralized waste treatment operations which EPA has not proposed to be subject to
provisions of this guideline.
Pipeline - "Pipeline" means an open or closed conduit used for the conveyance of material. A pipeline
includes a channel, pipe, tube, trench, ditch or fixed delivery system.

Pass Through - A pollutant is determined to "pass through" a POTW when the average percentage
removed by an efficiently operated POTW is less than the average percentage removed by the industry's
direct dischargers that are using well-defined, well-operated BAT technology.
                                        Definitions-5

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Point Source - Any discernable, confined, and discrete conveyance from which pollutants are or may
be discharged.

Pollutants of Concern (POCs) - Pollutants commonly found  in  centralized  waste  treatment
wastewaters.  For the purposes of this guideline, a POC is a pollutant that is detected three or more
times above a treatable level in influent wastewater samples from centralized waste treatment facilities.
Additionally, a CWT POC must be present in at least ten percent of the influent wastewater samples.

Priority Pollutant - One hundred twenty-six compounds that are a subset of the 65 toxic pollutants and
classes of pollutants outlined in Section 307 of the CWA. The priority pollutants are specified in the
NRDC settlement agreement (Natural Resources Defense Council et al v. Train, 8 E.R.C. 2120 [D.D.C.
1976], modified 12E.R.C. 1833 p.D.C. 1979]).

Product Stewardship - A program practiced by many manufacturing facilities which involves taking
back spent, used, or unused products, shipping and storage containers with product residues, off-
specification products and waste materials from use of products.

PSES  - Pretreatment standards for existing sources of indirect discharges, under Sec. 307(b) of the
CWA.

PSNS - Pretreatment standards for new sources of indirect discharges, under Sec. 307(b) of the CWA.

Publicly Owned Treatment Works (POTW) - Any device or system, owned by a state or municipality,
used in the treatment (including recycling and reclamation) of municipal sewage or industrial wastes of
a liquid nature that is owned by a state or municipality.  This includes  sewers, pipes, or other
conveyances only if they convey wastewater to a POTW providing treatment (40 CFR 122.2).

R

RCRA - The Resource Conservation and Recovery Act of 1976 (RCRA) (42 U.S.C. Section 6901 et
seq.). which regulates the generation, treatment, storage, disposal, or recycling of solid and hazardous
wastes.

Re-refining - Distillation, hydrotreating, and/or other treatment employing acid, caustic, solvent, clay
and/or chemicals of used oil in order to produce high quality base stock for lubricants or other petroleum
products.
SIC - Standard Industrial Classification (SIC). A numerical categorization system used by the U.S.
Department of Commerce to catalogue economic activity. SIC codes refer to the products, or group of
products, produced or distributed, or to services rendered by an operating establishment.  SIC codes are
used to group establishments by the economic activities in which they are engaged.  SIC codes often
denote a facility's primary, secondary, tertiary,  etc. economic activities.

                                        Definitions-6

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Small-business - Businesses with annual sales revenues less than $6 million. This is the Small Business
Administration definition of small business for SIC code 4953, Refuse Systems (13 CFR Ch.l, 
121.601) which is being used to characterize the CWT industry.

Solidification - The addition of sorbents to convert liquid or semi-liquid waste to a solid by means of
adsorption, absorption or both. The process is usually accompanied by stabilization.

Stabilization - A waste process that decreases the mobility of waste constituents by means of a chemical
reaction. For the purpose of this rule, chemical precipitation is not a technique for stabilization.

V

Variability Factor - used in calculating a limitation (or standard) to allow for reasonable variation in
pollutant concentrations when processed through extensive and well  designed treatment systems.
Variability factors assure that normal fluctuations in a. facility's treatment are accounted for in the
limitations.  By accounting for these reasonable excursions above the long-term average, EPA's use of
variability factors results in limitations that are generally well above the actual long-term averages.

w

Waste Receipt - Wastes,  wastewater or used material received for treatment and/or recovery.  Waste
receipts can be liquids or solids.
Zero or Alternative Discharge - No discharge of pollutants to waters of the United States or to a
POTW.  Also included in this definition are disposal of pollutants by way of evaporation, deep-well
injection, off-site transfer, and land application.
                                        Definitions-?

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                                                LIST OF ACRONYMS
A

AMSA: Association of Municipal Sewage
        Authorities

API:    American Petroleum Institute

B

BAT:   Best Available Technology
        (Economically Achievable)

BCT:   Best Conventional (Pollutant Control
        Technology

BDAT:  Best Demonstrated Available
        (Treatment) Technology

BOD:   Biological Oxygen Demand

BPJ:    Best Professional Judgement

BPT:    Best Practicable (Control) Technolog
        (Currently Available)
c
CBI:
Confidential Business Information
CERCLA: Comprehensive Environmental
          Response, Compensation, and
          Liability Act

CMA:   Chemical Manufacturers Association

COD:   Chemical Oxygen Demand

CWA:   Clean Water Act

CWT:   Centralized Waste Treatment
D

DAF:   Dissolved Air Flotation

DL:    Detection Limit

DMQ:  Detailed Monitoring Questionnaire

E

EAD:   Engineering and Analysis Division

ELG:   Effluent Limitations Guidelines

ENR:   Engineering News Record

EPA:   Environmental Protection Agency

F

F/M:    Food-to-microorganism (ratio)

G

GAC:   Granular Activated Carbon

GC/ECD:  Gas Chromatography/Electron
          Capture Detector

GFAA:  Graphite Furnace Atomic Absorption

H

HAP:   Hazardous Air Pollutant

HEM:   Hexane-Extractable Material

HSWA:   Hazardous and Solid Waste
          Amendments
                                           HTMR: High Temperature Metals Recovery

                                    Acronyms-1

-------
ICP:    Inductively Coupled Plasma (Atomic
        Emission Spectroscopy)

IDL:    Instrument Detection Limit

L

LDR:   Land Disposal Restriction

LTA:   Long-term Average
MACT: Maximum Achievable Control
        Technology

MADL: Minimum Analytical Detection Limit

MGD:  Million Gallons per Day

MIP:   Monitoring-in-place

ML:    Minimum Level

MLSS:  Mixed Liquor Suspended Solids

MNC:  Mean Non-censored (Value)


H

ND:    Non-detected

NOA:  Notice of (Data) Availability

NORA: National Oil Recyclers Association

NPDES:   National Pollutant Discharge
           Elimination System

NRDC: Natural Resources Defense Council

NRMRL:  National Risk Management
           Research Laboratory; formerly
           RREL

NSPS:  New Source Performance Standards
NSWMA: National Solid Waste Management
          Association

o

O&M:  Operation and Maintenance

OCPSF:   Organic Chemicals, Plastics, and
          Synthetic Fibers

OMB:  Office of Management and Budget


E

PAC:

POC:

POTW:

PSES:
Powdered Activated Carbon

Pollutant of Concern

Publicly Owned Treatment Works
PSNS:
Pretreatment Standards for Existing
Sources

Pretreatment Standards for New
Sources
Q

QC:    Quality Control

R

RCRA: Resource Conservation and Recovery
        Act
RO:
Reverse Osmosis
RREL: Risk Reduction Engineering
        Laboratory; now known as NRMRL
 SBA:   Small Business Administration

 SBR:   Sequencing Batch Reactor

 SBREFA:  Small Business Regulatory
           Flexibility Act
                                      Acronyms-2

-------
 SGT-HEM:    Silica Gel-Treated Hexane-
               Extractable Material

 SIC:    Standard Industrial Code

 SRT:    Sludge Retention Time

 I

 TDS:    Total Dissolved Solids

 TEC:    Transportation Equipment Cleaning

 TOC:    Total Organic Carbon

 TSDF:   Treatment, Storage, and Disposal
         Facility

 TSS:    Total Suspended Solids

 TWF:    Toxic Weighting Factor

 u

 UF:      Ultrafiltration

 UIC:    Underground Injection Control

 UTS:    Universal Treatment Standards

Y

VOC:    Volatile Organic Compound

 w

WTI:    Waste Treatment Industry
                                      Acronyms-3

-------

-------

-------

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