&EPA
United States
Environmental Protection
Agency
Office of Water
4304
EPA 822-B-00-020
December 2000
Ambient Water Quality
Criteria Recommendations
Information Supporting the Development
of State and Tribal Nutrient Criteria
Rivers and Streams in
Nutrient Ecoregion XI
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EPA 822-B-00-020
AMBIENT WATER QUALITY CRITERIA RECOMMENDATIONS
INFORMATION SUPPORTING THE DEVELOPMENT OF STATE AND TRIBAL
NUTRIENT CRITERIA
FOR
RIVERS AND STREAMS IN NUTRIENT ECOREGION XI
The Central and Eastern Forested Uplands
including all or parts of the States of
Pennsylvania, Ohio, West Virginia, Virginia, Tennessee, North Carolina, Kentucky, Alabama,
Georgia, Missouri, Arkansas, Oklahoma, South Carolina, New Jersey, New York
and the Tribes within the Ecoregion
U.S. ENVIRONMENTAL PROTECTION AGENCY
OFFICE OF WATER
OFFICE OF SCIENCE AND TECHNOLOGY
HEALTH AND ECOLOGICAL CRITERIA DIVISION
WASHINGTON, D.C.
DECEMBER 2000
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FOREWORD
This document presents EPA's nutrient criteria for Rivers and Streams in Nutrient
Ecoregion XI. These criteria provide EPA's recommendations to States and authorized Tribes
for use in establishing their water quality standards consistent with section 303(c) of CWA.
Under section 303(c) of the CWA, States and authorized Tribes have the primary responsibility
for adopting water quality standards as State or Tribal law or regulation. The standards must
contain scientifically defensible water quality criteria that are protective of designated uses.
EPA's recommended section 304(a) criteria are not laws or regulations - they are guidance that
States and Tribes may use as a starting point for the criteria for their water quality standards.
The term "water quality criteria" is used in two sections of the Clean Water Act, Section
304(a)(l) and Section 303(c)(2). The term has a different impact in each section. In Section 304,
the term represents a scientific assessment of ecological and human health effects that EPA
recommends to States and authorized Tribes for establishing water quality standards that
ultimately provide a basis for controlling discharges or releases of pollutants or related
parameters. Ambient water quality criteria associated with specific waterbody uses when
adopted as State or Tribal water quality standards under Section 303 define the level of a
pollutant (or, in the case of nutrients, a condition) necessary to protect designated uses in ambient
waters. Quantified water quality criteria contained within State or Tribal water quality standards
are essential to a water quality-based approach to pollution control. Whether expressed as
numeric criteria or quantified translations of narrative criteria within State or Tribal water quality
standards, quantified criteria serve as a critical basis for assessing attainment of designated uses
and measuring progress toward meeting the water quality goals of the Clean Water Act.
EPA is developing section 304(a) water quality criteria for nutrients because States and
Tribes consistently identify excessive levels of nutrients as a major reason why as much as half of
the surface waters surveyed in this country do not meet water quality objectives, such as full
support of aquatic life. EPA expects to develop nutrient criteria that cover four major types of
waterbodies - lakes and reservoirs, rivers and streams, estuarine and coastal areas, and wetlands -
across fourteen major ecoregions of the United States. EPA's section 304(a) criteria are
intended to provide for the protection and propagation of aquatic life and recreation. To support
the development of nutrient criteria, EPA is publishing Technical Guidance Manuals that describe
a process for assessing nutrient conditions in the four waterbody types.
EPA's section 304(a) water quality criteria for nutrients provide numeric water quality
criteria, as well as procedures by which to translate narrative criteria within State or Tribal water
quality standards. In the case of nutrients, EPA section 304(a) criteria establish values for causal
variables (e.g., total nitrogen and total phosphorus) and response variables (e.g., turbidity and
chlorophyll a). EPA believes that State and Tribal water quality standards need to include
quantified endpoints for causal and response variables to provide sufficient protection of uses and
to maintain downstream uses. These quantified endpoints will most often be expressed as
numeric water quality criteria or as procedures to translate a State or Tribal narrative criterion
into a quantified endpoint.
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EPA will work with States and authorized Tribes as they adopt water quality criteria for
nutrients into their water quality standards. EPA recognizes that States and authorized Tribes
require flexibility in adopting numeric nutrient criteria into State and Tribal water quality
standards. States and authorized Tribes have several options available to them. EPA
recommends the following approaches, in order of preference:
(1) Wherever possible, develop nutrient criteria that fully reflect localized conditions and
protect specific designated uses using the process described in EPA's Technical Guidance
Manuals for nutrient criteria development. Such criteria may be expressed either as
numeric criteria or as procedures to translate a State or Tribal narrative criterion into a
quantified endpoint in State or Tribal water quality standards.
(2) Adopt EPA's section 304(a) water quality criteria for nutrients, either as numeric
criteria or as procedures to translate a State or Tribal narrative nutrient criterion into a
quantified endpoint.
(3) Develop nutrient criteria protective of designated uses using other scientifically
defensible methods and appropriate water quality data.
Geoffrey H. Grubbs, Director
Office of Science and Technology
in
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DISCLAIMER
This document provides technical guidance and recommendations to States, authorized
Tribes, and other authorized jurisdictions to develop water quality criteria and water quality
standards under the Clean Water Act (CWA) to protect against the adverse effects of nutrient
overenrichment. Under the CWA, States and authorized Tribes are to establish water quality
criteria to protect designated uses. State and Tribal decision-makers retain the discretion to adopt
approaches on a case-by-case basis that differ from this guidance when appropriate and
scientifically defensible. While this document contains EPA's scientific recommendations
regarding ambient concentrations of nutrients that protect aquatic resource quality, it does not
substitute for the CWA or EPA regulations; nor is it a regulation itself. Thus it cannot impose
legally binding requirements on EPA, States, authorized Tribes, or the regulated community, and
it might not apply to a particular situation or circumstance. EPA may change this guidance in the
future.
IV
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EXECUTIVE SUMMARY
Nutrient Program Goals
EPA developed the National Strategy for the Development of Regional Nutrient Criteria
(National Strategy) in June 1998. The strategy presents EPA=s intentions to develop technical
guidance manuals for four types of waters (lakes and reservoirs, rivers and streams, estuaries and
coastal waters, and wetlands) and produce section 304(a) criteria for specific nutrient ecoregions
by the end of 2000. In addition, the Agency formed Regional Technical Assistance Groups
(RTAGs) which include State and Tribal representatives working to develop more refined and
more localized nutrient criteria based on approaches described in the waterbody guidance
manuals. This document presents EPA=s current recommended criteria for total phosphorus, total
nitrogen, chlorophyll a, and turbidity for rivers and streams in Nutrient Ecoregion XI (Central and
Eastern Forested Uplands) which were derived using the procedures described in the Rivers and
Streams Nutrient Criteria Technical Guidance Manual (U.S. EPA, 2000b).
EPA's ecoregional nutrient criteria are intended to address cultural eutrophication— the
.adverse effects of excess nutrient inputs. The criteria are empirically derived to represent
conditions of surface waters that are minimally impacted by human activities and protective of
aquatic life and recreational uses. The information contained in this document represent starting
points for States and Tribes to develop (with assistance from EPA) more refined nutrient criteria.
In developing these criteria recommendations, EPA followed a process which included, to
the extent they were readily available, the following elements critical to criterion derivation:
! Historical and recent nutrient data in Nutrient Ecoregion XI.
Data sets from Auburn University, Legacy STORET, New York State Department of
Environmental Conservation (NYSDEC), EPA Region 3, and EPA Region 4 were used to
assess nutrient conditions from 1990 to 1998.
! Reference sites/reference conditions in Nutrient Ecoregion XI.
Reference conditions presented in this document were calculated statistically using the 25th
percentile of the entire nutrient database for each nutrient parameter, including a
comparison of reference condition for the aggregate ecoregion versus the sub ecoregions.
States and Tribes are urged to determine their own reference sites for rivers and streams
.within the ecoregion at different geographic scales and to compare them to EPA's
reference conditions.
! Models employed for prediction or validation
EPA did not identify any specific models used in the ecoregion to develop nutrient
criteria. States and Tribes are encouraged to identify and apply appropriate models to
support nutrient criteria development.
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! RTAG expert review and consensus
EPA recommends that when States and Tribes prepare their nutrient criteria, they obtain
the expert review and consent of the RTAG.
! Downstream effects of criteria.
EPA encourages the RTAG to assess the potential effects of the proposed criteria on
downstream water quality and uses.
In addition, EPA followed specific QA/QC procedures during data collection and analysis.
All data were reviewed for duplications. All data are from ambient waters that were not located
directly outside a permitted discharger. The following States indicated that their data was
sampled and analyzed using either Standard Methods or EPA-approved methods: Georgia,
Maryland, Missouri, New York, New Jersey, N. Carolina, Ohio, S. Carolina and West Virginia.
The following tables contain a summary of Aggregate and level III ecoregion values for
TN, TP, water column chl a, and turbidity:
BASED ON 25th PERCENTILES ONLY
Nutrient Parameters
Total phosphorus (|ig/L)
Total nitrogen (mg/L)
Chlorophyll a (|ig/L) (Spec)
Turbidity (NTU)
Turbidity (FTU)
Aggregate Nutrient Ecoregion XI
Reference Conditions
10.00
0.31
1.61
2.3
1.7
VI
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For subecoregions 36, 38, 39, 66, 67, 68, 69, and 70 the ranges of nutrient parameter reference
conditions are:
BASED ON 25th PERCENTILE ONLY
Nutrient Parameters
Total phosphorus (|ig/L)
Total nitrogen (mg/L)
Chlorophyll a (|ig/L) (Spec)
Turbidity (NTU)
Turbidity (FTU)
Range of Level III Subecoregions
Reference Conditions
5.63
0.21
0.25
1.0-
1.68
- 10.47
-0.58
-3.26
5.2
-6.75
Vll
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NOTICE OF DOCUMENT AVAILABILITY
This document is available electronically to the public through the INTERNET at:
(http://www.epa.gov/OST/standards/nutrient.html). Requests for hard copies of the document
should be made to EPA's National Service Center for Environmental Publications (NSCEP),
11029 Kenwood Road, Cincinnati, OH 45242 or (513) 489-8190 or toll free (800) 490-9198.
Please refer to EPA document number EPA-822-B-00-020.
Vlll
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ACKNOWLEDGMENTS
The authors thankfully acknowledge the contributions of the following State and Federal
reviewers: EPA Regions 3, 4, 5, and 6; the States of Pennsylvania, Ohio, West Virginia, Virginia,
Tennessee, North Carolina, Kentucky, Alabama, Georgia, Mississippi, Arkansas and Oklahoma;
the Tribes within the Ecoregion; EPA Headquarters personnel from the Office of Wetlands,
Oceans and Watersheds, Office of Wastewater Management, Office of General Counsel, Office of
Research and Development, and the Office of Science and Technology. EPA also acknowledges
the external peer review efforts of Eugene Welch (University of Washington), Robert Carlson
(Kent State University), Steve Heiskary (Minnesota Pollution Control Agency), Greg Denton and
Sherry Wang (Tennessee Department of Environment and Conservation), and Gerhard Kuhn
(U.S. Geological Survey).
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LISTS OF TABLES AND FIGURES
Figures
Figure 1
Figure 2
Figure 3
Figure 4a
Figure 4b
Tables
Table 1
Table 2
Table 3a-h
Aggregate Ecoregion XI
Aggregate Ecoregion XI with level III ecoregions shown
Sampling locations within each level III ecoregion 11
Illustration of data reduction process for stream data 21
Illustration of reference condition calculation 22
Rivers and Streams records for Aggregate Ecoregion XI:
Central and Eastern Forested Uplands
Reference conditions for Aggregate Ecoregion XI streams
12
15
Reference conditions for level III ecoregion streams 16
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TABLE OF CONTENTS
Foreword ii
Disclaimer iv
Executive Summary v
Notice of Document Availability viii
Acknowledgments ix
List of Tables and Figures x
Table of Contents xi
1.0 Introduction 1
2.0 Best Use of this Information 4
3.0 Area Covered by This Document (waterbody type and ecoregion) 6
3.1 Description of Aggregate Ecoregion XI 6
3.2 Geographical Boundaries of Aggregate Ecoregion XI 6
3.3 Level III Ecoregions within Aggregate Ecoregion XI 6
4.0 Data Review for Rivers and Streams in Aggregate Ecoregion XI 9
4.1 Data Sources 9
4.2 Historical Data from Aggregate Ecoregion XI 10
4.3 QA/QC of Data Sources 10
4.4 Data for All Rivers/Streams within Aggregate Ecoregion XI 10
4.5 Statistical Analysis of Data 10
4.6 Classification of River/Stream Type 20
4.7. Summary of Data Reduction Methods 20
5.0 Reference Sites and Conditions in Aggregate Ecoregion XI 24
6.0 Models Used to Predict or Verify Response Parameters 24
7.0 Framework for Refining Recommended Nutrient Criteria for Rivers and Streams in
Aggregate Ecoregion XI 24
7.1 Example Worksheet for Developing Aggregate Ecoregion
and Subecoregion Nutrient Criteria 25
7.2 Tables of Refined Nutrient Water Quality Criteria for Aggregate
Ecoregion XI and Level III Subecoregions 26
7.3 Setting Seasonal Criteria 27
xi
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7.4 When Data/Reference Conditions Are Lacking 27
7.5 Site-Specific Criteria Development 27
8.0 Literature Cited 28
9.0 Appendices 28
xn
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1.0 INTRODUCTION
Background
Nutrients are essential to the health and diversity of our surface waters. However, in
excessive amounts, nutrients cause hypereutrophication, which results in overgrowth of plant life
and decline of the biological community. Excessive nutrients can also result in potential human
health risks, such as the growth of harmful algal blooms - most recently manifested in the
Pfiesteria outbreaks of the Gulf and East Coasts. Chronic nutrient over enrichment of a
waterbody can lead to the following consequences: low dissolved oxygen, fish kills, algal blooms,
overabundance of macrophytes, likely increased sediment accumulation rates, and species shifts of
both flora and fauna.
Historically, National Water Quality Inventories have repeatedly shown that nutrients are a
major cause of ambient water quality use impairments. EPA's 1996 National Water Quality
Inventory report identifies excessive nutrients as the leading cause of impairment in lakes and the
second leading cause of impairment in rivers (behind siltation). In addition, nutrients were the
second leading cause of impairments reported by the States in their 1998 lists of impaired waters.
Where use impairment is documented, nutrients contribute roughly 25-50% of the impairment
nationally. The Clean Water Act establishes a national goal to achieve, wherever attainable, water
quality which provides for the protection and propagation offish, shellfish, and wildlife and
recreation in and on the water. In adopting water quality standards, States and Tribes designate
uses for their waters in consideration of the Clean Water Act goals, and establish water quality
criteria that contain sufficient parameters to protect those uses. To date, EPA has not published
information and recommendations under section 304(a) for nutrients to assist States and Tribes in
establishing numeric nutrient criteria to protect uses when adopting water quality standards.
In 1995, EPA gathered a set of national experts and asked the experts how to best deal
with the national nutrient problem. The experts recommended that the Agency not develop single
criteria values for phosphorus or nitrogen applicable to all water bodies and regions of the
country. Rather, the experts recommended that EPA put a premium on regionalization, develop
guidance (assessment tools and control measures) for specific waterbodies and ecological regions
across the country, and use reference conditions (conditions that reflect pristine or minimally
impacted waters) as a basis for developing nutrient criteria.
With these suggestions as starting points, EPA developed the National Strategy for the
Development of Regional Nutrient Criteria (National Strategy), published in June 1998. This
strategy presented EPA's intentions to develop technical guidance manuals for four types of
waters (lakes and reservoirs, rivers and streams, estuaries and coastal waters, and wetlands) and,
thereafter, to publish section 304(a) criteria recommendations for specific nutrient ecoregions.
Technical guidance manuals for lakes/reservoirs and rivers/streams were published in April 2000
and July 2000, respectively. The technical guidance manual for estuaries/coastal waters will be
published in spring 2000 and the draft wetlands technical guidance manual will be published by
December 2001. Each manual presents EPA's recommended approach for developing nutrient
criteria values for a specific waterbody type. In addition, EPA is committed to working with
States and Tribes to develop more refined and more localized nutrient criteria based on
approaches described in the waterbody guidance manuals and this document.
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Overview of the Nutrient Criteria Development Process
For each Nutrient Ecoregion, EPA developed a set of recommendations for two causal
variables (total nitrogen and total phosphorus) and two early indicator response variables
(chlorophyll a and some measure of turbidity). Other indicators such as dissolved oxygen and
macrophyte growth or speciation, and other fauna and flora changes are also deemed useful.
However, the first four are considered to be the best suited for protecting designated uses.
The technical guidance manuals describe a process for developing nutrient criteria that
involves consideration of five factors. The first of these is the Regional Technical Assistance
Group (RTAG), which is a body of qualified regional specialists able to objectively evaluate all of
the available evidence and select the value(s) appropriate to nutrient control in the water bodies of
concern. These specialists may come from such disciplines as limnology, biology, natural
resources management- especially water resource management, chemistry, and ecology. The
RTAG evaluates and recommends appropriate classification techniques for criteria determination,
usually physical within an ecoregional construct.
The second factor is the historical information available to establish a perspective of the
resource base. This is usually data and anecdotal information available within the past ten-twenty
five years. This information gives evidence about the background and enrichment trend of the
resource.
The third factor is the present reference condition. A selection of reference sites chosen to
represent the least culturally impacted waters of the class existing at the present time. The data
from these sites is combined and a value from the distribution of these observations is selected to
represent the reference condition, or best attainable, most natural condition of the resource base at
this time.
A fourth factor often employed is theoretical or empirical models of the historical and
reference condition data to better understand the condition of the resource.
The RTAG comprehensively evaluates the other three elements to propose a candidate
criterion (initially one each for TP, TN, chl a, and some measure of turbidity).
The last and final element of the criteria development process is the assessment by the
RTAG of the likely downstream effects of the criterion. Will there be a negative, positive, or
neutral effect on the downstream waterbody? If the RTAG judges that a negative effect is likely,
then the proposed State/Tribal water quality criteria should be revised to ameliorate the potential
for any adverse downstream effects.
While States and authorized Tribes would not necessarily need to incorporate all five
elements into their water quality criteria setting process (e.g., modeling may be significant in only
some instances), the best assurance of a representative and effective criterion for nutrient
management decision making is the balanced incorporation of all five elements, or at least all
elements except modeling.
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Because some parts of the country have naturally higher soil and parent material
enrichment, and different precipitation regimes, the application of the criterion development
process has to be adjusted by region. Therefore, an ecoregional approach was chosen to develop
nutrient criteria appropriate to each of the different geographical and climatological areas of the
country. Initially, the continental U.S. was divided into 14 separate ecoregions of similar
geographical characteristics. Ecoregions are defined as regions of relative homogeneity in
ecological systems; they depict areas within which the mosaic of ecosystem components (biotic
and abiotic as well as terrestrial and aquatic) is different than adjacent areas in a holistic sense.
Geographic phenomena such as soils, vegetation, climate, geology, land cover, and physiology
that are associated with spatial differences in the quantity and quality of ecosystem components
are relatively similar within each ecoregion.
The Nutrient ecoregions are aggregates of U.S. EPA=s hierarchal level III ecoregions. As
such, they are more generalized and less defined than level III ecoregions. EPA determined that
setting ecoregional criteria for the large scale aggregates is not without its drawbacks - variability
is high due to the lumping of many waterbody classes, seasons, and years worth of multipurpose
data over a large geographic area. For these reasons, the Agency recommends that States and
Tribes develop nutrient criteria at the level III ecoregional scale and at the waterbody class scale
where those data are readily available. Data analyses and recommendations on both the large
aggregate ecoregion scale as well as more refined scales (level III ecoregions and waterbody
classes), where data were available to make such assessments, are presented for comparison
purposes and completeness of analysis.
Relationship of Nutrient Criteria to Biological Criteria
Biological criteria are quantitative expressions of the desired condition of the aquatic
community. Such criteria can be based on an aggregation of data from sites that represent the
least-impacted and attainable condition for a particular waterbody type in an ecoregion,
subecoregion, or watershed. EPA's nutrient criteria recommendations and biological criteria
recommendations have many similarities in the basic approach to their development and data
requirements. Both are empirically derived from statistical analysis of field collected data and
expert evaluation of current reference conditions and historical information. Both utilize direct
measurements from the environment to integrate the effects of complex processes that vary
according to type and location of waterbody. The resulting criteria recommendations, in both
cases, are efficient and holistic indicators of water quality necessary to protect uses.
States and authorized Tribes can develop and apply nutrient criteria and biological criteria
in tandem, with each providing important and useful information to interpret both the nutrient
enrichment levels and the biological condition of sampled waterbodies. For example, using the
same reference sites for both types of criteria can lead to efficiencies in both sample design and
data analysis. In one effort, environmental managers can obtain information to support
assessment of biological and nutrient condition, either through evaluating existing data sets or
through designing and conducting a common sampling program. The traditional biological
criteria variables of benthic invertebrate and fish sampling can be readily incorporated to
supplement a nutrient assessment. To demonstrate the effectiveness of this tandem approach,
EPA has initiated pilot projects in both freshwater and marine environments to investigate the
relationship between nutrient overenrichment and apparent declines in diversity indices of benthic
invertebrates and fish.
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2.0 BEST USE OF THIS INFORMATION
EPA recommendations published under section 304(a) of the CWA serve several
purposes, including providing guidance to States and Tribes in adopting water quality standards
for nutrients that ultimately provide a basis for controlling discharges or releases of pollutants.
The recommendations also provide guidance to EPA when promulgating Federal water quality
standards under section 303(c) when such action is necessary. Other uses include identification of
overenrichment problems, management planning, project evaluation, and determination of status
and trends of water resources.
State water quality inventories and listings of impaired waters consistently rank nutrient
overenrichment as a top contributor to use impairments. EPA's water quality standards
regulations at 40 CFR § 131.11 (a) require States and Tribes to adopt criteria that contain
sufficient parameters and constituents to protect the designated uses of their waters. In addition,
States and Tribes need quantifiable targets for nutrients in their standards to assess attainment of
uses, develop water quality-based permit limits and source control plans, and establish targets for
total maximum daily loads (TMDLs).
EPA expects States and Tribes to address nutrient overenrichment in their water quality
standards, and to build on existing State and Tribal initiated efforts where possible. States and
Tribes can address nutrient overenrichment through establishment of numerical criteria or through
use of new or existing narrative criteria statements (e.g., free from excess nutrients that cause or
contribute to undesirable or nuisance aquatic life or produce adverse physiological response in
humans, animals, or plants). In the case of narrative criteria, EPA expects that States and Tribes
establish procedures to quantitatively translate these statements for both assessment and source
control purposes.
The intent of developing ecoregional nutrient criteria is to represent conditions of surface
waters that are minimally impacted by human activities and thus protect against the adverse
effects of nutrient overenrichment from cultural eutrophication. EPA's recommended process for
developing such criteria includes physical classification of waterbodies, determination of current
reference conditions, evaluation of historical data and other information (such as published
literature), use of models to simulate physical and ecological processes or determine empirical
relationships among causal and response variables (if necessary), expert judgement, and
evaluation of downstream effects. To the extent allowed by the information available, EPA has
used elements of this process to produce the information contained in this document. The values
for both causal (total nitrogen, total phosphorus) and biological and physical response
(chlorophyll a, turbidity) variables represent a set of starting points for States and Tribes to use in
establishing their own criteria in standards to protect uses.
In its water quality standards regulations, EPA recommends that States and Tribes
establish numerical criteria based on section 304(a) guidance, section 304(a) guidance modified to
reflect site-specific conditions, or other scientifically defensible methods. For many pollutants,
such as toxic chemicals, EPA expects that section 304(a) guidance will provide an appropriate
level of protection without further modification in most cases. EPA has also published methods
for modifying 304(a) criteria on a site-specific basis, such as the water effect ratio, where site-
specific conditions warrant modification to achieve the intended level of protection. For nutrients,
however, EPA expects that, in most cases, it will be necessary for States and authorized Tribes to
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identify with greater precision the nutrient levels that protect aquatic life and recreational uses.
This can be achieved through development of criteria modified to reflect conditions at a smaller
geographic scale than an ecoregion such as a subecoregion, the State or Tribe level, or specific
class of waterbodies. Criteria refinement can occur by grouping data or performing data analyses
at these smaller geographic scales. Refinement can also occur through further consideration of
other elements of criteria development, such as published literature or models.
The values presented in this document generally represent nutrient levels that protect
against the adverse effects of nutrient overenrichment and are based on information available to
the Agency at the time of this publication. However, States and Tribes should critically evaluate
this information in light of the specific designated uses that need to be protected. For example,
more sensitive uses may require more stringent values as criteria to ensure adequate protection.
On the other hand, overly stringent levels of protection against the adverse effects of cultural
eutrophication may actually fall below levels that represent the natural load of nutrients for certain
waterbodies. In cases such as these, the level of nutrients specified may not be sufficient to
support a productive fishery. In the criteria derivation process, it is important to distinguish
between the natural load associated with a specific waterbody and current reference conditions,
using historical data and expert judgement. These elements of the nutrient criteria derivation
process are best addressed by States and Tribes with access to information and local expertise.
Therefore, EPA strongly encourages States and Tribes to use the information contained in this
document and to develop more refined criteria according to the methods described in EPA's
technical guidance manuals for specific waterbody types.
To assist in the process of further refinement of nutrient criteria, EPA has established ten
Regional Technical Advisory Groups (experts from EPA Regional Offices and States/Tribes). In
the process of refining criteria, States and authorized Tribes need to provide documentation of
data and analyses, along with a defensible rationale, for any new or revised nutrient criteria they
submit to EPA for review and approval. As part of EPA's review of State and Tribal standards,
EPA intends to seek assurance from the RTAG that proposed criteria are sufficient to protect
uses.
In the process of using the information and recommendations contained in this document,
as well as additional information, to develop numerical criteria or procedures to translate narrative
criteria, EPA encourages States and Tribes to:
• Address both chemical causal variables and early indicator response variables. Causal
variables are necessary to provide sufficient protection of uses before impairment occurs
and to maintain downstream uses. Early response variables are necessary to provide
warning signs of possible impairment and to integrate the effects of variable and
potentially unmeasured nutrient loads.
• Include variables that can be measured to determine if standards are met, and variables
that can be related to the ultimate sources of excess nutrients.
• Identify appropriate periods of duration (i.e., how long) and frequency (i.e., how often) of
occurrence in addition to magnitude (i.e., how much). EPA does not recommend
identifying nutrient concentrations that must be met at all times, rather a seasonal or
annual averaging period (e.g., based on weekly measurements) is considered appropriate.
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However, these seasonal or annual central tendency measures should apply each season or
each year, except under the most extraordinary of conditions (e.g., a 100 year flood).
3.0 AREA COVERED BY THIS DOCUMENT
The following sections provide a general description of the aggregate ecoregion and its
geographical boundaries. Descriptions of the level III ecoregions contained within the aggregate
ecoregion are also provided.
3.1 Description of Aggregate Ecoregion XI - Central and Eastern Forested Uplands
Ecoregion
The Central and Eastern Forested Uplands Ecoregion is disjunct and comprises most of
the unglaciated, forested low mountains and upland plateaus in the central and eastern United
States. It is underlain primarily by sedimentary and metasedimentary rocks and is characterized
by forests, high relief terrain, steep slopes, and high gradient streams. Region XI is higher and
more rugged than the neighboring Regions VI, VTI, IX, and X. Streams are generally faster
moving and clearer than the lower gradient streams of surrounding regions. Lakes are far less
common than in cooler, glaciated areas such as Region VIII. Dominant land uses in the Central
and Eastern Forested Uplands (XI) are logging, recreation, and grazing. The erosion hazard can
be severe on steep slopes if the soil or vegetation is disturbed by logging or road building. Land
slides and sheet flow have contributed sediments to streams which, in turn, have affected benthic
habitat, turbidity, hydrology, stream temperature, and stream biota. Coal mining is locally
common. It has contributed dissolved solids, suspended sediment, and acidic drainage to streams
which have, in turn, impacted fish and aquatic invertebrates. Cropland agriculture and urban
activity are generally less common than in nearby, lower and less-rugged regions; related water
quality issues such as nutrient runoff to streams is also less. Nevertheless, in Region XI, there are
a few urban areas as well as scattered croplands such as the Great Valley. Major poultry and
aquaculture operations are found in Region XI along with associated inputs of nutrients.
3.2 Geographical Boundaries of Ecoregion XI
Ecoregion XI has three separate lobes. The largest lobe encompasses a large portion of
Pennsylvania and West Virginia, also, relatively small sections of Virginia, North Carolina and
South Carolina. The western and southern borders of the ecoregion are in central Ohio, Kentucky
and Tennessee, and northern Alabama and Georgia, respectively. A second lobe includes the
southern half of Missouri, a section of northern Arkansas and a small corner of northeast
Oklahoma. The third lobe is the smallest area encompassing small sections of west-central
Arkansas and southeast Oklahoma.
3.3 Level III Ecoregions Within Aggregate Ecoregion XI
There are eight Level III ecoregions contained within Aggregate Ecoregion XI (Figure 2). The
following provides brief descriptions of the climate, vegetative cover, topography, and other
ecological information pertaining to these subecoregions.
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-Aggregate Nutrient Ecoregion 11
New York
.
Mississippi I. y s \ Georgia
Alabama
Figure 1. Aggregate Ecoregion XI.
Aggregate Nutrient Ecoregion 11
Ecoregion ID
Figure 2. Ecoregion XI with level III ecoregions shown
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36. Ouachita Mountains
The Ouachita Mountains ecological region is made up of sharply defined east-west trending
ridges, formed through erosion of compressed sedimentary rock formations. Once covered by
oak-hickory-pine forests, most of this region is now in loblolly and shortleaf pine. Commercial
logging is the major land use in the region.
37. Arkansas Valley
A region of mostly forested valleys and ridges, the physiography of the Arkansas Valley is much
less irregular than that of the Boston Mountains to the north and the Ouachita Mountains to the
south, but is more irregular than the ecological regions to the west and east. About one fourth of
the region is grazed and roughly one tenth is cropland. In the Arkansas Valley, even streams that
have been relatively unimpacted by human activities have considerably lower dissolved oxygen
levels, and hence support different biological communities, than those of most of the adjacent
regions.
39. Ozark Highlands
The Ozark Highlands ecoregion has a more irregular physiography and is generally more forested
than adjacent regions, with the exception of the Boston Mountains to the south. The majority of
this dissected limestone plateau is forested; oak-hickory is the predominant type, but stands of oak
and pine are also common. Less than one fourth of the core of this region has been cleared for
pasture and cropland, but half or more of the periphery, while not as agricultural as bordering
ecological regions, is in cropland and pasture.
66. Blue Ridge
The Blue Ridge extend from southern Pennsylvania to northern Georgia, varying from narrow
ridges to hilly plateaus to more massive mountainous areas with high peaks. The mostly forested
slopes, high-gradient, cool, clear streams, and rugged terrain occur on a mix of
igneous, metamorphic, and sedimentary geology. Annual precipitation of over 200 centimeters
can occur on the well-exposed high peaks of the Great Smoky Mountains that reach over 1830
meters. The southern Blue Ridge is one of the richest centers of biodiversity in the eastern U.S.
It is one of the most floristically diverse ecoregions, and includes Appalachian oak forests,
northern hardwoods, and Southeastern spruce-fir forests. Shrub, grass, and heath balds, hemlock,
cove hardwoods, and oak-pine communities are also significant.
67. Ridge and Valley
This northeast-southwest trending, relatively low-lying, but diverse ecoregion is sandwiched
between generally higher, more rugged mountainous regions with greater forest cover. As a
result of extreme folding and faulting events, the region's roughly parallel ridges and valleys have
a variety of widths, heights, and geologic materials, including limestone, dolomite, shale, siltstone,
sandstone, chert, mudstone, and marble. Springs and caves are relatively numerous. Present-day
forests cover about 50% of the region. The ecoregion has a diversity of aquatic habitats and
species offish.
68. Southwestern Appalachians
Stretching from Kentucky to Alabama, these open low mountains contain a mosaic of forest and
woodland with some cropland and pasture. The eastern boundary of the ecoregion in Tennessee,
along the more abrupt escarpment where it meets the Ridge and Valley, is relatively smooth and
-------
only slightly notched by small eastward flowing stream drainages. The western boundary, next to
the Interior Plateau's Eastern Highland Rim, is more crenulated, with a rougher escarpment that is
more deeply incised. The mixed mesophytic forest is restricted mostly to the deeper ravines and
escarpment slopes, and the upland forests are dominated by mixed oaks with shortleaf pine.
69. Central Appalachians
The Central Appalachian ecoregion, stretching from central Pennsylvania to northern Tennessee,
is primarily a high, dissected, rugged plateau composed of sandstone, shale, conglomerate, and
coal. The rugged terrain, cool climate, and infertile soils limit agriculture, resulting in a mostly
forested land cover. The high hills and low mountains are covered by a
mixed mesophytic forest with areas of Appalachian oak and northern hardwood forest.
Bituminous coal mines are common, and have caused the siltation and acidification of streams.
70. Western Allegheny Plateau
The hilly and wooded terrain of the Western Allegheny Plateau was not muted by glaciation and is
more rugged than the agricultural till plains of ecoregions to the north and west, but is less rugged
and not as forested as ecoregions to the east and south. Extensive mixed mesophytic forests and
mixed oak forests originally grew in the Western Allegheny Plateau and, today, most of its
rounded hills remain in forest; dairy, livestock, and general farms as well as residential
developments are concentrated in the valleys. Horizontally-bedded, sedimentary rock underlying
the region has been mined for bituminous coal.
Suggested Ecoregional subdivisions or adjustments
EPA recommends that the RTAG evaluate the adequacy of EPA nutrient ecoregional and
subecoregional boundaries and refine them as needed to reflect local conditions.
4.0 DATA REVIEW FOR RIVERS AND STREAMS IN AGGREGATE ECOREGION
XI
The following section describes the nutrient data EPA has collected and analyzed for this
Ecoregion, including an assessment of data quantity and quality. The data tables present the data
for each causal parameter— total phosphorus and total nitrogen (both reported and calculated
from TKN and nitrite/nitrate), and the primary response variables- some measure of turbidity
and chlorophyll a. These are the parameters which EPA considers essential to nutrient assessment
because the first two are the main causative agents of enrichment and the two response variables
are the early indicators of system enrichment for most of the surface waters (see Chapter 3 of the
Rivers and Streams Nutrient Criteria Technical Guidance Manual [U.S. EPA, 2000b] for a
complete discussion on choosing causal and response variables.)
4.1 Data Sources
Data from the following sources were used: Auburn University, Legacy STORET, New
York State Department of Environmental Conservation (NYSDEC), EPA Region 3, and EPA
Region 4. EPA recommends that the RTAGs identify additional data sources that can be used to
supplement the data sets listed above. In addition, the RTAGs may utilize published literature
values to support quantitative and qualitative analyses.
-------
4.2 Historical Data from Aggregate Ecoregion XI (TP, TN, Chi a, and Turbidity)
EPA recommends that States/Tribes assess long-term trends observed over the past 50
years. This information may be obtained from scientific literature or documentation of historical
trends. To gain additional perspective on more recent trends, it is recommended that States and
Tribes assess nutrient trends over the last 10 years (e.g., what do seasonal trends indicate?)
4.3 QA/QC of Data Sources
An initial quality screen of data was conducted using the rules presented in Appendix C.
Data remaining after screening for duplications and other QA measures (e.g., poor or unreported
analytical records, sampling errors or omissions, stations associated with outfalls, storm water
sewers, hazardous waste sites) were the data used in the statistical analyses.
States within Ecoregion XI were contacted regarding the quality of their data. The
following States indicated that their data were sampled and analyzed using either Standard
Methods or EPA-approved methods: Georgia, Maryland, Missouri, New York, New Jersey, N.
Carolina, Ohio, S. Carolina, and West Virginia.
4.4 Data for All Rivers and Streams Within Aggregate Ecoregion XI
Figure 3 shows the location of the sampling stations within each subecoregion. Table 1
presents all data records for all parameters for Aggregate Ecoregion XI and subecoregions within
the Aggregate Ecoregion.
4.5 Statistical Analysis of Data
EPA's Technical Guidance Manual for Developing Nutrient Criteria for Rivers and
Streams describes two ways of establishing a reference condition. One method is to choose the
upper 25th percentile (75th percentile) of a reference population of streams. This is the preferred
method to establish a reference condition. The 75th percentile was chosen by EPA since it is likely
associated with minimally impacted conditions, will be protective of designated uses, and provides
management flexibility. When reference streams are not identified, the second method is to
determine the lower 25th percentile of the population of all streams within a region. The 25th
percentile of the entire population was chosen by EPA to represent a surrogate for an actual
reference population. Data analyses to date indicate that the lower 25th percentile from an entire
population roughly approximates the 75th percentile for a reference population (see case studies
for Minnesota lakes in the Lakes and Reservoirs Nutrient Criteria Technical Guidance Document
[U.S. EPA, 2000a], the case study for Tennessee streams in the Rivers and Streams Nutrient
Criteria Technical Guidance Document [U.S. EPA, 2000b], and the letter from Tennessee
Department of Environment and Conservation to Geoffrey Grubbs [TNDEC, 2000]). New York
State has also presented evidence that the 25th percentile and the 75th percentile compare well
based on user perceptions of water resources (NYSDEC, 2000).
10
-------
Aggregate Nutrient Ecoregion 11
River and Stream Stations
hc.^ra
V™yi:"ra
- -^^fi£\™c™:M
,«jfW
^^(gNN'.Jpg * ^
Te'118&^s
Scuth Caroica
(Seorg.a
Level ill Ecoregions
3S Z 67 Z
H 68 ,
i 38
39
us
Stations
100 0 100 200
Figure 3 Sampling locations within each level III ecoregion.
11
-------
Table 1. Rivers and Streams records for Aggregate Ecoregion XI - Central and Eastern Forested Uplands
# of Stream names
# of Stream Stations
Key Nutrient Parameters
(listed below)
- # of records for Turbidity
(all methods)
- # of records for Chlorophyll
a (all methods) + Periphyton
- # of records for Total
Kjeldahl Nitrogen (TKN)
- # of records for Nitrate +
Nitrite (NO2 + NO3)
- # of records for Total
Nitrogen (TN)
- # of records for Total
Phosphorus (TP)
Total # of records for key
nutrient parameters
Aggregate
Ecoregion
XI
2,685
6,136
45,622
8,588
48,724
42,668
3,604
80,708
229,914
Sub
ecoR 36
112
185
2,813
15
1,828
2,777
42
3,390
10,865
Sub
ecoR38
67
117
1,634
3
787
1,763
46
1,644
5,877
Sub
ecoR 39
258
560
5,972
214
4,512
6,945
826
8,166
26,635
Sub
ecoR 66
123
282
7,120
272
5,578
6,078
46
7,245
26,339
Sub
ecoR 67
911
2,009
18,446
2,079
18,169
10,611
1,672
32,983
83,960
Sub
ecoR 68
78
254
2,241
410
1,329
1,472
17
1,846
7,315
12
-------
Table 1 (continued). Rivers and Streams records for Aggregate Ecoregion XI - Central and Eastern Forested Uplands
# of Stream names
# of Stream Stations
Key Nutrient Parameters
(listed below)
- # of records for Turbidity
(all methods)
- # of records for Chlorophyll
a (all methods) + Periphyton
- # of records for Total
Kjeldahl Nitrogen (TKN)
- # of records for Nitrate +
Nitrite (NO2 + NO3)
- # of records for Total
Nitrogen (TN)
- # of records for Total
Phosphorus (TP)
Total # of records for key
nutrient parameters
Sub
ecoR 69
603
1,225
4,754
1,704
5,277
4,478
627
7,477
24,317
Sub
ecoR 70
582
1,504
2,642
3,891
11,244
8,544
328
17,957
44,606
13
-------
Definitions used to complete Table 1:
1. # of records refers to the total count of observations for that parameter
over the entire decade (1990-1999) for that particular aggregate or
subecoregion. These are counts for all seasons over that decade.
2. # of stream stations refers to the total number of river and stream
stations within the aggregate or subecoregion from which nutrient data were
collected. Since streams and rivers can cross ecoregional boundaries, it is
important to note that only those portions of a river or stream (and data
associated with those stations) that exist within the ecoregion are included
within this table.
Tables 2 and 3a-h present potential reference conditions for both the aggregate ecoregion and the
subecoregions using both methods. However, the reference stream column is left blank because
EPA does not have reference data and anticipates that States/Tribes will provide information on
reference streams. Appendix A provides a complete presentation of all descriptive statistics for
both the aggregate ecoregion and the level III subecoregion.
14
-------
Table 2. Reference conditions for aggregate ecoregion XI.
Parameter
TKN (mg/L)
NO2 + NO3 (mg/L)
TN (mg/L) - calculated
TN (mg/L) - reported
TP («g/L)
Turbidity (NTU)
Turbidity (FTU)
Turbidity (JCU)
Chlorophyll a («g/L) -F
Chlorophyll a («g/L) -S
Chlorophyll a («g/L) -T
Periphyton Chi a (mg/m2)
No. of
Streams
N++
818
1,216
NA
290
1,591
405
314
54
19
117
59
7
Reported values
Min
0.018
0.002
0.02
0.059
0
0.1
0.25
0.5
0.125
0.25
0.25
32.5
Max
3.6
7.604
11.204
6.663
2160.4
98
99.5
28.25
8.55
45.665
43.4
45.5
25th Percentiles based
on all seasons data for
the Decade
P25-all seasons*
0.1
0.093
0.193
0.305
10
2.3
1.7
1.2
0.45
1.613
1.56
32.5
Reference Streams * *
P75 - all seasons
P25:
P75:
**
F
S
T
NA
25th percentile of all data
75th percentile of all data
as determined by the Regional Technical Assistance Groups (RTAGs)
Median for all seasons' 25th percentiles. E.g. this value was calculated from four seasons' 25th
percentiles. If the seasonal 25th percentile (P25) TP values are - spring Wug/L, summer l5ug/L,
fall l2ug/L, and winter 5ug/L, the median value of all seasons P25 will be llug/L.
N = largest value reported for a decade / Season.
TN calculated is based on the sum of TKN + NO2+NO3
TN reported is actual TN value reported in the database for one sample.
Chlorophyll a measured by Fluorometric method with acid correction.
Chlorophyll a measured by Spectrophotometric method with acid correction.
Chlorophyll a b c measured by Trichromatic method.
Not Applicable
calculated medians from less than 3 seasons' data.
Table(s) 3a-h present potential reference conditions for rivers and streams in the Level III
subecoregions within the Aggregate Ecoregion. Note that the footnotes for Table 2 apply to
Tables 3a-h.
15
-------
Table 3a. Reference conditions for level III ecoregion 36.
Parameter
TKN (mg/L)
NO2 + NO3 (mg/L)
TN (mg/L) - calculated
TN (mg/L) - reported
TP («g/L)
Turbidity (NTU)
Turbidity (FTU)
Turbidity (JCU)
Chlorophyll a («g/L) -F
Chlorophyll a («g/L) -S
Chlorophyll a («g/L) -T
Periphyton Chi a (mg/m2)
No. of
Streams
N++
69
79
NA
5
86
26 F
64 S
4
0
3z
Iz
Reported values
Min
0.05
0.005
0.055
0.3
2.5
2.488
1.2
6.1
-
0.25
-
-
Max
1.193
0.583
1.776
0.503
316.25
29.675
72.8
18.25
-
3.125
-
-
25th Percentiles based
on all seasons data for
the Decade
P25-all seasons
0.075
0.01
0.085
0.3
10.469
5.2
6.75
8.25 zz
-
0.25 zz
-
-
Reference Streams * *
P75 - all seasons
Table 3b. Reference conditions for level III ecoregion 38.
Parameter
TKN (mg/L)
NO2 + NO3 (mg/L)
TN (mg/L) - calculated
TN (mg/L) - reported
TP (Kg/L)
Turbidity (NTU)
Turbidity (FTU)
Turbidity (JCU)
Chlorophyll a («g/L) -F
Chlorophyll a («g/L) -S
Chlorophyll a («g/L) -T
Periphyton Chi a (mg/m2)
No. of
Streams
N++
40 W
42
NA
2z
45
25
37 W
3z
0
Iz
Reported values
Min
0.05
0.005
0.055
1.383
2.5
1.1
0.65
2.725
-
0.25
-
-
Max
0.698
2.757
3.455
2.287
160
45.5
13.55
5.438
-
0.25
-
-
25* Percentiles based
on all seasons data for
the Decade
P25-all seasons
0.073
0.03
0.103
1.383
5.625
3.138
1.625
2.725
-
0.25 zz
-
-
Reference Streams * *
P75 - all seasons
16
-------
Table 3c. Reference conditions for level III ecoregion 39.
Parameter
TKN (mg/L)
NO2 + NO3 (mg/L)
TN (mg/L) - calculated
TN (mg/L) - reported
TP («g/L)
Turbidity (NTU)
Turbidity (FTU)
Turbidity (JCU)
Chlorophyll a («g/L) -F
Chlorophyll a («g/L) -S
Chlorophyll a («g/L) -T
Periphyton Chi a (mg/m2)
No. of
Streams
N++
134
147
NA
31
175
72
95 W
6
10
14
IF
Reported values
Min
0.03
0.005
0.035
0.153
2.5
0.125
0.263
0.8
0.2
0.425
-
32.5
Max
1.87
7.604
9.474
3.887
2145
53.375
88.75
9.65
4.6
10.9
-
32.5
25 Percentiles based
on all seasons data for
the Decade
P25-all seasons
0.05
0.239
0.289
0.379
6.625
1.425
0.913
1.688
0.35 zz
0.9
-
32.5
Reference Streams * *
P75 - all seasons
Table 3d. Reference conditions for level III ecoregion 66.
Parameter
TKN (mg/L)
NO2 + NO3 (mg/L)
TN (mg/L) - calculated
TN (mg/L) - reported
TP («g/L)
Turbidity (NTU)
Turbidity (FTU)
Turbidity (JCU)
Chlorophyll a («g/L) -F
Chlorophyll a («g/L) -S
Chlorophyll a («g/L) -T
Periphyton Chi a (mg/m2)
No. of
Streams
N++
55
78
NA
5
84
12 F
57
10
2 z
8
Reported values
Min
0.025
0.003
0.028
0.233
0
0.325
0.25
0.55
1.625
1
-
-
Max
0.713
1.128
1.841
1.208
213.75
8.725
25
6.675
2
6
-
-
25 Percentiles based
on all seasons data for
the Decade
P25-all seasons
0.102
0.058
0.16
0.28
7.125
1
1.675
0.8
1.625 zz
2
-
-
Reference Streams * *
P75 - all seasons
17
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Table 3e. Reference conditions for level III ecoregion 67.
Parameter
TKN (mg/L)
NO2 + NO3 (mg/L)
TN (mg/L) - calculated
TN (mg/L) - reported
TP («g/L)
Turbidity (NTU)
Turbidity (FTU)
Turbidity (JCU)
Chlorophyll a («g/L) -F
Chlorophyll a («g/L) -S
Chlorophyll a («g/L) -T
Periphyton Chi a (mg/m2)
No. of
Streams
N++
188
289
NA
174
533
146
52 F
16W/S
0
33
--
7
Reported values
Min
0.025
0.003
0.028
0.092
0
0.625
1.4
1.325
-
0.595
-
26.85
Max
2.55
5.96
8.51
6.363
1387.9
52.25
40
20.575
-
17.3
-
53.75
25 Percentiles based
on all seasons data for
the Decade
P25-all seasons
0.169
0.23
0.399
0.214
10
2.4
4.25
3.425
-
1.063
-
32.75
Reference Streams * *
P75 - all seasons
Table 3f. Reference conditions for level III ecoregion 68.
Parameter
TKN (mg/L)
NO2 + NO3 (mg/L)
TN (mg/L) - calculated
TN (mg/L) - reported
TP («g/L)
Turbidity (NTU)
Turbidity (FTU)
Turbidity (JCU)
Chlorophyll a («g/L) -F
Chlorophyll a («g/L) -S
Chlorophyll a («g/L) -T
Periphyton Chi a (mg/m2)
No. of
Streams
N++
33
41
NA
2z
51
36
2z
11
0
9
Reported values
Min
0.025
0.003
0.028
0.3
0
0.825
1.975
0.5
-
0.25
-
-
Max
1.045
1.754
2.799
0.463
500
17.55
3.2
7.6
-
15.25
-
-
25 Percentiles based
on all seasons data for
the Decade
P25-all seasons
0.1
0.059
0.159
0.3
6
3.244
1.975
1.088
-
2
-
-
Reference Streams * *
P75 - all seasons
18
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Table 3g. Reference conditions for level III ecoregion 69.
Parameter
TKN (mg/L)
NO2 + NO3 (mg/L)
TN (mg/L) - calculated
TN (mg/L) - reported
TP («g/L)
Turbidity (NTU)
Turbidity (FTU)
Turbidity (JCU)
Chlorophyll a («g/L) -F
Chlorophyll a («g/L) -S
Chlorophyll a («g/L) -T
Periphyton Chi a (mg/m2)
No. of
Streams
N++
92
246
NA
98 S
291
104 S
30 S
4
0
12
Reported values
Min
0.025
0.014
0.039
0.305
0.5
0.6
1.2
0.55
-
0.25
-
-
Max
1.932
2.58
4.512
2.987
408.75
47.25
50.513
6.925
-
5.698
-
-
25 Percentiles based
on all seasons data for
the Decade
P25-all seasons
0.113
0.177
0.29
0.502
7.625
2.175
1.9
2.444
-
-
-
Reference Streams * *
P75 - all seasons
Table 3h. Reference conditions for level III ecoregion 70.
Parameter
TKN (mg/L)
NO2 + NO3 (mg/L)
TN (mg/L) - calculated
TN (mg/L) - reported
TP («g/L)
Turbidity (NTU)
Turbidity (FTU)
Turbidity (JCU)
Chlorophyll a («g/L) -F
Chlorophyll a («g/L) -S
Chlorophyll a («g/L) -T
Periphyton Chi a (mg/m2)
No. of
Streams
N++
219
294
NA
29
326
33
28
Iz
7
37
Reported values
Min
0.025
0.007
0.032
0.271
2
0.7
1.025
9.5
1.575
0.25
-
-
Max
2.1
5.585
7.685
4.95
1101.25
61
49.75
17
13.6
28.36
-
-
25th Percentiles based
on all seasons data for
the Decade
P25-all seasons*
0.178
0.083
0.261
0.575
10
4.575
4.75
9.5
1.8 zz
3.256
-
-
Reference Streams * *
P75 - all seasons
19
-------
Definitions used in filling Tables 2 and 3 - Reference Condition tables
1. Number of Streams in Table 2 refers to the largest number of streams and rivers for which
data existed for a given season within an aggregate nutrient ecoregion.
2. Number of Streams in Table 3 refers to the number of streams and rivers for which data
existed for the summer months since summer is generally when the greatest amount of nutrient
sampling is conducted. If another season greatly predominates, notification is made (s=spring,
f=fall, w=winter).
3. Medians. All values (min, max, and 25th percentiles) included in the table are based on
waterbody medians. All data for a particular parameter within a stream for the decade were
reduced to one median for that stream. This prevents over-representation of individual
waterbodies with a great deal of data versus those with fewer data points within the statistical
analysis.
4. 25th percentile for all seasons is calculated by taking the median of the 4 seasonal 25th
percentiles. If a season is missing, the median was calculated with 3 seasons of data. If less
than 3 seasons were used to derive the median, the entry is flagged (z).
5. A 25th percentile for a season is best derived with data from a minimum of 4
streams/season. However, this table provides 25th percentiles that were derived with less than 4
streams/season in order to retain all information for all seasons. In calculating the 25th
percentile for a season with less than 4 stream medians, the statistical program automatically
used the minimum value within the less-than-4 population. If less than 4 streams were used in
developing a seasonal quartile and or all-seasons median, the entry is flagged (zz).
4.6. Classification of River/Stream Type
It is anticipated that assessing the data by stream type will further reduce the variability in
the data analysis. There were no readily available classification data in the National datasets used
to develop these criteria. States and Tribes are strongly encouraged to classify their streams
before developing a final criterion.
4.7. Summary of Data Reduction Methods
All descriptive statistics were calculated using the medians for each stream within
ecoregion XI, for which data existed. For example, if one stream had 300 observations for
phosphorus over the decade or one year's time, one median resulted. Each median from each
stream was then used in calculating the percentiles for phosphorus for the aggregate nutrient
ecoregion/subecoregion (level III ecoregion) by season and year (Figure 4a & b).
20
-------
Observations for All Rivers/Streams
Winter
Spring
Data Reduced
to
Median Value
for each
River/Stream
by
Season
Summer
Fall
Figure 4a. Illustration of data reduction process for stream data.
21
-------
Winter
Select 25th Percentile
from Distribution
of Median
Values
25%
Spring
Summer
25%
Fall
TP
TN
TKN
NO2+NO3
Chi a
Turbidity
Calculate Median
Value of the
25th Percentiles
for the Four Seasons
} Half values -«J
Below Median ^^
1 1
}25% 25%
Season A Season B
25%
L, Half values
f Above Median
1 1
25% 25%
Season C Season D
Median = Reference Condition for the Ecoregion
Figure 4b. Illustration of reference condition calculation.
22
-------
Preferred Data Choices and Recommendations When Data Are Missing
1. Where data are missing or are very low in total records for a given parameter, use 25th
percentiles for parameters within an adjacent, similar subecoregion within the same aggregate
nutrient ecoregion or when a similar subecoregion can not be determined, use the 25th percentile
for the Aggregate ecoregion or consider the lowest 25th percentile from a subecoregion (level III)
within the aggregate nutrient ecoregion. The rationale being that without data, one may assume
that the subecoregion in question may be as sensitive as the most sensitive subecoregion within
the aggregate.
2. TN calculated: When reported Total Nitrogen (TN) median values are lacking or very low in
comparison to TKN and Nitrate/Nitrite-N values, the medians for TKN and nitrite/nitrate-N were
added, resulting in a calculated TN value. The number of samples (N) for calculated TN is not
filled in since it is represented by two subsamples of data: TKN and nitrite/nitrate-N. Therefore,
N/A is placed in this box.
3. TN reported: This is the median based on reported values for TN from the database.
4. Chlorophyll a: Medians based on all methods are reported, however, the acid corrected
medians are preferred to the uncorrected medians. In developing a reference condition from a
particular method, it is recommended that the method with the most observations be used.
Fluorometric and Spectrophotometric are preferred over all other methods. However, when no
data exist for Fluorometric and Spectrophotometric methods, Trichromatic values may be used.
Data from the variance techniques are not interchangeable.
5. Periphyton: Where periphyton data exist, record them separately For periphyton-dominated
streams, a measure of periphyton chlorophyll is a more appropriate response variable than
planktonic chlorophyll a. See Table 4, p. 101 of the Rivers and Streams Nutrient Technical
Guidance Manual (U. S. EPA, 2000b) for values of periphyton and planktonic chlorophyll a
related to eutrophy in streams.
6. Secchi depth: The 75th percentile is reported for Secchi depth since this is the only variable
for which the value of the parameter increases with greater clarity. (For lakes and reservoirs
only.)
7. Turbidity units: All turbidity units from all methods are reported. FTUs and NTUs are
preferred over JCUs. If FTUs and NTUs do not exist, use JCUs. These units are not
interchangeable. Turbidity is chosen as a response variable in streams since it can be an indicator
of increasing algal biomass due to nutrient enrichment. See pages 32 -33 of the Rivers and
Streams Nutrient Technical Guidance Manual for a discussion of turbidity and correlations with
algal growth.
8. Lack of data: A dash (-) represents missing, inadequate, or inconclusive data. A zero (0) is
reported if the reported median for a parameter is 0 or if the component value is below detection.
23
-------
5.0 REFERENCE SITES AND CONDITIONS IN AGGREGATE ECOREGION XI
Reference conditions represent the natural, least impacted conditions or what is
considered to be the most attainable conditions. This section compares the different reference
conditions determined from the two methods and establishes which reference condition is most
appropriate.
A priori determination of reference sites. The preferred method for establishing reference
condition is to choose the upper percentile of an a priori population of reference streams. States
and Tribes are encouraged to identify reference conditions based on this method.
Statistical determination of reference conditions (25th percentile of entire database.) See Tables 2
and 3a-h in section 4.0.
RTAG discussion and rationale for selection of reference sites and conditions in Ecoregion XI.
The RTAG should compare the results derived from the two methods described above and
present a rationale for the final selection of reference sites.
6.0 MODELS USED TO PREDICT OR VERIFY RESPONSE PARAMETERS
The RTAG is encouraged to identify and apply relevant models to support nutrient criteria
development. The following are three scenarios under which models may be used to derive
criteria or support criteria development.
• Models for predicting correlations between causal and response variables
• Models used to verify reference conditions based on percentiles
• Regression models used to predict reference conditions in impacted areas
7.0 FRAMEWORK FOR REFINING RECOMMENDED NUTRIENT CRITERIA
FOR RIVERS AND STREAMS IN AGGREGATE ECOREGION XI
Information on each of the following six weight of evidence factors is important to refine
the criteria presented in this document. All elements should be addressed in developing criteria,
as is expressed in our nutrient criteria technical guidance manuals. It is our expectation that EPA
Regions, States, and Tribes (as RTAGs) will consider these elements as States/Tribes develop
their criteria. This section should be viewed as a work sheet (sections are left blank for this
purpose) to assist in the refinement of nutrient criteria. If many of these elements are ultimately
unaddressed, EPA may rely on the proposed reference conditions presented in Tables 3a-h and
other literature and information readily available to the HQ nutrient team to develop nutrient
water quality recommendations for this ecoregion.
24
-------
7.1 Example Worksheet for Developing Aggregate Ecoregion and Subecoregion
Nutrient Criteria
Literature sources
• Historical data and trends
Reference condition
• Models
RTAG expert review and consensus
Downstream effects
25
-------
7.2 Tables of Refined Nutrient Water Quality Criteria for Aggregate Ecoregion XI and
Level III Subecoregions for TP, TN, Chi a, Turbidity (where sufficient data exist)
Aggregate Ecoregion XI- Central and
Eastern Forested Uplands
Total Phosphorus (|ig/L)
Total Nitrogen (mg/L)
Chlorophyll a (|ig/L or mg/m2)
Turbidity (NTU or other units)
Other (Index; other parameter such as DO)
Proposed Criterion
Literature sources
Historical data and trends
Reference condition
Models
RTAG expert review and consensus
Downstream effects
26
-------
Ecoregion #36-Ouachita Mountains
Total Phosphorus (|ig/L)
Total Nitrogen (mg/L)
Chlorophyll a (|ig/L or mg/m2)
Turbidity (NTU or other units)
Other (Index; other parameter such as DO)
Proposed Criterion
7.3 Setting Seasonal Criteria
The recommendations presented in this document are based in part on medians of all the
25th percentile seasonal data (decadal), and as such are reflective of all seasons and not one
particular season or year. It is recommended that States and Tribes monitor in all seasons to best
assess compliance with the resulting criterion. States/Tribes may choose to develop criteria which
reflect each particular season or a given year when there is significant variability between
seasons/years or designated uses that are specifically tied to one or more seasons of the year (e.g.,
recreation, fishing). Using the tables in Appendix A and B, one can set reference conditions based
on a particular season or year and then develop a criterion based on each individual season.
Obviously, this option is season-specific and would also require increased monitoring within each
season to assess compliance.
7.4 When Data/Reference Conditions are Lacking
When data are unavailable to develop a reference condition for a particular parameter(s)
within a subecoregion, EPA recommends one of three options: (1) Use data from a similar
neighboring subecoregion (e.g., if data are few or nonexistent for the northern cascades, consider
using the data and reference condition developed for the cascades); or (2) Use the 25th percentiles
for the Aggregate ecoregion; or (3) Consider using the lowest of the yearly medians for that
parameter calculated for all the subecoregions within the Aggregate Ecoregion.
7.5 Site-Specific Criteria Development
Criteria may be refined in a number of ways. The best way to refine criteria is to follow
the critical elements of criteria development as well as to refer to the Rivers and Streams Nutrient
Criteria Technical Guidance Manual (U.S. EPA, 2000b). The Technical Guidance Manual
presents sections on each of the following factors to consider in setting criteria:
- refinements to ecoregions (Section 2.3)
- classification of waterbodies (Chapter 2)
27
-------
- setting seasonal criteria to reflect major seasonal climate differences and accounting for
significant or cyclical precipitation events (high flow/low flow conditions) (Chapter 4)
8.0 LITERATURE CITED
NYSDEC (New York State Department of Environment and Conservation). 2000.
Memorandum from Scott Kishbaugh to Jay Bloomfield, September 26, 2000, regarding
reference lakes for nutrient criteria.
TNDEC (Tennessee Department of Environment and Conservation). 2000. Letter to
Geoff Grubbs, October 5, 2000, containing comments on draft nutrient criteria
recommendations.
U.S. EPA. 2000a. Nutrient Criteria Technical Guidance Manual: Lakes and Reservoirs,
U.S. Environmental Protection Agency, Washington, DC. EPA-822-BOO-001.
U.S. EPA. 2000b. Nutrient Criteria Technical Guidance Manual: Rivers and Streams,
U.S. Environmental Protection Agency, Washington, DC. EPA-822-BOO-002.
9.0 APPENDICES
A. Descriptive Statistics Data Tables for Aggregate Ecoregion
B. Descriptive Statistics Data Tables for Level III Subecoregions within Aggregate Ecoregion
C. Quality Control/Quality Assurance Rules
28
-------
APPENDIX A
Descriptive Statistics Data Tables for Aggregate Ecoregion
-------
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Fluo_ug_L_Hedian
FALL
SPRING
SUMMER
WINTER
SEASON
FALL
SPRING
SUMMER
WINTER
SEASON
FALL
SPRING
SUMMER
WINTER
SEASON
FALL
SPRING
SUMMER
WINTER
SEASON
FALL
SPRING
11 D.1D -DDD
D
11 E-17 .ESD
D
N MEAN MIN
D
1 D. 50 .500
a
a
N MEAN MIN
flb b-33 .ESD
flE 5-4D -ESD
117 fl-SS -ESD
50 E-Tl -DDD
N MEAN MIN
D
D
3 D-Dl -DDS
D
N MEAN MIN
45 1-15 -ESD
47 7-Db -ESD
3-SD i-n D-3b 133 D.DD D.ED D-4D
13- bD 3-3b D-77 113 D-ES D-7D 1-Sfl
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Phyto_C_F_ug_L_Med
MAX STDDEV STDERR CV PS PES MEDIAN
D.SD . . . D.SD D.SD D.SD
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Phyto_Spec_A_ug_L_Median
MAX STDDEV STDERR CV PS PES MEDIAN
33- b3 b-fll D-73 IDfl D-ES Lb3 3-SD
S7-7D 7-4fl D-fl3 131 D-ES 1-bfl 3-1D
bD-b? 11. D I.DE IEI D.ES i.tn 4.41
E3.D1 4- 3D D-bl 144 D-ES D-b3 1-35
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Phyto_Spec_U_ug_L_Median
MAX STDDEV STDERR CV PS PES MEDIAN
D.DI D.DD D.DD ES D.DI D.DI D.DI
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Tric_U_ug_L_Median
MAX STDDEV STDERR CV PS PES MEDIAN
37-lfl 1-bE 1-43 IDS D-fl7 Lfl3 3-15
fll-DD IE- 7 1-flS IflD D.ES LET E-74
D.1D 3-SD
S-4D 13- b
P7S PIS
D.SD D.SD
P7S PIS
1-bD ED-D
7-SD 1S-D
11-7 33- fl
3-D7 ID-l
P7S PIS
D.DI D.DI
P7S PIS
Ib-b Eb-S
T.fl3 ED-E
-------
SUMMER
WINTER
SEASON
FALL
SPRING
SUMMER
WINTER
SEASON
FALL
SPRING
SUMMER
WINTER
51
35
11. fl
3-lfl
• ESD
• ODD
4fl.fll
E5.fl4
11-7
5.D1
1.5E
D.flS
1S7
1-E4
D-ES
3.it
D-7S
7-4fl
1.41
lfl.5
E-3S
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chlb_Phyto_C_F_ug_L_Med
MEAN
D.DS
MIN
• DSD
MAX
D.DS
STDDEV
STDERR
CV
PS
D.DS
PES
D.DS
MEDIAN
D.DS
P75
D.DS
fll
71
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter DIP_ug_L_Median
MEAN
37.b
Ifl.E
EE-7
E4-b
MIN
S.DD
S.DD
S.DD
MAX
SflS-DD
135.DD
31D-DD
ISb-ES
STDDEV
7fl-4
E3-S
4D-S
33-1
STDERR
fl.71
E-7T
3-17
CV
EDI
1E1
17fl
13S
PS
S.DD
S.DD
4-DD
S.DD
PES
5-DD
5-DD
5-DD
S.DD
MEDIAN
15.D
b-ES
1D-D
11-3
P75
3E-S
E7-5
ELS
EE-5
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter DO_mg_L_Median
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter NOE_N03_mg_L_Median
SEASON
FALL
SPRING
SUMMER
WINTER
N
fl17
7b4
lElb
bbD
MEAN
D-bD
D-41
D-Sl
D-74
MIN
• DDD
• DD3
• DDD
• DD3
MAX
fl.
5.
41.
b.
bD
Db
SD
bl
STDDEV
1-DE
D-7D
1-57
D-lfl
STDERR
D.
D.
D.
D.
• D3
• D3
• D4
• D4
CV
Ibl
143
3Db
133
PS
D.DI
D.DI
D.DI
D.DI
PE5
D.Dfl
D • D1
D.ID
D-IS
MEDIAN
D-E4
ES
E3
D-4D
P75
D-S1
D-5S
D-4b
D.flfl
41-D
11-7
PIS
D.DS
PIS
1DD
bS-D
1D-D
IDS
SEASON
FALL
SPRING
SUMMER
WINTER
N
bflE
bEl
fl13
bD3
MEAN
Llfl
ID-l
fl.EE
11-4
MIN
• SSD
S-flD
.flSD
b-ED
MAX
14. bD
14- SD
14- ED
14- bD
STDDEV
1-7D
1-3E
l-7fl
LEE
STDERR
D-D7
D.DS
D-Db
D.DS
CV
11
13
EE
11
PS
b-SD
fl.lD
S-4D
1-4D
PES
fl.4D
1-E3
7-3S
ID-b
MEDIAN
1-35
1D-D
fl.ED
11-3
P7S
ID-l
1D-1
1-DD
1E-E
P15
11. 5
IE- 4
11. b
13-4
PIS
E-bD
l.flt
1-7D
E-S1
-------
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Org_P_ug_L_Hedian
ID
SEASON
FALL
SPRING
SUMMER
WINTER
N
ID
D
ID
D
MEAN
3-15
7-7b
MIN
• 77D
• DDD
MAX
fl.El
17-lfl
STDDEV
E-Sb
b-ES
STDERR
D-fll
1-17
CV
flD
PS
D-77
D.DD
PES MEDIAN P75 PIS
l.flD 4-E3 S-4E fl.El
l-7fl 7-41 ID-4 Ifl-D
SEASON
FALL
SPRING
SUMMER
WINTER
35
35
bs
31
MEAN
E3-5
11.D
15.b
E4-fl
MIN
S.DD
S.DD
• SDD
S.DD
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Orthophosphate_T_as_P_ug_L_Med
11
MAX
13D-DD
IbD-DD
117-SD
1SD-DD
STDDEV
EL7
31-S
Eb-S
3E-3
STDERR
S-D3
S-3E
3-Efl
S-flD
CV
Ibb
17D
13D
PS
S.DD
S.DD
I.DD
S.DD
PES
5-DD
5-DD
L.DD
7-SD
MEDIAN
1D-D
fl.7S
S.SD
1E-S
P7S
3D-D
1S-D
1S-D
ES-D
PIS
1D-D
11D
flD-D
1D-D
SEASON
FALL
SPRING
SUMMER
WINTER
N
747
bE7
fllfl
b37
MEAN
D-3D
D-Efl
D-34
D-E4
MIN
• DDD
• DES
• DES
• DID
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter TKN_mg_L_Median
IE
MAX
4-ED
4-4D
3-DD
3-DD
STDDEV
D-34
D-33
D-3S
D-ES
STDERR
D-Dl
D.DI
D.DI
D.DI
cv
us
117
1D3
1D4
PS
D.DS
D.DS
D.DS
D.DS
PES
D.ID
D.ID
D-13
D-Db
MEDIAN
D.EI
D.ED
D.ES
D.ED
P7S
].3S
].3S
D-4E
D-3D
PIS
D-fl4
D-73
I.DD
D-7D
SEASON
FALL
SPRING
SUMMER
WINTER
N
1ED
ES4
E1D
11
MEAN
D-13
D-71
1-31
1-Eb
MIN
• DED
• D7D
• D47
• 13D
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter TN_mg_L_Median
13
MAX
4.IS
S-7D
11.ED
7-b3
STDDEV
1-Db
D-11
1-bS
LEI
STDERR
D.ID
D-Db
D.ID
D-13
CV
114
US
lEb
IDE
PS
D.DI
D-IS
D-11
D-IS
PES
D-3S
D-41
MEDIAN
D-SS
D-47
D-bS
D-1S
P7S
1-11
D-13
1-S3
1. tD
PIS
3-fll
E-S7
4-S3
4-55
SEASON
FALL
SPRING
IDflt
11D3
MEAN
4S-S
MIN
• DDD
• DDD
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter TP_ug_L_Median
14
MAX
EE4D-7S
EDflD-DD
STDDEV
174
1E1
STDERR
S-Efl
3-fl7
CV
EbE
Efl3
PS
S.DD
E.SD
PES
1D-D
fl.ES
MEDIAN
ED-D
ED-D
P7S
SD-D
4D-D
PIS
EflD
14D
-------
SUMMER
WINTER
1511
flEb
54-E
53.b
• DDD
• DDD
E4DD.DD
111D.DD
131
13b
3-47
4-7E
ESS 4-SD
ES3 E-SD
1D.D
1D.D
ED.D
El-3
SD.D
4S-D
llfl
17S
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Turb FTU Median
IS
SEASON
FALL
SPRING
SUMMER
WINTER
N
313
314
31D
E13
MEAN
b-7E
1.75
7-17
7-31
MIN
• E5D
• ESD
• E5D
• ESD
MAX
15.
14D.
IDE.
17.
ES
5D
DD
DD
STDDEV
Lbl
15-1
11. fl
IE- 4
STDERR
D.
D.
D.
D.
.55
• as
• b7
.73
CV
144
1S4
14fl
17D
P5
D-bD
D-bD
D-7D
D.SD
PES
LbD
E • 4D
l.flD
1-3D
MEDIAN
4D
3D
34
3-lfl
P7S
fl.ED
1E-S
LSD
b-b3
PIS
ED-D
E7-S
E4-S
33-D
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Turb JCU Median
SEASON
FALL
SPRING
SUMMER
WINTER
41
54
SI
54
MEAN
3-SE
4-7b
4-41
5-fll
MIN
• SDD
• SDD
• SDD
.DDD
MAX
34-ED
ED-flD
3E-DD
E4-SD
STDDEV
5-b3
4-El
5-5b
S-73
STDERR
D.flfl
D-Sfl
D-7fl
D-7fl
CV
IbD
ID
1E4
Ifl
PS
D-bD
D-SD
D.SD
D-7D
PES
L.ID
L-4D
L.DD
MEDIAN
1-3D
l.flD
3-bfl
3-3S
4-3S
P7S
3. tD
b-75
S-flD
fl-ID
PIS
1.35
14-3
1E-D
11.D
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Turb NTU Median
17
SEASON
FALL
SPRING
SUMMER
WINTER
N
E4S
3flE
4DS
111
MEAN
b-34
fl.37
b-71
1.45
MIN
.DDD
• EDD
.DDD
.ESD
MAX
4fl-DD
EDD-DD
114-DD
flE-DD
STDDEV
14-7
1D-1
11-7
STDERR
D-41
D-7S
D-S4
D-flS
CV
IDE
17S
It3
1E4
PS
D-7D
D-7D
D.SD
D-b3
PES
. tfl
MEDIAN
4-ES
4-3S
3-flD
S-1D
P7S
fl.S3
fl-ID
7-DD
11.b
PIS
Ib-D
Et.fl
EE-D
-------
APPENDIX B
Descriptive Statistics Data Tables for Level III Subecoregions within Aggregate Ecoregion
-------
Eco_
Level_
III
Eco_
Level_
III
70
SEASON
SEASON
WINTER
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Fluo_ug_L_Median
MEAN
MIN
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
P75
P95
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
0
0
0
0
0
0
0
0
10 0.69 .000
0
10 1.92 .400
0
1 3.00 3.00
0
2 0.63 .250
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7 5.13 1.58
.
.
.
.
.
.
.
.
3.50 1.02 0.32 148 0.00 0.20
.
5.70 2.07 0.65 108 0.40 0.50
.
3.00 . . . 3.00 3.00
.
1.00 0.53 0.38 85 0.25 0.25
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
13.60 4.28 1.62 83 1.58 1.80
.
.
.
.
.
.
.
.
0.40 0.60 3.50
.
0.95 3.10 5.70
.
3.00 3.00 3.00
.
0.63 1.00 1.00
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
3.55 6.75 13.6
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Fluo_ug_L_Median
N MEAN
0
MIN
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
P75
P95
-------
Eco_
Level_
III
Eco_
Level_
III
70
SEASON
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Phyto_C_F_ug_L_Med
MEAN
0.50
MIN
.500
MAX STDDEV STDERR
0.50
CV
P5
P25 MEDIAN
P75
P95
0.50 0.50
0.50
0.50 0.50
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Phyto_C_F_ug_L_Med
SEASON N MEAN
WINTER 0
MIN
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
P75
P95
-------
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Phyto_Spec_A_ug_L_Median
Eco_
Level_
III
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
69
69
69
69
70
70
70
SEASON
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
N
3
0
3
0
1
0
1
0
14
10
14
8
6
7
8
0
18
19
33
9
8
9
9
5
12
16
12
12
24
21
37
MEAN
0.25
0.25
0.25
3.13
4.89
3.58
2.54
3.24
11.0
2.84
5.98
5.32
8.58
2.43
5.13
5.11
12.5
6.01
3.27
0.86
2. 67
0. 63
11.9
7.44
13.5
MIN
.250
.250
.250
.250
.250
2.28
.250
. 600
1.22
1.00
.250
.700
.710
.490
.000
.250
.250
.250
.250
.250
.250
.250
.250
1.28
.250
.250
MAX
6.00
0.25
0.25
0.25
9. 60
12.20
15.00
8.80
6.00
57.70
5.50
20.00
14. 60
60. 67
9.00
12.00
15.00
38.75
15.50
15.27
2. 60
8.79
1.85
STDDEV
3.00
0.00
59.26
2.57
3.37
4.07
2.92
1.74
20.7
1.86
6.11
4.16
11.9
2. 66
4. 63
4.76
14.3
5.86
4.24
0.79
2.78
0.53
8. 60
6.05
12.1
STDERR
1.73
0.00
0. 69
1.07
1.09
1.03
0.71
7.81
0. 66
1.44
0.96
2.07
0.89
1. 64
1.59
4.76
1.22
0.20
0.80
0.15
1.75
1.32
1.99
cv
114
0
•
•
82
69
114
115
54
188
65
102
78
139
110
90
93
114
97
129
92
104
85
72
81
90
0
0
0
0
0
2
0
0
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
2
P5
.25
.25
.25
.25
.25
.28
.25
. 60
.22
.00
.25
.70
.71
.56
.00
.25
.25
.25
.25
.25
.25
.25
.25
.83
.47
.55
0
0
0
0
0
3
0
0
2
2
1
1
2
1
1
1
2
2
2
0
0
0
0
4
2
4
P25
.25
.25
.25
.25
.85
.20
.80
.95
.00
.39
.50
.00
.50
.13
.00
.31
.00
.00
.75
.25
.25
.46
.25
.49
.02
. 65
MEDIAN
1.
0.
0.
0.
2.
3.
1.
1.
2.
3.
2.
3.
4.
3.
1.
4.
4.
9.
4.
2.
0.
1.
0.
10
6.
9.
63
25
25
25
80
49
98
25
88
00
50
50
00
00
59
00
50
00
50
58
38
95
25
. 6
87
75
P75
6.
0.
0.
0.
4.
4.
4.
3.
4.
6.
4.
10
8.
11
3.
9.
7.
12
7.
3.
1.
3.
1.
17
11
16
00
25
25
25
00
45
90
28
50
25
50
.0
50
.0
00
06
50
.0
06
20
46
27
06
.1
.5
.3
P95
6.
0.
0.
0.
9.
12
15
8.
6.
57
5.
20
14
27
9.
12
15
38
15
15
2.
8.
1.
25
16
37
00
25
25
25
60
.2
.0
80
00
.7
50
.0
. 6
.0
00
.0
.0
.8
.5
.3
60
79
85
. 6
.0
.2
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Phyto_Spec_A_ug_L_Median
Eco
Level
III ~
70
SEASON
WINTER
N
16
MEAN
4.35
MIN
.250
MAX
23.09
STDDEV
5.78
STDERR
1.45
CV
133
P5
0.25
P25 MEDIAN P75 P95
1.23 1.95 4.52 23.1
-------
Eco_
Level_
III
Eco_
Level_
III
70
SEASON
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
1
0
0
0
0
0
0
0
1
0
0
0
0
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Phyto_Spec_U_ug_L_Median
MEAN
MIN
MAX STDDEV STDERR
CV
P5
P25
MEDIAN
P75
P95
0.01
0.01
.005
.009
0.01
0.01
0.01 0.01 0.01 0.01 0.01
0.01 0.01 0.01 0.01 0.01
0.01
.006
0.01
0.01
0.01 0.01 0.01 0.01
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Phyto_Spec_U_ug_L_Median
SEASON N MEAN
WINTER 0
MIN
MAX STDDEV STDERR
CV
P5
P25 MEDIAN
P75 P95
-------
Eco_
Level
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Tric_U_ug_L_Median
II
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
SEASON
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
N
1
0
1
0
0
0
0
0
0
0
0
0
1
2
2
0
7
7
7
5
0
0
0
0
12
16
12
13
24
22
37
MEAN
14.2
19.8
1.83
42.0
3.49
.
1. 60
5. 69
2.86
1. 69
.
.
.
.
3. 61
1.18
2.97
0.88
14.2
8. 60
16. 6
MIN
14.2
19.8
1.83
3.00
2.57
.895
1.29
1.24
.000
.250
.250
.250
.250
1.47
.750
1.39
MAX
14.20
19.75
1,
81,
4,
3,
20,
7,
4,
17,
3,
10,
1,
37,
24,
48,
.83
.00
.40
.16
.20
.32
.00
.82
. 63
.42
. 62
.98
.33
.81
STDDEV
.
55.2
1.29
.
0.80
6. 60
2.14
1.49
.
.
.
.
4. 65
1.03
2. 63
0.51
10.2
7.07
12.1
STDERR
.
39
0.
.
0.
2.
0.
0.
.
.
.
.
1.
0.
0.
0.
2.
1.
1.
.0
92
30
49
81
67
34
26
76
14
07
51
99
CV
.
131
37
.
50
116
75
88
.
.
.
.
129
87
89
58
71
82
73
P5
14.2
19.8
1
3
2
0
1
1
0
0
0
0
0
1
1
3
.83
.00
.57
.
.90
.29
.24
.00
.
.
.
.
.25
.25
.25
.25
.50
.18
.31
P25
14.2
19.8
1
3
2
1
1
1
0
1
0
1
0
5
2
7
.83
.00
.57
.
.08
. 62
.48
.87
.
.
.
.
.03
.25
.48
.50
.01
.74
.48
MEDIAN
14.2
19.8
1.83
42.0
3.49
1.21
4.13
1.81
1. 65
2.89
0.88
2.37
0.75
13.0
6.76
14.5
P75
14.2
19.8
1.83
81.0
4.40
.
2.12
5.85
3.46
1.93
.
.
.
.
3.57
1.83
3.34
1.24
20.7
13.7
21.3
P95
14.2
19.8
1.83
81.0
4.40
.
3.16
20.2
7.32
4.00
.
.
.
.
17.8
3. 63
10.4
1. 62
30.9
19. 6
44.5
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chla_Tric_U_ug_L_Median
Eco
Level
III ~
70
SEASON
WINTER
N
17
MEAN
5.37
MIN
.750
MAX
25.84
STDDEV
6.51
STDERR
1.58
CV
121
P5
0.75
P25
1.38
MEDIAN P75 P95
2.31 5.88 25.8
10
-------
Eco_
Level_
III
Eco_
Level_
III
70
SEASON
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chlb_Phyto_C_F_ug_L_Med
11
MEAN
0.05
MIN
.050
MAX STDDEV STDERR
0.05
CV
P5
P25 MEDIAN
P75
P95
0.05 0.05
0.05
0.05 0.05
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Chlb_Phyto_C_F_ug_L_Med
12
SEASON N MEAN
WINTER 0
MIN
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
P75
P95
-------
Eco_
Level_
III
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter DIP_ug_L_Median
13
SEASON
MEAN
MIN
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter DIP_ug_L_Median
Eco
Level
III ~
70
SEASON
WINTER
N
19
MEAN
25.4
MIN
5.00
MAX
140.00
STDDEV
36.3
STDERR
8.32
CV
143
P5
5.00
P75
P95
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
2
2
2
2
2
2
2
2
25
15
25
15
4
4
5
3
24
23
89
23
2
2
2
2
3
4
19
3
19
19
19
12.5
6.88
8.13
5.00
43.8
30.0
47.5
25.0
35.2
19.3
24.7
23.8
21.3
13.1
25.2
27.9
52.9
23.3
24. 6
29.2
5.00
5.00
5.00
5. 63
23.3
11.3
8.08
11.3
32. 6
15.1
26.2
12
5.
5.
5.
5.
5.
5.
5.
5.
5.
3.
5.
5.
5.
5.
5.
5.
5.
2.
5.
5.
5.
5.
5.
8.
5.
3.
5.
5.
5.
5.
.5
00
00
00
00
00
00
00
00
00
75
00
00
00
00
00
00
00
00
00
00
00
00
00
75
00
50
00
00
00
00
12.
8.
11.
5.
82.
55.
90.
45.
342.
80.
195.
105.
70.
37.
80.
72.
585.
135.
390.
156.
5.
5.
5.
6.
40.
25.
40.
15.
228.
85.
99.
,50
,75
,25
,00
,50
,00
,00
,00
,50
,00
,00
,00
,00
,50
,00
,50
,00
,00
,00
,25
,00
,00
,00
,25
,00
,00
,00
,00
,00
,50
,00
0.00
2. 65
4.42
0.00
54.8
35.4
60.1
28.3
67.7
20.9
40.4
28.0
32.5
16.3
31.3
38. 6
117
29.7
47.2
39.1
0.00
0.00
0.00
0.88
15.7
9.46
7.87
5.45
52.5
22.3
28.4
0.00
1.88
3.13
0.00
38.8
25.0
42.5
20.0
13.5
5.39
8.08
7.24
16.3
8.13
14.0
22.3
23.9
6.19
5.00
8.15
0.00
0.00
0.00
0. 63
9.09
4.73
1.81
3.15
12.0
5.11
6.52
0
39
54
0
125
118
127
113
192
108
164
118
153
124
124
138
221
127
192
134
0
0
0
16
68
84
97
48
161
148
109
12
5.
5.
5.
5.
5.
5.
5.
5.
5.
4.
5.
5.
5.
5.
5.
5.
5.
4.
5.
5.
5.
5.
5.
8.
5.
3.
5.
5.
5.
5.
.5
00
00
00
00
00
00
00
00
00
76
00
00
00
00
00
00
00
00
00
00
00
00
00
75
00
50
00
00
00
00
12
5.
5.
5.
5.
5.
5.
5.
10
5.
5.
5.
5.
5.
6.
5.
11
5.
5.
7.
5.
5.
5.
5.
8.
5.
5.
5.
5.
5.
5.
.5
00
00
00
00
00
00
00
.8
00
00
00
00
00
00
00
.9
00
50
50
00
00
00
00
75
00
00
00
00
00
00
12.5
6.88
8.13
5.00
43.8
30.0
47.5
25.0
17.5
10.0
10.5
8.75
5.00
5.00
15.0
6.25
19.4
10.0
12.0
13.8
5.00
5.00
5.00
5. 63
21.0
7.50
6.50
13.8
13.8
5.00
16.3
12.5
8.75
11.3
5.00
82.5
55.0
90.0
45.0
27.5
30.0
20.0
35.0
37.5
21.3
20.0
72.5
45.0
30.0
22.0
33.8
5.00
5.00
5.00
6.25
40.0
17.5
7.50
15.0
38.0
12.5
40.0
12.5
8.75
11.3
5.00
82.5
55.0
90.0
45.0
85.0
80.0
85.0
105
70.0
37.5
80.0
72.5
105
65.0
90.0
120
5.00
5.00
5.00
6.25
40.0
25.0
40.0
15.0
228
85.5
99.0
P25 MEDIAN P75 P95
6.25 11.3 20.3 140
14
-------
Eco_
Level_
III
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter DO_mg_L_Median
15
SEASON
MEAN
MIN
MAX
STDDEV
STDERR
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
75
73
75
43
43
34
45
47
138
120
161
141
76
78
78
70
220
190
335
176
41
44
52
41
37
31
69
35
52
51
78
8.
10
6.
11
9.
9.
7.
10
9.
9.
7.
11
8.
10
8.
11
9.
10
8.
11
8.
9.
7.
10
10
10
8.
12
9.
10
9.
96
.4
82
.0
45
39
24
.9
04
91
48
.4
61
.1
14
.2
34
.2
78
.5
59
33
52
.9
.2
. 6
82
.1
59
. 6
23
5.80
5.80
2.30
9.35
3.50
8.00
2.20
7.20
4.25
7.95
2.80
7.75
.550
7.40
.925
10.0
.725
6.50
.850
6.20
3. 60
7.15
5.05
8.70
8.45
7.20
5. 60
10.4
7.45
6.80
4.80
11,
14,
10,
14,
11,
11,
10,
13,
13,
12,
10,
14,
10,
12,
10,
14,
14,
14,
14,
14,
11,
11,
10,
13,
12,
12,
14,
13,
13,
12,
13,
.10
.50
.00
.10
.40
.10
.40
. 60
.41
.80
.20
.40
.80
.55
.25
. 60
. 60
.20
.00
.20
.45
.20
.30
.30
.20
.30
.20
.70
.10
.85
.50
1
1
1
1
1
0
1
1
1
0
1
1
2
0
1
0
2
1
1
1
1
0
1
0
0
1
1
0
1
1
1
.30
.99
.55
.04
.37
. 63
. 61
.38
.31
.90
.47
.32
.02
.94
.46
.74
.04
.48
.75
.31
. 66
.84
.03
.86
.89
.14
.49
.79
.19
.08
.98
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.15
.23
.18
.16
.21
.11
.24
.20
.11
.08
.12
.11
.23
.11
.17
.09
.14
.11
.10
.10
.26
.13
.14
.13
.15
.20
.18
.13
.17
.15
.22
CV
P5
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter DO_mg_L_Median
Eco
Level
III ~
70
SEASON
WINTER
N
50
MEAN
12.1
MIN
7.40
MAX
14.20
STDDEV
1.09
STDERR
0.15
CV
9
P5
10.3
P25
MEDIAN
P75
P95
15
19
23
9
15
7
22
13
15
9
20
12
23
9
18
7
22
15
20
11
19
9
14
8
9
11
17
6
12
10
21
6.
7.
3.
9.
7.
8.
3.
8.
6.
8.
4.
9.
1.
8.
6.
10
6.
7.
6.
9.
5.
8.
5.
9.
8.
7.
6.
10
7.
9.
6.
60
25
70
65
90
20
20
70
60
60
53
28
90
65
40
.3
09
90
55
50
90
10
70
60
80
90
90
.4
95
05
90
8.
8.
6.
10
8.
9.
6.
10
8.
9.
6.
10
8.
9.
8.
10
8.
9.
7.
10
7.
8.
6.
10
9.
9.
7.
11
8.
10
7.
00
90
13
.3
60
00
50
.0
34
21
70
.7
53
65
10
.8
25
10
80
.4
60
88
85
.4
65
95
90
.7
85
.0
78
9.
10
7.
10
9.
9.
7.
11
9.
9.
7.
11
9.
10
8.
11
9.
10
8.
11
9.
9.
7.
11
10
10
8.
12
9.
10
8.
00
.3
00
.9
80
43
65
.1
18
80
85
.3
20
.0
45
.0
60
.2
64
. 6
00
23
65
.1
.2
.8
60
.0
41
.5
55
10
11
7.
11
10
9.
7.
11
9.
10
8.
12
9.
10
8.
11
10
11
9.
12
9.
9.
8.
11
10
11
9.
12
9.
11
10
.1
.7
60
.4
.3
70
85
.7
85
.4
48
.3
64
. 6
73
.4
. 6
.3
60
.5
45
80
08
.4
.7
.4
20
. 6
95
.2
.7
10
14
9.
13
11
10
9.
13
10
11
9.
13
10
12
9.
12
12
12
12
13
11
10
9.
12
11
12
12
13
12
12
13
.8
.0
30
.1
.2
.7
50
.2
.9
.8
40
. 6
.5
.1
45
.7
.4
.7
.0
.5
.1
.9
00
.1
.8
.2
.3
.5
.4
.8
.0
P25 MEDIAN P75 P95
11.8 12.2 12.8 13.5
16
-------
Eco_
Level_
III
Eco_
Level_
III
70
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter N02_N03_mg_L_Median
17
SEASON
MEAN
MIN
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter N02_N03_mg_L_Median
SEASON N MEAN MIN
WINTER 116 0.85 .050
MAX
5.58
STDDEV
0.95
STDERR
0.09
CV P5
112 0.11
P75
P95
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
76
74
79
82
49
33
42
46
156
119
147
137
78
81
78
72
151
114
289
98
36
35
41
31
155
121
246
78
196
187
294
0.10
0.07
0.06
0.11
0. 66
0.44
0.32
0.51
1.42
0.95
0.99
1.38
0.15
0.22
0.20
0.25
0. 61
0.73
0.52
0.91
0.31
0.38
0.27
0.55
0.45
0.37
0.37
0.56
0.48
0.44
0. 64
.005
.010
.005
.005
.005
.005
.005
.009
.000
.010
.000
.010
.003
.003
.003
.003
.003
.003
.003
.005
.003
.003
.003
.010
.003
.025
.003
.030
.010
.003
.003
0. 61
0.39
0. 66
0.56
3.35
2.57
1.85
2.95
8. 60
4.71
8.94
6. 61
0.93
1.24
1.02
1.34
5.89
5.06
6. 60
6.03
1. 65
1.86
1.19
2.34
5.40
2.16
3.00
1.40
5.59
4.46
41.50
0.13
0.10
0.10
0.12
0.86
0. 64
0.50
0.81
1. 64
0.98
1.45
1.34
0.19
0.24
0.21
0.25
0.92
0.80
0.82
1.08
0.43
0.51
0.30
0.70
0.79
0.33
0.35
0.34
0. 69
0.71
2.83
0.01
0.01
0.01
0.01
0.12
0.11
0.08
0.12
0.13
0.09
0.12
0.11
0.02
0.03
0.02
0.03
0.07
0.08
0.05
0.11
0.07
0.09
0.05
0.12
0.06
0.03
0.02
0.04
0.05
0.05
0.17
130
135
173
109
131
148
156
158
115
103
146
97
125
108
105
101
149
110
159
119
142
134
113
126
175
89
93
60
144
161
440
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.05
0.03
0.06
0.00
0.02
0.00
0.01
0.03
0.04
0.03
0.08
0.01
0.00
0.00
0.03
0.02
0.05
0.10
0.12
0.02
0.01
0.01
0.01
0.01
0.01
0.01
0.06
0.04
0.02
0.01
0.24
0.24
0.18
0.36
0.02
0.06
0.06
0.07
0.21
0.25
0.15
0.30
0.04
0.07
0.05
0.16
0.09
0.16
0.19
0.35
0.10
0.07
0.06
0.06
0.03
0.02
0.08
0.34
0.12
0.08
0.09
0.78
0.52
0.44
0.94
0.09
0.17
0.16
0.19
0.36
0.51
0.28
0. 61
0.12
0.19
0.12
0.30
0.23
0.28
0.28
0.46
0.24
0.20
0.19
0.13
0.10
0.06
0.15
0.84
0.38
0.32
0.57
2.22
1.40
1.30
2.06
0.20
0.28
0.26
0.33
0. 65
0.91
0.52
1.10
0.35
0.35
0.37
0.46
0.46
0.47
0.41
0.77
0.59
0.50
0.45
0.43
0.32
0.26
0.39
2. 60
1.73
1.51
2.20
5.02
3.10
3.50
3.82
0.49
0. 60
0.80
0.76
2.00
1.98
1.82
2.31
1.39
1. 69
0.80
2.22
1.56
1.00
1.00
1.29
1. 66
2.38
1.75
P25 MEDIAN P75 P95
0.34 0.52 0.91 2.82
18
-------
Eco_
Level_
III
Eco_
Level_
III
70
SEASON
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Org_P_ug_L_Median
19
MEAN
MIN
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
P75
P95
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
0
0
0
0
0
0
0
0
10 3.95
0
10 7.76
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.770 8.21
.000 17.98
2.56
6.25
0.81
1.97
65
80
0.77
0.00
1.80
1.78
4.23
7.49
5.42 8.21
10.4 18.0
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Org_P_ug_L_Median
20
SEASON N MEAN
WINTER 0
MIN
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
P75
P95
-------
Eco_
Level_
III
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Orthophosphate_T_as_P_ug_L_Med
21
SEASON
MEAN
MIN
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Orthophosphate_T_as_P_ug_L_Med
Eco
Level
III ~
70
SEASON
WINTER
N
12
MEAN
34.0
MIN
5.00
MAX
150.00
STDDEV
40.1
STDERR
11. 6
CV
118
P5
5.00
P75
P95
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
2
2
2
1
0
0
0
0
4
4
4
4
3
3
4
3
9
9
22
7
2
2
2
2
2
2
18
2
13
13
13
6.25
8.75
8.75
5.00
.
.
.
.
39.7
46.3
30.3
30.0
23.3
20.8
21.2
32.9
19.7
14.3
13.1
14. 6
5.00
6.88
7.50
6.25
17.5
8.13
7.44
11.3
27.7
18.5
27.1
5
8
5
5
7
5
6
7
5
5
1
5
5
5
5
5
6
5
5
5
5
1
5
5
5
5
.00
.75
.00
.00
.50
.00
.25
.50
.00
.00
.00
.00
.00
.00
500
.00
.00
.25
.00
.00
.00
.00
.00
.00
.00
.00
.00
7,
8,
12,
5,
90,
160,
80,
90,
60,
50,
65,
85,
90,
45,
110,
45,
5,
7,
10,
7,
30,
11,
100,
17,
130,
110,
117,
.50
.75
.50
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.50
.00
.50
.00
.25
.00
.50
.00
.00
.50
1.77
0.00
5.30
.
.
.
.
.
35.3
75.9
33. 6
40.1
31.8
25.3
29.5
45.1
26.9
12. 6
23.8
13.9
0.00
0.88
3.54
1.77
17.7
4.42
23.2
8.84
35.9
28.8
33. 6
1.25
0.00
3.75
.
.
.
.
.
17. 6
37.9
16.8
20.0
18.3
14. 6
14.7
26.1
8.95
4.19
5.08
5.24
0.00
0. 63
2.50
1.25
12.5
3.13
5.46
6.25
9.96
7.98
9.31
28
0
61
.
.
.
.
.
89
164
111
134
136
121
139
137
136
88
182
95
0
13
47
28
101
54
311
79
130
156
124
5
8
5
5
7
5
6
7
5
5
1
5
5
5
0
5
5
6
5
5
5
5
1
5
5
5
5
.00
.75
.00
.00
.
.
.
.
.50
.00
.25
.50
.00
.00
.00
.00
.00
.00
.50
.00
.00
.25
.00
.00
.00
.00
.00
.00
.00
.00
.00
5.
8.
5.
5.
.
.
.
.
18
6.
10
8.
5.
5.
4.
5.
5.
6.
1.
5.
5.
6.
5.
5.
5.
5.
1.
5.
5.
5.
10
00
75
00
00
.8
25
. 6
75
00
00
88
00
00
25
00
00
00
25
00
00
00
00
00
00
00
00
.0
6.25
8.75
8.75
5.00
30. 6
10.0
17.5
11.3
5.00
7.50
9.38
8.75
12.5
10.0
5.25
10.0
5.00
6.88
7.50
6.25
17.5
8.13
1.00
11.3
10.0
8.75
12.5
7.50
8.75
12.5
5.00
.
.
.
.
60. 6
86.3
50.0
51.3
60.0
50.0
37.5
85.0
17.5
17.5
18.0
15.0
5.00
7.50
10.0
7.50
30.0
11.3
3.00
17.5
30.0
15.0
21.3
7.50
8.75
12.5
5.00
.
.
.
.
90.0
160
80.0
90.0
60.0
50.0
65.0
85.0
90.0
45.0
40.0
45.0
5.00
7.50
10.0
7.50
30.0
11.3
100
17.5
130
110
118
P25 MEDIAN P75 P95
12.5 20.0 40.0 150
22
-------
Eco_
Level_
III
Eco_
Level_
III
70
SEASON
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter TKN_mg_L_Median
23
MEAN
MIN
MAX
STDDEV
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
69
66
69
73
37
27
28
40
146
119
134
133
56
49
55
54
135
117
188
112
26
27
33
22
94
95
92
81
184
127
219
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.28
.17
.35
.27
.17
.33
.24
.13
.21
.32
.29
.18
.19
.17
.22
.16
.34
.36
.36
.33
.28
.16
.24
.28
.27
.25
.34
.22
.42
.30
.42
.010
.050
.050
.050
.050
.050
.050
.050
.010
.050
.050
.010
.025
.025
.050
.025
.000
.025
.025
.025
.010
.025
.025
.025
.025
.025
.025
.025
.050
.025
.025
1.
0,
1.
1.
0,
1.
0,
0,
1.
4,
2,
1.
0,
0,
0,
0,
2,
3,
2,
3,
1.
0,
0,
1.
2,
1.
2,
0,
4,
1.
3,
.34
.91
.27
.12
.71
.99
. 69
. 60
. 69
.40
.05
.00
.70
.38
.87
.73
.05
.30
.10
.00
.98
. 62
.83
.26
. 65
.21
. 66
.95
.20
.20
.00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.27
.20
.26
.24
.15
.37
.17
.14
.29
.50
.34
.22
.11
.09
.15
.10
.30
.40
.32
.37
.37
.14
.17
.32
.35
.21
.38
.17
.44
.21
.45
STDERR
CV
P5
P25
MEDIAN
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter TKN_mg_L_Median
SEASON N MEAN MIN
WINTER 122 0.28 .025
P75
P95
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
03
02
03
03
03
07
03
02
02
05
03
02
02
01
02
01
03
04
02
03
07
03
03
07
04
02
04
02
03
02
03
95
114
73
92
90
112
71
113
137
157
117
124
59
50
69
59
89
110
89
113
131
90
71
114
130
85
111
79
107
69
105
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
05
05
05
05
05
05
05
05
05
05
05
05
03
03
06
05
05
05
05
05
05
03
04
03
03
05
03
05
05
07
05
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.10
.05
.18
.05
.05
.10
.10
.05
.05
.05
.05
.05
.10
.10
.11
.10
.16
.20
.14
.18
.10
.04
.10
.10
.10
.13
.13
.10
.20
.17
.19
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
.20
.05
.30
.20
.13
.30
.20
.05
.05
.15
.18
.05
.20
.20
.20
.16
.30
.30
.30
.25
.23
.10
.22
.22
.18
.20
.23
.17
.30
.24
.30
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.34
.20
.50
.38
.24
.41
.35
.14
.25
.44
.40
.20
.23
.20
.25
.20
.40
.40
.49
.37
.30
.26
.32
.29
.30
.30
.40
.29
.50
.39
.50
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
1
0
1
0
1
.90
.73
.93
.80
. 62
.57
.50
.52
.84
.90
.85
.71
.40
.33
.45
.23
.75
.73
.90
.80
.48
.36
. 63
.12
.80
.87
.10
.59
.07
. 68
.30
MAX STDDEV STDERR CV P5 P25 MEDIAN P75 P95
1.10 0.20 0.02 70 0.05 0.13 0.24 0.40 0.69
24
-------
Eco_
Level_
III
SEASON
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter TN_mg_L_Median
25
MEAN
MIN
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter TN_mg_L_Median
Eco
Level
III ~
70
SEASON
WINTER
N
16
MEAN
1.48
MIN
.490
MAX
4.00
STDDEV
0.87
STDERR
0.22
CV
59
P5
0.49
P75
P95
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
1
2
5
4
2
2
2
2
30
18
31
19
2
6
5
4
55
92
174
44
2
2
2
1
11
98
42
9
17
34
29
0
0
0
0
2
1
1
2
0
1
0
1
0
0
0
0
0
0
1
1
0
0
0
0
1
0
0
1
1
0
1
.30
.40
.32
.45
.20
.47
.10
.39
.73
.13
.78
.29
. 65
.39
.56
. 69
.92
.90
.58
.26
.25
.40
.36
.75
.09
.59
.78
.26
.23
.98
.39
.300
.300
.210
.370
1.74
1.03
1.01
1.93
.020
.220
.110
.195
.300
.159
.205
.260
.080
.103
.047
.130
.200
.400
.200
.745
.570
.070
.120
.490
.345
.141
.196
0,
0,
0,
0,
2,
1.
1.
2,
3,
3,
3,
4,
0,
0,
1.
1.
4,
5,
11.
7,
0,
0,
0,
0,
1.
4,
3,
2,
4,
5,
7,
.30
.50
.51
.56
. 67
.91
.19
.84
.82
.96
.34
.91
.99
.99
.50
.43
.95
.10
.20
. 63
.30
.40
.53
.75
.79
.15
.82
.15
.20
.70
.40
0
0
0
0
0
0
0
0
1
0
1
0
0
0
0
1
1
1
1
0
0
0
0
0
0
0
0
1
1
.
.14
.12
.08
. 65
. 62
.13
. 65
.79
.07
.74
.28
.49
.32
.54
.51
.31
.06
.92
. 60
.07
.00
.23
.
.49
.55
.75
.44
.92
.17
.55
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.
.10
.05
.04
.46
.44
.09
.46
.14
.25
.13
.29
.35
.13
.24
.25
.18
.11
.15
.24
.05
.00
.16
.
.15
.06
.12
.15
.22
.20
.29
.
35
36
18
30
43
12
27
108
95
94
100
76
80
97
74
142
118
121
128
28
0
63
.
45
93
96
35
75
120
111
0
0
0
0
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.30
.30
.21
.37
.74
.03
.01
.93
.02
.22
.17
.20
.30
.16
.21
.26
.09
.16
.15
.13
.20
.40
.20
.75
.57
.13
.20
.49
.35
.19
.21
0
0
0
0
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
.30
.30
.24
.40
.74
.03
.01
.93
.27
.43
.33
.46
.30
.20
.26
.39
.16
.25
.39
.18
.20
.40
.20
.75
. 69
.25
.31
.10
. 65
.27
.50
0,
0,
0,
0,
2,
1.
1.
2,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
1.
0,
0,
0,
.30
.40
.30
.44
.20
.47
.10
.39
.51
.51
.49
.59
. 65
.26
.30
.53
.29
.43
.79
.56
.25
.40
.36
.75
.80
.45
. 60
.20
.95
.70
.89
0
0
0
0
2
1
1
2
1
2
0
2
0
0
0
0
1
1
1
1
0
0
0
0
1
0
0
1
1
1
1
.30
.50
.33
.51
. 67
.91
.19
.84
.06
.04
.88
.30
.99
.50
.53
.99
.10
.18
.85
. 63
.30
.40
.53
.75
. 67
.78
.92
.48
.55
.10
.50
0
0
0
0
2
1
1
2
2
3
2
4
0
0
1
1
4
3
6
4
0
0
0
0
1
1
2
2
4
4
4
.30
.50
.51
.56
. 67
.91
.19
.84
.11
.96
.20
.91
.99
.99
.50
.43
. 60
.13
.16
. 68
.30
.40
.53
.75
.79
.47
.16
.15
.20
.55
.35
P25 MEDIAN P75 P95
0.93 1.29 1.58 4.00
26
-------
Eco_
Level_
III
Eco_
Level_
III
70
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter TP_ug_L_Median
27
SEASON
MEAN
MIN
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter TP_ug_L_Median
SEASON
WINTER
N
139
MEAN
60.9
MIN MAX STDDEV STDERR CV
.000 1012.50 105 8.86 172
P75
P95
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
84
80
86
85
49
36
45
47
180
150
175
158
79
87
84
73
279
268
533
200
38
42
51
34
159
217
291
90
218
223
326
42.
21.
46.
39.
34.
36.
41.
27.
88.
, 6
,2
,2
,1
,9
,1
,3
,5
,8
104
98.
87.
28.
26.
42.
29.
88.
44.
54.
61.
70.
39.
64.
41.
26.
23.
21.
17.
78.
47.
65.
,0
,5
,1
,2
,7
,8
,2
,9
,1
,0
,7
,4
, 6
,1
,1
,3
,3
,8
, 6
,1
,5
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
.000
2.50
2.50
2.50
.000
.000
.000
.000
.000
.000
.000
1.50
.000
.000
.000
2.50
.000
1.00
.000
1.50
2.50
2.50
285,
150,
375,
347,
110,
115,
270,
205,
2210,
2080,
2400,
1910,
190,
150,
410,
237,
2240,
725,
1870,
905,
650,
315,
735,
350,
950,
490,
327,
90,
1190,
950,
1550,
.00
.00
.00
.50
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.50
.75
.00
.00
.75
.00
.00
.00
.00
.00
.00
.50
.00
.00
.00
.00
54.9
26.3
54. 6
50. 6
31.4
30.3
53.9
37. 6
238
296
272
255
35.1
28. 6
64.9
38.7
226
70.7
127
112
142
55.0
159
69. 6
82.1
41.3
33.4
15.9
159
105
137
5.99
2.94
5.89
5.49
4.49
5.05
8.03
5.48
17.7
24.2
20.5
20.3
3.95
3.06
7.08
4.53
13. 6
4.32
5.49
7.90
23.1
8.49
22.2
11.9
6.51
2.81
1.96
1. 67
10.8
7.06
7.58
129
124
118
129
90
84
131
137
268
283
277
291
125
109
152
130
257
158
234
183
201
140
246
169
314
177
157
89
203
224
209
5.
2.
5.
2.
5.
2.
2.
2.
2.
4.
2.
2.
2.
2.
2.
2.
5.
2.
2.
3.
4.
0.
1.
0.
5.
3.
5.
2.
5.
5.
5.
00
50
00
50
00
50
50
50
50
00
50
50
50
50
50
50
00
50
50
13
00
00
00
00
00
00
00
50
00
00
00
10.9
5.00
20.0
10.0
6.25
10. 6
5.00
2.50
6.25
7.00
8.00
5.00
7.00
5.00
7.25
8.00
10.0
10.0
10.0
10.0
6.00
5.00
6.00
6.00
5.50
7.00
9.00
8.25
10.0
10.0
10.0
25
11
30
22
22
25
20
10
24
28
27
25
15
12
21
17
25
20
20
28
21
20
20
10
10
12
10
11
29
22
30
. 6
.3
.0
.5
.5
.0
.0
.0
.3
.8
.9
.0
.0
.5
.3
.5
.0
.0
.0
.8
.5
.0
.0
.0
.0
.5
.0
.5
.1
.0
.0
40.
28.
50.
40.
50.
60.
50.
32.
55.
70.
70.
45.
35.
40.
50.
32.
65.
54.
50.
63.
50.
55.
30.
40.
20.
26.
22.
22.
60.
40.
60.
,0
,8
,0
,0
,0
,0
,0
,5
,0
,0
,0
,0
,0
,0
,0
,5
,0
,5
,0
,8
,0
,0
,0
,0
,0
,0
,0
,5
,0
,0
,0
158
72.5
130
120
103
90.0
125
92.5
403
325
368
400
110
85.0
170
108
335
155
230
188
520
118
470
205
90.0
71.0
63.8
45.0
430
135
255
P5 P25 MEDIAN P75 P95
5.00 15.0 30.0 65.0 208
28
-------
Eco_
Level_
III
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Turb FTU Median
29
SEASON
MEAN
MIN
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Turb FTU Median
Eco
Level
III ~
70
SEASON
WINTER
N
14
MEAN
20.2
MIN
1.05
MAX
97.00
STDDEV
24.7
STDERR
6.59
CV
122
P5
1.05
P25
5.20
P75
P95
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
58
64
56
26
29
23
22
37
77
67
80
95
56
54
57
56
52
48
46
49
2
2
2
2
19
30
19
14
20
26
28
14.4
17.1
15.2
21.9
3.11
6.53
2.56
2. 67
4.31
9.94
3.77
2.89
3.45
4.85
6.50
5.09
6.81
8.88
8.25
9.90
1. 63
3.25
1.93
4.54
5.55
3. 69
12.9
9. 69
9.57
13.4
9.43
1.00
1.40
.500
2.10
.700
.250
.888
. 600
.300
.250
.275
.250
.250
.250
.250
.250
1.00
1.40
1.40
1.78
1.30
2.50
1.45
3.00
.700
1.10
1.30
1.40
.500
1.05
1.00
75.
70.
102.
63.
9.
20.
12.
15.
95.
140.
82.
33.
17.
25.
25.
61.
53.
27.
24.
57.
1.
4.
2.
6.
25.
13.
75.
80.
33.
57.
42.
,00
, 60
,00
,50
,30
,00
,10
,00
,25
,50
,25
,00
,00
,00
,00
,20
,00
,00
,00
,50
,95
,00
,40
,08
,98
,00
,05
,00
,40
,00
,50
11.9
12.3
16.9
19.5
2.06
6.03
2.31
2.58
11.7
26.8
9. 61
4.81
3.08
4.45
5.48
8. 69
8.01
6.10
5.79
9.57
0.46
1.06
0. 67
2.17
6.37
2.92
22.1
20.4
7.96
11.8
9.29
1
1
2
3
0
1
0
0
1
3
1
0
0
0
0
1
1
0
0
1
0
0
0
1
1
0
5
5
1
2
1
.56
.54
.25
.83
.38
.26
.49
.42
.33
.28
.07
.49
.41
. 61
.73
.16
.11
.88
.85
.37
.33
.75
.48
.54
.46
.53
.08
.46
.78
.31
.76
83
72
111
89
66
92
90
97
271
270
255
166
89
92
84
171
117
69
70
97
28
33
35
48
115
79
172
211
83
88
99
2
3
1
2
0
0
0
0
0
0
0
0
0
0
0
0
1
2
2
2
1
2
1
3
0
1
1
1
2
1
1
.55
. 60
.10
.98
.80
.40
.98
.70
.50
.50
.40
.40
.25
.25
.25
.25
.20
.10
.00
.00
.30
.50
.45
.00
.70
.10
.30
.40
.00
.40
.05
8.
10
5.
5.
1.
2.
1.
1.
0.
1.
0.
0.
1.
1.
2.
1.
2.
4.
3.
4.
1.
2.
1.
3.
1.
1.
2.
2.
4.
5.
3.
10
.1
35
40
73
10
53
00
90
00
93
80
50
85
70
30
65
80
70
80
30
50
45
00
70
60
65
10
30
80
30
13.0
14.8
9. 63
14.5
2. 60
4.05
1.95
2.00
1.40
2.50
1.55
1.30
2. 60
4.03
4. 60
2.99
4. 63
7.53
6.75
6. 60
1. 63
3.25
1.93
4.54
2.50
2.50
5.70
3.75
7.13
10.3
5.11
17.3
20. 6
17.3
35.0
3.50
9.75
2.70
3.30
2.70
5.00
2.38
2.75
5.00
6.00
8.80
5.86
7.75
11.8
11.5
12.8
1.95
4.00
2.40
6.08
9.30
5.00
9.50
7.00
11.5
18.5
15.2
44.0
33.0
43.0
61.0
7. 60
19.0
3.95
6.70
19.8
23.0
12. 6
7.35
8.20
13.4
17.0
17.3
19.0
24.3
20.0
22.0
1.95
4.00
2.40
6.08
26.0
9.15
75.1
80.0
28.0
35.0
23. 6
MEDIAN P75 P95
12.5 22.8 97.0
30
-------
Eco_
Level_
III
Eco_
Level_
III
70
SEASON
SEASON
WINTER
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Turb JCU Median
31
MEAN
MIN
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Turb JCU Median
N MEAN
2 10.7
MIN
4.30
MAX
17.00
STDDEV
STDERR
6.35
CV P5
84 4.30
P75
P95
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
0
0
4
4
2
2
3
2
6
5
6
6
8
14
10
8
11
16
12
16
10
12
11
12
4
4
4
4
0
1
1
.
.
7.
17
19
3.
3.
4.
3.
5.
2.
4.
1.
3.
2.
2.
3.
7.
6.
7.
2.
2.
2.
2.
3.
3.
4.
5.
.
9.
23
93
.0
. 6
19
17
73
11
41
26
00
26
13
54
19
82
79
79
24
04
50
35
88
51
85
70
81
50
.0
2.70
9.50
5.00
.500
.900
4.55
.700
.800
.800
1.00
.500
. 600
.500
. 600
.950
2.00
1.70
.700
1.05
.500
.500
.000
. 600
.500
.500
1.00
9.50
23.0
12.
24.
34.
5.
5.
4.
9.
14.
3.
9.
2.
8.
9.
5.
15.
20.
32.
20.
5.
6.
8.
8.
5.
6.
7.
11.
9.
23.
,00
,50
,20
,88
,00
,90
,35
,25
,55
,95
,40
,05
,80
,30
,00
,80
,00
,35
,50
,90
,30
,90
, 60
,80
,05
,85
,50
,00
.
.
4.
6.
20
3.
2.
0.
3.
5.
1.
3.
0.
2.
3.
1.
4.
5.
8.
5.
1.
1.
2.
2.
2.
2.
2.
4.
.
.
.
44
34
. 6
80
08
25
30
36
04
35
77
76
30
56
14
22
10
89
38
81
32
55
10
67
90
52
.
.
2.
3.
14
2.
1.
0.
1.
2.
0.
1.
0.
0.
1.
0.
1.
1.
2.
1.
0.
0.
0.
0.
1.
1.
1.
2.
.
.
.
22
17
. 6
69
20
17
35
40
42
37
27
74
04
55
25
31
34
47
43
52
70
73
05
34
45
26
.
.
56
37
105
119
66
5
106
99
46
84
61
88
130
71
108
67
119
81
67
72
99
88
60
69
62
78
.
.
.
.
.
2.
9.
5.
0.
0.
4.
0.
0.
0.
1.
0.
0.
0.
0.
0.
2.
1.
0.
1.
0.
0.
0.
0.
0.
0.
1.
.
9.
23
70
50
00
50
90
55
70
80
80
00
50
60
50
60
95
00
70
70
05
50
50
00
60
50
50
00
50
.0
.
.
4.
12
5.
0.
0.
4.
0.
1.
1.
1.
0.
1.
0.
1.
1.
4.
3.
3.
1.
1.
0.
0.
2.
1.
2.
2.
.
9.
23
25
.3
00
50
90
55
75
90
90
48
60
15
60
00
55
30
78
08
20
23
65
98
14
85
88
75
50
.0
8.
17
19
3.
3.
4.
1.
3.
1.
3.
1.
1.
0.
1.
2.
6.
4.
5.
1.
1.
1.
2.
3.
4.
5.
5.
9.
23
50
.0
. 6
19
60
73
93
85
96
35
00
75
98
75
10
15
65
58
55
95
60
30
91
05
63
20
50
.0
.
.
11. 6
21.8
34.2
5.88
5.00
4.90
4.00
6.25
3.40
4.90
1.98
6.20
2.50
3.05
3. 60
8.75
5.84
9.98
2.10
3.25
3.50
4.40
4.88
5.85
6.53
8.88
.
9.50
23.0
.
.
12.0
24.5
34.2
5.88
5.00
4.90
9.35
14.3
3.55
9.95
2.40
8.05
9.80
5.30
15.0
20.8
32.0
20.4
5.50
6.90
8.30
8.90
5. 60
6.80
7.05
11.9
.
9.50
23.0
P25 MEDIAN P75 P95
4.30 10.7 17.0 17.0
32
-------
Eco_
Level_
III
SEASON
MEAN
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Turb NTU Median
33
MIN
36
36
36
36
38
38
38
38
39
39
39
39
66
66
66
66
67
67
67
67
68
68
68
68
69
69
69
69
70
70
70
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
WINTER
FALL
SPRING
SUMMER
27
26
26
25
24
21
25
19
66
64
72
55
12
8
7
4
54
95
146
38
29
30
36
24
18
104
60
14
15
34
33
8. 61
13.4
9.39
12.8
7.50
11.7
7.03
9.42
5.85
7.84
5.00
7.79
4.40
3.53
3.39
2.33
6.18
7.00
5.41
9.15
4.11
5.72
4.88
8.46
5.92
7.15
6.22
9.00
9.47
14.5
17.4
2.20
2.78
2.20
3.55
. 600
1. 60
.800
1.40
.000
.500
.000
.250
.250
.400
1.00
.250
1.00
.250
.200
1.50
. 600
1.05
. 600
2.30
1.00
.200
.200
1.25
1.00
.700
.700
MAX
STDDEV
STDERR
CV
P5
P25
MEDIAN
Aggregate Nutrient Ecoregion: XI
Rivers and Streams
Descriptive Statistics by Decade and Season
Parameter Turb NTU Median
Eco
Level
III ~
70
SEASON
WINTER
N
12
MEAN
16.0
MIN
.250
MAX
30.00
STDDEV
10.8
STDERR
3.11
CV
67
P5
0.25
P75
P95
24.
34.
46.
24.
39.
45.
46.
57.
48.
58.
34.
82.
9.
10.
7.
7.
17.
104.
81.
22.
13.
17.
18.
33.
15.
200.
57.
37.
18.
92.
114.
,75
, 60
,00
,50
,00
,00
,00
,00
,00
,75
,40
,00
,80
,40
, 65
,09
,25
,50
, 65
,85
,05
,00
,10
,00
,50
,00
,00
,50
,50
,00
,00
5.96
9.36
9.13
5.98
8.14
10.3
10.3
13.0
9.23
9.79
6.13
17.5
3.08
3.77
2.36
3.19
3.72
11.5
8.16
5.14
2.94
3.43
2.95
6.88
4.05
21.1
9. 63
9.48
5.11
17.4
25. 6
1
1
1
1
1
2
2
2
1
1
0
2
0
1
0
1
0
1
0
0
0
0
0
1
0
2
1
2
1
2
4
.15
.84
.79
.20
. 66
.25
.07
.99
.14
.22
.72
.36
.89
.33
.89
.59
.51
.18
. 68
.83
.55
. 63
.49
.40
.95
.07
.24
.53
.32
.99
.46
69
70
97
47
109
88
147
138
158
125
123
225
70
107
70
137
60
164
151
56
72
60
60
81
68
295
155
105
54
120
147
2
2
2
3
1
2
1
1
0
0
0
0
0
0
1
0
1
0
0
1
0
2
1
2
1
0
0
1
1
1
0
.28
.80
.50
. 65
.20
.75
.30
.40
.00
.83
.25
.25
.25
.40
.00
.25
.40
. 60
.50
.55
.75
.40
.45
.43
.00
. 60
.45
.25
.00
.00
.70
3
5
4
7
3
5
2
3
1
2
1
1
1
1
1
0
3
1
1
5
2
3
3
4
3
1
1
4
5
3
2
.80
. 60
.80
.05
.05
.10
.40
.23
.50
.25
.21
.35
.43
.00
.00
. 63
.00
.80
. 60
.00
.00
.10
.39
.50
.00
.25
.35
.00
.25
.90
.40
7.
11
6.
13
4.
7.
3.
5.
2.
4.
3.
2.
5.
1.
3.
1.
5.
4.
3.
7.
3.
5.
4.
6.
4.
2.
3.
5.
9.
8.
10
10
.9
30
.0
75
40
85
90
79
15
00
20
15
30
40
00
73
05
15
88
45
25
31
20
90
80
10
00
00
45
.5
13.5
17.5
10.4
17.0
9.88
16.0
5.20
8.45
5.00
8.75
6.00
4.08
5.71
6.40
4.45
4.04
8.70
8.40
6.30
13.0
5.15
7.13
5.73
9. 65
8.70
5.18
6.00
13.0
14.0
20.0
17.0
20.0
31.0
28.0
22.8
16.0
28.0
33.0
57.0
26.5
23.5
15.9
64.0
9.80
10.4
7. 65
7.09
12.3
19.5
15.5
18.8
10.4
14.1
8.50
19. 6
15.5
19.5
22.9
37.5
18.5
44.0
103
P25 MEDIAN P75 P95
7.63 16.0 25.8 30.0
34
-------
APPENDIX C
Quality Control/Quality Assurance Rules
-------
Support for the Compilation and Analysis of National Nutrient Data
15 Nutrient Ecoregion/Waterbody Type Summary Chapters
Prepared for:
Robert Cantilli
Environmental Protection Agency
OW/OST/HECD
Prepared by:
INDUS Corporation
1953 Gallows Road
Vienna, Virginia 22182
Contract Number: 68-C-99-226
Task Number: 04
Subtask Number: 4
August 8, 2000
-------
CONTENTS
1.0 BACKGROUND 1
1.1 Purpose 1
1.2 References 1
2.0 QA/QC PROCEDURES 2
2.1 National Data Sets 3
2.2 State Data 3
2.3 Laboratory Methods 4
2.4 Waterbody Name 4
2.5 Ecoregion Data 5
3.0 STATISTICAL ANALYSIS REPORTS 5
3.1 Data Source Reports 6
3.2 Remark Code Reports 7
3.3 Median of Each Waterbody 7
3.4 Descriptive Statistic Reports 7
3.5 Regression Models 8
4.0 TIME PERIOD 8
5.0 DATA SOURCES AND PARAMETERS FOR THE AGGREGATE NUTRIENT
ECOREGIONS 9
5.1 Lakes and Reservoirs 9
5.1.1 Aggregate Nutrient Ecoregion 2 9
5.1.2 Aggregate Nutrient Ecoregion 6 10
5.1.3 Aggregate Nutrient Ecoregion 7 10
5.1.4 Aggregate Nutrient Ecoregion 8 11
5.1.5 Aggregate Nutrient Ecoregion 9 12
5.1.6 Aggregate Nutrient Ecoregion 11 12
5.1.7 Aggregate Nutrient Ecoregion 12 13
5.1.8 Aggregate Nutrient Ecoregion 13 13
5.2 Rivers and Streams 14
5.2.1 Aggregate Nutrient Ecoregion 2 14
5.2.2 Aggregate Nutrient Ecoregion 3 15
5.2.3 Aggregate Nutrient Ecoregion 6 16
5.2.4 Aggregate Nutrient Ecoregion 7 16
5.2.5 Aggregate Nutrient Ecoregion 9 17
5.2.6 Aggregate Nutrient Ecoregion 11 18
5.2.7 Aggregate Nutrient Ecoregion 12 19
5.2.8 Aggregate Nutrient Ecoregion 14 20
-------
APPENDIX A Process Used to QA/QA the Legacy STORE! Nutrient Data Set
APPENDIX B Process for Adding Aggregate Nutrient Ecoregions and Level III
Ecoregions
APPENDIX C Glossary
in
-------
15 Nutrient Ecoregion/Waterbody Type Summary Chapters, Contract # 68-C-99-226, TO# 04 August 8, 2000
1.0 BACKGROUND
The Nutrient Criteria Program has initiated development of a national Nutrient Criteria Database
application that will be used to store and analyze nutrient data. The ultimate use of these data will
be to derive ecoregion- and waterbody-specific nutrient criteria ranges. EPA converted STOrage
and RETrieval (STORET) legacy data, National Stream Quality Accounting Network
(NASQAN) data, National Water-Quality Assessment (NAWQA) data, and other relevant
nutrient data from universities and States/Tribes into the database. The data imported into the
Nutrient Criteria Database will be used to develop national nutrient criteria ranges.
1.1 Purpose
The purpose of this deliverable is to provide EPA with information regarding the data used to
create the statistical reports which will be used to derive ecoregion- and waterbody-specific
nutrient criteria ranges for Level III ecoregions. There are fourteen aggregate nutrient
ecoregions. Each aggregate nutrient ecoregion is divided into smaller ecoregions referred to as
Level III ecoregions. EPA will determine criteria ranges for the waterbody types and Level III
ecoregions within the following aggregate nutrient ecoregions:
Lakes and Reservoirs
Aggregate Nutrient ecoregions: 2, 6, 7, 8, 9, 11, 12, 13
• Rivers and Streams
Aggregate Nutrient ecoregions: 2, 3, 6, 7, 9, 11, 12, 14
1.2 References
This section lists documents that contain baselines, standards, guidelines, policies, and references
that apply to the data analysis. Listed editions were valid at the time of publication. All
documents are subject to revision, but these specific editions govern the concepts described in this
document.
Nutrient Criteria Technical Guidance Manual: Lakes and Reservoirs (Draft). EPA, Office of
Water, EPA 822-D-99-001, April 1999.
Nutrient Criteria Technical Guidance Manual: Rivers and Streams (Draft). EPA, Office of
Water, EPA 822-D-99-003, September 1999.
Guidance for Data Quality Assessment: Practical Methods for Data Analysis. EPA, Office of
Research and Development, EPA QA/G-9, January 1998.
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2.0 QA/QC PROCEDURES
In order to develop nutrient criteria, EPA needed to obtain nutrient data from the states. EPA
requested nutrient data from the states and forwarded the data sets to INDUS via e-mail and/or
US mail. In addition, EPA tasked INDUS to convert data from three national data sets. EPA
provided INDUS with a Legacy STORET extraction to convert into the database. The United
States Geologic Survey (USGS) sent INDUS a CD-ROM with NASQAN data to convert.
INDUS downloaded NAWQA files from the USGS Web site to convert the data. In total,
INDUS converted and imported the following national and state data sets into the Nutrient
Criteria Database:
Legacy STORET
NAWQA
NASQAN
• Region 1
• Region 2 - Lake Champlain Monitoring Project
• Region 2 - NYSDEC Finger Lakes Monitoring Program
• Region 2 - NY Citizens Lake Assessment Program
• Region 2 - Lake Classification and Inventory Survey
Region 2 - NYCDEP (1990-1998)
Region 2 - NYCDEP (Storm Event data)
Region 2 - New Jersey Nutrient Data ( Tidal Waters)
• Region 5
• Region 3
• Region 3 - Nitrite Data
• Region 3 - Choptank River files
• Region 4 - Tennessee Valley Authority
• Region 7 - Central Plains Center for BioAssessment (CPCB)
Region 7 - REMAP
• Region 2 - Delaware River Basin Commission (1990-1998)
• Region 3 - PA Lake Data
• Region 3 - University of Delaware
• Region 10
• University of Auburn
As part of the conversion process, INDUS performed a number of Quality Assurance/Quality
Control (QA/QC) steps to ensure that the data was properly converted into the Nutrient Criteria
Database. Section 2 explains the steps performed by INDUS to convert the data.
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2.1 National Data Sets
INDUS converted three national data sets into the Nutrient Criteria Database: Legacy STORET
data, NASQAN data, and NAWQA data. A previous EPA contractor performed the extraction of
Legacy STORET data and documented the QA/QC procedures used on the data. This
documentation is included in Appendix A. INDUS performed minimal QA/QC on the Legacy
STORET data set because the previous contractor completed the steps outlined in Appendix A.
INDUS and EPA also agreed to convert the NAWQA and NASQAN data sets with minimal
QA/QC on the assumption that the source agency, the USGS, QA/QC'd the data.
For each of the three national data sets, INDUS ran queries to determine if 1) samples existed
without results and 2) if stations existed without samples. Per Task Order Project Officer
(TOPO) direction, these records were deleted from the system. For analysis purposes, EPA
determined that there was no need to keep station records with no samples and sample records
with no results. INDUS also confirmed that each data set contained no duplicate records.
In addition, INDUS deleted all composite results from the Legacy STORET data. Per TOPO
direction, it was decided that composite sample results would not be used in the statistical
analysis.
2.2 State Data
Each state data set was delivered in a unique format. Many of the data sets were delivered to
INDUS without corresponding documentation. INDUS analyzed each state data set in order to
determine which parameters should be converted for analysis. INDUS obtained a master
parameter table from EPA and converted the parameters in the state data sets according to those
that were present in the EPA parameter table. INDUS converted all of the data elements in the
state data sets that mapped directly to the Nutrient Criteria Database; data elements that did not
map to the Nutrient Criteria Database were not converted. In some cases, state data elements
that did not directly map into the Oracle database were inserted into a comment field within the
database. Also, INDUS maintained an internal record of which state data elements were inserted
into the comment field.
As part of the data clean-up efforts, INDUS determined whether or not there were any duplicate
records in the state data sets and deleted the duplicate records. INDUS checked the waterbody,
station, and sample entities for duplicate records. In addition, INDUS deleted station records
with no samples and sample records with no results. INDUS also deleted waterbody records that
were not associated with a station. In each case, INDUS maintained an internal record of how
many records were deleted.
If INDUS encountered referential integrity errors, such as samples that referred to stations that
did not exist, or if INDUS was unsure of whether a record was a duplicate, INDUS contacted the
agency directly via e-mail or phone to resolve any issues that arose. INDUS saved an electronic
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copy of each e-mail correspondence with the states to ensure that a record of the decision was
maintained. INDUS also contacted each agency to determine which laboratory methods were
used for each parameter.
Finally, INDUS examined the remark codes of each result record in the state data sets. INDUS
mapped the remark codes to the STORET remark codes listed in Table 2 of Appendix A. If any
of the state result records were associated with remark codes marked as "Delete" in Table 2 of
Appendix A, the result records were not converted into the database.
2.3 Laboratory Methods
Many of the state data sets did not contain laboratory method information. In addition, laboratory
method information was not available for the three national data sets. In order to determine
missing laboratory method information, EPA tasked another contractor to contact the data
owners to obtain the laboratory method. In some cases, the data owners responded and the
laboratory methods were added to the database.
2.4 Waterbody Name and Class Information
A large percentage of the data did not have waterbody-specific information. The only waterbody
information contained in the three national data sets was the waterbody name, which was
embedded in the station 'location description' field. Most of the state data sets contained
waterbody name information; however, much of the data was duplicated throughout the data sets.
Therefore, the waterbody information was cleaned manually. For the three national data sets, the
'location description' field was extracted from the station table and moved to a temporary table.
The 'location description' field was sorted alphabetically. Unique waterbodies were grouped
together based on name similarity and whether or not the waterbodies fell within the same county,
state, and waterbody type. Finally, the 'location description' field was edited to include only
waterbody name information, not descriptive information. For example, 110 MILE CREEK AT
POMONA DAM OUTFLOW, KS PO-2 was edited to 110 MILE CREEK. Also, if 100 MILE
CREEK was listed ten times in New York, but in four different counties, four 100 MILE CREEK
waterbody records were created.
Similar steps were taken to eliminate duplicate waterbody records in the state data sets. If a
number of records had similar waterbody names and fell within the same state, county, and
waterbody type, the records were grouped to create a unique waterbody record.
Most of the waterbody data did not contain depth, surface area, and volume measurements. EPA
needed this information to classify waterbody types. EPA attempted to obtain waterbody class
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information from the states. EPA sent waterbody files to the regional coordinators and requested
that certain class information be completed by each state. The state response was poor; therefore,
EPA was not able to perform statistical analysis for the waterbody types by class.
2.5 Ecoregion Data
Aggregate nutrient ecoregions and Level III ecoregions were added to the database using the
station latitude and longitude coordinates. If a station was lacking latitude and longitude
coordinates or county information, the data were not included in the statistical analysis. Appendix
B lists the steps taken to add the two ecoregion types (aggregate and Level III) to the Nutrient
Criteria Database. The ecoregion names were pulled from aggregate nutrient ecoregion and Level
III ecoregion Geographical Information System (GIS) coverages. In summary, the station latitude
and longitude coordinates were used to determine the ecoregion under the following
circumstances:
The latitude and longitude coordinates fell within the county/state listed in the station
table.
The county data was missing.
The county centroid was used to determine the ecoregions under the following circumstances:
The latitude and longitude coordinates were missing, but the state/county information was
available.
The latitude and longitude coordinates fell outside the county/state listed in the station
table. The county information was assumed to be correct; therefore, the county centroid
was used.
If the latitude and longitude coordinates fell outside the continental US county coverage file
(i.e., the point fell in the ocean or Mexico/Canada), the nearest ecoregion was assigned to the
station.
3.0 STATISTICAL ANALYSIS REPORTS
Aggregate nutrient ecoregion tables were created by extracting all observations for a specific
aggregate nutrient ecoregion from the nutrient criteria database. Then, the data were reduced to
create tables containing only the yearly median values. To create these tables, the median value
for each waterbody was calculated using all observations for each waterbody by Level III
ecoregion, year, and season. Tables of decade median values were created from the yearly
median tables by calculating the median for each waterbody by Level III ecoregion by decade and
season.
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The Data Source and the Remark Code reports were created using all observations (all reported
values). All the other reports were created from either the yearly median tables or the decade
median tables. In other words, the descriptive statistics and regressions were run using the
median values for each waterbody and not the individual reported values.
Statistical analyses were performed under the assumption that this data set is a random sample. If
this assumption cannot be verified, the observations may or may not be valid. Values below the
1st and 99th percentile were removed from the Legacy STORET database prior to the creation of
the national database. Also, data were treated according the Legacy STORET remark codes in
Appendix A.
The following contains a list of each report and the purpose for creating each report:
Data Source Created to provide a count of the amount of data and to identify the
source(s).
Remark Codes Created to provide a description of the data.
• Median of Each Waterbody by Year This was an intermediate step performed to obtain a
median value for each lake to be used in the yearly descriptive statistics reports and the
regression models.
Median of Each Waterbody by Decade This was an intermediate step performed to obtain
a median value for each lake to be used in the decade descriptive statistics.
Descriptive Statistics Created to provide EPA with the desired statistics for setting criteria
levels.
Regression Models Created to examine the relationships between biological and nutrient
variables.
Note: Separate reports were created for each season.
3.1 Data Source Reports
Data source reports were presented in the following formats:
• The number and percentage of data from each data source were summarized in tables for
each aggregate nutrient ecoregion by season and waterbody type.
The number and percentage of data from each data source were summarized in tables for
each Level III ecoregion by season and waterbody type.
The 'Frequency' represents the number of data values from a specific data source for each
parameter by data source. The 'Row Pet' represents the percentage of data from a specific data
source for each parameter.
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3.2 Remark Code Reports
Remark code reports were presented in the following formats:
• The number and percentage of data associated with a particular remark code for each
parameter were summarized in tables by Level III ecoregion by decade and season.
The number and percentage of data associated with a particular remark code for each
parameter were summarized in tables by Level III ecoregion by year and season.
The 'Frequency' represents the number of data values corresponding to the remark code in the
column. The 'Row Pet' represents the percentage of data that was associated with the remark
code in that row.
In the database, remark codes that were entered by the states were mapped to Legacy STORET
remark codes. Prior to the analysis, the data were treated according to these remark codes. For
example, if the remark code was 'K,' then the reported value was divided by two. Appendix A
contains a complete list of Legacy STORET remark codes.
Note: For the reports, a remark code of'Z' indicates that no remark codes were recorded. It does
not correspond to Legacy STORET code 'Z.'
3.3 Median of Each Waterbody
To reduce the data and to ensure heavily sampled waterbodies or years were not over represented
in the analysis, median value tables (described above) were created. The yearly median tables and
decade median tables were delivered to the EPA in electronic format as csv (comma separated
value or comma delimited) files.
3.4 Descriptive Statistic Reports
The number of waterbodies, median, mean, minimum, maximum, 5th, 25th , 75th , 95th
percentiles, standard deviation, standard error, and coefficient of variation were calculated. The
tables (described above) containing the decade median values for each waterbody for each
parameter were used to create descriptive statistics reports for:
• Level III ecoregions by decade and season
Aggregate nutrient ecoregions by decade and season
In addition, the tables containing the yearly median values for each waterbody for each parameter
were used to create descriptive statistics reports for:
• Level III ecoregions by year and season
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3.5 Regression Models
Simple linear regressions using the least squares method were performed to examine the
relationships between biological and nutrient variables in lakes and reservoirs, and rivers and
streams. Regressions were performed using the yearly median tables. Chlorophyll(s) in
micrograms per liter (ug/L), secchi in meters (m), dissolved oxygen in milligrams per liter (mg/L),
turbidity, and pH were the biological variables in these models. When there was little or no data
for chlorophyll, then pH or dissolved oxygen was substituted for chlorophyll. Secchi data were
used in the lake and reservoir models, and turbidity data were used in the river and stream models.
The nutrient variables in these models include: total phosphorus in ug/L, total nitrogen in mg/L,
total kjeldahl nitrogen in mg/L, and nitrate and nitrite in mg/L. Regressions were also run for
total nitrogen and total phosphorus for ecoregions where both these variables were measured.
Note: At the time of creation of this document only regressions for aggregate nutrient ecoregion 7
for lakes and reservoirs were delivered to the EPA. Regressions for the remaining aggregate
nutrient ecoregions will be delivered in August 2000.
4.0 TIME PERIOD
Data collected from January 1990 to December 1999 were used in the statistical analysis reports.
To capture seasonal differences, the data were classified as follows:
Aggregate nutrient ecoregions: 6, 7, and 8
Spring: April to May
Summer: June to August
Fall: September to October
Winter: November to March
• Aggregate nutrient ecoregions: 1, 2, 9, 10, 11, 12, and 13
Spring: March to May
Summer: June to August
Fall: September to November
Winter: December to February
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5.0 DATA SOURCES AND PARAMETERS FOR THE AGGREGATE NUTRIENT
ECOREGIONS
This section provides information for the nutrient aggregate ecoregions that were analyzed by
waterbody type. Each section lists the data sources for the aggregate nutrient ecoregion
including: 1) the data sources, 2) the parameters included in the analysis, and 3) the Level III
ecoregions within the aggregate nutrient ecoregions.
Note: For analysis purposes, the following parameters were combined to form Phosphorous,
Dissolved Inorganic (DIP):
Phosphorus, Dissolved Inorganic (DIP)
Phosphorus, Dissolved (DP)
Phosphorus, Dissolved Reactive (DRP)
Orthophosphate, dissolved, mg/L as P
Orthophosphate (OPO4_PO4)
5.1 Lakes and Reservoirs
5.1.1 Aggregate Nutrient Ecoregion 2
Data Sources:
Legacy STORE!
EPA Region 10
Parameter:
Chlorophyll A, Fluorometric, Corrected (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Phosphorous, Dissolved Inorganic (DIP) (ug/L)
Dissolved Oxygen (DO) (mg/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Phosphorus, Total (TP) (ug/L)
Phosphorus, Total Reactive (ug/L)
SECCHI (m)
pH
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Level III ecoregions:
1, 2, 4, 5, 9, 11, 15, 16, 17, 19, 21, 23, 41, 77, 78
5.1.2 Aggregate Nutrient Ecoregion 6
Data Sources:
Legacy STORE!
Parameters:
Chlorophyll A, Fluorometric, Corrected (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Dissolved Oxygen (DO) (mg/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Phosphorus, Total (TP) (ug/L)
SECCHI (m)
Level III ecoregions:
46, 47, 48, 54, 55, 57
5.1.3 Aggregate Nutrient Ecoregion 7
Data Sources:
LCMPD
Legacy STORET
NYCDEP
EPA Region 1
Parameters:
Chlorophyll A, Fluorometric Corrected (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric, Uncorrected (ug/L)
Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Phosphorous, Dissolved Inorganic (DIP) (ug/L)
Dissolved Oxygen (DO) (mg/L)
10
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Nitrite and Nitrate, (NO2+NO3) (mg/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Phosphorus, Orthophosphate, Total as P (ug/L)
Phosphorus, Total (TP) (ug/L)
SECCHI (m)
Level III ecoregions:
51, 52, 53, 56,60,61, 83
5.1.4 Aggregate Nutrient Ecoregion 8
Data Sources:
LCMPD
Legacy STORET
NYCDEP
NYCDEC
EPA Region 1
EPA Region 3
Parameters:
Chlorophyll A, Fluorometric, Corrected (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric, Uncorrected (ug/L)
Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Chlorophyll B (ug/L)
Chlorophyll C (ug/L)
Phosphorous, Dissolved Inorganic (DIP) (ug/L)
Dissolved Oxygen (DO) (mg/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Phosphorus, Total (TP) (ug/L)
SECCHI (m)
Level III ecoregions:
49, 50, 58, 62, 82
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5.1.5 Aggregate Nutrient Ecoregion 9
Data Sources:
Auburn University
Legacy STORE!
EPA Region 4
Parameters:
Chlorophyll A, Fluorometric, Corrected (ug/L)
Chlorophyll A, Pheophytin (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric, Uncorrected (ug/L)
Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Phosphorous, Dissolved Inorganic (DIP) (ug/L)
Dissolved Oxygen (DO) (mg/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Phosphorus, Total (TP) (ug/L)
SECCHI (m)
Level III ecoregions:
29, 33, 35, 37, 40, 45, 64, 65, 71, 72, 74
5.1.6 Aggregate Nutrient Ecoregion 11
Data Sources:
Auburn University
Legacy STORET
NYSDEC
EPA Region 3
EPA Region 4
Parameters:
Chlorophyll A, Fluorometric, Corrected (ug/L)
Chlorophyll A, Pheophytin (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric, Uncorrected (ug/L)
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Chlorophyll A, Trichromatic, Uncorrected
Phosphorous, Dissolved Inorganic (DIP) (ug/L)
Dissolved Oxygen (DO) (mg/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Phosphorus, Total (TP) (ug/L)
SECCHI (m)
Level III ecoregions:
36, 38, 39, 66, 67, 68, 69, 70
5.1.7 Aggregate Nutrient Ecoregion 12
Data Sources:
Legacy STORET
Parameters:
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Dissolved Oxygen (DO) (mg/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Phosphorus, Total (TP) (ug/L)
SECCHI (m)
Level III ecoregions:
75
5.1.8 Aggregate Nutrient Ecoregion 13
Data Sources:
Legacy STORET
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Parameters:
Chlorophyll A, Fluorometric, Corrected (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Dissolved Oxygen (DO) (mg/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Phosphorus, Total (TP) (ug/L)
SECCHI (m)
Level III ecoregions:
76
5.2 Rivers and Streams
5.2.1 Aggregate Nutrient Ecoregion 2
Data Sources:
Legacy STORET
NASQAN
NAWQA
EPA Region 10
Parameters:
Chlorophyll A, Fluorometric, Corrected (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Phytoplankton, chromotographic- fluorometric (ug/L)
Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Chlorophyll B, Phytoplankton, chromotographic- fluorometric (ug/L)
Phosphorous, Dissolved Inorganic (DIP) (ug/L)
Dissolved Oxygen (DO) (mg/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Phosphorus, Orthophosphate, Total as P (ug/L)
Phosphorus, Total (TP) Reactive (ug/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Phosphorus, Total (TP) (ug/L)
Turbidity (FTU)
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Turbidity (JCU)
Turbidity (NTU)
Level III ecoregions:
1, 2, 4, 5, 8, 9, 11, 15, 16, 17, 19, 21, 23, 41, 77, 78
5.2.2 Aggregate Nutrient Ecoregion 3
Data Sources:
Legacy STORET
NASQAN
NAWQA
EPA Region 10
Parameters:
Chlorophyll A, Fluorometric, Corrected (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Phytoplankton, chromotographic- fluorometric (ug/L)
Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Chlorophyll B, Phytoplankton, chromotographic- fluorometric (ug/L)
Phosphorous, Dissolved Inorganic (DIP) (ug/L)
Dissolved Oxygen (DO) (mg/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Phosphorus, Total (TP) (ug/L)
Turbidity (FTU)
Turbidity (JCU)
Turbidity (NTU)
Level III ecoregions:
6, 10, 12, 13, 14, 18, 20, 22, 24, 79, 80, 81
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5.2.3 Aggregate Nutrient Ecoregion 6
Data Sources:
Legacy STORET
NASQAN
NAWQA
EPA Region 5
EPA Region 7
Parameters:
Chlorophyll A, Fluorometric, Corrected
Chlorophyll A, Phytoplankton, Spectrophotometric Acid
Chlorophyll A, Phytoplankton, chromotographic- fluorometric
Chlorophyll A, Trichromatic, Uncorrected
Chlorophyll B, Phytoplankton, chromotographic- fluorometric
Phosphorous, Dissolved Inorganic (DIP)
Dissolved Oxygen (DO)
Nitrite and Nitrate, (NO2+NO3)
Nitrogen, Total (TN)
Nitrogen, Total Kjeldahl (TKN)
Organic, Phosphorus
Phosphorus, Total (TP)
Phosphorus, Orthophosphate, Total as P
Turbidity
Turbidity
Turbidity
Level III ecoregions:
46, 47, 48, 54, 55, 57
5.2.4 Aggregate Nutrient Ecoregion 7
Data Sources:
LCMPD
Legacy STORET
NASQAN
NAWQA
NYCDEP
August 8, 2000
(ug/L)
(ug/L)
(ug/L)
(ug/L)
(ug/L)
(ug/L)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
(ug/L)
(ug/L)
(ug/L)
(FTU)
(JCU)
(NTU)
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Parameters:
Chlorophyll A, Fluorometric, Corrected (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric, Uncorrected (ug/L)
Chlorophyll A, Phytoplankton, chromotographic- fluorometric (ug/L)
Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Chlorophyll B, Phytoplankton, chromotographic- fluorometric (ug/L)
Phosphorous, Dissolved Inorganic (DIP) (ug/L)
Dissolved Oxygen (DO) (mg/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Organic, Phosphorus (ug/L)
Phosphorus, Orthophosphate, Total as P (ug/L)
Phosphorus, Total (TP) (ug/L)
Turbidity (FTU)
Turbidity (JCU)
Turbidity (NTU)
Level III ecoregions:
51, 52, 53, 56,60,61, 83
5.2.5 Aggregate Nutrient Ecoregion 9
Data Sources:
Auburn University
Legacy STORET
NASQAN
NAWQA
EPA Region 3
EPA Region 5
EPA Region 7
Parameters:
Chlorophyll A, Fluorometric, Corrected (ug/L)
Chlorophyll A, Phytoplankton, chromotographic- fluorometric (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric, Uncorrected (ug/L)
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Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Chlorophyll B, Phytoplankton, chromotographic- fluorometric (ug/L)
Chlorophyll B, Phytoplankton, Spectrophotometric (ug/L)
Phosphorous, Dissolved Inorganic (DIP) (ug/L)
Dissolved Oxygen (DO) (mg/L)
Organic, Phosphorus (ug/L)
Phosphorus, Orthophosphate, Total as P (ug/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Phosphorus, Total (TP) (ug/L)
Turbidity (FTU)
Turbidity (JCU)
Turbidity (NTU)
Level III ecoregions:
29, 33, 35, 37, 40, 45, 64, 65, 71, 72, 74
5.2.6 Aggregate Nutrient Ecoregion 11
Data Sources:
Auburn University
Legacy STORET
NASQAN
NAWQA
EPA Region 3
EPA Region 5
EPA Region 7
Parameters:
Chlorophyll A, Fluorometric, Corrected (ug/L)
Chlorophyll A, Phytoplankton, chromotographic- fluorometric (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric, Uncorrected (ug/L)
Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Chlorophyll B, Phytoplankton, chromotographic- fluorometric (ug/L)
Phosphorous, Dissolved Inorganic (DIP) (ug/L)
Dissolved Oxygen (DO) (mg/L)
Organic, Phosphorus (ug/L)
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Phosphorus, Orthophosphate, Total as P (ug/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Phosphorus, Total (TP) (ug/L)
Turbidity (FTU)
Turbidity (JCU)
Turbidity (NTU)
Level III ecoregions:
36, 38, 39, 66, 67, 68, 69, 70
5.2.7 Aggregate Nutrient Ecoregion 12
Data Sources:
Legacy STORET
NASQAN
NAWQA
Parameters:
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric, Uncorrected (ug/L)
Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Chlorophyll B, Phytoplankton, Spectrophotometric (ug/L)
Phosphorous, Dissolved Inorganic (DIP) (ug/L)
Dissolved Oxygen (DO) (mg/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Nitrogen, Total (TN) (mg/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Phosphorus, Orthophosphate, Total as P (ug/L)
Phosphorus, Total (TP) (ug/L)
Turbidity (FTU)
Turbidity (NTU)
Level III ecoregions:
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5.2.8 Aggregate Nutrient Ecoregion 14
Data Sources:
Legacy STORE!
NASQAN
NAWQA
NYCDEP
EPA Region 1
EPA Region 3
Parameters:
Chlorophyll A, Fluorometric, Corrected (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric Acid (ug/L)
Chlorophyll A, Phytoplankton, Spectrophotometric, Uncorrected (ug/L)
Chlorophyll A, Trichromatic, Uncorrected (ug/L)
Phosphorous, Dissolved Inorganic (DIP) (ug/L)
Dissolved Oxygen (DO) (mg/L)
Nitrite and Nitrate, (NO2+NO3) (mg/L)
Phosphorus, Orthophosphate, Total as P (ug/L)
Nitrogen, Total Kjeldahl (TKN) (mg/L)
Nitrogen, Total (TN) (mg/L)
Phosphorus, Total (TP) (ug/L)
Turbidity (FTU)
Turbidity (JCU)
Turbidity (NTU)
Level III ecoregions:
59, 63, 84
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APPENDIX A
Process Used to QA/QA the Legacy STORE! Nutrient Data Set
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1. STORET water quality parameters and Station and Sample data items were retrieved from
USEPA's mainframe computer. Table 1 lists all retrieved parameters and data items.
TABLE 1: PARAMETERS AND DATA ITEMS RETRIEVED FROM STORET
Parameters Retrieved
(STORET Parameter Code)
TN - mg/1 (600)
TKN - mg/1 (625)
Total Ammonia (NH3+NH4) - mg/1 (610)
Total NO2+NO3 - mg/1 (630)
Total Nitrite -mg/1 (6 15)
Total Nitrate - mg/1 (620)
Organic N - mg/L (605)
TP - mg/1 (665)
Chlor a - ug/L (spectrophotometric method,
32211)
Chlor a - ug/L (fluorometric method
corrected, 32209)
Chlor a - ug/L (trichromatic method
corrected, 32210)
Secchi Transp. - inches (77)
Secchi Transp. - meters (78)
+Turbidity JCUs (70)
+Turbidity FTUs (76)
+Turbidity NTUs field (82078)
+Turbidity NTUs lab (82079)
+DO - mg/L (300)
+Water Temperature (degrees C, 10/degrees
F, 11)
Station Data Items
Included
(STORET Item Name)
Station Type (TYPE)
Agency Code (AGENCY)
Station No. (STATION)
Latitude - std. decimal degrees
(LATSTD)
Longitude - std. decimal degrees
(LONGSTD)
Station Location (LOCNAME)
County Name (CONAME)
State Name (STNAME)
Ecoregion Name - Level III
(ECONAME)
Ecoregion Code -Level III
(ECOREG)
Station Elevation (ELEV)
Hydrologic Unit Code
(CATUNIT)
RF1 Segment and Mile
(RCHMIL)
RF ION/OFF tag (ONOFF)
Sample Data Items Included
(STORET Item Name)
Sample Date (DATE)
Sample Time (TIME)
Sample Depth (DEPTH)
Composite Sample Code
(SAMPMETH)
+ If data record available at a station included data only for this or other such marked parameters, data record was deleted
from data set.
The following set of retrieval rules were applied to the retrieval process:
Data were retrieved for waterbodies specified only as 'lake', 'stream', 'reservoir', or 'estuary'
under "Station Type" parameter. Any stations specified as 'well,' 'spring,' or 'outfall' were
eliminated from the retrieved data set.
Data were retrieved for station types described as 'ambient' (e.g., no pipe or facility
discharge data) under the "Station Type" parameter.
Data were retrieved that were designated as 'water' samples only. This includes 'bottom'
and 'vertically integrated' water samples.
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Data were retrieved that were designated as either 'grab' samples and 'composite' samples
(mean result only).
No limits were specified for sample depths.
Data were retrieved for all fifty states, Puerto Rico, and the District of Columbia.
The time period specified for data retrieval was January 1990 to September 1998.
No data marked as "Retired Data" (i.e., data from a generally unknown source) were
retrieved.
Data marked as "National Urban Runoff data" (i.e., data associated with sampling
conducted after storm events to assess nonpoint source pollutants) were included in the
retrieval. Such data are part of STORET's 'Archived' data.
Intensive survey data (i.e., data collected as part of specific studies) were retrieved.
Any values falling below the 1st percentile and any values falling above the 99th percentile
were transformed into 'missing' values (i.e., values were effectively removed from the data
set, but were not permanently eliminated).
Based on the STORET 'Remark Code' associated with each retrieved data point, the
following rules were applied (Table 2):
TABLE 2: STORET REMARK CODE RULES
STORET Remark Code
blank - Data not remarked.
A - Value reported is the mean of two or more
determinations.
B - Results based upon colony counts outside the acceptable
ranges.
C - Calculated. Value stored was not measured directly, but
was calculated from other data available.
D - Field measurement.
Keep or Delete Data Point
Keep
Keep
Delete
Keep
Keep
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E - Extra sample taken in compositing process.
F - In the case of species, F indicates female sex.
G - Value reported is the maximum of two or more
determinations.
H - Value based on field kit determination; results may not
be accurate.
I - The value reported is less than the practical
quantification limit and greater than or equal to the method
detection limit.
J - Estimated. Value shown is not a result of analytical
measurement.
K - Off-scale low. Actual value not known, but known to be
less than value shown.
L - Off-scale high. Actual value not known, but known to
be greater than value shown.
M - Presence of material verified, but not quantified.
Indicates a positive detection, at a level too low to permit
accurate quantification.
N - Presumptive evidence of presence of material.
O - Sample for, but analysis lost. Accompanying value is
not meaningful for analysis.
P - Too numerous to count.
Q - Sample held beyond normal holding time.
R - Significant rain in the past 48 hours.
S - Laboratory test.
T - Value reported is less than the criteria of detection.
Delete
Delete
Delete
Delete
Keep, but used one-half the reported value as the new value.
Delete
Keep, but used one-half the reported value as the new value.
Keep
Keep, but used one half the reported value as the new value.
Delete
Delete
Delete
Delete
Delete
Keep
Keep, but replaced reported value with 0.
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U - Material was analyzed for, but not detected. Value
stored is the limit of detection for the process in use.
V - Indicates the analyte was detected in both the sample
and associated method blank.
W - Value observed is less than the lowest value reportable
under remark "T."
X - Value is quasi vertically-integrated sample.
Y - Laboratory analysis from unpreserved sample. Data
may not be accurate.
Z - Too many colonies were present to count.
Keep, but replaced reported value with 0.
Delete
Keep, but replaced reported value with 0.
No data point with this remark code in data set.
Delete
Delete
If a parameter (excluding water temperature) value was less than or equal to zero and no remark code was present, the value
was transformed into a missing value.
Rationale - Parameter concentrations should never be zero without a proper explanation. A method detection limit should
at least be listed.
4. Station records were eliminated from the data set if any of the following descriptors were
present within the "Station Type" parameter:
MONITR - Source monitoring site, which monitors a known problem or
to detect a specific problem.
HAZARD - Site of hazardous or toxic wastes or substances.
ANPOOL - Anchialine pool, underground pools with subsurface
connections to watertable and ocean.
DOWN - Downstream (i.e., within a potentially polluted area) from a
facility which has a potential to pollute.
IMPDMT - Impoundment. Includes waste pits, treatment lagoons, and
settling and evaporation ponds.
STMSWR - Storm water sewer.
LNDFL - Landfill.
CMBMI - Combined municipal and industrial facilities.
CMBSRC - Combined source (intake and outfall).
Rationale - these descriptors potentially indicate a station location that at which an
ambient water sample would not be obtained (i.e., such sampling locations are potentially
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biased) or the sample location is not located within one of the designated water body types (i.e,
ANPOOL).
5. Station records were eliminated from data set if the station location did not fall within any
established cataloging unit boundaries based on their latitude and longitude.
6. Using nutrient ecoregion GIS coverage provided by USEPA, all station locations with
latitude and longitude coordinates were tagged with a nutrient ecoregion identifier
(nutrient region identifiers are values 1 - 14) and the associated nutrient ecoregion name.
Because no nutrient ecoregions exist for Alaska, Hawaii, and Puerto Rico, stations located
in these states were tagged with "dummy" nutrient ecoregion numbers (20 = Alaska, 21 =
Hawaii, 22 = Puerto Rico).
7. Using information provided by TV A, 59 station locations that were marked as 'stream'
locations under the "Station Type" parameter were changed to 'reservoir' locations.
8. The nutrient data retrieved from STORET were assessed for the presence of duplicate
data records. The duplicate data identification process consisted of three steps: 1)
identification of records that matched exactly in terms of each variable retrieved; 2)
identification of records that matched exactly in terms of each variable retrieved except for
their station identification numbers; and 3) identification of records that matched exactly in
terms of each variable retrieved except for their collecting agency codes. The data
duplication assessment procedures were conducted using SAS programs.
Prior to initiating the data duplication assessment process, the STORET nutrient data set
contained:
41,210 station records
924,420 sample records
Identification of exactly matching records
All data records were sorted to identify those records that matched exactly. For
two records to match exactly, all variables retrieved had to be the same. For
example, they had to have the same water quality parameters, parameter results
and associated remark codes, and have the same station data item and sample data
item information. Exactly matching records were considered to be exact
duplicates, and one duplicate record of each identified matching set were
eliminated from the nutrient data set. A total of 924 sample records identified as
duplicates by this process were eliminated from the data set.
Identification of matching records with the exception of station identification
number
All data records were sorted to identify those records that matched exactly except
for their station identification number (i.e., they had the same water quality
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parameters, parameter results and associated remark codes, and the same station
and sample data item information with the exception of station identification
number). Although the station identification numbers were different, the latitude
and longitude for the stations were the same indicating a duplication of station data
due to the existence of two station identification numbers for the same station. For
each set of matching records, one of the station identification numbers was
randomly selected and its associated data were eliminated from the data set. A
total of 686 sample records were eliminated from the data set through this process.
• Identification of matching records with the exception of collecting agency codes
All data records were sorted to identify those records that matched exactly except
for their collecting agency codes (i.e., they had the same water quality parameters,
parameter results and associated remark codes, and the same station and sample
data item information with the exception of agency code). The presence of two
matching data records each with a different agency code attached to it suggested
that one agency had utilized data collected by the other agency and had entered the
data into STORET without realizing that it already had been placed in STORET
by the other agency. No matching records with greater than two different agency
codes were identified. For determining which record to delete from the data set,
the following rules were developed:
> If one of the matching records had a USGS agency code, the USGS
record was retained and the other record was deleted.
> Higher level agency monitoring program data were retained. For
example, federal program data (indicated by a " 1" at the beginning
of the STORET agency code) were retained against state (indicated
by a "2") and local (indicated by values higher than 2) program
data.
> If two matching records had the same level agency code, the record
from the agency with the greater number of overall observations
(potentially indicating the data set as the source data set) was
retained.
A total of 2,915 sample records were eliminated through this process.
As a result of the duplicate data identification process, a total of 4,525 sample records and
36 individual station records were removed from the STORET nutrient data set. The
resulting nutrient data set contains the following:
41,174 station records
919,895 sample records
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APPENDIX B
Process for Adding Aggregate Nutrient Ecoregions and Level III Ecoregions
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Steps for assigning Level III ecoregions and aggregate nutrient ecoregion codes and names to the
Nutrient Criteria Database (performed using ESRI's ARCView v 3.2 and its GeoProcessing
Wizard). This process is performed twice; once for the Level III ecoregions and once for the
aggregate nutrient ecoregions:
Add the station .dbf data table, with latitude and longitude data, to project by 'Add
Event Theme'
Convert to the shapefile format
Create 'stcojoin' field, populate the 'stcojoin' field with the following formula:
'County.LCase+State.LCase'
Add field 'stco_flag' to the station shapefile
Spatially join the station data with the county shapefile (cntysjned.shp)
Select 'stcojoin' (station shapefile) field = 'stcojoin2' (county shapefile) field
Calculate stco_flag = 0 for selected features
Step through all blank stco_flag records, assign the appropriate stco_flags, see list
on the following page
Select all stco_flags = 4 or 7, switch selection
Calculate ctyfips (station) to cntyfips (county)
Stop editing and save edits, remove all joins
Add in 2 new fields 'x-coordl' and 'y-coordl' into station table
Select all stco_flags =1,2, and 6
Link county coverage with station coverage
Populate 'x-coordl' and 'y-coordl' with 'x-coord' and 'y-coord' from county
coverage
Select all stco_flags = 1, 2, and 6, export to new .dbf file
Add new .dbf file as event theme
Convert to shapefile format
Add the following fields to both tables (original station and station!26 shapefiles):
'eco_omer', 'name_omer', 'dis_aggr', 'code_aggr', 'name_aggr'
Spatially join station 126 and eco-omer coverage
Populate the 'eco_omer' field with the 'eco' value
Repeat the previous step using the nearest method (line coverage) to determine
ecoregion assignment for the line coverage, if some records are blank
Spatially join the ecoregion line coverage to station coverage, link the LPoly#
(from the spatially joined table) to Poly# (of the ecoregion polygon coverage)
Populate the Eco fields with the appropriate information.
Follow the same steps to the Rpoly#
Remove all table j oins
Link the useco-om table with station!26 table and populate 'name-omer' field
Spatially join station aggr coverage and populate the rest of the fields. Follow the
same procedures as outlined above
Remove all joins
Make sure the new Eco field added into the station 126 shapefile are different than
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the ones in the original station shapefile
Join station 126 and station coverage by station-id
Populate all the Eco fields in the original station coverage
Remove all joins
Save table
Make sure that all ctyfips records are populated; the county shapefile may have to
be joined to populate the records, if the stco_flag = 4
Create 2 new fields, 'NewCounty' and 'NewState'
Populate these new fields with a spatial join to the county coverage
Select by feature (ecoregion shapefile) all of the records in the station shapefile
Switch selection (to get records outside of the ecoregion shapefile)
If any of the selected records have stco_flag = 0 (they are outside the ecoregion
shapefile boundary), calculate them to stco_flag = 3
stco_flags (state/county flags in order of importance)
0 The state and county values from the data set matched the state and county values
from the spatial join.
(Ecoregions were assigned based on the latitude/longitude coordinates.)
1 The state and county values from the data set did not match the state and county
values from the spatial join, but the point was inside the county coverage
boundary.
(Ecoregions were assigned based on the county centroid.)
2 The state and county values from the data set did not match the state and county
values from the spatial join because the point was outside the county coverage
boundary; therefore, there was nothing to compare to the point (i.e., the point
falls in the ocean/Canada/Mexico). This occurred for some coastal samples.
(Ecoregions were assigned based on the county centroid.)
3 The state and county values from the data set matched the state and county from
the spatial join, but the point was outside the ecoregion boundary.
(Ecoregions were assigned to the closest ecoregion to the point.)
(No ecoregions were assigned to AK, HI, PR, BC, and GU.)
4 Latitude/longitude coordinates were provided, but there was no county
information.
(Ecoregions were assigned based on the latitude/longitude coordinates.)
5 The state and county values from the data set did not match the state and county
values from the spatial join due to spelling or naming convention errors.
The matches were performed manually.
(Ecoregions were assigned based on the latitude/longitude coordinates.)
6 No latitude/longitude coordinates were provided, only state and county
information was available.
(Ecoregions were assigned based on the county centroid.)
7 No latitude/longitude coordinates were provided, only state information was
available; therefore, no matches were possible.
(Ecoregions were not assigned. Data is not included in the analysis.)
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APPENDIX C
Glossary
Coefficient of Variation- Equal to the standard deviation divided by the mean multiplied by 100.
Maximum- The highest value.
Mean- The arithmetic average.
Median- The 50th percentile or middle value. Half of the values are above the median, and half of
the values are below the median.
Minimum- The lowest value.
Standard Deviation- Equal to the square root of the variance with the variance defined as the sum
of the squared deviations divided by the sample size minus one.
Standard Error- Standard error of the mean is equal to the standard deviation divided by the
square root of the sample size.
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