United States Environmental Protection Agency Office of Water (4305) EPA-823-N-97--OOt Number 18 Winter 1997 SEPA Contaminated Sediments News 3 ORD Activities— "\ff x, SedimentToxicity Test for the Ammonia Tolerance of the Marine Bivalve Mulinia lateralis Sediment £ffe,ct Concentrations Developed g Regional*: .Activities'.'1:. , ' •Manistique River/ Harbor Dredging Project Contaminated Sediment Management in Hawaii Creature Feature "J Activities Timeline CS News is produced by the >~ EPA Office of Science and Technology (OST) to exchange Information on contaminated ' > s&dimente and to increase •communication among interested parties. To obtain' • copies of Oils report or to contribute information, contact Jane Marshall Farris, EPA OST, mail code 4305,401M , StreetS.W., Washington, DC 20460 at ,(202) 260-8897. To be added to the mailing list or to make changes to your address, please fax your request to Jane Marshall Farris at (202) 260-9830. EPA Holds National Conference on Sediment Bioaccurnulation More than 400 persons attended the National Sediment Bioaccumulation Conference, cosponsored by EPA's Office of Science and Technology and Office of Research and Development, on September 11-13, 1996 in Bethesda, Maryland. The conference featured presentations by national experts in seven sessions. Attend- ees heard about recent advances in ap- proaches for assessing bioaccumulative sediment contaminants and for integrating assessment results into EPA decision mak- ing. They also had the opportunity for dia- logue with panelists during question-and- answer periods at the end of each session. The first day of the conference focused on measuring bioaccumulation and on inter- preting and applying the results of assess- ments. The second day included sessions on modeling the bioavailability of sedi- ment contaminants and on conducting hu- man health-based and environmentally based risk assessments. On the last day of the conference, an EPA program panel ad- dressed how the results of bioaccumulation assessments are being used in Agency de- cision making. The panelists represented the Agency's Superfund, NPDES, and Dredged Material Programs, as well as programs hi the EPA Office of Pollution Prevention and Toxics and the EPA Office of Science and Technology. Conference Feedback EPA received complimentary feedback from numerous conference attendees. Many appreciated the Agency's organizing and sponsoring the event on a national scale. They identified areas of interest for future conferences, such as sediment reme- diation, nonpoint source sediment contami- nants, dredged material disposal, and envi- ronmental indicators of sediment quality. Attendees said some session topics—par- ticularly sediment test methods, bioavail- ability of sediment contaminants, bioaccu- mulation modeling, and ecologically based risk assessment—should be expanded into an entire conference. Conference Proceedings A conference proceedings should be avail- able by late spring of 1997. Conference at- tendees will receive a copy. Once the pro- ceedings are available, a notice on how to obtain the proceedings through NCEPI will be published in the newsletter. Other infor- mation on the proceedings may be obtained from Leanne Stahl, EPA Office of Science and Technology, 202 260-7055 (or stahl.leanne@epamail.epa.gov). @ Screening Values for Tributyltin in Marine Sediments rTlhe EPA Region 10 Superfund • Program, with support from -M. an interagency workgroup, recently completed an evaluation of various approaches for deriv- ing an effects-based screening value or clean-up level for tributyltin (TBT) in marine sediments. This effort was initiated to assist EPA in recommending a cleanup approach for TBT-contaminated sediments at Superfund Continued on page 2 ------- No. 18 \Vlnlerl997 Seattle Tacoma * TBT Screening Values -Selocted for Sediments at Superfund Sites r - in Puget Sound __ Screening Valuo Lower Screening Valua Higher Screening Valus (a) Interstitial Water Concentration (ug TBT/L) 0.05 0.70 (b) Sediment Concentration {ug TBT/kg OC) 1,255 17,570 (*1 ImerititM water Is porewater extracted from whole sediments. tb) Assuming 2% TOC, tho lower screening value Is approximately equivalent to 2B.1 ug TBT/kg (dry weight) and the higher screening value Is equivalent to 351 ug TBT/kg (dry Weight). Bulk sediment analyses quantify the TBT concentrations In both pofewaler and tho sediments. TBT VALUES Continued from page I sites in Puget Sound, Washington. Re- sults are detailed in a final report, Recom- mendations for Screening Values for Tributyltin in Sediments at Superfund Sites in Puget Sound, Washington (EPA 1996). What is TBT? A man-made organotin compound, TBT has many commercial, industrial, and agricultural applications. TBT has been widely used in marine paints as an effective means of preventing or retarding the growth of fouling organ- isms such as barnacles and mussels on the hulls of boats and ships. It is this applica- tion that is thought to represent the main contribution of TBT to the marine and es- tuarine environments in Puget Sound. However, TBT compounds are also used as biocides hi cooling towers, pulp and paper mills, and textile mills, and as ac- tive ingredients in wood preservatives, disinfectant and antimicrobial cleaners and shampoos, and toilet bowl cleaners. Development of Agency TBT Screening Values In the 1990s, EPA found TBT was ex- tremely widespread in sediments at three Superfund sites located in highly industri- alized urban embayments. To evaluate these bulk sediment chemistry data, the Agency developed a range of bulk sedi- ment and interstitial water TBT screening values. Interstitial, or pore, water is ex- tracted or centrifuged from whole bulk sediments. Screening values were developed because there are no state or federal cri- teria for TBT, and it was neces- sary for Region 10 to move for- ward with sediment remedial design and remedial action at these sites. The range of screen- ing values allows for the site- specific selection of a cleanup level based on the protective- ness that is considered appropri- ate for the given sediment man- agement decision. The interstitial water screening values for TBT are based on chronic and acute water quality effects data reported in the lit- erature for concentrations of TBT (as the ion). The report summarizes all available TBT water quality effects data, including test species, endpoints, and citations. The sediment screening values for TBT are derived using a sediment-water parti- tioning approach. This approach is based on a mathematical relationship between TBT concentrations known to cause ad- verse effects in water and an organic car- bon-based partitioning coefficient. (A Koc value of 25,100 L/kg was used.) This mathematical relationship is shown here: [Sedl = [Water] * K where, Sedoc = organic-carbon normalized sedi- ment concentration (jag/kg) Water = effects concentration in water K = organic carbon based partitioning coefficient (L/kg) This equation was used to calculate a range of organic-carbon normalized sedi- ment TBT concentrations that would pre- dict TBT concentrations associated with minor adverse effects. Note that this ap- proach assumes that TBT is in equilib- rium between sediment interstitial water and particulate organic carbon phases. Results Because there were no state or federal critieria for TBT, Bulk Sediment TBT concentrations normalized to organic car- bon were developed as screening concen- trations to predict minor or adverse ef- fects. Two limited studies found that the screening values reflected interstitial wa- ter concentrations of TBT to within only one to two orders of magnitude of actual concentrations. The organotin compounds are unique, and they partition between sediment and water differently from other organic com- pounds. For a number of organic com- pounds, organic carbon normilization has been shown to reliably reflect interstitial water concentrations. For TBT, however, the interstitial water should actually be collected and analyzed for TBT, instead of using the original predictive concentra- tions. (See Table of Screening Values.) A ------- disadvantage of this method is that rela- * tively large amounts of sediment must be collected to obtain a large enough quan- tity of interstitial water for TBT analysis. However, for organotin compounds like TBT, this collection is necessary. Results of Region 10's study suggest that bulk sediment, and organic carbon-nor- malized sediment TBT concentrations may be poor predictors of the bioavail- able fraction of TBT. Thus, Region 10 strongly recommends that sediment cleanup decisions at Superfund sites in Puget Sound be based on TBT concentra- tions in interstitial water, and on any as- sociated biological effects testing. Two recent sampling efforts showed that measured concentrations of TBT hi inter- stitial water were lower than would have been predicted using the sediment-water partitioning approach and existing bulk sediment data. Recommendations for future work have also been identified. Additional research is needed on the environmental factors af- fecting TBT partitioning behavior and the degradation rates of TBT under varying conditions (e.g., anaerobic vs. aerobic conditions) and varying TBT concentra- tions (e.g., moderate vs. high concentra- tions). Also, to confirm the ecological significance of interstitial water "exceed- ances" of TBT screening values, appro- priate biological effects tests should be developed to assess the bioavailability of TBT in sediments. Some data suggest that several bioassay species commonly used in effects test appear to be insensitive to TBT, and/or test durations may be too short. The uptake of TBT from sediments to tissue appears to be fairly complex, and there are limited studies on tissue residue effects data for TBT. Additional information and copies of the EPA report are available from Karen Keeley, Superfund Site Manager, EPA Region 10 Office of Environmental Cleanup, ECL-111, Seattle, WA, 98101. 206 553-2141 (e-mail: keeley.karen@ epamail.epa.gov). O No. 18 Winter 1997 AED-Narragansett Sediment Toxicity Test for the Ammonia Tolerance of the Marine Bivalve Mulinia lateralis Ammonia is a naturally occurring, and of- ten a eutrophication-enhanced, chemical constituent of many freshwater and ma- rine sediments. At sufficiently high con- centrations ammonia can also be an im- portant sediment toxicant. Recent work at AED-Narragansett has focused on the ammonia tolerance of a new sediment toxicity test using the marine bivalve Mulinia lateralis. Because this species is being considered for regulatory use by EPA Region 6, knowing its response to sediment ammo- nia concentrations is important. M. lateralis had LC50 and EC50 (growth) val- ues of 0.6 and 0.3 mg/L unionized ammo- nia, respectively. These values indicate that the bivalve is among the most sensi- tive marine toxicity testing species. A second study assessed whether ammo- nia concentrations in the M. lateralis ex- posure chambers that contained natural sediments with high interstitial water am- monia concentrations would approach ef- fects levels. It was shown that the pre-test flushing procedure (i.e., overlying water replacement 24 hours after sediment addi- tion to exposure chambers) reduced over- lying water ammonia concentrations to well below the levels where toxicity would be expected. For further details please contact Peg Pelletier (401 782-3131) or Rob Burgess (401 782-3106), EPA Office of Research and Development, Atlantic Ecology Divi- sion, Narragansett, RI. © Sediment Effect Concentrations Developed A recent U.S. EPA publication, "Calcula- tion and Evaluation of Sediment Effect Concentrations for the Amphipod Hyalella Azteca and the Midge Continued on page 4 ------- No. 18 Winter 1997 The SEC is the concentration of a chemical that is associated with the effect. Once the probable cause(s) of sediment toxicity has been identified, better decisions can be made regarding remediation options. ORD ACTIVITIES Continued from page 3 Chironomus Riparius," describes proce- dures for calculating and evaluating sedi- ment effect concentrations (SECs) using laboratory data on the toxicity of con- taminants associated with field-collected sediment to the amphipod Hyalella azteca and the midge Chironomus riparius. SECs are the concentrations of individual contaminants hi sediment below which toxicity is rarely observed and above which toxicity is frequently observed. SECs were used to classify toxicity data for Great Lake sediment samples tested as part of the U.S. EPA Great Lakes Na- tional Program Office (GLNPO) Assess- ment and Remediation of Contaminated Sediments (ARCS) Program (Fox and Tuchman 1996; Ingersoll et al. 1996). Three types of SECs were calculated for Hyalella azteca and for Chironomus riparius: (1) Effect Range Low (ERL) and Effect Range Median (ERM), (2) Threshold Effect Level (TEL) and Prob- able Effect Level (PEL), and (3) No Ef- fect Concentration (NEC; analogous to Apparent Effect Thresholds). The SECs were calculated using: (1) dry- weight concentrations, (2) dry-weight concentrations normalized to total organic carbon concentrations (for non-ionic or- ganics), or (3) dry-weight concentrations normalized to acid volatile sulfide con- centrations (for divalent metals). SECs were calculated primarily for total metals, simultaneously extracted metals, poly- chlorinated biphenyls, and polycyclic aro- matic hydrocarbons. The database's ranges of concentrations in sediment were too narrow to adequately evaluate SECs for butyltins, methyl mercury, polychlori- nated dioxins and furans, or chlorinated pesticides. Using SECs, about 60 to 80 percent of the sediment samples in the database can be correctly classified as toxic or not toxic, depending on the type of SEC evaluated. ERMs and ERLs are generally as reliable as paired PELs and TELs at classifying both toxic and nontoxic samples in the database. Reliability of the SECs in terms of correctly classifying sediment samples is'similar between ERMs and NECs; but ERMs minimize Type I errors (false positives) relative to ERLs, and minimize Type II errors (false negatives) relative to NECs. Correct sample classification can be improved by using only the most reliable SECs for chemicals (those with a higher percentage of correct classification). Calculating SECs using dry-weight con- centrations—instead of using sediment concentrations for PAHs and total PCBs that have been normalized to TOC con- centrations—resulted in similar correct classification of toxicity and similar Type I and Type II error. The range of TOC concentrations in the database was rela- tively narrow compared to the ranges of contaminant concentrations. Therefore, normalizing dry-weight concentrations to a relatively narrow range of TOC concen- trations had little influence on relative concentrations of contaminants among samples. The SECs were calculated from toxicity tests with field-collected samples. Even if a chemical concentration exceeds an SEC generated from data derived from tests with field-collected samples, the chemical may not have caused the observed effect. Rather, the SEC is the concentration of a chemical that is associated with the ef- fect. Field-collected sediments typically con- tain complex mixtures of contaminants. Additional information is needed to iden- tify the specific contaminants that were responsible for the toxicity. Confirmation of sediment toxicity due to individual or groups of contaminants can be determined by using Toxicity Identifi- cation Evaluation procedures or by con- ducting toxicity tests with spiked sedi- ments. Once the probable cause(s) of sediment toxicity has been identified, bet- ter decisions can be made regarding re- mediation options. The SECs can be used as guidance for evaluating contaminated sediment, but there is no intent expressed or implied that they represent U.S. EPA or National Biological Service (NBS) criteria. The SEC data discussed here (U.S. EPA, 1996), including the database on disk, are ------- available from Callie Bolattino, U.S. EPA, GLNPO, 77 W. Jackson, Chicago, IL (312 353-3490, fax -2018; email: Bolattino.callie@epamail.epa.gov). An electronic copy of U.S. EPA (1996) including the database is also available on the internet at the NBS home page at: http://www.msc.nbs.govpubs.html. References Cited Fox, R.G., and M. Tuchman. 1996. The Assessment and Remediation of Contami- nated Sediments (ARCS) Program. J. Great Lakes Res. 22:493-494. Ingersoll, C.G., P.S. Haverland, E.L. Brunson, T.J. Canfield, F.J. Dwyer, C.E. Henke, and N.E. Kemble. 1996. Calcula- tion and Evaluation of Sediment Effect Concentrations for the Amphipod Hyalella azteca and the Midge Chironomus riparius. J. Great Lakes Res. 22:602-623. U.S. Environmental Protection Agency. 1996. Calculation and Evaluation of Sedi- ment Effect Concentrations for the Am- phipod Hyalella azteca and the Midge Chironomus riparius. EPA 905-R96-008, Chicago, IL.» No. 18 Winter 1997 Region 5 Manistique River/Harbor Dredging Project The Manistique River/Harbor Site, in northern Michigan, is 1 of 42 Areas of Concern, where Water Quality Objectives are not met. The site is hi the City of Manistique on the southern shores of Lake Michigan's Upper Peninsula, where the Manistique River discharges into Lake Michigan. PCBs are the major contaminant of con- cern, and three areas have PCB concen- trations that exceed the 10 part per mil- lion (ppm) cleanup level. Concentra- tions generally are in the hundreds of parts per million in the contaminated ar- eas, with concentrations as high as 2,510 ppm (see table at right). Approximately 18,000 pounds of PCBs can be found within 127,000 cubic yards of contaminated sediments. Surface water sample analysis indicate that 105 pounds of PCBs are being discharged annually into Lake Michigan, and there is potential for erosion of a greater volume of con- taminated sediments during a large storm or floods. There is a fish advisory for carp, in which PCB concentrations average approxi- mately 6 ppm. Sport fish are affected by PCB contamination. Potentially responsible parties (PRPs) consist of a paper company, an electric utility, a local salvage yard, and compa- nies that sent materials to the scrap yard. Recent Site History & Investigations After an Engineering Evaluation/Cost Analysis (EE/CA) was conducted by the paper company and the electric utility, EPA recommended that the contaminated sediments be dredged and disposed of at a nearby PCB landfill. This recommendation quickly be- came controversial, with the community and PRPs voicing strong opposition to dredging. They asserted that dredging was not protective because PCB-contammated sediment would be resuspended in the water during dredging, leaving contaminated materials behind. The opponents to EPA's rec- ommendation countered that capping contaminated sedi- ments in the river and harbor would be the most protective and cost-effective remedy. ^-IVfejilstlqile^Rf^e^Hairbbf , Drainage Project ' fe§r. " Area Near Manistique Papers Facility North Bay/U.S. 2 Highway Bridge 1,000 Feet Upstream From River Mouth Harbor TOTAL Cubic Yards of Sediment Exceeding 10 ppm ., 0 23,000 7,000 97,000 1 27,000 Maximum Concentration (ppm) — 2,510 460 810 2,510 After considering community input and remedial alternatives, EPA selected a "hybrid" remedy whereby the Agency would conduct and pay for dredging a relatively small area in the river, and the PRPs would implement a capping rem- edy. EPA began its dredging project dur- Continued on page 6 ------- No, 18 Winter 1997 EPA will continue to improve the efficiency of dredging and water treatment, employing such techniques as hydrocycloning to enhance the separation ofPCB- contaminated materials from noncontaminated sediments. TlilJ popular jportfijh iin'ta lalmonM, but a cliar. (an you identify it? B si ojnjea-j MANISTIQUE RIVER Continued from page 5 ing 1995, while negotiations for the PRPs to implement capping were conducted. EPA's project demonstrated that, by using diver-assisted dredging techniques on the sediment, which was described as "light and fluffy," resuspension during dredging was minimized. And by separating the sawdust and woodchips that accounted for the highest PCB' concentrations— about 1,000 ppm—from the sediments that had PCB concentrations less than 1- ppm, dis- posal costs were reduced. This is because the sawdust and woodchips accounted for only about 3 percent of the total volume of contaminated material. The Agency therefore reproposed a total dredging remedy, which was supported by • the PRPs and community. The PRPs agreed to pay $6.4 million for EPA to fin- ish dredging all the river and harbor sedi- ments whose contamination exceeded the cleanup level. Before beginning its dredging activities in 1995, EPA designed and built or installed: • Sheet piling and silt barriers to pre- vent any releases of resuspended sedi- ments. • An on-site water treatment plant to dewater dredged sediments and treat dredge water prior to its discharge back into the Manistique River. • Two 1.2 million gallon lagoons for storage of treated dredge water. The Agency also up- graded a pad for storage and additional sediment dewatering that was owned by the paper com- pany and previously used to store recycled paper. Dredging Progress During 1995 and through August 1996, EPA fo- cused its dredging activi- ties in the North Bay/ U.S. 2 Highway area of the Manistique River. aqj. Since September 1995, approximately 18,000 cubic yards of contaminated sedi- ments have been removed, dewatered and disposed of. Approximately 30 mil- lion gallons of dredge water have also been treated and discharged to the Manistique River. Short-term adverse impacts from dredg- ing were found to be negligible. Turbid- ity measurements of surface water imme- diately downstream of the dredging area have remained at background levels dur- ing all dredging activities. Future Activities EPA will continue to improve the effi- ciency of dredging and water treatment, employing such techniques as hydro- cycloning to enhance the separation of PCB-contaminated materials from noncontaminated sediments. The Agency has completed dredging Area B (North Bay/U.S. 2 Highway area) and will dredge Area C. Dredging of Area C is scheduled to begin in May 1997. For additional information, contact James Hahnenberg, Remedial Project Manager, Superfund Division, EPA Re- gion 5, 77 West Jackson Blvd. SR-6J, Chicago, IL 60604 (312 353-4213, e- mail: hahnenberg.james@epamail.epa. gov).lHi Region 9 Contaminated Sediment Management in Hawaii Most dredging in the Hawaiian Islands has been conducted by the Navy at Pearl Harbor. Operating under a general per- mit (GP) from the U.S. Army Corps of Engineers, the Navy had disposed of all sediments at the EPA-designated south Oahu ocean dredged material disposal site (or earlier ocean disposal sites in the vicinity). Under the old GP, the Corps had determined the suitability of all Pearl Harbor sediments for ocean disposal based on broad, one-time regional sam- pling. The old GP has expired, and today ------- project-specific sampling and analyses (chemistry and bioassays) are required by EPA and the Corps. This testing of the specific sediments to be dredged is begin- ning to identify areas of contamination within Pearl Harbor that require alternate disposal methods. (Contaminants found include metals and organics such as PAHs and PCBs.) However, no Confined Disposal Facilities (CDFs) or other sites capable of managing sediments deemed unsuitable for unconfined ocean disposal have been constructed in Hawaii. A re- gional dredging team for the Hawaiian Is- lands formed by EPA and the Corps has begun discussions and planning for man- aging contaminated sediments. Planning Hawaii's First CDF The first project-specific CDF to manage contaminated sediments hi Hawaii is be- ing planned. The Navy proposes to con- tain unsuitable sediments, from the recon- struction of a submarine base, in a sheet pile-lined fill to be incorporated into new piers being built as part of this project. Preliminary plans have been presented to EPA and the Corps, and the Navy plans to evaluate maximizing the CDF's capac- ity to accommodate contaminated sedi- ments from other planned projects. Managing Other Contaminated Sediments Advanced planning also has begun for the management of expected contaminated sediments from the Ala Wai canal in Waikiki. Based on recent sediment stud- ies that show elevated chemical concen- trations, EPA and the Corps have deter- mined that significant volumes of sediment in the proposed design may be found unsuitable for unconfined ocean disposal. The state and local agencies have been urged by EPA and the Corps to re-evaluate the engineering of the project to minimize the amount of dredged mate- rial generated and to begin exploring op- tions for alternative disposal sites as part of the environment assessment of this project. In particular, EPA and the Corps are working with the agencies to coordi- nate the Ala Wai's dredging needs with other potential projects that may have a need for fill, and whose sites may be en- gineered to appropriately manage the contaminants present in the Ala Wai sedi- ments. Limited availability of potential upland sites on the Hawaiian Islands, however, makes developing appropriate facilities difficult. Therefore, there is growing interest in Hawaii in manage- ment concepts such as Confined Aquatic Disposal and containerization techniques (e.g., with geotextile bags). For more information, contact Allan Ota, U.S. EPA Region 9, San Francisco, CA 94105 (415 744-1980). O No. 18 Winter 1997 G5G2 Activities Timeline February 9-12, 1997 1997 International Containment Technology Conference St. Petersburg, Florida Sponsors: U.S. Department of Energy, DuPont Company, U.S. EPA For further information, contact: Loreen Kollar, Conference Coordinator Florida State University 2035 East Paul Dirac Drive, 226 HMB Tallahassee, Florida Phone: 904 644-5524 Fax: 904 574-6704 e-mail: ICTCE@mailer.fsu.edu April 9-11, 1997 Third Environmental Monitoring and Assessment Program (EMAP) Research Symposium "Developing New Tools to Meet the Nation's Monitoring Needs: The Evolution of EMAP." Albany, New York Sponsor: U.S. EPA For further information, contact: Dr. Shabeg Sandhu NHEERL Building U.S. EPA EMAP Center. MD-87 Research Triangle Park, NC 27709 Phone: 919 541-3850 Fax: 919 541-4621 e-mail: sandhu.shabeg@epamail.epa.gov April 9-11, 1997 Seventeenth Annual Hydrology Days Sponsored by American Geophysical Union, Hydrology Section & the Front Range Branch American Society of Civil Engineers (ASCE), Water Resources Engineering Division, and the Colorado Section American Water Re- sources Association Colorado State University, Fort Collins, Colorado Abstract Submittal Deadline: March 7, 1997 For registration/general information, contact: Janet Lee Montera (Hydrology Days) Civil Engineering Department Colorado State University Fort Collins, CO 80523 Phone: 970491-7425 Fax:970491-7727 e-mail: jmontera@vines.colostate.edu ------- United States Environmental Protection Agency (4305) Washington, DC 20460 Official Business Penalty for Private Use $300 '"I Beginning in 1997 CS News will be primarily available via the INTERNET at http://www.epa.gov/OST/Events. If you would prefer to continue to receive CS News as a hard copy, please send your request to: Jane Marshall Farris, EPA Office of Science and Technology, FAX (202) 260-9830 or E-mail farris.jane@epamail.epa.gov or mail this form to: Jane Marshall Farris, U.S. EPA MC4305, 401 M St., SW, Washington DC 20460 Name: Organization: Address: L. .J ------- |