United States
                     Environmental Protection
                     Agency
                             Office of Water
                             (4305)
              EPA-823-N-97-Q07
              Number 20
              Winter 1998
SEPA   Contaminated
                     Sediments  News
  2 Regional
    Activities...
    SedimentAssessment
    and Remediation
    Team Continues
    Great Lakes Efforts

    MovingMud
    Documents Sediment
    Assessmentand'
    Remediation Program
    Successes in Great
    Lakes Basin

  A. Environment
    Canada Announces
    Sediment Technol-
    ogy Directory

  5 Assessingthe
    Toxicityand
    Bioavailabilityof
    PAH Mixtures in
    Sediments

  g Compiling Sedi-
    ment Chemistry
    and Toxicity Data

  "7 Second Great
    Waters Report to
    Congress Published

  g USGS Completes
    Upper Mississippi
    Assessment

 1Q Creature Feature

 1| ActivitiesTimeline

 CS News is produced by the.
 EPA Office ofSclencelahd
 Technology (OST) to exchange
 Information on contaminated
 sediments and to increase
 communication among
 interested parties. To obtain
 copies of this report or to
 contribute information* contact
 Jane Marshall Farr/s, EPA
 OST, mail code 4305,401M
 Street S.W., Washington, DC
 20460 at (202) 260-8897.
 To be added to the mailing list
 or to make changes to your
 address, please faxyour
 request to Jane Marshall Farrls.
 at(202) 260-9830.
ORD Contaminated  Sediments
Conference Draws 230+ Attendees
More than 230 professionals from a variety
of governmental agencies and the private
sector attended a national conference on
the management and treatment of contami-
nated sediments, which was sponsored by
the EPA Office of Research and Develop-
ment.

The conference had two major purposes:

  • To inform persons involved with the
   clean up of contaminated sediments
   about current cleanup options and
   about ongoing research into the devel-
   opment of new approaches and tech-
   nologies.

  • To obtain feedback from the partici-
   pants about needed research and future
   directions for the management and
   treatment of contaminated sediments.

Held in Cincinnati, Ohio on May 13 and 14,
1997, the conference featured two dozen
speakers from EPA and other organiza-
tions, including the U.S. Army Corps of
Engineers, Environment Canada, the Na-
tional Research Council, private sector de-
velopers, engineering firms and academic
researchers.

In an adjoining exhibit hall, 23 vendor
booths were open to the attendees for dis-
semination of information about technolo-
gies and discussion of case studies of sites
that have been remediated.

Presentation Topics
Presentations on May 13 were focused on
currently available technologies and ap-
proaches. The topics presented were:
   U.S. EPA's National Sediment Quality
   Survey.

   Roles of the U.S.EPA and U.S .Army
   Corp of Engineers.

   Strategies and Technologies for Clean-
   ing Up Contaminated Sediments (based
   on a report by the National Research
   Council).

   Solving Great Lakes Contaminated
   Sediment Problems.

   A Perspective on Remediation and
   Natural Recovery.

   Case Studies, including Natural Re-
   covery; In-Situ Capping; Brownfields
   and Sediment Disposal at Indiana Har-
   bor, East Chicago, Indiana; Environ-
   mental Dredging and Disposal; In-Situ
   Treatment; Ex-Situ Treatment Tech-
   nologies (New York Harbor); and
   FIELDS (Fully Integrated Environ-
   mental Location Decision Support
   System).
The second day of the conference was de-
voted to ongoing research, additional sys-
tems to facilitate decision making, and fu-
ture research directions. Presentations
were given on the following topics:

  • Remediation Strategies and Demon-
   stration of SEDTEC (a Directory of
   Contaminated Sediment Removal and
   Treatment Technologies) by Environ-
   ment Canada. (See page 4 for details.)
                   Continued on page 2

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No. 20
\\lnterI998
ORD CONTAMINATED SEDIMENTS CONFERENCE Continued from page 1
                    Demonstration of ADDAMS (Auto-
                    mated Dredging and Disposal Alter-
                    natives Modeling System).

                    U.S.Environmental Protection
                    Agency and U.S. Army Corps of En-
                    gineers Research Overviews.

                    Biological Research and Microbial
                    Dechlorination of PCBs.

                    Phytoremediation.

                    Treatment of Metal Bearing Solids
                    Using a Buffered Phosphate Stabiliza-
                    tion System.

                    Treatment by Thermal Desorption.

                    Treatment by a Solvent Extraction
                    Process.

                    Containment.
                                      Panel Discussion
                                      A panel of representatives from the fed-
                                      eral government, academia, and a repre-
                                      sentative from the Sierra Club discussed
                                      future research needs and responded to
                                      questions from the audience at the con-
                                      clusion of the conference. Some of the
                                      issues raised were stability of caps in a
                                      turbulent environment, beneficial uses and
                                      the marketability of dredged sediments,
                                      the need for a framework to help evaluate
                                      treatment options and the effort of the  In-
                                      ternational Joint Commission for the
                                      Great Lakes Region, and the need to ad-
                                      dress watershed management to  reduce
                                      further contamination of sediments from
                                      point and nonpoint source discharges.

                                      A conference proceedings is planned. For
                                      more information, please contact Joan
                                      Colson of the National Risk Management
                                      Research Laboratory, (513) 569-7501
                                      (e-mail: colson.j @epamail.epa.gov).
                                   Activities

                  !l,,ff
                 Sediment Assessment and  Remediation
                 Team  Continues Great Lakes  Efforts
                 EPA's commitment to cleaning up con-
                 taminated sediments remains strong.

                 Region 5's current Agenda for Action
                 lists contaminated sediments as a priority.

                 Formed by the Great Lakes National Pro-
                 gram Office (GLNPO) in 1994 to con-
                 tinue work begun under the Assessment
                 and Remediation of Contaminated Sedi-
                 ments (ARCS) Program, the Sediment
                 Assessment and Remediation Team con-
                 tinues to focus on the problem of con-
                 taminated sediments.

                 The Team's activities include:

                  • Performing and providing support for
                    sediment assessments throughout the
                    Great Lakes.

                  • Providing support for sediment-based
                                         mass balance modeling and risk as-
                                         sessment activities.

                                       • Providing technical support toward
                                         the selection and implementation of
                                         remedial alternatives.

                                       • Fostering partnerships among Great
                                         Lakes stakeholders to promote sedi-
                                         ment clean-up activities.

                                       • Providing outreach and communica-
                                         tions to the Great Lakes community
                                         on contaminated sediment issues.

                                     The Team works cooperatively with
                                     states, EPA regions, and other federal
                                     agencies to help address contaminated
                                     sediment problems around the Great
                                     Lakes basin. Team members also coordi-
                                     nate with the EPA Region 5 Sediment
                                     Team and Remedial Action Plan (RAP)

-------
 and Lakewide Management Plan (LAMP)
 activities to ensure resources are brought
 to bear on the most pressing contami-
 nated sediment problems.

 Other Resources
 GLNPO also has created a Sediment Da-
 tabase, which contains all of the sediment
 chemistry, toxicity,  and benthic data gen-
 erated by GLNPO-funded projects. Built
 in Microsoft Excel™, the database em-
 ploys a standard data-reporting format for
 both laboratory and field data/This infor-
 mation is available for any interested par-
 ties.

 Another major resource provided by
 GLNPO is the services of the R/V
 Mudpuppy, a 32-foot, flat-bottom boat
 designed specifically for sediment sam-
 pling in shallow rivers and harbors. First
used during the ARCS Program, and pro
filed in Contami-
nated Sediments
News issue 16, the
Mudpuppy is now
available to
GLNPO grantees
for use during
their projects. The
boat has already
been used in sedi-
ment  assessments
at 19 Great Lakes
locations.

For more informa-
tion, please con-
tact Marc Tuchman, Sediment Team
Leader, U.S. EPA, GLNPO, at (312) 353-
1369 (e-mail: tuchman.marc@epamail.
epa.gov).
                                                                                            No. 20
                                                                                        Winter 1998
The R/V Mudpuppy on station in
the Great Lakes.
 Moving Mud Documents Sediment Assessment and Remediation
 Program Successes in the Great Lakes Basin
 From 1993 through 1996, EPA's Great
 Lakes National Program Office (GLNPO)
 awarded $5.3 million in grants for 34
 projects to 14 state, tribal, and federal
 agencies and educational institutions to
 address contaminated sediments through-
 out the Great Lakes. These projects ex-
 emplify the significant progress being
 made toward restoring clean sediments, a
 building block for a healthy, vibrant eco-
 system. Thanks in part to these projects:

"  • Much more is known about the na-
    ture and extent of the sediment con-
    tamination at many Areas of Concern
    (AOCs), setting the stage for future
    actions, including mass balance mod-
    eling and remediation.

   • New assessment technologies, such a
    hydroacoustic profiling, are being re-
    searched.

   • Remedial treatment technologies are
    being evaluated.

   • Full-scale remediations are being de-
    signed and demonstrated.

   • Strong community partnerships be-
    tween government, private industry,
    and citizen groups are being formed
    to plan for and carry out remediation
    actions.

  • Actual remediation, or "moving
    mud," which refers  to several options
    including dredging and capping, will
    soon be a reality at many AOCs.

A synopsis of the sediment grants pro-
gram is now available in a document
which focuses on those 34 projects. The
report, Moving Mud: Remediating Great
Lakes Contaminated Sediments, demon-
strates the impact of GLNPO resources
provided for sediment projects during the
4-year period. It illustrates the many as-
sessments  that have been completed and
highlights new, innovative technologies
being developed to assess contaminated
areas. Moving Mud also focuses attention
on bridging the gap between assessment
and on-the-ground remediation, empha-
sizing the development of strong commu-
nity partnerships to plan and carry out
remediation actions.

For copies of the report, please contact
Brian Stage, U.S. EPA Great Lakes Na-
tional Program Office, at (312) 353-3565
(e-mail: stage.brian@epamail.epa.gov).

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No. 20
\Vinterl99S
Environment Canada Announces
Sediment  Technology  Directory
 s % i n «> s vt K \ i  C \
(Iremt Ijikei 20OO
Clt'tttiup 1'iinti
(.\»tu«K
                  As contaminated sediment removal and
                  treatment technologies have been devel-
                  oped, demonstrations of them have in-
                  creased in scope and complexity. Ini-
                  tially, demonstration projects involved
                  one dredging technology and one treat-
                  ment technology used on less than 1,000
                  cubic meters of contaminated sediment
                  over a 3-5 day period.

                   As each demonstration provided new
                   data and greater hands-on experience,
                   subsequent projects become more wide-
                   ranging and complex.  A typical demon-
                   stration project today features up to 6 in-
                   terlocked technologies involved in the
                   removal and treatment of more than
                   10,000 cubic meters of material for up to
                   3 years.

                   Over time, the private sector, various
                   levels of government,  academia, and
                   technology manufacturers and vendors
                   have requested information about re-
                   moval and treatment technologies. In re-
                   sponse, Environment Canada has pro-
                   duced the Sediment Technology
                   Directory (SEDTEC©). Environment
                   Canada also has begun providing project
                   management services.

                   The Directory
                  SEDTEC© is a user-friendly computer
                  software program which lists removal,
                  treatment, and support  technologies for
                  contaminated sediment. Based on a
                  worldwide inventory of technology
                  manufacturers and vendors, SEDTEC©
                  originally was developed to provide out-
                  lines of technologies suitable for dealing
                  with contaminated sediment in the Great
                  Lakes Basin.

                  Its scope has been expanded to identify
                  suitable technologies for site-specific
                  needs, provide project case studies, and
                  list contacts for stakeholders, project
                  funding agencies, and technology manu-
                  facturers and vendors worldwide. The di-
                  rectory is helpful for anyone seeking in-
                  formation on sediment  remediation
                  technologies.

                  SEDTEC© is available on CD-ROM or
                                      3!/2-inch diskettes and costs Can$250.
                                      Updates listing supplementary information
                                      and related technologies are planned.

                                      The Service
                                      Through SEDTEC©, Environment
                                      Canada also will provide:

                                        • Problem delineation
                                        • Data analysis
                                        • Remedial options identification
                                        • Cost evaluation
                                        • Definition of project goals
                                        • Funding negotiation and partnership
                                        • Technology selection
                                        • Environmental assessment
                                        • Public consultation
                                        • Formulation of scope of work docu-
                                          ments
                                        • Technology audits for implementation
                                        • Follow-up

                                      Workshops and Seminars
                                      Besides project management advice, Envi-
                                      ronment Canada will offer information
                                      exchange and technology transfer
                                      through workshops and seminars targeted
                                      for specific interest groups. Related areas
                                      of expertise that can be incorporated into
                                      the training include:

                                        • Pollution prevention specific to
                                          remediation or evaluation
                                        • Regulatory and corporate issues relat-
                                          ing to liability
                                        • Development of a range of solutions,
                                          including phased strategies for
                                          remediation
                                        • Site-specific costs
                                        • Implications of remedial activities.

                                      For more information, contact Ian Or-
                                      chard of Environment Canada at (416)
                                      739-5874 (e-mail: ian.orchard@ec.gc.ca).

                                      To purchase a copy of the directory, con-
                                      tact Marianne Woods of the Ontario Cen-
                                      ter for Environmental Technology Ad-
                                      vancement, 63 Poison St., 2nd Floor,
                                      Toronto, Ontario, M5A-1A4.  Her phone
                                      number is (416) 778-5264 (e-mail:
                                      oceta@oceta.on.ca). The directory may
                                      also be purchased online at http://
                                      www.oceta.on.ca.

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Assessing the Toxicity and Bioavailability of PAH Mixtures in
Sediments: Science Advisory Board Consultation
                                                                                             No. 20
                                                                                          Winter 1998
Over the past 15 years, a research team
from the EPA Office of Water (OW) and
Office of Research and Development
(ORD) has investigated the toxicity and
bioavailability of sediment contaminants
to benthic organisms. As a result of this
effort, the EPA has proposed the guid-
ance document Technical Basis for De-
riving Sediment Quality Criteria for Non-
ionic  Organic Contaminants for the
Protection of Benthic Organisms by Us-
ing Equilibrium Partitioning Theory
(EPA-822-R-93-011), which establishes
the foundation for developing sediment
quality criteria (SQC).

The Agency has developed SQC for the
pesticides dieldrin and endrin,  and antici-
pates releasing these final documents in
1998. Individual criteria have also been
proposed for the polycyclic aromatic hy-
drocarbons (PAHs) acenaphthene,
fluoranthene and phenanthrene. However,
since  PAHs invariably occur in the envi-
ronment as mixtures rather than as indi-
vidual chemicals, the research team has
continued to investigate the  toxicity of
PAH mixtures in sediment.

Numerous efforts previously have sought
to address and estimate the toxicity of
PAH mixtures (Long et al., 1995; Barrick
et al., 1988). However, the resultant sedi-
ment quality guidelines have engendered
considerable controversy over such is-
sues as the correlative vs. causal relations
between dry weight sediment chemistry
and biological effects, the bioavailability
of sediment contaminants, the effects of
covarying chemicals and mixtures, and
ecological relevance. The EPA team con-
cluded, based on additional  investigation,
that individual PAH criteria would not be
adequately protective of benthic organ-
isms or ecologically relevant.

An approach and methodology have been
identified which address the issues of
bioavailability and toxicity of PAH mix-
tures. The equilibrium partitioning theory
(EqP) provides an approach for identify-
ing and quantifying the bioavailable and
toxic  fraction of PAHs. The EqP pre-
sumes that a chemical partitions into a
state of equilibrium between the sediment
organic carbon, the organism lipid,
and the pore water based upon the
fugacity of the chemical contaminant.
The application of this approach has
been validated in laboratory and field
experiments. Based on their water
column toxicity, PAHs are identified
as "narcotics." The study of narcotic
chemicals has revealed two properties
critical to developing a PAH SQC:

  • The water-column toxicity of nar-
    cotics is inversely proportional to
    the octanol/water partition coeffi-
    cient.
  • The toxicity of narcotic chemical
    mixtures is additive (i.e., the tox-
    icity of the mixture is equal to the
    sum of the toxicities of the indi-
    vidual chemicals).

An empirical model which accurately
predicts the toxicity of PAH mixtures
has been developed by Dr. Richard
Swartz, formerly of EPA-Newport,
and his research team. It is based on
the combination and use of the EqP,
quantitative structure activity relation-
ships (QSAR), narcosis theory, and
concentration response models. This
model's application has been vali-
dated by comparison to the toxicity of
field-collected sediment samples for a
mixture of PAH chemicals. There was
an 86.6 percent correlation and no
significant difference between the
predicted and observed toxicity in
these PAH-contaminated sediments.
Thus, the EqP-based PAH model  pro-
vides a method to address causality,
account for bioavailability and mix-
tures, and predict toxicity and eco-
logical effects. It applies to all nar-
cotic compounds and provides a
unifying synthesis of other guidelines.
The synthesis of these elements pro-
vides the foundation for a sediment
quality criterion for PAH mixtures.

Response from SAB
On May 13, 1997, the research team
delivered a presentation on "Assess-
ing the Toxicity and Bioavailability of
PAH Mixtures in Sediments" to the
                      Continued on page 6

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A'o. 20
Winter 199S
Matching Sediment Chemistry and Toxicity Data Are
Being Compiled to Evaluate the Predictive Ability of
Sediment Quality Guidelines
                  Over the past 7 years, MacDonald Envi-
                  ronmental Sciences Ltd. (MESL), the Na-
                  tional Oceanic and Atmospheric Admin-
                  istration (NOAA), the U.S. Environ-
                  mental Protection Agency (EPA), and the
                  U.S. Geological Survey (USGS) have
                  been involved in studies to develop nu-
                  merical sediment quality guidelines
                  (SQGs) for freshwater,  estuarine, and ma-
                  rine ecosystems. These  studies have been
                  implemented cooperatively with Environ-
                  ment Canada, the Minnesota Pollution
                  Control Agency, and the Florida Depart-
                  ment of Conservation.

                  The SQGs have been used in a wide vari-
                  ety of sediment assessments in Canada
                  and the United States; however, many us-
                  ers have indicated the need to further
                  evaluate the predictive ability of SQGs
                  and develop additional tools for assessing
                  contaminated sediments. Therefore, we
                  are compiling an independent database
                  that can be used to further support sedi-
                  ment quality assessment.

                  Post-1993  Publications Needed
                  In order to develop this  database, we need
                  to obtain matching sediment chemistry
                  and toxicity  data including data from
                  laboratory toxicity tests  or benthic com-
                  munity surveys  conducted on field-col-
                  lected sediments or sediment spiking
                  studies from freshwater, estuarine, and
                                        marine locations. Therefore, we would
                                        like to take this opportunity to request
                                        copies of any recent publications (post-
                                        1993) that contain relevant information
                                        that could be incorporated into the data-
                                        base. Please let us know if the data are
                                        available in an electronic format.

                                        In addition, we would appreciate knowing
                                        about any other relevant studies that you
                                        may be aware of on effects of sediment-
                                        associated contaminants. Please let us
                                        know if you are interested in receiving
                                        copies of any reports or publications that
                                        are prepared during this study. We plan to
                                        make the compiled database available in
                                        1999 or 2000.  Thank you in advance for
                                        your consideration of this  request.

                                        For More Information
                                        For more information, contact Donald D.
                                        MacDonald, MESL, 2376 Yellow Point
                                        Road, RR #3, Ladysmith, BC at
                                        (250)753-1583 (e-mail:  sffmesl®
                                        island.net; L. Jay Field, NOAA, 7600
                                        Sand Point Way, NE, Seattle, WA 98115,
                                        (206) 526-6404, (e-mail: jayfe@hazmat.
                                        noaa.gov; Jim Keating, U.S. EPA, 401 M
                                        St.  SW, MS4305, Washington, DC,
                                        20460, (202) 260-3845 (e-mail: keating.
                                        jim@epamail.epa.gov; and Chris
                                        Ingersoll, USGS, 4200 New Haven Rd.,
                                        Columbia, MO 65201 (573) 876-1819,   '
                                        (e-mail: chris_ingersoll@usgs.gov).
                  SCIENCE ADVISORY BOARD CONSULTATION    Continued from page 5
                  Science Advisory Board (SAB). The ob-
                  jectives of the SAB consultation were to
                  evaluate the proposed approach, identify
                  remaining issues which require further in-
                  vestigation, and determine whether it is
                  reasonable to pursue the development of
                  an SQC for PAH mixtures. The response
                  from the SAB was unanimously favor-
                  able. The SAB identified the proposed
                  approach as  a "significant advancement
                  in the state of the science for evaluating
                  PAHs in sediments." SAB chairperson
                  Bill Adams summarized the consultation
                  by saying that "the research team is on
                  the right track. We agree that SQC for in-
                  dividual PAH compounds  would be
                  underprotective in practice and that a
                                       more meaningful SQC for PAHs should
                                       be based on total PAH."

                                       The OW/ORD team anticipates preparing
                                       a first draft of a PAH guidance document
                                       in 1997. Research and validation will
                                       continue for the next 1-2 years to respond
                                       to the identified research needs and un-
                                       certainties. At that time, the guidance will
                                       be updated, peer reviewed, and published.

                                       For more information, contact Heidi Bell,
                                       (202) 260-5464 (e-mail: bell.heidi
                                       @ epamail.epa.gov); Ross Elliott, (202)
                                       260-1311 (e-mail: elliott.ross@epamail.
                                       epa.gov); or Mary Reiley, (202) 260-9456
                                       (e-mail: reiley.mary @epamail.epa.gov).

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EPA Publishes Deposition of Air Pollutants to the Great Waters,
Second Report to Congress
                                                      No. 20
                                                  Winter 1998
In June 1997, EPA published its second
report to Congress on the atmospheric
deposition of pollutants to the Great Wa-
ters (EPA-453/R-97-011).

Section 112 of the Clean Air Act (CAA)
provides the legislative basis for hazard-
ous air pollutant (HAP) programs directed
by the U.S. Environmental Protection
Agency (EPA). In response to mounting
evidence that air pollution contributes to
water pollution, Congress included sec-
tion 112(m), "Atmospheric Deposition to
Great Lakes and Coastal Waters," in the
1990 CAA. Under this statute, EPA is re-
quired to periodically report to Congress
on the results of the program. Concurrent
with the second report  to Congress, EPA
is to determine  the adequacy of section
112 to prevent adverse effects to public
health and serious or widespread environ-
mental effects associated with atmo-
spheric deposition of hazardous  air pollut-
ants to the Great Waters.

Future Directions
A list of future directions which EPA may
take to support CAA section 112(m) is
provided in the report's executive sum-
mary. Within that list are future actions
which may involve sediment monitoring
and sediment data analysis. They include:

  • Perform exposure and effects studies
   that will build on the recent Great
   Lakes Water Quality Criteria, which
   consider biomagnification. These
   studies will be coordinated with an
   integrated research strategy on the
   persistent pollutants, their distribution
   and concentrations, exposure routes,
   and associated effects.

  • Improve modeling efforts to estimate
   atmospheric loadings to Great Wa-
   ters. For example, adapt and apply
   the comprehensive  approach devel-
   oped for the Lake Michigan Mass
   Balance Model to additional water
   bodies.

  • Increase efforts to identify specific
   emissions sources of atmospheric
   deposition to the Great Waters, both
   nearby and relatively distant from the
     water body, to develop risk manage-
     ment strategies, as well as investigate
     the impact from cycling of pollutants
     that are no longer used or manufac-
     tured in the United States.

   •  Continue to promote pollution reduc-
     tion in the Great Waters, including
     identifying and quantifying, where
     possible, economic impacts associ-
     ated with exposure  and effects indi-
     cators such as fish advisories, habitat
     decline, diminished species diversity,
     fish kills, and declining or contami-
     nated shellfish and fish populations.

 Great Waters Defined
 The water bodies collectively referred to
 as the "Great Waters" in this report are
 the Great Lakes, Lake Champlain, Chesa-
 peake Bay, and specific coastal waters
 (i.e., defined in the statute as coastal wa-
 ters designated through the National Estu-
 ary Program and the National Estuarine
 Research Reserve System). The contribu-
 tion of atmospheric deposition to overall
 pollutant loadings in the Great Waters
 continues to be studied. Atmospheric
 loadings of pollutants result from wet and
 dry particle deposition, and through air-
 water gas exchange. This report describes
 monitoring and modeling studies relevant
 to atmospheric deposition occurring at the
 major water bodies,of the Great Waters.

 Pollutants of concern to the Great Waters
 have not changed since the first report  to
 Congress was published in 1994. The list
 of 15 pollutants (see table) including pes-
 ticides, metal compounds, chlorinated or-
 ganic compounds, and nitrogen com-
 pounds. These pollutants have been
 selected based on information regarding
 their health and environmental effects and
 evidence that they are atmospherically
 deposited to the Great Waters. Most are
 bioaccumulative chemicals that persist in
 the environment for long periods. Many
 of these pollutants are listed as chemicals
 of concern on toxics lists for individual
 water bodies at the local and state levels.

 More information on this report is avail-
 able on the Internet at the EPA address:
http://www.epa.gov/oar/gr8water/.
 The 15 Great Waters
 Pollutants  of Concern

Cadmium and cadmium compounds
Chlordane
DDT/DDE
Dieldrin
Hexachlorobenzene (HOB)
a-Hexachlorocyclohexane (a-HCH)
Lindane(g-hexaphlorocyclohexane:
 g-HCH)
Lead and lead compounds
Mercury and mercury compounds
Polychlorinated Biphenyls (RGBs)
Polycyclic Organic matter (POM)
Tetrachlorodibenzo-p-dioxin(TCDD;
 dioxins)
Tetrachlorodibenzofuran (TCDF;
 furans)
Toxaphene
Nitrogen compounds

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No. 20
\Vmterl99S
USGS Completes  Sediment
Assessment Report of  Upper
Mississippi  River
                 The U.S. Geological Survey (USGS) has
                 been monitoring the Upper Mississippi
                 River (UMR) since 1987 to document the
                 fate and transport of contaminants
                 associated with sediments.

                 The UMR is that part of the
                 river upstream of the
                 confluence with the Ohio
                 River at Cairo, IL. It con-
                 sists of a series of 26 navi-
                 gational pools created by a
                 lock and dam system extend-
                 ing from Minneapolis, MN to   •
                 St. Louis, MO. The navigational
                 pools are shallow, lake-like areas which
                 trap and store large quantities of fine-
                 grained sediments during normal river
                 flows. Concern with the redistribution of
                 the river sediments arose after the flood
                 of 1993.

                 This project was designed to evaluate the
                 status of sediments in the UMR by:

                   • Measuring the concentrations of con-
                     taminants in sediments of the UMR.

                   • Evaluating the toxicity of sediments
                     collected from the river.

                   • Determining the bioaccumulation of
                     contaminants from UMR sediments
                     using field-collected and laboratory
                     exposed oligochaetes.

                   • Determining the benthic community
                     structure in fine-grained sediments
                     within the river.

                 Sediments are often a sink for water-
                 borne contaminants and a source of con-
                 taminants to the overlying water. Also,
                 sediments  may accumulate significant
                 concentrations of contaminants even
                 when water quality criteria are met.

                 Sediment and Organisms Sampled
                 To conduct these assessments, sediment
                 samples and benthic organisms were col-
                 lected from 24 of the 26 navigational
                 pools in the river and from 1 pool in the
                                      Saint Croix River. Two types of sediment
                                      samples were collected from the pools.
                                      One sediment sample was a composite of
                                            15 to 20 sediment grabs along 1 to
                                              5 transects across the down-
                                                stream one-third of each pool
                                                 (B samples). The other sedi-
                                                 ment sample was a compos-
                                                 ite of grabs from 1 station
                                                 on 1 transect within each
                                                 pool (C samples). The latter
                                                 stations were selected based
                                                on historical chemistry data
                                              and the potential to collect oli-
                                            gochaetes. Samples were not col-
                                      lected from the main navigation channels.

                                      Report Contents
                                      Chapter 1 of this report describes whole-
                                      sediment toxicity tests which were con-
                                      ducted for 28 days with the amphipod
                                      Hyalella. Chapter 2 describes the
                                      bioaccumulation of contaminants from
                                      sediments using field-collected oligocha-
                                      etes and 28-day bioaccumulation studies
                                      conducted in the laboratory with the oli-
                                      gochaete Lumbriculus variegatus. Chap-
                                      ter 3 assesses the benthic community in
                                      all 24 C samples. Using the Sediment
                                      Quality Triad approach, the status of
                                      UMR sediments was assessed by inte-
                                      grating sediment chemistry, laboratory
                                      toxicity tests and benthic community
                                      measurements.

                                      Oligochaetes and  Chironomids
                                      The benthic community was dominated
                                      by oligochaetes and chironomids in 14 of
                                      the 23 sediment samples from the UMR
                                      and the 1 sediment sample from Saint
                                      Croix River. Fingernail clams comprised a
                                      large portion of the community in 3 of the
                                      samples and exceeded 1,000/m2 in 5 of
                                      the samples. Total abundance values of
                                      invertebrates ranged from 250/m2 (station
                                      1C) to 22,389/m2 (station 19C) and were
                                      comparable to previously reported values
                                      of the UMR. The frequency of chirono-
                                      mid mouthpart deformities was only 3
                                      percent, which is consistent with the inci-
                                      dence of mouthpart deformities from un-
                                      contaminated sediments. Correlations be-

-------
 tween benthic measures, sediment chem-
 istry, or other abiotic parameters exhib-
 ited few strong or significant correlations
 indicating benthic communities are most
 likely controlled by factors independent of
 contaminant concentrations.

 Sediment Quality Triad
 The Sediment Quality Triad (Triad) is a
 weight-of-evidence approach used to as-
 sess the contamination of sediments by
 integrating sediment chemistry, laboratory
 toxicity testing, and benthic community
 measures. Results from the Triad analysis
 indicated 88 percent of the samples were
 classified as not affected based on sedi-
 ment chemistry, laboratory toxicity, and
 benthic measures. These results are con-
 sistent with the bioaccumulation study in
 which concentrations of contaminants in
 tissue were less than other U.S. sites that
 the laboratory (the Environmental Con-
 taminant Research Center in Columbia,
 MO) has previously studied. In addition,
 pools in about the lower third of the river
 had lower sediment contaminant concen-
 trations, less accumulation of contami-
 nants in tissue, and greater taxa richness.

 The results of the present study indicate
 that the UMR is not severely contami-
 nated compared to other sites that have
 been studied in the United States. Pertur-
 bations that may occur could be attrib-
 uted to channelization, sedimentation
 from surface runoff, or long-term
 changes in the river's natural flow condi-
 tions due to lock and dam construction.

 This study conducted only a partial as-
 sessment  of the UMR sediments and in-
 cluded no assessment of river water. Fur-
 ther, this study was a one-time
 assessment that was conducted after a
 major flood event and does not evaluate
 temporal or spatial variability of sediment
 contamination within the pools. Future re-
 search on, or management of, the Upper
 Mississippi River should evaluate the limi-
 tations of this study.

 For More Information
 This report is available on the Internet at
 http://www.msc.nbs.gov/pubs/unir.html.
 For copies of the report, specify report
 number EPA 823/R/97-005 and contact:
 U.S. EPA, National Center for Environ-
 mental Publications and Information,
 11029 Kenwood Road, Cincinnati, OH
 45242 (513) 489-8910.
                                                                                              No. 20
                                                                                           Winter 1998
1996 Listing of Fish and Wildlife Advisories Now Available
The 1996 update for the database, Listing
of Fish and Wildlife Advisories (LFWA),
is now available from the EPA.

This database includes all available infor-
mation describing state- tribal-, and feder-
ally issued fish consumption advisories in
the United States, the District of Colum-
bia, 4 U.S. territories, and the 12 Cana-
dian provinces and territories.

The number of advisories in the United
States rose by 453 in 1996 to a total of
2,193, representing a 26 percent increase
over 1995. The number of water bodies
under advisory represents 15 percent of
the nation's total lake acres and 5 percent
of the nation's total river miles. In addi-
tion, 100 percent of the Great Lakes wa-
ters and their connecting waters and a
large portion of the nation's coastal  wa-
ters are also under advisory. The number
of advisories in the United States in-
creased for 4 major contaminants (mer-
cury, PCBs,  chlordane,  and DDT).
The 1996 version of the LFWA is PC-
based and is available to the public free of
charge on both 3.5 inch diskettes (EPA
document number EPA-823-C-97-004)
and CD-ROM (EPA document number
EPA-823-C-97-005). For copies contact:

  U.S. Environmental Protection Agency
  National Center for Environmental
   Publications and Information
  11029 Kenwood Road
  Cincinnati, Ohio 45242
  (513-489-8190)

In addition, the database
may be downloaded from.
the Internet through the
URL: http://www.epa.gov/
OST/fishadvice/.For more
information concerning
the National Fish Con-
tamination Program, con-
tact: Jeffrey Bigler by phone at.
(202) 260-1305, fax (202) 260-8930, or
e-mail: bigler.jeff@epamail.epa.gov.

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No. 20
Winter 1998
Volume  II: Risk Assessment  and Fish
Consumption  Limits  Revised by EPA
                 The U.S. Environmental Protection
                 Agency (EPA) is pleased to announce the
                 availability of the Second Edition of the
                 Guidance for Assessing Chemical Con-
                 taminant Data For Use in Fish Adviso-
                 ries Volume II: Risk Assessment and Fish
                 Consumption Limits (EPA 823-B-97-
                 009).

                 The document provides the states, tribes,
                 and other interested parties with the
                 methods recommended by EPA for  cal-
                 culating consumption limits for reducing
                 health risks associated with contaminated
                 fish and shellfish.

                 The Second Edition provides new infor-
                 mation pertinent to selected chemical
                 contaminants, as well as updated guid-
                 ance on methods for developing fish
                 consumption advisories. Updated in-
                 formation is provided on mercury,
                 PCBs, PAHs, TBT, and arsenic.

                 The Second Edition is part of EPA's
                 four-volume series of documents devel-
                 oped to provide guidance to professionals
                 responsible for assessing the health  risks
                     associated with exposure to chemical
                        contaminants in noncommercial
                        fish and shellfish. This manual is
                        the Second Edition of Volume II.
                       Volume I: Fish Sampling and
                     Analysis, First Edition was released
                      in September 1993, with a Second
                        Edition released September 1995.
                        Volume II: Risk Assessment and
                        Fish Consumption Limits was first
                        published in June 1994. Volume
                        III: Risk Management was pub-
                        lished in June 1996. Volume IV:
                        Risk Communication was pub-
                        lished in March 1995.

                        These guidance documents were
                        developed cooperatively with
                        state, federal, tribal and local gov-
                        ernment agencies. All four of
                        these documents should be used
                        together, as no single volume ad-
                        dresses all of the topics necessary
                        for developing fish consumption
                        advisories.
                                      Copies of all four volumes may be ob-
                                      tained by writing to the U.S. Environ-
                                      mental Protection Agency, National Cen-
                                      ter For Environmental Publications and
                                      Information, 11029 Kenwood Rd., Cin-
                                      cinnati, Ohio, 45242, or calling 513-489-
                                      8190. Volumes I, II, and III are available
                                      on the Internet at http://www.epa.gov/
                                      OST/fishadvice.

                                      For More Information
                                      For questions related to the development
                                      or use of this series of documents, please
                                      call Jeffrey Bigler of the EPA Fish Con-
                                      tamination Program at (202) 260-3051
                                      (e-mail: bigler.jeff@epamail.epa.gov).
                                         I was exposed to pore water in sediment quality
                                         surveys, and after 48 noun this is what I look like.
                                         (an you identify me?
                                              eas aiajo asei|d snainjdowiioe

-------
                                                                                                 No. 20
                                                                                             Winter 1998
February 9-13, 1998
1998 Ocean Sciences Meeting
Town & Country Hotel
San Diego, California

Designed specifically for oceanographers,
limnologists, meteorologists, and scientists
working in related areas. Subdisciplines for
the meeting are atmospheric sciences,
hydrology, estuarine sciences, limnology,
oceanography, and ocean technology.

Sponsored  by the American Geophysical
Union and the American Society of Limnol-
ogy and Oceanography. Cosponsored by
the Acoustical Society of America, the
American Meteorological Society, the
Estuarine Research Foundation, the Marine
Technology Society, The Oceanography
Society, and the Virginia Institute of Marine
Science.

For details, contact:
American Geophysical Union
Phone: (800) 966-2481 or (202) 462-6900
Fax: (202) 328-0566
e-mail: meetinginfo@kosmos.agu.org
Web: http://www.agu.org
April 14-18,1998
SETAC -Europe 8th Annual Meeting
Bordeaux, France

"Interfaces in Environmental Chemistry and
Toxicology: from the global to the molecular
level."

For more information, contact:
SETAC-Europe
Av. E. Mounier 83
Box1,  1200
Brussels, Belgium
Phone: 32 2 772 7281
Fax: 32 2 770 53 86
e-mail: 100725.3525@compuserve.com
August 31 - September 3,1998
3rd International Conference on
Hydroscience and Engineering
Cottbus/Berlin, Germany

The conference will cover the latest ideas in
the field of hydroscience and engineering,
including the scientific aspects of modelling
(conceptual,  physical-mathematical
models, field observations, computer
science application, and computer imple-
mentation).
Conference topics will include surface and
subsurface hydrodynamics; estuarine,
coastal, and nearshore processes; river
mechanics; reservoir management; erosion
and sedimentation  modeling; pollutant
transport and dispersion in free surface and
ground water; data investigation and
uncertainty analysis;  numerical methods
and techniques; parameter estimation and
control applications; software development
and model building; and management and
decision support systems.

Sponsors  include the International Associa-
tion for Hydrological Sciences and the
International Research and Training Center
on Erosion and Sedimentation

For more  information, contact:
Conference Secretariat
Brandenburg University of Technology at
Cottbus
Institut fuer Bauinformatik
Karl-Marx-Strasse 17
D-03044
Cottbus, Germany
Phone: +1-49-355-69-2262
Fax: +1-49-355-69-2262
e-mail: lfb@bauinf.tu-cottbus.de
Web:  http://www.bauinf.tu-cottbus.de/
ICHE98/
October 5-7, 1998
Fifth International Conference on Remote
Sensing for Marine and Coastal Environ-
ments
San Diego Princess Convention Center
San Diego, California

Organized by ERIM. Sponsors include
NASA, NOAA/NESDIS. U.S. DOE Nevada
Operations and Remote Sensing Lab, GER
Corporations, RadarSat International, and
National Wetlands Research Center.

For details, contact:
ERIM Marine Conferences
Box 134001
Ann Arbor, Michigan 48113-4001
Phone: (313) 994-1200 ext. 3234
Fax: (313) 994-5123
e-mail: wallman@erim.org

-------
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