&EPA
Environmental Pfotection
Agency
Office of Science ana
Technology (WH-551)
Washington. D.C. 20460
EPA 823-R-92-CX)8b
September 1992
Water
NATIONAL STUDY OF
CHEMICAL RESIDUES
IN FISH
Volume II
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EPA 823-R-92-008b
September 1992
National Study of
Chemical
in Fish
Volume II
Office of Science and Technology
Standards and Applied Science Division
U.S. Environmental Protection Agency
401 M Street, SW
Washington, DC 20460
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Note
This is the third printing (September 1993) of the National Study of Chemical Residues in Fish.
All revisions listed on the errata sheet from the first printing have been incorporated into the
text of Volumes I and n where appropriate.
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Table of Contents
Chapter Page
VOLUME I
LIST OF FIGURES vii
LIST OF TABLES xi
ACKNOWLEDGMENTS xiii
EXECUTIVE SUMMARY xv
1 INTRODUCTION 1
BACKGROUND I
GENERAL APPROACH 1
2 STUDY DESIGN AND APPROACH 3
POLLUTANT SELECTION SCREENING PROCESS 3
FIELD SAMPLING PROCEDURES 4
Sample Collection 4
Sample Handling/Preparation 6
Fish Length and Weight Data 6
ANALYTICAL PROTOCOLS 6
Dioxins/Furans 7
Other Xenobiotic Chemicals 10
Mercury 12
Quality Assurance/Quality Control (QA/QC) 12
SITE SELECTION 15
3 DIOXIN AND FURAN RESULTS AND ANALYSIS 21
PREVALENCE AND CONCENTRATION SUMMARY 21
Toxkity Equivalency Concentration (TEC) 24
Comparison of TCDD and other Dioxin/Furan Compounds 30
GEOGRAPHICAL DISTRIBUTION 30
S OURCE CORRELATION ANALYSIS 30
Sources Located Near Highest Concentrations 30
Concentration Comparison Between Site Categories 39
4 OTHER XENOBIOTIC COMPOUND RESULTS AND ANALYSIS 53
PREVALENCE AND CONCENTRATION SUMMARY 53
COMPOUNDS DETECTED AT MORE THAN 50 PERCENT OF THE SITES 57
Total PCBs 57
Biphenyl 60
Mercury 64
Pentachloroanisole 67
1.Z3 and 1,2,4 TricUorobenzeae 70
Pesticides/Herbicides 73
Ui
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Table of Contents (Conk)
fhaprgr Page
COMPOUNDS DETECTED AT BETWEEN 10 AND 50 PERCENT OF THE SITES 9 1
Hexachlorobenzeoe 91
Pentacblorobenzene 96
1,3,5 Tricfatorobenzene 100
Tetrachlofobenzenes 100
Pesticides/Herbicides 107
COMPOUNDS DETECTED AT LESS THAN 10 PERCENT OF THE SITES 122
Octachlofoscyrene 122
Hexachtorobutadiene 122
DipbenylDisulfide 122
Pesticides/Herbicides 125
COMPARISON WITH NATIONAL CONTAMINANT BIOMONTTORING
PROGRAM 129
5 FISH SPECIES SUMMARY AND ANALYSIS 1 3 1
SUMMARY OF FISH SPECIES SAMPLED 131
PREVALENCE AND AVERAGE CONCENTRATION OF CHEMICALS
BY SPECIES 137
HABITAT AND FEEDING STRATEGY OF MOST FREQUENTLY
SAMPLED SPECIES 137
6 ESTIMATE OF POTENTIAL HUMAN HEALTH RISKS 147
METHOD OF ESTIMATING RISKS 148
Dose-Response Assessment 148
Exposure Assessment 148
150
CARCINOGENIC RISK ESTIMATES 151
NONCARCINOGENIC RISKS 156
REFERENCES 161
GLOSSARY 165
APPENDICES
A LABORATORY Q A/QC PROCEDURES AND RESULTS
A-l Analysis of laboratory QA/QC Data
A-2 AmlytkalProcedves and QosttyAsstnoce Pisa for tte
PCDD/PDCFinFfch
A-3
of Xeoooiotic Chemical O miaminaau to Fba
B ADDITIONAL DATA ANALYSES
B-l
B-2 Nomognpht for Etttoutim Noncttrinotaite Haart lodkct
B-3 SteDescripbon Matrix (abo provided in Volume n. Appendix D)
B-4 Dionm^oom; EpbodeN«nbenLF»ed in Sa«4«DC*lTe«t»(»Uo provided
in Vohme H, Appendix D)
B-5 Xcoobiotici: Eptede Nmten Used in S ttd«ocal Tetti (tl«o provided in
Volume n. Appendix D)
iv
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Table of Contents (Cont)
VOLUME n
PROFILES OF BIOACCUMULATION STUDY CHEMICALS
D iOTJns/Furans:
Dtoxm: 23.7,8 Tetnchkxodibeazo-p-dtaxiB
1.2,3,7.8 Peuidikxodibeozodtoxtai
Hexachlorodibenzodioxios
Furans
Gibe? Xenobioticst
Bipbenyl
Chlwdane
Chicxpyrifos
p.p'-DDE
Dicofol
Dfeldrin
Diphenyl Dtsulfide
Endrin
Hqjtachlor
Heptacblor Epoxide
Hexachkxobenzene
Alpba-BHC(a - HewbtorocyctoteuM)
Isopropalin
Gamma-BHC (Y -HexadtkxocydohouM)
Mercury
Metboxycfalor
Mirex
Nitrofen
Nooacblor
Octacblorosynene
Oxycblordaoe
Pentachlocoanisole
Pentacblocobeozene
Peotacbloropbeooi
Pefthane
Potycbloriotted Bipheoyb (PCBt)
1.2J.4 and 1X3.5 TetnctatanbmM
1,2,44 TetndUorotaaieaB
1^3 Tricbkxobenzene
1^,4 Tricfalotobemcae
1.3^ Tricbiorobeoreoe
Trifluralin
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Table of Contents (Cont.)
VOLUME II (Cont)
DATA TABLES
O-1 Site Description Matrix (also provided in Volume L Appendix B)
D-2 Dioxins/Furans: Episode Numbers Used in Statistical Tests (also provided
in Volume L Appendix B)
D-3 Xenobiotics: Episode Numbers Used in Statistical Tests (also provided
in Volume I, Appendix B)
D-4 Dioxin/Furan Data by Episode Number
Concentration And Detection Limits
D-5 Xenobiouc Data by Episode Number
Set 1 Chemicals
Set 2 Chemicals
Set 3 Chemicals
D-6 Information on Fish Samples
- Percent Lipid
- Sample Wet Weight
- Number of Fish in Composite Sample
- Sampling Date
D-7 List of Confirmation Samples
D-8 List of Duplicate Samples
D-9 Comments Regarding Sample Analyses from EPA Dulutb Laboratory
D-10 Risk Information for Sites Having Composite Fillet Samples with Xenobiooc Data
VI
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List of Figures
Figure Page
2-1 S chematic of laboratory procedures for dioxins and furans 8
2-2 Schematic of laboratory analytical procedure for other xenobiouc chemicals 11
2-3 Schematic of laboratory analytical procedure for mercury 13
2-4 Location of bioaccumulation study sampling sites 16
2-5 Location of targeted sites 17
2-6 Location of sites representing background conditions 18
2-7 Location of sites selected from a subset of the USGSNASQAN network 19
3-1 Summary of dioxins/furans detected in fish tissue 23
3 -2 Cumulative frequency diagrams of concentrations of six dioxin congeners in fish tissue 25
3 -3 Cumulative frequency diagrams of concentrations of six furan congeners in fish tissue 26
3-4 Cumulative frequency distribution of maximum calculated TEC values in fish tissue by
percenole of sites 28
3-5 Toxicity equivalency concentrations (TEC) based on Barnes et al., 1989 method 29
3-6 Map showing geographical distribution of various concentration ranges of
2,3,7,8 TCDD in fish tissue 31
3-7 Map showing geographical distribution of various concentration ranges of
2,3,7,8 TCDF in fish tissue 32
3-8 Map showing geographical distribution of various concentration ranges of TEC
in fish tissue 33
3-9 Example box plot with explanations of features 41
3-10 Box and whisker plot for 2,3,7,8 TCDD concentrations in fish tissue 42
3-11 Box and whisker plot for TEC concentrations in fish tissue 45
3-12 Box and whisker plot for 2,3,7,8 TCDF concentrations in fish tissue 46
3-13 Box and whisker plot for 1,2,3,7,8 PeCDD concentrations in fish tissue 47
3-14 Box and whisker plot for 1,2,3,7,8 PeCDF concentrations in fish tissue 48
3-15 Box and whisker plot for 2,3,4,7,8 PeCDF concentrations in fish tissue 49
3-16 Box and whisker plot for total HxCDDs concentrations in fish tissue SO
3-17 Box and whisker plot for total HxCDFs concentrations in fish tissue 51
4-1 Summary of other xenobiouc compounds detected in fish tissue 55
4-2 Total PCBs: a) cumulative frequency distribution and b) map of geographical distribution
of various concentration ranges in fish tissue 58
4-3 Box and whisker plot for total PCBs in fish tissue 61
4-4 Bipbenyl: a) cumulative frequency distribution and b) map of geographical distribution of
various concentration ranges in fish tissue 63
4-5 Box and whisker plot for biphenyl in fish tissue 65
4-6 Mercury: a) cumulative frequency distribution and b) map of geographical distribution of
various concentration ranges in fish tissue 66
4-7 Box and whisker plot for mercury in fish tissue 68
VII
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List of Figures (Cont.)
Figure Page
4-8 Pentacbloroanisole: a) cumulative frequency distribution and b) map of geographical
distribution of various concentration ranges in fish tissue 69
4-9 Box and whisker plot for pentachloroanisole in fish tissue 71
4-10 Cumulative frequency distribution of a) 1,2,3 trichiorobenzene and b) 1,2,4 trichloro-
benzene in fish tissue 72
4-11 Map of geographical distribution of various concentration ranges for a) 1,2,3 trichioro-
benzene and b) 1,2,4 trichiorobenzene in fish tissue 74
4-12 Box and whisker plot for 1,2,3 trichiorobenzene in fish tissue 75
4-13 Box and whisker plot for 1,2,4 trichiorobenzene in fish tissue 76
4-14 p.p' -DDE: a) cumulative frequency distribution and b) map of geographical distribution of
various concentration ranges in fish tissue 77
4-15 Box and whisker plot for p,p' -DDE in fish tissue 79
4-16 Cumulative frequency distribution of a) total chlordane. b) cis-cblordane, c) trans-chlordane,
and d) oxychlordane in fish tissue 81
4-17 Cumulative frequency distribution of a) trans-nonachlor b) cis-nonachlor and c) total
nonachlor in fish tissue 82
4-18 Map of geographical distribution of various concentration ranges for a) total chlordane
and b) total nonachlor in fish tissue 83
4-19 Box and whisker plot for total chlordane in fish tissue 85
4-20 Box and whisker plot for total nonachlor in fish tissue 87
4-21 Box and whisker plot for oxychlordane in fish tissue 88
4-22 Dieldrin: a) cumulative frequency distribution and b) map of geographical distribution of
various concentrations in fish tissue 89
4-23 Box and whisker plot for dieldrin in fish tissue 90
4-24 Cumulative frequency distribution of a) alpha-BHC and b) ganuna-BHC (lindane)
in fish tissue 92
4-25 Box and whisker plot for alpha-BHC in fish tissue 93
4-26 Box and whisker plot for ganuna-BHC in fish tissue 94
4-27 Map of geographical distribution of various concentration ranges for a) ganuna-BHC
(lindane) and b) alpha-BHC in fish tissue 95
4-28 Hexachlorobenzene: a) map of geographical distirbution of various concentration ranges
and b) cumulative frequency distribution in fish tissue 97
4-29 Box and whisker plot for hexacnlorobenzene in fish tissue 98
4-30 Pentachlorobenzene: a) map of geographical distribution of various concentration ranges and
b) cumulative frequency distribution in fish tissue, c) Cumulative frequency distribution of
1,3,5 trichiorobenzene in fish tissue 99
4-31 Box and whisker plot forpemachJorobeozeneinfisb tissue 101
4-32 Box and whisker plot for 1,3,5 trichiorobenzene in fish tissue 102
vtu
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List of Figures (Cont.)
Figure Page
4-33 Cumulative frequency distribution of a) 1,2,3,4 tetrachlorobenzene.
b) 1,2,3,5 tetrachlorobenzene, and c) 1,2,4,5 tetrachlorobenzene in fish tissue 103
4-34 Map of geographical distribution of various concentration ranges for
a) 1,2,3,4 tetrachlorobenzene, b) 1,2,3,5 tetrachlorobenzene, andc) 1,2,4,5 tetrachlorobenzene
in fish tissue 105
4-35 Box and whisker plot for 1,2,3,4 tetrachlorobenzene in fish tissue 106
4-36 Cumulative frequency distribution of a) inirex and b) chlorpyrifos in fish tissue 108
4-37 Box and whisker plot for mirex in fish tissue 109
4-38 Map of geographical distribution of various concentration ranges for chlorpyrifos in 110
fish tissue
4-39 Box and whisker plot for chlorpyrifos in fish tissue 112
4-40 Cumulative frequency distribution of a) dicofol (kelthane), b) methoxychlor. and c) perthane
in fish tissue 113
4-41 Map of geographical distribution of various concentration ranges for
a) dicofol and b) methoxychlor in fish tissue 114
4-42 Box and whisker plot for dicofol in fish tissue 115
4-43 Cumulative frequency distribution of a) trifluralin and b) isopropalin in fish tissue 117
4-44 Map of geographical distribution of various concentration ranges for a) trifluralin and
b) isopropalin in fish tissue 118
4-45 Box and whisker plot for trifluralin in fish tissue 119
4-46 Box and whisker plot for isopropalin in fish tissue 120
4-47 Endrin: a) cumulative frequency distribution and b) map of geographical distribution of
various concentration ranges in fish tissue 121
4-48 Box and whisker plot for endrin in fish tissue 123
4-49 Cumulative frequency distribution of a) octachlorostyrene, b) hexachlorobutadiene,
c) diphenyl disulfide, and d) nitrofen in fish tissue 124
4-50 Cumulative frequency distribution of a) heptachlor and b) heptachlor epoxide in fish tissue 126
4-51 Map of geographical distribution of various concentration ranges for a) heptachlor and
b) heptachlor epoxide in fish tissue 127
4-52 Box and whisker plot for heptachlor epoxide in fish tissue 128
4-53 Pentachtoronitrobenzene: a) cumulative frequency distribution and b) map of geographical
distribution of various concentration ranges in fish tissue 130
6-1 Graphical tool for estimating upper-bound cancer risk of p,p'-DDE or equivalents for
different fish consumption rates 158
6-2 Graphical tool for estimating upper-bound noncarcinogenic hazard index of p,p'-DDE
for different fish consumption rates 160
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List of Tables
Page
2-1 List of Target Analytes 5
2-2 Internal Standard Solutions Used for PCDD/PCDF Analyses and Xenobiotic Analyses 9
3-1 Surnmary of Dioxins/Furans Detected in Fish Tissue 22
3-2 1989 Toxicity Equivalency Factors 27
3-3 Location of Maximum Measured HxCDD and HpCDD Concentrations in Fish Tissue 37
3-4 Location of Maximum Measured HxCDF and HpCDF Concentrations in Fish Tissue 38
3-5 Mann-Whitney U Test Results for Dioxins/Furans Comparing Selected Source Categories 43
4-1 Summary of Xenobiotic Compounds in Fish Tissue 54
4-2 Summary of PCBs in Fish Tissue 59
4-3 Results of Statistical Tests for Selected Xenobiotics and Mercury 62
4-4 Results of Statistical Tests for Selected Xenobiotics (Pesticides/Herbicides) 80
4-5 Sites with Highest Concentrations of Chlordane-Related Compounds 84
5-1 Distribution and Feeding Strategy for Fish Species Collected 132
5-2 Average Fish Tissue Concentrations of Dioxins and Furans for Major Species 138
5-3 Detailed S ummary of Occurrence of Prevalent Dioxins/Furans by Fish Species 139
5-4 Average Fish Tissue Concentrations of Xenobiotics for Major Species 140
5-5 Detailed Summary of Occurrence of Prevalent Xenobiotics by Fish Species 141
6-1 Dose-Response Variables Used in Risk Assessment 149
6-2 Estimates of Potential Upper-Bound Cancer Risks at Targeted Sites Based on Fillet
Samples 152
6-3 Estimates of Potential Upper-Bound Cancer Risks at Background S ites Based on Fillet
Samples 153
6-4 Fish Tissue Concentrations Used to Estimate Cancer Risks 154
6-5 Number of Sites with Estimated Upper-Bound Risks 155
6-6 Estimated Upper-Bound Risks at Three Fish Consumption Rates Based on Fillet
Samples 157
6-7 Noncarcinogenic Hazard Index Values at Targeted and Background Sites Based on
Fillet Samples 159
XI
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xu
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APPENDIX C
PROFILES OF BIOACCUMULATION STUDY
CHEMICALS
Djoxins/Furans
Dioxin: 23,7,8 Tetrachloro-
dibenzo-p-dioxin
1,23,7,8 Pentachlorodibenzo-
dioxin
Hexachlorodibenzodioxins
Furans
Other Xenobiotics
Biphenyl
Chlordane
Chlorpyrifos
p,p' -DDE
Dicofol
Dieldrin
Diphenyl Disulfide
Endrin
Heptachlor
Heptachlor Epoxide
Hexachlorobenzene
a -Hexachlorocyclohexane
Isopropalin
Other Xenobiotics (cont.>
Lindane
Mercury
Methoxychlor
Mirex
Nitrofen
Nonachlor
Octachlorostyrene
Oxychlordane
Pentachloroanisole
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Perthane
Polychlorinated Biphenyls (PCBs)
1,2,3,4 and 1,2,3,5 Tetrachlorobenzene
1,2,4,5 Tetrachlorobenzene
1,2,3 Trichlorobenzene
1,2,4 Trichlorobenzene
1,3»5 Trichlorobenzene
Trifluralin
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DIOXIN: 23,73 TCDD
CAS No.: 1746-01-6
CAS Preferred Nomenclature:
Dibenzo[b,e][l,4]dioxin,2,3,7,8-tetrachloro-
Empirical Formula:
Synonyms and Common Names:
- 23,7,8 Tetrachlorodibenzo-p-dioxin
- TCDD or TDD
c
TCDD
REGULATORY STATUS
Standards and Criteria;
• EPA Water Quality Criteria (for human
consumption of fish) for a Iff6 cancer
risk (ATSDR, 1987):
0.000014 ng/L
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
• EPA Drinking Water Health Ad-
visories (U.S. EPA, 1988)
Child (10 kg):
1-day exposure = 1 ng/L
10-day exposure = 0.1 ng/L
longer-term exposure = 0.01 ng/L
adult (70 kg):
longer-term exposure = 0.04 ng/L
• Food and Drug Administration Health
Advisory for Fish* (U.S. EPA, 1987c):
<25 parts per trillion (ppt), no serious
health concerns
25-50 ppt, restrict consumption to
twice per month
>50 ppt, consumption not recom-
mended
* Guidance developed for fish caught in
the Great Lakes for use in interstate
commerce only.
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EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restrictions and Bans:
• Center for Disease Control Level of
Concern in Soil for residential areas
(U.S. EPA, 1987c):
Ippb
EPA has required manufacturers to reduce concentrations of TCDD in chemical
products; most chemicals now have less than 0.02 ^.g/g (ATSDR, 1987). Some
compounds such as 2,4,5 T are no longer produced in the U.S.
SOURCES OF DIOXIN
Dioxin Formation:
TCDD is one of 75 types of dioxin formed as unwanted impurities during the manufac-
ture of other organic compounds including herbicides containing 2,4,5 trichlorophenoxy
acids (2,4,5 T); 2,4,5 trichlorophenol used in the defoliant Agent Orange;
hexachlorophene formerly used as a germicide; pentachlorophenol; and PCBs. Other
dioxins which have been studied include 1,2,3,7,8 PeCDD and two of the HxCDDs
(1,2,3,6,7,8 and 1,2,3,7,8,9 HxCDD). TCDD is the most toxic and most studied of all
the isomers.
Dioxin can be generated as a by-product of paper and pulp mill bleaching processes
which use chlorine. It can then be released to aquatic systems in various wastewater
streams and sludges generated by these industries (U.S. EPA, 1988; NCASI, 1987).
Uses of Dioxin:
No commercial production or importation of dioxin in the U.S., but small quantities are
produced for research purposes (NTIS, 1980; ATSDR, 1987).
Other Sources:
Examples of levels of dioxin found in other organic compounds are listed below
(ATSDR), 1987):
- Until 1960, 2,4,5 T had up to 100 ng/g TCDD, now <0. 1
- Agent Orange had 0.02 to 54 [ig/g
- Hexachlorophene had 0.2 to 0.5 ng/g
- Pentachlorophenol has <0. 1 |ig/g of other dioxin isomers but no TCDD
- Polychlorinated Biphenyls (PCBs) also contain TCDD. Oil containing PCBs was
formerly used in electrical transformers. Utilities are gradually replacing these old
transformers.
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• Incineration of municipal and industrial wastes at too low a temperature (<800°C) can
produce dioxin. (Verschueren, 1983; ATSDR, 1987; U.S. EPA, 1987b).
• Derivatives of pentachlorophenol and other woodtreating wastes (NCASI, 1987; U.S.
EPA, 1987b).
• Currently, EPA is investigating possible correlations between dioxin and nearby
petroleum refineries that use chlorine or chlorinated solvents in the catalytic reforming
process.
• Other sources of dioxin include fires and/or spills involving chlorinated benzenes and
PCBs, particularly fires involving transformers or capacitors, burning of wood in
presence of chlorine, and automobile exhaust from leaded gasoline (ATSDR, 1987).
FATE OF DIOXIN IN ENVIRONMENT
Partitioning;
• Based on its physical/chemical properties, dioxin is only slightly soluble in water (Aq.
sol. = 0.000317) and strongly sorbs to soil (Kow = 10,500,000). It has a high potential
for bioaccumulation (BCF = 5,000), although experimental data have shown much
higher values (e.g., over 9,000).
Persistence;
• Because dioxin strongly sorbs to sediment, it persists in soils and aquatic systems.
Photolysis can occur, aided by photosensitizers in surface water (half-life 1 to 1.5 years)
or in the top few inches of soil (half-life 1 to 3 years) (U.S. EPA, 1985b and Freeman,
et al., 1986). Hydrolysis is not thought to be important (Callahan, et al., 1979).
Biotransformation of dioxin in soils is slow (ATSDR, 1987).
HEALTH EFFECTS
Cardnogenidty;
• Oral exposure causes increased incidence of tumors in liver, tongue, hard palate, and
lungs in rats (Kociba et al., 1978a,b) and in thyroid and adrenal glands in mice (NTP,
1982a,b). EPA classification is B2, a probable human carcinogen (IRIS, 1989). IARC
classification 2b (IARC, 1982).
• In combination with herbicides such as trichlorophenols, dioxin is classified by the EPA
as Bl, limited evidence of human carcinogenicity (IRIS, 1989).
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Mutagenic Activity:
Mutagenicity tests have produced inconclusive results. Bacterial tests were negative as
were most tests using rats and mice except when bone marrow cells were used (Green
et al., 1977; Meyne et al., 1985). Early tests using yeast cells showed positive results
(IARC, 1982).
Reproductive Effects:
Adverse reproductive effects are caused in a variety of animals:
- fetotoxic in monkeys (U.S. EPA, 1985b)
- embryotoxic and teratogenic in mice, rabbits, ferrets and rats (IARC, 1977; U.S.
EPA, 1985b)
- reduced fertility and spontaneous abortions in monkeys (ATSDR, 1987)
- birth defects in mice (e.g., cleft palates and kidney abnormalities) (U.S. EPA,
1985b)
Other Toxicological Effects:
Major observed toxic effect on humans is chloracne (U.S. EPA, 1985b).
Human exposure through herbicides and other TCDD-contaminated chemicals can also
cause altered liver function, porphyria, neurotoxicity, and hyperpigmentation (U.S.
EPA, 1985b).
Toxic effects to acutely exposed animals include extreme weight loss, liver and thymus
damage, immunotoxicity, and hepatotoxicity (IARC, 1977; U.S. EPA, 1985a).
Toxicological Effects Indices:
Cancer potency factor (CPF): 1.56xl05 (mg/kg/day)"1 (U.S. EPA, 1986a).
Reference Dose (RfD): IxlO'6 ng/kg/day (ATSDR, 1987).
Oral LDso: 0.6 [igflag in guinea pigs ; 5,500 ng/kg in hamsters (U.S. EPA 1985b).
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight (g/mole):
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Density (g/mL):
Acid Dissociation Constant,
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @
25°C (atm • m3/mol):
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc(mL/g):
Fish Bioconcentration
Factor, BCF:
321.97
solid, colorless
needles with no
odor
305
412.2
1.827 (est.)
N/A
1.93xlO'5(22°C)
3.17xlO~4(25°C)
1.4xlO'9(25°C)
2.1x10'°
6.15-7.28
6.0-7.39
best estimate,
5000
7900-9300,
fathead minnows
Windholz, 1983
Windholz, 1983
Schroy et al., 1985
Schroy etal., 1985
Schroy etal., 1985
Marpleetal., 1986
Schroy etal., 1985
Schroy et al., 1985
Schroy et al., 1985
U.S. EPA, 1985a
U.S. EPA, 1985a
U.S. EPA, 1986a
U.S. EPA, 1985b
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REFERENCES
ATSDR (Agency for Toxic Substances and Disease Registry). 1987. Draft lexicological Profile
for 2,3,7,8-Tetrachlorodibenzo-p-Dioxin. ATSDR, U.S. Public Health Service, Oak Ridge Nation-
al Laboratory, Oak Ridge, TN.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitraore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979. Water-Related
Environmental Fate of 129 Priority Pollutants. U.S. Environmental Protection Agency, Office of
Water Planning and Standards. EPA-440/4-79-029a.
Freeman, R.A., J.M. Schroy, F.D. Hileraan, R.W. Noble. 1986. Environmental Mobility of
2,3,7,8-TCDD and Comparison Chemicals in a Roadway Soil Matrix. In: Chlorinated Dioxins and
Dibenzofurans in Perspective. (C. Rappe, G. Choudhary, L.H. Keith, eds.) Lewis Publishers, Inc.,
Chelsea.
Green, S., Moreland, C. Sheu. 1977. Cytogenic Effect of 2,3,7,8-Tetrachlorodibenzo-p-dioxin on
Rat Bone Marrow Cells. Food and Drug Administration, Washington, D.C. FDA By-Lines 6:292.
(Cited in U.S. EPA 1985a.)
1ARC (International Agency for Research on Cancer). 1982. LARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 29. IARC, Geneva, World Health
Organization.
IRIS. 1989. 2,3,7,8,-TCDD. Integrated Risk Information System. U.S. Environmental Protection
Agency, Washington, DC.
Kociba, R.J., D.G. Keyes, I.E. Beyer, and R.M. Carreon. 1978a. Results of a Two-year Chronic
Toxicity and Oncogenicity Study of 2,3,7,8-Tetrachlorodibenzo-p-dioxin in Rats. Toxicol. Appl.
Pharmacol. 46(2):279-303.
Kociba, R.J., D.G. Keyes, J.E. Beyer, and R.M. Carreon. 1978b. Toxicologic Studies of 2,3,7,8-
Tetrachlorodibenzo-p-dioxin (TCDD) in Rats. Toxicol. Occup. Med. (De Toxicol. Environ. Sci.)
4:281-287. (Cited in U.S. EPA 1985a.)
Marple, L., R. Brunck, and L. Throop. 1986. Water Solubility of 2,3,7,8-Tetrachlorodibenzo-p-
dioxin. Environ. Sci. Technol. 20:180-182.
Meyne, J., D.C. Allison, K. Bose, S.W. Jordan, P.F. Ridolpho, and J. Smith. 1985. Hepatotoxic
Doses of Dioxin Do Not Damage Mouse Bone Marrow Chromosomes. Mutat. Res. 157:63-69.
NCASI (National Council of the Paper Industry of Air and Stream Improvement). 1987. Dioxin:
A Critical Review of Its Distribution, Mechanism of Action, Impacts on Human Health and the
Setting of Acceptable Exposure Limits. Technical Bulletin No. 254. New York, NY.
C-6
-------
NTIS. 1980. Dioxins. Prepared for EPA Industrial Environmental Research Laboratory. Contract
Numbers: 68-03-2577,68-03-2659,68-03-2579.
NTP (NationalToxicological Program). 1982a. Bioassay of 2,3,7,8-Tetrachloro-dibenzo-p-dioxin
for Possible Carcinogenicity (Gavage Study). DHHS Publ. No. (NIH) 82-1765. Carcinogenesis
Testing Program, NCI, NIH, Bethesda, MD; National Toxicology Program, Research Triangle Park,
NC.
NTP (National Toxicological Program). 1982b. Bioassay of 2,3,7,8-Tetrachloro-dibenzo-p-dioxin
for Possible Carcinogenicity (Dermal Study). DHHS Publ. No. (NIH) 82-1757. Carcinogenesis
Testing Program, NCI, NIH, Bethesda, MD; National Toxicology Program, Research Triangle Park,
NC.
Podoll, R.J., H.M. Jaber, and T. Mill. 1986. Tetrachlorodibenzodioxin: Rates of Volatilization and
Photolysis in the Environment. Environ. Sci. Technol. 20:490-492.
Schroy, J.M., F.D. Hileman, and S.C. Cheng. 1985. Physical/Chemical Properties of 2,3,7,8-
TCDD. Chemosphere 14:877-880.
U.S. EPA. 1985a. Drinking Water Criteria Document for 2,3,7,8-Tetrachlorodibenzo-p-dioxin.
U.S. Environmental Protection Agency, Environmental Criteria and Assessment Office, Cincinnati,
OH. EPA 600/X-84-194-L
U.S. EPA. 1985b. Health Assessment Document for Polychlorinated Dibenzo-p-dioxins. U.S.
Environmental Protection Agency, Office of Health and Environmental Assessment, Washington,
DC. EPA/600/8-84/014F.
U.S. EPA. 1986a. Superfund Public Health Evaluation Manual. Office of Emergency and
Remedial Response, Washington, DC. EPA/540/1-86/060.
U.S. EPA. 1986b. Health Assessment Document for Polychlorinated Dibenzofurans (Review
Draft). Environmental Criteria and Assessment Office, Cincinnati, OH. EPA/600/8-86/018-A.
U.S. EPA. 1987a. The National Dioxin Study. Tiers 3,5,6 and 7. U.S. Environmental Protection
Agency, Office of Water Regulations and Standards, Washington, DC. EPA 440/4-87-003.
U.S. EPA. 1987b. National Dioxin Study. U.S. Environmental Protection Agency, Washington,
DC. EPA 530-SW-87-025.
U.S. EPA. 1987c. 2,3,7,8-Tetrachlorodibenzo-p-dioxin. Health Advisory. U.S. Environmental
Protection Agency, Office of Drinking Water, Washington, DC.
U.S. EPA. 1988. U.S. EPA/Paper Industry Cooperative Dioxin Screening Study. U.S. Environ-
mental Protection Agency, Office of Water, Washington, DC. EPA-440/1-88-025.
C-7
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Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Windholz, M. ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals.
Merck and Co., Rahway, NJ.
C-8
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1,2^,7,8 PeCDD
(PENTACHLORODIBENZODIOXIN)
C12H3CI5°2
CAS No.: 40321-76-4
CAS Preferred Nomenclature:
Dibenzo-[b,e](l,4,)dioxin,
1,2,3,7,8-pentachIoro-
Empirical formula: C i2H3ClsO2
Synonyms and Common Names:
- 1,2,3,7,8 Pentachlorodibenzodioxin
- PeCDD
REGULATORY STATUS
• None established at present
SOURCES OF PeCDD
Formation of PeCDD;
• PeCDD is not intentionally produced for any commercial purposes in the U.S. It is an
unwanted by-product of the manufacture of other organic compounds, as is 2,3,7,8
TCDD. PeCDD can also be formed during the incineration of municipal and industrial
wastes at low temperatures (<800°C) (U.S. EPA, 1984; ATSDR, 1987).
• See dioxin: 2,3,7,8 TCDD and hexachlorodibenzodioxins profiles for more information
on other dioxins.
FATE IN ENVIRONMENT
Partitioning:
• Based on its physical/chemical properties, PeCDD is only slightly soluble in water and
strongly sorbs to soil (Row = 7x106). It also has a strong potential for bioaccumulation,
although experimental data on specific BCF values were not found.
C-9
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Persistence;
• Photolysis of PeCDD can occur. In hexane, the half-life of PeCDD exposed to sunlight
was reported to be 5.4 hours (U.S. EPA, 1984).
PeCDD OBSERVED IN THE ENVIRONMENT
• PeCDD has been detected in fish tissues (at unspecified concentrations), but not in
drinking water (U.S. EPA, 1984).
HEALTH EFFECTS
Toxicoiogical Effects;
• No chronic exposure studies have been conducted with PeCDD. This includes a lack
of studies on the potential carcinogenicity, teratogenicity, or mutagenicity of the com-
pound.
• Other forms of dioxin are extremely toxic and carcinogenic in animals. The acute LD50
value of PeCDD suggests that it is biologically less active than TCDD (2,3,7,8 TCDD),
but there are insufficient data to quantitatively estimate the health risk from PeCDD
exposure (U.S. EPA, 1984; ATSDR, 1987). See dioxin: 2,3,7,8 TCDD profile for more
information.
Toxicological Effects Indices;
• Oral LDso values: guinea pigs, 0.009 nmol/kg; mice, 0.94 ^mol/kg (U.S. EPA, 1984).
C-W
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PHYSICAL/CHEMICAL PROPERTIES
Value Reference
Molecular Weight: 356.5 U.S. EPA, 1984
Melting Point (°C): 240-241 U.S. EPA, 1984
Water Solubility, S (ng/L): 0.04 (est.) U.S. EPA, 1984
Kow (Octanol-Water Partition
Coefficient): 7xl06 (est.) U.S. EPA, 1984
Soil Adsorption Coefficient, Koc (mL/g): 5xl06 U.S. EPA, 1984
C-ll
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REFERENCES
ATSDR (Agency for Toxic Substances and Disease Registry). 1987. Draft lexicological Profile
for 2,3,7,8-TCDD (Dioxin). ATSDR, U.S. Public Health Service.
U.S. EPA. 1984. Health Assessment Document for Polychlorinated Dibenzo-p-Dioxins. U.S.
Environmental Protection Agency, Office of Health and Environmental Assessment, Washington,
DC. EPAy600/8-84/014A.
C-12
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HEXACHLORODIBENZODIOXINS
1,2,3,6,7,8 HxCDD;
CAS No.: 57653-85-7
CAS Preferred Nomenclature:
Dibenzo-[b,e](l,4,) dioxin,
1,2,3,6,7,8-hexachloro-
Empirical formula: C12H2C16O2
Synonyms and Common Names:
- 1,2,3,6,7,8 Hexachlorodibenzodioxin
- HxCDD
- HxDD
Ci
Cl
1,2,3/7,8,9 HxCDD:
CAS No.: 19408-74-3
CAS Preferred Nomenclature:
Dibenzo-[b,e](l,4,)dioxin,
1,2,3,7,8,9 hexachloro-
Empirical formula: Ci2H2Cl6O2
Synonyms and Common Names:
- 1,2,3,7,8,9 Hexachlorodibenzodioxin
- HxCDD
- HxDD
ci ci
HxCDD:
CAS No.: 39227-28-6
CAS Preferred Nomenclature:
Dibenzo-[b,e] ( 1 ,4)dioxin,
1 ,2,3,4,7 ,8-hexachloro-
Empirical formula:
Synonyms and Common Names:
- 1 ,2,3 ,4,7 ,8 Hexachlorodibenzodioxin
- HxCDD
- HxDD
C-13
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REGULATORY STATUS
• None established at present
SOURCES OF HxCDD
Total HxCDD Produced:
• The HxCDDs are not intentionally produced for any commercial purposes in the U.S.
• The HxCDDs, as well as other forms of dioxin, are produced as unwanted contaminants
of organic compounds, particularly chlorophenols such as pentachlorophenol (U.S.
EPA, 1984; ATSDR, 1987).
• See dioxin: 2,3,7,8 TCDD and 1,2,3,7,8 PeCDD profiles for more information on other
dioxins.
FATE IN ENVIRONMENT
Partitioning:
• Based on their physical/chemical properties, the HxCDDs are only slightly soluble in
water and strongly sorb to soil (Kow =4.2x10 ). They also have strong potential for
bioaccumulauon (BCF for 1,2,3,7,8,9 HxCDD = 5,800).
Persistence:
Photolysis of the HxCDDs can occur. In n-hexadecane, the half-life of 1,2,3,6,7,8
HxCDD exposed to a sunlamp was 6.8 hours. Two other HxCDDs, 1,2,3,6,7,9 and
1,2,4,6,7,9 HxCDD (in hexane) had half-lives, respectively, of 17 and 47 hours, when
exposed to sunlight (U.S. EPA, 1984).
HxCDDs OBSERVED IN THE ENVIRONMENT
HxCDDs (unspecified isomers) have been detected in fish, gelatin, and human milk but
not in drinking water. Concentrations were not given (U.S. EPA, 1984).
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HEALTH EFFECTS
Carcinogenicity:
• The HxCDDs are rated as probable (B2) human carcinogens by the U.S. EPA because
a 2:1 mixture of 1,2,3,7,8,9 and 1,2,3,6,7,8 HxCDD caused liver tumors in rats and mice
(U.S. EPA, L984).
Other Toxicological Effects:
• Potency of HxCDD estimated to be l/20th of TCDD, the most toxic form of dioxin (U.S.
EPA, 1984). See dioxin: 2,3,7,8 TCDD profile for more health effects information.
• No studies have been conducted on the teratogenicity or mutagenicity of the HxCDDs.
Toxicological Effects Indices;
• Cancer Potency Factor: 6.2xl03 (mg/kg/day)'1 (U.S. EPA, 1984; PHRED, 1988).
• 1,2,3,6,7,8 HxCDD oral LDso values: guinea pigs, 0.178 to 0.255 |imol/kg; mice, 3.19
[imol/kg.
• 1,2,3,7,8,9 HxCDD oral LDso values: guinea pigs, 0.153 to 0.255 |imol/kg; mice, 3.67
(imol/kg.
C-15
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1,2,3,6,7,8 HxCDD PHYSICAL/CHEMICAL PROPERTIES
Value Reference
Molecular Weight: 390.9 U.S. EPA, 1984
Melting Point (°C): 285-286 U.S. EPA, 1984
Water Solubility S(mg/L): 8xlO"6(est.) U.S. EPA, 1984
Log (Octanol-Water Partician
Coefficient), log Kow: 7.6 U.S. EPA, 1984
Soil Adsorption Coefficient, Koc (mL/g): 3xl07 (est.) U.S. EPA, 1984
1,2,3,7,8,9 HxCDD PHYSICAL/CHEMICAL PROPERTIES
Value Reference
Molecular Weight:
Melting Point (°C):
Water Solubility, S (mg/L):
390.9
243-244
6X10"4
PHRED, 1988
U.S. EPA, 1984
PHRED, 1988
Log (Octanol-Water Partition Coefficient),
log Kow: 7.6 PHRED, 1988
Soil Adsorption Coefficient, Koc (raL/g): 3xl07 PHRED, 1988
Fish Bioconcentration Factor BCF: 5800 PHRED, 1988
1A3A73 HxCDD PHYSICAL/CHEMICAL PROPERTIES
Value Reference
Molecular Weight: 390.9 U.S. EPA, 1984
C-16
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REFERENCES
ATSDR (Agency for Toxic Substances and Disease Registry). 1987. Draft lexicological Profile
for 2,3,7,8 TCDD (Dioxin). ATSDR, U.S. Public Health Service, Oak Ridge National Labortary,
Oak Ridge, TN.
PHRED. 1988. Public Health Risk Evaluation Database. U.S. Environmental Protection Agency,
Office of Emergency and Remedial Response, Washington, DC.
U.S. EPA. 1984. Health Assessment Document for Polychlorinated Dibenzo-p-Dioxins. U.S.
Environmental Protection Agency, Office of Health and Environmental Assessment, Washington,
DC. EPA/600/8-84/014A.
C-/7
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C-18
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FURANS
(POLYCHLORINATED DIBENZOFURANS, PCDFs)
CAS Preferred Nomenclature:
2,3,7,8-Tetrachloro-dibenzofuran,
2,3,7,8 TCDF
Empirical Formula: Ci2H4CUO
• The polychlorinated dibenzofurans (PCDFs) are a group of 135 halogenated tricyclic
aromatic hydrocarbons with many structural, distribution, and toxicity similarities to the
dioxins (polychlorinated dibenzodioxins, PCDDs). A partial list of the furans is shown
in Table 1. Very little is known about the individual furans because they typically occur
as mixtures of different forms. For this reason, the sources, environmental fates, and
health effects of the PCDFs will be discussed as a group, with mention of individual
furans when appropriate.
REGULATORY STATUS
• No criteria or standards established at present
SOURCES OF PCDFs
PCDF Production and Use:
• PCDFs are not intentionally produced for any commercial purposes.
• PCDF contamination of products or processes has not caused the banning or restriction
of use in the U.S.
Other Sources;
• Just like the PCDDs, PCDFs are unwanted trace impurities of PCBs, chlorinated phenols
such as hexachlorobenzene or pentachlorophenol, and phenoxy herbicides such as 2,4,5
T. The production of many of these compounds has been restricted or banned (e.g.,
PCBs), but products containing them may still be in use (e.g., electrical transformers).
Example concentrations are listed below:
C-19
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- Phenoxy herbicides had 0.008-0.15 mg/kg PCDFs (Rappe et al., 1978, 1979; Ah-
lingetal., 1977).
- Pentachlorophenol has contained 59.8-790 mg/kg PCDFs {Rappe et al., 1979).
- Hexachlorobenzene was found to contain 0.35 to 58.3 mg/kg PCDFs (Villanueva et
al., 1974).
- PCDF contaminants in polychlorinated bipnenyls (PCBs) have been measured at
levels of 0.8 to 13.6 mg/kg (CNRC, 1978). 2,3,7,8 TCDF and 2,3,4,7,8 PeCDF are
generally found at <1 ppm in most PCBs (U.S. EPA, 1986).
• Incineration of municipal and industrial wastes at too low a temperature (<800 °C) can
produce PCDFs, which can be released to the environment either in flue gas or adsorbed
to fly ash (U.S. EPA, 1986).
FATE OF PCDFs IN ENVIRONMENT
Partitioning:
• As shown in Table C-l, the compound 2,3,7,8 TCDF is the only PCDF for which a
number of physical and chemical properties have been determined. Based on these
properties, and its structural similarity to the dioxin 2,3,7,8, TCDD, 2,3,7,8 TCDF is
likely to be only slightly soluble in water and strongly sorb to soil {Kow = 660,700). It
also has a high potential for bioaccumulation based on an estimated BCF of 602,600
(Hansch and Leo, 1981).
Persistence:
• Because 2,3,7,8 TCDF strongly sorbs to sediments, it persists in soils and aquatic
systems. Some photodegradation can occur with tetra- and penta-CDFs losing chlorine
atoms and forming tri-CDFs. For example, irradiation (254 nm) of 1 ng/L 2,3,7,8 TCDF
in n-hexane for 4 hours yielded 2,3,8 and 2,3,7 TrCDF (Mazer and Hileman, 1982).
• Very little is known about the biodegradation of PCDFs, but they are probably like the
dioxins and relatively resistant to biodegradation (U.S. EPA, 1986).
HEALTH EFFECTS
PCDF Effects on Animals:
• Toxicological studies of PCDFs demonstrate that the effects of this group of compounds
are remarkably similar to the PCDDs (U.S. EPA, 1986) (see dioxin: 2,3,7,8 TCDD,
1,2,3,7,8 PeCDD, or HxCDDs profile for more information on dioxins).
• At present only short-term, high-dose, acute-exposure animal tests have been conducted
with PCDFs. The most studied form has been 2,3,7,8 TCDF, which causes adverse
health effects very similar to those caused by 2,3,7,8 TCDD. These effects include
C-20
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weight loss, liver, thymus and immune system damage, and skin changes (U.S. EPA,
1986).
Two of three monkeys died after 6 months of exposure to 5 g/kg 2,3,7,8 TCDF in their
food (U.S. EPA, 1986).
PCDF Effects on Humans:
Human exposure to PCDFs occurred in two major incidents when PCBs (containing a
mixture of PCDFs) accidently contaminated rice oil in Japan and China. The resulting
symptoms (attributed to 2,3,4,7,8 PeCDF exposure) consisted of liver disturbances, skin
lesions, excessive skin pigmentation, temporary blindness, numbness of feet and hands,
and weakness (Kuratsune et al., 1972; Kuratsune, 1975,1980; Urabe and Asahi, 1985;
Lu and Wu, 1985; Hsu et al., 1985).
Studies of potential carcinogenesis in humans are still ongoing. No tests have been
conducted with animals (U.S. EPA, 1986).
Reproductive Effects:
• 2,3,4,7,8 PeCDF, 1,2,3,7,8 PeCDF and 1,2,3,4,7,8 HxCDF can cause kidney damage
and cleft palate in mouse fetuses (U.S. EPA, 1986).
Mutagenic Activity;
• The four PCDFs (2,8 DCDF; 3,6 DCDF; 2,3,7,8 TCDF; and OCDF) tested for
mutagenicity in bacteria had negative results (U.S. EPA, 1986).
Toxicological Effects Indices:
• Reference Dose (RfD), 2,3,7,8 TCDF: 2x10-5 ng/kg/day (U.S. EPA, 1986).
• Reference Dose (RfD), 2,3,4,7,8 PeCDF: 3x10-6 ng/kg/day (U.S. EPA, 1986).
• Oral LD50 values for 2,3,7,8 TCDF: guinea pigs, 5-10 ^tg/kg; mice and rats, > 6000
Hg/kg; rhesus monkey, 1000 ng/kg (U.S. EPA, 1986).
C-21
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TABLE 1.
Physical/Chemical Properties of Some Polychlorinated Dibenzofurans (from U.S. EPA, 1986)
CAS No.
51207-31-9
57117-41-6
57117-31-4
57117-44-9
72918-21-9
70648-26-9
60851-34-5
67562-39-4
55673-89-7
Name Abbreviation
2,3,7,8 Tetrachloro- 2,3,7,8
dibenzofuran TCDF
1,2,3,7,8 Pentachloro- 1,2,3,7,8
dibenzofuran PeCDF
2,3,4,7,8 Pentachloro- 2,3,4,7,8
dibenzofuran PeCDF
1,2,3,6,7,8 Hexachloro- 1,2,3,6,7,8
dibenzofuran HxCDF
1,2,3,7,8,9 Hexachloro- 1,2,3,7,8,9
dibenzofuran HxCDF
1,2,3,4,7,8 Hexachloro- 1,2,3,4,7,8
dibenzofuran HxCDF
2,3,4,6,7,8 Hexachloro- 2,3,4,6,7,8
dibenzofuran HxCDF
1,2,3,4,6,7,8 Heptachloro- 1,2,3,4,6,7,8
dibenzofuran HpCDF
1,2,3,4,7,8,9 Heptachloro- 1,2,3,4,7,8,9
dibenzofuran HpCDF
Melting
Point Density
(°C) (g/ml)
219-228 1.72
225-227
168-170
232-234
N/A
225.5-226.5 -
N/A
236-237
221-223
Estimated
Vapor
Pressure
(mm Hg, 25°C)
2.0xlO'6
~
l.lxlO"6
—
~~
0.3-0.4
0.3-0.4
Log (Octanol- Soil
Water Partition Adsorption
Coefficient), Coefficient,
log Kow log Koc
5.82 5.61
—
_.
__
•_ — —
"
—
C-22
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REFERENCES
Ahling, B., A. Lindskog, B. Jansson, and G. Sundstrom. 1977. Formation of Polychlorinated
Dibenzo-p-Dioxins and Dibenzofurans During Combustion of a 2,4,5-T Formulation. Chemo-
sphere 8:461-468.
CNRC (Canadian National Research Council). 1978. Polychlorinated Biphenyls: Biological
Criteria for an Assessment of their Effects on Environment Quality. NRCC/CNRC, Ottawa. Publ.
No. 16077.
Hansch, C., and A.J. Leo. 1981. Log P Software Program for Med-Chem Project, Pomona College,
CA.
Hsu, S.T., C.I. Ma, and S.K.H. Hsu. 1985. Discovery and Epidemiology of PCS Poisoning in
Taiwan. A Four-Year Follow-up. Environ. Health Perspect. 59:5.
Kuratsune, M. 1975. National Conference on Polychlorinated Biphenyls. Chicago, November
19-21,1975. EPA 560/6-75-004.
Kuratsune, M. 1980. Yusho. In Halogenated Biphenyls, Terphenyis, Naphthalenes, Diben-
zodioxins and Related Products, ed. R.D. Kimbrough. Elsevier, Amsterdam.
Kuratsune, M., T. Yoshimara, J. Matsuzaka, and A. Yamaguchi. 1972. Epidemiological Study on
Yusho; a Poisoning Caused by Ingestion of Rice Oil Contaminated with a Commercial Brand of
Polychlorinated Biphenyls. Environ. Health Perspect. 1:119-128.
Lu, Y.C., and Y.C. Wu. 1985. Clinical Findings and Immunological Abnormalites in Yu-Cheng
Patients. Environ. Health Perspect. 59:17.
Mazer, T., and F.D. Hileman. 1982. The Ultraviolet Photolysis of Tetra-Chlorodibenzofurans.
Chemosphere 11:651 -661.
Rappe, C, A. Gara, and H.R. Buser. 1978. Identification of Polychlorinated Dibenzofurans
(PCDFs) in Commercial Chiorophenol Formulations. Chemosphere 7:981-991.
Rappe, C., H.R. Buser and H-P. Bosshardt. 1979. Dioxins, Dibenzofurans and Other
Polyhalogenated Aromatics: Production, Use, Formation, and Destruction. Ann. N.Y. Acad. Sci.
320:1-18.
Urabe, H.t and M. Asahi, 1985. Past and Current Dermatological Status of Yusho Patients. Environ.
Health Perspect 59:11.
U.S. EPA. 1986. Health Assessment Document for Polychlorinated Dibenzofurans. Review Draft.
U.S. Environmental Protection Agency, Environmental Criteria and Assessment Office, Cincinnati,
OH. EPA/600/8-86/018A.
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Villanueva, E.G., R.W. Jennings, V.W. Burse, and R.D. Kirabrough. 1974. Evidence of
Chlorodibenzo-p-dioxin and Chlorodibenzofuran in Hexachlorobenzene. J. Agric. Food Chem.
22(5):916-917.
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BIPHENYL
CAS No.: 92-52-4
CAS Preferred Nomenclature:
1,1-Biphenyl
Empirical Formula: C12H10
Synonyms and Common Names:
- Bibenzene - 1,1-Biphenyl
- Diphenyl - Phenylbenzene
C12H10
REGULATORY STATUS
Standards and Criteria;
• EPA Water Quality Criteria (for human
consumption of fish):
None established at present
• EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
• EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
• EPA Drinking Water Health Ad-
visories:
None established at present
• EPA Tolerance Level for Citrus Fruit
(40CFR180.141):
110 ppm
• Food and Drug Administration Action
Level for Fish:
None established at present
Use Restrictions and Bans:
None found.
SOURCES OF BIPHENYL
Total Biphenyl Produced:
Commercial production of biphenyl began in 1926 (Verschueren, 1983). In 1976,
approximately 88 million pounds of biphenyl were produced (Kirk-Othmer, 1982).
However, in 1984, production decreased to approximately 35 million pounds (USITC,
1985). In 1986, four companies were producing biphenyl: Bethlehem Steel Corpora-
tion, Dow Chemical, Monsanto Company, and Sybron Corporation.
C-25
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Uses of Biphenyl:
Biphenyl is used as a textile dye carrier, heat exchange medium, hydraulic fluid
component, and as a plasticizer (Kirk-Othmer, 1982). It is also used during packaging,
storage, and transport as a citrus wrapper fungicide to control mycelial growth and spore
formation of blue, green, and stem rot molds. Biphenyl is used primarily on grapefruit,
lemons, and oranges (Farm Chemicals Handbook, 1985; Thomson, 1985; Worthing,
1979).
Biphenyl is the basic structural unit for the production of polychlorinated biphenyls
(PCBs) (Waid, 1986) and is a breakdown product of PCBs.
Other Sources:
• Biphenyl is also a by-product of benzene production. About 1 kg is generated for every
100 kg of benzene (Verschueren, 1983).
FATE IN ENVIRONMENT
Partitioning;
• Based on its physical/chemical properties, biphenyl is soluble in water (Aq. Sol. = 7.5
mg/1), highly volatile (H estimated as 0.027 atm • m /mol), and strongly sorbed to
organic matter (Kow = 12,300). Biphenyl has a moderate potential for bioaccumulation
(BCF =500).
Persistence:
Biphenyl is biodegradable. Acclimation can significantly increase the biotransforma-
tion rate. For example, in fresh sewage no degradation occurred after 24 hours, whereas,
in acclimated sewage, 87 percent was degraded after 24 hours (Verschueren, 1983). In
river water at 20°C, 50 percent of initial biphenyl concentrations from 1 to 100 |ig/L
were degraded after 1.5 to 3 days. This corresponds to a degradation rate of 0.46/day
to 0.92/day (Bailey et al., 1983).
The volatilization half-life in deep water was found to be 7.52 hours (Bailey et al., 1983).
HEALTH EFFECTS
Carcinogenic! ty:
• Papilloma and squamous cell tumors of the forestomach were observed in rats (Clayton
and Clayton, 1981-1982).
C-26
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• The carcinogenic potential of this compound has not been evaluated by IARC or the
U.S. EPA.
Mutagenic Activity:
• Biphenyl produced chromosome damage (sister chromatid exchange) in hamster
fibroblast cells (Sax, 1984).
Reproductive Effects:
• No effect was observed in rats fed biphenyl during fetal development (Shepard, 1980).
Other Toxicological Effects;
• Repeated exposure to dust may result in irritation of human skin and the respiratory tract.
• Chronic (long-term, low-dose) exposure may affect the central nervous system causing
symptoms such as fatigue, headache, tremors, insomnia, sensory impairment, and mood
changes (Sittig, 1985).
• Brain damage and nerve degeneration were reported in workers exposed to biphenyl
(Gosselin et al., 1984).
Toxicological Effects Indices:
• Reference Dose (RfD): 5 x 10"2 mg/kg/day (PHRED, 1988).
• TWA-TLV (time-weighted average, threshold limit value) for occupational exposure:
0.2 ppm (1.5 mg/m3) (ACGffl, 1986).
• Oral LDso: rat, 328 g/kg; rabbit, 2.41 g/kg (Gosselin et al., 1984).
C-27
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant,
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H @ 25°C (atm - m3/mol):
Log (Octanol-Water Partition Coefficient),
log Kow:
Soil Adsorption Coefficient,
Koc (mL/g):
Fish Bioconcentration Factor, BCF:
154.2
solid, light tan flakes
69-71
254-255
1.18 @ 4°C
N/A
7.5 (25°C)
1 (70°C)
0.027 (calc.)
4.09
4.4xl03(calc.)
590 (calc.)
437 (exptl.)
Verschueren, 1983
Hartley & Kidd, 1983
Hartley & Kidd, 1983
Verschueren, 1983
Verschueren, 1983
Hartley & Kidd, 1983
Lymanetal., 1982
Leo,1983
Lymanetal., 1982
Lymanetal., 1982
Verschueren, 1983
C-28
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Chemical Substances in the Work Environment ACGIH, Cincinnati, OH.
Bailey, R.E., S.J. Gonsior, and W.L. RhineharL 1983. Biodegradation of the Monochlorobiphenyls
and Biphenyl in River Water. Environ. Sci. Technol. 17(10):621-624.
Clayton, G.D. and F.E. Clayton, eds. 1981-82. Patty's Industrial Hygiene and Toxicology. 3rd
rev. ed.. Vol. 2A, 2B, 2C, Toxicology. John Wiley and Sons, Inc., New York.
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Gosselin, R.E., R.P. Smith, H.C. Hodge, and J.E. Braddock. 1984. Clinical Toxicology of
Commercial Products. 5th ed. The Williams and Wilkins Co., Baltimore.
Hartley, D. and H. Kidd, eds. 1983. The Agrochemicals Handbook. The Royal Society of
Chemrstry, Nottingham, England.
Kirk-Othmer Encyclopedia of Chemical Technology. 1984. 3rd ed. John Wiley and Sons, Inc.,
New York.
Klaassen, C.D., M.D. Amdur, and J. Doull, eds. 1986. Casarett and DoulTs Toxicology. The Basic
Science of Poisons. 3rd ed. Macmillan Publishing Co., New York.
Leo, AJ. 1983. Log P Parameter Database. Pomona College, Claremont, CA.
Lyman, W.J., ed. 1982. Handbook of Chemical Property Estimation Methods. McGraw-Hill, New
York.
Public Health Risk Evaluation Database (PHRED). 1988. U.S. Environmental Protection Agency,
Office of Emergency and Remedial Response, Washington, D.C.
Reynolds, J.E.F., and A.B. Prasad, eds. 1982. Martindale: The Extra Pharmacopeia. 28th ed. The
Pharmaceutical Press, London.
Sax, N.I. 1984. Dangerous Properties of Industrial Materials. 6th ed. VanNostrandReinholdCo.,
New York.
Shepard,T.H. 1980. Catalog of Teratogenic Agents. 3rded. The Johns Hopkins University Press,
Baltimore.
Sittig, M., ed. 1985. Handbook of Toxic and Hazardous Chemicals and Carcinogens. 2nd ed.
Noyes Publications, Park Ridge, NJ.
C-29
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Thomson, W.T. 1985. Agricultural Chemicals Book IV - Fungicide. 1985 revision.
U.S. EPA. 1986. Superfund Public Health Evaluation Manual. U.S. Environmental Protection
Agency, Office of Solid Waste and Emergency Response, Washington, DC. EPA-540/1-86/060.
U.S. International Trade Commission (USUC). 1985. Synthetic Organic Chemicals. United States
Production and Sales. 1984. U.S. Government Printing Office, Washington, DC.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Waid, J.S., ed. 1986. PCBs and the Environment. CRC Press, Boca Raton, FL.
Worthing, C.R., ed. 1979. The Pesticide Manual: A World Compendium. 7th ed. British Crop
Protection Council, Croydon, England.
C-30
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CHLORDANE
CAS No.: 57-74-9 (combined form)
5 103-74-2 (trans- form)
5 103-7 1-9 (cis- form)
CAS Preferred Nomenclature:
4,7-Methano- IH-indene
1 ,2,4,5,6,7,8,8-octachloro-
2,3,3a,4,7,7a-hexahydro
C!
Cl
Empirical Formula:
occurs in cis and trans forms
Synonyms and Common Names:
- ChlorKil - Chlorindan
- Corodan
- Kypchlor
- Octa-Klor
- Oktaterr
- Synklor
- Toxichlor
Dowchlor
Niran
Topiclor
Ortho-Klor
Octachlorodi-hydrodicyclopentadiene
Velsicol 1068
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for human
consumption of fish) for a 10 cancer
risk (U.S. EPA, 1986b):
0.48 ng/L
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms)
(IRIS, 1989):
Freshwater Saltwater
'3
Chronic,
Acute, u.g/L
4.3x10
2.4
at
'3
4.0x10'
9.0x10
-2
EPA Drinking Water Health Ad-
visories (IRIS, 1989)
child (10 kg):
1-day exposure = 60 |ig/L
10-day exposure = 60 p.g/L
longer-term exposure = 0.5 |ig/L
adult (70 kg):
longer-term exposure = 2 jig/L
EPA Tolerance Levels for Raw
Agricultural Commodities (51 FR
46668):
All tolerances revoked, 12/24/86
C-3/
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EPA Drinking Water Standard (50 FR
4696):
Proposed Maximum Contaminant
Level = 0.002 mg/L
Proposed Maximum Contaminant
Level Goal = 0 mg/L
Food and Drug Administration Action
Level for Fish (55 FR 14361):
0.3 ppm ,
Action Level for Other Food
0.1 to 0.1 to 0.3 ppm*
* FDA Action Levels are for use in
interstate commerce.
Use Restrictions and Bans:
All uses except subsurface ground insertion for termite control cancelled in 1987. All
other uses except the dipping of roots or tops of nonfood plants were cancelled in 1978,
although some uses were phased out gradually through 1983 (43 FR 12372). Limited
sales, distribution and use of existing stocks of chlordane products allowed, with the
requirement that all applications must be done by a licensed applicator (1987,
52 FR 42145).
SOURCES OF CHLORDANE
Total Chlordane Produced:
In 1971, 25 million pounds were produced by Velsicol Chemical Co. (Ouellette and
King, 1977). In 1974, production had decreased to 22 million pounds (U.S. EPA, 1980).
Most uses were phased out between 1978 and 1980. Velsicol Corp. is still the only U.S.
producer (U.S. EPA, 1986b).
Oxychlordane, although not found in technical-grade chlordane, is a major metabolic
product of chlordane. It has comparable toxic effects (see Oxychlordane profile)
(Bamett and Dorough, 1974).
Uses of Chlordane:
Chlordane is a chlorinated hydrocarbon originally registered as a pesticide in 1948. Prior
to cancellation in 1980, it was used for control of ants, cutworms, grasshoppers, and
other insects for corn, grapes, strawberries, and other crops (Hartley and Kidd, 1987).
Until 1987, chlordane was used as a dip for nonfood roots and tips of plants.
No sale, distribution, or use is permitted after April 15,1988 (52 FR 42145, Nov. 3,1987).
C-32
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FATE IN ENVIRONMENT
Partitioning;
• Based on its physical/chemical properties, chlordane is moderately volatile (H = 9.6x 10"
atm • m /mole), sorbs moderately to soil (Kow = 2,100), and has a high potential for
bioaccumulation (BCF = 14,000).
Persistence;
• The cis- form of chlordane can hydrolyze under alkaline conditions (Kb = 4.3x103
mol/hr). The trans- form did not hydrolyze at pH 3, 7, or 11 during the 5-day duration
of the experiments (Ellington et al., 1987). Chlordane can undergo photolysis in the
presence of photosensitizers. One degradation product is photo-cis-chlordane (more
toxic to some animals and can be bioaccumulated (IRIS, 1989)). Little information is
available on the biotransformation of chlordane in aquatic systems. The half-life is
estimated to be about 1 year (Hartley and Kidd, 1987).
HEALTH EFFECTS
Carcinogenici'ty:
• Chlordane administered orally has been shown to cause liver carcinomas in mice and
rats of both sexes (IRIS, 1989; Williams et al., 1984). The EPA classification is B2, a
probable human carcinogen (IARC Class 2b) (IARC, 1979; IRIS, 1989).
Mutagenic Activity;
• Tests with chlordane in cultured mammalian cells has shown it to be mutagenic. Results
have been negative, however, in mouse and bacterial tests. Chlordane has induced gene
conversions in yeast (U.S. EPA, 1984; IRIS, 1989).
Reproductive Effects;
• Orally-administered chlordane was not fetotoxic or teratogenic to rat offspring. It did
cause decreased fertility in both sexes for rats and in female mice. The viability of mice
and rat offspring was also decreased (U.S. EPA, 1984).
Other Toxicological Effects;
• Acute (short-term, high-dose) poisoning effects are due to chlordane neurotoxicity and
can result in hyperexcitability, convulsions, depression, muscle tremors, coma, and
possible death (U.S. EPA, 1984). Chronic (long-term, low-dose) exposure can result in
C-33
-------
liver toxicity and blood disorders such as anemia (U.S. EPA, 1984). Chronic chlordane
exposure causes liver disease in rats, mice, and dogs (IRIS, 1989; TDB, 1985-1986).
ToxicologicaJ Effects Indices:
Cancer potency factor (CPF) = 1.3 (mg/kg/day)"1 (IRIS, 1989)
Concentration
Cancer Risk Level in Drinkin ^aterIRIS. 1989^
1 in 10,000 3
1 in 100,000 0.3 ng/L
I in 1,000,000 0.03
Reference Dose (RfD) for noncarcinogenic effects: 6xlO"5 mg/kg/day (IRIS, 1989)
TWA-TLV (Time-weighted average, threshold limit value for occupational exposures):
0.5 mg/m3 for skin exposure (ACGIH, 1986).
C-34
-------
PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Water Solubility, S (mg/L):
Vapor pressure, P (mm Hg):
Henry's Law Constant H @
25°C (atm • m3/mol):
Hydrolysis Rates:
Octanol-Water Partition
Coefficient, log Kow:
Org. Carbon Adsorption
Coefficient, KOC (mL/g):
Fish Bioconcentration
Factor, BCF:
409.8
pure-solid;
technical grade-
amber viscous liquid
103.0-105.0 (cis)
107.0-108.8 (trans-)
175
1.56-1.57
0.056-1.85
lx!0'5(25°C)
9.6xlO'5
trans-: no
degradation in 5 days
cis-:Kb = 4.3xlO"3/
mol/hr
3.32
1.4xl05
1.4xl04
Windholz, 1983
Windholz, 1983
Windholz, 1983
Windholz. 1983
Windholz, 1983
U.S. EPA, 1986b
Callahan et al., 1979
U.S. EPA, 1986b
Ellington et al.,
1987
U.S. EPA, 1986b
U.S. EPA, 1986b
U.S. EPA, 1986b
U.S. EPA, 1980
C-35
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Chemical Substances in the Work Environment ACGIH, Cincinnati, OH.
Barnett, J.R., and H.W. Dorough. 1974. Metabolism of Chlordane in Rats. J. Agric. Food Chem.
22:612-619.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979. Water-Related
Environmental Fate of 129 Priority Pollutants, Vol. I. U.S. Environmental Protection Agency,
Office of Water Planning and Standards. EPA-440/4-79-029a.
Ellington , J.J., F.E. Stancil, Jr., W.D. Payne, and C. Trusty. 1987. Measurement of Hydrolysis
Rate Constants for Evaluation of Hazardous Waste Land Disposal: Volume 2: Data on 54
Chemicals. U.S. Environmental Protection Agency, Athens, GA. EPA/600/3-87/019.
Hartley, D., and Kidd, eds. 1987. Agrochemicals Handbook. Royal Society of Chemistry:
Nottingham, England.
IARC (International Agency for Research on Cancer). 1979. I ARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans. Vol. 20. IARC, Lyon, France.
IRIS. 1989. Chlordane. Integrated Risk Information System. U.S. Environmental Protection
Agency, Washington, DC. Last updated Feb. 10, 1988.
Ouellette, R.P., and J.A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Committee.
U.S. EPA. 1980. Ambient Water Quality Criteria for Chlordane. U.S. Environmental Protection
Agency, Office of Water Regulations and Standards, Criteria and Standards Division. EPA-440/5-
8-027.
U.S. EPA. 1984. Health Effects Assessment for Chlordane. Office of Research and Development,
Cincinnati, OH. EPA-540/1-86-023.
U.S. EPA. 1986a. Pesticide Fact Sheet #109, Chlordane.
U.S. EPA. 1986b. Superfund Public Health Evaluation Manual. U.S. Enviromental Protection
Agency, Office of Solid Waste and Emergency Response, Washington, DC. EPA-540/1-86/060.
C-36
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Williams, G.M., and S. Numoto. 1984. Promotion of Mouse Liver Neoplasmas by the Or-
ganochlorine Pesticides Chlordane and Heptachlor in Comparison to Dichlorodi-
phenyltrichloroethane. Carcinogenesis 5:1689-1696.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck and Co., Rahway, NJ.
C-37
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CHLORDANE, HEPTACHLOR, OXYCHLORDANE, AND RELATED COMPOUNDS
OBSERVATIONS AND EFFECTS ON PISCIVOROUS WILDLIFE
There are several components in technical grade chlordane. Active ingredients include chlordane,
cis-chlordane, trans-chlordane, trans-nonachlor, andheptachlor(Stickeletal., 1979). The metabolic
products of chlordane are oxychlordane, chlordane isomers, glucuronides, and heptachlor (Newell
etal.. 1987).
Technical grade heptachlor contains heptachlor, trans-chlordane, and cis-chlordane (Stickel et al.,
1979). Heptachlor metabolizes to heptachlor epoxide (U.S. EPA, 1980, as cited in Newell).
Stickel et al. (1979) investigated the lethal levels of chlordane and the metabolites oxychlordane
and heptachlor epoxide in several bird species. The lethal level of heptachlor epoxide in the brains
of heptachlor-fed birds was 8 ppm wet weight. In oxychlordane-fed birds, the lethal level of
oxychlordane was 5 ppm wet weight. However, chlordane compounds exhibit an additive effect.
For birds that were fed chlordane, Stickel et al. (1979) found that the lethal levels of heptachlor
epoxide and oxychlordane in the brain were only about 28% of the concentrations listed above.
Chlordane components and metabolites have been detected in several fish-eating bird species. Two
hundred twenty eggs were randomly collected from black-crowned night-herons in the intermoun-
tain western United States between 1978 and 1980. Oxychlordane was detected in 35% of the eggs.
Over 27% had heptachlor epoxide residues. Cis-chlordane was detected in 16%. Trans-nonachlor
was found in 25%, and cis-nonachlor was present in 6% of the eggs (Henny et al., 1984).
Ohlendorf et al. (1981) collected individuals of various species of herons nationwide and analyzed
them for organochlorines. Most of the birds were found either dead or moribund. The highest
concentration of heptachlor epoxide (1.9 ppm), oxychlordane (0.87 ppm), and trans-nonachlor (1.1
ppm in the brain) were found in a great blue heron that apparently died from dieldrin.
Residues of these contaminants were also detected in a high percentage of dead or dying ospreys
collected from the eastern United States from 1975 to 1985 (Wiemeyeret al. 1987). Cis-chlordane
was detected in 52% of the ospreys. Trans-nonachlor was detected in 45%. Concentrations of
oxychlordane and cis-nonachlor were found in 35% of the birds, while 13% had detectable levels
of heptachlor epoxide.
The State of New York proposed piscivorous wildlife dietary criteria for chlordane (0.5 ppm), and
for heptachlor epoxide (0.2 ppm) (Newell et al., 1987). These general criteria were established
based on existing studies with factors of uncertainty taken into account.
The effects of chlordane, oxychlordane, and heptachlor epoxide on piscivorous wildlife are
summarized in the following table:
C-38
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Effects of Chlordane* Concentrations on Piscivorous Wildlife
Animal
Concentration
Effecj
Source
Chlordane
Piscivorous
Wildlife 0.5 ppm (diet)
Estimated
NOEL
0.37 ppm (diet) cancer risk
-2
Newell etal., 1987
Newell etal., 1987
HfiDtachlor Eooxide
Birds 8 ppm (brain)
Piscivorous
Wildlife
0.2 ppm (diet)
of 10
death
Estimated
NOEL
0.21 ppm (diet) cancer risk
Qxvchlordane
Birds 5 ppm (brain)
'Chlordane, heptachlor epoxide, and oxychlordane
Of 10
death
-2
Stickel et al., 1979
Newell et al., 1987
Newell etal., 1987
Stickel et al., 1979
REFERENCES
Henny, C.J., LJ. Blus, A.J. Krynitsky, and C.M. Bunck. 1984. Current Impact of DDE on
Black-Crowned Night-Herons in the Intermountain West J. Wildl. Manage. 48(1) 1-13.
Khasawinah, A.M. 1982. Metabolism of Chlordane/Heptachlor in Animals. Prepared for the
Velsicol Chemical Corp., Chicago (unpubl.) (as cited in Newell et al., 1987).
Newell, A.J., D.W. Johnson, and L.K. Allen. 1987. Niagara River Biota Contamination Project:
Fish Flesh Criteria for Piscivorous Wildlife. Tech. Rep. 87-3. NY DepL Environ. Conserv., Div.
Fish Wildl., Bureau Environ. Protection.
Ohlendorf, H.M., D.M. Swineford, and L.N. Locke. 1981. Organochlorine Residues and Mortality
of Herons. Pest Monit. J. 14(4) 125-135.
C-39
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Stickel, L.F., W.H. Stickel, R.D. McArthur, and D.L. Hughes. 1979. Chlordane in Birds: A Study
of Lethal Residues and Loss Rates. In: Toxicology and Occupational Medicine, organizer W.B.
Deichman, Elsevier/North Holland, New York, NY.
U.S. EPA. 1980. Ambient Water Quality Criteria for Heptachlor. U.S. Environmental Protection
Agency, Washington, DC. EPA 440/5-80-052.
Wiemeyer, S. N., S.K. Schmeling, and A. Anderson. 1987. Environmental Pollutant and Necropsy
Data for Ospreys from the Eastern United States, 1975-1982. J. Wildl. Diseases 23(2) 279-291.
C-40
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CHLORPYRIFOS
CAS No.: 2921-88-2
CAS Preferred Nomenclature:
Phosphorothioic acid, 0,0-diethyl
o-(3,5,6-trichloro-2-pyridinyl) ester
Empirical Formula:
Synonyms and Common Names:
- Dursban - Eradex
- Lorsban - Pyrinex
- Brodan
a
C9H11CI3N03PS
REGULATORY STATUS
Standards and Criteria:
• EPA Water Quality Criteria (for human
consumption of fish):
None established at present
• EPA Ambient Water Quality Criteria
(for protection of aquatic organisms)
(U.S. EPA, 1986):
Freshwater Saltwater
Acute, ng/L 0.083 0.041
Chronic, \ig/L 0.041 0.0056
• EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restrictions and Bans:
EPA Drinking Water Health Ad-
visories:
None established at present
EPA Tolerance Levels (40 CFR
185.1000):
mint oil = 10 ppm
citrus oil = 25 ppm
other listed commodities = 0.05 to 5
ppm
Food and Drug Administration Action
Level for Fish:
None established at present
Current labeling states that it is not to be applied directly to water bodies (U.S. EPA,
1986).
Meat or dairy animals are not allowed to graze in treated orchards.
Treated seeds are not to be used for human consumption, as a feed for livestock or
poultry, or for grains to be used in making oils.
C-41
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SOURCES OF CHLORPYRIFOS
Total Chlorpyrifos Produced:
In 1982 about 3,500 tons were used as an insecticide (Green et ai., 1987).
• Developed during the 1960s by Dow Chemical (Midland, Michigan) to replace the more
persistent organochlorine pesticides (e.g., DDT)(SRI, 1986; U.S. EPA, 1986).
Uses of Chlorpyrifos;
• Chlorpyrifos is an organophosphate insecticide developed in the 1960s to replace the
environmentally persistent organochlorine pesticides (e.g., DDT).
• It has been used for a broad range of insecticidal applications, including mosquitoes,
flies, household pests, and aquatic larvae.
• Primarily, it is used to control soil and foliar insect pests on cotton, peanuts, and sorghum
(Worthing, 1983; U.S. EPA, 1986).
• Chlorpyrifos is also used to control root-infesting and boring insects on a variety of fruits
(e.g., citrus crops, apples, bananas, peaches, grapes, nectarines), nuts (e.g., almonds,
walnuts), vegetables (e.g., beans, broccoli, brussel sprouts, cauliflower, soybeans,
cabbage, peas) and field crops (e.g., alfalfa and corn)(U.S. EPA, 1984).
• As a household insecticide it has been used to control ants, cockroaches, fleas, and
mosquitoes (Worthing, 1983).
• Chlorpyrifos is registered for use in controlling subsurface termites in California (U.S.
EPA, 1983).
• It is also used to control ticks on cattle and sheep (Thomson, 1985).
Other Sources: None identified.
FATE IN ENVIRONMENT
Partitioning:
• Based upon its physical/chemical properties, Chlorpyrifos has a low volatility (H =
6.7x10 aim • m-vmol), and a moderate potential for bioaccumulation (BCF=470).
Chlorpyrifos is predicted to have an intermediate volatilization rate from surface soil
(P/S Koc = 6.9x 10" mm Hg • L/mg corresponding to an estimated volatilization half-life
of 23 days) (Lyman etaL, 1982).
C-42
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• Chlorpyrifos is hydrophobia (i.e., has an affinity for organic soils), rapidly sorbs to
suspended organics and sediments in aquatic systems (Kow= 128,800), and remains
stable for long periods of time (U.S. EPA, 1986).
• McCall (1986) reported intermediate soil/water partition coefficients (K$) of 50,66, and
100 for chlorpyrifos adsorbed to a loam soil (organic carbon 0.68 percent), a sandy loam
soil (organic carbon 1.1 percent), and a silt loam soil (organic carbon 2.0 percent),
respectively. In soil column studies, using 30-cm columns, approximately 5 percent of
the chlorpyrifos applied leached below the top 5 cm of loam soil, but less than 1 percent
leached below the top 5 cm of sandy loam and silt loam soils leached with 20 in. of water
at a rate of 1 ml/hr.
• Murphy and Lutenske (1986) reported a high steady state BCF of 1.4x10 for chlor-
pyrifos in rainbow trout.
Persistence;
• The hydrolysis half-life for chlorpyrifos in buffered, distilled water at 25°C was found
to be 22.8,35.3, and 62.7 days at pH 8.1,6.9, and 4.7, respectively; the rate was enhanced
16-fold in canal and pond water at 25°C (Verschueren, 1983). McCall (1986) reported
relatively long to intermediate hydrolysis half-lives (25°C) for chlorpyrifos of 72.8 days
at pH 5, 72.1 days at pH 7, and 15.8 days at pH 9. Hydrolysis products are 3,5,6-
trichloro-2-pyridinol and O-ethyl O-(3,5,6-trichloro-2-pyridyl) phosphorothioate.
Macalady and Wolfe (1985) observed hydrolysis half-lives ranging from 12 to 68 days
in pond and river water.
• Photolysis of chlorpyrifos can occur as evidenced by the following experimental data.
Fontaine and Teeter (1987) reported a relatively short half-life of 2.6 days for chlor-
pyrifos in air exposed to artificial light with a comparable but less intense irradiation
spectrum to that of sunlight Yackovich and Miller (1984) reported relatively short 50
percent dissipation times of 3 to 6 days for chlorpyrifos on loam soil irradiated with >290
nm artificial light compared to a 50 percent dissipation time of 12 days on loam soil
incubated in the dark.
• Bidlack (1979) reported intermediate to relatively long 50 percent dissipation times of
11 to 141 days (averaging 63 days) for chlorpyrifos incubated in 7 different soils under
aerobic conditions. McCall (1985a) reported a 50 percent dissipation time of 7 to 10
days for chlorpyrifos incubated in a sandy loam soil under aerobic conditions. Bidlack
(1979) reported 50 percent dissipation times of 15 and 58 days for chlorpyrifos incubated
under anaerobic conditions in a loam soil and in a clay soil, respectively.
C-43
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HEALTH EFFECTS
Carcinogenic! ty:
• Studies with rats, mice and dogs demonstrated no carcinogenicity (U.S. EPA, 1983).
Mutagenic Activity:
• Bacterial mutagenicity tests were negative {U.S. EPA, 1983).
Reproductive Effects:
• No teratogenic or fetotoxic effects in mice or rats (IRIS, 1989).
Other Toxkological Effects;
• Chlorpyrifos, in a manner similar to other organophosphate pesticides, interferes with
the nerve-muscle relationship by inhibiting the enzyme cholinesterase. Without
cholinesterase, the neurotransmitter acetylcholine accumulates at nerve-muscle junc-
tions and interferes with muscle coordination (Green et al., 1986; U.S. EPA, 1986).
• Acute (high-dose, short-term) poisoning can produce a variety of symptoms including
weakness, blurred vision, nausea, diarrhea, wheezing, tremors, psychosis, convulsions,
paralysis, coma, and death (Klaassen et al., 1986; U.S. EPA, 1983, 1986).
• It is rapidly detoxified in rats and dogs (Worthing, 1983).
Toxicological Effects Indices:
• Reference Dose (RfD): 3 x 10~3 mg/kg/day (IRIS, 1989).
• TWA-TLV (time-weighted average, threshold limit value) for occupational skin ex-
posure: 0.2 mg/m3 (ACGIH, 1986).
• Oral LDso: rats, 82-245 mg/kg (U.S. EPA, 1983).
C-44
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
351
solid, white
granules
42-43.5
N/A
1.398@43.5°C
(liquid)
N/A
2 (25°C)
1.87xlO'5(25°C)
U.S. EPA, 1983
Farm Chemicals
Handbook, 1987
Hartley & Kidd, 1983
Verschueren, 1983
Hartley & Kidd, 1983
McCalletal., 1983
Henry's Law Constant,
H@ 25°C(atm.m/mol):
Log (Octanol-Water Partition
Coefficient), log KOW:
Soil Adsorption Coefficient, Koc(mL/g):
Fish Bioconcentration
Factor, BCF:
6.7x10'°
5.11
13,600
470
450 (exptl.)
McCall et al., 1983
Leo,1983
Kenaga, 1980
McCalletal., 1983;
Kenaga, 1980
C-45
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Bidlack. H.D. 1979. Degradation of Chlorpyrifos in Soil Under Aerobic, Aerobic/Anaerobic, and
Anaerobic Conditions. Dow Chemical Co. Asc. #256041.
Farm Chemicals Handbook. 1987. Meister Publishing Co., Willoughby, OH.
Fontaine, D.D., and D. Teeter. 1987. Photodegradation of Chlorpyrifos in the Vapor Phase. Report
#GH-C-1911. Dow Chemical Co. and ABC Laboratories.
Green, M.B., G.S. Hartley, and T.F. West. 1987. Chemicals for Crop Improvement and Pest
Management. 3rd ed. Pergamon Press, Oxford, England.
Hartley, D. and H. Kidd, eds. 1983. The Agrochemicals Handbook. The Royal Society of
Chemistry, Nottingham, England.
IRJS. 1989. Integrated Risk Information System. U.S. Environmental Protection Agency,
Washington, DC.
Kenaga, E.E. 1980. Correlation of Bioconcentration Factors of Chemicals in Aquatic and Ter-
restrial Organisms With Their Physical and Chemical Properties. Environ. Sci. Technol. 14:553-
556.
Klaassen C.D., M.D. Amdur, and J. Doull, eds. 1986. Casarett and DoulTs Toxicology. The Basic
Science of Poisons. 3rd ed. Macmillan Publishing Co., New York.
Leo, A.J. 1983. Log P Parameter Database, Issue #24 (dated Dec. 16, 1983). Obtained from the
Medchem Project, Pomona College, Claremont, CA.
Lyman, W.J., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods. McGraw-Hill Book Co.
Macalady, D.L., and N.L. Wolfe. 1985. Effects of Sediments Sorption and Abiotic Hydrolysis. 1.
Organophosphorothionate Esters. J. Agric. Food Chem. 33(2):167-173.
McCall, P.J. 1985a. Column Leaching and Sorption Studies with Chlorpyrifos. Report GH-C-
1977. Dow Chemical Co. Ace. No. 260794.
McCall, PJ. 1985b. Chlorpyrifos Aged Column Leaching. Report GH-C-1778. Dow Chemical
Co.
McCall, PJ. 1986. Hydrolysis of Chlorpyrifos in Dilute Aqueous Solution. Report GH-C-1791.
C-46
-------
McCall, P.R.,etaL, 1983. Estimation of Environmental Partitioning or Organic Chemicals in Model
Ecosystems. Residue Reviews. 85:231-244.
Murphy, P.O., and N.E. Lutenske. 1986. Bioconcentration of Chlorpyrifos in Rainbow Trout.
Project #ES-928. Dow Chemical Co. Ace. No. 400564-01.
SRI (Stanford Research Institute). 1986. Directory of Chemical Producers. Stanford Research
Institute, Menlo Park, CA.
Thomson, W.T. 1985. Agricultural Chemicals. Book I - Insecticide. 1985 revision.
U.S. EPA. 1983. Analysis of the Risks and Benefits of Seven Chemicals Used for Subterranean
Termite Control. U.S. Environmental Protection Agency. EPA-540/9-83-005.
U.S. EPA. 1984. Registration Standard for Chlorpyrifos. U.S. Environmental Protection Agency,
Office of Pesticides, Washington, DC.
U.S. EPA. 1986. Ambient Water Quality Criteria for Chlorpyrifos. U.S. Environmental Protection
Agency, Washington, DC. EPA-440/5-86-005.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Worthing, C.R., ed. 1983. The Pesticide Manual: A world compendium. 7th ed. British Crop
Protection Council, Croydon, England.
Yackovich, P.R., and J.H. Miller. 1984. Photodegradation of Chlorpyrifos on Commerce Soil
Surface. Dow Chemical Co.
C-47
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C-48
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p,p -DDE
CAS No.: 72-55-9
CAS Preferred Nomenclature:
Benzene, l,l'-(dichloroethenylidene)
bis (4-chloro-
Empirical Formula: CuHgCU
Synonyms and Common Names:
- 4,4'-DDE
- p,pF128Md-Dichlorodiphenyl dichloroethylene
- 1 ,l-Dichloro-2,2-bis (p-chlorophenyl) - ethylene
CUH8C14
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for human
consumption of fish) for a 10 com-
bined (DDT and DDE) cancer risk
(U.S. EPA, 1980):
0.024 ng/L
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms)
DDT, TDE and DDE combined (U.S.
EPA, 1980):
Freshwater Saltwater
Acute, fig/L ' ' ' "~1A*1
1.1
Chronic,M \ig/L 1.0x10
,-3
1.3x10*
1.0x10
-3
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
EPA Drinking Water Health Ad-
visories:
None established at present
Food and Drug Administration Action
Level for Fish, combined (DDT, TDE
and DDE) (55 FR 14361):
5*ppm
• Food and Drug Administration Action
Levels for Other Foods:
0.05 to 3* ppm
* FDA Action Levels are for use in inter-
state commerce
Use Restrictions and Bans: Not produced commercially.
C-49
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SOURCES OF DDE
Total DDE Produced:
• DDE is a metabolic breakdown product of the insecticide DDT. DDT was first
synthesized in 1874 and was used as an insecticide starting in 1939. By 1961, 1,200
formulations were available for use on 334 crops. Peak production was 180 million
pounds in 1963 (McEwen and Stephenson, 1979).
DDE was initially synthesized by German researchers during World War II. Production
data are not available, but presently the only production may be for use as a laboratory
standard (McEwen and Stephenson, 1979).
Uses of DDE:
• Unlike its parent compound, DDE has no insecticidal properties (McEwen and Stephen-
son, 1979).
• Military use only (Verschueren, 1983).
Other Sources:
• DDT is no longer used in the U.S. It was a widely-used insecticide on a variety of crops
and was also used for the control of insect-borne diseases (e.g., mosquitoes carrying
malaria). DDT was banned because it was shown to be carcinogenic and also more than
150 species of insects developed resistance to it DDE is formed by the degradation of
DDT by loss of one molecule of hydrochloric acid. DDE further degrades to DDA by
loss of two more molecules of HC1 (Farm Chemicals Handbook, 1985).
FATE IN ENVIRONMENT
Partitioning:
• Based on its physical/chemical properties, p,p'-DDE is moderately volatile (H=6.8x 10
atm • m /mole), very strongly sorbed to soil (Kow = 1.0x10" ), and has a high potential
for bioaccumulation (BCF was determined by experiment to be 1.8x10 ).
Persistence:
Direct photolysis of p,p'-DDE in water has been reported in laboratory experiments by
Zepp et al. (1976,1977) and in aquatic environments by Singmaster (1975). A quantum
yield of 0.3 was measured by Zepp et al. at a wavelength of 313 nm. This results in
estimated half-lives at 40° latitude of 0.9 days in summer to 6.1 days in winter.
C-50
-------
p,p'-DDE is the hydrolysis breakdown product of DDT. DDE, itself, was found to be
stable with respect of hydrolysis (half-life of more than 120 years at pH 5 and 27°C).
DDE is biodegraded very slowly, if at all, in aquatic environments (Callahan et al., 1979).
HEALTH EFFECTS
Carcinogenicity:
Liver tumors (hepatocellular carcinomas) observed in mice, but not in rats. IARC
Classification - 2b. (IARC, 1973; Sax, 1984; HSDB, 1988).
The U.S. EPA has classified DDE as a probable human carcinogen (B2) and is presently
reviewing experimental data in order to determine a cancer potency factor (PHRED,
1988).
Mutagenic Activity:
• Not mutagenic in bacterial assays, but weakly mutagenic in mouse lymphocytes and
cytogenetic analysis in rats (Sax, 1984; HSDB, 1988).
Reproductive Effects:
• No data located on teratogenicity of DDE, but did not adversely affect lactation or
neonatal growth at maternal daily doses of 10 mg/kg (HSDB, 1988).
Other ToxJcological Effects;
• Causes liver damage in rats (Sax, 1984).
Toxicologies! Effects Indices;
• Cancer Potency Factor (CPF): 3.4xlO*1 (rag/kg/day)"1 (IRIS, 1989).
• Oral LDso: rat, 880-1240 mg/kg (Sax, 1984).
C-51
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant,
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H @ 25°C (atm. m3/mol):
Log (Octanol-Water Partition
Coefficient), log KOW:
318.0
solid
88-90
N/A
N/A
N/A
0.04 (20°C)
6.5x10'6(20°C)
6.8x10
7.00
-5
Soil Adsorption Coefficient, Koc(mL/g): 4.4x10
Fish Bioconcentration
Factor, BCF:
(exptl.)
53,600 (calc)
Callahanetal., 1979
Cailahan et al., 1979
Callahanetal., 1979
PHRED, 1988
PHRED, 1983;
Mabeyetal., 1982
PHRED, 1988;
Mabeyetal., 1982
Verschueren, 1983;
PHRED, 1988;
Lymanetal., 1982
C-52
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REFERENCES
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979. Water-Related
Environmental Fate of 129 Priority Pollutants, Vol I. U.S. Environmental Protection Agency,
Office of Water Planning and Standards. EPA-440/4-79-029a.
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
HSDB. 1988. Hazardous Substances Data Base Computer Printout: p,p'-DDE. Retrieved May
16, 1988. National Library of Medicine, Bethesda, MD.
IARC (International Agency for Research on Cancer). 1973. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 5. IARC, Lyon, France.
IRIS. 1989. Integrated Risk Information System. U.S. Environmental Protection Agency,
Washington, DC.
Lyman, W.J., ed. 1982. Handbook of Chemical Property Estimation Methods. McGraw-Hill, New
York.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, J.W. Partridge,
H. Jaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority Pollutants.
SRI International. EPA 440/4-81-014.
McEwen, F.L., and G.R. Stephenson. 1979. The Use and Significance of Pesticides in the
Environment. John Wiley and Sons, Inc., New York.
PHRED. 1988. Public Health Risk Evaluation Database. U.S. Environmental Protection Agency,
Office of Emergency and Remedial Response, Washington, DC.
Sax, N.I. 1984. Dangerous Properties of Industrial Materials. 6th ed. VanNostrandReinholdCo.,
New York.
Singmaster, J.A., HI. 1975. Environmental Behavior of Hydrophobic Pollutants in Aqueous
Solutions. Ph.D. thesis, University of California, Davis, CA. University of Microfilms, Ann Arbor,
MI, Order No. 76-14,237. (Diss. Abstr. Int. B 1976,36(12, Pt. 1):6206-6207.
U.S. EPA. 1980. Ambient Water Quality Criteria for DDT. U.S. Environmental Protection
Agency, Office of Water Regulations and Standards, Washington, DC.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 1 2nd ed. Van
Nostrand Reinhold, New York.
C-53
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Zepp, R.G., N.L. Wolfe, J.A. Gordon, and R.C. Fincher. 1976. Light-Induced Transformations of
Methoxychlor in Aquatic Systems. J. Agric. Food Chem. 24(4):727-733.
Zepp, R.G., N.L. Wolfe, L.V. Azarraga, R.H. Coz, and C.W. Pape. 1977. Photochemical Trans-
formation of the DDT and Methoxychlor Degradation Products, DDE and DMDE, by sunlight.
Arch. Environ. Contam. Toxicol. 6:305-314.
C-54
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DDE
OBSERVATIONS AND EFFECTS ON PISCIVOROUS WILDLIFE
The use of the insecticide DDT was severely restricted in the United States in 1972. However, the
long-lived DDT and its metabolite, DDE, are still present in the tissue and eggs of many fish-eating
birds.
The concentration of DDE residue in avian eggs is negatively correlated with reproductive success.
A study of black-crowned night herons from 1978 to 1980, determined that residues greater than
1.0 ppm reduce eggshell thickness, and levels greater than 8.0 ppm reduce the percentage of
successful nests and clutch size and increase the percentage of cracked eggs (Henny et al., 1984).
Almost 11 percent of eggs collected from night herons in San Francisco Bay in 1982 had
concentrations of DDE above 8.0 pmm (Ohlendorf et al., 1988).
For the sensitive brown pelican, a concentration greater than 0.5 ppm in eggs was estimated to cause
eggshell thinning (Blus, 1972; Blus et al., 1971). From these data, the EPA in 1976 estimated a
NOEL for the eggs of the brown pelican at 2.0 ppm, with a corresponding dietary NOEL of 0.2 ppm
(Newell et al., 1987). More recently, the State of New York has also proposed a fish flesh criterion
of 0.2 ppm DDE to protect all piscivorous wildlife (Newell et al., 1987).
DDE residues in eggs at concentrations high enough to affect reproductive success were observed
in herring gull eggs from the Great Lakes between 1974 and 1978 (mean of 21 ppm for a Lake
Ontario colony in 1974) (Weseloh et al., 1979). In Maine, differences in DDE concentrations
observed between the common eider, herring gull, and black-backed gull were attributed to
differences in feeding habits (Szaro et al., 1979). The highest concentrations (mean of 8.66 ppm)
were detected in the eggs of black-backed gulls, which are piscivorous and have also been observed
to eat carrion of marine mammals. The common eider, with the lowest concentrations (mean of
0.23 ppm), feeds primarily on marine invertebrates.
DDE has also been detected in high concentrations (2.9 ppm) in eggs from the American crocodile
in the Florida Everglades (Hall et al., 1979).
In birds, the lethal effect of DDE in the brain is estimated to be about 250 ppm (as cited in Ohlendorf
et al., 1981). Although DDE is often present in the brains of piscivorous birds, it is seldom found
at levels considered lethal.
Dead or moribund bald eagles were collected nationwide from 1971 to 1974 and analyzed for
organochlorine residues. Of the 101 specimens analyzed, DDE was detected in 97 percent of the
brains. However, only one death could possibly be attributed to DDE (230 ppm) (Barbehenn and
Reichel, 1981).
In 1969 and 1973 in southern Ontario, ring-billed gulls found dead of no apparent disease were
analyzed for organochlorines. Most had DDE residues in the brain, although a lethal level was
detected in only one specimen (Stickel et al., 1984).
C-55
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Of 12 adult black-crowned night herons found dead in 1980 and 1981 in Nevada, all had DDE
residues in the brain. Only one dead immature heron collected did not have a detectable DDE
residue in the brain (Henny et al., 1984).
The effects of DDE on piscivorous wildlife are summarized in the following table:
Effects of DDE Concentrations on Piscivorous Wildlife
Animal
Birds
Brown
Pelican
Brown
Pelican
Brown
Pelican
Black-crowned
Night-heron
Piscivorous
Wildlife
Concentration
250 ppm (brain)
>0.5 ppm (egg)
>2.0 ppm (egg)
>0.2ppm (diet)
1.0 ppm (egg)
8.0 ppm (egg)
0.2 ppm (diet)
0.226 ppm
(diet)
Effect
death
eggshell
thinning
eggshell
eggshell
thinning
eggshell
thinning
reduced
clutch size
reduced percentage
of successful
nests
increased percentage
of cracked
eggs
estimated
NOEL
cancer risk
of 10'2
Source
Ohlendorf, 1981
Blus, 1972;
Blusetal.,1971
U.S. EPA, 1976
U.S. EPA, 1976
Henny etal., 1984
Henny et al., 1984
Newell etal. ,1987
Newell etal., 1987
C-56
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REFERENCES
Barbehenn, K.R., and W.L. Reichel. 1981. Organochlorine Concentrations in Bald Eagles:
Brain/Body Lipid Relations and Hazard Evaluation. J. Toxicol. Environ. Health. 8:325-330.
Blus, L. 1972. Further Analysis of the Logarithmic Relationship of DDE Residues to Nest Success.
Nature 240: 164. (As cited in Newell et al., 1987).
Blus, L.J., R. Heath, C. Gish, A. Belisle, and R. Prouty. 1971. Eggshell Thinning in the Brown
Pelican: Implication of DDE. Bioscience 21: 1213-1215. (As cited in Newell et al., 1987).
Hall, R. J., T. E. Kaiser, W. B. Robertson, Jr., and P.C. Patty. 1979. Organochlorine Residues in
Eggs of the Endangered American Crocodile (Crocodylus acutus). Bull. Environ. Contam. Toxicol.
23:87-90.
Henny, C. J., L. J. Blus, A. J. Krynitsky, and C. M. Bunck. 1984. Current Impact of DDE on
Black-Crowned Night-Herons in the Intermountain West. J. Wildl. Manage. 48(1): 1-13.
Newell, A. J., D.W. Johnson, and L.K. Allen. 1987. Niagara River Biota Contamination Project:
Fish Flesh Criteria for Piscivorous Wildlife. Tech. Rep. 87-3. NY Dept. Environ. Conserv., Div.
Fish Wildl., Bureau Environ. Protection.
Ohlendorf, H.M., T.in. Custer, R.W. Lowe, M. Rigney, and E. Cromartie. 1988. Organochlorines
and Mercury in Eggs of Coastal Terns and Herons in California, USA. Colon. Waterbirds
Ohlendorf, K.M., D.M. Swineford, and L.N. Locke. 1981. Organochlorine Residues and Mortality
of Herons. Pest. Monit. J. 14(4)125-135.
Stickel, U.K., L.F. Stickel, R.A. Dyrland and D.L.Hughes. 1984. Aroclor 1254 Residues in Birds:
Lethal Levels and Loss Rates. Arch. Environ. Contam. Toxicol. 13:7-13.
Szaro, R. C., N. C. Coon, and E. Kolbe. 1979. Pesticide and PCB of Common Eider, Herring Gull
and Great Black-Backed Gull Eggs. Bull. Environm. Contam. Toxicol. 22:394-399.
U.S. EPA. 1976. Quality Criteria for Water. U.S. Environmental Protection Agency, Washington,
DC. EPA 440/9-76-023. (As cited in Newell et al., 1987).
Weseloh, D.V., P. Mineau, and D.J. Hallett. 1979. Organochlorine Contaminants and Trends in
Reproduction in Great Lakes Herring Gulls, 1974-1978. Trans. N. Am. Wildl. Nat. Resour. Conf.
44:543-557.
C-57
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C-58
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DICOFOL
CAS No.: 115-32-2
CAS Preferred Nomenclature:
Benzenemethanol, 4-chloro-. alpha.
-(4-chlorophenyl)-.alpha.-
(trichloromethyl)-
Empirical Formula:
Synonyms and Common Names:
- Kelthane - Carbax
- Mitigan - CPCA
- Acarin - Decofol
REGULATORY STATUS
Standards and Criteria:
• EPA Water Quality Criteria (for human
consumption of fish):
None established at present
• EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
• EPA Drinking Water Health Ad-
visories:
None established at present
• EPA Tolerance Levels for Food (21
CFR 193.80; 40 CFR 185.410):
dried tea = 45 ppm
hops = 30 ppm
cottonseed = 0.1 ppm
other foods = 5-10 ppm
• Food and Drug Administration Action
Level for Fish:
None established at present
Use Restrictions and Bans:
Effective December 31,1988, all uses to be cancelled unless registered formulas contain
less than 0.1% DDT and related contaminants (51 FR 19508).
C-59
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SOURCES OF DICOFOL
Total Dicofol Produced:
• Dicofol is a pesticide structurally similar to DDT which was introduced in 1957.
Technical-grade dicofol is a brown viscous oil.
• Recent use in the U.S. is 2 to 3 million pounds per year (Holder, 1986). Dicofol is
produced by Rohm and Haas, Inc. and Makhteshim-Agan, Inc. (51 FR 19509).
Uses of Dicofol:
• Used primarily (60%) to control mites on cotton and citrus. Other major uses include
the control of mites on apples (10%) and on ornamental plants and turf (10%) (51 FR
19515).
• Another 20% is used for the control of mites on a variety of other agricultural products
including:
- pears, apricots and cherries (51 FR 19515; Farm Chemicals Handbook, 1985)
- seed crop soil treatment
- vegetables (e.g., beans and corn)
- shade trees (U.S. EPA, 1986).
Other Sources: None found.
FATE IN ENVIRONMENT
Partitioning:
• Based on its physical/chemical properties, dicofol is predicted to be essentially non-
volatile in water (H = 3.5x 10"9 atm • m3/mol) and from soil surfaces (P/SKoc = 4.8x 10"14
mmHg'L/mg). It is very strongly sorbed to soil and sediment (Kow =1,148,000),
and has a high potential for bioaccumulation (BCF = 5.5xl04) (Lyman et al., 1982).
• Fisher (1975) reported that dicofol and its aerobic soil breakdown products were
relatively immobile in a column experiment using sandy loam soil. Approximately 93%
of radioactivity applied as 14C-dicofol and >99% of the total radioactivity accounted
for remained in the upper 2 inches of a sandy loam soil column after 30 days of aerobic
aging followed by 44 days of leaching with water at a rate of 0.5 in/day.
• Tillman (1986) reported a maximum non-steady-state, whole-body BCF of 1.0 x 10
and an estimated steady-state whole-body BCF >2.5 x 104 for bluegill sunfish exposed
to 0.006 ppm dicofol for 28 days.
C-60
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Persistence:
• Dicofol can hydrolyze with the rate increasing as pH increases. For example, Warren
(1986) reported hydrolysis half-lives for dicofol (at 25°C) of 85 days at pH 5, 64 hours
at pH 7, and 26 minutes at pH 9. The half-life for dicofol hydrolysis in distilled water
at pH 8.2 was found to be 1 hour; in filtered river water at pH 7.5, roughly 90%
conversion of dicofol to 4,4'-dichlorobenzophenone occurred in 24 hours, though
dicofol recovery was poor (Walsh and Hites, 1979).
• The photolysis half-life for dicofol was found to be 144 hours in one study using thin
films (TDB, 1985). However, studies using water and soil solutions reported longer
half-lives. For example, Carpenter (1986a) reported a relatively long photodegradative
half-life of >37 days for dicofol in water exposed to artificial light with wavelengths >
290 nm. Carpenter (1986b) reported an intermediate photodegradative half-life between
21 and 30 days for dicofol adsorbed to a silt loam soil when exposed to these same
conditions. Dicofol appears to be poorly metabolized by microbes in aerobic soil
systems (Walsh and Hites, 1979). It has been found to undergo degradation in anaerobic
sewage sludge, however (Verschueren, 1983).
HEALTH EFFECTS
Carcinogeni city:
• Technical-grade dicofol (containing an undetermined level of DDT) induced hepatocel-
lular (liver) carcinomas in male mice. Results were negative in female mice as well as
in rats (NCI, 1978).
• Dicofol is classified by the U.S. EPA as a possible human carcinogen (Class C) with
only limited animal evidence supporting the classification (Holder, 1986).
• Because it is structurally related to DDT and there is a large data base supporting the
carcinogenicity of DDT, it has been suggested that difocol be classified somewhere
between C and B2 (as a probable human carcinogen). Further study is necessary to
determine the correct classification (Holder, 1986).
Mutagenic Activity:
• Additional studies need to be done to determine whether dicofol causes mutagenic
effects (Holder, 1986).
• Negative results were reported for induction of chromosomal aberrations in Chinese
hamster lung cells and for bacterial tests (IARC, 1983).
• Positive results were noted in a micronucleus test with rat bone marrow cells (IARC,
1983).
C-61
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Reproductive Effects:
• In a multi-generation mouse study there were no effects on reproduction or fetal
development (IARC, 1983).
• With rats, dicofol influenced only early (pre-implantation) embryo development (IARC,
1983).
Other lexicological Effects;
• Although no symptoms of toxicity were demonstrated in dogs fed 300 ppm for one year,
two of the four test animals died before completion of the experiment (Clayton and
Clayton, 1981).
• Report of possible suppression of adrenal function (Clayton and Clayton, 1981).
Toxicological Effects Indices:
• Estimated cancer potency factor (CPF): = 0.44 (mg/kg/day)"1 (Holder, 1986).
• The U.S. EPA Carcinogen Assessment Group recommends the use of a CPF of 0.34
(mg/kg/day)"1 for any combination of dicofol, DDT, DDE, and ODD (Holder, 1986).
• Occupational exposure to DDT should be limited to 1 mg/m3 (ACGIH, 1986).
• Oral LDso: rats, between 575 and 1,000 mg/kg (McEwen and Stephenson, 1979;
Worthing, 1983; Matsumura, 1985).
C-62
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PHYSiqAL/CHEMICAL PROPERTIES
Value
Reference
Molecular weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H
@ 25°C (atm • m3/mol):
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc (mL/g):
Fish Bioconcentration Factor, BCF:
370.5
Colorless solid;
technical grade,
brown viscous oil
78.5-79.5
180 @ 0.098mm Hg
technical grade,
1.45 @ 25°C
N/A
0.8 (20°C)
5.8xlO'9(calc.)
3.5xlO"9 (calc.)
6.06 (calc.)
1.5xl05(caic.)
5.5xl04 (calc.)
1.0xl04to>2.5xl04(est.)
Sax, 1984
Kirk-Othmer, 1984;
Matsumura, 1985
Hartley & Kidd, 1983
Hartley & Kidd, 1983
Hartley & Kidd, 1983
Verschueren, 1983
Lyman et al, 1982
Lymanetal., 1982
Lyman etal., 1982
Lyman et al., 1982
Lyman et al., 1982
Tillman, 1986
C-63
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Carpenter, M. 1986a. Aqueous Photolysis of 14C-p,p'-dicofol (Kelthane). Prepared by Analytical
Bio-Chemistry Laboratories for Rohm and Haas. TR No. 310-86-58.
Carpenter, M. 1986b. Photodegradation of 14C-p,p'-dicofol on the Surface of Soil. Prepared by
Analytical Bio-Chemistry Laboratories for Rohm and Haas. TR No. 310-86-58.
Clayton, G.D., and F.E. Clayton, eds. 1981-82. Patty's Industrial Hygiene and Toxicology. 3rd
rev. ed.. Vol. 2A, 2B, 2C, Toxicology. John Wiley and Sons, New York.
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Fisher, J.D. 1975. Laboratory Leaching Study With Soil-aged Kelthane. Rohm and Haas Co. Tech.
Report No. 3423-75-50.
Hartley, D., and H. Kidd, eds. 1983. The Agrochemicals Handbook. The Royal Society of
Chemistry, Nottingham, England.
Holder, J.W. 1986. The Assessment of the Carcinogenicity of Dicofol (Kelthane), DDT, DDE and
DDD (TDE). U.S. Environmental Protection Agency, Carcinogen Assessment Group. EPA/600/6-
86/001.
IARC (International Agency for Research on Cancer). 1983. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 30. IARC, Lyon, France.
Kirk-Othmer Encyclopedia of Chemical Technology. 1984. 3rd. ed. John Wiley and Sons, Inc.,
New York.
Lyman, W.L., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods. McGraw-Hill Book, Co., New York.
Matsumura, F. 1985. Toxicology of Insecticides. Plenum Press, New York.
McEwen, F.L., and G.R. Stephenson. 1979. The Use and Significance of Pesticides in the
Environment John Wiley and Sons, Inc., New York.
NCI (National Cancer Institute). 1978. Bioassay of Dicofol for Possible Carcinogenicity. NCI
Carcinogenesis Technical Report Series, No. 90.
Sax, N.I. 1984. Dangerous Properties of Industrial Materials. 6th ed. VanNostrandReinhoIdCo.,
New York.
C-64
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Tillman, A.M. 1986. The Bioconcentration, Elimination, and Metabolism of 14C-Dicofol by
Bluegill Sunfish (Lepomis rnachrochirus). Rohm and Haas Co. Report No. 310-86-17.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine's MEDLARS system, National Library of Medicine, TDB Peer Review Committee.
U.S. EPA. 1983. Guidance for the Reregistration of Pesticide Products Containing Dicofol as the
Active Ingredient. 540-RS-83-003.
U.S. EPA. 1985. Suspended, Cancelled, and Restricted Pesticides. U.S. Environmental Protection
Agency, Office of Pesticides and Toxic Substances, Washington, DC.
U.S. EPA. 1986. Computer retrieval from Office of Pesticides for registered sites and number of
products registered.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Walsh, P.R. and R.A. Hites. 1979. Dicofol Solubility and Hydrolysis in Water. Bull. Environ.
Contam. Toxicol. 22:305-311.
Warren, J. 1986. Hydrolysis of 14C-p,p'-dicofol (Kelthane). Prepared by Analytical Bio-
Chemistry Laboratories for Rohm and Haas. Report No. 310-86-41.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British Crop
Protection Council, Croydon, England.
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C-66
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DIELDRIN
CAS No.: 60-57-1
CAS Preferred Nomenclature:
2, 7:3,6-Dimethanonaphth(2,3b)oxirene,
3,4,5,6,9,9-hexachloro-la,2,2af3,6,6a,7,7,7a-
octahydro-,(la ,2 0,2 a,3p , 6p , 6aa
Empirical Formula: C i2HgC leO
Synonyms and Common Names:
-Dieldrex - Illoxol
-HEOD - Octalox
,7a
C!
C) IH-C-Hp-C-CIl
Cl
C!
H
Cl
REGULATORY STATUS
Standards and Criteria;
• EPA Water Quality Criteria (for human
consumption of fish) for a 10"6 cancer
risk (50 FR 79318):
0.076 mg/L
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms)
(U.S. EPA, 1980):
Freshwater Saltwater
Acute, |ig/L 2.5 0.71
Chronic, ng/L 0.0019 0.0019
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
EPA Drinking Water Health Ad-
visories (U.S. EPA, 1988; ATSDR,
1987):
cllildUOkg):
1-day, 10-day, longer-term
exposures = 0.5 jig/L
adjjll (7kg):
longer-term exposure = 2 ng/L
Food and Drug Administration Action
Level for Fish, total aldrin and dieldrin
(55 FR 14361):
0.3* ppm
• Food and Drug Administration Action
Levels for Other Foods (55 FR 14361):
0.02 - 0.3* ppm
* FDA Action Levels are for use in
interstate commerce
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Use Restrictions and Bans:
• Suspension of uses on food products in 1974 (ATSDR, 1987).
• All uses banned in 1985 except for subsurface termite control, dipping of nonfood roots
and tops, and moth proofing in a closed system by manufacturing processes (U.S. EPA,
1985). These uses have been voluntarily cancelled by industry (ATSDR, 1987).
SOURCES OF DIELDRIN
Total Dieldrin Produced:
• In 1970 about 670,000 pounds were used. Dieldrin is no longer produced in the U.S.
Until 1985, products containing dieldrin were imported from Europe. None have been
imported since then.
Uses of Dieldrin:
• Dieldrin is an organochlorine pesticide that was widely used from 1950 to 1974 for
controlling soil-dwelling insects, especially termites, on cotton, corn, and citrus crops.
• Uses prior to 1974 included the following (Worthing, 1983):
- Control of locusts
- Control of tropical disease carriers (e.g., mosquitoes)
- Wood preservative
- Termite control for electrical cables and buildings
- Moth proofing woolen clothes and carpets.
Other Sources:
• Breakdown product (by oxidation) of the pesticide aldrin (Verschueren, 1983)
FATE IN ENVIRONMENT
Partitioning;
• Based on its physical/chemical properties, dieldrin has a low volatility (H = 2x10"
atm • ra3/mol), sorbs readily to soil organic matter (Kow = 20,890), and has a high
potential for bioaccumulation (BCF = 4,670).
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Persistence:
• Dieldrin can undergo hydrolysis under neutral pH conditions (Kn = 7.5x 10"6/mole/hr),
but the half-life is long (10.5 years) (Ellington, et al., 1986). Direct photolysis of dieldrin
can also occur; the half life is about 2 months (Callahan, et al., 1979).
• Dieldrin can be biotransformed very slowly by soil microbes to an epoxide that is more
toxic to some insects than the parent compound. Further degradation results in the
ketone-aldrin, an aldehyde and alcohols (Morrill et al., 1982). Under aerobic conditions,
dieldrin can be degraded to 6,7-trans-dihydroxydihydroaldrin (Kirk-Othmer, 1978).
HEALTH EFFECTS
Carcinogenic) ty:
• Dieldrin has caused liver carcinoma in feeding studies (oral administration) with five
strains of male and female mice (50 FR 10080). The EPA has classified dieldrin as a
B2, probable human carcinogen, IARC classification 2b. (LARC, 1982; PHRED, 1988):
Mutagenic Activity:
• Mutagenic in human lung cells in culture. Interferes with metabolic cooperation in
cultured cells (i.e., it promotes mutagenic activity). Negative in mouse dominant lethal
test, Salmonella, yeast and Drosophila (fruit flies). Inconclusive data on chromosome
damage to mouse bone marrow cells (IARC, 1982).
Reproductive Effects:
In hamsters, high doses of dieldrin exposure resulted in fetal deaths, congenital defects
and retarded growth (Proctor and Hughes, 1978).
• Decreased fertility in rats and mice; increased postnatal mortality in rats (ATSDR, 1987).
Other Toxicological Effects:
• Identified as a neurotoxin (Clayton and Clayton, 1981). The acute affects can include:
headache, dizziness, hyperexcitability, tremors, convulsions, depression and death
(ATSDR, 1987).
• Chronic effects: damage to liver in rats, dogs, and hamsters, also evidence of suppressed
immune systems (Gosselin et al., 1984).
• Low levels decreased learning capabilities in monkeys (50 FR 10080).
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Toxicological Effects Indices:
• Cancer potency factor (CPF): 16 (mg/kg/day)"1 (U.S. EPA, 1987a).
• Reference Dose (RfD): 5xlO"5 mg/kg/day (U.S. EPA, 1987b).
TLV-TWA (time-weighted average, threshold limit value) for occupational skin ex-
posure: 0.25 mg/m3 (ACGIH, 1986).
« LDso in humans, approximately 5 mg/kg (ATSDR, 1987).
• Oral LDso: rats, 46 mg/kg (Sax, 1984).
• Tolerance levels for agricultural commodities: 0 to 0.1 ppm (ATSDR, 1987).
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H @ 25°C (atm • m3/mol):
Hydrolysis, Kn, L/mol/hr
Log (Octanol-Water Partition
Coefficient), log KOW:
Soil Adsorption Coefficient,
Koc(mL/g):
Fish Bioconcentration Factor, BCF:
380.9
solid; buff to light
tan flakes; mild odor
175-176
N/A
1.75
N/A
0.186 (20°C)
2xlO'7 (20°C)
7.5x10"*
4.32
1700
4670
Windholz, 1983
Worthing, 1983
Callahan et al., 1979
Verschueren, 1983
Callahan et al., 1979
Callahan et al., 1979
U.S. EPA, 1986b
Ellington etal.,
1986
Leo,1983
Mabey et al.. 1982
U.S. EPA, 1980
C-7I
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
ATSDR (Agency for Toxic Substances and Disease Registry). 1987. Draft Toxicological Profile
for Aldrin/Dieldrin. ATSDR, U.S. Public Health Service.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979. Water-Related
Environmental Fate of 129 Priority Pollutants, Vol. I. Office of Water Planning and Standards,
U.S. Environmental Protection Agency, Washington, DC. EPA-440/4-79-029a.
Clayton, G.D., and F.E. Clayton, eds. 1981-82. Patty's Industrial Hygiene and Toxicology. 3rd
rev. ed., Vol. 2A, 2B, 2C, Toxicology. John Wiley and Sons, Inc., New York.
Ellington, J.J., F.E. Stancil, Jr. and W.D. Payne. 1986. Measurement of Hydrolysis Rate Constants
for Evaluation of Hazardous Waste Land Disposal. Vol. I. U.S. Environmental Protection Agency,
Athens, GA. EPA Report No. EPA/600/3-86/043.
Gosselin, R.E., R.P. Smith, H.C. Hodge, and J.E. Braddock. 1984. Clinical Toxicology of
Commercial Products. 5th ed. The Williams and Wilkins Co., Baltimore.
LARC (International Agency for Research on Cancer). 1982. I ARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Suppl. 4. LARC, Lyon, France.
Kirk-Othmer Encyclopedia of Chemical Technology. 1978. 3rd Ed. John Wiley and Sons, Inc.,
New York.
Leo, A.J. 1983. Log P Parameter Database, Pomona College, Claremont, CA.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, J.W. Partridge,
H. Jaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority Pollutants.
SRI International. EPA 440/4-81-014.
Morrill, L.G., B.C. Mahilum, and S.H. Mohiuddin. 1982. Organic Compounds in Soils: Sorption,
Degradation and Persistence. Ann Arbor Science Publishers, Inc., Ann Arbor, MI. p. 187-238.
PHRED. 1988. Public Health Risk Evaluation Database. U.S. Environmental Protection Agency,
Office of Emergency and Remedial Response, Washington, DC.
Proctor, N.H., and J.P. Hughes. 1978. Chemical Hazards of the Workplace. Lippincott Company,
Philadelphia.
C-72
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Sax, N.I. 1984. Dangerous Properties of Industrial Materials. 6th ed. VanNostrandReinholdCo.,
New York.
Sittig, M., ed. 1980. Pesticide Manufacturing and Toxic Materials Control Encyclopedia. Noyes
Data Corp., Park Ridge, NJ.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine's MEDLARS system, National Library of Medicine, TDB Peer Review Committee.
U.S. EPA. 1976. Quality Criteria for Water. U.S. Environmental Protection Agency, Office of
Water and Hazardous Materials, Washington, DC.
U.S. EPA. 1980. Ambient Water Quality Criteria for Aldrin/Dieldrin. U.S. Environmental
Protection Agency, Office of Water Regulations and Standards, Criteria and Standards Division,
Washington, DC. EPA 440/5-80-019.
U.S. EPA. 1985. Suspended, Cancelled, and Restricted Pesticides. U.S. Environmental Protection
Agency, Office of Pesticides and Toxic Substances, Washington, DC.
U.S. EPA. 1986a. Computer retrieval from Office of Pesticides for registered sites and number of
products registered.
U.S. EPA. 1986b. Superfund Public Health Evaluation Manual. U.S. Environmental Protection
Agency, Office of Solid Waste and Emergency Response, Washington, DC. EPA-540/1-86/060.
U.S. EPA. 1987a. Carcinogenicity Assessment of Aldrin and Dieldrin. U.S. Environmental
Protection Agency, Carcinogen Assessment Group, Washington, DC. EPA/600/6-87/006.
U.S. EPA. 1987b. Draft RCRA Facility Investigation (RFI) Guidance. U.S. Environmental
Protection Agency, Office of Solid Waste, Washington, DC. EPA-530/SW-87-001.
U.S. EPA. 1988. Dieldrin - Health Advisory. U.S. Environmental Protection Agency, Office of
Drinking Water, Washington, DC.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold Co., New York.
Windholz, M. ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals.
Merck and Co., Rahway, NJ.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British Crop
Protection Council, Croydon, England.
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DIELDRIN
OBSERVATIONS AND EFFECTS ON PISCIVOROUS WILDLIFE
The concentration of dieldrin in the brain determined to cause death in several bird species appears
to be quite low. The average level that put the animal at risk of death is between 5 and 9 ppm
(Ohlendorf et al. 1981 and Stickel et al. 1972). A concentration of 6.8 ppm was determined to be
the average level lethal to birds from several laboratory studies (Heinz and Johnson, 1981).
However, levels as low as 1 ppm in the brain may trigger irreversible starvation in sensitive
individuals (Heinz and Johnson, 1981). During starvation, mobilization of low concentrations of
dieldrin from body fats to the brain may cause death, after concentrating to a lethal level (Newell
etal., 1987).
Dieldrin is commonly found in the brain, tissues, and eggs offish-eating birds that also have residues
of organochlorines such as DDE and PCBs. Dieldrin was the apparent cause of death for several
ring-billed gulls in southern Ontario in 1969 and 1973. Stickel et al. (1984) analyzed 54 gulls that
had died of no apparent disease. Of these birds, eight specimens had dieldrin levels in the brain
greater than 5 ppm. The cause of death in many of the other gulls was most likely PCB
contamination (Stickel et al., 1984).
From 1971 to 1981,101 dead or dying bald eagles were collected and analyzed for organochlorines.
Based on the data provided, four eagles had died from lethal concentrations of dieldrin (concentra-
tions near 5 ppm in the brain) (Barbehenn and Reichel, 1981).
In a nationwide survey of 72 species of heron found dead or moribund between 1966 and 1973,10
specimens had greater than 5 ppm in the brain and had possibly died of dieldrin poisoning. Eight
others had concentrations of dieldrin greater than 2.0 ppm in the brain (Ohlendorf et al., 1981).
Based on a number of studies in the literature, the State of New York proposed a dietary fish flesh
criterion of 0.12 ppm to protect piscivorous wildlife (Newell et al., 1987).
The effects of dieldrin on piscivorous wildlife are summarized in the following table:
C-74
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Effects of Dieldrin Concentrations on Piscivorous Wildlife
Animal
Birds
Birds
Birds (sensitive
individuals)
Piscivorous
Wildlife
Concentration
5 ppm (brain)
6.8 ppm
1.0 ppm (brain)
0.1 2 ppm (diet)
0.022 ppm (diet)
Effect
death
death
irreversible
starvation
estimated NOEL
cancer risk of
ID'2
Source
Stickeletal.,
1972
Heinz and
Johnson, 1987
Heinz and
Johnson, 1987
Newell et al.
1987,
Newell et al.,
1987
REFERENCES
Barbehenn, K.R., and L. Reichel. 1981. Organochlorine Concentrations in Bald Eagles:
Brain/Body Lipid Relations and Hazard Evaluation. J. Toxicol. Environ. Health 8:325-330.
Heinz, G. and R. Johnson. 1981. Diagnostic Brain Residues of Dieldrin: Some New Insights.
Avian and Mammalian Wildlife Toxicology: Second Conference, ASTM STP 757, D. Lamb and
G. Kenaga, eds., American Society of Testing and Materials, pp. 72-92. (As cited in Newell et al.,
1987)
Newell, A.J., D.W. Johnson, and L.K. Allen. 1987. Niagara River Biota Contamination Project:
Fish Flesh Criteria for Piscivorous Wildlife. Tech. Rep. 87-3. NY Dept. Environ. Conserv., Div.
Fish inildl., Bureau Environ. Protection.
Ohlendorf, K.M., D.M. Swineford, and L.N. Locke. 1981. Organochlorine Residues and Mortality
of Herons. Pest. Monit. J. 14(4): 125-135.
Stickel, W.H., L.F. Stickel, R.A. Dyrland and D.L. Hughes. 1984. Aroclor 1254 Residues in Birds:
Lethal Levels and Loss Rates, Arch. Environ. Contam. Toxicol. 13:7-13.
Stickel, W.H., L.F. Stickel and J. Spann. 1972. Tissue Residues of Dieldrin in Relation to Mortality
in Birds and Mammals. In Chemical Fallout: Current Research on Persistent Pesticides, ed., M.W.
Miller and G.G. Berg. Charles C. Thomas publisher, Springfield, USA.
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C-76
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DIPHENYL BISULFIDE
CAS No.: 882-33-7
CAS Preferred Nomenclature:
Disulfide, diphenyl
Empirical Formula: Ci2HioS2
yrms and Common N
- Phenyl disulfide
CHS
Synonyms and Common Names: ' 12 10 2
REGULATORY STATUS
• No use restrictions or regulatory standards.
SOURCES OF DIPHENYL DISULFIDE
Total Diphenyl Disulflde Produced:
• Manufactured by Parish Chemical Co., less than 23,000 pounds of diphenyl disulfide
were produced in 1982 (Perwak et al., 1983; SRI, 1986).
Uses of Diphenyi Disulflde;
• Diphenyl disulfide is used primarily as a flavoring agent in nonalcoholic beverages, ice
cream, candy, gelatin, and pudding (Perwak et al., 1983).
• Small amounts are used in the pharmaceutical industry and as a vulcanizing agent in the
manufacture of rubber (Perwak et al., 1983).
FATE IN ENVIRONMENT
Partitioning:
• Based on measured properties and structure-activity relationships, diphenyl disulfide
can volatilize at a low rate (H = 7.6xlO"6 aim • m3/mole) and has a moderately strong
tendency to sorb to soil (Kow=25,700).
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Persistence;
• Little information is available on transformation processes in the environment.
Hydrolysis and biodegradation are not expected to occur at environmentally significant
rates (Perwak et al., 1983).
HEALTH EFFECTS
Carcinogenic! ty:
• The U.S. EPA has not evaluated the potential carcinogenicity of diphenyl disulfide.
Other Toxicological Effects:
• There are no reports of adverse health effects caused by diphenyl disulfide in either
animals or humans.
Toxicological Effects Indices;
• Intraperitoneal LDso: mice, 100 mg/kg (Tatken and Lewis, 1983).
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PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Presure, P (mm Hg):
Henry's Law Constant, H @ 25 °C
Value
218.3
solid
61-62
310
1.353
N/A
5.1
1.4X10"4
Reference
Weast, 1986
Weast, 1986
Weast, 1986
Weast, 1986
Lyman, et al.,
Lyman, et al.,
1982
1982
(atnr m3/mol): 7.6x10"°
Log (Octanol-Water Partition
Coefficient), log Kow: 4.41
Soil Absorption Coefficient, Koc(rnUg): 7900
Fish Bioconcentration Factor, BCF: 1200 (calc.)
Lyman, etal., 1982
Leo,1983
Lyman, etal., 1982
Lyman, et al., 1982
C-79
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REFERENCES
Leo. AJ. 1983. Log P Parameter Database. Medchem Project, Pomona College, Claremont, CA.
Lyman, W.J., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods. McGraw-Hill Co.
Perwak, I, E. Cole, S. Coons, N. Green, W. Lyman, M. Miller, J.H. Ong, and K. Scow. 1983.
Evaluation of Waterborne Exposure Pathways to Paragraph 4(c) Pollutants. U.S. EPA Draft Report.
EPA Contract 68-01-5949.
SRI (Stanford Research Institute). 1986. Directory of Chemical Producers. Stanford Research
Institute, Menlo Park, CA.
Tatken, R.L. and R.J. Lewis, eds. 1983. Registry of Toxic Effects of Chemical Substances
(RTECS). 1981-82ed.
Weast, R.C., ed. 1986. CRC Handbook of Chemistry and Physics. 67th ed. CRC Press, Boca
Raton, FL.
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ENDRIN
CAS No.: 72-20-8
CAS Preferred Nomenclature:
2,7,3,6-Dimethanonaphth(2,3b)oxirene,
3,4,5,6,9,9-hexachloro-la,
2,2a, 3,6,6a,7 Ja-octahy dro-
Ernpirical Formula: C12HgCl6O
Synonyms and Common Names:
- Endrex - Insecticide 269
- Endriocol - Mendrin
- Hexadrin - Oktanex
ci
0<]CHiiCCI,j
CI
Cl
Cl
C12H,C.,0
REGULATORY STATUS
Standards and Criteria;
EPA Water Quality Criteria (for human
consumption of water and fish)
(PHRED, 1988):
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms)
(U.S. EPA, 1980):
Freshwater Saltwater
Acute, ^g/L 0.18 0.0023
Chronic, [ig/L 0.037 0.0023
EPA Drinking Water Standard Maxi-
mum Contaminant Level: (40 CFR
141.12):
0.0002 mg/L
EPA Drinking Water Health Ad-
visories (U.S. EPA, 1989):
-
1-day exposure = 20 |ig/L
10-day exposure = 20 ^ig/
longer-term exposure = 3
adulL(70 kg):
longer-term exposure = 10 p.g/L
lifetime exposure = 2
• Food and Drug Administration Action
Level for Fish (FDA, 1986 and 52 FR
18025):
0.3* ppm
Action Level for Other Foods:
0.02 to 0.3* ppm
* FDA Action Levels are for use in inter-
state commerce
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Use Restrictions and Bans:
• Endrin is an organochlorine compound originally registered as a pesticide in 1951. It
was used to control a wide variety of pests until its long-term persistence in soils and
high levels of mammalian toxicity were recognized.
• In 1964, the high level of endrin persistence in soils led to cancellation of its use on
tobacco (Sittig, 1980; U.S. EPA, 1980).
• By 1979, specified uses on cotton, small grains, apple orchards, sugarcane, and ornamen-
tals were also restricted (44 FR 43632).
• In 1984, the sole remaining producer of endrin voluntarily requested cancellation of
registration of all endrin products. This action effectively ended its use in the U.S. (U.S.
EPA, 1984).
SOURCES OF ENDRIN
Total Endrin Produced;
• Endrin was first used in the U.S. in 1951. By 1971, approximately 1 million pounds of
endrin were produced by Velsicol (Ouellette and King, 1977).
• Endrin production had decreased to 400,000 pounds by 1978 (U.S. EPA, 1978).
Uses of Endrin:
• Endrin is a broad spectrum pesticide and has been used to control many pests, including
termites, mice and army worms.
• Prior to 1979, the main domestic use of endrin was for the control of cotton boll worms
(an insect larva) which attack cotton crops in the southeastern and Mississippi delta
States (U.S. EPA, 1980).
• Registered uses of endrin included foliar treatment for citrus, potatoes, barley, oats, rye,
wheat, cotton, apple orchards, sugarcane, and various flowers and baric treatment for ash
and hackberry trees (U.S. EPA, 1986).
• Endrin has also been used to control pest populations of birds and rodents (U.S. EPA,
1980).
Other Sources;
• Isodrin may be metabolically converted to endrin (Matsumura, 1985).
• Endrin is also found in the pesticide dieldrin in small quantities (Verschueren, 1983).
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FATE IN ENVIRONMENT
Partitioning;
• Based on its physical/chemical properties, endrin is strongly sorbed to organic matter
=219,000) and volatilizes slowly from water (H = 4xlO"7 atm • m3/mol). It
volatilizes from soils even slower with an estimated half-life of 34 days (p/SKoc =
4.7x10" mm Hg- L/mg). Bioaccumulation is an important fate process; bioconcentra-
tion factors are moderately high to very high, ranging from 6.8xl02 to 1.3xl04 in
microcosm experiments (Callahan et al., 1979; Lyman et al., 1982).
Persistence:
• Endrin is very resistant to hydrolysis (half-life over 4 years). Photolysis of endrin in
hexane has been documented. No data concerning the photolysis rate of endrin in the
aqueous environment were found. A half-life of about 7 days was observed when endrin
was applied to a sandy loam soil and exposed to sunlight (Shell Chemical Co., 1975).
• Endrin can undergo biotransformation. Guenzi (1974) reported a biodegradation loss
rate of 4-5% per year over 14 years.
HEALTH EFFECTS
Cardnogenidty:
• No evidence of endrin carcinogenicity has been reported (U.S. EPA, 1980). Treon et
al. (1955) reported that the incidence of cancers in rats fed endrin for 2 years was no
greater than that in control rats.
• A National Cancer Institute bioassay determined no carcinogenic effects in rats or mice
(NCI, 1979).
• The U.S. EPA has classified endrin as a Class D carcinogen (inadequate evidence of
carcinogenicity in animals).
Mutagenic Activity;
• Conflicting results have been reported for endrin mutagenicity. Dikshith and Datta
(1972) reported chromosomal aberrations and cellular degeneration in rat testes. How-
ever, negative results for endrin have been recorded with the mouse dominant lethal test
(TDB, 1984).
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Reproductive Effects:
• Pregnant rats and mice fed endrin showed reduced fetal survi vaJ rates (Nodu et al., 1972).
Endrin-exposed mouse fetuses had a higher incidence of club feet.
Endrin produced embryocidal and teratogenic effects in pregnant hamsters. Single doses
of endrin (5 mg/kg) resulted in increased fetal death, congenital abnormalities (i.e., eye
deformities, cleft palate, and fused ribs), and growth retardation. Lower doses (1.5 to 5
mg/kg) did not cause similar effects (Ottolenghi et al., 1974; Chernoff et al., 1979).
Other Toxicological Effects:
• Regardless of the method of exposure, endrin, like the related compounds aldrin and
dieldrin. is highly toxic to humans (Matsumura, 1985). In one animal study endrin was
shown to be five times as toxic as dieldrin (U.S. EPA, 1980).
• Primarily, the central nervous system is affected with acute (short-term, high-dose)
poisoning by endrin. A range of symptoms can be caused, including dizziness, nausea,
confusion, hyperexcitability, generalized tremors or twitching, and convulsions. Death
from respiratory failure may also occur (U.S. EPA, 1980; Sax, 1984).
• In rats and dogs chronic (long-term, low-dose) exposure to endrin has led to poor survival
rates and degenerative changes in the liver, kidneys, and brain (U.S. EPA, 1980).
• Chronic human exposure to endrin (e.g., in the production of the pesticide) was not
shown to cause adverse health effects (Jager, 1970).
Toxicological Effects Indices:
• Reference Dose (RfD): SxlO"4 mg/kg/day (U.S. EPA, 1989).
• TWA-TLV (time-weighted average, threshold limit value) for occupational skin ex-
posure: 0.1 mg/m3 (ACGIH, 1986).
• Oral LDso: rats, 3-43 mg/kg; rabbits, 7-10 mg/kg; monkeys, 3 mg/kg (U.S. EPA, 1980;
Sax, 1984; Matsumura, 1985).
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @
25°C (atm • m3/mole):
Log (Octanol-Water
Partition Coefficient), log
Fish Bioconcentration
Factor, BCF:
380.9
white crystalline
solid; technical
grade, light tan
powder
Decomposition
above 200°C
N/A
1.7 @ 20°C
N/A
0.25 (25°C)
2xlO'7 (25°C)
-7
4x10
3.54
Soil Adsorption Coefficient, Koc(mL/g): 1.7x10
6.8x10^ to
1.3xl04
(exptl.)
1480
3970
Windholz, 1983
Matsumura, 1985
U.S. EPA, 1980
U.S. EPA, 1980
Callahan et al., 1979
Callahan et al., 1979
MabeyetaL, 1982
Leo,1983
PHRED, 1988
Verschueren et al.,
1983; Callahan etal.,
1979
PHRED, 1988
U.S. EPA, 1980
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Chemical Substances in the Work Environment ACGIH, Cincinnati, OH.
Callahan, M.A., M.W. Shimak, N.W. Gabel, I.P. May, C.F. Flowler, J.R. Freed, P. Jennings, R.L.
Durice, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould, 1979. Water-Related
Environmental Fate of 129 Priority Pollutants, Vol. 1. Office of Planning and Standards, U.S.
Environmental Protection Agency. EPA-440/4-79-029a.
Chernoff, N. et al., 1979. Perinatal Toxicity of Endrin in Rodents. I. Fetotoxic Effects of Prenatal
Exposure in Hamsters. Submitted to Toxicol. Appl. Pharmacol. and the U.S. Environmental
Protection Agency (Manuscript).
Emerson, T.E. et al., 1964. Cardiovascular Effects of the Insecticide Endrin Can. Jour. Physiol.
Pharmacol. 42:41.
FDA. 1986. NSSP Manual, Part 1, Appendix C. U.S. Food and Drug Administration, Washington,
DC.
Guenzi, W.D., ed. 1974. Pesticides in Soil and Water. Soil Science Society of America, Inc.
Madison, WI.
Jager, K.W. 1970. Aldrin, Dieldrin, Endrin and Telodrin: An Epidemioiogical and lexicological
Study of Long-Term Occupational Exposure. Elsevier Publ. Co., Amsterdam, The Netherlands.
Leo, A.J. 1983. Log P Parameter Database, Issue #24 (dated Dec. 16, 1983). Obtained from the
Medchem Project, Pomona College, Claremont, CA.
Lyman, W.J., W.F. Reehl and D.H. Rosenblatt 1982. Handbook of Chemical Property Estimation
Methods. McGraw Hill Book Co.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, J.W. Partridge,
H. Jaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority Pollutants.
SRI International. EPA 440/4-81-014.
Matsumura, F. 1985. Toxicology of Insecticides. Plenum Press, New York.
NCI (National Cancer Institute). 1979. Bioassay of Endrin for Possible Carcinogenicity. DHEW
Pub. No. (NIH) 79-812. U.S. Department of Health, Education and Welfare, Bethesda, MD.
Nodu et al. 1972. Influence of Pesticides on Embryos. On the Influence of Organochloric
Pesticides. Oyo Yakuri. 6:673. (Jap.)
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Ottolenghi, A.D. et al., 1974. Teratogenic Effects of Aldrin, Dieldrin, and Endrin in Hamsters and
Mice. Teratology 9:11.
Ouellette, R.P., and J.A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
PHRED. 1988. Public Health Risk Evaluation Database. U.S. Environmental Protection Agency,
Office of Emergency and Remedial Response; Washington, DC.
Reins, D.S., et al. 1966. Effect of Endrin on Venous Return and Catecholamine Release in the
Dog. Can. Jour. Physiol. Pharmacol. 44:59.
Sax, N.I. 1984. Dangerous Properties of Industrial Materials. 6th ed. Van Nostrand Reinhold Co.,
New York.
Shell Chemical Company. 1975. Photodegradation of Endrin on Soil. Experimental Data sub-
mitted to the U.S. Environmental Protection Agency.
Sittig, M., ed. 1980. Pesticide Manufacturing and Toxic Materials Control Encyclopedia. Noyes
Data Corp., Park Ridge, NJ.
Toxicology Data Bank (TDB) Database. 1985-86. Available through the National Laboratory of
Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Committee.
Treon, J.F., et al. 1955. Toxicity of Endrin for Laboratory Animals. Agric. Food Chem. 3:842.
U.S. EPA. 1978. Endrin-Position Document 2/3. U.S. Environmental Protection Agency, Office
of Pesticide Programs, Special Pesticide Review Division, Washington, DC.
U.S. EPA. 1980. Ambient Water Quality Criteria for Endrin. U.S. Environmental Protection
Agency, Office of Water Regulations and Standards, Washington, DC. EPA-440/5-80-047.
U.S. EPA. 1984. Internal Office of Pesticide Programs memorandum from G. La Rocca to B.
Burnam et al., August 16, 1984.
U.S. EPA. 1986. Computer retrieval from Office of Pesticides for registered sites and number of
products registered.
U.S. EPA. 1989. Health Effects Assessment Summary Tables (HEAST). U.S. Environmental
Protection Agency, Environmental Criteria and Assessment Office, Cincinnati, OH.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold Co., New York.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck Co., Inc., Rahway, NJ.
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ENDRIN
OBSERVATIONS AND EFFECTS ON PISCIVOROUS WILDLIFE
Endrin is lethal to birds at very low concentrations. In the brain, concentrations of only 0.8 ppm or
more result in death. Levels between 0.6 ppm and 0.8 ppm are hazardous may result in death (Stickel
etal., 1979).
During 1975 and 1976, 12 of 15 dead white pelicans collected from refuges in northern California
had lethal levels of endrin in the brain (0.74 to 2.7 ppm). Stickel et al. (1979) blamed these deaths
on the presence of endrin in the agricultural return flows entering the refuges.
White pelicans were also found dead with high levels of endrin near the Teton Dam disaster of 1976.
On the Gulf Coast of Louisiana, both white and brown pelicans were found dead with endrin present
in the brain (Stickel et al., 1979).
Ohlendorf et al., (1981) recorded lethal levels of endrin in the brain of one heron from Minnesota
in 1972, and one from Wisconsin in 1978. Bald eagles with lethal levels of endrin were found in
Iowa in 1977 and in Minnesota in 1976 (Stickel et al., 1979).
The endrin concentration in eggs appears to affect hatching success. For the brown pelican, Blus et
al. (1979) estimated that concentrations of greater than 0.5 ppm in the eggs caused reproductive
impairment (as cited in Newell et al., 1987). Pelican eggs from Louisiana during 1972 to 1974
commonly contained 0.5 ppm endrin (Stickel et al., 1979).
Based on data from several laboratory studies, the State of New York proposed a dietary fish flesh
criterion of 0.025 ppm endrin to protect piscivorous wildlife (Newell et al., 1987).
The effects of endrin on piscivorous wildlife are summarized in the following table:
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Effects of Endrin Concentrations on Piscivorous Wildlife
Animal Concentration Effect Source
Bird 0.6-0.8ppm hazardous Stickeletal.,
(brain) 1979
Bird 0.8 ppm (brain) death Stickel et al.,
1979
Brown Pelican 0.5 ppm (egg) reproductive Bluset al., 1979
impairment
Piscivorous 0.025 ppm (diet) estimated NOEL Newell etal,
Wildlife 1987
REFERENCES
Blus, L.J., R. Heath, C. Gish, A. Belisle, and R. Prouty. 1979. Eggshell Thinning in the Brown
Pelican: Implication of DDE. Bioscience 21: 1213-1215. (as cited in Newell et al., 1987)
Newell, A. J., D.W. Johnson, and L.K. Allen. 1987. Niagara River Biota Contamination Project:
Fish Flesh Criteria for Piscivorous Wildlife. Tech. Rep. 87-3. NY Dept. Environ. Conserv., Div.
Fish Wildl., Bureau Environ. Protection.
Ohlendorf, K.M., D.M. Swineford, and L.N. Locke. 1981. Organochlorine Residues and Mortality
of Herons. Pest. Monit. J. 14(4) 125-135.
Stickel, H., L. Reichel, and D.L. Hughes. 1979. Endrin in Birds: Lethal Residues and Secondary
Poisoning, Toxicology and Occupational Medicine, organizer in. B. Deichman, Elsevier/North-Hol-
land. New York.
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C-90
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HEPTACHLOR
CAS No.: 76-44-8
CAS Preferred Nomenclature:
4,7-Methano-lH-indene
l,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro-
Empirical Formula:
Synonyms and Common Names:
- Velsicol 104 - Heptagran
- Rhodiachlor - Heptalube
- Heptox - Drinox H-34
E3314 - Gold Crest H-60
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for human
consumption of fish) for a 10 cancer
risk (IRIS, 1989):
0.00029 jig/L
EPA Ambient Water Quality Criteria
(for protection of aquatic or-
ganismsXIRIS, 1988):
Freshwater
Acute, |ig/L 5.2x10-1
Chronic, )ag/L 3.8x10
-3
Saltwater
5.3x10'^
3.6x10
-3
EPA Drinking Water Standard (50 FR
46936; IRIS, 1989):
Proposed Maximum Contaminant
Level = 0.0004 mg/L
Proposed Maximum Contaminant
Level Goal = 0 mg/L
EPA Drinking Water Health Advisories
(IRIS, 1989):
1-day and 10-day exposures = 10 p.g/L
longer-term exposure = 5 ng/L
adult (70 kg):
longer-term exposure = 17.5 jig/L
Food and Drug Administration Action
Level for Fish (heptachlor + heptachlor
epoxide)(55 FR 14362):
0.03* ppm
FDA Action Levels for Other Foods (55
FR 14362):
0.01 to 0.02* ppm
* FDA Action Levels are for use in
interstate commerce
C-9I
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Use Restrictions and Bans:
All uses except subsurface ground insertion for termite control and dipping of roots or
tops of nonfood plants banned by 1983 (43 FR 12372).
SOURCES OF HEPTACHLOR
Total Heptachlor Produced:
In 1971,6 million pounds were produced by Velsicol Chemical Co. (Ouellette and King,
1977).
By 1983, most uses had been cancelled (Rafats and MacLean, 1986).
Heptachlor is no longer sold in the U.S. as of August 1987, but remaining stock can be
used in some States by commercial exterminators for termite control (ATSDR, 1987).
Uses of Heptachlor:
Production of heptachlor as a registered insecticide began in 1952. It was widely used
to control fire ants in southern States (Rafats and MacLean, 1986) and to control soil
insects on corn and other crops (U.S. EPA, 1980).
Use of registered products (e.g., soil treatment for pineapples and sugarcane) allowed
only by certified applicators (U.S. EPA, 1986b). No uses are allowed in Minnesota,
Massachusetts, and New York (ATSDR, 1987).
Other Sources:
• Contaminant of the pesticide chlordane (Callahan, el al., 1979).
FATE IN ENVIRONMENT
Partitioning;
Based on its physical/chemical properties, heptachlor is moderately volatile (H =
1.48xlO~3 atm • m3/mol), is strongly sorbed to sediment (Kow = 186,000), and has a
high potential for bioaccumulation (BCF = 1.57X104).
Persistence:
Heptachlor can persist in aquatic systems once it sorbs onto sediment.
Heptachlor in the water column can undergo hydrolysis and photolysis and can be
oxidized to heptachlor epoxide. Heptachlor is hydrolyzed to 1-hydroxychlordene; the
C-92
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half-life is 1 to 3 days (Callahan et al., 1979). Specific near-surface rate constants for
photolysis were not found, although photoisomerization is thought to occur
(Verschueren, 1983).
Heptachlor can be biotransformed to heptachlor epoxide or chlordane, but at a slower
rate in aquatic systems than abiotic hydrolysis (Callahan et al., 1979).
HEALTH EFFECTS
Carcinogenicity:
Exposure to heptachlor induced liver tumors in two strains of mice, but tests using rats
did not result in any tumors (IRIS, 1989). The EPA classification is B2, a probable
human carcinogen, based on tumors in mice and the fact that related chemicals cause
liver cancers (U.S. EPA, 1986b).
Mutagenic Activity:
Mutagenic effects were not observed in tests using bacteria, Drosophila. or mammalian
liver cells. Increased chromosomal aberrations were found in tests using mouse bone
marrow cells (IARC, 1979; U.S. EPA, 1980; IRIS, 1987).
Reproductive Effects;
Exposure to heptachlor has been associated with stillbirths in humans.
In animals, observed effects include decreased fertility and decreased survival of
newborns in rats and liver damage in dogs (U.S. EPA, 1980).
Other Toxicological Effects:
Acute (short-term, low-dose) exposure of humans can cause blood disorders, including
anemia and leukemia, and central nervous system damage (e.g., hyperexcitability,
depression, and convulsions) (U.S. EPA, 1980,1986b; IARC, 1979).
• Hepatotoxicity, renal and adrenotoxicity, and blood disorders have been reported from
chronic, Gong-term, low-dose) exposure to heptachlor in animals.
Toxicological Effects Indices:
• Cancer Potency Factor (CPF): 4.5 (mg/kg/day)"1 (IRIS, 1989).
• Reference Dose (RfD): 5 x 10"4 mg/kg/day (U.S. EPA, 1987a; IRIS, 1989).
• TWA-TLV (time-weighted average, threshold limit value), for occupational skin ex-
posure: 0.5 mg/m3 (ACGIH, 1986).
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PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Po'it (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor pressure, P (mm Hg):
Hydrolysis, Kn 1/hr:
Henry's Law Constant H @
25°C (atm • m3/mol):
Log (Octanol- Water Partition
Coefficient), log KOW:
Soil Adsorption Coefficient, KOC (mL/g):
Fish Bioconcentration Factor, BCF:
Value
373.3
solid
95-96 (pure)
46-74 (technical grade)
135-145°Cat
1-1.5 mm Hg
1.57-1.59
at9°C
1.65-1.67
at25°C
N/A
0.056-0.18
at25°C
3xHr*ai23°C
0.03 at 30°C
1.48xlO'3
5.27
4.4
UxlO"4
I.lxl03to
2.1xl04
11,200
Reference
Windholz, 1983
Hartley and Kidd, 1987
U.S. EPA, 1986c
U.S. EPA, 1986c
U.S. EPA, 1986c
Callahan et al., 1979
Verschueren, 1983
Callahan etal., 1979
Mills et al., 1985
Leo, 1983
Mabey et al., 1982
Mabey et al., 1982
Verschueren, 1983
U.S. EPA, 1980
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Chemical Substances in the Work Environment ACGIH, Cincinnati, OH.
ATSDR (Agency for Toxic Substances and Disease Registry). 1987. Draft Toxicological Profile
for 2,3,7,8-Tetrachlorodibenzo-p-Dioxin. ATSDR, U.S. Public Health Service, Oak Ridge Nation-
al Laboratory, Oak Ridge, TN.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979. Water-Related
Environmental Fate of 129 Priority Pollutants, Vol. I. U.S. Environmental Protection Agency,
Office of Water Planning and Standards, Washington, DC. EPA-440/4-79-029a.
Hartley, D., and H. Kidd, eds. 1987. Agrochemicals Handbook. Royal Society of Chemistry.
Nottingham, England.
IARC (International Agency for Research on Cancer). 1979. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS. 1987. Integrated Risk Information System Database. U.S. EPA, Washington, DC.
IRIS. 1988. Integrated Risk Information System Database. U.S. EPA, Washington, DC.
IRIS. 1989. Integrated Risk Information System Database. U.S. EPA, Washington, DC.
Leo, A.J. 1983. Log P Parameter Database. Pomona College, Claremont, CA.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, I.W. Partridge,
H. Jaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority Pollutants.
SRI International. EPA 440-4-81-014.
Mills, W.B., D.B. Porcella, M.J. Ungs, S.A. Gherini, K.V. Summers, L. Mok, G.L. Rupp, G.L.
Bowie, and D.A. Haith. 1985. Water Quality Assessment A Screening Procedure for Toxic and
Conventional Pollutants in Surface and Groundwater. U.S. Environmental Protection Agency,
Athens, Georgia. EPA 600/6-85/002a.
Ouellette, R.P., and J.A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
Rafats, J., and J. MacLean. 1986. Heptachlor Contamination, Special Reference Brief. National
Agricultural Library, Beltsville, MD. NAL SRB 86-02.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Committee.
C-95
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U.S. EPA. 1980. Ambient Water Quality Criteria for Heptachlor. U.S. Environmental Protection
Agency, Office of Water Regulations and Standards, Criteria and Standards Division. EPA
440/5-80-052.
U.S. EPA. 1985. Suspended, Cancelled, and Restricted Pesticides. U.S. Environmental Protection
Agency, Office of Pesticides and Toxic Substances, Washington, DC.
U.S. EPA. 1986a. Computer retrieval from Office of Pesticides for registered sites and number of
products registered.
U.S. EPA. 1986b. Superfund Public Health Evaluation Manual. U.S. Environmental Protection
Agency, Office of Emergency and Remedial Response, Washington, DC. EPA-540/1-86/060.
U.S. EPA. 1986c. Pesticide Fact Sheet Number 107.1: Heptachlor. U.S. Environmental Protec-
tion Agency, Office of Pesticide Programs, Washington, DC. EPA-540/FS-87-202. PB-87-
233748.
U.S. EPA. 1987a. Draft RCRA Facility Investigation (RFI) Guidance. U.S. Environmental
Protection Agency, Office of Solid Waste, Washington, DC. OSWER Directive 9502.00-6C.
U.S. EPA. 1987b. Health Advisory for Heptachlor and Heptachlor Epoxide. U.S. Environmental
Protection Agency, Office of Drinking Water, Washington, DC.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York..
Windholz, M, ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. lOthed. Merck Co., Inc., Rahway, NJ.
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HEPTACHLOR EPOXIDE
CAS No.: 1024-57-3
CAS Preferred Nomenclature:
2,5-Methano-2H-indeno(l-2-b)oxirene,
2,3,4,5,6,7,8-heptachloro- la, lb,5,5a,6,6a-
hexahydro-
Empirical Formula: CioHsClyO
Synonyms and Common Names:
- 1,4,5,6,7,8,8-Heptachloro-2,3-epoxy-
2,3,3a,4,7,7a-hexahydro-4,7-methanoindene,
- Epoxy heptachlor
- Velsicol53-CS-17
Cl
Cl Cl H
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for human
consumption of fish) for a 10 cancer
risk (IRIS, 1989):
0.00029
EPA Ambient Water Quality Criteria
(for protection of aquatic or-
ganisms)(IRIS, 1989):
Freshwater
Acute, ng/L 5.2X10"1
Chronic, ng/L 3.8xlO"J
Saltwai
5.3x10
3.6x10
•f
,-3
EPA Drinking Water Standard (50 FR
46936):
Proposed Maximum Contaminant
Level = 0.0002 mg/L
Proposed Maximum Contaminant
Level Goal = 0 mg/L
EPA Drinking Water Health Advisories
(IRIS, 1989):
child: flQkg)
long-term exposure = 0.13 |ig/L
adult: (10kg)
long-term exposure = 0.5 (ig/L
Food and Drug Administration Action
Level for Fish (heptachlor + heptachlor
epoxide)(55 FR 14362):
0.03* ppm
FDR Action Levels for Other Foods:
0.01 to 0.02 ppm*
* FDA Action Levels are for use in inter-
state commerce
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Use Restrictions and Bans:
Restrictions on heptachlor, the parent compound, were instituted in 1978. Heptachlor
is no longer sold in the U.S. as of August 1987, but remaining stock can be used in some
States by commercial exterminators for termite control. No uses are allowed in Min-
nesota, Massachusetts, and New York (ATSDR, 1987).
SOURCES OF HEPTACHLOR EPOXIDE
Not produced as a separate chemical.
Heptachlor epoxide is a metabolic breakdown product of heptachlor that can be produced
in microorganisms, plants, and animals (including humans).
It is a contaminant of heptachlor and chlordane.
Most uses of heptachlor have been banned. However, heptachlor epoxide can still be
found in the environment.
FATE IN ENVIRONMENT
Partitioning:
• Based on its physicaiychemical properties, heptachlor epoxide is somewhat volatile (H
= 4.4x10-4 atm • m /mol), sorbs to organic matter to a moderate extent (Kow = 500),
and can be bioaccumulated (BCF values range from 850 to 4,500 based on experimental
data).
Persistence;
Heptachlor epoxide is resistant to biotransformation. Its estimated half-life in soils is
several years (U.S. EPA, 1987a).
• Heptachlor epoxide is not susceptible to hydrolysis, oxidation, or photolysis. (Mabey
et al., 1982; Eichelberger and Lichtenberg, 1971).
HEALTH EFFECTS
Cardnogenidty;
• Exposure to heptachlor epoxide caused an increased incidence of liver carcinomas in
rats and mice and hepatomas in female rats (IRIS, 1989). It is classified as a probable
human carcinogen (B2) by the U.S. EPA (1986).
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Some increased lung and bladder cancers occurred in pesticide manufacturing plant
workers, but it is difficult to associate occurrences with quantitative doses of a specific
chemical (ATSDR, 1987).
Mutaeenic Activity:
No evidence of mutagenic activity was observed using mouse dominant lethal test, Ames
test, or tests with fruit flies (IRIS, 1989).
Reproductive Effects:
When animals were fed heptachlor epoxide there was decreased fertility and decreased
fetal survival noted in rat and mouse studies extending for two to three generations.
(Cerey and Ruttkay-Nedecka, 1971; Ruttkay-Nedecka, etal., 1972; Green, 1970).
Higher heptachlor epoxide levels were found in one group of women with premature
delivery (Wasserman, et al., 1982) and in stillborn infants (Curley, et al., 1969). Data
are not considered adequate to define a direct relationship between exposure and
reproductive effects (ATSDR, 1987).
Other Toxicological Effects:
Acute (short-term, high-dose) exposure in humans can cause central nervous system effects
(e.g., irritability, dizziness, muscle tremors, and convulsions) (U.S. EPA, 1986).
In animals, liver, kidney, and blood disorders can occur. The oral LDso values for
heptachlor epoxide range from 46.5 to 60 mg/kg. (U.S. EPA, 1980; IARC, 1979; IRIS,
1988).
Toxicological Effects Indices:
Cancer Potency Factor (CPF): 9.1 (mg/kg/day)"1 (IRIS, 1989)
Reference Dose (RfD): 1.3 x 10"5 mg/kg/day (IRIS, 1989)
C-99
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Density/Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor pressure, P (mm Hg):
Henry's Law Constant, H @
25°C (atm • m3/mol):
Log (Octanol-Water Partition
Coefficient), log
Fish Bioconcentration Factor,
BCF (for fish):
389.3
solid
157-160
N/A
N/A
N/A
0.350 (25°C)
3x10^ (25°C)
(value for
heptachlor)
4.4X10"4
2.70
Soil Adsorption Coefficient, Koc(mL/g): 2.2x10
1.44x10 (calc.)
2900 pinfish
4500 minnow
1700 mussel
850 oyster
11,280
Windholz, 1983
Callahanetal., 1979
Mabey et al., 1982
Mabeyetal., 1982
Mabey etal., 1982
Mabeyetal., 1982
Mabeyetal., 1982
Lymanetal., 1982
Zaroogian et al.,
1985
U.S. EPA, 1980
C-IOO
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REFERENCES
ATSDR (Agency for Toxic Substances and Disease Registry). 1987. Draft Toxicological Profile
for 2,3,7,8-Tetrachlorodibenzo-p-Dioxin. U.S. Public Health Service, Oak Ridge National
Laboratory, Oak Ridge, TN.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979. Water-Related
Environmental Fate of 129 Priority Pollutants, Vol. I. U.S. Environmental Protection Agency,
Office of Water Planning and Standards, Washington, DC. EPA-440/4-79-029a.
Cerey, K., and J. Ruttkay-Nedecka. 1971. The Influence of Heptachlor on Rat Fertility and Growth.
Z. Versuchstierkd. 13:243-244.
Curley, A., M.F. Copeland, and R.D. Kimbrough. 1969. Chlorinated Hydrocarbon Insecticides in
Organs of Stillborn and Blood of Newborn Babies. Arch. Environ. Health 19:628-632.
Eichelberger, J.W., and J.J. Lichtenberg. 1971. Persistence of Pesticides in River Water. Environ.
Sci. Technol. 5:541-544.
Green, V.A. 1970. Effects of Pesticides on Rat and Chick Embryo. In: Trace Subst. Environ.
Health 3, Proc. Univ. Mo. 3rd Annual. Conf., Meeting Date 1969 (D. Hemphill, ed.).
I ARC (International Agency for Research on Cancer). 1979. I ARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS. 1988. Integrated Risk Information System Database. U.S. Environmental Protection Agen-
cy, Washington, DC.
IRIS. 1989. Integrated Risk Information System Database. U.S. Environmental Protection Agen-
cy, Washington, DC.
Lyman, W.J., W.F. Reehe, and D.H. Rosenblatt 1982. Handbook of Chemical Property Estimation
Methods - Environment. McGraw-Hill, New York.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, I.W. Partridge,
H. Jaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority Pollutants.
SRI International. EPA 440- 4-81-014.
Ruttkay-Nedecka, J., K. Cerey, and L. Rosival. 1972. Evaluation of the Chronic Toxic Effect of
Heptachlor. Kongr. Chem. Pol'nohospod. 2:C27.
U.S. EPA. 1980. Ambient Water Quality Criteria for Heptachlor. U.S. Environmental Protection
Agency, Office of Water Regulations and Standards, Criteria and Standards Division. EPA
440/5-80-052.
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U.S. EPA. 1985. Drinking Water Criteria Document for Heptachlor, Heptachlor Epoxide and
Chlordane. U.S. Environmental Protection Agency, Washington, DC. EPA 600/X-84-197-1.
U.S. EPA. 1986. Superfund Public Health Evaluation Manual. U.S. Environmental Protection
Agency, Office of Emergency and Remedial Response, Washington, DC. EPA-540/1-86/060.
U.S. EPA. 1987. Draft. RCRA Facility Investigation (RFI) Guidance. U.S. Environmental
Protection Agency, Office of Solid Waste. OSWER Directive 9502.00-6C.
U.S. EPA. 1987b. Heptachlor and Heptachlor Epoxide Health Advisory. U.S. Environmental
Protection Agency, Office of Drinking Water.
Windholz, M.t ed., 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck Co., Inc., Rahway, NJ.
Zaroogian, G.E., J.F. Heltshe, and M. Johnson. 1985. Estimation of bioconcentration in marine
species using structure-activity models. Environ. Toxicol. Chem. 4:3-12.
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HEXACHLOROBENZENE
CAS No.: 118-74-1
CAS Preferred Nomenclature:
Benzene, hexachloro-
Empirical Formula:
Synonyms and Common Names:
- HCB - Amadin
- No Bunt - Co-op Hexa
- Perchlorobenzene
REGULATORY STATUS
Standards and Criteria;
• EPA Water Quality Criteria (for human
consumption of fish) for a 10 cancer
risk (U.S. EPA, 1987):
0.74 ng/L
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms)
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
EPA Drinking Water Health Advisories
(U.S. EPA, 1987):
Child (10 kg):
1-day, 10-day and long-term
exposure = 0.05 mg/L
adult (70 kg):
long-term exposure = 0.2 mg/L
Food and Drug Administration Action
Level for Fish:
None established at present
Food and Drug Administration Action
Level for Meat and Poultry (Morris and
Cabral, 1986):
0.5 ppm*
FDA Action Levels are for use in inter-
state commerce
Use Restrictions and Bans:
In 1984 registration of hexachlorobenzene as a pesticide was voluntarily cancelled
(Morris and Cabral, 1986).
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SOURCES OF HEXACHLOROBENZENE
Total Hexachlorobenzene Produced:
Production in the U.S. of HCB as a pesticide was about 3.2 million pounds in 1975
(Blackwood and Sipes, 1979). Commercial production in the U.S. was discontinued in
1976 (U.S. EPA, 1984). Since 1981 no HCB has been imported (Menzie, 1986).
HCB is formed, however, as a by-product of the production of other chlorinated
compounds. Major sources include carbon tetrachloride, tetrachloroethene, and
trichloroethene. HCB is also an impurity in some pesticides (e.g., pentachloronitroben-
zene, chlorothalonil, dacthal, picloran) and in pentachlorophenol.
Uses of Hexachlorobenzene:
Primary agricultural use prior to 1985 was as a fungicide to protect seeds of grain crops,
particularly wheat (Devine, 1982; Pelletier, 1985)
In the early 1970' s, small amounts of HCB were used for a variety of industrial purposes:
- fungicide in paper products (Verschueren, 1983)
- pyrotechnic materials (Quinlivan et al., 1975)
- synthetic rubber production for tires (Mumma and Lawless, 1975)
- reported use as fluxing agent in aluminum production (Quinlivan et al., 1975)
- reported use in graphite electrode production (Mumma and Lawless, 1975).
Other Sources:
Incineration of municipal waste and chlorination treatment of industrial process water
and wastewater.
• Breakdown product of the biotransformation of lindane (Morris and Cabral, 1986).
• Emissions to air and water from landfills containing pesticides and industrial wastes
(Brooks and Hunt, 1984).
FATE IN ENVIRONMENT
Partitioning:
Based on its physical/chemical properties, hexachlorobenzene can volatilize but not
readily (H = 6.8xl(T* atm • m /mol). An experimentally-determined volatilization
half-life was 41 hours in 1-meter-deep water (Korte and Greim, 1981). HCB sorbs
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strongly to soils or sediments containing organic matter (Kow = 457,000). HCB can
bioaccumulate, although the potential differs substantially among aquatic species (BCF
= 7,800 to 22,000).
Persistence:
Hexachlorobenzene is widespread and persistent in aquatic systems. Recent experi-
ments by Mill and Haag (1986) confirmed that photolysis is slow with a half-life of about
90 days. Earlier experiments had suggested that natural organics (e.g., humic acids)
might increase photolysis, but Mill and Haag found no such effect. Because of its
chemical structure, HCB does not undergo hydrolysis at temperatures normally found
in the environment. Experiments to determine biotransformation rates of HCB found
negligible degradation (Tabaket al., 1981; Callahan et al., 1979).
HEALTH EFFECTS
Carcinogenic! ty:
Hexachlorobenzene causes liver tumors in rats, mice, and hamsters (IARC, 1979; U.S.
EPA, 1984). Tumors have also been induced in kidneys of rats and in adrenal and thyroid
glands of hamsters (U.S. EPA, 1984). EPA classification B2: Probable human car-
cinogen (I ARC Class 2b) (PHRED, 19888).
Mutagenic Activity;
• Hexachlorobenzene was not mutagenic in bacterial or mammalian cell assays, but was
mutagenic in yeast (U.S. EPA, 1984). The Ames test was also negative (Morris and
Cabral, 1986).
Reproductive Effects:
HCB is teratogenic in mice and rats (IARC, 1979) and fetotoxic in rats and quail.
An increase in mortality of breast-fed babies whose mothers have been chronically
exposed to HCB has also been reported (IARC, 1979).
Other Toxicological Effects:
• Chronic Gong-term, low-dose) human exposure to HCB can cause porphyria with the
following symptoms: skin lesions, excessive pigmentation, excessive hair production
or hair loss, light sensitivity, and neurologic damage (U.S. EPA, 1984, 1987). Effects
on animals include liver and kidney lesions in rats; immunosuppression in mice, rats and
dogs; neurologic damage in mice; and changes in ovaries of female mice (U.S. EPA,
1987; Morris and Cabral, 1984). One test using rats showed no effects on the first
generation at dosages of 0.32-40 ppm, but the second generation had liver and
C-105
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parathyroid gland problems. Oral LDso values range from 1,700 mg/kg in cats to 10,000
mg/kg in rats (U.S. EPA, 1987).
Toxicological Effects Indices:
• Cancer potency factor (CPF): 1.7 (mg/kg/day)'1 (U.S. EPA, 1986; PHRED, 1988).
• Reference Dose (RfD): 0.0008 mg/kg/day (IRIS, 1989).
C-I06
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant,
Water Solubility, S (mg/P):
Vapor Pressure, P (mm Hg):
Henry's Law Constant H @
25°C (atra • m3/mol):
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient,
Koc (mL/g):
Fish Bioconcentration
Factor, BCF:
284.8
solid
231
323-326
2.044 (23°C)
N/A
6x10-3 (25°C)
0.11(24°C)
1.089xlO'5(20°C)
5.66
3900(calc)
7800 rainbow trout
22,000 fathead
minnow
8,690
Windholz, 1983
Windholz, 1983
Windholz, 1983
Windholz, 1983
Callahan et al., 1979
Verschueren, 1983
Callahan et al., 1979
Lyman et al., 1982
Leo, 1983
Lyman et al., 1982
U.S. EPA, 1987
U.S. EPA, 1987
U.S. EPA, 1980
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REFERENCES
Blackwood and Sipes. 1979. Status Assessment of Toxic Chemicals: Hexachlorobenzene. U.S.
Environmental Protection Agency, Office of Research and Development, Washington, DC. EPA-
600/2-79-2 lOg.
Brooks, G.W., and G.E. Hunt. 1984. Source Assessment for Hexachlorobenzene. EPA Contract
No. 68-02-3818. Research Triangle Park, NC.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979. Water-Related
Environmental Fate of 129 Priority Pollutants, Vol II. U.S. Environmental Protection Agency,
Office of Water Planning and Standards, Washington, DC. EPA-440/4-79-029b.
Devine, K. 1982. Preliminary Quantitative Usage Analysis of Hexachlorobenzene. U.S. Environ-
mental Protection Agency, Office of Pesticides Programs, Washington, DC.
ICF Incorporated. 1985. Draft Superfund Public Health Evaluation Manual. U.S. Environmental
Protection Agency, Office of Solid Waste and Emergency Response, Washington, DC. EPA
Contract #68-01-7090.
IARC (International Agency for Research on Cancer). 1979. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS. 1988. Integrated Risk Information Service. Office of Emergency and Remedial Response,
U.S. Environmental Protection Agency, Washington, DC.
IRIS. 1989. Integrated Risk Information Service. Office of Emergency and Remedial Response,
U.S. Environmental Protection Agency, Washington, DC.
Korte, F. and H. Greim. 1981. Feasibility of Test Guidelines and Evidence of Base-set Testing
according to the Chemicals Legislation. Environmental Research Plan of the Ministry of the
Interior, Research Report No: 10704006/1. Federal Environmental Agency, West Berlin, Germany.
Leo, A.J. 1983. Log P Parameter Database, Pomona College, Claremont, CA.
Lyman, W.J.,ed. 1982. Handbook of Chemical Property Estimation Methods. McGraw-Hill, New
York.
Menzie, C.M. 1986. Hexachlorobenzene: Uses and Occurrence, pp. 13-22. In: Morris, C.R. and
J.R.P. Cabral, ed. Hexachlorobenzene: Proceedings of an International Symposium. IARC.
Scientific Publications No.77.
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Mill, T., and W. Haag. 1986. The Environmental Fate of Hexachlorobenzene. p.61-66. In
Hexachlorobenzene: Proceedings of an International Symposium, ed. C.R. Morris and J.R.P. Cabral.
IARC Scientific Publications, No.77
Morris, C.R., and J.R.P. Cabral, eds. 1986. Hexachlorobenzene: Proceedings of an International
Symposium. IARC Scientific Publication No.77. Lyon, France.
Mumma, C.E., and E.W. Lawless. 1975. Survey of Industrial Processing Data, Task I -
hexachlorobenzene, pollution from chlorocarbon processes. U.S. Environmental Protection Agen-
cy, Washington, DC. EPA-560/3-75-003.
Pelletier, E.N. 1985. Fungicidal Uses of HCB and Other Fungicides Possibly Containing HCB.
Memo from E.N. Pelletier to P. Tobin, February 11,1985. U.S. Environmental Protection Agency,
Office of Pesticides Programs, Washington, DC.
PHRED. 1988. Public Health Risk Evaluation Database. Office of Emergency and Remedial
Response. U.S. Environmental Protection Agency, Washington, DC.
Quinlivan, S.M., M. Ghasseni, and M. Shanty. 1975. Survey of Methods Used to Control Water
Containing Hexachlorobenzene. U.S. Environmental Protection Agency, Washington, DC. NTIS
PB 25305.
Tabak, H.H., S.A. Quave, C.I. Mashni, and E.F. Barth. 1981. Biodegradability Studies with
Organic Priority Pollutant Compounds. Jour. Water Pollution Control Federation 53(10):1503-
1518
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Committee.
U.S. EPA. 1984. Health Effects Assessment for Hexachlorobenzene. U.S. Environmental Protec-
tion Agency, Washington, DC. EPA 540/1/86-017.
U.S. EPA. 1986. Computer retrieval from Office of Pesticides for registered sites and number of
products registered.
U.S. EPA. 1987. Health Advisory for Hexachlorobenzene. U.S. Environmental Protection
Agency, Office of Drinking Water, Washington, DC.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck & Co., Rahway, NJ.
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C-llo
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a-HEXACHLOROCYCLOHEXANE
(alpha-BHC)
CAS No.: 319-84-6
CAS Preferred Nomenclature:
Cyclohexane, 1 ,2,3,4,5,6- hexachloro-
(1. alpha., 2.alpha., 3.beta., 4.beta.,
S.beta., 6.beta.)-
Empirical Formula:
Synonyms and Common Names:
- a-Hexachlorocyclohexane - a-Benzenehexachloride
- ct-BHC - a-Hexachloran
- a-HCH - a-Lindane
REGULATORY STATUS
Standards and Criteria:
• EPA Water Quality Criteria (for human
consumption of fish) for a 10 cancer
risk (IRIS, 1989):
EPA Ambient Water Quality Criteria
(for protection of aquatic or-
ganismsXIRIS, 1989):
Freshwater Saltwater
Acute, tig/L 100 0.34
Chronic, jig/L — —
Above are LECs (Lowest Effect Con-
centration)
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
EPA Drinking Water Health Advisories:
child (10 kg):
1-day, 10-day and long-term
exposures = 50 ^ig/L
adult (70 kg):
long-term exposure = 20 fig/L
Food and Drug Administration Action
Level for Fish:
None established at present
C-lll
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Use Restrictions and Bans:
In 1977, EPA cancelled inclusion of a-hexachlorocyclohexane in technical grade
lindane (EPA, 1985).
Uses of all but y-hexachlorocydohexane (lindane) were cancelled by 1978 (41 FR
46031;43FR31432).
SOURCES OF q-HEXACHLOROCYCLOHEXANE
Total a-Hexachlorocyclohexane Produced:
a-Hexachlorocyclohexane is no longer produced in the United States.
Uses of o>Hexachlorocyclohexane:
Hexachlorocyclohexane occurs in eight forms. Technical grade lindane is an off-white
to brown powder that, prior to 1977, contained a-hexachlorocyclohexane.
Technical-grade lindane was used to control cockroaches, flies, aphids, grain weevils,
and beetles (Kirk-Othmer, 1982).
Other Sources;
May be selective degradation product of other hexachlorocyclohexane isomers.
(Matsumura, 1985).
FATE IN ENVIRONMENT
Partitioning:
Based on the physical/chemical properties of oc-hexachlorocyclohexane, sorption to
sediment is moderate(Kow = 8,000), and the potential for bioaccumulation is low (BCF
= 130). Based on its similarity to the 7 isomer, volatilization is estimated to be low.
Experiments by Tsukano (1973) reported Freundlich isotherms for the
hexachlorocyclohexane isomers on two soils with organic carbon contents of 1.9% and
5.2%. The values were 1/n =0.71 to 0.83 and K = 30 to 120 for the second soil.
Persistence:
Hydrolysis, photolysis, and oxidation are not thought to be important fate-determining
processes in the environment One experiment showed no change due to hydrolysis at
a pH of 7.3 to 8 after 2 years (Callahan et al., 1979). No other studies under acidic or
more alkaline conditions were found.
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Bio transformation has been observed in laboratory experiments conducted using
soil/water mixtures under anaerobic conditions (Tsukano, 1973).
HEALTH EFFECTS
Carcinogenicity:
Inadequate data exist to determine whether a-hexachlorocyclohexane is a human
carcinogen. Exposure to a-hexachlorocyclohexane caused increased incidences of liver
tumors in mice and rats. a-Hexachlorocyclohexane is classified by EPA as a probable
(B2) human carcinogen. IARC (1979) states that hexachlorocyclohexane cannot be
classified (class d) because of limited data.
Mutagenic Activity:
a-Hexachlorocyclohexane (tested individually and mixed with (3-hexachloro-
cyclohexane) was determined to be nonmutagenic in bacteria, yeast, and Drosophila
(IARC, 1979).
Reproductive Effects: No data found.
Other Toxicological Effects: None found.
Toxicological Effects Indices;
• Cancer potency factor (CPF): 6.3 (mg/kg/day)'1 (IRIS, 1989).
C-I13
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight: 291
Physical State @ 20°C: solid
Melting Point (°C): 157-158
Boiling Point (°C): N/A
Specific Gravity: N/A
Acid Dissociation Constant, pKa: N/A
Water Solubility, S (mg/L): 1.63
Vapor Pressure, P (mm Hg): 2.5x10
Henry's Law Constant,
H @ 25°C (atm • m3/mol): N/A
Log (Octanol-Water Partition
Coefficient), log Kow: 3.90
Soil Adsorption Coefficient, Koc(mL/g): 3800
Fish Bioconcentration Factor, BCF: 130
-5
Callahanetal., 1979
Gunther, 1971
Brooks, 1974
Callahanetal., 1979
Mabey et al., 1982
Mabey et al., 1982
OWRS, U.S. EPA, 1980
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REFERENCES
Brooks, G.T. 1974. Chlorinated Insecticides: Volume I: Technology and Applications. CRC
Press, Cleveland, OH.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitmore, and B. Maestri. 1979. Water Related Environmental Fate of 129 Priority
Pollutants. U.S. Environmental Protection Agency, Washington, DC. EPA-440/4-79-029a.
Gunther, F.A. 1971. Halogen Derivatives of Aliphatic Hydrocarbons. Residue Review. 36:34-77.
IARC (International Agency for Research on Cancer). 1979. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS. 1989. Integrated Risk Information Service. U.S. Environmental Protection Agency, Office
of Emergency and Remedial Response, Washington, DC.
Kirk-Othmer. 1982. Encyclopedia of Chemical Technology. 3rd. ed. John Wiley and Sons, Inc.,
New York.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, T.W. Partridge,
H. Jaber, D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority Pollutants. SRI
International. EPA 440/4-81-014.
Matsumura, F. 1985. Toxicology of Insecticides. 1982. 3rded. John Wiley and Sons, Inc., New
York.
OWRS, U.S. EPA. 1980. Ambient Water Quality Criteria Documents for -Hexa-
chlorocyclohexane.
Tsukano, Y. 1973. Factors Affecting Disappearance of BHCIsomers from Field Rice Soil. JARQ.
7(2):93-97.
U.S. EPA. 1985. Guidance for the Registration of Pesticide Products Containing Lindane as the
Active Ingredient U.S. Environmental Protection Agency, Office of Pesticide Programs,
Washington, DC. EPA 540/RS-86-121.
U.S. EPA. 1987. Draft RCRA Facility Investigation (RFI) Guidance. U.S. Environmental Protec-
tion Agency, Office of Solid Waste, Washington, DC. EPA-530/SW-87-001.
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C-116
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ISOPROPALIN
CAS No.: 33820-53-0
CAS Preferred Nomenclature:
Benzenamine, 4-( 1 -methylethyl)-2,6-
dinitro-N,N-dipropyl-
Empirical Formula: CisH23N3O4
Synonyms and Common Names:
- Paarlan
- 2,6-Dinitro-N,N-dipropylcumidene
- El-179
(CHj)jCH
REGULATORY STATUS
Standards and Criteria;
• EPA Water Quality Criteria (for human
consumption offish):
None established at present
• EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
EPA Drinking Water Health Advisories:
None established at present
EPA Tolerance Levels for peppers and
tomatoes (40 CFR 180.313):
0.05 ppm
(Proposed to be revoked in May 1990)
Food and Drug Administration Action
Level for Fish:
None established at present
Use Restrictions and Bans:
Isopropalin may be used only as a pre-emergent herbicide on tobacco fields that are not
rotated with food or feed crops.
SOURCES OF ISOPROPALIN
Total Isopropalin Produced:
Isopropalin is produced by Eli Lilly and Co. No production data are available (SRI,
1986).
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One report states that other dinitroaniline herbicides are used more widely than
isopropaiin. This would make isopropaiin production in the U.S. less than 4,000 tons
per year (Green et al., 1987).
Uses of Isopropaiin
Isopropaiin is a dinitroaniline compound used as a herbicide to control grasses and
broadleaf weeds in the vegetable crops of peppers and tomatoes (Ouellette and King,
1977; Worthing, 1983; Farm Chemicals Handbook, 1985).
The only currently registered use for isopropaiin is as a preemergent spray for controlling
weeds in tobacco crops (Worthing, 1983; IRJS, 1989).
Other Sources: None found.
FATE IN ENVIRONMENT
Partitioning;
Based upon its physical/chemical properties, isopropaiin is predicted to volatilize
relatively rapidly from water (H=1.5 x 10"4 atm • m /mol) and at a slower rate from
surface soil (P/SKoc = 4.4 x 10"9 mm Hg« L/mg corresponding to an estimated
volatilization half-life of 3.6 days).
It adsorbs relatively strongly to soils and sediments (estimated Kpc = 8.5 x 10 ) and has
a high potential for bioaccumulation (estimated BCF = 2.5 x 10 j.
Isopropaiin has a low potential for leaching from soils. Holzer and Sieck (1972) reported
that isopropaiin and its associated breakdown products, which formed during 30 days
of aerobic incubation, were relatively immobile in a sandy loam soil. Approximately
99% of the radio-labeled compound initially applied as 14C-isopropalin remained in the
top 2 inches of a 12-inch sandy loam column after 45 days of elution with 0.5 inch
water/day.
Sleight (1972) reported maximum isopropaiin concentrations of 25-40 mg/kg in the
edible tissues of bluegill sunfish during 42 days of exposure to 0.025 mg/L. The
tissue-to-water concentration ratios correspond to non-steady-state BCF values of 1.0 x
103tol.6xl03.
Persistence:
Saunders and Smith (1983) reported that at 24°C, isopropaiin did not undergo any
detectable hydrolysis over a 42-day period at pH values of 5,7, and 9.
Saunders and Smith (1983) reported a short photodegradative half-life of 1.5 hours for
isopropaiin in a pH 7 buffered aqueous solution exposed to artificial light with a similar
irradiation spectrum to that of sunlight.
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Biodegradation of isopropalin in soil occurs. The specific processes include dealkyla-
tion, reduction of nitro groups to amino groups. Twelve different breakdown products,
representing at most 4% of the parent compound, were identified (Golab and Althaus,
1975). Golab (1983) reported relatively long 50% dissipation times of approximately
6 months for 2 ppm isopropalin incubated at 23°C in a sandy loam, a loam, and a clay
loam soil under aerobic conditions. Golab and Sassic (1983) reported that the degrada-
tion of isopropalin in a loam soil was more rapid under anaerobic conditions (45%
dissipated within 60 days) than under aerobic conditions.
ISOPROPALIN OBSERVED IN THE ENVIRONMENT
No data available.
HEALTH EFFECTS
Carcinogenic! ty:
• The carcinogenic potential of isopropalin has not been evaluated by the U.S. EPA (IRIS,
1989). No experimental data have been found for carcinogenicity tests with isopropalin.
Mutopenic Activity: No data found.
Reproductive Effects:
• The U.S. EPA states that better studies on the reproductive effects of ispropalin need to
be conducted. In one rat study with isopropalin, the only effects noted were reduced
weights and reduced food consumption in exposed mothers (IRIS, 1989).
Other Toxicological Effects;
Acute human toxicity due to short-term, high-dose exposure to isopropalin is considered
to be insignificant (Sittig, 1985).
Isopropalin at high doses (>2000 rag/kg) caused eye and skin irritation in rabbits
(Worthing, 1983).
No fatalities were observed in chickens, dogs, mallard ducks, or rabbits fed isopropalin
at 2000 rag/kg or quail fed a dosage of 1000 rag/kg (Worthing, 1983).
Subchronic (90-day feeding) exposure of rats caused a reduction in the number of red
blood cells and alterations in organ weights at the highest dose (288 mg/kg/day).
• EPA does not require that chronic (long-term, low-dose) exposure tests be conducted
because of isopropalin's use on tobacco. EPA recognizes that the use of tobacco
products is detrimental to the consumer and that the use of tobacco is voluntary. It may
be possible then to avoid exposure to isopropalin residues (IRIS, 1989).
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Toxicological Effects Indices:
Reference Dose (RfD): 1.5 x 10"2 mg/kg/day (IRIS, 1989).
Oral LDso rats and mice: >5000 mg/kg (Dreisbach, 1980; Sittig, 1985; Worthing, 1983).
LCso (96 hour): fathead minnow, >0.1 mg/L; goldfish, >0.15 mg/L.
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @
25°C (atm • m3/mol)
Log (Octanol-Water
Partition Coefficient), log Kow:
Soil Adsorption Coefficient, Koc (mL/g):
Fish Bioconcentration Factor, BCF:
309.4
red-orange
liquid
N/A
390 (calc.)
N/A
N/A
0.08 Weed Science Society,
3xlO'5(25.6°C)
1.5x10"* (calc.)
5.74 (calc.)
8.5xl04(calc.)
2.5xl04 (calc.)
Worthing, 1893
Worthing, 1983
Lymanetal., 1982
1983
Weed Science Society,
1983
Lymanetal., 1982
Lymanetal., 1982
Lyman et al., 1982
Lyman et al., 1982
C-121
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REFERENCES
Dreisbach, R.H. 1980. Handbook of Poisoning: Prevention, Diagnosis and Treatment. Lange
Medical Publications, Los Altos, CA.
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Golab.T. 1983. 14C-Isopropalin Aerobic Soil Degradation Study. Eli Lilly and Co. ABC-0154.
Golab, T, and W.A. Althaus. 1975. Transformation of Isopropalin in Soil and Plants. Weed
Science 23:165.
Golab, T.,andK.A. Sassic. 1983. (14C) Isopropalin Anaerobic Soil Degradation Study. Eli Lilly
and Co. ABC-0155.
Green, M.B., G.S. Hartley, and T.F. West. 1987. Chemicals for Croplmprovement and Pest
Management. 3rd ed. Pergamon Press, Oxford, England.
Holzer, F.J., and R.F. Sieck. 1972. EL-179 Leaching Study on Degradation Products. Eli Lilly
Co. and Purdue University. CDL: 126281-C; MRID #00002474.
IRIS. 1989. Integrated Risk Information System. U.S. Environmental Protection Agency,
Washington, DC.
Lyman, W.G., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods. McGraw-Hill Book Co., New York.
Ouellette, R.P., and J.A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book Co.,
New York.
Saunders, D.G., and S.K. Smith. 1983. Photodegradation of Isopropalin in Aqueous Solution. Eli
Lilly and Co. l-EWD-83-02.
Sittig, M., ed. 1985. Pesticide Manufacturing and Toxic Materials Control Encyclopedia. Noyes
Data Corp., Park Ridge, NJ.
Sleight, R.H. 1972. Research Report: Accumulation and Persistence of 14C-EL-179 Residues of
Bluegill (Lepomis macrochirus) Continually Exposed to the Chemical in Water. Eli Lilly and Co.
CDL: 126281-D; MRID #00002475.
Smith, S.K., and D.G. Saunders. 1983. Hydrolysis of the Herbicide Isopropalin in Aqueous Buffer
Solution. Eli.LUly and Co. l-EWD-82-33.
SRI (Stanford Research Institute). 1986. Directory of Chemical Producers. Stanford Research
Institute, Menlo Park, CA.
C-/22
-------
Weed Science Society of America. 1983. Herbicide Handbook. 5th ed. Weed Science Society of
America, Champaign, IL.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British Crop
Protection Council, Croydon, England.
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C-124
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LINDANE
(y-HEXACHLOROCYCLOHEXANE)
CAS No.: 58-89-9
CAS Preferred Nomenclature:
Cyclohexane, 1,2,3,4,5,6-hexachloro-,
Empirical Formula:
Synonyms and Common Names:
- Y-Benzene hexachloride
- y-BHC
- y-HCH
- y-Hexachlorobenzene
C!
ci
C6H6CI6
-Y-Hexachlorocyclohexane
-Gammexane
-Jacutin
-Lindex
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for human
consumption offish) (IRIS, 1989):
6.25 x 10'2
EPA Ambient Water Quality Criteria
(for protection of aquatic or
ganisms)(IRIS, 1989):
Freshwater Saltwater
Acute, ng/L 2.0 . 1.6x10
S1
Chronic, ^ig/L 8.0x10
-2
EPA Drinking Water Health Advisories
(PHRED, 1988)
child (10 kg):
1-day and 10-day exposure = 1200 (ig/L
longer-term exposure = 33 (ig/L
adult (70 kg):
longer-term exposure = 0.12 }ig/L
lifetime exposure = 0.2 |ig/L
Food and Drug Administration Action
Level for Fish:
None established at present
C-125
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• EPA Drinking Water Standard • Food and Drug Administraiton Ac-
(IRIS, 1989): tion Level for Other Foods (55 FR
Current Maximum Contaminant 14362)
Level = 0.004 mg/L 0.1 to 0.5 ppm*
Proposed Maximum Contaminant
Level = 0.0002 mg/L
Proposed Maximum Contaminant
Level Goal = 0.0002 mg/L
* FDA Action Levels are for use in inter-
state commerce
Use Restrictions and Bans:
In 1977, EPA banned inclusion of oc-and p-hexachlorocyclohexane in technical grade
lindane.
Use in smoke fumigation devices for indoor domestic purposes banned in 1985 (48 FR
48512,50 FR 5424).
Use of lindane in dog dips for the control of pests (other than mites) permitted only for
veterinary use (U.S. EPA, 1985).
Application permitted only under direct supervision of a certified applicator. Protective
clothing required (U.S. EPA, 1985).
SOURCES OF LINDANE
Total Lindane Produced:
First synthesized in 1825, lindane's insecticidal properties were discovered in 1942
(Hayes, 1982).
In 1971, one million pounds were produced by Occidental Petroleum Corporation
(Ouellette and King, 1977).
• Technical lindane (a mixture of several isomers of hexachlorocyclohexane) is no longer
produced in the United States, but is imported from France, Germany, Spain, Japan, and
China (U.S. EPA, 1985). It is an off-white to brown powder with a persistent, musty
odor (Hayes, 1982).
Uses of Lindane;
• Lindane is registered for use as an insecticide/acaracide on a variety of fruit and vegetable
crops, ornamentals, tobacco, forestry, domestic outdoor and indoor uses by homeowners,
commercial warehouses or feed storage areas, farm animal premises, and wooden
structures (U.S. EPA, 1985).
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Lindane is primarily used on phytophagous and soil-inhabiting insects, public health
pests, and animal ectoparasites (Farm Chemicals Handbook, 1987).
In 1982, approximately 48%, 20%, and 19% of the lindane use in the U.S. was for seed
treatment, livestock, and hardwood lumber, respectively.
Other Sources: Component of other hexachlorocyclohexanes.
FATE OF LINDANE IN THE ENVIRONMENT
Partitioning;
Based upon its physical/chemical properties, lindane is predicted to volatilize relatively
slowly from water (H = 4.9 x 10 atm • m /mol), volatilize at an intermediate rate from
soil surfaces (P/SKoc = 3.3 x 10 mm Hg • L/mg, corresponding to an estimated
volatilization half-life of 18 days), and have intermediate adsorption to soils and
sediments (Koc = 3.8 x 103) (Lyman et al., 1982).
Kay and Elrick (1967) reported intermediate soil/water partition coefficients (Kp) of 23,
20, and 17 for lindane adsorbed to a sandy loam (organic carbon content (oc) of 3.2%),
loam (oc = 3.6%), and loamy sand (oc = 2.9%) soil, respectively. The corresponding
Koc values are 720,560, and 590, respectively. Foschietal. (1970) reported that lindane
is moderately susceptible to leaching from a low organic soil. After elution with 35
inches of water, 80%, 19%, and 1% of the total lindane recovered from a 60 cm sandy
clay loam (oc = 1.5%) column were recovered in the 0 to 5 cm, 5 to 20 cm, and 20 to
40 cm segments, respectively. No lindane was detected in the 40 to 60 cm segment or
in the leachate.
• Forbis (1986) reported maximum BCFs of 780 (edible tissue) and 1,400 (whole body)
for bluegill sunfish exposed to 0.54 ppb lindane over a 28-day period.
Persistence:
Based upon the hydrolysis rate constants measured by Ellington et al. (1986), lindane
has an intermediate hydrolysis half-life of 14 days at pH 9, and relatively long hydrolysis
half-lives of 210 days at pH 7 and 240 days at pH 5.
ADL (1986) reported a relatively long photodegradative half-life of 48 days for lindane
in water.
Biotransformation is favored in biologically rich, anaerobic environments. Half-lives
range from several days to over a year (Callahan et al., 1979). Under some conditions,
lindane degrades to g-pentachlorocyclohexane (Kirk-Othmer, 1978).
C-227
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HEALTH EFFECTS
Carcinogeni city:
Evidence to determine whether g-hexachlorocyclohexane is a human carcinogen is
limited. The technical grade of lindane (containing approximately 65% a-hexachloro-
cyclohexane) has been shown to cause liver cancer in four strains of mice. Experiments
performed on rats were negative (Ito et al., 1975, Fitzhugh et al., 1950).
' The carcinogenicity data for lindane is presently under review by the U.S. EPA (IRIS,
1989). However, on the basis of mouse carcinogenicity, EPA has previously rated
lindane as a B2 carcinogen (IRIS, 1989).
Mutagenic Activity:
Predominantly negative results have been obtained in mutagenicity testing of lindane.
Tsoneva-Maneva et al. (1971) reported lindane-induced alterations in mitotic activity of
Chinese hamster cells. Chromosomal breaks and gaps in Chinese hamster cells have
also been attributed to lindane exposure (Ishidata and Odashima, 1971). Mutagenic
effects were not observed in tests using bacteria (Buselmaier et al., 1972; Schubert,
1969).
Reproductive Effects:
Lindane has been shown to cause disturbed estrous cycles, decreases in fetal survival,
and reduced numbers of live births in rats; delayed sexual maturation in female rats
(Shtenberg and Mametkulien, 1976); and increases in stillbirths in dogs (Litterst and
Miller, 1975).
Other Toxicological Effects;
Acute lindane poisoning affects the nervous system, causing restlessness, tremors,
unsteady gait, heavy breathing, and convulsions. Violent convulsions are rapid in onset
and generally followed by death or recovery within 24 hours. The probable human oral
lethal dose is 50-500 mg/kg (Klaassen et al., 1986).
• Rats fed diets containing lindane developed mild toxicity-related changes primarily in
the kidneys and liver.
Toxicological Effects Indices:
• Cancer Potency Factor (CPF): 1.33 (mg/kg/d)"1 (PHRED, 1988)
C-128
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Technical Grade CPF: 1.8 (mg/kg/d)"1 (IRIS, 1989)
Reference Dose (RfD): SxlO"4 mg/kg/d (IRIS, 1989)
TWA-TLV (time-weighted average-threshold limit value) for occupational skin ex-
posure: 0.5 mg/m3 (ACGffl, 1986)
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PHYSICAL/CHEMICAL PROPERTIES FOR LINDANE
Value
Reference
Molecular Weight (g/mole):
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Hydrolysis, Kndir'1),
Kbd/Mhr)
Henry's Law Constant,
H @ 25°C (aim • m3/mol):
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc(ml/g):
Fish Bioconcentration Factor, BCF:
290.85
colorless solid
112.9
323.4
1.87
N/A
7.52 0.4 @ 25°C
9.4x10"6 @ 20°C
1.20.2X10"4
198
-7
4.9x10
3.72
3.8 x 103
780 edible tissue,
1400 whole body for
bluegill sunfish
130
Windholtz, 1983
IRIS,1989
Callahan et aL, 1979
IRIS, 1989; Weast, 1979
Verschueren, 1983
Callahan et al., 1979
IRIS, 1989; Windholz,
1983
Ellington et al., 1987
Mills etal., 1985
IRIS,1989
Lymanetal., 1982
Forbis, 1986
C-130
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Arthur D. Little (ADL), Inc. 1986. The Installation Restoration Program Toxicology Guide,
Vol. 2.
Buselmaier, W., G. Rohrbom, and P. Propping. 1972. Mutagenicity, Investigations with Pesticides
in the Host Predicted Assay and Dominant Lethal Test in Mice. Biol. Zbl. 91:311-325.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.P. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitmore, and B. Margin. 1979. Water Related Environmental Fate of 129 Priority
Pollutants. U.S. Environmental Protection Agency, Washington, DC. EPA 440/4-79-029A.
Ellington, J.J., F.E. Stancil, Jr., W.D. Payne, and C. Trusty. 1987. Measurement of Hydrolysis
Rate Constants for Evaluation of Hazardous Waste Land Disposal. Vol. 2. Data on 54 Chemicals.
U.S. Environmental Protection Agency, Athens, GA.
Farm Chemicals Handbook. 1987. Meister Publishing Co., Willoughby, OH.
Fitzhugh, O.G., A.A. Nelson, and J.P. Frawley. 1950. The Chronic Toxicities of Technical Benzene
Hexachloride and Its Alpha, Beta, and Gamma Isomers. J. Pharmacol. Exp Therap. 100:59-66.
Forbis, A.D. 1986. Uptake, Deouration, and Bioconcentration of l4C-Lindane by Bluegill Sunfish
(Lepomis macrochiurusl Analytical Bio-Chemistry Laboratories. Ace. No. 400561-02.
Foschi, S., A. Cesari, et al. 1970. Investigation into Degradation and Vertical Movement of
Agricultural Chemicals in Soil. Notiz. Mai. Pliante 82(37).
Hayes, W.J., Jr. 1982. Pesticides Studied in Man. Waverly Press, Inc. Baltimore, MD.
IRIS. 1989. Integrated Risk Information Service. U.S. Environmental Protection Agency,
Washington, DC.
Ito, N., H. Nagaski, and H. Ade. 1975. Development of Hepatocellular Carcinomas in Rats Treated
with Benzene Hexachloride. J. Natl. Cancer Inst 54:801-805.
Kay, B.D., and D.E. Elrick. 1967. Adsorption and Movement of Lindane in Soils. Soil Sci.
104(5):314-322.
Kirk-Othmer Encyclopedia of Chemical Technology. 1982. 3rd ed. John Wiley and Sons, Inc.,
New York.
C-131
-------
Kirk-Othmer Encyclopedia of Chemical Technology. 1975. 3rd ed. John Wiley and Sons, Inc.,
New York.
Klaassen, CD., M.O. Amdur.andJ. Doull.eds. 1986. Casarett and Doull's Toxicology: The Basic
Science of Poisons. 3rd ed. MacMillan Publishing Co., New York.
Litterst, C.L., and E. Miller. 1975. Distribution of Lindane in Basins of Control and Phenobarbitol
Pretreated Dogs at the Onset of Lindane Induced Convulsions. Bull. Environ. Contam. Toxicol.
13:619.
Lyman, W.J., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods. McGraw-Hill Book Co., New York.
Mills, W.B., D.B. Porcella, M.J. Ungs, S.A. Gherini, K.V. Summers, L. Mok, G.L. Rupp, G.L.
Bowie, and D.A. Haith. 1985. Water Quality Assessment: A Screening Procedure for Toxic and
Conventional Pollutants in Surface and Ground Water. U.S. Environmental Protection Agency,
Athens, GA. EPA 600/6- 85/002a.
Ouellette, R.P., and J.A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book Co.,
New York.
PHRED. 1988. Public Health Risk Evaluation Database. U.S. Environmental Protection Agency,
Office of Emergency and Remedial Response, Washington, DC.
Schubert, A. 1969. Investigations on the Induction of Respiration Deficient Yeast Mutants by
Chemical Herbicides. Z. Allg. Mikrobiol. (Gier.) 9:77.
Shtenberg, A.I., and C. Mametkulian. 1976. The Effect of Gamma-Isomer of
Hexachlorocyclohexane (HCHH) on the State of Sexual Glands in Rats. Vap. Pitan (Rus). 4:62.
U.S. EPA. 1985. Guidance for the Registration of Pesticide Products Containing Lindane as the
Active Ingredient. U.S. Environmental Protection Agency, Office of Pesticide Programs,
Washington, DC. EPA540/RS-86-121.
U.S. EPA. 1986. Superfund Public Health Evaluation Manual. U.S. Environmental Protection
Agency, Office of Solid Waste and Emergency Response, Washington, DC. EPA-540/1-86/060.
U.S. EPA. 1987. Draft of RCRA Facility Investigation (RFI) Guidance. U.S. Environmental
Protection Agency, Office of Solid Waste, Washington, DC. EPA 530/SW-87-001.
U.S. EPA. 1988. Treatabability Manual I. Treatability Data. U.S. Environmental Protection
Agency, Washington, DC. EPA 600/2-82-001 A.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. Van Nostrand
Reinhold, New York.
C-132
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Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. Merck and Co., Rahway, NJ.
C-133
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C-134
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MERCURY
CAS No.: 7439-97-6
CAS Preferred Nomenclature:
Mercury
Formula: Hg, can occur in elemental and
inorganic and organic (methyl) forms
Synonyms and Common Names: Quicksilver
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for human
consumption of fish) (45 FR 79318)
(IRIS, 1989):
0.153ng/L
EPA Ambient Water Quality Criteria
(for protection of aquatic or-
ganismsXIRIS, 1989):
Freshwater Saltwater
Acute, ^ig/L 2.4 . 2.1
Chronic, jxg/L 1.2x10
-2
2.5x10
-2
EPA Drinking Water Standard (for inor-
ganic mercury) (40 CFR 141.11):
Current Maximum Contaminant
Level = 0.002 mg/L
Proposed Maximum Contaminant
Level = 0.002 mg/L
Proposed Maximum Contaminant
Level Goal = 0.002 mg/L
EPA Drinking Water Health Advisories
(for inorganic mercury) (IRIS, 1989)
adulL(70 kg):
long-term and lifetime exposure
Food and Drug Administration Action
Level for Fish (40 FR 45663):
1 ppm*
* FDA Action Levels are for use in inter-
state commerce
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Use Restrictions and Bans;
All uses as a bactericide or fungicide banned after August 1978 except the following (41
FR 16497, 41 FR 26743, 41 FR 36068):
- treatment of textiles for outdoor use
- control of brown mold on new lumber
- in-can preservative in water-based paints
- for exterior use.
SOURCES OF MERCURY
Natural Sources:
Mercury occurs in nature (about 3x10" % of earth's crust) mostly in combination with
sulfur to form more than 25 different minerals. Commercially, the most important
mineral is cinnabar (HgS), from which elemental mercury (Hg) is extracted (USDI,
1985). Mercury can occur as elemental Hg, as well as inorganic and organic (organomer-
curial) forms. It forms complexes with organic ligands, chlorides, and sulfur compounds.
Degassing contributes an estimated 25,000 to 150,000 tons per year to the atmosphere,
compared to about 5,000 tons per year from fossil fuel burning (Klaassen et al., 1986).
Total Mercury Produced:
• 1.6 million pounds (USDI, 1986).
Industrial Uses of Mercury:
Electrical applications including the production of mercury cell batteries, mercury vapor
lamps, thermostats, cathode tubes, and switches.
• Catalyst in the production of urethane polymers for use in plastics.
• Cathode in the electrolytic production of chlorine and caustic soda (U.S. EPA, 1987).
Uses of Mercury In Homes and Businesses:
Batteries for small electronic devices such as calculators, hearing aids, and cameras
Thermometers and barometers
Amalgamated with silver and tin to form tooth fillings.
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Uses as Fungicide/Bactericide (Limited; see Regulatory Status):
A fungicide in some exterior water-based paints
Formerly as a fungicide in paper products and for the protection of seed grain from
mildew
As a preservative in laboratories.
FATE IN ENVIRONMENT
Partitioning:
The fate of mercury depends on its speciation, pH, redox conditions, and presence of
complexing ions including organic ligands, chloride, and sulfhydryl groups (-SH).
Mercury exists in the 0 (metallic), 1+ (mercurous) and 2+ (mercine) forms. The +1
species can hydrolyze to form Hg(OH)2 . The 2+ species can hydrolyze to form the
species Hg(OH)"1", Hg(OH)2, and Hg(OH)3 (Rubin, 1976). The relative amounts of each
species are dependent on pH.
Examples of Hg complexes include Hg(OH)2 under alkaline conditions and HgClz under
acidic conditions. In alkaline sediments under moderately reducing conditions, dimethyl
mercury, which is insoluble and highly volatile, can form. At neutral and lower pH
values, monomethyl mercury can form. Under strongly reducing conditions (e.g., in the
presence of hydrogen sulfide (H2S)), mercury can precipitate as HgS, which is insoluble
(Nriagu, 1979).
Persistence:
Mercury is readily sorbed to soil organic matter, clays, and hydrous metal oxides with
the exception of some organic chloride-Hg complexes, e.g. CHsHgCl. Methylmercuric
chloride has a Kow value of about 2.0 (Medeiros, 1980). Mercury is also bioaccumu-
lated. BCF values for inorganic mercury range from 1,800 to 5,000. BCF values for
organic mercury are higher (10,000 to 82,000). Most of the mercury in fish is present
in the methyl form.
Mercury is biologically methylated and in limited amounts may be lost from soils by
volatilization (Lyman et al., 1987).
HEALTH EFFECTS
Carcinogenic! ty:
Mercury has not been shown to cause cancer in humans.
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Rats have developed local tumors at the point of injection of metallic mercury (U.S.
EPA, 1984).
• The EPA designates mercury as a Group D chemical, not classified (U.S. EPA, 1984).
Mutagenic Activity:
Methyl mercury was shown to be a weak mutagen in experiments with fruit flies (U.S.
EPA, 1981). Mercuric salts were not mutagenic in tests using nonmammalian cells, but
results using mammalian cells were inconclusive.
Reproductive Effects;
Both inorganic and organic forms of mercury are toxic to developing fetuses. The fetal
nervous system is particularly sensitive, with mercury disrupting and delaying nerve cell
development. Fetuses chronically exposed (low doses over long time periods) to organic
mercury are born mentally retarded and exhibit cerebral palsy-like symptoms (Marsh,
1987).
Other Toxicologicai Effects;
Mercury toxicity in humans produces a number of different symptoms depending on
whether the exposure is of a short-term, high-dose (acute) type or long-term, low-dose
(chronic) type. Elemental mercury vapor produces an acute pneumonitis. Inorganic
mercury salts can cause acute gastrointestinal distress and renal failure. (The lethal dose
of mercuric chloride in humans is 1 to 4 g.) Both of these forms, as well as the organic
mercurials, produce neurologic effects after chronic exposure to mercury. Eye and skin
irritation can also occur (Sittig, 1985).
Symptoms such as numbness of the extremities, tremors, spasms, personality and
behavior changes, difficulty in walking, deafness, blindness, and death have been
associated with the long-term ingestion of mercury-contaminated fish. (U.S. EPA,
1981).
Toxicologicai Effects Indices;
RfD (Reference Dose): 0.002 mg/kg/day for inorganic mercury compounds and 0.0003
mg/kg/day for alkyl (organic forms) or mixed alkyl-inorganic mercury (U.S. EPA,
1986).
. TWA-TLV (Time-weighted average, threshold limit value for occupational exposures):
0.01 mg/m alkyl mercury for skin exposure and 0.05 mg/m for vapor exposure
(ACGIH, 1986).
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
200.6
liquid
-38.87
356.72
1 3.534 (25°C)
N/A
0.056 (25°C)
2x10-3 (25°C)
Windholz, 1983
Windholz, 1983
Windholz, 1983
Windholz, 1983
Windholz, 1983
Windholz, 1983
Henry's Law Constant @ 25°C
(atm • m /mol):
Hydrolysis Rates:
Log (Octanol-Water Partition
Coefficient), log Kow:
Partition Coefficient, Kp (mL/g):
(Inorganic Hg)
Fish Bioconcentration Factor,
BCF:
Hgo 6.97xlO'3
(CH3)2Hg = 7.45xl03
Hg(OH)2 = 7.2xlO'8
1+and 2+forms
hydrolyze, specific rate
constants not found
CH3HgCl =0.3
= 0.4
1,000-1x106 I/kg
1800-4994
(inorganic)
10,000-81,670
(organic)
5,500
Lindquist et al., 1984
Lindquist et al., 1984
Rubin, 1976
Medeirosetal.,1980
Halbach, 1985
Gherini and
Rajashenkar, 1975
U.S. EPA, 1985
U.S. EPA, 1985
Olson etal., 1975
U.S. EPA, 1980
C-139
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Bloom, N. 1988. Determination of Methylmercury in Water at the Femtomolar (pg/L) Level
Following Aqueous Phase Ethylation with Sodium Tetraethylborate. EPRJ Project Report, Palo
Alto, CA.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979. Water-Related
Environmental Fate of 129 Priority Pollutants, Vol. II. U.S. Environmental Protection Agency,
Office of Water Planning and Standards, Washington, DC. EPA-440/79-029b.
Gherini, S.A., and P. Rajashenkar, 1975. A Study of the Water Quality Impact of the Implemen-
tation of Air Quality Standards. U.S. Environmental Protection Agency, Washington, DC. Contract
No. 68-01-2243.
Halbach, S. 1985. The Octanol Water Distribution of Mercury Compounds. Short Communi-
cation. Arch. Toxicol. 57: 139-141.
IRIS. 1989. Integrated Risk Information System Database. U.S. Environmental Protection Agen-
cy, Washington, DC.
Kirk-Othmer Encyclopedia of Chemical Technology. 1982. 3rd ed. John Wiley and Sons, Inc.,
New York.
Klaassen, C.D., M.D. Amdur, and J. Doull, eds. 1986. Casarett and Doull's Toxicology, The Basic
Science of Poisons. 3rd ed. Macmillan Publishing Co., New York.
Lindquist, O., A. Jernelov, K. Johansson, and H. Rodhe. 1984. Mercury in the Swedish Environ-
ment: Global and Local Sources. Report No. 91-7590-154-4. Prepared for the National Swedish
Environment Board.
Lyman, W.L., I. Bodek, W.F. Reehl, and D.H. Rosenblatt. 1987. Methods for Estimating
Physicochemical Properties of Inorganic Chemicals of Environmental Concern. U.S. Army Medi-
cal Research and Development Command, Fort Detrick, MD. Contract No. DAMD 17-83-C-3274.
Marsh, D.O. 1987. Dose-Response Relationships in Humans: Methyl Mercury Epidemics in Japan
and Iraq. In: The Toxicity of Methyl Mercury. (C.U. Eccles and Z. Annau, eds). Johns Hopkins
University Press, Baltimore, MD.
Medeiros D., L. Cadwell, and R. Preston. 1980. A Possible Physiological Uptake Mechanism of
Methylmercury by the Marine Bloodworm (Glycera dibranchiata). Bull. Environm. Contam.
Toxicol. 24:97-101.
C-140
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Nriagu, J.O., ed. 1979. The Biogeochemistry of Mercury in the Environment. Elsevier/North-Hol-
land Biomedical Press, New York.
Olson, G.F., D.J. Mount, V.M. Snarski, and T.W. Thorslund. 1975. Mercury Residues in Fathead
Minnows, Pimpehales promelas Rafmesque, Chronically Exposed to Methyl Mercury in Water.
Bull. Environ. Contam. Toxicol. 14(2).
Rubin, A.J.,ed. 1976. Aqueous-Environmental Chemistry of Metals. Ann Arbor Science Publish-
ers, Inc., Ann Arbor, MI.
Sittig, M. 1985. Handbook of Toxic and Hazardous Chemicals and Carcinogens. 2nd ed. Noyes
Publications, Park Ridge, NJ.
U.S. Department of the Interior (USDI), Bureau of Mines. 1985. Minerals Facts and Problems.
1985 ed. Bulletin 675. U.S. Government Printing Office, Washington, DC.
U.S. Department of the Interior (USDI), Bureau of Mines. 1986. Mineral Commodity Summaries
1986. U. S. Government Printing Office, Washington, DC. Publication No. 1986-606-225.
U.S. EPA. 1980. Ambient Water Quality Document U.S. Environmental Protection Agency,
Washington, DC. EPA 440/5-80 Series.
U.S. EPA. 1981. An Exposure and Risk Assessment for Mercury. U.S. Environmental Protection
Agency, Office of Water Regulations and Standards, Washington, DC. EPA-440/4-85-011.
U.S. EPA. 1984. Health Effects Assessment for Mercury. U.S. Environmental Protection Agency,
Office of Emergency and Remedial Response, Washington, DC. EPA-540/1-86-042.
U.S. EPA. 1985. Ambient Aquatic Life Water Quality Criteria for Mercury. U.S. Environmental
Protection Agency, Office of Research and Development, Duluth, MM. PB85-22745.
U.S. EPA. 1986. Superfund Public Health Evaluation Manual. U.S. Environmental Protection
Agency, Office of Solid Waste and Emergency Response, Washington, DC. EPA-540/1-86/060.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck & Co., Rahway, NJ.
C-141
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MERCURY
OBSERVATIONS AND EFFECTS ON PISCIVOROUS WILDLIFE
Mercury is toxic to mink at diet concentrations of 1 to 2 ppm (Wren, 1989). This finding is consistent
with the lethal dose reported by the State of Wisconsin (WDHSS, 1988).
The effects of mercury on piscivorous wildlife are summarized in the following table:
Effects of Mercury Concentrations on Piscivorous WildJife
Animal Concentration Effect Source
Mink l.Omg/kg Death WDHSS, 1988
(diet)
Mink 1-2 ppm (diet) Death Wren, 1989
River Otter >2.0mg/kg Death WDHSS, 1988
(diet)
REFERENCES
WDHSS (Wisconsin Department of Health and Social Services). 1988. Technical Support Docu-
ment for Chapter MR 105 of the Wisconsin Administrative Code. Division of Health, Madison,
WI.
Wren, C.D. 1989. Personal communication. BAR. Environmental. Nicholas Beaver Park, RR3,
Guelph, Ontario, Canada.
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METHOXYCHLOR
CAS No.: 72-43-5
CAS Preferred Nomenclature:
Benzene, l,l'-(2,2,2-trichloroethylidene)
bis (4-methoxy)-
Empirical Formula:
Synonyms and Common Names:
- Methoxy-DDT - Marlate
- DMDT - Dianisyl trichloroethane
- Maralate - Dimethoxy-DT
- p.p'-Dimethoxydiphenyl - Metox
- trichloroethane
REGULATORY STATUS
C16H15CI3°2
Standards and Criteria:
• EPA Water Quality Criteria (for human
consumption of water and fish)(U.S.
EPA, 1987):
100ng/L
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
Freshwater Saltwater
Acute, jig/L — —
Chronic, ng/L 0.03 0.03
EPA Drinking Water Health Advisories
(U.S. EPA, 1987; PHRED, 1988):
Child (10 kg):
1 day exposure = 6.0 mg/L
10 day exposure = 2.0 mg/L
long-term exposure = 0.5 mg/L
adult (70 kg):
long-term exposure = 2.0 mg/L
lifetime exposure = 0.4 mg/L
EPA Tolerance Levels for Food (40
CFR180.120):
l-14ppm
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• EPA Drinking Water Standards (50 FR • Food and Drug Administration Action
46936; IRIS, 1989): Level for Fish
Current Maximum Contaminant None established at present
Level = 0.1 mg/L
Proposed Maximum Contaminant
Level = 0.4 mg/L
Proposed Maximum Contaminant
Level Goal = 0.4 mg/L
Use Restrictions and Bans:
None found.
SOURCES OF METHOXYCHLOR
Total Methoxychlor Produced:
Methoxychlor is an organochlorine pesticide with a similar chemical structure to DDT.
It was first introduced in 1945.
In 1971, 9.9 million pounds were produced by the companies Chemical Formulations,
DuPont, and Prentiss (Ouellette and King, 1977).
• By 1982, very little methoxychlor was being produced. Current data are unavailable,
but the volume produced by the two listed producers, Drexel Chemical Company and
Kincaid Enterprises, is likely to be small (SRI, 1986; Green et al., 1987).
Uses of Methoxychlor;
Like DDT, methoxychlor is effective against a wide range of insects that affect fruits,
vegetables, forage crops, and livestock (Hayes, 1982; McEwen and Stephenson, 1979).
• Hundreds of products containing rnethoxychlor are registered for insect control in foliar
treatment, dormant application, seed or soil treatment, and post-harvest application of
many crops (U.S. EPA, 1986).
Methoxychlor is used primarily to control houseflies, blackflies, and mosquitoes, in
areas of human habitation including hotels, bakeries, meat processing plants, flour mills,
and dairy barns (Worthing, 1983; U.S. EPA, 1986; McEwen and Stephenson, 1979).
Mosquito control uses also include methoxychlor treatment of stagnant ponds, streams,
and other aquatic recreation areas (U.S. EPA, 1986).
• Methoxychlor is also used in mothproofing (U.S. EPA, 1986).
Other Sources: None found.
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FATE IN ENVIRONMENT
Partitioning:
Based on its physical/chemical properties, methoxychlor is estimated to be volatile (H
= 1.5x10" atm • m /mole), strongly sorbed to soil (Kow= 47,900) and has a high potential
for bioaccumulation (BCF = 8,300), although some empirical data show a more moderate
potential for bioaccumulation.
Persistence:
Methoxychlor is considered to be moderately biodegradable (Wolfe et al., 1977).
Methoxychlor is estimated to have a half-life for direct photolysis in water (in the central
U.S.) of 4.5 months, and also undergoes indirect photolysis (Wolfe et al., 1977);
photolysis half-lives of 2-5 hours have been observed in river water (TDB, 1985). The
rate of hydrolysis has been found to be independent of pH under environmental
conditions, with a half-life of about 1 year at 27°C (Wolfe et al., 1977).
HEALTH EFFECTS
Carcinogenic! ty:
• The evidence for methoxychlor carcinogenicity is inconclusive, according to the EPA
Carcinogen Assessment Group's review of a National Cancer Institute Bioassay (HSDB,
1988). EPA has not yet classified its carcinogenic potential (PHRED, 1988).
No cancers were observed in four experiments with rats fed 1,000 mg/kg or in one mouse
feeding experiment (IARC, 1979).
Mutagenic Activity:
Methoxychlor was found not to be mutagenic in bacterial and yeast cell assays as well
as in a mouse dominant lethal test (IARC, 1979).
It was weakly positive in a mammalian cell transformation assay (HSDB, 1988).
Reproductive Effects:
Adverse reproductive effects have been reported. In studies with rats consuming a
dietary level of 1% methoxychlor has produced testicular atrophy, inhibition of sper-
matogenesis, and arrested folliculogenesis (IARC, 1979; HSDB, 1988).
C-145
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Methoxychlor is also reported to be fetotoxic in rats, causing wavy ribs, but only at doses
(100-400 mg/kg) causing maternal toxicity. There is no evidence of any teratogenesis
at lower doses (IARC, 1979; Hayes, 1982; HSDB, 1988).
Other Toxicological Effects:
In man, acute, short-term, high doses, up to 2 mg/kg/day, have not been shown to cause
any adverse effects.
Animals exposed to high doses of methoxychlor have exhibited a variety of symptoms.
Dogs fed 2,000 or 4,000 mg/kg for 2 years developed nervousness, tremors and
convulsions. Rats had similar central nervous system effects as well as severely retarded
growth (Hayes, 1982; HSDB, 1988). Kidney injury and uterine and mammary enlarge-
ment were observed in pigs, while monkeys had liver and intestinal damage (IARC,
1979; HSDB, 1988).
Toxicological Effects Indices:
Adjusted Reference Dose for drinking water: 1.7 mg/L (50 FR 46936).
TWA-TLV (time-weighted average, threshold limit value) for occupational exposure:
10rag/m3(ACGIH, 1986).
Oral LD50: rat, 5-7 mg/kg; mouse, 1.8 mg/kg (IARC, 1979; HSDB, 1988).
C-146
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant,
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H @ 25°C (atm • m3/mol):
345.7
colorless crys-
tals, solid
89
416 (calc.)
1.41 (25°C)
N/A
IxlO'1
1.3xlO"6(20°C)
(calc.)
1.5xlO"5(calc.)
Windholz, 1983
Hayes, 1982
Worthing, 1983
Lymanetal., 1982
Hartley & Kidd, 1983
PHRED, 1988
Lymanetal., 1982
Lyman et al., 1982
Log (Octanol- Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, K0c(mL/g):
Fish Bioconcentration Factor, BCF:
4.68
8xl04
1.9xl02-1.6xl03
(exptl.)
8300
PHRED, 1988
PHRED, 1988
Kenaga, 1980
PHRED, 1988
C-147
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Green, M.B., G.S. Hartley, and T.F. West. 1987. Chemicals for Crop Improvement and Press
Management. 3rd ed. Pergamon Press, Oxford, England.
Hartley, D., and H. Kidd, eds. 1983. The Agrochemicals Handbook. The Royal Society of
Chemistry, Nottingham, England.
Hayes, W.J., Jr. 1982. Pesticides Studied in Man. Waverly Press, Inc., Baltimore, MD.
HSDB. 1988. Hazardous Substances Data Base. Computer printout: Methoxychlor. Retrieved
May 16,1988. National Library of Medicine, Bethesda, MD.
I ARC (International Agency for Research on Cancer). 1979. I ARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS. 1989. Integrated Risk Information System. U.S. Environmental Protection Agency,
Washington, DC.
Kenaga, E.E. 1980. Correlation of Bioconcentration Factors of Chemicals in Aquatic and Ter-
restrial Organisms with Their Physical and Chemical Properties. Environ. Sci. Technol. 14:553-
556.
Lyman, W.L., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods. McGraw-Hill Book Co., New York.
Matsamura, F. 1985. Toxicology of Insecticides. 2nd ed. Plenum Press, New York.
McEwen, F.L., and G.R. Stephenson, 1979. The Use and Significance of Pesticides in the
Environment. John Wiley and Sons, New York.
Ouellette, R.P., and J.A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
PHRED. 1988. Public Health Risk Evaluation Database. U.S. Environmental Protection Agency,
Office of Emergency and Remedial Response, Washington, DC.
SRI (Stanford Research Institute). 1986. Directory of Chemical Producers. Stanford Research
Institute, Menlo Park, CA.
C-148
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Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Committee.
U.S. EPA. 1986. Computer retrieval from Office of Pesticides for registered sites and number of
products registered.
U.S. EPA. 1987. Methoxychlor Health Advisory. U.S. Environmental Protection Agency, Office
of Drinking Water, Washington, DC.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs and Biologicals.
10th ed. Merck & Co., Rahway, NJ.
Wolfe, N.L., R.G. Zepp, D.F. Paris, G.L. Baughman, and R.C. Hollis. 1977. Methoxychlor and
DDT Degradation in Water: Rates and Products. Environ. Sci. Technol. 11:1077-1081.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British Crop
Protection Council, Croydon, England.
C-149
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C-150
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MIREX
CAS No.: 2385-85-5
CAS Preferred Nomenclature:
1,3,4-Metheno- iH-cyclobuta(cd)
pentalene, 1,1 a,2,2,3,3a,4,5,5,5a,5b,6-
dodecachloro-octahydro-
Empirical Formula: C10C112
Synonyms and Common Names:
- Dechlorane - Perchloropentacyclodecane
- Hexachlorocyclo- - Perchlorodi-homocubaane
- pentadiene dime - Ferriamicide
- Paramex
- Dodecachlorooctahydro-1,3,4-metheno-2H-cyclobutal (cd) pentalene
a
C,0C',2
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for human
consumption offish):
None established at present
EPA Ambient Water Quality Criteria
(for protection of aquatic or-
ganismsXIRIS, 1989):
Freshwater Saltwater
Acute, jag/L — —
Chronic, ng/L 0.001 0.001
EPA Drinking Water Health Advisories:
None established at present
Food and Drug Administration Action
Level for Fish (43 FR 14736):
0.10 ppm*
FDA Action Levels are for use in inter-
state commerce
• EPA Drinking Water Standards Maxi-
um Contaminant Level:
None established at present
Use Restrictions and Bans;
• All registered uses were cancelled as of 1977 (41 FR 56703).
C-151
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All existing stock was not to be sold, distributed, or used after June 30, 1978 (NAS,
1978).
SOURCES OF MIREX
Total Mirex Produced:
3.3 million pounds were produced by Hooker Chemicals and Plastics Co. between 1959
and 1975 (Suta, 1977). Twenty-five percent was used as a pesticide and the remainder
as a fire retardant. Commercial production stopped in 1978.
Uses of Mirex:
Mirex was used primarily for the control of the imported fire ant in eight southeastern
States from 1962 to 1975. Approximately 250,000 kg were used to treat 14 million acres
(NAS, 1978; Kutz et al., 1985). Mirex was also used in Hawaii to control the pineapple
mealy-bug (Suta, 1977).
Mirex was used as a fire retardant in plastics, rubber, paint, paper, and electrical products
(Kutz et al., 1985; Windholz, 1983).
Other Sources: None identified.
FATE IN ENVIRONMENT
Partitioning:
• Based on its physical/chemical properties, mirex is predicted to have a relatively low
volatility from water (H=2.2 x 10-5 atm • m3/mol at 25°C), a low volatility from surface
soil (P/S Koc = 1.3 x 10 mm Hg • L/mg, corresponding to an estimated volatilization
half-life of >30 years), a strong adsorption to soils and sediments (Kow = 199,500 and
Koc = 2.4 x 107), and a high potential for bioaccumulation (BCF = 2.6 x 103 - 4.1 x 104).
Persistence:
Mirex is thermally and chemically very stable and resistant to biodegradation (Bell et
al., 1978). There is some evidence that mirex can be biotransformed into chlordecane
(Kepone) in soil (Klaassen et al., 1986). However, mirex applied at I Ib/acre to a
Mississippi soil was reported to have a 50% dissipation time of >2.5 years (State of
Mississippi, 1982 as cited by EPA, 1982). Mirex appears to be persistent in the aquatic
environment as evidenced by no reported significant decreases in the concentration of
mirex in a water/sediment system over a 130-day period (State of Mississippi, 1982 as
cited by EPA, 1982).
C-152
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Photolysis of mirex in water can occur, but at a slow rate (Verschueren, 1983). The rate
determined experimentally using river water in sunlight was 0.0042/day (Smith et al.,
1978).
HEALTH EFFECTS
Card nogeni city:
Hepatomas and liver-cell carcinomas were observed in mice and rats fed mirex in their
diet Mirex has been classified as a probable human carcinogen (2b) by IARC (1979).
The carcinogenic data for mirex are presently under review by the U.S. EPA (IRIS,
1989).
• The results of one animal cancer study (Ulland et al., 1977) have been analyzed using a
dose-response model not typically used by EPA. This one-hit model was used to derive
a possible carcinogenic potency factor of 0.354 (mg/kg/day)" (U.S. EPA, 1982).
Mutagenic Activity:
Negative in dominant lethal assay in mice (IARC, 1979). Not generally active in
short-term tests (WHO, 1984).
Reproductive Effects:
Some studies have reported that mirex is fetotoxic (25 mg/kg) and teratogenic (causing
cleft palate, heart defects, cataracts) to rats (6 mg/kg/day). Also, fewer and less viable
offspring were born to mice fed 1.8 mg/kg for 3 months (WHO, 1984; Klaassen et al.,
1986). Voles also had decreased pup survival when exposed to mirex in the diet (IRIS,
1988). Further studies must be done to confirm these results (IRIS, 1988).
Other Toxicological Effects;
Acute hepatotoxicity (liver toxicity) was noted in rats after oral administration of mirex
(IARC, 1979). Liver hypertrophy observed in rats fed 1 mg/kg for 14 days (WHO,
1984).
Chickens exposed to mirex had depressed levels of certain types of antibodies (IgG and
IgM) (Klaassen et al., 1986).
Toxicological Effects Indices:
• Cancer Potency Factor (CPF): 1.8 (mg/kg/day)'1 (HEAST, U.S. EPA, 1989).
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Reference Dose (RfD): 2 x 10"6 mg/kg/day (IRIS, 1989).
Oral LDso: rat, 740 mg/kg (IARC, 1979).
C-154
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 2°C:
Melting Point (°C):
Boiling Point (°C):
Density/Specific Gravity:
Acid Dissociation Constant
Water Solubility, S (mg/L):
Vapor Pressure, P (ram Hg):
Henry's Law Constant,
H @ 25°C (atm • m3/mol):
Log (Octanol- Water Partition
Coefficient), log
Soil Adsorption Coefficient, KOC (mL/g):
Fish Bioconcentration Factor, BCF:
545.6
solid, snow-
white crystals
485 (decomp.)
N/A
N/A
N/A
0.2 (24°C)
6xlO~6 (25°C)
2.2xlO"5
5.3
2.4x107
2.6xl03-4.1xl04
(exptl.)
18,100
Windholz, 1983
Verschueren, 1983
Windholz, 1983
PHRED, 1988;
Verschueren, 1983
TDB, 1985
Lymanetal, 1982
Lymanetal., 1982
PHRED, 1988
Verschueren, 1983
PHRED, 1988
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REFERENCES
Bell, M.A., R.A. Ewing, G.A. Lutz, and E.G. Alley. 1978. Review of the Environmental Effects
of Pollutants: I. Mirex and Kepone. (NTIS Abstract). EPA Health Effects Research Laboratory,
Cincinnati, OH. EPA/600/1-78-013. NTIS PB80-125958.
Green, M.B., G.S. Hartley, and T.F. West. 1987. Chemicals for Crop Improvement and Pest
Management. 3rd ed. Pergamon Press, Oxford, England.
IARC (International Agency for Research on Cancer). 1979. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS. 1988. Integrated Risk Information System. U.S. Environmental Protection Agency,
Washington, DC.
IRIS. 1989. Integrated Risk Information System. U.S. Environmental Protection Agency,
Washington, DC.
Klaassen, C.D., M.D. Amdur, and J. Doull, eds. 1986. Casarett and Doull's Toxicology, The Basic
Science of Poisons. 3rd ed. Macmillan Publishing Co., New York.
Kutz, F.W., S.C. Strassman, C.R. Stroup, J.C. Carra, C.C. Leininger, D.L. Watts, and C.M.
Sparacino. 1985. The Human Body Burden of Mirex in the Southeastern United States. J. Toxicol.
and Environ. Health, 15:385-394.
Lyman, W.T., W.E. Reehl, D.E. Rosenblatt. 1982. Handbook of Chemical Estimation Methods.
McGraw-Hill Book Co., New York.
NAS (National Academy of Sciences). 1978. Kepone/Mirex/Hexachlorocyclopentadiene: An
Environmental Assessment. National Academy of Sciences, National Research Council,
Washington, DC. NTIS PB 280289.
Ouellette, R.P., and J.A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
PHRED. 1988. Public Health Risk Evaluation Database. U.S. Environmental Protection Agency,
Office of Emergency and Remedial Response, Washington, DC.
State of Mississippi. 1982. Environmental Fate Studies in support of an emergency request for use
of mirex on fire ants.
Suta, B.E. 1977. Human Population Exposures to Mirex and Kepone. EPA-600/1-78-045.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Committee.
C-156
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Ulland, B.M., N.P. Page, R.A. Squire, E.K. Weisburger, and R.L. Cypher. 1977. A carcinogenicity
assay of mirex in Charles River CD rats. J. Natl. Cancer InsL 58:133-140.
U.S. EPA. 1982. Office of Pesticides Programs Reviews of Environmental Fate Studies submitted
by the State of Mississippi in support of an emergency request for use of mirex on fire ants.
U.S. EPA. 1989. Health Effects Assessment Summary Tables (HEAST). U.S. Environmental
Protection Agency, Office of Solid Waste and Emergencies Response, Washington, DC.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck & Co., Rahway, NJ.
WHO (World Health Organization). 1984. Mirex. Environmental Health Criteria 44:1-70.
Worthing, C.R., ed. 1983. The Pesticide Manual: A world compendium. 7th ed. British Crop
Protection Council, Croydon, England.
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MIREX
OBSERVATIONS AND EFFECTS ON PISCIVOROUS WILDLIFE
EPA banned the use of mirex in 1978, in part because of its detrimental effects on fish and wildlife
(Eisler, 1985). Eisler's review provides a good summary of mirex hazards to nontarget species and
concentrations found in wildlife.
High concentrations of mirex in eggs were blamed for the low reproductive success of Lake Ontario
herring gulls in the early I970's (Oilman et al., 1977,1978). In 1975, the reproductive success of
herring gulls in Lake Ontario colonies was only one-tenth that of colonies on the other four Great
Lakes (Oilman 1977, 1978). The mean concentration of mirex in eggs from one Lake Ontario
Lake Ontario was the only Great Lake contaminated with mirex (Kaiser, 1978; NAS, 1978), and
both Oilman et al. (1977, 1978) and Norstrom et al. (1980) suggested that a high percentage of the
mirex in the eggs originated from Lake Ontario fish.
Differences in feeding habits have been related to differences in mirex concentrations in eggs of
three bird species in Maine: the common eider, herring gull, and black-backed gull (Szaro et al.,
1979). Eggs of the black-backed gull had levels of DDE and PCBs greater than those in the eggs
of the herring gull, which, in turn, were higher than those in the eggs of the common eider. Mirex
was detected only in the eggs of the black-backed gull (up to 0.26 ppm) (Szaro et al., 1979). Szaro
et al. (1979) attributed the higher levels of contaminants in the blacked-back gull to its predatory
and scavenging feeding habits.
Based on a study of herring gulls and predation on alewives, Norstrom et al. (1978) estimated a
bioaccumulation factor of 50 for mirex in gull eggs.
Mirex residues have been detected in the brains and tissues of various piscivorous birds collected
nationwide, such as bald eagles (Barbehenn and Reichel, 1981) and herons (Ohlendorf et al., 1981).
However, in both studies, mirex concentrations were recorded at nonhazardous levels.
Mirex has also been detected in eggs of the American crocodile (up to 0.02 ppm) (Hall et al., 1979).
The State of New York proposed a fish flesh criterion for mirex at 0.33 ppm to protect piscivorous
wildlife. This criterion was based on studies of rats (Gaines and Kimbrough, 1969), prairie voles
and old field mice (Hyde, 1972), and mallards (Newell et al., 1987; Schafer et al., 1983).
The effects of mirex on piscivorous wildlife are summarized in the following table:
C-I58
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Effects of Mirex Concentrations on Piscivorous Wildlife
Animal Concentration Effort Source
Piscivorous 0.33 ppm (diet) estimated Newell et al.
Wildlife NOEL 1987
0.373 ppm (diet) cancer risk Newell et al.
of 10"2 1987
REFERENCES
Barbehenn, K.R., and in.L. Reichel. 1981. Organochlorine Concentrations in Bald Eagles:
Brain/Body Lipid Relations and Hazard Evaluation. J. Toxicol. Environ. Health 8:325-330.
Eisler, R. 1985. Mirex Hazards to Fish, Wildlife and Invertebrates: A Synoptic Review. U.S. Fish
Wildl, Serv. Biol. Rep. 85(1.1).
Gaines, T., and R. Kimbrough. 1969. The Oral Toxicity of Mirex in Adult and Suckling Rats.
Toxicol. Appl. Pharmacol. 14:631-632. (As cited in Newell et al.,1987)
Oilman, A.P., G.A. Fox, D.B. Peakall, S. M. Teeple, T.R. Carroll and G.T. Katmes. 1977.
Reproductive Parameters and Egg Contaminant Levels of Great Lakes Herring Gulls. J. Wildl.
Manage. 41:458-468. (As cited in Eisler, 1985)
Oilman, A.P., D. J. Hallett, G.A. Fox, L.J. Allan, W.J. Learning, and D.B. Peakall. 1978. Effects
of Injected Organochlorines on Naturally Incubated Herring Gull Eggs. J. Wildl. Manage. 42:484-
493. (As cited in Eisler, 1985)
Hall, R. J., T. E. Kaiser, in. B. Robertson, Jr., and P.C. Patty. 1979. Organochlorine Residues in
Eggs of the Endangered American Crocodile (Crocodvlus acutus). Bull. Environ. Contam. Toxicol.
23:87-90.
Hyde, K. 1972. Studies of the Responses of Selected Wildlife Species to Mirex Bait Exposure.
Ph.D. thesis, Louisiana State University, Baton Rouge. (As cited in Eisler, 1985)
Kaiser, K.L.E. 1978. The Rise and Fall of Mirex. Environ. Sci. Technol. 12:520-528. (As cited
in Eisler, 1985)
NAS (National Academy of Science). 1978. Scientific and Technical Assessments of Environ-
mental Pollutants. Kepone/Mirex/Hexachlorocyclopentadiene: An Environmental Assessment.
National Academy of Science, Washington, DC. (As cited in Eisler, 1985)
C-159
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Newell, A.J., D.W. Johnson, and L.K. Allen. 1987. Niagara River Biota Contamination Project:
Fish Flesh Criteria for Piscivorous Wildlife. NY Dept. Environ. Conserv., Div. Fish Wild!., Bureau
Environ. Protection. Tech. Rep. 87-3.
Norstrom, R.J., D.J. Hallett, and R.A. Bonstegard. 1978. Coho Salmon (Oncorhvnchus kisutch)
and Herring Gulls CLanis arsentatus) as Indicators of Organochlorine Contamination in Lake
Ontario. J. Fish. Re. Board Canada 35:1401-1400. (As cited in Eisler, 1985)
Norstrom, R.J., D.J. Hallett, F.I. Onuska, and M.E. Comba. 1980. Mirex and Its Degradation
Products in Great Lakes Herring Gulls. Environ. Sci. Technol. 14:860-866. (As cited in Eisler,
1985)
Ohlendorf, H.M., D.M. Swineford, and L.N. Locke. 1981. Organochlorine Residues and Mortality
of Herons. Pest. Monit. J. 14(4): 125-135.
Schafer, E., Jr., W. Bowles, and J. Hulbert. 1983. The Acute Oral Toxicity, Repellency and Hazard
Potential of 998 Chemicals to One or More Species of Wild and Domestic Birds. Arch. Environ.
Contain. Toxicol. 12:335-382. (As cited in Newell et al., 1987)
Szaro, R.C., N.C. Coon, and E. Kolbe. 1979. Pesticide and PCB of Common Eider, Herring Gull
and Great Black-Backed Gull Eggs. Bull. Environ. Contam. Toxicol. 22:394-399
Weseloh, D.V., P. Mineau, and D.J. Hallett. 1979. Organochlorine Contaminants and Trends in
Reproduction in Great Lakes Herring Gulls, 1974-1978. Trans. N. Am. Wildl. Nat. Resour. Conf.
44:543-557.
C-160
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NITROFEN
CAS No.: 1836-75-5
CAS Preferred Nomenclature:
Benzene, 2,4-dichloro-2-(4-nitrrophenoxy)-
et
'NO,
C12H7CI2N02
Empirical Formula: Ci2H?Cl2NO2
Synonyms and Common Names:
- NIP
- Nitrophen
- F-W-925
- TOKE-25
- Nitrochlor
- 2,4-Dichlorophenyl-.para.-nitrophenyl ether
REGULATORY STATUS
Standards and Criteria:
• EPA Water Quality Criteria (for human • EPA Drinking Water Health Advisories:
consumption of fish): None established at present
None established at present
• EPA Ambient Water Quality Criteria • EPA Tolerance Levels (50 FR 37850)
(for protection of aquatic organisms): All tolerances revoked 9/18/85
None established at present
• EPA Drinking Water Standard Maxi- • Food and Drug Administration Action
mum Contaminant Level: Level for Fish:
None established at present None established at present
Use Restrictions and Bans:
All uses of nitrofen, a selective herbicide, were cancelled voluntarily by 1984 (40 FR
2151).
SOURCES OF NITROFEN
Total Nitrofen Produced:
Nitrofen is no longer produced or sold in the United States (Ouellette and King, 1977).
C-161
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Uses of Nitrofen:
Prior to 1984, nitrofen was used as a selective herbicide to control weeds in various
crops, including vegetables, cereal, grains, sugar beets, rice, and some ornamental plants
(Worthing. 1983).
Other Sources: None identified.
NITROFEN OBSERVED IN THE ENVIRONMENT
No data available.
FATE IN ENVIRONMENT
Partitioning:
Based on estimates of physical/chemical properties, nitrofen strongly sorbs to soil (Kow
=339,000) and has a high potential for bioaccumulation (BCF estimated as 1.6x10 ).
Nitrofen volatilizes at a low rate (H = 3.1x10-6 atm • m /mol).
Persistence:
Nitrofen can biodegrade under both aerobic and anaerobic conditions. In one experi-
ment, a 70% loss of nitrofen present in soil at a concentration of 10 ppm (incubated at
30°C) occurred after 10 days, which represents a decay rate of 0.12/day. Nitrofen
applied in a flooded paddy field (anaerobic conditions) had a half-life of 16 days (TDB,
1986). Under these conditions, the nitro group (NO2) is reduced to NH2 (Grover, 1988).
Nitrofen solutions and aqueous suspensions can undergo rapid photolysis (TDB, 1986).
HEALTH EFFECTS
Cardnogenidty:
• The U.S. EPA has not classified the potential carcinogenicity of nitrofen. However,
IARC (1983) considers that the available information is sufficient evidence to identify
nitrofen as carcinogenic in experimental animals.
Mice fed nitrofen displayed a significant increase in the incidence of liver carcinomas
(IARC, 1983).
• Nitrofen administered in high doses to rats also resulted in various types of tumors at
different anatomical sites (IARC, 1983).
C-162
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Mutagenic Activity:
Nitrofen was found to be mutaeenic in Salmonella typhimurium. Negative results were
obtained when nitrofen was tested in Bacillus subtilis and rat and mouse bone cells
(IARC, 1983).
Reproductive Effects:
In rats, nitrofen increased the incidence of stillbirths and reduced the survival rate of
newboms (IARC, 1983). Poor survival was due to heart, diaphragm, and kidney
malformations, as well as lung immaturity (IARC, 1983; Klaassen et al., 1986).
• Nitrofen produced similar birth defects in mouse fetuses (IARC, 1983).
Other Toxicological Effects:
Increased liver weight, neurological symptoms, and respiratory distress generally occur
after rats are exposed to nitrofen (IARC, 1983).
Toxicological Effects Indices;
• Oral LDso: rats, 410-3580 mg/kg (IARC, 1983).
C-163
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L)
Vapor Pressure, P (mm Hg)
284.1
colorless
crystals
70-71
180-190 @
0.25 mm Hg
1.3 (liquid @
90°C)
N/A
0.7-1. 2 (22°C)
SxlO"6 (40°C)
Windholz, 1983
Hartley and Kidd, 1983
Hartley and Kidd, 1983
Hartley and Kidd, 1983
Hartley and Kidd, 1983
Worthing, 1983
Worthing, 1983
Henry's Law Constant, H @ 25°C
(atm* m3/mol)
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient,
Koc(mL/g):
Fish Bioconcentration Factor, BCF:
3.1xlO~°(calc.)
5.53 (calc.)
5.9xl04(calc.)
1.6xl04(calc.)
Lyman et al., 1982
Lyman et al., 1982
Lyraanetal., 1982
Lyman etal., 1982
C-164
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REFERENCES
Grover, R., ed. 1988. Environmental Chemistry of Herbicides. Vol. I, CRC Press, Inc., Boca
Raton, FL.
Hartley and Kidd, eds. 1983. Herbicide Handbook. 5th ed. Weed Science Society of America,
Champaign, IL.
I ARC (International Agency for Research on Cancer). 1983. I ARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 30. IARC, Lyon, France.
Klaassen,C.D.,M.O. Amdur, andJ. Doull.eds. 1986. Casarett and Doull's Toxicology: The Basic
Science of Poisons. 3rd ed. Macmillan Publishing Co., New York.
Lyman, W.L., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods. McGraw-Hill Book Co., New York.
Ouellette, R.P., and J.A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Committee.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck Co., Inc., Rahway, NJ.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British Crop
Protection Council, Croydon, England.
C-165
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-------
NONACHLOR
(cis- and trans- isomers)
CAS No.: cis-5103-73-1
trans - 39765-80-5
combined - 3734-49-4
CAS Preferred Nomenclature: (combined)
4,7-Methano- IH-indene,
l,2,3,4,5,6,7,8,8-nonachloro-2,3,3a,4,7,7a-
hexahydro-
cis-nonachlor
Empirical Formula:
REGULATORY STATUS
Standards and Criteria:
• EPA Water Quality Criteria (for human
consumption offish):
None established at present
• EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
• EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restrictions and Bans:
ci
EPA Drinking Water Health Advisories:
None established at present
Food and Drug Administration Action
Level for Fish:
None established at present
None for nonachlor. However, trans-nonachlor is a minor (7-10%) constituent of
technical-grade chlordane, a chlorinated hydrocarbon pesticide (McEwen and Stephen-
son, 1979; Takamiya, 1987). Chlordane has been banned for all uses except for
subsurface termites (see profile of chlordane for additional information).
C-167
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SOURCES OF NONACHLOR
Total Nonachlor Produced:
Nonachlor is not intentionally produced for any commercial purposes.
Uses of Nonachlor:
As an impurity in technical chlordane, nonachlor is distributed in the environment when
chlordane is used to control soil-inhabiting insects (e.g., termites).
Other Sources:
An impurity in the technical grade of the pesticide heptachlor (Nash and Harris, 1973).
FATE IN ENVIRONMENT
Partitioning:
Based on its estimated physical/chemical properties, nonachlor is nonvolatile (H =
2xlO~7atm» m3/mol), is strongly sorbec
for bioaccumulation (BCF = 2.2x104).
2x 10~7 atm • m3/mol), is strongly sorbed to soil (Kow = 457,000), and has a high potential
Persistence:
Data on the persistence of cis- and trans-nonachlor are sparse, although their structural
similarity to cis- and trans-chlordane (one chlorine atom replaces one hydrogen atom)
suggests that they would behave similarly. Nonachlor present as an impurity in
heptachlor was found in soil test plots 16 years after the application of 112 kg/ha and
224 kg/ha of technical heptachlor at concentrations of 2.3 and 5.2 ppm, respectively.
Plots of the same type soil treated with technical chlordane, which contains roughly 1%
nonachlor, also showed traces of nonachlor (<0.03 ppm) after 16 years (Nash and Harris,
1973). Assuming nonachlor behaves like chlordane, hydrolysis is not expected to be an
important process although sensitized photolysis may occur. Biodegradation is expected
to be very slow, although it may be important for ultimate degradation (Callahan et al.,
1979).
The immediate metabolic product of trans-nonachlor is trans-chlordane (Tashiro and
Matsumura, 1978).
C-168
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HEALTH EFFECTS
Carcinogenic! ty:
No data found for nonachlor.
• Chlordane is a probable human carcinogen because it causes liver tumors in mice and
rats (see chlordane profile).
Mutagenic Activity:
No data found.
Reproductive Effects;
No data found.
Other Toxicological Effects:
• Trans-nonachlor is reported to induce drug-metabolizing enzymes in the liver. Whether
this is potentially related to any adverse health effects is not known (Campbell et al.,
1983).
• Chlordane causes nerve, liver, kidney, and lung damage (see profile for chlordane).
Toxicological Effects Indices:
2
• LCso: mosquito larvae = 3.5x10" ppm (Tashiro and Matsumura, 1977).
• No health effects indices are available for nonachlor. The indices for chlordane are:
- Cancer Potency Factor (CPF): 1.3 (mg/kg/day)'1 (IRIS, 1989)
Concentration in
Cancer Risk Level Drinking Water (IRIS. 1988)
1 in 10,000 3
1 in 100,000 0.3
1 in 1,000,000 0.03
- Reference Dose (RfD): 6xlO~5 (mg/kg/day) (IRIS, 1989)
- TWA-TLV (time-weighted average, threshold limit value) for occupational skin ex-
posure: 0.5 mg/m3 (ACGIH, 1986; IRIS, 1988).
C-169
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H @ 25°C (atm • m3/mol):
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc (mL/g):
Fish Bioconcentration Factor, BCF:
444.2
solid
148 (calc.)
471 (calc.)
N/A
N/A
0.06 (calc.)
2x10~8 (calc.)
2xlO"7 (calc.)
5.66 (calc.)
7.3xl04(calc.)
2.2xl04 (calc.)
Lyman et al., 1982
Lymanetal., 1982
Lyman etal., 1982
Lymanetal., 1982
Lyman et al., 1982
Lymanetal., 1982
Lymanetal., 1982
Lyman et al., 1982
C-170
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Occupational Exposures to Chemicals. ACGIH, Cincinnati, OH.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979. Water-Related
Environmental Fate of 129 Priority Pollutants, Vol. I. U.S. Environmental Protection Agency,
Office of Water Planning and Standards, Washington, DC. EPA-440/4-79-029a.
Campbell, M.A., J. Gyorkos, B. Lee, K. Homonko, and S. Safe. 1983. The Effects of 22
Organohalogen Pesticides as Inducers of the Hepatic Drug-Metabolizing Enzymes. (Abstract).
Gen. Pharmacol. 14(4): 445-454.
IRIS. 1989. Integrated Risk Information System. U.S. Environmental Protection Agency.
Washington, DC.
Lyman, W.L., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods. McGraw-Hill Book Co., New York.
McEwen, F.L., and G.R. Stephenson. 1979. The Use and Significance of Pesticides in the
Environment John Wiley and Sons, New York.
Nash, R.G., and W.G. Harris. 1973. Chlorinated Hydrocarbon Insecticide Residues in Crops and
Soil. J. Environ. Quality 2:269-273.
Taguchi, S., and T. Yakushiji. 1988. Influence of Termite Treatment in the Home on the Chlordane
Concentration in Human Milk. Arch. Environ. Contam. Toxicol. 17:65-71.
Takamiya, K. 1987. Residual Levels of Plasma Oxychlordane and trans-Nonachlor in Pest Control
Operators and Some Characteristics of These Accumulations. Bull. Environ. Contam. Toxicol. 39:
750-755.
Tashiro, S., and F. Matsumura. 1977. Metabolic Routes of cis-and trans-Chlordane in Rats. J.
Agric. Food Chem. 25(4):872-880.
Tashiro, S. and F. Matsumura. 1978. Metabolism of trans-Nonachlor and Related Chlordane
Components in Rat and Man. (Abstract). Arch. Environ. Contam. Toxicol. 7:113-127.
C-171
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C-I72
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OCTACHLOROSTYRENE
CAS No.: 29082-74-4
CAS Preferred Nomenclature:
Benzene, pentachloro
(trichloroethenyl)-
Empirical Formula:
Molecular Weight: 379.7
REGULATORY STATUS
• No use restrictions or regulatory standards.
SOURCES OF TACHLORQSTYRENE
Formation of Octachlorostyrene:
• There is no intentional commercial production of octachlorostyrene. Octachlorostyrene
is associated with wastes from the electrolytic production of chlorine prior to 1970 when
graphite anodes and coal tar pitch binder were used. It is hypothesized that the
chlorination of this binder material was a major source of octachlorostyrene as well as
other chlorinated styrenes (Kaminsky and Hites, 1984). After 1970, metal anodes were
used.
• It is reported that octachlorostyrene is also formed when graphite anodes are used during
the electrolytic production of magnesium from magnesium chloride (Tarkpea et al.,
1985).
FATE IN ENVIRONMENT
Partitioning;
• Based on estimated physical/chemical properties using structure-activity relationships
(Lvman et al, 1982), octachlorostyrene is highly volatile (estimated H = 0.15 atm •
m /mol) and strongly sorbs to organic matter (Kow= 87,100,000). It has a high potential
for bioaccumulation (BCF = 4.2x106).
C-173
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Persistence:
• Octachlorostyrene is persistent in sediments (Kaminsky and Hites, 1984). Processes
that can transform octachlorostyrene include hydrolysis, biodegradation, and photolysis,
but at low rates. The estimated half-lives cited were > 1,000 days for hydrolysis and
>100 days for biodegradation (Wise and Wrich, 1984). Information was found showing
that octachlorostyrene can undergo photolysis in water/solvent mixtures exposed to
wavelengths between 230 and 290 mm. The rate was slower at wavelengths greater than
290 mm. (Hustert et al, 1984).
HEALTH EFFECTS
Cardnogenidty:
• The potential carcinogenicity of octachlorostyrene has not been evaluated.
Mutagenic Activity:
• Results were negative in bacterial mutagenicity tests (Tarkpea et al., 1985; Kaminskyu
and Hites, 1984).
Effects on Humans and Animals;
• No reports of adverse health effects in humans or animals.
C-174
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Water Solubility, (mg/L):
Henry's Law Constant, H@25°C
(atm* m /mol):
Log (Octanol - Water Partition
Coefficient), log KOW:
Soil Adsorption Coefficient, Koc(mL/g):
Fish Bioconcentration Factor, BCF:
379.7
Solid
2xlO~4(calc)
O.lS(calc)
7.94 (calc)
4.4xl06(calc)
33,000(calc)
Lyman, et al., 1982
Lyman, et al., 1982
Lyman, et al., 1982
Lyman, et al., 1982
Lyman, et al., 1982
C-175
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REFERENCES
Hustert, K., D. Kotzias, and F. Korte. 1984. Beitrag Zutn Verhalten von Octochlorostyrol bei
UV-Bestrahlung. Chemospher. 13:845-848.
Kaminsky, R., and R.A. Hites. 1984. Octachlorostyrene in Lake Ontario; Sources and Fates.
Environ. Sci. Technol. 18:275-279.
Lyraan, W.L., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods. McGraw-Hill Book Co., New York.
Tarkpea, M., I. Hagen. G.E. Carlberg, P. Kolsaker, and H. Storflor. 1985. Mutagenicity, Acute
Toxicity, and Bioaccumulation Potential for Six Chlorinated Sytrenes. Bull. Environ. Contam.
Toxicol. 35:525-530.
Wise, P.L., and M. Wrick. 1984. Candidates for the Emerging Chemical Identification and
Management Project: Polychlorinated Systems Memorandum, September 4, 1984.
C-176
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OXYCHLORDANE
CAS No.: 27304-13-8
CAS Preferred Nomenclature:
2,5-methano-2 H-indeno
( 1 ,2b)oxirene, 2,3,4,5,6,6aJ,7-octachloro-
la,lb,5,5a,6,6 hexahydro-
Empirical Formula:
Synonyms and Common Names:
- Octachlor epoxide
- Oxychlordan
- 1,2-dichlorochlordene epoxide
REGULATORY STATUS
• No use restrictions or regulatory standards.
a ci
Cl
CioHsC'e°
SOURCES OF OXYCHLORDANE
Uses of Oxychlordane:
Oxychlordane is not used in any commercial products and is not found in technical-grade
chlordane.
Other Sources
Oxychlordane is a major metabolic breakdown product of the pesticide chlordane
(Taguchi and Yakushuji, 1988). It is one of many compounds formed as a result of a
series of oxidative enzyme reactions with chlordane (Barnett and Dorough, 1974;
Tashiro and Matsumura, 1977).
FATE IN ENVIRONMENT
Partitioning;
Based on its physical/chemical properties, Oxychlordane is estimated to have low
volatility (H = 3xlO"7 atm • m /mol), a moderate tendency to sorb to soil (Kow ^400),
and a low potential for bioaccumulation (BCF = 19).
C-177
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Persistence:
Based on its structural similarity to the pesticides chlordane, dieldrin, and aldrin,
oxychlordane is not expected to be susceptible to hydrolysis, but is expected to be
affected by indirect photolysis. Biodegradation is also expected to be slow (Callahan et
al., 1979). It is likely to be highly persistent (Kirk-Othmer, 1978).
Four months after application of high-purity chlordane to alfalfa, oxychlordane com-
prised 16% of the residues measured in the crop (WHO, 1984).
Oxychlordane is considered to be more persistent than its parent compound, chlordane
(WHO, 1984).
OXYCHLORDANE OBSERVED IN THE ENVIRONMENT
Sample Type Concentration Reference
Market basket foods 1-5 jig/kg WHO, 1984
(found in less than 1% of samples
taken in 1963-1969)
Human breast milk 75.4-116 ng/L WHO, 1984
(1976 study of 1463 women)
Human fat 0.03-0.4 mg/kg WHO, 1984
Fat of dogs, rats, pigs, cattle (Concentrations WHO, 1984
not given)
Tokyo Bay gobyfish 3 ng/kg Worthing, 1983
Bats (Maryland and Virginia) 0.11-to 6.33 ^g WHO, 1984
HEALTH EFFECTS
Cardnogenidty:
It has been suggested that chlordane metabolites (e.g., oxychlordane) may be car-
cinogenic in humans because chlordane causes liver cancer in mice (WHO, 1984). EPA
has not evaluated the carcinogenic potential of oxychlordane.
Other Toxicologtcal Effects:
Oxychlordane is considered to be more toxic than its parent compound, chlordane (see
Chlordane profile) (WHO, 1984).
C-178
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No other information was found on the human health effects, mutagenicily, or reproduc-
tive effects of oxychlordane.
Toxicological Effects Indices:
Acute oral LDso: rat, 19.1 mg/kg (Mastri et al., 1969, in WHO, 1984).
Temporary reference dose proposed by the FAO/WHO for the sum of the alpha- and
gamma- forms of chlordane plus oxychlordane: 0.0 to 0.001 mg/kg (WHO, 1984).
A 1972 Joint Meeting on Pesticide Residues established food residue tolerance levels
of 0.02 to 0.5 mg/kg for a sum of alpha-, gamma-, and oxychlordane (WHO, 1984).
C-179
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PHYSICAL CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant H @
25°C (atm • m3/mol):
Log (Octanol- Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc(mL/g):
Fish Bioconcentration Factor, BCF:
354.9
solid
134 (calc.)
3 17 (calc.)
N/A
N/A
200 (calc.)
3xlO'7 (calc.)
2.60 (calc.)
300 (calc.)
19 (calc.)
Lymanetal., 1982
Lyman et al., 1982
Lymanetal., 1982
Lymanetal., 1982
Lymanetal., 1982
Lymanetal., 1982
Lymanetal., 1982
Lyman etal., 1982
C-180
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REFERENCES
Barnett, J.R., and H.W. Dorough. 1974. Metabolism of Chlordane in Rats. J. Agric. Food Chem.
22:612-619.
Kirk-Othmer. 1978. Encyclopedia of Chemical Technology. 3rded. John Wiley and Sons, Inc.,
New York.
Lyman, W.L., W.F. Reehe, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estima-
tion Methods - Environment. McGraw-Hill, New York.
Mastri, C, M.L. Keplinger, and O.E. Fancher. Acute Oral Toxicity Study on Four Chlordenes in
Albino Rats. 1969. Illinois, Industrial Bio-Test Laboratories (Report for Velsicol Chemical
Corporation). (As cited in WHO, 1984)
Taguchi, S., and T. Yakushiji. 1988. Influence of Termite Treatment in the Home on the Chlordane
Concentration in Human Milk. Arch. Environ. Contam. Toxicol. 17:65-71.
Tashiro, S., and F. Matsumura. 1977. Metabolic Routes of cis- and trans- Chlordane in Rats. J.
Agric. Food Chem., 25:872-880.
WHO fWorld Health Organization). 1984. Chlordane. Environmental Health Criteria 34. World
Health Organization, Geneva.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. British Crop Protection
Council, Craydon, England.
C-181
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C-182
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PENTACHLOROANISOLE
CAS No.: 1825-21-4
CAS Preferred Nomenclature:
Benzene, Pentachloromethoxy-
Empirical Formula: CyHsClsO
Synonyms and Common Names:
- PCA
- 2,3,4,5,6 Pentachloroanisole
- Pentachlorophenyl methyl ether
- Methyl pentachlorophenate
REGULATORY STATUS
Standards and Criteria;
• No standards or criteria for pentachloroanisole were found. See Pentachlorophenol
profile for standards applicable to parent compound.
Use Restrictions and Bans:
• Uses of pentachlorophenol were restricted in 1984 primarily to wood preservation,
excluding logs for homes and interiors of buildings. (See Pentachlorophenol profile.)
SOURCES OF PENTACHLOROANISQLE
Production;
• Not produced as a separate chemical.
Other Sources;
• Pentachloroanisole is a metabolic product of pentachlorophenol. It can be formed by
microorganisms in the soil environment (Kaufman, 1978; Cserjesi and Johnson, 1972)
and in aquatic sediments (Pierce and Victor, 1978).
C-183
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FATE IN ENVIRONMENT
Partitioning:
• Based on its physical/chemical properties, pentachloroanisole is volatile (H = 8x10
atm • m /mol), strongly sorbs to organic matter (Kow = 457,000), and has a high potential
for bioaccumulation (BCF = 10,000). It is also retained longer by fish than pen-
tachlorophenol (ti/2 = 6 to 24 days for pentachloroanisole versus a ti/2 = 0.25 to 1 day
for pentachlorophenol, Lech et al., 1978).
Persistence:
• Environmental fate data for pentachloroanisole are scarce. Rate constants for
hydrolysis, photolysis, or acid-base dissociation were not found. Based on its chemical
structure, it would not be expected to hydrolyze (Lyman et al., 1982) but may undergo
photolysis (Sadtler, 1979). Conversion back to pentachlorophenol in soils can occur
under both aerobic and anaerobic conditions, but is faster under anaerobic conditions
(42% in 24 days vs. 6% under aerobic conditions, Kaufman, 1978).
PENTACHLQROANISOLE OBSERVED IN THE ENVIRONMENT
• In lake contaminated with fuel oil containing pentachlorophenol in Mississippi (Pierce
and Victor, 1978):
Water (mg/L) 0.03-1.94
Sediment (mg/g) 14-80
Fish Tissue (ng/g wet weight) 30-250
HEALTH EFFECTS
Carcinogenic! ty:
• No data found. EPA has not evaluated the carcinogenic potential for pentachloroanisole.
The data for pentachlorophenol carcinogenicity are currently under review (IRIS, 1989).
Mutagenic Activity: No data found.
Reproductive Effects:
• Female rats fed pentachloroanisole at a dose of 41 mg/kg/day gained less weight during
pregnancy. Male offspring had lower birth weights and were smaller in length. Female
offspring exhibited no such effects. (Welsh et al., 1987.)
C-184
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Toxicological Effects Indices;
• Oral LDso: rats 500 mg/kg (Sax, 1984).
C-185
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @
25°C (atm • m3/raol):
Log (Octanol- Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc(ml/g):
Fish Bioconcentration Factor, BCF:
280.4
solid
104(calc.)
258 (calc.)
N/A
N/A
0.2 (calc.)
5xlO'3 (calc.)
8xlO'3(calc.)
5.66 (calc.)
4.2xl04 (calc.)
1.0xl04(calc.)
Windholz, 1983
Lyman et al., 1982
Lymanetal., 1982
Lyraan et al., 1982
Lyman et al., 1982
Lymanetal., 1982
Callahan et al.,
1982
Lymanetal., 1982
Lyman et al., 1982
C-I86
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REFERENCES
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979. Water-Related
Environmental Fate of 129 Priority Pollutants, Vol. I. U.S. Environmental Protection Agency,
Office of Water Planning and Standards, Washington, DC. EPA-440/4-79-029a.
Cserjesi, A.J., and E.L. Johnson. 1972. Methylation of Pentachlorophenol by Trichoderma vir-
gatum. Can. J. Microbiol. 18:45-49.
IRIS. 1989. Integrated Risk Information System. U.S. Environmental Protection Agency, Wash-
ington, DC.
Kaufman, D.D. 1978. Degradation of Pentachlorophenol in Soil, and by Soil Microorganisms. In:
Pentachlorophenol Chemistry, Pharmacology, and Environmental Toxicology (K.R. Rao, ed.), pp.
27-39. Plenum Press, New York.
Lech, J.J., A.H. Glickman, and C.N. Statham. 1978. Studies on the Uptake, Disposition and
Metabolism of Pentachlorophenol and Pentachloroanisole in Rainbow Trout (Salmo gairdneri). pp.
107-113.
Lyman, W.L., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods. McGraw-Hill Book Co., New York.
Pierce, R.H., Jr., and D.M. Victor. 1978. Fate of Pentachlorophenol in an Aquatic Ecosystem. In:
Pentachlorophenol Chemistry, Pharmacology, and Environmental Toxicology (K.R. Rao, ed.), pp.
27-39. Plenum Press, New York.
Sadtler Research Labs. 1979. Sadtlers Handbook of Ultraviolet Spectra. Sadtler Research Labs,
Division of Bio-Rad Labs, Inc., Philadelphia.
Sax, N.I. 1984. Dangerous Properties of Industrial Materials. 6th ed. Van Nostrand Reinhold
Co., New York.
Welsh, J.J., T.F. Collins, T.N. Black, S.L. Graham, and M.W. O'Donnell, Jr. 1987. Teratogenic
Potential of Purified Pentachlorophenol and Pentachloroanisole in Subchronically Exposed
Sprague-Dawley Rats. Food Chem. Toxicol. 25(2): 163-172.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck & Co., Rahway, NJ.
C-187
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C-188
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PENTACHLOROBENZENE
CAS No.: 608-93-5
CAS Preferred Nomenclature:
Benzene, pentachloro-
Empirical Formula:
Synonyms and Common Names:
- QCB
- 1, 2,3,4,5 Pentachlorobenzene
ci
ci
ci
ci
ci
C6HCI5
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for human
consumption of fish) (IRIS, 1989):
EPA Ambient Water Quality Criteria «
(for protection of aquatic organisms)
(IRIS, 1989):
Freshwater Saltwater
Acute, \igfL 250 160
Chronic, \ig/L 50 129
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
EPA Drinking Water Health Advisories:
None established at present
Above are LECs (Lowest Effect Con-
centration)
• Food and Drug Administration Action
Level for Fish:
None established at present
Use Restrictions and Bans: None found.
SOURCES OF PENTACHLOROBENZENE
Total Pentachlorobenzene Produced: No data found.
Maior Uses: No data found.
C-189
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Other Sources;
• Pentachlorobenzene is an impurity (approximately 0.17%) in the soil fungicide pen-
tachloronitrobenzene (Verschueren, 1983; Klaassen et al., 1986).
FATE IN ENVIRONMENT
Partitioning;
• Based on its physical/chemical properties, pentachlorobenezene is highly volatile (H =
3.8xlO~3 aim • m3/mol), is strongly sorbed to soil (Kow = 155,000), and has a high
potential for bioaccumulation. Experimentally determined values for BCF ranged from
1.3xl05 to 2xl05 (Oliver and Niimi, 1983).
• The steady-state bioconcentration factor found for bluegills was 3,400 (CIS database).
Persistence;
• Little information specific to pentachlorobenzene was found in the literature. Much of
its behavior is inferred from that of hexa- and tetrachlorobenzenes. Neither hydrolysis
nor chemical oxidation of pentachlorobenzene is expected to be environmentally sig-
nificant based on the behavior of these related compounds. Although chlorobenzenes
of 3 or fewer chlorines can be biodegraded, hexa- and pentachlorobenzene are considered
resistant to biodegradation (Bailey, 1983).
• Pentachlorobenzene has been found to undergo photolytic degradation in
acetonitrile/water mixtures at wavelengths >285 nm (Choudhry and Hutzinger, 1984).
After 24 hours, 41.2% of an initial pentachlorobenzene concentration of approximately
ImM underwent nonsensitized degradation while 53.8% disappeared in 4 hours when
acetone at 0.55 M was present as a sensitizer. Roughly 3.4% of the pentachlorobenzene
that underwent sensitized photolysis was converted to PCBs; lesser amounts were
converted by direct photolysis.
PENTACHLOROBENZENE OBSERVED IN THE ENVIRONMENT
• No data available.
C-190
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HEALTH EFFECTS
Carcinogenidty:
• Not yet evaluated by EPA for carcinogenicity (IRIS, 1989).
• EPA (1980) reports one study that alludes to carcinogenicity of pentachlorobenzene in
mice but not in rats and dogs. No details are available.
Mutflgenic Activity: No data available.
Reproductive Effects:
• Weanling rat pups of mothers receiving 18 mg/kg/day developed tremors (IRIS, 1989).
• Pregnant rats given 50,100, or 200 mg/kg orally during days 6-15 of gestation produced
sternal defects suggestive of retarded development (U.S. EPA, 1980).
Other Toxicological Effects:
• Liver and kidney toxiciry observed in rats fed pentachlorobenzene at doses as low as 8.3
mg/kg/day (IRIS, 1989).
Toxicological Effects Indices;
• Reference Dose (RfD): SxlO"4 mg/kg/day (IRIS, 1989).
C-191
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PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (rag/L):
Vapor Pressure, P (ram Hg):
Value
250.3
solid
86
277
1.8342 (16.5°)
N/A
0.24(22°)
2.8x1 0'3(25°)
Reference
Windholz, 1983
Weast, 1986
Weast, 1986
Weast, 1986
Verschueren, 1983
Lymanetal., 1982
Henry's Law Constant, H@ 25°C
(atm • ra /mol):
Log (Octanol-Water Partition
Coefficient), log KOW:
Soil Adsorption Coefficient,
Koc(mL/g):
Fish Bioconcentration
Factor, BCF:
(calc.)
3.8xlO"3(calc.)
5.19
5.8xl04 (calc.)
1.3xl05-2.0xl05
(exptl.)
2125
Lyraan et al., 1982
U.S. EPA, 1986
Lymanetal., 1982
Oliver & Niirai,
1983
U.S.EPA, 1986
C-192
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REFERENCES
Bailey, R.E. 1983. Comment on Chlorobenzenes in Sediments, Water, and Selected Fish from
Lakes Superior, Huron, Erie, and Ontario. Environ. Sci. Technol. 17:504.
Choudhry, G.G., and O. Hutzinger, 1984. Acetone-sensitized and Non-sensitized Photolysis of
Tetra- Penta- and Hexachlorobenzenes in Acetonitrile-water Mixtures: Photoisomerization and
Formation of Several Products including Polychlorinated Biphenyls. Environ. Sci. Technol.
18:235-241.
IRIS. 1989. Integrated Risk Information System. U.S. Environmental Protection Agency,
Washington, DC.
Klaassen, C.D., M.D. Amdur, and J. Doull, eds. 1986. Casarett and Doull's Toxicology. The Basic
Science of Poisons. 3rd ed. Macmillan Publishing Co., New York.
Lyman, W.L.,W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods. McGraw-Hill Book Co., New York.
Oliver, B.G., and A.J. Niimi. 1983. Bioconcentration of Chlorobenzenes from Water by Rainbow
Trout: Correlations with Partition Coefficients and Environmental Residues. Environ. Sci. Tech-
nol. 17:287-291.
PHRED. 1988. Public Health Risk Evaluation Database. U.S. Environmental Protection Agency,
Office of Emergency and Remedial Response, Washington, DC.
U.S. EPA. 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. U.S. Environmental
Protection Agency, Office of Water Regulations and Standards, Criteria and Standards Division,
Washington, DC. EPA-440/5-80-028.
U.S. EPA. 1986. Superfund Public Health Evaluation Manual. U.S. Environmental Protection
Agency, Office of Emergency and Remedial Response, Washington, DC. EPA-540/1-86/060.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Weast, R.C., ed. 1986. CRC Handbook of Chemistry and Physics. 67th ed. CRC Press, Boca
Raton, FL.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck & Co., Rahway, NJ.
Worthing, C.R., ed. 1983. The Pesticide Manual: A world compendium. 7th ed. British Crop
Protection Council, Croydon, England.
C-193
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PENTACHLORONITROBENZENE
CAS No.: 82-68-8
CAS Preferred Nomenclature:
Benzene, pentachloronitro-
Empirical Formula: CeClsNOz
CfiCUNO,
Synonyms and Common Names: I ° 5 z
- Brassicol - Terraclo
- Quintozene - PCNB
- Fungiclor - Folosan
REGULATORY STATUS
Standards and Criteria;
• EPA Water Quality Criteria (for human • EPA Drinking Water Health Advisories:
consumption of fish): None established at present
None established at present
• EPA Ambient Water Quality Criteria • EPA Tolerance Levels (40 CFR
(for protection of aquatic organisms): 180.291):
No specific criteria or LELs have been 0.1 ppm for cottonseed
developed for PCNB (IRIS, 1989) 0.2 ppm for collards, kale, and
mustard greens
• EPA Drinking Water Standard Maxi- • Food and Drug Administration Action
mum Contaminant Level: Levels for Fish:
None established at present None established at present
Use Restrictions and Bans:
Use of pentachloronitrobenzene itself has not been restricted; however, the allowable
level of the contaminant hexachlorobenzene has been set at 0.1 percent (U.S. EPA,
1986b).
C-195
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SOURCES OF PENTACHLORONITROBENZENE
Total Pentachloronitrobenzene Produced:
In 1971, approximately 3 million pounds were produced by Olin Co. (Ouellette and
King, 1977).
Uses of Pentachloronitrobenzene:
• Pentachloronitrobenzene has been used primarily as a soil fungicide and as a seed
dressing agent (e.g., peanuts). Other uses have been to control stem and root rot for
flowers and vegetables (e.g., cabbage), and molds on flowers, cotton, and turf (Farm
Chemicals Handbook, 1985).
Other Sources: None found.
FATE IN ENVIRONMENT
Partitioning:
• Based on its physical/chemical properties, Pentachloronitrobenzene is somewhat volatile
(H = I x 10 atm • m3/mol), is strongly sorbed to soil organic matter (Kow = 282,000),
and has a low potential for bioaccumulation (BCF values derived experimentally range
from 6.3 to 79) (Verschueren, 1983).
Persistence:
• Pentachloronitrobenzene can undergo hydrolysis (Kn = 2.8 x 10"5/hr) (Ellington, et al,
1986) and aqueous photoreduction (A.D. Little, 1974). The estimated half-life is 2.8
years at a pH of 7, so hydrolysis is unlikely to be environmentally significant in most
cases. Biotransformation in soils can also occur, particularly under anaerobic conditions
(Verschueren, 1983).
PENTACHLORONITROBENZENE OBSERVED IN THE ENVIRONMENT
No data found.
C-196
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HEALTH EFFECTS
Carcinogeni city:
• Dietary exposure of mice to pentachloronitrobenzene (1206 ppm for 18 months) induced
liver tumors (IARC, 1973). Similar studies in rats (2500 ppm for 25 months) showed
no increased incidence of tumors (IARC, 1973). Pentachloronitrobenzene is classified
as category 3 by IARC and Class C by EPA, indicating that there is limited evidence of
carcinogenicity in animals and that additional studies are needed to characterize the
effect of this chemical (IARC, 1973; PHRED, 1988).
Mutagenic Activity: No data found.
Reproductive Effects:
• Cleft palates were observed in the offspring of mice exposed orally to 500 mg/kg of
pentachloronitrobenzene (Courtney, 1983; Klaassen et al.t 1986).
• No effects were observed in rats given 1653 ppm pentachloronitrobenzene (Jordan and
Borzelleca, 1973).
Other Toxicological Effects:
• Dogs fed pentachloronitrobenzene for 2 years at levels between 180 ppm and 1080 ppm
developed various levels of liver damage, abnormal bile production, and secondary
kidney degeneration (RTECS, 1984; IRIS, 1989).
Toxicological Effects Indices;
• Reference Dose (RfD): 3 x 10"3 mg/kg/day (IRIS, 1989).
• Oral LDso: rats, 1200-1650 mg/kg (Klassen et al., 1986).
C-197
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @
25°C(atnr m3/mol):
Hydrolysis, KN 1/hr:
Log (Octanol-Water Partition
Coefficient), log KOW:
Fish Bioconcentration
Factor, BCF:
295.34
solid
146
328 (with slight
decomp.)
1.718
N/A
4.4 x 10
-1
7.11x10
-2
l.OxlO"4
2.8 x 10'5
5.45
Soil Adsorption Coefficient, Koc (mL/g): 1.4 x 10
6.3 to 79
(exptl.)
Verschueren, 1983
Verschueren, 1983
Windholz, 1983
Windholz, 1983
Hartley & Kidd, 1983
U.S. EPA, 1986;
Jaber et al., 1984
Jaberetal., 1984
Lymanetal., 1982
Ellington et al., 1986
Jaberetal., 1984
Lymanetal., 1982
Verschueren, 1983
C-198
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REFERENCES
Courtney, D. 1973. The Effect of Pentachloronitrobenzene on Fetal Kidneys. Toxicol. Appl.
Pharmacol. 25:455.
Ellington, J.J.,F.E. Stancil, Jr., and W.D.Payne. 1986. Measurement of Hydrolysis Rate Constants
for Evaluation of Hazardous Waste Land Disposal. Vol. I. U.S. Environmental Protection Agency,
Athens, GA. EPA/600/3-86/043.
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Hartley, D., and H. Kidd, eds. 1983. The Agrochemicals Handbook. The Royal Society of
Chemistry, Nottingham, England.
IARC (International Agency for Research on Cancer). 1973. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 5. IARC, Lyon, France.
IRIS. 1989. Integrated Risk Information System. U.S. EPA, Washington, DC.
Jager, K.W. 1970. Aldrin, Dieldrin, Endrin and Telodrin: An Epidemiological and Toxicological
Study of Long-Term Occupational Exposure. Elsevier Publ. Co., Amsterdam, The Netherlands.
Jordon, R.J., and J.F. Borzelleca. 1973. Teratogenic Studies with Pentachloronitrobenzene in Rats.
Toxicol. Appl. Pharmacol. 25:454.
Klaassen,C.D.,M.O. Amdur, andJ. Doull.eds. 1986. Casarett and Doull's Toxicology. The Basic
Science of Poisons. Macmillan Publishing Co., New York.
Ouellette, R.P., and J.A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
PHRED. 1988. Public Health Risk Evaluation Database. Draft 204. February 18, 1988. Phase
Linear Systems, Inc. for U.S. Environmental Protection Agency, Office of Emergency and Remedial
Response.
Registry of Toxic Effects of Chemical Substances (RTECS) Database. 1984. Available through
the National Library of Medicine's MEDLARS system, National Institute of Occupational Safety
and Health (NIOSH).
U.S. EPA. 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. U.S. Environmental
Protection Agency, Office of Water Regulations and Standards, Washington, D.C. Report #PB81-
117-392.
U.S. EPA. 1985. Suspended, Cancelled, and Restricted Pesticides. U.S. Environmental Protection
Agency, Office of Pesticides and Toxic Substances, Washington, DC.
C-199
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U.S. EPA. 1986a. Computer retrieval from Office of Pesticides for registered sites and number of
products registered.
U.S. EPA. 1986b. Superfund Public Health Evaluation Manual, U.S. Environmental Protection
Agency, Office of Solid Waste and Emergency Response, Washington, DC. EPA-540/1-86/060.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck & Co., Rahway, NJ.
C-200
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PENTACHLOROPHENOL
CAS No.: 87-86-5
CAS Preferred Nomenclature: Phenol, pentachloro-
Empirical Formula: CisHClsO
Synonyms and Common Names:
PCP
Permatox
Penchlorol
Fungilen
PreventolP
Permacide
Chem-Tol
Santobrite
Penwar
Termi-Trol
- Penta
- Chlorophen
- Permite
- Dowicide?
- Liroprem
- Priltox
- Durotox
- Lauxtol
- SantophenR
- Weedone
>H
C,HCI50
REGULATORY STATUS
Standards and Criteria;
• EPA Water Quality Criteria (IRIS,
1989):
for human consumption of fish and
water =1.01 mg/L to control undesirable
taste and odor = 30 p.g/L
EPA Ambient Water Quality Criteria «
(for protection of aquatic or-
ganisms)(IRIS, 1989):
Freshwater Saltwater
Chronic, ^g/L 22 13
Acute, p.g/L 13 7.9
EPA Drinking Water Health Advisories
(52 FR 175; IRIS, 1989):
ChjULdOkg):
1-day exposure = 1.0 mg/L
10-day and long-term exposure =
0.3 mg/L
adult (70 kg):
long-term exposure = 1.05 mg/L
lifetime exposure = 0.22 mg/L
Food and Drug Administration Action
Level for Fish:
None established at present
C-201
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• EPA Drinking Water Standards
(IRIS, 1989):
Proposed Maximum Contaminant
Level = 0.22 mg/L
Proposed Maximum Contaminant
Level Goal = 0.22 mg/L
Use Restrictions and Bans:
In 1984, most uses as an herbicide, antimicrobial agent (e.g., in cooling towers),
defoliant, disinfectant, and in marine anti-fouling paint were discontinued (49 FR
48367).
Continued uses allowed: wood preservative if not on logs for homes or interior of
buildings, in oil field flood waters, and in pulp and paper mill solutions (49 FR 48367).
SOURCES OF PENTACHLOROPHENOL
Total Pentachlorophenol Produced:
• Pentachlorophenol (PCP) was developed as a wood preservative in 1936.
• Four million pounds were produced in 1971 (Oueliette and King, 1977). By 1974
production had increased to 54 million pounds, of which 44 million pounds were used
in wood preservation. In 1984, uses were curtailed. By 1986 only one company, Vulcan
Materials, was producing pentachlorophenol (SRI, 1986).
• In aquatic systems a major metabolic product of pentachlorophenol is pentachloroanisole
(C?H3C150).
Uses of Pentachlorophenol;
• Major use (90%) is as a wood preservative to control termites and fungal rot for utility
poles, fence posts, railroad ties, and exterior lumber (Klaassen et al., 1986).
• Other uses (9%) include production of sodium pentachlorophenate (Na-PCP). This was
used in marine anti-fouling paint; in cooling tower water to control microorganism
growth; and to prevent fungal rot in carpets, canvas, and other textiles (Cirelli, 1978).
• PCP has also been used as a microbial agent in oil field flooding waters and drilling
muds and in the paper and pulp industry (Cirelli, 1978).
• PCP and Na-PCP together were formerly the second most used pesticide in the U.S.
(Cirelli, 1978), for example, as a pre-harvest defoliant for cotton and pre-emergence
herbicide (Agrochemicals Handbook, 1978).
C-202
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Other Sources:
• PCP is a breakdown product of the biotransformation of hexachlorobenzene and
pentachlorobenzene (Koss and Koransky, 1978).
FATE IN ENVIRONMENT
Partitioning:
• Based on its physical/chemical properties, pentachlorophenol can volatilize (H =
2.75x10" atm • m/mol), although this is not a dominant fate process. For example,
Ky in a shallow stream is calculated to be 0.024/day, compared to the photolysis rate of
1. I/day (Mills et al., 1985). PCP sorbs strongly to soil organic matter (Kow = 132,000)
and can bioaccumulate (BCF =1,000).
Persistence:
• PCP exists predominantly (over 90%) as an anion in waters having a pH of 5.7 or higher
(pKa = 4.7). Hydrolysis and volatilization are thus not generally environmentally
significant. Photolysis is rapid (Kpo = 1.224/hr), with half-lives of 0.2 and 4.8 hours at
depths of 10 cm and 300 cm, respectively, in a clear body of water at the latitude of
Cleveland on a midsummer day (Callahan et al., 1979).
• PCP can be degraded by a variety of microorganisms; one PCP-degrading strain
fFlavobacterium') was found to degrade PCP in natural waters at initial concentrations
of 10 ppb to 100 ppb, usually within 48 hours (Alexander and Aleem, 1961). First-order
biotransformation rate constants in water range from 0.05 to 0.5/day (Mills et al., 1985).
However, pentachlorophenol in soils degrades more slowly. In four laboratory experi-
ments, kb ranged from 4.2 x 10"4 to 5.2 x lO^/day (Tabak et al., 1981; Baker and
Mayfield, 1980).
HEALTH EFFECTS
Cardnogenidty;
• There was no evidence of the carcinogenicity of pure PCP in mice and rats fed doses of
up to 30 mg/kg/day for 2 years (U.S. EPA, 1984). However, technical-grade PCP may
be carcinogenic because of its contamination with the highly carcinogenic dioxins and
furans (IRIS, 1989).
• EPA has assigned pentachlorophenol to Group D; not classified as to human car-
cinogenicity. The research data are currently under review (IRIS, 1989).
C-203
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Mutagenic Activity:
Tests have yielded conflicting results. There were no observed mutagenic effects in
Drosophila melanogaster (fruit flies) (IARC, 1979) or Salmonella bacteria (Ames test).
Some mutations were observed in mice and Saccaromyces cerevisiae (yeast) (Scow
etal., 1980).
Reproductive Effects:
• PCP has caused fetal posioning in rats (Scow et al., 1980). The basic response was
reproductive failure with those surviving having subcutaneous fluid retention and
swelling, kidney damage, and skeletal defects of the skull, ribs, and vertebrae. The
incidence increased at higher doses (IARC, 1979).
Other Toxicological Effects;
• Acute (short-term, high-dose) and chronic (long-term, low-dose) effects both can include
(U.S. EPA, 1984):
skin irritation - fever
profuse sweating - tachycardia (rapid heartbeat)
kidney damage - vision damage
labored breathing - weakness
heart failure - convulsions.
• Chronic human exposure to PCP has been associated with aplastic anemia (Roberts,
1981). Exposure to PCP aggravates pre-existing kidney and liver diseases (Clayton and
Clayton. 1982).
• Fatalities due to PCP exposure have occurred (Klaassen et al., 1986).
Toxicological Effects Indices:
• Reference Dose (RfD): 0.03 mg/kg/day (IRIS, 1989).
• TWA-TLV (Time-weighted average, threshold limit value) for occupational skin ex-
posure: 0.5 mg/m3 (ACGIH, 1986).
• For a 70-kg (150-lb) person, a lethal oral dose is 50-500 mg/kg (IRIS, 1989).
C-204
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant,
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @ 25°C
(atm • m /mol):
Hydrolysis: Ka, L/mole/hr;
Kn, 1/hr; Kb, L/mole/hr:
Log (Octanol- Water Partition
Coefficient), log KOW:
Soil Adsorption Coefficient, KOC (mL/g):
Fish Bioconcentration Factor, BCF:
266.3
solid
190-191
309-310
1.978(22/4°C)
4.74
14(20°)
l.lxlO"4
(20°)
2.75 x 10'6
4.6 x 10"6
2.4 x W4
0.138
5.12
5.3 x 104
770 (calc.)
900-1,000
Windholz, 1983
Windholz, 1983
Windholz, 1983
Windholz, 1983
Callahan et al., 1979
CaUahanetal., 1979
Callahan et al., 1979
Mabeyetal., 1982
Parketal., 1980
Leo, 1982
Mabey et al., 1982
Lyman et al., 1982
Callahan et al., 1979
C-205
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Chemical Substances in the Work Environment ACGIH, Cincinnati, OH.
Agrochemicals Handbook. 1982. Meister Publishing Co., Willoughby, OH.
Alexander, M., and M.H. Aleem. 1961. Effect of Chemical Structure on Microbial Decomposition
of Aromatic Herbicides. J. Agric. Food Chem. 9(1): 44-47.
Baker, M.D., and C.I. Mayfield. 1980. Microbial and Nonbiological Decomposition of
Chlorophenols and Phenols in Soil, Water, Air. Soil Pollution 13:411.
Buhler, D.R., M.E. Rasmusson, and H.S. Nakave, 1973. Occurrence of Hexachlorophene and
Pentachlorophenol in Sewage and Water. Environ. Sci. Technol. 7:929-934.
Callahan, M.A., M.W. Slimak, N.W. Gabel, LP. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979. Water-Related
Environmental Fate of 129 Priority Pollutants, Vol. II. U.S. Environmental Protection Agency,
Office of Water Planning and Standards, Washington, DC. EPA-440/4-79-029b.
Cirelli, D.P. 1978. Patterns of Pentachlorophenol Usage in the United States of America - An
Overview. In Pentachlorophenol: Chemistry, Pharmacology, and Environmental Toxicology, ed.
K.R. Rao. Plenum Press, New York.
I ARC (International Agency for Research on Cancer). 1979. LARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS. 1989. Integrated Risk Information System. U.S. Environmental Protection Agency,
Washington, DC.
Kirk-Othmer Encyclopedia of Chemical Technology. 1982. 3rd. ed. John Wiley and Sons, Inc.,
New York.
Klaassen, C.D., M.O. Amdur, and J. Doulh, eds. 1986. Casarett and Doull's Toxicology. The
Science of Poisons. Macmillan Publishing Co., New York.
Koss, G., and W. Komasky. 1978. Pentachlorophenol in Different Species of Vertebrates after
Administration of Hexachlorobenzene and Pentachlorobenzene. In Pentachlorophenol: Chemistry,
Pharamacology, and Environmental Toxicology, ed. K.R. Rao. Plenum Press, New York.
Leo, AJ. 1983. Log P Parameter Database. Medchem Project, Pomona College, Claremont, CA.
Lyman, W.J., W.F. Reehe, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods-Environment. McGraw-Hill, New York.
C-206
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Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, I.W. Partridge,
H. Jaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority Pollutants.
SRI International. EPA 440/4-81-014.
Mills, W.B., D.B. Porcella, M.J. Ungs, S.A. Gherini, K.V. Summers, L. Mok, G.L. Rupp, G.L.
Bowie, and D.A. Haith. 1985. Water Quality Assessment: A Screening Procedure for Toxic and
Conventional Pollutants in Surface and Ground Water. U.S. Environmental Protection Agency,
Athens, GA. EPA 600/6-85/002a.
Ouellette, R.P., and J.A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book Co.,
New York.
Park, R.A., C.I. Connolly, J.R. Albanese, L.S. Clesceri, S.W. Heitzman, H.H. Herbrandson, B.H.
Indyke, J.R. Loehe, S. Ross, D.D. Sharma, and W.W. Shuster. 1980. Modeling Transport and
Behavior of Pesticides and Other Toxic Organic Materials in Aquatic Environments (PEST). Report
No. 7. Center for Ecological Modeling, Renselaer Polytechnic Institute, Troy, NY.
Roberts, H.J. 1981. Aplastic Anemia due to Pentachlorophenol. The New England Journal of
Medicine 305(27): 1650-1651.
Scow, K., M. Goyer, J. Penvak, E. Payne, R. Thomas, D. Wallace, P. Walker, M. Wood, and L.
Delpire. 1980. An Exposure and Risk Assessment for Pentachlorophenol. U.S. Environmental
Protection Agency, Office of Water Regulations and Standards, Office of Water and Waste
Management, Washington, DC.
SRI (Stanford Research Institute). 1986. Directory of Chemical Producers. Stanford Research
Institute, Menlo Park, CA.
Tabak, H.H., S.A. Quave, C.I. Mashni, and E.F. Earth. 1981. Biodegradation Studies with Organic
Priority Pollutant Compounds. J. Water Pollution Control Fed. 55:1503-1518.
U.S. EPA. 1976. Summary of Reported Episodes involving Pentachlorophenol. Pesticide Episode
Review System. U.S. EPA, Office of Pesticide Programs, Pesticide Episode Response Branch,
Operations Division, Washington, DC.
U.S. EPA. 1980a. Ambient Water Quality Criteria for Pentachlorophenol. U.S. Environmental
Protection Agency, Office of Water Regulations and Standards, Washington, DC. PBS 1-117764.
U.S. EPA. 1980b. An Exposure and Risk Assessment for Pentachlorophenol. U.S. Environmental
Protection Agency, Office of Water Regulations and Standards, Washington, DC. EPA-440/4-81-
021.
U.S. EPA. 1984. Health Effects Assessment for Pentachlorophenol. U.S. Environmental Protec-
tion Agency, Washington, DC. EPA/540/1-86-043.
C-207
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U.S. EPA. 1986. Superfund Public Health Evaluation Manual. U.S. Environmental Protection
Agency, Office of Solid Waste and Emergency Response, Washington, DC. EPA 540/1- 86/060.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck & Co., Rahway, NJ.
Wong, A.S., and D.E. Cosby. 1978. Photolysis of Pentachlorophenol in Water. In Pen-
tachlorophenol: Chemistry, Pharmacology, and Environmental Toxicology, ed. K.R. Rao, pp.
19-25. Plenum Press, New York.
Worthing, C.R., ed. 1979. The Pesticide Manual: A World Compendium. 7th ed. British Crop
Protection Council, Croydon, England.
Zitko, V., O. Hutzinger, and P.M.K. Chou. 1974. Determination of Pentachlorphenol and
Chlorobiphenylols in Biological Samples. Bull. Environ. Contam. Toxicol. 12(6):649-653.
C-208
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PERTHANE
CAS No.: 72-56-0
CAS Preferred Nomenclature:
Benzene, 1,1 -(2,2-dichloroethylidene)
bis (4-ethyl)-
Empirical Formula: Ci8H2oCl2
Synonyms and Common Names:
- Ethylan
- 1,1 -Dichloro-2,2-bis(p-ethylphenyl)R
- ethane
H5C
ci-c-ci
C18H20CI2
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for human
consumption offish):
None established at present
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
• EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restriction and Bans:
EPA Drinking Water Health Advisories:
None established at present
EPA Tolerance Levels for raw agricul-
tural commodities (40 CFR 180.139):
in meat and milk = 0 ppm
in other commodities = 15 ppm
Food and Drug Administration Action
Level for Fish:
None established at present
In 1980, all registered uses were cancelled (45 FR 41694).
SOURCES OF PERTHANE
Total Perthane Produced:
Perthane was produced by Rohm and Haas, Inc. from 1950 until it was discontinued in
1980 (Farm Chemicals Handbook, 1985).
C-209
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Uses of Perthane:
• Prior to 1980, perthane was used in a minor capacity as an insecticide on a variety of
crops and in certain household settings. Its structural similarity to DDT made it
particularly effective in controlling pests on pears, and leafhoppers and larvae on various
vegetables (i.e., peppers, tomatoes, broccoli, brussel sprouts, cauliflower, kohlrabi,
lettuce, spinach, and potatoes) (Ouellette and King, 1977; McEwen and Stephenson,
1979; Hayes, 1982; U.S. EPA, 1986).
• Perthane was registered as an insecticide for use on the foliage of grapes, apples, and
cherries.
• In homes and dog kennels, perthane was used in controlling animal pests (U.S. EPA,
1986).
• Perthane has also been used in mothproofing blankets, upholstery, and other textile
products (Hayes, 1982; U.S. EPA, 1986).
Other Sources: None identified.
FATE IN ENVIRONMENT
Partitioning:
• Based on its estimated physical/chemical properties, perthane is moderately volatile (H
= 6.1xlO~5 atm • m3/mol, is very strongly sorbed to soil (Kow =13,800,000), and has a
high potential for bioaccumulation (BCF = 6.6x10 ).
Persistence:
• Although perthane is structurally similar to DDT, it is not as persistent and can undergo
both biodegradation and photolysis (Ware, 1975; McEwen and Stephenson, 1979; TDB,
1985).
HEALTH EFFECTS
Cardnogenidty:
• In one study with mice, females, but not males, developed liver tumors as a result of 2
years of exposure to perthane in their diet (3000 ppm) (Reuber, 1980).
• EPA has not yet classified perthane as to its potential carcinogenicity.
Activity: No data found.
Reproductive Effects: No data found.
C-210
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Other ToxicologicaJ Effects:
There is no information available on any adverse human health effects caused by acute
(short-term, high-dose) exposure to perthane. In a few experimental cases, perthane was
used as a therapeutic agent in the treatment of prostate and breast cancers. Several of
the exposed persons developed diarrhea, vomiting, and nausea. There was no evidence
of liver, kidney, or nerve damage. However, there were no demonstrable benefits from
the treatments (Hayes, 1982).
Rats fed perthane for 2 years at doses between 500 and 5,000 ppm demonstrated no
adverse health effects. There were some minor liver changes (Hayes, 1982).
Perthane was lethal to dogs that received doses of 5,000 ppm for 22 weeks. Lower levels
either had no effects (100 ppm) or caused some adrenal degeneration (1,000 ppm)
(Hayes, 1982).
Toxicological Effects Indices:
Oral LDso: rats, 6600 to 8170 mg/kg; mice, 9340 mg/kg (McEwen and Stephenson,
1979; Hayes, 1982; RTECS, 1984).
C-211
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical Stale @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (ram Hg):
Henry's Law Constant,
H @ 25°C (atra • m3/mol):
Log (Octanol-Water Partition
Coefficient), log KOW:
Soil Adsorption Coefficient, KOC (mL/g):
Fish Bioconcentration Factor, BCF:
307.3
Crystalline
solid; technical
grade, waxy solid
56-57
N/A
N/A
N/A
0.1
1.5xlO'5(calc.)
6.1xlO"5(calc.)
7.14(calc.)
I.lxl06(calc.)
6.6x1 05 (calc.)
Hayes, 1982
Hayes, 1982
Windholz, 1983
Hollifield, 1979
Lyman et al., 1982
Lyman et al., 1982
Lyman etal., 1982
Lyman etal., 1982
Lyman etal., 1982
C-212
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REFERENCES
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Hayes, W.J., Jr. 1982. Pesticides Studied in Man. Waverly Press, Inc., Baltimore, MD.
Hollifield, H.C. 1979. Rapid Nephelometric Estimate of Water Solubility oi Highly Insoluble
Organic Chemicals of Environmental Interest Bull. Environ. Contam. Toxicol. 23:57-586.
Lyman, W.L., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods. McGraw-Hill Book Co., New York.
McEwen, F.L. and G.R. Stephenson. 1979. The Use and Significance of Pesticides in the
Environment John Wiley and Sons, Inc., New York.
Ouellette, R.P., and J.A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
Registry of Toxic Effects of Chemical Substances (RTECS) Database. 1984. Available through
the National Library of Medicine's MEDLARS system, National Institute of Occupational Safety
and Health (NTOSH).
Reuber, M.D. 1980. Histopathology of Carcinomas of the Liver in Mice Fed Perthane. Tumori.
66:277-283.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine's MEDLARS system, National Library of Medicine, TDB Peer Review Committee.
U.S. EPA. 1986. Computer retrieval from Office of Pesticides for registered sites and number of
products registered.
Ware, G.W. 1975. Pesticides: An Auto-tutorial Approach. W.H. Freeman and Co., San Francisco.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck & Co., Rahway, NJ.
C-213
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C-214
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POLYCHLORINATED BIPHENYLS
CAS No.: 1336-36-3 (undifferentiated)
Specific CAS numbers have also been assigned to PCBs with various levels of chlorination and
for individual Aroclors. Some of the other CAS numbers include:
Total Monochlorobiphenyl 27323-18-8
Total Dichlorobiphenyl 25512-42-9
Total Trichlorobiphenyl 25323-68-6
Total Tetrachlorobiphenyl 26914-33-0
Total Pentachlorobiphenyl 25429-29-2
Total Hexachlorobiphenyl 26601 -64-9
Total Heptachlorobiphenyl 28655-71-2
Total Octachlorobiphenyl 31472-83-0
Total Nonachlorobiphenyl 53742-07-7
Total Decachlorobiphenyl 2051-24-3
C1?H4d(, Hwacrdorobiprwnyl
Major Component of Arodor 1260
CAS Preferred Nomenclature:
1,1 '-Biphenyl, chloro-derivatives
Empirical Formula: Ci2Hio-xClx, where x is 1 to 10
Synonyms and Common Names:
- Chlorinated biphenyls - PCBs
- Chlorinated diphenyls - Aroclors*
REGULATORY STATUS
Standards and Criteria:
• EPA Water Quality Criteria (for human
consumption offish) (IRIS, 1989):
0.045 ng/L
EPA Drinking Water Health Advisories
for Aroclor 1016 (U.S. EPA, 1987):
Child (10 Kg):
long-term exposure = 1 ^ig/L
adult (70 Kg):
long-term exposure = 4 (ig/L
* Aroclors are mixtures of PCBs that have been designated using a four-digit numbering system. The first two digits indicate the
parent molecule (12 represents biphenyl). The next two digits indicate the percent chlorine. Up to 8 Cl atoms can be present
C-215
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• EPA Ambient Water Quality Criteria • Food and Drug Administration
(for protection of aquatic or- Tolerance Level for Fish and Shellfish
ganisms)(U.S. EPA, 1976): (21 CFR 109.30):
Freshwater Saltwater 2 ppm
Acute, ng/L 2.0 10.0
Chronic, ^ig/L 0.014 0.03
• EPA Drinking Water Standards (40
CFR Part 141):
Proposed Maximum Contaminant
Level = 0.0005 mg/L
Proposed Maximum Contaminant
Level Goal = 0 mg/L
Use Restrictions and Bans:
• In 1977, EPA banned the production-based discharge of PCBs (CWA 307(a)( 1)).
• In May 1979, EPA banned PCB manufacture, processing, and distribution in commerce
(>50 ppm). Continued use was allowed in totally-enclosed electrical systems (40 CFR
76).
• In August, 1982,40 CFR 76 was revised to restrict uses of PCBs in electrical equipment.
Some equipment was phased out. PCB transformers and electromagnets posing a risk
to food were banned after October 1, 1985. In restricted access areas, PCB tranformers
and large capacitors could be used until the equipment is worn out.
• In 1985, EPA established standards to lower fire-related risk. The use of electrical
equipment in commercial buildings and other high-risk areas was phased out.
SOURCES OF PCBs
Total PCB Production:
• PCB production in the U.S. began in 1929 and stopped in 1977 (Ghirelli et al., 1983).
Production peaked in 1970 at 85 million pounds (Matthews and Dedrick, 1984). Annual
production between 1971 and 1977 averaged about 40 million pounds (ATSDR, 1987).
Uses of PCBs:
PCBs are a family of chemicals. Commercial products can be mixtures of up to 209
different compounds. After 1974, PCBs were used primarily as a dielectric fluid in
capacitors and transformers.
C-216
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• Prior to 1974, PCBs were used in other products as well:
- plasticizer in plastic and rubber products
- lubricant in hydraulic and vacuum fluids
- ink carrier and solvent in manufacturing process for carbonless paper
- sealer for gaskets and furnaces (Versar 1976, 1980; Ghirelli et al, 1983; ATSDR,
1987).
Other Sources:
• Trace quantities of PCBs can be produced during manufacture of chlorinated hydrocar-
bon compounds in the presence of catalysts or at high temperatures (e.g. 1,1,1-
trichloroethene, tetrachloroethene, carbon tetrachloride) (Versar, 1983).
FATE IN ENVIRONMENT
Partitioning:
• PCBs differ in their behavior depending on the number of chlorine atoms present. A
higher number of chlorines (e.g., Aroclor 1260) makes the compound less soluble in
water, and more refractory (i.e., does not degrade). PCBs, in general, are relatively
insoluble, sorb strongly to organic matter (Kow = 750,000), and can volatilize (half-lives
are 10 to 12 hours) (Callahan et al., 1979). In lakes, volatilization is considered to be
an important loss process (Swackhamer and Armstrong, 1986). PCBs have a high
potential for bioaccumulation (BCF values range from 26,000 to 660,000 [Leifer et al,
1983]).
Persistence:
• PCBs can undergo photolysis, although specific rate constants in water were not found
(Leifler et al., 1983; Callahan, et al., 1979). PCBs do not hydrolyze at a significant rate
(Mabey et al., 1982). Biotransformation of PCBs with three or fewer chlorines (e.g.,
Aroclor 1221 and 1232) can occur, while other PCBs are essentially refractory (Brown
etal., 1987, Leifler etal., 1983). Highly chlorinated PCBs can degrade by dechlorination
reactions under anaerobic conditions to less chlorinated PCBs. These can then
biodegrade (Brown et al., 1987).
HEALTH EFFECTS
Carcinogenic! ty:
• PCBs administered orally have been shown to cause liver tumors in rats and mice
(Norback and Weltman, 1985; U.S. EPA 1985, 1987). They are classified as probable
human carcinogens: IARC class 2b; EPA class B2 (IARC, 1982; IRIS, 1988).
C-217
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Because PCBs can be contaminated with other compounds (e.g..chlorinated diben-
zofurans, dioxin). it is difficult to assess the cause of observed cancers in human exposure
incidents.
Mutagenic Activity:
• PCBs have not been shown to be mutagenic in either in vitro or in vivo experimental
tests (ATSDR, 1987).
• Negative results were obtained from the Ames bacterial test, the rat dominant lethal tests
and fruit fly chromosomal tests (U.S. EPA, 1984).
Reproductive Effects:
• PCBs are fetotoxic in rats, monkeys, minks, and rabbits (U.S. EPA, 1984).
• PCBs have not been found to be teratogenic in rats, mice, or monkeys (ATSDR, 1987).
Other Toxicological Effects:
The major toxic effect in animals is liver damage (IARC, 1978).
Other effects in animals include stomach, thyroid, and kidney damage, porphyria, and immunosup-
pressive effects (ATSDR, 1987).
Accidental and occupational exposures of humans (to relatively high levels of PCBs) have resulted
in chloracne and liver damage (Matthews and Dedrick, 1984; U.S. EPA, 1984; ATSDR, 1987).
Toxicological Effects Indices;
Cancer potency factor (CPF), total PCBs: 7.7 (rag/kg/day)"1 (ATSDR, 1987)
Reference Dose (RfD), Aroclor 1016:0.0001 mg/kg/day (ATSDR, 1987)
TWA-TLV (time-weighted average, threshold limit value), for occupational exposures:
Aroclor 1254* = 0.5 mg/m3 (ACGIH, 1986)
Aroclor 1242 = 1 rng/n? (ACGIH, 1986)
• Oral LDso: mink, 750 mg/kg (Aroclor 1221); rats, 1010 rag/kg (Arocior 1254).
Aroctors are mixture* of PCBi that have been designated using a four-digit numbering system. The first two digits indicate the
parent molecule (12 represents biphenyl). The next two digits indicate the percent chlorine. Up to 8 Cl atoms can be present
C-218
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Density, (g/cm3 at 25°C):
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor pressure, P (mm Hg):
Hydrolysis:
Henry's Law Constant KH ®
25°C(atm« m3/raol):
Log (Octanol-Water Partition
Coefficient), log KOW:
Soil Adsorption Coefficient, KOC (raL/g):
Fish Bioconcentration Factor, BCF:
200.7-375.7
liquid
N/A
275-420
1.15-1.58 at 25°C:
N/A
0.0027 (Aroclor 1260)
0.59 (Aroclor 1221)
7.7x101 T5 (Aroclor 1254)
6.7xlO'3 (Aroclor 1221)
not environmentally
significant
Hutzinger et al., 1974
Mackayetal., 1983
Callahan et al., 1979
Monsanto, 1974
Callahan etal., 1979
Mabeyetal., 1982
5.28X10"4 (Aroclor 1242) ATSDR, 1987
4.6xlO'3 (Aroclor 1260)
4.7 (Aroclor 1221)
6.8 (Aroclor 1260)
5.3xl05
26,000-660,000
31,200
Hansch and Leo, 1985
Mabey et al., 1982
Leiferetal., 1983
U.S. EPA, 1980
C-219
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Occupational Exposures to Chemicals. ACGIH, Cincinnati, OH.
ATSDR (Agency for Toxic Substances and Disease Registry). 1987. Draft Toxicological Profile
for Selected PCBs. ATSDR, U.S. Public Health Service.
Brown, J.F., Jr., B.L. Bedard, M.J. Brennan, J.C. Carnahan, H. Feng, and R.E. Wagner. 1987.
Polychlorinated Biphenyl Dechlorination in Aquatic Sediments. Science 236:709-712.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979. Water-Related
Environmental Fate of 129 Priority Pollutants, Vol. I. U.S. Environmental Protection Agency,
Office of Water Planning and Standards, Washington, DC. EPA-440/4-79-029a.
Ghirelli, R.P. F.H. Palmer. T.L. Spielman, M. Jung, R.L. Severeid, G.W. Bowes, D.B. Cohen.
1983. Polychlorinated Biphenyls. California State Water Resources Control Board. Special
Projects Report No. 83-lsp.
Hansch, C. and A.J. Leo. 1985. Log P Data Base. Pomona College, Claremom, CA.
Hutzinger, S., S. Safe, and V. Zitko. 1974. The Chemistry of PCBs. Chemical Rubber Publishing
Co., Cleveland, OH.
International Agency for Research on Cancer. 1978. LARC Monographs on the Evaluation of the
Carcinogenic Risk of Chemicals to Humans, Vol. 18. IARC, Lyont France.
International Agency for Research on Cancer. 1982. LARC Monographs on the Evaluation of the
Carcinogenic Risk of Chemicals to Humans, Vol. 29. IARC, Lyon, France.
IRIS. 1989. Integrated Risk Information System. U.S. Environmental Protection Agency,
Washington, DC.
Leifer, A., R.H. Brink, G.C. Thorn, K.G. Partymiller. 1983. Environmental Transport and
Transformation of Polychlorinated Biphenyls. U.S. Environmental Protection Agency,
Washington, DC. EPA-560/5-83-025.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, I.W. Partridge,
H. Jaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority Pollutants.
SRI International. EPA 440- 4-81-014.
Mackay, D., W.Y. Shiu, J. Billington, and G.L. Huang. 1983. Physical Chemical Properties of
Polychlorinated Biphenyls in Physical Behavior of PCBs in the Great Lakes. (D. Mackay, S.
Paterson, S.J. Eisenreich, and M.S. Simmons, eds.). Ann Arbor Science, Ann Arbor, MI.
C-220
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Matthews, H.B., and R.L. Dedrick. 1984. Pharmacokinetics of PCBs. Ann. Rev. Pharmacol.
Toxicol. 24:85-103.
Monsanto. 1974. PCBs-Aroclors Technical Bulletin 0/PL 360A. St. Louis, MO.
Norback, D.H., and R.H. Weltman. 1985. Polychlorinated Biphenyl Induction of Hepatocellular
Carcinoma in the Sprague-Hawley Rat. Envir. Health Perspective 60:97-105.
Swackhamer, D.L., and D.E. Armstrong. 1986. Estimation of the Atmospheric and Nonatmos-
pheric Contributions and Losses of Polychlorinated Biphenyls for Lake Michigan on the Basis of
Sediment Records of Remote Lakes. Environ. Science and Technol. 20(9):879-883.
U.S. EPA. 1976. Quality Criteria for Water. U.S. Environmental Protection Agency, Office of
Water and Hazardous Materials, Washington, DC.
U.S. EPA. 1980. Ambient Water Quality Criteria Document. U.S. Environmental Protection
Agency, Washington, DC. EPA 440/5-80 Series.
U.S. EPA. 1984. Health Effects Assessment for Polychlorinated Biphenyls. U.S. Environmental
Protection Agency, Office of Emergency and Remedial Response, Washington, DC. EPA-540/1-
86-004.
U.S. EPA. 1985. Draft Drinking Water Criteria Dcoument for Polychlorinated Biphenyls (PCBs).
U.S. Environmental Protection Agency, Washington, DC. NTIS #PB86-1183127AS.
U.S. EPA. 1987. Final Drinking Water Criteria Documents for Polychlorinated Biphenyls. U.S.
Environmental Protection Agency, Washington, DC. ECACO-CIN-414.
Versar. 1976. PCBs in the United States: Industrial Use and Environmental Distribution. Prepared
by Versar, Inc., for U.S. Environmental Protection Agency under contract 68-01-3259, Task 1.
Versar. 1980. Production and Use of PCB 1248 and 1254. Prepared by Versar, Inc., for U.S.
Environmental Protection Agency, Monitoring and Data Support Division, under contract 68-01-
3852, Task 22, Subtask 1.
Versar. 1983. Exposure Assessment for Incidentally Produced Polychlorinated Biphenyls (PCBs).
Prepared by Versar, Inc., for U.S. Environmental Protection Agency, Office of Toxic substances,
under contract 68-01-6251, Task 2.
Wilson, D.L. 1988. Project Summary Report on Decontamination of PCB-Gearing Sediments.
U.S. Environmental Protection Agency, Hazardous Waste Engineering Research Laboratory,
Cincinnati, OH. EPA/600/52-87/093.
C-221
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PCBs
OBSERVATIONS AND EFFECTS ON PISCIVOROUS WILDLIFE
During the last two decades, polychlorinated biphenyls (PCBs) were commonly detected in the
tissues and eggs of fish-eating birds. Szaro et ai. (1979) found PCBs in all eggs that were collected
from successful colonies of the herring gull and great black-backed gull in Maine. PCBs were also
detected in 50% of black-crowned night heron eggs from the intermountain western states (Kenny
et al., 1984). PCB residues were detected in 83% of the ospreys found dead or moribund in the
eastern states (Weimeyer et al., 1987), and in 90% of various heron species collected nationwide
(66 percent found dead or moribund) (Ohlendorf et al., 1981).
PCB residues were apparently the cause of death of many ring-billed gulls in southern Ontario in
1969 and 1973. Of the specimens sampled that died of no apparent disease, 61% had residues of
PCBs in the brain exceeding the lethal level of 310 ppm, and 30% had PCB concentrations greater
than 200 ppm in the brain (Stickel et al., 1984). DDE and dieldrin were also present in most
specimens. DDE residues were at a lethal level (250 ppm) in one specimen, and dieldrin residues
were at a lethal level (5 ppm) in more than 14% of the dead birds.
High reproductive failure of Lake Ontario herring gulls in the early 1970s prompted an investigation
of the organochlorine concentration in the gull eggs. PCB concentrations of up to 180 ppm were
detected. This level is one order of magnitude greater than the concentration found in eggs from
successful herring colonies on Lakes Erie, Huron, and Superior. Reproductive success of the Lake
Ontario herring gull colonies improved in latter years, parallelling a decline in PCB and other
organocnlorines concentrations in gull eggs (Weseloh et al., 1979). However, Oilman et al. (1978,
1977) suggest that high levels of mirex, not PCBs, in the eggs were to blame for the reproductive
failure.
In 1981 and 1982 duck hunters from New York and New Jersey were cautioned about eating wild
waterfowl. The waterfowl from the Hudson and Niagara River areas contained greater than 5 ppm
PCBs (fresh weight), which was in excess of FDA tolerances for poultry (Eisler, 1986).
Fish-eating mammals are also affected by PCBs. Mink are very sensitive to PCBs and are the most
sensitive of the wildlife species tested (Eisler, 1986). A concentration as low as 0.64 ppm wet weight
in food can cause reproductive failure in mink (Plantonow and Karstud, 1973). Ringer (1983)
determined that a concentration of 0.67 ppm in the mink diet causes reproductive failure. In the
field, residues of PCBs indicative of reproductive failure have been observed in mink from western
Maryland and northern Oregon (Henny et al., 1981; O'Shea et al., 1981).
River otters from the Columbia River in Oregon were found with high levels of PCBs. Henny et
al. (1981) suggest these elevated PCB levels may be contributing to the declining harvest of the
Columbia River otter.
Based on Plantonow and Karstud's 1973 mink study, the International Joint Commission (a United
States-Canada Treaty Organization) set an objective for PCB in fish at 0.1 ppm to protect piscivorous
C-222
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wildlife (Newell et ah, 1987). The State of New York proposed a slightly less conservative fish
flesh criterion of 0.13 ppm from the same data to protect piscivorous wildlife (Newell et ah, 1987).
The effects of PCBs on piscivorous wildlife are summarized in the following table:
Effects of PCB Concentrations on Piscivorous Wildlife
Animal
Birds
Mink
Mink
Piscivorous
Wildlife
Concentration
310 ppm (brain)
0.64 mg/kg
(diet)
0.67 mg/kg
(diet)
or
0.225 ppm/day
(diet)
Effect
death
reproduction
impaired
reproduction
impaired
Source
Stickel, 1984
Plantonow and
Karstud, 1973
Ringer, 1983
0.1 mg/kg/day
(diet)
0.13 ppm (diet)
0.11 ppm (diet)
NOEL
estimated
NOEL
cancer risk
oflO'2
Ringer, 1983
Newell et ah,
1987
Newell et ah,
1987
C-223
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REFERENCES
Eisler, R. 1986. Polychlorinated Biphenyl Hazards to Fish, Wildlife and Invertebrates: A Synoptic
Review. U.S. Fish Wildl. Serv. Biol. Rep. 85(1.7).
Oilman, A.P., G.A. Fox, D.B Peakail., S. M. Teeple, T.R. Carroll and G.T. Hatmes. 1977.
Reproductive Parameters and Egg Contaminant Levels of Great Lakes Herring Gulls. J. Wildl.
Manage. 41:458-468. (As cited in Eisler, 1985)
Oilman, A.P., D. J. Kallett, G.A. Fox, L.J. Allan, in J. Learning and D.B. Peakail. 1978. Effects
of Injected Organochlorines on Naturally Incubated Herring Gull Eggs. J. Wildl. Manage.
42:484-493. (As cited in Eisler, 1985)
Kenny, C.J., L.J. Blus, S. V. Gregory, and C. J. Stafford. 1981. PCBs and Organochlorine
Pesticides in Wild Mink and River Otters from Oregon. In Worldwide Furbearer Conference
Proceedings, Vol. HI, ed. J.A. Chapman and O. Pursley, pp. 1763-1780. Frostburgh, MD. (As cited
in Eisler, 1986)
Kenny, C.J., L.J. Blus, A.J. Krynitsky, and C.M. Bunck. 1984. Current Impact of DDE on
Black-Crowned Night-Herons in the Intermountain West. J. Wildl. Manage. 48(1):1-13.
Newell, A.J., D. Johnson, and L.K. Allen. 1987. Niagara River Biota Contamination Project: Fish
Flesh Criteria for Piscivorous Wildlife. Tech. Rep. 87-3. NY Dept Environ. Conserv., Div. Fish
Wildl., Bureau Environ. Protection.
Ohlendorf, H.M., D.M. Swineford, and L.N. Locke. 1981. Organochlorine Residues and Mortality
of Herons. Pest. Monit. J. 14(4):125-135.
O'Shea, T.J., T.E. Kaiser, G.R. Askins, and J.A. Chapman. 1981. Polychlorinated biphenyls in a
wild mink population. In Worldwide Furbearer Conference Proceedings, Vol. HI, ed. J.A. Chapman
and D. Pursley, pp. 1746-1752. Frostburgh, Md. (As cited in Eisler, 1986)
Plantonow, N., and C. Karstud. 1973. Dietary Effects of Polychlorinated Biphenyls on Mink. Can.
J. Comp. Med. 37:391-400. (As cited in Newell, 1987)
Ringer, R. 1983. Toxicology of PCBs in Minks and Ferrets. In PCBs: Human and Environmental
Hazards, ed. F.D'Itri and M. Kamrin, pp. 227-140. Butterworth Pub., Woburn, MA. (As cited in
Newell et al., 1987)
Stickel, W.H., L.F. Stickel, R.A. Dyrland, and D.L. Hughes, 1984. Aroclor 1254 Residues in Birds:
Lethal Levels and Loss Rates. Arch. Environ. Contam. Toxicol. 13:7-13.
Szaro, R.C., N.C. Coon, and E. Kolbe. 1979. Pesticides and PCB of Common Eider, Herring Gull
and Great Black-Backed Gull Eggs. Bull. Environm. Contam. Toxicol. 22:394-399.
C-224
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Weimeyer, S.N., S.K. Schmeling, and A. Anderson. 1987. Environmental Pollutant and Necropsy
Data for Ospreys from the Eastern United States, 1975-1982, J. Wildl. Diseases 23(2):279-291.
Weseloh, D.V., P. Mineau, D.J. Hallet, 1979. Organochlorine Contaminants and Trends in
Reproduction in Great Lakes Herring Gulls, 1974-1978. Trans. N. Am. Wildl. Nat. Resour. Conf.
44:543-557.
C-225
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C-226
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1,2,3,4 AND 1,23,5 TETRACHLOROBENZENE
1,2,3,4-TETRACHLOROBENZENE;
CAS No.: 634-66-2
CASPrefferredNomenclature:
Benzene, 1,2,3,4-tetrachloro-
Erapirical Formula: C6H2CL4
Synonyms and Common Names:
- 1,2,3,4 TCB
ci
ci
Cl
CI
1,2.3.4-tetrachtorotwizen*
1,2,3,5-TETRACHLOROBENZENE:
CAS No.: 634-90-2
CAS Preferred Nomenclature:
Benzene, 1,2,3,5-tetrachloro-
Empirical Formula: C6H2CL4
Synonyms and Common Names:
- 1,2,3,5 TCB
REGULATORY STATUS
Standards and Criteria!
• EPA Water Quality Criteria (for
human consumption of fish):
None established at present
• EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
• EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restrictions and Bans: None found.
EPA Drinking Water Health Advisories:
None established at present
Food and Drug Administration Action
Level for Fish:
None established at present
C-227
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SOURCES OF 1,2,3,4 AND 1,2,3,5 TETRACHLOROBENZENE
Total 1.2.3.4 and 1J.3.5 TCB Produced:
No current producers for either tetrachlorobenzene were identified (SRI, 1986).
Uses of 1.2.3.4 and 1.2JS.S TCB:
1,2,3,4 TCB has been used as a component of dielectric fluids (Verschueren, 1983).
• No information was found on the uses of 1,2,3,5 TCB.
Other Sources: None identified.
FATE IN ENVIRONMENT
Partitioning:
• Based on their properties, both 1,2,3,4 and 1,2,3,5 TCB are moderately volatile (es-
timated H = 1,300 to 1,400 atm • m3/mole), strongly sorb to soil (Kow = 43,000 to
83,000), and have a high potential for bioaccumulation. (BCF values from experimental
data ranged from 1,800 to 72,000.)
Persistence:
• Little information is available on the photolysis and hydrolysis of either 1,2,3,4 or 1,2,3,5
TCB, but based on the similarity of their structure to 1,2,4,5 TCB, neither process is
expected to be environmentally significant.
• Because of the high degree of chlorination of 1,2,3,4 and 1,2,3,5 TCB, biodegradation
is not expected to occur readily (Perwak et al., 1983). However, in a solution of 200
mg/L of 1,2,3,4 TCB.Pseudomonas bacteria were able to produce 33% ring degradation
after 120 hours at 30° (Verschueren, 1983). It is likely that 1,2,3,5 TCB would behave
similarly.
HEALTH EFFECTS
Carcinogenic! ty:
• No data found. EPA has not classified the potential carcinogenicity of either 1,2,3,4 or
1,2,3,5 TCB.
C-228
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Mutagenic Activity:
• No adequate data available (U.S. EPA, 1980).
Reproductive Effects:
• In rats 1,2,3,4 TCB reduced embryonic growth at the level that also caused maternal
poisoning effects (1000 mg/kg) (TDB, 1985).
• No data were found for 1 ,2,3,5 TCB.
Other
• Liver damage was produced in rats fed high doses of 1,2,3,4 TCB (1,000 to 6,600
mg/kg/day) (TDB, 1985).
• Rats fed 1,2,3,5 TCB (75 mg/kg) for 2 months developed enlarged adrenal glands. No
specific health effects were noted as a result of this condition (U.S. EPA, 1980).
ToxicologicaJ Effects Indices: None found.
C-229
-------
PHYSICAL/CHEMICAL PROPERTIES
1,2,3,4 TETRACHLOROBENZENE:
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (ram Hg):
215.9
solid needles
47.5
254
1.70
N/A
5.92
3.5 (22°C)
0.027 (25°C)
Verschueren, 1983
Verschueren, 1983
Weast, 1986
Weast, 1986
Kirk-Othmer, 1982
Banerjee, 1984
Verschueren, 1983
Kirk-Othraer, 1982
Henry's Law Constant, H @
250C(atra« m3/rnol):
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc (mL/g):
Fish Bioconcentration Factor, BCF:
1.3xlO"3 (calc.)
4.64
1.2xl04(calc.)
2100 (calc.)
1,125 to 12,000
(exptl.)
Lymanetal., 1982
Lyraan et al., 1982
Lyman et al., 1982;
U.S. EPA, 1980
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PHYSICAL/CHEMICAL PROPERTIES
1,2,3,5 TETRACHLOROBENZENE:
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
215.9
solid
54.5
246
N/A
N/A
5.10
2.4 (22°C)
1 @ 58.2°C
Verschueren, 1983
Weast, 1986
Weast, 1986
Banerjee, 1984
Verschueren, 1983
Weast, 1986
Henry's Law Constant, H @
25°C (atm • m3/mol):
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc (mL/g):
Fish Bioconcentration Factor, BCF:
1.4xlO'3 (calc.)
4.92
2.0xl04(calc.)
4,000 (calc.)
1,800 to 72,000
(exptl.)
Lymanetal., 1982
Leo,1983
Lymanetal., 1982
Lymanetal., 1982
U.S. EPA, 1980;
Verschueren, 1983
C-231
-------
REFERENCES
Banerjee, S. 1984. Solubility of Organic Mixtures in Water. Environ. Sci. Technol. 18:587-591.
Hawley, G.G. 1981. The Condensed Chemical Dictionary. 10th ed. VanNostrandReinhold.Inc.,
New York.
I ARC {International Agency for Research on Cancer). 1977. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans. Vol. 15. IARC, Lyon, France.
Kirk-Othmer Encyclopedia of Chemical Technology. 1982. 3rd ed. John Wiley and Sons, Inc.,
New York.
Leo, A.J. 1983. Log P Parameter Database. Pomona College, Claremont, CA.
Lyman, W.G., W.F. Reehl, andD.H. Rosenblatt. 1982. Handbook of Chemical Property Estimation
Methods. McGraw-Hill Book Co., New York
Oliver, B.G., and A.J. Niimi. 1983. Bioconcentration of Chlorobenzenes from Water by Rainbow
Trout: Correlations with Partition Coefficients and Environmental Residues. Environ. Sci. Tech-
nol. 17:287-291.
Perwak J., E. Cole, S. Coons, N. Green, W. Lyman, M. Miller, J.H. Ong, and K. Scow. 1983.
Evaluation of Waterborne Exposure Pathways to Paragraph 4(c) Pollutants. U.S. EPA Draft Report.
EPA Contract 68-01-5949.
SRI (Stanford Research Institute). 1986. Directory of Chemical Producers. Stanford Research
Institute, Menlo Park, CA.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine, TDB Peer Review Committee.
U.S. EPA. 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. U.S. Environmental
Protection Agency, Office of Water Regulations and Standards, Criteria and Standards Division,
Washington, DC. EPA 440/5-80-028.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Weast, R.C., ed. 1986. CRC Handbook of Chemistry and Physics. 67th ed. CRC Press, Boca
Raton, FL.
C-232
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1,2,4,5 TETRACHLOROBENZENE
CAS No.: 95-94-3
CAS Preferred Nomenclature:
Benzene, 1,2,4,5-tetrachloro-
Empirical Formula: C6H2CU
Synonyms and Common Names:
- 1.2,4,5 TCB
- 5-Tetrachlorobenzene
- s-Tetrachlorobenzene
,2,4.5-tetf»chlorob«ni»n«
REGULATORY STATUS
Standards and Criteria:
• EPA Water Quality Criteria (for human
consumption of fish)(45 FR 79318):
• EPA Ambient Water Quality Criteria «
(for protection of aquatic organisms)
ORB, 1989):
Freshwater Saltwater
Acute, ng/L 250 160
Chronic, [ig/L 50 129
Above are LECs (Lowest Effect Con-
centration).
• Food and Drug Administration Action
Level for Fish:
None established at present
Use Restrictions and Bans: None found.
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
EPA Drinking Water Health Advisories:
None established at present
C-233
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SOURCES OF 1,2,4,5 TETRACHLOROBENZENE
Total 1,2,4,5 Tetrachlorobenzene Produced:
• In 1977, Dow Chemical produced between 10 million and 50 million pounds of 1,2,4,5
TCB (Perwak et al., 1983).
Uses of 1,2,4,5 Tetrachlorobenzene:
• 1,2,4,5 TCB is a chlorophenoxy compound used as a precursor for the production of the
herbicide, 2,4,5 T(2,4,5 trichlorophenoxyacetic acid). 2,4,5 T was a major component
of Agent Orange, the defoliant used in Vietnam (Klaassen et al., 1986).
1,2,4,5 TCB has also been used as a precursor for the production of other organic
chemicals and in the dye industry (Perwak et al., 1983).
• It has also been utilized in the moisture-proofing of electrical insulation (Perwak et al.,
1983).
Other Sources: None identified.
FATE IN ENVIRONMENT
Partitioning:
• Based on its physical/chemical properties, 1,2,4,5 TCB is highly volatile (H = 0.027 atm
• m /mole), strongly sorbs to soil (Row =47,000), and has a high potential for bioac-
cumulation. BCF values from experimental data ranged between 5,300 and 13,000.
Persistence:
• Photolysis is not expected to be significant for 1,2,4,5 TCB since little absorption occurs
in the solar region (>290 mm) for the chemical (Perwak et al., 1983).
• Biodegradation is not expected to occur readily because of the high degree of chlorina-
tion, although Pseudomonas bacteria are able to produce 30% ring disruption of a 200
mg/L solution at 30° after 120 hours (Perwak et al., 1983; Verschueren, 1983). In one
study under anaerobic conditions, chlorobenzenes persisted for 7 years (TDB, 1985).
• Hydrolysis of 1,2,4,5 TCB is not expected to be environmentally significant (Perwak
etal., 1983).
1,2,4,5 TETRACHLOROBENZENE OBSERVED IN THE ENVIRONMENT
• No data available.
C-234
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HEALTH EFFECTS
Carcinogenic! ty:
• EPA has not yet evaluated the potential carcinogenicity of 1,2,4,5 TCB (IRIS, 1989).
Mutagenic Activity:
• No adequate data available (U.S. EPA, 1980).
Reproductive Effects: No data found.
Other Toxicological Effects:
• No reported effects on humans.
• Rats fed 1,2,4,5 TCB for 13 weeks developed kidney damage at relatively moderate
doses (0.34 mg/kg/day). Liver damage was also reported to occur at higher doses (3.4
to 32 mg/kg/day). A higher dose (200 mg/kg/day) caused a significant increase in deaths
(IRIS, 1989).
• Dogs fed 1,2,4,5 TCB (5 mg/kg/day) for 2 years showed no adverse health effects (IRIS,
1988).
Toxicological Effects Indices:
• Reference Dose (RfD): SxlO"4 mg/kg/day (IRIS, 1989).
• Oral LDso: rats, 1500 mg/kg; mice, 1035 mg/kg (Tatken and Lewis, 1984).
C-235
-------
PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @
25°C(atm* m3/mol):
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient,Koc (mL/g):
Fish Bioconcentration Factor,
BCF:
215.9
solid
139.5
248
1.833
N/A
6.0
0.3 (22°C)
0.045 (25°C)
0.027 (calc.)
4.67
1.6xl03
5300 to 13000
(exptl.)
1125
Windholz, 1983
Kirk-Othmer, 1984
Kirk-Othmer, 1984
Kirk-Othmer, 1984
PHRED, 1988
Verschueren, 1983
Kirk-Othmer, 1984
Lymanetal., 1982
PHRED, 1988
PHRED, 1988
Oliver and Niimi,
1983
PHRED, 1988;
U.S. EPA, 1980
C-236
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REFERENCES
IRIS. 1989. Integrated Risk Information System. U.S. Environmental Protection Agency,
Washington, DC.
Kirk-Othmer Encyclopedia of Chemical Technology. 1984. 3rd ed. John Wiley and Sons, Inc.,
New York.
Klaassen, C.D., M.O. Amdur,andJ. Doull.eds. 1986. Casarett and DoinTs Toxicology: The Basic
Science of Poisons. 3rd ed. Macmillan Publishing Co., New York.
Lyman, W.G., W.F. Reehl, and D.H. Rosenblatt 1982. Handbook of Chemical Property Estima-
tion Methods. McGraw-Hill Book Co., New York.
Oliver, B.C., and AJ. Niimi. 1983 Bioconcentration of Chlorobenzene from Water by Rainbow
Trout: Correlations with Partition Coefficients and Environmental Residues. Environ. Sci. Tech-
nol. 17:287-291.
Perwak J., E. Cole, S. Coons, N. Green, W. Lyman, M. Miller, J.H. Ong, and K. Scow. 1983.
Evaluation of Waterborne Exposure Pathways to Paragraph 4(c) Pollutants. Draft Report U.S.
Environmental Protection Agency, Washington, DC. EPA Contract 68-01-5949.
PHRED. 1988. Public Health Risk Evaluation Database. U.S. Environmental Protection Agency,
Office of Emergency and Remedial Response, Washington, DC.
Tatken, R.L., and R.J. Lewis, Sr., eds. 1983. Registry of Toxic Effects of Chemical Substances.
(RTECS). 1981-82 ed.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine, TDB Peer Review Committee.
U.S. EPA. 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. U.S. Environmental
Protection Agency, Office of Water Regulations and Standards, Criteria and Standards Division,
Washington, DC. EPA 440/5-80-028.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Weast, R.C., ed. 1986. CRC Handbook of Chemistry And Physics. 67th ed. CRC Press, Boca
Raton, FL.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck & Co., Rahway, NJ.
C-237
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C-238
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1,2,3 TRICHLOROBENZENE
CAS No.: 87-61-6
CAS Preferred Nomenclature:
Benzene, 1,2,3-trichloro-
Empirical Formula:
Synonyms and Common Names:
- 1,2,6-trichlorobenzene
- vic-trichlorobenzene
,2,3-trichlorobenzen«
REGULATORY STATUS
Standards and Criteria:
• EPA Water Quality Criteria
(for human consumption of fish):
None established at present
• EPA Ambient Water Quality Criteria
(for protection of aquatic
organisms):
None established at present
• EPA Drinking Water Standard
Maximum Contaminant Level:
None established at present
Use Restrictions and Bans: None found.
EPA Drinking Water Health
Advisories:
None established at present
Food and Drug Administration Action
Level for Fish:
None established at present
SOURCES OF 1,2,3 TRICHLOROBENZENE
Tv,tal 1,2,3 Trichlorobenzene Produced:
• In 1977, Dow Chemical Company in Midland, Michigan, produced between 1 and 10
million pounds of 1,2,3 trichlorobenzene (Perwak et al., 1983). In 1986, Standard
Chlorine Chemical (Delaware City, Delaware) was the only producer, but production
figures are not available (SRI, 1986).
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Uses of 1,2,3 Trichlorobenzene:
• 1,2,3 trichlorobenzene is not commonly used directly, but instead is used as an inter-
mediate in chemical synthesis (Sax, 1986).
• 1,2,3 trichlorobenzene is used as a solvent for high-melting products, as a coolant in
electrical installations and glass tempering, for polyester dying, termite preparations,
synthetic transformer oil, lubricants, heat transfer medium, and insecticides (Sax, 1986).
Other Sources: None found.
FATE IN ENVIRONMENT
Partitioning;
• Based on its physical/chemical properties, 1,2,3 trichlorobenzene sorbs moderately
strongly to sediment (Kow = 12,900). Volatilization can occur from water at a moderate
rate (H = 9.3x10 atm • m /mol). The potential for bioaccumulation is high based on
experimental data. (BCF ranged between 1,200 and 2,600.)
Persistence:
• Direct photolysis of 1,2,3 trichlorobenzene is not likely to occur in natural waters
(Perwak et al., 1983).
Hydrolysis is not an environmentally significant process (Ellington et al., 1986).
• Biotransformation of 1,2,3 trichlorobenzene may occur but at an unknown rate. No
degradation occurred beneath the water table (anaerobic conditions) (TDB, 1986).
Perwak et al. (1983) reported that 10% of 1,23 trichlorobenzene degraded after 12 weeks
in a soil containing high organic matter and up to 8% volatilized, while only 2% degraded
in a soil with low organic material content (up to 40% volatilized). Degradation by
Pseudomonas bacteria is more rapid; at 30°, 87% ring disruption occurred within 120
hours in a concentration of 200 mg/L 1,2,3 trichlorobenzene (Verschueren, 1983).
HEALTH EFFECTS
Cardnogenicity;
• No data found. EPA has not classified the potential carcinogenicity of 1,2,3
trichlorobenzene.
Mutagenic Activity: No data found.
C-240
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Reproductive Effects: No data found.
Other Toxicological Effects:
• Trichlorobenzenes can cause liver damage in humans and animals (Gosselin, 1984;
HSDB, 1988).
• 1,2,3 trichlorobenzene is irritating to human eyes and mucous membranes of the
respiratory tract (Sax, 1986; HSDB, 1988).
• 1,2,3 trichlorobenzene is considered moderately toxic to humans with acute or chronic
ingestion or inhalation (Sax, 1986).
• At high doses, technical-grade trichlorobenzene (30% 1,2,3 TCB and 70% 1,2,4 TCB)
is moderately irritating to rabbit skin (HSDB, 1988).
Toxicological Effects Indices:
• None found for human exposure.
• Chronic Hazard Level for rats: 0.01 mg/kg/day/5.5 month (loss of hair) (Sax, 1986).
C-241
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (ram Hg):
181.45
solid, white
crystals
53.5
218.5
1.69
N/A
12 @ 22°C
0.07 @ 25°C
Kirk-Othmer, 1982
Sax, 1986
Kirk-Othmer, 1982
Kirk-Othmer, 1982
Windholz, 1983
Verschueren, 1983
U.S. EPA, 1980
Henry's Law Constant,
H @ 25°C (aim • m3/mol):
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, K (mL/g):
Fish Bioconcentration Factor, BCF:
9.3x10"* (calc.)
4.11
4600 (calc.)
1200-2600
(exptl.)
Lyman et al., 1982
Leo,1983
Lyman et al., 1982
Oliver and Niimi,
1983
C-242
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REFERENCES
Ellington, J.J., F.E. Stancil, Jr., and W.D. Payne. 1986. Measurement of Hydrolysis Rate Constants
for Evaluation of Hazardous Waste Land Disposal. Vol. I. U.S. Environmental Protection Agency,
Athens, GA. EPA/600/3-86/043.
Gosselin, R.E., R.P. Smith, H.C. Hodge, and I.E. Braddock. 1984. Clinical Toxicology of
Commercial Products. 5th ed. The Williams and Wilkins Co., Baltimore.
HSDB. 1988. Hazardous Substances Data Base. National Library of Medicine, Bethesda, MD.
Kirk-Othmer Encyclopedia of Chemical Technology. 1982. 3rd ed. John Wiley and Sons, Inc.,
New York.
Leo, A.J. 1983. Log P Parameter Database, Issue #24 (dated 12/16/83). Obtained from the
MedChem Project, Pomona College, Claremont, CA.
Lyman, W.G., W.F. Reehl, and D.H. Rosenblatt 1982. Handbook of Chemical Property Estima-
tion Methods. McGraw-Hill Book Co., New York
Oliver, B.G., and A.J. Niimi. 1983. Bioconcentration of Chlorobenzenes from Water by Rainbow
Trout: Correlations with Partition Coefficients and Environmental Residues. Environ. Sci. Tech-
nol. 17:287-291.
Perwak, J., E. Cole, S. Coons, N. Green, W. Lyman, M. Miller, J.H. Ong, and K. Scow. 1983.
Evaluation of Waterborne Exposure Pathways to Paragraph 4(c) Pollutants. Draft Report U.S.
Environmental Protection Agency, Washington, DC. EPA Contract 68-01-5949.
Sax, N.I. 1986. Hazardous Chemicals, Information Annual, No. 1. Van Nostrand Reinhold Co.,
New York.
SRI (Stanford Research Institute). 1986. Directory of Chemical Producers. Stanford Research
Institute, Menlo Park, CA.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine's MEDLARS system, National Library of Medicine, TDB Peer Review Committee.
U.S. EPA. 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. U.S. Environmental
Protection Agency, Office of Water Regulations and Standards, Washington, DC. EPA 440/5-80-
028.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
C-243
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Windholz, M, ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck and Co., Rahway, NJ.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British Crop
Protection Council, Croydon, England.
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1,2,4 TRICHLOROBENZENE
CAS No.: 120-82-1
CAS Preferred Nomenclature:
Benzene, 1,2,4,-trichloro-
Empirical Formula:
ci
1 ,2,4-trichlorobenzan*
Synonyms and Common Names:
- Hostetex L-PEC
- Unsym-Trichlorobenzene
- 1 ,2,4 Trichlorobenzol
REGULATORY STATUS
Standards and Criteria:
• EPA Water Quality Criteria (for human • EPA Drinking Water Health Advisories:
consumption of fish) (U.S. EPA, 1989): None established at present
15.4 mg/L
• EPA Ambient Water Quality Criteria • Food and Drug Administration Action
(for protection of aquatic organisms): Level for Fish:
None established at present None established at present
• EPA Drinking Water Standard Maxi-
mum Contaminant Level:
(U.S. EPA, 1989)
Proposed MCLG 9 ng/L
• Use Restrictions and Bans: None
found.
SOURCES OF 1 ,2,4 TRICHLOROBENZENE
Total 1,2,4 Trichlorobenzene Produced:
• In 1979, 16 million pounds of 1,2,4 trichlorobenzene were produced (Perwak et al.
1983).
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Uses of 1,2,4 Trichlorobenzene:
• 1,2,4 trichlorobenzene is used as a solvent in chemical manufacturing, in dyes and
intermediate production, and in transformer dielectric fluid. In addition, it is used as a
degreaser, lubricant, and termiticide (Verschueren, 1983; Sax, 1986).
Other Sources: None found.
FATE IN ENVIRONMENT
Partitioning;
• Based on its physical/chemical properties, 1,2,4 trichlorobenzene strongly sorbs to
organics (Kow=19,900) andean volatilize (H = 2.3xlO~3 atm • m3/mol). In addition,
the potential for bioaccumulation is high (BCF estimated as 2,800).
Persistence:
1,2,4 trichlorobenzene is not expected to undergo hydrolysis at an environmentally
significant rate (Mabey et al., 1982).
• The biotransformation rate of 1,2,4 trichlorobenzene is reportedly very slow. After 135
hours, no degradation of 0.1 mg/L 1,2,4 trichlorobenzene exposed to normal sewage
occurred. However, 56% was degraded by adapted sewage (Verschueren, 1983).
Psetidomonas bacteria transformed 1,2,4 trichlorobenzene at a faster rate, with con-
centrations of 200 mg/L (at 30°) undergoing 92% ring disruption after 120 hours
(Verschueren, 1983).
HEALTH EFFECTS
Cardnogenidty:
• McNamara et al. (1981) reported no increased incidence of tumors in a 6-month feeding
study. A 2-year skin painting study with 1,2,4 trichlorobenzene demonstrated no
increase in tumors in mice (HSDB, 1988). These studies, however, are not considered
adequate for carcinogenicity assessment
• No tumor development was observed in mice inhaling 600 ppm 1,2,4 trichlorobenzene
daily for 6 months (U.S. EPA, 1980).
• EPA has not classified the carcinogenic potential of 1,2,4 trichlorobenzene.
Mutagenic Activity;
• 1,2,4 trichlorobenzene was found to be nonmutagenic in the bacterium Salmonella
typhimurium (McNamara et al.. 1981).
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Reproductive Effects:
While no increases in teratogenicity or embryo lethality were observed in rats fed 360
mg/kg/day on days 9-13 of gestation, retarded embryonic development occurred
(Kitchin and Ebron, 1983).
Other Toxicological Effects:
Chronic (long-term, low-dose) exposure to 1,2,4 trichlorobenzene has resulted in liver,
kidney, brain, and lung damage in animals (Sittig, 1985; HSDB, 1988).
In humans, exposure to 1,2,4 trichlorobenzene has been reported as causing central
nervous system stimulation, headache, dermatitis, and skin, eye, and throat irritation
(Sax, 1986; HSDB, 1988).
At high doses, technical-grade trichlorobenzene (30% 1,2,3 TCB and 70% 1,2,4 TCB
is moderately irritating to rabbit skin (HSDB, 1988).
Toxicological Effects Indices;
Reference Dose (RfD): 2x10-2 mg/kg/day (PHRED, 1988).
TLV-C (threshold limit value-ceiling — not to be exceeded during occupational ex-
posure): 40 mg/m3 (ACGIH, 1986).
Oral LDso: rat, 756 mg/kg (U.S. EPA, 1980; HSDB, 1988).
C-247
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H @ 25°C (atm • m3/mol):
Log (Octanol-Water Parti-
tion Coefficient), log Kow:
Soil Adsorption Coefficient,
Koc (mL/g):
Fish Bioconcentration Factor, BCF:
181.45
clear liquid
17.15
213.8
1.45(20/4°C)
N/A
30 @ 25°C
0.29 @ 25°C
2.3x10-3
4.3
9.2x103
2800 (calc.)
Kirk-Othmer, 1984
Kirk-Othmer, 1984
Kirk-Othmer, 1984
Weast, 1986
Sax, 1986
U.S. EPA, 1980
Mabey et al., 1982
PHRED, 1988
PHRED, 1988
PHRED, 1988;
ICF, 1985
C-248
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REFERENCES
ACGIH (American Conference for Governmental Industrial Hygienists). 1986. Threshold Limit
Values for Chemical Substances in the Work Place. ACGIH, Cincinnati, OH.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings, R.L.
Durt'ee, F.C. Whitmore, B. Maestri. 1979. Water Related Environmental Fate of 129 Priority
Pollutants. U.S. Environmental Protection Agency, Washington DC. EPA-440/4-79-029a.
HSDB. 1988. Hazardous Substances Data Base. National Library of Medicine, Bethesda, MD.
ICF, Inc., 1985. Draft Superfund Public Health Evaluation Manual.
Kirk-Othmer Encyclopedia of Chemical Technology. 1982. 3rd ed. John Wiley and Sons, Inc.,
New York.
Kitchin, K.T., and M.T. Ebron. 1983. Material Hepatic and Embryonic Effects of 1,2,4-
Trichlorobenzene in the Rat. Environ. Res. 31:362-373.
Lyman, W.G., W.F. Reehl, and D.H. Rosenblatt 1982. Handbook of Chemical Property Estima-
tion Methods. McGraw-Hill Book Co., New York
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, J.W. Patridge,
H. Saber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority Pollutants.
SRI International. EPA 440/4-81-014.
McNamara, P.W., M. Byrne, M. Goyer, P. Lucas, K. Scow, and M. Wood. 1981. An Exposure
and Risk Assessment for 1,2,4,-Trichlorobenzene. U.S. Environmental Protection Agency, Office
of Water Regulations and Standards, Washington, DC. EPA 440/4-85-017.
Perwak, J., E. Cole, S. Coons, N. Green, W. Lyman, M. Miller, J.R Ong, and K. Scow. 1983.
Evaluation of Waterborne Exposure Pathways to Paragraph 4(c) Pollutants. Draft Report U.S.
Environmental Protection Agency, Washington, DC. EPA contract 68-01-5949.
PHRED. 1988. Public Health Risk Evaluation Database. U.S. EPA Office of Emergency and
Remedial Response, Washington, DC.
Sax, N.I. 1986. Hazardous Chemicals Information Annual. No. 1. Van Nostrand Reinhold Co.,
New York.
Sittig, M. 1985. Handbook of Toxic and Hazardous Chemicals and Carcinogens. 2nded. Noyes
Publications: Park Ridge, NJ.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Committee.
C-249
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U.S. EPA. 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. U.S. Environmental
Protection Agency, Office of Water Regulations and Standards, Criteria and Standards Division,
Washington, DC. EPA 440/5-80-028.
U.S. EPA. 1987. Draft of RCRA Facility Investigation (RFI) Guidance. U.S. Environmental
Protection Agency, Office of Solid Waste, Washington, DC. EPA 530/SW-87-001.
U.S. EPA, 1989. Draft Summary of Drinking Water Regulations and Health Advisories, U.S.
Environmental Protection Agency, Office of Drinking Water, Washington, DC.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Weast, R.C., ed. 1986. CRC Handbook of Chemistry and Physics. 67 ed. CRC Press, Boca Raton,
FL.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British Crop
Protection Council, Croydon, England.
C-250
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1,3,5 TRICHLOROBENZENE
1,3,5-tricbiorob«nz«n«
CAS No.: 108-70-3
CAS Preferred Nomenclature:
Benzene, 1,3.5-trichloro-
Empirical Fonnula: C6H3C13
Synonyms and Common Names:
- sym-Trichlorobenzene
REGULATORY STATUS
Standards and Criteria;
• EPA Water Quality Criteria (for human • EPA Drinking Water Health Advisories:
consumption of fish): None established at present
None established at present
• EPA Ambient Water Quality Criteria • Food and Drug Administration Action
(for protection of aquatic organisms): Level for Fish:
None established at present None established at present
• EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restrictions and Bans: None found.
SOURCES OF 13,5 TRICHLOROBENZENE
Total 1,3,5 Trlchlorobenzene Produced;
• In 1986,1,3,5 trichlorobenzene was produced by Southland Corporation. No production
data are available (SRI, 1986).
Uses of 1,3,5 Trichlorobenzene;
• 1,3,5 trichlorobenzene is commonly used as an intermediate in chemical synthesis of
other organic compounds (Sax, 1984).
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1,3,5 trichlorobenzene is also used as a solvent for dyes in textile manufacture (Kirk-
Othtner, 1982).
Other Sources: None found.
FATE IN ENVIRONMENT
Partitioning:
• Based on its physical/chemical properties, 1,3,5 trichlorobenzene is moderately volatile
(H estimated to be 6.0 x 10~3 atm • m3/mol), is moderately sorbed to soil (Kows30,000),
and has a high potential for bioaccumulation. (BCF from experimental data range from
1,800 to 4,100.)
Persistence:
• Hydrolysis and aqueous photolysis are expected to be unimportant under environmental
conditions based on the structural similarity with 1,2,3 and 1,2,4 trichlorobenzene.
• Using fresh sewage, 1,3,5 trichlorobenzene at an initial concentration of 1.0 mg/L was
not degraded after 135 hours, compared with 47% degraded using acclimated sewage.
Biodegradation by Pseudomonas bacteria was found to be more rapid, with 78% of an
initial 200-mg/L sample degraded (ring disruption) after 120 hours at 30°C (Verschueren,
1983).
13,5 TRICHLOROBENZENE OBSERVED IN THE ENVIRONMENT
• No data available.
HEALTH EFFECTS
Carcinogeni city:
• No data found. EPA has not classified the potential carcinogenicity of 1,3,5
trichlorobenzene.
Mutagenic Activity: No data found.
Reproductive Effects:
• No teratogenic effects were observed in rats when mothers were fed 13,5 trichloroben-
zene at doses between 75 and 600 mg/kg. There were some mild changes in bone
development (at unspecified doses) (U.S. EPA, 1985).
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Other Toxicological Effects:
1,3,5 trichlorobenzene has been foound to be moderately irritating to human skin, eyes,
and mucous membranes (Sax, 1984).
• Rats that inhaled 1,3,5 trichlorobenzene on a schedule simulating possible occupational
exposures (6 hours/day, 5 days/week, for 13 weeks) developed some reversible changes
to lung tissues (U.S. EPA, 1985).
• It has been reported that trichlorobenzenes cause liver damage to humans and animals,
but it is not known which one (1,3,5, 1,2,3 or 1,2,4 trichlorobenzene) is the toxic
component (Gosselin, 1984).
Toxicological Effects Indices: None found.
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
181.45
solid
63.4
208.5
N/A
N/A
5.88 @ 20°C
0.15 (25°C)
Kirk-Othmer, 1982
Windholz, 1983
Kirk-Othmer, 1982
Verschueren, 1983
U.S. EPA, 1980
Henry's Law Constant,
H @ 25°C (atm • m3/mol):
Log (Octanol-Water
Partition Coefficient), Log KOW:
Soil Adsorption Coefficient, Koc(mL/g):
Fish Bioconcentration Factor, BCF:
6.0x10-3 (calc.)
4.49
9100 (calc.)
1400 (calc.)
1800-4100
(exptl.)
Lymanetal., 1982
Leo,1983
Lymanetal., 1982
Lyman et al., 1982
Oliver & Niimi, 1983
C-254
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REFERENCES
Gosselin, R.E., R.P. Smith, H.C. Hodge, and I.E. Braddock. 1984. Clinical Toxicology of
Commercial Products. 5th ed. The Williams and Wilkins Co., Baltimore.
Kirk-Othmer Encyclopedia of Chemical Technology. 1982. 3rd ed. John Wiley and Sons, Inc.,
New York.
Leo, A.J. 1983. Log P Parameter Database, Pomona College, Claremont, CA.
Lyman, W.G., W.F. Reehl, and D.H. Rosenblatt. 1982 Handbook of Chemical Property Estimation
Methods. McGraw-Hill Book Co., New York.
Oliver, B.G., and A.J. Niimi. 1983. Bioconcentration of Chlorobenzenes from Water by Rainbow
Trout: Correlations with Partition Coefficients and Environmental Residues. Environ. Sci. Tech-
nol. 17:287-291.
Sax, N.I. 1984. Dangerous Properties of Industrial Materials. 6th ed. VanNostrandReinholdCo.,
New York.
SRI (Stanford Research Institute). 1986. Directory of Chemical Producers. Stanford Research
Institute, Menlo Park, CA.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Committee.
U.S. EPA. 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. U.S. Environmental
Protection Agency, Office of Water Regulations and Standards, Criteria and Standards Division,
Washington, DC. EPA 440/5-80-028.
U.S. EPA. 1985. Health Assessment Document for Chlorinated Benzenes. U.S. Environmental
Protection Agency, Office of Health and Environmental Assessment, Washington, DC. EPA
600/8-84-015F.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck & Co., Rahway, NJ.
C-255
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C-256
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TRIFLURALIN
CAS No.: 1582-09-8
CAS Preferred Nomenclature:
Benzenamine, 2,6-dinitro-N,N-
dipropyl-4-(trifluoromethyl)-
Empirical Formula: C13H16F3N3O4
Synonyms and Common Names:
- Treflan - Triflurex
- Trefanocide - Crisalin
- Elancolan - Trim
- Ipersan - Ipifluor
C,HT-N—C,H,
REGULATORY STATUS
Standards and Criteria:
• EPA Water Quality Criteria (for human
consumption of fish):
None established at present
EPA Ambient Water Quality Criteria
(for protection of aquatic
organisms):
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
• EPA Drinking Water Health Advisories
(IRIS, 1989):
child TIP kg):
1-day, 10-day, long-term
exposures = 30 \ig/L
adult (70 kg):
long-term exposure = 30 jig/L
lifetime exposure = 2 jig/L
• EPA Tolerance Levels in foods for
human consumption (40 CFR 180.207):
0.05 to 2 ppm
Food and Drug Administration Ac don
Level for Fish:
None established at present
Use Restrictions and Bans:
As of August 1982, all technical formulations were to be formulated to contain less than
0.5 ppm of N-nitrosamine contaminants (47 FR 33777).
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SOURCES OF TRIFLURALIN
Total Trifluralin Produced:
• The herbicidal properties of the dinitroanilines, particularly trifluralin, were first
reported in 1960 (Farm Chemicals Handbook, 1985). In 1982,25,000 tons of trifluralin
were produced, of which 18,000 tons were used in the U.S. (Green etal., 1987). In 1986,
only the Eli Lilly Co. produced trifluralin (SRI, 1986).
Uses of Trifluralin:
• Trifluralin is used as a herbicide to control annual grasses and broadleaf weeds in a wide
variety of agricultural crops and in some domestic and industrial situations (Worthing,
1983; U.S. EPA, 1987a).
• The primary uses of trifluraiin are on cotton and soybeans. In 1987, the uses were
divided as follows: 65% on soybeans, 19% on cotton, 8% on sunflowers, 4% on wheat,
and 6% for all other purposes (U.S. EPA, 1987a).
• Trifluralin is registered for use on 40 broadleaf crops (McEwen and Stephenson, 1979).
It is also used to control weeds in orchards and in vegetable crops (47 FR 33777).
• Nonagricultural uses are the control of grasses (e.g., barnyard grass, chickweed,
crabgrass) in rights-of-way, for outdoor domestic sites and industrial sites (McEwen and
Stephenson, 1979; Thomson, 1983; Farm Chemicals Handbook, 1985; U.S. EPA,
1987a).
Other Sources: None identified.
FATE IN ENVIRONMENT
Partitioning;
• Based upon its physical/chemical properties, trifluralin is predicted to volatilize relative-
ly slowly from both water (H = 1.9 x 10"6 atm • ra3/raol) and soil surfaces (P/SKoc =
3.3 x 10 mm Hg • L/mg, corresponding to an estimated volatilization half-life of 48
days), adsorb relatively strongly to soils and sediments (Koc=218,800), and have a high
potential for bioaccumulation (BCF = 1.8 x 103 to 6.0 x 103) (LymanetaL, 1982).
• Trifluralin appears to have a very low potential for leaching. Gray et al. (1982) reported
that after elution with 60 cm of water, >90% of the applied trifluralin and >99% of the
trifluralin accounted for remained in the upper 5 cm of soil columns packed with a sandy
loam (oc = 0.8%), a silt loam (oc = 2.8%), or a clay loam (oc = 1.3%) soil. Helling and
Turner (1968) reported that trifluralin was essentially immobile (Rf = 0.0) on soil
thin-layer chromatography plates using 14 different soils.
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Bionomics (1973) reported trifluralin tissue concentrations of 5.5 to 12 mg/kg in bluegill
sunfish exposed to an average of 7.9 |ig/L over 35 days. The tissue to water concentra-
tion ratios correspond to non-steady-state bioconcentration factors of 7.0 x 10 to 1.5 x
103.
Persistence:
• Mosier and Saunders (1978) reported that trifluralin at 30°C did not undergo any
detectable hydrolysis at pH 3,6, or 9 over a 32-day period.
• Trifluralin is susceptible to photolytic degradation (McEwen and Stephenson, 1979;
TDB, 1985). A study by Zepp and Baughman reported a half-life of approximately 1
hour for trifluralin in water exposed to sunlight (TDB, 1985).
• Trifluralin is also biodegradable; a Pseudomonas bacterium has been found that decom-
poses it in aqueous media (Lyman et al., 1982.) The rate of biodegradation is uncertain.
Parr and Smith (1973) reported that the rate of trifluralin degradation in a silt loam soil
was much greater under anaerobic conditions (<1% remaining after 20 days incubation)
than under aerobic conditions (approximately 85% remaining after 20 days incubation).
• In soil, half-lives of 3 to more than 27 weeks have been reported (Verschueren, 1983).
The associated dissipation rates ranged from 0.033/day to 0.0037/day. Other determina-
tions of trifluralin half-lives are:
- 21 to 35 days in irrigated soils
- 126 to greater than 190 days in a sandy loam soil
- 50 days in sandy loam soil in a greenhouse (Worthing, 1983).
• Research by Golab et al. (1979) showed that trifluralin can undergo dealkylation and
cyclazation reactions to form 28 different breakdown products.
HEALTH EFFECTS
Carcinogenic! ty:
• EPA has classified trifluralin as a possible human carcinogen (group C) on the basis that
there is only limited evidence from animal experiments that it causes cancer (U.S. EPA,
1987a,b).
• In a feeding experiment with rats, trifluralin caused kidney tumors, but only at very high
doses (6500 ppm) and at a rate only slightly greater than that seen in control animals
(Tatken and Lewis, 1983; U.S. EPA, 1987a).
• Studies with mice and hamsters showed that technical-grade trifluralin caused liver and
lung tumors. However, it was not certain whether these were caused by the trifluralin
alone or by the nitrosamine contaminant (84-88 ppm dipropylnitrosamine) (47 FR
33777; Gosselin et al., 1984; U.S. EPA, 1987a).
C-259
-------
Similar chemicals (e.g., ethalfluralin) have been demonstrated to cause tumors in rats
(U.S. EPA, 1987a).
Mutagenic Activity:
Trifluralin is not considered to be mutagenic. The dominant lethal test with mice was
negative as were tests with yeast cells and sister chromatid (chromosome) exchange in
hamster cells (U.S. EPA, 1987a).
Reproductive Effects:
Trifluralin has not been shown to impair the reproductive ability of rats, rabbits, or dogs
(U.S. EPA, 1987a, b). The only adverse effect demonstrated was reduced birth weights
in rats exposed to high doses (IRIS, 1989).
Other Toxicologicai Effects:
Trifluralin is not acutely toxic to humans but may cause eye or skin irritation in exposed
humans (Dreisbach, 1980; U.S. EPA, 1987a).
Long-term, low-dose (chronic) exposure to trifluralin caused kidney damage in rats (at
200 ppm) (U.S. EPA, 1987a).
Toxicologicai Effects Indices;
Reference Dose (RfD): 7.5xlO"3 mg/kg/day (IRIS, 1989).
Cancer Potency Factor (CPF): 7.7xlO"3 (mg/kg/day)"1 (IRIS, 1989).
Oral LDso: mice, 500 mg/kg; rats, 10,000 mg/kg; dogs, chickens, rabbits, 2 mg/kg (U.S.
EPA, 1987b).
C-260
-------
PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H @ 25°C (atm • m3/mol):
Log (Octanol-Water Partition
Coefficient), log KOW:
Soil Adsorption Coefficient, KOC (mL/g):
Fish Bioconcentration Factor, BCF:
335.3
yellow-orange
crystalline solid
48.5-49
139-140 @
4.2 mm Hg
N/A
0.3
4.0 @ 27°C
1.1x10-4 (25°C)
l^xlO^calc.)
5.34
1.37xl04
1800-6000
Worthing, 1983
Worthing, 1983;
U.S. EPA, 1987b
Worthing, 1983
Windholz, 1983
N/A
U.S. EPA, 1987b;
Herbicide Handbook, 1983
Worthing, 1983;
Verschueren, 1983
U.S. EPA, 1987a
Lymanetal., 1982
Leo,1983
PHRED, 1988
Worthing, 1983
C-261
-------
REFERENCES
Bionomics EG+G. 1973. Exposure of Fish to l4C-trifluralin: Accumulation, Distribution, and
Elimination of 14C Residues. Submitted to U.S. Environmental Protection Agency by Elanco
Products Co.
Dreisbach, R.H. 1980. Handbook of Poisoning: Prevention, Diagnosis and Treatment. Lange
Medical Publications, Los Altos, CA.
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Golab, T., W.A. Althaus, and H.L. Woolen. 1979. Fate of 14C) Trifluralin in Soil, J. Agric. Food
Chem. 27:163.
Gosselin, R.E., R.P. Smith, H.C. Hodge, and J.E. Braddock. 1984. Clinical Toxicology of
Commercial Products. 5th ed. The Williams and Wilkins Co., Baltimore.
Gray, I.E., A. Loh, R.F. Sieck. et al. 1982. Laboratory Leaching of Ethalfluralin. Eli Lilly Co.
Green, M.B., G.S. Hartley, and T.F. West. 1987. Chemicals for Crop Improvement and Pest
Management. 3rd ed. Pergamon Press. Oxford, England.
Helling, C.S. 1976. Dinitroaniline Herbicides in Soils. J. Environ. Qual. 5(1): 1-15.
Helling and Turner. 1968. Pesticide Mobility: Determination by Soil Thin-Layer Chromatog-
raphy. Sci. 162:562-563.
Herbicide Handbook. 1983 Weed Science Society of America. 5th ed. Champaign, IL.
IRIS. 1989. Integrated Risk Information System. U.S. Environmental Protection Agency,
Washington, DC.
Leo, A.J. 1983. Log P Parameter Database, Issue #24 (dated 12/16/83). Obtained from the
Medchem Project, Pomona College, Claremont, CA.
Lyman, W.J., W.F. Reehl, and D.H. Rosenblatt, eds. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill, New York.
McEwen, F.L., and G.R. Stephenson. 1979. The Use and Significance of Pesticides in the
Environment. John Wiley and Sons, New York.
Mosier, J., and D. Saunders. 1978. A Hydrolysis Study on the Herbicide Trifluralin. Eli Lilly Co.
Submitted to U.S. Environmental Protection Agency, Washington, DC.
C-262
-------
Parr, J.F., and S. Smith. 1973. Degradation of Trifluralin Under Laboratory Conditions and Soil
Anaerobiosis. SoilSci. 115(l):55-63.
PHRED. 1988. Public Health Risk Evaluation Database. U.S. Environmental Protection Agency,
Office of Emergency and Remedial Response, Washington, DC.
SRI (Stanford Research Institute). 1986. Directory of Chemical Producers. Stanford Research
Institute, Menlo Park, CA.
Tatken, R.L., and R.J. Lewis, Sr., eds. 1983. Registry of Toxic Effects of Chemicals Substances
(RTECS). 1981-82ed.
Thomson, W.T. 1985. Agricultural Chemicals Book II - Herbicide. 1981-82 ed.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library of
Medicine's MEDLARS system, National Library of Medicine. TDB Peer Review Committee.
U.S. EPA. 1987a. Guidance for the Reregistration of Pesticide Products Containing Trifluralin as
the Active Ingredient. U.S. Environmental Protection Agency, Office of Pesticides and Toxic
Substances, Washington, DC. EPA 540 RS-87 195.
U.S. EPA. 1987b. Draft Trifluralin Health Advisory. U.S. Environmental Protection Agency,
Office of Drinking Water, Washington, DC.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologi-
cals. 10th ed. Merck & Co., Rah way, NJ.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British Crop
Protection Council, Croydon, England.
C-263
-------
APPENDIX D
Data Tables
-------
APPENDIX D-l
*
Site Description Matrix
Also included in Volume I, Appendix B-3
-------
Key to Table D-l
Matrix of Episodes and Site Descriptions
Descriptions of the column headings for Table D-l are as follows:
COLUMN HEADING DESCRIPTION
1.
2.
3.
4.
5.
6.
7.
8.
EPA REGION
EPISODE
LATITUDE
LONGITUDE
STATE
WATERBODY
LOCATION
NSQ
The U.S. Environmental Protection Agency Region which includes the
sample location.
The EPA Episode Number which is specific to each sampling event.
The latitude of the sample site in degrees, minutes and seconds.
The longitude of the sample site in degrees, minutes and seconds.
The state closest to the sample location.
Name of the water where the sample was collected.
The nearest town, road or county to the sample location.
Sample site selected using a statistical procedure to represent a subset of
the sites in the USGS NASQAN network.
9. B Background site as selected for study.
POINT SOURCES: Point sources include the following six categories:
10. PPC Site near paper and pulp mill using chlorine for process), (includes mills
using the sulfite process).
11. PPNC Site near paper and pulp mill not using chlorine for bleaching as well as
deinking plants.
12. REFINERY Site near refinery using the catalytic reforming process.
13. NPL SITE Site near an EPA National Priority List Site (Superfund site).
14. OTHER INDUSTRY Site near industrial discharge other than a paper mill or refinery.
15. POTW Site near discharge of a Publicly Owned Treatment Works (municipal
sewage).
16. WP Site near active or former wood pereserving activity.
NONPOINT: Nonpoint sources include the following two categories:
16. URBAN Site receives urban runoff.
17. AGRICULTURE Site receives agricultural runoff.
18. SITE DESCRIPTION A brief sentence or list of additionalinformation concerning the site.
D-M
-------
D-l-2
-------
TABLE P-1
Matrix of Episodes and Site Descriptions
WA
•a
1
11
II
II
!(
II
II
11
II
II
II
II
II
II
II
II
II
r>Ur t,
»
2376
2375
2369
3151
3150
2356
2721
2725
3026
3028
2358
3022
2355
2722
3027
3023
3024
3025
3152
3426
3429
3430
2651
3427
2653
342K
3433
34 U
2654
3304
32%
3298
3301
2326
3309
*
i*t**tt tintfm
4I:22:OON 072:5i40W
4I:36:47N 07I:58:26W
42:37:25N 071:23:IOW
42:35:22N 072:21 :08W
42:35:46N 07Z:03:27W
44:06:ION 070:13.58W
44:15:20N OTftlftSOW
44:30r09N 070:15«IW
44:10:20N 07tt20:25W
45:04:48N 057:19:25W
44:36:30N 067:55:30W
44:32:30N 07f>07:l5W
44:49:20N 068:42:30W
43:34:35N 07tt33:45W
43:34:25N 070:33:5SW
44:54:30N 069:55:05W
44:54.i»N 069:1 5: 15W
44;49:40N 069:24:OOW
44:24:42N 071:11:29W
4ft35:45N 074:12:20W
39.34:30N 075:M:OOW
39:18flON 074.37:30W
39:36flON 074:35K)OW
4ft39:15N 074:09: 16W
40:54:30N 074:12:OOW
40:43:15N 074i)7:l5W
40:2*:24N 0740J40W
40:27:OON 074:03:OOW
39:57:30N 074.12:30W
43:59:30N OT6.O4:30W
42:5 MSN 078:52:OOW
42.52.-OON 078:52:3OW
43:20:20N 0784300W
42:13flON 078«l:fluW
42:13:30N 078:r
rrr rrrtc wr «r«» SHt l*t rorw
XXX
XXX
XXX
X
X
X XX
X
X
XX X
X X
X
X
X X
X X
X
X
XXX
X
X X
X XXX
X
X X X X
X XX
XXX
X XX
X
X
X
X
X
NONKMKT
llrt» A(T|
X
X
X
X
X
X
X X
X
X
X
X
X
X
X
X
X
X
,>lmi »nlSH,DnfrtfM.«
(FidNUtt tt OM rktatiy rf NH Ifmft^t Mk)
Industry: chemical & pesticides; electronics; plastics; metab; Supcrfund
site (sohenti)
Ind : organk chem. it pea., textiles; Superfund site (Furans)
Ind.: chem. & pest., industrial WWTP; PAP mill on Nashua R. (Irib.);
Superfund site (solvents)
Erving Paper Mills; wooded arei; Ag.: croplands and grazing fields
Erving Paper Mills; wooded area; Ag.: croplands and grazing field*
International Paper, Boise Cascade, James River; Ind : textiles
International Paper Co. in Jay
Boise Cascade in Rumford; rural;wooded area
Ind.: textiles; downstream of paper mills
Two Mueberiy processing plants; blueberry fields (pesticides)
No industry, wooded and swampy area
Janes River Corporation on Old Town
Same as 3027; POTW oo upstream Irib. yet is Background site
Same as 2722; POTW oo upstream Irib. yet it Background ske
Industrial WWTP
Industrial WWTP
James River Corporation
GAP Corp. (chem. manufacturing)
Superfund site (several iitei; metals, &. org. chemicals)
Background even though has agricultural area and POTW nearby
Wooded area
Landfill
Marcal Paper and PAP mill on trib ; Ind.: metals, chem. & pest.;
Superfund tile (totventj)
80 Lister Ave.: chem. manufacturing
P&P mill effluent into bay, Exxon Co.; Ind.: chem.; Superfund site (sever.
sites; metals St. org. chem.)
Exxon Co.
Ind.: chemical; Superfund site (chlorabciizcne; Hg)
Five paper mills (PPNC); Air Brake Co.; hydro-power; dairy fields
Ind.: chemical, steel, petrochemical; landfills
Allied Chemical (mawafactver of HCB); landfills
Ind.: Harrison Radiator; cheat. ( HCB); Ag.: orchards awl ciopUadi
Same as 3309. Sampled below Belmool Dam. Superfund site ii
approximately 10 miles, upstream (heavy metals, hydrocarbons)
Same as 2326
D-l-3
-------
TABLE D-l (Cunt.)
KT
*t
II
II
II
II
II
11
J]
II
II
II
II
II
II
[[
11
II
II
II
II
II
II
II
II
1!
II
II
II
II
II
II
II
II
III
II
II
III
II
K,t~*
*
3306
3319
3320
2709
3259
3409
3321
3322
3260
2328
2329
3323
3324
3325
3326
3300
3297
3299
3302
3303
3412
3305
2322
3308
3411
3307
3327
3432
3431
2210
3147
3099
3096
3097
3149
3100
3317
(.MM* LM«tt«*
44;S7:30N 074:49flOW
40:40:OON 073:20:OOW
40:40:45N 073:I9.00W
41:16:30N 073:57:OOW
43.08.00N 073:36:30W
41:20flON 073:57:30W
40:38:40N 073:50:40W
40:37:4SN 073:47K»W
43.51 :30N 073.22:OOW
43.20:25N 078:43: 14W
43.14O5N 077:32.O3W
40,4S;OON 073.-45.-OOW
40.-47.flON 073.45.-OOW
40:49:OON 073:40flOW
40:50: ION 073:40. 1 5W
43:I5:30N 079:03:45W
43:03flON 078:58:55W
43O2OON 078:53:45W
43:IO:30N 079:03: 10W
44:I2:30N 075:00:OOW
4328KXJN 076:31 flOW
44.58:30N 074:44:OOW
44:S9:OON 07321:00*
45.flO.flON 073:2lflOW
43:11 1»N 0773L30W
44:42:30N 075:28:30W
40:38:20N 074.02: 15W
7:59:40N 066:46:25W
8:26:40N 066:0IY St. Lawrence River Ogdensburg
NY Upper Bay New York
>R Guayanilla Bay
PR Saa Juan Harbor San Juan
DC E. PatomfC River DC
DC Potomic River Park N. of Wilson Br
DE Indian River Rotedale Beach
DE Red Clay Creek Ashland
DE Red Lion Creek Tybouls Corner
DE While Clay Creek Thompson
MD Baltimore Harbor Baltimore
MO Potomac R.N. Br. Westernport
NMJ •
X
X
X
X
roiCT SOURCES
NPL Other
rrc rrNc wr *i*, sib i«4 POTW
X
X
X
XXX
X X
XXX
X X
X X
X
X
X
X X
X X
X X
X X
X X
X X
X X
X X
X
X
X XX
X
X
X
X
X X
X X
X XX
X X
X X
X X
X
X
X X
X X
NOMPOINT
llrWn Apt
X
X
X
X
X
X
X X
X X
X X
X X
X X
X
X
X X
X
X X
X X
X
X
X
*i«llliH«l SH. DCTtriyU..
(fatMMto !• U». rtiMIl «tlh« tmmf Hnjilfc)
Sampled below ALCOA'S outfall (PCB concern); GM A Reynolds (2
miles below mouth of river)
Same as 3320
Same as 3319
Same as 3409; Ind.: chem.; PAF mill ISO river miles upstream; Superfund
site (PCB)
Fort MiHer Pulp and Paper (Finch, Pyruyn & Co.)
Sane as 2709; Ind.: chem.; P&P mill ISO river miles upstream; Superfund
site (PCB)
Ind.: chem.; airport; landfill
Ind.: chem.; airport; landfill
International Paper Co.
Ag.: apple orchards and croplands
Ind.: chem (Kodak); Site at the mouth of Cenesee River
Same as 3324
Same as 3323
Same as 3326
Same as 3325
Ind.: cbem.; Olin, Dupont, Ondenlal (HCB); Ag.. orchards; landfill
Ind.: chem.; Olin, Dupont. Ondenlal Cbem. (HCB), (companies
downstream of ike)
Ind.: chemkal
Ind.: chem.; Olin, Duponl, Ondenlal (HCB); Ag.: orchards
Newlon Falls Paper Mill (defunct since October 1V84)
Ind.: Chemical
Potsdam Paper and Norfolk Paper (PPNC); ALCOA, GM, Reynold)
(upstream of mouth)
Ind.: chemical
Ponderosa Fibers (out of business more than 4 years); Dow chemical in
Canada
Sampled at 69th Slreel Pier
Caribbean Gulf Refining Corp.; landfill
Estuary
Ind.: metal plating, mining; illegal dump (landfifl); Ag.: mushroom farming
Chemical spill (HCB concern); Superfund site (HCB)
Westvaco (indirect); rural
D-l-4
-------
TABLE D-I (Com.)
er
•l
III
III
III
111
HI
III
Ml
HI
HI
IN
III
III
III
III
III
III
in
in
Ml
MI
III
11)
111
HI
lit
Ml
IM
III
111
III
lit
III
III
III
III
IV
IV
ETM,
0
2231
3103
3316
3161
3420
3094
3095
3096
3318
3419
3310
3101
2215
2212
3104
3415
2211
3414
3315
2216
3422
3421
2225
2228
2227
2220
3423
3424
319*
3258
2500
3314
3311
3312
3313
2304
2309
LMN»4t U«t*M>
3*39;31N OT6:10:28W
39-.3&OON 076:IOOOW
41:25:20N 078:44:10W
3ft56:30N 075:I4:35W
39:53:42N 076:4fc09W
40:02:24N 074:59:20W
39:53:OON 075:11:46W
39:51:36N 075:18:40W
4ft23:20N 078:24:20W
42:09:25N 0«h02:57W
40:39:40N 075:14:35W
40:03:40N (r75:28:23W
40-.n-.30N 079:52;33W
3*58:OON 075:1 1:20W
39:58:22N 075:11:33W
41:23:30N 075:4«.-OOW
40:03.«ON 076:30KMW
41:18:50N 075:48:45W
40:21 :OON 076:23flOW
41:33:22N fT77:41:28W
36:33: ION 076:54:57W
37:47:1 5N 08ftOO:06W
37:35:OON 079:25:OOW
37:40:15N 078:05:10W
36:46:13N 077:09:59W
37:46.-03N 077:19:57W
37:31 :55N 076:48:40W
37:32:01 N 076:50:38W
37.01 .4SN 078:55:40W
36:49:48N 076:17:30W
38:27:OON 081:49K»W
38:31 :30N 081:54:37W
3%4040N 080:51:52W
4049: ION 080-.4125W
39:31: ION 077:52:30W
31:32:48N 089:30:45W
32:24:4IN 086:24:30W
State WitotMr L»«to«
MD Susquehanna River Conowingo
MD Susquebanaa River Conowingo
PA CUrion River Ridgeway
PA Cobbt Creek Philadelphia
PA Codorus Creek Spring Grove
PA Delaware River Torresdale
PA Delaware River Schuytkill Jnct.
PA Delaware River Eddystooc
PA Frinkslown Branch Kladder Station
PA Lake Erie Erie
PA Lehigh River Eastern
PA Little Valley Creek Paoli
PA Monongabela River Ctatrton
PA Scbuylkill River Philadelphia
PA Schuylkill River Philadelphia
PA Susquehanna N.Br. Ransom
PA Susquehanna River Columbia
PA Susquehanna River Prttstoa
PA Union Canal Lebanon
PA Young Womens Cr. Renovo
VA Blackwater River Riverdale
VA Jackson River Covington
VA James River Glasgow
VA James River Canersville
VA NoUoway River Sebrell
VA Pamunkey River Hanover
VA Pamunkey River Weal Point
VA Pamunkey River West Point
VA Roanoke River Biookneal
VA S.Br Elizabeth R. Norfolk
WV Kanawfaa River Nilro
WV Kanawfaa River WmHeld
WV Ohio River Nw. Martiruvie
WV Ohio River Wheeling
WV Opequon Creek Bedington
AL Alabama River ClaJborue
AL Alabama River Montgomery
NSQ •
X
X
X
X
X
X
rOINT SOURCES
NFL Other
rrc rrNc wp ttaj su* imi rorw
X X
X X
X
X X
X
X X
X XX
X XX
X
X XX
X X
X
X X
X X X X
X XXX
X
X XX
X
X
X
X
X X
XX X
X X
X X
X
X
X
X X
X X
X X
X XX
X
X X
X X
NONPOINT
llrWa Afri
X
X
X
X X
X
X
X
X
X
X
X
X
X
X
X X
X X
X
X
X X
X X
AdfllliMl Site OxiilpH..
-------
TABLE Dl (Conl.)
ET
•l
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
E*M*
t
3360
3170
2302
3172
3328
3171
3169
3168
3331
3332
2151
3329
3334
3174
2148
3333
2142
3173
21S2
3330
3337
3177
3375
3376
3377
3378
3178
3179
2294
3176
3336
2290
3175
3338
3180
3335
In Mil ll ln«MHi
32.-07-.55N 085fl3:43W
31:29?40N 085:22:06W
31«4fllN OB7fl2:40W
3I:25:07N OM:2645W
33:17:24N 096:2 1:42W
3HJ1.02N OSJ.-13.24W
33:50:1SN 086:31:46W
3ft52:30N 087:S7:48W
30:M»:OON 087:20: ISW
30-.3&52N Ofll:29:28W
M23KHN 085i33:24W
VMIOOH 083:46:OOW
2*50:31N 085:17:59W
27:12:18N OHM7:28W
27:38:54N 080:24: 10 W
30tf7:38N 085:39:25W
2%38:48N 081:37:32W
30ttM)ON 081:40*WW
3ft21:30N 082.«4:34W
30:2&OON 083:15K»W
31:39: ION 081:49*»W
34:26.OON 083:4ft30W
33:39:24N 084:40;25W
33:2&37N 084:54, M rorw
X
X
X
X
X X
X
X
X
X X
X
X X
X X
X
X
X
X
X X
X X
X
X
X X
X
X
X X
X
X X
X XXX
X XX
X
NONPtHNT
UrW. Acri
X
X
X
X X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
AMMlMd MM DMcripttM
(r«dMt» !• OK ricWIr W lk« •••**•« •**)
Alabama Kraft in AL (goes into GA water but on AL side)
Container Corporation
Kimberly Clark; wooded area; Ag.: croplands and grazing fields
Several chem. & pest, plants; Hydro-power
Champion International Corp. in Cantonment; rural; swampland; Ag.:
croplands
ITT Rayonier, Inc.
Buckeye Cellulose; rural; swampland; Ag.: grazing fields
St. Joe Paper (indirect)
Collected below salinity structure
Southwest Forest Ind., Inc. (indirect) (Stone Container Corp.)
Georgia Pacific Corporation
Wood treatment plant
ITT Rayonier, Inc.: swampland; Ag.: croplands
Town of Schoville: heavy melak, wood products; Ag.: chicken farms and
orchards
Box Board on Hwy 92
Great Southern Pacific Paper Company
Mining: gold, sand, and gravel; Ag.: orchards, dairy farms & chicken
houses
Procter & Gamble (Buckeye Cellulose)
Great Southern Pacific Paper Company
Oilman Paper Company
Federal Paperboard' in Pond, Georgia Pacific; lad.: pest.
Port Howard Paper (PPC), Union Camp and Stone Container Corp.
(PPNC); Nuclear power
Ponderosa Fibers (indirect)
Brunswick Paper & Pulp on the Turtle R.; marshland; wooded area; Ag.:
grazing fields
D-l-6
-------
TABLED-1 (Conl.)
EM
•t
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
h>fc~k
t
3183
3339
3182
2056
2341
3181
3446
3185
2126
3445
3341
3340
3435
2133
3184
3344
2139
3165
3345
3164
3342
3167
3166
2138
3395
3343
3346
3385
3347
3186
3348
3187
3349
2301
3189
2298
3350
2297
L.IU.4C L.mM»
-------
TABLE D-l (ConL)
KP/V
«t
IV
rv
IV
IV
IV
rv
rv
V
v
V
y
y
V
Y
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
KpbWc
f
3403
3444
3188
3404
3351
3190
3401
2379
2383
3113
2380
3114
3115
3117
2059
3356
2060
2057
3119
3118
1994
3120
3122
1998
3148
2432
2410
2431
2430
2435
2387
2437
3112
3125
2385
3001
2416
2394
2439
L»Htu6t iM^ttuOt
36:33:02N 082:35:OOW
35:05:15N 090:05.30W
35:03:54N 085:20:28W
36.01 :20N 083:1 2.00W
35:56:24N 083:10:52W
35:S0:15N 084:04:13W
35:03.54N 086:I6:39W
37:37.3 IN 089:25.42W
41:35:47N 088O4O7W
41:52:13N 088:1 8.3IW
4U9-40N 088:45: 10W
39:43:OON 091:31O»W
38:32:30N 090:15:OOW
42:21 :10N 087:49:40W
41:37:ION 087:29:15W
41:37:ION 087:29:15W
38:07:50N 087:56:20W
38:3ft45N 087:17:30W
42:33:OON 085:54:OOW
45:5ftOON 087:05:OOW
43:03:OON 083:48:45W
42:39:OON 082:10:OOW
45:47:OON 087:59:OOW
43:15:05N 086:14:55W
43:15:05N 086:14:5SW
43:19:57N 086O8:42W
42:16:45N 083.O7:20W
46:29:45N 084:22:25W
46:34:30N 085:I5:IOW
47:55:23N 089O8:42W
44:16:08N 093:21:OSW
44:4I:33N 093:38.35W
45:58:17N 094:22K)5W
44:33:34N 092:2S:47W
48:36:29N 093:24:13W
48:35:29N 092:53:34W
41:29:50N 081:42:10W
39:33:44N 084:I8:I9W
39:15:53N 084:40:30W
StMt WatertMdj lacMm
TN Holslon R , S. Fork Kingspon
TN Mississippi River Nonconnah Cr
TN Nickajack Reservoir
TN Pigeon River Newport
TN Pigeon River Newport
TN Tennessee River Knoxville
TN Tennessee River Hardin Co.
IL Big Muddy River Grand Tower
IL DCS Plaines River Loclcpon
IL Fox River Geneva
IL Illinois River Marseilles
IL Mississippi River Quincy
IL Monsamo Effluent East St. Louis
IL Lake Michigan Waukegan
IN Indiana Harbor Can. East Chicago
IN Indiana Harbor Can. East Chicago
IN Wabash River New Harmony
IN While River Petersburg
Ml Allegan Lake Allegan
MI Escanaba River Escanaba
Ml Flint River Rushing
MI Kalamazoo River Saugatuck
Ml Menominee River Quinnesec
MI Muskegon Lake Muskegon
Ml Muskegon Lake Muskegon
Ml Muskegon River Bridgton
MI Rouge River River Rouge
Ml St Marys River Sault Si Marie
MI Tabquamenon R. Paradise
Ml Washington Creek Isle RoyaJe
MN Cannon Lake Fairbaull
MN Minnesota River Jordan
MN Mississippi River Little Falls
MN Mississippi River Red Wing
MN Rainy River lntem'1 Falls
MN Rainy River lntem'1 Falls
OH Cuyahoga River Cleveland
OH Great Miami River Franklin
OH Great Miami River Nw. Baltimore
NSQ B
X
X
X
X
X
X
X
X
POINT SOURCES NOWOINT 1
NPI, OdMr AddlUond Sir Unrrtpdon
PTC PPNC WP Rrny Sfe lad POTW , Urban Ajrl (FHdMIn to UK Hdnity of UK awiptiit *tt>
X
X XX
X X
X
X
X
X
X
X XX
X X
X XX
X X
X X
X X
X XXX
X XXX
X X
X X
X X
X
X X
X
X
X XXX
X XXX
;
Mead Corporation (Chlorine Dioxide process )
X Mapco. Exxon, Union refineries; content factory, soybean processing
X
X
X
X
X
X
X X
X X
X
X
X
X
X
X X
X
X
X
X
XXX
X XX
X X
X X
X
X X X X X
X XX
X
XXX
X XX
X X XXX
Ind, chem.; coke, rendering; railyards; landfill
Champion International in North Carolina
Champion International in North Carolina
Tennesee River Pulp and Paper in Counce. TN
Ind., organic chem. & pcsi , Refineries (downstream); sleet; incinerator
Ind; chem. & pcsi.. Union oil. Texaco. Mobil; Ammunition piani
Celotex Corporation (deinking)
Six chemicat/phamttceuticaJ plants (paradichlorobenzene)
Open lake sample; Superfund site (PCS) at Waukegan Harbor
Same as 3356; Amoco Oil: Ind.: primarily steel: wastewaler; Superfund site
(PCB)
Same as 2059; Amoco Oil; Ind.: primarily steel; wastewaler; SuperfunJ site
(PCB)
Ind.: chem. & pest.; coal mining; (site at the inouth of the Wabash R.)
Hydro-power, coal mining
Historical PCB contaminaion from paper linking; Superfund site (PCB)
Mead Corporation (historical PCB contamination)
Automobile manufacturing (heavy metals and oils)
Historical PCB contamination sue is downstream of Kalamazoo
Champion International Corporation
Scott Paper (indirect); Power* chem plant; Ag.: orch.; same as 3148.
Superfund site (PCB)
Scott Paper (indirect); Power & chem plant; Ag.: orch.; same as 1998;
Superfund site (PCB)
Far upstream of bleachkratl (Scon Paper Company)
bid.: heavy steel; chem.; automobile (PCB's in elllucm)
St Mary's Paper; Algoma Steel; dreugmg
Canadian Bleach Kraft P&f mill about 30 miles upwind in Thunder Bay,
Onl.
Hennepin Paper
Ashland Oil/Koch Refining, urban runolf. historical PCB contamination
Boise Cascade on both sides of the river
Sue is above the dam. Boise Cascade outfall is below dam.
Ind : chem.; oil.
Applelon Papers and Miami Papers (deinking). Ind : metals and others
Sorg P&P mill (deinking); Proctor ami Gamble. Ag. runoff; Superfund silt:
D-l-8
-------
TABLED I (Conl.)
EP
Re|
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
ErtT*r
»
2618
3132
3135
3136
3137
2429
3138
3140
3143
3144
2422
3134
3141
2427
3142
3110
2397
2608
3106
3107
3108
3109
3145
3146
2023
3060
3062
3061
3078
3443
2015
2018
3073
2016
3452
3077
2017
3088
3083
UUh* Lwwtt.*
39:24:40N 064:33: 14 W
39:1 7: 36N 082:55:48 W
44:49:39N 091:30:38W
45.-24.-05N 091:13:18W
45:55:OON 090:26:4IW
44:27:39N 088.O3:30W
44:I6:10N 088:22. 18 W
44:13:24N 088:27:34W
44:00:43N 088:31K»W
43:3il7N 089:27:36W
46:36:21N 090:52:30W
44fll:58N 088KM:45W
43:03:26N 087:S3:54W
45:03: 16N 087.44:50W
43:43:51N 087:47.-04W
44:58:OON 092:46flOW
45:37:27N 089:25: 14 W
44.-16.-OON 089-J3.-OOW
44:16:OON 089:53:OOW
4S:01:20N 089:39:09W
45:10:31N OB9:40:OOW
44:56:57N 089:37:4SW
45:26: 17N 089:43:S6W
44:5157N 089:38. 17W
35:20:56N 094:17:54W
34:26:41N 09i06:38W
34:UM»N 091:43:S6W
33: 10. 18N 092:39:OOW
34.50.39N 092.07:20W
34«M»N 091:31K»W
33:33:27N 091:14:15W
35:59:43N 092;12:45W
35:S6:33N 092,-fl7:05W
33-33KT7N 094:02:28W
33.34 1 5N 09406.00W
33:57: 17N 094:21.49W
33.14:32N 093.59-.58W
30.53.00N 093:25:OOW
32:40tt)N 091:43:OOW
SUk W*l«rW4y UolU*
OH Hamiltoo Canal Hamilton
OH Scido River ChilUcothc
WI Chippewa Rivet Eau Claire
WI Flambeau River E. Ladysmitfa
WI Flambeau River Park Falls
WI Fox River DePere Dam
WI Fox River Applelon
WI Fox River Lk BulteD.Morts
WI Fox River Oshkosh
WI Fox River, upper Portage
WI Lake Superior Ashland
WI Manilowoc River Chillon
WI Milwaukee River Milwaukee
WI Pesbligo R. Harbor Peshligo
WI Sheboygan River Kohler
WI Si Croix River Hudson
WI Wise. R/Boom Lake Rhioelaoder
WI Wisconsin River U. Pentenwell Fl
WI Wisconsin River U. Penlenwell Fl
WI Wisconsin River Brokaw
WI Wisconsin River Merrill
WI Wisconsin River Wausau
WI Wisconsin River Mohawskin
WI Wisconsin River Rothschild
AR Arkansas River Van Buren
AR Arkansas River Little Rock
AR Arkansas River Pine Bluff
AR Bayou DeLouIre El Dorado
AR Bayou Melo Jacksonville
AR Bayou Melo Reydell
AR Mississippi River Arkansas City
AR NSyUmore Creek Fifty Six
AR N.Syuuaore Creek Fifty Six
AR Red River Index
AR Red River Index
AR Rolling Pork River De Queen
AR Sulphur River Texarkana
LA Anacoco Bayou Deridder
LA Bayou Bonne Idee Oak Ridge
NSQ B
X
X
X
X
X
X
X
rOI NT SOURCES
NPL Other
PrC PPNC WP Rlhy Site Ind POTW
X X
X XX
X
X
X X
X XX
X X
X
X
X X
X
X X
X X
X X
X X
X XX
X XX
X
X
X
X
X
X X
X X
X X
X X
X
X X
X
X X
X X
X
X
NONPOINT
UrWn Atri
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
AddllbMl Silt Oncripll*>
(FacUUfc* In lb< rtelallj •( UK umpMn( >Ur)
Canal off G. Miami R.; Appleloo Paper; Aviation plant; steel;
hydro-power; Superfund site
Mead Corporation on Painl Creek; Ind : inorg chem. & pest.; Superfund
site
Pope and TaltxX (deinking)
Pope tad Talbot (deiakiag)
Flambeau Paper, Ag.: croplands and grazing fields
Fort Howard, James River, Green Bay Pkg., Nicolel Paper, Champion
Kerwin Paper Company (deinking), Gladlfeldcr, WI Tissue, Kimberly Clark
Gladlfelder, WI Tissue Mills, Kerwin Paper (historical PCB contamination)
Ponderosa (deinking)
Historical PCB contamination
James River-Dixie Northern (deinking); rural
Incinerator; H2O softener plant; Ag.: croplands
Ind.: metals (historical PCB contamination); 300-400 Industrial discharges
Badger Paper Mills, (indirect)
Superfund site (historical PCB contamination)
Anderson Windows; wood treatment plant
Upstream of paper mills
Nekoosa, Fort Edwards, Consolidated Kraft; Vulcan mat. (rubber &
plastic); same as 3106
Nekoosa, Fort Edwards, Consolidated Kraft; Vulcan mat. (rubber &
plastic), same as 2608
Wausau Paper (suttite mill)
Ward Paper (deinking)
Wood treatment plant site is between paper mills.
Rhinelander Paper Company
Weyerhaeuser, half dozen small mills; Ag.: croplands
International Paper Company, wooded area; Ag.: croplands
Lion Oil Company
Superfund sile (dioxins); rural; wooded area
Downstream about 30 miles of the Jacksonville sile (3078)
Potlalch Corporation; Ag.: croplands
Same as 3073
Same as 2018
Nekoosa Edwards Paper Company
Nekoosa Paper; lime and gravel mines; Ag.: crop and grazing lands
Wood treatment plant on Bear Creek
International Paper Company in Texas
BoUe Southern Co. (Boise Cascade); rural; Ag.: cropland
HCB use in agriculture
D-l-9
-------
TABLE Dl (Conl.)
jTf j
***
VI
VI
VI
VI
VI
V!
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
Vll
VII
VII
VJI
n-_i__ _a-
*
3086
3442
3353
3063
3092
3352
3064
3082
2532
3065
3066
3418
3416
3080
2544
3087
3425
3074
3105
3090
3079
2027
3076
3091
2026
3089
3084
3085
3068
3069
3081
2280
3075
3093
3070
3072
3071
2283
3035
3037
3038
3034
LMM. l.i^l.W
34:14:03N 096:58:32W
35:41«ON 095:14:OOW
26:11:42N 097:36:06W
28J8:59N 0»5:23:41W
29:4ft48N OW:58:50W
27:5I:30N 097:30:20W
3J:25:58N 05M:33:56W
28:57:35N 0%:41:13W
28.O9:OON 096:52:OOW
3108.-OON 094:48:39W
29.59-.30N 093:54:OOW
31:05.-OON J05:36:OOW
29:14-15N 098:21:43W
30:55:25N 098:02:I2W
42,-03:54N 091:47:48W
41:40:57N 093:40:08W
41:33:02N 093:31:29W
41:34:53N 09ft23.23W
State Wilirtifr U.c.llt.
LA BiyouD'Iode Sulfur
LA Bayou Labvchc Norco
LA Bayou LaFourche Bastrop
LA Cikasieu River Mo*s Lake
LA Dugdemoaa River Hodge
LA Lake Irwio Start
LA Lake Pontchartrian New Orleans
LA Lake Providence
LA Mississippi River, Si. f-rancisvillc
LA Mississippi River Baton Rouge
LA Mississippi River Union
LA Mississippi River Zachary
LA OuachiU River SlcrHngtoo
LA Ouachha River Monroe
LA Tangipaboe Rtvci Robert
LA Wkam Brake Swartz
LA Wham Brake Swartz
NM Rio Mora Terrero
OK Fon Cobb Reservoir Port Cobb
OK Fon GitKoa Res. Pyrer Creek
OK Kaw Reservoir
OK Kiamkki River Big Cedar
OK Little River Goodwater
OK Red River
OK Washita River Durwuod
OK Webbers Falb Muikogee
TX Arroyo Colorado Harlingen
TX Brazos River Precport
TX Houston Ship Chnl Morgan Point
TX Inner Harbor Corpus Cbristi
TX Lake Sam Rayburn Luflun
TX Lavica River Edna
TX Mesquite Bay
TX Neches River DiboU
TX Necbe* River (tidal) Port Arthur
TX Rio Grande River El Paso
TX San Antonio River Elmendorf
TX So. Fork Rocky Cr. Briggs
IA Cedar River Palo
A DCS Moines River DCS Moines
A DCS Moines River DCS Moinci
A Mississippi River Le Cbirc
NSQ (
X
X
X
X
X
X
X
X
rolNTSOUECKS
NPL Other
rrc rrnc wr tumj so. 1*4 rorw
X
X X
X X
X XX
X
X X
X
X XX
X
X
X
X X
X
X
X
X
X
X
X
X X
X X
X
X XXX
X XX
X X
X X
X XX
X X
X XX
X
X X
X
NUNfOINT
llrt». Api
X
X
X
X
X
X
X
X
X
X X
X
X
X
X
X
X
X
X X
X X
X
X X
A4dMw^SM« DwcrtpttMi
(f «iH>U» !• It. rtclmni •! Ib. nu»ytot dte)
Citgo Petroleum Corporation; Ind.: chcm.
Shell and Norco Refineries; Shell chemical plan!
International Paper Company, rural
Conoco, Inc.; Ind.: cbcm.
Above Bayou LaFourche. This dammed water feeds Wham Brake.
HCB use in agriculture
Crown Zellcrbach
Georgia Pacific Corporation, Crown Zelterbach; Iwu refineries
Ind.: multiple sources; Ag.: cropland and grazing
Georgia Pacific and James Madison Paper; rural; wooded area
Georgia Pacific and International Paper; rural; wooded area
Georgia Pacific in Arkansas; Ag.: crop and grazing lands
Same as 3425; International Paper Co. (discharges to B. LaFourche)
Same as 3087; International Paper Co. (discharges to B. LaFourcne)
Ag.: croplands; golf course near the si(e
RobcU Tissue Mills
Vulcan Plan! in Wichita, Kansas (chemical processing plant)
Heavily wooded area; Ag.: cattle
Wood treatment: Thompson Lumber, Hoffman Preserver, Nixon Bros
Preserver'
Weyerhaeuser Company
Kerr McGee Refining Corporation, Tula) Petroleum, Inc.
Fort Howard Paper Company
HCB use
At Dow Chemical outfall
Champion International and Simpson Paper; four refineries; Ag.; croplands
Four refineries
Champion International Corporation on the Angelina River
Temple- Eailex, Inc. in DiboU and Borden Chemical (resin)
Temple- EaK ex. Inc. in Silsbee, TX; two refineries; Ind.: cnem. & pest.
Chevron USA, Inc., El Paso Refining Company
HoweU Hydrocarbons
Background site
About 50 miles downstream of Waterloo
Upstream about 10 miles from a POTW
Below POTW (pretreatmenl plant)
Upstream of loclc and dam al Davenporl (abuvc dam)
D-1'10
-------
TABLE D-l (Com.)
fe,
VII
VII
VII
VII
VII
VII
Vll
Vll
VII
Vll
Vll
Vll
Vll
Vll
Vll
VII
VII
VII
VII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
IX
IX
IX
IX
*
2191
2190
3036
2194
3039
2201
3040
3047
3048
3049
3045
2199
3044
3045
3050
3042
3043
3041
2205
3197
3198
3200
3236
3237
3235
3234
2122
210S
2100
3111
2109
3199
2110
3195
3196
2098
3266
3282
3288
3285
1 •IHafr L«^IIMl*
41:15.32N 095.5S:20W
4ft36:07N 09S:38:44W
40;36fl7N 095:38:44W
37:32:34N 097:16:29W
37:32c35N 097:16:29W
36:02:30N 09O07:30W
36.02:30N 090#7.30W
39:42:36N 091:21.O6W
38:52:33N 090; 10:26 W
37:17:46N 089-JQ-.56W
3*07:S2N 094:27:58W
39:11:14N 093:S3:45W
3*44:32N 094:51:36W
39:11:14N 093:53:45W
37:59; 15N 093:48:45W
41:1S:32N 095:55:20W
41:08:18N 095:52:40W
41:45:42N 103.25.-02W
40:59:48N 096fll:18W
38:33:OON 106:01 :OOW
39:48:10N 104:57:30W
40-.10-.30N 104:59:OOW
46:U*OON 112:46:26W
47:01fl5N I14:21:20W
45:45:35N 111K)5«4W
47:56:14N 114.11KMW
45:47:48N I08:28:12W
47:35:25N 103:15:05W
4»00:OON 097.1345W
49.00.00N 097. 13 45 W
42:49:42N 096:33:45W
42.49:45N 096.33: 15W
44K»49N 103:49:48W
40:45: ION 111:SS:1SW
41:20:40N 10S:3S:4SW
42:34:27N 106:41:31W
33:05:OON 113fl2_i»W
33:12«ON 115:37«OW
36.41.00N 121:44:OOW
33:46:OON 118:08.00W
Stafe WMoMi LK»UM
IA Missouri River Council Bluffs
IA NuhoaboUu River Hamburg
IA Nishnabolna River Hamburg
KS Arkansas River Derby
KS Arkansas River Derby
MO Little River Ditch 81 Hot oersvillc
MO Little River Ditch 81 Hornersville
MO Mississippi River Hannibal
MO Mississippi River WestAllon
MO Mississippi River Cape Giradeau
MO Missouri River Kansas City
MO Missouri River Lexington
MO Missouri River Si Joseph
MO Missouri River Lexington
MO Osage River Roscoe
NE Missouri River Omaha
NE Missouri River Bcllevue
NE North Plane River Mcgrew
NE Plalle River Louisville
CO Arkansas River Salida
CO South Platte River Denver
CO St. Vrian River Longmont
MT dark Fork River Warm Springs
MT dark Fork River Huson
MT East Gallatin River Bozeman
MT Goose Bay Lakeside
MT Yellowstone River Billings
ND Little Missouri R. Watford City
ND Red River Pembina
ND Red River Pembina
SD Big Sioux River Akron
SD Big Sioux River Akron
SD Castle Creek Hill Guy
UT Jordan River Salt Lake City
WY Laramie River Laramie
WY North Plane River Alcova
AZ Gila River Gila Bend
CA Alamo River Calipatria
CA Blanco Drain Saunas
CA Colorado Lagoon Long Beach
NSQ •
X
X
X
X
X
X
X
X
X
X
X
X
X
rtHNT SOURCES
NH. OUW
prc rrNc wr *s*j SH> imt rorvr
X X
X
X
X X
X X
X X
X X
X X
X X
X X
X
X X
X
X X
X X
X
X
X
X X
X
X
X
X
X
X X
X X
X X
X X
X X
X X
X
X
NONPOINT
UikMi A(rt
X
X
X
X
X
X
X
X X
X
X X
X
X X
X X
X
X
X
X
X
X
X
X
X X
X X
X X
X X
X
X
X
AMHhmtA ftHrl DwcilpUiB
fftOHOm !• U» >fcMtr W Ifct UKrHat Uu)
lod.: chem. and pest.; metals; hydro-power; same as 3042-oppositc sides of
river
Same as 3036
Same as 2190
Same as 3039. Below Wichita
Same as 2194. Below Wichita
Same as 3040. Rice growing region
Same as 2201. Rice growing region; heavy pesticide use
Fish collected near downtown area.
Ind.: chem. ; heavy metals; heavy shipping traffic
Collected at POTW outfall. Proctor & Gamble paper products, Ag
croplands
Same as 3046
Same as 2199
Ag.: croplands
Ind.: chem. and pest.; metals; hydro power; same as 2191 - opposite sides
of river
Defunct wood treatment plant
Stone Container Corporation
Sugar beet processing plant; croplands; Same as 31 1 1
Sugar beet processing plant; croplands; Same as 2100
Same as 3199
Same as 2109
Ind.: pesticides; Superfund site (chlorobenzenes)
Railroad tie treating plant (defunct)
Cotton growing region (Near Phoenix)
HCB use in agriculture
Multiple sources
Multiple sources
D-l-11
-------
TABLE D-J (Conl.)
EP
R1
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
X
X
X
X
X
X
X
X
X
X
X
X
X
X
EplM*
»
3273
3286
3271
3272
3275
3276
3289
3451
3354
32S3
3355
3290
3274
3357
3267
3270
3287
2748
3281
3264
3450
3269
3278
2037
3261
3262
2776
3238
3241
3246
2070
3244
3245
3252
3250
3249
3158
2478
3256
3248
3203
Ulllwlc Uoftliuk
41:4S:OON 124:11:OOW
33:47: 15N U8.I7:33W
40:34:OON 123:11:OOW
37:55:OON 122:21:OOW
40:54:OON 124:00:OOW
40.52:OON 124:00:OOW
36:48:OON 121:46:OOW
34:Ol:45N llg:40:45W
37:57.-OON 121:18:OOW
33:06:OON 115:40:OOW
37:56:OON 121:19:OOW
37.57.00N 121:20:OOW
41:55:OON 124:07:OOW
38:05:OON 12l:44.00W
40:27.00N 122:11:OOW
40:09.00N 122:1 1:OOW
33:46:OON 118:06:OOW
34:24:OON 119:30:OOW
34:20:OON 119:04:OOW
33:54:27N 118:31:28W
33:55:OON 118:28:OOW
37:43:OON 121.-09.-OOW
39:24:OON 123:06:OOW
19:46: 15N 155.-05.33W
21:18:OON 157:59:OOW
22:04:30N 159:22:30W
35:40:OON H4:40:OOW
60.58:30N 149:27:35W
61:13:20N 149:51:21W
57:03X»N 133:14:OOW
61:32:42N 151:30:45W
58:41:OON 1 34.03:00 W
55:23:45N 131:44:20W
43:48:29N 1 17:00: 15W
47:38«5N 116:43:15W
47:33.-07N 116:Z2.D6W
42:37:25N 114:31:58W
3:00:08N 115:li06W
46:25:15N 117:02:04W
7:19:08N 116:33:35W
5:37.19N 122:45:20W
State Wuctfentr LKMM.II
CA Elk Creek Crescent Cily
CA Harbor Park Lake Harbor City
CA Hayfork Creek Hayfork
CA Laurilzeo Canal Richmond
CA Mad River Arcata
CA Mad River Slough Arcata
CA Moss Landing Dm. Moss Landing
CA Mouth of Malibu Cr. Malibu
CA New Mormon Sigh Stockton
CA New River Westmoreland
CA Old Mormon Slough Stockton
CA Port of Stockton Stockton
CA Rowdy Creek Smith River
CA Sacramento Delta Anlioch
CA Sacramento River Anderson
CA Sacramento River Red Bluff
CA San Gabriel River Long Beach
CA Santa Clara River Santa Paula
CA Santa Clara River Santa Paula
CA Santa Monica Bay Los Angeles
CA Short Bank (Pac. O.) Los Angeles
CA Stanislaus River Ripon
CA Upper Eel River Potter Valley
HI Honolii Stream Hilo
HI Pearl Harbor Middle Loch
HI WailuaPaelekaaSt. Kauai
NV Colorado River Blw Hoover Dn
AK Bird Creek Bird
AK Ship Creek Anchorage
AK Silver Bay Sitka
AK Susilna River Susitna
AK Vanderbill Creek Juneau
AK Ward Cove Ketchikan
D Boise River Parma
D Coeur d' Aleut Lake Coeur d'Alene
D Coeur d'Alene River Coeur d'Alene
D Rock Creek Twin Falls
D Snake River Kings Hill
D Snake River Lewislon
D St. Joe River St. Marie
OR Columbia River Portland
NSQ I
X
X
X
X
X
X
X
X
COINT SOURCES
NPL Olhtr
PPC PPNC WP Rlny Site Ind POTW
X
X
X
X
X
X
X
X
X X
\
X X
X X
X
X X
X
X
X
X XX
X
X
X
X
X X
X
X
X
X
X
X
X
X
NONPO1NT
Urix Afri
X
X X
X X
X
X
X
X
X
X
X X
X
X
X
X
X
X
AddllMjul Site Otxrlptten
(P*cUIU» ta UK rtetally *T UK uropUnc «lu|
McNamara & Peepe (historical PCP site)
Multiple sources
Sierra Pacific (historical PCP site)
United Hcckathorn: pesticide packaging plant in 60's (PCB's, DDT, Pb)
MoUala-Arcata
Sierra Pacific
Multiple sources
POTW: Tapia Creek; grazing land (horses)
McCormick and Baxter (wood preservers); Superfund site (solvents)
Multiple sources (HCB use)
McCormick & Baxter (wood preservers); Ag.: croplands & orch ;
Superfund site (solvents)
McCormick & Baxter (wood preservers); Superfund site (solvents)
Arcala Lumber Company (historical PCP site)
Gaylord Container Corp.; Ind.: chern.; refinery, power plant; Ag.:
orchards and croplands
Simpson Paper Company; wooded area
Diamond International (recycled paper); Ag.: croplands and grazing
Simpson Paper Company, Pacific Coast Paper
Same as 3281
Same as 2748
El Segundo Refinery; Hyperion POTW outfall; multiple sources
POTW: Hyperion outfall
Multiple sources
Louisiana Pacific (historical PCP site)
Ag.: sugar cane growing (pesticides)
Combustion sources; Superfund site (solvents)
Ageat Orange test site (not a designated superfund site)
Salvage yard with runoff of PCB; Superfund site; landfill
Alaska Pulp Company
Louisiana Pacific Corp. (sulfite mill); Ketchikan Pulp and Paper
Ind.: silver mining
Mining
Potlalch Corporation
D-l-12
-------
TABLE D-l (Cont.)
EPA
R
-------
D-l-14
-------
APPENDIX D-2
Dioxins/Furans: Episode Numbers Used in Statistical Tests
(By Category)
-------
TABLE D-2
Dioxins/Furans: Episode Numbers Used in Statistical Tests (By Category)
NASQAN (NSQ)
Episode
2015
2016
2017
2023
2026
2070
2098
2105
2122
2126
2148
2151
2152
2191
2205
2220
2228
2246
2247
2280
2298
2309
2322
2358
2430
2431
2432
2437
2439
2478
2544
2776
3036
3041
State
AR
AR
AR
AR
OK
AK
WY
ND
MT
MS
FL
FL
FL
IA
NE
VA
VA
WA
WA
TX
TN
3042
3050
3104
3199
3281
3308
Total
NE 3261
MO ' 3272
PA
SD
CA
NY
40
AGRICULTURE (AG)
Episode
2280
2358
2478
3050
3082
3083
3084
3099'
3105
3158*
3170
3171
3180
AL 3193
NY
3208
ME 3212
MI 3282
MI ! 3352
MI i 3437
MN Total
OH !
Jj^ SUPERFUND
LA Episode
NV 3078
IA 3097
NE 3226
State
TX
ME
ID
MO
LA
LA
TX
DE
OK
ID
AL
AL
GA
VA
OR
OR
CA
LA
OR
19
(NPL)
State
AR
DE
WA
3414
3415
Total
POTW
Episode
2122
2152
2322
2432
2544
3308
3450
3451
Total
BACKGROUND
Episode
2027
2037
2110
2139
2216
2283
2301
2379
2387
2397
2435
2651
3001
3022
3023
3027
HI
CA
PA
PA
7
State
MT
FL
NY
MI
LA
NY
CA
CA
8
(B)
State
OK
HI
SD
NC
PA
TX
TN
IL
MN
WI
MI
NJ
MN
ME
ME
ME
No data available for dioxins/furans. Number of data values varies by chemical.
D-2-1
-------
TABLE D-2 (Cont.)
3028
3037
3073
3074
3075
3166
3169
3178
3179
3187
3200
3205
3238
3248
3309
3320
3430
Total
PULP & PAPER
(Chlorine) (PPC)
Episode
2015
2016
2017
2138
2142
2294
2302
2304
2355
2385
2422
2427
2532
2721
2725
3062
* No data available
ME
IA
AR
NM
TX
NC
AL
GA
GA
SC
CO
OR
AK
ID
NY
NY
NJ
33
State
AR
AR
AR
NC
FL
GA
AL
AL
ME
MN
WI
WI
LA
ME
ME
3080
3081
3088
3107
3118
3122
3146
3150
3151
3152
3192
3217
3218
3220
3221
3222
3224
3237
3245
3246
3256
3260
3267
3303
3316
3317
3318
3328
3329
3331
3332
3333
3335
3336
3337
3339
3340
AR
LA 3341
I
TX 3342
LA 3343
WI ' 3344
MI 3345
MI 3346
WI ; 3347
MA 3348
MA 3349
NH
3350
WA 3351
OR 3353
OR
WA
WA
WA
WA
MT
AK
AK
ID
NY
CA
NY
PA
MD
PA
AL
FL
FL
FL
FL
GA
GA
GA
KY
MS
3395
3403
3404
3416
3418
3420
3421
3422
3423
3424
3425
3435
3452
Total
INDUSTRY/URBAN
(IND/URB)
Episode
1994
2023
2057
2060
2191
2210
2215
2220
MS
NC
NC
NC
NC
NC
SC
SC
SC
TN
TN
LA
NC
TN
TN
LA
LA
PA
VA
VA
VA
VA
LA
MS
AR
78
State
MI
AR
IN
IN
IA
DC
PA
VA
for dioxins/furans. Number of data values varies by chemical.
D-2-2
-------
TABLE D-2 (Cont.)
2225
2227
2309
2328
2329
2410
2416
2500
3024
3025
3034
3035
3038
3039
3040
3042
3043
3044
3045
3046
3047
3048
3049
3060
3064
3066
3079
3085
3094
3100
3101
3103
3111
3113
3115
3120
3134
* No data available
VA
VA
AL
NY
NY
MI
OH
WV
ME
ME
IA
IA
1A
KS
MO
NE
NE
MO
MO
MO
MO
MO
MO
AR
LA
LA
OK
TX
PA
MD
PA
MD
ND
IL
IL
MI
WI
3141
3144
3147
3149
3164
3165
3168
3172
3174
3182
3188
3189
3190
3198
3199
3203
3206
3219
3227
3231
3234
3235
3236
3244
3249
3250
3252
3258
3269
3275
3276
3283
3285
3286
3289
3296
3297
for dioxins/furans. Number of data
WI
WI
DC
DE
NC
NC
AL
AL
FL
KY
TN
TN
TN
CO
SD
OR
OR
OR
WA
WA
MT
MT
MT
AK
ID
ID
ID
VA
CA
CA
CA
CA
CA
CA
CA
NY
NY
3298
3299
3300
3301
3302
3306
3307
3310
3311
3313
3314
3315
3321
3322
3324
3326
3327
3411
3412
3426
3428
3432
3438
3443 *
Total
NY
NY
NY
NY
NY
NY
NY
PA
WV
WV
WV
PA
NY
NY
NY
NY
NY
NY
NY
NJ
NJ
PR
WA
AR
106
PULP & PAPER
(No Chlorine) (PPNQ
Episode
3089
3090
3091
3092
3093
3108
3112
3114
3135
values varies by chemical.
State
OK
OK
OK
LA
TX
WI
MN
IL
WI
D-2-3
-------
TABLE D-2 (Cont.)
3136
3137
3138
3140
3143
3145
3184
3191
3270
3287
3294
3330
3360
3375
3376
3377
3378
3401
Total
WI
WI
WI
WI
WI
WI
MS
WA
CA
CA
REFINERY/OTHER
INDUSTRY (R/I)
Episode State
2026 OK
2380
2383
3061
3063
3069
3071
WA 3072
FL 3086
AL i 3095
GA
GA
GA
GA
TN
27
WOOD PRESERVERS
(WP)
Episode State
3076 OK
3077 AR
3110
3167
3173
3196
3197
3271
3273
3274
3278
Total
WI
NC
FL
WY
CO
CA
CA
CA
CA
11
3096
3125
3183
3264
3312
3431
3434
3442
3444
3446
Total
IL
IL
AR
LA
TX
TX
TX
LA
PA
PA
MN
KY
CA
WV
PR
NJ
LA
TN
KY
20
i
* No data available for dioxins/furans. Number of data values varies by chemical.
D-2-4
-------
APPENDIX D-3
Xenobiotics: Episode Numbers Used in Statistical Tests
(By Category)
-------
TABLE D-3
Other Xenobiotics: Episode Numbers Used in Statistical Tests (By Category)
NASQAN (NSQ)
Episode
2015
2016
2017
2023
2026
2070
2098
2105
2122
2126
2148
2151
2152
2191
2205
2220
2228
2246
2247
2280
2298
2309
2322
2358*
2430
2431
2432
2437
2439
2478
2544
2776
3036
State
AR
AR
AR
AR
3041
3042
3050
3104
3199
3281
OK ' 3308
AK Total
NE
NE
MO
PA
SD
CA
NY
40
WY
:T * AGRICULTURE (AG)
jvfp Episode
MS 2280
FL 2358*
FL
FL
IA
NE
VA
VA
WA
WA
TX
TN
AL
NY
ME
MI
MI
MI
MN
OH
ID
LA
NV
IA
2478
3050
3082
3083
3084
3099
3105
3158
3170
3171
3180
3193
3208
3212
3282
3352
3437*
Total
SUPERFUND
Episode
3097
3226
State
TX
ME
ID
MO
LA
LA
TX
DE
OK
ID
AL
AL
GA
VA
OR
OR
CA
LA
OR
19
(NPL)
State
DE
3261
3272
3414
3415
Total
n^"w*W7
POTW
Episode
2122
2152
2322
2432
2544
3308
3450*
3451*
Total
BACKGROUND
Episode
2110
2139
2216
2283
2397
2435
2651
3022
3023
3028
3037
3073
3074
3075**
3166
WA 3169
HI
CA
PA
PA
6
State
MT
FL
NY
MI
LA
NY
CA
CA
8
(B)
State
SD
NC
PA
TX
WI
MI
NJ
ME
ME
ME
LA
AR
NM
TX
NC
AL
* No data available for other xenobiotics. Number of data values varies by chemical.
* * Data available
for mercury only.
D-3-1
-------
TABLE D-3 (Cont.)
3178
3200
3205
3238
3248
Total
PULP & PAPER
(Chlorine) (PPC)
Episode
2017
2138**
2294
2302
2422
2532
2721
2725
3107
3118
3122
3151
3152
3192
3222
3224
3237
3245
3246
3260
3267
3303
3316
3318
3332
3335
3336
* No data available
** Data available for
GA
CO
OR
AK
ID
21
State
AR
NC
GA
AL
WI
LA
3340
3341
3342
3348
3395
3403
3416*
3418*
3420
3421
3422
3423
3424
3425
3435
Total
ME
ME
WI
MI
MI
MA
NH
WA
WA
WA
MT
AK
AK
NY
CA
NY
PA
PA
FL
GA
GA
INDUSTRY/URBAN
(IND/URB)
Episode
3043
3044
3045
3079
3085
3101
3120
3149
3172
3174
3189
3190
3203
3234
3235
3236
3244**
MS
MS
NC
sc
NC
TN
LA
LA
PA
VA
VA
VA
VA
LA
MS
42
State
NE
MO
MO
OK
TX
PA
MI
DE
AL
FL
TN
TN
OR
MT
MT
MT
AK
3258
3269*
3275**
3276
3283
3285
3286
3289
3296
3298
3306
3307
3315
3411
3412
3426
3428
3438*
Total
VA
CA
CA
CA
CA
CA
CA
CA
NY
NY
NY
NY
PA
NY
NY
NJ
NJ
WA
35
PULP & PAPER
(No Chlorine )
Episode
3090
3091
3108
3112
3135
3136
3140
3143
3145
3191
3287
3294
3330
3360
(PPNC)
State
OK
OK
WI
MN
WI
WI
WI
WI
WI
WA
CA
WA
FL
AL
for other xenobiotics. Number of data values varies by chemical.
mercury only.
D-3-2
-------
TABLE D-3 (Cont.)
3376 GA
3377 GA
3401 TN
Total 17
WOOD PRESERVERS
(WP)
Episode State
3076 OK
3077 AR i
3110 WI
3167 NC !
3173 FL ;
3196 WY
3197** CO !
3271 CA !
3273 CA
3274 CA
3278 CA
Total 11
REFINERY/OTHER
INDUSTRY (R/T)
Episode State
3061 AR
3063 LA
3072 TX
3095 PA
3446 KY
Total 5
* No data available for other xenobiotics. Number of data values varies by chemical.
* * Data available for mercury only.
D-3-3
-------
D-3-4
-------
APPENDIX D-4
Dioxin/Furan Data by Episode Number
-------
Key for Diorin/Furan Data Table (Units = pg/g)
2,3,7,8 TCDD
1,2,3,7,8 PeCDD
1,2,3,4,7,8 HxCDD
1,2,3,6,7,8 HxCDD
1,2,3,7,8,9 HxCDD
1,2,3,4,6,7,8 HpCDD
2,3,7,8 TCDF
1,2,3,7,8 PeCDF
2,3,4,7,8 PeCDF
1,2,3,4,7,8 HxCDF
1,2,3,6,7,8 HxCDF
1,2,3,7,8,9 HxCDF
2,3,4,6,7,8 HxCDF
1,2,3,4,6,7,8 HpCDF
1,2,3,4,7,8,9 HpCDF
Compound Name
Tetrachlorinated dibenzodioxins
Pentachlorinated dibenzodioxins
Hexachlorinated dibenzodioxins
Heptachlorinated dibenzodioxins
Tetrachlorinated dibenzofurans
Pentachlorinated dibenzofurans
Hexachlorinated dibenzofurans
Heptachlorinated dibenzofurans
CAS Number
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
37871-00-4
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57117-44-9
72918-21-9
60851-34-5
67562-39-4
55673-89-7
Concentration Information
Enisode and SCC Information
ND = Not Detected
NA = Not Analyzed
QR = Below 40 percent recovery
DPE = Diphenyl Ether interference, a "Y" in the
column indicates that there was interference
with the analyses for 2,3,4,7,8 PeCDF; 1,2,3,4,6,7
HxCDF; 1,2,3,4,7,8 HxCDF; and 2,3,4,6,7,8
HxCDF
= Asterisk on 1,2,3,4,7,8 HxCDF indicates
coelution with 1,2,3,4,6,7 HxCDF on GC column
(DB5 30M)x
Episode Number: Refer to Site Matrix Table
D-l for Waterbody Name and Location
SCC = Sample Control Center Numbers
First Letter Designation:
S = Confirmation Sample
D = Environmental Sample
Q = Duplicate Sample
Sample Information
Sample Type
F = Field Sample
L = Lab Duplicate
M = Mollusks/Crustaceans
O = Other
Fish Tissue Type
PF = Predator Fillet
BF = Bottom Fillet
WB = Whole Body
WP = Whole Predator
Second Letter Designation •
A =
B =
C =
D =
E =
F =
G =
H =
Y =
J =
Region 1
Region 2
Region 3
Region 4
Region 5
Region 6
Region 7
Region 8
Region 9
Region 10
"The number of samples shown on the summary
tables in Volume I does not include the duplicate
and confirmation samples.
D-4-l
-------
D-4-2
-------
Dioxins/Furans
Concentration Ranges
D-4-3
-------
D-4-4
-------
Episode SCC
1994 DE017703
1994 00110586
1998 13285
1998 13421
2015 DF001001
2015 DF001002
2016 DF001101
2016 DF001102
2017 OF001201
2017 DF001202
2018 DF001301
2023 DFOOU02
2023 DF001403
2026 DF001702
2026 DF001703
2027 DF001802
2027 DF001803
2037 DY000501
2037 OY000502
2056 OE000501
2057 OE000601
2059 DE000801
2060 OE000901
2070 DJ000901
2070 OJ000902
2070 OD072186
2098 DH001501
2098 OH001504
2100 DH001702
2100 DH001703
2100 00111086
2105 DH002201
2105 DH002204
2105 00063086
2109 DH002601
2109 OH002602
2110 OH002710
2122 DH003901
2122 DH003904
2126 D0000302
2126 DD000303
2126 00062686
2133 OD001002
Type Description
F UB Carp
F PF U«U«y«
L UB Carp
f UB Carp
F PF Pike
F UB Carp
F UP Crappie
F UB Sucker
F BF Sucker
F UB Carp
F BF Carp
F UB Sucker
F PF Spotted Bass
F UB Carp
F UB Carp
F PF White Crappie
F PF Lm Bass
F UB Carp
F UB not available
F UP not available
F UB Carp
F UB Carp
F UB Carp
F UB Carp
F UP Rainbow Trout
F UB Longnose Sucker
L UP Rainbow Trout
F UB not available
F PF not available
F PF Sauger
F UB Catfish
L UB Catfish
F PF Sauger
F UB Carp
L U8 Carp
F UB not available
F BF not available
F UP Brown Trout
F PF Rainbow Trout
F UB White Sucker
F UB Carp
F PF White Crappie
L UB Carp
F BF Blue Catfish
2378
TCOO
34.03
ND
29.26
ND
0.68
4.73
1.43
4.17
1.69
0.66
ND
ND
ND
ND
1.17
ND
ND
0.46
ND
ND
4.23
ND
6.63
1.76
ND
ND
ND
ND
ND
ND
1.65
1.98
ND
ND
ND
0.97
ND
ND
ND
ND
ND
ND
2.16
ND
12378
PECOD
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
HO
1.09
OR 13
HO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
123478
HXCOD
OR 5
OR ND
4.01
ND
NO
ND
ND
ND
ND
1.72
ND
OR ND
NO
0.76
ND
ND
ND
ND
ND
ND
QR MD
ND
OR 2
QR ND
ND
ND
OR ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
NO
QR ND
ND
ND
ND
OR ND
1.84
ND
123678
HXCOD
OR 61
QR ND
58.90
1.91
MO
4.48
ND
2.95
2.05
3.32
1.05
QR NO
NO
ND
1.35
ND
ND
3.57
NO
NO
OR 15
ND
OR 16
OR 2
ND
ND
QR ND
ND
ND
ND
7.34
NO
ND
ND
ND
NO
ND
QR ND
NO
ND
5.48
OR NO
4.77
1.97
OIOXIN
123789
HXCOD
OR 16
QR NO
13.47
ND
NO
ND
ND
ND
NO
0.74
ND
OR ND
ND
ND
ND
ND
ND
ND
NO
NO
OR ND
ND
QR ND
QR ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
1.61
QR NO
1.41
ND
/ FURAN
CONCENTRATJOWS,
1234678 2378
HPCDD
QR 45
OR HD
OR ND
4.44
ND
OR 15
OR ND
4.04
5.10
OR 14
OR 6
QR ND
QR 2
3.08
OR 5
5.48
QR ND
QR ND
ND
QR 4
OR 45
8.16
OR 22
OR 8
ND
QR 3
QR ND
OR ND
1.01
ND
QR ND
QR NO
1,06
OR NO
OR ND
OR 14
QR 4
QR ND
1.89
4.32
QR 23
QR ND
OR 23
QR 6
TCDF
14.09
0.80
12.63
ND
2.28
4.17
2.38
16.61
5.23
1.47
0.31
0.74
ND
0.30
0.55
ND
NO
0.81
0.29
ND
2.39
2.66
4.55
2.20
0.50
NO
ND
0.61
NO
ND
0.21
ND
NO
ND
ND
0.46
ND
ND
ND
1.09
0.37
ND
ND
ND
12378
PECOF
8.19
ND
7.74
0.76
NO
ND
HO
ND
MD
0.33
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.92
1.36
ND
ND
0.51
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
P9/9
23478
PECOF
29.32
ND
24.30
1.93
NO
2.11
ND
1.11
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
1.33
3.26
0.91
15.41
HD
ND
ND
ND
ND
ND
ND
ND
1.47
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123478
HXCOF*
OR 19
OR ND
17.04
NO
HO
QR 2
ND
2.19
0.63
ND
ND
OR ND
NO
ND
ND
ND
ND
ND
ND
1.24
NO
ND
OR 3
0.84
ND
ND
QR NO
NO
NO
NO
ND
ND
ND
ND
ND
OR NO
HO
QR ND
0.35
ND
ND
QR ND
OR ND
ND
123678
HKCOF
QR 6
OR ND
ND
NO
HO
QR 1
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
NO
ND
ND
ND
1.35
1.51
ND
OR 1
ND
ND
ND
OR ND
NO
NO
ND
ND
ND
ND
ND
ND
QR ND
HO
OR ND
ND
ND
ND
QR NO
QR ND
ND
123789
HXCOF
OR ND
QR ND
ND
ND
ND
QR ND
ND
ND
ND
ND
NO
QR ND
ND
ND
ND
ND
NO
ND
ND
HO
HD
ND
QR ND
ND
ND
ND
QR HO
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
QR ND
ND
ND
ND
QR NO
QR ND
ND
234678
HXCOF
OR 8
QR HD
4.89
ND
HD
OR ND
ND
2.05
0.81
NO
HD
QR ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR 1
0.48
ND
ND
QR ND
HD
NO
ND
ND
ND
ND
ND
ND
QR ND
ND
QR ND
NO
ND
ND
QR HO
QR ND
ND
1234678 1234789
HPCDF
OR 17
QR ND
OR 17
ND
NO
OR 2
QR ND
3.09
NO
OR ND
OR ND
OR ND
OR NO
OR ND
QR ND
ND
QR ND
QR HD
1.13
OR ND
OR 6
1.29
OR 4
OR 2
NO
OR ND
QR NO
OR ND
NO
ND
OR ND
QR ND
ND
OR ND
OR HO
OR 3
QR NO
QR ND
NO
ND
QR HD
QR HD
QR MD
QR ND
HPCDF
QR ND
QR ND
OR ND
ND
NO
OR ND
QR ND
ND
HD
QR ND
OR ND
OR NO
OR NO
OR NO
QR ND
NO
QR ND
OR ND
HD
OR ND
QR NO
ND
QR ND
QR HO
ND
QR ND
QR ND
QR ND
NO
ND
QR ND
QR HO
HD
QR MD
QR ND
QR ND
OR NO
QR ND
ND
ND
OR ND
OR HO
QR ND
OR ND
OPE
TEC
50.51
0.08
52.89
0.35
0.9t
6.65
1.67
7.18
2.61
1.40
0.14
0.07
MO
0.14
1.36
0.05
ND
0.90
0.04
0.97
6.32
1.36
14.79
2.14
0.05
ND
HD
0.06
0.07
NO
2.40
2.72
0.01
ND
ND
1.02
NO
NO
0.05
0.15
0.75
ND
2.96
0.20
Y
Y
Y
r
Y
Y
Y
Y
Y
-------
Episode SCC Type Description
2138 D0001501 F UB Redhorse Sucker
2138 DD001504 F PF L» Bass
2139 00001601 F UB Carp
2139 DD001604 F PF Rainbow Trout
2139 00071486 L PF Rainbow Trout
2142 00001902 F UB Catfish
2142 00001903 F PF La Bass
2148 00002501 F UB Saltwater Catfish
2148 00002504 F BF Saltwater Catfish
2151 00002801 F PF Lm Bass
2151 00002803 F UB Spotted Sucker
2152 00002902 F PF L* Bass
2152 D0002903
2190 OC005101
2190 OG005104
2191 DG005205
2191 DGOOS206
2191 00092486
2194 OG005501
2194 DG005504
2199 OG006001
2199 OG006004
2201 OC006201
2201 DG006204
2205 OG006601
2205 DG006602
2210 DC005401
2211 OC005503
2212 OC005602
2212 OC005605
2215 OC005902
2216 DC006002
2216 OC006003
2220 OC006401
2220 OC006405
2225 OC006902
2225 DC006903
2225 00101387
2227 DC007102
2227 OC007104
2228 DC007201
2228 DC007204
UB Lake Chubsucker
UB Carp
PF Bluegill
UB Carp
BF Carp
BF Carp
UB Carp
BF Channel Catfish
UB Carp
PF L* Bass
UB Carp
PF Bow* in
UB Carp
BF Carp
UB Catfish
UB Redhorse Sucker
PF SB) Bass
UB White Sucker
UB Carp
PF Brown Trout
UB White Sucker
PF Redbreast Sunfish
UB Catfish
PF Sm Bass
UB Shorthead Redhorse
UB Shorthead Redhorse
PF Ua Bass
UB Channel Catfish
PF Longear Sunfish
UB Redhorse Sucker
2228 00070286 I UB Redhorte Sucker
2231 DC007503 F UB Gizzard Shad
2378
TCOO
2.01
0.86
NO
2.26
1.87
NO
ND
NO
NO
m
ND
M>
NO
m>
NO
M>
HO
HO
HD
HD
2.44
HO
HD
HD
HD
HD
5.61
0.59
HD
2.01
NO
HD
HD
HD
HD
NO
6.76
5.86
HD
NO
HD
HD
HD
ND
12378
PECDD
1.79
0.62
HD
NO
NO
0.66
ND
HD
NO
HD
HD
HD
HD
HD
HD
HD
HO
HO
HD
OR ND
HD
HD
HD
HD
HO
HD
HO
HD
HO
ND
NO
HO
NO
ND
NO
ND
2.93
2.58
ND
0.76
HO
ND
ND
ND
123478
HXCDO
NO
NO
OR ND
NO
ND
HD
HO
HD
ND
ND
ND
ND
ND
HO
ND
OR ND
NO
ND
ND
OR ND
NO
NO
OR ND
OR ND
ND
ND
OR HD
HO
OR ND
NO
ND
NO
NO
NO
NO
ND
1.70
1.10
ND
ND
ND
ND
ND
HO
123678
HXCOD
4.61
4.13
OR ND
NO
HD
HD
ND
HD
HD
HO
ND
ND
ND
ND
ND
OR 7
HD
1.59
4.48
OR NO
1.11
HD
OR 12
OK HO
ND
ND
OR ND
0.20
OR ND
ND
4.64
ND
ND
ND
2.22
ND
3.25
2.86
ND
2.77
ND
ND
1.36
ND
D10X1N
123789
HXCDO
1.14
0.56
OK ND
NO
NO
HD
NO
ND
ND
NO
ND
NO
ND
NO
ND
OR HD
ND
ND
NO
OR ND
ND
HD
Oft ND
a* NO
HD
HD
OR HD
HD
0« ND
HD
HD
HD
HD
ND
ND
HD
0.42
NO
ND
0.87
ND
ND
ND
ND
/ FlffiAN CONCENTRATIONS,
1234678 2378 12378
HPCDD
15.91
6.72
OR ND
2.21
1.67
6.74
ND
OR 3
1.60
2.06
2.04
2.62
2.55
5.98
1.80
OR 23
OR 9
OR 8
OR HD
OR HD
4.02
ND
OR 56
OR ND
OR HD
ND
OR 5
1.29
OR HD
4.32
12.92
HO
OR NO
OR 6
6.12
0.36
6.67
6.92
ND
8.05
OR 2
ND
OR 3
OR 4
TCDF
13.45
0.82
ND
0.90
0.75
0.26
0.10
HD
ND
ND
ND
HD
HD
HO
ND
1.33
HD
HD
1.16
ND
HD
HD
HD
HD
0.38
0.41
0.85
7.77
HD
13.97
0.80
ND
0.29
ND
0.42
0.38
44.75
38.76
0.39
0.24
HD
3.81
4.21
8.5
PECDF
1.33
0.27
NO
NO
0.47
HO
ND
ND
ND
ND
ND
NO
ND
NO
HD
0.61
HD
HD
HO
HD
NO
NO
ND
NO
NO
NO
OR ND
ND
ND
0.88
0.37
HD
HO
ND
ND
ND
1.96
1.54
ND
NO
ND
HD
ND
ND
P9/9
23478
PECDF
3.69
0.52
HD
0.70
0.70
0.86
ND
ND
ND
NO
NO
NO
HD
ND
ND
ND
NO
HD
0.74
ND
0.22
HO
HD
NO
ND
ND
OR ND
1.40
HD
2.86
1.73
ND
ND
ND
0.38
ND
3.88
3.16
HD
0.54
HD
HD
0.71
1.6
123478
HXCDF*
11.3
1.7
OR ND
NO
ND
NO
ND
ND
NO
ND
NO
ND
NO
NO
ND
Oft ND
ND
NO
NO
OR ND
0.37
ND
HD
ND
ND
ND
1.25
1.90
OR HD
1.11
ND
HD
HD
0.82
HD
NO
5.6
3.80
NO
ND
ND
0.83
1.67
2.6
123678
HXCOF
HD
HD
OR HD
HD
HD
HD
HD
HD
HD
HD
HD
HD
HD
HO
ND
OR ND
HD
ND
HO
OR ND
HO
HD
HO
HD
ND
ND
NO
HD
OR ND
NO
HD
ND
ND
ND
ND
ND
HD
HD
HD
HD
HD
HO
HD
HO
123789
HXCDF
NO
ND
OR NO
ND
ND
NO
ND
HD
HD
HO
HD
ND
ND
ND
ND
OR HD
HO
HD
ND
OR HD
HD
HO
ND
HO
HD
HD
ND
ND
OR HD
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
234678
HXCDF
5.45
0.60
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HO
HD
ND
OR ND
ND
HD
HD
OR HO
HD
ND
HD
HD
HD
ND
NO
1.56
OR ND
ND
ND
ND
ND
ND
ND
ND
8.37
4.11
HD
ND
ND
0.51
HD
1.0
1234678 1234789 OPE
HPCOF
4.77
1.00
OR HD
ND
0.48
1.13
NO
OR ND
HO
ND
HD
HD
ND
HD
ND
OR 4
OR NO
OR ND
OR NO
OR ND
HD
HD
OR HD
OR ND
OR ND
0.96
OR ND
1.29
OR NO
ND
1.44
HO
OR HD
OR ND
ND
ND
6.03
4.49
ND
0.61
OR ND
ND
OR ND
Oft 2
HPCOF
ND
ND
OR NO
ND
HD
ND
ND
OR ND
ND
ND
ND
NO
ND
ND
HD
OR ND
OR HD
OR HD
OR HD
OR ND
HO
HD
OR ND
OR ND
OR ND
HO
OR ND
ND
OR HD
HD
HD
HD
OH ND
OR HD
ND
ND
ND
ND
ND
NO
OR HD
HD
OR HD
OR ND
TEC
8.62
2.30
ND
2.72
2.34
0.86
0.01
HO
0.02
0.02
0.02
0.03
0.03
0.06
0.02
0.16
HD
0.16
0.93
ND
2.74
HD
ND
ND
0.04
0.05
5.82
2.46
ND
5.04
1.57
HD
0.03
0.08
0.52
0.04
16.80
13.98
0.04
1.12
ND
0.52
1.08
2.01
Y
T
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
D-4-6
-------
Episode SCC Type Description
2246 DJ002301
2246 DJ002302
2247 DJ002403
2247 DJ002404
2280 DF005201
2280 DF005204
2280 00062386
2283 DF005501
2283 DF005502
2290 DD003403
2294 DD003801
2294 00001804
2297 D0004102
2297 00004103
2298 DD004201
2298 DD004203 F
2301 D0004504 F
2301 00071786 L
2302 DD004601
2304 DD004801
2304 00004804
2309 D0005301
2309 DD005304
2322 DB001301
2322 DB001304
2322 00082686
2326 DB001701
2326 DB001704
2328 DB001904
2329 DB002004
2341 DD006002
2341 00006003
2355 DA001603
2356 DA001702
2356 DA001703
2358 DA001901
2369 DA003202
2369 DA003203
2369 00030387
2375 DA003802
2375 DA003803
2376 DA003903
2376 00111886
2379 DE005404
F BF Bridgetip Sucker
F UB Bridgetip Sucker
F BF Bridgetip Sucker
F UP Mountain Uhitefish
F UB Carp
F BF Channel Catfish
L BF Channel Catfish
F UB Gray Redhorse
F UP Longear Sunfish
F UB Spotted Sucker
PF Im Bass
UB Carp
UB Carp
PF LM Bass
UB Channel Catfish
UP Im Bass
UP Rock Bass
UP Rock Bass
F UB Quillback Carpsucker
F UB Carp
F PF Im Bass
F UB Carp
F PF LM Bass
F UB White Sucker
F PF LM Bass
L PF not available
F UB White Sucker
F PF Rock Bass
F PF Chinook Salmon
F PF Broun Trout
F PF LM Bass
f UB Carpsucker
F WB White Sucker
F PF LM Bass
F WB White Sucker
F UP ns
F PF LM Bass
F WB White Sucker
L UB White Sucker
F PF Pickerel
F UB White Sucker
F UB White Sucker
L UB White Sucker
F PF LM Bass
2378
TCOO
NO
NO
ND
0.37
ND
ND
ND
ND
ND
4.5
2.6
1.69
ND
ND
ND
ND
ND
ND
0.55
28.66
16.08
ND
ND
ND
ND
NO
ND
ND
12.89
12.49
2.14
4.42
7.97
3.57
23.38
ND
ND
1.01
ND
ND
1.26
ND
ND
ND
12378
PECDD
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
14.3
0.9
0.75
0.35
NO
Oft ND
Oft ND
ND
HD
0.47
9.40
1.26
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.16
ND
ND
ND
OR ND
OR ND
NO
ND
0.80
NO
ND
ND
123478
HXCDD
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.5
ND
0.55
ND
ND
OR ND
OR NO
ND
OR ND
HD
11.62
0.31
Oft ND
ND
QR NO
OR NO
ND
ND
HD
HD
ND
ND
ND
0.55
HD
ND
ND
Oft ND
OR ND
QR ND
ND
0.43
ND
OR ND
QR HO
123678
HXCDD
ND
ND
1.30
1.64
ND
0.44
ND
ND
HD
100.9
1.2
ND
0.47
HO
OR ND
OR ND
ND
OR ND
HD
25.98
1.77
OR 8
ND
OR HD
OR ND
ND
ND
ND
NO
ND
0.39
1.96
4.31
ND
4.76
4.57
QR ND
OR 1
QR 1
ND
1.77
ND
OR ND
OR ND
D10X1N
123789
HXCDD
ND
ND
NO
ND
ND
ND
ND
ND
ND
6.7
0.2
0.29
ND
ND
QR HO
OR ND
ND
OR ND
0.21
5.38
0.32
OR ND
ND
QR HD
QR HD
NO
ND
ND
ND
ND
ND
ND
0.40
ND
ND
ND
OR ND
QR ND
OR ND
HO
0.24
ND
OR ND
QR HD
/ FURAN
CONCENTRATIONS.
1234678 2378
HPCDD
OR ND
QR 5
OR 1
QR 2
Oft HO
2.17
2.10
OR ND
OR ND
141.2
2.3
4.58
1.67
HD
QR HO
OR ND
QR ND
OR ND
2.60
90.77
2.20
OR 26
QR 2
QR ND
QR ND
QR ND
8.16
ND
HD
QR ND
0.72
3.72
7.38
OR ND
1.11
OR 24
QR ND
OR ND
QR 3
1.77
3.87
ND
OR ND
OR HD
TCOF
ND
ND
1.22
0.99
HD
ND
ND
ND
ND
22.0
2.1
5.29
1.51
0.45
HD
HO
0.86
ND
0.45
49.48
34.50
11.67
3.2
HD
0.41
HD
ND
ND
4.29
5.76
4.38
6.56
40.59
2.32
43.82
0.60
HD
9.50
8.51
0.64
12.70
9.12
8.16
HO
12378
PECDF
ND
0.20
ND
ND
HD
ND
ND
ND
ND
17.2
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
0.97
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.59
3.11
1.46
ND
HD
ND
ND
ND
ND
ND
0.67
ND
ND
ND
P9/9
23478
PECDF
HD
NO
ND
0.50
ND
ND
ND
HD
ND
15.3
HD
0.52
ND
ND
ND
HO
ND
ND
NO
7.22
0.64
ND
ND
ND
ND
HO
0.56
ND
4.61
ND
0.91
5.21
1.13
NO
2.19
HD
ND
ND
ND
HD
1.19
2.03
1.67
ND
123478
HXCDF*
ND
1.00
ND
ND
ND
HO
ND
ND
OR ND
11.6
0.7
0.70
ND
ND
OR ND
QR ND
ND
ND
0.50
4.20
0.20
OR ND
ND
OR ND
ND
HD
NO
NO
8.14
4.15
0.60
3.40
0.74
ND
ND
3.01
OR ND
QR ND
OR 1
ND
0.88
3.61
ND
QR ND
123678
HXCDF
ND
NO
ND
ND
ND
HD
HD
ND
OR ND
6.2
HD
HD
ND
ND
QR ND
OR HD
ND
ND
ND
2.52
HO
OR NO
ND
OR ND
ND
ND
NO
ND
ND
ND
HD
0.82
ND
ND
ND
HD
Oft HO
OR HO
OR HO
ND
HD
NO
ND
OR NO
123789
HXCDF
HD
HO
HO
HO
ND
HD
HO
ND
OR ND
ND
HD
ND
ND
ND
OR ND
OR HD
NO
ND
ND
ND
HD
QR ND
ND
OR ND
NO
HD
HD
HO
ND
ND
HD
NO
ND
ND
ND
ND
QR ND
OR ND
OR ND
ND
HD
HD
ND
OR ND
234678
HXCDF
ND
0.52
0.58
0.57
NO
HD
HD
ND
OR ND
9.6
0.4
0.24
ND
ND
QR ND
OR ND
ND
ND
ND
1.82
ND
QR ND
ND
OR ND
NO
HD
HO
NO
1.36
ND
0.34
0.67
0.90
ND
ND
ND
QR HD
OR ND
OR ND
NO
HD
HO
NO
QR ND
1234678 1234789 DPE
HPCDF
QR HD
QR HD
OR 1
QR 1
QR NO
ND
HD
OR ND
OR ND
12.5
0.5
0.53
ND
0.30
OR NO
OR ND
OR HD
OR ND
0.73
5.54
0.37
OR HD
OR ND
Oft ND
QR HO
QR ND
HD
HO
5.46
OR 2
0.63
1.55
2.29
OR ND
ND
OR ND
QR HD
QR ND
OR 2
ND
1.02
HD
QR NO
OR HO
HPCDF
OR NO
OR HD
QR HD
OR ND
QR ND
ND
HD
QR ND
OR ND
0.5
NO
HD
HO
HD
QR NO
OR ND
OR ND
QR ND
NO
ND
ND
OR HD
OR NO
OR ND
OR ND
QR ND
HD
ND
ND
OR ND
ND
HD
HO
OR ND
ND
OR ND
OR HD
QR ND
OR ND
ND
ND
ND
QR HO
OR HD
TEC
NO
0.16
0.31
0.94
ND
0.07
0.02
HO
NO
38.15
3.54
3.08
0.39
0.05
HD
HO
0.09
ND
0.93
48.03
20.81
1.17
0.32
ND
0.04
ND
0.36
HO
16.63
13.48
3.21
8.57
14.03
3.80
29.34
0.82
HD
1.96
0.85
0.08
3.94
2.29
1.65
ND
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
D-4-7
-------
Episode SCC Type Description
3380 DE 005501 F WB Carp
2383 DEOOS801 F UB Carp
2385 CE006002 F WB White Sucker
2385 00701987 L WB White Sucker
2387 OE006201 F UB Carp
2394 OE006901 F WB Carp
2397 OE007201 F WB Sucker
2397 DE007204 F PF Wall eye
2410 DE003501 F WB Carp
2410 DE008504 F PF $m Bass
2416 OE009101 F WB Carp
2422 OE009702 F WB Carp
2427 DE010202 F WB Carp
2427 DE010203 F PF Walleye
2427 00 102887 I PF Walleye
2429 DE010402 F WB Carp
2429 DE010403 F PF Walleye
2429 00010687 L PF Walleye
2430 DE010602 F PF Northern Pike
2430 DE010603 F WB Redhorse Sucker
2431 DE010702 F PF Brown Trout
2431 OE010703 F WB Sucker
2432 DE010710 F WB Redhorse Sucker
2432 DE010713 F PF Walleye
2435 DE011001 f WB Longnose Sucker
2435 DE011004 PF Brook Trout
2437 DE011202 PF Walleye
2437 DE011203 WB Carp
2439 DE011401 WB Carp
2439 OE01K02 WP SM Bass
2478 DJ003901 BF Sucker
2478 OJ003902 WB Sucker
2500 DC010201 PF Bass
2500 OC010203 WB Black Buffalo
2532 DF019302 PF LM Bass
2532 DF019303 WB Carp
2544 DF019202 WB Blacktail Redhorse
2608 DE014501 PF Walleye
2608 DE014504 WB Carp
2618 DE015401 F WB Carp
2618 OE015402 F BF Carp
2618 DE015403 F WB Ouillback
2618 00102088 L WB Quillbeck
2651 DB008401 F WB White Sucker
2378
TCOO
11.29
17.83
32.69
31.72
NO
4.2
ND
NO
23.72
0.44
3.74
3.92
0.54
0.33
0.42
5.56
ND
0.48
ND
NO
ND
1.70
ND
0.8
ND
ND
ND
ND
2.23
1.75
ND
ND
10.40
ND
0.82
6.00
ND
7.07
67.18
3.96
1.64
2.10
1,73
0.85
12378
PECOO
ND
ND
0.87
0.83
ND
5.9
ND
ND
ND
OR ND
ND
1.19
12.13
NO
ND
ND
ND
NO
ND
NO
0.47
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.64
ND
ND
2.37
3.87
1.44
1.82
1.72
ND
123478
HXCOO
1.85
3.26
ND
ND
ND
3.7
ND
ND
OR NO
OR ND
1.40
0.39
4.45
ND
NO
OR ND
ND
ND
ND
OR ND
ND
NO
ND
NO
NO
NO
HO
ND
1.66
NO
ND
HO
Oft ND
OR NO
ND
2.95
ND
ND
1.80
2.73
ND
ND
0.54
NO
123678
HXCOO
ND
27.84
0.62
0.83
HO
11.8
NO
NO
OR 25
OR NO
9.47
3.54
19.32
NO
HO
OR 14
ND
ND
ND
Oft ND
ND
0.51
NO
NO
ND
ND
ND
NO
9.42
1.58
NO
NO
OR ND
OR NO
0.56
6.57
ND
NO
6.11
12.95
4.76
3.11
3.13
ND
DIOX1N
123789
HXCDD
NO
NO
ND
HO
ND
2.8
NO
NO
OR NO
OR NO
ND
0.30
2.67
NO
ND
OR ND
ND
NO
ND
OK NO
ND
ND
ND
ND
ND
ND
NO
ND
2.83
ND
ND
ND
OR NO
OR ND
ND
0.91
NO
ND
0.86
1.48
NO
ND
ND
ND
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
OR 29
OR 37
2.03
1.85
3.39
27.1
1.34
ND
OR NO
OR ND
OR 8
10.67
31.31
0.35
0.38
OR 25
ND
0.88
ND
OR ND
ND
1.42
ND
ND
ND
1.8
1.4
OR 4
OR 21
3.42
4.66
OR ND
OR 1
OR ND
2.14
20.34
0.35
0.43
18.10
22.49
8.50
9.37
9.46
OR ND
TCDF
5.51
6.81
75.29
74.70
1.36
8.0
0.89
ND
14.15
1.00
4.07
8.80
34.95
5.76
5.93
5.66
2.49
2.59
ND
0.80
3.60
0.93
0.6
2.0
4.4
ND
0.4
ND
2.32
2.97
ND
HO
1.07
ND
NO
9.81
0.90
7.72
35.27
9.18
2.79
8.33
8.43
2.19
12378
PECOF
1.74
4.47
0.71
0.68
ND
1.6
ND
NO
9.13
ND
1.87
0.63
9.08
ND
0.18
ND
ND
NO
ND
ND
0.41
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
NO
ND
ND
ND
4.07
ND
ND
2.66
1.70
ND
0.84
0.86
ND
P9/9
23478
PECDF
6.43
15.19
2.00
1.95
0.24
5.6
ND
ND
29.78
ND
10.11
1.47
20.14
ND
ND
0.51
ND
ND
ND
ND
0.56
ND
ND
ND
1.3
NO
ND
NO
3.27
1.36
ND
NO
ND
ND
ND
6.41
ND
0.15
3.65
5.05
1.81
2.25
2.37
NO
123478
HXCOF*
9.07
ND
2.30
1.90
NO
1.3
ND
NO
34.26
OR ND
1.85
1.40
5.60
0.40
0.50
OR ND
HD
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
4.53
2.01
ND
OR HD
ND
ND
0.40
4.91
ND
ND
2.98
1.14
0.33
NO
ND
NO
123678
HKCOF
ND
ND
ND
NO
ND
2.7
ND
NO
5.68
OR NO
1.03
0.99
4.84
ND
ND
OR ND
HD
ND
ND
ND
ND
ND
NO
ND
NO
HO
HO
NO
0.58
NO
NO
OR NO
ND
HD
HO
3.18
HO
ND
ND
1.61
0.62
ND
ND
ND
123789
HXCDF
ND
NO
NO
NO
ND
NO
ND
NO
HO
OR HO
NO
NO
HO
NO
NO
OR HO
HD
HO
HD
HO
HD
HO
HD
HO
ND
HO
HO
HO
HO
HO
HO
OR HO
HO
HO
HO
HO
HO
HO
HD
HD
MO
HO
HD
ND
234678
HXCOF
3.89
7.80
HD
NO
NO
0.9
ND
NO
6.42
OR ND
NO
1.01
2.59
ND
NO
OR ND
ND
NO
ND
NO
NO
ND
ND
NO
MO
ND
NO
NO
ND
1.82
NO
OR ND
ND
ND
NO
1.45
ND
ND
1.18
ND
MO
ND
ND
NO
1234678 1234789 DPE
HPCOF
OR 13
OR 16
1.10
0.86
0.30
1.7
NO
NO
cm HD
Oft NO
OR ND
2.84
4.23
0.23
ND
OR 11
ND
ND
ND
OR ND
ND
0.40
ND
ND
ND
ND
ND
OR ND
OR 6
2.85
ND
OR ND
OR ND
OR ND
ND
3.99
0.18
0.20
2.33
1.51
0.5J
0.89
0.95
OR ND
HPCOF
OR ND
OR ND
ND
ND
NO
ND
ND
ND
Off ND
OR ND
OR ND
ND
NO
ND
ND
OR ND
HO
ND
ND
OR HD
ND
ND
ND
ND
HD
ND
ND
OR HD
OR ND
ND
ND
OR HO
OR ND
OR ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
OR ND
TEC
16.62
30.22
42.01
40.91
0.29
13.44
0.10
NO
45.12
0.54
10.67
7.06
32.93
0.95
1.08
6.38
0.25
0.75
HD
0.08
0.90
1.86
0.06
1.00
1.09
0.02
0.05
HD
6.00
3.33
0.05
ND
10.51
HD
0.94
13.95
0.10
7.92
75.35
11.65
4.21
5.42
5.13
1.07
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
1
Y
Y
Y
Y
Y
Y
Y
Y
Y
D-4-8
-------
Episode SCC Type Description
2653 OB008503 F UB Carp
2654 DB008601 F UB Carp
2709 DB005101 F UB Catfish
2721 DA006502 F UB Sucker
2722 OA006601 F UB Sucker
2725 OA006301 F UB Sucker
2748 OY006505 F UB Sucker
2748 DY006506 F BF not available
2776 DY007101 F UB Carp
2776 DY007103 F PF Trout
3001 DE019501
3001 DE019502
3022 DA008401
3022 DA008402
3023 DA008S01
3024 DA008601
3025 DA008701
3025 OA008702
3026 DA009001
3026 DA009002
3027 DA009301
3028 DA008801
3028 00031787
3034 DG025701
3034 DG025702
3035 DG025801
3035 OG025802
3036 DG025901
3036 DG025902
PF Ualleye
UB Unite Sucker
UB White Sucker
PF Chain Pickerel
PF Sn Bass
PF LIB Bass
WB White Sucker
PF Chain Pickerel
UB Catfish
PF Lm Bass
UB Sucker
PF Chain Pickerel
PF Chain Pickerel
UB Carp
PF Lm Bass
UB Carp
PF Sm Bass
PF Freshwater Drum
UB Carp
3036 00120287 L PF Freshwater Drum
3037 DG026001 F UB Carp
3037 DG026002 F PF Black Crappie
3038 DG026101 F UB Carp
3038 DG026102 F BF Channel Catfish
3039 OG026201 UB Carp
3039 DG026202 BF Channel Catfish
3040 DG026301 UB Carp
3040 DG026302 PF White Crappie
3041 DG026401 BF Channel Catfish
3041 DG026402 UB Carp
3041 00031588 BF Channel Catfish
3042 DG026501 UB Carp
3042 DG026502 PF Northern Pike
3043 DG026601 UB Carp
2378
TCDO
2.82
ND
ND
40.96
ND
16.08
ND
ND
ND
ND
ND
ND
0.37
ND
ND
ND
1.57
ND
23.11
2.88
ND
ND
ND
1.17
ND
1.76
ND
NO
ND
ND
0.39
ND
2.90
0.63
1.54
ND
3.02
ND
ND
ND
0.44
ND
ND
0.47
12378
PECDD
1.08
ND
ND
2.45
ND
2.02
ND
ND
ND
ND
ND
ND
0.54
ND
ND
ND
1.33
ND
2.27
0.21
NO
ND
NO
0.66
ND
2.29
NO
ND
0.39
ND
0.38
NO
1.68
NO
1.95
ND
4.67
ND
0.72
ND
0.62
1.62
NO
ND
123478
HXCDD
0.78
ND
OR ND
NO
OR ND
ND
ND
ND
ND
ND
OR ND
ND
0.21
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
0.65
ND
1.11
NO
ND
ND
ND
ND
ND
1.00
ND
0.84
ND
6.71
NO
ND
0.21
0.47
0.63
ND
ND
123678
HXCDD
2.04
ND
OR ND
8.43
OR ND
9.54
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
10.76
ND
8.96
ND
ND
ND
ND
1.69
ND
2.33
ND
ND
0.69
NO
0.57
ND
3.21
1.22
3.86
0.88
8.78
NO
0.93
0.38
0.85
4.20
ND
1.32
DIOXIN
123789
HXCDD
ND
ND
OR ND
0.71
OR NO
0.89
ND
ND
ND
ND
OR NO
ND
ND
NO
ND
ND
ND
ND
0.83
ND
NO
ND
ND
0.49
ND
ND
NO
ND
0.22
ND
ND
ND
0.72
0.32
0.86
ND
3.13
ND
0.17
ND
0.18
0.95
ND
ND
/ FURAN CONCENTRATIONS,
1234678 2378 12378
HPCDD
7.17
ND
OR 5
4.49
OR ND
4.72
ND
OR 2
ND
ND
OR ND
OR ND
0.72
OR ND
0.23
OR ND
OR 20
0.98
2.39
0.28
OR ND
OR ND
ND
6.40
ND
4.41
OR ND
ND
2.66
ND
1.25
ND
11.09
1.81
U.05
2.13
55.10
0.50
1.46
1.71
1.52
OR 10
0.20
OR 3
TCDF
1.16
0.36
3.41
207.49
NO
106.82
ND
ND
ND
ND
ND
ND
6.21
NO
0.30
0.90
0.85
ND
8.25
6.05
1.93
ND
ND
10.60
0.30
1.94
ND
ND
0.38
ND
1.10
ND
1.78
ND
1.46
ND
0.71
NO
ND
0.26
0.21
1.07
ND
0.45
PECDF
0.43
ND
ND
4.87
ND
5.11
ND
NO
ND
NO
ND
ND
0.62
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
1.08
ND
0.39
ND
ND
ND
ND
ND
ND
0.50
ND
0.52
ND
ND
NO
ND
ND
ND
0.35
ND
ND
P9/9
23478
PECOF
2.36
ND
4.03
6.15
ND
6.19
NO
ND
ND
ND
ND
ND
1.36
ND
ND
NO
ND
ND
6.24
0.20
ND
ND
ND
1.28
ND
1.16
ND
ND
ND
ND
ND
ND
1.13
0.27
1.36
ND
0.66
ND
ND
ND
0.36
0.70
ND
ND
123478
HXCDF*
1.40
ND
OR ND
1.51
OR ND
1.58
ND
ND
NO
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
0.76
NO
OR ND
NO
NO
0.42
NO
1.60
ND
ND
ND
ND
0.40
ND
1.30
NO
0.51
ND
0.91
NO
0.13
ND
0.29
0.45
ND
0.38
123678
HXCOF
ND
ND
OR ND
NO
OR ND
0.50
ND
NO
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.62
ND
0.76
ND
0.52
ND
ND
ND
ND
0.37
ND
NO
123789
HXCDF
ND
ND
OR NO
ND
OR ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
OR ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
1.27
ND
OR ND
ND
OR ND
0.33
ND
ND
ND
ND
OR ND
NO
ND
ND
ND
NO
5.27
ND
0.29
NO
OR ND
ND
ND
0.73
ND
1.00
ND
ND
ND
ND
ND
ND
0.97
ND
0.29
ND
0.76
NO
ND
ND
0.26
ND
NO
0.25
1234678 1234789
HPCDF
1.70
ND
OR NO
2.05
OR ND
2.48
ND
OR ND
NO
ND
OR ND
OR ND
0.15
OR ND
ND
OR ND
OR 8
ND
0.94
ND
OR ND
OR ND
ND
3.11
ND
1.07
OR ND
ND
ND
ND
0.34
ND
1.70
0.39
1.25
ND
1.36
ND
0.31
0.18
0.33
OR 1
ND
OR ND
HPCOF
NO
ND
OR ND
ND
OR NO
ND
ND
OR ND
NO
ND
OR ND
OR ND
ND
OR ND
ND
OR HD
OR ND
ND
ND
ND
OR ND
OR ND
ND
ND
NO
ND
OR ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
OR ND
ND
OR ND
OPE
TEC
5.32
0.04
2.36
67.38
ND
32.48
ND
ND
NO
ND
ND
NO
2.00
ND
0.03
0.09
3.92
0.01
29.31
3.69
0.19
ND
ND
3.75
0.03
4.36
NO
ND
0.35
ND
0.80
NO
5.42
0.94
4.23
0.11
8.40
NO
0.50
0.10
1.17
1.94
ND
0.71
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
D-4-9
-------
Episode SCC Type Description
3043 DG026602 F PF Flathead Catfish
3043 00111987 L PF Flathead Catfish
3044 OG026701
3044 DG026702
3045 DG026801
3045 DG026802
3046 DG026901
3047 DG027001
3047 DG027002
3048 DG027101
3048 DG027102
3049 DG027201
3049 DG027202
F we Carp
F PF Flathead Catfish
F UB Carp
F PF Flathead Catfish
F UB Bigmouth Buffalo
F UB Carp
F PF Si* Bass
F UB Carp
F PF White Bass
F UB Carp
F PF Crappie
3049 00111087 L PF Crappie
3050 DG027301
3060 DF009101
3060 DF009102
3061 DF019105
3061 DF019106
3062 DF024024
3062 DF024324
3062 00024324
3062 OD071587 L
F UB Bigmouth Buffalo
F UB Flathead Catfish
F UB Sm Buffalo
F PF Bass
F UB Sucker
F UB Blue Catfish
F BF Grass Carp
L BF Grass Carp
UB Blue Catfish
3062 SF024324 F BF Grass Carp
3063 OF023301 F UB Sea Catfish
3063 DF023302 F PF Spotted Seatrout
3064 DF023305 H Shellfish
3064 OF023306 F PF Spotted Seatrout
3065 DF023419 F BF Bigmouth Buffalo
3065 DF023420 F UB Flathead Catfish
3065 OD022588 L UB Flathead Catfish
3066 DF023503 F UB Catfish
3066 DF023504 F PF Freshwater Drum
Oysters
3068 DF024001 M
3068 DF024002
3069 DF024007
3069 DF024008
3070 DF024009
3070 DF024010
3071 DF024014
3072 DF024017
3072 OF024018
F PF AtI. Croaker
F UB Sea Catfish
F PF Trout
F UB Croaker
F PF Sheepshead
F UB Carp
F UB Carp
F PF White Bass
3072 00040788 L PF White Bass
3073 DF019221 F UB White Sucker
2378
TCOO
0.31
0.27
0.82
0.23
2.40
ND
0.66
1.29
ND
2.69
ND
7.49
ND
ND
0.92
ND
1.21
0.62
ND
33.86
8.85
9.H
32.36
8.99
1.50
ND
ND
ND
1.83
1.78
1.79
4.62
ND
6.70
ND
0.72
ND
ND
0.69
1.07
ND
ND
ND
0.30
12378
PECDD
0.21
NO
1.09
NO
ND
0.42
ND
1.46
ND
3.96
ND
2.80
ND
ND
NO
ND
ND
1.13
3.68
1.21
ND
ND
1.17
ND
1.57
ND
ND
ND
0.53
0.66
0.67
ND
ND
ND
ND
0.81
ND
ND
ND
0.69
ND
ND
ND
NO
123478
HXCOO
ND
ND
0.68
ND
OR ND
ND
ND
1.14
ND
2.26
ND
1.79
ND
ND
0.40
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
0.29
0.44
0.71
ND
ND
ND
ND
ND
ND
0.19
ND
ND
ND
ND
ND
123678
HXCDD
0.39
0.24
ND
0.58
OR 4
1.26
0.39
2.92
ND
12.37
ND
5.55
NO
ND
0.54
NO
ND
1.98
7.94
1.28
ND
ND
1.50
ND
1.65
ND
0.26
ND
0.86
0.57
0.50
2.43
ND
ND
0.49
0.82
ND
0.59
ND
2.09
NO
ND
ND
0.45
DIOXIN
123789
HXCOO
ND
ND
0.34
ND
OR ND
ND
ND
ND
ND
ND
ND
1.09
NO
ND
ND
ND
ND
1.29
ND
ND
ND
ND
ND
ND
0.46
ND
ND
ND
0.30
ND
ND
0.77
ND
ND
ND
ND
ND
0.33
NO
ND
NO
ND
ND
ND
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
1.07
0.56
7.76
2.03
OR 15
2.73
2.44
10.76
0.32
OR 29
OR ND
25.93
NO
ND
2.69
OR ND
OR ND
5.22
OR 15
3.84
2.51
2.71
3.72
1.96
3.70
ND
3.45
1.46
2.50
2.03
1.97
11.11
0.85
0.89
NO
1.80
0.21
2.46
1.44
4.95
0.54
0.25
0.25
0.94
TCDF
0.15
ND
0.89
ND
ND
ND
0.85
3.10
ND
4.66
0.51
2.44
0.16
ND
3.15
ND
4.20
ND
ND
32.07
69.82
69.29
33.8
71.92
1.20
1.51
0.47
ND
0.18
5.09
4.93
4.58
0.28
14.13
1.38
ND
ND
0.71
0.31
3.11
0.52
0.26
0.30
1.46
12378
PECDF
ND
ND
0.29
ND
0.27
ND
NO
0.64
ND
ND
ND
ND
ND
NO
0.29
ND
ND
NO
0.27
0.64
ND
0.30
0.61
ND
1.09
2.52
ND
ND
ND
0.69
0.72
1.31
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
P9/9
23478
PECOF
ND
ND
0.47
0.18
ND
ND
ND
0.92
ND
2.46
ND
2.20
ND
ND
ND
ND
0.48
NO
ND
3.57
0.78
0.57
ND
0.50
5.73
ND
ND
ND
0.66
1.06
0.99
3.09
ND
ND
ND
1.07
ND
ND
ND
1.56
ND
ND
ND
0.14
123478
HXCOF*
0.40
ND
1.30
NO
OR 1
ND
ND
0.85
ND
1.65
ND
2.65
ND
ND
NO
ND
ND
0.27
ND
1.06
ND
NO
1.14
ND
3.52
2.00
ND
ND
ND
0.53
0.62
2.05
ND
ND
ND
ND
ND
ND
ND
0.42
ND
ND
NO
ND
123678
HXCOF
NO
ND
NO
ND
OR ND
ND
NO
ND
NO
NO
NO
NO
ND
NO
NO
ND
ND
NO
ND
NO
ND
ND
ND
NO
0.31
0.32
NO
ND
NO
NO
NO
0.73
ND
ND
NO
NO
ND
ND
ND
0.51
ND
ND
NO
ND
123789
HXCDF
ND
ND
ND
ND
OR ND
NO
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
HO
NO
ND
ND
ND
234678
HXCDF
NO
ND
ND
NO
OR 0
NO
ND
0.37
ND
ND
NO
1.86
NO
NO
1.44
NO
ND
ND
0.42
NO
ND
NO
HO
ND
ND
NO
ND
ND
ND
0.22
ND
0.74
ND
ND
ND
NO
ND
NO
ND
0.25
ND
NO
ND
NO
1234678 1234789 OPE
HPCDF
0.68
NO
1.18
0.34
OR NO
NO
ND
1.02
NO
OR NO
OR ND
3.34
ND
ND
1.71
OR ND
OR ND
0.23
OR 1
NO
HO
NO
0.40
NO
4.09
2.41
0.35
0.18
0.27
0.33
0.36
1.35
ND
NO
HO
0.21
ND
0.17
0.55
0.55
ND
NO
ND
0.20
HPCDF
ND
ND
ND
ND
OR ND
NO
NO
NO
ND
OR ND
OR ND
NO
NO
NO
ND
OR ND
OR ND
ND
OR ND
HO
NO
ND
ND
ND
HD
ND
ND
ND
NO
ND
HO
HD
ND
NO
ND
NO
ND
NO
HD
ND
HD
HO
ND
ND
TEC
0.53
0.30
2.02
0.40
2.41
0.36
0.81
3.47
NO
7.99
0.05
11.82
0.02
HD
1.53
HD
1.87
1.59
2.69
39.76
16.25
16.40
36.66
16.24
6.00
0.53
0.11
0.02
2.59
3.38
3.33
7.56
0.04
8.12
0.19
1.76
NO
0.19
0.76
2.89
0.06
0.03
0.03
0.57
y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
D-4-10
-------
Episode SCC Type Description
3073 DF019222
3073 00121587
3074 DF026017
3075 DF024102
3076 DF028502
3076 DF028503
3077 DF019113
3077 DF019114
3077 00121087
3078 DF009118
3078 DF023815
3078 DF023816
3078 SF009118
3079 DF019205
3079 DF019206
3080 DF023317
3080 DF023318
3080 00040987
3081 DF024105
3081 DF024106
3082 DF023401
3082 OF023402
3082 00120787
3083 DF023405
3083 DF023406
3084 DF024109
3084 OD072188
3085 DF024113
3085 DF024114
3085 SF024113
3086 DF023409
3086 DF023411
3087 DF023413
3087 DF023414
3087 DF023415
3087 DF023416
3087 00023414
3087 00072387
3087 SF023414
3087 SF023415
3088 DF023417
3088 DF023418
3089 DF019209
3089 DF019210
PF Sm Bass
WB White Sucker
F PF Brown Trout
F BF Sea Catfish
F WB Channel Catfish
F PF Spotted Bass
F PF Flathead Catfish
F WB Redhorse Sucker
L PF Flathead Catfish
F WB Carp
F WB Sm Buffalo
F PF Black Crappie
F WB Carp
F PF White Bass
F WB Carp
F WB Carp
F PF Lm Bass
L WB Carp
F PF White Bass
F WB Catfish
F WB Carp
F PF Lm Bass
L PF Lm Bass
F WB Black Bullhead
F PF Lm Bass
F WB Channel Catfish
L WB Channel Catfish
F WB Sea Catfish
F PF Black Drum
F WB Sea Catfish
F WB Catfish
F PF Black Drum
F WB Carp
F PF White Crappie
F WP Bluegill
F WP Lm Bass
L PF White Crappie
L WB Carp
PF White Crappie
WP Bluegill
WB Channel Catfish
PF Bluegill
PF White Crappie
WB Carp
2378
TCOO
NO
0.30
NO
NO
0.39
NO
NO
ND
NO
17.91
203.64
23.10
15.41
ND
0.34
3.62
1.03
3.35
0.94
2.45
ND
ND
ND
ND
ND
1.28
1.07
2.58
0.66
2.73
ND
NO
117.89
13.11
66.70
20.22
16.79
114.34
14.30
73.98
13.69
1.4
ND
ND
12378
PECOD
ND
0.25
OR ND
ND
0.63
ND
ND
ND
ND
3.35
12.62
ND
3.07
ND
ND
2.64
ND
3.31
ND
NO
1.02
ND
NO
0.80
ND
0.96
0.86
6.82
NO
8.01
2.99
ND
7.24
0.79
1.93
ND
1.21
7.28
1.00
1.91
ND
ND
ND
ND
123478
HXCDD
ND
0.24
OR ND
ND
0.63
ND
ND
ND
ND
2.43
1.50
ND
2.00
ND
ND
1.92
ND
2.18
ND
1.44
ND
ND
NO
0.49
ND
ND
ND
3.73
ND
4.38
0.82
ND
ND
ND
ND
ND
ND
1.94
ND
ND
ND
NO
ND
ND
123678
HXCOD
NO
0.46
OR ND
ND
1.47
ND
ND
ND
ND
5.13
2.46
ND
3.08
NO
0.52
4.88
0.25
6.58
0.47
2.20
2.52
NO
ND
0.91
NO
NO
0.94
10.50
1.77
11.85
2.47
ND
5.88
ND
1.92
ND
0.50
6.38
ND
1.24
1.25
NO
ND
0.4
D10X1N
123789
HXCDD
ND
ND
OR ND
ND
ND
ND
ND
ND
NO
1.51
0.49
ND
0.73
ND
ND
1.87
ND
2.14
NO
0.88
0.40
ND
ND
0.40
ND
ND
0.31
2.18
ND
2.51
ND
ND
2.11
ND
ND
ND
NO
ND
ND
ND
0.57
ND
NO
NO
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
0.19
1.11
OR NO
0.51
2.01
0.35
0.47
0.75
0.89
27.86
6.07
2.14
25.96
0.37
1.46
23.95
ND
29.65
1.56
7.86
12.89
1.44
0.37
10.74
ND
1.83
1.59
9.41
1.06
11.05
3.72
ND
12.33
ND
ND
2.82
0.94
12.33
0.46
1.24
4.92
0.5
ND
1.4
TCDF
0.33
1.27
ND
ND
0.24
ND
ND
ND
ND
8.87
21.23
12.41
7.23
1.08
0.61
4.89
ND
6.95
0.80
ND
3.83
0.97
0.99
0.32
ND
0.51
0.53
4.62
14.77
5.15
4.04
0.32
261 .34
81.40
71.94
8.74
110.71
253.01
107.66
68.81
7.65
2.2
0.40
1.4
12378
PECDF
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
1.51
ND
0.44
ND
0.14
ND
ND
0.32
ND
ND
0.88
ND
ND
ND
ND
ND
0.33
7.59
20.30
8.75
2.60
0.25
8.80
1.65
2.09
ND
2.28
8.74
1.67
1.73
ND
ND
ND
ND
P9/9
23478
PECDF
ND
NO
ND
ND
0.44
ND
ND
ND
ND
1.05
0.70
ND
0.91
0.20
0.32
0.47
ND
0.75
ND
0.26
ND
ND
ND
0.15
ND
1.01
0.92
45.51
11.25
56.85
33.25
ND
17.24
2.46
1.59
2.09
3.21
18.36
1.92
1.40
ND
ND
ND
0.3
123478
HXCDF*
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
0.41
ND
NO
ND
0.30
0.38
ND
0.54
ND
ND
0.40
NO
ND
ND
ND
ND
0.18
11.92
6.65
13.74
19.98
ND
0.40
ND
ND
ND
HO
ND
ND
ND
ND
ND
ND
ND
123678
HXCDF
ND
ND
OR ND
ND
ND
ND
ND
HO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
16.21
8.19
20.67
ND
NO
1.49
ND
ND
ND
ND
1.60
ND
NO
ND
ND
NO
ND
123789
HXCDF
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
NO
ND
0.96
NO
1.41
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
OR ND
ND
0.61
ND
ND
ND
NO
ND
ND
NO
ND
ND
0.18
0.38
ND
0.49
ND
ND
ND
NO
NO
NO
ND
ND
ND
5.29
1.08
7.01
2.48
NO
0.54
ND
ND
ND
ND
0.53
ND
ND
ND
ND
ND
ND
1234678 1234789 DPE
HPCOF
ND
ND
OR ND
ND
0.58
0.18
ND
ND
ND
0.23
ND
ND
ND
NO
0.27
0.59
ND
1.22
ND
0.23
1.16
ND
0.18
NO
ND
ND
0.21
8.20
1.45
8.95
25.66
ND
ND
ND
NO
ND
ND
0.75
ND
NO
ND
ND
ND
0.2
HPCOF
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.26
0.19
1.49
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
TEC
0.03
0.63
ND
0.01
1.25
0.01
ND
0.01
0.01
22.18
213.05
24.36
18.06
0.21
0.69
6.85
1.05
7.59
1.08
3.11
1.41
0.11
0.10
0.79
NO
2.33
2.19
34.85
10.57
15.01
21.52
0.04
157.87
22.98
75.95
22.17
30.24
154.07
25.93
82.18
14.69
1.63
0.04
0.35
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
D-4-ll
-------
Episode SCC Type Description
3090 DF019213 F PF White Crappie
3090 DF019214 F WB Channel Catfish
3091 DF019217 F WB River Carpsucker
3091 DF019218 F PF White Crappie
F WB Carp
F PF Warmouth
F PF Lm Bass
F UB Si* Buffalo
L WB Sm Buffalo
F BF Channel Catfish
L BF Channel Catfish
F BF Brown Bullhead
F WB Channel Catfish
F BF Brown Bullhead
F WB Channel Catfish
L WB Channel Catfish
F BF Broun Bullhead
F WB Carp
F WB White Sucker
F PF American Eel
L WB White Sucker
F PF White Perch
F WP Winter Flounder
F PF Brown Trout
F WB Channel Catfish
F WB Carp
F PF Lm Bass
F WB Carp
F WB Carp
F PF Lm Bass
F PF Walleye
F PF White Bass
F WB Carp
F PF Walleye
F WB Carp
F WB Carp
F PF Sm Bass
F BF Carp
3092 DF023501
3092 DF023502
3093 DF024011
3093 OF024118
3093 00080387
3094 DC017201
3094 00092988
3095 DC038801
3095 DC038802
3096 DC035001
3096 DC035002
3096 00052488
3097 DC038701
3097 DC038702
3098 DC038601
3098 DC038602
3098 00032587
3100 DC019701
3100 DC019702
3101 OC019901
3103 DC036201
3103 DC036202
3104 DC020001
3104 DC020002
3105 DF025001
3105 DF02S002
3106 OE026801
3106 OE026802
3107 DE026901
3108 DE027001
3108 DE027002
3109 DE025001
3109 DE025002
3110 DE022501
3111 DH015801
3111 DH015802
3112 DE022401
3112 OE022402
3113 DE021101
3113 DE021102
F PF Walleye
F WB Silver Redhorse
F WB Carp
F PF Walleye
F BF Channel Catfish
F BF Carp
2378
TCOD
NO
NO
ND
ND
2.11
NO
NO
0.41
ND
1.71
1.69
1.24
ND
0.53
4.62
4.53
0.81
1.42
24.89
3.32
24.02
NO
NO
ND
ND
0.96
ND
1.68
0.73
ND
7.02
17.52
ND
ND
2.68
0.50
0.35
ND
NO
ND
2.98
ND
ND
1.49
12378
PECDD
ND
0.36
NO
ND
6.99
ND
NO
0.70
0.68
2.16
2.08
1.23
ND
ND
5.33
4.84
ND
2.27
27.23
12.46
25.09
0.50
NO
ND
OR 2
NO
ND
ND
0.30
NO
NO
0.54
0.99
ND
2.09
0.42
ND
0.38
ND
ND
1.38
ND
0.77
1.73
123478
HXCDD
ND
ND
NO
ND
9.94
ND
NO
0.49
0.63
ND
ND
ND
NO
ND
ND
1.10
ND
NO
ND
ND
ND
NO
NO
ND
0.84
0.67
NO
1.01
ND
ND
ND
ND
ND
ND
ND
NO
ND
0.34
ND
ND
1.12
ND
ND
ND
123678
HXCDD
ND
0.55
ND
ND
14.18
ND
NO
1.90
1.45
2.16
2.50
1.67
4.72
0.43
5.32
4.95
ND
3.23
7.00
8.43
7.14
0.56
NO
ND
2.84
0.99
ND
2.19
ND
ND
0.25
ND
3.41
ND
14.39
0.74
ND
1.35
ND
1.48
2.79
ND
2.25
5.77
DtOXIN
123789
HXCDD
ND
NO
ND
ND
5.59
NO
ND
0.51
0.53
NO
0.33
NO
0.91
ND
ND
1.01
ND
0.88
6.80
3.21
5.90
ND
NO
NO
0.67
ND
ND
0.42
ND
ND
ND
ND
NO
ND
1.05
ND
ND
0.15
ND
ND
1.25
ND
ND
ND
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCOD
ND
2.04
0.49
ND
106.84
0.87
1.41
6.97
7.69
5.33
6.00
3.10
5.70
0.76
4.39
4.08
OR ND
NO
27.39
6.20
OR 26
1.31
1.26
ND
3.87
3.76
0.87
5.11
1.70
0.53
1.32
1.43
7.49
ND
42.22
1.21
ND
2.64
ND
ND
5.99
0.26
2.89
14.78
TCDF
0.71
0.39
ND
ND
0.41
ND
ND
ND
0.55
0.60
0.51
2.31
0.86
0.97
0.71
0.77
1.42
4.62
5.03
NO
5.18
3.70
2.91
5.49
ND
5.72
0.39
2.66
1.23
ND
8.22
26.57
2.66
0.36
2.73
ND
1.01
8.84
ND
1.42
5.50
1.01
0.94
3.60
12378
PECOF
ND
0.19
ND
ND
NO
ND
ND
ND
ND
NO
ND
1.35
0.77
ND
0.67
0.66
NO
2.96
ND
NO
ND
0.69
ND
1.85
0.29
0.76
ND
1.69
ND
ND
ND
0.96
0.35
ND
1.34
ND
ND
0.74
ND
ND
ND
ND
NO
2.03
w/g
23478
PECOF
ND
0.75
ND
ND
ND
ND
ND
ND
0.18
4.84
3.58
4.29
9.89
0.92
14.01
11.85
2.91
7.53
0.92
ND
0.99
2.43
1.12
5.92
3.06
1.90
ND
4.11
0.33
NO
ND
ND
1.55
ND
5.44
ND
ND
1.41
ND
ND
ND
ND
1.39
3.04
123478
HXCDF*
ND
NO
ND
ND
ND
ND
ND
1.49
ND
0.24
0.24
0.49
2.26
ND
2.60
2.42
ND
2.92
ND
NO
ND
0.19
ND
ND
1.46
0.50
ND
0.71
0.30
ND
ND
ND
ND
ND
7.32
1.01
ND
1.44
ND
NO
ND
ND
ND
2.30
123678
HXCOF
ND
ND
ND
ND
ND
ND
ND
ND
NO
0.63
0.48
0.75
ND
ND
ND
1.51
ND
2.63
ND
ND
ND
ND
ND
ND
0.31
ND
NO
1.00
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
2.52
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
0.41
ND
ND
ND
NO
ND
ND
NO
0.44
ND
ND
ND
234678
HXCDF
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
0.23
0.30
ND
ND
1.49
1.24
ND
0.53
ND
0.88
1.39
NO
ND
ND
1.09
0.31
ND
0.38
ND
ND
ND
ND
2.77
ND
5.61
0.60
NO
0.36
ND
ND
ND
NO
ND
0.29
1234678 1234789 OPE
HPCOF
ND
ND
0.72
ND
2.31
ND
ND
ND
NO
0.53
0.47
0.26
ND
ND
ND
ND
OR ND
1.71
2.66
1.45
OR 3
NO
0.19
NO
0.92
0.42
NO
0.61
0.37
0.53
0.19
0.42
3.46
ND
13.16
0.94
ND
0.49
ND
ND
1.32
NO
ND
2.00
HPCOF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
0.39
ND
ND
ND
NO
ND
ND
ND
ND
ND
TEC
0.07
0.68
0.01
ND
9.71
0.01
0.01
1.27
0.82
5.63
5.01
4.65
5.92
1.14
15.38
14.25
2.41
7.97
41.15
10.88
39.02
1.96
0.87
3.60
2.31
2.81
0.05
4.71
1.22
0.01
7.88
20.51
2.32
0.04
10.18
0.97
0.45
2.21
NO
0.29
4.85
0.10
1.43
5.59
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
D-4-12
-------
Episode SCC
3114
3115
3115
3117
3117
3t18
3118
3118
3118
3119
3119
3120
3120
3122
3122
3122
3125
3125
3125
3132
3132
3134
3134
3134
3134
3135
3136
3137
3137
3138
3138
3140
3141
3141
3141
3142
3143
3143
3143
3144
3145
3145
3146
3146
DE021201
Type Description
! BF Carp
DE021301 F UB Carp
DE021302
: BF Catfish
DE021501 F PF Lake Trout
DE021502
c PF Brown Trout
OE021601 F PF Walleye
DE021602
' UB Carp
OE021603 F UB Carp
SE021602
F UB Carp
DE021701 F UB Carp
OE021702
F PF Lm Bass
OE021801 F UB Carp
DE021802 F PF Bass
DE022001 F UB Carp
DE022003 1
UB Redhorse Sucker
DE022004 F PF Sm Bass
DE022301 F UB Carp
OE022302 F PF White Bass
00120888 L PF White Bass
OE023201 F UB Carp
DE023202 F UB Channel Catfish
DE023401 F PF Crappie
DE023403 F UB Carp
DE023405 F UB Carp
DE023406 F UB Sucker
DE023501 F UB Carp
DE023602 F PF Uatleye
DE023701 F UB Redhorse Sucker
DE023702 F PF Walleye
DE023801
DE023802
OE024002
DE024102
DE024103
SE024102
DE022502
DE024401
DE024402
DE024403
DE024901
DE026601
00071988
DE026701
DE026702
UB Carp
PF Sm Bass
UB Carp
UB Carp
PF Northern Pike
UB Carp
UB Carp
Rotten (catf)
PF White Bass
UB Carp
UB Carp
UB N. Redhorse
UB N. Redhorse
UB Carp
PF Walleye
2378
TCOO
0.72
7.00
6.24
3.74
ND
1.37
11.61
3.85
9.39
ND
2.30
3.07
0.73
21.01
1.36
1.37
2.15
0.41
0.29
8.58
14.75
0.16
ND
1.99
0.59
1.22
ND
ND
ND
4.99
ND
1.50
20.31
1.70
16.79
2.72
ND
ND
0.91
1.25
0.86
0.7B
4.56
0.24
12378
PECOD
ND
1.84
0.91
8.76
2.35
NO
2.22
1.01
2.22
0.59
ND
ND
ND
6.22
ND
ND
1.43
ND
ND
2.19
2.48
ND
0.53
1.14
ND
ND
ND
ND
ND
OR 2
ND
ND
22.39
OR 1
17.14
5.68
ND
ND
2.58
0.51
ND
0.33
2.78
ND
123478
HXCDD
ND
ND
ND
ND
ND
ND
0.69
0.53
0.70
ND
ND
0.40
ND
0.96
ND
ND
1.04
ND
ND
0.64
ND
ND
ND
ND
ND
NO
ND
ND
ND
OR ND
ND
ND
ND
ND
3.98
2.34
ND
NO
0.73
ND
ND
ND
1.87
ND
123678
HXCDO
1.18
7.18
3.82
5.97
1.41
ND
2.87
1.30
2.37
1.63
ND
2.41
ND
10.13
ND
ND
2.53
ND
ND
5.41
12.20
ND
0.48
1.16
ND
1.25
ND
ND
ND
OR ND
0.31
1.77
18.52
0.87
17.26
8.14
ND
ND
4.74
ND
0.96
0.70
13.68
ND
DIOXIN
123789
HXCDD
ND
0.84
0.70
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.40
ND
ND
ND
ND
ND
0.92
2.68
ND
ND
ND
ND
ND
ND
NO
ND
OR ND
ND
ND
5.03
ND
3.54
0.90
NO
ND
0.96
ND
ND
ND
ND
ND
/ FURAN CONCENTRATIONS,
1234678 2378 12378
HPCDD
4.61
39.51
11.94
0.98
2.00
ND
4.42
3.51
3.32
3.64
ND
0.54
ND
14.86
OR ND
OR 0
8.19
2.03
1.30
OR 7
4.91
ND
1.83
3.20
0.58
3.67
ND
0.78
ND
OR ND
1.25
4.87
43.71
2.12
37.99
10.35
3.11
0.62
20.56
2.43
1.22
1.48
47.38
0.88
TCDF
4.64
4.11
0.87
43.70
9.55
5.55
14.64
7.53
12.46
0.89
2.35
3.34
2.08
16.91
8.80
3.95
23.36
7.87
7.36
5.63
6.13
0.90
6.71
1.75
32.60
3.99
ND
10.63
ND
4.30
1.80
1.28
2.91
OR 9
2.48
16.96
1.82
2.66
12.10
2.05
15.11
14.76
10.22
0.93
PECOF
0.55
0.66
ND
12.69
ND
ND
1.60
0.89
1.35
ND
ND
0.38
ND
ND
ND
ND
2.30
ND
NO
ND
ND
ND
1.61
0.76
1.29
ND
ND
ND
ND
OR 1
ND
ND
2.59
0.74
2.07
4.35
ND
0.45
2.74
0.38
0.22
ND
1.12
ND
P9/9
23478
PECDF
0.71
2.41
1.65
25.28
2.49
0.66
4.33
2.14
3.86
ND
ND
1.22
ND
14.30
0.20
ND
3.61
ND
0.46
6.09
3.27
ND
7.16
10.68
4.37
ND
ND
ND
ND
OR ND
0.40
1.08
20.21
1.94
15.68
14.85
ND
0.26
2.54
1.90
0.47
0.35
2.76
ND
123478
HXCDF*
ND
0.82
ND
2.44
ND
ND
ND
1.17
0.29
ND
ND
0.29
ND
4.06
ND
ND
1.49
ND
ND
2.12
2.50
ND
0.76
0.40
ND
ND
ND
ND
ND
OR ND
ND
ND
3.16
ND
3.02
1.65
ND
ND
1.20
ND
ND
ND
1.17
ND
123678
HXCDF
ND
ND
ND
4.14
ND
ND
0.65
0.44
0.40
ND
ND
ND
ND
1.49
ND
ND
1.18
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR NO
ND
ND
5.79
ND
3.81
2.38
ND
ND
ND
ND
ND
ND
1.76
ND
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
ND
1.26
ND
0.38
ND
ND
ND
0.20
ND
0.24
ND
1.97
ND
ND
ND
ND
ND
1.35
2.61
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
1.69
ND
1.65
0.80
ND
ND
1.07
ND
ND
ND
0.62
ND
1234678 1234789 DPE
HPCDF
ND
3.12
ND
ND
NO
ND
0.50
0.77
0.35
ND
ND
0.41
ND
1.71
OR ND
OR ND
0.82
ND
ND
1.01
2.52
ND
ND
ND
ND
0.64
ND
ND
ND
OR ND
ND
MD
5.26
0.16
4.31
0.95
ND
ND
4.19
ND
ND
ND
3.55
ND
HPCDF
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
OR ND
ND
ND
HD
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TEC
1.73
10.88
8.18
27.16
3.54
2.29
16.90
6.61
12.40
0.60
2.53
4.38
0.94
35.03
2.34
1.76
7.84
1.22
1.27
14.34
20.31
0.25
4.74
8.30
6.11
1.79
ND
1.07
ND
5.42
0.42
2.39
45.94
2.82
28.50
16.63
0.21
0.42
5.93
2.70
2.73
2.68
10.83
0.34
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
D+13
-------
Episode SCC Type Description
3146 OD060288 L UB Carp
3146 SE026701 F UB Carp
3147 DC035201 f UB Carp
3148 DE027101
3148 DE027103
3149 DC038501
3150 DA008901
3151 DA009101
3151 DA009102
3151 QD072887
3152 DA009201
3161 DC019801
3161 DC019802
3162 OJ022121
3162 DJ022122
3162 DJ022123
3162 DJ022403
3162 DJ024001
3162 DJ02S103 0
3162 OD041889 L
3163 OJ022402 N
3163 DJ022404 H
3163 DJ024002
3163 OJ025102 0
3164 DD015701 F
3164 DD01S702
3165 00015703
3165 DD015704
3165 00031788
3166 00015705
3166 00015706
3167 DD015707
3167 D0015708
F UB Carp
F PF Wat(eye
UB White Sucker
UB White Sucker
UB White Sucker
PF Sn Bass
WB White Sucker
WB White Sucker
BF Black Bullhead
UB White Sucker
WB Big Skate
UB Ratfish
Dungeness Crab
PF Quillback Rockfish
UP Starry Flounder
Hepatopancreas,Crab
Hepatopancreas
Dungeness Crab
Dungeness Crab
F UP Starry Flounder
Hepatopancreas.Crab
F PF Lm Bass
F UB Carp
F PF Ln Bass
F UB Redhorse Sucker
L PF Lm Bass
F PF Walleye
F UB White Sucker
F PF Lm Bass
F UP Bluegill
3167 OD040588 L PF Lm Bass
3167 SD015708 F UP Bluegill
3168 DD015711
3168 00015712
3168 SD015711
3169 DD015713
3170 00015715
F UB Carp
F PF Lm Bass
F UB Carp
F UB Black Redhorse
F UB Spotted Sucker
3171 D0015717 F UB Spotted Sucker
3172 00015719 F UB Carp
3172 00015720
3173 DD015721
F PF Lm Bass
F PF Lm Bass
2378
TCOD
5.02
4.31
2.49
3.46
NO
NO
13.51
7.87
0.89
8.20
7.82
ND
1.52
2.86
5.04
MO
ND
2.43
6.61
10.79
5.44
ND
1.51
5.67
ND
5.66
ND
1.53
0.48
ND
ND
2.22
7.3
2.83
6.72
8.84
2.30
7.88
ND
ND
ND
1.40
0.15
ND
12378
PECDD
3.44
2.92
0.52
2.42
ND
ND
12.01
2.89
ND
2.95
0.40
0.73
2.68
4.61
ND
ND
ND
4.72
10.17
15.90
6.43
0.94
1.21
6.10
OR ND
9.94
ND
5.07
ND
ND
ND
3.59
11.5
4.44
11.01
2.60
ND
2.56
ND
ND
ND
OR 1
ND
ND
123478
HXCDD
ND
2.53
ND
1.17
ND
OR ND
2.01
ND
ND
ND
ND
0.78
2.11
ND
ND
ND
ND
ND
3.46
4.89
ND
ND
ND
HO
ND
NO
ND
3.52
ND
ND
ND
ND
14.3
1.88
11.80
3.64
ND
3.85
OR ND
0.39
NO
1.63
ND
ND
123678
HXCDD
17.34
14.27
0.70
2.89
NO
OR ND
9.25
1.85
NO
2.15
3.20
1.50
3.13
6.59
2.17
ND
ND
9.58
26.28
34.02
27.72
2.22
2.30
17.82
1.93
24.87
2.92
12.40
3.09
ND
0.40
6.40
37.3
7.28
44.20
10.96
ND
9.51
OR ND
0.89
ND
3.09
ND
ND
D10XIN
123789
HXCDD
2.30
1.89
NO
0.62
ND
OR ND
3.92
1.19
NO
0.59
ND
0.25
0.38
ND
ND
ND
ND
0.66
5.10
6.67
ND
ND
ND
2.67
0.22
3.53
ND
ND
ND
ND
ND
ND
8.5
ND
7.87
1.35
ND
ND
OR ND
0.28
ND
0.86
ND
ND
/ FURAN
CONCENTRATIONS.
1234678 2378
HPCDD
49.70
47.34
2.96
5.59
0.57
ND
16.10
3.13
NO
3.25
0.50
2.14
8.54
5.41
ND
2.25
ND
3.48
37.12
48.32
15.99
1.79
1.11
15 .31
1.69
50.79
4.41
14.19
4.47
0.86
1.24
10.52
111.9
14.49
110.12
OR 39
0.45
34.26
OR ND
4.55
0.59
11.64
0.70
NO
TCOF
11.10
9.02
8.73
8.54
3.54
1.40
21.84
43.19
1.67
43.55
81.2
0.81
11.05
59.62
145.88
26.47
1.09
9.80
334.80
403.90
67.41
49.18
3.00
206.62
0.31
4.61
0.43
4.37
NO
NO
1.88
ND
ND
ND
0.34
14.62
4.90
13.94
2.30
0.84
0.49
9.69
1.37
ND
12378
PECOF
1.44
1.10
1.34
2.46
NO
ND
3.51
0.90
ND
0.98
4.09
0.40
1.40
22.62
9.81
10.81
ND
5.88
99.62
120.30
3.70
19.65
ND
68.55
OR ND
1.59
ND
0.84
ND
NO
NO
ND
1.3
ND
1.03
1.19
ND
0.85
ND
ND
ND
0.92
ND
ND
P9/9
23478
PECOF
2.50
2.67
2.05
4.27
0.43
ND
ND
1.87
0.22
2.01
4.35
1.13
3.45
19.21
18.12
3.23
ND
13.58
45.72
56.37
4.11
6.40
1.09
34.48
OR ND
4.14
0.33
3.04
0.30
ND
0.23
ND
ND
NO
0.79
2.10
ND
1.92
ND
ND
ND
ND
ND
ND
123478
HXCOF*
1.32
1.14
0.90
1.70
ND
OR ND
6.51
1.31
ND
1.09
1.30
ND
2.56
8.03
1.64
3.09
ND
5.36
37.49
45.33
2.28
5.80
0.19
19. TS
0.40
2.41
2.22
6.65
1.91
ND
ND
3.74
13.8
3.61
1.50
0.52
NO
0.33
OR ND
ND
ND
0.22
ND
ND
123678
HXCDF
2.65
2.25
ND
NO
NO
OR ND
ND
ND
ND
ND
ND
ND
0.91
4.90
ND
2.12
ND
2.22
27.93
30.86
2.16
ND
ND
13. tZ
ND
2.09
ND
NO
ND
NO
NO
1.21
7.0
NO
5.24
NO
ND
ND
OR ND
ND
ND
0.30
ND
ND
123789
HXCDF
ND
ND
ND
ND
ND
OR ND
0.51
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
NO
ND
NO
ND
ND
MO
ND
ND
NO
ND
ND
ND
ND
ND
NO
HD
NO
ND
ND
ND
OR ND
ND
HD
NO
ND
NO
234678
HXCDF
0.78
0.50
0.32
0.75
NO
OR HO
2.57
ND
NO
1.02
ND
NO
2.44
NO
NO
HD
ND
NO
3.35
3.71
ND
ND
ND
NO
0.33
NO
1.68
5.40
1.12
NO
NO
3.92
19.3
4.67
0.87
ND
ND
ND
OR NO
ND
HO
ND
NO
HO
1234678 1234789 OPE
HPCOF
3.79
3.11
ND
1.45
ND
NO
4.03
1.27
0.22
ND
HO
HD
3.55
ND
NO
ND
ND
0.93
10.86
13.91
3.71
NO
0.35
4.52
0.31
3.99
1.66
6.36
1.45
ND
ND
10.12
58.3
10.68
9.43
OR ND
ND
ND
OR ND
0.36
NO
0.23
NO
NO
HPCOF
ND
NO
ND
ND
ND
NO
0.49
NO
ND
ND
HD
ND
ND
HD
NO
ND
HD
HD
HD
HD
HD
HD
HO
NO
HD
ND
HO
HD
ND
HD
HO
HD
0.5
NO
0.94
OR ND
ND
ND
OR ND
ND
ND
ND
ND
NO
TEC
12.15
7.89
4.94
8.57
0.57
0.14
24.56
15.09
1.17
15.60
18.97
1.31
7.03
23.87
29.56
5.35
0.11
14.68
83.86
106.50
21.05
10.39
3.22
55.57
0.34
17.08
0.95
9.07
1.30
0.01
0.36
5.75
24.84
7.05
15.20
14.36
2.79
11.40
0.23
0.29
0.05
3.14
0.29
ND
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
D-4-14
-------
Episode SCC Type Description
3173 DD015722 F UB Channel Catfish
3173 00070689 L PF La Bass
3174 DD015723 F PF L* Bass
F UB Channel Catfish
3174 DD015724
3175 D0015801
3175 DD015802
3176 DD015803
3176 DD015804
F UB Channel Catfish
PF Lai Bass
F UB Spotted Sucker
F PF La Bass
3177 00015805 F UB Carp
3177 00015806 F PF L« Bass
3178 00015807 F UB North Hogsucker
3178 00015808 F PF Redeye Bass
3179 DD015809 F UB Golden Redhorse
3179 00015810 F PF LM Bass
F PF L* Bass
F PF La Bass
F UB Carp
F PF Rock Bass
F UB Carp
F UB Carp
F PF Sauger
F UB Carp
F PF White Crappie
F UB Channel Catfish
F PF L* Bass
F UB Channel Catfish
F PF Spot
F UP Southern Flounder
F UP Sumer Flounder
F UB Carp
F PF L* Bass
F UB Carp
PF L» Bass
3180 00015812
3181 00015813
3181 00015814
3182 00015815
3182 00015816
3183 00015817
3183 00015818
3184 00015819
3184 00015820
3185 DD015821
3185 DD015822
3185 SD015821
3186 DD015823
3186 00015824
3187 00015902
3188 00015903
3188 00015904
3189 00015905
3189 00015906
3190 00015907
3190 00015908
3191 DJ024003
F UB Carp
F PF L* Bass
F UP Starry Flounder
3191 DJ024005 N Soft Shell Cl<
3192 DJ024007 F UP Starry Flounder
3192 DJ024009 N
3192 00020789
3193 DC039001
3193 00039001
3195 DH020104
3195 DH020105
Soft Shell Cli
L Soft Shell Clt
F PF Striped Bass
L PF Striped Bass
F UB Carp
F UB Chub
2378
TCOO
1.39
NO
ND
ND
3.31
ND
ND
ND
ND
ND
ND
ND
0.31
ND
ND
ND
4.38
ND
ND
4.38
0.67
3.13
ND
4.14
1.50
3.97
ND
0.18
ND
ND
ND
ND
0.84
0.60
5.35
NO
ND
0.45
ND
ND
0.52
ND
ND
2.33
12378
PECOD
0.86
ND
ND
ND
3.82
ND
ND
ND
ND
ND
ND
ND
0.57
NO
ND
ND
2.69
ND
ND
0.93
ND
5.13
ND
12.27
1.81
12.09
ND
ND
ND
2.83
ND
0.76
ND
1.02
ND
ND
ND
ND
ND
ND
NO
ND
ND
0.98
123478
HXCDD
ND
ND
ND
ND
0.97
ND
ND
ND
0.70
ND
ND
ND
ND
ND
ND
NO
2.84
ND
ND
ND
ND
5.98
ND
7.94
0.81
9.37
ND
ND
ND
2.08
ND
OR .6
ND
1.13
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123678
HXCDD
1.69
ND
ND
ND
5.50
0.31
2.03
ND
1.74
ND
ND
ND
1.36
ND
ND
ND
13.37
0.51
ND
ND
ND
11.09
ND
50.77
8.74
51.84
ND
0.50
0.67
5.48
ND
OR .9
ND
2.56
ND
ND
ND
ND
ND
ND
0.48
ND
ND
0.76
DIOXIN
123789
HXCDD
0.32
ND
ND
ND
1.25
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.15
ND
ND
ND
ND
2.98
ND
9.49
0.99
8.96
NO
ND
0.34
0.77
ND
OR ND
ND
0.48
ND
ND
ND
ND
ND
ND
ND
MO
NO
ND
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
2.30
ND
ND
0.36
6.72
0.62
1.63
ND
7.14
0.75
0.74
ND
3.23
ND
ND
ND
54.47
0.92
3.23
7.76
0.59
53.19
ND
105.15
22.15
106.52
ND
1.47
3.06
11.49
ND
OR 4
ND
10.75
ND
0.5
1.70
0.69
2.35
2.10
2.28
2.82
1.79
2.24
TCDF
1.61
ND
ND
0.28
ND
ND
1.54
ND
1.24
NO
ND
NO
1.77
NO
NO
ND
3.23
8.63
23.53
3.05
ND
ND
ND
0.32
0.26
0.28
ND
0.23
ND
4.13
ND
1.24
ND
3.58
0.73
ND
1.90
9.06
12.97
13.18
15.86
19.28
ND
7.71
12378
PECDF
0.41
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
1.02
1.36
ND
ND
ND
ND
0.33
0.49
ND
ND
ND
1.18
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HO
ND
ND
P9/9
23478
PECDF
1.43
ND
ND
ND
0.65
ND
ND
ND
0.34
ND
ND
ND
ND
ND
ND
ND
4.49
ND
7.02
3.83
ND
ND
ND
ND
0.29
4.76
ND
ND
ND
2.79
ND
0.54
ND
0.80
ND
ND
ND
0.23
ND
ND
0.80
1.02
NO
0.73
123478
HXCDF*
ND
ND
ND
ND
1.88
ND
ND
ND
ND
ND
ND
ND
1.18
ND
ND
ND
4.17
ND
ND
2.47
ND
1.79
ND
16.45
0.72
2.70
ND
ND
ND
1.50
ND
OR .8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
123678
HXCDF
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
HD
ND
ND
ND
ND
ND
1.94
ND
ND
0.95
ND
ND
ND
2.96
0.68
2.67
ND
ND
ND
1.12
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123789
HXCDF
ND
HD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HD
ND
ND
HD
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
OR ND
ND
ND
ND
HD
NO
ND
ND
HD
HD
HO
ND
NO
234678
HXCDF
ND
ND
ND
ND
0.79
ND
ND
ND
0.92
ND
ND
ND
1.25
ND
ND
ND
2.29
ND
ND
0.57
ND
0.81
ND
11.85
ND
1.14
ND
ND
ND
0.80
HD
OR .6
HD
0.90
HD
HD
ND
ND
ND
ND
ND
ND
NO
ND
1234678 1234789 OPE
HPCDF
0.25
ND
ND
ND
2.73
ND
ND
HD
1.31
ND
0.27
ND
1.25
ND
NO
ND
4.51
ND
ND
1.40
ND
1.53
ND
29.41
1.98
7.76
ND
ND
ND
1.27
ND
0.78
ND
1.66
ND
ND
0.29
0.56
0.49
0.38
ND
NO
0.25
0.24
HPCDF
ND
ND
HD
HD
HD
ND
ND
ND
HD
HD
HD
HD
HD
HD
HD
HD
HD
HD
NO
ND
HD
HD
HD
HO
HD
0.69
HD
ND
ND
ND
HD
HD
HD
HD
HD
HD
HD
ND
ND
ND
ND
ND
ND
ND
TEC
2.94
ND
HD
0.03
6.68
0.04
0.37
HD
0.71
0.01
0.01
HD
1.20
HD
HD
ND
11.56
0.92
5.95
7.62
0.68
8.51
ND
21.60
4.03
13.56
ND
0.27
0.13
4.58
ND
0.78
0.84
2.50
5.42
HD
0.21
1.48
1.33
1.34
2.58
2.47
0.02
4.06
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
D-4-15
-------
Episode SCC Type Description
3196 DH020108 F UB Sucker
3197 DH020110 F UB Sucker
3198 DH020111 F UB Sucker
3199 DH020101 F UB Carp
3199 DH020103 F UB Carp
3200 OHOZ0112 f UB Sucker
3201 DJ024012 F UB Carp
3203 DJ024018 F UB Carp
3205 DJ024024 H Crayfish (whole)
3206 DJ022301 H Crayfish
3206 OJ024102 F Pf Lm Bass
3206 DJ024103 F UB Sucker
3208 DJ024109 F UB Sucker
3212 DJ024121 F UB Carp
3212 00050388 L UB Carp
3216 OJ023707 F PF Squawfish
3216 DJ023708 F UB Sucker
3216 00091688 L UB Sucker
3217 DJ023709 PF Uhitefish
3217 DJ023710 UB Sucker
3218 DJ023711 PF Squawfish
3218 OJ023712 UB Sucker
3219 DJ023713 UB White Sturgeon
3219 OJ0237U PF White Sturgeon
3220 DJ023902 PF Squawfish
3220 DJ023903 UB Bridget ip Sucker
3220 00012288 L PF Squawfish
3221 DJ022405 F UB Carp
3221 OJ023904 F BF Channel Catfish
3221 DJ023905 F UB Sucker
3222 OJ023906 F PF Squawfish
3222 OJ023907 F UB Sucker
3223 DJ023717 F UP Starry Flounder
3224 OJ023715 M Soft Shell Clams
3226 OJ023721 M Pacific Oysters
3227 DJ023723 N Pacific Oysters
3231 DJ023911 F UB Carp
3234 DH020301 F UP Squawfish
3235 OH020303 F UB White Sucker
3236 OH020305 F UB Largescale Sucker
3236 DH020306 F PF Brown Trout
3237 DH020307 F PF Rainbow Trout
3237 OH020308 F UB Largescale Sucker
3238 DJ023918 F UP Dolly Varden
2378
TCOO
ND
NO
1.53
0.25
ND
0.56
7.66
2.86
ND
2.61
0.74
2.25
ND
0.70
0.87
1.28
2.57
2.01
4.58
0.76
1.73
2.78
2.14
0.36
1.48
5.23
1.75
56.02
7.92
5.12
1.14
2.28
1.57
ND
ND
ND
0.79
ND
0.33
0.53
ND
ND
ND
ND
12378
PECOO
0.28
ND
0.74
0.46
ND
ND
7.83
3.33
ND
3.75
NO
3.31
NO
ND
ND
0.95
0.68
0.55
1.56
0.27
0.78
ND
NO
ND
0.49
0.68
ND
1.67
0.34
0.23
ND
0.32
ND
ND
ND
ND
1.20
ND
0.50
0.72
0.91
ND
ND
ND
123478
HXCDD
0.16
NO
ND
ND
ND
ND
2.93
ND
ND
NO
ND
1.10
ND
ND
ND
ND
ND
ND
0.35
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.75
ND
ND
ND
ND
123678
HXCDD
0.58
ND
0.63
0.58
ND
NO
24.79
8.68
ND
10.05
0.82
4.06
ND
ND
ND
0.80
0.90
0.77
1.79
ND
0.77
0.66
ND
ND
0.56
ND
ND
1.34
0.37
ND
0.20
0.45
0.42
1.48
ND
ND
2.93
ND
0.94
1.00
NO
ND
ND
ND
DIOXIN
123789
HXCDD
ND
ND
ND
0.25
ND
ND
3.36
1.09
ND
1.42
ND
0.61
ND
ND
ND
ND
0.18
0.19
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
0.41
ND
ND
ND
ND
ND
ND
ND
ND
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
2.26
0.44
1.69
2.21
0.74
0.74
91.72
13.27
0.49
34.42
0.43
16.57
0.56
0.77
NO
0.90
5.86
4.66
2.47
0.54
2.00
ND
0.52
0.37
1.16
2.20
ND
ND
2.70
0.33
ND
1.65
2.37
34.14
ND
7.49
6.88
0.91
2.77
2.80
ND
ND
ND
0.79
TCDF
0.18
0.75
9.36
0.43
ND
3.64
1.82
4.10
ND
48.14
1.09
3.35
1.69
ND
ND
9.03
11.38
10.27
16.12
2.43
21.63
16.39
61.58
8.02
20.12
28.34
20.73
320.69
4.97
41.78
11.95
15.95
11.58
0.49
1.29
1.74
9.14
ND
1.02
1.73
1.42
1.67
2.98
0.37
12378
PECOF
MO
ND
0.38
ND
ND
ND
1.65
0.57
ND
54.32
ND
0.91
ND
ND
ND
0.51
0.28
ND
ND
ND
0.29
ND
0.64
ND
0.21
0.30
ND
3.52
ND
ND
ND
ND
ND
ND
ND
ND
0.65
ND
ND
ND
ND
ND
ND
ND
pg/g
23478
PECOF
ND
ND
0.66
ND
ND
0.34
4.81
2.19
ND
19.02
0.34
2.27
ND
ND
ND
0.59
0.44
0.43
0.45
ND
0.36
ND
0.33
ND
ND
0.67
0.26
7.32
1.09
0.55
0.21
0.25
ND
ND
ND
ND
ND
ND
0.34
0.64
ND
ND
ND
ND
123478
HXCOF*
0.96
ND
ND
ND
ND
ND
2.23
2.88
ND
18.85
ND
3.02
ND
ND
ND
ND
ND
ND
0.60
0.40
ND
0.60
ND
ND
ND
ND
ND
ND
ND
0.20
ND
ND
ND
0.25
ND
ND
0.42
ND
ND
ND
ND
ND
ND
ND
123678
HXCDF
ND
ND
ND
ND
ND
NO
3.62
0.91
ND
10.15
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
123789
HXCOF
ND
NO
ND
NO
NO
NO
ND
ND
ND
0.23
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCOF
0.67
ND
ND
ND
ND
ND
0.80
1.85
NO
0.87
NO
1.16
ND
ND
ND
ND
ND
ND
0.36
0.25
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.47
ND
ND
ND
ND
ND
ND
ND
1234678 1234789 DPE
HPCOF
0.95
ND
ND
0.32
ND
ND
8.88
2.88
NO
6.44
0.24
2.66
ND
ND
ND
ND
0.76
0.65
0.40
ND
ND
0.28
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.24
0.26
3.06
ND
2.14
0.91
ND
0.20
0.23
ND
ND
ND
ND
HPCOF
ND
ND
ND
ND
ND
HO
ND
ND
ND
1.76
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TEC
0.43
0.08
3.26
0.63
0.01
1.10
19.02
7.76
ND
26.11
1.11
6.61
0.17
0.71
0.87
3.07
4.46
3.68
7.54
1.21
4.57
4.55
8.50
1.17
3.82
8.78
3.95
92.89
9.20
9.71
2.46
4.22
2.80
0.59
0.13
0.31
2.80
0.01
0.98
1.59
0.60
0.17
0.30
0.04
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
D-4-16
-------
Episode SCC Type Description
3238 00080888 L UP Dolly Varden
3241 DJ023924 F UP Dotty Varden
3244 DJ023622 F UB Coast Sculpin
3245 DJ023623 F UP Spotted Rat fish
3245 DJ023624 F UP Flathead Sole
3246 DJ022108 F PF Red Striped Rockfish
3246 DJ022109 F UP Flat head Sole
3248 DJ022502 F UB Composite Bottom
3249 DJ022504 F UB Sucker
3250 DJ022506 F UB Sucker
3252 DJ022510 F UB Sucker
3252 00082288 L UB Sucker
3256 DJ022517 F PF Sra Bass
3256 DJ022518 F UB Sucker
3258 DC038901 F PF Spot
3258 DC038902 F UB Croaker
3259 DB000466 F UB Goldfish
3259 DB069101 F UB Sucker
3260 DB000493 F UB Carp
3261 DY026002 F UB Striped Mullet
3262 DY026004 F UB Tilapia Tilapia
3264 DY022602 F UB Horn/head Turbot
3266 DY022702 F UB Channel Catfish
3267 DY022101 F PF Rainbow Trout
3267 DY022102 F UB Sacramento Sucker
3267 OD020288 L PF Rainbow Trout
3269 DY022106 F UB Channel Catfish
3270 DY022107 F PF Squawfish
3270 DY022108 F UB Sucker
3270 SY022108 F UB Sucker
3271 DY022110 F UB Sucker
3272 OY022111 F PF Leopard Shark
3272 DY022112 F UB White Surfperch
3273 OY022113 F UB Sculpin
3273 OY022114 F UB Surf Smelt
3274 DY022116 F UB Sculpin
3275 DY022118 F UB Sucker
3276 DY022119 F UB Walleye
3276 DY022120 F PF Brown Rockfish
3278 DY022124 F UB Sacramento Sucker
3281 DY022205 F UB Sucker
3282 DY022207 F UB Carp
3283 DY022209 F UB Carp
3285 DY022212 F UP Stingray
2378
TCDD
NO
0.53
ND
NO
ND
NO
ND
ND
NO
ND
0.58
0.48
0.74
0.46
1.52
ND
1.20
1.89
0.96
0.76
0.33
4.08
0.47
11.74
6.35
11.26
ND
6.84
6.45
5.60
0.21
NO
1.27
0.63
NO
ND
ND
0.68
ND
ND
ND
ND
0.93
1.91
12378
PECDD
ND
ND
NO
ND
0.24
NO
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
OR 1
ND
ND
ND
ND
3.99
ND
ND
ND
NO
0.91
0.83
ND
ND
ND
ND
2.98
ND
ND
ND
ND
0.43
ND
ND
ND
ND
0.78
1.65
123478
HXCDD
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
0.51
ND
0.48
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
0.81
123678
HXCDO
ND
0.57
ND
ND
NO
ND
ND
NO
ND
0.40
ND
0.44
ND
ND
ND
0.87
4.07
1.37
ND
1.15
0.81
4.93
ND
ND
NO
ND
1.33
0.63
ND
NO
0.42
0.47
2.46
0.71
ND
NO
ND
0.78
0.31
ND
ND
ND
0.48
3.15
DIOXIN
123789
HXCDD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.46
ND
ND
0.31
NO
NO
ND
NO
ND
ND
ND
NO
ND
ND
NO
ND
0.36
ND
ND
ND
ND
0.16
ND
ND
ND
ND
NO
0.96
/ FURAN CONCENTRATIONS,
1234678
HPCDD
0.77
0.58
1.62
0.44
1.59
ND
0.34
2.18
0.86
2.25
0.96
0.97
0.28
0.73
ND
2.80
5.87
2.40
2.91
4.17
15.08
3.25
1.22
ND
0.64
1.69
4.08
NO
0.62
0.47
1.22
1.70
4.84
1.47
0.54
0.73
0.32
2.42
3.12
0.74
0.72
NO
1.32
8.69
2378
TCDF
0.37
3.13
0.45
0.22
ND
ND
0.35
0.86
0.75
1.95
2.31
2.19
2.75
2.62
5.05
ND
0.93
24.73
6.65
3.48
ND
3.49
0.61
106.94
61.40
99.67
0.36
35.81
55.75
44.52
0.27
0.52
17.98
0.64
1.06
0.39
ND
1.54
0.61
ND
ND
1.57
3.96
12.90
12378
PECDF
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.76
0.64
ND
0.96
0.42
0.71
ND
ND
ND
0.35
ND
ND
ND
ND
ND
ND
ND
ND
1.82
0.47
ND
ND
ND
ND
ND
ND
ND
ND
0.50
2.67
P9/9
23478
PECDF
ND
ND
NO
ND
ND
ND
ND
NO
ND
0.44
ND
0.23
ND
ND
3.96
ND
2.72
5.53
0.52
1.54
ND
2.36
0.76
0.54
ND
0.60
0.73
0.54
ND
0.30
ND
NO
3.90
0.49
NO
NO
ND
0.22
0.16
ND
ND
0.53
0.95
7.30
123478
HXCDF*
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
NO
NO
ND
0.25
0.59
ND
ND
0.70
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.76
ND
ND
ND
ND
ND
ND
ND
ND
0.22
0.66
123678
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
0.51
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
0.42
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123789
HXCDF
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
0.33
ND
ND
ND
0.94
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.70
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.39
1234678
HPCDF
ND
ND
ND
ND
ND
ND
ND
0.23
NO
0.30
ND
ND
ND
0.23
ND
0.40
0.42
0.23
NO
1.54
3.48
0.35
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
0.67
ND
ND
ND
0.28
0.17
ND
ND
ND
0.26
0.46
1234789
HPCDF
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
DPE
TEC
0.04
0.91
0.06
0.03
0.14
ND
0.04
0.11
0.08
0.48
0.82
0.87
1.02
0.73
4.09
0.21
3.28
7.39
1.94
2.33
0.60
8.13
0.92
22.72
12.50
21.54
1.03
11.17
12.03
10.08
0.29
0.12
6.97
1.20
0.11
0.05
ND
1.28
0.20
0.01
0.01
0.42
2.30
8.50
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
D-4-17
-------
Episode SCO Type Description
3285 DY022213 F UB Diamond Turbot
3286 DV022215 F UB Carp
3287 DT022216 UB Titapia Zitti
3288 DT022218 UB Sucker
3288 00060168 UB Sucker
3289 DY022219 UP Bocaccio
3289 OT022220 UB Sculpin
3290 DY022221 PF Redeer Sunfish
3290 OT022222 UB Blacklist)
3294 OJ022111 UP True Cod
3294 OJ022113 H Mussel
3295 DJ022114 F UP Atlantic Salnon
3296 DB040101 F UB White Sucker
3297 DB041501 F UB Carp
3297 DB041504 F PF Sn Bass
3297 SB041S01 F UB Carp
3298 DB041601 F UB Carp
3298 06041604 F PF L* Bass
3298 00112988 L PF Ln Bass
3299 DB040601 F UB White Sucker
3299 DB040604 F PF Ln Bass
3300 OB040201 F UB Uhite Sucker
3300 DB040204 F PF S» Bass
3300 SB040201 F UB Uhite Sucker
3301 OB041101 F UB Carp
3301 D8041104 F PF Northern Pike
3301 00092088 L UB Carp
3301 SB041101 F UB Carp
3302 OB041901 F UB Uhite Sucker
3302 DB041904 F PF Ln Bass
3303 OB042301 F UB Uhite Sucker
3304 DB041001 F PF Northern Pike
3304 OB041004 F UB Uhite Sucker
330S OB042001 F UB Channel Catfish
330S DB042004 F PF S» Bass
3306 DB041801 F UB Uhite Sucker
3307 OB042101 F UB Uhite Sucker
3307 Q0100588 L UB Uhite Sucker
3308 DB040001 F PF Northern Pike
3308 00030689 L PF Northern Pike
3309 DB041301 F UB Uhite Sucker
3310 DC032701 F UB Bullhead
3310 DC032702 F PF Ualleye
2378
TCDO
HO
1.59
0.54
NO
NO
NO
NO
NO
2.39
ND
NO
NO
ND
6.40
ND
5.42
3.49
NO
ND
1.35
1.24
9.83
2.40
8.27
33.70
0.74
35.07
32.01
8.76
0.98
1.15
0.70
1.70
12.82
ND
1.01
1.38
1.30
NO
ND
0.24
1.20
HD
12378
PECOO
2.40
1.48
NO
NO
NO
ND
ND
HD
6.38
NO
NO
ND
NO
1.97
ND
1.86
4.34
ND
ND
1.61
0.49
1.13
ND
0.99
6.92
ND
6.91
6.17
0.96
ND
0.25
ND
0.93
3.22
HD
NO
ND
ND
ND
ND
ND
1.38
ND
12347B
HXCDO
ND
0.90
ND
NO
HD
ND
ND
NO
2.60
HD
NO
HO
HD
NO
ND
0.55
0.88
ND
HO
0.36
NO
HO
HD
HD
2.43
ND
HD
2.12
ND
ND
ND
ND
NO
NO
ND
ND
ND
HO
NO
ND
ND
0.61
ND
123678
HXCDO
2.34
3.26
ND
HD
NO
ND
NO
ND
7.92
ND
NO
0.25
NO
1.63
ND
1.44
5.51
HO
HD
0.83
ND
ND
HD
ND
12.17
ND
13.07
11.83
NO
HO
0.63
HD
0.87
2.07
HD
ND
HD
HD
ND
HD
0.42
2.71
ND
DIOXIN
123789
HXCDO
0.63
0.38
ND
NO
NO
NO
ND
ND
1.29
ND
ND
HD
HD
0.24
ND
NO
1.21
ND
NO
ND
HO
NO
ND
HD
1.57
ND
1.89
HO
HD
HD
HD
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
0.39
ND
/ FUftAN CONCENTRATIONS,
1234678
HPCDO
5.05
5.33
7.30
0.56
0.43
2.74
0.68
1.44
15.80
ND
ND
1.81
0.42
2.13
0.59
1.62
17.01
ND
ND
0.88
0.66
0.58
ND
0.42
17.82
ND
18.99
16.97
0.68
0.39
4.11
ND
1.67
1.57
ND
0.84
0.81
ND
ND
ND
4.78
3.60
0.42
2378
TCOF
0.79
1.81
3.61
1.95
2.01
0.76
0.84
NO
22.07
0.94
ND
1.44
2.90
8.62
NO
7.14
2.62
HD
ND
4.65
1.32
7.33
0.70
7.18
7.30
1.67
7.92
7.37
6.53
NO
9.10
0.91
22.64
3.00
2.43
12.34
8.67
9.73
0.63
0.68
1.41
2.16
0.69
12378
PECDF
ND
0.53
ND
ND
ND
ND
NO
HD
1.97
HD
ND
ND
NO
6.39
HO
5.83
1.04
NO
ND
5.50
0.85
1.20
NO
1.02
6.38
ND
6.16
5.60
0.92
HD
HD
ND
0.93
0.57
NO
0.65
NO
0.31
ND
ND
ND
1.39
ND
pa/g
23478
PECDF
1.85
1.35
HD
0.30
0.35
ND
HD
ND
4.75
HD
ND
HD
0.58
22.67
1.85
20.80
3.89
ND
ND
42.58
5.48
4.94
ND
4.80
27.29
ND
26.30
26.09
4.36
NO
0.48
HD
1.88
8.86
NO
2.20
0.71
0.75
NO
ND
ND
4.21
ND
123478
HXCDF*
HD
ND
HD
HO
ND
ND
HD
NO
3.90
NO
HD
HD
NO
37.92
1.34
36.53
1.07
NO
HD
30.77
3.08
1.46
HD
1.32
15.44
NO
15.98
16.73
0.78
ND
ND
NO
ND
1.15
ND
ND
ND
ND
ND
ND
ND
HD
HD
123678
HXCDF
0.63
0.56
HO
NO
ND
ND
NO
ND
1.29
ND
HD
ND
ND
13.84
0.35
10.77
1.83
ND
ND
8.31
ND
ND
HO
NO
12.72
NO
13.95
10.07
NO
HO
NO
ND
NO
0.65
NO
NO
HD
NO
NO
NO
ND
1.00
ND
123789
HXCDF
HO
ND
NO
NO
NO
ND
HO
ND
HD
ND
HD
HD
HD
HO
NO
HO
ND
NO
ND
NO
ND
NO
NO
NO
HD
HO
ND
HO
NO
NO
HO
NO
HO
HD
ND
HO
HD
ND
HD
HO
HD
HO
NO
234678
HXCDF
HO
NO
NO
ND
ND
NO
NO
NO
1.81
NO
HO
ND
ND
HO
NO
0.85
0.83
ND
ND
1.42
ND
ND
NO
ND
1.37
NO
1.54
1.57
NO
ND
HO
ND
NO
HD
ND
NO
NO
ND
ND
HD
HD
HD
ND
1234678
HPCOF
NO
0.53
1.35
ND
HD
ND
ND
ND
3.29
HD
ND
ND
HD
11.76
ND
10.22
3.02
ND
ND
6.38
0.58
0.32
NO
ND
9.26
NO
9.56
8.46
0.56
HD
0.99
ND
NO
ND
ND
NO
NO
NO
NO
ND
1.88
ND
ND
1234789
HPCOF
ND
HD
HD
ND
ND
ND
ND
NO
HO
NO
ND
NO
HD
0.47
NO
HD
HD
HD
ND
0.48
ND
ND
NO
NO
HD
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
NO
NO
ND
ND
HD
DPE
TEC
2.61
3.78
0.99
0.35
0.38
0.10
0.09
0.01
12.33
0.09
NO
0.19
0.58
25.43
1.10
10.30
9.25
HO
HO
28.43
4.72
13.81
2.47
10.08
56.69
0.91
57.70
39.87
12.21
0.98
2.54
0.79
5.52
19.59
0.24
3.38
2.61
2.66
0.06
0.07
0.49
4.79
0.07
Y
T
Y
Y
Y
D-4-18
-------
Episode SCC Type Description
3311 OC032801
3311 DC032802
3312 DC033101
3312 DC033102
3313 DC033201
3313 DC033202
3314 DC033301
3314 DC033302
3314 SC033301
3314 SC033302
3315 DC033401
3316 DC033501
3316 DC033502
3317 DC033601
3317 DC033602
3317 SC033601
3317 SC033602
3318 DC033701
3318 DC033702
3319 DB041401
3319 00063088
3320 DB041412
3321 DB040401
3322 08040412
3323 DB041206
3324 DB041252
3325 DB041218
3325 00082988
3326 DB041208
3327 DB040301
3327 DB04031S
3328 00029111
3328 00029112
3328 S0029111
3328 S0029112
3329 D0016003
3329 SD016003
3330 DD029109
3330 00029110
3330 00029423
3331 00016001
WB Redhorse Sucker
PF S» Bass
UB Redhorse Sucker
PF SB Bass
UB Redhorse Sucker
PF SM Bass
UB Channel Catfish
PF White Bass
WB Channel Catfish
PF White Bass
WB Carp
WB White Sucker
PF Brown Trout
UB White Sucker
UP Puapkinseed
WB White Sucker
UP Punpkinseed
UB White Sucker
PF Rock Bass
UP Winter Flounder
WP Winter Flounder
WP Bluefish
WP Winter Flounder
WP Bluefish
UP Winter Flounder
WP Bluefish
UP Bluefish
WP Bluefish
WP Bluefish
WP Bluefish
WP Bluefish
UB Carp
PF L« Bass
WB Carp
PF im Bass
WB Bowfin
UB Bowfin
PF Suwannee Bass
WB Spotted Sucker
PF Black Crappie
WB Brown Bullhead
2378
TCOO
NO
HO
ND
NO
3.65
0.55
56.34
7.20
47.10
6.22
ND
5.79
3.55
58.21
35.50
46.57
29.85
1.71
0.41
ND
1.2
0.75
2.39
1.16
0.69
1.74
0.71
0.52
1.07
2.92
3.53
30.04
8.78
23.83
7.24
13.19
11.46
NO
1.21
ND
5.96
12378
PECDD
ND
ND
0.36
ND
0.41
NO
1.02
ND
0.91
NO
0.59
0.57
ND
0.32
ND
ND
NO
ND
NO
ND
ND
ND
0.37
ND
ND
NO
ND
ND
ND
ND
0.75
0.88
ND
0.72
ND
0.65
0.54
HO
1.79
NO
ND
123478
HXCDD
ND
ND
ND
ND
ND
NO
ND
ND
0.34
ND
0.42
ND
ND
ND
NO
ND
ND
ND
ND
NO
NO
OR ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
0.54
ND
ND
ND
ND
ND
NO
ND
ND
ND
123678
HXCDD
ND
ND
0.41
ND
0.37
ND
1.95
ND
1.16
ND
0.62
0.37
ND
0.25
NO
ND
ND
0.18
HO
ND
0.4
OR ND
0.34
ND
ND
ND
ND
ND
NO
HO
0.40
1.11
ND
0.75
ND
0.71
0.50
ND
1.12
ND
0.27
DIOXIN
123789
HXCDD
ND
ND
ND
ND
ND
ND
0.27
ND
ND
ND
0.25
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.22
ND
HO
/ FURAH CONCENTRATIONS,
1234678
HPCDO
0.53
ND
1.72
0.42
1.45
0.48
4.37
0.37
3.48
ND
4.87
1.52
0.45
0.37
0.43
ND
0.23
0.69
0.38
0.61
0.8
OR NO
0.65
ND
ND
0.72
1.31
0.60
0.60
0.53
0.48
3.64
0.82
2.96
0.47
ND
0.61
1.72
1.35
0.43
1.37
2378
TCDF
6.42
1.05
8.30
2.18
13.51
0.52
8.20
5.84
6.97
5.24
1.52
30.48
3.89
171.06
88.06
144.02
73.02
30.70
4.52
13.73
13.3
1.93
9.09
0.67
4.18
1.65
1.27
1.40
1.47
2.72
3.20
13.24
22.04
10.89
21.59
40.76
39.89
NO
1.41
ND
1.18
12378
PECDF
0.64
ND
0.51
ND
0.23
ND
1.76
0.40
1.35
0.33
0.38
1.48
NO
0.39
ND
0.35
0.20
0.31
NO
1.74
1.9
1.06
0.87
0.42
NO
0.48
0.42
0.42
0.46
0.72
0.84
0.82
ND
ND
ND
1.32
1.20
ND
NO
ND
ND
P9/9
23478
PECDF
0.61
ND
0.83
ND
0.71
ND
5.70
0.89
5.14
0.58
0.63
2.13
0.78
0.63
0.28
0.56
0.18
0.46
ND
0.64
0.7
0.93
1.15
0.75
NO
0.88
0.72
0.66
0.70
2.46
2.59
4.45
0.30
4.05
0.32
2.21
2.04
ND
0.30
ND
ND
123478
HXCDF*
ND
ND
ND
ND
ND
ND
1.00
0.22
0.93
ND
ND
0.48
0.28
ND
ND
ND
ND
NO
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
0.36
NO
0.87
1.02
ND
ND
ND
ND
123678
HXCDF
ND
ND
ND
ND
ND
ND
0.59
ND
NO
NO
ND
0.35
NO
ND
NO
NO
NO
ND
NO
NO
ND
NO
ND
NO
NO
NO
NO
NO
ND
NO
ND
ND
ND
ND
NO
1.55
1.39
ND
ND
NO
ND
123789
HXCDF
ND
ND
NO
ND
NO
ND
ND
NO
NO
ND
ND
ND
NO
NO
NO
ND
ND
NO
ND
HO
NO
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
NO
NO
ND
ND
NO
ND
ND
ND
NO
ND
234678
HXCDF
ND
ND
ND
ND
NO
ND
0.27
ND
ND
NO
ND
NO
NO
NO
NO
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
0.32
NO
ND
ND
ND
ND
1234678
HPCDF
ND
ND
ND
ND
ND
ND
0.79
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
OR ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
NO
NO
1.20
1.08
ND
ND
ND
ND
1234789
HPCDF
ND
ND
ND
ND
NO
ND
0.50
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
NO
ND
OR ND
NO
NO
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
OPE
TEC
0.98
0.10
1.51
0.22
5.62
0.61
61.07
8.27
48.97
6.84
0.96
10.40
4.36
75.84
44.45
61.07
37.19
5.05
0.87
1.79
3.02
1.46
4.14
.62
.11
2.38
.23
.02
.60
4.46
5.31
34.27
11.14
25.72
9.43
19.12
16.09
0.02
2.54
ND
6.12
ZW-I9
-------
Episode SCC Type Description
3331 DD016002 F PF Lm Bass
3331 D0016007 F UB Carp
3331 DD016008 F BF White Catfish
3331 S0016008 F BF White Catfish
3332 D0016009 F UP Spotted Dru*
3332 DD016010 F PF Crevalle Jack
3333 DD016011 F PF Bluefish
3333 DD016012 F UB Sea Catfish
3333 DD029108 F PF Weakfish
3333 00121588 I PF Bluefish
3334 DD016013 F WB Sea Catfish
3334 DD016014 F BF Striped Mullet
3335 D0016015 F UP Spot
3335 D0016016 F PF Spotted Bass
3335 D0029101 f WP Red Drum
3335 DD029102 F UB Southern Flounder
3335 D0029103 F UP Sheepshead
3335 00081588 L UP Southern Flounder
3335 S0016015 F UP Spot
3336 DD016004 F WP Black Drum
3336 DD016005 F PF Striped Mullet
3336 DD016006 F UP Sheepshead
3336 DD016017 F UP Red Drum
3336 DD016018 F PF Spotted Seatrout
3336 OD092288 L PF Spotted Seatrout
3337 D0016019 F UB Spotted Sucker
3337 DD016020 F PF Lm Bass
3337 00051388 L UB Spotted Sucker
3338 D0016021 F PF Lm Bass
3338 00016022 F WB Spotted Sucker
3338 DD029107 F PF Chain Pickerel
3339 DD016023 F WB Carp
3339 DD016024 F PF White Bass
3339 00016023 L UB Carp
3340 00029113 F PF Lm Bass
3340 DD029114 F UB Channel Catfish
3340 SD029114 F UB Channel Catfish
3341 DD016103 F PF Lm Bass
3341 DD016104 F UB Catfish
3341 OD092788 L PF Lm Bass
3341 SD016103 F PF Lm Bass
3341 SD016104 F WB Catfish
3342 DD016105 F WB Spotted Sucker
3342 DD016106 F PF Bluegill
2378
TCDD
4.37
24.04
8.94
8.10
0.63
ND
0.77
3.13
NO
0.98
3.50
ND
24.01
ND
0.82
0.71
40.25
0.70
20.11
ND
2.70
3.53
ND
ND
ND
4.62
0.88
4.88
ND
1.72
0.83
4.75
1.42
4.48
3.77
98.88
82.72
7.75
34.40
6.10
6.68
31.20
2.70
ND
12378
PECOD
ND
1.17
0.55
0.61
1.12
ND
0.70
0.54
ND
0.78
4.04
ND
2.41
ND
ND
0.39
2.57
0.36
2.08
ND
ND
1.32
ND
ND
ND
1.93
ND
2.23
ND
1.85
ND
1.84
0.28
1.74
ND
3.52
3.33
ND
4.00
ND
ND
3.44
0.94
ND
123478
HXCDD
NO
ND
NO
ND
0.23
ND
ND
0.24
ND
ND
1.24
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
1.18
ND
1.61
ND
ND
ND
1.40
ND
1.60
ND
1.42
ND
ND
2.28
ND
ND
1.83
0.91
ND
123678
HXCDD
ND
ND
0.76
0.68
0.90
ND
ND
1.06
ND
0.81
8.02
NO
2.53
ND
ND
ND
1.52
0.75
1.66
0.43
ND
NO
ND
ND
ND
2.53
ND
3.36
ND
7.08
ND
3.15
0.25
3.04
ND
3.70
3.12
ND
9.54
ND
ND
9.51
3.13
ND
DIOXIN
123789
HXCDD
ND
0.37
0.18
ND
0.29
ND
NO
0.25
ND
ND
1.55
ND
0.71
ND
0.29
ND
ND
0.32
0.59
0.23
ND
0.24
ND
ND
ND
0.86
ND
0.99
ND
0.40
ND
0.68
ND
ND
ND
0.98
0.67
ND
3.75
ND
ND
3.07
0.37
ND
/ FURAN CONCENTRATIONS,
1234678
HPCDD
1.09
13.42
1.68
0.96
1.40
ND
0.69
1.06
ND
0.72
5.05
NO
2.72
0.45
1.12
2.42
3.76
2.47
2.25
1.66
1.07
1.00
0.29
0.72
0.58
5.34
0.90
5.41
ND
11.03
ND
20.03
1.79
17.57
ND
5.38
4.94
ND
23.44
ND
ND
18.72
5.05
0.44
2378
TCDF
0.58
7.84
1.48
1.57
2.95
ND
2.50
1.62
ND
2.50
0.71
ND
40.03
1.00
4.99
0.84
9.21
0.92
39.06
0.90
11.62
4.88
0.75
ND
ND
8.09
0.34
8.89
ND
5.87
ND
6.46
2.91
6.79
0.31
10.19
10.28
14.90
18.06
10.92
12.81
15.82
24.54
ND
12378
PECDF
ND
0.40
ND
ND
0.30
ND
ND
ND
ND
ND
NO
ND
4.52
0.65
3.20
NO
1.40
ND
3.61
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.40
0.86
ND
0.21
ND
0.23
ND
ND
ND
ND
0.72
ND
P9/9
23478
PECDF
ND
ND
0.27
0.21
0.50
ND
0.34
0.43
ND
0.40
ND
ND
5.15
ND
ND
ND
6.06
ND
4.90
ND
NO
ND
ND
ND
ND
0.50
ND
0.75
ND
1.04
ND
2.18
0.74
2.15
ND
1.93
1.83
0.31
3.25
0.26
ND
2.80
1.16
ND
123478
HXCDF*
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
1.41
ND
0.26
ND
0.71
ND
1.43
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.28
ND
1.13
ND
ND
ND
ND
ND
ND
ND
ND
0.30
ND
123678
HXCOF
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
1.09
ND
ND
ND
0.49
ND
0.77
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
0.86
ND
0.75
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123789
HXCDF
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
1.10
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
0.97
ND
0.23
ND
0.71
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.23
ND
ND
ND
0.19
ND
ND
ND
ND
ND
ND
ND
ND
1234678
HPCDF
ND
2.75
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
0.39
NO
ND
OR NO
ND
ND
0.30
0.21
ND
ND
ND
ND
ND
0.36
ND
0.27
ND
0.89
ND
0.74
ND
0.78
NO
0.39
ND
ND
ND
ND
ND
ND
0.48
ND
1234789
HPCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
OR ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TEC
4.44
25.74
9.61
8.61
1.91
ND
1.55
3.94
ND
1.91
6.72
ND
32.72
0.14
1.57
1.01
45.94
1.10
26.02
0.17
3.87
4.71
0.08
0.01
0.01
7.16
0.92
7.91
ND
4.62
0.83
8.37
2.28
7.98
3.80
103.32
85.75
9.41
41.62
7.32
7.96
35.38
6.77
ND
DPE
Y
Y
Y
Y
D-4-20
-------
Episode SCC Type Description
3343 DD016107 F UB
3343 DD016108 F PF
33A4 D0016109 F U6
3344 DD016110 F PF
3344 S0016109 F UB
3345 DD016111 F UB
3345 DD016112 F PF
3345 S0016111 F UB
3346 D0016113 F UB
3346 OD016114 F PF
3346 00042088 L UB
3346 SD016113
3346 SD016114
3347 00016115
3347 DD016116
3347 SD016115
3348 D0016117
3348 DD016118
3348 OD072888
3348 SD016117
3348 SD016118
3349 00016119
3349 00016120
3350 00016121
3350 OD016122
3350 00052688
3351 00016123
3351 00016124
UB
PF
UB
PF
UB
PF
UB
UB
PF
UB
UB
PF
UB
PF
WB
PF
UB
3351 00021888 L UB
3352 OF023723 F PF
3352 DF023724 F UB
3352 00091388 L UB
3353 DF024121 F BF
3353 DF024122 F UB
3353 00024121 L BF
3354 DY022301 F UB
3354 DY022302 F PF
3355 DY022303 F UB
3355 DY022304 F PF
3355 SY022303 f UB
3356 DE030201 F UB
3356 SE030201 F UB
3357 DY022223 F PF
3357 DY022224 F UB
White Sucker
Redbreast Sunfish
Carp
Lm Bass
Carp
Redhorse Sucker
Lm Bass
Redhorse Sucker
Creek Chubsucker
Lm Bass
Creek Chubsucker
Creek Chubsucker
Lm Bass
Carp
Lm Bass
Carp
White Perch
Blue Catfish
Blue Catfish
White Perch
Blue Catfish
Carp
Lm Bass
Carp
Lm Bass
Carp
Rock Bass
Carp
Carp
Crappie
Carp
Carp
Blue Catfish
Sm Buffalo
Blue Catfish
Carp
Lm Bass
Carp
Lm Bass
Carp
Carp
Carp
Squawf i sh
Sacramento Sucker
2378
TCDD
75.70
12.01
22.30
0.93
20.94
5.50
1.44
5.78
143.32
18.24
157.50
156.34
20.88
15.31
3.17
12.58
18.20
104.13
107.02
15.73
87.26
9.10
1.17
3.97
0.48
3.83
0.17
22.07
21.04
ND
1.31
1.23
5.53
5.17
4.83
1.07
ND
13.38
ND
15.0
6.55
5.50
0.80
3.47
12378
PECDD
2.64
ND
2.32
ND
2.60
6.71
1.00
7.69
1.34
NO
1.53
1.44
0.20
2.29
0.32
1.80
1.65
12.48
12.19
1.33
10.81
1.51
NO
4.58
ND
4.40
ND
2.49
1.95
ND
2.55
2.41
0.92
1.68
0.75
3.08
0.49
53.95
ND
58.9
9.35
8.95
0.34
0.90
123478
HXCDD
ND
ND
1.76
ND
1.68
ND
ND
2.44
ND
ND
ND
0.25
ND
2.39
ND
1.80
ND
1.11
1.16
ND
0.93
0.97
ND
1.35
ND
1.47
ND
1.91
2.48
ND
5.39
4.45
ND
1.06
ND
2.62
ND
37.56
ND
40.0
3.00
2.28
ND
ND
123678
HXCDD
ND
0.33
6.80
ND
7.26
7.08
1.14
8.34
ND
ND
ND
0.67
ND
ND
0.34
4.82
0.22
2.25
2.25
ND
1.59
3.02
ND
6.82
ND
6.13
ND
5.33
4.44
ND
6.52
5.77
1.82
1.62
1.47
7.54
0.43
89.08
0.89
113.5
7.77
6.69
0.44
1.40
DIOXIN
123789
HXCDD
0.51
ND
1.51
ND
1.23
2.69
ND
3.44
ND
ND
ND
0.17
NO
0.95
NO
0.65
NO
0.71
0.81
ND
ND
0.95
ND
1.08
ND
0.91
ND
0.52
ND
ND
1.88
1.68
0.54
0.53
0.47
1.68
ND
24.76
ND
24.9
1.73
1.20
ND
ND
/ FURAN CONCENTRATIONS,
1234678
HPCDD
4.43
1.01
33.06
ND
35.39
17.20
2.45
22.01
1.74
0.28
1.18
2.00
0.37
32.23
0.95
27.62
1.85
4.59
4.57
1.18
3.81
16.84
0.81
14.12
ND
13.42
ND
13.53
13.36
1.10
37.95
32.45
5.21
5.08
4.74
25.82
1.47
249.06
1.24
283.1
12.44
11.91
ND
2.68
2378
TCDF
143.88
5.94
3.34
ND
2.84
93.71
1.39
105.13
194.74
20.10
207.38
194.16
23.20
4.11
2.12
3.42
48.49
26.15
27.48
48.32
21.03
10.43
0.56
4.32
ND
3.65
ND
16.09
16.89
ND
0.96
0.86
2.87
19.91
2.74
3.44
ND
1.03
ND
1.2
5.33
5.27
3.71
35.79
12378
PECDF
7.20
ND
0.49
ND
0.59
ND
ND
ND
1.25
ND
1.31
1.48
0.21
0.33
ND
0.28
1.97
4.17
4.47
1.43
3.53
0.53
ND
0.93
ND
0.97
ND
1.66
1.64
ND
ND
ND
ND
0.33
ND
1.24
ND
3.08
ND
3.5
3.35
2.63
ND
0.24
P9/9
23478
PECDF
8.23
ND
ND
ND
2.28
0.68
ND
1.00
9.18
0.48
10.32
12.08
0.64
ND
ND
1.51
1.99
16.58
16.76
1.60
13.10
2.03
ND
2.05
ND
1.93
ND
3.47
3.65
ND
ND
ND
0.33
0.49
ND
2.37
ND
17.07
ND
19.6
24.81
21.67
0.23
1.25
123478
HXCDF*
1.40
ND
2.07
ND
0.63
0.36
ND
ND
ND
ND
ND
ND
NO
0.39
ND
0.37
ND
ND
0.42
ND
ND
ND
ND
2.09
ND
1.85
ND
1.73
1.10
ND
NO
ND
ND
ND
ND
1.85
ND
19.67
ND
16.5
2.37
2.31
ND
ND
123678
HXCDF
1.34
ND
ND
ND
0.83
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.60
ND
ND
ND
ND
ND
ND
ND
0.84
ND
0.60
ND
1.15
0.94
ND
ND
ND
NO
ND
ND
1.85
ND
13.14
ND
14.3
3.30
2.33
ND
ND
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
MO
ND
NO
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
0.61
ND
1.89
ND
0.27
ND
ND
MO
ND
ND
ND
ND
ND
0.29
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.39
ND
1.41
ND
3.03
3.48
ND
ND
ND
ND
ND
ND
ND
ND
6.78
ND
2.8
1.29
0.99
ND
ND
1234678
HPCDF
0.85
ND
2.92
ND
1.35
0.48
ND
NO
ND
ND
ND
ND
ND
1.48
0.13
1.31
ND
ND
ND
ND
ND
ND
ND
1.79
ND
1.55
ND
2.83
3.53
ND
ND
ND
NO
ND
ND
3.46
ND
25.42
ND
23.7
2.43
2.01
ND
ND
1234789
HPCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
2.57
ND
5.7
NO
NO
ND
ND
DPE
TEC
96.32 Y
12.65
25.58 Y
0.93 Y
23.27
19.76 Y
2.22 Y
20.63
168.13 Y
20.49
184.24 Y
177.88
23.39
17.62
3.59
14.33
25.01
121.94
124.98
21.53
96.54
12.60
1.23
9.28 f
0.48
8.80 Y
0.17
28.27 Y
27.02 Y
0.01
4.44
4.04
6.73
8.63
5.72
6.05 Y
0.30
71.02 Y
0.10 Y
54.7
26.43
13.41
1.50
8.30
D-4-21
-------
Episode SCC Type Description
3360 00029117 F UB Carp
3360 DD029118 F PF In Bass
3360 00022389 L UB Carp
3375 DD016305
3375 OD016306
3375 00101188 L
3376 DD016307 F
3376 00016308
UB Carp
PF LM Bass
UB Carp
UB Carp
F PF LM Bass
3376 00050389 L PF LM Bass
3377 00016309 F UB Carp
3377 DD016310 F PF LM Bass
3377 S0016309 F UB Carp
3378 00016311 F UB Spotted Sucker
3378 DD016312 F PF Lm Bass
F UB Creyfln Sucker
F BF Channel Catfish
F UB Redhorse Sucker
F UB Redhorse Sucker
F PF Lm Bass
F UB Redhorse Sucker
F UB Carp
F PF Lm Bass
F UB River Carpsucker
F PF LM Bass
3378 00029115
3378 00029116
3385 D0016401
3395 00016421
3395 DD016422
3395 SD016421
3401 00016509
3401 00016510
3403 00016513
3403 00016514
3404 OD016515 F UB Carp
3404 DD016516 F PF LM Bass
3404 SD016515
3409 DB040701
3409 DB040706
3411 DB040501
3412 DB040901
3412 DB040907 F UB Carp
3412 SB040907 F UB Carp
3414 DC036203
3414 DC036204
3415 OC036205
3415 DC036206 F
3416 OF025210 F
3416 OF02521J
3416 DF025212
3418 DF025007
3419 DC036207
F UB Carp
F UB Carp
F PF LM Bass
F UB Redhorse Sucker
F PF SM Bass
F PF SM Bass
F BF Channel Catfish
F PF SM Bass
BF Channel Catfish
F BF Channel Catfish
f BF Carp
F PF LM Bass
F BF Blue Catfish
F UB White Sucker
PF Freshwater Drum
3419 DC036208 F
3420 DC036209 F PF Greenfish
2378
TCOO
1.09
NO
NO
5.18
0.83
5.34
7.15
NO
ND
7.15
NO
7.64
0.43
NO
0.36
NO
1.38
49.19
5.48
45.04
3.35
NO
6.59
1.00
12.20
0.67
9.70
2.32
ND
1.10
1.30
28.30
24.40
HD
0.65
ND
1.85
3.14
6.46
ND
1.40
ND
ND
23.86
12378
PECDD
0.52
NO
0.68
5.43
ND
5.78
10.55
ND
ND
12.38
NO
12.28
NO
ND
0.49
ND
KO
3.04
ND
2.56
1.09
HO
6.61
ND
4.78
ND
4.06
4.75
ND
0.70
ND
6.94
5.52
HD
ND
ND
1.00
ND
NO
ND
HD
ND
ND
0.79
123478
HXCDO
ND
HD
NO
2.88
HO
3.21
7.53
NO
ND
8.29
NO
9.93
ND
NO
0.30
NO
HD
ND
HO
HO
0.74
NO
1.38
NO
1.11
NO
1.14
3.55
ND
NO
NO
1.25
1.21
HO
HO
HD
0.42
ND
HO
ND
HD
ND
ND
HO
123678
HXCOO
1.37
NO
2.28
20.42
0.59
22.47
41.95
ND
NO
47.29
HO
50.11
HD
NO
0.78
ND
0.55
2.11
NO
1.56
2.06
10.67
3.07
ND
5.60
ND
4.89
13.63
NO
1.12
ND
6.50
4.54
ND
1.10
ND
1.28
ND
ND
ND
ND
ND
ND
1.07
DIOXIN
123789
HXCOD
NO
NO
ND
2.68
HO
2.73
5.84
ND
ND
7.77
HO
10.50
HD
NO
NO
ND
HD
0.43
NO
NO
0.43
ND
0.70
ND
1.05
ND
0.85
2.54
NO
HD
HD
0.86
0.65
ND
ND
HD
HD
NO
ND
ND
NO
ND
HD
ND
/ FURAN CONCENTRATIONS.
1234678
HPCOD
4.73
ND
6.74
93.06
0.85
102.97
138.06
1.22
ND
171.02
ND
161.29
1.91
ND
2.31
HO
1.60
4.81
0.71
4.13
11.70
HO
7.59
HD
9.51
0.87
7.70
34.76
0.34
1.38
HD
8.76
7.67
ND
2.48
ND
2.71
2.19
2.61
ND
ND
ND
ND
4.11
2378
TCOF
2.49
NO
2.91
6.97
1.69
7.59
5.56
MO
NO
8.01
0.43
6.99
9.05
NO
7.13
HD
3.92
273.81
10.96
245.75
12.00
1.00
19.71
2.51
6.29
1.10
6.66
9.19
1.01
4.83
1.16
2.83
2.57
NO
0.56
ND
1.43
1.68
2.97
2.16
0.65
6.85
HO
19.22
12378
PECOF
ND
ND
ND
2.08
HO
2.35
2.46
HD
NO
3.09
ND
2.77
ND
HD
NO
ND
HD
4.21
ND
3.38
1.05
ND
1.82
ND
0.76
NO
0.58
1.95
NO
ND
ND
1.89
1.70
NO
ND
ND
0.47
ND
NO
ND
ND
HD
HO
0.68
P9/0
23478
PECDF
0.50
HD
0.59
5.93
0.42
6.68
7.16
MO
NO
10.21
NO
8.64
0.46
NO
0.56
ND
0.19
5.15
NO
4.65
2.04
NO
4.47
HD
1.97
ND
1.76
11.86
ND
0.98
HO
20.91
16.80
0.26
2.73
HD
3.30
HD
NO
HO
ND
ND
NO
0.34
123478
HXCOF*
ND
ND
ND
1.97
HO
2.24
4.59
ND
NO
4.20
HD
4.52
ND
ND
HD
HD
HD
ND
HD
NO
HO
HO
0.59
HD
HD
ND
HD
1.65
NO
0.24
HD
8.50
8.82
HD
ND
ND
HD
HD
ND
ND
ND
ND
HO
NO
123678
HXCOF
ND
NO
ND
3.37
ND
4.18
5.51
NO
ND
6.17
NO
5.73
ND
HD
HO
HD
ND
0.31
HO
ND
NO
NO
0.37
HO
HD
ND
NO
3.19
NO
NO
NO
5.88
4.35
HO
HD
HD
NO
HD
NO
ND
NO
HD
NO
HO
123789
HXCDF
ND
HD
NO
HO
HO
HO
NO
MD
ND
HO
NO
HO
HD
NO
NO
NO
HD
NO
HD
ND
HD
ND
ND
ND
ND
ND
HO
HO
HD
HD
HD
HD
HD
HD
HD
HD
ND
ND
ND
ND
HD
ND
NO
NO
234678
HXCOF
NO
ND
HD
1.01
NO
1.23
2.03
NO
NO
2.48
NO
3.72
HD
NO
NO
HD
ND
HO
HD
ND
HO
HO
0.51
NO
HO
ND
NO
0.99
HD
NO
NO
0.85
ND
ND
ND
ND
NO
ND
ND
NO
ND
NO
NO
NO
1234678
HPCOF
NO
NO
NO
7.58
NO
7.96
15.53
NO
ND
16.35
NO
26.74
HD
NO
HD
HD
HD
HD
HD
0.32
0.34
NO
1.84
NO
0.57
NO
0.34
3.15
HD
0.31
ND
3.36
2.62
ND
HD
KD
ND
HD
NO
ND
HD
HD
NO
0.24
1234789
HPCOF
NO
NO
ND
0.65
NO
0.83
0.91
NO
NO
0.97
NO
ND
ND
NO
NO
ND
ND
ND
HO
HD
NO
NO
0.50
NO
NO
NO
HD
HO
HD
HD
HO
HD
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
HO
HD
DPE
TEC
2.03
ND
1.22
15.91
t.28
17.17
24.97
0.01
ND
28.90
0.04
18.77
1.58
ND
1.73
HD
1.94
81.21
6.58
71.77
6.61
f.17
14.95
1.25
17.12
0.79
12.91
14.58
0.10
2.58
1.42
45.11
29.67
0.13
2.21
NO
4.36
3.33
6.78
0.22
1.47
0.69
NO
26.53
D-4-22
-------
Episode SCC Type Description
3420 DC036210 F
3421 DC036211 F
3421 DC036212 F
3421 SC036212 F
3422 DC036213 F
3422 DC036214
3423 DC036215
3423 OC036216
3424 DC036217
3424 DC036218
3425 OF025005
3425 DF025012
3425 OD031389 I
3426 OB069102 F
3427 DB069103
3428 DB069104
3429 DB069105
3430 DB069106
3431 DB069109
3432 DB069111
3433 DB069112
3433 00021689
3434 OB040801
3435 DD016601
3435 DD016602 F
3437 DJ022302 M
3438 DJ022303 M
3439 OJ022304 F
3439 00062289 I
3440 DJ022305 F
3441 DJ022306
3442 DF024301
3442 00081089
3444 D0016603
3444 DD016604
3444 DD029512
3444 00091289
3445 00029513
3445 DD029514
3446 DD016605
3446 00016606
3446 D0029511
3446 00092089 L
3450 DY022308 F
WB Carp
PF White Perch
WB Carp
WB Carp
PF Im Bass
WB Yellow Bullhead
PF White Perch
WB White Catfish
PF Shortnose Gar
WB White Catfish
WB Carp
BF Channel Catfish
BF Channel Catfish
PF Bluefish
PF Bluefish
PF Bluefish
PF Weakfish
WB White Catfish
WB Red Snapper
BF Red Snapper
WP Flounder
WP Flounder
WP Flounder
PF White Bass
WB Bignouth Buffalo
Crayfish
Dungeness Crab
WB White Sturgeon
WB White Sturgeon
WB White Sturgeon
WB White Sturgeon
BF Channel Catfish
BF Channel Catfish
WB Carp
BF Channel Catfish
PF LM Bass
WB Carp
WB Flounder
WB Hardhead Catfish
PF Striped Bass
WB Carpsucker
WB Carp
WB Carp
PF White Croaker
2378
TCDO
40.32
5.95
54.09
43.96
1.45
1.84
0.83
2.46
1.07
1.94
160.36
52.90
43.41
0.85
1.26
NO
NO
0.75
NO
NO
4.45
4.37
6.29
HO
3.08
NO
0.97
NO
0.88
1.06
NO
HO
NO
3.51
3.77
NO
4.01
NO
0.91
21.55
1.90
3.22
2.26
1.02
12378
PECOO
1.64
NO
1.77
1.78
NO
NO
NO
2.71
NO
1.05
9.43
3.08
2.43
NO
NO
ND
NO
ND
1.19
NO
0.94
ND
0.97
HO
2.52
ND
ND
ND
ND
NO
ND
HO
ND
9.00
3.54
ND
9.80
ND
2.40
ND
NO
ND
HO
ND
123478
HXCDD
ND
ND
ND
0.40
ND
ND
ND
ND
ND
ND
2.08
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
HD
ND
ND
ND
ND
ND
ND
ND
HD
NO
8.29
1.16
ND
8.72
ND
ND
ND
ND
ND
HD
ND
123678
HXCDD
2.67
ND
4.43
3.43
ND
ND
ND
2.91
0.99
ND
6.98
1.29
ND
ND
ND
ND
ND
0.68
ND
ND
0.92
1.19
1.70
ND
3.22
ND
1.22
ND
NO
ND
ND
ND
ND
22.88
7.68
ND
25.53
NO
5.57
ND
ND
1.03
1.45
NO
DIOXIN
123789
HXCDD
0.51
ND
0.76
0.45
ND
ND
ND
0.89
ND
0.52
2.89
0.58
0.55
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
0.64
NO
HD
ND
ND
ND
ND
ND
ND
4.00
1.45
ND
5.04
ND
2.02
ND
ND
NO
HD
NO
/ FURAH CONCENTRATIONS,
1234678
HPCOD
5.86
ND
2.40
2.10
ND
1.62
1.84
5.75
1.36
3.60
21.60
4.05
3.14
ND
ND
ND
ND
0.89
ND
ND
0.79
0.63
0.69
ND
8.68
3.33
HD
0.72
0.84
ND
0.62
ND
ND
131.65
10.03
OR ND
150.84
2.63
5.90
ND
ND
3.84
4.61
ND
2378
TCDF
12.57
10.86
60.25
50.75
0.67
0.68
4.68
3.32
2.33
3.60
82.46
4.92
4.23
1.90
2.23
1.80
ND
1.14
1.43
ND
1.37
1.47
1.26
2.2
8.29
1.77
16.45
22.05
20.94
17.75
22.15
ND
ND
1.51
HD
NO
1.45
HD
HD
3.62
0.68
1.42
1.38
HD
12378
PECDF
0.69
ND
3.05
2.48
ND
ND
ND
0.67
ND
ND
4.15
NO
ND
HD
0.41
ND
ND
0.73
0.71
ND
ND
HD
ND
ND
1.66
ND
ND
ND
0.52
HD
ND
ND
ND
1.14
ND
ND
1.26
HD
ND
ND
ND
ND
ND
ND
P9/9
23478
PECOF
3.03
ND
ND
5.34
ND
ND
ND
2.09
ND
0.74
10.45
2.34
1.72
0.42
0.63
0.98
ND
1.39
1.71
NO
1.90
2.21
3.12
ND
1.70
ND
0.43
ND
NO
HD
ND
ND
NO
2.28
1.02
NO
2.67
HD
HO
1.78
NO
1.76
1.92
ND
123478
HXCDF*
ND
ND
0.40
0.46
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
HD
ND
ND
NO
ND
ND
ND
ND
0.73
ND
ND
NO
ND
HD
ND
ND
NO
2.55
HD
ND
2.76
ND
ND
HD
HO
0.86
0.92
HD
123678
HXCDF
ND
ND
ND
HD
ND
ND
HO
ND
HD
ND
1.54
NO
ND
ND
ND
ND
HD
ND
ND
HD
ND
ND
ND
ND
HD
HD
NO
ND
ND
ND
ND
ND
HD
5.63
ND
ND
5.88
ND
ND
ND
ND
ND
ND
NO
123789
HXCDF
ND
HD
ND
HD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
HD
HD
NO
NO
HD
ND
ND
ND
ND
KD
ND
ND
HD
NO
ND
NO
ND
HD
ND
ND
NO
ND
ND
HD
ND
HD
HD
ND
HD
234678
HXCDF
ND
NO
ND
HD
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HO
ND
ND
NO
ND
HD
1.26
0.36
ND
1.91
ND
NO
ND
HD
HO
ND
HD
1234678
HPCDF
ND
NO
ND
ND
ND
ND
HD
ND
ND
ND
0.47
ND
HD
ND
HD
ND
ND
NO
ND
HD
NO
ND
ND
HD
0.89
NO
NO
HD
NO
ND
HD
ND
HD
13.76
1.20
OR HD
13.43
ND
ND
ND
ND
ND
ND
HD
1234789
HPCDF
ND
ND
ND
ND
ND
ND
HD
ND
ND
ND
NO
ND
ND
ND
HD
ND
ND
ND
ND
HD
NO
ND
ND
ND
ND
ND
ND
HD
NO
ND
HD
NO
ND
ND
NO
OR ND
ND
HD
ND
NO
ND
ND
HD
HD
DPE
TEC
44.32
7.04
61.74
50.88
1.52
1.92
1.32
5.66
1.42
3.28
180.32
56.33
45.99
1.25
1.82
0.67
ND
1.67
1.63
ND
6.11
5.75
8.64
0.23
6.66
0.21
2.95
2.21
3.01
2.84
2.22
NO
ND
15.27
7.23
HD
17.08
0.03
2.93
22.80
1.97
4.47
3.64
1.02
D-4-23
-------
DIOXIN / FURAN CONCENTRATIONS, pg/g
Episode SCC Type Description 2378 12378 123478 123678 123789 1234678 2378 12378 23478 123478 123678 123789 234678 1234678 1234789 DPE
TCOO PECOO HXCDO HXCDO HXCDD HPCOD TCOF PECOF PECOF HXCOF* HXCOF HXCOF HXCDF HPCOF HPCDF TEC
3450 DY022309 F PF White Croaker 2.24 NO NO NO NO NO NO NO NO NO NO NO NO NO NO 2.24
3451 DY022310 F PF White Croaker 1.93 NO NO NO NO NO NO NO NO NO NO NO NO NO NO 1.93
3451 DY022314 F PF White Croaker 1.22 NO NO NO NO NO NO NO NO NO NO NO NO NO NO 1.22
3452 OF025218 F UB &» Buffalo 9.01 NO NO NO NO NO 17.37 NO NO NO NO NO NO NO NO 10.75
3452 OF025219 F BF Blue Catfish 40.73 1.06 NO NO NO NO 10.98 NO NO NO NO NO NO NO NO 42.36
3452 OF02S220 F PF Flathead Catfish 2.26 NO NO NO NO NO NO NO NO NO NO NO NO NO NO 2.26
3452 00103189 L WB Sm Buffalo 9.03 NO NO NO NO NO 16.85 ND NO NO NO NO NO NO NO 10.72
D-4-24
-------
Dioxins/Furans
Detection Limits
D-4-2S
-------
D-4-26
-------
Episode SCC Type Description
1994 DE017702
1994 DE017703
1994 00110586 1
1998 13285
1998 13421
2015 DF001001
2015 DF001002 1
2016 DF001101
2016 DF001102
2017 DF001201
2017 DF001202
2018 DF001301
2023 DF001402
2023 DF001403
2026 DF001702
2026 DF001703
2027 DF001802
2027 DF001803
2037 DY000501
2037 DY000502
2056 DE000501
2057 DE000601
2059 DE000801
2060 DE000901
2070 DJ000901
2070 DJ000902 F
2070 00072186 I
2098 DH001501 F
2098 OH001504 F
2100 DH001702 F
2100 DH001703 F
2100 00111086 L
2105 DH002201 F
2105 DH002204 F
2105 00063086 L
2109 DH002601 F
2109 DH002602 F
2110 OH002710 F
2122 DH003901
2122 DH003904
2126 D0000302
2126 DD000303
2126 OD062686
2133 DD001002
2138 D0001501
2138 DD001504
2139 DD001601
F WB Carp
F PF Ualleye
. WB Carp
: WB Carp
F PF Pike
: UB Carp
: WP Crappie
UB Sucker
BF Sucker
WB Carp
BF Carp
WB Sucker
PF Spotted Bass
WB Carp
WB Carp
PF White Crappie
PF Lm Bass
WB Carp
WB not available
WP not available
WB Carp
WB Carp
WB Carp
WB Carp
WP Rainbow Trout
WB Longnose Sucker
WP Rainbow Trout
WB not available
PF not available
PF Sauger
WB Catfish
WB Catfish
PF Sauger
WB Carp
WB Carp
WB not available
BF not available
WP Brown Trout
PF Rainbow Trout
WB White Sucker
WB Carp
PF White Crappie
WB Carp
BF Blue Catfish
WB Redhorse Sucker
PF Lm Bass
WB Carp
OIOXIN / FURAN DETECTION LIMITS, pg/g
2378
TCOO
NA
2.16
NA
3.94
NA
NA
NA
NA
NA
NA
1.13
1.99
0.60
0.67
NA
1.94
0.74
NA
1.15
2.35
NA
3.28
NA
NA
2.15
0.50
0.50
0.88
0.36
1.69
NA
NA
0.44
0.58
0.40
NA
0.42
0.27
0.39
0.81
6.49
0.93
NA
1.45
NA
HA
1.02
12378
PECOO
30.99
2.15
112.58
5.18
1.43
6.04
1.70
2.75
2.37
4.90
1.24
3.09
0.52
0.72
1.52
2.52
0.75
2.07
1.94
5.33
6.33
NA
NA
3.50
6.64
1.33
1.16
1.17
0.65
1.35
8.80
8.12
1.14
1.75
1.29
7.28
1.23
0.97
0.92
1.74
9.79
0.77
7.44
5.42
NA
NA
2.75
123478
HXCDO
NA
3.02
NA
1.00
1.65
4.70
1.28
0.97
1.70
NA
2.20
3.37
1.17
NA
1.35
3.37
0.90
1.73
1.50
3.31
1.69
0.78
NA
2.09
13.32
3.61
2.23
1.50
1.47
1.72
2.29
2.94
0.73
1.45
0.79
2.00
1.02
1.96
0.84
0.78
6.14
1.30
NA
1.57
3.52
2.44
2.69
123678
HXCDD
NA
3.02
NA
NA
2.89
NA
1.28
NA
NA
NA
NA
3.37
0.78
1.62
NA
3.37
0.90
NA
2.25
5.80
NA
7.10
NA
NA
13.32
3.61
2.23
1.50
0.73
2.58
NA
23.55
0.73
1.45
0.79
12.01
1.02
1.96
0.84
0.78
NA
1.30
NA
NA
NA
NA
2.69
123789 1234678
HXCDD
NA
3.02
NA
1.00
1.65
3.13
1.28
2.93
1.27
NA
1.10
3.37
0.78
1.08
1.35
3.37
0.90
1.15
1.50
2.48
3.95
0.78
1.25
2.09
13.32
3.61
2.23
1.50
0.73
1.72
2.29
2.94
0.73
1.45
0.79
2.00
1.02
1.96
0.84
0.78
NA
1.30
NA
1.57
NA
NA
2.69
HPCDD
NA
4.19
99.13
NA
3.06
NA
2.24
NA
NA
NA
NA
6.04
NA
NA
NA
NA
5.31
41.78
6.96
NA
NA
NA
NA
NA
19.59
NA
6.12
4.00
NA
5.68
8.87
6.35
NA
5.16
3.58
NA
NA
4.91
NA
NA
NA
3.66
NA
NA
NA
NA
6.49
2378
TCOF
NA
NA
NA
6.02
NA
NA
NA
NA
NA
NA
NA
NA
1.34
NA
NA
0.60
0.23
NA
NA
0.89
NA
NA
NA
NA
NA
0.30
1.75
NA
0.41
0.74
NA
0.50
0.40
0.48
0.20
NA
0.91
0.20
1.18
NA
NA
0.20
0.85
0.35
NA
NA
0.59
12378
PECDF
NA
0.98
NA
NA
1.23
2.45
0.61
1.29
0.70
NA
0.37
0.93
0.25
0.31
0.48
1.21
0.33
0.56
0.93
NA
NA
0.77
7.27
NA
2.58
0.58
0.87
0.51
0.30
0.42
0.50
1.02
0.63
0.90
0.37
0.58
0.49
0.36
0.47
0.88
0.44
0.32
0.64
0.59
NA
NA
0.77
23478
PECDF
NA
0.98
NA
NA
1.05
NA
1.23
NA
1.64
1.82
0.37
0.93
0.25
0.77
0.48
1.21
0.33
0.74
0.62
NA
NA
NA
NA
3.40
2.58
0.58
0.87
0.51
0.30
0.42
2.83
NA
0.63
0.90
0.37
0.58
0.49
0.36
0.47
1.17
0.73
0.32
0.81
0.59
NA
NA
0.77
123478
HXCDF*
NA
1.50
NA
2.91
0.90
NA
0.60
NA
NA
1.23
0.51
1.65
0.36
0.46
0.69
1.63
0.41
1.05
0.78
NA
10.11
0.28
NA
NA
4.51
1.41
0.94
0.66
0.34
0.69
1.60
1.18
0.79
1.46
0.67
0.85
0.86
0.96
NA
1.19
0.39
0.54
0.47
0.80
NA
NA
1.31
123678
HXCDF
NA
1.50
10.18
0.38
0.90
NA
0.60
1.11
0.47
0.61
0.51
1.65
0.36
0.46
0.69
1.63
0.41
0.52
0.78
NA
NA
0.28
NA
1.82
4.51
1.41
0.94
0.66
0.34
0.69
0.96
1.18
0.79
1.46
0.67
0.85
0.43
0.96
0.59
1.19
0.59
0.54
0.47
0.80
3.06
2.82
1.31
123789
HXCDF
3.07
1.50
1.78
0.38
0.90
0.74
0.60
0.24
0.47
0.41
0.51
1.65
0.36
0.46
0.69
1.63
0.41
0.52
0.78
0.77
0.79
0.28
0.58
1.04
4.51
1.41
0.94
0.66
0.34
0.69
0.96
0.89
0.79
1.46
0.67
0.85
0.43
0.96
0.59
1.19
0.39
0.54
0.47
0.80
2.77
2.75
1.31
234678 1234678 1234789
HXCDF
NA
1.50
NA
1.55
0.90
1.87
0.90
NA
NA
0.41
0.51
1.65
0.36
0.46
0.69
1.63
0.41
0.52
0.78
2.72
3.72
0.28
NA
NA
4.51
1.41
0.94
0.66
0.34
0.69
0.96
0.89
0.79
1.46
0.67
0.85
0.43
0.96
0.59
1.19
0.39
0.54
0.47
0.80
NA
NA
1.31
HPCDF
NA
2.94
NA
3.48
1.82
NA
1.26
NA
3.44
1.21
1.25
4.23
NA
NA
1.34
4.74
NA
NA
NA
6.57
NA
NA
NA
NA
6.82
2.13
4.00
NA
NA
1.66
2.79
2.79
1.27
4.13
2.87
NA
1.20
NA
2.40
1.51
NA
NA
NA
1.52
NA
NA
3.24
HPCDF
8.18
2.94
5.14
0.77
1.82
1.57
1.26
0.39
0.87
0.80
1.25
4.23
NA
NA
1.34
3.16
NA
NA
1.12
1.64
2.91
0.80
2.22
3.35
6.82
2.13
4.00
NA
NA
1.66
2.79
2.79
1.27
4.13
2.87
2.52
1.20
NA
1.20
3.77
NA
NA
NA
1.52
2.62
2.59
3.24
D-4-27
-------
Episode SCC Type Description
2139 00001604
2139 00071486
2142 00001902
2142 DD001903
2148 DD002501
2148 DD002504
2151 00002801
2151 DD002803
2152 DD002902
2152 00002903
2190 OG005101
2190 DG005104
2191 DG005205
2191 DG005206
2191 00092486
2194 OG005501
2194 DG005504
2199 DG006001
2199 DG006004
2201 DG006201
2201 DG006204
2205 DG006601
2205 DG006602
2210 DC005401
2211 DC005503
2212 DC005602
2212 OC005605
2215 DC005902
2216 DC006002
2216 DC006003
2220 DC006401
2220 DC006405
2225 DC006902
2225 DC006903
2225 00101387
2227 DC007102
2227 DC007104
2228 DC007201
2228 DC007204
2228 00070286
2231 DC007503
2246 OJ002301
2246 DJ002302
2247 DJ002403
2247 DJ002404
2280 OF005201
2280 DF005204
PF Rainbow Trout
PF Rainbow Trout
WB Catfish
PF Lm Bass
WB Saltwater Catfish
F BF Saltwater Catfish
F PF LM Bass
F WB Spotted Sucker
F PF Lm Bass
F WB Lake Chubsucker
F WB Carp
F PF Bluegill
F WB Carp
F BF Carp
L BF Carp
F WB Carp
F BF Channel Catfish
F WB Carp
F PF Lm Bass
F WB Carp
F PF Bowfin
F WB Carp
F BF Carp
F WB Catfish
F WB Redhorse Sucker
F PF S» Bass
F WB White Sucker
F WB Carp
F PF Brown Trout
F WB White Sucker
F PF Redbreast Sunfish
F WB Catfish
F PF Sm Bass
F WB Shorthead Redhorse
L WB Shorthead Redhorse
F PF Lm Bass
F WB Channel Catfish
F PF Longear Sunfish
F WB Redhorse Sucker
L WB Redhorse Sucker
F WB Gizzard Shad
F BF Bridgelip Sucker
F WB Bridgelip Sucker
F BF Bridgelip Sucker
F WP Mountain Uhitefish
F WB Carp
F BF Channel Catfish
DIOXIN / FURAN DETECTION LIMITS, pg/g
2378
TCOD
NA
NA
1.60
1.02
1.85
0.36
0.29
0.33
0.70
0.51
1.12
0.82
1.59
1.06
1.00
2.46
0.40
NA
1.H
6.01
1.28
1.12
0.66
NA
NA
1.80
NA
2.75
0.34
0.37
0.70
1.10
1.31
NA
NA
0.97
1.65
0.62
2.81
3.40
2.70
0.41
2.20
0.98
NA
0.49
0.93
12378
PECDD
1.50
1.11
NA
0.92
1.61
0.99
1.13
1.03
1.17
1.53
1.87
0.67
4.28
2.37
0.84
0.56
1.65
3.11
1.13
13.63
1.53
1.74
1.12
10.44
1.21
2.74
1.62
4.19
0.70
0.63
1.51
2.62
0.96
NA
NA
0.90
NA
0.97
2.62
3.11
5.30
0.92
5.07
0.94
3.59
1.88
1.08
123478
HXCOO
1.04
0.89
2.47
2.46
1.27
0.77
0.54
0.73
1.55
0.75
1.83
1.20
2.20
1.68
1.12
0.33
1.04
0.88
0.78
18.77
2.38
1.94
0.78
4.78
2.47
2.26
0.20
3.93
0.72
0.71
1.35
1.46
2.47
NA
NA
2.42
2.46
1.51
1.23
1.47
1.20
1.00
1.35
0.86
1.18
1.25
0.67
123678
HXCOD
1.74
1.78
2.85
1.84
1.27
0.77
0.54
0.73
3.10
0.75
3.20
1.20
NA
5.06
NA
NA
3.14
NA
1.17
NA
2.38
1.94
0.78
7.97
NA
2.26
1.66
NA
0.72
1.06
3.39
NA
1.85
NA
NA
1.81
NA
1.51
4.30
NA
6.20
1.00
8.78
NA
NA
1.25
NA
123789 1234678
HXCOO
1.04
0.89
1.38
1.37
1.27
0.77
0.54
0.73
1.55
0.75
1.83
1.20
2.20
1.68
1.12
0.33
0.69
0.88
1.17
11.55
2.38
1.94
0.78
4.78
1.38
2.26
0.20
3.93
0.72
0.71
1.35
0.97
1.38
NA
.44
.35
NA
.51
.23
.47
.90
.00
.35
0.86
1.18
1.25
0.67
HPCOD
NA
NA
NA
1.26
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.60
4.62
NA
4.70
NA
9.92
7.29
5.54
NA
NA
3.82
NA
NA
4.45
2.72
NA
NA
NA
NA
NA
1.96
NA
NA
11.91
NA
NA
9.77
NA
NA
NA
5.70
NA
2378
TCOF
NA
NA
NA
NA
0.90
0.26
0.25
0.55
0.47
0.58
0.90
0.20
NA
1.23
1.20
NA
0.20
1.20
0.45
1.44
0.29
NA
NA
NA
NA
0.86
NA
NA
0.20
NA
0.48
NA
NA
NA
NA
NA
NA
0.47
NA
NA
NA
0.36
5.06
NA
NA
0.38
NA
12378
PECOF
1.11
NA
0.99
0.77
0.81
0.43
0.41
0.48
0.75
0.51
0.79
0.46
NA
0.56
0.49
0.20
0.27
0.20
0.25
1.08
0.67
0.61
0.31
1.50
0.96
1.21
NA
NA
0.35
0.30
0.87
0.52
0.78
NA
NA
0.76
0.77
0.75
1.51
1.41
3.00
0.40
NA
0.32
0.30
0.34
0.39
23478
PECOF
NA
NA
NA
0.85
0.81
0.43
0.41
0.48
0.75
0.51
0.53
0.46
2.65
0.56
0.74
NA
0.27
NA
0.25
1.08
0.67
0.61
0.31
2.26
NA
1.51
NA
NA
0.35
0.30
0.87
NA
0.85
NA
NA
0.83
NA
0.75
2.65
NA
NA
0.40
2.03
1.62
NA
0.34
0.58
123478
HXCOF*
0.58
0.45
2.84
2.83
1.20
0.65
0.82
0.68
1.78
0.74
0.66
1.32
1.13
0.65
0.44
0.20
0.41
NA
0.37
1.83
0.79
1.21
0.50
1.38
NA
1.00
NA
2.37
0.42
0.39
NA
1.75
2.84
NA
NA
2.78
2.82
J.J7
NA
NA
NA
0.46
NA
2.59
0.44
0.76
0.37
123678
HXCOF
0.58
0.45
2.85
2.84
1.20
0.65
0.82
0.68
0.71
0.74
0.88
0.53
1.13
0.65
0.44
0.20
0.41
0.39
0.37
1.83
0.79
1.21
0.50
1.38
2.85
1.00
NA
0.79
0.42
0.39
0.67
0.50
2.85
2.83
2.84
2.79
2.83
0.78
0.68
0.68
0.60
0.46
0.50
0.47
0.44
0.51
0.37
123789
HXCOF
0.39
0.45
2.78
2.77
1.20
0.65
0.82
0.68
0.71
0.74
0.44
0.53
1.13
0.65
0.44
0.20
0.41
0.39
0.37
1.83
0.79
1.21
0.50
1.38
2.78
1.00
0.20
0.79
0.42
0.39
0.67
0.50
2.78
2.76
2.77
2.72
2.76
0.78
0.68
0.68
0.60
0.46
0.50
0.47
0.44
0.51
0.37
234678 1234678 1234789
HXCOF
0.58
0.45
1.96
1.96
1.20
0.65
0.82
0.68
0.71
0.74
0.44
0.53
1.13
0.65
0.44
0.20
0.41
0.39
0.37
1.83
0.79
1.21
0.50
1.38
NA
1.00
0.22
1.58
0.42
0.39
0.67
0.50
1.96
NA
NA
1.92
1.95
0.78
NA
0.68
NA
0.46
NA
NA
NA
0.51
0.37
HPCOF
1.26
NA
NA
1.44
3.48
1.31
0.99
1.23
NA
2.05
NA
NA
NA
2.37
1.35
0.43
1.30
0.75
0.76
5.33
2.52
2.11
NA
4.40
NA
2.81
0.52
NA
0.80
0.98
NA
NA
1.45
NA
NA
1.42
NA
HA
NA
NA
NA
1.11
4.57
NA
NA
NA
0.87
HPCOF
0.63
0.91
2.62
2.61
3.48
1.31
0.99
1.23
NA
1.36
NA
NA
2.89
2.37
1.35
0.43
1.30
0.50
0.76
5.33
2.52
2.11
0.87
4.40
2.62
2.81
0.19
2.70
0.80
0.98
NA
NA
2.62
2.60
2.61
2.56
2.60
JM
NA
NA
1.30
1.11
1.82
0.93
0.93
NA
0.58
D-4-28
-------
Episode SCC Type Description
2280 00062386 L BF Channel Catfish
2283 DF005501 WB Gray Redhorse
2283 DF005502 UP Loogear Sunfish
2290 DD003403 WB Spotted Sucker
2294 DD003801 PF Lm Bass
2294 DD003804 WB Carp
2297 DD004102 WB Carp
2297 DD004103 PF Lm Bass
2298 DD004201 UB Channel Catfish
2298 DD004203 UP Lm Bass
2301 DD004504 UP Rock Bass
2301 00071786 UP Rock Bass
2302 DD004601 WB Ouillback Carpsucker
2304 DD004801 WB Carp
2304 DD004804 PF Lm Bass
2309 DD005301 WB Carp
2309 DD005304 PF Lm Bass
2322 DB001301 UB White Sucker
2322 DB001304 PF Lm Bass
2322 00082686 PF not available
2326 DB001701 WB White Sucker
2326 DB001704 PF Rock Bass
2328 DB001904 PF Chinook Salmon
2329 DB002004 PF Brown Trout
2341 D0006002 PF Lm Bass
2341 DD006003 UB Carpsucker
2355 DA001603 WB White Sucker
2356 DA001702 PF Lm Bass
2356 DA001703 UB White Sucker
2358 DA001901 UP ns
2369 DA003202 PF Lm Bass
2369 DA003203 WB White Sucker
2369 00030387 UB White Sucker
2375 DA003802 PF Pickerel
2375 DA003803 WB White Sucker
2376 DA003903 WB White Sucker
2376 00111886 WB White Sucker
2379 DE005404 PF Lm Bass
2380 DE005501 UB Carp
2383 DE005801 UB Carp
2385 DE006002 WB White Sucker
2385 00101987 WB White Sucker
2387 DE006201 UB Carp
2394 DE006901 UB Carp
2397 DE007201 UB Sucker
2397 DE007204 PF Walleye
2410 DE008501 UB Carp
DIOXIN / FURAN DETECTION LIMITS, pg/g
2378
TCOD
0.40
0.20
0.30
NA
NA
NA
1.25
1.08
0.41
0.07
0.96
1.49
NA
NA
NA
2.39
1.20
0.20
0.36
0.68
0.42
1.17
NA
NA
NA
NA
NA
NA
NA
3.57
1.84
NA
1.73
0.51
NA
3.02
2.85
1.39
NA
NA
NA
NA
1.04
NA
1.09
0.33
NA
12378
PECDD
0.96
0.62
1.40
NA
NA
NA
NA
0.92
2.29
0.26
2.74
2.99
NA
NA
NA
4.74
0.30
0.75
1.75
1.23
4.05
1.85
5.85
3.87
1.12
2.02
NA
0.86
6.24
7.07
2.35
2.01
0.94
0.60
NA
4.44
5.40
2.18
19.70
33.59
NA
NA
0.92
NA
0.87
0.69
55.12
123478
HXCDD
1.32
1.10
1.13
NA
2.46
NA
2.45
2.47
1.60
0.20
2.47
2.87
2.45
NA
NA
5.82
1.00
0.83
.39
.96
.46
.25
.36
.89
2.47
2.46
NA
0.86
1.62
6.62
4.02
1.46
0.70
0.69
NA
1.70
2.41
2.40
NA
NA
2.49
2.46
2.47
NA
0.73
0.80
17.50
123678
HXCDO
0.53
1.10
1.13
NA
NA
3.17
NA
1.84
5.60
0.20
3.71
2.87
2.09
NA
NA
NA
2.10
0.83
1.39
1.30
5.36
3.49
1.36
1.89
NA
NA
NA
1.30
NA
NA
4.02
NA
NA
1.38
NA
2.84
2.41
2.40
38.31
NA
NA
NA
1.85
NA
1.46
0.80
NA
123789
HXCDD
0.53
1.10
1.13
NA
NA
NA
1.37
1.38
1.60
0.20
2.47
2.87
NA
NA
NA
1.94
1.00
0.83
1.39
1.30
1.46
1.25
1.36
1.89
1.38
1.37
NA
0.86
1.62
6.62
4.02
1.09
0.70
0.69
NA
1.70
2.41
2.40
10.10
13.12
1.38
1.38
1.38
NA
1.10
0.80
9.10
1234678
HPCDD
NA
3.10
7.36
NA
NA
NA
NA
1.28
15.47
1.28
19.27
12.94
NA
NA
NA
NA
NA
1.54
2.66
4.86
NA
10.70
3.60
3.09
NA
NA
NA
2.23
NA
NA
3.93
3.69
NA
NA
NA
8.44
6.05
4.28
NA
NA
NA
NA
NA
NA
NA
0.73
106.38
2378
TCDF
NA
0.42
0.41
NA
NA
NA
NA
NA
0.42
0.20
NA
3.23
NA
NA
NA
NA
NA
3.99
NA
0.73
2.81
1.95
NA
NA
NA
NA
NA
NA
NA
NA
0.52
NA
NA
NA
NA
NA
NA
0.57
NA
NA
NA
NA
NA
NA
NA
0.20
NA
12378
PECDF
0.29
0.25
0.52
NA
0.77
1.16
0.77
0.78
1.03
0.20
0.82
0.76
0.77
4.27
NA
0.44
0.30
0.30
0.32
0.36
1.13
0.59
0.87
1.02
NA
NA
NA
0.21
3.73
1.78
1.04
0.47
0.36
0.30
NA
0.58
1.04
0.69
NA
NA
NA
NA
0.78
NA
0.22
0.25
NA
23478
PECDF
0.44
0.25
0.52
NA
0.93
NA
1.16
0.85
1.03
0.20
0.82
0.76
0.84
NA
NA
1.79
0.30
0.30
0.32
0.36
NA
0.59
NA
0.61
NA
NA
NA
0.21
NA
1.78
1.04
0.62
0.36
0.30
NA
NA
NA
0.69
NA
NA
NA
NA
NA
NA
0.22
0.25
NA
123478
HXCDF*
0.28
0.52
0.78
NA
NA
NA
2.82
2.83
0.96
0.20
1.30
1.13
NA
NA
NA
0.92
0.50
0.45
0.56
0.61
0.53
0.72
NA
NA
NA
NA
NA
0.35
0.54
NA
1.98
0.93
NA
0.35
NA
NA
8.62
1.17
NA
29.79
NA
NA
2.84
NA
0.47
0.32
NA
123678
HXCDF
0.28
0.52
0.52
NA
2.83
2.85
2.83
2.85
0.96
0.20
1.30
1.13
2.83
NA
2.84
0.92
0.50
0.45
0.56
0.61
0.53
0.72
0.67
1.01
2.85
NA
2.85
0.35
0.54
2.64
1.98
0.93
0.61
0.35
2.83
0.90
1.72
1.17
5.17
11.67
2.85
2.84
2.85
NA
0.31
0.32
NA
123789
HXCDF
0.28
0.52
0.52
2.73
2.76
2.78
2.76
2.77
0.96
0.20
1.30
1.13
2.76
2.79
2.77
0.92
0.50
0.45
0.56
0.61
0.53
0.72
0.67
1.01
2.78
2.76
2.76
0.35
0.54
2.64
1.98
0.93
0.61
0.35
2.76
0.90
1.72
1.17
0.79
0.99
2.78
2.77
2.78
2.77
0.31
0.32
1.33
234678 1234678 1234789
HXCDF
0.28
0.52
0.52
NA
NA
NA
1.95
1.96
0.96
0.20
1.30
1.13
1.95
NA
1.96
0.92
0.50
0.45
0.56
0.61
0.53
0.72
NA
3.03
NA
NA
NA
0.35
0.54
2.64
1.98
1.86
0.61
0.35
1.95
2.40
1.72
1.17
NA
NA
2.11
1.96
1.96
NA
0.31
0.32
NA
HPCDF
0.46
2.75
3.11
NA
NA
NA
1.44
NA
3.81
0.36
6.61
8.89
NA
NA
NA
6.06
1.40
1.52
2.10
2.30
2.05
1.40
NA
NA
NA
NA
NA
1.13
1.82
36.36
2.75
3.64
NA
0.72
NA
2.74
3.59
3.00
NA
NA
NA
NA
NA
NA
0.71
0.74
42.82
HPCDF
0.46
2.75
3.11
NA
2.61
2.62
2.60
2.62
3.81
0.36
2.64
5.92
2.60
2.63
2.61
2.42
1.40
1.52
2.10
1.53
1.02
1.40
1.37
2.75
2.62
2.61
2.60
1.13
1.82
9.09
2.75
3.64
1.57
0.72
2.61
1.37
3.59
3.00
2.67
2.74
2.62
2.61
2.62
2.61
0.71
0.74
4.50
D-4-29
-------
Episode SCC Type Description
2410 DE008504 F PF Sin Bass
2416 DE009101 F UB Carp
2422 DE009702 F WB Carp
2427 DE010202 F UB Carp
2427 DE010203 F PF Walleye
2427 00102887 L PF Walleye
2429 DE010402 F WB Carp
2429 OE010403 F PF Walleye
2429 00010687 L PF Walleye
24X0 OE010602 f PT Northern Pike
2430 DE010603 F WB Redhorse Sucker
2431 DE010702 F PF Brown Trout
2431 DE010703 F WB Sucker
2432 DE010710 F WB Redhorse Sucker
2432 DE010713 F PF Walleye
2435 OE011001 F WB Longnose Sucker
2435 DE011004 F PF Brook Trout
2437 DEO11202 F PF Walleye
2437 DE011203 F WB Carp
2439 DE011401 F WB Carp
2439 DE011402 F WP Sm Bass
2478 DJ003901 F BF Sucker
2478 DJ003902 F BF Sucker
2500 DC010201 F PF Bass
2500 DC010203 F WB Black Buffalo
2532 OF019302 F PF Lm Bass
2532 OF019303 F WB Carp
2544 DF019202 F WB Blacktail Redhorse
2608 DE014501 F PF Walleye
2608 DE014504 F WB Carp
2618 OE015401 F WB Carp
2618 DE015402 F BF Carp
2618 DE015403 F WB Quillback
2618 00102088 F WB Ouillback
2651 DB008401 F WB White Sucker
2653 DB008503 F WB Carp
2654 DB008601 F WB Carp
2709 DB005101 F WB Catfish
2721 DA006502 F WB Sucker
2722 DA006601 F WB Sucker
2725 DA006301 F WB Sucker
2748 DY006505 F WB Sucker
2748 DY006506 F BF not available
2776 DY007101 F WB Carp
2776 DY007103 F PF Trout
3001 DE019501 f Pf Walleye
3001 DE019502 F WB White Sucker
DIOXIN / FURAN DETECTION LIMITS, pg/g
2378
TCDD
NA
MA
NA
NA
NA
NA
NA
1.19
NA
0.99
0.49
1.70
NA
0.58
NA
0.58
O.S8
0.58
0.58
NA
NA
0.39
0.37
NA
1.62
NA
NA
1.40
NA
NA
NA
NA
NA
NA
NA
NA
1.88
7.87
NA
1.39
NA
0.55
0.81
0.72
1.19
O.JO
0.28
1237B
PECOD
0.95
17.66
NA
NA
0.97
0.92
13.65
1.16
1.25
0.92
1.19
NA
.79
.75
.75
.75
.75
.75
.75
10.82
4.54
.48
.06
.38
.71
.11
NA
0.93
0.95
NA
NA
NA
NA
NA
1.35
NA
1.53
4.80
NA
2.73
NA
1.01
1.11
1.69
0.98
0.37
0.93
123478
HXCOD
0.64
NA
NA
NA
2.40
2.46
17.25
0.63
0.68
2.46
1.88
2.46
2.46
1.45
1.45
1.45
1.45
1.45
1.45
NA
0.81
1.40
1.51
2.70
2.92
2.45
NA
2.10
2.46
NA
NA
2.47
2.62
NA
1.00
NA
1.13
2.79
2.43
3.12
2.46
1.28
1.55
1.97
0.71
0.60
0.90
123678
HXCDO
0.64
NA
NA
NA
1.79
1.84
NA
0.63
1.03
1.84
1.88
1.84
NA
1.45
1.45
1.45
1.45
1.45
1.45
NA
NA
1.40
1.51
2.70
2.92
NA
NA
1.57
1.84
NA
NA
NA
NA
NA
1.33
NA
2.26
5.59
NA
3.12
NA
1.28
1.55
1.97
0.71
0.60
1.21
123789 1234678
HXCOD
0.64
6.65
NA
NA
1.34
1.37
5.07
0.63
0.68
1.37
1.88
1.37
1.37
1.45
1.45
1.45
1.45
1.45
1.45
NA
0.81
1.40
1.51
2.70
2.92
1.37
NA
1.13
1.37
NA
NA
1.45
1.68
1.57
0.66
1.35
1.13
2.79
NA
3.12
NA
1.28
1.55
1.97
0.71
0.60
0.60
HPCDO
4.15
NA
NA
NA
NA
NA
NA
2.84
NA
1.34
3.28
1.49
NA
5.16
5.16
5.16
NA
NA
NA
NA
NA
NA
5.25
NA
4.00
NA
NA
NA
NA
NA
NA
NA
NA
NA
8.55
NA
3.62
NA
NA
8.07
NA
4.60
NA
5.89
2.99
1.21
4.22
2378
TCDF
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.53
NA
NA
NA
NA
NA
NA
0.48
NA
0.48
NA
NA
0.29
0.97
NA
0.45
1.34
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.11
NA
0.26
0.32
1.59
1.62
0.51
2.25
12378
PECDF
0.31
NA
NA
NA
0.75
NA
4.54
0.31
0.55
0.77
0.39
M
0.77
0.90
0.90
0.90
0.90
0.90
0.90
1.91
0.99
0.41
0.46
1.03
0.56
0.80
NA
0.63
0.77
NA
NA
1.13
NA
NA
0.69
NA
0.24
1.86
NA
0.76
NA
0.50
0.43
0.72
0.32
0.20
0.41
23478
PECDF
0.42
HA
NA
NA
1.06
1.09
NA
0.74
0.78
0.85
0.39
NA
1.06
0.90
0.90
NA
0.90
0.90
0.90
NA
NA
0.41
0.46
1.03
0.56
1.07
NA
0.74
NA
NA
NA
NA
NA
NA
0.34
NA
0.59
NA
NA
0.76
NA
0.50
0.43
0.72
0.64
0.20
0.31
123478
HXCDF*
0.29
MA
NA
NA
NA
NA
35.95
0.66
0.30
2.83
0.74
2.83
2.83
1.46
1.46
1.46
1.46
1.46
1.46
NA
NA
0.58
2.08
0.64
1.07
NA
NA
2.74
2.88
NA
NA
NA
2.84
2.83
0.33
NA
0.30
4.43
NA
1.39
NA
0.63
0.65
1.04
0.38
0.21
0.39
A 23678
HXCDF
0.29
HA
NA
NA
2.77
2.84
1.84
0.39
0.30
2.84
0.74
2.84
2.84
.46
.46
.46
.46
.46
1.46
NA
0.37
0.58
0.69
0.64
1.07
2.82
NA
2.29
2.84
4.42
NA
NA
2.85
2.84
0.33
2.78
0.30
1.32
2.81
1.39
NA
0.63
0.65
1.04
0.38
0.21
0.26
123789
HXCDF
0.29
2.18
2.77
2.76
2.70
2.77
1.84
0.26
0.30
2.77
0.74
2.77
2.77
1.46
1.46
1.46
1.46
1.46
1.46
0.46
0.37
0.58
0.69
0.64
1.07
2.75
2.73
2.44
2.77
2.76
2.76
2.78
2.78
2.77
0.33
2.71
0.30
1.32
2.74
1.39
2.77
0.63
0.65
1.04
0.38
0.21
0.26
23467B 1234678 1234789
HXCDF
0.29
2.45
NA
NA
1.90
1.96
1.84
0.26
0.30
1.96
0.74
1.95
1.96
.46
.46
.46
.46
.46
.46
10.41
NA
0.58
0.69
0.64
1.07
1.94
NA
1.70
1.95
NA
2.10
1.96
1.96
1.96
0.33
NA
0.30
1.32
2.51
1.39
NA
0.63
0.65
1.04
0.38
0.21
0.26
HPCOF
1.13
4.61
NA
NA
NA
1.46
NA
0.64
0.61
1.44
2.37
1.44
NA
4.13
4.13
4.13
4.13
4.13
4.13
NA
NA
1.28
1.80
3.36
4.06
1.45
NA
MA
NA
NA
NA
NA
NA
NA
1.33
NA
0.73
NA
NA
3.77
NA
1.37
1.99
NA
MA
0.77
1.38
HPCDF
1.13
2.30
2.61
2.60
2.54
2.61
6.69
0.64
0.61
2.61
2.37
2.61
2.61
4.13
4.13
4.13
4.13
4.13
4.13
1.06
0.70
1.28
1.80
2.24
4.06
2.59
2.57
2.18
2.61
2.61
2.60
2.62
2.62
2.61
1.33
2.56
0.73
NA
2.58
3.77
2.61
1.37
1.99
NA
NA
0.71
0.92
D-4-30
-------
Episode SCC Type Description
3022 DA008401 F US White Sucker
3022 DA008402 F PF Chain Pickerel
3023 DA008501 F PF Sffl Bass
3024 DA008601 F PF Lm Bass
3025 DA008701 F WB White Sucker
3025 DA008702 F PF Chain Pickerel
3026 DA009001 F WB Catfish
3026 DA009002 F PF Lm Bass
3027 DA009301 F WB Sucker
3028 DA008801 F PF Chain Pickerel
3028 OD031787 L PF Chain Pickerel
3034 DG025701
3034 DG025702
3035 DG025801
3035 DG025802
3036 DG025901
3036 DG025902
F WB Carp
F PF Lm Bass
F WB Carp
F PF Sm Bass
F PF Freshwater Drum
F WB Carp
3036 00120287 L PF Freshwater Drum
3037 DG026001
3037 DG026002
3038 DG026101
3038 DG026102
3039 DG026201
3039 DG026202
3040 DG026301
3040 DG026302
3041 DG026401
3041 DG026402
F WB Carp
F PF Black Crappie
F WB Carp
F BF Channel Catfish
F WB Carp
F BF Channel Catfish
F WB Carp
F PF White Crappie
F BF Channel Catfish
WB Carp
3041 00031588 L BF Channel Catfish
3042 DG026501
3042 DG026502
3043 DG026601
3043 DG026602
3043 00111987 L
3044 DG026701
3044 DG026702
3045 DG026801
3045 DG026802
3046 DG026901
3047 DG027001
3047 DG027002
3048 DG027101
3048 DG027102
3049 DG027201
3049 DG027202
F WB Carp
F PF Northern Pike
F WB Carp
F PF Flathead Catfish
PF Flathead Catfish
F WB Carp
F PF Flathead Catfish
F WB Carp
PF Flathead Catfish
F WB Bigmouth Buffalo
F WB Carp
F PF Sm Bass
F WB Carp
PF White Bass
f WB Carp
F PF Crappie
3049 00111087 F PF Crappie
3050 DG027301 F WB Bigmouth Buffalo
DIOXIH / FURAN DETECTION LIMITS, pg/g
2378
TCOO
NA
0.10
0.99
0.20
NA
0.12
NA
NA
1.19
0.11
0.11
NA
1.01
NA
0.16
0.99
1.26
0.99
NA
0.16
NA
NA
NA
1.16
NA
1.01
1.31
1.03
NA
1.30
0.99
NA
NA
NA
NA
NA
NA
0.73
NA
NA
1.00
NA
0.09
NA
1.01
1.13
NA
12378
PECDD
NA
0.49
0.95
0.40
NA
0.32
NA
NA
0.50
0.29
0.19
NA
0.92
NA
0.25
0.92
NA
0.92
NA
0.20
NA
1.50
NA
0.95
NA
0.98
NA
1.23
NA
NA
0.92
2.39
NA
0.91
NA
1.04
6.27
NA
0.94
NA
0.92
NA
0.32
NA
0.92
0.92
1.22
123478
HXCDD
NA
1.04
2.47
3.42
0.76
0.68
2.47
2.47
0.80
0.87
0.22
NA
2.46
NA
0.38
2.46
2.49
2.47
2.46
0.22
NA
2.47
NA
2.46
NA
2.47
2.46
NA
NA
NA
2.46
0.30
2.46
2.45
NA
2.47
1.04
0.22
2.45
NA
2.48
NA
0.44
NA
2.46
2.47
NA
123678
HXCDD
1.82
1.04
1.84
1.14
NA
0.68
NA
1.85
3.61
0.87
0.91
NA
1.84
NA
0.38
1.84
NA
1.84
NA
0.22
NA
NA
NA
NA
NA
1.85
NA
NA
NA
NA
1.84
NA
NA
NA
2.33
NA
NA
NA
NA
NA
1.85
NA
0.44
NA
1.84
1.84
NA
123789 1234678
HXCDD
1.36
1.04
1.38
1.14
0.50
0.68
NA
1.38
0.80
0.87
0.22
NA
1.37
1.55
0.38
1.37
NA
1.38
1.37
0.22
NA
NA
NA
1.38
NA
1.38
NA
1.38
NA
NA
1.37
0.73
1.37
1.37
NA
1.38
2.79
0.22
1.37
1.38
1.38
5.18
0.44
NA
1.38
1.38
1.38
HPCDD
NA
3.08
NA
5.03
NA
NA
NA
NA
4.92
5.09
3.95
NA
1.26
NA
0.69
1.31
NA
1.26
NA
2.29
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.07
NA
1.26
1.26
NA
2378
TCDF
NA
0.20
NA
NA
NA
0.20
NA
NA
NA
0.24
0.20
NA
NA
NA
0.97
0.49
NA
0.49
NA
0.20
NA
0.49
NA
0.49
NA
0.49
0.51
NA
NA
NA
0.48
NA
NA
0.48
HA
0.49
1.97
NA
NA
NA
0.51
NA
NA
NA
NA
0.55
NA
12378
PECDF
NA
0.28
0.77
0.37
0.26
0.21
1.85
0.78
0.20
0.19
0.20
NA
0.77
NA
0.20
0.77
0.78
0.77
0.77
0.20
NA
0.78
NA
0.77
0.87
0.78
0.77
0.78
0.77
NA
0.77
NA
0.77
0.77
NA
0.78
NA
0.20
0.77
NA
0.78
2.78
0.20
1.32
0.77
0.78
NA
23478
PECDF
NA
0.28
0.85
0.37
0.26
0.32
NA
NA
1.30
0.19
0.20
NA
0.85
NA
0.20
0.85
0.85
0.85
0.85
0.20
NA
NA
NA
0.85
NA
0.85
1.17
0.89
NA
NA
0.84
0.90
0.85
0.84
NA
NA
1.51
0.93
0.84
NA
0.85
NA
0.20
NA
0.85
0.85
1.10
123478
HXCDF*
2.80
0.42
2.83
0.51
0.26
0.37
NA
2.84
0.34
0.30
0.20
NA
2.83
NA
0.19
2.83
2.86
2.83
NA
0.20
NA
2.84
NA
2.83
NA
2.84
NA
2.84
NA
NA
2.82
NA
NA
2.82
NA
2.84
NA
0.46
2.82
NA
2.85
NA
0.22
NA
2.83
2.83
2.83
123678
HXCDF
2.81
0.42
2.84
0.34
0.39
0.37
2.85
2.85
0.34
0.30
0.20
3.42
2.84
2.83
0.19
2.84
2.87
2.84
2.84
0.20
NA
2.85
NA
2.84
NA
2.85
2.83
2.85
2.83
NA
2.83
NA
2.84
2.83
2.85
2.85
0.70
0.20
2.83
2.85
2.86
2.81
0.22
3.06
2.84
2.85
2.85
123789
HXCDF
2.74
0.42
2.77
0.34
0.26
0.37
2.78
2.78
0.34
0.30
0.20
2.77
2.77
2.76
0.19
2.77
2.80
2.77
2.77
0.20
2.77
2.78
2.76
2.77
2.75
2.78
2.76
2.78
2.76
0.20
2.76
0.20
2.77
2.76
2.78
2.78
0.28
0.20
2.76
2.78
2.79
0.20
0.22
2.77
2.77
2.77
2.77
234678 1234678 1234789
HXCDF
1.94
0.42
1.96
0.34
NA
0.37
NA
1.96
0.34
0.30
0.20
NA
1.96
NA
0.19
1.95
1.98
1.96
1.96
0.20
NA
1.96
NA
1.96
NA
1.96
1.95
1.96
NA
0.97
1.95
NA
1.95
1.95
2.47
1.96
NA
0.20
1.95
NA
1.97
2.81
0.22
NA
1.96
1.96
NA
HPCDF
NA
1.28
1.45
0.79
NA
3.48
NA
1.45
1.53
0.70
0.27
NA
1.44
NA
0.44
1.44
1.46
1.45
NA
0.35
NA
NA
NA
1.44
NA
1.45
NA
NA
NA
NA
1.44
1.20
NA
1.44
NA
NA
6.04
0.81
1.44
NA
1.45
8.87
0.59
NA
1.45
1.45
NA
HPCDF
2.59
1.28
2.61
0.79
0.85
0.71
2.62
2.62
1.02
0.70
0.27
2.62
2.61
2.60
0.44
2.61
2.64
2.61
2.61
0.23
2.61
2.62
2.60
2.61
2.59
2.62
2.61
2.62
2.60
0.22
2.60
0.20
2.61
2.60
2.62
2.62
1.09
0.20
2.60
2.62
2.63
0.42
0.59
2.61
2.61
2.62
2.62
D-4-31
-------
Episode SCC Type Description
3060 DF009101
3060 DF009102
3061 DF019105
3061 DF019106
3062 DF024024
3062 DF024324
3062 00024324
3062 00071587
3062 SF024324
3063 DF023301
3063 DF023302
3064 DF023305
3064 DF023306
3065 DF023419
3065 DF023420
3065 00022588
3066 DF023503
3066 DF023504
3068 DF024001
3068 DF024002
3069 DF024007
3069 DF024008
3070 DF024009
3070 DF024010
3071 DF024014
3072 DF024017
3072 OF024018
3072 00040788
3073 DF019221
3073 DF019222
3073 00121587
3074 DF026017
3075 DF024102
3076 DF028502
3076 DF028503
3077 DF019113
3077 DF019114
3077 OD121087
3078 DF009118
3078 DF023815
3078 DF023816
3078 SF009118
3079 DF019205
3079 DF019206
3080 DF023317
3080 DF023318
3080 00040987 L
WB Flathead Catfish
WB Sm Buffalo
PF Bass
WB Sucker
WB Blue Catfish
BF Grass Carp
BF Grass Carp
WB Blue Catfish
BF Grass Carp
WB Sea Catfish
PF Spotted Seatrout
Shellfish
PF Spotted Seatrout
BF Bigmouth Buffalo
WB Flathead Catfish
WB Flathead Catfish
WB Catfish
PF Freshwater Drum
Oysters
PF At I. Croaker
WB Sea Catfish
PF Trout
WB Croaker
PF Sheepshead
WB Carp
WB Carp
PF White Bass
PF White Bass
WB White Sucker
PF Sm Bass
WB White Sucker
PF Brown Trout
BF Sea Catfish
WB Channel Catfish
PF Spotted Bass
PF Flathead Catfish
WB Redhorse Sucker
PF Flathead Catfish
WB Carp
WB Sm Buffalo
PF Black Crappie
WB Carp
PF White Bass
WB Carp
WB Carp
PF im Bass
WB Carp
D10X1N / FURAN DETECTION LIMITS, pg/g
2378
TCDD
0.40
NA
NA
2.18
NA
NA
NA
NA
NA
NA
1.02
1.15
0.99
NA
NA
NA
NA
0.99
NA
1.30
NA
.00
.07
NA
NA
.06
.06
.19
NA
1.10
NA
0.75
1.00
NA
0.99
0.99
1.09
0.99
NA
NA
NA
NA
1.23
NA
NA
NA
NA
12378
PECOD
0.30
2.19
NA
NA
NA
1.03
0.93
NA
0.35
NA
0.92
0.92
0.96
NA
NA
NA
1.83
0.92
1.06
0.91
NA
0.92
0.92
1.16
NA
2.11
0.92
0.92
1.05
0.92
NA
0.48
0.92
NA
0.93
0.92
0.99
0.92
NA
NA
1.47
NA
0.91
1.08
NA
0.92
NA
123478
HXCDD
0.38
0.43
3.18
0.27
2.46
2.47
2.46
2.46
1.37
2.59
2.45
2.46
2.45
2.46
NA
NA
NA
2.46
2.45
2.46
2.69
2.47
2.46
NA
2.46
2.47
2.47
2.47
2.47
2.47
NA
0.65
2.47
NA
2.46
2.44
2.45
2.45
NA
NA
2.46
NA
2.45
2.46
NA
0.20
NA
123678
HXCDD
0.38
3.92
NA
NA
NA
1.84
1.84
NA
0.67
NA
1.83
NA
1.83
NA
NA
NA
NA
1.84
1.97
NA
NA
1.85
NA
1.83
NA
1.85
1.85
1.85
NA
1.85
NA
0.65
1.85
NA
1.84
1.83
1.83
1.83
NA
NA
1.85
NA
1.83
NA
NA
NA
NA
123789 1234678
HXCDD
0.38
0.43
NA
0.27
1.44
1.38
1.37
1.37
1.98
NA
1.37
1.37
1.37
NA
1.38
1.36
NA
1.38
1.37
1.37
1.38
1.38
NA
1.37
1.37
1.38
1.38
1.38
1.38
1.38
1.38
0.65
1.38
1.37
1.38
1.37
1.37
1.37
NA
NA
1.37
NA
1.37
1.37
NA
0.20
NA
HPCDD
0.89
8.35
NA
NA
NA
NA
NA
NA
NA
NA
1.58
NA
NA
NA
NA
NA
NA
NA
NA
1.80
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.31
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3.49
NA
2378
TCDF
0.41
NA
0.60
1.17
NA
NA
NA
NA
NA
NA
NA
NA
0.52
NA
NA
NA
NA
NA
NA
NA
0.50
0.49
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.20
0.49
NA
0.49
0.48
0.86
0.48
NA
NA
NA
NA
NA
NA
NA
1.09
NA
12378
PECDF
0.20
0.72
0.77
NA
NA
0.77
NA
NA
0.45
NA
NA
0.77
0.77
0.77
NA
NA
NA
0.77
0.77
0.99
0.77
0.78
0.77
0.77
0.95
0.78
0.78
0.78
0.78
0.78
0.77
0.20
0.78
0.77
0.77
0.77
0.77
0.77
0.77
NA
1.03
NA
0.77
NA
NA
0.28
NA
23478
PECDF
0.20
NA
0.99
1.27
NA
NA
NA
0.84
NA
NA
0.84
0.84
0.84
NA
NA
NA
NA
0.85
1.08
0.84
NA
0.85
0.84
0.84
NA
0.95
0.85
0.85
NA
0.85
0.87
0.20
0.85
NA
0.85
0.84
0.84
0.84
NA
NA
0.85
NA
NA
NA
NA
0.20
NA
123478
HXCDF*
0.20
1.27
NA
2.73
NA
2.83
2.82
NA
0.97
NA
NA
2.82
2.81
2.82
NA
NA
NA
2.83
2.82
2.83
2.83
2.84
2.82
2.81
NA
2.84
2.84
2.84
2.84
2.84
2.83
0.23
2.84
2.83
2.83
2.81
2.81
2.81
2.83
NA
2.83
0.87
2.81
NA
NA
0.20
NA
123678
HXCDF
0.20
0.20
2.84
1.10
2.84
2.84
2.83
2.84
1.21
NA
NA
2.84
2.82
2.83
2.84
2.82
NA
2.84
2.83
2.84
2.84
2.85
2.83
2.83
NA
2.85
2.85
2.85
2.85
2.85
2.84
0.23
2.85
2.84
2.84
2.82
2.82
2.82
2.84
2.81
2.84
1.04
2.82
2.84
0.42
0.20
0.68
123789
HXCDF
0.20
0.20
2.77
0.22
2.77
2.77
2.76
2.77
1.40
2.77
2.76
2.76
2.75
2.76
2.77
2.75
2.77
2.77
2.76
2.77
2.77
2.78
2.76
2.76
2.77
2.78
2.78
2.78
2.78
2.78
2.77
0.23
2.78
2.77
2.77
2.75
2.75
2.75
2.77
2.74
2.77
0.89
2.75
2.77
0.20
0.20
0.20
234678 1234678 1234789
HXCDF
0.20
0.20
1.96
NA
2.07
1.96
1.95
1.99
1.57
2.14
1.95
1.95
1.95
1.95
NA
1.94
NA
1.96
1.95
1.95
1.96
1.97
1.95
1.95
NA
1.96
1.96
1.96
1.96
1.96
1.96
0.23
1.96
NA
1.96
1.94
1.94
1.95
1.96
1.95
1.95
0.86
1.95
NA
NA
0.20
NA
HPCDF
0.49
0.47
NA
NA
1.48
1.45
1.44
NA
0.66
NA
NA
NA
NA
NA
NA
NA
NA
1.45
1.44
1.44
NA
1.45
NA
NA
NA
.45
.45
.45
NA
.45
.45
0.77
1.45
NA
NA
1.43
1.44
1.44
NA
1.43
1.44
0.66
1.44
NA
NA
0.40
NA
HPCDF
0.49
0.47
2.61
0.34
2.6T
2.61
2.60
2.61
1.66
2.61
2.60
2.61
2.60
2.60
2.61
2.59
2.62
2.61
2.60
2.61
2.61
2.62
2.61
2.60
2.61
2.62
2.62
2.62
2.62
2.62
2.61
0.77
2.62
2.61
2.61
2.59
2.59
2.60
2. 61
2.59
2.61
1.66
2.60
2.61
0.24
0.20
0.26
D-4-32
-------
DIOXIN / FURAN DETECTION LIMITS, pg/g
Episode SCC Type Description
3081 DF024105 F PF White Bass
3081 DF024106 WB Catfish
3082 DF023401 WB Carp
3082 DF023402 PF Lm Bass
3082 00120787 PF Lm Basa
3083 DF023405 WB Black Bullhead
3083 DF023406 PF Lm Bass
3084 DF024109 F WB Channel Catfish
3084 00072188 L WB Channel Catfish
3085 DF024114 F PF Black Drum
3086 DF023409 F WB Catfish
3086 OF023411
3087 DF023413
3087 DF023414
3087 DF023415
3087 DF023416
3087 00023414
3087 00072387
3087 SF023414
3087 SF023415
3088 DF023417
3088 DF023418
3089 DF019209
3089 DF019210
3090 OF019213
3090 DF019214
3091 DF019217
3091 DF019218
3092 DF023501
3092 DF023502
3093 DF024011
3093 DF024118
PF Black Drum
WB Carp
PF White Crappie
WP Bluegill
WP Lm Bass
PF White Crappie
WB Carp
PF White Crappie
WP Bluegill
WB Channel Catfish
PF Bluegill
PF White Crappie
WB Carp
PF White Crappie
WB Channel Catfish
WB River Carpsucker
PF White Crappie
WB Carp
PF Yarmouth
PF Lm Bass
WB Sm Buffalo
3093 00080387 L UB Sm Buffalo
3094 DC017201 F BF Channel Catfish
3094 00092988 L BF Channel Catfish
3095 DC038801 F BF Brown Bullhead
3095 DC038802 F WB Channel Catfish
3096 DC035001 F BF Brown Bullhead
3096 DC035002 F WB Channel Catfish
3096 00052488 F WB Channel Catfish
3097 DC038701 F BF Brown Bullhead
3097 DC038702 F WB Carp
3098 OC038601 F WB White Sucker
3098 DC038602 F PF American Eel
3098 00032587 L WB White Sucker
3100 DC019701 F PF White Perch
3100 DC019702 F WP Winter Flounder
2378
TCOD
NA
NA
1.43
1.04
1.12
1.08
0.11
HA
NA
NA
4.32
0.99
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.99
1.05
0.98
1.27
0.99
0.98
NA
0.98
1.01
NA
1.07
NA
NA
NA
5.16
NA
NA
NA
NA
NA
NA
HA
NA
1.60
1.25
12378
PECDD
5.39
2.89
NA
0.93
1.01
NA
0.20
NA
NA
1.46
NA
0.92
NA
NA
NA
1.97
NA
NA
NA
NA
0.92
0.94
0.98
1.04
0.91
NA
0.92
0.91
NA
0.94
0.92
NA
NA
NA
NA
NA
4.92
1.07
NA
NA
4.78
NA
NA
HA
NA
NA
1.07
123478
HXCDD
0.76
NA
3.57
2.43
2.43
NA
0.20
2.47
2.47
2.46
NA
2.46
4.93
2.45
2.46
2.46
2.46
NA
1.11
1.36
2.46
2.46
2.45
2.46
2.44
2.46
2.46
2.44
NA
2.45
2.46
NA
NA
2.46
2.46
2.46
3.37
2.46
3.69
NA
18.44
2.47
4.01
2.73
0.29
2.47
2.56
123678
HXCDD
NA
NA
NA
1.82
1.81
NA
0.55
2.51
NA
NA
NA
1.84
NA
1.83
NA
1.97
NA
NA
0.72
NA
NA
1.84
1.83
NA
1.82
NA
1.84
1.82
NA
1.83
1.84
NA
NA
NA
NA
NA
NA
NA
NA
NA
6.27
NA
NA
NA
NA
NA
1.91
123789 1234678
HXCDD
0.68
NA
NA
1.36
1.35
NA
0.20
1.38
NA
1.41
1.55
1.37
NA
1.37
1.37
1.38
1.37
2.94
1.32
1.98
NA
1.37
1.37
1.38
1.36
NA
1.38
1.36
NA
1.37
1.37
NA
NA
1.37
NA
1.38
NA
1.37
2.12
NA
3.13
NA
0.44
NA
NA
1.38
1.43
HPCDD
NA
NA
NA
NA
NA
NA
2.56
NA
NA
NA
NA
1.32
NA
1.25
2.37
NA
NA
NA
NA
NA
NA
NA
1.29
NA
1.37
NA
NA
1.25
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
24.85
15.14
NA
NA
NA
NA
NA
2378
TCDF
NA
0.50
NA
NA
NA
NA
0.20
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.52
0.48
NA
0.48
0.48
0.86
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.20
NA
NA
NA
12378
PECDF
0.20
0.77
NA
0.77
0.76
0.77
0.20
0.87
NA
NA
NA
NA
NA
NA
NA
0.96
NA
NA
NA
NA
0.77
0.77
0.77
0.77
0.76
NA
0.77
0.76
0.77
0.77
0.77
0.77
0.77
0.88
0.77
NA
NA
0.85
NA
NA
1.87
NA
0.51
0.20
0.43
NA
1.14
23478
PECDF
0.44
NA
1.76
0.84
0.83
NA
0.20
NA
NA
NA
NA
0.84
NA
NA
NA
NA
NA
NA
NA
NA
0.85
0.84
0.84
NA
0.84
NA
0.85
0.84
1.53
0.84
0.84
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.20
NA
NA
NA
123478
HXCDF*
0.20
2.82
NA
2.80
2.79
2.83
0.20
2.84
NA
NA
NA
2.82
NA
2.81
2.83
2.83
2.82
2.94
0.94
0.96
2.83
2.82
2.82
2.83
2.81
2.82
2.83
2.80
2.89
2.82
2.83
NA
2.83
NA
NA
NA
NA
2.83
NA
NA
1.71
NA
0.21
0.20
1.21
NA
2.94
123678
HXCDF
0.20
2.83
3.19
2.81
2.80
2.84
0.20
2.85
2.85
NA
3.93
2.83
NA
2.82
2.84
2.84
2.84
NA
1.18
1.20
2.84
2.83
2.83
2.84
2.82
2.83
2.84
2.82
2.84
2.83
2.84
3.70
2.84
NA
NA
NA
3.85
2.84
3.82
NA
0.85
NA
0.20
0.20
0.30
2.85
2.95
123789
HXCDF
0.20
2.76
2.76
2.74
2.73
2.77
0.20
2.78
2.77
2.77
2.77
2.76
2.76
2.75
2.77
2.77
2.76
2.78
1.07
1.40
2.77
2.76
2.76
2.77
2.75
2.76
2.77
2.74
2.77
2.76
2.77
3.29
2.77
2.77
2.77
2.76
2.77
2.77
2.77
2.78
0.51
2.78
0.20
0.20
0.21
2.78
2.88
234678 1234678 1234789
HXCDF
0.20
1.95
2.16
1.93
1.93
1.95
0.20
1.96
1.96
NA
NA
1.95
NA
1.95
1.96
1.96
1.95
NA
1.03
1.57
1.96
1.95
1.95
1.96
1.94
1.95
2.14
1.94
1.96
1.95
1.96
3.23
1.95
1.96
NA
NA
3.06
1.96
NA
NA
0.85
NA
2.83
NA
NA
1.96
2.03
HPCDF
0.32
NA
NA
1.46
NA
1.44
0.27
1.45
NA
NA
NA
1.44
1.76
1.44
1.44
1.44
1.44
NA
0.66
0.70
1.44
1.44
1.44
NA
1.43
1.76
NA
1.43
NA
1.44
1.44
1.45
1.57
NA
NA
NA
2.45
1.44
3.25
2.81
1.37
NA
NA
NA
NA
1-45
NA
HPCDF
0.20
2.60
2.61
2.58
2.57
2.61
0.20
2.62
2.62
NA
2.61
2.60
2.60
2.60
2.61
2.61
2.61
2.61
1.65
2.07
2.61
2.60
2.60
2.61
2.59
2.60
2.61
2.59
2.61
2.60
2.61
2.62
2.61
2.61
2.61
2.60
2.61
2.61
2.61
2.62
0.91
2.62
0.35
0.20
0.40
2.62
2.71
D-4-33
-------
Episode SCC Type Description
3101 DC019901
3103 DC036201
3103 DC036202
3104 DC020001
3104 DC020002
3105 DF025001
3105 DF025002
3106 DE026801
3106 DE026802
3107 DE026901
3108 DE027001
3108 DE027002
3109 DE025001
3109 DE025002
3110 DE022501
3111 DHO 15801
3111 DH015802
3112 DE022401
3112 DE022402
3113 OE021101 1
3113 DE021102 1
3114 DE021201 I
3115 OE021301
3115 DE021302
3117 DE021501
3117 DE021502
3118 DE021601
3118 DE021602
3118 OE021603
3118 SE021602
3119 DE021701
3119 DE021702
3120 DE021801
3120 DE021802 f
3122 DE022001 F
3122 DE022003 F
3122 DE022004 F
3125 DE022301 F
3125 DE022302 F
3125 00120888 L
3132 DE023201
3132 DE023202
3134 DE023401
3134 DE023403
3134 DE023405
3134 DE023406
3135 DE023501
PF Brown Trout
WB Channel Catfish
WB Carp
PF Lm Bass
WB Carp
WB Carp
PF Lm Bass
PF Walleye
PF White Bass
WB Carp
PF Walleye
WB Carp
WB Carp
PF Sm Bass
BF Carp
PF walleye
WB Silver Redhorse
WB Carp
PF Wat I eye
' BF Channel Catfish
' BF Carp
: BF Carp
WB Carp
BF Catfish
PF Lake Trout
PF Brown Trout
PF Walleye
WB Carp
WB Carp
WB Carp
WB Carp
PF Lm Bass
WB Carp
PF Bass
WB Carp
WB Redhorse Sucker
PF Sm Bass
WB Carp
PF White Bass
PF White Bass
WB Carp
WB Channel Catfish
PF Crappie
WB Carp
WB Carp
WB Sucker
WB Carp
010XIN / FURAN DETECTION LIMITS, pg/g
2378
TCOO
1.88
3.67
NA
1.24
NA
NA
0.99
NA
NA
2.38
0.98
NA
NA
NA
1.67
0.09
1.16
NA
1.26
1.60
NA
NA
NA
NA
NA
2.44
NA
NA
NA
NA
4.64
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3.71
NA
NA
NA
12378
PECDO
1.00
NA
1.42
0.95
2.99
NA
0.91
0.98
NA
NA
1.03
NA
NA
0.97
NA
0.23
2.64
NA
1.06
NA
NA
1.35
NA
NA
NA
NA
1.73
NA
NA
NA
NA
1.06
5.20
1.53
NA
0.22
0.24
NA
1.02
0.92
NA
NA
0.93
NA
NA
1.26
1.49
123478
HXCOD
2.46
NA
NA
2.44
NA
2.45
2.45
2.46
2.46
2.45
2.45
2.47
2.43
2.44
NA
0.29
0.20
NA
2.46
2.45
2.46
2.68
3.45
2.46
2.45
2.52
2.47
NA
NA
NA
0.59
0.24
NA
0.89
NA
0.32
0.32
NA
2.47
2.46
NA
2.63
2.49
2.43
2.45
2.46
2.47
123678
HXCOD
1.84
NA
NA
1.83
NA
2.05
1.83
NA
2.55
NA
1.83
NA
NA
1.83
NA
0.29
NA
NA
1.84
NA
NA
NA
NA
NA
NA
NA
1.84
NA
NA
NA
NA
2.60
NA
0.89
NA
1.51
0.32
NA
1.85
1.84
NA
NA
1.86
NA
NA
1.84
NA
123789
HXCDD
1.37
NA
.37
.36
NA
.37
.37
.37
.37
.36
.36
NA
1.36
1.36
NA
0.29
0.20
NA
1.37
1.37
1.72
1.38
NA
NA
1.60
1.41
1.38
1.37
1.37
1.22
1.31
0.24
0.20
0.89
NA
0.32
0.32
1.38
1.38
1.38
NA
NA
1.39
1.36
1.37
1.38
1.38
1234678
HPCDD
1.27
NA
NA
NA
NA
NA
NA
NA
HA
NA
1.25
NA
NA
1.25
NA
2.26
2.57
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.34
NA
NA
NA
NA
111.71
NA
3.92
NA
2.21
NA
NA
NA
NA
NA
NA
1.27
NA
NA
NA
NA
2378
TCDF
NA
0.70
NA
NA
NA
NA
0.48
NA
NA
NA
NA
NA
0.49
NA
NA
0.28
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12378
PECOF
NA
NA
NA
0.77
NA
0.77
0.77
0.77
HA
NA
0.77
NA
0.76
0.78
NA
0.20
0.31
1.20
0.77
1.08
NA
NA
NA
0.95
NA
1.65
0.98
NA
NA
NA
0.38
0.37
NA
0.48
1.98
0.31
0.30
NA
0.88
0.83
1.62
1.45
0.78
NA
NA
NA
0.78
23478
PECDF
NA
NA
NA
0.84
NA
NA
0.84
0.89
1.94
NA
0.84
NA
1.01
1.03
NA
0.20
0.63
1.80
0.84
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.31
1.17
NA
0.60
NA
NA
0.40
NA
1.26
NA
NA
NA
0.86
NA
NA
NA
1.47
123478
HXCDF*
2.82
NA
NA
2.80
NA
NA
2.82
2.83
3.01
3.72
2.81
NA
NA
2.81
NA
0.20
0.20
3.39
2.83
2.81
NA
2.83
NA
3.04
NA
2.83
2.83
2.82
NA
NA
1.25
0.20
NA
0.57
NA
0.20
0.20
NA
2.84
2.83
NA
NA
2.86
NA
NA
2.83
2.84
123678
HXCDF
2.83
NA
2.84
2.82
NA
2.83
2.83
2.84
2.84
2.81
2.82
3.29
2.80
2.82
2.81
0.20
0.20
2.85
2.84
2.82
NA
2.84
2.89
2.84
NA
2.84
2.85
NA
NA
NA
0.57
0.20
0.58
0.20
NA
0.20
0.20
NA
2.85
2.84
2.91
2.82
2.87
2.80
2.82
2.84
2.85
123789
HXCDF
2.76
2.77
2.77
2.75
2.74
2.76
2.76
2.77
2.77
NA
2.75
2.78
2.73
2.75
2.74
0.20
0.20
NA
2.77
2.75
2.77
2.77
2.76
2.77
2.76
2.77
2.78
2.76
2.77
0.88
0.20
0.20
0.20
0.20
2.76
0.20
0.20
2.78
2.78
2.77
2.76
2.75
2.80
2.73
2.75
2.77
2.78
234678 1234678 1234789
HXCDF
1.95
NA
NA
1.94
NA
1.95
1.95
1.96
1.99
NA
1.94
NA
NA
1.94
NA
0.20
0.20
2.32
1.96
1.95
NA
1.96
1.95
1.96
NA
1.96
NA
1.95
1.96
0.86
NA
0.28
NA
0.20
NA
0.40
0.20
2.13
1.96
1.96
NA
NA
1.98
2.06
1.95
1.96
2.18
HPCDF
1.44
NA
NA
1.43
NA
NA
NA
NA
NA
NA
1.43
NA
NA
1.43
NA
0.28
0.26
NA
1.44
1.44
NA
1.45
NA
2.13
1.44
1.44
1.48
NA
NA
NA
1.36
0.72
NA
0.73
NA
0.25
0.25
NA
1.45
1.47
NA
NA
1.46
1.59
1.46
1.45
NA
HPCDF
2.60
2.61
2.61
2.59
2.59
2.60
2.60
2.61
2.61
2.59
2.60
NA
2.57
2.59
2.59
0.28
0.26
2.61
2.61
2.60
2.61
2.61
2.60
2.61
2.60
2.61
2.62
2.60
2.61
1.65
0.27
0.36
0.21
0.48
2.61
0.25
0.25
2.62
2.62
2.65
2.60
2.59
2.64
2.57
2.60
2.61
2.62
D-4-34
-------
Episode SCC Type Description
3136
3137
3137
3138
3138
3140
3141
3141
3141
3142
3143
3143
3143
3144
3145
3145
3146
3146
3146
3146
3147
3148
3148
3149
3150
3151
3151
3151
3152
3161
3161
3162
3162
3162
3162
3162
3162
3162
3163
3163
3163
3163
3164
3164
3165
3165
3165
DE023602
DE023701
DE023702
DE023801
DE023802
DE024002
DE024102
DE024103
SE024102
DE022502
DE024401
DE024402
DE024403
DE024901
DE026601 I
00071988 1
DE026701 1
DE026702 1
00060288 1
SE026701
DC035201
OE027101
DE027103
OC038501
DA008901
DA009101
DA009102
00072887
DA009201
DC019801
OC019802
OJ022121
DJ022122
DJ022123 1
DJ022403 1
DJ024001 1
DJ025103 C
00041889 (
DJ022402 t
DJ022404 1
DJ024002 1
DJ025102 (
00015701 1
DD015702 1
DD015703 I
DD015704 1
00031788 1
F PF
F W8
F PF
F we
F PF
F UB
F UB
PF
UB
UB
PF
UB
UB
• UB
: UB
: UB
c PF
. UB
UB
UB
UB
PF
UB
UB
UB
PF
UB
UB
BF
UB
UB
UB
1
: PF
UP
)
)
1
1
: UP
)
' PF
' UB
; PF
• UB
. PF
Walleye
Redhorse Sucker
Walleye
Carp
Sm Bass
Carp
Carp
Northern Pike
Carp
Carp
Rotten (catf)
White Bass
Carp
Carp
N. Redhors
N. Redhorse
Carp
Walleye
Carp
Carp
Carp
Carp
Walleye
White Sucker
White Sucker
White Sucker
Sm Bass
White Sucker
White Sucker
Black Bullhead
White Sucker
Big Skate
Rat fish
Dungeness Crab
Quill back Rock fish
Starry Flounder
Hepatopancreas.Crab
Hepatopancreas
Dungeness Crab
Dungeness Crab
Starry Flounder
Hepatopancreas.Crab
Lm Bass
Carp
Lm Bass
Redhorse Sucker
Lm Bass
DIOXIN / FURAN DETECTION LIMITS, pg/g
2378
TCOO
0.97
1.35
1.00
NA
1.11
NA
NA
NA
NA
NA
1.33
1.00
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.30
0.51
MA
NA
NA
NA
NA
1.34
NA
NA
NA
1.61
1.12
NA
NA
NA
NA
2.24
NA
NA
1.64
NA
1.46
NA
NA
12378
PECDO
0.90
1.29
0.92
NA
1.22
1.35
NA
NA
NA
NA
1.49
0.99
NA
NA
1.09
NA
NA
0.97
NA
NA
NA
NA
0.91
0.52
NA
NA
1.05
NA
NA
NA
NA
NA
1.03
1.81
1.04
NA
NA
NA
NA
NA
NA
NA
64.57
NA
1.89
NA
1.86
123478
HXCDD
2.41
2.45
2.47
3.21
2.46
2.95
6.72
2.47
NA
NA
2.45
2.47
NA
2.46
2.46
2.47
NA
2.47
2.46
NA
2.52
NA
2.45
0.81
NA
2.47
2.45
2.73
2.45
NA
NA
2.46
2.45
2.74
2.45
2.47
NA
NA
2.46
2.45
2.47
2.47
2.46
2.46
2.46
NA
2.47
123678
HXCDD
1.80
1.83
1.85
2.41
NA
NA
NA
NA
NA
NA
3.93
1.85
NA
2.32
NA
NA
NA
1.84
NA
NA
NA
NA
1.84
2.43
NA
NA
1.83
NA
NA
NA
NA
NA
NA
3.56
1.83
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
123789 1234678
HXCDD
1.34
1.37
1.38
1.88
1.37
1.38
NA
1.38
NA
NA
.37
.38
NA
.37
.37
.38
3.58
1.38
NA
NA
1.38
NA
1.37
0.81
NA
NA
1.37
NA
1.37
NA
NA
1.65
1.37
1.56
1.37
NA
NA
NA
5.94
1.40
1.38
NA
NA
NA
1.43
2.13
1.38
HPCDD
1.23
NA
1.34
1.26
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.93
NA
NA
1.25
NA
NA
NA
NA
NA
2.01
NA
1.41
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2378
TCDF
0.50
NA
0.55
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.73
12378
PECOF
0.76
0.89
0.78
NA
0.83
0.87
NA
NA
NA
NA
1.34
NA
NA
NA
NA
0.78
NA
0.78
NA
NA
HA
NA
0.77
0.25
NA
NA
0.77
NA
NA
NA
NA
NA
NA
NA
1.01
NA
NA
NA
NA
NA
0.78
NA
4.24
NA
0.77
NA
0.78
23478
PECDF
0.83
1.29
0.85
7.13
NA
NA
NA
NA
NA
NA
1.38
NA
NA
NA
NA
NA
NA
0.85
NA
NA
NA
NA
NA
0.25
2.23
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.87
NA
NA
NA
NA
NA
NA
NA
193.32
NA
NA
NA
NA
123478
HXCDF*
2.77
2.82
2.84
2.83
2.82
2.83
NA
2.84
NA
NA
2.81
2.84
NA
2.83
2.83
2.83
NA
2.83
NA
NA
NA
NA
2.82
3.33
NA
NA
2.81
NA
NA
2.80
NA
NA
NA
NA
2.81
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
123678
HXCDF
2.78
2.83
2.85
2.84
2.84
2.84
NA
2.85
NA
NA
2.83
2.85
3.82
2.84
2.84
2.85
NA
2.85
NA
NA
2.85
3.48
2.83
0.33
4.61
2.85
2.82
2.84
2.83
2.81
NA
NA
3.37
NA
2.82
NA
NA
NA
NA
7.19
2.85
NA
2.84
NA
2.84
3.31
2.85
123789
HXCDF
2.71
2.76
2.78
2.77
2.76
2.77
2.77
2.78
0.89
2.76
2.76
2.78
2.75
2.77
2.77
2.77
2.77
2.77
2.77
0.88
2.78
2.74
2.76
0.33
NA
2.78
2.75
2.77
2.76
2.74
2.78
2.77
2.76
2.77
2.75
2.77
2.77
2.77
2.77
2.76
2.77
2.77
2.77
2.77
2.77
2.77
2.78
234678 1234678 1234789
HXCDF
1.91
1.95
1.96
1.96
1.95
1.96
NA
1.96
NA
NA
1.95
1.96
NA
1.96
1.96
1.96
NA
1.96
NA
NA
NA
NA
1.95
0.33
NA
2.71
1.95
NA
1.95
1.98
NA
1.96
1.95
1.96
1.94
2.19
NA
NA
1.98
1.95
1.96
2.54
NA
3.08
NA
NA
NA
HPCDF
1.41
1.44
1.45
1.44
1.44
1.45
NA
NA
NA
NA
1.45
1.45
NA
1.44
1.44
1.45
NA
1.45
NA
NA
1.54
NA
1.44
0.51
NA
NA
NA
2.26
1.59
1.83
NA
2.23
1.44
1.79
1.43
NA
NA
NA
NA
1.79
NA
NA
NA
NA
NA
NA
NA
HPCDF
2.55
2.60
2.62
2.61
2.61
2.61
2.61
2.62
1.81
2.60
2.60
2.62
2.59
2.61
2.61
2.62
2.62
2.62
2.61
1.84
2.62
2.59
2.60
0.51
NA
2.62
2.60
2.61
2.60
2.59
2.62
2.61
2.61
2.61
2.59
2.61
2.62
2.61
2.61
2.60
2.62
2.61
2.61
2.61
2.61
2.61
2.62
D-4-35
-------
Episode SCC Type Description
3166 DD015705 F
3166 DD015706 F
3167 DD015707 F
3167 DD015708 F
3167 00040588 L
3167 SD015708
3168 DD015711
3168 DD015712
3168 S0015711
3169 D0015713
3170 DD015715 F
3171 DD015717 F
3172 DD015719 F
3172 DD015720 F
3173 DD015721 F
3173 DD015722 F
3173 00070689 L
3174 00015723 F
3174 DD015724
3175 DD015801
3175 DD015802
3176 DD015803
3176 DD015804
3177 DD015805 F
3177 00015806 F
3178 DD015807 F
3178 00015808 F
3179 00015809 F
3179 00015810
3180 00015812
3181 D0015813
3181 00015814
3182 DD015815 F
3182 DD015816 F
3183 00015817 F
3183 00015818 F
3184 00015819 F
3184 DD015820
3185 00015821
3185 DD015822
3185 SD015821
3186 DD015823
3186 D0015824
3187 00015902 F
3188 00015903 F
3188 00015904 F
3189 D0015905 F
PF Watteye
UB White Sucker
PF Lm Bass
WP Bluegill
PF Lm Bass
WP Bluegill
WB Carp
PF Lm Bass
WB Carp
WB Black Redhorse
WB Spotted Sucker
WB Spotted Sucker
WB Carp
PF Lm Bass
PF Lm Bass
WB Channel Catfish
PF Lm Bass
PF Lm Bass
WB Channel Catfish
WB Channel Catfish
PF Lm Bass
WB Spotted Sucker
PF Lm Bass
WB Carp
PF Lm Bass
WB North Hogsucker
PF Redeye Bass
WB Golden Redhorse
PF Lm Bass
PF Lm Bass
PF Lm Bass
WB Carp
PF Rock Bass
WB Carp
WB Carp
PF Sauger
WB Carp
PF White Crappie
WB Channel Catfish
PF Lm Bass
WB Channel Catfish
PF Spot
WP Southern Flounder
WP Sunmer Flounder
WB Carp
PF Lm Bass
WB Carp
2378
TCDO
1.00
1.01
NA
NA
NA
NA
NA
NA
NA
0.99
1.16
1.07
NA
NA
0.99
NA
0.99
0.99
1.10
NA
1.02
1.23
1.11
1.06
1.04
1.00
1.00
NA
0.99
0.99
1.12
NA
1.18
2.29
NA
NA
NA
1.04
NA
NA
NA
1.22
NA
1.02
2.70
1.39
2.36
12378
PECDD
0.92
1.00
NA
NA
NA
NA
NA
1.00
NA
1.10
0.92
0.92
NA
0.92
0.93
NA
0.92
0.92
0.92
NA
0.94
1.68
1.14
1.52
0.92
0.97
0.92
NA
1.13
0.93
0.92
NA
0.92
1.64
NA
0.92
NA
0.92
NA
NA
NA
0.92
1.04
1.21
NA
1.00
NA
D10X1N / FURAN DETECTION LIMITS, pg/9
123478 123678 123789 1234678 2378 12378
HXCDD HXCOO HXCOD HPCOD TCOF PECDF
2.47 1.85 1.38 NA 0.49 0.78
2.47 NA 1.38 NA NA 0.78
3.40
NA
NA
NA
NA
2.47
NA
2.46
NA
2.47
NA
2.47
2.46
2.46
2.46
2.46
2.46
NA
2.46
2.47
2.46
NA
2.47
2.47
2.47
2.56
2.46
2.46
2.47
NA
2.46
2.48
2.46
2.46
NA
2.47
NA
NA
NA
2.46
2.46
2.47
NA
2.46
NA
NA 2.53
NA NA
NA 2.30
NA NA
NA NA
1.85 1.38
NA 2.44
1.84 1.37
NA NA
1.84 1.38
NA NA
1 .85 1 .38
1.84 1.37
NA NA
1.84
1.84
1.84
NA
NA
NA
1.84
NA
.85
.85
.85
NA
.84
.84
.84
NA
NA
3.04
3.23
1.84
.37
.37
.37
NA
.37
.38
.37
.38
.38
.38
.38
.38
.37
.37
.38
NA
.37
.38
.37
.38
NA NA
1.84 1.38
NA NA
NA NA
NA NA
1.84 1.37
NA 1.38
NA NA
NA NA
1.84 1.37
NA 1.36
NA
NA
NA
NA
NA
NA
NA
4.43
NA
NA
NA
NA
1.26
NA
1.26
1.26
NA
NA
NA
NA
1.34
NA
NA
NA
1.26
NA
1.26
1.62
1.32
NA
NA
NA
NA
NA
NA
1.44
NA
NA
NA
1.32
NA
NA
NA
1.83
NA
0.49
0.67
0.49
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.50
NA
0.49
0.49
NA
0.49
0.53
NA
0.56
NA
0.49
0.84
0.49
NA
0.59
0.60
0.49
NA
NA
NA
NA
0.93
1.24
0.52
NA
NA
NA
1.00
NA
0.71
NA
0.57
NA
0.77
NA
0.77
NA
NA
0.78
NA
0.77
0.77
0.77
NA
0.78
0.77
NA
0.77
0.77
0.77
0.78
0.77
0.78
0.77
0.60
0.78
0.78
0.78
0.78
0.77
0.77
0.78
2.18
0.77
NA
NA
0.77
0.80
0.78
1.18
NA
NA
0.79
0.77
0.77
NA
0.77
0.77
23478
PECDF
0.85
NA
0.94
1.33
1.03
NA
NA
0.85
NA
0.95
0.86
0.85
NA
0.85
0.85
NA
0.85
0.84
0.93
NA
0.85
0.96
0.85
NA
0.85
0.85
0.85
0.92
0.85
0.85
0.85
NA
0.86
NA
NA
0.85
1.04
0.85
1.57
NA
NA
0.86
0.85
0.85
NA
0.84
NA
123478
HXCDF*
2.84
2.84
NA
NA
NA
NA
NA
2.84
NA
2.82
2.83
2.83
NA
2.84
2.83
2.83
2.83
2.82
2.82
NA
2.83
2.84
2.83
3.79
2.84
2.84
2.84
NA
2.83
2.82
2.83
NA
2.82
2.88
NA
2.83
NA
2.83
NA
NA
NA
2.83
2.83
2.83
NA
2.82
NA
123678
HXCDF
2.85
2.85
NA
NA
3.69
NA
3.12
2.85
1.28
2.83
2.84
2.84
NA
2.85
2.84
2.84
2.84
2.83
2.83
2.85
2.84
2.85
2.84
2.85
2.85
2.85
2.85
2.85
2.84
2.84
2.85
NA
2.84
2.84
NA
2.84
2.85
2.85
NA
NA
NA
2.84
2.84
2.84
NA
2.83
2.81
123789
HXCDF
2.78
2.78
2.77
2.77
2.76
0.86
2.77
2.78
1.40
2.76
2.77
2.77
2.76
2.78
2.77
2.77
2.77
2.76
2.76
2.77
2.77
2.78
2.77
2.78
2.78
2.78
2.78
2.78
2.77
2.76
2.77
2.77
2.76
2.77
2.77
2.77
2.77
2.77
2.77
2.75
0.87
2.77
2.77
2.77
2.78
2.76
2.74
234678 1234678 1234789
HXCDF HPCOF HPCDF
1.96 1.45 2.62
1.96 1.45 2.62
NA
NA
NA
NA
1.96
1.96
1.57
.95
.95
.96
.95
.96
.95
.96
.96
.95
.95
NA
1.96
1.96
1.95
NA
1.96
1.97
1.96
NA
1.96
1.95
1.96
NA
1.95
1.96
NA
1.96
NA
1.96
NA
1.94
NA
1.95
1.96
1.96
NA
1.95
NA
NA
NA
NA
NA
1.44
1.45
0.67
2.25
NA
1.45
NA
1.45
1.44
NA
1.44
1.44
1.44
NA
1.44
1.45
1.44
NA
1.45
NA
1.45
NA
1.44
1.44
1.45
NA
1.44
1.45
NA
1.44
NA
1.45
NA
NA
NA
1.44
1.45
1.45
NA
1.44
NA
2.61
NA
2.61
NA
2.61
2.62
1.87
3.82
2.61
2.61
2.60
2.62
2.61
2.61
2.61
2.61
2.60
2.62
2.61
2.62
2.61
2.62
2.62
2.62
2.62
2.62
2.61
2.61
2.62
2.61
2.61
2.61
2.61
2.61
2.62
2.62
2.75
2.59
NA
2.61
2.61
2.61
2.62
2.60
2.59
D-4-36
-------
Episode SCC Type Description
3189 DD015906 F PF Ltn Bass
3190 DD015907 F WB Carp
3190 DD015908 F PF Lm Bass
3191 DJ024003 F UP Starry Flounder
3191 DJ024005 M Soft Shell Clams
3192 OJ024007 F WP Starry Flounder
3192 DJ024009 M Soft Shell Clams
3192 00020789 I Soft Shell Clams
3193 DC039001 F PF Striped Bass
3193 00039001 L PF Striped Bass
3195 DH020104 F UB Carp
3195 DH020105 F WB Chub
3196 DH020108 F WB Sucker
3197 DH020110 F WB Sucker
3198 DH020111 F WB Sucker
3199 DH020101 F WB Carp
3199 DH020103 F WB Carp
3200 DH020112 F WB Sucker
3201 DJ024012 F WB Carp
3203 DJ024018 F WB Carp
3205 DJ024024 M Crayfish (whole)
3206 DJ022301 M WB Crayfish
3206 DJ024102 F PF Lm Bass
3206 OJ024103 F WB Sucker
3208 DJ024109 F WB Sucker
3212 DJ024121 F WB Carp
3212 00050388 L WB Carp
3216 DJ023707 F PF Squawfish
3216 DJ023708 F WB Sucker
3216 00091688 F WB Sucker
3217 DJ023709 F PF Whitefish
3217 OJ023710 F WB Sucker
3218 DJ023711 F PF Squawfish
3218 DJ023712 F WB Sucker
3219 DJ023713 F WB White Sturgeon
3219 DJ023714 F PF White Sturgeon
3220 DJ023902 F PF Squawfish
3220 DJ023903 F WB Bridgelip Sucker
3220 00012288 F PF Squawfish
3221 DJ022405 F WB Carp
3221 OJ023904 F BF Channel Catfish
3221 DJ023905 F WB Sucker
3222 DJ023906 F PF Squawfish
3222 DJ023907 F WB Sucker
3223 DJ023717 F WP Starry Flounder
3224 DJ023715 M Soft Shell Clams
3226 DJ023721 M Pacific Oysters
DIOXIN / FURAN DETECTION LIMITS, pg/g
2378
TCOD
NA
NA
NA
1.01
1.07
NA
1.19
1.23
NA
1.26
1.68
NA
1.08
1.12
NA
NA
1.09
NA
NA
NA
0.99
NA
NA
NA
1.12
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.11
1.23
12378
PECOD
0.93
NA
0.95
0.98
0.91
1.09
0.92
0.92
1.28
1.31
1.42
NA
NA
1.04
NA
NA
0.97
1.17
NA
NA
0.92
NA
1.41
NA
0.97
0.93
0.91
NA
NA
NA
NA
NA
NA
1.48
0.92
0.92
NA
NA
1.18
NA
NA
NA
1.14
NA
0.97
0.91
0.92
123478
HXCOD
2.45
NA
2.46
2.47
2.45
2.45
2.46
2.46
2.47
2.46
2.46
2.46
NA
2.46
2.46
2.47
2.47
2.46
NA
3.47
2.47
2.64
2.46
NA
2.48
2.47
2.45
2.47
2.48
2.46
NA
2.46
2.46
2.46
2.46
2.47
2.46
2.98
2.45
2.46
2.47
2.44
2.47
2.46
2.46
2.45
2.47
123678
KXCDD
1.83
NA
.84
.85
.84
.83
.84
.84
NA
1.86
2.06
NA
NA
1.84
NA
NA
1.85
1.84
NA
NA
1.85
NA
NA
NA
1.85
1.85
1.83
NA
NA
NA
NA
1.84
NA
NA
1.84
1.84
NA
1.84
1.96
NA
NA
1.83
NA
NA
NA
NA
1.84
123789 1234678
HXCDD
1.37
NA
.37
.38
.37
.37
.37
.37
.38
.38
.37
.37
.36
.37
.38
NA
1.38
1.37
NA
NA
1.38
NA
1.38
NA
1.38
1.38
1.37
1.38
NA
NA
1.35
1.37
1.37
1.38
1.37
1.38
.37
.37
.37
.37
.38
.36
.38
.37
.37
.82
.38
HPCOD
1.25
NA
1.26
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.65
NA
NA
NA
NA
NA
NA
2.27
NA
NA
NA
NA
1.91
3.20
NA
NA
1.93
NA
NA
NA
1.47
2378
TCOF
0.72
NA
NA
0.49
NA
NA
NA
NA
NA
NA
1.09
NA
NA
NA
NA
NA
1.05
NA
NA
NA
0.57
NA
NA
NA
NA
0.61
0.77
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12378
PECOF
0.77
0.88
0.77
0.78
0.77
0.77
0.77
0.77
0.77
1.03
0.79
0.87
0.77
0.77
NA
0.78
0.90
0.77
NA
NA
0.78
NA
0.84
NA
0.78
0.78
0.77
NA
NA
0.87
0.82
0.77
NA
0.83
NA
0.77
NA
NA
0.77
NA
0.77
0.77
0.78
0.77
0.77
0.77
0.78
23478
PECOF
0.84
NA
0.84
0.85
0.84
NA
0.85
0.84
NA
NA
1.27
NA
0.84
0.85
NA
0.91
0.93
NA
NA
NA
0.85
NA
NA
NA
0.85
0.85
0.84
NA
NA
NA
NA
0.85
NA
1.18
NA
0.85
1.03
NA
NA
NA
NA
NA
NA
NA
1.24
0.87
0.95
123478
HXCDF*
2.82
3.57
2.82
2.84
2.82
2.81
2.83
2.82
2.83
2.83
2.83
2.82
NA
2.83
2.83
2.84
2.84
2.82
NA
NA
2.84
NA
2.83
NA
2.85
2.84
2.81
2.84
2.84
2.83
NA
NA
2.82
NA
2.82
2.83
2.82
2.82
2.82
2.83
2.83
NA
2.84
2.83
2.82
NA
2.83
123678
HXCDF
2.83
2.76
2.83
2.85
2.83
2.83
2.84
2.83
2.84
2.84
2.84
2.83
2.82
2.84
2.84
2.85
2.85
2.83
NA
NA
2.85
NA
2.84
2.79
2.86
2.85
2.82
2.85
2.86
2.84
2.79
2.84
2.83
2.84
2.83
2.84
2.83
2.83
2.83
2.84
2.84
2.82
2.85
2.84
2.83
2.83
2.85
123789
HXCDF
2.76
2.69
2.76
2.78
2.76
2.76
2.77
2.76
2.77
2.77
2.77
2.76
2.75
2.77
2.77
2.78
2.78
2.76
2.77
2.79
2.78
NA
2.77
2.72
2.79
2.78
2.75
2.78
2.78
2.77
2.72
2.77
2.76
2.77
2.76
2.77
2.76
2.76
2.76
2.77
2.77
2.75
2.78
2.77
2.76
2.76
2.77
234678 1234678 1234789
HXCDF
1.95
NA
.95
.96
.95
.95
.96
1.95
1.96
1.96
1.96
1.95
NA
1.96
1.96
1.96
1.96
1.95
NA
NA
1.96
NA
1.96
NA
1.97
1.96
1.94
1.96
1.97
1.96
NA
NA
1.95
.96
.95
.96
.95
.95
.95
.96
.96
.94
.96
.95
.95
.95
.96
HPCDF
1.44
NA
1.44
1.45
NA
NA
NA
NA
1.45
1.44
NA
NA
NA
1.44
1.47
NA
1.45
1.44
NA
NA
1.45
NA
NA
NA
1.45
1.45
1.44
1.45
NA
NA
NA
1.44
1.44
NA
1.44
1.45
1.44
1.46
1.44
1.44
1.45
1.43
1.45
NA
NA
NA
1.45
HPCDF
2.60
2.53
2.60
2.62
2.60
2.60
2.61
2.61
2.61
2.61
2.61
2.61
2.59
2.61
2.61
2.62
2.62
2.60
2.61
2.63
2.62
NA
2.61
2.56
2.63
2.62
2.59
2.62
2.62
2.61
2.56
2.61
2.61
2.61
2.60
2.61
2.60
2.60
2.60
2.61
2.61
2.59
2.62
2.61
2.60
2.60
2.62
D-4-37
-------
Episode SCC Type Description
3227 DJ023723 M Pacific Oysters
3231 DJ023911 F UB Carp
3234 DH020301 F UP Squawfish
3235 DH020303 F UB White Sucker
3236 DH02030S F UB Largescale Sucker
3236 OH020306 F PF Brown Trout
3237 DH020307 F PF Rainbow Trout
3237 DH020308 F UB Largescate Sucker
3238 DJ023918 F UP Dolly Varden
3238 00080888 F UP Dolly Varden
3241 DJ023924 F UP Dolly Varden
3244 DJ023622 F UB Coast Sculpin
3245 DJ023623 F UP Spotted Ratfish
3245 DJ023624 F UP Flathead Sole
3246 OJ022108 F PF Red Striped Rockf ish
3246 DJ022109 F UP Flathead Sole
3248 DJ022502 F UB Composite Bottom
3249 OJ022504 F UB Sucker
3250 DJ022506 F UB Sucker
3252 DJ022510 F UB Sucker
3252 00082288 L UB Sucker
3256 DJ022517 F PF SM Bass
3256 DJ022518 F UB Sucker
3258 DC038901 F PF Spot
3258 DC038902 F UB Croaker
3259 DB000466 F UB Goldfish
3259 DB069101 F UB Sucker
3260 DB000493 F UB Carp
3261 DY026002 F UB Striped Mullet
3262 or026004 F UB Tilapia Tilapia
3264 DY022602 F UB Hornyhead Turbot
3266 DY022702 F UB Channel Catfish
3267 DY022101 F PF Rainbow Trout
3267 OY022102 F UB Sacramento Sucker
3267 00020288 L PF Rainbow Trout
3269 DY022106 F UB Channel Catfish
3270 DY022107 F PF Squawfish
3270 DY022108 F UB Sucker
3270 SY022108 F UB Sucker
3271 DY022110 F UB Sucker
3272 Dr022111 F PF Leopard Shark
3272 DY022112 F UB White Surf perch
3273 DY022113 F WB Sculpin
3273 DY022114 F UB Surf Smelt
3274 OY022116 F WB Sculpin
3275 DY022118 F UB Sucker
3276 DY022119 F WB Walleye
2378
TCOO
1.01
NA
1.15
NA
NA
.08
.25
.37
.11
.04
NA
.11
.02
.11
.14
0.95
1.01
1.00
1.10
NA
NA
NA
NA
NA
1.01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.74
NA
NA
NA
NA
0.99
NA
NA
1.23
1.11
0.99
NA
12378
PECOO
1.52
NA
0.94
NA
NA
NA
0.98
1.15
0.95
0.92
1.21
0.94
0.91
NA
0.92
0.88
0.95
0.92
1.30
1.16
1.05
0.92
0.93
2.89
0.92
NA
1.68
1.25
1.98
0.96
NA
1.57
1.14
0.97
1.28
NA
NA
1.03
0.33
1.00
0.92
NA
1.35
1.07
0.93
1.00
NA
D10X1N /
123478 123678
NXCOO NXCDD
2.47 2.81
2.67 NA
2.53 1.90
2.51 NA
NA NA
2.47 2.72
2.46 1.84
2.47 1.85
2.46 1.84
2.46 1.84
2.46 NA
2.46 1.84
2.43 1.82
2.46 2.01
2.46 1.84
2.36 1.76
2.47 1.85
2.47 1.85
2.45 NA
2.47 1.87
2.47 NA
2.46 1.84
2.40 1.79
2.61 3.20
2.47 NA
3.12 NA
NA NA
2.47 2.06
NA NA
2.46 NA
2.47 NA
2.46 1.84
2.46 1.84
2.47 1.85
2.47 1.84
2.47 NA
2.47 NA
2.46 1.84
1.04 0.65
2.44 NA
2.46 NA
2.70 NA
2.47 NA
2.47 1.84
2.49 1.86
2.46 1.84
2.45 NA
FURAN DETECTION
123789 1234678
HXCDD HPCOO
NA NA
1.37 NA
1.42 NA
1.39 NA
1.39 NA
1.38 2.09
1.37 1.26
1.38 1.59
1.38 NA
1.37 NA
1.38 NA
1 .37 NA
1.36 NA
1.38 NA
1.38 3.00
1.32 NA
1.38 NA
1.38 NA
1 .37 NA
1.38 NA
1.38 NA
1 .37 NA
1.34 NA
1.47 5.25
1.39 NA
NA NA
1.37 NA
1.38 NA
NA NA
1 .37 NA
1.53 NA
1 .38 NA
1.37 2.60
1.38 NA
1.38 NA
1.38 NA
1.38 2.27
1.38 NA
1.22 NA
1.36 NA
1.37 NA
NA NA
1.38 NA
1.38 NA
1.39 NA
1.38 NA
NA NA
LIMITS,
2378
TCOF
NA
NA
0.91
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.25
0.52
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.81
NA
NA
NA
NA
0.66
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.49
NA
pg/9
12378
PECDF
0.77
NA
0.80
0.83
0.82
0.99
0.77
0.81
0.77
0.77
0.81
0.88
0.77
0.77
0.77
0.74
0.78
0.78
0.77
0.78
0.78
0.77
0.75
NA
NA
0.77
NA
NA
NA
0.84
0.92
0.77
NA
0.78
0.90
0.81
0.78
0.77
0.43
0.77
0.77
NA
NA
0.77
0.78
0.77
0.77
23478
PECDF
1.22
2.34
0.87
NA
NA
1.08
1.06
1.40
0.85
0.85
1.02
0.92
0.84
1.08
0.85
0.81
0.85
0.85
NA
0.97
NA
0.84
0.82
NA
0.85
NA
NA
NA
NA
0.89
NA
NA
NA
0.99
NA
NA
NA
0.96
NA
0.84
1.01
NA
NA
0.85
0.85
0.85
NA
123478
HXCOF*
2.83
NA
2.91
2.86
2.86
2.84
2.82
2.84
2.83
2.83
2.83
2.83
2.80
2.83
2.83
2.71
2.84
2.84
2.82
2.83
2.84
2.82
2.76
2.87
NA
NA
2.83
2.84
NA
2.82
2.86
2.83
2.83
2.84
2.83
2.84
2.84
2.83
0.93
2.80
2.82
2.83
NA
2.83
2.86
2.83
2.81
123678
HXCDF
2.84
2.84
2.92
2.87
2.87
2.85
2.83
2.85
2.84
2.84
2.84
2.84
2.81
2.84
2.84
2.72
2.85
2.85
2.83
2.85
2.85
2.83
2.77
2.90
2.85
NA
2.84
2.85
2.83
2.84
2.85
2.84
2.84
2.85
2.85
2.85
2.85
2.84
1.23
2.81
2.84
NA
2.85
2.84
2.87
2.84
2.82
123789 234678 1234678 1234789
HXCDF HXCDF HPCOF HPCDF
2.77 1.96
2.76 NA
2.85 2.01
2.80 1.97
2.80 1.98
2.78 .96
2.76 .95
2.78 .96
2.77 .96
2.77 .95
2.77 .96
2.77 .96
2.74 .93
2.77 .96
2.77 .96
2.65 .87
2.78 .96
2.78 .96
2.76 .95
2.77 .96
2.78 .96
2.76 .95
2.70 .91
NA 2.61
NA 2.61
1.49 2.69
NA 2.64
NA 2.64
1.45 2.62
.44 2.61
.45 2.62
.45 2.61
.44 2.61
.44 2.61
.44 2.61
.43 2.58
.45 2.61
.44 2.61
.38 2.50
NA 2.62
.45 2.62
NA 2.60
.45 2.62
.45 2.62
.44 2.61
NA 2.54
2.81 .99 1.45 2.62
2.78 NA
2.77 .96
2.77 .96
2.78 .96
2.76 NA
2.76 .95
2.78 .96
2.77 .96
2.77 1.96 1
2.78 1.96
2.77 1.96
2.78 1.96
2.78 1.96
2.77 1.96
NA 2.62
NA 2.61
NA 2.61
I. 76 2.62
NA 2.60
NA 2.61
NA 2.62
.45 2.61
.44 2.61
.45 2.62
.45 2.62
.45 2.62
.45 2.62
.45 2.61
0.96 0.95 0.70 2.07
2.74 1.94
2.76 1.95
2.77 1.96
2.77 NA
2.77 1.96
2.80 1.97
2.77 1.96 1
2.75 1.94
.43 2.58
.44 2.61
.63 2.61
NA 2.62
.45 2.61
.46 2.64
.45 2.61
NA 2.59
D-4-38
-------
Episode SCC Type Description
3276 OY022120 F PF Broun Rockfish
3278 DY022124 F WB Sacramento Sucker
3281 DY022205 F W8 Sucker
3282 DY022207 F UB Carp
3283 DY022209 F UB Carp
3285 DY022212 F WP Stingray
3285 DY022213 F WB Diamond Turbot
3286 DY022215 F UB Carp
3287 DY022216 F UB Tilapia Zilli
3288 DY022218 F UB Sucker
3288 00060188 F UB Sucker
3289 DY022219 F WP Bocaccio
3289 DY022220 F UB Sculpin
3290 OY022221 F PF Redear Sunfish
3290 DY022222 F WB Btackfish
3294 DJ022111 F UP True Cod
3294 DJ022113 M Mussel
3295 DJ022114 F UP Atlantic Salmon
3296 DB040101 F WB White Sucker
3297 DB041501 F UB Carp
3297 DB041504 F PF Sm Bass
3297 SB041501 F UB Carp
3298 DB041601 F WB Carp
3298 08041604 F PF Ira Bass
3298 00112988 L PF Lm Bass
3299 DB040601 F UB White Sucker
3299 DB040604 F PF Lm Bass
3300 DB040201 F WB White Sucker
3300 08040204 F PF Sm Bass
3300 SB040201 F WB White Sucker
3301 DB041101 F WB Carp
3301 DB041104 F PF Northern Pike
3301 00092088 L WB Carp
3301 SB041101 F UB Carp
3302 DB041901 F UB White Sucker
3302 08041904 F PF Lm Bass
3303 DB042301 F WB White Sucker
3304 DB041001 F PF Northern Pike
3304 DB041004 F WB White Sucker
3305 DB042001 F WB Channel Catfish
3305 DB042004 F PF Sm Bass
3306 DB041801 F WB White Sucker
3307 DB042101 F WB White Sucker
3307 00100588 L WB White Sucker
3308 DB040001 F PF Northern Pike
3308 00030689 L PF Northern Pike
3309 DB041301 F WB White Sucker
OIOX1N / FURAN DETECTION LIMITS, pg/g
2378
TCOD
1.13
0.99
0.99
1.70
NA
NA
1.76
NA
NA
1.09
1.20
0.99
1.20
1.07
NA
1.02
0.99
1.11
1.34
NA
1.14
NA
NA
0.99
0.99
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.48
NA
NA
NA
1.11
1.01
NA
12378
PECDD
0.98
0.92
1.15
1.23
NA
NA
NA
NA
0.99
0.99
1.14
0.93
0.97
0.96
NA
0.94
0.92
0.96
1.04
NA
0.93
NA
NA
0.92
0.92
NA
NA
NA
1.02
NA
NA
0.95
NA
NA
NA
0.92
NA
0.94
NA
NA
0.94
1.11
1.41
1.12
0.93
0.94
0.97
123478
HXCOO
2.42
2.46
2.46
2.56
2.50
NA
2.46
NA
2.46
2.47
2.45
2.45
2.46
2.47
NA
2.47
2.46
2.47
2.44
2.78
2.46
NA
NA
2.46
2.47
NA
2.46
2.46
2.46
1.10
NA
2.46
5.04
NA
2.46
2.47
2.46
2.45
2.45
2.63
2.45
2.46
2.43
2.46
2.47
2.47
2.47
123678
HXCDD
NA
1.84
1.84
1.91
NA
NA
NA
NA
.84
.85
.83
.83
.84
.85
NA
1.85
1.84
NA
1.83
NA
1.84
NA
NA
1.84
1.84
NA
1.84
2.06
1.84
0.67
NA
1.84
NA
NA
2.05
1.85
NA
1.84
NA
NA
.83
.84
.82
.84
.84
1.84
NA
123789 1234678
HXCDD
1.35
1.38
1.37
1.44
1.40
NA
NA
NA
1.37
1.38
1.37
1.37
1.37
1.38
NA
.38
.38
.38
.36
NA
.37
.24
NA
.38
.38
.37
.37
.37
1.38
1.31
NA
1.38
NA
1.70
1.38
1.38
1.37
1.37
1.37
1.38
1.37
1.37
1.36
1.37
1.38
1.38
1.38
HPCDD
NA
NA
NA
2.27
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.41
1.50
NA
NA
NA
NA
NA
NA
1.34
1.36
NA
NA
NA
1.26
NA
NA
1.35
NA
NA
NA
NA
NA
1.25
NA
NA
1.25
NA
NA
1.58
1.30
1.26
NA
2378
TCDF
NA
0.49
0.71
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.60
NA
NA
0.55
NA
NA
NA
0.51
NA
NA
0.51
0.49
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.65
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12378
PECOF
0.76
0.77
0.77
0.98
NA
NA
1.05
NA
0.77
0.78
0.77
0.85
0.77
0.78
NA
0.78
0.77
0.78
0.77
NA
0.77
NA
NA
0.77
0.77
NA
NA
NA
0.80
NA
NA
0.79
NA
NA
NA
0.78
0.77
0.77
NA
NA
0.77
NA
1.04
NA
0.77
0.77
0.78
23478
PECOF
NA
0.85
0.84
NA
NA
NA
NA
NA
0.85
NA
NA
0.90
0.84
0.85
NA
0.85
0.85
0.85
NA
NA
NA
NA
NA
0.85
0.85
NA
NA
NA
1.59
NA
NA
1.08
NA
NA
NA
0.88
NA
0.91
NA
NA
1.00
NA
NA
NA
0.85
0.85
0.86
123478
HXCDF*
2.78
2.83
2.82
2.83
NA
NA
2.91
2.93
2.83
2.84
2.81
2.82
2.82
2.84
NA
2.84
2.83
2.84
2.81
NA
NA
NA
NA
2.83
2.83
NA
NA
NA
2.83
NA
NA
2.83
NA
NA
NA
2.84
2.83
2.82
2.82
NA
2.81
2.83
2.79
2.83
2.83
2.83
2.84
123678
HXCOF
2.79
2.84
2.84
2.84
2.89
3.36
NA
NA
2.84
2.85
2.83
2.83
2.83
2.85
NA
2.85
2.84
2.85
2.82
NA
NA
NA
NA
2.84
2.84
NA
3.48
2.84
2.84
1.17
NA
2.84
NA
NA
2.84
2.85
2.84
2.83
2.83
NA
2.82
2.84
2.81
2.84
2.84
2.84
2.85
123789
HXCDF
2.72
2.77
2.76
2.77
2.82
2.78
2.73
2.81
2.77
2.78
2.76
2.76
2.76
2.78
2.73
2.78
2.77
2.78
2.75
2.77
2.76
0.87
2.77
2.77
2.77
2.77
2.76
2.77
2.77
1.06
2.78
2.77
2.77
1.07
2.77
2.78
2.77
2.76
2.76
2.77
2.75
2.77
2.74
2.77
2.77
2.77
2.78
234678 1234678 1234789
HXCDF
1.92
1.96
1.95
.96
.99
NA
.93
.99
.95
.96
.95
.95
.95
.96
NA
1.96
1.96
1.96
1.94
2.37
1.95
NA
NA
1.96
1.96
NA
1.95
1.96
1.96
1.03
NA
1.96
NA
NA
1.96
1.96
.96
.95
.95
.97
.94
.95
.93
.96
.96
.96
1.96
HPCOF
NA
1.44
1.44
1.45
NA
NA
1.59
NA
NA
1.45
1.44
1.44
1.44
1.45
NA
1.45
1.45
1.45
1.43
NA
1.44
NA
NA
1.44
1.45
NA
NA
NA
1.44
0.65
NA
1.45
NA
NA
NA
1.45
NA
1.44
1.44
1.59
1.43
1.44
1.43
1.44
1.45
1.45
NA
HPCOF
2.57
2.61
2.61
2.61
2.66
2.62
2.57
2.65
2.61
2.62
2.60
2.60
2.60
2.62
2.57
2.62
2.61
2.62
2.59
NA
2.61
1.81
2.78
2.61
2.61
NA
2.60
2.61
2.61
1.64
2.62
2.61
2.67
2.07
2.61
2.62
2.61
2.60
2.60
2.62
2.59
2.61
2.58
2.61
2.61
2.61
2.62
D-4-39
-------
Episode SCC Type Description
3310 DC032701
3310 DC032702
3311 DC032801
3311 DC032802
3312 DC033101
3312 DC033102
3313 DC033201
3313 OC033202
3314 DC033301
3314 DC033302
3314 SC033301
3314 SC033302
3315 DC033401
3316 DC033501
3316 DC033502
3317 DC033601
3317 DC033602
3317 SC033601
3317 SC033602
3318 OC033701
3318 DC033702
3319 DB041401
3319 00063088
3320 DB041412
3321 DB040401
3322 DB040412
3323 08041206
3324 DB041252
3325 DB041218
332S 00082988
3326 DB041208
3327 OB040301
3327 DB040315
3328 DD029111
3328 D0029112
3328 S0029111
3328 SD029112
3329 00016003
3329 S0016003
3330 OD029109
3330 DD029110
3330 DD029423
3331 00016001
3331 DD016002
3331 00016007
3331 D0016008
3331 S0016008
WB
PF
WB
PF
WB
PF
WB
PF
WB
PF
WB
PF
WB
WB
PF
WB
WP
WB
WP
WB
PF
WP
WP
WP
WP
WP
WP
WP
WP
WP
WP
WP
WP
WB
PF
WB
PF
WB
WB
PF
WB
PF
WB
PF
WB
BF
BF
Bullhead
Walleye
Redhorse Sucker
Sm Bass
Redhorse Sucker
Sin Bass
Redhorse Sucker
Sm Bass
Channel Catfish
White Bass
Channel Catfish
White Bass
Carp
White Sucker
Brown Trout
White Sucker
Punpkinseed
White Sucker
Punpkinseed
White Sucker
Rock Bass
Winter Flounder
Winter Flounder
Bluefish
Winter Flounder
Bluefish
Winter Flounder
Bluefish
Bluefish
Bluefish
Bluefish
Bluefish
Bluefish
Carp
im Bass
Carp
Lm Bass
Bowfin
Bowfin
Suwannee Bass
Spotted Sucker
Black Crappie
Brown Bullhead
LM Bass
Carp
White Catfish
White Catfish
2378
TCOO
NA
1.21
1.29
1.37
2.12
1.01
NA
NA
NA
NA
NA
NA
1.33
NA
NA
NA
NA
NA
NA
NA
NA
1.66
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.20
NA
0.99
NA
NA
NA
NA
NA
12378
PECDD
NA
0.94
1.00
0.94
NA
0.92
NA
0.99
NA
0.96
NA
0.22
NA
NA
1.05
NA
0.92
0.38
0.27
1.00
0.92
1.24
1.20
1.61
NA
0.91
0.92
1.06
1.05
1.03
1.03
1.36
NA
NA
0.94
NA
0.25
NA
NA
1.30
NA
0.92
0.92
0.99
NA
NA
NA
DIOXIN / FURAN DETECTION LIMITS, pg/g
123478 123678 123789 1234678 2378 12378
HXCOO
NA
2.47
2.46
2.47
2.47
2.47
2.46
2.47
2.46
2.47
NA
1.15
NA
2.46
2.46
2.46
2.46
1.07
1.15
2.46
2.45
2.47
2.47
2.47
2.44
2.44
2.47
2.45
2.46
2.46
2.46
2.46
NA
NA
2.46
1.36
1.11
2.47
1.04
2.47
2.45
2.47
2.46
2.46
2.47
2.47
1.12
HXCOO HXCDD
NA NA
1.84 1.38
1.84 1.37
1.85 1.38
NA 1.38
1.84 1.38
NA 1.38
1.85 1.38
NA NA
1.85
NA
0.64
NA
NA
1.84
NA
1.84
0.64
0.64
NA
1.83
1.86
NA
1.84
NA
1.82
.84
.83
.84
.84
.84
.84
.38
.33
.34
NA
.37
.37
.37
.37
.22
.33
.37
.37
.38
.38
.38
.37
.36
.38
.37
.37
.37
.37
.38
NA NA
NA 1.37
1.84 1.37
NA 1.21
0.65 1.31
NA 1.38
NA 1.22
1.84 1.38
NA NA
1.85 1.38
NA 1.37
1.84 1.37
4.91 NA
NA NA
NA 1 .32
HPCDD
NA
NA
NA
1.26
NA
NA
NA
NA
NA
NA
NA
1.09
NA
NA
NA
NA
NA
1.08
NA
NA
NA
NA
NA
4.10
NA
1.29
2.23
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.63
NA
NA
NA
NA
NA
NA
NA
NA
NA
TCOF
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.49
NA
0.49
NA
NA
NA
NA
NA
PECDF
NA
0.78
NA
0.80
NA
0.77
NA
0.78
NA
NA
NA
NA
NA
NA
0.77
NA
1.15
NA
NA
HA
0.77
NA
NA
NA
NA
NA
0.88
NA
NA
NA
NA
NA
NA
NA
0.77
1.04
0.43
NA
NA
0.77
0.77
0.78
0.77
0.77
NA
0.78
0.43
23478
PECOF
NA
0.85
NA
0.86
NA
0.91
NA
0.85
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.84
NA
NA
NA
NA
NA
0.92
NA
HA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.85
NA
0.85
0.84
0.84
1.41
NA
NA
123478
HXCOF"
2.95
2.83
2.82
2.84
2.83
2.63
2.83
2.84
NA
NA
NA
0.89
2.82
NA
NA
2.83
2.82
0.87
0.88
2.82
2.81
2.84
2.83
2.83
2.81
2.80
2.83
2.81
2.83
2.83
2.83
2.83
2.83
2.82
2.82
NA
0.94
NA
NA
2.83
2.82
2.84
2.82
2.82
3.33
2.84
0.94
123678
HXCDF
NA
2.85
2.83
2.85
2.85
2.84
2.84
2.85
NA
2.85
1.10
1.11
2.83
NA
2.84
2.84
2.84
1.03
1.10
2.84
2.83
2.85
2.85
2.84
2.82
2.81
2.84
2.82
2.84
2.84
2.84
2.84
2.84
2.83
2.83
1.22
1.18
NA
NA
2.84
2.83
2.85
2.84
2.83
2.84
2.85
1.19
123789
HXCDF
2.76
2.77
2.76
2.78
2.77
2.77
2.77
2.78
2.77
2.78
0.99
0.99
2.76
2.77
2.77
2.77
2.76
0.89
0.99
2.76
2.76
2.78
2.77
2.77
2.75
2.74
2.77
2.75
2.77
2.77
2.77
2.77
2.77
2.76
2.76
0.96
1.07
2.77
0.96
2.77
2.76
2.78
2.76
2.76
2.77
2.78
1.07
234678 1234678 1234789
HXCDF
2.02
1.96
1.95
.96
.96
.96
.96
.96
NA
1.96
0.91
0.91
1.95
1.96
1.95
1.95
1.95
0.86
0.91
1.95
.95
.96
.96
.96
.94
.94
.96
.95
.96
.96
.95
.96
1.96
1.95
1.95
0.95
1.03
NA
0.95
1.96
.95
.96
.95
.95
NA
.96
.04
HPCDF
2.31
1.45
1.44
.45
.45
.45
.50
.45
NA
1.45
0.71
0.67
1.44
1.44
1.44
1.44
1.44
0.67
0.67
1.44
1.44
1.45
1.45
1.78
1.43
1.43
1.45
1.44
1.44
1.44
1.44
1.44
NA
1.44
1.44
0.66
0.66
NA
NA
1.45
1.44
1.45
1.44
1.44
NA
1.45
0.71
HPCDF
2.61
2.62
2.60
2.62
2.62
2.61
2.61
2.62
NA
2.62
1.87
1.88
2.60
2.61
2.61
2.61
2.61
1.87
1.87
2.61
2.60
2.62
2.62
3.12
2.59
2.59
2.61
2.60
2.61
2.61
2.61
2.61
2.61
2.60
2.60
1.80
1.65
2.62
1.81
2.61
2.60
2.62
2.61
2.61
2.61
2.62
2.07
D-4-4Q
-------
D10XIN / FURAN DETECTION LIMITS, pg/g
Episode SCC Type Description
3332 D0016009 F UP Spotted Drum
3332 DD016010 F PF Crevatle Jack
3333 DD016011 F PF Bluefish
3333 DD016012 F UB Sea Catfish
3333 DD029108 F PF Ueakfish
3333 00121588 1 PF Bluefish
3334 DD016013 F UB Sea Catfish
3334 DD016014 F BF Striped Mullet
3335 00016015 F UP Spot
3335 DD016016 F PF Spotted Bass
3335 DD029101 F UP Red Drum
3335 DD029102 F UB Southern Flounder
3335 DD029103 F UP Sheepshead
3335 00081588 L UP Southern Flounder
3335 S0016015 F UP Spot
3336 DD016004 F UP Black Drum
3336 D0016005 F PF Striped Mullet
3336 DD016006 UP Sheepshead
3336 DD016017 UP Red Drum
3336 DD016018 PF Spotted Seatrout
3336 00092288 PF Spotted Seatrout
3337 OD016019 UB Spotted Sucker
3337 DD016020 PF Lm Bass
3337 00051388 UB Spotted Sucker
3338 DD016021 PF Lm Bass
3338 DD016022 UB Spotted Sucker
3338 DD029107 PF Chain Pickerel
3339 DD016023 UB Carp
3339 DD016024 PF White Bass
3339 00016023 UB Carp
3340 OD029113 PF Lm Bass
3340 00029114 UB Channel Catfish
3340 SD029114 F UB Channel Catfish
3341 DD016103 F PF Lm Bass
3341 ODD 161 04 F UB Catfish
3341 00092788 F PF Lm Bass
3341 S0016103 F PF Lm Bass
3341 SD016104 F UB Catfish
3342 DD016105 UB Spotted Sucker
3342 00016106 PF Bluegill
3343 00016107 UB White Sucker
3343 00016108 PF Redbreast Sunfish
3344 00016109 UB Carp
3344 00016110 PF Lm Bass
3344 SD016109 UB Carp
3345 00016111 UB Redhorse Sucker
3345 00016112 F PF Lm Bass
2378
TCDD
NA
1.16
NA
NA
1.05
NA
NA
1.00
NA
1.05
NA
NA
NA
NA
NA
0.99
NA
NA
1.17
0.99
0.99
NA
NA
NA
1.07
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.10
NA
NA
NA
NA
NA
NA
NA
12378
PECDD
NA
0.99
NA
NA
0.93
NA
NA
0.91
NA
0.92
0.92
NA
NA
NA
NA
0.94
1.22
NA
0.92
0.92
0.92
NA
0.97
NA
0.95
NA
0.97
NA
NA
NA
0.93
NA
NA
0.98
NA
0.97
0.22
NA
NA
0.92
NA
1.84
NA
0.97
NA
NA
NA
123478
HXCDD
NA
2.45
2.46
NA
2.47
2.45
NA
2.45
2.47
2.46
2.46
2.46
2.45
2.44
1.09
2.47
2.47
2.46
2.46
2.46
2.46
NA
2.45
NA
2.46
2.47
2.47
NA
2.47
NA
2.47
NA
1.87
2.46
NA
2.47
1.15
NA
NA
2.47
2.47
4.93
NA
2.46
NA
3.85
2.46
123678
HXCDD
NA
1.83
2.13
NA
1.84
NA
NA
1.84
NA
1.84
2.12
2.35
NA
NA
NA
NA
1.84
2.50
1.84
1.84
1.84
NA
1.83
NA
1.84
NA
1.85
NA
NA
NA
1.85
NA
NA
1.84
NA
1.85
0.64
NA
NA
1.85
5.95
NA
NA
1.84
NA
NA
NA
123789 1234678
HXCDD
NA
1.37
1.37
NA
1.38
1.37
NA
1.37
NA
1.37
NA
1.37
1.37
NA
NA
NA
1.38
NA
1.37
1.38
1.37
NA
1.37
NA
1.37
NA
1.38
NA
1.38
1.53
1.38
NA
NA
1.38
NA
1.38
1.33
NA
NA
1.38
NA
2.75
NA
1.38
NA
NA
1.37
HPCDD
NA
1.25
NA
NA
1.26
NA
NA
1.45
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.28
NA
1.40
NA
NA
NA
1.40
NA
NA
1.49
NA
1.48
1.30
NA
NA
NA
NA
NA
NA
1.48
NA
NA
NA
2378
TCDF
NA
0.50
NA
NA
0.57
NA
NA
0.52
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.62
0.58
NA
NA
NA
0.53
NA
0.66
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.92
NA
NA
NA
0.53
NA
NA
NA
12378
PECDF
NA
0.77
0.77
0.77
0.78
0.77
0.77
0.77
NA
NA
NA
0.77
NA
0.77
NA
0.77
0.78
0.87
0.77
0.77
0.77
0.80
0.77
0.77
0.77
1.33
0.78
1.47
NA
NA
0.78
NA
0.44
NA
0.81
0.78
0.42
0.41
NA
0.78
NA
1.55
NA
0.77
NA
1.17
0.77
23478
PECDF
NA
0.84
NA
NA
0.85
NA
2.40
0.84
NA
0.84
0.85
0.90
NA
0.88
NA
0.85
0.95
1.42
0.84
0.85
0.85
NA
0.84
NA
0.84
NA
0.85
NA
NA
NA
0.85
NA
NA
NA
NA
NA
0.36
NA
NA
0.85
NA
1.69
2.79
0.85
NA
NA
0.85
123478
HXCDF*
2.81
2.81
2.82
2.82
2.83
2.82
2.82
2.82
NA
2.82
NA
2.83
NA
2.80
NA
2.83
2.83
2.82
2.82
2.83
2.83
2.86
2.81
2.82
2.82
2.91
2.84
NA
2.83
NA
2.84
2.84
0.94
2.83
2.81
2.84
0.88
0.84
NA
2.84
NA
5.66
NA
2.83
NA
NA
2.83
123678
HXCDF
2.83
2.82
2.83
2.83
2.85
2.83
2.83
2.83
NA
2.84
2.84
2.84
NA
2.81
NA
2.84
2.85
2.83
2.83
2.84
2.84
2.85
2.82
2.84
2.83
2.85
2.85
NA
2.85
NA
2.85
2.86
1.19
2.84
2.83
2.85
1.10
1.10
2.84
2.85
NA
5.69
3.48
2.84
NA
2.85
2.84
123789
HXCDF
2.76
2.75
2.76
2.76
2.77
2.76
2.76
2.76
2.78
2.76
2.77
2.77
2.76
2.74
0.97
2.77
2.77
2.76
2.76
2.77
2.77
2.78
2.75
2.76
2.76
2.78
2.78
2.76
2.77
2.76
2.78
2.78
1.07
2.77
2.76
2.78
0.99
0.87
2.77
2.78
2.77
5.55
2.78
2.77
0.87
2.78
2.77
234678 1234678 1234789
HXCDF
.95
.94
.95
.95
.96
.95
.95
.95
NA
1.95
NA
1.95
NA
1.94
1.65
1.96
1.96
1.95
1.95
1.96
1.96
1.97
1.95
1.95
1.95
1.96
1.96
NA
1.96
1.95
1.96
NA
1.04
1.96
1.95
1.96
0.91
0.86
1.96
1.96
NA
3.92
NA
1.96
NA
1.96
1.96
HPCDF
1.44
1.43
1.44
1.44
1.45
1.44
1.44
1.44
NA
1.44
1.44
1.44
1.59
1.43
NA
NA
1.45
1.44
1.44
1.44
1.44
NA
1.44
NA
1.44
NA
1.45
NA
1.45
NA
1.45
NA
0.66
1.44
1.44
1.45
0.67
0.65
NA
1.45
NA
2.89
NA
1.44
NA
NA
1.44
HPCOF
2.60
2.59
2.61
2.60
2.62
2.60
2.60
2.60
2.62
2.61
2.61
2.61
2.60
2.59
1.88
2.61
2.62
2.61
2.61
2.61
2.61
2.62
2.60
2.61
2.61
2.62
2.62
2.60
2.62
2.60
2.62
2.62
1.66
2.61
2.60
2.62
1.87
1.80
2.61
2.62
2.62
5.23
2.62
2.61
3.01
2.62
2.61
D-4-41
-------
OIOX1M / FURAN DETECTION LIMITS, pg/g
Episode SCC Type Description
3545 SD016111 F WB Redhorse Sucker
3346 DD016113 F WB Creek Chubsucker
3346 DD0161U F PF Im Bass
3346 00042088 L WB Creek Chubsucker
3346 S0016113 F WB Creek Chubsucker
3346 SD016114
3347 D0016115
3347 DD016116
3347 SD016115
3348 D0016117
3348 DD016118
3348 00072888
3348 SD016117
3348 S0016118
3349 D0016119
3349 D0016120
3350 DD016121
3350 00016122
3350 00052688
3351 00016123
3351 DD016124
3351 00021888
3352 DF023723
3352 DF023724
3352 00091388
3353 DF024121
3353 OF024122
3353 00024121
3354 DY022301
3354 DY022302
3355 DY022303
3355 DY022304
3355 SY022303
3356 DE030201
3356 SE030201
3357 DY022223
3357 DY022224
3360 DD029117
3360 00029118
3360 00022389
3375 D0016305
3375 00016306
3375 00101188
3376 00016307
3376 00016308
PF LM Bass
WB Carp
PF LM Bass
WB Carp
PF White Perch
WB Blue Catfish
WB Blue Catfish
PF White Perch
WB Blue Catfish
WB Carp
PF Im Bass
WB Carp
PF Ln Bass
WB Carp
PF Rock Bass
WB Carp
WB Carp
PF Crappie
WB Carp
WB Carp
BF Blue Catfish
WB SM Buffalo
BF Blue Catfish
WB Carp
PF LM Bass
WB Carp
PF Lm Bass
WB Carp
WB Carp
WB Carp
PF Squawfish
WB Sacramento Sucker
WB Carp
PF Lm Bass
WB Carp
WB Carp
PF LM Bass
WB Carp
WB Carp
PF Im Bass
3376 00050389 L PF Im Bass
3377 00016309 F UB Carp
2378
TCDD
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.00
NA
NA
NA
NA
NA
NA
1.11
NA
1.49
NA
NA
NA
NA
NA
NA
1.13
2.36
NA
NA
NA
NA
1.21
1.19
NA
12378
PECDD
NA
NA
0.98
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.95
NA
0.91
NA
0.92
NA
NA
0.91
NA
NA
NA
NA
NA
NA
NA
NA
1.80
NA
NA
NA
NA
NA
NA
1.14
NA
NA
1.19
NA
NA
1.13
1.29
NA
123478
HXCDD
NA
2.47
2.46
2.46
NA
0.90
NA
2.46
NA
2.47
NA
NA
1.12
NA
NA
2.47
NA
2.45
NA
2.46
NA
NA
2.45
NA
NA
2.46
NA
2.47
NA
2.47
NA
2.46
NA
NA
NA
2.46
2.45
2.47
2.46
2.46
NA
2.46
NA
NA
2.76
2.83
NA
123678
HXCDD
NA
1.85
1.84
1.84
NA
0.69
8.97
HA
NA
NA
NA
NA
0.66
NA
NA
1.84
NA
1.83
NA
1.84
NA
NA
1.83
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.84
NA
NA
NA
NA
NA
2.07
2.12
NA
123789 1234678
HXCDD
NA
1.38
1.37
1.37
NA
1.15
NA
1.37
NA
1.38
NA
NA
1.32
1.51
NA
1.38
NA
1.37
NA
1.38
NA
1.36
1.37
NA
NA
NA
NA
NA
NA
1.38
NA
1.37
NA
NA
NA
1.37
1.37
1.38
1.38
1.38
HA
1.37
NA
NA
1.58
1.62
NA
HPCDD
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.68
NA
1.26
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.46
NA
NA
1.26
NA
HA
NA
NA
NA
NA
1.49
NA
2378
TCDF
NA
NA
NA
NA
NA
NA
NA
NA
NA
HA
NA
HA
NA
NA
NA
NA
NA
0.77
NA
0.63
NA
NA
0.58
NA
NA
NA
NA
NA
NA
0.57
NA
0.62
NA
NA
NA
NA
NA
NA
1.10
NA
HA
NA
NA
NA
0.64
0.64
NA
12378
PECDF
0.92
NA
0.77
HA
NA
HA
NA
0.77
NA
HA
NA
NA
NA
NA
NA
0.77
NA
0.77
NA
0.77
NA
NA
0.77
0.78
0.77
0.77
NA
0.78
NA
0.77
NA
0.77
NA
NA
NA
0.77
HA
0.78
0.81
0.77
NA
0.81
NA
NA
0.78
0.78
NA
23478
PECDF
NA
NA
NA
NA
NA
HA
2.68
0.85
NA
NA
NA
NA
NA
NA
NA
0.85
NA
0.84
NA
0.85
NA
NA
0.84
0.85
0.91
NA
NA
1.09
NA
0.85
NA
1.20
NA
NA
NA
NA
HA
NA
0.87
NA
NA
NA
NA
NA
0.85
0.85
NA
123478
HXCDF*
0.76
2.84
2.83
2.83
0.77
0.76
NA
2.83
NA
2.84
2.84
NA
0.94
1.05
2.84
2.83
NA
2.82
NA
2.83
HA
NA
2.81
2.84
2.82
2.82
2.83
2.84
NA
2.83
HA
2.83
HA
NA
HA
2.83
2.82
2.83
2.83
2.83
NA
2.82
NA
NA
2.84
2.84
NA
123678
HXCDF
1.25
2.85
2.84
2.84
1.28
1.25
3.08
2.84
NA
2.85
2.84
2.65
1.19
1.11
2.85
2.84
NA
2.83
NA
2.84
NA
NA
2.82
2.85
2.83
2.83
2.84
2.85
NA
2.84
NA
2.84
HA
NA
HA
2.84
2.83
2.85
2.84
2.84
NA
2.84
NA
NA
2.85
2.85
NA
123789
HXCOF
0.88
2.78
2.77
2.77
0.94
0.87
2.77
2.77
0.99
2.78
2.77
2.78
1.07
0.99
2.78
2.77
2.77
2.76
2.78
2.77
2.76
2.74
2.75
2.78
2.76
2.76
2.77
2.78
2.77
2.77
2.77
2.77
0.20
2.77
0.96
2.77
2.76
2.77
2.77
2.77
2.77
2.76
2.76
2.76
2.78
2.78
2.77
234678 1234678 1234789
HXCDF
0.83
1.96
1.96
1.%
0.88
0.83
NA
1.96
0.91
1.96
1.96
1.96
1.04
0.91
1.96
1.96
NA
1.95
NA
1.96
NA
NA
1.94
1.96
1.95
1.95
1.96
1.96
2.17
1.96
NA
1.96
HA
NA
NA
1.96
1.95
1.96
1.96
1.96
NA
1.95
NA
NA
1.96
1.96
NA
HPCDF
0.81
1.45
1.44
1.44
0.81
0.81
NA
NA
NA
1.45
1.45
1.45
0.66
0.68
1.45
1.45
NA
1.44
NA
1.45
NA
NA
1.43
1.45
1.44
1.44
1.44
1.45
HA
1.45
HA
1.44
HA
NA
NA
1.44
1.44
1.45
1.44
1.45
NA
1.44
NA
NA
1.45
1.45
NA
HPCDF
3.01
2.62
2.61
2.61
3.01
3.01
2.61
2.61
1.81
2.62
2.61
2.62
1.66
1.81
2.62
2.61
2.61
2.60
2.62
2.61
2.60
2.59
2.59
2.62
2.61
2.60
2.61
2.62
2.62
2.61
HA
2.61
HA
2.61
1.87
2.61
2.60
2.62
2.61
2.61
NA
2.61
NA
NA
2.62
2.62
NA
D-4-42
-------
Episode SCC Type Description
3377
3377
3378
3378
3378
3378
3385
3395
3395
3395
3401
3401
3403
3403
3404
3404
3404
3409
3409
3411
3412
3412
3412
3414
3414
3415
3415
3416
3416
3416
3418
3419
3419
3420
3420
3421
3421
3421
3422
3422
3423
3423
3424
3424
3425
3425
3425
DD016310
SD016309
00016311
00016312
00029115
00029116
DD016401
00016421
DD016422
SD016421
DD016509
DD016510
00016513
00016514
DD016515
00016516
SD016515
DB040701
DB040706
DB040501
DB040901
DB040907
SB040907
DC036203
DC036204
DC036205
DC036206
DF025210
DF025211
DF025212
DF025007
DC036207
DC036208
OC036209
DC036210
DC036211
DC036212
SC036212
DC036213
DC036214
DC036215
DC036216
DC036217
DC036218
DF025005
DF025012
00031389 L
PF Lm Bass
UB Carp
UB Spotted Sucker
PF Lm Bass
WB Greyfin Sucker
BF Channel Catfish
UB Redhorse Sucker
UB Redhorse Sucker
PF Lm Bass
UB Redhorse Sucker
UB Carp
PF Lm Bass
UB River Carpsucker
PF Lm Bass
UB Carp
PF Lm Bass
UB Carp
UB Carp
PF Lm Bass
UB Redhorse Sucker
PF Sm Bass
UB Carp
UB Carp
PF Sm Bass
BF Channel Catfish
PF Sm Bass
PF Channel Catfish
BF Channel Catfish
BF Carp
PF Lm Bass
BF Blue Catfish
UB White Sucker
PF Freshwater Drum
PF Greenfish
UB Carp
PF Uhite Perch
UB Carp
UB Carp
PF Lm Bass
UB Yellow Bullhead
PF Uhite Perch
UB Uhite Catfish
PF Shortnose Gar
UB Uhite Catfish
UB Carp
BF Channel Catfish
BF Channel Catfish
OIOXIN / FURAN DETECTION
2378
TCOO
1.24
NA
NA
1.00
NA
1.02
NA
NA
NA
NA
NA
1.12
NA
NA
NA
NA
NA
NA
1.09
NA
NA
NA
NA
1.11
NA
1.04
NA
NA
NA
1.54
NA
1.16
0.99
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12378
PECDD
0.95
NA
1.24
1.06
NA
1.18
1.26
NA
1.25
NA
NA
0.94
NA
1.10
NA
1.17
NA
NA
0.97
NA
1.00
NA
NA
0.92
1.22
0.92
NA
1.17
1.37
1.09
1.01
1.19
0.91
NA
NA
0.92
NA
NA
0.94
0.91
1.07
NA
0.92
NA
NA
NA
NA
123478
HXCOD
2.46
NA
2.62
2.47
NA
2.47
2.46
3.33
2.46
1.59
NA
2.46
NA
2.45
NA
2.46
NA
NA
2.46
2.46
2.45
NA
NA
2.46
2.47
2.46
NA
2.46
2.47
2.46
2.46
2.47
2.45
2.46
2.95
2.46
2.47
NA
2.47
2.45
2.47
2.45
2.46
2.56
NA
2.46
2.46
123678 123789
HXCDD HXCOD
1.88 1.38
NA NA
2.02 1.37
1.85 1.38
NA 1.38
1.84 1.38
NA 1.37
NA NA
1 .84 1 .38
NA 1.39
NA NA
NA 1.37
NA NA
1.83 1.37
NA NA
1 .85 1 .37
NA NA
NA NA
1.84 1.38
NA 1.38
1.83 1.37
NA NA
NA NA
1.84 .37
NA .38
1.84 .38
NA .37
1.84 .37
1.84 .38
1.84 .37
1.84 .38
1.84 .38
1.83 .37
NA .37
NA NA
1.84 .37
NA NA
NA NA
1 .85 .38
1.83 .37
1.84 .38
NA NA
NA 1.37
1 .83 NA
NA NA
NA NA
2.41 NA
1234678
HPCDD
2.27
NA
NA
1.32
NA
1.65
NA
NA
NA
NA
NA
1.35
NA
1.42
NA
NA
NA
NA
NA
NA
1.31
NA
NA
1.26
NA
1.39
NA
NA
NA
1.32
1.52
1.55
1.25
NA
NA
1.56
NA
NA
1.71
NA
NA
NA
NA
NA
NA
NA
NA
LIMITS,
P9/9
2378 12378
TCDF
NA
NA
NA
0.53
NA
0.56
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
HA
NA
0.54
NA
0.49
NA
NA
NA
NA
NA
NA
0.48
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
PECOF
0.77
NA
0.91
0.78
0.94
0.80
0.77
NA
0.78
NA
NA
0.77
NA
0.77
NA
0.77
NA
NA
0.77
0.94
0.77
NA
MA
0.77
0.78
0.77
NA
0.82
0.77
0.77
0.77
0.91
0.77
NA
NA
0.77
NA
NA
0.78
0.77
0.77
NA
0.77
0.85
NA
0.87
0.85
23478
PECDF
0.85
NA
NA
0.85
NA
0.86
NA
NA
1.16
NA
NA
0.85
NA
1.04
NA
0.85
NA
NA
0.85
NA
1.18
NA
NA
NA
NA
0.85
NA
0.94
1.24
0.85
1.12
1.61
0.84
NA
NA
0.86
7.11
NA
0.85
0.87
0.87
NA
1.19
NA
NA
NA
NA
123478
HXCOF*
2.83
NA
2.83
2.84
2.84
2.83
2.82
2.84
2.83
0.94
2.81
2.83
NA
2.82
2.82
2.83
0.94
NA
2.83
NA
2.82
NA
NA
2.82
2.83
2.83
2.83
2.82
2.83
2.83
2.83
2.83
2.82
2.83
2.83
2.83
NA
NA
2.84
2.82
2.83
2.82
2.82
2.82
2.89
2.82
2.83
123678
HXCOF
2.84
NA
2.84
2.85
2.85
2.85
2.83
NA
2.84
1.19
2.83
2.84
NA
2.83
2.91
2.84
1.18
NA
2.84
2.84
2.83
NA
NA
2.83
2.85
2.84
2.84
2.83
2.84
2.84
2.84
2.85
2.83
2.84
2.85
2.84
2.85
1.04
2.85
2.83
2.84
2.83
2.84
2.83
NA
2.83
2.84
123789 234678 1234678
HXCOF HXCOF HPCOF
2.77 1.96 1.44
1 .40 NA NA
2.77 1.95 .44
2.78 1.96 .45
2.78 1.96 .45
2.77 1.96 .45
2.76 1.95 .44
2.78 .96 .54
2.77 .96 .45
1.07 .04 NA
2.76 .95 NA
2.77 .95 1.44
2.76 NA NA
2.76 .95 1.44
2.76 .95 NA
2.77 .96 1.44
1.06 .03 NA
2.77 NA NA
2.77 .96 1.45
2.77 .96 NA
2.76 .95 1.44
2.77 NA NA
1.07 .40 NA
2.76 .95 .44
2.77 .96 .45
2.77 .96 .44
2.77 .95 .44
2.76 .95 .44
2.77 .96 .45
2.77 .96 .44
2.77 .96 .45
2.77 .96 .45
2.76 .95 .44
2.77 .95 NA
2.77 .96 .45
2.77 .96 .44
2.78 .96 .45
0.89 0.87 0.66
2.78 .96 .45
2.76 .95 .44
2.77 .96 .45
2.76 .95 .44
2.76 .95 .44
2.76 .95 .44
2.77 .97 NA
2.76 .95 .44
2.77 1.96 .45
1234789
HPCDF
2.61
0.93
2.61
2.62
2.62
2.62
2.60
2.62
2.61
1.66
2.60
2.61
NA
2.60
2.60
2.61
1.65
2.61
2.61
2.61
2.60
2.61
1.66
2.61
2.62
2.61
2.61
2.61
2.61
2.61
2.61
2.62
2.60
2.61
2.62
2.61
2.62
1.66
2.62
2.60
2.61
2.60
2.61
2.60
2.62
2.61
2.61
D-4-43
-------
Episode SCC Type Description
3426 DB069102
3427 DB069103
3428 DB069104
3429 OB069105
3430 DB069106
3431 DB069109
3432 DB069111
3433 DB069112
3433 00021689
3434 DB040801
3435 00016601
3435 00016602
3437 OJ022302
3438 OJ022303
3439 DJ022304
3439 00062289
3440 DJ022305
3441 OJ022306
3442 DF024301
3442 00081089
3444 DD016603
3444 D0016604
3444 DD029512
3444 00091289
3445 OD029513
3445 00029514
3446 D0016605
3446 00016606
3446 00029511
3446 QD092089
3450 DY022308
3450 DY022309
3451 DY022310
3451 DY022314
3452 DF025218
3452 DF025219
3452 OF025220
3452 00103189
PF Bluefish
PF Bluefish
PF Bluefish
PF Weakfish
F WB White Catfish
F WB Red Snapper
F BF Red Snapper
F UP Flounder
UP Flounder
F UP Flounder
F PF White Bass
F WB Bigmouth Buffalo
N WB Crayfish
N Dungeness Crab
F WB White Sturgeon
L WB White Sturgeon
F WB White Sturgeon
F WB White Sturgeon
F BF Channel Catfish
L BF Channel Catfish
F WB Carp
F BF Channel Catfish
F PF Lm Bass
F WB Carp
F WB Flounder
F WB Hardhead Catfish
F PF Striped Bass
F WB Carpsucker
F WB Carp
F WB Carp
F PF White Croaker
F PF White Croaker
F PF White Croaker
F PF White Croaker
F WB Sm Buffalo
F BF Blue Catfish
F PF Flathead Catfish
F WB Sm Buffalo
OIOXIN / FURAN DETECTION LIMITS, pg/g
2378
TCDD
NA
NA
1.06
0.99
NA
1.22
0.99
NA
NA
NA
1.72
NA
1.11
NA
2.07
NA
NA
1.75
0.99
0.99
NA
NA
1.44
NA
1.05
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12378
PECOD
0.95
0.94
1.01
1.00
1.01
NA
1.01
NA
1.62
NA
1.08
NA
0.99
1.22
0.94
1.06
1.12
0.92
0.96
0.92
NA
NA
1.20
NA
1.16
NA
1.07
0.92
.20
.28
.28
.64
.74
.48
.10
NA
.16
.10
123478
HXCOO
2.47
2.47
2.46
2.46
2.47
2.57
2.46
2.46
2.46
2.46
2.47
3.04
2.45
2.45
2.47
2.47
2.46
2.48
2.47
2.45
NA
NA
2.73
NA
2.46
3.18
2.45
2.46
2.46
2.46
2.47
2.46
2.47
2.47
2.46
2.71
2.47
2.47
123678
HXCDD
1.85
1.84
1.84
1.84
NA
1.85
1.84
NA
NA
NA
1.85
NA
1.84
NA
1.84
1.85
1.84
1.85
1.85
1.84
NA
NA
2.05
NA
1.95
NA
1.83
1.84
NA
NA
1.84
.84
.85
.85
.84
2.03
.84
.84
123789 1234678
HXCDD
1.38
1.38
1.37
1.37
1.38
1.38
1.37
1.37
1.37
1.37
1.38
NA
1.37
1.37
1.38
1.38
1.37
1.38
1.38
1.37
NA
NA
1.56
NA
1.37
NA
1.37
1.37
1.38
1.37
1.38
1.37
1.38
1.38
1.38
1.54
1.38
1.38
HPCOD
1.26
1.26
1.26
1.26
NA
1.26
1.26
NA
NA
NA
1.34
NA
NA
3.95
NA
NA
1.51
NA
1.33
1.25
NA
NA
1.64
NA
NA
NA
1.65
1.59
NA
NA
1.35
1.26
1.26
1.26
1.39
1.99
1.26
1.29
2378
TCDF
NA
NA
NA
0.49
NA
NA
0.49
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.49
0.48
NA
0.59
0.75
NA
0.58
0.64
NA
NA
NA
NA
0.49
0.49
0.57
0.55
NA
NA
0.54
NA
12378
PECDF
0.78
NA
0.87
0.77
NA
NA
0.77
0.97
1.03
1.14
0.80
NA
0.77
0.91
1.03
NA
1.07
1.09
0.78
0.77
NA
0.82
0.87
NA
0.78
0.78
1.28
1.05
1.32
1.39
0.77
0.77
0.93
1.02
0.93
0.80
0.80
0.80
23478
PECOF
NA
NA
NA
0.85
NA
NA
0.85
NA
NA
NA
0.87
NA
0.84
NA
0.91
0.94
0.93
0.91
0.85
0.84
NA
NA
0.91
NA
0.87
1.19
NA
1.65
NA
NA
0.93
0.97
0.96
1.02
0.96
1.78
0.86
0.87
123478
HXCOF*
2.84
2.83
2.83
2.83
2.84
2.84
2.83
2.83
2.83
2.83
2.84
NA
2.82
2.81
2.83
2.84
2.83
2.83
2.84
2.82
NA
2.84
2.84
NA
2.83
Z.84
2.96
2.82
NA
NA
2.83
2.82
2.84
2.84
2.83
2.82
2.83
2.83
123678
HXCOF
2.85
2.85
2.84
2.84
2.85
2.85
2.84
2.84
2.84
2.84
2.85
2.84
2.83
2.83
2.85
2.85
2.84
2.85
2.85
2.83
NA
2.85
2.85
NA
2.84
2.85
2.83
2.84
2.94
2.84
2.84
2.83
2.85
2.85
2.84
2.83
2.84
2.84
123789
HXCOF
2.78
2.77
2.77
2.77
2.78
2.78
2.77
2.77
2.77
2.77
2.77
2.77
2.76
2.76
2.77
2.78
2.77
2.77
2.78
2.76
2.77
2.78
2.78
2.76
2.77
2.78
2.76
2.76
2.77
2.77
2.77
2.76
2.78
2.78
2.77
2.76
2.77
2.77
234678 1234678 1234789
HXCDF
1.96
1.96
1.95
1.96
1.96
1.96
1.95
1.96
1.96
1.96
1.96
1.96
1.95
1.95
1.96
.96
.96
.96
.96
.95
NA
NA
1.96
NA
1.96
1.96
1.95
1.95
1.96
1.95
.96
.95
.96
.96
.96
.95
.96
.96
HPCDF
.45
.45
.44
.44
.45
.45
1.44
1.44
1.44
1.44
1.45
NA
1.44
1.54
1.45
1.45
1.44
1.45
1.45
1.44
NA
NA
1.56
NA
1.44
1.45
1.44
1.44
1.70
1.67
1.45
1.44
1.45
1.45
1.44
1.49
1.45
1.45
HPCDF
2.62
2.62
2.61
2.61
2.62
2.62
2.61
2.61
2.61
2.61
2.62
2.61
2.60
2.60
2.62
2.62
2.61
2.62
2.62
2.60
3.02
2.62
2.78
2.97
2.61
2.62
2.60
2.61
2.61
2.61
2.61
2.61
2.62
2.62
2.61
2.68
2.61
2.61
D-4-44
-------
APPENDIX D-5
Xenobiotic Data by Episode Number
-------
Key for Xenobiotic Data Table (Units = ng/g)
Sqt I CAS Number
Merc = Mercury, jig 7439-97-6
123 TCB = 1,2,3 Trichlorobenzene 87-61 -6
124 TCB = 1,2,4 Trichlorobenzene 120-82-1
135 TCB = 1,3,5 Trichlorobenzene 108-70-3
1234 TCB = 1,2,3,4 Tetrachlorobenzene 634-66-2
1235 TCB = 1,2,3,5 Tetrachlorobenzene 634-90-2
1245 TCB =1,2,4,5 Tetrachlorobenzene 95-94-3
OCS = Octachlorostyrene 29082-74-4
PCB = Pentachlorobenzene 608-93-5
PCNB = Pentachloronitrobenzene 82-68-8
HCB = Hexachlorobenzene 118-74-1
aBHC = alpha BHC 319-84-6
gBHC = gamma BHC (lindane) 58-89-9
cisCHLOR =cisChlordane 5103-71-9
trans CHLOR = trans Chlordane 5103-74-2
DATA FLAGS
D= Value below limit of quantitation for all xenobiotics except mercury and PCBs
D = 2.5 ng/g
For polychlorinated biphenyls
Number of Chlorines D. ng/g
1-3 1.25
4-6 2.50
7-8 3.75
9-10 6.25
Detection limit for mercury was 0.05 Jig/g, except for 1990 samples which had a detection limit
of0.0013^ig/g.
E = Value exceeds highest calibration standard
See Dioxin/Furan Data Table Key for explanation of other codes. The tables include
environmental samples (those starting with a sample number of D) and the duplicate samples
(those starting with a Q) and confirmation samples (those starting with an S). The number of
samples shown on the summary tables in Volume I does not include the duplicate and
confirmation samples.
D-5-1
-------
D-J-2
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
1994 DEO17703
1994 DE017702
1998 13421
1998 13285
2015 DF001002
2015 OF001001
2016 DF001102
2016 DF001101
2017 DF001202
2017 DF001201
2018 DF001301
2023 DF001402
2023 DF001403
2026 DF001706
2026 DF001702
2027 DF001802
2027 DF001803
2037 DY000502
2037 OY000501
2056 OE000501
2057 DE000601
2059 DE000801
2060 DE000901
2070 DJ000901
2070 DJ000902
2098 DH001504
2098 OH001501
2100 DH001702
2100 DH001703
2105 DH002201
2105 DH002204
2109 DH002602
2109 DH002601
2110 DH002710
2122 OH003901
2122 OH003904
2126 DD000303
2126 DD000302
2133 D0001002
2138 DD001504
2138 DD001501
2139 DD001604
2139 DD001601
2142 DD001903
2142 D0001902
F PF Walleye
F WB Carp
PF Northern Pike
WB Carp
UP Crappie
WB Carp
BF Sucker
WB Sucker
BF Carp
WB Carp
WB Sucker
PF Spotted Bass
WB Carp
WB Flathead Catfish
F WB Carp
F PF Lin Bass
F WB Carp
F WP not available
F WB not available
F WB Carp
F WB Carp
F WB Carp
F WB Carp
F WP Rainbow Trout
F WB Longnose Sucker
F PF not available
F WB not available
F PF Sauger
F WB Catfish
F PF Sauger
F WB Carp
F BF not available
F WB not available
F WP Brown Trout
F PF Rainbow Trout
F WB White Sucker
F PF White Crappie
F WB Carp
F BF Blue Catfish
F PF Lm Bass
F WB Redhorse Sucker
F PF Rainbow Trout
F WB Carp
F PF Lm Bass
F WB Catfish
Merc
09/9
0.12
0.11
0.28
0.08
0.17
0.14
0.31
0.18
0.15
0.11
0.07
0.24
0.16
0.14
0.16
1.63
0.21
0.09
0.10
0.06
0.12
0.14
0.09
NO
NO
ND
NO
0.35
0.32
0.45
ND
0.12
ND
ND
0.11
0.12
0.71
0.14
0.37
0.88
0.437
ND
0.08
0.348
0.10
123
TCB
1.40
NO
ND
0.19
ND
ND
ND
ND
69.0
ND
ND
ND
ND
0.45
ND
ND
ND
0.60
1.02
0.15
0.28
ND
ND
124
TCB
D 1.35
ND
ND
D 0.29
ND
ND
ND
ND
191
ND
ND
ND
ND
D 0.64
ND
ND
ND
D 0.35
D 0.60
D 0.35
D ND
ND
ND
135
TCB
D ND
ND
ND
D ND
ND
ND
ND
ND
E 2.77
ND
ND
ND
ND
D ND
ND
ND
ND
D ND
D ND
D ND
ND
ND
ND
1234
TCB
ND
ND
ND
0.09
ND
ND
NO
ND
11.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1235
TCB
ND
ND
ND
D ND
ND
ND
ND
ND
15.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1245
TCB
ND
ND
ND
ND
ND
ND
ND
ND
15.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DCS
ND
ND
ND
ND
ND
ND
ND
ND
3.72
ND
20.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PCB
ND
ND
ND
ND
ND
ND
ND
ND
4.72
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PCI
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HCB
aBHC
gBHC
CIS TRANS
CHLOR CHLOR
4.07
ND
2.52
ND
ND
0.66
ND
ND
19.7
ND
4.56
2.18
ND
ND
2.52
ND
ND
ND
ND
ND
ND
ND
ND
3.58
ND
4.10
ND
ND
D ND
1.26
ND
18.6
7.84
9.80
D 3.63
ND
6.42
6.58
1.55
ND
ND
3.98
ND
1.39
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
15.3
ND
5.26
ND
ND
ND
D ND
ND
ND
ND
ND
D 1.64
ND
ND
46.4
7.67
5.17
3.30
ND
13.2
3.04
ND
148
60.2
68.2
74.9
ND
ND
26.0
ND
14.3
ND
ND
D 4.06
43.6
ND
3.50
ND
5.20
8.23
1.96 D
ND
E 111
38.9
38.0
55.5
ND
ND
22.7
ND
16.5
ND
2.43 D ND
2.73
3.46
ND ND
45.5 22.2
D-5-3
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
Here
123
TCB
124
TCB
135
TCB
1234
TCB
1235
TCB
1245
TCB
DCS
PCB
PCNB
HCB
aBHC
gBHC
CIS
CHLOR
TRANS
CHLOR
2148 DD002504
2148 00002501
2151 DD002801
2151 00002803
2152 00002902
2152 00002903
2190 DG005101
2190 DG005104
2191 DG005206 F BF Carp
2191 OG005205 F WB Carp
2194 DG005504
2194 DG005501
2199 OG006001
2199 DG006004
2201 DG006204
2201 DG006201
2205 DG006602
2205 DG006601
2210 DC005401
2211 OC005503
2212 DC005602
2212 DC005605
2215 DC005902
2216 DC006002
2216 OC006003
2220 DC006401
2220 DC006405
2225 DC006903
2225 DC006902
2227 OC007102
2227 DC007104
2228 DC007204
2228 OC007201
2231 DC007503
2246 DJ002301
2246 DJ002302
2247 DJ002403
2247 DJ002404
2280 OF005204
2280 DF005201
2280 00121688
2283 DF005502
2283 OF005501
2290 DD003402
2290 DD003403
F BF Saltwater Catfish
F WB Saltwater Catfish
F PF Lm Bass
F WB Spotted Sucker
F PF Lm Bass
F WB Lake Chubsucker
F WB Carp
F PF Bluegill
F BF Channel Catfish
F WB Carp
F WB Carp
F PF Lm Bass
F PF Bowfin
F WB Carp
F BF Carp
F WB Carp
F WB Catfish
F WB Redhorse Sucker
F PF SMI Bass
F WB White Sucker
F WB Carp
F PF Brown Trout
F WB White Sucker
F PF Redbreast Sunfish
F WB Catfish
F WB Shorthead Redhorse
F PF Sn Bass
F PF Lm Bass
F WB Channel Catfish
F PF Redhorse Sucker
F PF Longear Sunfish
F WB Gizzard Shad
F BF Bridgelip Sucker
F WB Bridgelip Sucker
F PF Bridgelip Sucker
F WP Mountain Whitefish
F BF Channel Catfish
F WB Carp
L WB Carp
f WP Longear Sunfish
F WB Gray Redhorse
F PF Lm Bass
0.28
0.12
0.81
0.07
0.98
0.13
NO
0.85
0.05
NO
0.24
0.10
NO
0.27
0.58
0.12
0.16
0.07
0.08
0.151
0.24
0.06
NO
0.14
0.08
0.07
NO
0.125
0.23
0.614
0.138
0.08
0.16
NO
0.52
0.20
0.19
0.10
0.29
0.17
NO
1.35
2.60
NO
0.92
NO
NO
NO
0.35
NO
0.28
NO
0.33
0.71
NO
NO
NO
NO
NO
NO
NO
NO
0.38
NO
NO
NO
D 1.01
1.97
NO
0 0.67
NO
0.76
NO
0 0.26
0.35
0 0.45
4.60
0 0.64
0 0.59
NO
NO
0.15
0.46
0.82
NO
NO
NO
D NO
NO
NO
NO
D NO
D NO
NO
D NO
NO
D NO
NO
D NO
0 NO
D NO
NO
D NO
D NO
NO
NO
0 NO
D NO
0 NO
NO
NO
NO
NO
NO
NO
f WB Spotted Sucker
0.13
0.15
1.13
0.21
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
17.7
ND
104
ND
9.20
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
0.10 D ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
12.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
NO
NO
ND
ND
ND
ND
ND
12.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
NO
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.43 0 NO
ND ND
ND ND
ND
NO ND
1.88 D NO
ND ND
ND NO
0.32 D ND
1.93 D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
11.6
ND
ND
ND
ND
ND
NO
ND
3.12
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
4.90
NO
3.97
ND
NO NO NO ND ND
0.51 D 1.09 D 1.68 D 69.7 E 182
ND
ND ND
2.15 D 10.2
ND
1.89 D 11.9
ND ND
NO ND
ND
ND
NO
76.2
77.5
34.5
19.9
3.99
ND
107
72.9
34.6
11.0
ND
ND
5.07
ND
ND
2.72
NO
0.93
6.55
2.33
ND
ND
ND
D
D
ND
ND
2.
1.
7.
13
70
36
18
.6
ND
166
7.14
D 6.05
112
378
E
E
E
ND
126
3.94
2.27
64.3
310
D
E
ND ND
0.78 D ND
0.83 D ND
ND
15.7
ND
7.75
ND
ND
NO
ND
ND
8.78
ND
ND
ND
ND
4.57
ND
ND
128
3.07
3.51
NO
2.40 D
ND
ND
87.7
ND
9.70
2.46 D 1.17 D
1.28 D 2.41 D 1.20 D
ND ND ND
ND 41.8 39.8
D-5-4
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
2294 00003801
2294 00005804
2297 DD004103
2297 DD004102
2298 00004201
2298 DD004203
2301 DD004502
2301 D0004S03
2301 DD004501
2301 DD004504
2302 00004601
2304 DD004804
2304 00004801
2309 00005304
2309 DD005301
2322 DB001304
PF Lm Bass
WB Carp
PF Lm Bass
WB Carp
WB Channel Catfish
WP Lm Bass
WB Sm Bass
WB Bluegill
WP Black Crappie
WP Rock Bass
WB Quill back Carpsucker
PF Lm Bass
WB Carp
PF Lm Bass
WB Carp
PF Lm Bass
2322 OB001301 F WB White Sucker
2326 DB001704 F PF Rock Bass
2326 DB001701 F UB White Sucker
2328 DB001904
2329 DB002004
2341 00006002
2341 00006003
2355 DA001603
2356 OA001703
2356 DA001702
2369 OA003202
2375 DA003802
2375 DA003803
2376 DA003903
2379 DE005401
2379 DE005404
2380 DE005501
2383 DE005801
2385 DE006002
2387 DE006201
2387 DE006204
PF Chinook Salmon
PF Broun Trout
PF Lm Bass
UB Carpsucker
WB White Sucker
WB White Sucker
PF Lm Bass
PF Lm Bass
PF Pickerel
WB White Sucker
WB White Sucker
WB Carp
PF Lm Bass
WB Carp
WB Carp
WB White Sucker
WB Carp
PF Walleye
2394 OE006901 f WB Carp
2394 00006901 L WB Carp
2394 00022189 L WB Carp
2397 DE007204 F PF Walleye
2397 DE007201 F WB Sucker
2410 DE008501 F WB Carp
2410 DE008504 F PF Sm Bass
2416 OE009101 F WB Carp
Here
M9/9
0.592
0.068
0.522
0.076
0.11
0.23
0.18
0.2
0.11
0.14
0.366
0.356
0.230
0.32
0.16
0.74
0.20
0.21
NO
0.32
0.24
0.296
0.06
0.100
0.2
1.07
0.47
0.64
0.17
NO
0.14
0.45
0.11
0.16
0.167
0.06
0.15
0.03
1.77
0.13
0.08
0.16
NO
123
TCB
3.53
0.77
0.51
NO
NO
NO
0.35
NO
NO
0.46
2.11
24.8
NO
0.60
NO
NO
1.10
3.23
NO
0.57
NO
NO
NO
NO
NO
NO
NO
124
TCB
2.25
0 0.47
D 0.37
NO
0.29
0.65
0 0.29
0.47
0.78
0 0.54
0 1.73
49.0
0.59
0 0.32
0.84
0.78
0 0.71
5.66
1.28
D 0.57
0.69
1.25
NO
NO
3.33
NO
10.2
135
TCB
D 0.44
D NO
D NO
NO
0 NO
0 NO
D NO
D NO
D NO
D 0.15
D NO
NO
D NO
D NO
0 NA
D NO
D NO
0.29
D NO
D NO
D NO
D NO
NO
NO
NO
NO
NO
1234
TCB
D NO
NO
NO
NO
NO
NO
NO
NO
NO
D 0.35
NO
11.3
NO
NO
NO
NO
NO
D 0.93
NO
NO
NO
NO
NO
NO
2.45
NO
4.76
1235
TCB
NO
NO
NO
NO
NO
NO
NO
NO
NO
D 0.33
NO
12.9
NO
NO
NO
NO
NO
D NO
NO
NO
NO
NO
NO
NO
D NO
NO
NO
1245
TCB
HO
NO
NO
NO
NO
NO
NO
NO
NO
D 0.33
NO
12.9
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
DCS
HO
NO
NO
NO
NO
NO
NO
NO
NO
D 16.8
14.8
14.3
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
50.7
5.61
NO
PCB
HO
NO
NO
NO
NO
NO
NO
NO
NO
0.82
1.46
8.56
NO
NO
NO
0.82
NO
2.77
3.40
NO
NO
2.24
1.63
NO
3.64
NO
5.21
PCI
HD
NO
NO
NO
NO
NO
NO
NO
NO
D NO
D NO
HD
NO
NO
NO
D NO
NO
NO
NO
NO
NO
D NO
D NO
NO
NO
NO
NO
HC8
HO
NO
NO
NO
NO
aBHC
gBHC
30.3
1.95
NO
6.10
NO
NO
CIS
CHLOR
TRANS
CHLOR
2.67 3.98
NO NO
NO NO
HO 3.67
4.35 2.49 D
NO NO
NO
NO
NO
NO
NO
NO
NO
NO
NO 2.94 NO NO 14.9
NO NO NO NO 4.74
NO 1.12 0 0.58 0 1.26 0 HO
1.16 D 0.27 D 1.96 D 1.08 D NO
8.19 2.27 D 1.33 D 18.1 5.58
8.87 4.76 NO 17.0 1.91 D
NO
7.22
NO
15.2
NO
NO
125 E 84.7
3.69 NO
1.42 D 1.09 0 NO
85.5 NO 5.43
NO
5.06
55.3
NO
3.08
30.6
NO NO
NO 17.4
6.94 19.3
NO NO
9.16
NO
NO
NO
18.1
18.9
NO
15.8
25.1
18.2
1.28 D NO
100 78.5
179 125
NO NO
83.2 71.5
129 107
118 96.0
0.85 0 2.22 D NO 2.70 NO
25.3 20.8 NO 95.3 53.8
2.38 D 1.45 D 0.86 D 1.86 D NO
NO 15.9 44.5 164 112
D-S-5
-------
XENOB10TICS CONCENTRATIONS, ng/g
Episode SCC Type Description
Merc
P9/9
123
TCB
124
TCB
135
TCB
1234
TCB
1235
TCB
1245
TCB
DCS
PCS
PCNB
HCB
aBHC gBHC
CIS
CHLOR
TRANS
CHLOR
2422 DE009702 F UB Carp 0.206 NO NO ND
2427 DE010203 F PF Walleye 0.23
2427 DE010202 F UB Carp 0.10 NO 1.24 0 ND
2429 DE010403 F PF Walleye 0.33
2429 DE010402 F W8 Carp 0.27 ND ND ND
2430 DE010602 F PF Northern Pike 0.2
2430 DE010603 F WB Redhorse Sucker 0.10 ND ND ND
2430 00721488 I WB Redhorse Sucker NO NO ND
2431 DE010702 F PF Brown Trout
2431 DE010703 F WB Sucker
2432 DE010713 F PF Walleye
2432 OE010710 F WB Redhorse Sucker
2435 DE011004 F PF Brook Trout
2435 DE011001 F WB Longnose Sucker
2437 DEO11202 F PF Walleye
2437 DE011203 F WB Carp
2439 DE011401 F WB Carp
2439 DE011402 F WP Sm Bass
2478 DJ003901 F BF Sucker
2478 DJ003903 F WB Chi setmouth
2478 DJ003902 F WB Sucker
2500 DC010201 F PF Bass
2500 DC010203 F WB Black Buffalo
2532 DF019302 f PF Lm Bass
2532 DF019303 F WB Carp
2544 OF019203 F PF Lm Bass
2544 DF019202 F WB Blacktail Redhorse
2608 DE014501 F PF Walleye
2608 OE014504 F WB Carp
2618 DE015401 F WB Carp
2618 OE015402 f BF Carp
2618 DE015403 F WB Quillback
2651 DB008401 F WB White Sucker
2653 DB008503 F WB Carp
2654 DB008601 F WB Carp
2709 DB005101 F WB Catfish
2721 DA006502 F WB Sucker
2721 00011089 L WB Sucker
2722 DA006601 F WB Sucker
2725 DA006301 f WB Sucker
2748 OY006506 F BF Sucker ND
2748 DY006505 F WB Sucker ND 0.51 D ND ND
2776 DY007103 F PF Trout ND
2776 DY007101 F WB Carp ND ND ND ND
2776 00010489 L WB Carp ND ND ND
0.27
0.09
0.49
0.25
0.13
0.08
0.29
0.12
0.05
0.05
0.16
ND
0.14
0.26
0.12
0.11
ND
0.73
0.58
0.69
0.18
0.02
0.06
0.04
0.28
0.14
0.68
0.10
0.11
0.34
0.06
ND
ND
ND
ND
ND
ND
ND
0.32
0.65
ND
2.11
ND
0.33
1.86
ND
0.47
10.59
1.59
ND
ND
ND
ND
ND
ND
ND
ND
1.81 D
ND
ND
D 0.47 D
D ND
ND
D ND
ND
D 0.34 D
D 1.49 D
0.45 D
D 0.93 D
264. 81E
D 3.01
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND ND ND ND ND ND
ND ND ND ND ND ND
ND ND ND ND ND ND
ND ND ND ND ND ND
ND ND ND ND ND NO
ND ND ND ND ND ND
ND ND ND ND ND ND
ND ND ND ND ND ND
ND ND ND ND ND ND
ND ND ND ND ND ND
ND ND ND ND ND ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND ND ND ND ND ND
ND ND ND 6.27 9.61 ND
ND
ND ND ND
11.3 ND ND
1.92 D ND ND
ND 2.92 ND
ND ND ND
ND 0.59 D ND
0.57 D 0.93 D 0.93 D ND 1.98 D ND
ND 0.52 D 0.52 D ND ND ND
ND ND ND ND ND ND
ND ND ND ND ND ND
ND ND ND ND ND ND
ND ND ND ND ND ND
ND
ND
NO
2.72 11.3 ND ND NO
7.51 29.0 ND 92.1 45.8
ND 9.09 4.65 31.0 14.5
ND ND ND ND ND
0.5T 0 1.56 D HO NO ND
ND 2.32 D ND ND ND
1.76 D 3.37 ND ND ND
2.36 D 9.08 2.97 26.5 11.8
ND ND ND 12.2 ND
6.49 5.56 27.4 96.0 69.4
3.08 2.61 9.95 41.0 20.3
ND 1.04 D ND 1.97 D ND
ND 0.52 D 2.1fl D 6.51 5.53
93.7 ND 2.24 D 41.0 48.0
ND
ND
ND
ND
ND ND
4.03 15.9 ND
ND
ND
4.86
6.73
22.5 6.00 17.2 147 118
5.41 2.07 D 6.58 39.4 31.4
ND ND 24.4 131 97.1
ND 0.80 D ND 9.90 3.92
2.56 1.45 D 5.25 ND ND
0.84 D 2.37 D ND 37.25 64.66
3.48 3.58 3.97 41.1 20.9
ND ND ND ND ND
ND ND ND ND ND
ND ND ND ND ND
ND ND 19.0 ND ND
ND
ND
ND
ND
ND
ND
ND
ND
1.11 D ND
1.31 D ND
D-5-6
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3001 DE019501
3001 DEO19503
3022 DA008402
3022 DA008401
3023 DA008501
3024 DA008601
3025 DA008702
3025 DA008701
3026 DA009001
3026 DA009002
3027 DA009301
3028 DA008801
3034 DG025702
3034 DG025701
3035 DG025802
3035 DG025801
3036 DG025901
3036 DG025902
3037 DG026002
3037 DG026001
3038 DG026102
3038 OG026101
3039 DG026202
3039 DG026201
3040 DG026302
3040 DG026301
3041 DG026401
3041 DG026402
3042 DG026501
3042 DG026502
3042 00026501
3043 DG026602
3043 DG026601
3044 DG026702
3044 DG026701
3045 DG026801
3045 DG026802
3046 DG026901
3047 DG027002
3047 DG027001
3048 DG027101
3048 DG027102
3048 00012689
3048 00027101
3049 DG027202
F PF Walleye
F WB White Sucker
F PF Chain Pickeral
F WB White Sucker
F PF Sm Bass
F PF Lm Bass
F PF Chain Pickeral
F WB White Sucker
F WB Catfish
F PF Lm Bass
F WB Sucker
F PF Chain Pickerel
F PF Lm Bass
F WB Carp
F PF Sm Bass
F WB Carp
F PF Freshwater Drum
F WB Carp
F PF Black Crappie
WB Carp
BF Channel Catfish
WB Carp
BF Channel Catfish
WB Carp
PF White Crappie
WB Carp
BF Channel Catfish
WB Carp
WB Carp
PF Northern Pike
WB Carp
PF Flathead Catfish
WB Carp
PF Flathead Catfish
WB Carp
WB Carp
BF Flathead Catfish
WB Bigmouth Buffalo
PF Sm Bass
WB Carp
WB Carp
PF White Bass
L PF White Bass
L WB Carp
F PF Crappie
Merc
M9/9
0.82
NA
0.31
0.05
0.54
0.37
0.99
0.28
0.08
0.8
0.21
0.73
0.13
0.08
0.17
0.08
0.19
ND
0.09
0.12
0.077
ND
0.08
0.05
0.39
0.11
ND
ND
ND
0.64
0.16
ND
0.19
ND
0.13
0.24
0.14
0.21
0.09
NO
0.13
123
TCB
ND
0.28
0.37
0.34
ND
ND
ND
ND
0.39
ND
ND
ND
0.29
ND
ND
0.19
ND
ND
ND
ND
ND
ND
ND
NO
0.14
ND
ND
124
TCB
ND
D 0.47
D 0.22
D 0.67
.28
ND
0.17
ND
D 0.57
ND
ND
ND
D ND
ND
ND
D ND
ND
0.46
ND
ND
NO
ND
ND
1.16
D 0.09
ND
ND
135
TCB
ND
D 0.18
D ND
D ND
D ND
ND
D ND
ND
D ND
ND
NND
ND
0.15
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
D 0.66
D ND
ND
ND
1234
TCB
ND
D 0.25
ND
0.28
.09
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
1235
TCB
ND
D ND
ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1245
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DCS
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PCS
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.88
ND
0.77
ND
ND
ND
NO
ND
0.84
0.82
ND
ND
PCNB
ND
ND
ND
ND
.12 D ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
D 15.5
D ND
ND
ND
HCB
ND
ND
ND
ND
0.60
ND
ND
ND
aBHC
ND
ND
ND
ND
gBHC
ND
ND
ND
NO
CIS
CHLOR
ND
ND
ND
ND
0.59 D 2.40 D 0.67 D 5.05
ND
0.73
1.41
0.93
0.86
ND
16.8
1.73
D
D
D
D
D
ND
2.
1.
2.
2.
ND
1.
0.
73
83
83
27
84
21
ND
10
D ND
2.
D ND
ND
D 8.
D 0.
.3
53
25
51
ND
8.65
22.6
ND
12.4
73.9
102
0 8.95
D 0.99
12.3
ND
5.03
D 0.76
83.3
ND
70.9
D 1.50
51.8
1.34
89.9
1.37 D 2.59 2.31 D ND
3.37
3.06
ND
0.59
2.93
ND
ND
D 1.16
10.1
10.5
ND
D ND
ND
196
19.9
23.6
ND
2.32
ND
ND
ND
ND
D 2.01
ND
NO
ND
ND
D 3.50
ND
ND
2.23
ND
4.74
0.76
0.66
D 1.68
D
D
D
ND
4.99
0.80
0.77
5.02
ND
147
D ND
D ND
200
TRANS
CHLOR
ND
ND
ND
ND
3.50
ND
8.00
26.3
ND
13.0
77.4
86.8
E 7.03 E
D 1.25 D
57.1
D 0.72 D
90.8
ND
ND
E 188 E
21.2
21.8
ND
E 135
ND
ND
E 169
0.17
D-5-7
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3049 OG027201
3050 06027301
3060 DF009101
3060 DF009102
3060 00073189
3061 OF01910S
3061 DF019106
3062 DF024024
3063 DF023301
3063 OF023302
F WB Carp
F UB BigMOUth Buffalo
F UB Flathead Catfish
F UB S« Buffalo
UB Flathead Catfish
F PF Bass
F UB Sucker
F UB Blue Catfish
F UB Sea Catfish
F PF Spotted Seatrout
3064 DF023306 F PF Spotted Seatrout
3064 DF023305 H Shellfish
306S DF023419 F BF BigMuth Buffalo
3065 DF023420 F UB Flathead Catfish
3065 00010788 F BF Bignwuth Buffalo
F UB Catfish
PF Freshwater Drum
Oysters
3068 DF024002 F PF Atl. Croaker
3069 DF024007 F UB Sea Catfish
3069 OF024008 F PF Trout
3069 00051788 F UB Sea Catfish
3070 OF024009
3070 DF024010
3071 DF024014
3071 DF024015
3072 OF024018
3066 DF023503
3066 DF023504
3068 DF024001 N
F UB Croaker
F PF Sheepshead
F UB Carp
F PF Longnose Gar
F PF White Bass
3072 OF024017 F UB Carp
3072 00070688 L UB Carp
3073 DF019222 F PF
3073 DF019221
3074 OF026017
3075 DF024102
3076 DF028503
3076 DF028502
3077 OF019113
3077 DF019114
3078 DF009118
3078 DF023815
3078 DF023816
3079 DF019205
3079 DF019206
3080 DF023317
3080 DF023318
3081 OF024105
SM Bass
F UB White Sucker
F PF Brown Trout
F BF Hardhead Catfish
F PF Spotted Bass
F UB Channel Catfish
F PF Flathead Catfish
F UB Redhorse Sucker
F UB Carp
F UB Sn Buffalo
F PF Black Crappie
F PF White Bass
F UB Carp
F UB Carp
F PF L« Bass
F PF White Bass
Merc
P9/9
0.09
0.09
0.12
NO
0.24
0.20
ND
0.23
0.15
0.07
0.00
0.06
ND
NA
ND
0.08
NO
ND
0.11
0.20
NA
0.05
0.06
0.08
0.66
0.49
0.11
NA
0.204
0.06
0.07
0.38
0.58
0.09
0.882
0.42
NA
0.26
0.07
0.18
0.06
0.23
0.83
0.68
123
TCB
ND
ND
ND
NO
ND
ND
1.73
ND
NO
ND
ND
0.37
ND
0.51
0.52
0.62
NO
ND
1.04
ND
5.84
1.48
ND
ND
ND
ND
0.27
0.69
NO
ND
ND
NO
ND
ND
ND
ND
0.64
0.16
0
D
D
D
D
0
D
0
D
D
D
124
TCB
0.40
ND
ND
NO
ND
0.06
1.05
1.36
0.45
ND
0.15
0.63
0.15
1.11
0.71
0.34
0.66
ND
0.60
ND
3.39
0.87
NO
0.97
ND
ND
0.25
0.43
ND
ND
ND
NO
ND
ND
ND
4.81
0.36
ND
D
D
0
D
D
D
D
D
D
D
D
D
D
D
D
D
D
135
TCB
ND
ND
NO
ND
ND
ND
NO
0.54
0.18
HO
NO
ND
ND
ND
ND
ND
0.45
ND
NO
ND
0.56
0.14
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
1234
TCB
ND
ND
NO
ND
ND
ND
ND
D 3.47
D 5.21
NO
0.60
0.19
ND
NO
ND
ND
D ND
ND
ND
ND
D ND
D NO
NO
NO
ND
NO
ND
ND
ND
ND
ND
0.38
ND
ND
ND
ND
NO
0.06
1235
TCB
ND
ND
ND
ND
ND
NO
ND
8.74
NO
NO
D ND
D ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
0.53
ND
D ND
1245
TCB
ND
ND
ND
ND
ND
ND
ND
8.74
9.10
ND
ND
ND
NO
NO
ND
ND
ND
NO
NO
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
3 0.53
ND
ND
DCS
ND
ND
ND
ND
ND
ND
ND
43.1
4.53
ND
ND
ND
NO
ND
ND
ND
ND
0.56
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
D ND
ND
NO
PCB
ND
ND
ND
ND
ND
ND
NO
10.4
51.40
ND
ND
0.24
ND
0.81
ND
ND
1.99
D ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
HO
ND
ND
NO
0.34
ND
NO
ND
ND
ND
ND
PCI
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
D NO
ND
D ND
ND
ND
D NO
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
D ND
NO
ND
ND
ND
ND
NO
HCB
1.27
1.37
NO
NO
NO
0.13
NO
75.0
43.69
NO
0.30
3.26
0.31
6.19
2.41
NO
7.66
NO
NO
NO
NO
NO
NO
NO
0.73
0.48
NO
NO
NO
ND
NO
ND
NO
2.10
2.24
ND
NO
0.12
D
D
D
D
D
D
0
D
D
D
0
aBHC
2.51
4.51
ND
NO
NO
0.42
ND
2.69
3.23
0.80
ND
1.94
ND
6.63
ND
NO
10.1
3.10
NO
ND
4.71
ND
ND
NO
0.96
0.54
ND
NO
0.99
ND
ND
4.04
0.31
ND
2.19
3.33
ND
0.58
gBHC
2.68
3.19
ND
ND
NO
D ND
ND
3.15
NO
D 1.98
ND
D 0.81
ND
ND
ND
5.34
6.68
ND
NO
5.11
NO
ND
9.53
ND
D 0.66
D 0.78
ND
NO
D ND
NO
ND
1.07
D NO
1.59
D 2.58
14.4
NO
D ND
CIS
CHLOR
ND
21.0
ND
9.19
NO
ND
11.5
6.16
8.07
D ND
2.70
D 8.46
2.88
19.8
1.75 D
NO
8.78
3.51
ND
1.89 D
2.59
ND
82.09
66.04
D 2.00 D
D 2.30 0
NO
ND
ND
ND
ND
D ND
NO
D 5.19
13.2
NO
ND
1.70 D
TRANS
CHLOR
30.2
18.2
ND
15.64
ND
ND
9.30
ND
3.13
3.12
3.08
6.86
3.30
19.3
2.64
NO
4.00
ND
ND
NO
ND
NO
91.94
101.90
1.35
1.43
ND
ND
1.83
ND
ND
23.2
1.62
19.67
9.74
31.0
NO
0.26
D
D
D
D
D
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3081 DF024106
3082 DF023402
3082 DF023401
3083 DF023405
3083 DF023406
3084 DF024109
3085 DF024113
3085 DF024114
3086 DF023411
3086 DF023409
3086 DF023410
3087 DF023416
3087 DF023413
3087 DF023414
3087 DF023415
3088 DF023417
3088 DF023418
3089 DF019209
3089 OF019210
3090 DF019213
3090 OF0192U
3091 OF019218
3091 OF019217
3092 DF023501
3092 OF023502
3093 DF024011
3093 DF024118
3094 OC017201
3095 OC038801
3095 DC038802
3096 DC035001
3096 OC035002
3097 DC038701
3097 OC038702
3097 00071989
3098 OC038601
3098 DC038602
3098 00051288
3100 OC019701
3101 OC019901
3103 DC036201
3103 DC036202
3104 DC020001
3104 DC020002
3105 DF025001
F US Catfish
F PF Lffl Bass
F UB Carp
F WB Black Bullhead
F PF Lm Bass
F WB Channel Catfish
F UB Sea Catfish
F PF Black Drum
F PF Black Drum
F UB Catfish
F PF Red Orun
F UP Lffl Bass
F UB Carp
F PF Uhite Crappie
F UP Bluegill
F UB Channel Catfish
F PF Bluegill
F PF Uhite Crappie
F UB Carp
F PF Uhite Crappie
F UB Channel Catfish
F PF Uhite Crappie
F UB River Carpsucker
F UB Carp
F PF Warmouth
F PF Lm Bass
F WB Sin Buffalo
F BF Channel Catfish
F BF Brown Bullhead
F UB Channel Catfish
F BF Brown Bullhead
F UB Channel Catfish
F BF Brown Bullhead
F UB Carp
L PF Brown Bullhead
F UB Uhite Sucker
F PF American Eel
F UB Uhite Sucker
F PF Uhite Perch
F PF Brown Trout
F UB Channel Catfish
F UB Carp
F PF Lm Bass
F UB Carp
F UB Carp
Merc
09/9
0.10
NO
NO
ND
0.313
0.10
0.12
0.05
0.08
0.31
0.32
0.09
NO
0.07
0.03
0.05
0.18
ND
ND
ND
ND
0.06
ND
0.26
0.28
0.816
0.207
0.15
0.06
0.08
0.06
0.11
0.16
0.07
0.08
0.19
NA
ND
ND
0.05
ND
0.15
ND
0.08
123
TCB
0.23
NO
0.32
ND
ND
ND
ND
ND
0.57
NO
0.55
ND
0.26
NO
0.43
0.33
0.35
NO
0.31
0.53
0.18
ND
3.36
0.51
ND
1.35
1.47
NO
ND
54.89
ND
3.13
ND
0.99
0.51
ND
ND
0.89
1.31
ND
D
D
D
D
D
D
0
D
D
D
D
0
D
D
124
TCB
0.22
ND
0.30
ND
ND
0.91
ND
ND
0.49
ND
0.46
NO
ND
0.11
0.30
0.21
0.21
ND
0.78
0.29
0.14
0.08
3.30
0.44
0.55
1.11
1.43
ND
ND
0
D
D
D
D
D
D
D
D
D
0
D
D
D
D
D
D
103.82
0
0
D
D
ND
5.15
ND
0.78
0.79
ND
ND
0.98
1.23
NO
D
D
D
D
135
TCB
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.08
ND
ND
ND
0.48
ND
0.12
ND
ND
ND
ND
ND
ND
ND
ND
1234
TCB
0.07 D
ND
ND
ND
ND
ND
2.18 0
6.35
ND
NO
ND
ND
ND
ND
ND
ND
ND
0.05 0
ND
ND
ND
0.09 D
10.4
1.82 D
3.50
D 1.16 D
10.6
20.92
6.34
D 76.65
ND
D 2.22 D
ND
ND
0.28 D
ND
ND
ND
NO
ND
1235
TCB
NO
ND
ND
ND
3.46
1.08
3.17
10.7
ND
ND
ND
ND
ND
ND
0.16
ND
0.27
ND
NO
NO
ND
ND
4.25
1.44
1.64
1.29
6.18
4.21
0.79
28.30
NO
1.23
ND
ND
ND
NO
ND
ND
HD
NO
1245
TCB
ND
ND
ND
ND
3.46
D 1.08 D
3.17
10.7
NO
ND
ND
ND
ND
ND
D 0.16 D
ND
D 0.27 D
ND
ND
ND
NO
NO
4.25
D 1.44 D
D 1.64 D
D 1.29 D
6.18
4.21
D 0.79 D
28.30
ND
D 1.23 D
NO
ND
ND
ND
NO
NO
ND
ND
DCS
ND
ND
NO
ND
65.3
ND
138
ND
ND
ND
ND
ND
ND
ND
NO
ND
0.74
ND
ND
ND
ND
HD
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
PCB
0.06
ND
ND
ND
42.6
11.02
E 125
ND
ND
ND
ND
ND
ND
ND
NO
ND
D 0.57
ND
0.32
ND
ND
ND
7.76
1.71
5.41
1.19
9.47
30.49
46.3
36.17
NO
1.30
ND
0.53
0.35
NO
ND
HD
1.26
ND
PCI
D ND
ND
ND
ND
NO
ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
D ND
ND
ND
ND
ND
D ND
ND
D HD
NO
ND
ND
ND
ND
0 ND
NO
D ND
D ND
ND
ND
ND
D ND
ND
HCB
ND
1.54
ND
ND
913
50.74
202
18.1
ND
NO
ND
ND
ND
ND
0.34
ND
1.35
ND
ND
ND
ND
0.25
5.38
ND
ND
ND
ND
2.57
12.5
1.97
ND
0.77
ND
2.74
0.31
2.11
ND
ND
NO
ND
D
E
E
D
D
D
D
D
D
D
aBHC
0.83
7.56
0.43
2.27
NO
ND
4.23
0.74
2.83
0.93
2.98
17.8
ND
ND
0.90
ND
2.17
0.63
1.65
NO
ND
0.65
2.78
ND
ND
0.64
15.3
1.10
NO
0.41
ND
ND
44.4
4.27
NO
ND
ND
1.58
HD
HD
D
D
D
D
D
D
D
D
D
0
D
D
D
D
gBHC
HD
NO
ND
9.57
NO
NO
1.64
0.29
NO
ND
1.54
ND
NO
ND
0.49
ND
1.40
0.42
NO
ND
NO
NO
1.68
2.09
ND
ND
4.86
ND
ND
ND
ND
38.8
ND
2.85
ND
ND
22.6
NO
5.04
ND
CIS
CHLOR
ND
ND
ND
80.6
ND
ND
D 6.62
D ND
ND
NO
D ND
ND
ND
ND
0 4.02
0.90
D 19.3
D 0.62
ND
ND
ND
1.68
D 92.8
D 23.1
78.4
5.80
97.7
3.76
7.80
2.44
NO
1.95
ND
4.52
0.22
26.25
ND
1.80
56.9
6.22
0
D
D
E
0
D
0
D
E
TRANS
CHLOR
NO
7.85
NO
39.8
ND
ND
ND
NO
4.38
ND
HO
HO
HD
HD
2.73
0.44
11.2
HD
NO
NO
ND
0.93
58.1
17.2
53.1
7.61
62.2
5.81
ND
3.81
ND
7.12
ND
13.08
2.63
51.05
15.9
4.75
45.4
3.33
0-5-9
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3105 DF025002
3106 OE026801
3107 OE026901
3108 DE027001
3108 DE027002
3109 DE025001
3110 OE022501
3111 DH015801
3111 DH015802
3112 DE022401
3112 DE022402
3113 DE021101
3113 DE021102
3113 00030789
3114 DE021201
3115 DE021301
3115 DE021302
3115 00101689
3117 DE021501
3118 OE021601
3118 DE021602
3118 DE021603
3118 00010689
3118 00020468
3119 DE021702
3119 OE021701
3120 DE021601
3120 DE021802
3122 OE022004
3122 DE022001
3122 DE022003
3125 OE022301
3125 DE022302
3132 OE023201
3132 00010588
3134 OE023403
3134 DE023405
3134 OE023406
3135 DE023501
3136 OE023601
3137 OE023701
3138 OE023801
3140 DE024001
3140 OE024002
3141 OE024101
F PF Lm Bass
F PF Walleye
F US Carp
F PF Walleye
F WB Carp
F WB Carp
F BF Carp
F PF Walleye
F WB Silver Redhorse
F WB Carp
F PF Walleye
BF Channel Catfish
F BF Carp
F BF Channel Catfish
F BF Carp
F WB Carp
BF Catfish
I WB Carp
F PF Lake Trout
F PF Walleye
F WB Carp
F WB Carp
L WB Carp
I PF Walleye
F PF Lm Bass
WB Carp
WB Carp
PF Bass
PF Sm Bass
WB Carp
WB Redhorse Sucker
WB Carp
PF White Bass
WB Carp
WB Carp
WB Carp
WB Carp
WB Sucker
WB Carp
PF Northern Pike
WB Redhorse Sucker
WB Carp
PF Walleye
WB Carp
PF Northern Pike
Merc
M9/9
0.134
0.57
0.16
0.25
0.30
0.23
0.11
0.91
0.14
0.179
0.47
0.08
0.08
0.07
0.05
0.09
0.22
0.56
0.15
0.24
NA
0.28
0.33
0.17
0.30
0.56
1.40
0.61
0.11
0.48
0.22
NA
0.09
0.03
0.05
0.09
0.24
0.13
0.21
0.09
0.04
0.17
123
TCB
ND
0.57
ND
0.18
ND
0.44
ND
ND
0.70
ND
ND
ND
ND
ND
ND
2.48
ND
6.94
ND
1.77
ND
ND
ND
ND
0.22
NO
0.16
ND
0.51
1.47
2.05
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
124
TCB
NO
0 0.42
0.07
0 0.13
ND
0 ND
ND
0.50
0 0.63
ND
ND
ND
0.50
0.24
2.43
D 4.98
1.06
4.51
ND
D ND
ND
ND
ND
0.20
D 0.13
ND
D 0.19
ND
D 0.26
D 8.41
D 11.94
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.59
135
TCB
ND
D ND
D ND
D ND
ND
ND
ND
D ND
D ND
ND
ND
ND
D ND
D ND
D ND
0.57
D NO
ND
ND
ND
NO
ND
ND
D ND
D NO
ND
0 ND
ND
0 ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
D ND
1234
TCB
NO
ND
0.10
NO
0.11
NO
ND
ND
ND
0.03
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
0.06
ND
ND
ND
ND
0.74
0.78
ND
ND
ND
ND
0.04
ND
ND
ND
ND
ND
1235
TCB
NO
ND
D ND
ND
D ND
ND
ND
ND
0.28
D ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
NO
ND
NO
NO
NO
D ND
NO
NO
NO
ND
D NO
D ND
ND
ND
ND
NO
0 ND
NO
ND
ND
ND
ND
1245
TCB
ND
ND
ND
ND
ND
NO
NO
NO
D 0.28
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
oc:
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
NO
NO
NO
NO
NO
NO
ND
ND
NO
NO
NO
NO
ND
NO
ND
ND
ND
ND
PCS
ND
ND
ND
NO
NO
NO
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
0.87
0.91
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.54
PCNB
NO
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
MO
ND
NO
NO
D ND
D 13.85
ND
ND
NO
NO
NO
ND
ND
ND
ND
0 ND
HCB
ND
NO
0.77
ND
HO
NO
ND
ND
1.63
ND
1.57
1.68
1.21
0.75
3.82
ND
NO
5.22
0.10
NO
0.74
ND
0.24
ND
0.15
NO
NO
2.64
NO
ND
ND
0.73
ND
ND
0.92
ND
ND
1.44
ND
0.49
ND
0
0
D
D
D
D
D
D
D
D
D
D
D
D
aBHC
NO
NO
1.81
NO
1.77
NO
1.08
10.6
2.77
ND
0.79
ND
0.50
1.45
ND
ND
0.76
5.48
ND
ND
0.39
ND
0.18
ND
0.42
8.31
1.55
6.56
0.34
ND
ND
1.15
1.20
ND
1.46
ND
2.22
NO
ND
ND
3.31
D
D
D
D
D
D
0
0
D
0
0
0
0
0
0
0
gBHC
NO
ND
ND
ND
ND
ND
ND
7.59
ND
ND
1.39
2.17
1.35
1.71
NO
NO
NO
NO
ND
ND
NO
NO
NO
NO
0.48
NO
0.69
5.68
0.61
12.40
NO
1.17
ND
NO
1.58
ND
NO
ND
NO
ND
ND
CIS
CHLOR
ND
NO
NO
NO
2.03
5.81
4.42
7.53
3.35
ND
0 12.1
0 23.7
D 12.8
D 31.3
31.0
29.1
28.5
154
6.74
18.8
3.88
19.6
7.73
10.40
D 2.99
35.2
D ND
ND
D 2.21
53.84
67.69
D 3.15
5.86
ND
D 4.73
ND
ND
12.5
1.93
3.63
22.2
TRANS
CHLOR
NO
ND
ND
ND
D ND
3.87
2.09
5.24
1.17
ND
7.44
14.4
7.86
33.5
36.4
39.4
34.1
51.8
1.71
5.60
1.41
6.29
1.87
6.06
0.86
18.4
ND
NO
0 0.50
41.20
46.00
2.55
7.30
ND
2.74
ND
ND
7.59
D 0.72
2.32
6.93
0
0
D
D
D
D
D
D
D
D-5-10
-------
XEH06IOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3141 DE024102
3141 OE024103
3142 OE022502
3143 OE024401
3143 OE024403
3144 DE024901
3145 DE026601
3146 DE026701
3146 DE026702
3147 DC035201
3148 DE027101
3148 DE027103
3149 DC038501
3150 DA008901
3150 00120187
3151 DA009101
3152 DA009201
3161 OC019801
3161 OC019802
3162 DJ024001
3163 DJ024002
3164 00015701
3164 00015702
3165 00015703
3165 00015704
3166 00015705
3166 00015706
3167 00015707
3167 DD015708
3167 00062388
3168 00015711
3168 00015712
3169 DOO15714
3169 00015713
3169 00022789
3170 00015716
3170 00015715
3171 00015718
3171 DD015717
3172 00015719
3172 00015720
3173 00015721
3173 00015722
3174 00015723
3174 00015724
WB Carp
PF Northern Pike
WB Carp
Rotten (catf)
WB Carp
WB Carp
WB N. Redhorse
WB Carp
PF Walleye
WB Carp
WB Carp
PF Walleye
WB White Sucker
WB White Sucker
WB White Sucker
WB White Sucker
WB White Sucker
F BF Black Bullhead
F WB White Sucker
F WP Starry Flounder
F WP Starry Flounder
F PF Lm Bass
F WB Carp
F PF Lm Bass
F WB Redhorse Sucker
F PF Walleye
F WB White Sucker
F PF Lm Bass
F WP Bluegill
L WP Bluegill
F WB Carp
F PF Lm Bass
F PF Lm Bass
F WB Black Redhorse
L WB Black Redhorse
F PF Lm Bass
F WB Spotted Sucker
F PF Lm Bass
f WB Spotted Sucker
F WB Carp
F PF Lm Bass
F PF Lm Bass
F WB Channel Catfish
F PF Lm Bass
F WB Channel Catfish
Here
M9/9
0.02
0.14
0.04
0.01
0.05
0.20
0.22
0.16
0.28
0.05
0.08
0.82
0.14
0.158
HA
0.22
0.06
0.12
0.05
0.05
NO
0.665
0.18
0.43
0.25
0.87
0.29
0.33
0.08
NA
0.19
0.37
0.4
0.16
0.82
0.15
0.72
0.15
NO
0.11
0.31
0.06
0.29
0.05
123
TCB
NO
NO
7.46
3.78
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
0.20
NO
0.53
NO
NO
NO
30.2
4.90
0.24
NO
NO
NO
0.22
NO
NO
NO
NO
NO
NO
NO
NO
124
TCB
NO
NO
4.71
2.32
NO
NO
NO
NO
NO
0.55
NO
NO
NO
NO
NO
D NO
NO
D 0.55
NO
NO
NO
23.3
8.52
0 0.25
NO
NO
NO
0 NO
NO
NO
0.12
0.09
0.69
NO
0.42
NO
135
TCB
NO
NO
NO
D NO
NO
0.26
NO
NO
NO
D NO
NO
NO
NO
NO
NO
NO
NO
D NO
NO
NO
NO
NO
0.14
D NO
NO
NO
ND
NO
NO
NO
D NO
D NO
D NO
NO
D NO
NO
1234
TCB
NO
NO
NO
NO
NO
0 NO
NO
NO
HO
NO
0.37
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
6.29
0 1.10
0.23
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
1235
TCB
NO
NO
HO
NO
NO
0.39
NO
NO
NO
NO
0 NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
3.12
D NO
D 0.13
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
1.26
NO
1245
TCB
NO
NO
NO
NO
NO
0 0.39
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
3.12
NO
0 0.13
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
D 1.26
NO
DCS
NO
NO
NO
NO
NO
0 NO
NO
NO
NO
NO
NO
NO
NO
NO
ND
NO
ND
ND
NO
33.
ND
ND
ND
D ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
PCB
0.78
NO
NO
ND
0.28
NO
ND
ND
ND
0.81
ND
NO
NO
ND
ND
NO
ND
0.52
1.45
ND
ND
2.77
ND
ND
ND
NO
0.56
ND
ND
NO
ND
ND
NO
ND
NO
ND
PCNB
D ND
ND
NO
ND
D NO
ND
ND
ND
ND
D ND
ND
NO
ND
ND
ND
NO
ND
D ND
D ND
ND
ND
NO
ND
ND
ND
NO
D NO
ND
ND
ND
ND
ND
NO
NO
ND
NO
HCB
4.69
NO
NO
NO
0.81
NO
0.57
1.21
NO
3.64
3.19
NO
0.23
NO
NO
NO
NO
0.64
NO
29.2
NO
aBHC
NO
1.90
5.87
NO
0 1.33
NO
0 1.95
0 0.85
NO
3.98
3.29
NO
0 0.26
NO
1.84
1.47
NO
0 0.59
4.64
0.45
0.25
gBHC
6.28
0 NO
NO
NO
0 NO
NO
0 1.82
0 NO
NO
6.40
1.71
NO
0 6.40
6.34
0 6.50
D 1.56
3.98
D NO
1.40
D NO
D 0.66
CIS
CHLOR
56.5
10.3
67.8
NO
6.92
6.88
0 NO
NO
NO
42.6
D NO
7.37
10.0
13.0
14.3
D 7.19
NO
23.03
0 155
1.96 D
D 0.58 D
TRANS
CHLOR
30.9
2.79
38.7
NO
3.52
4.23
NO
NO
NO
28.9
NO
2.12
3.64
6.12
6.62
2.92
NO
36.15
82.7
0.76
NO
ND
ND
ND
ND
ND
NO ND
ND ND
ND ND
NO ND ND
ND NO NO
4.84 1.86 D ND
0.89 D ND
NO
ND
0.09 D ND
0.09 D ND
NO NO
ND NO
ND
ND
ND
ND
ND
ND
ND
NO
NO
NO
ND
4.83
4.40
ND
NO ND
1.15 0 6.18
ND ND
ND
ND
ND
ND
3.27
ND
9.70
3.38
NO
ND
ND
ND
ND
1.43 D
ND
NO
2.01 D
0.63 0
0.49 D
5.11
ND
4.53
1.29 0
D-5-11
-------
XEN08IOT1CS CONCENTRATIONS, ng/g
Episode SCC Type Description
3175
3175
3176
3176
3177
3177
3178
3178
3179
3179
3180
3181
3181
3182
3182
3183
3183
3184
3184
3185
3185
3186
3187
3188
3188
3189
3189
3189
3190
3190
3191
3191
3192
3192
3193
3193
3195
3195
3196
3196
3197
3197
3198
3199
3199
DD015802
D0015801
D0015804
D0015803
D0015805
00100488
00015808
D0015807
DD015810
DD015809
00015812
DD015813
D0015814
00015815
00015816
00015817
DD015818
00015819
00015820
00015822
00015821
00015824
00015902
00015903
00015904
00015906
00015905
00092188
00015908
00015907
DJ024003
OJ024005
OJ024007
OC039002
OC039001
DH020104
OH020105
OH020107
DH020108
OH020110
OH020109
OH020111
OH020102
OH020101
DJ024009 M
PF Lm Bass
UB Channel Catfish
PF Lm Bass
WB Spotted Sucker
UB Carp
WB Carp
PF Redeye Bass
UB North Hogsucker
PF LM Bass
UB Golden Redhorse
PF LM Bass
PF Lm Bass
UB Carp
PF Rock Bass
UB Carp
UB Carp
PF Sauger
UB Carp
PF White Crappie
PF LM Bass
UB Channel Catfish
UP Southern Flounder
UP Sumier Flounder
UB Carp
PF LM Bass
PF LM Bass
UB Carp
UB Carp
PF Lm Bass
UB Carp
UP Starry Flounder
Soft Shell Clams
UP Starry Flounder
Soft Shell Clams
PF Sm Bass
PF Striped Bass
UB Carp
UB Chub
PF Brown Trout
UB Sucker
UB Sucker
PF Rainbow Trout
UB Sucker
PF Walleye
UB Carp
Merc
M9/g
0.4
0.18
0.13
NO
0.03
NA
0.55
0.23
0.44
0.24
0.43
0.28
0.06
0.13
0.04
NO
0.30
0.14
0.31
0.67
0.12
0.05
NO
0.03
0.14
0.26
0.06
NA
0.05
0.05
0.01
0.01
0.01
0.01
0.4
0.35
0.08
0.14
0.182
0.182
0.06
NO
0.12
0.37
0.09
123
TCB
NO
NO
NO
NO
NO
NO
0.39
1.03
NO
NO
NO
NO
NO
NO
NO
NO
1.67
0.16
NO
NO
NO
0.09
NO
0.05
NO
1.71
NO
NO
NO
HO
NO
124
TCB
NO
NO
NO
NO
NO
NO
D 0.27
0 2.25
NO
NO
NO
NO
NO
NO
NO
NO
1.43
0 NO
NO
NO
NO
0 0.07
NO
0 0.08
NO
0 2.46
0.83
NO
NO
2.00
0.17
135
TCB
NO
NO
NO
NO
NO
NO
D NO
0 NO
NO
NO
NO
NO
NO
NO
NO
NO
0.486
0.09 0
1.20 D
0.20 D
0.92 D
D NO
NO
D NO
NO
D NO
D NO
NO
NO
D NO
D 0.06 D
1234
TCB
NO
NO
NO
NO
NO
NO
NO
0.58
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
0.06
NO
0.06
NO
NO
NO
NO
NO
NO
NO
1235
TCB
NO
NO
NO
NO
NO
NO
NO
0 0.65
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
D NO
NO
D NO
NO
NO
NO
NO
NO
HO
NO
1245
TCB
NO
NO
NO
NO
NO
NO
NO
0 0.65
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
HO
NO
OCS
NO
NO
NO
NO
NO
NO
NO
D 1.90
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
0.48
HO
NO
NO
NO
NO
NO
NO
NO
NO
NO
PCB
NO
NO
NO
NO
NO
NO
NO
D 1.02 D
NO
NO
0.73 0
NO
NO
5.73
NO
HO
0.629
NO
NO
NO
D NO
NO
NO
NO
NO
NO
0.54 0
NO
NO
1.21 0
NO
PCI
NO
NO
NO
NO
NO
NO
NO
NO
NO
HO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
HCB
NO
NO
NO
NO
NO
aBHC
NO
NO
NO
NO
NO
0.32 D NO
NO NO
3.25 3.69
NO NO
0.891 D NO
9.30 7.83
0.28 D NO
NO
NO
NO
0.33
NO
NO
NO
NO
0.32
HO
NO
NO
NO
6.57 NO
NO NO
NO HO
NO 5.68
NO NO
3.58
4.11
0 0.51
0.25
NO
NO
NO
D NO
2.29
NO
NO
gBHC CIS
CHLOR
1.48 D NO
NO
NO
NO
NO
NO
NO
NO
0.33
14.6
NO
NO
NO
8.02
NO
NO
NO
NO
3.88
4.67
D NO
0 NO
NO
1.46
NO
NO
D NO
NO
NO
5.32
5.25
NO
8.13
NO
59.8
D NO
41.5
52.3
1.75
NO
38.8
NO
NO
60.1
NO
25.9
31.8
25.2
HO
NO
0 NO
NO
19.8
14.0
30.1
TRANS
CHLOR
NO
1.06
4.18
4.12
NO
6.73
NO
38.5
NO
35.0
40.3
D 0.47
NO
30.6
NO
NO
58.4
NO
18.6
23.7
14.4
NO
NO
NO
NO
4.23
11.1
18.2
1.56 D 1.25 D NO
16.3 12.0 NO 28.8 20.4
0.52 D 0.93 0 0.45 D NO HO
D-5-12
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3199 DH020103 F
3200 DH020112 F
3203 DJ024018 F
3205 DJ024023 F
3205 DJ024024 M
3206 DJ024103 F
3208 DJ024109 F
3212 DJ024120 F
3212 DJ024121 F
3213 DJ024123
3215 DJ023705
3216 DJ023707
3216 DJ023708
3216 00022388
3217 DJ023709
3217 DJ023710
3218 DJ023712
3218 OJ023711
3219 DJ023713
3219 DJ023714
3220 DJ023902
3220 DJ023903
3221 DJ023904
3221 DJ023905
3222 DJ023906
3222 DJ023907
WB Carp
WB Sucker
WB Carp
PF Cutthroat Trout
Crayfish (whole)
F WB Sucker
F WB Sucker
F BF Catfish
F WB Carp
F WB Squawfish
F WB Sucker
F PF Squawfish
F WB Sucker
L WB Sucker
F PF Whitefish
F WB Sucker
F WB Sucker
F PF Squawfish
F WB White Sturgeon
F PF White Sturgeon
F PF Squawfish
F WB Bridgetip Sucker
F BF Channel Catfish
F WB Sucker
F PF Squawfish
F WB Sucker
3223 DJ023717 F WP Starry Flounder
3224 OJ023715 M Soft Shell Clams
3226 DJ023721 N Pacific Oysters
3227 DJ023723 M Pacific Oysters
3231 DJ023910 F PF Sm Bass
3231 DJ023911 F WB Carp
3234 DH020302 F PF Lake Whitefish
3234 DH020301 F WP Squawfish
3235 DH020304 F PF Brown Trout
3235 DH020303 F WB White Sucker
3236 DH020306 F PF Brown Trout
3236 DH020305 F WB Largescate Sucker
3237 DH020307 F PF Rainbow Trout
3237 DH020308 F WB Largescale Sucker
3237 00080988 F WB Largescale Sucker
3238 DJ023918 F WP Dotly Varden
3241 DJ023923 F PF Rainbow Trout
3241 DJ023924 F WP Dolly Varden
3244 DJ023622 F WB Coast Sculpin
Merc
P9/9
0.06
0.11
0.10.
0.07
ND
NO
0.13
0.21
0.22
0.11
0.18
0.33
0.05
NA
0.06
0.07
0.09
0.36
0.10
0.09
0.23
0.05
0.34
0.08
0.74
NO
0.058
0.06
ND
ND
0.24
0.20
0.08
0.14
0.1
0.06
0.1
0.08
0.08
0.14
NA
0.05
0.06
0.05
MO
123
TCB
2.40
0.34
NO
ND
ND
ND
ND
ND
4.78
7.05
ND
0.24
ND
0.12
ND
ND
ND
ND
0.43
ND
ND
ND
0.32
ND
0.20
0.31
ND
ND
ND
NO
ND
ND
ND
124
TCB
D 1.39
D 0.32
0.72
ND
ND
0.38
ND
ND
2.16
6.26
ND
D ND
0.48
D 0.17
ND
0.12
ND
ND
D ND
ND
NO
ND
D 0.23
NO
D 0.14
D 0.55
NO
ND
ND
ND
ND
ND
ND
135
TCB
D ND
D 0.24
0 ND
ND
ND
D ND
ND
NO
D 0.43
ND
ND
ND
D ND
D ND
ND
D ND
ND
ND
ND
ND
ND
ND
D ND
NO
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
1234
TCB
ND
D ND
NO
ND
ND
ND
ND
NO
D ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
NO
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
1235
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.61
ND
ND
ND
ND
ND
ND
1.02
ND
ND
ND
ND
ND
ND
ND
1245
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 1.61
ND
ND
NO
ND
ND
ND
D 1.02
ND
ND
ND
ND
NO
ND
ND
OC!
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D NO
ND
NO
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
PCB
PCNB
ND
0.60 D
0.54 0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
NCB
ND
6.88
2.12
ND
ND
4.98
2.24
15.6
ND
ND
ND
ND
ND
NO
NO
3.32
ND
ND
10.6
1.49
NO
ND
NO
ND
ND
4.55
0.40
0.77
0.67
0.65
1.07
aBHC
ND
NO
D 1.11
ND
7.17
ND
D NO
NO
ND
ND
NO
2.74
5.48
4.03
NO
NO
ND
NO
4.89
D ND
ND
ND
0.35
ND
ND
1.89
D 0.91
D 2.78
D NO
ND
D ND
0 ND
gBHC
ND
ND
D ND
ND
18.6
ND
NO
ND
ND
9.34
ND
ND
ND
ND
NO
ND
ND
ND
6.05
ND
ND
NO
D ND
ND
NO
0 ND
D ND
2.88
2.57
3.35
3.88
ND
CIS
CHLOR
9.33
13.7
9.68
ND
ND
7.03
3.59
13.7
NO
18.1
0.17
ND
NO
ND
0.73
10.8
0.80
ND
10.4
ND
NO
ND
ND
ND
NO
12.3
0.67
0.58
ND
NO
ND
ND
TRANS
CHLOR
B.64
ND
6.70
ND
NO
2.45 D
2.48 D
7.36
NO
6.53
D ND
ND
ND
ND
D ND
9.18
D 0.72 0
ND
4.68
ND
ND
ND
ND
NO
ND
7.27
D ND
D ND
ND
NO
ND
ND
1.47 D ND
ND
1.81 D ND
D-S-13
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3245 DJ023624
3246 OJ022109
3248 DJ022S02
3248 00050588
3249 OJ022503
3249 DJ022504
3250 DJ022505
3250 DJ022506
3252 DJ022509
3252 DJ022510
3252 00020989
3252 00052588
3256 DJ022518
3258 OC038901
3258 DC038902
3259 DB000466
3259 DB000473
3259 DB069101
3260 DB000493
3261 OY026001
3261 DY026002
3262 DY026004
3266 DY022701
3266 DY022702
3266 00012389
3267 OY022101
3267 DY022102
3270 DY022107
3270 OY022108
3271 DY022110
3272 DY022111
3272 OY022112
3273 OY022113
3273 OY022114
3274 DY022115
3274 DY022116
3275 OY022118
3276 DY022119
3278 DY022123
3278 DY022124
3281 DY022205
3282 DY022206
3282 DY022207
3283 OY022209
3285 DY022212
F UP Flathead Sole
f UP Flathead Sole
F UB Composite Bottom
F WB not available
F PF Brook Trout
F UB Sucker
F PF Pink Salmon
F UB Sucker
F PF Lm Bass
F UB Sucker
I PF Lm Bass
L UB Sucker
F UB Sucker
F PF Spot
F UB Croaker
F UB Goldfish
F PF Lm Bass
F UB Sucker
F UB Carp
F PF Giant Kingfish
F UB Striped Mullet
F UB Tilapia Tilapia
F PF Black Crappie
F UB Channel Catfish
L PF Black Crappie
F PF Rainbow Trout
F UB Sacramento Sucker
F PF Squawfish
F UB Sucker
F UB Sucker
F PF Leopard Shark
F UB White Surfperch
F UB Sculpin
F UB Surf Smelt
F PF Rainbow Trout
F UB Sculpin
F UB Sucker
F UB Uatleye
F PF Green Sunfish
F UB Sacramento Sucker
F UB Sucker
F PF Flathead Catfish
F UB Carp
F UB Carp
F UP Stingray
Merc
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3285 DY022213
3286 DY022215
3287 DY022216
3288 DY022217
3288 DY022218
3289 DY022219
3289 DY022220
3290 OY022221
3290 OY022222
3294 DJ022112
3294 DJ022111
3294 DJ022113
3295 DJ0221U
3296 DB040101
3297 DB041501
3298 OB041601
3298 DB041604
3299 DB040601
3299 08040604
3299 00040601
3300 DB040201
3300 DB040204
3300 00021389
3301 DB041101
3301 OB041104
3301 00030989
3302 DB041901
3302 DB041904
3303 DB042301
3303 DB042304
3303 00102588
3304 DB041001
3304 DB041004
3304 00041004
3305 DB042001
3305 DB042004
3305 00110388
3306 DB041801
3306 DB041804
3306 00041801
3307 DB042101
3308 DB040001
3309 DB041301
3310 OC032701
3310 DC032702
UB
UB
UB
PF
UB
UP
WB
PF
UB
PF
UP
UP
UB
UB
UB
PF
UB
PF
UB
UB
PF
UB
UB
PF
PF
UB
PF
UB
PF
UB
PF
UB
UB
UB
PF
UB
UB
PF
UB
UB
PF
UB
UB
PF
Diamond Turbot
Carp
Tilapia Zilti
Squowfish
Sucker
Bocaccio
Scutpin
Redear Sunfish
Blackfish
Atlantic Salmon
True Cod
Mussel
Atlantic Salmon
White sucker
Carp
Carp
Lm Bass
White Sucker
Lm Bass
Sucker
White Sucker
SIR Bass
Channel Catfish
Carp
Northern Pike
Horthern Pike
White Sucker
Lm Bass
White Sucker
S» Bass
White Sucker
Northern Pike
White Sucker
White Sucker
Channel Catfish
S« Bass
Channel Catfish
White Sucker
Sm Bass
White Sucker
White Sucker
Northern Pike
White Sucker
Bullhead
Walleye
Merc
M9/9
0.11
ND
ND
0.11
ND
0.02
NA
0.11
0.06
0.05
ND
0.00
0.05
0.05
0.03
0.00
0.32
0.08
0.11
0.10
0.14
0.08
0.17
0.12
0.25
0.17
1.19
0.48
0.20
0.14
0.32
0.11
0.72
0.17
0.48
0.13
ND
0.24
123
TCB
ND
ND
ND
0.17
ND
3.89
ND
ND
ND
0.19
0.25
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
2.40
0.25
ND
NO
ND
0.27
ND
ND
ND
ND
ND
HO
ND
ND
ND
1.35
ND
1.95
1.58
124
TCB
ND
0.354
0.26
D ND
ND
2.26
0.12
ND
ND
0 0.17
0 0.24
ND
ND
1.06
2.16
ND
0.37
0.28
ND
ND
NO
ND
1.10
ND
ND
D 3.09
D 0.22
ND
ND
ND
D ND
ND
ND
1.58
ND
ND
0.19
NO
0.42
0.14
D 0.79
ND
D 11.0
D 2.46
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
135
TCB
ND
ND
ND
ND
ND
0.36
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
0.32
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
1234
TCB
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
NO
1.78
0.76
NO
ND
ND
ND
0.17
0.13
ND
0.68
ND
HO
D 4.63
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
1235
TCB
ND
ND
ND
ND
ND
ND
ND
NO
ND
0.56
ND
ND
ND
0 0.97
D 0.75
NO
ND
ND
NO
D ND
D ND
ND
D 0.66
ND
ND
1.56
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
1245
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.56
ND
ND
NO
D 0.97
D 0.75
ND
ND
ND
ND
ND
ND
NO
D 0.66
ND
ND
D 1.56
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OCS
ND
ND
NO
ND
ND
ND
ND
ND
ND
D ND
ND
NO
ND
D ND
0 ND
ND
0.94
N
ND
26.6
1.35
1.53
D 49.6
1.01
1.42
D 28.2
ND
ND
ND
ND
NO
3.23
5.38
32.8
ND
37.1
ND
ND
0.84
1.20
ND
ND
ND
ND
PCB
ND
1.08
NO
NO
ND
ND
ND
ND
0.80
ND
ND
ND
ND
6.11
5.82
ND
D 0.45
0.66
NO
2.05
D ND
D ND
5.99
D ND
D ND
8.37
NO
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
D ND
D ND
ND
ND
MO
ND
PCI
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
NO
ND
ND
ND
ND
NO
D ND
D ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
NO
NO
HD
ND
ND
ND
ND
HCB
ND
ND
ND
0.51
2.12
ND
0.33
ND
2.14
0.79
NO
ND
ND
9.43
8.54
ND
5.23
3.03
1.65
9.80
0.54
0.78
43.2
1.20
1.13
11.5
0.30
ND
ND
ND
ND
0.58
1.25
11.1
ND
12.7
0.86
ND
1.22
0.84
ND
0.91
ND
0.80
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
0
aBHC
ND
ND
ND
ND
ND
2.63
1.17
ND
2.54
2.64
0.65
ND
4.57
4.05
16.0
ND
0.84
0.90
0.39
3.42
ND
ND
7.85
HD
ND
3.42
ND
1.70
ND
2.67
NO
0.42
2.36
3.94
ND
6.63
1.77
0.72
2.87
0.97
ND
ND
NO
ND
D
D
D
D
D
D
D
D
D
D
D
gBHC
ND
5.59
6.94
NO
ND
ND
HO
ND
4.85
ND
0.63
ND
4.13
NO
ND
NO
ND
ND
ND
4.16
ND
ND
5.28
NO
HD
1.90
ND
NO
ND
1.83
ND
ND
ND
1.39
ND
ND
ND
ND
1.82
ND
NO
1.83
6.43
ND
CIS
CHLOR
37.4
43.4
3.83
NO
14.9
ND
1.48
ND
33.2
ND
D ND
ND
3.13
8.64
28.5
NO
2.99
1.64
3.57
14.6
1.08
0.93
32.9
1.53
1.86
D 10.3
0.60
ND
ND
D ND
ND
4.43
6.19
D 34.8
ND
38.5
1.94
ND
D 3.01
2.06
ND
D HD
12.2
3.20
D
0
D
D
D
D
D
D
D
TRANS
CHLOR
17.5
31.6
HO
2.48
8.90
ND
0.80
ND
17,3
ND
ND
ND
ND
4.55
18.1
ND
ND
0.32
ND
2.62
ND
ND
14.6
ND
HD
1.54
ND
ND
ND
ND
ND
ND
HD
7.40
ND
8.23
ND
HD
HD
HD
HD
HD
8.07
5.16
D-5-15
-------
XEN08IOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
Merc
123
ICt
124
1C*
135
1C!
1234
UB
1235
1C!
124S
KB
DCS
PCB
PCNB
HCB
•BHC
gBHC
CIS
CHI OR
TRANS
CNIM
3311 DC032801 F UB Redhorse Sucker
3311 DC032002 F PF to IMS
3312 OC033101 f M ftcdhorse Sucker
3312 OC033102 f ff ta Bass
3313 OC033201 F M Redhorse Sucker
3313 OC033202 F »f to Bass
3314 OC03330I F M Channel Catfish
33U OC033302 F Pf White Bess
331S DC033401 F UB Carp
331S OC033402 f Pf l« Bass
3314 DC033501 F W White Sucker
3317 DC033601 F M White Sucker
3318 DC033701 F M White Sucker
3319 DB041401 F UP Winter Flounder
3320 DB041412 F UP Bluefish
3321 DB040401 F WP Winter Flounder
3121 00100680 I WP Winter Flounder
3323 OB041206 F WP Winter Flounder
3324 OB041252 F WP Bluefish
3325 OBM1218 F WP Bluefish
3326 DB04120B F WP Bluefish
3327 DBM0301 F WP Bluef fsh
3327 DBM031S F WP Bluefish
3328 D0029111 F M Carp
3329 00016003 F WB Bowfin
3330 00029110 F WB Spotted Sucker
3331 D0016007 F WB Carp
3332 00016009 F WP Spotted Drum
3333 DD016012 F WB Sea Catfish
3334 00016013 F WB Sea Catfish
3335 0001601S F WP Spot
3335 DD029101 F WP Red Drum
3335 00029102 F WB Southern Flounder
3335 D0029103 F WP Sheepshead
3335 00091588 L WP Red Orua
3336 00016004 F WP Black Onm
3336 00016006 f UP Sheepshead
3336 00016017 F WP Red Orua
3336 00016018 F PF Spotted Seatrout
3337 00016019 F WB Spotted Sucker
3338 00016022 F WB Spotted Sucker
3339 00016023 F WB Carp
3340 OD029114 F WB Channel Catfish
3341 D0016104 F UB Catfish
3341 00081788 L UB Catfish
0.10
0.08
ND
0.09
0.23
0.63
0.07
0.15
NO
0.18
0.07
NO
NO
0.01
0.11
0.02
HA
0.03
0.06
0.03
0.03
0.08
0.10
0.05
0.02
0.18
0.05
0.02
0.18
0.53
0.53
0.63
0,04
0.60
0.04
0.31
0.06
0.08
0.11
0.08
0.10
0.05
0.12
NA
0.22
0.47
NO
1.10
0.13
0.48
NO
0.26
NO
NO
0.15
NO
NO
NO
ND
0.48
0.95
0.10
4.56
0.26
0.80
2.27
2.69
NO
0.17
0.16
NO
ND
NO
ND
ND
ND
0.30
NO
ND
ND
NO
ND
0.10
1.44
0.70
3.16
0.42
NO
NO
D 0.68
0 0.80
NO
D 1.05
0 0.22
0 0.43
0.96
0 0.17
NO
ND
0 0.12
NO
ND
NO
ND
0 0.85
0 0.85
0 0.07
2.93
D 0.17
0 0.50
0 10.6
ND
0.52
0 0.35
0 0.29
NO
NO
NO
ND
0.49
0.12
P 0.28
ND
NO
NO
ND
ND
D ND
0 2.09
D NO
6.57
0 NO
ND
0.10
D ND
0 NO
ND
0 ND
0 NO
0 ND
D ND
0 NO
NO
ND
0 ND
NO
ND
ND
ND
0 ND
0 ND
D ND
0.39
D NO
0 ND
ND
ND
D 0.10
0 NO
0 NO
ND
NO
NO
ND
D ND
D ND
0 NO
ND
ND
ND
NO
NO
ND
0 ND
NO
ND
ND
ND
0 NO
0.14
0.16
ND
0.37
NO
NO
NO
NO
NO
ND
NO
ND
ND
ND
NO
ND
ND
NO
D ND
NO
ND
NO
ND
D ND
ND
NO
ND
NO
NO
NO
ND
ND
NO
ND
NO
ND
ND
NO
NO
ND
NO
0.99
NO
ND
ND
D 0.14
D NO
ND
0 ND
ND
ND
NO
NO
ND
NO
NO
ND
ND
W
NO
NO
0.92
ND
ND
NO
NO
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
M>
ND
ND
ND
ND
NO
ND
NO
NO
0 1.04
ND
NO
ND
0 0.14
NO
NO
NO
ND
NO
NO
NO
NO
ND
NO
NO
NO
NO
ND
NO
D 0.92
ND
ND
NO
NO
NO
ND
HO
ND
NO
NO
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
D 1.04
ND
ND
ND
D NO
ND
ND
ND
NO
NO
NO
0.73
NO
NO
0.67
HO
NO
ND
NO
NO
D 3.19
HO
NO
NO
NO
NO
NO
NO
ND
NO
NO
ND
NO
ND
NO
ND
ND
NO
NO
NO
ND
ND
ND
NO
ND
D 1.60
NO
NO
ND
0.34
NO
NO
0.33
HO
HO
NO
0 NO
ND
NO
0 NO
NO
ND
ND
ND
NO
1.S6
NO
0.21
NO
0.09
ND
HO
HO
ND
O.H
NO
NO
ND
ND
NO
NO
NO
ND
NO
NO
ND
ND
ND
ND
ND
D 0.57
NO
NO
HO
0 NO
NO
ND
D ND
NO
ND
NO
NO
ND
NO
HO
NO
ND
ND
ND
NO
D »
NO
0 NO
ND
D ND
ND
ND
ND
ND
0 NO
NO
ND
ND
ND
NO
NO
NO
NO
ND
NO
ND
ND
ND
ND
NO
D NO
ND
M>
NO
1.99 0 0.50 D NO 15.3 8.77
1.18 0 NO
NO NO
NO 2.57
NO NO
NO NO
6.39 NO
1.94 0 NO
NO NO
NO NO
0.46 0 NO
NO 8.11
NO NO
NO 1.40 D 3.46
NO 48.9 30.5
NO 4.B8 10.65
NO 8.42 4.33
NO 0.73 0 2.03 0
HO l»2 90.7
0.97 0 U.I 6.70
HO 16.1 9.59
NO NO NO
0.91 0 2.61 1.16 0
NO NO NO
NO NO NO
NO 1.69 0 0.84 D 14.5 5.16
0.48 D 0.76 0 NO 4.12 1.42 D
NO 2.50 NO 24.0 11.3
2.5ft 5.01 1.TO 0 27.0 10.8
0.23 0 0.60 D 1.41 0 19.4 5.49
NO 2.33 0 1.53 0 12.3 8.15
NO NO 0.81 D 7.01 4.20
NO 1.51 D NO 11.4 6.10
NO 1.98 0 0.19 0 0.40 4.M
NO 3.01 1.66 NO NO
NO NO NO 8.16 5.36
NO NO NO NO NO
NO 0.85 0 0.64 0 NO 2.10 0
NO NO NO NO NO
NO 2.09 D NO NO NO
NO NO NO 1.35 0 NO
ND ND NO 10.5 NO
NO 5.84 2.59 NO NO
NO 0.61 D NO 0.46 0 NO
NO NO NO Jtt> NO
1.72 DM NO ON NO
NO NO NO NO NO
NO NO NO NO NO
NO NO NO NO NO
NO NO NO NO NO
NO NO NO 0.69 D NO
ND NO NO NO NO
NO 10.6 NO NO 4.63
2.61 0.85 D NO 27.7 17.2
NO NO 20.8 NO HO
NO 6.13 ND 6.43 1.30 0
NO 1.25 D ND 6.07 NO
0-5-76
-------
XENOB10TICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3342 00016105 F UB Spotted Sucker
3343 D0016107 F WB White Sucker
3344 D0016110 F PF Lm Bass
F UB Carp
F UB Redhorse Sucker
F UB Creek Chubsucker
F PF Lm Bass
F UB Carp
F PF White Perch
F UB Blue Catfish
F UB Carp
F UB Carp
F PF Lm Bass
F UB Carp
3344 00016109
3345 00016111
3346 00016113
3346 00016114
3347 DD016115
3348 00016117
3348 00016118
3349 00016119
3350 DD016121
3350 00016122
3351 00016124
3352 OF023723 F PF Crappie
3352 DF023724 F UB Carp
3352 00022089 I PF Crappie
3353 DF024121
3353 OF024122
3354 OY022301
3354 DY022302
3355 DY022303
3355 DY022304
3356 DE030201
3357 DY022223
3357 OY022224
3360 00029117
3375 DD016305
3375 00016306
3375 00071189
3376 DD016307
3376 00016308
3377 00016309
3377 00016310
3378 00016311
3378 D0029115
3385 00016401
3385 00101888
3395 DD016421
3401 DD016509
3401 00016510
3403 00016513
3403 00016514
3404 00016515 F UB Carp
3404 00016515 F UB Carp
F BF Blue Catfish
F UB Sffl Buffalo
F UB Carp
F PF Lm Bass
F UB Carp
F PF Lm Bass
F UB Carp
F PF Squawfish
F UB Sacramento Sucker
F UB Carp
F UB Carp
F PF Lm Bass
L PF Lm Bass
F UB Carp
F PF Lm Bass
F UB Carp
F PF Lm Bass
F UB Spotted Sucker
F UB Greyfin Sucker
F WB Redhorse Sucker
L UB Redhorse Sucker
F UB Redhorse Sucker
F UB Carp
F PF Lm Bass
F UB River Carpsucker
F PF Lm Bass
Merc
M9/9
0.18
NO
0.26
0.23
0.87
0.03
0.32
0.07
0.25
0.12
0.12
0.08
0.65
0.07
0.17
0.09
0.32
0.14
0.07
0.11
0.03
0.28
0.04
0.95
0.10
0.07
0.08
0.31
0.09
0.34
0.07
0.20
0.07
0.07
0.17
NA
0.24
0.13
0.42
0.10
0.21
0.07
123
TCB
3.92
0.52
0.37
ND
0.26
NO
5.20
0.08
ND
ND
ND
ND
ND
0.17
ND
0.41
ND
NO
NO
ND
ND
ND
ND
NO
1.83
19.4
0.38
0.55
26.8
0.24
4.03
0.54
8.16
4.38
NO
ND
ND
ND
0.07
1.14
0.29
NO
0.97
0
D
D
D
D
D
D
0
D
D
0
D
D
D
D
124
TCB
7.58
ND
0.50
ND
0.16
ND
9.01
ND
NO
ND
ND
ND
ND
ND
ND
0.28
ND
ND
NO
ND
0.34
ND
1.30
ND
1.20
17.0
0.38
0.61
16.1
0.24
2.58
0.40
4.77
2.80
NO
ND
ND
0.51
0.08
1.05
0.17
ND
0.62
0
D
D
D
0
D
D
D
D
D
D
0
D
D
D
135
TCB
NO
ND
ND
ND
ND
ND
0.06
NO
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
2.35
NO
NO
0.04
0.79
ND
ND
ND
ND
0.25
ND
14.9
0.78
ND
NO
1234
TCB
0.88
ND
NO
ND
ND
NO
D NO
NO
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
0 ND
ND
ND
D ND
D ND
ND
ND
ND
ND
D NO
ND
ND
D ND
NO
NO
1235
TCB
D ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
0.18
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
1245
TCB
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
D 0.18
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
OCS
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
NO
ND
D ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
2.30
4.64
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
PCB
ND
NO
ND
ND
ND
ND
ND
ND
0.12
ND
ND
ND
ND
NO
0.25
ND
ND
ND
ND
NO
1.02
ND
D 0.83
ND
ND
ND
NO
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
0.36
ND
ND
ND
ND
ND
PCI
ND
ND
ND
NO
ND
ND
ND
ND
D ND
ND
ND
NO
NO
NO
D ND
ND
ND
NO
NO
ND
D ND
ND
0 NO
ND
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0 ND
NO
ND
ND
ND
ND
HCB
NO
NO
2.08
NO
NO
NO
NO
NO
NO
NO
NO
NO
1.59
NO
0.30
NO
NO
NO
1.38
NO
2.92
NO
NO
11.5
NO
NO
0.90
NO
NO
NO
NO
ND
NO
NO
NO
ND
ND
2.70
0.14
2.31
ND
ND
ND
aBHC
ND
9.58
0 4.01
ND
ND
ND
NO
NO
ND
2.79
ND
ND
0 ND
ND
D 1.13
ND
1.10
2.33
D ND
ND
1.66
ND
6.34
ND
NO
ND
D ND
ND
NO
NO
ND
1.02
3.05
NO
ND
ND
ND
NO
D NO
D ND
ND
ND
ND
gBHC
25.7
4.66
6.75
0.98
3.35
0.16
ND
NO
4.62
NO
NO
NO
NO
ND
0 1.14
NO
0 0.58
D 2.04
8.42
ND
D NO
NO
ND
21.3
2.37
21.9
ND
0.71
18.5
ND
21.9
D 1.56
NO
4.98
1.35
1.11
ND
ND
0.39
3.24
NO
NO
0.50
CIS
CHLOR
ND
ND
ND
D 2.18
ND
0 ND
25.3
ND
ND
ND
NO
1.29
ND
ND
D NO
NO
D 6.14
D NO
ND
ND
57.9
ND
43.8
27.0
D 16.2
145
2.01
D 4.53
IBS
1.57
177
D 2.58
NO
ND
D 13.2
D 10.5
46.5
13.4
D 0.43
64.4
3.86
13.1
0 12.9
TRANS
CHLOR
32.8
2.55
11.9
D 1.42
ND
NO
20.1
ND
ND
7.98
ND
D ND
9.72
ND
2.40
ND
3.37
3.25
6.46
ND
32.0
NO
25.8
16.8
10.9
155
D 6.40
13.26
E 191
D 2.92
159
5.03
ND
ND
8.06
6.17
32.0
8.38
D ND
30.0
1.55
8.75
8.77
D-5-17
-------
XENOB10TICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3409 OB005101
3409 DB040701
3409 DB040706
3411 DB040501
3412 OB040901
3412 DB040907
3414 DC036203
3414 OC036204
3415 DC03620S
3415 DC036206
3419 DC036207
3419 DC036208
3420 DC036209
3420 DC036210
3421 OC036211
F UB Catfish
F UB Carp
F PF Lm Bass
F WB Redhorse Sucker
F PF SIR Bass
F UB Carp
F PF Sm Bass
F BF Channel Catfish
F PF Sm Bass
F BF Channel Catfish
F WB White Sucker
F PF Freshwater Drum
F PF Greenfish
F UB Carp
F PF White Perch
3421 OC036212 F UB Carp
3422 DC036213 F PF Lm Bass
3422 OC036214 F UB Yellow Bullhead
3423 OC036216 F UB White Catfish
3424 DC036218 F UB White Catfish
3425 DF025005 F UB Carp
3426 OB069102 F PF Bluefish
3427 DB069103 F PF Bluefish
3428 08069104 F PF Bluefish
3429 OB069105 F PF Ueakfish
3430 DB069106 F UB White Catfish
3431 DB069109 F WB Red Snapper
3433 DB069112 F UP Flounder
3434 DB040801 F UP Flounder
3434 00011889 L UP Flounder
3435 00016602 F UB Bigmouth Buffalo
3443 DF009118 F UB Carp
3444 DD016603 F WB Carp
3444 D0016604 F BF Channel Catfish
3444 OD029512 F PF Lm Bass
3445 DD029513 F UB Flounder
3446 D0016605 F PF Striped Bass
3446 DD016606 F WB Carpsucker
3446 00091889 F WB Carpsucker
Here
P9/9
0.1
0.06
0.26
0.04
0.22
0.21
0.31
0.09
0.22
0.29
0.02
0.20
0.07
0.03
0.05
0.01
0.73
0.46
0.07
0.03
0.03
0.20
0.28
0.19
0.11
0.08
0.15
0.05
0.04
0.05
0.422
0.05
0.08
0.28
0.04
0.39
0.02
123
TCB
0.35
NO
1.93
NO
NO
5.34
2.19
0.14
1.14
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
0.41
17.7
0.64
0.18
NO
NO
0.47
0.27
0.68
NO
NO
NO
NO
NO
NO
NO
0.11
124
TCB
0 0.62
NO
D 80.4
NO
5.11
3.12
D 1.06
0 NO
D 0.83
NO
NO
NO
NO
NO
NO
0.22
NO
NO
NO
NO
0 1.35
11.9
D 0.72
0 0.15
NO
HO
D 1.42
0 1.00
0 2.31
NO
NO
NO
NO
0.30
0.13
0.22
D 0.19
135
TCB
0 NO
NO
0.95
NO
NO
0.55
D NO
NO
0 NO
NO
ND
NO
NO
ND
ND
0 ND
ND
ND
NO
ND
D NO
1.70
0 ND
D ND
ND
NO
D NO
D ND
0 NO
ND
ND
0.35
ND
0 ND
D ND
D ND
D ND
1234
TCB
ND
NO
0 NO
NO
ND
0 ND
ND
ND
ND
NO
NO
ND
NO
ND
ND
ND
NO
ND
ND
NO
ND
D ND
NO
ND
ND
NO
ND
ND
NO
ND
ND
0 ND
ND
ND
ND
ND
ND
1235
TCB
0.22
ND
ND
NO
ND
ND
NO
ND
ND
NO
NO
ND
NO
NO
NO
ND
ND
NO
ND
ND
NO
ND
ND
NO
ND
NO
ND
ND
NO
NO
ND
NO
ND
ND
NO
NO
ND
1245
TCB
0 0.22
NO
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
OCS
D NO
NO
ND
1.51
29.5
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
NO
NO
ND
NO
ND
ND
ND
ND
NO
ND
ND
4.95
ND
ND
1.09
2.93
3.30
PCB
0.47
NO
NO
D ND
NO
HO
ND
ND
ND
NO
ND
ND
NO
ND
ND
NO
ND
ND
ND
NO
NO
ND
ND
ND
ND
NO
ND
ND
ND
4.90
1.87
1.90
ND
ND
0 NO
ND
NO
PCNB
D ND
ND
ND
NO
ND
ND
HO
ND
ND
NO
NO
ND
NO
NO
ND
ND
NO
NO
ND
NO
0.86
HO
NO
NO
ND
NO
NO
ND
NO
NO
D ND
D ND
ND
ND
ND
NO
ND
HCB
2.53
ND
3.91
0.58
11.5
ND
NO
NO
ND
2.14
NO
NO
NO
ND
NO
ND
ND
NO
ND
ND
0 ND
ND
ND
NO
ND
NO
NO
NO
ND
44.1
7.24
10.7
0.85
ND
1.09
0.94
6.44
aBHC
2.47
NO
ND
D 0.73
ND
NO
3.63
NO
1.43
0 4.65
ND
0.39
ND
ND
3.80
ND
ND
0.85
NO
3.37
1.13
HO
ND
NO
NO
NO
1.15
ND
4.04
ND
ND
ND
D 0.73
NO
D ND
4.97
ND
gBHC
D 8.00
NO
NO
D ND
ND
NO
NO
ND
D NO
ND
NO
D ND
ND
ND
ND
ND
ND
D ND
NO
NO
D 0.37
NO
NO
ND
ND
NO
D 1.11
1.25
2.67
ND
ND
ND
D ND
0.31
ND
1.41
1.35
CIS
CHLOR
37.3
NO
ND
1.72
42.6
NO
6.34
ND
9.54
1.63
ND
ND
ND
ND
ND
ND
NO
6.17
ND
NO
D 2.81
5.18
8.36
ND
3.97
NO
D 11.5
D 13.0
10.6
173
86.8
113
7.66
D ND
5.77
D 10.3
D 11.3
TRANS
CHLOR
22.6
ND
ND
0 NO
17.8
NO
4.56
ND
6.39
0 5.75
1.92
ND
ND
NO
NO
ND
ND
1.89
ND
ND
1.35
1.91
3.61
NO
2.13
ND
4.84
6.72
5.77
206
85.0
E 126
12.9
ND
23.9
20.5
22.1
0
0
D
D
D
E
D-5-I8
-------
Key for Xenobiotic Data Table (Units = ng/g)(continued)
SfiLJ CAS Number
OXYCHLOR = Oxychlordane 26880-48-8
cis NON = cis-Nonachlor 3732-49-4
trans NON = trans-Nonachlor 39765-80-5
HEPT = Heptachlor 76-44-8
HEPT EP = Heptachlor epoxide 1024-57-3
DDE = p,p'- DDE 72-55-9
DffiLDRIN 60-57-1
ENDRIN 72-20-8
DICOFOL = Dicofol (Kelthane) 115-32-2
ME CHL = Methoxychlor 72-43-5
PERTHANE 72-56-0
MIREX 2385-85-5
NITROFEN 1836-75-5
CHLORPYRIFOS 2921-88-2
ISOPROP = Isopropalin 33820-53-0
DATA FLAGS
D= Value below limit of quantitation for all xenobiotics except mercury and PCBs
D = 2.5 ng/g
For polychlorinated biphenyls
Number of Chlorines D. ng/g
1-3 1.25
4-6 2.50
7-8 3.75
9-10 6.25
E = Value exceeds highest calibration standard
See Dioxin/Furan Data Table Key for explanation of other codes. The tables include
environmental samples (those starting with a sample number of D) and the duplicate samples
(those starting with a Q) and confirmation samples (those starting with an S). The number of
samples shown on the summary tables in Volume I does not include the duplicate and
confirmation samples.
D-5-I9
-------
D-5-20
-------
Episode SCC Type Description
XENOBIOTICS CONCENTRATIONS, ng/g
2015 DF001001
2016 DF001101
2017 DF001201
2018 OF001301
2023 DFOOU03
2026 DF001702
2027 DF001803
2037 OY000501
2056 DE000501
2057 DE000601
2059 OE000801
2060 DE000901
2070 DJ000902
2098 DH001501
2100 DH001703
2105 DH002204
2109 DH002601
2110 DH002710
2122 DH003904
2126 DD000302
2133 DD001002
2139 OD001601
2142 DD001902
2148 DD002501
2151 DD002803
2152 D0002903
2190 OG005101
2190 DG005104
2191 OG005205
2194 DG005501
2199 DG006001
2199 OG006004
2201 DG006201
2205 DG006601
2210 DC005401
2211 DC005503
2212 DC005602
2212 DC005605
2215 DC005902
2216 DC006003
2220 DC006405
F UB Carp
F UB Sucker
F WB Carp
F WB Sucker
F UB Carp
F UB Carp
F UB Carp
F. UB not available
F UB Carp
F UB Carp
F UB Carp
F UB Carp
F UB Longnose Sucker
F UB N/A
F UB Catfish
F UB Carp
F UB N/A
F UP Brown Trout
F UB White Sucker
F UB Carp
F BF Blue Catfish
F UB Carp
F UB Catfish
F UB Saltwater Catfish
F UB Spotted Sucker
F UB Lake Chubsucker
F UB Carp
F PF Bluegill
F UB Carp
F UB Carp
F UB Carp
F PF Lm Bass
F UB Carp
F UB Carp
F UB Catfish
F UB Redhorse Sucker
F PF Sm Bass
F UB White Sucker
f UB Carp
UB White Sucker
UB Catfish
OXY
CHLOR
NO
NO
NO
ND
NO
ND
ND
ND
ND
28.5
ND
19.1
ND
ND
ND
ND
12.9
ND
ND
ND
ND
ND
ND
ND
ND
ND
36.0
ND
ND
28.8
ND
9.94
ND
ND
5.62
4.26
4.09
25.3
91.4
ND
ND
CIS
NON
22.6
ND
ND
ND
ND
6.14
ND
ND
30.4
31.2
25.5
27.7
ND
ND
8.56
ND
ND
ND
ND
ND
ND
ND
20.5
ND
ND
ND
14.6
ND
17.8
23.3
9.67
12.6
ND
ND
52.0
5.57
6.57
42.5
124
ND
ND
TRANS HEPT
NON
61.7
18.1
2.49
8.66
4.96
16.1
3.85
3.18
82.9
89.1
74.6
77.4
ND
ND
25.2
ND
17.6
ND
3.31
9.23
6.17
ND
36.8
11.1
ND
ND
39.7
ND
56.2
73.6
26.3
36.4
2.38
ND
158
15.6
22.9
142
477
NO
7.07
ND
ND
D NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
NO
ND
ND
3.79
ND
NO
D NO
NO
ND
ND
ND
E ND
E 19.6
ND
ND
HEPT
EP
6.34
ND
ND
ND
ND
NO
NO
NO
ND
15.0
16.0
23.2
ND
ND
ND
ND
24.4
ND
ND
3.77
ND
HO
ND
NO
ND
ND
63.2
ND
ND
32.7
19.1
7.91
ND
ND
15.7
ND
1.07
ND
21.9
ND
ND
ODE
471
1223
66.7
ND
30.5
252
64.4
0.51
38.7
64.6
769
46.5
2.89
5.04
187
2.57
62.8
5.61
18.9
474
659
4.95
75.1
34.4
8.97
10.4
56.2
4.61
52.3
41.8
70.0
48.8
19.2
22.3
381
88.8
52.1
186
122
2.04
19.6
DIELDRIN ENDRIN DICOFOL HE PER
E
E
E
0
E
E
E
E
E
E
E
E
E
D
73.7
ND
ND
ND
1.70
ND
ND
ND
58.5
110
81.2
153
ND
ND
18.1
ND
108
ND
7.64
18.2
15.4
NO
21.9
7.36
NO
ND
224
14.7
258
60.8
312
70.4
8.79
7.94
73.1
8.45
4.92
112
128
ND
ND
ND
ND
ND
ND
D 3.73
ND
ND
ND
ND
NO
NO
ND
ND
ND
NO
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
E NO
ND
7.50
NO
E ND
E ND
ND
ND
9.02
ND
ND
E 2.25
ND
ND
ND
ND
0.61
ND
ND
ND
0.26
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
0.79
ND
ND
5.37
ND
4.09
ND
ND
4.56
2.32
1.23
0.66
ND
ND
ND
ND
ND
D 0.64
6.02
ND
ND
CHL
ND
D ND
ND
ND
ND
D ND
ND
ND
8.22
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.81
D ND
NO
ND
ND
ND
ND
ND
ND
ND
D 1.04
D ND
D ND
ND
ND
4.82
ND
NO
D ND
ND
ND
NO
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
MIREX
ND
4.24
21.6
ND
NO
ND
ND
NO
2.07
ND
6.22
0.76
ND
ND
1.30
ND
ND
ND
ND
23.1
3.62
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.24
2.31
ND
ND
NO
ND
ND
NITROFEN
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
ND
ND
NO
ND
ND
CHLOR
PYRIFOS
ND
NO
NO
NO
NO
NO
ND
ND
11.4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.21
1.82 0
ND
ND
ND
5.61
ND
10.4
ND
NO
19.4
ND
ND
ND
ND
23.9
ND
ND
7.66
26.3
ND
ND
ISOPI
ND
ND
NO
ND
ND
8.65
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D-S-21
-------
Episode SCC Type Description
XENOB10TICS CONCENTRATIONS, ng/g
•
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
2439 DE01K01 F WB Carp
2439 DE01U02 F WP Sm Bass
2478 DJ003902 F UB Sucker
2500 DC010203 F UB Black Buffalo
2532 DF019303 F UB Carp
2544 OF019202 F UB Blacktail Redhorse
2608 DE014504 F UB Carp
2618 DE015401 F UB Carp
2618 DE015402 F BF Carp
2618 OE015403 F UB Quill back
2651 DB008401 F UB White Sucker
2653 DB008503 F UB Carp
2654 DB008601 F UB Carp
2709 DB005101 F UB Catfish
2721 DA006502 F UB Sucker
2721 00011089 1 UB Sucker
2722 DA006601 F UB Sucker
2725 DA006301 F UB Sucker
2748 DY006505 F UB Sucker
2776 DY007101 F UB Carp
2776 00010489 L UB Carp
3001 DE019502 F WB White Sucker
3022 OA008401 F UB White Sucker
3023 DA008501 F PF Sm Bass
3024 DA008601 F PF Lm Bass
3025 DA008701 F UB White Sucker
3028 DA008801 F PF Chain Pickerel
3034 DG025701 F UB Carp
3035 DG025801 F UB Carp
3036 DG025902 F UB Carp
3037 DG026001 F UB Carp
3038 DG026101 F UB Carp
3039 DG026201 F UB Carp
3040 DG026301 F UB Carp
3041 DG026402 F UB Carp
3042 DG026501 F UB Carp
3042 DG026502 F PF Northern Pike
3042 00026501 L UB Carp
3043 DG026601 F UB Carp
3044 DG026701 F UB Carp
3045 DG026801 F UB Carp
3045 DG026802 F PF Flathead Catfish
3046 DG026901 F UB Bigmouth Buffalo
3047 DG027001 F UB Carp
3048 OG027101 F UB Carp
OXY
CHLOR
77.0
37.7
NO
NO
NO
ND
NO
96.2
24.3
68.9
1.45
16.4
9.34
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
13.5
ND
3.91
ND
28.0
1.17
ND
4.08
NO
ND
NO
8.44
42.3
2.53
6.95
ND
19.6
CIS
NON
54.8
48.3
ND
ND
12.5
ND
ND
57.7
19.3
51.2
0 7.04
38.4
ND
20.8
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
5.29
12.3
9.88
6.69
ND
44.1
D 8.37
ND
ND
ND
18.8
11.3
20.4
59.6
7.31
8.02
ND
64.6
TRANS
NON
147
173
4.53
7.15
30.7
15.3
ND
197
66.1
164
17.2
138
65.61
57.2
ND
ND
ND
ND
ND
3.14
5.42
NO
ND
ND
NO
11.1
ND
ND
47.9
ND
20.1
ND
133
E 23.4
2.07
84.6
2.33
50.7
NO
ND
186
22.3
20.7
ND
225
HEPT
ND
E ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
E ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
E ND
ND
ND
ND
ND
ND
NO
E ND
E ND
D ND
8.84
D ND
ND
ND
4.43
E 9.74
2.09
ND
ND
E 3.63
HEPT
EP
20.8
16.8
NO
ND
12.4
ND
ND
28.6
8.16
ND
ND
6.57
8.07
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
6.64
22.4
ND
19.9
ND
14.5
ND
1.03
NO
ND
ND
ND
10.9
24.1
D 2.26
10.6
NO
17.6
DDE
109
80.9
197
6.98
73.8
25.3
64.4
77.6
23.2
65.2
89.0
177
59.92
223
20.6
13.8
3.01
10.6
31.1
58.7
101
27.6
14.0
2.18
118
18.6
ND
39.2
258
72.0
103
70.3
185
555
374
165
12.0
108
85.8
133
166
23.4
36.4
ND
67.1
DIELDR1N ENDRIN DICOFOL ME PER
99.8
103
E ND
3.99
99.5
38.2
35.0
128
47.3
88.5
E 6.90
E 23.8
19.25
E 14.9
ND
ND
ND
ND
ND
E ND
E ND
ND
ND
D ND
E 46.0
E 3.68
ND
35.5
E 160
323
E 136
ND
E 36.0
E 24.6
E 74.3
E 61.3
1.58
55.8
79.3
E 116
E 107
18.5
216
ND
190
ND
E ND
ND
ND
7.45
NO
ND
35.1
12.9
6.30
ND
ND
ND
ND
8.55
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E 4.52
NO
ND
E ND
E ND
E ND
ND
NO
E ND
E 4.97
ND
D ND
ND
ND
E ND
E 7.37
NO
E ND
ND
E 18.5
ND
ND
ND
NO
NO
ND
ND
ND
NO
ND
2.17
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
ND
ND
ND
ND
ND
ND
3.57
ND
ND
ND
ND
ND
ND
ND
ND
ND
N
ND
ND
CHI
ND
NO
NO
ND
ND
NO
NO
ND
ND
ND
D ND
ND
1.51
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
2.50
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
D ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
PERTHANE MI REX
NITROFEN CHLOR ISOPROP
PYRIFOS
ND
ND
ND
1.73
1.16
2.63
ND
ND
ND
ND
0.97
5.90
ND
2.21
4.77
ND
ND
ND
ND
0.36
ND
ND
ND
ND
ND
ND
ND
ND
1.03
NO
ND
ND
ND
0.39
ND
ND
ND
ND
ND
ND
0.70
ND
ND
NO
ND
ND
ND
ND
D ND
D ND
ND
ND
ND
ND
ND
D ND
ND
10.40
D ND
ND
ND
ND
ND
ND
D ND
ND
ND
NO
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
D NO
ND
ND
NO
ND
ND
ND
D ND
ND
ND
ND
ND
NO
17.3
ND
1.50
ND
NO
ND
17.8
5.55
ND
2.91
4.59
ND
3.62
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.46
4.53
5.13
ND
12.4
0.81
ND
30.1
1.62
40.8
5.44
9.04
17.8
6.12
NO
ND
12.1
ND
ND
NO
0 ND
ND
ND
ND
NO
ND
ND
ND
ND
2.11
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
D ND
15.0
ND
ND
ND
D 2.82
ND
13.4
D ND
25.9
37.5
10.5
6.53
ND
ND
16.5
5.92
D-5-23
-------
Episode SCC Type Description
XENOeiOTlCS CONCENTRATIONS, ng/g
HEPT DDE DIELDRIN ENDRIN DICOFOL ME
EP CHL
PERTHANE MIREX
N1TROFEN CHLOR
PYRIFOS
ISOPROP
3048 DG027102
3048 00012689
3048 00027101
3049 DG027201
3050 DG027301
3060 OF009101
3060 DF009102
3060 00073189
3061 DF019106
3062 OF024024
3063 DF023301
3063 DF023302
3064 DF023305
3065 DF023419
3065 OF023420
3065 00010788
3066 DF023503
3066 DF023504
3068 OF024001
3068 DF024002
3069 DF024007
3069 DF024008
3069 00051788
3070 OF024009
3070 DF024010
3071 OF024014
3071 DF024015
3072 DF024017
3072 00070688
3073 DF019221
3074 OF026017
3076 DF028502
3077 OF019114
3078 DF009118
3078 DF023815
3078 DF023816
3079 DF019205
3079 DF019206
3080 DF023317
3080 OF023318
3081 DF02410S
3081 DF024106
3082 DF023401
3083 OF023406
3084 DF024109
F PF
L PF
L UB
F UB
F UB
F UB
F UB
L UB
F UB
F UB
F UB
F PF
N
F BF
F UB
F BF
F UB
F PF
*
F PF
F UB
F PF
F UB
F UB
F PF
F UB
F PF
F UB
L UB
F UB
PF
UB
UB
UB
UB
PF
PF
UB
UB
PF
PF
UB
UB
PF
UB
White Bass
White Bass
Carp
Carp
Bigmouth Buffalo
Flathead Catfish
Sm Buffalo
Flathead Catfish
Sucker
Blue Catfish
Sea Catfish
Spotted Sea trout
Shellfish
Bigmouth Buffalo
Flathead Catfish
Bigmouth Buffalo
Catfish
Freshwater Drum
Oysters
At I. Croaker
Sea Catfish
Trout
Sea Catfish
Croaker
Sheepshead
Carp
Longnose Gar
Carp
Carp
White Sucker
Brown Trout
Channel Catfish
Redhorse Sucker
Carp
Sm Buffalo
Black Crappie
White Bass
Carp
Carp
Lm Bass
White Bass
Catfish
Carp
Lm Bass
Channel Catfish
2.27
1.94
18.6
10.1
6.75
ND
NO
ND
2.23
ND
2.79
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
61.5
ND
ND
ND
ND
ND
ND
ND
1.85
ND
ND
NO
2.27
ND
ND
ND
ND
ND
6.59
D 5.42
D 4.98
38.1
37.6
8.92
ND
ND
ND
D ND
ND
8.66
3.60
ND
ND
4.97
ND
7.74
ND
NO
5.18
5.56
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 11.3
ND
ND
7.44
D 13.2
ND
ND
ND
ND
ND
34.6
12.9
11.8
97.5
ND
23.9
ND
21.47
ND
ND
20.3
20.1
7.55
3.77
4.24
10.6
7.28
16.3
ND
ND
10.4
9.98
NO
15.8
4.44
ND
104.14
172. 05E
6.55
4.47
NO
ND
7.10
ND
6.72
45.9
2.89
24.86
18.3
31.9
ND
2.54
ND
7.87
ND
70.4
NO
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
4.15
3.88
17.0
16.6
9.34
ND
ND
ND
2.26
ND
NO
ND
ND
NO
ND
ND
9.10
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
3.21
ND
2.87
3.40
4.29
ND
ND
ND
NO
ND
ND
13.1 26.2
11.6 25.3
32.0 92.8
206 E 201
30.6 125
21.99 NO
447. 57E ND
14.87 ND
5.93 4.18
271 E 8.33
41.5 12.4
8.54 5.91
3.17 ND
18.8 3.61
29.1 6.44
31.3 4.95
39.6 61.5
9.49 8.28
16.8 ND
12.2 13.4
51.2 5.38
3.33 NO
69.7 5.71
6.80 ND
0.56 D ND
154. 75E 53.11
302. 29E 89.36
545 E ND
416 E ND
7.79 2.20
43.0 ND
55.1 ND
6.39 ND
2425 E ND
152 E 30.6
51.1 E 4.78
23.21 9.96
32.4 8.44
298 E ND
10.66 ND
10.3 0.62
4.40 ND
2199 E ND
93.2 ND
3221 E 66.4
ND
ND
NO
E ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
2.52
ND
NO
ND
ND
ND
0.64
ND
ND
ND
NO
ND
ND
D ND
ND
ND
ND
ND
NO
ND
ND
2.51
ND
ND
D NO
ND
ND
ND
18.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
0.70
ND
ND
NO
0.76
4.05
0.30
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
2.10
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.81
0 ND
ND
ND
ND
0 ND
ND
D ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
D ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
NO
1.17
ND
2.03
0.88
ND
0.33
0.51
0.42
ND
ND
ND
ND
0.35
ND
ND
NO
ND
ND
4.19
ND
ND
ND
0.94
ND
ND
ND
ND
ND
ND
ND
42.4
ND
0.34
0.71
10.4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
D ND
D ND
ND
D ND
D ND
D NO
ND
NO
ND
ND
0 NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
D ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
D ND
0 ND
ND
ND
ND
ND
ND
12.3
4.37
NO
ND
ND
NO
ND
ND
ND
ND
NO
ND
0.81
NO
3.11
ND
ND
ND
NO
ND
ND
ND
ND
63.68
11.78
1.83
2.10
ND
ND
ND
ND
NO
5.68
0.82
3.57
1.61
17.5
ND
ND
ND
ND
ND
20.6
ND
ND
ND
13.9
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
9.09
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
D ND
D ND
ND
ND
ND
ND
NO
ND
D ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
D-5-24
-------
Episode SCC Type Description
XENOBIOTICS CONCENTRATIONS, ng/g
HEPT DOE OIELDR1N ENDRIN DICOFOL ME
EP CHL
PERTHANE HIREX
NITROFEN CHLOR
PTR1FOS
ISOPROP
3085 DF024113
3085 DF0241U
3086 DF023409
3086 DF023410
3087 DF023413
3087 DF023414
3087 DF023415
3088 DF023417
3088 DF023418
3089 DF019209
3089 DF019210
3090 DF019213
3090 OF0192H
3091 DF019217
3092 DF023501
3092 DF023502
3093 DF024011
3093 DF024118
3094 DC017201
3095 DC038801
3095 OC038802
3096 DC035001
3096 DC03S002
3097 OC038701
3097 OC038702
3097 00071989
3098 DC038601
3098 DC038602
3098 00051288
3100 DC019701
3101 DC019901
3103 DC036201
3103 DC036202
3104 DC020001
3104 OC020002
3105 OF025001
3105 OF025002
3106 DE026801
3107 DE026901
3108 DE027001
3108 DE027002
3109 DE025001
3110 DE022501
3111 DH015802
3112 DE022401
UB Sea Catfish
PF Black Dru»
UB Catfish
PF Red Orui
UB Carp
PF White Crappie
UP Bluegill
UB Channel Catfish
PF Bluegill
PF White Crappie
UB Carp
PF White Crappie
UB Channel Catfish
UB River Carpsucker
UB Carp
PF Uanaouth
PF Lm Bass
UB S* Buffalo
BF Channel Catfish
BF Brown Bullhead
UB Channel Catfish
BF Broun Bullhead
UB Channel Catfish
BF Brown Bullhead
UB Carp
BF Brown Bullhead
UB White Sucker
PF American Eel
UB White Sucker
PF White Perch
PF Brown Trout
UB Channel Catfish
UB Carp
PF Lm Bass
UB Carp
UB Carp
PF Lai Bass
PF Walleye
UB Carp
PF Walleye
UB Carp
UB Carp
BF Carp
UB Silver Redhorse
UB Carp
NO
NO
3.53
NO
NO
NO
NO
NO
NO
NO
NO
NO
3.48
NO
NO
NO
NO
NO
NO
NO
11.7
NO
21.5
NO
NO
NO
NO
7.29
NO
NO
5.53
NO
NO
NO
7.98
NO
NO
NO
HO
NO
NO
NO
NO
NO
NO
NO
NO
18.8
NO
NO
NO
NO
NO
NO
NO
1.58
NO
13.8
NO
NO
NO
NO
NO
34.5
8.64
40.6
NO
65.6
NO
NO
NO
NO
0.19
NO
NO
NO
NO
NO
NO
16.0
NO
HO
NO
NO
NO
NO
NO
ND
NO
NO
ND
NO
53.8
NO
NO
NO
2.29 0
NO
HO
ND
D 3.17
1.12 0
28.9
0.98 0
NO
ND
NO
1.29 0
106
30.8
126
3.70
162 E
5.42
7.65
5.45
NO
19.0
NO
11.88
12.9
40.69
NO
7.66
50.7
8.32 E
NO
ND
2.08
ND
2.40 0
10.2
4.36
10.8
3.47
NO
NO
NO
NO
ND
NO
NO
NO
HO
ND
NO
NO
NO
HO
ND
NO
NO
NO
NO
ND
NO
HO
NO
HO
NO
NO
NO
NO
ND
ND
NO
HO
NO
HO
HO
ND
HO
NO
NO
NO
NO
ND
ND
ND
ND
NO
ND
ND
NO
ND
HO
NO
NO
NO
ND
0.80
HO
2.87
HO
ND
HO
HO
HO
ND
ND
NO
NO
HO
NO
ND
NO
HO
2.10
HO
ND
1.18
NO
ND
ND
NO
ND
NO
NO
NO
HO
NO
ND
NO
ND
ND
86.8 NO
14.97 NO
48.6 25.1
ND NO
38.4 ND
8.92 ND
35.8 NO
6.89 ND
2.09 0 NO
2.46 0 HO
20.8 3.97
1.48 0 NO
52.7 9.89
33.1 0.51
40.93 8.34
0.81 D NO
0.76 D NO
5.51 NO
984 E 83.5
322 20.3
2329 E 64.9
34.38 6.89
1189 E NO
77.72 NO
114 HO
70.09 ND
224 E ND
D 551 E 11.7
284 E NO
18.81 7.47
D 18.8 13.1
164.92 7.69
152 ND
15.61 6.37
81.6 E 29.4
1448 E HO
75.9 E NO
5.57 NO
22.99 1.73
2.06 D NO
22.81 NO
136 E NO
91.5 E 7.73
60.6 8.60
53.5 5.15
ND
HO
1.65 0
HO
4.0
NO
HO
NO
NO
ND
NO
HO
NO
D HO
12.25
NO
ND
HO
HO
NO
ND
HO
HO
NO
5.63
ND
NO
NO
NO
ND
ND
NO
NO
NO
4.45
HD
HO
ND
D NO
ND
HD
NO
NO
ND
ND
ND
ND
ND
NO
HO
NO
ND
NO
NO
NO
ND
ND
ND
HO
HO
NO
NO
HD
10.4
HO
3.69
NO
NO
HD
NO
NO
NO
NO
HO
HD
NO
1.13
HD
ND
4.66
ND
NO
NO
HO
NO
ND
ND
ND
ND
2.44
NO
ND
HD
ND
NO
NO
ND
NO
NO
ND
ND
ND
NO
NO
NO
ND
NO
NO
NO
NO
ND
NO
NO
NO
ND
NO
NO
3.40
ND
ND
5.21
D HO
ND
ND
NO
ND
ND
NO
ND
NO
NO
ND
ND
NO
D ND
NO
ND
NO
NO
ND
ND
ND
ND
NO
ND
NO
ND
ND
NO
ND
HO
HD
ND
5.12
ND
ND
HD
ND
ND
ND
ND
ND
HO
ND
HO
ND
NO
NO
NO
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
1.93
ND
ND
2.45
NO
0.99
NO
0.68
3.68
NO
ND
0.52
ND
0.57
NO
0.71
NO
ND
0.29
NO
ND
ND
3.01
1.88
0.21
ND
NO
ND
NO
NO
NO
ND
ND
ND
0.63
ND
NO
ND
NO
ND
ND
ND
5.95
ND
0.47
D 2.98
ND
ND
D ND
ND
D ND
ND
D NO
ND
HO
ND
D NO
ND
D ND
ND
D ND
ND
ND
D ND
NO
NO
ND
ND
D ND
D NO
NO
ND
ND
NO
ND
ND
ND
ND
ND
D NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
NO
NO
NO
NO
ND
NO
NO
NO
ND
1.82
NO
ND
ND
ND
NO
19.8
8.95
19.4
2.50
23.0
NO
NO
ND
ND
2.09
HO
NO
ND
1.96
ND
ND
14.0
HO
ND
ND
HD
ND
HO
ND
ND
2.19
ND
ND
NO
HD
ND
NO
NO
ND
ND
ND
ND
NO
HO
D HO
HD
HO
HD
HD
HO
HO
HO
NO
HO
HD
ND
ND
NO
ND
D ND
NO
ND
NO
D ND
ND
ND
ND
NO
ND
ND
ND
ND
HD
ND
ND
D NO
HO
D-S-2S
-------
episode SCC Type Description
XENOBIOTICS CONCENTRATIONS, ng/g
3112 DE022402
3113 DE021101
3113 DE021102
3113 QD030789
3114 DE021201
3115 OE021302
3115 00101689
3115 DE021301
3117 W-021501
3118 DE021601
3118 DE021602
3118 DE021603
3118 QD010689
3118 QD020488
3120 DE021801
3120 DE021802
3122 DE022001
3122 DE022003
3125 DE022301
3125 OE022302
3132 DE023201
3132 00010588
3134 DE023403
3134 DE023405
3134 DE023406
3135 DE023501
3136 DE023601
3137 DE023701
3138 DE023801
3140 DE024001
3140 DE024002
3141 DE024101
3141 DE024102
3141 DE024103
3142 DE022502
3143 DE024401
3143 DE024403
3144 DE024901
3145 DE026601
3146 DE026701
3146 DE026702
3147 DC035201
3148 DE027101
3148 DE027103
3149 DC038501
F PF Walleye
F BF Channel Catfish
F BF Carp
F BF Channel Catfish
F BF Carp
F BF Catfish
L UB Carp
F UB Carp
F PF Lake Trout
F PF Walleye
F UB Carp
F UB Carp
L WB Carp
L PF Walleye
F UB Carp
F PF Bass
F UB Carp
F UB Redhorse Sucker
F UB Carp
F PF White Bass
F UB Carp
L UB Carp
F UB Carp
F UB Carp
F UB Sucker
F WB Carp
F PF Northern Pike
F UB Redhorse Sucker
F WB Carp
F PF Walleye
F UB Carp
F PF Northern Pike
F UB Carp
PF Northern Pike
UB Carp
Rotten (catf)
WB Carp
UB Carp
WB N. Redhorse
UB Carp
PF Walleye
UB Carp
UB Carp
PF Walleye
UB White Sucker
OXY
CHLOR
NO
4.83
9.75
5.24
11.9
9.74
ND
5.6
87.2
3.90
ND
ND
ND
5.00
ND
6.65
ND
ND
ND
ND
24.82
25.93
ND
14.5
ND
ND
ND
ND
ND
ND
ND
24.0
ND
13.8
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.86
3.56
CIS
WON
ND
5.73
25.3
5.95
23.7
ND
ND
ND
127
9.25
14.6
3.51
16.2
10.4
ND
ND
10.5
ND
ND
ND
37.37
48.02
ND
3.88
ND
ND
ND
ND
4.02
ND
ND
18.6
21.8
9.40
25.8
ND
ND
ND
ND
ND
ND
ND
17.1
7.70
ND
TRANS
NON
ND
13.9
78.0
15.0
60.1
47.7
47.4
48.1
350 E
22.3
36.6
9.62
40.1
28.7
7.22
5.30
28.7
1.73 D
ND
2.66
106.17
133.24
3.14
12.1
ND
7.41
ND
ND
11.6
1.82 D
5.11
57.3 E
63.2
27.9
81.5
ND
7.64
9.34
3.80
15.1
ND
32.3
58.0
15.7
26.5
HEPT
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HEPT
EP
ND
NO
ND
ND
25.8
10.2
9.95
NO
40.7
0.84
NO
NO
ND
0.97
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
29.5
ND
ND
1.86
ND
ND
ND
ND
NO
0.67
ND
DDE DIELDRIN
4.69 ND
130 E 11.1
1003 E ND
133 E 10.3
46.6 187 E
104 E 55.3
73.3 52.1
76.6 50.8
1891 E 405 E
145 12.2
814 E 17.7
181 ND
895 E 19.5
180 16.0
48.71 11.09
35.60 4.36
450 E ND
10.70 ND
136 54.0
30.6 5.17
50.71 83.39
63.70 69.62
22.2 2.80
74.4 E ND
33.8 ND
59.1 8.62
0.94 D ND
6.86 D ND
85.6 4.15
14.8 ND
42.5 ND
291 E 50.0
564 E 63.8
137 E 29.9
658 E 228
29.5 ND
34.49 4.04
137 23.9
17.5 4.22
100 16.5
1.78 D ND
79.2 15.8
282 E 4.51
85.7 9.37
289 15.6
ENDRIN
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
3.60
3.07
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
DICOFOL
ND
NO
ND
ND
ND
ND
ND
ND
14.9
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
1.51 0
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
HE
CHL
ND
ND
ND
HO
ND
NO
ND
ND
ND
ND
ND
0.64
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
1.72
ND
ND
ND
7.71
ND
NO
ND
ND
ND
ND
ND
PERTHANE
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
D ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
MI REX
ND
ND
1.71
NO
NO
34.3
ND
ND
7.06
0.32
1.88
0.64
2.24
0.27
ND
ND
3.32
NO
ND
0.70
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.16
2.90
0.34
ND
ND
ND
ND
0.48
1.52
ND
ND
ND
0.29
ND
NITROFEN
ND
ND
D NO
ND
ND
ND
ND
ND
ND
D ND
D ND
0 ND
0 ND
D ND
ND
ND
NO
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
D ND
ND
0 NO
NO
ND
ND
ND
D ND
0 NO
NO
NO
ND
D ND
ND
CHLOR
PYRIFOS
ND
6.92
7.23
7.40
ND
12.8
7.22
7.44
ND
NO
NO
ND
ND
ND
ND
NO
NO
ND
ND
0.61 D
ND
ND
HO
ND
ND
0.80 D
HD
ND
ND
ND
ND
62.7 E
ND
5.23
ND
ND
ND
ND
ND
NO
ND
7.90
ND
ND
3.99
I SI
HD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
HD
ND
ND
ND
ND
ND
NO
NO
NO
ND
NO
ND
ND
ND
D-5-26
-------
Episode SCC Type Description
XENOBIOTICS CONCENTRATIONS, ng/g
HEPT DDE DIELDRIN ENDRIN DICOFOL HE
EP CHL
PERTHANE M1REX
NITROFEN CNLOR ISOPROP
PYRIFOS
3150 DA008901 F UB White Sucker
3150 00120187 L UB White Sucker
3151 DA009101 F UB White Sucker
3152 DA009201 F UB White Sucker
3161 OC019801 F BF Black Bullhead
3161 DC019802 F WB White Sucker
3162 DJ024001 F WP Starry Flounder
3163 DJ024002 F UP Starry Flounder
3164 DD015702 F UB Carp
F UB Redhorse Sucker
F UB White Sucker
3165 DD015704
3166 00015706
3167 DD015708 F WP Bluegitl
3167 00062388 L WP Bluegill
3168 00015711
3168 D0015712
F UB Carp
F PF Lra Bass
3169 DD015713 F UB Black Redhorse
3169 00022789 L UB Black Redhorse
3170 D0015715 F UB Spotted Sucker
3171 DD015717 F UB Spotted Sucker
3172 D0015719 F WB Carp
3172 00015720 F PF Lm Bass
WB Channel Catfish
F WB Channel Catfish
F UB Channel Catfish
F UB Spotted Sucker
F WB Carp
3177 00100488 L UB Carp
3178 DD015807 F UB North Hogsucker
F UB Golden Redhorse
F PF Lm Bass
F UB Carp
F PF Rock Bass
F UB Carp
F UB Carp
F PF Sauger
F PF White Crappie
F WB Channel Catfish
F UP Southern Flounder
F UP Summer Flounder
F WB Carp
F PF Lm Bass
F UB Carp
L UB Carp
F UB Carp
F WP Starry Flounder
3173 D0015722 F
3174 DD015724
3175 00015801
3176 00015803
3177 D0015805
3179 00015809
3180 00015812
3181 DD015814
3182 00015815
3182 00015816
3183 00015817
3183 DD015818
3184 DD015820
3185 00015821
3186 00015824
3187 00015902
3188 00015903
3188 DD015904
3189 00015905
3189 00092188
3190 00015907
3191 DJ024003
8.64
9.45
NO
ND
6.33
29.8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
2.37
ND
5.35
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.51
ND
2.60
NO
ND
ND
NO
ND
ND
47.2
ND
ND
29.1
16.4
ND
ND
NO
ND
ND
ND
NO
ND
ND
HO
ND
9.12
NO
ND
ND
ND
ND
ND
D 3.82
ND
57.0
ND
24.9
27.7
ND
ND
19.2
NO
ND
35.5
NO
14.0
18.3
11.1
ND
7.32
7.63
7.93
ND
23.72
161
4.39
1.57
104
52.3
NO
1.75
2.64
2.80
NO
6.93
5.71
3.51
3.53
9.08
ND
13.4
3.15
8.60
3.54
7.82
7.10
1.95
15.4
ND
242
1.38
94.2
94.9
2.39
ND
60.7
1.01
ND
130
1.83
42.6
55.5
29.1
ND
ND
ND
ND
ND
ND
NO
ND
D ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
D ND
NO
ND
E ND
0 ND
E ND
76.2
0 ND
ND
ND
D ND
ND
E ND
D ND
ND
ND
ND
ND
ND
NO
NO
ND
8.60
36.8
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
3.55
ND
NO
E ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
1.83
NO
19.1
18.4
26.2
5.83
26.38
114
21.0
4.84
111
35.5
79.9
15.2
21.9
590
65.4
384
335
104
48.6
638
32.1
55.0
78.5
55.9
82.2
33.0
30.8
9.37
38.6
13.1
121
3.16
87.7
38.8
2.00
27.3
41.9
4.70
3.75
162
2.85
148
203
31.6
0.89
3.36
3.43
2.36
1.75 D
63.26
450
NO
0.28 D
32.2
4.76
ND
ND
ND
E ND
E ND
E ND
E NO
E NO
ND
E ND
ND
ND
2.07 D
E 3.74
E ND
1.95 D
1.89 0
ND
6.99
ND
E 57.3
ND
E 46.1
13.5
D ND
ND
17.6
ND
ND
E 100
ND
E 29.6
E 47.6
8.39
D NO
ND
ND
ND
1.63
ND
NO
ND
ND
ND
4.73
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
6.53
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.92
D NO
ND
8.16
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.73
0.89
ND
ND
ND
ND
ND
0.50
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
0 NO
ND
2.66
ND
ND
NO
ND
NO
NO
ND
NO
NO
ND
D ND
D ND
ND
ND
8.15
ND
ND
D ND
NO
NO
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
0.27
ND
ND
ND
NO
ND
NO
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
NO
NO
ND
NO
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
D ND
ND
0.69
ND
ND
NO
ND
0.50
ND
ND
ND
ND
ND
ND
4.96
ND
11.3
10.8
0.21
0.28
3.26
0.36
ND
ND
73.2
1.47
0.30
ND
ND
ND
1.39
5.89
ND
ND
1.89
ND
ND
6.88
ND
ND
3.68
ND
ND
ND
ND
ND
ND
D ND
ND
HO
ND
ND
D ND
ND
ND
ND
ND
ND
NO
2.04
ND
ND
ND
D ND
D ND
ND
D ND
ND
ND
E ND
D ND
D ND
ND
ND
NO
D ND
NO
0.65
ND
D ND
ND
NO
ND
ND
NO
ND
ND
ND
NO
ND
ND
6.09
4.22
ND
ND
4.35
13.6
ND
NO
NO
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
NO
ND
ND
1.90
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
1.39
ND
ND
19.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
10.2
D ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
D ND
ND
ND
ND
ND
ND
NO
ND
NO
2.32
ND
ND
D-5-27
-------
Episode SCC Type Description
XEN06IOTICS CONCENTRATIONS, ng/g
KEPT DOE OIELDR1N ENORIN DICOFOL ME
EP CHL
PERTHANE H1REX
NITROFEN CHLOR
PYRIFOS
ISOPROP
3191 DJ024005 H Soft Shell Clans
3192 DJ024007 F UP Starry Flounder
3192 DJ024009 M Soft Shell Clams
3193 OC039001
3195 DH020104
3195 DH020105
3196 DH020108
3198 DH020111
3199 OH020101
3199 DH020103
3200 OH020112
3203 DJ024018
320S DJ024024
3206 DJ024103
3208 DJ024109
3212 OJ024120
3212 DJ024121
3213 DJ024123
3215 DJ023705
3216 OJ023707
3216 OJ023708
3216 00022388
3217 DJ023710
3218 DJ023711
3219 DJ023713
3219 DJ023714
3220 OJ023903
3221 DJ023905
3222 DJ023907
PF Striped Bass
WB Carp
WB Chub
WB Sucker
WB Sucker
WB Carp
WB Carp
WB Sucker
WB Carp
Crayfish (whole)
WB Sucker
WB Sucker
BF Catfish
WB Carp
WB Squawfish
WB Sucker
PF Squawfish
WB Sucker
WB Sucker
WB Sucker
PF Squawfish
WB White Sturgeon
PF White Sturgeon
WB Bridgelip Sucker
WB Sucker
WB Sucker
3223 DJ023717 F WP Starry Flounder
3224 DJ023715 M Soft Shell Clams
3226 DJ023721 K Pacific Oysters
3227 DJ023723 H Pacific Oysters
3231 DJ023910 F PF Sm Bass
3231 DJ023911 F WB Carp
3234 DH020301 F UP Squaufish
3235 OH020303 F WB White Sucker
3236 DH020305 F WB Largescale Sucker
3237 OH020308 F WB Largescale Sucker
3237 00080988 F WB Largescale Sucker
3238 DJ023918 F WP Dol ly Varden
3241 DJ023924 F WP Dol ly Varden
3245 DJ023624 F WP Flathead Sole
3246 DJ022109 F WP Flathead Sole
3248 DJ022502 F WB Composite Bottom
ND
ND
NO
ND
ND
ND
ND
2.93
ND
3.75
ND
ND
ND
ND
5.56
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
15.4
5.16
10.6
ND
4.36
6.26
6.77
NO
5.41
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
NO
ND
ND
ND
ND
NO
ND
31.8
16.4
33.4
1.38
14.7
21.3
20.2
10.9
14.4
ND
ND
13.4
4.54
24.7
ND
33.3
1.58
ND
ND
ND
2.67
20.1
1.88
ND
15.8
4.45
NO
ND
ND
ND
ND
23.9
7.32
1.81
ND
ND
ND
1.17
4.57
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
NO
NO
NO
ND
NO
ND
ND
ND
ND
ND
NO
D ND
ND
ND
NO
ND
ND
D ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
D ND
ND
ND
ND
D ND
NO
ND
ND
ND
NO
NO
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
3.62
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
1.04
1.44
ND
201
84.4
225
11.8
35.4
78.8
39.9
200
333
0.58
37.1
1142
517
3214
43.5
463
34.3
80.9
89.8
35.8
52.0
797
136
107
590
89.2
1.46
1.00
1.50
7.21
63.6
2493
44.3
16.9
15.7
13.0
12.7
7.94
50.5
5.29
1.80
32.9
D ND
D ND
ND
E 9.76
E 18.5
E 27.6
1.97
24.7
33.5
11.5
79.2
E 12.4
D ND
NO
E 88.0
E 74.3
E 182
ND
E 37.3
ND
ND
ND
NO
ND
E ND
E ND
ND
E ND
E ND
D ND
NO
D ND
ND
E 5.32
E 103
ND
ND
ND
ND
1.40
NO
ND
NO
D ND
ND
ND
HD
ND
ND
ND
ND
D ND
ND
ND
ND
26.5
ND
ND
ND
ND
E ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
0 ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
21.1
NO
ND
2.29
ND
ND
ND
18.4
11.6
ND
ND
9.91
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
NO
ND
ND
ND
3.44
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
46.5
393
ND
2.55
NO
ND
D ND
ND
NO
ND
3.42
ND
HD
ND
ND
0.39
ND
NO
0.56
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
E ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
0.39
ND
ND
0.94
ND
ND
ND
NO
ND
ND
ND
0.26
NO
ND
ND
ND
0.51
ND
ND
ND
ND
NO
ND
ND
NO
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
D ND
ND
ND
D ND
ND
ND
ND
NO
ND
NO
ND
D ND
ND
ND
ND
ND
0 NO
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
7.08
15.4
2.51
26.5
ND
NO
ND
NO
ND
ND
NO
2.36
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
3.44
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
NO
ND
NO
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D-5-28
-------
Episode SCC Type Description
XENOBIOTICS CONCENTRATIONS, ng/g
KEPT DOE DIELDRIN ENDR1N OICOFOL ME
EP CHL
PERTHANE NIREX
NITROFEN CHLOR
PYRIFOS
ISOPROP
3248 OD050588
3249 DJ022503
3249 OJ022504
3250 DJ022506
3252 DJ022509
3252 DJ022510
3252 00020989
3252 00052588
3256 OJ022518
3258 DC038901
3258 DC038902
3259 DB000466
3259 DB000473
3259 DB069101
3260 DB000493
3261 DY026002
3262 DY026004
3266 OY022701
3266 DY022702
3266 00012389
3267 DY022101
3267 DY022102
3270 OY022108
3271 OY022110
3272 DY022112
3273 OY022113
3273 DY022114
3274 DY022116
3276 DY022119
3278 DY022124
3281 DY022205
3282 OY022206
3282 DY022207
3283 DY022209
3285 DY022212
3285 DY022213
3286 DY022215
3287 OY022216
3288 DY022217
3288 DY022218
3289 DY022219
3289 DY022220
3290 OY022221
3290 DY022222
3294 DJ022111
F UB not available
F PF Brook Trout
F W8 Sucker
F UB Sucker
F PF Lm Bass
F WB Sucker
L PF Lm Bass
L UB Sucker
F UB Sucker
F PF Spot
F WB Croaker
F UB Goldfish
F PF Lm Bass
F UB Sucker
F UB Carp
F UB Striped Mullet
f UB Tilapia Tilapis
F PF Black Crappie
F UB Channel Catfish
L PF Black Crappie
F PF Rainbow Trout
UB Sacramento Sucker
UB Sucker
UB Sucker
UB Uhite Surfperch
UB Sculpin
UB Surf Smelt
UB Sculpin
UB Walleye
UB Sacramento Sucker
UB Sucker
PF Flathead Catfish
WB Carp
WB Carp
UP Stingray
WB Diamond Turbot
UB Carp
UB Tilapia Zilli
PF Squawfish
UB Sucker
UP Bocaccio
UB Sculpin
PF Redear Sunfish
UB Blackfish
UP True Cod
NO
ND
NO
ND
ND
4.39
ND
NO
NO
ND
5.33
ND
NO
ND
ND
NO
ND
NO
NO
ND
ND
ND
ND
ND
14.3
ND
ND
ND
ND
ND
2.14
NO
NO
ND
19.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.26
ND
NO
ND
ND
44.7
5.66
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
D ND
ND
ND
ND
83.2
22.2
25.7
8.94
ND
ND
ND
ND
ND
15.6
ND
ND
ND
NO
6.36
ND
23.7
ND
20.3
3.69
19.66
13.9
11.6
NO
14.1
NO
88.2
10.9
NO
10.9
ND
1.71 D
2.78
4.57
ND
16.0
1.11 D
ND
ND
ND
11.6
7.21
10.9
36.8
9.27
140 E
43.5
60.6 E
25.5
3.63
16.6
ND
5.16
ND
37.8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
31.7
1.99
7.37
60.6
84.0
848
62.1
1061
117
58.31
45.8
94.2
5.37
202
54.0
144
48.8
54.8
2090
77.1
3.90
10.4
53.8
3.10
805
11.7
4.34
1.65
7.23
73.2
80.4
2820
8708
772
10.9
101
149
45.7
1433
1484
95.3
172
13.3
997
9.46
ND
D ND
NO
E 4.00
E 5.50
E 56.8
E 3.77
E 56.1
10.8
14.99
16.8
ND
NO
ND
6.51
E 41.2
ND
E ND
E ND
E ND
ND
ND
ND
ND
E 260
NO
ND
D ND
ND
E ND
E 1.21 D
E 44.0
E 188 E
E ND
21.9
NO
E ND
4.12
E 174 E
E 161
5.07
E 6.78
ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
16.2
NO
ND
ND
ND
ND
NO
13.8
45.4
ND
ND
NO
ND
ND
7.39
16.0
NO
ND
ND
ND
ND
ND
ND
ND
ND
1.58
24.3
1.49
36.0
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
0.93
5.13
ND
ND
ND
ND
ND
ND
11.8
NO
ND
ND
ND
1.37
ND
ND
ND
ND
ND
D ND
NO
0 ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
D NO
ND
ND
ND
ND
NO
ND
NO
0.36
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
D 0.29
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
NO
ND
ND
1.87
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
NO
ND
0.48
ND
ND
ND
ND
ND
ND
ND
ND
D ND
NO
NO
ND
ND
0.88
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
D ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
3.95
3.17
ND
ND
ND
D ND
NO
ND
ND
ND
NO
ND
7.18
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
78.7
344
61.7
ND
NO
5.12
3.40
ND
ND
ND
ND
ND
2.22
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
E ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
D ND
ND
D-S-29
-------
Episode SCC Type Description
XEMOBIOTICS CONCENTRATIONS, ng/g
3294
3295
3296
3297
3298
3298
3299
3299
3299
3300
3300
3300
3301
3301
3301
3302
3302
3303
3303
3303
3304
3304
3304
3305
3305
3305
3306
3306
3306
3307
3308
3309
3310
3310
3311
3311
3312
3312
3313
3313
3314
3314
3315
3315
3316
DJ022113
DJ022114
DB040101
DB041501
DB041601
DB041604
DB040601
08040604
00040601
DB040201
DB040204
00021389
DB041101
OB041104
00030989
DB041901
DB041904
DB042301
DB042304
00102588
DB041001
OB041004
00041004
DB042001
DB042004
00110388
DB041801
DB041804
00041801
DB042101
DB040001
OB041301
OC032701
DC032702
DC032801
DC032802
DC033101
DC033102
DC033201
OC033202
DC033301
DC033302
DC033401
DC033402
OC033501
UP
WB
WB
WB
PF
WB
PF
WB
WB
PF
WB
WB
PF
PF
WB
PF
WB
PF
WB
PF
WB
WB
WB
PF
WB
WB
PF
WB
WB
PF
WB
WB
PF
WB
PF
WB
PF
WB
PF
WB
PF
WB
PF
WB
Mussel
Atlantic Salmon
White Sucker
Carp
Carp
Lm Bass
White Sucker
Lm Bass
Sucker
White Sucker
Sm Bass
Channel Catfish
Carp
Northern Pike
Northern Pike
White Sucker
Lm Bass
White Sucker
Sm Bass
White Sucker
Northern Pike
White Sucker
White Sucker
Channel Catfish
Sm Bass
Channel Catfish
White Sucker
Sm Bass
White Sucker
White Sucker
Northern Pike
White Sucker
Bullhead
Walleye
Redhorse Sucker
Sm Bass
Redhorse Sucker
Sm Bass
Redhorse Sucker
Sm Bass
Channel Catfish
White Bass
Carp
Lm Bass
White Sucker
OXY
CHLOR
ND
ND
ND
ND
ND
ND
ND
ND
ND
9.83
ND
ND
ND
NO
ND
7.89
ND
ND
ND
ND
ND
ND
ND
36.1
ND
43.3
ND
ND
ND
3.02
ND
ND
ND
NO
2.96
ND
ND
1.99
3.33
2.03
9.51
1.93 D
2.41 D
ND
ND
CIS
NON
ND
ND
ND
ND
ND
ND
ND
ND
ND
10.9
ND
ND
23.3
ND
ND
18.7
ND
ND
ND
ND
ND
ND
6.29
29.0
ND
28.9
ND
ND
ND
3.75
ND
ND
ND
ND
4.54
ND
20.3
ND
6.35
ND
50.9
7.53
ND
ND
ND
TRANS
NON
ND
1.22 D
6.99
9.59
29.2
0.83 D
27.1
3.63
17.6
26.7
4.97
3.80
68.7
3.03
3.69
39.4
2.16 D
ND
ND
ND
2.04 D
8.03
16.1
77.1
ND
77.2
3.93
1.53 D
5.90
5.98
ND
ND
30.8
ND
13.2
3.95
53.9
12.83
26.4
4.16
185 E
24.1
22.1
2.08 D
1.84 D
HEPT
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
0.28
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
HEPT
EP
ND
NO
ND
ND
ND
ND
ND
N
ND
ND
ND
ND
ND
ND
ND
1.51
ND
ND
ND
ND
ND
ND
NO
ND
ND
5.17
ND
ND
NO
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DDE
0.38
31.0
43.6
58.2
202
11.5
141
21.7
106
267
41.4
30.9
1005
29.9
35.5
509
19.8
31.0
1.81
10.7
20.7
115
207
602
9.75
607
42.1
13.5
63.4
78.8
2.49
15.2
100
12.4
6.28
1.51
22.6
5.33
200
19.48
51.7
10.0
14028
915
3.92
D
E
E
E
E
E
E
D
E
E
E
E
E
D
E
D
E
E
DIELDRIN
ND
ND
13.7
19.8
22.4
ND
19.3
3.69
14.6
18.1
2.53
1.65 D
85.4
2.64
3.86
25.8
ND
ND
ND
ND
ND
ND
12.5
43.0
ND
42.9
12.9
ND
12.6
5.55
ND
4.05
12.4
4.50
3.74
1.18 D
5.69
4.55
7.75
ND
19.6
4.79
ND
ND
ND
ENDRIN
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
118
4.54
ND
ND
ND
DICOFOL
ND
ND
ND
NO
ND
ND
NO
ND
ND
1.95 D
ND
ND
6.71
0.36 D
0.57 D
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
HE
CHI
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PERTHANE NIREX NITROFEN CHLOR ISOPROP
PYRIFOS
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.57
2.78
ND
ND
0.75
0.28
1.29
37.9
7.91
6.03
73.7
5.92
6.87
65.6
3.63
ND
ND
ND
7.25
12.7
18.1
135
2.25
137
5.53
4.10
8.84
18.8
ND
ND
ND
ND
0.57
0.18
1.36
1.14
0.83
ND
ND
0.22
ND
NO
ND
ND
ND
D ND
D NO
ND
ND
D ND
D ND
D ND
12.8
ND
ND
ND
ND
ND
10.6
ND
ND
NO
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
D ND
D ND
D ND
D ND
D ND
NO
ND
D ND
ND
ND
ND
ND
ND
ND
ND
12.0
ND
ND
ND
ND
ND
NO
ND
14.0
4.29
5.29
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
0.34
0.93
ND
2.86
1.23
1.12
NO
17.2
2.40
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
ND
ND
D ND
D ND
ND
ND
D ND
ND
ND
ND
D-5-30
-------
Episode SCC Type Description
XENOBIOTICS CONCENTRATIONS, ng/g
HEPT DDE D1ELDRIN ENDRIN DICOFOL ME
EP CHL
PERTHANE HI REX
NITROFEN CHLOR ISOPROP
PYRIFOS
3317 DC033601
3318 DC033701
3319 DB041401
3320 DB041412
3321 DB040401
3321 00100688
3323 DB041206
3324 DB041252
3325 DB041218
3326 DB041208
3327 DB040301
3327 OB04031S
3328 DD029111
3329 DDO 16003
3330 DD029110
3331 DD016007
3332 DD016009
3333 DD016012
3334 000 160 13
3335 ODD 160 15
3335 DD029101
3335 DD029102
3335 D0029103
3335 00091588
3336 DDO 16004
3336 DDO 16006
3336 D0016017
3336 DD016018
3337 DD016019
3338 DDO 16022
3339 DDO 16023
3340 DD029114 1
3341 DD016104 1
3341 00081788 1
3342 DD016105
3343 DD016107
3344 DD016109
3345 D0016111
3346 DD016113
3346 DD016114
3347 DD016115
3348 DDO 161 17
3348 DD016118
3349 DD016119
3350 DD016121
F WB White Sucker
WB White Sucker
WP Winter Flounder
WP Bluefish
UP Winter Flounder
WP Winter Flounder
WP Winter Flounder
WP Bluefish
WP Bluefish
WP Bluefish
WP Bluefish
WP Bluefish
WB Carp
WB Bowfin
WB Spotted Sucker
WB Carp
WP Spotted Drum
WB Sea Catfish
WB Sea Catfish
WP Spot
WP Red Drum
WB Southern Flounder
WP Sheepshead
WP Red Drum
WP Black Drum
WP Sheepshead
WP Red Drum
PF Spotted Sea trout
WB Spotted Sucker
WB Spotted Sucker
WB Carp
: WB Channel Catfish
: WB Catfish
. WB Catfish
WB Spotted Sucker
WB White Sucker
WB Carp
WB Redhorse Sucker
WB Creek Chubsucker
PF Lm Bass
WB Carp
PF White Perch
WB Blue Catfish
WB Carp
WB Carp
ND
ND
ND
ND
2.20
2.13
2.75
4.56
ND
3.05
ND
ND
ND
ND
0.46
ND
ND
1.70
5.94
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.52
ND
4.46
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.13
ND
ND
ND
ND
ND
D 6.21
D 5.47
11.9
4.14
2.59
6.11
3.34
6.82
6.72
ND
D ND
ND
ND
D ND
29.8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
9.81
19.6
ND
18.0
16.2
ND
ND
ND
ND
ND
ND
21.2
ND
ND
D 7.86
29.6
ND
5.56
13.5
12.3
20.6
20.9
39.4
8.77
7.12
14.6
8.90
17.1
18.2
ND
6.59
ND
ND
5.03
65.0
ND
1.45
1.12
2.19
ND
ND
ND
ND
ND
ND
ND
53.9
ND
41.8
38.7
41.0
5.42
42.0
14.4
3.62
ND
76.4
ND
2.50
17.0
89.3
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.46
ND
ND
22.2
25.8
42.9
26.2
26.4
29.5
27.3
15.9
29.0
46.2
43.8
247
2.07
15.1
8.31
11.9
51.2
254
6.32
3.37
6.03
5.83
2.20
1.13
3.49
1.71
ND
18.2
ND
95.5
15.9
288
265
207
9.57
229
106
17.7
4.45
178
3.85
13.8
242
146
ND
5.93
14.1
4.52
12.1
9.85
8.18
9.74
2.78
8.90
4.82
8.41
E ND
D 4.25
1.84
ND
ND
ND
E ND
NO
D 1.76
ND
ND
D ND
D ND
ND
D ND
ND
3.46
ND
E 30.7
7.75
E 16.7
E 14.3
E 22.0
ND
E 36.4
E 3.50
ND
ND
E ND
0.96
6.06
E 7.18
E 47.0
ND
ND
ND
ND
ND
4.24
ND
ND
ND
ND
NO
ND
ND
ND
D ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.45
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
2.39
ND
ND
ND
ND
ND
ND
ND
ND
0.53
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.72
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.52
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.30
0.63
ND
ND
ND
ND
0.32
5.84
ND
7.00
2.39
ND
0.27
8.17
ND
ND
ND
ND
ND
ND
ND
ND
D 0.42
7.22
ND
1.41
10.2
3.67
3.25
ND
ND
4.55
ND
NO
ND
1.50
ND
0.27
1.47
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
NO
D ND
ND
ND
ND
D ND
ND
D ND
ND
ND
0.51
ND
ND
ND
ND
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
D ND
D ND
ND
ND
22.3
ND
ND
1.45
1.61
0.63
3.38
1.11
0.84
2.88
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.67
ND
NO
ND
ND
ND
ND
ND
ND
ND
0.88
ND
ND
0.98
ND
ND
ND
ND
ND
D ND
D ND
D ND
ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D NO
ND
ND
D ND
ND
D-5-31
-------
Episode SCC Type Description
XENOBIOT1CS CONCENTRATIONS, ng/g
KEPT DDE DIELDRIN ENDRIN DICOFOL HE
EP CHL
PERTHANE MIREX
NITROFEN CHLOR ISOPROP
PYRIFOS
3350 D0016122
3351 00016124
3352 DF023723
3352 DF023724
3352 X022089
3353 DF024121
3353 DF024122
3354 DY022301
3354 DY022302
3355 DY022303
3355 DY022304
3356 DE030201
3357 OY022224
3360 D0029117
3375 D0016305
3375 DD016306
3375 00071189
3376 00016307
3376 D0016308
3377 00016309
3377 00016310
3378 00016311
3378 00029115
3385 DD016401
3385 00101888
3395 00016421
3401 00016509
3401 00016510
3403 DD016513
3403 DD016514
3404 00016515
3404 00016515
3409 DB040701
3409 DB040706
3411 DB040501
3412 DB040901
3412 DB040907
3414 DC036203
3414 OC036204
3415 DC036205
3415 DC036206
3419 DC036207
3419 DC036208
3420 DC036209
PF Lm Bass
WB Carp
PF Crappie
WB Carp
PF Crappie
BF Blue Catfish
UB Sm Buffalo
UB Carp
PF LM Bass
UB Carp
PF LM Bass
UB Carp
UB Sacramento Sucker
UB Carp
UB Carp
PF Lm Bass
PF LM Bass
UB Carp
PF LM Bass
UB Carp
PF LM Bass
UB Spotted Sucker
UB Greyfin Sucker
UB Redhorse Sucker
B not available
UB Redhorse Sucker
UB Carp
PF LM Bass
UB River Carpsucker
PF Lm Bass
UB Carp
UB Carp
UB Carp
PF Lm Bass
UB Redhorse Sucker
PF Sm Bass
WB Carp
PF Sm Bass
BF Channel Catfish
PF Sm Bass
BF Channel Catfish
WB White Sucker
PF Freshwater Drum
PF Greenfish
3420 DC036210 F WB Carp
NO
NO
MO
NO
ND
NO
ND
ND
ND
4.65
ND
ND
ND
ND
ND
0.88
ND
ND
ND
ND
1.78
ND
ND
ND
2.77
4.78
ND
ND
14.4
ND
ND
1.84
26.5
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
16.5
ND
ND
NO
ND
ND
14.1
ND
24.4
ND
ND
ND
15.9
ND
0.38
ND
48.5
ND
123
NO
5.11
ND
6.76
5.70
23.7
ND
ND
28.0
ND
6.60
D 8.52
25.2
ND
ND
3.01
19.2
ND
ND
ND
3.45
ND
ND
ND
ND
4.21
ND
ND
6.17
ND
7.49
11.3
ND
0.98
53.9
2.02
37.1
30.3
33.8
188
6.08
21.65
157
4.39
398
13.70
7.18
ND
19.8
25.3
65.6
27.2
1.72
99.8
8.36
19.2
22.0
78.0
3.17
ND
6.58
47.2
ND
13.4
ND
20.7
9.20
4.88
4.12
11.4
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
NO
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.27
559
144
2237
118
1082
1980
835
14.1
477
22.1
382
207
409
447
2.57
8.22
167
4.38
632
11.42
175
194
17.5
18.6
174
1157
68.0
32.5
3.40
136
185
374
14.3
17.2
55.6
671
13.4
54.6
8.56
81.9
29.58
9.47
10.31
36.9
ND
E 3.30
D ND
E ND
E NO
ND
E ND
2.29
ND
E 22.3
ND
E 25.6
20.5
E ND
E 94.1
1.82
7.06
E 41.5
ND
E ND
3.37
E 6.77
E ND
ND
ND
E 28.7
ND
E ND
66.7
3.97
E ND
E ND
E 16.9
ND
12.3
E 2.59
E 29.3
ND
14.7
ND
11.4
20.02
4.78
7.59
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
8.80
ND
ND
2.88
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
8.10
ND
ND
ND
ND
ND
0.54
ND
1.73
ND
74.3
ND
ND
1.77
ND
ND
ND
0.78
ND
0.46
ND
1.25
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.19
ND
ND
ND
ND
ND
ND
NO
ND
D ND
NO
D ND
ND
ND
ND
ND
D ND
ND
17.9
NO
D ND
ND
D ND
ND
D ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.00
ND
4.96
12.0
ND
ND
1.00
ND
1.45
ND
10.2
14.4
ND
ND
20.9
ND
35.5
ND
1.73
10.6
ND
ND
1.89
4.83
0.21
ND
ND
ND
ND
ND
ND
ND
14.2
85.4
ND
ND
ND
0.77
ND
ND
1.03
ND
ND
ND
ND
ND
ND
ND
ND
17.9
NO
D ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
D ND
ND
ND
ND
D NO
NO
D ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
1.37
ND
ND
1.57
4.78
64.5
1.15
2.72
45.6
0.90
23.6
3.42
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.07
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
D ND
ND
ND
D ND
ND
ND
D ND
ND
ND
D ND
ND
HO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D-5-32
-------
Episode SCC Type Description
XENOB10T1CS CONCENTRATIONS, ng/g
HEPT DDE DIELDRIN ENDRIN DICOFOL HE
EP CHI
PERTHANE MIREX
N1TROFEN CHLOR 1SOPROP
PYRIFOS
3421 DC036211
3421 DC036212
3422 DC036213
3422 DC036214
3423 DC036216
3424 DC036218
3425 DF025005
3426 DB069102
3427 OB069103
3428 DB069104
3429 DB069105
3430 DB069106
3431 DB069109
3433 DB069112
3434 DB040801
3434 00011889
3435 DD016602
3444 DD016603
3444 DD016604
3444 DD029512
3445 DD029513
3446 DD016605
3446 DD016606
3446 00091889
F PF White Perch
F UB Carp
F PF Lm Bass
F UB Yellow Bullhead
F UB White Catfish
F UB Whits Catfish
F UB Carp
F PF Bluefish
F PF Bluefish
F PF Bluefish
F PF Ueakfish
F WB White Catfish
F UB Red Snapper
F UP Flounder
F UP Flounder
L UP Flounder
F UB Bigmouth Buffalo
F UB Carp
F BF Channel Catfish
F PF Lm Bass
F UB Flounder
F PF Striped Bass
F UB Carpsucker
F UB Carpsucker
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.09
8.39
6.61
ND
ND
10.
1.87
ND
2.62
2.52
ND
ND
ND
ND
ND
5.42
ND
ND
ND
ND
ND
ND
ND
ND
3.94
5.95
7.09
44.3
ND
ND
ND
ND
ND
ND
ND
3.38
ND
ND
NO
10.3
1.75
ND
5.98
5.09
11.6
ND
7.51
5.01
8.48
14.2
20.1
115
76.4
109
16.1
ND
30.5
26.9
27.8
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
28.7
15.4
10.5
1.36
ND
ND
ND
ND
2.76
22.2
4.35
5.91
57.7
14.1
55.1
27.2
ND
60.2
10.2
28.7
8.33
36.8
65.3
88.1
141
2448
2459
28.7
8.08
11.1
12.9
13.2
ND
13.4
ND
ND
ND
NO
ND
4.13
ND
E 4.47
ND
ND
ND
5.05
E 14.8
E 16.5
236
E 115
E 58.9
14.3
1.36
1.22
1.70
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
162
ND
3.22
ND
D ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.53
ND
2.83
ND
ND
1.40
0.43
0.57
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
4.55
0.88
ND
NO
D ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.38
ND
ND
ND
ND
ND
0.24
ND
ND
1.73
2.01
3.49
ND
ND
0.65
ND
ND
ND
ND
ND
ND
ND
ND
NO
D ND
ND
ND
ND
ND
ND
D ND
0.24
ND
D ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.96
D ND
ND
22.6
21.7
22.3
1.53
ND
0.48
NO
0.45
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
NO
D ND
ND
D ND
ND
D ND
D-5-33
-------
D-5-34
-------
Key for Xenobiotic Data Table (Units = ng/g) (continued)
TRIFLUR
PCA
BIPHENYL
TOT PCBs
1C1
2C1
3C1
4C1
5C1
6C1
7C1
8C1
9C1
10 Cl
DIPHEN DIS
HCBUT
Trifluralin
Pentachloroanisole
Total Polychlorinated Biphenyls
Total Monochlorobiphenyls
Total Dichlorobiphenyls
Total Trichlorobiphenyls
Total Tetrachlorobiphenyls
Total Pentachlorobiphenyls
Total Hexachlorobiphenyls
Total Hectachlorobiphenyls
Total Octachlorobiphenyls
Total Nonachlorobiphenyls
Total Decachlorobiphenyls
Diphenyl Disulfide
Hexachlorobutadiene
CAS Number
1582/09/8
1825/21/4
92/52/4
1336/36/3
27323/18/8
2551/42/9
25323/68/6
26914/33/0
25429/29/2
26601/64/4
28655/71/2
31472/83/0
53742/07/7
2051/24/3
882/33/7
87/68/3
DATA FLAGS
D = Value below limit of quantitation for all xenobiotics except mercury and PCBs,
D = 2.5 ng/g
For Polychlorinated Biphenyls
Number of Chlorines D. ng/g
1-3 1.25
4-6T 2.50
7-8 3.75
9-10 6.25
E = Value exceeds highest calibration standard
See Dioxin/Furan Data Table Key for explanation of other codes. The tables include
environmental samples (those starting with a sample number of D) and the duplicate samples
(those starting with a Q) and confirmation samples (those starting with an S). The number of
samples shown on the summary tables in Volume I does not include the duplicate and
confirmation samples.
D-5-35
-------
D-5-36
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 ACT 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBU
DIS
2015 DF001001
2016 DF001101
2017 DF001201
2018 DF001301
2023 DFOOH03
2026 DF001702
2027 DF001803
2037 DY000501
2056 DE000501
2057 DE000601
2059 DE000801
2060 DE000901
2070 OJ000902
2098 DH001501
2100 DH001703
2105 DH002204
2109 OH002601
2110 DH002710
2122 DH003904
2126 DD000302
2133 D0001002
2139 DD001601
2142 DD001902
2148 00002501
2151 DD002803
2152 OD002903
2190 DG005101
2190 DG005104
2191 DG005205
2194 OG005501
2199 DG006001
2199 DG006004
2201 DG006201
2205 DG006601
2210 DC005401
2211 DC005503
2212 DC005602
2212 DC005605
2215 DC005902
2216 DC006003
2220 DC006405
2227 DC007104
2228 DC007201
2231 DC007503
F UB Carp
F UB Sucker
F WB Carp
F UB Sucker
F UB Carp
F UB Carp
F UB Carp
F UB not available
F UB Carp
F UB Carp
F UB Carp
F UB Carp
F UB Longnose Sucker
F UB N/A
F UB Catfish
F UB Carp
F UB N/A
F UP Brown Trout
UB White Sucker
F UB Carp
F BF Blue Catfish
F UB Carp
F UB Catfish
F UB Saltwater Catfish
F UB Spotted Sucker
UB Lake Chubsucker
F UB Carp
F PF Bluegill
F UB Carp
F UB Carp
F UB Carp
F PF Lm Bass
F UB Carp
F UB Carp
F UB Catfish
F UB Redhorse Sucker
F PF Sm Bass
F WB Uhite Sucker
F UB Carp
F UB Uhite Sucker
F UB Catfish
F UB Channel Catfish
F PF Longear Sunfish
F UB Gizzard Shad
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
16.4
ND
ND
ND
ND
120
ND
ND
4.62
ND
ND
ND
ND
ND
ND
85.5
ND
458
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.41
1.82
2.85
0.15
0.33
2.31
0.82
ND
13.6
4.47
3.59
3.06
ND
ND
14.1
ND
ND
ND
ND
4.02
1.70
ND
ND
ND
ND
2.01
E 1.23
ND
E 5.66
15.0
6.28
ND
ND
0.57
19.9
0.87
0.59
12.1
23.8
ND
1.69
ND
ND
4.27
0.57
D 0.34
ND
D 0.45
D 0.13
D 0.59
D 0.29
ND
33.4
1.05
22.5
0.56
0.22
0.85
1.08
ND
0.46
0.17
0.45
0.36
D 0.13
0.61
0.54
ND
0.64
D 0.66
D 0.15
0.49
2.07
2.47
2.63
0.57
0.86
D 0.40
25.9
D 0.89
D 0.41
0.24
10.2
0.29
D 0.82
0.87
0.10
1.84
D 924.75
D 142
6.12
D ND
D 101.67
D 106.85
D 7.64
ND
1295.2
D 1051
15897.3
D 461.7
D ND
D 2.94
D 685.64
ND
D ND
D ND
D 19.62
D ND
D 30.74
D ND
D 273.95
24.66
D ND
D ND
D 5.04
D ND
D 146.37
D 297
26.64
D 42.63
D ND
D 19.06
2313.5
D 1322.6
D 856.34
D 3804.1
9437
D ND
D 31.2
D ND
D ND
D 1228.9
ND
ND
ND
NO
ND
ND
ND
ND
22.4
ND
ND
ND
ND
ND
4.97
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.50
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.00
ND
46.3
ND
ND
ND
1.55
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
7.58
ND
ND
10.4
112
ND
ND
ND
ND
ND
4.75
ND
ND
ND
1.17
1.11
ND
ND
24.4
95.6
1196
32.5
ND
ND
12.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
9.37
16.1
ND
3.18
ND
ND
28.7
3.71
3.14
206
E 1689
ND
ND
ND
ND
11.4
129
20.3
ND
ND
D 13.9
D 4.61
ND
ND
102
517
E 7183
147
ND
ND
131
ND
ND
ND
ND
ND
2.44
ND
2.85
NO
ND
ND
ND
ND
41.0
54.0
ND
19.3
ND
ND
229
81.0
86.9
E 1032
E 4112
ND
ND
ND
ND
161
E 300
50.3
2.27
ND
24.6
33.0
NO
ND
209
E 305
f. 4523
147
ND
ND
265
ND
ND
ND
11.1
ND
D 11.6
NO
63.3
6.06
ND
ND
2.06
ND
56.3
106
6.80
7.88
ND
6.74
E 578
E 242
E 258
E 1203
E 2230
ND
7.50
ND
ND
337
E 367
54.7
D 3.85
ND
41.0
48.1
7.64
ND
E 552
E 108
E 2169
109
ND
2.94
E 213
ND
ND
ND
8.52
ND
16.7
ND
139
18.6
ND
ND
D 1.81
ND
28.9
94.3
16.0
10.2
ND
10.8
E 1017
E 525
E 340
E 1005
E 1063
ND
23.7
ND
ND
E 445
E 124
16.7
ND
ND
21.0
16.9
ND
ND
E 328
25.4
E 663
26.2
ND
ND
E 54.2
ND
ND
ND
ND
ND
ND
ND
E 58.3
ND
ND
ND
D 1.17
ND
10.8
26.1
3.84
2.07
ND
1.52
E 389
E 346
E 148
E 309
E 231
ND
ND
ND
ND
E 171
ND
ND
ND
ND
ND
3.13
ND
ND
E 53.4
ND
E 117
ND
ND
ND
3.82
ND
ND
NO
ND
ND
ND
ND
10.5
ND
ND
ND
D ND
ND
ND
ND
ND
D ND
ND
D ND
E 64.2
E 88.8
E 20.3
E 38.7
E ND
ND
ND
ND
ND
45.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E 27.1
ND
ND
ND
ND
ND
ND
ND
42.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E 8.99
ND
ND
ND
ND
ND
ND
ND
16.4
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D-5-37
-------
XEN0610T1CS CONCENTRATIONS, ng/g
Episode SCC Type Description
2246 DJ002302 F WB Bridget ip Sucker
2247 DJ002404 F UP Mountain Whitefish
2280 DFOOS201 F WB Carp
2280 00121688 L WB Carp
2283 OF005501 F WB Gray Redhorse
2290 DD003403 F WB Spotted Sucker
2294 00003804 F WB Carp
2297 DD004102 F WB Carp
2298 DD004203 F UP Lm Bass
2301 00004504 F WP Rock Bass
2302 DD004601 F WB Quill back Carpsucker
2304 00004801 F WB Carp
2309 00005301 F WB Carp
2322 DB001301 F WB White Sucker
2326 OB001701 F WB White Sucker
2328 DB001904 F PF Chinook Salmon
2329 DB002004 F PF Brown Trout
2341 00006003 F WB Carpsucker
2355 OA001603 F WB White Sucker
2356 DA001702 F PF Lm Bass
2375 OA003803 F WB White Sucker
2376 DA003903 F WB White Sucker
2379 DE005404 F PF Lm Bass
2380 DE005501 F WB Carp
2383 DE005801 F WB Carp
2385 DE006002 F WB White Sucker
2394 DE006901 F WB Carp
2394 00006901 L WB Carp
2394 00022189 L WB Carp
2397 DE007201 F WB Sucker
2410 DE008501 F WB Carp
2410 DE008504 F PF Sm Bass
2416 DE009101 F WB Carp
2422 DE009702 F WB Carp
2427 DE010202 F WB Carp
2429 DE010402 F WB Carp
2430 OE010603 F WB Redhorse Sucker
2430 00121488 L F not available
2431 DE010703 F WB Sucker
2432 OE010710 F WB Redhorse Sucker
2435 DE011001 F WB Longnose Sucker
2437 DE011203 F WB Carp
2439 DE011401 F WB Carp
2439 DE011402 F WP Sm Bass
TR1FLUR PCA
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
54.8
ND
ND
ND
ND
ND
ND
ND
37.9
3.08
ND
ND
NO
ND
31.5
6.02
0.33
10.3
0.70
ND
15.4
4.14
ND
3.65
11.6
ND
62.3
42.7
0.87
25.8
30.0
25.8
ND
ND
NO
60.4
ND
ND
1.70
ND
0.56
ND
ND
ND
9.40
44.5
46.8
BIPHENYL TOT 1C1
0.56
0.49
ND
0.14
0.51
12.5
0.82
0.14
0.22
0.15
0.22
0.72
0.16
D 0.79
1.12
D 1.04
1.17
ND
0.86
0.32
0.58
3.59
0.16
1.71
0.99
D 0.92
2.05
2.38
1.13
0.24
12.4
0.19
7.54
0.36
1.42
D 1.35
0.32
D 0.40
0.21
0.64
0.27
0.82
0.55
0.18
PCBS
D 205.5 ND
D 82.24 ND
5.48 ND
D 2.68 ND
D ND ND
472.7 ND
D ND ND
D 132.5 ND
D 4.52 ND
D 28.24 ND
D 26.21 NO
D 1058.7 ND
D 828.56 ND
D 93.28 ND
D 18.87 ND
D 3937.2 ND
D 2109.4 ND
1776.9 7.74
D 84.6 ND
D 39.62 ND
D 796.74 ND
1110.2 ND
D ND ND
D 8471.2 ND
D 8783.1 ND
D 343.1 ND
D 7319.9 ND
D 5332.9 ND
D 4609.8 ND
D 45.37 ND
11119.2 ND
D 422.66 ND
3680.9 ND
D 938.69 ND
D 18490.5 ND
D 29129.7 ND
D 10.15 ND
D 9.27 ND
D 29.3 ND
D 1676.99 ND
D 115.18 ND
0 789.5 ND
D 7977.2 ND
D 5444 ND
2C1
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
9.82
ND
6.07
ND
ND
2.04
2.23
ND
9.31
8.79
ND
21.5
36.7
30.9
ND
17.2
ND
32.0
ND
7.23
81.7
ND
ND
ND
NO
ND
ND
24.2
45.0
3C1
ND
ND
ND
ND
ND
11.8
ND
ND
ND
ND
ND
5.26
2.26
2.11
ND
63.7
8.76
34.5
ND
ND
D 19.8
D 59.5
ND
184
323
ND
1105
577
477
1.31
194
3.46
260
2.69
1108
2458
ND
ND
ND
6.69
ND
ND
647
E 616
4C1
21.5
4.38
ND
ND
ND
88.7
ND
ND
ND
3.74
ND
109
69.3
D 19.9
ND
E 557
250
313
18.1
ND
270
E 309
ND
E 207^
E 1921
32.4
E 2740
E 1576
E 1262
4.56
E 2789
45.7
E 1030
81.7
E 12055
E 17379
ND
ND
ND
242
6.65
40.1
E 2843
E 1970
5C1
94.4
37.0
ND
ND
ND
171
ND
33.1
ND
11.7
4.08
390
E 262
41.3
9.16
f. 1343
f. 679
E 507
44.5
6.83
E 323
E 348
ND
E 3142
E 280J
79.2
f. 2348
E 1713
E 1524
20.2
E 3743
91.4
E 1044
264
E 3699
E 6251
2.15
1.71
13.0
E 601
35.4
303
E 2745
E 1718
6C1
E 77.7
36.1
5.48
2.68
ND
170
ND
83.3
4.52
12.8
16.5
E 435
E 392
25.8
9.71
E 1455
E 818
E 625
22.0
23.3
E 162
E 274
ND
E 2254
E 2636
E 141
E 1048
E 1198
E 1100
19.3
E 2872
E 188
E 955
E 378
E 1226
E 2147
D 8.00
D 7.56
16.3
E 638
55.1
E 379
E 1526
E 982
7C1
11.9
4.76
ND
NO
ND
31.2
ND
E 16.1
ND
ND
5.63
E 105
E 95.2
4.17
ND
E 442
E 307
E 245
ND
9.49
E 19.9
E 101
ND
E 672
E 924
E 78.4
E 57.4
E 202
E 190
ND
E 1306
E 82.3
E 327
E 174
E 328
E 619
NO
ND
ND
E 167
16.5
E 67.4
E 192
E 113
8C1
NO
ND
ND
ND
ND
NO
ND
ND
ND
NO
NO
14.4
E 7.80
ND
ND
E 66.7
E 46.6
E 38.6
ND
NO
ND
E 16.5
ND
E 124
E 159
E 12.1
ND
30.2
25.9
ND
E 198
E 11.8
32.9
38.3
67.3
E 169
ND
ND
ND
22.3
1.53
ND
ND
ND
9C1
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
13.9
8.28
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
25.0
ND
ND
ND
ND
ND
ND
ND
ND
10C
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DIPHEN HCBUT
DIS
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
D-5-38
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
2478 DJ003902 F WB Sucker
2500 DC010203 F WB Black Buffalo
2532 DF019303 F WB Carp
2544 DF019202 F WB Blacktail Redhorse
2608 DE014504 F WB Carp
2618 DE015401 F WB Carp
2618 DE015402 F BF Carp
2618 DE015403 F WB Ouillback
2651 DB008401 F WB White Sucker
2653 DB008503 F WB Carp
2654 DB008601 F WB Carp
2709 DB005101 F WB Catfish
2721 DA006502 F WB Sucker
2721 OD011089 L WB Sucker
2722 DA006601 F WB Sucker
2725 DA006301 f WB Sucker
2748 DY006505 F WB Sucker
2776 DY007101 F WB Carp
2776 ODO10489 L WB Carp
3001 DE019502 F WB White Sucker
3022 DA008401 F WB White Sucker
3023 DA008501 F PF Sm Bass
3024 0*008601 F PF Lffl Bass
3025 DA008701 F WB White Sucker
3028 DA008801 F PF Chain Pickerel
3034 DG025701 F WB Carp
3035 DG025801 F WB Carp
3036 DG025902 F WB Carp
3037 DG026001 F WB Carp
3038 DG026101 F WB Carp
3039 DG026201 F WB Carp
3040 DG026301 F WB Carp
3041 DG026402 F WB Carp
3042 OG026501 F WB Carp
3042 DG026502 F PF Northern Pike
3042 00026501 L WB Carp
3043 DG026601 F WB Carp
3044 DG026701 F WB Carp
3045 DG026801 F WB Carp
3045 DG026802 F PF Flathead Catfish
3046 DG026901 F WB Bigmouth Buffalo
3047 DG027001 F WB Carp
3048 DG027101 F WB Carp
3048 OG027102 F PF White Bass
ND ND
ND 0.76
23.1 3.19
ND 24.2
ND 6.02
ND 122
NO 33.1
NO 240
ND 2.91
0.53 D 40.77 ND
3.50 687.2 ND
0.54 D 677 ND
0.62 D 24.79 ND
1.91 D 3955.98 ND
ND 8706.3 ND
0.20 D 2909.5 ND
E 1.37 0 7091.4 ND
0.71 D 480.04 ND
ND 1.50 D 0.76 D 1833.2 ND
ND 10.88 131.69E 20.5 ND
ND 4.06 1.19 D 8444.1 ND
ND ND ND 460.31 ND
ND ND ND 384.89 ND
ND ND 0.08 D ND ND
ND ND 2.16 D 321.71 14.8
ND ND 0.24 D ND ND
ND ND ND 21.2 ND
ND ND NO 32.69 ND
ND ND ND 10.2 ND
ND ND 0.75 D ND ND
ND ND 0.11 D ND ND
ND ND 0.53 D 30.78 ND
ND 16.1 E .25 D 33.6 ND
ND ND 0.09 D ND ND
1.79 D 2.97 0.72 D 872.12 ND
23.1 3.20 0.65 D 731.85 ND
117 E 6.21 0.64 D ND ND
53.0 3.33 0.48 D 38.55 ND
222 6.49 70.2 148.7 ND
ND 3.87 0.36 D 635.4 NO
28.6 E 1.01 D 0.29 D 58.26 ND
6.15 0.30 D 0.52 D 8.9 ND
27.7 3.43 75.6 E 285.12 7.32
ND ND 0.52 D 3.96 ND
25.9 ND 28.9 245.69 ND
55.9 0.65 D 0.75 D 153.19 ND
82.8 E 4.03 3.37 100.23 ND
39.1 3.98 32.8 2220.99 ND
5.58 0.60 D 13.2 121.03 NO
NO 8.01 1.89 D 31.28 ND
ND ND 1.17 D 192.3 ND
ND 15.4 4.82 2472.5 ND
1.64 D 0.96 D 0.37 D 80.31 ND
NO
ND
ND
ND
6.28
72.2
27.4
45.9
ND
3.29
ND
5.49
4.41
12.6
ND
15.6
ND
ND
ND
10.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
20.7
ND
ND
ND
20.9
ND
ND
ND
ND
17.1
ND
ND
8.10
12.9
ND
ND
ND
16.8
ND
432
1280
455
E 1022
1.34
82.5
ND
303
14.9
4.29
ND
1.74
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.02
6.75
ND
ND
0.80
16.0
ND
1.54
28.6
ND
8.29
5.29
ND
310
8.98
1.43
ND
263
1.70
E
E
E
E
D
E
E
D
D
E
E
D
ND
ND
91.9
ND
2341
3140
1162
2514
27.0
461
8.83
2918
21.6
10.4
ND
28.0
ND
ND
ND
ND
ND
ND
4.72
ND
ND
85.5
87.2
NO
5.85
ND
103
3.16
4.72
34.3
ND
60.8
40.1
12.2
1104
38.0
9.26
50.5
1247
23.7
11.1
42.4
201
7.99
E 895
E 2594
E 800
E 2014
114
E 649
11.67
E 2502
86.1
84.9
ND
64.4
NO
5.32
9.01
ND
ND
ND
16.9
18.2
NO
E 235
244
ND
17.2
17.3
264
E 23.7
2.64
111
ND
95.1
68.6
46.5
E 458
31.2
9.17
26.5
E 687
32.0
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
22.8
206
254
16.8
258
1418
419
1276
220
482
ND
1963
209
180
ND
124
ND
12.4
19.1
ND
ND
ND
9.16
15.4
NO
372
330
ND
15.5
94.8
199
31.4
ND
83
3.96
65.5
39.2
31.9
239
33.1
9.87
88.1
219
18.4
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
6.87
303
96.5
ND
23.7
186
46.1
197
99.6
118
ND
620
110
92.7
ND
64.4
ND
3.48
4.58
ND
ND
ND
ND
ND
ND
144
63.9
ND
ND
15.1
53.4
ND
ND
ND
NO
16.0
ND
9.63
86.5
9.75
1.55
19.1
43.6
4.51
ND
E 124
16.8
ND
ND
16.1
ND
22.5
E 18.1
E 32.0
ND
E 121
14.3
ND
ND
8.77
ND
ND
ND
ND
ND
ND
ND
ND
ND
E 30.6
ND
ND
ND
ND
ND
ND
ND
ND
HD
ND
ND
ND
6.39
NO
D ND
ND
ND
ND
ND
E 11.8
ND
ND
ND
ND
ND
ND
ND
5.37
ND
11.6
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D-S-39
-------
Episode SCC Type Description
TR1FLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3048 00012689 L PF White Bass
3048 00027101 L WB Carp
3049 DG027201 F WB Carp
3050 OG027301 F WB Bigmouth Buffalo
3060 DF009101 F WB Hothead Catfish
3060 OF009102 F WB Sm Buffalo
3060 00073189 I WB Flathead Catfish
3061 OF019106 F WB Sucker
3062 DF024024 F WB Blue Catfish
3063 DF023301 F WB Sea Catfish
3063 DF023302
3064 DF023305 H
3065 OF023419
3065 DF023420
3065 00010788 F BF Bigmouth Buffalo
F WB Catfish
f PF Freshwater Drum
F PF Spotted Seatrout
Shellfish
F BF Bigmouth Buffalo
F WB Flathead Catfish
3066 DF023503
3066 DF023504
3068 DF024001 M Oysters
3068 OF024002 F PF Atl. Croaker
3069 OF024007 F WB Sea Catfish
3069 OF024008 F PF Trout
3069 00051788 F WB Sea Catfish
3070 DF024009 F WB Croaker
3070 OF024010 F PF Sheepshead
3071 DF024014 F WB Carp
3071 OF024015 F PF Longnose Gar
3072 DF024017 F WB Carp
3072 00070688 L WB Carp
3073 DF019221
3074 DF026017
3076 DF028502
3077 DF019114
3078 DF009118
3078 DF023815
3078 DF023816
3079 DF019205
3079 DF019206
3080 DF023317
3080 DF023318
3081 DF024105
3081 OF024106
3082 OF023401
3083 DF023406
3084 DF024109
F WB White Sucker
f PF Broun Trout
F WB Channel Catfish
F WB Redhorse Sucker
F WB Carp
F WB Sm Buffalo
F PF Black Crappie
F PF White Bass
F WB Carp
F WB Carp
F PF Lm Bass
F PF White Bass
F WB Catfish
F WB Carp
F PF Lm Bass
F WB Channel Catfish
1.43
NO
46.5
27.8
NO
NO
NO
NO
ND
NO
ND
ND
NO
NO
NO
5.23
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.90
2.20
NO
NO
NO
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
6.05
ND
16.0
D 0.96
9.14
10.5
7.31
ND
2.51
ND
7.52
3.75
NO
NO
NO
0.48
1.47
0.50
8.12
0.87
3.25
0.73
ND
ND
ND
ND
ND
3.09
8.03
0.32
0 0.21
0.28
NO
4.47
ND
ND
11.8
0.31
1.27
2.77
8.30
ND
0.38
3.39
3.44
ND
5.61
D 0.35
4.69
1.10
0.58
0.15
0.53
0.06
0.43
0.54
0.65
0.69
0.38
0 0.38
0 0.59
D 0.53
0.77
D 0.43
ND
D 1.25
0.19
0.25
0.24
0.56
0.21
3.06
2.25
D 0.12
0 0.11
D 0.79
0.20
0.39
0.13
0.65
0.98
D 0.17
D 0.25
0.20
3.52
0.16
D 0.34
0.51
1.11
0.33
0.75
0 75.81
1125.7
D 1661.6
D 15.55
D 4.96
D 3960
D 3.96
D ND
D 282.4
D 349.34
D 163.17
0 9.04
D 92.73
D 180.95
D 133.2
D 190.55
D 21.16
40.8
D 136.39
D 216.37
D 11.48
D 324
D 84
D 141.08
278.89
D 859.56
D 102.65
D 87.24
D ND
D 44.76
D 46
D 1.43
D ND
D 114.89
D 10.53
D 55.21
D 97.67
337.71
D 10.34
D 10.45
D 12.3
0 7
0 1.49
0 239.7
ND
ND
ND
NO
ND
1.96
NO
ND
ND
ND
2.90
ND
ND
0.45
ND
1.12
ND
ND
ND
ND
ND
NO
ND
NO
NO
4.19
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.00
ND
ND
NO
NO
ND
ND
ND
1.96
NO
NO
NO
0 13.52
NO
NO
ND
ND
ND
ND
ND
D ND
ND
D ND
ND
ND
ND
ND
NO
NO
NO
ND
14.34
1.65
ND
ND
ND
ND
ND
0.10
ND
ND
ND
0.75
ND
18.0
NO
ND
NO
NO
NO
ND
1.69 D
D 66.4
26.7
ND
ND
1128. 1E
NO
NO
ND
2.54
4.97
ND
ND
1.70 D
ND
9.33
ND
ND
7.29
ND
NO
ND
ND
1.70 D
22.96
D 17.47
ND
ND
ND
ND
ND
D ND
ND
7.98
ND
0 2.94
NO
8.81
NO
NO
ND
NO
ND
8.10
23.2
503 E
231 f.
NO
0.87 D
1782. 7E
0.79 D
ND
45.0
35.9
22.4
ND
2.63
33.0
4.60
31.5
2.61 D
24.1
46.2
3.17
3.88
11.7
10.3
50.72
76.06
78.44
3.05
6.44
ND
7.56
NO
0.24 D
NO
31.8
ND
22.98
5.27
71.8
2.44 D
0.81 D
ND
ND
0.75 D
43.0
29.7
347 E
499 E
5.58
4.09
937. 37E
2.75
ND
92.6
84.7
66.5
4.80
22.8
62.5
37.8
45.1
14.3
16.7
48.7
48.7
6.48
85.7 E
19.3
75.12
137.27
219.80E
31.5
23.6
ND
18.9
18.4
1.09 D
NO
38.4
3.47
24.98
33.0
103
6.00
3.61
2.50
7.00
0.74 D
86.7
17.2
167
652 E
9.97
ND
96.30
0.42 D
ND
124
177
55.9
4.24
49.0
69.1
71.5
78.5
4.25
ND
34.2
119 E
1.12 0
178 E
39.0
13.54
28.26
372. 82E
55.8 E
47.2
ND
18.3
27.6
NO
NO
29.9
5.77
3.56
45.9
103
1.90 D
6.03
9.80
NO
ND
78.6
4.02
40.3
238 E
ND
ND
ND
ND
ND
20.8
42.6
10.5
ND
18.3
14.2
19.3
25.0
ND
ND
ND
45.5
NO
48.6
15.4
ND
ND
144.40
12.3
10.0
NO
NO
NO
NO
ND
6.81
1.29 D
ND
13.5
27.1
ND
ND
ND
ND
ND
23.3
ND
ND
14.9
ND
ND
ND
ND
ND
ND
6.60
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
20.79
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
NO
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
NO
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
164
88.31
NO
ND
2.54
ND
1.96
ND
ND
0.81
NO
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
0.27
NO
ND
ND
ND
D-S-40
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HC8UT
DIS
3085 DF024113 F WB Sea Catfish
3085 DF024114 F PF Black Drum
3086 DF023409 F WB Catfish
3086 DF023410 F PF Red Drum
3087 DF023413 F UB Carp
3087 OF023414 F PF White Crappie
3087 DF023415 F WP Bluegill
3088 DF023417 F UB Channel Catfish
3088 DF023418 F PF Bluegill
3089 DF019209 F PF White Crappie
3089 OF019210 F UB Carp
3090 DF019213 F PF White Crappie
3090 DF019214 F WB Channel Catfish
3091 DF019217 F UB River Carpsucker
3092 DF023501 F UB Carp
3092 DF023502 F PF Uamnuth
3093 DF024011 F PF Lm Bass
3093 DF024118
3094 DC017201
3095 DC038801
3095 DC038802
3096 DC035001
F WB Sffl Buffalo
F BF Channel Catfish
BF Brown Bullhead
F WB Channel Catfish
F BF Brown Bullhead
3096 DC035002 F UB Channel Catfish
BF Broun Bullhead
F WB Carp
L BF Brown Bullhead
WB White Sucker
PF American Eel
UB White Sucker
PF White Perch
PF Brown Trout
UB Channel Catfish
UB Carp
PF Lm Bass
F UB Carp
F UB Carp
PF Lm Bass
3097 DC038701
3097 DC038702
3097 00071989
3098 DC038601
3098 DC038602
3098 00051288
3100 DC019701
3101 DC019901
3103 DC036201
3103 DC036202
3104 DC020001
3104 DC020002
3105 DF025001
3105 DF025002
3106 DE026801
3107 OE026901
3108 DE027001
3108 DE027002
3109 DE025001
3110 DE022501
3111 DH015802
F PF Walleye
F WB Carp
F PF Walleye
F WB Carp
F WB Carp
F BF Carp
F UB Silver Redhorse
NO
ND
NO
ND
ND
ND
ND
NO
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
23.7
ND
ND
ND
ND
1.05
ND
1.60
NO
ND
NO
1.80
1.33
4.92
0.11
2.69
NO
ND
0.63
8.95
3.92
13.2
2.15
13.8
0.45
0.39
0.44
35.0
17.4
39.9
0.80
0.27
0.64
NO
ND
4.76
NO
ND
0.90
3.38
0.33
4.49
13.4
ND
1.92
8.74
13.79
0.61
2.76
D 1.68
0.08
D 0.70
0.45
0.23
0.21
D 0.62
D 0.25
0.96
D 0.16
1.30
0.14
0.17
0 0.50
4.70
ND
0.98
0 0.74
1.64
0 0.1T
0 ND
0 0.61
ND
0.98
ND
D 1.71
D 1.06
D 0.35
0.34
1.19
5.07
0.68
0.14
D 0.19
0.32
D 0.20
0.61
0.50
0.20
0.60
82.2
77.40
D 1116.97
14.63
D 142.6
0 8.95
D 86.56
D 8.86
D ND
D 6.93
D 67.65
D 74.7
D 1887.6
D ND
D 67.6
D 0.07
D ND
D 4.3
1961.6
838.8
D 2974.6
D 150.08
D 4412.9
D 270.28
463.54
D 216.67
809.24
0 809.26
1042.7
D 370.17
D 5148.1
0 1392.01
0 778.7
D 321.66
1783.4
D 8.62
D ND
D 231.79
D 761.4
D 37.85
D 483.7
D 5863.5
D 1804.4
D 271.46
ND
ND
1.53
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
0.07
NO
ND
ND
ND
ND
ND
ND
0.21
ND
ND
ND
ND
9.71
ND
ND
ND
ND
0.63
ND
ND
ND
ND
ND
NO
ND
0.90
ND
ND
ND
2.25
ND
ND
9.30
ND
ND
ND
ND
ND
ND
NO
0.51
ND
3.70
D NO
ND
ND
8.26
9.09
ND
2.77
18.0
1.07
3.94
1.42
6.87
6.26
4.46
12.71
NO
2.79
NO
1.11
17.5
ND
ND
ND
ND
ND
ND
D 1.35
ND
ND
ND
D 13.89
8.94
0.86 D
ND
ND
0.86 D
ND
ND
NO
ND
NO
D 7.64
ND
ND
ND
ND
ND
38.2
30.0 E
72.1 E
0 5.04
91.6 E
D 4.35
40.1 E
0 4.94
45.8
310
62.1
66.64
129
80.75
ND
0 23.64
184 E
ND
ND
18.5
46.4
1.01 D
25.1
0 115 E
6.03
7.76
ND 45.7 36.5 ND
37.96 21.69 1.61 D ND
98.7 E 399 E 455 E 98.8
ND 6.67 7.10 NO
ND 109 ND 24.3
1.59 D 1.81 D 5.55 NO
12.8 20.7 36.6 15.6
ND 3.68 5.18 ND
ND ND NO ND
ND 1.68 D 5.25 ND
5.15 21.9 29.2 11.4
12.5 42.1 20.1 NO
135 E 704 E 891 E 134
ND ND ND ND
ND 29.7 30.4 3.80
NO HO ND NO
NO ND NO NO
NO 1.10 0 3.20 ND
321 E 616 E 710 E 223
171 E 282 E 244 E 86.4
551 E 877 E 1006 E 333
24.78 54.76 43.19 11.71
807 E 1556 E 1432 E 419
30.78 68.03 84.38 41.58
120 E 151 E 119 E 29.5
30.30 63.02 65.27 28.40
379 E 298 E 74.0 5.57
370 123 NO ND
473 400 87.4 6.00
105.01 123.28 43.51 11.16
1076 E 2634 E 1248 61.1
290.82 542.44 271.36 81.24
77.0 234 384 83.7
106.43 95.67 70.04 21.18
655 E 522 E 298 E 96.5
ND ND 8.62 E ND
ND ND ND ND
124 E 62.7 E 22.3 4.29
298 274 110 28.9
18.7 12.2 5.94 ND
164 185 86.5 23.1
2833 E 2047 E 630 E 182
159 E 807 E 710 E 110
66.3 115 E 69.8 12.6
NO
ND
E 24.4
ND
ND
ND
ND
ND
NO
NO
NO
ND
15.4
ND
D ND
HO
ND
ND
E 36.6
E 10.9
E 67.3
2.62
E 66.6
14.29
ND
8.48
ND
ND
ND
5.24
ND
85.10
NO
2.96
10.4
ND
ND
ND
4.10
NO
ND
E 47.9
12.4
ND
ND
NO
15.5 E
ND
NO
ND
ND
ND
ND
ND
NO
NO
NO
ND
ND
HO
ND
NO
8.52
5.41
52.1 E
3.28
22.7
17.30
ND
11.10
ND
ND
NO
2.62
ND
37.51
ND
NO
NO
NO
ND
NO
ND
ND
ND
6.31
NO
HO
ND
NO
15.1
NO
NO
ND
ND
ND
NO
NO
NO
ND
ND
ND
ND
NO
NO
NO
ND
ND
16.1
1.93
ND
8.29
ND
3.74
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
NO
NO
ND
ND
ND
ND
ND
NO
NO
ND
ND
NO
ND
ND
HO
ND
ND
NO
ND
ND
ND
ND
ND
NO
NO
ND
NO
NO
ND
NO
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
23.0
3.53
2.37
NO
NO
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
HD
NO
ND
ND
NO
ND
ND
ND
NO
ND
ND
NO
NO
NO
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
NO
HO
ND
ND
D-5-41
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3d 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3112 DE022401 F WB Carp
3112 DE022402 F PF Walleye
3113 OE021101 F BF Channel Catfish
3113 DE021102 F BF Carp
3113 00030789 F BF Channel Catfish
31 U DE021201 F BF Carp
3115 DE021301 F WB Carp
3115 DE021302 F BF Catfish
3115 00101689 L WB Carp
3117 DE021501 F PF Lake Trout
3118 DE021601 F PF Watleye
3118 DE021602 F WB Carp
3118 DE021603 F WB Carp
3118 00010689 L WB Carp
3118 00020488 L PF Walleye
3120 DE021801 F WB Carp
3120 OE021802 F PF Bass
3122 DE022001 F WB Carp
3122 DE022003 F WB Redhorse Sucker
3125 OE022301 F WB Carp
3125 DE022302 F PF White Bass
3132 DE023201 F WB Carp
3132 00010588 L WB Carp
3134 OE023403 F WB Carp
3134 DE023405 F WB Carp
3134 DE023406 F WB Sucker
3135 DE023501 F WB Carp
3136 DE023601 F PF Northern Pike
3137 DE023701 F WB Redhorse Sucker
3138 DE023801 F WB Carp
3140 OE024001 F PF Walleye
3140 DE024002 F WB Carp
3141 DE024101 F PF Northern Pike
3141 OE024102 F WB Carp
3141 OE024103 F PF Northern Pike
3142 OE022502 F WB Carp
3143 OE024401 F Rotten (catf)
3143 OE024403 f WB Carp
3144 DE024901 f WB Carp
3145 DE026601 F WB N. Redhorse
3146 DE026701 F WB Carp
3146 DE026702 F PF Walleye
3147 DC035201 F WB Carp
3148 OE027101 F WB Carp
NO
NO
NO
NO
NO
20.0
58.5
33.1
52.5
NO
NO
NO
ND
NO
NO
ND
NO
ND
ND
ND
ND
5.20
6.03
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.77
HO
6.05
4.68
5.26
1.27
3.10
5.68
2.79
ND
ND
ND
ND
ND
0.19
2.32
ND
1.37
0.69
11.5
1.26
5.21
7.30
ND
ND
ND
0.92
ND
ND
0.59
0.66
0.95
7.79
0.86
1.90
ND
ND
4.05
ND
0.76
23.0
2.93
6.59
ND
D 1.79
0.15
0.55
1.25
1.30
0 0.52
5.63
53.8
3.16
ND
0.13
0.68
0.18
0.62
D 0.11
D 0.90
0.26
D 1.23
0 0.22
1.80
D 1.37
1.89
2.13
0.38
0.33
0.69
D 0.72
0.23
1.01
D 0.50
0 0.22
0 0.15
8.43
D 2.14
D 1.47
1.22
3.35
2.29
0.93
0 0.37
3.58
0.32
1.91
0.72
D 176.1 ND
D 12.2 ND
D 537.6 ND
D 2658.9 ND
D 570.79 ND
D 74 ND
922.56 17.1
757.5 34.3
901.5 19.5
5108.2 ND
D 515.1 ND
D 2516.5 ND
D 832.6 ND
D 2744.8 ND
D 666.3 ND
D 1938.3 ND
D 854.05 ND
D 17723.3 NO
0 473.7 0.50
0 3938.2 NO
D 792.96 NO
D 2804.3 ND
D 3145.8 ND
D 9223.9 ND
0 13587.4 ND
D 25240 ND
D 1521.4 ND
D 8 ND
D 38.19 0.62
D 13362 ND
D 1467.4 1.41
0 4390.3 0.95
4117 ND
D 22695.8 ND
D 3678.1 ND
D 23809 ND
206.97 ND
D 435.6 ND
D 22283.9 12.6
0 643.2 ND
4137.6 NO
D 68.72 ND
0 786.1 ND
0 1824.1 ND
ND
NO
ND
ND
ND
ND
104
27.5
101
ND
ND
ND
ND
ND
ND
3.86
1.07
ND
D 2.66
ND
0.52
4.40
8.60
3.46
ND
ND
1.13
ND
0 ND
79.1
53.3
D 83.9
50.5
283
93
102
NO
2.10
267
NO
ND
NO
5.00
NO
ND
ND
3.50
37.5
3.49
ND
E 259
34.9
E 250
47.2
5.10
11.9
24.6
11.9
8.10
196
D 63.7
6.26
ND
100
D 10.6
127
126
298
56.9
253
D 36.2
ND
8.82
E 1194
E 388
E 788
E 609
E 3334
E 598
1114
4.87
20.6
E 3123
26.1
224
6.71
53.7
13.7
20.7
ND
52.9
418
54.8
ND
E 231
126
E 217
951
138
543
280
569
186
829
313
1102
20.5
863
127
684
792
E 2744
E 2234
4664
273
6.00
19.0
E 7801
E 660
E 2093
E 1675
E 9981
E 1639
E 9812
64.2
125
E 13038
244
E 2149
39.2
E 131
267
71.8
5.30
132
E 928
141
36.4
E 220
E 203
E 204
E 1744
203
E 969
302
E 1058
245
622
293
E 7377
131
E 1896
E 354
787
815
E 3656
E 6093
E 11880
E 667
2.00
8.67
E 2343
E 256
E 1008
E 962
E 5180
E 824
E 8766
87.0
167
E 5317
E 248
E 1261
17.2
E 227
E 792
66.3
6.90
E 234
E 980
E 249
37.6
E 86.1
E 227
E 91.1
E 1848
142
E 753
184
E 839
161
251
151
E 7159
231
E 1005
E 263
700
859
E 2128
E 4363
E 7582
E 478
D ND
1.08
E 1228
E 98.5
E 330
E 622
E 2816
E 414
E 3502
50.9
108
E 508
E 99.8
E 397
5.61
E 312
E 613
17.3
NO
E 97.8
E 268
E 104
NO
5.36
E 89.7
18.9
E 446
27.0
E 197
42.0
E 221
66.2
36.4
28.2
E 1850
78.4
E 74.2
E 34.5
404
469
E 348
E 771
E 861
E 66.1
ND
D ND
E 570
E 10.2
E 69.8
E 174
E 946
E 102
E 453
ND
12.9
E 18.3
25.3
E 92.2
ND
E 57.4
E 125
NO
NO
17.4
E 27.4
18.5
ND
NO
15.1
ND
E 72.0
ND
42.6
ND
45.9
ND
ND
4.08
E 229
9.60
NO
3.34
97.9
76.2
E 46.5
E 65.5
ND
ND
ND
ND
E 133
NO
14.6
E 24.5
E 150
E 8.1
E 60.0
ND
NO
NO
NO
14.4
ND
ND
13.4
NO
HO
NO
NO
NO
NO
ND
NO
NO
ND
NO
NO
NO
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
NO
4.01
ND
ND
NO
NO
13.9
ND
2.06
ND
5.85
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
NO
ND
ND
ND
NO
NO
D ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
NO
NO
NO
ND
ND
ND
NO
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
HO
NO
ND
ND
NO
8.53
10.5
2.99
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
NO
ND
ND
HO
ND
ND
ND
ND
NO
D-5-42
-------
Episode SCC Type Description
TR1FLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3148 DE027103
3149 OC038501
3150 DA008901
3150 00120187
3151 DA009101
3152 DA009201
3161 OC019801
3161 DC019802
3162 DJ024001
3163 DJ024002
3164 DD015702
3165 OD015704
3166 DD015706
3167 D0015708
3167 00062388
3168 00015711
3168 DD015712
3169 00015713
3169 00022789
3170 00015715
3171 00015717
3172 00015719
3172 00015720
3173 DD015722
3174 00015724
3175 00015801
3176 00015803
3177 00015805
3177 00100488
3178 00015607
3179 00015809
3180 00015812
3181 00015814
3182 DD015815
3182 00015816
3183 00015817
3183 DD015818
3184 DD015820
3185 D0015821
3186 DD015824
3187 00015902
3188 00015903
3188 00015904
3189 00015905 F
PF Walleye
UB White Sucker
WB White Sucker
UB White Sucker
WB White Sucker
WB White Sucker
BF Black Bullhead
WB White Sucker
WP Starry Flounder
WP Starry Flounder
WB Carp
WB Redhorse Sucker
WB White Sucker
WP BluegiU
WP BluegiU
WB Carp
PF Lm Bass
WB Black Redhorse
WB Black Redhorse
WB Spotted Sucker
WB Spotted Sucker
WB Carp
PF Lm Bass
WB Channel Catfish
WB Channel Catfish
WB Channel Catfish
WB Spotted Sucker
WB Carp
WB Carp
WB North Hogsucker
WB Golden Redhorse
PF Lm Bass
WB Carp
PF Rock Bass
WB Carp
WB Carp
PF Sauger
PF White Crappie
WB Channel Catfish
WP Southern Flounder
WP Summer Flounder
WB Carp
PF Lm Bass
WB Carp
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
16.7
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
12.2
88.8
87.4
16.0
0.58
23.19
72.8
NO
0.17
47.4
7.74
1.41
1.75
1.19
2.02
NO
NO
NO
NO
0.07
1.95
NO
1.83
NO
2.45
NO
1.73
1.30
0.74
0.96
NO
14.1
NO
1.70
2.13
NO
NO
570
NO
MO
4.64
NO
2.76
0.10
0.03
0.31
0.32
0.31
0 0.72
4.29
18.3
NO
0 0.35
2.08
0.65
0 0.56
D 0.14
0 0.10
0 0.36
0.10
0.47
0.43
0.48
0 0.36
0 0.50
0.23
0 1.50
0.40
D 0.53
0.10
0 NO
D 0.21
D NO
D 0.19
NO
0.32
0.31
D 0.279
0 1.19
0.52
0.31
4.43
0.24
0.12
2.61
0.57
0.99
D 363.9
0 51
D 669.98
D 646.07
D 5365.9
D 479.7
198.1
1697.5
525.54
D 82.01
1033.4
D 548.2
D 11.8
0 3.13
D 14.43
D 354.59
D 1.36
D 10.1
D 9.55
D 5.14
D 2.03
D 2803.4
D 293.6
0 485.52
D 2.54
D 170.6
D 21.72
67.37
D 63.79
NO
0 79.63
NO
D 1367.4
D 780.42
D 24118.2
D 1218.02
D 93.79
D NO
315.1
0 19.08
D NO
3309.2
D 32.02
D 1029.3
NO
NO
3.30
2.86
NO
NO
1.31
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
HO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
0.792
5.02
NO
NO
NO
NO
NO
10.4
NO
NO
NO
NO
1.08 0
0.61 D
4.43
NO
0 20.30
49.5 E
NO
NO
NO
NO
4.50
NO
1.10 0
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
1.98
NO
NO
NO
NO
NO
NO
NO
1.83
D 100 E
4.20
ND
NO
ND
ND
ND
26.5
NO
ND
3.40
3.00
61.8
58.9
403
ND
52.72
339
ND
ND
ND
25.5
NO
ND
ND
1.97
ND
ND
ND
ND
ND
20.9
ND
ND
ND
2.67
ND
ND
NO
NO
ND
ND
25.4
26.5
1754
13.8
ND
ND
37.2
ND
ND
28.3
NO
19.4
82.7
12.5
256
243
E 3153
19.2
44.07
E 690
47.1
5.71
299
237
ND
ND
NO
D 27.0
ND
ND
ND
NO
ND
298
21.6
10.3
ND
18.7
1.67
1.17
1.09
ND
3.13
ND
265
E 322
E 9934
167
3.29
ND
138
NO
ND
443
ND
154
139
18.3
172
169
E 1388
80.6
50.87
E 311
178
26.6
E 366
E 180
7.30
ND
5.81
98.6
ND
ND
ND
ND
ND
E 1140
110
97.9
ND
42.0
0 6.65
D 18.3
0 15.5
ND
22.5
ND
E 450
E 356
E 9872
E 393
25.1
ND
83.8
10.1
ND
E 1297
11.6
E 344
115
17.2
96.5
95.9
E 332
218
24.72
E 227
E 208
38.6
E 289
E 87.1
ND
3.13
7.52
E 151
1.36
10.1
9.55
4.22
2.03
E 1021
E 119
265
2.54
68.9
13.4
33.4
32.5
NO
38.9
ND
E 521
E 65.2
E 2061
E 456
47.9
ND
56.1
8.98
ND
E 1270
16.9
E 396
23.8
NO
47.4
47.7
E 68.1
139
4.11
E 72.3
E 63.8
11.1
E 74.9
E 18.6
ND
NO
ND
E 58.1
D ND
ND
ND
0.92
D ND
E 280
E 36.7
E 103
NO
E 23.9
ND
14.5
14.7
NO
15.1
ND
E 106
E 8.89
E 346
E 160
17.5
ND
ND
ND
ND
E 234
3.52
E 103
ND
NO
27.6
23.5
17.4
22.9
ND
8.73
22.1
ND
4.53
ND
ND
ND
ND
15.1
ND
ND
ND
D ND
NO
E 43.5
6.30
9.32
ND
9.71
NO
ND
ND
ND
ND
NO
E NO
ND
E 50.4
E 19
NO
ND
ND
ND
ND
E ND
ND
E 12.9
ND
NO
4.30
4.60
NO
NO
NO
NO
6.54
ND
ND
ND
ND
ND
ND
2.82
ND
ND
ND
ND
ND
ND
NO
ND
ND
2.74
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
D ND
D ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
NO
ND
ND
D ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
D-5-43
-------
Episode SCC Type Description
TRtFLUR PCA
BIPHENYL TOT
PCBS
XENOB10TICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
F UP Starry Flounder
Soft Shell Clams
F UP Starry Flounder
Soft Shell Clams
F PF Striped Bass
F UB Carp
F UB Chub
F UB Sucker
F UB Sucker
F UB Carp
F UB Carp
F UB Sucker
F UB Carp
Crayfish (whole)
F UB Sucker
F UB Sucker
F BF Catfish
3189 00092188 L UB Carp
3190 00015907 F UB Carp
3191 DJ024003
3191 DJ024005 M
3192 DJ024007
3192 DJ024009 M
3193 OC039001
3195 DH020104
3195 DH020105
3196 OH020108
3198 DH020111
3199 DH020101
3199 DH020103
3200 OH020112
3203 OJ024018
3205 DJ024024 0
3206 OJ024103
3208 DJ024109
3212 DJ024120
3212 OJ024121 F UB Carp
3213 DJ024123 F UB Squawfish
3215 DJ023705 F UB Sucker
3216 DJ023707 F PF Squawfish
3216 OJ023708 F UB Sucker
3216 00022388 L UB Sucker
3217 OJ023710 F UB Sucker
3218 DJ023711 PF Squawfish
3219 DJ023713 UB White Sturgeon
3219 DJ023714 PF White Sturgeon
3220 OJ023903 UB Bridgelip Sucker
3221 DJ023905 UB Sucker
3222 DJ023907 UB Sucker
3223 OJ023717 UP Starry Flounder
3224 OJ023715 N Soft Shell Clams
3226 OJ023721 M Pacific Oysters
3227 DJ023723 M Pacific Oysters
3231 DJ023910 F PF Sm Bass
3231 DJ023911 F UB Carp
3234 DH020301 F UP Squawfish
3235 DH020303 F UB White Sucker
3236 OH020305 F UB Largescale Sucker
3237 DH020308 F UB Largescale Sucker
3237 00080988 F UB Largescale Sucker
3238 DJ023918 F UP Dolly Varden
NO
NO
NO
NO
NO
NO
NO
ND
NO
ND
ND
20.0
NO
163
ND
ND
ND
20.5
64.8
153
NO
ND
NO
NO
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
7.16
ND
ND
ND
ND
NO
ND
4.48
1.07
NO
ND
ND
ND
0.91
0.58
1.48
ND
29.7
1.11
ND
3.11
2.13
ND
5.24
ND
E ND
ND
1.16
16.9
ND
0.92
1.32
2.49
NO
0.18
NO
6.74
ND
0.68
ND
ND
ND
ND
ND
ND
ND
12.5
8.55
0.35
0.33
NO
1.44
D 0.16
0.25
ND
0.21
0.11
D 0.35
0 3.64
0 4.59
0.51
8.85
D 0.27
0.21
1.04
D 3.41
0.09
7.33
0.59
0.33
0.79
D ND
0.79
0.06
D 0.73
0 1.09
D 0.70
0.06
D 0.31
NO
NO
1.47
D 0.20
ND
1.20
0.24
0.14
0.15
0.89
0.17
0.68
0.42
D 0.45
D 0.31
0.19
D 1389.3
D 541.5
D 8
ND
D 7.27
D 5.79
D 1064.3
382
516.9
0 31.29
256.6
0 64.24
D 23.47
D 80.09
2043.1
D ND
1536.9
0 31.12
D ND
D ND
102.74
0 722.01
D 37.1
D 127.9
D 173
D 8.2
D 55.6
D 190.84
23.91
174.72
0 265
D 92.36
10.46
D NO
D 2.51
D ND
D 2.89
D 330.9
D 33.3
D 22.01
D 202.12
D 741.17
D 683.21
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.93
ND
ND
ND
NO
1.32
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
2.34
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.79
ND
ND
ND
D 3.62
8.00
NO
NO
6.50
0 NO
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
NO
ND
NO
NO
ND
D ND
ND
ND
ND
ND
29.4
3.30
ND
ND
ND
ND
20.7
15.8
20.6
2.52
23.9
ND
ND
9.79
14.5
ND
NO
ND
NO
ND
0.98
4.91
ND
ND
ND
ND
ND
ND
ND
0.72
ND
0.63
ND
ND
ND
ND
ND
ND
ND
NO
ND
21.2
15.9
ND
206
75.4
NO
ND
ND
ND
456
40.4
73.1
3.35
59.6
ND
ND
7.60
208
ND
236
ND
ND
ND
0 9.86
149
NO
15.0
21.7
ND
ND
7.01
ND
D 41.3
11.7
D 24.9
ND
ND
ND
ND
ND
13.3
ND
ND
18.1
205
174
ND
E 484
E 166
3.30
NO
1.60
ND
E 420
111
152
6.72
81.2
24.1
8.36
31.5
E 890
ND
E 702
7.62
ND
ND
32.9
381
12.4
55.1
71.0
NO
20.8
57.9
4.97
67.1
129
37.5
2.50
ND
ND
ND
ND
73.5
14.0
14.9
105
E 311
E 291
NO
E 519
E 212
4.70
NO
0 5.67
NO
E 140
E 164
E 205
10.8
66.9
30.9
12.5
24.7
E 713
ND
E 502
23.5
ND
ND
45.5
E 160
19.8
57.8
68.6
8.20
29.7
E 95.4
15.4
55.1
107
25.3
7.98
ND
2.51
ND
2.89
163
19.3
4.77
E 72.5
E 197
E 195
ND
E 132
E 74.0
ND
ND
NO
ND
E 27.6
E 50.8
E 66.2
3.35
17.0
9.24
2.61
ND
E 186
ND
E 84.3
ND
ND
ND
13.5
27.1
4.90
ND
11.7
NO
5.10
E 29.3
3.54
10.5
17.3
4.03
ND
ND
ND
ND
NO
81.1
ND
ND
6.52
E 6.97
E 7.31
ND
E 18.9
10.8
ND
ND
ND
ND
ND
ND
ND
0 ND
ND
ND
ND
ND
E 30.3
ND
12.6
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.23
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
NO
NO
NO
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
D-5-44
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
OIPHEN HCBUT
01S
3241 DJ023924
3245 DJ023624
3246 DJ022109
3248 DJ022502
3248 00050588
3249 OJ022S03
3249 DJ022S04
3250 DJ022506
3252 DJ022509
3252 DJ022510
3252 00020989
3252 00052588
3256 DJ022518
3258 DC038901
3258 DC038902
3259 DB000466
3259 OB000473
3259 DB069101
3260 OB000493
3261 DY026002
3262 OY026004
3266 DY022701
3266 DY022702
3266 00012389
3267 DY022101
3267 DY022102
3270 OY022108
3271 DY022110
3272 DY022112
3273 DY022113
3273 DY022114
3274 OY022116
3276 DY022119
3278 DY022124
3281 DY022205
3282 OY022206
3282 DY022207
3283 DY022209
3285 DY022212
3285 DY022213
3286 DY022215
3287 OY022216
3288 DY022217
3288 DY022218
F UP Dolly Varden
F UP Flathead Sole
F UP Flathead Sole
F UB Composite Bottom
f UB not available
F PF Brook Trout
F UB Sucker
F UB Sucker
F PF Lm Bass
F UB Sucker
L PF Lm Bass
L UB Sucker
F UB Sucker
F PF Spot
F UB Croaker
F UB Goldfish
F PF Lm Bass
F UB Sucker
F UB Carp
F UB Striped Mullet
F UB Tilapia Tilapia
F PF Black Crappie
F UB Channel Catfish
L PF Black Crappie
F PF Rainbow Trout
f UB Sacramento Sucker
F UB Sucker
F UB Sucker
F WB White Surfperch
F UB Sculpin
F UB Surf Smelt
F UB Sculpin
F UB Walleye
F UB Sacramento Sucker
F UB Sucker
F PF Flathead Catfish
F UB Carp
F UB Carp
F UP Stingray
F UB Diamond Turbot
F UB Carp
F UB Tilapia Zilli
F PF Squawfish
F UB Sucker
NO
ND
NO
ND
ND
ND
ND
ND
ND
11.4
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
116
43.8
19.7
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
0.22
2.20
1.15
ND
NO
2.05
NO
ND
NO
ND
ND
ND
ND
0.56
0.62
ND
ND
0.54
ND
ND
ND
ND
NO
E ND
ND
NO
ND
ND
0.425
4.35
ND
ND
0.53
ND
0.18
0.83
ND
0.09
0.25
0.14
0.14
0.28
0.07
0.90
D 1.03
D 1.15
D 0.55
2.55
0.15
D 3.15
0.31
ND
ND
0.10
0.69
0.12
0.11
D ND
D ND
1.47
1.27
D 0.56
0.16
0.10
0.88
ND
0.45
0.25
0.57
0.95
0.33
ND
0.700
ND
0.15
1.09
0 142.92
131.56
D 17.4
D 56.3
112.32
D 1.27
D 563.8
0 313.6
D 1.38
D 182.29
D 3.18
D ND
D 53.9
D 629.76
D 486.4
82276.6
D 4539.4
124192
D 293.2
690.9
6.3
D ND
D 13.6
D NO
0 ND
3.75
34.9
D ND
D 126.72
D 25.21
D ND
D 76.21
D 4.98
121.8
0 4.47
D 6.1
D 16.79
D 41.42
D 725
60.3
199.63
61
D 59.37
D 70.4
NO
ND
ND
ND
ND
ND
NO
ND
NO
ND
NO
ND
NO
1.87
ND
235
4.41
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.69
ND
ND
ND
ND
ND
ND
ND
ND
1.99
ND
ND
1.10
ND
ND
ND
ND
3.90
ND
ND
ND
5.63
ND
E 1132
32.0
5072
ND
35.1
NO
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 5.02
NO
ND
NO
ND
ND
ND
ND
4.59
NO
ND
ND
8.85
10.6
E 4748
241
E 18344
20.3
29.9
NO
NO
ND
ND
NO
0.94
NO
ND
ND
NO
ND
ND
0.21
1.05
ND
ND
ND
ND
3.70
NO
8.00
2.30
ND
ND
2.72
10.1
NO
ND
1.62 D
ND
11.4
10.9
ND
61.4
ND
ND
ND
69.26
94.6 E
E 42685 E
1929 E
E 60764 E
141
97.3 E
ND
ND
ND
ND
ND
D ND
ND
ND
8.35
ND
ND
ND
D 1.64 0
D 23.2
NO
ND
ND
ND
78.5
ND
64.0 E
D 11.4
ND
ND
38.1 81.5
47.3 51.3
ND 13.0
20.4 21.3
22.1 70.1
ND 1.27
60.6 E 265
92.4 E 157
ND 1.38
71.2 41.2
0.80 D 2.38
ND ND
30.5 23.4
20.6
15.0
4.40
14.6
17.4
D ND
E 187
E 53.3
D ND
ND
D ND
ND
NO
215.80 251.35 73.36
192 E 155
23843 E 7513
1495 E 660
29578 E 8862
97.9 34.0
159 E 266
1.78 0 4.52
ND NO
NO 13.6
ND ND
ND NO
ND 2.81
17.9 17.0
ND ND
49.9 59.1
12.1 11.7
ND NO
8.31 47.7
2.62 0.51
50.1 42.4
2.02 0 2.45
1.51 D 4.59
5.88 7.22
ND 32.6
223 E 325
30.4 29.9
78.7 E 40.1
25.1 22.2
26.3 30.3
30.8 39.6
E 34.2
E 1663
E 137
E 1332
ND
E 92
ND
ND
NO
ND
ND
ND
ND
ND
9.37
1.41
ND
20.2
D ND
5.05
D ND
ND
ND
8.82
E 76.9
NO
8.83
NO
2.77
ND
ND
0.85
ND
ND
ND
ND
E 39.8
ND
ND
ND
ND
ND
ND
3.64
ND
E 369
41.0
177
ND
E 11.6
ND
NO
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
17.9
ND
NO
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
E 81.4
ND
63.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E 7.18
ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
D-5-45
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3289 DY022219 F WP Bocaccio
3289 DY022220 F WB Sculpin
3290 DY022221 F PF Redear Sunfish
3290 DY022222 F UB Blackfish
3294 DJ022111 F WP True Cod
3294 DJ022113 H Mussel
3295 DJ022114 F WP Atlantic Salmon
3296 DB040101 F WB White Sucker
3297 DB041501 F WB Carp
3298 OB041601 F WB Carp
3298 DB041604 F PF Lm Bass
3299 DB040601 F WB White Sucker
3299 DB040604 F PF Lm Bass
3299 00040601 L WB Sucker
3300 DB040201 F WB White Sucker
3300 DB040204 F PF Sm Bass
3300 00021389 L WB Channel Catfish
3301 DB041101 F WB Carp
3301 DB041104 F PF Northern Pike
3301 00030989 L PF Northern Pike
3302 DB041901 F WB White Sucker
3302 DB041904 F PF Lm Bass
3303 OB042301 F WB White Sucker
3303 DB042304 F PF Sm Bass
3303 00102588 L WB White Sucker
3304 OB041001 F PF Northern Pike
3304 DB041004 F W8 White Sucker
3304 00041004 L WB White Sucker
3305 OB042001 F WB Channel Catfish
3305 DB042004 F PF Sm Bass
3305 001 10388 L WB Channel Catfish
3306 DB041801 F WB White Sucker
3306 DB041804 F PF Sm Bass
3306 00041801 L WB White Sucker
3307 DB042101 WB White Sucker
3308 DB040001 PF Northern Pike
3309 DB041301 WB White Sucker
3310 DC032701 WB Bullhead
3310 DC032702 PF Walleye
3311 DC032801 F WB Redhorse Sucker
3311 DC032802 F PF Sm Bass
3312 DC033101 F WB Redhorse Sucker
3312 DC033102 F PF Sm Bass
3313 DC033201 F WB Redhorse Sucker
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
NO
0.31
64.2
ND
ND
NO
ND
ND
2.79
ND
ND
ND
ND
0.28
NO
ND
4.21
1.28
1.25
0.39
ND
ND
ND
ND
ND
1.31
2.89
ND
ND
ND
ND
ND
ND
ND
ND
1.93
1.23
1.08
1.37
0.37
3.08
1.59
0.62
0.45
1.14
0 0.19
1.55
0.51
0.30
0.07
0.17
0.73
1.68
0.14
0.60
0.42
0.24
0 0.13
0.21
0.25
12.1
D 0.18
0 0.13
D 1.41
0.11
0.30
0.20
0.81
0.09
0 0.46
0.64
1.48
0.13
1.56
0.43
0.20
0.50
0.47
0.12
D 0.37
D 1.70
D 1.63
D 0.15
D 0.24
0.33
D 1.24
D 0.21
D 35.5
D 90.57
0 6.62
D 1217.4
D 16.31
D 2.12
D 23.84
D 579.63
D 754.3
D 3029.4
D 126.25
D 6345.8
D 610.32
0 4057
D 1896.2
D 205.47
D 160.97
9305.9
D 399.86
D 474.21
D 2561.8
D 93.6
D 6055.6
D 755.66
0 8371
D 127.2
0 4770.98
D 8811.7
D 5579.1
D 85.83
D 5562.9
D 7435.9
D 3172.03
D 12027
D 488.7
0 ND
D 62.47
D 372.6
D 101.01
D 285.95
D 83.22
D 741.47
D 250.37
D 326.61
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
4.26
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
2.00
1.27
5.55
NO
NO
ND
ND
ND
ND
0.18
ND
1.14
ND
ND
ND
ND
ND
ND
0.06
ND
ND
ND
45.6
ND
109
3.62
24.0
NO
ND
ND
46.7
5.16
4.81
ND
ND
17.1
0.86
31.2
NO
5.98
16.1
10.5
ND
6.26
D 146
52.3
249
ND
ND
ND
ND
2.40
ND
0.63
ND
1.88
ND
ND
2.08
NO
12.1
ND
D 0.32
ND
14.4
42.3
243
1.75
E 437
43.7
E 160
16.1
ND
1.62
1163
60.5
68.6
30.8
ND
879
D 65.0
1302
ND
162
364
116
1.81
105
E 698
E 279
E 1122
3.20
ND
ND
19.5
D 16.9
6.55
D 2.75
6.77
D 5.94
0.61
2.76
D 17.6
ND
199
ND
D 0.88
ND
109
300
E 1006
D 24.5
E 2478
E 247
E 1246
331
32.6
D 27.6
E 4133
E 175
E 207
407
14.3
E 3813
E 460
E 5619
29.0
E 1526
E 3170
1154
22.9
1034
E 2477
E 1127
E 4490
77.6
ND
2.97
62.8
29.6
35.6
14.89
95.6
42.23
D 20.8
13.8
39.5
2.41
E 505
6.86
D 0.86
8.87
E 182
E 260
E 791
40.7
E 1901
E 193
E 1401
E 619
69.6
53.9
E 2256
E 98.8
E 119
E 926
36.0
E 1076
E 183
E 1106
50.8
E 1823
E 3316
E 1989
32.9
E 1925
E 2064
E 835
E 3174
E 169
ND
29.3
153
40.9
81.4
25.30
E 254
84.98
116
15.8
29.3
D 4.21
E 412
9.45
D ND
13.4
E 208
E 125
£ 668
43.0
E 1083
E 97.5
E 887
E 622
E 75.1
E 56.9
E 1313
E 50.2
E 62.5
E 910
35.5
E 206
E 35.9
E 243
E 39.2
E 1013
E 1634
E 1635
22.5
E 1735
E 1280
E 546
E 1890
E 172
ND
27.0
E 107
6.27
E 110
29.97
E 279
86.64
E 141
3.14
2.09
ND
E 84.7
ND
ND
1.57
E 60.9
27.0
E 246
16.3
E 311
E 25.5
E 300
E 258
E 26.3
E 19.8
E 357
10.2
E 12.3
E 262
7.80
E 52.0
10.9
E 56.2
8.20
E 211
E 286
E 580
5.72
E 621
E 586
E 261
E 880
E 55.4
ND
3.20
E 30.3
4.94
E 44.3
9.07
E 93.7
25.04
E 37.8
NO
D ND
ND
4.60
ND
ND
D ND
5.33
ND
E 29.8
ND
E 22.5
ND
E 39.0
E 47.4
1.87
1.15
E 37.2
NO
ND
E 26.0
ND
12.5
ND
13.6
ND
E 30.0
E 25.6
E 94.6
NO
E 126
E 168
E 65.7
E 203
11.5
ND
ND
ND
ND
8.10
0.43
E 12.4
2.52
10.4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
2.72
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
10.6
E 14.9
4.76
E 13.5
ND
ND
ND
ND
ND
ND
D ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
1.84
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.36
ND
ND
ND
ND
D-5-46
-------
Episode SCO Type Description
TRIFLUR PCA
B1PHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3313 DC033202 F PF Sm Bass
3314 DC033301 F WB Channel Catfish
3314 OC033302 F PF White Bass
3315 DC033401 F WB Carp
3315 DC033402 F PF Im Bass
3316 DC033501 F WB White Sucker
3317 DC033601 F WB White Sucker
3318 DC033701 F WB White Sucker
3319 DB041401 F WP Winter Flounder
3320 DB041412 F WP Bluefish
3321 DB040401 F WP Winter Flounder
3321 00100688 L WP Winter Flounder
3323 DB041206 F WP Winter Flounder
3324 DB041252 F WP Bluefish
3325 OB041218 F WP Bluefish
3326 DB041208 F WP Bluefish
3327 08040301 F WP Bluefish
3327 DB040315 F WP Bluefish
3328 00029111 F WB Carp
3329 00016003 F WB Boufin
3330 00029110 F WB Spotted Sucker
3331 00016007 WB Carp
3332 00016009 WP Spotted Drum
3333 00016012 WB Sea Catfish
3334 00016013 WB Sea Catfish
3335 00016015 WP Spot
3335 00029101 WP Red Drum
3335 00029102 WB Southern Flounder
3335 00029103 WP Sheepshead
3335 00091588 L WP Red Drum
3336 00016004 F WP Black Drum
3336 00016006 F WP Sheepshead
3336 00016017
3336 00016018
3337 00016019
3338 00016022
3339 00016023
3340 00029114
3341 00016104
WP Red Drum
F PF Spotted Seatrout
F WB Spotted Sucker
F WB Spotted Sucker
F WB Carp
F WB Channel Catfish
F WB Catfish
3341 00081788 L WB Catfish
3342 DD016105 F WB Spotted Sucker
3343 00016107 F WB White Sucker
3344 00016109 F WB Carp
3345 00016111 F WB Redhorse Sucker
NO
NO
NO
NO
NO
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.07
ND
ND
ND
NO
ND
NO
ND
ND
7.77
0.78
ND
ND
0.46
1.78
1.50
ND
ND
1.29
1.23
0.45
1.67
ND
0.35
ND
0.63
0.67
8.11
2.32
0.85
ND
ND
1.34
11.7
1.99
1.17
1.79
0.82
ND
ND
ND
ND
1.45
121
0.65
8.90
0.75
0.56
12.5
8.28
4.67
1.49
0.42
1.95
D 0.76
0.18
0.19
D 0.32
D 4.93
D 1.53
0.14
0.70
D 0.35
D 1.28
D 0.07
D 0.48
0.08
D 0.19
2.37
0.65
D 0.67
1.05
D 1.47
D 0.28
0.85
0.39
D 2.95
1.83
D 0.67
D 0.43
D 0.74
D 0.31
3.34
0.42
0.06
0.23
D 1.33
E 2.30
D 0.67
2.38
D 5.30
D 5.89
13.8
0.93
1.01
D 0.80
D 24.98
D 3201.5
D 502.84
D 65.9
D 4.58
D 1783.5
6.38
D 51.5
D 129.77
D 279.73
D 312
D 303.09
D 227.46
D 411.27
D 184.81
D 394.07
D 628.2
D 1319.2
D 3305.7
D 26.3
D 144.85
D 144.3
0 12.3
D 89.57
1066.2
D 344
D 522.57
D 48.98
D 1327.8
D 611.44
37.48
0 210.12
D 15.67
D 15.25
D 41.47
D 429.25
D 757.1
D 78.66
456.67
439.4
132.8
D 16.27
D 1444.3
D 86.21
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
3.35
ND
ND
ND
ND
ND
ND
ND
ND
0.23
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.01
ND
ND
0.91
ND
ND
ND
ND
ND
ND
0.24
ND
ND
ND
ND
ND
ND
19.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 1.46
37.3
4.39
ND
ND
0.59
NO
ND
3.92
2.73
12.0
7.79
3.96
9.77
2.74
6.77
17.6
79.4
27.0
1.50
D 5.37
ND
ND
ND
17.6
ND
1.88
D 0.83
ND
ND
2.12
ND
ND
ND
ND
20.8
13.9
11.6
ND
ND
ND
ND
7.19
ND
D 10.01
403
62.2
11.6
ND
D 187
ND
3.68
28.0
43.2
64.8
62.8
45.4
95.5
38.8
87.2
164
493
368
6.41
22.9
ND
ND
1.77
14.7
ND
0 14.4
D 4.62
8.60
2.31
D ND
3.22
ND
ND
2.98
90.7
173
9.07
51.2
47.3
21.2
ND
71.6
3.11
11.49
E 1261
E 188
27.1
1.11
E 1019
6.38
27.3
53.2
111
E 113
113
88.3
E 157
84.0
E 161
E 221
395
E 987
8.73
54.1
30.5
ND
D 25.9
138
22.0
22.2
6.91
27.4
0 7.73
ND
28.6
4.49
2.55
5.27
E 142
E 218
24.6
114
104
64.2
12.0
E 249
23.2
1.79
E 1229
E 192
22.2
D 3.47
E 517
ND
16.9
E 38.9
E 108
E 100
98.5
E 77.6
E 122
E 51.9
f. 121
E 186
E 275
E 1371
9.66
E 52.3
90.0
12.3
51.1
E 539
45.8
39.9
5.46
70.3
28.5
3.88
82.5
9.29
8.81
12.6
E 146
E 251
25.9
E 227
E 219
47.4
4.27
E 322
44.4
D ND
E 260
E 51.9
5.00
ND
E 52.7
ND
3.62
5.75
E 14.8
E 22.2
21.0
E 12.2
E 27.0
E 7.37
E 18.1
E 39.6
62.2
E 439
NO
E 8.71
23.8
ND
10.8
E 259
64.8
97.7
17.14
186
98.7
4.28
E 51.1
1.89
3.89
1.62
E 26.4
E 88.8
7.49
E 57.8
E 58.5
ND
ND
E 192
15.5
ND
E 11.2
4.35
ND
ND
7.25
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
11.6
E 96.3
ND
0.56 D
ND
ND
ND
E 79.1
150
E 239 E
13.78
E 593 E
E 327 E
14.4
30.0
D ND
ND
D ND
ND
12.4
ND
6.67
10.6
NO
ND
E 379 E
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
17.4
ND
ND
ND
ND
ND
18.8
61.4
102
ND
413
135
12.8
14.7
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
207
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
E ND
ND
ND
ND
ND
ND
ND
E ND
E 5.49
ND
E 29.5
E 12.2
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
E 16.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.24
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
2.50
ND
D ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
D-5-47
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOB10TICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3346 D0016113 F WB Creek Chubsucker
3346 000161 H
3347 D0016115
3348 00016117
3348 00016118
3349 00016119
3350 00016121
33SO 00016122
3351 00016124
3352 DF023723
3352 DF023724
3352 00022089
3353 DF024121
3353 DF024122
3354 DY022301
3354 OY022302
3355 DY022303
3355 OY022304
3356 DE030201
3357 DY022224
3360 00029117
3375 00016305
3375 00016306
3375 00071189
3376 00016307
3376 DD016308
3377 00016309
3377 DD016310
3378 00016311
3378 00029115
3385 DD016401
3385 00101888
3395 00016421
3401 OD016509
3401 00016510
3403 00016513
3403 00016514
3404 00016515
3404 00016515
3409 08040701
3409 DB040706
3411 OB040501
3412 DB040901
3412 DB040907
PF Lm Bass
WB Carp
PF White Perch
WB Blue Catfish
WB Carp
WB Carp
PF Lm Bass
WB Carp
PF Crappie
WB Carp
PF Crappie
BF Blue Catfish
WB Sm Buffalo
WB Carp
PF Lm Bass
WB Carp
PF Lm Bass
WB Carp
WB Sacramento Sucker
WB Carp
WB Carp
PF Lm Bass
PF Lm Bass
WB Carp
PF Lm Bass
WB Carp
PF Lm Bass
WB Spotted Sucker
WB Greyfin Sucker
WB Redhorse Sucker
B not available
WB Redhorse Sucker
WB Carp
PF Lm Bass
WB River Carpsucker
PF Lm Bass
WB Carp
WB Carp
WB Carp
PF Lm Bass
WB Redhorse Sucker
PF Sm Bass
WB Carp
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
10.9
NO
40.3
3.21
NO
NO
26.8
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
3.40
NO
NO
NO
NO
NO
ND
NO
ND
ND
ND
1.44
ND
14.7
0.28
2.82
6.17
ND
ND
3.18
ND
0.29
ND
0.57
5.95
18.4
ND
21.9
ND
2.00
1.43
16.4
647
9.70
14.45
334
3.09
187
1.82
1.56
4.14
1.21
1.09
9.59
1.67
ND
27.7
0.36
ND
0.59
1.92
ND
13.0
ND
NO
0 ND
0.10
2.16
0 0.26
0.18
0.10
0.51
0.24
0.68
0.14
D 0.19
0.18
D 0.34
0.29
0.96
0.14
2.37
0.13
D 26.4
D 0.35
0.51
E 15.3
0.52
0.80
E 1.92
0.15
0.90
D 0.30
0 0.52
4.20
D 0.60
D 0.44
0.73
D 1.07
0.17
70.6
D 3.66
ND
0 0.29
D 0.60
0.73
12.0
0.22
0.69
74.65
D NO
D 1935.1
D 6.04
D 38.22
D 550.06
D 569.5
D 34.07
D 1085.9
D ND
D 22.79
D ND
D 20.31
D 213
D 311.95
0 25.58
0 1950.8
D 113.45
6819.1
D 270.38
D 843.09
2847
D 60.38
D 176.6
D 3030.3
D 53.77
D 6061.6
D 137.95
D 89
4.51
D 182.43
D 191.77
D 926.8
D 1116.6
D 29.66
E 2528.3
80.05
332.4
0 414.96
D 14323.3
0 256.9
207.43
D 274.7
D 3784.99
1.44
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
3.55
ND
ND
ND
1.14
3.06
ND
0.15
7.56
0.87
NO
ND
ND
ND
ND
ND
ND
0.86
ND
ND
ND
ND
ND
ND
NO
ND
0 20.2
NO
2.38
ND
0.81
NO
ND
ND
ND
ND
1.17
ND
ND
ND
ND
NO
0.60
ND
24.9
ND
ND
45.0
D 6.53
16.43
5.77
0 1.44
ND
D 3.32
ND
ND
NO
ND
ND
ND
ND
D ND
ND
ND
NO
8.00
ND
ND
ND
ND
17.8
ND
32.2
ND
D 2.63
2.56
ND
ND
2.35
ND
D 9.26
ND
NO
10.8
6.15
NO
D 11.2
NO
786
2.48
4.09
258
22.10
63.15
73.1
D 9.73
104
31.83
5.70
4.51
0.63
ND
ND
2.63
ND
2.76
1.71
ND
1.16
1007
20.3
14.0
ND
3.90
10.6 16.3 8.31
ND ND NO
E 335 E 503 E 720
ND 2.56 3.48
7.41 8.07 14.2
53.3 162 E 229
67.0 226 E 240
ND 10.8 18.3
D 92.0 353 E 456
ND ND ND
2.42 0 2.45 D 7.49
ND ND ND
1.08 D 6.22 10.1
49.7 61.5 74.2
65.3 148 E 79.5
2.22 0 11.2 10.8
184 600 E 811
2.35 D 20.9 59.7
E 3517 E 1649 E 618
D 41.6 98.1 105
99.0 E 253 E 364
E 799 E 756 E 747
14.28 12.24 4.09
44.09 37.55 11.64
508 E 820 E 1042
13.19 19.64 8.14
E 1171 E 1960 E 2102
36.23 45.39 17.18
16.3 30.1 36.9
ND ND ND
D 16.2 77.3 E 76.5
21.2 91.8 E 72.2
29.8 206 E 457
66.9 293 E 643
ND 8.10 19.4
156 E 436 E 1515
6.27 21.7 44.3
26.4 81.0 E 142
D 28.9 100 E 188
E 6345 E 4164 E 2225
118 E 83.4 E 35.2
62.5 75.3 46.0
35.2 92.3 E 109
440 E 1397 E 1340
NO
ND
E 289
ND
5.10
E 86.0
E 36.5
4.97
E 158
ND
NO
NO
2.91
16.8
13.0
1.36
E 296
E 29.2
E 190
23.2
E 123
E 242
NO
0.68
E 490
1.48
E 717
3.13
NO
ND
E 11.8
E 6.57
E 194
E 106
2.16
E 335
6.07
E 68.2
E 80.8
E 475
ND
9.63
E 38.2
E 495
ND
ND
E 53.5
ND
ND
E 17.2
NO
NO
24.6
ND
ND
ND
0 ND
ND
ND
D ND
E 48.0
1.30
E 30.7
ND
ND
ND
NO
0 ND
E 91.4
D ND
E ND
ND
ND
NO
ND
ND
E 40.0
5.10
D ND
E 76.3
ND
14.8
16.1
E 87.3
ND
ND
NO
E 84.3
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
6.38
ND
NO
ND
12.0
ND
ND
ND
9.19
ND
ND
NO
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
NO
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
15.6
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
NO
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
NO
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
D-S-48
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3414 DC036203
34 H DC036204
3415 DC036205
3415 DC036206
3419 DC036207
3419 DC036208
3420 DC036209
3420 DC036210
3421 OC036211
3421 DC036212
3422 DC036213
3422 DC036214
3423 DC036216
3424 DC036218
3425 DF025005
3426 DB069102
3427 OB069103
3428 DB069104
3429 DB069105 1
3430 DB069106 1
3431 DB069109 1
3433 DB069112 1
3434 DB040801 1
3434 00011889 L
3435 DDO 16602 1
3444 DD016603
3444 DD016604
3444 DD029512
3445 DD029513
3446 DDO 16605
3446 DD016606
3446 00091889
PF Sm Bass
BF Channel Catfish
PF Sm Bass
BF Channel Catfish
UB White Sucker
PF Freshwater Drum
PF Greenfish
UB Carp
PF White Perch
UB Carp
PF Lm Bass
UB Yellow Bullhead
UB White Catfish
UB White Catfish
UB Carp
PF Bluefish
PF Bluefish
PF Bluefish
' PF Ueakfish
UB White Catfish
" WB Red Snapper
UP Flounder
' UP Flounder
. UP Flounder
UB Bigmouth Buffalo
UB Carp
BF Channel Catfish
PF Lm Bass
UB Flounder
PF Striped Bass
UB Carpsucker
UB Carpsucker
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
21.8
13.4
ND
ND
ND
ND
ND
ND
2.99
ND
2.53
ND
ND
10.54
12.3
0.33
2.92
0.77
ND
1.10
0.86
ND
0.16
ND
ND
ND
ND
ND
0.57
0.56
0.77
85.1
57.3
48.6
1.82
ND
ND
ND
1.19
0.23
2.70
0.60
1.62
0.15
ND
0.13
0.95
D 0.21
2.22
D 0.23
0.09
D 0.14
D 0.13
0.44
D 0.28
0.31
ND
0.12
0.17
0.34
D 0.60
D 0.41
D 0.98
7.11
2.77
1.44
D 0.22
0.44
0.28
0.62
D 0.47
D 142.6
D 586.95
D 102.21
D 1075.2
D 305.08
117.92
D 82.35
D 324.5
D ND
D 33.99
D ND
D 13.25
D 693.9
D 76.4
D 187.07
D 213.34
D 193.05
697.8
D 16.98
D 107.04
D 231.18
D 485.37
D 759.78
D 1082.5
593.6
D 406.32
D 470.16
D 145.96
D 18.57
D 740.97
D 504.47
D 529.22
ND
NO
NO
ND
0.41
ND
1.03
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.01
3.49
ND
ND
0.65
ND
ND
ND
ND
ND
ND
D 3.12
ND
2.98
5.51
ND
6.92
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.93
10.1
4.51
3.89
5.74
0.37
0.90
ND
ND
ND
3.85
ND
17.8
41.50
5.59
3.22
7.99
ND
2.47
ND
ND
ND
ND
1.37
5.64
6.93
24.4
ND
ND
2.05
20.9
39.3
D 83.5
73.0
22.6
15.5
39.1
D 1.33
D 3.16
4.36
18.5
11.8
79.5
2.20
99.3
43.2 64.4 E 23.2
158 E 257 E 88.6
D 22.1 51.4 E 25.1
230 E 480 E 219
116.65E 117.16E 26.24 ND
29.62
13.60
65.0
ND
D ND
ND
ND
17.0
ND
D 17.4
49.6
47.4
246
ND
5.74
D 18.6
122
E 240
E 410
172
112
107
50.2
D 5.53
54.9
68.8
70.1
57.09 22.05 3.57
22.73 28.39 9.91
132 E 93.3 E 20.7
ND ND ND
24.6 ND ND
ND ND ND
1.97 D 8.99 2.29
111 E 334 E 196
15.4 43.8 17.2
33.8 77.2 44.9
81.2 E 66.5 E 10.4
73.0 E 57.2 8.52
E 260 E 151 E 16.4
5.08 11.9 ND
28.7 54.8 E 17.8
48.8 118 E 40.8
E 154 E 139 E 42.3
E 264 E 175 E 39.6
E 357 E 203 E 28.1
189 129 20.5
127 102 36.2
E 152 E 130 E 49.5
39.7 10.4 0.82
8.60 2.74 D ND
E 219 E 306 E 124
E 146 E 192 E 74.5
E 150 E 195 E 74.9
ND
ND
1.41
E 29.1
ND
ND
0.49
ND
ND
ND
ND
D ND
E 35.9
ND
12.4
ND
ND
ND
ND
ND
2.93
7.17
1.88
ND
ND
ND
8.78
D ND
ND
E 27.6
E 15.5
E 17.1
ND
ND
D ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
3.79
2.51
2.72
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.97
D 0.80
E 0.90
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
D ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D-S-49
-------
£-5-50
-------
APPENDIX D-6
Information on Fish Samples
-------
Key to Table D-6
FISH AND SHELLFISH SAMPLE INFORMATION
Episode Number
SCC Number
Dioxin/Furan Analyses
Percent Lipid Content
Wet Weight of Sample Analyzed
Xenobiotic Analyses
Percent Lipid Content
Wet Weight of Sample Analyzed
Number of Fish Used to Make Composite Sample
Date Sample Collected
Kev
NA = Not Available
NM = Not Measured
D-6-1
-------
D-6-2
-------
Episode
No.
1994
1994
1994
1998
1998
2015
2015
2016
2016
2017
2017
2018
2023
2023
2026
2026
2026
2027
2027
2037
2037
2056
2057
2059
2060
2070
2070
2070
2098
2098
2100
2100
2100
2105
2105
2105
2109
2109
2110
2122
2122
2126
2126
2126
2133
2138
2138
2139
2139
2139
2142
2142
2148
2148
2151
2151
2152
2152
2190
2190
2191
2191
2191
2194
2194
2199
2199
sec
No.
DE017702
DE017703
00110586
13285
13421
DF001001
DF001002
DF001101
DF001102
DF001201
DF001202
DF001301
OF001402
DF001403
DF001702
DF001703
DF001706
DF001802
DF001803
DY000501
DY000502
DE000501
DE000601
DE000801
OE000901
OJ 000901
DJ 000902
QD072186
DH001501
DH001504
DH001702
DH001703
00111086
DH002201
OH002204
00063086
OH002601
DH002602
DH002710
OH003901
DH003904
DD000302
DD000303
00062686
DD001002
DD001501
DD001504
DD001601
DD001604
00071486
OD001902
OD001903
D0002501
OD002504
DD002801
DD002803
D0002902
DD002903
DG005101
DG005104
DG005205
DG005206
00092486
DG005501
OG005504
DG006001
OG006004
Dioxi
Xlipi
MM
NM
NM
NM
NM
5.8
3.5
3.5
1.8
NM
NM
NM
NM
NM
5
NM
NM
NM
NM
NM
NM
NM
13
13.3
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
4.4
NM
NM
NM
NM
NM
NM
3.2
NM
3.2
NM
NM
NM
0.9
NM
NM
3.8
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
2.6
NM
NM
wet weight
(g)
19.98
20
20.01
20.02
19.92
20.09
20.07
19.98
20.06
19.95
20.12
20.01
20
20
20
5.67
NM
20.02
20.1
19.98
20.09
20.06
20.06
20.02
20.07
20.05
20.01
20.04
19.99
20
20.04
19.97
20.04
20.09
20
20.12
20.06
20
20.06
19.88
20.03
20.04
20.04
20.01
20
20.01
20.22
20
20.02
20.02
20
20.06
19.91
19.99
19.93
19.98
20
20.3
19.98
20.02
20.07
20
19.96
19.93
20.07
19.95
20.03
Xenobiotics
Xlipid wet weight
(9)
NM
NM
NM
NM
NM
9.2
NM
7
NM
10.5
NM
3
NM
1.1
7.6
NM
NM
NM
9.7
7
NM
11.2
15.2
17.4
12.9
NM
4.6
NM
6.8
NM
NM
12.7
NM
NM
3.1
NM
12.5
NM
2.4
NM
7.7
4.9
NM
NM
2.1
NM
NM
8.2
NM
NM
4.9
NM
4.8
NM
NM
6.2
NM
10.2
4.8
1
21.1
NM
NM
9.1
NM
10.2
2.1
NM
NM
NM
NM
NM
20.01
NM
19.98
NM
20.09
NM
20.09
NM
19.98
20
NM
NM
NM
20.01
20.04
NM
20.04
20.03
20.01
20.21
NM
20.18
NM
20.15
NM
NM
19.98
NM
NM
20.09
NM
20
NM
17.33
NM
20.07
20.12
NM
NM
20.05
NM
NM
20.04
NM
NM
20
NM
20.07
NM
NM
20.04
NM
20.13
20.06
20.16
20.11
NM
NM
20.14
NM
20.06
19.99
No. of
Samples in
Composite
NA
NA
NA
NA
NA
03
03
01
01
01
01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
04
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
01
01
NA
NA
NA
01
01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Sampling
Date
850617
850617
850617
830527
830527
841117
841117
850522
850522
850531
850531
850309
840722
840722
840905
840905
840905
840816
840816
840801
840801
840808
841017
841009
841016
840820
840820
840820
841004
841004
840920
840920
840920
841004
841004
841004
840906
840906
840913
841017
841017
841002
841002
841002
841114
841023
841023
841017
841017
841017
840918
840918
840725
840725
841030
841030
840918
840918
840807
840807
841009
841009
841009
840906
840906
840911
840911
D-6-3
-------
Episode SCC
No.
2201
2201
2205
2205
2210
2211
2212
2212
2215
2216
2216
2220
2220
2225
2225
2225
2227
2227
2228
2228
2228
2231
2246
2246
2247
2247
2280
2280
2280
2280
2283
2283
2290
2290
2294
2294
2297
2297
2298
2298
2301
2301
2301
2301
2301
2302
2304
2304
2309
2309
2322
2322
2322
2326
2326
2328
2329
2341
2341
2355
2356
2356
2358
2369
2369
2369
2375
No.
DG006201
DG006204
DG006601
DG006602
DC005401
DC005503
DC005602
DC005605
DC005902
DC006002
DC006003
DC006401
DC006405
DC006902
OC006903
00101387
DC007102
DC007104
DC007201
OC007204
00070286
DC007503
OJ002301
DJ002302
DJ002403
DJ002404
DF005201
DF005204
00062386
00121688
DF005501
DF005502
DD003402
00003403
DD003801
00003804
00004102
DD004103
00004201
D0004203
00004501
DD004502
00004503
00004504
00071786
00004601
DD004801
DD004804
00005301
00005304
DB001301
DB001304
00082686
DB001701
DB001704
DB001904
DB002004
00006002
00006003
DA001603
DA001702
DA001703
OA001901
DA003202
DA003203
00030387
OA003802
Dioxin/Furans
Xlipid
NM
NM
NM
NM
10.9
4.8
NM
NM
NM
NM
NM
NM
NM
1.2
31.9
25.7
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
10.4
NM
4.1
3.2
9.5
3.7
1
16.6
2.8
NM
NM
NM
NM
NM
2.2
15.5
3.8
NM
NM
4
NM
NM
NM
NM
NM
NM
2.8
8.8
10.9
NM
NM
NM
NM
16
12.6
NM
wet weig
20
20
20.03
20.01
20.06
19.98
20
20.04
20
20.08
20.04
20.06
19.99
19.96
20.15
20.05
20.43
20.1
20.03
19.98
20.01
20.01
20.02
20.05
20.01
20.07
20.1
18.98
19.97
NM
20.02
20.18
NM
20.3
20.09
19.95
20.14
20.01
18.83
20.1
NM
NM
NM
20.02
20.02
20.11
19.89
20.03
20.13
20.21
20.06
20.16
20.11
20.05
20.05
20.08
20.01
20
20.08
20.1
20.05
19.96
4.75
20.01
20.1
20.02
20.02
Xenobiotics
Xlipid wet weight
(9)
9.7
NM
5.1
NM
13.5
3.9
1.8
7.7
10.5
NM
4.8
NM
8.9
NM
NM
NM
NM
8.6
0.4
NM
NM
18.6
NM
7.2
NM
5.5
2.6
NM
NM
3.1
6.3
NM
NM
15
NM
9.9
2.1
NM
NM
1.5
NM
NM
NM
2.1
NM
3.3
15.5
NM
3.6
NM
2.9
NM
NM
7.1
NM
4.2
11.9
NM
10.3
10.2
0.6
NM
NM
NM
NM
NM
NM
19.98
NM
20
NM
20.04
20.17
20.04
20.1
20.03
NM
19.99
NM
19.99
NM
NM
NM
NM
19.94
20.13
NM
NM
20.11
NM
19.97
NM
20.06
20.04
MM
NM
20.06
20.03
NM
KM
20
NH
19.97
20.11
NH
NH
20.08
NM
NH
NH
20
NM
20.06
20.04
NH
19.99
NH
19.94
NH
NH
20.04
NH
20.01
20.05
NM
20.11
20.14
20.09
NM
NM
NM
NM
NM
NM
No. Of
Samples in
Composite
NA
NA
NA
NA
NA
01
NA
NA
NA
NA
NA
06
03
OS
03
03
03
02
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
01
01
01
01
01
01
NA
NA
NA
NA
NA
NA
NA
02
01
03
NA
NA
NA
NA
NA
NA
NA
NA
NA
01
01
01
NA
NA
NA
NA
NA
NA
NA
Sampling
Date
840919
840919
841027
841027
840829
1984
1984
1984
1984
1984
1984
840920
840920
840906
840906
840906
840817
840817
840809
840809
840809
850918
840918
840918
840919
840919
8SOS07
8SOS07
850507
850507
841120
841120
841127
841127
850422
850422
841128
841128
850410
850410
850116
850116
850116
850116
850116
841101
841102
841102
841026
841026
840919
840919
840919
840926
840926
840918
840919
850423
840726
840814
840805
840805
840723
840917
840917
840917
840828
D-6-4
-------
Episode SCC
Ho. Ho.
Dioxin/Furans
Xlipid wet weight
(g)
Xenobiotics
XHpid wet weight
(9)
2375
2376
2376
2379
2379
2380
2383
2385
2385
2387
2387
2394
2394
2394
2397
2397
2410
2410
2416
2422
2427
2427
2427
2429
2429
2429
2430
2430
2430
2431
2431
2432
2432
2435
2435
2437
2437
2439
2439
2478
2478
2478
2500
2500
2532
2532
2544
2544
2608
2608
2618
2618
2618
2618
2651
2653
2654
2709
2721
2721
2722
2725
2748
2748
2776
2776
2776
OA003803
DA003903
OD111886
OE005401
DE005404
DE005501
DE005801
DE006002
00101987
DE006201
DE006204
DE006901
00006901
00022189
DE007201
DE007204
DE008501
DE008504
DE009101
DE009702
DE010202
DE010203
OD 102887
DE010402
DE010403
00010637
DEO 10602
DE010603
00121488
DE010702
DE010703
DEO 10710
DE010713
DE011001
DE011004
DE011202
DEO 11 203
DE011401
DE011402
DJ003901
DJ003902
DJ003903
DC010201
DC010203
DF019302
OF019303
DFO 19202
DF019203
OE014501
OE014504
DE015401
DE015402
OE015403
00102088
D8008401
DB008503
DB008601
DB005101
DA006502
0001 1089
DA006601
DA006301
DY006505
DY006506
DY007101
DY007103
ODO 10489
7.4
HH
NM
NM
HM
HH
HM
4
4.1
8.5
NM
10.8
HM
NM
NH
NM
HM
3.1
NM
11.2
24.4
1.9
1.7
NM
NM
NM
1.4
HM
NH
5.6
3.2
NM
NM
HM
NM
NM
NM
HM
HM
NM
NH
NM
NM
NM
2.3
10.8
NM
NM
1.7
21.5
14.7
5.9
8.9
8.8
7.6
3.9
NM
NM
6.2
HH
NH
6.3
NH
NH
2.6
HH
NH
20.09
19.95
20.03
NM
20.02
20.03
20.02
20
20.03
19.98
NM
20.02
NM
NH
20.05
20
20.07
20.08
20.09
20.04
20.12
20.59
20.06
19.98
20.06
20.05
20.06
19.92
NM
20.07
20.05
20.75
20.11
20
20.93
20.47
20.16
20
20.03
20.01
20.07
NM
20.11
20
20.18
20.37
20.02
NM
20.07
20.09
20.1
19.99
20
20.04
20.02
20.48
20.01
20
20.27
NM
20.04
20.05
20.02
20.04
20.02
20.01
NM
6.8
5.3
HH
NM
0.6
15.8
16.9
3.7
NM
NM
NM
14
12.9
11.4
5.7
NM
23.8
1.5
21.1
13.7
29.1
NM
NM
17.1
NM
NM
HM
5.1
4.7
NN
3.4
8.9
NM
5.9
NM
NM
17.9
16.2
7.1
NM
3.3
NM
NM
3.2
NM
11.4
10.5
NM
NM
22.5
20.4
6.3
12
NM
3.1
3.4
7.3
9.3
6.3
6.2
2.2
7.2
6.3
NM
2.6
NM
2.6
20.01
20.06
NH
NM
20.07
20.12
20.03
20.09
NM
NM
NM
20.15
20.05
20.09
20.11
HM
19.99
20.09
19.99
20.03
20.11
NH
NM
20.1
NM
NM
HM
20.17
20.04
NM
20.05
20.12
NM
19.96
HM
NH
19.98
20.15
20.15
NM
20.18
NM
NM
20.04
NM
20.02
20.03
NM
NM
19.96
20.03
20.06
20
NM
19.97
20.02
0.8
20.04
20.02
20.01
20.11
19.93
20.05
NM
20
NM
20.11
01
NA
NA
05
HA
HA
NA
04
04
01
NA
03
03
03
NA
NA
NA
NA
NA
05
03
05
05
05
05
05
01
NA
NA
01
01
NA
NA
NA
HA
NA
HA
NA
NA
HA
NA
NA
NA
NA
01
01
HA
01
04
03
01
01
01
01
NA
02
NA
NA
03
03
NA
02
NA
NA
NA
NA
NA
No. of
Samples in
Composite
01
HA
NA
05
HA
HA
NA
04
04
01
NA
03
03
03
NA
NA
NA
NA
MA
05
03
05
05
05
05
05
01
NA
NA
01
01
NA
NA
NA
HA
NA
NA
NA
NA
HA
NA
NA
NA
NA
01
01
HA
01
04
03
01
01
01
01
NA
02
NA
NA
03
03
NA
02
HA
NA
NA
NA
NA
Sampl i ng
Date
840828
840828
840828
840921
840921
840828
840717
840813
840813
840821
840821
841025
841025
841025
1984
1984
850619
850619
841016
1984
841010
841010
841010
840910
840910
840910
841017
841017
841017
841016
841016
850603
850603
850626
850626
841002
841002
841025
841025
841120
841120
841120
841114
841114
850809
850809
850725
850725
840801
840801
841025
841025
841025
841025
840809
841004
840919
850618
850613
850613
850613
850613
850630
850630
850914
850914
850914
.D-6-5
-------
Episode SCC
No. No.
Dioxin/Furans
Xlipid wet weight
(g)
3001
3001
3022
3022
3023
3024
3025
3025
3026
3026
3027
3028
3028
3034
3034
3035
3035
3036
3036
3036
3037
3037
3038
3038
3039
3039
3040
3040
3041
3041
3041
3042
3042
3042
3043
3043
3043
3044
3044
3045
3045
3046
3047
3047
3048
3048
3048
3048
3049
3049
3049
3050
3060
3060
3060
3061
3061
3062
3062
3062
3062
3062
3063
3063
3064
3064
3065
DE019501
DEO19502
DA008401
DA008402
OA008501
DA008601
DA008701
DA008702
DA009001
DA009002
DA009301
DA008801
00031787
DG025701
DG025702
DG025801
DG025802
DG025901
DG025902
00120287
DG026001
DG026002
DG026101
DG026102
DG026201
OG026202
DG026301
DG026302
DG026401
DG026402
00031588
DG026501
DG026502
00026501
DG026601
DG026602
00111987
DG026701
OG026702
DG026801
OG026802
OG026901
OG027001
DG027002
DG027101
DG027102
00012689
00027101
DG027201
DG027202
00111087
DG027301
OF009101
OF009102
00073189
DF019105
DF019106
DF024024
OF024324
00024324
OD071587
SF024324
DF023301
OF023302
DF023305
DF023306
OF023419
1.6
8.2
21.8
1.4
1.6
0.9
5.2
2
2.1
0.9
9.8
1.3
1.3
7.9
0.7
NM
1.1
2.5
3.1
2.2
9.5
1.5
NM
NM
8.6
1.7
5.7
NM
9
5.1
9.2
15.2
NM
NM
9.7
NM
NM
NM
NM
4.5
2.8
5.7
10.8
1.4
13.7
1.8
NM
NM
10.3
0.6
0.5
17
1.6
11.9
NM
1.2
2.4
10.4
5.2
5.2
9.7
5.2
9.8
6.7
1.8
6.4
2.3
20.01
20.01
20.23
20.1
20.02
20.16
20.19
20.04
19.99
19.98
20.13
20.04
20.6
20.01
20.06
20.15
20.1
20.07
19.85
20.02
20.05
20.08
20.02
19.99
20.1
20.04
20.18
19.98
20.09
19.96
20.11
20.25
20.1
NM
20.18
20.07
20.11
19.99
20
20.02
20.06
20.13
19.95
19.93
20.01
20
NM
NM
20.07
20.03
20.01
20.01
20.06
20.04
NM
20.02
20
20.03
20.02
20.1
20
20.02
20.02
20.14
20.08
20.16
20.1
Xenobiotics
Xlipid
HM
3.6
17.9
NM
1.2
1.3
4.3
NM
2
NM
NM
0.2
NM
8.6
MM
13.5
NM
NM
9.3
NM
10
NM
17.7
NM
9
NM
5.1
NH
NM
5.2
NM
14.1
0.8
15.5
9.5
NM
NM
8.4
NM
6.2
2.5
5.4
10.3
NM
13.7
2.3
2.5
14.5
9
NM
NH
16.4
2.1
19.9
2
NM
2.2
15.1
NM
NM
NM
NM
10.3
5.8
3
NM
0.9
wet weight
(g)
NM
20.07
20.06
NM
20.08
20.03
20.18
NM
20.11
NH
NM
0.04
NM
20.11
NN
20.07
NM
NM
20
NM
20.06
NM
20
NM
19.77
NM
20.04
NM
NM
20.06
NM
20.07
20.08
20.14
20.12
NM
NM
19.99
NM
19.97
20.02
20.12
20.12
NM
20.01
20
20.12
20.03
20
NM
NM
20.08
0.42
0.82
0.4
NM
20.04
20.04
NM
NM
NM
NM
20.04
19.96
20.14
NM
20.02
No. of
Samples in
Composite
NA
NA
01
02
01
01
02
01
02
01
02
01
01
03
05
04
04
05
05
05
05
05
04
05
05
05
05
05
03
05
03
05
01
05
05
07
07
05
03
05
02
03
05
05
05
05
05
05
05
05
05
05
02
02
02
01
01
07
01
01
07
01
05
03
30
08
03
Sampling
Date
851023
851023
860818
860818
860818
860820
860820
860805
860805
860805
860805
860814
860814
860908
860908
860827
860827
860904
860904
860904
860827
860827
860827
860827
871014
871014
860820
860820
860820
860908
860820
860909
860909
860909
860910
860910
860910
860911
860911
860916
860916
871203
860819
860819
860819
860819
860819
860819
860820
860820
860820
871229
861117
861117
861117
861231
861231
861106
871119
871119
861106
871119
870507
870507
870405
870404
870326
D-6-6
-------
Episode SCC
Mo. No.
Dioxin/Furans
Xlipid uet weight
3065
3065
3065
3066
3066
3068
3068
3069
3069
3069
3070
3070
3071
3071
3072
3072
3072
3072
3073
3073
3073
3074
3075
3076
3076
3077
3077
3077
3078
3078
3078
3078
3079
3079
3080
3080
3080
3081
3081
3082
3082
3082
3083
3083
3084
3084
3085
3085
3085
3086
3086
3086
3087
3087
3087
3087
3087
3087
3087
3087
3088
3086
3089
3089
3090
3090
3091
DF023420
00010788
00022588
DF023503
DF023504
DF024001
DF024002
DF024007
OF024008
00051788
DF024009
DF024010
DF024014
DF024015
DF024017
OF024018
00040788
00070688
DF019221
DF019222
00121587
DF026017
DF024102
DF028502
DF028503
DF019113
DF019114
00121087
DF009118
DF023815
DF023816
SF009118
DF019205
DFO19206
DF023317
DF023318
00040987
DF024105
DF024106
DF023401
DF023402
00120787
DF023405
DF023406
OF024109
00072188
OF024113
DF024114
SF024113
DF023409
DF023410
OF023411
OF023413
DF023414
DF023415
DF023416
00023414
00072387
SF023414
SF023415
DF023417
DF02341B
DF019209
DF019210
DF019213
DF019214
DF019217
8.7
NM
7.6
14.2
1.3
1.7
7.1
4.8
1.5
NM
6.3
1
9.9
NM
3.2
0.7
0.7
NM
7.2
2.1
6.7
2
1.9
6.3
0.9
3.1
4.6
0.6
8.2
3.6
1.4
8.2
4.8
8.2
12.3
1
12.8
3.1
5.8
8.3
1.5
1.3
4.8
1.3
8.1
NM
4.5
1.6
4.5
9.1
NM
1
9.6
1
4.6
1.4
2
9.6
1
4.6
8.2
1.4
1.1
4.1
0.5
7.2
1.9
20.04
NM
20.2
20.01
20.03
20.08
20.01
20.04
19.95
NM
20.09
20.15
20.07
NK
20
20
19.99
NM
19.97
19.98
20.02
20.01
20
20.07
20.04
20.19
20.17
20.06
20.03
20.24
20.07
20.03
20.16
20.07
19.98
20.02
20.06
20.17
20.1
20.09
20.28
20.35
20.07
20.11
19.99
20.01
20.02
20.07
20.02
20.03
NM
20.1
20.1
20.16
20.06
20.04
20.08
19.99
20.08
20.06
20.04
20.1
20.08
20.03
20.17
20.06
20.03
Xenobi ot i cs
Xlipid
6.8
0.6
MM
8.6
1.1
2.4
7.2
4.9
1.1
4.9
5.7
0.7
12.1
10
2.6
NM
NM
2.4
8.3
NM
NM
1.7
NM
8.2
NM
NM
2.3
NM
6.1
3.1
0.8
NM
4.9
9.6
11.9
0.3
NM
5.1
5.4
8.3
NM
NM
NM
0.6
8.1
MM
4.6
1.3
NM
8.9
2
NM
9.5
0.7
3.9
HM
NM
MM
NM
HM
8.4
0.9
0.5
4.3
0.8
7.8
2
wet weight
(g)
20.04
20.09
NM
20.04
0.23
0.49
20.01
20.13
0.22
20.04
20.03
0.13
0.86
0.8
20.16
NM
NM
19.95
19.98
MM
NM
20.12
NM
19.98
NM
NN
0.46
NM
19.93
20.11
20.01
NM
0.81
19.99
19.96
0.06
NM
20.02
20.03
19.92
NM
NM
NM
0.12
19.73
NM
19.95
0.27
NM
20.02
19.99
NM
20.08
20.05
20.12
NM
NM
NM
NM
NM
20.06
19.94
20.11
19.97
19.96
19.97
19.98
No. of
Samples in
Composite
03
NA
03
07
07
25
04
05
05
05
04
04
03
02
04
09
09
04
03
02
03
09
04
05
05
01
03
01
02
03
01
02
06
05
03
05
NA
04
04
03
05
05
03
05
05
05
08
06
08
04
02
03
05
02
01
01
02
05
02
01
08
06
06
05
05
05
05
Sampling
Date
870326
870320
870326
870409
870409
870320
870320
870225
870225
870225
870303
870303
870721
870721
870623
870610
870610
870623
870423
870423
870423
861112
870218
861203
870127
870409
870409
870409
870306
870306
870306
870306
861125
861125
870211
870211
870211
861209
861209
870212
870212
870212
870305
870212
871208
871208
870625
870625
870625
870507
870507
870507
870213
870213
870213
870213
870213
870213
870213
870213
870508
870508
870113
870113
871203
861201
870128
D-6-7
-------
Episode SCC
No.
3091
3092
3092
3093
3093
3093
3094
3094
3095
3095
3096
3096
3096
3097
3097
3097
3098
3098
3098
3098
3100
3100
3101
3103
3103
3104
3104
3105
3105
3106
3106
3107
3108
3108
3109
3109
3110
3111
3111
3112
3112
3113
3113
3113
3114
3115
3115
3115
3117
3117
3118
3118
3118
3118
3118
3118
3119
3119
3120
3120
3122
3122
3122
3125
3125
3125
3132
No.
DF019218
DF023501
OF023502
DF024011
DF024118
00080387
DC017201
00092988
DC038801
DC038802
DC035001
DC035002
00052488
DC038701
DC038702
00071989
DCQ38601
DC038602
00032587
00051288
DC019701
DC019702
DC019901
DC036201
DC036202
DC020001
OC020002
OF025001
OF025002
OE026801
OE026802
DE026901
DE027001
DE027002
DE025001
DE025002
DE022501
DH015801
DH015802
DE022401
DE022402
DE021101
DE021102
00030789
DE021201
DE021301
DE021302
00101689
DE021501
OE021502
DE021601
OE021602
DE021603
00010689
00020488
SE021602
DE021701
DE021702
DE021801
DE021802
DE022001
DE022003
DE022004
OE022301
OE022302
00120888
OE023201
Dioxin/Furans
Xlipid
0.7
9.7
1.7
0.4
8
NH
7.3
7.2
3.4
11.5
1.7
11.2
11.2
4.4
7.5
NH
1.9
3
2
NH
4.4
3.9
3.5
4.6
10.7
1.2
8.6
4.9
2.5
NH
NM
7.8
1.9
9.1
1.5
2.2
7.3
1.2
9.7
11.8
NM
5.6
7.9
NM
11.3
9.1
7.2
NM
16.3
8.1
2.6
14.6
7.6
NM
NH
14.6
2.1
5.4
6.3
1.9
NH
1.6
1.4
21.3
3.7
3.7
8.4
wet weig
20.19
20.04
20.09
19.99
19.96
20.02
20.06
20.04
20.1
20.03
20.06
20.05
20
20.07
20
NH
20.02
20.34
20
NM
19.97
19.3
20.01
20.05
20.06
20.22
20.24
20.14
20.13
19.99
20.04
20.14
20.13
19.94
20.34
20.2
20.24
20
20
20
19.99
20.16
20.05
NH
20.02
20.12
20.05
NH
20.13
20.04
19.97
20.13
20.05
NM
MM
20.13
20.26
19.99
19.96
20.02
20.08
20.02
20.03
20
20
20.03
20.11
Xenobiotics
Xlipid wet weight
NM
9.7
1.5
0.6
8
NM
7.9
NM
2.9
13.3
1.3
12.2
NM
1.6
7
1
2.1
2.9
NM
2
2.3
NM
1.6
4.3
12.5
0.6
8.3
4.7
0.9
2
NM
7.7
0.6
10
2.5
NM
7.3
NM
9.9
10.9
0.3
5.9
6.3
5.7
11.8
10
7.8
8.4
17.5
NM
0.4
15.8
1.5
18.7
0.4
NM
NM
NM
5.9
0.9
17.4
1.7
NM
22.6
3.2
NM
8.5
NM
20.08
0.3
19.9
19.97
NM
20.02
NM
20.05
20.02
0.26
20.23
NM
0.32
19.96
0.2
20
0.59
NM
20.03
0.46
NM
0.33
0.87
20
0.12
20.06
20.08
19.98
20.11
NM
20.13
20.01
19.94
20.1
NM
19.99
NH
20.05
19.95
20.06
20.03
20.02
20.12
20.1
0.8
0.87
0.87
20
NM
20.05
19.97
20.04
20.02
20.06
NM
NM
NK
20.11
19.97
20.06
20.01
MM
19.99
20.08
NM
20.07
No. of
Samples in
Composite
07
05
08
04
04
04
05
05
02
05
03
05
05
05
03
05
03
01
MA
03
04
01
04
05
01
05
03
05
05
03
07
05
04
04
02
03
04
04
04
05
05
07
05
07
05
04
08
04
05
05
05
05
05
05
05
05
05
05
05
05
01
05
05
05
05
05
05
Sampling
Date
870128
870430
870430
870603
870603
870603
871001
871001
871001
871001
870930
870930
870930
861118
861118
861118
861024
861024
861024
861024
861120
861120
861118
861105
861105
861217
861217
870210
870210
860617
851014
860811
860811
860811
860729
860729
860426
861030
861030
860815
860815
870731
870731
870731
860904
890629
890629
890629
870929
870929
860730
860730
860730
860730
860730
860730
850708
850708
850709
850709
861009
861009
861009
870819
870819
870819
850917
D-6-8
-------
Episode SCC
No. No.
Dioxin/Furans
Xlipid wet weight
(9)
Xenobiotics
Xlipid wet weight
(9)
3132
3132
3134
3134
3134
3134
3135
3136
3136
3137
3137
3138
3138
3140
3140
3141
3141
3141
3141
3142
3143
3143
3143
3144
3145
3145
3146
3146
3146
3146
3147
3148
3148
3149
3150
3150
3151
3151
3151
3152
3161
3161
3162
3162
3162
3162
3162
3162
3162
3163
3163
3163
3163
3164
3164
3165
3165
3165
3166
3166
3167
3167
3167
3167
3167
3168
3168
OE023202
00010588
DE023401
DE023403
DE023405
DE023406
DE023501
DE023601
DE023602
DE023701
DE023702
DE023801
DE023802
OE024001
DE024002
OE024101
OE024102
DE024103
SE024102
DE022502
DE024401
DE024402
DE024403
OE024901
DE026601
00071988
DE026701
DE026702
00060288
SE026701
OC035201
DE027101
DE027103
DC038501
DA008901
00120187
DA009101
OA009102
00072887
DA009201
OC019801
DC019802
OJ022121
OJ022122
DJ022123
DJ022403
DJ024001
DJ025103
00041889
DJ022402
DJ022404
DJ024002
OJ025102
0001 5701
00015702
D0015703
DD015704
00031788
OD015705
DD015706
DD015707
00015708
00040588
00062388
SD015708
D0015711
00015712
9.1
NM
1.9
5
4.3
5.2
11.1
NM
0.9
9.7
1.3
7.9
2.5
NM
3.3
NM
15.8
2.6
15.8
19.6
10.4
3
10.8
11.1
10.8
10.9
16.3
1.3
16.3
16.3
9.6
NM
1.7
2.8
4
NM
1.4
1
1.4
3.7
3.5
8.2
3.4
10.6
0.8
0.5
1.9
4
5
4.1
0.7
1.5
2.6
2
14.7
2.1
4.6
1.9
1.8
7.2
1
2.4
0.8
NM
2.4
5.3
0.8
20.18
NM
19.82
20.33
20.16
20.03
20
NM
20.5
20.14
20
20.06
20.06
NM
20.02
NM
20.03
19.97
20.03
20.1
20.15
19.99
20.18
20.05
20.06
20.01
20.01
20.01
20.05
20.01
19.96
20.2
20.11
20
20.08
NM
20
20.16
20.05
20.1
20.23
19.99
20.04
20.13
20.04
20.18
20.02
20.01
20.03
20.04
20.13
20.01
20.02
20.06
20.04
20.06
20.02
20
19.98
19.99
20.04
20.02
20.09
NM
20.02
20.06
20
NM
6.5
NM
4.4
NM
5.5
11.4
1.1
NM
7.4
NM
8.1
NM
1.9
2.8
3.9
15
2.5
NM
25.5
13
NM
10
12.5
11
NM
17.8
1.9
NM
NM
9.1
12.7
0.3
2.9
4.6
5.2
4.5
NM
NM
3.9
2.6
7.4
NM
NM
NM
NM
1.4
NM
NM
NM
NM
1.9
NM
NM
12.8
NM
3.2
NM
NM
7.9
NM
2.1
NM
2.9
NM
4.7
0.5
NM
19.97
NM
20.27
20.13
20.06
20.04
20.03
NM
0.84
NM
20.16
NM
20.07
20.07
20.02
20.08
19.98
NM
20.09
20.09
NM
20
20.21
20.01
NM
20.02
19.99
NM
NM
19.97
20.02
20.06
20.05
20
20.08
20.1
NM
NM
20.02
0.52
20.02
NM
NN
NM
NN
20.14
NM
NM
NM
NM
20.03
DM
NM
20.09
NM
19.98
NM
NM
19.96
NM
19.95
NM
20.02
NM
20.19
20.06
01
05
01
02
02
02
01
02
01
05
NA
04
01
01
04
01
03
05
03
02
01
02
03
03
04
04
03
05
03
03
05
05
05
01
03
03
01
01
01
03
02
05
01
04
05
01
09
05
05
05
05
09
05
05
04
05
02
05
02
02
04
06
04
06
06
02
05
No. of
Samples in
Composite
01
05
01
02
02
02
01
02
01
05
NA
04
01
01
04
01
03
05
03
02
01
02
03
03
04
04
03
05
03
03
05
05
05
01
03
03
01
01
01
03
02
05
01
04
05
01
09
05
05
05
05
09
05
05
04
05
02
05
02
02
04
06
04
06
06
02
05
Sampling
Date
850916
850917
870513
860513
860513
860513
1986
870520
870520
890508
890508
870903
870903
870902
870902
870729
870326
870326
870326
860920
870616
870616
870615
870521
870910
870910
870904
870904
870904
870904
861217
860806
870806
861118
861028
861028
861017
861017
861017
861017
861218
861218
890222
890222
890222
890222
870513
890222
890222
890222
890223
870513
890223
870518
870518
870519
870519
870519
870527
870527
870529
870529
870529
870529
870529
871014
871015
D-6-9
-------
Episode SCC
No.
3168
3169
3169
3169
3170
3170
3171
3171
3172
3172
3173
3173
3173
3174
3174
3175
3175
3176
3176
3177
3177
3177
3178
3178
3179
3179
3180
3181
3181
3182
3182
3183
3183
3184
3184
3185
3185
3185
3186
3186
3187
3188
3188
3189
3189
3189
3190
3190
3191
3191
3192
3192
3192
3193
3193
3195
3195
3196
3196
3197
3197
3198
3199
3199
3199
3200
3201
No.
S0015711
D0015713
00015714
00022789
DD015715
DD015716
D0015717
D0015718
DD015719
DDO 15720
DD015721
D0015722
00070689
DOO 15723
DDO 15724
DDO 15801
DDO 15802
DD015803
DD015804
00015805
D0015806
00100488
00015807
DDO 15808
ODO 15809
DD015810
DD015812
DD015813
00015814
DDO 1581 5
DDO 158 16
DD015817
DD015818
00015819
00015820
DDO 15821
DDO 15822
SD015821
DD015823
OD015824
00015902
00015903
ODO 15904
DD015905
00015906
00092188
00015907
DDO 15908
DJ024003
DJ024005
DJ024007
DJ024009
00020789
DC039001
00039001
DH020104
DH020105
DH020107
DH020108
DH020109
DH020110
DH020111
DH020101
DH020102
DH020103
DH020112
DJ024012
Dioxin/Furans
Xlipid
5.3
10.2
NM
NM
5.5
NM
3.9
NM
8.4
0.6
0.5
20.3
0.6
0.7
10.8
3.4
1.4
4.6
1.2
9
1.8
NM
3.3
0.7
7.9
2
1
2.5
7.2
1.1
7.4
7
0.6
5.5
0.5
6.5
2.2
6.3
2.9
1.7
2.7
4.5
0.4
4.8
0.5
NM
6.3
0.7
1.4
1.4
1
1.2
1
3.5
4.5
3.9
8.7
NM
1.4
NM
3.8
11.5
8.4
NM
4.9
6.1
10.3
wet weig
20.06
20.09
NM
NM
20.07
NM
20.02
NM
20.11
19.99
20.07
20.05
20.06
20.09
20.1
20.01
20.05
19.99
20.07
19.99
20
NM
19.95
19.96
19.98
20.06
20.08
20.01
20.03
20.08
20.02
20.07
20.04
20.01
20.01
20.04
20.21
20.04
20.07
20.03
20.02
19.98
20.1
20.23
20.13
HM
20.65
20.1
20.16
20.11
20.15
20.06
20.09
20.02
20.04
20.05
20.09
NM
20.21
NM
20.06
20.04
20
NM
20
20.1
20.04
Xenobiotics
Xlipid
NH
11.3
NM
10.7
6
NM
3.7
NM
6.6
0.7
NM
19.7
NM
NM
8.9
2.9
NM
3.2
NM
7
NM
6.7
3.3
NM
8.2
NM
0.8
NM
6.8
0.4
8.6
6.9
0.3
NM
0.9
6.9
NM
NM
NM
1.4
2.8
10.8
1.9
6.2
NM
6.8
5.9
NM
2.7
1.8
2
1.5
NM
4.6
NM
4.1
8.5
NM
2.1
NM
NM
10.2
10.1
NM
4.8
6.5
NM
wet weight
(9)
NM
20.1
NH
20.1
19.97
NM
20.04
NM
19.9
19.92
NM
20
NM
NM
20.08
20.37
NM
19.98
NM
20.08
NM
20.16
20.32
NM
20.08
NM
20.11
NM
20.07
19.97
19.97
20.29
20
NM
19.94
20.12
HM
NM
NM
20.05
20.05
20.04
20.03
20
NM
19.99
19.97
MM
20.02
20.1
20
20.14
NM
20.09
MM
20.14
20.12
NM
20.23
NM
NM
20
20.01
NM
20.12
20.04
NM
No. of
Samples in
Composite
02
05
04
05
04
03
05
05
04
03
04
02
04
05
05
03
03
05
05
04
04
04
20
13
04
03
06
05
03
05
03
05
04
05
05
05
01
05
04
04
03
03
04
03
03
03
04
04
05
NA
01
NA
NA
05
05
05
04
05
05
05
05
05
02
03
02
05
NA
Sampling
Date
871014
871112
871112
871112
871027
871027
871028
871028
871111
871111
870713
870721
870713
870623
870623
870915
870915
870626
870626
870914
870914
870914
870911
870911
870915
870915
870923
871006
871006
870813
870813
871008
871008
870903
870903
870915
870915
870915
871124
871124
870819
870707
870819
870708
870708
870708
870709
870709
870625
870625
870625
870625
870625
870526
870526
870819
870819
870823
870823
870826
870826
870822
870817
870817
870817
870824
870714
D-6-10
-------
Episode
No.
3203
3205
3205
3206
3206
3206
3208
3212
3212
3212
3213
3215
3216
3216
3216
3216
3217
3217
3218
3218
3219
3219
3220
3220
3220
3221
3221
3221
3222
3222
3223
3224
32C6
3227
3231
3231
3234
3234
3235
3235
3236
3236
3237
3237
3237
3238
3238
3241
3241
3244
3245
3245
3246
3246
3248
3248
3249
3249
3250
3250
3252
3252
3252
3252
3252
3256
3256
sec
No.
DJ024018
DJ024023
DJ024024
DJ022301
OJ024102
DJ024103
DJ024109
DJ024120
DJ024121
00050388
DJ024123
DJ023705
DJ023707
OJ023708
00022388
00091688
DJ023709
DJ023710
OJ023711
OJ023712
DJ 02371 3
DJ023714
OJ023902
DJ023903
00012288
OJ022405
OJ023904
OJ023905
DJ023906
DJ023907
DJ023717
DJ023715
DJ023721
DJ023723
DJ023910
0 J02391 1
DH020301
DH020302
OH020303
OH020304
OH020305
DH020306
DH020307
DH020308
00080988
DJ023918
00080888
OJ023923
DJ023924
OJ 023622
OJ023623
DJ023624
DJ022108
OJ022109
DJ022502
00050588
OJ022503
DJ022504
DJ022505
DJ022506
DJ022509
DJ022510
00020989
00052588
00082288
OJ022517
DJ022518
Dioxi
Xlipi
4.3
NH
1.1
3.9
2
4.2
14.1
NH
4.5
MM
NH
NH
2
9.6
NH
8.2
8.8
9.6
2.9
7
3.9
0.7
3
11.4
3
25.1
3.6
10.9
1.3
9.2
2.5
0.7
2.8
2.1
NH
12.1
3.2
NM
7.4
NH
9.5
3
4.1
7.6
NH
9.9
2.1
NH
9.2
1.9
1.1
4.2
1.3
1.6
6.2
NH
NH
3.7
NH
6.3
NH
20.5
NN
NM
19.3
4.4
6.4
wet weight
19.88
NM
20
20.1
20.03
20.44
19.91
NM
19.98
20.17
NM
NM
20
19.94
NM
20.03
20.42
20.06
20.09
20.03
20.1
20.02
20.1
20.08
20.11
20.05
20.02
20.21
20
20.07
20.1
20.13
20.01
20.02
NM
20.08
19.47
NH
19.86
NH
19.84
19.98
20.09
20
NM
20.03
20.07
NM
20.04
20.05
20.27
20.03
20.04
20.92
20
NM
NM
19.98
NM
20.12
NH
20.01
NM
NM
19.98
20.09
20.57
Xenobiotics
Xlipid wet weight
(9)
8.9
NH
0.7
NH
NH
6
18.3
3.4
6.3
NN
5.8
15.9
1.4
7.8
7.7
NM
NH
8.3
2.8
NM
3.3
0.5
NM
15.9
NH
NM
NM
23.7
NM
8
2.4
1.9
2.8
1.3
0.7
15.3
2.8
NM
6.8
NH
8.5
NH
NM
7.2
7.1
10
NM
NH
9.9
NM
NH
3.9
NM
2.2
6
6.3
0.7
3.4
NM
5.8
0.8
25
0.7
26.6
NM
NM
6.1
20.11
NM
19.9
NM
NM
20.09
20.14
20.02
20
NH
19.99
20.11
20.07
20.06
20.15
NM
NM
19.98
20.11
NM
20
20.1
NM
20.09
NH
NM
NM
20.13
NM
20.06
19.94
20.18
20.09
20.03
20
20.05
20.01
NH
20.08
NM
20.09
NM
NM
20.11
20.12
19.98
NM
NH
20.04
NH
NH
20.07
NM
20.01
20
20.15
20.03
19.97
NM
19.98
20.13
20.1
20.13
20.12
MM
NM
20
No. of
Samples in
Composite
03
04
01
NA
04
04
05
07
05
NA
NA
NA
04
04
04
04
05
04
05
05
NA
NA
05
04
05
03
01
01
03
05
11
NA
30
20
04
03
04
05
02
04
02
04
04
02
02
11
11
06
05
10
04
10
10
10
04
04
06
02
10
06
04
04
04
04
04
12
06
Sampling
Date
870714
870813
870813
870722
870722
870722
870804
870804
870804
870804
870723
870811
870819
870819
870819
870819
870729
870729
870819
870819
870630
870630
870818
870818
870818
890328
870804
870804
870903
870903
870724
870613
870904
870904
870825
870825
870924
870924
870915
870915
870928
870928
870902
870902
870902
870613
870813
870612
870612
871016
870618
870618
870404
870404
870804
870804
870804
870804
870804
870804
870916
870916
870916
870916
870916
871124
871124
D-6-11
-------
Episode SCC
HO. NO.
Dioxin/Furans
Xtipid wet weight
(9)
Xenobiotics
XUpid wet weight
(9)
3258
3258
3259
3259
3259
3260
3261
3261
3262
3264
3266
3266
3266
3267
3267
3267
3269
3270
3270
3270
3271
3272
3272
3273
3273
3274
3274
3275
3276
3276
3278
3278
3281
3282
3282
3283
3285
3285
3286
3287
3288
3288
3288
3289
3289
3290
3290
3294
3294
3294
3295
3296
3297
3297
3297
3298
3298
3298
3299
3299
3299
3300
3300
3300
3300
3301
3301
DC038901
OC038902
08000466
DB000473
DB069101
DB000493
DY026001
DY026002
DY026004
DY022602
DY022701
DY022702
00012389
DY022101
DY022102
00020288
DY022106
DY022107
OY022108
SY022108
DY022110
DY022111
DY022112
DY022113
DY022114
DY022115
DY022116
OY022118
OY022119
OY022120
DY022123
OY022124
DY022205
DY022206
OY022207
DY022209
DY022212
DY022213
DY022215
DY022216
DY022217
DY022218
00060188
OY022219
DY022220
DY022221
OY022222
OJ022111
DJ022112
OJ022113
DJ022114
DB040101
DB041501
DB041504
SB041501
DB041601
DB041604
00112988
08040601
OB040604
00040601
DB040201
DB040204
00021389
SB040201
DB041101
0 8041 104
17
8.4
10
NM
NM
8.9
NM
8
3.1
8.4
NM
6.9
NM
5.4
9.1
5.6
5.2
2.4
7.2
7.2
9.7
1.1
7.6
6.7
2
NM
3.7
11.2
4.4
3.3
NM
1.7
10.9
NM
7.6
5.1
6.3
4.3
5.3
2.4
NM
4.5
4.5
4.9
3.6
0.9
18.4
4.4
NM
1.5
1.8
6
14.6
1.1
14.6
16.8
0.7
1
3.4
1.7
NM
3.8
1.1
NM
3.8
19.7
0.8
19.99
19.98
20.02
NM
20.06
19.99
NM
20.14
20.08
20
NM
20.03
NM
20.06
20
20.01
20
19.99
20.03
20.03
20.26
20.08
20.05
20.01
20.02
NM
19.86
20.03
20.17
20.38
NM
20.04
20.08
NM
20.03
19.71
19.99
20.34
19.73
20.07
NM
19.98
20.15
20.13
20.1
20
20.33
19.99
NM
20.03
20
20.2
20.04
20.09
20.04
20.06
20.04
20.02
20.05
20.1
NM
20.05
20.04
NM
20.23
19.98
20.03
18.6
8.3
13.2
0.2
8.3
17.8
NH
7.6
2
NM
0.5
6.7
0.7
1.2
9
NM
NM
NM
6.9
NM
6.7
NM
6.3
4.7
0.1
NM
2.9
NM
4.4
NM
NM
3.5
8.1
1.8
7.8
3.5
7.4
3
4.6
2.3
3.2
4.5
NM
5
2.6
1.6
17.7
6.9
NM
0.9
1.1
6.1
14.7
NM
NM
15.8
1.7
NM
2.8
1.6
2.7
5.8
2.1
2.1
NM
19.4
0.6
3.73
20.04
20.01
20.07
20.1
20.02
NM
20.02
20.34
NM
20.04
20.3
20.04
20.13
20.09
NM
NM
NM
20.29
NM
20.04
NM
20.01
19.94
20.08
MM
20.11
NM
0.89
NM
NM
20.02
20.13
20.04
20.2
20.08
20.02
19.91
19.96
20.07
20.02
20.03
NM
20.05
20.11
20.03
19.98
19.97
NM
0.17
20.03
20.06
20.02
NM
NM
20.02
20.09
NM
20.08
20.05
19.9
20.02
19.98
20
NM
20.07
20.21
03
03
04
03
03
03
02
01
10
06
05
OS
OS
04
04
04
01
04
04
04
09
01
04
22
20
10
09
10
03
07
06
06
10
03
03
03
06
03
04
04
07
08
08
10
07
08
03
20
07
20
10
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
No. Of
Samples in
Composite
03
03
04
03
03
03
02
01
10
06
05
OS
OS
04
04
04
01
04
04
04
09
01
04
22
20
10
09
10
03
07
06
06
10
03
03
03
06
03
04
04
07
08
08
10
07
08
03
20
07
20
10
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
Sampling
Date
870812
870812
870609
870609
870721
870610
870729
870729
870716
871119
871020
871020
871020
871009
871009
871009
871217
871006
871006
871006
870916
871210
871210
870914
870914
8709H
870914
870913
870915
870915
871014
871014
870728
870903
870903
870903
870616
870616
870617
870616
870812
870812
870812
870813
870813
871119
871119
871121
870921
870921
871021
870714
870731
870731
870731
870724
870724
870724
870723
870723
870723
870713
870713
870713
870713
870713
870713
D-6-12
-------
Episode SCC
No. No.
Dioxin/Furans
Xlipid wet weight
(8)
Xenobiotics
Xlipid wet weight
(9)
3301
3301
3301
3302
3302
3303
3303
3303
3304
3304
3304
3305
3305
3305
3306
3306
3306
3307
3307
3308
3308
3309
3310
3310
3311
3311
3312
3312
3313
3313
3314
3314
3314
3314
3315
3315
3316
3316
3317
3317
3317
3317
3318
3318
3319
3319
3320
3321
3321
3322
3323
3324
3325
3325
3326
3327
3327
3328
332f
3328
3328
3329
3329
3330
3330
3330
3331
00030989
00092088
SB041101
DB041901
DB041904
DB042301
DB042304
00 102588
DB041001
DB041004
00041004
OB042001
DB042004
001 10388
DB041801
DB041804
00041801
DB042101
00100588
OB040001
00030689
DB041301
DC032701
DC032702
DC032801
OC032802
DC033101
DC033102
DC033201
OC033202
DC033301
DC033302
SC033301
SC033302
DC033401
DC033402
DC033501
DC033502
OC033601
DC033602
SC033601
SC033602
DC033701
DC033702
DB041401
00063088
DB041412
DB040401
00100688
OB040412
OB041206
D8041252
DB041218
00082988
DB041208
DB040301
DB040315
D0029111
D0029112
S0029111
SD029112
ODC16003
SD016003
D0029109
DD029110
DD029423
DD016001
NM
20.4
19.7
6.7
0.6
5.2
NM
NH
NM
5.5
NM
23
NM
NM
4.5
NM
NM
3.7
4.6
0.6
1.5
6.3
6.1
0.7
3
1.5
3.9
1.4
1.9
0.8
10.9
2.7
10.9
2.8
3.9
NM
2.5
1.6
4.9
4.7
4.9
4.7
3.9
0.8
3.6
3.8
3
3.2
NM
2.7
2.7
3.4
2.6
2.5
3.2
NM
3.6
5.8
1.4
5.8
1.4
8.4
8.4
1.5
3.5
0.5
3.2
NM
20.07
19.98
20.04
20
20.06
NM
NM
20.11
20.11
NM
20.01
20.18
NM
20.07
NM
NM
20.29
20.06
20.02
20.02
20
20.08
20.01
20.1
19.99
20.01
20.02
20.04
20
20.05
19.97
20.05
19.97
20.11
NM
20.05
20.07
20.07
20.08
20.07
20.08
20.08
20.15
19.98
20.01
20.02
20.19
NH
20.24
20.02
20.16
20.06
20.06
20.07
20.04
20.03
20.1
20.1
20.1
20.1
20.01
20.01
20.02
20.12
19.99
20.08
0.7
NM
NM
7.1
0.4
6.1
0.7
6
0.4
6.1
8.2
21.2
1.2
23.2
5.2
2.2
6.1
3.7
NM
0.7
NM
5.9
5.6
0.7
2.9
0.6
3.8
1.7
1
0.5
10.7
2.1
NM
NM
4.5
1
2.2
NM
3.7
NM
NM
NM
3.5
NM
3.6
NM
3
4
4
NM
2.9
4.7
2.3
NM
4.2
3.8
3.1
6.1
NM
NM
NM
8.1
NM
NM
3.5
NM
NM
20.02
NM
NM
20.08
20.14
20.1
20.1
20.1
20.05
19.96
20.06
20.03
20.14
20.12
19.95
20.03
20.07
20.02
NM
20.03
NM
20.06
20.15
0.14
19.93
0.13
19.83
0.34
20
0.1
19.84
20.02
NM
NM
19.81
20.06
20.24
NM
19.96
NM
NM
NM
19.83
NM
20
NN
20.01
19.99
19.99
NM
20.14
20.03
19.94
NM
20.15
20.11
20.03
19.93
NM
NM
NM
20.1
NM
NM
20.1
NM
NM
03
MA
03
03
03
03
03
03
03
03
03
03
04
03
04
05
04
03
03
03
03
03
05
04
05
05
05
05
05
05
04
05
04
05
02
02
05
03
05
10
05
10
05
05
11
11
28
11
11
29
02
10
34
34
10
14
08
03
04
03
04
02
02
02
04
04
01
No. of
Samples in
Composite
03
MA
03
03
03
03
03
03
03
03
03
03
04
03
04
05
04
03
03
03
03
03
OS
04
OS
05
OS
05
05
05
04
05
04
05
02
02
05
03
05
10
05
10
05
05
11
11
28
11
11
29
02
10
34
34
10
14
06
03
04
03
04
02
02
02
04
04
01
Sampling
Date
870713
870713
870713
870723
870723
870630
870630
870630
870827
870827
870827
870909
870909
870909
880828
880828
880828
870917
870917
870813
870813
870724
871027
871027
870928
870928
870929
870929
871014
871014
871007
871007
871007
871007
870922
870922
870924
870924
871015
871015
871015
871015
870923
870923
870616
870616
870915
870630
870630
870908
870826
871002
870921
880921
870921
870929
871002
880512
880512
880512
880512
880513
880513
880419
880419
880419
880108
D-6-13
-------
Episode SCC
No. Ho.
Dioxin/Furans
Xlipid wet weight
Xenobiotics
Xlipid wet weight
(9)
3331
3331
3331
3331
3332
3332
3333
3333
3333
3333
3334
3334
3335
3335
3335
3335
3335
3335
3335
3335
3336
3336
3336
3336
3336
3336
3337
3337
3337
3338
3338
3338
3339
3339
3339
3340
3340
3340
3341
3341
3341
3341
3341
3341
3342
3342
3343
3343
3344
3344
3344
3345
3345
3345
3346
3346
3346
3346
3346
3347
3347
3347
3348
3348
3348
3348
3348
00016002
00016007
00016008
S0016008
000 16009
00016010
00016011
00016012
00029108
00121588
DD016013
00016014
DD016015
00016016
D0029101
DD029102
00029103
Q0081588
00091588
S0016015
00016004
OD016005
00016006
DD016017
00016018
00092288
00016019
00016020
00051388
00016021
00016022
00029107
00016023
00016024
00016023
DD029113
00029114
S0029114
0001 6 103
DD016104
00081788
00092788
SD016103
SD016104
00016105
D0016106
00016107
DD016108
00016109
00016110
S0016109
DD016111
00016112
S0016111
DD016113
DD016114
00042088
SD016113
SD016114
00016115
00016116
SD016115
00016117
00016118
00072888
S0016117
S0016118
1.1
5
2.7
2.7
13.4
1.2
7.6
6.3
0.8
NM
12.2
1.5
13.2
2.3
4.8
1.4
8.1
2.1
NM
13.2
2.7
7.6
5.1
2
1.2
8.2
5.9
2
NM
0.8
4.9
0.6
7.4
1.9
7.3
0.9
8.8
8.8
0.7
7.7
NM
0.7
0.7
7.7
0.9
1.4
6.9
3.4
8.2
0.9
8.2
1.1
0.5
2.4
3.9
0.9
4
3.9
0.9
6.1
1.4
6.1
2.1
5.3
5.7
2.1
5.3
20.09
20.02
19.99
19.99
20.15
20.18
20.09
20.13
20.01
20.11
20.14
20.11
19.96
20.08
20.04
20.07
20.11
20.23
NM
19.96
20.02
20.01
20.09
20.09
20.04
20.06
19.95
20.16
20.08
20.09
19.98
19.98
20.12
20.01
20.1
20
19.94
19.94
20.04
20.15
NM
19.98
20.04
20.15
20.04
20
20.01
10.01
20
20.04
20
20
20.05
20
20
20.05
20.06
20
20.05
20.03
20.06
20.03
19.98
20.02
20
19.98
20.02
NM
1.1
NM
NM
14.2
-0-
NM
6.2
NM
NM
9.4
NK
11.3
NM
3.3
1.1
9.5
NM
3.6
NM
1.6
NM
4.8
3
1.1
NM
6.1
NM
NM
NM
5
NM
7.3
NM
MM
NM
8.2
NM
NM
7.8
8.2
NM
NM
NM
13.9
NM
1.4
NM
8.4
NM
NM
2.1
NM
NM
3.9
2.6
NM
NM
NM
4.5
NM
NM
2.1
5.1
NM
NM
NM
NM
20
NM
NM
20.07
-0-
NM
19.99
HH
NM
20.06
MM
20.04
NM
20.02
0.23
20
NM
19.81
NM
19.93
NM
20.02
19.98
20.04
NM
20.01
NM
NM
NM
20.04
NM
20
NM
NM
NM
20.13
NM
NM
20.01
20.02
NM
NM
NM
20.03
NM
20.12
NM
20.04
NM
NM
20.07
NM
NM
19.88
20.12
NM
NM
NM
20.05
NM
m
20.06
20.03
NM
NM
NM
01
02
02
02
22
09
03
05
02
03
05
05
04
05
02
01
01
01
02
04
02
02
01
02
06
06
08
03
08
08
10
09
04
07
04
03
04
04
05
05
05
05
05
05
03
04
02
06
01
05
01
06
01
06
01
05
01
01
05
05
04
05
06
06
06
06
06
No. of
Samples in
Composite
01
02
02
02
22
09
03
05
02
03
05
05
04
05
02
01
01
01
02
04
02
02
01
02
06
06
08
03
08
08
10
09
04
07
04
03
04
04
05
05
05
05
05
05
03
04
02
06
01
05
01
06
01
06
01
05
01
01
05
05
04
05
06
06
06
06
06
Sampling
Date
380108
880108
880108
880108
880621
880621
880609
880609
880609
880609
880606
880606
880425
880425
880425
880425
880425
880425
880425
880425
880519
880519
880519
880519
880519
880519
880407
880407
880407
880129
880129
880129
880524
880524
880524
880428
880428
880428
870929
870929
870929
870929
870929
870929
871202
871202
871102
871102
871028
871028
871028
871103
871103
871103
871214
871214
871214
871214
871214
880307
880307
880307
880318
880318
880318
880318
880318
D-6-14
-------
Episode
No.
3349
3349
3350
3350
3350
3351
3351
3351
3352
3352
3352
3352
3353
3353
3353
3354
3354
3355
3355
3355
3356
3356
3357
3357
3360
3360
3360
3375
3375
3375
3375
3376
3376
3376
3377
3377
3377
3378
3378
3378
3378
3385
3385
3395
3395
3395
3401
3401
3403
3403
3404
3404
3404
3404
3409
3409
3411
3412
3412
3412
3414
3414
3415
3415
3416
3416
3416
sec
Ho.
DD016119
00016120
DD016121
OD016122
00052688
D0016123
DD016124
00021888
DF023723
OF023724
00022089
00091388
DF024121
DF024122
00024121
DY022301
OY022302
DY022303
DY022304
SY022303
DE030201
SE030201
DY022223
DY022224
D0029117
DD029118
00022389
ODD 16305
OD016306
00071189
00101188
00016307
DD016308
00050389
00016309
DD016310
SCO 16309
DD016311
00016312
00029115
DD029116
D0016401
00101888
00016421
DDO 16422
SOO 16421
00016509
00016510
00016513
00016514
DD016515
00016516
00016515
S0016515
OB040701
DB040706
DB040501
OB040901
DB040907
SB040907
DC036203
DC036204
OC036205
DC036206
OF025210
DF025211
DF025212
Dioxi
Xlipi
8.5
1.5
10.6
0.5
NM
1.2
10.3
7.7
1.3
5.5
NM
NM
3
6.2
2.9
8.4
1.1
7.5
1
7.5
10.4
10.4
0.5
18.5
5.9
1.9
6.7
16.9
1.4
NM
18
12.6
2.4
1.7
12.7
1.3
12.7
7.4
1.6
10.8
2.7
4.8
NM
8.2
0.8
8.2
11.1
1.3
10.7
6.4
6.2
0.8
NM
6.2
12.2
1.1
8.3
1.8
14.7
14.7
0.8
9.6
0.8
11.5
3.1
2
1.6
wet weight
(9)
20
20.02
20.07
20.13
20
20.03
20.12
20.23
20.18
19.99
MM
20.09
20.1
20.04
19.98
20.01
20.02
20.02
20.06
20.02
20.05
20.05
20.06
20.11
20.01
20.05
20.03
20.01
20.08
NM
20.12
20.09
19.99
19.99
20.05
20.04
20.05
20.07
19.98
20
20.01
20.1
KM
19.97
20.03
19.97
20.15
20.07
20.12
20.13
20.14
20.05
NM
20.14
20.07
20.03
20.03
20.13
20.03
20.03
20.09
20.01
20.04
20.07
20.09
20.02
20.06
Xenobiotics
Xiipid wet weight
(9)
5.8
NM
10.4
0.9
NM
NM
9.7
NM
1
5.6
0.7
NM
2.6
6.3
NM
9.2
0.8
6.5
0.6
NM
10.1
NM
NM
22.7
6.9
NM
NM
19.3
0.8
1.4
NM
13
0.5
NM
14.7
1
NM
1.5
NM
12
NM
4.7
6.7
8.1
NM
NM
12.3
0.6
11.7
1.4
6.1
NM
6.2
NM
11.7
0.6
10.3
2.1
16.9
NM
2.3
10.4
1.1
8.1
NM
NM
NM
20.05
MM
20
19.99
NM
NM
19.99
NM
20.09
19.74
20.05
NM
19.96
19.74
NM
20.01
19.99
19.97
19.98
NM
19.66
NM
NM
20.02
20.06
NM
NM
19.97
0.16
0.29
NM
20.03
0.09
NM
20.12
0.2
NM
19.98
NM
19.96
NM
20.08
20.11
20
NM
MM
19.98
20.1
19.98
20.01
20.03
NM
20.12
NM
20
20.08
20
20.02
20.06
NM
20.06
20.12
20.02
20.04
NM
NM
NM
Mo. of
Samples in
Compos i te
03
02
06
04
06
01
02
02
01
03
01
03
02
03
02
03
03
03
03
03
04
04
01
01
04
04
04
03
05
05
03
05
05
05
05
05
05
02
05
03
01
05
NA
06
03
06
03
04
05
04
05
03
05
05
05
MA
03
06
03
03
MA
NA
05
NA
03
03
03
Sampling
Date
880218
880218
880406
880406
880406
880202
880202
880202
871211
871211
871211
871211
871210
871210
871210
871114
871114
871119
871119
871119
871118
871118
871202
871202
880901
880901
880901
880914
880914
880914
880914
880906
880906
880906
880906
880906
880906
880912
880912
880912
880912
880901
880901
880901
880901
880901
880421
880421
880810
880810
880810
880810
880810
880810
870915
870915
870909
870917
870917
870917
871007
871007
870922
870922
590906
890906
890906
D-6-15
-------
Episode
No.
3418
3419
3419
3420
3420
3421
3421
3421
3422
3422
3423
3423
3424
3424
3425
3425
3425
3426
3427
3428
3429
3430
3431
3432
3433
3433
3434
3434
3435
3435
3437
3438
3439
3439
3440
3441
3442
3442
3443
3444
3444
3444
3444
3445
3445
3446
3446
3446
3446
3446
3450
3450
3451
3451
3452
3452
3452
3452
sec
No.
DF025007
DC036207
DC036208
DC036209
DC036210
DC036211
DC036212
SC036212
DC036213
DC036214
DC036215
DC036216
DC036217
DC036218
OF025005
DF025012
00031389
08069102
DB069103
DB069104
D8069105
DB069106
DB069109
D 80691 1 1
OB069112
00021689
DB040801
00011889
D0016601
DD016602
DJ022302
DJ022303
DJ022304
00062289
OJ022305
DJ022306
DF024301
00081089
DF009118
DD016603
DD016604
DD029512
00091289
DD029513
DD029514
DD016605
OD016606
D0029511
00091889
00092089
DY022308
DY022309
DY022310
DY022314
DF025218
DF025219
DF025220
00103189
Dioxi
Xlipi
2
7,3
1.8
2.9
6.2
1.2
9.7
9.7
7.6
1.9
2.1
6.2
2.1
4.1
5.6
2.3
2.1
NH
MM
NM
MM
NM
NM
NM
3.6
3.6
NM
NM
2.8
22.6
3.5
3.6
2.9
2.6
3.2
4
1.2
1.1
8.2
12.1
7.1
1.2
11.4
2.7
6.5
1.2
2.8
7.5
NM
7.8
1.3
1.8
2.1
1.9
2.2
3
1.2
2.4
wet weight
20.03
20.01
20.13
20.07
20.01
20.05
19.99
19.99
19.97
20.13
20.02
20.13
20.08
20.12
20.01
20.09
20.03
20
20.01
20.07
20.05
20
19.99
20.07
20.05
20.05
20.05
NM
20
20.02
20.11
20.15
20.01
19.99
20.06
20.01
20
20.11
20.03
20.03
19.98
20
20.12
20.06
19.99
20.13
20.08
20.03
NM
20.07
20.02
20.09
20
19.97
20.04
20.11
20.02
20.02
Xenobiotics
Xlipid wet weight
(a)
7.3
1.4
2.8
5.4
0.9
10
NM
0.3
0.8
NM
6
NM
4.2
5.7
NM
MM
3.8
1
4.6
1.7
2.9
2.9
NM
4
NM
4.2
4.1
NM
23.6
NM
NM
NN
NH
NM
NM
NM
MM
6.1
10.9
6.4
0.8
NM
2.2
NM
0.5
2.9
NM
2.9
NM
NM
HM
NM
NM
NM
NM
NM
0.86
0.27
0.57
20.08
20.09
20
HM
0.05
20.15
NM
20.12
NM
20
20.04
NM
NM
19.98
20.01
20.05
20.1
20.14
20.11
MM
19.99
NM
19.95
20.11
NM
20
NM
NM
MM
NM
NM
NM
NM
NM
19.93
0.82
0.8
0.16
NM
0.45
NM
0.1
0.57
NM
0.58
NM
NM
MM
NM
NM
NM
NM
NM
NM
No. of
Samples in
Composite
08
03
05
03
03
05
05
05
05
03
05
05
03
05
03
03
03
03
03
03
05
05
02
02
OS
05
05
05
02
01
NA
30
05
05
04
05
07
07
02
OS
05
03
05
03
05
02
03
03
03
03
04
04
04
04
06
06
02
06
Sampling
Date
890516
890606
890606
881115
881115
880907
880907
880907
880920
881006
880913
880929
880914
880914
890131
890131
890131
880908
880908
880908
880829
880927
870927
870926
870820
870820
870820
870820
890105
890105
870822
890321
890327
890327
890328
890328
890426
890426
870306
890829
890829
890829
890829
890524
890524
890718
890718
890718
890718
890718
1988
1988
880518
880518
890912
890912
890912
890912
D-6-16
-------
APPENDIX D-7
List of Confirmation Samples
-------
TABLE D-7
List of Confirmation Samples
Episode
Number
3062
3085
3087
3087
3118
3141
3146
3167
3168
3185
3297
3300
3301
3314
3314
3317
3317
3328
3328
3329
3331
3335
3340
3341
3341
3345
3346
3347
3348
3348
3355
3356
3377
3395
3404
3412
3421
3443
SCC No. for
Environnw nt&l SiniDlf
DF024324
DF024113
DF023414
DF023415
DE021602
DE024102
DE026701
DD015708
DD015711
DD015821
DB041501
DB040201
DB041101
DC033301
DC033302
DC033601
DC033602
DD029111
DD029112
DD016003
DD016008
DD016015
DD029114
DD016103
DD016104
DD016111
DD016113
DD016115
DD016117
DD016118
DY022303
DE030201
DD016309
DD016421
DD016515
DB040907
DC036212
DF009118
SCC No. for
Confirmation Sample
SF024324
SF024113
SF023414
SF023415
SE021602
SE024102
SE026701
SD015708
SD0157I1
SD015821
SB041501
SB040201
SB041101
SC033301
SC033302
SC033601
SC033602
SD029111
SD029112
SD016003
SD016008
SD016015
SD029114
SD016103
SD016104
SD016111
SD016113
SD016115
SD016117
SD016118
SY022303
SE030201
SD016309
SD016421
SD016515
SB040907
SC036212
SP009118
D-7-1
-------
D-7-2
-------
APPENDIX D-8
List of Duplicate Samples
-------
TABLE D-8
List of Duplicate Samples
Episode
1994
2070
2100
2105
2126
2139
2191
2225
2228
2280
2280
2301
2322
2369
2376
2385
2394
2427
2427
2429
2430
2618
2721
2776
3028
3036
3041
3042
3043
3048
3048
3049
3060
3062
3062
3065
3065
3069
3072
3072
3073
3077
3080
SCC No. for
DEO 17702
DJ000901
DH001703
DH002204
DD000302
DD001604
DG005206
DC006903
DC007204
DF005201
DF005204
DD004504
DB001304
DA003203
DA003903
DE006002
DE006901
DEO 10203
DEO 10403
DE010403
DE010603
DE015403
DA006502
DY007101
DA008801
DG025901
DG026401
DG026501
DG026602
DG027101
DG027I02
DG027202
DF009101
DF024024
DF024324
DF023419
DF023420
DP024008
DF024017
DF024018
DF019221
DF019113
DF023317
SCC No. for
Duplicate Samp^
QD1 10586
QD072186
QD111086
QD063086
QD062686
QD071486
QD092486
QD101387
QD070286
QD121688
QD062386
QD071786
QD082686
QD030387
QD1 11886
QD101987
QD006901 and QD022189
QD102887
QD010687
QD010687
QD121486
QD102088
QD011089
QD010489
QD031787
QD120287
QD031588
QD026501
QD1 11987
QD027101
QD012689
QD1 11087
QD073189
QD071587
QD024324
QD010788
QD022588
QD051788
QD070688
QD040788
QD121587
QD121087
QD040987
D-8-1
-------
TABLE D-8( Continued)
Episode
Number
3082
3084
3087
3087
3088
3093
3093
3094
3096
3097
3098
3113
3115
3118
3118
3125
3132
3145
3146
3150
3151
3162
3165
3167
3167
3169
3177
3189
3192
3193
3212
3216
3220
3237
3238
3248
3252
3252
3266
3267
3288
3298
3299
3300
SCC No. for
Environment8' Sample
DF023402
DF024109
DF023413
DF023414
DF023418
DF024118
DF024118
DC017201
DC035002
DC038701
DC038601
DEX)21101
DE021301
DE021601
DE021602
DE022302
DE023201
DE026601
DE026701
DA008901
DA009101
DJ025103
DD015703
DD015707
DD015708
DD015713
DDO 15805
DD015905
DJ024009
DC039001
DJ024121
DJ023708
DJ023902
DJ020308
DJ023918
DJ022502
DJ022509
DJ022510
DY022701
DY022101
DY022218
DB041604
DB041601
DB040204
SCC No. for
Duplicate Sample
QD 120787
QD072188
QD072387
QD023414
QD091587
QD080387
QD080387
QD092988
QD052488
QD071989
QD032587
QD030789
QD101689
QD020488
QD010689
QD120888
QD010588
QD071988
QD060288
QD120187
QD072887
QD041889
QD031788
QD040588
QD062388
QD022789
QD100488
QD092188
QD020789
QD039001
QD050388
QD022388 and QD091688
QD012288
QD080988
QD080888
QD050588
QD020989
QD082288 andQD052588
QD012389
QD020288
QD060188
QD1 12988
QD040601
QD021398
D-8-2
-------
TABLE D-8 (Continued)
Episode
Number
3301
3303
3304
3305
3306
3307
3308
3319
3321
3325
3333
3335
3335
3336
3337
3339
3341
3341
3346
3348
3350
3351
3352
3352
3353
3360
3375
3375
3376
3385
3404
3425
3433
3434
3439
3442
3444
3446
3446
3452
SCC No. for
Envirannnc |)tfll S"1™1'*
DB04I101
DB042301
DB041004
DB042001
DB041801
DB042101
DB040001
DB041401
DB040401
DB041218
DD016011
DD029101
DD029102
DD016018
DD016019
DD016023
DD016103
DD016104
DD016113
DD016118
DD016121
DD016124
DF023723
DF023724
DF024121
DD029117
DD016305
DD016306
DD016308
DD016401
DD016515
DF025012
DB069112
DB040801
DJ022304
DF024301
DF016603
DD016606
DD029511
DP025218
SCC No. for
Duplicate Samnle
QD092088
QD 102588
QD041004
QD 110388
QD041801
QD100588
QD030689
QD063088
QD100688
QD082988
QD121588
QD091588
QD081588
QD092288
QD051388
QD016023
QD092788
QD081788
QD042088
QD072888
QD052688
QD012888
QD022089
QD091388
QD024121
QD022398
QD101188
QD071189
QD050389
QD101888
QD016515
QD031389
QD021689
QD011889
QD062289
QD081089
QD091289
QD091889
QD092089
QD 103 189
D-8-3
-------
APPENDIX D-9
Comments Regarding Sample Analyses from EPA Duluth
Laboratory
-------
TABLE D-9
Comments Regarding Sample Analyses From EPA-Duluth Laboratory
Episode SCC Ho.
2016
2017
2057
2110
2122
2133
2190
2194
2212
2283
2298
2309
2309
2322
2328
2358
2383
2427
2429
2432
3022
3039
3041
3042
3048
3048
DF001101
DF001201
DE000601
DH002710
DH003904
DD001002
DG005104
DG005504
DC005602
DF005502
DD004201
DD005301
DD005304
DB001304
DB001904
DA001901
DE005801
DE010202
DE010402
DE010710
DA008401
DG026202
QD031588
DG026501
DG027101
QD027101
Comments
XC:
XC:
SC:
SC:
SC:
XC:
SC:
SC:
XC:
SC:
SC:
SC:
XC:
SC:
SC:
SC:
XC:
XC:
XC:
XC:
XC:
XC:
DC:
SC:
DC:
DC:
DC-
DC:
DC:
XC:
XC:
XC:
CONC OF DDE TAKEN FROM DILUTION
CONCENTRATION FOR DDE TAKEN FROM DILUTION
RERUN OF C102086LH
SAMPLE NUMBER ASSIGNED AT LAB AND DSR FILLED OUT AT LAB
DH003905 WAS COMBINED WITH DH003904 TO MAKE THIS SAMPLE
DDE QUANT. ION SATURATED, DDE CONCENTRATION IS A MINIMUM
VAL
NS = NO MORE SAMPLE
SAMPLE CONTAINER BROKEN POSSIBLE CONTAMINATION
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE
RERUN OF D070286SN
RERUN FROM C082686CS.C070786KJ
RERUN FROM D082686CS,D070786KJ
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE.
ORIGINAL WAS F070786KJ
ORIGINAL WAS G070786KJ
ORIGINAL WAS I070786KJ
DDE VALUE HIGHER THAN REPORTED, DUE TO TIME CONSTRAINTS
UNABLE TO DILUTE SAMPLE
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE
CONC FOR DDE TAKEN FROM DILUTION
CONC FOR DDE AND 4CL-PCB TAKEN FROM DILUTION
CONC FOR 4CL-PCB TAKEN FROM DILUTION
CONC FOR DDE TAKEN FROM DILUTION
1234678 HPCDD HAS LEVEL OF CONTAMINATION BELOW 1.5 PPT
LEVEL OF CONTAMINATION IN BLANK IS AT 0.6 PPT,
(QA: 2.5 X BLANK LEVEL)
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 123567 HXCDD
AND 3 PPT OF 1234678 HPCDD
234678 HXCDF CONTAIMINATION BELOW 0.5 PPT
BLANK LEVEL AT 0.2 PPT (QA: 2.5 X BLANK LEVEL)
LOW CHRYSENE D12 INTERNAL STD. AREA WILL AFFECT VALUES
LOW CHRYSENE D12 INTERNAL STD. AREA WILL AFFECT VALUES
HIGH CHRYSENE D12 RESPONSE MAY PRODUCE LOWER TA VALUE
FOR THESE ANALYTES RELATED
D-9-1
-------
TABLE D-9(Continued)
Episode SCC No. Comments
3066
3069
3082
3084
3085
3087
3092
3094
3095
3095
3098
3100
3101
3105
3109
3115
3115
3115
3117
3134
3134
3134
3138
3151
3167
3168
3172
3175
DF023504
DF024008
DF023401
DF024109
DF024113
DF023416
DF023502
DC017201
DC038801
DC038802
DC038602
DC019702
DC019901
DF025001
DE025001
DE021301
DE021302
QD01689
DE021501
DE023401
DE023402
DE023406
DE023801
DA009101
DD015708
DD015711
DD015719
DD015802
DC:
DC:
DC:
DC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
SC:
XC:
XC:
XC:
SC:
XC:
DC:
XC:
DC:
DC:
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 123678 HXCDD
AND 0.5 PPT OF 1234678 HPCDD
1234678 HPCDD CONTAMINATION BELOW 1.5 PPT, BLANK
CONTAMINATION AT 0.6 PPT
(GA: 2.5 X BLANK LEVEL)
XENO SAMPLE DILUTED 10:1
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
SAMPLE DILUTED 10:1
NS = NO MORE SAMPLE, XENO ANALYSIS WAS DONE BUT DID NOT
MEET XENO QA
HYDROCARBON PATTERN PRESENT
DDE QUANT ION SATURATED DDE CONCENTRATION IS A MINIMUM
VALUE
CONC FOR DDE TAKEN FROM DILUTION
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
PCB AND DDE-P,F VALUES TAKEN FROM DILUTIONS
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE
PCB VALUES ARE TAKEN FROM DILUTIONS
SAMPLE DILUTED 10:1
4CL-PCB SATURATED SO VALUE REPORTED IS A MINIMUM VALUE
RECEIVED GROUND SAMPLE ID NUMBER IS 89-578-147
RECEIVED GROUND SAMPLE ID NUMBER IS 89-567-150
SAMPLE ID NUMBER IS 89-576-147
DDE QUANT ION SATURATED DDE CONCENTRATION IS A MINIMUM
VALUE
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE
NS = RECEIVED GROUND. NOT ENOUGH SAMPLE FOR ANALYSIS
ALL PCB CONCENTRATIONS TAKEN FROM DILUTION
CONC OF 4CL-PCB TAKEN FROM DILUTION
4CL-PCB SATURATED VALUE REPORTED IS A MINIMUM
CONCENTRATION
ACTUAL OMNIVORE ANALYZED AS BOTTOM FEEDER
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
PENTA WINDOW HAD CHROMATOGRAPHY PROBLEMS
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 123678 HXCDD
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 1234678 HPCDD
D-9-2
-------
TABLE D-9(Continued)
Episode SCCNo. Comments
3182
3185
3206
3206
3212
3212
3213
3219
3231
3245
3252
3259
3259
3259
3266
3272
3272
3282
3282
3283
3288
3288
3289
3290
3299
3300
3303
3306
DD015815
DD015821
DJ024102
DJ024103
DJ024120
DJ024121
DJ024123
DJ023713
DJ023911
DJ023623
QD020989
DB000466
DB000473
DB069101
DY022702
DY022111
DY022112
DY022206
DY022207
DY022209
DY022217
DY022218
DY022220
DY022222
QD040601
DB040201
QD102588
QD041801
DC:
DC:
XC:
DC:
XCi
XC:
XC:
SC:
XC:
XC:
DC:
XC:
XC:
XC:
XC:
XC:
DC:
XC:
XC:
XC:
XC:
XC:
XC:
SC:
XC:
XC:
XC:
XC:
XC:
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 123678 HXCDD
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 1234678 HPCDD
SAMPLE DILUTED 10:1
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 123678 HXCDD AND 0.5
PPTOF 1234678 HPCDD
TO MUCH NOISE IN TRICHLOROBIPHENYL WINDOW (M/Z 256) TO
QUANT
CONCENTRATION FOR DDE TAKEN FROM DILUTION
SAMPLE DILUTED 10:1
WERE RECIEVED GROUND
DDE CONCENTRATIONS CALCULATED FROM DILUTED SAMPLE
DDE CONCENTRATIONS CALCULATED FROM DILUTED SAMPLE
1234678 HPCDD CONTAMINATION BELOW 1.5 PPT, BLANK CONTAMINATION
AT 0.6 PPT, (GA:2.5 X BLANK LEVEL)
DOES NOT PASS GA FOR IODONAPHTHALENE BUT CORRELATES WELL
WITH
CONC FOR DDE, 4CL-PCB & 5CL-PCB ARE TAKEN FROM DILUTION
CONC FOR ALL PCBS TAKEN FROM DILUTION
CONC FOR DDE AND PCBS TAKEN FROM DILUTION
DILUTED SAMPLE BY A FACTOR OF 10:1
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 123678 HXCDD AND 0.5
PPT OF 1234678 HPCDD
SAMPLE DILUTED 10:1
CONC FOR DDE TAKEN FROM DILUTION
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
SAMPLE DILUTED 10:1
CONC FOR DDE TAKEN FROM DILUTION
SAMPLE DILUTED 10:1
NS = NO MORE SAMPLE
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL
SAMPLE
LOW CHRYSENE MAY PRODUCE ELEVATED VALUES FOR TA'S
RELATED TO QUANTIFICATION
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL
SAMPLE
CONC FOR 4CL-PCB TAKEN FROM DILUTION
CONC FOR 4CL-PCB AND 5CL-PCB TAKEN FROM DILUTION
D-9-3
-------
TABLE D-9 (Continued)
Episode SCC No.
3310
3315
3315
3317
3331
3333
3343
3333
3335
3335
3345
3352
3533
3353
3354
3355
3401
3401
3404
3416
3433
3443
3450
3450
3451
3451
DC032701
DC033401
DC033402
DC033602
DD016002
DD016011
DD016108
QD121588
DD029101
QD091588
DD016112
DF023724
DF024121
DF024122
DY022301
DY022303
DD016509
DD016510
DD016516
DF025212
DB069112
DF009118
DY022308
DY022309
DY022310
DY022314
CommentsJ
XC:
XC:
XC:
SC:
XC:
XC:
DC:
XC:
DC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
DC:
DC:
DC:
XC:
XC:
DC:
DC:
DC:
DC:
INTERNAL STD. AREA FOR CHRYSENE WAS LOW
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
CONC FOR DDE TAKEN FROM DILUTION
SAMPLE TO SMALL TO FILLET, GROUND WHOLE
FAILED QA XENOBIOTICS, NO MORE SAMPLE FOR REANALYSIS
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE
PCDD/F: DUPLICATE IS 00121588 PCDD/F BLANK SAMPLE INDICATED
0 .5 PPT OF 123678 HXCDD AND 0.5 PPT OF 1234678 HPCDD
NS = NO MORE SAMPLE XENOBIOTIC ANALYSIS WAS NOT DONE
PCDD/F: DUPLICATE OF QD016011 PCDD/F: BLANK SAMPLE INDICATED
0.5 PPT OF 123678 HXCDD AND 0.5 PPT OF 1234678 HPCDD
XENO: DUPLICATE OF DD091588, DUPLICATE NOT RUN WITH SET WAS
MISTAKENLY REASSIGNED BUT DATA USED FOR PRECISION
XENO: DUPLICATE OF QD029101 NOT RUN WITH SET WAS MISTAKENLY
REASSIGNED BUT USED FOR PRECISION
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
CONC OF DDE TAKEN FROM DILUTION
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
DDE CONC. CALCULATED FROM DILUTION RUN OF ORIGINAL SAMPLE
DDE NUMBER TAKEN FROM DILUTION
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 123678 HXCDD AND 0.5
PPTOF 1234678 HPCDD
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF HXCDD AND 0.5 PPT OF
1234678 HPCDD
NO WEIGHTS GIVEN
CHRYSENE-D12 HIGH RESPONSE MAY GIVE LOWER VALUES FOR
RELATED
SAMPLE DILUTED 10:1
SAMPLE CONTAINS THE FOLLOWING ID NUMBERS: AA 948,949,950,951
SAMPLE CONTAINS THE FOLLOWING ID NUMBERS: AA 952,953,954,955
SAMPLE CONTAINS THE FOLLOWING ID NUMBERS: AA 396,397,398,399
SAMPLE CONTAINS THE FOLLOWING ID NUMBERS: AA 412,413,414,415
D-9-4
-------
APPENDIX D-10
Risk Information for All Sites with Fillet Data
-------
Table D-10
Estimated Cancer Risks from Ingest ion of Fish Contaminated with Total PCBs
(Consumption Rate 6.5 g/day)
Epfaodc Cone, (ng/jQ Estimated Risk Species
Location
3101 5148.1
3117 5108.2
3259 4539.41
3141 4117
2328 3937.22
3306 3172.03
2329 2109.36
3094 1961.58
3HO 1804.4
3113 1614.8
3193 10643
3120 854.05
3125 792.96
3182 780.42
3115 757.5
3303 755.66
3428 697.8
3118 666.3
3258 629.76
3299 610.32
3104/2212* 589
3415 588.7
3314 502.84
3301 474.21
2410 422.66
3444 380.1
3100 370.17
3414 364.8
3148 363.9
3172 293.6
3412 274.7
3097 270.28
3409*72709 256.9
3312 250.37
3106+/2608 231.79
3426 213.34
3300 205.47
3427 193.05
3375 176.6
3.7xlO"3
3.7x10°
3.3x10°
2.9x10°
2.8x10°
2.3xlO'3
1.5xlO'3
1.4x10°
1.3x10°
1.6x10°
7.6xlO'4
6. IxlO'4
5.7x10^
5.6xlO"4
5.4xlO"4
5.4xlO'4
4.9xlO'4
4,8xlO'4
4.5xlO'4
4.4xlO"4
4.2xlO'4
4.2xlO'4
3.6xlO'4
3.4xlO'4
3.0xlO'4
2.7xlO'4
2.7xlO'4
2.6x1 0'4
2.6xlO'4
2.1xlO"4
2.0x1 0'4
1.9xlO'4
l.SxlO'4
l.SxlO'4
1.7xlO'4
1.5xIO'4
l.SxlO'4
1.4xlO'4
1.3X10"4
Brown Trout
Lake Trout
Lm Bass
Northern Pike
Chinook Salmon
Sm Bass
Brown Trout
Channel Catfish
Carp
Carp/Channel Catfish
Sm Bass
Bass
White Bass
Rock Bass
Catfish
Sm Bass
Bluefish
Walleye
Spot
Lm Bass
Sm Bass/Lin Bass
Channel Catfish/Sm Bass
White Bass
Northern Pike
Sm Bass
Channel Catfish/Lm Bass
White Perch
Channel Catfish/Sm Bass
Walleye
Lm Bass
Sm Bass
Brown Bullhead
Lm Bass
Sm Bass
Walleye
Bluefish
Sm Bass
Bluefish
Lm Bass
PA - Paoli - Little Valley Creek
IL - Waukegan - Lake Michigan
NY - Fort Miller - Hudson R.
WI - Milwaukee - Milwaukee R.
NY - Olcott - Lake Ontario
NY - Massena - Grass R.
NY - Rochester - Lake Ontario
PA - Torresdale - Delaware R.
WI -Hudson- St. CroixR.
IL - Geneva- Fox R.
VA - Brookneal - Roanoke R.
MI - Saugatuck - Kalamazoo R.
MN - Red Wing - Mississippi R.
KY-Russellville-MudR.
IL - East St. Louis - Mississippi River below Sauget
NY - Newton Falls - Oswegatchie R.
NJ - Newark - Passaic R.
MI - Escanaba - Escanaba R.
VA - Norfolk - S. Br. Elizabeth R.
NY - N. Tonawanda - Niagara R.
PA - Philadelphia - Schuylkill R.
PA - Ransom - N Br. Susquehanna R.
WV - Wmfield - Kanawha R.
NY - Olcott - Eighteen Mile Creek
MI - River Rouge - Rouge R.
TN - Memphis - Mississippi R.
MD - Baltimore - Baltimore Harbor
PA - Pittston - Susquehanna R.
MI - Muskegon - Muskegon Lake
AL /GA- State Line - Coosa R.
NY - Oswego - Oswego Harbor
DE - Tybouts Corner - Red Lion Creek
NY -Peekskill- Hudson R.
WV- Wheeling- Ohio R.
WI - U. Pentenwell Flow - Wisconsin R.
NJ - Carteret - Arthur Kill R.
NY - Porter - Niagara R. Delta
NJ - Elizabeth - Newark Bay
GA - Austell - Chattahoochee R.
* Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-J
-------
Table D-10 PCBs (cont)
Episode Cone, (ng/g) Estimated Rl»k Spec lea Location
3063 163.17
30% 153.09
3070 141.08
3377 137.95
3068 136.39
3065 133.2
3304 127.2
3298 126.25
3419 117.92
335S 113.45
3310 101.01
3183 93.79
3302 93.6
3305 85.83
3311 83.22
3420 82.35
3048 80.31
3403 80.05
3085 77.4
3090 74.7
3114 74
3146 68.72
3288 59.37
3218 55.6
3079 55.21
3376 53.77
3046/2199* 42.63
2356 39.62
3108 37.85
3216 37.1
3350 34,07
3188 32.02
3184/2133* 30.74
3401 29.66
3354 25.58
3313 24.98
3219 23.91
3066 21.16
3429 16.98
3336 15.25
3112 12.2
3069 11.48
3081 10.45
3080 10.34
1.2xlO'4
l.lxlQ-4
l.OxlO'4
9.9xlO"5
9.8xlO'5
9.5xlO'5
9.1xlO'5
9.0xlO'5
8.4xlO'5
S.lxlO'5
7.2xlO"5
6.7xlO"5
6.7xlO'5
6.1xlO"5
5.9xlO"5
5.9xlO"5
5.7xlO"5
5.7xlO'5
5.5xlO'5
5.3xlO'3
5.3xlO'3
4.9X10'3
4.2xlO'5
4.0xlO'5
4.0xlO'5
3.8xlO'5
3.1xlO"5
2.8xlO'5
2.7xlO'5
2.7xIO"5
2.4xlO'5
2.3xlO'5
2.2x1 0"5
2.1xlO'5
l.SxlO'5
l.SxlO'5
1.7xlO'5
l.SxlO'5
1.2xlO'5
l.lxlO'5
8.7X10"6
%.2x\Q'6
7.5xlO'6
7.4xlO'6
* Asterisk indicates episode number
Species listed is for
Spotted Seatrout
Brown Bullhead
Sheepshead
Lm Bass
All. Croaker
Bigmouth Buffalo
Northern Pike
Lm Bass
Freshwater Drum
Lm Bass
Walleye
Sauger
Lm Bass
Sm Bass
Sm Bass
Green Sunfish
White Bass
Lm Bass
Black Drum
White Crappie
Carp
Walleye
Squawfish
Squawfish.
White Bass
Lm Bass
Lm Bass
Lm Bass
Walleye
Squawfish
Lm Bass
Lm Bass
Blue Catfish
Lm Bass
Lm Bass
Sm Bass
White Sturgeon
Freshwater Drum
Weakfish
Spotted Seatrout
Walleye
Trout
White Bass
Lm Bass
associated with sample
LA - Moss Lake - Calcasieu R.
PA - Eddystone - Delaware R.
TX - Port Arthur - Heches R. (tidal)
GA - Franklin - Chattahoochee R.
TX - Morgan Point - Houston Ship Channel
LA - Baton Rouge - Mississippi R.
NY - Dexter - Black River Delta
NY -Buffalo- Buffalo R.
PA - Erie - Lake Erie
CA - Stockton - Old Mormon Slough
PA - Easton - Lehigh R.
KY - Catlettsburg - Big Sandy R.
NY - Lewiston - Niagara R.
NY - Massena - Raquette R.
WV - New Martinsville - Ohio R.
PA - Spring Grove - Codorus Creek
MO - West Alton - Mississippi R.
TN - Kingsport - S. Fork Holston R.
TX - Freeport - Brazos R.
OK - Pyrer Creek - Fort Gibson Reservoir
IL - Quincy - Mississippi R.
WI - Rothschild - Wisconsin R.
CA - Salinas - Blanco Drain
OR - Wauna - Columbia R.
OK - Kaw Reservoir
G A - Whitesburg - Chattahoochee R.
MO - Lexington - Missouri R.
ME - Lewiston - Androscoggin R.
WI - Merrill - Wisconsin R.
OR - St. Helens - Columbia R.
TN - Calhoun - Hiwassee R.
TN - Nickajack Reservoir
MS - Redwood - Yazoo R.
TN - Hardin Co. - Tennessee R.
C A - Stockton - New Mormon Slough
WV - Bedington - Opequon Creek
OR - Dalles - Columbia R.
LA - Union - Mississippi R.
NJ- Salem- Delaware R.
GA - St. Marys - North R. (mouth)
MN - Little Falls - Mississippi R.
TX - Corpus Christi - Inner Harbor
TX - Lufkin - Lake Sam Rayburn
LA - Monroe - Ouachita R.
actually used for the risk calculations.
the sample used.
D-10-2
-------
Episode
3089
3290
3282
3348
3231
3083
3252
3168
3249
3092
2228
3036/2190
3088
3093
3105
3180
3212
3266
3267
3308
3346
3421
3422
Cone, (nff
6.93
6.62
6.1
6.04
2.89
1.49
1.38
1.36
1.27
0.07
ND
* ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
f) Estimated Risk
S.OxlO'6
4.7xlO'6
4.4xlO'6
4.3xlO'6
2. IxlO"6
l.lxlO'6
9.9xlO"7
9.7xlO'7
9. IxlO'7
S.OxlO"8
—
--
--
--
—
--
-
-
—
—
—
—
--
Table D-10 PCBs
Species
White Crappie
Redear Sunfish
Flathead Catfish
White Perch
Sm Bass
Lm Bass
Lm Bass
Lm Bass
Brook Trout
Warmouth
Longear Sunfish
Bluegill
Blue gill
Lm Bass
Lm Bass
Lm Bass
Catfish
Black Crappie
Rainbow Trout
Northern Pike
Lm Bass
White Perch
Lra Bass
(cont)
Location
OK - Muskogee - Webbers Falls
CA - Stockton - Port of Stockton
CA - Calipatria - Alamo R.
SC - Georgetown - Sampit R.
WA - Richland - Yakima R.
LA - Oak Ridge - Bayou Bonne Idee
ID -Parma- Boise R.
AL - Mobile - Cold Creek
ID - Coeur d'Alene - Coeur d'Alene R.
LA - Hedge - Dugdemona R.
VA - Cartersville - James R.
I A - Hamburg - Nishnabotna R.
LA - Deridder - Anacoco Bayou
TX-Diboll-NechesR.
OK - Fort Cobb - Fort Cobb Reservoir
GA - Early County - Spring Creek
OR - Owyhee - Owyhee R.
AZ -GilaBend -GilaR.
CA - Anderson - Sacramento R.
NY - Rouses Pt, - Richelieu R.
NC - Plymouth - Roanoke R.
VA - Covington - Jackson R.
VA - Riverdale - Backwater R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-IO-3
-------
D-10-4
-------
Table D-10 (cont)
Estimated Cancer Risks from Ingestion of Fish Contaminated with DDE
(Consumption Rate 6.5 g/day)
Epfaode Cone, (pg'g) Estimated Rlik Spectei
Location
3282 ;
3117
3288
3444
3094
2328
3113
3212
2329
3184/2133*
3141
3193
3118
3219
3115
3083
3110
3148
3252
3097
3266
3105
3401
3168
3231
3428
3258
3412
3218
3046/2199*
3114
3415
3300
3120
3301
30%
3216
3414
3104/2212*
3172
2820
1891
1433
1243.8
984
682
568
517
415
343.2
291
201
180
136
104
93.2
91.5
85.7
84
77.72
77.1
75.9
68
65.4 :
63.6 :
60.2
58.31
55.6
52
48.8
46.6
45.2
41.4
35.6
35.5
34.38
34.3
34
33.9
32.1
8.9xlO'5
6.0xlO"5
4.5xlO'5
3.9xlO'5
3.1xlO'5
2.2xlO'5
1.8xlO-S
1.6xlO'5
1.3xlO'5
l.lxlO'5
9.2x10^
5. 3x10*
5.7x10*
4.3x10*
3.3x10*
2.9x10*
2.9x10*
2.7x10*
2.7x10*
2.5xlO~6
2.4x10*
2.4xlO"6
2.1x10*
2. IxlO'6
1.0x10*
.9x10*
.8x10*
.8x10*
.6x10*
.5xlO*
.5x10*
.4x10*
.3x10*
.1x10*
.1x10"*
.IxlO"6
.1x10*
.1x10^
.IxlO'6
.0x10*
Flathead Catfish
Lake Trout
Squawfish
Channel Catfish/Lm Bass
Channel Catfish
Chinook Salmon
Carp/Channel Catfish
Catfish
Brown Trout
Blue Catfish/W. Crappie
Northern Pike
Sm Bass
Walleye
White Sturgeon
Catfish
Lm Bass
Carp
Walleye
Lm Bass
Brown Bullhead
Black Crappie
Lm Bass
Lm Bass
Lm Bass
Sm Bass
Bluefish
Spot
Sm Bass
Squawfish
Lm Bass
Carp
Channel Catfish/Sm Bass
Sm Bass
Bass
Northern Pike
Brown Bullhead
Squawfish
Channel Catfish/Sm Bass
Sm Bass/Lm Bass
Lm Bass
CA - Calipatria - Alamo R.
IL - Waukegan - Lake Michigan
CA - Salinas - Blanco Drain
TN - Memphis - Mississippi R.
PA - Torresdale - Delaware R.
NY - Olcott - Lake Ontario
IL -Geneva -FoxR.
OR - Owyhee - Owyhee R.
NY - Rochester - Lake Ontario
MS - Redwood - Yazoo R.
WI - Milwaukee - Milwaukee R.
VA - Brookneal - Roanoke R.
MI - Escanaba - Escanaba R.
OR - Dalles - Columbia R.
IL - East St. Louis - Mississippi River below Sauget
LA - Oak Ridge - Bayou Bonne Idee
WI -Hudson- St. CroixR.
MI - Muskegon - Muskegon Lake
ID - Parma - Boise R.
DE - Tybouts Corner - Red Lion Creek
AZ -GilaBend-GilaR.
OK - Fort Cobb - Fort Cobb Reservoir
TN - Hardin Co. - Tennessee R.
AL - Mobile - Cold Creek
WA - Richland - Yakima R.
NJ - Newark - Passaic R.
VA - Norfolk - S. Br. Elizabeth R.
NY - Oswego - Oswego Harbor
OR - Wauna - Columbia R.
MO - Lexington - Missouri R.
IL - Quincy - Mississippi R.
PA - Ransom - N. Br. Susquehanna R.
NY - Porter - Niagara R. Delta
MI - Saugatuck - Kalamazoo R.
NY - Olcott - Eighteen Mile Creek
PA - Eddystone - Delaware R.
OR - St. Helens - Columbia R.
PA - Pittston - Susquehanna R .
PA - Philadelphia - Schuylkill R.
AL/GA - State Line - Coosa R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-5
-------
Table D-10 DDE (cont)
Episode Cone. (pg/g) Estimated Rhk Specteg Location
3065 31.3
3125 30.6
3426 27.2
3079 23.21
3355 22.1
3299 21.7
3304 20.7
3302 19.8
3313 19.48
3100 18.81
3101 18.8
2410 15.3
3085 14.97
3409*/2709 14.3
3354 14.1
3306 13.5
3290 13.3
3048 13.1
3180 13.1
3310 12.4
3068 12.2
3298 11.5
3377 11.42
3080 10.66
3420 10.31
3081 10.3
3429 10.2
3314 10
3305 9.75
3066 9.49
3419 9.47
3063 8.54
3375 8.22
3350 6.27
3106*/2608 5.57
3259 5.37
3312 5.33
3112 4.69
3036/2190* 4.61
3346 4.45
3376 4.38
3422 4.35
3267 3.9
3348 3.85
9.9xlO'7
9.7xlO"7
8.6xlO'7
7.3xlO'7
7.0xlO"7
6.9xlO'7
6.5xlO'7
6.3xlO"7
6.2xlO'7
5.9xlO'7
5.9xlO'7
4.8xlO'7
4.7xlO'7
4.5xlO'7
4.5xlO'7
4.3xlO'7
4.2xlO'7
4.1xlO"7
4.1xlO'7
3.9xlO'7
3.9xlO'7
3.6xlO"7
3.6xlO'7
3.4xlO'7
3.3xlO'7
3.3xlO'7
3.2xlO'7
3.2xlO'7
3.1xlO'7
3.0xlO'7
3.0xlO'7
2.7xlO'7
2.6xlO'7
2.0x1 0'7
l.SxlO'7
1.7xlO'7
1.7xlO'7
l.SxlO'7
l.SxlO'7
1.4xlO'7
1.4xlO'7
1.4xlO'7
1.2xlO'7
1.2xlO"7
* Asterisk indicates episode number
Species listed is for
Bigmouth Buffalo
White Bass
Bluefish
White Bass
Lm Bass
Lm Bass
Northern Pike
Lm Bass
Sm Bass
White Perch
Brown Trout
Sm Bass
Black Drum
Lm Bass
Lm Bass
Sm Bass
Redear Sunfish
White Bass
Lm Bass
Walleye
Atl. Croaker
Lm Bass
Lm Bass
Lm Bass
Green Sunfish
White Bass
Weakfish
White Bass
Sm Bass
Freshwater Drum
Freshwater Drum
Spotted Seatrout
Lm Bass
Lm Bass
Walleye
Lm Bass
Sm Bass
Walleye
Bluegill
Lm Bass
Lm Bass
Lm Bass
Rainbow Trout
White Perch
associated with sample
LA - Baton Rouge - Mississippi R.
MN - Red Wing - Mississippi R.
NJ - Carteret - Arthur Kill R.
OK - Kaw Reservoir
CA - Stockton - Old Mormon Slough
NY - N. Tonawanda - Niagara R.
NY - Dexter - Black River Delta
NY - Lewiston - Niagara R.
WV - Bedington - Opequon Creek
MD - Baltimore - Baltimore Harbor
PA - Paoli - Little Valley Creek
MI - River Rouge - Rouge R.
TX - Freeport - Brazos R.
NY -Peekskill- Hudson R.
CA - Stockton - New Mormon Slough
NY - Massena - Grass R.
CA - Stockton - Port of Stockton
MO - West Alton - Mississippi R.
G A - Early County - Spring Creek
PA - Eastern -LehighR.
TX - Morgan Point - Houston Ship Channel
NY -Buffalo- Buffalo R.
GA - Franklin - Chattahoochee R.
LA - Monroe - Ouachita R.
PA - Spring Grove - Codorus Creek
TX - Lufkin - Lake Sam Rayburn
NJ - Salem - Delaware R.
WV - Winfield - Kanawha R.
NY - Massena - Raquette R.
LA - Union - Mississippi R.
PA -Erie -Lake Erie
LA - Moss Lake - Calcasieu R.
GA - Austell - Chattahoochee R.
TN - Calhoun - Hiwassee R.
WI - U. Pentenwell Flow - Wisconsin R.
NY - Fort Miller - Hudson R.
WV - Wheeling - Ohio R.
MN - Little Falls - Mississippi R.
I A - Hamburg - Nishnabotna R.
NC - Plymouth - Roanoke R.
GA - Whitesburg - Chattahoochee R.
VA - Riverdale - Blackwater R.
CA - Anderson - Sacramento R
SC - Georgetown - Sampit R.
actually used for the risk calculations.
the sample used.
D-10-6
-------
Episode
Table D-10 DDE (cont)
Cone. (pg/R> Estimated Risk Species Location
3403
3069
3182
2356
3188
3421
3308
3089
3088
3108
3183
3249
3303
3146
3311
3090
2228
3092
3093
3070
3336
3427
3.4
3.33
3.16
3.02
2.85
2.76
2.49
2.46
2.09
2.06
2
1.99
1.81
1.78
1.51
1.48
1.09
0.81
0.76
0.56
ND
ND
l.lxlO'7
l.lxlO'7
l.OxlO'7
9.5xlO'8
9.0xlO'8
8.7xlO'8
7.9xlO'8
7.8xlO'8
6.6xlO'8
6.5xlO'8
6.3xlO'8
6.3xlO'8
5.7xlO'8
5.6xlO'8
4.8xlO'8
4.7xlO'8
3.4xlO"8
2.6x1 0'8
2.4x1 0'8
l.SxlO'8
--
-
Lm Bass
Trout
Rock Bass
Lm Bass
Lm Bass
White Perch
Northern Pike
White Crappie
Blue gill
Walleye
Sauger
Brook Trout
Sm Bass
Walleye
Sm Bass
White Crappie
Longear Sunfish
Warmouth
Lm Bass
Sheepshead
Spotted Seatrout
Bluefish
TN - Kingsport - S. Fork Holston R.
TX - Corpus Christi - Inner Harbor
KY - Russellville - Mud R
ME - Lewiston - Androscoggin R ,
TN - Nickajack Reservoir
VA - Covington - Jackson R.
NY - Rouses Pt. - Richelieu R.
OK - Muskogee - Webbers Falls
LA - Deridder - Anacoco Bayou
WI - Merrill - Wisconsin R.
KY - Catlettsburg - Big Sandy R.
ID - Coeur d'Alene - Coeur d'Alene R.
NY - Newton Falls - Oswegatchie R.
WI - Rothschild - Wisconsin R.
W V - New Martinsville - Ohio R.
OK - Pyrer Creek - Fort Gibson Reservoir
VA - Cartersville - James R.
LA - Hedge - Dugdemona R.
TX-Diboll-NechesR.
TX - Port Arthur - Neches R. (tidal)
GA - St. Marys - North R. (mouth)
NJ - Elizabeth - Newark Bay
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-IO-7
-------
D-10-8
-------
Table D-lO(cont)
Estimated Risks from Ingestion of Fish Contaminated with Dieldrin
(Consumption Rate 6.5 g/day)
Epfaode Cone, (ng/g) Estimated Risk Specks
Location
3117
3114
3288
3094
3212
3046/2199*
3115
2328
3141
2329
3282
3444
3048
3118
3184/2133*
3258
3414
3036/2190*
3068
3101
3415
3113
3079
3193
3148
3066
3110
3420
3100
3375
3096
3063
3104*/2212
3252
3231
3125
3314
3419
3312
3310
405
187
174
83.5
74.3
70.4
55.3
53.5
50
47.3
44
36.6
26.2
16
15.4
14.99
14.7
14.7
13.4
13.1
11.4
11.1
9.%
9.76
9.37
8.28
7.73
7.59
7.47
7.06
6,89
5.91
5.6
5.5
5.32
5.17
4.79
4.78
4.55
4.5
6.0xlO'4
2.8XIO"4
2.6X10"4
1.2xlO'4
l.lxlO"4
1.1 xlO'4
8.2xlO'5
8.0xlO'S
7.4xlO'3
7.0xlO'5
6.5xlO"5
5.4xlO'5
3.9xlO'5
2.4x1 0'5
2.3xlO"5
2.2xlO"5
2.2xlO"5
2.2xlO'5
2.0x1 0'5
2-OxlO"3
.7xlO'5
.7xlO'5
.5xlO'5
.5xlO'5
.4xlO'5
.2x1 0'5
.IxlO'5
l.lxlO'5
l.lxlO'5
l.OxlO'5
l.OxlO'5
S.SxlO"6
8.3xlO'6
8.2X10"6
7.9X10"6
7.7xlO'6
7.1X10"6
7.1xlO'6
6.8X10"6
6.7x10"*
Lake Trout
Carp
Squawfish
Channel Catfish
Catfish
Lm Bass
Catfish
Chinook Salmon
Northern Pike
Brown Trout
Flathead Catfish
Channel Catfish/Lm Bass
White Bass
Walleye
Blue Catfish
Spot
Channel Catfish
Bluegill
Atl. Croaker
Brown Trout
Channel Catfish
Channel Catfish
White Bass
Sm Bass
Walleye
Freshwater Drum
Carp
Green Sunfish
White Perch
Lm Bass
Brown Bullhead
Spotted Seatrout
Lm Bass/Sin Bass
Lm Bass
Sm Bass
White Bass
White Bass
Freshwater Drum
Sm Bass
Walleye
IL - Waukegan - Lake Michigan
IL - Quincy - Mississippi R.
CA - Salinas - Blanco Drain
PA - Torresdale -Delaware R.
OR - Owyhee - Owyhee R.
MO - Lexington - Missouri R.
IL - East St. Louis - Mississippi Riwr below Sauget
NY - Olcott - Lake Ontario
WI - Milwaukee - Milwaukee R.
NY - Rochester - Lake Ontario
CA - Calipatria - Alamo R.
TN - Memphis - Mississippi R.
MO - West Alton - Mississippi R.
MI - Escanaba - Escanaba R.
MS - Redwood - Yazoo R.
VA - Norfolk - S. Br. Elizabeth R.
PA - Pittston - Susquehanna R.
IA - Hamburg - Nishnabotna R.
TX - Morgan Point - Houston Ship Channel
PA - Paoli - Little Valley Creek
PA • Ransom - N. Br. Susquehanna R.
IL - Geneva - FoxR.
OK - Kaw Reservoir
VA - Brookneal - Roanoke R.
MI - Muskegon - Muskegon Lake
LA - Union - Mississippi R.
WI - Hudson - St. CroixR.
PA - Spring Grove - Codorus Creek
MD - Baltimore - Baltimore Harbor
GA - Austell - Chattahoochee R.
PA - Eddystone - Delaware R.
LA - Moss Lake - Calcasieu R.
PA - Philadelphia - Schuylkill R.
ID - Parma - Boise R.
WA - Richland - Yakima R.
MN - Red Wing - Mississippi R.
WV - Winfield - Kanawha R.
PA -Erie -Lake Erie
WV- Wheeling- Ohio R.
PA - Easton - Lehigh R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-IO-9
-------
Epltodc
Table D-10 Dkldrln (cont)
Cone, (n^g) Eitlmatcd Rltk Speclet Location
3428
3120
2410
3426
3403
3301
3299
3065
3377
3412
3300
3311
3348
3081
2228
2356
3069
3070
3080
3083
3085
3088
3089
3090
3092
3093
3097
3105
3106*/2608
3108
3112
3146
3168
3172
3180
3182
3183
3188
3216
3218
3219
3249
3259
3266
4.47
4.36
4.3
4.13
3.97
3.86
3.69
3.61
3.37
2.59
2.53
1.18
0.%
0.62
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.6x10"*
6.5xlO"6
6.4x10"*
6.1x10"*
5.9x10"*
5.7x10-*
5.5x10"*
5.4x10"*
5.0x10"*
3.9x10"*
3.8x10"*
1.8x10"*
1.4x10"*
9.2xlO"7
--
--
-
--
--
--
-
--
--
--
--
—
—
—
-
—
—
~
--
—
—
~
—
-
—
—
—
—
—
—
* Asterisk indicates episode number
Species listed is for
Bluefish
Bass
Sm Bass
Bluefish
Lm Bass
Northern Pike
Lm Bass
Bigmouth Buffalo
Lm Bass
Sm Bass
Sm Bass
Sm Bass
White Perch
White Bass
L on gear Sunfish
Lm Bass
Trout
Shecpshead
Lm Bass
Lm Bass
Black Drum
Bluegill
White Crappie
White Crappie
Warmouth
Lm Bass
Brown Bullhead
Lm Bass
Walleye
Walleye
Walleye
Walleye
Lm Bass
Lm Bass
Lm Bass
Rock Bass
Sauger
Lm Bass
Squawfish
Squawfish
White Sturgeon
Brook Trout
Lm Bass
Black Crappie
associated with sample
NJ - Newark - Passaic R.
MI - Saugatuck - Kalamazoo R.
MI - River Rouge - Rouge R.
NJ - Carteret - Arthur Kill R.
TN - Kingsport - S. Fork Holston R.
NY - Olcott - Eighteen Mile Creek
NY - N. Tonawanda - Niagara R.
LA - Baton Rouge - Mississippi R.
GA - Franklin - Chattahoochee R.
NY - Oswego - Oswego Harbor
NY - Porter - Niagara R. Delta
W V - New Martinsville - Ohio R.
SC - Georgetown - Sampit R.
TX - Lufkin - Lake Sam Raybum
VA - Cartersville - James R.
ME - Lewiston - Androscoggin R.
TX - Corpus Christi - Inner Harbor
TX - Port Arthur - Neches R. (tidal)
LA - Monroe - Ouachita R.
LA - Oak Ridge - Bayou Bonne Idee
TX - Freeport - Brazos R.
LA - Deridder - Anacoco Bayou
OK - Muskogee - Webbers Falls
OK - Pyrer Creek - Fort Gibson Reservoir
LA - Hodge - Dugdemona R.
TX-Diboll- Neches R.
DE - Tybouts Corner - Red Lion Creek
OK - Fort Cobb - Fort Cobb Reservoir
Wl - U. Pentenwell Flow - Wisconsin R.
WI - Merrill - Wisconsin R
MN - Little Falls - Mississippi R.
WI - Rothschild - Wisconsin R.
AL - Mobile - Cold Creek
AL/GA - State Line - Coosa R.
G A - Early County - Spring Creek
KY - Russellville - Mud R.
KY - Catlettsburg - Big Sandy R.
TN - Nickajack Reservoir
OR - St. Helens - Columbia R.
OR - Wauna - Columbia R
OR - Dalles - Columbia R.
ID - Coeur d'Alene - Coeur d'Alene R.
NY - Fort Miller - Hudson R.
AZ -GilaBend-GilaR.
actually used for the risk calculations.
the sample used.
D-10-10
-------
Table D-10 Dieldrln (cont)
Epliode Cone, (ngfg) Eitimated Risk Species Location
3267
3290
3298
3302
3303
3304
3305
3306
3308
3313
3336
3346
3350
3354
3355
3376
3401
3409*/2709
3421
3422
3427
3429
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Rainbow Trout
Redear Sunfish
Lm Bass
Lm Bass
Sm Bass
Northern Pike
Sm Bass
Sra Bass
Northern Pike
Sm Bass
Spotted Seatrout
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
White Perch
Lm Bass
Bluefish
Weakfish
CA
CA
NY
NY
NY
NY
NY
NY
NY
WV
GA
NC
TN
CA
CA
GA
TN
NY
VA
VA
NJ-
NJ-
- Anderson - Sacramento R.
- Stockton - Port of Stockton
-Buffalo- Buffalo R.
- Lewiston - Niagara R.
- Newton Falls - Oswegatchie R.
- Dexter - Black River Delta
- Massena - Raquette R.
- Massena - Grass R.
- Rouses Pt. - Richelieu R.
- Bedington - Opequon Creek
- St. Marys - North R. (mouth)
- Plymouth - Roanoke R.
- Calhoun - Hiwassee R.
- Stockton - New Mormon Slough
- Stockton - Old Mormon Slough
- Whitesburg - Chattahoochee R.
- Hardin Co. - Tennessee R.
- Peekskill - Hudson R.
- Covington - Jackson R.
- Riverdale - Blackwater R.
Elizabeth - Newark Bay
Salem - Delaware R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-11
-------
D-10-12
-------
Table D-10 (cont)
Estimated Risks from Digestion of Fish Contaminated with Combined Chlordane
(Combined Chlordane is the sum of cis - and trans - chlordane,
cis - and trans - nonachlor, and oxychlordane)
(Consumption Rate 6.5 g/day)
Epliode Cone, (ng/g) Estimated Risk Species
Location
3117 770
3094 291.4
2328 206.28
3444 198.3
3114 160.5
3141 129.03
3115 125.94
2329 114.41
3113 97.6
3046/2199* 89.84
3193 71.23
3314 57.36
3118 53.6
3258 51.27
3079 49.72
3375 40.7
3415 40.08
3148 36.75
3312 30.35
3100 29.48
3068 28.36
3104/2212* 28
3282 27.56
3414 24.3
3428 23.57
3377 23.09
3063 22.35
3101 21.28
3048 20.59
3096 17.11
3120 15.8
3097 15.02
3403 13.77
3184/2133* 13.69
3427 12.18
3412 11.31
3110 10.87
9.3xlO'5
3.5xlO'5
2.5xlO'J
2.4xlO'5
1.9xlO'5
1.6xlO'S
1.5xlO"J
1.4xlO'J
1.2xlO'5
l.lxlO'5
8.6xlO'6
6.9xlO-6
6.5xlO'6
6.2xlO-6
6.0xlO'6
4.9xlO'6
4.8x10"*
4.4x10"*
3.7xlO'6
3.6xlO'6
3.4x10^
3.4xlO"6
3.3xlO'6
2.9xlO"6
2.8xlO'6
2.8xlO'6
2.7xlO"6
2.6xlO'6
2.5xlO'6
2.1X10"6
1.9xlO'6
l.SxlO'6
1.7X10"6
1.7X10"6
l.SxlO'6
1. 4x1 0"6
1.3X10"6
Lake Trout
Channel Catfish
Chinook Salmon
Channel Catfish/Lm Bass
Carp
Northern Pike
Catfish
Brown Trout
Carp/Channel Catfish
Lm Bass
Sm Bass
White Bass
Walleye
Spot
White Bass
Lm Bass
Channel Catfish
Walleye
Sm Bass
White Perch
Atl. Croaker
Sm Bflss/Lm Bass
Flathead Catfish
Channel Catfish
Bluefish
Lm Bass
Spotted Seatrout
Brown Trout
White Bass
Brown Bullhead
Bass
Brown Bullhead
Lm Bass
Blue Catfish
Bluefish
Sm Bass
Carp
IL - Waukegan - Lake Michigan
PA - Torresdale - Delaware R.
NY - Olcott - Lake Ontario
TN - Memphis - Mississippi R.
IL - Quincy - Mississippi R.
WI - Milwaukee - Milwaukee R.
IL - East St. Louis - Mississippi Riwr below Sauget
NY - Rochester - Lake Ontario
IL - Geneva- Fox R.
MO - Lexington - Missouri R
VA - Brookneal - Roanoke R.
W V - Wmfield - Kanawha R.
MI - Escanaba - Escanaba R.
VA - Norfolk - S. Br. Elizabeth R.
OK - Kaw Reservoir
G A - Austell - Chattahoochee R.
PA - Ransom - N. Br. Susquehanna R.
MI - Muskegon - Muskegon Lake
WV- Wheeling- Ohio R.
MD - Baltimore - Baltimore Harbor
TX - Morgan Point - Houston Ship Channel
PA - Philadelphia - Schuylkill R .
CA - Cah'patria - Alamo R.
PA - Pittston - Susquehanna R.
NJ - Newark - Passaic R.
GA - Franklin - Chattahoochee R.
LA - Moss Lake - Calcasieu R.
PA - Paoli - Little Valley Creek
MO - West Alton - Mississippi R.
PA - Eddystone - Delaware R.
MI - Saugatuck - Kalamazoo R.
DE - Tybouts Corner - Red Lion Creek
TN - Kingsport - S. Fork Holston R.
MS - Redwood - Yazoo R.
NJ - Elizabeth - Newark Bay
NY - Oswego - Oswego Harbor
WI - Hudson - St. CroixR.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-JO-J3
-------
Table D-10 Chlordanc (cont)
Epbode Cone, (nf/f) Estimated Rlik Speclet Location
3212 10.61
3426 10.14
3065 10.02
3313 8.95
3376 8.88
3311 8.81
3310 8.36
3419 6.8
3288 6.11
3300 6.05
3299 5.59
3301 5.55
3350 5.5
2410 5.49
3125 5.37
3183 4.61
3081 4.5
3066 4.39
3420 4.12
3218 3.4
3219 3.4
3421 3.38
3409*72709 3. 17
3302 2.76
3090 2.46
3401 2.15
3304 2.04
3355 2.02
3267 1.94
3188 1.83
3216 1.75
3306 1.53
3182 1.38
3354 0.98
3298 0.83
3336 0.69
2228 ND
2356 ND
3036/2190* ND
3069 ND
3070 ND
3080 ND
3083 ND
3085 ND
1.3xlO'6
1.2xlO'6
1.2X10"6
l.lxlO"6
l.lxlO"6
l.lxlO'6
l.OxlO"6
8.2xlO'7
7.4xlO'7
7.3xlO'7
6.7xlO"7
6.7xlO'7
6.6xlO"7
6.6xlO'7
6.5xlO'7
5.6xlO'7
5.4xlO"7
5.3xlO'7
S.OxlO'7
4.1xlO"7
4.1xlO'7
4. IxlO"7
3.8xlO'7
3.3xlO'7
3.0xlO"7
2.6xlO'7
2.5xlO'7
2.4xlO"7
2.3xlO'7
2.2xlO'7
2.1xlO'7
LSxlO'7
1.7xlO'7
1.2xlO'7
l.OxlO'7
8.3xlO'8
--
~
--
--
--
--
—
"
Catfish
Bluefish
Bigmouth Buffalo
Sm Bass
Lm Bass
Sm Bass
Walleye
Freshwater Drum
Squawfish
Sm Bass
Lm Bass
Northern Pike
Lm Bass
Sm Bass
White Bass
Sauger
White Bass
Freshwater Drum
Green Sunfish
Squawfish
White Sturgeon
White Perch
Lm Bass
Lm Bass
White Crappie
Lm Bass
Northern Pike
Lm Bass
Rainbow Trout
Lm Bass
Squawfish
Sm Bass
Rock Bass
Lm Bass
Lm Bass
Spotted Seatrout
Longear Sunfish
Lm Bass
Bluegill
Trout
Sheepshead
Lm Bass
Lm Bass
Black Drum
OR - Owyhee - Owyhee R.
NJ - Carteret - Arthur Kill R.
LA - Baton Rouge - Mississippi R.
WV - Bedington - Opequon Creek
GA - Whitesburg - Chattahoochee R.
WV - New Martinsville - Ohio R.
PA-Easton-LehighR.
PA - Erie - Lake Erie
CA - Salinas - Blanco Drain
NY - Porter - Niagara R. Delta
NY - N. Tonawanda - Niagara R.
NY - Olcott - Eighteen Mile Creek
TN - Calhoun - Hiwassee R.
MI - River Rouge - Rouge R.
MN - Red Wing - Mississippi R.
KY - Catlettsburg - Big Sandy R.
TX - Lufkin - Lake Sam Rayburn
LA - Union - Mississippi R.
PA - Spring Grove - Codorus Creek
OR - Wauna - Columbia R.
OR - Dalles - Columbia R.
VA - Covington - Jackson R.
NY - Peekskill - Hudson R.
NY - Lewiston - Niagara R.
OK - Pyrer Creek - Fort Gibson Reservoir
TN - Hardin Co. - Tennessee R.
NY - Dexter - Black River Delta
CA - Stockton - Old Mormon Slough
CA - Anderson - Sacramento R.
TN - Nickajack Reservoir
OR - St. Helens - Columbia R.
NY - Massena - Grass R.
KY - Russeliville - Mud R.
CA - Stockton - New Mormon Slough
NY - Buffalo - Buffalo R.
GA - St. Marys - North R. (mouth)
VA - Cartersville - James R.
ME - Lewiston - Androscoggin R.
IA - Hamburg - Nishnabotna R.
TX - Corpus Christi - Inner Harbor
TX - Port Arthur - Neches R. (tidal)
LA - Monroe - Ouachita R.
LA - Oak Ridge - Bayou Bonne Idee
TX - Freeport - Brazos R.
* Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is
for the sample
used.
D-10-14
-------
Table D-10 Chlordane (cont)
Episode Cone, (ng/g) Estimated Risk Species Location
3088
3089
3092
3093
3105
3106*72608
3108
3112
3146
3168
3172
3180
3231
3249
3252
3259
3266
3290
3303
3305
3308
3346
3348
3422
3429
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Bluegill
White Crappie
Warmouth
Lm Bass
Lra Bass
Walleye
Walleye
Walleye
Walleye
Lm Bass
Lm Bass
Lm Bass
Sm Bass
Brook Trout
Lm Bass
Lm Bass
Black Crappie
Redear Sunfish
Sm Bass
Sm Bass
Northern Pike
Lm Bass
White Perch
Lm Bass
Weakfish
LA - Deridder - Anacoco Bayou
OK -Muskogee - Webbers Falls
LA - Hodge - Dugdemona R.
TX - Diboll - Neches R.
OK - Fort Cobb - Fort Cobb Reservoir
WI - U. Pentenwell Flow - Wisconsin R.
WI - Merrill - Wisconsin R.
MN - Little Falls - Mississippi R.
WI - Rothschild - Wisconsin R.
AL -Mobile - Cold Creek
AL/GA - State Line - Coosa R.
GA - Early County - Spring Creek
WA - Richland - Yakima R.
ID - Coeur d'Alene - Coeur d'Alene R.
ID -Parma- Boise R.
NY -Fort Miller- Hudson R.
AZ -GilaBend -GilaR.
C A - Stockton - Port of Stockton
NY - Newton Falls - Oswegatchie R.
NY - Massena - Raquette R.
NY - Rouses Pt. - Richelieu R.
NC - Plymouth - Roanoke R.
SC - Georgetown - Sampit R.
VA - Riverdale - Blackwater R.
NJ - Salem - Delaware R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-15
-------
D-10-16
-------
Table D-lO(cont)
Estimated Risks from Ingestion of Fish Contaminated with Heptachlor Epoxide
(Consumption Rate 6.5 g/d«y)
Epbode Conc.(mfo) Eittoated Rbk Spectei
Location
3117
3114
3115
3046/2199*
3444
2329
3048
2328
3079
3101
3104/2212*
3118
3148
2228
2356
2410
3036/2190*
3063
3065
3066
3068
3069
3070
3080
3081
3083
3085
3088
3089
3090
3092
3093
3094
3096
3D97
3100
3105
3106-V260*
3108
3110
40.7
25.8
10.2
7.91
5.9
5.06
4.15
2.92
2.87
1.18
1.07
0.97
0.67
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.4xlO"3
2.2xlO"3
8.6X10"6
6.7X10"6
S.OxlO"*
4.3X10"6
3.5X10"6
2.5X10"6
2.4X10"6
1.0x10"*
9.0xlO'7
8.2xlO'7
5.7xlO'7
«
«
—
—
—
«
—
..
—
..
—
..
..
—
—
—
~
—
..
..
..
..
—
..
—
—
—
Lake Trout
Carp
Catfish
Lm Bass
Channel Catfish/Carp
Brown Trout
White Bass
Chinook Salmon
White Bass
Brown Trout
SmBass
Walleye
Walleye
Longear Sunfish
Lm Bass
Sm Bass
Bluegill
Spotted Seatrout
Bigmouth Buffalo
Freshwater Drum
Atl. Croaker
Trout
Sheepshead
Lm Bass
White Bass
Lm Bass
Black Drum
Bluegill
White Crappie
White Crappie
Warmouth
Lm Bass
Channel Catfish
Brown Bullhead
Brown Bullhead
White Perch
LmBass
Walleye
Walleye
Carp
IL - Waukegan - Lake Michigan
IL - Quincy - Mississippi R.
IL - East St. Louis - Mississippi River below Sauget
MO - Lexington - Missouri R.
TN - Memphis - Mississippi R.
NY - Rochester - Lake Ontario
MO - West Alton - Mississippi R.
NY - Olcott - Lake Ontario
OK - Kaw Reservoir
PA - Paoli - Little Valley Creek
PA - Philadelphia • Schuylkill R.
MI - Escanaba - Escanaba R.
MI - Muskegon - Muskegon Lake
VA - Cartersville - James R.
ME - Lewiston - Androscoggin R.
MI - River Rouge - Rouge R.
I A - Hamburg - Nishnabotna R.
LA - Moss Lake - Calcasieu R.
LA - Baton Rouge - Mississippi R.
LA - Union - Mississippi R.
TX - Morgan Point - Houston Ship Channel
TX - Corpus Christi - Inner Harbor
TX - Port Arthur - Neches R. (tidal)
LA - Monroe - Ouachita R.
TX - Lufkin - Lake Sam Rayburn
LA - Oak Ridge - Bayou Bonne Idee
TX - Freeport - Brazos R.
LA - Deridder - Anacoco Bayou
OK - Muskogee - Webbers Falls
OK - Pyrer Creek - Fort Gibson Reservoir
LA - Hodge - Dugdemona R.
TX - Diboll - Neches R.
PA - Torresdale - Delaware R.
PA - Eddystone - Delaware R.
DE - Tybouts Corner - Red Lion Creek
MD - Baltimore - Baltimore Harbor
OK - Fort Cobb - Fort Cobb Reservoir
WI - U. Pentenwell Flow - Wisconsin R.
WI - Merrill - Wisconsin R.
WI -Hudson- St. CroixR.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-J7
-------
Table D-10 Heptacblor Epoxlde (coot)
Episode Cone. (DR/JJ) Estimated
3112 ND
3113 ND
3120 ND
3125 ND
3141 ND
3146 ND
3168 ND
3172 ND
3180 ND
3182 ND
3183 ND
3184/2133* ND
3188 ND
3193 ND
3212 ND
3216 ND
3218 ND
3219 ND
3231 ND
3249 ND
3252 ND
3258 ND
3259 ND
32*6 ND
3267 ND
3282 ND
3288 ND
3290 ND
3298 ND
3299 ND
3300 ND
3301 ND
3302 ND
3303 ND
3304 ND
3305 ND
3306 ND
3308 ND
3310 ND
3311 ND
3312 ND
3313 ND
3314 ND
3336 ND
Risk Specie*
Walleye
Channel Catfish/Carp
Bass
White Bass
Northern Pike
Walleye
Lm Bass
Lm Bass
Lm Bass
Rock Bass
Sauger
Blue Catfish/W. Crappie
Lm Bass
Sm Bass
Catfish
Squawfish
Squawfish
White Sturgeon
Sm Bass
Brook Trout
Lm Bass
Spot
Lm Bass
Black Crappie
Rainbow Trout
Flathead Catfish
Squawfish
Redear Sunfish
Lm Bass
Lm Bass
Sm Bass
Northern Pike
Lm Bass
Sm Bass
Northern Pike
Sm Bass
SmBass
Northern Pike
Walleye
Sm Bass
Sm Bass
Sm Bass
White Bass
Spotted Seatrout
Location
MN - Little Falls - Mississippi R,
IL -Geneva-FoxR.
MI - Saugatuck - Kalamazoo R.
MN - Red Wing - Mississippi R.
WI - Milwaukee - Milwaukee R.
WI - Rothschild - Wisconsin R.
AL - Mobile - Cold Creek
AL/GA - State Line - Coosa R.
GA - Early County - Spring Creek
KY-Russellville-MudR.
KY - Catlettsburg - Big Sandy R.
MS - Redwood - Yazoo R.
TN - Nickajack Reservoir
VA - Brookneal - Roanoke R.
OR - Owyhee - Owyhee R.
OR - St. Helens - Columbia R.
OR - Wauna - Columbia R.
OR -Dalles- Columbia R.
WA - Richland - Yakima R.
ID - Coeur d'Alene - Coeur d'Alene R.
ID -Parma- Boise R.
VA - Norfolk - S. Br. Elizabeth R.
NY - Fort Miller - Hudson R.
AZ -GilaBend-GilaR.
CA - Anderson - Sacramento R.
CA - Calipatria - Alamo R.
CA - Salinas - Blanco Drain
CA - Stockton - Port of Stockton
NY - Buffalo - Buffalo R.
NY - N. Tonawanda - Niagara R.
NY - Porter - Niagara R. Delta
NY - Olcott - Eighteen Mile Creek
NY - Lewiston - Niagara R.
NY - Newton Falls - Oswegatchie R.
NY - Dexter - BJack River Delta
NY - Massena - Raquette R.
NY - Massena - Grass R.
NY - Rouses Pt. - Richelieu R.
PA-Easton-LehighR.
W V - New MartinsviJJe - Ohio R.
W V - Wheeling - Ohio R.
W V - Bedington - Opequon Creek
WV - Winfield - Kanawha R.
GA - St. Marys - North R. (mouth)
* Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample
used.
D-10-18
-------
Table D-10 Heptachtor Epoxide (cont)
Episode Cone, (nf/g) Estimated Risk Species Location
3346
3348
3350
3354
3355
3375
3376
3377
3401
3403
3409*/2709
3412
3414
3415
3419
3420
3421
3422
3426
3427
3428
3429
3446
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Lm Bass
White Perch
Lm Bass
Lm Bass
Lm Bass
LmBass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Sm Bass
Channel Catfish/Sm Bass
Channel Catfish/Sm Bass
Freshwater Drum
Green Sunfish
White Perch
Lm Bass
Blucfish
Bluefish
Bluefish
Weakfish
Striped Bass
NC - Plymouth - Roanoke R.
SC - Georgetown - Sampit R.
TN - Calhoun - Hiwassee R.
C A - Stockton - New Mormon Slough
CA - Stockton - Old Mormon Slough
GA - Austell - Chattahoochee R.
GA - Whitesburg - Chattahoochee R.
G A - Franklin - Chattahoochee R.
TN - Hardin Co. - Tennessee R.
TN - Kingsport - S. Fork Holston R.
NY -Peekskill- Hudson R.
NY - Oswego - Oswego Harbor
PA - Pittston - Susquehanna R.
PA - Ransom - N. Br. Susquehanna R.
PA - Erie - Lake Erie
PA - Spring Grow - Codorus Creek
VA - Covington - Jackson R.
VA - Riverdale - Backwater R.
NJ - Carteret - Arthur Kill R.
NJ - Elizabeth - Newark Bay
NJ - Newark - Passaic R.
NJ - Salem - Delaware R .
KY - Catlettsburg - Big Sandy R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-19
-------
D-10-20
-------
Table D-10 (cont)
Estimated Risks from Digestion of Fish Contaminated with Alpha-BHC
(Consumption Rate 6.5g/day)
Eplfode Cone, (n^g) Estimated Rlik Species
Location
3258 17.48
3068 10.1
3117 5.48
2329 4.76
3100 4.27
3414 3.63
3141 3.31
3063 3.23
3094 2.78
3312 2.57
2328 2.27
3104*/2212 1.58
2410 1.45
3114 1.45
3415 .43
3184/2133* .39
3426 .13
3097 .1
3110 .08
3377 .02
3299 0.9
3113 0.79
3048 0.76
3412 0.73
3444 0.73
3306 0.72
3096 0.64
3081 0.58
3083 0.43
3120 0.42
3420 0.39
3125 0.34
3118 0.18
2228 ND
2356 ND
3036/2190* ND
3046/2199* ND
3065 ND
3066 ND
3069 ND
l.OxlO"5
5.9x10"*
3.2x1 ff6
2.8x10"*
2.5x10-*
2.1x10-*
.9x10-*
.9x10"*
.6x10-*
.5x10"*
.3x10"*
9.2xlO"7
8.5xlO"7
8.5xlO"7
8.4xlO"7
S.lxlO"7
6.6xlO'7
6.4xlO'7
6.3xlO"7
6.0xlO"7
5.3xlO"7
4.6xlO"7
4.4xlO'7
4.3xlO"7
4.3xlO"7
4.2xlO'7
3.7xlO"7
3.4xlO"7
2.5xlO"7
2.5xlO"7
2.3xlO"7
2.0xlO"7
l.lxlO"7
--
—
--
-
--
--
--
* Asterisk indicates episode number
Species listed is for
Spot
All. Croaker
Lake Trout
Brown Trout
White Perch
Channel Catfish
Northern Pike
Spotted Seatrout
Channel Catfish
Sm Bass
Chinook Salmon
Lm Bass
Sm Bass
Carp
Channel Catfish
Blue Catfish
Bluefish
Brown Bullhead
Carp
Lm Bass
Lm Bass
Channel Catfish
White Bass
Sm Bass
Channel Catfish
Sm Bass
Brown Bullhead
White Bass
Lm Bass
Bass
Green Sunfish
White Bass
Walleye
Longear Sunfish
Lm Bass
Bluegill
Lm Bass
Bigmouth Buffalo
Freshwater Drum
Trout
associated with sample
VA - Norfolk - S. Br. Elizabeth R.
TX - Morgan Point - Houston Ship Channel
IL - Waukegan - Lake Michigan
NY - Rochester - L ake Ontario
MD - Baltimore - Baltimore Harbor
PA - Pittston - Susquehanna R.
WI - Milwaukee - Milwaukee R.
LA - Moss Lake - Calcasieu R.
PA - Torresdale - Delaware R.
WV - Wheeling - Ohio R.
NY - Olcott - Lake Ontario
PA - Philadelphia - Schuylkill R.
MI - River Rouge - Rouge R.
IL - Quincy - Mississippi R.
PA - Ransom - N. Br. Susquehanna R.
MS - Redwood - Yazoo R.
NJ - Carteret - Arthur Kill R.
DE - Tybouts Corner - Red Lion Creek
WI - Hudson - St. CroixR.
GA - Franklin - Chattahoochee R.
NY - N. Tonawanda - Niagara R.
IL - Geneva- Fox R.
MO - West Alton - Mississippi R.
NY - Oswego - Oswego Harbor
TN - Memphis - Mississippi R.
NY - Massena - Grass R.
PA - Eddystone -Delaware R.
TX - Lufkin - Lake Sam Rayburn
LA - Oak Ridge - Bayou Bonne Idee
MI - Saugatuck - Kalamazoo R.
PA - Spring Grove - Codorus Creek
MN - Red Wing - Mississippi R .
MI - Escanaba - Escanaba R.
VA - Cartersville - James R.
ME - Lewiston - Androscoggin R .
I A - Hamburg - Nishnabotna R.
MO - Lexington - Missouri R.
LA - Baton Rouge - Mississippi R.
LA - Union - Mississippi R.
TX - Corpus Christi - Inner Harbor
actually used for the risk calculations.
the sample used.
D-10-2 J
-------
Table D-10 Alpha-BHC (cont)
Eptiode
3070
3079
3080
3085
3088
3089
3090
3092
3093
3101
3105
Cone, (ng/g) Estimated Risk
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3106*/2608 ND
3108
3112
3115
3146
3148
3168
3172
3180
3182
3183
3188
3193
3212
3216
3218
3219
3231
3249
3252
3259
3266
3267
3282
3288
3290
3298
3300
3301
3302
3303
3304
3305
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
* Asterisk indicates episode number
Specfci
Sheep shead
White Bass
Lm Bass
Black Drum
BJuegill
White Grapple
White Crappie
Warmouth
Lm Bass
Brown Trout
Lm Bass
Walleye
Walleye
Walleye
Catfish
Walleye
Walleye
Lm Bass
Lm Bass
Lm Bass
Rock Bass
Sauger
Lm Bass
Sm Bass
Catfish
Squawfish
Squawfish
White Sturgeon
Sm Bass
Brook Trout
Lm Bass
Lm Bass
Black Crappie
Rainbow Trout
Flathead Catfish
Squawfish
Redear Sunfish
Lm Bass
Sm Bass
Northern Pike
Lm Bass
Sm Bass
Northern Pike
Sm Bass
associated with sample
Location
TX - Port Arthur - Neches R. (tidal)
OK - Kaw Reservoir
LA - Monroe - Ouachita R.
TX - Freeport - Brazos R.
LA - Deridder - Anacoco Bayou
OK - Muskogee - Webbers Falls
OK - Pyrer Creek - Fort Gibson Reservoir
LA - Hodge - Dugdemona R.
TX -DiboU- Neches R.
PA - Paoli - Little Valley Creek
OK - Fort Cobb - Fort Cobb Reservoir
WI - U. Pentenwell Flow - Wisconsin R.
WI - Merrill - Wisconsin R.
MN - Little Falls - Mississippi R.
IL - East St. Louis - Mississippi River below Sauget
WI - Rothschild - Wisconsin R.
MI - Muskegon - Muskegon Lake
AL - Mobile - Cold Creek
AL A3 A- State Line - Coosa R.
GA - Early County - Spring Creek
KY - Russellville - Mud R.
KY - Catlettsburg - Big Sandy R.
TN - Nickajack Reservoir
VA - Brookneal - Roanoke R.
OR - Owyhee - Owyhee R.
OR - St. Helens - Columbia R.
OR - Wauna - Columbia R.
OR - Dalles - Columbia R.
WA - Richland - Yakima R.
ID - Coeur d'Alene - Coeur d'Alene R.
ID - Parma - Boise R.
NY - Fort Miller - Hudson R.
AZ -GilaBend-GilaR.
CA - Anderson - Sacramento R.
CA - Calipatria - Alamo R.
CA - Salinas - Blanco Drain
CA - Stockton - Port of Stockton
NY - Buffalo - Buffalo R.
NY - Porter - Niagara R. Delta
NY - Olcott - Eighteen Mile Creek
NY - Lewiston - Niagara R.
NY - Newton Falls - Oswegatchie R.
NY - Dexter - Black River Delta
NY - Massena - Raquette R.
actually used for the risk calculations.
Species listed is for the sample used.
D-10-22
-------
Table D-10 Alpha-BHC (cont)
Episode Cone, (ng/g) Estimated Risk Spectei Location
3308
3310
3311
3313
3314
3336
3346
3348
3350
3354
3355
3375
3376
3401
3403
3409*72709
3419
3421
3422
3427
3428
3429
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Northern Pike
Walleye
Sm Bass
Sm Bass
White Bass
Spotted Seatrout
Lm Bass
White Perch
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Freshwater Drum
White Perch
Lm Bass
Bluefish
Bluefish
Weakfish
NY - Rouses Pt. - Richelieu R.
PA - Easton - Lehigh R.
WV - New Martinsville - Ohio R.
WV - Bedington - Opequon Creek
WV - Winfield - Kanawha R.
GA - St. Marys - North R, (mouth)
NC - Plymouth - Roanoke R.
SC - Georgetown - Sampit R,
TN - Calhoun - Hiwassee R.
CA - Stockton - New Mormon Slough
CA - Stockton - Old Mormon Slough
GA - Austell - Chattahoochee R.
GA - Whitesburg - Chattahoochee R.
TN - Hardin Co. - Tennessee R.
TN - Kingsport - S. Fork Holston R.
NY -Peekskill- Hudson R.
PA -Erie -Lake Erie
VA - Covington - Jackson R.
VA - Riwrdale - Blackwater R.
NJ - Elizabeth - Newark Bay
NJ - Newark - Passaic R.
NJ - Salem - Delaware R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-23
-------
D-10-24
-------
Table D-10 (cont)
Estimated Risks from Ingestion of Fish Contaminated with Mirex
(Consumption Rate 6.59/day)
Eptaode Cone, (nfl'g) Ettlmated Risk Spectei
Location
2328 225
2329 131
3115 34.3
3412 14,2
3300 7,91
3304 7.25
3117 7.06
3301 6.87
3306 4.1
3302 3.63
3184/2133* 3.62
3444 3.49
3096 3.01
3305 2.25
3258 1.87
3113 1.71
3180 1.39
3141 1.16
3312 1.14
3420 1.03
3063 0,88
3415 0.77
3125 0.7
3104*72212 0.63
3336 0.42
3426 0.38
3172 0.36
3081 0.34
3065 0.33
3118 0.32
3148 0.29
3299 0.28
3216 0.26
3314 0.22
3097 0.21
3401 0.21
3311 0.18
2228 ND
2356 ND
2410 ND
3.8xlO'5
2.2xlO'5
S.7KIQ-6
2.4xlO'6
1.3xIO'6
1.2xlO'6
1.2X10"6
l.lxlO'6
6.9xlO'7
6.1xlO'7
6.1xIO'7
5.8xlO'7
S.OxlO"7
3.8xlO"7
3.MO'7
2.9xlO'7
2.3xlO'7
1.9xlO"7
1.9xtO"7
1.7xlO'7
1.5xlO'7
1.3xlO"7
1.2xlO'7
l.lxlO'7
7.0xlO"8
6.4xlO"8
6.0xlO'8
5.7xlO"8
5.5xlO"8
5.3xlO'8
4.8xlO'8
4.7xlO'8
4.3xlO"8
3.7xlO'8
3.5xlO'8
3.5xlO"8
3.0xIO'8
—
--
—
Chinook Salmon
Brown Trout
Catfish
Sm Bass
Sm Bass
Northern Pike
Lake Trout
Northern Pike
Sm Bass
Lm Bass
Blue Catfish
Channel Catfish
Brown Bullhead
Sm Bass
Spot
Carp
L m Bass
Northern Pike
Sm Bass
Green Sunfish
Spotted Seatrout
Channel Catfish
White Bass
Lm Bass
Spotted Seatrout
Bluefish
Lm Bass
White Bass
Bigmouth Buffalo
Walleye
Walleye
Lm Bass
Squawfish
White Bass
Brown Bullhead
Lm Bass
Sm Bass
Longear Sunfish
Lm Bass
Sm Bass
NY - Olcott - Lake Ontario
NY - Rochester - Lake Ontario
IL - East St. Louis - Mississippi River below Sauget
NY - Oswego - Oswego Harbor
NY - Porter - Niagara R. Delta
NY - Dexter - Black Riwr Delta
IL - Waukegan - Lake Michigan
NY - Olcott - Eighteen Mile Creek
NY - Massena - Grass R.
NY - Lewiston - Niagara R.
MS - Redwood - Yazoo R.
TN - Memphis - Mississippi R.
PA - Eddystone - Delaware R.
NY - Massena - Raquette R.
VA - Nortolk - S. Br. Elizabeth R.
IL -Geneva -FoxR.
GA - Early County - Spring Creek
WI - Milwaukee - Milwaukee R.
WV- Wheeling- Ohio R.
PA - Spring Grove - Codorus Creek
LA - Moss Lake - Calcasieu R.
PA - Ransom - N. Br. Susquehanna R.
MN - Red Wing - Mississippi R.
PA - Philadelphia - Schuylkill R.
GA - St. Marys - North R. (mouth)
NJ - Carteret - Arthur Kill R.
AL /GA- State Line - Coosa R.
TX - Lufkin - Lake Sam Rayburn
LA - Baton Rouge - Mississippi R.
MI - Escanaba - Escanaba R.
MI - Muskegon - Muskegon Lake
NY - N. Tonawanda - Niagara R.
OR - St. Helens - Columbia R.
WV - Winfield - Kanawha R.
DE - Tybouts Corner - Red Lion Creek
TN - Hardin Co. - Tennessee R.
WV - New Martinsville - Ohio R.
VA - Cartersville - James R.
ME - Lewiston - Androscoggin R.
MI - River Rouge - Rouge R.
* Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for
the sample
used.
D-10-25
-------
Table D-10 Mirtx(cont)
Episode Cone. (ngfe) Eitimated Risk Species
3036/2190*
3046/2199*
3048
3066
3068
3069
3070
3079
3080
3083
3085
3088
3089
3090
3092
3093
3094
3100
3101
3105
3106*/2608
3108
3110
3112
3114
3120
3146
3168
3182
3183
3188
3193
3212
3218
3219
3231
3249
3252
3259
3266
3267
3282
3288
3290
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
..
--
-
•-
-
-
--
--
—
--
--
--
--
--
-
--
--
—
--
—
—
--
--
--
--
-
—
—
—
—
--
--
—
--
—
--
—
.-
..
--
~
--
--
™"
* Asterisk indicates episode number
Species listed is
Bluegill
Lm Bass
White Bass
Freshwater Drum
All. Croaker
Trout
Sheep shead
White Bass
Lm Bass
Lm Bass
Black Drum
Bluegill
White Crappie
White Crappie
Wannouth
Lm Bass
Channel Catfish
White Perch
Brown Trout
Lm Bass
Walleye
Walleye
Carp
Walleye
Carp
Bass
Walleye
Lm Bass
Rock Bass
Sauger
Lm Bass
Sm Bass
Catfish
Squawfish
White Sturgeon
Sm Bass
Brook Trout
Lm Bass
Lm Bass
Black Crappie
Rainbow Trout
Flathead Catfish
Squawfish
Redear Sunfish
associated with sample
Location
IA - Hamburg - Nishnabotna R.
MO - Lexington - Missouri R.
MO - West Alton - Mississippi R.
LA - Union - Mississippi R.
TX - Morgan Point - Houston Ship Channel
TX - Corpus Christi - Inner Harbor
TX - Port Arthur - Neches R. (tidal)
OK - Kaw Reservoir
LA • Monroe - Ouachita R
LA - Oak Ridge - Bayou Bonne Idee
TX - Freeport - Brazos R.
LA - Deridder - Anacoco Bayou
OK - Muskogee - Webbers Falls
OK - Pyrer Creek - Fort Gibson Reservoir
LA • Hodge - Dugdemona R.
TX-Diboll- Neches R.
PA - Torresdale - Delaware R.
MD - Baltimore - Baltimore Harbor
PA - Paoli - Little Valley Creek
OK - Fort Cobb - Fort Cobb Reservoir
WI - U. Pentenwell Flow - Wisconsin R.
WI - Merrill - Wisconsin R.
WI - Hudson - St. CroixR.
MN - Little Falls - Mississippi R.
IL - Quincy - Mississippi R.
MI - Saugatuck - Kalamazoo R.
WI - Rothschild - Wisconsin R.
AL - Mobile - Cold Creek
KY-Russellville-MudR.
KY - Catlettsburg - Big Sandy R.
TN - Nickajack Reservoir
VA - Brookneal - Roanoke R.
OR - Owyhee - Owyhee R.
OR - Wauna - Columbia R.
OR - Dalles - Columbia R.
WA - Richland - Yakima R.
ID - Coeur d'Alene - Coeur d'Alene R.
ID -Parma- Boise R.
NY - Fort Miller - Hudson R.
AZ -GilaBend-GUaR.
CA - Anderson - Sacramento R
CA - Catipatria - Alamo R.
CA - Salinas - Blanco Drain
CA- Stockton - Port of Stockton
actually used for the risk calculations.
for the sample used.
D-10-26
-------
Table D-10 Mlrex(cont)
Episode Cone, (ngfc) Estimated Risk Species Location
3298
3303
3308
3310
3313
3346
3348
3350
3354
3355
3375
3376
3377
3403
3409*/2709
3414
3419
3421
3422
3427
3428
3429
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Lm Bass
Sm Bass
Northern Pike
Walleye
Sm Bass
Lm Bass
White Perch
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Channel Catfish/Sm Bass
Freshwater Drum
White Perch
Lm Bass
Bluefish
Bluefish
Weakfish
NY -Buffalo- Buffalo R.
NY - Newton Falls - Oswegatchie R.
NY - Rouses Pt. - Richelieu R.
PA - Easton - Lehigh R.
WV - Bedington - Opequon Creek
NC - Plymouth - Roanoke R.
SC - Georgetown - Sampit R.
TN - Calhoun - Hiwassee R.
CA - Stockton - New Mormon Slough
CA - Stockton - Old Mormon Slough
G A - Austell - Chattahoochee R.
GA - Whitesburg - Chattahoochee R.
GA - Franklin - Chattahoochee R.
TN - Kingsport - S. Fork Holston R.
NY-Peekskill-HudsonR.
PA - Pittston - Susquehanna R.
PA - Erie - Lake Erie
VA - Covington - Jackson R.
VA - Riverdale - Blackwater R.
NJ - Elizabeth - Newark Bay
NJ - Newark - Passaic R.
NJ - Salem - Delaware R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-27
-------
D-JO-28
-------
Table D-10 (cont)
Estimated Risks from Ingestion of Fish Contaminated with Gamma-BHC
(Consumption Rate 6.5g/day)
Eplaode Cone,
Estimated Rl»k Spectei
Location
3068
3100
3258
3113
3114
3094
3184/2133*
3079
3377
3104/2212*
2328
3110
3314
2410
3048
3375
3125
3120
3401
3426
3182
3346
2228
2329
2356
3036/2190*
3046/2199*
3063
3065
3066
3069
3070
3080
3081
3083
3085
3088
3089
3090
3092
6.68
2.85
2.67
1.78
1.71
1.68
1.64
1.59
1.56
1.36
1.33
1.08
0.97
0.86
0.8
0.71
0.61
0.48
0.39
0.37
0.33
0.16
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S.lxlO'7
3.4x1 0'7
3.2xlO'7
2.2xlO'7
2.1xlO'7
2.0xlO'7
2.0xlO'7
.9xlO'7
.9xlO'7
.6xlO'7
.6xlO'7
.3xlO'7
.2xlO'7
I.OxlO"7
9.7xlO'8
8.6xlO"8
7.4xlO'8
5.8xlO'8
4.7xlO'8
4.5xlO'8
4.0xlO'8
1.9xlO'8
—
—
--
--
-
-
--
--
--
--
--
--
--
--
--
--
--
~
* Asterisk indicates episode number
Atl. Croaker
White Perch
Spot
Channel Catfish/Carp
Carp
Channel Catfish
Blue Catfish
White Bass
Lm Bass
Sm Bass
Chinook Salmon
Carp
White Bass
Sm Bass
White Bass
Lm Bass
White Bass
Bass
Lm Bass
Bluefish
Rock Bass
Lm Bass
Longear Sunfish
Brown Trout
Lm Bass
Bluegill
Lm Bass
Spotted Seatrout
Bigmouth Buffalo
Freshwater Drum
Trout
Sheepshead
Lm Bass
White Bass
Lm Bass
Black Drum
Bluegill
White Crappie
White Crappie
Warmouth
associated with sample
TX - Morgan Point - Houston Ship Channel
MD - Baltimore - Baltimore Harbor
VA - Norfolk - S. Br. Elizabeth R.
IL - Geneva- Fox R.
IL - Quincy - Mississippi R.
PA - Torresdale - Delaware R.
MS - Redwood - Yazoo R.
OK - Kaw Reservoir
GA - Franklin - Chattahoochee R.
PA - Philadelphia - Schuylkill R.
NY - Olcott - Lake Ontario
WI -Hudson- St. CroixR.
WV - Winfield - Kanawha R.
MI - River Rouge - Rouge R.
MO - West Alton - Mississippi R.
GA - Austell - Chattahoochee R.
MN - Red Wing - Mississippi R.
MI - Saugatuck - Kalamazoo R.
TN - Hardin Co. - Tennessee R.
NJ - Carteret - Arthur Kill R.
KY - Russellville - Mud R.
NC - Plymouth - Roanoke R,
VA - Carter sville - James R.
NY - Rochester - Lake Ontario
ME - Lewiston - Androscoggin R.
I A - Hamburg - Nishnabotna R.
MO - Lexington - Missouri R.
LA - Moss Lake - Calcasieu R.
LA - Baton Rouge - Mississippi R.
LA - Union - Mississippi R.
TX - Corpus Christi - Inner Harbor
TX - Port Arthur - Neches R. (tidal)
LA - Monroe - Ouachita R.
TX - Lufkin - Lake Sam Rayburn
LA - Oak Ridge - Bayou Bonne Idee
TX - Freeport - Brazos R.
LA - Deridder - Anacoco Bayou
OK - Muskogee - Webbers Falls
OK - Pyrer Creek - Fort Gibson Reservoir
LA - Hodge - Dugdemona R.
actually used for the risk calculations.
Species listed is for the sample used.
D-10-29
-------
Table D-10 Gamma-BHC (cent)
Episode
3093
3096
3097
3101
3105
Cone, (ng/g) Eitlnated Risk Spectei
ND
ND
ND
ND
ND
3106*/2608 ND
3108
3112
3115
3117
3118
3141
3146
3148
3168
3172
3180
3183
3188
3193
3212
3216
3218
3219
3231
3249
3252
3259
3266
3267
3282
3288
3290
3298
3299
3300
3301
3302
3303
3304
3305
3306
3308
3310
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
* Asterisk indicates episode number
Lm Bass
Brown Bullhead
Brown Bullhead
Brown Trout
Lm Bass
Walleye
Walleye
Walleye
Catfish
Lake Trout
Walleye
Northern Pike
Walleye
Walleye
Lm Bass
Lm Bass
Lm Bass
Sauger
Lm Bass
Sm Bass
Catfish
Squawfish
Squawfish
White Sturgeon
Sm Bass
Brook Trout
Lm Bass
Lm Bass
Black Crappie
Rainbow Trout
Flathead Cattish
Squawfish
Redear Sunfish
Lm Bass
Lm Bass
Sm Bass
Northern Pike
Lm Bass
Sm Bass
Northern Pike
Sm Bass
Sm Bass
Northern Pike
Walleye
associated with sample
Location
TX-Diboll- Heches R.
PA - Eddystone - Delaware R.
DE - Tybouts Corner - Red Lion Creek
PA - Paoli - Little Valley Creek
OK - Fort Cobb - Fort Cobb Reservoir
WI - U. Pentenwell Flow - Wisconsin R.
WI - Merrill - Wisconsin R.
MN - Little Falls - Mississippi R.
IL - East St. Louis - Mississippi River below Sauget
IL - Waukegan - Lake Michigan
MI - Escanaba - Escanaba R.
WI - Milwaukee - Milwaukee R.
WI - Rothschild - Wisconsin R.
MI - Muskegon - Muskegon Lake
AL - Mobile - Cold Creek
AL/GA - State Line - Coosa R.
GA - Early County - Spring Creek
KY - Catlettsburg - Big Sandy R.
TN - Nickajack Reservoir
VA - Brookneal - Roanoke R.
OR - Owyhee - Owyhee R.
OR - St. Helens - Columbia R.
OR - Wauna - Columbia R.
OR - Dalles - Columbia R.
WA - Richland - Yakima R.
ID - Coeur d'Alene - Coeur d'Alene R.
ID - Parma - Boise R.
NY - Fort Miller - Hudson R.
AZ - Gila Bend - Gila R.
CA - Anderson - Sacramento R.
CA - Calipatria - Alamo R.
CA - Salinas - Blanco Drain
C A - Stockton - Port of Stockton
NY - Buffalo - Buffalo R.
NY - N. Tonawanda - Niagara R.
NY - Porter - Niagara R. Delta
NY - Olcott - Eighteen Mile Creek
NY - Lewiston - Niagara R.
NY - Newton Falls - Oswegatchie R.
NY - Dexter - Black River Delta
NY - Massena - Raquette R.
NY - Massena - Grass R.
NY - Rouses Pt. - Richelieu R.
PA - Easton - Lehigh R.
actually used for the risk calculations.
Species listed is for the sample used.
D-10-30
-------
Table D-10 Gamma-BHC (coot)
Epfaode Cone, (ng/g) E»tlmated Risk Spectei Location
3311
3312
3313
3336
3348
3350
3354
3355
3376
3403
3409*/2709
3412
3414
3415
3419
3420
3421
3422
3427
3428
3429
3444
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Sm Bass
Sm Bass
Sm Bass
Spotted Seatrout
White Perch
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Sm Bass
Channel Catfish/Sm Bass
Channel Catfish/Sm Bass
Freshwater Drum
Green Sunfish
White Perch
Lm Bass
Bhiefish
Bluefish
Weakfish
Channel Catfish/Lm Bass
WV - New Martinsville - Ohio R.
WV-Wheeling-Ohio R.
WV - Bedington - Opequon Creek
GA - St. Marys - North R. (mouth)
SC - Georgetown - Sampit R.
TN - Calhoun - Hiwassee R.
CA - Stockton - New Mormon Slough
CA - Stockton - Old Mormon Slough
GA - Whitesburg - Chattahoochee R.
TN - Kingsport - S. Fork Holston R.
NY-Peekskill-Hudson R.
NY - Oswego - Oswego Harbor
PA - Pittston - Susquehanna R.
PA - Ransom - N. Br. Susquehanna R.
PA - Erie - Lake Erie
PA - Spring Grove - Codorus Creek
VA - Covington - Jackson R.
VA - Riwsrdale - Blackwater R.
NJ - Elizabeth - Newark Bay
NJ - Newark - Passaic R.
NJ - Salem • Delaware R.
TN - Memphis - Mississippi R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-31
-------
D-IO-32
-------
Table D-10 (cont)
Estimated Risks from Ingestion of Fish Contaminated with Hexachlorobenzene
(Consumption Rate 6.5 g/day)
Episode Cone, (ng/g) Estimated RUk Specks
Locution
3085
3063
2329
2328
3068
3444
3094
3117
3299
3100
3097
3066
2410
3212
3079
3282
3314
3113
3301
3311
3375
3168
3310
3114
3412
3300
3288
3193
3101
3065
3302
3183
3118
3120
3401
3081
2228
2356
3036/2190*
3046/2199*
50.74
43.69
8.87
8.19
7.66
5.8
5.38
5.22
3.03
2.74
2.57
2.41
2.38
2.24
2.1
2.02
1.94
1.72
1.2
1.18
0.9
0.89
0.8
0.75
0.58
0.54
0.51
0.32
0.31
0,3
0.3
028
0.24
0.15
0.14
0.12
ND
ND
ND
ND
8.0x10-*
6.9X10"6
1.4X10"6
1.3xlO'6
1.2X10'6
9.2xlO'7
8.5xlO"7
8.2x1 0"7
4.8xlO'7
4.3xlO"7
4.1xlO'7
3.8xlO'7
3.8xlO'7
3.5xlO'7
3.3xlO"7
3.2xlO'7
3.1xlO'7
2.7xlO'7
1.9xlO"7
1.9xlO'7
1.4xlO'7
1.4xlO'7
1.3xlO"7
1.2xlO'7
9.2xlO'8
8.5xlO"8
S.lxlO"8
S.lxlO'8
4.9xlO'8
4.7xlO'8
4.7xlO'8
a
4.4xlO'8
3.8xlO'8
2.4xlO'8
2.2xlO'8
1.9xlO'8
--
-
--
—
Black Drum
Spotted Seatrout
Brown Trout
Chinook Salmon
All. Croaker
Channel Catfish/Lm Bass
Channel Catfish
Lake Trout
Lm Bass
White Perch
Brown Bullhead
Freshwater Drum
Sm Bass
Catfish
White Bass
Flathead Catfish
White Bass
Channel Catfish/Carp
Northern Pike
Sm Bass
Lm Bass
Lm Bass
Walleye
Carp
Sm Bass
Sm Bass
Squawfish
Sm Bass
Brown Trout
Bigmouth Buffalo
Lm Bass
Sauger
Walleye
Bass
Lm Bass
White Bass
Longear Sunfish
Lm Bass
Bluegill
Lm Bass
TX - Freeport - Brazos R.
LA - Moss Lake - Calcasieu R.
NY - Rochester - Lake Ontario
NY - Olcott - Lake Ontario
TX - Morgan Point - Houston Ship Channel
TN - Memphis - Mississippi R.
PA - Torresdale - Delaware R.
IL - Waukegan - Lake Michigan
NY - N. Tonawanda - Niagara R.
MD - Baltimore - Baltimore Harbor
DE - Tybouts Corner - Red Lion Creek
LA - Union - Mississippi R .
MI - River Rouge - Rouge R.
OR - Owyhee - Owyhee R.
OK - Kaw Reservoir
CA - Calipatria - Alamo R.
WV - Winfield - Kanawha R.
IL - Geneva- Fox R.
NY - Olcott - Eighteen Mile Creek
WV - New Martinsville - Ohio R.
GA - Austell - Chattahoochee R.
AL - Mobile - Cold Creek
PA -Easton-LehighR.
IL - Quincy - Mississippi R.
NY - Oswego - Oswego Harbor
NY - Porter - Niagara R. Delta
CA - Salinas - Blanco Drain
VA - Brookneal - Roanoke R.
PA - Paoli - Little Valley Creek
LA - Baton Rouge - Mississippi R.
NY - Lewiston - Niagara R.
K Y - Catlettsburg - Big Sandy R.
MI - Escanaba - Escanaba R.
MI - Saugatuck - Kalamazoo R.
TN - Hardin Co. - Tennessee R.
TX - Lufkin - Lake Sam Rayburn
VA - Cartersville - James R.
ME - Lewiston - Androscoggin R.
IA - Hamburg - Nishnabotna R.
MO - Lexington - Missouri R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-33
-------
Table D-10 Heiachk>robenzene(cont)
Episode Cone, (atft) Estimated Risk
3048
3069
3070
3080
3083
3088
3089
3090
3092
3093
3096
3104*72212
3105
3106*/2608
3108
3110
3112
3115
3125
3141
3146
3148
3172
3180
3182
3184/2133*
3188
3216
3218
3219
3231
3249
3252
3258
3259
3266
3267
3290
3298
3303
3304
3305
3306
3308
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
* Asterisk indicates episode number
Species
Species
White Bass
Trout
Sheepshead
Lm Bass
Lm Bass
Blue gill
White Crappie
White Crappie
Warmouth
Lm Bass
Brown Bullhead
Lm Bass/Sm Bass
Lm Bass
Walleye
Walleye
Carp
Walleye
Catfish
White Bass
Northern Pike
Walleye
Walleye
Lm Bass
Lm Bass
Rock Bass
Location
MO - West Alton - Mississippi R.
TX - Corpus Christi - Inner Harbor
TX - Port Arthur - Neches R. (tidal)
LA - Monroe - Ouachita R.
LA - Oak Ridge - Bayou Bonne Idee
LA - Deridder - Anacoco Bayou
OK - Muskogee - Webbers Falls
OK - Pyrer Creek - Fort Gibson Reservoir
LA - Hedge - Dugdemona R.
TX-Diboll- Neches R.
PA - Eddystone - Delaware R.
PA - Philadelphia - Schuylkill R.
OK - Fort Cobb - Fort Cobb Reservoir
WI - U. Pentenwell Flow - Wisconsin R.
WI - Merrill - Wisconsin R.
WI - Hudson - St. CroixR
MN - Little Falls - Mississippi R.
IL - East St. Louis - Mississippi River below Sauget
MN • Red Wing - Mississippi R.
WI - Milwaukee - Milwaukee R.
WI - Rothschild - Wisconsin. R.
MI - Muskegon - Muskegon Lake
AL/GA-- State Line - Coosa R.
GA - Early County - Spring Creek
KY- Russell ville - Mud R.
Blue Catfish/W. Crappie MS - Redwood - Yazoo R.
Lm Bass
Squawfish
Squawfish
White Sturgeon
Sm Bass
Brook Trout
Lm Bass
Spot
Lm Bass
Black Crappie
Rainbow Trout
Redear Sunfish
Lm Bass
Sm Bass
Northern Pike
Sm Bass
Sm Bass
Northern Pike
associated with sample
TN - Nickajack Reservoir
OR - St Helens - Columbia R.
OR - Wauna - Columbia R.
OR - Dalles - Columbia R.
WA - Richland - Yakima R.
ID - Coeur d'Alene - Coeur d'Alene R.
ID -Parma- Boise R.
VA - Norfolk - S. Br. Elizabeth R.
NY - Fort Miller - Hudson R.
AZ -GilaBend-GilaR.
CA - Anderson - Sacramento R.
CA - Stockton - Port of Stockton
NY -Buffalo- Buffalo R.
NY - Newton Falls - Oswegatchie R.
NY - Dexter - Black River Delta
NY - Massena - Raquette R.
NY - Massena - Grass R.
NY - Rouses Pt. - Richelieu R.
actually used for the risk calculations.
listed is for the sample used.
D-10-34
-------
Table D-10 Heiachk>robenzene(cont)
Epliode Cone, (ngfe) Eitlmated Rlik Spectei Location
3312
3313
3336
3346
3348
3350
3354
3355
3376
3377
3403
3409*^2709
3414
3415
3419
3420
3421
3422
3426
3427
3428
3429
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Sm Bass
Sm Bass
Spotted Seatrout
Lm Bass
White Perch
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Channel Catfish/Sm Bass
Channel Catfish/Sm Bass
Freshwater Drum
Green Sunfish
White Perch
Lm Bass
Bluefish
Bluefish
Bluefish
Weakfish
WV-Wheeling-Ohio R.
WV - Bedington - Opequon Creek
GA - St. Marys - North R. (mouth)
NC - Plymouth - Roanoke R.
SC - Georgetown - Sampit R.
TN - Calhoun - Hiwassee R.
CA - Stockton - New Mormon Slough
CA - Stockton - Old Mormon Slough
GA - Whitesburg - Chattahoochee R.
GA - Franklin - Chattahoochee R.
TN - Kingsport - S. Fork Holston R.
NY - Peekskill - Hudson R.
PA - Pittston - Susquehanna R.
PA - Ransom - N. Br. Susquehanna R.
PA - Erie - Lake Erie
PA - Spring Grove - Codorus Creek
VA - Covington - Jackson R.
VA - Riverdale - Blackwater R.
NJ - Carteret - Arthur Kill R.
NJ - Elizabeth - Newark Bay
NJ - Newark - Passaic R.
NJ - Salem - Delaware R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-35
-------
D-10-36
-------
Table D-10 (cont)
Estimated Cancer Risks from Ingestion of Fish Contaminated with Trifluralin
(Consumption Rate 6.5 g/day)
Episode Cone, (ng/g) Eitlmated Risk Species
Location
3282 116
3212 64.8
3115 33.1
3114 20
3444 13.4
3048 1.64
2228 ND
2328 ND
2329 ND
2356 ND
2410 ND
3036/2190* ND
3046/2199* ND
3063 ND
3065 ND
3066 ND
3068 ND
3069 ND
3070 ND
3079 ND
3080 ND
3081 ND
3083 ND
3085 ND
3088 ND
3089 ND
3090 ND
3092 ND
3093 ND
3094 ND
3096 ND
3097 ND
3100 ND
3101 ND
3104/2212* ND
3105 ND
3106*/2608 ND
3108 ND
3110 ND
3112 ND
8.3xlO"8
4.6xlO'8
2.4xlO'8
1.4xlO'8
9.6x1 0'9
1.2xlO"9
~
—
—
—
--
--
--
—
«
—
--
--
—
—
—
—
—
—
—
—
—
—
—
..
—
—
—
—
—
—
—
--
--
~
* Asterisk indicates episode number
Species listed is for
Flathead Catfish
Catfish
Catfish
Carp
Channel Catfish
White Bass
Longear Sunfish
Chinook Salmon
Brown Trout
Lm Bass
Sm Bass
Bluegill
Lm Bass
Spotted Seatrout
Bigmouth Buffalo
Freshwater Drum
Atl. Croaker
Trout
Sheepshead
White Bass
Lm Bass
White Bass
Lm Bass
Black Drum
Bluegill
White Crappie
White Crappie
Warmouth
Lm Bass
Channel Catfish
Brown Bullhead
Brown Bullhead
White Perch
Brown Trout
Sm Bass/Lm Bass
Lm Bass
Walleye
Walleye
Carp
Walleye
associated with sample
CA - Calipatria - Alamo R.
OR - Owyhee - Owyhee R.
IL - East St. Louis - Mississippi River below Sauget
IL - Quincy - Mississippi R.
TN - Memphis - Mississippi R.
MO - West Alton - Mississippi R.
VA - Cartersville - James R.
NY - Olcott - Lake Ontario
NY - Rochester - Lake Ontario
ME - Lewiston - Androscoggin R.
MI - River Rouge - Rouge R.
I A - Hamburg - Nishnabotna R.
MO - Lexington - Missouri R.
LA -Moss Lake - Calcasieu R.
LA - Baton Rouge - Mississippi R.
LA - Union - Mississippi R .
TX - Morgan Point - Houston Ship Channel
TX - Corpus Christi - Inner Harbor
TX - Port Arthur - Neches R. (tidal)
OK - Kaw Reservoir
LA - Monroe - Ouachita R.
TX - Lufkin - Lake Sam Rayburn
LA - Oak Ridge - Bayou Bonne Idee
TX - Freeport - Brazos R.
LA - Deridder - Anacoco Bayou
OK - Muskogee - Webbers Falls
OK - Pyrer Creek - Fort Gibson Reservoir
LA - Hodge - Dugdemona R.
TX-Diboll- Neches R.
PA - Torresdale - Delaware R.
PA - Eddystone - Delaware R.
DE - Tybouts Corner - Red Lion Creek
MD - Baltimore - Baltimore Harbor
PA - Paoli - Little Valley Creek
PA - Philadelphia - Schuylkill R.
OK - Fort Cobb - Fort Cobb Reservoir
WI - U. Pentenwell Flow - Wisconsin R.
WI - Merrill - Wisconsin R.
WI -Hudson- St. CroixR.
MN - Little Falls - Mississippi R.
actually used for the risk calculations.
the sample used.
D-10-37
-------
Table D-10 TrtfUralin(cont)
Epbode Cone. (n^R) Eitlmatcd Rlik Spectci Location
3113
3117
3118
3120
3125
3141
3146
3148
3168
3172
3180
3182
3183
3184/2133*
3188
3193
3216
3218
3219
3231
3249
3252
3258
3259
3266
3267
3288
3290
3298
3299
3300
3301
3302
3303
3304
3305
3306
3308
3310
3311
3312
3313
3314
3336
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Channel Catfish/Carp
Lake Trout
Walleye
Bass
White Bass
Northern Pike
Walleye
Walleye
Lm Bass
Lm Bass
Lm Bass
Rock Bass
Sauger
Blue Catfish/W. Crappie
Lm Bass
Sm Bass
Squawfish
Squawfish
White Sturgeon
Sm Bass
Brook Trout
Lm Bass
Spot
Lm Bass
Black Crappie
Rainbow Trout
Squawfish
Redear Sunfish
Lm Bass
Lm Bass
Sm Bass
Northern Pike
Lm Bass
Sm Bass
Northern Pike
Sm Bass
Sm Bass
Northern Pike
Walleye
Sm Bass
Sm Bass
Sm Bass
White Bass
Spotted Seatrout
IL -Geneva- Fox R.
IL - Waukegan - Lake Michigan
MI - Escanaba - E scan aba R.
MI - Saugatuck - Kalamazoo R.
MN - Red Whig - Mississippi R.
WI - Milwaukee - Milwaukee R.
WI - Rothschild - Wisconsin R.
MI - Muskegon - Muskegon Lake
AL - Mobile - Cold Creek
AL/GA - State Line - Coosa R.
GA - Early County - Spring Creek
KY-Russellville-MudR.
KY - Catlettsburg - Big Sandy R.
MS - Redwood - Yazco R.
TN - Nickajack Reservoir
VA - Brookneal - Roanoke R.
OR - St. Helens - Columbia R,
OR - Wauna - Columbia R.
OR - Dalles - Columbia R.
WA - Richland - Yakima R.
ID - Coeur d'Alene - Coeur d'Alene R.
ID -Parma - Boise R.
VA - Norfolk - S. Br. Elizabeth R.
NY - Fort Miller - Hudson R.
AZ -GilaBend -GilaR.
CA - Anderson - Sacramento R.
CA - Salinas - Blanco Drain
C A - Stockton - Port of Stockton
NY -Buffalo- Buffalo R.
NY - N. Tonawanda - Niagara R.
NY - Porter - Niagara R. Delta
NY - Olcott - Eighteen Mile Creek
NY - Lewiston - Niagara R.
NY - Newton Falls - Oswegatchie R.
NY - Dexter - Black River Delta
NY - Massena - Raquette R.
NY - Massena - Grass R.
NY - Rouses Pt. - Richelieu R.
PA - Easton - Lehigh R.
WV - New Martinsville - Ohio R.
WV - Wheeling - Ohio R.
WV - Bedington - Opequon Creek
WV - Winfield - Kanawha R.
GA - St. Marys - North R. (mouth)
* Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-38
-------
T«We D-10 TrtnuraHn(cont)
Episode Cone, (ngfc) Estimated Riik Speclei Location
3346
3348
3350
3354
3355
3375
3376
3377
3401
3403
3409*72709
3412
3414
3415
3419
3420
3421
3422
3426
3427
3428
3429
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Lm Bass
White Perch
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Sm Bass
Channel Catfish/Sin Bass
Channel Catfish/Sm Bass
Freshwater Drum
Green Sunfish
White Perch
Lm Bass
Bluefish
Bluefish
Bluefish
Weakfish
NC - Plymouth - Roanoke R.
SC - Georgetown - Sampit R.
TN - Calhoun - Hiwassee R.
CA - Stockton - New Mormon Slough
CA - Stockton - Old Mormon Slough
GA - Austell - Chattahoochee R.
GA - Whitesburg - Chattahoochee R.
GA - Franklin - Chattahoochee R.
TN - Hardin Co. - Tennessee R.
TN - Kingsport - S. Fork Holston R.
NY - Peekskill - Hudson R.
NY - Oswego - Oswego Harbor
PA - Pittston - Susquehanna R.
PA - Ransom - N. Br. Susquehanna R.
PA - Erie - Lake Erie
PA - Spring Grove - Codorus Creek
VA - Covington - Jackson R.
VA - Riverdale - Blackwater R.
NJ - Carteret - Arthur Kill R.
NJ - Elizabeth - Newark Bay
NJ - Newark - Passaic R.
NJ - Salem - Delaware R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-39
-------
D-10-40
-------
Table D-10 (com)
Estimated Cancer Rbks from Ingestion of Fish Contaminated with Heptachlor
(Consumption Rate 6.5 fi/day)
Episode Coac.(agfc) Eitimated Rbk Speciet
Location
3310 0.28 I.2xlO'7
2228 ND
2328 ND
2329 ND
2356 ND
2410 ND
3036/2190* ND
3046/2199* ND
3048 ND
3063 ND
3065 ND
3066 ND
3068 ND
3069 ND
3070 ND
3079 ND
3080 ND
3081 ND
3083 ND
3085 ND
3088 ND
3089 ND
3090 ND
3092 ND
3093 ND
3094 ND
30% ND
3097 ND
3100 ND
3101 ND
3104/2212* ND
3105 ND
3106*/2608 ND
3108 ND
3110 ND
3112 ND
3113 ND
3114 ND
3115 ND
3117 ND
* Asterisk indicates episode number
Walleye
Longear Sunfish
Chinook Salmon
Brown Trout
Lm Bass
Sm Bass
Blucgil!
Lm Bass
White Bass
Spotted Seatrout
Bigmouth Buffalo
Freshwater Drum
All. Croaker
Trout
Sheepshead
White Bass
Lm Bass
White Bass
Lm Bass
Black Drum
Bluegill
White Crappie
White Crappie
Warmouth
Lm Bass
Channel Catfish
Brown Bullhead
Brown Bullhead
White Perch
Brown Trout
Sm Bass/Lm Bass
Lm Bass
Walleye
Walleye
Carp
Walleye
Carp/Channel Catfish
Carp
Catfish
Lake Trout
associated with sample
PA-Easton-LehighR.
VA - Carter sville - James R.
NY - Olcott - Lake Ontario
NY - Rochester - Lake Ontario
ME - Lewiston - Androscoggin R.
MI - Ri\er Rouge - Rouge R.
IA - Hamburg - Nishnabotna R.
MO - Lexington - Missouri R.
MO - West Alton - Mississippi R.
LA - Moss Lake - Calcasieu R.
LA - Baton Rouge - Mississippi R.
LA - Union - Mississippi R.
TX - Morgan Point - Houston Ship Channel
TX - Corpus Christi - Inner Harbor
TX - Port Arthur - Neches R. (tidal)
OK - Kaw Reservoir
LA - Monroe - Ouachita R.
TX - Lufkin - Lake Sam Rayburn
LA - Oak Ridge - Bayou Bonne Idee
TX - Freeport - Brazos R.
LA - Deridder - Anacoco Bayou
OK - Muskogee - Webbers Falls
OK - Pyrer Creek - Fort Gibson Reservoir
LA - Hodge - Dugdemona R.
TX-Diboll- Neches R.
PA - Torresdale - Delaware R.
PA - Eddystone - Delaware R.
DE - Tybouts Corner - Red Lion Creek
MD - Baltimore - Baltimore Harbor
PA - Paoli - Little Valley Creek
PA - Philadelphia - Schuylkill R.
OK - Fort Cobb - Fort Cobb Reservoir
WI - U. Pentenwell Flow - Wisconsin R.
WI - Merrill - Wisconsin R.
WI -Hudson- St. CroixR.
MN - Little Falls - Mississippi R.
IL - Geneva- Fox R.
IL - Quincy - Mississippi R.
IL - East St. Louis - Mississippi River below Sauget
IL - Waukegan - Lake Michigan
actually used for the risk calculations.
Species listed is for the sample used.
D-10-41
-------
Episode Cone, (ng'g) Estimated Risk
3118
3120
3125
3141
3146
3148
3168
3172
3180
3182
3183
3184/2133*
3188
3212
3216
3218
3219
3231
3249
3252
3258
3259
3266
32t>7
3282
3288
3290
3298
3299
3300
3301
3302
3303
3304
3305
3306
3308
3311
3312
3313
3314
3315
3336
3346
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
* Asterisk indicates episode number
Table D-10 Heptachlor
Specie*
Walleye
Bass
White Bass
Northern Pike
Walleye
Walleye
Lm Bass
Lm Bass
Lm Bass
Rock Bass
Sauger
Blue Catfish/W. Crappie
Lm Bass
Catfish
Squawfish
Squawfish
White Sturgeon
Sm Bass
Brook Trout
Lm Bass
Spot
Lm Bass
Black Crappie
Rainbow Trout
Flathead Catfish
Squawfish
Redear Sunfish
Lm Bass
Lm Bass
Sm Bass
Northern Pike
Lm Bass
Sm Bass
Northern Pike
Sm Bass
Sm Bass
Northern Pike
Sm Bass
Sm Bass
Sm Bass
White Bass
Lm Bass
Spotted Seatrout
Lm Bass
(coot)
Location
MI - Escanaba - Escanaba R.
MI - Saugatuck - Kalamazoo R.
MN - Red Wing - Mississippi R.
WI - Milwaukee - Milwaukee R.
WI - Rothschild - Wisconsin R.
MI - Muskegon - Muskegon Lake
AL - Mobile - Cold Creek
AL/GA - State Line - Coosa R.
G A - Early County - Spring Creek
KY-Russellville-MudR.
KY - Catlettsburg - Big Sandy R,
MS - Redwood - Yazoo R.
TN - Nickajack Reservoir
OR - Owyhee - Owyhee R,
OR - St. Helens - Columbia R.
OR - Wauna - Columbia R.
OR - Dalles - Columbia R
WA - Richland - Yakima R.
ID - Coeur d'Alene - Coeur d'Alene R.
ID - Parma - Boise R.
VA - Norfolk - S. Br. Elizabeth R.
NY - Fort Miller - Hudson R.
AZ -GilaBend-GilaR.
CA - Anderson - Sacramento R.
CA - Calipatria - Alamo R.
CA - Salinas - Blanco Drain
CA - Stockton - Port of Stockton
NY - Buffalo - Buffalo R.
NY - N. Tonawanda - Niagara R.
NY - Porter - Niagara R. Delta
NY - Olcott - Eighteen Mile Creek
NY - Lewiston - Niagara R.
NY - Newton Falls - Oswegatchie R.
NY - Dexter - Black River Delta
NY - Massena - Raquette R.
NY - Massena - Grass R.
NY - Rouses Pt. - Richelieu R.
WV - New Martinsville - Ohio R.
WV - Wheeling - Ohio R.
WV - Bedington - Opequon Creek
WV - Winfield - Kanawha R.
PA - Lebanon - Union Canal
G A - St. Marys - North R. (mouth)
NC - Plymouth - Roanoke R.
associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-1Q-42
-------
Eplaode
Table D-10 Heptachh>r(cont)
Cone, (ng/g) Estimated Rlik Specie* Location
3348
3350
3354
3355
3375
3376
3377
3401
3403
3409*/2709
3412
3414
3415
3419
3420
3421
3422
3426
3427
3428
3429
3444
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
White Perch
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Sm Bass
Channel Catfish/Sm Bass
Channel Catfish/Sm Bass
Freshwater Drum
Green Sunfish
White Perch
Lm Bass
Bluefish
Bluefish
Bluefish
Weakfish
Channel Catfish/Lm Bass
SC - Georgetown - Sampit R.
TN - Calhoun - Hiwassee R.
CA - Stockton - New Mormon Slough
CA - Stockton - Old Mormon Slough
GA - Austell - Chattahoochee R.
GA - Whitesburg - Chattahoochee R.
GA - Franklin - Chattahoochee R.
TN - Karelin Co. - Tennessee R.
TN - Kingsport - S. Fork Holston R.
NY - Peekskill - Hudson R.
NY - Oswego - Oswego Harbor
PA - Pittston - Susquehanna R.
PA - Ransom - N. Br. Susquehanna R.
PA - Erie - Lake Erie
PA - Spring Grove - Codorus Creek
VA - Covington - Jackson R.
VA - Riverdale - Blackwater R.
NJ - Carteret - Arthur Kill R.
NJ - Elizabeth - Newark Bay
NJ - Newark - Passaic R.
NJ - Salem - Delaware R.
TN - Memphis - Mississippi R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-43
-------
D-10-44
-------
Table D-10 (cont)
Estimated Cancer Risks from Digestion of Fish Contaminated with Dicofol
(Consumption Rate 6.5 g/day)
EpUodc Cone, (ng/g) Eitlmatcd Riik Specie)
Location
3117 14.9
3288 11.8
3212 11.6
3094 10.4
3282 5.13
2328 3.88
3444 2.83
2329 2.82
3252 1.58
3141 1.51
3377 1.25
3184/2133* 0.79
3375 0.78
3083 0.76
3080 0.7
3046/2199* 0.66
3376 0.46
2228 ND
2356 ND
2410 ND
3036/2190* ND
3048 ND
3063 ND
3065 ND
3066 ND
3068 ND
3069 ND
3070 ND
3079 ND
3081 ND
3085 ND
3086 ND
3088 ND
3089 ND
3090 ND
3092 ND
3093 ND
3096 ND
3097 ND
3100 ND
6.1xlO'7
4.8xlO'7
4.7xlO'7
4.2xlO'7
2.1xlO'7
1.6xlO'7
1.2xlO'7
1.2xlO'7
6.5xlO'8
6.2xlO'8
S.lxlO'8
3.2xlO"8
3.2xlO'8
3.1xlO'8
2.9xlO'8
2.7xlO'8
1.9xlO'8
--
--
--
—
~
--
--
-
--
—
~
—
—
--
--
--
--
—
--
—
--
-
—
* Asterisk indicates episode number
Species listed is
Lake Trout
Squawfish
Catfish
Channel Catfish
Flathead Catfish
Chinook Salmon
Channel Catfish
Brown Trout
Lm Bass
Northern Pike
Lm Bass
Blue Catfish
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Longear Sunfish
Lm Bass
Sm Bass
Bluegill
White Bass
Spotted Seatrout
Bigmouth Buffalo
Freshwater Drum
Atl. Croaker
Trout
Sheepshead
White Bass
White Bass
Black Drum
Red Drum
Bluegill
White Crappie
White Crappie
Warmouth
Lm Bass
Brown Bullhead
Brown Bullhead
White Perch
IL - Waukegan - Lake Michigan
CA - Salinas - Blanco Drain
OR - Owyhee - Owyhee R.
PA - Torresdale - Delaware R.
CA - Calipatria - Alamo R.
NY - Olcott - Lake Ontario
TN - Memphis - Mississippi R.
NY - Rochester - Lake Ontario
ID -Parma- Boise R.
WI - Milwaukee - Milwaukee R.
GA - Franklin - Chattahoochee R.
MS - Redwood - Yazoo R.
GA - Austell - Chattahoochee R.
LA - Oak Ridge - Bayou Bonne Idee
LA - Monroe - Ouachita R.
MO - Lexington - Missouri R .
GA - Whitesburg - Chattahoochee R.
VA - Cartersville - James R.
ME - Lewiston - Androscoggin R.
MI - River Rouge - Rouge R.
IA - Hamburg - Nishnabotna R.
MO - West Alton - Mississippi R.
LA - Moss Lake - Calcasieu R.
LA - Baton Rouge - Mississippi R.
LA - Union - Mississippi R.
TX - Morgan Point - Houston Ship Channel
TX - Corpus Christi - Inner Harbor
TX - Port Arthur - Neches R. (tidal)
OK - Kaw Reservoir
TX - Lufkin - Lake Sam Rayburn
TX - Freeport - Brazos R.
LA - Sulfur - Bayou Dlnde
LA - Deridder - Anacoco Bayou
OK - Muskogee - Webbers Falls
OK - Pyrer Creek - Fort Gibson Reservoir
L A - Hodge - Dugdemona R.
TX-Diboll- Neches R.
PA - Eddystone - Delaware R.
DE - Tybouts Corner - Red Lion Creek
MD - Baltimore - Baltimore Harbor
associated with sample actually used for the risk calculations.
for the sample used.
D-10-45
-------
Table D-10 Dlcofol (coot)
Epliode Cone, (ngfc) Eitimated Riik Spectei Location
3101
3104/2212*
3105
3106*/2608
3108
3110
3112
3113
3114
3115
3118
3120
3125
3146
3148
3168
3172
3180
3182
3183
3188
3193
3216
3218
3219
3231
3249
3258
3259
3266
3267
3290
3298
3299
3300
3302
3303
3304
3305
3306
3308
3310
3311
3312
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Brown Trout
Sm Bass/Lm Bass
Lin Bass
Walleye
Walleye
Carp
Walleye
Carp/Channel Catfish
Carp
Catfish
Walleye
Bass
White Bass
Walleye
WaUeye
Lm Bass
Lm Bass
Lm Bass
Rock Bass
Sauger
Lm Bass
Sm Bass
Squawfish
Squawfish
White Sturgeon
Sm Bass
Brook Trout
Spot
Lm Bass
Black Crappie
Rainbow Trout
Redear Sunfish
Lm Bass
Lm Bass
Sm Bass
Lm Bass
Sm Bass
Northern Pike
Sm Bass
Sm Bass
Northern Pike
Walleye
Sm Bass
Sm Bass
PA - Paoli - Little Valley Creek
PA - Philadelphia - Schuylkill R.
OK - Fort Cobb - Fort Cobb Reservoir
WI - U . Pentenwell Flow - Wisconsin R.
WI - Merrill - Wisconsin R.
WI - Hudson - St. CroixR.
MN - Little Falls - Mississippi R.
IL - Geneva- Fox R.
IL - Quincy - Mississippi R.
IL - East St. Louis - Mississippi River below Sauget
MI - Escanaba - Escanaba R.
MI - Saugatuck - Kalamazoo R .
MN - Red Wing - Mississippi R.
WI - Rothschild - Wisconsin R.
MI - Muskegon - Muskegon Lake
AL - Mobile - Cold Creek
AL/G A - State Line - Coosa R.
GA - Early County - Spring Creek
KY - Russellville - Mud R.
KY - Catlettsburg - Big Sandy R.
TN - Nickajack Reservoir
VA - Brookneal - Roanoke R.
OR - St. Helens - Columbia R.
OR - Wauna - Columbia R.
OR - Dalles - Columbia R.
WA - Richland - Yakima R.
ID - Coeur d'Alene - Coeur d'Alene R.
VA - Norfolk - S. Br. Elizabeth R.
NY - Fort Miller - Hudson R.
AZ -GilaBend-GilaR.
C A - Anderson - Sacramento R.
CA - Stockton - Port of Stockton
NY - Buffalo - Buffalo R.
NY - N. Tonawanda - Niagara R.
NY - Porter - Niagara R. Delta
NY - Lewiston - Niagara R.
NY - Newton Falls - Oswegatchie R.
NY - Dexter - Black River Delta
NY - Massena - Raquette R.
NY - Massena - Grass R.
NY - Rouses Pt. - Richelieu R.
PA-Easton-LehighR.
W V - New Martinsville - Ohio R.
WV - Wheeling - Ohio R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-46
-------
Table D-10 Dtcofol (coot)
Epliode Cone, (ng/g) Estimated Risk Species Location
3313
3314
3336
3346
3348
3350
3354
3355
3401
3403
3409*/2709
3412
3414
3415
3419
3420
3421
3422
3426
3427
3428
3429
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Sm Bass
White Bass
Spotted Seatrout
Lm Bass
White Perch
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Sm Bass
Channel Catfish/Sm Bass
Channel Catfish/Sm Bass
Freshwater Drum
Green Sunfish
White Perch
Lm Bass
Bluefish
Bluefish
Bluefish
Weakfish
WV - Bedington - Opequon Creek
WV - Winfield - Kanawha R.
GA - St. Marys - North R. (mouth)
NC - Plymouth - Roanoke R.
SC - Georgetown - Sampit R.
TN - Calhoun - Hiwassee R.
CA - Stockton - New Mormon Slough
CA - Stockton - Old Mormon Slough
TN - Hardin Co. - Tennessee R.
TN - Kingsport - S. Fork Holston R.
NY - Peekskill - Hudson R.
NY - Oswego - Oswego Harbor
PA - Pittston - Susquehanna R.
PA - Ransom - N. Br. Susquehanna R.
PA - Erie - Lake Erie
PA - Spring Grove - Codorus Creek
VA - Covington - Jackson R.
VA - Riwrdale - Blackwater R.
NJ - Carteret - Arthur Kill R.
NJ - Elizabeth - Newark Bay
NJ - Newark - Passaic R.
NJ - Salem - Delaware R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-47
-------
D-10-48
-------
Table D-10 (cont)
Estimated Cancer Risks from Digestion of Fish Contaminated with Hexachlorobutadiene
(Consumption Rate 6.5 g/day)
Episode Cone, (ng/g) Estimated Risk Species
Location
3063 88.31
3115 10.5
3085 3.53
3068 0.81
3081 0.27
2228 ND
2328 ND
2329 ND
2356 ND
2410 ND
3036/2190* ND
3046/2199* ND
3048 ND
3065 ND
3066 ND
3069 ND
3070 ND
3079 ND
3080 ND
3083 ND
3088 ND
3089 ND
3090 ND
3092 ND
3093 ND
3094 ND
3095 ND
3096 ND
3097 ND
3100 ND
3101 ND
3104/2212* ND
3105 ND
3106*/2608 ND
3108 ND
3110 ND
3112 ND
3113 ND
3114 ND
3117 ND
6.4xlO'7
7.6x1 0'8
2.6xlO"8
5.9xlO*9
2.0xlO'9
--
—
..
—
—
—
—
—
—
—
--
—
—
—
—
—
--
-
--
—
..
—
-
—
—
—
—
—
—
—
--
--
--
—
--
Spotted Seatrout
Catfish
Black Drum
All. Croaker
White Bass
Longear Sunfish
Chinook Salmon
Brown Trout
Lm Bass
Sm Bass
Blue gill
Lm Bass
White Bass
Bigmouth Buffalo
Freshwater Drum
Trout
Sheepshead
White Bass
Lm Bass
Lm Bass
Bluegill
White Crappie
White Crappie
Warmouth
Lm Bass
Channel Catfish
Brown Bullhead
Brown Bullhead
Brown Bullhead
White Perch
Brown Trout
Sm Bass/Lm Bass
Lm Bass
Walleye
Walleye
Carp
Walleye
Carp/Channel Catfish
Carp
Lake Trout
* Asterisk indicates episode number associated with sample
Species listed is for
the sample
used.
LA - Moss Lake - Calcasieu R.
IL - East St. Louis - Mississippi River below Sauget
TX - Freeport - Brazos R.
TX - Morgan Point - Houston Ship Channel
TX - Lufkin - Lake Sam Rayburn
VA - Cartersville - James R.
NY - Olcott - Lake Ontario
NY - Rochester - Lake Ontario
ME - Lewiston - Androscoggin R.
MI - River Rouge - Rouge R.
I A - Hamburg - Nishnabotna R.
MO - Lexington - Missouri R.
MO - West Alton - Mississippi R.
LA - Baton Rouge - Mississippi R.
LA - Union - Mississippi R.
TX - Corpus Christi - Inner Harbor
TX - Port Arthur - Neches R. (tidal)
OK - Kaw Reservoir
LA - Monroe - Ouachita R.
LA - Oak Ridge - Bayou Bonne Idee
LA - Deridder - Anacoco Bayou
OK - Muskogee - Webbers Falls
OK - Pyrer Creek - Fort Gibson Reservoir
LA - Hodge - Dugdemona R.
TX -Diboll- Neches R.
PA - Torresdale - Delaware R.
PA - Schuylkill Jet. - Delaware R.
PA - Eddystone - Delaware R.
DE - Tybouts Corner - Red Lion Creek
MD - Baltimore - Baltimore Harbor
PA - Paoli - Little Valley Creek
PA - Philadelphia - Schuylkill R.
OK - Fort Cobb - Fort Cobb Reservoir
WI - U. Pentenwell Flow - Wisconsin R.
WI - Merrill - Wisconsin R.
WI -Hudson- St. CroixR.
MN - Little Falls - Mississippi R.
IL - Gene va - Fox R.
IL - Quincy - Mississippi R.
IL - Waukegan - Lake Michigan
actually used for the risk calculations.
D-10-49
-------
Table D-10 Hexachforobutadkne (cont)
EpUode Cone, (ntfg) Estimated Risk Specks
3118
3120
3125
3141
3146
3148
3168
3172
3180
3182
3183
3184/2133*
3188
3193
3212
3216
3218
3219
3231
3249
3252
3258
3259
3266
3267
3282
3288
3290
3298
3299
3300
3301
3302
3303
3304
3305
3306
3308
3310
3311
3312
3313
3314
3336
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
--
-
—
—
~
~
—
-.
—
—
--
—
-
—
—
—
~
~™
Walleye
Bass
White Bass
Northern Pike
Walleye
Walleye
Lm Bass
Lm Bass
Lm Bass
Rock Bass
Sauger
Blue Catfish/W. Crappie
Lm Bass
Sm Bass
Catfish
Squawfish
Squawfish
White Sturgeon
Sm Bass
Brook Trout
Lm Bass
Spot
Lm Bass
Black Crappie
Rainbow Trout
Flathead Catfish
Squawfish
Redear Sunfish
Lm Bass
Lm Bass
Sm Bass
Northern Pike
Lm Bass
Sm Bass
Northern Pike
Sm Bass
Sm Bass
Northern Pike
Walleye
Sm Bass
Sm Bass
Sm Bass
White Bass
Spotted Seatrout
Location
MI - Escanaba - E scan aba R.
MI - Saugatuck - Kalamazoo R.
MN - Red Wing - Mississippi R.
WI - Milwaukee - Milwaukee R.
WI - Rothschild - Wisconsin R.
MI - Muskegon - Muskegon Lake
AL - Mobile - Cold Creek
AL/G A - State Line - Coosa R.
GA - Early County - Spring Creek
KY-Russellville-MudR.
KY - Catlettsburg - Big Sandy R.
MS - Redwood - Yazoo R.
TN - Nickajack Reservoir
VA - Brookneal - Roanoke R.
OR - Owyhee - Owyhee R
OR - St. Helens - Columbia R.
OR - Wauna - Columbia R.
OR - Dalles - Columbia R.
WA - Richland - Yakiroa R.
ID - Coeur d'Alene - Coeur d'Alene R.
ID -Parma- Boise R.
VA - Norfolk - S. Br. Elizabeth R.
NY - Fort Miller - Hudson R.
AZ -GilaBend-GilaR.
CA - Anderson - Sacramento R.
CA - Calipatria - Alamo R.
CA - Salinas - Blanco Drain
C A - Stockton - Port of Stockton
NY - Buffalo - Buffalo R.
NY - N. Tonawanda - Niagara R.
NY - Porter - Niagara R. Delta
NY - Olcott - Eighteen Mile Creek
NY - Lewiston - Niagara R.
NY - Newton Falls - Oswegatchie R.
NY - Dexter - Black Ri\er Delta
NY - Massena - Raquette R.
NY - Massena - Grass R.
NY - Rouses Pt. - Richelieu R.
PA-Easton-LehighR.
W V - New Martinsville - Ohio R.
WV- Wheeling- Ohio R.
WV - Bedington - Opequon Creek
WV - Winfield - Kanawha R.
GA - St. Marys - North R. (mouth)
* Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-50
-------
Table D-10 Hexacblorobutadiene (cont)
EpUode Cone, (ng/g) Estimated Rhk Specks Location
3346
3348
3350
3354
3355
3375
3376
3377
3401
3403
3409*/2709
3412
3414
3415
3419
3420
3421
3422
3426
3427
3428
3429
3444
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Lm Bass
White Perch
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Lm Bass
Sm Bass
Channel Catfish/Sm Bass
Channel Catfish/Sm Bass
Freshwater Drum
Green Sunfish
White Perch
Lm Bass
Bluefish
Bluefish
Bluefish
Weakfish
Channel Catfish/Lm Bass
NC - Plymouth - Roanoke R.
SC - Georgetown - Sampit R.
TN - Calhoun - Hiwassee R.
CA - Stockton - New Mormon Slough
CA - Stockton - Old Mormon Slough
GA - Austell - Chattahoochee R.
GA - Whitesburg - Chattahoochee R.
GA - Franklin - Chattahoochee R.
TN - Hardin Co. - Tennessee R.
TN - Kingsport - S. Fork Holston R.
NY-Peekskill-Hudson R.
NY - Oswego - Oswego Harbor
PA - Pittston - Susquehanna R.
PA - Ransom - N. Br, Susquehanna R.
PA -Erie-Lake Erie
PA - Spring Grove - Codorus Creek
VA - Covington - Jackson R.
VA - Rivsrdale - Blackwater R.
NJ - Carteret - Arthur Kill R.
NJ - Elizabeth - Newark Bay
NJ - Newark - Passaic R.
NJ - Salem - Delaware R.
TN - Memphis - Mississippi R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-SI
-------
D-10-52
-------
Table D -10 (cont)
Estimated Cancer Risks from Ingestion of Fish Contaminated with Pentachloroanisole
(Consumption Rate 6.5 g/day)
Episode Cone, (ng/g) Eitlmatcd Rlik Specki
Location
3444
3375
3420
3094
3141
3113
3115
3376
3414
3146
3415
3258
3096
3377
3184/2133*
3312
3090
3301
3079
3114
3125
3310
3048
3193
3106*72608
3066
3100
3314
3422
3068
2328
3104/2212*
3065
3097
3081
3311
3403
3108
3421
3290
48,6
14.45
10.54
8.95
7.79
5.7
5.68
3.09
2.99
2.93
2.53
2.2
2.15
1.82
1.7
1.59
1.33
1.28
1.27
1.27
1.26
1.08
0.96
0.91
0.9
0.87
0.8
0.78
0.77
0.73
0.7
0.59
0.5
0.45
0.38
0.37
0.36
0.33
0.33
0.31
7.2xlO'8
2.1xlO'8
1.6xlO'8
1.3xlO'8
1.2xlO'8
8.5xlO'9
Q
8.4xl09
4.6xlO'9
4.4x1 0'9
4.4x1 0'9
3.8xlO'9
3.3xlO'9
3.2xlO"9
2.7xlO'9
2.5xlO"9
2.4xlO'9
2.0x1 0'9
1.9xlO'9
1.9xlO'9
1.9xlO'9
1.9xlO'9
l,6xlO'9
1.4xlO'9
1.4xlO'9
1.3xlO'9
1.3xlO'9
1.2xlO'9
1.2xlO'9
l.lxlO'9
l.lxlO'9
l.OxlO'9
8.8xlO'10
7.4X10'10
6.7xlO-10
5.7x10- 1°
5.5X10'10
5.3X10'10
4.9xlO-1°
4.9xlO-10
4.6X10'10
Channel Catfish/Lm Bass
Lm Bass
Green Sunfish
Channel Catfish
Northern Pike
Channel Catfish/Carp
Catfish
Lm Bass
Channel Catfish
Walleye
Channel Catfish
Spot
Brown Bullhead
Lm Bass
Blue Catfish
Sm Bass
White Crappie
Northern Pike
White Bass
Carp
White Bass
Walleye
White Bass
Sm Bass
Walleye
Freshwater Drum
White Perch
White Bass
Lm Bass
All. Croaker
Chinook Salmon
Sm Bass
Bigmouth Buffalo
Brown Bullhead
White Bass
Sm Bass
Lm Bass
Walleye
White Perch
Redear Sunfish
TN - Memphis - Mississippi R.
GA - Austell - Chattahoochee R.
PA - Spring Grove - Codorus Creek
PA - Torresdale - Delaware R.
WI - Milwaukee - Milwaukee R.
IL - Geneva- Fox R.
IL - East St. Louis - Mississippi River below Sauget
GA - Whitesburg - Chattahoochee R.
PA - Pittston - Susquehanna R.
WI - Rothschild - Wisconsin R.
PA - Ransom - N. Br. Susquehanna R.
VA - Norfolk - S. Br. Elizabeth R.
PA - Eddystone - Delaware R.
GA - Franklin - Chattahoochee R.
MS - Redwood - Yazoo R.
WV- Wheeling- Ohio R.
OK - Pyrer Creek - Fort Gibson Reservoir
NY - Olcott - Eighteen Mile Creek
OK - Kaw Reservoir
IL - Quincy - Mississippi R.
MN - Red Wing - Mississippi R.
PA - Easton - Lehigh R.
MO - West Alton - Mississippi R.
VA - Brookneal - Roanoke R.
WI - U. Pentenwell Flow - Wisconsin R.
LA - Union - Mississippi R.
MD - Baltimore - Baltimore Harbor
WV - Winfield - Kanawha R.
VA - Riverdale - Blackwater R.
TX - Morgan Point - Houston Ship Channel
NY - Olcott - Lake Ontario
PA - Philadelphia - Schuylkill R.
LA - Baton Rouge - Mississippi R.
DE - Tybouts Corner - Red Lion Creek
TX - Lufkin - Lake Sam Rayburn
WV - New Martinsville - Ohio R.
TN - Kingsport - S. Fork Holston R.
WI - Merrill - Wisconsin R.
VA - Covington - Jackson R.
C A - Stockton - Port of Stockton
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-S3
-------
Table D-10 Pentachloroanlsole(cont)
Episode Cone, (ng/g) Estimated Risk Species
3348 0.28 4.2xlO'10
3101 0.27 4.0xlO'10
3118 0.19 2.8xlO'10
3426 0. 16 2.4xlO'10
2228 ND
2329 ND
2356 ND
2410 ND
3036/2190* ND
3046/2199* ND
3063 ND
3069 ND
3070 ND
3080 ND
3083 ND
3085 ND
3088 ND
3089 ND
3092 ND
3093 ND
3105 ND
3110 ND
3112 ND
3117 ND
3120 ND
3148 ND
3168 ND
3172 ND
3180 ND
3182 ND
3183 ND
3188 ND
3212 ND
3216 ND
3218 ND
3219 ND
3231 ND
3249 ND
3252 ND
3259 ND
3266 ND
3267 ND
3282 ND
3288 ND
* Asterisk indicates episode number
White Perch
Brown Trout
Walleye
Bluefish
Longear Sunfish
Brown Trout
Lm Bass
Sm Bass
Bluegill
Lm Bass
Spotted Seatrout
Trout
Sheepshead
Lm Bass
Lm Bass
Black Drum
Bluegill
White Crappie
Warmouth
Lm Bass
Lm Bass
Carp
Walleye
Lake Trout
Bass
Walleye
Lm Bass
Lm Bass
Lm Bass
Rock Bass
Sauger
Lm Bass
Catfish
Squawfish
Squawfish
White Sturgeon
Sm Bass
Brook Trout
Lm Bass
Lm Bass
Black Crappie
Rainbow Trout
Flathead Catfish
Squawfish
associated with sample
Location
SC - Georgetown - Sampit R.
PA - Paoli - Little Valley Creek
MI - E scan aba - E scan aba R.
NJ - Carteret - Arthur Kill R.
VA - Cartersville - James R.
NY - Rochester - Lake Ontario
ME - Lewiston - Androscoggin R.
MI - River Rouge - Rouge R.
IA • Hamburg - Nishnabotna R.
MO - Lexington - Missouri R.
LA - Moss Lake - Calcasieu R
TX - Corpus Christi - Inner Harbor
TX - Port Arthur - Neches R. (tidal)
LA - Monroe - Ouachita R.
LA - Oak Ridge - Bayou Bonne Idee
TX - Freeport - Brazos R.
LA - Deridder - Anacoco Bayou
OK - Muskogee - Webbers Falls
LA - Hodge - Dugdemona R.
TX -Diboll- Neches R.
OK - Fort Cobb - Fort Cobb Reservoir
WI -Hudson- St. CroixR.
MN - Little Falls - Mississippi R.
IL - Waukegan - Lake Michigan
MI - Saugatuck - Kalamazoo R.
MI - Muskegon - Muskegon Lake
AL - Mobile - Cold Creek
AL/GA - State Line - Coosa R.
GA - Early County - Spring Creek
KY-Russellville-MudR.
KY - Catlettsburg - Big Sandy R.
TN - Nickajack Reservoir
OR - Owyhee - Owyhee R.
OR - St. Helens - Columbia R.
OR - Wauna - Columbia R.
OR - Dalles - Columbia R.
WA - Richland - Yakima R.
ID - Coeur d'Alene - Coeur d'Alene R.
ID -Parma- Boise R.
NY - Fort Miller - Hudson R.
AZ -GilaBend -GilaR.
CA - Anderson - Sacramento R.
CA - Calipatria - Alamo R.
CA - Salinas - Blanco Drain
actually used for the risk calculations.
Species listed is for the sample used.
D-10-54
-------
Table D-10 Pentachloroanbole(cont)
Epbode Cone, (ng/g) Estimated Risk Specie* Location
3298
3299
3300
3302
3303
3304
3305
3306
3308
3313
3336
3346
3350
3354
3355
3401
3409*/2709
3412
3419
3427
3428
3429
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Lm Bass
Lm Bass
Sm Bass
Lm Bass
Sm Bass
Northern Pike
Sm Bass
Sm Bass
Northern Pike
Sm Bass
Spotted Seatrout
Lm Bass
Lm Bass
Lm Bass
LmBass
Lm Bass
Lm Bass
Sm Bass
Freshwater Drum
Blue fish
Blucfish
Weakfish
NY - Buffalo - Buffalo R.
NY - N. Tonawanda - Niagara R.
NY - Porter - Niagara R. Delta
NY - Lewiston - Niagara R.
NY - Newton Falls - Oswegatchie R.
NY - Dexter - Black River Delta
NY - Massena - Raquette R.
NY - Massena - Grass R.
NY - Rouses Pt. - Richelieu R.
WV - Bedington - Opequon Creek
GA - St. Marys - North R. (mouth)
NC - Plymouth - Roanoke R.
TN - Calhoun - Hiwassee R,
CA - Stockton - New Mormon Slough
CA - Stockton - Old Mormon Slough
TN - Hardin Co. - Tennessee R.
NY - Peekskill - Hudson R.
NY - Oswego - Oswego Harbor
PA - Erie - Lake Erie
NJ - Elizabeth - Newark Bay
NJ - Newark - Passaic R.
NJ - Salem - Delaware R.
Asterisk indicates episode number associated with sample actually used for the risk calculations.
Species listed is for the sample used.
D-10-55
-------
D-10-56
-------
EPA
United States
Environmental Protection Agency
(WH-551)
Washington, DC 20460
Official Business
Penalty for Private Use
$300
* 1 9 9 2
THE YEAR OF
CLEAN WATER
------- |