PA United States Environmental Protection Agency Off ice of Water (WH-546) 832 B-92-001 April 1992 Municipal Water Pollution Prevention Bibliography 992 if THE YEAR OF CLEAN WTER Printed on Recycled Paper ------- ------- MIVPP Bibliography - October t, t99t r PREFACE The Pollution Prevention Act of 1990 established pollution prevention as national policy This Act sets forth a formal legislative charter for EPA to establish programs that promote pollution prevention. Specifically, the Act establishes a hierarchy of waste management activities placing source reduction as the most preferred option. Source reduction refers to preventing or reducing the generation of waste at the source before it becomes a waste management problem. To accomplish this goal in the area of domestic waste treatment, EPA is initiating the Municipal Water Pollution Prevention (MWPP) program. The MWPP Program is a voluntary and cooperative effort by EPA, State governments and municipalities to: fl Prevent NPDES permit violations and maintain high compliance rates by publicly owned treatment works (POTWs); fl Maximize .the useful lives of POTWs through reduced wastewater flows and loading, and effective operation and maintenance; and fl Ensure effective and timely planning and financing for future needs and growth before permit violations occur. An effectively designed and implemented MWPP program can: fl Reduce the need for substantial additional investment in the municipal pollution control infrastructure by emphasizing source reduction at the POTW, not increases in the size and complexity of the treatment works. fl Improve usability of sludge, increase ability of local community expansion, reduce operation and compliance costs, and enhance worker safety. This document has been designed for the use of POTW operators and dischargers to POTWs It provides a listing of the most current literature available on pollution prevention as it relates to municipal wastewater. The literature has been categorized into the following sections: pretreatment - with specific citations for tanning, metal finishing, and aircraft cleaning; PACT (Powdered Activated Carbon Treatment); legal and policy issues; enforcement; municipalities; land application of sludge- surface and ground water; and miscellaneous. Many of these documents contain case studies that may serve as model pollution prevention programs. These sources are indicated in the biblioaraohv with an asterisk (*). This bibliography also gives interested parties direct access to each source. A telephone number is provided at the end of each citation to assist the reader in acquiring further information on each source or a copy of the source. ------- ------- MWPP Bibliography - October 1, 1991 CONTENTS I. PRETREATMENT . . . . . . , . • 1 A. General ..... 1 B. Tanning Industry 5 C. Metal Finishing 5 D. Aircraft 7 H. PACT (Powdered Activated Carbon'Treatment) ... 8 III. LEGAL AND POLICY RELATED ISSUES . . g IV. ENFORCEMENT ^ V. MUNICIPALITIES . . '. 12 VI. LAND APPLICATION OF SLUDGE 14 VII. SURFACE AND GROUND WATER ' 15 VIII. MISCELLANEOUS 16 ------- ------- MWPP Bibliography ~ October 1, 1991 I. PRETREATMENT A. General Austin, Scott R., et al., Toxic Pollutant Removals and Removal Credits at a Major POTW • Proceedings of the 40th Industrial Waste Conference. Purdue University, (May 14-15 1985 DD 639-647). Reprints are available through Lewis Publishers at (313) 475-8619. ' Removal credits to companies that discharge to public sewers are an essential part of the EPA's program to establish equivalent wastewater disposal burdens on direct and indirect dischargers as mandated by the Clean Water Act. Basing the removal credits on the performance of individual publicly owned treatment works (POTWs), however, does not fully ' establish this equivalency. Since pollutants are easier to remove from concentrated wastestreams than from more dilute wastestreams, industrial users of POTWs with high toxic pollutant loadings will have higher revised pretreatment standards and lower costs than users'of less industrialized systems. The Sanitation District of Los Angeles County's experience indicates that administering removal credits may be more complicated than had been anticipated. The Sanitation District's data indicate that a single year's data may not adequately characterize the long-term performance of a wastewater treatment plant. Beall, John H., "Current Status of EPA's Industrial Pretreatment Program," The Georgia Operator, (Spring 1985, p. 4). Reprints are available through the Georgia Water and Pollution Control Association at (404) 429-0187. The Georgia Environmental Protection Division assumes the responsibility for industrial pretreatment program development for publicly owned treatment works (POTWs) with design flows less than 5 mgd and in those cases where one or two industries discharge to the POTW. As a result of such programs, many POTWs have experienced improved performance at their plants as industrial contributors pretreat their process wastewaters. Categorical standards and program implementation issues are surveyed. * Bringer, Robert P., "Making Pollution Prevention Pay." EPA Journal. (1984, Vol 10 No 10 DD 28-29). Reprints are available through the EPA Library at (202) 260-5922. ' ' ' The 3M Company made pollution prevention an integral part of its worldwide manufacturing operations and environmental policy in 1975. Savings resulted from pollution control equipment purchases that were eliminated or delayed, raw materials saved and operating costs reduced, energy saved, and sales retained on products that might otherwise have been taken off the market as environmentally unacceptable. Page 1 ------- MWPP Bibliography - October 1,1991 * Calvin, D.W., et al., "Integrated Waste Management: An Industrial Perspective, 'Toxic Contamination in Large Lakes Volume III. (1988. pp. 165-175). Reprints are available through Lewis Publishers at (313) 475-8619. The Midland, Michigan location is abundant in natural resources, particularly : brine, this facility is DOWs specialty chemical production headquarters, more than 500 different products are produced at this site. The company began a policy at the Midland facility to determine what type and quantity of waste will be generated before any new product is manufactured. DOWs mission is to minimize unnecessary risks while maximizing the benefit of products and services to the rest of society. This paper discusses the production, disposal, and communication options (with a focus on wastewater) necessary to achieve their goal. * Cootey, Robert V., et al., eds., 'Municipal Pretreatment Program Development," Journal of the Water Pollution Control Federation. (July 1982, Vol. 54, No. 7, pp. 1067-1077). Reprints are available through the Water Pollution Control Federation Library at (703) 684-2402. The requirements and development of a publicly owned treatment works (POTW) pretreatment program are described. Elements of program development include an industrial inventory, establishment of pretreatment limitations, a monitoring enforcement program, arrangements with legal authorities, appropriate funding, and an information program to educate industry and the general public. Three case histories illustrate development of toxic limitations, control of operational problems, and analysis of control measures. Santa Cruz, California, established rational discharge limits by performing mass balance analyses of the pretreatment works to determine allowable influent concentrations. Clark County, Nevada, developed a program to determine the contribution of pollutants from all users, domestic and industrial, and evaluate several treatment options. Operational problems at Albany, Georgia, were solved after an industrial monitoring program determined that two industries out of 44 were responsible for most of the problems. The development of Seattle, Washington's metropolitan pretreatment program was presented as an illustration of the entire pretreatment process. Gold, Tod A., 'EPA's Pretreatment Program," Boston College Environmental Affairs Law Review, (1989, Vol. 16, pp. 459-530). Reprints are available through the Boston College Environmental Affairs Law Review at (617) 552-8553. EPA's efforts to control the discharge of toxins into surface waters have shifted to address pretreatment standards that require industrial users to treat their wastewater before it reaches publicly owned treatment works (POTWs). Pretreatment standards are comprised of three tiers, but standards can be modified when individual circumstances warrant. The local and Federal legal disputes among industry, environmental groups, and EPA that have shaped the pretreatment program are considered. Enforcement options are discussed. Page 2 ------- MWPP Bibliography - October 1, 1991 * Gunthert and Hajek, 'Industrial Wastewater Pretreatment of a Dental-Pharmaceutical Company." Pretreatment in Chemical Water and Wastewater Treatment. (iaa« pp 179.18?) Reprints are available through SpringerrVerlag Publishers at (212) 460-1500. The industrial wastewater from this dental-pharmaceutical company contains compounds that cannot be discharged into the municipal wastewater system without pretreatment. In order to treat the different streams from the wastewater settling tanks, buffer and neutralization tanks are provided. If • necessary, anti-foam agents can be added. Before the pretreated wastewater is discharged into the municipal wastewater system, it is monitored as to its composition. The paper discusses the expansion of the facility in 1986 and 1987 to meet modern sanitary engineering standards during excessive overloads. * Hubbell, George, et al., "Municipal Pretreatment Program Goes On-Line,' Water Engineering and Management, (January 1986, Vol. 133, No. 1, pp. 22-24). Reprints are available through Water Engineering and Management at (312) 298-6622. An industrial pretreatment program involving more than 5,700 industrial and commercial businesses was implemented in Flint, Michigan. The program is designed to prevent the introduction of toxic and incompatible pollutants into publicly owned treatment works that will receive inadequate treatment. Establishing the pretreatment system program entailed surveying potential users, developing discharge limitations, devising a monitoring program and evaluating equipment needs. Interrante, John V., "Pretreatment of Fluoride Bearing Wastewaters," Toxic and Hazardous Wastes: Proceedings of the 7th Mid-Atlantic Industrial Waste Conference. fJune ?*-?* lore pp. 74-92). Reprints are available through BCM Engineers, Inc. at (215) 825-3800. The various methods available for pretreatment of fluoride bearing wastewaters include: (1) Precipitation/clarification using lime and/or calcium chloride; (2) Two-stage precipitation/clarification using aluminum sutfate to "polish" the effluent from method 1. Treatability testing indicates that effluent levels of less than 20 mg/l can be achieved with a two-stage precipitation/clarification treatment scheme; (3) Precipitation/clarification using alum by itself in a one stage system; and (4) Ion exchange using activated aluminum, which is technologically feasible and can consistently achieve effluent levels well below 20 mg/l. However, this is the most expensive of the four methods described and would not be economically feasible except as a last resort. * Ling, Joseph T.,»The 3P Program: An Effective Approach to Industrial Pollution" Toxic Contamination in Large Lakes Volume JV, (1988, pp. 111-118). Reprints are availablelhTough Lewis Publishers at (313) 475-8619. ««uaii The concern of this program is the preservation of the world's large lakes from pollution. The solution requires the thoughtful consideration, planning and cooperation of those in science, technology, industry, and government' Pages ------- MWPP Bibliography- October 1,1991 working together for the public interest. It protects the environment from , pollution, especially industrial sources, saves resources, and money, and encourages the development and Implementation of new and innovative technology. The program uses 3M as an .industrial case study. * Nichols, A.B., 'Industry Initiates Source Prevention," Journal of the Water Pollution Control Federation. (January 1988, Vol. 60(1), pp. 36-44). Reprints are available through the Water Pollution Control Federation Library at (703) 684-2404. Efforts in source prevention made by 3M, Dow Chemical, Borden, and smaller firms are described. The effect on publicly owned treatment works from the adoption of source prevention by their industrial customers is discussed. In an October 1986 report, EPA states that in 25 years, aggregate waste generation volumes can be reduced by an additional 15- 30% by the extension of existing source control techniques. The Office of Technology Assessment has strongly advocated the waste minimization concept. Schauer, D., "Pretreatment Standards for Hazardous Wastes," BioCycle. (May-June 1986, Vol. 27, No. 5, pp. 45-47). Reprints are available through BioCycle at (215) 967-4135. Results of the U.S. Environmental Protection Agency's Domestic Sewage Study are summarized under the following headings: Resource Recovery and Conservation Act (RCRA) vs. pretreatment; pretreatment program; environmental concerns (water pollution, sludge contamination, air pollution, worker health and safety, overall publicly-owned treatment works' (PCTW) operation, and ground water pollution); study methods; discharge data (overview of sources, types, and quantities; nonpriority RCRA constituents, solvents and other common organics; pollutant fate within POTWs; hazardous waste discharges; and adequacy of existing governmental controls); and recommendations. Four recommendations for improving controls on hazardous waste discharges to sewers have been derived: (1) additional research, data collection, and analysis are necessary to fill information gaps; (2) improvements can be made to federal categorical standards and local pretreatment controls to enhance control of hazardous wastes discharged to sewers; (3) EPA should emphasize improvement of controls on hazardous wastes through ongoing implementation of water programs; and (4) RCRA and CERCLA should be considered along with the Clean Water Act to control hazardous waste discharges and/or receiving POTWs if the recommended additional studies indicate problems. * Zoss, Sara J. and Koenigsberger, Michael D., "Pollution Prevention Pays (3P). 3M's Response to Industrial Waste Control," Proceedings of the 39th Industrial Waste Conference. Purdue University, (May 8-10,1984, pp. 459-461). Reprints are available through Lewis Publishers at (313)475-8619. In the nine years since the Pollution Prevention Pays (3P) Program was formalized at 3M, over 1,000 programs have been developed preventing the annual generation of 90,000 tons of air pollutants, 950 million gallons of wastewater, 10,000 tons of water pollutants, and 138,000 tons of sludge and solid waste. In addition, energy savings equivalent to 254,000 barrels of fuel oil are achieved annually. Conventional methods of pollution control only deal with the symptoms of "First Generation" pollution; they are Page 4 ------- MWPP Bibliography - October 1, 1991 ineffective against "Second Generation' and Third Generation" pollution. Pollution prevention programs deal with these second and third generation pollution types. This paper lists examples and discusses some of the programs implemented by 3M. B. Tanning Industry Alexander, Dr. Ken and Donohue, Veronica, "Cleaner Technologies in the Tanning Industry" The Environmental Challenge of the igon^: Proceedings. International Conference on Poiiirtir Prevention: Clean Technologies and Clean Products. June 10-13, iflgn (Spptomhor 1QQn RePrirrts are available through the RCRA/Superfund Hotline at The British Leather Confederation is gathering information on clean technologies of leather manufacture in cooperation with other leather industrial associations. First results of this work will be presented as an example of the role that industrial associations can play in networking and promoting cleaner production. Key aspects of the work are: (1) development of a practical database of clean technologies for the leather industry; and (2) development of networks of experts on clean technoloav for the leather industry. * Tsotsos, Dimitrios, 'Recovery of Chromium from Tannery Wastewaters," The Environmental Challenge of the 1990's: Proceedings. International Conference on Pollution Prevention- Clean Technologies and Clean Products. June 1O-13, igon, (fioptomh^ 1QQn Epyy600/g 00/0J3 pp 665-675). Reprints are available through the RCRA/Superfund Hotline at (800) 424-9346. ' This demonstration project combines the requirements of minimized wastewater discharge with economical benefits for the tanning production process. This combination demonstrates that the proper functioning and operation of the related facilities is not only a matter of control by the environmental authorities but also is closely linked with the industry's economic interest (raw material saving). C. Metal Finishing Cushnie, George C., Jr., Ed., Removal of Metals From Wastewater - Neutralization and FJlgmgjioj?, (Noyes Publications, 1984). Reprints are available through Noyes Publications at (&01) 391-8484. This book is a manual of design and operating procedures for the removal of metals from industrial wastewaters by neutralization and precipitation Also covered are methods for the handling and disposal of residues from the treatment processes. Davis Mark W. and Sandy, Tom, "Zero Sludge/Zero Discharge Pretreatment System for the Metal Finishing and Plating Industry," Proceedings of the 44th Industrial Waste Conferen™ ^Id0tLe,UniVersity' (1"°' pp< 649-654). Reprints are available through Lewis Publishers at'(313) 475-8619. ' A wide variety of metals are used in the metal finishing and plating industry Although some of these metals are relatively benign, most are toxic to either humans or wildlife. Many metal finishing and plating companies discharge Page 5 ------- MWPP Bibliography- October 1,1991 their wastewater to municipal sewage treatment plants.. Since metal contaminants accumulate in the sludge produced by conventional wastewater treatment systems, thus complicating disposal, pretreatment of * the wastewater is required. Because state and local governments may have stricter standards than EPA's pretreatment standards, it is important to identify all pertinent regulatory standards before designing a treatment system. * Drabkin, Marvin and Sylvestri, Paul, Project Summary: Waste Minimization Audit Report: Case Studies of Minimization of Solvent Wastes and Electroplating Wastes at a POD Installation. EPA Hazardous Waste Engineering Research Laboratory, (March 1988). Reprints are available through EPA at (513) 569-7562. This study presents the elements of a waste minimization program, of which the audit procedure is a central component, and includes details of the waste minimization audit (WMA) procedure, its development, and its final recommended form. A case study is presented using this WMA procedure and covers audits performed at a DOD installation. Such procedures include facilities that generate listed wastes F002 and F004 as well as a facility that generates listed waste F006. Feasibility of Water Recycling as a Waste Reduction Method. Prepared for the Minnesota Waste Management Board by PACE Laboratories, Inc. (December 1985). Reprints are available through the Minnesota Waste Management Board at (612) 649-5750. A summary of the effects of recycling ion exchange treated metal finishing wastewaters on hazardous waste reduction. Hazelwood, D.L and B.J. Burgher, 'Solvent Waste Reduction and Recovery," Earth Technology Corporation, (Alexandria, VA, pp. 334-342). Reprints are available through the Earth Technology Corporation at (703) 549-8728. There are numerous industrial operations that result in waste solvent generation. Some of the most common operations include parts cleaning and degreasing, general plant clean-up and maintenance, painting, paint stripping, fuel tank cleaning, and printing. One of the largest sources of waste solvents is preparation of metal surfaces for further processing by solvents and degreasing. In light of the large quantities of waste solvents from this source and the renewed interest in solvent recovery, this paper explores the available technology, economics, and applications/limitations of waste stream reduction techniques as well as on-site and off-site recovery systems. Hillier, A.C., et al., eds., 'Process Options for Waste Minimization and Metal Recovery for the Metal Finishing Industries," The Environmental Challenge of the 1990's: Proceedings. International Conference on Pollution Prevention: Clean Technologies and Clean Products. June 10-13.1990. (September 1990, EPA/600/9-90/039, pp. 703-712). Reprints are available through the RCRA/Superfund Hotline at (800) 424-9346. There is growing environmental concern with the methods of waste disposal used for handling hazardous materials in the metal finishing industry. A resulting need exists to develop and implement the best existing and potential technologies for waste minimization and resource recovery. The Page 6 ------- MWPP Bibliography - October 1,1991 objectives of this study were to identify and briefly describe both existing and potential future methods for minimizing and recovering metallic wastes in the metal finishing industries. Included in the evaluation are the advantages and disadvantages of the various methods available and under development. • Tsai, Eric Chai-EI and Nixon, Roy, "Simple Techniques for Source Reduction of Wastes from Metal Plating Operations," Hazardous Wastes and Hazardous Materials, (Winter 1939, Vol 6 No. 1, pp. 67-78). Reprints are available through Hazardous Wastes and Hazardous Materials at (212) 289-2300. There are many simple techniques available for source reduction of wastes from metal plating operations. They may be grouped into eight categories: reactive rinsing, counterflow rinsing, dragout minimization, dragout recovery, process modifications/operational changes, material substitutions, waste exchange opportunities, and housekeeping improvements. A technical assistance project and financial incentive programs offered by Environment Canada are also described. D. Aircraft North Carolina Agricultural Extension Service. Pesticides and Water Quality. Disposal of Aircraft Rinse Water, (1988, Fact Sheet 9). Reprints are available through the North Carolina Agricultural Extension Service at (919) 515-2811. This paper discusses the disposal of aircraft rinsewater as it relates to ~ hazardous waste laws, recycling, and treatment. Rester, Darryl, 'Pesticide Application Equipment Rinse Water Recycling," The Environmental Challenge of the 1990's: Proceedings, International Conference on PollutionPrevention- Clear Technologies and Clean Products, June 10-13. 1990. teeptemhpr -mon FPA/«nn/Q Q0/0'39 pp 563-572). Reprints are available through the RCRA/Superfund Hotline at (800) 424-9346. ' Wastewater recycling involves collecting the aircraft washwater and storing the water in tanks for use as a diluent on future application jobs. Three to five, 250 jo 500 gallon tanks are normally used to store waste from various pesticides thus preventing label violations and the possibility of crop damage. Thirty percent of the applicators rinsed the aircraft over the field being treated. Ten percent modified the aircraft or used other waste disposal techniques. During the past four years, several applicators have been interviewed to determine the cost of constructing and operating the wastewater recycling systems, as well as information on problems. Page 7 ------- MWPP Bibliography - October 1,1991 II. PACT (Powdered Activated Carbon Treatment) Dietrich, M.J., Cdpa, W.M., et al., "Removal of Pollutants from Dilute Wastewater by the PACT Treatment Process," Environmental Progress. (May 1988, Vol. 7, No. 2, pp. 143-149). Reprints are available through Zimpro/Passavant, Inc. at (7i5) 359-7211. The PACT wastewater treatment system incorporates the use of powdered activated carbon in a conventional activated sludge system. The combination of physical adsorption with biological oxidation and assimilation in the PACT system has been shown to be particularly effective in treating dilute wastewaters that are variable in concentration and composition, highly colored, or contain materials that are refractive or potentially toxic to biological growth. Dilute wastewaters treated successfully in bench-scale PACT systems include those from organic chemicals, Pharmaceuticals, metal coating, shale oil retort'water, evaporation ponds, leachates, and rainwater runoff: Specific pollutants present included compounds such as phenols, cyanides, thiocyanate, pesticides, and priority pollutants. The PACT wastewater treatment process has successfully treated these wastewaters and produced effluents meeting POTW or direct environmental discharge requirements. Operational parameters and performance results obtained for a number of bench-scale PACT systems are presented. Loehr, R.C., "Reduction of Organics by Biological Treatment," Control of Organic Substances in Water and Wastewater. (1987, pp. 305-336). Reprints are available through the Uniyersity of Texas - Austin at (512) 471-4624. This chapter describes the major aerobic processes (activated sludge, aerated lagoons, oxidation ponds, trickling filters, PACT, and sedimentation), effluent quality, the factors affecting removal of organics, and typical process performance. It also identifies the type and quantity of organics that can be removed from untreated industrial wastewater, as well as municipal wastewater, by typical aerobic biological treatment processes. Data indicates that: (1) well operated publicly owned treatment works (POTWs) remove variable but significant amounts of organic priority pollutants; (2) POTW effluents contain some organic priority pollutants in low concentrations (generally < 100 micrograms/L); and (3) many of the priority pollutants can be found in POTW sludges. Available information indicates that biological treatment processes can achieve hjgh removals of organic pollutants. It is clear that microbial degradation is not the only mechanism of removal of organic compounds in biological treatment systems. Pages ------- MWPP Bibliography ~ October 1, 1991 LEGAL AND POLICY RELATED ISSUES Belpe, Marcia R., "Pollution Control Laws Against Public Facilities,' Harvard Environmental Law S^view8at (617) 495^9?"146)' ^'^ *** available through the Harvard Environmental Publicly owned treatment works and other public facilities are frequent violators of pollution law, but enforcement against publicly owned facilities is often lax. The statutory framework and causes of noncompliance are examined in light of special enforcement problems involving public discharges. A variety of remedies are evaluated in administrative and judicial enforcement contexts and funding issues are considered. It is concluded that agencies and courts have not used the full extent of their authority and have placed too much reliance on ordering compliance for enforcement. Erdheim, Eric, 'United States Marine Waste Disposal Policy,' Nearshore Waste Disposal Bostwick H. Ketchum, ed., (1985, pp. 421-460). Reprints are available through Wiley- ' Interscience at (212) 850-6000. Laws such as the Resource Conservation and Recovery Act and the Clean Air Act have made waste disposal on land and in the atmosphere more difficult, thus forcing a reevaluation of the policy of not using the marine environment for waste disposal. The marine environment is likely to be used for waste disposal to a greater extent in the future. The health of the marine environment will depend on effective implementation and integration of the Ocean Dumping Act and the Clean Water Act. For the long term, the United States needs to develop a comprehensive waste-disposal policy'that results in wastes being disposed of in the environmental medium of least risk to human health and to the environment. Hahn, H.H. and Hartmann, K.H., "Pretreatment of Industrial Wastewater: Legal and Planning Aspects - A Case Study," Pretreatment in Chemical Water and Wastewater Treatment (1988 pp. 125-137). Reprints are available through Springer-Verlag Publishers at (212) 460-1500. ' There are new administrative regulations that permit the water authorities to demand, in specific situations, industrial pretreatment. In terms of waste load or treatability, the subsequent treatment of such industrial streams in the central municipal plant may no longer be a problem. The purpose of this contribution is to describe these new regulations and to illustrate their effect by discussing one example of reorientation in combined industrial wastewater treatment. Page 9 ------- MWPP Bibliography - October 1,1991 "Law and Water: Court Clarifies Liability of Industrial POTW User," Journal of American Water Works Association. (January 1989, Vol. 81(1), p. 18). Reprints are available through the American Water Works Association at (303) 794-7711. A federal appellate court held that an industrial user of a publicly owned treatment works (POTW) could be liable under the Clean Water Act even if the user's discharge was not a significant contributor to the POTW's violation of its permit. Municipal Water Pollution Prevention Program. United States Environmental Protection Agency, Office of Water (WH-546) 21W-7002, (March 1991). Reprints are available through EPA, Office of Water at (202) 260-7779. The Municipal Water Pollution Prevention (MWPP) program encourages municipalities to apply elements of pollution prevention. Publicly owned treatment works (POTWs) not only discharge wastewater, but may contribute to the releases of various air emissions and solid waste streams as a result of their activities and the activities of their indirect dischargers. MWPP may also play a valuable part in addressing releases of various air emissions and solid waste streams. There are additional opportunities to achieve pollution prevention through industrial source reduction under the p'retreatment program. This document contains program components and options including: early warning systems, reporting mechanisms, corrective action, and program management. Funding options are identified, and the role and responsibilities of EPA are defined. Several case studies dealing with compliance maintenance on a state level are defined in the appendices. Neuman, Barry S., "Third Circuit Clears Way for National Pretreatment Program," Environmental Law Reporter. (February, 1984, pp. 10039-10046). Reprints are available through the Environmental Law Institute at (202) 939-3813. The U.S. Court of Appeals for the Third Circuit upheld the basic program established by EPA to control the discharge of wastewater from industrial facilities. The decision rendered in National Association of Metal Finishers v. EPA resolved numerous challenges to the EPA pretreatment program, a controversial aspect inherent in the Federal Water Pollution Control Act of 1977. Regulations requiring pretreatment of industrial effluents prior to their discharge to publicly owned treatment works and setting standards for metal finishing effluents were the focus of the litigation. Niehaus, Kristy A., "Clean Water Act Permitting: The NPDES Program at Fifteen," Natural Resources and Environment. (Winter 1987, pp. 16-48). Reprints are available through the American Bar Association at (312) 988-5555. Three major aspects of the current NPDES permitting program are discussed: the scope of the program, substantive permit application requirements, and permit terms and conditions. The scope of the program is broad, but it does not cover non-point sources of pollution, discharges to publicly owned treatment works and dredge or fill material discharges. The Page 10 O ------- M WPP Bibliography - October 1, 1991 differences among various application requirements are underscored for stormwater point sources, new sources and new dischargers, and nonprocess discharges. Issues such as how to regulate stormwater and how to set water quality-based limits under the NPDES program remain to be determined by EPA. Wigglesworth, David, Profiting from Wastewater Reduction in Your Small Business Alaska Health Project, (1988), Reprints are available through the Alaska Health Project at (907) 276- This manual is intended to be a guidance manual to help businesses take the first step toward evaluating waste reduction opportunities and to build awareness of the benefits of waste reduction. Compliance with environmental and occupational safety and health laws is the responsibility of each individual business and is not the focus of this manual. IV. ENFORCEMENT Toon' w°,9er' "EPA>S Carrot Turns lnto A B|9 stick'" Water Engineering and Management (July 1989, Vol. 136, No. 7, pp. 30-32). Reprints are available through Water Engineerinq and Management at (312) 298-6622. a a«uu In the early 1980s, EPA realized that despite massive Federal funding, nearly 1,500 large publicly-owned treatment works (POTWs) were not making sufficient progress to achieve secondary or greater treatment levels by deadlines mandated by the Federal Water Pollution Control Act of 1977 The agency adopted a new enforcement policy in 1984, levying stiff monetary fines for national pollution discharge elimination system violations and failures of POTWs to meet stringent treatment requirements. As of July 1988, there were still more than 400 major and 1,600 minor noncompliant plants subject to EPA's enforcement weapons. The typical enforcement response has been the assessment of $10 thousand to $10 million fines- the Agency has collected more than $10 million in penalties from municipalities to date. Wann, David, •Pretreatment Protects POTWs," WasteAge, (October, 1989 Vol 20(10) pp 136 138). Reprints are available through Waste Age at (202) 861-0708. Publicly owned treatment works are being hurt by a lack of enforcement of industrial wastewater pretreatment standards. This paper describes a few such incidents and details possible solutions. Page 11 ------- MtVPP Bibliography ~ October 1,1991 V. MUNICIPALITIES Analysis of Performance Limiting Factors (PLFs) at Small Sewage Treatment Plants. United States EPA, Office of Water (WH-546), QMPC-10-89, (April 1989). Reprints are available through EPA, Office of Water at (202) 260-7779. The Section 104(g)(1) program, the On-Srte Operator Assistance Program, has been very successful in identifying the factors that have typically limited performance of small treatment plants and in providing solutions to these problems. While the program is a cost-effective approach to meeting these needs, it is, by design, an after-the-fact approach. This paper describes many actions - mostly simple, straightforward, and inexpensive - that can be taken to forestall the problems that can limit small plant performance. * Bemardin, Frederick E., "A Waste Hauler/Disposer Meets Pretreatment Guidelines," Proceedings of the 37th Industrial Waste Conference. Purdue University, (May 11-13, 1982, pp. 369-37). Reprints are available through Lewis Publishers at (313) 475-8619. In these times of economic stress and reduced federal support it is imperative that municipalities and industries work together to solve pollution problems in a rational and economical way. This project and the cooperation between Wayne County, the provider of sanitary sewerage services, and Chem-Met Services is an example of the type of effort that will be required in the future to solve environmental problems related to wastewater discharges with respect to waste minimization. * Dalton, Frank E. and Rimkus, Raymond R., The Chicago Area's Tunnel and Reservoir Plan," Water Pollution Control Federation Journal. (December 1985, Vol. 57, No. 12, pp. 1114-1121). Reprints are available through the Water Pollution Control Federation Library at (703) 684-2404. The Tunnel and Reservoir Plan (TARP) nas Deen designed to service the rivers, in conjunction with the canals, sewers, and treatment plants, built over the past 90 years. By incorporating the existing features into its overall plan, TARP will revitalize the system already in place. Once TARP is completed, the quality of the greater Chicago area's waterways will be greatly improved and flooding will be significantly reduced. * Kendrick, Kenneth J., et al., "Pollution Control Program for the Taste of Chicago's Lakefront Festival." Proceeding of the 43rd Industrial Waste Conference. Purdue University, (1989, pp. 751-756). Reprints are available through Lewis Publishers at (313) 475-8619. With more than a million people in Grant Park and thousands more on Lake Michigan, the task of controlling pollution to the lake is a formidable and necessary one during Chicago's summer festivals. This paper describes the pollution prevention techniques implemented for the festival in 1980, 1981, and 1982. Page 12 ------- MWPP Bibliography- October 1, 1991 Lazaro, Timothy R.. Urban Hydrology: A Multidisciplinarv Perspective. (Technomic Publishing Co., Inc., 1990). Reprints are available through Technomic Publishing Co., Inc at (800) 233- 9936. This book is a basic guide to all aspects of urban hydrology, ranging from over-all planning to details of analysis and controls. Contains chapters on structural and nonstructural control measures. Lo, Philip M., "Pollution Prevention: A Winning Proposition for A POTW,1 The Environmental Challenge of the 1990's: Proceedings. International Conference on Pollution Prevention- Clean Technologies and Clean Products. June 10-13. 1990. (September 1990, EPA/600/9-90/039) Reprints are available through the RCRA/Superfund, Hotline at (800) 424-9346. Reducing toxic pollutant inputs into the sewer through pollution prevention may be needed to augment the traditional approach of regulating inputs through wastewater discharge limitations on industrial users. A few successful cases of pollution prevention using good operating practices, material substitution, process modification, and product reformulation are given as examples. In addition, recycling, recovery, and reuse can also contribute to the reduction. Ultrafiltration, ion exchange, electrowinning, and electrodialysis are successful technologies that have been applied. Quigley , Michael J., 'Discussion of Municipal Sector.' The Environmental Challenge of the 1990's: Proceedings. International Conference on Pollution Prevention: Clean Technologies and Clean Products. June 10-13.199Q. (September 1990, EPA/600/9-90/039). Reprints are available through the RCRA/Superfund Hotline at (800) 424-9346. This paper discusses attempts in the municipal sector to diagnose, at an early stage, potential compliance problems that construction grant facilities, built with federal dollars, may be experiencing as they approach their treatment capacity or the end of their design life. These problems may result in noncompliance down the road if they are not identified in the early stage of construction. * Sherry, Susan (Local Government Commission), Reducing Industrial Toxic Wastes and Discharge: The Role of POTWs. (December 1988). Reprints are available through the Local Government Commission at (916) 448-1196. This guidebook was developed by the Local Government Commission as part of a three-year project to help counties, cities, and special districts develop hazardous waste reduction policies and programs. The guidebook attempts to answer questions such as "Why Reduce Industrial Toxic Discharges to the Sewers?,'"What Can POTWs Do?," and "Have any POTWs implemented Hazardous Waste Minimization Programs?.' Page13 ------- MWPP Bibliography- October 1,1991 * Stoltenberg, David H. and Howatin, Paul J., 'Results from Great Lakes POTW Optimization Project," Journal of Environmental Engineering. (August 1987, Vol. 113(4), pp. 736-751). Reprints are available through the Journal of Environmental Engineering at (212) 705-7288. In 1982, an EPA contract to improve operation and maintenance at several major municipal wastewater treatment plants in the Great Lakes Region was completed by trie consulting engineering firm McNamee, Porter, and Seeley of Ann Arbor, Michigan. The study was conducted in two parts. Phase I consisted of comprehensive evaluations at 30 major municipal plants experiencing problems, during which reports were written and recommendations were made for operational improvements. Phase II consisted of composite correction programs at ten of the plants to actually implement the recommendations made, in Phase I. The overall results of the project are summarized and the results of the composite correction programs instituted in Trenton, Michigan, Genesee County WWTP #2, Michigan, and Wapakoneta, Ohio, are highlighted. These examples of technical assistance clearly illustrate that significant improvement in operational efficiency can be made without major investments in capital construction. Significant results are achieved by this study, in terms of cost savings and phosphorus, BOD, suspended solids, and ammonia nitrogen reductions. * Waste Reduction Assessment and Technology Transfer Teleconference. The University of Tennessee, Center for Industrial Services. Copies are available through the Waste Reduction Assistance Program at (615) 242-2456. Prepared to provide industry and state waste reduction program and regulatory personnel with practical information on how to approach and implement a multimedia waste program. Portions address opportunities for local governments to promote pollution prevention. VI. LAND APPLICATION OF SLUDGE Dempsey, B.A. and Elliott, H.A., "Agronomic Effects of Land Application of Water Treatment Sludges." Journal of the American Water Works Association. (April 1991, pp. 126-131). Reprints are available through the American Water Works Association at (303) 794-7711. Economic, regulatory, and legal constraints on alternative disposal methods are raising interest in land application of water treatment sludges. Understanding the agronomic and environmental issues is essential before a land-based disposal program is implemented. Water treatment sludges may favorably modify the pH and water-holding capacity of soils but generally have little fertilizer value. Supplemental phosphorus (P) fertilizer will usually be needed to offset the strong P-binding capacity of these sludges. Heavy metal concentrations can be limited in sludges primarily by controlling the purity of the coagulant chemicals. Page 14 ------- MWPP Bibliography ~ October 1, 1991 Sustaining Our Water Resources: A Progress Report from the Virginia Water Resources Research Center. Virginia Water Resources Research Center: Virginia Polytechnic Institute and State University, (1985). Reprints are available through the Virginia Water Resources Research Center at (703) 231-5624. A five-year plan covering 1982-87 was developed by the Virginia Water Resources Center to address and resolve water resource problems in the State. The primary objective is to develop a state water resources management plan, and to assist in developing land management measures to protect surface and ground water. Research is being conducted to examine ways to facilitate the use of water quality monitoring data being collected in the public and private sectors. The plan calls for resolving issues related to land application of sewage sludge from publicly owned treatment works. VII. SURFACE AND GROUND WATER Arniella, Ello F., et al., "Ground Water Discharges Into Publicly Owned Treatment Works (POTWs),' The Georgia Operator. (Fall 1988, pp. 6-50). Reprints are available through the Georgia Water and Pollution Control Association at (404) 429-0187. In 1987, the EPA estimated that at least one percent of all ground water in the U.S. was contaminated. Direct migration, infiltration, interaquifer exchange, and surface water recharge can cause ground-water contamination by volatile organic compounds (VOCs), non-volatile organics, or metals. Areas of high population, that rely heavily on ground water as a source of drinking water, are the most frequent sites of ground-water contamination. Publicly owned treatment works must consider hydraulics, organic content, toxicity, environmental safety, and other factors when processing ground-water discharge requests. Temporary permits should require applicants to indicate purpose, activity, discharge and flow rate, treatment requirements, expected water characteristics, and safety plans. Van Baardwijkj.Frans A.N. and Pols, H.B., "Water Pollution Prevention in the Netherlands." The Environmental Challenge of the 1990's: Proceedings. International Conference on Pollution Prevention: Clean Technologies and Clean Products. June 10-13.1990. (September 1990, EPA/600/9-90/039, pp. 686-694). Reprints are available through the RCRA/Superfund Hotline at (800)424-9346. According to some recent environmental policy documents a further and faster reduction of the pollution of the surface waters by the industry is necessary. From an analysis of the common practice in licensing, it is indicated that the water authorities should pay much more attention to other fields than just technology in order to take away the barriers for the use of clean preventive measures. Nine points are indicated that are necessary to improve the use of preventive measures. Implementation of this preventive approach should result in a new preventive pollution reduction policy. Page 15 ------- MWPP Bibliography- October 1,1991 VIII. MISCELLANEOUS I * Bonazountas, M. and Mathias, S., "Sedim: A Stream Sedimentation and POTW. Model," Computer Techniques In Environmental Studies. (September 1988, pp. 109-129). Reprints are available through Arthur D. Little, Inc. at (617) 864-5770. Transport of sediment is an important aspect of simulating aquatic pollutant fate because toxic chemicals may attach to sediment particles. A computerized model, sedim/POTW, was developed for estimating the sedimentation dynamics of streams and effluent characteristics. The model is based upon scientific information available for sediment behavior on movable stream beds and on information available on particle distribution behavior of publicly owned wastewater treatment works and other treatment facilities. An application and model validation is presented for the Missouri River at Omaha, Nebraska. * Brown, Lisa M., "Chrome Recovery via Absorptive Filtration," The Environmental Challenge of the 1990's: Proceedings. International Conference on Pollution Prevention: Clean Technologies and Clean Products, dune 10-13. 1990. (September 1990, EPA/600/9-90/039, pp. 100-110). Reprints are available through the RCRA/Superfund Hotline at (800) 424-9346. The University of Washington, under a thirty-one month cooperative agreement with the EPA, is evaluating the performance of packed beds of granular media coated with iron oxide and other adsorbents for recovering chromate from industrial waste solutions. The initial tests are being conducted using synthetic wastes. Following the completion of these tests, tests will be conducted using batches of real waste. A small recovery unit will be installed on-site at an industry near the University at the culmination 'of the project for pilot-scale evaluation. * Dyer, Jon C., Handbook of Industrial Residues. Volume 1: Industries and Management Options. (1983). Reprints are available through Noyes Publications at (201) 391-8484. Prepared to help publicly owned treatment works (POTWs) and their industrial users solve waste management problems, this book provides current information on residual waste management options and requirements, data on categorical industries regulated by federal pretreatment standards, and pretreatment and sludge management technologies. Contents include information on management options available for dealing with residuals, a process approach to total waste management, and several scenarios that depict options available to small, medium, and large POTWs. Furthermore, the book describes possible pretreatment and sludge residual treatment and management technologies applicable to the categorical industries. Available through interlibrary loan. Page 76 ------- MWPP Bibliography - October 1, 1991 Freeman, Harry, "Hazardous Waste Minimization, A Strategy for Environmental Improvement," JAPCA. (January 1988, Vol. 38, No. 1, pp. 59-62). Reprints are available through the Air and Waste Management Association at (412) 232-3444. Many public and private organizations in the United States are supporting waste minimization as an approach to reducing waste generation; In this article, the author provides an overview of waste minimization and introduces a new series of articles on waste minimization in various U.S. , industries to be published in JAPCA this year. : Handbook: Improving POTW Performance Using the Composite Correction Program Approach. EPA, Center for Environmental Research Information, Cincinnati, OH, (October 1984). Reprints are available through the Center for Environmental Research Information at (513) 569-7562. The Handbook provides information on methods to economically improve the performance of existing publicly owned treatment works (POTWs). It is "how-to" oriented and describes an approach that POTWs can use to achieve improvements in treatment without review and analysis of a POTW's design capabilities and associated administration, operation, and maintenance practices. It provides information for POTW administrators to make decisions regarding efforts necessary to improve performance. The primary objective is to determine if significant improvements in treatment can be achieved without making major capita! expenditures. Focus is on POTWs treating typical municipal wastewater compatible with common biological wastewater treatment processes. Heckman, Richard A.,"A look at Biodegradation of Hazardous Wastes, Sludges, arid Wastewaters," Pollution Prevention Review. (Spring 1991, pp. 205-208). Reprints are available through Nationwide Technologies, Inc. at (415) 547-2309. This paper looks at biological processes to detoxify hazardous wastes, sludges, and wastewaters. It also discusses the possibility of combining both chemical and biological treatments of these wastes. " * Hegg, Bob A., et al., "Achieving Wastewater Compliance with Reduced Grant Support,' Journal of the Water Pollution Control Federation. (September 1984, Vol. 56, No. 9, pp. 1007- 1013). Reprints are available through the Water Pollution Control Federation Library at (703) 684-2402. -,: >.' The applicability of a plant-specific approach for improving a publicly owned treatment works' (POTWs) performance and compliance was completed through a study funded by a U.S. Environmental Protection Agency (EPA) grant in Colorado. The study, conducted from September 1980 through December 1982, also researched the motivational forces that prompt POTW administrators to implement activities to improve performance at their plant. This paper summaries the results of the project. In addition, the paper summarizes the data obtained from 31 state pollution control agencies through personal contact and through an informal information gathering effort conducted by the Water Pollution Control Federation (WPGF) Plant Operations Committee. . * ; --,-,, ; Page17 ------- MWPP Bibliography - October 1,1991 * Komegay, Randall A., "North Carolina Plant Solves Textile-Wastewater Problems," Water Environment and Technology. (October 1990, p. 26). Reprints are available through the East Burlington Wastewater Treatment Plant at (919) 578-0515. The East Burlington (N.C.) wastewater treatment plant is a 12-mgd facility that was upgraded 11 years ago to deal with textile-manufacturing wastewaters that comprised up to 60% of the flow. This paper describes a number of operational difficulties in the early 1980s and resolutions to these difficulties. • Michael F. Torpy, Anaerobic Treatment of Industrial Wastewaters. (Noyes Publications, 1988). Reprints are available through Noyes Publications at (201) 391-8484. The latest advances in anaerobic treatment of industrial wastewaters are described in this book. The technology of anaerobic digestion has developed significantly in recent years. It has gained increased credibility from successful application in industry as well as other sectors. Mission Impossible: Introduction to the Pollution Prevention Information Clearinghouse. Available from the Pollution Prevention Information Clearinghouse at (800) 424-9346. Describes in detail the purpose, structure, and activities of the Pollution Prevention Information Clearinghouse. Includes training session on how to access and use the system. . Pifher, Mark T. and Egan, James T., "Biomonrtoring and Toxics Control: The POTW Perspective,1 Natural Resources and Environment. (Spring 1989, pp. 13-49). Reprints are available through the American Bar Association at (312) 988-5555. Water pollution monitoring is shifting away from measuring the levels of specific pollutants in wastewater to the practice of whole effluent toxicity testing, or biomonitoring. This method of testing to assess acute or chronic toxicity of wastewater for certain aquatic test organisms recognizes the synergistic effects of toxics, and the lack of specific toxicity data. The technical and legal basis for this emerging regulatory practice is explored as it applies to publicly owned treatment works (POTWs). The difficulty in establishing negligence by POTWs following a positive toxicity test is discussed. Biomonitoring can be useful to POTWs as part of a workable toxics control program if permit violations and enforcement are based on "diligence of efforts to investigate and eliminate toxicity once detected." * Preston, Lisa A., "A New Horizon for Water Quality in Japan," Water Pollution Control Federation Journal. (May 1989, Vol. 61, No. 5, pp. 579-583). Reprints are available through the Water Pollution Control Federation Library at (703) 684-2402. Today, with its tremendous industrial capacity, superior educational institutions, swift railway systems, relatively nonexistent crime rate, and highly productive workforce, Japan is still striving to improve the quality of its natural environment. This paper describes improvements such as reducing the amount of contaminants that are discharged by wastewater Page 18 ------- MWPP Bibliography _ October 1,1991 treatment facilities and reducing the production of contaminants at the source. The country appears to be accomplishing these goals through rigorous education programs, municipal improvements, and stricter effluent limitations. * Sales, James G., "Wastewater Recycle Facility at IBM East Fishkill," The Environmental Challenge of the 1990's: Proceedings. International Conference on Pollution Prevention: Clean Technologies and Clean Products. June 10-13. 1990. (September 1990, EPA/600/9-90/039, pp. 585-593). Reprints are available through the RCRA/Superfund Hotline at (800) 424-9346. IBM East Fishkill has increased water and wastewater demands significantly. To meet these increased demands, a recycle facility was built to treat relatively dilute inorganic industrial wastewaters and use them as cooling tower feedwater. The Wastewater Recycle Facility integrates two distinct operations. The first is a highly automated, monitored, and controlled 1.2 million gallons per day process, that segregates and treats industrial wastewater for reuse. The second is a polishing process that reduces lime precipitated fluoride and Heavy Metals Treatment Facility effluent fluoride levels via a phosphoric acid addition process. A 90-95% removal efficiency is achieved. This integrated recycle concept has allowed the site to reuse millions of gallons of wastewater with no detrimental effects to the cooling system nor final effluent discharge quality. * Schuk, Walter W. and James, Stephen C.,Treatment of Landfill Leachate at Publicly Owned Treatment Works.' Waste Management and Research. (September 1986, pp. 265-277). Reprints are available through the Academic Press, London at 01-267-4466. One of the requirements of RCRA is the collection of leachates from both municipal and hazardous waste land disposal facilities. Once leachate is collected, treatment is a necessary control technology. One control technology under investigation is the discharge of leachate into a municipal wastewater collection system with subsequent treatment at the municipal treatment plant. In order to develop a more comprehensive understanding of the problems associated with the joint treatment of sanitary landfill leachate and municipal wastewaters, the Wastewater Research Division, Water Engineering Research Laboratory of the United States Environmental Protection Agency (EPA), conducted a pilot-scale study of the process at the U.S. EPA's Test and Evaluation Facility in Cincinnati, Ohio. * Singer, Philip Q., Complying with Trihalomethane Reduction Requirements in Water Treatment Facilities. (Noyes Publications, 1989). Reprints are available through Noyes Publications at (201)391-8484. . This book provides information on complying with trihalomethane (THM) reduction requirements in water treatment facilities, as exemplified in eight specific case studies. Page 19 ------- MWPP Bibliography - October 1, 1991 Thron, Harty M., Jr. and Rogoshewski, Paul J., "Best Management Practices: Useful Tools for Cleaning Up,' Hazardous Materials Spiils Conference. (1982, pp. 487-493). Reprints are available through Government Institutes, Inc. at (301) 251-5609. Best Management Practices or BMPs are expected to be an important part of the Environmental Protection Agency's second round of National Pollutant Discharge Elimination System permits. EPA has worked with industry to identify the generic BMPs that most facilities use for pollution control, fire prevention, occupational safety and health, or product loss prevention. Several general characteristics of BMPs are noted. * Vickers, Amy, 'New Directions in Waste Minimization Technologies: Water Conservation Offers Multi-Faceted Benefits,11 The Environmental Challenge of the 1990's: Proceedings. International Conference on Pollution Prevention: Clean Technologies and Clean Products. June 10-13. 1990. (September 1990, EPA/600/9-90/039, pp. 696-702). Reprints are available through the RCRA/Superfund Hotline at (800) 424-9346. Over the past decade, innovative technologies and advances in water supply management have demonstrated that the science of water conservation has much to contribute to the emerging field of pollution prevention. Numerous case studies show that reductions in water demand significantly reduce energy, natural resource use, waste generation, wear and tear on system infrastructure, and deterioration of water quality. Conservation also benefits both water supply and wastewater systems, such as publicly owned treatment works (POTWs). In addition, the more efficient use of water can help stave off the destructive political conflicts that are often associated with water supply management today. This paper explores the techniques and benefits of water conservation and outlines recommendations to help integrate them into future utility management and pollution prevention programs. * Werschulz, Pat, 'Reduction of Total Toxic Organics in Metal Finishing Wastewater - Alternative Paint Strippers," Toxic and Hazardous Wastes - Proceedings of the 18th Mid Atlantic Industrial Waste Conference. (June 29 - July 1, 1986, pp. 348 - 356). Reprints are available through Technomic Publishing Company at (717) 291-5609. There are several strategies for reducing methylene chloride in discharge streams but the least expensive and simplest is to find a substitute stripper that is more environmentally acceptable. These alternatives would have either no chemicals on the TTO list or have reduced amounts of the TTO's. One study of alternative paint strippers was part of a larger pollution abatement program initiated by the U.S. Army. Page 20 ------- ------- ------- |