vvEPA
United States
Environmental Protection
Agency
Office of Water
Washington, D.C.
EPA 832-F-99-063
September 1999
Wastewater
Technology Fact Sheet
Ozone Disinfection
DESCRIPTION
Disinfection is considered to be the primary
mechanism for the inactivation/destruction of
pathogenic organisms to prevent the spread of
waterborne diseases to downstream users and the
environment. It is important mat wastewater be
adequately treated prior to disinfection in order for
any disinfectant to be effective. Table 1 lists some
common microorganisms found in domestic
wastewater and the diseases associated with them.
Ozone is produced when oxygen (O2) molecules are
dissociated by an energy source into oxygen atoms
and subsequently collide with an oxygen molecule
to form an unstable gas, ozone (O3), which is used
to disinfect wastewater. Most wastewater treatment
plants generate ozone by imposing a high voltage
alternating current (6 to 20 kilovolts) across a
dielectric discharge gap that contains an
oxygen-bearing gas. Ozone is generated onsite
because it is unstable and decomposes to elemental
oxygen in a short amount of time after generation.
Ozone is a very strong oxidant and virucide. The
mechanisms of disinfection using ozone include:
Direct oxidation/destruction of the cell wall
with leakage of cellular constituents outside
of the cell.
Reactions with radical by-products of ozone
decomposition.
Damage to the constituents of the nucleic
acids (purines and pyrimidines).
« Breakage of carbon-nitrogen bonds leading
to depolymerization.
TABLE 1 INFECTIOUS AGENTS
POTENTIALLY PRESENT IN UNTREATED
DOMESTIC WASTEWATER
Organism
Disease Caused
Bacteria
Escherichia coli
(enterotoxigenic)
Leptospira (spp.)
Salmonella typhi
Salmonella (=2,100 serotypes)
Shigetta (4 spp.)
Vibrio cholerae
Protozoa
Balantidiumcoli
Cryptosporidium pan/urn
Entamoeba histolytica
Giardia lamblia
Helminths
Ascaris lumbricoides
T. solium
Trichuris trichiura
Viruses
Enteroviruses (72 types, e.g.,
polio, echo, and coxsackie
viruses)
Hepatitis A virus
Norwaik agent
Rotavirus
Gastroenteritis
Leptospirosis
Typhoid fever
Salmonellosis
Shigellosis (bacillary
dysentery)
Cholera
Balantidiasis
Cryptosporidiosis
Amebiasis (amoebic
dysentery)
Giardiasis
Ascariasjs
Taeniasis
Trichuriasis
Gastroenteritis, heart
anomalies,
meningitis
Infectious hepatitis
Gastroenteritis
Gastroenteritis
Source: Adapted from Crites and Tchobanoglous, 1998.
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When ozone decomposes in water, the free radicals
hydrogen peroxy (HO2) and hydroxyl (OH) that are
formed have great oxidizing capacity and play an
active role in the disinfection process. It is
generally believed that the bacteria are destroyed
because of protoplasmic oxidation resulting in cell
wall disintegration (cell lysis).
!||H
The effectiveness of disinfection depends on the
susceptibility of the target organisms, the contact
time, and the concentration of the ozone. A line
diagram of the ozonation process is shown in
Figure 1. The components of an ozone disinfection
system include feed-gas preparation, ozone
generation, ozone contacting, and ozone
destruction.
Air or pure oxygen is used as the feed-gas source
and is passed to the ozone generator at a set flow
rate. The energy source for production is generated
by electrical discharge in a gas that contains
oxygen. Ozone generators are typically classified
by:
• The control mechanism (either a voltage or
frequency unit).
• The cooling mechanism (either water, air,
or water plus oil).
• The physical arrangement of the dielectrics
(either vertical or horizontal).
• The name of the inventor.
However, generators manufactured by different
companies have unique characteristics but also have
some common configurations.
The electrical discharge method is the most
common energy source used to produce ozone.
Extremely dry air or pure oxygen is exposed to a
controlled, uniform high-voltage discharge at a high
or low frequency. The dew point of the feed gas
must be -60°C (-76 °F) or lower. The gas stream
generated from air will contain about 0.5 to 3.0%
ozone by weight, whereas pure oxygen will form
approximately two to four times that concentration.
After generation, ozone is fed into a down-flow
contact chamber containing the wastewater to be
disinfected. The main purpose of the contactor is to
transfer ozone from the gas bubble into the bulk
liquid while providing sufficient contact time for
disinfection. The commonly used contactor types
diffused bubble (co-current and counter-current) are
positive pressure injection, negative pressure
(Venturi), mechanically agitated, and packed tower.
Because ozone is consumed quickly, it must be
contacted uniformly in a near plug flow contactor.
•4
Recycle
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I
i
Feed Gas Preparation
•Oxygen Production
•Oxygen Storage
•Air/Oxygen Treatment
Ozone Destruction
v-'^UIlc OcilcIculOn
>•
r
Off-Gases
j
v
Ozone Con
Discharge
IdCl U3Sin *
1
Wastewater In
FIGURE 1 OZONE PROCESS SCHEMATIC DIAGRAM
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The off-gases from the contact chamber must be
treated to destroy any remaining ozone before
release into the atmosphere. Therefore, it is
essential to maintain an optimal ozone dosage for
better efficiency. When pure oxygen is used as the
feed-gas, the off-gases from the contact chamber
can be recycled to generate ozone or for reuse in the
aeration tank. The ozone off-gases that are not used
are sent to the ozone destruction unit or are
recycled.
The key process control parameters are dose,
mixing, and contact time. An ozone disinfection
system strives for the maximum solubility of ozone
in wastewater, as disinfection depends on the
transfer of ozone to the wastewater. The amount of
ozone that will dissolve in wastewater at a constant
temperature is a function of the partial pressure of
the gaseous ozone above the water or in the gas
feed stream.
It is critical that all ozone disinfection systems be
pilot tested and calibrated prior to installation to
ensure they meet discharge permit requirements for
their particular sites.
APPLICABILITY
Ozone disinfection is generally used at medium to
large sized plants after at least secondary treatment.
In addition to disinfection, another common use for
ozone in wastewater treatment is odor control.
Ozone disinfection is the least used method in the
U.S. although this technology has been widely
accepted in Europe for decades. Ozone treatment
has the ability to achieve higher levels of
disinfection than either chlorine or UV, however,
the capital costs as well as maintenance
expenditures are not competitive with available
alternatives. Ozone is therefore used only
sparingly, primarily in special cases where
alternatives are not effective.
ADVANTAGES AND DISADVANTAGES
Advantages
The ozonation process utilizes a short contact
time (approximately 10 to 30 minutes).
There are no harmful residuals that need to
be removed after ozonation because ozone
decomposes rapidly.
After ozonation, there is no regrowth of
microorganisms, except for those protected
by the particulates in the wastewater stream.
Ozone is generated onsite, and thus, there
are fewer safety problems associated with
shipping and handling.
Ozonation elevates the dissolved oxygen
(DO) concentration of the effluent. The
increase in DO can eliminate the need for
reaeration and also raise the level of DO in
the receiving stream.
Disadvantages
Low dosage may not effectively inactivate
some viruses, spores, and cysts.
Ozonation is a more complex technology
than is chlorine or UV disinfection.
requiring complicated equipment and
efficient contacting systems.
Ozone is very reactive and corrosive, thus
requiring corrosion-resistant material such
as stainless steel.
Ozonation is not economical for wastewater
with high levels of suspended solids (SS).
biochemical oxygen demand (BOD).
chemical oxygen demand, or total organic
carbon.
Ozone is extremely irritating and possibly
toxic, so off-gases from the contactor must
be destroyed to prevent worker exposure.
The cost of treatment can be relatively high
in capital and in power intensiveness.
Ozone is more effective than chlorine in
destroying viruses and bacteria.
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PERFORMANCE
OPERATION AND MAINTENANCE
Belmont and Southport Wastewater
Treatment Plants in Indianapolis, Indiana
In 1985, the City of Indianapolis, Indiana, operated
two-125 million gallons per day (mgd) advanced
wastewater treatment plants at Belmont and
Southport using ozone disinfection. The rated
capacity of the oxygen-fed ozone generators was
6,380 pounds per day, which was used to meet
geometric mean weekly and monthly disinfection
permit limits for fecal coliforms of 400 and 200 per
100 mL, respectively.
Disinfection was required at both Indianapolis
treatment plants from April 1 through October 31,
1985. Equipment performance characteristics were
evaluated during the 1985 disinfection season and
consequently, disinfection performance was
optimized during the 1986 season. The capital cost
of both ozone systems represented about 8% of the
plants' total construction cost. The ozone system's
Operation and Maintenance (O&M) cost
represented about 1.9% and 3.7% of the total plant
O&M costs at the Belmont and Southport plants,
respectively.
In 1989, a disciplined process monitoring and
control program was initiated. Records indicated a
significant effect on process performance due to
changes in wastewater flow, contactor influent fecal
coliform concentration, and ozone demand.
Previously, ozone demand information was
unknown. Several studies were conducted to
enable better control of the ozone disinfection
process. These included the recent installation of a
pilot-scale ozone contactor to allow the plant staff
to measure ozone demand on a daily basis. Also,
tracer tests were conducted to measure contactor
short-circuiting potential. Results demonstrated a
noticeable benefit of adding additional baffles.
Results also indicated operating strategies that
could maximize fecal coliform removal, such as
reducing the number of contactors in service at low
and moderate flow conditions.
Ozone generation uses a significant amount of
electrical power. Thus, constant attention must be
given to the system to ensure that power is
optimized for controlled disinfection performance.
There must be no leaking connections in or
surrounding the ozone generator. The operator
must on a regular basis monitor the appropriate
subunits to ensure that they are not overheated.
Therefore, the operator must check for leaks
routinely, since a very small leak can cause
unacceptable ambient ozone concentrations. The
ozone monitoring equipment must be tested and
calibrated as recommended by the equipment
manufacturer.
Like oxygen, ozone has limited solubility and
decomposes more rapidly in water than in air. This
factor, along with ozone reactivity, requires that the
ozone contactor be well covered and that the ozone
diffuses into the wastewater as effectively as
possible.
Ozone in gaseous form is explosive once it reaches
a concentration of 240 g/m3. Since most ozonation
systems never exceed a gaseous ozone
concentration of 50 to 200 g/m3, this is generally
not a problem. However, ozone in gaseous form
will remain hazardous for a significant amount of
time thus, extreme caution is needed when
operating the ozone gas systems.
It is important that the ozone generator,
distribution, contacting, off-gas, and ozone
destructor inlet piping be purged before opening the
various systems or subsystems. When entering the
ozone contactor, personnel must recognize the
potential for oxygen deficiencies or trapped ozone
gas in spite of best efforts to purge the system. The
operator should be aware of all emergency
operating procedures required if a problem occurs.
All safety equipment should be available for
operators to use in case of an emergency. Key
O&M parameters include:
• Clean feed gas with a dew point of -60 °C
(-76 °F), or lower, must be delivered to the
ozone generator. If the supply gas is moist,
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the rection of the ozone and the
moisture will yield a very corrosive
condensate on the inside of the
ozonator. The output of the
generator could be lowered by the
formation of nitrogen oxides (such
as nitric acid).
• Maintain the required flow of generator
coolant (air, water, or other liquid).
• Lubricate the compressor or blower in
accordance with the manufacturer's
specifications. Ensure that all compressor
sealing gaskets are in good condition.
• Operate the ozone generator within its
design parameters. Regularly inspect and
clean the ozonator, air supply, and dielectric
assemblies, and monitor the temperature of
the ozone generator.
• Monitor the ozone gas-feed and distribution
system to ensure that the necessary volume
conies into sufficient contact with the
wastewater.
• Maintain ambient levels of ozone below the
limits of applicable safety regulations.
COSTS
The cost of ozone disinfection systems is dependent
on the manufacturer, the site, the capacity of the
plant, and the characteristics of the wastewater to be
disinfected. Ozonation costs are generally high in
comparison with other disinfection techniques.
Table 2 shows a typical cost estimate (low to
medium) for ozone disinfection system used to
disinfect one mgd of wastewater. The costs are
based on the wastewater having passed through
both primary and secondary treatment processes of
a properly designed system (the BOD content does
not exceed 30 milligrams per liter [mg/L] and the
SS content is less than 30 mg/L). In general, costs
are largely influenced by site-specific factors, and
thus, the estimates that follow are typical values
and can vary from site to site.
TABLE 2 TYPICAL COST ESTIMATE OF
AN OZONE DISINFECTION
Items
Costs
Capital Costs
Oxygen feed gas and compressor
Contact vessel (500 gpm)
Destruct unit:
Small (around 30 cfm)
Large (around 120)
Non-component costs
Engineering
Contingencies
Annual O&M Costs
Labor
Power
Other (filter replacements,
compressor oil, spare dielecrtic, etc.)
$245,500
$4,000-5,000
$800
$1,000-1,200
$35,000.
$12,000-15,000
30%
$12,000
90 kW
$6,500
gpm = gallons per minute
cfm = cubic feet per minute
Source: Champion Technology, 1998.
Because the concentration of ozone generated from
either air or oxygen is so low, the transfer
efficiency to the liquid phase is a critical economic
consideration. For this reason, the contact
chambers used are usually very deep and covered.
The overall cost of an ozonation system is also
largely determined by the capital and O&M
expenses. The annual operating costs for ozone
disinfection include power consumption, and
supplies, miscellaneous equipment repairs, and
staffing requirements.
Another consideration for the cost is that each
ozonation system is site specific, depending on the
plant's effluent limitations. Chemical suppliers
should be contacted for specific cost information.
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3.
4.
7.
8.
REFERENCES
Crites, R. and G. Tchobanoglous. 1998.
Small and Decentralized Wastewater
Management Systems. The McGraw-Hill
Companies. New York, New York.
Martin, E. J. and E. T. Martin. 1991.
Technologies for Small Water and
Wastewater Systems. Environmental
Engineering Series. VanNostrand Reinhold
(now acquired by John Wiley & Sons, Inc.).
New York, New York. pp. 209-213.
Metcalf & Eddy, Inc. 1991. Wastewater
Engineering: Treatment, Disposal, and
Rquse. 3d ed. The McGraw-Hill
Companies. New York, New York.
Rakness, K. L.; K. M. Corsaro; G. Hale;
and B. D. Blank. 1993. "Wastewater
Disinfection with Ozone: Process Control
and Operating Results." Ozone: Science and
Engineering, vol. 15. no. 6. pp. 497-514.
Rakness, K. L.; R. C. Renner; D. B.
Vomehm; and J. R. Thaxton. 1988.
"Start-Up and Operation of the Indianapolis
Ozone Disinfection Wastewater Systems."
Ozone: Science and Engineering, vol. 10.
no. 3. pp. 215-240.
Rudd, T. and L. M. Hopkinson. December
1989. "Comparison of Disinfection
Techniques for Sewage and Sewage
Effluents." Journal of International Water
and Environmental Management, vol. 3. pp
612-618.
Task Force on Wastewater Disinfection.
1986. Wastewater Disinfection. Manual of
Practice No. FD-10. Water Pollution
Control Federation. Alexandria, Virginia.
U.S. Environmental Protection Agency
(EPA). 1986. Design Manual: Municipal
Wastewater Disinfection. EPA Office of
Research and Development. Cincinnati,
Ohio. EPA/625/1-86/021.
9. Water Environment Federation (WEF).
1996. Operation of Municipal Wastewater
Treatment Plants. Manual of Practice No.
11. 5th ed. vol. 2. WEF. Alexandria,
Virginia.
10. Rasmussen, Karen (Frost & Sullivan).
1998. Pollution Engineering Online.
"Market Forecast: Wastewater Treatment
Equipment Markets." WEFTEC, Orlando,
FL.
ADDITIONAL INFORMATION
Mark Boner, P.E.
WWETCO
1825 2nd Avenue
Columbus, GA 31901
Roy F. Weston Inc.
Peter J. Lau
1515 Market Street, Suite 1515
Philadelphia, PA 19102-1956
The mention of trade names or commercial
products does not constitute endorsement or
recommendation for use by the U.S. Environmental
Protection Agency.
For more information contact:
Municipal Technology Branch
U.S. EPA
Mail Code 4204
401MSt., S.W.
Washington, D.C. 20460
MTB
I
Excellence in compliance through optimal technical
MUNICIPAL TECHNOLOGY
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