&EPA
United States
Environmental Protection
Agency
Environmental Sciences Research
Laboratory
Research Triangle Park NC 27711
EPA-600/2-79-081
May 1979
Research and Development
Ambient Air
Carcinogenic
Vapors
Improved Sampling
and Analytical
Techniques and
Field Studies
-------
RESEARCH REPORTING SERIES
Research reports of the Office of Research and Development, U S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology. Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:
1. Environmental Health Effects Research
2. Environmental Protection Technology
3. Ecological Research
4. Environmental Monitoring
5. Socioeconomic Environmental Studies
6. Scientific and Technical Assessment Reports (STAR) .
7. Interagency Energy-Environment Research and Development
8. "Special" Reports
9. Miscellaneous Reports
This report has been assigned to the ENVIRONMENTAL PROTECTION TECH-
NOLOGY series. This series describes research performed to develop and dem-
onstrate instrumentation, equipment, and methodology to repair or prevent en-
vironmental degradation from point and non-point sources of pollution. This work
provides the new or improved technology required for the control and treatment
of pollution sources to meet environmental quality standards.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.
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EPA-600/2-79-081
May 1979
AMBIENT AIR CARCINOGENIC VAPORS
Improved Sampling and Analytical Techniques
and Field Studies
by
Edo D. Pellizzari and John E. Bunch
Research Triangle Institute
Post Office Box 12194
Research Triangle Park, North Carolina 27709
Contract No. 68-02-2764
Project Officer
Eugene Sawicki
Atmospheric Chemistry and Physics Division
Environmental Sciences Research Laboratory
Research Triangle Park, NC 27711
ENVIRONMENTAL SCIENCES RESEARCH LABORATORY
OFFICE OF RESEARCH AND DEVELOPMENT
U. S. ENVIRONMENTAL PROTECTION AGENCY
RESEARCH TRIANGLE PARK, NC 27711
-------
DISCLAIMER
This report has been reviewed by the Environmental Sciences Research
Laboratory, U. S. Environmental Protection Agency, and approved for publi-
cation. Approval does not signify that the contents necessarily reflect the
views and policies of the U. S. Environmental Protection Agency, nor does
mention of trade names or commercial products constitute endorsement or
recommendation for use.
11
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ABSTRACT
i
Improved techniques for sampling and analyzing volatile organic
compounds in the ambient air were developed and evaluated, Emphasis
placed on techniques for halocarbons and other compounds known or suspected
of being carcinogenic, Areas of investigation included' (fl'l the evaluation
of XAD-2, charcoal and Tenax qc sorbents for tn situ formation of halor
genated organics during the sampling of air co|vEaWng chlortne and olefins;
(b) the development and testing of a cryoheatefmodule for a thermal desorp«
tions inlet-manifold; and (c) the characterization and quantification of
hazardous organic vapors in ambient air collected at several different
geographical areas within the continental United States,
This report was submitted in fulfillment of 68-02-2764 by the Research
Triangle Institute under the sponsorship of the U, S, Environmental
Protection Agency, This report covers the period from September 9, 1977,
to September 8, 1978.
iii
-------
CONTENTS
Abstract.
Figures vi
Tables ix
Acknowledgements xiii
1. Introduction ]_
2. Conclusions 2
3. Recommendations 4
4. Program Objectives 5
5. Studies on In Situ Formation of Halogenated Compounds
on XAD-2, Charcoal and Tenax GC Sorbents 6
6. Design of a Cryoheater Module for the Thermal Desorption
Inlet-Manifold System. 14
7. Sampling and Analysis for Hazardous Vapor-Phase Organics
in Ambient Air 21
References. 54
Appendices
A. Analytical Methods for Volatile Organics and Poly-
chlorinated Biphenyls in Ambient Air 65
B. Organic Vapors Identified in Ambient Air 95
C. Maps Depicting Sampling Sites and Locations Throughout
the Continental U.S 135
D. Vapor-Phase Halogenated Chemicals Identified in the
Ambient Air Throughout the Continental U.S. ... 186
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FIGURES
Number Page
1 Schematic of instrumentation and devices for examining
in situ formation of halogenated hydrocarbons on
solid sorbent surfaces 7
2 Cryoheater module for inlet-manifold 15
3 Heating rates for cryoheater module on inlet-manifold. . . 17
4 Map of Linden, NJ, area depicting sampling sites 24
5 Map of Linden, NJ, area depicting sampling sites 26
6 Map of Buffalo and Niagara Falls, NY 31
7 Map depicting sampling locations 1 to 13 in Niagara
Falls, NY 32
8 Sampling locations and plant identifications for Niagara
Falls, NY 37
9 Sampling locations and plant identifications in Buffalo, NY 38
Al Vapor collection and analytical systems for analysis of
organic vapors in ambient air 67
A2 Sampling head for housing cartridge sampling train .... 75
A3 Profile of ambient air pollutants for Wood River, IL using
high resolution gas chromatography/mass spectrometry/
computer 83
A4 Background profile for Tenax GC cartridge blank 84
A5 Schematic diagram of GC/MS/Computer System 85
A6 Mass fragmentograms of characteristic ions representing
carbon tetrachloride (m/z 117), tetrachloroethylene
(m/z 166) and m-dichlorobenzene (m/z 146) in ambient
air 89
A7 Mass fragmentograms of characteristic ions representing
methylene chloride (m/z 49) and chloroform (m/z 83)
in ambient air 90
VI
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FIGURES
Number Page
Bl GC/MS/COMP profile of volatile organic vapors in ambient
air from L5 102
B2 GC/MS/COMP profile of volatile organic vapors in ambient
air from L2 108
B3 GC/MS/COMP profile of volatile organic vapors in ambient
air from L3 112
B4 GC/MS/COMP profile of volatile organic vapors in ambient
air from LI 116
B5 GC/MS/COMP profile of volatile organic vapors in ambient
air from L12A 120
Cl Map of Continental U. S. depicing EPA regional territories. 136
C2 Map of California 138
C3 Map of Los Angeles, CA, and vicinity 139
C4 Map depicting sampling locations (x) in Los Angeles, CA,
and vicinity 140
C5 Map depicting sampling locations in Los Angeles, CA . . . . 141
C6 Map of "Four Corner" States 143
C7 Texas and Oklahoma maps 144
C8 Perspective map of Houston, TX and vicinity 145
C9 Map of Houston, Texas and vicinity depicting sampling
locations (A-E). 146
CIO Sampling locations at Pasadena, TX site . . 147
Cll Sampling site in Freeport, TX (Dow 'A') 148
C12 Map depicting south/central states 150
C13 Map depicting locations of ambient air sampling network in
Iberville Parish, LA 151
C14 Sampling site and locations in Geismar, LA area 152
C15 Sampling site and locations in Baton Rouge, LA area .... 153
C16 Sampling sites in St. Louis and vicinity 155
C17 Sampling sites in Southern states 157
CIS Sampling sites visited in North Carolina 158
C19 Sampling sites in West Virginia, Virginia and Maryland. . . 160
Vll
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FIGURES
Number Page
C20 Perspective map of the Kanawha Valley in West Virginia. . 161
C21 The Kanawha River Valley, West Virginia 162
C22 Map of area around Nitro, WV, showing sampling locations. 163
C23 Map of area around St. Albans and Institute, WV, showing
sampling locations 164
C24 Map of area around Charleston and South Charleston, WV,
showing sampling locations 165
C25 Map of area around W. Belle, WV, showing sampling loca-
tions 166
C26 Plant map of DuPont in Belle, WV, depicting sampling
locations 167
C27 Front Royal, VA 168
C28 Map of sampling site in East Brooklyn, Baltimore, Maryland 169
C29 Plant map of FMC 170
C30 Sampling sites in New Jersey 172
C31 Sampling sites in Northeast New Jersey 173
C32 Location of E. I. DuPont de Nemours in Deepwater, NJ. . . 174
C33 Sampling locations on E. I. DuPont de Nemours plant site. 175
C34 Map of Chester, Camden, Philadelphia areas along the De-
laware River 176
C35 Sampling locations surrounding Kin-Buc Land-fill, Edison,
NJ 177
C36 General location of American Cyanamid Corp. with respect
to Tremley's Point and Staten Island 178
C37 Map of Linden, NJ 179
C38 Map of Linden, NJ, area depicting sampling sites 180
C39 Map of Linden, NJ, area depicting sampling sites 181
C40 Sampling locations on American Cyanamid Corp. plant site. 182
C41 Sampling sites visited in Northeastern states 183
C42 Map of Buffalo and Niagara Falls, NY, area 184
C43 Map depicting sampling locations 1 to 13 in Niagara Falls,
NY 185
Vlll
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TABLES
Number page
1 Effect of 03, NO, N02 and Molecular Chlorine on In Situ
Reactions with Cyclohexene Using Tenax GC as the
Sampling Sorbent 9
2 Effect of 03, NO, N02 and Molecular Chlorine on In Situ
; Reactions with Olefins Using SKC-107 Charcoal as the
Sampling Sorbent 12
3 Effect of Criteria Pollutants and Molecular Chlorine
on In Situ Reactions with Olefins Using XAD-2 as the
Sampling Sorbent. . 13
4 Trapping Efficiency of Cryoheater Module on Inlet-Manifold 19
5 Trapping Efficiency of Cryoheater Module on Inlet-Manifold 20
6 Listing of Some Chemical/Industrial Firms in the Linden,
NY Area 23
7 Ambient Air Sampling Protocol for Linden, NJ, Area .... 25
8 Sampling Protocol for Vapor-Phase Organics in Air From
Household Basements and School Rooms in Niagara, NY . 28
9 Sampling Protocol for Collection of Vapor-Phase Organics
and Particulate Organic Material on Polyurethane
from Air in Household Basements in Niagara, NY. ... 30
10 Sampling Protocol for Niagara Falls, Buffalo, NY and
Vicinity 35
11 Estimated Levels of Halogenated Hydrocarbons in Ambient Air
Samples from Linden, NJ 39
12 Summary of Volatile Organic Vapors Detected in Air:
Household Basement and School Rooms in Niagara, NY. . 40
13 Organic Chemicals Identified in Air from Household Base-
ment (LI), Niagara, NY, using PUF Technique 44
14 Organic Chemicals Identified in Air from Household Base-
ment (L2), Niagara, NY using PUF Collection Technique 45
IX
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TABLES
N ujnb e r
15 Organic Chemicals Identified in Air from Household Base-
ment (L3) , Niagara, NY using PUF Technique 46
16 Organic Chemicals Identified in Air from Household Base-
ment (L4), Niagara, NY using PUF Collection Technique 47
17 Organic Chemicals Identified in Air from Household Base-
ment (L5), Niagara, NY Using PUF Collection Technique 48
18 Organic Chemicals Identified in Air from Household Base-
ment (L6), Niagara, NY Using PUF Collection Technique 49
19 Ions Selected for the Estimation of Levels of Vapor-
Phase Organics in Ambient Air 50
20 Estimated Levels of Benzene and Halogenated Organic Vapors
in Air of Household Basements and School Room in
Niagara, NY 51
21 Estimated Levels of Halogenated Organics in Air from House-
hold Basements in Niagara, NY 54
22 Estimated Levels of Halogenated Organics in Ambient Air of
Household Basements and School Rooms in Niagara Falls,
NY 57
23 Recoveries of Selected Organic Vapors from Tenax Cartridges
Subjected to Sample Transportation and Storage. ... 58
24 Summary of Volatile Organics Identified in Ambient Air
from Niagara Falls and Buffalo, NY 59
25 Estimated Levels of Selected Halogenated Hydrocarbons for
Niagara Falls, Buffalo, NY, and Vicinity 61
26 Ubiquitous Vapor-Phase Halogenated Organics in Ambient Air 63
Al Overall Theoretical Sensitivity of High Resolution Gas
Chromatography/Mass Spectrometry/Computer Analysis
for Atmospheric Pollutants 68
A2 Tenax GC Breakthrough Volumes for Several Atmospheric
Pollutants 76
A3 Operating Parameters for GLC/MS/COMP System 81
Bl Volatile Organic Vapors in Ambient Air from Linden, NJ
(P4/L5) 96
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TABLES
Number gage
B2 Volatile Organic Vapors in Ambient Air from Staten
Island, NY (P6/L9) 98
B3 Volatile Organic Vapors Identified in Ambient Air From
Staten Island, NY (P6/L8) 100
B4 Volatile Organic Vapors Identified in Air From Household
Basement (L5), Niagara, NY 103
B5 Volatile Organic Vapors Identified in Air from Household
Basement (L6), Niagara, NY 106
B6 Volatile Organic Vapors Identified in Air from Household
Basement (L2), Niagara, NY 109
B7 Volatile Organic Vapors Identified in Air from Household
Basement (L3), Niagara, NY 113
B8 Volatile Organic Vapors Identified in Air from Household
Basement (LI), Niagara, NY 117
B9 Volatile Organic Vapors Identified in Air from Household
Basement (L12A), Niagara, NY 121
BIO Volatile Organic Vapors Identified in Ambient Air From
Linden, NJ (P1/L3) 122
Bll Volatile Organics Identified in Ambient Air from Amherst,
NY (P1/L3) 125
B12 Volatile Organics Identified in Ambient Air from Buffalo,
NY (P2/L10) 127
B13 Volatile Organics Identified in Ambient Air from Niagara
Falls, NY (P1/L2) 129
B14 Volatile Organics Identified in Ambient Air from Niagara
Falls, NY (P3/L5) 131
B15 Volatile Organics Identified in Ambient Air from Amherst,
NY (P4/L12) 133
Dl Vapor-Phase Halogenated Chemicals - EPA Region II 187
D2 Vapor-Phase Halogenated Chemicals - EPA Region III .... 227
D3 Vapor-Phase Halogenated Chemicals - EPA Region IV 263
D4 Vapor-Phase Halogenated Chemicals - EPA Region VI 266
XI
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TABLES
Number Page
D5 Vapor-Phase Halogenated Chemicals - EPA Region VIII. . . . 311
D6 Vapor-Phase Halogenated Chemicals - EPA Region VII .... 316
D7 Vapor-Phase Halogenated Chemicals - EPA Region IX 317
xn
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ACKNOWLEDGMENTS
The valuable assistance of Mr. R. N. Williams in performing the labora-
tory and field experimentation is gratefully appreciated. Ms. N. Castillo
and D. Smith provided their expertise for interpreting mass spectra and the
analysis of samples by high resolution gas-liquid chromatography/mass
spectrometry/ computer in this research program: a sincere thanks for
their support.
The author extends his gratitude to the personnel at the EPA regional
offices and industrial sites for their cooperation. The constant encourage-
ment and constructive criticisms of Dr E. Sawicki and Mr. K. Krost of
NERC, RTF, NC are appreciated.
xiii
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SECTION 1
INTRODUCTION
The presence of halogenated hydrocarbons in the atmosphere is now a
well-documented occurrence (1-6). Prior to the initiation of EPA Contracts
No. 68-02-1228 and 68-02-2262, little effort had been devoted to the charac-
terization of ambient air for the presence of mutagens and carcinogens.
Under these contracts, many halogenated hydrocarbons were identified as
well as other chemicals. Many of these chemicals are believed to be associa-
ted with anthropogenic sources. The actual health impact of the halogenated
compounds in the environment, particularly at the concentrations which have
been measured, is not completely understood.
Characterization in combination with comprehensive studies on the
levels of carcinogenic agents in all media and the correlation of this
exposure to body-burden and health effects on man should be conducted. A
well-defined epidemiological approach to establish whether an associational
relationship exists requires appropriate monitoring technology.
As a continuing effort to characterize the atmosphere for mutagens and
carcinogens, this program addresses the further identification of many
vapor-phase organics in the atmosphere from several industrial sites.
Also, a solid waste disposal site where the chemicals are now being released
into the environment was examined.
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SECTION 2
CONCLUSIONS
A series of laboratory experiments was conducted to determine whether
air containing both NO and ozone plus molecular halogen and olefins might
X
convert olefins to chlorinated hydrocarbons on the surface of collection
media. Studies on the potential in situ formation of halogenated compounds
on XAD-2, charcoal and Tenax GC sorbents utilizing cyclohexene, ethylene,
propylene, 1- and 2-butenes indicated that trace quantities of 1,2-dichloro-
cyclohexane, 2,3-dichlorobutanes (racemic and meso forms) and cyclohexene-
2-one were detected on all three sorbents. The formation of halogenated
compounds from 2-butene and cyclohexene was relatively independent of the
presence of criteria pollutants.
A new cryoheater module was designed, fabricated and tested for the
thermal desorption inlet-manifold system. The cryoheater module exhibits
high trapping efficiency (>95%) for vinyl chloride as well as a series of
hydrocarbons (n-pentane to n-hexadecane) when a purge rate of 10 ml/min is
used with a 0.04 in i.d. x 0.064 in o.d. x 18 in Ni capillary trap. The
heating rate for the cryoheater module on the inlet-manifold was examined.
It required approximately 3 min to heat from -195°C to 250°C. The cryoheater
module was found to be compatible with injection of samples onto a support
coated open tubular (SCOT) column since the mode of cooling and heating the
capillary trap maintained the chromatographic resolution.
Sampling and analysis of ambient air in household basements was conduc-
ted in "Old Love" Canal, Niagara Falls, NY. A total of 42 halogenated
compounds was identified. Most of the halogenated hydrocarbons observed
were specific to this site. Microgram levels for the individual halogenated
compounds were detected.
-------
A compilation of halogenated hydrocarbons which have been identified
in ambient air samples from various geographical regions throughout the
Continental U. S. was prepared. A few of the compounds were considered to
be ubiquitous while the majority were found to be site-specific and associa-
ted with industrial activity in these areas.
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SECTION 3
RECOMMENDATIONS
Three major phases of research should be pursued: (1) studies
should begin on characterizing industrial atmospheres where known chemical
synthesis, usage, or storage of nitrogen- and sulfur-containing compounds
occurs; (2) accuracy and reproducibility studies for the collection and
analysis of nitrogen- and sulfur-containing compounds from the ambient air
should be conducted; and (3) information on nitrogen- and sulfur-containing
compounds in industrial atmospheres for the specific purpose of classifying
the chemicals according to site-specific and ubiquitous compounds should be
acquired.
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SECTION 4
PROGRAM OBJECTIVES
The general aim of this contract was to collect, characterize, and
quantify hazardous vapor-phase organic pollutants at several locations
throughout the Continental U. S. Specifically, the purpose was: (1) to
place emphasis on the analysis for known or suspected mutagens and carcino-
gens and to assess the capability of the analytical method as a function of
pollutant type with particular emphasis on carcinogens and mutagens; (2) to
develop "pollution profiles" indicative of the individual sites sampled
under this and previous programs and to establish a "pollution background
profile" common to all sites studied; and (3) to prepare in graphic or
tabular form all past and present findings on site pollution profiles.
Furthermore the objectives under this program were to conduct further
studies on: (1) the potential in situ formation of halogenated compounds
on XAD-2, charcoal, and Tenax GC sorbents; and (2) the design and perfection
of a cryoheater module for the thermal desorption inlet-manifold system.
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SECTION 5
STUDIES ON IN SITU FORMATION OF HALOGENATED COMPOUNDS ON XAD-2,
CHARCOAL AND TENAX GC SORBENTS
INTRODUCTION
In a previous report we presented the possibility of in situ reactions
occurring on the sorbent Tenax GC between molecular halogens (chlorine and
bromine) and ozone, NO , ethylene, propylene, and 1- and 2-butenes (6). In
these studies traces of 2,3-dichlorobutanes (meso and racemic forms) were
detected as well as polar products. Furthermore, we have examined the
potential formation of N-nitrosodimethylamine when NO , ozone and dimethyl-
A
amine are sampled together using the Tenax GC sampling cartridge (4).
Traces of N-nitrosodimethylamine were also detected.
Further studies have been conducted to determine whether chlorination
of olefins would occur on XAD-2 and charcoal. The results of this study
are presented in this section.
EXPERIMENTAL
The apparatus used to determine whether air containing ozone, nitric
oxide (Matheson, Coleman, Bell), cyclohexene, and water might convert
olefins to a chlorinated cyclohexane on Tenax GC (35/60 Applied Science,
State College, PA) in the presence of molecular chlorine is depicted in
Figure 1. Nitric oxide was measured into the stream with a rotometer and
a metering valve from a supply tank which contained 48.9 ppm of NO in
nitrogen (Scott Environmental). Ozone was generated by an ultraviolet lamp
equipped with a sliding cover for obtaining different concentrations.
Concentrations of NO, N00, NO and ozone were monitored with a Bendix NO
£* X X
analyzer (Model 5513802) and a Bendix Ozone analyzer. Gas phase titration
was employed to calibrate these instruments. Intakes for these instruments
were at the same point as the intake for the Tenax GC glass cartridge
sampler (1.5 cm i.d. x 6.0 cm length) through which air was drawn by a
-------
SCRUBBER
TRAIN
AIR
SUPPLY
TEFLON MEMBRANE
FILTER
HO-NOj-NO,
ANALVZER
OZONE
MONITOR
Figure 1.
NITRIC
OXIDE
INLET
/CONNECTOR
CLASS REACTION TUBE
(3.5 Cm i.d. x 2.2 ml
ETHVLENE
IN
\^
Schematic of instrumentation and devices for examining in situ formation of
halogenated hydrocarbons on solid sorbent surfaces.
-------
Nutech Model 221A (Nutech Corporation, Durham, NC) sampler. The sampling
cartridge and analyzer inlet tube were centered in the air flow of the
reaction tube (Fig. 1).
Prior to its use Tenax was purified by Soxhlet extraction as previously
described and thermally conditioned (6).
Replicate samples (duplicate) and blanks were analyzed by gas-liquid
chromatography (glc) using a glass SCOT capillary coated with OV-101 statio-
nary phase and flame ionization detection. After sampling, the cartridges
were thermally desorbed as previously described and the sample introduced
into the gas chromatographic column. The SCOT column was programmed from
30° to 240°C at 4°C/min. The carrier flow was approximately 2.5 ml/min.
and the hydrogen and air were 35 and 200 ml/min., respectively. A Varian
model 3700 glc was used.
The effect of ozone on tetrachloroethylene during sampling with charcoal
(SKC) tubes containing 150 mg of sorbent was examined. Tetrachloroethylene
(194 ng) was loaded on charcoal sampling cartridges and known levels of
ozone, NO, and N0? in ambient air were sampled through the charcoal tube.
A mixture of methanol and carbon disulfide was used to desorb the tetrachloro-
ethylene for subsequent analysis. Glc with electron capture detection and
a column (Pyrex, 2.5 mm i.d. x 1.8 m) of 0.2% Carbowax 1500 on Carbopack C
was used. A Fisher Victoreen model 4400 glc equipped with a high temperature
3
Sc electron capture detector was used.
The potential chlorination of cyclohexene in the absence and presence
of ozone and other standard pollutants was also studied using a sampling
cartridge containing XAD-2 sorbent.
RESULTS AND DISCUSSION
Table 1 presents the series of experiments which was conducted utili-
zing different combinations of ozone, NO , NO, N09, chlorine, and cyclohexene.
A £•
The volume of air stream that was sampled in all cases was 16 liters. In
experiments No. 1-6 the Tenax GC cartridges were loaded with the olefin
equivalent to a level of 90 ppb. In all of these experiments where the
cyclohexene had been loaded on the Tenax GC cartridge no formation of 1,2-
dichlorocyclohexane or other artifact was detected (Table 1). Experiments
No. 8-16 utilized a cyclohexene permeation tube plus a molecular chlorine
-------
Tab lei . EFFECT OF 03, NO, N02 AND MOLECULAR CHLORINE ON IN SITU REACTIONS WITH
CYCLOHEXENE
USING TENAX GC AS THE SAMPLING SORBENT
Standard Inorganic
Pollutants (added)
Experiment
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
ppb 03
0
100
100
700
0
220
0
0
0
160
0
180
0
140
100
0
0
100
ppb NO
0
0
0
0
300
0
0
0
0
0
0
0
0
0
0
100
0
0
ppb NO
0
0
0
0
350
200
0
0
0
0
0
0
0
0
100
0
0
0
Cl2
2 ppb
104
0
104
104
104
104
104
0
104
104
0
104
104
104
104
104
104
0
Cyclohexene
ppb
90
90
90
90
90
90
0
818
818
818
0
818
818
818
818
818
818
818
(continued)
1, 2-Dichlorocyclohexane
ng
0
0
0
0
0
0
0
0
100
110
0
120
110
120
100
100
110
0
Other "Artifacts"
_
_
_
_
_
_
_
_
cyclohexene-2-one
_
cyclohexene-2-one
_
eye lohexene- 2 -one
cyclohexene-2-one
—
_
cyclohexene-2-one
-------
Table 1 (cont'd)
Standard Inorganic
Pollutants (added)
Experiment C12 Cyclohexene 1,2-Dichlorocyclohexane
No. ppb 63 ppb NO ppb NC>2 ppb ppb ng
Other "Artifacts"
19
20
720
720
0
0
0
0
0
104
818
818
0
120
cyclohexene-2-one
cyclohexene-2-one
Expts. No. 1-6 utilized Tenax GC cartridges loaded with cvclohexene and nursed with Cl?, Expts.
No. 8-16 utilized a cyclohexene permeation tube in line with a Cl2 permeation tube, and Expts.
No. 17-20 involved loading of cyclohexene onto the Tenax or. cartridge and sampling in the pre-
sence of criteria pollutants as indicated with C12. Sampling volumes were 16 H in all cases.
-------
permeation tube which were housed in the permeation tube chamber (point A,
Fig. 1). Thus, the molecular chlorine plus cyclohexene entered and travelled
together down the glass reaction tube to the Tenax GC cartridge at E (Fig.
1). In these experiments the quantity of cyclohexene was almost an order
of magnitude greater than in the previous experiments.
In experiments 8-16 approximately 100-120 nanograms of 1,2-dichloro-
cyclohexane was measured when molecular chlorine was present with cyclohexene
regardless of whether ozone, NO, or N0» was added.
A replicate cartridge representing the conditions under which 1,2-di-
chlorocyclohexane was expected to form was submitted for mass spectral
analysis. The mass spectral data confirmed the presence of 1,2-dichlorocyclo-
hexane. In addition, another compound was identified as cyclohexene-2-one.
The formation of this compound, however, occurred only when ozone was also
added to the air stream (Table 1).
Additional experiments were performed (Nos. 17-20) which involved the
loading of cyclohexene onto the Tenax GC cartridge at a considerably higher
concentration as indicated in Table 1. Again, 1,2-dichlorocyclohexene and
cyclohexene-2-one were detected.
These experiments indicate that 1,2-dichlorocyclohexene as well as
cyclohexene-2-one could be formed, particularly when higher concentrations
of cyclohexene are used. This also probably accounts for the observations
in the first series of experiments where formation of 1,2-dichlorocylcohexene
and cyclohexene-2-one may have been below the detection limit for the flame
ionization detection.
Traces of 2,3-dichlorobutane were found when charcoal (Table 2) or
XAD-2 (Table 3) was used as the sampling sorbents.
Sampling of atmospheres containing 1 ppm ozone, 1 ppm NO or 1 ppm N0?
with a charcoal tube containing tetrachloroethylene did not deplete the
levels of tetrachloroethylene.
11
-------
WITH OLEFINS USING SKC-107 CHARCOAL AS THE SAMPLING SORBENT
Standard Inorganic
Pollutants
Experiment
No.
1
2
3
4
5
ppm 0_
0
1
0
1
0
ppm NO
0
0
1
0
0
ppm NO-
0
0
0
1
0
C12 Olefin Mixture3
ppb (ppb)
90 B(744), P(577), E(581), B2(940)
90
90
90
0
2 , 3-dichlorobutane
ng (formed)
60
20
20
20
0 '"
a01efin mixture: B = 1-butene, P = propylene, E = ethylene, B2 = butene-2. In each case 16 H was
sampled.
-------
Table 3. EFFECT OF CRITERIA POLLUTANTS AND MOLECULAR CHLORINE ON IN SITU REACTIONS
u>
WITH OLEFINS USING XAD-2 AS THE SAMPLING SORBENT
Standard Inorganic
Pollutants
Experiment
No. ppm 0,.
1 0
2 1
3 1
4 0
5 0
C12 Olefin Mixture"
ppm NO ppm N02 ppb (ppb)
0 0 90 B(744), P(577), E(581), B2(940)
0 0 90 " " " "
0 1 90 " " " "
1 0 90 " " " "
0 0 90 " " " "
2 , 3-dichlorobutane
ng (formed)
30
20
20
20
0
See Table 2.
-------
SECTION 6
DESIGN OF A CRYOHEATER MODULE FOR THE THERMAL DESORPTION
INLET-MANIFOLD SYSTEM
INTRODUCTION
In previous reports a thermal desorption manifold was described and
its performance presented (1-5). Additional research included examining
coaxial and transaxial configurations of the capillary trap on the thermal
desorption inlet-manifold (4). As part of the overall objective of this
program on the improvement of methodologies for the collection and analysis
of carcinogenic vapors further work was conducted on the perfection of the
inlet-manifold system. Specifically a cryoheater module for the inlet-
manifold was designed fabricated, and tested.
EXPERIMENTAL
The cryoheater module for the trapping of desorbed vapors from sorbent
cartridges is depicted in Figure 2. Specifications were delineated to
insure that specific performance criteria could be achieved. These were:
a) a high trapping efficiency for all chemical classes of interest; b) the
ability to quantitatively transfer vapors from the trap to a high resolution
chromatographic column; c) injection of vapors without loss of chromatograp-
hic resolution; d) minimal decomposition or artifact formation during
trapping and injection; and e) a simple and inexpensive device which could
easily be fabricated.
The cryoheater module consists of an aluminum cylinder which is machined
from a 2.54 cm o.d. aluminum bar. The internal diameter of the cylinder is
bored to 0.957 cm to receive a Hot Watt heating cartridge (100 watts, 3.81
cm in length, 150 volts, model HS3715NR). The tolerance is 0.005 cm which
is necessary to distribute the heat evenly throughout the cylinder. On the
outside of the aluminum cylinder a threaded groove is machined to receive a
0.10 cm i.d. x 0.15 cm o.d. x 1 m nickel capillary trap. A groove is
14
-------
0.04 in. id x 0.062 in.od x 36 in.
Ni capillary
Thermocouple
1/16 in. Swagelok union
1.6cm
I t
A B
4.5cm
Figure 2. Cryoheater module for inlet-manifold
15
-------
milled the length of the aluminum cylinder in order to accommodate one leg
of the capillary trap. An aluminum cup is fabricated as depicted in Figure
2. A 1/16" Swagelok union was affixed to the bottom to feed liquid nitrogen
into the cup.
During the cooling cycle nitrogen gas from a bottle is liquefied and
delivered to the aluminum cup. Cooling to -196°C is achieved in approxima-
tely 180 sec. The desorption of vapors from sorbent cartridges is then
initiated. After thermal desorption is complete (approximately 5 min.) the
liquid nitrogen feed is terminated and the power to the Hot Watt cartridge
is initiated (150 volts). A thermocouple (iron-constantan) is used to
monitor the heating and cooling cycles.
A Varian 3700 gas liquid chromatograph equipped with a thermal desorp-
tion inlet-manifold system was used to evaluate the cryoheater module. The
trapping efficiency of the cryoheater on the inlet manifold was assessed by
loading a series of hydrocarbons and halogenated hydrocarbons onto the
Tenax GC cartridge followed by thermal desorption with helium purging. A
backup Tenax GC cartridge on the exhaust of the thermal desorption chamber
was used to determine the trapping efficiency of the cryoheater module by
subsequent analysis of the backup Tenax GC cartridge. Gas chromatography
was conducted on a 100 meter glass SCOT capillary coated with OV-101 program-
med from 30°C to 240°C at 4°C/min. The carrier flow was approximately 2.5
ml/min. and the hydrogen and air flows were 35 and 225 ml/min, respectively.
RESULTS AND DISCUSSION
Figure 3 depicts the heating rates for the cryoheater module. Heating
from -196°C to +275°C was achieved in approximately 155 sec. when 100 volts
was applied to the heating cartridge (Fig. 3, profile 1). At 115 volts the
heating time was 125 seconds (Fig 3, profile 2). A differential heating
rate was observed between the capillary trap in the aluminum cup and the
capillary near the top of the cryoheater module (Fig. 3, profiles 2 and 3).
After the heating cycle had been initiated for 40 seconds, the difference
in temperature at these two points was approximately 100°C. During the
cooling cycle a similar temperature differential was observed. Thus, the
desired specifications were achieved, i..e. , a gradient from one end of the
capillary trap to the other. This differential heating rate between the
16
-------
0)
M
u
cfl
M
(U
P.
-100-
-150.
-200
thermocouple in cup (100V)
thermocouple in cup (115V)
thermocouple on top strand (115V)
0 10 20 30 40 50 60 70 80 90 100 110 120 1JO 1^0 150 l'60 IT'O
Time Sec
Figure3 . Heating rates for cryoheater module on inlet-manifold.
-------
two ends of the capillary trap is considered a feature of the system.
Under normal operating conditions the desorbed vapors from the sorbent
cartridge enter point A of the capillary trap which is at an elevated
temperature. As the vapors gradually pass through the trap the temperature
decreases until it reaches -196°C before exiting through point B. During
the heating cycle the carrier gas (helium) for the capillary column enters
point A and carries the vapors toward the cooler end of the trap which
sharpens the band prior to its injection onto the chromatographic column.
This feature is important; otherwise, the entire capillary trap would
constitute dead volume during injection which ultimately would be expressed
as broad peaks and low resolution.
The trapping efficiency of the cryoheater module for several compounds
is given in Table 4. A series of hydrocarbons was examined to determine
the percent retained by the cryoheater module using different purge rates
from the thermal desorption chamber. A 45.7 cm nickel capillary trap was
used in this study. A purge rate of 25 ml/min yielded high efficiencies
for all listed hydrocarbons. Low trap efficiency was observed for vinyl
chloride (boiling point -13°C) at a flow rate of 40 ml/min.
Further studies were performed with purge rates and the orientation of
the gas flow through the capillary trap. The results of this study are
shown in Table 5. These data indicate that in order to obtain a high
trapping efficiency it is extremely important that the purge gas carrying
the desorbed vapors enter at point A on the cryoheater module (Fig. 2).
These data show that a gradual cooling of the gas is necessary to minimize
aerosol formation in order to achieve high trapping efficiencies. Comparison
of these data with those previously obtained in Table 2 indicate that the
use of an approximately 45.7 cm nickel capillary trap with half of it wound
in the liquid nitrogen cooled portion (cup) and the remainder separated by
3 turns and wound in the upper portion of the module is necessary to achieve
a temperature gradient. The maximum trapping efficiency of the cryoheater
module was observed utilizing a 0.04" i.d. x 0.064" o.d. x 18" length
nickel capillary trap with a 10 to 15 ml per minute purge rate from the
thermal desorption chamber for a period of 10 minutes.
18
-------
Table 4, TRAPPING EFFICIENCY OF CRYOHEATER MODULE
ON INLET MANIFOLD3
% Retained
Chemical Class Compound PR**
Hydrocarbons
Halogenated
Hydrocarbons
a0.04 in i.d.
time = 4 min
V
n-pentane
n-hexane
n-heptane
n-octane
ri-nonane
ri-decane
n-undecane
ri-dodecane
n-tridecane
n-tetradecane
ii-pentadecane
n-hexadecane
vinyl chloride
vinyl bromide
chloroform
1, 2-dibromome thane
chlorobenzene
x 0.064 in o.d. x 18 in Ni
(from RT). Heating time »
- 40 ml/min PR
59
68
79
88
93
94
95
99+
99+
99+
99+
99+
77
-
-
-
capillary trap.
2.3 min (-196°C -»
= 25 ml/min
88
91
97
99
99+
99+
99+
99+
99+
99+
99+
99+
93
97
99
99
99+
Cooling
• 300°C).
PR = purge rate (He) from thermal desorption chamber.
19
-------
Table 5. TRAPPING EFFICIENCY OF CRYQHEATER MODULE ON
INLET MANIFOLD3
Compound
n-pentane
n-hexane
n-heptane
n-octane
n-nonane
n-decane
PRb = 20 ml/min
(5 min)
88+3
96 + 2
99 + 1
99.5 + 0.5
99.5 + 0.5
99.5 + 0.5
% Retained
PRb = 10 ml/min
(10 min)
98
99
99
99
99
99
PR° =20 ml/min
(5 min)
67 + 17
74 + 3
89 + 3
97 + 4
96 + 2
98 + 1
0.04 in i.d. x 0.064 in o.d. x 40 in Ni capillary trap.
Purge gas (He) entered point A, see Fig. 2.
°Purge gas (He) was directed through point B, see Fig. 2.
20
-------
SECTION 7
SAMPLING AND ANALYSIS FOR HAZARDOUS VAPOR-PHASE ORGANICS
IN AMBIENT AIR
INTRODUCTION
Study sites were selected on the basis of the types of industrial
activity. This is important in our pursuit of validation of the collection
and analysis method which has been developed under this program. It is
important to have background information on potential emissions in order to
assess the collection and analysis capability of the method. By applying
the method to a variety of ambient atmospheres associated with anthropogenic
sources it has been our objective to characterize many different types of
atmospheres, and to demonstrate the qualitative and quantitative capabilities
of the Tenax GC sampling cartridge when used in combination with glass
capillary/gas chromatography/mass spectrometry/computer methods (GC/MS/COMP).
As part of the overall endeavor, sampling and analysis was conducted in
Linden, NJ near chemical and industrial sites, at the "Old Love" Canal site
in Niagara Falls, NY, which constituted a disposal site for several chemical
companies, and in Niagara Falls and Buffalo, NY at-large.
Love Canal is an old landfill used by several chemical companies back
in the 1920's to dump chemical residues. Subsequently the area was covered
and suburban homes constructed. In recent years due to corrosion of the
drums the chemicals came to the surface and thp residues have been leaching
into the basements of homes. Local problems have been reported which include
the presence of strong odors in the basements. There was also congressional
interest from the 36th district.
The New York State Department of Environmental Conservation (NYDEC) has
had the lead role in investigating and correcting the problem at the "Old
Love" Canal site. Inadequate information was available to identify the
contaminants present in the migrating material resulting in air and water
21
-------
pollution. The NYDEC has sampled to gather information to support state
regulatory action. The EPA region II was concerned with the potential
health implications particulately those associated with air contaminates in
the enclosed basements.
Because of these problems, technical assistance was provided by schedul-
ing a monitoring project in the "Old Love" Canal area of Niagara Falls, New
York.
EXPERIMENTAL
The collection and analysis techniques used for vapor-phase organics in
ambient air are described in Appendix A. These methods were used throughout
this program.
As part of a scouting expedition in Linden, New Jersey, the solicitation
of aerial photography service in Camden, New Jersey was performed. The use
of aerial photography has several advantages, one of which is the ability to
provide an overall perspective of the industrial layout and the potential
sampling sites. By examination of aerial photographs, e.g., color prints
and infrared slides, potential problems, if any, could be enumerated prior
to sampling in the area. City maps were also obtained from the city planning
department in Linden, New Jersey. Property maps were consulted to identify
plant boundaries. The major boundaries found in the Linden area are listed
in Table 6. The locations of these industries are depicted in Figure 4.
Those of interest were Exxon, E.I. Dupont de Nemours, GAF, Linden Chlorine,
American Cyanamid and FMC. During scouting for potential sampling locations
strong chlorine odors were detected at the intersection of Grasselli Road
and Tremly Point Road. Accessibility of the industrial complex ranges from
one mile just southwest of the Goethals Bridge to 200 yards directly east of
Tremly Point. The Rose Hill Cemetery was considered as a sampling site
since it was located within a half mile of the large petroleum complex.
Table 7 and Figure 5 give the sampling protocol and the locations of
sampling. Weather data were obtained from the Newark International Airport.
Additional weather data were recorded at the sites using hand-held instrumen-
tation as well as a Meteorological Research Incorporated weather station.
During the first two days of the sampling trip sampling was postponed due to
8-1/4" of rain and excessive flooding of the area of interest.
22
-------
Table 6. LISTING OF SOME CHEMICAL/INDUSTRIAL FIRMS IN THE LINDEN, NJ AREA
1. FMC - industrial chemicals, phosphates, MSP.
2. GATX - tank storage and transfer.
3. American Cyanamid - sulfuric acid, pesticides.
4. Cities Service - natural gas.
5. Tremely Point Industries - tank storage.
6. BP Oil Company - tank storage.
7. Linden Chlorine - Cl~ and caustic soda
8. Linden Terminal Corporation - tank farm.
9. GAF - dyes, aniline
10. E. I. DuPont de Nemours, Inc. (Grasselli unit) - agricultural
chemicals, ammonia, sulfuric acid.
11. Generating Station
12. Reichold Chemical - synthetic resins, maleic anhydride, acrylates.
13. Public Service Corp. - tank farm.
14. Mobil Oil Corp. - tank farm.
15. Gulf Oil Corp. - tank farm.
16. Texas Corp. - tank farm.
17. Merck Company - pharmaceutical, industrial chemicals, methanol,
benzene.
18. Exxon - refinery and chemicals plus tank farm.
23
-------
Figure 4. Map of Linden, NJ, area depicting sampling sites.
24
-------
Table 7. AMBIENT AIR SAMPLING PROTOCOL FOR LINDEN, NJ, AREA
Ui
Sampling Time Volume Sampled
Site Sampling Period/Location (min) (£) Remarks
Linden, NJ PI/LI
P1/L3
P1/L2
P2/L4
P4/L4
P4/L5
P4/L6
P5/L7
P6/L8
P6/L9
60 46 11/9/77
58% RH
70 75 11/9/77
80% RH
60 59 11/9/77
81% RH
120 80 11/9/77
59% RH
60 95 11/10/77
95% RH
60 66 11/10/77
95% RH
60 67 11/10/77
95% RH
60 78 11/10/77
94% RH
75 111 11/11/77
34% RH
62 39 11/11/77
34% RH
60°F
210°/6 kts
65°F
210°/6 kts
65°F
210°/6 kts
62°F
210°/6 kts
60°F
120°/6 kts
60°F
120°/6 kts
59°F
140°/6 kts
62°F
130°/5 kts
44°F
240°/14 kts
45°F
240°/14 kts
-------
KJ
Figure 5. Map of Linden, NJ, area depicting sampling site.
Q = industry. See Table 6 for listings.
0 = sampling locations,
-------
Samples were taken around the Exxon Chemical Complex (LI, L2, L3) and
at this time the winds were light and variable with plumes from the predomi-
nant stacks traveling southeast. Both upwind and downwind samples were in
good locations with respect to odors emanating from the area. Turnpike
traffic was heavy with considerable diesel exhaust odors at L3 (Fig. 5).
Other odors were detected at L2.
An afternoon sample was taken off West Brook Drive in the Rose Hill
Cemetery (L4). Winds were predominantly southwest at 6 kts/hr. This sample
served as a good background profile of the area minus the industrial pollution.
A sample was also taken outside the gate entrance to Linden Chlorine. A
security guard was consulted to determine whether the samples would be on
plant property at the site chosen.
On Thursday winds were out of the southeast at 6 kts/hr. Sampling was
conducted at the Rose Hill Cemetery (L4), just off Tremly Point Road (L5),
and off Gulf Road on Staten Island (L6). The Staten Island samples were to
represent the upwind sample; however, flooded highways prevented access to
the desired area. This sample represents a background sample of Staten
Island. Thursday evening a distant downwind sample from Tremly Point
Industries was acquired in Linden (L7). Light rains occurred throughout the
sampling period.
On Friday, winds were predominantly from the southwest at 14 kts/hr.
Samplers were placed in downwind locations on Staten Island (Fig. 5, L8, L9)
at a distance of approximately 1.5 miles from the industrial complex.
Ammonia odors were detected during the sampling period as evidence that
pollution from the vicinity of Dupont was carrying across the distance.
Because it was uncertain exactly what chemicals were dumped in "Old
Love" Canal back in the 1920's, the sampling and analysis approach adopted
was to sample for a large spectrum of chemicals that might be in the ambient
air. For this reason, two sampling and analysis techniques were chosen:
(1) for vapor-phase organics; and (2) for vapor-phase plus particulate
organic matter. The sampling protocols and locations are given in Tables 8
and 9, and Figures 6 and 7, respectively.
Ambient air samples were taken between Tuesday, February 7, and Thursday,
February 9th, in eleven homes and one elementary school along the "Old Love"
27
-------
Table 8. SAMPLING PROTOCOL FOR VAPOR-PHASE ORGANICS IN AIR FROM
HOUSEHOLD BASEMENTS AND SCHOOL ROOMS IN NIAGARA, NY
N)
oo
Remarks
Sampling Location
1
2
3
4
5
6
7
8
9
10
11
Sampling Time
(min)
198
135
235
207
562
212
186
192
151
200
154
Sampling Volume
(£)
268
95
258
300
597
140
134
283
219
263
226
(continued)
Date
Relative Humidity
2/9/78
52% RH
. 2/7/78
49% RH
2/7/78
66% RH
2/7/78
68% RH
2/8/78
50% RH
2/8/78
44% RH
2/9/78
49% RH
2/7/78
61% RH
2/9/78
37% RH
2/8/78
48% RH
2/8/78
31% RH
' Time
Temp. (°C)
1051-1409
15°
1035-1250
22°
1055-1450
18°
1130-1457
16°
1013-1935
17°
0923-1255
19°
0910-1216
13°
1155-1507
18°
0950-1221
17°
0945-1305
22°
1038-1312
18°
Odors
6/6
10/9.5
9.5/10
6/6
8/8
6/7
1/1
1/1
1/1
1/2
1/1
-------
Table 8 (cont'd)
N3
VO
Remarks
Sampling Location
12A
12B .
13A
13B
13C
Sampling Time
(min)
480
520
490
490
536
Sampling Volume
W
43
47
44
66
72
Date
Relative Humidity
2/8/78
22% RH
, 2/8/78
25% RH
Time
Temp. (°C) Odors
0855-1655 ,
0845-1725 '
21°
0830-1460
0832-1642 1/1
23°
Each household basement was designated as a sampling location.
Using a scale of 1-10, subjective evaluations were made for presence of chlorinated and general
odors in basements.
-------
Table 9. SAMPLING PROTOCOL FOR COLLECTION OF VAPOR-PHASE ORGANICS
AND PARTICULATE ORGANIC MATERIAL ON POLYURETHANE FROM
AIR IN HOUSEHOLD BASEMENTS IN NIAGARA, NY
Remarks
Sampling Location
1
2
3
4
5
6
7
8
9
10
11
Sampling Time
(min)
497
558
514
513
• 562
600
580
500
566
643
553
Sampling Volume
W •
94,049
116,067
100,369
100,173
109,742
124,803
120,643
94,097
110,523
125,559
104,072
Date
2/9/78
2/7/78
2/7/78
2/7/78
2/8/78
2/8/78
2/9/78
2/7/78
2/9/78
2/8/78
2/8/78
Time
1051-1908
1025-1943
1056-1930
1130-2003
1013-1935
0923-1923
0912-1852
1155-2015
0934-1900
0945-2028
1038-1951
30
-------
Figure 6. Map of Buffalo and Niagara Falls, NY, area (x
LaSalle Arterial).
31
= sampling site near
-------
NIAGARA RIVER
,WEST__| LA SALLE EXPRESSWAY
EAST
i FRONTIER AVENUE
WHEATFIELD AVENUE
Figure 7
Map depicting sampling locations 1 to 13 in Niagara
Falls, NY.
32
-------
Canal area of Niagara Falls, New York, and in one elementary school in a
nearby neighborhood. The trip was coordinated with EPA Region II office in
Edison, New Jersey, the New York State Department of Environmental Conserva-
tion and the Niagara County Health Department. Concomitant with the sampling
of ambient air, the NYDEC group was responsible for taking water samples
from the sump pumps. NYDEC took all but two of their water samples on the
first day; thus, only five of the eleven homes were sampled concurrently for
water and air.
The collection and analysis techniques employed utilized Tenax GC and
polyurethane foam plugs as adsorbents. Samples using Tenax GC were acquired
with Nutech Model 221A and DuPont personnel samplers, while the samples
collected on polyurethane foam (PUF) employed a Nutech High-Vol sampler. In
the basement of each home, sampling with Tenax and PUF substrates was perfor-
med side-by-side near the sump pumps. Ambient air samples taken with the
Tenax cartridge generally covered a 2-3 hour period while the High-Vol
sampler was operated at a maximum flow rate O200 A/min.) over a 8-10 hour
period. DuPont personnel samplers were used at each school and were operated
at maximum rates ('v-lOO ml/min/cartridge) for 8 hours.
Beginning with the vapor-phase organics collected on Tenax GC (Table
8), the sample taken at location 1 was in the corner of a basement of a
concrete floor near an uncovered sump. There was a moderate chlorinated
odor coming from the sump area. A water sample had previously been taken
from this sump by NYDEC on Wednesday, February 8th. In the basement at LI a
washer/dryer and a furnace were present. The house appeared to be 25 years
old and had been moved to the present site. Therefore it was unknown how
long the house had actually been located on the "Old Love" Canal.
At L2 a strong chlorinated odor was detected throughout the basement.
The floor was made of concrete and on it were located a washer/dryer and a
furnace. In addition a dog was kept in the basement and at one time the
owner's son's bedroom was located here until the odor apparently became too
strong; the bedroom had to be moved upstairs. The sump pump was uncovered
in one corner of the basement and the house seemed to be 20-25 years old.
In the basement of the third location (L3) a strong chlorinated odor
mixed with an odor of cat litter was apparent. The basement floor was made
33
-------
of concrete and on it was a washer/dryer and a furnace. A sump was uncovered
in the corner near the washer. The house appeared to be 10-15 years old and
was for sale.
The fourth sample was also from a basement which contained a moderate
chlorinated odor in the air. The uncovered sump was located in one corner
and on the concrete floor was a washer, dryer, and a furnace. This house
appeared to be at least 20 years old.
The fifth sample was taken in a basement which contained only a modera-
tely strong chlorinated odor from the sump area. The sump was enclosed in
a tool cabinet and emitted no odor when the cabinet was closed. The floor
of the basement was tiled and was arranged as a recreation room. A water
sample from the sump and an ambient air sample were concurrently taken.
This home appeared to be 15-20 years old.
The basement at L6 did not emit odors. The sump was uncovered in a
corner of a concrete basement floor. Towards the end of the sampling period
(Hi-Vol), a slight chlorinated odor was detectable. A washer, dryer and
furnace were present. The resident of this household had lived along the
canal since the 1920's and recalled when dumping of the chemicals occurred
during the war years by the industry. The household inhabitant also recalled
several instances when the chemical waste caught fire and burned for several
days. The present home is approximately 30 years old.
The seventh sample was taken in a basement where no apparent odor from
the sump could be detected as it lay open in the corner. In the basement
was a washer, dryer and a furnace. The house was approximately 20-25 years
old.
The eighth and ninth samples were taken also in basements where no
apparent odor could be detected when the sumps were uncovered. A washer,
dryer and furnace were also present. The houses appeared to be 20-25 years
old.
The ninth sample was taken at a home in the basement where there was no
sump present. The floor was made of concrete. A washer, dryer and furnace
were present. Also kept here was a pet animal. Even though there was no
apparent odor in the basement, the owner complained of strong odors during
the warmer months of the year. This house was approximately 20-25 years old.
34
-------
The tenth sample was acquired from a basement which had undergone
remodeling. The floor was tiled and was covered with sawdust. There was
no odor from the sump since it was enclosed. This house represented one of
the newer homes sampled and it was approximately 10 years old.
The last ambient air sample (Lll) was taken in a basement which also
contained a sump along one wall. However, there were no odors coming from
the sump area. The basement had a tiled floor and was divided into two
sections, one used as a utility room and the other as an office. Also kept
in the basement was a pet animal. The owner of this residence remarked
that during the summer, explosions underground along the canal could be
heard. The house appeared to be no more than 10 years old.
The remaining ambient air samples collected on Tenax GC cartridges
were taken at the 93rd and 99th Street schools. Air samples were collected
in two gymnasiums and a classroom. During the sampling, no chlorinated
odors could be detected.
Sampling was also conducted in the Niagara Falls and Buffalo, NY,
areas. The sampling protocol is given in Table 10 and the respective
locations in Figure 8 and 9.
RESULTS AND DISCUSSION
Linden, NJ
Qualitative Analysis—
A detailed listing of the vapor-phase organics which were identified
in ambient air samples from Linden, NJ, is given in Appendix B.
Quantitative Analysis--
Table 11 presents the estimated levels of halogenated hydrocarbons in
ambient air samples from Linden, NJ. Of all the Lalogenated organics
detected, the compounds in Table 11 are considered ubiquitous.
"Old Love" Canal, Niagara Falls, NY
Qualitative Analysis—
A total of 42 halogenated compounds was identified (Table 12). Among
the halogenated hydrocarbons were four site-specific compounds. These were
pentachlorobutadiene, 1,3-hexachlorobutadiene, 1,2-dibromoethane and 1,2-
dichloropropane. The remaining halogenated hydrocarbons were present in
trace quantities and are considered ubiquitous, i.£., they normally are
35
-------
Table 10. SAMPLING PROTOCOL FOR NIAGARA FALLS, BUFFALO, NY AND VICINITY
Sampling Area
Niagara Falls
Niagara Falls
Ambers t
Ambers t
Buffalo
Buffalo
Niagara Falls
Niagara Falls
Cheektowaga
Cheektowaga
Sampling Location
Packard Viaduct
(PI/LI)
Packard, E. of Pine
(P1/L2)
1-290, Brompton St.
(P1/L3)
1-290, Brompton St.
(P1/L4)
1-290, River Rd.
(P2/L9)
Edgar St. , Irene St.
(P2/L10)
On Viaduct across from
NCI (P3/L5)
Packard St, "New Rd"
(P3/L6)
3470 Genesse
(P4/L12)
3440 Genesse
(P4/L13)
Vo lume
U)
103
112
38
29
36
56
104
116
124
60
Time
(rain)
25
27
101
92
47
20
30
35
71
65
Remarks
7/9/78
7/9/78
7/9/78
7/9/78
7/10/78
7/10/78
7/11/78
7/11/78
7/12/78
7/12/78
1800-1825
1808-1835
1713-1854
1732-1904
1715-1802
1730-1750
1215-1245
1225-1300
1040-1200
1051-1156
-------
.-NIAGARA. CO
EHIE co
Figure 8. Sampling locations and plant identifications for Niagara Falls, NY.
-------
>*r>FHHrS
Figure 9. Sampling locations and plant identifications
in Buffalo, NY.
38
-------
Table 11. ESTIMATED LEVELS OF HALOGENATED HYDROCARBONS IN AMBIENT AIR SAMPLES
FROM LINDEN, NJa
CO
\o
COMPOUND
methylenc chloride
chloroform
carbon tetrachloride
vinyl idene chloride
1 , 2-d Ichloroe thy lene
1,1-dichloroe thane
1 , 2-d Ichloroe thane
1,1,1-tr Ichloroe thane
1,1, 2- tr Ichloroe thane
tr Ichloroe thy lene
tctrachloroechylene
1,1, 1 ,2-tetrachloroethane
1,1,2,2-tetrachloroeth.v.e
pen tachloroe thane
hexachloroe thane
chlorobenzene
o-dlchlorobenzene
m-d Ichlorobenzene
£-dlchlorobenzene
1 , 2 , A-trichlorobenzene
1,3, 5-tr Ichlorobenzene
1,2, 3- tr Ichlorobenzene
PERIOD/LOCATION
PI/LI
2,709
1,178
426
<212
<21?.
<160
101
222
<167
130
321
<130
<130
<109
<109
63
T(217)
T(217)
<196
<130
<109
030
PI/L3
1,454
429
129
<212
<212
<160
41
265
<167
240
960
<80
<80
<67
<67
<200
T(133)
78
<120
<90
<67
<90
P1/L2
1,772 +1,318
440 + 210
98 + 39
<212
<212
<160
<160
217 + 43
<167
129 + 31
<674 + 411
<101
<101
< 84
84
58
T(169)
T(169)
<152
<101
<84
<101
P2/L4
1,960
T(75)
T(62)
<212
<212
<160
<160
T(100)
<217
T(167)
52
<75
<75
<62
<62
T(187)
T(125)
T(125)
<112
<75
<62
<75
P3/LX
2,100
T(75)
T(62)
<212
<212
<160
T(160)
T(217)
<167
T(59)
78
<70
<70
<59
<59
T(126)
89
T(118)
<106
<70
<59
<70
P4/L4
6,444
125
T(69)
<250
<250
<160
T(151)
T(217)
<200
T(72)
84
<63
<63
<52
<52
T(158)
T(105)
T(105)
<94
<63
<52
<63
P4/L5
T(500)
T(93)
T(69)
T(263)
T(263)
229
T(195)
T(250)
200
T(72)
T(106)
91
91
76
76
T(227)
T(151)
T(151)
136
91
76
91
P4/L6
17,400
144
T(69)
<263
<263
<216
T(186)
T(250)
<200
T(73)
T(104)
<89
<89
<75
<75
<224
T(149)
T(149)
<134
<89
<75
<89
P5/L7
26,778
355
T(74)
<263
<263
<229
<195
T(278)
<217
<217
<104
<77
<77
<64
<64
<192
<128
<128
<115
<77
<64
<77
1-6/L8
19,333 + 555
258 + 97
T(74)
T(263)
<263
<229
T(195)
T(278)
<217
T(74)
T(63)
<54
<54
<45
<45
T(135)
T(90)
T(90)
<81
<54
<45
<54
P6/L9
9,778
164
T(74)
<263
<263
<229
T(205)
T(278)
<217
<128
T(179)
<154
<154
<128
<128
T(385)
T(256)
T(256)
<231
<154
<128
<154
15 In nk
T(5)
17
T(2)
T(10)
<10
<8
<8
1(5)
<5
<5
<7
<6
<6
<5
<5
<15
<10
<10
<9
<6
<5
<6
•a
See Table 7 for sampling protocol and locations. Values are in ng/m , < signifies the
approximate detection limit considering all conditions of collection and analysis, T = trace
and ( ) is the limit of detection.
-------
Table 12. SUMMARY OF VOLATILE ORGANIC VAPORS DETECTED IN AIR:
SCHOOL ROOMS IN NIAGARA, NY
HOUSEHOLD BASEMENT AND
Chemical Class
Sampling Location
Compound
L5
L6 L2 L3 LI L12A
Elution
Temperature
Halogenated
hydrocarbons
Halogenated
aromatics
dichloroethylene
methylene chloride
chloroform
1,1,1-trichloroethane
carbon tetrachloride
trichloroethylene
tetrachloroethylene
pentachlorobutadiene
1,3-hexachlorobutadiene
1,2-dibromoethane
1,2-dichloropropane
l,2-bis-(trifluoromethyl)benzene
chlorobenzotrifluoride isomer
chlorobenzene
chlorobenzotrifluoride isomer
chlorotoluene isomer
dichlorobenzene isomer
chlorotoluene isomer
dichlorobenzene isomer
dichlorobenzene isomer
bromotoluene isomer
chlorobenzodichlorofluoride isomer
chlorobenzaldehyde isomer
dichlorotoluene isomer
trichlorobenzene isomer
dichlorotoluene isomer
trichlorobenzene isomer
(continued)
+
+•
71
72
84
90
94
100
124
182'-
197
121
99
102
130
131
141
151
161
160
165
168
168
172
179
181
183
185
189
-------
Table 12 (cont'd)
Sampling Location
Chemical Class
Compound
L5
L6 L2 L3 LI L12A
Elution
Temperature
•t-
H'
Esters
Ethers
dichlorotoluene isomer
trichlorobenzene isomer
bromochlorotoluene isomer
dichlorobenzaldehyde
trichlorotoluene isomer
trichlorotoluene isomer
trichlorotoluene isomer
tetrachlorobenzene isomer
trichlorotoluene isomer
trichlorotoluene isomer
tetrachlorobenzene isomer
tetrachlorobenzene isomer
chloronaphthalene isomer
tetrachlorotoluene isomer
pentachlorobenzene isomer
methyl formate
ethyl acetate
isopropyl acetate
ri-butyl acetate
benzyl acetate
methyl salicylate
alkyl butyrate
vinyl acetate
methyl furan isomer
2,5-dimethyl furan
diphenyl ether
furan
di-n-butyl ether
(continued)
190
195
197
202
203
208
209
213
213
215
219
222
222
232
240
64
84
93
122
184
191
218
79
83
222
70
138
-------
Table 12 (cont'd)
Chemical Class
Aldehydes
Ke tones
alcohols
acids
Miscellaneous
Compound
acetaldehyde
isobutyraldehyde
butenal isomer
n-butanal
n-pentanal
n-heptanal
furfural
acetone
methyl vinyl ketone
methyl ethyl ketone
methyl isopropyl ketone
Ci2HisO ketone isomer
2-pentanone
4-methyl-2-pentanone
methanol
ethanol
t-butanol
isopropanol
(2-butoxyethoxy) ethanol isomer
acetic
heptanoic
methoxy-di-t-butylphenol isomer
benzothiazole
Sampling Location
Elution
L5 L6 L2 L3 LI L12A Temperature
+ + + + + + 61
- + - 76
4. + + + 78
-|- — f T 1
i i Q A
4. _ 4- - + + °U
,+ - + - + + 98
+ + 119
__ + --- 126
4- 4- + + + + 70
__-- + - 81
4- + + + + + 81
, 4. 92
-4- «. — ^^ -^ *•
4- 184
_„ __ ^ ~" T^ -». >^ i
+ 97
4. 4. 4- 107
_|_ .^ -p T^ -*- "
__-- + - 64
• 4. + 4- + - 67
~T t ~ T^ '
+ _---- 73
__ + --- 72
r -_ —
4- + + + + + 95
4, - - - - 159
T
+ __--- 240
__-'+-- 196
-------
observed during sampling of any ambient air. Thirty-one halogenated aroma-
tics were identified (Table 12). The majority were primarily chlorinated
benzenes and toluenes.
Other compounds such as esters, ethers, aldehydes, ketones, alcohols
and acids were also identified. The complete listing of all the organic
compounds which were identified in these six samples is given in Appendix
B.
Using the procedures described in Appendix A, samples of ambient air
collected on PUF were analyzed by GC/MS/COMP and the mass spectra of the
chromatographic runs were examined principally for the presence of polychlori-
nated biphenyls, chlorinated phenols, and other chlorinated substances
which might be present. The results of these analyses are given in Tables
13-18. The sampling protocol and locations were previously given in Table 9
and Figure 7, respectively. In sample No. 1, in addition to many of the
chlorinated benzenes and toluenes, which were also found on the Tenax
cartridges, additional compounds were detected on PUF. They were chloronaph-
thalene, pj-chlorotoluene and dichloroaniline (tentative). At location 2
(Table 14), two isomers of hexachlorocyclohexane were identified as well as
£-chlorotoluene isomers, hexachlorobenzene, hexachlorotoluene, dichlorobi-
phenyl (tentative), chlorobenzofluorene (tentative) and heptachlorotoluene.
In addition to chlordnaphthalene, hexachlorocyclohexane, pentachlorotoluene,
we identified dichlorophenols, trichlorophenol and trichloroaniline (tenta-
tive) in ambient air at L4 (Table 16). Dichloronaphthalene and £-chloro-
biphenyl (tentative) were found at L6.
Quantitative Analysis—
The levels of benzene and halogenated organics in air which were
collected on the Tenax GC cartridges from household basements were estimated.
For quantification by HRGC/MS/COMP the ions listed in Table 19 were used.
Quantitative data are given in Tables 20 and 21. Significant concentrations
of the majority of the halogenated hydrocarbons were present. The highest
levels occurred at L6 where many of the halogenated compounds occurred in
3 ^
(jg/m amounts. Furthermore, the level of benzene was 522,697 ng/m . Also
given in Table 20 is an estimated sum of the halogenated organic materials
at each location. For example, the total quantity of halogenated organics
43
-------
Table 13. ORGANIC CHEMICALS IDENTIFIED IN AIR FROM HOUSEHOLD BASEMENT
(LI), NIAGARA, NY, USING PUF TECHNIQUE
Chroma to graphic
Peak No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Elution Time
(min)
0.73
0.86
1.00
1.24
1.38
1.54
1.86
1.89
2.13
2.19
2.46
2.73
3.44
4.06
Compound
dichloro toluene
trichlorobenzene
unknown
trichlorotoluene
trichloro toluene
tetrachlorobenzene
tetrachlorobenzene
chloronaphthalene
dichloroaniline (tent.)
tetrachloro toluene
tetrachloro toluene
tetrachloro toluene
unknown
pentachloro toluene
44
-------
Table 14. ORGANIC CHEMICALS IDENTIFIED IN AIR FROM HOUSEHOLD BASEMENT
(L2), NIAGARA, NY, USING PUF COLLECTION TECHNIQUE
Chromatographic
Peak No.
1
2
3
4
5
6
7
8
9
10
12
13
14
15
16
17
18
19
20
21
22
Elution Time
(min)
0.76
0.93
1.39
1.53
1.83
2.43
2.69
3.00
3.06
3.13
3.43
3.96
4.89
5.66
5.76
6.06
6.39
6.69
7.33
9.09
10.13
Compound
dichloro toluene
trichlorobenzene
trichloro toluene
tetrachlorobenzene
tetrachlorobenzene
unknown
tetrachlorotoluene
tetrachlorotoluene
hexachlorocyclohexane
pentachlorobenzene
pentachlorobenzene
pentachlorotoluene
pentachlorotoluene
pentachlorotoluene
hexachlorocyclohexane
dichlorobiphenyl (tent.)
hexachlorobenzene
unknown
hexachlorotoluene
chlorobenzof luorene
(tent.)
hep tachloro toluene
45
-------
Table 15. ORGANIC CHEMICALS IDENTIFIED IN AIR FROM HOUSEHOLD BASEMENT
(L3), NIAGARA, NY, USING. PUF TECHNIQUE
Chromatographic Elution Time
Peak No. ' (min) Compound
1 1.69 tetrachlorobenzene
2 3.06 pentachlorobenzene
46
-------
Table 16. ORGANIC CHEMICALS IDENTIFIED IN AIR FROM HOUSEHOLD BASEMENT
(L4), NIAGARA, NY, USING PUF COLLECTION TECHNIQUE
Chromatographic
Peak No.
;
2
3
4
5
6
7
8
9
10
11
12
13
Elution Time
(min)
0.7;
0.83
0.86
1.33
1.46
1.63
1.69
1.73
1.79
1.93
2.59
3.06
3.79
Compound
dichlorotoluene
dichlorophenol
trichlorobenzene
trichlorotoluene
tetrachlorobenzene
chloronaphthalene
trichlorophenol
tetrachlorobenzene
tetrachlorobenzene
trichloroaniline (tent.)
tetrachloro toluene
pentachlorobenzene
pentachlorotoluene
14
5.46
(tent.)
hexachlorocyclohexane
47
-------
Table 17. ORGANIC CHEMICALS IDENTIFIED IN AIR FROM HOUSEHOLD BASEMENT
(L5), NIAGARA, NY, USING PUF COLLECTION TECHNIQUE
Chromatographic
Peak No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Elution Time
(min)
0.54
0.79
0.89
1.06
1.23
1.36
1.53
1.83
2.00
2.69
3.16
5.66
5.93
6.39
Compound
dichlorobenzene
dichlorotoluene
trichlorobenzene
hexachlorobutadiene
unknown
trichloro toluene
tetrachlorobenzene
tetrachlorobenzene
unknown
tetrachlorotoluene
pentachlorobenzene
hexachlorocyclohexane
pentachloropropane
unknown
48
-------
Table 18. ORGANIC CHEMICALS IDENTIFIED IN AIR FROM HOUSEHOLD BASEMENT
(L6), NIAGARA, NY, USING PUF COLLECTION TECHNIQUE
Chromatographic E'.
Peak No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
Lution Time
(min)
0.36
0.43
0.59
0.73
1.01
1.26
1.49
1.56
2.26
2.73
3.19
3.36
3.46
4.33
5.79
6.00
6.76
11.39
Compound
chloro toluene
dichlorobenzene
dichlorotoluene
trlchlorobenzene
trichlorotoluene
tetrachlorobenzene
tetrachlorobenzene
ot-chloronaphthalene
tetrachloro toluene
pentachlorobenzene
dichloronaphthalene
trichlorophenol (tent . )
. pentachloro toluene
pentachloro toluene
hexachlorobenzene
unknown
hexachloro t oluene
pentachlorobipheriyl
(tent.)
49
-------
Table 19. IONS SELECTED FOR THE ESTIMATION OF LEVELS OF
VAPOR-PHASE ORGANICS IN AMBIENT AIR
Ion (m/z)
Chemical Class
Halogenated
hydrocarbons
Halogenated
aromatics
Compound
dichloroethylene
methylene chloride
chloroform
1, 1, 1-trichloroethane
carbon tetrachloride
trichloroethylene
tetrachloroethylene
pentachlorobutadiene
1 , 3-hexachlorobutadiene
chlorobenzene
dichlorobenzene
trichlorobenzene
tetrachlorobenzene
chlorotoluene
dichlorotoluene
trichloro toluene
tetrachloro toluene
chlorobenzaldehyde
dichlorobenzaldehyde
bromotoluene
bromochlorotoluene
chlo ronaph thalene
MW
96
84
118
132
152
130
166
224
258
112
146
180
214
126
160
194
228
140
174
170
204
162
1st
96
84
83
97
117
130
166
224
258
112
146
180
216
91
125
159
193
139
173
170
206
162
2nd
98
86
85
-
119
-
168
226
260
114
148
184
218
126
127
161
197
141
176
172
208
164
3rd
,_
-
118
-
-
-
131
189
223
113
150
147
220
128
160
194
230
142
178
171
207
—
4th
mm
-
• -
-
-
-
133
191
225
_
149
-
-
-
162
196
-
-
-
-
-
—
50
-------
Table 20. ESTIMATED LEVELS OF BENZENE AND HALOGENATED ORGANIC VAPORS IN AIR OF
HOUSEHOLD BASEMENTS AND SCHOOL ROOM IN NIAGARA, NY3
Sampling/Location
Chemical
benzene
dichloroethylene
methylene chloride
chloroform
1,1, 1- trichloroethane
carbon tetrachloride
trichloroethylene
tetrachloroethylene
pentachloroethane
pentachlorobutadiene
1, 3-hexachlorobutadiene
chlo rob enz ene
dichlorobenzene isomer
dichlorobenzene isomer
dichlorobenzene isomer
trichlorobenzene isomer
trichlorobenzene isomer
trichlorobenzene isomer
LI
13,896b
<263
1,534
1,670
3,656
200
1,224
6,346
<19
<22
<22
1,940
2,044
260
<30
642
58
<22
L2
73,785
<334
<714
834
506
496
2,920
10,652
<53
<63
114
4,232
4,400
2,442
<63
10,084
1,010
<63
L3
4,194
<294
1,300
464
412
T(83)
270
3,342
<19
<23
<23
1,000
154
76
418
72
T(23)
<23
L4
6,286
<263
1,334
684
400
5,038
5,344
5,386
<17
<20
26
3,674
2,940
2,106
3,654
56
1,306
1,066
L5
T(39)
T(79)
11,556
13,484
3,890
562
1,374
51,992
<10
T(10)
100
2,778
8,914
6,024
2,294
26
3,424
580
L6
522,698
T(334)
9,428
8,584
1,000
704
15,880
37,442
<36
<43
414
<107
100,476
51,600
34,686
27,228
2,370
3,686
L12A
976
T(334)
4,000
2,668
<334
<95
T(116)
<163
<116
<140
<140
<348
<186
<186
<186
<140
<140
<140
BC
5.6
<10
3.6
22
<5
<2
<5
<7
<5
<6
<6
<15
<8
<8
<8
<6
<6
<6
(continued)
-------
Table 20 (cont'd)
Ln
Sampling/ Location
Chemical
tetrachlorobenzene isomer
tetrachlorobenzene isomer
tetrachlorobenzene isomer
pentachlorobenzene isomer
chlorotoluene isomer
chlorotoluene isomer
dichloro toluene isomer
dichloro toluene isomer
dichlorotoluene isomer
trichlorotoluene isomer
trichlorotoluene isomer
trichlorotoluene isomer
trichlorotoluene isomer
trichlorotoluene isomer
tetrachlorotoluene isomer
tetrachlorotoluene isomer
chlorobenzaldehyde isomer
dichlorobenzaldehyde isomer
bromotoluene isomer
LI
16
12
<22
<22
2,552
3,820
8,836
3,956
<19
634
3,336
<19
1,142
<19
148
58
<26
<26
25
L2
1,832
9,600
<63
494
14,990
<53
20,926
6,316
<53
206
3,790
1,810
842
<53
168
<26
180
<63
T(53)
L3
<23
62
<23
T(23)
1,754
< "I Q
< 1 Q
86
48
46
62
T(19)
T(19)
<19
<27
<27
<19
<23
<19
L4
280
360
<20
18
4,586
<17
5,240
5,320
314
134
1,786
<17
594
60
<15
16
746
<20
134
L5
214
406
<10
30
3,022
<8
7,428
2,318
<8
1,644
4,908
466
160
<8
56
<8
34
<10
66
L6 L12A
2,400 <140
17,142 <140
<43 <140
250 <140
226,514 <116
223,042 <116
158,628 <116
98,428 <116
109,872 <116
6,886 <116
42,286 <116
43,700 <116
25,986 <116
<36 <116
<18 <116
970 <116
4,058 <116
950 <140
4,372 <116
BC
<6
<6
<6
<6
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<7
<7
<5
<6
<5
(continued)
-------
Table 20 (cont'd)
Sampling/Location
Chemical
bromochlorotoluene isomer
chloronaphthalene isomer
1 , 2-dichloropropane
total halogenated organics
LI
T(19)
78
1,406
59,489
L2
<53
84
<53
172,713
L3 L4
<19 80
<31 <27
<19 <17
13,760 58,968
L5
28
<13
<8
127,778
L6 L12A
1,542 <116
3,414 <186
<36 <116
1,786,636 7,644
Bc
<5
<8
<5
Ln
See Table 8 and Fig. 7 for sampling protocol and locations.
""Values are in ng/m , T = trace, ( ) or < indicates limit of detection.
"Values are ng/cartridge, B = Tenax GC blank cartridge.
-------
Table Si. ESTIMATED LEVELS OF HALOGENATED ORGANICS IN AIR FROM HOUSEHOLD BASEMENTS
IN NIAGARA, Wfa
Chemical
benzene
dichloroethylene
methylene chloride
chloroform
l>l»l-trichloroethane
carbon tetrachloride
trichloroethylene
tetrachloroethylene
pentachloroethane
pentachlorobutadiene
1, 3-hexachlorobutadiene
chlorobenzene
dichlorobenzene isomer
dichlorobenzene isomer
dichlorobenzene isomer
trichlorobenzene isomer
trichlorobenzene isomer
trichlorobenzene isomer
tetrachlorobenzene isomer
L8
2,610b
710
3,000
3,452
2,000
111
388
109
<18
<21
<21
25
109
T(29)
<28
T(21)
T(21)
<21
T(21)
_
L10
2,000
334
1,285
1,250
T(334)
T(334)
156
183
<19
<23
<23
35
7,863
<30
<30
11
<23
<23
T(23)
(continued)
Location
Lll
85
294
2,250
>21
1,562
80
667
396
<22
T(26)
<26
75
217
53
<30
23
T(23)
T(23)
T(23)
L13A
2,407
<334
1,428
667
373
T(83)
295
222
<111
<133
<133
T(334)
<178
<178
<178
<134
<134
<134
<134
L13B
241
<334
1 , 857
833
<334
<95
T(100)
T(155)
<122
<122
<312
T(167)
167
<167
<125
<125
<125
<125
Bc
<6
^>- \J
<4
22
<5
<2,
<5
<7
<5
<6
<6
<8
<8
<8
<6
<6
<6
<6
-------
Table 21 (cont'd)
Oi
Wn
Chemical
tetrachlorobenzene isomer
tetrachlorobenzene isomer
pentachlorobenzene
chlorotoluene isomer
chlorotoluene isomer
dichlorotoluene isomer
dichlorotoluene isomer
dichlorotoluene isomer
trichlorotoluene isomer
trichlorotoluene isomer
trichlorotoluene isomer
trichlorotoluene isomer
trichlorotoluene isomer
tetrachlorotoluene isomer
tetrachlorotoluene isomer
chlorobenzaldehyde
dichlorobenzaldehyde
bromo toluene
bromochlorotoluene
chloronaphthalene
1 , 2-dichloropropane
L8 L10
T(21) 23
<21 <23
<21 <23
<21 581
590 <19
<18 <19
74 <19
<18 <19
T(18) T(19)
T(18) T(19)
<18 <19
<18 <19
<18 <19
<25 <27
<25 <27
T(18) <21
<21 <23
<18 <23
<18 <23
<28 <30
<18 <23
Location
Lll L13A L13B
T(23) <134 <125
<23 <134 <125
<23 <134 <125
25 1,067 1,729
<19 <111 <104
49 T(lll) <104
<19 <111 <104
<19 <111 <104
<19 <111 <104
<19 <111 <104
<19 <111 <104
<19 <111 <104
<19 <111 <104
<27 <155 <146
<27 <155 <146
<19 <111 <104
<23 <133 <125
<19 <111 <104
<19 <111 <104
<30 <178" <167
<19 <111 <104
B
<6
<6
<6
<5
<5
<5
<5
<5^-
<5
<5
<5
<5
<5
<7
<7
<5
<6
<5
<5
<8
<5
See Table 8 and Fig. 7 for sampling protocol and location.
*5
Values are in ng/m , T = trace, ( ) or < indicates limit of detection.
Values are in ng/cartridge, B = Tenax GC blank cartridge.
-------
measured at L6 was 1,786,636 ng/m3. In contrast, the levels of halogenated
organics in the ambient air samples at the Elementary Schools (L12A, 13A
and 13B) were near or below the detection limit. Also, the total estimated
halogenated organics in the sample from L12A was 7,644 ng/m3.
Table 23 presents the controls which were used in this study. Since
the actual chemicals present in the air of the basements were not known
prior to sampling, a number of chemicals were used representing different
classes for controls.
Niagara Falls and Buffalo, NY
Qualitative Analysis—
A complete listing of vapor-phase organics found in this area is given
in Appendix B. Table 24 presents a summary of the volatile organics which
were identified.
Quantitative Analysis--
The levels of a few selected halogenated hydrocarbons were determined
and these data are given in Table 25. Of particular interest are two sets
of samples which were collected as upwind-downwind combinations across a
public swimming pool (P1/L4 and P1/L3) and a dry cleaning establishment
(P4/L13 and P4/L12). An elevated level of 1,1,1-trichloroethane was detected
at the swimming pool. A significantly higher level of tetrachloroethylene
was found near the dry cleaning operation.
Pollution Profiles of Vapor-Phase Halogenated Organics in Ambient Air:
Ubiquitous and Site-Specific Categories
One of the major concerns of this contract program has been to provide
pollution profiles which delineate those ambient air pollutants that are
site-specific from those which are considered to be ubiquitous. To this
end, a compilation of the chemicals identified from various sampling sites
(Locations) throughout the Continental U.S. was prepared. Information from
the following contracts was extracted: 68-02-1228, 68-02-2262, 6802-2543,
68-02-2808, 68-02-2721, 68-02-2764 and 68-01-1978.
A series of maps is given in Appendix C which will assist in locating
the origin of the ambient air sample. A map of the Continental U.S. depic-
ting the EPA regional territories is provided. The circles indicate the
geographical areas which were sampled with the Tenax GC sampling cartridge.
56
-------
Table 22. ESTIMATED LEVELS OF HALOGENATED ORGANICS IN AMBIENT AIR OF
HOUSEHOLD BASEMENTS AND SCHOOL ROOMS IN NIAGARA FALLS, NY3
CHEMICAL
benzene
dichloroethylene
methylene chloride
chloroform
1,1, 1-trichloroethane
carbon tetrachloride
trichloroethylene
tetrachloroethylene
pentachloroethane
pentachlorobutadiene
1 , 3-hexachlorobutadiene
chlorobenzene
dichlorobenzene isomer
dichlorobenzene isomer
dichlorobenzene isomer
trichlorobenzene isomer
dichlorobenzene isomer
dichlorobenzene isomer
tetrachlorobenzene isomer
tetrachlorobenzene isomer
tetrachlorobenzene isomer
pentachlorobenzene
chlorotoluene isomer
chlorotoluene isomer
dichlorotoluene isomer
dichlorotoluene isomer
dichlorotoluene isomer
trichlorotoluene isomer
trichlorotoluene isomer
trichlorotoluene isomer
trichlorotoluene isomer
trichlorotoluene isomer
tetrachlorotoluene isomer
chlorobenzaldehyde isomer
dichlorobenzaldehyde isomer
bromo toluene
bromochlorotoluene
chloronaphthalene
LOCATION
L7
3,240b
63
1,545
1,595
608
153
151
304
<38
<45
<45
68
2,172
31
45
65
45
45
32
T(45)
45
45
4,142
<37
653
<37
<37
69
79
<37
<37
<37
97
<52
<37
<45
<37
<59
L9
4,694
<213
3,627
2,190
356
85
122
151
<23
<27
<27
<69
386
22
<36
28
T(27)
<27
17
<27
<27
<27
639
<23
<23
<23
<23
<23
<23
<23
<23
<23
<32
<23
<27
<23
<23
<36
L12B
1,704
104
10,182
3,119
369
59
238
294
<106
<128
<128
T(319)
238
T(170)
<170
T(128)
<127
<127
<127
<127
<127
<127
1,013
296
T(106)
<106
<106
<106
<106
<106
<106
<106
<149
<106
<128
<106
<106
<106
L13C
1,775
NQ
44
895
395
73
126
625
<66
<79
<79
T(197)
722
295
<79
T(79)
<79
<79
<79
<79
<79
<79
645
<66
<66
<66
<66
<66
<66
<66
<66
<66
<92
<66
<79
<66
<66
<105
- a
See Table 8 and Fig. 7 for sampling protocol and locations.
Values are in ng/m^, T = trace, ( ) or < indicates limits of detection.
57
-------
Table 23. RECOVERIES OF SELECTED ORGANIC VAPORS FROM TENAX CARTRIDGES
SUBJECTED TO SAMPLE TRANSPORTATION AND STORAGE3
Chemical . Quantity Added Quantity Recovered % Recovery
(ng) (ng)
perfluorobenzene
perfluoro toluene
benzene
methylene chloride
chloroform
1,1, 1-trichloroethane
toluene
methyl ethyl ketone
320.8
221.1
258.0
355.1
177.8
45.6
101.2
302.0
337
232
220
179
159
9
115
211
105
105
85
50
89
20
113
70
n
Each chemical was spiked onto a Tenax GC sampling cartridge from a
permeation line, transported to Niagara Falls, NY, returned, stored
(-20°C) and then analyzed by GC/MS/COMP. Total time was 25 days.
58
-------
Table 24 • SUMMARY OF VOLATILE ORGANICS IDENTIFIED IN AMBIENT AIR
FROM NIAGARA FALLS AND BUFFALO, NY3
Chemical Class
Compound
LI
L2
L3
L4
L5
Halogenated hydrocarbons
Ul
VD
Phenols
Aldehydes
methylene chloride
chloroform
1,1,1-trichloroethane
carbon tetrachloride
tetrachloroethylene
dichlorobenzene isomer(s)
trichloroethylene
methyl chloride
chlorobenzene
tetrachlorobenzene
phenol
cresol isomer(s)
C2~alkyl phenol isomer(s)
C3~alkyl phenol isomer(s)
C^-alkyl phenol isomer(s)
Cg-alkyl phenol isomer(s)
Cg-alkyl phenol isomer(s)
propanal
n-butanal
pentanal
heptanal
benzaldehyde
n-octanal
iv-nonanal
n-decanal
n-hexanal
n-undecanal
acetaldehyde
(continued)
-------
Table 24 (cont'd)
Chemical Class
Compound
LI
L3
L4
L5
Furans
Ketones and Esters
Alcohols
fur an
2-methylfuran
furfural
methylbenzofuran isomer
acetophenone
diethyl phthalate(s)
alkyl butyrate(s)
methyl ethyl ketone
vinyl acetate
methyl vinyl ketone
ethyl acetate
4-methyl-2-pentanone
acetone
alcohol(?)
1-butanal
4-
1
See Table 10 for protocol and Figs. 8 and 9 for locations.
-------
Table 25. ESTIMATED LEVELS OF SELECTED HALOGENATED HYDROCARBONS FOR
NIAGARA FALLS, BUFFALO, NY, AND VICINITY
Halogenated Compound
chloroform
1, 2-dichloroethane
1,1, 1-tr ichloroethane
carbon tetrachloride
trichloroethylene
tetrachloroethylene
chlorobenzene
m,£-dichlorobenzene
o-dichlorobenzene
PI/LI P1/L2
10,333 6,524
ND ND
786 714
T 842
744 767
107 268
ND 1,911
97 2,482
126 18
Pl/L3b Pl/L4b
4,000 5,809
ND T
22,786 571
1,105 789
ND T
70 T
ND T
T ND
ND ND
Period/Location
P2/L9 P2/L10 P3/L5 P3/L6
8,333 5,809 6,333 1,190
ND T ND ND
1,000 6,571 1,286 1,143
T 631 842 632
T T 581 349
444 625 769 302
ND T ND ND
T 54 67 T
ND 62 T ND
P4/L12C
5,238
357
4,286
1,158
2,698
28,024
40
137
24
L4/L13°
3,238
679
3,571
1,947
1,279
5,217
83
233
50
See Table 25 for sampling protocol and Figs. 8 and 9 for locations.
P1/L3 and P1/L4 represent downwind and upwind locations across a public swimming pool, respectively.
ft
P4/L12 and P4/L13 are downwind and upwind locations across a dry cleaning establishment, respectively.
-------
Subsequent maps are provided for each of the regions with increasing degrees
of resolution to pinpoint the sampling locations.
Appendix D presents the compilation of halogenated chemicals. Based
upon the frequency of observation of a compound per number of determinations,
two categories were prepared. The halogenated compounds appearing in up-
wind samples more than 60% of the time were designated as ubiquitous while
those appearing only in downwind samples from industrial sites were grouped
as site-specific. Table 26 lists the ubiquitous halogenated compounds
detected in ambient air.
62
-------
TABLE 26. UBIQUITOUS VAPOR-PHASE HALOGENATED ORGANICS
IN AMBIENT AIR
Compound Compound
chloromethane trichloroethylene
methylene chloride tetrachloroethylene
chloroform chlorobenzene
1,2-dichloroethane o-dichlorobenzene
1,1,1-trichloroethane m-dichlorobenzene
carbon tetrachloride
63
-------
REFERENCES
E. D. Pellizzari. Development of Method for Carcinogenic Vapor Analysis
in Ambient Atmospheres, EPA-650/2-74-121, July 1974, 148 pp.
E. D. Pellizzari. Development of Analytical Techniques for Measuring
Ambient Atmospheric Carcinogenic Vapors, EPA-600/2-75-076, November
1975, 186 pp.
E. D. Pellizzari. The Measurement of Carcinogenic Vapors in Ambient
Atmospheres, EPA-600/7-77-055, June 1977, 288 pp.
E. D. Pellizzari. Measurement of Carcinogenic Vapors in Ambient
Atmospheres, EPA-600/7-78-062, April 1978, 237 pp.
E. D. Pellizzari. Analysis of Organic Air Pollutants by Gas Chromato-
graphy and Mass Spectroscopy, EPA-600/2-77-100, June 1977, 104 pp.
E. D. Pellizzari. Analysis of Organic Air Pollutants by Gas Chromato-
graphy and Mass Spectroscopy, EPA Contract No. 68-02-2262, in press.
64
-------
APPENDIX A
ANALYTICAL METHODS FOR VOLATILE ORGANICS AND
POLYCHLORINATED BIPHENYLS IN AMBIENT AIR
65
-------
SAMPLING AND ANALYSIS OF VOLATILE ORGANIC COMPOUNDS IN AMBIENT AIR
Principle of Method
Volatile organic compounds are concentrated from ambient air onto
Tenax GC in a short glass tube (1-3). Recovery of the volatile organics
is accomplished by thermal desorption and purging with helium into a
liquid nitrogen cooled nickel capillary trap (1,2,4) and then the vapors
are introduced into a high resolution glass gas chromatographic column
where the constituents are separated from each other (2,5). Charac-
terization and quantification of the constituents in the sample are
accomplished by mass spectrometry either by measuring the intensity of
the total ion current signal or mass fragmentography (2,6). The collec-
tion and analysis systems are shown in Figure A-l.
Range and Sensitivity
The linear range for the analysis of volatile organic compounds
depends upon two principal features. The first is a function of the
breakthrough volume of each specific compound which is trapped on the
Tenax GC sampling cartridge and the second is related to the inherent
sensitivity of the mass spectrometer for each organic (2,7). Thus, the
range and sensitivity are a direct function of each compound which is
present in the original ambient air. The linear range for the quantita-
tion on the gas chromatograph/mass spectrometer/computer (GC/MS/COMP) is
generally three orders of magnitude. Table Al lists the overall theore-
tical sensitivity for some examples of volatile organics which is based
on these two principles (7).
The sensitivity of this technique for the very volatile organic
compounds (C, to C^ alkanes) is inadequate for the purpose of this
study. Alternate methods for their collection and analysis are sug-
gested (11) .
Interferences
The potential difficulties with this technique are primarily asso-
ciated with those cases where isomeric forms of a particular substance
cannot be resolved by the high resolution chromatographic column and
when the mass cracking patterns of each of the isomers are identical. An
66
-------
FLOW
/METES
NEEDLE
VALVE
CARTRIDGE
GLASS
rl=E3
FILTER
VAPOR COLLECTION SYSTEM
PURGE
GAS
THERMAL
DESC.-PT1CN
CKAM3ER
ANALYTICAL SYSTEM
CAPILLARY
TRAP
HEATED
SLCCXS
EXHAUST
Figure Al. Vapor collection and analytical systems for
analysis of organic vapors in ambient air.
67
-------
Table Al. OVERALL THEORETICAL SENSITIVITY OF HIGH RESOLUTION
GAS CHROMATOGRAPHY/MASS SPECTROMETRY/COMPUTER ANALYSIS
FOR ATMOSPHERIC POLLUTANTS
00
Estimated Detection
Limit
Chemical
Class
Halogenated
hydrocarbon
Compound
Vinyl bromide
Bromoform
Bromodichlorome thane
Dibromochlorome thane
l-Bromo-2-chloroethane
Allyl bromide
1-Bromopropane
l-Chloro-3-bromopropane
l-Chloro-2 , 3-dibromopropane
1 , l-Dibromo-2-chloropropane
1 , 2-Dibromoethane
"
1 , 3-Dibromopropane
Epichlorohydrin
(l-Chloro-2, 3-epoxypropane)
Epibromohydrin
(l-Bromo-2, 3-epoxypropane)
Bromobenzene
Methyl bromide
Methyl chloride
Vinyl chloride
Methylene chloride
Chloroform
Carbon tetrachloride
ng/m
250
0.340
1.300
0.667
1.00
5.00
5.200
0.150
•vO.100
M) . 100
0.530
M) . 100
9.600
0.300
0.100
500
2000
800
700
200
250
ppt
57
0.03
0.22
0.07
0.67
1.04
1.06
0.01
<0.01
<0.01
0.07
•v-0.01
2.50
0.05
0.02
135
1000
333
200
/ f\f\
420
400
(continued)
-------
Table Al (cont'd)
VO
Estimated Detection
Limit
Chemical
Class
Halogenated
hydrocarbon
(cont'd)
Halogenated
ethers
Nitrosamines
Oxygenated
hydrocarbons
Compound
1 , 2-Dichloroethane
1,1, 1-Trichloroe thane
Tetrachloroethylene
Trichloroethylene
l-Chloro-2-methylpropene
3-Chloro-2-methylpropene
3-Chloro-l-butene
Allyl chloride
4-Chloro-l-butene
l-Chloro-2-butene
Chlorobenzene
o-Dichlorobenzene
m-Dichlorobenzene
Benzylchloride
2-Chloroethyl. ethyl ether
Bis- (chloromethyl) ether
N-Nitrosodimethylamine
N-Nitrosodiethylamine
Acrolein
Glycidaldehyde
Propylene oxide
3
ng/m
32
66
2.5
10
62
62
83
83
38
13
2.10
1.00
0.75
0.65
4.15
1.0
5.0
3.0
VIOO
•^•59
•v60
ppt
8.15
12.45
0.38
1.92
21.5
21.5
28.8
28.8
13.2
4.5
0.47
0.06
0.01
0.01
0.97
1.10
1.67
0.74
56.5
9.5
25.5
(continued)
-------
Table Al (cont'd)
Estimated Detection
Limit
Chemical
Class
Oxygenated
hydrocarbons
(cont'd)
Compound
Butadiene diepoxide
Cyclohexene oxide
Styrene oxide
Acetophenone
ng/m
•vLO
2
•v-2
ppt
6.7
2.5
0.415
•vO.415
M..2
Nitrogenous
Compounds
Sulfur
Compounds
Nitromethane
Aniline
Diethyl sulfate
Ethyl methane sulfate
8
3.0
•vS.O
0.78
aLimits are calculated on the basis of the breakthrough volume for 2.2 g of Tenax GC (at 70°F),
capillary column performance and sensitivity of the mass spectrometer to that compound m the
mass fragmentography mode of most intense ion.
-------
there are 53 isomers. As the number of carbon atoms increases in the
hydrocarbons and aromatics, the number of potential isomers becomes
increasingly large and difficult to completely resolve by gas chroma-
tography and/or by their corresponding mass cracking patterns. However,
differentiation between the hydrocarbons, that is, alkanes, alkenes,
aromatics, oxygenated, etc., can be accomplished.
4.0 Reproducibility
The reproducibility of this method has been determined to range
from ±10 to ±30% of the relative standard deviation for different subs-
tances when replicate sampling cartridges are examined (5). The inhe-
rent analytical errors are a function of several factors: [1] the
ability to accurately determine the breakthrough volume for each of the
identified organic compounds; [2] the accurate measurement of the am-
bient air volume sampled; [3] the percent recovery of the organic from
the sampling cartridge after a period of storage; [4] the reproduci-
bility of thermal desorption for a compound from the cartridge and its
introduction into the analytical system; [5] the accuracy of determining
the relative molar response ratios between the identified substance and
the external standard used for calibrating the analytical system, [6]
the reproducibility of transmitting the sample through the high resolu-
tion gas chromatographic column; and [7] the day-to-day reliability of
the MS/COMP system (1-8).
The accuracy of analysis is generally ±30% but depends on the
chemical and physical nature of the compound (2,8).
5.0 Advantages and Disadvantages of the Method
The gas chromatograph/mass spectrometer interfaced with a glass jet
separator is extremely sensitive and specific for the analysis of many
volatile organic compounds in ambient air. High resolution gas chroma-
tographic separation provides adequate resolution of the substances
found in ambient air for their subsequent quantification. The com-
bination of the high resolution gas chromatographic column and the
selection of specific or unique ions representing the various compounds
of interest identified in the air samples yields a relatively specific
assay method for these compounds (1-8).
71
-------
Collected samples can be stored up to one month with less than 10%
losses for most of the chemical classes (2,8). Because some of the
compounds of interest may be hazardous to man, it is extremely important
to exercise safety precautions in the preparation and disposal of liquid
and gas standards, cleaning of used glassware, etc. in the analysis of
air samples.
Since the mass spectrometer cannot be conveniently mobilized,
sampling must be carried out away from the instrument.
The efficiency of air sampling increases as the ambient air de-
creases Ci-e. , sensitivity increases) (8).
The retention of water by Tenax is low; its thermal stability is
high; and its background is negligible allowing sensitivity analysis
(1,2,5,8).
Apparatus
Sampling Cartridges--
The sampling tubes are prepared by packing a ten centimeter long by
1.5 cm i.d. glass tube containing 6 cm of 35/60 mesh Tenax GC with glass
wool in the ends to provide support (2,5). Virgin Tenax (or material to
be recycled) is extracted in a Soxhlet apparatus for a minimum of 18
hours each time with acetone and hexane prior to preparation of cart-
ridge samplers (2,5). After purification of the Tenax GC sorbent and
drying in a vacuum oven at 100°C for 3 to 5 hours at 28 inches of water,
all the sorbent material is meshed to provide a 35/60 particle size
range. Cartridge samplers are then prepared and conditioned at 270°C
with helium flow at 30 ml/min for 30 min. The conditioned cartridges
®
are transferred to Kimax (2.5 cm x 150 cm) culture tubes, immediately
sealed using Teflon-lined caps and cooled. This procedure is performed
in order to avoid recontamination of the sorbent bed (2,5).
Cartridge samplers with longer beds of sorbent may be prepared
using a proportionally increased amount of Tenax in order to achieve a
larger breakthrough volume for compounds of interest, and thus increa-
sing the overall sensitivity of the technique (8).
72
-------
Gas Chromatographic Column—
A 0.35 mm i.d. x 100 m glass SCOT capillary column coated with SE-
30 stationary phase and 0.1% benzyltriphenylphosphonium chloride is used
for effecting the resolution of the volatile organic compounds (5). The
capillary volume is conditioned for 48 hrs. at 245° at 2.25 ml/min of
helium flow.
A glass jet separator on a Varian MAT CH-7 GC/MS/COMP system is
employed to interface the glass capillary column to the mass spectro-
meter. The glass jet separator is maintained at 240°C (2,5).
Inlet Manifold--
An inlet manifold for thermally recovering vapors trapped on Tenax
sampling cartridges is used and is shown in Figure Al (1,2,4,5).
Gas Chromatograph—
A Varian 1700 gas chromatograph is used to house the glass capil-
lary column and is interfaced to the inlet manifold (Figure Al).
Mass Spectrometer/Computer—
A Varian MAT CH-7 mass spectrometer with a resolution of 2,000
equipped with a single ion monitoring capability is used in tandem with
a gas chromatograph (Figure Al). The mass spectrometer is interfaced to
a Varian 620/L computer (Figure Al).
Reagents and Materials
All reagents used are analytical reagent grade.
Procedure
Cleaning of Glassware—
All glassware, sampling tubes, cartridge holders, etc. are washed
in Isoclean/water, rinsed with deionized distilled water, acetone and
air dried. Glassware is heated to 450-500°C for 2 hours to insure that
all organic material has been removed prior to its use.
Preparation of Tenax GC—
Virgin Tenax GC is extracted in a Soxhlet apparatus for a minimum
of 18 hours with acetone or methanol prior to its use. The Tenax GC
sorbent is dried in a vacuum oven at 100°C for 3-5 hours and then sieved
to provide a fraction corresponding to 35/60 mesh. This fraction is
used for preparing sampling cartridges. In those cases where sampling
73
-------
cartridges of Tenax GC are recycled, the sorbent is extracted in a
Soxhlet apparatus with acetone or methanol as described for the virgin
material, but the sorbent is further extracted with a non-polar solvent,
hexane, in order to remove the relatively non-polar and non-volatile
materials which might have accumulated on the sorbent bed during previous
sampling periods.
Collection of Volatile Organics in Ambient Air—
Continuous sampling of ambient air is accomplished using a Nutech
Model 221-A portable sampler (Nutech Corp., Durham, NC, see Figure Al,
Reference 2). Flow rates between 1-10 £/min are available with this
sampling system. Flow rates are generally maintained at 1 £ using
critical orifices and the total flow is monitored through a calibrated
flow meter. The total flow is also registered by a dry gas meter. Con-
concomitant with these parameters the temperature is continuously recorded
with a Meteorological Research, Inc. Weather Station since the break-
through volume is important in order to obtain quantitative data on the
volatile organics. This portable sampling unit operates on a 12 volt
storage battery and is capable of continuous operation up to a period of
24 hours. However, in most cases at the rates which are employed in the
field, the sampling period is generally 1-3 hours. This portable sampling
unit is generally utilized for obtaining "high volume" samples. Duplicate
cartridges are deployed on each sampling unit utilizing a sampling head
as shown in Figure A2.
In addition to the Nutech samplers, DuPont personnel samplers are
also used to acquire "low volumes" of ambient air as well as long-term
integrated samples (12-36 hrs). Identical Tenax GC sampling cartridges
are employed in this case, and the sampling is conducted in duplicate.
The flow rate is balanced between duplicate cartridges using critical
orifices to maintain a rate of 25-100 ml/min per cartridge.
For large sample volumes, it is important to realize that a total
volume of air may cause the elution of compounds through the sampling
tube if their breakthrough volume is exceeded. The breakthrough volumes
of some of the volatile organics are shown in Table A2 (2,4,7,8). These
breakthrough volumes have been determined by a previously described
74
-------
Figure A2. Sampling head for housing cartridge sampling train.
75
-------
Table A2. TENAX GC BREAKTHROUGH VOLUMES FOR SEVERAL ATMOSPHERIC POLLUTANTS*
Temperature (°F)
Chemical
Class
Halogenated
hydrocarbon
Compound
methyl chloride
methyl bromide
vinyl chloride
methylene chloride
chloroform
carbon tetrachloride
1 , 2-dichloroethane
7
1,1, 1-trichloroethane
J r
tetrachloroethylene
trichloroethylene
l-chloro-2-methylpropene
3-chloro-2-methylpropene
1 , 2-dichloropropane
1 , 3-dichloropropane
epichlorohydrin (1-chloro-
2,3-epoxypropane)
3-chloro-l-butene
allyl chloride
4-chloro-l-butene
l-chloro-2-butene
chlorobenzene
o-dichlorobenzene
m-dichlorobenzene
b.p.
(°C)
-24
3.5
13
41
61
77
83
75
121
87
68
72
95
121
116
64
45
75
84
132
181
173
50
8
3
2
11
42
34
53
23
361
90
26
29
229
348
200
19
21
47
146
899
1,531
2,393
60
6
2
1.5
9
31
27
41
18
267
67
20
22
162
253
144
15
16
36
106
653
1,153
1,758
70
5
2
1.25
7
24
21
31
15
196
50
16
17
115
184
104
12
12
27
77
473
867
1,291
80
4
1.0
5
18
16
23
12
144
38
12
13
81
134
74
9
9
20
56
344
656
948
90
3
0.8
4
13
13
18
9
106
28
9
10
58
97
54
7
6
15
40
249
494
697
100
2.5
On
.y
0.6
3
10
10
14
7
78
21
7
8
41
70
39
6
5
12
29
181
372
510
(continued)
-------
Table A2 (cont'd)
Temperature (°F)
Chemical
Class
Halogenated
hydrocarbons
(cont'd)
Halogenated
Ethers
Nitrosamines
Oxygenated
hydrocarbons
Nitrogenous
Hydrocarbons
Sulfur
Compounds
Compound
benzyl chloride
bromoform
ethylene dibromide
bromobenzene
2-chloroethyl ethyl ether
Bis-(chloromethyl)ether
N-nitrosodimethylamine
N-nitrosodiethylamine
acrolein
glycidaldehyde
propylene oxide
butadiene diepoxide
cyclohexene oxide
styrene oxide
phenol
acetopheonone
B-propiolactone
nitromethane
aniline
diethyl sulfate
ethyl methane sulfate
b.p.
179
149
131
155
108
-
151
177
53
-
34
-
132
194
183
202
57
101
184
208
86
50
2,792
507
348
2,144
468
995
385
2,529
19
364
35
1,426
2,339
5,370
2,071
3,191
721
45
3,864
40
5,093
60
2,061
386
255
1,521
336
674
280
1,836
14
247
24
1,009
1,644
3,926
1,490
2,382
514
34
2,831
29
3,681
70
1,520
294
188
1,079
241
456
204
1,330
10
168
17
714
1,153
2,870
1,072
1,778
366
25
2,075
21
2,564
80
1,125
224
138
764
234
309
163
966
8
114
11
506
811
2,094
769
1,327
261
19
1,520
15
1,914
90
830
171
101
542
124
209
148
700
6
77
8
358
570
1,531
554
991
186
14
1,114
11
1,384
100
612
131
74
384
89
142
107
508
4
52
5
253
400
1,119
398
740
132
11
817
8
998
(continued)
-------
Table A2 (cont'd)
00
Temperature (°F)
Chemical
Class
Amines
Ethers
Esters
Ketones
Aldehydes
Alcohols
Compound
dimethylamine
isobutylamine
t-butylamine
di- (n-butyl)amine
pyridine
aniline
diethyl ether
propylene oxide
ethyl acetate
methyl acrylate
methyl methacrylate
acetone
methyl ethyl ketone
methyl vinyl ketone
acetophenone
acetaldehyde
benzaldehyde
methanol
n-propanol
allyl alcohol
b.p.
7.4
69
89
159
115
184
34.6
35
77
80
100
56
80-2
81
202
20
179
64.7
97.4
97
50
9
71
6
9,506
378
8,128
29
13
162
164
736
25
82
84
5,346
3
7,586
1
27
32
60
6
47
5
7,096
267
5,559
21
9
108
111
484
17
57
58
3,855
2
5,152
1
20
23
70
4
34
4
4,775
189
3,793
15
7
72
75
318
12
39
40
2,767
2
3,507
0.8
14
16
80
3
23
3
3,105
134
2,588
11
5
48
50
209
8
27
28
2,000
1
2,382
0.6
10
11
90
2
16
2
2,168
95
1,766
8
4
32
34
137
6
19
19
1,439
0.9
1,622
0.4
7
8
100
1
11
1
1,462
67
1,205
5
3
22
23
90
4
13
14
1,037
0.7
1,101
0.3
5
6
(continued)
-------
Table A2 (cont'd)
vo
Temperature (°F)
Chemical
Class
Aromatics
Hydrocarbons
Inorganic
gases
Compound
benzene
toluene
ethylbenzene
cumene
n-hexane
n-heptane
1-hexene
1-heptene
2 , 2-dimethylbutane
2 , 4-dimethylpentane
4-methyl-l-pentene
cyclohexane
nitric oxide
nitrogan dioxide
chlorine
sulfur dioxide
water
b.p.
(°C)
80.1
110.6
136.2
152.4
68.7
98.4
63.5
93.6
49.7
80.5
53.8
80.7
-
-
-
-
100
50
108
494
1,393
3,076
32
143
28
286
0.5
435
14
49
0
0
0
0.06
0.06
60
77
348
984
2,163
23
104
20
196
0.4
252
10
36
0
0
0
0.05
0.05
70
54
245
693
1,525
17
75
15
135
0.3
146
8
26
0
0
0
0.03
0.04
80
38
173
487
1,067
12
55
11
93
0.2
84
6
19
0
0
0
0.02
0.03
90
27
122
344
750
9
39
8
64
0.2
49
4
14
0
0
0
0.02
0.01
100
19
86
243
527
6
29
6
44
0.1
28
3
10
0
0
0
0.01
0
breakthrough volume is given in fc/2.2 g Tenax GC used in sampling cartridges.
-------
technique (2). The breakthrough volume is defined as that point at
which 50% of a discrete sample introduced into the cartridge is lost.
Although the identity of a compound during ambient air sampling is not
known (therefore, also its breakthrough volume), the compound can still
be quantified after identification by GC/MS/COMP once the breakthrough
volume has subsequently been established. Thus, the last portion of the
sampling period is selected which represents the volume of air sampled
prior to breakthrough for calculating concentration. For cases in which
the identity of a volatile organic compound is not known until after
GC/MS, the breakthrough volume is subsequently determined.
Previous experiments have shown that the organic vapors collected
on Tenax GC sorbent are stable and can be quantitatively recovered from
the cartridge samplers up to 4 weeks after sampling when they are
tightly closed in cartridge holders and placed in a second container
that can be sealed, protected from light and stored at 0°C (1,2).
Analysis of Samples--
The instrumental conditions for the analysis of volatile organics
on the sorbent Tenax GC sampling cartridge is shown in Table A3. The
thermal desorption chamber and the six port Valco valve are maintained
at 270° and 240°, respectively. The glass jet separator is maintained
at 240°. The mass spectrometer is set to scan the mass range from 25-
350. The helium purge gas through the desorption chamber is adjusted to
15-20 ml/min. The nickel capillary trap on the inlet manifold is cooled
with liquid nitrogen. In a typical thermal desorption cycle, a sampling
cartridge is placed in the preheated desorption chamber and the helium
gas is channeled through the cartridge to purge the vapors into the
liquid nitrogen capillary trap [the inert activity of the trap has been
shown in a previous study (5)]. After the desorption has been completed,
the six-port valve is rotated and the temperature on the capillary loop
is rapidly raised (greater than 10°/min); the carrier gas then introduces
the vapors onto the high resolution GC column. The glass capillary
column is temperature programmed from ambient to 240°C at 4°C/min and
held at the upper limit for a minimum of 10 min. After all the
80
-------
Table A3. OPERATING PARAMETERS FOR GLC/MS/COMP SYSTEM
Parameter
Setting
Inlet-manifold
desorption chamber
valve
capillary trap - minimum
maximum
thermal desorption time
GLC
100 m glass SCOT SE/30
carrier (He) flow
transfer line to MS
270°C
220°C
-195°C
+250°C
4 min
25-240°C, 4°C/min
^3 ml/min
240°C
MS
scan range
scan range, automatic-cyclic
filament current
multiplier
ion source vacuum
m/z 20 •* 300
1 sec/decade
300 (JA
6'° -6
^4 x 10" torr
81
-------
components have been eluted from the capillary column, the analytical
column is then cooled to ambient temperature and the next sample is
processed (2).
An example of the analysis of volatile organics in ambient air is
shown in Figure A3 and the background from a blank cartridge is shown in
Figure A4. The high resolution glass capillary column was coated with
SE-30 stationary phase which is capable of resolving a multitude of
compounds to allow their subsequent identification by MS/COMP techniques;
in this case over 120 compounds were identified in this chromatogram.
Operation of the MS/COMP System (Figure A5)--Typically the mass
spectrometer is first set to operate in the repetitive scanning mode.
In this mode the magnet is automatically scanned exponentially upward
from a preset low mass to a high mass value. Although the scan range
may be varied depending on the particular sample, typically the range is
set from m/z 25 to m/:z 300. The scan is completed in approximately 1.8
seconds. At this time the instrument automatically resets itself to the
low mass position in preparation for the next scan, and the information
is accumulated by an on-line 620/L computer and written onto magnetic
tapes or the dual disk system. The reset period requires approximately
2.0 seconds. Thus, a continuous scan cycle of 3.8 seconds/scan is
maintained and repetitively executed throughout the chromatographic run.
The result is the accumulation of a continuous series of mass spectra
throughout the chromatographic run in sequential fashion.
Prior to running unknown samples, the system is calibrated by
introducing a standard substance, perfluorokerosene, into the instrument
and determining the time of appearance of the known standard peaks in
relation to the scanning magnetic field. The calibration curve which is
thus generated is stored in the 620/L computer memory. This calibration
serves only to calibrate the mass ion over the mass scanning range.
While the magnet is continuously scanning, the sample is injected
and automatic data acquisition is initiated. As each spectrum is acquired
by the computer, each peak which exceeds a preset threshold is recognized
and reduced to centroid time and peak intensity. This information is
stored in the computer core while the scan is in progress. In addition,
82
-------
oo
oo
T T i i i i r i
3» 42 48 «• » B4 6T
TIME (WIN)
Figure A3. Profile of ambient air pollutants for Wood River, IL using high resolution gas
chromatography/mass spectrometry/computer.
-------
ao-.
32
styrene
44 56
68 80 92
TEMPERATURE (°C)
104
116 128
140 152
Figure AA. Background profile for Tenax GC cartridge blank.
-------
GC Column
(capillary)
Sample
inlet/
manifold
Separator
Varian CH-7
mass
spectrometer
Varian
620L
computer
9-track
magnetic
tape
oo
Ln
Figure A5. Schematic diagram of GC/MS/Computer system.
-------
approximately 30 total ion current values and an equal number of Hall
probe signals are stored in the core of the computer as they are acquired.
During the two-second period between scans this spectral information,
along with the spectrum number, is written sequentially on disks, and
the computer is reset for the acquisition of the next spectrum.
This procedure continues until the entire GC run is completed. By
this time there are from 800-1400 spectra on the disk which are then
subsequently processed. Depending on the information required, they may
then either be processed immediately or additional samples may be run,
stored on magnetic tape and the results examined at a later time.
The mass spectral data are processed in the following manner.
First, the original spectra are scanned and the total ion current (TIC)
information is extracted. Then the TIC intensities are plotted against
the spectrum number on the States 31 recorder. The information will
generally indicate whether the run is suitable for further processing,
since it provides some idea of the number of unknowns in the sample and
the resolution obtained using the particular GC column conditions.
The next stage of the processing involves the mass conversion of
the spectral peak times to peak masses which is done directly via the
dual disk system. The mass conversion is accomplished by use of the
calibration table obtained previously using perfluorokerosene. Normally
one set of the calibration data is sufficient for an entire day's data
processing since the characteristics of the Hall probe are such that the
variation in calibration is less than 0.2 daltons/day. A typical time
required for this conversion process for 1,000 spectra is approximately
30 min.
After the spectra are obtained in mass converted form, processing
proceeds either manually or by computer. In the manual mode, the full
spectrum of scans for the GC run is recorded on the Statos 31 plotter.
The TIC information available at this time is most useful for deciding
which spectra are to be analyzed. At the beginning of the runs where
peaks are very sharp nearly every spectrum must be inspected
individually to determine the identity of the component. Later in the
86
-------
chromatographic run when the peaks are broader only selected scans need
to be analyzed.
Identification of resolved components is achieved by comparing the
mass cracking patterns of the unknown mass spectra to an eight major
peak index of mass spectra (9). Individual difficult unknowns are
searched by the use of the Cornell University STIRS and PBM systems.
Unknowns are also submitted to EPA MSSS system for identification. When
feasible, the identification of unknowns is confirmed by comparing the
cracking pattern and elution temperatures for two different chroma-
tographic columns (SE-30 and Carbowax SCOT capillaries) for the unknown
and authentic compounds. The relationship between the boiling point of
the identified halogenated hydrocarbon and the elution temperature on a
non-polar column (the order of elution of constituents is predictable in
homologous series since the SE-30 SCOT capillary separates primarily on
the basis of boiling point) is carefully considered in making structure
assignments.
Mass spectral search programs are operational at the Triangle
Universities Computation Center (TUCC). RTI maintains twice daily
service to TUCC, which is a one-quarter mile distance from the RTI
campus. Additional information about each magnetic tape containing the
mass spectra of halogenated hydrocarbons is entered directly into the
TUCC job stream using a remote job entry processing. This is normally
done at TUCC using one of the five terminals located within the Analytical
Sciences Laboratory. The control information contains selected spectrum
numbers with instructions to process entire GC runs. The computer
program systems compare simultaneously either the entire library of
25,000 compounds or some subset of this library. The complete reports
showing the best fits for each of the unknowns is produced at TUCC and
printed out at the high speed terminals located on the RTI campus or
TUCC. Thus, the processing of the mass spectral data obtained for the
halogenated hydrocarbons in the samples collected proceeds by one of
three routes. Each consists of a different level of effort. The first
level is strictly a manual interpretation process which proves to be the
87
-------
most thorough approach. The second level is executed when the interpre-
tation at the first level has not yielded conclusive results.
Quantitative Analysis — In many cases the estimation of the level of
pollutants by capillary gas chromatography in combination with mass spec-
trometry is not feasible utilizing only the total ion current monitor (See
Figure A3 for example). Since baseline resolution between peaks is not
always achieved, we employ the techniques which have been previously deve-
loped under contract whereby full spectra are obtained during the chroma-
tographic separation step and the selected ions are presented as mass
fragmentograms using computer software programs which allow the possibility
of deconvoluting constituents which were not resolved in the total ion
current chromatogram (6). Examples are depicted in Figures A6 and A7 which
represent an ambient air sample with a TIC profile as in Figure A3.
In our gc/ms/comp system, we request from the Varian 620/L dedi-
cated computer mass fragmentograms for any combination of m/e ions when
full mass spectra are obtained during chromatography; thus selectivity
is obtained by selecting the unique ion for that particular organic
substance and this is represented vs. time with subsequent use of that
ion intensity for quantitation. Also quantitation with external stan-
dards is easily achieved using the intensity of the total ion current
monitor or the use of a unique mass cracking ion in a mass spectrum of
the external standard. Thus, we use mass fragmentography for the
quantitation of organics in ambient air when the total ion current
monitor is inadequate because of the lack of complete resolution between
components in the mixture.
As described previously, the quantitation of constituents in am-
bient air samples is accomplished either by utilizing the total ion
current monitor or where necessary the use of mass fragmentograms. In
order to eliminate the need to obtain complete calibration curves for
each compound for which quantitative information is desired, we use the
method of relative molar response (RMR) factors (10). Successful use of
this method requires information on the exact amount of standard added
and the relationship of RMR (unknown) to the RMR (standards). The
method of calculations is as follows:
88
-------
00
200
MASS SPECTRUM NO.
250
900
-------
fi . . ..i ....... n i • i l.i.i...i,1.1,1,1.1.1.1.1
o so IUU
MASS SPECTRUM NO.
Figure A7. Mass fragmentograms of characteristic ions representing methylene chloride
(m/e 49) and chloroform (m/z 83) in ambient air.
-------
A ./Moles
(1) RMR
unknown/ standard A , /Moles ,
A = peak area, determined by integration or triangulation.
The value of RMR is determined from at least three independent
analyses.
A . /g . /GMW ,
unk unk unk
A „ ./g , ./GMW „.
std 6std std
A = peak area, as above
g = number of grams present
GMW = gram molecular weight
Thus, in the sample analyzed:
A . -GMW . -g . .
unk unk std
( ^
1 J 8unk ~ A ^-GMW . -RMR . . . .
std std unk/ std
The standard can be added as an internal standard during sampling;
however, since the volume of air taken to produce a given sample is
accurately known, it is also possible and more practical to use an
external standard where the standard is introduced into the cartridge
prior to its analysis. Two standards, hexafluorobenzene and perfluoro-
toluene, are used for the purpose of calculating RMR's. From previous
research it has been determined that the retention times for these two
compounds are such that they elute from the glass capillary column (SE-
30) at a temperature and retention time which does not interfere with
the analysis of unknown compounds in ambient air samples.
Since the volume of air taken to produce a given sample is accura-
tely known and an external standard is added to '.he sample, then the
weight per cartridge and hence the concentration of the unknown can be
determined. The approach for quantitating ambient air pollutants
requires that the RMR be determined for each constituent of interest.
This means that when an ambient air sample is taken, the external standard
is added at a known concentration during the analysis. It is not impera-
tive at this point to know what the RMR of each of the constituents in
91
-------
the sample happens to be. However, after the unknowns are identified
then the RMR can be subsequently determined and the unknown concen-
tration calculated in the original sample using the RMR. In this manner
it is possible to obtain qualitative and quantitative information on the
same sample with a minimum of effort.
References
1. Pellizzari, E. D., Development of Method for Carcinogenic Vapor
Analysis in Ambient Atmospheres. Publication No. EPA-650/2-74-121,
Contract No. 68-02-1228, 148 pp., July, 1974.
2. Pellizzari, E. D., Development of Analytical Techniques for
Measuring Ambient Atmospheric Carcinogenic Vapors. Publication No.
EPA-600/2-75-075, Contract No. 68-02-1228, 187 pp., November, 1975.
3. Pellizzari, E. D., J. E. Bunch, B. H. Carpenter and E. Sawicki,
Environ. Sci. Technol., 9, 552 (1975).
4. Pellizzari, E. D., B. H. Carpenter, J. E. Bunch and E. Sawicki,
Environ. Sci. Technol., 9, 556 (1975).
5. Pellizzari, E. D., The Measurement of Carcinogenic Vapors in
Ambient Atmospheres. Publication No. EPA-600/7-77-055, Contract
No. 68-02-1228, 288 pp., June, 1977.
6. Pellizzari, E. D., J. E. Bunch, R. E. Berkley and J. McRae,
Anal. Chem., 48, 803 (1976).
7. Pellizzari, E. D., Quarterly Report No. 1, EPA Contract No.
68-02-2262, February, 1976.
8. Pellizzari, E. D., J. E. Bunch, R. E. Berkley and J. McRae,
Anal. Lett., 9, 45 (1976).
9. "Eight Peak Index of Mass Spectra", Vol. 1, (Tables 1 and 2) and
II (Table 3), Mass Spectrometry Data Centre, AWRE, Aldermaston,
Reading, RF74PR, UF, 1970.
10. Pellizzari, E. D., Quarterly Report No. 3, EPA Contract No.
68-02-2262, in preparation.
11. Pellizzari, E. D., "Measurement of Carcinogenic Vapors in
Ambient Atmospheres", EPA Contract No. 68-02-1228, Final Report,
in press.
Written analytical protocol prepared 1/24/77.
92
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SAMPLING AND ANALYSIS FOR POLYCHLORINATED BIPHENYLS AND OTHER
SEMI-VOLATILE ORGANICS IN AMBIENT AIR
1 0 PROCEDURE FOR CLEANUP OF POLYURETHANE FOAM PLUGS
®
1. Cut 5 cm diameter x 13 cm long plugs from sheet of Olympic 2315
polyurethane foam.
2. Mark each plug with an identification number in the top using a
hot wire.
3. Place four plugs in bottom of clean four liter beaker, add 500 ml
hot toluene (100°C.).
4. Compress the plugs 10 times using a one liter Erlenmeyer flask.
5. Let sit five minutes on steam bath.
6. Repeat Steps 4 and 5.
7. Compress the plugs and decant the toluene.
8. Add 250 ml fresh, hot toluene and repeat steps 4 through 7.
9. Repeat Step 8 three times (total of five extractions).
10. Using clean tweezers, transfer each plug into a foil-wrapped wide-
mouth jar and cover loosely with a foil-lined cap.
11. Dry in vacuo at 50° for 12 hours.
12. Remove from oven, tighten cap and store away from potential con-
taminants .
2.0 PROCEDURE FOR EXTRACTION OF POLYCHLORINATED BIPHENYLS FROM POLY-
URETHANE FOAM PLUGS AND GLASS FIBER FILTERS
1. Using cleaned tongs, remove foam plugs and filters from storage
jars and place them in 400 ml beakers.
2. Add 150 ml of toluene to beakers containing foam plugs and 50 ml
toluene to beakers containing filters.
3. Compress the foam plug 10 times to the bottom of the beakers with a
125 ml Erlenmeyer flask, soak for five minutes and compress an addi-
tional 10 times.
4. Squeeze the toluene out of the plug and decant into a flat bottom
boiling flask. Similarly decant the toluene from the glass fiber
filter into a separate flask.
5. Repeat Steps 2 through 4 two more times.
6. Concentrate in a flat bottom boiling flask topped with a Snyder
column to approximately 15 ml.
93
-------
7. Transfer concentrate to 1.5 x 120 mm culture tube, assuring quanti-
tative transfer with small portions of petroleum ether. Blow down
under N at <25°C just to dryness.
8. Dilute to approximately 1 ml with hexane and proceed with column
cleanup.
9. Concentrate column eluant with a Kuderna-Danish (K-D) apparatus
to 2.0 ml.
3.0 COLUMN CLEANUP PROCEDURE
1. Silica gel (Davison Chemical Division. W. H. Grace, Baltimore, MD) ,
Grade 923, 100-200 mesh is washed with toluene, followed by hexane,
dried at 130° for 16 hr and stored in a sealed amber bottle.
2. Using a 1.0 x 30 cm glass column, pack with a plug of glass wool,
silica gel in a hexane slurry to 10 cm height, and 1.0 cm Na2SO^.
3. Wash column with 50 ml hexane to settle the bed and clean any residual
contaminants.
4. Transfer sample to column in 1.0 ml or less solvent (preferably
hexane) with washing.
5. Elute the PCB's with 50 ml hexane.
6. The foam background and pesticides are eluted with toluene.
7. Concentrate hexane eluate in K-D apparatus, followed by nitrogen
blow down if necessary to achieve a detectable concentration.
8. Analyze by GC/ECD or GC/MS as described elsewhere.
4.0 GAS CHROMATOGRAPHY/MASS SPECTROMETER ANALYTICAL CONDITIONS
Instrument: Finnigan 3300 Quadrupole gas chromatograph/mass
spectrometer with PDP/12 computer
Column: 180 cm x 2 mm i.d. glass
Column Packing: 2% OV-101 on Chromosorb W HP
Oven Temperature: 150°, 3 min. 8°/min to 230°, Hold
Flow Rate: 30 cc/mins helium
MID Ions: 188, 222, 256, 290, 324, 358, 392 426 (nominal)
Full Scan: 110-500 m/e
lonization Voltage: 70 eV (nominal)
Detector Voltage: 1.8 - 2.2 kV
94
-------
APPENDIX B
ORGANIC VAPORS IDENTIFIED IN AMBIENT AIR
95
-------
Table Bl. VOLATILE ORGANIC VAPORS IN AMBIENT AIR FROM LINDEN, NJ
(P4/L5)3
Chromato-
graphic
Peak No.
1
1A
IB
3
4
5
5A
6
7A
8
8A
9
10
11
12
12A
13
14
14A
15
15A
16
16A
16B
17
18A
18B
18C
19
19A
20
21
21A
21B
22
22A
23
23A
24
24A
25
-Z6
26A
27A
28 .
28A
Elution
Temp.
48
55
60
62
63
64
64
65
71
72
73
75
76
77
78
80
81
82
84
87
88
89
90
90
91
94
94
94
96
96
97
101
103
107
108
109
110
111
112
113
115
117
118
122
123
124
Compound
co2
acetaldehyde
isopentane
acetone
n-pentane
diethyl ether
dichloroethylene isomer
dichloromethane
C,HgO isomer (tent.)
C,H isomer
2-methylpentane
3-methylpentane
hexafluorobenzene (ef)
r^-hexane
chloroform
ethyl acetate
perfluorotoluene (eS)
methylcyclopentane
1 , 1, 1-trichloroethane
benzene
carbon tetrachloride
cyclohexane
2-methylhexane
2, 3-dimethylpentane
3-methylhexane
n-pentanal
trichloroetnylene
CgH.g isomer
n-heptane
C^H.. , isomer
acetic acid
methylcyclohexane
CBH1H isomer
O J-O
C.H,, isomer
o ID
toluene
CgH.g isomer
CgH18 isomer
C_H. , isomer
O J.O
n-hexanal
C0H.,, isomer
o 16
n-octane
tetrachloroethylene
C0H1£ isomer
8 16
C.H-_ isomer
C8H16 isomer
CqHj. isomer
Chromato-
graphic
Peak No.
29
29A
30
30A
30B
31
31A
31B
32
32A
33
34
34A
34B
35
35A
36
36A
37
37A
38
38A
38B
39
39A
40
41
41A
42
43
43A
44
44A
44B
44C
44D
44E
45
45A
45B
45C
46
46A
Elution
Temp.
126
127
128
128
129
131
131
132
132
133
134
135
136
137
138
139
141
142
143
144
145
146
146
147
148
148
149
150
150
151
152
152
153
154
156
156
157
157
158
159
159
160
161
Compound
ethylbenzene
CjH 8 isomer
xylene isomer
cqH-0 isomer
CgH.n isomer
C10H22 isonier
styrene isomer
ii-heptanal
<>-xylene + cinH22 isomer
C9Hlg isomer
n-nonane
C10H22 ^somer
CgH.g isomer
C.-H2_ isomer
C -H22 isomer +
isopropylbenzene
C. _H22 isomer
C11H24 isomer
C10H20 is°mer
benzaldehyde
n-propylbenzene
ethyltoluene isomer
^10^22 ^-somer
1,3, 5- trimethylbenzene
C11H24 isomer
C,H,-benzene isomer
C H isomer + o-ethyltoluene
C10H22 isolner
C, , H- . isomer
11 24
n-octanal
1,2,4-trimethylbenzene
C10H20 lsomer
ti-decane
dichlorobenzene isomer (trace)
C,-alkyl benzene +
C11H22 isomers
1 , 2 , 3-trime thylbenzene
C,-alkyl benzene isomer
C11H24 isomer
^12^26 + dichlorobenzene
isomers
indan
C10H20 isoner
C11H22 isomer
C11H24 lsolner
C,-alkyl benzene isomer
(continued)
96
-------
Table Bl (cont'd)
Chroma to-
graphic
LI
47A
47E
47C
47D
^7E
«7F
48
48A
49
49A
49E
i9C
49D
49E
49F
49G
49H
50
Elution
Temp .
162
163
164
165
166
166
167
168
169
170
172
173
175
177
177
182
182
184
184
Compound
acetophenone
CUH24 isomer
cresol isomer
C,-alkyl benzene +
C11H24 lsomers
C,-alkyl benzene isomer
CgHlgO isomer
C,-alkyl benzene isomer
n-nonanal
C11H22 lsomer
n-undecane
C12H24 isomer
C, -alkyl benzene isomer
dimethylphenol isomer
C,H7-benzene + Cj-alkyl
benzene isomers
C11H22 isomer
C,-alkyl benzene isomer
C10H20° 1SOmer
naphthalene
n-decanal
Shromato-
;raphic
Peak No.
50A
51
51A
51B
51C
52
53
53A
53B
53C
53D
54
54A
55
55A
55B
55C
55D
55E
55F
Elution
Temp.
(°C)
185
186
187
188
197
199
200
201
203
206
208
210
211
213
215
215
217
218
219
221
Compound
C12H24 isolner
n-dodecane
C,-alkyl benzene isomer
C13H28 isomer
C11H22° isomer
n-undecanal
ii-tridecane
B-methylnaphthalene
a-methylnaphthalene
C14H30 iSOmer
alkyl phthalate
alkyl phthalate
biphenyl
n-tetradecane
C15H30 ls°mer
C--alkyl naphthalene isomer
alkyl ketone
C..,H,,,0 isomer
lj /D
n-pentadecane
C15H30 is°mer
See Table 7 for sampling protocol.
97
-------
Table B2. VOLATILE ORGANIC VAPORS IN AMBIENT AIR FROM
STATEN ISLAND, NY (P6/L9)a
Chromato-
graphic
Peak No.
1
4
4A
4B
5A
6
6A
6E
7
8
8A
9
10
10A
11
12
12A
13
14
14A
15
ISA
15E
16
16A
17
17A
17B
18
20
21
21A
21B ,
22
22A
23
23A
2J.
25
26
27
27A~
27B
28
28A
Elution
Temp.
48
53
54
59
60
61
61
62
63
68
69
70
73
74
75
76
77
78
80
81
82
83
85
86
87
88
89
90
91
94
95
96
98
101
102
103
105
106
108
109
110
111
112
113
113
Compound
co2
C4H10 i80mer
acetaldehyde
isopentane
furan + propanal +
C.H, _ isomer
5 10
n-pentane
acetone
diethyl ether (tent.)
methylene chloride
ter-butanol
C,H,n isomer
5 10
2-methylpentane
3— methylpentane
butanal + C,H, , isomer
D Lf.
hexafluorobenzene (eS)
n-hexane
chloroform
C.H,_ isomer (tent.)
o LL
perfluorotoluene (eS)
methylcyclopentane
C-jH.., isomer (tent.)
1,1, 1-trichloroethane
C.H 0 isomer
benzene
carbon tetrachloride (traces)
cyclohexane
2-methylhexane
2,3-dimethylpentane
3-methylhexane
CgH 8 isomer
acetic acid
ri-heptane
C7H1, isomer
methylcyclohexane
CgHlg isomer
CgH g isomer
CgH,, isomer
C8Hlg isomer
toluene
CgHlg isomer
CgH18 isomer
CgH 6 Isomer
CgH16 isomer
CgHlg isomer
n-hexanal
hronato-
;r«phic
'eak Mo.
28B
29
29A
30
30A
31
31A
31B
32
32A
33
33A
34
35
35A
36
36A
37
37A
38
38A
39
39A
40
40A
41
41A
4 IB
42
42A
42B
42C
42D
43
43A
44
44A
44B
44 C
44D
44E
45
45A
45B
Elution
Temp.
CO
114
116
117
117
122
124
125
126
127
128
129
129
130
132
132
133
134
136
139
140
142
143
144
145
146
147
148
148
148
150
151
152
152
153
153
154
155
155
156
156
159
160
161
161
Compound
CgH,, isomer
jn-octane
C-H, . isomer
o ID
tetrachloroethylene
C9H20 isomer
C0H_- isomer
9 20
C?Hlg isomer (tent.)
C9H18 lsomer
ethy Ibenzene
C9H18 lso!ner
xylene isomer
CQH_n isomer
9 20
C.Hj- isomer
CgHj- isomer
styrene
t>-xylene
CjHjg isomer
n-nonane
C9Hlg isomer
C10H22 ieomeT +
isopropy Ibenzene
^10^22 ^solner
C10H22 + C9H18 isomers
C10H16 I80tner
benzaldehyde
C,-alkyl benzene isomer
ethyltoluene isomer
1, 3, 5-trimethy Ibenzene
phenol
C11H24 isomer
o-ethyltoluene
sat . hydrocarbon
iv-octanal
C10H20 isomer
1,2, 4- trimethy Ibenzene
C10H20 I80mer
n-decane
C11H24 isomer
dichlorobenzene isomer
C^-alkyl benzene isomer
1,2, 3-trimethy Ibenzene
C11H24 isomer
C, ,H_. + dichlorobenzene
11 24
isomers
indan
C11H22 isomer
(continued)
98
-------
Table B2 (cont'd)
Chromato-
graphic
Peak No.
45C
45D
46
46A
46B
46C
46D
46E
47
47A
48
48A
48B
48C
48D
48E
48F
48G
Elution
Temp.
CO
163
164
164
165
166
167
168
169
170
171
172
174
175
177
178
179
180
184
Compound
C.-alkyl benzene isomer
C,-alkyl benzene isomer
acetophenone
cresol isomer
C.-alkyl benzene isomer
C12H26 isomer (tent-)
C;-alkyl benzene isomer
C.-alkyl benzene isomer
ri-nonanal
C11H22 isomer (tent-)
n-undecane
C.-alkvl benzene isomer
4
C,-alkyl benzene isomer (tent.)
C.-alkyl phenol isomer
dimethylphenol isomer
unsat. hydrocarbon
C.-alkyl phenol isomer
C12H24 isomer
Chromato-
graphic
Peak No.
48H
49
49A
50
50A
SOB
50C
SOD
50E
50F
50G
50H
501
51
51A
52A
52B
Elution
Temp.
185
186
187
188
191
195
200
202
203
203
206
209
212
213
217
229
230
Compound
C..H-. + C.-alkyl phenol
12 24 3 i r
isomers
naphthalene
C12H24 isomer
ii-dodecane
unsat. hydrocarbon
C, ,H_, isomer
13 26
unsat. hydrocarbon
C13H26 isomer
n-tridecane
g-methylnaphthalene
o-methylnaphthalene
unsat. hydrocarbon
C. eH.. isomer
alkyl butyrate
n-tetradecane
C15H30 isomer
n-pentadecane
See Table 7 for sampling protocol.
99
-------
Table B3. VOLATILE ORGANIC VAPORS IDENTIFIED IN AMBIENT AIR FROM
STATEN ISLAND, NY (P6/L8)a
Chromato-
grapnic
Peak No.
1
4
4A
4B
4C
5A
6
6A
7
7A
8
9A
9B
10
10A
11
12
13
13A
14
14A
15
ISA
15E
16
16A
17
17A
17E
18
ISA
18B
19
20
20A
21
21A
22
22 A
22B
22C
22D
•X. '
22E
23
23A
24"
Elution
Temp .
48
53
55
55
58
60
61
61
62
63
63
67
68
69
70
72
73
74
75
76
77
79
80
82
84
85
86
87
88
89
91
92
92
94
99
101
104
106
108
109
110
111
113
114
115
116
Compound
co2
isobutane (tent.)
ii-butane
acetaldehyde
isopentane
C.H isomer
acetone
n-pentane
diethyl ether
dichloroethylene isomer (tent.)
methylene chloride
ter-butanol (tent.)
C5H1Q isomer
2-methylpentane
C.H, - isomer
6 Li
3-methylpentane
hexaf luorobenzene (ef)
n-hexane
chloroform
methyl ethyl ketone
ethyl acetate
perf luorotoluene (eS)
methylcyclopentane
1,1, 1-trichloroethane
benzene
carbon tetrachloride
cyclohexane
2-methylhexane
2 , 3-dimethylpentane
3-methylhexane
C7H14 isomer
trichloroethylene
acetic acid
n- heptane
methylcyclopentane
4-methyl-2-pentanone
C-H., isomer
toluene
CgH,g isomer
C-H „ isomer
C-H,, isomer
8 16
C-H , isomer
O ID
CgH., isomer
n-octane
C8H16 is°mer
tetrachloroethylene
Tiromato-
raphic
eak No.
4A
4B
4C
24D
24E
24F
24G
25
26
26A
26B
27
27A
28
28A
28B
29
29A
29B
30
30A
31
31A
32
33
33A
33B
34
34A
34B
34C
35
35A
36
36A
37
37A
37B
37C
38
39
39A
39B
Elution
Temp.
CC)
117
117
120
121
122
123
124
126
128
128
129
131
131
132
133
134
135
137
137
138
140
141
142
144
145
146
147
147
148
149
149
150
151
152
152
153
154
156
157
158
159
159
161
Compound
CgHj, isomer
C,H,-0 isomer (tent.)
o Li
C9H2(. isomer
CgH 8 isomer
C_H,, isomer + chlorobenzene
o J.O
(tent.)
C9H. g isomer
CgH,g isomer
ethylbenzene
xylene isomer
C-H-- isomer
C10H22 lsomer
C10H22 isolner
styrene
o-xylene + C-.QH isomer
n-heptanal (tent . )
CgH « isomer
n-nonane
C9H18 istraer
C10H20 i80mer
C.0H-2 isomer 4-
isopropylbenzene
C11H24 1S°mer
C,-K-- isomer
C10H20 is°mer
benzaldehyde + ri-propylbenzene
ethyltoluene
1,3,5-trimethylbenzene
ClnH-- isomer
C11H24 isomer
phenol
-------
Table B3 (cont'd)
Chromato-
graphic
Peak No.
40
40A
41
41A
41B
41C
41D
41E
41F
42
42A
42B
42C
42D
42E
42F
42G
42H
421
43
43A
44
44A
Elution
Temp.
162
163
163
164
165
166
168
169
169
171
172
173
178
178
179
180
181
183
185
185
186
187
188
Compound
C -alkyl benzene +
isomers
C.-alkyl benzene isomer
acetophenone
C.-alkvl benzene isomer
4
C-...H,.. isomer
11 Z4
C.-alkyl benzene isomer
C H isomer
n-nonanal
C H isomer
ji-undecane
C.-.jH-,, isomer
C.-alkyl benzene isomer
C11H22 isomer
C11H20 lsomer
C.-alkyl benzene isomer
C,,.H,., isomer
LL ZO
C^-alkyl benzene isomer
C- oH~ , isomer
naphthalene
ii-decanal
C12H24 isomer
n- do de cane
C12H24 lsomer
Chroma to-
graphic
Peak No.
44B
44C
44D
45
45A
46
46A
46B
46C
46D
46E
46F
47
47A
48
48A
48B
48C
48D
48E
49
49A
50A
Elution
Temp.
189
190
194
198
199
202
202
203
204
207
209
210
212
213
216
218
220
222
223
227
229
231
240
Compound
C13H28 isomer
C ioH2fi *somer
C12H24 lsomer
C14H30 isolner
C H , isomer
n-tridecane
B-me thylnaphthalene
C13H26 *somer
o-methylnaphthalene
C14H28 lsomer
C, -H,, isomer
U ^D
sat. hydrocarbon
alkyl butyrate
C15H32 isomer
n-tetradecane
C2-alkyl naphthalene
C_-alkyl naphthalene
C15H30 lsomer
C,/H00 isomer
14 28
C14H20 isomer
n-pentadecane
C16H32 *somer
ti-hexadecane
See Table 7 for sampling protocol and locations.
101
-------
s
0)
S-i
M
o
c
o
H
cd
4J
o
H
Mass Spectrum No.
Figure Bl. GC/MS/COMP profile of volatile organic vapors in ambient air from
L5 (see Table 8 for protocol).
-------
Table B4. VOLATILE ORGANIC VAPORS IDENTIFIED IN AIR FROM
HOUSEHOLD BASEMENT (L5), NIAGARA, NY3
Chroma to-
graphic
Peak No.
1
2A
3
3A
3B
4
4A
4B
5
6
6A
6B
7
7A
9
10
11
11A
11B
11C
12
12A
13
11
UA
14B
15
16
17
17A
17B
18
ISA
19
20
20A
21
21A
21B
22
22A
22B
23
23A
24
Elutic
Temp
57
60
61
62
62
64
66
67
68
70
70
71
72
73
75
77
79
79
80
80
81
82
83
84
84
86
88
88
90
92
92
93
94
95
96
96
97
98
99
100
101
101
102
103
104
>n
Compound
co2
propane
acetaldehyde
C.HQ isomer
C,H.rt isomer
4 10
C3HgO isomer (tent.)
ethanol
C_H _ isomer
acetone
ii-pentane
C Hg isomer
dichloroethylene
methylene chloride
ter-butanol (tent.)
C^HgO + C.jHgO isolners (tent.)
butenal isomer
2-methylpentane
C5H10 isomer
butanal
methyl ethyl ketone
3-methylpentane
C,H, _ isomer
o iz
hexafluorobenzene (el) +
methylfuran isomer
ri-hexane
chloroform
C,H. _ isomer
6 12
perfluorotoluene (el)
methylcyclopentane
1 • 1 i 1-trichloroethane
methyl isoprppyl ketone
isopropyl acetate
benzene
carbon tetrachloride (traces)
acetic acid + cyclohexane
2-methylhexane
C,.H,QO isomer
3-methylhexane
ll-pentanal
C^H^^ isomer
trichloroethylene
C5H120 isomer (tent.)
^7^12 **" ^7^14 *somers
n- heptane
C^H., isomer
C-H1 , isomer
Chromato-
graphic
Peak No.
24A
25
26
26A
26B
27
27A
28
29
29A
30
30A
31
32
33
35
36
37
37A
37B
38
39
39A
39B
41
42
42A
43
43A
44
45
45A
45B
46
47
48
49
50
50A
2
2A
Elution
Temp.
107
107
109
110
112
114
116
117
118
118
120
121
122
123
124
127
128
129
130
132
133
135
135
136
138
140
141
142
144
146
147
148
149
151
155
156
157
159
160
161
165
Compound
C^H isomer
4-me thy 1- 2-pen tanone
C8H18 + C8H14 lsomers
C8H16 isomer
CgHj, isomer
toluene
CgH g isomer
CgH isomer
^6*112° iso!ner (tent.)
C_H_, isomer
CgH- , isomer
CgH isomer
n-butyl acetate
Ti- octane
tetrachloroethylene
C9H20 isomer
C9H20 isomer
chlorobenzene
chlorobenzotrifluoride
(traces)
C-H,. isomer
ethylbenzene
xylene isomer
C9H20 isomer
C9H20 lsomer
styrene
o- xylene
CgH- n isomer
ti-nonane
CgH^g isomer
isopropylbenzene +
^10H22 isolner
C,_H._ isomer
10 22
C,-alkyl cyclohexane isomer
C10H22 lsomer
chlorotoluene isomer
C,-alk-, 1 benzene +
j
C1nH_. isomers
10 22
C10H22 isomer
C10H20 + C3~alk>'1 benzene
isomers
heptanoic acid (tent.) +
cmHo/% isomer
10 20
C,-alkyl benzene isomer
dichlorobenzene isomer
C^-alkyl benzene isomer
(continued)
103
-------
Table B4 (cont'd)
Chromato-
graphic
Peak No.
53
54
54A
55
56
57
58
59
59A
60
61
61A
62
62A
63
63A
63B
63C
64
65
67
68
69
69A
69B
70
71
72
72A
73
73A
74
75
76
76A
77
78
78A
79
79A
80
81
82
Elution
Temp.
(°C)
165
167
168
169
170
171
172
173
174
175
176
177
177
179
181
182
183
183
184
185
189
190
192
193
194
195
197
198
199
200
201
203
204
205
206
207
208
208
209
210
212
213
213
Compound
C -alkyl benzene +
C H isomers
11 24
C11H22 + C10H16 is°mers
bromo toluene isomer
C, -alkyl benzene + sat.
hydrocarbon isomers
C,-alkyl benzene isomer
Cn -H,, . isomer
11 24
C11H24 isomer
C11H24 + C10H16 isomers
C. -alkyl benzene isomer
C, -alkyl benzene +
C .H_-benzene isomers
C -.H,., isomer
C11H22 isomer
ri-undecane
chlorobenzaldehyde isomer
dichlorotoluene isomer
pentachlorobutadiene
trichlorobenzene isomer
C- -alkyl benzene isoraer
C1QH160 Isomer
dichlorotoluene isomer
trichlorobenzene isomer
trichlorobenzene isomer
napthalene
methyl salicylate
C-i />Hi£ isomer
LZ Zo
trichlorobenzene isomer
1, 3-hexachlorobutadiene
unknown
unsat. hydrocarbon
C, ^H- isomer
1 J £t3
sat. hydrocarbon
trichloro toluene isomer
C- /H-o isomer
C10H18 isomer
C.. -H.. , isomer (tent.)
n-tridecane
trichlorotoluene isomer
B-methylnaphthalene
trichlorotoluene isomer
a-methylnaphthalene
C H,- isomer (tent.)
tetrachlorobenzene isomer
trichlorotoluene isomer
Chromato-
graphic
Peak No.
83
84
85
86
87
88
89
89A
90
91
91A
92
93
94
95
96
96A
97
98
99
100
101
102
103
104
105
106
107
108
108A
110
111
111A
112
113
114
114A
115
116
116A
117
118
119
120
121
Elution
Temp.
(°C)
214
215
216
216
217
218
219
220
221
222
223
224
225
226
227
228
229
229
230
232
233
234
235
236
238
239
240
240
240
240
240
240
240
240
240
240
240
240
240
240
240
240
240
240
240
Compound
C13H26 isolner
C14H30 lsomer
C14H30 lsomer
sat. hydrocarbon
sat . hydrocarbon
biphenyl
tetrachlorobenzene isomer
C14H28 isomer
ii-tetradecane
C^-alkyl naphthalene isomer
C15H30 isomer
C_-alkyl naphthalene isomer
C15H30 isomer
unsat . hydrocarbon
Cg-alkyl benzene isomer (tent.)
C- /H-- isomer
C15H28 isomer
C_ ,H_ . isomer
lo .34
C15H24° isomer (tent.)
tetrachlorotoluene isomer
n-pentadecane
C_ eH,._ isomer
C -alkyl naphthalene isoraer
unsat. hydrocarbon
C-i cH.™ isomer
lo JL
C_-alkyl benzene isomer
C, /-H,,^ isomer
C, /-HT^ isomer
lo jz
diethyl phthalate
C3~alkyl naphthalene isomer
n— hexadecane
sat. hydrocarbon
uns at . hydrocarbon
sat . hydrocarbon
C18H38 isomer
C^^H isomer
CI(,H,.. isomer
ii-heptadecane
C19H40 lsomer
C,,H_. isomer
17 34
methoxy-di-ter-butylphenol
isomer
hydrocarbon
C._H,_ isomer
C17H34 isomer
n-octadecane
(continued)
'104
-------
Table B4 (cont'd)
Chroraato-
graphic
Peak No.
122
123
Elution
Temp.
C°C)
240
240
unknown
Compound
sat. hydrocarbon
Chromato-
graphic
Peak No.
123A
124
Elution
Temp.
<°C)
240
240
Compound
unsat . hydrocarbon
sat. hydrocarbon
See Table 8 for sampling protocol.
105
-------
Table B5. VOLATILE ORGANIC VAPORS IDENTIFIED IN AIR FROM
HOUSEHOLD BASEMENT (L6), NIAGARA, NYa
Chroma to-
graphic
Peak No.
1
1A
IB
2
2A
2B
3
3A
3B
4
4A
4B
4C
4D
4E
5
5A
6
7
7A
7B
8
9
9A
10
11
12
13
14
15
ISA
16
17
18
ISA
18B
18C
19
20
21
22
23
23A
24
25
26
Elution
Temp.
57
61
62
63
66
68
69
70
70
71
72
73
73
78
79
80
81
82
83
83
84
85
86
87
88
90
93
95
97
98
100
100
103
108
110
111
112
115
121
122
123
124
125
126
129
130
Compound
co2
acetaldehyde
C.H0 isomer
4 8
n-butane
ethanol (tent. )
C H isomer
acetone
C,H00 isomer (tent.)
J O
fur an (traces)
n-pentane
CCH0 isomer
J O
C H isomer
methylene chloride
C.H 0 isomer (tent.)
vinyl acetate
2-methylpentane
methyl ethyl ketone
3-methylpentane
C,H - isomer
hexafluorobenzene (eS)
methylfuran isomer
n-hexane
chloroform + C,H, „ isomer
O Li
perfluorotoluene (eS)
acetic acid + C,H.,_ isomer
o J./
methylcyclopentane
benzene
cyclohexane
C,H.., isomer
7 16
C-.H,, isomer
/ ID
C-jH.., isomer
trichloroethylene
ii-heptane
methylcyclohexane
C0H.... isomer
o lo
C-H _ isomer
o lo
C.H , isomer
a ID
toluene
CDH1n isomer
o lo
C0H, isomer
o io
C0H, , isomer
o lo
n-octane
C0H,, isomer
o 16
tetrachloroethylene
C_H-~ isomer
CgH isomer
Chromato-
graphic
Peak No.
27
27A
28
29
30
30A
31
32
32A
33
33A
34
35
35A
36
36A
36B
36C
37
38
38A
38B
39
40
41
42
42A
43
44
44A
45
46
47
47A
48
49
50
51
51A
52
Elution
Temp. ,
131
132
134
135
136
136
138
139
139
140
141
143
145
147
148
148
149
150
152
160
160
160
162
164
165
166
166
167
168
168
169
170
171
171
172
172
173
174
175
176
Compound
chlorobenzene
chlorobenzotrifluoride isomer
(traces)
ethylbenzene
C-H „ isomer
xylene isomer
Cgli- isomer
CqH«_ isomer
styrene
CgHj o isomer
o-xylene
CgH1 p isomer
n-nonane
CqH fi isomer
C10H22 isomer
CgR. , isomer
C H isomer
C H isomer
C10H16 isomer (tent.)
chlorotoluene isomer
chlorotoluene + C,-alkyl
benzene isomers
C1 n^9n ^somer
C_-alkyl benzene isomer
C--alkyl benzene +
C10H20 lsomers
n-decane
dichlorobenzene isomer
C^-alkyl benzene isomer
C,-alkyl benzene isomer
C11H24 lsomer
dichlorobenzene isomer
C10H16 isolner
bromotoluene isomer
C.-alkyl benzene H-
C. -H__ isomers
11 22
C,-alkyl benzene isomer
C,-alkyl benzene Isomer
chlorobenzodichlorof luoride
isomer (traces)
C--H_. isomer
11 24
CH22 isomer
C,,H0, + C.-alkyl
11 24 4
benzene isomers
C11H24 + C10H18 is°mers
C.-alkyl benzene isomer
(continued)
106
-------
Table B5 (cont'd)
Chromato-
graphic
Peak No.
53
54
54A
55
56
57
57A
58
59
60
60A
£]_
62
62A
63
64
65
66
67
68
69
70
71
72
73
73A
Elution
Temp.
(°C)
178
180
181
183
185
188
188
189
190
192
193
193
195
196
197
198
199
201
202
202
203
204
205
206
208
Compound
C H isomer
n-undecane
chlorobenzaldehyde isomer
dichlorotoluene isomer
dichlorotoluene isomer
dichlorotoluene isomer
C,-alkyl benzene isomer (tent.)
C--alkyl benzene isomer
C_-alkyl benzene isomer
trichlorobenzene isomer
C12H24 isomer
naphthalene
n-dodecane
C -alkyl benzene +
Cn ~H,. . isomers
12 24
trichlorobenzene +
bromochlorotoluene isomers
1 , 3-hexachlorobutadiene
C10H14° isomer
unsat. hydrocarbon isomer
(tent.)
C13H26 + dichlorobenzaldehyde
(traces) isomers
C10H0, isomer
-L J iD
C13H28 ls°mer
C13H26 isomer (tent.)
trichlorotoluene isomer
C13H28 isomer
C H., isomer
ii-tridecane
Chromato-
graphic
Peak No.
74
75
76
77
78
79
79A
80
81
82
83
84
84A
85
86
87
88
89
90
91
92
93
94
97
Elution
Temp.
(°C)
210
212
214
215
216
217
217
218
218
219
221
222
222
223
225
227
228
230
231
232
235
237
240
240
Compound
trichlorotoluene isomer
trichlorotoluene isomer
sat. hydrocarbon isomer
(tent.)
tetrachlorobenzene isomer
trichlorotoluene isomer
C14H30 lsomer
C. -H-, isomer
ij £.0
C14H3Q isomer
sat . hydrocarbon
sat . hydrocarbon
C14H30 isomer +
biphenyl (traces)
tetrachlorobenzene isomer
chloronaphthalene isomer
ri-tetradecane
C_-alkyl naphthalene +
C14H28 ls°mers
unknown
C14H28 + V"*1
naphthalene isomers
C15H24 isomer
C14H20 isomer
C16H34 isomer
tetrachlorotoluene isomer
ii-pentadecane
C ,H , isomer (tent.)
pentachlorobenzene
n-hexadecane
See Table 8 for sampling protocol.
107
-------
o
oo
c
2
t-t ttant
g
lit" 13SD int
Mass Spectrum No.
Figure B2. GC/MS/COMP profile of volatile organic vapors in ambient air from L2 (see
Table 8 for protocol).
-------
Table B6. VOLATILE ORGANIC VAPORS IDENTIFIED IN AIR FROM
HOUSEHOLD BASEMENT (L2), NIAGARA, NYS
Chromato-
graphic
Peak No.
1
1A
IB
1C
ID
IE
2
3
3A
3B
4
4A
4B
5
5A
6
7
8
8A
8B
9
9A
9B
9C
10
10A
10B
11
11A
12
12A
12B
12C
13
14
14A
15
16
16A
16B
16C
17
18
Elution
Temp.
57
61
62
62
63
64
68
70
72
79
81
81
82
83
84
85
85
86
87
88
90
90
92
94
95
96
96
97
99
99
100
101
101
• 102
104
104
109
111
112
114
114
116
117
Compound
co2
C,H, isomer (tent.)
J D
acetaldehyde
C,Hfi isomer
C4H10 isomer
C.Hg isomer
ethanol (tent.)
acetone
isopropanol (tent.)
butenal isomer
2-methylpentane
C.H isomer
butanal
methyl ethyl ketone
C,H10 isomer
6 12
hexaf luorobenzene (e§)
n-hexane
chloroform + ethyl acetate
C,H, „ isomer
D \.£
C,H, . isomer
D -LZ
perfluorotoluene (eS)
methylcyclopentane
1,1,1-trichloroethane (traces)
c6Hio + c5Hio° aldehy»e
isomers
benzene
carbon tetrachloride (traces)
cyclohexane
2-methylhexane
C H 0 isomer (traces)
3-me thy Ihexane
ri-pentanal
CyHj, isomer
acetic acid
trichloroethylene + 1,2-bis-
(trif luorome thy 1) benzene
ii-heptane
CyH,, isomer
4-methyl-2-pentanone +
methylcyclohexane
CSH18 isomer
0 lo
C.H,, isomer
O ID
CQH,, isomer
0 ID
C-.H,. isomer
7 12
toluene
CnH, . isomer
Chromato-
graphic
Peak No.
19
19A
20
20A
21
22
23
23A
23B
24
25
25A
26
26A
26B
26C
27
27A
28
29
29A
30
31
31A
31B
32
33
34
34A
35
36
36A
36B
37
37A
38
38A
39
40
41
42
42A
43
44
Elution
Temp.
118
119
120
121
123
124
125
126
128
128
130
130
131
131
132
133
134
135
135
136
136
138
139
140
140
141
142
143
144
145
146
147
148
148
149
150
151
152
153
155
156
156
157
158
Compound
C8H18 ls°iner
ii-hexanal
CnH., isomer
CgH^, isomer
ii-butyl acetate
ii-octane
tetrachloroethylene
furfural (tent.)
C9H2Q isomer
CqH-_ isomer
C.H... isomer
CgH. , isomer
chlorobenzene +
ethylcyclohexane
chlorobenzotrifluoride isomer
C,,H „ isomer
C.H- „ isomer
ethylbenzene
C.Hjg isomer
CqH.. isomer
xylene isomer
C.H-. isomer
C9H20 lsomer
styrene
CgHj. isomer
^-xylene
chlorobenzotrifluoride isomer
C9Hlg isomer
n-nonane
C.H1 . isomer
CgH isomer
isopropylbenzene
C10H22 is°mer
C9H16 + C9H18 isomers
C10H22 lsomer
propylcyclohexane
C _H2_ isomer
C10H16 isomer
chlorotoluene isomer
ii-propylbenzene
ethyltoluene isomer
1,3,5-trimethylbenzene +
C10H22 lsomer
C. _H-_ isomer
10 20
C10H22 lsomer
o-ethyl toluene
(continued)
109
-------
Table B6 (cont'd)
Chromato-
graphic
Peak No.
45
45A
46
47
47A
48
48A
48B
49
50
50A
51
51A
52
52A
53
53A
54
54A
55
56
57
57A
58
59
59A
60
61
61A
62
62A
63
64
64A
65
65A
65B
66
66A
66B
67
67A
68
Elution
Temp.
159
159
159
161
161
162
163
163
163
164
165
165
166
166
167
167
168
169
169
170
171
172
172
172
173
173
174
175
176
176
177
177
178
178
179
180
182
182
183
183
184
184
185
Compound
C10H20 + C10H18 lsomers
C, ,-H. , isomer
iU lo
C, .-.H-- isomer
1,2, 4-trimethylbenzene
C__Hon isomer
10 20
n-decane
dichlorobenzene isomer
CinHon isomer
10 20
C.-alkyl benzene isomer
C H isomer
C.-alkyl benzene isomer
1,2, 3-trimethylbenzene
C.-alkyl benzene isomer
C-..H-, isomer
11 24
dichlorobenzene isomer
C1QH16 isomer
C11H22 isomer
n-butylcyclohexane
C11H24 isomer
C.-alkvl benzene H-
4
C H isomers
C.-alkyl benzene isomer
C,-alkyl benzene isomer
chlorobenzochlorodifluoride
isomer
C,_H,., isomer
11 24
C.-H- . isomer
11 24
C.-alkyl benzene isomer
decahydronaphthalene (tent. )
C.-alkyl benzene isomer
C, -,^22 *somer
C.-alkyl benzene isomer
C,H_-benzene isomer
4 7
C--H,,- + C-jRyj isomers
C- -,Kyj isomer
C^-alkyl benzene isomer
ii-undecane
Cn_H_0 isomer
11 22
C,-alkyl benzene isomer
dichlorotoluene isomer
C H isomer
C11H20 ±SOiner
C ~H-,. isomer
C.-alkyl benzene isomer
C.-alkyl benzene +
C12H24 isomers
Chromato-
»raphic
>eak No.
69
70
70A
71
71A
71B
72
72A
73
73A
74
75
75A
76
77
77A
78
79
80
80A
808
80C
81
82
83
83A
84
84A
85
86
86A
87
88
88A
89
89A
90
91
91A
9 IB
9 1C
92
93
Elution
Temp.
186
186
187
187
188
188
188
189
189
190
190
191
192
193
194
195
196
198
199
201
202
203
204
205
206
206
208
209
209
211
211
213
214
215
216
215
221
223
225
227
230
232
235
Compound
C.-alkyl cyclohexane isomer
dichlorotoluene isomer
C,H-.-benzene isomer
4 7
C.-alkyl benzene isomer
C, -H~ .. isomer
12 26
C.-alkyl benzene isomer
C.-H-, isomer
12 26
C, «H. , isomer
12 24
C _H_, + C.-alkyl benzene
isomers
C,-alkyl benzene isomer
C11H18 lsomer (tent')
trichlorobenzene isomer
naphthalene
C10H16 isomer
n-dodecane
C.-alkyl benzene isomer
trichlorobenzene isomer
1 , 3-hexachlorobutadiene
sat. hydrocarbon
C12H24 lsomer
C13H28 isomer
C,-alkyl benzene isomer
sat. hydrocarbon
trichlorotoluene +
C, -H-. isomers
13 28
C,_H~n isomer
13 28
C,-alkyl benzene isomer
D
C..H_. isomer
J-J /D
n-tridecane +
B— methylnaphthalene
trichlorotoluene isomer
trichlorotoluene isomer
a-methylnaphthalene
C. ,H _ isomer (tent.)
tetrachlorobenzene isomer
trichlorotoluene isomer
Cn,H__ isomer
14 30
trichlorotoluene isomer
tetrachlorobenzene isomer
ii-tetradecane
C--alkyl naphthalene (traces)
C.-alkyl naphthalene isomer
C14H28 isomer
Cj,H isomer
tetrachlorotoluene isomer
(continued)
ifo
-------
Table B6 (cont'd)
Chromato-
graphic
Peak No.
9-
95
98
Elution
Temp.
(°C)
236
240
240
Compound
n-pentadecane
pentachlorobenzene
n-hexadecane
Chromato- Elution
graphic Temp .
Peak No. (°C)
99 240
100 240
Compound
ri-heptadecane
sat . hydrocarbon
See Table 8 for sampling protocol.
Ill
-------
ZII
Total Ion Current
•s
l-i
fD
W
r1 a
u> n
CO CO
(D ^
(D O
O
CD f-!
O
CO Hi
H-
Hi M
O 0)
H
O
>O Ki
2 <
rt O
O I-1
O (a
O rt
I-1 H-
O
i-t
00
O
I-!
CO
I
H-
(D
H-
t-i
H
O
3
-------
Table B7. VOLATILE ORGANIC VAPORS IDENTIFIED IN AIR FROM
HOUSEHOLD BASEMENT (L3), NIAGARA, NY3
Chroraato-
graphic
Peak No
1
1A
2
2A
2B
2C
2D
3
3A
j
-A
iB
iC
4D
3
6
7
7A
8
6A
SB
8C
9
9A
10
10A
11
11A
12
12A
I j
13A
14
14A
15
16
16A
17
17A
18
19
19A
20
21
22
Elution
Temp.
57
61
62
63
64
68
68
69
70
71
72
74
74
75
79
80
82
84
85
86
87
90
90
92
95
96
98
99
100
101
101
102
102
103
104
106
106
109
110
111
113
114
116
118
119
Compound
co2
C,H- isomer
acetaldehyde
C.Hg isomer
C H_ isomer
ethanol (tent.)
propenal
acetone
furan (traces)
ri-pentane + propanol (tent.)
C..H- isomer
5 o
methylene chloride
C.H,nO isomer
4 1U
CrH, isomer
J D
butenal isomer
2-methylpentane
methyl ethyl ketone
hexaf luorobenzene (eS)
n-hexane
ethyl acetate
C.H.- isomer
o LL
perf luorotoluene (el)
methylcyclopentane
1,1,1-trichloroethane (traces)
benzene
cyclohexane
2-methylhexane
2, 3-dimethylpentane
3-methylhexane
acetic acid
C,H , isomer
trichloroethylene (traces)
C.,H, , isomer
7 14
C?H1 ? isomer
n-heptane
C,H, . isomer
7 14
C7H1? isomer (traces)
methylcyclohexane +
4-methyl-2-pentanone
CHH , isomer
0 ID
CSH „ isomer
0 10
C_H . isomer
o ID
C?H12 isomer
toluene
C0H, „ isomer
8 18
C.H isomer
0 lo
iromato-
raphic
eak No.
23
23A
24
25
26
27
27A
28
29
30
30A
31
31A
31B
32
33
33A
34
34A
34B
35
36
37
37A
38
39
40
41
41A
42
42A
43
44
45
46
46A
47
47A
48
49
50
51
Elution
Temp.
<°C)
120
121
122
123
124
125
126
127
128
129
130
131
131
132
133
134
135
136
136
137
138
138
139
140
140
141
142
143
144
145
146
147
148
149
150
iso
151
151
152
152
154
155
Compound
CgH , isomer
1,2-dibromoethane (traces)
CRH1 , isomer
ji-butyl acetate
n-octane
tetrachloroethylene
CgH , isomer
Cqli-- isomer
C9H20 isomer
CgH.,,. isomer
C8H16 isomer
chlorobenzene +
ethylcyclohexane
C9H2- isomer
C_H „ isomer
C9Hlg isomer
ethylbenzene
C9H18 lsolner
xylene Isomer
C_H2(, isomer + phenylacetylene
CjH.,,0 isomer (tent.)
CnH_0 isomer
di-ri-butyl ether
styrene
CgHlg isomer
o-xylene
CgH.|8 isomer
C9H18 isomer
ri-nonane
C10H20 isomer
CgHjo isomer
isopropylbenzene
C10H22 isomer
C9H16 + C10H22 lsomer
C10H22 isolner
r,-alkyl cyclohexane
C10H22 isolner
benzaldehyde + C10H16
C10H22 isomer
chlorotoluene isomer
n-propylbenzene
ethyltoluene -f C. -H«-
C1QH22 isomer +
s
isomer
isomer
isomers
1, 3, 5-trimethylbenzene
52
52A
155
156
C,nH__ isomer
10 22
C10H20 isomer
(continued)
113
-------
Table B7 (cont'd)
Chromato-
graphic
Peak No.
52A
53
53A
53B
53C
54
54A
55
55A
55B
56
56A
56B
57
57A
58
59
60
60A
61
61A
61B
62
63
63A
64
65
65A
66
66A
67
67 A
67B
68
69
70
71
71A
71B
7 1C
72
Elution
Temp .
156
157
157
158
158
159
159
160
161
161
162
163
163
164
165
165
166
167
167
168
169
169
169
170
171
171
172
172
173
173
174
174
175
175
176
177
178
179
181
181
181
Compound
C.-alkyl benzene isomer
C10H22 lsomer
o-e thy 1 toluene
C -H-,. isomer
C H isomer
C10H16 is°mer
C-H. -benzene isomer
C10H20 isomer +
1, 2,4-trimethylbenzene
C -jH-^ isomer
dichlorobenzene isomer
(traces)
ri-decane
C, -alkyl benzene isomer
C H isomer
C10H16 +
C.-alkyl benzene isomers
1,2,3-trimethylbenzene
C.-alkyl benzene isomer
C11H24 isotner
C10H16 isomer
C11H22 isomer + indan (traces)
C,-alkyl cyclohexane isomer +
indene
C -alkyl benzene isomer
C^H.- isomer
C, -alkyl benzene isomer
C,-alkyl benzene isomer
C11H22 isomer
C11H24 isomer
C11H24 lsomer
C^-alkyl benzene isomer
C11H24 isomer
decalin or C,^H. _ isomer
1U .Lo
CUH24 lsomer
C.-alkyl benzene isomer
C H „ isomer
C.-alkyl benzene +
C,H_-benzene isomers
C11H22 isomer
C11H22 ^scraler
n-undecane
('11H22 •i-somer
C^-alkyl benzene isomer
dichlorotoluene isomer
C-_H_, isomer
I/ zb
Chromato-
graphic
Peak No.
72A
73
74
74A
75
75A
76
77
77 A
77B
77C
77D
78
79
80
80A
81
81A
82
83
83A
83B
84
84A
85
86
87
88
89
90
91
92
93
93A
94
95
96
97
98
Elution
Temp.
182
182
183
183
184
184
185
185
186
186
186
187
187
188
189
189
190
190
191
192
192
193
194
195
196
199
201
201
202
203
204
205
205
207
207
209
211
212
213
Compound
C.-alkyl benzene isomer
C 2H2, isomer
^11^20 ^somer
C^-alkyl benzene isomer
C.-alkyl benzene +
C12H24 isomers
C.Hq-benzene isomer (tent.)
C.-alkyl benzene isomer
C -alkyl cyclohexane isomer
C11H20 isomer
C.-alkyl benzene isomer
C ,H-,-benzene isomer
4 7
C^-alkyl benzene isomer
C12H°6 isomer
C -alkyl benzene isomer
C.-alkyl benzene +
C 2H2 isomers
C^-alkyl benzene isomer
(2-butoxyethoxy)ethanol isomer
trichlorobenzene isomer
(traces)
C12H24 isomer (tent.)
naphthalene
C10H16 lsomer
C -alkyl benzene isomer
ti-dodecane
C.-alkyl benzene isomer
benzothiazole (tent.) +
C13H28 isomer
C,-alkyl benzene +
C _H isomers (tent.)
C. oH-,. isomer
C, -alkyl cyclohexane isomer
o
C, -alkyl benzene isomer
o
C. o^o£ isomer
sat . hydrocarbon
C13H28 isomer
C14H30 ±somer
C13H24 isomer (tent.)
C13H26 isomer
6-methylnaphthalene +
n-tridecane
trichlorotoluene isomer
(traces)
ct-^methylnaphthalene
unsat. hydrocarbon
(continued)
114
-------
Table B7 (cont'd)
Chromato-
graphic
Peak So.
98A
99
99A
100
101
102
103
104
10 4 A
10-5
105
106
107
107A
IDS
109
110
110A
111
112
112A
112B
113
Elution
Temp . Compound
<°C)
214
215
215
"M ?
CIS
218
219
220
220
221
222
223
225
225
227
228
230
231
231
232
234
235
237
tetrachlorobenzene isomer
unknown
C14H28 isomer
C7-alkyl cyclohexane isomer
C14H30 isomer
sat. hydrocarbon
C14H30 isomer
biphenyl
C H_ isomer
tetrachlorobenzene isomer
C14H28 lsomer
ri-tetradecane
dimethylnaphthalene isomer
C14H28 isomer
C^-alkyl naphthalene isomer
CT CH_ . isomer
1 j z4
cisH32 + c2-alkyl
naphthalene isomers
C14H28 isomer
biphenylene
C,£H isomer
16 34
C15H30 isomer
C16H32 isomer
^i-pentadecane
Chromato-
graphic
Peak No.
113A
114
114A
115
116
116A
117
119
121
122
123
124
125
126
127
128
128A
129
131
132
Elution
Temp.
(°C)
238
239
240
240
240
240
240
240
240
240
240
240
240
240
240
240
240
240
240
240
Compound
C15H30 ±somel
Cj-alkyl naphthalene +
0^ ,^2 . isomers
C15H30 lsomer
Cj-alkyl naphthalene +
pentachlorobenzene (traces)
isomers
sat. hydrocarbon
<'16li32 isomer
C15H30 isolner
C16H32 isomer
ii-hexadecane
C16H32 isomer
unsat. hydrocarbon
CioH-io isomer
18 38
unsat. hydrocarbon
C16H32 lsomer
ji-heptadecane
C19H40 isomer
C_ _H_ . Isomer
ti-octadecane
sat. hydrocarbon
sat . hydrocarbon
for sampling protocol
-------
"9TT
Total Ion Current
era
e
o>
o o
H --
•a to
i-j ->>.
o n
rt O
8 S
o
O
J-h
TO
O
O
(D
O
H
OQ
("
3
H-
I
o
H
CO
I
PJ
l-h
H
O
3
ca
CO
(D
o
i
o3
ca
-------
Table B8. VOLATILE ORGANIC VAPORS IDENTIFIED IN AIR FROM
HOUSEHOLD BASEMENT (LI), NIAGARA, NYa
Chromato-
graphlc
Peak No.
1
3
3A
3B
4
4A
5
6
8
8A
9
10
10A
10B
IOC
11
12
13
14
14A
15
16
17
17A
18
18A
19
19A
19B
19C
19D
20
21
21A
2 IB
22
22A
22B
23
24
24A
25
26
26A
Elution
Temp.
57
61
61
62
62
63
64
67
70
71
71
73
73
74
75
76
78
79
80
81
81
82
83
83
84
84
85
85
86
86
87
88
89
89
90
90
92
92
93
93
94
95
96
97
Compound
co2
isobutane
acetaldehyde
C.Hg isomer
ii-butane
C.H. Isomer
4 8
methanol + methyl formate
(tent.)
ethanol
acetone
C.H 2 isomer
C,H0 isomer
J a
dichlorome thane
C.H,.. isomer
C4H10° isolner
C.H, isomer (tent.)
:> D
isobutyraldehyde
butenal isomer
2-methylpentane
ja-butanal
methyl vinyl ketone
methyl ethyl ketone +
3-methylpentane
C,H1 . isomer
hexafluorobenzene (el)
methylfuran isomer
n-hexane
ethyl acetate
chloroform
C,H . isomer
6 12
C6H10 is
-------
Table B8 (cont'd)
Chroma to-
graphic
Peak No.
50
50A
SOB
51
51A
52
53
53A
53B
54
55
55A
55B
56
56A
56B
57
58
59
59A
60
60A
61
61A
61B
62
62A
62B
62C
62D
62E
62F
63
64
65
65A
66
67
67A
68
68A
69
69A
Elution
Temp.
140
140
141
142
142
146
147
147
149
150
152
153
154
154
154
155
156
156
157
158
158
150
159
160
160
161
161
162
162
163
163
164
164
165
166
167
168
168
169
169
170
170
170
Compound
o-xylene
C,H..,0, isomer (tent)
/ ±D L
CgH „ isomer
n-nonane
CgH2Q isomer
isopropylbenzene + C..,H
isomer
C9H16 + C9H18 isomers
C10H22 isomer
C -alkyl cyclohexane isomer
C10H22 isomer
chlorotoluene isomer
ethyltoluene isomer
C10H22 isomer
1 , 3 , 5-t rime thy Ibenzene
C H isomer
C10H20 isomer '
C10H22 isomer
£-ethyltoluene
C10H20 1SOTOr
C__H- - isomer
C, .jH__ isomer
C-H.-benzene isomer
1 ,2 ,4-trimethy Ibenzene
C10H20 isomer
C11H22 is°mer
n-decane
dichlorobenzene isomer
C - nHo n is omer
C,-alkyl benzene isomer
C11H22 isomer
C.-alkyl benzene isomer
C11H24 isomer
C.-alkyl benzene isomer +
1,2,3-trimethylbenzene
C11H24 isomer
C10H16 isomer
CUH22 isomer
^12^26 ~*~ ^ ~alkyl cyclohexane
isomers
CnH22 isomer
C.-alkyl benzene isomer
C,-alkyl benzene isomer
C11H26 iSOmer
C -alkyl benzene isomer
4
C H isomer
Chroma to-
graphic
Peak No.
70
71
71A
72
72A
73
73A
73B
73C
74
75
75A
75B
76
76A
76B
76C
77
77A
78
79
79A
80
80A
81
82
83
84
84A
85
86
86A
86B
87
88
88A
88B
89
89A
89B
90
90A
Elution
Temp.
171
172
172
172
173
173
174
174
175
175
177
177
178
179
180
180
181
182
183
183
183
184
ISA
185
185
186
186
187
187
187
188
188
189
189
190
191
191
192
193
193
193
195
Compound
C11H24 ^Bcmer
Cn.H.. isomer
11 24
C.-alkyl benzene isomer
C11I*24 ^somer
C1QH18 isomer
^11H24 *somer
C.-alkyl benzene isomer
C.iHoj isomer
C4-alkyl benzene + C4H7-
benzene isomers
C12H26 isomer
C11H22 lsoner
C12H24 lsolLer
C.-alkyl benzene isomer
n-undecane
C11H22 isower
C.-alkyl benzene isomer
Cj_H2, isomer
dichlorotoluene isomer
C,.H2g isomer
^12^26 *somer
C.-alkyl benzene isomer
C..H, 00 ketone isomer (tent.)
I/ Xo
benzyl acetate
C12H24 isomer
C.-alkyl cyclobexane isomer
dichlorotoluene isomer
C^-alkyl benzene + C5-alkyl
benzene isomers
C12^26 isomer
C.-alkyl benzene isomer
Cj_H2, isomer
C12H26 isomer
C.-alkyl benzene isomer
C12H24 lsomer
C.-alkyl benzene isomer
trichlorobenzene isomer
methyl salicylate
naphthalene
C10H16 l801Der
C12H2A i800er
C.-alkyl benzene isomer
n-dodecane
trichlorobenzene + bromo-
chlorotoluene (traces)
isomers
(continued)
118
-------
Table B8 (cont'd)
Chromato-
graphic
Peak No.
91
91A
92
93
9i
9iA
95
96
98
99
:oo
100A
] OOB
101
102
102 A
103
104
105
106
Elution
Temp.
(°C)
196
196
197
198
200
201
201
202
203
205
206
207
208
20S
210
211
212
214
215
218
Compound
C -H_g isomer
C,-alkyl benzene isomer
6
C13H28 isomer
C.-H_, isomer
± J £V
C,-alkyl cyclohexane isomer
0
C. _H_, isomer
13 26
C13H28 isomer
sat. hydrocarbon
C13H28 isomer
C14H30 lsomer
C,-H_, isomer
13 26
C,,H, .0 isomer (tent.)
11 16
jj-tridecane + B-methyl-
naphthalene
trichlorotoluene isomer
trichlorotoluene isomer
a-methylnaphthalene
sat. hydrocarbon (tent.)
trichlorotoluene isomer
C14H30 iSOmer
alkyl butyrate
Chromato-
graphic
Peak No.
106A
107
107A
108
108A
109
109A
109B
109C
110
111
112
113
114
117
118
119
Elution
Temp.
<"C)
219
219
220
221
222
222
223
224
226
229
231
234
235
238
240
240
240
Compound
biphenyl
C14H30 I8omer
tetrachlorobenzene isomer
(traces)
chloronaphthalene isomer
(traces)
diphenyl ether (tent.)
ii-tetradecane
C14H28 lsomer
C«-alkyl naphthalene isomer
C«-alkyl naphthalene isomer
C14H28 ls°mer
sat . hydrocarbon
tetrachloro toluene isomer
ri-pentadecane
tetrachloro toluene isomer
n-hexadecane
sat . hydrocarbon
n-heptadecane
See Table 8 for sampling protocol.
119
-------
c
0)
I—•{ tOBOO-
cd
•u
o
H
11" I' I' I
1050
1100 USD IB 00
130') 13SO I tOO It 50 1500 1550
Mass Spectrum No.
Figure B5. GC/MS/COMP profile of volatile organic vapors in ambient air from L12A
(See Table 8 for protocol).
-------
Table B9. VOLATILE ORGANIC VAPORS IDENTIFIED IN AIR FROM
HOUSEHOLD BASEMENT (L12A), NIAGARA, NYa
Chromato-
graphic
Peak No.
1
2
2A
2B
3
4
5
5A
5B
6
6A
7
8
8A
9
9A
10
11
11A
11B
11C
12
12A
13
14
14A
15
16
Elution
Temp.
CO
57
62
68
68
69
71
73
81
83
84
85
86
89
90
94
96
98
100
102
104
109
115
117
119
123
134
135
139
Compound
co2
acetaldehyde
isopentane
propenal (tent)
acetone
n-pentane
methylene chloride
butanal (tent)
methyl ethyl ketone
hexaf luorob enzene (el)
ii-hexane
chloroform
perfluorotoluene (el)
methylcyclopentane
benzene
cyclohexane
acetic acid
pentanal
trichloroethylene
ii-heptane
C7H14 isomer
toluene
C8H18 lsomer
jv-hexanal
n-octane
ethylbenzene
xylene isomer
n-heptanal
Chroma to-
graphic
Peak No.
16A
17
18
ISA
18B
19
20
20A
21
21A
22
22A
23
23A
24
24A
24B
24C
24D
25
25A
26
27
28
29
29A
29B
Elution
Temp.
CO
140
143
150
153
154
155
158
159
161
168
169
170
175
177
179
182
185
189
190
191
193
207
208
215
221
233
234
Compound
»-xylene
n-nonane
benzaldehyde
C,-alkyl benzene isomer
phenol
C10H22 lsomer
n-octanal
C,-alkyl benzene isomer
C10H22 iBOaer
C11H24 i80ner
acetophenone
cresol isomer
n-nonanal
sat. hydrocarbon
e-caprolactone
C2-alkyl phenol isomer
C2-alkyl phenol isomer
Cj-alkyl phenol isomer
naphthalene
n-decanal
n-dodecane
n-undecanal
ji-tridecane + 8-methyl-
naphthalene
unsat. hydrocarbon (tent)
sat. hydrocarbon
unsat. hydrocarbon
sat. hydrocarbon
See Table 8 for sampling protocol.
121
-------
Table BIO.
VOLATILE ORGANIC VAPORS IDENTIFIED IN AMBIENT AIR
FROM LINDEN, NJ (P1/L3)3
Chroma to-
graphic
Peak No.
1
3
3A
4
5
6
6A
6B
7
7A
7B
8
10
10A
10B
11
12
12A
12B
13
14
14A
15
16
17
17A
17B
18
19
20
21
21A
21B
•) •)
£.£.
23
24A
24B
24C
25
26
27
27A
28
28A
29
Elution
Temp.
49
51
52
54
56
59
59
60
60
61
62
63
67
68
68
69
71
73
73
74
76
78
79
81
84
84
85
86
87
88
90
91
91
92
93
95
95
98
99
100
103
104
107
108
110
.,.
Compound
CO
2
propane (tent.)
C H isompr
^4n8 lsoD>er
acetaldehyde
ji-butane
isopentane
propenal
propanal
acetone
ri-pentane
C5H10 isoIDer
methylene chloride
C^,HgO isomer (tent.)
C4H60 aldehyde isomer
C H isomer
5 10
2-methylpentane
3-methylpentane
methyl ethyl ketone
hexafluorobenzene (el )
ii-hexane
2-butanol (tent.)
C8H18 lsonier +
perfluorotoluene (eS)
methylcyclopentane
C0Hno isomer
o IB
benzene
C-H,- isomer
carbon tetrachloride (tent.)
cyclohexane
2-methylhexane
2, 3-dimethylpentane
3-methylhexane
C-H isomer
o lo
trichloroethylene (tent.)
9 20 OTler
ti-heptane
C2-alkyl furan + alcohol (tent.)
C7H12 isomer (tent.)
methylcyclohexane
2-methyl-4-pentanone
C_H10 isomer
o 10
acetic acid
C8H16 isomer
toluene
C8H18 isolner
C-H., Isomer
ICnromato-
graphic
Peak No.
30
30A
31
32
33
34
35
35A
36
36A
37
38
38A
39
40
41
42
42A
43
43A
44
44A
44B
45
46
46A
46B
47
47A
47B
47C
48
48A
49
49A
50
51
51A
51B
52
52A
53
53A
Elution
Temp.
?
110
111
111
112
113
114
115
116
117
118
120
122
123
123
124
125
127
127
129
130
131
132
132
133
134
134
135
136
139
139
139
140
141
141
143
143
144
145
145
146
146
147
148
Compound
_
C0H , isomer
8 16
C,H._0 isomer
6 12
C_H, , Isomer
8 16
4-methyl-3-penten-2-one
C-H isomer
8 16
CoH-i-O alcohol isomer
o 10
.n-octane
C-H,, isomer
8 16
tetrachloroethylene
GO^I, isomer
8 16
C-H,- isomer
9 18
C-H-n isomer
9 20 """"=*
CnH, 0 isomer
9 18
ethylcyclohexane +
C9H20 lsomer
C9Hlg isomer
C-H - isomer
9 18
ethylbenzene
CftH. f. isomer
9 18
xylene isomer
C— H- — isomer
9 18
C0H-n isomer
9 20
C^Hj^O isomer
C,-H-- isomer
10 22
styrene
o-xylene
C-H-- isomer
9 20
C H isomer
9 18
n-nonane
C...H-- isomer
alcohol isomer (tent.)
C10H20 isomer
C10H22 isomer +
isopropylbenzene
C10H20 isomer
C_ -.H_- isomer
10 22
C_ x»H— isomer
10 20
CftH, - isomer
9 18
C,nH,, isomer
10 16
benzaldehyde
C.-H-- isomer
ii-propylbenzene
C,_H-n isomer
10 20
ethyltoluene Isomer
phenol
(continued)
122
-------
Table BIO (cont'd)
Chroma io-
Pesk No
55B
=,:.
54A
54B
;;
56
57
58
58A
59
59A
h '
60A
cl
61A
62
63
63A
63B
b-i
64A
65
65A
66
67
68
68A
69
70
70A
71
71A
72
72A .
73
73A
74
74A
74B
74C
Elution
Temp.
("Q
14S
149
150
150
151
151
152
153
154
155
156
156
157
• 158
156
159
160
161
161
162
162
163
163
164
165
166
167
167
168
169
169
170
171
171
172
173
173
174
175
175
Compound
C.-H,,,, isomer +
1,3, 5- trimethylbenzene
C11H24 isomer
C10H22 isomer
o-e thy 1 toluene
C11H24 isomer
C11H24 is0mer
C10H16 iSOmer
1,2, 4- trimethylbenzene
Chromato-
graphic
Peak No.
74B
74C
75
75A
76
76A
76B
77
78
C10H20 iSOm"
n-decane
dichlorobenzene isomer (trace)
C,,H,, isomer
11 24
CH22 isomer
C,,H0, isomer
11 24
C^-alkyl benzene isomer
1,2,3-trimethylbenzene +
C11H24 isomer
C H^, isomer
C10H16 Is0mer
C H -benzene isomer
C -alkyl cyclohexane isomer
C11H22 isomer
11 24 4
isomers
C.-alkyl benzene isomer
acetophenone + C^-alkyl
benzene isomer
cresol isomer
C.-alkyl benzene +
C11H24 isomers
C10H18 + C12H24 isomers
C11H24 isomer
C.-alkyl benzene isomer
CUH22 isomer
C.-alkyl benzene isomer
C12H22 isomer
C, -H, , isomer
C11H22 lsomer
n-undecane
C,,H_. + C.-alkyl benzene
il 22 **
isomers
C13H24 isomer
C12H24 isomer
C2-alkyl phenol isomer
C10H18 isomer (tent>)
79
79A
80
80A
81
81A
81B
82
82A
83
83A
84
84A
85
86
87
89
90
90A
91
92
93
94A
95
96
98
99
99A
100
100A
101
102
102A
102B
103
Elution
Temp.
175
175
175
176
177
178
179
180
182
184
184
185
186
186
187
188
188
189
190
191
192
193
194
195
196
198
200
202
202
203
206
209
211
212
213
217
219
219
221
222
226
228
229
230
Compound
C.-alkyl phenol isomer
C10H18 ie°mer (tent')
C.-alkyl benzene isomer
C, -H,, Isomer
13 26
dimethylphenol isomer
C13H26 isomer
C11H22 isomer
C--alkyl phenol isomer
dimethylphenol +
unsat. hydrocarbon isomers
C12H2, isomer
C.-alkyl benzene isomer
C,-alkyl phenol isomer
C, ,H_, isomer
13 26
naphthalene
C12H24 isomer
Ce-alkyl benzene isomer
n-dodecane
C13H26 ls°mer
C,-alkyl phenol isomer
C,,H.D isomer
J. J 4.O
C.-alkyl phenol isomer
C14H26 is°m"
C14H28 is°mer
C,,H,, isomer
13 26
C14H28 lsol"er
C13H28 lsomer
C14H30 iSOBer
Cj-H-, isomer
C14H28 is°mer
6-methylnaphthalene +
n-tridecane
a-methylnaphthalene
C.-alkyl phenol isomer (tent.)
C13H26 + C14H30 isomers
C, ,H-_ isomer (tent.)
14 30
alkyl butyrate (BKG)
ti-i .tradecane
C--alkyl naphthalene isomer
C15H32 isomer
C2-alkyl naphthalene isomer
C^H,- isomer (tent.)
C16H34 isomer
C, .H-. isomer
C15H30 isomer
n-pentadecane
(continued)
123
-------
Table BIO (cont'd)
Chronato-
graphic
Peak No.
104
104A
106A
106B
Elutlon
Temp.
232
236
240
240
Compound
unknown
C,-alkyl naphthalene Isomer
C16H34 iSOTer
C, ,H_, isomer
17 36
Chromato-
graphlc
Peak No.
106C
107
108
109
Elutlon
Temp.
240
240
240
240
Compound
CI,H.« isomer
sat. hydrocarbon
n-heptadecane
sat. hydrocarbon
See Table 10 for sampling protocol.
124
-------
Table Bll. VOLATILE ORGANICS IDENTIFIED IN AMBIENT AIR
FROM AMHERST, NY (P1/L3)
Chromato-
graphic
Peak No.
1
2A
2B
3A
4
4A
5
5A
5B
5C
6
6A
7
8
9
9A
10
11
11A
11B
11C
12
12A
12B
13
14
14A
14B
15
ISA
15B
16
17
17A
18
18A
19A
19B
20
20A
2 OB
20C
20D
21
22
23
Elution
Temp.
58
63
70
71
72
72
lit
76
78
80
81
83
83
85
86
86
88
90
91
91
92
95
96
97
98
99
101
102
104
109
110
116
118
119
124
125
131
134
136
136
137
139
140
141
143
146
Compound
co2
acetaldehyde
isopentane
propenal + propanal (tent.)
acetone
n-pentane
methylene chloride
C_H, , isomer
7 16
C,HgO isomer
cyclopentane
2-methylpentane
n-butanal
3-methylpentane
hexafluorobenzene (eS)
n-hexane
chloroform
C,H,rt isomer (tent.)
D 1U
per fluoro toluene (eS)
C^H., isomer
methylcyclopentane
1,1, 1-trichloroethane
benzene
carbon tetrachloride
cyclohexane
2-methylhexane
3-methylhexane
pentanal (tent.)
C..H- , isomer
7 14
n-heptane
methylcyclohexane
CRH1fi isomer
o J-O
toluene
acetic acid
CRHlfl isomer
0 Lo
n-octane
tetrachloroethylene
CgH20 isomer (tent.)
ethylbenzene
xylene isomer
C9H20 isomer
sat. hydrocarbon
styrene (traces)
heptanal (tent.)
o-xylene
n-nonane
C.-.H22 isomer
Chroma to-
graphic
Peak No.
24
25
25A
26
26A
27
27 A
27B
28
28A
29
29A
30
31
31A
32
33
33A
33B
34
34A
35
35A
36
37
38
39
39A
40
40A
41
41A
42
44
45
45A
46
47
48
49
49A
50
51
51A
Elution
Temp.
149
152
152
153
153
155
156
157
158
159
161
162
165
169
169
170
172
173
175
176
177
178
181
183
186
187
190
191
192
193
193
195
198
206
207
208
210
218
220
221
234
235
240
240
Compound
sat. hydrocarbon (tent.)
benzaldehyde
n-propylbenzene
ethyltoluene isomer
C10H22 isomer
C11H24 isomer
phenol
C....H,. isomer
11 24
ii-octanal
1,2,4-trimethylbenzene
ii-decane
dichlorobenzene isomer
(traces)
C11H24 isolner
C11H24 isomer
C, -alkyl benzene isomer
acetophenone
cresol isomer
sat. hydrocarbon
C, -alkyl benzene isomer
n-nonanal
cresol isomer
n-undecane
C_-alkyl phenol isomer
C2-alkyl phenol isomer
C.-alkyl phenol isomer
C--alkyl phenol isomer
C -alkyl phenol isomer
naphthalene
ti-decanal
Cj-alkyl phenol isomer
n-dodecane
C -alkyl phenol isomer
alcohol unknown
undecanal (tent.)
ii-tridecane
6 lethylnaphthalene
methylethyldioxolane (tent.)
alkyl butyrate
C14H28 lsomer
n-tetradecane
C. rH_~ isoraer
n-pentadecane
diethyl phthalate
C-,£H isomer
16 32
(continued)
125
-------
Table Bll (cont'd)
Chromato-
graphic
Peak No.
53
Elution
Temp . Compound
(°C)
240 n-hexadecane
Chronato-
graphic
Peak No.
53A
53B
Elution
Temp.
(°C)
240
240
Compound
alkyl alcohol
sat. hydrocarbon
126
-------
Table B12. VOLATILE ORGANICS IDENTIFIED IN AMBIENT AIR FROM
BUFFALO, NY (P2/L10)
Chromato-
graphic
Peak No.
1
2
2A
2B
2C
2D
3
3A
4
4A
4B
5
6
6A
6B
6C
7
7A
8
8A
8B
9
9A
10
IDA
10B
11
11 A
12
12A
13
13A
14
15
15A
16
16A
16B
17
17A
17B
18
19
20
21
Elutlon
Temp.
58
62
62
67
68
68
69
69
70
71
72
73
74
75
78
78
79
80
81
82
82
83
83
84
84
87
88
89
90
93
93
95
96
97
98
100
100
101
102
104
107
114
115
117
118
Compound
co2
acetaldehyde + C.Hg isomer
C.H.,. isomer
isopentane
propenal (tent.)
propanal (tent.)
acetone
furan
ii-pentane
C.H0 isomer (traces)
J O
C_H1(, isomer
methylene chloride
cs2
CrH, isomer
5 6
2-methylpropenal or
C.H.O isomer
4 6
cyclopentane
2-methylpentane
butanal
3-methylpentane
methyl ethyl ketone
C,H10 isomer
o 1^
hexafluorobenzene (e§)
2-methylf uran
n-hexane
chloroform
C,H, - isomer
perf luorotoluene (eS)
methylcyclopentane
1,1,1-trichloroethane
C.-H. « isomer
benzene
cyclohexane
2— methylhexane
C.H _0 isomer
n-pentanal
C.,H, , isomer
7 14
trichloroethylene (traces)
C_H-2 isomer
n-heptane
C-H, . isomer
7 14
methylcyclohexane
acetic acid
toluene
CsHia isomer
O lo
C_Hn „ isomer
o J.O
Chromato-
graphlc
Peak No.
22
23
23A
24
24A
24B
25
25A
25B
26
26A
27
27 A
28
28A
29
30
30A
31
32
32A
33
33A
34
34A
35
36
36A
37
38
39
39A
40
40A
40B
41
41A
42
42A
43
43A
43B
44
45
Elutlon
Temp.
119
121
122
123
124
125
127
130
131
134
135
136
136
138
138
139
140
142
143
145
146
146
147
148
149
149
151
152
153
154
155
155
156
157
158
j.58
159
159
160
161
162
165
165
166
Compound
n-hexanal
^8H16 lsomer
CgH., isomer
n-octane
tetrachloroethylene
C8H16 lsolner
furfural
CgH , isomer
C,H,.0 isomer (tent.)
O Li.
ethylbenzene
unsat. hydrocarbon
xylene isomer
C9H20 lsomer
C.,H, , 0 isomer
7 14
CqH, _ isomer
styrene
N .N-dimethylacetamide
CgH1 ,. isomer
n-nonane
C_Hjo isomer
isopropylbenzene
C1_H_,? isomer
C, -H, „ isomer (tent.)
10 18
C10H22 lsomer
C -alkyl cyclohexane isomer
C^,H?, isomer
C-0H2- isomer + benzaldehyde
n-propylbenzene
ethyltoluene
C10H22 isomer +
1,3,5-trimethylbenzene
C1QH22 isomer
phenol + C1f.H«n isomer
o— ethyltoluene
C10H20 lsomer
C- -H, o isomer
n-octanal
methylstyrene + CinH20 isomers
1,2 ,4-trimethylbenzene
C10H20 is°mer
n-decane
C10H20 isomer
C,-alkyl benzene isomer
(traces)
1,2, 3-trimethylbenzene
C,,H. , + C-H..-benzene isomers
11 24 35
(continued)
127
-------
Table B12 (cont'd)
Chromato-
graphic
Peak No .
45A
46
46A
46B
47
47A
47B
47C
48
48A
49
49A
49B
50
50A
51
51A
51B
52
52A
53
53A
53B
54
55
55A
56
56A
57
57A
58
58A
59
Elution
Temp.
(°C)
167
168
168
169
170
171
171
172
172
173
174
174
175
176
177
178
179
181
181
182
183
184
185
185
187
188
188
189
189
190
190
191
191
Compound
indan
C -alkyl cyclohexane isomer
indene
C.-alkyl benzene isomer
acetophenone +
C, -alkyl benzene isomer
C11H22 isomer
C, ,H_, isomer
11 Z4
cresol isomer
C11H24 isomer
C10H18 isomer (tent-)
C11H24 isomer
C . -alkyl benzene isomer
C, -alkyl benzene isomer
n— nonanal
C11H22 isomer
n-undecane
C11H22 lsomer
C,-alkyl benzene isomer
C, 0H_ , isomer
L2. £D
CH20 isomer (tent.)
C.-alkyl phenol isomer
C,H-,-benzene isomer
4 7
C, -alkyl benzene isomer
(traces)
C11H22 lsomer
C -alkyl phenol +
C -alkyl benzene isomer
C--alkyl phenol isomer
C,,,H,,, isomer
12 26
C12H24 1SOmer
C.-alkyl benzene isomer +
sat. hydrocarbon (tent.)
C10H20° 1S°mer
C,-alkyl phenol isomer
C.-alkyl phenol isomer (tent.)
naphthalene
Chromato-
;raphic
Peak No.
60
60A
61
61A
62
62A
62B
63
64
64A
65
65A
66
67
67A
68
68A
69
69A
69B
70
71
72
72A
73
73A
74
74A
76
77
77A
78
79
80
Elution
Temp.
(°C)
192
193
194
195
196
201
202
203
205
206
208
209
211
216
217
220
221
222
224
226
227
230
231
232
235
240
240
240
240
240
240
240
240
240
Compound
n-decanal
C10H20 isomer
n-dodecane
Cr-alkyl benzene isomer
C13H2g isomer
C12H24 isomer
C13H28 *somer
C13H28 isomer
sat . hydrocarbon
C13H26 isomer
n-tridecane
B-methylnaphthalene
a-methylnaphthalene
C13H26 isomer
C14H30 isomer
biphenyl + C. ,!!,„ isomer
C14H28 isomer
n-tetradecane
C--alkyl naphthalene isomer
C,-alkyl naphthalene isomer
unsat. hydrocarbon
C14H28 lsomer
C15H32 isomer
unsat. hydrocarbon
n-pentadecane
C15H30 lsom"
diethyl phthalate
C16H32 isomer
n-hexadecane
C18H38 isomer
C16ti32 isomer
n-heptadecane
sat. hydrocarbon
ii-octadecane
128
-------
Table B13. VOLATILE ORGANICS IDENTIFIED IN AMBIENT AIR FROM
NIAGARA FALLS, NY (P1/L2)
Chroma to-
graphic
Peak No.
1
i
3
3A
3B
4
5
5 A
53
6
6A
62
6C
fcL
7
/ A
8
8A
9
10
11
11A
12
12A
12B
13
13B
14
15
15A
16
17
18
ISA
19
20
21
22
23
24
24A
24B
24C
25
26
Elution
Temp.
58
61
62
67
68
69
70
70
71
7 ~)
77
7-
77
78
79
80
81
81
82
83
84
87
88
89
90
93
a/.
7H
95
96
97
99
100
102
104
107
109
113
115
116
118
119
121
121
123
123
124
Compound
co2
chloromethane (tent.) (traces)
acetaldehyde
isopentane
propenal (tent. )
acetone
n-pentane
C,H,nO isomer (tent.)
4 10
C(.H, n isomer
methylene chloride
so2
2 , 2-dimethylbutane
C,H,0 aldehyde isomer
cyclopentane
2-methylpentane
butanal
3-methylpentane
methyl ethyl ketone
hexafluorobenzene (eS)
n-hexane
chloroform
C,H. „ isoraer
• o Li.
perfluoro toluene (ef)
methylcyclopentane
1, 1,1-trichloroethane
benzene
cyclohexane
2-methylhexane
3-methylhexane
unsat . hydrocarbon
trichloroethylene
n-heptane
alcohol (tent. )
methylcyc lohexane
CRH p isomer
0 J.O
acetic acid
toluene
CRH1R isomer
O J-O
C8H18 isomer
n-hexanal
C0H, , isomer
8 16
C,H. _0 isomer
o 1Z
C_H,, isomer
o lo
n-octane
tetrachloroethylene
Chromato-
graphic
Peak No.
27 A
28
29
29A
30
30A
31
32
33
33A
34
34A
35
36
37
38
38A
39
40
41
42
42A
42B
43
44
45
46
47
47A
48
48A
49
49A
49B
50
50A
51
51A
52
53
54
55
55A
Elution
Temp.
129
130
134
135
136
136
137
140
141
142
143
146
147
149
150
151
152
153
155
156
157
157
157
158
159
160
161
162
165
165
166
167
169
170
170
171
172
173
174
175
176
179
181
Compound
CqH~n isomer
chlorobenzene
ethylbenzene
CgH1 R isomer
xylene isomer
CqH-- isomer
C9H20 lsomer
styrene + n-heptanal
<>-xylene
CgH „ isomer
n-nonane
C1f.H«. isomer
C10H22 isomer +
isopropylbenzene
alcohol or unknown
C10H22 isomer
benzaldehyde
n-propylbenzene
ethyltoluene isomer
1,3, 5-trimethylbenzene +
C10H22 isomer
C11H24 isomer
phenol
C -H-, isomer
o-ethyltoluene
C11H24 isomer
n— octanal
1,2, 4-trimethylbenzene
ti-decane
dichlorobenzene isomer
C11H24 lsomer
1,2,3-trimethylbenzene
unknown
dichlorobenzene isomer
C,-alkyl benzene isomer
C,-alkyl benzene isomer
acetophenone
C,-alkyl benzene isomer
cresol isomer
C11H24 isomer
C,-alkyl benzene isomer
C,-alkyl benzene isomer
n-nonanal
n-undecane
C,-alkyl benzene isomer
(continued)
129
-------
Table B13 (cont'd)
Chrotnato-
graphic
Peak No.
56
57
57A
58
59
60
60A
60B
60C
61
61A
62
63
63A
64
65
66
67
68
69
Elution
Temp.
182
184
186
187
189
191
191
192
193
193
194
195
196
197
199
201
204
206
208
209
Compound
C, -alkyl benzene + ethylphenol
isomers
dimethylphenol isomer
C, -alkyl benzene isomer
C.-alkyl phenol isomer
C.-alkyl phenol isomer
trichlorobenzene isomer
C -alkyl phenol isomer
C.-alkyl phenol isomer (tent.)
naphthalene
ri-decanal
C12H24 isomer
n-dodecane
C -alkyl phenol +
trichlorobenzene
C.-alkyl phenol isomer
alcohol (tent. )
alcohol (tent. )
unsat. hydrocarbon (tent.)
C11H22° isomer (tent-)
unknown
n-tridecane +
3-methylnaphthalene
Chromato-
graphic
Peak No.
70
70A
71
72
72A
72B
73
74
74A
74B
74C
75
76
77
7BA
79
79A
BO
81
Elution
Temp.
212
212
217
219
220
220
221
223
225
227
234
236
239
240
240
240
240
240
240
Compound
methylethyldioxolane isomer
or unknown
ct-methylnaphthalene
C14H30 lsomer
alkyl butyrate (tent.)
biphenyl (traces)
tetrachlorobenzene isomer
(traces)
C, -alkyl phenol isomer
n-tetradecane
C_-alkyl naphthalene isomer
C^-alkyl naphthalene (tent.)
C. e^on isomer
n-pentadecane
unknown
diethyl phthalate
ja-hexadecane
Cp-alkyl phenol isomer
tributyl phosphate
C1?H36 isomer
alcohol or unknown
130
-------
Table B14. VOLATILE ORGANICS IDENTIFIED IN AMBIENT AIR FROM
NIAGARA FALLS, NY (P3/L5)
Chroma to-
graphic
Peak No.
,
2
3A
4
4A
5
6
6A
6B
6C
6D
6E
6F
6G
7
8
9
10
11
11A
11B
lie
12
12A
12B
12C
12D
12E
13
13A
!l
15
16
17
18
18A
19
19A
20
21
21A
2 IB
22
22A
23
24
Elution
Temp.
58
62
67
69
69
70
72
76
77
78
79
79
80
80
81
82
83
83
87
88
89
92
94
95
97
99
101
102
104
107
107
110
114
116
117
118
119
120
123
124
129
130
130
131
134
136
Compound
co2
acetaldehyde
isopentane
acetone
n-pentane
isopropanol
methylene chloride
C,H,0 isomer
4 6
cyclopentane
2-methylpentane
vinyl acetate (tent.)
butanal
methyl vinyl ketone
3-methylpentane
methyl ethyl ketone
hexafluorobenzene (eS)
n-hexane
chloroform 4- ethyl acetate
perf luorotoluene (eS)
methylcyclopentane
1 , 1 , 1-trichloroethane
benzene
1-butanol
C.H., isomer
. C-H.., isomer
trichloroethylene
n-heptane
alcohol (tent.)
alcohol (tent.)
C7H14 isomer
4-methyl-2-pentanone
acetic acid
toluene
CftH1 o isomer
CRH1R isomer
CgH16 isomer (tent.)
n-hexanal
CaH , isomer
o -Lo
n-octane
tetrachloroethylene
CgHjg isomer
ethylcyclohexane
CQH,,« isomer
CQH, o isomer
ethylbenzene
xylene isomer
hromato-
;raphic
>eak No.
25
26
27
27A
28
29
30
30A
31
32
33
33A
33B
33C
33D'
34
35
36
36A
37
37A
37B
38
38A
39
39A
39B
40
41
42
43
43A
43B
44
45
45A
46
46A
47
47A
48
49
50
51
Elution
Temp.
("C>
141
143
147
148
150
151
152
153
156
159
161
162
165
166
167
168
170
171
172
173
174
175
176
177
178
178
181
183
184
187
189
191
192
193
194
198
199
202
209
209
211
217
219
222
Compound
£-xylene
n-nonane
isopropy Iben zene
C10H22 i80Iner
C1()H22 isomer
benzaldehyde
ri-propylbenzene
ethyltoluene isomer
phenol
C -alkyl benzene isomer
n-decane
dichlorobenzene isomer
(traces)
C,-alkyl benzene isomer
C11H24 isomer
C10H16 lsomer
cresol isomer
C10H18 * C4~alkyl benzene
isomer s
acetophenone
cresol isomer
phenyl allyl ether (tent.)
C -alkyl benzene isomer
C,-alkyl benzene isomer
n-nonanal
C_-alkyl phenol isomer
n-undecane
methylbenzofuran isomer
C--alkyl phenol isomer
C--alkyl phenol isomer
unknown
C_-alkyl phenol isomer
C--alkyl phenol isomer
C,-alkyl phenol isomer
naphthalene
n-decanal
n-dodecane
C, -alkyl phenol isomer
unknown
C -alkyl phenol isomer
n-tridecane
B-methylnaphthalene
unknown + a-methylnaphthalene
alkyl butyrate (tent.)
alkyl butyrate
diphenyl ether + n-tetradecane
(continued)
131
-------
Table B14 (cont'd)
Chrornato-
graphic
Peak No.
52
53
54
Elution
Temp .
CO
236
239
240
Compound
n-pentadecane
unknown
diethyl phthalate
Chromato-
graphic
Peak No.
55A
55B
Elution
Temp . Compound
(°c;
240 alkyl phenol
240 C18H3g ieomer
132
-------
Table B15. VOLATILE ORGANICS IDENTIFIED IN AMBIENT AIR FROM
AMHERST, NY (P4/L12)
Chromato-
graphic
Peak No.
i_
2
2A
2B
2C
2D
3
3A
4
5
5A
5B
5C
6
6A
7
7A
8
9
9A
9B
10
IDA
10B
11
11A
12
12A
13
13A
13B
14
15
ISA
16
17
18
19
20
21
21A
22
22A
23
23A
24
Elution
Temp.
58
62
62
67
67
68
68
68
69
71
73
76
77
78
79
80
81
82
83
83
86
87
87
89
92
94
95
96
96
97
98
99
101
106
108
111
113
115
117
118
118
124
130
133
134
135
Compound
co2
acetaldehyde
C4H10 1SOmer
isopentane
propenal
propanal
acetone
furan (traces)
n-pentane
methylene chloride
C.H,. isomer
6 14
methylpropenal or C,H,0 isomer
cyclopentane
2-methylpentane
butanal
3-me thylpentane
methyl ethyl ketone
hexaf luorobenzene (eS)
n-hexane
chloroform
C.H.j isomer
perfluorotoluene (eS)
methylcyclopentane
1,1, 1-trichloroethane
benzene
cyclohexane
2-methylhexane
C H 0 isomer (tent.)
3-methylhexane
n-pentanal
C-H. , isomer
trichloroethylene
n-heptane
methylcyclohexane
CgHlg isomer
acetic acid
toluene
Cffl.,, isomer
o 1O
CftH, - isomer
n-hexanal
C0H,, isomer
o ID
tetrachloroethylene
C0H., isomer (tent.)
o ID
ethylbenzene
C-H1 _ isomer
xylene isomer
Chroma to-
graphic
Peak No.
24A
25
26
27
27A
28
28A
29
30
31
32
33
34
34A
34B
35
35A
36
36A
37
37A
38
39
39A
39B
40
41
41A
42
42A
43
44
44A
45
46
47
47A
48
48A
49
50
51
52
Elution
Temp.
135
136
138
139
140
141
143
145
147
148
149
151
152
153
153
153
154
155
155
157
157
158
160
161
163
163
164
165
166
167
168
169
169
170
j.71
172
173
174
175
177
180
181
185
Compound
C_H?ri isomer
CgH20 isomer
styrene
o-xylene
C-H-n isomer
n-nonane
CgH.g isomer
C10H22 isomer +
isopropy Ibenzene
C,,.H_,j isomer + unknown
C10H22 iS°mer
benzaldehyde
n-propy Ibenzene
ethyltoluene isomer
benzonitrile
1,3, 5-trimethy Ibenzene
C10H22 isomer
phenol
C.-H,,,, isomer
o-ethyltoluene
n-octanal
C10H2Q isomer
1, 2, 4-trimethy Ibenzene
ri-decane
dichlorobenzene isomer
C.-alkyl benzene isomer
1,2, 3-trimethy Ibenzene +
C11H24 isomer
C11H24 isomer
C-H.-benzene + ci iH24 isolners
C1 rfijn isomer
<'11H22 isomer
C.-alkyl benzene isomer
acetophenone
C.-alkyl benzene isomer
cresol + ciiH24 isomers
indan + C,.H2. isomer
C,-alkyl benzene +
sat . hydrocarbon
C.-alkyl benzene isomer
n-nonanal
C11H__ isomer
n-undecane
C.-alkyl benzene isomer
C.-alkyl phenol isomer
C.-alkyl phenol isomer
(continued)
133
-------
Table B15 (cont'd)
Cr.ro~£to-
^rapnic
53
5-
5-A
55
56
5~
55
59
59A
60
60A
61
Eiution
Tercp .
166
189
190
191
192
195
197
198
206
207
:os
210
Compound
r -alkyl phenol isomer
C -alkyl phenol isomer
naphthalene
n-decanal
n-dodecane
Cj-alkyl phenol +
C ,H28 isomers
unknown
sat. hydrocarbon
C H , isomer
n-tridecane
6-methylnaphthalene
a-methylnaphthalene
^hromato-
jraphic
Peak No.
62
63
64
64A
64B
65
66
67
63A
68B
Elution
Temp.
216
217
221
230
233
234
236
240
240
240
Compound
alkyl butyrate
alkyl butyrate
n-tetradecane
C.gH32 isomer
C15H30 isomer
n-pentadecane
unknown
diethyl phthalate
n-hn:,adecane
C, -$")* isomer
134
-------
APPENDIX C
MAPS DEPICTING SAMPLING SITES AND LOCATIONS
THROUGHOUT CONTINENTAL U.S.
135
-------
CO
YORK
HILADELPHIA
BALTIMORE
WASHINGTON
^JACKSONVILLE
Figure Cl. Map of Continental U. S. depicting EPA regional territories. Circles indicate
geographical areas sampled by RTI under EPA contracts.
-------
EPA REGION IX
137
-------
'AN FRANCISCO
CALIFORNIA
rV-. •GLENDORA
/-^•WEST COVINA
EL SEGUNDO*-JDOMINQUE>UPI-ANO
TORRANCEV* CANAHEIM
LONGBEBCH .• GARDEN GROVE
SAN DIEGO
|"= 65 mites
Figure C2. Map of California. Solid circles indicate cites sampled.
138
-------
LOS ANGELES AND VICINITY
i
v-sr—
UPLAND
Figure C3. Map of Los Angeles, CA, arid vicinity
-------
01234
MILES
Figure G4. Map depicting sampling locations (x) in Los Angeles, CA, and vicinity
-------
0 1/4 1/2
I 1 h-
MILES
Figure C5.. Map depicting sampling locations in Los Angeles, CA.
-------
EPA REGION VIII
142
-------
co
ROCKY MTN.
I NATIONAL PARK
EISENHOWER
COLORADO
NEWMEXICO
I =65 miles
Figure G6. Map of "Four Corner" States. Solid circles indicate sampling sites.
-------
TULSA •
OKLAHOMA
I"= 112 miles
Figure C7. Texas and Oklahoma maps. Solid circles indicate sites sampled.
-------
HOUSTON + VICINITY
N
I =4.1 miles
Figure C8. Perspective map of Houston, TX, add vicinity
-------
Kay Street
Stuebner Airline
Shaw Drive
Texas City
7200 Bayway Drive
To Texas City
I
HOUSTON
AND VICINITY
o ! ? * 1 3
rate * mHm
Figure C9. Map of Houston, Texas and vicinity depicting sampling locations (A-E).
-------
Figure CIO. Sampling locations at Pasadena, TX, site.
147
-------
oo
Figure Cll. Sampling site in Freeport, TX (Dow 'A').
-------
EPA REGION VI
149 '
-------
\
OKANSAS
CITY
ST ANN*
WEBSTER GROVES
• ALTON
^•WOOD RIVER
1ST. LOUIS
MISSOURI
L
I = 65 miles
ARKANSAS
LITTLE ROCK
O
• MAGNOLIA
•EL DORADO
LOUISIANA
k* BATON ROUGE.
PLAOUEMINE*\
__.,
VEW ORLEANS
Figure C12. Map depicting south/central states. Solid circles
represent cities sampled.
150
-------
INDUSTRIAL
COMPLEX L K>«
Figure C13. Map depicting locations of ambient air sampling network
in Iberville Parish, LA.
151
-------
Figure C14. Sampling site and locations in Geismar, LA, area.
M = Borden Chemical Co., N = Monochem, Inc., 0 =
Uniroyal Inc., P - Rubicon Chemical, Inc., Q « BASF
Wyandotte Chemical Corp., R a Shell Chemical Co.,
S * Vulcan Materials, Inc.
152
-------
Figure C15. Sampling site and locations in Baton Rouge, LA area.
153
-------
EPA REGION VII
154
-------
GREATER ST LOUIS + VICINITY
Figure C16. Sampling sites in St. Louis and vicinity.
155
-------
EPA REGION IV
156
-------
UT
-•J
' BIRMINGHAM
ALABAMA
MOBIL
SOUTH CAROLINA
FLORIDA
" = 35 miles
Figure G17. Sampling sites in Southern states (solid circles)
-------
00
(RTP) RESEARCH TRIANGLE
• PARK
• RALEIGH
l"= 16 miles
Figure CIS. Sampling sites visited in North Carolina (solid circles)
-------
EPA REGION III
159
-------
OHIO
O
KENTUCKY
PENNSYLVANIA
l"= 35 miles
Figure C19. Sampling sites in West Virginia, Virginia and Maryland (solid circles)
-------
Figure C20. Perspective map of the Kanawha Valley in West Virginia.
161
-------
re
Figure C21. The Kanawha River Valley, West Virginia.
-------
Figure C22. Map of area around Nitro, WV, showing sampling locations.
163
-------
ON
Figure C23. Map of area around St. Albans and Institute, WV, showing sampling locations.
-------
CHARLESTON
Ui
Figure C24. Map of area around Charleston and South Charleston, WV, showing sampling locations
-------
CHESAPEAKE
Figure C25. Map of area around W. Belle, WV, showing sampling locations.
166
-------
r I
j PARKING LOT \
•OLD US ROUTE GO
«]' 0*
• HMiyl omhu • «m 60S' 0*
• DlmM^I lotmo«.l« MI* 75J' 0"
f
BARGE tOADING
KANAWHA RIVER
BARGE WADING
Figure C26. Plant map of DuPont in Belle, WV, depicting sampling locations.
-------
00
00
c
(0
o
M
§
-------
EAST BROOKLYN,
BALTIMORE, MARYLAND
CHESSIE
COAL PIERS
CURTIS BAY
SCALE: ONE INCH =0.5 miles
Figure C28. Map of sampling site in East Brooklyn, Baltimore, Maryland.
169
-------
STONEHOUSE COVE
•JlhPcflGk^'
j^ninpOTUsjy*^^.^
uir^r*-*-* ,
nf^R9 |a-:aicay .^.^^.., __^
At7|
SHEilfia^Si^Sn:
V l> POND j^-~" f \ *OMA H.»COil '—•-*
\v • /'\-%JTpi.KE] F^
-*?^ x''r/- = -- I I s'
X= INCINERATOR STACK
SAMPLING SITE
Figure C29. Plant map of FMC.
-------
EPA REGION II
171
-------
PENNSYLVANIA
I =17 miles
Figure C30. Sampling sites in New Jersey (solid circles)
172
-------
NORTHERN NEW JERSEY
{-V* /
\WESTFIELD
•'X O
Figure C31. Sampling sites in Northeast New Jersey (solid circles),
173
-------
TOTAL AC"?^iGr
DEVELOPED ACREAGE
VrET LASCS ACREAGE
DEVELOPABLE ACREAGE
CHAIJOERS 1 CARNEY3
W0»«5 loo'ST wn«rf«
73T
100
20
T!«
150
ISO
130 1 ISO
V>@
i. \>, ^ v_/
CHAMBERS \VORKS
AND
CARNEYS POINT WORKS
Figure C32. Location of E. I. DuPont de Nemours in Deepwater, NJ.
174
-------
-vj
Ln
Figure C33. Sampling locations on E. I. DuFont de Nemours plant site.
-------
Figure C34. Map of Chester, Camden, Philadelphia areas along the Delaware River.
-------
0.5
1.0
I
M!lr.S
Figure C35.
Sampling locations surrounding Kin-Buc Land-fill,
Edison, NJ.
177
-------
Figure C36. General location of American Cyanamid Corp. with respect
to Tremley's Point and Staten Island.
178
-------
Figure C37. Map of Linden, NJ.
-------
B
CO
cu
00
(3
cti
CO
00
P.
0)
"d
cfl
0)
c
0)
T3
•H
4-1
O
CX
cfl
OO
ro
00
•H
180
-------
Figure C39. Map of Linden, NJ, area depicting sampling sites.
181
-------
ARTHUR KILL
Figure: C40. Sampling locations on American Cyanamid Corp. plant site.
182
-------
00
ONTARIO
OREEN •
ISLAND / •MOHTHAOAM3
NEW YORK
\ - 35 mites
Figure C41. Sampling sites visited in Northeastern states (solid circles)
-------
Figure C42. Map of Buffalo and Niagara Falls, NY, area (x = sampling
site near LaSalle Arterial).
184
-------
NIAGARA RIVER
•*— WEST LA SALLE EXPRESSWAY — »• EAST
J
1 FRONTIER AVENUE
8
t>
II
I
K> fc 2
9
8
7
6
WHEATFIELD AVENUE
%
g
._
12
s
o»
< 3
" 4
5
•R
£
t
i
_
e.
s
READ AVENUE
'
APT
COMPLEX
\
\\
Vv_
\
in
•s
»
VREADAVE
COLVIN BLVD. "
«
£
«
^J
£
In
IS
0
t
SI
CAD
END
Figure C43. Map depicting sampling locations 1 to 13 in
Niagara Falls, NY.
185
-------
APPENDIX D
VAPOR-PHASE HALOGENATED CHEMICALS IDENTIFIED IN THE AMBIENT AIR
THROUGHOUT THE-.CONTINENTAL U.S.
186
-------
Table Dl. VAPOR-PHASE HALOGENATED CHEMICALS - EPA REGION II
oo
EPA
Region Compound
II chloroinethane
II vinyl chloride
II bromomethane
CASS 1 Site
74-87-3 Clifton, NJ
Passalc , NJ
Hoboken, NJ
Newark, NJ
Edison, NJ
Edison, NJ
Sayrevllle, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
East Brunswick, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Deepwater, NJ
75-01-4 Clifton, NJ
Passalc , NJ
Edison, NJ
74-83-9 Newark, NJ
Linden, NJ
Linden, NJ
Address
Dyer Ave. &
Wheeler St.
First St. &
Essex St.
New County Rd.
U.S. Post Office
Depot
552 Doremus Ave.
N. of Kln-Buc
Meadow Rd.
Off St. Stanislaus
School Rd.
Meadow Rd.
Meadow Rd.
Tower Marina
On Kln-Buc disposal
site
Tower Marina
Tremley Point Rd.
Tremley Point Rd.
Off Tremley Point Rd.
Off US Route 130
Dyer Ave. &
Wheeler St.
First St. &
Essex St.
Top of KB Mound
552 Doremus Ave.
Tremley Point Rd.
Off Tremley Point Rd.
Zip
Code
07014
07055
07030
07105
08817
08817
08872
08817
08817
08816
08817
08816
67031
07036
07036
08023
07014
07055
08817
07105
07036
07036
Sampling
Time
1528-1607
1715-1754
1223-1302
1400-1438
1207-1359
1607-1737
1029-1229
1030-1230
1458-1646
1006-1206
1015-1038
1425-1625
1228-1445
1540-1045
1150-1420
1554-1759
1528-1607
1715-1754
1506-1517
1400-1438
1228-1445
1540-1045
Calendar
Day - Year
082-76
082-76
083-76
083-76
181-76
181-76
182-76
182-76
182-76
183-76
183-76
183-76
172-77
172-3-77
173-77
174-77
082-76
082-76
085-76
083-76
172-76
173-3-76
Cone.
(ng/m3)
400
^120,000
T (11538)
- Continued -
-------
Table Dl (cont'd)
oo
00
EPA
Region Compound CASS # Site
II chloroethane 75-00-3 Passaic, NJ
Newark, NJ
Bound Brook, NJ
Edison, NJ
Linden, NJ
Linden, NJ
Linden, NJ
II vlnylidene chloride 75-35-4 Edison, NJ
Bridgeport, NJ
Linden, NJ
Staten Island, NY
II bromoethane 74-96-4 Edison, NJ
Edison, NJ
II methylene chloride 75-09-2 Paterson, NJ
Clifton, NJ
Passaic, NJ
Hoboken, NJ
Newark, NJ
Staten Island, NY
Fords, NJ
Bound Brook, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Address
First St. &
Essex St.
552 Doremus Ave.
Eastern Turnpike
N.J. Turnpike at
Mill Rd.
Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
W. of Kln-Buc
Off High Hill Rd.
Tremley Point Rd.
Forest Ave.
Parkland
Top of KB Mound
12th St. & 4th Ave.
Dyer Ave. &
Wheeler St.
First St. & Essex St.
New County Rd.
U.S. Post Office Depot
552 Doremus Ave.
Chelsea Rd. at
Bloomfield Ave.
Eastern Turnpike
Parkland
Tower Marina School-
house Rd.
Parkland
Zip
Codu
07055
07105
08805
08817
07036
07036
07036
08817
08014
07036
10303
08817
08817
07524
07014
07055
07030
07105
10314
08863
08805
08817
08816
08817
Sampling
Time
1715-1754
1400-1438
1732-1816
1048-1259
1228-1445
1540-1045
1150-1420
1029-1229
1030-1130
1035-1135
1045-1200
1247-1323
1506-1517
1231-1313
1528-1607
1715-1754
1223-1302
1400-1438
1702-1739
1559-1643
1732-1816
1247-1323
1647-1725
1647-1725
Calendar
Day - Year
.082-76
083-76
084-76
086-76
172-77
172-3-77
173-77
182-76
265-77
315-77
316-77
084-76
085-76
082-76
082-76
082-76
083-76
083-76
083-76
084-76
084-76
084-76
084-76
084-76
Cone .
(ng/m3)
T (454)
T (303)
T (263)
T (263)
1,000
T
1,091
1,545
400
T
9,286
375,000
125,000
390,000
(continued)
-------
Table Dl (cont'd)
oo
vo
EPA
Region
II
Compound CASS # Site
methylene chloride, 75-09-2 East Brunswick, NJ
(cone . )
Edison, NJ
East Brunswick, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Sayreville, NJ
East Brunswick, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Sayreville, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Address
Tower Marina School-
house Rd.
Parkland
Tower Marina
Tower Marina
Top of KB Mound
Meadow Rd. (bet.
Stauffer and KB)
N.J. Turnpike at
Mill Rd.
St. Stanislaus
School Rd.
Tower Marina
N. or Kin-Buc
Tower Marina
Meadow Rd.
E. of Kin-Buc
E. of KB disposal
site
Off St. Stanislaus
School Rd.
Meadow Rd.
Meadow Rd.
W. of Kin-Buc
disposal site
Tower Marina
Meadow Rd.
HE of Kin-Buc
disposal site
Tower Marina
Meadow Rd.
Zip
Code
08816
08817
08816
08816
08817
08817
08817
08872
08816
08817
08816
08817
08817
08817
08872
08817
08817
08817
08816
08817
08817
08816
08817
Sampling
Time
1647-1725
1647-1725
1115-1155
1508-1553
1506-1517
1620-1702
1048-1259
1049-1259
1207-1359
1207-1359
1607-1737
1607-1737
1607-1737
1607-1737
1029-1229
1030-1230
1029-1229
1029-1229
1457-1646
1458-1646
1457-1648
1006-1206
1006-1206
Calendar
Day - Year
084-76
084-76
085-76
085-76
085-76
085-76
086-76
086-76
181-76
181-76
181-76
181-76
181-76
181-76
182-76
182-76
182-76
182-76
182-76
182-76
182-76
183-76
183-76
Cone .
(ng/mS)
125,000
390,000
50
10
1,250,000
T
42
T
T (1000)
T (1000)
T (3750)
T (3750)
I <3750)
T (3750)
7,600
T (1000)
T (1000)
T (1000)
T (1250)
T (1250)
T (1250)
T (1000)
T (1000)
(continued)
-------
Table Dl (cont'd)
O
EPA
Region Compound CASS # Site
II methylene chloride, 75-09-2 Edison, NJ
(cont.)
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Deepwater , NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Address
On Kin-Buc disposal
site
E. of Kin-Buc
Tower Marina
N. of Kin-Buc disposal
site
Meadow Rd.
On Kin-Buc disposal
site
E. of Kin-Buc
Tremley Point Road
upwind N.
Tremley Point Road
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Close Salem Canal
Off U.S. Route 130
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Zip
Code
08817
08817
08816
08817
08817
08817
08817
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
08023
08023
08023
08023
08023
08023
08023
08023
08023
08023
Sampling
Time
1015-1038
1006-1206
1425-1625
1457-1646
1425-1625
1444-1458
1425-1625
1225-1445
1228-1445
1226-1445
1227-1445
1603-1045
1535-1045
1540-1045
1530-1045
1150-1420
1150-1420
1150-1420
1150-1420
1612-1833
1602-1818
1600-1807
1554-1754
1837-1050
1800-1120
1055-1255
1107-1307
1115-1315
1125-1325
Calendar
Day - Year
183-76
183-76
183-76
182-76
183-76
183-76
183-76
172-77
172-77
172-77
172-77
172-3-77
172-3-77
172-3-77
172-3-77
173-77
173-77
173-77
173-77
174-77
174-77
174-77
174-77
174-5-77
174-5-77
175-77
175-77
175-77
175-77
Cone.
(ng/m3)
40,000
100,000
3,000
T (1250)
T (1000)
260,000
42,000
100
258
168
58
52
324
369
134
81
261
972
418
65
405
35
437
75
625
345
248
261
81
(continued)
-------
Table Dl (cont'd)
EPA
Region Compound CASS 1 Site
II methylene chloride 75-09-2 Burlington, NJ
(cont.) Bridgeport, NJ
Bridgeport, NJ
Deepwater, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Staten Island,
Linden, NJ
Staten Island,
Staten Island,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls.
Niagara Falls,
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
Address
Burlington Ave.
Logan Township
Off High Hill Rd.
Off U.S. Route 130
Park Rd. with
Brunswick
Off Turnpike (NE)
Off Turnpike
West Brook Dr.
Parking Lot
Rose Hill Cementary
in West Brook Dr.
Tremley Point Rd.
Gulf Ave.
Gibbons Ave. & Wood
Forest Ave.
Off 1-278
703, 97th St.
763, 97th St.
779, 97th St.
783, 97th St.
476, 99th St.
474, 99th St.
468, 99th St.
460, 99th St.
454, 99th St.
440, 99th St.
99th St. School Gym.
99th St. School
93rd St. School
93rd St. School
93rd St. School
Zip
Code
08016
08014
08014
08023
07036
07036
07036
07036
07036
07036
07026
10303
07036
10303
10303
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
Sampling
Tine
1545-1645
1532-1642
1030-1130
1823-1103
1130-1230
1130-1240
1130-1230
1458-1700
1520-1640
1040-1140
1035-1135
1035-1135
1530-1630
1045-1200
1051-1153
1051-1409
1055-1450
1130-1457
1013-1935
0923-1255
0910-1216
1155-1507
0950-1221
0945-1305
1038-1312
0855-1655
0845-1725
0830-1460
0832-1642
0830-1640
Calendar
Day - Year
262-77
265-77
265-77
174-5-77
314-77
314-77
314-77
314-77
314-77
315-77
315-77
315-77
315-77
316-77
316-77
040-78
038-78
038-78
039-78
039-78
040-78
038-78
040-78
039-78
039-78
039-78
040-78
039-78
039-78
040-78
Cone.
(ng/«3)
T (1000)
T (555)
914 + 460
486
2,709
1,454
1,772 + 1,318
1,960
2,100
6,444
T (500)
17,400
26,778
19,333 + 555
9,778
1,534
1,300
1,334
11,556
9,428
1,545
3,000
3,627
1,285
2,250
4,000
10,182
1,428
1,857
44
(continued)
-------
Table Dl (cont'd)
ho
EPA
Region
II
II
II
II
II
Compound CASS » Site
1, 2-dichloroethy lene 540-59-0 East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Linden, NJ
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
chloropropane Isomer 540-54-5 or Fords, NJ
75-29-6 Sayrevllle, NJ
3-chloropropene 107-05-1 Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
1,1-dlchloroe thane 75-34-3 Edison, NJ
Linden, NJ
chloroform 67-66-3 Faterson, NJ
Clifton, NJ
Passalc, NJ
Hoboken, NJ
Address
Tower Marina
Meadow Rd.
E. of Kln-Buc
E. of Kln-Buc
Tremley Point Rd.
783, 97th St.
476, 99th St.
474, 99th St.
468, 99th St.
454, 99th St.
440, 99th St.
99th St. School Gym.
99th St. School
Off St. Stanislaus
School Road
E. of Kin-Buc
Meadow Rd .
W. of Kin-Buc
N. of Kin-Buc
On Kln-Buc disposal
site
Tremley Point Rd.
12th St. & 4th Ave.
Dyer Ave. & Wheeler St
First St. & Essex Ave.
New County Rd.
U.S. Post Office Depot
Zip
Code
08816
08817
08817
08817
07036
14304
14304
14304
14304
14304
14304
14304
14304
08863
08872
08817
08817
08817
08817
08817
07036
07524
.07014
07055
07030
Sampling
Time
1607-1737
1607-1737
1607-1737
1607-1737
1035-1135
1013-1935
0923-1255
0910-1216
1155-1507
0945-1305
1038-1312
0855-1655
0845-1725
1559-1643
1029-1229
1607-1737
1029-1229
1029-1229
1457-1646
1444-1458
1035-1135
1231-1313
1528-1607
1715-1754
1223-1302
Calendar
Day - Year
181-76
181-76
181-76
181-76
315-77
039-78
039-78
040-78
038-78
039-78
039-78
039-78
040-78
084-76
182-76
181-76
182-76
182-76
182-76
183-76
315-77
082-76
082-76
082-76
083-76
Cone.
(ng/«3)
4,847
4,500
5,263
T (565)
T (263)
T (29)
T (334)
63
710
334
294
T (334)
104
4,067
28,667
T
T
2,428
22,700
229
3,750
8,300
4,167
2,083
(continued)
-------
Table Dl (cont'd)
00
EPA
Region Compound
II chloroforn
(cont . )
CASS t Site
67-66-3 Newark, NJ
Scaten Island, NY
Fords, NJ
Bound Brook, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
East Brunswick, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Sayrevllle, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Sayreville, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Address
552 Doremus Ave.
Chelsea Rd. at
Bloonfield Ave.
Eastern Turnpike
Parkland
Tower Marina School-
house Rd.
Parkland
Tower Marina
Tower Marina
Top of KB Mound
Meadow Rd. (bet.
Stauffer and KB)
N.J. Turnpike at
Mill Rd.
St. Stanislaus
School Rd.
Tower Marina
Meadow Rd.
N. of KB disposal
site
N. of Kin Buc
Tower Marina
Meadow Rd.
E. of Kln-Buc
Off St. Stanislaus
School Rd.
Meadow Rd.
Meadow Rd.
W. of Kln-Buc
disposal site
Zip
Code
07105
10314
08863
08805
08817
08816
08817
08816
08816
08817
08817
08817
08872
08816
08817
08817
08817
08816
08817
08817
08872
08817
08817
08817
Sanpling
Time
1400-1438
1702-1739
1559-1643
1732-1816
1247-1323
1647-1725
1647-1725
1115-1155
1508-1553
1506-1517
1620-1702
1048-1259
1049-1259
1207-1359
1206-1355
1207-1359
1207-1359
1607-1737
1607-1737
1607-1737
1029-1229
1030-1230
1029-1229
1029-1229
Calendar
Day - Year
083-76
083-76
084-76
084-76
084-76
084-76
084-76
085-76
085-76
085-76
085-76
086-76
086-76
181-76
181-76
181-76
181-76
181-76
181-76
181-76
182-76
182-76
182-76
182-76
Cone.
(ng/«3)
37,000
20,830
16,700
4,167
74,000
1,000
128,000
15,000
20,000
266,000
45.000
1,000
30.000
6,389
T <230)
T (230)
T (230)
1,999
T (230)
T (230)
9,000
1.844
12,333
3.445
(continued)
-------
Table Dl (cont'd)
EPA
Region Compound CASS # Site
II chloroform 67-66-3 E. Brunswick, NJ
(cone.) Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden , N J
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Address
Tower Marina
Meadow Rd.
NE of Kin-Buc
disposal site
Tower Marina
Meadow Rd.
On Kin-Buc disposal
site
E. of Kin-Buc
Tower Marina
N. of Kin-Buc disposal
site
Meadow Rd.
On Kin-Buc disposal
site
E. of Kin-Buc
Tremley Point Rd.
upwind N.
Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Zip
Code
08816
08817
08817
08816
08817
08817
08817
08816
08817
08817
08817
08817
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
08023
08023
08023
Sampling
Time
1457-1646
1458-1646
1457-1648
1006-1206
1006-1206
1015-1038
1006-1206
1425-1625
1457-1646
1425-1625
1444-1458
1425-1625
1225-1445
1228-1445
1226-1445
1227-1445
1603-1045
1535-1045
1540-1045
1530-1045
1150-1420
1150-1420
1150-1420
1150-1420
1612-1833
1602-1818
1554-1754
Calendar
Day - Year
182-76
182-76
182-76
183-76
183-76
183-76
183-76
183-76
182-76
183-76
183-76
183-76
172-77
172-77
172-77
172-77
172-3-77
172-3-77
172-3-77
172-3-77
173-77
173-77
173-77
17>77
174-77
174-77
174-77
Cone.
(ng/m3)
186
5,834
2,778
17,222
11,111
19,444
8,334
944
8,999
2,500
27,200
28,334
50
154
133
99
41
195
178
150
86
229 '
773
190
152
T
T
(continued)
-------
Table Dl (cont'd)
Cn
EPA
Region Compound
II chloroform
(cont.)
CASS *. Site
67-66-3 Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Burlington, NJ
Bridgeport, NJ
Bridgeport, NJ
Deepwater, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden , NJ
Linden, NJ
Linden, NJ
1 1 nr10n N T
ijiuQen , n j
Staten Island,
Linden, NJ
Staten Island,
Staten Island,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
Address
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Burlington Ave.
Logan Township
Off High Hill Rd.
Off U.S. Route 130
Park Rd. with
Brunswick
Off Turnpike (NE)
Off Turnpike
West Brook Dr.
Parking Lot
Rose Hill Cemetary
In West Brook Dr.
Gulf Ave.
Gibbons Ave. & Wood
Forest Ave.
Off 1-278
703, 97th St.
753, 97th St.
763, 97th St.
779, 97th St.
783, 97th St.
476, 97th St.
474, 99th St.
468, 99th St.
460, 99th St.
454, 99th St.
Zip
Code
08023
08023
08023
08023
08023
08016
08014
08014
08023
07036
07036
07036
07036
07036
07036
07036
10303
07036
10303
10303
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
Sampling
Time
1837-1050
1800-1120
1107-1307
1115-1315
1125-1325
1545-1645
1532-1642
1030-1130
1823-1103
1130-1230
1130-1240
1130-1230
1458-1700
1520-1640
1040-1140
1035 1135
1035-1135
1530-1630
1045-1200
1051-1153
1051-1409
1035-1250
1055-1450
1130-1457
1013-1935
0923-1255
0910-1216
1155-1507
0950-1221
0945-1305
Calendar
Day - Year
174-5-77
174-5-77
175-77
175-77
175-77
262-77
265-77
265-77
174-5-77
314-77
314-77
314-77
314-77
314-77
315-77
315-77
315-77
315-77
316-77
316-77
040-78
038-78
038-78
038-78
039-78
039-78
040-78
038-78
040-78
039-78
Cone .
(ng/B3)
150
64
70
90
13
T (167)
154 + 58
277 + 166
439
1,178
429
440 + 210
T (75)
T (75)
125
T (93)
144
355
258 + 97
164
1,670
834
464
684
13,484
8,584
1,595
3,452
2,190
1,250
(continued)
-------
Table Dl (cont'd)
EPA
Region
II
II
Compound CASS )/ Site-
chloroform 67-66-3 Niagara
(cent.) Niagara
Niagara
Niagara
Niagara
Niagara
1, 2-dichloroethane 107-06-2 Paterson
Clifton,
Address
Falls,
Falls,
Falls,
Falls ,
Falls,
Falls,
, NJ
NJ
NY
NY
NY
NY
NY
NY
440,
99th
99th
93rd
93rd
93rd
12th
Dyer
99th
St.
St.
St.
St.
St.
St.
Ave.
St.
School Gym.
School
School
School
School
& 4th Ave.
&
Zip
Code
14304
14304
14304
14304
14304
14304
07524
07014
Sampling
Time
1038-1312
0855-1655
0845-1725
0830-1460
0832-1642
0830-1640
1231-1313
1528-1607
Calendar
Day - Year
039-78
039-78
040-78
039-78
039-78
040-78
082-76
082-76
Cone.
(ng/m3)
821
2,668
3,119
667
833
895
T.
64,516
VO
CTx
Passaic, NJ
Hoboken, NJ
Newark, NJ
Fords, NJ
Bound Brook, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Sayreville, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
E. Brunswick, NJ
Edison, NJ
Wheeler St.
First Street &
Essex St.
New County Rd.
U.S. Post Office Depot
552 Doremus Ave.
Eastern Turnpike
Parkland
Parkland
Top of KIn-Buc
E. of Kin-Buc
E. of KB disposal site
Off St. Stanislaus
School Rd.
Meadow Rd.
Meadow Rd.
W. of Kin-Buc disposal
site
Meadow Rd.
N. of Kin-Buc
Tower Marina
Meadow Rd.
07055
07030
1715-1754
1223-1302
082-76
083-76
07105
08863
08805
08817
08817
08817
08817
08817
08872
08817
08817
08817
08817
08817
08816
08817
1400-1438
1559-1643
1732-1816
1247-1323
1647-1725
1506-1517
1607-1737
1607-1737
1029-1229
1030-1230
1029-1229
1029-1229
1458-1646
1207-1359
1607-1737
1607-1737
083-76
084-76
084-76
084-76
084-76
085-76
181-76
181-76
182-76
182-76
182-76
182-76
182-76
181-76
181-76
181-76
T
T
T
35,000
33,000
57,000
T (347)
2,173
37,913
T
T (347)
347
T (444)
217
T (150)
434
(continued)
-------
Table Dl (cont'd)
EPA
Region
Compound
CASS t
Site
Address
It
1,2-dichloroethane 67-66-3
(cont.)
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Deepwater, NJ
Deepuater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Burlington, NJ
Bridgeport, NJ
Bridgeport, NJ
Linden, NJ
Linden, NJ
Linden, NJ
On Kin-Buc disposal
site
E. of Kin-Buc
Tower Marina
N. of Kin-Buc disposal
site
On Kin-Buc disposal
site
E. of Kin-Buc
Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Burlington Ave.
Logan Township
Off High Hill Rd.
Parking Lot
Rose Hill Cemetary
in West Brook Dr.
Tremley Point Rd.
lal
1.
i.
1.
I.
Zip
Code
08817
08817
08816
08817
08817
08817
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
08023
08023
08023
08023
08023
08023
08016
08014
08014
07036
07036
Sampling
Time
1015-1038
1006-1206
1425-1625
1457-1646
1444-1458
1425-1625
1228-1445
1226-1445
1227-1445
1603-1045
1535-1045
1540-1045
1530-1045
1150-1420
1150-1420
1150-1420
1150-1420
1612-1833
1602-1818
1554-1754
1800-1120
1107-1307
1125-1325
1545-1645
1532-1642
1030-1130
1520-1640
1040-1140
Calendar
Day - Year
183-76
183-76
183-76
182-76
183-76
183-76
172-77
172-77
172-77
172-O-77
172-3-77
172-3-77
172-3-77
173-77
173-77
173-77
173-77
174-77
174-77
174-77
174-5-77
175-77
175-77
262-77
265-77
265-77
314-77
315-77
Cone.
(ng/»3)
7,575
9,565
T (347)
1,130
27,700
260
14
9
42
12
9
47 .
34
T
38
9
8
12
T
T
53
T
24
T
T (195)
T (222)
T (160)
T (151)
07036
1035-1135
315-77
T (195)
(continued)
-------
Table Dl (cont'd)
oo
EPA
Region Compound CASS * Site
II 1, 2-d ichloroe thane 67-66-3 Staten Island, NY
(cont.) Staten Island, NY
Staten Island, NY
Linden, NJ
Linden, NJ
TT 1 1,1-trichloroethane 71-55-6 Paterson, NJ
Clifton, NJ
Passaic, NJ
Hoboken, NJ
Newark, NJ
Staten Island, NY
Fords, NJ
Bound Brook, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
East Brunswick, NJ
East Brunswick, NJ
Edison, NJ
Edison,, NJ
Edison, NJ
Sayreville, NJ
E. Brunswick, NJ
Edison, NJ
Edison, NJ
Address
Gulf Ave.
Forest Ave.
Off 1-278
Park Rd. with
Brunswick
Off Turnpike (NE)
12th St. & 4th Ave.
Dyer Ave. & Wheeler St
First St. & Essex St.
New County Rd.
U.S. Post Office Depot
552 Doremus Ave.
Chelsea Rd. at
Bloomfield Ave.
Eastern Turnpike
Parkland
Tower Marina School-
house Rd.
Parkland
Tower Marina
Tower Marina
Top of KB Mound
Meadow Rd. (bet.
Stauffer and KB)
N.J. Turnpike at
Mill Rd.
St. Stanislaus School
Road
Tower Marina
Meadow Rd.
N. of KB disposal
site
Zip
Code
10303
10303
10303
07036
07036
07524
.07014
07055
07030
07105
10314
08863
08805
08817
08816
08817
08816
08816
08817
08817
08817
08872
08816
08817
08817
Sampling
Time
1035-1135
1045-1200
1051-1153
1130-1230
1130-1240
1231-1313
1528-1607
1715-1754
1223-1302
1400-1438
1702-1739
1559-1643
1732-1816
1247-1323
1647-1725
1647-1725
1115-1155
1508-1553
1506-1517
1620-1702
1048-1259
1049-1259
1207-1359
1206-1355
1207-1359
Calendar
Day - Year
315-77
316-77
316-77
314-77
314-77
082-76
082-76
082-76
083-76
083-76
083-76
084-76
084-76
084-76
084-76
084-76
085-76
085-76
085-76
085-76
080-76
086-76
181-76
181-76
181-76
Cone.
(ng/m3)
T (186)
T (195)
T (205)
101
41
T
T
13,000
T
T
T
1,300
T
25,000
T
5,000
30
T
500,000
T
40
30
T (417)
NQ
T (417)
(continued)
-------
Table Dl (cont'd)
vo
EPA
Region Compound CASS It Site
II 1,1, 1-trichloroethane 71-55-6 Edison, NJ
(cont.) E. Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Sayreville, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Address
N. of Kin-Buc
Tower Marina
Meadow Road
E. of Kln-Buc
E. of KB disposal site
Off St. Stanislaus
School Rd.
Meadow Rd.
Meadow Rd.
W. of Kin-Buc disposal
site
Tower Marina
Meadow Rd.
NE of Kin-Buc disposal
site
Tower Marina
Meadow Rd.
On Kin-Buc disposal
site
E. of Kln-Buc
Tower Marina
N of Kln-Buc disposal
site
Meadow Road
On Kin-Buc disposal
site
E. of Kin-Buc
Tremley Point Road
upwind N .
Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Zip
Code
08817
08816
08817
08817
08817
08872
08817
08817
08817
08816
08817
08817
08816
08817
08817
08817
08816
08817
08817
08817
08817
07036
07036
07036
07036
Sampling
Time
1207-1359
1607-1737
1607-1737
1607-1737
1607-1737
1029-1229
1030-1230
1029-1229
1029-1229
1457-1646
1458-1646
1457-1648
1006-1206
1006-1206
1015-1038
1006-1206
1425-1625
1457-1646
1425-1625
1444-1458
1425-1625
1225-1445
1228-1445
1226-1445
1227-1445
Calendar
Day - Year
181-76
181-76
181-76
181-76
181-76
182-76
182-76
182-76
182-76
182-76
182-76
182-76
183-76
183-76
183-76
183-76
183-76
182-76
183-76
183-76
183-76
172-77
172-77
172-77
172-77
Cone.
(ng/i.3)
T (417)
T (555)
T (417)
T (417)
T (417)
T
T
19,167
158
T
T (556)
T (555)
T (417)
T (417)
3,417
^1 50, 000
T (417)
7,684
T
12,000
75,000
13
735
9
13
(continued)
-------
Table Dl (cont'd)
N>
O
o
EPA
Region Compound CASS // Site
II 1,1,1-trlchloroethane 71-55-6 Linden, NJ
r~n~r \ Linden, NJ
(C°nt-) Linden! NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Burlington, NJ
Bridgeport, NJ
Bridgeport, NJ
Linden, NJ
Linden , N J
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Staten Island, NY
Linden, NJ
Staten Island, NY
Staten Island, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Address
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd .
Off Tremley Point Rd.
Off Tremley Point Rd .
Off Tremley Point Rd .
Off Tremley Point Rd.
Off Tremley Point Rd.
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Burlington Ave.
Logan Township
Off High Hill Rd.
Park Rd. with
Brunswick
Off Turnpike (NE)
Off Turnpike
West Brook Dr.
Parking Lot
Rose Hill Cemetery
In West Brook Dr.
Tremley Point Rd.
Gulf Ave.
Gibbons Ave. & Wood
Forest Ave.
Off 1-278
703, 97th St.
753, 97th St.
763, 97th St.
Zip
Code
07036
07036
07036
07036
07036
07036
07036
07036
08023
08023
08023
08023
08023
08016
08014
08014
07036
07036
07036
07036
07036
07036
07036
10303
07036
10303
10303
14304
94304
14304
Sampling
Time
1603-1045
1535-1045
1540-1045
1530-1045
1150-1470
1150-1420
1150-1420
1150-1420
1600-1807
1554-1754
1800-1120
1107-1307
1125-1325
1545-1645
1532-1642
1030-1130
1130-1230
1130-1240
1130-1230
1458-1700
1520-1640
1040-1140
1035-1135
1035-1135
1530-1630
1045-1200
1051-1153
1051-1409
1035-1250
1055-1450
Calendar
Day - Year
172-3-77
172-3-77
172-3-77
172-3-77
173-77
173-77
173-77
173-77
174-77
174-77
174-5-77
175-77
175-77
262-77
265-77
265-77
314-77
314-77
314-77
314-77
314-77
315-77
315-77
315-77
315-77
316-77
316-77
040-78
038-78
038-78
Cone.
(ng/«3)
9
13
39
244
T
3,116
1,440
24
2,842
T
67
T
14
T (294)
129 + 2
656 + 344
222
265
217 + 43
T (100)
T (217)
T (217)
T (250)
T (250)
T (278)
T (278)
T (278)
3,656
506
412
(continued)
-------
Table Dl (cont'd)
10
o
EPA
Region Compound CASS //
II 1,1,1-trichloroethane 71-55-6
(cont.)
II 1,1-d Ichloropropane 78-99-9
II carbon tetrachloride 56-23-5
Site
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Hoboken, NJ
Pater son, NJ
Clifton, NJ
Passaic, NJ
Hoboken, NJ
Newark, NJ
Staten Island, NY
Fords, NJ
Bound Brook
East Brunswick, NJ
Edison, NJ
East Brunswick, NJ
East Brunswick, NJ
Edison, NJ
Address
779, 97th St.
783, 97th St.
476, 99th St.
474, 99th St.
468, 99th St.
460, 99th St.
454, 99th St.
440, 99th St.
99th St. School
93rd St. School
93rd St. School
New County Rd.
U.S. Post Office Depot
12th St. & 4th Ave.
Dyer Ave. &
Wheeler St.
First St. & Essex St.
New County Rd.
U.S. Post Office Depot
552 Doremus Ave.
Chelsea Road at
Bloomfield Ave.
Eastern Turnpike
Tower Marina School-
house Road
Parkland
Tower Marina
Tower Marina
Meadow Rd. (bet.
Stauffer and KB)
Zip
Code
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
07030
07524
07014
07055
07030
07105
10314
08863
08805
08816
08817
08816
08816
08817
Sampling
Time
1130-1457
1013-1935
0923-1255
0910-1216
1155-1507
0950-1221
0945-1305
1038-1312
0845-1725
0830-1460
0830-1640
1223-1302
1231-1313
1528-1607
1715-1754
1223-1302
1400-1438
1702-1739
1159-1643
1732-1816
1647-1725
1647-1725
1115-1155
1508-1553
1620-1702
Calendar
Day - Year
038-78
039-78
039-78
040-78
038-78
040-78
039-78
039-78
040-78
039-78
040-78
083-76
082-76
082-76
082-76
083-76
083-76
083-76
084-76
084-76
084-76
084-76
085-76
085-76
085-76
Cone .
(ng/m3)
400
3,890
1,000
608
2,000
356
T (334)
1,562
369
373
395
T
T (59)
T
T
T
T
334
T
20,000
T
T
T
T
(continued)
-------
Table Dl (cont'd)
EPA
Region
Compound
CASS //
Siti
II
carbon tetrachloride 56-23-5
(cont.)
Edison, NJ
Sayrevllle, NJ
Edison, NJ
Edison, NJ
E. Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Sayreville, NJ
Edison, NJ
Edison, NJ
Edison, NJ
E. Brunswick, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Linden, NJ
Address
N.J. Turnpike at
Mill Road
St. Stanislaus School
Road
N. of KB disposal site
N. of Kin-Buc
Tower Marina
Meadow Rd.
E. of Kin-Buc
E. of KB disposal site
Off St. Stanislaus
School Road
Meadow Road
Meadow Road
W. of Kin-Buc disposal
site
Tower Marina
Meadow Rd.
NE of Kin-Buc disposal
site
Tower Marina
Meadow Rd.
On Kin-Buc disposal
site
E. of Kin-Buc
Tower Marina
N. of Kin-Buc disposal
site
Meadow Rd.
On Kin-Buc disposal
site
E of Kin-Buc
Tremley Point Road
upwind N .
Zip
Code
08817
08872
08817
08817
08816
08817
08817
08817
08872
08817
08817
08817
08816
08817
08817
08816
08817
08816
08817
08816
08817
08817
08817
08817
07036
Sampl Ing
Time
1048-1259
1049-1259
1207-1359
12Q7-1359
1607-1737
1607-1737
1607-1737
1607-1737
1029-1229
1030-1230
1029-1229
1029-1229
1457-1646
1458-1646
1457-1648
1006-1206
1006-1206
1015-1038
1006-1206
1425-1625
1457-1646
1425-1625
1444-1458
1425-1625
1225-1445
Calendar
Day - Year
086-76
086-76
181-76
181-76
181-76
181-76
181-76
181-76
182-76
182-76
182-76
182-76
182-76
182-76
182-76
183-76
183-76
183-76
183-76
183-76
182-76
183-76
183-76
183-76
172-77
Cone.
(ng/»3)
T
T
1,312
750
12,687
13,687
7,250
1,937
T (125)
T (125)
T (125)
2,000
1,937
1,875
T (153)
T (120)
T (120)
T (120)
7,000
3,125
7,625
625
10,600
7,000
21
(continued)
-------
Table Dl (cont'd)
O
U>
EPA
Region Compound CASS It site
11 carbon tetrachloride 56-23-5 Linden, NJ
(cont.) Linden, NJ
Linden, NJ
Linden, NJ
Linden , NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Deepuater, NJ
Deepwater, NJ
Burlington, NJ
Bridgeport, NJ
Bridgeport, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Staten Island, NY
Linden, NJ
Staten Island, NY
Staten Island, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Address
Tremley Point Road
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Close Salem Canal
Off U.S. Route 130
Burlington Ave.
Logan Township
Off High Hill Rd.
Park Rd. with
Brunswick
Off Turnpike (NE)
Off Turnpike
West Brook Dr.
Parking Lot
Rose Hill Cemetery
in West Brook Dr.
Tremley Point Rd.
Gulf Ave.
Gibbons Ave. & Wood
Forest Ave.
Off 1-278
703, 97th St.
753, 97th St.
763, 97th St.
779, 97th St.
Zip
Code
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
08023
08023
08016
08014
08014
07036
07036
07036
07036
07036
07036
07036
10303
07036
10303
10303
14304
14304
14304
14304
Sampling
Time
1228-1445
1226-1445
1227-1445
1603-1045
1535-1045
1540-1045
1530-1045
1150-1420
1150-1420
1150-1420
1150-1420
1612-1833
1125-1325
1545-1645
1532-1642
1030-1130
1130-1230
1130-1240
1130-1230
1458-1700
1520-1640
1040-1140
1035-1135
1035-1135
1530-1630
1045-1200
1051-1153
1051-1409
1035-1250
1055-1450
1130-1457
Calendar
Day - Year
172-77
172-77
172-77
172-3-77
172-3-77
172-3-77
172-3-77
173-77
173-77
173-77
173-77
174-77
175--77
262-77
265-77
265-77
314-77
314-77
314-77
314-77
314-77
315-77
315-77
315-77
315-77
316-77
316-77
040-78
038-78
038-78
038-78
Cone .
-------
Table Dl (cont'd)
to
o
EPA
Region
II
II
II
II
II
Compound CASS t Site
carbon tetrachloride 56-23-5 Niagara Falls, NY
(cont.) Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, HY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
dibromomethane 74-95-3 Paterson, NJ
Edison, NJ
E. Brunswick, NJ
l-chloro-2-bromoethane 107-04-0 Edison, NJ
Edison, NJ
Edison, NJ
1,1,2-trichloroethane 79-00-5 Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Sayreville, NJ
Edison, NJ
Linden, NJ
trichloroethylene 79-01-6 Paterson, NJ
Clifton, NJ
Address
783, 97th St.
476, 99th St.
474, 99th St.
468, 99th St.
460, 99th St.
454, 99th St.
440, 99th St.
99th St. School
93rd St. School
93rd St. School
12th St. & 4th Ave.
Top of KB Mound
Tower Marina
Parkland
Parkland
Top of KB Mound
Parkland
Top of KB Mound
N. of Kln-Buc dispoi
site
N. of Kln-Buc
Off St. Stanislaus
School Road
E. of Kln-Buc
Tremley Point Rd.
12th St. & 4th Ave.
Dyer Ave. &
Wheeler St.
Zip
Code
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
07524
08817
08816
08817
08817
08817
08817
08817
sal 08817
08817
08872
08817
07036
07524
07014
Sampling
Time
1013-1935
0923-1255
0910-1216
1155-1507
0950-1221
0945-1305
1038-1312
0845-1725
0830-1460
0830-1640
1231-1313
1506-1517
1607-1737
1247-1323
1647-1725
1506-1517
1247-1323
1506-1517
1207-1359
1207-1359
1029-1229
1006-1206
1035-1135
1231-1313
1528-1607
Calendar
Day - Year
039-78
039-78
040-78
038-78
040-78
039-78
039-78
040-78
039-78
040-78
082-76
085-76
181-76
084-76
084-76
085-76
084-76
085-76
181-76
181-76
182-76
183-76
315-77
082-76
082-76
Cone .
(ng/03)
562
704
153
111
85
T (334)
80
59
T (83)
73
130
63,000
42
25,000
5,000
27,000
17,571
11,435
294
294
3,500
4,467
200
1,200
T
(continued)
-------
Table Dl (cont'd)
O
01
EPA
Region
II
Compound CASS t Site
trichloroethylene 79-01-6 Passaic, NJ
(cont.) Hoboken, NJ
Staten Island, NY
Bound Brook, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
East Brunswick, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Sayreville, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
E. Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Sayreville, NJ
Edison, NJ
Address
First St. i Essex St.
New County Rd.
U.S. Post Office Depot
Chelsea Rd. at
Bloomfleld Ave.
Eastern Turnpike
Parkland
Tower Marina School-
house Road
Parkland
Tower Marina
Tower Marina
Top of KB Mound
Meadow Rd. (bet.
Stauffer and KB)
N.J. Turnpike at
Mill Rd.
St. Stanislaus
School Road
Tower Marina
Meadow Road
N. of KB disposal
site
N. of Kin-Buc
Tower Marina
Meadow Rd.
E. of Kin-Buc
E. of KB disposal
site
Off St. Stanislaus
School Road
Meadow Road
Zip
Code
07055
07030
10314
08805
08817
08816
08817
08816
08816
08817
08817
08817
08872
08816
08817
08817
08817
08816
08817
08817
08817
08872
08817
Sumpl Ing
Time
1715-1754
1223-1302
1702-1739
1732-1816
1247-1323
1647-1725
1647-1725
1115-1155
1508-1553
1506-1517
1620-1702
1048-1259
1049-1259
1207-1359
1206-1355
1207-1359
1207-1359
1607-1737
1607-1737
1607-1737
1607-1737
1029-1229
1030-1230
Calendar
Day - Year
082-76
083-76
083-76
084-76
084-76
084-76
084-76
085-76
085-76
085-76
085-76
086-76
086-76
181-76
181-76
181-76
181-76
181-76
181-76
181-76
181-76
182-76
182-76
Cone .
T
T
T
T
93,000
9,000
82,000
T
T
T
13,000
T
T
T (131)
210
1,315
10,052
4,947
4,500
5,263
T (178)
3,737
T (178)
(continued)
-------
Table Dl (cont'd)
O
ON
EPA
Region Compound CASS t Site
II trichloroethylene 79-01-6 Edison, NJ
(cont.) Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Deepwacer, NJ
Deepwater, NJ
Address
Meadow Rd.
W. of Kin-Buc
disposal site
Tower Marina
Meadow Rd.
NE of Kin-Buc
disposal site
Tower Marina
Meadow Rd.
On Kin-Buc disposal
site
E. of Kin-Buc
Tower Marina
N. of Kin-Buc
disposal site
Meadow Rd.
On Kin-Buc
disposal site
E. of Kin-Buc
Tremley Point Road
upwind N.
Tremley Point Road
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Close Salem Canal
Off U.S. Route 130
Zip
Code
08817
08817
08816
08817
08817
08816
08817
08817
08817
08816
08817
08817
08817
08817
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
08023
08023
Sampling
Time
1029-1229
1029-1229
1457-1646
1458-1646
1457-1648
1006-1206
1006-1206
1015-1038
1006-1206
1425-1625
1457-1646
1425-1625
1444-1458
1425-1625
1225-1445
1228-1445
1226-1445
1227-1445
1603-1045
1535-1045
1540-1045
1530-1045
1150-1420
1150-1420
1150-1420
1612-1833
1800-1120
Calendar
Day - Year
182-76
182-76
182-76
182-76
182-76
183-76
183-76
183-76
183-76
182-76
182-76
183-76
183-76
183-76
172-77
172-77
172-77
172-77
172-3-77
172-3-77
172-3-77
172-3-77
173-77
173-77
173-77
174-77
174-5-77
Cone.
(ng/m3)
6,895
10,315
T
394
T (214)
T (132)
T (132)
18,940
3,684
T (132)
5,289
T (132)
T (263)
10,606
T
139
11
6
8
2
242
25
17
T
T
4
56
(continued)
-------
Table Dl (cont'd)
EPA
Region
II
Compound CASS // site
trlchloroethylene 79-01-6 Deepwater, NJ
(cont.) Burlington, NJ
Bridgeport, NJ
Bridgeport, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Staten Island,
Staten Island,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
Address
Off U.S. Route 130
Burlington hve.
Logan Township
Off High Hill Rd.
Park Rd. with
Brunswick
Off Turnpike (NE)
Off Turnpike
West Brook Dr.
Parking Lot
Rose Hill Cemetery
in West Brook Dr.
Tremley Point Rd.
Gulf fcve.
Forest hve.
703, 97th St.
753, 97th St.
763, 97th St.
771, 97th St.
783, 97th St.
476, 99th St.
474, 99th St.
468, 99th St.
460, 99th St.
454, 99th St.
440 99th St.
99th St. School Gym.
99th St. School
93rd St. School
93rd St. School
93rd St. School
Zi|,
Code
18023
OB016
08014
08014
07036
07036
07036
07036
07036
07036
07036
10303
10303
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
Sampling
Time
1125-1325
1545-1645
1532-1642
1030-1130
1130-1230
1130-1240
1130-1230
1458-1700
1520-1640
1040-1140
1035-1135
1035-1135
1045-1200
1051-1409
1035-1250
1055-1450
1130-1457
1013-1935
0923-1255
0910-1216
1155-1507
0950-1221
0945-1305
1038-1312
0855-1655
0845-1725
0830-1460
0832-1642
0830-1640
Calendar
Day - Year
175-77
262-77
265-77
265-77
314-77
314-77
314-77
314-77
314-77
315-77
315-77
315-77
316-77
040-78
038-78
038-78
038-78
039-78
039-78
040-78
038-78
040-78
039-78
039-78
039-78
040-78
039-78
039-78
040-78
Cone .
(ng/m3)
5
T (92)
T (77)
T (312)
130
240
129 + 31
T (167)
T (59)
T (72)
T (72)
T (73)
T (76)
1,224
2,920
270
5,344
1,374
15,880
151
388
122
156
667
T (116)
238
295
T (100)
126
(continued)
-------
Table Dl (cont'd)
N3
O
oo
EPA
Region Compound CASS // Site
II 1,2-dibromoethane 106-93-4 Sayreville, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Deepwater, NJ
II tetrachloroethylene 127-18-4 Paterson, NJ
Clifton, NJ
Fassalc, NJ
Hoboken, NJ
Newark, NJ
Staten Island, NY
Fords, NJ
Bound Brook, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
East Brunswick, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Sayreville, NJ
Address
Off St. Stanislaus
School Rd.
W. of Kin-Buc disposal
site
N of Kin-Buc
On Kin-Buc disposal
site
Off U.S. Route 130
12th St. 6, 4th Ave.
Dyer Ave. 4
Wheeler St.
First St. &
Essex St.
New County Rd.
U.S. Post Office Depot
552 Doremus Ave.
Chelsea Rd. at
Bloomfield Ave.
Eastern Turnpike
Parkland
Tower Marina School-
house Rd.
Parkland
Tower Marina
Tower Marina
Top of KB Mound
Meadow Rd. (bet.
Stauffer and KB)
H.J. Turnpike at
Mill Road
St. Stanislaus
School Road
Zip
Code
08872
08817
08817
08817
08023
07524
07104
07055
07030
07105
10314
08863
08805
08817
08816
08817
08816
08816
08817
08817
08817
08872
Sampl ing
Time
1029-1229
1029-1229
1457-1646
1015-1038
1600-1807
1231-1313
1528-1607
1715-1754
1223-1302
1400-1438
1702-1739
1559-1643
1732-1816
1247-1323
1647-1725
1647-1725
1115-1155
1508-1553
1506-1517
1620-1702
1048-1259
1049-1259
Calendar
Day - Year
182-76
182-76
182-76
183-76
174-77
082-76
082-76
082-76
083-76
083-76
083-76
084-76
084-76
084-76
084-76
084-76
085-76
085-76
085-76
085-76
086-76
086-76
Cone.
(ng/m3)
591
T
535
757
T
T
T
T
T
T
T
T
T
T
T
26,000
T
T
142,000
T
8,000
60,000
(continued)
-------
Table Dl (cont'd)
EPA
Region Compound CASS t Site
II tetrachloroethylene 127-18-4 East Brunswirk, NJ
(cont.) Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Sayrevllle, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Linden, NJ
Address
Tower Marina
Meadow Rd.
N. of KB disposal
site
N. of Kin-Buc
Tower Marina
Meadow Rd.
E. of Kin-Buc
E. of KB disposal
site
Off St. Stanislaus
School Rd.
Meadow Rd.
Meadow Rd.
W. of Kin-Buc
disposal site
Tower Marina
Meadow Rd.
NE of Kin-Buc
disposal site
Tower Marina
Meadow Rd.
On Kin-Buc disposal
site
E. of Kin-Buc
Tower Marina
N. of Kin-B.ic dis-
posal site
Meadow Road
On Kin-Buc disposal
site
K. of Kin-Buc
Tremley Point Road
upwind N.
Zip
Code
08816
08817
08817
08817
08816
08817
08817
08817
08872
08817
08817
08817
08816
08817
08817
08816
08817
08817
08817
08816
08817
08817
08817
08817
07036
Sampling
Time
1207-1359
1206-1355
1207-1359
1207-1359
1607-1737
1607-1737
1607-1737
1607-1737
1029-1229
1030-1230
1029-1229
1029-1229
1457-1646
1458-1646
1457-1648
1006-1206
1006-1206
1015-1038
1006-1206
1425-1625
1457-1646
1425-1625
1444-1458
1425-1625
1225-1445
Calendar
Day - Year
181-76
181-76
181-76
181-76
181-76
181-76
181-76
181-76
182-76
182-76
182-76
182-76
182-76
182-76
182-76
183-76
183-76
183-76
183-76
183-76
182-76
183-76
183-76
183-76
172-77
Cone.
(ng/m3)
354
1,527
T (45)
T (45)
1,187
T (49)
2,896
T (49)
T (49)
291
2,847
T (49)
2,722
527
1,389
1,360
152
25,560
34,632
694
9,173
1,229
394,000
12,500
(continued)
-------
Table Dl (cont'd)
EFA
Region Compound CASS // Site
II tetrachloroethylene 127-18-4 Linden, NJ
(cont.) Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Burlington, NJ
Bridgeport, NJ
Bridgeport, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Address
Tremley Point Road
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd .
Off Tremley Point Rd.
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Close Salem Canal
Off U.S. Route 130
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Burlington Ave.
Logan Township
Off High Hill Road
Park Rd. with
Brunswick
Off Turnpike (NE)
Off Turnpike
West Brook Dr.
Parking Lot
Rose Hill Cemetery
In West Brook Dr.
Tremley Point Rd.
Zip
Code
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
07036
08023
08023
08023
08023
08023
08023
08023
08023
08023
08016
08014
08014
07036
07036
07036
07036
07036
07036
07036
Sampling
Time
1228-1445
1226-1445
1227-1445
1603-1045
1535-1045
1540-1045
1530-1045
1150-1420
1150-1420
1150-1420
1150-1420
1612-1833
1602-1818
1600-1807
1554-1754
1837-1050
1800-1120
1055-1255
1107-1307
1125-1325
1545-1645
1532-1642
1030-1130
1130-1230
1130-1240
1130-1230
1458-1700
1520-1640
1040-1140
1035-1135
Calendar
Day - Year
172-77
172-77
172-77
172-3-77
172-3-77
172-3-77
172-3-77
173-77
173-77
173-77
173-77
174.-77
174-77
174-77
174-77
174-5-77
174-5-77
175-77
175-77
175-77
262-77
265-77
265-77
314-77
314-77
314-77
314-77
314-77
315-77
315-77
Cone.
(ng/mJ)
6
13
T
60
69
218
22
29
57
185 + 56
276 + k69
T (189)
321
960
52
78
84
T (106)
(continued)
-------
Table Dl (cont'd)
EPA
Region
II
II
Compound CASS // Site
tetrachloroethylene 127-18-4 Staten Island,
(cont.) Linden, NJ
Staten Island,
Staten Island,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
chlorobenzene 108-90-7 Faterson, NJ
Clifton, NJ
Hoboken, NJ
Newark, NJ
Staten Island,
Fords, NJ
Bound Brook, N,
Edison, NJ
East Brunswick
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
MY
NY
NY
NY
NY
NY
MY
J
, NJ
Address
Gulf Ave.
Gibbons Ave. & Wood
Forest Ave.
Off 1-278
703, 97th St.
753, 97th St.
763, 97th St.
779, 97th St.
783, 97th St.
476, 99th St.
474, 99th St.
468, 99th St.
460, 99th St.
454, 99th St.
440, 99th St.
99th St. School
93rd St. School
93rd St. School
934d St. School
12th St. & 4th Ave.
Dyer Ave. &
Wheeler St.
New County Rd.
U.S. Post Office Depot
552 Doremus Ave.
Chelsea Road at
Bloomfleld Ave.
Eastern Turnpike
Parkland
Tower Marina School-
Zip
Code
10303
07036
10303
10303
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
07524
07014
07030
07105
10314
08863
08805
08817
08816
Sampling
Time
1035-1135
1530-1630
1045-1200
1051-1153
1051-1409
1035-1250
1055-1450
1130-1457
1013-1935
0923-1255
0910-1216
1155-1507
0950-1221
0945-1305
1038-1312
0845-1725
0830-1460
0832-1642
0830-1640
1231-1313
1528-1607
1223-1302
1400-1438
1702-1739
1559-1643
1732-1816
1247-1323
1647-1725
Calendar
Day - Year
315-77
315-77
316-77
316-77
040-78
038-78
038-78
038-78
039-78
039-78
040-78
038-78
040-78
039-78
039-78
040-78
039-78
039-78
040-78
083-76
082-76
083-76
083-76
083-76
084-76
084-76
084-76
084-76
Cone.
(ng/n.3)
T (104)
T (63)
T (179)
6,349
10,652
3,342
5,386
51,992
37,442
304
109
151
183
396
294
222
T (155)
625
T
T
T
T
T
T
20,000
50,000
T
Edison, NJ
house Road
Parkland
08817
1647-1725
084-76
(continued)
-------
Table Dl (cont'd)
N)
I—'
NJ
EPA
Region Compound CASS // Site
II chlorobenzene 108-90-7 East Brunswick, NJ
(cont.) East Brunswick, NJ
Edison, NJ
Edison, HJ
Edison, NJ
Sayrevllle, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Sayreville, NJ
Edison, NJ
Edison, NJ
Edison, NJ
-
East Brunswick, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Address
Tower Marina
Tower Marina
Top of KB Mound
Meadow Rd. (bet.
Stauffer and KB)
N.J. Turnpike at
Mill Road
St. Stanislaus
School Road
Tower Marina
Meadow Rd.
N. of KB disposal
site
N. of Kin-Buc
Tower Marina
Meadow Rd.
E. of Kin-Buc
E. of KB disposal
site
Off St. Stanislaus
School Road
Meadow Road
Meadow Road
W. of Kin-Buc
disposal site
Tower Marina
Meadow Rd.
NE of Kin-Buc
disposal site
Tower Marina
Meadow Road
On Kin-Buc disposal
site
E. of Kin-Buc
Tower Marina
Zip
Code
08816
08816
08817
08817
08817
08872
08816
08817
08817
08817
08816
08817
08817
08817
08872
08817
08817
08817
08816
08817
08817
08816
08817
08816
08817
08816
Sampling
Time
1115-1155
1508-1553
1506-1517
1620-1702
1048-1259
1049-1259
1207-1359
1206-1355
1207-1359
1207-1359
1607-1737
1607-1737
1607-1737
1607-1737
1029-1229
1030-1230
1029-1229
1029-1229
1457-1646
1458-1646
1457-1648
1006-1206
1006-1206
1015-1038
1006-1206
1425-1625
Calendar
Day - Year
085-76
085-76
085-76
085-76
086-76
086-76
181-76
181-76
181-76
181-76
181-76
181-76
181-76
181-76
182-76
182-76
182-76
182-76
182-76
182-76
182-76
183-76
183-76
183-76
183-76
183-76
Cone.
(ng/m3)
T
T
T
T
T
4,000
170
112
T (82)
507
T (135)
T (85)
T (82)
1,127
T (60)
167
480
1,807
1,127
T (60)
610
T (132)
T (74)
T (74)
12,791
T (77)
(continued)
-------
Table Dl (cont'd)
N>
I—'
GJ
EPA
Region Compound CASS * Site
II chlorobenzene 108-90-7 Edison, NJ
(cont.)
Edison, NJ
Edison, NJ
Edison, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Burlington, NJ
Bridgeport, NJ
Bridgeport, NJ
Linden, NJ
Address
N. of Kln-Buc
disposal site
Meadow Rd.
On Kin-Buc
disposal site
E. of Kln-Buc
Tremley Point Road
upwind N.
Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Close Salem Canal
Off U.S. Route 130
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Burlington Ave.
Logan Township
Off High Hill Rd.
Park Rd. with
Brunswick
Zip
Code
08817
08817
08817
08817
07036
07036
07036
07036
07036
07036
07036
07306
07036
07036
07036
08023
08023
08023
08023
08023
08023
08023
08023
08023
08023
08016
08014
08014
07036
Sampling
Time
1457-1646
1425-1625
1444-1458
1425-1625
1225-1445
1228-1445
1226-1445
1227-1445
1603-1045
1535-1045
1540-1045
1530-1045
1150-1420
1150-1420
1150-1420
1612-1833
1602-1818
1600-1807
1554-1754
1837-1050
1800-1120
1055-1255
1107-1307
1115-1315
1125-1325
1545-1645
1532-1642
1030-1130
1130-1230
Calendar
Day - Year
182-76
183-76
183-76
183-76
172-77
172-77
172-77
172-77
172-3-77
172-3-77
172-3-77
172-3-77
173-77
173-77
173-77
174-77
174-77
174-77
174-77
174-5-77
174-5-77
175-77
175-77
175-77
175-77
262-77
265-77
265-77
314-77
Cone.
(ng/m3)
607
T (83)
2,656
918
3
5
123
272
11
4
30
222
T
T
T
14
15
11
512
55
305
25
17
12
669
T (278)
T (231)
T (405)
63
(continued)
-------
Table Dl (cont'd)
ho
EPA
Region Compound CASS // Site
II chlorobenzene 108-90-7 Linden, NJ
(cont . ) Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Staten Island,
Staten Island,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
II 1,1,2,2-tetra- 79-34-5 Sayreville, NJ
chloroethane
Edison, NJ
Edison, NJ
Edison, NJ
Linden, NJ
II chlorotoluene 108-41-8 Edison, NJ
isomer(a) or Edison, NJ
95-49-8
or Edison, NJ
106-43-4 Edison, NJ
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
Address
Off Turnpike
West Brook Dr.
Parking Lot
Rose Hill Cemetery
in West Brook Dr.
Tremley Point Rd.
Forest Ave.
Off 1-278
703, 97th St.
753, 97th St.
763, 97th St.
779, 97th St.
783, 97th St.
474, 99th St.
468, 99th St.
454, 99th St.
440, 99th St.
99th St. School
93rd St. School
93rd St. School
St. Stanislaus
School Rd.
E. of Kin-Buc
On Kin-Buc disposal
site
r,. of Ktn-Buc
Tremley Point Rd.
Parkland
Meadow Rd. (bet.
Stauffer and KB)
Meadow Rd.
Meadow Rd.
Zip
Code
07036
07036
07036
07306
07036
10303
10303
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
08872
08817
08817
08817
07036
08817
08817
08817
08817
Sampling
Time
1130-1230
1458-1700
1520-1640
1040-1140
1035-1135
1045-1200
1051-1153
1051-1409
1035-1250
1055-1450
1130-1457
1013-1935
0910-1216
1155-1507
0945-1305
1038-1312
0845-1725
0830-1460
0830-1640
1049-1259
1006-1206
1444-1458
1425-1625
1035-1135
1247-1323
1620-1702
1206-1355
1607-1737
Calendar
Day - Year
314-77
314-77
314-77
315-77
315-77
316-77
316-77
040-78
038-78
038-78
038-78
039-78
040-78
038-78
039-78
039-78
040-78
039-78
040-78
086-76
183-76
183-76
183-76
315-77
084-76
085-76
181-76
181-76
Cone.
(ng/m3)
58
T (187)
T (126)
T (158)
T (227)
T (135)
T (385)
1,940
4,232
1,000
3,674
2,778
68
25
35
75
T (319)
T (334)
T (197)
22,785
15,000
1,389
91
(continued)
-------
Table Dl (cont'd)
Cn
EPA
Region
II
II
II
Compound CASS II Site
chlorotoluene 108-41-8 Edison, NJ
isomer(s) or Edison, NJ
(cont.) 95-49-8
or Kast Brunswick
106-43-4 Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
, Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
pentachloroethane 76-01-7 Linden, NJ
m-dichlorobenzene 541-73-1 Clifton, NJ
Hoboken, NJ
, NJ
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
HY
NY
Address
E. of Kln-Buc
W. of Kln-Buc
disposal site
Tower Marina
Meadow Rd.
Meadow Rd.
E. of Kln-Buc
N. of Kln-Buc
disposal site
Meadow Rd.
703, 97th St.
703, 97th St.
753, 97th St.
763, 97th St.
779, 97th St.
783, 97th St.
476, 99th St.
476, 99th St.
474, 99th St.
468, 99th St.
460, 99th St.
454, 99th St.
440, 99th St.
99th St. School
99th St. School
93rd St. School
93rd St. School
93rd St. School
Tremley Point Rd
Dyer Ave. &
Wheeler St.
New County Rd.
U.S. Post Office
Zip
Code
08817
08817
08816
08817
08817
08817
08817
08817
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
07036
07014
07030
Depot
Sampling
Time
1607-1737
1029-1229
1457-1646
1458-1646
1006-1206
1006-1206
1457-1646
1425-1625
1051-1409
1051-1409
1035-1250
1055-1450
1130-1457
1013-1935
0923-1255
0923-1255
0910-1216
1155-1507
0950-1221
0945-1305
1038-1312
0845-1725
0845-1725
0830-1460
0832-1642
0830-1640
1035-1135
0528-1607
1223-1302
Calendar
Day - Year
181-76
182-76
182-76
182-76
183-76
183-76
182-76
183-76
040-78
040-78
038-78
038-78
038-78
039-78
039-78
039-78
040-78
038-78
040-78
039-78
039-78
040-78
040-78
039-78
039-78
040-78
315-77
082-76
083-76
Cone.
(ng/m3)
2,552
3,820
14,990
1,754
4,586
3,022
226, 514
223, 042
4,142
590
639
581
25
1,013
296
1,067
1,729
645
76
T (33)
T (33)
(continued)
-------
Table Dl (cont'd)
EPA
Region Compound CASS " slte
II m-dichlorobenzene 541-73-1 Newark, NJ
(cont.) Bound Brook, NJ
Edison, NJ
East Brunswick, NJ
East Brunswick, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Sayreville, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Sayreville, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Address
552 Dorerous Ave.
Eastern Turnpike
Parkland
Tower Marina School-
house Rd.
Tower Marina
Tower Marina
Top of KB Mound
N.J. Turnpike at
Mill Rd.
St. Stanislaus
School Road
Tower Marina
Meadow Rd.
N. of KB disposal
site
N. of Kin-Buc
Tower Marina
Meadow Rd.
E. of Kin-Buc
E. of KB disposal
site
Off St. Stanislaus
School Road
Meadow Rd .
Meadow Rd.
W. of Kin-Buc
Meadow Rd.
ME of Kin-Buc
disposal site
Tower Marina
Meadow Rd.
On Kin-Buc disposal
site
Zip
Code
07105
08805
08817
08816
08816
08816
08817
08817
08872
08816
08817
08817
08817
08816
08817
08817
08817
08872
08817
08817
08817
08817
08817
08816
08817
08817
Sampling
Time
1400-1438
1732-1816
1247-1323
1647-1725
1115-1155
1508-1553
1506-1517
1048-1259
1049-1259
1207-1359
1206-1355
1207-1359
1207-1359
1607-1737
1607-1737
1607-1737
1607-1737
1029-1229
1030-1230
1029-1229
1029-1229
1458-1646
1457-1648
1006-1206
1006-1206
1015-1038
Calendar
.Day - Year
083-76
084-76
084-76
084-76
085-76
085-76
085-77
086-76
086-76
181-.76
181-76
181-76
181-76
181-76
181-76
181-76
181-76
182-76
182-76
182-76
182-76
182-76
182-76
183-76
183-76
183-76
Cone.
(ng/in3)
T (33)
T (33)
7,000
T (33)
143
T
26,583
T
126
205
33,783
244
T
T (90)
205
T
T
T (72)
T (50)
376
895
T (40)
T (54)
T (88)
T (49)
789
(continued)
-------
Table Dl (cont'd)
EPA
Region Compound CASS # Site
II m-dichlorobenzene 541-73-1 Edison, NJ
(cont.) East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Burlington, NJ
Bridgeport, NJ
Bridgeport, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Address
E. of Kin-Buc
Tower Marina
N. of Kin-Buc
disposal site
Meadow Rd.
On Kin-Buc
disposal site
F.. of Kin-Buc
Tremley Point Rd.
upwind N .
Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremiey Point Rd.
Off Tremley Point Rd.
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Close Salem Canal
Off U.S. Route 130
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Burlington Ave.
Logan Township
Off High Hill Rd.
Park Rd. with
Brunswick
Off Turnpike (NE)
Off Turnpike
West Brook Dr.
Zip
Code
08817
08816
08817
08817
08817
08817
07036
07036
07036
07036
07036
07036
07036
07036
07036
08023
08023
08023
08023
08023
08023
08023
08023
08023
08016
08014
08014
07036
07036
07036
07036
Sampling
Time
1006-1206
1425-1625
1457-1646
1425-1625
1444-1458
1425-1625
1225-1445
1228-1445
1227-1445
1535-1045
1540-1045
1530-1045
1150-1420
1150-1420
1150-1420
1612-1833
1602-1818
1554-1754
1837-1050
1800-1120
1055-1255
1107-1307
1115-1315
1125-1325
1545-1645
1532-1642
1030-1130
1130-1230
1130-1240
1130-1230
1458-1700
Calendar
Day - Year
183-76
182-76
182-76
182-76
183-76
183-76
172-77
172-77
172-77
172-3-77
172-3-77
172-3-77
173-77
173-77
173-77
174-77
174-77
174-77
174-5-77
174-5-77
175-77
175-77
175-77
175-77
262-77
265-77
265-77
314-77
314-77
314-77
314-77
Cone .
(ng/m3)
839
659
410
T (55)
3,526
T (48)
T
30
1
T
13
T
T
T
T
19
12
1,240
21
T
101
404
14
T (185)
T (154)
T (286)
T (217)
78
T (169)
T (125)
(continued)
-------
Table Dl (cont'd)
I-o
H-'
00
EPA
Region Compound CASS It Site
II m-dichlorobenzene 541-73-1 Linden, NJ
(cont.) Linden, NJ
Linden, NJ
Staten Island, NY
Staten Island, NY
Staten Island, NY
II o-dichlorobenzene 95-50-1 Edison, NJ
East Brunswick, NJ
Bound Brook, NJ
East Brunswick, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Sayrevllle, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Edison, NJ
Edison, NJ
Edison, NJ
East Brunswick, NJ
Address
Parking Lot
Rose Hill Cemetery
in West Brook Dr.
Tremley Point Rd.
Gulf Ave.
Forest Ave.
Off 1-278
Parkland
Tower Marina School-
house Road
Eastern Turnpike
Tower Marina
Tower Marina
Top of KB Mound
NJ Turnpike at
Mill Road
St. Stanislaus
School Road
Meadow Rd.
N. of Kin Buc
NE of Kin-Buc
disposal site
Meadow Rd.
Meadow Rd.
W. of Kin-Buc
disposal site
Tower Marina
Meadow Rd.
On Kin-Buc disposal
site
E. of Kin-Buc
Tower Marina
Zip
Code
07036
07036
07036
10303
10303
10303
08817
08816
08805
08816
08816
08817
08817
08872
08817
08817
08817
08817
08817
08817
08816
08817
08817
08817
08816
Sampling
Time
1520-1640
1040-1140
1035-1135
1035-1135
1045-1200
1051-1153
1247-1323
1647-1725
1732-1816
1115-1155
1508-1553
1506-1517
1048-1259
1049-1259
1206-1355
1207-1359
1457-1648
1607-1737
1029-1229
1029-1229
1457-1646
1006-1206
1015-1038
1006-1206
1425-1625
Calendar
Day - Year
314-77
315-77
315-77
315-77
316-77
316-77
084-76
084-76
084-76
085-76
085-76
085-76
086-76
086-76
181-76
181-76
182-76
181-76
182-76
182-76
182-76
183-76
183-76
183-76
183-76
Cone.
(ng/B3)
T (118)
T (105)
T (151)
T (149)
T (90)
T (256)
6320
T (33)
T (33)
250
T
12,433
58
T
1,873
77
T (54)
T (57)
341
942
T (49)
1,526
5,087
1,500
(continued)
-------
Table Dl (cont'd)
vo
EPA
Region
II
Compound CASS // Site
o-dichlorobenzene
(cont.) 95-50-1 Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Burlington, NJ
Bridgeport, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Staten Island, NY
Staten Island, NY
Staten Island, NY
Address
N. of Kin-l'.uc
disposal site
Meadow Rd.
On Kin-Buc
E. of Uin-Buc
Tremley Point Road
upwind N .
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Close Salem Canal
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Burlington Ave.
Logan Township
Park Rd. with
Brunswick
Off Turnpike (NE)
Off Turnpike
West Brook Dr.
Parking Lot
Rose Hill Cemetery
in West Brook Dr.
Tremley Point Rd.
Gulf Ave.
Forest Ave.
Off 1-278
Zip
Code
08817
08817
08817
08817
07036
07036
07036
07036
08023
08023
08023
08023
08023
08023
08023
08016
08014
07036
07036
07036
07036
07036
07036
07036
10303
10303
10303
Sampling
Time
1457-1646
1425-1625
1444-1458
1425-1625
1225-1445
1530-1045
1150-1420
1150-1420
1612-1833
1602-1818
1554-1754
1837-1050
1055-1255
1115-1315
1125-1325
1545-1645
1532-1642
1130-1230
1130-1240
1130-1230
1458-1700
1520-1640
1040-1140
1035-1135
1035-1135
1045-1200
1051-1153
Calendar
Day - Year
182-76
183-76
183-76
183-76
172-77
172-3-77
173-77
173-77
174-77
174-77
174-77
174-5-77
175-77
175-77
175-77
262-77
265-77
314-77
314-77
314-77
314-77
314-77
315-77
315-77
315-77
316-77
316-77
Cone.
(ng/n.3)
150
T (55)
9,899
300
2
74
20
T
17
554
51
25
T
T
1,319
T (185)
T
T (217)
T (133)
T (169)
T (125)
89
T (105)
T (151)
T (149)
T (90)
T (256)
(continued)
-------
Table Dl (cont'd)
N>
NJ
O
EPA
Region Compound CASS I Site
Address
II dlchiorobenzene 541-73-1 Fords, NJ
Isomer(s) or Bound Brook, NJ
95-50-1 Niagara
or Niagara
106-46-7 Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls ,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls ,
Falls,
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
Eastern Turnpike
93rd
93rd
93rd
93rd
93rd
93rd
93rd
779,
779,
779,
783,
783,
783,
476,
476,
476,
474,
474,
474,
468,
468,
460,
460,
454,
440,
440,
99th
99th
'93rd
93rd
93rd
93rd
St.
St.
St.
St.
St.
St.
St.
97th
97th
97th
97th
97th
97th
99th
99th
99th
99th
99th
99th
99th
99th
99th
99th
99th
99th
School
School
School
School
School
School
School
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
99th St.
St.
St.
St.
St.
St.
St.
School
School
School
School
School
School
Zip
Code
08863
08805
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
Sampling
Time
1559-1643
1732-1816
0830-1460
0830-1460
0832-1642
0832-1642
0830-1640
0830-1640
0830-1640
1130-1457
1130-1457
1130-1457
1013-1935
1013-1935
1013-1935
0923-1255
0923-1255
0923-1255
0910-1216
0910-1216
0910-1216
1155-1507
1155-1507
0950-1221
0950-1221
0945-1305
1038-1312
1038-1312
0845-1725
0845-1725
0832-1642
0832-1642
0830-1640
0830-1640
Calendar
Day - Year
084-76
084-76
039-78
039-78
039-78
039-78
040-78
040-78
040-78
038-78
038-78
038-78
039-78
039-78
039-78
039-78
039-78
039-78
040-78
040-78
040-78
038-78
038-78
040-78
040-78
039-78
039-78
039-78
040-78
040-78
039-78
039-78
040-78
040-78
Cone.
(ng/»3)
T
T
2,044
260
4,400
2,442
154
76
418
2,940
2,105
3,654
8,914
6,024
2,294
100,476
51 , 600
34,686
2,172
31
45
109
T (29)
386
22
7,863
217
53
238
T (170)
T (167)
167
722
295
(continued)
-------
Table Dl (cont'd)
N>
EPA
Region
II
II
II
Compound CASS It
chlorobenzaldehyde 587-04-2
isomer or
104-88-1
or
89-98-5
bromotoluene 95-46-5
Isomer (m or p) or
100-39-0
or
591-17-3
or
106-38-7
dichlorotoluene
Isomer(s)
Site
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Fords, NJ
Edison, NJ
Deepuater, NJ
Deepwater , NJ
Deepwater, NJ
Deepwater, NJ
Edison, NJ
Edison, NJ
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
Niagara Falls,
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
Address
753, 97th St.
779, 97th St.
783, 97th St.
476, 99th St.
474, 99th St.
468, 99th St.
Meadow Rd.
Meadow Rd.
Meadow Rd.
Meadow Rd.
703, 97th St.
753, 97th St.
779, 97th St.
783, 97th St.
476, 99th St.
Meadow Rd. (bet.
Stauffer and KB)
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Meadow Rd.
Meadow Rd.
703, 97th St.
703, 97th St.
753, 97th St.
753, 97th St.
763, 97th St.
763, 97th St.
779, 97th St.
779, 97th St.
Zip
Code
14304
14304
14304
14304
14304
14304
08817
08817
08817
08817
14304
14304
14304
14304
14304
08863
08817
08023
08023
08023
08023
08817
08817
14304
14304
14304
14304
14304
14304
14304
14304
Sampling
Time
1035-1250
1130-1457
1013-1935
0923-1255
0910-1216
1155-1507
1206-1355
1458-1646
1006-1206
1425-1625
1051-1409
1035-1250
1130-1457
1013-1935
0923-1255
1559-1643
1620-1702
1554-1754
1800-1120
1107-1307
1125-1325
1458-1646
1425-1625
1051-1409
1051-1409
1035-1250
1035-1250
1055-1450
1055-1450
1130-1457
1130-1457
Calendar
Day - Year
083-78
038-78
039-78
039-78
040-78
038-78
181-76
182-76
183-76
183-76
040-78
038-78
038-78
039-78
039-78
084-76
085-76
174-77
174-5-77
175-77
175-77
182-76
183-76
040-78
040-78
038-78
038-78
038-78
083-78
038-78
038-78
Cone.
(ng/m3)
180
746
34
4,058
T (18)
T (18)
1,873
507
472
472
25
T (53)
134
66
4,372
T
59
61
107
29
8,836
3,956
20,926
6,316
86
48
5,240
5,320
(continued)
-------
Table Dl (cont'd)
EPA
Region
II
II
II
II
Compound CASS t Site
dichlorotoluene Niagara Falls, NY
isomer(s) Niagara Falls, NY
(cont.) Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
benzyl chloride 100-44-7 Edison, NJ (bet.
Stauffer and KB)
Edison, NJ
Edison, NJ
Edison, NJ
Edison, NJ
chloroanil ine Bound Brook, NJ
isomer Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
trichlorobenzene 120-82-1 Bound Brook, NJ
isomer(s) or Edison, NJ
108-70-3 Edison, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Deepwater, NJ
Deepwater, NJ
Deepwater, NJ
Address
779, 97th St.
783, 97th St.
783, 97th St.
476, 99th St.
476, 99th St.
476, 99th St.
474, 99th St.
468, 99th St.
99th St. School
Meadow Rd.
Meadow Rd.
Meadow Rd.
Meadow Rd.
Meadow Rd.
Eastern Turnpike
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Eastern Turnpike
Parkland
E. of Kin-Buc
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Off Tremley Point Rd.
Close Salem Canal
Off U.S. Route 130
Off U.S. Route 130
Zip
Code
14304
14304
14304
14304
14304
14304
14304
14304
14304
08817
08817
08817
08817
08817
0880S
08023
08023
08023
08805
08817
08817
07036
07036
07036
07036
07036
08023
08023
08023
Sampling
Time
1130-1457
1013-1935
1013-1935
0923-1255
0923-1255
0923-1255
0910-1216
1155-1507
0845-1725
1620-1702
1030-1230
1458-1646
1006-1206
1425-1625
1732-1816
1554-1754
1107-1307
1125-1325
1732-1816
1247-1323
1425-1625
1228-1445
1540-1045
1530-1045
1150-1420
1150-1420
1612-1833
1602-1818
1554-1754
Calendar
Day - Year
038-78
039-78
039-78
039-78
039-78
039-78
040-78
038-78
040-78
085-76
182-76
182-76
183-76
183-76
084-76
174-77
175-77
175-77
084-76
084-76
183-76
172-77
172-3-77
172-3-77
173-77
173-77
174-77
174-77
174-77
Cone.
-------
Table Dl (cont'd)
CO
EPA
Region Compound
11 crichlorobenzene
Isomer(s)
(cont.)
CASS II Sice
120-82-1 DeepvaCer, NJ
or DeepwaCer, NJ
108-70-3 Deepwacer, NJ
Linden, NJ
Linden, NJ
Linden, NJ
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls, NY
Niagara Falls. NY
Address
Off U.S. Rouce 130
Close Salem Canal
Off U.S. Rouce 130
Tremley PoinC Rd.
Tremley PoinC Rd.
Tremley PoinC Rd.
703, 97th SC.
703, 97th St.
753, 97ch SC.
753, 97ch St.
763, 97th St.
763, 97th SC.
779, 97ch SC.
779, 97ch SC.
779, 97ch St.
783, 97ch St.
783, 97th St.
783, 97ch SC.
476, 99ch SC.
476, 99ch SC.
476, 99ch SC.
474, 99th St.
474, 99th SC.
474, 99ch SC.
468, 99th St.
468, 99th St.
460, 99th St.
460. 99th St.
454, 99th St.
440, 99th SC.
440, 99ch St.
440, 99th St.
99th St. School
93rd St. School
Zip
Code
08023
08023
08023
07036
07036
07036
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
Sampling
Time
1800-1120
1055-1255
1125-1325
1035-1135
1035-1135
1035-1135
1051-1409
1051-1409
1035-1250
1035-1250
1055-1450
1055-1450
1130-1457
1130-1457
1130-1457
1013-1935
1013-1935
1013-1935
0923-1255
0923-1255
0923-1255
0910-1216
0910-1216
0910-1216
1155-1507
1155-1507
0950-1221
0950-1221
0945-1305
1038-1312
1038-1312
1038-1312
0845-1725
0830-1640
Calendar
Day - Year
178-5-77
175-77
173-77
315-77
315-77
315-77
040-78
040-78
038-78
038-78
038-78
038-78
038-78
038-78
038-78
039-78
039-78
039-78
039-78
039-78
039-78
040-78
040-78
040-78
' 038-78
038-78
040-78
040-78
039-78
039-78
039-78
039-78
040-78
040-78
Cone.
(ng/«3)
150
13
113
91
76
91
642
58
10,084
1,010
72
T (23)
56
1,306
1,066
26
3,424
580
27,228
2,370
3.686
65
45
45
T (21)
T (21)
28
T (27)
11
23
T (23)
T (23)
T (128)
T (79)
(continued)
-------
4-)
d
O
O
Q
0)
i—I
ft
«
H
•en
\D CM
oo
-TO
oo co en o>
o^o •» en »H \o r-» co CM -*^v^^r^< ^ ^ ^ _ _
h
P «
a «
COCOOOOOCOOOOOOOQOCOQOOOCOCOOOCDOOOOCOCO OO COOOOOOOOOOOOOOO OO OO 00 OO
V I I I I I t I I I I I I I I I I I I I I I I t I t I I I I I I I I I
^ ooooooocoooaoaoooooaocoooaoo\o\ovototota>o\oooooo
-------
Table Dl (cont'd)
EPA
Region Compound CASS 1 Site
II chloronitrobenzene Deepwater, NJ
isomer Deepwater, NJ
II dlchloronitrobenzene Deepwater, NJ
Isomer Deepwater, NJ
Deepwater, NJ
II tetrachlorobenzene 95-94-3 Niagara
isomer (s) or Niagara
634-66-2 Niagara
or Niagara
634-90-2 Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
II tetrachlorotoluene Niagara
Isomer (s) Niagara
Niagara
Niagara
Falls ,
Falls ,
Falls,
Falls ,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls ,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
NY
Address
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
Off U.S. Route 130
703,
753,
753,
763,
779,
779,
783,
783,
476,
476,
474,
474,
474,
468,
478,
460,
454,
454,
440,
440,
703,
703,
753,
779,
97th
97th
97th
97th
97th
97th
97th
97th
99th
99th
99th
99th
99th
99th
99th
99th
99th
99th
99th
99th
97th
97th
97th
97th
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
Zip
Code
08023
08023
08023
08023
08023
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
143ttt
14304
14304
14304
14304
14304
14304
14304
14304
14304
14304
Sampling
Time
1554-1754
1800-1120
1554-1754
1800-1120
1125-1325
1051-1409
1035-1250
1035-1250
1055-1450
1130-1457
1130-1457
1013-1935
1013-1935
0923-1255
0923-1255
0910-1216
0910-1216
0910-1216
1155-1507
1155-1507
0950-1221
0945-1305
0945-1305
1038-1312
1038-1312
1051-1409
1051-1409
1035-1250
1130-1457
Calendar
Day - Year
174-77
• 174-5-77
174-77
174-5-77
175-77
040-78
038-78
038-78
038-78
038-78
038-78
039-78
039-78
039-78
039-78
040-78
040-78
040-78
038-78
038-78
040-78
039-78
039-78
039-78
039-78
040-78
040-78
038-78
038-78
Cone.
(ng/»3)
360
T
2,704
T
32
16
1,832
9,600
62
280
360
214
406
2,400
17,142
32
T (45)
45
T (21)
T (21)
17
T (23)
23
T (23)
T (23)
148
58
168
16
(continued)
-------
Table Dl (cont'd)
EPA
Region
II
II
Compound
tetrachlorotoluene
isomer(s)
(cont.)
pentachlorobenzene
CASS * Sice
Niagara
Niagara
Niagara
608-93-5 Niagara
Niagara
Niagara
Niagara
Niagara
Niagara
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls,
Falls ,
Falls,
NY
NY
NY
NY
NY
NY
NY
NY
NY
Address
783,
476,
474,
753,
763,
779,
783,
476,
474,
97th
99th
99th
97th
97th
97th
97th
99th
99th
St.
St.
St.
St.
St.
St.
St.
St.
St.
Zip
Code
14304
14304
14304
14304
14304
14304
14304
14304
14304
Sampling
Time
1013-1935
0923-1255
0910-1216
1035-1250
1055-1450
1130-1457
1013-1935
0923-1255
0910-1216
Calendar
Day - Year
039-78
029-78
040-78
038-78
038-78
038-78
039-78
039-78
040-78
Cone.
(ng/o>3)
56
970
97
494
T (23)
18
30
250
45
CO
NJ
-------
Table D2. VAPOR-PHASE HALOGENATED CHEMICALS - EPA REGION III
to
N>
EPA
Region Compound
III chloromethane
III vinyl chloride
III chloroethane
III vinylidene chloride
CASS # Site
74-87-3 South Charleston, WV
South Charleston, WV
Belle, WV
Nitro, WV
75-01-4 Belle, WV
South Charleston, WV
Nitro, WV
75-00-3 South Charleston, WV
Baltimore, MD
Baltimore, MD
75-35-4 Charleston, WV
Front Royal, VA
Front Royal, VA
Front Royal, VA
Bristol, PA
North Philadelphia, PA
Marcus Hook, PA
Address
167th llth Ave.
314 4th Ave.
Off Creek St.
Hwy. 60 and WV 25
Off Creek St.
Off Kanawha River
Hwy. 60 and WV 25
314 4th Ave.
Off Fairfield Rd.
Off Patapsco River
4th Ave. W. and
21st St. W.
Commerce Ave. bet.
4th St. and 5th St.
501 Grand Ave.
3rd St. and Villa
Ave.
Off Hwy. 413 in
Roadside Park
Brill St. bet.
Bridge St. and
Richmond
Off Hwy. 13
Zip
Code
25303
25303
25015
25143
25015
25303
25143
25303
21226
21226
25312
22630
22630
22630
19007
19007
19061
Sampling
Time
0900-1700
0931-1800
1906-2106
1158-1548
1906-2106
1441-1640
1158-1548
0931-1800
2300-0250
1000-1350
0925-0810
1609-1305
1735-0715
0737-1315
1315-1415
1220-1320
1100-1200
Calendar
Day - Year
216-75
220-75
338-75
339-75
338-75
337-75
339-75
220-75
288-75
289-75
297-9-77
272-3-77
272-3-77
273-77
231-77
233-77
234-77
Cone.
(ng/m3)
^2-4,000
T
•v. 50,000
T(263)
T(500)
2,500
778
1(333)
1(263)
T(263)
(continued)
-------
Table D2 (cont'd)
NJ
N>
CO
EPA
Region Compound
III methylene chloride
CASS t Sice
75-09-2 South Charleston, WV
Dunbar, WV
South Charleston, WV
South Charleston, WV
Baltimore, MD
Baltimore, MD
Baltimore, MD
Baltimore, MD
Baltimore, MD
Belle, WV
South Charleston, WV
Nitro, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
Bristol, PA
Bristol, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
Address
4th & C St.
llth & Myers
167 llth Ave.
314 4th Ave.
Off Fairfield Rd.
Off Fairfield Rd.
Off Patapsco River
Off North Ridge Ave.
Off Patapsco Ave.
Off Creek St.
Off Kanawha River
Hwy. 60 and WV 25
Off Hwy. 64
Off Hwy. 64
Off Hwy. 64
Off Hwy. 64
Off Hwy. 64
Off Otter Creek
Off Hwy. 413 in
Roadside Park
Belgrade St. and
Pratt St.
Belgrade St.
Bridge St. and
Garden St.
Brill St. bet.
Bridge St. and
Richmond
Zip
Code
25303
25054
25303
25303
21226
21226
21226
21226
21226
25015
25303
25143
25303
25303
25303
25303
25303
19007
19007
19007
19007
19007
19007
Sampling
Time
1000-1800
1015-1815
0900-1700
1000-1750
1100-1450
2300-0250
1000-1350
1400-1600
1355-1555
1906-2106
1441-1600
1158-1548
1302-1450
1508-1639
1650-1558
1605-1341
1349-1010
1314-1414
1315-1415
1030-1130
1025-1125
1220-1320
1220-1320
Calendar
Day - Year
255-74
254-74
216-75
216-75
287-75
288-9-75
289-75
292-75
297-75
338-75
337-75
339-75
076-8-77
078-80-77
080-2-77
082-4-77
084-6-77
231-77
231-77
233-77
233-77
233-77
233-77
Cone.
(ng/m3)
* 8,700
^50,000
821
+ 107
T(714)
T(714)
T(714)
T(714)
1(714)
T(571)
562
+ 7
T(555)
T(555)
1(555)
(continued)
-------
Table D2 (cont'd)
N>
to
VO
EPA
Region Compound
III methylene chloride
(cont. )
CASS // Site
75-09-2 Marcus Hook, PA
Marcus Hook, PA
Charleston, W
South Charleston, WV
St. Albans, WV
Nitro, WV
W. Belle, WV
South Charleston, WV
St. Albans, WV
Charleston, WV
South Charleston, WV
St. Albans, WV
Nitro, WV
W. Belle, WV
South Charleston,' WV
St. Albans, WV
Nitro, WV
W. Belle, WV
Charleston, WV
Address
Hwy. 13 and
Smith St.
Off Hwy. 13
4th Ave. W. and
21st St. W.
314 4th Ave.
6500 MacCorkle
Ave., SW
NW of WV 25 and
1-64
Kanawha Blvd.
314 4th Ave.
6500 MacCorkle
Ave., SW
4th Ave. W and
21st St. W.
314 4th Ave.
6500 MacCorkle
Ave., SW
NU of WV 25
and 1-64
Kanawha Bid.
314 4th Ave.
6500 MacCorkle
Ave., SW
NW of WV 25 and
1-64
Kanawha Bid.
4th Ave. and
21st St. W.
Zip
Code
19061
19061
25312
25303
25177
25143
25015
25312
25177
25312
25303
25177
25143
25015
25303
25177
25143
25015
25312
Sampling
Time
1046-1146
1100-1200
1020-1435
1115-1617
1202-1715
1400-1610
1349-1945
0825-1308
0715-1355
0925-0850
1200-1737
1130-1635
1035-1600
1315-1808
0632-1205
0534-1147
0505-1118
0600-1635
1910-1125
Calendar
Day - Year
234-77
234-77
270-1-77
270-77
270-77
270-77
270-77
271-77
271-77
297-9-77
297-77
297-77
297-77
297-77
298-77
298-77
298-77
298-77
320-2-77
Cone.
(ng/m3)
T(555)
966
+ 78
T(IOOO)
T(1000)
T(714)
T(714)
T
1(555)
778
267
715
T(714)
T(714)
T(714)
11,334
T(555)
T(555)
1,778
2,818
(continued)
-------
Table D2 (cont'd)
to
w
o
EPA
Region Compound CASE * site
III methylene chloride 75-09-2 South Charleston, WV
(cont.) W. Belle, WV
Nitro, WV
Institute, WV
Charleston, WV
South Charleston, WV
W. Belle, WV
Institute, W
Nitro, WV
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Address
314 4th Ave.
Kanawha Blvd.
4107 1st Ave.
Barren Dr. bet.
4th St. and
Curtis Sq.
4th Ave. W. and
21st St. W.
314 4th Ave.
Kanawha Blvd.
Barron Dr. bet.
4th St. and
Curtis Sq.
NW of WV 25 and
1-64
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave bet.
4th St. and
5th St.
501 Grand Ave.
Commerce Ave. and
John Marshall Hwy.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
Zip
Code
25303
25015
25143
25112
25312
25303
25015
25112
25143
22630
22630
22630
22630
22630
22630
22630
22630
Sampling
Time
1235-1737
1348-1811
1335-1725
1235-1700
1135-0930
0809-1310
0729-1241
0728-1210
0802-1250
1040-1655
1115-1715
1140-1728
1609-1305
1735-0715
2030-0635
0737-1315
0800-1325
Calendar
Day - Year
321-77
321-77
321-77
321-77
322-4-77
322-77
322-77
322-77
-•
322-77
272-77
272-77
272-77
272-3-77
272-3-77
272-3-77
273-77
273-77
Cone.
(ng/m3)
T(454)
T(454)
1(454)
4,091
1,636
9,818
1,272
1,636
1,600
1,000
T(714)
1,857
2.U3
97,627
2,444
4,600
1,000
(continued)
-------
Table D2 (cont'd)
U>
EPA
Region Compound CASS t
III methylene chloride 75-09-2 Front
(cont.)
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Site
Royal,
Royal,
Royal ,
Royal,
Royal
Royal,
Royal,
Royal,
Royal,
Royal ,
Royal,
Royal ,
Royal,
Royal,
Royal,
Royal,
Royal ,
VA
VA
VA.
VA
VA
VA
VA.
VA.
VA.
VA.
VA,
VA
VA.
VA.
VA
VA.
VA.
VA.
Address
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. bet.
4th St. and
5th St.
John Marshall Hwy.
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. and
John Marshall Hwy.
3rd St. and
Villa Ave.
Commerce Ave. and
John Marshall Hwy.
13th St. and
Commonwealth Ave.
346 10th St.
1040 Adams Ave.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
346 10th St.
Zip
Code
22630
22630
22630
22630
ooA'in
££OJU
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
Sampling
Time
1508-2150
1455-2115
1520-2120
1550-0850
1 Q9ft 9^1 5
ly£o~ z jlo
2155-0560
2115-0555
2126-0620
2330-0645
1540-2315
1315-0845
1605-2330
1637-2335
1700-2345
1000-1722
1047-1705
1015-1715
Calendar
Day - Year
300-77
300-77
300-77
300-1-77
inn 77
JUU""/ /
300-1-77
300-1-77
300-1-77
300-1-77
328-77
328-30-77
328-77
328-77
328-77
329-77
329-77
329-77
Cone.
(ng/m3)
8
40
11
120
07
o/
25
2
111
238
1
,375
,571
,428
,142
07 c
,J/3
,250
,625
,556
,250
,364
T(454)
2
T
1
1
2
6
.545
,091
,818
,090
.273
(continued)
-------
Table D2 (cont'd)
03
EPA
Region Compound CASS * Site
III chloroform 67-66-3 South Charleston, WV
Dunbar, WV
South Charleston, WV
South Charleston, WV
Baltimore, MD
Baltimore, MD
Baltimore, MD
Baltimore, MD
Baltimore, MD
Belle, WV
South Charleston, WV
Nitro, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
Bristol, PA
Bristol, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
Address
4th and C St.
llth and Myers
167 llth Ave.
314 4th Ave.
Off Fairfield Rd.
Off Fairfield Rd.
Off Patapsco River
Off North Ridge Ave.
Off Patapsco Ave.
Off Creek St.
Off Kanawha River
Hwy. 60 and WV 25
Off Hwy. 64
Off Hwy. 64
Off Hwy. 64
Off Hwy. 64
Off Hwy. 64
Off Otter Creek
Off Hwy. 413 in
Roadside Park
Belgrade St. and
Pratt St.
Belgrade St.
Bridge St. and
Garden St.
Zip
Code
25303
25064
25303
25303
21226
21226
21226
21226
21226
25015
25303
25143
25303
25303
25303
25303
25303
19007
19007
19007
19007
19007
Sampling
Time
1000-1800
1015-1815
0900-1700
1000-1750
1100-1450
2300-0250
1000-1350
1400-1600
1355-1555
1906-2015
1441-1600
1158-1548
1302-1450
1508-1639
1650-1558
1605-1341
1349-1010
1314-1414
1315-1415
1030-1130
1025-1125
1220-1320
Calendar
Day - Year
255-74
254-74
216-75
216-75
287-75
288-9-75
289-75
292-75
297-75
338-75
337-75
339-75
07«-8-77
078-80-77
080-2-77
082-4-77
084-6-77
231-77
231-77
233-77
233-77
233-77
Cone.
(ng/n.3)
T/ 39,000
416
+ 162
425
+ 200
478
+ 188
383
+ 129
826
+ 131
146
+ 21
262
4" 137
T(97)
T(97)
T(96)
(continued)
-------
Table D2 (cont'd)
U>
U5
EPA
Region Compound
III chloroform
(cont.)
CASS t
67-66-3 Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Site
Royal,
Royal ,
Royal ,
Royal,
Royal ,
Royal ,
Royal,
Royal ,
Royal ,
Royal,
Royal ,
Royal ,
Royal,
Royal,
Royal,
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
Address
Commerce Ave. and
John Marshall Hwy.
3rd St. and Villa
Ave.
13th St. and
Commonwealth Ave.
8th St. and
Crosby Rd.
3rd St. and Villa
Ave.
501 Grand Ave.
Commerce Ave. bet.
4th St. and
5th St.
Commerce Ave. and
John Marshall Hwy.
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. and
John Marshall Hwy.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
346 10th St.
Zip
Code
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
Sampling
Time
2030-0635
0737-1315
0800-1325
1508-2150
1455-2115
1520-2120
1550-0850
1925-2315
2155-0520
2115-0555
2126-0620
2330-0645
1540-2315
1047-1705
1015-1715
Calendar
Day - Year
272-3-77
273-77
273-77
300-77
300-77
300-77
300-1-77
.
300-77
300-1-77
300-1-77
300-1-77
300-1-77
328-77
329-77
329-77
Cone .
(ng/m3)
149
278
T(125)
692
792
T(125)
2,708
1,807
711
T(115)
2,193
14,517
T(71)
T(71)
119
(continued)
-------
Table D2 (cont'd)
N>
U>
EPA
Region Compound CASS t Site
III chloroform 67-66-3 North Philadelphia, PA
(cont.)
Marcus Hook, PA
Marcus Hook, PA
Charleston, WV
South Charleston, WV
St. Albans, WV
Nitro, WV
South Charleston, WV
St. Albans, WV
Charleston, WV
South Charleston, WV
St. Albans, WV
Nitro, WV
W. Belle, WV
South Charleston, WV
St. Albans, WV
Nitro, WV
Address
Brill St. bet.
Bridge St. and
Richmond
Hwy. 13 and
Smith St.
Off Hwy. 13
4th Ave. and
21st St. W.
314 4th Ave.
6500 MacCorkle
Ave., SW
NW of WV 25 and
1-64
314 4th Ave.
6500 MacCorkle
Ave., SW
4th Ave. W. and
21st St. W.
314 4th Ave
6400 MacCorkle
Ave., SW
NW of WV 25
and 1-64
Kanawha Blvd.
314 4th Ave.
6500 MacCorkle
Ave., SW
NW of WV 25
and 1-64
Zip
Code
19007
19061
19061
25312
25303
25177
25143
25312
25177
25312
25303
25177
25143
25015
25303
25177
25143
Sampling
Time
1220-1320
1046-1146
1100-1200
1020-1435
1115-1617
1202-1715
1400-1610
0825-1308
0715-1355
0925-0850
1200-1737
1130-1635
1035-1600
1315-1808
0632-1205
0534-1147
0505-1118
Calendar
Day - Year
233-77
234-77
234-77
270-1-77
270-77
270-77
27.0-77
271-77
271-77
297-9-77
297-77
297-77
-297-77
297-77
298-77
298-77
298-77
Cone .
(ng/m3)
T(96)
T(97)
235
+ 22
T(167)
T(167)
T(125)
T(125)
T(97)
T(97)
177
T(125)
T(125)
1(125)
1(125)
2,161
161
1,333
(continued)
-------
Table D2 (cont'd)
171
EPA
Region Compound
III 1,2-dichloroethylene
CASS It Site
540-59-0 St. Albans, WV
W. Belle, WV
St. Albans, WV
Charleston, WV
Nitro, WV
W. Belle, WV
South Charleston, WV
W. Belle, WV
Charleston, WV
South Charleston, WV
W. Belle, WV
Nitro, WV
Institute, WV
Charleston, WV
South Charleston, WV
Nitro, WV
Front Royal, VA
Front Royal, VA
Address
6500 MacCorkle
Ave., SW
Kanawha Blvd.
6500 MacCorkle
Ave., SW
4th Ave. W. and
21st St. W.
NW of WV 25 and
1-64
Kanawha Blvd.
314 4th Ave.
Kanawha Blvd.
4th Ave. and
21st St. W.
314 4th Ave.
Kanawha Blvd.
4107 1st Ave.
Barren Dr. bet.
4th St. and
Curtis Sq.
4th Ave. W. and
21st St. W.
314 4th Ave.
NW of WV 25 and
1-64
8th St. and
Crosby Rd.
Commerce Ave. bet.
4th St. and
5th St.
Zip
Code
21577
25015
25177
25312
25143
25015
25303
25015
25312
25303
25015
25143
25112
25312
25303
25143
22630
22630
Sampling
Time
1202-1715
1349-1945
0715-1355
0925-0850
1035-1600
1315-1808
0632-1205
0600-1235
1910-1125
1235-1737
1348-1811
1335-1725
1235-1700
1135-0930
0809-1310
0802-1250
1040-1655
1609-1305
Calendar
Day - Year
270-77
270-77
271-77
297-9-77
297-77
297-77
298-77
298-77
320-2-77
321-77
321-77
321-77
321-77
322-4-77
322-77
322-77
272-77
272-3-77
Cone.
(ng/m3)
T(334)
T(322)
T(322)
T(263)
T(334)
T(334)
T(263)
T(263)
T(212)
T(213)
T(213)
T(213)
T(213)
1(213)
T(213)
T(213)
T(334)
1(500)
(continued)
-------
Table D2 (cont'd)
to
co
EPA
Region Compound CASS ff
III 1, 2-dichloroethylene 540-59-0 Front
(cont.)
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Site
Royal ,
Royal,
Royal ,
Royal ,
Royal ,
Royal ,
Royal ,
Royal ,
Royal ,
Royal,
Royal ,
Royal,
Royal,
Royal,
Royal,
Royal ,
Royal,
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
Address
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. bet.
4th St. and
5th St.
Commerce Ave. and
John Marshall Huy.
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. and
John Marshall Hwy.
3rd St. and
Villa Ave.
Commerce Ave. and
John Marshall Hwy.
13th St. and
Commonwealth Ave.
1040 Adams Ave.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
346 10th St.
1040 Adams Ave.
Zip
Code
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
Sampling
Time
1508-2150
1455-2115
1520-2120
1550-0850
1925-2315
2155-0520
2115-0555
2126-0620
2330-0645
1540-2315
1315-0845
1605-2330
1700-2345
1000-1722
1047-1705
1015-1715
1030-1710
Calendar
Day - Year
300-77
300-77
300-77
300-1-77
300-77
300-1-77
300-1-77
300-1-77
300-1-77
328-77
328-30-77
328-77
328-77
329-77
329-77
329-77
329-77
Cone.
(ng/m3)
1(312)
T(334)
T(334)
T(334)
1(312)
T(312)
T(312)
1,842
2,974
T(213)
T(213)
T(213)
T(213)
1(213)
T(213)
T(213)
T(213)
(continued)
-------
Table D2 (cont'd)
NJ
EPA
Region Compound
III 1, 2-dichloroethane
CASS f Site
107-06-2 Bristol, PA
Bristol, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
Marcus Hook, PA
Marcus Hook, FA
South Charleston, WV
Charleston, WV
South Charleston, WV
W. Belle, WV
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Address
Off Otter Creek
Off Hwy. 413 in
in Roadside Park
Belgrade St. and
and Pratt St.
Belgrade St.
Bridge St. and
Garden St.
Brill St. bet.
Bridge St. and
Richmond
Hwy. 13 and Smith
St.
Off Hwy. 13
Off Hwy. 64
4th Ave. W. and
sit St., W.
314 4th Ave.
Kanawha Blvd.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Zip
Code
19007
19007
19007
19007
19007
19007
19061
19061
25303
25312
25303
25015
22630
22630
22630
22630
22630
Sampling
Time
1314-1414
1315-1415
1030-1130
1025-1125
1220-1320
1220-1320
1046-1146
1100-1200
1650-1558
1020-1435
1115-1617
1349-1945
0737-1315
0800-1325
1508-2150
1455-2115
1520-2120
Calendar
Day - Year
231-77
231-77
233-77
233-77
233-77
233-77
234-77
^
234-77
080-2-77
270-1-77
270-77
270-77
273-77
273-77
300-77
300-77
300-77
Cone.
(ng/m3)
T(258)
1(258)
+ 167
77
T(195)
965
+ 21
927
T(195)
1(195)
T(258)
T(347)
T(258)
T(250)
T(348)
T(258)
1(242)
T(258)
1(258)
(continued)
-------
Table D2 (cont'd)
00
EPA
Region Compound CASS t Site
III 1, 2-dichloroethane 107-06-2 Front Royal, VA
(cont.)
Front Royal, VA
Front Royal, VA
Charleston, WV
South Charleston, WV
Nitro, HV
South Charleston, WV
St. Albans, WV
Nitro, WV
W. Belle, WV
Charleston, WV
South Charleston, WV
W. Belle, W
Nitro, WV
Institute, WV
Charleston, WV
South Charleston, WV
W. Belle, W
Address
Commerce Ave. bet.
4th St. and
5th St.
8th St. and
Crosby Rd .
3rd St. and
Villa Ave.
4th Ave. , W. and
21st St. W.
314 4th Ave.
NW of WV 25 and
1-64
314 4th Ave.
6500 MacCorkle
Ave., SW
NW of WV 25 and
1-64
Kanawha Blvd.
4th Ave. and
21st St. W.
314 4th Ave.
Kanawha Blvd.
4107 1st Ave.
Barron Dr. bet.
4th St. and
Curtis Sq.
4th Ave. , W. and
21st St. W.
314 4th Ave.
Kanawha Blvd.
Zip
Code
22630
22630
22630
25312
25303
25143
25303
25177
25143
25015
25312
25303
25615
25143
25112
25312
25303
25015
Sampling
Time
1550-0850
2155-0520
2115-0555
0925-0850
1200-1737
1035-1600
0632-1205
0534-1147
0505-1118
0600-1235
1910-1125
1235-1737
1348-1811
1335-1725
1235-1700
1135-0930
0809-1310
0729-1241
Calendar
Day - Year
300-1-77
300-1-77
300-1-77
297-9-77
297-77
297-77
288-77
298-77
298-77
298-77
320-2-77
321-77
321-77
321-77
321-77
322-4-77
322-77
322-77
Cone.
(ng/in3)
322
T(242)
T(242)
T(195)
T(258)
T(258)
T(195)
T(195)
1(195)
T(195)
1(151)
151
T(163)
T(151)
T(151)
T(151)
1(151)
T(151)
(continued)
-------
Table D2 (cont'd)
EPA
Region Compound
III 1,2-dichloroethane
(cont.)
Ill 1,1,1-trichloroethane
CASS t site
107-06-2 Institute, WV
Nitro, WV
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
71-55-6 South Charleston, WV
South Charleston, WV
Baltimore, MD
Baltimore, MD
Baltimore, MD
Baltimore, MD
Baltimore, MD
Belle, WV
South Charleston, WV
Nitro, WV
South Charleston, WV
Address
Barron Dr . bet .
4th St. and
Curtis Sq.
NW of WV 25
and 1-64
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
346 10th St.
1040 Adams Ave.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
346 10th St.
1040 Adams Ave.
167 llth Ave.
314 4th Ave.
Off Fairfield Road
Off Fairfield Road
Off Patapsco River
Off North Ridge Ave.
Off Patapsco Ave.
Off Creek St.
Off Kanawha River
Hwy. 60 and WV 25
Off Hwy. 64
Zip
Code
25112
25143
22630
22630
22630
22630
22630
22630
22630
22630
25303
25303
21226
21226
21226
21226
21226
25015
25303
25143
25303
Sampling
Time
0728-1210
0802-1250
1540-2315
1605-2330
1637-2335
1700-2345
1000-1722
1047-1705
1015-1715
1030-1710
0900-1700
1000-1750
1100-1450
2300-0250
1000-1350
1400-1600
1355-1555
1906-2106
1441-1600
1158-1548
1302-1450
Calendar
Day - Year
322-77
322-77
328-77
328-77
328-77
328-77
329-77
.
329-77
329-77
329-77
216-75
216-75
287-75
288-9-75
289-75
292-75
297-75
338-75
337-75
339-75
076-8-77
Cone.
(ng/B3)
T(151)
T(151)
T(151)
1(151)
T(151)
T(151)
T(151)
TU51)
T(151)
1(151)
5,026
+ 1,093
(continued)
-------
Table D2 (cont'd)
•e-
o
EPA
Region Compound CASS # Site
III 1,1,1-trichloroethane 71-55-6 South Charleston, WV
(cont. )
South Charleston, WV
South Charleston, WV
South Charleston, WV
Bristol, PA
Bristol, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
Marcus Hook, PA
Marcus Hook, PA
Charleston, WV
South Charleston, WV
St. Albans, WV
Address
Off Hwy. 64
Off Hwy. 64
Off Hwy. 64
Off Hwy. 64
Off Otter Creek
Off Hwy. 413 in
Roadside Park
Belgrade St. and
Pratt St.
Belgrade St.
Bridge St. and
Garden St.
Brill St. bet.
Bridge St. and
Richmond
Hwy. 13 and
Smith St.
Off Hwy. 13
4th Ave. W. and
21st St. W.
314 4th Ave.
6500 MacCorkle
Ave., SW
Zip
Code
25303
25303
25303
25303
19007
19007
19007
19007
19007
19007
19061
19061
25312
25303
25177
Sampling
Time
1508-1639
1650-1558
1605-1341
1349-1010
1314-1414
1315-1415
1030-1130
1025-1125
1220-1320
1220-1320
1046-1146
1100-1200
1020-1435
1115-1617
1202-1715
Calendar
Day - Year
078-80-77
080-2-77
082-4-77
084-6-77
231-77
231-77
293-77
.
233-77
233-77
233-77
234-77
234-77
270-1-77
270-77
270-77
Cone.
(ng/n>3)
2,663
+ 270
2,300
+ 167
2,867
+ 400
1,820
+ 580
T(333)
T(267)
325
+ 108
T(278)
T(277)
T(278)
T
1,639
+ 1,250
T(417)
T(334)
1(334)
(continued)
-------
Table D2 (cont'd)
EPA
Region Compound CASS it
III 1,1,1-trichloroethane 71-55-6
(cont.)
Site
Nitro, WV
W. Belle, WV
South Charleston, WV
St. Albans, WV
Charleston, WV
South Charleston, WV
St. Albans, WV
Nitro, WV
W. Belle, WV
South Charleston, WV
St. Albans, WV
Nitro, WV
Charleston, WV
South Charleston, WV
W. Belle, WV
Nitro, WV
Institute, WV
Charleston, WV
Address
NW of WV 25
and 1-64
Kanawha Blvd.
314 4th Ave.
6500 MacCorkle
Ave., SW
4th Ave. W. and
21st St. W.
314 4th Ave.
6500 MacCorkle
Ave., SW
NW of WV 25
and 1-64
Kanawha Blvd.
314 4th Ave.
6500 MacCorkle
Ave., SW
NW of WV 25
and 1-64
4th Ave. and
21st St. W.
314 4th Ave.
Kanawha Blvd.
4107 1st Ave.
Barron Dr. bet.
4th St. and
Curtis Sq.
4th Ave. W. and
21st St. W.
Zip
Code
25143
25015
25312
25177
25312
25303
25177
25143
25015
25303
25177
25143
25312
25303
25015
25143
25112
25312
Sampling
Time
1400-1610
1349-1945
0825-1308
0715-1355
0925-0850
1200-1737
1130-1635
1035-1600
1315-1808
0632-1205
0534-1197
0505-1118
1910-1125
1235-1737
1348-1811
1335-1725
1235-1700
1135-0930
Calendar
Day - Year
270-77
270-77
271-77
271-77
297-9-77
297-77
297-77
297-77
.
297-77
298-77
298-77
298-77
320-2-77
321-77
321-77
321-77
321-77
322-4-77
Cone.
(ng/n>3)
T(334)
T(312)
T(312)
T(312)
278
T(334)
1(334)
T(334)
1(334)
3,278
T(278)
T(278)
T(217)
1(217)
T(217)
T(217)
T(217)
T(217)
(continued)
-------
Table D2 (cont'd)
ro
-P-
N>
EPA
Region Compound CASS t Site
III 1,1,1-trichloroethane 71-55-6 South Charleston, WV
(cent,) W. Belle, WV
Institute, WV
Nitro, WV
Front Royal,
Front Royal,
Front Royal,
Front Royal,
Front Royal,
Front Royal,
Front Royal,
Front Royal,
Front Royal,
Front Royal,
Front Royal,
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
Address
314 4th Ave.
Kanawha Blvd.
Barren Dr. bet.
4th St. and
Curtis Sq.
NW of WV 25
and 1-64
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. bet.
4th St. and
5th St.
501 Grand Ave.
Commerce Ave. and
John Marshall Hwy.
13th St. and
Commonwealth Ave.
8th St. and
Crosby Rd .
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. bet.
4th St. and
5th St.
Zip
Code
25303
25015
25112
25143
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
Sampling
Time
0809-1310
0729-1241
0728-1210
0802-1250
1040-1655
1115-1715
1140-1728
1609-1305
1735-0715
2030-0635
0800-1325
1508-2150
1455-2115
1520-2120
1550-0850
Calendar
Day - Year
322-77
322-77
322-77
322-77
272-77
272-77
272-77
272-3-77
272-3-77
272-3-77
273-77
300-77
300-77
300-77
300-1-77
Cone.
(ng/m3)
1(217)
1(217)
347
1(217)
1(334)
1(100)
1(334)
1(334)
381
1(278)
1(334)
1(294)
800
1(334)
2,933
(continued)
-------
Table D2 (cont'd)
EPA
Region Compound CASS 1
III 1,1,1-trichloroethane 71-55-6
(cont.)
Front
Site
Royal ,
VA
Address
Commerce Ave.
and
Zip
Code
22630
Sampl ing
Time
1925-2315
Calendar
Day - Year
300-77
John Marshall Hwy.
Front
Front
Front
Front
Royal ,
Royal,
Royal ,
Royal ,
VA
VA
VA
VA
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave.
and
22630
22630
22630
22630
2155-0520
2115-0555
2126-0620
2330-0645
300-1-77
300-1-77
300-1-77
300-1-77
Cone.
T(294)
T(470)
T(470)
195
T(312)
John Marshall Hwy.
Front
Front
Royal,
Royal,
VA
VA
3rd St. and
Villa Ave.
Commerce Ave. and
22630
22630
1540-2315
1315-0845
328-77
328-30-77
T(217)
T(217)
John Marshall Hwy.
Front
Front
Front
Front
Front
Front
Front
Royal,
Royal ,
Royal ,
Royal,
Royal,
Royal,
Royal,
VA
VA
VA
VA
VA
VA
VA
13th St. and
Commonwealth
346 10th St.
1040 Adams Ave
3rd St. and
Villa Ave.
13th St. and
Commonwealth
346 10th St.
1040 Adams Ave
Ave.
.
Ave.
•
22630
22630
22630
22630
22630
22630
22630
1605-2330
1637-2335
1700-2345
1000-1722
1047-1705
1015-1715
1030-1710
328-77
328-77
328-77
329-77
329-77
329-77
329-77
1(217)
T(217)
T(217)
T(217)
T(217)
T(217)
T(217)
CO
(continued)
-------
Table D2 (cont'd)
EPA
Region Compound CASS f Site
III carbon tetrachloride 56-23-5 South Charleston, WV
South Charleston, WV
South Charleston, WV
Baltimore, MD
Baltimore, MD
Baltimore, MD
Baltimore, MD
Belle, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
Bristol, PA
Bristol, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
Marcus Hook, PA
Marcus Hook, PA
South Charleston, WV
Address
167 llth Ave.
314 4th Ave.
314 4th Ave.
Off Fairfield Rd.
Off Patapsco River
Off North Ridge Ave.
Off Patapsco Ave.
Off Creek St.
Off Kanawha River
Off Hwy. 64
Off H«y. 64
Off Hwy. 64
Off Hwy. 64
Off Hwy. 64
Off Otter Creek
Off Hwy. 413 in
Roadside Park
Belgrade St. and
Pratt St.
Belgrade St.
Bridge St. and
Garden St.
Brill St. bet.
Bridge St. and
Richmond
Hwy. 13 and
Smith St.
Off Hwy. 13
314 4th Ave.
Zip
Code
25303
25303
25303
21226
21226
21226
21226
25015
25303
25303
25303
25303
25303
25303
19007
19007
19007
19007
19007
19007
19061
19061
25303
Sampling
Time
0900-1700
1000-1750
0931-1800
1100-1450
1000-1350
1400-1600
1355-1555
1906-2106
1441-1600
1302-1450
1508-1639
1650-1558
1605-1341
1349-1010
1314-1414
1315-1415
1030-1130
1025-1125
1220-1320
1220-1320
1046-1146
1100-1200
1115-1617
Calendar
Day - Year
216-75
216-75
220-75
287-75
289-75
292-75
297-75
338-75
337-75
076-8-77
078-80-77
080-2-77
082-4-77
084-6-77
231-77
231-77
233-77
233-77
233-77
233-77
234-77
234-77
270-77
Cone.
(ng/m3)
T(95)
T(95)
T(95)
T(95)
T(95)
T(95)
T(95)
T(74)
T(74)
T(74)
T(74)
T(74)
T(74)
1(125)
(continued)
-------
Table D2 (cont'd)
EPA
Region Compound CASS it
III carbon cetrachloride 56-23-5
(cone.)
Site
Nitro, WV
W. Belle, WV
South Charleston, WV
St. Albans, WV
Charleston, WV
South Charleston, WV
St. Albans, WV
Nitro, WV
W. Belle, WV
South Charleston, WV
St. Albans, WV
Nitro, WV
W. Belle, WV
Charleston, WV
South Charleston, WV
W. Belle, WV
Nitro, WV
Institute, WV
Address
NW of WV 25
and 1-64
Kanawha Blvd.
314 4th Ave.
6500 MacCorkle
Ave., SW
4th Ave. W. and
21st St. W.
314 4th Ave.
6500 MacCorkle
Ave., SW
NW o£ WV 25
and 1-64
Kanawha Blvd.
314 4th Ave.
6500 MacCorkle
Ave., SW
NW of WV 25
and 1-64
Kanawha Blvd.
4th Ave. and
21st St. W.
314 4th Ave.
Kanawha Blvd.
4107 1st Ave.
Barren Dr. bet.
4th St. and
Curtis Sq.
Zip
Code
25143
25015
25312
25177
25312
25303
25177
25143
25015
25303
25177
25143
25015
25312
25303
25015
25143
25112
Sampling
Time
1400-1610
1349-1445
0825-1308
0715-1355
0925-0850
1200-1757
1035-1600
1315-1808
0632-1205
0534-1147
0505-1118
0600-1235
1910-1125
1235-1737
1348-1811
1335-1725
1235-1700
Calendar
Day - Year
270-77
270-77
271-77
271-77
297-9-77
297-77
297-77
297-77
298-77
298-77
298-77
298-77
320-2-77
321-77
321-77
321-77
321-77
Cone.
(ng/o|3)
T(95)
T(91)
1(74)
T(74)
215
T(95)
T(95)
1(95)
2,222
3,630
97
1(74)
529
T(59)
1(59)
T(59)
441
(continued)
-------
Table D2 (cont'd)
N>
J>
ON
EPA
Region Compound CASS t Site
III carbon tetrachloride 56-23-5 Charleston, WV
(cont') South Charleston, WV
W. Belle, WV
Institute, WV
Nitro, WV
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Address
4th Ave. W. and
21st St.,W.
314 4th Ave.
Kanawha Blvd.
Barren Dr. bet.
4th St. and
Curtis Sq.
NW of WV 25
and 1-64
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. and
John Marshall Hwy.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. bet.
4th St. and
5th St.
Zip
Code
25312
25303
25015
25112
25143
22630
22630
22630
22630
22630
22630
22630
22630
22630
Sampling
Time
1135-0930
0809-1310
0729-1241
0728-1210
0802-1250
1115-1715
1140-1728
1735-0715
0737-1315
0800-1325
1508-2150
1455-2115
1520-2120
1550-0850
Calendar
Day - Year
322-4-77
322-77
322-77
322-77
322-77
272-77
272-77
272-3-77
273-77
273-77
300-77
300-77
300-77
300-1-77
Cone.
(ng/m3)
T(59)
500
T(59)
T(59)
T(59)
T<74)
T(95)
190
1(125)
T(95)
217
1(95)
T(95)
1,190
(continued)
-------
Table D2 (cont'd)
to
EPA
Region Compound CASS it
III carbon tetrachlorlde 56-23-5
(cone.)
Ill trichloroethylene 79-01-6
Site
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Baltimore, MD
Baltimore, MD
Baltimore, MD
Baltimore, MD
Belle, WV
South Charleston, WV
Nitro, WV
Charleston, WV
South Charleston, WV
Nitro, WV
South Charleston, WV
St. Albans, WV
Address
Commerce Ave. and
John Marshall Hwy.
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. and
John Marshall Hwy.
Commerce Ave. and
John Marshall Hwy.
3rd St. and
Villa Ave.
346 10th St.
Off Fairfleld Rd.
Off Patapsco River
Off North Ridge Ave.
Off Patapsco Ave.
Off Creek St.
Off Kanawha River
Hwy. 60 and WV 25
4th Ave. W. and
21st St. W.
314 4th Ave.
HW of WV 25
and 1-64
314 4th Ave.
6500 MacCorkle
Ave., SW
Zip
Code
22630
22630
22630
22630
22630
22630
22630
22630
21226
21226
21226
21226
25015
25303
25143
25312
25303
25143
25312
25177
Sampling
Time
1925-2315
2155-0520
2115-0555
2126-0620
2330-0645
1315-0845
1000-1722
1015-1715
1100-1450
1000-1350
1400-1600
1355-1555
1906-2106
1441-1600
1158-1548
1020-1435
1115-1617
1400-1610
0825-1308
0715-1355
Calendar
Day - Year
300-77
300-1-77
300-1-77
300-1-77
300-1-77
328-30-77
329-77
,
329-77
287-75
289-75
292-75
297-75
338-75
337-75
339-75
270-1-77
270-77
270-77
271-77
271-77
Cone.
(ng/m3)
T(87)
T(87)
565
889
280
T<59)
T(59)
1(59)
1(132)
1(100)
300
T(98)
T(98)
(continued)
-------
Table D2 (cont'd)
CO
EPA
Region Compound CASS f Site
III trichloroethylene 79-01-6 Bristol, PA
(cont.) Bristol, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
Marcus Hook, PA
Marcus Hook, PA
South Charleston, WV
Nitro, WV
W. Belle, WV
South Charleston, WV
St. Albans, WV
Nitro, WV
W. Belle, WV
Charleston, WV
South Charleston, WV
W. Belle, WV
Nitro, WV
Institute, WV
Address
Off Otter Creek
Off Hwy. 413 in
Roadside Park
Belgrade St. and
Pratt St.
Belgrade St.
Bridge St. and
Garden St.
Hwy. 13 and
Smith St.
Off Hwy. 13
314 4th Ave.
NW of WV 25
and 1-64
Kanawha Blvd.
314 4th Ave.
6500 MacCorkle
Ave., SW
NW of WV 25
and 1-64
Kanawha Blvd.
4th Ave. and
21st St. W.
314 4th Ave.
Kanawha Blvd.
4107 1st Ave.
Barron Dr . bet .
4th St. and
Curtis Sq.
Zip
Code
19007
19007
19007
19007
19007
19061
19061
25303
25143
25015
25303
25177
25143
25015
25312
25303
25015
25143
25112
Sampling
Time
1314-1414
1315-1415
1030-1130
1025-1125
1220-1320
1046-1146
1100-1200
1200-1757
1035-1600
1315-1808
0632-1205
0534-1147
0505-1118
0600-1235
1910-1125
1235-1737
1348-1811
1335-1725
1235-1700
Calendar
Day - Year
231-77
231-77
233-77
233-77
233-77
234-77
234-77
297-77
29T.-77
297-77
298-77
298-77
298-77
298-77
320-2-77
321-77
321-77
321-77
321-77
Cone.
(ng/n.3)
T(100)
I (100)
T(lll)
T(92)
T(83)
T(80)
T(88)
T(100)
360
1(100)
179
45
358
T(75)
T(56)
T(56)
T(55)
T(55)
T(55)
(continued)
-------
Table D2 (cont'd)
EPA
Region Compound CASS // Site
III trlchloroethylene 79-01-6 Charleston, WV
(cone.)
South Charleston, WV
W. Belle, WV
Institute, WV
Nitro, WV
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Address
4th Ave. W, and
21st St. W.
314 4th Ave.
Kanawha Blvd.
Barron Dr. bet.
4th St. and
Curtis Sq.
NW of WV 25
and 1-64
Commerce Ave. bet.
4th St. and
5th St.
501 Grand Ave.
Commerce Ave. and
John Marshall Hwy.
3rd St. and
Villa Ave.
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. bet.
4th St. and
5th St.
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
Commerce Ave. and
John Marshall Hwy.
3rd St. and
Villa Ave.
Zip
Code
25312
25303
25015
25112
25143
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
Sampling
Time
1135-0930
0809-1310
0729-1241
0728-1210
0802-1250
1609-1305
1735-0715
2030-0635
0737-1315
1508-2150
1455-2115
1520-2120
1550-0850
2155-0520
2115-0555
2330-0645
1540-2315
Calendar
Day - Year
322-4-77
322-77
322-77
322-77
322-77
272-3-77
272r3-77
272-3-77
273-77
300-77
300-77
300-77
300-1-77
300-1-77
300-1-77
300-1-77
328-77
Cone.
(ng/m3)
T(55)
T(55)
T(55)
T<55)
T(55)
T(100)
T(98)
1(74)
T(132)
T(96)
T(100)
T(100)
420
1(96)
T(96)
T(77)
T(155)
(continued)
-------
Table D2 (cont'd)
ho
ui
o
EPA
Region Compound CASS # Site
III trichloroethylene 79-01-6 Front Royal, VA
(cont.)
Front Royal , VA .
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
III tetrachloroethylene 127-18-4 South Charleston, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
Baltimore, MD
Baltimore, MD
Baltimore, MD
Baltimore, MD
Baltimore, MD
Belle, WV
South Charleston, WV
Nitro, WV
Bristol, PA
Bristol, FA
Address
Commerce Ave. and
John Marshall Hwy.
13th St. and
Commonwealth Ave.
346 10th St.
1040 Adams Ave.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
346 10th St.
1040 Adams Ave.
4th and C St.
167 llth Ave.
314 4th Ave.
314 4th Ave.
Off Fairfield Rd.
Off Fairfield Rd.
Off Patapsco River
Off North Ridge Ave.
Off Patapsco Ave.
Off Creek St.
Off Kanawha River
Hwy. 60 and WV 25
Off Otter Creek
Off Hwy. 413 in
Roadside Park
Zip
Code
22630
22630
22630
22630
22630
22630
22630
22630
25303
25303
25303
25303
21226
21226
21226
21226
21226
25015
25303
25143
19007
19007
Sampling
Time
1315-0845
1605-2330
1637-2335
1700-2345
1000-1722
1047-1705
1015-1715
1030-1710
1000-1800
0900-1700
1000-1750
0931-1800
1100-1450
2300-0250
1000-1350
1400-1600
1355-1555
1906-2106
1441-1600
1158-1548
1314-1414
1315-1415
Calendar
Day - Year
328-30-77
328-77
328-77
328-77
329-77
329-77
329-77
329-77
255-74
216-75
216-75
220-75
287-75
288-9-75
289-75
292-75
297-75
338-75
337-75
339-75
231-77
231-77
Cone.
(ng/mS)
T(155)
T(155)
T(155)
T(155)
T(155)
T(155)
T(155)
T(155)
(continued)
-------
Table D2 (cont'd)
ro
EPA
Region Compound CASS // Site
III tetrachloroethylene 127-18-4 North Philadelphia, PA
(cont.)
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
Marcus Hook, PA
Marcus Hook, PA
Charleston, WV
South Charleston, WV
St. Albans, WV
W. Belle, WV
South Charleston, WV
St. Albans, WV
Charleston, WV
South Charleston, WV
Nitro, WV
W. Belle, WV
South Charleston, WV
St. Albans, WV
Nitro, WV
Charleston, WV
Address
Belgrade St. and
Pratt St.
Belgrade St.
Bridge St. and
Garden St.
Brill St. bet. Bridge
St. and Richmond
Hwy. 13 and
Smith St.
Off Hwy. 13
4th Ave. W. and
21st St. W.
314 4th Ave.
6500 MacCorkle
Ave. SW
Kanawha Blvd.
314 4th Ave.
6500 MacCorkle
Ave. SW
4th Ave. W. and
21st St. W.
314 4th Ave.
NW of WV 25
and 1-64
Kanawha Blvd.
314 4th Ave.
6400 MacCorkle
Ave. SW
NW of WV 25
and 1-64
4th Ave. and
21st St. W.
Zip
Code
19007
19007
19007
19007
19061
19061
25312
25303
25177
25015
25312
25177
25312
25303
25143
25015
25303
25177
25143
25312
Sampling
Time
1030-1130
1025-1125
1220-1320
1220-1320
1046-1146
1100-1200
1020-1435
1115-1617
1202-1715
1349-1945
0825-1308
0715-1355
0925-0850
1200-1757
1035-1600
1315-1808
0632-1205
0534-1147
0505-1118
1910-1125
Calendar
Day - Year
233-77
233-77
233-77
233-77
234-77
234-77
270-1-77
270-77
270-77
270-77
271-77
271-77
297-9-77
297-77
297-77
297-77
298-77
298-77
298-77
320-2-77
Cone.
(ng/m3)
T(48)
T(35)
T(36)
T(36)
146
T(26)
109
T(36)
T(360)
T(36)
1,536
434
52
T(20)
(continued)
-------
Table D2 (cont'd)
NJ
Ul
EPA
Region Compound CASS t Site
III tetrachloroethylene 127-18-4 South Charleston, WV
(cont.) W. Belle, WV
Nitro, WV
Institute, WV
Charleston, WV
South Charleston, WV
W. Belle, WV
Institute, WV
Nitro, WV
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Address
314 4th Ave.
Kanawha Blvd.
4107 1st Ave.
Barren Dr. bet.
4th St. and
Curtis Sq.
4th Ave. W. and
21st St. W.
314 4th Ave.
Kanawha Blvd.
Barron Dr. bet.
4th St. and
Curtis Sq.
NW of WV 25
and 1-64
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
Commerce Ave. bet.
4th St. and
5th St.
501 Grand Ave.
Commerce Ave. and
John Marshall Hwy.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
8th St. and
Crosby Rd.
Zip
Code
25303
25015
25143
25112
25312
25303
25015
25112
25143
22630
22630
22630
22630
22630
22630
22630
22630
Sampling
Time
1235-1737
1348-1811
1335-1725
1235-1700
1135-0930
0809-1310
0729-1241
0728-1210
0802-1280
1040-1655
1115-1715
1609-1305
1735-0715
2030-0635
0737-1315
0800-1325
1508-2150
Calendar
Day - Year
321-77
321-77
321-77
321-77
322-4-77
322-77
322-77
322-77
-.
322-77
272-77
272-77
272-3-77
272-3-77
272-3-77
273-77
273-77
300-77
Cone.
(ng/m3)
T(19)
T(19)
T(19)
T(19)
T(19)
T(19)
T(19)
T(19)
T(19)
1(36)
20
T(36)
132
26
35
31
380
(continued)
-------
Table D2 (cont'd)
EPA
Region
III
Compound
.,- —^——^—
tetrachloroethylene
(cont.)
CO
. . •
i CASS t Site
flene 127-18-4 Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal , VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Address
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. bet.
4th St. and
5th St.
Commerce Ave. and
John Marshall Hwy.
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. and
John Marshall Hwy.
3rd St. and
Villa Ave.
Commerce Ave. and
John Marshall Hwy.
13th St. and
Commonwealth Ave.
346 10th St.
1040 Adams St.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
346 10th St.
1040 Adams Ave.
Zip
Code
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
Sampling
Time
1455-2115
1520-2120
1550-0850
1925-2315
2155-0520
2115-0555
2126-0620
2330-0645
1540-2315
1315-0845
1605-2330
1637-2335
1700-2345
1000-1722
1047-1705
1015-1715
1030-1710
Calendar
Day - Year
300-77
300-77
300-1-77
300-77
300-1-77
300-1-77
30CH-77
300-1-77
328-77
328-30-77
328-77
328-77
328-77
329-77
329-77
329-77
329-77
Cone.
(ng/m3)
332
36
2,994
T(36)
163
35
388
77
T(19)
1(19)
T(19)
T(19)
T(19)
T(19)
T(19)
T(19)
TU9)
(continued)
-------
Table D2 (cont'd)
ro
Ui
•o
EPA
Region Compound CASS # Site
III chlorobenzene 108-86-1 South Charleston, WV
South Charleston, WV
South Charleston, WV
Baltimore MD
Baltimore MD
Baltimore MD
Baltimore MD
Baltimore MD
Nltro, WV
South Charleston, WV
South Charleston, WV
Nltro, WV
Charleston, WV
South Charleston, WV
W. Belle, WV
Nitro, WV
W. Belle, WV
Nltro, WV
Bristol, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
Address
167 llth Ave.
314 4th Ave.
314 4th Ave.
Off Falrfield Rd.
Off Fairfield Rd.
Off Patapsco River
Off North Ridge Ave.
Off Patapsco Ave.
Hwy. 60 and WV 25
Off Hwy. 64
Off Hwy. 64
NW of WV 25 and
1-64
4th Ave. W. and
21st St. W.
314 4th Ave.
Kanawha Blvd.
NW of WV 25 and
1-64
Kanawha Blvd.
4107 1st Ave.
Off Hwy. 413 in
Roadside Park
Belgrade St.
and Pratt St.
Belgrade St.
Bridge St. and
Garden St.
Zip
Code
25303
25303
25303
21226
21226
21226
21226
21226
25143
25303
25303
25143
26312
25303
25015
25143
25015
25143
19007
19007
19007
19007
Sampling
Time
0900-1700
1000-1750
0931-1800
1100-1450
2300-0250
1000-1350
1400-1600
1355-1555
1158-1548
1605-1341
1349-1010
1400-1610
0925-0850
1200-1737
1315-1808
0505-1118
1348-1811
1335-1725
1315-1415
1030-1130
1025-1125
1220-1320
Calendar
Day - Year
216-75
216-75
220-75
287-75
288-75
289-75
292-75
297-75
339-75
082-4-77
084-6-77
270-77
-
297-9-77
297-77
298-77
298-77
321-77
321-77
231-77
233-77
233-77
233-77
Cone.
(ng/n.3)
1(319)
1(349)
T(32)
T(29)
T(56)
1(36)
T(37)
T(18)
T(18)
448
+ 190
T(278)
T(238)
T(278)
(continued)
-------
Table D2 (cont'd)
Ul
01
EPA
Region Compound CASS t Sice
III chlorobenzene 108-86-1 North Philadelphia, PA
(cont.)
Marcus Hook, PA
Marcus Hook, PA
Institute, WV
Charleston, WV
South Charleston, WV
W. Belle, WV
Institute, WV
Nltro, WV
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Address
Brill St. bet.
Bridge St.
and Richmond
Hwy. 13 and
Smith St.
Off Hwy. 13
Barron Dr. bet.
4th St. and
Curtis Sq.
4th Ave. U. and
21st St. W.
314 4th Ave.
Kanawha Blvd.
Barron Dr. bet.
4th St. and
Curtis Sq.
NW of WV 25 and
1-64
Commerce Ave. and
John Marshall Hwy.
3rd St. and
Villa Ave.
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. bet.
4th St. and
5th St.
Zip
Code
19007
19061
19061
25112
25312
25303
25015
25112
25143
22630
22630
22630
22630
22630
22630
Sampling
Time
1220-1320
1046-1146
1100-1200
1235-1700
1135-0930
0809-1310
0729-1241
0728-1210
0802-1250
2030-0636
0737-1315
1508-2150
1455-2115
1520-2120
1550-0850
Calendar
Day - Year
233-77
234-77
234-77
321-77
322-4-77
322-77
322-77
322-77
322-77
272-3-77
273-77
300-77
300-77
300-77
300-1-77
Cone.
(ng/m3)
T(250)
T(278)
T(242)
T(18)
T(18)
T(18)
T(18)
T(18)
1(18)
T(26)
T(44)
T(38)
1(36)
T(32)
T(82)
(continued)
-------
Table D2 (cont'd)
to
EPA
Region Compound CASS It Site
III chlorobenzene 108-86-1 North Philadelphia, PA
(cont.)
Marcus Hook, PA
Marcus Hook, PA
Institute, WV
Charleston, WV
South Charleston, WV
W. Belle, WV
Institute, WV
Micro, WV
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Address
Brill St. bet.
Bridge St.
and Richmond
Hwy. 13 and
Smith St.
Off Hwy. 13
Barron Dr. bet.
4th St. and
Curtis Sq.
4th Ave. W. and
21st St. W.
314 4th Ave.
Kanawha Blvd.
Barron Dr. bet.
4th St. and
Curtis Sq.
NW of WV 25 and
1-64
Commerce Ave. and
John Marshall Hwy.
3rd St. and
Villa Ave.
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Crand Ave.
Commerce Ave. bet.
4th St. and
5th St.
Zip
Code
19007
19061
19061
25112
25312
25303
25015
25112
25143
22630
22630
22630
22630
22630
22630
Sampling
Time
1220-1320
1046-1146
1100-1200
1235-1700
1135-0930
0809-1310
0729-1241
0728-1210
0802-1250
2030-0636
0737-1315
1508-2150
1455-2115
1520-2120
1550-0850
Calendar
Day - Year
233-77
234-77
234-77
321-77
322-4-77
322-77
322-77
322-77
322-77
272-3-77
273-77
300-77
300-77
300-77
300-1-77
Cone.
(ng/m3)
T(250)
T(278)
T(242)
T(18)
1(18)
T(18)
T(18)
T(18)
T(18)
T(26)
T(44)
T(38)
T(36)
T(32)
T(82)
(continued)
-------
Table D2 (cont'd)
EPA
Region Compound
III chlorobenzene
(cont.)
Ill m-dichlorobenzene
CASS It Site
108-86-1 Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
541-73-1 Baltimore, MD
Baltimore, MD
Baltimore, MD
Baltimore, MD
Belle, WV
South Charleston, WV
Nitro, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
St. Albans, WV
Nitro, WV
Address
3rd St. and
Villa Ave.
Commerce Ave. and
John Marshall Hwy.
13th St. and
Commonwealth Ave.
346 10th St.
1040 Adams Ave.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
346 10th St.
1040 Adams Ave.
Off Fairfield Rd.
Off Fairfield Rd.
Off Patapsco River
Off Patapsco Ave.
Off Creek St.
Off Kanawha River
Hwy. 60 and WV 25
Off Hwy. 64
Off Hwy. 64
Off Hwy. 64
Off Hwy. 64
Off Hwy. 64
314 4th Ave.
6500 MacCorkle
Ave. SW
NW of WV 25 and
1-64
Zip
Code
22630
22630
22630
22630
22630
22630
22630
22630
22630
21226
21226
21226
21226
25015
25303
25143
25303
25303
25303
25303
25303
25303
25177
25143
Sampling
Time
1540-2315
1315-0845
1605-2330
1637-2335
1700-2345
1000-1722
1047-1705
1015-1715
1030-1710
1100-1450
2300-0250
1000-1350
1355-1555
1906-2106
1441-1600
1158-1548
1302-1450
1508-1639
1640-1558
1604-1341
1349-1010
1115-1617
1202-1715
1400-1610
Calendar
Day - Year
328-77
328-30-77
328-77
328-77
328-77
329-77
329-77
329-77
329-77
287-75
288-9-75
289-75
297-75
338-75
337-75
339-75
076-8-77
078-80-77
080-2-77
082-4-77
084-6-77
270-77
270-77
270-77
Cone .
(ng/m3)
T(18)
T(18)
T(18)
T(18)
T(18)
T(18)
T(18)
T(18)
T(18)
T
T
T
T
T
T(28)
T(18)
T(20)
(continued)
-------
Table D2 (cont'd)
00
EPA
Region Compound CASS # Site
III m-dichlorobenzene 541-73-1 Nitro, WV
(cont.) Institute, WV
W. Belle, WV
Institute, WV
Nitro, WV
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Front
Royal ,
Royal,
Royal ,
Royal ,
Royal ,
Royal ,
Royal ,
Royal ,
Royal ,
Royal ,
Royal ,
Royal ,
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
VA
Address
4107 1st Ave.
Barron Dr. bet.
4th St. and
Curtis Sq.
Kanawha Blvd .
Barron Dr. bet.
4th St. and
Curtis Sq.
NW of WV 25 and
1-64
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. bet.
4th St. and
5th St.
501 Grand Ave.
Commerce Ave. and
John Marshall Hwy.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. bet.
4th St. and
5th St.
8th St. and
Crosby Rd.
Zip
Code
25143
25112
25015
25112
25143
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
Sampling
Time
1335-1725
1235-1700
0729-1241
0728-1210
0802-1250
1115-1715
1140-1728
1609-1305
1735-0715
2030-0635
0737-1315
0800-1325
1508-2150
1455-2115
1520-2120
1550-0850
2155-0520
Calendar
Day - Year
321-77
321-77
322-77
322-77
322-77
272-77
272-77
272-3-77
272-3-77
272-3-77
273-77
273-77
300-77
300-77
300-77
300-1-77
300-1-77
Cone .
(ng/D3)
T(12)
T(12)
T(9)
T(9)
T(9)
T(27)
T(18)
22
8
T(18)
T(17)
T(31)
35
T(24)
1(21)
279
T(26)
(continued)
-------
Table D2 (cont'd)
Cn
VO
EPA
Region Compound CASS # Site
III ra-dichlorobenzene 541-73-1 W. Belle, WV
(cont.) South Charleston, WV
Bristol, PA
Bristol, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
Marcus Hook, PA
Marcus Hook, PA
Charleston, WV
South Charleston, WV
Nitro, WV
W. Belle, WV
South Charleston, WV
St. Albans, WV
Nitro, WV
South Charleston, WV
W. Belle, WV
Address
Kanawha Blvd.
314 4th Ave.
Off Otter Creek
Off Hwy. 413 in
Roadside Park
Belgrade St. and
Pratt St.
Belgrade St.
Bridge St. and
Garden St.
Brill St. bet.
Bridge St. and
Richmond
Hwy. 13 and
Smith St.
Off Hwy. 13
4th Ave. W. and
21st St. W.
314 4th Ave.
NW of WV 25 and
1-64
Kanawha Blvd.
314 4th Ave.
6500 MacCorkle
Ave. SW
NW of WV 25 and
1-64
314 4th Ave.
Kanawha Blvd.
Zip
Code
25015
25312
19007
19007
19007
19007
19007
19007
19061
19061
25312
25303
25143
25015
25303
25177
25143
25303
25015
Sampling
Time
1349-1945
0825-1308
1314-1414
1315-1415
1030-1130
1025-1125
1220-1320
1220-1320
1046-1146
1100-1200
0925-0850
1200-1737
1035-1600
1315-1808
0632-1205
0534-1147
0505-1118
1235-1737
1348-1811
Calendar
Day - Year
270-77
271-77
231-77
231-77
233-77
233-77
233-77
233-77
234~-77
234-77
297-9-77
297-77
297-77
297-77
298-77
298-77
298-77
321-77
321-77
Cone.
(ng/m3)
T(18)
38
T(182)
T(172)
T(159)
T(185)
T(167)
T(185)
1(161)
T(182)
101
1(37)
1(27)
T(240
276
1(23)
T(24)
T(12)
T(8)
(continued)
-------
Table D2 (cont'd)
EPA
Region Compound
III m-dichlorobenzene
(cont.)
Ill o-dichlorobenzene
CASS # Site
541-73-1 Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
95-50-1 South Charleston, WV
Dunbar, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
Baltimore, MD
Baltimore, MD
Nitro, WV
South Charleston, WV
South Charleston, WV
South Charleston, WV
Nitro, WV
South Charleston, WV
Address
501 Grand Ave.
3rd St. and
Villa Ave.
Commerce Ave . and
John Marshall Hwy.
13th St. and
Commonwealth Ave.
346 10th St.
1040 Adams Ave.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
346 10th St.
1040 Adams Ave.
4th and C St.
llth and Myers
167 llth Ave.
314 4th Ave.
314 4th Ave.
Off Fairfield Rd.
Off Patapsco Rd.
Hwy. 60 and WV 25
314 4th Ave.
314 4th Ave.
314 4th Ave.
NW of WV 25 and
1-64
314 4th Ave.
Zip
Code
22630
22630
22630
22630
22630
22630
22630
22630
22630
22630
25303
25064
25303
25303
25303
21226
21226
25143
25303
25303
25303
25143
25303
Sampling
Time
2126-0620
1540-2315
1315-0845
1605-2330
1637-2335
1700-2345
1000-1722
1047-1705
1015-1715
1030-1710
1000-1800
1015-1815
0900-1700
1000-1750
0931-1800
1100-1450
1000-1350
1158-1548
1115-1617
0825-1308
1200-1737
1035-1600
0632-1205
Calendar
Day - Year
300-1-77
328-77
328-30-77
328-77
328-77
328-77
329-77
329-77
329-77
329-77
255-74
254-74
216-75
216-75
220-75
287-75
289-75
339-75
270-77
271-77
297-77
297-77
298-77
Cone.
(ng/m3)
T(14)
T(9)
T(9)
T(9)
T(9)
T(9)
T(9)
T(9)
T(9)
T(9)
1(17)
T(18)
1(37)
T(27)
306
(continued)
-------
Table D2 (cont'd)
N)
EPA
Region Compound CASS It Site
III o-dichlorobenzene 95-50-1 St. Albans, WV
(cont . )
Nitro, WV
W. Belle, WV
Nitro, WV
Institute, WV
South Charleston, WV
W. Belle, W
Institute, WV
Nitro, WV
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Address
6500 MacCorkle
Ave. SW
NW of WV 25 and
1-64
Kanawha Blvd .
4107 1st Ave.
Barron Dr. bet.
4th St. and
Curtis Sq.
314 4th Ave.
Kanawha Blvd.
Barron Dr. bet.
4th St. and
Curtis Sq.
NW of WV 25 and
1-64
501 Grand Ave.
Commerce Ave. and
John Marshall Hwy
13th St. and
Commonwealth Ave.
8th St. and
Crosby Rd.
3rd St. and
Villa Ave.
501 Grand Ave.
Commerce Ave. bet.
4th St. and
5th St.
Zip
Code
25177
25143
25015
25143
25112
25303
25015
25112
25143
22630
22630
22630
22630
22630
22630
22630
Sampling
Time
0534-1147
0505-1118
1348-1811
1335-1725
1235-1700
0809-1310
0729-1241
0728-1210
0802-1250
1235-0715
2030-0635
0800-1325
1508-2150
1455-2115
1520-2120
1550-0850
Calendar
Day - Year
298-77
298-77
321-77
321-77
321-77
322-77
322-77
322-77
.
322-77
272-3-77
272-3-77
273-77
300-77
300-77
300-77
300-1-77
Cone.
(ng/m3)
T(23)
39
T(8)
T(12)
59
T(9)
T(9)
T(9)
T(9)
T(13)
TC18)
T(31)
58
T(24)
T(21)
T(55)
(continued)
-------
Table D2 (cont'd)
EPA
Region Compound CASS # Site
III o-dichlorobenzene 95-50-1 Front Royal, VA
(cont.) Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Front Royal, VA
Bristol, PA
North Philadelphia, PA
North Philadelphia, PA
North Philadelphia, PA
III trichlorobenzene 12002-48-1 South Charleston, WV
[isomer(s)] Dunbar, WV
Baltimore, MD
Front Royal, VA
Bristol, PA
North Philadelphia, PA
North Philadelphia, PA
Address
501 Grand Ave.
3rd St. and
Villa Ave.
Commerce Ave. and
John Marshall Hwy.
346 10th St.
1040 Adams Ave.
3rd St. and
Villa Ave.
13th St. and
Commonwealth Ave.
346 10th St.
1040 Adams Ave.
Off Hwy. 413
Belgrade St.
Bridge St. and
Garden St.
Brill St. bet.
Bridge St. and
Richmond
4th and C St.
llth and Myers
Off Fairfield Rd.
13th St. and
Commonwealth Ave.
Off Hwy. 413
Belgrade St.
Brill St. bet.
Bridge St. and
Richmond
Zip
Code
22630
22630
22630
22630
22630
22630
22630
22630
22630
19007
19007
19007
19007
25303
25064
21226
22630
19007
19007
19007
Sampling
Time
2126-0620
1540-2315
1315-0845
1637-2335
1700-2345
1000-1722
1047-1705
1015-1715
1030-1710
1315-1415
1025-1125
1220-1320
1220-1320
1000-1800
1015-1815
1100-1450
1637-2335
1315-1415
1025-1125
1220-1320
Calendar
Day - Year
300-1-77
328-77
328-30-77
328-77
328-77
329-77
329-77
329-77
329-77
231-77
233-77
233-77
232-77
255-74
254-74
287-75
328-77
231-77
233-77
233-77
Cone .
(ng/m3)
38
1(9)
T(9)
T(9)
L \y j
T(9)
1(9)
T(9)
T(9)
T(9)
T(172)
185
T(167)
T(185)
T(7)
T(103)
11
T(92)
-------
Table D3. VAPOR-PHASE HALOGENATED CHEMICALS - EPA REGION IV
EPA
Region
IV
IV
IV
IV
IV
Compound CASS t Site
methylene chloride 75-09-2 Birmingham,
Birmingham,
Birmingham,
Birmingham,
chloroform 67-66-3 Birmingham,
Birmingham,
Birmingham,
Birmingham,
carbon tetrachloride 56-23-5 Birmingham,
Birmingham,
Birmingham,
Birmingham,
Birmingham,
1, 2-d ichloroethane 107-06-2 Birmingham,
Birmingham,
1,1, 1-tr ichloroethane 71-55-6 Birmingham,
Birmingham,
Birmingham,
Birmingham,
Birmingham,
Address
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
Zip
Code
35207?
35207
35207
35207
35207?
35207
35207
35207
35207?
35207
35207
35207
35207
35207
35207
35207?
35207
35207
35207
35207
Sampling
Time
1616-1630
1615-1715
1830-1400
1445-1430
1616-1630
1830-1435
1830-1400
1445-1430
1616-1630
1830-1435
1615-1715
1830-1400
1445-1430
1830-1435
1616-1715
1616-1630
1830-1435
1615-1715
1830-1400
1445-1430
Calendar
Day - Year
102-4-77
106-8-77
108-10-77
110-2-77
102-4-77
104-6-77
108-10-77
110-2-77
102-4-77
104-6-77
106-8-77
108-10-77
110-2-77
104-6-77
106-8-77
102-4-77
104-6-77
106-8-77
108-10-77
110-2-77
Cone.
(ng/m3)
286
T(715)
T(715)
1,074
±3,590
375
146
±21
T(125)
1,096
±690
T(95)
T(95)
T(95)
T(95)
T(95)
205
±12
399
±52
2,267
2,067
' ±267
2,100
±233
1,867
T(334)
(continued)
-------
Table D3 (cont'd)
EPA
Region Compound CABS # Site
IV trichloroethylene 79-01-6 Birmingham,
Birmingham,
Birmingham,
Birmingham,
Birmingham,
IV tetrachloroethylene 127-18-4 Birmingham,
Birmingham,
Birmingham,
Birmingham,
Birmingham,
IV ' chlorobenzene 108-90-7 Birmingham,
Birmingham,
Birmingham,
Birmingham,
Birmingham,
IV m-dichlorobenzene 541-73-1 Birmingham,
Birmingham,
Birmingham,
Birmingham,
Birmingham,
Address
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
Off
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
N ?
Zip
Code
35207?
35207
35207
35207
35207
35207?
35207
35207
35207
35207
35207?
35207
35207
35207
35207
35207?
35207
35207
35207
35207
Sampling
Time
1616-1630
1830-1435
1615-1715
1830-1400
1445-1430
1616-1630
1830-1435
1615-1715
1830-1400
1445-1430
1616-1630
1830-1435
1615-1715
1830-1400
1445-1430
1616-1630
1830-1435
1615-1715
1830-1400
1445-1430
Calendar
Day - Year
102-4-77
104-6-77
106-8-77
108-10-77
110-2-77
102-4-77
104-6-77
106-8-77
108-10-77
110-2-77
102-4-77
104-6-77
106-8-77
108-10-77
110-2-77
102-4-77
104-6-77
106-8-77
108-10-77
110-2-77
Cone .
(ng/m3)
T(100)
134
± 2
T(100)
T(100)
1(100)
T(25)
58
±7
T(65)
T(65)
T(65)
38
122
±54
92
±42
T(141)
1,000
1(188)
278
±19
557
±196
T(94)
T(94)
(continued)
-------
Table D3 (cont'd)
EPA
Region Compound TS&SS //
IV o-dichlorobenzene 95-50-1
IV methylene chloride 75-09-2
IV chloroform 67-66-3
IV 1,1,1-trichloroethane 71-55-6
Site
Birmingham , AL
Birmingham, AL
Birmingham, AL
St. Ann, MO
St. Louis, MO
St. Ann, MO
St. Louis, MO
St. Louis, MO
St. Ann, MO
Address
Off St. 30 N ?
Off St. 30 N ?
Off St. 30 N ?
St. Charles Rd. and
Industrial Blvd.
4400 Lindell
St. Charles Rd. and
Industrial Blvd.
4400 Lindell
4400 Lindell
St. Charles Rd. and
Industrial Blvd.
Zip
Code
35207?
35207
35207
63074
63108
63074
63108
63108
63074
Sampling
Time
1616-1630
1830-1400
1445-1430
2035-0525
0650-1250
2035-0525
0650-1250
2212-0235
2035-0525
Calendar
Day - Year
102-4-77
108-10-77
110-2-77
251-2-75
253-75
251-2-75
253-75
2523-75
251-2-75
Cone.
(ng/m3)
T(189)
T(94)
348
-------
Table D4. VAPOR-PHASE HALOGENATED CHEMICALS - EPA REGION VI
ON
EPA
Region Compound CASS f Site
VI chloromethane 74-87-3 Pasadena, TX
Houston, TX
Houston, TX
Pasadena, IX
Pasadena, TX
Pasadena, TX
Baton Rouge , LA
El Dorado, AK
El Dorado, AK
El Paso, IX
El Paso, TX
VI vinyl chloride 75-01-4 Pasadena, TX
Deer Park, TX
Deer Park, TX
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Address
Shaw Dr.
5609 May St.
May St.
Mae St.
Shaw Dr.
C. H. Milby Park
Off unpaved, un-
marked road
Hwy. 167
Hwy. 167
Shaw Dr.
Diamond Shamrock
Property
Off Tidal Road
Bayou Road
Church & Main St.
LA 988 & Davis St.
50 yd. east off
LA IN
East off LA 1
Off LA 1
Off LA 1
Plaquemine Ever-
green Plantation
Plaquemine Ever-
green Plantation
Zip
Code
77506
77076
77076
77502
77506
77017
70807
71730
71730
77506
77536
77536
70764
70764
70764
70764
70764
70764
70764
70764
70764
Sampling
Time
1130-1130
1630-1630
1245-2400
1000-1000
1000-1000
1005-1425
1207-1237
1140-1415
1140-1411
1150-1245
1218-1330
1130-1130
1455-1555
1115-1215
1437-1320
1540-1350
1255-1705
1430-1740
1445-1755
1600-1015
1745-1015
1250-1725
1325-1715
Calendar
Day - Year
315-6-74
320-1-74
235-75
237-8-75
238-9-75
241-75
63-77
265-76
265-76
99-101-78
99-101-78
315-6-74
211-76
212-76
31-2-77
31-2-77
32-77
32-77
32-77
32-3-77
32-3-77
33-77
33-77
Cone.
(ng/m3)
T
100
192
1,230
30
T
59
534
1,334
64
76
(continued)
-------
Table D4 (cont'd)
ro
EPA
Region Compound CASS // Site
VI methyl bromide 74-83-9 El Dorado, AK
El Dorado, AK
Magnolia, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
VI ethyl chloride 75-00-3 Pasadena, TX
Houston, TX
Houston, TX
Pasadena, TX
Pasadena, TX
Deer Park, TX
Freeport, TX
Freeport, TX
Plaquemine, LA
Plaquemine, LA
Geismar, LA
VI vinylidene chloride 75-35-4 Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Geismar, LA
Geisaar, LA
Liberty Hounds, OK
Tulsa, OK
Houston, TX
Houston, TX
Address
Hwy. 167
Hwy. 167
Hwy. 79
Off Hwy. 15
Off Hwy. 15
Off Hwy. 15
Shaw Dr.
5609 May St.
May St.
Shaw Dr.
C. H. Milby Park
Off Tidal Rd.
Off St. 325
Off St. 325
Off LA 1
Off LA 1
Hwy. 73
Bayou Rd.
Church & Main St.
Off LA 1
Off LA 1
Hwy. 73
Hwy. 73
District Water
Works
2nd & Elwood
Aldine (Mail Rt.)
Aldine (Mail Rt.)
Zip
Code
71730
71730
71753
71730
71730
71730
77506
77076
77076
77506
77017
77536
77541
77541
70764
70764
70734
70764
70764
70764
70764
70734
70734
74047
74103
77037
or 9
77037
or 9
Sampling
Time
1140-1415
1120-1625
1355-1903
1329-1257
1329-1257
1329-1257
1130-1130
1630-1630
1245-2400
1000-1000
1005-1425
1100-1200
1348-1555
1425-1508
1745-1015
1600-1015
1155-1615
1437-1320
1540-1350
1600-1015
1745-1015
1155-1615
1615-1220
0355-0355
0600-0600
0630-0930
1207-1510
Calendar
Day - Year
265-76
265-76
267-76
138-9-78
138-9-78
138-9-78
315-6-74
320-1-74
235-75
238-9-75
241-75
211-76
221-76
221-76
32-3-77
32-3-77
60-77
31-2-77
31-2-77
32-3-77
32-3-77
60-77
60-1-77
191-2-77
192-3-77
232-77
293-77
Cone .
(ng/m3)
T
T
T
1,378
128
36
132
990
T
200
T
T
427 + 27
T (334)
(continued)
-------
Table D4 (cont'd)
to
o\
oo
EPA
Region Compound CASS # Sice
VI bromoethane 74-96-4 El Dorado, AK
El Dorado, AK
VI methylene chloride 75-09-2 Pasadena, TX
Bay town, IX
Texas City, TX
Houston, TX
Houston, TX
Pasadena, IX
Pasadena, IX
Texas City, TX
Texas City, TX
Pasadena, TX
Houston, IX
Houston, IX
Pasadena, TX
Pasadena, IX
Pasadena, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Freeport, TX
Freeport, TX
Address
Hwy. 167
Hwy. 167
Shaw Dr.
7200 Bayway Dr.
5609 May St.
May St.
Mae St.
Mae St.
Connie #10
Connie #10
C. H. Milby Park
Milby Park
Steelman Ave S. E.
& Buey Way
Between industrial
site and ship
channel
Off Hwy. 225
Near Houston ship
channel
Off Tidal Rd.
Off 225
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off St. 352
Off St. 352
Zip
Code
71730
71730
77506
77520
77590
77076
77076
77502
77502
77590
77590
77017
77017
77017
77503
77503
77503
77536
77536
77536
77536
77536
77536
77536
77541
77541
Sampling
Time
1140-1415
1140-1415
1130-1130
1630-1630
1415-1415
1630-1630
1245-2400
1430-2200
1000-1000
1200-2235
2235-1155
1005-1425
1670-1750
1620-1750
1430-1600
1430-1600
1430-1600
1100-1200
1100-1200
1455-1555
1020-1035
1115-1215
1455-1555
1115-1215
1348-1555
1425-1508
Calendar Cone.
Day - Year (ng/m^)
265-76
265-76
315-6-74
317-8-74
316-7-74
320-1-74
235-75
237-75
237-8-75
239-75
239-40-75
241-75
209-76
209-76
210-76
210-76
210-76
211-76
211-76
211-76
212-76
212-76
211-76
212-76
221-76
221-76
(continued)
-------
Table D4 (cont'd)
EPA
Region Compound CASS # Site
VI methylene chloride 75-09-2 Plaquemine, LA
Plaquemine, LA
(contl) Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar , LA
Geismar, LA
Geismar, LA
Geismar , LA
Geismar, LA
Geismar, LA
Geismar, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Address
Bayou Rd.
Church & Main St.
LA 988 & Davis St.
50 yd. east off LA IN
East of LA 1
Off LA 1
Off LA 1
Plaquemine Ever-
green Plantation
Plaquemine Ever-
green Plantation
Plaquemine Ever-
green Plantation
Plaquemine Ever-
green Plantation
Corner of Hwy. 73 '&
75
Vulcan Rd.
Hwy. 73
Between Hwy. ' 90
& 73
Off LA 73
Hwy. 73
Off Hwy. 73
Off LA 75
Off Hwy. 75
Off Hwy. 30
Off U. S. 61
Off unpaved, un-
marked road
Off U. S. 61
Off unpaved, un-
marked road
East side of LA 61
Off U. S. 61
Zip
Code
70764
70764
70764
70764
70764
70764
70764
70764
70764
70764
70764
70734
70734
70734
70734
70734
70734
70734
70734
70734
70734
70807
70807
70807
70807
70807
70807
Sampling
Time
1437-1320
1540-1350
1255-1705
1430-1740
1445-1755
1600-1015
1745-1015
1250-1725
1325-1715
1400-1630
1705-1020
1545-1503
1630-1550
1155-1615
1215-1240
1620-1537
1615-1220
1025-1240
1620-1537
1330-1400
1603-1220
1150-1110
1135-1130
1220-1615
1207-1237
1205-1630
1235-1550
Calendar
Day - Year
31-2-77
31-2-77
32-77
32-77
32-77
32-3-77
32-3-77
33-77
33-77
33-77
33-4-77
59-60-77
59-60-77
60-77
60-77
59-60-77
60-1-77
61-77
59-60-77
60-77
60-1-77
62-3-77
62-3-77
62-77
63-77
67-77
67-77
Cone.
(ng/n.3)
1,700
1,909
727
1,714
700
545
772
442
2,333
454
2,800
2,160
280
1,999
160
280
(continued)
-------
Table D4 (cont'd)
FPA
Region Compound CASS f Site
VI methylene chloride 75-09-2 Baton Rouge, LA
(c°nt-) Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge , LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Liberty Mounds, OK
Tulsa, OK
Liberty Mounds, QK
Address
Off of Turning
Basin Rd.
Graveyard area
Mengel Rd.
Off LA 61
Off Mengel Rd.
Off LA 190
Off Mengel Rd.
Off LA 61
Choctaw Rd. &
LA 1 6. LA 190
Downwind of several
petroleum faci-
lities
Hwy. 167
Hwy. 167
AK City Water
Tower
Parker's Chapel
Water Tower
Hwy. 167
Hwy. 167
Hwy- 167
Devil's Swamp
Devil's Swamp
Devil's Swamp
Devil's Swamp
District Water
Works
2nd & Elwood
District Water
Works
Zip
Code
70807
70807
70807
70805
70807
70807
70807
70805
70805
70807
70807
71730
71730
71730
71730
71730
71730
71730
74047
74103
74047
Sampling
Time
1625-1215
1640-1030
1330-1640
1400-1700
1650-1100
1715-1115
1105-1505
1140-1550
1215-1610
1700-0900
1530-0930
1330-1530
1325-1524
2000-0900
2130-0930
1140-1415
1140-1411
1140-1415
1935-1430
1515-1530
1535-1400
1400-0900
0355-0355
0600-0600
0600-0900
Calendar
Day - Year
67-8-77
67-8-77
68-77
68-7-77
68-9-77
68-9-77
69-77
69-77
69-77
69-70-77
69-70-77
264-76
264-76
268-9-76
268-9-76
265-76
265-76
265-76
132-4-77
134-6-77
136-8-77
138-40-77
191-2-77
192-3-77
264-77
Cone.
(ng/m3)
840
440
240
160
320 + 76
220
280
320
160
680
160
1129 +
1449 +
1900 +
1,000
229
337
900
(continued)
-------
Table D4 (cont'd)
to
EPA
Region Compound CASS // Sice
VI methylene chloride 75-09-2 Tulsa, OK
(cont.) Vera, OK
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Dorado, AK
El Dorado, AK
El Dorado, AK
Address
2nd & Elwood
• -
Aldine (Mail Rt.)
Clan ton Dr.
Clanton Dr.
Aldine (Mail Rt.)
Crawford at Polk
Aldine (Mail Rt.)
Crawford at Polk
Clanton Dr.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Hwy. 10
Hwy. 10
Hwy- 10
Off Hwy . IS
Off Hwy. 15
Off Hwy. 15
Zip
Code
74103
74082
77037
or 9
77080
77080
77037
or 9
77002
77037
or 9
77002
77080
77003
or 11
77003
or 11
77003
or 11
77003
or 11
77003
or 11
79902
79902
79902
71730
71730
71730
Sampling
Time
0600-0900
1400-1700
0945-1245
0745-1050
0630-0930
0630-0930
0615-0915
1207-1510
1546-1853
0607-0907
1730-0930
1000-0900
1030-0915
0915-0945
1000-1015
1150-1245
1150-1245
1218-1330
1015-1145
1015-1145
0918-1235
1329-1257
1329-1257
1329-1257
Calendar
Day - Year
264-77
264-77
173-77
179-77
231-77
232-77
292-77
293-77
294-77
294-77
195-7-77
202-4-77
204-6-77
206-8-77
208-10-77
99-101-78
99-101-78
99-101-78
115-117-78
115-117-78
115-117-78
138-9-78
138-9-78
138-9-78
Cone.
(ng/m3)
4375 + 3125
2736 + 1014
1100 + 100
1000 + 0
4142 + 428
3428
1000
4500 + 1643
(continued)
-------
Table DA (cont'd)
10
~j
N3
EPA
Region Compound
VI 1, 1-dichloroethane
VI chloroform
CASS # Site
75-34-3 Deer Park, TX
Freeport, TX
Plaquemine , LA
Plaquemine , LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
67-66-3 Pasadena, TX
Texas City, TX
Houston, TX
Houston, TX
Pasadena, TX
Pasadena, TX
Pasadena, TX
Texas City, TX
Texas City, TX
Pasadena, TX
Houston, TX
Houston, TX
Pasadena, TX
Pasadena, TX
Pasadena, TX
Deer Park, TX
Address
Off Hwy. 225
Off St. 325
Off LA 1
Off LA 1
Hwy. 73
Between Hwy. 30 & 73
Hwy. 73
Off Hwy. 73
Off Hwy. 73
Off US 61
Mengel Rd.
Off Mengel Rd.
Off LA 61
Downwind of several
petroleum facilities
Shaw Dr.
-
5609 May St.
May St.
Mae St.
Shaw Dr.
Shaw Dr.
Connie #10
Connie #10
C. H. Milby Park
Milby Park
Steelman Ave. & El
Buey Way
Between industrial
site & shl channel
Off Hwy. 225
Near Houston ship
channel
Off Tidal Rd.
Zip
Code
77536
77541
70764
70764
70734
70734
70734
70734
70734
70807
70807
70807
70805
70807
77506
77590
77076
77076
77502
77506
77506
77590
77590
77017
77017
77017
77503
77503
77503
77536
Sampl ing
Time
1100-1200
1425-1508
1600-1015
1745-1015
1155-1615
1215-1240
1615-1220
1025-1240
1603-1220
1235-1550
1330-1640
1105-1505
1140-1550
1530-0930
1130-1130
1415-1415
1630-1630
1245-2400
1430-2200
1000-1000
2230-1017
1200-2235
2235-1155
1005-1425
1670-1750
1620-1750
1430-1600
1430-1600
1430-1600
1100-1200
Calendar
Day - Year
211-76
221-76
32-3-77
32-3-77
60-77
60-77
60-1-77
61-77
60-1-77
67-77
68-77
69-77
69-77
69-70-77
315-6-74
316-7-74
320-1-74
235-75
237-75
238-9-75
238-9-75
239-75
239-40-75
241-75
209-76
209-76
210-76
210-76
210-76
211-76
Cone.
(ng/m3)
555
T
478 + 56
235
75
550
133
167
68
90
34
64
477
11,539
11,538
T
T
T
53,846
(continued)
-------
Table D4 (cont'd)
co
EPA
Region Compound
VI chloroform (cent,):
CASS t site
67-66-3 Deer Park, TX
Deer Park, XX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Freeport, TX
Freeport, TX
Freeport, TX
La Porte, TX
La Porte, TX
La Porte, TX
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine , LA
Plaquemine , LA
Plaquemine, LA
Plaquemine , LA
Plaquemine, LA
Plaquemine, LA
Plaquemine , LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Address
Off Hwy. 225
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off St. 352
Off St. 352
Off St. 352
Off Hwy. 225
Off Hwy. 225
Off Hwy. ''225
Bayou Rd.
Church & Main St.
East Off LA 1
50 yd. East Off LA IN
Off LA 1
Off LA 1
Plaquemine Evergreen
Plantation
Plaquemine Evergreen
Plantation
Plaquemine Evergreen
Plantation
Plaquemine Evergreen
Plantation
Corner of Hwy. 73 & 75
Vulcan Rd.
Hwy. 73
Between Hwy. 30 & 73
Off LA 75
Hwy. 73
Off Hwy. 73
Off LA 75
Up
('.ode
77536
77536
77536
77536
77536
77536
77541
77541
77541
77571
77571
77571
70764
70764
70764
70764
70764
70764
70764
70764
70764
70764
70734
70734
70734
70734
70734
70734
70734
70734
Sampling
Time
1100-1200
1455-1555
1020-1035
1115-1215
1455-1555
1115-1215
1342-1543
1348-1555
1425-1508
1645-1833
1641-1824
1114-1252
1437-1320
1540-1350
1445-1755
1430-1740
1600-1015
1745-1015
1250-1725
1325-1715
1300-1630
1705-1020
1545-1503
1630-1550
1155-1615
1215-1240
1620-1537
1615-1220
1025-1240
1620-1537
Calendar
Day - Year
211-76
211-76
212-76
212-76
211-76
212-76
221-76
221-76
221-76
224-76
224-76
225-76
31-2-77
31-2-77
32-77
32-77
32-3-77
32-3-77
33-77
33-77
33-77
33-4-77
59-60-77
59-60-77
60-77
60-77
59-60-77
60-1-77
61-77
59-60-77
Cone.
(ng/m3)
6,420
7,692
1,923
8,846
T
15,384
280
T
8,461
8,850
7,692
1,988 + 122
419 + 0
956 + 112
633 + 10
2433 + 100
5866 + 688
1080 + 468
511 + 327
1387 + 161
1113 + 274
1,571
3,057
3,000
11,742
857
9,943
999
943
(continued)
-------
Table D4 (cont'd)
EPA
Region Compound CASS t Site
VI chloroform (cont) 67-66-3 Gelsmar, LA
Geismar , LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge , LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge , LA
Baton Rouge , LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Address
Off Hwy. 75
Off Hwy. 30
Off US 61
Off unpaved, unmarked
road
Off US 61
Off US 61
Off unpaved, unmarked
road
East side of LA 61
Off US 61
Off of Turning
Basin Rd
Graveyard Area
Mengel Rd.
Off LA 61
Off Mengel Rd.
Off LA 190
Off Mengel Rd.
Off LA 61
Choc taw Rd. and
Pholox St.
LA 1 and LA 190
Downwind of several
petroleum facilities
Hwy. 167
Hwy. 167
Arkansas City Water
Tower
Parker's Chapel Water
Tower
Hwy. 167
Hwy. 167
Hwy. 167
Hwy. 167
Zip
Code
70734
70734
70807
70807
70807
70807
70807
70807
70807
70807
70807
70807
70805
70807
70807
70807
70805
70805
70807
70807
71730
71730
71730
71730
71730
71730
71730
71730
Sampling
Time
1330-1400
1603-1220
1150-1110
1135-1130
1220-1615
1125-1545
1207-1237
1205-1630
1235-1550
1625-1215
1640-1030
1330-1640
1400-1700
1650-1100
1715-1115
1105-1505
1140-1550
1215-1610
1700-0900
1530-0930
1330-1530
1325-1524
2000-0900
2130-0930
1140-1415
1140-1411
1140-1415
1140-1415
Calendar
Day - Year
60-77
60-1-77
62-3-77
62-3-77
62-77
63-77
63-77
67-77
67-77
67-8-77
67-8-77
68-77
68-77
68-9-77
68-9-77
69-77
69-77
69-77
69-70-77
69-70-77
264-76
264-76
268-9-76
268-9-76
265-76
265-76
265-76
265-76
Cone.
(ng/m3)
10,355
1,257
6,710
6,968
1,290
181
4,775
387
542
1,484
1,097
560
368
568 + 13
839
387
464
258
2,129
477
(continued)
-------
Table D4 (cont'd)
Cn
EPA
Region Compound CASS # Site
VI chloroform (cont.) 67-66-3 Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Liberty Hounds, OK
Tulsa, OK
Liberty Hounds, OK
Tulsa, OK
Vttrti, OK
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston. TX
Houston, TX
Houston, TX
Houston, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
Address
Devil's Swamp
Devil's Swamp
Devil's Swamp
Devil's Swamp
District Water Works
2nd & Elwood
District Water Works
2nd & Elwood
-
Aldine (Mail Rt.)
Clanton Dr.
Clanton Dr.
Aldine (Hall Rt.)
Crawford at Polk
Aldine (Hail Rt.)
Crawford at Polk
Clanton Dr.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Hwy. 10
Hwy. 10
Zip
Code
74047
74103
74047
74103
74082
77037
or 9
77080
77080
77037
or 9
77002
77037
or 9
77002
77080
77003
or 11
77003
or 11
77003
or 11
77003
or 11
77003
or 11
79902
79902
Sampling
Time
1935-1430
1515-1530
1535-1400
1400-0900
0355-0355
0600-0600
0600-0900
0600-0900
1400-1700
0945-1245
0745-1050
0630-0930
0630-0930
0615-0915
1207-1510
1546-1853
0607-0907
1730-0930
1000-0900
1030-0915
0915-0945
1000-1015
1150-1245
1218-1330
1015-1145
1015-1145
Calendar
Day - Year
132-4-77
134-6-77
136-8-77
138-40-77
191-(2)-77
192-(3)-77
264-77
264-77
264-77
173-77
179-77
231-77
232-77
292-77
293-77
294-7
294-77
195-7-77
202-4-77
204-6-77
206-8-77
208-10-77
99-101-78
99-101-78
115-7-78
115-7-78
Cone .
(ng/m3)
144 + 277
1700 + 233
1417 + 750
1389
3884 + 2884
2064 + 397
292 + 125
400 + 25
327 + 77
500 ± 333
354 + 146
T (125)
541 + 166
2282 + 162
519 + 58
896 + 396
795 ± 147
(continued)
-------
Table DA (cont'd)
EPA
Region Compound CASS t Site
VI chloroform (cont.J 67-66-3 El Paso, TX
El Dorado, AK
VI 2-chloro-l, 3-butadiene 126-99-8 Pasadena, TX
(chloroprene) Houston, TX
Houston, TX
VI 1-bromopropane 106-94-5 El Dorado, AK
or El Dorado, AK
2-bromopropane 75-26-3 El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Magnolia, AK
Magnolia, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Address
Hwy. 10
Off Hwy. 15
C. H. Milby Park
Milby Park
Off Goodyear Rd.
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 167
Hwy. 167
Hwy. 167
Hwy. 167
Hwy. 167
Hwy. 167
Hwy. 167
Hwy. 79
Hwy. 79
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Zip
Code
77902
71730
77017
77017
77017
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71753
71753
71730
71730
71730
71730
71730
71730
Sampling
Time
0918-1235
1329-1257
1005-1425
1670-1750
1510-1515
1330-1530
1325-1524
1200-1420
1200-1420
1200-1420
1200-1420
1018-1818
1145-1824
1740-0948
1745-0945
2130-0930
1140-1411
1140-1415
1140-1415
1140-1614
1124-1624
1120-1625
1105-1742
1427-1726
1422-1726
1139-1240
1155-1305
1543-1352
1256-1110
1400-1147
1042-0845
Calendar
Day - Year
115-7-78
138-9-78
241-75
209-76
209-76
264-76
264-76
268-76
268-76
268-76
268-76
268-76
268-76
268-9-76
268-9-76
268-9-76
265-76
265-76
265-76
265-76
265-76
265-76
265-76
267-76
267-76
199-200-77
199-200-77
199-200-77
200-1-77
200-1-77
202-3-77
Cone .
(ng/n,3)
4,000
266
5.5
6.7
13.4
10.8
16.8
15.4
5.5
16
4
11.8
25.2
T
47.2
T
20.8
24.8
35
T
16.2
26.6
T
T
T
T
T
T
(continued)
-------
Table D4 (cont'd)
EPA
Region Compound
VI 1-bromopropane
or
2-bromopropane
(cont . )
VI 1,2-dichloroethane
CASS t Site
106-94-5 El Dorado, AK
El Dorado, AK
75-26-3 Magnolia, AK
Magnolia, AK
107-06-2 Pasadena, TX
Pasadena, TX
Houston, TX
Pasadena, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Freeport , TX
Freeport, TX
La Porte, TX
Plaquemine, LA
Plaquemine , LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Geismar, LA
Address
Hwy. 15
Hwy. 15
Hwy. 79
Hwy. 79
Mae St.
Shaw Dr.
Milby Park
Off Hwy 225
Off Tidal Rd.
Off Hwy. 225
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off St. 352
Off St. 352
Off Hwy. 225
Bayou Rd.
Church & Main St.
LA 988 & Davis St.
50 yd. East off
LA IN
East off LA 1
Off LA 1
Off LA 1
Plaquemine Evergreen
Plantation
Plaquemine Evergreen
Plantation
Plaquemine Evergreen
Plantation
Plaquemine Evergreen
Plantation
Corner of Hwy. 73 & 75
Zip
Code
71730
71730
71753
71753
77502
77506
77017
77503
77536
77536
77536
77536
77536
77536
77541
77541
77571
70764
70764
70764
70764
70764
70764
70764
70764
70764
70764
70764
70734
Sampling
Time
1138-0910
1150-0925
0925-1130
1015-1150
1000-1000
1000-1000
1670-1750
1430-1600
1100-1200
1455-1555
1020-1035
1115-1215
1455-1555
1115-1215
1348-1555
1425-1508
1645-1833
1437-1320
1540-1350
1255-1705
1430-1740
1445-1755
1600-1015
1745-1015,
1250-1725
1325-1715
1400-1630
1705-1020
1545-1503
Calendar
Day - Year
202-3-77
202-3-77
210-1-77
210-1-77
237-8-75
238-9-75
209-76
210-76
211-76
211-76
212-76
212-76
211-76
212-76
221-76
221-76
224-76
31-2-77
31-2-77
32-77
32-77
32-77
32-3-77
32-3-77
33-77
33-77
33-77
33-4-77
59-60-77
Cone.
(ng/m3)
T
T
734
T
T
158
66,300
6,722
T
4,055
T
T
3,300
4,500
778
1726 + 345
1219 + 0
9 + 7
1590 + 45
399 + 28
3727 + 1127
3727 + 1127
1556 ± 0
524 + 61
416 + 27
112 + 56
683
(continued)
-------
Table D4 (cont'd)
N>
-J
00
EPA
Region Compound CASS # Site
VI 1 , 2-dichloroethane 107-06-2 Geismar, LA
(cont.) Geismar, LA
Geismar, LA
Geismar , LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Baton Rouge ,
Baton Rouge,
Baton Rouge,
Baton Rouge,
Baton Rouge,
Baton Rouge,
Baton Rouge,
Baton Rouge,
Baton Rouge,
Baton Rouge,
Baton Rouge,
Baton Rouge,
Baton Rouge,
Baton Rouge,
Baton Rouge,
Baton Rouge,
Houston, TX
Houston, TX
Houston, TX
Houston, TX
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
Address
Hwy. 73
Between Hwy. 30 & 73
Off LA 75
Hwy. 73
Off Hwy. 73
Off LA 75
Off Hwy. 75
Off Hwy. 30
Off US 61 North
Off unpaved, unmarked
road
Off US 61
Off US 61
Off unpaved, unmarked
road
Off US 61
Off of Turning Basin
Road
Graveyard Area
Mengel Rd.
Off LA 61
Off Mengel Rd.
Off LA 190
Off Mengel Rd.
Off LA 61
LA 1 and LA 190
Downwind of several
petroleum facilities
Aldine (Mail Rt.)
Clandon Dr.
Crawford at Polk
Aldine (Mail Rt.)
Zip
Code
70734
70734
70734
70734
70734
70734
70734
70734
70807
70807
70807
70807
70807
70807
70807
70807
70807
70805
70807
70807
70807
70805
70807
70807
77037
or 9
77080
77002
77037
or 9
Sampling
Time
1155-1615
1215-1240
1620-1537
1615-1220
1025-1240
1620-1537
1330-1400
1603-1220
1150-1110
1135-1130
1220-1615
1125-1545
1207-1237
1235-1550
1625-1215
1640-1030
1330-1640
1400-1700
1650-1100
1715-1115
1105-1505
1140-1550
1700-0900
1530-0930
0945-1245
0630-0930
0615-0915
1207-1510
Calendar
Day - Year
60-77
60-77
59-60-77
60-1-77
61-77
59-60-77
60-77
60-1-77
62-3-77
62-3-77
62-77
63-77
63-77
67-77
67-8-77
67-8-77
68-77
68-77
68-9-77
68-9-77
69-77
69-77
69-70-77
69-70-77
173-77
231-77
292-77
293-77
Cone.
(ng/m3)
10,333
7,844
232
4,689
1,555
100
800
1,444
137
712
458
585
78
887
731
712
10,341
751
322 + 0
3,229
2,000
1,522
5,024
302
T (444)
T (348)
209 + 48
T (258)
(continued)
-------
Table D4 (cont'd)
EPA
Region Compound CASS # Site
VI 1,2-dichloroethane 107-06-2 Houston, TX.
(cont.) Houston, TX
Houston, TX
Houston, TX
Houston, TX
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
VI 1,1,1- trichloroethane 71-55-6 Houston, TX
Texas City, TX
Houston, TX
Pasadena, TX
Pasadena, TX
Texas City, TX
Pasadena, TX
Houston, TX
Houston, TX
Pasadena, TX
Pasadena, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Address
Crawford at Polk
Clanton Dr.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
US 90
US 90
US 90
US 90
US 90
US 90
5609 May St.
-
May St.
Mae St.
Shaw Dr.
Connie #10
C. H. Milby Park
Milby Park
Steelman Ave. &
El Buey Way
Between industrial
site & ship channel
Off Hwy. 225
Off Hwy. 225
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Zip
Code
77002
77080
77003
or 11
77003
or 11
77003
or 11
70601
70601
70601
70601
70601
70601
77076
77590
77076
77502
77506
77590
77017
77017
77017
77503
77503
77536
77536
77536
77536
Sampling
Time
1546-1853
0607-0907
1730-0930
1000-0900
1030-0915
1430 min
1430 min
1430 min
1430 min
1425 min
1476 min
1630-1630
1415-1415
1245-2400
1430-2200
2230-1017
1200-2235
1005-1425
1670-1750
1620-1750
1430-1600
1430-1600
1100-1200
1115-1215
1455-1555
1115-1215
Calendar
Day - Year
294-77
294-77
195-7-77
202-4-77
204-6-77
174-5-78
174-5-78
174-5-78
174-5-78
174-5-78
174-5-78
320-1-74
316-7-74
235-75
237-75
238-9-75
239-75
241-75
209-76
209-76
210-76
210-76
211-76
212-76
211-76
212-76
Cone.
(ng/m3)
T (258)
T (258)
123 ± 10
157 + 36
242 + 0
159
283
45
21
+
1,243 + 6
522
900
T
144
1.000
400
400
(continued)
-------
Table D4 (cont'd)
00
O
EPA
Region
VI
Compound CASS t Site
1,1, 1-trichloroethane 71-55-6 Freeport, TX
Freeport, TX
Freeport , TX
La Porte, TX
La Porte, TX
La Porte, TX
Plaquemine , LA
Plaquemine , LA
Plaquemine, LA
Plaquemine , LA
Plaquemine, LA
Plaquemine, LA
Plaquemine , LA
Plaquemine , LA
Plaquemine, LA
Plaquemine, LA
Plaquemine , LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar , LA
Geismar, LA
Geismar, LA
Address
Off St. 352
Off St. 352
Off St. 352
Off Hwy. 225
Off Hwy. 225
Off Hwy. 225
Bayou Rd.
Church & Main St.
LA 988 & Davis St.
50 yd. East Off
LA IN
East off LA IN
Off LA 1
Off LA 1
Plaquemine Evergreen
Plantation
Plaquemine Evergreen
Plantation
Plaquemine Evergreen
Plantation
Plaquemine Evergreen
Plantation
Corner of Hwy. 73 & 75
Vulcan Rd.
Hwy. 73
Between
Off LA 75
Hwy. 73
Off
Off LA 75
Off Hwy. 30
Zip
Code
77541
77541
77541
77571
77571
77571
70764
70764
70764
70764
70764
70764
70764
70764
70764
70764
70764
70734
70734
70734
70734
70734
70734
70734
70734
70734
Sampling
Time
1342-1543
1348-1555
1425-1508
1645-1833
1641-1824
1114-1252
1437-1320
1540-1350
1255-1705
1430-1740
1445-1755
1600-1015
1745-1015
1250-1725
1325-1715
1400-1630
1705-1020
1545-1503
1630-1550
1155-1615
1215-1240
1620-1537
1615-1220
1025-1240
1330-1400
1603-1220
Calendar
Day - Year
221-76
221-76
221-76
224-76
224-76
225-76
31-2-77
31-2-77
32-77
32-77
32-77
32-3-77
32-3-77
33-77
33-77
33-77
33-9-77
59-60-77
59-60-77
60-77
60-77
59-60-77
60-1-77
61-77
60-77
60-1-77
Cone .
(ng/m3)
16,600
15,200
3,889
27,700
T
1100 + 20
1820 + 100
68 + 8
1500 + 20
430 + 50
2680 + 0
8760 + 1160
1556 + 0
524 + 61
416 + 27
112 + 56
T
250
200
200
75
175
400
80
675
(continued)
-------
Table D4 (cont'd)
S3
oo
EPA
Region
VI
Compound CASS // Site
1,1,1-trichloroethane 71-55-6 Baton Rouge, LA
(cont.) Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
f Baton Rouge, LA
Liberty Mounds, OK
Tulsa, OK
Vera, OK
Liberty Hounds, OK
Houston, TX
Houston, TX
Houston, TX
Address
Off US 61 North
Off unpaved, un-
marked road
Off of Turning
Basin Rd.
Graveyard Area
Hengel Rd.
Off Mendel Rd.
Choctaw Rd. &
Pholox St.
LA 1 and LA 190
Hwy. 167
Hwy. 167
Parker's Chapel
Water Tower
Hwy. 167
Hwy. 167
Hwy. 167
Devil's Swamp
Devil's Swamp
Devil's Swamp
Devil's Swamp
District Water Works
2nd & Elwood
District Water Works
Aldine (Hail Rt.)
Clanton Dr.
Clanton Dr.
Zip
Code
70807
70807
70807
70807
70807
70807
70805
70807
71730
71730
71730
71730
71730
71730
74047
74103
74083
74047
77037
or 9
77080
77080
Sampling
Time
1150-1110
1207-1237
1625-1215
1640-1030
1330-1640
1650-1100
1215-1610
1700-0900
1330-1530
1325-1524
2130-0930
1140-1415
1140-1411
1140-1415
1935-1430
1515-1530
1535-1400
1400-0900
0355-0355
0600-0900
1400-1500
0600-0900
0945-1245
0745-1050
0630-0930
Calendar
Day - Year
62-3-77
63-77
67-8-77
67-8-77
68-77
68-9-77
69-77
69-70-77
264-76
264-76
268-9-76
265-76
265-76
265-76
132-4-77
134-6-77
136-8-77
138-40-77
191- (2) -7 7
264-77
264-77
264-77
173-77
179-77
231-77
Cone .
(ng/m3)
178
178
200
178
222
78 + 24
200
167
500 + 83
2.250 +
1.750
T
T
T (417)
T (334)
T (334)
T (454)
T (555)
708 + 41
533 + 116
(continued)
-------
Table D4 (cont'd)
N3
co
EPA
Region Compound CASS t Site
VI 1,1, 1-trichloroethane 71-55-6 Houston, TX
(cont.)
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Dorado, AK
El Dorado, AK
El Dorado, AK
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Address
Aldine (Mail Rt.)
Crawford at Polk
Aldine (Mail Rt.)
Crawford at Polk
Clanton Dr.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Hwy. 10
Hwy. 10
Hwy. 10
Off Hwy. 15
Off Hwy. 15
Off Hwy. 15
US 90
US 90
US 90
US 90
US 90
US 90
Zip
Code
77037
or 9
77002
77037
or 9
77002
77080
77003
or 11
77003
or 11
77003
or 11
77003
or 11
77003
or 11
79902
79902
79902
71730
71730
71730
70601
70601
70601
70601
70601
70601
Sampling
Time
0630-0930
0615-0915
1207-1510
1546-1853
0607-0907
1730-0930
1000-0900
1030-0915
0915-0945
1000-1015
1150-1245
1150-1245
1218-1330
1015-1145
1015-1145
0918-1235
1329-1257
1329-1257
1329-1257
1430 min
1430 min
1430 min
1430 min
1425
1476
Calendar
Day - Year
232-77
292-77
293-77
294-77
294-77
195-7-77
202-4-77
204-6-77
206-8-77
208-10-77
99-101-78
99-101-78
99-101-78
115-7-78
115-7-78
115-7-78
138-9-78
138-9-78
138-9-78
174-5-78
174-5-78
174-5-78
174-5-78
174-5-78
174-5-78
Cone .
(ng/m3)
995 + 5
T (334)
T (533)
T (334)
T (334)
367 + 33
235 + 59
T (470)
T (334)
T (454)
238
78
88
111
32
317 + 22
(continued)
-------
Table D4 (cont'd)
to
oo
EPA
Region Compound
VI allyl bromide
VI carbon tetrachloride
CASS It Site
106-95-6 El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Magnolia, AK
Magnolia, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
56-23-5 Pasadena, TX
Bay town, TX
Texas City, TX
Houston, TX
Houston, TX
Pasadena, TX
Pasadena, TX
Texas City, TX
Texas City, TX
Pasadena, TX
Houston, TX
Houston, TX
Houston, TX
Address
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Parker's Chapel
Water Tower
Hwy- 167
Hwy. 167
Hwy. 167
Hwy. 79
Hwy. 79
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Shaw Dr.
7200 Bayway Dr.
-
5609 May St.
May St.
Mae St.
Shaw Dr.
Connie #10
Connie #10
C. H. Milby Park
Milby Park
Off Goodyear Rd.
Steelman Ave. &
El Buey Way
Zip
Code
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71753
71753
71730
71730
71730
71730
71730
71730
77506
77520
77590
77076
77076
77502
77506
77590
77590
77017
77017
77017
77017
Sampling
Time
1330-1523
1330-1525
1330-1530
1200-1420
1018-1818
1145-1824
1745-0945
2130-0930
1140-1415
1140-1614
1120-1625
1427-1726
1427-1726
1242-1315
1256-1110
1137-1130
1152-1150
1042-0845
1138-0910
1130-1130
1630-1630
1415-1415
1630-1630
1245-2400
1430-2200
1000-1000
1200-2235
2235-1155
1005-1425
1670-1750
1510-1515
1620-1750
Calendar
Day - Year
264-76
264-76
264-76
268-76
268-76
268-76
268-9-76
268-9-76
265-76
265-76
276-76
267-76
267-76
199-200-77
200-1-77
201-2-77
201-2-77
202-3-77
202-3-77
315-6-74
317-8-74
316-7-74
320-1-74
235-75
237-75
238-9-75
239-75
239-40-75
241-75
209-76
209-76
209-76
Cone.
(ng/n.3)
70
T
29.7
8.4
T
8
2.5
24.8
T
3.2
32.9
9.4
15.8
T
T
T
T
T
T
238
114
T
(continued)
-------
Table D4 (cont'd)
to
00
EPA
Region Compound CASS 9
VI carbon tetrachloride 56-23-5
I ^
icon
Site
Pasadena, TX
Pasadena, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, IX
Freeport, TX
Freeport , TX
Freeport, TX
La Porte, TX
La Porte, TX
La Porte, TX
Plaquemine , LA
Plaquemine, LA
Plaquemine , LA
Plaquemine, LA
Plaquemine , LA
Plaquemine, LA
Plaquemine, LA
Gelsmar, LA
Geismar , LA
Geismar, LA
Geismar, LA
Geismar, LA
Address
Between industrial
site and ship channel
Off Hwy. 225
Off Tidal Rd.
Off Hwy. 225
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off St. 352
Off St. 352
Off St. 352
Off Hwy. 225
Off Hwy. 225
Off Hwy. 225
Bayou Rd.
LA 988 & Davis St.
Off LA 1
Off LA 1
Plaquemine Ever-
green Plantation
Plaquemine Ever-
green Plantation
Plaquemine Ever-
green Plantation
Corner of Hwy. 73
and 75
Hwy
Vulcan Rd.
Between Hwy. 30
and 73
Off LA 75
Zip
Code
77503
77503
77536
77536
77536
77536
77536
77536
77536
77541
77541
77541
77571
77571
77571
70764
70764
70764
70764
70764
70764
70764
70734
70734
70734
70734
70734
Sampling
Time
1430-1600
1430-1600
1100-1200
1100-1200
1455-1555
1020-1035
1115-1215
1455-1555
1115-1215
1342-1543
1348-1555
1425-1508
1645-1833
1641-1824
1114-1252
1437-1320
1255-1705
1600-1015
1745-1015
1250-1725
1325-1715
1400-1630
1545-1503
1155-1615
1630-1550
1215-1240
1620-1537
Calendar
Day - Year
210-76
210-76
211-76
211-76
211-76
212-76
212-76
211-76
212-76
221-76
221-76
221-76
224-76
224-76
225-76
31-2-77
32-77
32-3-77
32-3-77
33-77
33-77
33-77
59-60-77
60-77
59-60-77
60-77
59-60-77
Cone.
(ng/m3)
T
146
846
T
T
T
T
276
69
11,538
T
T
1,230
T
800 + 800
20 + 10
T
4,628
+ 1,100
335 ± 250
667 + 200
277 + 18
400
1,433
1,133
300
183
(continued)
-------
Table D4 (cont'd)
00
EPA
Region Compound
VI carbon tetrachloride
(cont.)
CASS # Site
56-23-5 Geismar, LA
Geismar, LA
Gelsmar, LA
Geismar , LA
Geismar, LA
Baton Rouge , LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Address
Hwy. 73
Off Hwy. 73
Off LA 75
Off Hwy. 75
Off Hwy. 30
Off US 61 North
Off unpaved, un-
marked road
Off US 61
Off unpaved, un-
marked road
Off US 61
Off of Turning
Basin Rd.
Graveyard Area
Mengel Rd.
Off LA 61
Off Mengel Rd.
Off LA 190
Off Mengel Rd.
Off LA 61
Choc taw Rd. and
Pholox St.
LA 1 and LA 190
Downwind of several
petroleum facilities
Hwy. 167
Hwy. 167
Ak. City Water Tower
Parker's Chapel
Water Tower
Hwy. 167
Hwy. 167
•I. Ip
Code
70734
70734
70734
70734
70734
70807
70807
70807
70807
70807
70807
70807
70807
70805
70807
70807
70807
70805
70805
70807
70807
71730
71730
71730
71730
71730
71730
Sampling
Time
1615-1220
1025-1240
1620-1537
1330-1400
1603-1220
1150-1110
1135-1130
1220-1615
1207-1237
1235-1550
1625-1215
1640-1030
1330-1640
1400-1700
1650-1100
1715-1115
1105-1505
1140-1550
1215-1610
1700-0900
1530-0930
1330-1530
1325-1524
2000-0900
2130-0930
1140-1415
1140-1411
Calendar
Day - Year
60-1-77
61-77
59-60-77
60-77
60-1-77
62-3-77
62-3-77
62-77
63-77
67-77
67-8-77
67-8-77
68-77
68-77
68-9-77
68-9-77
69-77
69-77
69-77
69-70-77
69-70-77
264-76
264-76
268-9-76
268-9-76
265-76
265-76
Cone.
(ng/m^)
4,667
10,100
300
286
2,633
874
452
289
74
311
592
533
311
533
148 + 0
429
163
119
74
1,037
192
(continued)
-------
Table D4 (cont'd)
00
EPA
Region Compound CASS t Site
VI carbon tetrachloride 56-23-5 El Dorado, AK
(cont.) El Dorado, AK
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Liberty Mounds, OK
Tulsa, OK
Liberty Mounds, OK
Tulsa , OK
Vera, OK
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Address
Hwy. 167
Hwy. 167
Devil's Swamp
Devil's Swamp
Devil's Swamp
Devil ' s Swamp
District Water Works
2nd & Elwood
District Water Works
2nd & Elwood
Aldine (Mail Rt.)
Clanton Dr.
Clanton Dr.
Aldine (Mail Rt.)
Crawford at Polk
Aldine (Mail Rt.)
Crawford at Polk
Clanton Dr.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Zip
Code
71730
71730
74047
74103
74047
74103
74083
77037
or 9
77080
77080
77037
or 9
77002
77037
or 9
77002
77080
77003
or 11
77003
or 11
77003
or 11
77003
or 11
77003
or 11
Sampling
Time
1140-1415
1140-1415
1935-1430
1515-1530
1535-1400
1400-0900
0355-0355
0600-0600
0600-0900
0600-0900
1400-1700
0945-1245
0745-1050
0630-0930
0630-0930
0615-0915
1207-1510
1546-1853
0607-0907
1730-0930
1000-0900
1030-0915
0915-0945
1000-1015
Calendar
Day - Year
265-76
265-76
132-4-77
134-6-77
136-8-77
138-140-77
191-(2)-77
192-(3)-77
264-77
264-77
264-77
173-77
179-77
231-77
232-77
292-77
293-77
294-77
294-77
195-7-77
202-4-77
204-6-77
206-8-77
208-10-77
Cone.
(ng/m3)
T
T
T
T
T
T (154)
217 + 63
T (125)
T (125)
T (95)
T (95)
T (95)
T (95)
T (92)
T (87)
T (87)
T (95)
T (133)
(continued)
-------
Table D4 (cont'd)
to
oo
EPA
Region Compound
VI carbon tetrachloride
(cont.)
VI 1 , 2-dichloropropane
VI trichloroethylene
CASS # Site
56-23-5 El Paso, TX
El Paso, TX
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
78-87-5 Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Lake Charles, LA
79-01-6 Pasadena, TX
Baytown, TX
Texas City, TX
Pasadena, TX
Pasadena, TX
Pasadena, TX
Houston, TX
Houston, TX
Pasadena, TX
Pasadena, TX
Deer Park, TX
Freeport, TX
Freeport, TX
Freeport, TX
Address
US 90
US 90
US 90
US 90
US 90
US 90
Vulcan Rd.
Between Hwy. 30
and 73
Hwy. 73
Off Hwy. 73
Off LA 75
Off Hwy. 30
OS 90
Shaw Dr.
7200 Bayway Dr.
-
Mae St.
Mae St.
Shaw Dr.
Milby Park
Steelman Ave. &
El Buey Way
Between industrial
site & ship channel
Off Hwy. 225
Off Hwy. 225
Off St. 352
Off St. 352
Off St. 352
Zip
Code
70601
70601
70601
70601
70601
70601
70734
70734
70734
70734
70734
70734
70601
77506
77520
77590
77502
77502
77506
77017
77017
77503
77503
77536
77541
77541
77541
Sampling
Time
1150-1245
1218-1330
1430 mln
1430 min
1430 min
1430 min
1425 min
1476 min
1630-1550
1215-1240
1615-1220
1025-1240
1620-1537
1603-1220
1476 min
1130-1130
1630-1630
1415-1415
1430-2200
1000-1000
2230-1017
1670-1750
1620-1750
1430-1600
1430-1600
1100-1200
1342-1543
1348-1555
1425-1508
Calendar
Day - Year
99-101-78
99-101-78
174-5-78
174-5-78
174-5-78
174-5-78
174-5-78
174-5-78
59-60-77
60-77
60-1-77
61-77
59-60-77
60-1-77
174-5-78
315-6-74
317-8-74
316-7-74
237-75
237-8-75
238-9-75
209-76
209-76
210-76
210-76
211-76
221-76
221-76
221-76
Cone.
(ng/m3)
104
68
43
63
30
132 + 18
1,163
121
71
39
3,999
36
23 + 0
75
39
76
5,071
321
107
200
(continued)
-------
Table D4 (cont'd)
N>
CO
CO
EPA
Region Compound
VI trichloroethylene
(cont . )
CASS # Site
79-01-6 La Porte, TX
La Porte, TX
La Porte, TX
Plaquemine, LA
Plaquemine , LA
Plaquemine, LA
Plaquemine, LA
Plaquemine , LA
Plaquemine , LA
Geismar, LA
Geismar, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
El Dorado, AK
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Liberty Hounds, OK
Tulsa, OK
Houston, TX
Houston, TX
Address
Off Hwy. 225
Off Hwy. 225
Off Hwy. 225
East Off LA 1
Off LA 1
Off LA 1
Plaquemine Ever-
green Plantation
Plaquemine Ever-
green Plantation
Plaquemine Ever-
green Plantation
Corner of Hwy. 73
and 75
Between Hwy. 30 & 73
Off US 61 North of
Plant A
Off unpaved, un-
marked road
Off of Turning
Basin Road
Off Mengel Rd.
Off LA 190
Off LA 61
Parker's Chapel
Water Tower
Devil's Swamp
Devil's Swamp
Devil's Swamp
District Water Works
2nd & Elwood
Clanton Dr.
Clanton Dr.
Zip
Code
77571
77571
77571
70764
70764
70764
70764
70764
70764
70734
70734
70807
70807
70807
70807
70807
70805
71730
74047
74103
77080
77080
Sampling
Time
1645-1833
1641-1824
1114-1252
1445-1755
1600-1015
1745-1015
1250-1725
1325-1715
1705-1020
1545-1503
1215-1240
1150-1110
1207-1237
1625-1215
1650-1100
1715-1115
1140-1550
2130-0930
1935-1430
1515-1530
1535-1400
0600-0900
0600-0900
0745-1050
0630-0930
Calendar
Day - Year
224-76
224-76
225-76
32-77
32-3-77
32-3-77
33-77
33-77
33-4-77
59-60-77
60-77
62-3-77
63-77
67-8-77
68-9-77
68-9-77
69-77
268-9-76
132-4-79
134-6-77
136-8-77
264-77
264-77
179-77
231-77
Cone.
(ng/m3)
T
43
T
T (132)
T (172)
T (132)
T
T
T (179)
T (132)
(continued)
-------
Table D4 (cont'd)
00
VO
EPA
Region Compound CASS t Site
VI trichloroethylene 79-01-6 Houston, TX
(cont.)
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Dorado, AK
El Dorado, AK
El Dorado, AK
Lake Charles, LA
Lake Charles, LA
Address
Aldine (Mall Rt.)
Crawford at Polk
Aldine (Mail Rt.)
Crawford at Polk
Clanton Dr.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Hwy. 10
Hwy. 10
Hwy. 10
Off Hwy. 15
Off Hwy. 15
Off Hwy. 15
US 90
US 90
Zip
Code
77037
or 9
77002
77037
or 9
77002
77080
77003
or 11
77003
or 11
77003
or 11
77003
or 11
77003
or 11
79902
79902
79902
71730
71730
71730
70601
70601
Sampling
Time
0630-0930
0615-0915
1702-1510
1546-1853
0607-0907
1730-0930
1000-0900
1030-0915
0915-0945
1000-1015
1150-1245
1150-1245
1218-1330
1015-1145
1015-1145
0918-1235
1329-1257
1329-1257
1329-1257
1425
1476
Calendar
Day - Year
232-77
292-77
293-77
294-77
294-77
195-7-77
202-4-77
204-6-77
206-8-77
208-10-77
99-101-78
99-101-78
99-101-78
115-7-78
115-7-78
115-7-78
138-9-78
138-9-78
138-9-78
174-5-78
174-5-78
Cone.
(ng/m3)
158 + 26
72 + 28
T
T (250)
T (250)
T (100)
T (100)
130 + 10
T (100)
T (135)
(continued)
-------
Table D4 (cont'd)
N3
VO
O
EPA
Region Compound CASS f
VI bromodlchloromethane 75-27-4 El
El
El
El
El
El
El
Site
Dorado,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado,
Magnolia ,
Magnolia ,
El
El
El
El
El
El
El
El
El
El
VI l-chloro-2-bromoethane 107-04-0 El
El
El
El
El
El
El
El
El
El
El
El
El
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado ,
Dorado,
Address
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
15
15
15
15
15
167
167
79
79
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
Zip
Code
71730
71730
71730
71730
71730
71730
71730
71753
71753
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
Sampling
Time
1200-1420
1200-1420
1200-1420
1018-1818
1145-1824
1140-1411
1140-1415
1427-1726
1422-1726
1955-1420
1139-1240
1155-1305
1256-1110
1310-1121
1347-1139
1127-1047
1137-1130
1147-1143
1115-0900
1200-1420
1200-1420
1145-1824
1745-0945
1155-1305
1242-1315
1543-1352
1514-1334
1310-1121
1118-1032
1137-1130
1147-1143
1115-0900
Calendar
Day - Year
268-76
268-76
268-76
268-76
268-76
265-76
265-76
265-76
265-76
198-9-77
199-200-77
199-200-77
200-1-77
200-1-77
200-1-77
201-2-77
201-2-77
201-2-77
202-3-77
268-76
268-76
268-76
268-9-76
199-200-77
199-200-77
199-200-77
199-200-77
200-1-77
201-2-77
201-2-77
201-2-77
202-3-77
Cone.
(ng/m^)
1.
9.
15
T
26
6.
5.
3.
6.
T
T
T
T
T
T
T
T
T
T
2.
6.
13
0.
73
70
34
2.
T
I
T
22
T
9
6
.4
4
2
4
8
8
6
3
8
(continued)
-------
Table D4 (cont'd)
S3
VO
EPA
Region
VI
VI
VI
Compound CASS // slte
l-chloro-2-bromoethane 107-04-0 El Dorado, AK
(cont.) Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
El Dorado, AK
El Dorado, AK
1,1,2-trichloroethane 79-00-5 Deer Park, IX
Deer Park, TX
Freeport, TX
Freeport, TX
Flaquemine, LA
Plaquemine, LA
Flaquemine, LA
Flaquemine, LA
Geismar, LA
Gelsmar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
chlorodibromomethane 124-48-1 El Dorado, AK
El Dorado, AK
El Dorado, AK
Address
Hwy. 15
Hwy. 132
Hwy. 132
Hwy. U32
Hwy. 132
Hwy.. 132
Hwy. 132
Hwy. 132
Off Hwy. 15
Off Hwy. 15
Off Tidal Rd.
Off Tidal Rd.
Off St. 352
Off St. 352
Bayou Rd.
East Off LA 1
Off LA 1
Off LA 1
Corner of Hwy. 73
and 75
Vulcan Rd.
Hwy. 73
Between Hwy. 30
and 73
Hwy .73
Off Hwy. 75
Graveyarc Area
Off LA 61
Downwind of several
petroleum facilities
Hwy. 15
Off Hwy . 167
Off Hwy . 167
Zip
Code
71730
71753
71753
71753
71753
71753
71753
71753
71730
71730
77536
77536
77541
77541
70764
70764
70764
70764
70734
70734
70734
70734
70734
70734
70807
70805
70807
71730
71730
71730
Sampling
Time
1150-0925
1208-1100
1150-1105
1110-1045
1230-0945
1120-0846
1100-0900
1000-0820
1329-1257
1329-1257
1100-1200
1115-1215
1348-1555
1425-1508
1437-1320
1445-1755
1600-1015
1745-1015
1545-1503
1630-1550
1155-1615
1215-1240
1615-1220
1330-1400
1640-1030
1400-1700
1530-0930
1150-0925
1140-0945
1105-1015
Calendar
Day - Year
202-3-77
213-4-77
214-5-77
214-5-77
214-5-77
215-6-77
215-6-77
215-6-77
138-9-78
138-9-78
211-76
212-76
221-76
221-76
31-2-77
32-77
32-3-77
32-3-77
59-60-77
59-60-77
60-77
60-77
60-1-77
60-77
67-8-77
68-77
69-70-71
202-3-77
203-4-77
203-4-77
Cone .
(ng/m3)
T
445
163
1,089
32
304
251
403
6,700
3,334
T
3,821
580 + 60
36 + 0
260 + 18
1840 + 440
120
150
5,450
9,611
6,900
320
80
54
533
T
8.4 + 2.8
T
(continued)
-------
Table D4 (cont'd)
ro
EPA
Region
VI
VI
VI
Compound CASS f Site
chlorodibromomethane 124-48-1 El Dorado, AK
(cont.) El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado^ AK
El Dorado, AK
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
dichloropropane 142-28-9 Deer Park, TX
isomer(s) Deer Park, TX
Freeport, TX
Freeport, TX
Freeport, TX
Flaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
1, 2-dibromoe thane 106-93-4 El Dorado AK
El Dorado AK
El Dorado AK
El Dorado AK
El Dorado AK
El Dorado AK
Address
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
US 90
US 90
US 90
US 90
US 90
US 90
Off Hwy. 225
Off Tidal Rd.
Off St. 352
Off St. 352
Off St. 352
Bayou Rd.
Church & Main St.
LA 988 & Davis St.
East Off LA 1
Off LA 1
Off LA 1
Plaquemine Ever-
green Plantation
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Zip
Code
71730
71730
71730
71730
71730
71730
71730
70601
70601
70601
70601
70601
70601
77536
77536
77541
77541
77541
70764
70764
70764
70764
70764
70764
70764
71730
71730
71730
71730
71730
71730
Sampling
Time
1220-1040
1400-0945
1020-1010
1040-1025
0940-1002
0950-1017
1055-1045
1430
1430
1430
1430
1425
1476
1100-1200
1115-1215
1342-1543
1348-1555
1425-1508
1437-1320
1540-1350
1255-1705
1445-1755
1600-1015
1745-1015
1250-1725
1330-1530
1330-1523
1330-1525
1325-1524
1200-1420
1200-1420
Calendar
Day - Year
203-4-77
204-5-77
204-5-77
204-5-77
205-6-77
205-6-77
205-6-77
174-5-78
174-5-78
174-5-78
174-5-78
174-5-78
174-5-78
211-76
212-76
221-76
221-76
221-76
31-2-77
31-2-77
32-77
32-77
32-3-77
32-3-77
33-77
264-76
264-76
264-76
264-76
268-76
268-76
Cone.
(ng/m3)
31
T
T
22
T
23
81
147
130
96
34
64
230 + 74
T
2,586
69
1,478
944 + 172
735 + 37
1015 + 620
209 + 4
1363 + 33
2239 + 136
T
81
3.10 + 0.8
5.30
133
7.4
1,107
(continued)
-------
Table D4 (cont'd)
vo
u>
EPA
Region Compound CASS t Site
VI 1, 2-dlbromoethane 106-93-4 El Dorado, AK
(cont'd) El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Address
Hwy.
Hwy.
Hwy.
Hwy.
15
15
15
15
Parker's Chapel
Water
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Tower
167
167
167
79
79
79
79
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
Zip
Code
71730
71730
71730
71730
71730
71730
71730
71730
71753
71753
71753
71753
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
Sampling
Time
1200-1420
1145-1824
1740-0948
1745-0945
2130-0930
1140-1415
1140-1415
1120-1625
1427-1726
1427-1726
1422-1726
1355-1903
1955-1420
1139-1240
1155-1305
1242-1315
1543-1352
1514-1334
1256-1110
1310-1121
1321-1131
1400-1157
1347-1139
1118-1032
1127-1047
1137-1130
1152-1150
1147-1143
1042-0845
1115-0900
1138-0910
1210-0950
1150-0925
Calendar
Day - Year
268-76
268-76
268-9-76
268-9-76
268-9-76
265-76
265-76
265-76
267-76
267-76
267-76
267-76
198-8-77
199-200-77
199-200-77
199-200-77
199-200-77
199-200-77
200-1-77
200-1-77
200-1-77
200-1-77
200-1-77
201-2-77
201-2-77
201-2-77
201-2-77
201-2-77
202-3-77
202-3-77
202-3-77
202-3-77
202-3-77
Cone.
(ng/m3)
1,837
430
89
500
7.2
1.7
34
T
227
174
21.2
20,250
1.7
95
271,283
2,408
20
T
2.8
8,092
39.060
3,352
32,872
T
118
896
190
35,056
T
1,056
526
T
270
(continued)
-------
Table D4 (cont'd)
N3
VO
EPA
Region Compound CASS it Site
VI 1, 2-dibromomethane 106-93-4 El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Address
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Off Hwy.
Hwy. 79
Hwy. 79
Hwy. 79
Hwy. 79
Hwy. 79
Hwy. 79
Hwy. 79
Hwy- 79
Hwy- 79
Hwy. 79
Hwy. 79
Hwy. 79
Hwy. 79
Hwy. 79
167
.167
167
167
167
167
167
167
167
167
167
167
167
167
167
167
167
Zip
Code
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71753
71753
71753
71753
71753
71753
71753
71753
71753
71753
71753
71753
71753
71753
Sampling
Time
1130-0925
1140-0945
1205-1000
1105-1015
1220-1040
0935-0925
1400-0945
1010-1000
1020-1010
1040-1025
0940-1002
0950-1017
1005-1033
1055-1040
1010-1019
1040-0840
1055-0850
1655-1000
1708-1018
0945-0845
1005-0900
1020-1000
1055-1012
0850-0845
0915-0915
1002-1005
1035-0955
0900-1125
0925-1130
1015-1150
1000-1150
Calendar
Day - Year
203-4-77
203-4-77
203-4-77
203-4-77
203-4-77
204-5-77
204-5-77
204-5-77
204-5-77
204-5-77
205-6-77
205-6-77
205-6-77
205-6-77
206-7-77
206-7-77
206-7-77
207-8-77
207-8-77
208-9-77
208-9-77
208-9-77
208-9-77
209-10-77
209-10-77
209-10-77
209-10-77
210-1-77
210-1-77
210-1-77
210-1-77
Cone .
(ng/n.3)
493
227 + 45
501
45
448
T
868
T
280
120
T
T
2,425
342
67
193
171
2,957
216
818
1,008
1,411
2,520
1,638
1,868
26
5,012
3,791
2,800
356
2,366
(continued)
-------
Table D4 (cont'd)
VO
01
EPA
Region Compound
VI 1,2-dibromoethane
(cont.)
VI tetrachloroethylene
CASS // Site
106-93-4 Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
127-18-4 Bay town, IX
Pasadena, TX
Texas City, TX
Houston, TX
Houston, TX
Pasadena, TX
Pasadena, TX
Pasadena, TX
Pasadena, TX
Texas City, TX
Pasadena, TX
Houston, TX
Houston, TX
Houston, TX
Pasadena, TX
Address
Hwy. 132
Hwy. 132
Hwy. 132
Hwy. 132
Hwy. 132
Hwy. 132
Hwy.. 132
Hwy.. 132
Hwy. 132
Hwy. 132
Hwy. 132
Hwy- 132
Off Hwy. 15
Off Hwy. 15
Off Hwy. 15
7200 Bayway Dr.
Shaw Dr.
-
5609 May St.
May St.
Mae St.
Mae St.
Shaw Dr.
Shaw Dr.
Connie #10
C. H. Milby Park
Milby Park
Off Goodyear Rd.
Steelman Ave. &
El Buey Way
Between industrial
site and ship channel
Zip
Code
71753
71753
71753
71753
71753
71753
71753
71753
71753
71753
71753
71753
71730
71730
71730
77520
77506
77590
77076
77076
77502
77502
77506
77506
77590
77017
77017
77017
77017
77503
Samp 1 ing
Time
1055-0950
1130-1030
1208-1100
1000-1005
1150-1105
1110-1045
1230-0945
1015-0830
1035-0840
1120-0846
1100-0900
1000-0820
1329-1257
1329-1257
1329-1257
1630-1630
1130-1130
1415-1415
1630-1630
1245-2400
1430-2200
1000-1000
1000-1000
2230-1017
1200-2235
1005-1425
1670-1750
1510-1515
1620-1750
1430-1600
Calendar
Day - Year
213-4-77
213-4-77
213-14-77
214-5-77
214-5-77
214-5-77
214-5-77
215-6-77
215-6-77
215-6-77
215-6-77
215-6-77
138-9-78
138-9-78
138-9-78
317-8-74
315-6-74
316-7-74
320-1-74
235-75
237-75
237-8-75
238-9-75
238-9-75
239-75
241-75
209-76
209-76
209-76
210-76
Cone .
-------
Table D4 (cont'd)
EPA
Region Compound
VI tetrachloroechylene
(cont . )
CASS # Site
127-18-4 Pasadena, IX
Pasadena, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Freeport, TX
Freeport, TX
Freeport, TX
La Porte, IX
La Porte, TX
La Porte, TX
Plaquemine , LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine , LA
Plaquemine, LA
Plaquemine , LA
Plaquemine , LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Geismar, LA
Address
Off Hwy. 225
Near Houston ship
channel
Off. Hwy 225
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off St. 352
Off St. 352
Off St. 352
Off Hwy. 225
Off Hwy. 225
Off Hwy. 225
Bayou Rd.
Church & Main St.
LA 988 & Davis St.
50 yd. East Off
LA IN
East off LA 1
Off LA 1
Off LA 1
Plaquemine Ever-
green Plantation
Plaquemine Ever-
green Plantation
Plaquemine Ever-
green Plantation
Plaquemine Ever-
green Plantation
Corner of Hwy. 73
and 75
Zip
Code
77503
77503
77536
77536
77536
77536
77536
77541
77541
77541
77571
77571
77571
70764
70764
70764
70764
70764
70764
70764
70764
70764
70764
70764
70734
Sampling
Time
1430-1600
1430-1600
1100-1200
1455-1555
1020-1035
1115-1215
1115-1215
1342-1543
1348-1555
1425-1508
1641-1824
1645-1833
1114-1252
1437-1320
1540-1350
1255-1705
1430-1740
1445-1755
1600-1015
1745-1015
1250-1725
1325-1715
1400-1630
1705-1020
1545-1503
Calendar
Day - Year
210-76
210-76
211-76
211-76
212-76
212-76
212-76
221-76
221-76
221-76
224-76
224-76
225-76
31-2-77
31-2-77
32-77
32-77
32-77
32-3-77
32-3-77
33-77
33-77
33-77
33-4-77
59-60-77
Cone .
(ng/m^)
18
T
T
2,019
75
68
72
N.D.
94
1,585
83
17
T
82 + 20
977 + 900
T
21 + 0
54 + 3
489 + 70
1224 + 173
159 + 170
27 + 3
30 + 10
16 + 8
46
(continued)
-------
Table D4 (cont'd)
VO
--J
EPA
Region Compound
VI tetrachloroethylene
(cont.)
CASS // Site
127-18-4 Geismar, LA
Celsmar , LA
Geismar , LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar, LA
Geismar , LA
Geismar, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
El Dorado, AK
El Dorado, AK
Address
Vulcan Rd.
Hwy. 73
Between Hwy. 30
and 73
Off LA 75
Hwy. 73
Off Hwy. 73
Off LA 75
Off Hwy. 75
Off Hwy. 30
Off US 61
Off unpaved, un-
marked road
Off US 61
Off unpaved, un-
marked road
East side of LA 61
Off US 61
Off of Turning
Basin Road
Graveyard Area
Mengel Road
Off LA 61
Off Mengel Rd.
Off LA 190
Off Mengel Rd.
Off LA 61
Choctaw Rd, and
Pholox St.
LA 1 and LA 190
Downwind of several
petroleum facilities
Hwy. 167
Hwy. 167
Zip
Code
70734
70734
70734
70734
70734
70734
70734
70734
70734
70807
70807
70807
70807
70807
70807
70807
70807
70807
70805
70807
70807
70807
70805
70805
70807
70807
71730
71730
Sampling
Time
1630-1550
1155-1615
1215-1240
1620-1537
1615-1220
1025-1240
1620-1537
1330-1400
1603-1220
1150-1110
1135-1130
1220-1615
1207-1237
1205-1630
1235-1550
1625-1215
1640-1030
1330-1640
1400-1700
1650-1100
1715-1115
1105-1505
1140-1550
1215-1610
1700-0900
1530-0930
1330-1530
1325-1524
Calendar
Day - Year
59-60-77
60-77
60-77
59-60-77
60-1-77
61-77
59-60-77
60-77
60-1-77
62-3-77
62-3-77
62-77
63-77
67-77
67-77
67-8-77
67-8-77
68-77
68-77
68-9-77
68-9-77
69-77
69-77
69-77
69-70-77
69-70-77
264-76
264-76
Ciwc .
(ng/m^)
86
43
86
11
100
36
7
32
100
85
34
32
60
11
44
53
43
33
64
20 + 0
364
13
47
17
250
18
(continued)
-------
Table D4 (cont'd)
CO
EPA
Region Compound CASS It Site
VI tetrachloroethylene 127-18-4 El Dorado, AK
(cont.) El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Liberty Mounds, OK
Tulsa, OK
Liberty Mounds, OK
Tulsa, OK
Vera, OK
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
Address
AK City Water Tower
Parker's Chapel
Water Tower
Hwy. 167
Hwy. 167
llwy. 167
Devil's Swamp
Devil's Swamp
Devil's Swamp
District Water Works
2nd & Elwood
District Water Works
2nd & Elwood
-
Aldine (Mail Rt.)
Clanton Dr.
Clanton Dr.
Crawford at Polk
Aldine (Mail Rt.)
Crawford at Polk
Clanton Dr.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Hwy. 10
Zip
Code
71730
71730
71730
71730
71730
74047
74103
74047
74103
74083
77037
or 9
77080
77080
77002
77037
or 9
77002
77080
77003
or 11
77003
or 11
77003
or 11
77003
or 11
79902
Sampling
Time
2000-0900
2130-0930
1140-1411
1140-1415
1140-1415
1935-1430
1535-1400
1535-1400
0355-0355
0600-0600
0600-0900
0600-0900
1400-1700
0945-1245
0745-1050
0630-0930
0615-0915
1207-1510
1546-1853
0607-0907
1730-0930
1000-0900
1030-0915
1000-1015
1150-1245
1150-1245
1280-1330
1015-1145
Calendar
Day - Year
268-9-76
268-9-76
265-76
265-76
265-76
132-4-77
136-8-77
136-8-77
191-(2)-77
192-(3)-77
264-77
264-77
264-77
173-77
179-77
231-77
292-77
293-77
294-77
294-77
195-7-77
202-4-77
204-6-77
208-10-77
99-101-78
99-101-78
99-101-78
115-7-78
Cone.
(ng/m3)
T (59)
T (60)
T (60)
T
T
T
T
T
T (55)
69 + 8
T (79)
262 + 77
252 + 130
250 + 0
T (46)
T (62)
57 + 4
T (44)
130 + 26
(continued)
-------
Table D4 (cont'd)
N>
EPA
Region Compound CASS // Site
VI tetrachloroethylene 127-18-4 El Paso, TX
(cent-) El Paso, TX
El Dorado, AK
El Dorado, AK
El Dorado, AK
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
VI chlorobenzene 108-90-7 Pasadena, TX
Bay town, TX
Texas City, TX
Pasadena, TX
Pasadena, TX
Pasadena, TX
Pasadena, TX
Texas City, TX
Pasadena, TX
Deer Park, TX
Deer Park, TX
Freeport, TX
La Porte, TX
La Porte, TX
La Porte, TX
Plaquemlne, LA
Gelsmar, LA
Geismar, LA
Gelsmar, LA
Geismar, LA
Geismar, LA
Address
Hwy. 10
Hwy. 10
Off Hwy. 15
Off Hwy. 15
Off Hwy. 15
US 90
US 90
US 90
US 90
US 90
US 90
Shaw Dr.
7200 Bayway Dr.
-
Mae Street
Mae Street
Shaw Dr.
Shaw Dr.
Connie #10
C. H. Milby Park
Off Tidal Rd.
Off Tidal Rd.
Off St. 352
Off Hwy. 225
Off Hwy. 225
Off Hwy. 225
Plaquemine Ever-
green Plantation
Hwy. 73
Between Hwy . 30 & 73
Off LA 75
Hwy. 73
Off Hwy. 73
Zip
Code
79902
79902
71730
71730
71730
70601
70601
70601
70601
70601
70601
77506
77520
77590
77502
77502
77506
77506
77590
77017
77536
77536
77541
77571
77571
77571
70764
70734
70734
70734
70734
70734
Sampling
Time
1015-1145
0918-1235
1329-1257
1329-1257
1329-1257
1430
1430
1430
1430
1425
1476
1130-1130
1630-1630
1415-1415
1430-2200
1000-1000
1000-1000
2230-1017
1200-2235
1005-1425
1455-1555
1115-1215
1342-1543
1645-1833
1641-1824
1114-1252
1250-1725
1155-1615
1215-1240
1620-1537
1615-1220
1025-1240
Calendar Cone.
Day - Year (ng/m3)
115-7-78
115-7-78
138-9-78
138-9-78
138-9-78
174-5-78
174-5-78
174-5-78
174-5-78
174-5-78
174-5-78
315-6-74
317-8-74
316-7-74
237-75
237-8-75
238-9-75
238-9-75
239-75
241-75
211-76
212-76
221-76
224-76
224-76
225-76
33-77 29 ± 10
60-77 93
60-77 93
59-60-77 T
60-1-77 143
61-77 171
(continued)
-------
Table DA (cont'd)
o
o
EPA
Region Compound CASS // Site
VI chlorobenzene 108-90-7 Geismar, LA
Baton Rouge, LA
Baton Rouge , LA
Baton Rouge, LA
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, IX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
El Dorado, AK
El Dorado, AK
El Dorado, AK
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
VI bromofonn 75-25-2 Pasadena, TX
Texas City, TX
Houston, TX
Houston, TX
Pasadena, TX
Pasadena, TX
El Dorado, AK
El Dorado, AK
Address
Off LA 75
Choctaw Rd. &
Pholox St.
Devil's Swamp
Devil's Swamp
Clanton Dr.
Crawford at Polk
Aldine (Mail Rt.)
Crawford at Polk
Clanton Dr.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Off Hwy. 1$
Off Hwy. 15
Off Hwy. .15
US 90
US 90
US 90
Shaw Dr.
-
5609 May St.
May St.
Mae St.
Shaw Dr.
Hwy. 15
Hwy. 15
Zip
Code
70734
70805
77080
77002
77037
or 9
77002
77080
77003
or 11
77003
or 11
77003
or 11
77003
or 11
71730
71730
71730
70601
70601
70601
77506
77590
77076
77076
77502
77506
71730
71730
Sampling
Time
1620-1537
1215-1610
1935-1430
1515-1530
0630-0930
0615-0915
1207-1510
1546-1853
0607-0907
1000-0900
1030-0915
0915-0945
1000-1015
1329-1257
1329-1257
1329-1257
1430
1430
1425
1130-1130
1415-1415
1630-1630
1245-2700
1000-1000
1000-1000
1330-1523
1200-1420
Calendar
Day - "Year
59-60-77
69-77
132-4-77
134-6-77
231-77
292-77
293-77
294-77
294-77
202-4-77
204-6-77
206-8-77
208-10-77
138-9-78
138-9-78
138-9-78
174-5-78
174-5-78
174-5-78
315-6-74
316-7-74
320-1-74
235-75
237-8-75
238-9-75
264-76
268-76
Cone.
(ng/n3)
900
10
T (153)
T (128)
T (283)
T (132)
T (168)
T (224)
T (139)
T (132)
T (132)
125 + 0
52
17
29
7
T
15.1
(continued)
-------
Table D4 (cont'd)
u>
o
EPA
Region Compound
VI bromoform
(cont. )
CASS // Site
75-25-2 El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Address
Hwy. 15
Hwy. 167
Hwy. 167
Hwy. 167
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. .15
Hwy. 15
Hwy. • 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. : 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 167
Hwy. 167
Hwy. 167
Hwy. 167
Hwy. 167
Hwy. 167
Hwy. 132
Hwy. 132
Hwy. 132
Off Hwy 15
Off Hwy. 15
Off Hwy. 15
US 90
US 90
US 90
US 90
US 90
Zip
Code
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71753
71753
71753
71730
71730
71730
70601
70601
70601
70601
70601
Sampling
Time
1200-1420
1140-1411
1140-1614
1105-1742
1139-1240
1155-1305
1242-1315
1514-1334
1256-1110
1310-1121
1321-1131
1400-1147
1347-1139
1127-1047
1137-1130
1147-1143
1115-0900
1138-0910
1210-0950
1150-0925
1140-0945
1205-1000
1400-0945
1020-1010
0940-1002
1005-1033
1208-1100
1035-0845
1000-0820
1329-1257
1329-1257
1329-1257
1430
1430
1430
1425
1476
Calendar
Day - Year
268-76
265-76
265-76
265-76
199-200-77
199-200-77
199-200-77
199-200-77
200-1-77
200-1-77
200-1-77
200-1-77
200-1-77
201-2-77
201-2-77
201-2-77
202-3-77
202-3-77
202-3-77
202-3-77
203-4-77
203-4-77
204-5-77
204-5-77
205-6-77
205-6-77
213-4-77
215-6-77
215-6-77
138-9-78
138-9-78
138-9-78
174-5-78
174-5-78
174-5-78
174-5-78
174-5-78
Cone.
(ng/m3)
11.96
26.4
T
4.0
T
25
20
22
T
T
T
T
98
T
104
37
T
22
T
T
T
T
T
T
T
T
8
380
50
309
729
265
68
637 + 220
(continued)
-------
Table D4 (cont'd)
EPA
Region Compound CASS t Site
VI bromobenzene 108-86-1 El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
VI B-dichlorobenzene 541-73-1 Houston, TX
Houston, TX
Address
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 167
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy
Hwy . -15
Hwy. 15
Hwy. 15
Hwy- 15
Hwy. 132
Hwy. 132
Hwy. 132
Off Hwy. 15
Off Hwy. 15
Off Hwy. 15
5609 May St.
May St.
Zip
Code
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71753
71753
71753
71753
71730
71730
71730
77076
77076
Sampling
Time
1200-1420
1200-1420
1745-0945
1105-1742
1955-1420
1155-1305
1242-1315
1543-1352
1515-1334
1310-1121
1321-1131
1400-1147
1347-1139
1118-1032
1127-1047
1137-1130
1152-1150
1147-1143
1042-0845
1115-0900
1138-0910
1210-0950
1150-0925
1120-0846
1100-0900
1000-0820
1038-0840
1329-1257
1329-1257
1329-1257
1630-1630
1245-2400
Calendar
Day - Year
268-76
268-76
268-9-76
265-76
198-9-77
199-200-77
199-200-77
199-200-77
199-200-77
200-1-77
200-1-77
200-1-77
200-1-77
201-2-77
201-2-77
201-2-77
201-2-77
201-2-77
202-3-77
202-3-77
202-3-77
202-3-77
202-3-77
215-6-77
215-6-77
215-6-77
215-6-77
138-9-78
138-9-78
138-9-78
320-1-74
235-75
Cone .
(ng/m3)
20.7
60
25
28
53
470
3,842
188
1,131
29
4,276
20
51
T
280
1,041
22
980
4.5
428
95
4.8
4.8
23
140
35
66
(continued)
-------
Table D4 (cont'd)
u>
o
oo
EPA
Region Compound CASS t Site
VI m-dichlorobenzene 541-73-1 Pasadena, TX
(cont.) Pasadena, TX
Pasedena, TX
Pasedena , TX
Texas City, TX
Pasadena, TX
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
Houston, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
El Paso, TX
Address
Mae St.
Mae St.
Shaw Dr.
Shaw Dr.
Connie #10
C.H. Milby Park
Devil's Swamp
Devil's Swamp
Devil's Swamp
Aldine (Mail Rt)
Clanton Dr.
Clanton Dr.
Aldine (Mail Rt)
Crawford at Polk
Aldine (Mail Rt)
Crawford at Polk
Clanton Dr.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
Hwy. 10
Hwy. 10
Zip
Code
77502
77502
77506
77506
77590
77017
77037
or 39
77080
77080
77037
77002
77037
77002
77080
77003
or 11
77003
or 11
77003
or 11
77003
or 11
79902
79902
Sampling
Time
1430-2200
1000-1000
1000-1000
2230-1017
1200-2235
1005-1425
1935-1430
1515-1530
1535-1400
0945-1245
0745-1050
0630-0930
or 9 0630-0930
0615-0915
or 9 1207-1510
1546-1853
0607-0907
1000-0900
1030-0915
0915-0945
1000-1015
1150-1245
1150-1245
1218-1330
1015-1145
1015-1145
0918-1235
Calendar
Day - Year
237-75
237-8-75
238-9-75
238-9-75
239-75
241-75
132-4-77
134-6-77
136-8-77
173-77
179-77
231-77
232-77
292-77
293-77
294-77
294-77
202-4-77
204-6-77
206-8-77
208-10-77
99-101-78
99-101-78
99-101-78
115-7-78
115-7-78
115-7-78
Cone.
(ng/m3)
T(102)
T(85)
T(87)
T(110)
T(127)
T(159)
1(179)
T(88)
T(112)
T(149)
T(92)
T(88)
T(88)
t(83)
T(87)
(continued)
-------
Table D4 (cont'd)
o
•P-
EPA
Region Compound
VI m-dichlorobenzene
(cont.)
VI £-dichlorobenzene
VI dichlorobenzene
idomer(s)
CASS I Site
541-73-1 El Paso, TX
El Dorado, AK
El Dorado, AK
El Dorado, AK
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
Lake Charles, LA
' Lake Charles, LA
95-50-1 Pasadena, TX
Pasadena, TX
Pasadena, TX
Pasadena, TX
Baton Rouge, LA
Baton Rouge, LA
Baton Rouge, LA
Tulsa, OK
Tulsa, OK
Houston, TX
Houston, TX
Houston, TX
Lake Charles, LA
Lake Charles, LA
541-73-1 Houston, TX
or Pasadena, TX
95-50-1 Baytown, TX.
Texas City, TX
Texas City, TX
Houston, TX
Houston, TX
Address
Hwy. 10
Off Hwy. 15
Off Hwy. 15
Off Hwy. 15
US 90
IS 90
US 90
US 90
US 90
Mae St.
Shaw Dr.
Shaw Dr.
C.H. Milby Park
Devil's Swamp
Devil ' s Swamp
Devil ' s Swamp
2nd & Elwood
2nd & Elwood
Navigation Blvd.
Navigation Blvd.
Navigation Blvd.
US 90
US 90
5609 May St.
Shaw Dr.
7200 Bayway Dr.
Connie #10
Milby Park
Steelman Ave.
Zip
Code
79902
71730
71730
71730
70601
70601
70601
70601
70601
77502
77506
77506
77017
74103
74103
77003
or 11
77003
or 11
77003
or 11
70601
70601
77076
77506
77520
77590
77590
77017
77017
Sampling
Time
1329-1257
1329-1257
1329-1257
1430
1430
1430
1430
1425
1476
1000-1000
1000-1000
2230-1017
1005-1425
1935-1430
1515-1530
1535-1400
0600-0600
0600-0900
100-0900
0915-0945
1000-1015
1430 rain.
1430 min
1630-1630
1130-1130
1630-1630
1415-1415
2235-1155
1670-1750
1620-1750
Calendar
Day - Year
138-9-78
138-9-78
138-9-78
174-5-78
174-5-78
174-5-78
174-5-78
174-5-78
174-5-78
237-8-75
238-9-75
238-9-75
241-75
132-4-77
134-6-77
136-8-77
192-(3)-77
264-77
202-4-77
206-8-77
206-10-77
174-5-78
124-5-78
320-1-74
315-6-74
317-8-74
316-7-74
239-40-75
209-76
209-76
Cone.
(ng/m3)
16
27
14
7
6
15 ± 6
T(84)
T(85)
T(87)
T
T
T(88)
T(83)
T(86)
T
T
(continued)
-------
Table D4 (cont'd)
o
Ui
EPA
Region Compound CASS * Site
VI dichlorobenzene 541-73-1 Pasadena, TX
isomer (a) or Deer Park, TX
(cont.) 95-50-1 Deer Park, TX
Freeport , TX
Freeport, TX
Freeport, TX
LaPorte, TX
LaPorte, TX
Flaquemine , LA
Plaquemlne, LA
Plaquemlne, LA
Geismar, LA
Geismar, LA
Geismar, LA
El Dorado, AK
Liberty Mounds, OK
Tulsa, OK
Tulsa, OK
VI 1, 3-hexachlorobutadiene 87-68-3 Deer Park, TX
Deer Park, TX
Deer Park, TX
Freeport, TX
Freeport, TX
La Porte, TX
La Porte, TX
Plaquemine, LA
Plaquemlne, LA
Baton Rouge, LA
Baton Rouge, LA
Address
Off Hwy. 225
Off Tidal Rd.
Off Hwy. 225
Off St. 352
Off St. 352
Off St. 352
Off Hwy. 225
Off Hwy. 225
Off LA 1
Off LA 1
Plaquemlne Evergreen
Plantation
Hwy. 73
Between Hwy. 30 & 73
Off LA 75
Off Hwy. 15
District Water Works
2nd, & Elwood
2nd, & Elwood
Off Tidal Rd.
Off Tidal Rd
Off Tidal Rd
Off St. 325
Off St. 325
Off Hwy. 225
Off Hwy. 225
Off LA 1
Off LA 1
Off LA 61
Downwind of several
petroleum facilities
Zip
Code
77503
77536
77536
77541
77541
77541
77571
77571
70764
70764
70764
70734
70734
70734
71730
74047
74103
74103
77536
77536
77536
77541
77541
77571
77571
70764
70764
70805
70807
Sampling
Time
1430-1600
1100-1200
1100-1200
1342-1543
1348-1555
1425-1507
1645-1833
1641-1824
1600-1015
1745-1015
1250-1725
1155-1615
1215-1240
1620-1537
1330-1524
0355-0355
0600-0600
0600-0900
1455-1555
1115-1215
1115-1215
1342-1543
1348-1555
1641-1824
1114-1252
1600-1015
1745-1015
1140-1550
1530-0930
Calendar
Day - Year
210-76
211-76
211-76
221-76
221-76
221-76
224-76
224-76
32-3-77
32-3-77
33-77
60-77
60-77
59-60-77
264-76
191-(2)-77
192-(3)-77
264-77
211-76
212-76
212-76
221-76
221-76
224-76
224-76
32-3-77
32-3-77
69-77
69-70-77
Cone.
(ng/m3)
81 ±
T
T
334
2,066
25
13.3
8.3
T
T
18 ±
37 ±
23
117
39
3
15
(continued)
-------
Table D4 (cont'd)
OJ
o
ON
EPA
Region Compound
VI dichlorobutane
isoraer (s)
VI dibromochloropropane
isomer (s)
CASS t Site
Plaquemine , LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Plaquemine, LA
Eaton Rouge, LA
Baton Rouge, LA
96-12-8 El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Address
Bayou Rd.
Church and Main St.
LA 988 6. Davis St.
Off LA 1
Plaquemine Evergreen
Plantation
Off US 61 North
of Plant A
Off Mengel Rd.
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Zip
Code
70764
70764
70764
70764
70764
70807
70807
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
71730
Sampling
Time
1437-1320
1540-1350
1255-1705
1745-1015
1325-1715
1150-1110
1105-1505
1155-1305
1242-1315
1514-1334
1256-1110
1310-1121
1321-1131
1400-1147
1347-1139
1118-1032
1147-1143
1042-0845
1150-0925
1130-0925
1140-0945
1205-1000
1105-1015
1220-1040
0935-0925 '
1400-0945
1010-1000
1020-1010
Calendar
Day - Year
31-2-77
31-2-77
32-77
32-3-77
33-77
62-3-77
69-77
199-200-77
199-200-77
199-200-77
200-1-77
200-1-77
200-1-77
200-1-77
200-1-77
201-2-77
201-2-77
202-3-77
202-3-77
203-4-77
203-4-77
203-4-77
203-4-77
203-4-77
204-5-77
204-5-77
204-5-77
204-5-77
Cone.
(ng/m3)
153 ±70
2,714 ± 2,000
71 ± 45
1,392 ± 178
54 ± 25
193
13
1.4
1.4
T
T
T
T
T
2.8
T
5.6
T
T
93
174
7.8
34
14
12
187
37
32
(continued)
-------
Table D4 (cont'd)
EPA
Region Compound CASS //
VI dibromochloropropane
isomer(s)
VI l-chloro-2, 3-dibro-
mopropane 96-12-8
Site
El Dorado AK
El Dorado AK
El Dorado AK
El Dorado AK
El Dorado AK
El Dorado AK
El Dorado AK
El Dorado AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Address
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Off Hwy. 167
Hwy. 132
Hwy. 132
Hwy. 132
Hwy. 132
Hwy. 132
Hwy. 132
Hwy. 132
Hwy. 132
Hwy. 132
Hwy. 132
Hwy. 132
Hwy. 15
Hwy. 15
Hwy. 167
Hwy. 167
Hwy. 167
Zip
Code
71730
71730
71730
71730
71730
71730
71730
71730
71753
71753
71753
71753
71753
71753
71753
71753
71753
71753
71753
71730
71730
71730
71730
71730
Sampling
Time
1040-1025
0940-1002
0950-1017
1005-1033
1055-1045
1055-1040
1040-0840
1055-0850
1055-0950
1130-1030
1208-1100
1000-1005
1150-1105
1110-1045
1230-0945
1015-0830
1035-0840
1100-0900
1000-0820
1330-1523
1200-1420
1140-1415
1124-1625
1120-1625
Calendar
Day - Year
204-5-77
205-6-77
205-6-77
205-6-77
205-6-77
205-6-77
206-7-77
206-7-77
213-4-77
213-4-77
213-4-77
214-5-77
214-5-77
214-5-77
214-5-77
215-6-77
215-6-77
215-6-77
215-6-77
264-76
268-76
265-76
265-76
J65-76
Cone.
(ng/m3)
T
T
T
T
T
T
T
T
25
75
1,996
99
624
6,653
300
36
100
188
2,002
1.87
T
17
6.5
20.6
(continued)
-------
Table DA (cont'd)
EPA
Region
Compound
CASS
Site
Address
Zip
Code
Sampling
Time
Calendar
Day - Year
Cone.
VI l,l-dibromo-2~
chloropropane
VI 1,2- or 1,3-dibromo-
propane
96-12-8
78-75-1
or
109-64-8
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
Hwy. 167
Hwy. 167
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy.. 15
Hwy. 15
Hwy. 15
Hwy. 132
Hwy. 132
Hwy. 132
Hwy. 132
Hwy- 132
Hwy. 132
Hwy- 132
71730
1140-1415
265-76
2.6
71730
71730
71730
71730
71730
71730
71730
71730
71753
71753
71753
71753
71753
71753
71753
1140-1415
1242-1315
1127-1047
1137-1130
1147-1143
1042-0845
1210-0950
1150-0925
1000-1005
1150-1105
1110-1045
1230-0945
1015-0830
1100-0900
1000-0820
265-76
199-200-77
201-2-77
201-2-77
201-2-77
202-3-77
202-3-77
202-3-77
214-5-77
214-5-77
214-5-77
214-5-77
215-6-77
215-6-77
215-6-77
1.1
T
I
T
T
T
T
T
T
T
T
T
T
T
T
co
o
co
(continued)
-------
Table D4 (cont'd)
U)
o
EPA
Region
VI
VI
VI
VI
Compound CASS t Site
1,2-or 1,3-dibromo- 78-75-1 Magnolia,
propane (cont.) or Magnolia,
109-64-8 Magnolia,
Magnolia,
Magnolia,
Magnolia,
Magnolia,
dichlorodibromo- Pasadena ,
methane Pasadena , '
El Dorado,
El Dorado,
chlorobromopropane 109-70-6 El Dorado,
isomer El Dorado,
El Dorado,
Magnolia ,
l-chloro-3-bromo- 109-70-6 El Dorado,
propane El Dorado,
El Dorado,
El Dorado,
El Dorado,
El Dorado,
Magnolia,
Magnolia,
Magnolia,
Magnolia,
Magnolia,
Magnolia,
Magnolia ,
Magnolia,
Magnolia,
Address
AK
AK
AK
AK
AK
AK
AK
TX
TX
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
AK
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
132
132
132
132
132
132
132
Mac St.
Shaw
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Hwy.
Dr.
167
167
167
167
167
79
15
15
15
167
167
167
79
79
79
79
79
79
79
79
79
Zip
Code
71753
71753
71753
71753
71753
71753
71753
77502
77506
71730
71730
71730
71730
71730
71753
71730
71730
71730
71730
71730
71730
71753
71753
71753
71753
71753
71753
71753
71753
71753
Sampling
Time
1000-1005
1150-1105
1110-1045
1230-0945
1015-0830
1100-0900
1000-0820
1000-1000
1000-1000
1140-1411
1124-1625
1140-1415
1120-1625
1105-1742
1422-1726
1200-1420
1740-0948-
1745-0945
1140-1415
1140-1614
1120-1625
1620-0935
1708-1018
0945-0845
1005-0900
1020-1000
1055-1012
0850-0845
0915-0915
1002-1005
Calendar
Day - Year
214-5-77
214-5-77
214-5-77
214-5-77
215-6-77
215-6-77
215-6-77
237-8-75
238-9-75
265-76
265-76
205-76
265-76
265-76
267-76
268-76
268-9-76
268-9-76
265-76
265-76
264-76
207-8-77
207-8-77
208-9-77
208-9-77
208-9-77
208-9-77
209-10-77
209-10-77
209-10-77
Cone.
-------
Table D4 (cont'd)
EPA
Region
VI
VI
VI
VI
VI
Compound
l-chloro-3-bromo-
propane
(cont . )
l-chloro-3-bromo
propene
dichloropropene
isomer(s)
1,3,5-trichloro-
benzene
trlchlorobenzene
isomer(s)
CASS t Site
109-70-6 Magnolia, AK
Magnolia, AK
Magnolia, AK
Magnolia, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
El Dorado, AK
26952-23-8 Pasadena, IX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Deer Park, TX
Plaquemine , LA
Plaquemine, LA
Plaquemine , LA
108-70-3 Pasadena, TX
12002-48-1 Houston, TX
Houston, TX
El Paso, TX
El Paso, TX
Address
Hwy. 79
Hwy. 79
Hwy. 79
Hwy. 79
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Hwy. 15
Off Hwy- 225
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off Tidal Rd.
Off LA 1
Off LA 1
Bayou Rd.
C.H. Milby Park
Crawford at Polk
Clanton Dr.
Zip
Code
71753
71753
71753
71753
71730
71730
71730
71730
71730
71730
77503
77536
77536
77536
77536
77536
77536
77536
77536
77536
70764
70764
70764
77017
77002
77080
Sampling
Time
1035-0955
0900-1125
0925-1130
1000-1150
1242-1315
1256-1110
1127-1047
1115-0900
1138-0910
1150-0925
1420-1600
1100-1200
1100-1200
1100-1200
1020-1035
1115-1215
1115-1215
1115-1215 '
1115-1215
1115-1215
1600-1015
1745-1015
1437-1320
1005-1425
1546-1853
0607-0907
1150-1245
1150-1245
Calendar
Day - Year
209-10-77
210-1-77
210-1-77
210-1-77
199-200-77
200-1-77
201-2-77
202-3-77
202-3-77
202-3-77
210-76
211-76
211-76
211-76
212-76
212-76
212-76
212-76
212-76
212-76
32-3-77
32-3-77
31-2-77
241-75
294-77
294-77
99-101-78
99-101-78
Cone.
(ng/m3)
T
1,688
20
171
T
T
T
T
T
T
180
90
90
T,T
241
1,291
72
1,293
345
106 + 4
261 + 92
10 + 5
T (55)
T (75)
-------
Table D5. VAPOR-PHASE HALOGENATED CHEMICALS - EPA REGION VIII
EPA
Region Compound
VIII chloroform
VIII 1, 2-dichloroethylene
VIII carbon tetrachloride
CASS t site
67-66-3 Denver, CO
Denver, CO
Magna, UT
Magna, UT
Magna, UT
Magna, UT
Grand Canyon, AZ
Grand Canyon, AZ
Grand Canyon , AZ
Grand Canyon, AZ
Grand Canyon, AZ
Grand Canyon, AZ
Grand Canyon , AZ
540-59-0 Magna, UT
Magna, UT
Magna, UT
Grand Canyon, AZ
56-23-5 Denver, CO
Denver , CO
Magna, UT
Magna, UT
Magna, UT
Magna, UT
Magna, UT
Zip
Address Code
Eisenhower Tunnel
16th Ave. & Park 80218
84044
84044
84044
84044
86023
86023
86023
86023
86023
86023
86023
84044
84044
84044
86023
Eisenhower Tunnel
16th Ave. 4 Park 80218
84044
84044
84044
84044
84044
Sampling
Time
2024-0550
1200-1800
1010-1019
1045-1045
1045-1145
1115-1245
0930-1030
1030-1015
1015-1015
1015-1640
1645-1613
1510-1410
1415-1500
1000-0930
1045-1045
1045-1145
1015-1640
2024-0550
1200-1800
1000-0930
1010-1019
1045-1045
1045-1145
1115-1245
Calendar
Day - Year
252-75
249-75
299-301-77
301-3-77
303-5-77
305-7-77
332-3-77
333-4-77
334-5-77
335-6-77
336-7-77
337-8-77
338-9-77
297-9-77
301-3-77
303-5-77
335-6-77
252-75
249-75
297-9-77
299-301-77
301-3-77
303-5-77
305-7-77
Cone.
-------
Table D5 (cont'd)
EPA
Region Compound CASS t
VIII carbon tetrachloride 56-23-5
(cont.)
VIII 1,1,1-trichloroethane 71-55-6
VIII trichloroethylene 79-01-6
Site
Grand Canyon ,
Grand Canyon,
Grand Canyon ,
Grand Canyon,
Grand Canyon,
Denver, CO
Denver, CO
Magna, UT
Magna, UT
Magna, UT
Magna, UT
Magna, UT
Grand Canyon ,
Grand Canyon,
Grand Canyon,
Grand Canyon,
Grand Canyon,
Grand Canyon,
Grand Canyon,
Denver, CO
Denver , CO
Magna, UT
Magna, UT
Magna, UT
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
Zip
Address Code
86023
86023
86023
86023
86023
Eisenhower Tunnel
16th Ave.6. Park 80218
84044
84044
84044
84044
84044
86023
86023
86023
86023
86023
86023
86023
Eisenhower Tunnel
16th Ave. & Park 80218
84044
84044
84044
Sampling
Time
1030-1015
1015-1640
1645-1613
1510-1410
1415-1500
2024-0550
1200-1800
1000-0930
1010-1019
1045-1045
1045-1145
1115-1245
0930-1030
1030-1015
1015-1015
1015-1640
1645-1613
1510-1410
1415-1500
2024-0550
1200-1800
1010-1019
1045-1045
1045-1145
Calendar
Day - Year
333-4-77
335-6-77
336-7-77
337-8-77
338-9-77
252-75
249-75
297-9-77
299-301-77
301-8-77
303-5-77
305-7-77
332-3-77
333-4-77
334-5-77
335-6-77
336-7-77
337-8-77
338-9-77
252-75
249-75
299-301-77
301-3-77
303-5-77
Cone.
(ng/m3)
T(59)
T(59)
T(59)
T(59)
T(59)
T(334)
T(334)
T(334)
1(334)
T(334)
218
il
T(217)
T(217)
T(217)
T(217)
T(217)
T(217)
1(100)
1(100)
T(100)
(continued)
-------
Table D5 (cont'd)
U>
EPA
Region Compound
VIII trichloroethylene
(cont.)
VIII tetrachloroethylene
VIII chlorobenzene
CASS t Site
79-01-6 Magna, UT
Grand Canyon,
Grand Canyon ,
Grand Canyon ,
Grand Canyon,
Grand Canyon,
Grand Canyon ,
127-18-4 Denver, CO
Denver , CO
Magna, UT
Magna, UT
Magna, UT
Magna, UT
Grand Canyon,
Grand Canyon,
Grand Canyon,
Grand Canyon,
Grand Canyon,
Grand Canyon,
108-90-7 Denver, CO
Denver , CO
Magna, UT
Magna, UT
Magna, UT
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
Zip
Address Code
84044
86023
86023
86023
86023
86023
86023
Elsenhower Tunnel
16th Ave. & Park 80218
84044
84044
84044
84044
86023
86023
86023
86023
86023
86023
Eisenhower Tunnel
16th Ave. & Park 80218
84044
84044
84044
Sampling
Time
1115-1245
0930-1030
1030-1015
1015-1015
1015-1640
1510-1410
1415-1500
2024-0550
1200-1800
1000-0930
1010-1019
1045-1045
1045-1145
0930-1030
1015-1015
1015-1640
1645-1613
1510-1410
1415-1500
2024-0550
1200-1800
1000-0930
1010-1019
1045-1045
Calendar
Day - Year
305-7-77
332-3-77
333-4-77
334-5-77
335-6-77
337-8-77
338-9-77
252-75
249-75
297-9-77
299-301-77
301-3-77
303-5-77
332-3-77
334-5-77
335-6-77
336-7-77
337-8-77
338-9-77
252-75
249-75
297-9-77
299-301-77
301-3-77
Cone.
(ng/m3)
T(39)
TU30)
T(130)
T(130)
T(130)
T(130)
T(130)
79
±30
80
±31
T(54)
T(34)
T(234)
T(234)
T(234)
T(234)
T(234)
1(234)
T<105)
T(104)
T(115)
(continued)
-------
Table D5 (cont'd)
EPA
Region Compound
VIII chlorobenzene
(cont.)
VIII m-d ichlorobenzene
VIII o-dichlorobenzene
C«SS # Site
108-90-7 Magna, UT
Grand Canyon,
Grand Canyon ,
Grand Canyon,
Grand Canyon,
Grand Canyon,
541-73-1 Denver, CO
Denver, CO
Magna, UT
Magna, UT
Magna, UT
Magna, UT
Magna, UT
Grand Canyon ,
Grand Canyon ,
Grand Canyon ,
Grand Canyon ,
Grand Canyon ,
Grand Canyon,
Grand Canyon,
95-50-1 Magna, UT
Magna, UT
Magna, UT
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
Zip
Address Code
84044
86023
86023
86023
86023
86023
Eisenhower Tunnel
16th Ave. & Park 80218
84044
84044
84044
84044
84044
86023
86023
86023
86023
86023
86023
86023
84044
84044
84044
Sampling
Time
1045-1145
0930-1030
1015-1015
1645-1613
1510-1410
1415-1500
2024-0550
1200-1800
1000-0930
1010-1019
1045-1045
1045-1145
1115-1245
0930-1030
1030-1015
1015-1015
1015-1640
1645-1613
1510-1410
1415-1500
1000-0930
1045-1045
1045-1145
Calendar
Day - Year
303-W7
332-3-77
334-5-77
336-7-77
337-8-77
338-9-77
252-75
249-75
297-9-77
299-301-77
301-3-77
303-5-77
305-7-77
332-3-77
333-4-77
334-5-77
335-6-77
336-7-77
337-8-77
338-9-77
297-9-77
301-3-77
303-5-77
Cone .
T(104)
T(105)
T(105)
T(390)
T(390)
T(390)
T(70)
T(69)
T(77)
T(69)
T(77)
T(260)
260
T(260)
T(260)
T(260)
T(260)
T(260)
(continued)
-------
Table D5 (cont'd)
EFA
Region Compound CASS t Site
VIII vinylidene chloride 75-35-4 Grand Canyon,
Grand Canyon,
Grand Canyon,
Grand Canyon,
Grand Canyon ,
VIII methylene chloride 75-09-2 Denver, CO
Denver, CO
Magna, UT
Magna, UT
Magna, UT
Magna, UT
Magna, UT
Grand Canyon,
Grand Canyon ,
Grand Canyon ,
Grand Canyon,
Grand Canyon,
Grand Canyon,
Grand Canyon,
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
AZ
Zip
Address Code
86023
86023
86023
86023
86023
Eisenhower Tunnel
16th Ave. S. Park 80218
84044
84044
84044
84044
84044
86023
86023
86023
86023
86023
86023
86023
Sampling
Time
0930-1030
1015-1015
1015-1640
1645-1613
1510-1410
2024-0550
1200-1800
1000-0930
1010-1019
1015-1045
1045-1145
1115-1245
0930-1030
1030-1015
1015-1015
1015-1640
1645-1613
1510-1410
1415-1500
Calendar
Day - Year
332-3-77
334-5-77
335-6-77
336-7-77
337-8-77
252-75
249-76
297-9-77
299-301-77
301-3-77
303-5-77
305-7-77
332-3-77
333-4-77
334-5-77
335-6-77
336-7-77
337-8-77
338-9-77
Cone.
(ng/n.3)
T(714)
23,714
±13,428
6,071
±785
2,071
±929
5,714
u>
VIII 1,1-dichloroethane
75-34-3
Magna, UT
84044
1115-1245
305-77
T(334)
-------
Table D6. VAPOR-PHASE HALOGENATED CHEMICALS - EPA REGION VII
o\
EPA
Region Compound CASS //
VII carbon tetrachloride 56-23-5
VII trichloroethylene 79-01-6
VII tetrachloroethylene 127-18-4
VII chlorobenzene 108-90-7
VII m-dichlorobenzene 548-73-1
VII £-dichlorobenzene 95-50-1
VII 1,3, 5-trichlorobenzene 108-70-3
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
St.
Site
Louis, MO
Louis, MO
Louis, MO
Ann, MO
Louis, MO
Louis, MO
Ann, MO
Louis, MO
Louis, MO
Ann, MO
Louis, MO
Louis, MO
Ann, MO
Louis, MO
Louis, MO
Address
4400 Lindell
4400 Lindell
4400 Lindell
St. Charles Rd. and
Industrial Blvd.
4400 Lindell
4400 Lindell
St. Charles Rd. and
Industrial Blvd.
4400 Lindell
4400 Lindell
St. Charles Rd. and
Industrial Blvd.
4400 Lindell
4400 Lindell
St. Charles Rd. and
Industrial Blvd.
4400 Lindell
4400 Lindell
Zip
Code
63108
63108
63108
63074
63108
63108
63074
63108
63108
63074
63108
63108
63074
63108
63108
Sampling
Time
0650-1250
0650-1250
2212-0635
2035-0525
0650-1250
2212-0635
2035-0525
0640-1250
2212-0635
2035-0525
0650-1250
2212-0635
2035-0525
0650-1250
0650-1250
Calendar Cone.
Day - Year (ng/m^)
253-75
253-75
252-3-75
251-2-75
253-75
252-3-75
251-2-75
253-75
252-3-75
251-2-75
253-75
252-3-75
251—2-75
253-75
252-75
-------
Table D7. VAPOR-PHASE HALOGENATED CHEMICALS - EPA REGION IX
u>
EPA
Region Compound CASS # Site
IX chloromethane 74-87-3 West Covina, CA
Garden Grove, CA
Anaheim, CA
Torrance, CA
IX methylene chloride 75-09-2 Santa Monica, CA
West Covina, CA
Santa Monica, CA
Glendora, CA
Garden Grove, CA
Anaheim, CA
Anaheim, CA
El Segundo, CA
Torrance, CA
Torrance, CA
Dominquez, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Address
820 Phillips Ave.
12281 Nelson St.
1700 W. Broadway
20100 Normandle
Ave.
2441 Arizona Ave.
820 Phillips Ave.
2441 Arizona Ave.
840 E. Laurel
12281 Nelson St.
1700 W. Broadway
1700 W. Broadway
Illinois St. with
El Segundo Blvd.
19146 Van Ness Blvd.
15th S. Emery St.
2055 223 St.
-
Zip
Code
91791
92640
92805
90502
90404
91791
90404
91740
92650
92805
92805
90245
90504
90023
90745
91786
91786
91786
91786
91786
Samp ling
Time
1000-1615
0900-1630
0930-1700
1357-1451
0850-1700
1000-1615
1700-0800
1000-2100
0900-1630
0930-1700
1730-0815
1329-1423
1307-1412
1534-1624
1322-1416
?
1400-0600
Calendar
Day - Year
093-75
094-75
093-75
134-76
090-75
091-75
090-1-75
092-75
094-75
093-75
093-4-75
133-76
134-76
135-76
135-76
225-7-77
227-9-77
229-31-77
231-3-77
256-8-77
Cone.
(ng/m3)
27,250
+ 17,750
42,000
+ 32,000
1,875
±125
7,750
±250
34,555
+ 14,333
(continued)
-------
Table D7 (cont'd)
LO
H-l
oo
EPA
Region Compound CASS # Site
IX methylene chloride 75-09-2 Upland, CA
(cont . )
Upland, CA
Upland, CA
IX chloroform 67-66-33 Santa Monli-.n, CA
West Covina, CA
Santa Monica, CA
Glendora, CA
Garden Grove, CA
Anaheim, CA
Anaheim, CA
El Segundo, CA
Torrance, CA
Torrance, CA
Los Angeles, CA
Dominguez , CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Address
2441 Arizona Ave.
820 Phillips Ave.
2441 Arizona Ave.
840 E. Laural
12281 Nelson St.
1700 W. Broadway
1700 W. Broadway
Illinois St. with
El Segundo Blvd.
19146 Van Ness Blvd.
20100 Normandie Ave.
15th St. Emery St.
2055 223 St.
-
Zip
Code
91786
91786
91786
90404
91791
90404
91740
92640
92805
92805
90245
90504
90502
90023
90745
91786
91786
91786
91786
Samp Ling
Time
0600-0030
0030-0030
0030-0600
0850-1700
1000-1616
1700-0800
1000-2100
0900-1630
0930-1700
1730-0815
1329-1423
1307-1412
1357-1451
1534-1624
1322-1416
?
c)a U'lular
Day - Yoar
2r)8-(>l-77
262-4-77
264-6-77
090-75
091-75
090-1-75
092-75
094-75
093-75
093-4-75
133-76
134-76
134-76
135-76
135-76
225-7-77
227-9-77
229-31-77
231-3-77
Cone.
(ng/n)3)
40,000
±388
44,250
+ 22,000
37,750
+ 12,000
4,423
±1,346
14,730
+ 13,115
1,269
±269
1,615
±769
(continued)
-------
Table D7 (cont'd)
EPA
Region Compound CASS # Sice
IX chloroform 67-66-33 Upland, CA
(cont.)
Upland, CA
Upland, CA
Upland, CA
IX 1,2-dichloroethane 107-06-2 Sai&a Monica, CA
El Segundo, CA
Torrance, CA
Torrance, CA
Los Angeles, CA
Dominguez , CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Zip
Address Code
91786
91786
91786
91786
2441 Arizona Ave. 90404
Illinois St. with 90245
El Segundo Blvd.
19146 Van Ness Blvd. 90504
20100 Nornandie Ave. 90502
llth Emery St. 90023
2055 223 St. 90745
91786
91786
91786
91786
91786
91786
91786
91786
Samp I ing
Time
1400-0600
0600-0030
0030-0030
0030-0600
0850-1700
1329-1423
1307-1412
1357-1451
1534-1624
1322-1416
?
1400-0600
0600-0030
0030-0030
0030-0060
Calendar
Day - Year
256-8-77
258-61-77
262-4-77
264-6-77
090-75
133-76
134-76
134-76
135-76
135-76
225-7-77
227-9-77
229-31-77
231-3-77
256-8-77
258-11-77
262-4-77
264-6-77
Cone .
(ng/n.3)
885
1448
533
±99
884
±654
423
±38
14,814
T(277)
861
±140
T(444)
1(444)
1(250)
T(400)
T(444)
T(444)
10
(continued)
-------
Table D7 (cont'd)
EPA
Region
Compound
CASS t
Site
IX
1,1,1-trichloroethane 71-55-6
OO
N>
O
West Covlna. CA
Santa Monica, CA
Glendora, CA
Garden Grove, CA
Anaheim, CA
Anaheim, CA
El Segundo, CA
Torrance, CA
Torrance, CA
Los Angeles, CA
Domlnguez, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Address
820 Phillips Ave.
2441 Arizona Ave.
840 E. Laurel
12281 Nelson St.
1700 W. Broadw.-iy
1700 W. Broadway
Illinois St. with
El Segundo Blvd.
19146 Van Ness Blvd.
20100 Normandie Ave.
15th S. Emery St.
2055 223 St.
-
Zip
Qiik-
91791
90404
9174(1
92640
92805
92805
90245
90504
90502
90023
90745
91786
91786
91786
91786
91786
91786
91786
91786
Samp ling
Time
1000-1615
1700-0800
1000-2100
0900-1630
0930-1700
1730-0815
1329-1423
1307-1412
1357-1451
1534-1624
1322-1416
?
1400-0600
0600-0030
0030-0030
0030-0600
Calendar
Day - Year
091-75
090-1-75
092-75
094-75
093-75
093-4-75
133-76
134-76
134-76
135-76
135-76
225-7-77
227-9-77
229-31-77
231-3-77
256-8-77
258-61-77
262-4-77
264-6-77
Cone .
(ng/m3)
8,340
805
±538
51,721
+ 10,055
2,344
±0
589
±10
616
±383
T(454)
944
±166
739
±204
(continued)
-------
Table D7 (cont'd)
co
EPA
Region Compound CASS It site
IX carbon tetrachloride 56-23-5 Santa Monica, CA
West Covina, CA
Santa Monica, CA
Glendora, CA
Garden Grove, Ct.
Anaheim, CA
Anaheim, CA
El Segundo, CA
Torrance, CA
Torrance, CA
Los Angeles , CA
Dominguez , CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
IX trichloroethylene 79-01-6 West Covina, CA
Santa Monica, CA
Glendora, CA
Garden Grove, CA
Anaheim, CA
El Segundo, CA
Torrance, CA
Torrance , CA
Los Angeles, CA
Address
2441 Arizona Ave.
820 Phillips Ave.
2441 Arizona Ave.
840 E. Laurel
12281 Nelson St.
1200 W. Broadway
1200 W. Broadway
Illinois St. with
El Segundo Blvd.
19146 Van Ness Blvd.
2100 Normandie Ave.
15th S. Emery St.
2055 223 St.
820 Phillips Ave.
2441 Arizona Ave.
840 E. Laurel
12281 Nelson St.
1700 W. Broadway
Illinois St. with
El Segundo, Blvd.
19146 Van Ness Blvd.
20100 Normandie Ave.
15th S. Emery St.
Zip
Code
90404
91791
90404
91740
92640
92805
92805
90245
90504
90502
90023
90745
91786
91786
91786
91786
91786
91786
91786
91786
91791
90404
91740
92640
92805
90245
90504
90502
90023
Sampling
Time
0850-1700
1000-1615
1700-0800
1000-2100
0900-1630
0930-1700
1730-0815
1329-1423
1307-1412
1357-1451
1534-1624
1322-1416
7
1400-0600
0600-0030
0030-0030
0030-0060
1000-1615
1700-0800
1000-2100
0900-1630
1730-0815
1329-1423
1307-1412
1357-1451
1534-1624
Calendar
Day - Year
090-75
091-75
090-1-75
092-75
094-75
093-75
093-4-75
133-76
134-76
134-76
135-76
135-76
225-7-77
227-9-77
229-31-77
221-3-77
256-8-77
258-61-77
262-4-77
264-6-77
091-75
090-1-75
092-75
094-75
093-4-75
133-76
134-76
134-76
135-76
Cone.
T(153)
1,461
±0
T(154)
T(153)
T(142)
T(134)
T(153)
T(153)
(continued)
-------
Table D7 (cont'd)
CO
EPA
Region Compound CASS t Site
IX trichJoroethylene 79-01-6 Dominguez, CA
(cont.) Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
IX tetrachloroethylene 127-18-4 Santa Monica, CA
West Covina, CA
Santa Monica, CA
Glendora, CA
Garden Grove, CA
Anaheim, CA
Anahe im , C A
El Segundo, CA
Torrance, CA
Torrance, CA
Los Angeles , CA
Dominguez, CA
Upland, CA
Address
2055 223 St.
-
2441 Arizona Ave.
820 Phillips Ave.
2441 Arizona Ave.
840 E. Laurel
12281 Nelson St.
1700 W. Broadway
1700 W. Broadway
Illinois St. with
El Segundo Blvd.
19146 Van Ness Blvd.
20100 Normandie Ave.
15th S. Emery St.
2055 223 St.
-
Zip
Code
90745
91786
91786
91786
91786
91786
91786
91786
91786
90404
91791
90404
91740
92640
92805
92805
90245
90504
90502
90023
90745
91786
Sampling
Time
1322-1416
?
1400-0600
0600-0030
0030-0030
0030-0600
0850-1700
1000-1615
1700-0800
1000-2100
0900-1630
0930-1700
1730-0815
1329-1423
1307-1412
1357-1451
1534-1624
1322-1416
?
Calendar
Day - Year
135-76
225-7-77
227-9-77
229-31-77
231-3-77
256-8-77
258-61-77
262-4-77
264-6-77
090-75
091-75
090-1-75
092-75
094-75
093-75
093-4-75
133-76
134-76
134-76
135-76
135-76
225-7-77
Cone .
(ng/m3)
9,210
T(178)
3,428
± 2,143
T(178)
T(178)
T(167)
T(167)
T(179)
T(179)
20,000
1,260
Upland, CA
91786
227-9-77
±458
7,258
±155
(continued)
-------
Table D7 (cont'd)
u>
N>
co
EPA
Region Compound CASS t Site
IX cetrachloroethylene 127-18-4 Upland, CA
(cont.)
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
IX chlorobenzene 108-90-7 Santa Monica, CA
West Covina, CA
Santa Monica, CA
Glendora, CA
Garden Grove, CA
Anaheim, CA
El Segundo, CA
Torrance, CA
Torrance , CA
Los Angeles, CA
Dominguez , CA
Upland, CA
Upland, CA
Address
2441 Arizona Ave.
820 Phillips Aye.
2441 Arizona Ave.
840 E. Laurel
12281 Nelson St.
1700 W. Broadway
Illinois St. with
El Segundo Blvd.
19146 Van Ness Blvd.
20100 Normandie Ave.
15th S. Emery St.
2055 223 St.
-
Zip
Code
91786
91786
91786
91786
91786
91786
90404
91791
90404
91740
92640
92805
90245
90504
90502
90023
90745
91786
91786
Sampling
Time
1400-0600
0600-0030
0030-0030
0030-0600
0850-1700
1000-1615
1700-0800
1000-2100
0900-1630
0930-1700
1329-1423
1307-1412
1357-1451
1534-1624
1322-1416
?
Calendar
Day - Year
229-31-77
231-3-77
256-8-77
258-61-77
262-4-77
264-6-77
090-75
091-75
090-1-75
092-75
094-75
093-75
133-76
134-76
134-76
135-76
135-76
225-7-77
227-9-77
Cone .
(ng/m3)
1,207
±113
70
±23
281
±42
89
±29
98
±42
188
±56
T(156)
152
Upland, CA
91786
229-31-77
±12
T(136)
(continued)
-------
Table D7 (cont'd)
EPA
Region Compound CASS It Site
IX chlorobenzene 108-90-7 Upland, CA
(cont.) Upland, CA
Upland, CA
Upland, CA
IX m-dichlorobenzene 541-73-1 West Covtna, CA
Santa Monica, CA
Glendora, CA
Garden Grove, CA
Anahe im , CA
Anaheim, CA
El Segundo, CA
Torrance, CA
Los Angeles, CA
Dominguez , CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Address
820 Phillips Ave.
2441 Arizona Ave.
840 E. Laurel
12281 Nelson St.
1700 W. Broadway
1700 W. Broadway
Illinois St. with
El Segundo Blvd.
20100 Normandie Ave.
15th S. Emery St.
2055 223 St.
-
Zip
Code
91786
91786
91786
91786
91791
90404
91740
92640
92805
92805
90245
90502
90023
90745
91786
91786
91786
91786
91786
91786
91786
91786
Sampl ing
Time
1400-0600
0600-0030
0030-0060
1000-1615
1700-0800
1000-2100
0900-1630
0930-1700
1730-0815
1329-1423
1357-1451
1534-1624
1322-1416
7
1400-0600
0600-0030
0030-0030
0030-0060
Calendar
Day - Year
231-3-77
256-8-77
258-61-77
261-6-77
091-75
090-1-75
092-75
094-75
093-75
093-4-75
133-76
134-76
135-76
135-76
225-7-77
227-9-77
229-31-77
231-3-77
256-8-77
258-61-77
262-4-77
264-6-77
Cone.
(ng/m3)
T(136)
T(156)
T(59)
T(59)
144
±10
382
±107
87
±22
T(90)
T(104)
T(26)
T(84)
T(92)
(continued)
-------
Table D7 (cont'd)
u>
EPA
Region Compound CASS # Site
IX o-dichlorobenzene 95-50-1 Santa Monica, CA
West Covina, CA
Santa Monica, CA
Glendora, CA
Garden Grove, CA
Anaheim, CA
El Segundo, CA
Torrance, CA
Torrance, CA
Los Angeles, CA
Dominguez, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
Upland, CA
IX bromoform 75-25-2 Glendora, CA
Anaheim, CA
Address
2441 Arizona Ave.
820 Phillips Ave.
2441 Arizona Ave.
840 E. Laurel
12281 Nelson St.
1700 W. Broadway
Illinois St. with
El Segundo Blvd.
19146 Van Ness Blvd.
20100 Normandie Ave.
15th S. Emery St.
2055 223 St.
-
840 E. Laurel
1700 N. Broadway
Zip
Code
90404
91791
90404
91740
92640
92805
90245
90504
90502
90023
90745
91786
91786
91786
91786
91786
91786
91786
91786
91740
92805
Sampling
Time
0850-1700
1000-1615
1700-0800
1000-2100
0900-1630
0930-1700
1329-1423
1307-1412
1357-1451
1534-1624
1322-1416
9
1400-0600
0600-0300
0030-0030
0030-0600
1000-2100
1730-0815
Calendar
Day - Year
090-75
091-75
090-1-75
092-75
094-75
093-75
133-76
134-76
134-76
135-76
135-76
225-7-77
227-9-77
229-31-77
231-3-77
256-8-77
258-61-77
262-4-77
264-6-77
091-75
093-4-75
Cone.
(ng/m^)
T(104)
20
±9
T(90)
T(90)
T(104)
T(26)
T(84)
T<92)
(continued)
-------
Table D7 (cont'd)
EPA
Region
Compound
CASS #
Site
Address
Zip
Code
Samp ling
Time
Calendar
Day - Year
Cone.
(ng/m3)
trichlorobenzene
[isomer(s)]
West Covina, CA
Garden Grove, CA
Anaheim, CA
Torrance, CA
Los Angeles, CA
Dominguez, CA
Upland, CA
820 Phillips Ave.
12281 Nelson St.
1700 W. Broadway
20100 Normandie Ave.
15th S. Emery St.
2055 223 St.
91797
92640
92805
90502
90023
90745
91786
1000-1615
0900-1630
0930-1700
1357-1451
1534-1624
1322-1416
091-75
094-75
093-75
134-76
135-76
135-76
227-9-77
1(43)
00
S3
o\
-------
TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1. REPORT N
EPORT NO.
EPA-600/2-79-081
2.
3. RECIPIENT'S ACCESSION-NO.
4. TITLE AND SUBTITLE
AMBIENT AIR CARCINOGENIC VAPORS
Improved Sampling and Analytical Techniques
and Field Studies
5. REPORT DATE
May 1979
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
Edo D. Pellizzari
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Research Triangle Institute
PO Box 12194
Research Triangle Park, NC 27709
10. PROGRAM ELEMENT NO.
1AD712 DB-13 (FY-79)
11. CONTRACT/GRANT NO.
68-02- 2764
12. SPONSORING AGENCY NAME AND ADDRESS
Environmental Sciences Research Laboratory—RTF, NC
Office of Research and Development
US Environmental Protection Agency
Research Triangle Park, NC 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/600/09
15. SUPPLEMENTARY NOTES
16. ABSTRACT
Improved techniques for sampling and analyzing volatile organic compounds
in the ambient air were developed and evaluated. Emphasis was placed on techniques
for halocarbons and other compounds known or suspected of being carcinogenic.
Areas of investigation included (a) the evaluation of XAD-2, charcoal and Tenax
GC sorbents for in situ formation of halogenated organics during the sampling
of air containing chlorine and olefins; (b) the development and testing of a cryo-
heater module for a thermal desorptions inlet-manifold; and (c) the characterization
and quantification of hazardous organic vapors in ambient air collected at several
different geographical areas within the continental United States.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.lDENTIFIERS/OPEN ENDED TERMS
c. COS AT I Field/Group
*Air pollution
*Halohydrocarbons
*Vapors
*Carcinogens
*Chemical analysis
Gas chromatography
Mass spectrometry
*Field tests
13B
07C
07D
06E
14B
14A
13. DISTRIBUTION STATEMENT
RELEASE TO PUBLIC
19. SECURITY CLASS (ThisReport)
UNCLASSIFIED
21. NO. OF PAGES
340
20. SECURITY CLASS (Thispage)
UNCLASSIFIED
22. PRICE
EPA Form 2220-1 (9-73)
327
------- |