PROCESS DESIGN MANUAL
                FOR
         UPGRADING EXISTING
    WASTEWATER TREATMENT PLANTS
U. S. ENVIRONMENTAL PROTECTION AGENCY
           Technology Transfer
             October 1974

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                              ACKNOWLEDGMENTS
The original edition of this Design Manual was published in October 1971. This first revision
to the original text was prepared by Metcalf & Eddy, Inc.; the original manual was prepared
by Roy F. Weston, Inc. Major EPA contributors and reviewers were Richard C. Brenner and
John M. Smith of the U. S. EPA National Environmental Research Center, Cincinnati, Ohio,
and Denis Lussier of the Office of Technology Transfer. Revisions to the text were under
the direction of Donald E. Schwinn and Richard B. Gassett of Metcalf & Eddy, Inc.
                          rp ,TT
                                     NOTICE

The  mention of trade names or commercial products in this publication is for illustration
purposes and does  not  constitute endorsement  of  recommendation  for  use  by the
U. S. Environmental Protection Agency.

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                                     ABSTRACT
The  main purposes of this manual are to examine situations that necessitate upgrading of
existing municipal wastewater treatment plants  and to discuss and evaluate the corrective
actions that are required to upgrade these existing plants. Upgrading to overcome organic
and  hydraulic  overloadings and/or  to meet more stringent  treatment  requirements is
considered.

The  manual emphasizes that operational improvement and modifications to existing unit
operations be considered as the logical initial approach to  upgrading existing treatment
plants, before major expansion of existing facilities is implemented.

Because of the numerous alternatives available for upgrading  an existing treatment plant, it
is  necessary to  understand thoroughly the  fundamentals  of the various unit operations
commonly used in municipal wastewater treatment plants. Therefore, this manual examines
in depth the capabilities, limitations, and  interrelationships  of the various unit processes.
The  manual also examines hypothetical situations  requiring  upgrading of unit operations
and  describes "order of magnitude" costs associated with the upgrading of various unit
operations.

One chapter of the manual presents  case histories  of upgrading of existing  wastewater
*"*•  nent plants to illustrate the approaches actually used in these circumstances.
                                         111

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                                 CONTENTS


Chapter                                                                Page

        ACKNOWLEDGMENTS                                          ii

        ABSTRACT                                                    "»

        CONTENTS                                                    v

        LIST OF FIGURES                                             ix

        LIST OF TABLES                                               xiii

        FOREWORD                                                   xvii

  1     INTRODUCTION                                               1-1

  2     INVESTIGATIVE APPROACH

        2.1 Purpose of Upgrading Existing Wastewater Treatment Plants        2-1
        2.2 Identification of Existing Problem Areas                        2-1
        2.3 Upgrading to Meet More Stringent Treatment Requirements        2-2
        2.4 Upgrading to Relieve Hydraulic and Organic Overloads             2-2
        2.5 Upgrading to Improve Plant Design and Operation                2-8
        2.6 Consideration of Applicable Upgrading Techniques                2-10
        2.7 References                                                 2-11
                            v-
  3     FLOW EQUALIZA,

        3.1 Introduction and Concept                                    3-1
        3.2 Benefits of Dry Weather Flow Equalization                      3-4
        3.3 Determination of Equalization Requirements                     3-6
        3.4 Costs                                                     3-15
        3.5 Performance and Case Histories                                3-16
        3.6 References                                                 3-21

  4     TECHNIQUES FOR UPGRADING TRICKLING FILTER PLANTS

        4.1 General                                                    4-1
        4.2 Trickling Filter Processes                                     4-1

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                            CONTENTS - Continued
Chapter                                                                 Page

         4.3  Trickling Filter Design Considerations                           4-3
         4.4  Trickling Filter Upgrading Considerations                        4-12
         4.5  Trickling Filter Upgrading Techniques and Design Basis            4-17
         4.6  References                                                  4-48

  5      TECHNIQUES FOR UPGRADING ACTIVATED SLUDGE PLANTS

         5.1  General                                                    5-1
         5.2  Activated Sludge Processes                                    5-1
         5.3  Activated Sludge Design Considerations                         5-19
         5.4  Pilot Studies                                                5-28
         5.5  Activated Sludge Upgrading Techniques and Design Bases          5-36
         5.6  References                                                  5-55

  6      CLARIFICATION AND CHEMICAL TREATMENT

         6.1  Advantages of Upgrading Clarifiers                             6-1
         6.2  Process Design of Clarifiers                                    6-2
         6.3  Physical Upgrading of Clarifiers                                6-5
         6.4  Chemical Treatment                                          6-14
         6.5  References                                                  6-22

  7      EFFLUENT POLISHING TECHNIQUES

         7.1  General                                                    7-1
         7.2  Polishing Lagoons                                            7-1
         7.3  Microscreening                                              7-7
         7.4  Filtration                                                   7-12
         7.5  Activated Carbon Adsorption                                  7-23
         7.6  References                                                  7-36

  8      PREAERATION AND POSTAERATION PRACTICES

         8.1  Preaeration                                                 8-1
         8.2  Postaeration                                                8-4
         8.3  References                                                  8-13
                                       VI

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                            CONTENTS - Continued


Chapter                                                                 Page

   9     DISINFECTION AND ODOR CONTROL

         9.1    General                                                  9-1
         9.2    Disinfection                                               9-1
         9.3    Odor Control                                             9-10
         9.4    Other Uses of Chlorine                                     9-15
         9.5    References                                                9-16

  10     SLUDGE THICKENING

         10.1   Sludge Treatment                                          10-1
         10.2   General Sludge Thickening Considerations                     10-6
         10.3   Gravity Thickening                                         10-7
         10.4   Air Flotation                                             10-12
         10.5   Centrifugation                                             10-19
         10.6   References                                                10-25

  11     SLUDGE STABILIZATION

         11.1   General                                                  11-1
         11.2   Anaerobic Digestion                                       11-1
         11.3   Aerobic Digestion                                          11-17
         11.4   Heat Treatment of Sludge                                   11-23
         11.5   Lime Stabilization of Sludge                                 11-27
         11.6   References                                                11-28

  12     SLUDGE DEWATERING

         12.1   General                                                  12-1
         12.2   Vacuum Filtration                                         12-1
         12.3   Drying Beds                                               12-13
         12.4   Centrifugation                                             12-17
         12.5   Filter Presses                                              12-24
         12.6   References                                                12-25
                                      vn

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                          CONTENTS - Continued


Chapter                                                                Page

  13     CASE HISTORIES OF TREATMENT PLANT UPGRADING

         13.1   Case History No. 1 — Use of Roughing Filter to Upgrade
                  an Existing Low-Rate Trickling Filter Plant                13-1
         13.2   Case History No. 2 — Upgrading an Existing High-Rate
                  Trickling Filter by Conversion to a Super-Rate
                  Filter System                                          13-1
         13.3   Case History No. 3 — Upgrading Using Polyelectrolyte
                  Addition Before the Primary Clarifier                     13-5
         13.4   Case History No. 4 — Upgrading a Trickling Filter
                  Plant by Adding Activated Sludge Treatment and
                  Pre-and Post-Chlorination                               13-9
         13.5   Case History No. 5 — Upgrading a Primary Treatment
                  Plant to Provide Tertiary Treatment                      13-11
         13.6   Case History No. 6 — Upgrading a Trickling Filter Plant
                  in Stages to an Activated Sludge Plant with Roughing
                  Filters                                                13-19
         13.7   Case History No. 7 — Upgrading by Optimization of               a"-
                  Aeration Tank-Clarifier Relationship                      13-25
         13.8   Case History No. 8 — Upgrading by Optimization of
                  Aeration Tank-Clarifier Relationship                      13-28
         13.9   Case History No. 9 — Upgrading a Modified Aeration
                  System for Nutrient Removal                            13-30
         13.10 References                                              13-36
 APPENDIX A  -METRIC CON VERSION CHART                         A-l

 APPENDIX B  -  WORD ABBREVIATIONS                               B-l
                                      vm

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                                 LIST OF FIGURES
Figure No.                                                                   Page

  3-1         Schematic Flow Diagrams of Equalization Facilities                3-3
  3-2         Raw Wastewater Flow and BOD Variation before Equalization      3-8
  3-3         Hydrograph for Typical Diurnal Flow                            3-9
  3-4         Raw Wastewater Flow and BOD Variation after Equalization       3-12
  3-5         Earthen Equalization Basin                                      3-14
  3-6         Effect of Tannery Flow Equalization                             3-18
  3-7         Walled Lake-Novi Wastewater Treatment: Plant                    3-20
  4-1         Comparison of Trickling Filter Operating Data with NRC
                Equation                                                    4-7
  4-2         Common Flow Diagrams for Single and Two-Stage High-Rate
                Trickling Filters                                             4-14
  4-3         Upgrading a Single-Stage Low-Rate TricMing Filter by
                Improving Distribution                                       4-19
  4-4         Modifying a Single-Stage Trickling Filter to a Two-Stage
                Filtration System                                            4-22
  4-5         Upgrading a Single Stage Trickling Filteir to a Two-Stage
                Biological Filtration/Activated  Sludge System                   4-24
  4-6         Upgrading a Trickling Filter System to rtovide Year Round
                Nitrification                                                 4-31
  4-7         Upgrading a Single-Stage Trickling Filter to a Two-Stage
                Filtration System to Provide Nitrification                      4-32
  4-8         Upgrading a Single-Stage Trickling Filter to a Two-Stage
                Biological System to Provide Nitrification                      4-35
  4-9         Upgrading a Standard Rate Trickling Filter System with
                Chemical Addition to Provide Phosplhorus Removal             4-39
  4-10        Upgrading a Trickling Filter System Using Chemical
                Addition for Phosphorus Removal                             4-44
  4-11        Upgrading a Trickling Filter System to Provide Phosphorus
                Removal                                                    4-46
  5-1         Conventional Activated Sludge Plant                             5-4
  5-2         Step Aeration Plant                                             5-6
  5-3         Comparison of Solids Loading on  the Final Clarifier for
                Conventional and Step Aeration Plants                         5-7
  5-4         Contact Stabilization Plant                                      5-8
  5-5         Complete Mix Plant                                             5-12
  5-6         Two-Stage Activated Sludge Plant                                5-16
                                         IX

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                           LIST OF FIGURES - Continued
Figure No.                                                                   Page

  5-7         Schematic Diagram of Multi-Stage Oxygenation System             5-18
  5-8         Oxygen Consumption for Pure Oxygen Systems Related to
                Organic Loading; (F/M)                                       5-21
  5-9         BOD Removal Characteristics for Various Complete Mix
                Activated Sludge Plants                                       5-23
  5-10        Relationship Between BOD Removal Rate Constants and
              Loading Ratios for the Activated Sludge Modifications             5-25
  5-11        Bench-Scale Aeration Unit                                       5-30
  5-12        Schematic of a Continuous-Flow Pilot Unit                        5-31
  5-13        Determination of Oxygen Uptake Requirements                   5-34
  5-14        Determination of Sludge Production Characteristics                5-35
  5-15        Upgrading a Conventional Activated Sludge Plant to Step
                Aeration                                                     5-38
  5-16        Upgrading a Conventional Activated Sludge Plant to
                Contact Stabilization                                         5-41
  5-17        Upgrading a Contact Stabilization Plant to Complete-Mix
                Activated Sludge:                                             5-44
  5-18        Upgrading a Modified Aeration Activated Sludge System to
                Oxygen-Activated Sludge                                     5-49
  5-19        Upgrading a Primary Treatment Plant to Pure Oxygen
                Activated Sludge Treatment                                   5-50
  6-1         Typical Clarifier Configurations                                  6-6
  6-2         Clarifier Modifications at the Greater Peoria Sanitary District
                Sewage Plant                                                 6-9
  7-1         Typical Cross Section of a Facultative Lagoon                     7-5
  7-2         Typical Microscreen Unit                                       7-8
  7-3         Typical Pilot Plant Data for Filter Design                         7-18
  7-4         Effect of  Reactivation on Adsorption Capacity                    7-27
  7-5         COD Isotherms Using Virgin Carbon and Different Secondary
                Wastewater Effluents                                         7-31
  7-6         Total Capital Costs i'or Carbon Treatment                        7-33
  7-7         Carbon Adsorption Operation and Maintenance Costs              7-34
  7-8         Total Annual and Unit Costs for Carbon Treatment                7-35
  8-1         Primary Treatment Units at the Central Contra Costa Sanitary
                District Water Reclamation Plant                              8-3

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                           LIST OF FIGURES - Continued
Figure No.                                                                  Page

  8-2         Various Postaeration Devices                                    8-6
  8-3         Cascade Aerator at Pittsfield, Mass.                              8-11
  9-1         Relationship Between Concentration and Time for 99 Percent
                Destruction of Escherichia Coli by Different Forms of
                Chlorine at 2 to 6°C                                         9-3
  9-2         MPN Coliform Vs. Chlorine Residual                             9-4
  9-3         Impact of Chlorine Tank Baffle Design on Actual Detention
                Time                                                       9-7
 10-1         Sludge Treatment Processes                                     10-2
 10-2         Typical Sludge Processing Systems Using Biological Stabilization    10-4
 10-3         Typical Sludge Processing Systems Using Nonbiological
                Stabilization                                                10-5
 10-4         Upgrading Sludge Handling Facilities Using Gravity Thickening     10-13
 10-5         Schematic of an Air Flotation Unit                              10-15
 10-6         Upgrading Sludge Handling Facilities Using Air Flotation
                Thickening                                                  10-18
 10-7         Upgrading Sludge Handling Using Centrifugal Thickening           10-24
 11-1         Relationship Between pH and Bicarbonate Concentration           11-4
 11-2         Anaerobic Digestion Systems                                    11-7
 11-3         Relationships Between Sludge Solids Digester Loadings, and
                Detention Time                                             11-11
 11-4         Upgrading an Existing Low-Rate Digestion System Using
                Pre-Thickening of the Combined Sludge and Improvements
                to the Primary Digester                                       11-16
 11-5         Conversion of Anaerobic to Aerobic Digestion                     11-24
 12-1         Typical Vacuum Filter Flow Diagram                            12-2
 12-2         Types of Centrifuges                                           12-18
 13-1         Case History No. 1 Comparison of Original and Upgraded Flow
                Diagrams                                                   13-2
 13-2         Hydrasieve Screening Unit                                      13-4
 13-3         Case History No. 2 Comparison of Original and Upgraded Flow
                Diagrams                                                   13-6
 13-4         Case History No. 4 Comparison of Original and Upgraded Flow
                Diagrams                                                   13-10
 13-5         Case History No. 5 Comparison of Original and Upgraded Flow
                Diagrams                                                   13-14

                                        xi

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                       LIST OF FIGURES - Continued
Figure No.                                                              Page

  13-6       Case History No. 6 Comparison of Original and Upgraded Flow
               Diagrams                                                13-20
  13-7       Case History No. 7 Comparison of Original and Modified Flow
               Diagrams                                                13-27
  13-8       Case History No. 8 Flow Diagram                             13-29
  13-9       Upgrading a Modified Aeration System for Nutrient Removal
               Flow Diagram Primary and Secondary Systems               13-33
  13-10      Upgrading a Modified Aeration System for Nutrient Removal
               Flow Diagram Nitrification and Denitrification Systems        13-34
  13-11      Upgrading a Modified Aeration System for Nutrient Removal
               Flow Diagram Filtration and Disinfection Systems             13-35
                                      XII

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                                 LIST OF TABLES
Table No.                                                                   Page

  2-1         Characteristics of Septage                                       2-7
  3-1         Effect of Flow Equalization on Primary Settling  .
                Newark, New York                                          3-5
  3-2         Cost of Equalization Facilities                                   3-16
  4-1         Operating Data for Single-Stage Trickling Filter Plants at Low,
                Intermediate,  and High Loading Rates                          4-4
  4-2         Trickling Filter Volumes for Various Organic Removals as
                Calculated by Different Design Equations                      4-10
  4-3         Comparative Physical Properties of Trickling Filter Media           4-15
  4-4         Operating Data for Pueblo, Colorado                             4-20
  4-5         Operating Data for Chapel Hill, North Carolina                    4-23
  4-6         Operating Data for Kankakee, Illinois                            4-25
  4-7         Upgrading Techniques for Improvement of Trickling Filter Plant
                Efficiency                                                  4-27
  4-8         Trickling Filter Nitrification Data                                4-29
  4-9         Operating and Design Conditions for Allentown, Pennsylvania      4-34
  4-10        Operational and  Design Data for an Industry in New York State     4-37
  4-11        Summary of Treatment Processes for Nutrient Removal            4-38
  4-12        Operating Data for Richardson, Texas                            4-40
  4-13        Operating Data for Chapel Hill, North Carolina                    4-45
  4-14        Operating Data for Marlborough, Massachusetts                   4-47
  5-1         Operating Data from Conventional Activated Sludge Plants          5-3
  5-2         Operating Data from Step Aeration Activated Sludge Plants         5-5
  5-3         Operating Data from Contact Stabilization Activated Sludge Plants  5-9
  5-4         Suggested Design Guidelines                                     5-10
  5-5         Operating Data from Complete Mix Activated Sludge Plants         5-13
  5-6         Operating Data from Modified Aeration Activated Sludge Plants     5-14
  5-7         Operating Data from Two-Stage Activated Sludge Plants            5-17
  5-8         Operating Data from Pure Oxygen Activated Sludge Plants          5-20
  5-9         Oxygen and Air Requirements for Activated Sludge Modifications   5-26
  5-10        Oxygen Transfer Capabilities of  Various Aeration Systems          5-27
  5-11        Operating and Performance Data for  the Wards Island Plant,
                New York City                                              5-39
                                       xui

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                            LIST OF TABLES - Continued
Table No.                                                                    Page

  5-12        Operating and Performance Data for Austin, Texas                 5-42
  5-13        Operating and Performance Data for Coralville, Iowa                5.45
  5-14        Operating and Performance Data for Newtown Creek Plant,
                Brooklyn, New York                                          5-47
  5-15        Operating and Performance Data for Fairfax County, Virginia       5-31
  5-16        Upgrading Techniques for Improvement of Activated Sludge
                Treatment Plant Efficiency                                    5-53
  5-17        Design Guidelines for Nitrification                                5-54
  6-1         Typical Design Parameters for Primary Clarifiers                    6-3
  6-2         Typical Design Parameters for Secondary Clarifiers                 6-4
  6-3         Tube Settler Installations                                        6-15
  6-4         Effect of Chemical Treatment on Primary Clarifier Performance      6-17
  6-5         Polyelectrolyte Addition to Primary Clarifiers                      6-19
  6-6         Lime Addition to Primary Clarifiers                               6-19
  6-7         Effect of Chemical Treatment on Secondary Clarifier Performance   6-21
  7-1         Operational Data from Shallow Aerobic Polishing Lagoons          7-2
  7-2         Removal Efficiencies for Deep Aerated Effluent Polishing Lagoons   7-3
  7-3         Mechanical Mixing Energy Required for Oxygen Dispersion         7-4
  7-4         Comparison of Operational Data from Facultative and
                Aerated Polishing Lagoons                                     7-6
  7-5         Microscreen Fabric Sizes                                         7-7
  7-6         Typical Microscreen Power and Space Requirements                7-9
  7-7         Typical Microscreen Design Parameters                            7-11
  7-8         Microscreen Performance Data                                    7-13
  7-9         Typical Multimedia Gradations                                   7-14
  7-10        Factors Governing Filter Performance                             7-15
  7-11        Expected Filter Performance for Activated Sludge Plants            7-19
  7-12        Expected Filter Performance for Trickling Filter Plants             7-19
  7-13        In-Depth Filtration of Activated Sludge and Trickling Filter
                Plant Effluents                                               7-20
  7-14        Surface Filtration of Activated  Sludge and Trickling Filter
                Plant Effluents                                               7-21
  7-15        Filtration of Chemically Treated Secondary Effluent                7-22
  7-16        Typical Carbon Column Design Data                              7-25
  7-17        Performance of Upflow Bed and Downflow Bed Adsorbers          7-28
  7-18        Performance of Tertiary Carbon Wastewater Treatment Plants       7-29
                                         xiv

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                           LIST OF TABLES - Continued
Table No.                                                                   Page

   8-1        Performance of Primary Facilities at Central Contra Costa
                Sanitary District with Chemical Treatment to Preaeration          8-5
   9-1        Chlorine Dosage Ranges                                          9-5
   9-2        Relative Total Annual Costs of Disinfection Alternatives             9-10
   9-3        Effect of Chlorine on Odor Reduction for a Raw Domestic
                Wastewater                                                   9-13
   9-4        Effect of Powdered Activated Carbon on Odor Reduction            9-14
   9-5        Capital Costs for Odor Control Systems                            9-15
  10-1        Thickener Design Loadings and Underflow Concentrations          10-9
  10-2        Example of Upgrading Sludge Handling Facilities Using
                Gravity Thickening                                           10-12
  10-3        Typical Air Flotation Design Parameters                           10-14
  10-4        Air Flotation Thickening Performance Data                       10-16
  10-5        Example of Upgrading Sludge Handling Facilities Using Air
                Flotation Thickening                                         10-17
  10-6        Centrifugal Thickening Performance Data                         10-21
  10-7        Example of Upgrading Sludge Handling Facilities Using
                Centrifugal Thickening                                       10-22
  11-1        Concentrations Which Will Cause a Toxic Situation in
                Anaerobic Digestion of Municipal Sludges                       11-6
  11-2        Typical Design Criteria for Low-Rate and High-Rate Anaerobic
                Digesters                                                    11-8
  11-3        Typical Properties of Anaerobic Digester Supernatant               11-13
  11-4        Upgrading an Existing Low-Rate Digestion System Using
                Prethickening of the Combined Sludge and Improvements
                to the Primary Digester                                       11-15
  11-5        Typical Properties of Aerobic Digester Supernatant                 11-17
  11-6        Batch-Type Aerobic  Sludge Digestion Operating Data for
                Mixtures  of Primary and Waste Activated Sludge                 11-19
  11-7        Results of High-Purity Oxygen Aerobic Digestion Speedway,
                Indiana                                                      11-20
  11-8        Aerobic Digestion Design Parameters Using Air                     11-22
  11-9        Aerobic Digester Upgrading Design Parameters                     11-25
  11-10       Characteristics of Heat Treated Sludge Filtrate at Batavia            11-26
  11-11       Bactericidal Effect of Lime Addition to Chemically
                Precipitated Sludges                                          11-27
                                        xv

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                           LIST OF TABLES - Continued
Table No.                                                                  Page

  12-1       Typical Specific Resistance Values for Various Sludges             12-6
  12-2       Vacuum Filtration Performance Using Inorganic Chemicals
                and Purifloc C-31 on Municipal Sludge                         12-8
  12-3       Summary Data on Vacuum Filtration of Pure Oxygen
                Aeration Sludges                                            12-9
  12-4       A Comparison Between Lime/Ferric Chloride and Poly electrolytes
                for Conditioning Raw Primary Sludge                          12-12
  12-5       Sludge-Drying Bed Area Requirements                           12-15
  12-6       Summary of Centrifuge Characteristics                           12-17
  12-7       Solid Bowl Centrifuge Performance Data                         12-22
  13-1       Case History No. 1 — Plant Operating and Performance Data        13-3
  13-2       Case History No. 2 — Plant Operating, Performance and
                Design Data                                                13-7
  13-3       Case History No. 3 — Plant Operating and Performance Data        13-8
  13-4       Case History No. 4 — Plant Operating and Design Conditions        13-12
  13-5       Summary of Treatment Performance for Cast History No. 4        13-13
  13-6       Case History No. 5 — Plant Operating and Design Conditions        13-15
  13-7       Summary of Treatment Performance for Case History No. 5        13-18
  13-8       Estimated Costs for Construction for Case History No. 5           13-18
  13-9       Case History No. 6 - Plant Design Conditions                    13-22
  13-10      Summary of Treatment Performance for Cast History No. 6        13-24
  13-11      Capital Costs of Upgrading for Case History No. 6                 13-25
  13-12      Case History No. 7 - Operating Data                            13-26
  13-13      Case History No. 7 - Performance Data                          13-28
  13-14      Case History No. 8 — Operating and Performance Data             13-30
  13-15      Case History No. 9 — Anticipated Performance After Upgrading     13-32
                                       xvi

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                                    FOREWORD
The formation of the United States Environmental Protection Agency marked a new era of
environmental  awareness in  America. This Agency's goals  are  national  in scope and
encompass broad responsibility  in  the area of  air and  water pollution,  solid wastes,
pesticides, and radiation. A vital part of EPA's national water pollution control effort is the
constant development and dissemination of new technology for wastewater treatment.

It is now clear that only the most effective design and operation of wastewater treatment
facilities,  using the latest available techniques, will be adequate to meet the future water
quality objectives and to ensure continued protection of the nation's waters. It is essential
that this new technology be incorporated into the contemporary design of waste treatment
facilities to achieve maximum benefit of our pollution control expenditures.

The purpose of this manual is to provide the engineering community and related industry a
new source of information to be used in the planning, design and operation of present and
future wastewater treatment facilities. It is recognized that there are  a  number of design
manuals, manuals of standard practice, and design guidelines currently available in the field
that adequately describe and interpret  current engineering practices as related to traditional
plant design. It is the intent of this manual to supplement  this existing body of knowledge
by describing new treatment  methods,  and by discussing the application of new techniques
for more effectively removing a broad spectrum of contaminants from wastewater.

Much  of  the  information  presented is based on the evaluation and  operation of pilot,
demonstration  and full-scale plants. The design criteria thus generated represent typical
values. These  values  should  be used as a  guide and  should  be  tempered  with sound
engineering judgment based on a complete analysis of the specific application.

This manual is one of several available through the Technology Transfer  Office of EPA to
describe  recent technological  advances and  new information.  This  particular  manual was
initially issued in October of 1971 and this edition represents  the first revision to the basic
text. Future editions will be issued as warranted by advancing state-of-the-art to include new
data as it becomes available, and to revise design criteria  as additional full-scale operational
information is  generated.
                                        xvu

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                                    CHAPTER 1

                                  INTRODUCTION
The ability of wastewater treatment plants to perform  at required levels of efficiency
becomes more critical as water  pollution abatement programs achieve their  objectives.
Deviations  from  design performance,  which were  formerly  of lesser consequence, now
become paramount because  of their impact on the receiving waters.  Improved  process
monitoring  and  plant  operation will obviously  reduce the incidence  of  inadequate
performance, but  many  cases are the result of more basic deficiencies in the treatment
system. Upgrading of wastewater  treatment plants  may be required to handle higher
hydraulic  and organic loadings to  meet existing effluent quality and/or to meet higher
treatment requirements. Any of these situations requires optimization of existing facilities
before consideration of additional treatment facilities. It is necessary that a distinction be
made between upgrading to accommodate higher hydraulic  and organic loads, and upgrading
to meet stricter treatment requirements. Existing facilities can be made to handle higher
hydraulic  and organic loads by process modifications, whereas meeting higher treatment
requirements usually requires significant expansion and/or modification of existing facilities.

Regardless  of the cause, the result is that an inadequately treated effluent is discharged. The
historical solution to such a problem has been plant expansion along the same lines as the
original facility, or addition  of conventional unit processes to add secondary  or tertiary
treatment to the system.  Depending  on its application, a generalized approach such as this
does  not necessarily  make optimum use of the previously existing facilities nor of the
expanded  facilities. The situation is further complicated where regional  treatment systems
are proposed for the future and existing facilities are inadequate for the interim period. In
such  cases,  a  solution must make  optimum use of available technology, with minimum
capital expenditure.

Rapid urbanization, development of industries,  and stricter treatment requirements often
necessitate  unanticipated upgrading  of treatment plants or premature implementation of
upgrading programs. Many existing treatment plants are not capable of meeting the more
stringent performance levels required by today's water quality standards. In addition, there
are needs  for interim improvements.  These considerations,  plus  economic pressures to
optimize pollution  abatement  expenditures,  make  it mandatory that  a  logical  and
technically sound approach to upgrading existing treatment facilities be established. This is
especially true because of the numerous alternatives available for consideration prior to the
selection of a  method for upgrading an existing facility. It is for this reason that a major
plant  expansion,  i.e., complete duplication of existing unit treatment  processes, for the
purposes of this manual will be considered the least attractive upgrading procedure available,
since this approach does not consider optimization of existing facilities.
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Therefore,  the purpose  of this  manual  will be  to present necessary information for
considering various courses of action with regard to an impending or existing plant overload
situation, or with regard to increasing the efficiency to meet stricter treatment standards.
The diversity of causes that necessitate upgrading of existing plants precludes the use of this
manual as a conventional design manual. Therefore, it is aimed at establishing a framework
of possible alternative methods  of upgrading overloaded treatment  plants. To facilitate the
information presented, only plants treating  "typical"  domestic wastewaters will  be
considered.

Particular upgrading procedures are stressed as interim methods which may be implemented
with  a minimum amount  of effort and  capital  expenditure prior to  a more elaborate
upgrading or  even  a major  plant expansion. Cost  information has  been compiled and
estimates prepared for the upgrading of individual unit processes. Capital costs are based on
an EPA cost index of 175, and unless noted otherwise do not include an allowance for land,
right-of-ways, engineering and legal fees, contingencies or interest during construction. When
available, cost information has  also been included for the reported case histories on plant
upgrading.  Due to the varying  complexity of existing  plants, the  real benefit of the
subsequent cost information will be as a tool for developing comparative capital costs for
various upgrading techniques.  Particular unit process cost information must be used
cautiously, since the complexity  of the individual situation  will dictate the costs required
for upgrading.

The aspects of nutrient removal, although extremely important  and oftentimes responsible
for upgrading  action at many treatment plants, will  be discussed only briefly herein since
more  detailed information is presented in other manuals either currently available or soon to
be published.
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                                    CHAPTER 2

                           INVESTIGATIVE APPROACH


2.1  Purpose of Upgrading Existing Wastewater Treatment Plants

Upgrading of existing wastewater treatment plants may be required for a number of reasons,
including the following:

     1.   To meet more stringent treatment requirements

     2.   To increase hydraulic and/or organic loading capacity

     3.   To improve poor performance due to improper plant design and/or operation.

The approach to the solution of an upgrading problem  will vary depending upon  the
objectives to be attained. In some cases, upgrading only a portion of the plant may achieve
significant  improvements  in  plant performance.  This  chapter  describes the general
investigative techniques applicable to most upgrading situations.

2.2  Identification of Existing Problem Areas

As  the  initial step  in  solving an  upgrading  problem, the engineer should thoroughly
familiarize himself with the following aspects of the existing facility:

     1.   Efficiency of treatment

     2.   Normal operational and maintenance procedures

     3.   Condition of structures

     4.   Condition of process hardware

     5.   Staffing pattern and level of operator skill.

Thorough discussions with plant operating personnel are of great benefit in determining the
above. These discussions must be supplemented by a complete review of  plant operating
records such as daily flow charts, operating logs and laboratory data. Normally, much of this
information is compiled on standard State regulatory agency forms which are submitted
monthly.
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The  engineer should become  completely familiar with  the  type of sampling  and flow
measurement techniques employed by  the plant personnel and verify their accuracy. One
difficult  area in  assessing plant performance data  is  the  reliability  of influent flow
measurement data. Often,  plant flow data are obtained from  some type of flow recording
instrument,  and  reliable  flow information  is  possible  only when the treatment  plant
operator routinely calibrates the flow measuring and recording  instruments. A representative
portion of the operating data, normally a period of one to three years, should be evaluated
by the engineer.  If adequate operational and performance data are not available, it is the
responsibility of the engineer to collect the additional information needed to complete the
evaluation.

2.3  Upgrading to Meet More Stringent Treatment Requirements

Increased  pressure from Federal  and State governments, and a more ecologically minded
public are requiring local communities and  sanitary districts  to enforce existing water
quality  standards. In addition,  many regulatory agencies are stipulating (1) increased BOD
and SS removal, (2) the maintenance of minimum DO concentrations in the plant effluent
or receiving body of water, (3) more stringent disinfection requirements, (4) phosphorus
removal, (5) partial or complete oxidation of ammonia nitrogen, and, in some cases, (6) high
levels of nitrogen removal.

An essential feature of  any upgrading plan is the provision of adequate flexibility in plant
design to  accommodate  future  treatment requirements.  These requirements  will  vary
depending on the  location of the treatment  plant, the  expected useful  lifetime of the
existing facility  and the  condition and projected  use of the receiving  body  of water.
Regardless of  the ultimate  treatment  goal, adequate consideration  must  be  given to
maximum utilization of the existing plant in the overall upgrading plan. In some instances,
moderate  improvements in plant efficiency  may  be sufficient, while in other situations,
extensive  improvements may be  required to  meet very  stringent effluent requirements.
Often, upgrading to meet long-term water quality goals involves expansion of major portions
of the plant to accommodate increased flows.

Since this type of upgrading involves a major capital investment, a detailed evaluation of all
feasible alternatives is  justified.  This  evaluation should  include a careful  analysis of the
increased  operating cost and staffing pattern required by the upgraded facility along with
the  municipality's ability to provide the needed financial  support. Often, major  plant
expansion and added tertiary facilities will substantially increase the cost of sludge handling
and disposal, which represents a significant portion of the total plant operating cost.

2.4  Upgrading to Relieve Hydraulic and Organic Overloads

The performance of different unit processes within a treatment plant is affected to varying
degrees by hydraulic and organic overloads. The relationship  between higher flows and the

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 corresponding  changes in BOD  and SS  loading  is also an important consideration. For
 example, a significant increase in flow without a corresponding increase in organics will
 require a different upgrading approach than when the increase in flow is accompanied by an
 increase in BOD and SS.

 Hydraulic and organic overloading normally occurs as  the tributary  population increases
 beyond  the plant design capacity. Projections must then be made for a  reasonable design
 period  into  the  future.  Forecasting  changes in  population and  wastewater  flows  in
 connection with upgrading of an existing treatment plant may be quite burdensome but
 generally will not be subject to as much uncertainty as in similar forecasting for a relatively
 undeveloped area. In many cases, the maximum anticipated growth is defined by saturation
 of the tributary area. Potential extension of this area must also be considered and is often
 limited by topographical constraints and political  boundaries. Analysis of local area growth
 patterns; examination  of  local influences  such as  land use planning studies, zoning
 regulations and wastewater discharge ordinances; and full use  of State,  County and local
 planning agencies can all be extremely useful in  judging the future expected flows for a
 given upgrading situation.

 Rapid industrialization in an existing plant's service area can cause increased hydraulic and
 organic  loads.  The  alert  community,  before issuing a building permit, should notify
 industries that  pretreatment may be required for wastewaters containing toxic or treatment
 inhibiting materials, or for wastewaters having an unusually high percentage of organic  or
 inorganic material compared to typical domestic wastewaters. Equalization of industrial
 wastewater discharges may be helpful in minimizing diurnal flow variations and in damping
 short-term, high-strength discharges.

 Population equivalent equates the organic content or flow contribution of industries to the
 ordinary per capita  contribution present in domestic  wastewaters. Even a relatively small
 industry may contribute a  significantly higher organic loading than the existing domestic
 load. Population  equivalents for many industrial wastewaters should be based on COD
 analysis  rather  than BOD, since extremely strong or toxic wastes may show an artificially
 low BOD.

 Historical  data  on  raw  wastewater  flows and  concentrations  can  provide valuable
 information  on  the magnitude, frequency  and  duration of  peak flows  and loadings.
 Electronic data processing and plotting  techniques are effective in reducing data to a usable
 form and can provide a firm base for projecting future loading conditions (1). Such analyses
 can  detect whether  significant seasonal  or  weekly variations exist.  This is  particularly
 important  in determining  whether plant expansions  can be designed for  annual average
values, or whether weekday industrial loads warrant higher than annual average design values
for sizing of plant components.
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  2.4.1   Hydraulic Overloads

Excessive hydraulic loadings in primary  and secondary clarifiers are a major  cause of
reduced plant efficiency. Increased surface overflow rates and reduced detention periods in
primary clarifiers result in poor BOD and SS capture which increases the loads to be handled
by subsequent treatment units. SS removal in secondary  clarifiers is even more sensitive to
excessive  hydraulic loadings  than  primary  clarifiers.   High secondary  clarifier surface
overflow  rates in  activated sludge plants can result  in the direct  carry-over of biological
solids from the clarifier  sludge  blanket into the  effluent. In trickling filter plants, high
secondary clarifier loadings prevent effective capture of the biological solids sloughed from
the filter media.

In any upgrading situation, it is essential that a thorough study  be made of plant influent
flow records. It is desirable to  review actual meter flow charts to determine typical diurnal
flow variations. These data can be  used to size flow equalization basins, as discussed in
Chapter 3.  Moreover, such analyses are  required  to  determine  whether  seasonal or
continuous  excessive flows exist, and whether the excessive flows are due to groundwater
infiltration or to inflow contributions.

Since  excessive flows can  hydraulically overload  the  unit processes in a  wastewater
treatment plant,  every  effort should  be made  to  reduce excessive infiltration/inflow
contributions before undertaking upgrading techniques. Excessive infiltration/inflow  is a
likely  possibility  when  influent BOD  and SS  concentrations  are  consistently  below
150 mg/1. Plant flow and connected population data, and in some  cases records of potable
water usage, can be used  to determine if an infiltration/inflow problem exists. Major  causes
of infiltration are leaky manholes, faulty lateral connections and  leaky pipe joints.  Major
sources of  excessive inflow are illegal downspouts,  footer drains, cross-connections with
storm sewers and surface runoff into the  top of illogically  placed manholes.

Where it  has been established  that  an infiltration/inflow problem exists, detailed study is
recommended (2). Usually this  consists of an initial analysis to determine the magnitude and
location of the problem  area.  A survey is then made to inspect and/or test the suspected
locations. Usually, the affected portions of the sewers are cleaned before the inspection is
begun. Typical testing and inspection techniques include:

     1.   Smoke testing

     2.   Hydrostatic testing

     3.   Air testing
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     4.   Closed circuit television

     5.   Photographic methods.

The  survey  report  should  identify  the specific  locations for  remedial  action,  the
recommended rehabilitation method and an estimate of the rehabilitation cost. This cost
can  then  be  compared  to  the  cost  of  upgrading  the  plant  with  and  without
infiltration/inflow control to establish a cost effective course of action. The most common
remedial techniques considered are:

     1.   Internal or external pressure grouting with chemical sealants

     2.   Manhole grouting

     3.   Replacing, elevating and/or sealing of manhole covers

     4.   Replacement of severely damaged sewer sections or service connections

     5.   Insertion of sewer liners

     6.   Removal or plugging of illegal inflow connections such as downspouts or footer
         drains.

Reported costs for inspection and repair of sewers vary widely due to a number of factors
such as:

     1.   Sewer age, construction materials and construction methods

     2.   Accessibility of sewers

     3.   Sewer size

     4.   Soil condition.

Because of the great variety of conditions which can be encountered, average cost values or
specific cost  data can be misleading. However, a general cost of $5 to $20 per foot has been
estimated (3).

A number of successful infiltration studies  and control programs  have  been reported
(3)(4)(5), and many others are ongoing.  Once the  problems  are corrected, a continuing
program of  flow  analysis and sewer inspection  can significantly prolong the effective
lifetime of the upgraded plant.
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     2.4.2  Organic Overloads

The more common causes of organic overloading of existing plants are the addition of
substantial industrial loads, increased discharge of septage to the plant, and in-plant recycle
from poorly operating or  overloaded sludge processing operations. Recycled BOD and SS
loads from properly loaded and operated thickeners, digesters, elutriation tanks and vacuum
filters  can amount to  as much as 25 percent of the total  plant organic load. When these
solids processing units  become overloaded or are improperly operated, recycled BOD and SS
loads can reach 50 percent or more  of the total plant organic load. Unless pretreated or
equalized, or unless the plant was originally sized to account for them, these intermittent
recycle loads  can significantly decrease  overall plant performance and,  when  extremely
severe, can cause complete process failure.

Overloads  created  by industrial  contributors can   be   relieved by  pretreatment,  by
equalization or by expansion of critical plant components. As discussed earlier, Federal and
State regulations, along with local ordinances, may necessitate pretreatment. Equalization of
industrial flows  by the discharging industry, or at the municipal plant, is especially effective
when the discharge is of relatively short duration.

Excessive BOD  loadings usually do not have a major adverse  effect on primary treatment.
However, in biological treatment systems, BOD overloads can cause anaerobic conditions in
aeration tanks and trickling filters, and may result in unstable, unsettleable activated sludges
which are prone to bulking and odor problems. High influent BOD loads will also result in
excessive secondary sludge production. The engineer evaluating an existing plant should
check all of the normally used loading parameters to determine if  additional tank volume,
oxygen  supply,  and  return  and  waste  sludge  capacity  is necessary,  or if  operating
adjustments can be implemented.

Excessive SS loadings  will result in  increased primary and secondary  sludge production
which, in turn,  may exceed  the  capacity of existing  thickeners, digesters and dewatering
equipment. If adequate plant data exist, the actual loading parameters can be compared to
the plant design values to  determine  the degree of overloading and to identify alternative
courses of action.

Complete system mass balances for phosphorus and SS are excellent tools to determine the
validity of wastewater  and sludge flow measurements and analytical  data. Solids balances are
a key  factor in  identifying the source and magnitude  of excessive  in-plant recycling loads.
Phosphorus balances are useful because phosphorus is  the one major pollutant common to
all  municipal  wastewaters  which does not break down (even partially)  to  gaseous forms
during biological treatment.

In  smaller plants located in communities served  partially by septic tank systems, the
discharge of relatively large quantities of septage can create signficant BOD and SS overloads

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and sludge handling and odor problems. Thus, in such an upgrading evaluation, the quantity
of  septage which will  be  discharged  to  the plant should be thoroughly investigated. In
northern states, where  tanks are normally emptied during the spring and summer months,
the  annual quantities of materials collected  will be introduced to the plant over a 6- to
8-month period.  The quantity and characteristics of septage vary widely (5)(6)(7)(8)(9).
This variation is greater in  communities that  do not employ a permit system, or otherwise
regulate the  collection and disposal  of septage.  In these  cases,  septage haulers  will
indiscriminately include septic tank contents along with raw wastewater collected from pit
toilets,  wastes from camping trailer  pump-out stations,  waste  motor oil from service
stations, cutting oil and other hard to treat or toxic wastes from small industries throughout
the community.

Typical concentration ranges for septage are shown in Table 2-1 (7) (8).
                                     TABLE 2-1
                         CHARACTERISTICS OF SEPTAGE

            Parameter                   Range                     Average

         BOD, mg/1                 2,000 - 25,000                 9,800
         TSS, mg/1                  7,000 - 106,000               43,000
         VSS, percent of TSS           47 - 82                         69

         COD, mg/1                 5,000 - 80,000                54,000
Two methods are commonly employed to handle septage at existing treatment facilities.
The method of choice will depend on a complete analytical characterization of the septage,
the relative volume of septage to influent wastewater flow and physical constraints at the
plant site.

If the ratio of septage to total plant flow is relatively small on a pound of BOD/day basis,
these wastes may be discharged to an aerated storage basin at the plant site and metered into
the plant at a controlled rate so as not to seriously interefere with normal plant operation
and performance.

If the  ratio of  septage to total plant  flow  is  high, or if the septage contains  toxic or
treatment inhibiting substances, separate treatment facilities  must be  provided. Full-scale
separate treatment techniques that have been considered include aerobic digestion followed
by sludge dewatering  and aerobic digestion followed by introduction of digester contents at

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a controlled  rate into the plant. Separate treatment pilot studies have included aerobic
digestion, followed by dewatering on sand beds, polymer thickening, and high  lime  (pH
11.5) stabilization followed by dewatering on sand beds (7).

2.5  Upgrading to Improve Plant Design and Operation

Many  existing  plants,  although well  designed,  have  not  produced  the  anticipated
performance because of inadequate operator staffing and training, and/or a lack of financial
support and commitment to water pollution abatement from the community. On the other
hand, some poorly  designed plants are functioning well because of the excellence of plant
operation.  Each upgrading situation will  contain its  own innate characteristics relative to
plant  design  and  operation.  The  design   engineer  must  carefully  evaluate  the
interrelationships of the  design and its operation to arrive at the solution which optimizes
both of these factors.

     2.5.1  Plant Design

In the past,  the problems  associated with inadequately designed municipal wastewater
treatment plants have been a major concern of Federal and State agencies. For this reason,
most  states have adopted conservative design guidelines and review procedures which must
be  followed  unless the engineer  can  substantiate  a less conservative  viewpoint.  The
implementation of  these procedures by regulatory agencies has reduced the frequency of
inadequate plant design. However, there are many aspects of detailed design other than
those covered by these regulations which can still adversely affect overall plant performance.
Usually,  the  plant operators responsible  for day-to-day supervision of plant  systems  and
components can identify major design deficiencies.

Among the  numerous design features  which can adversely affect  plant operation  and
performance are:

     1.   Inadequate standby equipment

     2.    Fixed speed units where variable speed is essential, such as raw wastewater pumps,
         recycle pumps and air blowers

     3.   Poor hydraulic and solids distribution among identical units operating in parallel

     4.   Insufficient or inflexible return and sludge wasting pumping capacity

     5.   Inability  of  instrumentation and equipment  to operate at low flows and loads
          occurring in the early lifetime of the plant
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     6.   Lack  of tank  dewatering systems  to  permit  rapid  servicing of submerged
          equipment

     7.   Lack of flexibility in disinfection systems to permit prechlorination for odor
          control, or return sludge chlorination for control of sludge bulking

     8.   Inadequate electrical and  hydraulic capacity to permit standby pumps and air
          blowers to operate in parallel

     9.   Inadequate laboratory facilities

    10.   Lack of accessibility to  key mechanical equipment for routine maintenance or
          repair.

From  a process standpoint, the most common  deficiency is plant design based on average
flow and  BOD and SS loadings, with no recognition of peak conditions.  In many plants,
sustained  peak influent flows and BOD and SS  loads can reach two  or more times average
values. Therefore, all plant units  and systems, including primary  and secondary sludge
pumping,  air supply equipment and solids processing components,  should be designed to
perform successfully  at peak conditions. Frequently, peak flows and  BOD and SS mass
loadings do not occur simultaneously (10). Thus, a design based on the concurrence of peak
flow and peak pollutant concentration conditions may result in excess capacity. Analysis of
existing plant data, if available, will assist in determining the appropriate peak mass loadings
and flows.

     2.5.2  Plant Operation

One of the primary considerations in evaluating an overloaded plant is in the area of plant
operation  and control. Therefore,  no physical  upgrading should be considered before the
engineer is assured that the plant is being operated to yield its maximum efficiency.

A major tool required for proper  process control  is frequent and accurate  sampling and
laboratory analysis. The locations  at which samples are  taken are critical, particularly in
solids-laden flows where solids tend to travel near the bottom of the conduit.

Many wastewater treatment plants do not have a laboratory equipped to analyze wastewater
samples from the various  treatment  units in order  to assess  their performance. Improper
operation, coupled with inadequate  laboratory  control, increases the probability  of poor
treatment. For this reason, plants must be staffed with an adequate  number of competent
operators  and laboratory personnel.  Further, sufficient funds must be made available for
proper maintenance and for the purchase of adequate sampling and analytical equipment
and supplies.
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Because  of  the availability of field  training programs (11) and the trend to mandatory
operator certification, operator skills  have improved markedly  over the past five years. The
engineer involved  in  an upgrading situation should identify any areas in which additional
training would result in an improved operation.

2.6  Consideration of Applicable Upgrading Techniques

Technology in the field of wastewater treatment in  the past decade has  provided many
innovative upgrading  procedures. Various research projects sponsored by the U.S. EPA have
resulted in a better understanding of existing and new unit processes. In addition, new types
of equipment  have  significantly  enlarged the  range of alternatives available for plant
upgrading.

It has long been recognized that the performance of a wastewater treatment plant is affected
by  variations  in  the influent flow.  Equalization  of extreme flows  can  dampen the
fluctuations in flows and mass loadings to existing plants.

Various techniques such as chemical coagulation, polyelectrolyte addition and novel settling
devices are being successfully used to increase removal efficiency in primary and secondary
clarifiers. These procedures  can improve removal efficiency  while  maximizing hydraulic
throughput in the  existing facilities.

Several modifications of the  conventional activated sludge process, including step aeration,
contact  stabilization  and complete  mix have  been  successfully used to upgrade various
treatment plants.  A most significant recent development in the activated sludge treatment
process is the use of oxygenation as a substitute for air aeration.

Another method  of upgrading an overloaded  secondary  plant is  to  provide additional
treatment ahead of the  existing biological treatment facilities. The use  of synthetic media
trickling filters should be considered when roughing treatment would reduce BOD loadings
on  existing facilities  to acceptable operating levels. Synthetic  media filters have been used
successfully as roughing  filters in industrial wastewater treatment, and it is very likely that
they will be used in the future for upgrading municipal treatment plants.

The beneficial  effect of  a nitrified effluent on DO in receiving waters is  receiving increasing
attention. For  this reason, some regulatory agencies are requiring nitrification of treatment
plant effluents during summer periods, and in some  cases are contemplating a year-round
nitrification  requirement.   Nitrification  at  higher  wastewater  temperatures   may  be
accomplished through modifications to the existing treatment units,  such  as increasing
aeration tank volume or adding chemicals to the primary clarifier to decrease the organic
loading  to existing  aeration units. However, dependable  year-round nitrification will
normally require a two-stage biological treatment system.

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In an increasing number of instances, treatment plants which are functioning satisfactorily
(design flow not exceeded) will have  to  improve BOD and SS removals because of more
stringent water quality standards. The necessary additional treatment can often be achieved
by polishing the treatment plant effluent. Several methods are currently available and have
been used successfully, including tertiary aerobic and facultative lagoons, microscreening,
multimedia filtration and activated carbon treatment.

Various  sludge handling  developments  which  have been successful  are: (1)  high-rate
anaerobic digestion,  (2) aerobic  digestion,  (3)  air flotation  thickening or  centrifugal
thickening of waste activated sludge, (4) polyelectrolyte addition to improve thickening and
dewatering of sludges and (5) heat treatment processes for sludge stabilization.

Although this  manual presents in detail current technology available for upgrading existing
wastewater treatment  plants,  the  engineer should keep in  mind  the following overall
considerations which will affect the economics of upgrading:

     1.   The physical  condition  of  existing plant equipment and  structures and their
         potential uses in an upgrading situation

     2.   The length of  time  before  a major  expansion  will be required,  based  on
         population and wastewater flow projections

     3.   The time required for implementation of various upgrading techniques

     4.   The compatibility of upgrading procedures with future planned expansion

     5.   The financial assistance available to the community

     6.   The costs of the various  upgrading techniques that can be used  to achieve
         essentially the same  result. The operation and maintenance costs, as well as the
         capital costs, may vary substantially for different available alternatives. Therefore,
         economic comparison of these alternatives is essential.

2.7  References

 1.  Schwinn, D. E., and Dickson, B. H., Computer Analysis of Wastewater Treatment Plant
     Operating Data. Metcalf & Eddy, Inc., Internal Document (1970).

 2. Sewer System  Evaluation. U. S. EPA, Office of Water Program Operations (October,
     1973).
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 3.  American  Public Works Association, Control of Infiltration and In-flow into Sewer
    Systems. U. S. EPA,  Water Pollution Control Research Series, Program  No. 11022
    EFF, Contract No. 14-12-550, pp. 45-52, p. 93 (December, 1970).

 4.  Ground Water Infiltration  and Internal  Sealing of Sanitary Sewers,  Montgomery
    County, Ohio. U. S. EPA, Water Pollution Control Research Series, Project No. 11020
    DHQ (June, 1972).

 5.  Sewer Bedding and Infiltration  - Gulf Coast Area. U. S. EPA, Water Pollution Control
    Research Series, Project No. 11022 DEI (May, 1972).

 6.  Graner, W., Scavenger  Waste Disposal Problems  on Long Island. Unpublished paper
    presented before New York Water Pollution Control Association (June, 1968).

 7.  Feige,  W.A., Oppelt,  E.T., and Kreissl, J.F., Alternative to  Septage Treatment; Lime
    Stabilization  — Sand Bed  Dewatering.  Prepublication Interim Report,  U. S. EPA,
    Advanced  Waste Treatment Research Laboratory, National Environmental Research
    Center, Cincinnati, Ohio (April, 1974).

 8.  Kolega, J., Design Curves for Septage. Water and Sewerage Works, 118, pp. 132-135
    (May, 1971).

 9.  Rotondo,  V., "Honey Wagon" Sludge Disposal. Journal New England Water Pollution
    Control Assoc., 2, No. 1, pp. 59-64 (March, 1968).

10.  Schwinn, D. E., and Dickson, B. H., Nitrogen and Phosphorus  Variations in Domestic
    Wastewater. Journal Water  Pollution Control Federation, 44, No. 11, pp. 2059-2065
    (November, 1972).

11.  Operation  of  Wastewater   Treatment  Plants,  A  Field Study  Training Program.
    U. S. EPA, Office of Water Programs (1970).
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                                    CHAPTER 3

                              FLOW EQUALIZATION


3.1  Introduction and Concept

     3.1.1  General

The  cyclic nature of wastewater flows in terms of volume and strength is well recognized.
Nearly all municipal wastewater treatment plants today are processing variable wastewater
flows.  However, improved efficiency,  reliability and  control is  possible when physical,
biological and chemical processes  are  operated at or near uniform conditions. For this
reason, flow equalization is employed in the field of water supply and in the treatment of
some industrial  wastewater.  Presently, the advent  of more  demanding water quality
standards is stirring interest in the application of flow equalization to municipal wastewater
treatment.

The primary objective of flow equalization basins for municipal treatment plants is simply
to dampen the diurnal flow variation, and thus achieve a constant or nearly constant flow
rate  through  the downstream treatment processes. A desirable secondary objective is to
dampen  the  concentration and  mass flow of wastewater  constituents  by blending  the
wastewater  in the  equalization basin.  This results in a more uniform loading of organics,
nutrients and  other suspended and dissolved constituents to subsequent processes.

Through achieving these  objectives,  flow equalization  can significantly  improve  the
performance  of an existing treatment facility, and is a useful upgrading technique. In the
case  of  new plant design,  flow equalization can  reduce the required size of downstream
facilities.

     3.1.2  Variations of Flow Equalization

Equalization of municipal wastewater flows may be divided into three broad categories:

     1.   Equalization of dry weather flows

     2.   Equalization of wet  weather flows from separate sanitary sewers

     3.   Equalization of combined storm and sanitary wastewater.

This  chapter is primarily concerned with equalization of dry weather flows. This procedure
provides a technique for achieving  normal operation of a treatment plant under near ideal
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loading conditions. Its relatively low cost makes it attractive for upgrading an overloaded
plant.

Increased wet weather flows in sanitary sewers is the sum of two components, infiltration
and inflow. In some cases,  it is feasible to equalize stormwater inflow, depending on its
magnitude and duration. Infiltration from high groundwater tables can seldom be equalized.
Equalization of wet  weather flows  from  combined  storm and sanitary sewers usually
requires very large storage basins. The design of equalization basins to deal with these types
of flow  requires  a special knowledge of the collection system, precipitation  patterns,
topography,  and  other factors not  directly  related  to wastewater  treatment.  Strictly
speaking,  wet weather and  combined sewer flow equalization cannot  be considered  as a
wastewater treatment upgrading technique, and the design of such a  facility is beyond the
scope of this chapter.  However, the concepts presented for  dry weather flow equalization
are generally applicable to equalization of wet weather and combined wastewater flows.

In some instances, large interceptor sewers entering the treatment plant can be effectively
used as storage basins  to dampen peak diurnal dry weather flow variations. In such cases,
nightly or weekly  drawdown of the interceptor system is necessary to flush out solids which
may have been deposited during the previous storage period.

Although the use of influent sewers  for  equalization should not  be ignored,  the most
positive and effective means to maximize the benefits possible with equalization is through
the use of specially designed equalization basins. These basins should normally be located
near the head end of the treatment works, preferably downstream of pretreatment facilities
such as bar screens, comminutors, and grit chambers. Adequate aeration and mixing must be
provided to keep the basins aerobic and prevent solids deposition.

It is sometimes desirable to locate the equalization basin at strategic locations within the
collection system. This offers the  added advantage of economically relieving trunk sewer
overload  during peak flow  periods (1).  However, it does result in the  need for a pumping
facility and therefore is best located where a need for pumping already exists.

Equalization basins may be designed as either  in-line or side-line units. In the in-line design
shown on Figure  3-la, all the flow passes  through the  equalization basin. This  results in
significant concentration and  mass flow damping. In  the side-line design shown on Figure
3-lb, only that amount of flow above the daily average is diverted through the equalization
basin.  This scheme minimizes  pumping requirements  at  the  expense  of  less effective
concentration damping.
                                        3-2

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                                    FIGURE 3-1

             SCHEMATIC FLOW DIAGRAMS OF  EQUALIZATION FACILITIES

                                                           -CONTROLLED  FLOW PUMPING STATION
RAH         J—
WASTEWATER~*|	
   BAR  SCREEN
   AND/OR
   COMMINUTOR-
 FINAL
'EFFLUENT
                                                      FLOW METER AND CONTROL  DEVICE
                                                      SLUDGE  PROCESSING
                                                      RECYCLE FLOWS
                            3-la IN-LINE EQUALIZATION

RAW i | 	 1 G
IIHSTtllAT tR 1 REM
BAR SCREEN!
AND/OR \
COMMINUTOR-1
CONTROLLED
FLOW PUMPIN
STATION 	
\
RIT r— i
OVAL 1 1
T
EQUALIZA-
TION
BASIN
.H
CONTROL DEVICE^
t
« ^
!/
i 	 i "
i
PRIMARY
TREATMENT



SECONDARY
TREATMENT

FINAL
~~*" EFFLUENT
SLUDGE PROCESSING
RECYCLE FLOWS




                                 3-lb  SIDE-LINE EQUALIZATION
                                            3-3

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For  new construction and  for upgrading  large plants,  it  is  desirable to  construct
compartmentalized or multiple basins.  This feature will allow the flexibility to  dewater a
portion of the facility for maintenance or equipment  repair while still providing some flow
equalization. Where a basin is  designed for storage  and equalization of wet weather flows,
compartmentalized tanks will allow the utilization of a portion of the basin for dry weather
flow equalization.

Single  basin installations  may be used for upgrading small plants, but  must have the
provision to be dewatered while maintaining complete treatment. This will require a bypass
line around the basin to allow the downstream portion of the plant to operate unequalized
when the flow  equalization facility is out of service.

3.2  Benefits of Dry Weather Flow Equalization

Flow equalization has a positive impact on all treatment processes from primary  treatment
to advanced waste treatment.

     3.2.1  Impact on Primary Settling

The  most beneficial impact on primary settling is the reduction of peak overflow rates
resulting in improved performance,  and a  more uniform primary effluent quality. Flow
equalization permits  the sizing of new clarifiers based on equalized flow rates rather than
peak rates.  In  an existing primary clarifier that is hydraulically overloaded during  periods of
peak diurnal flow, equalization can reduce the maximum overflow  rate to an acceptable
level. A constant influent feed rate also avoids hydraulic disruptions in the clarifier created
by sudden flow  changes,  especially those caused by  additional wastewater lift pumps
suddenly coming on line.

LaGrega and Keenan (2) investigated the effect of flow equalization at the 1.8 mgd Newark,
New  York  Wastewater Treatment  Plant.  An existing  aeration tank was temporarily
converted to an equalization basin. They  compared  the performance of primary  settling
under marginal operating conditions, with and without equalization.  The results  are shown
in Table 3-1.

It has been demonstrated (3) (4) that preaeration can significantly improve primary  settling,
as discussed in Chapter 8.  Roe (3) concluded that preaeration preflocculates SS  thereby
improving their settling characteristics. Indications  are that this benefit may be realized by
aerated equalization basins. This benefit may be  diminished when  the equalized flow is
centrifugally pumped to the primary clarifier, due to the shearing of the floe.
                                        3-4

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                                    TABLE 3-1
            EFFECT OF FLOW EQUALIZATION ON PRIMARY SETTLING
                              NEWARK, NEW YORK

                                            Normal Flow    Equalized Flow

       Primary Influent SS, mg/1                 136.7            128.0
       Primary Effluent SS, mg/1                 105.4             68.0
       SS Removal in Primaries, percent            23               47

       Note: Average flow slightly higher in unequalized portion of study.
     3.2.2  Impact on Biological Treatment

As contrasted to primary treatment or other mainly physical processes where concentration
damping is of minor benefit,  biological treatment performance can benefit significantly
from both concentration damping and flow smoothing. Concentration damping can protect
biological processes  from upset or  failure from shock loadings  of  toxic or treatment
inhibiting substances. Therefore, in-line equalization basins are preferred to side-line basins
for biological treatment applications.

Improvement in effluent quality  due to stabilized  mass loading  of  BOD on biological
systems treating normal domestic wastes has not been adequately demonstrated to date. It is
expected that the effect will  be  significant where  diurnal  fluctuations in organic mass
loadings are extreme. This situation may arise at  a wastewater treatment plant receiving a
high-strength industrial flow of short duration. Damping of flow and mass loading will also
improve aeration tank performance where aeration equipment is marginal or inadequate in
satisfying peak diurnal loading oxygen demands (5).

The optimum pH for bacterial growth lies between 6.5 and 7.5. In-line flow equalization can
provide an effective means for maintaining a stabilized pH within this range.

Flow smoothing can be expected  to improve final settling even  more so than primary
settling. In the  activated sludge  process, flow  equalization has  the added benefit of
stabilizing the solids loading on the final clarifier. This has two ramifications:

     1.   The  MLSS concentration  can be increased thereby decreasing the F/M and
         increasing the  SRT. This may result in an increased level of nitrification, and a
         decrease in  biological sludge production. It may also improve the performance of
         a system operating at an excessively high daily peak F/M.
                                       3-5

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     2.   Diurnal fluctuations in the sludge blanket level will be reduced. This reduces the
         potential for solids being drawn over the weir by the higher velocities in the zone
         of the effluent weirs.

     3.2.3   Miscellaneous Benefits

In chemical coagulation and precipitation systems using iron or aluminum salts, the quantity
of chemical coagulant  required is proportional to the mass of material to be precipitated.
Damping of mass loadings with in-line equalization will improve chemical feed control and
process reliability, and may reduce instrumentation complexity and costs.

Flow smoothing  will reduce the surface area required and enhance the performance of
tertiary filters. A constant feed rate will lead to more uniform solids loadings and filtration
cycles.

The equalization basin provides an excellent point of return for recycled concentrated waste
streams  such  as digester  supernatant,  sludge  dewatering  filtrate  and  polishing  filter
backwash.

Some BOD reduction is likely to occur in an aerated equalization basin. A 10 to 20 percent
reduction has been suggested (6) for an in-line basin equalizing raw wastewater. However,
the degree  of reduction  will depend upon the detention time in the basin, the aeration
provided, wastewater temperature and other factors. For an existing treatment plant, a
simple series of  oxygen uptake studies on a representative sample of wastewater can
determine the BOD reduction that will occur.

Roe  (3)  observed that preaeration may improve  the  treatability of raw  wastewater  by
creating a positive oxidation-reduction potential, thereby reducing the degree of oxidation
required in subsequent stages of treatment.

3.3  Determination of Equalization Requirements

The  design of an equalization basin requires the evaluation and selection  of a number of
features as follows:

     1.   In-line versus side-line basins

     2.   Basin volume

     3.   Degree of compartmentalization

     4.   Type of construction - earthen,  concrete or steel
                                        3-6

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     5.   Aeration and mixing equipment

     6.   Pumping and control concept

     7.   Location in treatment system.

The design decisions must be based on the nature and extent of the treatment processes
used, the benefits desired, and local site conditions and constraints.

It may  not be  necessary  to  equalize the  entire  influent flow where  high  flow or
concentration variations can be attributed to one source, such as an industry. In these cases
the desired benefits can be achieved by simply equalizing the industrial flow. This can be
accomplished through construction of an equalization basin at the industrial site or through
in-house industrial process modifications to effect an equalized wastewater discharge.

     3.3.1   Determination of Required Volume

Two methods are available for computing equalization volume requirements. One procedure
is based on the characteristic diurnal flow pattern. In this case, the function of the basin is
to store flows in excess of the average daily flow and to discharge them at times when the
flow is less than  the average. The required volume can be determined graphically through
the construction  of a hydrograph. The  second procedure is based upon the mass loading
pattern of a particular constituent. This method computes the volume required to dampen
mass loading variations to within a preset acceptable range (7)  (8).

Since the prime objective of flow equalization  in wastewater treatment is to equalize flow,
the determination of equalization volume should be  based on the hydrograph. Once the
volume has been determined for flow smoothing, the effect on concentration and mass load
damping can be  estimated. The required volumes for  side-line  and in-line  basins will be
identical. The hydrograph procedure is discussed below.

The first step in design involves the establishment of a diurnal  flow pattern. Whenever
possible, this should be based upon actual plant  data. It is important to note that the diurnal
pattern  will vary from day to  day, especially from weekday to weekend and also from
month to month. The pattern selected must yield a large enough basin design to effectively
equalize any reasonable dry weather diurnal flow. Figure 3-2 depicts a typical diurnal flow
pattern. The average flow rate is 4.3 mgd. For purposes of this example, the average flow is
used as the desired flow rate out of the equalization basin. The diurnal peak and minimum
flow rate for this example are 1.7 and 0.45 times the average, respectively.

The next step involves the actual construction  of the hydrograph.  The hydrograph for this
example is  shown on Figure 3-3. The inflow mass diagram is plotted first. To do  this, the
hourly diurnal flows are converted  to equivalent hourly volumes, and accumulated over the

                                       3-7

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                          FIGURE 3-2

       RAW WASTEWATER FLOW AND BOD VARIATION
                    BEFORE EQUALIZATION
      - 300
   BOD MASS LOADING
   PEAK: AVERAGE  =1.97
   MINIMUM: AVERAGE = 0.14
   PEAK:MINIMUM  =  14.59
12
MIDNIGHT
                                                       0
     12
MIDNIGHT
                                                               -_4QO  «P
                                                               __ 200
                           TIME  OF DAY
                               3-8

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4,000 -
3,500-
3,000 -
2,500-
2,000-
1 ,500-
 ,000-
  500-
                             FIGURE  3-3
            HYDROGRAPH FOR TYPICAL DIURNAL FLOW
             REQUIRED EQUALIZATION
             VOLUME,  740,000 GALLONS
                                            INFLOW MASS DIAGRAM
                                            AVERAGE FLOW 4.3 MGD
     12     2

   MIDNIGHT
   NOON
TIME OF DAY
                                 3-9

-------
24-hour day. A line is then drawn from the  origin to the end point on the inflow mass
diagram. The slope of this line actually represents the average flow for the day.

Enough tank volume must be provided to accumulate flows above the equalized flow rate.
This normally requires a volume equivalent to 10  to 20 percent of the average daily dry
weather flow. To  determine this volume, the inflow mass diagram must be enveloped with
two lines parallel  to the average flow line and  tangent to the extremities of the inflow mass
diagram.  These are shown  as lines A  and  B on Figure 3-3.  The  required volume is
represented by the vertical distance between these two lines. In this illustration, the required
volume for equalization is 740,000 gallons, which represents approximately 17 percent of
the average daily flow.

The physical interpretation of the hydrograph is simple. At 8:00 AM, the equalization basin
is empty, as signified by the tangency of the inflow mass diagram with the bottom diagonal.
At this point, plant  flow begins to exceed the average flow rate and the tank begins to fill.
This is represented by the divergence of the inflow  mass diagram and the bottom diagonal.
At 5:00 PM, the basin is full, as shown by the tangency of the inflow mass diagram with the
top diagonal. Finally, the tank is drawn down from 5:00 PM to 8:00 AM on the following
day, when the flow is below average.

The  actual  equalization basin volume  must be  greater  than  that obtained with  the
hydrograph for several reasons, including:

     1.   Continuous operation of aeration and mixing equipment will not allow complete
         drawdown.

     2.   Volume must be provided to accommodate anticipated concentrated plant recycle
         streams.

     3.   Some contingency should be provided for unforeseen changes in diurnal flow.

The final volume  selected should include adequate consideration of the conditions listed
above and will also depend on the basin geometry. For the example presented herein, a
basin volume of approximately one million gallons is adequate.

     3.3.2  Impact  of Equalization on Diurnal Concentration Variation

At this point, it is appropriate to examine the impact of flow equalization on mass loading
and concentrations.  As previously mentioned,  side-line equalization has a minimal effect on
diurnal concentration variations. The following  discussion is  therefore limited to in-line
basins.
                                       3-10

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An hourly concentration plot for raw wastewater BOD is plotted with the diurnal flow
pattern on Figure 3-2. Note that low BOD concentrations occur at night with low flows, and
high BOD concentrations occur during the daytime with high flows. This is a typical pattern
for dry weather flows and BOD's. Because of this characteristic, the mass loading rate of raw
wastewater BOD, shown on Figure 3-2, exhibits even greater fluctuations. If this wastewater
is equalized  in  a one  million gallon in-line  basin,  the equalized flow  will exhibit the
characteristics shown on Figure 3-4, provided:

     1.   The basin is designed to provide complete mixing.

     2.   There is no BOD reduction in the basin.

This damping effect would be similarly  beneficial for all concentration variables including
SS, nitrogen, phosphorus, and toxic constituents.

On Figure 3-4, the changes in BOD concentration are most pronounced during periods  of
minimum wastewater volume in the equalization tank. If desired, increased damping can  be
achieved by  increasing the active volume of the  tank, i.e., the volume in excess of that
obtained from the hydrograph.

     3.3.3   Basin Construction

Equalization  basins can be provided through the construction of new facilities or through
the  modification of  existing facilities  of  sufficient volume. Equalization may   be
implemented with relative ease  in an upgrading  plan that calls for the abandonment  of
existing tankage.  Facilities which  may  be suitable for conversion to equalization basins
include aeration tanks, clarifiers, digesters and sludge lagoons.

New basins may be constructed of earth, concrete or steel. Earthen basins are generally the
least expensive. They can normally be constructed with side slope varying between 3:1 and
2:1 horizontal to vertical,  depending on the type of lining used. To prevent  embankment
failure in areas of high groundwater, drainage facilities should be provided for groundwater
control. In large basins where a combination of aerator action and wind forces may cause
the formation of large waves, precaution should be taken in design to prevent erosion. It is
also customary to provide  a concrete pad directly under the equalization  basin aerator  or
mixer. The top of the dikes should be  wide enough to ensure a stable embankment. For
economy of construction, the top width of the dike should be sufficient to accommodate
mechanical compaction equipment.

In-line  basins should be  designed to  achieve complete mixing in  order  to optimize
concentration damping.  Elongated  tank design enhances plug flow and should be avoided.
Inlet and outlet configurations should be  designed to prevent short-circuiting. Designs which
discharge influent flow as close as possible to the basin mixers are  preferred.

                                        3-11

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                FIGURE 3-4

RAW WASTEWATER FLOW AND BOD VARIATION
            AFTER EQUALIZATION
8 -
7 -
6-
a
3
E
. 5 -
J
C
'- 4 -
C
>
- 3 -
2 -
1 -
n
1
MIDN
BOD MASS LOADING
PEAK: AVERAGE= 1.22
MINIMUM:AVERAGE = 0.61
PEAK:MINIMUM = 2.01
BOD CONC.-^
X\ /' BOD MASS LOADING-v
'\. X\ 1 ^--^ FLOW RATE-/ X
'\. X^^ f'^
2 6 12 6 1
IGHT NOON MIDN
- 30
- 20
- 10
n
2
GHT
                                                  -r- 600
                                                 -- 400
                                                        oo
                                                        CO
                                                  -- 200
                                                  -L-0
             TIME OF DAY
                     3-12

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 To continue the previous illustration, an earthen basin has been selected for the equalization
 facility. A square plan has  been chosen to effect optimum mixing. A section view of the
 basin  with appropriate dimensions  is shown on Figure 3-5. The volume requirement
 computed from the hydrograph is provided in the upper eight feet. Note that the minimum
 required operating depth lies above the minimum allowable aerator operating level.

     3.3.4  Air and Mixing  Requirements

 The successful operation of both in-line  and side-line basins  requires proper mixing and
 aeration.  Mixing equipment should be designed to blend the contents of the tank, and to
 prevent deposition of solids in  the basin.  To minimize mixing requirements, grit removal
 facilities  should  precede  equalization basins  wherever possible.  Aeration is  required to
 prevent the wastewater from becoming septic. Mixing requirements for blending a municipal
 wastewater having a  SS  concentration of approximately 200 mg/1 range  from 0.02 to
 0.04 hp/1,000 gallons of storage. To maintain aerobic conditions, air should be supplied at a
 rate of 1.25 to 2.0 cfm/1,000 gallons of storage (9).

 Mechanical aerators are one method  of providing both mixing and  aeration. The oxygen
 transfer capabilities of mechanical aerators operating in tap water under standard conditions
 vary  from  3  to 4 Ib 02/hp-hr. Baffling may be  necessary to ensure  proper  mixing,
 particularly with  a  circular tank configuration.  Minimum operating levels for floating
 aerators generally exceed  five feet, and vary with the horsepower and design of the unit.
 Low  level shutoff controls should be provided to protect the unit. The  horsepower
 requirements to prevent deposition of solids in the basin may greatly exceed the horsepower
 needed for blending and oxygen transfer. In such cases, it may be more economical to install
 mixing equipment to  keep the solids in suspension and furnish the air requirements through
 a diffused air system, or by mounting a surface aerator blade on the mixer.

 It should  be cautioned that other factors  including maximum operating depth and basin
 configuration affect the size, type, quantity and placement of the aeration equipment. In all
 cases, the  manufacturer should be consulted.

     3.3.5  Pump and Pump Control Systems

 Flow  equalization imposes an additional head requirement within  the treatment plant. As a
 minimum, this head is equal to the sum of the dynamic losses and the normal surface level
variation.  Additional head may be required if the basin is to be dewatered to a downstream
location. It may be possible to dewater the basin upstream (e.g., ahead of raw wastewater
pumps) by gravity.

Normally, the head requirement cannot be fulfilled by gravity, thereby requiring pumping
facilities. The pumping may  precede or follow equalization. In some cases pumping of both
                                       3-13

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                                       FIGURE  3-5

                              EARTHEN EQUALIZATION BASIN
                                          153'
                    -3-0'FREEBOARD

                    MAX. SURFACE LEVEL
FLOATING  AERATOR

EL.  15.0
MIN.  REQ'D  OPERATING
LEVEL
MIN.  ALLOWABLE  OPERATING
LEVEL TO  PROTECT FLOATING
AERATOR*
                                                           CONCRETE  SCOUR PAD*
                     VOLUMES:
                            EL.  0.0  TO  EL. 7.0 APPROXIMATELY   260,000  GAL.
                            EL.  7.0  TO  EL. 15.0 APPROXIMATELY  740,000  GAL,
                            TOTAL  VOLUME  =
       1,000,000 GAL.
  *THESE  DIMENSIONS WILL VARY WITH  AERATOR DESIGN AND HORSEPOWER
                                        3-14

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raw and equalized flows will be required. Influent pumping will require larger capacity
pumps to satisfy diurnal peaks.

Gravity discharge from equalization will require an automatically controlled flow regulating
device.

A flow  measuring device is required downstream of the basin to monitor the equalized flow.
Instrumentation should be  provided to control  the  preselected equalization rate  by
automatic adjustment of the basin effluent pumps or flow-regulating device.

     3.3.6   Miscellaneous Considerations

The following  features are considered to be desirable for the design of the equalization
facility:

     1.   Equalization should be preceded if possible with screening and grit removal to
         prevent grit deposition and rag fouling of equipment in the basin.

     2.   Surface aerators should be fitted with legs to support and protect the units when
         the tank is dewatered.

     3.   Facilities should be provided to flush solids and grease accumulations from the
         basin walls.

     4.   A high-water level  takeoff should be provided for withdrawing floating material
         and foam,

     5.   An emergency overflow should be provided.

3.4  Costs

The development of alternatives for any plant upgrading program should include at least one
which incorporates flow equalization.  In all cases, the added cost of flow equalization must
be measured against (1)  the  savings in cost of modifying downstream processes to accept
diurnal  variations  and (2) the improved performance that can be achieved by operating
downstream processes under relatively  constant loading conditions.

The cost of flow  equalization will vary considerably from  one application to another,
depending  on  the  basin size, construction  selected,  mixing and  aeration  requirements,
availability  of land, location of facility, and pumping requirements. Some judgment must be
made on the distribution of pumping costs. Pumping costs for an equalization basin used to
upgrade existing facilities should be charged to the basin.
                                       3-15

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Capital costs for equalization facilities have been estimated by Smith, et al, (10) and are
listed in Table 3-2. The costs for earthen basins include plastic liner and floating mechanical
aerators. The costs for the concrete basins include diffused aeration facilities. Pumping costs
are based on the construction of a separate equalization basin effluent pumping station. The
costs were  developed in conjunction with activated sludge treatment  system designs and
therefore include  a  proportional  amount  of the engineering fees  and interest during
construction.
                                     TABLE 3-2
                       COST OF EQUALIZATION FACILITIES
                                 (EPA INDEX 175)

                              Earthen Basin               Concrete Basin
       Plant     Basin      With        Without        With         Without
        Size     Size     Pumping      Pumping      Pumping      Pumping
       mgd     mil gal
1
3
10
0.32
0.88
2.40
$124,000
170,000
318,000
$ 72,300
84,000
134,000
$175,000
333,000
779,000
$124,000
247,000
595,000
The  construction cost for the earthen equalization basin  on Figure 3-5 is estimated  at
$80,000. The cost includes excavation, plastic liner, sand subbase, concrete scour pad, dike
fill, underdrain and a 40-hp floating aerator. The costs do not provide for pumping costs,
land costs, engineering and legal fees, nor interest during construction.

3.5  Performance and Case Histories

Little full-scale  operating  data  are currently available to  compare  the performance  of
wastewater treatment plants with and without flow equalization. However, an increasing
number of plant designs are incorporating the use of equalization facilities for upgrading
existing plants and construction of new plants. The following case histories are presented as
examples of equalization basin design.

     3.5.1  Ypsilanti Township, Michigan

A flow equalization project at  the Ypsilanti Township Sewage Treatment Plant is currently
under way. The treatment facility consists of two adjacent activated sludge plants recently
upgraded from 7.0 mgd to treat a total flow of 9.0 mgd. Two 350,000-gallon digesters have
been converted to equalization tanks. Data will be collected over a two-year study period
for each plant. The flow will be equalized to one plant the first year while background data

                                       3-16

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is collected for the remaining plant. The situation will be reversed the second year, with the
flow  being equalized to the second plant while unequalized flow performance data are
collected  on the first plant. Comparison of  these  data  will be made to  determine the
beneficial effects of flow equalization on each plant.

     3.5.2  Fond du Lac, Wisconsin

This case  illustrates a situation in which only a portion of the flow is equalized. The City of
Fond du  Lac, Wisconsin,  presently employs  a single-stage trickling filter  plant to treat
combined municipal-industrial wastes. Placed in operation in 1950, the plant was designed
to treat an ultimate dry weather flow of 8 mgd and a BOD loading of 12,500 Ib/day. The
facility is presently treating  an  average of 7.1 mgd with a BOD loading of 24,000 Ib/day,
and hence is  organically overloaded.  This condition is aggravated by the fact that the waste
discharges from a major industrial contributor (a tannery) are presently concentrated during
daylight hours.  The tannery  discharges wastes to the treatment plant via a  separate force
main. It accounts for about 35 percent of the BOD and 50 percent of the SS into the plant,
and about 15 percent of the influent flow, resulting in a widely fluctuating BOD and SS
diurnal load profile.

The  wide fluctuations  in  organic loading are resulting in reduced performance  of the.
trickling filters.  This, in conjunction  with the advent of more stringent treatment standards,
has rendered this  facility inadequate. Plans are  presently under  way  to upgrade the
treatment plant.

This case  represents an ideal situation for employing partial equalization in  the upgrading
scheme. The  volume of the wastes from the tannery is relatively small compared to the total
volume of flow received  at the plant, whereas the organic contribution  is  significant.
Therefore, a relatively  small volume equalization  tank is all  that is required to attain
effective  organic load equalization.  In addition, because the  tannery discharges  to the
treatment  plant via a  separate force  main,  equalization may be accomplished  at the
treatment plant site. The effect of equaKzing the tannery flow over 24 hours is illustrated on
Figure 3-6.

Located at the plant site  are six abandoned square anaerobic digesters, each measuring
50 feet by 50 feet by 17.5 feet  deep. Four of the units have fixed covers  and two have
floating covers. The utilization of these  tanks for equalizing the  tannery  flow was
investigated. The investigations indicate  that the four fixed cover tanks would be adequate
for equalization for all but  a  few days each year when the use of the two additional tanks
would be necessary because of high flows or maintenance.

The  conversion  of the abandoned digesters to  equalization tanks entails  complete
modification  of the four fixed covered tanks  and only minimal modification  of the two
tanks  which  have floating  covers. The four fixed covered tanks would  each  require the

                                        3-17

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\
  \
   \

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installation of  a mechanical mixer to maintain solids in suspension, including structural
modifications in order to support the mixers. A ventilation system would be required for
the covered tanks to ensure the safety of plant  personnel who may enter the tanks for
purposes of inspection or maintenance. Minor structural repairs and waterproofing of all six
tanks would  be necessary to ensure their structural integrity and watertightness. The two
floating covers would be removed and  the pipe gallery would be converted to  a pump
station.

The cost  for converting these units to equalization tanks is estimated at approximately
$440,000.  This cost includes process pumping equipment and piping,  four mechanical
mixers, tank ventilation system, instrumentation, electrical work, structural renovations and
alterations, and engineering fees.

At present, additional studies are under way to evaluate the feasibility of equalization of
tannery wastes at the tannery in lieu of equalizing these wastes at the plant site.

     3.5.3  Walled Lake — Novi, Michigan

The Walled Lake-Novi Wastewater Treatment Plant is a new 2.1 mgd facility employing
side-line flow equalization. The treatment plant was placed into operation in  1971. It was
designed to meet stringent effluent quality standards, including (1) a summertime monthly
average BOD2Q  of 8 mg/1, (2) a wintertime monthly average BOD2Q of 15 mg/1, and (3)
10 mg/1 of SS. The  facility  utilizes the activated sludge process followed by multimedia
tertiary filters. Ferrous chloride and  lime are added  ahead of aeration for phosphorus
removal. Sludge is processed by aerobic digestion, and dewatered on sludge drying beds. A
schematic diagram of this facility is shown on Figure 3-7.

A major factor in the decision to employ flow  equalization was the desire to load the
tertiary filters at  a  constant rate. The equalization facility consists of  a 315,000-gallon
concrete tank which is equivalent in volume to 15 percent of the design flow. The tank is
15 feet deep  and 60 feet  in diameter.  Aeration and  mixing are provided  by a diffused air
system with a capacity of 2  cfm/1,000 gallons of storage. Chlorination is provided for odor
control. A sludge scraper is installed to prevent consolidation of the sludge.

The equalization facility is operated as follows (11). The process pumping rate is preset on
the pump controller  to deliver the estimated average flow to the treatment processes. The
flow delivered by these pumps is monitored by a flowmeter which automatically adjusts the
speed of the pumps to maintain the average flow rate. When the raw wastewater flow to the
wet well exceeds the preset average, the wet well level rises, thereby actuating variable speed
equalization pumps which deliver the excess flow to the equalization basin. When the inflow
to the wet well is less than the average, the wet well level falls and an automatic equalization
basin effluent control valve opens. The valve releases enough wastewater to the wet well to
reestablish the average flow rate through the plant. Since this is a new plant as opposed to

                                       3-19

-------
                                                 FIGURE 3-7
                               WALLED LAKE-NOVI  WASTEWATER TREATMENT  PiLANT
co
N>
O
                            FLOW
                        EQUALIZATION
                           BASIN
FLUENT
	 »

1
t
WET
NELL
t
k
v^


4



PROCESS
PUMPS —
y^-EQUALIZAT
/^•^
^^^ FLOW
/ METERS
/
/ 	 '
i /.
G
ON PUMPS
r- FaCI2
| — LIME & POL
t
AERATION
,, ' ' „•
TANKS

fELEt

;TROLYTE
FINAL
CLARIFIERS
/-CHLORINE CONTACT (


/




MULTI-
MEDIA
FILTERS
DMMINUTOR AND AERATED
RIT CHAMBER
	 , 	 ^

                                                                                                  EFFLUENT
                                               FILTER BACKWASH

-------
 an upgraded plant, no comparative data exist. However, the treatment facility is typically
 producing a highly treated  effluent,  with BOD and SS less  than 4 mg/1 and 5 mg/1,
 respectively (9).

     3.5.4  Novi Interceptor Retention Basin, Oakland County, Michigan

 This case (12) illustrates the utilization of an equalization basin within the wastewater
 collection system.

 A portion of the wastewater collection system for the City of Novi, Michigan, discharges to
 the existing Wayne County Rouge Valley Interceptor System. Due to the existing connected
 load on the Wayne  County system, Novi's wastewater discharge to the interceptor system is
 limited to a maximum flow rate of 4 cfs. This rate was matched by the existing maximum
 diurnal flows from  the city. In order that additional population could be served, it was
 decided to equalize wastewater flows to the interceptor system. By discharging to  the
 interceptor continuously at an average rate of flow, the total wastewater flows from the
 City of Novi to the Wayne County Rouge Valley Interceptor system could be increased by a
 factor of 2.6.

An 87,000-cu ft concrete basin was constructed for  equalizing flows. The tank has a
 diameter  of 92 feet and a depth of 10.5 feet. Aeration  and mixing are provided by a
 diffused air system with a capacity to deliver 2 cfm/1,000 gallons of storage.

A manhole located  upstream of the equalization  basin intercepts the flow in the existing
Novi trunk sewer. The intercepted wastewater flows into  a weir structure which allows a
maximum of 4 cfs to discharge into the Wayne County system. The wastewater in excess of
the preset average overflows into a wet well where it is pumped to the equalization basin.
When flows in the interceptor fall below the preset average, a flow control meter generates a
signal  opening an  automatic valve  on  the effluent  line of the  basin, allowing  stored
wastewater to augment the flow.

 3.6  References

  1.  Click, C.N., The Feasibility of Flow Smoothing Stations in Municipal Sewage Systems.
     U. S. EPA Project No. 11010 FDI, Contract No. 14-12-935 (August, 1972).

  2.  LaGrega, M.D., and Keenan, J.D., Effects of Equalizing Sewage Flow. Presented at the
     45th Annual Conference of  the Water  Pollution Control Federation, Atlanta, Ga.
     (October, 1972).

  3.  Roe, F.C., Preaeration and Air  Flocculation.  Sewage Works  Journal, 23, No. 2, pp.
     127-140 (1951).
                                       3-21

-------
 4.  Seidel, H.F.,  and Baumann, E.R., Effect of Preaeration on the Primary Treatment of
    Sewage. JWPCF, 33, No. 4, pp. 339-355 (1961).

 5.  Boon, A.G., and Burgess, D.R., Effects of Diurnal Variations in Flow of Settled Sewage
    on the Performance of High Rate Activated-Sludge Plants. Water Pollution Control,
    pp. 493-522 (1972).

 6.  Ames,  Iowa: Private  communication with  Dr.  E. Robert Baumann,  Iowa  State
    University (December 11, 1973).

 7.  Bradley, P.R., and Oldshue, J.Y., The Role of Mixing in Equalization. Presented at the
    45th Annual Conference of the Water Pollution  Control  Federation, Atlanta,  Ga.
    (October, 1972).

 8.  Wallace, A.T., Analysis of Equalization Basins. Journal of the  Sanitary Engineering
    Division, ASCE, SA6, pp.  1161-1171 (1968).

 9.  Smith, J.M., Masse, A.N., and Feige, W.A., Upgrading Existing Wastewater Treatment
    Plants,  Technology Transfer Design Seminar.  Presented  at Vanderbilt University
    (September 18,1972).

10.  Smith, R.,  Eilers, R.G., and Hall, E.D., Design and Simulation of Equalization Basins.
    U.S. Environmental Protection Agency, Internal Publication (February, 1973).

11.  Johnson & Anderson,  Inc., Operation  and Maintenance  Manual for Wastewater
    Treatment  Plant, Walled  Lake Arm, Huron-Rouge Sewage Disposal System. Oakland
    County D.P.W., Oakland Co., Michigan (June, 1973).

12.  Johnson & Anderson, Inc., Operation and Maintenance Manual for Sewage Retention
    Reservoir,  Novi Trunk  Extension  No. 1,  Huron-Rouge  Sewage  Disposal System.
    Oakland County D.P.W., Oakland Co., Michigan (September, 1973).
                                      3-22

-------
                                     CHAPTER 4

           TECHNIQUES FOR UPGRADING TRICKLING FILTER PLANTS
4.1  General

In 1973 there were more than 3,500 trickling filter plants in the United States serving over
28 million  people.  In  contrast,  there  were approximately  3,750 activated sludge plants
serving 48 million people (1). In the past, the trickling filter plant has been considered the
ideal plant for populations of 2,500 to 10,000.

Several reasons have justified this popularity. One is its economy, not only in first cost, but
also  in operation; another is its relative simplicity of operation, which does not require as
highly skilled operators as activated sludge plants.

Although activated  sludge plants provide higher levels of treatment and greater operational
flexibility than  trickling filter plants, trickling filter plant performance was considered
adequate where stream assimilative  capacity was relatively large in relation  to population.
However, increased urbanization  and more stringent effluent and water quality standards
will require that many existing trickling filter plants be upgraded.

Upgrading of  a  trickling filter may  be required due  to hydraulic or organic overloading,
higher effluent quality requirements, or both. In general, decreasing hydraulic or organic
overloading in existing facilities  will not produce a significant increase in BOD and  SS
removals above the original  design values. However, the  effluent polishing techniques
discussed in Chapter 7 may provide enough additional treatment to obtain an effluent of the
desired quality.

4.2  Trickling Filter Processes

Trickling filtration  consists  of uniform distribution of wastewater over the trickling filter
media by a  flow distributor. A large portion of the wastewater applied to the filter passes
rapidly through  it, and the remainder trickles slowly over the surface of the biological slime
which forms. BOD removal  occurs by biosorption and coagulation from the rapidly moving
portion of the flow and by progressive removal of soluble constituents from the more slowly
moving portion of the flow.

The  quantity  of biological  slime produced  is controlled by the available  food,  and the
growth will increase as the organic load increases until a maximum thickness is reached. This
maximum growth is controlled by hydraulic rate, ventilation, type of media, type of organic
matter, amount of  essential nutrients present  and  the nature of the particular biological
growth.

                                        4-1

-------
In the past, trickling filters have been classified as either low- (standard), intermediate- or
high-rate filters, depending upon hydraulic and organic loading rates.

     4.2.1   L ow- Rate Trickling Filters

Low-rate  trickling  filters  are  designed  to handle  organic  loadings  of 5  to  20 Ib
BOD/day/1,000 cu ft, and hydraulic loadings of 1 to 4 mgd/acre. In general, low-rate filters
do  not  use  recirculation  to maintain  a  constant  hydraulic  loading, but  use either
suction-level controlled pumps or a dosing siphon. Dosing tanks are small, usually with only
a 2-minute  detention time based on  twice  the average design flow  so that intermittent
dosing  is minimized.  Even  so,  at  small  plants, low  night-time flows may result in
intermittent dosing. If the interval between  dosing is greater than  one or two hours, the
efficiency of the process will  deteriorate since the character of the biological slime will be
altered due to lack of moisture. Under normal conditions, the BOD removal efficiency of a
low-rate filter and secondary clarifier  may average 75 to 85 percent. By the addition of
recirculation  during periods of low flows to keep the filter wet, it is possible to  increase
overall plant efficiency (2).

Low-rate filters are normally constructed using a 5 to 10 foot depth of stone media. In  most
low-rate filters, only the top 2 to 4 feet of the filter media have appreciable biological slime.
As  a result, the  lower portions of the filter may be  populated by autotrophic nitrifying
bacteria  which  oxidize  ammonia nitrogen to  nitrite  and nitrate forms. If the nitrifying
population is  sufficiently  well  established,  and  if  climatic conditions and wastewater
characteristics  are favorable,  a well-operated low-rate  filter, in addition to providing  good
BOD removal, can produce a highly nitrified effluent. The benefits of well-nitrified effluents
for reduction of  total oxygen demand in receiving waters are being increasingly utilized in
the formulation of effluent standards.

     4.2.2  Intermediate-Rate Trickling Filters

Intermediate-rate trickling filters are generally designed to treat hydraulic loadings of 4 to
10 mgd/acre, including recirculation, and organic loadings, excluding recirculation,  range
from 15 to 30 Ib BOD/day/1,000 cu ft. In the past, there have  been some cases where the
organic loading in the intermediate  range stimulated  considerable biological filter growth
and the rate of  hydraulic loading was not sufficient to  eliminate clogging of the  trickling
filter media (2). This clogging situation can be remedied somewhat by utilizing relatively
large stone, 3  to 4 inches in diameter. However, many  plants operate in the intermediate
loading range without reported  operational  problems (2) (3). In practice, many high-rate
filters will operate in the intermediate range  during the  early low-flow period  of  their
operating lifetime.
                                          4-2

-------
     4.2.3  High-Rate Trickling Filters

High-rate trickling  filters have   hydraulic  loadings of  10  to  30 mgd/acre,  including
recirculation,  and  organic loadings of  30  to 60  Ib BOD/day/1,000  cu ft,   excluding
recirculation. Media depths of 3 to 6 feet are commonly employed. In all high-rate filters,
recirculation is used to maintain a relatively constant hydraulic loading. The higher organic
loadings in  high-rate filters preclude the development of nitrifying bacteria in the lower
section of the filter.  Hence,  these plants will seldom  exhibit any  nitrification,  and will
generally not perform as well as low-rate filters.

     4.2.4  Super-Rate Trickling Filters

Super-rate trickling  filters have evolved as a  result of the development of various types of
synthetic media.  Past experience has indicated that hydraulic loadings of 150 mgd/acre and
higher, including recirculation, may be  accommodated  in super-rate trickling filters. The
major  application of super-rate filters has been for high-strength wastes and  as roughing
units.  Synthetic  media  filters, because  of their  high surface  area  per unit volume, can
perform as well as high-rate filters at volumetric BOD loadings of about 50 to 100 lb/1,000
cu ft,  and  hydraulic  loadings of  0.5  to 1.5 gpm/sq ft. A  discussion of synthetic media
characteristics is presented in Section 4.4.4.

     4.2.5  Trickling Filter Performance Data

Performance data for a number of trickling filters under various operating conditions are
presented in Table 4-1. These  data  emphasize the  wide range of effluent quality that can be
expected depending upon design and operating conditions.

4.3  Trickling Filter Design Considerations

Trickling filters traditionally  have  been  designed  using one of several equations developed
over the years from trickling filter plant operating data. The equations incorporate different
combinations   of  the  many variables that  most  affect   trickling  filter  efficiency.
Unfortunately, no equation has yet been  developed which reflects the actual performance of
filters,  due  to the  complex  interrelationship  of  the many variables involved. Since it is
difficult to  accurately  predict trickling filter performance based on these equations, they
have limited utility in trickling filter plant design. Wherever possible, it is recommended that
treatability  or pilot  plant studies be used to  verify performance predictions based upon the
various design equations.

     4.3.1  Trickling Filter Design Equations

The  trickling filter  design equations which are in general use  are those published by the
National Research Council (8), Ten-State Standards (9), Velz (10), Caller and  Gotaas (1.1)

                                         4-3

-------
                                                   TABLE 4-1
                          OPERATING DATA FOR SINGLE-STAGE TRICKLING FILTER PLANTS
                                AT LOW, INTERMEDIATE, AND HIGH LOADING RATES
     Plant Location
Low-Rate
  Aurora, Illinois
  Dayton, Ohio
  Durham, N. Carolina
  Madison, Wisconsin
  Richardson, Texas

Intermediate-Rate
  Plainfield, New Jersey
  Great Neck, New York

High-Rate
  Oklahoma City, Oklahoma
  Freemont, Ohio
  Storm Lake, Iowa
  Richland, Washington
  Alisal, California
  Chapel Hill, N. Carolina


Influent
Flow
mgd
7.8
34.4
1.8
4.8
1.5
4.3
0.5
16.2
1.8
7.4
2.2
0.6
1.4

Filter
Media
Depth
ft
6
7.5
7
10
6.5
6
4
6
3.3
8
4.5
3.2
4.25

Plant
Influent
BOD
mg/1
117
227
375
248
166
629
187
463
134
690
173
293
166

Recircu-
lation
Ratio

0
0
0
0
0
0.6
1.0
1.0
1.5
2.1
2.8
3.1
2.0


Hydraulic
Loading
mgd/acre
2.1
3.5
1.9
2.4
3.9
2.4
7.8
16.3
19.0
21.5
19.6
20.8
16.3


Organic
Loading
Ib BOD/
day/
l,000cu
4.4
12
13
6.4
13.31
25
20
78
41
62
44
53
19

Final
Effluent
BOD
mg/1
ft
14
33
68
33
20
13
20
66
21
61
20
24
44
Filter and
Final
Clarifier
BOD Removal
percent
80
76
74
76
83
83
83
78
78
84
83
87
43



Reference

4
4
4
4
5
4
6
6
6
6
6
6
7
^Computed based on assumed 30 percent BOD removal in primary clarifiers.

-------
Schulze (12) and Eckenfelder (13) (14). The National Research Council, Velz, Eckenfelder,
and Galler and Gotaas equations are presented and discussed in the following sections.

         4.3.1.1   National Research Council (NRC) Equations

The  NRC formulation was  the result of an extensive analysis of operational records from
stone-media trickling filter plants serving military installations. Based on data analyses, the
NRC recommended the following equations for predicting the performance of stone-media
trickling filters:

           First or Single Stage:

                    v    _             100
                           1 + 0.0085 VVF )

           Second Stage:

                    E2  = 	10Q_
                           l + 0.0085
                                 I-EI

               where:

                    EI  - Percent BOD removal efficiency through the first-stage
                           filter and clarifier
                    W   = BOD loading (Ib/day) to the first or single-stage
                           filter, not including recycle
                    V    = Volume of the particular filter stage in acre-feet
                    F    = Recirculation factor for a particular stage, (1 + R)/(l + 0.1R)2
                           R = Recirculation ratio = recirculated flow/plant
                           influent flow
                    E2  - Percent BOD removal efficiency through the second-stage
                           filter and clarifier
                    W   = BOD loading (Ib/day) to the second-stage
                           filter, not including recycle


Some of the limitations of the NRC equations are:

     1.   Military wastewater is characteristically more concentrated than average domestic
         wastewaters. Consequently, higher percentage  removal efficiencies  per unit of
         volume were easier to obtain.
                                        4-5

-------
     2.    The effect of temperature on trickling filter performance is not considered.

     3.    NRG equations indicate that organic  loading  has  a greater influence  on filter
          efficiency than hydraulic loading. This is probably because of the concentrated
          nature of the wastewaters.

     4.    Applicability is limited to concentrated domestic wastewaters because no factor is
          included to account for differing treatability rates.

     5.    The equation for second-stage filters is based on the existence of intermediate
          clarifiers following the first-stage filters.

A comparative plot of trickling filter operating data with the predicted value using the first
or single-stage NRG equation is shown on Figure 4-1. It is evident from Figure 4-1 that the
use of the NRG equation may result in substantial deviation from the actual performance of
a trickling filter.

          4.3.1.2   Velz Equation

In  1948,  Velz proposed the  first major formulation delineating  a  fundamental  law as
contrasted to previous attempts based on data analysis. The Velz equation relates the BOD
remaining at depth D as follows:

          LD
          -^ =io-KD
           L

     where:

          L   =  Total removable BOD, mg/1
          Lj) =  Removable BOD at depth D, mg/1
          D   =  Filter depth, feet
          K   =  Constant

Removable BOD in the Velz equation is defined as the maximum fraction of applied BOD
removed at a specific hydraulic loading range. When recirculation is  used, the total applied
BOD, La after dilution by recirculation, R, may be determined as follows:
          La   =
                          Li + RLe
                           1 + R
      where:
               =  Total influent BOD, not including recirculation, mg/1
               =  Total effluent BOD, mg/1
                                           4-6

-------
                                FIGURE 4-1

COMPARISON OF TRICKLING FILTER  OPERATING DATA WITH  NRC  EQUATION
     100
      80
     60
      40
      20
                                         LEGEND
    • BETHLEHEM,  PA    (15)
    • BURGESS,  El AL   (16)
    •DEEDS &  DATA     (17)
    DHOMACK          (18)
    A McCABE &  ECKENFELDER (19)
    AGALLER &  GOTAAS      (in
    o NATIONAL  RESEARCH COUNCIL (7)
                       2000
4000
                                  LB BOD/DAY
                                  EQUIVALENT ACRE-FT
6000
               (A)
8000
                                    4-7

-------
         4.3.1.3   Eckenfelder Equation

Eckenfelder expanded  the  Velz equation  to include other factors.  Schulze (12) had
postulated that the time of liquid contact with the biological slime is directly proportional
to the filter depth and inversely proportional to the hydraulic loading rate. Combining the
time of contact with Velz's first order equation for BOD removal and including the effect of
changes in  filter depth  on the BOD removal per unit of depth, Eckenfelder proposed the
following equation:

         Le  =    	  *
                      0 K n 0-67
          La       1 + 2-5 D
                      Qx0.5
         La  = Influent BOD (including recirculation), mg/1
         Le  = BOD of unsettled filter effluent, mg/1
         With A in acres, D in feet and Q in mgd

         4.3.1.4   Galler and Gotaas Equation

In 1964, the last major effort to forecast the performance of stone filters was attempted by
Galler and Gotaas (11) using multiple regression analysis of data from existing plants.

Based on regression analysis, the following equation was developed:

          Le  =        K(iLj + rLe)l-19
                   (i + r) 0.78 (1 + D) 0.67 a 0.25

     where:

                    0.464 ( 43-560 \
          K        '
                    • 0.28   T0.15

          Le  = Unsettled filter effluent BOD, mg/1
          Lj   = Filter influent BOD, mg/1
          D   - Filter depth, feet
          i    = Influent flow, mgd
          r    = Recirculation flow, mgd
          a    ~ Filter radius, feet.
          T   = Wastewater temperature, deg C
                                          4-8

-------
 The Caller and Gotaas equation recognized the effects of recirculation, hydraulic loading,
 filter  depth,  and  wastewater temperature as  being important  in understanding  the
 performance of  a trickling filter.  They further indicated that recirculation improves the
 performance  of  a  filter, but established  a  4:1 ratio  as a practical  upper  limit for
 recirculation.

     4.3.2  Applicability of Various Trickling Filter Design Equations

 The design engineer has available several  equations  for  trickling  filter  designs, and the
 decision to use one in preference  to  another is often difficult. The availability of several
 equations often raises doubts concerning their validity.

 An attempt has  been made by Hanumanulu (20) to compare the actual performance of a
 12-foot  deep  stone  media trickling  filter  with that predicted using  NRG, Ten-States
 Standards, Velz,  Eckenfelder, and Galler and Gotaas equations. The filter was operated at a
 constant flow without recycle as well as with a 1:1 recirculation ratio. It was found that the
 Velz, Ten-States  Standards and the NRG  equations predicted filter efficiencies that are
 closer to observed values when operated without recycle, while the Eckenfelder and Galler
 and Gotaas equations predicted efficiencies closer to observed values for filters operated
 with recirculation. However, because the filter studied was about double the depth of most
 filters, the conclusions may have differed from  those that would have been observed with a
 shallow filter.

 Ordon  (21) calculated  the  volume of filter  media required to  achieve specified BOD
 removals using the NRG, Eckenfelder, and Galler and Gotaas  equations. The wastewater
 flow, BOD, and temperature were assumed  as 1 mgd,  100 mg/1, and 20 deg C, respectively.
 The trickling filter volume calculated by the  different equations is shown in Table 4-2.

 Inspection of Table 4-2 indicates characteristic trends which the designer should be aware of
 before  using  any of  these  equations. When recirculation  was zero, the  filter volumes
 calculated  from the NRG and Eckenfelder  equations were essentially the same, while the
 Galler and Gotaas equation gave volumes which  were significantly different. However, when
 recirculation was  considered,  the NRG design volumes were generally quite conservative,
 while the volumes calculated  by Eckenfelder and Galler and Gotaas equations were more
 nearly the  same. In general, the NRG equations would seem  to apply when recirculation is
 not considered, when seasonal temperature differentials are minor, and when the wastewater
 load is highly variable and of high strength.

     4.3.3   Laboratory and Pilot-Plant Treatability Studies

As previously indicated,  treatabiHty or pilot-plant studies are advantageous in verifying the
performance predicted by  design equations. The  use  of treatability studies for design  of
trickling filters has been limited due to the lack of suitable laboratory-scale testing methods,

                                          4-9

-------
                                                 TABLE 4-2
                                     TRICKLING FILTER VOLUMES FOR
                              VARIOUS ORGANIC REMOVALS AS CALCULATED
                                     BY DIFFERENT DESIGN EQUATIONS
                               (ALL VOLUMES IN THOUSANDS OF CUBIC FEET)
 Recirculation  50% BOD Removal
60% BOD Removal
70% BOD Removal
75% BOD Removal
80% BOD Removal
90% BOD Removal
Ratio
0
1
2
3
4
5
6
NRC1
2.7
1.7
1.4
1.2
1.0
0.9
_
ECK2
3.8
0.96
0.42
0.24
0.15
0.12
0.08
G&G3
0.2
0.12
0.12
0.12
0.12
0.12
0.12
NRC
6
3.6
2.8
2.6
2.4
2.2
_
ECK
8.5
2.2
0.95
0.55
0.35
0.24
0.17
G&G
1.2
0.28
0.26
0.26
0.26
0.26
0.26
NRC
15
8.8
6.8
6.1
5.8
5.7
_
ECK
20
5
2.3
1.3
0.8
0.6
0.4
G&G
10
1.8
1.2
0.9
0.9
0.9
0-9
NRC
23
15
11
9.9
9.3
8.8
—
ECK
32
8
3.5
2
1.5
0.92
0.67
G&G
42
5
2.4
1.8
1.6
1.5
1.5
NRC
40
25
20
18
17
16
_
ECK
58
15
7
4
2.5
1.8
1.4
G&G
300
23
7.3
4.3
3.6
3.0
—
NRC
210
130
105
90
85
80
_
ECK
290
75
35
20
14
9
6
G&G

—
400
170
80
45
—
     - National Research Council.
 2ECK - Eckenfelder.
 3G&G - Caller and Gotaas.

Design Conditions:
 Filter Influent Flow     I mgd
 Filter Influent BOD     100 mg/1
 Wastewater Temperature 20 deg C

-------
and has generally been restricted to synthetic media. Pilot units can be rented from the
media  manufacturers but will require  considerable manpower and  funds to obtain the
meaningful  data needed for  design  purposes. Treatability  studies  for evaluation  of
stone-media filter design parameters have not been commonly performed.

However,  advances  are  being made in the development of  a  practical  laboratory-scale
piloting facility for both stone and plastic media. Based on the concept of contact time as
introduced by Schulze, the trickling filter  process may be modeled by using an inclined
plane to support biological growth (22).

Wastewater  is introduced at a variable rate to the top  of the slimed inclined plane. The
plane's inclination  may  be  varied  to  change the  contact  time. As previously discussed,
Schulze's equation relates the contact time to the depth and hydraulic loading, as well as to
the physical characteristics of the filter media. BOD removal is then assumed to vary with
the following first-order removal equation:

          L^  = e-Kt
          Li

     where:

          Le  = BOD of unsettled filter effluent, mg/1
          LJ  = BOD of filter influent, mg/1
          K   = Treatability constant
          t    = Contact time, minutes

The inclined plane method furnishes data on BOD removal, contact time, hydraulic loading
and recirculation ratios.

Since the basic purpose of either a laboratory or pilot-plant evaluation is to study variables
that affect filter performance, any treatability  study should  be of sufficient duration to
adequately describe the following variables as they affect the filter performance:

     1.   Applied BOD loading

     2.    Hydraulic loading

     3.   Recirculation

     4.   Wastewater temperature.
                                         4-11

-------
The data thus obtained from treatability studies can be evaluated using the various trickling
filter equations previously discussed.

4.4  Trickling Filter Upgrading Considerations

The performance of a trickling filter plant is determined by the complex interrelationship of
numerous  variables. Thus, in any upgrading  situation,  the acquisition and analysis of
year-round performance data are essential in determining the additional treatment facilities
needed to  meet more stringent effluent requirements. In addition to those variables that
directly  affect  performance  of the trickling filter itself, the performance of the plant as a
whole  also depends on proper integration of the filter with the other unit processes being
utilized. The more important variables  to be considered prior to upgrading any trickling
filter plant are discussed in the following sections.

     4.4.1   Wastewater Characteristics

Municipal wastewaters vary in composition and strength, depending on the relative amounts
of industrial wastewater and infiltration present. The rate of BOD removal from a domestic
wastewater in a trickling filter generally exceeds the BOD removal rate from an  industrial
wastewater which has a high percentage of dissolved BOD. This is due to the high percentage
of colloids in domestic wastewater, and  to the increased ability of the filter to remove this
colloidal material.  A reasonable explanation for this is that some of these materials are
removed by biological flocculation and not by oxidation and synthesis of new cells.

A trickling filter plant that  requires upgrading due to industrial loads in excess of those
anticipated in the design may be improved by equalization of the industrial flows. Often this
is most economically accomplished at the industrial source and is particularly advantageous
when the entire industrial load  is  discharged  in an  8-  or 16-hour  period. Under other
conditions, equalization facilities at the  treatment  plant may be provided  as discussed in
Chapter 3 to reduce peak loadings on the trickling filter.

     4.4.2   Recirculation

The practice of effluent recirculation can be used to improve the efficiency and operation of
some stone-media trickling filters. For example, it can minimize the operational  problems
associated with intermittent dosing of low-rate trickling filters. Recirculation ratios of 0.5 to
4.0 have been used in  high-rate filters;  Caller and  Gotaas (11) have demonstrated that a
recirculation ratio of greater than  4.0 does  not materially increase plant efficiency and is
also uneconomical.  Normal design practice is to use ratios of 1.0 to 2.0.

Recirculation as applied to synthetic media involves a somewhat different concept than is
applied to stone filters.  Various  types  of synthetic filter media  have higher minimum
wetting rates,  i.e.,  a  rate  of flow  per unit area which will  induce a biological slime

                                         4-12

-------
throughout the depth of the media. This minimum wetting rate typically ranges from 0.5 to
1.0 gpm/sq ft (30 to 60 mgd/acre), depending on the geometric configuration of the media.
Therefore, recirculation in  synthetic media filters is practiced to maintain the  desired
wetting  rate  for  a  particular  medium.  Generally,  increasing  the  hydraulic loading
substantially  above the  minimum wetting rate decreases the BOD removal through the filter
(23).

There are many possible flow configurations which  may be used with a single- or two-stage
high-rate trickling filter plant. Some  of the more common flow diagrams  which have been
presented in  the Water Pollution Control Federation  MOP No. 8, Sewage Treatment Plant
Design (3) are shown on Figure 4-2. Decisions regarding the use of any one of these flow
configurations in  a plant upgrading  must be based on its  suitability to the existing plant
facilities and  an examination of the relative economics.

The hydraulic capacity of  the trickling filter distribution  and underdrain systems also
requires  investigation where changes to the recirculation pattern are proposed. Significant
increases in recirculated flow may exceed  the capacity of the  distribution mechanism or
overload the filter media or underdrain conduits.

     4.4.3  Clarifier Capacity

When modifying an existing trickling filter plant, the effect of increased recirculation on
both  the primary and  final clarifiers must be  considered. Recycle schemes requiring  the
recycled flow to pass entirely  through  the  primary and/or  secondary  clarifiers exert
significantly higher load on these units than schemes  where the recycle passes through  the
filter  alone. Since studies have shown that direct recirculation of trickling filter effluent is as
effective as recycling clarified effluent (24), this is the preferred flow pattern where clarifier
loading is otherwise excessive. Recommended loadings for trickling filter clarifiers  are
presented in Chapter 6.

     4.4.4  Trickling Filter Media

The physical  properties of various types of trickling filter media are shown in Table 4-3.

The properties shown in Table 4-3 which are of greatest interest are specific surface area and
percent void space. Greater  surface area permits a larger mass of biological slimes per unit
volume,  while increased void space allows  for higher hydraulic  loadings and  enhanced
oxygen transfer.  The ability of synthetic media to  handle higher hydraulic and  organic
loadings is directly attributed  to  the higher  specific  surface area and void space of these
media compared to stone media and blast furnace slag.
                                         4-13

-------
                                 FIGURE  4-2
COMMON  FLOW DIAGRAMS  FOR  SINGLE AND  TWO-STAGE
                     HIGH-RATE  TRICKLING  FILTERS (2)
                                       SINGLE-STAGE









1




'
s

mums

1
±_
J




1







;$$^^-
•^^
\
_*
i







                  SLUOSE «ET»««

                  RECIRCULATED FLOW

                  PRIMARY CLARIFIER
                           NOTE  'RCPRINIED IITH PERIISSION FROII '  SEIAGE TREATAEIT PLIBT DESICN
                                 HAHUAL OF PRADTIVE NO B IA7ER POLL, COKIBOL FE«E«»TH«
                                 IASHIICTOI, 0 C IAKIIAL OF ENC PDACTICE »0 36. AMER SOC
                                 CIVIL ENGR , NEW YORK H Y (1950)
CZ3
 / N    TRICMING FILTER
                  IHTEIIEDIATE CLIRIFIER


                  FINAL CLARIFIER
                                        4-14

-------
                                    TABLE 4-3
      COMPARATIVE PHYSICAL PROPERTIES OF TRICKLING FILTER MEDIA
       Media
Plastic
Redwood
Granite
Granite
Blast Furnace Slag
    Nominal
     Size
       in.
24 x 24 x 48
47% x 47'/2 x 35%
1-3
4
2-3
Units
per
cuft

2-3
—
—
—
50-60

Unit
Weight
Ib/cu ft
2-6
10.3
90
—
68
Specific
Surface
Area
sq ft/cu ft
25-35
14
19
13
20


Void Space
percent
94-97
76
46
60
49
An important consideration in any upgrading involving increased recirculation is the effect
of the resulting increased flow through the filter media. In some cases, replacement of an
existing filter media with a  media having greater void  space may be required to avoid
ponding due to the higher hydraulic loadings and increased biological growths.

     4.4.5   Trickling Filter Depth

Low-rate trickling filters have traditionally been designed with  depths ranging from 5 to
10 feet. Because the rate of biological activity is greatest at the surface  of a stone-media
trickling filter and diminishes with depth, high-rate stone media filters are designed with
shallower depths of 3 to 6 feet to maximize the rates of treatment per unit volume of filter
media.

As previously mentioned, nitrifying bacteria residing in the lower portions of the relatively
deep low-rate filters can produce a highly nitrified effluent, while high-rate filters seldom
exhibit significant nitrification because of high volumetric BOD loadings. The high loadings
favor the  growth  of  heterotrophic  carbonaceous organisms  rather than  autotrophic
nitrifying organisms.

Recommended  depths for synthetic  media  are  15 to 30 feet.  This is because optimum
synthetic media hydraulic wetting rates permit  smaller diameter units to be used. Thus,
increased depth is required to  provide adequate contact time with the wastewater. The low
unit weight of  synthetic media enhances the construction of much  deeper filters than is
feasible with stone media.
                                         4-15

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     4.4.6   Ventilation

Proper ventilation of trickling filters is essential to the maintenance of aerobic conditions
throughout the filter media. It is recommended that all drains, channels, and pipes be sized
such that not more than 50 percent of their cross-sectional area will be submerged at the
peak hydraulic loading.

If the  trickling filter is constructed on or near grade, provision  for ventilation will be less
critical than  if the topography necessitates  construction well below grade. In these latter
instances, forced ventilation or ventilation shafts may be necessary.

     4.4.7   Temperature of Applied Wastewater

The efficiency  of  trickling  filters  is affected by wastewater temperature changes  in
accordance with the following relationship (25) (26):

         ET  =  E20 e T-20

  where:
          9    -  Constant varying from 1.035 to 1.041
          ET  =  Filter efficiency at temperature, T
          E20 =  Filter efficiency at 20 deg C
          T    =  Wastewater temperature, deg C
In northern regions, the effect of both air and wastewater temperatures on trickling filter
performance is very evident, and significant deterioration of the plant performance can be
expected  during the  winter months (27). The effect of  air temperature  is especially
pronounced  in  high-rate  filters due to  the cooling effect of recirculation, and therefore
should be taken into consideration wherever an upgrading involves significant changes in the
recirculation pattern. It has been reported that covering of filters in cold climates does not
substantially increase  the performance  because the filter covering does not increase the
temperature of the applied wastewater (28).

     4.4.8  Sludge Handling

Upgrading secondary treatment facilities usually results in an increase in sludge production.
Prior to any trickling filter upgrading, therefore, a thorough evaluation of the effects of the
upgrading on the sludge processing system should be made and the results incorporated into
the overall plant upgrading plan. Sludge production increases may be particularly significant
where chemical precipitation in the secondary clarifiers is practiced.
                                         4-16

-------
Humus sludge from trickling filters is commonly returned to the primary clarifier, often as
part of the recirculation pattern. Conservative primary clarifier overflow rates must be used
in such cases. Where primary tank overflow rates are excessive, separate gravity thickening
of combined primary and humus sludge can be employed.

Although  sludge processing modifications and/or expansions may be costly, an efficient
sludge  handling  system   is  crucial  to  good  treatment  plant  operation.  Upgrading
considerations for sludge processing facilities are  discussed in detail in Chapters 10 through
12.

4.5  Trickling Filter Upgrading Techniques and Design Basis

Upgrading to relieve overloaded  conditions, to improve organic removal efficiency, to
provide nitrification, and to remove nutrients  is covered in the following sections.  The
choice  between  the available options will depend  on such  factors  as plant  hydraulics,
conditions of existing treatment facilities and future effluent  requirements. The  final
selection should maximize the utilization of available clarifiers and minimize modifications
in process piping and additional pumping.

     4.5.1   Upgrading to Relieve  Organic and Hydraulic Overloading

Trickling filter plants may  be  upgraded to relieve hydraulic and/or organic overloading by
any one of the following three general procedures:

     1.   Upgrading existing single-stage filters by the construction of additional trickling
          filters in  parallel with existing units, or by conversion of a low-rate filter to high
          rate

     2.   Upgrading single-stage trickling filters  to  a two-stage biological system by the
          addition of second-stage trickling filters or an activated sludge system

     3.   Upgrading existing two-stage trickling filters to a multiple-stage biological system.

Upgrading  of single-stage filters by the construction of parallel single-stage units or by
conversion to high-rate filters  is a straightforward procedure and is not discussed in detail
since all of the factors involved have been covered previously. It is emphasized that before a
decision is made to adopt this procedure, a careful analysis of plant performance  data
should be made to determine if effluent criteria can be met.
                                         4-17

-------
         4.5.1.1   Upgrading  a  Single-Stage  Low-Rate  Trickling Filter  by  Improving
                   Distribution

Upgrading  an organically overloaded and hydraulically underloaded single-stage  low-rate
trickling filter may be accomplished  by providing recirculation. This upgrading procedure
was used to improve the wastewater treatment plant performance at Pueblo, Colorado (29).

The  original  secondary treatment facilities consisted of low-rate rock-media trickling filter
and final clarifier units as shown on Figure 4-3. At the time of design it was determined that
a 3-foot filter  depth, without recirculation, would  provide adequate treatment  to meet
Colorado State  Health Department regulations prohibiting a BOD discharge in excess of
30 mg/1. Table 4-4 shows operating data for the plant. It is apparent from these data that
the trickling filters were  not operating as well as had  been expected. Hydraulic loading was
inadequate to keep the  distributor arms  moving during periods of low flow. As  a result,
sufficient filter growth could not be maintained throughout the media to adequately treat
the relatively high organic loads, especially during the cold weather months when reduced
biological activity and freezing occurred. The shallow depth of the filter media aggravated
these problems.

The  plant was upgraded in 1967 to include recirculation facilities having a capacity  of about
30 percent of the average daily flow. A flow diagram of the upgraded plant is also shown on
Figure 4-3. Recirculation during periods  of low flow provided the necessary flow to keep
the  distributors revolving and thus prevented loss of the filter growth. The benefits of
recirculation  were particularly  evident in the summer months when the process  was not
adversely affected by low wastewater temperature. Operating data for the upgraded plant
are shown in Table 4-4. Despite  an  increase of more  than 80 percent  in  filter organic
loading, effluent BOD was slightly improved.

The  construction costs for this upgrading were estimated to be $129,000 and were allocated
as follows:

         Recirculation pumps, motors and controls           $ 61,000
         Piping and valves                                    68,000
              Total                                        $129,000

          4.5.1.2   Upgrading a Single-Stage Trickling Filter to a Two-Stage Filter  System

Upgrading an organically overloaded single-stage trickling filter may be  accomplished by
conversion to a two-stage filtration system. The objective of a pilot-plant study conducted
at the Chapel Hill, N. C., treatment plant in May-July, 1972, was to determine the degree of
improvement that could  be obtained by such a conversion (30).
                                         4-18

-------
                         FIGURE 4-3

   UPGRADING A SINGLE-STAGE LOW-RATE TRICKLING FILTER
                 BY IMPROVING DISTRIBUTION
PRIMARY EFFLUENT
14.6 MGD
SECONDARY
CLARIFIER
                                                            EFFLUENT
                                         SLUDGE
               TREATMENT  SYSTEM BEFORE  UPGRADING
PRIMARY EFFLUENT
12,8 MGD 	IT—*
                               EXISTING
                               SECONDARY
                               CLARIFIER
                                SLUDGE
             RECIRCULATION 3.75  MGD
          TREATMENT SYSTEM  AFTER UPGRADING
                                                  NEW RECIRCULATION
                                                  PUMPING STATION
                EFFLUENT
                             4-19

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                                    TABLE 4-4
                   OPERATING DATA FOR PUEBLO, COLORADO
                                                   Average
                                                  Operating
                                                  Condition
                                                  (1959-66)
                Description

Flow, mgd
Influent BOD, mg/1
Influent SS, mgA

Primary Clarifier
  Overflow Rate, gpd/sq ft
  BOD Removal, percent
  SS Removal, percent

Trickling Filter
  Depth, ft
  Hydraulic Loading, mgd/acrel
  Organic Loading, Ib BOD/day/1,000 cu ft1
  Recirculation Ratio

Secondary Clarifier
  Overflow Rate, gpd/sq ftl
  BOD Removal, percent
  SS Removal, percent
Overall Plant Performance
  BOD  Removal, percent
  SS Removal, percent
  Effluent BOD, mg/1
  Effluent SS, mg/1

1 Includes recirculation.
The single- versus two-stage studies were conducted using two pilot rock-media trickling
filter systems operated as shown on Figure 4-4. During the tests, the influent flow to the
single-stage unit was maintained at 1.2 gpm while the two-stage influent flow rate was set at
2.4 gpm. These rates of flow were established so that performance could be compared for
both a single-stage system where the plant influent is split into equal portions for treatment
through the filters in  parallel,  and a two-stage system where the entire plant flow passes
through the two filters in series. In the two-stage sequence, the entire influent flow was
                                                     14.6
                                                    148
                                                    163

                                                    400
                                                     47
                                                     49

                                                       3
                                                       9.4
                                                     42
                                                       0

                                                    775
                                                     50
                                                     70

                                                     74
                                                     82
                                                     39
                                                     29
Upgraded
Operating
Condition
 (1972)

   12.8
  273
  322

  350
   50
   49
    10.7
    77
     0.3

  880
    73
    75

    86
    88
    37
    40
                                       4-20

-------
treated through one primary tank, then through one filter with recirculation to the head of
primary. Effluent from  the first-stage filter was then passed through the other primary
clarifier, now serving as an intermediate clarifier. The partially treated flow was then fed to
the second-stage filter with recirculation directly around the filter. Lastly, second stage filter
effluent was split evenly between the two final clarifiers. The  operating data  given in
Table 4-5 show that 87 percent of the BOD and 93 percent of the SS were removed by the
two-stage system. These were better reductions than the 80 percent BOD and 85  percent SS
removals obtained with single-stage treatment.

         4.5.1.3   Upgrading  a Single-Stage Trickling  Filter to a Two-Stage Biological
                   Filtration/Activated  Sludge System

If the hydraulic and organic loads to a high-rate trickling filter unit are such that  it does not
produce the desired effluent BOD  quality, it is possible to upgrade  the facility by  the
addition of an activated sludge unit immediately downstream from the existing filters. In
this  situation,  the  existing  trickling  filter  acts as a roughing  filter, and the subsequent
activated sludge unit provides the treatment capacity needed to  obtain the desired BOD
removal.

Alterations  made on the  Kankakee, Illinois, treatment plant beginning in  1968 exemplify
this  type of upgrading (31). The flow diagram of the plant before upgrading appears on
Figure 4-5,  and operating data  for  the  year preceding  the upgrading are summarized in
Table 4-6. The  plant was upgraded by conversion of the existing trickling filters to roughing
filters, addition of a conventional activated  sludge system with expanded sludge processing
facilities, and modification  as necessary to  the existing piping. The flow  diagram for the
upgraded plant appears on Figure 4-5,  and operating data for a year after the upgrading are
given in Table 4-6. Implementation of this upgrading procedure  improved the overall plant
performance by increasing the BOD removal from 67 to 98 percent and  the SS removal
from 73 to  99 percent. Details concerning the design  of  an activated sludge system treating
an effluent from a single-stage biological treatment process are presented in Chapter 5.

The  construction costs for  this  plant  modification were estimated  to  be $3,468,000 and
were allocated as follows:

         Materials and earthwork                           $1,905,000
         Piping and mechanical                                384,000
         Equipment                                          922,000
         Electrical                                            257,000
              Total                                        $3,468,000
                                         4-21

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                              FIGURE 4-4
               MODIFYING A SINGLE-STAGE TRICKLING FILTER
                    TO  A TWO-STAGE FILTRATION  SYSTEM
   INFLUENT
   1 2 GPM
                     RECIRCULATION 2  4  GPM
       PRIMARY
       CLARIFIER
                            TRICKLING
                            FILTER
                                                    RECIRCULATION PUMP
                                                      EFFLUENT
FINAL
CLARIFIER
                   TREATMENT SYSTEM  PERFORMING AS
                SINGLE-STAGE TRICKLING FILTER SYSTEM
                    (ONE  OF TWO  DUPLICATE  TRAINS)
    1ST STAGE RECIRCULATION  2.4 GPM
INFLUENT
2.4  GPM
                                         RECIRCULATION PUMPS-
                           2ND STAGE RECIRCULATION 2,4  GPM
PRIMARY
CLARIFIER
                                                        EFFLUENT
                      1ST STAGE  INTERMEDIATE  2ND STAGE    FINAL
                                             TRICKLING    CLARIFIERS
                                             FILTER       (TWO)
           TRICKLING  SETTLING
           FILTER     (CONVERTED
                                PRIMARY
                                CLARIFIER)


                     TREATMENT SYSTEM  MODIFIED TO
                   TWO-STAGE TRICKLING FILTER SYSTEM
                                   4-22

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                                   TABLE 4-5
            OPERATING DATA FOR CHAPEL HILL, NORTH CAROLINA

                                                 Single-Stage        Two-Stage
                                                 Operating         Operating
                Description                       Conditions         Conditions

Flow, gpm                                             1.2               2.4
Influent BOD, mg/1                                  179               179
Influent SS, mg/1                                    247               247

Primary Clarifier
  Overflow Rate, gpd/sq ft                            470               628
  BOD Removal, percent                              35                30

Trickling Filter - 1st Stage
  Depth, ft                                            4.25              4.25
  Hydraulic Loading, mgd/acrel                        18.0              23.9
  Organic Loading, Ib BOD/day/1,000 cu ft1             34.4              73.5
  Recirculation Ratio                                   2.0               1.0

Final or Intermediate Clarifier
  Overflow Rate, gpd/sq ftl                           436               314
  BOD  Removal - 1st Stage Filter and Clarifier, percent    69                59

Trickling Filter - 2nd Stage
  Depth, ft                                           -                 4.25
  Hydraulic Loading, mgd/acrel                         —                23.9
  Organic Loading, Ib BOD/day/1,000 cu ft1              -                29.8
  Recirculation Ratio                                  —                 1.0

Final Clarifier
  Overflow Rate, gpd/sq ft                              -               436
  BOD  Removal - 2nd Stage Filter and Clarifier, percent    ~                55
  SS Removal - 2nd Stage Filter and Clarifier, percent      -                44
Overall Plant Performance
  BOD Removal, percent                              80                87
  SS Removal, percent                                85                93
  Effluent BOD, mg/1                                 36                23
  Effluent SS, mg/1                                   36                18

1 Includes recirculation.
                                    4-23

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                                FIGURE  4-5
               UPGRADING A SINGLE STAGE TRICKLING  FILTER
 TO A TWO-STAGE BIOLOGICAL FILTRATION/ACTIVATED  SLUDGE SYSTEM
 INFLUENT
 8  1 MGD
        PRIMARY       TRICKLING     FINAL
        CLARIFIERS      FILTERS      CLARIFIERS
                PUMP
                       1
            SLUDGE
                         SETTLED FINAL SLUDGE
                                                  EFFLUENT
                TREATMENT  SYSTEM  BEFORE UPGRADING
INFLUENT
6,9  MGD
                               INTERMEDIATE
                               CLARIF1ERS-
PRIMARY     TRICKLING
CLARIFIERS  FILTERS
        PUMP
                                            AERATION   FINAL
                                            TANKS      CLARIFIERS
                   SLUDGE
/

1
fc-
A
SLUDGE
k







A
RETURN SLUDGE ~p
                                                      EFFLUENT
                                              .4 MGD
                                                            SLUDGE
                                                            PUMP
                                                         I
                                                         I  WASTE
                                                        + SLUDGE
                    TREATMENT  SYSTEM AFTER  UPGRADING
                                   4-24

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                                   TABLE 4-6
                 OPERATING DATA FOR KANKAKEE, ILLINOIS

                                                 Year Before       Year After
               Description                        Upgrading         Upgrading

Flow, mgd                                              8.1              6.9
Influent BOD, mg/1                                    292             313
Influent SS, mg/1                                      280             332

Primary Clarifier
  Overflow Rate, gpd/sq ft                             700             600
  BOD Removal, percent                                21              47
  SS Removal, percent                                  30              54

Trickling Filter
  Depth, ft                                             6.4              6.4
  Hydraulic Loading, mgd/acre                           13.3             11.3
  Organic Loading, Ib BOD/day/1,000 cu ft                93.4             56.9
  BOD Removal, percent                                28              27

Final (or Intermediate) Clarifier
  Overflow Rate, gpd/ft                              1,050             900
  BOD Removal - 1st Stage Filter and Clarifier, percent      43              80
  SS Removal - 1st Stage Filter and Clarifier, percent        53              79

Complete-Mixed Aeration Tank
  Detention Time Based on Average Flow, hr^            —                 8.2
  Sludge Recycle Rate, percent of Average Flow           —                20
  Volumetric Loading, Ib BOD/day/1,000 cu ft
   Aeration Tank Volume                              —                25

Final Clarifier
  Overflow Rate, gpd/sq ft                             -               610
  BOD Removal - 2nd Stage Filter and Clarifier, percent    —                77
  SS Removal - 2nd Stage Filter and Clarifier, percent      —                76
Overall Plant Performance
  BOD Removal, percent                                67              98
  SS Removal, percent                                  73              99
  Effluent BOD, mg/1                                   95               6
  Effluent SS, mg/1                                     75               4

^Includes sludge recycle.
                                     4-25

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         4.5.1.4   Upgrading an Existing Two-Stage Trickling Filter to a Multiple-Stage
                   Biological System

Several  options  are  available for upgrading  a hydraulically  or organically  overloaded
two-stage filter. Three of the more common techniques are listed below:

     1.   Construction of a roughing filter preceding the existing system

     2.   Construction of an activated sludge system following the existing system

     3.   Construction of a separate parallel biological treatment system.

A  detailed  discussion   will  not  be  presented here,  since  most   of  the engineering
considerations pertaining to these three options have been examined in  previous sections.

     4.5.2   Upgrading to Increase Organic Removal Efficiency

Upgrading techniques previously discussed relate to the ability of existing facilities to handle
increased hydraulic or organic loads by providing modifications  to meet existing effluent
standards. However, there may be a need to meet higher effluent standards even though the
existing  facilities are not hydraulically or organically overloaded.   Table 4-7 contains
suggested alternatives for  improving  effluent  quality  under these conditions.  The main
purpose of the table is to present various alternatives and to suggest a range of anticipated
improvement in performance for each alternative.

It  should be emphasized that in cases where unit processes are  added to existing facilities,
the improvement in overall organic removal will be a direct function  of the BOD removal
achieved in the "add-on" unit process.  However, where unit processes precede existing units,
e.g.,  the use of a roughing filter, the  overall BOD removal may not be increased in direct
proportion to the amount achieved in the "add-on" process.

A  detailed  discussion on polishing  lagoons,  microscreens,  filters, activated carbon  and
clarifier modifications appears in subsequent chapters. The applicability of alternatives to
individual cases should  be evaluated in detail  prior  to the implementation of a particular
upgrading procedure.

         4.5.2.1   Upgrading a  Single-Stage  Trickling  Filter Through  Conversion to a
                   Complete-Mix  Activated Sludge System

In 1965, the Ontario Water Resources  Commission set 15 mg/1 of BOD and SS as the
objectives  for  secondary treatment  plant  effluents. This  effluent quality could  not be
achieved with an existing high-rate trickling filter plant at Gravenhurst, Ontario (32).
                                         4-26

-------
f"
to
                                                         TABLE 4-7
                  UPGRADING TECHNIQUES FOR IMPROVEMENT OF TRICKLING FILTER PLANT EFFICIENCY
         Addition Preceding
           Existing Unit
        Roughing Trickling Filter
         (Rock or Synthetic Media)
        Chemical Addition
         To Primary Clarifier
    Modification to
     Existing Unit


1.  Low-Rate Trickling Filter
   Add recirculation during
   low-flow periods

2.  High-Rate Trickling Filter

   Increase recirculation.

3.  Two-Stage Trickling Filterl
Addition Following
   Existing Unit
Incremental BOD Removal
   Across the Added or
    Modified Process
        percent
                                                                 2nd Stage Activated Sludge^
                                                                 Polishing Lagoon
                                                                 Multimedia Filters
                                                                 Microscreening
                                                                 Activated Carbon
        ^Generally not amenable to modifications for increasing treatment efficiency.
           consideration if year-round nitrification is required.
                                                                                                         0-10
                                                                                                         0-10
                                                                   2040

                                                                   30-50
                                                                   30-70
                                                                   30-60
                                                                   50-80
                                                                   30-80
                                                                   60-80

-------
To upgrade the high-rate filter, the plant was converted to complete-mix activated sludge.
The 40-foot diameter filter was converted to an aeration tank by removing the media and
raising the concrete sidewalls 7 feet to a total height of 12 feet. A 10-hp mechanical aerator
was installed. The duo-clarifier (combination primary and secondary clarifier) was converted
to a 40-foot diameter secondary clarifier, and a new 35-foot diameter primary clarifier was
constructed. A 100-percent sludge recycle capacity was provided.

The previously  described  upgrading  technique  resulted  in  the  following measured
improvements:
                                                    Before             After
          Parameter                                Upgrading          Upgrading
Dry weather design flow, gpd
Influent organic load, Ib BOD/day
Effluent BOD, mg/1
300,000
    360
  > 20
375,000
    540
  15-20
The upgrading technique employed allowed the plant to handle 50 percent greater BOD
loads while producing an effluent of higher quality.

The capital costs for this upgrading were estimated at $82,000  and were  allocated as
follows:
          Tank modification
          Secondary clarifier modification
              Total
         $64,000
           18,000
         $82,000
These costs do not include upgrading of any other unit treatment processes, e.g., primary
clarification.

     4.5.3   Upgrading Existing Trickling Filters to Provide Nitrification

Increasingly stringent State and Federally approved water quality standards are requiring the
partial or complete removal of nitrogenous oxygen-demanding materials from critical stream
basins, lakes and estuaries. For this reason, many existing trickling filter plants will have to
be upgraded to provide nitrification.

The development  and maintenance of nitrifying organisms in trickling filter  systems  is
mainly   dependent  upon  organic  loading   and  wastewater  temperature.   Generally,
nitrification occurs best at low BOD loadings and high wastewater temperature (20 deg C or
higher). Table 4-8  clearly shows that the degree of nitrification in trickling filters improves
as the volumetric BOD loading is reduced.
                                         4-28

-------
                                                        TABLE 4-8
                                         TRICKLING FILTER NITRIFICATION DATA
f'
tb
           Plant
    Livermore, Calif.
    Glenwood City, Wise.
    Lakefield, Minn.
    Allentown, Pa.
    Ft. Benjamin Harrison, Ind,
    Fitchburg, Mass.
    Salford, England
    Midland, Mich. - Summer
                 - Winter
Organic
Loading
BOD
lb/day/1,000
cuft
110
66
54
18
4.6
3.7
3.2
4.6
5.9
7.7
9.2
11.8
16.3
22.6
4.2-5.6
4.2-5.6
Influent
BOD
mg/1
50
168
296
209
113
100
206
199
192
165
239
191
235
266
15-20
15-20
Hydraulic
Loading
mgd/acre
3.4
14.3
7.1
4.4
1.7
4.0
0.7
1.0
1.3
2.0
1.6
2.6
2.9
3.6
31
31
Recirculation
Depth Ratio
ft
4.25
7.0
7.5
10.0
8.0
10.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
21.5
21.5

2.0
2.0
0.3
0.1
0
0
0/1
0/1
0/1
0/1
0/1
0/1
0/1
0/1
0-1.0
1.0
Influent
NHa - N
mg/1
40.7
10.6
19.0
30.0
21.0
12.0
36.6
38.3
40.7
40.5
43.9
32.0
31.3
33.9
12.7
14.0
Effluent
NH3-N
mg/1
32.6
6.7
16.3
12.0
6.3
2.0
0.7/0.4
2.8/0.9
5.7/2.8
11.4/4.9
12.5/2.2
9.7/4.8
16.9/11.8
19.7/13.6
1.5
2.2
NH3-N
Removal
percent
20
37
13
60
70
83
93/99
93/98
86/93
72/88
72/95
70/85
46/62
42/60
88
84
Reference

33
34
34
35
7
36
37







38


-------
In colder climates, existing trickling filter plants may be modified to achieve a high degree
of nitrification on a year-round basis,  or  only  during the warmer months  of the  year,
depending on effluent criteria. Year-round  nitrification facilities must be designed for the
lowest wastewater  temperatures  experienced in the  winter months. In this instance, the
required filter volume is generally much greater than that required for seasonal nitrification
and  normally requires at least  two-stage treatment. Figure 4-6  illustrates four possible
systems for implementing year-round nitrification.

Table 4-8 indicates that  a  high  degree of nitrification (> 80 percent) was achieved at
Salford, England (37) at BOD loading rates less than 12 and 6 Ib BOD/day/1,000 cu ft with
recirculation ratios of 1.0 and zero, respectively. These results were obtained  with 20-foot
diameter trickling filters, 8 feet  deep,  with a media consisting of blast furnace slag.  At
Midland, Michigan, a pilot study  was conducted by Dow Chemical for the U.  S. EPA (38),
using synthetic media in a 3-foot diameter by 21.5-foot deep column. Table 4-8 shows that
secondary  effluent fed  to  the  pilot facility  at  organic   loading  rates  less  than
5.6 Ib BOD/day/1,000  cu  ft produced a high degree of nitrification at temperatures as low
as 7 deg C.  The data shown in Table 4-8, and similar operating data from other locations,
indicate that trickling filters can achieve a high degree of nitrification at organic loadings less
than 5 Ib BOD/day/1,000 cu ft.

Example C on Figure 4-6  utilizes an activated sludge  system which can also be used as the
second-stage nitrification facility. This scheme can be used with or without an intermediate
clarifier. If plant hydraulics permit, the existing first-stage clarifier may be converted for use
as a final clarifier.  The design of this type of facility is discussed in Chapter 5 and in
reference (39).

The  following examples  describe  the  upgrading  of existing  trickling filter  plants for
nitrification.
         4.5.3.1    Upgrading a Single-Stage  Trickling Filter  to a Two-Stage Filtration
                    System to Provide  Nitrification

In January 1971, the Pennsylvania Department of Health upgraded the water quality criteria
established for the Lehigh River and its major tributaries. As a result, the City  of Allentown
was  informed that  upgrading of its wastewater treatment plant would be required. The
upgraded plant was designed to meet the following effluent standards from May 1 to
October 31:  BOD not to exceed 20 mg/1, ammonia nitrogen (NH3-N) not to exceed 3 mg/1
and  total SS not  to exceed 30 mg/1. It was also necessary to  expand plant capacity from
28.5 to 40 mgd.

The existing plant  provided  secondary treatment  using fixed-nozzle rock-media trickling
filters as shown on Figure 4-7. The raw wastewater to the plant contained 190 mg/1 BOD,
16 mg/1 NH3-N,  and  215 mg/1  SS, which was reduced  through the plant  to effluent
concentrations of 40 mg/1 BOD, 12 mg/1 NH3-N, and 40 mg/1 SS.

                                         4-30

-------
                       FIGURE  4-6
        UPGRADING A TRICKLING FILTER SYSTEM
        TO  PROVIDE TWO-STAGE NITRIFICATION
EXAMPLE A
                                                           FINAL
                                                           EFFLUENT
EXAMPLE D
PRIMARY
^
EFFLUENT
AERATION
TANK
fc

CLARIFIER


       NOTES'  I.  CROSS HATCHED FACILITIES DESIGNATE EXISTING TRICKLING
                FILTERS AND CLARIFIERS,

             2  RECIRCULATION SCHEMES NOT SHOWN
                            4-31

-------
      INFLUENT
      24 MGD
                                FIGURE 4-7

                UPGRADING  A SINGLE-STAGE TRICKLING FILTER

                   TO A TWO STAGE FILTRATION SYSTEM
                        TO PROVIDE  NITRIFICATION
                              PRIMARY
                              TANKS
                       TRICKLING
                       FILTERS
FINAL
CLARIFIERS
k.
i
h


V
1
R
/
SL
r
                                      RECIRCULATION
                                                            SLUDGE
                           TREATMENT  SYSTEM  BEFORE UPGRADING
                                                  EFFLUENT
          PRIMARY
          TANKS-
SYNTHETIC MEDIA
FIRST-STAGE
FILTERS
                                      INTERMEDIATE
                                      PUMPING  STATIONS
INFLUENT
40  MGD
                                       INTERMEDIATE
                                        CLARIFIERS
 EXISTING  TRICKLING
 FILTERS-NITRIFICATION
 UNIT-^
          -EXPANDED
           FINAL CLARIFIERS
                                                  EFFLUENT
                              RECIRCULATION 4.0  MGD

                    TREATMENT SYSTEM  AFTER UPGRADING
                                                                SLUDGE
                                       4-32

-------
Under the plan (35) recommended to meet the additional removal and flow requirements,
an  auxiliary  pumping station  was installed near the existing  main station. The  existing
detritus  tank and  grit washing facilities  were replaced by  aerated  grit chambers.  New
synthetic media first-stage filters were installed. The old rectangular primary tanks were
used  as  intermediate clarifiers  following the first-stage  filters and new circular  primary
clarifiers  were  installed.  The  existing rock-media trickling  filters  were  retained  as
nitrification  units.  The final  clarifiers  and  chlorine contact  tanks  were expanded and
modifications were made to the existing piping. Recirculation of flow to the trickling filters
will only be used during low flow conditions to maintain a minimum hydraulic wetting rate.
A flow diagram of the upgraded plant  is  shown  on Figure 4-7. Operating conditions and
upgraded design conditions are given in Table 4-9.

The capital costs associated with this upgrading were estimated at $11,632,000 and were
allocated as follows:

          Pumping                                          $ 1,192,000
          Grit Handling Facilities                                 423,000
          Primary Clarifiers                                    1,200,000
          Trickling Filters                                      3,985,000
          Final Clarifiers                                         414,000
          Chlorine Contact Tank Additions                         80,000
          Sludge Processing                                      745,000
         Instrumentation, Electrical, Plumbing and HVAC       1,647,000
          Sitework, Outside Pumping and Dewatering            1,800,000
          Miscellaneous                                          146,000
              Total                                        $11,632,000

          4.5.3.2   Upgrading  a Single-Stage Trickling  Filter to a Two-Stage System  to
                   Provide Nitrification

In  1969, an industry in New  York  State was  required by the Department of Health  to
upgrade  its existing trickling filter plant to meet year-round effluent standards of about
160 Ib/day of Ultimate  Oxygen Demand (ultimate BOD plus nitrogenous oxygen demand).
The plant consisted of  single-stage, high-rate  trickling filters designed to treat 0.9 mgd  of
sanitary  and industrial  wastes generated by  the  industry. The treatment system before
upgrading is shown on Figure 4-8.

To  meet the  more stringent standard, it  was decided to follow the existing facility with  an
activated sludge nitrification system (40). Except for some modifications in trickling filter
recirculation, the existing facility was incorporated into the upgrading scheme unchanged.
Effluent from the trickling   filter  plant  was fed to  a four-compartment, plug-flow
nitrification reactor equipped with mechanical  aerators. Two new final clarifiers followed
the nitrification reactor. A flow  diagram  of  the upgraded plant  is shown on Figure 4-8.
                                        4-33

-------
                                  TABLE 4-9
                     OPERATING AND DESIGN CONDITIONS
                      FOR ALLENTOWN, PENNSYLVANIA
            Description

 Flow, mgd
 Influent BOD, mg/1
 Influent SS, mg/1
 Influent NH3 - N, mgA

 Primary Clarifier
   Overflow Rate, gpd/sq ft
   BOD Removal, percent

First-Stage Filter - Synthetic Media
  Depth, ft
  Hydraulic Loading, mgd/acre
  Organic Loading, Ib BOD/day/1,000 cu ft

Intermediate Clarifier
  Overflow Rate, gpd/sq ft
   1st Stage BOD Removal, percent
   1st Stage NHg - N Removal, percent

Trickling Filter - Rock Medial
  Depth, ft
  Hydraulic Loading, mgd/acre
  Organic Loading, Ib BOD/day/1,000 cu ft

Final Clarifier
  Overflow Rate, gpd/sq ft
  2nd Stage BOD Removal, percent
  2nd Stage NHg - N Removal, percent

Overall Plant Performance
  BOD Removal, percent
  SS Removal, percent
  NHg - N Removal, percent
  Effluent BOD, mg/1
  Effluent SS, mg/1
  Effluent NH3 - N, mg/1

^Proposed nitrification unit.
2May 1 - October 31.
  1971
Operating
Condition

   24
  190
  215
   16

  870
   10
    4.5
   18.0

  760
   79
   81
   25
   40
   40
   12
Upgraded
 Design
Condition

     40
    210
    230
     15

    920
     31

     32
     58
     50

  1,500
     80
     0

     10
     7.5
     4.3

   800
     33
     80

     91
     87
     80
     202
     302
     32
                                    4-34

-------
                                  FIGURE 4-8

                    UPGRADING A SINGLE-STAGE TRICKLING FILTER TO
              A TWO-STAGE BIOLOGICAL SYSTEM TO PROVIDE NITRIFICATION
         INDUSTRIAL FLOW
  SANITARY
    FLOW
  0. 11 MGD
                                                                        EFFLUENT
                 PUMP
               STATION
                                                    0,55 MGD
                                                                         PUMP
                                                                         STATION
                       TREATMENT SYSTEM  BEFORE  UPGRADING
        INDUSTRIAL FLOW
SANITARY FLOW
0. 25 MGD
            PUMP
            STATION
EXISTING
TRICKLING^
FILTERS'
INTERMEDIATE
CLARIFIER '
ISTING FINAL
CLARIFIER)
^
, '
NITRI-
FICATION
REACTOR


RETURN SLUDGE
FINAL
CLARIFIERS
i




P
S
                                                                             EFFLUENT
                                                                            PUMP
                                                                            STATION
                         TREATMENT  SYSTEM AFTER UPGRADING
                                       4-35

-------
Operating conditions and upgraded design conditions are given in Table 4-10. The upgraded
facility has been in operation for over a year and has produced an effluent of higher quality
than specified.

The capital cost for the construction of the upgraded facility was estimated at $690,000 in
1970.

     4.5.4   Upgrading to Remove Nutrients

The preceding discussion  has  been primarily  concerned  with upgrading techniques  to
improve treatment plant effluent quality by reducing the oxygen demand that the effluent
will exert on the receiving water. A matter of increasing concern, however, has been the
nutrient content  of treatment  plant effluent. It is known that the continued and normal
growth of microorganisms requires the availability of certain elements and nutrients as well
as an energy source. Nitrogen and phosphorus are nutrients normally present in substantial
quantities in raw wastewater that are not effectively removed  by conventional biological
treatment.  The  discharge  of these  substances contributes to  the  overfertilization and
eutrophication  of our surface  waters. As a result,  many  states have established  or are
considering standards to limit the discharge of nutrients. The techniques that  have been
developed for nutrient removal are summarized in Table 4-11.

The design of a plant  for nitrogen removal generally requires separate biological units for
secondary treatment, nitrification and denitrification. In upgrading a trickling filter plant  to
remove nitrogen, the  existing  trickling  filters  may  be  used for roughing, as  secondary
treatment units, or as nitrification units.

The techniques available for removal of phosphorus are the subject of detailed discussion in
the Process  Design  Manual for Phosphorus Removal (41). The  following  case histories
illustrate the upgrading of existing trickling filter plants for phosphorus removal.

         4.5.4.1    Upgrading a Low-Rate Trickling Filter System With Chemical Addition
                   for Phosphorus Removal

A plant-scale study  was  begun at Richardson, Texas, in 1970 to evaluate the potential  of
chemical addition to remove phosphorus from and improve overall performance of the
City's trickling filter plant (5). Major objectives were to reduce the effluent phosphorus
concentration  to  1.0 mg/1 (as P),  or less, and to reduce effluent BOD and SS residuals  to
15 mg/1, or less.

The existing  plant  was  a  low-rate trickling  filter facility with  combination  primary
clarifier/digester units (clarigesters) as shown on Figure 4-9. Operating data for a  control
period  before the addition of chemicals are shown in Table 4-12.
                                         4-36

-------
                                TABLE 4-10
             OPERATIONAL AND DESIGN DATA FOR AN INDUSTRY
                             IN NEW YORK STATE
             Description

Wastewater Flow, mgd
  Sanitary
  Industrial
    Total
Influent BOD, mgA
  Sanitary
  Industrial

Influent SS, mgA
  Sanitary
  Industrial

Primary Clarifier
  Overflow Rate, gpd/sq ft
  BOD Removal (Sanitary Flow), percent

Trickling Filters - Stone Media
  Depth, ft
  Hydraulic Loading, mgd/acrel
  Organic Loading, Ib BOD/day/1,000 cu ft2
  Recirculation Ratio

Intermediate Clarifier (Existing Final Clarifier)
  Overflow Rate, gpd/sq ftl
  1st Stage BOD Removal, percent

Nitrification Reactor
  Volume, cu ft
  Depth, ft
  Volumetric Loading, Ib BOD/day/1,000 cu ft
  MLSS, mg/1
  F/M, Ib BOD/day/lb MLSS
  Sludge Recycle Rate, percent of Average Flow
  Oxidizable Nitrogen to Reactor, mgA
  1970
Operating
Condition
  0.11
  0.51
  0.62
   485
    55


   224
    43

   336
    30


    5
  22.6
    34
  1.67


   740
    66
Upgraded
 Design
Condition
    0.25
    0.64
    0.89
     500
     120


     250
      90

     435
      30


       5
    20.4
      86
    0.67


     560
      50

  55,500
      12
    12.5
   4,000
    0.05
     100
    32.5
                                     4-37

-------
                           TABLE 4-10 (Continued)
            Description
                                  1970
                                Operating
                                Condition
        Upgraded
          Design
        Condition
Final Clarifier
  Overflow Rate, gpd/sq ft
  2nd Stage BOD Removal, percent

Overall Plant Performance
  BOD Removal, percent
  SS Removal, percent
 .Effluent BOD, mgA
  Effluent SS, mgA
  Effluent NH3 - N, mgA

^Includes recirculation.
      not include recirculation.
                                   72
                                   44
                                   36
                                   42
                                   23
             280
              92

              97
            >90
               7
            <15
              1.4
Nitrogen
                                 TABLE 4-11
                 SUMMARY OF TREATMENT PROCESSES FOR
                            NUTRIENT REMOVAL
      Physical-Chemical

Ammonia Stripping after
pH Adjustment

Ammonia Removal by Breakpoint
Chlorination
                                                             Biological
Nitrification-Denitrification
                                                     Algae Harvesting
Phosphorus
Ammonia Removal by Ion Exchange

Chemical Precipitation
                                    4-38

-------
                          FIGURE  4-9
        UPGRADING A STANDARD RATE TRICKLING FILTER SYSTEM
    WITH CHEMICAL ADDITION TO  PROVIDE PHOSPHORUS  REMOVAL
INFLUENT
1,5 MGD
                   PRIMARY
                   CLARIFIERS     TRICKLING
                   (CLARIGESTERS) FILTERS
FINAL
CLARIFIER
                          DIGESTED
                        I  SLUDGE
                        V TO  SAND BEDS


                      SETTLED FINAL  SLUDGE
                 EFFLUENT
          TRICKLING FILTER SYSTEM  BEFORE UPGRADING
              PRIMARY
CLARIF
(CLAR
INFLUENT

. u MGD 	 t




•IERS TRICKLING
GESTERS) FILTERS


f\

^\ ^^™"
\ D GESTED
4 SLUDGE
TO SAND BEDS
SETTLED FINAL
ALUM |
V b

INAL
-LARIFIER




SLUDGE
^^^^ ^.




             TRICKLING FILTER SYSTEM  AFTER UPGRADING
                                                          EFFLUENT
                               4-39

-------
                                 TABLE 4-12
                 OPERATING DATA FOR RICHARDSON, TEXAS
            Description

Flow, mgd
Influent BOD, mg/1
Influent SS, mg/1
Influent P, mg/1

Primary Clarifier
  Overflow Rate, gpd/sq ft
  Primary Effluent BOD, mg/1
  Primary Effluent SS, mg/1
  Primary Effluent P, mg/1
  BOD Removal, percent
  SS Removal, percent
  P Removal, percent

Trickling Filter
  Depth, ft
  Recirculation Ratio
  Hydraulic Loading, mgd/acre
  Organic Loading, Ib BOD/day/1,000 cu ft

Secondary Clarifier
  Alum Dosage Rate, Average A1:P mole ratio
  Overflow Rate, gpd/sq ft
  Secondary BOD Removal, percent
  Secondary SS Removal, percent
  Secondary P Removal, percent

Overall Plant Performance
  Effluent BOD, mg/1
  Effluent SS, mg/1
  Effluent P, mg/1
  BOD Removal, percent
  SS Removal, percent
  P Removal, percent

 *Not reported.
**Based on Influent P.
 1970
Control
Period

  1.5
166
155
 11


400
 *
 *
  6.5
  0
  3.9
390
 20
 15
  8
 88
 90
 27
    1971-72
   Extended
   Alum Run
(11-1/2 Months)

      1.6
    170
    155
     11.4


    425
    115
    110
      8.6
     32
     29
     25


      6.5
      0
      4.1
     14.0

      1.6**
    415
     96
     94
     94


      5
      7
      0.5
     97
     95
     96
                                    4-40

-------
Liquid alum and liquid ferric chloride were selected as the two coagulants to be used in
operational chemical addition trials. Points of chemical injection evaluated were just ahead
of the influent wet well and in the junction box ahead of the final clarifier. The preliminary
trials provided the following observations:

     1.   Ferric  chloride addition at either injection point resulted in about 80 percent
         overall phosphorus removal, actually downgraded plant BOD and SS removals and
         produced excessive carry-over of discrete iron colloids in the plant effluent.

     2.   Alum addition to the influent wet well, although somewhat more effective than
         ferric chloride addition in achieving the  desired effluent quality, resulted in a
         rapid  and  dramatic decrease  in  digester  alkalinity  and  pH,   necessitating
         termination of the trial in nine days.

     3.   Alum addition just ahead of the final clarifier proved to be the most effective
         chemical injection technique for removing phosphorus and upgrading BOD and SS
         removals, and did not exhibit the deleterious side effect on the unheated digesters
         observed when alum was dosed to the raw wastewater.

Based on the above operational trials, alum addition ahead of the final clarifier was selected
as the most promising chemical additive system for an extended 11-1/2-month run. The
flow diagram for the upgraded system is shown on Figure 4-9.

It was found that a mole ratio (Al: Influent P) of 1.5  to 1.7 consistently yielded effluent
concentrations of 5 mg/1 of BOD, 7 mg/1 of SS and 0.5 mg/1 of total phosphorus (as P). The
corresponding effluent  values for this  plant prior to chemical addition  were 20, 15 and
8 mg/1,  respectively.  The  improved  plant  performance  obtained with this  upgrading
technique was attributed in part to the low final clarifier overflow rate, careful management
of final clarifier sludge withdrawal to prevent disruption to and loss of the alum floe blanket
and frequent manual adjustment of the chemical feed pump rate to match alum dosage to
mass inflow of phosphorus. Alum treatment doubled the volume of anaerobically  digested
sludge produced. However, the digested alum/biological sludge exhibited superior drying
characteristics on sand beds  and could  be removed in about one-half the normal  time.
Operating data for the upgraded plant are shown in Table 4-12.

Chemical costs were $0.05/1,000 gal of plant flow or $0.36/lb of phosphorus removed, with
phosphorus removal at the 96 percent level. The 1970 capital costs associated with plant
modifications for chemical addition were $65,000, allocated as follows:

          New laboratory building                           $21,000
          Laboratory equipment and furniture                   6,000
          Chemical storage and feed equipment, plant piping
           and metering modifications                         38,000
              Total                                        $65,000
                                        4-41

-------
          4.5.4.2   Upgrading a High-Rate Trickling Filter System With Chemical Addition
                   for Phosphorus Removal (A)

Promising results were obtained in removing phosphorus and in generally improving plant
performance at Richardson, Texas, by the addition of alum to trickling filter effluent as
discussed in Subsection 4.5.4.1. In view of these results,  the University of North Carolina
Wastewater Research Center initiated a follow-up study to further explore and confirm this
process at the Chapel Hill, North Carolina Wastewater Treatment Plant (7). Conducting a
similar chemical addition project at Chapel Hill was considered worthwhile because it is a
typical high-rate trickling filter plant using recirculation, whereas the Richardson filters were
low-rate  units. Furthermore, parallel and identical lines of treatment units were available at
Chapel  Hill, allowing  direct comparison  of  results  with  and  without alum addition.
Comparison of parallel results was not possible at Richardson.

The wastewater treatment plant  at Chapel Hill is a conventional  high-rate installation
treating  predominately   domestic  wastewater.   Incoming  wastewater   passes  through
pretreatment facilities for the removal of large  solids and  grit. The flow is then divided into
equal portions for diversion to two identical lines of treatment,  each consisting of a primary
clarifier,  trickling filter and final clarifier as shown on Figure 4-10.  On one side of the plant,
a feed pump system was installed to add liquid alum to the trickling filter effluent just prior
to the final clarifier.

Operating data  for the  two sides of  the plant are shown  in Table 4-13.  Significant
improvements in BOD, SS and phosphorus removals were achieved  with an alum dosage rate
that ranged between an Al:Influent P mole ratio  of 1.5 and  2.2. Within this range and for
the loading rates shown, the final clarifier hydraulic loading  appeared to be the significant
factor affecting  process  efficiency.  Subsequent phases of  the  study indicated that
phosphorus  removals of over 90 percent  and BOD removals  of about 95 percent could be
consistently  obtained  by lowering the  final  clarifier overflow  rate to 500 gpd/sq ft.
Recirculation of the final clarifier  settled alum/humus sludge  to  the primary clarifier for
thickening had a beneficial effect on primary treatment efficiency and decreased the organic
loading on the alum train trickling filter.

Some  problems were  encountered  at Chapel Hill in the  sludge digestion  and digester
thickening operations during alum addition (see Section 11.2.6).

          4.5.4.3    Upgrading a High-Rate Trickling Filter System With Chemical Addition
                   for Phosphorus Removal (B)

In 1968, the City of Marlborough, Massachusetts, initiated a series  of studies to improve the
performance of its existing high-rate trickling filter plant  (42).  It was hoped that chemical
treatment of the filter effluent prior to final settling would  provide  acceptable effluent
concentrations of BOD, SS and phosphorus, with nominal additional capital costs. In 1971,

                                       4-42

-------
following pilot studies, a plant-scale program of alum addition was begun. A flow diagram of
the existing single-stage, high-rate trickling filter system is shown on Figure 4-11.

The existing plant includes Imhoff  tanks for primary treatment and  sludge digestion.
Secondary  humus  sludge  is returned  to  the Imhoff tanks' 'influent.  Recirculation is
accomplished with either trickling filter or final clarifier effluent. Pre-upgrading operating
data for the period from January, 1970 to April, 1971 are shown in Table 4-14.

The upgrading  modifications included  the  installation  of alum storage and  feeding
equipment. Operating data for the upgraded plant from May, 1971 through August, 1972
are also shown in Table 4-14. As can be seen, the recycle of alum-laden sludge from the final
clarifier substantially improved the performance of the Imhoff tanks.

The capital cost for the chemical storage and  feed system was $4,250. Based on a chemical
cost of $65/ton of dry alum and a dosage of  1.5 moles of Al+3 to 1 mole of inorganic
phosphorus, the treatment cost was $0.32/1,000 gal of plant flow.
                                       4-43

-------
                  FIGURE  4-10
        UPGRADING A TRICKLING FILTER SYSTEM
USING CHEMICAL ADDITION FOR  PHOSPHORUS REMOVAL
PRIMARY TRICKLING FINAL
rONTROL CLARIFIER FILTER CLAR
TRAIN - /^~X
lUCMICUT W h/ \ 	 fe
1,4 MGD =
]/2 PLANT
INFLUENT






i "A J
i COMBINED
SLUDGES





i
i W
FIER

	 fe.
w
CJ
ce.
^—
CJ
LU
ce
r
ca
LU LU
_l —I C9
1— «r CD
^— ;z "~*
LU — _J
CO U_ CO
                                                 EFFLUENT
TRICKLING  FILTER  TRAIN WITHOUT CHEMICAL ADDITION
TEST
TRAIN
INFLUFNT
1 .4 MGD = '
1/0 D 1 1 U T
Z r L AN 1
INFLUENT
PRIMARY
CLARIFIE

b
1 c
1 s
, "tffil",1 T
>c\ i
\J i
OMBINEO «
LUDGES =
C3
ce
• • ej
LU
ce
FINAI
CLAR


r
FIER
	 k.

o
UJ LU
_j _i co
1 — -tt C3
1— ^ 13
UJ 	 1
CO U- CO
                                                  EFFLUENT
   TRICKLING FILTER  TRAIN  WITH  CHEMICAL ADDITION
                         4-44

-------
                                  TABLE 4-13
           OPERATING DATA FOR CHAPEL HILL, NORTH CAROLINA

                                                    Side 1         Side 2
            Description                            (No Alum)    (With Alum)

Flow, mgd                                               1.41         1.41
Influent BOD, mg/1                                      168          168
Influent SS, mg/1                                        229          229
Influent P, mg/1                                           11.3         11.3

Primary Clarifier
  Overflow Rate, gpd/sq ft                              1,100         1,100
  Primary Effluent BOD, mg/1                              77           63
  Primary Effluent SS, mg/1                                89           68
  Primary Effluent P, mg/1                                 9.7          6.6
  BOD Removal, percent                                  54           63
  SS Removal, percent                                    61           70
  P Removal, percent                                     14           42

Trickling Filter
  Depth, ft                                              4.25         4.25
  Organic Loading, Ib BOD/day/1,000 cu ft                  2.0          2.0
  Hydraulic Loading, nigd/acre^                            16.3         16.3
  Organic Loading, Ib BOD/day/1,000 cu ft                  18.8         15.4

Secondary Clarifier
  Alum Dosage Rate, Average A1:P mole ratio             —              1.7^
  Overflow Rate, gpd/sq ft                               885          885,
  Secondary BOD Removal, percent                         43           76
  Secondary SS Removal, percent                           29           53
  Secondary P Removal, percent                            5           73

Overall Plant Performance
  Effluent BOD, mg/1                                     44           15
  Effluent SS, mg/1                                       63           32
  Effluent P, mg/1                                        9.2          1.8
  BOD Removal, percent                                  74           91
  SS Removal, percent                                    72           86
  P Removal, percent                                     19           84

^Includes recirculation.
^Based on Influent P.
                                     4-45

-------
                FIGURE 4-11
     UPGRADING A TRICKLING FILTER SYSTEM
      TO PROVIDE PHOSPHORUS REMOVAL
IMHOFF
TANKS-y
/
INFLUbNI
9 99 ucn ^ [w

T
SLUDGE
TRICKLING
FILTERS-^
/
r-*T\^
^\J^
RECIRCULATION,


h

r





\n
\



NAL
ARI Fl ERS

fe EFFLUFNT

1
1
. J
     TRICKLING  FILTER SYSTEM BEFORE  UPGRADING
r-IMHOFF TRICKLING
\TANKS FILTERSy
\ SECONDARY SLUDGE/ C
INFLUENT / V
i qn u nn " _h »/ i w
w A


SLUDGE

1
ALUM
RECIRCULATION ,



' ^- -
INAL
LARIFIERS

^
|
1
1
1
_l
TRICKLING  FILTER SYSTEM AFTER UPGRADING
                     4-46

-------
                                  TABLE 4-14
           OPERATING DATA FOR MARLBOROUGH, MASSACHUSETTS
             Description

Flow, mgd
Influent BOD, mg/1
Influent SS, mg/1
Influent Inorganic P, mg/1

Primary Settling - Imhoff Tanks
  Overflow Rate, gpd/sq ft
  BOD Removal, percent 1

Trickling Filter
  Depth, ft
  Hydraulic Loading, mgd/acrel
  Organic Loading, Ib BOD/day/1,000 cu ft

Secondary Clarifier
  Alum Dosage Rate, Average Al: Inorganic P
   mole ratio
  Overflow Rate, gpd/sq ft
  BOD Removal, percent
  Percent SS Removal percent^
Overall Plant Performance^
  BOD Removal, percent
  SS Removal, percent
  Inorganic P Removal, percent
  Effluent BOD, mg/1
  Effluent SS, mg/1
  Effluent Inorganic P, mg/1

^Includes 0.8 mgd recirculation.
^Includes primary removal.
^Includes effluent polishing lagoon.
Operating
Conditions
 Prior to
Upgrading

    2.22
  134
  112
    7


  605
    3


    6
   21.4
   74
  915
   54
   71

   70
   85
   14
   40
   17
    6
Operating
Conditions
  After
Upgrading

    1.99
  171
  190
    8.1


  520
   22


    6
   19.1
   57
    1.5
  785
   77
   78

   86
   88
   81
   24
   23
    1.4
                                     4-47

-------
4.6  References

 1.  Unpublished data, U. S. EPA Office of Water Programs, Washington, D. C. (September,
     1973).

 2.  McKinney, R., Microbiology for Sanitary Engineers. New York:  McGraw  Hill Book
     Company, Inc. (1962).

 3.  Sewage  Treatment  Plant  Design.  Water Pollution Control Federation Manual  of
     Practice No. 8, Washington, D. C. (1959).

 4.  Dreier,  D.E. Experience in the Operation of Standard Trickling Filters. Sewage Works
     Journal (July, 1946).

 5.  Derrington, R.E., Stevens,  D.H., Laughlin,  J.E., Enhancing Trickling Filter Plant
     Performance  by Chemical Precipitation. Environmental Protection Technology Series,
     U. S. EPA-670/2-73-060 (August, 1973).

 6.  Rankin, R.S., Evaluation  of the Performance  of Biofiltration Plants. Transactions of
     the American Society of Civil Engineers, 120, pp. 823-835 (1955).

 7.  Brown, J.C., Alum  Treatment of High-Rate  Trickling  Filter Effluent, Chapel Hill,
     North Carolina,  Technology  Transfer  Design Seminar.  Presented  at  Newark, New
     Jersey (March 13-15, 1974).

 8.  Sewage Treatment at Military Installations. National Research Council, Sewage Works
     Journal, 18, No. 5, pp. 787-1,028 (1946).
    X*
upf"
 9.  Recommended Standards for Sewage  Works. Great Lakes-Upper  Mississippi  River
     Board of State Sanitary Engineers (1971).

10.  Velz, C.J., A Basic Law for the Performance of Biological Beds. Sewage Works Journal,
     20, No. 3, pp. 245-261 (1960).

11.  Caller, W.S., and Gotaas,  H.B., Analysis of Biological Filter  Variables. Journal of  the
     Sanitary Engineering Division, ASCE, 90, No. 6, pp. 59-79 (1964).

12.  Schulze, K.L., Load and Efficiency of  Trickling Filters.  Journal Water  Pollution
     Control Federation, 32, No. 3, pp. 245-261 (1960).

13.  Eckenfelder,  W.W.,  Trickling Filter  Design and Performance. Transactions of  the
     American Society of Civil Engineers, 128, Part III, pp. 371-398 (1963).
                                        4-48

-------
 14.  Eckenfelder, W.W.,  and Barnhart, W., Performance of a High-Rate Trickling Filter
     Using Selected  Media. Journal Water  Pollution Control Federation, 35, No. 12, pp.
     1,535-1,551 (1963).

 15.  Bethlehem,  Pa.:  Private  communication  with  William  Grim,   Plant  Operator
     (November, 1970).

 16.  Burgess,  F.J.,  et  al, Evaluation Criteria for  Deep  Trickling  Filters. Journal Water
     Pollution Control Federation, 33, No. 8, pp. 787-816  (1961).

 17.  Deeds and Data. Journal Water Pollution Control Federation, 31, No. 3, pp. 315-320
     (1959).

 18.  Homack, P., Discussion of Article by R. Rankin. Transactions of the American Society
     of Civil Engineers, 120, pp. 836-841 (1955).

 19.  McCabe,  J., and  Eckenfelder,  W.,  Biological Treatment of Sewage and  Industrial
     Wastes. New York: Reinhold Publishing Company (1956).

 20.  Hanumanulu, V., Effect of Recirculation of Deep Trickling Filter Performance. Journal
     Water Pollution Control Federation, 41, No. 10, pp. 1,803-1,806 (1969).

 21.  Ordon, C., Discussion of Article by Baker and Graves (February 1968). Journal of the
     Sanitary Engineering Division, ASCE, 94, No. 3, pp. 579-583 (1968).

 22.  Maier, W., et al, Simulation of  the  Trickling Filter Process. Journal of the Sanitary
     Engineering Division, ASCE, 93, No. 4, pp. 91-112 (1967).

 23.  Reynolds, L.B., and Chipperfield, P.N.J., Principles Governing the Selection of Plastic
     Media for High-Rate Biological Filtration. Presented  at the International Congress on
     Industrial Waste Water, Stockholm, Sweden (1970).

 24.  Gulp, G., Direct Recirculation of High-Rate Trickling Filter Effluent. Journal Water
     Pollution Control Federation, 35, No. 6, pp. 742-747 (1963).

25.  Rowland, W.E., Flow  Over Porous Media as  in a Trickling Filter. Proceedings—12th
     Purdue Industrial Waste Conference, Lafayette, Indiana, pp. 435-465 (1957).

26.  Eckenfelder, W.W., Industrial Water Pollution Control. New York: McGraw-Hill Book
     Company (1966).

27.  Benzie,  W.,  Effects of  Climatic and Loading Factors  on Trickling Filter Performance.
     Journal Water Pollution Control Federation, 35, No. 4, pp. 445-455 (1963).

                                       4-49

-------
28. Sheahan, J.P., Use of Styrofoam for Trickling Filter Covers. Proceedings—20th Purdue
    Industrial Waste Conference, Lafayette, Indiana, pp. 572-582 (1965).

29. Sellards & Grigg, Inc., Sanitary Sewerage  and Wastewater Treatment Facilities. An
    Engineering Report for the City of Pueblo, Colorado (November, 1971).

30. Brown, J.C., Little, W., Francisco,  D.E., and Lamb, J.C., Methods for Improvement of
    Trickling  Filter  Plant Performance,  Part I,  Mechanical and  Biological  Optima,
    Environmental Protection Technology Series, U. S. EPA Contract No. 14-12-505.

31. Pritchett, J., Kankakee Sewage  Treatment Plant. A report on the original facilities and
    expansion programs at Kankakee, Illinois (June, 1971).

32. Economical Sewage  Treatment Plant Conversion at Gravenhurst.  Water and Pollution
    Control, 106, No. 1, pp. 26-27 (1968).

33. Hazen and  Sawyer Engineers,  Upgrading Existing Wastewater Treatment Facilities.
    Prepared for U. S. EPA Technology Transfer Design Seminar, Pittsburgh, Pennsylvania
    (August, 1972).

34. Walton, Grantham, High-Rate Trickling Filter Performance. Under the direction of the
    Board of State Health Commissioners  —  Upper Mississippi  River Basin  Sanitation
    Agreement (March, 1943).

35. Metcalf &  Eddy,  Inc., Report on The Design for Increased Capacity and  Tertiary
    Treatment  at the Allentown  Wastewater Treatment Plant. Allentown, Pennsylvania
    (November, 1971).

36. Town Report. Fitchburg, Massachusetts (1928).

37. Stones, T., Investigations on Biological Filtration at Salford. Journal of the Institute of
    Sewage Purification, No. 5, pp. 406-417 (1961).

38. Duddles, G.A., and Stevens, E.R., Application of Plastic Media  Trickling  Filters for
    Biological Nitrification Systems. Environmental  Protection Technology Series,  U. S.
    EPA Contract No. 14-12-900 (June, 1973).

39. Nitrification and Denitrification Facilities, Technology Transfer Seminar Publication,
     U. S. EPA, Washington, D. C. (August, 1973).

40. Metcalf & Eddy,  Inc., Report to (Unnamed Industry) on  Sewage  and Industrial Waste
    Treatment (August 26, 1970).
                                       4-50

-------
41. Process Design Manual for Phosphorus  Removal. U. S. EPA, Office of Technology
    Transfer, Washington, D.C. (1974).

42. Metcalf & Eddy, Inc., Modifications to the High-Rate Trickling Filter Process. A report
    to the Commonwealth of Massachusetts Water Resources Commission (October, 1970).
                                      4-51

-------

-------
                                    CHAPTER 5

          TECHNIQUES FOR UPGRADING ACTIVATED SLUDGE PLANTS
5.1  General

A better understanding of the activated sludge process has evolved down through the years,
primarily  due to an improved  knowledge  of the theory involved and to the experience
accumulated in the successful operation of the process. For these reasons, it has become the
most versatile biological treatment process available to the design engineer.

Historically, the activated sludge  process has been used in larger cities, where the ratio of
river assimilative capacity to waste load is small. More recently, there  has been a trend
toward  its use  by  smaller  communities to meet  the more stringent  requirements  of
regulatory agencies.

Existing overloaded conventional activated sludge plants pose a problem to the maintenance
of established water quality standards. Various modifications of the conventional process
developed over  the years permit reduced aeration detention time and higher volumetric
loadings. The applicability of these process modifications in the efficient upgrading of
existing plants will be examined and discussed in this chapter.

5.2  Activated Sludge Processes

Basically, the activated sludge process uses microorganisms in  suspension to oxidize soluble
and colloidal organics to C02 and H20  in the presence of molecular oxygen. During the
oxidation  process, a portion of the organic  material is synthesized into new cells. A part of
the synthesized cells then undergoes auto-oxidation in the aeration tank, the remainder
forming excess sludge. Oxygen is required in the process to support the oxidation and
synthesis reactions. To operate the process on a continuous basis, the solids generated must
be separated  in a clarifier with the major fraction being recycled to the aeration tank and
the excess sludge being withdrawn from  the clarifier underflow for  further handling and
disposal.

Due to the adaptability of the process, an activated sludge plant may be designed as a:

     1.   Conventional Plant
     2.   Step Aeration Plant
     3.   Contact Stabilization Plant
     4.   Complete  Mix Plant
     5.   Modified Aeration Plant
     6.   Two-Stage Plant
     7.   Pure Oxygen Activated Sludge Plant.

                                       5-1

-------
It is  possible to  design  a  plant  which  can be  operated  under several  of the above
modifications.

When compared with one another, these  plants each have advantages and  disadvantages.
Some achieve better BOD and SS removals than others, some cost less to construct, others
cost less to operate, some produce  less sludge and some obtain better nutrient removal. All
of these factors must be considered  in selecting a particular modification for use in a specific
upgrading situation.

     5.2.1   Conventional Activated Sludge

Design of a conventional activated  sludge system is usually based upon volumetric loadings
of 20 to 40 Ib BOD/day/1,000 cu ft and organic loadings (food to microorganisms, F/M) of
0.2 to 0.4 Ib BOD/day/lb MLSS. Sludge retention times (SRT) are normally between 5 and
15 days for this process which will achieve 85 to 95 percent BOD removals with proper
operation (1). SRT as used herein is defined as:

         	Ib MLSS under aeration
         (Ib SS wasted + Ib SS lost in final effluent)/day

A  schematic for a  conventional activated  sludge  plant  is  shown  on Figure 5-1. The
wastewater is commonly aerated for a period of 6 to 8 hours (based on the average design
flow) in the presence of a portion of the secondary sludge (2). The  rate of sludge return
expressed  as a percentage  of the  average wastewater design  flow is  normally  about
25 percent,  with minimum  and maximum rates  of 15 to  75 percent. A plug flow
configuration is achieved  in  rectangular tanks, designed so that the total tank length is
generally 5 to 50 times the width. Operating data from conventional activated sludge plants
are summarized in Table 5-1.

The  following  factors have been recognized  as limitations in the design and use of  a
conventional activated sludge plant:

     1.   Volumetric BOD loadings are limited to about 40 lb/day/1,000 cu ft because of
         poor load distribution.

     2.   Required aeration detention times are in the range of 6 to 8 hours.

     3.   A high  initial oxygen demand is experienced in the head end of the aeration tank;
         however, this can be offset by tapering the air supply.

     4.   There may be a lack of operational stability with extreme variations in hydraulic
         and organic loadings.
                                        5-2

-------
                             TABLE 5-1
OPERATING DATA FROM CONVENTIONAL ACTIVATED SLUDGE PLANTS
             BOD
Plant
Location

Michigan
Illinois
Ohio
Indiana
Oi
CO Maryland
Michigan
Wisconsin
Indiana

Maryland

California

Pennsylvania

Illinois
Influent Sludj
Flow Recy
mgd perce
5.0 32
288.0 48
86.9 25
14.9 30
3.9 32
8.0 16
7.6 52
3.9 31
5.5 29
8.0 26
7.7 25
47.0 45
48.0 34
3.44 20
2.71 26
200.1 38
1 Excluding sludge recycle.
Secondary
Influent
mg/1
182
129
92
161
254
118
157
134
113
155
148
157
181
175
161
119
Secondary
Effluent
mg/1
19
11
12
14
33
6
36
14
6
10
15
6
8
20
14
13
                        Aeration
                          Tank
                          MLSS
                          mg/1
                         1,844
                         1,930
                         2,180
                         2,420
                         1,808
                         2,801
                         1,094
                         2,625
                         1,680
                         2,040
                         2,240
                         2,449
                         2,111
                         1,180
                         1,160
                         2,775
Organic
Loading
Ib BOD/day
Ib MLSS
0.34
0.18
0.13
0.16
0.39
0.15
0.39
0.22
0.20
0.23
0.20
0.19
0.23
0.60
0.45
0.17
Volumetric
Loading
Ib BOD/day
l,000cuft
39
21
17
24
44
26
26
35
21
29
25
28
29
45
32
30
Aeration
Detention
Time1
hours
7.0
8.7
7.7
10.0
8.8
6.7
9.1
5.7
8.2
7.7
8.2
8.4
9.2
5.9
7.5
5.8
Air Supplied
per Ib of
BOD Removed
cuft
770
876
1,600
733
500
690
690
886
435
1,260
1,900
1,581
1,352
1,430
1,650
676
Secondary
BOD Removal
Efficiency
percent
90
92
87
91
87
95
77
90
95
94
90
96
96
89
91
89
Reference

3
3
3
3
3
3
3
3

4

5

6

7

-------
                                 FIGURE 5-1
               CONVENTIONAL ACTIVATED SLUDGE  PLANT
      RAW
      I/ASTEWATER

PRIMARY
CURIFIER
i
SLUDGE


^

AERATION ~N
^-T»NK +S
^ ^
c ^
w





FINAL
CLARIFIED

RETURN SLUDGE
—
EXCESS SLUDGE

EFFLUENT
Some of these limitations have stimulated the  development and use of various process
modifications, such as step aeration, contact stabilization, complete mix, modified aeration,
two-stage activated sludge  and the use of oxygen instead of air as a source of DO. These
process modifications are discussed in subsequent sections.

     5.2.2  Step Aeration

A typical flow diagram of a step aeration plant is illustrated on Figure 5-2. Unlike the
conventional plant, the influent wastewater is introduced at several points along the aeration
tank. However, the return sludge, which normally ranges from  25 to 75 percent of the
average  design flow,  is introduced at the  head  end of  the  aeration  tank  as in  the
conventional  system.  Distributing the  influent flow along the aeration  tank reduces the
initial oxygen demand usually experienced in the conventional plant. This permits a more
efficient utilization of the activated sludge biomass.

Step  aeration  plants  are  usually  designed  for  volumetric  loadings  of 40  to  60 Ib
BOD/day/1,000 cu ft at F/M's varying from 0.2 to 0.4 Ib BOD/day/lb  MLSS. SRT's are
similar to those of the conventional system. A step aeration system will achieve 85 to
95 percent  BOD removal.  Operating data  from  step aeration plants  are summarized in
Table 5-2.
                                       5-4

-------
                                        TABLE 5-2
                OPERATING DATA FROM STEP AERATION ACTIVATED SLUDGE PLANTS
ROD
Plant
Location

New York
New York
New York
New York
New York
New York
Maryland
Indiana
Indiana
Indiana
Pennsylvania
Connecticut
Ontario, Canada
Influent
Flow
mgd
110.0
20.7
92.0
50.0
95.0
31.0
16.9
12.8
19.3
34.3
178.3
37.7
183.0
Sludge
Recycle
percent
24
49
35
28 '
28
28
24
92
50
52
28
34
16
Secondary
Influent
mg/1
74
137
100
120
115
100
140
124
139
131
87
121
115
Secondary
Effluent
mg/1
12
3
8
6
16
12
11
15
17
18
12
17
11
Aeration
Tank
MLSS
mg/1
1,170
3,520
1,110
3,300
3,300
4,400
2,120
2,900
2,750
3,360
2,780
2,540
1,500
Organic
Loading
Ib BOD/day
Ib MLSS
0.49
0.10
0.42
0.31
0.28
0.13
0.54
0.19
0.22
0.22
0.23
0.27
0.40
Volumetric
Loading
Ib BOD/day
l,000cuft
36
23
30
71
58
37
58
33
41
45
40
43
38
Air
Supplied
cu ft/gal
_
-
_
0.43
0.54
0.59
—
_
_
_
0.58
2.05
1.6
Air Supplied
per Ib of
BOD Removed
cuft
910
910
933
_
_
-
_
1,240
1,080
911
927
2,353
1,580
Aeration
Detention
Time'
hours
3.1
8.4
4.9
2.5
2.9
4.2
3.8
5.3
5.0
4.3
3.2
4.3
4.5
Secondary
BOD Removal
percent
84
94
92
94
86
90
92
89
88
86
86
86
90
Reference

8
8
8
8
8
8
4
8
8
8
9
10
11
1 Excluding sludge recycle.

-------
                                   FIGURE  5-2
                           STEP AERATION  PLANT
                                 AERATION  TANK
RAW
WASTEWATER
EFFLUENT
                SLUDGE
                                                                          EXCESS  SLUDGE
 Biological  oxygen requirements  for  step  aeration are similar to those of conventional
 activated  sludge. However, because  of  more  uniform load  distribution, the actual  air
 supplied is more effectively utilized and the quantity may be somewhat reduced. Since the
 detention times are lower  than for the conventional  system,  the air piping and diffusion
 equipment must be modified to supply approximately the conventional volume of air to a
 tank approximately one-half the conventional size.

 In the conventional plant, the MLSS concentration is relatively constant throughout the
 aeration tank; in the step aeration plant, the MLSS concentration decreases at each point of
 influent addition. The reason that a step aeration system can be  operated at the same F/M as
 a conventional system,  but in about one-half to two-thirds of the aeration tankage, is the
 higher average  MLSS  concentration gained by  the incremental addition of flow. The step
 feed concept permits the utilization of the same size  clarifiers as the conventional system
 because the aerator effluent SS concentrations are similar. This  principle is shown on Figure
 5-3. The  concept can  also be  used to decrease the final clarifier solids loading while
 maintaining the same average aerator MLSS concentration.

      5.2.3  Contact Stabilization

 The principles  of the contact stabilization modification were initially demonstrated in the
 upgrading  of an existing hydraulically overloaded conventional plant (12). As in the step

                                        5-6

-------
                           FIGURE  5-3

     COMPARISON OF SOLIDS LOADING ON THE FINAL CLARIFIER

         FOR  CONVENTIONAL AND STEP AERATION PLANTS
   MODE 1 - CONVENTIONAL
1
25% RETURN
SLUDGE
SS = 10,000 mg/|
100% PRIMARY EFFLUENT
r
A
2,000
B
2,000
C
2,000
D
2,000
AERATOR
EFFLUENT
SS = 2,000 mg/l
                     AVERAGE AERATOR MLSS CONCENTRATION
                               2,000 mg/l
MODE 2 - STEP  AERATION   25% PRIMARY EFFLUENT/PASS
1
25% RETURN
SLUDGE
k.

SS = 10,000 mg/l

r i
A



5,000
> i
B



3,333
r 1
C



2,500
r
D



2,000


AERATOR
EFFLUENT
SS = 2,000 mg/l
                     AVERAGE  AERATOR MLSS CONCENTRATION
                               3,208 mg/l
            NOTE:   EXAMPLE  ASSUMES NEGLIGIBLE SS IN  PRIMARY  EFFLUENT
                                 5-7

-------
aeration process, this modification involves a change in the feed location to the aeration
tanks.  Volumetric BOD loadings, F/M, SRT and removal efficiency are similar to those of
the step aeration system. Sludge return ratios vary from 25 to 100 percent of the average
design flow. A schematic for the contact stabilization process is shown on Figure 5-4.
                                 FIGURE 5-4
                     CONTACT STABILIZATION PLANT
  RAW
  WASTEWATER
REAERATION
   TANK
CONTACT
 TANK
                                               RETURN
                                                                        EFFLUENT
                                     EXCESS
                                               SLUDGE
                                                                  SLUDGE
Laboratory studies and field work have demonstrated that wastewater BOD in the colloidal
or insoluble state is rapidly removed from wastewater in a relatively short contact time by
the combined mechanism of biological sorption, synthesis  and flocculation. This may offer
the  possibility  of a  reduction in  plant  volume for  wastewaters  exhibiting  these
characteristics. In the contact stabilization process, after the biological sludge is separated
from  the  wastewater in  the clarifier, the concentrated sludge is separately aerated in a
reaeration tank.  Here the flocculated and absorbed BOD is stabilized. In addition to a
smaller total aeration volume than required with the conventional activated sludge process,
the contact stabilization process has the advantage of being able to handle greater shock and
toxic  loadings because of the biological buffering capacity of the reaeration tank, and the
fact that at any given time the majority of the activated sludge is isolated from  the main
stream of the plant flow. Operating data from  contact stabilization plants are summarized in
Table 5-3.

The detention times required in the sludge reaeration and contact tanks are interdependent.
The contact tank detention time  also depends on wastewater characteristics. For domestic
wastewaters containing normal  amounts of insoluble and colloidal BOD,  contact  tank
                                       5-8

-------
                                                        TABLE 5-3
                 OPERATING DATA FROM CONTACT STABILIZATION ACTIVATED SLUDGE PLANTS

Plant
Location
Texas4






New Jersey

Influent
Flow
mgd
6.3
8.3
7.6
7.6
8.6
6.7
6.5
2.5

Sludge
Recycle
percent
46
35
39
39
39
55
56
70


BOD
Influent
mg/1
330
267
300
331
299
354
358
3125
Effluent
mg/1
22
17
21
19
18
23
21
30
Contact
Tank
MLSS
mg/1
2,321
1,894
1,698
1,377
1,829
2,432
2,533
4,000
Contact
Tank
Aeration
Detention
Timel
minutes
61
46
51
51
45
58
59
100
Reaeration
Tank
MLSS
mg/1
7,072
8,018
7,266
6,050
6,084
6,930
6,917
6,700
Reaeration
Tank
Aeration
Detention
Time2
minutes
392
391
383
383
338
308
312
144

Organic
Loading ^
Ib BOD/day
Ib MLSS
0.34
0.32
0.36
0.49
0.49
0.39
0.38
0.32

Volumetric
Loading **
Ib BOD/day
l,000cuft
123
131
135
149
152
140
138
104
Secondary
BOD Removal
Efficiency
percent
93
94
93
94
94
93
94
90

Reference

12






13
Based on influent flow excluding sludge recycle.
Based on sludge recycle flow.
Based on contact and reaeration volume.
No primary treatment.
Raw wastewater. Organic and volumetric loading computed assuming 25 percent BOD removal in primary clarifiers.

-------
detention times  of about 0.5  to  1  hour are employed based on average plant flow, with
reaeration times  of 2 to 4 hours based on sludge recycle flow. Total air requirements for this
process are  similar to those of conventional activated sludge and are normally divided
equally between  the contact and reaeration tanks.

Most  of the benefits of contact stabilization are achieved  if the organic load is present
mainly in the colloidal state. Generally, the greater the fraction of soluble BOD, the greater
the required contact time. As a result, the  required total aeration volume of this process
approaches that  of the conventional process as the relative amount of soluble BOD in the
wastewater increases.

Ten-States Standards require significantly higher  contact and reaeration times than those
previously cited, especially for smaller  sized plants as indicated in Table 5-4 (14). These
standards also specify an F/M  of 0.2 to 0.5 Ib BOD/dayAb MLSS and a volumetric loading
of 30 to 50 Ib BOD/day/1,000 cu  ft.  Although these values  were, no doubt, selected to
compensate for the extreme flow variations that occur at small plants, their use may result
in poor quality  effluents  (15). McKinney (16) has indicated that in typical conservatively
designed contact stabilization plants, all of the stabilization of the organic matter in the raw
wastewater occurs in the contact zone; therefore, only endogenous respiration occurs in the
reaeration tank.  This situation often results in poor  sludge settling characteristics in the
secondary clarifier.
                                     TABLE 5-4
                      SUGGESTED DESIGN GUIDELINES (14)

Plant Design
    Flow            Contact Time!        Reaeration Time^      Aerator Loading^
     mgd               hours                    hours             Ib BOD/day
                                                                   l,000cuft

  to 0.5                   3.0                     6.0                  30
0.5 to 1.5               3.0 to 2.0              6.0 to 4.0            30 to 50
1.6 and up              2.0 to 1.5              4.0 to 3.0               50
 •*•  Based on average design flow.
 2  Based on average sludge recycle flow.
 3  Based on total aeration capacity (reaeration plus contact).
                                        5-10

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     5.2.4  Complete Mix

In  the  complete  mix process, influent wastewater and recycled sludge are introduced
uniformly throughout the aeration tank, as indicated on Figure 5-5. This flow distribution
results in a  uniform oxygen  demand throughout the aeration tank which adds some
operational stability when treating slug loads of industrial wastes (17). This process may be
loaded to levels comparable to those of the step aeration and contact stabilization processes
with only slight reductions from  the removal efficiencies of those processes.  The reduced
efficiency occurs because there is a small amount of short circuiting in the complete mix
aeration tank. Operating data from plants utilizing complete mix are presented  in Table 5-5.

     5.2.5  Modified Aeration

The flow scheme  for modified  aeration is similar to that of conventional activated sludge
(Figure 5-1) with the exception  that this process is frequently used without primary settling.
In this system, organisms are brought into contact with the incoming wastes for  a brief
period of sorption and synthesis.  Modified aeration plants  are  designed to  process
volumetric BOD loadings varying from 75 to 150 Ib BOD/day/1,000 cu ft, and will achieve
60 to 75 percent BOD removals under these loading conditions. F/M's normally range from
1.5 to 5.0 Ib  BOD/day/lb MLSS, and SRT's vary from 0.2 to 0.5 day. For proper operation,
the return sludge rate normally  ranges from 5 to 15 percent of the influent flow (1) (24).
Aeration requirements are less  than those of the conventional system due to the reduced
biological activity.

Modified aeration  has been proposed as the first stage in a two-stage aeration system where
the second stage will be used for nitrification. Two advantages of using modified aeration in
the first stage are a substantial cost savings in aeration facilities and an SRT sufficiently low
to preclude nitrification. The absence of nitrification and the partial concentration damping
afforded  by  mixing in  the modified  aeration tank results in a more uniform ammonia
concentration in the influent to  the nitrification system (1) (25).

When modified aeration is used  as the first stage of  a two-stage system, the first-stage
effluent BOD  should be sufficiently high to permit  good sludge flocculation and settling in
the second-stage clarifier, but not  so high as to cause a  high heterotroph growth rate and a
subsequent washout of  the nitrifying population in the second stage. The upper limit will
depend  on the BOD/NH4 of  the  second-stage influent. At the U. S. EPA District  of
Columbia Pilot Plant, addition  of alum helped  to maintain the BOD  of the first-stage
effluent within the desired range of 30-60 mg/1 (25). Operation of the full scale District of
Columbia Wastewater Treatment Plant has also shown  that oxygen requirements  for the
modified process are significantly less than for other activated sludge systems  and that the
sludge exhibits good settling qualities (24) (25).

Operating data from modified aeration plants are shown in Table 5-6.

                                         5-11

-------
                           FIGURE  5-5
                      COMPLETE MIX PLANT
RAW
WASTEWATER OR 	
PRIMARY EFFLUENT
                  T  fttftt
                    AERATION TANK
                  ,  i   i  A  i 11 11
                           RETURN SLUDGE
EFFLUENT
                                                      EXCESS SLUDGE
                                5-12

-------
                                                     TABLE 5-5
                          OPERATING DATA FROM COMPLETE MIX ACTIVATED SLUDGE PLANTS
CO
BOD
Plant
Location

Illinois



Minnesota
Nebraska






Nebraska


Nebraska

Texas



Influent
Flow
mgd
1.6
1.94
1.91
1.55
9.8
4.1
4.3
4.6
4.2
4.8
5.8
5.8
3.4
4.1
5.0
0.38
0.43
0.29
0.29
0.30
0.37
Sludge
Recycle
percent
21
21
25
25
158
87
66
62
65
64
37
49
50
100
200
26
40
82
100
145
100
Secondary
Influent
mg/1
102
80
80
108
177
260
270
290
300
350
240
105
250
270
280
225
227
115
141
123
180
Secondary
Effluent
mg/1
8
13
19
18
15
26
16
17
22
34
37
14
15
13.5
6
25
32
9
25
19
17
Aeration
Tank
MLSS
mg/1
6,500
6,000
6,500
6,300
3,750
4,400
4,460
3,920
4,020
4,280
4,040
3,400
4,500
4,500
4,500
4,230
5,460
3,820
5,000
5,540
5,620
Organic
Loading
Ib BOD/day
Ib MLSS
0.17
0.20
0.18
0.20
0.31
0.27
0.32
0.43
0.41
0.51
0.49
0.24
0.27
0.32
0.38
0.48
0.42
0.21
0.20
0.16
0.29
Volumetric
Loading
Ib BOD/day
1,000 cu ft
74
73
72
79
73
80
97
120
110
132
114
50
80
97
116
126
142
50
62
54
103
Aeration
Detention
Time1
hours
2.2
1.8
1.8
2.2
3.6
4.5
4.3
4.0
4.4
3.8
3.2
3.2
5.0
4.4
3.8
2.6
2.5
3.7
3.7
2.2
3.0
Air Supplied
per Ib of
BOD Removed
cuft/lb
1,670
1,900
1,380
1,290
- 2
540
450
500
480
560
570
900
500
500
560
-
-
-
-
-
-
Secondary
BOD Removal
Efficiency
percent
92
84
76
83
92
90
94
94
93
90
85
87
94
95
98
89
86
92
82
85
91
Reference

18



19
20






21


22

23



        Excluding sludge recycle.
        Mechanical aerators.

-------
                                                TABLE 5-6
                    OPERATING DATA FROM MODIFIED AERATION ACTIVATED SLUDGE PLANTS
Ul
BOD
Location

New York
Florida





Washington, D. C.



Influent
Flow
mgd
152.0
39.8
42.0
55.8
49.6
53.3
59.2
269.0
273.0
276.0
277.0
Sludge
Recycle
percent
20
8
7
6
6
8
10
12
12
13
11
Secondary
Influent
mg/1
202
205
145
125
165
175
185
154
163
151
146
Secondary
Effluent
mg/1
24
62
59
38
66
62
62
49
44
51
39
Aeration
Tank
MLSS
mg/1
2,000
360
305
275
345
310
430
606
704
775
714
Organic
Loading
Ib BOD/day
IbMLSS
0.9
5.1
4.6
6.2
4.2
4.9
4.3
2.8
2.7
2.3
3.3
Volumetric
Loading
Ib BOD/day
l.OOOcuft
106
138
93
125
127
107
126
105
121
113
134
Air Supplied
per Ib of
BOD Removed
cuft
-
805
1,171
992
1,065
1,061
858
669
739
863
639
Air
Supplied
cu ft/gal
_
0.96
0.84
0.72
0.88
1.0
0.88
0.53
0.68
0.70
0.52
Aeration
Detention
Timel
hours
2.6
2.3
2.2
1.7
2.5
2.3
2.0
2.1
2.0
2.3
1.5
Secondary
BOD Removal
Efficiency
percent
88
68
59
69
60
64
66
68
73
66
73
Reference

26
27





24



     Excluding sludge recycle.

-------
     5.2.6   Two-Stage Activated Sludge

A two-stage activated sludge  plant  is essentially two separate activated sludge processes
operating in series, as shown on  Figure 5-6.  The two separate sludge systems permit the
development of two specialized microbial populations. In the first stage, the bulk of the
carbonaceous material is removed by a wide variety of heterotrophic organisms commonly
found in activated sludge. The reduction of BOD in the first stage permits an accumulation
of the slower growing nitrifying organisms in the second stage which oxidize the ammonia
nitrogen to the nitrate form.

The  operating data presented in Table 5-7 indicate that the second-stage effluent BOD is not
sufficiently better than for alternative single stage systems previously discussed to warrant
consideration of this approach  unless nitrification  is  also  required. The advantage of
satisfying the oxygen demand of the ammonia nitrogen normally discharged should not be
underestimated since this can amount to as much as 70 percent of the total oxygen demand
of the plant secondary effluent (30). The high air requirement in Ib air supplied/lb BOD
removed in the second stage includes the air used for ammonia oxidation.

     5.2.7   Pure Oxygen Activated Sludge

The  use of pure oxygen for activated sludge treatment has become competitive with the use
of air due to the development of efficient oxygen dissolution systems. Efficient utilization
of oxygen can be achieved by two methods:

     1.   Oxygenation  is performed in a staged, covered reactor in which oxygen gas is
         recirculated within the  system until it reaches a level of impurity at which it can
         no longer  be used.  This method is presently used in several municipal  and
         industrial treatment plants, and is shown schematically on Figure 5-7 (31).

     2.   Oxygenation is performed in an open reactor in which extremely fine diffusers are
         utilized to develop small oxygen gas bubbles that are completely dissolved before
         breaking surface in normal-depth  tanks  (31).  This approach has not  yet  been
         implemented in full scale treatment plants.

The  use of pure oxygen has the advantages of reduced reactor volume, high effluent DO and
effective odor control.  Possible additional advantages include less waste sludge production
and  higher waste sludge concentrations. Disadvantages include the increased complexity of
operation of both oxygen generation and dissolution systems and excessive pH depression in
low  alkalinity wastewaters when alum is added for phosphorus removal or when nitrification
occurs.

Oxygen gas can be produced at the  plant site by either a cryogenic unit or, in the case of
smaller  plants,  a  molecular  sieve  device.  A  liquid  oxygen  storage tank  is  generally

                                         5-15

-------
                                 FIGURE  5-6
                  TWO-STAGE  ACTIVATED  SLUDGE PLANT
               FIRST-STAGE
              AERATION TANK
RAW
WASTEWATER
OR PRIMARY
EFFLUENT
SECOND-STAGE
AERATION TANK
                          EFFLUENT
                                                             EXCESS SLUDGE
                              EXCESS SLUDGE
                                     5-16

-------
                                                       TABLE 5-7
         OPERATING DATA FROM TWO-STAGE ACTIVATED STJJDGE PLANTS
Ist-STAGE PERFORMANCE
Plant
Location

Pennsylvania




Pennsylvania



Ol
1— '
-J
Sludge
Recycle
percent
24
11
23
29
14
19
19
19
19
19
19


BOD
Influent Sludge Ist-Stage Ist-Stage
Flow Recycle Influent Effluent













mgd percent
2.27 27
2.24 19
1.47 48
1.28 46
2.10 27
0.21 56
0.21 56
0.21 56
0.21 56
0.21 56
0.21 56
BOD
2nd-Stage 2nd-Stage
Influent Effluent
mg/1
36
23
32
33
41
12
29
19
25
13
10
mg/1
12
11
19
19
17
7
8
4
21
8
7
mg/1
204
220
271
249
223
138
266
104
133
110
mg/1
36
23
32
33
41
12
29
19
25
13
Aeration
Tank
MLSS
mg/1
3,760
2,020
2,350
1,980
1,920
3,150
3,150
2,650
2,650
2,650
134 10 2,650
2nd-STAGE PERFORMANCE
Aeration
Tank
MLSS
mg/1
1,520
1,600
820
800
935
1,500
1,510
1,350
1,350
1,350
1,350
Organic
Loading
Ib BOD/day
Ib MLSS
0.34
0.21
0.36
0.34
0.59
0.21
0.47
0.35
0.49
0.24
0.20
Volumetric
Loading^
Ib BOD/day
1,000 cuff
33.0
21.0
19.0
17.0
35.0
20.5
44.0
29.0
41.5
20.5
17.0
Organic
Loading
Ib BOD/day
Ib MLSS
0.86
1.56
1.10
1.02
1.56
1.0
1.9
0.92
1.20
0.95
1.10
2nd-Stage
BOD Removal
Efficiency
percent
67.0
53.7
40.4
42.5
59.0
41.6
72.2
79.0
16.0
38.5
30.0
Ist-Stage
Volumetric BOD Removal
Loading Efficiency
Ib BOD/day
l,000cuft
182
197
160
128
188
205
375
154
196
158
186
Air Supplied
per Ib of
BOD Removed2
cu ft
4,600
4,600
4,600
4,600
4,600
4,600
4,100
4,100
4,100
4,100
4,100
percent
82
89
87
83
82
96
89
82
81
88
93
Aeration
Detention
Timel
hours
1.6
1.7
2.5
2.9
1.8
-
0.7
0.7
0.7
0.7
0.7
Air Supplied
per Ib of
BOD Removed
cuft
1,180
1,180
1,180
1,180
1,180
820
820
820
820
820
820
Overall
Secondary
BOD Removal
percent
94
95
93
93
93
95
96
96
81
93
95
Aeration
Detention
Time1
hours
1.6
1.7
2.5
2.9
1.8
0.7
0.7
0.7
0.7
0.7
0.7
Reference

28




29





Excluding sludge recycle.
Including that needed for ammonia oxidation.

-------
                          FIGURE 5-7
SCHEMATIC DIAGRAM OF MULTI-STAGE OXYGEN  AERATION SYSTEM (31)
          AERATION TANK  COVERS
-SURFACE  AERATOR
          ^MIXER  DRIVE
OXYGEN
FEED GAS -*•-
WASTEWATER
FEED —*-Z
RECYCLE
S L II n R F 	 *•




3
-**-+



L_n W

-o

f
/

J
^^\, 	 	

->
L

-, / Jt EXHAUST
If | 1 1 	 =*• R4C

Lx*^v
C. y^-^—
i
i
I
I
I
1
C>0
\\
I
i
i
i
i
i
i
	 1
i
i
i
i
i
i
i
i
*
[1 BAFFLE




MIXED LIQUOR
=-»• EFFLUENT TO
CLARIFIER



                    SUBMERGED PROPELLER (OPTIONAL)
                               5-18

-------
recommended to provide  standby and peak load capacity. In the covered reactor design,
oxygen transfer and mixing are accomplished with surface aerators for tank depths up to 15
to 18  feet (as shown on  Figure 5-7) or alternatively with submerged turbine-spargers and
recirculating gas compressors for deeper tanks.

Pure oxygen systems are normally designed to handle volumetric BOD loadings ranging from
150 to 225 Ib BOD/day/1,000 cu ft, but in some instances much higher loadings have been
reported (31)(32)(33)(34)(35)(36).

The F/M may vary from 0.07 to more than 1.0, but normal design values range from 0.5 to
0.8 (31)(32)(33). Table 5-8 summarizes operating data from plants utilizing pure oxygen.

Pure oxygen  pilot plant studies  have  indicated that at a  given F/M oxygen consumption
increases with higher COD/BOD ratios, as shown on Figure 5-8 (33). This increase in oxygen
requirements may be  attributed to the biodegradation of part  of the COD which is not
measured in  the standard BOD test. Oxygen requirements for pure oxygen systems for
typical domestic wastewaters normally range from 0.6 to 0.7 Ib 02/lb COD removed in the
system (31).

Since the pure oxygen system  operates at high MLSS concentrations, the clarifier will often
be subjected to increased solids loadings. Clarifier solids loadings for pure oxygen and other
systems are discussed in  detail  in Chapter 6. Clarifier underflow SS concentrations may
range from 1.0 to 3.5 percent, depending on the sludge composition and the clarifier sludge
detention time.

5.3 Activated Sludge  Design Considerations

Initially, plant operators, through a trial and error procedure, developed the most efficient
operating criteria for conventional activated sludge plants as well as for the modifications of
the process. Out of this evolution, basic design criteria were  developed. These criteria are
still in use today and, in  many cases, are rigidly adhered to by regulatory agencies.

A limitation of these design criteria is that volumetric loading (Ib BOD  applied/day/1,000 cu
ft) has been considered  preferable, for design purposes, to organic or F/M loading (Ib BOD
applied/day/lb MLSS). Many of the modifications have shown  that  organic loading is an
important  consideration;  in fact,  a  higher  volumetric  loading has been  achieved for
modifications  of the  conventional process  at the  same organic loading used  in  the
conventional process.

Basic parameters of interest in the design of an activated sludge process are:

    1.  BOD removal rates
    2.  Oxygen and air requirements

                                        5-19

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                                              TABLE 5-8
                    OPERATING DATA FROM PURE OXYGEN ACTIVATED SLUDGE PLANTS
BOD
Plant
Location

New York






Washington, D. C.


New York






Virginia
Indiana
Influent
Flow
mgd
1.33
1.29
1.38
1.19
1.36
1.41
1.64
0.07
0.10
0.10
20.8
17.7
15.1
20.6
25.3
30.0
35.4
11.0
4.4
Sludge
Recycle
percent
53
54
56
45
42
38
32
50
31.5
38
30
40
50
45
44
34
25
14
50
Secondary
Influent
mg/1
237
221
249
283
270
304
269
115
102
116
156
157
152
171
213
218
212
158
84
Secondary
Effluent
mg/1
22
18
19
19
9
11
15
19
12
14
9
21
17
17
22
21
23
14
10
Aeration
Tank
MLSS
mg/1
5,890
6,810
6,840
5,890
7,400
5,700
5,560
4,140
6,000
8,120
4,890
5,060
4,000
3,875
4,550
4,155
3,090
3,8202
5,150
Organic
Loading
Ib BOD/day
Ib MLSS
0.35
0.27
0.38
0.37
0.31
0.47
0.50
0.31
0.25
0.22
0.55
0.47
0.46
0.74
0.95
1.30
1.96
0.483
0.15
Volumetric
Loading
Ib BOD/day
1,000 cu ft
126
115
140
132
142
166
170
80
90
108
163
140
110
178
272
331
379
113
50
Aeration
Detention
Timel
hours
2.9
3.0
2.8
3.3
2.9
2.8
2.4
2.2
1.7
1.7
1.4
1.7
2.0
1.4
1.2
1.0
0.8
2.1
2.5
Secondary
BOD Removal
Efficiency
percent
91
92
93
92
97
97
94
84
88
88
94
87
89
90
90
90
89
91
88
Reference

37






38


26






39
40
1 Excluding sludge recycle.
2 Aeration tank MLVSS.
3 Ib BOD/day/lb MLVSS.

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                 FIGURE 5-8

OXYGEN CONSUMPTION FOR PURE OXYGEN SYSTEMS
     RELATED TO ORGANIC LOADING (F/M) (33)
    0.2
0,4    0,6    0.8

    F/M,  LB BOD/DAY/LB MLVSS
                     5-21

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     3.   Sludge production
     4.   Oxygen transfer rates in wastewater
     5.   Nutrient requirements
     6.   Separation and return of activated sludge.

     5.3.1  BOD Removal Rates

Eckenfelder (41) has indicated that a linear arithmetic relationship exists between BOD
removal rate (mg BOD/hr/g VSS) and effluent BOD (mg/1), as shown on Figure 5-9 for
typical data from various complete-mix activated sludge plants. The variations in the BOD
removal relationship on Figure 5-9 are influenced by the presence of various proportions of
domestic and industrial wastes.

Using Figure 5-9, the detention time required to achieve  a specific effluent BOD can be
obtained as follows:

         .  _  La—Le
               Sar'
     where:
         t = Aeration tank detention time, hours
        La = Influent BOD to aeration tank, mg/1
        Le = Clarifier effluent BOD, mg/1
        Sa = MLVSS, mg/1
         r' = BOD removal rate, mg BOD/hr/g VSS

Weston (42) developed a log-log relationship between a BOD removal rate constant (r) and a
loading ratio (L0/S0); r and L0 are defined by the following equations:

         r _ Lo~Le

    where:
        T   —    i
        L° "    1 + R

         r =  BOD removal rate constant,
        Lo =  BOD of wastewater after mixture of raw wastewater or
              primary effluent with sludge recycle, mg/1
        Le =  Clarifier effluent BOD, mg/1
        te =  Aeration tank detention time, minutes (including recycle)
        Lj =  Raw wastewater or primary effluent BOD, mg/1
        R =  Sludge recycle as percent of influent flow
        S0 =  MLVSS, mg/1

                                       5-22

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                       FIGURE  5-9

              BOD REMOVAL CHARACTERISTICS

FOR VARIOUS COMPLETE MIX ACTIVATED  SLUDGE PLANTS (41)
    100
CO
oo
    60
    40
    20
READILY REMOVABLE
ORGANICS
                                      RESISTANT
                                      ORGANICS
               20       40       60       80

                    EFFLUENT BOD (rag/1)
                               00
                          5-23

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The aeration tank  detention time is related to process efficiency (E, percent) and BOD
removal rate (r) by the following equation:
         te  =
                100-E       r

     where:

         E   = ^5_  x  100
                 Lo

Operating data  from  over  20 plants  with various  activated sludge modifications were
analyzed using the Weston procedure to determine BOD removal rate constants. Operating
data for this analysis  were taken from references (3)(4)(8)(12)(13)(15)(18)(21)(22)(23)
(28)(29)(37)(38)(43)(44)(45)(46)(47).  The  results  are summarized on Figure 5-10. It
should be pointed out that the BOD removal rate curves represent only average kinetics with
no temperature  correction  applied, and the various loading ratios were determined using
MLSS,  not  MLVSS.  For these  reasons, these curves  are  not recommended for  design
purposes, but are included merely to illustrate the relative kinetic rates of the modifications.
The presence of significant quantities of industrial wastes, which may have different removal
rate characteristics, would modify or displace the curves shown.

The BOD removal rate curve  for the second stage of a two-stage process on Figure 5-10
represents data obtained from three two-stage biological treatment plants (28)(29)(45). Two
of these plants use activated sludge as the first  stage,  while the third plant uses trickling
filtration. The BOD removal rates for second-stage treatment are markedly lower than those
of conventional activated sludge because the organics remaining in the first-stage effluent are
more resistant to biological degradation than those entering a conventional plant.

     5.3.2   Oxygen and Air Requirements

Table  5-9 contains ranges  for oxygen and air required per Ib of BOD  removed for the
activated sludge modifications previously discussed. These values represent overall process
requirements. The total amount of oxygen required will  vary within  the ranges shown
depending upon  the F/M, increasing  as  F/M  decreases. In diffused  air systems, the air
requirements  will vary  depending on the  oxygen  transfer efficiency  of the diffusers
employed. The designer must recognize that the various process modifications will require
different air  and oxygen distribution patterns. Also,  the values shown in the table do not
include allowances for nitrification or for other plant air  requirements.
                                        5-24

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                          FIGURE 5-10
      RELATIONSHIP BETWEEN BOD  REMOVAL RATE CONSTANTS
AND LOADING RATIOS FOR THE ACTIVATED SLUDGE MODIFICATIONS
   003
                                            LEGEND


                                             •  CONVENTIONAL PROCESS

                                             •  STEP  AERATION  PROCESS

                                             O  COMPLETE MIX PROCESS

                                             4*  PURE  OXYGEN  PROCESS

                                             *  CONTACT STABILIZATION
                                                PROCESS (OVERALL r)

                                             A  CONTACT STABILIZATION
                                                PROCESS (CONTACT r)

                                             •  SECOND OF TWO-STAGE
                                                PROCESS
              02.   ,03  .04 .05

                 LOAD RATIO  Lo
. 10
                                5-25

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                                    TABLE 5-9
                     OXYGEN AND AIR REQUIREMENTS FOR
                      ACTIVATED SLUDGE MODIFICATIONS

       Process          Ib Q2/lb BOD Removed      Standard cu ft Air/lb BOD Removed

Conventional               0.8-1.1                         800 - 1,500
Step Aeration               0.7 - 1.0                         800 - 1,200
Contact Stabilization        0.7 - 1.0                         800 - 1,200
Complete Mix               0.7 - 1.0                         800 - 1,200
Modified Aeration           0.4 - 0.6                         400 -  800
Pure Oxygen                0.8 - 1.4                             -


     5.3.3   Sludge Production

Normally,  the  activated  sludge processes  generate excess sludge in  relation to the F/M
maintained in  the system (48). For  normal ranges  of  F/M  (0.3 to 0.5 Ib BOD/day/lb
MLVSS), the  quantity of excess sludge produced in air activated  sludge systems varies
between 0.5 to 0.7 Ib VSS/lb BOD removed (21)(43)(49). The quantity of sludge increases
with increasing F/M, since  at higher organic  loadings  less  auto-oxidation occurs. The
quantity of sludge generated is also  temperature  dependent, decreasing with increasing
wastewater temperature. Data  reported  by  various  studies  indicate that  excess sludge
production in pure oxygen activated sludge systems may be slightly less than in air activated
sludge systems when operating at similar F/M's (31)(32)(49).

     5.3.4   Oxygen Transfer Rates in Wastewater

Oxygen  transfer rates  in  wastewater are  affected  by various physical  and  chemical
parameters, e.g., temperature, degree of mixing, liquid depth in the aeration tank, oxygen
composition of aerating gas, type of aeration device, operating DO, barometric pressure and
chemical characteristics of the wastewater. The major area often overlooked in the past by
design engineers has  been the effect of an industrial  waste on the overall oxygen transfer
rate of a system. Where the industrial waste makes up a large proportion of the total flow, it
is desirable to verify oxygen transfer  rates in the laboratory for proper sizing of aeration
units.

Oxygen transfer capability for several aeration systems are indicated in Table 5-10. The
transfer capability for each system  at standard conditions are approximate  and may vary
somewhat for  different makes and models. The effective transfer rates shown are for the
                                       5-26

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specific field conditions listed in the table footnote, and should not be used for design
purposes. The relative effective transfer rates will vary considerably for different field
conditions, and must be determined for the design conditions at the specific installation.
                                    TABLE 5-10
                      OXYGEN TRANSFER CAPABILITIES OF
                          VARIOUS AERATION SYSTEMS
            Type of Aeration System
Diffused-Air, Fine Bubble
Diffused-Air, Coarse Bubble
Mechanical Surface Aeration, Vertical Shaft
Agitator-Sparger System
Pure Oxygen (50)
   Mechanical Surface Aeration + Cryogenic Generation
   Mechanical Surface Aeration + PSA Generation
   Agitator-Sparger System + Cryogenic System
Standard
Transfer
  Rate1
   2.5
   1.5
   3.2
   2.1
Effective
 Transfer
  Rate2
                                                           Ib O2/hp-hr   Ib 02/hp-hr
    1.4
    0.9
    1.8
    1.2

    2.6
    1.9
    2.2
1  Transfer Rate at standard conditions, i.e., tap water, 20 deg C, 760 mm barometric
   pressure and initial DO = O mg/1.
2  Transfer rate at following specific field conditions
     x =  0.85
     6 =  0.9
     t =  15 deg C
     Altitude = 500 ft
     Operating DO = 2 mg/1 for air aeration, 6 mg/1 for oxygenation
     5.3.5   Nutrient Requirements

It is necessary that sufficient nitrogen and phosphorus be present in a wastewater so that
neither nutrient  becomes the limiting factor in microbial growth reactions encountered in
the  activated  sludge  process.  Normally, supplemental  nutrients are not required for
municipal wastewater treatment plants because adequate quantities are available in domestic
wastewaters to make organic carbon the limiting macronutrient. For optimum operation of
the activated sludge process, the minimum ratios of raw wastewater N:BOD and P:BOD are
3:60 and 1:60, respectively (51).
                                       5-27

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     5.3.6   Separation and Return of Activated Sludge

In the past, the importance of the final clarifier as an integral unit of the activated sludge
process has not been fully recognized. Improperly designed final clarifiers have resulted in
inefficient BOD and SS removals in many activated sludge plants.

Doubt has been raised as to the advisability of designing clarifier overflow rates solely on the
basis of average or nominal design flow. It is recommended that final clarifiers be designed
on the basis of maximum daily flow rates. This technique provides greater protection against
system solids washout,  at the expense of a somewhat larger clarifier. Recent work by Dick
(52) also indicates that solids loading and  thickening aspects must be considered  in  the
design of final clarifiers. Typical  design parameters for final clarifiers are presented in Table
6-2.

Control of sludge  recycle and wasting rates is the most important operational tool available
to the  plant  operator for intelligently managing the sludge  inventory  and maintaining
optimum loading  conditions and sludge settling characteristics. Therefore,  it is extremely
important to  provide sufficient sludge recycle  capacity to give the operator the required
operating flexibility to  handle the highly variable and fluctuating waste loads characteristic
of many plants.  Excessive  detention of sludge within  the  final clarifier  will result in
deterioration of the sludge.

Three techniques which have been used to control sludge recycle are:

     1.   Automatically varying  the recycle  flow to maintain a set relationship to influent
         flow

     2.   Setting the  recycle flow at a constant rate based upon the average daily flow

     3.   Controlling the  recycle  pumps  with a sludge  blanket sensor set to maintain a
         predetermined blanket  level in the final clarifier.

A firm sludge recycle capacity of at least 50  percent of average design flow is recommended
for the conventional and step aeration processes; at least 100 percent is recommended for
the contact stabilization and complete mix  modifications. Firm capacity is defined as the
available pumping capacity with the largest pump out of service.

5.4  Pilot Studies

The use of pilot facilities for investigating the upgrading of existing  activated  sludge plants is
strongly indicated, in many cases, to ensure that optimum design parameters are selected.
There  are  two general types of piloting  facilities available:  batch or continuous-flow
systems. Batch studies are used primarily to evaluate treatability. Continuous-flow systems

                                          5-28

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generally range in size from bench-scale to 10-gpm units and are used to generate data for
design, such as BOD removal rates, oxygen requirements and sludge production.

   5.4.1   Batch Studies

Batch laboratory-scale units are subject to all  of the  inherent difficulties of biological
oxidation systems, with the added magnified complexities of large surface-to-volume ratios,
small quantities of sludge mass in the reactor and the undesirable factors associated with
slug feeding of  wastewater.  In spite of these inherent difficulties,  batch studies  have
attractive features in that they afford an  economic and efficiently  controlled method of
determining  the  biological  treatability of a  wastewater  and  developing fundamental
information  concerning the applicability of various  activated  sludge modifications.

   5.4.2   Continuous-Flow Studies

Use of the  continuous-flow  system  is preferable to obtain design parameters  since it
approximates the operation of an actual plant, permitting evaluation  of the effects of
variations in  wastewater loading  or  strength.  Continuous-flow units must be used on
wastewaters  which exhibit biostatic or exert  toxic  effects to permit  development  of an
acclimated biomass. However, most municipal  wastewaters  do  not exhibit these properties
unless there  is  a significant discharge of  untreated  industrial wastes.  A  continuous-flow
bench-scale aeration unit is illustrated on Figure 5-11. The  initial step in setting up such a
unit is to characterize the wastewater  and  to design the unit and select the proper loadings
accordingly.  Frequently, the bench-scale unit is designed as an integral aerator-settler system
constructed  of  plexiglass  with a  volume of  1 to 10 liters. The  aeration  and  settling
compartments are separated by a plexiglass baffle wall which may be adjusted to vary the
size of the opening between the two zones. Solids separated  in the settling compartment
may be returned to the aeration compartment by sloping the  bottom of the settling zone
toward the aeration compartment or preferably by the use  of a small pump. Air is supplied
through a porous diffuser at the end of a tube. An effluent overflow tube is located  at the
desired water level. The aeration unit may be  fed  either by a  small metering pump,  or by
gravity as illustrated on Figure 5-11. Once equilibrium conditions have  been established
within the unit, the removal of BOD, nitrogen and phosphorus can be evaluated. SS removal
is   determined  from  settling   tests  and  the  resulting  sludge may  be  evaluated for
dewaterability by using a capillary suction device. An approximate determination of the
quantity of  sludge produced  per  unit of  BOD  removed may also  be  made during  a
bench-scale study.

A  schematic  of a medium-sized (0.1 to 1.0 gpm) continuous-flow pilot unit is shown on
Figure 5-12.  Basically, the system consists  of a wastewater feed tank equipped with a  mixer
to blend the  wastewater prior to feeding the aeration unit and to prevent solids deposition
in  the feed tank. The wastewater from the feed tank and the recycle sludge from the final
clarifier are pumped  to the aeration tank using peristaltic-type  pumps.  The difficulty of

                                         5-29

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                     FIGURE 5-11
              BENCH-SCALE AERATION  UNIT
                              RATE  CONTROLLER-
        ADJUSTABLE BAFFLE
SETTLING
COMPARTMENT
                                                                WASTEWATER
                                                                CONTAINER
                          5-30

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                                   FIGURE  5-12
            SCHEMATIC OF A CONTINUOUS-FLOW PILOT UNIT
                                          V ROTOMETER
WASTE«ATER
FEED TANK
                                                      MIXED LIQUOR
                        FEED PUMP
                        (PERISTALIC
                        TYPE)
                                                    POROUS
                                                    DIFFUSER
  AERATION
    TANK


SLUDGE RECYCLE
                                        EFFLUENT


                                     FINAL
                                     CLARIFIER
                                                             SLUDGE PUMP
                                                          (PERISTALTIC  TYPE)
                                              EXCESS SLUDGE
                                       5-31

-------
pumping  extremely  low  flows  makes  it  essential  to  provide  a  reasonably large
aerator-clarifier system.  Air is normally supplied through porous diffusers controlled by the
use of rotameters. The wastewater, after  treatment, flows by gravity to a separate clarifier.
In the small-scale clarifier, care must be taken to prevent solids deposition on the side walls.
The clarifier should have a scraper mechanism to aid in thickening and removal of the mixed
liquor solids.  If 24-hour composite  sampling of feed  wastewater and clarifier effluent is
required, provision should be made to pump these streams into refrigerated sample bottles.

Two  approaches  may  be applied  for  the  acclimation  and  growth  of a  culture  of
microorganisms for use in a pilot study. An available activated sludge culture  may  be
utilized as the  source  of microorganisms, with the  normal feed to that system being
gradually replaced by the wastewater under investigation until satisfactory performance is
obtained.  Alternatively, culture  development can begin with a small  quantity  of seed
organisms and a wastewater feed diluted below the toxicity threshold (if toxicity exists). As
the biological mass  develops, the toxicity threshold is redetermined and the  wastewater
concentration is increased accordingly until the culture is capable of handling wastewater at
100 percent concentration. The latter technique is preferred  because it provides the best
opportunity  to  observe the growth characteristics of  the biological culture as well as
potential problems with acute or chronic toxicity.

When the culture is capable of functioning on the undiluted wastewater, data are collected
on the performance of the system, beginning with  a low-feed rate and increasing the feed
rate until anticipated design loadings and performance are attained. For various F/M's, the
performance and characteristics of the system should be evaluated in terms of:

     1.    BOD, COD and SS removal

     2.    Oxygen consumption

     3.    Waste sludge production

     4.    Biomass characteristics (microscopic appearance and  settling rates)

     5.    Physical nature of the effluent (turbidity,  odor, color, etc.).

          5.4.2.1   BOD Removal Rate Determinations

The data collected from continuous-flow units can be analyzed using either the Eckenf elder
or Weston procedures  to  define  the  appropriate BOD removal  characteristics for design
conditions as previously discussed (41)(42).
                                         5-32

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         5.4.2.2   Oxygen Uptake Requirements

Reliable oxygen consumption data cannot be obtained from pilot plants because of the scale
factors involved.  However, oxygen  uptake studies can and  should be  conducted on the
mixed liquor to obtain energy and  endogenous oxygen requirements. A schematic of an
oxygen uptake curve for a typical continuous-flow activated  sludge pilot unit is shown on
Figure 5-13 (51). The slope of the line (m) represents the oxygen required for cell synthesis,
while the ordinate intercept (b) represents  the oxygen required for endogenous respiration.
The net oxygen consumption is expressed by the following equation:

                   (\\> BOD removed A
         62  -  m I        ~j~~I + b  (lb VSS under aeration)

     where:

         O2  = lb oxygen uptake/day
         m   = energy oxygen, lb  oxygen uptake/lb BOD  removed
         b   = endogenous oxygen, lb oxygen uptake/day/lb VSS  under aeration

         5.4.2.3   Sludge Production

Sludge production in an activated  sludge system is expressed as the  net effect of  two
processes as follows:

     1.   Synthesis  of new organisms resulting from the assimilation of the organic material
         removed

     2.   Reduction of the  weight of  organisms   under aeration  by the  process of
         endogenous respiration.

Figure 5-14 is a schematic representation of sludge production from a continuous-flow pilot
plant (51). The  slope of the line  (m') represents  sludge synthesis, while the  ordinate
intercept (b') represents the endogenous destruction  of solids. The net sludge production is
expressed by the following equation:

         VSS produced/day =  m' (lb BOD  removed/day) - b'  (lb VSS under aeration)

     where:

         m'  = sludge synthesis (lb VSS  produced/lb BOD removed)
         b'   = endogenous destruction of  sludge (lb VSS  destroyed/day/lb  VSS
                under aeration)
                                        5-33

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                  FIGURE 5-13
DETERMINATION OF  OXYGEN UPTAKE REQUIREMENTS (51)
          LB BOD REMOVED DAY  LB MLVSS UNDER AREATION
            ffl = ENERGY 02 (LB 02/LB BOO  REMOVFn)
            b = ENDOGENOUS 02 (LB 02/DAY,LB MLVSS  UNDER AERATION)
                         5-34

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                      FIGURE 5-14
DETERMINATION  OF SLUDGE  PRODUCTION CHARACTERISTICS (51)
     CO
     CO
     CO
     CO
           LB BOD  REMOVED/DAY/LB MLVSS UNDER AERATION

             m'  =  SLUDGE SYNTHESIS (LB VSS/LB BOD REMOVED)

             b'  =  ENDOGENOUS  DESTRUCTION  OF SLUDGE (LB  VSS/OAY/LB
                  MLVSS UNDER  AERATION)
                            5-35

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Although the  bench-scale and small pilot-scale techniques described above are extremely
useful  in initial screening and  treatability tests, extreme caution  must be  exercised in
extrapolating  pilot-generated design data  to  full-scale plants. The  pilot tests should be
conducted to approximate the most severe conditions expected for the full-scale plant.

5.5  Activated Sludge Upgrading Techniques and Design Bases

Upgrading activated sludge plants  to  relieve overloaded conditions,  to improve  organic
removal efficiency, to provide nitrification and to remove nutrients will be covered in the
following sections.

     5.5.1  Upgrading to Relieve Overloaded Conditions

The  following activated sludge  modifications are  examined  as  they apply to upgrading
existing activated sludge plants:

     1.    Step aeration
     2.    Contact stabilization
     3.    Complete mix
     4.    Pure oxygen.

The  step aeration and contact stabilization processes are similar in that both modifications
can  be  incorporated into the  upgraded  design at a minimum capital investment.  The
flexibility to operate in both modes is accomplished  by sizing the influent step aeration
piping so that the  entire flow may  be introduced in the last bay of  the aeration tank, thus
permitting operation as a contact stabilization process.

Before examining  each individual upgrading procedure, several general  statements  can be
made.  Operating data,  BOD removal  rate constants  and volumetric loadings previously
discussed indicate that at least one of the  activated sludge modifications may be applicable
for  upgrading an  overloaded activated sludge  plant. These  modifications  may require
renovation of the  air system to supply sufficient air to meet  the requirements of the new
process because  of higher volumetric loadings. The mechanical aerator and agitator-sparger
systems are illustrated on Figure 8-2. Even though mechanical aerators afford a high transfer
efficiency, their use in  an  existing  basin  may pose  problems because  the geometric
configurations required for their most  efficient utilization may be quite different than the
existing  basin configuration. This  was found to be  true for an  upgrading investigation
performed for the  City  of Baltimore, Maryland (53).  In an economic comparison, it was
found that the annual costs for  a diffused versus  a mechanical aeration  system  were
approximately equal because of  the existing configuration of the plug flow basins. However,
it was  recommended that mechanical  aeration be considered  for future  aeration  tank
expansion.

                                         5-36

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Most existing conventional plants use either fine- or coarse-bubble diffused air systems. The
fine-bubble  system is  more efficient,  but on the other hand represents a greater capital
investment  and  more  costly  maintenance problem than  a coarse-bubble system. At
Milwaukee, Wisconsin, it was found that the type and arrangement of fine-bubble diffusers
had a significant effect on oxygen transfer efficiency. The studies showed that ceramic tubes
in both spiral and transverse patterns did not perform as efficiently as ridge and furrow
pattern ceramic plates located longitudinally. By converting to the ridge and furrow pattern,
the overall plant removal efficiency was substantially increased (54).

The  agitator-sparger system has an operational advantage over the  diffused air unit (coarse-
or fine-bubble) in that during low flows the air may be reduced but the mixing will be
maintained due to the action of the turbine agitator.

          5.5.1.1   Upgrading a Conventional Activated Sludge Plant to Step Aeration

Step aeration has been  used successfully as an upgrading technique in New York  City;
Indianapolis, Indiana;  and numerous other  locations. The case history  discussed below
illustrates the implementation of  this technique  of the Wards Island Wastewater Treatment
Plant in New York City (55)(56)(57).

Wards  Island  was built in 1937 to provide secondary treatment  for a design  flow of
180 mgd. By 1947, the average flow was in excess of 226 mgd, solids removal performance
had become erratic and air consumption was excessive. The problems were remedied and the
capacity was increased to  240 mgd  by: (1) converting the conventional activated sludge
aeration tanks to the step aeration process and (2) modifying the final clarifier inlet-outlet
configurations.

The  original design provided parallel treatment trains, with an aeration detention time of
7.0 hours and  a final clarifier overflow  rate of 700 gpd/sq  ft at the design flow. The
modification of the aeration tank influent systems to provide step aeration, as shown on
Figure 5-15, increased  the plant's organic loading capacity and greatly enhanced operational
flexibility. Using the step aeration process, 12 of the original aerators had sufficient capacity
for 240 mgd, providing a nominal aeration detention time of 4.0 hours. A study of plant
capacity carried out in 1965 concluded that if the existing preliminary tanks were replaced
and the four surplus aerators converted into final clarifiers, the plant could be rated for at
least 250 mgd.

Operating and performance data for the upgraded plant from 1953 are shown in Table 5-11
for one of the four treatment plant batteries (Battery C).
                                       5-37

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                     FIGURE  5-15

UPGRADING A CONVENTIONAL ACTIVATED SLUDGE PLANT
                   TO STEP AERATION
 PRIMARY
 EFFLUENT
                  AERATION
                    TANK
  FINAL
CLARIFIER
                           RETURN  SLUDGE
EFFLUENT
                                        EXCESS SLUDGE
          ACTIVATED SLUDGE  SYSTEM BEFORE  UPGRADING
                    (1 OF 16 PARALLEL MODULES)
PRIMARY
EFFLUENT
                   AERATION
                    TANK •
                                                   EFFLUENT
                           RETURN SLUDGE

                                      EXCESS  SLUDGE


       ACTIVATED SLUDGE  SYSTEM AFTER UPGRADING

                (1  OF  16 PARALLEL MODULES)
                        5-38

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                                 TABLE 5-11
               OPERATING AND PERFORMANCE DATA FOR THE
                   WARDS ISLAND PLANT, NEW YORK CITY

                                              Operating and Performance After
           Description                             Upgrading (1953) (55) (58)

Flow, mgd                                                   481

Raw Wastewater
  BOD, mg/1                                                123
  SS, mg/1                                                  145

Primary Effluent
  BOD, mg/1                                                 99
  SS, mg/1                                                   89

Aeration Tanks
  MLSS, mg/1                                             1,030
  Air Rate, cu ft/gal                                            0.60
  Volumetric Loading, Ib BOD/day/1,000 cu ft                     46
  Organic Loading, Ib BOD/day/lb MLSS                           0.71
  Detention Time, hr                                           3.32

Final Clarifiers
  Overflow Rate, gpd/sq ft                                     900

Secondary Effluent
  Overall BOD Removal, percent                                 95
  Overall SS Removal, percent                                   95
  BOD, mg/1                                                  6
  SS, mg/1                                                    7

1 Battery C of 4 batteries.
2 Excluding sludge recycle.
                                    5-39

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The costs for the plant modifications projected to an EPA cost index of 175 are as follows:

         Final Clarifier Alterations                           $  990,000

         Aeration Tank Modifications                           510,000

                                                            $1,500,000

         5.5.1.2   Upgrading  a  Conventional  Activated  Sludge  Plant  to  Contact
                   Stabilization

Contact stabilization has been successfully used as an upgrading technique in Austin, Texas;
York, Pennsylvania; and Bergen  County, New Jersey. The case history discussed below
illustrates the implementation of this technique at Austin, Texas.

The first full scale application of the contact stabilization concept was developed by Ullrich
and Smith (59)(60) at the Austin, Texas Wastewater Treatment Facility. In 1954, the entire
plant was converted from the original 6.0 mgd conventional activated sludge operating mode
to the "Biosorption" process, later to be renamed contact stabilization. Earlier field studies
had indicated that implementation  of contact stabilization could effectively control  a
long-standing sludge bulking problem and significantly increase plant capacity. The cause of
the sludge  bulking was   undetermined, and could  be  effectively  controlled in  the
conventional operating mode only by bypassing a portion of the primary effluent.

Schematics of the original  and  upgraded  facility are shown on Figure 5-16. Conversion of
the plant to  contact stabilization was  achieved through the splitting of the flow to two
separate parallel and independent plants. The two original aeration tanks were split between
the two  plants, with additional  clarification  capacity provided. In  the upgraded plant,
aeration tank A  was coupled with the two existing final clarifiers and the original primary
clarifier converted to final clarification service. Aeration tank B was matched with two new
clarification units. Primary clarification was omitted in the upgraded contact  stabilization
flow pattern. Table 5-12 compares the operation and performance of the facility before and
after upgrading. The data shown for the upgraded plant are for one-half of the treatment
facility (Plant A).

Overall  removals averaged  94 percent for BOD and  92 percent for SS in January, 1956.
Sludge bulking problems were also eliminated. The data reveal that through conversion to
the contact stabilization process and the addition of further final clarification capacity, the
upgraded facility could adequately treat over twice the original average daily design flow.
                                        5-40

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                                      FIGURE 5-16

              UPGRADING A CONVENTIONAL  ACTIVATED SLUGE PLANT
                              TO  CONTACT STABILIZATION
     RAW
     WASTEWATER
                                                       AERATION
                                                       TANK NO.
                                                        AERATION
                                                        TANK NO  2
               COMBINED PRIMARY
               AND WASTE SLUDGE
                                                      EFFLUENT
ACTIVATED SLUDGE  SYSTEM
    BEFORE UPGRADING
RETURN
SLUDGE
EXCESS
                                                SLUDGE STABILIZATION
                                                       ZONE
                                               SLUDGE STABILIZATION
                                                     ZONE
      RAW WASTEWATER
(CONVERTED
 EXISTING
 PRIMARY
 CLARIFIER)
                                     EXCESS SLUDGE

                      ACTIVATED SLUDGE SYSTEM  AFTER  UPGRADING
                                         5-41

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                                 TABLE 5-12
          OPERATING AND PERFORMANCE DATA FOR AUSTIN, TEXAS

                                       Overloaded Operating    Upgraded Operating
                                         and Performance      and Performance
                                             Data1	     Data2 (Plant A)

Flow, mgd                                        8.2                   6.5
Raw Wastewater
  BOD, mg/1                                    249                  358
  SS, mg/1                                      243                  247
Primary Treatment
  Primary Effluent BOD, mg/1                    ,151
  BOD Removal, percent                          39                   —
  Primary Effluent SS, mg/1                        98                   -
  SS Removal, percent                             60                   —
Aeration Tank
  MLSS,mg/l                                 1,282                 2,533
  Sludge Recycle, percent                          26.4                  56
  Air Requirement, cu ft air/lb
   BOD removed                              1,778                  776
  Volumetric Loading, Ib BOD/day/
   1,000 cu ft                                   40.9                1383
  Organic Loading, Ib BOD/day/lb MLSS              0.51                  0.383
  Detention Time in Aerator, minutes^1              331                    59^
  Detention Time in Stabilization
   Zone, minutes^                               —                   312
Secondary Clarifier
  Overflow Rate, gpd/sq ft                        774                  410
Secondary Treatment
  BOD Removal, percent                          40                    94
  SS Removal, percent                             70                    92
  Effluent BOD, mg/1                             91                    21
  Effluent SS, mg/1                               73                    21

1 January - September, 1946.
2 January, 1956.
«* Including stabilization.
4 Excluding sludge recycle.
^ Contact zone.
" Based on return sludge flow.
                                      5-42

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         5.5.1.3   Upgrading a Contact Stabilization  Plant to Complete Mix Activated
                   Sludge

Past experience with complete mix  activated sludge  on  a  large  scale has been quite
successful,  although somewhat limited. Complete mix plants have been installed at Grand
Island,  Nebraska; Freeport, Illinois;  South  Tahoe,  California; and Albany,  Oregon.
McKinney (21) and Smith (44) have reported the usefulness of this process for upgrading an
overloaded activated sludge plant. When the complete mix process is to be considered as an
upgrading technique, the geometric configuration of the existing aeration basin sometimes
poses a major problem.

Coralville,  Iowa  (15) had a contact  stabilization  package plant which  was providing
detention times of 2.6 and 6.5 hours, respectively, in the contact and stabilization zones,
based on the average  influent flow of  867,000 gallons per day. The contact stabilization
package plant is shown in plan view on Figure 5-17.

As  previously  discussed  in Section 5.2.3,  a contact-zone detention time of this magnitude
may result in  poor  quality effluent because the sludge becomes partially stabilized in this
zone and exhibits poorer settling characteristics. After investigation, this was found to be
the case in Coralville.  Operating and performance data from the plant before upgrading are
summarized in Table 5-13. The  effluent BOD and SS concentrations were 26 and 24 mg/1,
respectively.

To  improve the plant's performance, it was decided to modify the flow pattern as indicated
on  Figure 5-17. The influent piping was  modified so that the raw wastewater was evenly
distributed  into  what  originally  was  the stabilization zone.  No  raw wastewater  was
introduced into the former contact zone. Mixed liquor  in the upgraded system proceeded
from the former stabilization zone through the former contact zone  to the final  clarifier.
The return  sludge was introduced into the former  stabilization zone at one point only.
Therefore,  the  upgrading resulted in  a "modified" complete mix flow pattern,  with an
overall detention time  of 9.1 hours at an average influent flow of 867,000 gpd.

Operating and performance data for the upgraded plant are also included in Table 5-13.  The
effluent BOD  and SS concentrations were lowered to 13 and 6 mg/1, respectively, by the
upgrading procedure.  The costs associated with this modification are primarily for piping
changes. No cost breakdown was available for the modification.

         5.5.1.4   Upgrading Existing Treatment  Plants  to  Oxygen-Activated Sludge

An  existing activated sludge system  may be upgraded by conversion to  a pure oxygen
system.  However, because of  a  number of distinct differences between  the  physical
                                       5-43

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                          FIGURE 5-17

       UPGRADING A CONTACT STABILIZATION PLANT TO
      COMPLETE-MIX FLOW PATTERN  ACTIVATED SLUDGE (15)

   SLUDGE                     _	^      ^-CONTACT ZONE
   STABILIZATION ZONE
  RETURN SLUDGE
   EXCESS SLUDGE
   WASTING LINE
BEFORE UPGRADING
CONTACT STABILIZATION FLOW PATTERN
           RAW
           WASTEWATER
                                                     EFFLUENT
      AEROBIC DIGESTER

FINAL  CLARIFIER
           COMPLETE-MIX
           AERATION  TANK
         RETURN
         SLUDGE
    EXCESS  SLUDGE
    WASTING  LINE
 AFTER UPGRADING
 MODIFIED COMPLETE -MIX FLOW PATTERN
                                                AERATION TANK
              RAW
           \  WASTEWATER
                                                      EFFLUENT
                                                  AEROBIC DIGESTER
                                              FINAL CLARIFIER
                              5-44

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                                  TABLE 5-13
                    OPERATING AND PERFORMANCE DATA
                           FOR CORALVILLE, IOWA
    Parameter
Average Flow, mgd
Raw Waste water
  BOD, mg/1
  SS, mg/1
Aeration Tank
  Sludge Recycle, percent
  Contact Zone Volumetric Loading,
   Ib BOD/day/1,000 cu ft
  Contact Zone Organic Loading,
   Ib BOD/day/U) MLVSS
  Contact Zone MLSS, mg/1
  Complete Mix Volumetric Loading,
   Ib BOD/day/1,000 cu ft
Final Clarifier
  Overflow Rate^, gpd/sq ft
Overall Plant Performance
  BOD Removal, percent
  SS Removal, percent
  Effluent BOD, mg/1
  Effluent SS, mg/1
  Contact        "Modified"
Stabilization 1    Complete Mi
     0.867
  0.867
   135
   150

    60

    78

     0.4
 3,500
135
150

 60
   750

    81
    84
    26
    24
 224

750

 90
 96
 13
  6
1 Before Upgrading.
2 After Upgrading.
o
  Based on average flow.
4 Based on total aeration volume.
                                      5-45

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components  of air  and  oxygen  systems,  special  consideration  must be  given to the
following:

     1.   Tank foundations and walls must be checked structurally for increased loadings
         due to the oxygen dissolution equipment and tank covers.

     2.   Baffling  may  be  required to  sectionalize  the  existing  aeration  tank for
         compatibility with various pure oxygen dissolution configurations.

     3.   Existing air diffusion piping may have to be removed.

     4.   Protection must be  provided  against the  potential explosion  hazard of pure
         oxygen or oxygen-enriched air.

     5.   Protection may  have to be provided against potential accelerated corrosion due to
         pure oxygen  or oxygen-enriched air.

Aspects of using pure oxygen which may make it economically attractive include:

     1.   Significant increases  in  volumetric loading may be  accommodated in existing
         aeration tank structures.

     2.   The oxygen generation equipment may be placed outside and does not require a
         protective enclosure.

     3.   Sludge production may be reduced.

     4.   Expensive renovation of the blower building is eliminated.

     5.   Liquid oxygen storage may be used to reduce peak energy requirements.

Full scale use of pure oxygen for upgrading municipal treatment plants handling extremely
large flows is in the startup stage  in Detroit, Michigan, and is under consideration in New
York City. Oxygenation  at Detroit has been utilized to expand a 300-mgd  section of the
existing primary treatment plant  to  secondary treatment. In  New  York City,  a 20-mgd
section  of the Newtown Creek Wastewater Treatment Plant has been converted to oxygen
aeration to  upgrade treatment efficiency. This conversion is presented as  a case history
below (31).

The Newtown Creek Plant has  16  parallel bays, each of which has a design capacity of 20
mgd and consists of an aerated grit chamber,  an aeration tank and a final clarifier. The
system  is designed as  a modified  aeration process,  a process that typically  achieves 65 to
70 percent BOD removal when operated at design flow and MLSS concentration. Currently,

                                        5-46

-------
the Newtown Creek facility is receiving only 55 to 60 percent (11 to 12 mgd/bay) of the
design flow. This temporary flow condition has allowed operation of the modified aeration
system  in  a more conventional  mode  with a nominal  aeration detention  time of
approximately 2.5 hours and an MLSS concentration of 2,000 mg/1, as shown in Table 5-14.
When design flow is reached within the next one to two years, operation will have to revert
to the modified aeration mode because of air supply limitations. At that time, the City will
be confronted with a severe upgrading problem in a land-locked neighborhood.
                                  TABLE 5-14
                  OPERATING AND PERFORMANCE DATA FOR
                           NEWTOWN CREEK PLANT,
                            BROOKLYN, NEW YORK
                                                                     Oxygen2
       Description                                  System (26)       System (31)

Flow, mgd                                              10.9              20.6
Raw Wastewater
   BOD, mg/1                                          202              171
   SS, mg/1                                            184              159
Aeration Tank
   MLSS, mg/1                                       2,000            3,875
   Sludge Recycle, percent                                20               45
   Oxygen Requirements, Ib 02/lb BOD removed             16.1 3              1.02
   Volumetric Loading, Ib BOD/day/1,000 cu ft            106              178
   Organic Loading, Ib BOD/day/lb MLSS                    0.92              0.74
   Detention Time in Aerator, minutes^                   158               86
Secondary Clarifier
   Overflow Rate, gpd/sq ft                              500              936
Secondary Treatment
   BOD Removal, percent                                 88               90
   SS Removal, percent                                   80               89
   Effluent BOD, mg/1                                    24               17
   Effluent SS, mg/1                                      37               18

1  October 1, 1972 through November 30, 1972.
2  Phase 4 of study, April 8, 1973 through June 2, 1973.
3  Excludes air diffuser oxygen transfer efficiency.
4  Excluding sludge recycle.
                                     5-47

-------
Pure oxygen is believed to be a good candidate for achieving the required 90 percent BOD
removal within the confines of the existing aeration and final clarification tankage at design
flow. To evaluate this possibility, one bay of the Newtown Creek Plant was converted to a
staged, covered reactor oxygen system, as shown on Figure 5-18. This test system has been
operated continuously since May, 1972.

From  September  17,  1972 to  September 1, 1973, seven  phases of a  multi-faceted
experimental program were  conducted.  The  oxygenation system was evaluated under
different loading and diurnal flow patterns in each phase. Operating and performance data
for Phase 4 are summarized in Table 5-14. In this phase, the average flow approximated the
design flow of the bay,  with  diurnal  fluctuation  matching the typical diurnal  pattern
experienced at the plant.  Throughout the seven phases, the pure oxygen system achieved
overall BOD  removals of  at least 87 percent.  In Phase 4, the  BOD removal equalled the
required rate of 90 percent.

A second case history wherein an existing plant was converted to pure oxygen is described
below for Fairfax County, Virginia. In May, 1970, Fairfax County was required to upgrade
its Westgate Treatment Plant to prevent the imposition of a building moratorium in the area
served by this plant (61). The  original  plant was designed in  1954  as an 8-mgd capacity
facility consisting of two rectangular tanks baffled to form three  compartments, as shown
on Figure  5-19. The plant was designed to achieve 50 percent BOD removal. By 1970,
average flows had increased to 12 mgd and BOD removal was reduced at times to as low as
35 percent.

The Westgate Plant was scheduled to be abandoned  by 1975 when its service area is to be
incorporated into  a regional system  tributary to  an  advanced waste  treatment facility.
Hence,  a minimum  cost  interim  upgrading  plan  was  sought to meet  the imposed
requirements of 80 percent BOD removal. It was decided to upgrade the facility with pure
oxygen-activated sludge.

Portions  of the  existing rectangular tanks  were converted to  oxygenation reactors. The
initial clarification  zone  was maintained, and the  remainder  of the  tanks  was  divided
longitudinally to form two reactors each, for a total of four. Each reactor was then baffled
to form  four stages. The  first three stages were covered and the fourth left open to the
atmosphere. Surface aerators were provided in each  stage, but oxygenation occurred in the
first three stages only. Two circular final clarifiers were constructed. The upgraded facility is
shown on Figure 5-19. Since this was only a short-term upgrading, the pure oxygen supply
system selected was simply an oxygen storage  station in which trucked-in liquid oxygen is
stored, vaporized and fed to the reactors. The upgraded facility became operational in
October, 1971.
                                        5-48

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                               FIGURE  5-18

     UPGRADING  A MODIFIED AERATION ACTIVATED  SLUDGE  SYSTEM
                       TO OXYGEN-ACTIVATED  SLUDGE
       PUMPS
   RAW
»ASTE»ATER-
                  r-GAS  RECIRCULATING
                  \COMPRESSORS
                                             SUBMERGED PROPELLER-
s
1
)

— >
-*
\ /SPARGER ASSEMBLY
ODD D D /
o
o
o
o
o
o
/
0
o
fe
fc

Ju
JO
1 In
                            -200'-
                                       J   I
                                                        -400'
                                                                         EFFLUENT
                                       PLAN  VIEW
    RAW
»ASfE«IATER	»
             GRIT
           CHAMBER
                     Ml XER DRIVE FOR
                   V PROPELLER-SPARGER
                    \ ASSEMBLY
                     Yi    n
                              n
                          I
                   FOUR-STAGE OXYGEN REACTOR
                        SKD = ,5
                     "Z
                       RETURN SLUDGE


                                                      EXCESS SLUDGE



                                       ELEVATION

               TREATMENT SYSTEM AFTER UPGRADING TO OXYGENATION (31)
                                     5-49

-------
                           FIGURE 5-19

             UPGRADING A PRIMARY TREATMENT PLANT
          TO PURE OXYGEN ACTIVATED SLUDGE TREATMENT
CLAR
RAW
WASTEWATER 	 >
IFIER


s AERATION* CLARIFIERS-,
/ BASINS-y ~7







i
i

RAW
WASTEWATER
                                                             EFFLUENT
                    *WITHOUT SLUDGE RECYCLE

                          BEFORE  UPGRADING
              PRIMARY
              CLARIFIERS
                              BIOLOGICAL REACTOR
                              3 STAGES OXYGENATION
                              1 STAGE AIR AERATION
                     7
EFFLUENT
                                AFTER UPGRADING    EXCESS
                                                    SLUDGE
                                    5-50

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 Operating and performance data for the original facility and the upgraded plant are listed in
 Table 5-15. BOD removals greater than 90 percent are presently being achieved. The cost of
 upgrading this facility, adjusted to an EPA cost index of 175, was $907,000.
                                  TABLE 5-15
                  OPERATING AND PERFORMANCE DATA FOR
                         FAIRFAX COUNTY, VIRGINIA

                                                Before Upgrading   After Upgrading
       Description                                  (1969) (62)    (May, 1972) (63)

Average Flow, mgd                                      11.3              11.0
Influent BOD, mg/1                                     245              158
Influent SS, mg/1                                         -              148
Aeration Tank
  MLVSS, mg/1                                          _            3,822
  Sludge Recycle, percent                                 —               13.7
  Oxygen Requirements, Ib O2/lb BOD Removed              -           0.8-1.052
  Volumetric Loading, Ib BOD/day/1,000 cu ft               -              113
  Organic Loading, Ib BOD/day/lb MLVSS                   -                0.48
  Detention Time in Aerator, minutesl                      —              126
Secondary Clarifier
  Overflow Rate, gpd/sq ft                                 —              509
  Solids Loading, Ib/sq ft/day                               —               23.3
Overall Treatment
  BOD Removal, percent                                49               04
  SS Removal, percent                                    _               87
  Effluent BOD, mg/1                                     _               14
  Effluent SS, mg/1                                       _               19


* Does not include sludge recycle.
  The higher uptake rate occurs in warm weather operation due to the higher activity of the
  biomass.
                                      5-51

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     5.5.2   Upgrading to Improve Organic Removal Efficiency

Upgrading techniques previously discussed relate to the ability of existing activated sludge
facilities to handle increased loads and/or overcome operational problems by providing
modifications to  meet existing effluent standards.  However, there may be a need to meet
higher effluent standards even though the existing  facilities are not overloaded and are
performing  in  accordance  with  design expectations.   Table 5-16  contains  suggested
alternatives for improving effluent quality under these conditions, along with a range of
anticipated improvement in performance for each alternative.

It should be emphasized that, in cases where new unit processes are constructed downstream
of existing activated sludge facilities, the improvement in over ah1 organic removal will be a
direct function of the BOD  removal achieved in the "add-on" process. However, where new
unit processes are installed  upstream of existing activated sludge units,  e.g., the use of a
roughing filter, the overall BOD removal may not be increased in direct proportion to the
amount achieved by the "add-on" process.

A detailed discussion on  polishing lagoons, microscreens, filters, activated  carbon and
clarifier modifications appears in subsequent chapters. The applicability of these alternatives
to individual  cases should be evaluated in detail prior to the implementation of a particular
upgrading procedure.

     5.5.3   Upgrading for Nutrient Control and Removal

With the trend toward more stringent effluent standards,  the upgrading of activated sludge
plants to achieve  phosphorus removal and nitrification and/or nitrogen removal is becoming
more frequent. Some of the techniques that may be utilized for this purpose are discussed
below. A case history for upgrading an existing plant for combined phosphorus and nitrogen
removal is presented in Chapter 13.

          5.5.3.1    Phosphorus Removal

One of the most commonly used methods to accomplish phosphorus removal in an activated
sludge system is  to  precipitate the phosphorus  by addition of  a  metallic salt  to the
secondary  system.  Metallic salts that have been used include aluminum sulfate, sodium
aluminate, ferric chloride, ferric sulfate and ferrous  sulfate. The selected salt may be applied
to  the  primary  effluent as  it enters  the aerator,  directly  to the mixed  liquor  at  a
predetermined point  in  the aerator or  to the  mixed liquor channel leading  to the final
clarifier. The optimum addition point  should be  selected through a  combination  of
laboratory jar testing and comprehensive field testing. A flexible chemical addition design
permitting addition at  several  points  in the  secondary  system flow  pattern is highly
desirable. When sufficient metallic salt dosages  are utilized, phosphorus removals of 80 to
                                         5-52

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                                                       TABLE 5-16
                               UPGRADING TECHNIQUES FOR IMPROVEMENT OF ACTIVATED
                                         SLUDGE TREATMENT PLANT EFFICIENCY
            Addition Preceding
             Existing Process
      Roughing Trickling Filter
       (Rock or Synthetic Media)
      Chemical Addition
       to Primary Clarifier
Existing Process


Activated Sludge
01
to
Addition Following
  Existing Process
                     2nd-Stage Activated Sludgel
                     Polishing Lagoon
                     Multimedia Filters
                     Microscreens
                     Activated Carbon
Incremental BOD
 Removal Across
  the Added or
Modified Process
    percent
                                     20-40

                                     30-50
                                     30-70
                                     30-60
                                     50-80
                                     30-80

                                     60-80
      1 A consideration if year-round nitrification is required.

-------
90 percent may be obtained.  Case histories illustrating the implementation of phosphorus
removal in activated  sludge  plants may  be found  in  the  Process  Design Manual for
Phosphorus Removal (64).

The  addition of metallic salts will  increase the solids loading on the final clarifiers, and
decrease the  percentage of volatile solids in the clarifier underflow. If  the benefits  of
chemical addition are to be fully realized, the existing clarifiers must have adequate capacity
to handle the higher solids loadings. Also, the existing sludge recycle and processing systems
must be capable, respectively,  of returning sufficient sludge to the aeration  system  to
maintain proper biological  activity  in that unit, and to handle the increase in the  total
quantity of waste sludge generated by the process. If adequate existing capacity is lacking in
any  of the above, additional construction may be necessary prior  to implementation  of
phosphorus removal.

         5.5.3.2   Nitrification

If year-round nitrification is a design criteria, the information presented in Table 5-17 may
be useful in the preliminary sizing of second-stage process units (65). It  should be stressed
that  the detention time required to achieve nitrification is strongly dependent upon the
wastewater temperature and the MLVSS concentration maintained in the system.
                                    TABLE 5-17
                    DESIGN GUIDELINES FOR NITRIFICATION

         Description                                            Design Parameter

Nitrification Reactor
   Optimum pH range                                                7.6 to 7.8
   Maximum influent BOD, mg/1                                        40 to 50
   Tank configuration                                                plug flow
   MLVSS, mg/1                                                   1,000 to 2,000
   DO at average loading, mg/1                                            3.0
   Minimum DO  at peak loads, mg/1                                       1.0
   Sludge recirculation, percent                                         50 to 100
   Detention time based on average flow, hr                               2 to 6
   Oxygen requirements (stoichiometric), Ib 02/lb NHg—N                  4.6
Clarifier
   Maximum allowable overflow rate, gpd/sq ft                            1,000
                                       5-54

-------
Nitrification reactors should be designed to ensure that plug flow will exist throughout the
reactor.  This is because the rate of oxidation of ammonia  nitrogen is basically  linear,
requiring full utilization of the  available detention time to complete the oxidation  to the
higher valence form of nitrate nitrogen. Plug flow is probably  best ensured by providing a
series of compartments within the reactor.  Compartmentation has the further advantage
that reactors or portions of reactors may be taken out of service when ambient temperatures
are such  that the full reactor design capacity is not required to accomplish nitrification.

Air requirements for completing the oxidation process can vary widely depending on pH,
wastewater temperature, diurnal flow variations and chemical characteristics of the influent
to  the reactors (66).  These  changing oxygen requirements  can be  met with properly
monitored and  controlled diffused air or mechanical aeration systems, or a combination of
the two.

If nitrification  is not required during the colder months, a two-stage system may not be
necessary and nitrification may  be accomplished within the existing single-stage activated
sludge system.  The degree of nitrification that can be attained in a single-stage activated
sludge system  depends  on the  SRT,  mixed liquor  DO  concentration  and  wastewater
temperature (67). The SRT or rate of wasting sludge is of primary importance. If sludge is
wasted at too high a rate, the nitrifying bacteria will be washed from the system. Generally,
nitrification begins at an SRT of about five days, but does not become appreciable until the
SRT reaches about 15 days, depending upon the temperature.  The existing single-stage air
supply system must be  sufficient to provide the additional oxygen needed to oxidize the
ammonia nitrogen.

         5.5.3.3   Nitrogen Removal

Denitrification may be added to the nitrification process as the  second stage of the nitrogen
removal sequence. In this stage, nitrate is reduced to carbon dioxide, water and nitrogen gas
following addition of methanol to provide the carbon source. Other methods of removing
nitrogen from wastewaters include ammonia stripping, chlorination and ion exchange.

5.6  References

 1.  Metcalf &  Eddy, Inc., Wastewater Engineering.  McGraw-Hill Book Company, New
     York City (1972).

 2.  Sawyer,  C.N., Activated Sludge  Modifications.  Journal Water Pollution  Control
     Federation, 32, No. 3, p. 232 (1960).

 3.  Haseltine,  T.R., A  Rational Approach  to the Design of Activated Sludge Plants.
     Included in Biological Treatment and  Industrial Wastes,  edited by McCabe, J.,  and
     Eckenfelder, W.W., Jr., Reinhold Publishing Company,  New York City (1956).

                                        5-55

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 4. Phosphate Study at the Baltimore Back River Wastewater Treatment Plant. U. S. EPA,
    Program Number 17010 DFV (September, 1970).

 5. Operating Reports. Hyperion Treatment Plant, Sewage Treatment Division, Bureau of
    Sanitation, City of Los Angeles, California (September, 1972).

 6. Summary of Operation. Sewage Treatment Plant, Jeanette, Pennsylvania.

 7. The Metropolitan Sanitary District of Greater  Chicago, Calumet Treatment  Works
    Operating Data (1972).

 8. Torpey, W., and Ghasick, A.H., Principles of Activated Sludge Operation. Included in
    Biological  Treatment of Sewage  and Industrial Wastes, edited by McCabe, J.,  and
    Eckenfelder, W.W., Jr., Reinhold Publishing Company, New York City (1956).

 9. Allegheny  County Sanitary  Authority, Pittsburgh, Pennsylvania, Pittsburgh Sewage
    Treatment Plant Operating Data (February, 1974).

10. The Metropolitan District, Hartford, Connecticut, Hartford Water Pollution Control
    Plant Operating Data (September, 1973).

11. Metropolitan Department of Works, Toronto, Ontario, Canada,  Main Treatment Plant
    Operating Data (August, 1973).

12. Ullrich, A., and Smith, M., Operation Experience with Activated Sludge - Biosorption
    at Austin, Texas. Sewage and Industrial Wastes, 29, No. 4, p. 400 (1957).

13. Grich,  E., Operating Experience  with Activated  Sludge  Reaction.  Journal  Water
    Pollution Control Federation, 33, No. 8, p. 856 (1961).

14. Recommended Standards for Sewage  Works. Great Lakes-Upper  Mississippi River b
    Board of State Sanitary Engineers (1971).

15. Dague,  R.R., Elbert, G.F., and  Rockwell,  M.D.,  Contact  Stabilization: Theory,
    Practice, Operational Problems and Plant Modifications. Presented at the 43rd Annual
    Conference of  the  Water  Pollution  Control  Federation, Boston,  Massachusetts
    (October, 1970).

16. McKinney, R., Research and Current Developments in  the Activated Sludge Process.
    Journal Water Pollution Control Federation, 37, No. 12, p. 1696 (1965).

17. Full Scale  Parallel Activated Sludge Process Evaluation. Freeport, Illinois Water and
    Sewer Commission, U. S. EPA Project No. 17950 ENM (January, 1972).

                                       5-56

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18.  Private communication with C.L. Swanson, Sanitary Engineer, U. S. EPA, Cincinnati,
     Ohio (November 5, 1970).

19.  Robinson, J.H.,  New  Regional Plant  Built  for the  Future.  Water and Wastes
     Engineering, 10, No. 8, pp. 35-37 (August, 1973).

20.  Private communication  with Dr. Ross McKinney, University of Kansas, Lawrence,
     Kansas (March 28, 1974).

21.  McKinney, R., et al, Evaluation of a Complete Mixing Activated Sludge Plant. Journal
     Water Pollution Control Federation, 42, No. 5, p. 737 (1970).

22.  Hammer, M.,  and Tilsworth, T., Field Evaluation of  a  High Rate  Activated Sludge
     System. Water and Sewage Works, 115, No. 6, p. 261 (1968).

23.  Private communication with M.E. Bolding, Water Reclamation Research Center, Dallas,
     Texas (January, 1971).

24.  Plant  Performance Summary. Bureau of Wastewater Treatment, Government of the
     District of Columbia (1971, 1972).

25.  Schwinn, D.E., Design Features of the District of Columbia's Water Pollution Control
     Plant.  Presented  at  the   Sanitary   Engineering  Specialty  Conference,   Sanitary
     Engineering Division, ASCE, Rochester, New York (June,  1972).

26.  Operating Data and Report. Department of Water Resources, New York City  (May
     1972 - January 1973).

27.  Operating Reports. Department of Water and Sewers, City of Miami, Florida.

28.  Private communication  with Department  of  Civil Engineering, Pennsylvania  State
     University, University  Park, Pennsylvania (January, 1968).

29.  Simpson, R.W., Activated Sludge Modification. Water and Sewage Works, 106, No. 10,
     p. 421 (1959).

30.  Earth, E.F., Brenner, R.C.,  and  Lewis, R.F., Chemical - Biological Control of Nitrogen
     and Phosphorus in Wastewater Effluent. Journal Water Pollution Control Federation,
     40, No. 12, p. 2,040 (1968).

31.  Brenner, R.C., EPA Experiences in Oxygen-Activated Sludge. Prepared for U. S. EPA
     Technology Transfer Design Seminar Program (October, 1973).
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32.  Stamberg, J.B., Bishop, D.F., Hais, A.B., and Bennett, S.M., System Alternatives in
     Oxygen  Activated Sludge. Presented  at  the  45th Annual  Conference of the Water
     Pollution Control Federation, Atlanta, Georgia (October, 1972).

33.  Operating Experience and Design Criteria for UNOX Wastewater Treatment Systems.
     Union Carbide Corporation, Linde Division, Tonawanda, New York. Prepared for U. S.
     EPA Technology Transfer  Design Seminar Program (1972).

34.  Report on  Wastewater  Treatment Pilot  Plant Study for the  City of Eculid, Ohio.
     Havens and Emerson, Cleveland, Ohio (April 20, 1971).

35.  Continued Evaluation  of  Oxygen Use in Conventional Activated Sludge Processing.
     U. S. EPA Project No. 17050 DNW, Contract No. 14-12-867 (February, 1972).

36.  UNOX Design Information for Contract  Documents. Metcalf &  Eddy, Inc., Boston,
     Massachusetts. Prepared for U. S. EPA Technology Transfer Design Seminar Program
     (1972).

37.  Albertsson, J., McWhirter, J.R., Robinson, E.K., and Vahldieck, N.P., Investigation of
     the  Use of High Purity Oxygen Aeration in the Conventional Activated Sludge Process.
     Federal   Water  Quality   Administration,  Program  No.  17050  DNW,  Contract
     No. 14-14-465 (May, 1970).

38.  Private communication with  D.F. Bishop, Chief,  U. S. EPA - Washington, D.C. Pilot
     Plant, Washington, D.C. (January 10-11, 1971).

39.  Air  Products and Chemicals, Inc., OASES Wastewater Treatment Plant at the Fairfax
     County,  Virginia Westgate  Treatment Plant, Release No. 2 (September 1, 1972).

40.  Henry B. Steeg & Associates, Inc., Town  of Speedway, Indiana Wastewater Treatment
     Plant Design Data and Other Pertinent Information.

41.  Eckenfelder, W.W., Jr. Theory of Design.  Included in The Activated Sludge Process in
     Sewage Treatment Theory and Application. Presented at a Seminar at the University of
     Michigan, Ann Arbor, Michigan (February, 1966).

42.  Weston,  R.F., Fundamentals  of Aerobic  Biological Treatment  of Wastewater. Public
     Works, 94, No. 11, p. 74 (1963).

43.  Torpey,  W., Practical Results of Step Aeration.  Sewage Works Journal, 20, No. 5,
     p. 781 (1948).
                                      5-58

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44.  Smith, H., Homogeneous Activated Sludge-Three Parts. Water and Wastes Engineering,
     4, No. 7, 8, 10, pp. 46-50, 56-63, 40-53 (1967).

45.  Private communication with Leonard Waller, Plant Superintendent, South River Water
     Pollution Control Plant, Atlanta, Georgia (January 27, 1971).

46.  Boon, A.G.,  The Role of Contact Stabilization in the Treatment of Industrial Waste
     and Sewage. Journal of Effluent and Water Treatment, 9, No. 6, p. 319 (1969).

47.  Jackson, R.,  Bradney, L., and Bragstad, R.E., Short Term Aeration Solves Activated
     Shidge  Expansion  Problems  at  Sioux  Falls.  Journal Water  Pollution  Control
     Federation, 37, No. 2, p. 255 (1965).

48.  Lesperance, T.W., A Generalized Approach to Activated Sludge. Reprinted from Water
     and Wastes Engineering by Reuben H. Donnelly Corporation, New York, N.Y.

49.  Union Carbide  Unox  System  Wastewater  Treatment. Union Carbide  Corporation,
     Linde Division, Tonawanda, New York (1970).

50.  Private  communication with  Ted  Zander, Linde Division, Union Carbide Corp.,
     Tonawanda, New York (June 3, 1974).

51.  Eckenfelder,  W.W., Industrial Water Pollution Control. McGraw-Hill Book Company,
     New York City (1966).

52.  Dick, R., Role  of Activated Sludge Final Settling Tanks. Journal  of the  Sanitary
     Engineering Division, ASCE, 96, No. 2, p. 423 (1970).

53.  Letter Report to the City of Baltimore, Maryland, Roy F. West on, Inc., West Chester,
     Pennsylvania (July 14, 1970).

54.  Leary, R.D., et al, Effect of Oxygen-Transfer Capabilities on Wastewater Treatment
     Plant Performance. Journal  Water Pollution Control Federation, 40, No. 7,  p. 1,298
     (1968).

55.  Chasick, A.H., Activated Aeration at the Wards Island Sewage Treatment Plant. Journal
     Sewage and Industrial Wastes, 26, No. 9, pp.  1059-1068 (September, 1954).

56.  Gould,  R.H., Wards Island Plant  Capacity Increased by  Structural Changes. Journal
     Sewage and Industrial Wastes 22, No. 8, pp. 997-1003 (August, 1950).

57.  Upgrading Existing   Wastewater  Treatment  Plants  —  Case  Histories.  U. S. EPA
     Technology Transfer Design Seminar Publication, pp. 16-18 (August, 1973).

                                      5-59

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58.  Wards Island  STP Step Aeration  Operation  Results, N.Y.C. Department of Public
     Works, Division of Engineering (1953-1955).

59.  Ullrich, A.H., and Smith, M.W., "The Biosorption of Process and Waste Treatment,"
     Sewage and Industrial Wastes, Vol. 23, No. 10, pp. 1242-1253 (October 1951).

60.  Ullrich,   A.H.  and  Smith,   M.W.,  Operation  Experience  with  Activated
     Sludge-Biosorption at Austin, Texas. Journal Sewage and Industrial Wastes, 29, No. 4,
     pp. 400-413 (April, 1957).

61.  Robson, C.M., Block, C.S., Nickerson, G.L., and Klinger, R.C., Operational Experience
     of a Commercial Oxygen Activated Sludge Plant. Presented before the 45th Annual
     Conference, Water Pollution Control Federation, Atlanta, Georgia (October 12, 1972).

62.  Nickerson, G.L. and  Van  Atten,  J.L.,  Westgate-A Study  in  Plant Modification.
     Presented before the Chesapeake Water Pollution Control Association and Water and
     Waste  Operators Association of Maryland, Delaware and District of Columbia (June 8,
     1973).

63.  Westgate Plant Operating Data (April 29 through May 31, 1972).

64.  Process Design  Manual for Phosphorus Removal.  U. S. EPA Office  of Technology
     Transfer, Washington, D.C. (revised 1974).

65.  Sawyer,  C.N., Design  of Nitrification and Denitrification  Facilities.  Presented at a
     Symposium on  Design of Wastewater Treatment Facilities. Presented by U. S. EPA,
     Cleveland, Ohio  (April 22-23, 1971).

66.  Nitrification   and Denitrification   Facilities.  Prepared  for  U. S. EPA Technology
     Transfer Program (1972).

67.  Jenkins, D. and Garrison, W.E., Control of Activated Sludge by Mean Cell Residence
     Time.  Journal Water Pollution Control Federation, 40, No. 11, p. 1905 (1968).
                                       5-60

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                                   CHAPTER 6

                  CLARIFICATION AND CHEMICAL TREATMENT
6.1 Advantages of Upgrading Clarifiers

    6.1.1  General

One of the more important  considerations in any upgrading situation is the utilization of
overloaded clarification  units.  In  many cases,  it  is  possible to  achieve  substantial
improvements in their performance by the use of appropriate upgrading techniques.

By improving the performance of existing clarifiers, the requirement for new facilities can
be minimized. In a typical activated sludge plant, it can be expected that with an increased
capture of 1.0 mg/1 of SS, a concurrent reduction of about 0.6 mg/1 of BOD will be attained
in the final effluent. Consequently,  the required capacity of new units providing either
physical or biological treatment may be reduced.

Clarifier performance can be improved in two  ways.  The first is to  improve the physical
characteristics of the tanks to achieve more efficient settling and compaction. The second
approach  is  to introduce  chemicals  into the  wastewater  to  improve the  settling
characteristics of the  SS.

    6.1.2  Primary  Clarifiers

The upgrading of primary clarifiers has the following advantages:

     1.   Improved BOD and SS removals at the same flow or similar BOD and SS removals
          at somewhat higher flows.

     2.   An increase in quantity of primary sludge produced which can be more readily
         thickened and dewatered than secondary sludge.

     3.   A decrease  in quantity of secondary sludge produced.

    4.   A decrease  in organic loading to secondary treatment process units.

Primary clarifier performance significantly influences  the extent of secondary treatment
required and, in most cases, affects the overall effluent quality  of existing treatment plants.
Also,  since clarification is the most  economical way to remove suspended and colloidal
pollutants, every effort should be made to improve the primary clarification process before
additional primary or secondary facilities are considered.

                                       6-1

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     6.1.3   Secondary Clarifiers

The performance of secondary wastewater treatment systems is determined by comparing
the quality of the  overflow from secondary clarifiers to that of the incoming wastewater.
The biological treatment  unit converts a portion  of  the soluble and insoluble  organic
pollutants to suspended organic solids (biological). Unless these organic solids are effectively
removed in the secondary clarifiers, the treatment process cannot be considered a successful
operation.  In fact, of all the  process design variables  which can affect  overall  plant
performance,  those which  are selected for  secondary clarification  are among the  most
critical.

Effective secondary clarification also will allow more efficient disinfection, reduce the
frequency of cleaning chlorine contact tanks, and provide an aesthetically pleasing effluent.

6.2  Process Design of Clarifiers

     6.2.1   Primary Clarifiers

Primary clarifiers are designed mainly on the basis of hydraulic overflow rates. In practice,
the designer will select appropriate overflow rates for the average and peak flows  being
considered.  Required surface  areas are  then calculated for both conditions and the larger
area is used.  In  many cases, especially in combined  collection systems,  the peak flow
conditions will govern the  design. It should be recognized, however, that clarifier efficiency
at peak flows is a  function of both magnitude and duration. Therefore, it is of extreme
importance  that the designer analyze past flow data and the characteristics of the collection
system in order to avoid a design based on a short duration peak which  may have little
effect on clarifier efficiency.

After selection of an overflow rate, the detention  time in the clarifiers will be set by the
depth. Generally,  SS in raw wastewaters  are susceptible to some  degree of flocculation.
Adequate detention time should be provided to allow this flocculation to occur and in turn
increase the clarifier efficiency.  Normally, the depth should be set to provide a detention
time of 90 to 150 minutes.

For  rectangular tank  design,  the longitudinal velocity of  flow must also  be considered.
Excessive velocities can result in scouring of  settleable solids with subsequent losses to the
effluent.  Peak velocities greater than four to five fpm should be avoided.  Tank length to
width ratios of less than 3:1 should be avoided to prevent short-circuiting.

Typical design parameters for primary clarifiers are presented in Table 6-1. These parameters
are based on municipal wastewaters containing pollutants in the concentrations normally
encountered. For wastewaters containing a high percentage of industrial wastes, it may be
advantageous to initiate a testing program to determine design criteria. Based on the values

                                         6-2

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presented in Table 6-1, it can be anticipated that a well-designed primary clarifier will be
capable of removing 30 to 35 percent of the BOD and 50 to 60 percent of the SS from a
domestic wastewater.
                                     TABLE 6-1
            TYPICAL DESIGN PARAMETERS FOR PRIMARY CLARIFIERS

                                     Overflow Rate
     Type of Treatment          Average	Peak
                                       gpd/sq ft

Primary Settling Followed
 by Secondary Treatment       800-1,200     2,000-3,000               10-12

Primary Settling with Waste
 Activated Sludge Return       600-800       1,200-1,500               12-15
     6.2.2   Secondary Clarifiers

The function of secondary clarifiers varies with the method of biological treatment utilized.
Clarifiers following trickling filters must effectively separate biological solids sloughed from
the filter media. Clarifiers in an activated sludge system serve a dual purpose. In addition to
providing a clarified effluent, they must also provide a concentrated source of return sludge
for process control. Adequate area and depth must be provided to allow this compaction to
occur  while avoiding rejection  of  solids into the tank effluent. Secondary clarifiers in
activated sludge systems are also sensitive to sudden changes in flow rates.  Therefore, the
use  of multispeed  pumps for  in-plant wastewater lift stations is strongly recommended
where flow equalization is not provided.

The design of clarifiers following trickling filters is based on hydraulic overflow rates similar
to  the  method  described  for primary  clarifiers.  Design overflow  rates must include
recirculated flow where clarified secondary effluent is used for recirculation. Because the
influent SS concentrations are low, tank solids loadings need not be considered. Typical
design parameters for clarifiers following trickling filters are presented in Table 6-2.

Clarifiers in activated sludge systems must be designed not only for hydraulic overflow rates
but  also for solids loading rates. This is due mainly  to the need for both clarification and
thickening in  activated  sludge clarifiers to provide both  a well  clarified effluent and a
concentrated return sludge.

When the MLSS concentration is less than about 3,000 mg/1, the clarifier size will normally
be governed by hydraulic overflow rates. At higher MLSS values, the ability of the clarifier
to thicken solids becomes the governing factor. Therefore, solids loading rates become more

                                        6-3

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critical in determining tank size. Design size should be computed for both average and peak
conditions to insure satisfactory effluent quality at all times.
                                    TABLE 6-2
        TYPICAL DESIGN PARAMETERS FOR SECONDARY CLARIFIERS
                         Overflow Rate
 Type of Treatment    Average       Peak
                            gpd/sq ft

Settling Following
  Trickling Filtration    400-600    1,000-1,200

Settling Following Air-
  Activated Sludge
  (Excluding Extended
  Aeration)            400-800    1,000-1,200
                   Solids Loading!
               Average        Peak
                Ib solids/day/sq ft
Settling Following
  Extended Aeration    200-400
800
                   20-30
20-30
           < 50
< 50
Settling Following
  Oxygen-Activated
  Sludge with Primary
  Settling              400-800    1,000-1,200
                   25-35
           <50
                                          10-12
            12-15
12-15
            12-15
  Allowable solids loadings are generally governed by sludge settling characteristics associated
  with cold weather operations.
Depth of clarifiers in activated sludge systems is extremely important. The depth must be
sufficient to permit the development of a sludge blanket, especially under conditions when
the sludge may be bulking. At the same time, the interface of the sludge blanket and the
clarified wastewater should be well below the effluent weirs.

For  rectangular  tanks, criteria similar to those given for primary tanks  also apply to
secondary tanks. However,  in  long tanks it is common practice to locate the sludge
withdrawal hopper about  1/3 to  1/2 the distance to the end of the tank to reduce the
effects of density currents.

Typical design parameters for clarifiers in activated sludge systems treating typical domestic
wastewaters  are  also presented in  Table 6-2. The design of these clarifiers should be based
upon  an  evaluation  of  average  and  peak overflow  rates and solids  loadings. That
combination of parameters which yields the largest surface area should be used.
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6.3  Physical Upgrading of Clarifiers

     6.3.1   Optimization of Aeration Tank — Clarifier Relationship

The activated sludge process is flexible in that the operator can vary the rate of sludge
wasting, thereby controlling the MLSS concentration to maintain the F/M and SRT at any
desired value. However, the MLSS in the aeration tank, in conjunction with the return
sludge rate, has a direct effect on the solids loading and capture efficiency of the secondary
clarifiers. Therefore when evaluating the performance of an existing treatment plant and/or
planned expansions, it is important  to  analyze aeration tanks, secondary clarifiers, and
return and waste sludge pumps as a system.

In many treatment  plants,  the MLSS concentration will be altered to  achieve a desired
operating condition in the aeration tanks without considering the possible adverse effects on
the secondary clarifiers. It is common practice among many operators to carry  high MLSS
concentrations to increase SRT, thereby oxidizing more organic matter and reducing waste
sludge mass.  In many instances, the high solids loading rate associated with high MLSS
concentrations will cause the sludge blanket to rise to a level where solids will be swept over
the effluent weirs. Thus it is essential that a proper solids balance be maintained between
the aeration tank and clarifier.

Improved performance through optimization of internal process balances was accomplished
at both the Coldwater Creek Wastewater Treatment Plant in St. Louis,  Missouri,  and the
Sioux Falls, South Dakota, Wastewater Treatment Plant. Case histories of the upgrading of
these  plants   presenting the  major  modifications  implemented  and  resultant removal
efficiencies are described in Chapter 13.

     6.3.2  Inlet-Outlet Configurations

Typical inlet-outlet arrangements for circular clarifiers are shown on Figure 6-1. Figure 6-la
is the most common arrangement currently in use. The influent is carried to the center of
the tank by means of a pipe that may be  either suspended a few feet below the water
surface or constructed beneath  the tank floor. A circular baffle is provided at the center of
the tank to dissipate the energy generated by the influent discharging into the tank and to
distribute  flow  equally  in  all  directions. The  diameter of the influent well  should be
approximately 15 to 20 percent of the clarifier diameter. The well should  extend deep
enough into the  clarification zone  (at least 1/2 the tank depth)  to insure good distribution,
but should  be high enough above the  sludge zone to prevent scouring of settled sludge. The
clarified effluent leaves the tank over a circular  weir located at the perimeter of the tank.
For large circular tanks, the clarified effluent may be removed  by means of a cantilevered
circular effluent  trough at a  point  about 2/3 to 3/4 of the clarifier radius. The  purpose of
such an arrangement  is to reduce weir hydraulic loadings and approach velocities to
discourage the creation of currents which may  travel along the clarifier floor and up the

                                       6-5

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                         FIGURE 6-1
             TYPICAL CLARIFIER CONFIGURATIONS
                                                 EFFLUENT
           SLUDGE
INFLUENT
            8-ta CIRCULAR CENTER-FEED CLARIFIER WITH
                 A  SCRAPER SLUDGE REMOVAL  SYSTEM
INFLUENT
                                                  EFFLUENT
                                           7-* SLUDGE
      6-lb CIRCULAR RIM-FEED, CENTER TAKE-OFF  CLARIFIER WITH A
             HYDRAULIC  SUCTION SLUDGE REMOVAL  SYSTEM
                                               SLUDGE
           B-lc CIRCULAR RIM-FEED, RIM TAKE-OFF  CLARIFIER
                               6-6

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clarifier wall. However, many  designs of  this type  have an opposite result when  the
cantilevered trough is insufficiently far from the tank wall. In  such cases, high upward
velocities  in  the  annular  space  between the wall and the trough will actually create a
significantly worse condition than that which would have existed with a single peripheral
weir.

Rectangular tanks also perform effectively with appropriate inlet  and outlet arrangements.
Frequently,  poor hydraulic  distribution  in  an  influent  channel  common  to  several
rectangular tanks will cause some of the tanks to become overloaded. It is good design
practice to provide sufficient head loss in the ports feeding the tanks which will negate the
effect of water level variations within the distribution channel.

Inlet baffles for rectangular tanks should extend to at least 1/2 the tank depth to minimize
short-circuiting.  Effluent  weir arrangements should be  checked carefully for excessive
upward velocities. A  common tank  deficiency  is to have adequate weir length,  but with
closely spaced troughs creating high rising velocities, enhancing solids losses at higher sludge
blanket levels.

Inefficient scum removal can adversely affect plant performance. Scum is usually trapped on
the tank  surface by  means  of  baffles  placed  in  front of the effluent weirs. Skimmers
connected to the arms of the sludge collectors, separate helical devices, or tiltable slotted
pipes are used for scum collection and withdrawal. To insure adequate scum capture, baffles
should project  9  to  12 inches below the water surface. Since  scum  removal is ordinarily
accompanied by large volumes of water, decanting facilities are  desirable to avoid excess
water in digestion and dewatering operations.

Two types of  rim-feed circular clarifiers are shown on Figures 6-lb and 6-lc.  A baffle
located a  short distance from the tank wall forms an annular space into which the influent
wastewater is discharged in a tangential direction. The influent flows spirally around the
tank and underneath the baffle.  The effluent may be removed by either a centrally located
weir trough as shown on Figure  6-lb or by a trough along the tank perimeter as shown on
Figure 6-lc.  Typically, scum is removed by  means of a slotted pipe at the end of the
influent annular ring.

It has been demonstrated  that the flow pattern generated  by the  rim-feed clarifier is more
stable with varying hydraulic loads than the flow pattern which  is developed in circular
center-feed clarifiers  (1) (2) (3).  Bergman  (3) noted  that  rim-feed clarifiers with center
takeoff were more stable than center-feed clarifiers when subjected to varying thermal loads,
i.e., variation between the temperature of the incoming wastes and the  wastes in  the
clarifiers.  Studies undertaken by  Dague, et al, (2) indicate that center-takeoff rim-feed
clarifiers are hydraulically two to four times more efficient than center-feed clarifiers.
                                        6-7

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Cleasby, et al,  (4) indicate  that rim-feed and center-feed clarifiers should have the same
removal efficiency when handling discrete particles and that rim-feed clarifiers should have
higher removal efficiencies when handling flocculent solids.

Although some of the papers cited above suggest that the rim-feed concept is superior to
center-feed units, the conversion from center-feed to rim-feed has not been used extensively
as an upgrading technique. Some of the impediments to such a conversion are:

     1.    Structural  modifications to inlet  and  outlet configurations may be  extensive,
          especially if the inlet pipe passes under the tank floor.

     2.    Scum removal in rim-feed, center-takeoff  clarifiers  is somewhat less effective
          because  only the  annular  influent ring is available for scum separation and
          removal. With this arrangement, floating sludge is free to escape the tank.

     3.    The location  of the effluent weirs in rim-feed, center-takeoff clarifiers results in
          relatively short weir length and high approach velocities.

     4.    The  support  system of  the  central weir  trough must be designed to avoid
          interference with existing sludge collector mechanisms.

The limitations outlined in the last three comments above are largely eliminated in rim-feed,
rim takeoff designs.

It is now more common to construct center-feed tanks as deep as originally used in rim-feed
units (12 to  14 feet). The trend is also towards deeper inlet baffles and to  suction type
sludge collectors in  center-feed tanks.  These features  have commonly been installed in
rim-feed tanks for many years. Consequently, the advantages of the rim-feed units have been
reduced.  In  most cases,  it can be expected  that the  cost benefit of  conversion from
center-feed to rim-feed will be lower than the cost benefit of other upgrading techniques.

Fall (5) has  described a system in the Greater Peoria Sanitary District Sewage Treatment
Plant where  changes in inlet and  outlet designs were  implemented to  improve clarifier
performance. The existing primary clarifiers were square tanks with inlet ports along one
side and  outlet ports along the opposite side. The secondary clarifiers (following aeration
tanks) were  similar in design except an effluent  weir was provided in lieu of  outlet ports.
These tanks  were experiencing extreme short-circuiting, up to about 1/4 of the theoretical
detention time, resulting in poor  SS  capture. One  primary  and one final clarifier were
modified as indicated on Figure 6-2. After modification, the influent enters the  tank from
two opposite sides through pipes that  discharge near the bottom  of the tank. Velocities
generated by the influent pipes carried  the solids to the center of the tank where the solids
are collected. The clarified  effluent is removed over a peripheral weir.  The modified tanks
showed actual and theoretical detention times that were  about equal. Peak primary tank

                                        6-8

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                         FIGURE  6-2
       CLARIFIER MODIFICATIONS AT  THE GREATER PEORIA
               SANITARY DISTRICT SEWAGE PLANT
SLUDGE
                           EFFLUENT  CONDUIT
                                                     EFFLUENT
                                                     TROUGH
                       EFFLUENT WEIR

                                PIPES
                                                      -INFLUENT
                                                       CHANNEL
                              INFLUENT

                           6-2a  TOP VIEW
                INFLUENT CHANNEL
                .EFFLUENT TROUGH
        SLUDGE
                                                     INFLUENT
                                                     PIPES
                         6-2D SIDE  VIEW
                             6-9

-------
overflow rates as high as 4,100 gpd/sq ft were encountered with very little loss in average SS
removal  efficiency. Based on these test results, the entire plant  was converted to the
modified clarifier design. Since this conversion, there have been other process modifications
and changes in plant loadings. As a result, it has been difficult to verify the improvement in
plant performance due to the clarifier modifications.

     6.3.3   Control of Problem Sludges

Two of the major problems encountered in activated sludge systems are rising sludge and
bulking sludge.  In  many instances these problems can be corrected through operational
control. Where operational control is limited, plant modifications may be required.

         6.3.3.1   Rising Sludges

Sludge accumulation  on the bottom of secondary clarifiers for excessively long periods
often  causes  oxygen  deficient  conditions. If  the biological system is  nitrifying, the
accumulated sludge may undergo denitrification, which occurs when the oxygen contained
in nitrites  and nitrates is used  to satisfy the oxygen  demand of the settled sludge. As
nitrate-bound  oxygen is  consumed,  nitrogen  gas is formed and becomes  trapped in the
sludge  mass. If enough gas is formed,  portions of the sludge mass become buoyant and rise
to the surface.

The  problem  can  usually be solved by reducing the residence time of the sludge in the
clarifier. Corrective actions that may be taken are:

     1.  Increase the return sludge pumping rate.

     2.  Increase the speed of the sludge collector (if possible).
                        \
     3.  Increase the sludge wasting rate.

In some instances, floating sludge has  been caused by the organism Nocardia actinomyces.
This condition is difficult to eliminate and is evidenced by a heavy brown scum on aeration
tanks and final clarifiers. Some success has been achieved by the following:

     1.  Chlorination of return sludge or MLSS

     2.  Lowering DO to 0.5 mg/1 or  less

     3.  Reducing MLSS concentration

     4.  Raising pH to 7.5 to 8.0 by lime addition (6).
                                        6-10

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Plant modifications that may improve sludge management include increasing the capacity of
return and waste sludge pumping, installing sludge blanket finders, and replacing plow-type
sludge collectors  with  suction-type units. The suction-type units will remove the sludge
directly from the clarifier bottom through suction orifices that sweep the entire bottom of
the tank during each revolution. They are recommended for clarifiers with diameters greater
than 50 feet.

         6.3.3.2   Bulking Sludges

A bulked sludge is one  which has poor settling characteristics and poor compactibility. Two
principal types of sludge  bulking have  been  identified.  One is  caused  by the growth of
filamentous organisms  (7) (8)  or  organisms which can grow in a filamentous form under
adverse  conditions. The other is caused by bound water,  in  which the bacterial cells
composing the floe swell through the addition of water to the point  that their density
approaches that of water.

The causative factors  normally associated with  sludge bulking  and the recommended
preventive actions are as follows:

     1.   DO content:  Limited DO has been noted more than any other cause of bulking.
         The DO in the aeration tank should be normally maintained at or above 2 mg/1.

     2.   Process loading: The F/M should be maintained  within the recommended range
         for the  operational  mode of  the  type of  activated  sludge  plant being used.
         Recommended ranges are given in Chapter 5. SRT has  also been shown to be an
         effective tool in preventing the growth of filamentous organisms. Stamberg et al
         (9)  found, for oxygen and conventional  activated sludge systems at the EPA-DC
         Pilot Plant, that for  SRT's below five days, both systems exhibited filamentous
         growth. Such growths  did not occur  at  SRT's greater than five days.  When
         encountering  filamentous growth for  a few  days only,  increasing the  SRT
         reestablished a filamentous free sludge in  several days.

     3.   Wastewater characteristics: If it is known that industrial wastewaters are being
         introduced to the system,  the quantity of nitrogen and phosphorus in the
         wastewater should be checked,  since limitations of either are known to favor
         bulking. Wide fluctuations in BOD and pH should also be checked. The presence
         of toxic substances has also been implicated as a cause of bulking.

     4.   Clarifier operation: Evaluation of clarifier performance should be made. This is
         particularly applicable  to rectangular  and  center-feed circular tanks.  Profile
         sampling of the sludge blanket may show that a large part of the sludge is retained
         in the tank for many hours rather than the desired 30 minutes. Such a condition
         may require major modifications to the clarifier's sludge collection system.

                                       6-11

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When filamentous growths become firmly entrenched in the biomass, it is doubtful any of
the above actions will be effective. In these situations, chemical treatment to selectively
destroy these growths has been successful as discussed below:

     1.   Chlorination of wastewater, mixed liquor  and return sludge has  been found
         effective in controlling bulking due to filamentous growths. It is ineffective when
         bulking is  due to light, diffuse floes. Recommended dose rates based on return
         sludge flow are between 0.2 and 1.0 Ib of chlorine per 100 Ib of return sludge
         solids. This method is only considered as a temporary measure and should not
         exceed 24 hours duration.  Selective destruction of filamentous organisms by
         chlorination generally will cause a turbid effluent until the destroyed organisms
         are washed out of the system.

     2.   Application of hydrogen peroxide has also been employed successfully for control
         of filamentous growths  for both air and oxygen  activated sludges. At the EPA-DC
         Pilot Plant, continuous  dosing of the return sludge for  24 hours with a hydrogen
         peroxide dosage of 200 mgA (based on plant influent) resulted in an immediate
         improvement  in   sludge  settling  and  a  gradual  recovery  of  system
         performance (10).

     6.3.4   Tube Settlers

The information regarding tube settlers presented in this section is addressed only to the
upgrading of existing, conventionally designed ciarifiers. A detailed discussion for the design
of  tube settlers  is  presented  in  the  Process Design Manual  for Suspended Solids
Removal (11).

According to  the classical theory of discrete particle settling, the efficiency of  suspended
particle removal in  a sedimentation basin is  solely a function of overflow rate and is
independent  of depth  and detention time.   If the  above  theory is applicable to raw
wastewater  or activated sludge  floe settling, then the clarifier  performance could  be
improved by introducing a number of trays or tubes in the existing ciarifiers. This concept
has led to the development of the tube settler. Although tube settlers have been installed in
several  existing plants,  little  comparative  data have  been  published to  verify  their
effectiveness as  an upgrading technique. However,  it can be expected that as  additional
operational data are  developed, the use of tube settlers may  warrant further consideration.

Tube settlers have been used in primary and secondary ciarifiers to improve performance as
well as to increase throughput in  existing ciarifiers. Conley and Slechta (12) and  Hansen, et
al, (13) have described the performance of several plant-scale installations of tube settlers in
primary and secondary ciarifiers.  The results of their studies indicate that the overflow rates
in primary ciarifiers can be substantially increased while producing the same quality effluent
as the control unit without the settlers.

                                        6-12

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One  manufacturer of  tube settlers has  suggested  the  peak  overflow rate for circular
secondary clarifiers  in  activated  sludge systems  be  limited  to about  1.0 gpm/sq ft
(1,440 gpd/sq ft) for the tube settler area  (14). These values apply to 70 deg F wastewaters
and should be reduced  by a factor of two at 40 deg F. This value is essentially the same as
that recommended for  secondary clarification without tube settlers. Therefore, tube settlers
are not expected  to  accomplish a saving  in tank area. A minimum tank depth  of  10 to
12 feet is necessary  to accommodate  the tube modules and to provide sufficiently  low
approach velocities.

Tube settlers enhance the ability to capture settleable solids at  high overflow rates because
the depth of settling has been reduced to a few inches in the tube. It should be realized that
tube settlers do not improve the efficiency of primary clarifiers that are already  achieving
very high (40 to  60 percent) removals of SS. Moreover, tube settlers  will neither remove
colloidal solids that remain in suspension nor induce additional  coagulation to effect added
particle removal. A portable tube settler unit has been evaluated following primary clarifiers
that were handling paper mill wastewaters which contain  a high concentration of solids.
With this arrangement,  it  was possible to appreciably increase the hydraulic capacity of the
primary system without reducing the quality of the effluent (15).

The characteristics of the existing tanks will play a large  part in determining the feasibib'ty
of installing tube settlers. In many upgrading situations, the tube settlers are installed over a
portion of the basin near the  outlet. For example, in circular basins, the tubes are  placed in
pie-shaped segments in  a ring around the basin outer wall. Major physical factors that must
be considered are:

     1.   Provision of adequate tank depth

     2.   Provision for  adequate sludge management and storage

     3.   Modifications to existing effluent weir troughs

     4.   Potential conflicts with sludge and scum collection equipment.

Fouling due to biological  growths on the tubes has been cited as an operating problem. This
problem  has largely been overcome by the  installation of permanent air headers beneath the
entrance to the tubes.  Typical installation details are shown in  the Process Design Manual
for Solids Removal (11). Algal growths near the water surface can sometimes be controlled
by covering the clarifiers to block direct sunlight.

Since the flocculating and settling characteristics of  sludge vary from plant to plant, each
case should be evaluated separately for suitable design criteria. Small pilot units are available
from the manufacturer for this purpose.
                                        6-13

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Operational data for tube settlers  at  three locations  are  presented in Table 6-3. These
installations employ tube settlers for clarifying activated sludge mixed liquor. At the two
locations, Hopewell Township and Lebanon, where comparative data are available, the tube
settlers have markedly outperformed conventional clarification. Case histories for these two
installations are presented in the Process Design Manual for Solids Removal (11).

6.4  Chemical Treatment

Chemical addition to primary and secondary clarifiers  in this manual is addressed only to
increased solids and BOD removal. Chemical treatment for phosphorus removal is covered in
detail in  the Process Design Manual  for Phosphorus Removal (18). A detailed discussion of
chemical properties, storage facilities, and feed equipment is presented in the Process Design
Manual for Suspended Solids Removal (11).

     6.4.1   Chemicals Used

The chemicals commonly used in wastewater treatment are the salts of iron and aluminum,
lime, and synthetic  organic poly electrolytes. The iron (ferrous and ferric) and aluminum
salts (sodium  aluminate or alum) react with the alkalinity and soluble orthophosphate in
wastewater to form precipitates of the respective metallic hydroxides or phosphates. In
addition, they destabilize the colloidal particles that would otherwise remain in suspension.
These precipitates,  along with the destabilized colloids, flocculate and settle readily in a
clarifier.

Both alum and sodium aluminate exhibit great capability for total phosphorus removal, but
the use of alum introduces six times as much dissolved solids to the wastewater as does
sodium  aluminate (19). Normally, lime is used to precipitate hydrous oxides of iron and
aluminum when the alkalinity of wastewaters is low.  The reaction of iron and aluminum
salts is pH-dependent and has to be evaluated for each  case to determine the most effective
pH range and the optimum chemical dosage.

The addition of hme alone is also effective in coagulating wastewater. The positive calcium
ions  destabilize  colloidal particles  while  precipitating  soluble  orthophosphates as
hydroxyapatite. Since lime treatment takes place at pH 9.0 to 11.5, pH adjustment may be
required before subsequent biological  treatment depending on the operating pH and the
degree of biologically induced recarbonation that occurs. This requirement may be reduced
or eliminated for biological systems that nitrify.

     6.4.2  Addition of Chemicals to Primary Clarifiers

In the early stages of wastewater treatment, especially  in the late 1930's and early 1940's,
chemicals were used to improve the efficiency of primary clarification systems. Later, when
these systems were followed by secondary treatment processes, the practice  of adding

                                       6-14

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         TABLE 6-3
TUBE SETTLER INSTALLATIONS
                               Operational Data Using Tube Settlers
Plant Location

Hopewell Township ,
Pennsylvania
£ Trenton,
01 Michigan
Lebanon,
Ohio
Type

Activated
Sludge
Activated
Sludge
Activated
Sludge
Plant Flow Tube Existing Facility Tube Over- Tank Over-
Design Actual Location Overflow Rate Effluent SS flow Rate flow Rate Effluent SS
mgd mgd gpm/sq ft mg/1 gpm/sq ft gpm/sq ft mg/1
0.13 0.13 Secondary 0.34 60-70 -
Clarifier - -2 0.68 27
6.5 5.6 Secondary - - 0.56 0.29 8
Clarifier
0.75 1.25 Secondary 0.61 61 0.85 0.61 30
Clarifier
Reference

13
16
17

-------
chemicals to upgrade primary treatment became unnecessary. However, the technique of
adding chemicals to the primary clarifier is still an effective upgrading procedure for a
secondary plant when the following conditions exist (20):

     1.   Wastewater flow is intermittent or varies greatly.

     2.   Space available for additional clarification facilities is limited.

     3.   Industrial wastes that would interfere with biological treatment are present.

     4.   Plant is hydraulically and/or organically overloaded.

     5.   Improvements  in existing treatment  performance are  required as an interim
         measure before the addition of new facilities.

When considering the addition of chemicals to primary clarifiers, it is important to examine
the effect of  increased primary clarifier efficiency on subsequent treatment units.  The
increased  removal of  SS and  BOD from raw  waste water  can  affect the downstream
biological process  in several ways. If the BOD  load to  the aerator falls below 0.25 to
0.35 Ib BOD/lb MLVSS/day for extended periods of  time, nitrification conditions can
develop in the aerator. This can reduce the total oxygen demand of the effluent, but will
impose  an added  oxygen demand on the aeration facility because the oxidation of one
pound of ammonia nitrogen requires about 4.6 pounds of oxygen.

A decrease in loading  to the aerator will normally require more careful management of
sludge to ensure stable operation of the  aeration basin. However, the quantity of excess
activated sludge generated under these reduced loading conditions will be substantially less
than  that generated under  normal loading conditions. This may be considered  an added
advantage of adding chemicals to the primary clarifier,  if the additional fines captured
chemically do not seriously degrade the quality of the primary sludge.

Little information has  been generated regarding the periodic addition of chemicals to the
primary clarifier for controlling peak organic or hydraulic loads. This approach,  while not
always applicable, can  frequently be used to' maintain system stability during temporary
overload.

The effect of  polyelectrolyte and coagulant addition on  primary clarifier performance is
shown in Table 6-4. Where plant information is available,  the performance of clarifiers
before and after the addition of chemicals is shown. The data show a considerable variation
in BOD and SS removals. However, the effect  of polyelectrolyte addition is pronounced
where the existing clarifier performance is poor. The variations shown make it difficult to
project  the expected improvement due to chemical addition at a specific treatment plant.
                                       6-16

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                                                                  TABLE 6-4
                         EFFECT OF CHEMICAL TREATMENT ON PRIMARY CLARIFIER PERFORMANCE
            Type and Amount
                  of
            Chemical Added
Purifloc - A21 (0.95 mg/1)
DOW -SA 1193 (0.2 mg/1)
Purifloc - A21 (1 mg/1)
Purifloc - A21 (0.75 mg/1)
Purifloc - A21 (0.89 mg/1)
DOW - SA1193 (0.25 mg/1)
Purifloc - A21 (1 mg/1)
FeCl2 + NaOH + Purifloc - A23 (0.3 mg/1)
FeCl2 + NaOH + Purifloc - A23 (0.3 mg/1)
Purifloc - A21 (1 mg/1)
Purifloc - A23 (0.25 mg/1)
FeCl3 + Purifloc - A23
FeCls + Purifloc - A23
Purifloc - A21 (0.74 mg/1)
Purifloc - A21M (1.14 mg/1)
FeCls (20 mg/1) + Purifloc - A23 (0.3 mg/1)
FeCl3(35 mg/1 Fe3+) + Purifloc - A23 (0.5 mg/1)
FeCl3 (15-18 mg/1 Fe3+) + Purifloc - A23
 (0.5 mg/1)
        mg/1 Fe3+) + Purifloc - A23 (0.5 mg/1)
      0-25 mg/1 Fe3+) + Purifloc - A23
 (0.4 mg/1)
FeCl3(22 mg/1 Fe3+) + Purifloc - A23 (0.5 mg/1)
Alum (15-20 mg/1 A13+) + Purifloc - A23
 (0.5 mg/1)
Alum (90 mg/1) + Polyelectrolyte (0.4 mg/1)
Alum (110 mg/1) + Polyelectrolyte (0.35 mg/1)
Weight
Performance Preceding Chemical Treatment Ratio of
SS Removed
mg/1
13
13
157
26
113
120
107
230
104
	
52
93
93
	
	
1
-

-

-



percent
12
12
43
18
43
47
47
82
49.7
	
31
33
33
50
43
1.3
-
35.5
-

-


_
BOD
mg/1
28
28
82
_
50
_
135
111
83
_
47
53
53
_
_
_
-

-

-


_
Removed WAS/PS1
percent
26 0.61
26 0.61
23
_ —
22
0.8
37
31
43.8
0.79
31 1.44
34
34
36
_ _
_ _
-
19.1
-

-

	 	
_ _
Performance After Chemical Treatment
SS Removed
mg/1
75
72
281
69
159
151
169
379
173
—
80
196
213
—
—
38
323
_
177
41
61.7
134.8
157
204
percent
65
55
76
52
60
61
62
79
76.8
—
51
74
68
63
63
24.4
80
63.6
74.5
74.0
84
70
84
74
BOD Removed
mg/1
46
36
127
-
87
-
154
74
105
-
58
102
97
—
—
-
249
	
-
115
226
423.9
66
126
percent
48
37
33
—
37
-
46
39
57.8
-
46.4
61
53
45
-
-
61
54.4
-
57.4
38
32
61.1
71
Weight
Ratio of
WAS/PS1 Reference

0.31 21
0.41 21
21
21
21
0.46 21
21
22,23
22,23
0.28 24
0.67 25
26
26
27
27
28
29
30
31
32
33
33
34
35
IWAS - Waste activated sludge
   PS - Primary sludge

-------
For proper evaluation, the characteristics of the wastewater and the effects of recycle flows
from  the sludge processing operations must be known. Such information can be obtained
through pilot plant tests or full-scale plant trials.

Freese,  et  al,  (27)  studied the  application of  polyelectrolytes  for raw wastewater
flocculation in the District of Columbia 7/ater Pollution Control Plant. Full-scale plant trials
were  conducted both with and  without recycle of elutriate to the primary clarifiers. The
overflow from gravity thickening was recycled to the primary tanks for all tests. Without
elutriate recycle, primary tank BOD  removals  were increased from  36 to  45 percent and
SS removals from 50 to  63 percent. Overall  BOD  removal was improved from 74 to
78 percent, but no improvement in overall SS removal was obtained. When the elutriate was
added to the  primary tank influent without poly electrolyte addition, poor capture of the
elutriate  solids   occurred.  Although  capture   of  elutriate  solids  improved   when
polyelectrolyte was added, a major portion of these solids still escaped and were captured in
secondary treatment.  This led to a gradual accumulation of elutriate  solids in  the  solids
processing system, which  increased the loadings on thickening, digestion  and elutriation
tanks. The increased loadings on the elutriation tanks caused by recycled  solids caused a
gradual decrease  in capture efficiency,  increasing the solids recycled to primary treatment. It
was concluded that polyelectrolyte application  to the raw wastewater with elutriate recycle
would not prevent the buildup of large  quantities of recycled solids through  the  solids
processing components, and that  the elutriation  tank efficiency  would be the focus of
further tests.

It has since been found that polyelectrolyte addition to  the elutriation tank has increased
the capture  of  solids in  the elutriation process from  57 to 92 percent. The resulting
improvement  in elutriate  clarity has enabled the plant to tolerate  the recycle without the
accumulation of fine solids (36).

Table 6-5 summarizes data of the effect of polyelectrolyte addition in primary clarifiers on
the primary and overall plant efficiency. The data reported covers both activated sludge and
trickling filter treatment plants.

Schmidt  and McKinney (39) studied phosphorus removal by lime addition  to the primary
clarifier of an activated sludge treatment plant. In this study, the system was operated at a
pH value of 9.5 which, during biological treatment, was reduced to a value between 7 and 8.
Therefore, no neutralization was required. The  lime precipitation step reduced the BOD by
60 percent, SS by  90 percent, and total phosphorus by 80 percent. However, Schmidt and
McKinney indicated that the lime-primary sludge was gelatinous  in nature and required
polyelectrolyte treatment  prior to dewatering by vacuum filtration. They further indicated
that the mass of  primary sludge is  about twice that obtained by conventional settling,
although the total  mass of primary and secondary sludge produced  is  increased by less than
50 percent. Lime addition to primary clarifiers for phosphorus removal has been  used in
many locations.  In all cases, significant improvements in both SS  and BOD removal were
noted. Table 6-6  presents the results of some of these studies.

                                        6-18

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                                    TABLE 6-5
              POLYELECTROLYTE ADDITION TO PRIMARY CLARIFIERS
                                     Primary Clarifier
                                 Total Plant
                                    Percent     Percent    Percent    Percent
                                   Removal   Removal    Removal    Removal
                                    Before      After      Before     After
                                     Poly-       Poly-       Poly-      Poly-
                                   electrolyte  electrolyte  electrolyte  electrolyte
Treatment Process  Coagulant  Dose   Addition   Addition    Addition    Addition   Reference
Activated Sludge   Purifloc
                  A-21
mg/1  BOD   SS  BOD   SS  BOD   SS  BOD   SS


 1      26-48-83-90-37
Trickling Filter    Purifloc
                  A-21       1      23   43    33   76   79    72   85    84    37

Activated Sludge   Purifloc
                  A-23      0.21    31   31    46   51   79    85   83    89    38

*Case history presented in Chapter 13.

                                    TABLE 6-6
                     LIME ADDITION TO PRIMARY CLARIFIERS

                        Percent Removal   Percent Removal
                        in Primary Before  in Primary After
Location Lime Added Lime Addition Lime Addition Remarks Reference
mg/1 CaO BOD
Duluth,
Minnesota
Rochester,
New York
Lebanon,
Ohio
Richmond
Hill, Ontario
Central Contra
Costa, Calif.
75 50
125 55

100

145

175 21
378 46
303 37
SS BOD
70 60
70 75

50

66

37 71
71 74
71 69
SS
75
90

80-90 Jar tests

74 Pilot plant

77 Full-scale plant
79 Full-scale test
76 Full-scale test

18


18

40

41
42

                                        6-19

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As mentioned  above,  the addition  of  lime  to the primary clarifier can be expected to
increase  the  primary sludge mass to about twice that obtained by  conventional primary
settling,  depending  on the operating  pH  and  alkalinity of  the incoming  wastewater.
Therefore, a complete evaluation of the sludge handling facilities  must  be  made when
considering this technique. For instance, some states have cautioned against this practice
when the primary sludge is to be anaerobically digested.

     6.4.3  Use of Chemicals in Secondary Processes

Much of the published information available on the addition  of  chemicals to secondary
processes emphasizes their use for phosphorus removal. These  studies have shown that in
many cases the addition of iron and aluminum salts can significantly improve secondary
clarifier performance depending upon the applied dosage, the  point of  addition, and the
flocculent  nature of the biomass. The results of several of these  studies are presented in
Table 6-7.

In certain processes, such as  trickling  filtration and  extended aeration,  solids may not
flocculate and settle well in the secondary clarifier. In these instances,  the addition of iron
or aluminum salts will  provide a greater benefit in improving plant performance than would
a similar chemical addition to an activated sludge that flocculates and settles well.

Polyelectrolytes have also been  used to  improve the performance of secondary clarifiers.
Singer, et  al, (43)  studied the  effect of adding cationic and anionic polyelctrolytes to
improve  settling characteristics of bulking activated sludge in the laboratory. Their studies
indicated that cationic  polyelectrolytes at a concentration of 2.0 to 3.0 mg/1 were effective
in coagulating a bulking activated sludge but  that the anionic polyelectrolyte tested had no
beneficial  effect on improving settling. Goodman and  Mikkelson (53) on  the basis  of
full-scale studies, concluded that application of cationic polyelectrolytes to primary clarifier
effluent  at the rate  of 0.1 Ib/ton of secondary dry solids increased overall BOD removal
efficiency to 95 percent and decreased  the loss of solids in the secondary effluent of the
activated sludge plant.

Based on studies conducted at the Hanover Treatment Plant  by the Metropolitan Sanitary
District  of Chicago, Zenz and  Pivnicka (54) have  shown that the addition of alum to
aeration  tanks  (primarily  intended for soluble phosphorus removal) improved flocculation
of activated  sludge.  However, their  results indicated that increasing  amounts of alum floe
escaped  through the final clarifiers  as the dosage of alum increased from an A1:P  weight
ratio of  1.54 to 1.85. The addition of alum to the aeration tank  favored the development of
lower organisms,  while  the higher forms  such as protozoa  and metazoa were absent.
Although higher forms of organisms are adversely affected by  the addition of alum, BOD
removal  is not  affected (54) (55). Earth and  Ettinger (47) found that dosages of 10 mg/1 of
alum (as A13+) in the secondary aerator did not interfere with the nitrification process.
Zenz and Pivnicka (54) also indicated that alum sludges can be stabilized anaerobically, and
that in this process the precipitated  phosphate is  not released, and is therefore permanently
removed from the system.

                                         6-20

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                                      TABLE 6-7
    EFFECT OF CHEMICAL TREATMENT ON SECONDARY CLARIFIER PERFORMANCE
                                       Effluent BOD5   Effluent SS   Effluent BOD5   Effluent SS   Total
Location

Richardson, Texas
Chapel Hill,
North Carolina
Pennsylvania State
Cincinnati,
Ohio
Lebanon,
Ohio
Minneapolis,
Minnesota
Madison,
Wisconsin
Lmversity Park,
Pennsylvania
Bloomington,
Illinois
Blue Plams,2
Washington, D.C
Sandusky, Ohio
Michigan City,
Indiana
Guelph, Ontano
Palmetto, Florida
Type of Plant
Tnckling filter
std. rate
Tnckling filter
high rate
Conventional
activated sludge
Activated sludge
(100 gpd pilot)
Activated sludge
(0.11 mgd pilot)
Tnckling filter
low rate
	
Trickling filter
Activated sludge
Tnckling filter
Modified Activated
sludge
Conventional
activated sludge
Conventional
activated sludge
Conventional
activated sludge
Tnckling filter
Location of Chemical and (or COD) Before Before (or COD) After After Phos
Chemical Addition Dosage Chemical Addition Chemical Addition Chemical Addition Chemical Addition Removal Reference

Before final settling
Before final settling
Aerator effluent
Aerator
Final clanfier
Before final settling
Before final settling
Before final settling
Aerator
Before final settling
Before final settling
Aerator
Aerator
Aerator
Before final settling
mg/1 mg/1
Al/P Mole
Dosage 1.6/1 20 15
Al/P Mole
Dosage 1.6/1 44 64
AVPwt
Ratio 3/1 13 26
10mg/IAl3+ (89%) 1 (95«)1
Add lime to
raisepH=9.4-10.9 — 435
720 mg/1
Ca(OH)2 83
200 mg/1
Alum 8-29
160 mg/1
Alum 18 31
46 mg/1
Na2Al2O4 61 95
33 9 mg/1 Fe3+
+0.7 mg/1
Punfloc - A23 8 8 12 7
25-30 mg/1 Fe3+
+0.5 mg/1
Punfloc -A23 130 496
26 mg/1 Alum 47 48
50 mg/1 Alum 38 39
60 mg/1 Alum 68 53
80 mg/1 Alum 46 41
89 mg/1 Alum 50 57
50 mg/1
Alum 9 24
60 mg/1
Alum 13 19
100 mg/1
Alum 26 38
45 mg/1 — 30-40
Alum
mg/1 mg/1 percent
<5 <7 95 44
15 34 82 45
9 22 86 46
(92%)' (96%)! 94 47
16.5 — 48
27 — 86 49
1 8-2.9 — 98 7 50
6 19 96 4
51
23 8 93 4
50 8.6 — 50
33 16.0 — 50
40 43
27 36
25 36 — 52
41 31
30 31
2 15 80 35
9 7 922 35
14 22 87 35
10 — 35
1 Percent removal
^Data arc monthly average.
                                        6-21

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Derrington, et al, (44) have reported adding 435 gpd of liquid alum (8.3 percent A^Os) to
the secondary clarifier of the  Richardson, Texas, trickling filter plant treating 1.6 mgd of
wastewater. The results indicated a reduction in effluent BOD and SS concentrations from
20 mg/1  and  15 mg/1,  respectively,  to  5 mg/1  and 7 mg/1.  The  effluent  phosphorus
concentration was reduced from 8 mg/1 to 0.5 mg/1. In addition, Derrington, et al, (44) have
reported problems of reduced alkalinity in sludge undergoing digestion when alum was used
as coagulant in primary treatment at the Richardson, Texas, plant. The addition of alum to
raw  wastewater was discontinued  after nine days  total  operation  to  prevent  further
reduction in  alkalinity and pH in the digester.  Studies undertaken at Pomona,  California
(46) indicated that the turbidity of  the final effluent may be increased when alum is added
to the aeration system. This may occur when the alum dosage is sufficient to lower the pH
below the optimu m pH for good alum flocculation, resulting in an increase in fines in the
final effluent.

Lime addition  may  not  be feasible  for upgrading  activated  sludge  secondary clarifiers
because of the potential adverse effect of recirculated lime sludge on mixed liquor microbial
characteristics. Lime addition to either trickling filter or activated sludge secondary clarifiers
will require pH adjustment of the effluent before discharge to the receiving waters. Lime
addition to primary  clarifiers may be used, if consideration is given to controlling the pH
within  acceptable limits for the  subsequent   processes,  and  to   changes in  sludge
characteristics and handling requirements. Generally, chemical addition will  increase the
weight of solids  and/or  the volume of sludge. Accordingly, sludge piping, pumping and
process  units  should  be of sufficient size and capacity to handle the increased quantities of
sludge.

6.5  References

 1.  Katz, W. J., and Geinopolos, A., A Comparative Study of the Hydraulic Characteristics
     of Two  Types of Circular Solids Separation  Basins. In Biological Treatment  of Sewage
     and Industrial Wastes, Vol. II, Anaerobic Digestion and Solids-Liquid Separation. Paper
     presented at the Conference on Anaerobic Digestion and Solids Handling, April 1957,
     Manhattan   College.  Edited   by  B. J. McCabe  and  W.W. Eckenfelder, Jr.,   New
     York: Reinhold Publishing Corporation, pp. 196-206 (1958).

 2.  Dague, R.R., and Bauman E.R., Hydraulics of Circular Settling Tanks Determined by
     Models.  Paper presented at the 1961 Annual Meeting of Iowa Water Pollution Control
     Association, Lake Okoboji, Iowa (June 8, 1961).

 3.  Bergman, B.S.,  An Improved  Circular  Sedimentation  Tank Design. Journal Institute
     Sewage Purification, Part I, pp.  50-67 (1958).

 4.  Cleasby, J.L., Bauman, E.R.,  and  Schmid,  L., Comparison of Peripheral  Feed and
     Center Feed Settling Tanks  Using Model.  Progress Report to Lakeside Engineering

                                       6-22

-------
    Corporation, Engineering  Experiment Station Project 387-S, Iowa State University,
    Ames, Iowa (February, 1962).

 5. Fall,  E.B., Jr., Redesigning Existing Treatment to Increase Hydraulic and Organic
    Loading. Presented at the 43rd Annual Conference of  the Water Pollution Control
    Federation, Boston, Massachusetts (October, 1970).

 6. Hankin,  L., Glover, W.D., and Anagnostakis, S.L., Elimination of Heavy Biological
    Scum in  Secondary Sedimentation Tanks. Journal of the New England Water Pollution
    Control Association, Vol. 6, No. 1, pp. 80-84 (June, 1972).

 7. Farquhar, G.J.,  and Boyle, W.C., Identification of Filamentous  Microorganisms in
    Activated Sludge. Journal  Water Pollution Control Federation, 43, No. 4, pp. 604-622
    (April, 1971).

 8. Farquhar,  G.J., and Boyle, W.C., Occurrence  of Filamentous  Microorganisms in
    Activated Sludge. Journal  Water Pollution Control Federation, 43, No. 5, pp. 779-798
    (May, 1971).

 9.  Stamberg, J.B., Bishop, D.F., Hais,  A.B., and Bennett, S.M., System Alternatives in
    Oxygen Activated  Sludge. Presented at the  45th  Annual Conference of the Water
    Pollution Control Federation, Atlanta, Georgia (October, 1972).

10. Cole, C.D., Stamberg, J.B.,  and Bishop, D.F., Hydrogen Peroxide Cures Filamentous
    Growth in Activated  Sludge. Journal Water Pollution Control Federation, 45, No. 5,
    pp. 829-836 (1973).

11. Process Design Manual for Suspended Solids Removal.U. S. Environmental Protection
    Agency, Office of Technology Transfer, Washington, D.C. (1974).

12. Conley, W.R., and Slechta, A.F., Recent Experiences in Plant Scale Application of the
    Settling  Tube Concept. Presented  at  the 43rd Annual  Conference of  the Water
    Pollution Control Federation, Boston, Massachusetts (October, 1970).

13. Hansen,  S.P., Gulp,  G.L. and Stukenberg, J.R., Practical Application  of Idealized
    Sedimentation Theory in Wastewater Treatment,  Journal Water Pollution Control
    Federation, 41, No. 8, pp.  1421-1444 (1969).

14. Neptune Microfloc Incorporated, Application Criteria for Tube Settling in Activated
    Sludge Plant, Secondary Chrifiers. Technical Release No. 3 (1972).
                                      6-23

-------
15.  Abrams, R.C., Use of Inclined Tube Settlers for Improved Clarifier Performance. Paper
     presented at the 32nd Annual Shibley Award Meeting of the Pacific Section, TAPPI,
     Tacoma, Washington (March 31, 1970).

16.  Neptune Microfloc Incorporated, City  of Trenton Sewage Treatment Plant.  Case
     History No. 27 (1971).

17.  Oppelt, E.T., Evaluation of High Rate Settling of Activated Sludge. Interim U. S. EPA
     Internal Report, Advanced Waste Treatment Laboratory, Cincinnati, Ohio (1973).

18.  Process Design  Manual for Phosphorus Removal.  U. S. Environmental Protection
     Agency, Office of Technology Transfer, Washington, D.C. (1974).

19. .Brenner, R.C., Phosphorus Removal by Mineral Addition.  Nutrient Removal and
     Advanced  Water Treatment  Symposium. Sponsored by  Federal  Water Pollution
     Administration, Cincinnati, Ohio (April 29-30,1969).

20.  Sewage  Treatment  Plant  Design.  Water Pollution  Control Federation  Manual  of
     Practice No. 8, Washington, D.C. (1959).

21.  Anon, Effects of Raw Sewage Flocculation in  Secondary  Waste Treatment Plants.
     Midland, Michigan:  The Dow Chemical Co.

22.  Wukasch, R.F.,  The Dow Process for Phosphorus Removal. Paper presented at the
     Phosphorus Removal  Symposium.  Sponsored by Federal Water Pollution  Control
     Administration, Chicago, Illinois (June, 1968).

23.  Wukasch, R.F., New Phosphate Removal Process. Water and Wastes Engineering,  5,
     No. 9, pp. 58-60(1968).

24.  Voshel, D., and Sak, J.G., Effect of Primary Effluent Suspended Solids and BOD on
     Activated Sludge Production. Journal Water Pollution Control Federation, 40, No. 5,
     Part 2, pp. R203-R212 (1968).

25.  Wirts, J.J., The Use  of Organic Polyelectrolyte for Operational Improvement of Waste
     Treatment   Processes.  Federal  Water   Pollution  Control   Administration,  Grant
     No. WPRD 102-01-68 (May, 1969).
                                      6-24

-------
26. Applications of Chemical Precipitation Phosphorus Removal at the Cleveland Westerly
     Wasteimter Treatment Plant. Prepared for the City of Cleveland, Ohio, by the Dow
     Chemical Co., Midland, Michigan (April, 1970).

27.  Freese, P.V.,  Hicks, E., Bishop, D.F., and Griggs, S.H., Raw Wastewater Flocculations
     with  Polymers  at  the District  of  Columbia Water Pollution Control Plant. Federal
    Water Quality Administration, Contract No. WPRD 53-01-67.

28.  Schuessler, R.G., Phosphorus Removal—A Controllable Process. Paper presented at the
    41st  Meeting, Water Pollution Control Association of Pennsylvania, University Park,
    Pennsylvania (August, 1969).

29. Parker, D.G., Raw Sewage Flocculation Trial at Stevens Point, Wisconsin, December 8,
     1971 to March 4, 1972. The Dow Chemical Company Report (1972).

30. The Dow Chemical Company, Phosphorus Removal by Chemical Precipitation at the
    Buffalo  Sewage Treatment  Plant.  Report prepared for  Consoer,  Townsend and
    Associates, Chicago and the Buffalo Sewer Authority (December, 1970).

31. Parker, D.G., Phosphorus Removal  Trial,  Lansing, Michigan.  Report prepared for
    McNamee, Porter, and Seeley  — Ann  Arbor and the City of Lansing by the Dow
    Chemical Co. (December, 1970).

32. Parker, D.G., Phosphorus Removal  Trial, East Lansing, Michigan. Report prepared for
    Hubbell, Roth,  and Clark, Inc., and the City of East Lansing by the Dow Chemical Co.
    (January, 1971).

33. Parker, D.G., Phosphorus Removal  Trial, Fond du Lac, Wisconsin. Report prepared for
    John A. Strand & Associates and the City  of Fond du  Lac, Wisconsin by the Dow
    Chemical Co. (July, 1971).

34. Allied Chemical Canada, Ltd., Phosphorus  Removal in  a Primary  Plant at Windsor,
    Ontario. Wastewater News, Allied Chemical Canada, Ltd. (February 5,1973).

35. Ockershausen, R.W.,  Upgrading Wastewater Plant Effluent by Chemical Treatment.
    Presented at the Joint Conference AWWA-FPCA, Orlando, Florida (November, 1973).

36. Dahl, Zelinski, and Taylor, Polymer Aids in Dewatering and  Elutriation. Journal Water
    Pollution Control Federation, 44, No. 2, pp. 201-211 (1972).

37. Mogelnicki,  S., Experiences in  Polymer Applications  to  Several Solids - Liquids
    Separation Process.  Proceedings - Tenth Sanitary Engineering Conference -  Waste
    Disposal from  Water and Wastewater Treatment Processes, University  of Illinois
    (February 6-7, 1968).

                                       6-25

-------
38.  Wirts, John J., The  Use of Organic Polyelectrolyte for Operational Improvement of
     Waste  Treatment   Processes.   Prepared  for  Federal  Water  Pollution   Control
     Administration, Grant No. WPRD 102-01-68 (May, 1969).

39.  Schmidt,  L.A., and McKinney, R.E., Phosphate Removal by a  Lime-Biological
     Treatment  Scheme. Journal  Water  Pollution  Control  Federation,  41,  No. 7,
     pp. 1,259-1,279 (1969).

40.  Villiers,   Ronald  V.,  Municipal  Wastewater  Treatment  by   Single  Stage  Lime
     Clarification and  Activated Carbon.  Internal U. S. EPA paper, Advanced  Waste
     Treatment Research  Laboratory, Cincinnati, Ohio (1971).

41.  Black, S.A., and  Lewandowski, W.,  Phosphorus Removal by Lime Addition to  a
     Conventional Activated  Sludge Plant. Division of Research Publication No. 36, Ontario
     Water Resources Commission (November, 1969).

42.  Central Contra Costa Sanitary District - Project Report for the Water Reclamation
    Plant. Brown and Caldwell Consulting Engineers, San Francisco, California (November,
     1971).

43.  Singer, P.C., Pipes, W.O., and Hermann, E.R., Flocculation of Bulked Activated Sludge
     with Polyelectrolytes.  Journal Water Pollution Control Federation, 40, No. 2, Part  2,
     pp. R1-R9 (1968).

44.  Derrington, R.E., Stevens, D.H., and Laughlin, J.E., Enhancing Trickling Filter Plant
     Performance  by Chemical  Precipitation.  U. S.  EPA,  Project 11010 EGL (August,
     1973).

45.  Brown, J.C., Little,  L.W., Francisco, D.E., and Lamb, J.C., Methods for Improvement
     of Trickling Filter Plant Performance, Part II, Alum Treatment Studies.  U. S. EPA,
     Contract  No. 14-12-505, University of North Carolina, Chapel Hill, N.C. (1974).

46.  Directo,  L.S., Miele, R.P., and Masse, A.N., Phosphate Removal by Mineral Addition  to
     Secondary and Tertiary Treatment Systems. 27th Industrial Waste Conference, Purdue
     University, Lafayette, Indiana (May 2-4, 1972).

47.  Barth, E.F.,  and Ettinger, M.B.,  Mineral  Controlled Phosphorus  Removal  in the
     Activated Sludge Process.  Journal Water Pollution Control Federation,  39,  No. 8,
     pp. 1,362-1,368 (August, 1967).

48.  Berg, E.L., Brunner,  C.A., and William, R.T., Single-Stage Lime Clarification  of
     Secondary Effluent. Water and Wastes Engineering, 7, pp. 42-46 (March, 1970).
                                        6-26

-------
 49.  Owne, R., Removal of Phosphorus from Sewage Plant Effluent with Lime. Sewage &
     Industrial Wastes, 24, No. 5, pp. 548-556 (May, 1953).

 50.  Lea, W.L., Rohlich, G.A., and Katz, W.J., Removal of Phosphate from Treated Sewage.
     Sewage & Industrial Wastes, 26, No. 3, pp. 261-275 (March, 1954).

51.  Long,  D.A., Nesbitt, J.B.,  and Kountz, R.R., Soluble Phosphorus Removal in the
    Activated Sludge Process. Progress Report  for the Water Quality Office, U. S.  EPA,
    Project No. 17010 EIP, Pennsylvania University, University Park, Pa. (August, 1971).

 52.  U. S. EPA - District of Columbia Pilot Plant, Monthly Reports, June-October  1972,
     Washington, D. C. (1972).

 53.  Goodman, B.C., and  Mikkelson,  K.A., Advanced Wastewater Treatment. Chemical
     Engineering Desk Book Issue, 77, pp. 75-85  (April 27, 1970).

 54.  Zenz, D.R. and Pivnicka, J.R., Effective Phosphorus Removal by the Addition of Alum
     to  the Activated Sludge Process.  Proceedings - 24th Industrial Waste Conference,
     Purdue University, pp. 273-301 (1969).

55. Anderson,  D.T., and Hammer, M.J., Effect of Alum Addition on  Activated Sludge
    Biota. Water & Sewage Works, 120, No. 1, pp. 63-67 (January, 1973).
                                      6-27

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-------
                                    CHAPTER 7

                       EFFLUENT POLISHING TECHNIQUES
7.1  General

The use of effluent polishing techniques is receiving increasing attention as a practical and
economical method of upgrading existing secondary treatment facilities to obtain improved
organic and SS removal. Effluent polishing is particularly applicable where it is necessary to
increase overall efficiency by 10 to 20 percent.

Four effluent polishing processes are considered in this manual:  (1) polishing lagoons, (2)
microscreening, (3) filtration, and (4) activated carbon absorption. The reader is referred to
the Process Design Manual for Suspended Solids Removal  (1) for an in-depth discussion of
microscreening and filtration, and to the Process Design Manual for Carbon Adsorption (2)
for detailed design information on carbon columns.

7.2  Polishing Lagoons

Polishing lagoons offer an opportunity for increased organic and SS removal at a minimum
cost. Both aerobic and facultative lagoons can be used for this purpose.

     7.2.1   Aerobic Lagoons

Aerobic lagoons are generally subdivided into two groups:

     1.  Shallow lagoons, with depths ranging from 2.5 to 4.0 feet.

     2.  Deep lagoons,  7 to  10 feet deep,  with aeration devices  included to ensure
         maintenance of aerobic conditions.

The shallow aerobic lagoon is one in which the algae-bacterial symbiotic interrelationship is
optimized  by  providing  as  much  light  penetration as  possible,  and  by  maximizing
photosynthetic efficiency and bacterial oxidation of organic wastes.  Operational data from
several shallow aerobic lagoons are presented in Table 7-1. The data indicate consistent BOD
removals throughout the year, but a marked  increase in  the concentration of SS in the
effluent during the summer periods, when algal activity is at its peak. The seasonal increase
in residual SS without a concurrent increase in BOD during the summer months is caused by
algae  carry-over into the effluent. This indicates that algae present in the effluent do not
exert a significant amount of  BOD demand  during  the five-day incubation used in the
standard BOD  test.  The substantial increase  in effluent  SS during the summer period,
however, is a major disadvantage of the shallow lagoon  as a dependable year-round polishing
technique.
                                        7-1

-------
                                                  TABLE 7-1
                     OPERATIONAL DATA FROM SHALLOW AEROBIC POLISHING LAGOONS

Plant
Location


Marlborough,
Mass.


Indian Creek,
Kansas








Sedalia,
Missouri



Time Detention
Period

1962
Feb. 13-14
June 13-14
Aug. 30-31
1963
June 12-13
July 10-11
Aug. 27-28
Dec. 1-2

1964
Jan. 28-29
March 6-7
April 10-11

Year of 1969

Time
days

—
-
-

2.2
2.7
2.4
3.4


3.9
3.0
1.8

-

Flow
mgd

1.4
1.1
0.9

2.3
1.9
2.1
1.5


1.3
1.7
2.8

1.8



BOD
In
Out
mg/1

45
36
26

19
11
11
30


38
27
36

24


15
29
24

10
9
5
15


16
15
11

11

Lagoon
BOD
Removal
percent

67
19
8

50
20
58
50


59
44
69

54


Surface Organic
Loading
Ib BOD/day/acre

47
30
18

61
29
32
61


67
62
135

30



SS
In
Out
mg/1

13
44
39

29
15
11
43


64
20
21

-


9
31
41

52
31
27
17


34
9
5

-

Lagoon
SS
Removal
percent

35
30
-5

-77

-103
-140
61


45
23
77

—
                                                                                              Remarks
                                                                                           Trickling Filter
                                                                                           Effluent
                                                                                           Trickling Filter
                                                                                           Effluent
                                                                                           Pond Size-6.2 acres
                                                                                           Depth - 2.5 ft
                                                                                           Odorous in spring
Reference
                                                                                           Activated Sludge
                                                                                           Effluent
*See Case History, Chapter 13.

-------
 An alternative to the shallow lagoon is the deep, aerated, lagoon. These deeper lagoons can
 operate at greater surface organic loadings than shallow lagoons  and yet maintain higher
 organic removals. Settling of the lagoon effluent is normally necessary to provide efficient
 SS capture. This can be provided by a quiescent  zone at the end of the lagoon, or by a
 separate clarifies Since oxygen is supplied to the basin by mechanical devices rather than
 furnished by the algae-bacterial biosymbiotic  relationship, the algae production in the
 aerated lagoon is minimal compared to the shallow lagoon. Operational data for aerated
 effluent polishing lagoons (5 to  10 feet deep) are presented in Table 7-2.
                                    TABLE 7-2
                  REMOVAL EFFICIENCIES FOR DEEP AERATED
                         EFFLUENT POLISHING LAGOONS

                                  Surface
                                  Organic           BOD        SS
        Plant Location             Loading          Removal    Removal      Reference
                              Ib BOD/day/acre      percent    percent

Washington Borough, N. J. 1           230              63         78            5
East Windsor Township, N.J. 2         134              75         75            ^
Indian Creek, Kansas3             60 to 178            60         50            4

1 Low-Rate Trickling Filter Plant.
^Contact Stabilization Plant.
3High-Rate Trickling Filter Plant.
 The  lagoon at  the Washington Borough  Plant  has average influent BOD  and  SS
 concentrations  of 43 mg/1 and 70 mg/1, respectively. The  average effluent BOD  and SS
 concentrations  are 16 mg/1 and 15 mg/1, respectively. The East Windsor Plant's polishing
 lagoon  receives  BOD  and  SS  concentrations  as  high  as  80 mg/1,  while  the  effluent
 concentrations are generally about 15 mg/1.

 In  1965, the Indian Creek Plant  capacity was increased to serve a population of 70,000.
 Under these conditions it was estimated that the BOD loading to the shallow aerobic lagoon,
 previously  discussed, would increase  to  450 Ib/day/acre, causing a deterioration of the
 effluent quality shown in Table 7-1. The shallow lagoon was  modified  by raising the berm
 elevation, installing a new effluent structure, deepening the lagoon to 5 feet and providing a
 perforated  hose aeration system. After the above modifications, the lagoon received a flow
 of 4.0 to 7.0 mgd and provided a detention time of 1.4 to 2.4 days. During 1969, effluent
                                       7-3

-------
BOD and SS concentrations averaged 10 rag/1 and 9 mg/1, respectively. The highest monthly
average effluent BOD and  SS concentrations during this time were 17 mg/1 and 14 mg/1,
respectively.

Deep aerated polishing lagoons may be aerated by either mechanical or diffused air systems.
These devices must be designed to provide sufficient oxygen for biological metabolism and
adequate  mixing. Mechanical surface  aerators are commonly used for  this purpose in the
Southern  and temperate climate areas, while diffused  air systems have been successful in
severe climates where icing may prove troublesome for the mechanical devices.

Eckenfelder  (6) has indicated that the  power  levels  required to maintain solids under
suspension  and  to  disperse oxygen  uniformly  throughout the  basin  are  0.02  to
0.03 hp/1,000 gallons and 0.006 - 0.01 hp/1,000 gallons, respectively.

Edde (7)  studied the degree  of mixing  provided by mechanical aerators used in treating
wastewater from pulp mills. His study indicates that a velocity greater than 0.4 fps should
be maintained in the basin  to prevent solids deposition, and that mixing energy input varies
with the  size of the  aeration unit. The following values were given as sufficient  mixing
energy to  disperse oxygen uniformly throughout the basin (7):
                                    TABLE 7-3
                 MECHANICAL MIXING ENERGY REQUIRED FOR
                              OXYGEN DISPERSION

                Size of Aerators                         Mixing Energy
                      hp                                hp/1,000 gal

                     100                                   0.014
                      50                                   0.018
                      20                                   0.021
The  above discussions indicate  that mechanical aerators can be designed to provide either
complete  mixing of solids  including  oxygen  dispersion,  or  just  to  provide  uniformly
dispersed oxygen. In the latter case, solids deposition will occur in the basin.

     7.2.2   Facultative  Lagoons

Facultative  lagoons  are  characterized  by  two  distinct  zones -  aerobic  and  anaerobic.
Hydraulic and organic loadings are such that the DO in the lower section of the lagoon is
depleted but an aerobic layer is maintained near the surface. A cross section of a typical
facultative lagoon is shown on Figure 7-1.

                                        7-4

-------
                                           FIGURE 7-1
                         TYPICAL CROSS SECTION OF A FACULTATIVE  LAGOON
71
on
                                        2-3  FT AEROBIC ZONE
                                          TRANSITION ZONE
                                        ANAEROBIC ZONE >3  FT

-------
At Peoria, Illinois,  Fall (8) investigated the efficiency of a 10-foot deep polishing lagoon
operated for 9-month periods each as a facultative lagoon and as an aerated lagoon. The
results of his work  are summarized in Table 7-4. It is interesting to note that both the BOD
and the SS concentrations in the  effluent did not change  appreciably  during the period
when the lagoon was operated aerobically as compared to the facultative operation. Fall also
has stated that during the two winters of operation there  was no  ice on the pond. The
lowest temperature of the pond effluent was 48 deg F, and this was recorded after five days
during which air temperatures were below zero degrees F. Facultative operation of  the
lagoon produced small amounts of algae in the pond during the summer period, but no odor
problems were noted during the operation of this lagoon.
                                   TABLE 7-4
        COMPARISON OF OPERATIONAL DATA FROM FACULTATIVE AND
                        AERATED POLISHING LAGOONS


Description
Type of Secondary Plant

Flow, mgd
Lagoon Size, acres
Average Pond Depth, feet
Influent BOD, mg/1
Effluent BOD, mg/1
BOD Removal, percent
Influent SS, mg/1
Effluent SS, mg/1
SS Removal, percent
Detention Time, days
Organic Surface Loading,
Ib BOD/day/acre
Air Applied, cu ft air/lb
BOD applied
Odor
Minimum Temperature of
Lagoon During Study, deg F
Sources: Peoria - Fall (8)
Decatur - Reynolds


Aerated
Peoria,
Illinois
Facultative
Activated Activated
Sludge
0.66
0.45
10
58
34
41
55
17
67
1.8

710

223
None

48

(9)
Sludge
0.65
0.45
10
62
30
52
55
18
67
1.82

747

0
None

48


Springfield - Hickman (10)
                                                           Decatur,     Springfield,
                                                           Illinois       Missouri
                                                          Facultative    Facultative
                                                          Trickling
                                                            Filter
                                                              6.8
                                                              8.4
                                                              5.5
                                                             30
                                                             18
                                                             40
                                                             61
                                                             31
                                                             49
                                                              2.3

                                                            218

                                                              0
                                                             None

                                                             52
Activated
 Sludge

    18.7
    10
    12
    83
    30
    64
    69
    26
    62
     1.61

 1,292

     0
                                       7-6

-------
Operational data from the facultative effluent polishing lagoon in Decatur,  Illinois, also
shown in Table 7-4, indicate that BOD and SS removals averaged 40 percent and 49 percent,
respectively, while operating under an organic surface loading of 218 Ib BOD/day/acre (9).
As seen in Table 7-4, the facultative lagoon at Springfield, Missouri, receives  much higher
surface BOD loadings (approximately 1,290 Ib BOD/day/acre) and  still performs creditably,
with average BOD and SS removals of 64 and 62 percent, respectively (10).

A major disadvantage of facultative lagoons is the fact that the effluent will have a minimal
DO content.  Springfield,  Missouri, solved this problem  by  using cascade aeration. The
effluent from  the polishing lagoon flows  over a series of five weirs with a total drop of
75 inches. The average DO  in the effluent (September  1970 through  March 1971) was
7.0 mg/1 with a minimum and maximum, respectively, of 4.0 and 9.9 mg/1 (10).

7.3  Microscreening

     7.3.1  Principles of Operation

The microscreen is a surface filtration device that has found increasing utility  for polishing
secondary effluents. It consists of a  specially woven polyester  or stainless-steel screen
mounted on the  periphery of a partially  submerged, horizontal revolving drum. Influent
wastewater enters the drum internally and passes radially outward  through the screen, with
deposition of solids on the inner surface of the drum screen. A typical microscreen unit is
shown on Figure 7-2.

Microscreens are  continuously backwashed by water jets located  at  the top of the drum.
These jets normally operate at a pressure of 15 to 50 psig. The backwash water is returned
to the head of the plant, and usually totals 4 to 6 percent of the microscreen throughput.

The screens employed have extremely small  openings and are available in a variety of sizes,
as shown in Table 7-5.

                                    TABLE 7-5
                          MICROSCREEN FABRIC SIZES

                                                       Number of
                Opening                                 Openings
                   y                                    per sq in.

                  15
                  23                                     165,000
                  35                                      80,000
                  60                                      60,000
                                        7-7

-------
                  8-Z
I(Nn

-------
 Typical microscreen drum sizes,  capacities, power and space requirements are shown in
 Table 7-6.
                                    TABLE 7-6
           TYPICAL MICROSCREEN POWER AND SPACE REQUIREMENTS
                         Approximate
                          Floor Space
Diameter   Length     Width    Length
Drum Sizes
   ft
          ft
ft
ft
5.0
5.0
7.5
10.0
1.0
3.0
5.0
10.0
8
9
11
14
6
14
16
22
0.50
0.75
2.00
5.00
Motors
Drive
BHP
0.50
0.75
2.00
5.00
Wash Pump
BHP
1.0
3.0
5.0
7.5
Approximate
 Ranges of
  Capacity
    mgd
 0.07 - 0.15
 0.2  -0.4
 0.5  - 1.0
 1.5  -3.0
                              Courtesy Crane Company
4.0
6.0
10.0
4.0
6.0
10.0
7
10
14
15
17
22
0.75
2.00
5.00
                                                         1.0
                                                         1.5
                                                         5.0
                                                               0.2  -0.4
                                                               0.5  - 1.0
                                                               1.5  -3.0
                              Courtesy Zurn Industries
 The weave and shape of individual fabric wires are such that they allow the water from the
 backwashing jets to penetrate the screen and remove the solids mat which forms on the
 inside of the screen during its passage through the feed stream.  Bodien and Stenburg (11)
 have noted that only about one-half of the applied washwater actually penetrates the screen;
 the rest flows down the  outer perimeter into the effluent chamber. Previously screened
 effluent can be used as washwater.

 As a section of the screen passes through its cycle, the resistance to flow increases as the
 solid mat forms.  Standard  design calls for a three-inch  head loss at  average flow and a
 six-inch head  loss for maximum flows.  Newer microscreen models are available with
 automatic controls to increase drum speed and backwash pressure to accommodate variation
 in flow and, to a lesser extent, variation in solids loading. Ultraviolet light placed in close
 proximity to the screen has been somewhat successful in slowing the development of screen
 clogging slimes. In general, however, the units must be taken out of service on a regular basis
 (once a month, for  example) to have the screens cleaned. In  addition, cleaning may be
 required for  removal  of iron, manganese, or grease. In cases where oil and grease problems
 occur,  a hot water or steam treatment can be used to remove these materials from the
 screen.
                                        7-9

-------
One of the advantages of using a microscreen for upgrading the performance of existing
plants  is  its low  head requirement. It is  therefore advantageous to transfer  secondary
effluent without pumping, to a tertiary microscreening installation to minimize the shear
force imparted to  the relatively fragile biological floe. Careful design of inlet structures and
outlet  structures will eliminate turbulent areas and hold the head loss through the entire
installation to 12 to 18 inches (12). Typical designs include overflow weirs to bypass part of
the flow when the head loss through the screen exceeds a predetermined amount, usually six
to eight inches.

     7.3.2  Functional Design

Functional design of a microscreen unit involves:

     1.   Characterization of SS in feed as to concentration and degree of flocculation. The
          character  of  the  solids  affects  microscreen  capacity,  performance   and
          backwashing requirements.

     2.   Selection of unit design parameter values which will:   a) assure capacity to  meet
          maximum hydraulic loadings with critical solids characteristics, b) provide desired
          performance  over  the  expected range  of  hydraulic  loadings  and solids
          characteristics.

     3.   Provision of backwash  and supplemental cleaning facilities to maintain capacity.

Table  7-7 shows  typical  microscreen and  backwash design parameter values for tertiary
solids removal applications.

     7.3.3  Performance

Suitable relationships have not been developed for quantitative predictions of microscreen
performance from knowledge of influent characteristics and key design parameters.

Where  performance must be predicted closely, pilot studies should be made. Where  close
prediction is less  critical, performance data from  other locations with generally similar
conditions may serve as a guide.

Microscreening has been used for the removal of algae from lagoon  effluents. At Bristol,
England,  algae reductions of 1,565 to 450 algae per ml and 989 to 168 algae per ml  were
achieved on astrerionella, cyclotella and synedra (1).

Many  classes of algae  (e.g., chlorella) are, however, too small to be removed, even  on fine
screens (23 M )and excessive loadings (up to 2 x  10^ algae per ml) make this application a
limited one.

                                          7-10

-------
                                  TABLE 7-7
                 TYPICAL MICROSCREEN DESIGN PARAMETERS
         Item

Screen Mesh

Submergence


Hydraulic Loading
Head Loss (H.L.)
 through Screen
Peripheral Drum Speed
Diameter of Drum
Backwash Flow and
 Pressure
    Typical Value

      20-25 u

     75% of height
     66% of area

5-10 gpm/sq ft of sub-
merged drum surface
area

       3-6 in.
15 fpm at 3 in. H.L.
125-150 fpm at 6 in.
H.L.

        10ft
2% of throughput at
50 psi
5% of throughput at
15 psi
             Remarks
         Range 15-60
Maximum under extreme condition:
12-18 in. Typical designs provide for
overflow weirs to bypass part of flow
when head exceeds 6-8 in.

Speed varied to control H.L. Extreme
maximum speed 150 fpm
Use of smaller diameters increases
backwash requirements
                                     7-11

-------
Table 7-8 provides performance data for a number of microscreen applications for tertiary
solids removal. Reported data indicate the following:

     1.    Even under best  operation, 5  to  10 mg/1 residual SS will  pass  through the
          microscreen unit.

     2.    Although  the  pattern is irregular,  performance tends to  be better at lower
          hydraulic loadings.

     3.    Increases in influent  SS are reflected in the effluent but with noticeable damping
          of peaks.

     4.    Better removals are obtained with smaller mesh size.

7.4  Filtration

     7.4.1  General

Filtration of secondary effluent provides  a positive method of SS control,  and as such, is
one  of  the more widely used and  the most efficient single unit process for upgrading
treatment plant performance today. The primary  applications of filtration are:  (1) direct
filtration of secondary effluent, (2) filtration of chemically clarified secondary effluent, and
(3) filtration of secondary effluent after in-line chemical injection. Direct filtration has the
highest  probability of use where existing plants will be required to consistently meet better
effluent quality standards than  they are presently able to attain.

The major goals of filtration design are:

     1.    Attainment of required effluent quality

     2.    Low capital cost

     3.    Low operating cost.

Present filtration technology provides the designer with a broad selection of filter types and
sizes, all of which have been  shown capable of producing high quality effluents. For any
particular application, adequate consideration must be given to matching filter design and
capability  to the existing site  conditions and wastewater characteristics. Such  factors  as
present and projected plant flows, variability and concentration of filter influent SS, plant
hydraulics, and present and projected operation schedules all affect filter selection (13).
                                         7-12

-------
                                TABLE 7-8
                 MICROSCREEN PERFORMANCE DATA (1)


Location

Harpenden, England
Luton, England
Brackncl], England

G. L. C Rcdbridgc, England
Hamblrdon R.D.C.
Elmbridgc, England
Leighton-Lmslade U.D.C.
England
Fleet U.D.C., England
Eshcr U.D.C. , England
Hatfield R.D.C.. England

The Borough of Bury
St. Edmonds, England
Essex R.B. Works, England
Franklin Township
STP Murraysville, Pa.
Letchworth, England

Bahinstokc, England

Euclid, Ohio



Euthd, Ohio


Euclid, Ohio

Lebanon, Ohio

Hanover Park, III.

MSD North Side STP
Chicago, 111.
Miami, Fla.
Murfreesboro, Tenn.
Essex Junction, Vermont
Source of Micro-
screener Influent
Stream

Trickling Filters
Humus-Tank *
Humus-Tank

Humus-Tank
Humus Tank

Humus-Tank

Humus-Tank
Humus-Tank
Humus-Tank

Humus-Tank

Humus-Tank
Trickling Filters
Final Clanficrs
Activated Sludge
Final Clarifiers
Activated Sludge
Final Clarifiers
Activated Sludge
with Chem Precip.
in Primary Clarif.
(FeCl)
Activated Sludge with
Chem. Precip. in Final
Clarif. (FeCl)
Pure Oxygen-Activated
Sludge Final Clanficrs
Activated Sludge
Final Canf.
Attivaled Sludge
Final Clarif.
Activated Sludge
Final Clarif.
	
	
	
Drum
Diameter
Width
ft
5x3
-
7.5x5

-
-
-
-

10x10
lOx 10
7.5 x 5

lOx 10

-
lOx 10

5x3

lOx 10

2.5x2



2.5 x 2


2.5x2

Sx 1
5x 1
lOx 10

12.5x30

lOx 10
lOx 10
4x4
Screen
Mesh
V
'65
60
35

23
23
35
35

35
-
-

23

-
23

23

23

23



23


23

35
23
23

23

20
20
35
Hydraulic
Load on
Submerged
No. of Area
Units Max.
gpm
1 6.6
9.0
2 6.3

9.4
10.8
10.8
68

2 6.0
3
3

5

9.8
2 7.8

1 4.3

5 1.5

1 2.5



1 2.5


1 2.5

1
1
Avg.
/sqft
Plant Flow
Max.
mgi
Avg-
il
Pilot Study
-
2.2

6.8
2.5
2.5
3.9

2.0
-
-

-

6.8
-

3.3

1.0

1.25



1.25


1 25

-
-
1 5 3 2.6

-

1
2
1

-

-
_
-
3
6.3

2.7
2.5
25
2.0

3.6
10.82
2.552
9.02
5.3

2.8
4.0

-
2.2

2.0
0.6
0.6
1.2

1.2



-

2.0
-

Pilot Study

3.2

40
gpm


40
gpm

40
gpm
-

1 5

152

2.7
4.0
0.25

2.2

20
gpm


20
gpm

20
gpm
1.0

08



-
-
-
Influent
mg/1
40
14
20
16
30
14
14
29

15
19

14
28

26
37

17

13

54



38


65

27
17
6-28

10

-
_
-
Average SS
Effluent
mg/1
11
8
11
7
15
8
8
11

6
9

8
7

14
6

6.6

4

8



10


21

7
2
4-11

3

-
_
-
Removal
percent
73
45
45
57
50
45
45
60

60
60

43
75

44
83

62

70

85



74


68

73
83
55 (avg.)

67

71
50
50
Manufacturer

Crane
Crane
Crane

Crane
Crane

Crane

Crane
Crane

Crane
Crane

Crane
Crane

Crane

Crane

Crane



Crane


Crane

Crane'

Crane

Crane

Zurn
Zurn
Zurn
I. Trickling Filters Final Clanfier.
2 Design Flow.
                                    7-13

-------
Low capital costs will generally result from low filter surface areas, and high filtration rates.
Operating costs are reduced  by  designs  that  minimize backwashing requirements and
maximize filter run lengths. In wastewater filtration, run lengths are terminated by either
excessive head loss or by deterioration of effluent  quality beyond allowable limits. The
optimum bed  design is one that reaches these limiting conditions at the same time. In some
cases, especially in small plants, it  may be  desirable to design the filter beds so that routine
backwashing can be performed once a day.

     7.4.2   Filter Types

Filtration systems can be broadly  classified as either in-depth or surface. In-depth systems
include deep-bed single  coarse medium filters as well as dual- or tri-media filters. The use of
two or more layers  of different media having increasing specific gravity in the direction of
flow allows gradation of the filter bed from coarse to fine.  This allows more efficient
utilization  of  the   total bed  depth  for solids  storage  than  conventionally  graded,
single-medium filters. Multimedia  beds normally require more backwash water and higher
backwash rates (25-30 gpm/sq ft) than  single-medium beds (13). Typical multimedia
gradations are shown in Table 7-9. The use of several  media such as garnet, sand and coal
will allow some flexibility in  bed design to  meet specific effluent quality  or desired run
lengths.


                                     TABLE 7-9
                      TYPICAL MULTIMEDIA GRADATIONS (1)

                        Garnet                 Sand               	Coal	
Gradation           Size     Depth      Size        Depth         Size        Depth
   No.             (Mesh)   (Inches)    (Mesh)      (Inches)       (Mesh)      (Inches)

     1              -40x80    8         -20x40       12          -10x20       22
     2              -20 x 40    3         -10 x 20       12          -10 x 16       15
     3              -40x80    3         -20x40        9          -10x20        8
The approach taken in the development of surface filters is to allow filtration to take place
on or near the top of relatively shallow (12 in.) single medium filters, and to optimize
removal of the accumulated solids.  In addition to the standard pressure and gravity surface
filters, several innovative techniques for maintaining a continuous clean filter surface have
been developed. These  include moving bed filters, radial flow filters, radial-flow external
wash filters, and traveling-bed filters.
                                         7-14

-------
Although  both upflow and  downflow modes  of filter operation are in use, the downflow
filter is far more common for wastewater applications.

As a rule, in-depth filters are better suited to treating strong biological floe, will yield longer
run lengths, and are less sensitive to solids loading than are surface filters. Surface filters are
better adapted to removing more fragile floes, yield  shorter run lengths, and require less
backwash water per cycle than in-depth filters.

     7.4.3   General Design Considerations

          7.4.3.1   Filter Selection and Governing Factors

Performance of different filter systems on a given wastewater may be termed "equivalent" if
they produce the same output quality and quantity (1). The  major factors that determine
overall filter performance are summarized in Table 7-10.

                                     TABLE 7-10
                  FACTORS GOVERNING FILTER  PERFORMANCE

     1.    Maximum Available Head Loss

     2.    Filtration Rate

     3.    Influent Characteristics

          a.    SS concentration
          b.    Particle size distribution
          c.    Floe strength
          d.    Temperature (viscosity)
          e.    Properties governing adhesion of solids to each  other or to media

     4.    Media Characteristics

          a.    Grain size
          b.    Porosity
          c.    Depth
          d.    Specific gravity
          e.    Configuration

     5.    Design of Cleaning System

          a.    Adequacy of cleaning
          b.    Washwater volume per cleaning cycle

                                        7-15

-------
In general, variations in these factors which increase quality, such as use of finer media, tend
to increase head loss and hence reduce output whereas those which increase output tend to
reduce  quality.  Run length may  be  limited  by  available  head  or effluent quality
(breakthrough). Washwater requirements depend chiefly on  the size  gradation, specific
gravity of the media, and on the type of supplementary cleaning available.

Another factor that must be examined when selecting a filter for a given wastewater is the
effect of chemical  pretreatment. Typical situations include activated sludge and trickling
filter plants that incorporate  alum or iron addition  followed  by filtration for high level
phosphorus  removal. In these  cases the filter performance may be quite different than for
untreated effluents due to the weaker  chemical floe normally produced. Generally it is
desirable to  provide for the addition of polyelectrolytes in installations where aluminum or
iron salts are employed for phosphorus removal.

Since influent solids characteristics are variable, the operating head provided in design must
cover a range of conditions. If breakthrough consistently requires termination of filter runs
at a low head loss, much of the available head will be wasted. On the other hand, if available
head is so low that head  loss instead of quality limits the run length, filter  production
capacity will be impaired unnecessarily.

Based on long term practice  in water filtration, maximum terminal head loss of 10 to
15 feet  has  commonly been allowed. In water filtration, this head loss  range generally
permits runs of 24 or even 48  hours. In wastewater applications, however, heavy solids
loadings and high biological floe strength can cause rapid  head loss buildup, frequently
reaching limiting  values well below 24 hours. Filter design should allow sufficient head so
that, with maximum influent solids concentrations and floe strengths, minimum run lengths
of six hours can be achieved. Also the effect of backwash recycle flows and  filter downtime
must be considered  when sizing units.

Proper  cleaning is vital to  filter performance. Ineffective cleaning results directly in short
filter runs and  poor effluent quality and if continued, sets up self-perpetuating operational
difficulties such as mud balls,  slime coating of the media and cracking of the filter bed (14).
In wastewater filtration, normal upflow washing plus  auxiliary cleaning (air wash or surface
wash by  water jets)  and periodic shock chlorination have proven necessary  to maintain
filters in proper condition. During a normal backwashing operation, accumulated solids are
removed from  filters by a rapid upflow of washwater  which is  returned  to the previous
treatment units. In small plants, equalization of this flow is necessary to prevent surcharge
of upstream treatment units.  Washwater sources  may include feedwater, filter effluent, or
effluent from  subsequent  treatment units. Washwater storage may be  needed if  rates
required exceed effluent flow available. Backwash  rates for most effective cleaning vary with
media size, particle density, floe penetration, and strength of floe adherence to the media.
                                         7-16

-------
In  most  applications  a  number of  specific  filter  designs  can  provide the  required
performance. For  a  given treatment application, if costs  and performance variations of
alternatives can be defined quantitatively, it is possible to base selection on "least cost."
Cost comparisons should include both installed cost and operating cost items such as control
required, operating head loss, and backwash water consumption.

          7.4.3.2  Pilot Plant Investigations

The extent of pilot investigations which should be conducted as a basis for a given design
depends on  the size of the  proposed  installation and on  the  performance requirements
which must be met. For large installations the cost of the necessary pilot plant investigations
for optimizing filter design is certainly justified in view of the potential cost savings. When
undertaken,  these studies should be sufficiently well planned to relate filter performance to
the full range of variables  expected under actual operating conditions. Figure 7-3 illustrates
the type of information that should be  developed as a part  of an overall pilot investigation
to optimize  filter design.  This figure represents the results of pilot plant studies including
only those runs that produced effluents of satisfactory quality. From such data a rational
design can be formulated.

Where quality requirements are less  stringent, or for very small plants  where extensive
efforts at cost optimization are not justified, filter design parameters may be selected based
upon evaluations of similar installations.

     7.4.4   Performance

The single most important factor affecting filter performance is the quality of the secondary
effluent produced by the biological treatment. If consistently good performance is exhibited
by the biological treatment system, good filter performance  can be expected. Conversely, if
the biological facility is subject to frequent upsets, filtration will be much more difficult.

Data are presented in Tables 7-11 and 7-12 relating expected filter performance with degree
of treatment in activated sludge  and trickling filter plants. The data in  the tables are based
on  a  filter rate of 5 gpm/sq ft, using a 30-inch deep multimedia filter (55 percent coal,
30 percent sand, and 15 percent garnet) operated to a 10-foot head differential.

Pilot and  full-scale performance  data for in-depth filters operating on activated  sludge and
trickling filter plant effluents are shown in Table 7-13. Performance data for surface filters
are shown in Table 7-14.  As indicated  in these tables,  both in-depth and  surface filters
produce an effluent with BOD and SS concentrations generally less than 7 mg/1.

Data describing filter performance at various plants treating chemically treated secondary
effluent are shown in  Table 7-15.
                                          7-17

-------
   60
                          FIGURE 7-3
         TYPICAL PILOT PLANT DATA FOR FILTER DESIGN (13)
                                      I           r
   50
oo
CO
   40
   30
2  20
                                      2  GPM/SQ FT
                 6 GPM/SQ FT
                I
I	L
                10          20          30          40

                   INFLUENT SOLIDS  CONCENTRATION,  MG/L
                     50
                              7-18

-------
                              TABLE 7-11
                  EXPECTED FILTER PERFORMANCE FOR
                    ACTIVATED SLUDGE PLANTS (15)

                                  Good Biological Treatment
Type of Activated
Sludge Process

Conventional and
Extended Aeration
Contact Stabilization
Type of Activated
Sludge Process

Conventional and
Extended Aeration
Contact Stabilization

Filter Influent Filter Effluent
BOD SS BOD SS
mg/1 mg/1 mg/1 mg/1
12-15 15-25 2-5 1-4

15-20 15-25 5-10 1-5
Fair Biological Treatment
Filter Influent Filter Effluent
BOD SS BOD SS
mg/1 mg/l mg/l mg/l
20-35 30-50 5-10 5-10

30-45 25-50 20-25 5-10
TABLE 7-12
Run Time
hr
16-24

12-20

Run Time
hr
6-12

6-10

EXPECTED FILTER PERFORMANCE FOR

Percent
85 Percent
Filter Filter
Influent Effluent
BOD SS BOD SS
me/1 mg/1 mg/1 mg/1
TRICKLING FILTER PLANTS (15)
Soluble BOD Removed in Secondary Process
80 Percent
Filter Filter
Influent Effluent
RunTime BOD SS BOD SS
hr mg/1 mg/1 mg/1 mg/1




Run Time
hr
30-40  30-40  20-30  15-20
6-11
40-50  35-45  30-40  20-25
5-9
                                  7-19

-------
              TABLE 7-13
IN-DEPTH FILTRATION OF ACTIVATED SLUDGE
 AND TRICKLING FILTER PLANT EFFLUENTS

Location

Goldwater, Michigan


Bedford Twp., Michigan

Walled Lake-Novi,
Michigan
Pontiac, Michigan
State College, Pa.
(Spring Creek)
Louisville, Kentucky
(Hite Creek)
Ann Arbor, Michigan

Philomath, Oregon



Ventura, California

Hanover Park, Illinois









Note. () indicated range
Influent
Source

Trickling
Filter

Activated
Sludge
Activated
Sludge
-
Activated
Sludge
Activated
Sludge
Activated
Sludge
Extended
Aeration +
Tube
Settler
Trickling
Filter
Activated
Sludge
Activated
Sludge
Activated
Sludge
Activated
Sludge
Activated
Sludge
of values.

Type of Filter

Horizontal
Pressure

Horizontal
Pressure
Gravity
Downflow
-
-

Pressure

-

Pressure
Downflow


Gravity Deep
Bed Downflow
Pressure
Dpflow
Pressure
llpflow
Pressure
Upflow
-

-


Hydraulic
Media Loading
gpm/sq ft
Coal-(18 in )
Sand-(12 in.)
Garnet
Multimedia —

Multimedia 3 to 4

Multimedia —
-

Multimedia 3.4

Multimedia 6

Multimedia 5



1.2mm 6
Sand
Multimedia 2.2

Multimedia 4.0

Multimedia 4.9

Multimedia 2.0

Multimedia 4.0


Filter Influent
BOD
mg/1
(32-56)
44

(15-20)
-

-
9
12

(3-19)
17
(11-50)
22
(7-36)
26



23
17

24

20

23

13


SS
mg/1
(13-29)
21

(10-25)
15
(5-10)
7
19
12

(11-32)
27
(28-126)
42
(30-2180)
165


(19-21)
18
14

15

13

14

16


Filter Effluent
BOD
mg/1
(16-42)
30

(4-10)
7

-
2
3


2
(3-8)
5
(1-4)
3



18
6

6

7

6

2


SS
mg/1
(4-12)
8

(2-5)
3
(1-4)
3
2
4

(1-4)
3
(1-17)
5
(1-20)
5



7
7

5

6

4

4


Length of
Filter Runs Reference
hr

2.5 to 8 16


15 16

16
17
12 18


19

17

15-24 20



6-18 21
22

, 22

22

22

22


                7-20

-------
                                                         TABLE 7-14
                                         SURFACE FILTRATION OF ACTIVATED SLUDGE
                                          AND TRICKLING FILTER PLANT EFFLUENTS
10
   Influent Source

Activated Sludge


Activated Sludge


Activated Sludge


Activated Sludge
Activated Sludge
Activated Sludge
Contact Stabilization
Trickling Filter
Filter
Type of Filter

Gravity Downflow

Gravity Downflow

Gravity Downflow

Gravity Downflow
Gravity Downflow
Gravity Downflow
Gravity Downflow
Gravity Downflow
Media

Coal - 30 in.
Sand - 12 in.
Garnet - 6 in.
Coal - 30 in.
Sand - 12 in.
Garnet - 6 in.
Coal - 30 in.
Sand - 12 in.
Garnet - 6 in.
—
—
—
—
—
Hydraulic
Loading
gpm/sq ft
2.2

4.0

8.0

1.6-4.0
2.0
2.0-6.0
5.3
0.75
Influent
BOD
mg/1
20

25

19

—
—
—
18
47
SS
mg/1
16

15

12

—
—
—
14
36
Filter
Effluent
BOD
mg/1
7

7

7

52-70%*
57%'
80% l
4
17
SS
mg/1
7

5

6

72-91%'
46% i
70% 1
5
10
Reference

' 22

22

22

23
24
25
26
16
            Removal Efficiencies.

-------
                                                             TABLE 7-15
                          FILTRATION OF CHEMICALLY TREATED SECONDARY EFFLUENT
                                    Type of    Plant
     Location         Influent Source    Filter    Capacit\
Piscataway, Maryland   Activated Sludge + Pressure     5 mgd   Dual
                    2-Stage Lime Clari- Downflow
                    fication
Ely, Minnesota        High Hate Trick-   Gravity    1.5 mgd  Dual
                    ling Filter +      Downflow
                    2-Stage Lime Clari-
                    fieation
Hydraulic
Loading
gpm/sq ft
3
2.3
3
Length
of
Filter
Run BOD
In mg/l
50
24
2.5-6.5 (30-130)
75
Filter Influent
COD TOC
mg/l mg/l
9
	 i -j
Filter Effluent
SS
mg/l
12
8
(20-70)
40
BOD COD TOC
mg/l mg/l mg/l
19 8
6-15
(18-110) -
46
SS
mg/l
8
<2
(5-35)
21
Reference
27
28
29
Jefferson Parish,       Trickling Filter    Upflow    0.5 mgd Sand
 Louisiana            and In-Line Alum
                    Injection
Lebanon, Ohio         Activated Sludge   Pressure    50 gpm  Dual     5      2.5-4     -       -   (10-30)   (20-35)    -     -    (5-15) <1        30
                    with In-Line Alum Downflow
                    and Polyelectro-
                    lyte Injection
Pomona, California     Activated Sludge   Gravity    30 gpm  Dual     3        24              81            10            21     -     5       31
                    with Tertiary     Downflow
                    Alum and Poly-
                    flcctrol)tc
                    Clarification

Note  ( ) indicates range of values.

-------
While it is recognized that filtration efficiency varies depending on the type of filter, bed
design, characteristics of the  wastewater, and many other factors previously discussed, it is
informative to examine the limits of this variability. An evaluation of filtration data from a
number  of installations indicates that  removal of SS averages approximately 70 percent,
with a range of 50 to 90 percent.

7.5  Activated Carbon Adsorption

The limitations  of conventional  biological  treatment processes in  regard  to reliable
achievement of a high degree of organic removal (particularly of certain compounds which
are refractory to  biodegradation), along with increasingly strict water quality standards,
emphasize the need for a supplementary organic removal process. Thus, activated  carbon is
presently  being  used  to  provide  tertiary  treatment  of biologically treated effluents.
Experience gained  from the  operation of activated  carbon plants for tertiary treatment of
wastewater suggests that activated carbon need not be restricted to a polishing role, but can
be used  as an alternative to biological treatment.  Replacement  of conventional biological
treatment  by activated carbon (i.e. secondary treatment application) is emphasized in the
Process Design Manual for Carbon Adsorption (2). The following discussion is concerned
exclusively with the tertiary application of carbon.

Activated carbon for wastewater  treatment  can  be used either in the  powdered  or in the
granular forms.  The  impracticality of economical regeneration has restricted the use  of
powdered carbon in wastewater treatment, although this problem  is being resolved.

     7.5.1  Process Principles and Design Factors

The adsorption of organic materials from wastewater onto the  activated carbon involves
complex physical  and chemical interactions. Biological  degradation of adsorbed  materials
also occurs, and this can significantly enhance  the overall treatment performance (32) (33).

The ability of activated carbon  to adsorb large  quantities of dissolved  materials from
wastewater is due to its highly porous structure and to the resulting large surface area, which
provides many sites for adsorption of dissolved materials.

Important  factors   in  the   design   of  activated   carbon  treatment  facilities
include:  pretreatment  requirements; particle  size; hydraulic  loading  and contact time;
regeneration losses; flow configuration; and required effluent quality.

          7.5.1.1   Pretreatment Requirements

Granular carbon can be used as a  direct polishing technique for secondary effluents or may
be preceded by a SS removal process or other treatment processes as required to accomplish
treatment objectives.  Long term studies at Pomona, California, have indicated that carbon

                                        7-23

-------
can function as an effective filter in addition to removing  dissolved organic matter (34).
However, it is important that the secondary treatment plant clarification system produce a
reasonably high quality effluent (<20 mg/1  SS),  since the use of carbon as a media to
remove large quantities of suspended material is not a cost-effective treatment technique.

          7.5.1.2   Particle Size

Theoretically, carbon particle size primarily  affects the rate of adsorption and  not  the
capacity  of the carbon. Adsorption rates are greater for smaller particle sizes than for larger
particle sizes.  However, adsorbents close to saturation will be less affected by particle size
than adsorbents in their virgin state (32).

Data from Lake Tahoe  indicates that there will be a reduction in the adsorption capacity of
about 20 to 35 percent in going from 12 by 40 mesh carbon to 8 by 30 mesh carbon at a
relatively short contact  time (32).  This apparent  difference  in  adsorption  capacity
attributable to particle  size is minimized at longer contact times (35). Since finer particle
sizes are susceptible to  greater head  losses, 12 by 40 mesh carbon is probably not  suitable
for use in downflow columns (35).

          7.5.1.3   Hydraulic Loading Rate and Contact Time

Contact time, hydraulic loadings, and bed depth are interrelated physical parameters. Of the
three, contact time is clearly the most important. Since the  activated carbon treatment of
wastewater requires that a definite contact time be established to complete the adsorption
process,  any increase in  applied hydraulic load necessitates a deeper  carbon  column to
maintain the same  contact time.

Data  obtained at  the Pomona, California  Pilot Plant  indicate that Total Organic Carbon
(TOG) removal  does .not vary significantly  after  15  minutes contact time for hydraulic
loading rates of 4, 7, and 10 gpm/sq ft (32). It was further noted that for equivalent contact
times, the percent TOG  removal was similar for hydraulic  loading rates of 4, 7 and  10
gpm/sq ft. These results indicate that contact time is more important than applied hydraulic
loadings, and is, in fact,  the most important design factor in carbon adsorption systems.

Typical hydraulic  loading rates and contact times used in various  locations are shown in
Table 7-16. It should be noted that both gravity and pressure systems are available. Gravity
flow systems are not likely to be practical at  hydraulic loading rates above about 4 gpm/sq
ft.
                                        7-24

-------
Ol
                                                         TABLE 7-16
                                          TYPICAL CARBON COLUMN DESIGN DATA
                                   Average               No. of                        Total
Effluent

1.

2.
3.
4.

5.

6.
7.
8.
9.

10.

11.
12.

13.

Site

Arlington, Virginia

Colorado Springs, Colorado
Dallas, Texas
Fairfax County, Virginia

Los Angeles, California

Montgomery County, Maryland
Occoquan, Virginia
Orange County, California
Piscataway, Maryland

St. Charles, Missouri

South Lake Tahoc, California
Windhoek, South Africa

Pomona, California

Plant
Capacity
mgd
30

3
100
36

52

60
18
15
5

5.5

7.5
1.0

0.3

Contactor Contactors
Type in Series

Downflow
Gravity
Downflow
Upflow
Packed
Downflow
Gravity
Downflow
Gravity
Upflow
Packed
Upflow
Packed
Upflow
Packed
Downflow
Pressure
Downflow
Gravity
Upflow
Packed
Downflow
Pressure
Downflow
Pressure

1

2
1
1

2

1
1
1
2

1

1
2

4

Contact
Time1
min
38

30
10
36

50

30
30
30
37

30

17
30

40

Hydraulic
Loading
gpm/sq ft
2.9

5
8
3

4

6.5
5.8
5.8
6.5

3.7

6.2
3.8

7

Carbon
Depth
ft
15

20
10
15

26

26
24
24
32

15

14
15

38

Carbon Requirements
Size (Oxygen Demand) Reference
mesh
8x

8x
8x
8x

8x

8x
8x
8x
8x

8x

8x
12 x

12 x

30

30
30
30

30

30
30
30
30

30

30
40

40

mg/1
BOD

BOD
BOD
BOD
BOD

COD

BOD
COD
BOD
COD
COD
BOD



BOD
COD
COD

COD

< 3 2

< 2 2
<10 2
< 5 (by 1980)
< 3 2

<12 2

< 1 2
< 1 2
<30 2
< 5 2



< 5 2
<30
<10 2

<12 34

       *  Empty bed (superficial) contact time for average plant flow.
       2  Ultimate capacity t>0 mgd.

-------
         7.5.1.4   Effect of Regeneration

Activated  carbon  requires regeneration  when  its  adsorption capacity  is  exhausted.
Considerable effort has been expended  to determine  the effect  of regeneration on
adsorption  capacity of the carbon. However, since few research groups have regeneration
facilities, only limited data are available.  Results obtained at Pomona (32) indicate that the
adsorptive capacity decreases by approximately 35 percent after seven regeneration cycles,
as indicated on  Figure 7-4. It  was also determined that regeneration does not affect the
degree of organic removal in subsequent exhaustion cycles. This loss of capacity is not
necessarily  a critical factor, since it is necessary to make up  physical losses of carbon after
each regeneration  cycle.  These losses are caused by several  factors: carbon is burned and
lost through the stack as combustion products; or is abraded into dust in the course of
handling. Further  "losses" are due to the buildup of inorganic ash in the carbon particles
during repeated use and regeneration.

         7.5.1.5   Flow Configuration

Depending   on   the  dissolved  organic  and  SS loading,  any  of several  optional flow
configurations can be adopted:

     1.   Downflow Beds  in  Series  — the lead  contactor  is removed',  regenerated, and
         replaced in line at the downstream end, the other  contactors being moved up in
         sequence.

     2.   Downflow Beds in Parallel — parallel beds are arranged in a staggered exhaustion
         pattern so that when one is exhausted and removed from service, the product of
         the others can be blended with that portion of  flow normally treated by the
         exhausted contractor to maintain the required product quality  for the entire
         plant.

     3.   Upflow Beds (expanded  or  partially expanded) — no head loss is built up, and no
         backwashing is necessary; postfiltration is required; the same series and parallel
         considerations apply as for downflow operation.

     4.   Upflow  (moving bed) — exhausted  lower  strata  of the bed  are continuously
         removed and replaced at the top of the bed by virgin carbon.

Parallel comparison studies between  downflow and upflow beds were  conducted at the
treatment plant of the Ewing-Lawrence Sewerage Authority located near  Trenton,  New
Jersey (36). These studies  have indicated that upflow and downflow beds have equivalent
adsorption  capacities since each  system  removed approximately  the  same  quantity of
soluble  organic material from the plant's secondary effluent (see Table 7-17).  The downflow
bed system  is more effective for removal of SS, but at the expense of an increased head loss,

                                         7-26

-------
                        FIGURE 7-4
      EFFECT OF REACTIVATION  ON  ADSORPTION CAPACITY
CJ




CD
    50
    45  -
CJ




CJ
    35  -i
    30  -
    25
                      2345



                       NUMBER OF REGENERATIONS
6      7
                             7-27

-------
and a corresponding increase in the frequency of backwashing. Accordingly, an upflow bed
system can process more effluent than a downflow bed system of equivalent size because of
less downtime for the carbon-backwash operation. If no allowance is made for backwashing,
an upflow bed  system is capable of processing  about 9 percent more effluent than a
downflow system of equivalent size (36).
                                    TABLE 7-17
                       PERFORMANCE OF UPFLOW BED AND
                        DOWNFLOW BED ADSORBERS (36)

       Description           Filtered Secondary Effluent   Unfiltered Secondary Effluent
                              Downflow    Upflow       Downflow       Upflow

TOG Removed, percent            52.6         48.1           57.0            52.0

Soluble Organic Carbon
  Removal, percent               42.2         44.7           49.6            45.7
Soluble Organic Carbon
  Removed per Ib Active
  Carbon, Ib                       0.19         0.20          0.23            0.22
         7.5.1.6    Performance

In addition to the above design considerations, the question of effluent quality standards
should not be neglected.

The effectiveness of granular activated carbon for upgrading the treatment efficiency is well
established. Full-scaJe operating experiences at Pomona and South Lake Tahoe, California;
Colorado Springs,  Colorado;  and Piscataway,  Maryland,  have left little doubt regarding
process efficiency, operating  cost  and reliability of these  systems. The principal design
parameters for these plants and other tertiary granular carbon plants were previously shown
in Table 7-16,

Performance  data  for  operating tertiary carbon facilities are  shown in Table 7-18. It is
evident from these data that a very high quality effluent can be produced with the  addition
of tertiary carbon treatment.

     7.5.2   Laboratory and/or Pilot Plant Investigations

Activated carbon removes dissolved materials from wastewaters by a combination  of  three
mechanisms:  adsorption, filtration, and biological degradation. Therefore, in order to judge

                                        7-28

-------
KI
IS3
BOD, mg/1
COD, mg/1
TOG, mg/1
SS, mg/1
Turbidity, Jtu
Color (Platinum-Cobalt)
Odor
MB AS, mg/1
                                                    TABLE 7-18
                                        PERFORMANCE OF TERTIARY CARBON
                                         WASTEWATER TREATMENT PLANTS
                              Pilot Plant
                           Pomona, Calif. (34)
                                           Lake Tahoe, Calif. (2)
                 Piscataway, Md. (27)
     Pilot Plant
Orange County, Calif. (2)
Carbon
Influent
3
43
12
9
8
28
12
Effluent
1
10
3
0.6
1
3
1
Secondary
Effluent
30
70

26
15


Carbon »
Influent
3
25

0
0.3


Effluent
0.7
10

0
0.3


Secondary
Effluent

32.9
11.9
15.7



Carbon
Influent

18.6
7.8
7.7



Effluent

6.1
1.5
1.0



Carbon
Influent
30-80
100-200

30-80



Effluent
2
10-30

1



                                               2.0
0.5     0.1
     3-4      0-1

-------
the effectiveness  of activated carbon for wastewater treatment, both laboratory and pilot
testing are required.

The  adsorption mechanism  can be  evaluated  in the  laboratory by  running adsorption
isotherms. Actual plant conditions should be simulated with regard to temperature, pH, and
pretreatment.  A  detailed isotherm procedure  is given in many books, as well as in the
Process Design Manual for Carbon Adsorption (2).

Adsorption isotherms are normally conducted by contacting a sample of wastewater with
varying amounts  of pulverized  carbon for a standard interval  of  time. The wastewater
sample is analyzed for  TOG,  COD, or  BOD (as deemed necessary), both before and after
contacting with the pulverized activated carbon. The treated water should be coarse-filtered
prior to analysis to eliminate carbon fines. The isotherm is  a plot of the amount of solute
adsorbed per unit weight of carbon as  a function of residual concentration of solute. The
isotherm is empirically represented by the following expression (23):

          x/m =  KG1/"

     where:

          x  = weight of solute adsorbed
          m = weight of carbon
          C  = equilibrium concentration of solute  in solution  after  adsorption
          K and  n are constants

The isotherms are normally plotted on a log-log scale. The extrapolation of the isotherm line
to the initial concentration (abscissa)  gives the  theoretical  adsorption capacity  of that
carbon when it is in equilibrium with  the influent concentration.

The  advantage  of isotherms  are: (1) they are relatively simple tests to perform; (2) they
indicate whether  the desired degree of treatment can be readily achieved; and (3) they give
the approximate  adsorptive  capacity of the carbon in a  column  application.  However,
isotherm results should not be used to extrapolate carbon capacities and dosages to full-scale
plant size.

Typical  isotherms  obtained for the same carbon  with different  secondary wastewater
effluents were  reported by Masse (37)  (see Figure  7-5).  The results shown on Figure 7-5
indicate that the  adsorptive capacity of the carbon with respect to COD varies from 0.37 to
0.12 Ib of COD/lb of carbon. This is equivalent to 1.58 to 1.09  Ib of  carbon/1,000 gal of
throughput. The carbon requirements  (per unit volume  of wastewater treated) obtained
from  isotherms  are  conservative (i.e., high),  because removal  by adsorption  alone  is
estimated.
                                          7-30

-------
                                          FIGURE 7-5
71
co
          CJ




          BO
        XIS
              0.0
                             COD ISOTHERMS USING VIRGIN CARBON


                      AND DIFFERENT SECONDARY WASTEWATER EFFLUENTS (37)
                                                                                 (j)C0=0.37
                                     (C) RESIDUAL  COD CONC.,  MG/L

-------
Since isotherms  cannot measure  the quantity of  organics removed by filtration  and
biological action, pilot column testing must be conducted to evaluate the effect of these
factors.   Column  testing  helps  to determine: (1)  the  required  contact time; (2)  the
adsorptive  capacity of the carbon; (3) the pressure drop across the beds and backwash
requirements for  downflow operation; and (4) the shape of the column exhaustion wave
front.

The column used in pilot testing should have a diameter of at least 4 inches. The depth of
column  depends  on the range of contact times being considered, as  does the hydraulic
loading. Normally, two to four columns are used in series, since this arrangement permits
evaluation  of the effect  of  different contact times on  effluent quality. When loading
granular  carbon into the test column (a "wet" packing procedure is recommended), care
must be exercised to avoid entrapping air within the carbon column. Air entrapment  causes
channeling and reduces the contact area, which in turn yields false test results. The Process
Design Manual for Carbon Adsorption (2) describes the conduct of pilot operations in more
detail.

     7.5.3   Costs of Tertiary Carbon Treatment

The  capital cost  of tertiary granular carbon systems will vary widely depending on the
particular  system design  and  pretreatment provided.  Direct  application of  secondary
effluent to downflow carbon adsorption columns as practiced at  Pomona, California, will
result in  a smaller capital investment than a tertiary system using effluent polishing prior to
carbon  treatment.  Total  capital  costs  for  carbon treatment may  be  estimated from
Figure 7-6  for two levels of carbon dosage. For tertiary treatment, the carbon dosage will
generally be in the 200 to 500 Ib/mil gal range.

Operating cost will depend primarily on the organic loading and associated carbon dosage.
Annual costs for power, labor, and maintenance may be estimated from Figure 7-7 which is
based on the experience at Lake Tahoe. Total annual and unit costs may be estimated from
Figure 7-8 for various carbon dosages.
                                        7-32

-------
                       FIGURE 7-6

     TOTAL CAPITAL COSTS  FOR  CARBON TREATMENT (2)
1.000,
  9
  8
  7;
  6
 100
  9
  8
  7
  6

  5
 10
  9
  8
  7

  6

  5
        NOTES

1.   EPA STP  INDEX = 175

2.   COSTS  INCLUDE 100 PERCENT
    EXCESS REGENERATION
    CAPACITY  ABOVE AVERAGE
    ESTIMATED DOSAGE.

3.   COSTS  INCLUDE PUMP STATION,
    CONTACTOR SYSTEM,  REGENERA-
    TION SYSTEM, BUILDINGS,
    ENGINEERING, LEGAL,  INTEREST
    CHARGES.
                                         1200
                                          200
                           CARBON
                           DOSAGE  .
                           LB/MIL  GAL
                    4   5  6 7 8 9 10       2    3

                    DESIGN AVERAGE FLOW,  MGD
                           4   5678 9100
                            7-33

-------
1.000 •
  9
  8
  7
  6
                      FIGURE 7-7

                   CARBON ADSORPTION
          OPERATION AND MAINTENANCE  COSTS (2)
 100
  9
  8
  7
  10
  9
  8
  7
  6
                    YEAR              - 1972
                    LABOR PAYROLL  COST - $5/HR
                    POWER COST        - $.02/kWh
                   456789 10       2    3
                    AVERAGE DESIGN FLOW,  MGD
                                                 5 6 7 8 9 100
                           7-34

-------
                           FIGURE  7-8

TOTAL ANNUAL AND UNIT COSTS  FOR CARBON TREATMENT (2)
10,0
 1,000
   9
   8
   7
 100
   9
   8
   7
   6
  10
                               NOTES
       1,  COSTS INCLUDE OPERATION, 4.
          MAINTENANCE, AND CAPITAL
          AMORTIZATION AT 51/2*
          FOR 25 YEARS.

       2.  EPA STP INDEX = 175.0    R
                                   U
       3.  COSTS INCLUDE 100 PERCENT
          EXCESS REGENERATION
          CAPACITY RELATIVE TO
          ESTIMATED AVERAGE
          DOSAGE.
CAPITAL COSTS  INCLUDE
PUMP STATIONS,  CONTACTORS,
REGENERATION  SYSTEM,
BUILDINGS,  ENGINEERING,
LEGAL.  INTEREST  CHARGES.
O&M COSTS INCLUDE LABOR,
POWER,  FUEL,  MAKEUP
CARBON, MAINTENANCE
MATERIALS.
                                            1200
                                             „„„.  CARBON
                                             800t  DOSAGE
                                             400 (  LBS/MIL GAL
                                             200
                                           1201U
                                            800 /   CARBON
                                            400 /   DOSAGE
                                            2QOJ   LBS/MIL  GAL
                           200
                            80
                            70
                            60

                            50

                            40


                            30



                            20
                                                                 10
                  3   45678910       2    3   4  56789 100
                       DESIGN AVERAGE  FLOW.  MGD
                                7-35

-------
7.6  References

 1.  Process Design Manual for Suspended Sotids Removal. Office of Technology Transfer,
     U. S. Environmental Protection Agency, Washington, D. C. (1974).

 2.  Process Design  Manual  for  Carbon Adsorption.  Office of  Technology  Transfer,
     U. S. Environmental Protection Agency, Washington, D. C. (October, 1973).

 3.  Metcalf & Eddy Engineers, Report to  Marlboro, Massachusetts, on  "Operation of
     Sewage Treatment Works for the Years 1961 and 1962." (August 19, 1963).

 4.  Loehr,  R., and Stephenson, R., An  Oxidation Pond as a Tertiary Treatment Device.
     Journal of the Sanitary Engineering Division, ASCE 91, No. 3, pp. 31-44 (1965).

 5.  Private  Communication  with  James Neighbor,  Vice President, Hinde Engineering
     Company, Highland Park, Illinois (October 28, 1970).

 6.  Eckenfelder, W. W., Engineering Aspects of Surface Aerator Design. Presented at the
     22nd Industrial Waste Conference, Purdue University (May, 1967).

 7.  Edde, G., Field Research  Studies of Hydraulic Mixing Patterns in Mechanically Aerated
     Stabilization Basins. Presented at the International Congress in  Industrial Wastewater,
     Stockholm,  Sweden (November, 1970).

 8.  Fall, E., Retention  Pond Improves Activated Sludge Effluent Quality. Journal Water
     Pollution  Control Federation, 37, No. 9, pp. 1,194-1,202 (1965).

 9.  Reynolds, Jeremiah,  Decatur  Tertiary Treatment Plan Proves its Worth. Water  and
     Sewage Works, 115, No. 12, pp. 553-584 (1968).

10.  Hickman, Paul, Polishing and Secondary Effluents and Treatment Bypasses. Presented
     at the 26th Industrial Waste Conference, Purdue University (May 4, 1971).

11.  Bodien, D.  G.,  and  Stenburg, R.  L., Microstraining Effectively Polishes Activated
     Sludge Plant Effluent. Water and Wastes Engineering, 3, No. 9, pp.  74-77 (1966).

12.  Diaper, E.W.J., Tertiary  Treatment by Microstraining. Water and  Sewage Works, 115,
     No. 6, pp. 202-207 (1969).

13.  Kreissl, J. F., Granular Media  Filtration of Wastewater: An Assessment. Presented at
     Seminar "Filtration of Water and Wastewater," Ann Arbor, Michigan (January, 1973).
                                        7-36

-------
14.  Hirsch, A.  A., Backwash Investigation of a Proposed Simple Uniformity  Control.
     Journal AWWA, 60, 570 (May, 1968).

15.  Neptune Microfloc Technical Release No. 4, Design Helps for Tertiary Filtration.

16.  University of Michigan  short  course, January  25-26,  1973.  Reported by  Thomas
     Hoogerhyde, Michigan Department of Health.

17.  Private communication with H. M. Mueller, Jr., Neptune Microfloc (April, 1973).

18.  Private communication with  S.  T. Welch,  Superintendent Spring Creek Pollution
     Control Facility (April, 1973).

19.  Private communication with J. Wiley Finney, Jr., Treatment results Hite Creek Tertiary
     Plant, Louisville, Kentucky (April, 1973).

20.  Gulp, G. L., and Hansen, S. P., Extended Aeration Effluent Polishing by Mixed-Media
     Filtration. Water and Sewage Works, 114, No. 2, pp. 46-51 (1967).

21.  Technical Bulletin, Dravo  Corp., Water and Waste Treatment Division, Pittsburgh, Pa.,
     Ventura, California East Side STP Test Report.

22.  Zenz,  D.  R., Weingarden, M. J., and Bogusch, E.D., Hanover Park Experimental Bay
     Project (March 8, 1972).

23.  Convery,  J.  J.,  Solids Removal Processes. Nutrient Removal and  Advanced Waste
     Treatment Symposium. Presented by Federal  Water Pollution Control Administration,
     Cincinnati, Ohio (April 29-30, 1969).

24.  Laverty, F. B., Stone, R. and Meyerson, L. A., Reclaiming Hyperion Effluent. Journal
     Sanitary Engineering Division, ASCE, 87, 6, 1  (November, 1961).

25.  Lynam, B., Ettelt,  G., and  McAloon, T. J., Tertiary Treatment at Metro Chicago by
     Means of Rapid Sand Filtration and Microstrainers. Journal Water Pollution Control
     Federation, 41, p. 247 (February, 1969).

26.  Performance Data Contained in Hydroclear Corporation Catalogue, Avon Lake, Ohio,
     as tested by the Clark County Utilities Department, Springfield, Ohio (May, 1969).

27.  U. S. EPA Internal Monthly Reports, Piscataway, Md. (March-September, 1973).

28.  U. S. EPA Internal Monthly Reports, Ely, Minn. (April-December, 1973).
                                         7-37

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29.  Study of Upflow Filter for Tertiary Treatment. U. S. EPA, Project No. 17030 DMA
     (August, 1972).

30.  Berg, E. L., and Brunner, C. A., Pressure Filtration of Secondary Treatment Plant
     Effluent. Water and Wastes Engineering, p. 54 (October, 1969).

31.  U. S. EPA Internal Monthly Report, Pomona Pilot Plant, summarizing previous work
     (June, 1972).

32.  Appraisal of Granular Carbon Contacting, Report No. TWRC 11 and 12, Federal Water
     Pollution Control Administration, Ohio Basin Region, Cincinnati, Ohio (May, 1969).

33.  Parkhurst, J. D., Dryden, F. D., McDermott, G.  N. and English, J., Pomona Activated
     Carbon Pilot Plant, Journal Water Pollution Control Federation, 39, No.  10, Part 2, pp.
     R70-R81 (1967).

34.  English, J.,  Masse, H. N., Carry, C. W., Pitkin,  J. B., and Haskins, J. E., Removal of
     Organics from Wastewater by Activated Carbon. Water, 67, No. 107, pp  147-153
     (1970).

35.  Gulp,  R. L.,  and Gulp, G. L., Advanced  Wastewater Treatment.  New  York: Van
     Nostrand-Reinhold Company (1971).

36.  Weber,  W. J., Jr.,  Hopkins,  C. B., and Bloom,  R., Jr., Expanded-Bed Active-Carbon
     Adsorption  Systems  for Wastewater Treatment. In Water Quality Improvement  by
     Physical and Chemical Processes. Edited by Gloyna, E. F., and Eckenfelder, W. W., Jr.,
     University of Texas Press, Austin, pp. 294-311 (1970).

37.  Masse,  A.  N., Organic  Residue Removal.  Nutrient  Removal  and Advanced Waste
     Treatment Symposium.  Presented by Federal Water Pollution Control Administration,
     Cincinnati, Ohio (April 29-30, 1969)
                                        7-38

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                                    CHAPTER 8

                 PREAERATION AND POSTAERATION PRACTICES
8.1  Preaeration

Preaeration  of  wastewater  has  been practiced for over 50 years throughout the United
States, generally for the purpose of odor control and to improve  the treatability of the
wastewater.  Short aeration periods ranging up to 15 minutes have been found adequate for
these purposes. For longer aeration periods, the additional benefits of grease separation and
improved flocculation of solids have also been observed (1).

While the use of aerated grit chambers is becoming increasingly popular as a pretreatment
unit in wastewater treatment plants, their use  should not be expected to  substantially
increase  BOD  or  SS removal  during primary  clarification due  to the relatively short
detention times normally employed.

     8.1.1   Preaeration Process Design Considerations

The major parameters to be considered in the design of preaeration facilities are rate of air
application and detention time. In order to maintain proper agitation, the air supply system
should provide a range  of  1.0 to  4.0 cfm per lineal  foot of tank.  This range will assure
adequate performance for nearly all physical tank layouts and types of aeration equipment
used.

Effective preaeration has been achieved  at detention times of 45 minutes and less (1) (2).
The Ten-States Standards (3) recommends a detention time of 30 minutes  for  effective
solids flocculation when inorganic chemicals are  used  in conjunction with preaeration. For
appreciable BOD reduction, a minimum of 45 minutes is recommended. In addition, the use
of polyelectrolytes may vary these detention times.

     8.1.2   Upgrading Considerations for Preaeration

Several efforts have been made to determine the  effects of preaeration on primary clarifier
performance. In 1961,  Seidel and Baumann (2) conducted a study at the Ames, Iowa,
secondary treatment plant  to determine the effects of preaeration by  direct comparison
with  a  parallel primary clarifier  receiving an  equal flow of the same waste  without
preaeration.  They  determined that with 45 minutes  detention and an aeration rate of
0.1 cu ft/gal of wastewater,  BOD and SS removals were both increased by seven to eight
percent in the primary tank. In this instance, an economic evaluation based on conventional
design standards showed that preaeration costs increase the total annual plant operating  cost
by two to three percent.

                                       8-1

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In an analysis of  operation  data  from 38 plants  using preaeration, Roe (1) observed
increased primary clarifier SS removals were obtained in some instances. Quantities of air
used  varied between  0.06 and 0.15  cu ft/gal. However, informal tests at the Allegheny
County  Sanitary  Authority  Wastewater  Treatment Plant  showed  that little or  no
improvement  in  primary clarifier  performance was achieved using preaeration with a
detention time of 45 minutes.

These results and others as reported by Eliassen (4) have lead to some disagreement as to the
desirability of providing  preaeration for increased primary SS or BOD removals. Although
the studies  by Roe,  and by Seidel and Baumann have established that primary clarifier
performance will  improve with prolonged preaeration time, it is often difficult to justify the
additional cost since the  incremental removals achieved as a  result of preaeration probably
would be partially or completely obtained in the secondary system without preaeration.

The specific conditions involved in determining the merits of preaeration must be evaluated
for each treatment situation. The  costs of providing sufficient preaeration and clarifier
detention times required for  significant improvements in primary performance must be
weighed against the savings that would be derived from the resulting reduction in secondary
loading.

The most likely upgrading situations involving preaeration that will be encountered are: (1)
when an existing plant  with preaeration  is to be  upgraded, and (2)  when  considering
chemical additions prior to existing primary treatment.  In  the  latter case,  existing plant
hydraulics will have a significant impact on the designer's options.

Where existing preaeration-primary plants  are being upgraded to secondary treatment, it
may  be beneficial  to  inject waste-activated sludge  upstream of preaeration  to improve
primary clarifier performance.

     8.1.3   Preaeration with Chemical Addition

Removal of BOD, SS and phosphorus in primary clarification may be substantially improved
through the use of chemical additions to preaeration units (5). The addition of chemicals
such as lime, alum, ferric chloride, or organic polyelectrolytes to the wastewater flow ahead
of the preaeration unit allows for adequate mixing of the chemical by air stirring. Chemical
addition can also  reduce  the preaeration time required to obtain  improved primary clarifier
performance.  Before implementing  preaeration with  chemical addition, it is  recommended
that full-  or pilot-scale tests be conducted to determine optimum chemical dosages and
removal efficiencies.

The  Central Contra Costa Sanitary District near San Francisco,  California, has operated a
2-mgd advanced treatment test facility since November 1971. The existing preaeration and
primary  clarification  facilities  shown on  Figure 8-1 were  upgraded  by providing lime

                                        8-2

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                                                  FIGURE  8-1
CD
CO
                                         PRIMARY TREATMENT UNITS AT THE

                       CENTRAL CONTRA COSTA SANITARY DISTRICT WATER RECLAMATION PLANT
                                            AGITATION  AIR
                                               HEADER
               HELICAL SCUM SKIMMER
 PREAERATION,
FLOCCULATION AND
 GRIT REMOVAL
    TANK
                LONGITUDINAL
                SLUDGE COLLECTOR
                                                                                     LUDGE RECIRCULATION
                                                                                           LINE
                                                                                                             NFLUENT
             SLUDGE CROSS  COLLECTOR

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addition to precipitate phosphorus and to maximize the removal of raw wastewater solids
thus reducing the load on the subsequent combined oxidation-nitrification unit (5) (6).

At  the Contra Costa facility, lime is added  to  the raw wastewater  in  a steep channel
immediately after screening. A hydraulic jump occurs ahead of the preaeration tank and
provides the necessary agitation for chemical mixing. Parker and Niles (5) indicate that the
combined preaeration and grit removal tank performs well as a flocculation basin using lime
as the coagulant. Diffused air mixing is used to promote  the  formation  of large readily
settleable flocculent particles. To further enhance coagulation and floe aggregation, settled
primary solids are  recirculated to the  preaeration  tank  influent.  Increasing the solids
concentration and solids contact in this manner  has been  shown to improve flocculation
efficiency.

Air diffusers of the swing-type were selected for this application as being most compatible
with the multiple function served by the preaeration tank. Diffused air induced currents
provide a readily  adjustable stirring  action necessary to  promote  flocculation  and grit
collection.  Problems  with scaling have often been encountered where  lime addition is
practiced  and rag fouling of  mechanical pretreatment equipment is  common. The easy
accessibility of air diffusers for maintenance minimizes these problems.

Critical design criteria for flocculation are detention time and aeration  rate. At Contra
Costa, the  preaeration  tank  was designed for 30 minutes detention  time  at  average
dry-weather flow. Satisfactory results  have  been obtained at operational detention times of
20 minutes.  Air supply rates for lime flocculation  must be lower than the rates used for
conventional preaeration to avoid shearing of the floe. Although  optimal rates have not been
definitely established, preliminary results based on the Contra Costa experience indicate air
requirements may be 1/3 to 1/7 those normally used for preaeration.

At  an overflow rate of 1,300 gpd/sq ft and 1.5 hours detention, the preaerated, chemically
treated system  significantly  outperforms  a parallel conventional system,  as shown  in
Table 8-1 (6).

8.2  Postaeration

Many states are considering or have already enacted legislation requiring the maintenance of
minimum DO concentrations in wastewater treatment plant effluents. This design criteria is
established to provide additional oxygen to the  receiving  waters. Plant effluents from
secondary clarifiers normally contain between 0.5  to 2.0 mg/1 of DO. Most surface water
quality standards,   depending  on the intended  water  use,  specify  a minimum DO
concentration of 4.0 mg/1.
                                         8-4

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                                   TABLE 8-1
                    PERFORMANCE OF PRIMARY FACILITIES
               AT CENTRAL CONTRA COSTA SANITARY DISTRICT
                WITH CHEMICAL TREATMENT TO PREAERATION

                                   pH 11.5  Operation        pH 11.0 Operation
                                   Ca(OH)2 = 500 mg/1       Ca(QH)2 = 400 mg/1
                                   Control  Chemical        Control  Chemical
                                   Primary   Primary        Primary   Primary

  BOD Removal, Percent                46        74             37       69

  SS Removal, Percent                  71        79             71       76

  Grease Removal, Percent               44        79             21       64
     8.2.1  Postaeration Process and Design Considerations

There are at least four methods available for the postaeration of a wastewater treatment
plant effluent. These are shown on Figure 8-2. Most of these devices were initially developed
for water treatment and are now being used in the wastewater treatment field.

         8.2.1.1   Diffused Aeration

Diffused  air aerators are usually placed in concrete tanks which are commonly 9 to 15 feet
deep and 10 to 30 feet wide. Ratios of width to depth of 1.5 are most desirable and should
not exceed 2.0 if effective mixing is to be obtained. Tank length is governed by the desired
detention period, which usually varies from 10 to 30 minutes.

Aeration  systems are  designed on the basis of their oxygen-transfer rate at standard
conditions. Standard conditions are defined as 1.0 atmosphere dry pressure at 20 deg C for
tap water containing 0.0 mg/1 DO. The required rate at which oxygen must be transferred to
the wastewater to raise the  DO the desired amount under actual operating conditions is
given by the following:

         AOR   = 8.33Q(C-C0)

     where:

         AOR   = Actual oxygen-transfer rate, Ib O2/day
         Q      = Postaeration influent flow, mgd
         C      = Required final DO level after postaeration, mg/1
         Co     = DO concentration of the postaeration influent, mg/1

                                      8-5

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                         FIGURE 8-2
               VARIOUS POSTAERATION DEVICES
    A.  DIFFUSED  AERATION

OXYGEN  SOURCE OR
MR COMPRESSOR^
              o
B.   MECHANICAL AERATION
                                           UULTU
                                      B-1 TURBINE  TYPE AERATOR
     C.   CASCADE A-ERATION
                     HEAD
             r^Z^LOSS
    D.   U-TUBE AERATION

 AIR—,.  ,	VENTURI
                ASPIRATOR
                   EFFLUENT
                   CHANNEL
                                       B-2 PUMP  TYPE AERATOR

BINE-^


AIR LINE 	
._ /SPARGER
p/. )


K


                                    B-3  AGITATOR SPARGED-SYSTEM
                              8-6

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This actual oxygen-transfer  rate  may be  adjusted to standard conditions by  applying
correction factors according to the following equation (7):
          SOR =
AOR
3CS-C\
k C20/
1.024T-20 a
     where:

          SOR   = Standard oxygen-transfer rate, Ib 02/day
          Cs     - DO saturation concentration of tap water at
                    temperature T, mg/1
          €20    = DO saturation concentration of tap water at
                    20 deg C, mg/1
          T      = Design temperature of the wastewater, deg C
          a      = 02 transfer coefficient of the wastewater
          3      = 02 saturation coefficient of the wastewater

Diffused air systems are designed to provide firm blower capacity, which is the capacity
remaining with the largest blower out of service.  The maximum air rate required to provide
firm capacity may be computed from the standard oxygen-transfer rate as follows:

          A™    =             SOR
                      1440   et   Ya   P0

     where:

          Am    = Firm blower capacity, cfm
          SOR   = Standard oxygen-transfer rate, Ib 02/day
          et      ~ ^2 transfer efficiency of 02 in diffused air
          ^a     = Specific weight of air at  design temperature and
                    relative humidity, pcf
          Po     = 02 content of dry air, proportion by weight

The use  of oxygen aeration  in the activated  sludge process may eliminate the need for
postaeration. Oxygen-aerated mixed liquor discharged to the secondary clarifier usually has
a DO of at least 6.0 mg/1 (8). In some instances,  postaeration with high purity oxygen may
be advantageous.

The Reno-Sparks, Nevada Joint Wastewater Treatment Facility provides activated sludge
secondary treatment for an average design flow of 20 mgd.  State standards requiring that a
minimum plant effluent DO concentration of 6.0 mg/1 be maintained are met by diffused air
postaeration of the secondary clarifier effluent prior to chlorine disinfection and discharge

                                        8-7

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over a final effluent weir (9). The postaeration unit consists of a single 210-foot by 30-foot
by  15-foot tank that provides a detention time of 48 minutes at average design flow. The
diffused air system serves both secondary and postaeration requirements using two blowers
with a total capacity range of 7,240 to 16,080 cfm of standard air. The system is regulated
on  the  basis  of the  secondary  aeration  air  requirements with surplus air used  for
postaeration.

Examination of plant  operating records for the year 1972 showed that an average of
17.0 mgd  was  treated. Monthly  average  secondary  clarifier effluent DO concentration
ranged from 0.3 mg/1 to 0.6 mg/1, while the plant discharge DO concentration was observed
to average between 6.1  mg/1 and 9.4 mg/1.

A recent  study was conducted to determine  on a daily  basis the  increase in  the  DO
concentration  of the treated effluent due to the postaeration facility alone.  Typical data
taken during this study are as follows:

                   Flow  Rate,  Q                 =   18.21 mgd
                   Wastewater temperature, T     =   20° C
                   Postaeration influent  DO,  Co  =   0.5  mg/1
                   Air supply rate, Am           =   6,050 cfm
                   Observed  postaeration DO,  C  =   7.6  mg/1

Assuming a diffuser oxygen-transfer efficiency, e^, of 10 percent; and oxygen transfer and
oxygen  saturation  coefficients, a and 3  of  0.85 and  0.95, respectively; the expected
postaeration effluent DO  concentration, C, may be  computed using  the equations stated
previously. The computed value for this data is 7.4 mg/1, which is in close agreement with
the observed DO concentration of 7.6 mg/1.

          8.2.1.2   Mechanical Aeration

Mechanical aerators are generally grouped in two broad categories:  turbine types and pump
types, as  shown on Figure 8-2.  In all  types, oxygen transfer occurs  through a vortexing
action and/or from the interfacial exposure of large volumes of liquid sprayed over the
surface.

To   optimize  aeration  and  mixing and  to  avoid  interference  between units,  aerator
manufacturers  have developed criteria for minimum  areas  and depths, depending on the
horsepower of the aerator and the configuration of the impeller.

Mechanical  aeration systems are  designed on  the basis of the horsepower required to
produce the needed standard oxygen transfer rate (SOR), which was defined in the previous
section. One aeration  design equation proposed by  Kormanik for  a  postaeration basin is
(10):

                                         8-8

-------
         p=  	SOR
              24  NO  ₯„  n
                        &

    where:

         P      = Horsepower required
         SOR   = Standard oxygen-transfer rate, Ib 02/day
         N0    =02 transfer efficiency under standard conditions in tap
                  water, Ib O2/hp-hr
         ₯„    = Correction factor related to basin geometry
         Tl      = Aerator  efficiency correction

         8.2.1.3  Cascade  Aeration

Cascade aeration takes advantage of the effluent discharge to create a series of steps or weirs
over which the flow moves in fairly thin layers, as shown on Figure 8-2. The objective is the
maximization of turbulence  to increase oxygen transfer. Head requirements vary from three
to ten feet,  depending upon the initial DO and the desired increase. If the necessary head is
not available, effluent pumping is required.

In England,  the Water Research Laboratory has performed investigations to qualify as much
as possible  the  layout of  cascade  aeration  schemes.  Barrett and  others proposed the
following formulae (11):

          r    = (Cs - C0)/(C8 - C)

          h   =         r-1
                 0.11ab(l-t-0.046T)

      where:
           r    - The deficit ratio
           Cs  - DO saturation concentration of the wastewater at
                 temperature T, mg/1
           C0  = DO concentration of the postaeration influent, mg/1
           C   = Required final DO level after postaeration, mg/1
           a    = Water quality parameter equal to 0.8 for a wastewater
                 treatment plant effluent
           b    = Weir geometry parameter equal to unity for a free
                 weir and 1.3 for the step weirs used in their
                 experimental work
           T   = Water temperature in deg C
           h    = Height in feet through which water falls
                                         8-9

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For example, to raise the DO concentration of a wastewater treatment plant effluent from
0.5 mg/1 to 4.5 mg/1 at 20 deg C, the computed overall height requirement for a series of
step weirs  would be approximately 4.0 feet.  However, it should be pointed out that the
values of the parameters a and b are somewhat arbitrary and need further refinement to
substantiate preliminary results.

The  wastewater treatment  plant at Pittsfield, Massachusetts, a trickling filter  plant,  is
followed by two cascades in parallel, each receiving half of the effluent flow. Each cascade
consists of a series of 18 three-foot wide concrete steps with a total horizontal length of
24.6 feet and a total vertical drop  of 10.3 feet, as shown on Figure 8-3.

Recently, a study was conducted to determine the increase in the effluent DO concentration
resulting from flow over the cascades (12). During the study period the total treated flow
averaged 7.0 mgd  at ISdegC.  The  secondary clarifier effluent  DO concentration was
observed to vary from 3.9 to 4.2  mg/1, while the aerated final  effluent DO varied between
5.8 and 6.2 mg/1. The values computed using Barrett's formula with a = 0.8 and b = 1.1 were
six  to ten  percent  higher than  the observed final effluent  DO  concentrations for the
corresponding clarifier  effluent and temperature. This value of b  is reasonable in this
instance since the  concrete steps  involved would be expected to produce more turbulence
than a free  weir (b  = 1.0), but less  turbulence than step weirs (b  =  1.3).

         8.2.1.4   U-Tube Aeration

The  U-tube aerator consists  of two basic  components: a conduit  to provide a vertical
U-shaped flow path and a device  for entraining air into the stream flow in the down leg of
the conduit as indicated on Figure 8-2. The entrainment device is one of two types: (1)
aspirator; or (2) compressor and diffuser. In either case, the entrained air is carried along the
down leg of the tube because the water velocity exceeds the buoyant rising velocity of the
air bubbles.

Various design considerations include air-to-water ratio, tube cross-sectional area, and depth.
The maximum air-to-water ratio practicable is a function of the  velocity through the system.
At velocities of approximately 4 fps, 20 percent air-to-water injection is about  the limit for
satisfactory operation (13).  The  hydraulic head requirements for  plants of 5 mgd  or less
should be  less than five feet. If sufficient head is not available, the flow  may be pumped
through the U-tube.

Speece and Orosco (13) have suggested that one economic method of construction for deep
U-tubes, greater than 20 feet in depth, would be a circular hole  bored into the soil. The hole
would be cased and a smaller pipe then suspended a few feet from the bottom of the hole as
shown on Figure 8-2. The diameter of the smaller pipe is selected so that its cross-sectional
area is approximately equal to the cross-sectional area of the annular space between the two
pipes.  Thus, the velocity of the  water will be approximately  equal in both legs  of the
U-tube.
                                          8-10

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CO
                                                          FIGURE  8-3
                                              CASCADE AERATOR AT PITTSFIELD,MASS.
                      12 STEPS
                      6" DROP
                      18" TREAD
                      6 STEPS
                      85/8" DROP
                      IB" TREAD

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Presently  there are no known  U-tube installations  in wastewater treatment plants for
postaeration.  However,  full-scale (8- to 20-inch diameter) U-tube units are now being
operated to provide in situ aeration in sanitary force mains in two communities in Louisiana
and  Texas  (14). These installations have been effective in reducing serious odor  and
corrosion   problems  resulting from  sulfides.   No  maintenance  has  been  required in
approximately two years of continuous operation. The possibilities of using a U-tube  as a
postaeration device seem good at this time.

     8.2.2  Upgrading Considerations for Postaeration

The selection of postaeration facilities for treatment plant upgrading is greatly influenced by
the specific conditions encountered.  The degree to which existing facilities  can be used in
the upgrading will, in  many cases, determine the proper selection  of  equipment.  For
example,  where the  plant is undergoing general upgrading, it  may  be  possible to
substantially reduce the costs of mechanical  or diffused  air facilities by converting an
existing basin for use as a postaeration tank.

In some situations there may be  operational and/or other advantages in the use of the same
type of aeration system for postaeration as is already in use elsewhere in  the plant. This is
especially true of a diffused air secondary treatment plant where the same  blowers  and
housing structure could be used to supply the postaeration unit as well,  with only minor
modification.

Cascade postaeration has the obvious advantage of no power, labor or maintenance costs
where sufficient head is available between the plant discharge and the receiving water. Where
stream standards rather than effluent standards are applicable, but available head is limited
at high river levels, it may be possible to use cascade postaeration by taking advantage of
seasonal fluctuations in the dilution capacity of the stream. The plant effluent DO is most
critical to stream quality during low flow  periods. This coincides with the  time when the
maximum head is  available for  effective cascade postaeration of the effluent. At higher
stream flows when the cascade may be partially submerged, less postaeration is required
because of greater dilution.

Although U-tube aeration has been utilized only for sanitary force main  aeration to date,
the use of this technique for postaeration is promising where sufficient head is available for
gravity  flow.  U-tube  postaeration appears particularly attractive where  limited  space  is
available for facilities.

Because the peculiarities of each upgrading situation so greatly affect the feasibility and
costs of the various  alternative  postaeration  devices, no clear picture emerges as to the
relative merits and  costs of each  method. In each upgrading, an analysis should be made of
the applicable conditions such as type of treatment involved, usable existing facilities, and
                                          8-12

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available tank volume and head. As will be discussed in Chapter 9,  it may be feasible to
combine postaeration and chlorine disinfection advantageously.

It must be noted that postaeration can be expected to produce a detergent type foam. Thus,
the facilities should be designed to retain and destroy the foam created, rather than to allow
it to flow unimpeded to the surface of the receiving water.

8.3  References

  1.  Roe,  F.,  Pre-aeration  and  Air Flocculation.  Journal  Water  Pollution  Control
     Federation, 23, No. 2, pp. 127-140 (1951).

  2.  Seidel, H., and Baumann, E., Effect of Pre-aeration on the Primary Treatment of
     Sewage. Journal Water Pollution Control Federation, 33, No. 4, pp. 339-355 (1961).

  3.  Recommended Standards for Sewage Works. Great Lakes -  Upper Mississippi River
     Board of State Sanitary Engineers (1971).

  4.  Eliassen, R. and Coburn, D.F., Versatility and Expandability ofPretreatment, Journal
     of the Sanitary Engineering Division, ASCE, 95, No. 2, pp. 299-310 (1969).

  5.  Parker, D.S. and Niles, D.G., Full-Scale Test Plant at Contra Costa Turns Out Valuable
     Data on  Advanced  Treatment. Bulletin of the  California Water Pollution  Control
     Association, 9, No. 1 (1972).

  6.  Horstkotte, G.A., Niles, D.G., Parker, D.S., and Caldwell, D.H., Full-Scale Testing of a
     Water Reclamation  System.  Journal Water Pollution Control Federation,  46 No. 1,
     pp. 181-197(1974).

  7.  Metcalf  & Eddy,  Inc.,  Wastewater Engineering:  Collection,  Treatment,  Disposal.
     McGraw-Hill, Inc. (1972).

 8.  Albertsson, J., et al,  Investigation of the Use of High Purity  Oxygen Aeration in the
     Conventional  Activated  Sludge Process.  Federal  Water  Quality Administration,
     Program Number 17050 DNW, (1970).

 9.  Private communication with  G. Davis, Superintendent, Reno-Sparks Joint Treatment
     Plant, Sparks,  Nevada, November, 1973.

10.  Kormanik,  R., Simplified  Mathematical Procedure  for  Designing  Post  Aeration
     Systems. Journal Water Pollution Control Federation, 41, No.  11,  pp. 1956-1958
     (1969).
                                        8-13

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11. Barrett,  M.J., et  al, Aeration Studies of Four Weir Systems. Water  and Water
    Engineering, 64, No. 9, pp. 407-413 (1960).

12. Private communication with W. Fallen, Plant Superintendent, Pittsfield, Massachusetts,
    October, 1973.

13. Speece,  R., and  Orosco,  R.,  Design of U-tube Aeration Systems. Journal  of the
    Sanitary Engineering Division, ASCE, 96, No. 3, pp. 715-726 (1970).

14. Mitchell, R.C., U-Tube Aeration. U. S. EPA, Project No. 17050 DVT, Contract No.
    68-01-0120 (September, 1973).
                                       8-14

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                                    CHAPTER 9

                       DISINFECTION AND ODOR CONTROL
9.1  General

Disinfection and  odor control are receiving increased attention from regulatory agencies
through the establishment and enforcement of rigid bacteriological effluent standards and
air pollution standards. In upgrading situations, the need for improved disinfection and the
elimination  of  odor  problems  are  frequently  encountered.  Adequate  and  reliable
disinfection and odor control are essential to ensure that wastewater treatment plants are
environmentally safe and aesthetically acceptable to the public.

9.2  Disinfection

In 1973, 48 percent of all municipal wastewater treatment plants in the United States were
equipped with chlorination facilities for disinfection purposes (1). Other disinfectants, such
as ozone, ultraviolet light and bromine chloride, are currently being evaluated by the U. S.
EPA to determine their potential use  in disinfecting wastewater treatment plant effluents.
Recent  shortages and  price  escalation  of  liquid  chlorine  have emphasized the need to
consider other methods of disinfection.

     9.2.1  Chlorine Fundamentals

When chlorine is added  to water,  it hydrolyzes to form hypochlorous  acid (HOC1) as
follows:

         ci2 + H2o  ^        HOCI + H+ + cr

The hypochlorous acid further ionizes to form hypochlorite ion (OC1") as follows:
The  equilibrium concentrations of HOCI and  OC1" in solution depend on the  pH of the
wastewater. Increasing the pH will  shift the equilibrium toward the formation of higher
concentrations of OC1" and, conversely, decreasing the pH will shift the equilibrium toward
the formation of higher concentrations of HOCI.

Chlorine may also  be applied as sodium hypochlorite (NaOCl), or calcium hypochlorite
[Ca  (OC1)2].  The hypochlorite  form reacts as follows:

         NaOCl - s- Na+ + OC1"

                                       9-1

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          Ca (OC1)2 - * Ca2+ 2OC1'

          H+ +  OCr^^ HOC1

The quantity of HOC1 plus OC1" in wastewater is known as free available chlorine.

Hypochlorous acid is an extremely potent germicide ai pH 6.5 to 7.5 (2). It is also a very
active  oxidizing agent and is therefore short lived in the presence of readily  oxidized
compounds such as  ammonia. Since  most wastewater effluents contain ammonia, the
following reactions will occur upon  the addition of chlorine:

          NH3 + HOC1 - *- NH2 Cl + H20
                              (monochloramine)
         NH2  Cl + HOC1 - >NHC12 + H2O
                              (dichloramine)

         NHC12 +  HOC1 - *- NC13 + H20
                              (nitrogentrichloride)

The  two species that predominate in most cases are monochloramine  and dichloramine.
They are commonly referred to  as  the  combined available  chlorine.  The reaction with
ammonia is unfortunate, because chloramines are many times less potent than hypochlorous
acid  as a disinfectant. Figure 9-1 illustrates the relative potency of free and combined forms
of chlorine.

Hypochlorous acid also reacts with other  organic matter in wastewater such as amino acids
and inorganic matter such as sulfites and nitrites  to produce chlorine compounds that have
very  little or no disinfecting power (2). Design engineers should  be aware of the extent of
such  side reactions when determining  the  optimum chlorine dosages to  apply  to  a
wastewater.

Total chlorine  residual  is  the  sum  of the  combined and free chlorine concentrations
remaining after a specified  period of time. Chlorine demand  is defined as the difference
between the chlorine applied and the total residual chlorine  remaining at the end of the
contact period  (3). It  provides a measure of all chlorine demanding reactions including
disinfection.

Browning and McLaren (3) analyzed 844 samples from 12 primary treatment plants and 777
samples from  15 secondary  treatment  plants to obtain a correlation between residual
chlorine and coliform  MPN  per  100ml. The   results of  their analyses are shown on
Figure 9-2. The curves represent the MPN remaining after 30 minutes of chlorine contact in
                                       9-2

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                   FIGURE 9-1
        RELATIONSHIP BETWEEN CONCENTRATION AND TIME
       FOR 99 PERCENT DESTRUCTION OF ESCHERICHIA CPU
        BY DIFFERENT FORMS OF CHLORINE AT 2 TO 6°C (2)
    10
   1 .0-
   0.10-
co

oe
  0.010 -
I _ I—I—I I I 1-1
           I  I  I—-III
         \      X
            \\
           \   \
                              \

        	HYPOCHLOROUS
           ACID (HOCI)

        -—HYPOCHLORITE ION
             (OCD

        •— MONOCHLORAMINE
            (NH2CI)
                            \
  0. 001
              5   10
               50   100
500  1000
                     MINUTES
                    9-3

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                  FIGURE 9-2
   MPN COLIFORM VS. CHLORINE  RESIDUAL (3)
100,000-3
  0.000-
   1000_
     00-
     10
                           I   I   I    I   I
                 CONTACT  TIME OF 30 MINUTES
                      o -  PRIMARY EFFLUENT
                      v -  SECONDARY EFFLUENT
             T
        0123456
  CHLORINE RESIDUAL, MG/L MODIFIED STARCH  -  IODIDE METHOD
                       9-4

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a well-designed  chlorine contact chamber.  Insufficient data were available for residuals
above 4 mg/1.  The results of these analyses should not be quantitatively applied to any
primary or  secondary effluent.  However, the  study  provides a good indication of the
effectiveness of increased chlorine residuals on primary and secondary effluents.

Other  factors which influence  the  germicidal  effectiveness of  chlorine  are pH and
wastewater temperature. At pH values greater than 7.5, the less potent form of free chlorine
(OC1~) predominates.  Increased  pH  also  diminishes  the  disinfecting  efficiency  of
monochloramine (2). It has also been demonstrated that the germicidal effectiveness of free
and combined chlorine is markedly diminished with decreasing wastewater temperature (2).

     9.2.2   Chlorine Dosage Rates

The  following table was  taken  from  the Water Pollution Control Federation's Sewage
Treatment Plant Design Manual  of  Practice  No. 8 and contains ranges of chlorine dosages
recommended for disinfection (4).
                                     TABLE 9-1
                           CHLORINE DOSAGE RANGES

                Waste                                Chlorine Dosage
                                                           mg/1

     Raw Sewage                                          6 to 12
     Raw Sewage (Septic)                                  12 to 25
     Settled Sewage                                        5 to 10
     Settled Sewage (Septic)                               12 to 40
     Chemical Precipitation Effluent                         3 to 10
     Trickling Filter Effluent                                3 to 10
     Activated Sludge Effluent                              2 to  8
     Sand Filter Effluent                                   1 to  5
   9.2.3   Upgrading Chlorine Contact Tanks

Improved disinfection can be achieved in existing chlorine contact tanks by:

     1.    Improving the mixing characteristics of the basin

     2.    Improving the flow pattern by elimination of short circuiting

     3.    Improving the chlorine diffuser system

                                        9-5

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     4.    Lengthening the contact time

     5.    Increasing the chlorine dosage rate

     6.    Maintaining the optimum pH range

     7.    Upstream removal of ammonia nitrogen.

The technique to be employed will depend primarily on the disinfection standard to be met,
the characteristics of the plant effluent and physical characteristics of the plant itself.

Stringent  disinfection  standards  required for protection of shellfish waters, recreational
waters and for various  reuse purposes will often require nitrification  of  the  ammonia
nitrogen present prior to chlorine addition unless extremely long postchlorination retention
basins are  used to allow monitoring of plant effluents prior to discharge.

If less stringent disinfection is required, existing chlorination systems may be upgraded by
providing  higher chlorine dosages, improved mixing and/or longer  contact periods. In most
cases, improved mixing and longer contact times have proven more effective than increased
chlorine dosage.  Effective  contact time can be  increased by improving  the flow pattern
through the existing basin to eliminate short circuiting or by adding additional tankage.

The  configuration of the contact tank may result in appreciable differences between the
actual and theoretical  contact times. Model tests were made by the Metropolitan Sanitary
District of Greater Chicago (5) to evaluate the impact of different baffle  designs on actual
detention  time. The various  baffle designs evaluated and the test results  are shown on
Figure 9-3.

The  data  show that the baffle  arrangement used in Scheme HA, using turning  vanes,
provided  substantially higher actual contact times than  the  other  schemes tested. The
improper  use of turning vanes, Scheme II, resulted in the lowest actual contact times. Based
on the findings of this study, the features of Scheme IIA were incorporated in the design of
the 330 mgd chlorination  facility  at the Chicago  Calumet Sewage Treatment Plant. The
findings of this  study saved the Metropolitan  Sanitary District of  Greater  Chicago an
estimated  $284,000 in construction costs and considerable reduction in annual costs due to
more efficient chlorine nrxing.

Rapid dispersement of  chlorine at the  addition point  increases  chlorine contact and
improves  disinfection efficiency. Baffles can be designed to create turbulence at the chlorine
addition point  and improve  mixing. Baffled systems have the advantage of not requiring
mechanical equipment. Mechanical  mixing or air agitation can be advantageously employed
where plant hydraulics will not allow the use of baffles, or where a portion  of the existing
basin can  be  converted to a mixing chamber and the  remainder of the basin and/or  a long
outfall sewer can be used to provide the needed contact time.
                                        9-6

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   SCHEME
dD
FLOW. MGD
WATER DEPTH, FT
CONTACT TIME. MIN
MINIMUM
MEAN
MAXIMUM
82
14.

21
29.
36.
5
2

0
2
5
                                                  FIGURE 9-3
                      IMPACT OF CHLORINE TANK BAFFLE DESIGN ON ACTUAL DETENTION TIME (5)
                            SCHEME  IA
                                  /\
                             82 5
                             14 2

                             17 6
                             26,4
                             17 8
                                                    SCHEME IB
82.5
U. 2

15.3
23.9
34  8
                                                                             SCHEME I I
82  5
M  2

15.2
20.5
31.9
                                                                                                      SCHEME III
                                                                                                  r
82.5
14.2

25.0
31. 1
39.5

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Studies by Kothandaraman and  Lin (6) have shown  that chlorinated wastewater can be
subjected to air agitation with no apparent loss of total chlorine residual. Their studies also
indicated a better  bacterial  kill  with air  agitation than without air  agitation. In  those
facilities where  postaeration facilities  are  required  to  raise  the DO  content  of the
wastewater, it may  be feasible to use the chlorine contact tanks for both postaeration and
disinfection.

     9.2.4   Chlorination Systems

The  most common form of chlorine utilized in the field of wastewater treatment is liquid
chlorine. In a typical installation, liquid  chlorine is  delivered in pressurized containers.
Standard sizes for containers are 100-pound, 150-pound and 1-ton cylinders, and 16-ton,
30-ton and 55-ton  tank cars. Normally, gaseous chlorine is released from the top of the
container and is drawn through  the chlorinators by  a vacuum. In larger plants where the
evaporation rate within the container cannot meet the demand, liquid chlorine is withdrawn
and evaporated in separate evaporators. The chlorine gas is then mixed with plant effluent
or potable  water (small plants) to form a chlorine solution which is fed into the wastewater.
Such systems have proven  to  be  highly reliable and  economical.  However,  there  are
ramifications that should be considered.

     1.  Liquid chlorine is a potentially dangerous material.

     2.  The  demand  for  liquid  chlorine  has been  increasing  steadily,  while the
         construction of liquid chlorine manufacturing facilities has lagged.

     3.  Unless the  above trend is corrected, it can  be expected that shortages of liquid
         chlorine will develop, and the cost will significantly increase.

In recent  years, the utilization of sodium hypochlorite  for  disinfection has become
attractive. Sodium hypochlorite can either be delivered to the site in liquid form in 500 to
5,000  gallon tank cars or trucks,  or manufactured on  site. When delivered to the site, it is
normally sold at a  concentration of 12 to 15 percent  by weight of available chlorine. The
tank cars are unloaded into  storage tanks, and the hypochlorite is fed to the wastewater
through  chemical feeders.  Sodium  hypochlorite  can be manufactured on  site from salt or
from  seawater.  Generation units  are  now  being   produced  by at  least  four  major
manufacturers. While most of these units produce hypochlorite  at concentrations of one
percent or  less, one system produces hypochlorite at a concentration of about eight percent.

     9.2.5   Ozonation

Based  on the success of ozonation in the water treatment field, ozone has been considered
as a possible  disinfectant  for  wastewater.  Some of  the advantages  of ozonation are as
follows:

                                         9-8

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     1.   Ozone is generated from  air and its supply is  dependent only on a source of
         power. Ozone can also be produced from oxygen at significant energy savings, an
         option  which  should  be considered where on-site generation of oxygen  is
         practiced in conjunction with biological treatment.

     2.   Ozone may be a more efficient viricide than chlorine.

     3.   Ozonation can  also be used  as a tertiary  treatment process  for oxidation of
         residual carbon compounds and for odor control.

     4.   The Maximum Allowable  Concentration (MAC)  of ozone in air as established by
         the  American  Council of Governmental Industrial Hygienists is 0.1 ppm  by
         volume for continuous human exposure. The threshold odor of ozone is 0.01 to
         0.02 ppm. This means that a person working near an ozone handling area should
         be able to detect the presence of ozone at concentrations far below the MAC.

     5.   Ozonated effluents have not been shown to be toxic to the receiving water biota,
         as  have residual  chlorine  compounds  such as  chloramines and  chlorinated
         hydrocarbons.  Ozone does not increase  the  dissolved solids  concentration  in the
         effluent as does chlorine.

     6.   Ozonation of effluents increases the DO.

The predominant disadvantage of ozonation is the high capital and operating cost associated
with its generation. Further  development of the process may lead to better economy which
would encourage greater use  of ozonation for wastewater disinfection.  .

Nebel, et al,  (7) conducted pilot plant  studies at Louisville,  Kentucky, using ozone for
disinfection of activated sludge effluent. The wastewater contained a significant amount of
nonbiodegradable industrial  organic  wastes which exerted an above-normal ozone demand.
Nevertheless, the tests indicated that a dosage of 15 mg/1 and a contact time of 22 minutes
resulted in excellent destruction of fecal and total coliforms and fecal streptococci.

During 1973, two separate cost evaluations of alternative disinfection systems were made by
Metcalf & Eddy, Engineers in Boston. Both of the plants studied were large; one a 105-mgd
plant  located on the eastern seaboard,  and the  other a  230-mgd  plant located  in the
midwest. The eastern plant  study included cost comparisons of liquid chlorine, trucked-in
and on-site generated sodium hypochlorite and ozonation.  The  midwestern study compared
all of the above alternatives  except ozonation.  The results  of the two studies are presented
in Table 9-2. The costs are shown as a ratio to the liquid chlorine cost and are a sum  of the
annual operating costs and amortized capital costs.
                                        9-9

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                                    TABLE 9-2
      RELATIVE TOTAL ANNUAL COSTS OF DISINFECTION ALTERNATIVES
                                                         Cost Ratio 1
           Alternative

Liquid Chlorine
Sodium Hypochlorite, Trucked to Site
On-Site Generation
  8% Sodium Hypochlorite
  \% Sodium Hypochlorite
Ozone (Generated from Oxygen)
Eastern
Plant
105 mgd
1
2.0
1.2
1.8
3.0
Midwestern
Plant
230 mgd
1
2.4
1.4
2.1
	
  Data used to compute cost ratios:
     1. Cost of liquid chlorine
     2. Cost of liquid sodium hypochlorite
     3. Capital cost of on-site generator (1%)
     4. Capital cost of on-site generator (8%)
     5. Average ozone dosage
     6. Average chlorine dosage
     7. Amortization rate
   }.49/ton
$0.18/gal
$4,200,000
$2,900,000
10 mg/1
16.6 mg/1
$75/ton
$0.20/gal
$1,116,000
$  975,400

3 mg/1
                                                  40 yr. at6!/2% 15yr. at 7%
9.3  Odor Control

Wastewater  treatment  plants serving  large municipalities  are generally  characterized by
extensive collection systems with correspondingly high detention times. For example, the
Washington, D. C. Pollution Control Plant serves areas as far as 25 to 30 miles away. This
type of situation often leads to odor problems during summer periods. Odor problems are
characteristically most critical during the plant's low flow periods (approximately 9 PM to 4
AM), due to increases in the sewer detention time.

     9.3.1   Odor Generation and Characteristics

Odors from wastewater treatment plants can usually be attributed to three sources:  septic
raw wastewater, overloaded secondary treatment facilities and sludge treatment practices.

Septicity in wastewaters is caused by the depletion of DO  due to long residence in sewers
and the subsequent increase in anaerobic activity. As wastewater becomes septic, facultative
                                        9-10

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and anaerobic bacteria  flourish.  These bacteria utilize  nitrates  and sulfates present in
wastewater  as their oxygen source.  The reduction of sulfate  ions  produces the highly
odorous gas,  hydrogen sulfide. Other odorous gases  which may be present  are indole,
skatole, mercaptans, disulfides, volatile fatty acids and ammonia.

Increased summer temperature  and extended sewer detention times can result in the rapid
buildup of hydrogen sulfide and carbon dioxide according to the following reactions (8):
                                             S= + H20 + CO2
At a pH level below 8, the equilibrium shifts toward the formation of nonionized H2S and is
about 80 percent complete at pH 7. At pH 8 and above, most of the reduced sulfur exists in
solution as HS" and S~ ions (8). H^S is noticeable even in the cold when present in water to
the extent of 0.5 mg/1. When present to the extent of 1.0 mg/1, it becomes very  offensive
(9).

Overloaded  secondary  treatment facilities  are also a potential source of odor. If  the air
supply to  an activated  sludge aeration tank is inadequate,  odorous conditions usually
develop. It is also possible that a properly  sized air supply system can strip odorous gases
from septic wastewater.

Odors associated with sludge treatment occur in thickening, digestion and sludge dewatering
facilities. Thickeners may receive both  septic primary and secondary sludges. Gases from
well-operated digesters may contain small quantities of t^S, which are usually destroyed by
normal  flaring of digester gas.  The predominant odor  in digested sludge is ammonia,
although traces of volatile organic acids may be present.

     9.3.2   Odor Measurement

Odor data are generally  qualitative rather than  quantitative in nature. The two  available
quantitative methods are the t^S determination and  the Threshold Odor Number (TON).
The latter method is only semiquantitative in that determination  of the TON is dependent
on  the  olfactory  senses  of  the  individual  performing  the  analysis.  This  can  be
de-personalized somewhat by using a panel to determine the TON value for a sample.
                                        9-11

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     9.3.3  Odor Control Methods Available

The various methods available for control of odor emanating from a wastewater treatment
plant are:

     1.   Changes in the operational procedures and new techniques

     2.   Chemical treatment or pretreatment, which might include chlorine, ozone, lime or
          powered carbon

     3.   Collection and treatment of noxious gases.

          9.3.3.1   Changes in Operational Procedures and New Techniques

Odors associated with septic wastewater are generally not amenable to solution through
operational  changes within the treatment  plant itself. These odors must be controlled
upstream of the plant through  the use of  aeration or chemical  treatment methods. The
applicability of in-sewer aeration methods for  reduction  of odors  and hydrogen sulfide
corrosion is discussed in the Process Design Manual for Sulfide Control in Sanitary Sewerage
Systems  (10). Among the procedures that have been evaluated are U-tube installations  (refer
to Section 8.2.1.4) and pure oxygen injection into force mains.

Many sludge odors in  a plant are a direct  result of an improperly operated or overloaded
anaerobic sludge digester.  Improved temperature control  and better mixing  of digester
contents may alleviate the odor problem.

          9.3.3.2   Chemical Treatment of Wastewater

Chlorination is  probably the most widely used of the chemical treatment processes available
to control odors for the following reasons:

     1.    It is highly effective.

     2.    Many treatment operators have had experience in handling chlorine.

     3.    Chlorination facilities already exist at most plants for disinfection.

Chlorination is  used for two purposes: to retard biological action which produces odors,
and to react chemically with odorous sulfur compounds, oxidizing them to innocuous sulfur
forms, usually free colloidal sulfur.
                                        9-12

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1
Sulfide
mg/1
1.7
0.5
0.2
0.2
0.2
120
Sulfide
mg/1
1.7
0.7
0.2
0.2
0.2
Table 9-3 contains a summary of odor  reduction data for a chlorinated raw domestic
wastewater (11). A prechlorination dosage of 10 mg/1 at maximum flow was recommended
for odor control.  In  addition,  another incremental 5 mg/1 of chlorine capacity was
recommended as an adequate safety margin for peaks in sulfide levels or chlorine demand.
                                   TABLE 9-3
               EFFECT OF CHLORINE ON ODOR REDUCTION FOR A
                       RAW DOMESTIC WASTEWATER (11)

                                                  Detention Time in Minutes
       Chlorine^
       Dosage
         mg/1
          0
          5
         10
         25
         50

1 PH = 7.
  Air Temperature = 85 deg F.
Ozone has been added to wastewaters for odor control with some favorable results. Because
of the  extremely  high  reactivity of ozone, a much higher ozone  demand  is generally
exhibited by a wastewater than would be exhibited for chlorine. However, the use of pure
oxygen in activated sludge treatment may have an added benefit, since the oxygen gas could
provide the ozone generator with an economic source of oxygen.  Due to the  high cost of
ozone generation, the use of ozone for odor control may be limited  (11).

Lime and powdered carbon have also been used in various applications for odor control. The
addition of lime to septic wastewater raises the pH. Since the solubility of H2S increases
with increasing pH, less ^S evolves, thereby decreasing the odor level. Powdered activated
carbon adsorbs odor-causing materials and thereby decreases the odor level. The results of a
laboratory odor study are presented in Table 9-4 (12). Concentrations of less than 10 mg/1
of powdered activated  carbon  were successful in providing significant  odor reduction.
Additional design information for controlling odors is available in the Process Design Manual
for Sulfide Control (10).
                                       9-13

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                                    TABLE 9-4
                   EFFECT OF POWDERED ACTIVATED CARBON
                            ON ODOR REDUCTION (12)

                         Raw Domestic      Activated Carbon       Concentration of
       Plant              Wastewaterl       Treated Effluent       Activated Carbon
                              TON2              TON2                 mg/1
Charlottesville, Va.             300                100                    3.8
Hershey Estates, Pa.            140                100                    5.0
Butler, Pa.                     280                200                   10.0
 1 Sample temperature = 60 deg F.
 2 Threshold Odor Number.
         9.3.3.3   Collection and Treatment of Noxious Gases

The covering of odorous unit process facilities to localize odors is a method which can be
used to prevent odors from reaching the atmosphere. The major expenses of this method are
the covering of the units and collection and treatment of the evacuated gases. In cold
climates, covering units can lead to conditions of high humidity and indoor fog if proper
ventilation  is not provided.  Many municipal plants,  e.g., Cedar Rapids, Iowa (13), and
Elmira, New York (13), are  using low-cost, formed-in-place styrofoam domes on odorous
treatment units.

The treatment methods usually considered for evacuated gases include simple or catalytic
combustion, ozonation and chemical oxidation.  Combustion  methods require heating the
gases to approximately 800 to 900 deg F for catalytic combustion and approximately 1,300
to 1,400 deg F for simple combustion.  Operating costs for these methods are  primarily
determined by the amount of air to be heated. Ozonation costs, while somewhat affected by
the volume of gas collected, are primarily affected by  the quantity of odorous materials to
be controlled.

    9.3.4   Effects on Subsequent Units

A consideration in using  chlorine for odor control is  that the chlorine dosage should not
produce a  high residual chlorine level which may in turn  be detrimental to secondary
biological units. When using lime for odor control, consideration must also  be given to
increased sludge production.
                                       9-14

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   9.3.5  Process Designs and Cost Estimates

A cost estimate has been prepared for two odor-control systems (chlorination and powdered
activated carbon) for 1, 3 and 5 mgd treatment plants. The capital costs are presented in
Table 9-5. The  chemicals are added to raw wastewater before the downstream treatment
units.
                                     TABLE 9-5
                 CAPITAL COSTS FOR ODOR CONTROL SYSTEMS

   Plant                                Capital Costs for Odor Control Systems
   Size                            Chlorination       Powdered Activated Carbon
   mgd                              10mg/l                    10mg/l

    1                                $46,000!                  $37,000

    3                                 49,000!                   52,000
    5                                 51,0001                   73,000


  Smallest size commercially available chlorinator.
The chlorination system included a gas chlorinator capable of delivering 10 mg/1 of chlorine
during peak flow rates. A building, scale and other necessary appurtenances were included.
The powdered activated carbon system included a 15 day storage hopper and a volumetric
feeder capable  of  delivering 10 mg/1 at  peak flow rates.  In addition,  a one-day capacity
slurry tank, pump,  building and associated piping were included.

9.4  Other Uses of Chlorine

In the operation  of wastewater treatment plants, chlorine has been  found useful as an
upgrading technique. Some of the various applications of chlorine are as follows (4) (14)
(15):

     1.   Destruction or control of undesirable growths of algae and slime-forming bacteria
         in pipelines and conduits

     2.   Control of filter flies, clogging and ponding in trickling filters (Chlorine applied
         for approximately 8 hours to produce a residual of 1 to 2 mg/1 in the distributor
         arm will generally unclog the filter. Residuals  of 20 to 50  mg/1 will  eliminate
         ponding by causing the filter to unload all of its biological slime)
                                       9-15

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     3.   Improvement in wastewater coagulation

     4.   Improvement in the separation of grease from wastewaters

     5.   Reduction of the immediate oxygen requirements of return activated sludge and
         digester supernatant return

     6.   Chlorination of return activated sludge to control sludge bulking (A chlorine dose
         of 1 to  10 mg/1 based on return sludge flow has been used, provided the chlorine
         application point is located to allow for 2 to 3 minutes of mixing before being
         discharged to the aeration  basin; otherwise high "spot  chlorine" concentrations
         may damage the activated sludge biomass).

9.5  References

 1.  Unpublished  U. S. EPA Data (October, 1973).

 2.  Chambers, C., Chlorination for  Control of Bacteria and Viruses in Treatment Plant
     Effluents. Journal Water Pollution Control Federation, 43, No. 2, pp. 228-241 (1971).

 3.  Browning, G. E. and  McLaren, F. R., Experiences with Wastewater Disinfection in
     California. Journal Water  Pollution Control  Federation,  39,  No. 8,  pp. 1351-1361
     (1967).

 4.  Sewage  Treatment Plant Design. Water  Pollution  Control Federation  Manual of
     Practice No. 8, Washington, D. C. (1959).

 5.  Louie, D., and Fohrman M., Hydraulic Model Studies of Chlorine Mixing and Contact
     Chambers. Journal Water Pollution Control Federation, 40, No. 2, pp. 174-184 (1968).

 6.  Kothandaraman, V., and Lin, S. D., Air Agitation of Treatment Plant Effluents. Public
     Works, 104, No. 8, pp. 65-68 (1973).

 7.  Nebel, C., Gottschling, R. D., Hutchison, R. L., McBride, T.  J., Taylor, D. M., Pavoni,
     J. L., Tittlebaum, M. E., Spencer,  H. E., and Fleischman, M., Ozone Disinfection of
     Industrial-Municipal Secondary Effluents. Journal Water Pollution Control Federation,
     45, No. 12, pp. 2493-2507 (1973).

 8.  Sawyer,   C.,  Chemistry for  Sanitary  Engineers.  New York: McGraw-Hill  Book
     Company (1960).

 9.  Nordell,  E.,  Water Treatment for Industrial and Other Uses. New York:  Reinhold
     Publishing Corporation (1961).

                                       9-16

-------
10. Process Design Manual for Sulfide Control in Sanitary Sewerage Systems. U. S. EPA,
    Office of Technology Transfer, Washington, D. C. (1974).

11. Roy F. Weston, Inc., Engineer's Preliminary Report Odor Control Studies Washington,
    D. C. Water Pollution Control Plant. (December, 1967)

12. Aqua Nucharfor Odor Control in Waste Treatment, Covington, Virginia.

13. Dow Domes-Environmental Enclosures. Dow  Chemical  Company Bulletin,  Midland,
    Michigan (1968).

14. Fair, G., and Geyer,  J., Water Supply and Waste-Water Disposal.  New York: John
    Wiley and Sons, Inc. (1954).

15. Operation of Wastewater Treatment Plants. Water Pollution Control Federation Manual
    of Practice No. 1, Washington, D. C. (1970).
                                       9-17

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                                   CHAPTER 10

                               SLUDGE THICKENING


10.1  Sludge Treatment

Raw sludge is normally unsuitable for disposal without prior treatment. Such treatment is
required to reduce the volume to be handled and to provide stabilization. Sludge treatment
is the most complex  and costly aspect  of wastewater treatment. Although the volume of
sludge produced is frequently  less  than one percent of the total volume of wastewater
treated, sludge  treatment  facilities  can  often account for 25 to 50 percent of the total
capital and operating costs for the entire plant (1).

      10.1.1 Sludge Treatment Processes

The processes used for sludge treatment may be grouped into the following categories:

     1.   Thickening

     2.   Stabilization

     3.   Dewatering.

The important processes included in  each of these categories are shown on Figure  10-1.

The  separation of solids  in either primary  or secondary sedimentation tanks has two
objectives. These are the recovery of a high percentage of solids from the liquid portion as
required by effluent standards,  and  the concentration of these solids to reduce the required
capacity of the sludge processing units (2). These objectives are conflicting in that highest
effluent quality is  achieved by immediate removal of settled solids, without allowing them
to accumulate in sedimentation tanks.  Although  primary  sludges can often be effectively
thickened in the sedimentation tanks, it is preferable to remove secondary sludges quickly
and provide separate  thickening units. Thickening of sludge to reduce its volume prior to
stabilization, dewatering,  and  ultimate  disposal, in fact, generally provides the highest
benefit to cost ratio of all sludge handling processes(2). This chapter is directed to various
methods of sludge thickening.

Sludge stabilization processes are used to convert raw primary and secondary  sludges to
inoffensive forms by reducing the organic  material in the sludges or by otherwise rendering
them  inert.  This is especially essential when  sludge is  to be  disposed of on land.  Sludge
dewatering characteristics may also  be improved by some methods of stabilization such as
thermal or lime conditioning. Where incineration is to be used for ultimate disposal, organic

                                        10-1

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                       FIGURE 10-1
              SLUDGE TREATMENT PROCESSES
   THICKENING
    STABILIZATION
DEWATERING
GRAVITY
THICKENING
1

3
ANAEROBIC
DIGESTION
1

3
VACUUM
FILTRATION
1
2
3
AIR
FLOTATION

2

CENTRIFUGATION

2

AEROBIC
DIGESTION

2
3
HEAT
TREATMENT

2
3
DRYING
BEDS

CENTRIFUGATION
1
2
3

1

3
NORMAL APPLICATION
               1
CHEMICAL
CONDITIONING
1
2
3
PRIMARY SLUDGE ONLY
SECONDARY SLUDGE  ONLY
COMBINED PRIMARY  AND SECONDARY SLUDGES
PRESSURE
FILTRATION
1
2
3
                           10-2

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matter is required for self-supporting  combustion and no prior organic reduction process
should be used. Sludge stabilization is considered in detail in Chapter 11.

Sludge dewatering is advantageous because it reduces the volume of sludge that will require
further processing and ultimate disposal. Where the sludge must be transported to a disposal
site, dewatering reduces the land requirements as well as handling costs. Dewatering prior to
incineration is necessary to remove excess water that otherwise would have to be removed in
the  incinerator at the expense of auxiliary  fuel.   Sludge  dewatering is the  subject of
discussion in Chapter 12.

      10.1.2  Sludge Processing Interrelationships

The various unit processes shown  on Figure 10-1 may be combined in  numerous different
sludge treatment configurations. Typical flow  diagrams for several commonly used sludge
treatment systems are shown on Figures 10-2 and 10-3. The systems have been grouped into
two general  categories,  depending  on whether or  not biological sludge stabilization is
involved. Systems using biological  stabilization  are shown on Figure 10-2 and nonbiological
systems are shown on Figure 10-3.

The selection of the individual components of a sludge treatment system must not be made
independently  of the  other components to be used. Instead, a cost-effective system of
compatible sludge thickening, stabilization, and dewatering units must be selected on the
basis of the local situation. The method to be used for ultimate disposal of the sludge after
treatment may limit the selection of a sludge treatment system for a particular application.
The alternative process units that can be considered  will depend on the type of wastewater
treatment, the sludge characteristics, and the space available for the treatment facilities.

Small plants are generally located in less densely populated areas where land availability is
not a primary constraint for either treatment facilities or ultimate sludge disposal and where
skilled operators  may be  difficult to obtain. In these instances a simple system such as is
shown on Figure 10-2(a)  may be  adequate. Stabilized sludge in this case is dried on sand
beds prior to  ultimate disposal. Plants serving populations larger than 10,000 often find
mechanical devices more  economical  for  sludge dewatering. A system using mechanical
sludge dewatering devices is shown on Figure 10-2(b). In this situation, waste activated
sludge is returned to the plant influent and the combined sludge  is concentrated in the
primary clarifier without separate thickeners. Where  separate thickening of waste activated
sludge is  desirable prior  to  stabilization,  a  system  such  as  shown  on Figure 10-2(c)  is
commonly used.

Nonbiological sludge processing systems are used mainly when:

     1.    The  nature of the sludge makes it difficult to digest.
                                         10-3

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                                        FIGURE 10-2

       TYPICAL  SLUDGE PROCESSING SYSTEMS  USING BIOLOGICAL STABILIZATION (3)
SLUDGE  FROM SMALL
BIOLOGICAL
TREATMENT PLANT W
PRIMARY SEDIMENTA
(a)
ITHOUT
TION
AEROBIC OR
ANAEROBIC
SLUDGE
DIGESTION
DIGESTED
SLUDGE


SAND BEOS
1
                                DRIED  SLUDGE TO
                                ULTIMATE DISPOSAL
                      SUPERNATANT TO
                           INFLUENT
PLANT
                                                  UNDERFLOW TO
                                                 PLANT  INFLUENT
 COMBINED WASTE
 ACTIVATED AND
 PRIMARY SLUDGE
 FROM  PRIMARY
 SEDIMENTATION
ANAEROBIC
SLUDGE
DIGESTION
DIGESTED
SLUDGE


CHEMICAL
CONDITIONING

                                                           VACUUM FILTER
                                                           OR CENTRIFUGE
                             1
                                      SLUDGE CAKE TO
                                      ULTIMATE DISPOSAL
                       SUPERNATANT TO
                       PLANT  INFLUENT
                         FILTRATE OR
                         CENTRATE TO
                        PLANT INFLUENT
u
PL
WASTE ACTIVATED
SLUDGE — ^i
PRIMARY
SLUDGE
WERFLOW TO
(NT INFLUENT
t
FLOTATION
THICKENING
\



ANAEROBIC
SLUDGE
DIGESTION
VACUUM FILTER
OR CEMTRIFUGE
DIGESTED _
SLUDGE CHEMICAL ^ \ ^
^CONDITIONING *l J
1
SLUDGE CAKE
TO ULTIMATE
DISPOSAL
1 *
1 * ' FILTRATE OR CEHTRATE
1 ! SUPERNATANT TO T0 THICKENER
PLANT INFLUENT DIHUTIUCMICMT
                  GRAVITY
                 THICKENING
                 (OPTIONAL)
                                          10-4

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               FIGURE 10-3

   TYPICAL SLUDGE PROCESSING SYSTEMS
  USING NONBIOLOGICAL STABILIZATION  (3)
                             VACUUM
                             FILTER
THICKENED
SLUDGE
(a)

HEAT
TREATMENT
r|
'
                                                SLUDGE CAKE
                                             -*. TO ULTIMATE
                                                DISPOSAL
  DECANT TO PLANT
    INFLUENT OR
SEPARATE TREATMENT
FILTRATE TO THICKENER
  OR  PLANT INFLUENT
                        VACUUM
                        FILTER
THICKENED
SLUDGE
(b)

CHEMICAL
CONDITIONING
J
*\
                   EXHAUST GASES TO
                       SCRUBDER

                          t	
                 FILTRATE  TO  THICKENER
                   OR PLANT  INFLUENT
                                          MULTIPLE-HEARTH
                                            INCINERATOR
                    ASH TO ULTIMATE
                       DISPOSAL
-


THICKENED (c) CHEMICAL 	 rrNTItinirr 	 f
SLUOGE * CONDITIONING * CENTRIFUGE *
i
CENTRATE TO
THICKENER OR
PLANT INFLUENT
EXHAUST GASE
AND ASH


FLU ID IZED
BED
INCINERATOR

IXHAUST GASES T
i SCRUBBER
t
I

CYCLONE
* SEPARATOR
SH TO ULTIMATE
                                                        DISPOSAL
                    10-5

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     2.   A  chemically  or thermally  conditioned sludge, dewatered by filtration or
         centrifugation, is acceptable  for  land disposal  and is the  most economical
         alternative.

     3.   Incineration is necessary for maximum sludge volume reduction thereby making it
         uneconomical to provide anaerobic digestion, due to the loss of caloric value.

Nonbiological systems such as shown on Figure 10-3 may be used in  these instances. Heat
treatment may be used to stabilize sludge organics prior to dewatering and ultimate disposal
as shown on Figure 10-3(a). Incineration systems such  as shown on Figures 10-3(b) and
10-3(c)  provide the highest degree of sludge volume and organic reduction. Although the
capital and operating  costs  of these units are high, the site requirements for disposing of the
residue are considerably reduced.

10.2  General Sludge Thickening Considerations

Sludge thickening is  commonly  used as the first step  in  a sludge  treatment system to
separate  more water from  the  sludge solids than can  be accomplished in the wastewater
clarifiers. This reduces  the required capacity  and increases the efficiency of subsequent
sludge stabilization and dewatering processes that have  higher unit costs than thickening.
The  processes commonly  used  to  thicken  sludge are  gravity thickening, air flotation
thickening, and centrifugation.

Gravity  thickeners  are used  extensively since  they are the most  economical method of
thickening primary sludge  or some blended primary and waste activated sludges. Gravity
thickeners are particularly applicable to smaller  installations where the thickened sludge will
be anaerobically  digested  and dried on sand beds. Although waste  activated sludge  is
difficult  to thicken, it often is effectively handled by mixing with primary solids prior to
gravity thickening. Where the weight of waste activated sludge is greater than 40 percent of
the total sludge weight, gravity thickening is not effective and separate thickening of waste
activated sludge by other methods should be considered.

Air flotation is  a  commonly  used method of  thickening for large quantities of waste
activated sludge. Under these circumstances, primary sludge can be thickened in the primary
clarifiers  or   by  separate   gravity  thickening.  Normally,  air flotation  thickening, in
conjunction with separate primary sludge thickening, will produce the highest overall sludge
concentration.

Centrifugation is  a very adaptable process capable of thickening sludges with a wide range of
characteristics. Due to  high operating, maintenance  and power requirements,  centrifugal
thickening is generally used only where spacial limitations or sludge characteristics make
other methods unsuitable.
                                         10-6

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 An important consideration in the use of any sludge processing unit is the effect of recycled
 flows that are returned to the head of the plant. The quality of the overflow from well
 operated gravity thickeners and the underflow from flotation thickeners is similar to that of
 raw wastewater (1). However, return flows from thickeners are normally of sufficiently large
 volume to result in recycled BOD and  SS loads which can adversely affect overall plant
 performance.  With centrifugal  thickening, high solids captures  must be obtained to avoid
 recycle of unsettleable fine solids to the head of the plant, which will adversely affect plant
 effluent quality.

 Thickening  is an operation that produces a more concentrated and therefore more viscous
 sludge.  The more viscous  sludge will  result in higher friction losses than water or dilute
 sludge,  so it is important that the thickened sludge pumping and piping system be designed
 to handle the  sludge throughout the range of expected solids concentrations. Because the
 consistency of the sludge may  vary  under different conditions, pumps must be able to
 operate properly  over  a wide range  of discharge pressures. The design of sludge piping
 systems is complicated  by the  need  for  both large sizes  to decrease the likelihood of
 stoppages and to  facilitate cleaning, and for high velocities to minimize the deposition of
 grease and the settling of solids in the  pipes. To minimize friction losses, sludge lines should
 be as short as possible and should contain a minimum  of bends and fittings.

 10.3  Gravity Thickening

 Gravity thickening is the most common process in use today for the concentration of sludge
 prior to digestion  and/or dewatering. Thickeners can  contribute to the upgrading of sludge
 handling facilities as follows:

     1.    Increase the  hydraulic capacity  of  overloaded digesters or  subsequent  sludge
          handling units.

     2.    Improve primary clarifier performance  by providing  continuous withdrawal of
          sludge, thereby ensuring maximum removal  of solids.

 The  process is simple and  is the least  expensive of the available thickening processes. The
 reduction in size and improvement  in efficiency of  subsequent sludge handling processes
 often can offset the cost of gravity thickening. The process also allows equalization and
 blending of sludges, thereby improving the uniformity of  feed solids to  the following
 processes. Existing gravity  thickeners  can  be  upgraded by providing continuous feed and
 drawoff, by diluting the feed solids, and by chemical addition.

      10.3.1  Process Considerations

Gravity thickening is characterized  by  zone  settling.  The  four basic settling zones in a
thickener are:

                                        10-7

-------
     1.    The clarification zone at the top containing the relatively clear supernatant.

     2.    The hindered settling zone where the suspension moves downward at a constant
          rate and a layer of settled solids begins building from the bottom of the zone.

     3.    The transition zone characterized by a decreasing solids settling rate.

     4.    The compression zone where  consolidation of sludge results  solely from liquid
          being forced upward around the solids.

To date, many attempts have been made to simulate zone settling in a batch settling test to
generate design  information which would be applicable to a continuous unit. Various
theories have been developed for analyzing batch settling data and they have been reviewed
and discussed in the literature (4) (5) (6) (7). Most of the theories assume that the settling
velocity of sludge  at a given concentration in a small batch cylinder is similar to the velocity
in prototype thickening units.  However, it has also been recognized that other parameters
are involved,  such as cylinder  depth,  cylinder diameter, mixing conditions, and  sludge
characteristics. All have a definite influence on thickening performance. The cumulative
effect of these parameters is such that when batch settling test data are used for unit sizing,
the result is an oversized unit.  For this reason, batch settling test results must be used with
caution (5). Edde  et al (6) have developed a mathematical model from batch  and full-scale
thickening data. The  model facilitates  determination  of solids loading at a given sludge
blanket depth, initial feed solids, underflow  concentration, and hydraulic loading. This
'technique is  particularly useful for determining gravity thickener design parameters when
upgrading existing wastewater treatment plants.

      10.3.2  Design Considerations

Both solids  and hydraulic  surface loadings must  be  considered when designing gravity
thickeners. Experience indicates that solids loading generally governs the design (8). Design
solids loadings and expected underflow concentrations are shown in Table 10-1.

The dry solids  ratio  of  waste activated to primary sludge governs the acceptable  solids
loading to be used in thickener design. As this ratio increases, the acceptable solids loading
decreases.

Most thickeners are operated at a hydraulic loading of 600 to 800 gpd/sq ft (9). Thickeners
with hydraulic loadings less than 400 gpd/sq ft have been found to produce odors (9). To
achieve hydraulic  loadings in the acceptable range, secondary effluent is normally blended
with the combined waste sludge before feeding the resulting uniform diluted  sludge to the
thickeners.
                                          10-8

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                                   TABLE 10-1
                      THICKENER DESIGN LOADINGS AND
                         UNDERFLOW CONCENTRATIONS

                                      Underflow
       Type of Sludge                 Concentration          Average Solids Loading
                                         %,TS                    psf/day
  Primary                                8-10                        20

  Primary and Trickling Filter              6-8                         12

  Primary and Waste Activated             3-6                          8
   (60:40 Weight Ratio)
As mentioned previously, solids loading is generally the controlling parameter and dictates
the required surface area of the thickener. For example, if a solids loading of 10 psf/day is
used for a combined primary and activated sludge and typical performance efficiencies are
desired, the calculated hydraulic loading will be in the order of 25 to 50 gpd/sq ft. Dilution
will be required to achieve the recommended 600 to 800 gpd/sq ft.

An important consideration in designing a thickener is to provide the capability to handle
peak conditions. Gravity thickeners are normally sized for average sludge production rates.
Peak sludge  production rates often are adequately handled by storage available within the
system, either in the primary tanks or the thickener itself. However, a solids balance for the
system as it  will be operated  should be determined to indicate whether supplementary
storage or additional thickener capacity is required to accommodate the peak conditions.
Sufficient storage  normally should  be available within  the  system for the maximum
three-day plant solids loading.

Most  continuous thickeners today are circular  and designed with a side water  depth of
approximately 10 feet. While  sludge  blanket depth is an important parameter, it has been
reported  that underflow  solids concentrations are independent of sludge blanket depths
greater than  3 feet (1). Increased  sludge detention time in the thickener  will result in
increased  underflow solids concentration.  A detention  period of 24 hours  has been
suggested as  the time required  to achieve maximum compaction (1). Sludge blanket depth
and detention time are closely interrelated. The sludge blanket depth may be varied with
fluctuation in solids production to achieve  good compaction. During peak conditions the
detention  time  may have  to be shortened to keep the sludge blanket  depth sufficiently
below the overflow weirs to prevent excessive solids carry-over.

The performance of a  gravity thickener depends a great deal upon the type of sludge to be
thickened. Generally, gravity thickening should not be used for thickening activated sludge
alone.
                                        10-9

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In the design of gravity thickeners, it is important that operational flexibility be provided.
Such flexibility includes  the  ability to regulate the quantity of dilution water, adequate
sludge pumping capacity  so that solids  concentrations are not limited, continuous feed and
underflow  pumping,  protection devices  against torque overload, and a sludge  blanket
detection device.

      10.3.3 Use of Gravity Thickening for Upgrading Existing Sludge Handling Facilities

Gravity thickening  is often used prior to digestion  processes. It can  also be used as a
combined  thickening  and equalization  process prior to  sludge  dewatering.  Another
application is in areas where  sludge hauling is utilized and there is a need to reduce the
volume of  sludge to be. hauled. In all cases, gravity thickening will yield higher underflow
solids  concentrations than obtainable with primary sedimentation, and the efficiency of
subsequent  digestion and  dewatering  facilities  will  improve.  Hence,  gravity thickening
should always be  considered in upgrading existing solids handling and dewatering facilities.

      10.3.4 Upgrading  Existing Gravity Thickeners

Improved thickening can be obtained by diluting the  sludges to be thickened. It has been
reported that a feed solids concentration of 0.5 to 1.0 percent is optimum and that dilution
reduces the interference between the settling particles (1).

Torpey (10) used dilution for thickening combined primary and secondary sludges  in the
development of the Densludge System. A feed sludge  concentration of less than 1 percent
produced underflow  concentrations of  11.2 and 6 percent for combined primary and
modified waste activated sludge, and combined primary and conventional waste activated
sludge, respectively.  To obtain these dilute feed  sludge concentrations,  dilution water was
pumped from the primary or secondary  clarifier and blended with the combined sludges
prior to thickening.

Thickening systems  at New York City's Tallmans Island and Bowery Bay pollution control
facilities utilize the  processes developed by  Torpey and presently obtain 4 to 6 percent
underflow  solids  concentration with a  yearly average of 4.5 percent (11). Both plants are
operating using a  combination of the step and activated aeration processes. A similar  design
with digested sludge recirculation at Bergen  County,  New Jersey, produces an underflow
concentration of  5.2 to 7.5 percent with a yearly average of 6.3 percent (12). In both cases,
the lower underflow concentrations occur during the summer months.

The improved thickening due to dilution can also be attributed to the fines that are washed
from the sludge and returned to the plant through the thickener overflow. Experiences at
Bergen County,  New Jersey, show  that, even  with  digested  sludge  recirculated to the
thickener, the overflow from the thickener  does not appreciably affect the overall BOD
removal efficiency of the  treatment plant (13).

                                        10-10

-------
 Similar experiences were reported at the Bowery Bay Pollution Control Plant. However, the
 air requirements were increased from 0.28 to 0.31 cu ft/gal. (14) by the return of thickener
 supernatant to the aeration tanks.

 Experiences with  the use of polyelectrolytes for upgrading gravity thickening have been
 reported at Amarillo, Texas (15). The original plant was designed to handle 7.5 mgd,  but
 was receiving a flow of up to 10.5 mgd. A 55-foot diameter gravity thickener was being used
 to thicken combined primary and waste activated sludge. However, bulking occurred in the
 thickener due to the overloaded conditions  and the low ratio of primary sludge to waste
 activated  sludge.  In-plant recycling  of solids resulted.  To minimize the problem, only
 activated sludge was thickened in the gravity thickener. Primary sludge was thickened in the
 primary clarifiers.  Polyelectrolyte addition was  utilized  in the thickener in an attempt to
 improve sludge blanket control and to obtain maximum  underflow solids concentration. It
 was found that  a  cationic polyelectrolyte permitted a solids loading of 4.5 to 7.0 psf/day
 while maintaining an underflow solids concentration of  2.6 percent, at a  cost of $1.10 to
 $3.64 per ton of dry solids. Polyelectrolyte was used here to successfully control the sludge
 blanket height. This practice was continued until the plant was upgraded to 12 mgd.

 For the expansion to 12 mgd at Amarillo, Texas, an existing 70-foot diameter final clarifier
 was modified  for thickening the waste activated sludge. The overflow from this thickener is
 mixed with the primary sludge to dilute the feed sludge to  the  existing primary sludge
 thickener (15). Operation of the waste activated sludge thickener showed that at a solids
 loading of 2 to 3.5 psf/day, only a 2.4 percent underflow solids  concentration could be
 obtained.   Polymer  addition  was  tried  once  again  to increase  the underflow solids
 concentration during a 142-day program, but proved unsuccessful.

 In  Chicago, the addition of polyelectrolyte  at  dosages  of less  than  10 Ib/ton dry solids
 increased  the solids loading by  two  to  four times,  but there was no  improvement in
 underflow   solids   concentration  (16).  From   these  two  examples,  it  appears  that
 polyelectrolyte addition improves solids capture  and reduces solids overflow, but has little
 or no effect on improving solids underflow concentration.

      10.3.5  Process Designs and Cost Estimates

 The following example  illustrates the use of gravity thickening before anaerobic digestion.

 Existing anaerobic digesters were experiencing  unstable operation due to  the increased
 amount of sludge  generated by an increase in plant flow from 10 to  16 mgd. Operational
 data from  the overloaded plant without gravity thickening and the upgraded plant with
thickening  are presented in Table 10-2. The volume of the combined primary and secondary
sludge was  100,000 gpd at 3 percent solids prior to upgrading. The increased sludge volume
 due  to  the plant  overloading  decreased the  detention time in the digesters from 17 to
 11.25 days.

                                        10-11

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                                   TABLE 10-2
                                  EXAMPLE OF
                  UPGRADING SLUDGE HANDLING FACILITIES
                          USING GRAVITY THICKENING

            Description                   Overloaded Plant          Upgraded Plant

  Loadings to the Anaerobic Digester

    Total Weight Primary and
      Secondary Solids                     25,100 Ib                  25,100 Ib
    Total Volume Primary and
      Secondary Sludge                   100,000 gpd (3%)        66,200 gpd (4.5%)
    Digester Hydraulic Detention Time        11.25 days                    17 days
To  improve the operation of the existing digesters, it was decided to reduce the sludge
volume  by gravity  thickening.  The  flow diagram of the upgraded  plant is shown  on
Figure 10-4. The total volume of sludge discharged to the anaerobic digestion  facility as a
result of gravity thickening was reduced from 100,000 gpd at 3 percent solids to 66,200 gpd
at 4.5 percent solids. The gravity thickener was designed using a mass loading of 10 psf/day.
A hydraulic overflow rate of 600 gpd/sq ft was achieved by recycling final effluent to the
mixing chamber ahead of the thickener as shown on Figure 10-4.

The capital costs for gravity thickening in this example are estimated  at $305,000. These
costs include one gravity thickener, a mixing chamber, effluent recycle capacity, and an
allowance for appropriate  connecting  piping.  They  do not  include the allowance for
engineering design, bonding, and construction supervision.

10.4  Air Flotation

The use of air flotation is limited primarily  to thickening of sludges prior to  dewatering.
Used in this way, the efficiency and/or capacity of the subsequent dewatering units can be
increased and the volume of supernatant from the subsequent digestion units can  be
decreased. Existing air flotation thickening units can be upgraded by the optimization of
process variables, and by the utilization of polyelectrolytes.

Air flotation thickening is best applied to thickening waste  activated sludge. With this
process, it is possible to  thicken the sludge to 6 percent, while the maximum concentration
attainable by gravity thickening without chemical addition is  2 to 3 percent  (1). The  air
flotation process can also be applied to mixtures of primary and waste activated sludge. The
greater the ratio of primary sludge to waste activated sludge, the higher the permissible

                                        10-12

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                                           FIGURE  10-4


                   UPGRADING SLUDGE HANDLING FACILITIES USING GRAVITY THICKENING
          RAW

          WASTEWATER
o
I—'
co
       THICKENER

       OVERFLOW
' PR
CLARIF
1
MIX
CHA

MARY
\
CATION! '
PRIMARY
SLUDGE
t
NG
MBER

*
AERATION
RETURN
WASTE


ACTIVATED
THICKENER D

/ GRAVITY ^
TH
i fc TD
/ FINAL \ EFFLUENT
'iCLARIF
V
SLUDGE
SLUDGE
LUTION WATER
CATION/
CKENED SLUDGE
n i CF?T i ny no

                                      THICKENER
                                                       DEWATERING

-------
solids loading to  the  flotation unit.  Due  to the high  operating costs, it is generally
recommended that air  flotation be considered only for thickening waste activated sludge
(17).

      10.4.1   Process and Design Considerations

The most commonly used  type of air flotation unit is the dissolved air pressure flotation
unit. A schematic flow diagram for a typical unit is illustrated on Figure 10-5. In this unit,
the recycled  flow is pressurized from 40 to 70 psig and  then  saturated  with air in the
pressure  tank. The  pressurized  effluent is  then  mixed with  the  influent  sludge  and
subsequently  released into the flotation tank. The excess dissolved air then separates from
solution, which  is now  under atmospheric pressure, and  the minute (average diameter
80 microns) rising gas bubbles attach themselves to particles which form the sludge blanket
(1). The  thickened blanket  is skimmed off and pumped to the downstream sludge handling
facilities while the subnatant is returned to the plant.

The following table is a summary of typical parameters  used  in the design of air flotation
thickening units.
                                    TABLE 10-3
                 TYPICAL AIR FLOTATION DESIGN PARAMETERS

                                        Without                         With
            Parameter                Polyelectrolyte                Polyelectrolyte

Air Pressure, psig                                          40-70
Effluent Recycle Ratio, percent
 of Influent Flow                                         30-150
Air to Solids Ratio, Ib air/lb  solids                           0.02
Solids Loading, psf/day                  10 (average)                      20-40
Polyelectrolyte Addition,
 Ib/ton dry solids                           0                             5-10
Solids Capture, percent                    70-90                          90-96
Total Solids, percent
  Unthickened                                          0.5-1.5
  Thickened                                              4-6
A detailed discussion of the above parameters can be found in references (1) (17) (18) (19).
                                        10-14

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                                            FIGURE  10-5


                                 SCHEMATIC OF AN AIR FLOTATION  UNIT
                                          SKIMMER MECHANISM
o
H-i
ca
            RECYCLED  _


            SUBNATANT  "
   S—BOTTOM COLLECTOR

j-A—i	i
                                                                             PRESSURE  TANK
i
             i
                                                                        J
                                                                    ^
                                                                                         AIR
                                                                                       RECYCLED    AUXILIARY
                                                                                                  "RECYCLE
                                                     NFLUENT  SLUDGE

-------
 Bench-scale flotation units have been utilized for air flotation designs, but poor correlations
 have generally been obtained with full-scale performance (17) (19). Therefore, pilot units
 usually are recommended to determine optimum recycle rates, chemical requirements, and
 general applicability of air flotation to sludge thickening.

 Typical operating data for various air flotation units are presented in Table 10-4. Combined
 primary and  activated sludge produces  a more  concentrated float  sludge  than waste
 activated sludge alone. Polyelectrolyte and/or chemical addition allows greater solids loading
 and improves solids recovery without substantially increasing the float solids concentration.
 However, the increased operating cost of the polyelectrolyte may largely offset the capital
 cost savings resulting from the reduction of thickener area.
                                    TABLE 10-4
               AIR FLOTATION THICKENING PERFORMANCE DATA
       Type of
        Sludge
Waste Activated
Waste Activatedl
Waste Activated
Waste Activated
Waste Activated
Waste Activated
Waste Activated
Combined Primary and
 Waste Activated
Combined Primary and
 Waste Activated
Combined Primary and
 Waste Activated
Solids
Loading
psf/day
12 to 18
24 to 48
13.9
7.1
19.8
26.2
28.8
Feed
Solids
percent
0.5 to 1.5
0.5 to 1.5
0.81
0.77
0.45
0.80
0.46
Float
Solids
percent
4.0 to 6.0
4.0 to 5.0
4.9
3.7
4.6
6.5
4.0
Solids
Recovery
percent
85 to 95
95 to 99
85
99
83
93
88
Reference

20
21
22
22
22
22
22
24 to 30

 21
 46.6
 40.7
1.5 to 3.0  6.0 to 8.0
  0.64

  2.30
  1.77
8.6
7.1
5.3
85 to 95

   91
   94
   88
20

22
22
22
13 to 6 Ib polyelectrolyte/ton dry solids.
                                       10-16

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       10.4.2  Process Designs and Cost Estimates

 The following example illustrates the use of prethickening by air flotation prior to anaerobic
 digestion.

 Existing anaerobic  digesters were experiencing unstable operation due to  the increased
 volume of sludge produced by an increase in plant flow from 10 to 16 mgd. Operational
 data from the overloaded and the upgraded plant is  presented in Table 10-5. Prior to
 upgrading, waste activated sludge  was recycled to the primary clarifier.  The volume of the
 combined sludge was 100,000 gpd at 3 percent solids. The increased sludge volume due to
 the plant overloading decreased the detention time  in the digesters from 17 to 11.25 days.
 To improve the operation of the existing digesters, it was necessary to reduce the sludge
 volume to increase the digester detention time. To reduce sludge volume, thickening of the
 waste activated sludge by air flotation was considered.
                                   TABLE 10-5
                                  EXAMPLE OF
                  UPGRADING SLUDGE HANDLING FACILITIES
                      USING AIR FLOTATION THICKENING

            Description                Overloaded Plant          Upgraded Plant

Primary Solids, Ib                          15,300                  15,300
Primary Sludge Volume, gpd                                        30,600 (6%)
Waste Activated Solids, Ib                   9,700                   9,700
Waste Activated Sludge Volume, gpd                                 29,100 (4%)
Combined Solids, Ib                       25,000                  25,000
Combined Sludge Volume, gpd             100,000 (3%)             59,700 (5%)
Digester Hydraulic Detention
 Time, days                               11.25                    18.8
 The flow diagram for the upgraded plant is shown on Figure 10-6. As a result of separate
 thickening of the waste activated sludge, it  is expected that the primary sludge can be
 concentrated to 6 percent in the primary clarifiers. The total volume of sludge discharged to
 the anaerobic digestion facility  due to the separate thickening of the waste activated sludge
 and the  improved  solids  concentrations in  the primary clarifier  is  expected  to be
 59,700 gpd, compared to 100,000 gpd  prior to upgrading. The air flotation system was
 designed using an air pressure of 50 psig,  an effluent recycle of 100 percent, and a solids
                                      10-17

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                          FIGURE  10-6


             UPGRADING SLUDGE HANDLING FACILITIES
                USING AIR FLOTATION  THICKENING
RAW
WASTEHATER
           PRIMARY
           CLARIFICATION
              PRIMARY
              SLUDGE
                FLOTATION
                SUBNATANT
           AERATION
FINAL
CLARIFICATION
                 RETURN SLUDGE
              AUXILIARY RECYCLE   AIR
           SLUDGE
           STORAGE
           TANK
               AIR  FLOTATION
               UNIT
THICKENED SLUDGE
                                       EFFLUENT
           WASTE ACTIVATED
           SLUDGE
                               POLYELECTROLYTE
                                        DIGESTED  SLUDGE
                                        TO DEWATERING
                               10-18

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loading of 25 psf/day. It is anticipated that the polyelectrolyte dosage requirements will be
5 Ib/ton of dry solids.

The capital costs for air flotation thickening in this example are  estimated at $183,000.
These costs include two air flotation units,  a polyelectrolyte  addition system,  and
appropriate connecting piping. They do not include an allowance for engineering design,
bonding, and construction supervision.

Where separate thickening of primary and waste activated  sludge is indicated, separate
gravity thickening of primary sludge in conjunction with air flotation thickening of waste
activated  sludge will normally provide minimum  thickening  tank  area.  The  following
example has been prepared to demonstrate this concept:
                                       Combined
                                        Gravity                          Separate
                                      Thickening                       Thickening

 Plant Flow, mgd                                               50
 Primary Sludge, Ib/day                                    60,000
 Waste Activated Sludge, Ib/day                             40,000
 Solids Loadings, psf/day
   Combined Gravity Thickening           8
   Primary Sludge Thickening                                                20
   Waste Activated Sludge Thickening                                         25
 Area Required, sq ft
   Combined Thickening                 12,500
   Primary Sludge Thickening               —                              3,000
   Waste Activated Thickening               -                              1,600
     Total                              12,500                            4,600
10.5  Centrifugation

The centrifugation process has  been successfully used for many  years in industry for
separating liquids of different density,  for  thickening slurries,  and for removing solids.
Although the potential value of centrifuges for wastewater treatment has been recognized
for quite some time, only recently have they been installed for  regular use in wastewater
treatment plants. The increasing use of centrifuges in the wastewater treatment field is the
result of recent improvements in  centrifuge design, the availability of reliable performance
data,  and the advantages of centrifuges  in certain instances over other sludge processing
facilities.
                                         10-19

-------
This discussion is limited to performance data for centrifuges used in sludge thickening and
the applicability of centrifuges for upgrading  sludge  thickening facilities.  The  types  of
centrifuges used for sludge thickening and dewatering  are discussed in Section 12.4.1 and
illustrated on Figure 12-2. The centrifuge process and design principles discussed in Sections
12.4.2  and  12.4.3  are  applicable to  both  sludge thickening and  sludge  dewatering
applications.

        10.5.1   Centrifuge Performance in Sludge Thickening

Due to high maintenance and power costs, centrifugal thickening is generally used  only
where  space limitations or  sludge  characteristics  make  other  methods  unsuitable.
Performance  data for centrifuges used to thicken various types of sludge are shown in Table
10-6.

A disc  centrifuge can  thicken waste  activated  sludge to 4 to 5 percent solids without
polyelectrolytes.  However, it is essential  that  this unit be preceded  by coarse  and fine
screening plus cyclonic grit removal to prevent clogging of the discharge nozzles.

A basket centrifuge can also  thicken waste activated sludge. It can attain 8 to 10 percent
discharge solids,  but thickens at  a much lower rate  than  a disc  centrifuge. No sludge
prescreening is required with the basket centrifuge.

A solid-bowl centrifuge can thicken waste activated sludge to 5 to 8 percent solids. The
addition of polyelectrolytes to the feed sludge significantly improves  the solids feed rate
and/or captures efficiency in this type unit.

Centrifugal thickening  of waste  activated sludge was  extensively studied at the Chicago
Sanitary District. Ettelt and Kennedy (16) evaluated  both  disc  type and solid-bowl
centrifuges. The disc-type machine concentrated the activated sludge to about 7.0 percent at
6,000 rpm, but operational problems made its use impractical. Clogging  of the sludge
discharge  nozzles  required  repeated  maintenance.  Solid-bowl  centrifuges,  processing
activated sludge alone, thickened sludge from 6.6 to 7.5 percent.

A disc centrifuge has been successfully field tested for thickening waste activated sludge at
an eastern  Pennsylvania community (26). Using a 30-inch centrifuge with a  150-hp motor
and 300-gpm feed rate, the disc centrifuge produced a 5 percent underflow with 90 percent
solids recovery. Since the plant did not have primary treatment, it was necessary to install a
screening device ahead  of the centrifuge. The screening effectiveness was demonstrated in
that the nozzles of the  centrifuge  did not plug. The combination of effective screening and
patented recirculating system (allowing  a larger nozzle size) was instrumental to the good
performance. Normally, however, disc centrifuges are  not recommended where activated
sludge treatment has not been preceded by primary treatment.
                                       10-20

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                                                  TABLE 10-6
                               CENTRIFUGAL THICKENING PERFORMANCE DATA
      Type of Sludge

Waste Activated
Waste Activated
Waste Activated
 (after Roughing Filter)
Waste Activated
 (after Roughing Filter)
Waste Activated
Waste Activated
Waste Activated
Waste Activated
Centrifuge
Type

Disc
Disc
Disc
Disc
Basket
Solid-Bowl
Solid-Bowl
Solid-Bowl



Capacity
gpm
150
400
50-80
60-270
33-70
10-12
75-100
110-160



Feed Solids
percent
0.75-1.0

0.7
0.7
0.7
1.5
0.44-0.78
0.5-0.7



Underflow
Solids
percent
5-5.5
4.0
5-7
6.1
9-10
9-13
5-7
5-8



Solids
Recovery
percent
90+
80
93-87
97-80
90-70
90
90-80
65
85
90
95
Polymer
Requirement
Ib/ton
None
None
None
None
None

None
None
<5
5-10
10-15
Reference

   23
   23

   23

   23
   23
   24
   25
   25

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       10.5.2   Use of Centrifugal Thickening for Upgrading Existing Sludge Handling
                Facilities

The performance of centrifuges in various applications clearly indicates that centrifugal
thickening should be considered when the upgrading of solids handling facilities is required.
Centrifuges are a flexible upgrading device because of their applicability in the thickening of
various mixtures of sludges.

When used as a thickening device, a centrifuge can upgrade an overloaded anaerobic digester
by  reducing the volume of feed  sludge, thereby increasing digester  detention time. In
addition, centrifuges can also be used to supplement existing overloaded gravity thickeners.

       10.5.3   Process Designs and Cost Estimates

The following example is given  to illustrate the upgrading of sludge handling facilities
through the use of centrifuges.

Existing anaerobic digestion facilities at an activated sludge plant became overloaded due to
an increase in plant flow from 10 to 16 mgd. As a result, the detention time in the digesters
was reduced to 11.25 days, thereby causing unstable operation of the digesters. Operational
data from the  overloaded and  the upgraded plant  are presented in Table 10-7. Prior to
upgrading, waste activated sludge was recycled to the primary clarifier.
                                    TABLE 10-7
                                   EXAMPLE OF
                   UPGRADING SLUDGE HANDLING FACILITIES
                        USING CENTRIFUGAL THICKENING

             Description                 Overloaded Plant          Upgraded Plant

 Primary Solids, Ib                           15,300                  15,300
 Primary Sludge Volume, gpd                                         30,600 (6%)
 Waste Activated Solids, Ib                    9,700                   9,700
 Waste Activated Sludge Volume, gpd                                  23,300 (5%)
 Combined Solids, Ib                         25,000                  25,000
 Combined Sludge Volume, gpd              100,000 (3%)             53,900 (5.6%)
 Digester Hydraulic Detention
  Time, days                                 11.25                     21
                                        10-22

-------
To upgrade the digestion facilities, it was decided to thicken the waste activated sludge by
using a disc centrifuge, as shown on  Figure 10-7. It  was decided that polyelectrolyte
addition  was not necessary. The volume  of the waste activated sludge,  69,400 gpd at
1.7 percent solids (9,700 Ib dry solids/day) before centrifugal thickening was reduced to
23,300 gpd at 5 percent solids. Combination of the thickened waste activated sludge with
30,600 gpd of 6 percent primary sludge  resulted in an increase in digester detention time to
approximately 21 days.

The capital cost for this upgrading procedure was estimated at $253,000. This cost includes
one  operating  and  one standby disc  centrifuge, in-line  screens,  sludge pumps,  and
appurtenances,  but does not include an allowance for engineering design, bonding, and
construction supervision.
                                        10-23

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                                 FIGURE  10-7
       UPGRADING SLUDGE HANDLING  USING CENTRIFUGAL THICKENING
RAW  WASTEWATER
                PRIMARY

                CLARIFICATION
      CENTRATE
      SUPERNATANT
                            PRIMARY   SCREENINGS AND  GRIT
FINAL

CLARIFICATION
                                                                    EFFLUENT
    WASTE ACTIVATED
    SLUDGE
IN-LINE
SCREENING
AND GRIT
REMOVAL
                                    SLUDGE  DEWATERING
                                    10-24

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10.6 References

 1.  Burd, R.S., A Study of Sludge Handling and Disposal. Federal Water Pollution Control
     Administration, Publication WP-20-4 (May, 1968).

 2.  Barnard, J. and Eckenfelder, W.W., Interrelationships in Sludge Separations. Included
     in Water Quality Improvement by Physical and Chemical Processes, etc., by Gloyna, E.,
     and Eckenfelder, W.W., Austin, Texas: University of Texas Press (1970).

 3.  Metcalf  &  Eddy,  Inc.,  Wastewater  Engineering:  Collection,  Treatment,  Disposal.
     McGraw-Hill, Inc. (1972).

 4.  Dick, Richard, and Ewing,  Benjamin, Evaluation of Activated Sludge Thickening
     Theories. Journal  of the Sanitary Engineering  Division,  ASCE, 93, No. 4,  pp. 9-29
     (1967).

 5.  Vesilind, Arne, Design of Prototype Thickeners from Batch Settling Curves. Water and
     Sewage Works, 115, No. 7, pp. 302-307 (1968).

 6.  Edde,  Howard,  and  Eckenfelder, W.,  Theoretical  Concept  of  Gravity  Sludge
     Thickening; Scale-Up Laboratory Units  to Prototype Design.  Journal Water Pollution
     Control Federation, 40, No. 8, pp. 1486-1498 (1968).

 7.  Dick, R.,   Thickening.  Included  in Water  Quality Improvement by Physical  and
     Chemical  Processes,  edited  by  Gloyna,   E.,  and  Eckenfelder,  W.W.,  Austin,
     Texas; University of Texas Press (1970).

 8.  Schroepfer, G.J., and Ziemke, N.R., Factors Affecting Thickening in Liquid  Solids
     Separation. National Institute  of Health,  Sanitary Engineering Report No. 156S
     (March, 1964).

 9.  Sparr, A.,  and Grippi,  V.,  Gravity Thickeners for Activated Sludge. Journal Water
     Pollution Control Federation, 41, No. 11, pp. 1886-1904 (1969).
                                  *
10.  Torpey, W.N., Concentration of Combined Primary and Activated Sludges in Separate
     Thickening  Tanks.  Journal  of the Sanitary Engineering Division, ASCE, 80,  No. 1,
     pp. 1-17 (1954).

11.  Private Communication with J.  Donnellon,  Department of Public Works, New York
     City (December 10, 1970).

12.  Zablatzky, H.R., and Baer, G.T., High Rate Digester Loadings. Journal Water Pollution
     Control Federation, 43, No. 2, pp. 268-277 (1971).

                                       10-25

-------
13. Private Communication with H. R. Zablatzky, Superintendent, Bergen County Sewer
    Authority, Little Ferry, New Jersey (December 15, 1970).

14. Torpey,  W.N., and Milbinger,  N.R.,  Reduction  of Digester  Sludge  Volume  by
    Controlled Recirculation. Journal Water  Pollution Control Federation,  39,  No. 9,
    pp. 1464-1474 (1967).

15. Jordon,  V.J.,  and  Scherer,  C.H.,  Gravity  Thickening  Techniques  at a  Water
    Reclamation  Plant.  Journal   Water  Pollution  Control   Federation,  42,
    No. 2, pp. 180-189 (1970).

16. Ettelt, G.A.,  and  Kennedy,  T., Research and Operational  Experience in Sludge
    Dewatering at Chicago. Journal Water Pollution  Control  Federation,  38,  No. 2,
    pp. 248-257 (1966).

17. Jones, Warren H., Sizing and Application of Dissolved Air Flotation Thickeners. Water
    and Sewage Works, 115, No. 11, pp. R177-178 (1968).

18. Mulbarger, M.C., and  Huffman, D., Mixed Liquor Solids Separation  by Flotation.
    Journal of the Sanitary Engineering Division, ASCE, 96, No. 4, pp. 861-871 (1970).

19. Ettelt, G.A., Activated Sludge Thickening by Dissolved Air Flotation. Proceedings —
    19th Industrial Waste Conference, Purdue University, pp. 210-244 (1964).

20. Katz, W.J., and Geinopolos, A., Sludge Thickening by Dissolved-Air Flotation. Journal
    Water Pollution Control Federation, 39, No. 6, pp. 946-958 (1967).

21. Koogler, J.B., Operational  Report of the Biddeford, Maine Sludge Disposal System.
    Peapack, New Jersey:   Komline-Sanderson Engineering Company (1966).

22. Katz, W.J., and Geinopolos, A., Concentration of Sewage Treatment Plant Sludges by
    Thickening. Proceedings — Tenth Sanitary Engineering Conference — Waste Disposal
    from Water and Wastewater Treatment  Processes, University of Illinois (February 6-7,
    1968).

23. Private Communication with George Patanaude, Philadelphia District Representative,
    Sharpies-Stokes  Division, Pennwalt Corporation, Wynnewood, Pennsylvania (October
    27, 1970).

24. Eckenfelder, W.W., Industrial Water Pollution Control. New York:  McGraw-Hill Book
    Company (1966).
                                        10-26

-------
25. Private  Communication with Gene Guidi,  Sales Manager,  Environmental  Control
    Equipment,  Bird Machine  Company,  South Walpole,  Massachusetts (February  22,
    1974).

26. Private  Communication with Laurence  Sheker, Resident Manager,  Environmental
    Equipment and Systems Division, Dorr-Oliver Incorporated, Camp Hill, Pennsylvania
    (April 22, 1970).
                                    10-27

-------

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                                    CHAPTER 11

                              SLUDGE STABILIZATION
 11.1  General

 Sludge  stabilization processes  are used to convert raw wastewater sludges to inoffensive
 forms by decreasing the organic content in the sludges or by otherwise rendering them inert.
 This is especially essential when sludge is  to be disposed of on land. The four major sludge
 stabilization  processes are  anaerobic  digestion, aerobic digestion, heat treatment and lime
 stabilization. Principal design parameters  and upgrading techniques for these processes are
 discussed in this chapter. Additional information on the design of these processes is available
 in the Process Design Manual for Sludge Treatment and Disposal (1).

 A sludge stabilization process must be viewed as an integral component of the overall sludge
 handling and treatment system. The selection and design of each of the components within
 this  system   are  interdependent.   Important   considerations  in  sludge   processing
 interrelationships are discussed in Section 10.1.2.

 11.2  Anaerobic Digestion

 Anaerobic  digestion  is  one  of the more  commonly  employed processes for  sludge
 stabilization in treatment plants over  1 mgd. The process biologically reduces the amount of
 VSS  that must be handled by subsequent  dewatering and ultimate disposal operations,
 renders the organic material nonputrescible and destroys a large number of pathogenic
 organisms.  However, since  anaerobic  digestion results in a breakdown  of coarse solids into
 finer  particles, digested  sludges  are  generally  more difficult to dewater than undigested
 sludges.  Also,  the  high alkalinity  of digested  sludges  may  require  a greater dosage of
 conditioning chemicals  than  would  be  required  with  undigested  sludges  to  achieve
 comparable performance in the dewatering process.

 The major gaseous end product of anaerobic digestion is methane, which is often used as a
 source of fuel in wastewater  treatment  plants.  The  digested sludge is an  excellent soil
 conditioner and has found some utility for this purpose.

 A major advantage associated with anaerobic digestion is its low energy requirement. Power
 consumption is much less than that required for aerobic stabilization or heat treatment. The
 methane produced is normally  more  than sufficient to generate the heat required to
maintain optimum digester temperatures and thus provides a surplus energy source that can
be used elsewhere in a wastewater treatment plant.
                                         11-1

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     11.2.1 Process Biochemistry

Anaerobic digestion of sludge is a complex biochemical process employing several groups of
anaerobic and facultative organisms. In general, the process can be considered to consist of
two steps. In the first step, facultative organisms called "acid formers" degrade the complex
organics of wastewater sludge to volatile organic acids, primarily acetic acid. In the second
step, these volatile  acids are fermented to methane and carbon dioxide by a group of strict
anaerobes called "methane bacteria."

The more important of these two phases is the methane fermentation phase because:

     1.    The only mechanism of COD or BOD removal is the production of methane. Acid
          production  only  solubilizes  the  complex  organics; it does  not  accomplish
          stabilization.

     2.    This step has been found to be the rate-limiting step in the reaction sequence.

The primary reason  why  the  methane  fermentation  step is  rate  limiting is that  the
reproduction rate for  these  organisms is  quite low relative  to  that of  other groups of
bacteria. For example, the  doubling time of the acid formers is several hours while that of
the  methane formers is, under ideal  conditions,  four  days.  Thus, even if a temporary
difficulty  in the system arose, it would be much harder for the methane organisms to adjust
than for the acid formers. In addition, it has been  found that the environmental conditions
required to maintain optimum performance by the methane organisms are much more
restrictive  than  for the acid-forming organisms.  Consequently,  most of  the effort in
upgrading existing digesters should be expended to insure that the methane fermentation
step is carried out as efficiently as possible.

Improperly functioning digestion systems  can be  upgraded by applying procedures which
will make the systems more closely approach optimum performance conditions. Therefore,
before  upgrading existing digesters, the environmental factors discussed below  should be
investigated to determine if the units are operating at their full potential.

     11.2.2 Environmental Conditions for Optimum Performance

Knowledge of the range of environmental conditions which favor optimum performance of
anaerobic  digestion is not as extensive as desired. A  summary  of the state of knowledge is
given below.
                                        11-2

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          11.2.2.1 pH

Close  pH  control is required for this process  because  methane  bacteria are extremely
sensitive to slight changes in pH. The usual pH range required is 6.6 to 7.4. In general, it is
wise to maintain the pH as close to 7.0 as possible.

In  a  properly operating anaerobic digester, pH  is maintained naturally by a bicarbonate
buffer system  due  to  the great quantity of carbon  dioxide  produced during methane
fermentation. The pH is a function of the bicarbonate alkalinity of the digesting liquor and
the fraction of €62 in the digester gas. Figure 11-1 prepared by McCarty (2) illustrates this
relationship.  Because of the significance  of pH control in  digester  operation, it is  most
important  that the dynamic nature of  buffer destruction and formation in the digester be
understood. This process is reviewed in the following equations for  simple carbohydrates
such as glucose. The equations mentioned are equally applicable to digestion of sludge.

         „          acid formers
         C6H1206	*- 3 CH3COOH

         3 CH3COOH + 3 NH4HC03	^3 CH3COONH4 + 3 H20 + 3 CO2
         o  /^TT ^^^IVTTT    r,TT  ^  methane bacteria
         3  CH3COONH4 + 3H20	^ 3 CH4 + 3 NH4HC03

The first equation represents  the breakdown of glucose to acetic  acid by acid-forming
bacteria. The acid is neutralized, as  shown in the second equation,  by the biocarbonate
buffer. If sufficient buffer is not present, the pH would drop, and the conversion of acetate
to methane, as  shown in the third equation, would be inhibited. During the third reaction,
the buffer consumed  in the second reaction is reformed.

A dynamic equilibrium  between buffer formation and destruction is  maintained when the
process is  proceeding  satisfactorily. However,  when  an upset occurs, it  is usually the
methane bacteria rather than the acid formers which are adversely affected. Therefore, net
buffer consumption takes place, and the process is in danger of pH failure. When this occurs,
an external source of alkalinity such as lime must  be added to maintain the pH in the proper
range.

Figure 11-1 indicates that the bicarbonate alkalinity should be maintained at a minimum
level of 1,000 mg/1 as CaCO3 to ensure adequate pH control. To determine the bicarbonate
alkalinity, both the volatile acid concentration and the total alkalinity  must be measured.
Then,

         Bicarbonate Alkalinity = Total Alkalinity - 0.8 Volatile Acids

The 0.8 factor in the above equation is required to convert the volatile acid units from mg/1
as acetic acid to mg/1  as CaCO3 the equivalent alkalinity unit.

                                         11-3

-------
                            FIGURE 11-1

    RELATIONSHIP BETWEEN pH AND BICARBONATE CONCENTRATION
GO
«c
C3
   50
   40
   30 -
 CNl

°  20
   10 —
250
500
                                             I
                                   2500      5000    10,000

                         HCO: CONCENTRATION,  MG/L AS CaC03
                            J
25,000
                                11-4

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It should be noted that in the second and third equations, ammonium bicarbonate was used
as the form of the alkalinity. This represents the situation in wastewater sludge digestion
where large concentrations of ammonium result from the destruction of protein. In fact, the
maximum value of the total alkalinity is set by the concentration of the ammonium ion.
The carbon dioxide generated in the methane fermentation will not form negatively-charged
bicarbonate (the buffer) unless an equivalent quantity of  cation is present. This is provided
by the destruction of natural protein with the release of positively-charged ammonium. If a
cation is not  present to force formation of bicarbonate buffer, self-regulation of pH in the
digestion process is not possible. In this case, alkaline material must be added continuously
to control the pH. For example, the anaerobic degradation of glucose, illustrated in the first
three  equations, would require  the addition of an external source of alkalinity. It is not
necessary that ammonium bicarbonate be utilized for this purpose; in fact, in terms of cost
and avoidance of potential toxicity, another bicarbonate salt might be favored.

In general, this difficulty  will  not be experienced in  wastewater  sludge digestion unless
either a high carbohydrate fraction from an industrial waste is present in the sludge or a very
thin sludge is being treated.

         11.2.2.2  Temperature

The  temperature response  of methane bacteria is the  same  as  other  bacterial  groups.
Although thermophilic  methane bacteria exist, it is generally not economically feasible  to
heat sludge to this temperature range. Thus,  digestion  of wastewater sludge is conducted in
the mesophilic range. The optimum temperature in this range is 35 deg C (95 deg F). More
important  than maintenance  of a particular temperature  is maintenance  of the chosen
temperature at a constant level. A temperature change of 1 or 2 deg C is sufficient to disturb
the dynamic balance between the acid formers and the methane formers. This will lead to an
upset because the acid formers will respond much more rapidly to  changes in temperature
than will the methane bacteria. When heat exchangers are used to upgrade the performance
of existing digesters, care must be exercised  to avoid wide temperature  variations and
excessive temperature in the heat exchanger itself.

         11.2.2.3  Nutrients

Speece  and McCarty  (3) have done the most  definitive work  on the macro-nutrient and
micro-nutrient  requirements of  methane  bacteria. As these  authors  indicate, domestic
wastewater appears to contain all of the nutrients required by  these organisms. However,
due  to the  uncertainty of the precise  nutritional requirements  of  methane bacteria,
difficulty may be encountered in digestion when a considerable fraction of the wastewater is
of industrial origin.
                                          11-5

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         11.2.2.4  Toxic Materials

Substances  which may be present in municipal sludges in concentration ranges which can
produce toxicity include heavy metals, sulfides, surface-active agents,  light metals, and
certain organics. All of these can gain entrance to wastewater sludge from industrial sources.
In addition, light metal cations will enter sludge if an alkaline material is added to control
the pH. Several papers (4) (5) (6) review the best engineering data available on toxicity.
Reference should be made to these papers for complete information. General information
on some substances is shown in Table 11-1.
                                   TABLE 11-1
           CONCENTRATIONS WHICH WILL CAUSE A TOXIC SITUATION
               IN ANAEROBIC DIGESTION OF MUNICIPAL SLUDGES

              Substance                                       Concentration
                                                                  mg/1

            Sulfides                                             200
            Heavy Metals 1                                        > 1
            Sodium                                           5,000- 8,000
            Potassium                                          4,000 - 10,000
            Calcium                                           2,000- 6,000
            Magnesium                                         1,200 - 3,500
            Ammonium                                        1,700- 4,000
            Free Ammonia                                       150
            1 Soluble.
It must be emphasized that the values in this table are only guides. If toxicity is suspected, a
thorough  analysis  of all the chemical constituents of the sludge must be made before
definite conclusions  can be drawn.  Potential solutions to toxicity problems, other than
elimination from the wastewater, should be evaluated in small-scale digesters of the type
used in laboratory investigations.

     11.2.3  Anaerobic  Digestion Systems

Prior to a discussion of procedures for  upgrading the performance of anaerobic digestion
systems, a description of typical  anaerobic digestion systems will be presented. Figure 11-2
illustrates the two types of digestion systems in use at present.

                                       11-6

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              FIGURE 11-2

    ANAEROBIC DIGESTION SYSTEMS

             GAS WITHDRAWAL
                     iti
INLET
                      LAYERx
                 SUPERNATANT
                 ACTIVE LAYER
                  STABILIZED
                   SOLIDS
                   REMOVAL

             LOW-RATE DIGESTER
                 GAS WITHDRAWAL
  INLET —»r:
                      OUTLET

               HIGH-RATE  DIGESTER
                                       OUTLET
                      11-7

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In a low-rate system, the tank is not mixed and, in some cases, is not heated. Sludge is added
at the top and withdrawn at the bottom. Stratification develops in the system due to a lack
of mixing.  In general, this  can be classified as a plug-flow system. Because of the lack of
mixing and consequent  stratification, much of the  digester  volume is wasted, and many
operational problems result. In this type of digester, acidification sometimes takes place in
the top and middle layers while methane fermentation is confined to the lower layers. This
can lead to areas of low and high pH  in the system,  which restrict optimum  biological
activity. Also, chemicals added for pH control are not dispersed throughout the tank, and
their effectiveness is limited. Grease breakdown is poor because the grease tends to float to
the top of the digester while the methane bacteria are confined to the lower levels. Methane
bacteria are removed with the  digested sludge and are not recycled to the top, where they
are required.  During progression from top  to  bottom of the digestion tank, the sludge is
compressed and gradually dewatered.

The high-rate system differs from the low-rate  system in that the contents are well mixed,
either continuously or intermittently, and the digester is heated. This procedure avoids most
of the difficulties inherent  in low-rate systems. Consequently, this system operates well at
lower HRT values and higher organic loading rates. Table 11-2 compares design criteria for
low-rate and high-rate digesters.

                                   TABLE 11-2
                 TYPICAL DESIGN  CRITERIA FOR LOW-RATE AND
                       HIGH-RATE ANAEROBIC DIGESTERS

                Parameter                      Low-Rate          High-Rate

  Hydraulic Retention Time (HRT), days          30 to 60           15 to 20
  VSS Solids Loading, pcf/day                 0.04 to 0.1         0.15 to 0.30

  Volume Criteria, cu ft/capita
    Primary Sludge                              2 to 3          1-1/3 to 2
    Primary Sludge + Trickling Filter Sludge        4 to 5          2-2/3 to 3-1/3
    Primary Sludge + Waste Activated Sludge       4 to 6          2-2/3 to 4
 Various mixing systems have been successfully utilized in digesters. These include:

     1.   Single  or multiple draft tubes through which sludge is circulated by a turbine
          mixer set in the tube

     2.   Digester gas recirculation through diffusers in the base of the digester or drop
          pipes.

                                        11-8

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Specific  design  information  for  these  systems  can  be  obtained  from  the  various
manufacturers.

Sludge  heating is accomplished either (1) by circulating hot water through coils mounted on
the inner wall of the digestion tank, (2) by a heat exchanger furnished as part of the mixer
draft tube  or  (3) by  circulating  sludge through an  external heat exchanger.  The latter
method is preferred since it has been found that the coils inside the digestion tank are easily
caked with  partially dried sludge. The sludge circulation rate to the external heat exchanger
depends on the efficiency of the heat exchanger and the temperature differential. Design of
a high-rate  digestion system must include  a heat  balance to determine fuel requirements.
The WPCF  Manual of Practice No. 8 (7) presents in detail the procedure for making such a
heat balance. This discussion includes valuable data on the fuel value of sludge gas and the
insulation characteristics of typical digester construction materials.

One difficulty with high-rate digestion  is that the sludge leaving  the digester is thinner than
the incoming sludge due to solids destruction. Secondary digesters are normally added to
many  high-rate  digestion systems to  concentrate the  sludge  and  provide supernatant
separation.  These units are designed primarily as settling tanks, but also provide a source of
seed sludge  in case of digester upset, and sludge storage where intermittent withdrawals for
dewatering  or drying  are  made.  If suitably equipped, they can also serve as  standby
digesters.

     11.2.4  Upgrading Existing Anaerobic Digestion Facilities

The first step in upgrading a  digester is  to evaluate process performance.  This can be
accomplished with the  aid of such tests as volatile acids and alkalinity and by a digester gas
analysis. Any sudden rise of volatile acids  indicates that the system is out of biochemical
balance. A  rise  in the  CC>2  fraction in the gas  or  a  decrease in methane production per
pound of volatile solids added  will also indicate upset. However, the volatile acid test is
more sensitive. When an upset occurs,  an alkaline  material must be added to maintain the
bicarbonate alkalinity above 1,000 mg/1 as CaCO%. An easily soluble bicarbonate salt, such
as NaHCO3, is best for this purpose. Care must be exercised not to exceed the level at which
the cation  of the alkaline material will cause toxicity. If this is a potential problem, a
mixture of alkaline salts should be used. Kugelman and McCarty (5) have described methods
of preventing cation toxicity by  adding  appropriate quantities of cation antagonists.

Control of pH during an upset is only a temporary measure. The  cause of the upset must be
located  and eliminated. Sometimes this is easy.  For example, heavy-metal toxicity can be
completely  eliminated by  precipitation of  the metal  in the digester as the sulfide (8). In
other cases,  only exclusion of the toxin  from the system will suffice.
                                         11-9

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The major upgrading technique for low-rate digesters is conversion to high-rate digestion. To
maintain high-rate digestion, the following conditions are necessary:

     1.    Solids thickening to increase volatile solids loading and HRT

     2.    Complete mixing of digester contents

     3.    Uniform solids feed and withdrawal

     4.    Temperature control system  capable of maintaining a uniform temperature at a
          point within the range of 30 to 35 deg C

     5.    An average HRT of at least  15 days.

The  principal techniques used  for upgrading high-rate digesters are to increase feed solids
concentration, to provide a  secondary  digester for  liquid-solids separation and to increase
HRT.

The relationship between thickening  of solids, HRT and solids loading has been illustrated
by Sawyer (9) and is shown  on Figure  11-3. This relationship points out the importance of
thickening the  solids  prior  to  digestion. Sludge  thickening  is discussed in Chapter 10.
Sections 10.3.5,  10.4.2  and  10.5.3 illustrate how the solids loading capacity of anaerobic
digesters can be increased by  implementing sludge thickening techniques.

There are restrictions on the  degree to which raw sludge can be thickened. These include the
difficulty of pumping thick sludge and  the maintenance of adequate mixing in the digester.
Generally, sludge need  not  be thickened beyond  about eight percent solids to optimize
digester volume  utilization. If it is desired to thicken beyond this point, adequate studies of
the sludge flow  characteristics  must be  made to evaluate pumping and mixing requirements.

The addition  of digester mixing by itself can have a significant beneficial effect on digester
performance.  At the City of Pontiac, Michigan (10), modifications were made to an existing
digester  by  adding a gas recirculation unit to improve mixing. Mixing inhibited scum
formation, improved heat transfer and provided a more stable digestion process. Many other
communities have had similar success  (11).

Experiences at Chicago (12) have shown that digesters can be  upgraded to operate at VSS
loadings of 0.2 pcf/day  and  at an HRT of 10 days. Complete mixing is necessary to operate
under these loading conditions.

Bergen County, New Jersey, is the best reported example of upgrading low-rate digesters to
high-rate digesters (13).  In 1951, a 20 mgd activated sludge plant was constructed with four
1.3-million gallon digesters.  In 1961, the capacity of the plant was increased to 50 mgd, and

                                        11-10

-------
                     FIGURE  11-3

RELATIONSHIPS BETWEEN SLUDGE SOLIDS DIGESTER LOADINGS,
                 AND DETENTION TIME (9)
     CO
     CO
        .40
        .35
        .30
        .25
        .20
        . 15
        . 10
        .05
                          11-11

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the existing digesters were modified to high rate. In 1969, additional studies were conducted
on  a full-scale  basis, and it was found that two of the original digesters could handle the
entire loading from the  existing 50 mgd activated sludge plant. On this basis, it has been
projected that the original four digesters will be able to handle the increased solids loading
when the plant is expanded to 75 mgd. It is significant  to note that even at  these higher
loadings, the anaerobic process was very stable and  the efficiency of the process remained
the same.

Successful upgrading of existing digestion facilities at Bergen County was accomplished by
the following methods:

     1.    Completely mixing the digester contents

     2.    Prethickening the primary  and secondary sludge to  an average concentration of
          6.3 percent (range 5.2 to 7.5 percent)

     3.    Increasing the  applied solids loading from 0.22 pcf/day to 0.5 pcf/day as a result
          of thickening

     4.    Decreasing the HRT from 22 to 10 days.

The loading to two-stage high-rate digestion systems may be increased by recirculating the
concentrated digested sludge from the secondary stage back to the primary stage, since this
effectively increases the SRT at the same digester HRT. As with activated  sludge systems,
the limiting factor is the solids-liquid phase separation. Perhaps a degasification process can
be  included between the primary and secondary tanks to aid in the separation, as is done
with the anaerobic contact process (14). When satisfactory phase separation is obtained in
the secondary  digester, adequate SRT's can be maintained while decreasing HRT's to less
than 10 days (15). A more stable digestion process then results,  due to higher populations of
methane bacteria  in the primary stage and to  the  lessening of toxicity effects at longer
SRT's.

Digesters can also  be upgraded by recirculating a portion of the digested sludge back to the
thickening units and mixing it with the incoming combined  sludge and effluent recycle
water. This procedure  has been reported  by Torpey and  Melbinger (16) with  modified
aeration  plants in  New  York City, and was originally adopted to improve  the pumping
characteristics  of  highly  concentrated digester  feed sludge of 10 to  14 percent  solids. It
appears  that  the  thickening  process  was improved because  the digested sludge  was
incorporated into  the pore spaces of the mixed primary and waste activated sludge, thereby
eliminating the typical gel structure produced by grease in the raw sludge. It was also found
that recycling  digested  sludge improved digester performance due to the seeding of the
combined sludge  prior to digestion  and because of the greater SRT thereby  afforded.
Volatile  solids  reduction  was  also  increased.  A digested  sludge  recycle of 50 percent

                                         11-12

-------
appeared to be optimum for the  New York City plants, and a net volume reduction of
digested sludge from 197 cu ft/million gallons to 112 cu ft/million gallons was achieved.

It must be pointed out that conversion to high-rate digestion is not a cure-all, especially if
digested sludge is to be dewatered prior to final disposal. Methane production and volatile
solids reductions are approximately the same at high rate as at low rate, but indications are
that supernatant separation and dewatering of high-rate sludge are difficult (17). To obviate
this difficulty,  Sawyer (9)  has  suggested that  secondary digesters in high-rate  digestion
systems be  two to four  times the  capacity of high-rate primary digesters, to provide
adequate time for solids separation and conditioning. This technique has been reported at
Grand Rapids, Michigan (18), where the volatile solids loading to  the primary digester is in
excess of 0.25 pcf/day. The ratio between secondary and primary digester capacity is 3.5:1.
In this case, secondary digester underflow solids exceed 10 percent and  supernatant solids
average less than 2 percent of the raw solids load. This indicates that  the economics of
decreasing the detention time in the primary digesters should be weighed against providing
the additional capacity in the secondary digesters when solids dewatering is required.

     11.2.5  Anaerobic Digester Supernatant

Anaerobic digester supernatant constitutes a high strength recycle flow, as indicated by
Table 11-3. It imposes a significant  incremental organic  loading on biological treatment
processes. Separate supernatant treatment may be  necessary in  cases where  available
treatment capacity is limited.
                                  TABLE 11-3
                     TYPICAL PROPERTIES OF ANAEROBIC
                         DIGESTER SUPERNATANT (19)

               Parameter                     Low Rate           High Rate
                                               mg/1                rcig/1

          Total Solids                      4,000 - 5,000      10,000 - 14,000
          SS                               2,000 - 3,000       4,000 -  6,000
          BOD                            2,000 - 3,500       6,000 -  9,000
          VSS                               650-3,000       2,400-  3,800
          Alkalinity (MO)                  1,000 - 2,400       1,900 -  2,700
          H2S                                70-90            190-  440
          NH3-N                            240-560           560-  620
          PH                                 7.0-7.6            6.4-  7.2
                                       11-13

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     11.2.6  Impact of Alum and Iron Phosphorus Sludges on Anaerobic Digestion

The addition of alum or ferric chloride for phosphorus removal during biological treatment
substantially increases the weight of the solids generated by the treatment process (20) (21)
(22). However, in most instances, due to a higher sludge density, the volume of secondary
sludge  after chemical addition does not increase in the same proportion. If the chemical is
added  in the primary clarifier, the primary sludge concentration may be decreased. Piping,
pumping and process units should be sufficient in size and number to handle the change in
weight and/or volumes of sludges that result from  chemical addition to either primary or
secondary treatment processes.

Many studies have indicated that neither ferric chlorine nor alum phosphorus sludges inhibit
anaerobic digestion  (20) (21) (22) (23) (24). However, digester performance may be altered
due to changes in physical sludge characteristics or  feed sludge alkalinity. Studies have also
indicated that  chemically  bound  phosphorus is not released to the  supernatant in the
anaerobic digestion process (20) (24) (25).

At Chapel Hill, North Carolina (26), it was reported that digester alkalinity was reduced in
the primary digester from 2,500 mg/1 to 1,500 mg/1 as CaCO3 after addition of alum to one
of two parallel trains (see Chapter 4),  resulting in a need to add lime on one occasion.
Further, the secondary  digester underflow concentration decreased from a normal  range of
6 to 7 percent to 3.8 percent with a coincident increase in the supernatant SS concentration
from  1,000 mg/1 to  10,000 mg/1. In spite of these difficulties, the digestion process  itself
produced a normal reduction in VSS throughout the entire alum treatment study.

     11.2.7   Process Design and Cost Estimates

The following example  illustrates the upgrading of a two-stage low-rate digestion facility to
a two-stage high-rate digestion system. This was required due  to the increase in plant flow
from   1  to  3 mgd.  A  gravity thickener was added  prior to digestion. Primary  digester
performance was improved by adding gas mixing and installing external heat exchangers to
control the  temperature more accurately. The comparison between existing and upgraded
design conditions is presented in Table 11-4. The flow  diagram  of the upgraded  plant is
shown on Figure 11-4.

A mixing chamber ensures proper blending of sludges and effluent water prior to thickening.
With  thickening, the solids concentration and  the volatile solids loading  to the  primary
digester were increased from 2 to 5 percent and from 0.036 to 0.108 pcf/day, respectively.
Provision was  made for  recirculating  digested  sludge back to the thickener at a rate of
50 percent of the raw sludge feed.
                                         11-14

-------
                                                 TABLE 11-4
                        UPGRADING AN EXISTING LOW-RATE DIGESTION SYSTEM USING
                               PRETHICKENING OF THE COMBINED SLUDGE AND
                                 IMPROVEMENTS TO THE PRIMARY DIGESTER
               Parameter
Plant Flow, mgd

Combined Sludge Characteristics
  Volume, gpd
  Solids Contribution, Ib/day
  VSS, percent

Gravity Thickener
  Number
  Solids Loading, psf/day
  Effluent Water Required to Dilute Sludge, gpd
  Hydraulic Loading, gpd/sq ft
  Thickened Sludge Volume, gpd

Digester
  Number - Primary Digesters
  Number - Secondary Digesters
  Primary Digester Characteristics
  Secondary Digester Characteristics

  Digester Volume (Total), cu ft
  Hydraulic Retention Time, days (Total)
                         days (Primary)
  VSS Loading, pcf/day (Primary)
     Original Design

           1
       9,100 (2%)
       1,530
          70
           1
           1
Limited heating and mixing
No heating or mixing

      60,000
      49.4
      24.7
       0.036
        Upgraded Design

               3
           27,300 (2%)
            4,590
               70
                                             1
                                             10
                                        248,100
                                           600
                                         10,920 (5%)
               I
               1
New gas mixing and improved heating
No heating or mixing

           60,000
           41.0
           20.5
            0.108

-------
                              FIGURE  11-^
           UPGRADING AN EXISTING  LOW-RATE DIGESTION SYSTEM
             USING PRE-THICKENING OF  THE COMBINED SLUDGE
              AND IMPROVEMENTS TO THE PRIM ARY DIGESTER
RAW
*ATER w PRIMARY
THICKENER SUPERNATANTJ
k CLARIFIER
1
	 ^ Ml)
i CHM
i 	
« C3
•«t CD
r gf ^
JNG f1
KBER L
	 1^ 	
^ AERATION

-------
The capital cost of this upgrading was estimated at $137,000, allocated as follows:

         Thickener                                      $  74,000
         Digester Renovation                              63,000
                Total                                   $137,000

11.3  Aerobic Digestion

Aerobic digestion can be applied to the stabilization of primary sludges or combinations of
primary and secondary sludges. It has been indicated that aerobic digestion is competitive
with anaerobic  digestion for activated sludge plants up to  a size of at least 8 mgd  (27).
Fewer  operational problems  are associated with aerobic  digestion than with anaerobic
digestion.  Hence, less laboratory control  and daily  maintenance are required. Also, the
dangers of  gas explosions  are eliminated because the  only  gaseous byproducts of aerobic
digestion are carbon dioxide and water vapor.

Typical concentrations of various  constituents  present in aerobic digester supernatant
liquors are  listed in Table 11-5. Compared to anaerobic digester supernatant, the recycle
stream from aerobic  digesters  is relatively innocuous. The  recycled SS, although high in
concentration, consists of stabilized solids which can be effectively removed in  primary
settling and would have  little impact  on biological  processes. The true organic  loading,
attributable to this recycle, is represented by the soluble BOD and is similar in strength to
primary effluent.

                                  TABLE 11-5
                      TYPICAL PROPERTIES OF AEROBIC
                            DIGESTER  SUPERNATANT

    Parameter                Average              Range            Reference
                               mg/1                mg/1

  SS                           3,400             46 - 11,500              28
  BOD                          500              9-  1,700              28
  Soluble BOD                    51              4-  183                23
  COD                          2,600           228- 8,140              28
  Alkalinty                        -            473 - 514                29
  KjeldahlN                     170             10- 400                28
  Total P                         98             19- 241                28
  Soluble P                        26           2.5- 64                  28
  pH                             7.0           5.9- 7.7                 28

                                      11-17

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     11.3.1   Process Considerations

Aerobic digestion is accomplished by aerating sludge until it is stable and relatively nuisance
free. In the aerobic digestion of sludges, two  different forms of oxidation take place, as
shown in the following two reactions. First, a portion of the organic substrate in the sludge
is oxidized and the remainder is converted to cellular matter. Second, the cellular matter
produced is oxidized until only a relatively inert fraction remains.

          (1)  organic  matter  +  C>2 - ^-cellular matter + CC>2 +

          (2)  cellular  matter  +  02 - *- digested  sludge + CO2 +

The first reaction,  biological oxidation, is  most significant in the  stabilization of sludges
with  a high fraction   of  primary  sludge.  The second reaction, endogenous  respiration,
predominates in the aerobic stabilization of waste activated sludge or trickling filter humus.
Since  biological oxidation  requires a higher  oxygen transfer  rate  than  endogenous
respiration,  more air dissolution capacity must be provided for the  stabilization of sludges
containing significant quantities of primary sludge.

Both pH  and  alkalinity are reduced in   a properly functioning  aerobic  digester when
nitrification takes place. Nitrification lowers pH according to the following reaction:
                  1.5 02                » N02-  + 2H+ + H20

The second step of nitrification is as follows:

              -    0.5 Q    Nitrobacter
Theoretically, 7.1 Ib of CaCO3 alkalinity are destroyed per pound of ammonia nitrogen
oxidized, since the two protons released neutralize  one mole of CaCO.3 according to the
following reaction:

          2H+ + CaC03 - «-H2CO3 + Ca2+
In batch-type aerobic digestion, it is possible that the pH may drop to a rather low value
(5.5±) at increased detention times. However, this does not seem to inhibit the process (30).

Batch-type  aerobic  digestion  operating  data  shown  in  Table  11-6  indicate process
performance and the relationship between ammonia,  nitrite, and nitrate  nitrogen as a
function of detention time. Table 11-6 also indicates that in the normal temperature range
of 15 to 35 deg C, an increase in temperature increases the rate of VSS reduction.
                                         11-18

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Detention
  Time
  days

   5
  10
  30
  60
                                   TABLE 11-6
                   BATCH-TYPE AEROBIC SLUDGE DIGESTION
                OPERATING DATA FOR MIXTURES OF PRIMARY
                      AND WASTE ACTIVATED SLUDGE (31)
Temperature
   degC

    15
    15
    15
    15
   vss
Reduction
  percent

   21
   32
   40.5
   46
pJL
7.6
7.6
6.6
4.6
Alkalinity
  mg/1

 510
 380
  81
  23
54
3.2
4.0
38
Trace
1.28
0.36
0.23
None
64
170
835
   5
  10
  15
  30
  60

   5
  10
    20
    20
    20
    20
    20

    35
    35
24
41
43
44
46
7.6
7.6
7.8
5.4
5.1
590
390
560
31
35
   26
   45
7.9
8.0
 630
 540
54
4.9
7.0
28
7.0
Trace
0.59
2.27
0.19
0.51
None
60
29
275
700
14
10.0
0.18
0.08
None
None
Pure oxygen  rather than air may be used in the aerobic digestion process. Because air
contains only about 20 percent oxygen, the oxygen solubility in a system using air is only
1/5 that  obtained when  using pure oxygen. Consequently, pure oxygen  may be used to
stabilize thicker sludges in which the high oxygen uptake rates cannot be  satisfied with air
aeration.

A three-month plant scale study of aerobic digestion using pure oxygen in a covered system
was conducted at Speedway, Indiana (32). Aeration was accomplished in a covered 31,000
cu ft, four-stage reactor  followed  by a clarifier for decanting the  sludge. The study was
divided into two phases, the first treating only waste  activated  sludge and the second
treating mixed primary and waste activated sludge. Much of the heat generated by biological
oxidation was retained within the covered system. This resulted in  a significant increase in
sludge temperature and a corresponding increase in the rate of VSS  destruction. The results
of this study are shown  in Table 11-7. A positive DO level of 2 mg/1 was required for the
process to function well.
                                       11-19

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                                   TABLE 11-7
            RESULTS OF HIGH-PURITY OXYGEN AEROBIC DIGESTION
                            SPEEDWAY, INDIANA (32)
              Parameter                         Phase 1

Feed Sludge Type                                 WAS*
Feed TSS, percent                                 2.14
VSS/TSS                                         0.77
Biodegradable VSS/TSS                            0.45
Feed Temperature, deg C                         19.5
Average Ambient Air Temperature, deg C            7.5
Sludge Temperature - Stage 4, deg C               33.0
HRT, days                                       16.3
Volatile Solids Loading Rate, pcf/day                0.064
VSS Reduction, percent                           44
Biodegradable VSS  Reduction, percent             94.6

1 Waste Activated Sludge.
2 Primary Sludge.
       Phase 2

57% WAS + 43% PSL2
        3.06
        0.66
        0.48
       16.0
      -2.2
       31.0
       11.6
        0.109
       43
       89.6
Batch tests were conducted at the Metropolitan Denver Plant on a pure oxygen aerobic
digestion system using open tanks and a special oxygen diffuser system producing extremely
fine bubbles (33).  These  tests indicated  that a 40 to 60 percent reduction in VSS can be
obtained with an HRT of ten days, when digesting waste activated sludge.

The overall cost effectiveness of using high-purity oxygen for aerobic digestion is greatly
enhanced if the wastewater treatment plant employs the high-purity oxygen activated sludge
process.

     11.3.2 Design Basis

There are two methods of operating aerobic digestion tanks. One is on a continuous basis,
and the other is on an intermittent batch basis. The latter method is used most frequently in
smaller plants. Continuous digester operation requires provision for continuously decanting
the supernatant, but offers the  advantages of equalizing air requirements and providing a
slow continuous supernatant return. In the batch operation, the sludge is supplied with air
in a completely mixed tank for a protracted period, followed by quiescent settling and
                                       11-20

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decantation as  new sludge is admitted. However, care must be  taken in cold climates to
avoid creating a slush at prolonged detentions and subfreezing air temperatures.

In designing an aerobic digestion system, the characteristics of the raw sludge must be fully
identified.  This can best be done with pilot plant studies. A small (55-gallon) aerobic
digestion pilot plant can be used for this purpose. Through such studies, the detention time,
oxygen requirements and optimum VSS reduction can be determined. Mathematical models
analyzing aerobic digestion kinetics have been reported by Reynolds (34) and by Smith, et
al (35).

Table 11-8 contains a summary of parameters used in the design of aerobic digestion units
for municipal wastewater sludges. When considering aeration requirements, recognition must
be given to the oxygen demand of the ammonia nitrogen present.

     11.3.3 Use of Aerobic Digestion for Upgrading Sludge Handling Facilities

          11.3.3.1  Use of Existing Facilities

As  an upgrading technique, aerobic digestion can be carried out in existing unused tankage,
such  as old Imhoff tanks or old clarifiers. If  unusually  shaped basins are used, attention
should be placed on ensuring that complete mixing will be achieved and that dead spots will
be  eliminated.  Potential dead spots can be filled and covered with concrete. Air-diffusion
systems are more easily adapted to unusual basin shapes than are surface aerators.

          11.3.3.2  Supplemental Aerobic  Digestion

Aerobic digestion can  be used in conjunction with existing anaerobic digesters. In Monroe,
Wisconsin, and Corpus Christi,  Texas, it has been found best to digest the primary sludge
anaerobically and  the waste  biological  sludge  aerobically (36). The advantage of  this
segregation is that the primary sludge is not diluted by the waste biological  sludge and the
anaerobically digested primary sludge subsequently filters better on a vacuum filter when it
does not contain the waste biological sludge.

          11.3.3.3  Conversion of Anaerobic Digesters to Aerobic Digesters

If existing anaerobic digesters  are  overloaded  and for some reason cannot be upgraded as
described in Section 11.2, they can be converted to aerobic digesters. Aerobic digesters yield
similar  VSS reductions  and  are relatively odor free.  Hence, this conversion may be
applicable  to small overloaded  plants  in  residential areas. Aerobic digestion will usually
require an increase  in  the  blower capacity  of the  air supply  system,  which would
significantly  increase the yearly operating cost. However, these increased costs  could be
offset by  savings in  maintenance  requirements.  An alternative method of supplying the
additional air is by using mechanical surface aerators where tank geometry permits.

                                         11-21

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                                             TABLE  11-8
                 AEROBIC DIGESTION DESIGN PARAMETERS USING AIR
           Parameter

Solids Retention Time


Volume Allowance, cu ft/capita

VSS Loading, pcf/day

Air Requirements
  Diffuser System, cfm/1,000 cu ft

                 cfm/l,000cuft

  Mechanical System, hp/1,000 cu ft
Minimum DO, mg/1

Temperature, deg C
VSS Reduction, percent

Tank Design
Power Requirement, BHP/10,000
  Population Equivalent

Power Cost
  $/yr/lb BOD Removed
  $/yr/Capita
   Value

   10-151
   15-202

    3-4

0.024-0.14


   20-351

   >602

  1.0-1.25
  1.0-2.0
                                       40-50
    8-10

    2.18
    0.37
                                                                        Remarks
Depending on temperature, type of sludge, etc.
Depending on temperature, type of sludge, etc.


Enough to keep the solids in suspension and
maintain a DO between 1-2 mg/1.
This level is governed by mixing requirements.
Most mechanical aerators in aerobic digesters
require bottom mixers for solids concentration
greater than 8,000 mg/1, especially if deep tanks
(> 12 feet) are used.
                If sludge temperatures are lower than 15 deg C,
                additional detention time should be provided so
                that digestion will occur at the lower biological
                reaction rates.
                 Aerobic digestion tanks are open and generally
                 require no special heat transfer equipment or
                 insulation. For small treatment systems (0.1 mgd),
                 the tank design should be flexible enough so that
                 the digester tank can also act as a sludge thickening
                 unit. If thickening is to be utilized in the aeration
                 tank, sock-type diffusers should be used to
                 minimize clogging.
These cost data are based upon three operational
plants in Pennsylvania and do not reflect current
escalation of energy costs.
 Reference

   36,37
29, 31, 38, 39

   40,41,42

29, 36, 42, 43


 1,17,35,40

 1, 35, 36, 43
                                                  40,44
                                                                  38,40
                                                  17
                                                                   35
    40
 1 Waste activated sludge alone.
 2 Primary and waste activated sludge, or primary sludge alone.
                                                    11-22

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When existing anaerobic digesters are converted to aerobic digesters, the impact of retaining
or removing the digester covers on  sludge temperature and the temperature of the air under
the covers, accessibility of diffused air equipment, generation of objectionable odors during
warm  weather periods, oxygen  demand  and air supply  capacity  must  be considered.
Experience at one midwestern city indicated that the combination of an air-diffusion system
and a covered aerobic digester (converted from an existing anaerobic digester) increased the
air temperature inside the digester to 135 deg F and the sludge temperature to 97 deg F
(45).  At these  high temperatures,  objectionable odors  were  produced  due  to  high
concentrations of organic sulfides  in the sludge and the  low digester DO. Under these
conditions the sulfur-bearing compounds  were not  completely oxidized resulting in the
release of f^S to the atmosphere. The increased oxygen demand of the sludge that occurred
at the unanticipated high temperatures also reduced the ability  of the air supply system to
maintain the desired DO levels.

     11.3.4 Process Design and Cost Estimates

The following example illustrates upgrading sludge handling facilities with aerobic digestion.
Due to continued  operational problems with an  existing  anaerobic digestion  facility, a
community decided to convert the existing anaerobic digesters  to aerobic digesters by the
installation of blower and diffused air equipment. The waste activated sludge from the 4
mgd activated sludge plant is settled along with raw wastewater in the primary clarifiers and
pumped directly to the digestion system at an average solids concentration of 3 percent. The
upgraded facility is shown on Figure 11-5.

In the  upgraded system, the two  aerobic digesters will be operated continuously at a  total
detention time of 37.4 days. This detention time is in excess of the 15 to 20 days required
and will allow the aerobic digestion process to handle increased solids loading in the future.
A summary of the design data for the upgraded facility is presented in Table 11-9.

The estimated total  capital costs for the upgrading are $203,000,  broken down as follows:

          Air System                                       $157,000
          Renovation to Existing Tank                         46,000

              Total                                       $203,000

11.4 Heat Treatment of Sludge

The heat treatment process involves heating sludge for short periods of time under pressure.
It is essentially a conditioning process which prepares sludge for  dewatering without the use
of chemicals. In addition, the sludge is sterilized and generally rendered inoffensive.
                                         11-23

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COMBINED PRIMARY AND
WASTE BIOLOGICAL SLUDGE
                                               FIGURE  11-5

                         CONVERSION OF ANAEROBIC TO AEROBIC  DIGESTION
                                             DIGESTER 1
                                        (EXISTING STRUCTURE)
                                           AIR HEADER
                                         1	r
                             EXISTING SLUDGE
                                  PUMPS
               DIGESTER 2
          (EXISTING STRUCTURE)
                                                                                            STABILIZED SLUDGE
                                                                                            TO DENATERING
                                                                                            FACILITIES
SUPERNATANT

-------
                                    TABLE 11-9
             AEROBIC DIGESTER UPGRADING DESIGN PARAMETERS

                        Description                                     Value

Plant Design Flow, mgd                                                   4
Number of Digesters                                                      2
   Volume (each), cu ft                                                 75,000
Total Solids Added to Aerobic Digesters, Ib/day                           7,500
Volatile Solids Added to Aerobic Digesters (70 percent volatile), Ib/day      5,250
Sludge Volume (3 percent solids), gpd                                   30,000
   VSS  Loading (each) pcf/day                                           0.035
Hydraulic Detention Time (total), days                                  37.4
Aeration Requirements (each), cfm                                       4,500


1 (60 cfm/1,000 cu ft).
When sludge is conditioned by heat treatment, thermal activity releases the bound water and
results in coagulation of solids. In addition, hydrolysis of proteinaceous material occurs
resulting in cell destruction and ammonia nitrogen release. Approximately 30 to 40 percent
of the VSS are solubilized resulting in a very high strength recycle liquor.

Two variations exist for heat treatment. In both systems, sludge is passed through a heat
exchanger into a reactor vessel, where steam is injected directly into the sludge to bring the
temperature to within the range of 144 to 200 deg C, under a pressure of 150 to 200 psig.
In one variation air is also injected into the reactor vessel with the sludge. The detention
time in the  reactor is approximately  30 minutes. After heat treatment,  the sludge passes
back  through  the heat  exchanger  to  recover  heat,  and then is   discharged  to  a
thickener-decant tank. The  thickened sludge may be dewatered by vacuum filtration or
centrifugation to a solids content of 30 to 45 percent.

The supernatant and filtrate recycle liquor contains high concentrations of short-chain water
soluble  organic compounds  and ammonia nitrogen.  The strength of the recycle is  much
higher than that from anaerobic or aerobic digestion, but is generally amenable to biological
treatment. This flow should be returned to  the plant for treatment but careful consideration
must  be given to the  effects  of the increased organic and  ammonia nitrogen loads.
Otherwise, the liquor must be treated separately and then returned to the plant. A complete
discussion of  the  heat  treatment  process is presented in the Process Design Manual for

                                      11-25

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Sludge Treatment and Disposal (1). Characteristics of filtrate for a heat treated sludge with
and without air addition  are listed in Table 11-10. The results presented are from a pilot
study on  high-purity oxygen  activated sludge with  a feed concentration of 2.68 percent
from the Batavia, New York, Wastewater Treatment Plant.
                                  TABLE 11-10
           CHARACTERISTICS OF HEAT TREATED SLUDGE FILTRATE
                                AT BATAVIA (46)

       Parameters                  With Air Injection      Without Air Injection
                                        mg/1                    mg/l

       COD                           17,000                   15,900
       BOD                             7,210                    7,650
       TSS                              8,800                   11,400
       VSS                              7,800                   10,200
       Total P                            250                      140
       Total N                           1,610                    1,510
       NH3-N                           740                      540
       pH                                 4.7                       6.4

The advantages claimed for the heat treatment process are:

     1.   Excellent  dewatering  characteristics  of  treated  sludge  without  chemical
         conditioning

     2.   Innocuous sludge suitable for ultimate disposal by a variety of methods

     3.   Few nuisance problems

     4.   Suitable for many types of sludge which cannot be stabilized biologically

     5.   Reduction in subsequent incineration energy requirements

     6.   Reduction in size of subsequent vacuum filters and incinerators.
                                       11-26

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 Disadvantages claimed for the heat treatment process are:

     1.   High construction and operation

     2.   Specialized supervision and  maintenance requirements due to high temperatures
          and pressures

     3.   High recycle organic and ammonia nitrogen loads

     4.   Expensive material costs to prevent corrosion.

 11.5  Lime Stabilization of Sludge

 Land disposal of raw sludge  is objectionable primarily because the sludge contains a large
 quantity  of  pathogenic  microorganisms  and heavy  metals. Furthermore,  biological
 conversion of  the  sludge  cake into  an inert  material can create odor problems. Lime
 stabilization of raw sludge can improve its acceptability for land disposal.

 Various investigators have reported that the addition of lime to raw or digested sludges to
 pH  ranges of 10.2 to  12.5 has effectively reduced the number of pathogenic organisms
 present (47) (48) (49). Current U. S. EPA sponsored work indicates that the pH should be
 increased to  12.0 for more effective disinfection  (1). Farrell, et al, have investigated the
 bactericidal effect of lime  on chemically precipitated primary  sludges. Their findings are
 presented in Table 11-11.
                                   TABLE 11-11
                 BACTERICIDAL EFFECT OF LIME ADDITION TO
                   CHEMICALLY PRECIPITATED SLUDGES (50)

                                   Bacterial Count (organisms/liter of sludge)
Alum-Primary
Limed Alum-Primary
Ferric-Primary
Limed Ferric-Primary
Salmonella
Species
110
None detected
> 24,000
None detected
Pseudomonas
aeruginosa
1,300
None detected
610
None detected
Total Aerobic
Count
41 x 108
5.0 xlO8
190 x 108
0.29 x 108
                                       11-27

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Lime  addition  to raw  sludge does  not render it permanently  stable because the pH
eventually drops and surviving organisms, or organisms that recontaminate the sludge, can
create nuisance conditions (50). Disposal in  sanitary landfills of dewatered lime stabilized
raw sludge has been suggested as a satisfactory procedure. In such cases, the sludge should
be deposited in thin layers and covered daily.

11.6 References

 1. Process Design Manual for Sludge Treatment and Disposal. U. S. EPA, Office of
    Technology Transfer, Washington, D. C. (1974).

 2. McCarty, P.L., Anaerobic Waste Treatment Fundamentals. Public Works, 95, No. 9, pp.
    107-112(1964).

 3. Speece,  R.L., and McCarty, P.L., Nutrient Requirements and  Biological  Solids
    Accumulation in Anaerobic Digestion. Proceedings of the International Conference on
    Water Pollution Research, Pergamon Press (1962).

 4. Kugelman, I.J.,  and Chin, K.K., Toxicity  Synergism and Antagonism in Anaerobic
    Waste  Treatment  Processes. Presented  before  Division of  Air,  Water and  Waste
    Chemistry, American Chemical Society, Houston, Texas (February, 1970).

 5. Kugelman, I.J.,  and McCarty,  P.L., Cation Toxicity and Stimulation in Anaerobic
    Waste  Treatment.  Journal Water Pollution Control Federation, 37, No. 1, pp. 97-115
    (1965).

 6. Lawrence, A.W.,  Kugelman,  I.J.,  and  McCarty,  P.L.,  Ion  Effects  in  Anaerobic
    Digestion.  Technical  Report  No. 33,  Department  of Civil Engineering, Stanford
    University (March, 1964).

 7. Sewage  Treatment Plant Design.  Water Pollution  Control  Federation Manual of
    Practice No. 8, Washington, D.C. (1959).

 8. Lawrence, A.W., and  McCarty, P.L., The Role of Sulfide in Preventing Heavy Metal
    Toxicity in Anaerobic  Treatment.  Journal Water Pollution Control Federation, 37,
    No. 3, pp. 392-409 (1965).

 9. Sawyer,  C.,  Anaerobic  Units. Proceedings  of  a Symposium on Advances in  Sewage
    Treatment Design, Metropolitan  Section-Sanitary Engineering Division, ASCE, New
    York (1961).

10. Meyers, H.V., Improved Digester Performance through Mixing. Journal Water Pollution
    Control Federation, 33, No. 11, pp.  1,185-1,187 (1961).

                                       11-28

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11. Langford,  L.L., P.F.T.  - Pearth Multipoint Gas Recirculation. Water and  Sewage
    Works, 108, No. 10, pp.  382-383 (1962).

12. Lynam, B., et al, Start-Up and Operation of Two High-Rate Digestion Systems. Journal
    Water Pollution Control  Federation, 39, No. 4, pp. 518-535 (1967).

13. Zablatzky, H., and Peterson, S., Anaerobic Digestion Failures. Journal Water Pollution
    Control Federation, 40,  No. 4, pp. 581-585 (1968).

14. Schroepfer, G.J., et  al,  The Anaerobic Contact Process as Applied to Packing House
    Wastes. Sewage and Industrial Wastes, 27, No. 4, pp. 460-486 (1955).

15. Dague,  R., Application of Digestion  Theory  to Digester Control. Journal Water
    Pollution Control Federation, 40, No. 12, pp. 2,021-2,031 (1968).

16. Torpey,  W.,  and Melbinger, N., Reduction of Digested Sludge Volume by Controlled
    Recirculation. Journal Water Pollution Control Federation, 39, No. 9, pp. 1,464-1,474
    (1967).

17. Burd, R.S., A Study of Sludge Handling and Disposal. Federal Water Pollution Control
    Administration, Publication WP-20-4 (May, 1968).

18. Voshel,  D.,  Gas Recirculation  and CRP Operation. Wastes Engineering, 34, No. 9,
    pp. 452-455 (1963).

19. Malina, J.F., Jr. and DiFilippo, J., Treatment of Supernatants and Liquids Associated
    with Sludge Treatment. Water and Sewage Wastes, pp. R-30-R-38 (1971).

20. The Dow  Chemical Company, Application  of Chemical  Precipitation Phosphorus
    Removal at the Cleveland Westerly Wastewater Treatment Plant. Report prepared for
    the City  of Cleveland, Ohio, by the Dow Chemical Company (April, 1970).

21. Derrington,  R.E.,  Stevens,  D.,  and  Laughlin,  J.E.,  Enhancing  Trickling Filter
    Performance by Chemical  Precipitation. U. S. EPA, Grant No. S800685, Project
    No. 11010 EGL (August, 1973).

22. Long,  D.A., Nesbitt, J.B., and Kountz, R.R., Soluble Phosphorus Removal in the
    Activated  Sludge Process.  Report for  the Water Quality Office, U. S. EPA, Project
    No. 17010 EIP  (August, 1971).

23. Thompson, J.C., Removal of Phosphorus at a Primary Wastewater Treatment Plant.
    Paper  presented at the  Spring  Meeting, New  England   Water Pollution  Control
    Association, Stratton, Vermont  (June 7, 1972).

                                       11-29

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24. Johnson, E.L., and Beeghly, J.H., and Wukasch, R.F., Phosphorus Removal at Benton
    Harbor —  St. Joseph, Michigan. Report  prepared  for Benton Harbor — St. Joseph,
    Michigan, Joint Board of Commissioners by the Dow Chemical Company (1968).

25. Zenz,  D.R.,  and Pivnicka, J.R., Effective Phosphorus Removal by the  Addition  of
    Alum  to  the Activated Sludge Process. Proceedings of the 24th  Industrial Waste
    Conference, Purdue University, Lafayette, pp. 273-301 (May, 1969).

26. Brown, J.C., Little, L.W., Francisco, D.E., and Lamb, J.C., Methods for Improvement
    of Trickling Filter Plant Performance, Part II, Alum Treatment Studies, U. S. EPA,
    Contract No. 14-12-505, University of North Carolina, Chapel Hill, N. C. (1974).

27. Smith, A.R., Aerobic Digestion Gains Favor. Water and Wastes Engineering, 8, No. 2,
    pp. 24-25 (1971).

28. Ahlberg, N.R., and Boyko, B.I., Evaluation and Design of Aerobic Digesters. Journal
    Water Pollution Control Federation, 44, No. 4, pp. 634-643 (1972).

29. Malina, J.F., and Burton, H.M., Aerobic  Stabilization of Primary Waste water Sludge.
    Proceedings-19th Industrial Waste Conference, Purdue University,  Lafayette, Indiana,
    pp. 716-723 (May, 1964).

30. Metcalf  &  Eddy, Inc., Wastewater  Engineering: Collection, Treatment,  Disposal.
    McGraw-Hill Book Company, New York, page 612 (1972).

31. Jaworski,  N.,  et  al, Aerobic  Sludge Digestion.  Presented  at the Conference  on
    Biological Waste Treatment, Manhattan College, N. Y., N. Y. (April 20-22, I960).

32. Smith, J.E., Jr., Young,  K.W., and Dean, R.B., Biological Oxidation and Disinfection of
    Sludge. Prepublication copy (1973).

33. Cohen, D.B., and Puntenney, J.L., Metro  Denver's Experiences with  Large Scale
    Aerobic Digestion of Waste Activated Sludge. Presented at the 46th Annual Conference
    of the Water Pollution Control Federation, Cleveland, Ohio (October , 1973).

34. Reynolds,  T., Aerobic Digestion of Waste Activated Sludge. Water and Sewage Works,
     114, No. 22, pp. 37-42 (1967).

35. Smith, R., Eilers, R.G., and Hall, E.D., A Mathematical Model for Aerobic Digestion.
     U. S. EPA, Office of Research and Monitoring, Advanced Waste Treatment Research
     Laboratory, Cincinnati, Ohio (February, 1973).
                                        11-30

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36.  Dreier,   D.E.,  Aerobic  Digestion  of  Solids.  Proceedings-18th  Industrial Waste
     Conference, Purdue University, Lafayette, Indiana, pp. 123-139 (1963).

37.  Loehr, R.C., Aerobic Digestion: Factors Affecting Design. Water and Sewage Works,
     Reference Number, pp. R169-R180 (November 30, 1965).

38.  Barnhart, E., Application  of  Aerobic  Digestion  to  Industrial  Waste  Treatment.
     Proceedings-16th Industrial  Waste Conference, Purdue University, Lafayette, Indiana,
     pp. 612-618(1961).

39.  Lawton, G.W., and Norman, J.D., Aerobic Digestion Studies. Journal Water Pollution
     Control Federation, 36, No.  4, pp. 495-504 (1964).

40.  Ritter,  L.,  Design and Operating Experiences Using Diffused Aeration  for Sludge
     Digestion. Journal Water Pollution Control Federation, 42, No. 10, pp. 1,782-1,791
     (1970).

41.  Dreier, D.E., Discussion on Aerobic Sludge  Digestion. By Jaworski, N., Lawton, G.W.,
     and Rohlich, G.A.  Presented  at  the  Conference  on  Biological  Waste  Treatment,
     Manhattan College, N. Y., N. Y. (April 20-22, 1960).

42.  Levis, C.E., Miller, C.R., and Vosburg,  L.E., Design and Operating Experiences  Using
     Turbine  Dispersion for Aerobic Sludge  Digestion.  Journal  Water Pollution Control
     Federation,  43, No. 3, pp. 417-421 (1971).

43.  Howe, R.H.L., What to do  with Supernatant. Waste Engineering 30,  No. 1, page 12
     (1959).

44.  Randall, C.N., and Koch,  C.T., Dewatering  Characteristics  of Aerobically Digested
     Sludge. Journal Water Pollution Control Federation, Research Supplemental, No. 5,
     Part 2, pp. R215-R238 (1969).

45.  Private communication with C.L. Swanson, U. S. EPA, Cincinnati, Ohio (November 12,
     1970).

46.  Personal communication  with  Kai W.  Young,  Union  Carbide Corporation,  Linde
     Division, Tonawanda, N. Y. (March 29, 1974).

47.  Kampelmacher,  E.H., and van  Noorle Jansen, L.M., Reduction of Bacteria in Sludge
     Treatment.  Journal Water  Pollution  Control Federation,  44, No. 2,  pp. 309-313
     (1972).
                                       11-31

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48.  Evans, S.C., Sludge Treatment at Luton. Journal Institute Sewage Purification, Part 5,
     pp. 381-390 (1960).

49.  Doyle, C.B., Effectiveness of High pH for Destruction of Pathogens in Raw Filter Cake.
     Journal Water Pollution Control Federation, 39, No. 8, page 1,403 (1967).

50.  Farrell, J.B., Smith, J.E., Jr., Hathaway, S.W., and Dean, R.B., Lime Stabilization of
     Chemical—Primary  Sludge at 1.15 Mgd.  Presented at the 45th Annual Conference of
     the Water Pollution Control Federation, Atlanta, Georgia (October, 1972).
                                       11-32

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                                    CHAPTER 12

                              SLUDGE DEWATERING
12.1 General

The  selection of  a  sludge  dewatering process is mainly  dependent  on the subsequent
treatment and disposal of the dewatered sludge. If incineration is used, sludges with low
moisture content are required to minimize fuel consumption. However, if dewatered sludge
is taken directly to a landfill, higher sludge moisture contents may be tolerable depending
on the construction and management practices of the landfill operation. Other factors that
should be considered are space limitations, economics and general operation.

12.2 Vacuum Filtration

Vacuum filtration is  the most common mechanical method of sludge dewatering utilized in
the United  States.  The majority of vacuum filters are installed in larger facilities where
sludge  drying beds are impractical due to limited space, or  where incineration is necessary
for maximum volume reduction. In small plants, vacuum filters have not been commonly
used because of  the higher operating skill required; the increased construction costs for
facilities  to  house chemical  storage, conditioning and filtration facilities; and the higher
operating cost for chemical  conditioning. Today, however, there is  an increasing trend
toward the  use  of vacuum filters  in smaller communities,  because of improvements in
operator  training, the increasing scarcity of land and, in some  instances, the difficulty of
obtaining unskilled labor for cleaning of sludge drying beds. A flow diagram of a typical
vacuum filter installation is shown on Figure 12-1.

     12.2.1  Process Considerations

Process operating considerations for vacuum filtration include:

     1.   Type of sludge
     2.   Feed solids concentration
     3.   Sludge age
     4.   Chemical requirements for sludge conditioning
     5.   Sludge mixing and flocculation
     6.   Drum speed and drum submergence
     7.   Filter fabric characteristics
     8.   Filter cake discharge.
                                        12-1

-------
                                                   FIGURE  12-1

                                     TYPICAL VACUUM  FILTER  FLOW DIAGRAM
to
             COAGULANT              FLOW CONTROL
SLUDGE

C
o
)
_!
POLYELETROLTYE
. 9l C 1
=3
/
•A
CJ
•=>
s~
*
«
0
" \.
*

                   SLUDGE  CONDITIONING TANKS
                                               -DRUM
                                                                           FILTRATE RETURNED
                                                                           TO  PLANT
                                                                                    AIR TO
                                                                                    ATMOSPHERE
                                                                                          SILENCER

                                                                                          WATER TO PLANT
CONVEYOR     /   |   <—VACUUM RUMP
    FILTRATE/  WATER
    PUMP —
                                                           WASHINGS
                                                           RETURNED
                                                           TO  PLANT
     TO FILTER
     CLOTH WASH
                                                                             FROM WATER SOURCE

-------
Each  of these  parameters affects  the filter yield, economy of operation and filter cake
characteristics.  The nature of the sludge to be filtered is important in establishing several of
the design parameters. Sludge particle size, shape, consistency and density affect filterability
and chemical conditioning requirements (1). Because digestion results in the breakdown of
coarse solids into finer particles, vacuum filtration of raw primary or primary-secondary
sludges permits higher filter yields, lower chemical requirements and lower cake moisture
contents than vacuum filtration of digested sludges. As the ratio of secondary to primary
sludge increases, vacuum filtration of undigested sludge becomes more difficult.

The feed solids concentration  has  an important influence on the filtration rate and filter
yield.  In a  large  number of cases where poor filter performance  has been experienced,
sufficient care in  operation has not been given to optimizing the feed solids concentration
(1). The optimum solids concentration for filtration is 8 to  10 percent. Higher solids content
makes the sludge difficult to  pump and  condition for dewatering. Lower solids content
requires the use  of more or larger  vacuum  filters than necessary. In general, sludge yield
increases directly in proportion to  an increase in feed solids concentration, although data
have been reported where the increase was more than proportional (2)(3)(4).

It is  generally  agreed that as raw sludge ages, it becomes more difficult to dewater on
vacuum filters.  This effect has  been reported by Ettelt and Kennedy (5), and Tenney, et al,
(3) who observed increasing  filter cake moisture with increasing age of thickened activated
sludge. Tests at the Chicago Sanitary District (5) showed  that even a short holding period
after  thickening can significantly affect vacuum filter performance. It was observed that the
filter   cake  solids  concentration varied linearly  with detention  time,  decreasing from
17 percent for  immediate filtering  after thickening to 13 percent after a holding period of
3-1/2 hours. In this situation, it was found that freshening of the sludge by reaeration prior
to filtration dramatically reduced the filter  cake moisture and the required ferric chloride
conditioning dosage.

Few,  if any, raw  or digested wastewater sludges can be successfully dewatered without some
form  of chemical conditioning using ferric  chloride, lime and/or polyelectrolytes. Proper
sludge conditioning requires  a  determination of optimum chemical dosages. Experience and
careful laboratory monitoring of the sludge characteristics are key factors in maintaining the
proper chemical  proportions and concentrations. Where a mixture  of undigested primary
and secondary  sludge is to be dewatered, it is essential that careful attention be given to
maintaining a uniform  ratio of primary to  secondary sludge. Mechanically mixed and/or
aerated blending tanks are often provided for this purpose.

Optimum sludge mixing and  flocculation under  varying conditions  require that  sludge
conditioning tanks be provided with variable-speed mixer drives, adjustable weirs or flow
control  devices  to  vary  the sludge  detention time and multiple  points  of  chemical
application as  indicated on Figure  12-1. The sludge slurry must be  agitated sufficiently to
                                         12-3

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maintain uniformity; however, excessive agitation should be avoided so that the conditioned
slurry particles are not sheared.

Drum speed and drum submergence are important factors in the operation of vacuum filters
since  they affect filter yield and  filter cake moisture. Increasing the drum submergence
generally  results in increased filter yield, but produces a filter cake with higher moisture
content. Decreasing the drum speed, i.e., increasing the cycle time, has the opposite effect
of decreasing the filter yield, but produces a cake with lower moisture content.

Much information  is available from the various manufacturers of vacuum filters and filter
media on the selection of proper media. A wide variety of media are now available including
natural  and synthetic fabrics and metal coils. Because of the variable nature of sludge, it is
important that  the selection of the media be  based as nearly as possible  on actual plant
conditions. Often this can best be  accomplished through laboratory experimentation, using
the Filter Leaf Test, to provide information on filter  fabric blinding, filtrate quality and
cake characteristics.

In general, a media is selected on the basis of the cleanest possible filtrate  consistent with
high  filtration  rates, and  where  incineration  is  used,  lowest  moisture  contents.  In
incineration situations, it is often economically justifiable to oversize  the filters to  achieve
lower moisture  contents and significant fuel savings. The concentration of total solids in the
vacuum filter filtrate is the primary measure of filtrate quality. The SS may vary between
100 and  20,000 mg/1  depending on sludge type, the filter media, and the applied vacuum
(1). In  practice, filtrate SS concentrations of 500 to 2,000 mg/1 are normal. Although the
solids in the filtrate normally resettle readily when returned to the head of the plant, fine
solids may resist removal and be continuously recycled. Accumulation of these solids in the
system  may eventually reduce overall plant efficiency.  Activated sludges normally  contain
more fine particles than primary  sludge  and,  therefore,  require tighter filter medias and
slower filtration rates.

A prerequisite for  good filter operation is that the sludge cake discharge cleanly from the
filter media (6). Characteristics of both the sludge and the media affect filter cake discharge.
Primary sludges having high fiber content generally  produce a drier  cake that discharges
more readily than activated or digested sludges containing finer material. Because the cake
discharge characteristics of various fabrics differ, a number of materials should be evaluated
when running Filter Leaf Tests to determine the best fabric for a given sludge. Generally,
cake  discharge  occurs   through  the  flexing  action  of  the  media  passing  around   a
small-diameter discharge roller. Where  sludge characteristics are such that the cake tends to
adhere to the  media, a scraper blade may be provided to assist removal.
                                          12-4

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     12.2.2 Evaluation of the Vacuum Filtration Process

Experience has shown that there are considerable  variations  in filtration rate, not only
between different sludge types, but also between the  same types  of sludges at different
times and  locations.  The discrepancies in filter test results at  different plants are usually
related  to variations in feed solids concentrations, particle size  distributions, and industrial
waste components in the raw wastewater. Obviously then, it is of major concern to have a
laboratory technique which can accurately predict the performance of a full-scale vacuum
filter prior to its installation.

The Buchner Funnel Test and the Filter Leaf Test are commonly used in laboratory testing
programs for  determining the filterability of sludges. When the amount of representative
sludge is limited (less than 10 liters), it is advisable first to perform the Buchner Funnel Test
to  determine optimal chemical dosage and sludge filtration  characteristics. The Filter Leaf
Test can then be run at the optimum condition to determine filter yield. If a large amount
of  sludge is available, the Buchner Funnel Test can be eliminated and the  Filter Leaf Test
run instead.

The main  purpose  of  the  Buchner Funnel  Test is  to  determine  optimum chemical
requirements based on  a  comparison of the specific resistance of chemically treated sludge
with that of untreated  sludge. An approximate filter yield can  also be calculated from the
Buchner Funnel  Test.  Basically, the Buchner Funnel Test  consists of filtering 100 ml  of
sludge,  either  raw or conditioned, through filter paper under a vacuum of 20 to 25 inches  of
mercury. The volume of filtrate (V, in ml) with time is noted  and plotted against elapsed
time/volume (t/V in sec/ml)  to  obtain  the  slope  of the resulting line. Using the above
information, the specific resistance of the sludge is calculated from  the following equation:
          r  = 6.91 x 106
bA2P
     where:
          r = Specific resistance, sec2/g
          b = Slope of plot (V vs. t/V), sec/ml2
          A = Area of filter, sq cm
          P = Filtration vacuum, psig
          ^ = Absolute viscosity of filtrate, centipoise
          c = Initial SS concentration, mg/ml

The dimensions of the variables in the above equation are in units typically measured in the
laboratory. The conversion constant, 6.91  x  10^ reduces the variables to units which are
dimensionally  consistent. The specific resistance as calculated by the above equation would
be expressed as sec2/g.  Typical values of specific resistance for various sludges are shown in
Table 12-1.

                                        12-5

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                                     TABLE 12-1
        TYPICAL SPECIFIC RESISTANCE VALUES FOR VARIOUS SLUDGES
Raw Sludge
   5% FeClg
   5% FeCl3 + 5% CaO
   2% Polyelectrolyte
Digested Sludge
   5% FeCl3
   5% FeClg + 5% CaO
   2% Polyelectrolyte
  Primary Sludge
Specific Resistance,
    107 sec2/g

  1,300-2,100
        10
         3
         3
    400-1,600
        25
        18
        20
 Activated Sludge
Specific Resistance,
    107 sec2/g

    2,800
      140
        60
        50
      800
                                                                           Reference
8
8
8
7
8
8
8
The approximate filter yield can be estimated from the specific resistance data using the
following relationship (9):
             i  (loo-CiA   %
         L =  0.0357
      where:

         L = Filter yield, psf/hr
 Cj and Cf  = Initial and final moisture content of the sludge, percent
         m = Percentage of time for which vacuum acts during cycle
         9 - Time for one drum revolution, minutes (usually between 1.5 and 5 minutes)
         Y' - Absolute viscosity of filtrate, centipoise
         R = r x lO-7 g/sec2
         r  = Specific resistance, sec2/g
         P  = Filtration vacuum, psig
The  Filter  Leaf Test techniques are simple, and the test can be run with minimum effort.
The  advantage  of the Filter Leaf Test is  that the filter yield is measured and not merely
calculated using an empirical equation.  With careful laboratory techniques, results will be
closely indicative of full-scale vacuum filter operation, although plant scale tests are more
conclusive and should be used whenever possible. A scale-up design factor of 0.9 is typically
used for the Filter Leaf Test where plant scale tests are not practical.
                                        12-6

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The Filter Leaf Test is usually performed on a 0.1 sq ft filter leaf. The main objective of the
test is to evaluate the effect of different fabrics, fabric forms and drying times on filter
yield.  Varying doses and types of chemicals should also be tested to establish chemical
conditioning requirements. The basic steps in performing  a Filter Leaf Test are outlined
below and should be repeated a number of times to optimize the performance of each media
tested.

     1.  Condition the sludge in a 2 to 5 gallon container.

     2.  Submerge the filter leaf in the sludge  slurry and apply vacuum for a fixed form
         time.

     3.  Gently remove the filter leaf from the sludge slurry to allow the cake to dry for a
         fixed drying time.

     4.  Remove  the cake  from the filter leaf and measure the weight and moisture
         content of the cake. Note cake thickness and separability from the media.

     5.  Measure the filtrate SS and filtrate volume.

The filter yield is then calculated using the following equation:

         L = dry sludge weight (g) x number of filtration cycles/hr
              453.6 x area of test filter leaf (sq ft)

     where:

         L = filter yield in psf/hr

     12.2.3  Vacuum Filter Performance

The results  of studies by the Dow Chemical Company (10) on vacuum filter performance
are shown  in Table 12-2. Various  types of municipal  sludges were  dewatered using
polyelectrolytes and  inorganic chemicals as conditioners for the same  sludges. The data
shown in Table 12-2 indicate that the yield obtained when using polyelectrolytes for sludge
conditioning  is  generally  higher than  that obtained  when  using  inorganic chemical
conditioners.

Vacuum filtration of pure oxygen waste activated sludge has been studied at Batavia, New
York,  and  in several other demonstration plants (11) (12).  Data from  these studies are
shown in Table 12-3. The settling characteristics of pure oxygen waste activated sludge are
such that, where  primary settling is omitted, it can be thickened adequately in the clarifiers
for direct vacuum filtration. In this instance, additional sludge storage capacity beyond that

                                        12-7

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                                 TABLE 12-2
       VACUUM FILTRATION PERFORMANCE USING INORGANIC CHEMICALS
                 AND PURIFLOC C-31 ON MUNICIPAL SLUDGE (10)

Type of Sludge

la Raw primary

b Raw primary
2a Raw primary

b Raw primary
3a Raw primary

b Raw primary
4a Raw primary

b Raw primary
5a Digested primary
b Digested primary
6a Digested primary

b Digested primary
7a Elutriated/digested/primary
b Elutriated/digested/primary
8a Elutriated/digested/primary
b Elutriated/digested/primary
9a Elutriated/digested/primary
b Elutriated/digested/primary
lOa Elutriated/chgested/primary
and secondary
b Elutriated/digested/primary
and secondary
lla Digested primary and
secondary
b Digested primary and
secondary
12a Elutriated/digested/primary
and secondary
b Elutriated/digested/primary
and secondary

Filter Media

Coil

Coil
Coil

Coil
Open synthetic

Open synthetic
Open synthetic

Open synthetic
Long napped dacron
Long napped dacron
44 x 44 Saran

44 x 44 Saran
Napped polyester
Napped polyester
Napped polyester
Napped polyester
Napped polyester
Napped polyester
Long napped dacron

Long napped dacron

Synthetic

Synthetic

Napped dacron

Napped dacron

Chemical
Conditioning

FeCl3
Lime
C-31
Fe2(S04)3
Lime
C-31
FeCl3
Lime
C-31
FeCl3
Lime
C-31
Fe2(S04)3
C-31
FeClg
Lime
C-31
FeCl3
C-31
FeCl3
C-31
Fe2(S04)3
C-31
Lime and
F"2(S04)3
C-31

FeClg
Lime
C-31

Fe2(S04)3
Lime
C-31

Solids Concentration
Dosage
Ib/ton dry solids
162.4
166.8
14.0
60
106
8.4
80.0
280.0
18.0
78.0
390.0
20.0
(16.06/T)
(S6.58/T)
66.0
206.0
17.0
56.8
10.2
100.0
8.0
108.0
9.0

(S8.90/T)
(S8.79/T)

610.0 (total)
or($10.07/ton)
18.0 or
($6.12/ton)
360.0
120.0
22.0

Initial
percent

7.57
7.0

9.1
9.6

15
12

11.2
10.7
7.2
7.2

15.0
15.0
6.1
7.7
10.4
10.1
10.9
11.1

9.1
9.1

4.4

4.3


8.0
9.0

Final
percent

20.1
20.0

24.0
20.0

40.0
30.0

39.0
34.5
26.0
33.5

43.0
32.0
36.0
32.9
32.7
38.6
34.0
35.0

25.0
24.0

26.2

23.7


28.0
25.0

Filter Yield
psf/hr

6.91
7.53

8.6
11.5

5.0
7.0

3.1
3.5l
3.9
11.0

9.2
25.0
5.74
12.66
3.88
5.94
2.8
5.5

4.7
7.4

5.2

5.6


5.1
7.25

1. Yield intentionally kept down to avoid overloading incinerator.
                                    12-8

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    Location


Batavia, N. Y.2



Louisville, Ky.


New Orleans, La.3

Philadelphia, Pa.3


Notes:
                                                    TABLE 12-3
                                   SUMMARY DATA ON VACUUM FILTRATION OF
                                      PURE OXYGEN AERATION SLUDGES (11)
         Type
          of
        Sludge
     Waste activated
     Waste activated
     Waste activated
Thickened waste activated
     Waste activated
     Waste activated
     Combined 1
     Waste activated
     Waste activated
     Waste activated
     Waste activated
Feed Solids
percent
2.75
2.75
2.29
4.37
2.91
3.58
6.39
3.00
3.00
1.48
1.84

174
174
192
200
115
190
88
100
150
144
146
Chemical Dose Rate
Ib/ton of Dry Solids
FeCl3        Lime
                             272
                             266
  1.   Combined Sludge:  5 parts raw primary sludge, 1 part waste activated sludge.
  2.   Pilot Scale Filter (3 ft diameter by 1 ft length).
  3.   Filter Leaf (filter area = 0.1 sq ft).

Cake Yield
psf/hr
1.96
2.14
4.55
5.12
2.36
1.95
4.08
5.60
5.30
1.72
1.56
Cake
Solids
percent
24.1
20.5
16.0
14.5
13.3
17.6
29.0
16.3
19.5
30.8
36.0

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available in the clarifiers is necessary to allow optimum filter operation without adversely
affecting clarifier performance. The most effective chemical conditioner for vacuum filtering
pure  oxygen  sludge  at  Batavia  was found to be  ferric chloride  at a dosage of 175  to
200 Ib/ton of dry solids (11). Cake yield was roughly doubled by increasing the drum speed
from  6.3 minutes per revolution to  2.5 minutes per revolution, but cake moisture content
increased substantially. The use of polyelectrolytes  alone or in combination with inorganic
chemicals was not as effective as ferric chloride.

     12.2.4 Upgrading Existing Vacuum Filters

In some instances, recycling a load  of fine solids within the plant can seriously  impair
vacuum filter performance. Such conditions are created by poor quality digester supernatant
or elutriate which must be corrected before good filter performance can be reestablished.

The  need  to upgrade existing  vacuum  filters is  usually  due to an increase  in  sludge
production  or a change in  sludge  characteristics.  In these  cases, existing  vacuum filter
operations may be upgraded by improving one of the following:

     1.   Feed solids concentration

     2.   Filter media

     3.   Sludge conditioning.

Sludge thickening to  increase feed solids concentration  to the vacuum filter is generally the
most  economical and therefore  the most desirable method of increasing the filtration rate.
An increase  in  feed  solids concentration  will normally result in  at least a proportional
increase in the filtration rate (1) (4). Therefore, the effect of upgrading sludge thickening
facilities to increase  feed solids  concentration from 4 percent to  5 percent  would be  to
increase the filtration rate or sludge dewatering  capacity by 25 percent. For this reason,
steps  should be taken to ensure  that feed solids concentration is maximized before other
upgrading techniques are considered.

The use of  proper vacuum filter media is very important to efficient filter performance.
Most  primary sludges and certain industrial waste sludges have fibrous, non-uniform solids
that may  clog or blind  improper media and lead to lower filter yields, increased chemical
consumption and the need for frequent  washing (1). For this reason, primary sludges are
most  effectively dewatered  with media  having comparatively  large openings that resist
blinding. These media, however, are not suitable for activated or digested sludge due to the
higher proportions of fine particles. These sludges require tighter media and lower filtration
rates. Therefore, where sludge  characteristics  have  been  altered  significantly  due  to
upgrading procedures, vacuum filter operation  often may be correspondingly upgraded by
replacing filter media as indicated by laboratory Filter Leaf Tests or  full-scale trials (1).

                                       12-10

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Chemical conditioning is normally  required  prior  to vacuum filtration  of sludge. The
operation of a dewatering facility, therefore, may be upgraded by providing more efficient
chemical sludge conditioning. Most older filter installations were designed to use inorganic
chemicals, such as ferric chloride  and lime, as sludge conditioners. Within the last 10 years,
organic polyelectrolytes have begun  to replace inorganic chemicals as sludge conditioners,
and offer an  attractive  advantage  in more  economical  storage,  handling  and feeding
equipment. Polyelectrolytes are  also less corrosive  and frequently less  expensive than
inorganic chemicals.  The use  of  polyelectrolytes  in  improving the operation of vacuum
filters has been practiced at treatment plants in Bay City, Michigan (13), and Kansas City,
Missouri (14), among others.

The Bay City Wastewater Treatment Plant provides  primary treatment for 7.0 mgd and
produces approximately 450 tons of dry solids/year. Until  1961, raw primary sludge was
conditioned with ferric chloride and  either kiln-dried pebble lime or spent carbide (calcium
hydroxide formed as  the result of chemical action in  making acetylene). Bay  City's
conditioned sludge is dewatered on vacuum filters having an effective area of 150 sq ft. The
vacuum filter cake is incinerated. In 1961, polyelectrolytes were tried as sludge conditioners
in an attempt to improve filter yield. Results of filter operation for 1959-1964 using ferric
chloride, lime and polyelectrolytes are presented in Table 12-4. These results clearly indicate
that use of  polyelectrolytes increased the filter yield and significantly reduced  vacuum
filtration operation time. The  cost of chemicals for sludge conditioning at Bay City was
$10.40/ton of dry solids when using ferric chloride  and kiln-dried lime, $7.15/ton of dry
solids when using ferric chloride and carbide lime and $7.30/ton of dry  solids when using
polyelectrolytes. The following advantages were realized when polyelectrolytes were used
for sludge conditioning:

     1.    Savings in equipment and floor space

     2.    Improved housekeeping

     3.    Improved safety

     4.    Reduced quantities of ash, with a large reduction in ash handling and storage

     5.    Reduction in operating  time, with resulting savings in operating and maintenance
          costs.

     12.2.5 Process Design and Cost Estimates

The following example will serve to illustrate design and cost considerations when upgrading
vacuum filter installations by converting from inorganic chemical  to polyelectrolyte sludge
conditioning.
                                        12-11

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                                             TABLE 12-4
                    A COMPARISON BETWEEN LIME/FERRIC CHLORIDE AND POLYELECTROLYTES
                               FOR CONDITIONING RAW PRIMARY SLUDGE (13)
to
Year

1959
1960
1961-62
1962-63

inAQ A/I
Dry
Solids
tons
461
580
424
415

/I 37
Feed
Solids
percent
11.2
11.2
10.9
10.7

in o
Filter Chemical Added, Ib
Yield Lime FeClo. C-31 C-32 C-149 A-21
psf/hr
3.1 162,000 31,000 - -
3.1 225,000 44,000 - -
5.3 - 5,562
5.5 - - 10,300 -
Total of all three
polyelectrolytes
A3 U- 7A71 	 «J
Cake
Solids
percent
40.1
39.0
35.9
34.5

34 fi
Solids
Recovery
percent
64.1
62.1
75.6
73.7

75 Q
Operation
Time
hr/yr
2,125
2,420
1,119
1,114

1 .301

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An existing vacuum filter installation was annually conditioning and filtering 300 tons (dry
basis) of mixed digested primary and secondary sludge with a filter yield of 3 psf/hr. Sludge
conditioning had been accomplished using 65 Ib of ferric chloride and 200 Ib of lime/ton of
dry solids. To  reduce the costs involved in bulk chemical handling and  to increase filter
yield, the applicability of a polyelectrolyte  system for sludge conditioning was investigated.

The optimum polyelectrolyte dosage was found to be 20 Ib/ton of dry solids,  added to the
digested sludge  in  a  1-percent  solution.   The  polyelectrolyte addition  resulted  in  a
subsequent filter  yield of 4 psf/hr. This upgrading procedure reduced the operating time of
the vacuum filter by 25 percent, thereby decreasing operational and maintenance costs.

The capital cost  for  the polyelectrolyte application system was estimated at $7,000. This
cost included all required tankage, pumps, and mixers.

12.3 Drying Beds

The dewatering of digested sludge on drying beds has long been practiced in the United
States. Historically, sludge drying beds have  mainly been used for smaller communities (15).

The widespread use of drying beds for smaller plants is due  to  their simplicity and low
maintenance costs. The chemical cost and operating complexity of  mechanical dewatering
equipment are  additional factors which favor drying beds. Disadvantages include their large
land requirement, inability to dewater effectively during inclement weather,  difficulty of
obtaining labor for cleaning, and potential odor problems.

     12.3.1 Process Considerations

One of the difficulties in  developing a rational design for sludge beds is the multitude of
variables which affect the sludge drying rate. In practice, it is  difficult to isolate these
variables and evaluate them quantitatively. Some of the more important variables are (16):

     1.    Climate and atmospheric conditions

          a.    Temperature
          b.    Humidity
          c.    Rainfall
          d.    Wind velocity
          e.    Barometric pressure
         f.    Solar radiation
                                        12-13

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     2.   Sludge characteristics

          a.    Type of sludge
          b.    Method of stabilization
          c.    Moisture content
          d.    Grease content

     3.   Operational factors

          a.    Sludge age
          b.    Presence or absence of coagulants
          c.    Depth and frequency of application

     4.   Bed characteristics

          a.    Condition and gradation of sand
          b.    Condition of drainage system
          c.    Travel distance to bed extremities.

Notwithstanding the magnitude  of the problems involved, some generalizations concerning
the applicability of these factors can be made.  When  possible,  decisions regarding the
specific effect of any or all of these factors should be based on bench-scale testing.

Quon and Johnson (17) have indicated that well-digested sludge should be applied to drying
beds in depths of 6 to 9 inches, with  8 inches appearing to give optimum drying rates.

Sludge should be properly digested before being applied to the drying beds. Raw or poorly
digested sludge dewaters  slowly and produces strong odors. Sludge that has been overly
digested will  contain a high percentage of fine solids which will impair drainage. Aerobically
digested sludge usually drains well on sand drying beds (1) (18).

Drainage  and  evaporation are  the mechanisms  which  affect  the dewatering  rates  of
well-digested sludge on  drying beds. It  has been  widely  accepted  that under normal
conditions, practically all of  the drainage of sludge occurs  during the  first three  days
following the  filling of  the  drying bed (6). After this initial  period,  it was felt that
evaporation was largely responsible for additional  dewatering of the sludge. Recent studies
indicate  this  is not the case (16) (17) (19).  In an extended study, it was found that the
initial rate of drainage was small, but that it increased with time (17). After approximately
three days, the drainage rate  increased and  the sludge surface dropped substantially. This
phenomenon is explained by considering that air trapped in the voids of the sand bed is not

                                        12-14

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free to move and thus impedes the initial flow of water through the filter. Eventually, this
air is liberated, allowing a greater flow to pass  through the  sand  bed. After a period of
maximum drainage, the drainage rate gradually decreases due to the  buildup of solids on the
sand surface, which  offers resistance to further  filtration.  Once this  point  is reached,
evaporation from the free water surface accounts for further dewatering.

Drying  beds  are  usually constructed with an underdrain  piping  system  to increase the
drainage rate. Although some  installations have been designed with asphalt or concrete
bottoms to facilitate sludge removal, experiments have shown that  drained sludge beds dry
25 percent faster than beds with an impervious bottom (17). Underdrainage from drying
beds should be returned to the plant for treatment (20).

In areas with adverse  climatic conditions, the use of glass-covered beds, while expensive, has
been found to  increase the total output  of dewatered sludge  by 100 percent (21). Recent
work in northern Texas, however, indicated that during the dry season, covers retarded the
drying rate  rather than accelerating  it (16). Thus,  where covered beds are constructed,
adequate  ventilation  must be  provided so that maximum  evaporation  rates may  be
maintained.

     12.3.2 Design Basis

Present-day design practices are based largely on comparisons  with  existing plants in the
area, or upon empirical recommendations. The sludge drying bed area requirements shown
in Table 12-5 are recommended for domestic wastewater  treatment plants located in the
northern United States (6).
                                    TABLE 12-5
                   SLUDGE-DRYING BED AREA REQUIREMENTS
       Type of Sludge

Primary Digested
Primary and Humus Digested
Primary and Activated Digested
Primary and Chemically Precipitated Digested
                                                         Area of Drying Beds
                                                             sq ft/capita
 Open Beds

 1.0 to 1.5
1.25 to 1.75
1.75 to 2.5
 2.0 to 2.5
Covered Beds

 0.75 to 1.0
  1.0 to 1.25
 1.25 to 1.5
 1.25 to 1.5
                                       12-15

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In the southern United States, reduced areas are often practical because of more favorable
climatic conditions.

Recently, rational  design  procedures have  been developed for sludge drying beds  (6).
Equations which describe a sludge's drainage and drying properties have been derived (22).
These equations lend themselves to incorporation in computer models for sludge properties,
weather  variability and  economics. These  methods  may  eventually replace the present
empirical practice for designing drying beds.

     12.3.3  Upgrading Existing Facilities

It is possible to upgrade an overloaded sludge drying bed by the following methods:

     1.   Improving the performance of upstream facilities, e.g., thickeners, digesters

     2.   Adding chemicals to improve sludge dewatering characteristics

     3.   Covering open beds where climatic conditions adversely affect performance.

Chemicals such as alum, ferric chloride and polyelectrolytes have been used as flocculants to
improve the dewatering capacity of sludge drying beds. The use of these chemicals increases
the  permissible  sludge loadings to the  drying beds  by  increasing the number of  bed
applications per year.

In general, the chemical flocculants allow greater amounts of water to drain from the sludge,
thereby  decreasing the amount of water to be  removed through the slower evaporation
process.  Bed loadings for chemically treated and untreated sludge should be evaluated by
laboratory and field testing to determine the effectiveness of chemical addition on  sludge
drying.  Buchner Funnel Tests can be used to predict dewatering rates on drying beds in the
same manner as for vacuum filters (23). Care must be taken to avoid adding excess amounts
of chemicals, which might blind sand particles and lower drainage rates. Alum has been used
successfully at a  dosage  of  1 lb/100  gal  of digested sludge (1). On the other hand,
polyelectrolyte has been used at dosages as low as 0.05 lb/100 gal of digested sludge (16).

     12.3.4 Process Designs and Cost Estimates

An open drying bed at an  existing activated sludge plant was originally designed based  on a
population  equivalent of  20,000 and  a  bed area  requirement of 2 sq ft/capita  and was
loaded at a rate of 10 Ib of dry solids/sq ft/yr. As a result of upgrading secondary treatment
units, it was  necessary  to increase the  loading to  15 Ib/sq  ft/yr to  accommodate the
increased sludge quantities. Two alternatives were available for upgrading the existing drying
beds. It was possible either  to  cover the beds  or to add 1 Ib  of alum/100 gal  of digested
sludge to decrease the drying time by approximately 50 percent.

                                        12-16

-------
Covering the drying beds was estimated to cost $240,000. The estimated cost of the alum
slurry feed system and flocculation tank was $33,000.

Based on comparison of these capital costs, it appears that chemical addition may be the
most economic alternative. However, to draw a definite conclusion, it would be necessary to
compare total annual costs of both alternatives over the expected life of the facility.

12.4 Centrifugation

The use  of centrifuges for separating materials of different densities is well established as
discussed in Section 10.5. However, their use in the United States for sludge dewatering is
not as widespread as the use of vacuum filters. Recent improvements in centrifuge design
and the  availability of  full-scale  performance data have encouraged  their use for sludge
dewatering.

     12.4.1 Types of Centrifuges

There  are three general classifications  of  centrifuges  that  can be applied  to sludge
dewatering: solid-bowl,  disc, and basket. These  are illustrated  on Figure 12-2.  Typical
centrifuge characteristics are summarized in Table 12-6.
                                    TABLE 12-6
               SUMMARY OF CENTRIFUGE CHARACTERISTICS (25)

                                             Centrifuge Description
     Description

Method of Operation
Bowl Diameter, in.
Flow Rate, gpm
Solids in Feed, percent
Solids Discharged
Speed, rpm
Centrifugal Force, G
Motor Horsepower
Solid-Bowl
Continuous
6 to 60
1 to 200
*
1 to 15 tons/hr
1,000 to 6, 000
3,200 max
5 to 250
Basket
Batch
12 to 60
100 max
0.1 to 30
l,0001b-max
2,500 max
2,000 max
100 max
Disc
Continuous
8 to 30
10 to 300
0.1 to 10
10 to 3,000 gal/hr
4,500 to 10,000
12,000 max
10 to 125
*Any liquid or slurry which can be pumped.
                                       12-17

-------
               FIGURE  12-2
          TYPES OF CENTIFUGES (24)
 GEAR BOX
                              r
                                 DRIVE SHEAVE
                                   FEED
            CENTRATE     CAKE
                      DISCHARGE
         SOLID-BOWL  CENTRIFUGE
CAKE DISCHARGE •«-
                       FEED
               S3  it
                               CENTRATE
             BASKET CENTRIFUGE
                           FEED
                            CENTRATE
                                 UNDERFLOW
             DISC  CENTRIFUGE
                   12-18

-------
Solid-bowl centrifuges  are widely  used because  of their dependable  performance  and
relatively  low maintenance requirements. Solid-bowl centrifuges  are suited to dewatering
primary sludge and  mixtures of primary and waste biological sludge. For most sludges, to
achieve solids recovery in the range of 80 to 95 percent with a solid-bowl centrifuge requires
the addition of polyelectrolytes.

Unlike solid-bowl centrifuges, basket centrifuges operate on a batch basis. Because of the
large  bowl diameter, basket  centrifuges operate at slower speeds. The centrifuge can be
operated on an automatic cycle for programmed filling and skimming. Basket centrifuges are
generally applicable only for sludge dewatering at smaller plants.

Disc centrifuges are used primarily for thickening of waste  activated sludge as discussed in
Chapter 10.

     12.4.2 Process Considerations

Major process variables for centrifugation are feed rate, sludge solids  characteristics, feed
consistency,  temperature and chemical additives.  Solid-bowl  machine variables  are bowl
design, bowl speed,  pool volume  and conveyor speed  (1). Major performance factors are
cake dryness and solids recovery. To increase cake  dryness, the following actions should be
considered (1):

     1.    Increase feed rate.
     2.    Decrease feed solids concentration.
     3.    Increase temperature.
     4.    Do not use flocculants.
     5.    Increase bowl speed.
     6.    Decrease pool volume.
     7.    Decrease differential conveyor speed.

Actions which should be considered for increasing solids recovery are as follows (1):

     1.    Decrease feed rate.
     2.    Increase feed solids concentration.
     3.    Increase temperature.
     4.    Use flocculants.
     5.    Increase bowl speed.
     6.    Increase pool volume.
     7.    Decrease differential conveyor speed.

                                       12-19

-------
Most of the variables which improve cake dryness tend to decrease the solids recovery. This
is an important feature of centrifuge operation. Therefore, operation of a centrifuge should
be optimized to obtain the desired balance between cake dryness and solids recovery.

The following advantages are associated with solid-bowl centrifugal dewatering:

     1.   Capital cost is less than for vacuum or pressure filters.

     2.   The unit is totally enclosed so that odors are more readily controlled.

     3.   The unit will fit in a small space and requires a minimum of auxiliary equipment.

     4.   A wide variety of solids can be handled.

     5.   Minimum operator attention is required.

Disadvantages of solid-bowl centrifugal dewatering are:

     1.   Solids capture is often poor without the use of chemicals.

     2.   Chemical costs can be substantial.

     3.   Cake  moisture is often  higher and centrate quality lower than with vacuum
          filtration.

     4.   Maintenance costs  are high, especially if the sludge contains substantial  grit
          quantities.

     5.   Fine solids which escape in the centrate may resist settling when recycled to the
          head of the treatment plant, gradually build up in concentration and eventually
          raise effluent  solids level. However, this  should not  be  a  problem if capture
          efficiencies can be maintained above 90 percent.

     12.4.3 Design Considerations

Centrifuges should be  selected on the basis of pilo^ tests with smaller, geometrically-similar
machines.  Proper  scale-up for  predictable results  must  consider  and  provide for  the
following variables (26):

     1.   Physical nature of solids being handled

     2.   Stability of centrifuge feed
                                        12-20

-------
     3.   Solids dewatering time

     4.   Chemical flocculant dosages

     5.   Percent solids recovery

     6.   Resistance to abrasion

     7.   Wet cake discharge rate.

The  use  of a small continuous pilot centrifuge for testing purposes may not be possible if
sludge supply is limited. Several manufacturers have correlated full-scale unit performance
with "spin tests" conducted  on laboratory centrifuges. This technique has limited value in
estimating design criteria and generally is of use only to the manufacturer.

     12.4.4  Centrifuge Performance in Sludge Dewatering

Table 12-7 contains operating data for solid-bowl centrifuges for various combinations of
municipal wastewater sludges.

Raw primary and digested primary sludges dewater easily; with polyelectrolyte addition, a
centrifuge can produce 25 to 40 percent cake solids with better than 90 percent recovery.
Waste activated sludge alone  is very difficult to  dewater. When waste activated or trickling
filter sludge is added to raw  or digested primary sludges,  the cake solids content is reduced
to about 20 to  25 percent,  and the polyelectrolyte dosage to obtain 90 percent recovery
increases. Factors  responsible  for  this  loss  in efficiency  include  lower  feed  solids
concentration and the poorer dewatering characteristics of biological sludge.

The  use of  centrifuges for sludge dewatering  has been considered recently by  several
municipalities. At one large southeastern city, a  centrifuge test program was conducted to
determine the applicability  of centrifugal  dewatering of raw primary, digested primary,
co-settled raw primary  and  waste  activated, mixed  digested and primary digested plus
thickened waste  activated sludges (27). With a solid-bowl centrifuge, 55 to 85 percent
recovery was obtained without the use of polyelectrolytes, depending upon the feed rate.
Recovery levels of 85 percent or better were achieved with 0.5 to 5.0 Ib of strong cationic
poly electrolyte/ton of  dry solids for  combined raw primary  and waste activated  sludge,
primary  digested plus  waste activated sludge and mixed digested sludge. Problems were
encountered in trying to use a solid-bowl centrifuge on the combination of thickened waste
activated and primary digested sludge. Higher levels of polyelectrolyte were required as the
proportion of waste  activated  sludge to primary sludge increased. When operating with a
mixture  of  two-thirds  primary digested sludge  and one-third thickened  waste activated
sludge  on  a  dry   solids  basis,   50  to  60 percent recovery  was  achieved without
polyelectrolytes. To  increase recovery to 80 to 90 percent, polyelectrolyte dosages of 10 to
20 Ib/ton of dry solids were required.
                                        12-21

-------
              TABLE 12-7
SOLID-BOWL CENTRIFUGE PERFORMANCE DATA

Type of Sludge Capacity
gpm
Pnmary - Raw




23-26
23-36



27.5
275
27.5
Pnmary - Digested








70-140

Raw Pnmary and Trickling Filter

99-22



Digested Primary and Trickling Filter






Raw Pnmary and Waste Activated 40-80
30-80




Thickened Waste
Activated Sludse 40-60
(by Disc Onlnfup-) 30-80
digested Primary and V, astc \ctlvatcd 50-1 20
30-150





Digested Primary and Thn kcne d 40- 1 40
Waste Activated 30 80
Aerobic Digested
(Contact stabilization)
Heat Treatment Sludge
Zimpro
Porteut,
Chemical Sludges
Lime-Phosphate
Lime-Treatment in Primaries
Tertiary Phosphate Removal
(Chemical and Waste Activated)
Feed Cake
Solids Solids
percent percent
3040
30-40
25-35
28-40
30-40
9-12 28-50
912 28-50
3237
25-28
26-37
8.8
84
9.2
30-40
30-40
2430
25-35
20-30
6 22-28
6 22-28
26-30
22-30
4 > 17
4 > 17
24-30
25-35
96 23
2026
21-25
20-25
5 5 25+
5.6 20 2
2028
22-36
25
18-25
18-25
18-20
18-20
1523
19-25
18-24
18-24

5-6 15-17
5-6 15-17
22-30
2532
28 15-19
1520
15-20
18-24
1824
6 2033
6 20-22
1014
10 14

JO-45
3050

3540
40-45
1620


Recovery
percent
7080
95
90+
70-90
5090
65-80
80-98
84-93
88-95
85-96
44
84
97
70-90
95
90+
70-85
85-90
75-85
85
81-90
87-95
20-50
85
90+
65-75
96-100
82-96
83-90
85-94
40
90
90+
60-75
85
6085
95+
40-60
85
90+
5075
50-80
95

50-65
85
80-95
50-75
8590
50-60
85-100
50-70
95
40-80
85
90+
50-60

85-90
85-90

75-85
96-98
85-90

Polyclc
•clrolyte
Requirement
t/ton


2-4
None

None

64
3-5
27
None
394
572


3-6
None



8
3-7


3-6
-
4-9
5-8
4-10
6-9
None
674
4-8
-

None
8-16


5 10
None
None
6-20




None
12
None
10-85
None
10-20
' None
13 17
5-10
None

None
None

None



Ib/ton
None
5-10


1 5-2 5

1.0-2 5






None
5-10


3-6
0
05-1


None
3-8










2 5-3.5


None
4-5





6-17
11-17
24-10














10
34


Reference

27
27
27
27
27
27
27
28
28
28
29
29
29
30
30
30
30
27
27
27
28

27
27
30
30
28
28
28
28
29
29
30
30
27
28
28
27
27
30
30
31
31

27
27
27
27
30
30
30
31
31
27
27
30
30

30
30

30
27
30

                 12-22

-------
At a southwestern community, field tests were conducted to determine the applicability of
centrifugation for dewatering combined primary and secondary digested sludge (27). The
results indicated that a solid-bowl centrifuge could be used to replace concrete drying beds.
With the use of a strong cationic polyelectrolyte at a concentration of 3 to 4 Ib/ton of dry
solids, the sludge could be dewatered to 17 to 18 percent solids with a  solids recovery of
85 percent. Solids  recovery was increased  to  98 to 99 percent when the  polyelectrolyte
dosage was raised to 5 to 6 Ib/ton of dry solids.

In  El Paso,  Texas,  a land problem necessitated replacement  of sludge  drying beds (32).
Centrifuges were used to dewater the digested sludge at  a 6 to  7 percent  feed  solids
concentration. The centrifuges produced 20 to 22 percent cake solids with 85 to 90 percent
recovery, at a polyelectrolyte dosage of 2 to 3 Ib/ton of dry solids.

The use of a cationic polyelectrolyte was  evaluated for a combination of 80 percent raw
Imhoff  and 20 percent digested sludge (27). The cationic polyelectrolyte was effective in
improving  sludge dewatering at economical dosage levels  (2 to 3 Ib/ton of dry solids). With
an  average feed solids concentration of 8 percent, a cake solids of 35 percent at 95 percent
solids recovery was obtained.

     12.4.5 Use of Centrifugal Dewatering for Upgrading Sludge Handling Facilities

The performance of centrifuges in various applications clearly  indicates that centrifugation
should  be considered  when  the upgrading  of sludge  dewatering  facilities is  required.
Centrifuges can be  used to replace or supplement vacuum filters for sludge dewatering,
especially  where space  is  limited.  Where  centrifuges  are  considered for  an  upgrading
situation,  the efficiency of existing grit and screenings removal facilities  must be carefully
studied.  Solid-bowl  centrifuge  manufacturers normally recommend that  cyclonic  grit
removal be provided ahead of the centrifuge to reduce abrasion. Inadequate removal or
comminution of screenings can result in plugging of the centrifuge inlet. As centrifuges must
be periodically dismantled for maintenance,  provision for an overhead hoist is desirable.

     12.4.6 Process Design and Cost Estimates

The following example is presented to  illustrate the upgrading of sludge  handling facilities
through the use of centrifuges.

Vacuum filter facilities  at an existing activated sludge plant  were overloaded due  to  an
increase in plant flow from 10 to 20 mgd. Space limitations  at the  plant prohibited the
installation of additional vacuum filters.

It was decided to add centrifugal dewatering to handle the additional  12,000 Ib/day of dry
solids (20 gpm by volume). Facilities for  sludge  dewatering included two solid-bowl
centrifuges, each capable  of handling  15 to 20 gpm, sludge feed pumps, polyelectrolyte

                                       12-23

-------
addition facilities and other  necessary  appurtenances.  The  solid-bowl centrifuges  were
designed to produce  20 to 25 percent cake solids at 85 percent recovery, with 5 percent
feed solids and a polyelectrolyte dosage of 3 to 6 Ib/ton of dry solids. The capital cost for
this upgrading procedure was estimated at $256,000.

12.5  Filter Presses

A variety of filter presses have been used to dewater sludge. The most commonly used type
consists of a series of rectangular plates, recessed on  both sides, and supported face to face
in a vertical position on a frame with a fixed and movable head. A filter cloth is hung or
fitted over each plate.  The plates are held together with sufficient force to withstand the
pressure applied during the filtration process. Hydraulic rams or powered screws are used to
hold the plates together.

In operation, chemically conditioned sludge is pumped into the space between the plates at
a pressure of 60 to 180 psig. Under this pressure, the liquid is forced through the filter cloth
and  plate  outlet ports. The plates  are then separated and  the sludge  drops  to a hopper
below. Filtrate normally is returned to the headworks of the treatment plant.,The sludge
cake  thickness  varies  from 1  to  1-1/2 inches and  the moisture  content from  55 to
70 percent. A complete filtration cycle includes time required for pressing, cake removal,
media washing and press closing. Total filtration time varies from three to six hours with
pressing time ranging from one to three hours.

The  major operating costs  associated with this method of dewatering are those for chemical
conditioning and maintenance  and  replacement of filter cloths. Although not commonly
used in the United States, filter presses have been used extensively in Europe.

The advantages of filter presses  are as follows:

     1.   Low  cake  moisture  permits  incineration  of   primary/secondary  sludge
          combinations without auxiliary fuel.

     2.   Continuous operating attendance is less than that required for vacuum filters.

     3.   A large filtration area can be installed in a minimum of floor area.

     4.   Hard to dewater sludges can  be handled more readily.

Major disadvantages are as follows:

     1.   Capital costs are considerably higher than for centrifuges or vacuum filters.

     2.   Batch  discharge  requires  equalization  of pressed  cake production prior to
          incineration.
                                         12-24

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12.6 References

 1.  Burd, R.S., A Study of Sludge Handling and Disposal. Federal Water Pollution Control
    Administration, Publication WP-20-4 (May, 1968).

 2.  Sherwood, R.J., and Dahlstrom, D.A.,  Economic  Costs  of Dewatering Sludges by
    Continuous Vacuum Filtration. Presented at the 65th Annual Meeting of the American
    Institute of Chemical Engineers, New York, N. Y. (November, 1972).

 3.  Tenney, M.W., Echelberger,  W.F.,  Jr.,  Coffey, J.J.  and McAloon, T.J., Chemical
    Conditioning of Biological Sludges  for  Vacuum Filtration. Journal Water Pollution
    Control Federation, 42, No. 2, Part 2, pp. Rl-20 (1970).

 4.  Schepman, B.A., and Cornell, C.F., Fundamental Operating Variables in Sewage Sludge
    Filtration. Sewage and Industrial Wastes, 28, 1443 (1956).

 5.  Ettelt,  G.A.,  and  Kennedy,  J., Research  and Operational Experience in Sludge
    Dewatering at Chicago. Journal Water Pollution  Control  Federation, 38, No.  2, pp.
    248-257(1966).

 6.  Sludge  Dewatering. Water Pollution Control Federation Manual of Practice No. 20,
    Washington, B.C. (1969).

 7.  Ford, D.L., General Sludge Characteristics. Included in Water Quality Improvement by
    Physical Chemical Processes. Edited by E. Gloyna and W.W. Eckenfelder, Jr., Austin,
    Texas — University of Texas Press (1970).

 8.  Malina,, J. F., Sludge Filtration  and Sludge Conditioning. Included in Water Quality
    Improvement  by  Physical  Chemical Processes. Edited  by  E.  Gloyna and  W.W.
    Eckenfelder, Jr., Austin, Texas — University of Texas Press (1970).

 9.  Eckenfelder, W.W.,  and O'Connor, D.J., Biological  Waste Treatment.  New York:
    Pergamon Press (1961).

10.  Sludge Conditioning with Purifloc. Dow Chemical Company (1966).

11.  Young, K., Status  of UNOX Sludge Pretreatment and Dewatering.  Linde Division of
    Union Carbide Corporation (September, 1971).

12.  McDowell,  M.A.,   Vahldieck, N.P., Wilcox,  E.A.,  and  Young,  K.W., Continued
    Evaluation of Oxygen  Use in  the Conventional Activated Sludge Process. U. S. EPA
    Contract No. 14-12-867, Project No. 17050 DNW (February, 1972).
                                      12-25

-------
13. Sherbick, J.M., Synthetic Organic  Flocculants Used for Sludge Conditioning. Journal
    Water Pollution Control Federation, 37, No. 8, pp. 1,180-1,183 (1965).

14. Hopkins, G., and Jackson, R., Polymers in the Filtration of Raw Sludge. Journal Water
    Pollution Control Federation 43, No. 4, pp. 689-698 (1971).

15. Statistical Summary 1968 Inventory Municipal Waste Facilities in the United States.
    Federal Water Quality Administration: Government Printing Office (1971).

16. Jennett, J.C., and  Santry, I., Jr.,  Characteristics  of Sludge  Drying.  Journal of the
    Sanitary Engineering Division, ASCE, 95, No. 5, pp. 849-863 (1969).

17. Quon, J., and Johnson, G., Drainage Characteristics of Digested Sludge. Journal of the
    Sanitary Engineering Division, ASCE, 92, No. 2, pp. 67-82 (1966).

18. Randell, C.W., and Koch, C.T., Dewatering Characteristics of Aerobically Digested
    Sludge. Journal Water Pollution Control Federation, 41, No. 5, Part 2, pp. R215-238
    (1969).

19. Jennett, J.C., and Harris,  D.J.,  Environmental Effects on  Sludge  Drying Bed
    Dewatering. Journal Water Pollution Control Federation, 45, No. 3, 449 (1973).

20. Recommended Standards for Sewage Works. Great Lakes-Upper  Mississippi River
    Board of State Sanitary Engineers (1971).

21. Nebiker, J., Drying of Wastewater Sludge in the Open  Air. Journal Water Pollution
    Control Federation, 39, No. 4, pp. 608-626 (1967).

22. Adrian, D.D., Dewatering Sludge on Sand Beds. Presented at the 65th Annual Meeting
    of the American Institute of Chemical Engineers, New York, N. Y. (November, 1972).

23. Nebiker, J.H., Sanders, T.G., and Adrian, D.D., An Investigation of Sludge Dewatering
    Rates. Journal Water Pollution Control Federation, 41, No. 8, Part 2, pp. R255-R266
    (1969).

24. Lawson, George, R., Equipment and Chemicals - An Approach to Water Pollution.
    Investment Dealer's Digest (August 5, 1969).

25. Townsend,  Joseph,  What  the  Was'ewater  Plant  Engineer Should  Know  about
    Centrifuges. Water and Wastes Engineering, 6, No. 11, pp. 41-44 (1969).

26. White,  W.F.,  Fifteen  Years  of   Experience  Dewatering  Municipal  Wastes with
    Continuous Centrifuges. Bird Machine Company, Inc.

                                       12-26

-------
17.  Private  communication with George Patenaude, Philadelphia District Representative,
     Sharpies-Stokes Division, Pennwalt Corporation, Wynnewood, Pennsylvania (October
     27, 1970).

28.  Albertson, 0., and Guidi, E., Centrifugation of Waste Sludges. Journal Water Pollution
     Control Federation, 41, No. 4, pp. 607-628 (1969).

29.  Hercofloc Flocculant Polymers for Use in Sludge Conditioning. Hercules Incorporated,
     Environmental Services Division, Bulletin ESD-102A, Wilmington, Delaware (1969).

30.  Private  communication with  Gene  Guidi,  Sales  Manager,  Environmental Control
     Equipment, Bird Machine Company, Walpole, Massachusetts (February 22, 1971).

31.  Albertson, 0., and Guidi, E., Advances in the Centrifugal Dewatering of Sludges. Water
     and Sewage Works, 114, No. 11, pp. 133-142 (1967).

32.  El Paso Loses Drying Beds in Boundary Action. Water and Sewage Works, 117, No. 2,
     pp. 26-27 (1970).
                                      12-27

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                                   CHAPTER 13

              CASE HISTORIES OF TREATMENT PLANT UPGRADING
13.1   Case History No.  1  -  Use of Roughing Filter to  Upgrade an Existing  Low-Rate
       Trickling Filter Plant (1) (2) (3)

Case History No. 1 involves the upgrading of an existing  low-rate trickling filter plant in
Huber  Heights, Ohio. The original plant  was designed in August, 1956, for a flow of
0.7 mgd, with 85 percent BOD and SS removals. The community developed so rapidly that
by 1970, the average flow had increased to 2.3 mgd. The flow diagrams for the original and
upgraded plants are shown on Figure 13-1.

Operating and performance  data for the overloaded plant for  1962, when  the  plant was
receiving 1.15 mgd, are compared with corresponding data after the plant was upgraded to
2.3 mgd in Table 13-1.

The comminutor and primary clarifiers were replaced with three Hydrasieve units of 1-mgd
capacity each. These units are stationary screens capable of removing 20 to 35 percent of
the BOD and SS in raw wastewater. A Hydrasieve unit is illustrated on Figure 13-2, along
with a flow diagram through the unit. These screens generally require  no power and little
maintenance; however, a head loss does occur across the units.

The plastic-media roughing filter used in the upgrading operates at an application rate of
approximately 2.5 gpm/sq ft.  Present BOD  removal is about 25 to 35 percent across the
roughing unit. Because of the  increased hydraulic loading, it was necessary to expand the
secondary clarification  and chlorine contact tank  capacities.  The  abandoned primary
clarifiers were converted to  sludge thickeners. This step, in addition to conversion of the
low-rate anaerobic digester to a high-rate unit using gas recirculation for mixing, enabled the
sludge handling system to process the increased quantity of sludge produced.

This case history emphasizes that an existing plant  may be gradually upgraded to handle a
three-fold increase in flow with the use of innovative techniques and newly applied process
equipment.  The capital costs  for upgrading the capacity  of the plant were estimated at
approximately $352,000.

13.2   Case History No. 2 - Upgrading an Existing High-Rate Trickling Filter by Conversion
       to a Super-Rate Filter System (4)

The North Treatment Plant at Sedalia, Missouri, a high-rate trickling filter plant designed for
1.25 mgd, was achieving 85 percent BOD removal in  1963. However, the State of Missouri
                                       13-1

-------
                                                FIGURE  13-1
                                              CASE HISTORY  NO.l
                       COMPARISON OF ORIGINAL AND UPGRADED FLOW DIAGRAMS
              LEGEND
ORIGINAL PLANT
                                                  UPGRADED PLANT
                WASTEMTER
         	 SLUDGE

             LOW-RATE
             ANAEROBIC
             DIGESTER
cw
        DRYING
          BEDS
          ULTIMATE DISPOSAL
                 FINAL
                 CLAFIFiERS
SLUDGE  THICKENERS
   /CONVERTED
    PRIMARY
   \CLARIFIERS
        GRIT REMOVAL
        COMMINUTION
                    ANAEROBICf     )
                    DIGESTER V7
                                                    DRYING
                                                     BEOS
                                                         ULTIMATE
                                                         DISPOSAL
                                     CHLORINE CONTACT
                                     TANK
HYDRASIEVE
                                                                                        NEW
                                                                                        PLASTIC  MEDIA
                                                                                        ROUGHING FILTER
                                                               FINAL
                                                               CLARIFIERS
                                                               (ONE NEW)
                                                        CHLORINE CONTACT
                                                        TANK

-------
                                   TABLE] 3-1
      CASE HISTORY NO. 1 - PLANT OPERATING AND PERFORMANCE DATA

                Description                    Before Upgrading     After Upgrading
                                                  (1962)

Average Flow Rate, mgd                                1.15               2.3
Primary Clarifier
  Overflow Rate 1, gpd/sq ft                        1,170
  Hydrasieve Slot Size, in.                              —                  0.06
  BOD Removal, percent                              353                254
  SS Removal, percent                                 -  5              224
Plastic Media Roughing Filter
  Hydraulic Loading6, gpm/sq ft                        —                  2.5
  Organic Loading6, Ib BOD/day/1,000 cu ft             -               520
  Recirculation Ratio                                  —                «2.0
  BOD Removal, percent                               -                 30
Trickling Filter (Stone Media)
  Hydraulic Loading, mgd/acre                          6.0               12.0
  Organic Loading, Ib BOD/day/1,000 cu ft              56.2               87.0
Final Clarifiers
  Overflow Rate, gpd/sq ft                          1,170               750
Overall Plant Performance
  BOD Removal, percent                              83                 85
  SS Removal, percent                                 —  ^              84
  Effluent BOD, mg/1                                 41                 37
  Effluent SS, mg/1                                    -  5              40
^ Based on average flow rate.
2 Primary clarifiers converted to gravity thickeners.
* Based on primary clarifier performance.
4 Based on hydrasieve performance only.
5 Performance data not available.
" Including recirculation.
                                      13-3

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                           FIGURE 13-2
                    HYDRASIEVE SCREENING UNIT
                 ,-1 y
COURTESY OF THE BAUER BROS. CO. - SPRINGFIELD, OHIO
                                 13-4

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Water Pollution Board set a new final effluent BOD requirement of 20 mg/1, which Sedalia
could not meet with the existing facilities. The  1963 plant flow diagram is illustrated on
Figure 13-3.

The plant was upgraded to treat an average design flow of 2.5 mgd. The existing stone-media
filter was renovated to operate with plastic media. In addition, a second plastic-media filter
was constructed.  The  two plastic-media filters are  operated  in  parallel with a total
recirculation  ratio of 1.55.  One additional primary clarifier and one additional secondary
clarifier were installed.

To remove additional BOD and SS, a shallow aerobic polishing lagoon was constructed after
the secondary clarifiers, and a vacuum filter was added to dewater the additional volume of
digested sludge. A flow diagram of the upgraded  plant is also  shown on Figure 13-3. Table
13-2 contains  a summary of operating and performance data  for the 1963 overloaded
period,  along with the upgraded design criteria and actual operating  and performance data
for the  post-upgrading period. It should be noted  that the effluent BOD was improved from
115 mg/1 to 11 mg/1 after upgrading, which is considerably below the 20 mg/1 requirement.

The capital costs of upgrading the plant were estimated at $3,055,000.

13.3   Case History No.  3 - Upgrading Using Polyelectrolyte Addition Before the Primary
       Clarifier (5)

The Easterly Wastewater Treatment Works in Cleveland, Ohio, is a conventional activated
sludge plant whose dry-weather design flow is 123 mgd. In 1968, the plant was hydraulically
overloaded. Operating data from the 1968 control period are presented in Table 13-3. It is
interesting  to note that  the overflow rate of the  primary clarifiers was  2,030 gpd/sq ft,
which  is substantially above  normally accepted  values.  As a result of  the hydraulic
overloading, the overall BOD and SS removals were only 79 and 85 percent, respectively.

To improve the overall plant performance, a polyelectrolyte addition program was initiated.
An anionic polyelectrolyte, Purifloc A-23, was added at an average dosage of 0.21 mg/1.
Since  proper  polyelectrolyte  dispersal and uniform mixing  into the  entire  waste flow
constitute an extremely important aspect of the flocculation process, it was decided to  add
the polyelectrolyte at the plant's two Venturi meters. These meters are located immediately
after the grit  chamber and in front of the preaeration basin.  Dye studies indicated that there
was a 7.5-minute travel time between the  Venturi meters and  the primary clarifiers. Six of
the 7.5  minutes were spent  in the preaeration basin. The gentle agitation in the preaeration
basin provided adequate flocculation of wastewater solids.
                                       13-5

-------
                                               FIGURE 13-3
                                           CASE HISTORY NO.2
                   COMPARISON OF ORIGINAL AND UPGRADED FLOW DIAGRAMS
                 LEGEND
                - HASTEWATER
                -- SLUDGE
             OVERLOADED PLANT
OJ
             ANAEROBIC
             DIGESTION
                ORYI
                BED
NG
                          GRIT REMOVAL
                          COMMINUTION
                                r

                           —4
                A,
       PRIMARY
"\JCLARIFIER
  0
                        T
                      ULTIMATE
                      DISPOSAL


             NOTE: CONVERTED TO USE PLASTIC MEDIA.
                                             UPGRADED PLANT
                                                                           r-
                                   ANAEROBIC
                                   DIGESTION
         .__-_**
                                                   DRYING
                                                   BEDS
                       SECONDARY
                       CLARIFIER
I	*-l
I           I
      NEW.—A-
   VACUUM
   FILTER
                                                              ULTIMATE
                                                              DISPOSAL
                EXISTING
                TRICKLING
                FILTER
                                                          REMOVAL
                                                          NUTION

                                                         PRIMARY
                                                         CLARIFIERS
                                                         (ONE NEW)
                                                            NEW
                                                            PLASTIC-
                                                            MEDIA
                                                            FILTER
                                                         SECONDARY
                                                         CLARIFIERS
                                                         (ONE NEW)

                                                        NEW  SHALLOW
                                                        AEROBIC
                                                        POLISHING
                                                        LAGOON

-------
                                  TABLE 13-2
  CASE HISTORY NO. 2 - PLANT OPERATING, PERFORMANCE AND DESIGN DATA


                                           1963                      1969
                                        Operating and              Operating and
                                         Performance   Upgraded    Performance
               Description                  Data         Design        Data

Average Daily Flow, mgd                         1.25          2.5         1.80
Raw Waste water BOD, mg/1                    768          576        450
Primary Clarifiers
  Overflow Rate1, gpd/sq ft                  1,000        1,000        720
  BOD Removal, percent                       40           40         60
Trickling Filters
  Hydraulic Loading^, mgd/acre                 25           32         23
  Organic Loading2, Ib BOD/day/1,000 cu ft    226           73         30
  Recirculation Ratio                           1.0          1.55        1.55
Final Clarifiers
  Overflow Rate1 gpd/sq ft                   755          755        545
  Secondary BOD Removal, percent              75           93.2       86.8
Polishing Lagoon (Shallow Aerobic)
  Maximum BOD Loading, Ib BOD/acre/day      -            68         30
  BOD Removal, percent                       -            12         54
Vacuum Filtration Rate, Ib/sq ft/hr              -             5.0         -  3
Overall Plant Performance
  BOD Removal, percent                       85           96.5       97.7
  Effluent BOD, mg/1                        115           20         11
1 Based on average daily flow.
2 Including recirculation.
^ Lack of sufficient operating data.
                                     13-7

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                                   TABLE 13-3
      CASE HISTORY NO. 3 - PLANT OPERATING AND PERFORMANCE DATA
                                              1968               Polyelectrolyte
                                             Control             Demonstration
                Description                   Period                  Period

Influent BOD, mg/1                              104                    67
Influent SS, mg/1                                169                   157
Primary Clarifier
   Overflow Rate, gpd/sq ft                     2,030                 2,170
   BOD Removal, percent                          31                    46
   SS Removal, percent                            31                    51
   Sludge Solids Concentration, percent               4.1                    4.3
   Sludge Volume Pumped, million gallons/month      5.0                    6.8
Aeration Tank
   MLSS, mg/1                                1,670                 1,602
   Organic Loading, lb BOD/day/lb MLSS             0.48                   0.29
   Dissolved Oxygen, mg/1                           3.2                    3.8
   Waste Activated Sludge Concentration, percent      2.4                    2.0
   Waste Activated Sludge Pumped,
   million gallons/month                          12.3                    9.8
Overall Plant Performance
   BOD Removal,, percent                          79.1                   83.4
   SS Removal, percent                            85.3                   89.2
   Effluent BOD, mg/1                             21.8                   11.1
   Effluent SS, mg/1                               24.8                   17.0
A summary of the effectiveness of the poly electrolyte addition on plant performance as
compared to performance during the previous control period is also presented in Table 13-3.
The improvement in primary SS removal increased the volume of primary sludge from 5.0
to 6.8 million gallons per month. Overall plant performance was improved, as noted by the
reduced  effluent  BOD and  SS concentrations.  In  addition to the increased treatment
efficiency,  the polyelectrolyte addition was responsible for the  following benefits to the
downstream activated sludge process:

     1.   A 20 percent volume decrease in waste activated sludge production

     2.   A 22 percent reduction in air supply requirements, resulting in a power cost
         savings of over $3,300 per month

                                     13-8

-------
     3.   An increase in aeration tank  DO  concentration from an average of 3.2 mg/1 to
         3.8 mg/1.

An economic  comparison  was made  between  polyelectrolyte addition and  providing
additional tankage to equal the performance of the flocculation system. The amortized cost
for the additional tankage  was about  $369,000 per  year, while the  chemical  cost was
$158,000 per  year, thereby  indicating a  considerable yearly savings in  favor of  the
polyelectrolyte alternative.

13.4   Case History  No. 4 - Upgrading a Trickling Filter Plant by Adding Activated Sludge
       Treatment and Pre- and Post-Chlorination

In 1967, the Livermore, California Wastewater Treatment Plant was upgraded to increase
plant capacity from 2.5 to 5.0 mgd and to provide a higher degree of treatment (6). All of
the existing treatment facilities were used in the upgraded treatment process. Flow diagrams
that show the type, number and arrangement of process units before and after upgrading are
presented on Figure 13-4.

The original plant was constructed in 1958 to provide  secondary treatment for a domestic
wastewater flow of 2.5 mgd. Effluent standards in effect at that time required that the plant
produce  an effluent  that contained no  more than 40 mg/1 of BOD and 40 mg/1  of SS. To
achieve this degree of treatment, preliminary and primary treatment facilities, a stone-media
trickling  filter,  a final clarifier and a 30-day polishing pond were provided. Waste sludge was
stabilized by anaerobic digestion and dewatered  on sludge drying beds. This  treatment
process produced an effluent that contained 45 to 50 mg/1 of BOD and 45 to 50 mg/1 of SS.

The upgraded  plant was designed  to produce an  effluent that contained not more  than
20 mg/1 of BOD, 20 mg/1 of SS and 1 mg/1  of grease. Bacteriological requirements limited
the average total  coliform count to not more than 5 MPN per 100 ml  over a five-day period.
To meet  these design criteria, the plant  facilities were expanded to provide activated sludge
treatment following first-stage trickling filtration along with pre- and post-chlorination. As
indicated on  Figure 13-4, the existing grit chambers were adequate for the increased flow.
Sufficient primary clarification  capacity at the higher flow was provided by converting the
existing final clarifier to a primary clarifier. An additional stone-media trickling filter was
constructed to provide for the increased hydraulic loading. To  improve the  degree  of
treatment,  two new aeration  tanks,  a  new  larger final clarifier  and a new chlorination
contact tank were added to the treatment sequence. The polishing pond was converted to an
emergency holding basin from  which any substandard effluent could be recycled through
the treatment  plant. The sludge handling and treatment  system was  designed to return
excess waste activated  sludge to the head  end of the plant, and to anaerobically digest
combined primary and waste activated sludge. The existing sludge drying beds and two new
sludge lagoons  were  used for dewatering the  digested  sludge. A cost saving feature of the
upgraded plant is that trickling filter effluent  is fed directly to the aeration tanks without
intermediate clarification.
                                        13-9

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                                     FIGURE  13-4
                                CASE HISTORY  NO.4
       COMPARISON OF  ORIGINAL AND UPGRADED FLOW DIAGRAMS
                                                                         EFFLUENT TO
                                                                         POLISHING POND
                                                                                    DRV CAKE
                                                                                    TO LANDFILL
RAW
»ASTE*AT£R
                                      BEFORE UPGRADING
                                         RECIRCULATION
                    (1 EXISTING,  I FINAL
CONVERTED TO PRIHARl),
i
EXISTING
AERATED
GRI T CHAMBERS


PRIMARY
CLARIFIERS


                WASTE
                SlUOGE
                         COMBINED
                         PRIHARY
                         AND
                         HASTE
                         SLUOGE
                                                                                  EFFLUENT
 /EXISTING \
J ANAEROBIC  )—»
 V DIGESTERS J
                                          FILTRATE OR SUPERNATANT

                                      AFTER UPGRADING
                                           13-10

-------
Design conditions before and after  upgrading  are presented in Table 13-4. A summary of
treatment performance before and after upgrading is presented in Table 13-5.

As indicated in Table 13-5,  the  plant is now producing an effluent that well exceeds the
effluent  standards for which it was designed. The effluent concentrations of BOD and SS
represent,  respectively,  96.6   and  94.3 percent   removals   of  the  raw  wastewater
concentrations of these two constituents.

The plant is presently  achieving  99 percent  oxidation  of ammonia nitrogen.  This  is
important, not only because  of the oxygen demand associated with ammonia nitrogen, but
also because  the presence of  ammonia compounds would require excessive chlorine dosages
to achieve the required high levels of disinfection.

The plan for upgrading requires that the existing digesters operate as high-rate units to
accommodate the increased  quantity of sludge. Under present operating conditions, each
digester is loaded at an average rate  of 0.22 Ib of dry solids/cu ft/day. At this loading rate,
approximately 54 percent reduction in volatile  solids is achieved and the digested sludge
contains 1.6  percent solids by weight. This low concentration of solids coupled with the
lack of mechanical cleaning facilities has caused some difficulty  in attaining optimum use of
the sludge drying beds.  Accordingly, most of the digested sludge is dewatered in the sludge
lagoons.  The recycled flow from the sludge lagoons has  caused some difficulties in plant
operation. For these reasons, various plans for upgrading the sludge treatment and disposal
system are now under consideration (7).

The cost of upgrading the plant was $1,950,000, and the annual operating costs for 1970
were estimated at $227,840, exclusive of administrative costs.

13.5  Case  History  No. 5  - Upgrading a Primary Treatment Plant to Provide Tertiary
       Treatment (8)

The Central   Contra Costa  Sanitary  District  of  Walnut  Creek,  California, undertook
plant-scale studies to determine the best method of upgrading a primary plant to produce an
effluent  that  would be  acceptable for industrial cooling water use. The findings of  this
investigation  indicated that if the existing plant facilities were modified and expanded to
provide carbonaceous and nitrogen oxidation,  denitrification  and filtration, the effluent
would be acceptable for the intended use. Flow diagrams for the existing and  proposed
plant are shown on Figure 13-5.

Operating conditions for the existing plant and proposed design parameters for the upgraded
plant are shown in Table 13-6. Most of the proposed design parameters are based on the
results obtained from the plant-scale studies.
                                       13-11

-------
                                  TABLE 13-4
      CASE HISTORY NO. 4 - PLANT OPERATING AND DESIGN CONDITIONS
                Description

Pretreatment Facilities Capacity, mgd

Preaeration Tanks
  Number of Units
  Detention Time, hr
  Air Supplied per tank, cfm
  Hydraulic Capacity, mgd

Primary Clarifiers
  Number of Units
  Overflow Rate, gpd/sq ft^
  Hydraulic Capacity

Trickling Filters
  Number of Units
  Hydraulic Loading, mgd/acre
  Organic Loading, Ib BOD/day/acre-ft
  Recirculation Ratio

Aeration Tanks
  Number of Units
  Detention Time, hr
  Volumetric Loading, Ib BOD/day/1,000 cu ft
  Sludge Recycle, percent1

Final Clarifier
  Number of Units
  Detention Time, hr
  Overflow Rate, gpd/sq ftl

Polishing Pond
  Number of Units
  Detention Time, days
  Organic Loading, Ib BOD/day/acre-ft
Operating
Conditions
  Before
Upgrading

       2.5


       2
       0.6l
    200
      10

       2
   1,050
      10
       1
       2.0
    822

       1
      30
      28
  Design
Conditions
  After
 Upgrading

      5.0


      2
      0.62
    150
     10

      2
  1,050
     10
2
34.5
4,600
1.5 to 3.0
2
34.5
4,400
1.5 to 3.0
      2
      5.2
     28
     10 to 100

      1
      2.75
    787
                                     13-12

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                            TABLE 13-4 (Continued)
                                                Operating
                                               Conditions
                                                 Before
                                                Upgrading
                                                      2
                                                      0.07
               Description

Anaerobic Digesters
  Number of Units
  Loading, Ib dry solids/cu ft/day

Chlorine Contact Tank
  Number of Units
  Detention Time, hr
Sludge Drying Beds
  Number of Units
  Total Area, sq ft
Digested Sludge Lagoons
  Number of Units
  Volume each, 1,000 cu ft

1 Only one  tank in service.
2 Both tanks in service.
3 Average dry weather flow.
                                  TABLE 13-5
      SUMMARY OF TREATMENT PERFORMANCE FOR CASE HISTORY NO. 4
                                                      4
                                                 22,400
      Design
    Conditions
      After
    Upgrading
          2
          0.22

          1
          1.0

          4
     22,400

          2
        320
       Parameter

Average Flow, mgd
Effluent BOD, mg/1
Effluent SS, mg/1
NHg-N, mg/1
N03-N, mg/1
Conforms, MPN/100 ml
Grease, mg/1
                                      Measured Performance
                                         Before Upgrading

                                                2.5
                                              45-50
                                              45-50
                                                 _ 1
                                                 _ 1
Measured Performance
   After Upgrading^

          3.37
          7.3
         13
          0.14
         21.5
          2.5
          0.23
1 Before upgrading, the plant produced no significant nitrification.
^ Monthly average.
                                     13-13

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co
                                                  FIGURE 13-5

                                                CASE HISTORY NO.5

                        COMPARISON OF ORIGINAL  AND UPGRADED FLOW DIAGRAMS
SCREENED
RA* 	 ».
WASTEWATER
AERATED
GRIT
CHAMBER



PRIMARY
CURIFI ERS
i


CHLORINE
CONTACT
TANK
PRIMARY
SLUDGE
/ ANAEROBIC\
( DIGESTORS f"
	 * TO SLUDGE LAGO
                                                                             EFFLUENT
                                               BEFORE UPGRADING
                                                                                                       EFFLUENT TO
                                                                                                      ^-INDUSTRIAL
                                                                                                       REUSE
                                                                                            >• EFFLUENT TO
                                                                                              RECEIVING WATER
                          WASTE SLUDGE
                                                    AFTER UPGRADING

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                                  TABLE 13-6
      CASE HISTORY NO. 5 - PLANT OPERATING AND DESIGN CONDITIONS
                Description

Preliminary Treatment (Bar Screen, Raw
 Wastewater Pumps) Average Capacity, mgd
Preaeration-Grit Removal Tanks
  Detention Time (ADWF1), hr
  Design Flow, mgd
Primary Clarifiers
  Number of Units
  Detention Time (ADWF), hr
  Overflow Rate (ADWF), gpd/sq ft
Aeration and Nitrification Tanks
  Number of Units
  Detention Time, hr
  Volumetric Loading, Ib BOD/day/1,000 cu ft
Intermediate Clarifiers
  Number of Units
  Detention Time (ADWF), hr
  Overflow Rate (ADWF), gpd/sq ft
  Overflow Rate (peak flow), gpd/sq ft
Denitrification  Tanks
  Number of Units
  Detention Time (ADWF), minutes
Final Clarifiers
  Number of Units
  Detention Time (ADWF), hr
  Overflow Rate (ADWF), gpd/sq ft
  Overflow Rate (peak flow), gpd/sq ft
Effluent Polishing Filters
  Number of Units
  Filtration Rate (ADWF), gpm/sq ft
  Backwash Water Rate, gpm/sq ft
   Maximum Rate
   Minimum Rate
                                     13-15
Operating
Conditions
  Before
Upgrading
     31

      0.5
     31
   1.5-1.62
 1,040-1,200
  Design
Conditions
   After
 Upgrading
     30

      0.37
     30

      4
      2.4
    720

      2
      6.8
     27.3

      4
      5
    788
  2,000

      2
    103

      4
      5
    788
  2,000

      4
      4.0

     25
     10

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                              TABLE 13-6 (Continued)
                Description

Sludge Digesters
  Number of Units
  SRT, days
  Loading, Ib dry solids/cu ft/day

Sludge Dewatering and Incineration
  Centrifuges, Number of Units
   Rate, gpm
   Polymer dosage, Ib/ton of dry solids
  Incinerators, Number of Units
   Furnace Capacity, Ib/hr
Sludge Drying Beds
  Number of Units
  Total Area, sq ft
Sludge Lagoons
  Number of Units
  Capacity, 1,000 Ib dry solids

Chlorination, Ib/day
Operating
Conditions
   Before
Upgrading
       4
      25
       0.15
       4
  20,000

       2
  15,600
  18,000
  Design
Conditions
  After
 Upgrading
                       2
                     100
                     4-5
                       3
                  51,200
  ADWF = Average dry weather flow.
  Varies from tank to tank.
The original primary treatment plant was constructed in 1948, with expansions in 1957 and
1964 to increase  the plant capacity to  31 mgd.  Pretreatment including pre-chlorination,
screening, and grit removal, followed by primary sedimentation and chlorine disinfection
produced an effluent with 144 mg/1 of BOD. Sludge produced in the primary tanks was
anaerobically digested and then discharged to sludge lagoons and drying beds.

The upgraded plant is designed to produce an effluent that is suitable for either industrial
reuse or discharge into receiving waters. As indicated on Figure 13-5, the design calls for the
                                      13-16

-------
addition of lime to the  wastewater flow, after screening. The plant-scale field studies
indicated  that when lime is mixed  with the wastewater  in the aerated grit chambers, it
combines  with  phosphorus  and  other substances to form  a floe  that  improves  the
coagulation  of solids.  As a result, increased BOD, SS and phosphorus removals may be
expected in  the primary clarifiers.  Effluent from the primary tanks will be pumped to the
aeration-nitrification tanks,  where carbonaceous organics and ammonia  nitrogen will be
simultaneously oxidized. The increased BOD removal accomplished in the primary clarifiers
due to  lime addition  lowers the  organic  loading on  the aeration  tanks and is the  key
upgrading feature that  will permit nitrification in a single-stage activated sludge system. The
previously   mentioned  plant-scale  studies also  indicated  that  recarbonation  of  the
lime-treated primary effluent prior to entering the aeration tanks was  not necessary when
the lime clarification process was operated at a pH of 11.0  or less, due to the C02 and nitric
acid produced in the nitrification reactor.

Nitrified effluent from the intermediate clarifiers will be fed to a stirred anaerobic reactor
for biological  denitrification.  Methanol  will  be  added  as  an  energy source for  the
denitrifying organisms. Following denitrification,  the  wastewater passes  through a short
detention  aerobic polishing  reactor for  oxidizing residual  methanol and  for stripping
nitrogen gas formed prior to final clarification. After final clarification, the effluent will be
chlorinated  and the portion required  for  industrial use pumped  to dual-media polishing
filters and final chlorine disinfection. Any remaining effluent will be discharged  to the
receiving water.

The sludge handling and treatment system  will be upgraded and expanded  to accommodate
the increased quantities of sludge. Waste  biological sludge will be returned to the plant
influent ahead of the point of lime addition and settled in the primary tanks together with
the chemical-primary  sludge. The existing sludge digesters will be modified to serve as
holding and mixing tanks for the combined sludge. The blended sludge will be classified and
dewatered by two-stage centrifugation prior to incineration in multiple-hearth furnaces.

The upgraded plant will provide  for  an average  dry  weather  flow capacity of  45 mgd
through the primary treatment  units, and 30 mgd through the remainder of the plant.  The
design and layout for  this upgrading were planned such that subsequent plant expansions
will ultimately provide the capacity to treat a future average dry weather flow of 120 mgd.
All hydraulic structures for  the primary and secondary treatment facilities are designed to
carry the ultimate maximum wet weather flow of 300 mgd.

Design  criteria for the existing and the upgraded plant are presented in Table 13-6. A
summary  of  the treatment plant  performance  before  upgrading and  the  anticipated
performance after upgrading is  given in Table 13-7. Costs for the upgrading are presented in
Table 13-8.
                                       13-17

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                                   TABLE 13-7
      SUMMARY OF TREATMENT PERFORMANCE FOR CASE HISTORY NO. 5
                                 Measured Performance     Anticipated Performance
       Parameter                     Before Upgrading          After Upgrading 1

Average Design Flow, mgd                    31                     30
Effluent BOD, mg/1                       103-137                    2
Effluent SS, mg/1                          57-64                     1
Effluent Total Nitrogen, mg/1                  -                       2
Effluent Total Phosphorus, mg/1               —                       0.2
  After effluent polishing for industrial reuse.
                                  TABLE 13-8
       ESTIMATED COSTS FOR CONSTRUCTION FOR CASE HISTORY NO. 5


                  Description                                     Estimated Cost
Preliminary Treatment Works                                       $   680,000
Preaeration-Grit Removal Structure                                      540,000
Primary Clarifiers                                                     920,000
Aeration and Nitrification Tanks                                       4,480,000
Aeration Blower Building and Equipment                               1,620,000
Intermediate Clarifiers                                                1,710,000
Denitrification Tanks                                                  860,000
Final Clarifiers                                                      1,670,000
Primary Effluent and Final Effluent Pumping Structure                    3,430,000
Incineration and Dewatering Building and Equipment                     4,000,000
Chemical Storage Area                                                 650,000
Dual-Media Filters                                                    1,900,000
Effluent Storage, Chlorination and Pumping Facilities                     2,380,000
Administration Building Laboratory                                    1,330,000
Maintenance Building                                                  610,000
Utility Tunnel                                                        950,000
Outside Piping and Site Development                                   1,400,000

     Total Construction Cost                                      $29,130,000
                                     13-18

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13.6   Case History No. 6 - Upgrading a Trickling Filter Plant in Stages to an Activated
       Sludge Plant with Roughing Filters (6)

The original South Buffalo  Creek  Wastewater  Treatment  Plant  in  Greensboro, North
Carolina, was built in 1931 for an average flow of 3.25 mgd. This facility provided primary
clarification and secondary treatment using fixed-nozzle square-tank trickling filters. Sludge
was digested anaerobically and dewatered on sludge drying beds.

The existing plant was first upgraded in 1957 when treatment efficiency became inadequate
due to an increase in average flow to 4.0 mgd, including 1.5 mgd of industrial wastes. The
upgrading included  replacement of the screening  and grit  removal  units, expansion  of
primary clarification, final clarification and digestion facilities, installation of new circular
trickling filters and  addition  of chlorine disinfection facilities. Replacement of the drying
beds  with a vacuum  filter installation was also required due to the  additional sludge
produced by the upgraded treatment system. The treatment provided  by  this upgraded
system resulted in BOD and SS removals of 89 percent and 84 percent, respectively.

Increases in the industrial BOD influent loads beyond those anticipated in the 1957 design,
required further plant upgradings in 1964 and 1970. In each of these upgradings, one of the
two original  fixed-nozzle  trickling  filters was  converted into two   aeration basins for
activated sludge treatment. Waste activated sludge  was  returned to the plant influent and
settled with the primary sludge. In 1970, digestion of the combined sludge was discontinued
and trucking of the dewatered raw sludge to an incinerator replaced landfilling for ultimate
disposal.

Current upgrading (presently under construction) to increase plant capacity  will include
chemical  addition  to  the raw wastewater for phosphorus  removal, separate  flotation
thickening of waste activated sludge to reduce the loading on the dewatering facilities and
effluent  polishing including  postaeration and dual-media filtration.  Under this current
upgrading, the  plant will provide 98 percent  BOD and SS removals  for an  ultimate dry
weather flow of 10.7 mgd.

A flow  diagram and design data for the original plant and each subsequent upgrading are
shown on Figure 13-6 and Table 13-9, respectively. Plant performance data before and after
each upgrading  are shown in Table 13-10.

Capital costs for each stage of the upgrading are presented in Table 13-11.
                                       13-19

-------
                     FIGURE  13-6
COMPARISON OF ORIGINAL AND UPGRADED FLOW DIAGRAMS
INFLUENT
WASTEWATER
SLUDGE
DRYING
BEDS
1
TO LANDFILL
t
/AN
\ "


PRIM
CLARI
\
r
AEROBIC \
IGESTER J*
	 '
FIXED-
ARY ^ NOZZLE .. FINAL
FIER * TRICKLING ' CLARIFIER
FILTERS
•^ WASTE SLUDGE ''
EFFLUENT
COMBINED PRIMARY
AND WASTE SLUDGE
OR GINAL PLANT f 931)
EXISTING
FIXEO-
— * NOZZLE
TRICKLING
FILTERS
(1 EXISTING,
1 NEW)-^ ^> 	 ^
' / NEW \
INFLUENT PRIMARY / TR1CnL1HG \
""ilc""":" " ' CLARIFIERS T FILTERS /
^^ WASTE SLUDGE
	 PRIMARY OR

/ \ SLUDGE
NEW VACUUM 	 / ANAEROBIC \^ ir
FILTER I OIGESTERSr WASTE SLUDGE
4 \|l NEW (PRIMARY)
SLUDGE CAKE }l EXISTING (SECONDARY)
TO
LANDFILL



NEW
CLARIFIERS
(CONVERTED
CHLORINE EXISTING
A • - Jtl\u • M n i FINAL
T,u «!„«.»

4
EFFLUENT

                  PLANT AFTER 1957 UPGRADING
                         13-20

-------
                                          FIGURE  13-6

                                           (CONTINUED]
                         INFLUENT
                         KASTEWATER
                                                                       (CONVERTED
                                                                       FIXED-NOZZLE
                                                                     TRICKLING FILTERS)

SLUDGE
AERATION
TANKS

VERTED


EXISTING
FINAL
CLARIFIERS
^-y"



1

EXI STING
CHLORINE
CONTACT
TANK
                                                               ANAEROBIC
                                                               DlGESTERS)
                               SLUDGE CAKE
                              TU  INCINERATOR
                                                            »ASTE SLUDGE
                                                             PLANT  AFTER  1970  UPGRADING
                                                            OPTIONAL
                                                            EQUALIZATION
INFLOENT _
KASTEHATER
NEW
PREAERATION
TANK


EXISTING
PRIMARY
CLARIFI ERS
v^ ./
                                                                                                     EFFLUENT
                 SLUDGE CAKE
               TO INCINERATOR
                                                  PLANT  AFTER  CURRENT UPGRADING
                                                 13-21

-------
                                                           TABLE 13-9
                                        CASE HISTORY NO. 6 - PLANT DESIGN CONDITIONS
co
           Description

Design Average Flow, mgd

Preaeration Tanks
  Detention Time (DAFl), minutes
Primary Settling Tanks
  Detention Time (DAF), hr
  Overflow Rate (DAF), gpd/sq ft
Secondary Treatment
  Square Trickling Filters
   Organic Loading (DAF),
    Ib BOD/day/1,000 cu ft
   Hydraulic Loading (DAF), mgd/acre^
  Round Trickling Filters
   Organic Loading (DAF),
    lbBOD/day/l,OOOcuft
   Hydraulic Loading (DAF), mgd/acre^
Aeration Tanks
  Detention Time (DAF), hr

Final Clarifiers
  Detention Time (DAF), hr
  Overflow Rate (DAF), gpd/sq ft
Chlorination Tanks
  Contact Time (DAF) minutes
Original Plant
1931
3.25
—
2.7
670
12
1.8

—
—
1.4
1,300
1957
8.0
—
2.1
810
15
2.2
31
4.6
—
3.5
460
1964
8.0
—
2.1
810

—
62
9.2
7.3
3.5
460
1970
8.0
—
2.1
810

—
62
9.2
14.7
3.5
460
Current
Upgrading
10.7
14.8
1.6
1,080

—
83
12.4
11.0
2.6
620
                                                                       34
34
34

-------
                                                       TABLE 13-9 (Continued)
to
CO
                  Description

      Sludge Thickening
         Flotation Unit Surface Area, sq ft
      Sludge Digestion (Number of Units)
         60 ft diameter x 23 ft SWD anaerobic
         80 ft diameter x 30 ft SWD anaerobic
      Sludge Dewatering
         Sludge Drying Beds, sq ft
         Vacuum Filter Surface Area, sq ft
      Ultimate Disposal
Original Plant
    1931
  32,600

  Landfill
 1957
 430
Landfill
 1964
  1970
 Current
Upgrading
                                                              250
 430
Landfill
  430
Incineration
     430
Incineration
         DAF = Design Average Flow.
         Does not include recirculation.

-------
                                                     TABLE 13-10
                            SUMMARY OF TREATMENT PERFORMANCE FOR CASE HISTORY NO. 6
                                      1957
                                                       1964
1970
co
fe
Average Flow, mgd

Peak Flow, mgd

BOD
  Raw Waste water, mg/1
  Removal, percent
      SS
        Raw Wastewater, mg/1
        Removal, percent
Before
Upgrading
3.7
10.0
380
60- *
350
60
After
Upgrading
4.5
11.5
310
90
240
85
Before
Upgrading
4.9
11.5
290
70
250
75
After
Upgrading
6.6
16.0
300
90
260
80
Before
Upgrading
6.8
16.0
390
85
290
75
After
Upgrading
8.9
18.0
390
90
300
75
Current
Upgrading
10.7
21.0
400
>98
300
>98

-------
                                  TABLE 13-11
           CAPITAL COSTS OF UPGRADING FOR CASE HISTORY NO. 6
                                                            Capital Cost
 Date of
Upgrading

   1957
  1964
  1970
 Current
  Design
             Item

Screening and Degritting
Rehabilitation of Pump and
 Control Building
Primary Clarification
Secondary Process
Final Clarification
Chlorination Facilities
Sludge Handling
Miscellaneous

      Total

Modifications to Secondary Process
Modifications to Secondary Process
Renovation of Screens and
 Degritting Equipment
Preaeration and Odor Control
Enclosure of Primary Tanks and
 Odor Control
Phosphorus Removal Facilities
Effluent Filters and Aerators
Sludge Handling
Miscellaneous
      Total
Cost at Time
of Upgrading

$   45,000

   150,000
    65,000
   330,000
   135,000
    25,000
   300,000
   150,000
$1,200,000
   200,000
   100,000
   1972
   Cost

$  110,000

   365,000
   160,000
   800,000
   330,000
    60,000
   730,000
   365,000
$2,920,000
   367,000
   133,000

    60,000
   160,000

   200,000
    75,000
   450,000
   250,000
    55,000
$1,250,000
13.7   Case History No.  7  -  Upgrading by  Optimization  of Aeration  Tank-Clarifier
       Relationship (9)

The Coldwater Creek Wastewater Treatment Plant in St. Louis, Missouri, is an activated
sludge  plant designed to treat a flow of 25 mgd. The plant facilities include six aeration
tanks and four final clarifiers; however, at the time of upgrading, only three of the aeration
tanks were  being used to treat a flow of 13.2 mgd. Under these operating conditions, the
plant efficiency was poor with BOD and SS removals of 73 and 46 percent, respectively.
                                      13-25

-------
 Table  13-12 summarizes  operating data before and after optimization of the aeration
 tank-clarifier relationship. The flow diagrams, presented on Figure 13-7, depict the changes
 in operation that were made. Analysis of the data indicates that before the modifications,
 the return sludge rate and the resulting MLSS concentration in the aeration tanks were both
 high. These  conditions imposed a solids loading rate on the  final clarifiers in excess of the
 recommended range (20-30 Ib/day/sq ft) shown in Table 6-2, even though the overflow rate
 was within  acceptable limits. As a result, poor clarifier performance lowered  the  overall
 BOD and SS removals normally expected in an activated sludge system.
                                   TABLE 13-12
                    CASE HISTORY NO. 7 - OPERATING DATA

                                                 Before Operating   After Operating
         Description                              Modifications      Modifications

Average Flow, mgd                                       13.2               14.5

Aeration Tanks
  Tanks in Service                                        3                  4
  MLSS, mg/1                                        7,200              3,400
  Return Sludge Rate, percent
    of Average Flow                                      93                 30
  Volumetric Loading, IbBOD/day/l,000 cu ft             44.7               31.5
  Organic Loading, Ib BOD/day/ Ib MLSS                   0.10               0.15
Final Clarifiers
  Tanks in Service                                        4                  3
  Overflow Rate at Average Flow, gpd/sq ft               515                755
  Solids Loading Rate at Average Flow                    59.8               27.8
 To  improve plant performance, a fourth aeration tank was put in service. A lower return
 sludge rate was used and  the MLSS concentration in the aeration tanks was decreased by
 over 50 percent. With these operational modifications, it was possible to maintain both the
 final clarifier solids loading rate and the overflow rate within their recommended limits with
 only three final clarifiers in service. The improvement in treatment plant efficiency resulting
 from the proper balancing of the aeration tanks and final clarifiers is shown in Table 13-13.
                                        13-26

-------
                      FIGURE  13-7
                   CASE HISTORY NO.7
COMPARISON OF ORIGINAL AND MODIFIED FLOW DIAGRAMS
    4 PRIMARY CLARIFIERS
      (ALL  IN SERVICE)
6 AERATION TANKS
 (3  IN SERVICE)
4 FINAL CLARIFIERS
 (ALL  IN SERVICE)





RAW
WASTEWATER i












r~*







->


h-






1 — P















— ^

















— ^













LU
CJ9
a
__i

oc.
UJ
oc
r— >




1 	 ^




















->|

fc




























fe











fc-

^



^>
































—^

^



^


                                                                 EFFLUENT
     EXCESS SLUDGE

         FLOW  DIAGRAM BEFORE  OPERATING  MODIFICATION
      PRIMARY CLARIFIERS   6 AERATION TANKS
      (ALL  IN SERVICE)      (4  IN SERVICE)
                   4 FINAL CLARIFIERS
                     (3  IN SERVICE)






RAW
HASTEWATER *












t w'






1 	 ^



- -w


^


'



































^


i *








*














cr>
CO
*
LU
0=


























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h









































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k.


























































k



^




                                                                 EFFLUENT
      EXCESS SLUDGE

           FLOW DIAGRAM AFTER  PLANT MODIFICATION
                             13-27

-------
                                    TABLE 13-13
                   CASE HISTORY NO. 7 - PERFORMANCE DATA
          Description

 Average Wastewater Flow, mgd

 BOD
   Raw Wastewater, mg/1
   Primary Effluent, mg/1
   Final Effluent, mg/1
   Overall Plant Removal, percent
 SS
   Raw Wastewater, mg/1
   Primary Effluent, mg/1
   Final Effluent, mg/1
   Overall Plant Removal, percent
Before Modification
  of Flow Pattern

        13.2

       150
       152
        40
        73

       173
       155
        92
        47
After Modification
 of Flow Pattern

        14.5

       162
       130
         9l
        94

       198
       142
        161
        92
1 One week average.
 13.8   Case  History  No.  8 - Upgrading by  Optimization of Aeration  Tank-Clarifier
        Relationship  (9)

 The  Sioux  Falls, South Dakota Wastewater Treatment Plant is a 9.5-mgd activated sludge
 plant. Approximately 3.5 mgd of the flow is industrial wastes (meat-packing wastes with a
 BOD of  2,500 mg/1). The  industrial wastes are pretreated by clarification and high-rate
 trickling filtration. The pretreated industrial wastes are then added to the main wastewater
 flow which is primarily domestic,  and the combined flow is treated by primary clarification
 followed by an activated sludge process. A flow diagram of the major treatment processes is
 presented on Figure 13-8.

 During most of the year, the plant provided excellent treatment. However, during the fall,
 the treatment plant  is subjected to high industrial loads that significantly  lowered plant
 efficiency prior  to optimization  of  the  aeration tank-clarifier  relationship. Table 13-14
 shows operating and performance data for the months of October and November, the period
 when loads are highest. The aeration tank loadings during 1967 were extremely high, while
                                        13-28

-------
the solids  loading rate on the final  clarifiers  was low. The unbalanced loadings on the
aeration tanks and final clarifiers were attributed to the relatively low return sludge rate and
the resulting low MLSS concentration.
                  PRETREATMENT
                  CLARIFIERS
         INDUSTRIAL
         WASTEHfATET
         DOMESTIC
         WASTEWATER
     FIGURE 13-8
  CASE HISTORY NO.8
    FLOW DIAGRAM

PRETREATMENT
HIGH-RATE
TRICKLING FILTER
                                        EFFLUENT
                                    PRIMARY
                                    CLARIFIERS
                 AERATION
                 TANKS
FINAL
CLARIFIERS
To improve treatment plant efficiency during the peak load season, it was decided to lower
the organic loading on  the  aeration  tanks by increasing the return sludge rate, thereby
raising the MLSS concentration. The success of this operational modification was dependent
on the ability of the final clarifiers to satisfactorily handle the increased solids loading.
Table 13-14 also presents operating and performance data for October and November, 1968,
after implementation of the modified operational mode. These data indicate that the final
clarifier solids loading rate was substantially raised, although still at an  acceptable level,
without affecting the overflow rate. The  improvements to treatment plant efficiency are
evident in Table 13-14.
                                        13-29

-------
                                  TABLE 13-14
         CASE HISTORY NO. 8 - OPERATING AND PERFORMANCE DATA

                                               1967                 1968
                                         Before Modification     After Modification
         Description                      of Operating Mode      of Operating Mode

Average Wastewater Flow, mgd                       10.0                   9.8
Aeration Tanks
  MLSS, mg/1                                   1,000                  3,000
  Return Sludge Rate,
   percent of Average Flow                         30                    90
  Volumetric Loading,
   Ib BOD/day/1,000 cu ft                         115                   117
  Organic Loading,
   Ib BOD/day/lb MLSS                             1.84                  0.63
Final Clarifiers
  Overflow Rate, gpd/sq ft                         660                   650
  Solids Loading Rate,
   Ib/day/sqft                                      7                    31
Final Effluent1
  BOD, mg/1                                      29.5                  20.0
  SS, mg/1                                        34.5                  13.5
  Fifty percent of the time effluent quality was equal to or less than values shown.
13.9   Case  History  No.  9 -  Upgrading  a Modified  Aeration  System  for  Nutrient
       Removal (10)

In 1969, regulatory agencies established more stringent effluent standards for treatment
plants that discharge into the Potomac River in the vicinity of Washington, D. C. These
higher  standards required upgrading the Washington, D. C. Blue Plains Plant to  provide
phosphorus and nitrogen removal as well as improved BOD and SS removals.

In 1969, very little  performance data were available on the  alternative phosphorus and
nitrogen  removal  methods that  might be used in this  upgrading situation. Fortunately,
through the cooperation  of the Joint EPA-DC  Pilot Plant, it was possible to pilot and
evaluate several alternative nutrient removal treatment sequences. Based on these studies,
                                      13-30

-------
two-point  addition  of a metal  salt was selected  for  phosphorus removal, and it was
determined that nitrogen removal would be best  achieved through biological nitrification
and denitrification processes. The pilot studies also indicated that to consistently meet the
established  effluent  standards,  multimedia  filtration would be  required.  Anticipated
performance data for the upgraded plant are presented in Table 13-15. Figures 13-9, 13-10,
and 13-11 show, respectively, the flow diagrams  for the primary and secondary systems,
nitrification  and denitrification  systems and filtration and  disinfection systems of the
upgraded plant.

The existing secondary system consists of four aeration tanks and 12 sedimentation units.
To handle the anticipated increase in plant design flow from 240 mgd to 309 mgd, the
existing  secondary  system will  be upgraded with two  additional  aeration tanks and  12
additional  final  sedimentation  tanks. The aeration tanks are designed for  a volumetric
loading of 120 Ib BOD/day/1,000 cu ft, an organic loading of 2.4  Ib BOD/day/lb MLSS and
a MLSS  concentration of 1,300  mg/1 (10). Since the increased design loadings require more
air per unit  volume  than  the  existing aeration system  can  deliver, the existing  aeration
system  will be expanded.  This  system will  be modified  from a coarse-bubble, spiral-roll
system  to a coarse-bubble,  spread-pattern  to improve oxygen transfer efficiency. The
secondary  system air capacity has  been designed  to provide 0.54 Ib C>2/lb BOD removed
(10).

Alum or ferric chloride will be added to the mixed liquor of the secondary system and is
expected to remove approximately 70 percent of the phosphorus contained in the plant
influent. To remove most of the remaining phosphorus, metallic salts will also be added to
the nitrogen release tanks. The  addition of metallic salts to the secondary system is also
expected to improve the  BOD  removal  in the  secondary  system from  75 percent  to
85 percent.  This will ensure a secondary effluent BOD concentration of less than 40 mg/1,
which was found during pilot testing to be desirable for successful nitrification in the second
stage.

Biological nitrification  facilities are designed for  oxidation  of 0.066  Ib NH3~N/day/lb
MLVSS  at minimum wastewater temperatures and a MLVSS concentration of 1,700 mg/1.
At the  stoichiometric oxygen requirement of 4.6 Ib O2/lb NHg—N oxidized, 120-75 hp
turbine aerators are required (10). Maximum air supply to the turbines will be 88,000 cfm.
The turbines were selected in this instance because, due to the limitations of the site, the
nitrification tanks are designed to have depths of 30 feet to obtain  the required volume. The
turbines  will provide adequate  mixing to this depth and are  capable of supplying a wide
range of oxygen to  the system  as required by varying NHg—N influent loads and varying
wastewater temperatures. Lime will be  added to  the nitrification reactor to maintain the
necessary pH for nitrification. The nitrification sedimentation tanks are designed for average
and  peak  hydraulic  and  solids loadings of 580  and  1,210 gpd/sq  ft  and  17.4 and
36.6 Ib/sq ft/day, respectively. The  sludge return system is designed to provide return  of
                                        13-31

-------
                                                     TABLE 13-15
                           CASE HISTORY NO. 9 - ANTICIPATED PERFORMANCE AFTER UPGRADING
co
BOD, mg/1
Total Phosphorus, mg/1

Nitrogen:
  Organic-N, mg/l
  NH3-N, mg/1
  NO2 + NOa-N, mg/1
  Total N, mg/1

Grit Chamber
Effluent
206
8.4
8.6
13.7
0
22.3

Secondary
Effluent1
35
2.0
3.0
14.8
0.2
18.0

Nitrification
Effluent
10
1.0
1.0
1.5
11.1
13.6
Denitri-
fication
Effluent
6
0.5
1.0
1.0
1.0
3.0

Filtration
Effluent
4
0.2
0.5
1.0
0.5
2.0

Effluent
Standard
5
0.22

—
—
2.4
          With ferric chloride or alum addition.

-------
                                                  FIGURE 13-9

                          UPGRADING A MODIFIED AERATION SYSTEM FOR NUTRIENT REMOVAL


                                                  FLOW DIAGRAM

                                        PRIMARY AND SECONDARY SYSTEMS (10)
OJ
oo
w
pa
ANACOSTIA 1 '
FORCE MAIN
mil
RAW T^|~PUMP "I Jnf*
WASTEWATER | >ift''^Np ~+
(5
Z _
N 3
^ 0
< Z
o 8
u*
2 !
"i ,_i
WASTEWATER^' 5TATIONJ * <"<"
LEGEND
CONTINUOUS INTERMITT
FLOW FLOW


(INC. AIR)
PSL PRIMARY SLUDGE
RSL RETURN SLUDGE
WSL WASTE SLUDGE
ALT.
SPENT
| WASHWATER
1
| FERRIC OR ALUM 1 !
: j| 	 •
m

\ DISINFECTION | EXCESS FLOW TO RIVER
ATRl ! 1



! .--— ~ -v JSE<
1 / \ TL"
ERATED ~|ir%*/ PRIMARY \Tl' ' f
CHAMBERlT T\j SEDIMENTATION |U- ' '
1 r\ TANKS 1
v^^x

r" SLUDGE
GRAVITY RECYCLE >SE<
^ THICKENERS 	
1 GRAVITY ' ^
pH THICKENING ,
1 j OVERFLOW j
^^^^^^^^^^^
EXIST 	 k Jj EXIST \ 1
CBATcn 1 V PRIMARY 1 ISE(
ECRH"MDBER[T^;SEOI^TKASTIONI 	 N •
ENT r^- ["PCJLYMTR"
fTEl RiN THK
NITRIFICATION
j INFLUENT^
1
I
lATTlcf
FILTERS
1 OR
OUTFALL
L „ —^
ALT TO
ITRIFICATION l_ .
OR T"^
NITRIFICATION j
KENERS

-------
                                                FIGURE 13-10

                         UPGRADING A MODIFIED AERATION SYSTEM FOR NUTRIENT REMOVAL

                                                FLOW DIAGRAM

                                   NITRIFICATION AND DENITRIFICATION  SYSTEMS (10)
co
co

LIME
1
SECONDARY
EFFLUENT I
i
i
^
•
•
•
POLYMER AIR METHANOL
i i t
NITRIFICATION! 1
^ REACTORS l_^

NITRIFICATION! | pl.up ! I
SED. BASINS LJ^^U,
III 1:
t !'
«* i 1
t ' ^
ALT. WSL FROM
SECONDARY
OR
DENITRIFICATION

FERR

SPENT ...
WASHWATER AIR
1 '

DENITRIFICATION li r NIT*
REACTORS Uk yAL
COR ALUM

1 ' POLYMER
f

3AGSEEN JDEN''R'F'CA''?N| TO MULTI-MEDIA
MKi *| --CD. BA.IN, 1 F|ITERS »
t
i RSL
rWSl j JAITJ ^ J
^ "-1
I t
• 1
ALT WSL FROM !
SECONDARY
OR
NITRIFICATION

WSL W
TO
FLOTATION THICKENERS
AwSL
LEGEND
CONTINUOUS INTERMITTENT
FLOW FLOW
"iSTFWATFR — _^i,__>. . i

(INC. AIR)
RSL RETURN SLUDGE
WSL WASTE SLUDGE

-------
                                                         FIGURE 13-11

                              UPGRADING A MODIFIED AERATION SYSTEM FOR NUTRIFENT REMOVAL
                                                         FLOW DIAGRAM
                                             FILTRATION AND DISINFECTION  SYSTEMS (10)
                   SPENT WASHWATER
                  TO NITROGEN RELEASE
co
co
cn
                                   LEGEND

                                 CONTINUOUS  INTERMITTENT
                                   FLOW       FLOW
FLUSHING. SERVICE AND
   DILUTION WATER
                       WASTEWATER

                        CHEMICALS

-------
40 percent of  peak flow. However, the  system will  normally be operated to  return
30 percent of  the average  flow.  Continuous  monitoring  of the DO  content of  the
nitrification effluent will be provided to ensure that the influent DO to the denitrification
system is minimized.

The biological denitrification  system will include  reactors, nitrogen release tanks and
sedimentation  tanks.  The  reactors  have  been  designed  for  removal  of  0.0425  Ib
N03-N/day/lb MLVSS at a design MLVSS concentration of 2,100 mg/1, with up to 4.5 Ib
methanol  added/lb NOg—N  applied  (10). The  reactors will be equipped with 48-75 hp
mixers, and will be covered but not airtight.

The nitrogen release tanks will serve three functions: (1) to strip supersaturated nitrogen
gas,  (2) to provide  mixing for second-stage metal salt addition for residual phosphorus
removal and  (3) to provide an  aeration zone for removal of excess  methanol.  These tanks
will furnish a 23-minute detention period at average flow.

The denitrification sedimentation tanks are designed for hydraulic loadings of 670 gpd/sq ft
at  average flow,  and  1,410  gpd/sq ft   at peak flow.  Solids loadings are  25.6 and
54.0 Ib/sq ft/day at average and peak flows, respectively.

The 36 multimedia filters are designed for  filtration rates of 3.0 gpm/sq ft at average flow
and 6.2 gpm/sq ft at peak flow. Backwashing will occur at normal intervals of 24 hours at a
rate of 25 gpm/sq ft. The backwash water will be equalized in conduits and may be returned
upstream of either the secondary reactors or the nitrogen release tanks.

Provision has been made to chlorinate either upstream or downstream of the filters with 24
minutes detention provided in contact tanks following the filters.

Sludge processing facilities will include gravity thickening  of primary sludge, flotation
thickening of secondary and advanced treatment sludges,  vacuum filtration  and  sludge
incineration.

13.10  References

  1.  Wittenmyer,  J.D.,  and Sak,  J.G.,  Plastic Media  Roughing  Filter Provides Most
     Economical  Plant  Expansion.  Presented  at the  Ohio Water Pollution Control
     Association Conference (June 15, 1967).

  2.  Wittenmyer, J.D., A Look at  the Future Now. Presented at the Ohio Water Pollution
     Control Association Conference (June 20, 1969).

  3.  Private communication with J.D. Wittenmyer, Vice President, Ohio Suburban Water
     Company, Dayton, Ohio (January 22,  1971).

                                       13-36

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 4. Burns  & McDonnel  Engineering Company. Report  on Sewage Treatment Plant and
    Sanitary Sewer Improvements for Sedalia, Missouri (1963).

 5. Wirts, J.J., The Use of Organic Polyelectrolyte for Operational Improvement of Waste
    Treatment   Processes.   Federal  Water  Pollution   Control  Administration,  Grant
    No. WPRD 102-01-68 (May, 1969).

 6. Hazen and  Sawyer,  Engineers, Upgrading Existing  Wastewater Treatment Facilities.
    Prepared for U.S. EPA Technology Transfer Design Seminar, Pittsburgh, Pennsylvania
    (August 29-31, 1971).

 7. 1970 Annual Report,  Livermore Water  Reclamation Plant,  City  of Livermore,
    California.

 8. Brown  and Caldwell Consulting  Engineers,  Project Report for  Water Reclamation
    Plant, Central Contra Costa Sanitary District, California (November, 1971).

 9. West, A.W., Case Histories of Plant Improvement  by Operations Control,  Nutrient
    Removal  and Advanced  Waste   Treatment.   Federal  Water  Pollution  Control
    Administration, Cincinnati, Ohio (1969).

10. Schwinn, D.E., Design Features of the District of Columbia's Water Pollution Control
    Plant.  Presented at the Sanitary  Engineering Specialty Conference, ASCE,  Sanitary
    Engineering Division, Rochester, New York (June, 1972).
                                      13-37

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                               APPENDIX A
                      METRIC CONVERSION CHART

  Multiply                            BX                       To Get

Inches                             2.54                  Centimeters
Feet                              0.3048                Meters
Square Feet                        0.0929                Square Meters
Cubic Feet                         0.0283                Cubic Meters
Pounds                            0.454                 Kilograms
Gallons                            3.79                  Liters
Gallons/Minute                     5.458                 Cubic Meters/Day
Feet/Second                       0.305                 Meters/Second
                                     A-l

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                                 APPENDIX B
                           WORD ABBREVIATIONS
                                                            Text
Tables
afternoon
average
before noon
biochemical oxygen demand
brake horsepower
centimeter(s)
chemical oxygen demand
cubic foot
cubic feet per minute
cubic feet per second
degree Centigrade
degree Fahrenheit
dissolved oxygen
elevation
feet per minute
food to microorganism ratio
foot (feet)
gallon(s)
gallons per day
gallons per minute
gram(s)
head loss
horsepower
hour(s)
inch(es)
Jackson turbidity units
kilowatt-hour
micron(s)
milligrams per liter
milliliter
millimeter(s)
million gallons
million gallons per day
PM
AM
BOD
BHP
cm
COD
cuft
cfm
cfs
degC
degF
DO
El
fpm
F/M
—
gpd
gpm
::
hp
—
—
kwh
y
mg/1
ml
mm
mil gal
—
PM
avg
AM
BOD
BHP
cm
COD
cuft
cfm
cfs
°C
DO
El
fpm
F/M
ft
gal
gPd
gpm
g
H.L.
hp
hr
in
Jtu
kwh
y
mg/1
ml
mm
mil gal
mgd
                                       B-l

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                          APPENDIX B - Continued
                                                          Text          Tables

mixed liquor suspended solids                                MLSS        MLSS
mixed liquor volatile suspended solids                         MLVSS       MLVSS
most probable number                                      —           MPN
number (s)                                                 —           No.
parts per million                                            PPm          PPm
pound(s) (weight)                                          —           Ib
pounds per cubic foot                                       pcf           pcf
pounds per square foot                                      psf           psf
pounds per square inch gage                                  psig          psig
revolutions per minute                                      rpm          rpm
second(s)                                                  —           sec
side water depth                                            	           SWD
sludge retention time                                       SET          SRT
square  foot                                                sq ft          sq ft
standard oxygen transfer rate                                 SOR          SOR
suspended solids                                            SS           SS
total solids                                                —           TS
total suspended solids                                       —           TSS
volatile suspended solids                                     —           VSS
year(s)                                                    —           yr
                                       B-2

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