United States
Environmental Protection
Agency
Air and Energy Engineering
Research Laboratory
Research Triangle Park NC 2771 1
EPA/600/7-86/057a
December 1986
Research and Development
r/EPA
Development of the
1980 NAPAP
Emissions Inventory
-------
EPA-600/7-86-057a
December 1986
DEVELOPMENT OF THE
1980 NAPAP EMISSIONS INVENTORY
by
Janice K. Wagner, Robert A. Walters
Leslie J. Maiocco, Donald R. Neal
ALLIANCE TECHNOLOGIES CORPORATION
213 Burlington Road
Bedford, Massachusetts 01730
EPA Contract No. 68-02-3997
Work Assignment Nos. 10, 11 and 15
and
EPA Contract No. 68-02-4274
Work Assignment No. 6
J. David Mobley, EPA Project Officer
Air and Energy Engineering Research Laboratory
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
This study was conducted in cooperation with the
National Acid Precipitation Assessment Program
Prepared for:
Office of Research and Development
U.S. Environmental Protection Agency
Washington, DC 20460
t/.S. Environmental Protection Agency
' • <-.•• 5, Library (5PL-16)
' ' <"=, Dc3rt>orn Street, Room 1670
IL COG04
-------
ABSTRACT
This report documents the development of the 1980 National Acid
Precipitation Assessment Program (NAPAP) Emissions Inventory. The current
version of the annual inventory, Version 5.0, and the related Version 5.2
Eulerian Modeling Inventory and Version 5.3 Regional Oxidant Modeling
Inventory represent the most comprehensive, highest quality emissions data
available for the 1980 base year. The inventory spans the 48 contiguous
states and 10 Canadian provinces, providing detailed point source data for
over 14,000 plants and area source information by source category for 3,070
U.S counties. Canadian area source data are reported at the province level.
Emissions from 11 pollutants (S02, 804, NOX, Pb, CO, HC1, HF, NH3,
TSP, VOC, and total hydrocarbons) are included in Version 5.0 of the
inventory, while in the 5.2 modeling inventory, pollutants are disaggregated
into 39 individual classes. NAPAP Version 5.0/5.2 emissions of S02, NOX
and VOC are 32.1, 24.4, and 26.2 million tons/year, respectively. Summaries
of emissions data are presented at various levels of aggregation including
nation, EPA region, state/province, and source category. Emissions data are
also analyzed by plant size, stack height, and general source type, and
emissions variations are examined on a seasonal and daily basis. The
Version 5.0 NAPAP Emissions Inventory represents the last of a series of NAPAP
inventory compilation efforts for base year 1980. This report provides a
history of the inventory development, focusing on enhancements made from
version to version. It also includes a number of topics specific to
development of Version 5.0 and 5.2, including development of emission factors
for newly-added pollutants; incorporation of updated utility data with
information from the NAPAP Utility Reference File (NURF); development of
temporal, spatial and species allocation factors; and creation of the Flexible
Regional Emissions Data System, used to process the 5.0 inventory into the 5.2
and 5.3 modeling inventories.
11
-------
CONTENTS
Abstract ii
Key to Appendix A Tables, 1980 NAPAP Emissions Inventory Version 5.0 . . v
Key to Appendix A Tables, 1980 NAPAP Emissions Inventory Version 5.2 .. vi
Figures vii
Tables x
Acknowledgments xiii
Executive Summary xiv
1. Introduction i
Background 1
Objectives 1
1980 NAPAP Emissions Inventory 2
Report Organization 5
2. Overview of Emissions Data 6
Version 5.0 6
Version 5.2 37
3. Creation and Quality Assurance of the 1980 NAPAP Emissions
Inventory 61
NAPAP Emissions Inventory Development Approach 61
Evolution and Quality Assurance of the 1980 Annual NAPAP
Emissions Inventory 62
Evolution and Quality Assurance of the 1980 Resolved
NAPAP Emissions Inventory 82
4. NAPAP Version 5 Emission Factors 87
Primary Sulfate Emission Factors 88
HC1 and HF Emission Factors 91
NH3 Emission Factors 93
Alkaline Dust Emission Factors 97
5. Development of Emissions Estimates for the Utility Sector .... 100
NAPAP Utility Reference File (NURF) 100
NAPAP Inventory Updates File (NIUF) 105
6. Development of Temporal, Species, and Spatial Allocation
Factors 108
Temporal Allocation Factor Development 108
Spatial Allocation Factor Development 126
Speciation Factor Development 140
7. Emissions Inventory Software Development and Data Processing . . 151
FREDS System 151
Data Processing Results 153
Products Available 158
References 172
iii
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CONTENTS (continued)
Appendices
A. Detailed Emissions Summaries A-l
B. Default Parameter Tables and SAROAD Listings B-l
C. Figures Depicting United States Area Source Temporal Allocation
Factors C-l
D. Listing of Source Classification Codes for U.S. and Canadian
Point and Area Sources D-l
E. Speciation Files and Discussion of Conversion of Emission Rates
From Moles/Year to Tons/Year E-l
IV
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KEY TO APPENDIX A TABLES, 1980 NAPAP EMISSIONS INVENTORY VERSION 5.0
National
coverage
U.S.
Canada
U.S. &
Canada
Level of
Source type resolution
Area SCC
State
Region
Point SCC
State
Region
Area & Point State
Region
Area SCC
Province
Point SCC
Province
Area & Point Province
Area & Point Totals
Hydrocarbon
classes ?
No
No
No
No
No
No
No
No
No
No
No
No
No
No
Units
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Page
A-4 - A-5
A-6 - A-7
A-8
A-9
A- 10
A- 10
A-ll - A-17
A-18 - A-24
A-25
A-26
A-27
A-27
A-28
A-29
A-30
A-30
A-31 - A-33
A-34 - A-36
A-37
A-37
A-38 - A-39
A-40 - A-41
A-42
A-42
A-43
A-43
A-44
A-44
U.S.
Area & Point State
(Emissions density)
No
Tons/sq mi. A-45 - A-46
-------
KEY TO APPENDIX A TABLES, 1980 NAPAP EMISSIONS INVENTORY VERSION 5.2
National Level of
coverage Source type resolution
U.S. Area SCC
State
Region
Point SCC
State
Region
Area & Point State
Region
Canada Area SCC
Province
Point SCC
Province
Area & Point Province
U.S. & Area & Point Totals
Canada
Hydrocarbon
classes ?
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
Un i t s
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Page
A-47 - A-48
A -4 9 - A-50
A-51 - A-5/»
A-55
A-56
A-57 - A-58
A-59
A-59
A-60
A-61 - A-67
A-68 - A-74
A-75 - A-88
A-89
A-90
A-91 - A-92
A- 9 3
A-93
A-94
A-95
A-96
A-97 - A-98
A-99
A-99
A-100
A-KH - A-103
A-104 - A-106
A-107 - A-112
A- 11 3
A-113
A-1U
A-115 - A-116
A-117 - A-118
A-119 - A-122
A-123
A-123
A- 124
A-125
A-125
A-126
A-127
A-127
A-128
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
VI
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FIGURES
Number Page
1-1 Major program components for developing the 1980 NAPAP
emissions inventory 3
2-1 1980 NAPAP Emissions Inventory Version 5.0 - relative distri-
bution of point versus area source emissions for S02, NOX,
and VOC 11
2-2 1980 NAPAP Emissions Inventory Version 5.0 - distribution of
U.S. emissions by source category for S0_, NO , and VOC ... 13
2-3 1980 NAPAP Emissions Inventory Version 5.0 - distribution of
Canadian emissions by source category for S0_, NO , and VOC . 14
2-4 1980 NAPAP Emissions Inventory Version 5.0 - combined U.S. and
Canadian emissions totals by year of record 15
2-5 1980 NAPAP Emissions Inventory Version 5.0 - spatial
distribution of point sources emitting greater than 25,000
tons/year S02 19
2-6 1980 NAPAP Emissions Inventory Version 5.0 - distribution of
point source emissions by estimation method 20
2-7 1980 NAPAP Emissions Inventory Version 5.0 - S02 state
emissions density 21
2-8 1980 NAPAP Emissions Inventory Version 5.0 - NOX state
emissions density . 22
2-9 1980 NAPAP Emissions Inventory Version 5.0 - VOC state
emissions density 23
2-10 1980 NAPAP Emissions Inventory Version 5.0 - TSP state
emissions density ... 24
2-11 1980 NAPAP Emissions Inventory Version 5.0 - NH3 state
emissions density 25
2-12 1980 NAPAP Emissions Inventory Version 5.0 - 804 state
emissions density . 26
vii
-------
FIGURES (continued)
Number Page
2-13 1980 NAPAP Emissions Inventory Version 5.0 - Pb state
emissions density ...................... 27
2-14 1980 NAPAP Emissions Inventory Version 5.0 - CO state
emissions density ...................... 28
2-15 1980 NAPAP Emissions Inventory Version 5.0 - HC1 state
emissions density ...................... 29
2-16 1980 NAPAP Emissions Inventory Version 5.0 - HF state
emissions density ...................... 30
2-17 1980 NAPAP Emissions Inventory Version 5.0 - THC state
emissions density ...................... 31
2-18 1980 NAPAP Emissions Inventory Version 5.0 - SC>2 county
emissions density .................... • • 32
2-19 1980 NAPAP Emissions Inventory Version 5.0 - NOX county
emissions density ...................... 33
2-20 1980 NAPAP Emissions Inventory Version 5.0 - VOC county
emissions density ...................... 34
2-21 1980 NAPAP Emissions Inventory Version 5.0 - TSP county
emissions density ...................... 35
2-22 1980 NAPAP Emissions Inventory Version 5.0 - NH3 county
emissions density ...................... 36
2-23 1980 NAPAP Emissions Inventory Version 5.2 - hourly emissions
patterns for S0_, NO , and VOC for a typical summer weekday . 46
2-24 1980 NAPAP Emissions Inventory Version 5.2 - Annual S02
emissions, U.S. point sources ................ ^7
2-25 1980 NAPAP Emissions Inventory Version 5.2 - Annual SC>2
emissions, U.S. area sources ................ 48
2-26 1980 NAPAP Emissions Inventory Version 5.2 - Annual S02
emissions, U.S. point and area sources ........... 49
2-27 1980 NAPAP Emissions Inventory Version 5.2 - Annual NOX
emissions, U.S. point sources ................ 50
2-28 1980 NAPAP Emissions Inventory Version 5.2 - Annual NOX
emissions, U.S. area sources ................ 51
viii
-------
FIGURES (continued)
Number Page
2-29 1980 NAPAP Emissions Inventory Version 5.2 - Annual NOX
emissions, U.S. point and area sources 52
2-30 1980 NAPAP Emissions Inventory Version 5.2 - Annual VOC
emissions, U.S. point sources 53
2-31 1980 NAPAP Emissions Inventory Version 5.2 - Annual VOC
emissions, U.S. area sources 54
2-32 1980 NAPAP Emissions Inventory Version 5.2 - Annual VOC
emissions, U.S. point and area sources 55
2-33 1980 NAPAP Emissions Inventory Version 5.2 - S02 emissions
for a typical summer weekday at 1700 GMT 56
2-34 1980 NAPAP Emissions Inventory Version 5.2 - NOX emissions
for a typical summer weekday at 1700 GMT 57
\
2-35 1980 NAPAP Emissions Inventory Version 5.2 - VOC emissions
for a typical summer weekday at 1700 GMT 58
2-36 1980 NAPAP Emissions Inventory Version 5.2 - TSP emissions
for a typical summer weekday at 1700 GMT 59
2-37 1980 NAPAP Emissions Inventory Version 5.2 - NH^ emissions
for a typical summer weekday at 1700 GMT 60
3-1 Evolution of the 1980 NAPAP emissions inventory 63
5-1 Hierarchy of NURF data sources by data element 103
6-1 Development of land use allocation factors 130
6-2 Example of county to grid cell areal relationship 132
IX
-------
TABLES
Number Page
1-1 1980 NAPAP Emissions Inventory Coverage 4
2-1 1980 NAPAP Emissions Inventory Version 5.0 - Annual U.S. Point
and Area Source Emissions by EPA Region 7
2-2 1980 NAPAP Emissions Inventory Version 5.0 - Annual U.S. Point
and Area Source Emissions by State 8
2-3 1980 NAPAP Emissions Inventory Version 5.0 - Annual Canadian
Point and Area Source Emissions by Province 9
2-4 1980 NAPAP Emissions Inventory Version 5.0 - Point and Area
Source Emissions by Major Category 12
2-5 1980 NAPAP Emissions Inventory Version 5.0 - Emissions
Percentages by Emissions Release Height (Combined U.S. and
Canadian Sources) 17
2-6 1980 NAPAP Emissions Inventory Version 5.0 - Distribution of
SO,, NO , and VOC Emissions Point Sources by Size Range .... 18
£* X
2-7a 1980 NAPAP Emissions Inventory Version 5.2 - Annual U.S. Point
and Area Source Emissions by EPA Region 38
2-7b 1980 NAPAP Emissions Inventory Version 5.2 - Annual U.S. Point
and Area Source Hydrocarbon Species Emissions by EPA Region . 39
2-8a 1980 NAPAP Emissions Inventory Version 5.2 - Annual U.S. Point
and Area Source Emissions by State 40
2-8b 1980 NAPAP Emissions Inventory Version 5.2 - Annual U.S. Point
and Area Source Hydrocarbon Species Emissions by State ... 41
2-9a 1980 NAPAP Emissions Inventory Version 5.2 - Annual Canadian
Point and Area Source Emissions by Province 43
2-9b 1980 NAPAP Emissions Inventory Version 5.2 - Annual Canadian
Point and Area Source Hydrocarbon Species Emissions by
/ *3
Province ^J
-------
TABLES (continued)
Number Page
2-10 1980 NAPAP Emissions Inventory Version 5.0 - Seasonal
Variation in Emissions of S00. NO and VOC 44
2 x
3-1 Emissions Totals for 1980 and Non-1980 Sources in 1980
NAPAP Inventory (Version 5.0) 75
3-2 Plant Level QA Checks of 1980 NAPAP U.S. Point Sources
(Version 5.0) 76
3-3 Point Level QA Checks of 1980 NAPAP U.S. Point Sources
(Version 5.0) 77
3-4 SCC Level QA Checks of 1980 NAPAP U.S. Point Sources
(Version 5.0) 79
3-5 Summary of Total U.S. Emissions from Versions 1.0 - 5.0 of
the 1980 NAPAP Inventory 81
3-6 Size Cutoffs for Version 5.0 of the NAPAP Point Source
Inventory 84
3-7 Temporal Scenarios Available Under the 1980 NAPAP Emissions
Inventory, Version 5.2 and 5.3 85
4-1 Primary Sulfate Emission Factors 89
4-2 Hydrogen Chloride and Hydrogen Fluoride Emission Factors. ... 92
4-3 Ammonia Emission Factors 95
4-4 Anthropogenic Point Source Alkaline Particulate Emission
Factors 98
5-1 Major Data Inputs to NURF 101
5-2 Sources of Unit-Specific Data 104
6-1 Application of Temporal Allocation Factors to Total Hydrocarbon
Emissions for U.S. Area Source Category 32, Medium Duty
Gasoline Vehicles - Rural Roads 110
6-2 Temporal Allocation Factor Development for NAPAP Version 5.2
Emissions Categories 112
6-3 Canadian Area Source Categories and Temporal Factor Level
of Specificity 120
XI
-------
TABLES (continued)
Number Page
6-4 Sample Displaying Format of U.S. Area Source Temporal
Allocation Factor Records 127
6-5 Allocation Factors for Canadian Area Sources . 135
6-6 Spatial Allocation Factor Surrogates for NAPAP Version 5.2
Area Source Emissions Categories 136
«
6-7 Definition of Classes for Hydrocarbon Speciation, Versions
6-8
7-1
7-2
7-3
7-4
7-5
7-6
7-7
7-8
7-9
7-10
7-11
Hydrocarbon Species/Class Assignments for 1980 NAPAP Inventory
Version 5.0, U.S. and Canadian Point Sources (SAS and EBCDIC
Version 5.0, U.S. and Canadian Area Sources (SAS and EBCDIC
Version 5.2, Area Sources (SAS and EBCDIC Format)
Version 5.3, Point Sources (SAS and EBCDIC Format)
itj.
143
155
156
157
159
160
161
164
166
168
169
171
Xll
-------
ACKNOWLEDGMENTS
This report describes the development of the 1980 NAPAP Emissions
Inventory, a project administered by the U.S. Environmental Protection Agency
(EPA) with funding from the National Acid Precipitation Assessment Program
(NAPAP) Task Group on Emissions and Controls. David J. Beecy of the U.S.
Department of Energy serves as chairman of this task group, and Edward
C. Trexler (DOE) serves as deputy chairman.
The project has been a cooperative effort involving personnel from both
the EPA Office of Research and Development (ORD) and the EPA Office of Air
Quality Planning and Standards (OAQPS). In particular, Lowell Smith, Mike
Maxwell and Dale Pahl made significant contributions from ORD, while John
Bosch and Chuck Mann were the primary contributors from OAQPS. In addition,
several contractors contributed to the compilation of the 1980 NAPAP Emissions
Inventory. Douglas Toothman and the staff of Engineering-Science were
responsible for the creation of the 1980 NAPAP Annual Emissions Inventory
described in Section 3. Emission factors discussed in Section 4 were
developed by James Homolya of Radian and by David Misenheimer of Alliance.
Edward Pechan of E. H. Pechan & Associates developed the NAPAP Utility
Reference File (NURF) used to generate emissions estimates for utilities in
the NAPAP 5.0 inventory (as described in Section 5). Canadian emissions and
allocation factors were provided by Frank Vena of Environment Canada. In
addition, Joan Novak of EPA's Atmospheric Sciences Research Laboratory
provided valuable support and guidance.
xili
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EXECUTIVE SUMMARY
The 1980 NAPAP Emissions Inventory has been developed by the Task Group
on Emissions and Controls of the National Acid Precipitation Assessment
Program (NAPAP). This report summarizes the data in the emissions inventory
and documents the history of its development and enhancements to previous
versions.
SCOPE OF THE 1980 NAPAP EMISSIONS INVENTORY
The 1980 NAPAP Emissions Inventory represents the best available point
and area source emissions data for the United States and Canada for the base
year 1980. The NAPAP study area extends from 25 to 60 degrees north latitude
and 50 to 125 degrees west longitude.
Annual Emissions Inventory
Within the NAPAP study area, the inventory contains annual point source
emissions data for 14,244 plants encompassing 36,807 emission points and
52,904 source classification code (SCC) or process level records. Area source
emissions are reported for 88 emissions categories for the 3,070 counties in
the 48 contiguous United States and the District of Columbia, and for 157
categories for 10 Canadian provinces. Emissions for 11 pollutants are
reported in the annual emissions inventory: S02, SO^, NOX, Pb, CO, HC1,
HF, NH3, TSP, VOC, and THC. Volatile Organic Compounds (VOC) are defined as
reactive hydrocarbon species, whereas the Total Hydrocarbon (THC) category
includes both reactive and nonreactive species. This annual emissions
inventory is termed "Version 5.0."
Eulerian Modeling Emissions Inventory
NAPAP requires an emissions inventory that is suitable as input to
the Regional Acid Deposition Model (RADM). The RADM dictates that annual
emissions be further resolved temporally, spatially, and by pollutant
species.
Temporal resolution is accomplished by applying factors which allocate
annual emissions to 24 hourly emissions totals for a "typical" weekday,
Saturday, and Sunday in each season, giving a total of 12 temporal scenarios,
each suitable as RADM input. The point source and county-level area source
emissions are spatially allocated to 63,000 20 x 20 kilometer grid cells, each
representing 1/6 degree latitude by 1/4 degree longitude.
xiv
-------
Three pollutants from the annual inventory (NOX, TSP, and total
hydrocarbons) are further resolved into constituent species or classes of
species. Although the data handling system was designed to accommodate the
29 hydrocarbon classes used in the RADM, lack of speciation profiles resulted
in estimated emissions of zero for some classes. In addition, NOX emissions
were not maintained in the resolved inventory following speciation into NO and
NC>2. As a result, the Eulerian Modeling Emissions Inventory (Version 5.2)
contains a total of 39 pollutants as follows:
so
SO
NO
Pb
CO
HC1
HF
NH3
TSP
Calcium
Magnesium
Potassium
Sodium
VOC
THC
Methane
Ethane
Ethylene
Propane
Propylene
N-butane
Isobutane
Isobutene
Pentane
Isopentane
Other Alkanes
Other Alkenes
Other Organic Acids
Formaldehyde
Acetaldehyde
Acetone
Other Ketones
Other Aldehydes
Xylene
Benzene
Toluene
Ethylbenzene
Other Aromatics
EMISSIONS SUMMARY
Annual Emissions Inventory
Table 1 details the annual U.S. and Canadian emissions of the 11
pollutants in Version 5.0 of the 1980 NAPAP Emissions Inventory. The
distribution of S02 emissions among major source categories and by source
type (point and area) is shown in Figure 1. Clearly, point sources (mainly
utilities and smelters) are the major S02 emitters. State and county S02
emission density maps are shown in Figures 2 and 3; the concentration of S02
emissions east of the Mississippi River is apparent. This report contains
similar maps for additional pollutants; S02 is used here as an example.
Eulerian Modeling Emissions Inventory
The annual emissions of the 39 species represented in Version 5.2 of
the 1980 NAPAP Emissions Inventory are summarized in Table 2. These totals
reflect the application of species allocation factors to NOX, TSP, and THC
emissions.
Emissions totals for some pollutants in Version 5.2 are slightly lower
than in Version 5.0, because a small number of sources could not be properly
allocated. As an example, 40 Canadian point source observations fell outside
xv
-------
TABLE 1. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.0
AREA AND POINT SOURCES
X
<
h"
Country
Canada
Contig. U.S.
Total
-- +
1
1
1
1
S02
5,109
26,954
32,063 1
NR => Not Reported
Note: Numbers may
S04
188
976
,164
not sum
• THOUSAND IUNb/Tt/\K
NOX PB CO HCL
2,054 NR 18,036 NR
22,352 32 99,309 527
24,406 32 117,345 527
due to rounding.
HF NH3 TSP VOC THC
NR 210 31,574 2,994 5,138
115 839 42,617 23,165 24,977
115 1,048 74,192 26,158 30,115
-------
Annual SC>2 emissions by source category
U.S.
CANADA
INO/UFG PROC
12 ««•
IHD COMBUSTION
I] ia<
OTHER COUBUST
4 2I>
iNO/urc PROC
HD COUBUSTI OH
I 94i
TRANSPORTATION
OTHER COUBUST
4.8B«
Annual S02 emissions by source type
CANADIAN POINT
13.551
CANADIAN ARE*
2.981
Figure 1. 1980 NAPAP Emissions Inventory Version 5.0 - S02
emissions by source category and source type.
XVll
-------
<
(-"•
I-1-
TONS/SO.MI
J 0-10
10-20
>20
Figure 2. 1980 NAPAP Emissions Inventory Version 5.0 - S02 state emissions density.
-------
-------
TABLE 2. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.2 - AREA AND POINT SOURCES
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN t U.S. EMISSIONS, AREA t POINT SOURCES
Country )
Cmda |
Contl«. U.S. j
lot.l |
S02
5,095
26,954
32,049
104
167
976
1,143
HO
1,«79
22,756
H02
171
1,475
1,646
n
W
32
32
CO
17,946
99.309
117,295
- THOUSAND TCMS/YEAII -••
HCL ttf
m HI
527 115
527 115
»H3
210
U9
1.049
ISP
31,509
42,617
74,126
CA
17
114
130
HC
5
32
37
JM K VDC
} 3 2,992
11 15 23. 165
16 16 26,156
TNC
4,135
J4,»77
511.113
MR => Hot Reported
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN & U.S. EMISSIONS OF HYDROCARBON SPECIES, AREA & POINT SOURCES
X
X
Country
| METHANE
ETHANE
PROPANE
BUTANE
-- THOUSAND MOLES/YEAR -
ISO-BUTANE PENTANE ISO-PENT ALKANES ETHYLENE PROPYLENE ISO-BUTENE
Canada | 120.389,361 759,253 1,096,057 2,339,149 643,943 814,803 27,796 15,103,733 9,434,992 2,001,986 14,897
Contig. U.S. | 91,994,146 6,698,261 4,079,718 15,972,045 3,301,153 3,294,293 340,374 134,447,565 41,611,730 15,457,664 103,241
Total | 212,383,507 7,457,514 5,175,775 18,311,194 3,945,097 4,109,096 368,171 149,551,298 51,046,722 17,459,650 118,138
Country
ALKENES
BENZENE
TOLUENE
XYLENE
THOUSAND MOLES/YEAR
ETH BEN2 AROMATIC FORMALDEH ACETALDEH ALDEHYDES ACETONE
KETONES ORG. ACID
Canada | 6,317,955 547,649 1,172,180 1,129,434 238,103 398,445 2,626,378 330,143 105,814 424,770 309,714 33,100
Contig. U.S. | 28,722,513 5,492,770 16,492,428 13,762,475 2,870,820 4,011,537 19,199,592 2,247,947 816,293 7,253,977 4,376,829 1,594,637
Total
| 35,040,468 6,040,419 17,664,608 14,891,909 3,108,923 4,409,982 21,825,970 2,578,090 922,107 7,678,747 4,686,543 1,627,737
For conversion of hydrcarbon classes to tons/year, see discussion in Appendix E.
Note: Numbers may not sum due to rounding.
-------
the northern and western boundaries of the NAPAP domain (60° north latitude
and 125° west longitude, respectively) and were therefore not retained in
Version 5.2 of the inventory.
The temporal variability of SO2 emissions is graphically shown in
Figure 4. Since hour 12 Greenwich Mean Time corresponds to 8 a.m. Eastern
Daylight Time, it is clear that national S02 emissions are greatest during
the daytime.
Data in the Version 5.2 inventory are spatially resolved into grids
measuring 1/6 degree latitude by 1/4 degree longitude (approximately
20 x 20 km). Figure 5 is a surface plot showing the spatial distribution of
point and area source annual S02 emissions. Point and area source 862
emissions for a typical summer weekday (1 of 12 temporal scenarios) are shown
in Figure 6; here an 80 x 80 km grid is used for clarity of presentation.
Additional surface plots and grid maps are provided in Section 2.
INVENTORY ENHANCEMENTS
Several related NAPAP work assignments resulted in work products which
have been applied in the development of the current version of the 1980 NAPAP
Emissions Inventory. Emission factors were developed for HC1, HF, NH3, and
SO^, and applied to generate emissions estimates in the current inventory.
A significant improvement to the previous inventory was the integration of the
NAPAP Utility Reference File into the inventory, replacing previous National
Emissions Data System (NEDS) data with quality assured emissions estimates for
the utility sector.
In order to create the Eulerian Modeling Emissions Inventory
(Version 5.2) used in the testing of the RADM, temporal, spatial, and species
allocation factors were developed. The basis for these factors was the
Northeast Corridor Regional Modeling Project (NECRMP); these factors were
quality assured and revised as necessary. Allocation factors were developed
for those states not considered in the NECRMP study. The allocation factors
and the 1980 NAPAP Annual Emissions Inventory (Version 5.0) were used as
inputs to the Flexible Regional Emissions Data System (FREDS), an emissions
inventory data processing system developed for NAPAP. Written in the command
language of the Statistical Analysis System (SAS), FREDS was designed to allow
the vast amount of data in the NAPAP inventory to be processed efficiently.
EPA's Atmospheric Sciences Research Lab (ASRL) requested that an
emissions inventory be developed to enable testing of the Regional Oxidant
Model (ROM), which requires hydrocarbon species consistent with Carbon Bond IV
mechanisms as input. The flexibility of FREDS was utilized and a Version 5.3
inventory was developed.
An uncertainty methodology was developed by Brookhaven National
Laboratory and applied to the 1980 NAPAP Emissions Inventory; this effort and
its results are documented in a separate EPA report.
A complete listing of the products of this effort in printed and magnetic
form is presented in Table 3.
xx i
-------
5-
w
a
z
<
(A
D
O
V)
z
O
3-
234567
I
8
9 10 11 12 13 14 15
HOUR (GMT)
i
16
17 18 19 20 21 22 23 24
Figure 4. 1980 NAPAP Emissions Inventory Verison 5.2 - hourly emissions
pattern for SC>2 for a typical summer weekday.
-------
5/YR
X
X
5. 1980
Missions
U'S'
Invent
'•2 - Annual SO
-------
X
X
TONS/HR
0-0.05
0.05-1.0
Figure 6. 1980 NAPAP Emissions Inventory Version 5.2 - S0£ emissions
for a typical summer weekday at 1700 GMT.
-------
TABLE 3. NAPAP VERSION 5 PRODUCTS
Version
A 5.0/5.2/5.3
B 5.0 (Tape)
C
D-l
D-2
D-3
E
F 5.2 (Tape)
G-l
G-2
H-l
H-2
1-1
1-2
J-l
J-2
K-l
K-2
L-l
L-2
M-l
M-2
N-l
N-2
0-1
0-2
P-l
P-2
Q-l
Q-2
R-l
R-2
Description
Development of the 1980 NAPAP
Emissions Inventory (Report)
U.S. Point Sources
Canada Point Sources
U.S. Area Sources (Volume 1 of 3)
U.S. Area Sources (Volume 2 of 3)
U.S. Area Sources (Volume 3 of 3)
Canada Area Sources
Point Sources
**Area Sources (West) - Winter Weekday
Area Sources (East) - Winter Weekday
Area Sources (West) - Winter Saturday
Area Sources (East) - Winter Saturday
Area Sources (West) - Winter Sunday
Area Sources (East) - Winter Sunday
Area Sources (West) - Spring Weekday
Area Sources (East) - Spring Weekday
Area Sources (West) - Spring Saturday
Area Sources (East) - Spring Saturday
Area Sources (West) - Spring Sunday
Area Sources (East) - Spring Sunday
Area Sources (West) - Summer Weekday
Area Sources (East) - Summer Weekday
Area Sources (West) - Summer Saturday
Area Sources (East) - Summer Saturday
Area Sources (West) - Summer Sunday
Area Sources (East) - Summer Sunday
Area Sources (West) - Fall Weekday
Area Sources (East) - Fall Weekday
Area Sources (West) - Fall Saturday
Area Sources (East) - Fall Saturday
Area Sources (West) - Fall Sunday
Area Sources (East) - Fall Sunday
Temporal
resolution
Annual
Annual
Annual
Annual
Annual
Annual
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
*Data on all tapes are in EBCDIC characters.
**Area Sources are divided into 2 regions separated at 100°W longitude,
(continued)
XXV
-------
TABLE 3 (continued)
Version
S 5.3 (Tape)
T-l
T-2
U-l
U-2
V-l
V-2
W-l
W-2
X-l
X-2
Y-l
Y-2
Z-l
Z-2
AA-1
AA-2
BB-1
BB-2
CC-1
CC-2
DD-1
DD-2
EE-1
EE-2
Description
Point Sources
**Area Sources (West)
Area Sources (East)
Area Sources (West)
Area Sources (East)
Area Sources (West)
Area Sources (East)
Area Sources (West)
Area Sources (East)
Area Sources (West)
Area Sources (East)
Area Sources (West)
Area Sources (East)
Area Sources (West)
Area Sources (East)
Area Sources (West)
Area Sources (East)
Area Sources (West)
Area Sources (East)
Area Sources (West)
Area Sources (East)
Area Sources (West)
Area Sources (East)
Area Sources (West)
Area Sources (East)
- Winter Weekday
- Winter Weekday
- Winter Saturday
- Winter Saturday
- Winter Sunday
- Winter Sunday
- Spring Weekday
- Spring Weekday
- Spring Saturday
- Spring Saturday
- Spring Sunday
- Spring Sunday
- Summer Weekday
- Summer Weekday
- Summer Saturday
- Summer Saturday
- Summer Sunday
- Summer Sunday
- Fall Weekday
- Fall Weekday
- Fall Saturday
- Fall Saturday
- Fall Sunday
- Fall Sunday
Temporal
resolution
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
Hourly
*Data on all tapes are in EBCDIC characters.
**Area Sources are divided into 2 regions delineated by 100°W longitude.
xxvi
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SECTION 1
INTRODUCTION
BACKGROUND
The National Acid Precipitation Assessment Program (NAPAP) was
established by Congress in 1980 to coordinate and expand research on problems
posed by acid deposition in and around the United States. The program is
managed through- the Interagency Task Force on Acid Precipitation which
coordinates eight task groups having specific technical responsibilities.
The Task Group on Emissions and Controls is charged with development of
comprehensive and accurate inventories of emissions from sources thought to be
important in acid deposition processes. To fulfill its stated objective and
to support other related NAPAP research, the Task Group on Emissions and
Controls has generated a number of major emissions data bases. This report
focuses on the development of Version 5.0 of the 1980 NAPAP Annual Emissions
Inventory and the related Version 5.2 and 5.3 Modeling Emissions Inventories.
OBJECTIVES
The primary focus of the 1980 NAPAP Emissions Inventory is the
fulfillment of the emissions data requirements for development and testing
of the Eulerian Regional Acid Deposition Model (RADM). Within EPA's Office of
Research and Development, the Atmospheric Sciences Research Laboratory (ASRL)
has been assigned lead responsibility for developing the RADM. The National
Center for Atmospheric Research (NCAR) has been assigned the task of
developing the model framework, which includes a number of chemical
transformation modules. Since the RADM reflects the most extensive data
requirements of the anticipated applications of the NAPAP Emissions Inventory,
the specific requirements of the modules dictate the chemical species
contained in Version 5.2 of the NAPAP Emissions Inventory.
Subsequent to the definition of the requirements of the NAPAP Version 5.2
Emissions Inventory, EPA expressed its need for emissions data to support
applications of the Regional Oxidant Model (ROM), which requires hydrocarbon
speciation data consistent with Carbon Bond IV chemistry. Version 5.3 of the
1980 NAPAP Emissions Inventory was developed to meet the modelers' needs.
The NAPAP Emissions Inventory data will also support certain NAPAP
assessment activities. The emissions inventory needs for assessment purposes
are generally less detailed and resource-intensive than those required by the
modelers, but are nonetheless extremely important to the overall NAPAP
-------
program. Assessment projects use more aggregated emissions information in
combination with models or other analytical techniques to evaluate the
relative importance of various pollutants, regions, and types of sources to
the acid deposition problem. Results of these studies have implications for
planning additional research needed and development of potential
control/mitigation strategies.
1980 NAPAP EMISSIONS INVENTORY
Versions 5.0, 5.2, and 5.3 of the 1980 NAPAP Emissions Inventory used as
their bases earlier versions (4.0 and 4.2) of the inventory. Compilation and
development of the current inventory required the integration of several
unique but related work efforts, as shown in Figure 1-1. The contents of the
primary products of this effort, Versions 5.0, 5.2, and 5.3, are described in
Table 1-1. Both Volatile Organic Compounds (VOC) and Total Hydrocarbons (THC)
are present in the inventory; the VOC category is defined as reactive
hydrocarbon species (no methane or ethane), while THC is comprised of both
reactive and nonreactive species.
The 1980 NAPAP Emissions Inventory, representing the most comprehensive
and highest quality emissions data available for the 1980 base year, evolved
from EPA1s National Emissions Data System (NEDS) 1980 "snapshot" inventory. A
number of updates were made to enhance the quality and comprehensiveness of
the NEDS data. These included substitution of specific data items with
information from other inventories or data bases believed to be more
reliable. Since NAPAP requires emissions data for a number of pollutants not
included in NEDS, emission factors and corresponding emissions estimates had
to be developed and incorporated. Emissions data from Canada were added, and
improvements were made to methods used to calculate area source and highway
vehicle emissions.
Recognizing the importance of the utility industry in the estimation of
both current and future emissions levels, NAPAP has developed a single data
base designed to address utility-related data needs of all NAPAP task groups
(Pechan, 1983). The NAPAP Utility Reference File (NURF) consists of four
component files: the master unit data file (containing information on all
electric generating units), the fuel-specific emissions file (containing
emissions information by fuel type), the stack parameters file (containing
stack information on a unit-specific basis), and the announced unit file
(containing unit-specific information on units coming on-line or converting to
coal-firing after 1980). The NURF was utilized to derive and verify emissions
data from the utility sector in Version 5.0 of the NAPAP Emissions Inventory.
To support development and testing of the models, one of the most
extensive applications of the NAPAP Emissions Inventory, the 1980 Annual
Inventory (Version 5.0) had to be resolved temporally, spatially, and by
component species to create an Eulerian modeling emissions inventory
(Version 5.2) and an oxidant modeling emissions inventory (Version 5.3).
Annual emissions were allocated to the hourly level for a typical weekday,
Saturday, and Sunday in each season (12 temporal scenarios); county-level area
sources and major and minor point sources were spatially resolved to modeling
-------
1980 NEDS EMISSIONS DATA
SUPPLIED BY THE STATES
• EMISSION FACTORS FOR
NON-NEDS POLLUTANTS
• NADB-DEVELOPED COUNTY LEVEL
AREA SOURCE INVENTORY
• CANADIAN EMISSIONS DATA ».
• NAPAP UTILITY REFERENCE FILE »•
• QUALITY ASSURANCE
• UNCERTAINTY ESTIMATES
1980 NAPAP ANNUAL EMISSIONS
INVENTORY (VERSION 5.0)
SPATIAL ALLOCATION FACTORS
TEMPORAL ALLOCATION FACTORS
SPECIATION FACTORS (NOX>
TSP, THC)
FLEXIBLE REGIONAL EMISSIONS
DATA SYSTEM (FREDS)
QUALITY ASSURANCE
UNCERTAINTY ESTIMATES
1980 EMISSIONS INVENTORY FOR
THE EULERIAN ATMOSPHERIC MODEL
(VERSION 5.2)
1980 EMISSIONS INVENTORY FOR
THE REGIONAL OXIDANT MODEL
(VERSION 5.3)
Figure 1-1. Major program components for developing the
1980 NAPAP emissions inventory.
-------
TABLE 1-1. 1980 NAPAP EMISSIONS INVENTORY COVERAGE
Annual Emissions
Inventory
Version 5.0
Eulerian Model
Emissions Inventory
Version 5.2
Oxidant Model
Emissions Inventory
Version 5.3
Temporal
resolution
Geographic
domain and
resolution
Anthropogenic
point sources
Anthropogenic
area sources
Pollutants
Annual/seasonal
Hourly emissions values for typical
weekday, Saturday, and Sunday for all four
seasons
48 contiguous 48 states and Canada from 50° to 125°
states and Canada; west longitude and from 25° to 60° north
area sources at latitude; separate major point source file
the county level with minor point sources and area sources
assigned to 20 x 20 km grid cells
Stationary sources emitting greater than or equal to 100 tons
of criteria pollutants in 1980
Stationary sources emitting less than 100 tons of criteria
pollutants in 1980 and county-level area sources
SO SO TSP,
Pb, CO, HC1, HF,
NO NH3, VOC,
total hydro-
carbons (THC)
SO , SO, , TSP (Ca,
Mg, K, Na), Pb, CO,
HC1, HF, NO, N02,
NH , VOC, THC
(methane, ethane,
ethylene, propane,
propylene, N-butane,
1,2-butane, isobu-
tene, pentane,
isopentane, other
alkenes, other
alkanes, other or-
ganic acids, formal-
dehyde, acetaldehyde,
acetone, other ketones
other aldehydes,
xylene, benzene,
toluene, ethylbenzene,
other aromatics)
SO , SO , TSP (Ca,
Mg, K, fta), Pb, CO,
HC1, HF, NO, N0?,
NH3, VOC, THC
(methane, paraffins,
ethylene, olefins,
formaldehyde, other
aldehydes, toluene,
xylene, isoprene,
nonreactives)
-------
grid cells; TSP emissions were assigned to alkalinity classes; NOX emissions
were split into NO and NC>2 constituents; and THC emissions were apportioned
into as many as 28 photochemical reactivity classes.
To create the 1980 NAPAP Modeling Emissions Inventories, temporal,
spatial, and pollutant species allocation factors were developed and applied
to the Version 5.0 data base. In addition to creating allocation factors to
address the requirements of the models, a data handling system capable of
creating subsequent versions of the NAPAP Emissions Inventory was developed.
The Flexible Regional Emissions Data System (FREDS), consisting of five
primary independent subsystems written in the command language of the
Statistical Analysis System (SAS), was used to preprocess the Emissions
Inventory System (EIS) formatted emissions data for input to the RADM.
FREDS was also used to generate a SAS version of the 5.0 NAPAP Emissions
Inventory for incorporation into the Acid Deposition Data Network (ADDNET).
To be able to evaluate the results of the NAPAP modeling and assessment
analyses, it was necessary to estimate the uncertainty associated with the
NAPAP Emissions Inventory data. The analysis of uncertainty, while important
for all NAPAP Emissions Inventory applications, is particularly crucial for
the atmospheric modeling efforts aimed at establishing relationships between
the release of precursor emissions and acid deposition. The degree of
uncertainty in the emissions inventory will be a limiting factor in the
quantification of these relationships.
NAPAP has developed a methodology for quantifying the degree of
uncertainty associated with the NAPAP emissions data (Benkovitz, 1985).
Ongoing NAPAP efforts are developing uncertainty estimates for the individual
parameters that will be input to the NAPAP uncertainty methodology. To enable
development of preliminary estimates of uncertainty within the 1980 NAPAP
Emissions Inventory prior to completion of these efforts, a NAPAP Emissions
Inventory Uncertainty Workshop was held (Homolya, 1985). At that workshop a
panel was assembled to develop a consensus regarding the uncertainty
associated with parameters used to calculate annual emissions and resolve them
in space, in time, and by pollutant species. Based on these uncertainty
estimates, the methodology was tested and preliminary estimates of emissions
uncertainties were derived and documented in an EPA report (Wagner, et al.,
1986).
REPORT ORGANIZATION
Section 2 summarizes emissions data from Version 5.0 and Version 5.2 of
the 1980 NAPAP Emissions Inventory. A discussion of the evolution of the 1980
NAPAP Emissions Inventories is presented in Section 3. Section 4 describes
the formulation of emission factors used to derive estimates of emissions of
hydrogen chloride (HC1), hydrogen fluoride (HF), ammonia (NH3), primary
sulfate (SO^), and alkaline dust. The development of emissions estimates
for the utility sector is discussed in Section 5. The development of
temporal, spatial, and pollutant species allocation factors required to
generate the modeling emissions inventories is covered in Section 6.
Section 7 discusses the creation of the data handling system used to process
Version 5.0 and create Version 5.2 and 5.3 of the 1980 NAPAP Emissions
Inventory.
5
-------
SECTION 2
OVERVIEW OF EMISSIONS DATA
The following pages present summary data from Version 5 of the 1980 NAPAP
Emissions Inventory in tabular and graphic form. The Version 5.0 inventory
contains annual point source emissions data for over 14,000 plants in the
United States and Canada, encompassing more than 36,000 emissions points. It
also contains area source data for the 3,070 counties in the 48 contiguous
United States and the District of Columbia, as well as province level data
from Canada south of 60° latitude and east of 125° longitude. The Version 5.2
Eulerian Modeling Inventory covers a similar study area, providing additional
temporal, spatial, and species resolution.
VERSION 5.0
Summary of Total Emissions
Table 2-1 summarizes emissions for the 11 pollutants in the Version 5.0
inventory by EPA Region. Both Volatile Organic Compounds (VOC) and Total
Hydrocarbon (THC) categories are present in the inventory; the VOC category is
defined as reactive hydrocarbon species (no methane or ethane), while THC is
comprised of both reactive and nonreactive species. Region 5 is the most
significant contributor in 7 of the 11 categories, while Region 6 contributes
the most NOX and TSP emissions. Region 4 is also a significant source of
emissions, leading all regions in sulfate and hydrogen fluoride; the 14 states
in Regions 4 and 5 contribute over half the inventory's S02 emissions.
The data in Table 2-1 are further subdivided by state in Table 2-2. In
nearly all categories, Ohio (most 802), Texas (most NOX and TSP), and
California (most CO and VOC) contribute significantly to U.S. emission totals.
Canadian emissions data are summarized at the province level in
Table 2-3. It should be noted at the outset that Canadian data do not include
emissions of chloride, fluoride and lead, and that Canadian emissions reported
include only that portion of Canada within the NAPAP study area and therefore
do not constitute total national emissions. Emissions for all Canadian
provinces are available from Environment Canada. Ontario is clearly the
largest emissions source, leading in emissions of S02, NOX, CO, VOC, and
total hydrocarbons, while Alberta contributes more ammonia and TSP than any
other province.
-------
TABLE 2-1. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.0 - ANNUAL U.S. POINT
AND AREA SOURCE EMISSIONS BY EPA REGION
EPA REGION |
REGION 1 |
REGION 2 |
REGION 3 |
REGION 4 |
REGION 5 |
REGION 6 |
REGION 7 |
REGION 8 |
REGION 9 |
REGION 10 |
Contig. U.S.j
S02
685,936
1,180,163
3,858,772
6,473,217
7,867,419
2,179,556
1,973,687
793,365
1,512,034
429,988
26,954,136
S04
41,953
63,920
126,506
206,358
202,874
113,688
45,243
54,576
73,455
47,035
975,608
NOx
596,578
1,154,353
2,234,725
3,978,083
4,467,218
4,957,327
1,541,904
1,065,188
1,743,576
613,287
22,352,239
Pb
1,415
1,979
3,748
5,199
8,105
3,573
1,725
1,485
3,116
1,387
31,732
CO
4,703,212
7,052,898
9,526,520
16,253,808
18,753,223
15,437,049
4,993,826
6,096,071
11,356,048
5,136,282
99,308,937
lUNS/TCAK
HCl
3,847
11,835
86,787
130,211
165,692
35,964
44,940
28,165
12,963
6,120
526,524
HF
215
2,208
13,285
48,740
27,076
10,851
5,768
3,765
1,676
1,850
115,434
NH3
2,470
14,042
40,660
135,784
205,228
133,234
176,547
55,581
44,639
30,479
838,664
TSP
657,426
1,204,930
2,573,135
5,088,856
5,286,234
9,727,381
7,049,162
5,204,444
3,297,549
2,528,253
42,617,370
VOC
1,185,538
1,857,619
2,210,510
4,075,244
4,414,825
3,537,629
1,285,770
1,005,242
2,564,528
1,027,643
23,164,547
THC
1,274,058
2,016,830
2,360,328
4,316,670
4,805,098
3,847,014
1,409,712
1,073,957
2,785,895
1,087,898
24,977,459
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TABLE 2-2. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.0 - ANNUAL U.S. POINT
AND AREA SOURCE EMISSIONS BY STATE
State
A I aba/na
Arizona
Arkansas
Cat i form* a
Colorado
Connecticut
Delaware
Dist. of Colon.
Florida
Georgia
Idaho
III mois
Indi ana
loua
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
M i ssour i
Montana
Nebraska
Nevada
New Hampshire
New Jersey
New Mexico
New York
North Carolina
North Dakota
Ohio
Oklahoma
Oregon
Pennsylvania
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Utah
Vermont
Virginia
Washington
West Virginia
Wisconsin
Wyoming
Cont i g. U.S.
S02
857,549
844,078
87,127
519,799
140,138
63,665
124,669
15,325
1.102,994
900,080
56,210
1,464,520
1,970,870
334,278
228,074
1,150,036
401,333
133,369
303,471
358,065
841,399
238,705
303,846
1,335,218
169,224
78,117
148,157
108,484
309,856
262,555
870,307
655,591
115,391
2,681,314
104,168
55,987
1,899,006
14,168
344,968
40.863
1,158,153
1,324,373
116,615
8,185
370,780
317,791
1,145,522
670,610
211,134
26,954,136
S04
32,991
30,871
10,478
35,957
9,347
8,110
4,645
1,121
30,793
30,684
8,676
42,270
38,111
11,010
7,409
23,108
24,581
11,223
10,727
14,498
32,609
14,535
11,281
22,746
7,583
4,078
6,667
4,867
20,690
9,202
43,230
31.046
11,574
51,554
9,558
18,601
60,532
1,491
17,550
3,798
28,905
59,869
8,886
1,764
21,579
19,758
27,902
23,795
13,388
975 , 608
NOx
487,256
263,894
211,143
1,382,764
304,778
139,750
62,266
25,352
712,209
590,650
91,874
972,987
786,843
305,754
513,314
551,354
708,966
67,068
261,103
270,770
715,377
366,630
294,511
549,797
140,299
173,039
96,918
58,957
417,509
254,116
736,844
532,675
136,091
1,217,607
453,066
226,767
1,041,556
36,253
278,092
79,356
531,336
3,330,036
155,757
23,780
383,434
294,646
461,014
407,774
248,907
22,352,239
Pb
681
366
264
2,643
756
381
71
39
1,087
697
548
2,635
1,101
427
250
519
554
124
456
666
1,148
469
297
849
310
199
107
100
706
174
1,273
727
72
2,160
412
334
1,918
82
459
70
732
2,169
191
62
646
505
618
592
86
31,732
CO
1,811,119
1,310,433
1,045,560
9,524,250
2,302,185
1,192,328
242,885
338,780
4,071,755
2,335,826
1,280,507
4,246,797
2,374,627
1,105,666
1,072,560
1,594,516
2,541,546
506,637
1,459,780
2,133,002
3,613,069
1,928,665
991,881
2,206,090
1,422,156
609,510
521,365
352,582
2,294,053
932,466
4,758,845
2,289,334
282,219
4,697,200
1,854,007
1,454,001
4,377,701
316,586
1,207,907
509,495
1,951,470
9,063,470
990,051
202,077
2,322,403
2,401,774
784,971
1,892,865
589,965
99,308,937
UNVTtAK-
HCl
19,542
8,937
1,786
472
9,110
491
1,152
655
8,834
20,453
329
34,318
33,494
11,505
6,614
22,635
857
40
6,559
2,241
22,871
8,820
2,599
22,184
2,003
4,637
3,554
1,036
2,566
8,299
9,269
23,667
119
50,783
5,765
729
42,015
27
9,045
235
23,436
19,257
3,588
12
7,328
5,062
29,078
15,406
13,110
526,524
HF
3,539
1,087
1,445
145
1,186
0
184
23
29,228
2,503
242
7,937
4,607
1,706
799
3,841
1,761
5
1,307
86
3,150
1,120
314
2,681
243
582
444
124
328
977
1,880
3,310
60
7,934
768
92
5,525
0
1,648
38
4,357
5,900
511
0
1,385
1,516
4,861
2,328
1,727
115,434
NN3
11,964
11,921
25,418
32,013
24,987
1,946
2,051
59
28,793
35,359
8,133
68,633
29,361
80,410
34,189
8,185
26,314
417
2,992
104
10,433
48,624
7,809
17,264
3,890
44,683
705
1
80
4,523
13,961
21,118
6,642
16,124
15,266
4,249
24,309
0
4,440
12,941
18,117
61,713
1,961
3
10,913
18,097
335
32,054
5,159
838,664
TSP
439,271
841,489
874,245
1,536,414
1,134,995
120,226
49,382
15,099
919,841
882,031
330,728
932,702
496,649
1,237,845
1,852,371
452,395
559,071
127,174
227,611
210,504
880,263
1,199,026
587,204
2,877,954
880,654
1,080,992
919,646
66,310
402,215
1,249,009
802,715
700,462
1,295,268
1,070,910
1,107,180
1,849,960
1,432,694
32,323
451,493
715,996
656,159
5,937,876
690,811
100,889
466,354
347,565
381,995
706.684
486,720
42,617,370
VOC
391,455
254,096
223,135
2,216,485
356,946
284,183
77,101
44,081
828,561
508,361
222,050
988,586
562,647
237,157
250,269
441,688
625,559
141,991
363,270
515,765
916,363
469,214
261,800
629,726
236,467
168,618
93,948
103,987
696, 758
191,042
1,160,860
614,002
53,274
1,001,059
324,988
340,267
1,043,563
81,042
474,791
95,639
554.586
2,172,905
160,449
58,570
527,715
465,326
154,780
476,956
102,467
23,164,547
THC
425,591
271,243
234,377
2,414,927
385,554
299,090
81,188
48,400
868,694
530,222
230,398
1,092,842
623,821
258,603
298,662
469,555
669,847
149,051
394,420
568,190
987,380
496,094
278,672
673,526
245,600
178,920
99,725
109,401
749, 784
213,500
1,267,046
655,149
58,166
1,092,677
347,352
363,147
1,113,027
86,846
501,073
101,160
587,715
2,381,939
172,386
61,481
561,508
494,352
161,785
512,284
111,091
24,977,459
-------
TABLE 2-3. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.0 - ANNUAL CANADIAN POINT
AND AREA SOURCE EMISSIONS BY PROVINCE
1 UNa/ TEAK
Province |
Alberta |
British Columbia |
Hani toba |
New Brunswick |
Newfoundland |
Nova Scotia |
Ontario |
Prince Edward I stand |
Quebec |
Saskatchewan |
Canada |
S02
660,788
184,106
533,199
223,053
65,635
212,343
1,954,125
4,973
1,210,291
60,125
5,108,638
S04
7,677
34,915
13,790
14,963
4,604
11,094
45,947
343
50,699
4,250
188,282
NOx
485,564
221,795
102,392
58,760
35,930
83,476
563,749
6,130
321,999
174,217
2,054,012
Pb
0
0
0
0
0
0
0
0
0
0
NR
CO
3,023,686
2,203,914
1,603,510
347,965
197,323
393,785
4,424,186
57,947
2,409,711
3,373,897
18,035,924
HCl
0
0
0
0
0
0
0
0
0
0
NR
HF
0
0
0
0
0
0
0
0
0
0
NR
NH3
83,323
7,012
21,011
1,024
123
1,646
46,260
832
16,564
31,879
209,674
TSP
8,828,141
2,025,634
3,142,219
415,749
280,665
763,019
6,604,382
41,629
2,491,946
6,980,762
31,574,146
VOC
685,711
285,050
233,681
51,010
28,948
73,664
733,251
6,501
390,108
505,957
2,993,881
THC
898,962
530,780
325,091
114,009
78,892
149,945
1,482,757
17,202
946,493
593,482
5,137,613
NR = NOT REPORTED
-------
The relative weight of point and area source contribution to emissions
varies from state to state and pollutant to pollutant. Appendix A provides
additional resolution of point and area source emissions on the state/province
and SCC level. Figure 2-1 illustrates graphically the relative contributions
of point and area source emissions for S02, NOX, and VOC. Sulfur dioxide,
associated primarily with utilities and industrial operations, is heavily
represented by point sources. VOC emissions are concentrated in the area
sources, including the solvent use/evaporation and transportation categories.
NOX represents a more even distribution between point and area sources,
reflecting a relatively equal mix of industrial sources and vehicular
transportation. Canadian emissions generally represent 10-20 percent of NAPAP
totals, with Canadian area source TSP being a noteworthy exception (41 percent
of NAPAP total). The relatively heavy TSP emissions in Canada reflect
emissions estimation methodology differences between the two nations; attempts
have been made to minimize these differences by removing from Canadian totals
those area source categories having no U.S. counterparts, namely agricultural
tilling, construction, and wind erosion. The distribution of Canadian
emissions between point and area sources generally parallels U.S. data.
Table 2-4 illustrates S02, NOX, and VOC emissions aggregated by major
source categories. U.S. emissions of S02 are dominated by the electric
utility sector (65 percent); the overwhelming majority of these emissions are
from coal-fired external combustion boilers. Industrial combustion sources
and manufacturing operations combine for another 25 percent of total U.S.
S02 emissions. NOX emissions, as mentioned earlier, are fairly evenly
distributed between combustion sources and vehicular transportation.
Emissions of VOC are dominated by transportation and manufacturing operations,
including solvent losses. Other sources, constituting about 13 percent of
U.S. VOC totals, include forest fires and managed burning (1.2 million tons),
gasoline marketed (950,000 tons), agricultural processes, and minor point
sources, which are aggregated into a single area source category to facilitate
processing (see Section 3 for details). Canadian sources are distributed in a
similar fashion with one notable exception. A much higher percentage of
Canadian SO2 emissions is attributed to industrial/manufacturing operations
than in the U.S. This is due primarily to the fact that nonferrous smelters
contribute over one-third of total Canadian S02 emissions, a much larger
percentage than in the United States. Forest fires and managed burning also
contribute heavily to Canadian VOC emissions, accounting for over 1 million
tons of VOC per year. Pie charts depicting the data in Table 2-4 are shown in
Figures 2-2 and 2-3.
Though the 1980 NAPAP Emissions Inventory was based on NEDS data for base
year 1980, information in the file was actually collected over a range of
years from 1966 to 1982. The current distribution of U.S. and Canadian point
and area source emissions by year of record, shown in Figure 2-4, represents a
number of updates and improvements to the original NEDS data, particularly
with regard to utility sources. These updates are discussed in Section 3. It
should be noted that most identification and stack parameter data would not be
expected to change on a yearly basis, and that annual throughputs remain
fairly constant over the short term; therefore, data not associated with a
1980 year of record are not necessarily in error.
10
-------
so,
U.S. AREA
VOC
CANADIAN POINT
13.551
CANADIAN AREA
2.38>
CANADIAN POINT
1.44«
CANADIAN AREA
10.011
U.S. POINT
15.16s
NO,
U.S. POINT
39.51%
CANADIAN POINT
1.57»
CANADIAN AREA
6.85<
Figure 2-1. 1980 NAPAP Emissions Inventory Version 5.0 - relative distribution
of point versus area source emissions for SC>2, NOX, and VOC.
11
-------
TABLE 2-4. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.0 - POINT AND
AREA SOURCE EMISSIONS BY MAJOR CATEGORY
U.S. sources
Electric utilities
Industrial combustion
Commercial /residential /other combustion
Indus trial /manufacturing processes
(including solvent evaporation)
Transportation
Other
U.S. Total:
Canadian sources
Electric utilities
Industrial combustion
Commercial /residential /other combustion
Indus trial /manufacturing processes
Transportation
Other
Canadian total:
Emissions
S02
17,479
3,606
1,153
3,473
879
365
26,954 2
849
610
249
3,250
149
1
5,109
(103
NOX
6,448
4,283
1,061
693
9,266
601
12,352
249
146
122
179
1,023
335
2,054
tons/yr)
VOC
47
197
2,563
7,079
10,348
2,931
23,165
6
4
22
1,018
823
1,120
2,994
12
-------
so,
IND/HFG PROC.
12 «8«
TRANSPORTATION
44.671
tO. COMBUSTION
0.85«
VOC
IND/VFC PROC.
30.56«
INC. COMBUSTION
I3.38"
TRANSPORTATION
3.26f
OTHER COUBUST.
4.28«
NO,
TRANSPORTATION
41.45i
I NO. COMBUSTION
19.16*
IND/MFG PROC.
3-10* OTHER
2.69«
OTHER COMBUST.
UTILITIES
0.20«
OTHER
12.65"
OTHER COMBUST.
4.75»
UTILITIES
28.85«
Figure 2-2. 1980 NAPAP Emissions Inventory Version 5.0 - distribution of
U.S. emissions by source category for S02, NOX and VOC.
13
-------
so,
IND. COMBUSTION
11.941
TRANSPORTATION
2.91«
NO
x
I NO/MFC PROC.
«3.82i
OTHER COUBUST
5.Ml
voc
IND. COMBUSTION
O.U«
TRANSPORTATION
27.50%
IND/MFG PROC.
34.001
OTHER COMBUST.
0.75«
UTILITIES
0.20«
Figure 2-3. 1980 NAPAP Emissions Inventory Version 5.0 - distribution of
Canadian emissions by source category for SC>2, NOX and VOC.
14
-------
30,000,000 1
o;
20,000,000 '
CO
T
5
o
C/)
CO
2
10,000,000
NOX S02 VOC
PRE-75
NOX 802 VOC
75-79
NOX 802 VOC
80 1
NOX 802 VOC
81-82
POLLUTANT
YEAR
Figure 2-4. 1980 NAPAP Emissions Inventory Version 5.0 - combined
U.S. and Canadian emissions totals by year of record.
-------
Point and area source emissions percentages are tabulated by release
height, an important modeling parameter, in Table 2-5. SC^ emissions are
dominated by point sources in the high stack height ranges; over 68 percent of
SC>2 comes from stacks in excess of 240 feet in height. Again, these large
stacks correspond to utilities, smelters, and other major emitters. VOC
emissions are concentrated at the lowest release height range, representing
fugitive solvent evaporation, transportation, and emissions from area sources
to an overwhelming degree.
Point-Specific Emissions Data
Point source data in the NAPAP inventory can be considered to exist on
three levels—plant, point, and SCC. Each SGC, representing the greatest
degree of disaggregation, represents a process or function within a source
category logically associated with a point of air pollution emissions.
Several SCC-level observations may be associated with a single "point";
similarly, several point-level records may exist for each individual plant.
There are 52,904 SCC-level records in Version 5.0 of the NAPAP Emissions
Inventory, corresponding to 36,807 individual points located in 14,244 unique
plants. Table 2-6 presents a distribution of these sources by emissions
range. Emissions of S02, and to a lesser degree NOX, are concentrated
within a small number of large emitters, such as utilities and smelters. VOC
emissions, on the other hand, are distributed among a much larger number of
proportionally minor emissions sources. A total of 225 plants emit greater
than 25,000 tons of S02 annually; the locations of these major emitters are
shown in Figure 2-5.
Figure 2-6 illustrates the distribution of point source emissions of
SOo, NO , and VOC by emissions estimation method. Estimation methods 3
and 5 constitute the vast majority of criteria pollutant emissions in the
inventory. Utility source estimation methods were changed to 3 during the
utility updates discussed in Section 3. Systematic QA checks also
necessitated computer recalculation of emissions for many other sources; these
methods were also changed to 3. In general, any estimation method other
than 3 would provide (in theory) a better estimate of emissions than would
method 3. The preponderance of method 3 emissions as shown in Figure 2-4
merely indicates that the states requested that OAQPS calculate emissions
based on AP-42 emission factors in NEDS and reported operating data. S02
data for copper smelters taken from the Work Group 3B inventory and nonutility
NOX and VOC emissions from the NECRMP modeling effort constitute the
majority of method 5 emissions in the United States. In addition, all
Canadian emissions are reported under estimation method 5.
State and County Emissions Density
Emissions density maps were created on the state and county level by
aggregating point and area source emissions and dividing by land area. The
state emission density maps, Figures 2-7 through 2-17, provide a general
geographic distribution of emissions on a statewide basis. Maps of emissions
density at the county level, shown in Figures 2-18 through 2-22, provide a
16
-------
TABLE 2-5. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.0 -
EMISSIONS PERCENTAGES BY EMISSIONS RELEASE
HEIGHT (COMBINED U.S. AND CANADIAN SOURCES)
Emissions percentages
Stack height range (ft)
0-120
121-240
241-480
>480
S02
19.2
12.5
30.1
38.2
NOX
69.1
7.1
12.7
11.1
VOC
98.7
0.9
0.3
0.1
Emissions Totals:
(10-* tons/year)
100.0 100.0 100.0
32,063 24,406 26,158
17
-------
TABLE 2-6. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.0 - DISTRIBUTION OF
S02, NOX, AND VOC EMISSIONS POINT SOURCES BY SIZE RANGE
NUMBER OF PLANT-LEVEL RECORDS
EMISSIONS RANGE
(TONS/YEAR)
>10,000
2,500 - 10,000
1,000 - 2,500
100 - 1,000
0 - 100
PLANT-LEVEL TOTAL:
EMISSIONS RANGE
(TONS/YEAR)
>10,000
2,500 - 10,000
1,000 - 2,500
100 - 1,000
0 - 100
POINT-LEVEL TOTAL:
EMISSIONS RANGE
(TONS/YEAR)
>10,000
2,500 - 10,000
1,000 - 2,500
100 - 1,000
0 - 100
US
418
595
598
2,118
9,950
13,679
US
518
887
1,223
6,674
25,181
34,483
US
516
867
1,237
7,030
40,509
S02
CANADA
50
65
61
109
280
565
S02
CANADA
53
88
106
313
1,764
' 2,324
S02
CANADA
73
93
111
335
2,133
TOTAL
468
660
659
2,227
10,230
14,244
NUMBER
TOTAL
571
975
1,329
6,987
26,945
US
NOX
CANADA TOTAL
224 6
513 23
582 * 33
2,624 138
9,736 365
13,679 565
OF POINT-LEVEL RECORDS
US
164
706
834
6,841
25,938
NOX
CANADA
6
21
41
305
1,951
36,807 34,483 2,324
NUMBER OF SCC-LEVEL RECORDS
TOTAL
589
960
1,348
7,365
42,642
US
162
694
771
7,297
41,235
NOX
CANADA
6
28
40
334
2,337
230
536
615
2,762
10,101
14,244
TOTAL
170
727
875
7,146
27,889
36,807
TOTAL
168
722
811
7,631
43,572
VOC
US CANADA TOTAL
54 3 57
277 42 319
411 20 431
2,971 103 3,074
9,966 397 10,363
13,679 565 14,244
VOC
US CANADA TOTAL
23 3 26
221 38 259
502 40 542
5,236 188 5,424
28,501 2,055 30,556
34,483 2,324 36,807
VOC
US CANADA TOTAL
20 3 23
222 38 260
490 40 530
5,352 189 5,541
44,075 2,475 46,550
SCC-LEVEL TOTAL:
50,159
2,745 52,904
50,159
2,745 52,904
50,159
2,745 52,904
18
-------
Figure 2-5. 1980 NAPAP Emissions Inventory Version 5.0 - spatial distribution
of point sources emitting greater than 25,000 tons/year SC^-
-------
so.
NO
x
VOC
20 i
10 -
15 -
co
O
co
o
10 '
re
o
5 -
co
to
CO
12345
ESTIMATION METHOD
Key to estimation method codes:
1. Stack Test
2. Material Balance
3. Emission Factor (AP-42)
4. Engineering Judgement
5. Local/Other Emission Factor
a:
I
to
O
o
CO
o
5 1
4 •
3 -
2 '
ESTIMATION METHOD
ESTIMATION METHOD
Figure 2-6. 1980 NAPAP Emissions Inventory Version 5.0 - distribution of
point source emissions by estimation method.
-------
TONS/SQ.MI I I 0-10
10-20
>20
Figure 2-7. 1980 NAPAP Emissions Inventory Version 5.0 - S02 state emissions density.
-------
-------
TONS/SQ.MI I I 0-10
10-20
>20
Figure 2-9. 1980 NAPAP Emissions Inventory Version 5.0 - VOC state emissions density.
-------
TONS/SO.MI I I 0-15
15-25
>25
Figure 2-10. 1980 NAPAP Emissions Inventory Version 5.0 - TSP state emissions density.
-------
TONS/SO.MI
0-0.2
0.2-0.5
>0.5
Figure 2-11. 1980 NAPAP Emissions Inventory Version 5.0 - NH^ state emissions density.
-------
TONS/SQ.MI
J 0-0.5
0.5-1.0
Figure 2-12. 1980 NAPAP Emissions Inventory Version 5.0 - SO^ state emissions density,
-------
TONS/SQ.MI
C
0-0.01
0.01-0.05
>0.05
Figure 2-13. 1980 NAPAP Emissions Inventory Version 5.0 - Pb state emissions density.
-------
00
TONS/SO.MI
I I 0-50
50-100
>100
Figure 2-14. 1980 NAPAP Emissions Inventory Version 5.0 - CO state emissions density.
-------
TONS/SQ.MI I I 0-0.1
0.1-0.5
>0.5
Figure 2-15. 1980 NAPAP Emissions Inventory Version 5.0 - HC1 state emissions density.
-------
TONS/SQ.MI
0-0.05
0.05-0.10
>0.10
Figure 2-16. 1980 NAPAP Emissions Inventory Version 5.0 - HF state emissions density.
-------
TONS/SO.MI
0-10
10-20
>20
Figure 2-17. 1980 NAPAP Emissions Inventory Version 5.0 - THC state emissions density.
-------
c*
$
Gf
\T>
\
0*
1
1
6
o
£
<»
V*
a)
V
^
k ^
1 ^
^^
%
o
.^
<»
^
"k
Oi ®
\
o -^
r\ ^
\\ ^
\ \
I*
<*
&
%
Y"
6)
^
\*»
-------
rti
*»'
\
(6
1
<$>
I
$ r-x
CP \ \
0 \ >
* \
^ V
^
«)
t
y*
w
«
\»
o
^
0>
y^
\
&
v>
r<
y
\
3
1
°a 1
« *
rt
V
V*
%
u>
*o
%
V*
-------
-------
-------
TONS/SQ.MI
0-0.2
0.2-0.5
>0.5
Figure 2-22. 1980 NAPAP Emissions Inventory Version 5.0 - NH3 county emissions density.
-------
significantly greater degree of resolution. Emissions ranges for S02, NOX
and VOC were standardized for comparative purposes, but it was not practical
to extend this standardization to other pollutants due to their radically
different emissons levels. In addition, emissions ranges on the state density
maps generally differ from those on the county density maps for the same
pollutant. This accounts for the presence of many counties in Arizona and New
Mexico in the middle S02 emissions range, while the aggregated state density
falls in the lowest category in Figure 2-7. Ammonia range* are comparatively
narrow, making the state density categories highly sensitive to individual
counties with exceptionally high emissions. In Louisiana., for example, enough
ammonia is generated by three counties to place the entire state within the
high range on the state density map. The majority of S02, NOX, and VOC
emissions are associated with heavily industrialized areas, primarily east of
the Mississippi River. Total particulate emissions are concentrated in both
urban and agricultural areas, while ammonia emissions are centered in the
midwest, due principally to agricultural applications.
VERSION 5.2
The 1980 NAPAP Eulerian Modeling Emissions Inventory (Version 5.2)
provides additional temporal, spatial, and species resolution of the
information contained in Version 5.0 by applying a series of allocation
factors to the annual emissions data. A detailed description of the
development and application of these factors is the subject of Section 6 of
this report.
Tables 2-7 through 2-9 summarize emissions by EPA region, state, and
province, respectively. Note that NOX emissions are apportioned into NO and
N02, TSP emissions include four classes of alkaline dust, and total
hydrocarbons (THC) are allocated to classes based on photochemical
reactivity. Region 5 remains the largest source of hydrocarbon emissions,
while Regions 4 and 6 also contribute significantly. Among hydrocarbons,
alkanes have the largest emissions, primarily due to the large number of
individual species represented in the class (approximately half of the 160
species in the inventory). On a state level, Texas and California lead in
emissions of virtually all hydrocarbon species; in Canada, Ontario, Quebec,
and Alberta are the greatest contributors.
The reader will note that Version 5.2 emissions totals for some
pollutants are slightly smaller than those in the 5.0 inventory. This is due
to the fact that some emissions sources could not be properly allocated due to
missing or invalid data. As an example, 40 Canadian point source observations
fell outside the northern and western boundaries of the NAPAP grid system and
were therefore not retained in Version 5.2 of the inventory. A complete
synopsis of inventory processing is contained in Section 7.
The NAPAP 5.2 Inventory can temporally allocate emissions to the hourly
level for a typical weekday, Saturday, or Sunday in any of the four seasons.
Table 2-10 illustrates the seasonal variation in emissions of S02, NOX,
and VOC. The greatest variation (2.7 percentage points between spring and
fall) occurs for VOC, while NOX emissions are relatively independent of
37
-------
TABLE 2-7a. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.2 - ANNUAL U.S. POINT
AND AREA SOURCE EMISSIONS BY EPA REGION
00
00
EPA REGION | S02
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
Contig
1
2
3
4
5
6
7
8
9
10
U.S.
685,936
1,180,163
3,858,772
6,473,217
7,867,419
2,179,556
1,973,687
793,365
1,512,034
429,988
26,954,136
S04
41,953
63,920
126,506
206,358
202,874
113,688
45,243
54,576
73,455
47,035
975,608
NO
552,696
1,075,799
2,096,543
3,725,913
4,187,088
4,640,733
1,440,226
993,160
1,604,421
560,507
20,877,086
N02
43,882
78,555
138,182
252,170
280,130
316,592
101,678
72,028
139,155
52,780
1,475,151
Pb
1,415
1,979
3,748
5,199
8,105
3,573
1,725
1,485
3,116
1,387
31,732
CO
4,703,212
7,052,898
9,526,520
16,253,808
18,753,223
15,437,049
4,993,826
6,096,071
11,356,048
5,136,282
99,308,937
HCl
3,847
11,835
86,787
130,211
165,692
35,964
44,940
28,165
12,963
6,120
526,524
HF
215
2,208
13,285
48,740
27,076
10,851
5,768
3,765
1,676
1,850
115,434
NH3
2,470
14,042
40,660
135,784
205,228
133,234
176,547
55,581
44,639
30,479
838,664
TSP
657,426
1,204,930
2,573,135
5,088,856
5,286,234
9,727,381
7,049,162
5,204,444
3,297,549
2,528,253
42,617,370
Ca
312
1,404
10,367
13,766
38,742
13,762
22,074
8,339
3,359
1,684
113,808
M9
183
1,168
4,162
4,664
10,528
3,265
4,103
2,758
800
396
32,025
Na
169
559
1,713
2,049
4,869
696
1,124
1,362
181
253
12,975
K
80
315
1,991
1,306
7,451
751
429
2,220
304
627
15,474
VOC
1,185.538
1,857,619
2,210,510
4,075,244
4,414,825
3,537,629
1,285,770
1,005,242
2,564,528
1,027,643
23,164,547
THC
1,274,058
2,016,830
2,360,328
4,316,670
4,805,098
3,847,014
1,409,712
1,073,957
2,785,895
1,087,898
24,977,459
-------
TABLE 2-7b. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.2 - ANNUAL U.S. POINT
AND AREA SOURCE HYDROCARBON SPECIES EMISSIONS BY EPA REGION
VD
EPA REGION | Methane
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
Cont i g .
1 | 4,488,261
2 | 8,243,208
3 | 7,164,608
4 | 11,923,392
5 | 19,943,921
6
7
8
9
10
15,760,210
6.391,697
3,569,567
11,455.675
3,053,606
U.S. | 91,994,146
Ethane
327,245
491,826
797,476
1,102,242
1,348,978
1,070,750
395,581
224,119
708,892
231,153
6,698,261
Propane
134,969
324,307
453,331
555,938
501.301
1,008,229
202,425
193,733
517,552
187,933
4,079,718
Butane
854,466
1,414,954
1,528,977
2,615,654
2,778,259
2,561,530
806,464
715,431
2,085,014
611,297
15,972,045
i nujbANU n
I so- Butane
128,371
268,306
341,262
565,032
506,159
591,888
149,087
162,461
421,084
167,503
3,301,153
JLtS/TtAK
Pentane
123,580
294,022
261,384
428,845
485,791
858,782
154,481
153,049
400,152
134,208
3,294,293
I so- Pent Alkanes
30,523 6,570,576
37,972 11,110,085
53,953 12,535,958
60,880 24,080,968
81,174 26,050,896
17,009 19,898,278
15,734 7,408,045
8,838 5,623,277
18,456 15,441,577
15,835 5,727,904
340,374 134,447,565
Ethylene
1,428,731
2,414,630
3,187,076
7,256,567
6,487,520
7,984,392
2,344,611
2,804,459
4,787,257
2,916,488
41,611,730
Propylene
674,720
1,116,702
1,346,102
2,580,343
2,766,134
3,111,527
890,088
620,664
1,792,586
558,798
15,457,664
Iso-Buten Alkenes
2,332 1,
4,020 1,
9,897 2,
18,138 5,
21,432 4,
15,376 4,
7,961 1,
9,109 1,
10,240 3,
4,737 1,
103,241 28,
258,505
988,577
445,803
180,087
770,952
616,501
492,723
789,389
243,512
936,466
722,513
EPA REGION | Benzene
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
Contig.
1
2
3
4
5
6
7
8
9
10
U.S.
227,905
433,089
477,301
895,017
949,131
1,154,477
311,050
195,570
684,105
165,126
5,492,770
Toluene
931,231
1,337,002
1,673,599
2,960,603
3,295,684
2,223,543
1,064,588
616,120
1,833,406
556,652
16,492,428
Xylene
1,056,215
1,352,810
1,871,433
2,439,933
3,082,877
1,233,095
789,555
393,871
987,454
555,232
13,762,475
Eth Benz Aromatics Formaldeh Acetatdeh Aldeh
231,621
301,227
411,867
501,777
687,808
186,129
137,583
82,388
206,728
123,692
2,870,820
162,388
277,135
356,953
679,826
723,409
798,511
244,343
179,678
449,368
139,926
4,011,537
1,411,102
1,837,451
1,746,176
2,868,961
3,014,136
3,481,031
923,051
865,120
2,422,941
629,623
19,199,592
49,580 28,945
88,371 43,927
210,780 59,670
392,474 199,568
452,399 88,477
370,831 158,497
174,703 37,233
190,449 38,435
218,516 132,590
99,842 28,951
2,247,947 816,293
Acetone
507,699
587,929
623,232
1,336,863
1,528,633
1,054,279
399,882
126,026
951,808
137,627
7,253,977
Ketones
261,771
333,884
411,091
881,286
1,080,721
566,651
323,485
75,275
353,087
89,578
4,376,829
Org. Acid
121,765
164,995
198,794
280,819
392,563
153,211
84,856
23,812
120,563
53,259
1,594,637
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
-------
TABLE 2-8a. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.2 - ANNUAL U.S.
AND AREA SOURCE EMISSIONS BY STATE
POINT
State |
Alabama
Ari zona
Call f orni a
Cormec t i cut
Del aware
!s '. °
Geor ia
Idaho
III inois
lana
.
.
Maine
Maryland
Massachusetts
M i ch i gan
Minnesota
M i ssouri
Montana
Nebraska
Nevada
New Hampshire
New Jersey
New Mexico
New York
North Carolina
North Dakota
Ohio
Ok I ahoma
Pennsyl vani a
Rhode Island
South Carolina
South Dakota
Tennessee
Utah
Vermont
Virginia
Washington
West Virginia
Ui scons in
Wyoming
Contig. U.S.
S02
857,5*9
844,078
87.127
519,799
140,138
63,665
124,669
15,325
1,102,994
900,080
56,210
1,464,520
1,970,870
334,278
228,074
1,150,036
401,333
133,369
303,471
358,065
841,399
238,705
303,846
1,333,218
169,224
78,117
148,157
108,484
309,856
262,555
870,307
655,591
115,391
2,681,314
104,168
55,987
1,899,006
14,168
344,968
40,863
1,158,153
1,324,373
116,615
8,185
370,780
317,791
1,145,522
670,610
211,134
26,954,136
S04
32,991
30,871
10,478
35,917
9,347
8,110
4,645
1,121
30,793
30,684
8,676
42,270
38,111
11,010
7,409
23,108
24,581
11,223
10,727
14,498
32,609
14,535
11,281
22,746
7,583
4,078
6,667
4,867
20,690
9,202
43,230
31,046
1 1 , 574
51,554
9,558
18,601
60,532
1,491
17,550
3,798
28,905
59,869
8,886
1,764
21,579
19,758
27.902
23,795
13,388
975,608
NO
457,653
245,625
194,532
1,268,139
284.405
128,656
58,416
23,194
663,745
553,085
82.313
909,708
741,610
284,792
479,624
519,674
664,196
62,433
242,626
251.390
668,942
340,540
274,714
515,805
127,844
160,005
90,658
55,291
387,707
237,643
688,092
499,064
128,008
1,145,357
422,056
207.286
976,345
33.295
259,758
73,063
498,219
3,122,306
145,205
21,631
355,772
270,908
440,190
380,932
234,634
20,877,086
H02
29.603
18,269
16,611
114,625
20.372
11,094
3,850
2,158
48,464
37,565
9,561
63,279
45,233
20,962
33,690
31,680
44,770
4,635
18,477
19,380
46,435
26,090
19,797
33,992
12,455
13,034
6,260
3,666
29,802
16,473
48,752
33,611
8,083
72,251
31,010
19,481
65,211
2,958
18,334
6,293
33,117
207,728
10,552
2,149
27,662
23,738
20,824
26,842
14,273
1,475,151
Pb
681
366
264
2,643
756
381
71
39
1,087
697
548
2.635
1,101
427
250
519
554
124
456
666
1,148
469
297
849
310
199
107
100
706
174
1,273
727
72
2,160
412
334
1,918
82
459
70
732
2,169
191
62
646
505
618
592
86
31,732
1
CO
1,811,119
1,310,433
1,045,560
9,524,250
2,302.185
1,192,328
242,885
338.780
4,071,755
2.335,826
1,280,507
4,246,797
2,374,627
1,105,666
1,072,560
1,594,516
2,541,546
506,637
1,459,780
2,133,002
3,613,069
1,928,665
991,881
2,206.090
1,422,156
609,510
521,365
352,582
2,294,053
932,466
4,758,845
2,289,334
282,219
4,697,200
1,854.007
1,454,001
4,377,701
316,586
1,207,907
509,495
1,951,470
9,063,470
990,051
202,077
2,322,403
2.401,774
784.971
1,892,865
589,965
99,308,937
UNS/ItAK-
HCl
19,542
8,937
1,786
472
9,110
491
1,152
655
8,834
20,453
329
34,318
33,494
11,505
6,614
22,635
857
40
6,559
2,241
22,871
8,820
2,599
22,184
2,003
4,637
3.554
1,036
2,566
8,299
9,269
23,667
119
50,783
5,765
729
42,015
27
9,045
235
23,436
19,257
3.588
12
7.328
5,062
29,078
15.406
13,110
526,524
HF
3,539
1,087
1,445
145
1,186
0
184
23
29,228
2,503
242
7,937
4,607
1,706
799
3.841
1,761
5
1,307
86
3,150
1,120
314
2,681
243
582
444
124
328
977
1,880
3,310
60
7,934
768
92
5,525
0
1,648
38
4,357
5,900
511
0
1,385
1,516
4,861
2,328
1,727
115,434
NH3
11,964
11,921
25,418
32,013
24,987
1,946
2,051
59
28,793
35,359
8,133
68,633
29,361
80,410
34,189
8,185
26,314
417
2,992
104
10,433
48,624
7,809
17,264
3.890
44,683
705
1
80
4,523
13,961
21,118
6,642
16,124
15,266
4,249
24,309
0
4,440
12,941
18,117
61,713
1,961
3
10,913
18,097
335
32,054
5,159
838,664
TSP
439,271
841,489
874.245
1,536.414
1.134,995
120,226
49,382
15,099
919,841
882,031
330,728
932,702
496,649
1,237.845
1,852,371
452,395
559,071
127,174
227,611
210.504
880,263
1,199,026
587.204
2,877,954
880,654
1,080,992
919,646
66,310
402,215
1,249,009
802,715
700,462
1,295,268
1,070,910
1,107,180
1,849,960
1,432.694
32,323
451,493
715,996
656,159
5,937,876
690,811
100,889
466,354
347,565
381,995
706,684
486,720
42,617,370
Co
1,604
1,175
307
1,777
2,320
28
167
7
6,269
299
87
5.B92
5,026
3,038
354
1,734
407
72
442
193
9,496
2,218
125
18,356
129
326
407
15
37
923
1,367
2,247
777
7,714
5,458
1,103
6,383
1
486
2,168
1,002
6,686
2,851
3
2,422
494
946
8,395
116
113,808
My
4BU
354
95
375
445
8
176
7
931
263
23
1,»99
2,324
6U5
103
9 A)
50
21
217
142
1,217
624
68
3,220
56
87
91
9
24
409
1,144
943
7U6
3,5i8
648
54
2,006
0
317
4rt
665
2,0'>6
BV2
3
1.090
319
666
927
103
32,025
Na
356
111
23
48
U7
3
84
4
201
201
10
708
1,694
386
42
349
133
75
101
65
482
160
86
6115
23
12
21
23
11
178
5',8
303
371
1,500
34
54
826
1
178
89
375
329
658
1
402
188
296
324
44
12,975
1C
280
57
48
235
119
3
45
2
84
222
37
899
4,565
54
22
183
219
36
79
35
565
79
41
347
26
6
12
3
6
105
310
165
199
1,131
29
310
1,400
1
122
9
209
351
1,844
2
223
280
240
213
25
15,474
VOC
391,455
254,096
223,135
2,216,485
356,946
284,183
77,101
44.081
828.561
508,361
222,050
988,586
562,647
237.157
250,269
441,688
625,559
141,991
363,270
515.765
916,363
469,214
261,800
629,726
236,467
168,618
93,948
103,987
696,758
191,042
1,160,860
614.002
53,274
1,001,059
324,988
340,267
1,043,563
81,042
474,791
95,639
554,586
2,172,905
160,449
58,570
527,715
465,326
154,780
476,956
102,467
23,164,547
me
4rt,591
2M,24J
234.377
2.414.92/
385,554
299,090
81,188
48,400
868,694
530,222
230,398
1,092,842
623,821
258,603
298,662
469,555
669,847
149,051
394,420
568,190
987,380
496,094
278,672
673,526
245,600
178,920
99,725
109,401
749,784
213,500
1,267.046
655,149
58,166
1,092,677
347,352
363,147
1,113,027
86,846
501,073
101,160
587.715
2,381,939
172,386
61,481
561,508
494,352
161,785
512.284
111,091
24,977,459
-------
TABLE 2-8b. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.2 - ANNUAL U.S. POINT
AND AREA SOURCE HYDROCARBON SPECIES EMISSIONS BY STATE
| Methane Ethai
Propane
-THOUSAND HOLES/YEAR---
I so-Butane Pentane Iso-Penta Alkanes
EthyLene Propylene Iso-Buten Alkcnes
Alabama
Arizona
Arkansas
Cal ifornia
Colorado
Connecticut
Delaware
Di:t. of Co I urn
Florida
Georgia
Idaho
Illinois
Indiana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Hampshire
New Jersey
New Mexico
Hew York
North Carolina
North Dakota
Ohio
Oklahoma
Oregon
Pennsylvania
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Utah
Vermont
Virginia
Washington
west Virginia
Wisconsin
Wyoming
1,573,771
896,985
558,234
10,260,471
1,485,865
732,077
205,177
204,402
1,996,490
1,085,897
430,560
5,380,945
3,147,863
1,139,796
2,474,816
1,374,175
2,084,408
309,467
1,393,384
2,766,519
3,599,190
1,332,039
875,921
2,230,248
468,310
546,837
298,220
253,471
2,757,208
1,124,795
5,486,000
2,017,901
260,510
4,705,255
1,043,501
1,146,557
3,390,799
297,983
1,350,544
288,618
1,648,692
10,949,271
622,059
128,745
1,643,629
1,476,488
327,217
1,778,628
444,205
209,627
53,822
52,601
633,765
93,589
72,370
17,314
23,401
190,339
106,257
28,034
325,420
193,805
54,180
155,411
124,553
245,672
51,938
213,749
130,616
262,855
121,895
53,722
157,675
32,253
28,316
21,304
31,403
161,291
88,358
330,535
190,226
12,471
305,838
131,690
92,788
332,268
19,886
86,039
16,303
141,478
552,430
39,437
21,031
166,156
110,331
44,587
139,165
30,067
155,998
24,755
25,129
484,114
36,497
25,185
11,797
1,196
64,620
51,751
59,608
129,931
71,539
15,863
105,469
76,867
197,016
26,038
182,598
51,565
94,209
51,657
33,106
71,577
71,890
9,516
8,682
15,062
106,216
54,137
218,091
76,421
7,131
103,317
152,523
57,838
170,193
6,513
37,137
20,223
60,037
579.425
17,872
10,607
64,313
70,487
23,232
50,648
40,121
320,528
150,781
140,577
1,862,844
271,698
181,076
52,016
18,458
603,312
360,837
105,347
666,352
339,975
174,794
189,434
282,557
372,151
70,755
363,460
461,183
549,635
281,453
160,996
341,325
120,748
100,912
71,389
55,770
506,219
142,060
908,735
369,005
41,316
650,221
284,130
198,968
656,095
56,233
216,852
55,791
301,568
1,622.612
128,881
29,449
338,089
306,982
100.858
290,622
96,998
116,617
26,862
30,055
382.842
40,933
29,891
10,594
3,051
111,848
76,178
48,168
127,598
61,311
30,326
42,278
60,201
91,413
13,461
125,305
59,912
103,574
51,668
33,654
59,661
54,709
16,823
11,379
10,431
93,946
23,652
174,360
71,208
7,710
112,347
93,091
49.745
124,571
9,077
40,853
19,018
54,473
353,678
19,625
5,599
57.062
69,590
20,680
49,660
20,467
35,204
14,227
24,437
375,136
29,784
19,613
13,841
385
90,327
62,646
38,322
113,602
55,777
22,480
58,562
61,642
123,265
23,856
50,603
57,754
110,405
64,524
39,125
55,707
47,323
17,732
10,789
8,508
134,033
60,161
159,989
58,440
7,032
91,706
87,690
36,867
128,805
9.398
32,610
17,209
48,850
563.229
20,713
4,452
52,722
59,018
15,028
49,776
30,988
5,329
1,646
3,369
16,040
3,191
7,270
922
105
4,996
6,224
2,387
12,821
11,583
1,305
1,112
7,962
2,452
8,232
5,860
5,858
16,521
10,332
4,703
12,647
2,290
670
770
4,357
10,574
3,063
27,398
14,924
291
18,485
4,775
6,562
29,232
1,284
3,829
693
12,913
3,349
1,387
3,521
12,118
6,886
5,716
11,432
986
2,319,833
1,520,405
1,305,146
13,384,252
2,127,989
1,606,122
381,500
290,630
5,048,220
2,946,840
1,109,709
5,880,990
3,242,282
1,560,840
1,446,173
2,670,051
3,488,418
661,775
2,062,491
2,978,536
5,584,447
2,733,721
1,507,955
3,568,453
1,149,951
832,578
536,920
546,596
4,093,330
1,007,218
7,016,755
3,623,809
318,645
5,867,268
1,757,806
1,886,315
5,860,445
499,415
2,783,383
522,694
3,180,878
12,339.690
961,298
278,131
3,097,842
2,731,880
843,050
2,742,188
542,700
756,285
656,653
503,046
3,927,557
794,754
353,013
100,872
72,146
1,667,630
981,268
971,704
1,480,249
883,593
427,234
480,608
914,457
1,800,977
129,826
489,473
683,158
1,202,002
723,385
450,615
1,179,046
1,017,435
257,722
203,047
98,438
973,665
312,587
1,440,965
956,294
109,770
1,546,811
569,149
873,792
1,477,528
104,316
681,306
349,198
848,711
4,798,633
323,377
59,980
777,212
1,070,991
269,844
651,480
209,926
257,270
181,695
177,029
1,541,610
263,880
170,873
46,113
82,772
660,287
325,575
73,974
633, 184
341,907
194,612
170,076
270,926
827,238
63,819
226,538
320,678
540,016
315,331
137,992
425,759
70,750
99,641
69,281
43,540
442,308
121,450
674,394
353,734
42,115
627,042
176,897
192,263
570,729
49,250
238,179
53,037
336,381
1.808.913
124,809
26,560
330,061
292,561
89,889
308,655
66,074
2,385
1,725
1,458'
7,648
2,383
558
321
131
3,215
2,947
768
5,548
4,005
1,667
2,744
2.320
2,032
270
1,069
1,101
2,214
1,813
1,196
2,317
1,429
1,233
866
127
1,914
1,856
2,106
2,193
768
6,018
1,373
2.155
4,951
150
1,120
367
2,761
8.457
1,875
126
2.319
1,814
1,106
1,832
2,287
482,416
422,069
321,801
2,684,126
517,496
309,577
80,139
32,585
1,153,037
700,443
629,825
1,087,219
594,963
268,938
298,532
681,889
931,941
152,992
387,379
530,006
922,305
548,556
337,040
765,362
655,280
159,891
137,317
111,563
736,594
221,475
1,251,982
711,531
64,435
1,110,201
413,355
578,528
1,134,168
85,884
455,019
222,061
658,712
2,727,929
209,609
68,482
598,216
728.113
213,316
507,707
120,507
Contig. U.S. | 91,994,146 6,698,261 4,079,718 15,972,045 3.301,153 3,294,293 340,374 134,447,565 41,611,730 15,457,664 103,241 28.722,513
41
-------
TABLE 2-8b (continued)
State Benzene
Alabama
Arizona
Arkansas
California
Colorado
Connecticut
Delaware
Dist. of Colum.
Florida
Georgia
Idaho
I llinois
Indiana
Iowa
Kansas
Kentucky
Louisiana
Haine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Kampsh i re
Neu Jersey
New Mexico
New York
North Carolina
North Dakota
Ohio
Oklahoma
Oregon
Pennsylvania
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Utah
Vermont
Virginia
Washington
West Virginia
Wisconsin
Wyoming
89,501
59,304
52,999
601,633
86,940
57,234
17,754
11.251
229,249
109,761
20,278
204,777
133,299
58,579
61,218
101,038
276,075
20,448
83,079
108,988
194,116
96,152
44,746
159,348
21,505
31,904
22,968
14,444
183,820
45,818
249,269
114,625
11,712
229,760
65,700
55,358
225,515
18,262
84,966
13,649
121,130
713,885
39,639
8,529
113,069
89,491
26,632
91,027
22,126
Contig. U.S. 5,492,770
Toluene
243,603
174,565
151,319
1,584,475
286,203
281,066
104,644
38,583
617,922
423,006
70,819
772,740
432,474
176,389
174,385
262,336
341,397
96,607
277,321
371,886
643,102
330,655
172,776
447,560
68,376
266,253
74,367
77,267
495,186
149,511
841,816
413,488
35,477
736,290
205,473
196,172
775,370
64,222
463,241
43,718
364,231
1,375,843
121,038
40,183
375,119
289,661
102,562
380,425
61,308
16,492,428
Xylene
205,961
90,847
127,830
853,308
158,408
266,244
57,451
15,058
312,838
280,901
80,110
566,170
426,143
78,445
88,969
278,477
172,142
245,155
230,376
253,931
634,751
370,252
179,149
516,632
76,475
105,508
43,300
136,578
428,671
143,272
924,138
505,266
17,738
681,147
195,591
217,570
976,773
52,729
237,428
30,857
439,913
594,260
67,823
101,578
418,972
257,552
172,803
404,415
42,571
13,762,475
Eth Benz
45,062
18,922
27,638
179,897
32,321
55,178
8,471
1,978
60,615
55,337
17,959
119.973
91,273
16,790
14,440
61,032
26,884
54,220
48,135
53,991
157,943
77,633
36,189
97,448
17,169
8,906
7,910
32,243
88,890
24,461
212,338
111,876
3,598
153,976
38,620
49,540
215,513
12,022
34,329
6,305
97,337
68,527
14,360
23,967
97,394
56,192
40,376
87,009
8,635
2,870,820
THOUSAND MOLES/TEAR
Aromatics Formaldeh Acetaldeh
67,071
49,833
43,493
375,576
66,789
34,433
11,509
16,965
177,855
87,188
19,006
179,184
90,543
42,367
68,225
73,033
158,281
25,794
58,151
72,912
132,620
86,113
44,256
104,642
21,816
29,109
23,959
10,227
136,296
69,805
140,839
90,602
13,433
157,209
64,190
47,373
160,949
13,110
55,479
13,670
84,342
462,742
36,190
5,913
86,086
73,547
23,292
77,741
27,780
4,011,537
249,170
190,691
159,273
2,156,076
314,604
215,616
94,179
25,185
687,059
346,609
76,609
654,043
402,404
194,161
217,084
365,889
560,405
77,004
309,082
961,810
571,711
330,437
267,383
386,118
152,828
125,688
76,174
65,899
781,319
145,756
1,056,132
376,800
80,657
753,465
312,669
194,580
806,177
57,583
228,471
49,333
347,580
2,302,927
147,018
33,191
397,547
358,434
114,005
302,076
120,680
19,199,592
50,371
36,076
31,923
164,316
49,907
11,899
7,169
2,737
68,558
61,687
16,064
117,253
84,240
34,862
57,995
52,507
64,275
5,730
22,435
23,316
46,636
38,445
24,991
56,082
29,867
25,764
18,123
2,705
43,853
38,933
44,518
46,766
16,040
127,213
29,221
45,412
105,124
3,270
26,512
7,671
61,082
206,478
39,190
2,662
50,108
38,367
23,208
38,612
47,775
2,247,947
Aldeh
21,887
21,823
8,380
98,469
19,947
5,370
2,186
6,187
80,150
24,059
4,698
28,759
8,726
4.958
7,101
12,834
29,712
3,557
11,559
14,552
15,765
9,118
11,733
20,155
3,776
5,019
12,298
2,241
13,557
9,236
30.J70
25,189
4,299
18,187
12,408
7,551
23,703
1,962
11,849
3,084
11,866
98,762
5,677
1,263
12,626
16,703
3,408
7,921
1,653
816,293
Acetone
72,265
62,885
28,718
868,194
64,785
105,038
41,253
4,636
291,242
136,169
12,527
324,306
227,464
45,902
50,294
91,699
160.493
26,388
87,166
305,718
309,737
120,696
74,158
188,836
12,484
114,850
20.730
29,880
290,770
27,194
297,159
179,863
7,096
415,042
59,881
53,671
308,948
26,925
269,015
7,640
222,452
777,994
27,658
13,751
165,600
71,429
15,629
131,387
6,362
7,253,977
Ketones Org Acid
45,057
23,869
28,515
321,086
39,890
62,707
21,433
4,675
102,741
82,615
8,714
221,031
160,694
30,748
29,807
55,738
86,379
21,949
70,755
121,552
264,206
86,368
47,226
176,818
7,597
86,111
8,132
29,900
114,213
11,532
219,671
150,545
3,995
224,326
31,171
35,018
205,283
16,629
283,609
4,614
113,755
409,054
14,695
9,035
96,536
45,846
12,410
124,095
4,484
4,376,829
19,763
8,026
13,611
110,828
14,501
19,773
3,504
4,195
39,105
36,945
3,994
90,195
29,901
11,986
17,188
34,538
30,115
17,005
34,690
66,391
82,420
26,848
9,718
49,833
2,136
5,849
1,709
7,013
62,114
2,586
102,881
40,532
1,224
80,248
10,160
25,949
104,205
7,575
55,381
1,484
44,837
96,738
3,831
4,008
47,743
23,316
4,458
82,950
636
1,594,637
for conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
42
-------
TABLE 2-9a. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.2 - ANNUAL CANADIAN POINT
AND AREA SOURCE EMISSIONS BY PROVINCE
Province | S02
Alberta
660,788
British Colutbia| 170.640
Manitoba
New Brunswick
Newfoundland
Nova Scotia
Ontario
Prince Edward
Quebec
Saskatchewan
Canada
533,199
223,053
65,635
212,343
1,954,125
4,973
1,210,291
60,125
5,095,172
S04
7,677
13,903
13,790
14,963
4,604
11,094
45,947
343
50,699
4,250
167,270
NO
447,652
197,116
91,581
55,120
33,220
78,375
517,732
5,624
297,214
155,082
1,878,716
N02
37,913
20,060
10,811
3,640
2,710
5,101
46,017
506
24,785
19,135
170,677
Pb
0
0
0
0
0
0
0
0
0
0
NR
CO
3,023,686
2,153,713
1,603,510
347,965
197,323
393,785
4,424,186
57,947
2,409,711
3,373,897
17,985,723
TONS/YEAR
HCl HF NK3
0
0
0
0
0
0
0
0
0
0
NR
0
0
0
0
0
0
0
0
0
0
NR
83,323
7,012
21,011
1,024
123
1,646
46,260
832
16,564
31,879
209,674
TSP
8,828,141
1,967,089
3,142,219
415,749
280,665
763,019
6,604,382
41 ,629
2,484,937
6,980,762
31,508,592
Ca
709
1,354
602
743
508
483
6,461
0
3,883
1,936
16,680
Mg
249
159
153
233
178
250
1,265
0
761
1,623
4,870
Na
152
266
55
232
1
238
838
0
687
821
3,289
K
66
19
28
53
0
389
1,350
0
282
412
2,599
VOC
685,711
283,067
233,681
51,010
28,948
73,664
733,251
6,501
390,108
505,957
2,991,898
THC
898,962
528,424
325,091
114,009
78,892
149,945
1,482,757
17,202
946,493
593,482
5,135,257
NR = NOT REPORTED
TABLE 2-9b. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.2 - ANNUAL CANADIAN POINT
AND AREA SOURCE HYDROCARBON SPECIES EMISSIONS BY PROVINCE
Province | Methane
Iberta
rit.Cot.
anitoba
ew Brun.
ewfound.
ova Scot
Ontario
Prince Ed
Ouebec
Saslcatch.
11,767,688
13,744,136
5,143,30o
3,540,911
2,816.537
4,270,917
42,288,130
604,107
31.357,047
4.856,581
Canada | 120, 389,161
Ethane
244,099
100,764
25,654
19,213
10,116
32,081
141,549
1.756
122,510
61,512
759,253
Propane
353,461
78,290
77,185
24,317
10,341
35,417
165,843
669
143,555
206,981
1,096,057
Butane Iso*Butane
497,510
224,948
117,894
68,831
37,951
86,577
592,743
6,875
473,749
232,071
2,339,149
129,735
44,684
57,563
13,490
6,734
13,651
155,139
1,302
91,040
130,606
643,943
Pentane ISO-Pen Alkanes
188,312 11,632
57,496 8,916
53,469 100
24,315 266
10,099 48
26,381 2,329
181,941 439
1,382 28
146,480 248
124,927 3,789
814,803 27,796
3,153,143
1,393,282
1,145,443
286,046
167,312
362,041
4,035.725
39,333
2,221,058
2,300,349
15,103,733
Ethyl ene
2,611,986
495,673
1,139,139
65,434
42,847
81,958
1,849,973
10,093
536,115
2,601,774
9,434,992
Propylene Iso-Buten
413,931
170,165
82,670
30,142
20,811
45,396
731,441
5.517
398,776
103,137
2,001,986
3,606
2,105
1,122
305
273
440
3,528
46
2,126
1,345
14,897
Alkenes Benzene
1,700,819 168,267
386,827 49,748
716,521 21,680
49,121 9,968
30,369 5,649
75,160 12,438
1,275,151 165,690
7,379 1,449
396,238 92,840
1,680,370 19,920
6^317,955 547,649
Toluene
207,056
159,900
55,092
27,597
18.777
44,940
352.940
5,074
223,733
77,070
1,172,180
Xylene Eth Benz Aromatice
357,078
282,269
19,652
16,514
7,577
72,679
154,512
2,302
96,794
120.057
1,129,434
79,550
63,336
1,637
3,458
1.672
16,943
25.018
504
17,256
26,729
238,103
98,130
50,425
23,338
9,310
6,262
10,030
109,588
1,414
62,645
27.304
398,445
Fonnaldeh Acetaldefi
455,622
290,111
61,738
84,721
58,197
109,845
808,285
8,326
668,593
80,939
2,626,378
88,824
44,880
24,135
6,381
5,697
9.207
76,953
967
44,986
28,114
330,143
Aided
23,656
20,464
4,507
4,249
2.107
1,578
28,863
300
16,021
4,067
105,814
Acetone
54,432
56,317
8,537
8,719
4,911
7,533
157,779
720
119,173
6,649
424,770
Ketones Org Acid
22,228
35.850
9,589
5,738
4.344
7.445
135,767
1,034
78,463
9.256
309,71*
8,027
3,108
1,294
683
543
831
10,331
117
7.211
955
33,100
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
-------
TABLE 2-10. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.2 -
SEASONAL VARIATION IN EMISSIONS OF S02,
NOX and VOC
Winter
Spring
Summer
Fall
Emissions percent.
S02 NOX
26.15 24.80
24.68 25.02
24.65 25.47
24.52 24.71
iges
VOC
24.62
26.62
24.81
23.93
100.00
100.00
100.00
44
-------
season, showing a variation of less than one percentage point. SC>2
emissions show an intermediate degree of variation, reaching a maximum in
winter but remaining fairly constant throughout the remainder of the year.
Figure 2-23 illustrates the hourly variation of SC>2, NOX, and VOC
emissions for one possible scenario, a typical summer weekday. Hours are
expressed in Greenwich Mean Time; as an example, hour 17 would correspond to
1:00 p.m. Eastern Daylight Time. Note that diurnal SC>2 emissions exhibit
relatively little variation, indicative of a more uniform operating pattern,
while NOX and VOC emissions, highly dependent on highway traffic, vary more
widely over a 24-hour period.
The spatial resolution capabilities of the 1980 NAPAP Version 5.2
inventory are shown in Figures 2-24 to 2-32, which illustrate emissions
apportioned into grid cells measuring 1/6 degree latitude by 1/4 degree
longitude (approximately 20 x 20 km) for U.S. point and area source emissions
of S02, NOX, and VOC. Figures 2-33 to 2-37 provide gridded emissions at
the 80 x 80 km level for clarity of presentation, and show hourly emissions
distribution for a typical summer weekday at 1700 GMT.
45
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1-
2345
11 12 13 14 15
HOUR (GMT)
22 23 24
POLLUTANT -A--A--A NOX
S02
o o e voc
Figure 2-23. 1980 NAPAP Emissions Inventory Version 5.2 - hourly emissions patterns
for S02, NOX, and VOC for a typical summer weekday.
-------
THOUSAND TONS/YR
Figure 2-24. 1980 NAPAP Emissions Inventory Version 5.2 - Annual
emissions, U.S. point sources.
SO,
-------
IIIOUSANL) 10NS/YR
/Q -
25 -
o -:
.P-
CD
Figure 2-25. 1980 NAPAP Emissions Inventory Version 5.2 - Annual SO
emissions, U.S. area sources. 2
-------
THOUSAND TONS/YR
"Sure 2-26.
«.,..,.„
U.S. point and
-------
THOUSAND TONS/YR
150 -.
100 -
50 -
0 -
Figure 2-27. 1980 NAPAP Emissions Inventory Version 5.2 - Annual NOX
emissions, U.S. point sources.
-------
THOUSAND TONS/YR
150 -
100 -
50 -
0 -
Figure 2-28. 1980 NAPAP Emissions Inventory Version 5.2 - Annual NO
emissions, U.S. area sources.
-------
"I HOUSAMD TONS/YR
200
150 -
100 -
50 -
0 -
Figure 2-29. 1980 NAPA.P Emissions Inventory Version 5.2 - Annual NO
emissions, U.S. point and area sources.
-------
THOUSAND TONS/YR
100 -
75 -
50 -
25 -
0 -
U)
Figure 2-30. 1980 NAPAP r
emissions' J
=>. u.
e-ion 5 2 A ,
. point sources. ~ Ann"al
VOC
-------
THOUSAND TONS/YR
Figure 2-31. 1980 NAPAP Emissions Inventory Version 5.2 - Annual VOC
emission, U.S. area sources.
-------
THOUSAND TONS/YR
Figure 2-32. 1980 NAPAP Emissions Inventory Version 5.2 - Annual VOC
emissions,'U.S. point and area sources.
-------
Ui
-------
-------
_ VOC emissions
, 35 1980
2-35. & typx
-------
TONS/HR
0-5
5-10
Figure 2-36.
1980 NAPAP Emissions Inventory Version 5.2 - TSP emissions
for a typical summer weekday at 1700 GMT.
-------
TONS/HR
-------
SECTION 3
CREATION AND QUALITY ASSURANCE OF THE
1980 NAPAP EMISSIONS INVENTORY
The primary goal of the 1980 NAPAP Emissions Inventory development effort
is to provide an emissions data base adequate for acid deposition research and
modeling. The basic requirements of the emissions inventory include a
comprehensive data base of anthropogenic emissions data representing a common
year, 1980; coverage of all pollutants believed to be important in acid
deposition processes; detailed information on all point and area sources;
accurate accounting of all emissions sources; and a high level of quality
assurance.
Several versions of the 1980 NAPAP Emissions Inventory have been
developed with each new version representing enhancements over the previous
version. This section discusses the evolution of the 1980 NAPAP Emissions
Inventory in both its annual and fully resolved forms, highlighting
improvements made from version to version and describing the quality assurance
activities that were undertaken.
NAPAP EMISSIONS INVENTORY DEVELOPMENT APPROACH
Several constraints to inventory development existed at the outset of the
NAPAP program. Limited funding was available for the initial year of the
program and future resource commitments were uncertain. Inventory data were
needed for preliminary analyses in a relatively short time frame, yet the
final set of data needs had not been fully defined. As a result, the approach
adopted for the inventory was to start with the best data base available at
the time and to supplement and improve the initial inventory as time and
resources permitted.
The inventory judged to be best suited for the 1980 NAPAP Annual
Emissions Inventory was the 1980 "snapshot" inventory of the National
Emissions Data System (NEDS), maintained by EPA's National Air Data Branch
(NADB). NEDS, selected as the logical starting point for the NAPAP
development effort, includes: comprehensive coverage of the contiguous United
States, data at the emission point level for point sources, county-level area
source data for each area source category, and annual emissions estimates for
five criteria pollutants (TSP, CO, S02, NOX, and VOC).
Although NEDS represented the most logical starting point for development
of the 1980 NAPAP Annual Emissions Inventory, NEDS has several data processing
limitations which precluded its use in NAPAP; its primary limitation is its
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inability to handle more than the five criteria pollutants. Although at the
outset of the NAPAP effort all of the requirements of the emissions inventory
were not fully defined, it was known that data for additional pollutants would
be desired. It was also known that modeling applications of the data would
require further temporal, spatial, and species resolution. It was determined
that the Emissions Inventory System (EIS) represented the most logical data
handling system for the intended application. EIS has the capability to carry
the number of pollutants desired, does not present the data processing
limitations of NEDS, and has been used in similar programs in the past, such
as the Northeast Corridor Regional Modeling Project (NECRMP) (Sellars, et al.,
1982). EIS is also supported on the National Computing Center's IBM mainframe
and enabled use of the Regional Modeling Data Handling System (RMDHS),
developed for NECRMP, in generating the preliminary version of the NAPAP
Eulerian Modeling Inventory (Version 4.2).
The inventory formulation process began in 1983 with the 1980 NEDS
snapshot file. It was recognized that a number of improvements and additions
were necessary. As previously indicated, only five pollutants were included
in the inventory. Stack data and coordinates were missing or suspect in a
number of cases. The emission factors used to develop emissions estimates did
not reflect the latest supplement of EPA's emission factor publication, AP-42
(U.S. EPA, 1985). The development procedures used by the states to compile
the individual inventories included in the 1980 NEDS snapshot were likely to
be inconsistent, and the degree of quality control employed by the states was
unknown. The inventory covered the contiguous United States, but emissions
inventory data were also needed for Canada. Improved methodologies for
developing emissions estimates for certain area source categories were
available. These improvements were the focus of the 1980 NAPAP inventory
development process. Thus, the remainder of the program was entirely a
quality assurance effort related to improving and supplementing the initial
inventory. The improvements/additions made were prioritized over time, based
on available funding, NAPAP data needs, and inventory quality. This
evolutionary process, culminating in the NAPAP 5.0/5.2 inventory, is
summarized schematically in Figure 3-1.
EVOLUTION AND QUALITY ASSURANCE OF THE 1980 ANNUAL NAPAP EMISSIONS INVENTORY
Version 1.0
The first version of the NAPAP Emissions Inventory was prepared in
mid-1983 and represented a number of enhancements to the NEDS snapshot file.
Using a program developed by EPA's Atmospheric Sciences Research Laboratory
(ASRL), missing or suspect Universal Transverse Mercator (UTM) coordinates
were identified. Sources with missing UTMs, or those falling outside of
county boundaries, were updated to reflect the centroid of the county.
NEDS data from previous or later versions than the 1980 snapshot file
were investigated. It was determined that for 12 states, data from other
versions of NEDS were more representative of calendar year 1980 than those
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1983-1
1984-
Annual Inventories
Resolved Inventories
• NEDS snapshot inventory
converted to EIS format,
creating initial inventory
• Version 1.0 developed
• Version 2.0 developed
• Version 3.0 developed
1985-
• Version 4.0 developed
Version 4.1 developed by com-
pressing data from Version 4.0
Version 4.2 resolved file
containing emissions for a
summer weekday created by
processing Version 4.1 data
1986-
• Version 5.0 developed
Version 5.2 developed by
processing Version 5.0 data,
creating fully resolved
emissions inventory
Version 5.3 created by
processing Version 5.0 data
using carbon bond IV
speciation chemistry
Figure 3-1. Evolution of the 1980 NAPAP Emissions Inventory.
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found in the snapshot file. These data were obtained, converted to EIS format
and substituted as appropriate.
The NAPAP emission factor file was updated to reflect changes through
Supplement 14 of AP-42 (the NEDS data reflected emission factors only through
Supplement 13). Emissions for the five NEDS pollutants were recalculated
using the updated emission factors and the EIS maintenance routine.
The significance of SO.,, NO,,, and other pollutant emissions from the
A A
electric utility industry made it necessary to have consistent, quality data
for utilities for 1980. Data from the Pechan Unit Inventory, compiled using
1980 utility data from the DOE, were obtained and used to update the initial
NAPAP inventory. Individual units were matched with boilers in the NAPAP
inventory to the extent possible. Updates were made for source classification
code, fuel quantity and quality, and control type and efficiency. Emissions
were calculated using these updated data and the latest EPA emission factors
previously discussed. Monthly fuel use data from Federal Power Commission
(FPC) Form 4 were used to determine seasonal throughput percentages.
One of the most significant uses of Version 1.0 was to support Lagrangian
modeling being conducted by ASRL, To support this application, seasonal
percentage factors were developed for each area source category.
Version 2.0
Version 2.0 of the NAPAP Emissions Inventory, released in late 1983, was
utilized by ASRL to support Lagrangian modeling and represented a number of
enhancements of Version 1.0.
SOX emissions from copper smelters contained in the Work Group 3B
inventory (1982) were believed to be more reliable than those in the NAPAP
inventory since the WG3B effort involved procurement of 1980 data directly
from the 15 significant smelters in the United States. Data on emissions were
updated to agree with the WG3B data; updates were also made to process rates
and control efficiencies when possible.
Because the Northeast Corridor Regional Modeling Project (NECRMP)
(Sellars, et al., 1982) entailed collection of state supplied data for 1980
with a high level of quality assurance with regard to VOC and NOX, these
data were considered to be of generally higher quality than those contained in
NAPAP. The NECRMP data were reviewed for potential incorporation into NAPAP.
Since reliable utility data had previously been substituted, it was decided to
limit the review to nonutility point sources. Major VOC and NOX emitters
were compared and NECRMP data were substituted for all but 30 plants. The 30
plants not changed either reflected more current data or data judged to be
more reliable. Following substitution, emissions were recalculated using the
NAPAP (AP-42 Supplement 14) emission factors and the EIS maintenance routine.
In reviewing the electric utility updates made for Version 1.0 of the
NAPAP inventory, it was discovered that some transactions had not been run and
that errors were made in a few cases. Transactions to correct these problems
were generated and used to update the NAPAP file.
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Version 3.0
A number of additional refinements were made in Version 3.0, released in
mid-1984 and extensively documented in a report published by EPA in December
1984 (Toothman, 1984).
Fuel combustion in stationary sources is responsible for over 80 percent
of total SOX emissions and over half of the NOX emissions. Because of the
significance of fuel combustion, fuel data by type, consuming sector, and
state were summarized from Version 2.0 and compared to data taken from the
1980 State Energy Data Report published by the DOE. For fuel types and
consuming sectors that exhibited large differences (factor of two or more),
reports were generated from the point source inventory by state and reviewed
in an attempt to identify obvious errors in units (gallons versus thousand
gallons, thousand barrels versus thousand gallons, etc.) or inconsistencies in
fuel type. Update transactions for fuel quantity and source classification
code (identifies fuel type) were generated in these cases, and the point
source inventory was updated.
Additional work was performed to more completely match combustion units in
the Pechan Unit Inventory with boilers in the NAPAP inventory. As a result,
updates for several plants and/or boilers not previously matched were
generated and made. During this process, some problems with previous updates
were discovered and corrected. As before, the updates included source
classification code (SCO, fuel quantity and quality, and control type and
efficiency.
In addition to the Unit Inventory, Pechan and Associates also compiled a
plant-level inventory based on 1980 DOE data. Plant-level emissions of sulfur
oxides were calculated by Pechan using a different procedure than applying EPA
emission factors. In order to be consistent with data in the Pechan
inventories, plant-level sulfur oxides emissions in Version 2.0 were updated
to match those in the Pechan plant inventory. In general, point-level
emissions in Version 2.0 were normalized as necessary to obtain the
appropriate plant-level emissions.
A review of the area source emissions data revealed that 15 counties
which fall within more than one Air Quality Control Region (AQCR) were not
properly converted from NEDS to EIS. The county data were re-combined such
that only one AQCR was reported and the area source data were replaced in
Version 3.0.
Version 4.0
Version 4.0 was released in late 1984 and reflected a number of
enhancements to Version 3.0, primarily related to generation of an Eulerian
modeling emissions inventory. The preliminary Eulerian modeling emissions
inventory reflected further temporal, spatial, and species allocation and was
numbered Version 4.2; it is discussed in more detail later in this section.
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To support testing of the Eulerian Regional Acid Deposition Model (RADM),
two additional pollutants, ammonia and primary sulfate, were required.
Uncontrolled emission factors were developed for these two pollutants under
NAPAP direction; this work is detailed in Section 4. Information from the
emission factor reports was used to develop removal efficiencies for a number
of control devices. Assumed control efficiencies for ammonia and sulfate are
provided in Appendix B.
The sulfate emission factors and assumed control efficiencies were coded
along with operating data in the inventory to update the NAPAP EIS master file
and generate sulfate emissions estimates. For cases in which more than one
control device existed, credit was given only for the most effective device.
Plants with the greatest sulfate emissions were reviewed to identify any
problems with data used in the calculations and adjustments were made as
necessary. A similar process was undertaken for ammonia, with one exception:
for sulfate, point source emission factors were used for area source
categories where appropriate; point and area sources of ammonia were, however,
not as interchangeable. One significant area source of ammonia is manure
application. State level ammonia estimates for manure application were
allocated to counties on the basis of farm acreage.
The procedure used to add sulfate and ammonia emissions to the inventory
resulted in the addition of emission estimates for other pollutants in
certain cases. Some SCCs had emission factors in the NAPAP emission factor
file for a given pollutant but did not have emission estimates in.the
inventory. The omitted pollutant was added and an emission estimate generated
based on the emission factor in the emission factor file and on the operating
rate and other data in the inventory.
Another enhancement of Version 4.0 entailed a review of UTM coordinates
for sources added as a result of the Version 2.0 and 3.0 efforts. It was
determined that a number of sources added to the NAPAP Emissions Inventory as
a result of these efforts had missing or invalid location coordinates. In
these instances, county centroid latitude and longitude data were added and
UTM coordinates calculated.
It was discovered that the emission factor data supplied by NADB and used
in the NEDS contained roundoff errors, e.g., 24.99 instead of 25.0. NADB
supplied a substitute emission factor file to correct the earlier data used in
NAPAP. An updated NAPAP emission factor file was created and used to revise
the emission estimates.
Version 5.0
Version 5.0 of the NAPAP Emissions Inventory was generated to support
applications of the RADM and to support NAPAP assessment activities. As
Version 5.0 represents the final version of the 1980 Annual Inventory, a
number of additions and refinements were made to improve the quality of the
inventory.
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Canadian Data--
The RADM study area includes Canada, north to 60 degrees latitude.
Environment Canada provided 1980 data for both point and area sources of
particulates, sulfur dioxide, nitrogen oxides, total hydrocarbons, carbon
monoxide, sulfate, ammonia, and four classes of alkaline particulates:
calcium, magnesium, potassium, and sodium. These data were not in EIS format,
and did not contain information on plant name, UTM coordinates, SCC,
ash/sulfur flags, control equipment code/efficiencies, emission estimation
method, annual throughput, seasonal throughput percentages, operating
schedule, points sharing common stacks, boiler capacity, maximum design rate,
and fuel heat content.
The Canadian data were converted into EIS format. This required revising
province, SIC, and some pollutant SAROAD codes to be consistent with the
United States data. Area source categories had to be renumbered, and units
had to be converted to be consistent with EIS. To enable matching of
temporal, spatial, and pollutant species allocation factors (described in
Section 6), SCCs had to be manually assigned based on source descriptions.
Although the area source categories used in the Canadian inventory were
not consistent with those in the United States inventory, they were left
intact. A review of the converted inventory was conducted to ensure agreement
with the original emissions data.
Utility Data—
The importance of the utility sector to the NAPAP emissions inventory was
previously discussed. The utility data used to update earlier versions of the
inventory did not reflect EPA emission factors and procedures for classifying
fuels. In addition, better data concerning the distribution of fuels to
combustion units within plants for 1980 became available from DOE. It was
also desirable to maintain all utility data needed for NAPAP (emissions and
projections) in one file for consistency. For these reasons, NAPAP sponsored
the development of the NAPAP Utility Reference File (Pechan, 1983). Section i>
of this report presents a comprehensive accounting of the development of the
NURF, and details how data in the NURF were used to generate emissions
estimates for the utility sector in Version 5.0 of the NAPAP Emissions
Inventory.
Chloride, Fluoride, and Lead Emissions—
Estimates of emissions of chloride (HCl), fluoride (HF), and lead (Pb)
were derived in a manner similar to ammonia and sulfate in-the Version 4.0
inventory. NAPAP developed emission factors for HCl and HF, and coded Pb
emission factors from AP-42. These factors were added to the NAPAP Emission
Factor File and utilized in conjunction with operating rate data contained in
the NAPAP inventory and EIS software to calculate emissions estimates for
these three pollutants.
The assumed removal efficiencies for HCl and HF were determined from
information in the emission factor report and are presented in Appendix B.
The removal efficiencies for Pb were assumed to be equivalent to those in the
inventory for particulate matter.
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Improvement of VOC Area Source Categories—
The most significant contributors to VOC emissions are area and mobile
sources. In creating the Version 5.0 NAPAP Emissions Inventory, improvements
were made to three significant area source categories: organic solvent
evaporation, residential wood combustion, and highway vehicles.
Previous versions of the NAPAP Emissions Inventory reported a large
composite category for organic solvent evaporation which had to be assigned to
a composite VOC profile in speciating the emissions data for RADM input. A
program was written to obtain emissions data for the 18 individual categories
of solvent use normally aggregated by NEDS to make up the organic solvent use
category. The organic solvent evaporation category was then replaced in
Version 5.0 of the inventory by the following individual categories:
• degreasing
• dry cleaning
• graphic arts
• rubber and plastics manufacture
• architectural surface coating
• auto body repair
• motor vehicle surface coating
• paper coating
• fabricated metals coating
• machinery coating
• furniture coating
• flatwood products coating
• transportation equipment coating
• electrical equipment coating
• ship building surface coating
• miscellaneous industrial surface coating
• miscellaneous industrial solvent use
• miscellaneous nonindustrial solvent use
VOC speciation profiles for many of these categories were developed for
the Northeast Corridor Regional Modeling Project (Sellars, et al., 1982). To
68
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enable use of the more detailed NECRMP speciation data, the NAPAP area source
emissions data for organic solvent evaporation were expanded to reflect the
above subcategories.
Previous versions of the NAPAP Emissions Inventory did not properly
reflect the quantity of wood burned in the residential sector, nor did it
accurately reflect the proportion of wood burned in wood stoves versus
fireplaces in 1980. In addition, earlier versions of the NAPAP Emission
Factor File did not reflect recent test data which indicate VOC emissions from
wood burning are considerably higher than previously thought. State-level
wood consumption estimates were obtained from DOE, adjusted to agree with more
recent regional data for 1980, and allocated to counties OM the basis of wood
burning households from the 1980 Census. Consumption data for each county
were adjusted to reflect the fact that the emission factors for wood
combustion reflect oven-dried equivalent rates, while the fuel use data
reflect undried wood. The revised emission factors for VOC were weighted on
the basis of the nationwide proportion of wood stove versus fireplace wood
combustion to .obtain a single emission factor from which emission estimates
were developed.
Emissions data for highway vehicles in previous versions of the NAPAP
Emissions Inventory were based on the MOBILE2 emissions model. To support
Version 5.0, the MOBILES emissions model was incorporated into the NEDS
system. Revised highway vehicle emission factors for each U.S. county were
generated for hydrocarbons, NOX, and CO and incorporated into the NAPAP
Emission Factor File. Using EIS software, revised emissions estimates for all
highway vehicle categories were calculated. It should be noted that
nonmethane emission factors were generated using MOBILE2 (i.e. VOC), while
MOBILES calculated emission factors are for total hydrocarbons.
Systematic Quality Assurance Checks—
Previous quality assurance (QA) efforts focused on the expansion of the
NAPAP Emissions Inventory to reflect the needs of the RADM or substitution of
certain emissions data with those judged to be of higher quality. The
Version 5.0 data base was subjected to a detailed systematic quality checK.
Specific checks applied to the annual data base are described in the following
paragraphs.
Ash and Sulfur Flags and Percents—Calculation of SC-2 and TSP emissions
for certain SCCs requires knowledge of the sulfur and/or ash content of the
fuel used. If any of these values are missing, emissions .cannot be properly
calculated. All SCCs whose emissions calculations are dependent on ash and/or
sulfur percents were identified. Records in the NAPAP Emissions Inventory
with those SCCs were examined; those records that were missing the needed data
were identified. Similar processes at the same plant were first examined. If
sulfur and/or ash percentages were available on those records, the same values
were substituted for the missing values. When this approach could not be
used, default ash and/or sulfur percentages (see Appendix B) were used. This
procedure was also applied to ash and/or sulfur contents that appeared to be
unreasonably high or low.
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Estimation Methods—In cases where the estimation method is 0 or blank,
NEDS calculates emissions using data in the inventory and the appropriate
emission factor from the emission factor file. EIS does not calculate
emissions in these cases. Therefore, all estimation methods of zero and blank
were identified and changed to 3 so that EIS would calculate emissions in the
same manner as NEDS. Estimation method 6 or 7 indicates that the emission
point has not yet begun to operate or has ceased operations. Many times,
however, these emission points had emissions in the NAPAP inventory. Though
NEDS recognizes that such points should not have emissions and does not report
emissions for them, EIS reports the emissions just as for any other estimation
method. To correct this, all emission points with estimation method 6 or 7
for one or more pollutants were deleted from the inventory.
Incorrect SCCs—A number of emission records appearing in the NAPAP
Emissions Inventory had SCCs that are not considered valid by NADB (e.g.,
00000000, 19999999, 29999999, and 39999999). In cases where an SCC had a zero
operating rate and occurred at an emission point with multiple SCCs, the
incorrect SCC was deleted. In all other cases, data in the inventory were
reviewed, and manual updates were generated where possible to change the
incorrect SCC. In addition, the data identified by Pechan as nonutility but
given a utility SCC were reviewed and manually updated to accurately define
the type of source.
Asterisks in Data Fields—EIS allows an asterisk in the first space of
certain data fields which instructs the system to "blank out" the field when
the data are converted back into NEDS format. Because the NAPAP Emissions
Inventory data are never reconverted into NEDS, the asterisks remained,
creating data processing problems for a number of inventory users. To
eliminate this problem, fields with asterisks were blanked out using the EIS
to NEDS program.
Zero or Blank Emissions Rates—A number of emission sources were detected
that had blank or zero emission rates for certain pollutants, and based on
emissions of other pollutants, were suspected to be incorrect. In instances
in which the estimation method was 3 (EIS calculates automatically), it was
found that a data item crucial to the emissions calculation was missing or
zero. To correct the error, where the missing data item was such that a
default value could be utilized (e.g., sulfur or ash content), emissions were
recalculated with the default value. In many instances, however, the affected
data item involved operating rate information, or the SCC did not have an
emission factor, despite the use of estimation method 3. Nothing could
realistically be done in these instances within the time and budget
constraints of the program, so they were noted but not addressed.
Missing or Anomalous Stack Data—Stack data are important because they
are required by the RADM. The NAPAP Emissions Inventory was screened to
identify sources with missing stack data. Average values based on SCC were
substituted in these instances. For sources with multiple SCCs, the primary
SCC was utilized in selecting default stack data.
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Limit checks were applied to all stack data in the NAPAP Emissions
Inventory, as follows :
• Stack height greater than 900 feet
• Utility boiler stack heights less than 100 feet
• Stack diameter greater than 30 feet
• Stack gas temperatures for scrubber stacks greater than 250 degrees
• Stack gas temperatures less than 250 degrees for nonscrubber stacks
• Stack flow rate greater than temperature (degrees R) x capacity for
fuel combustion sources.
Stacks exceeding the above limits were identified and reviewed.
Suspected problems were resolved based on engineering judgment. In addition
all stacks with exit temperatures less than 77°F were changed to 77. Stack
gas flow rates were also screened. Those found to exceed the product of
capacity and temperature were set to a default flow rate equal to 1/2 the
product of capacity and temperature :
_ (250 SCFM/MMBtu/hr) (Capacity in MMBtu/hr) (stack temperature in °R)
Ambient temperature in °R
250 (capacity) (temperature) ~ n ,„ , . _ ^ , _ . ..
= - - - - - - = 1/2 (capacity) (temperature)
As previously indicated, the utility data in Version 4.0 were completely
replaced with data generated by Pechan. In creating the new utility data,
Pechan renumbered the emission points at a plant. Emission points were
matched to those in Version 4.0 where possible but many of the emission points
were not matched and several new emission points were created. For the
unmatched or new emission points, no stack data were placed in NURF and
therefore none were entered into the NAPAP inventory. These emission points
were treated like other emission points in the inventory in that average
values were substituted.
Operating Rates — Operating rate data were screened for consistency with
maximum hourly operating capacities and operating hours. Sources with
inconsistent operating rate data were identified. In some instances it was
determined that maximum design capacity data were in error; these data were
corrected. However, only a few annual operating rates could be corrected, and
in most cases, it was not possible to determine whether the annual rate or the
maximum rate was in error.
Control Equipment Efficiency — The data were screened to identify emission
points which reported control types, but not efficiencies. In these instances,
default efficiencies were substituted (see Appendix B). If more than one
device was found, the efficiency corresponding to the most efficient device
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was entered. In instances in which the control efficiency was present, but
the control equipment code was missing, no action was taken.
Non-Computer Calculated Emissions—Sources whose emissions are based on
an estimation method other than 3 (e.g., stack test, material balance) were
identified. Emissions were estimated using the NAPAP Emission Factor File and
operating data reported for the source. In cases in which the calculated
emissions differed from the reported emissions by more than a factor of three,
the estimation method was changed to 3 so that the computer calculated
emissions would be substituted.
Two exceptions to the above procedure should be noted. The emissions
estimation method for SOX emissions from copper smelters was changed to 5
(indicating state-supplied data) when the data were updated with Work Group 3B
data, to prevent EIS from changing the estimates automatically. The same
procedure was followed in NECRMP, the source of considerable VOC and NOX
data in NAPAP. The copper smelter data were left unchanged in Version 5.0.
However, since the NECRMP data had been developed prior to the release of
Supplement 14 of AP-42, the following procedure was undertaken. NOX and VOC
emissions were computer-calculated using Supplement 13 emission factors and
compared to the NECRMP values. If the two values matched, emissions were
recalculated to reflect supplement 14, using estimation method 3. Sources
whose emissions did not match the computer calculated values were left
unchanged.
Operating Data—Operating data consist of seasonal throughput and
hours/day, days/week, and weeks/year of operation. These data are needed for
major point sources to obtain the temporal emissions detail required for
Eulerian modeling. Seasonal throughput percentages that did not sum to 100
were identified and reviewed. Additional updates were made manually based on
the type of source and engineering judgement.
Fuel Heat Content—For fuel-burning sources, missing heat values or
values falling outside an appropriate range were replaced with default values
as specified in Appendix B.
Emission Factor Confidence Levels—
The procedure adopted to develop uncertainty estimates for emissions in
the 1980 NAPAP inventory required the compilation of confidence levels for the
factors in the emission factor file. It was decided to assign confidence
levels on the basis of the letter ratings included in AP-42 which are
indicative of the amount and quality of emissions test data used to develop
each factor. The confidence levels were assigned to the letter ratings as
follows: A: + 10%, B: ^ 25%, C: ^50%, D: ^75%, and E: +100%. The
confidence ratings (1 through 5 correspond to A through E) were added to the
point and area source emission factor files in the appropriate fields.
Ratings could not be found in AP-42 for several factors in the emission factor
file. These cases were discussed with NADB personnel and engineering
judgement was used to assign a confidence level. In cases where a zero
emission factor occurred, a confidence rating of 1 was assigned.
72
-------
SCC-Level Emissions—
The program which speciates total hydrocarbons, NOX, and TSP from the
NAPAP inventory into the components required for the Eulerian model is based
upon the SCC. Emissions by SCC were thus needed for the program. The NAPAP
inventory has the capability to calculate and store SCC-level emissions.
Emissions are inserted for the SCC when calculations are based on factors from
the emission factor file. In other cases, however, SCC-level emissions are
not available. A computer program was developed to handle these cases using
the algorithms included in NEDS for reporting SCC-level emissions. When only
one SCC existed at an emission point, the point-level emissions were assigned
to the SCC. The NEDS algorithms could not handle situations where all process
rates or emission factors were zero or blank for the emission point.
Point-level emissions were assigned in such situations equally to each SCC
that occurred at the emission point.
York County—
During the creation of Version 5.0 of the 1980 NAPAP inventory, it was
discovered that York County, Pennsylvania, did not exist in earlier versions
of the area source inventory or in the original NEDS data supplied by NADB.
Area source activity data for York County were obtained from NADB and,
together with the factors in the emission factor file (including MOBILES
factors for highway vehicles), were used to create a separate inventory for
York County in EIS/AS format. The inventory was supplied to Alliance for
developing Eulerian model input and later merged with the area source
inventory for other counties in the U.S.
Correction of Canadian Emissions and Stack Parameters—
Communication with Environment Canada uncovered a problem with reported
ammonia emissions from Canadian sources. A tape was provided with new
emissions values which were substituted into the inventory. After updating,
ammonia emissions were reevaluated and determined to be correct.
The Canadians revised their estimate of total hydrocarbon emissions from
fuel marketing and landfills based on recent surveys. Canadian area source
THC emissions were updated accordingly.
Environment Canada also provided a complete point source printout
containing additions and corrections to previous stack parameter data. The
Canadian point source file was updated as follows:
I. Additions and corrections were made as reported.
2. Average stack parameter values, based on SCC, were added to point
sources missing some, but not all, stack data. SCC averages were
also added to sources missing all stack data if SC-2 emissions from
the point source were 100 or more tons/year.
3. The remaining points missing all stack parameters were given nominal
plume heights to facilitate modeling applications.
73
-------
Ammonia Emission Factor Updates—
A review of ammonia emissions estimates from the NAPAP ammonia emission
factor report revealed that reported ammonia emissions in the NAPAP inventory
were much higher than expected. A revised version of the ammonia emission
factor report was obtained, and a systematic check of point and area source
emission factors was undertaken. New factors were inserted where appropriate
and emissions recalculated, resulting in a much better agreement between
estimated and reported values.
VOC and THC Emissions—
Previous versions of the 1980 NAPAP inventory contain a mixture of
hydrocarbon types including nonmethane VOCs, nonreactive VOCs, and total
VOCs. In cases where the NAPAP emission factor file was used to calculate
emissions, the emissions are generally nonmethane or nonreactive, because the
NEDS emission factor file (on which the NAPAP file was based) contains
nonmethane or nonreactive "VOC" factors to the extent possible. However, the
program to speciate hydrocarbons for Version 5.2 assumes that total
hydrocarbons are being provided, and in the case of non-computer-calculated
emissions (estimation method ^ 3), VOC and THC were set equal to each other.
In addition, the AP-42 emission factors for hydrocarbons do not account for
aldehydes because the flame ionization technique used to determine the
emission factor does not detect aldehydes. Though the speciation program
accounts for this and adds a mass for aldehydes to the appropriate Version 5.2
photochemical class, this mass was not being accounted for in the 5.0
inventory.
Total hydrocarbon emission factors were added to the inventory using
information provided by NADB and AP-42. These factors were evaluated for
consistency and judged to be of higher quality than those for VOC. At the
recommendation of ASRL, the speciation program was run on the 5.0 inventory
and the resulting aldehyde mass was added to the Version 5.0 total hydrocarbon
value to yield adjusted THC. VOC emissions were then calculated by
subtracting those species considered photochemically nonreactive (essentially
methane and ethane) from the revised hydrocarbon emissions.
The final Version 5.0 emission inventory was subjected to a series of QA
checks. Tables 3-1 through 3-4 summarize the QA checks and present the total
number of records flagged for review. Because the NAPAP inventory is an
emissions inventory rather than a compliance data base, no QA was performed on
allowable emissions and compliance data that were present in NEDS.
A summary of emissions for Version 1.0 through 5.0 of the 1980 NAPAP
inventory is shown in Table 3-5. The emission changes on a nationwide basis
are minor, with the exception of ammonia, which has been reduced greatly as a
result of the emission factor updates discussed earlier. Sulfur oxides
emissions have generally decreased while VOC emissions have increased slightly.
Nitrogen oxide emissions increased from Versions 1.0 to 4.0, but decreased in
Version 5.0. Emission changes at the state and especially at the plant and
emission point level are more dramatic from Versions 1.0 to 5.0. The changes
reflect the greater degree of quality in each succeeding version of the 1980
NAPAP inventory.
74
-------
TABLE 3-1. EMISSIONS TOTALS FOR 1980 AND NON-1980 SOURCES
IN 1980 NAPAP INVENTORY (VERSION 5.0)
COMBUSTION SOURCES
OTHER SOURCES — |
CHECK DESCRIPTION
TOTAL S02 EMISSIONS (TONS/YEAR)
NON-1980 S02 EMISSIONS
PCT OF EMISSIONS FROM 1980
PCT OF EMISSIONS NOT FROM 1980
TOTAL NOX EMISSIONS (TONS/YEAR)
NON-1980 NOX EMISSIONS
PCT OF EMISSIONS FROM 1980
PCT OF EMISSIONS NOT FROM 1980
TOTAL VOC EMISSIONS (TONS /YEAR)
NON-1980 VOC EMISSIONS
PCT OF EMISSIONS FROM 1980
PCT OF EMISSIONS NOT FROM 1980
TOTAL ISP EMISSIONS (TONS/YEAR)
NON-1980 ISP EMISSIONS
PCT OF EMISSIONS FROM 1980
PCT OF EMISSIONS NOT FROM 1980
TOTAL CO EMISSIONS (TONS/YEAR)
NON-1980 CO EMISSIONS
PCT OF EMISSIONS FROM 1980
PCT OF EMISSIONS NOT FROM 1980
UTILITIES
17,478,705
0
100.0*
0.0%
6,148,070
0
100. OK,
0.0%
46,644
0
100. 0%
0.0*
637,746
0
100.0*
0.0*
309,189
0
100.0*
0.0*
INDUSTRIAL
3,480,756
1,912,003
45.1*
54.9*
3,565,714
1,128,913
68.3*
31.7*
372,053
286,749
22.9*
77.1*
1,000,393
766,437
23.4*
76.6*
2,520,855
2,007,362
20.4*
79.6*
COMMERCIAL
560,696
124,386
77.8*
22.2*
287,502
63,601
77.9*
22.1*
17,648
9,289
47.4*
52.6*
103,510
63,114
39.0%
61.0*
52,551
11,471
78.2*
21.8*
OTHER
460,109
151,033
67.2*
32.8*
727,851
168,070
76.9*
23.1*
2,650,912
104,407
96.1*
3.9*
1,585,726
75,458
95.2*
4.8*
9,109,898
365,619
96.0*
4.0*
POINT
3,766,301
2,608,596
30.7*
69.3*
1,472,412
1,094,111
25.7*
74.3*
3,400,594
2,725,275
19.9*
80.1*
2,537,357
1,975,020
22.2*
77.8*
6,034,925
4,702,272
22.1*
77.9*
AREA
1,207,568
0
100.0*
0.0*
9,850,690
0
100.0*
0.0*
16,676,697
0
100.0*
0.0*
36,752,638
0
100.0*
0.0*
81,281,519
0
100.0%
0.0*
TOTAL
26,954,135
4,796,018
82.2*
17.8*
22,352,239
2,454,695
89.0*
11.0%
23,164,548
3,125,720
86.5*
13.5*
42,617,370
2,880,029
93.2*
6.8*
99,308,937
7,086,724
92.9%
7.1*
1 - Utility sources include SCCs lOlxxxxx and 201xxxxx, and area source SCCs 96-98.
Industrial sources include SCCs 102xxxxx, 202xxxxx and lOSOOlxx, and
area source SCCs 14-20.
Commercial sources include SCCs 103xxxxx, 203xxxxx and 105002xx, and
area source SCCs 7-12.
Other combustion sources include all SCCs under 300xxxxx not mentioned above,
306001xx-306002xx, 390xxxxx-391xxxxx, 40201XXX-402011XX,
5xxxxxxx-51xxxxxx, and 30500206-3050028X, and area source SCCs 1-6 and 21-26.
2 - Other sources include all point and area source SCCs not included in note (1) above.
75
-------
TABLE 3-2. PLANT LEVEL QA CHECKS OF 1980 NAPAP
U.S. POINT SOURCES (VERSION 5.0)
COMBUSTION SOURCES
OTHER
TOTAL PERCENT
CHECK NUMBER AND DESCRIPTION
SAMPLE POOL
1: DATE OF RECORD NOT 1980
2: PLANTS FLAGGED IN CHECK 1
EMITTING > 1,000 TONS/YEAR
3: PLANTS WITH MISSING S02, NOX,
TSP, VOC AND CO EMISSIONS
UTILITIES INDUSTRIAL COMMERCIAL OTHER SOURCES FLAGGED FLAGGED
1,364 2,879 392 621 8,423 13,679 NA
0 2,402 318 522 6,647 9,889 72.29
0 6 0 3 14 23 0.17
000000 0.00
1 - Utility sources include SCCs lOlxxxxx and 201xxxxx
Industrial sources include SCCs 102xxxxx, 202xxxxx, lOSOOlxx, and 390xxxxx
Commercial sources include SCCs 103xxxxx, 203xxxxx and 105002xx
Other combustion sources include all SCCs under 300xxxxx not mentioned above,
30600lxx-306002xx, 40201xxx-402011xx, 5xxxxxxx-51xxxxxx,
and 30500206-3050028x
2 - Other sources include all point source SCCs not included in note (1) above.
-------
TABLE 3-3. POINT LEVEL QA CHECKS OF 1980 NAPAP
U.S. POINT SOURCES (VERSION 5.0)
CHECK NUMBER AND DESCRIPTION
SAMPLE POOL
1: VELOCITY DATA MISSING AND PLUME
HEIGHT 0 OR MISSING
2: VELOCITY PRESENT, BUT NOT
BETWEEN 5 AND 130 FT/SEC
3: STACK PARAMS (HT,DIA,TEMP,OR
FLOW) AND PLUME HEIGHT MISSING
4: STACK HGT > 1000 FT.
5: STACK DIAMETER NOT BETWEEN 0.5
AND 30 FT.
6: RATIO OF STACK HGT. TO DIA.
NOT BETWEEN 5 AND 60
7: STACK FLOW RATE IS MISSING
8: STACK TEMPERATURE NOT BETWEEN
60 AND 2000 DEGREES F
9: DAYS PER YEAR NOT BETWEEN
0 AND 365
10: SUM OF SEASONAL THRUPUTS NOT
EQUAL TO 100 t/- 5%
11: DAYS PER WEEK NOT BETWEEN
0 AND 7
12: HOURS PER DAY NOT BETWEEN
0 AND 24
13: WEEKS PER YEAR NOT BETWEEN
0 AND 52
lit: EMISSIONS < 100 TONS/YEAR3
15: UTILITIES WITH ESTIMATION
METHOD OTHER THAN 3
16: ESTIMATION METHOD OF 0, 6, OR 7
17: CONTROL EQUIPMENT PRESENT BUT
CONTROL EFFICIENCY MISSING
; (-unmjaiiun auuKi>ta ; OTHEK FT TOTAL
UTILITIES INDUSTRIAL COMMERCIAL OTHER SOURCES FLAGGED
'•,''72 7,637 761. 1,591 20,019 34,1.83
000000
223 1,027 155 232 2,341 3,978
000000
400015
44 496 10 160 567 1,277
326 765 42 J53 1,844 3,330
0 84 5 19 1,547 1,655
12 24 3 19 1,880 1,938
000000
0 3 0 0 9 12
000000
000000
000000
NA11 471 47 73 7,139 7,730
0 NA NA NA NA 0
000000
000022
PERCENT
FLAGGED
NA
0.00
11.54
0.00
0.01
3.70
9.66
4.80
5.62
0.00
0.03
0.00
0.00
0.00
22.42
0.00
0.00
0.01
77
-------
TABLE 3-3 (continued)
CHECK NUMBER AND DESCRIPTION
SAMPLE POOL
18: ESTIMATION METHOD 3 AND
EMISSIONS MISSING
19: ESTIMATION METHOD NOT EQUAL TO
3 AND EMISSIONS MISSING
20: S02 > 25,000 TONS/YEAR
21: TSP > 25,000 TONS/YEAR
22: NOX > 25,000 TONS/YEAR
23: VOC > 25,000 TONS/YEAR
24: CO > 25,000 TONS/YEAR
25: SPACE HEAT % > 0 AND POINT IS
NOT A COMBUSTION SOURCE
26: SPACE HEAT % > 30 AND WINTER
THRUPUT < SUMMER THRUPUT
UTILITIES INDUSTRIAL COMMERCIAL OTHER SOURCES 2 FLAGGED FLAGGED
4,472 7,637 764 1,591 20,019 34,483 NA
0 0 0-0 0 0 0.00
000000 0.00
187 0 0 0 16 203 0.59
000088 0.02
14 0 0 0 2 16 0.05
000000 0.00
0 1 0 1 88 90 0.26
NA NA NA NA 162 162 0.47
0 27 31 1 11 70 0.20
1 - Utility sources include SCCs lOlxxxxx and 201xxxxx
Industrial sources include SCCs 102xxxxx, 202xxxxx, lOSOOlxx, and 390xxxxx
Commercial sources include SCCs 103xxxxx, 203xxxxx and 105002xx
Other combustion sources include all SCCs under 300xxxxx not mentioned above,
306001xx-306002xx, 40201xxx-402011xx, 5xxxxxxx-51xxxxxx,
and 30500206-3050028X
2 - Other sources include all point source SCCs not included in note (1) above.
3 - These point sources have been flagged because at least one point
within the same plant has emissions exceeding 100 tons/year.
4 - For utility sources, the cutoff for all sources was 1OO tons/year
at the plant level rather than the point level.
78
-------
TABLE 3-4. SCC LEVEL QA CHECKS OF 1980 NAPAP
U.S. POINT SOURCES (VERSION 5.0)
COMBUSTION SOURCES
CHECK NUMBER AND DESCRIPTION
SAMPI.E POOL
1: HOURLY OPERATING RATE > MAX-
IMUM HOURLY OPERATING RATE
2: ALL SCC-I.EVEL EMISSIONS
MISSING
3: SULFUR FLAG = 'S1 AND SULFUR
CONTENT = 0 OR MISSING
It: ASH CODE 'A1 BUT ASH CONTENT
0 OR MISSING
5: THRUPUT = 0 AND SO2 OR NOX > 0
6: S02 = 0, SULFUR CONTENT > 0,
AND THRUPUT NOT EQUAL TO 0
7: HEATRATE =" 0 AND THRUPUT > 0
OR S02 > 0
8: HEATRATE = 0 AND S02 = 0 AND
THRUPW>0
9: S02 NOT EQUAL TO CALCULATED SO2
+/- 15%
10: SOURCES FLAGGED IN CHECK 9 WITH
ESTIMATION METHOD 3
11: SAME AS CHECK 9 NOT INCLUDING
FLAGS OF CHECKS 5 AND 6
12: S02 NOT EQUAL TO CALCULATED S02
t/- 50%
13: S02 NOT EQUAL TO CALCULATED S02
+/- 100%
14: SO2 NOT EQUAL TO CALCULATED SO2
+/- 200%
15: NOX NOT EQUAL TO CALCULATED NOX
<•/- 50%
16: VOC NOT EQUAL TO CALCULATED VOC
+/- 50%
17: ISP NOT EQUAL TO CALCULATED TSP
+/- 50%
UTILITIES INDUSTRIAL COMMERCIAL OTHER SOURCES
7,831. 13,029 973 2,108 26,215
156 1,270 108 268 3,170
0 60 0 63 755
0600k).
00000
0 742 8 287 331
0 404 8 9 24
0 320 6 164 6
110 502 18 101 3
0 1,688 48 506 936
00000
0 1,381 41 327 829
0 1,339 26 405 830
0 997 19 281 550
0 918 18 264 500
0 2,074 106 574 432
0 3 1 1 237
0 2,654 183 604 2,562
FLAGGED
50,159
4,972
878
49
0
1,368
445
496
734
3,178
0
2,578
2,600
1,847
1,700
3,186
242
6,003
FLAGGED
NA
9.91
1.75
0.10
0.00
2.73
0.89
0.99
1.46
6.34
0.00
5.14
5.18
3.68
3.39
6.35
0.48
11.97
79
-------
TABLE 3-4 (continued)
CHECK NUMBER AND DESCRIPTION
SAMPLE POOL
18: CO NOT EQUAL TO CALCULATED CO
t/- 50*
19: POINTS NOT IN CORRECT
COUNTY
UTILITIES INDUSTRIAL COMMERCIAL
7,831. 13,029 973
0 1,9411 148
000
*
• ulHtK j 1V1AL
OTHER SOURCES FLAGGED
2,108 26,215 50,159
429 390 2,911
000
ffcKUtKl
FLAGGED
NA
5.80
0.00
1 - Utility sources include SCCs lOlxxxxx and 201xxxxx
Industrial sources include SCCs 102xxxxx, 202xxxxx, 105001xx, and 390xxxxx
Commercial sources include SCCs lOlxxxxx, 203xxxxx and 10S002xx
Other combustion sources Include all SCCs under JOOxxxxx not mentioned above,
306001xx-306002xx, 40201xxx-402011xx, Sxxxxxxx-Slxxxxxx,
and 30500206-3050028X
2 - Other sources include all point source SCCs not included in note (1) above.
3 - These utility sources have zero annual thruput due to
intermittent operation throughout the year.
80
-------
TABLE 3-5. SUMMARY OF TOTAL U.S. EMISSIONS FROM VERSIONS 1.0 - 5.0
OF THE 1980 NAPAP INVENTORY
Emissions (thousand tons per year)
Version
Pollutant 1.0 2.0 3.0 4.0 5.0a
S02
NOX
voc
Sulfate
Ammonia
Chloride
Fluoride
Lead
27,916 27,784 27,111 27,222
22,905 23,198 23,667 23,833
22,582 22,520 23,269 23,307
947
4,250
—
—
—
26,954
22,352
23,165
976
838
527
115
32
aVersion 5.0 totals shown do not include Canadian emissions which are as
follows:
S02 - 5,109
NOX - 2,054
VOC - 2,994
Sulfate - 188
Ammonia - 210
81
-------
EVOLUTION AND QUALITY ASSURANCE OF THE 1980 RESOLVED NAPAP EMISSIONS INVENTORY
One of the primary functions of the NAPAP emissions inventory, as
recognized at the project's outset, was to serve as a source of data for
emissions modeling. The development of an Eulerian modeling inventory was
initiated with Version 4.0. In order to create a suitable data set, it was
necessary to further resolve the emissions data spatially (to 20 x 20
kilometer grids) and temporally (to the hourly level), and to resolve selected
pollutants (nitrogen oxides, alkaline particulates, and total hydrocarbons)
into their component species. The remainder of this section documents the
development of the fully resolved inventories. A detailed discussion of
allocation factor development appears in Section 6, and a more in-depth
accounting of quality assurance checks applied to the 5.2 inventory can be
found in Section 7.
Versions 4.1 and 4.2
Version 4.0 of the 1980 NAPAP inventory could not be input directly into
the data processing system used to create Eulerian model input. The point
source file had to be compressed to keep data processing costs within reason,
and some additional data processing was necessary to accommodate the system
used to develop Eulerian model input.
The NAPAP point source master file was analyzed to determine how many
emission points would be required to represent 90 percent or more of total
S02, NOX, and VOC emissions. It was discovered that with an emission
cutoff of 100 tons per year for S02 and NOX and 50 tons per year for VOC,
98.1% of S02, 94.5% of NOX, and 89.9% of VOC would be represented. It was
decided to use these cutoffs for the file compression and also to include all
ammonia emission points. Sulfate emissions in the compressed file represented
91.2% of total point source sulfate emissions. The compressed file of major
point sources contained 25,298 emission points compared to about 201,000 in
the entire master file. The remaining point sources were combined by county
and included as a separate area source category for every county in the study
area.
Due to limitations of the data processing, some modifications to the
master files were made to facilitate the use of NAPAP data for developing
Eulerian model input. These included:
• Elimination of TSP and CO data from the point and area source master
files.
• Elimination of industrial fuel-coke, industrial fuel-process gas,
vessels-coal, unpaved road travel, and unpaved airstrip LTOs from
the area source master file.
• Restructuring the area source master file to occupy the first 54
available locations.
* Disaggregating the nationwide NAPAP master files into four smaller
files based on time zone boundaries.
82
-------
The compressed inventory, designated Version 4.1, was processed into an
input file for use in Eulerian modeling by the Regional Model Data Handling
System (RMDHS) which applied temporal, spatial, and species allocation factors
to the data. The resulting Eulerian Modeling Emissions Inventory Version 4.2
represented hourly emissions for 15 pollutants for a typical summer weekday in
1980.
Version 5.2
As was the case for Version 4.0 of the 1980 NAPAP inventory, it was
desirable to compress Version 5.0 of the point source file to limit data
processing time for developing Eulerian model input. Table 3-6 summarizes the
emission cutoffs for each pollutant and the percentage of the total point
source emissions represented by the major emission points in Version 5.0.
Detailed data for only the 34,500 major emission points is maintained in
Version 5.0. The remaining point source emissions (minor points) were
aggregated by county and treated as an area source category in Version 5.0.
Canadian emissions, added to the Version 5.0 inventory, were needed on a
20 x 20 kilometer grid basis. The grid system being used for the U.S. was
extended northward into Canada to 60° latitude, while the westernmost boundary
of the U.S. grid system, 125° longitude, was preserved for the Canadian
inventory. Thus, a portion of northern Quebec and Western British Columbia
fell outside the grid system. The grid system was extended on the east to
cover all Canadian provinces. It should therefore be noted that the Canadian
emission values reported in the Version 5.2 NAPAP inventory do not constitute
total Canadian emissions.
Once the NAPAP grid system for Canada was defined, its description was
furnished to the Canadian Land Directorate, which provided available
allocation data for the 20 x 20 kilometer NAPAP grids in each province in
Canada. A more detailed discussion of spatial allocation of Canadian data can
be found in Section 6.
A number of data processing limitations were discovered during the
development and QA of the 4.2 resolved inventory, which led to the conclusion
that RMDHS was unsuitable for use with the Version 5 data. The Flexible
Regional Emissions Data System (FREDS) was developed as a replacement. Each
of the five FREDS modules, executed sequentially to generate the NAPAP
Version 5.2 Emission Inventory, analyzes incoming data for validity and
quality. The development and QA of the 5.2 inventory using FREDS is
documented in detail in Section 7 of this report.
The resulting NAPAP 5.2 Emissions Inventory contains data resolved to the
hourly level for any of the 12 temporal scenarios shown in Table 3-7. NOX
emissions are allocated between NO and N02, TSP emissions are allocated into
constituent alkaline dust species, and hydrocarbons are divided into 28
photochemical reactivity classes. Data can be resolved to the 20 x 20
kilometer grid level for the 48 contiguous United States and Canada north to
60° latitude.
83
-------
TABLE 3-6. SIZE CUTOFFS FOR VERSION 5.0 OF THE
NAPAP POINT SOURCE INVENTORY
Pollutant
sox
NOX
Total VOC
Sulfate
Ammonia
Chloride
Fluoride
Lead
TSP
CO
Emission point
cutoff
( tons/yr)
100
100
50
50
100
100
50
5
50
100
Percentage of
total point source
emissions represented
98. 1
93.^
89.9
80. 4
93.4
91.4
86. b
89.1
88.2
96.7
84
-------
TABLE 3-7. TEMPORAL SCENARIOS AVAILABLE UNDER THE 1980 NAPAP
EMISSIONS INVENTORY, VERSIONS 5.2 AND 5.J
FREDS temporal
allocation
scenario number
1
2
3
4
5
6
7
8
9
10
11
12
Scenario
Winter Weekday
Winter Saturday
Winter Sunday
Spring Weekday
Spring Saturday
Spring Sunday
Summer Weekday
Summer Saturday
Summer Sunday
Fall Weekday
Fall Saturday
Fall Sunday
85
-------
Following the original processing of the 5.0 inventory through FREDS, a
problem was discovered with the speciation of hydrocarbons which resulted in
an overestimation of all THC classes, particularly formaldehyde. FREDS was
rerun on point sources to correct the averages; however, data processing costs
and the relative magnitude of the overall error for area sources (roughly
3.5%) precluded rerunning the area source FREDS modules. The precise
magnitude of the hydrocarbon class overestimation is dependent on source
category, and can range as high as 95 percent for SCCs corresponding to
distillate oil combustion. Most categories, however, show zero error, and all
major THC source categories exhibit errors of no more than 5 percent
Additional QA revealed that not all point source NOX emissions in the
5.0 inventory were being apportioned into NO and NC>2 in the 5.2 inventory,
resulting in an apparent shortfall of 1.3 percent. This was due to the
presence of several blank NOX speciation profiles in source categories with
nonzero NOX emissions. The profiles were updated to reflect the default
NOX split (95% NO, 5% N02) prior to the rerunning of FREDS to ensure that
all annual NOX is accounted for in the resolved inventory.
It should also be noted that the QA for the 5.0 and 5.2 inventories is
not mutually exclusive. A number of additions and modifications performed on
the Version 5.0 inventory and enumerated in previous sections were geared
toward development and QA of the resolved inventory. Examples include
operating data updates (temporal), SCC level emissions (spatial) and VOC/THC
updates (species). Conversely, the gridded emission density maps developed
from Version 5.2 were instrumental in locating inconsistencies within the 5.0
inventory. For example, a grid map of annual NOX emissions identified a
problem with data from area source category 44 in Vermont, which was traced to
an order of magnitude error in activity level and subsequently rectified.
Also, the updates performed on hydrocarbon classes described above
necessitated an update to annual (5.0) VOC emissions to ensure that they
accurately represented total hydrocarbons less nonreactive species. Since
area source emissions of THC classes remained slightly high, area source VOC
in both the 5.0 and 5.2 inventories is correspondingly low; however, this
error has been estimated to be no greater than 0.4 percent over the NAPAP
study area.
Version 5.3
EPA's Atmospheric Sciences Research Laboratory requested an inventory to
support applications of the Regional Oxidant Model (ROM) throughout the NAPAP
study area. The ROM apportions hydrocarbons into classes based on carbon
bond IV chemistry, a method not supported under Version 5.2. However, the
flexible speciation capabilities of FREDS and the associated program PSPLIT
allowed the generation of a new resolved inventory from the Version 5.0 annual
data. ASRL modified the speciation program (PSPLIT) and generated a set of
speciation factors to apportion total hydrocarbons into 10 reactivity classes
consistent with carbon bond IV mechanisms. Using the new factors, the Version
5.0 inventory was reprocessed through the FREDS system to create Version 5.3.
This newest version of the NAPAP inventory was forwarded to ASRL, which
verified the accuracy of the speciated data. Version 5.3 emissions were also
checked against totals in Version 5.2'to ensure consistency and accuracy.
86
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SECTION 4
NAPAP VERSION 5 EMISSION FACTORS
Emission factors are used by NEDS to compute estimates of emissions
associated with a process when a more accurate estimate is not supplied to the
system. For the NEDS criteria pollutants (S02, NOX, CO, VOC, and total
suspended particulates), these factors were available from the October 19&5
NEDS Emission Factor Listing. Generally, these factors are taken from AP-42.
In some cases, however, they may be derived from better information not yet
incorporated into AP-42 or based on the similarity of one process to another
for which emissions information does exist.
Emissions component species included in the 1980 NAPAP Emission Inventory
are :
• Sulfur Dioxide (802)
• Oxides of Nitrogen (NOX)
• Volatile Organic Compounds (VOC)
• Total Hydrocarbons (THC)
• Carbon Monoxide (CO)
• Lead (Pb)
• Primary Sulfates (804)
• Ammonia (NH^)
• Hydrogen Chloride (HC1)
• Hydrogen Fluoride (HF)
• Total Suspended Particulates (TSP), including Alkaline Dusts
Due to a lack of standardized, reliable sources of data, NAPAP developed
emission factor reports specifically for primary sulfates, hydrogen fluoride,
hydrogen chloride, and ammonia. In addition, emission factors for alkaline
dust fractions were developed by Canada and incorporated into the NAPAP
inventory. These reports review analyses of existing data on emissions from a
87
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variety of source categories and present a tabulation of emission factors
appropriate for use with the NAPAP Emissions Inventory. The reliability of
the emission factors is discussed and areas where data are either lacking or
incomplete are identified. A summary of each report is presented below.
PRIMARY SULFATE EMISSION FACTORS
The primary sulfate emission factor report discussed four major
activities:
1. a summary discussion of primary sulfate formation mechanisms thought
to be prevalent in combustion processes;
2. assessment of the state-of-the-art methodology for primary sulfate
sampling and analysis of source emissions;
3. review of the SURE (Klemm, 1981) and WG3B (1982) primary sulfate
emission inventories; and
4. collection, review, and calculation of primary sulfate emission
factors derived from additional field studies not included in the
SURE and WG3B inventories.
Primary sulfate emission factors recommended for use in the NAPAP
Emissions Inventory are given in Table 4-1. The factors are reported for a
number of SCCs based on an analysis of available data. Most of the current
data set is for fossil fuel combustion in the industrial and utility sectors.
The emission factors have been calculated to a normalized Emissions
Information System (EIS) format as:
Sulfate emissions per SCC unit = (Emission factor x percent sulfur
content of fuel)
The emission factors given in Table 4-1 reflect sulfate emitted as
_2
SO, . Limited data available suggest that sulfate emissions can be markedly
affected by fuel sulfur content and other parameters such as furnace oxygen
levels and trace element content of the fuel. For source categories other
than fossil fuel combustion, sulfate emission factors are reported in standard
SCC units or as percentages of mass particulate emissions.
The calculation of specific primary sulfate emission factors was based on
the following hierarchical selection process.
I. Where available, all field measurements using the CCS procedure were
considered as the prime data set.
2. Sulfate emission assessments were aggregated for different point
sources within the same source category only if fuel composition ana
emission controls were similar.
88
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TABLE 4-1. PRIMARY SULFATE EMISSION FACTORS
Source category
Control
device
Primary sulfate
emission factor
Rating
Electric Utilities -
External Combustion
Eastern bituminous coal
Western bituminous coal
Lignite
Residual oil (>1% sulfur
content)
Industrial - External
Combustion
Eastern bituminous coal
Residual oil
Commercial/Institutional -
External Combustion
Residual oil (<1% sulfur
content)
Space Heating - External
Combustion
Distillate oil
Industrial Process - Chemical
Manufacturing
- contact process
Electric Utilities - External
Combustion
Industrial Process - Primary
Metals
Primary copper smelters
total
roaster
smelter
converter
Primary zinc smelters
ESP 0.385 Ib/ton
ESP and FGD 0.2503
ESP 1.290
ESP and FGD 0.761
ESP
1.951
Fuel oil 5.439 lb/1,000 gallonsb
additives
Multiclones 2.646 Ib/ton
Multiclones
and FGD 0.462
Multiclones 5.296 lb/1,000 gallons
Multiclones
and FGD 2.616
Fuel oil 25.07 lb/1,000 gallonsb
additives
None
5.65 lb/1,000 gallonsb
Demister 0.100 Ib/ton acid produced
None
None
22.5 Ib/ton concentrated ore
1.08
5.76
15.66
55.5 Ib/ton processed
A
C
B
C
C
B
B
C
D
D
C
C
D
D
(continued)
89
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TABLE 4-1 (continued)
Source category
Industrial Process - Primary
Metals (cont.)
Primary aluminum smelter
Iron production
Coke
Industrial Process - Wood
Products
Control
device
None
None
None
Primary sulfate
emission factor
0.5% of S02
2.0% of S02
0.320 Ib/ton coal charged
Rating
D
D
D
Kraft pulp mill None
Sulfite pulp mill None
Wood/bark waste Multiclone
Industrial Process - Mineral
Product
Cement manufacturing None
Gypsum manufacturing None
Industrial Process - Petroleum
Industry
Fluid crackers ESP
Sulfur recovery Glaus plants None
(1)
(2)
3.6 Ib/ton bark
(3)
(4)
15.0 lb/1,000 barrels oil
2.8 Ib/ton produced
C
C
D
D
D
C
C
aEmission factor based on average sulfate scrubbing efficiency of 35 percent.
^Emission factor applicable only to low sulfur content (0.3 percent S)
residual fuel oil.
(l)lotal sulfate emissions for kraft pulp mills estimated as 85 percent of
NEDS total particulate emissions from kraft recovery boilers.
(2)*Total sulfate emissions from sodium-base sulfite mills estimated as
70 percent of NEDS S02 emissions; for calcium-base sulfite mills estimated as
25 percent of NEDS SC<2 emissions.
(3)total sulfate emissions from cement kilns estimated as 5.6 Ib/ton of cement
on an uncontrolled basis. Average particulate control efficiency from NEDS
data assumed to apply in order to calculate actual emissions.
sulfate from gypsum plants estimated as 56 percent as NEDS actual
particulate emissions.
The percentage estimates of the sulfate content of particulate matter in
footnotes 1 through 4 were reported in: Draft Report P-3901/6,
Anthropogenic Sources and Emissions of Primary Sulfates in Canada, Ontario
Research Foundation, Contract No. 477SS.KE204-1-0318, November 30, 1981.
90
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3. Emissions data acquired through the use of methods other than CCS
were included only if multiple measurements yielded data with
minimal scatter.
There are a number of source categories for which no experimental field
data exist. At present, the only alternative to an emission factor for the
NAPAP Emissions Inventory is the assignment of an "assumed" factor already
contained within the source allocation codes for the Regional Model Data
Handling System (RMDHS). However, most of the regional mass emissions of
primary sulfates should occur from those source categories for which emission
factors have already been substantiated (utility and industrial fossil fuel
burning). The best approach to improving the NAPAP Emissions Inventory
sulfate component may be an expanded field measurement activity which focuses
on the source categories which have not been characterized sufficiently, but
which are potentially significant contributors to regional emissions.
Improvements are needed in the data base for low sulfur residual oil-fired
industrial and commercial boilers. Field measurements using the CCS procedure
are recommended for this source type which is a significant source of sulfur
emissions in major metropolitan areas in the eastern United States. In
addition, sulfate emissions from the pulp and paper industry need further
characterization given the large preliminary emission factors reported by
WG3B. Pulp mill operations are concentrated in the acid deposition sensitive
Northeast and represent a major SC>2 and particulate source contributor in
the southeastern United States.
HCl AND HF EMISSION FACTORS
A literature search was conducted to identify significant anthropogenic
emission sources and to estimate emission rates for each source. The emission
factors summarized in Table 4-2 were developed from the most recent data
available. When available, emission factors based on tests performed by a
sound methodology and accompanied by adequate background data were chosen.
Emission factors were evaluated on a scale of A through E, with an A
representing data taken from a large data base covering a good cross section
of the industry, determined from valid test methods, and possessing a high
confidence level. Data rated E were developed from a small data base, which
was not necessarily representative of the industry, and consequently have a
low confidence level. Ratings of B through D represent data with intermediate
confidence levels. National emission estimates for base year 1980 were
calculated by multiplying the level of activity (production/use rates) for
each emission factor for that source. National emission estimates provide a
measure of the relative importance of each source category.
Hydrogen chloride is emitted from coal combustion, waste incineration,
and organic chemical manufacture. Hydrogen fluoride is emitted primarily as a
by-product of coal combustion and primary aluminum production. Other sources
of HF include the fertilizer industry and the hydrogen fluoride manufacturing
industry.
The rates at which HCl and HF are emitted during coal combustion are
functions of coal composition and air pollution control techniques. A study
91
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TABLE 4-2. HYDROGEN CHLORIDE AND HYDROGEN FLUORIDE EMISSION FACTORS
Source
Emission factor
Rating
—HC1--
Coal Combustion
Utility Boiler
Bituminous
Anthracite
Lignite
Industrial Boilers
Bituminous
Anthracite
Lignite
Residential Boilers
Bituminous
Anthracite
Lignite
Propylene Oxide Manufacture
Incineration
Municipal Waste
Industrial Waste
Liquid Waste
By-product Hydrochloric Acid Production
(without final scrubber)
(with final scrubber)
—HF--
Coal Combustion
Utility Boiler
Bituminous
Anthracite
Lignite
Industrial Boilers
Bituminous
Anthracite
Lignite
Residential Boilers
Bituminous
Anthracite
Lignite
Hydrogen Fluoride Manufacture
Tail gas vent
Uncontrolled
Controlled - caustic rubber
78.8 ID/109 Btu
35.5 lb/109 Btu
1.0 lb/109 Btu
78.8 lb/109 Btu
35.5 lb/109 Btu
1.0 lb/109 Btu
60.5 lb/109 Btu
120 lb/109 Btu
35.1 lb/109 Btu
7.46 Ib/ton
5.0 lb/tona
5.35 lb/tona
1.19 lb/tona
3.0 Ib/ton
0.2 Ib/ton
9.4 lb/109 Btu
7.2 lb/109 Btu
1.2 lb/109 Btu
9.4 lb/109 Btu
7.2 lb/109 Btu
1.2 lb/109 Btu
6.37 lb/109 Btu
4.95 lb/109 Btu
6.34 lb/109 Btu
25.0 Ib/ton
0.2 Ib/ton
A
A
A
A
A
A
C
C
C
E
E
E
C
C
A
A
A
A
A
A
C
C
C
E
E
aBased on 1970 data.
92
-------
of coal combustion in utility boilers conducted by the Bureau of Mines found
the majority of chlorine contained in coal to volatilize and form HC1. There
is a need for additional scientific data which directly assess the chemical
form of fluorine emitted during coal combustion. In lieu of such data and
because of the chemical similarity between fluorine and chlorine, it is
assumed that all fluorine in the feed coal reacts to form HF.
Data compiled in 1979 on trace element compositions in coal were obtained
from studies by TRW and Alliance and were used to calculate emission factors
for coal combustion in utility and industrial boilers. These factors were
assigned an A ranking due to the number of tests conducted, availability of
information concerning accuracy, and type of test methods used. Recent data
(1985) developed by the Department of Energy's Pittsburgh Energy Technology
Center from lab tests on bituminous coal in utility boilers resulted in
emission factors which compare favorably with those developed from the
TRW/Alliance study.
Scrubbers, electrostatic precipitators (ESPs), cyclones, and baghouses
are used frequently on coal-fired utility boilers as flue gas control
techniques. The primary purpose of these controls is to remove particulate
matter from the flue gas stream. The efficiency of wet scrubbing devices has
been reported at about 80 percent for HC1 and HF emissions from bituminous
coal-fired utility boilers. Baghouses which have sorbent or alkaline
materials introduced may remove a substantial amount of HC1 and HF. A study
of the use of nacholite and sodium bicarbonate as dry sorbent resulted in a
95 to 98 percent HC1 removal. However, under normal operating practices,
baghouses, ESPs, and cyclones have no significant effect on removal of HC1
or HF.
Another control technique, flue gas desulfurization, is used to remove
sulfur oxides from coal combustion. Data have indicated that flue gas
desulfurization is at least 95 percent effective in removal of HC1. No data
are available to quantify removal efficiencies of HF.
Several emission factors received low ratings because of limited data.
Factors for HC1 from residential boilers, hydrochloric acid manufacturing, and
waste incineration received intermediate to poor rankings because of the small
number of plants actually tested and the absence of information concerning
test methodology. Factors for HF emissions from residential boilers,
phosphoric acid production, and hydrogen fluoride manufacture were assigned
low rankings based upon the low number of studies, absence of information
concerning accuracy of test methods, and the number of assumptions made in
determining these factors. Additional data which address emission rates of
HC1 and HF from these sources would be beneficial.
NH3 EMISSION FACTORS
Ammonia emission factors for the 1980 NAPAP inventory were developed
using a methodology similar to that used for HC1/HF emission factors,
including a literature search, identification of the best available data, and
assignment of confidence ratings. As was done for emission factors for HF and
93
-------
HC1, emission factors for NH3 were assigned a confidence rating on a scale
of A through E, with an A representing a high confidence level, and ratings of
B through D representing intermediate confidence levels. The ammonia emission
factors and their related confidence ratings are summarized in Table 4-3.
Anthropogenic sources of ammonia emissions include field application of
livestock wastes, beef cattle feedlots, fertilizer manufacture and use, fuel
combustion, ammonia synthesis, petroleum refineries, and coke manufacture.
Ammonia volatilization rates from livestock wastes applied to
agricultural land are based on several sets of data. Van Dyne, et al.
compiled information on amounts of manure used in land application while
estimates of ammonia volatilization for various waste management practices and
for various types of livestock were calculated from data developed by Huff,
et al. and Westerman, et al. Ammonia emission factors were calculated from
these data. Because several assumptions were made in deriving the factors,
and because the accuracy of these assumptions is uncertain, these factors
should be considered at best to be gross estimates. Volatilization rates vary
drastically with weather conditions and waste management practices.
Ammonia from beef cattle feedlots were reported by Peters, et al., and
Hutchinson, et al. Data ranged over three orders of magnitude; averages of
the data from these two studies provide emission factors which should again be
considered gross estimates which will vary, depending on weather and waste
management practices.
AP-42 data were used to characterize emissions from fertilizer
manufacture, ammonia synthesis, petroleum refineries, and coke manufacture.
The fertilizer manufacture emission factor varies over several orders of
magnitude depending upon whether a plant uses an excess of ammonia or an
excess of acid in the process. Emissions from petroleum refineries are
primarily from catalytic cracking operations. Sources in the manufacture of
coke include oven charging, door leaks, coke pushing, and quenching. Emission
factors from all of these source categories were rated at a high level of
confidence except coke manufacture, which is based on a small amount of data
from tests conducted in Poland.
Other ammonia sources include land application of anhydrous ammonia
fertilizer and combustion of fuels such as coal, fuel oil, natural gas, and
gasoline. Emission factors for these sources were rated at intermediate to
low confidence levels because they were based on small amounts of data as well
as data of questionable origin. Several emission factors for fuel combustion
were found to originate from estimates published three decades ago that lack a
published basis; despite this deficiency, these estimates have been repeated
in numerous subsequent reports. Additional data addressing ammonia emissions
from combustion sources that use current technology are needed to properly
characterize NH3 emissions.
94
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TABLE 4-3. AMMONIA EMISSION FACTORS
Source
Emission
factor
Rating
Combustion Sources
Coal
Fuel oil
Natural gas
utility boilers
industrial boilers
commercial boilers
Mobile sources
leaded gasoline
unleaded gasoline
diesel
Livestock Wastes
Beef cattle feedlocks
Manure field application
feed cattle
range cattle
dairy cows
swine
sheep
laying hens
broilers
turkeys
Ammonium Nitrate Manufacture
Neutralizer
Solids formation
evaporation/concentration
high density prill towers
low density prill towers
rotary drum granulators
pan granulator
high density prill coolers
low density prill coolers
low density prill dryers
rotary drum granulator coolers
pan granulator coolers
0.00056 Ib/ton coala
0.8 lb/103 gallons fuel3
3.2 lb/106 ft3 gasa
3.2 lb/106 ft3 gasa
0.49 lb/106 ft3 gasa
0.42 lb/103 gallons fuela
0.63 lb/103 gallons fuel3
0.95 lb/103 gallons fuel3
13 Ib/animal marketed1*
7.9
0.22
26
3.1
2.0
0.19
0.024
0.16
0.86-36.0 Ib/ton
0.54-33.4 lb/tonc
57.2 lb/tonc
0.26 lb/tonc
59.4 lb/tonc
0.14 lb/tonc
0.04 lb/tonc
0.30 lb/tonc
0-3.18 lb/tonc
1.19 lb/tonc
0 lb/tonc
D
E
C
C
C
U
D
E
E
E
E
E
E
E
E
E
A
A
A
A
A
A
A
A
A
A
(continued)
95
-------
TABLE 4-3 (continued)
Source
Emission
factor
Hating
Anhydrous Ammonia Fertilizer
Application
Petroleum Refineries
FCC units
TCC units
Reciprocating engine
compressors
Ammonia Synthesis
Carbon dioxide regeneration
Condensate stripping
Urea Manufacture
Solution formation/
concentration
Solid formation
nonfluidized bed prilling
agricultural grade
fluidized bed prilling
agricultural grade
feed grade
drum granulation
rotary drum cooler
Coke Manufacture
Oven charging
Door leaks
Coke pushing
Quenching (contaminated water)
Ammonium Phosphate
Manufacture
19 Ib/ton fertilizer
54 lb/103 barrels feedd
6 lb/103 barrels feedd
0.2 lb/103 ft3 gasa
2.0 lb/tonc
2.2 lb/tonc
18.2 lb/tonc
0.87 lb/tonc
2.9 lb/tonc
4.1 lb/tonc
2.2 lb/tonc
0.0051 lb/tonc
0.02 Ib/ton coal charged
0.06 Ib/ton coal charged
0.1 Ib/ton coal charged
0.28 Ib/ton coal charged
0.14 lb/tonc
B
B
A
A
A
A
A
A
D
D
D
D
Refers to pounds ammonia emitted per unit of fuel burned.
Refers to pounds ammonia emitted per head of cattle marketed from feedlots.
£
Refers to pounds ammonia emitted per ton of product.
^Refers to pounds ammonia emitted per 103 barrels of feed to the cracking
unit.
96
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ALKALINE DUST EMISSION FACTORS
Anthropogenic point source alkaline particulate emission factors were
developed by Meteorological and Environmental Planning Limited and the Ontario
Research Foundation using the following approach:
1. Identify major anthropogenic sources of particulate Ca, Mg, Na,
and K emissions.
2. Estimate the amount of total particulate substances from these
sources in all the provinces and nationally.
3. Estimate the amount of Ca, Mg, Na, and K in these particulates.
4. Estimate the specific types of alkali metal compounds. The total
elemental emission estimates include both the reactive and
nonreactive compounds (from the acid rain point of view). The
nonreactive compounds are salts or rock materials (e.g., calcium
silicates), whereas the reactive materials are defined as portions
of elements associated with carbonates, hydroxides, oxides, and
carbides.
Sources considered were grouped into six sectors:
• Industrial Processes (21 classes of sources)
• Fuel combustion (power generation and fuel wood)
• Transportation (gasoline powered vehicles)
• Solid Waste Incinerators (municipal incinerators and wigwam burners)
• Open sources (paved roads, unpaved roads, agricultural tillings,
construction, mine tillings)
• Open burning (slash burning)
Alkaline particulate emissions from these sectors are assumed to be 89 percent
of total Canadian anthropogenic particulate emissions.
Generic source descriptions were allocated to SCC categories. Where
possible, six-digit SCCs are utilized, with the assumption that the factors
are equally applicable to all relevant particulate emissions within
subcategories to the eight-digit level. Table 4-4 presents a listing of
emission factors as well as an uncertainty rating defined as follows:
A: Actual Canadian test data.
B: Source measurement conducted elsewhere for similar industry.
97
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TABLE 4-4. ANTHROPOGENIC POINT SOURCE ALKALINE PARTICULATE EMISSION FACTORS
00
Percentage of total
particulate emission
as an alkali metal3
sec
3-03-023
3-03-008
3-03-006
3-04-006
3-04-020
3-05-016
3-05-020
3-05-025
3-05-006
3-05-011
3-05-008
3-07-001
1-01-001
1-01-002
1-01-003
1-02-001
1-02-002
1-02-003
1-03-001
1-03-002
1-03-003
3-90-001
3-90-002
3-90-003
1-01-009
1-02-009
1-03-009
1-05-002-09
3-90-009
5-02-002-01
5-01-001
5-01-002-01
5-01-005-07
5-02-001
Generic source description
Iron Ore Mining and Benef iciation
Iron and Steel Industry
Ferroalloy Manufacture
Magnesium Production
Mining and Rock Quarrying
Line Manufacture
Stone Processing
Sand and Gravel
Cement Manufacture
Concrete Batching
Clay Products Manufacture
Sulphate (Kraft) Pulping
Power Generation by Utilities
Fuelwood Combustion
Municipal Incineration
Tons
Tons
Tons
Tons
Tons
Tons
Tons
Tons
Tons
Tons
Tons
Air
Tons
Tons
Tons
Units
Pellets Produced
Produced
Produced
Processed
Raw Material
Limestone Processed
Raw Material
Product
Cement Produced
Processed
Input to Process
Dry Tons Unbleached Pulp
Burned
Burned
Burned
0
3
1
23
5
33
14
0
28
46
0
0
1
0
0
Ca.
.49
.98
.06
.81
.77
.89
.38
.65
.50
.00
.85
.12
.62
.05
.57
w
0.
1.
1.
13.
1.
5.
4.
0.
0.
1.
0.
1.
0.
0.
Ig
24
66
45
90
69
01
12
70
78
50
90
0
71
04
14
Na
0
1.74
1.35
0
0
0.50
0
0
0
0
0
1.38
0.82
0.04
0.57
K
0
5.63
0
0
0
0
0
0
0
0
0
0
0.44
1.95
0.46
Ratingb
E
E
C
C
D
C
C
D
B
C
D
C
C
E
E
aExample: For SCC 3-03-023, emissions of alkaline calcium particulate are calculated as: (particulate per ton pellet
produced) x (0.0049). Total alkaline particulate emitted is calculated as: [(particulate per ton pellet produced) x
(0.0049)1 + [(particulate per ton pellet produced) x (0.0024)].
bUncertainty rating of alkali metal content as B = _+25%, C = +50Z, D = +75Z, and E - ^
-------
C: Inferred data based on product analysis, feed analysis or other
secondary material.
D: Limited data for one or more operations or materials within a sector
or related sector. This is extrapolated to estimate required data.
E: Estimate only.
It should be noted that there is additional uncertainty associated with
assigning these Canadian factors to U.S. particulate emissions. It has been
assumed that the alkali metal contents of U.S. and Canadian particulate
emissions are identical. It should also be noted that there are other source
categories which emit particulate matter containing calcium, magnesium,
sodium, and/or potassium. However, these elements were found to be associated
anions other than carbonates, hydroxides, oxides, and carbides which represent
the alkaline fraction.
99
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SECTION 5
DEVELOPMENT OF EMISSIONS ESTIMATES FOR THE UTILITY SECTOR
Emissions from electric utilities account for a large share of the total
acid deposition precursor emissions; it has been estimated that in 1980 these
emissions accounted for 65 percent of S02 and 29 percent of NOX emissions
from all U.S. sources. As a result, the National Acid Precipitation
Assessment Program (NAPAP) has placed special emphasis on the development of
accurate utility emissions data. NAPAP's Task Group on Emissions and Controls
has sponsored work both in developing estimates of current emissions from the
utility industry and in projecting future emissions. Part of this work
entailed the development of a single, comprehensive utility-related data
file: the NAPAP Utility Reference File (NURF) (Pechan, 1985). The NURF was
created to meet the broad utility-related data needs of all NAPAP work groups,
including atmospheric modeling, emissions forecasting, and assessment. In the
1980 NAPAP Emissions Inventory Version 5.0, the NURF data were used to provide
the utility sector emissions estimates; these estimates were integrated into
the NAPAP inventory for all U.S. electric utilities. This section documents
the development and use of the NURF and its derivative files, focusing on the
integration of the NURF data into the NAPAP inventory.
NAPAP UTILITY REFERENCE FILE (NURF)
Introduction
The NURF is a central repository of data for utility operations and
emissions, designed to facilitate analysis of the electric utility sector.
Information is maintained on all conventional, nuclear, and hydroelectric
utility generating units, including the following data: S02, NOX, and TSP
emissions by fuel and unit; stack parameters on a unit-specific basis; and
information on units coming on-line or converting to coal after 1980. Because
the NURF data were compiled and cross checked using several data sources, the
NURF is considered to present an accurate picture of the U.S. utility industry
for 1980.
Data Sources
NURF was developed using information from Version 4.0 of the 1980 NAPAP
Emissions Inventory (Toothman, 1984), a reimplementation of the Unit Inventory
(Pechan, 1983), and new data; additional updates were obtained from a variety
of sources. Table 5-1 lists major data inputs to NURF. In developing NURF,
the greatest reliance was placed on data available from public sources,
especially files available in machine-readable form.
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TABLE 5-1. MAJOR DATA INPUTS TO NURF
Name
EIA Form 759
FPC Form 423
FPC Form 67
FGDIS
NAPAP Inventory
Generating Unit
Reference File
EPA State
Implementation
Plan file
NERC planned plants
NERC coal conversions
DOE coal conversions
Nuclear plant status
NOX control update
ANL firing data
Type3
A
A
A
A
A
A
A
M
M
M
M
M
A
Level
of detail
Plant
Plant
Boiler/fuel
feeder
Boiler
Boiler
Unit
Unit
Unit
Unit
Unit
Unit
Unit
Unit
Data provided
Fuel consumption and generation
Cost and quality of fuels
Fuels consumed, control equipment,
firing type, and bottom type
S02 scrubber data
Stack parameters
Year online, year retired,
capacity
TSP, S02, and NOX emission
limits
New plants
Plant converted or planning
conversion to coal
Plants converted or planning
conversion to coal
Status of planned nuclear units
NOX control measures
Supplemental data on firing types
and bottom type
aA = Automated
M = Manual
101
-------
In most cases, a single primary source for each NURF data element was
selected. In some cases, more than one source of data was scrutinized and the
most appropriate information chosen. These selections were based on the
quality of the data source, its date of publication, and its coverage. All
other things being equal, published reports (or data files which directly
support them) were given highest preference. Data supplied to DOE or reported
directly by the industry were given the next highest preference. A summary of
the hierarchy of the data sources is presented in Figure 5-1. Some data
elements (e.g., heat rate and capacity factor) could not be obtained from
standard sources and, therefore, had to be calculated fiom data that were
available. For those cases in which the calculated values were unreasonable,
judgments were made as to which of the input values were most accurate; other
data were adjusted on a unit-specific basis so that all resultant values were
consistent.
Because the coverage of the major contributing data files to NURF
differed, it was necessary to compare several data files on a plant-specific
basis in order to develop the best possible universe of facilities. Table 5-2
identifies the sources and coverage of the files contributing unit-specific
information to NURF. Conflicts between these files were resolved on a
case-by-case basis. In most cases in which a conflict occurred, two or more
files contained consistent information, and in those cases, the most
consistent data were chosen. Preference was given to the U.S. Department of
Energy's (DOE) 1980 Form 67 data (U.S. DOE, 1980b) and the Generating Unit
Reference File (GURF—U.S. DOE, 1981b), as they contained more recent
information.
Operating characteristics such as total generation and total fuels
consumed for generation were obtained from DOE's Form 4 (U.S. DOE, 1980a).
Form 4 is a monthly data base; for use in NURF, however, the monthly data for
1980 were aggregated into annual totals. Form 4 data were reported by plant
and prime mover. For example, a plant having both steam and combustion
turbine units would have fuel use and generation data provided for each of
these two prime movers.
Unit-specific operational data for 1980 were estimated by applying 1980
unit shares computed from 1980 Form 67 data on fuel use and generation to the
corresponding data elements from the 1980 plant and prime mover totals from
Form 4. This method was adopted to correct errors associated with the use of
incorrectly reported units on Form 67 submissions. Because the Form 67 data
were used only to compute shares of violated totals, unit errors in Form 67
data were not carried through to the NURF.
Fuel quality data were obtained from the Federal Power Commission (FPC)
Form 423 (U.S. DOE, I981a). For units with no reported Form 423 information,
State average data obtained from Form 423 were used. The State average values
used in NURF are listed in the NAPAP Utility Reference File (NURF), Final
Report (Pechan, 1985).
102
-------
Data Elements
Primary
Secondary
Data Sources
Tertiary
Fourth
Fifth
o
U)
New Plants
Control Equipment
and
Stack Parameters
^^-
Litera-
ture
FGDIS
1 ^*-
NERC
FPC 67
GURF
NAPAP
*»»
NOX
Control
Review
ANL
Firing
Data
Figure 5-1. Hierarchy of NURF data sources by data element.
-------
TABLE 5-2. SOURCES OF UNIT-SPECIFIC DATA
Source
Coverage
Unit identifier
1979 FPC Form 67
1980 FPC Form 67
EPA State
Implementation
Plan File
Generating Unit
Reference File
Boilers at plants with more
than 25 MW steam capacity
Boilers at plants with more
than 25 MW steam capacity
Boilers at plants with more
than 25 MW steam capacity
(based on 1979 Form 67)
All electric utility
generating units
Boiler number
Boiler/feeder number
Generating unit number
Generating unit number
104
-------
NURF Structure
Although labeled the NAPAP Utility Reference File for convenience, the
NURF is actually a data system, consisting of several data files and computer
programs. Because of the diversity of data processing required to create
NURF, a combination of programming languages and methodologies was used in its
development. Initial data reduction of the larger data files was performed by
a series of programs written in Programming Language/I (PL/I). These larger
files were reduced to one record per unit (or plant if a plant-level file) and
converted to a consistent format using the Statistical Analysis System (SAS).
These SAS files were then combined and manipulated using a series of SAS
programs. Examples of the processing required include calculation of default
state average fuel quality data and assignment of plant technology codes. The
result of these manipulations was a final NURF in SAS format. The final
processing steps converted the NURF data in its component file form into the
set of derivative files which are discussed below.
NAPAP INVENTORY UPDATES FILE (NIUF)
Because of the vast number of data elements in NURF taken as a whole, it
was considered impractical to extensively quality assure the file in its
entirety. As a result, only subsets of the NURF data are in distributable
form. Three NURF derivative files have been compiled, QA'd, and made
available for distribution:
• the Unit Inventory, listing unit-specific data on larger generating
units and aggregated information on smaller units;
• the Announced Inventory, containing information on units coming
on-line or planned for conversion to coal after 1980; and
• the NAPAP Inventory Updates File (NIUF), containing corrections and
addenda to the 1980 NAPAP Inventory.
The NIUF contains EIS transactions that are designed to delete, replace,
and supplement utility information in Version 5.0 of the 1980 NAPAP
Inventory. In order to accomplish this update of the NAPAP utility data, the
NIUF was developed as four subfiles:
• plant I.D. information for facilities which appear to be improperly
categorized as utilities in the NAPAP Inventory;
• EIS delete transactions to remove properly categorized utilities
from the NAPAP Inventory, in anticipation of their replacement with
NURF data;
• EIS add transactions of NURF emissions data for utility sources
emitting 100 tons/year or more of 862, NOX, or TSP; and
• EIS area source add transactions to provide county-level aggregates
of utility sources emitting less than 100 tons/year.
105
-------
Creation of the NIUF required the extraction of all relevant information
on utilities from the NAPAP point source file. A candidate list of utility
facilities was identified by selecting points that met at least one of the
following three criteria:
I. The first three digits of the SCC were 101 or 201.
2. The Standard Industrial Classification Code was 4911, 4931, 4961,
or 4900.
3. The first digit of the SCC was one (boiler) and the design capacity
was 1 billion Btu per hour or greater.
These criteria were designed to be general enough that all utility
sources in the NAPAP Inventory would be identified. It was anticipated that
some nonutility sources may have also satisfied these general screening
criteria; as a result, the candidate list of facilities meeting the initial
screening criteria for utilities was reviewed and compared with other data
sources contributing to NURF. A total of 599 NAPAP facilities which were not
utility sources as defined in NURF were identified. The state, county, and
NAPAP plant ID for each of these sources are listed in the first component of
the NIUF. It appears that these sources have been incorrectly classified as
utilities in the NAPAP Inventory; as a result, they were not updated in the
NAPAP Inventory updates process discussed herein. Source information for
these nonutility plants was reviewed; whenever possible, corrections were made
to eliminate the utility information. Changes to SIC and SCC codes and heat
input were made as necessary to reflect reviews of the data.
Existing data from NURF were match-merged at the plant level with the
extracted NAPAP utility point source data. Special emphasis was placed on
matching plants that emit at least 100 tons per year of any criteria pollutant
because point level emissions data were to be provided for plants having
emissions greater than this level. EIS transactions were prepared to delete
data for the matched facilities from the NAPAP Inventory in preparation for
the replacement with the more accurate NURF data. A total of 1,358 delete
transactions were prepared, forming the second component of the NIUF.
After completion of the plant level matching, unit-level matching was
performed. Applying the 100 tons per year cutoff, data for 4,648 NURF units
were then prepared in the form of EIS transactions to be added to the NAPAP
Inventory. These transactions constitute the third component of the NIUF.
There are a total of 41,899 transaction records provided.
The fourth component of the NIUF contains aggregated data, by county, on
the 3,089 NURF units that emitted less than 100 tons per year of any of the
NURF pollutants (TSP, S02, and NOX). Reported information includes state;
county; fuel type; quantity-weighted fuel characteristics (sulfur, ash, and
heating value); fuel quantity; and emissions of TSP, SC>2, and NOX. This
produced a total of 657 data records.
106
-------
Integration of the NIUF Into the 1980 NAPAP Inventory (Version 5.0)
In May 1985, the NIUF data were received for integration into the 1980
NAPAP Inventory. Delete transactions from the NIUF were used to delete all
utility sources in the NAPAP Inventory. Add transactions, containing point
source information for major utilities, were then merged into the point source
inventory. Emissions estimates for these additions were generated using the
operating rate data supplied in the NIUF and AP-42 emission factors, input to
the EIS Master File Maintenance routine. Area source data for minor utility
sources were merged into the NAPAP area source inventory in the following
categories:
96 Minor Utility Sources - Coal;
97 Minor Utility Sources - Oil; and
98 Minor Utility Sources - Gas.
Emission factors were then prepared to generate HC1, HF, and Pb emissions
estimates for the above sources.
107
-------
SECTION 6
DEVELOPMENT OF TEMPORAL, SPECIES, AND
SPATIAL ALLOCATION FACTORS
TEMPORAL ALLOCATION FACTOR DEVELOPMENT
The FREDS Temporal Allocation Module generates a. set of temporal
allocation factors for each NAPAP point or area source emission record. These
factors serve to apportion the annual emissions totals contained in the
emission records into 24 hourly totals for a typical weekday, Saturday, or
Sunday in each of the four seasons of the year. This discussion of temporal
allocation factor development is structured as follows:
I. the form and use of the temporal allocation factors;
2. the development of the factors; and
3. file creation and quality assurance (QA).
Form and Use of Temporal Allocation Factors
NAPAP emission data records contain a single annual emissions total. The
purpose of the temporal allocation factors is to accurately apportion this
total into hour-by-hour subtotals for a weekday, a Saturday, or a Sunday in
any season of the year.
The temporal allocation factors take the form of three sets of fractional
multipliers, applied to the NAPAP annual emissions records in sequence as
follows:
1. Four seasonal factors divide the annual total into four subtotals
representing emissions in each of the four seasons;
2. Three daily factors per season divide each seasonal total into three
subtotals representing emissions for a typical weekday, Saturday,
and Sunday in each season;
3. Twenty-four hourly factors per day divide each daily total into
24 subtotals representing emissions for each hour of that day.
After this final step, the annual emissions total has been divided
into 288 subtotals (four seasons * 3 day "types'Vseason *
24 hours/day "type").
108
-------
The seasonal multipliers for each record sum to unity, as do the hourly
multipliers for each season/day type combination. Since daily emissions
totals represent emissions for one typical weekday, Saturday, or Sunday in
each season, the governing equation for daily allocation factors is:
(65 x weekday factor) + (13 x Saturday factor) + (13 x Sunday factor) = 1
where a season is defined as 91 days (13 weeks). For the purposes of the
NAPAP inventory, the four seasons are defined as:
Season Months
Winter December, January, February
Spring March, April, May
Summer June, July, August
Fall September, October, November
Table 6-1 presents an example of the application of a set of temporal
allocation factors to total hydrocarbon emissions from area source category 32
(Medium Duty Gasoline Vehicles—Rural Roads). For the sake of clarity, hourly
emissions are shown only for summer; however, a similar set of data can be
generated for each of the four seasons using the appropriate hourly
multipliers. In most emissions categories, the daily and hourly factors do
not exhibit a full range of variation, because the data upon which they are
based do not allow such fine resolution.
The hourly temporal allocation factors are based on local time. For many
applications of the NAPAP emissions data, temporally resolved emissions must
be standardized to a common reference (e.g., Greenwich Mean Time). To allow
this standardization, a separate Time Zone File was created. For each county
in the United States (or Canadian county equivalent), this file contains a key
to offset the appropriate hourly emissions pattern from a common reference
point. For each county, this file also contains a flag to key proper offset
of the hourly emissions if and when Daylight Savings Time is in effect for the
county.
Development of Temporal Allocation Factors
The NAPAP point source emissions records contain operating rate data
which allow temporal allocation of yearly emissions to be made on a
point-by-point or plant-by-plant basis. For this reason, emphasis was placed
on development of temporal allocation factors for area source emissions
categories. Independent point source temporal allocation factors were
developed only for a subset of all electric power plants.
U.S. Area Source Factor Development—
The NAPAP Version 5.2 U.S. temporal allocation factors were derived from
three sources:
109
-------
TABLE 6-1. APPLICATION OF TEMPORAL ALLOCATION FACTORS TO TOTAL HYDROCARBON EMISSIONS FOR
U.S. AREA SOURCE CATEGORY 32, MEDIUM DUTY GASOLINE VEHICLES - RURAL ROADS
ANNUAL THC {MISSIONS:
(TOMS/YEAR)
690,863
SEASON:
SEASONAL MULTIPLIERS:
SEASONAL EMISSIONS TOTAL:
'(TONS/SEASON)
0.216
149,226
0.239
165,116
0.269
199,659
0.256
176,861
DAI:
DAILY HULTIFUDtS:
DAILY EMISSIONS TOTAL:
(TONS/DAY)
WEEKDAY
0.0115
1,716
SATURDAY
0.0104
1,552
SUNDAY
0.0089
1,328
WEEKDAY
0.0111
1,833
SATURDAY
0.0111
1,833
SUNDAY
0.0100
1,651
WEEKDAY
0.0110
2,196
SATURDAY
0.0113
2,256
SUNDAY
0.0105
2,096
WEEKDAY
0.0111
1,963
SATURDAY
0.0111
1,961
SUNDAY
0.0097
],H6
HOURLY ALLOCATION (SHOWN: SUMMER ONLY)
(TONS/HUUK)
SUMMER WEEKDAY
SUMMER SATURDAY
SUMMER SUNDAY
HOUR
MNT - 1AM
1AM - 2AM
2AM - 3AM
3AM - 4AM
4AM - 5AM
5AM - 6AM
6AM - 7AM
7AM - BAM
BAM - 9AM
«AH - 10AH
10AM - 11AM
11AM - NOON
NOON - 1PH
1PH - 2PM
2PM - 3PM
3PM - 4PM
4PM - SPM
5PM - 6PM
6PM - 7PM
7PM - SPM
am - 9m
9PM - 10PH
10PM - 11PM
11PM - MNT
HOURLY
MULTIPLIER
0.014
0.010
0.009
0.009
0.011
0.019
0.041
0.056
0.051
0.052
0.056
0.057
0.056
0.057
0.060
0.066
0.07J
0.071
0.059
0.049
0.040
0.035
0.028
0.021
HOURLY
EMISSIONS
31
22
20
20
24
42
90
123
112
114
125
125
123
125
132
145
160
156
130
10B
88
77
61
46
HOURLY
MULTIPLIER
0.022
0.016
0.012
0.010
0.009
O.OU
0.021
0.031
0.042
0.055
0.065
0.069
0.067
0.065
0.064
0.063
0.062
0.059
0.057
0.052
0.045
0.040
0.034
0.029
HOURLY
EMISSIONS
50
36
27
23
20
29
47
70
95
124
147
156
151
147
144
142
140
133
129
117
102
90
77
65
HOURLY
MULTIPLIER
0.025
0.019
0.014
0.011
0.010
0.012
0.017
0.022
0.031
0.044
0.054
0.062
0.068
0.068
0.069
0.069
0.070
0.069
0.065
0.058
0.050
0.042
0.031
0.023
HOURLY
EMISSIONS
52
40
29
23
21
25
36
46
65
92
113
130
143
143
145
145
147
145
136
122
105
88
65
48
-------
1. the NECRMP inventory effort (Sellars, et al. 1982d);
2. the NAPAP Version 4.2 inventory effort (Sellars, et al. 1985); and
3. new research.
The first step in completion of the NAPAP Version 5.2 factors was a
review of each set of factors created for the earlier NECRMP and NAPAP
Version 4.2 inventories. Based on this review, a decision was made to take
one of three actions:
1. Accept the NECRMP/NAPAP Version 4.2 factors without modification.
2. Review the data sources used to compile the NECRMP/NAPAP Version 4.2
factors. If it was determined that the most accurate available data
had been used, the factors were accepted without modification. If
more accurate or more recently available data promised to make
possible an improvement in the factors, new research was conducted
and new factors developed.
3. Develop new factors from scratch. For a few categories where either
(a) NECRMP/NAPAP Version 4.2 factors had been based on engineering
judgment, or (b) the importance of the emission category warranted
the effort, new factors were developed after only a cursory review
of the NECRMP/NAPAP Version 4.2 factors.
Sixteen area source emissions categories in the NAPAP Version 5.0
Inventory were not present in the earlier inventories. Eight of these
categories represented minor variations of an existing category (e.g., a
different fuel), and existing factors could be reviewed and utilized as
appropriate. New factors were developed for the remaining newly added
categories.
Table 6-2 summarizes the actions taken to produce the NAPAP Version 5.2
temporal allocation factors. The table lists each emission category and notes
whether factors had been developed for earlier inventory efforts. The action
taken to produce the NAPAP Version 5.0 factors is listed in the right hand
column.
Table 6-2 also lists the resolution of each set of temporal allocation
factors. The factors for a given area source category apply either to a
single state, a group of states, or to the entire nation. The level of
resolution for each category was determined by:
1. Importance of the category in terms of emissions. Raw data were
scanned; categories which contributed little to national emissions
totals were generally given national resolution;
2. Data availability. State- or region-specific factors could not be
developed where data were not available to support this resolution.
Ill
-------
TABLE 6-2. TEMPORAL ALLOCATION FACTOR DEVELOPMENT FOR NAPAP VERSION 5.2 EMISSIONS CATEGORIES
CATEGORY
NUMBER
'NEW' 'OLD'
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
1
2
3
It
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
EMISSIONS CATEGORY FACTORS PRESENT ACTION TAKEN
IN NECRMP OR FOR NAPAP V. 5
NAPAP V. 4 INVENTORY
INVENTORY
Residential Fuel — Anthracite Coal
Residential Fuel — Bituminous Coal
Residential Fuel — Distillate Oil
Residential Fuel — Residual Oil
Residential Fuel — Natural Gas
Residential Fuel — Wood
Comnercial/Institutional Fuel — Anthracite Coal
Commercial/Institutional Fuel — Bituminous Coal
Commercial/Institutional Fuel — Distillate Oil
Comnercial/Institutional Fuel — Residual Oil
Comnercial/Institutional Fuel — Natural Gas
Commercial/Institutional Fuel — Hood
Industrial Fuel -- Anthracite Coal
Industrial Fuel — Bituminous Coal
Industrial Fuel — Coke
Industrial Fuel — Distillate Oil
Industrial Fuel — Residual Oil
Industrial Fuel -- Natural Gas
Industrial Fuel — Wood
Industrial Fuel — Industrial Process Gas
Incineration — Residential
Incineration — Industrial
Incineration — Commercial/Institutional
Open Burning — Residential
Open Burning — Industrial
Open Burning — Conmerical /Institutional
Light Duty Gas Vehicles — Limited Access
Light Duty Gas Vehicles — Rural
Light Duty Gas Vehicles — Suburban
Light Duty Gas Vehicles — Urban
Medium Duty Gas Vehicles — Limited Access
YES
YES
NO
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
NO
YES
YES
YES
YES
YES
NO
YES
NO
YES
NO
REVIEW,
REVIEW,
USE CAT
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
USE CAT
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
REVIEW,
DEVELOP
DEVELOP
DEVELOP
DEVELOP
DEVELOP
USE
USE
NAPAP V
NAPAP V
.4
.4
. 4 FACTORS
USE
USE
USE
USE
USE
USE
USE
USE
USE
USE
USE
. 14
USE
USE
USE
USE
USE
USE
USE
USE
USE
USE
USE
NEW
NEW
NEW
NEW
NEW
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
FACTORS
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
NAPAP V
FACTORS
FACTORS
FACTORS
FACTORS
FACTORS
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
RESOLUTION
STATE
STATE
STATE
STATE
STATE
STATE
STATE (NECRMP STATES), NATIONAL
STATE (NECRMP STATES), NATIONAL
STATE (NECRMP STATES), NATIONAL
STATE (NECRMP STATES), NATIONAL
STATE (NECRMP STATES), NATIONAL
STATE (NECRMP STATES), NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
(OTHER)
(OTHER)
(OTHER)
(OTHER)
(OTHER)
(OTHER)
-------
TABLE 6-2 (continued)
CATEGORY
NUMBER
'NEW1 'OLD'
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
EMISSIONS CATEGORY
Medium Duty Gas Vehicles — Rural
Medium Duty Gas Vehicles -- Suburban
Medium Duty Gas Vehicles — Urban
Heavy Duty Gas Vehicles — Limited Access
Heavy Duty Gas Vehicles — Rural
Heavy Duty Gas Vehicles -- Suburban
Heavy Duty Gas Vehicles — Urban
Off-Highway Gas Vehicles
Heavy Duty Diesel Vehicles — Limited Access
Heavy Duty Diesel Vehicles — Rural
Heavy Duty Diesel Vehicles — Suburban
Heavy Duty Diesel Vehicles — Urban
Off-Highway Diesel Vehicles
Railroad Locomotives
Aircraft — Military
Aircraft — Civil
Aircraft — Commercial
Vessels — Coal-Powered
Vessels — Diesel
Vessels — Residual Oil
Vessels — Gasoline
BLANK (formerly Solvents Purchased)
Gasoline Marketed
Unpaved Roads
Unpaved Airport LTO's (NO EMISSIONS DATA)
Construction Sites (NO EMISSIONS DATA)
Miscellaneous Wind Erosion (NO EMISSIONS DATA)
Agricultural Tilling (NO EMISSIONS DATA)
Forest Fires
Managed Burning
Agricultural Field Burning
FACTORS PRESENT ACTION TAKEN
IN NECRMP OR FOR NAPAP V. 5
NAPAP V. 4 INVENTORY
INVENTORY
YES
NO
YES
NO
YES
NO
YES
YES
NO
YES
NO
YES
YES
YES
YES
YES
YES
NO
YES
YES
YES
YES
NO
YES
YES
YES
DEVELOP NEW FACTORS
DEVELOP NEW FACTORS
DEVELOP NEW FACTORS
USE CAT. 36 FACTORS
REVIEW, USE NAPAP V.4
USE CAT. 38 FACTORS
REVIEW, USE NAPAP V.4
REVIEW, USE NAPAP V.4
USE CAT. 41 FACTORS
REVIEW, USE NAPAP V.4
USE CAT. 43 FACTORS
REVIEW, USE NAPAP V.4
REVIEW, USE NAPAP V.4
Q.A. ONLY
Q.A. ONLY
Q.A. ONLY
Q.A. ONLY
USE CAT. 50 FACTORS
REVIEW, USE NAPAP V.4
REVIEW, USE NAPAP V.4
REVIEW, USE NAPAP V.4
REVIEW, USE NAPAP V.4
DEVELOP NEW FACTORS
REVIEW, USE NAPAP V.4
Q.A. ONLY
Q.A. ONLY
RESOLUTION
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
STATE
NATIONAL
NATIONAL
NATIONAL
NATIONAL
STATE
REGION
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
STATE
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
-------
TABLE 6-2 (continued)
CATEGORY
NUMBER
'NEW' 'OLD'
63
64 46
65
66
67
68
69
70
71 47
72 48
73 49
74 50
75 51
76 52
77 53
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
EMISSIONS CATEGORY
Orchard Heaters (NO EMISSIONS DATA)
Structural Fires
(UNFILLED)
(UNFILLED)
(UNFILLED)
(UNFILLED)
(UNFILLED)
(UNFILLED)
Manure Field Application — Beef Cattle
Manure Field Application — Dairy Cows
Manure Field Application — Hogs and Pigs
Manure Field Application — Broilers
Manure Field Application — Other Chickens
Anhydrous NH3 Fertilizer Application
Beef Cattle Feed Lots
Degreasing
Drycleaning
Graphic Arts
Rubber and Plastic Manufacturing
Architectural Coating
Auto Body Repair
Motor Vehicle Manufacturing
Paper Coating
Fabricated Metals
Machinery Manufacturing
Furniture Manufacturing
Flat Wood Products
Other Transportation Equipment Manufacturing
Electrical Equipment Manufacturing
Ship Building and Repair
Miscellaneous Industrial Manufacturing
FACTORS PRESENT
IN NECRMP OR
NAPAP V. 4
INVENTORY
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
(NECRMP
(NECRMP
(NECRMP
(NECRMP
(NECRMP
(NECRMP
(NECRMP
(NECRMP
(NECRMP
(NECRMP
(NECRMP
(NECRMP
(NECRMP
(NECRMP
(NECRMP
(NECRMP
only)
only)
only)
only)
only)
only)
only)
only)
only)
only)
only)
only)
only)
only)
only)
only)
ACTION TAKEN
FOR NAPAP V. 5
INVENTORY
Q.A. ONLY
DEVELOP NEW FACTORS
DEVELOP NEW FACTORS
DEVELOP NEW FACTORS
DEVELOP NEW FACTORS
DEVELOP NEW FACTORS
DEVELOP NEW FACTORS
Q.A. ONLY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
NEW SEASONAL, DAILY
FACTORS
FACTORS
FACTORS
FACTORS
FACTORS
FACTORS
FACTORS
FACTORS
FACTORS
FACTORS
FACTORS
FACTORS
FACTORS
FACTORS
FACTORS
FACTORS
RESOLUTION
NATIONAL
REGION
REGION
REGION
NATIONAL
NATIONAL
REGION
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
-------
TABLE 6-2 (continued)
CATEGORY
NUMBER
'NEW' 'OLD1
94
95
96
97
98
99 54
EMISSIONS CATEGORY
Miscellaneous Industrial Solvent Use
Miscellaneous Non- Industrial Solvent Use
Utility Area Sources — Coal Fired Plants
Utility Area Sources — Oil Fired Plants
Utility Area Sources -- Natural Gas Fired Plants
Minor Point Sources
FACTORS PRESENT
IN NECRMP OR
NAPAP V. 4
INVENTORY
YES (NECRMP only)
YES (NECRMP only)
NO
NO
NO
YES
ACTION TAKEN
FOR NAPAP V. 5
INVENTORY
NEW SEASONAL, DAILY FACTORS
NEW SEASONAL, DAILY FACTORS
DEVELOP NEW FACTORS
DEVELOP NEW FACTORS
DEVELOP NEW FACTORS
Q.A. ONLY
RESOLUTION
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
NATIONAL
1 - NECRMP STATES: Connecticut, Delaware, District of Columbia, Maine,
Maryland, Massachusetts, New Hampshire, New Jersey, New York,
Ohio, Pennsylvania, Rhode Island, Vermont, Virginia, West Virginia.
-------
A description of the development of the area source temporal allocation
factors for each category or set of categories follows.
Residential Fuel Combustion (Categories 1-6)—Monthly average heating
degree days for a representative meteorological recording station from each
state were obtained from State, Regional, and National Monthly and Seasonal
Heating Degree Days Weighted by Population (U.S. Department of Commerce,
1983); from these data, the seasonal temporal factors for each state were
developed. The hourly variations in residential fuel use were developed with
data from NOAA (U.S. Department of Commerce, 1980). Monthly averages of the
3-hour meteorological records were obtained for each meteorological station to
determine these diurnal patterns. For each month, the average temperature was
subtracted from 18.7°C (the value used to calculate degree days). Negative
values (indicating temperatures above 18.7°C) were set to zero. The resulting
eight values were proportional to the variation in diurnal heating for a
selected station for a month. Months were then averaged to obtain seasonally
adjusted diurnal factors for each state.
Commercial/Institutional Fuel Use (Categories 7-12)—Seasonal, daily, and
hourly fuel use patterns for these categories were developed from the EPA
Guidelines (U.S. EPA, l979b). For the NECRMP study area, daily and hourly
patterns were developed from data collected for the Philadelphia AQCR
Inventory (Engineering-Science, 1981).
Industrial Fuel Use (Categories 13-20)—National seasonal patterns were
developed from the EPA Guidelines (U.S. EPA, 1979b), in which a uniform
distribution is recommended. The daily pattern was based on U.S. Bureau of
Labor statistics on average overtime at manufacturing facilities (U.S.
Department of Labor, 1981). The assumption was made that all overtime hours
were worked on weekends, and that three times as much overtime was put in on
Saturdays as on Sundays. The daily patterns developed from these data indicate
that approximately 93 percent of emissions occur on weekdays, 5 percent of
Saturdays, and 2 percent on Sundays. This distribution varied slightly
depending on the season. The hourly pattern was developed during the
Philadelphia AQCR inventory effort (Engineering-Science, 1981). In the
Philadelphia study, 50 percent of industrial coal and oil fuel use emissions
were allocated uniformly from 7 a.m. to 4 p.m., to reflect greater production
during business hours. The remaining 50 percent of emissions were uniformly
allocated to the remaining hours in a day. This pattern was applied
nationwide to all industrial fuel use categories in the NAPAP inventory.
Onsite Incineration and Open Burning (Categories 21-26)—Seasonal, daily,
and hourly patterns were developed from existing inventories (Klemm and
Brennan, 1981; U.S. EPA, I979a; New Jersey Department of Environmental
Protection, 1980; New York Department of Environmental Conservation, 1980;
U.S. EPA, 1980).
Highway Vehicles, Light and Medium Duty (Categories 27-34)—The
U.S. Department of Transportation (USDOT) collects Continuous Traffic Count
(CTC) data from all 50 states, and uses a subset of these data representing
13 states as a basis for estimating national traffic patterns. These
13 states' data allow hourly temporal allocation factors to be derived for
each day of the week in each month of "the year for six roadway types. This
116
-------
data set was obtained and analyzed to yield seasonal, daily, and hourly
temporal allocation factors for light and medium duty vehicles (Welty,
personal communication).
Highway Vehicles, Heavy Duty (Categories 35-38, 40-43)—These eight
categories represent gas and diesel heavy duty vehicles on limited access,
urban, suburban, and rural roads. The NECRMP uniform seasonal pattern was
used for NAPAP Version 5.2 after its applicability was confirmed by the U.S.
Trucking Association (Roth, personal communication).
Off-Highway Vehicles (Categories 39, 44)—State-specific seasonal
emission patterns were derived from data contained in Highway Statistics (U.S.
DOT, 1980). Monthly distribution of off-highway motor fuel use was calculated
by subtracting monthly on-highway fuel use from total monthly fuel use.
Seasonal allocation factors were then derived from the monthly pattern.
Daily patterns were derived from the EPA Guidelines (U.S. EPA, 1979b),
and are a composite (weighted by emission strength) of the daily patterns for
the five subcategories of off-highway vehicles (agricultural equipment,
construction equipment, industrial equipment, lawn and garden equipment, and
motorcycles) for which factors are separately described in the Guidelines.
Separate hourly patterns were derived for gasoline (Category 39) and
diesel (Category 44) vehicles using data from a variety of sources, including
the EPA Guidelines (U.S. EPA, 1979b), the Regional Air Pollution Study:
Off-Highway Mobile Sources Emission Inventory (U.S. EPA, 1977), Highway
Statistics, 1980 (U.S. Department of Transportation, 1980) and several
statewide area source emission inventories (Sellars, et al., 1982a, 1982b,
1982c; Haupt, et al., 1982).
Railroads (Category 45)—The temporal factors developed for railroad
locomotives in the NECRMP study were based on information provided by Conrail
and in the Philadelphia AQCR inventory (Engineering-Science, 1981). These
data are probably not representative of the entire nation. Thus, the
NECRMP-developed temporal profile for railroads was used only for those states
within the NECRMP study area; new seasonal, daily, and hourly patterns,
developed from factors in the EPA Guidelines (U.S. EPA, 1979b), were used for
the remaining states in the NAPAP inventory.
Aircraft (Categories 46-48)—For civil aircraft, seasonal, daily, and
hourly patterns were derived from the EPA Guidelines (U.S. EPA, 1979b). For
military aircraft, patterns were derived from the Philadelphia AQCR Inventory
(Engineering-Science, 1981). For commercial aircraft, patterns were derived
from data presented in Seasonally Adjusted Traffic and Capacity (U.S. Civil
Aeronautics Board, 1981).
Vessels (Categories 49-52)—Patterns for coal (Category 49), diesel
(Category 50), and residual oil (Category 51) powered vessels were developed
from the EPA Guidelines (U.S. EPA, 1979b). For gasoline powered vessels
(dominated by pleasure boats), the Guidelines recommend that seasonal patterns
be based on the number of months the mean temperature exceeds 45°F; State,
Regional, and National Monthly and Annual Average Temperatures Weighted by
Area (U.S. Department of Commerce, 1983) provided this information, and
117
-------
seasonal patterns were created as recommended. Daily and hourly patterns were
developed from the Guidelines.
Gasoline Marketed (Category 54) — The primary sources of information for
seasonal patterns were the U.S. Department of Energy's (DOE's) Petroleum
Marketing Monthly (U.S. Department of Energy, 1984) and the U.S. Department of
Transportation's (DOT's) Highway Statistics, 1980 (U.S. Department of
Transportation, 1980). Analyses of these data yielded the conclusion that
evidence was insufficient to justify using other than a uniform seasonal
distribution. Daily and hourly patterns were based on the EPA Guidelines
(U.S. EPA, 1979b).
Unpaved Roads (Category 55) — The seasonal, daily, and hourly patterns for
this category were assigned those for Light Duty Vehicles on rural roads
(Category 28).
Agricultural, Structural, and Forest Fires (Categories 60, 61, 62, 64) —
Managed burning (Category 61) and agricultural field burning (Category 62)
used the patterns developed for field/slash burning in the NECRMP study
(Sellars, et al., 1982d). Structural fires (Category 64) and forest fires
(Category 60) were assumed to occur randomly, 7 days per week, 24 hours per
day. Structural fires were assumed to occur uniformly throughout the year.
It was estimated that 90 percent of forest fires occur during summer or fall,
and that the remaining 10 percent are split evenly between winter and spring.
Manure Field Application (Categories 71-75) — Agricultural Extension
Agents in 12 states across the country (Indiana, Wisconsin, Nebraska, Kansas,
North Dakota, Idaho, Iowa, North Carolina, Alabama, New York, Texas and
Arkansas) were contacted; they provided information on the seasonal pattern of
manure application in their states. These patterns were extended to nearby
states not contacted directly. Daily patterns were governed by the assumption
that most farm activity takes place on weekdays and Saturdays; hourly patterns
assume this activity takes place during daylight hours.
Fertilizer Application (Category 76) — The 12 Agricultural Extension
Agents contacted to provide information on manure spreading practices (see
above) were also asked to share their knowledge of NH3 fertilization
practices. Daily and hourly factors were assigned under the same assumptions
which governed the selection of factors for the manure spreading categories
(see above).
Beef Cattle Feed Lots (Category 77) — Emissions were assumed to be uniform
throughout the year and the week.
Solvent Use Categories (Categories 78-95) — U.S. Department of Labor
statistics on 1980 working hours (U.S. Department of Labor, 1981) were
consulted to derive seasonal and daily temporal variation in these emission
categories. These data were broken down by SIC code; the NAPAP emission
categories were matched with the most appropriate code in the data set.
Monthly data on total hours worked served as the basis for seasonal allocation
factors. Data on overtime hours worked served as the basis for daily factors;
the assumption was made that all overtime hours were worked on weekends, and
that three times as much overtime was put in on Saturdays as on Sundays.
118
-------
Utility Point Source Emissions (Categories 96-98)—The seasonal factors
were based on electric generation data contained in the EPRI Regional Systems
(EPRI, 1981). Daily factors are governed by the assumption that utility
activity is constant during the week; hourly factors assume that most activity
around these plants occurs during normal working hours.
Minor Point Sources (Category 99)—The temporal variation for this minor
emissions category assumes an operating "schedule" of 52 weeks per year,
5 days per week, and 8 hours per day.
Summary—Appendix C contains figures which highlight the seasonal, daily,
and hourly temporal allocation patterns for the United States area source
emission categories. Categories for which temporal allocation factors were
resolved by state are represented only by the mean pattern for all states.
Canadian Area Source Temporal Allocation Factors—
The Canadian area source temporal allocation factors were developed under
the auspices of Supply and Services Canada by the MEP company of Markham,
Ontario, and the Ontario Research Foundation of Mississauga, Ontario; they
were adopted without substantial changes for incorporation into the NAPAP
Inventory effort. The Canadian factors were developed through the same sort
of research which went into development of the U.S. factors. Business and
government statistics and meteorological and climatological data formed the
raw input into development of the factors. Where the data made such
resolution possible, factors were developed at the individual province level.
Where emissions for a category are climate-dependent, an attempt was made to
refine province-level factors further by 4 degree zone of latitude. Where
appropriate and possible, separate factors were developed for different
pollutant species within a single emissions category (this resolution applied
only to factors for automobile emissions).
The Canadian temporal allocation factors were provided to NAPAP in a
written report (MEP/Ontario Research Foundation, 1985). The factors were
extracted from this report and reformatted by a procedure described below.
The FREDS handling of the Canadian emissions data did not allow use of either
(a) the latitude-zone-specific factors, or (b) the species-specific factors.
Where appropriate, the mean of the latitude-zone-specific factors was
calculated and used to represent an entire province; where species-specific
factors had been calculated, che factors for a pollutant for which emissions
vary directly with temperature were used for the emissions category.
Table 6-3 summarizes the Canadian area source emission categories and the
level of resolution of the associated temporal allocation factors.
U.S. Point Source Temporal Allocation Factors—
State- and fuel-specific temporal allocation factors were developed only
for a subset of all electric generating emissions sources. For the remaining
point sources in the NAPAP Version 5.0 Inventory, operating rate data
contained in the emissions records themselves formed the basis for the
temporal allocation of emissions.
119
-------
TABLE 6-3. CANADIAN AREA SOURCE CATEGORIES AND TEMPORAL FACTOR
LEVEL OF SPECIFICITY
CATEGORY
NIJMBFR
BASF CATEGORY
SUB-CATEGORY
LEVEL
10101
1.0102
10103
10104
10105
10106
10201
10202
10203
10204
10206
10207
10208
10210
10211
10213
10214
10217
102 IB
10220
10221
10301
10501
10601
10701
10801
11201
11301
11401
1402
1403
1404
1501
1502
1503
1504
11702
11703
11704
11705
11706
11711
11712
11713
11714
11715
11716
11721
11722
11723
11724
11725
GASOLINE POWERED MOTOR VEH.
GASOLINE POWERED MOTOR VEH.
GASOLINE POWERED MOTOR VEH.
GASOLINE POWERED MOTOR VEH.
GASOLINE POWERED MOTOR VEH.
GASOLINE POWERED MOTOR VEH.
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAr MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
OFF-HIGHWAY MOBILE SOURCES
NON-HIGHWAY USE OF GASOLINE
FOREST FIRES
SLASH BURNING
STRUCTURAL FIRES
FERTILIZER APPLICATION
DRY CLEANING
SAND AND GRAVEL PROCESSING
COAL INDUSTRY
INDUSTRY
INDUSTRY
INDUSTRY
INDUSTRY
INDUSTRY
INDUSTRY
INDUSTRY
COAL
COAL
COAL
MOOD
WOOD
WOOD
WOOD
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
LIGHT DUTY TRUCfS
HEAVY DUTY TRLO- S
MEDIUM DUTY VEHICLES
AUTOMOBILES
MOTORCYCLES
SNOWMOBILES
HELICOPTERS
HELICOPTER FLIGHTS
JET AIRCRAFT
JET AIRCRAFT FLIGHT
LOCAL AIRCRAFT FLIGHT
PISTON ENGINE AIRCRAFT
PISTON ENGINE INFLIGHT
PISTON TRANSPORT INFLIGHT
SMALL PISTON AIRCRAFT
TURBOPROP AIRCRAFT
DIESEL OIL — RAILROADS
GASOLINE OUTBOARD MOTORS
MOTORSHIPS DOCK'S IDE
MOTORSHIPS UNDERWAY
STEAMSHIPS DOCKSIDE
STEAMSHIPS UNDERWAY
PROVINCE
PROVINCE
PROVINCE
PROVINCE
NATIONAL
NATIONAL
PROVINCE
PROVINCE
PROVINCE
PROVINCE
PROVINCE
NATIONAL
PROVINCE
PROVINCE
NATIONAL
NATIONAL
COAL HANDLING
COAL MINING
OVERBURDEN REMOVAL
COAL TRANSPORTATION
SAWMILL PRODUCTION
PLYWOOD AND VENEER PROD.
HARDWOOD PRODUCTION
PULPBOARD PRODUCTION
ELEC PWR — DISTILLATE OIL
ELEC PWR — DIESEL TURBINES
ELEC PWR — HEAVY OIL
ELEC PWR — MISC DIESEL
ELEC PWR — NATURAL GAS
RESIDENTIAL COAL
RESIDENTIAL DISTILLATE OIL
RESIDENTIAL KEROSENE
RESIDENTIAL LIQ. PETROLEUM
RESIDENTIAL NATURAL GAS
RESIDENTIAL RESIDUAL OIL
COMM/INST COAL
COMM/INST DISTILLATE OIL
COMM/INST KEROSENE
COMM/INST LIQ. PETROLEUM
COMM/INST NATURAL GAS
NATIONAL
PROVINCE
PROVINCE
PROVINCE
NATIONAL
PROVINCE
PROVINCE
PROVINCE
120
-------
TABLE 6-3 (continued)
:APE':;OF:,'
NUMBER
BA5t~ CATEGORY
SUB-CATEGORY
LEVEL
11725
L : 73 t
\ i77'2
11733
11734
1 1735
1 1 736
1 17^0
1 1801
12001
12002
12101
121 <">2
i r 103
12104
17111
I 2 1 12
12113
12114
12115
12116
121 1.7
1 211' 1
12501
125U2
12601
12602
12603
12604
126O5
12606
12613
12614
12615
12623
1 2624
1 2625
12626
12641
12642
12643
12644
1 2701
12702
12703
12704
12705
12801
12802
12803
12901
12902
12903
FUEL COMB.
FUEL COMB.
FUEL TOMB.
FUEL COMB.
FUEL COMB.
FUEL COMB.
FUEL CUMB.
FUEL
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
STATIONARY SRCS.
COMB.
TiM CRIES
ASPHALT PRODUCTION
ASHPALT PRODUCTION
STONE PROCESSING
STONE PROCESSING
STONE PROCESSING
STONE PROCESSING
STONE PROCESSING
STONE PROCESSING
STONE PROCESSING
STONE PROCESSING
STONE PROCESSING
STONE PROCESSING
STONE PROCESSING
STONE PROCESSING
CLAY PRODUCTS MANUFACTURE
CLAY PRODUCTS MANUFACTURE
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
GRAIN HANDLING AND MILLING
NATURAL GAS PROCESSING
NATURAL GAS PROCESSING
NATURAL GAS PROCESSIKG
NATURAL GAS PROCESSING
NATURAL GAS PROCESSING
SOLID WASTE INCINERATION
SOLID WASTE INCINERATION
SOLID WASTE INCINERATION
DIESEL AND GASOLINE MARKETING
DIESEL AND GASOLINE MARKETING
DIESEL AND GASOLINE MARKETING
COMM/INST RESIDUAL OIL
INDUSTRIAL COAL
INDUSTRIAL DISTILLATE OIL
INDUSTRIAL KEROSENE
INDUSTRIAL LIQUID PETROLEUM
INDUSTRIAL NATURAL GAS
INDUSTRIAL RESIDUAL OIL
FUELWOOD COMBUSTION
ASPHALT DRYING
ASPHALT FUGITIVES
CRUSHED STONE — PRIMARY
CRSH STN — SCREEN, CONVEY
CRSH STN — SECONDARY
CRSH STN — SECONDARY
PULV STONE -- PRIMARY
PULV STN — RECRUSH, SCREEN
PULV STN — SCREEN, CONVEY
PULV STN — SECONDARY
PULV STN — SECONDARY, FINAL
PULV STN — FINES
PULV STN — STORAGE PILES
BUILDING STONE
DRYING, GRINDING
STORAGE
TERM ELEV
TERM ELEV
TERM ELEV
TERM ELEV
TERM ELEV
TERM ELEV
PRIM ELEV
PRIM ELEV
PRIM ELEV
XFER ELEV
XFER ELEV
XFER ELEV
XFER ELEV
PROVINCE
PROVINCE
PROVINCE
PROVINCE
PROVINCE
CLEANING
DRYING
HEADHOU3E
SHIP, RECEIVE
TRANSFER
TRIPPER
HEADHOUSE
SHIP, RECEIVE
TRANSFER
HEADHOUSE
SHIP, RECEIVE
TRANSFER
TRIPPER
PROC ELEV — CLEANING
PROC ELEV — MILLHOUSE
PROC ELEV — PRECLEAN
PROC ELEV — RECEIVING
COMPRESSOR ENGINES
COMPRESSOR TURBINES
COMPRESSORS IN-PLANT
HEATERS, BOILERS IN-PLANT
WOOD WASTE DISPOSAL.
CONTROLLED AIR
MULTIPLE CHAMBER
FILLING VEHICLE TANKS
REFINERY STORAGE, TRANSFER
SPILLAGE AT STATION
NATIONAL
PROVINCE
NATIONAL
PROVINCE
PROVINCE
i NATIONAL
> PROVINCE
121
-------
TABLE 6-3 (continued)
CATEGORY
NUMBER
BASE CATEGORY
SUB-CATEGORY
LEVEL
12904 DIESEL AND GASOLINE MARKETINS
12905 DIESEL AND GASOLINE MARKETING
12=706 DIESEL AND GASOLINE MARKETING
12907 DIESEL AND GASOLINE MARKETING
13001 SURFACE COATINGS
13002 SURFACE COATINGS
13101 LANDFILL SITES
13201 FERROUS FOUNDRIES
13202 FERROUS FOUNDRIES
13203 FERROUS FOUNDRIES
13204 FERROUS FOUNDRIES
13205 FERROUS FOUNDRIES
13701 DUST FROM UMPAVED ROADS
13702 DUST FROM UNPAVED ROADS
13703 DUST FROM IINPAVFD ROADS
13704 DUST FROM UNPAVED ROADS
1370F5 DUST FROM UNPAVCD ROADS
1370& DUST FROM UNPAVED ROADS
13901 CONCRETE BATCHINB
13902 CONCRETE BATCHING
14001 CIGARETTE SMOKING
14101 CRUDE OIL PRODUCTION
14102 CRUDE OIL PRODUCTION
14201 MINING AND ROCK QUARRYING
14202 MINING AND ROCK QUARRYING
14203 MINING AND ROCK QUARRYING
14204 MINING AND ROCK QUARRYING
14205 MINING AND ROCK QUARRYING
14401 TIRE WEAR
14501 PESTICIDE APPLICATION
14601 DIESEL-POWERED ENGINES
14602 DIESEL-POWERED ENGINES
14603 DIESEL-POWERED ENGINES
14604 DIESEL-POWERED ENGINES
14801 AGRICULTURE
14802 AGRICULTURE
14901 TAILING PILES
15001 CONSTRUCTION SITES
15002 CONSTRUCTION SITES
15003 CONSTRUCTION SITES
15004 CONSTRUCTION SITES
15005 CONSTRUCTION SITES
15101 GENERAL SOLVENT USE
15201 DUST FROM PAVED ROADS
15202 DUST FROM PAVED ROADS
STATION STORAGE, TRANSFER
TRANSFER TO CARS
VAPOR LOSS AT STATION
DIESEL EVAPORATION
INDUSTRIAL USE
TRADE, SALES USE
CUPOLA FURNACE
CUPOLA (•*•! REVERB) FURNACE
ELECTRIC ARC FURNACE
INDUCTION FURNACE
ROTARY OIL FURNACE
TRUCKS, EARTH ROADS
TRUCKS, TREATED GRAVEL
TRUCKS, UNTREATED GRAVEL
VEHICLES, EARTH ROADS
VEHICLES, TREATED GRAVEL-
VEHICLES, UNTREATED GRAVEL
FUGITIVE
EVAPORATION FROM SHIPS
EVAPORATION
CONCENTRATE DRYERS
CONCENTRATE TRANSPORT
OPEN PIT MINING
OVERBURDEN REMOVAL
UNDERGROUND MINING
PROVINCE
NATIONAL
PROVINCE
NATIONAL
NATIONAL
PROVINCE
PROVINCE
NATIONAL
) PROVINCE
PROVINCE
PROVINCE
PROVINCE
AGRICULTURAL
CONSTRUCTION
HEAVY DUTY VEHICLES
OTHER INDUSTRIAL ENGINES
WIND EROSION OF CROPLAND
FUGITIVE TILLING EMIS.
BRIDGES, TUNNELS, ROADS
HEAVY CONSTRUCTION
NON-RESIDENTIAL CONSTRUCTION
RESIDENTIAL CONSTRUCTION
WATER, SEWER, UTILITY
TRUCKS
OTHER VEHICLES
I PROVINCE
) PROVINCE
NATIONAL
PROVINCE
NATIONAL
) PROVINCE
122
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Temporal Allocation Factors for Utilities—State- and fuel-specific
temporal allocation factors were developed during the NECRMP study for power
plants within the Northeast Corridor (the region comprised of Connecticut,
Delaware, Maine, Maryland, Massachusetts, New Hampshire, New Jersey, New York,
Ohio, Pennsylvania, Rhode Island, Vermont, Virginia, the District of Columbia,
and West Virginia). For NAPAP Version 5.2, most of the NECRMP factors were
retained for sources inside the NECRMP region, while some were replaced by new
factors, derived from additional data. For sources outside the NECRMP region,
some factors were based on the original NECRMP figures, while most were
developed from additional data. Following is a description of the data
sources consulted for the utility point source temporal allocation factors.
Seasonal Factors—The fuel- and state-specific seasonal temporal factors
which were derived for the NECRMP study from power generation statistics
obtained from the U.S. Department of Energy's (DOE's) 1979 Data Reports were
retained for NAPAP Version 5.2 (U.S. Department of Energy, 1979). To avoid
the climatic bias of the northeast seasonal statistics, a uniform seasonal
temporal factor of 25 percent was assigned to all sources outside the NECRMP
region.
Daily Factors—The daily factors developed for the NECRMP study were
inadequate for use with the NAPAP Version 5.2 Inventory. Daily factors for
the entire nation were developed from weekly load cycle listings in the EPRI
Regional Systems (EPRI, 1981). These were calculated by normalizing the
averages of daily load statistics.
Hourly Factors—For the NECRMP study, fuel- and state-specific weekday
hourly temporal factors were calculated using hourly power plant fuel use data
previously collected by GCA for use in the Electric Power Research Institute's
(EPRI's) SURE Program (Klemm and Brennan, 1981). Included in this effort was
the acquisition of hourly fuel use data for approximately 300 power plants
within the SURE region for several study periods, at least one in each
season. Since the SURE study area included all of the NECRMP study area, and
the power plants contained in the hourly inventory represented approximately
90 percent of the utility SOX emissions in the SURE region, the SURE data
are believed to represent the best available data for determining hourly
emission patterns within the Northeast Corridor.
There were no SURE hourly fuel use data available for the states of
Rhode Island or Vermont. Weekday factors were assigned from the neighboring
states of Connecticut and New Hampshire, respectively. For sources outside
the NECRMP region, global fuel-specific hourly factors for weekdays were
calculated by taking averages of the NECRMP figures.
Because the temporal resolution of the NECRMP study was limited to hourly
emissions on a typical weekday, national Saturday and Sunday allocation
factors were developed for NAPAP Version 5.2 from the weekly load cycle
listings in the EPRI Regional Systems (EPRI, 1981). These were calculated by
normalizing the averages of hourly load statistics.
123
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Point Source Default Temporal Allocation Patterns—Most NAPAP point
source emission records contain operating rate data which make possible the
point-specific temporal allocation of emissions. These data consist of
information on:
I. Seasonal throughput percentages for each of the four seasons;
2. The number of days per week the process operates; and
3. The number of hours per day the process operates.
For all SCC for which specific temporal allocation factors were not
developed, these operating rate data were used to divide yearly emission
totals into subtotals for the 24 hours of a typical weekday, Saturday, and
Sunday in each of the four seasons. The algorithms used to allocate yearly
emissions were as follows:
Seasonal Patterns—The operating rate data contains specific information
on the percent of yearly emissions attributable to each of the four seasons.
Daily Patterns—The operating rate data provide information on the number
of days per week the process is in operation. This information is used to
allocate emissions among the days of the week according to the following
schedule:
If the process operates Then emissions are allocated
x days per week: as follows;
1 Saturdays only
2 Equally on Saturdays and Sundays
3-5 Weekdays only
6 Equally on weekdays and Saturdays
7 Equally on all days of the weefc.
Hourly Patterns—The operating rate data state how many hours per day the
process is in operation. Since this information does not allow precise
diurnal patterns to be defined, hourly patterns were created according to the
following simple algorithm:
• If the process operates ^>17 hours/day, the hourly allocation pattern
divides emissions equally among the 24 hours of the day;
• If the process operates I through 17 hours/day, hourly allocation
jfactors are made 0 for the hours from midnight to 7 A.M. Total
daily emissions are divided evenly among the following x hours,
where x = the number of hours the process operates (for example, if
124
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the process operates 8 hours/day, the 8 hourly factors from 7 A.M.
through 3 P.M. would all equal 0.125). The remaining hourly factors
(filling out the 24 hours of the day) are all set equal to zero.
Canadian Point Source Temporal Allocation Factors—
Temporal allocation factors for Canadian point sources have not been
developed by NAPAP, and the emissions records for Canadian point sources do
not contain operating rate data. As a result of this lack of temporal
profiles and operating rate data, most Canadian point sources have been
assigned a default operating pattern which assumes: (1) equal emissions in
all seasons, (2) equal emissions for all days of the week, and (3) constant
emissions throughout the 24 hours of ea.ch day. Canadian point source utility
emissions, however, were allocated using the appropriate U.S. point source
utility temporal allocation factors, whose development is described above.
File Creation and Quality Assurance
Extensive effort was put into the task of creating the temporal
allocation factor files and into assuring the quality of these data. A
variety of data entry, data modification, and quality assurance software was
written which will speed the process of incorporating further improvements to
the temporal allocation factors for future NAPAP Inventory efforts.
The U.S. temporal allocation factors were put into FREDS format in one of
two ways:
• Factors which were adapted from earlier inventory efforts, and which
therefore already existed in computer data files, were reformatted
to the required input format; and
• Factors which were the product of new research conducted for this
NAPAP effort were put into data files through a system of data entry
programs designed for this effort.
The Canadian factors were not supplied on a magnetic medium, but were
extracted from a written report. The data entry programs written to accept
the U.S. temporal allocation factors were modified slightly to allow
straightforward creation of data files for the Canadian factors.
The temporal allocation factors were put through a series of quality
assurance checks before further processing:
• Files were scanned following data reformatting or transferring to
insure that no errors were made during transcription. All data
entry and data manipulation software was checked to be sure that all
factors summed to the correct values;
• Printouts similar to those presented in Appendix C were created and
visually scanned to be sure that all temporal allocation factor
patterns were reasonable. As an example, this process revealed that
the NAPAP Version 4.2 factors for Industrial Fuel Use emissions
allocated no emissions to Sundays; this omission seemed unusual, so
further research was initiated to reveal what portion of weekly
emissions should properly be allocated to this day;
125
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• When the factors were in final form for input into the FREDS system,
a statistical check was made to find outliers. Software was written
which scanned similar sets of factors (for example, factors for the
Residential Heating emissions category for all 48 States) and
calculated the mean value for each factor. The factors were then
scanned a second time, and all factors more than two standard
deviations from the mean value were pinpointed for explicit
examination. When such "abnormal" factors were located, the
original data sources were re-examined to assure that no errors in
calculation or transcription had been made.
File Format for Input to the FREDS System—
Table 6-4 displays a portion of the U.S. temporal allocation factors as
they are formatted for input into the FREDS system. Separate files have been
created for the Canadian and the U.S. factors. One line of data contains
seasonal, daily, and hourly factors for a single emissions category, for a
single state or province (if applicable), for a single day. There are
therefore 12 lines of data for each emissions category for each State or
province—one line each for a weekday, a Saturday, and a Sunday in each of the
four seasons.
SPATIAL ALLOCATION FACTOR DEVELOPMENT
Introduction
In the NAPAP emissions records, area source emissions are inventoried by
county; for modeling applications of the NAPAP data, area source emissions
must be allocated to individual grid cells. The allocation of county-wide
area source emissions to grid cells is accomplished by the FREDS Spatial
Allocation Module, and depends on the existence of a set of spatial allocation
factors. This section describes the development and application of these
factors.
The NAPAP Version 5.2 grid system is comprised of 63,000 individual grid
cells (210 rows by 300 columns), each 1/6° latitude by 1/4° longitude
(approximately 20 km x 20 km), extending from 50° to 125° west longitude and
from 25° to 60° north latitude. The grid system covers the continental
United States and Canada south of the 60th parallel (the southern border of
the Yukon and Northwest Territories). Grid cells are assigned numbers on a
Cartesian coordinate system, with row numbers increasing from south to north
and column numbers increasing from west to east. Thus, the cell at the
southwestern corner of the grid is denoted (1,1); the cell at the northeastern
corner is denoted (300,210). Latitude/longitude data can be converted to
row/column format using the following equations:
Column = ((125 - longitude) x 4) + 1
Row = ((latitude - 25) x 6) + 1
where the numbers 4 and 6 represent the number of grids per degree longitude
and latitude, respectively. The resultant integer parts are the row and
column; fractional parts are truncated.
126
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TABLE 6-4. SAMPLE DISPLAYING FORMAT OF U.S. AREA SOURCE TEMPORAL ALLOCATION FACTOR RECORDS
f
/
24 Hourly Multipliers
10
11
12
"3
185
185
185
452
452
452
333
333
333
110
110
110
110
110
110
• no
110
110
67 67 67 83 83 83100100100 43 43 43 0 0
67 67 67 83 83 83100100100 43 43 43 0 0
67 67 67 83 83 83100100100 43 43 43 0 0
47 47 47 53 53 53 53 53 53 40 40 40 30 30
47 47 47 53 53 53 53 53 53 40 40 40 30 30
47 47 47 53 53 53 53 53 53 40 40 40 30 30
77 77 77 86 86 86 77 77 77 20 20 20 0 0
77 77 77 86 86 86 77 77 77 20 20 20 0 0
77 77 77 86 86 86 77 77 77 20 20 20 0 0
0 0 0 0 0 0 0 43 43 43
0 0 0 0 0 0 0 43 43 43
0 0 0 0 0 0 0 43 43 43
30 26 26 26 40 40 40 47 47 47
30 26 26 26 40 40 40 47 47 47
30 26 26 26 40 40 40 47 47 47
0 0 0 0 20 20 20 56 56 56
0 0 0 0 20 20 20 56 56 56
0 0 0 0 20 20 20 56 56 56
-------
For each area source emissions category, the purpose of the spatial
allocation factors is to allocate emissions for each county among all grid
cells which contain a portion of the county. Since the actual areal
distribution of emissions within a county is unknown, emissions are assumed to
be distributed according to the known distribution of a surrogate indicator.
For example, the distribution of housing within a county should be an accurate
surrogate indicator for residential fuel use emissions; if 50 percent of
County X's housing were located in Grid Cell Y, then 50 percent of County X's
residential fuel emissions should be allocated to Grid Cell Y.
An extensive development effort for the spatial allocation factors took
place for the NAPAP Version 4.2 Inventory; that development effort is
summarized here. For NAPAP Version 5.2, effort has been focused on assuring
the quality and completeness of the factors.
The goal of the spatial allocation factor development effort was to
create as many surrogate values as possible for each county in the NAPAP study
area to allow the user maximum flexibility in assigning county level emissions
to specific grid cells. A total of 14 surrogate indicators have been
developed, based on the areal distribution of housing, population, land area,
and 11 land use categories. After the distribution of the surrogate
indicators had been calculated and allocated to grid cells, county level area
source emissions could be spatially distributed by matching area source
emission categories to the most appropriate surrogate indicators.
Spatial Allocation Factor Development
The two major data sources used to compile the spatial allocation factors
were:
1. 1980 Bureau of the Census population and housing data, and
2. Land use classification data derived from LANDSAT satellite imagery.
Spatial allocation factors were developed separately from the
housing/population data and the LANDSAT data during the NAPAP Version 4.2
inventory effort. These separate sets of factors were then merged to create
the single spatial allocation factor file used for NAPAP Version 4.2. This
file served as the starting point for the quality assurance and reformatting
performed for NAPAP Version 5.2.
The following discussion of the development of spatial allocation factors
applies only to factors for the U.S. area source emission categories. Because
of the different method of compilation of the Canadian area source inventory,
and a lack of data on Canadian land use comparable to the U.S. LANDSAT data,
no spatial allocation factors like those discussed below exist for the
Canadian area source emissions. The allocation of Canadian area source
emissions to individual grid cells is discussed under a separate heading.
Population and Housing Allocation Factors—
U.S. Bureau of the Census data contain information on the distribution of
housing and population at several levels of detail more precise than
128
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whole-county totals, including (where applicable) township, place, tract,
block, and election district. To make possible the spatial allocation of area
source emission categories for which housing or population is an appropriate
surrogate (e.g., residential heating emissions), NAPAP obtained and adapted
these refined Census data, which are available as part of EPA's STF3A Census
tapes.
These data allowed the resolution of population and housing patterns to
the subcounty level; based on this resolution, a match based on latitude and
longitude was made between the subcounty population and housing patterns and
individual grid cells, and the allocation of county-wide population and
housing to grid cells was completed.
The computer programs written to accomplish this allocation were designed
to accommodate anomalies in the Census or emissions data. For example, some
localities repress portions of their housing and population data to maintain
confidentiality, while the commonwealth of Massachusetts maintains emissions
data by AQCR instead of by county. Such problems were overcome after
discussion within NAPAP had yielded consensus on appropriate solutions.
Land Use Spatial Allocation Factors—
The development of the spatial allocation factors based on land use
patterns proceeded in three steps:
1. Allocation of land use categories to individual grid cells;
2. Determination of the area of each county located in each grid cell;
3. Calculation of spatial allocation factors based on land use
categories and county areas in each grid cell.
This process is portrayed in Figure 6-1.
Allocation of Land Use Categories to Grid Cells—Land use data were
obtained through the EPA/ASRL's Meteorology and Assessment Division and
consist of 10 land use and land cover classification percentages for each
NAPAP grid cell. The data were developed under EPA contract by Lockheed
Engineering and Management Services Company's Remote Sensing Laboratory using
LANDSAT mosaic images covering the periods 23 July through 31 October 1972,
and 1 January through 31 March 1973. Total land use and land cover in each
grid cell was divided into the following classifications:
• Urban Land • Mixed Forest Land (including
forested wetlands)
• Agricultural Land • Water
• Rangeland • Barren Land
• Deciduous Forest Land • Nonforested Wetland
• Coniferous Forest land • Mixed Agricultural Land and
Rangeland
129
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/ COUNTY
BOUNDARY
V DEFINITIONS
GRID
DEFINITIONS
:ONS )
/ COUNTY-GRID
I RELATIONSHIPS
LANDSAT
LAND USE
DATA
V
/ LAND USE
ALLOCATION
V FACTORS
SORT BY
GRID-COUNTY
SORTED
/ LAND USE \
\ALLOCATION I
V FACTORS /
Figure 6-1. Development of land use allocation factors.
130
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Two additional categories — Composite Forest (the sura of Coniferous
Forest, Deciduous Forest, and Mixed Forest Land) and Total Land Area (the sum
of all classifications minus area covered with water) — were calculated by
NAPAP.
Prior to further processing, these data are formatted as a single data
file with one record per grid cell. Each record documents the fraction of the
grid cell covered by each of the 12 land use categories. These fractions sum
to 1 for the 10 LAND SAT categories; the Total Land Area category and Composite
Forest fractions both have values less than or equal to one.
Determination of Grid Cell/County Areas Relationships — Since land use
classification data were available for each grid cell, while emissions data
are stored for individual counties, it was necessary to allocate the total
area of each county to all of the grid cells in which a portion of the county
is located. EPA/ASRL developed the software to perform this match.
Very simply, this software takes a file which defines the boundaries of
each county in "the United States and overlays it on the NAPAP grid system.
The software then calculates the fraction of each county located in each grid
cell which the county overlaps. Figure 6-2 illustrates this process for a
single grid cell which contains portions of three counties. For this grid
cell, the ASRL software would calculate the proportion of each of Counties A,
B, and C located in the cell as follows:
County Total Area Area in Cell Fraction in Cell
A 500 150 0.30
B 1,000 50 0.05
C 800 200 0.25
The fractional totals calculated for each county must sum to 1; the
fractional totals for each grid cell do not have to sum to a particular
number. The output of this software is a single file, sorted by grid cell
number, which contains an identification code for each county overlapping the
grid cell, and the fraction of each auch county located in the cell.
Calculation of Spatial Allocation Factors — The final step in the
calculation of spatial allocation factors based on the LAND SAT land use
categories is to match the grid cell/land use allocation pattern with the grid
cell/county pattern. For each land use classification in each county
overlapping each grid cell, the spatial allocation factor is calculated as
follows :
(A .
SPAFCT . = - —
1
where: SPAFCTp-. = The spatial allocation factor for County C, land use
Type S, and grid i
131
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OVERLAP ~
COUNTY A / GRID CELL X
AREA - 150
OVERLAP
COUNTY C / GRID CELL
AREA = 200
OVERLAP
COUNTY B / GRID CELL X
AREA - 50
Figure 6-2. Example of county to grid cell areal relationship.
132
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AC^ = The portion of County C that falls within grid i
Ag£ = The portion of grid i with land use type S
n = The total number of grids covering County C
For example:
Assume 80 percent of County A falls within ftrid 1 and 20 percent within
grid 2. Agricultural land comprises 10 percent of grid I and 75 percent of
grid 2. The distribution of emissions from pesticide application, using
agricultural land use as the surrogate indicator, would be calculated:
SPAFCT = (0.80)(0.10) „ 35
b grid 1 [(0.80X0.10) + (0.20X0.75)]
SPAFCT _ (0.20X0.75) 0 b5
SPAF grid 2 [(0.80)(0.10) + (0.20)(0.75)] U' "
In the above example, 65 percent of County A's emissions from pesticide
application are assigned to grid 2, even though more of County A falls within
grid 1, because grid 2 has much more agricultural land than grid 1. One
limitation of this methodology is that the grids are necessarily assumed to be
homogeneous in terms of land use. In the previous example, 10 percent of the
land in grid 1 was agricultural and, therefore, 10 percent of the portion of
County A that falls within grid 1 is assumed to be agricultural, even if only
a fraction of grid 1 covers County A.
The file output from this process contains one record for each county
overlapping each grid cell, and 12 spatial allocation factors per record (one
factor for each of the 10 LANDSAT land use classifications and one each for
the two composite classifications devised by NAPAP). This file is sorted by
grid cell number, then merged with the population and housing factors created
as described above to yield the complete set of spatial allocation factors
suitable for further processing.
Allocation of Canadian Area Source Emissions to Grid Cells—
The Canadian area source emissions files contain data already allocated
to individual grid cells (unlike the U.S. emissions data files, in which
emissions are initially allocated to counties). Nothing comparable to the
U.S. LANDSAT data exists for Canada, nor does the Canadian government maintain
statistics as detailed as the U.S. Census data on areal distribution of
housing; the best surrogates available as a basis to distribute Canadian area
source emissions are various categories of population.
The Canadian Land Directorate provided available allocation data for
the 20 x 20 kilometer NAPAP grids in each province in Canada. The Land
Directorate was responsible for providing Environment Canada with population,
employment, and other data on a grid basis to allocate province-level
emissions to the 127 x 127 kilometer grid system used by the Canadians.
Environment Canada manually developed additional allocation factors to
supplement those generated by the Land Directorate. The factors used by
Environment Canada to allocate each area source category were applied to the
133
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NAPAP grid in Canada to the extent possible. However, the allocation
parameters developed manually by Environment Canada were not considered.
Allocation factors provided by the Land Directorate were used to allocate all
area source categories including those for which Environment Canada applied
manually-developed factors. Table 6-5 identifies the allocation factors
provided and shows which factor was used to allocate each of the area source
categories.
Quality Assurance and File Formatting
Before the spatial allocation factors were processed, they were subjected
to quality assurance checks. These checks confirmed: (1) that factors summed
to 1 (where appropriate) for each county, and (2) that a nonzero surrogate
factor existed for each land use classification in each grid cell.
The first check assured that all emissions assigned a given surrogate
would be allocated to grid cells. Without this QA check, if the factors for
Agricultural Land, County X, summed to only 0.5, then only half of all
emissions assigned Agricultural Land as a spatial allocation surrogate would
be allocated to the grid cells covering this county—after processing, half of
these emissions would have "disappeared". Conversely, if the factors summed
to a value greater than 1, emissions would appear to increase. This QA check
summed the allocation factors for each surrogate in each county; if they did
not sum to 1, the nonzero factors were normalized to yield this sum.
The second QA check verified that a nonzero factor existed for each
spatial allocation surrogate in each county. Another example will highlight
the importance of this check: if the LANDSAT data indicated that there was no
Agricultural Land in County X, yet the NAPAP Inventory for County X contained
emissions for an emission category for which Agricultural Land was the spatial
allocation surrogate, these emissions would "disappear" during processing—the
spatial allocation factor for this emissions category in County X would
equal 0. To insure that all area source emissions are allocated to grid
cells, all factors which equalled 0 were set equal to the spatial allocation
factor for population.
Assignment of Spatial Allocation Surrogates
To accomplish the allocation of area source emissions to individual grid
cells, each area source emissions category must be matched with one of the
spatial allocation surrogates. For example, if Residential Heating emissions
are to be allocated to grid cells on the basis of housing patterns, a
mechanism must exist to instruct the FREDS Spatial Allocation Module to make
this match.
A surrogate factor selection file has been developed to perform this
function. Based on discussion within NAPAP, each area source emissions
category has been assigned to one of the 14 spatial allocation surrogates.
This file is an independent input, so that assignments can be easily changed
as new emissions categories are added, or as the development of new surrogates
makes the revision of these assignments desirable. The NAPAP Version 5.2
surrogate factor assignments for the U.S. area source emission categories are
shown in Table 6-6.
134
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TABLE 6-5. ALLOCATION FACTORS FOR CANADIAN AREA SOURCES
Allocation factor
Categories allocated
Population
Oil Dwellings
Gas Dwellings
Total Dwellings
Industrial Labor Force
Commercial Labor Force
Agricultural Labor Force
Mining Labor Force
Gasoline-powered motor vehicles, off-highway
mobile sources, non-highway use of gasoline, dry
cleaning, sand and gravel processing, electric
power fuel combustion, asphalt production, stone
processing, clay products manufacture, refuse
incineration, diesel and gasoline marketing,
application of surface coatings, landfill sites,
concrete batching, cigarette smoking, tire wear,
diesel-powered engines, construction sites,
general solvent use, and dust from paved roads.
None.
None.
Structural fires, residential fuel combustion,
fuelwood combustion.
Industrial fuel combustion, ferrous foundries,
plastics fabrication.
Commercial fuel combustion, bakeries.
Fertilizer application, dust from unpaved roads,
pesticide application, agricultural tilling and
wind erosion, grain handling and milling.
Forest fires, slash burning, coal industry, wood
industry, natural gas processing, wood waste
disposal, crude oil production, mining and rock
quarrying, tailing piles.
135
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TABLE 6-6. SPATIAL ALLOCATION FACTOR SURROGATES FOR NAPAP
VERSION 5.2 AREA SOURCE EMISSIONS CATEGORIES
CAT.
ID
SURROGATE
ID
SURROGATE
INDICATOR
EMISSIONS CATEGORY
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
3
3
2
3
3
14
14
2
3
14
14
Housing
Housing
Housing
Housing
Housing
Housing
Urban Land
Urban Land
Urban Land
Urban Land
Urban Land
Urban Land
Urban Land
Urban Land
Urban Land
Urban Land
Urban Land
Urban Land
Urban Land
Urban Land
Housing
Urban Land
Urban Land
Housing
Urban Land
Urban Land
Land Area
Land Area
Housing
Urban Land
Land Area
Land Area
Residential Fuel -
Residential Fuel -
Residential Fuel -
Residential Fuel -
Residential Fuel -
Residential Fuel -
Commercial/Institutional Fuel
Commercial/Institutional Fuel
Commercial/Institutional Fuel
Commercial/Institutional Fuel
Commercial/Institutional Fuel
Commercial/Institutional Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
Incineration --
Incineration --
Incineration --
Open Burning --
Open Burning --
Open Burning --
Light Duty Gas Vehicles
Light Duty Gas Vehicles
Light Duty Gas Vehicles
Light Duty Gas Vehicles
Medium Duty Gas Vehicles
Medium Duty Gas Vehicles
Anthracite Coal
Bituminous Coal
Distillate Oil
Residual Oil
Natural Gas
Wood
Anthracite Coal
Bituminous Coal
Distillate Oil
Residual Oil
Natural Gas
Wood
-- Anthracite Coal
-- Bituminous Coal
-- Coke
-- Distillate Oil
-- Residual Oil
-- Natural Gas
-- Wood
-- Industrial Process Gas
Residential
Industrial
Commercial/Institutional
Residential
Industrial
Commerical/Institutional
Limited Access
Rural
Suburban
Urban
Limited Access
Rural
-------
TABLE 6-6 (continued)
CAT.
ID
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
SURROGATE
ID
2
3
14
14
2
3
14
14
14
2
3
14
3
1
1
1
1
1
1
1
N.A.
1
14
N.A.
N.A.
N.A.
N.A.
13
13
4
N.A.
2
SURROGATE
INDICATOR
Housing
Urban Land
Land Area
Land Area
Hous ing
Urban Land
Land Area
Land Area
Land Area
Housing
Urban Land
Land Area
Urban Land
Population
Population
Population
Population
Population
Population
Population
N.A.
Population
Land Area
N.A.
N.A.
N.A.
N.A.
Composite Forest
Composite Forest
Agricultural Land
N.A.
Housing
EMISSIONS CATEGORY
Medium Duty Gas Vehicles -- Suburban
Medium Duty Gas Vehicles -- Urban
Heavy Duty Gas Vehicles -- Limited Access
Heavy Duty Gas Vehicles -- Rural
Heavy Duty Gas Vehicles -- Suburban
Heavy Duty Gas Vehicles -- Urban
Off -Highway Gas Vehicles
Heavy Duty Diesel Vehicles -- Limited Access
Heavy Duty Diesel Vehicles -- Rural
Heavy Duty Diesel Vehicles -- Suburban
Heavy Duty Diesel Vehicles -- Urban
Off -Highway Diesel Vehicles
Railroad Locomotives
Aircraft -- Military
Aircraft -- Civil
Aircraft -- Commercial
Vessels -- Coal-Powered
Vessels -- Diesel
Vessels -- Residual Oil
Vessels -- Gasoline
BLANK (formerly Solvents Purchased)
Gasoline Marketed
Unpaved Roads
Unpaved Airport LTO's (NO EMISSIONS DATA)
Construction Sites (NO EMISSIONS DATA)
Miscellaneous Wind Erosion (NO EMISSIONS DATA)
Agricultural Tilling (NO EMISSIONS DATA)
Forest Fires
Managed Burning
Agricultural Field Burning
Orchard Heaters (NO EMISSIONS DATA)
Structural Fires
-------
TABLE 6-6 (continued)
CO
00
CAT.
ID
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
SURROGATE
ID
— — — •.— . . •- ;
N.A.
N.A.
N.A.
N.A.
N.A.
N.A.
4
4
4
4
4
4
4
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
SURROGATE
INDICATOR
EMISSIONS CATEGORY
N.A.
N.A.
N.A.
N.A.
N.A.
N.A.
Agricultural Land
Agricultural Land
Agricultural Land
Agricultural Land
Agricultural Land
Agricultural Land
Agricultural Land
Population
Population
Population
Population
Population
Population
Population
Population
Population
Population
Population
Population
Population
Population
Population
Population
Population
Population
Population
-- Beef Cattle
-- Dairy Cows
(UNFILLED)
(UNFILLED)
(UNFILLED)
(UNFILLED)
(UNFILLED)
(UNFILLED)
Manure Field Application
Manure Field Application
Manure Field Application -- Hogs and Pigs
Manure Field Application — Broilers
Manure Field Application -- Other Chickens
Anhydrous NH3 Fertilizer Application
Beef Cattle Feed Lots
Degreasing
Drycleaning
Graphic Arts
Rubber and Plastic Manufacturing
Architectural Coating
Auto Body Repair
Motor Vehicle Manufacturing
Paper Coating
Fabricated Metals
Machinery Manufacturing
Furniture Manufacturing
Flat Wood Products
Other Transportation Equipment Manufacturing
Electrical Equipment Manufacturing
Ship Building and Repair
Miscellaneous Industrial Manufacturing
Miscellaneous Industrial Solvent Use
Miscellaneous Non-Industrial Solvent Use
Utility Area Sources -- Coal Fired Plants
-------
TABLE 6-6 (continued)
CAT. SURROGATE SURROGATE
ID ID INDICATOR
97
98
99
1
1
3
Population
Population
Urban Land
EMISSIONS CATEGORY
Utility Area Sources
Utility Area Sources
Minor Area Sources
--Oil Fired Plants
-- Natural Gas Fired Plants
U!
-------
SPECIATION FACTOR DEVELOPMENT
Introduction
The NAPAP Version 5.0 emissions records contain emissions data for
11 pollutant classes:
NOX S02
S04 Pb
CO HC1
HF NH3
TSP VOC
THC
For three of these classes—NOX, TSP, and THC—a further subclassification
is performed for the NAPAP modeling inventories. NOX emissions are
allocated between NO and N02? TSP emissions are allocated among calcium
(Ca), potassium (K), magnesium (Mg), sodium (Na), and "other" species. THC
emissions are allocated among up to 30 classes based on photochemical
reactivity (28 of these classes are utilized in NAPAP Version 5.2; 10 are used
in Version 5.3; see Table 6-7). For TSP emissions, only about 10 percent of
point source SCCs are allocated among the five cation species; the balance of
point source TSP emissions and area source TSP emissions are not speciated in
NAPAP Version 5.2 or 5.3.
Speciation Methodology
The speciation requirement for hydrocarbon emissions can change depending
on the modeling chemistry used in a particular application of an emissions
data set. Therefore, it was decided during the development of the NECRMP
Inventory in the early 1980s (the speciation methodology adapted for NAPAP) to
make hydrocarbon speciation as flexible as possible. This objective was
achieved by creating an independent program (PSPLIT) to compute factors which
can be used to disaggregate hydrocarbon emissions into selected groups of
compounds.
PSPLIT was primarily developed to automate a method for generating
hydrocarbon speciation factors for any specified chemistry mechanism or
species classification scheme. It also provides an effective means of
incorporating revised species profiles for each source type.
The first step in using the flexible speciation capabilities of PSPLIT is
to code a set of "species profiles," each of which provides a breakdown of TriC
emissions to a typical set of component species. In these profiles, each
hydrocarbon species is defined by its Storage and Retrieval of Aerometric Data
140
-------
TABLE 6-7. DEFINITION OF CLASSES FOR HYDROCARBON SPECIATION,
VERSIONS 5.2 AND 5.3
REACTIVITY CLASSES FOR 1980 NAPAP INVENTORY VERSION 5.2
Class Number Class Name Class SAROAD Code
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
REACTIVITY
Class Number
01
02
03
04
05
06
07
08
09
10
11-30
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
2,3-DIMETHYLBUTANE
PENTANE
ISO-PENTANE
OTHER ALKANES
ETHYLENE
PROPYLENE
Not Used
ISO-BUTENE
TRANS -2-BUTENE
OTHER ALKENES
BENZENE
TOLUENE
XYLENES
ETHYL BENZENES
OTHER AROMATICS
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
OTHER ALDEHYDES
ACETONE
OTHER KETONES
FORMIC ACID
ACETIC ACID
OTHER ORGANIC ACIDS
Not Used
CLASSES FOR 1980 NAPAP
Class Name
OLEFINS
PARAFFINS
TOLUENE
XYLENE
FORMALDEHYDE
OTHER ALDEHYDES
ETHYLENE
NON-REACTIVES
ISOPRENE
METHANE
Not Used
141
:s ==sss:ssis±=sss=s:s:ss='
43201
43202
43204
43212
43214
43244
43220
43221
43299
43203
43205
-
43215
43216
43298
45201
45202
45102
45203
45999
43502
43503
43504
43599
43551
43598
43403
43404
43499
-
INVENTORY VERSION 5.3
Class SAROAD Code
43298
43199
45202
45102
43502
43511
43203
43899
43243
43201
-
-------
(SAROAD) Code, its molecular weight, and its percentage contribution (by
weight) to total profile THC emissions. These profiles are independent of any
reactivity scheme. Each species is then matched to a reactivity class using a
Species/Class File, allowing the conversion of species profiles (which define
emissions for a given SCO to a reactivity class profile required by users of
the NAPAP emissions data. Manipulation of the class assignments in the
Species/Class file allows users to modify the definitions of reactivity
classes to fit particular modeling requirements.
The creation of the Hydrocarbon Splits file, then, requires three
independent input files:
I. An SCC/Profile file, which assigns each SCC to a species profile;
2. A Species/Profile file, which documents the relative contribution of
different individual SAROAD species to each species profile; and
3. A Species/Class file, which assigns each SAROAD species to one of up
to 30 photochemical classes.
Hydrocarbon speciation then proceeds as follows:
1. The Species/Profile file is merged with the Species/Class file; the
result is a set of profiles defined by the relative contribution of
each photochemical class to total profile composition; and
2. The Class/Profile matches produced in Step 1 are merged with the
SCC/Profile file; the result is an output file in which each SCC is
matched with the relative contribution of each photochemical class
to total SCC THC emissions by the use of mole factors. These
factors are in moles per kilogram, and thus when multiplied by total
hydrocarbon emissions for a given SCC, they will yield moles of
hydrocarbon in each class.
SCC/Profile and Species/Profile assignments for Version 5.2 are provided
in Appendix E. Table 6-8 presents the species/class assignments for
Version 5.2, in which each species is assigned to one and only one reactivity
class. In Version 5.3, species are assigned to classes on the basis of carbon
bond structures rather than photochemical reactivity, and since it is possible
for a single compound to have bonds of different character, a species can be
apportioned on a percentage basis to more than one class. A list of 5.3
species and their class assignments is presented in Table 6-8. The
species/class matrix is filled with "carbon numbers," used to determine mole
factors for the respective class. For example, assume that a hypothetical
emissions profile contained only one species, 1-heptene. Given a molecular
weight of 98.19 grams/mole and a weight fraction of 1.0:
1*° x 1000 gm/kg = 10.18 moles/kg
98.19 gm/mole
This result is multiplied by the carbon numbers in the table. Since 1-heptene
has an olefin carbon number of 1 and a paraffin carbon number of 5, the
resultant mole factors are:
142
-------
TABLE 6-8. HYDROCARBON SPECIES/CLASS ASSIGNMENTS FOR
i960 NAPAP INVENTORY VERSIONS 5.2 AND 5.3
HYDROCARBON SPECIES
UNIDENTIFIED HYDROCARBONS
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
ISOMERS OF TRIDECANE
ISOMERS OF DODECANE
ISOMERS OF TETRADECANE
ISOMERS OF PENTADECANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
MINERAL SPIRITS
LACTOL SPIRITS
ISOMERS OF BUTENE
ISOMERS OF PENTENE
ISOMERS OF PENTANE
TERPENES
METHANE
ETHANE
ETHYLENE
PROPANE
PROPYLJENE
ACETYLENE
CYCLOPROPANE
PROPADIENE
METHYLACETYLENE
N-BUIANE
BUTENE
ISOBUTANE
ISOBUTYLENE
1,3-BUTADIENE
ETHYLACETYLENE
N-PENTANE
ISOPENTANE
3-METHYL-1-BUTENE
1-PENTENE
CIS, 2-PENTENE
2-METHYL,2-BUTENE
N-HEXANE
N-HEFTANE
N-OCTANE
N-NONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
1-HEXENE
2,4, DIMETHYL PENTANE
SAROAD
CODE
========
43000
43105
43106
43107
43108
43109
43110
43111
43112
43113
43114
43115
43116
43117
43118
43119
43120
43121
43122
43123
43201
43202
43203
43204
43205
43206
43207
43208
43209
43212
43213
43214
43215
43218
43219
43220
43221
43223
43224
43227
43228
43231
43232
43233
43235
43238
43241
43242
43245
43247
5.2
CLASS
=;===;: = =
09
09
09
09
09
09
09
09
09
09
09
09
09
09
09
09
15
15
09
15
01
02
10
03
11
09
09
15
15
04
15
05
13
15
15
07
08
15
15
15
15
09
09
09
09
09
09
09
15
09
5.3
CLASS: 1 2
====================,
2
6
7
8
9
10
11
13
12
14
15
7
8
9
6
8
1
5
1 8
0.01
0.4
1.5
1 1
1
3
1.5
4
1 2
4
1
1
4
5
5
1 3
1 3
1
3
6
7
8
9
10
11
5
1 4
7
5.3 CARBON NUMBER/CLASS ASSIGNMENTS
345678
10
0.99
1.6
1.5
1.5
143
-------
TABLE 6-8 (continued)
HYDROCARBON SPECIES
CYCLOHEXANE
N-DODECANE
N-TRIDECANE
N-IETRADECANE
N-PENTADECANE
METHYLCYCLOHEXANE
MEIHYLCYCLOPENTANE
1-HEPTENE
1-OCTENE
3,3 DIMETHYL, 1-PENTENE
N-HEXADECANE
N-HEPTADECANE
N-OCXADECANE
N-NONADECANE
N-EICOSANE
N-HENEICOSANE
N-DOCOSANE
C8 OLEFIN UNK
METHYL ALCOHOL
ETHYL ALCOHOL
N-PROPYL ALCOHOL
ISOPROPYL ALCOHOL
N-BUTYL ALCOHOL
ISOBUTYL ALCOHOL
BUTYL CELLOSOLVE
TERT-BUTYL ALCOHOL
METHYL CELLOSOLVE
CELLOSOLVE
DIACETONE ALCOHOL
ETHYL ETHER
GLYCOL ETHER
GLYCOL
PROPYLENE GLYCOL
ETHYLENE GLYCOL
TETRAHYDROFURAN
ACETIC ACID
METHYL ACETATE
ETHYL ACETATE
PROPYL ACETATE
N-BUTYL ACETATE
ETHYL ACRYLATE
CELLOSOLVE ACETATE
ISOPROPYL ACETATE
METHYL AMYL ACETATE
ISOBUTYL ACETATE
DIMETHYLFORMAMIDE
ISOBUTYL ISOBUTYRATE
2-ETHOXYETHYL ACETATE
FORMALDEHYDE
ACETALDEHYDE
SAROAD
CODE
43248
43255
43258
43259
43260
43261
43262
43264
43265
43268
43281
43282
43283
43284
43285
43286
43287
43290
43301
43302
43303
43304
43305
43306
43308
43309
43310
43311
43320
43351
43367
43368
43369
43370
43390
43404
43432
43433
43434
43435
43438
43443
43444
43445
43446
43450
43451
43452
43502
43503
5.2
CLASS
09
09
09
09
09
09
09
15
15
15
09
09
09
09
09
09
09
15
09
09
09
09
09
09
09
09
09
09
26
09
09
09
09
09
09
28
29
29
29
29
15
09
09
09
09
24
09
09
21
22
5.3 5.3 CARBON NUMBER/CLASS ASSIGNMENTS
CLASS: 123456789 10
6
12
13
14
15
7
6
1 5
1 6
5
16
17
18
19
20
21
22
1 6
1
2
3
3
2 1
4
4 1
4
1 1
2 1
4 1
2 1
2
2
3
2
3 1
1 1
3
3 1
4 1
5 1
1 2
3 11
5
8
6
3
6 1
4 1
1
1
144
-------
TABLE 6-8 (continued)
HYDROCARBON SPECIES
BUTYRALDEHYDE
ALDEHYDE
ACETONE
METHYL ETHYL KETONE
METHYL N-BUTYL KETONE
METHYL ISOBUTYL KETONE
CYCLOHEXANONE
ETHYLENE OXIDE
PROPYLENE OXIDE
ACETONITRILE
ACRYLONITRILE
METHYLAMINE
ETHYLAMINE
TRIMETHYLAMINE
METHYL CHLORIDE
DICHLOROMETHANE
CHLOROFORM
CARBON TETRABROMIDE
TRICHLORO-FLUOROMETHANE
ETHYL CHLORIDE
1 , 1 jDICHLOROETHANE
1,1,1,-TRICHLOROETHANE
ETHYLENE DICHLORIDE
PERCHLOROETHYLENE
METHYLENE BROMIDE
1 , 1 , 2 -TRI CHLOROETHANE
TRICHLOROTRIFLUOROETHANE
TRIMETHYLFLUOROSILANE
DICHLORODIFLUOROMETHANE
TRICHLOROEIHYLENE
VINYL CHLORIDE
PRIM. & SEC-ALKYL BENZENES
NAPHTHA
ISOMERS OF XYLENE
DIMETHYLETHYLBENZENE
ISOMERS OF ETHYLTOLUENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF DIETHYLBENZENE
ISOMERS OF TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
BENZENE
TOLUENE
ETHYLBENZENE
ORTHO XYLENE
1,3 DIMETHYLBENZENE
1 , 3 , 5-TRIMETHYLBENZENE
M-ETHYLTOLUENE
N-BUTYLBENZENE
TERT-BUTYLBENZENE
SEC-BUTYLBENZENE
SAROAD
CODE
43510
43513
43551
43552
43559
43560
43561
43601
43602
43702
43704
43720
43721
43740
43801
43802
43803
43807
43811
43812
43813
43814
43815
43817
43819
43820
43821
43822
43823
43824
43860
45100
45101
45102
45103
45104
45105
45106
45107
45108
45201
45202
45203
45204
45205
45207
45212
45214
45215
45216
5.2 5.3
CLASS CLASS:
24
24
25
26
26
26
26
09
09
15
15
09
09
09
09
09
09
09
09
09
09
09
09
15
09
09
09
09
09
15
15
20
09
18
20
20
20
20
20
20
16
17
19
18
18
20
20
20
20
20
5.3 CARBON NUMBER/CLASS ASSIGNMENTS
345678
10
145
-------
TABLE 6-8 (continued)
HYDROCARBON SPECIES
STYRENE
A-MEIHYLSTYREHE
1,2,3-TRIMETHXLBENZENE
ISOMERS OF TRIMETHYLBENZENE
TETRAMEIHYLBENZENE
TRI/TETRAALKYL BENZENE
PHENOLS
XYLENE BASE ACIDS
CHLOROBENZENE
1,4 DIOXANE
SAROAD
CODE
45220
45221
45225
452JO
45232
45233
45)00
45401
45801
46201
5.2
CLASS
20
20
20
20
20
20
20
29
20
09
5.3
CLASS: 1 2
1
1
1
2
3
5
1
5.3 CARBON NUMBER/CLASS ASSIGNMENTS
3456789 10
1 1
1 1
1
1
1
1
1 4
1
1
1
146
-------
ic- m IQ /-I •» i /. i o moles olefin
olefin: 10.18 (1) = 10.18
kg THC emissions
paraffin: 10.18 (5) = 50.9 .uo^r P*raffin
kg THC emissions
Emissions profiles containing more than one species are handled in the same
manner, by using the appropriate profile weight fractions and summing each
species' contribution to each bond class.
A separate species profile does not exist for every SCC. Since many SCCs
produce emissions with the same or very similar THC species mixes, there are
many fewer THC species profiles (approximately 175) than there are SCCs
(approximately 1,250 point source SCCs, 88 U.S. area source SCCs, and
150 Canadian area source SCCs).
The speciation of NOX emissions into NO and N02 is more straight-
forward. Each species profile also includes the weight percents of NO and
N02 which comprise the profile's NOX emissions. When an SCC is matched
with a species profile to create a species mole factor record, these weight
percents are carried along and become the allocation factors for these two
species.
Speciation Factor Development
The NAPAP Version 4.2 and Version 5.2 species mole factors are built upon
those originally created for the NECRMP Inventory and modeling effort. The
original development of the species mole factors for NECRMP consisted of an
extensive exercise in data collection and reduction.
For NECRMP, data were collected on the species makeup of hydrocarbon
emissions for all SCCs included in the NECRMP Inventory. From this large data
set, the smaller set of species profiles was distilled, and each SCC was
assigned to one of these profiles. The NECRMP effort resulted in the creation
of the first set of SCC/Profile, Species/Profile, Species/Class, and Species
Mole Factor files.
A number of improvements and expansions to the NECRMP species mole
factors were made during the NAPAP Version 4.2 Inventory effort. Chief among
these were :
1. Addition of 198 point source SCCs. These were either matched with
existing species profiles, or were assigned new profiles developed
during the NAPAP Version 4.2 effort; and
2. Reassignment of the area source species profiles. The NAPAP area
source categories were similar but not identical to those used for
NECRMP. Some new categories were added, necessitating the
assignment or development of species profiles, and some categories
were combinations of several NECRMP categories, necessitating the
assignment of the most appropriate species profile.
147
-------
Modifications to the Species Factors for NAPAP Version 5.2
Refinement and expansion of the species mole factors for NAPAP Version 5.2
have proceeded in four areas:
I. Creation of 169 new species profiles. A review of the NAPAP
Version 4.2 species mole factors revealed that species profiles
assigned to some SCCs did not precisely reflect actual composition
of THC emissions for these SCCs. In addition, some newly added SCCs
were not adequately represented by existing species profiles.
2. Expansion of photochemical reactivity classes from 10 to 30;
3. Expansion of U.S. area source SCCs from 54 to 88, addition of
Canadian area source SCCs, and addition of approximately 40 point
source SCCs;
4. Addition of TSP speciation into five alkaline dust fractions for a
subset of all point source SCCs.
Creation of New Species Profiles—
A thorough review of the assignment of SCCs to species profiles was
undertaken for the NAPAP Version 5.2 effort. On the basis of this review, it
was decided that profiles could be more precise for many SCCs. The review
consisted of an engineering analysis of the match between the actual typical
species composition of THC emissions for a given SCC and the species profile
assignment for that SCC. For most SCCs, the assignment of SCCs to species
profiles was sound, but for some the acquisition of new data on emission
composition made possible the creation of a new and more accurate species
profile.
A second reason for the creation of the new species profiles was the
addition of new emissions categories to the NAPAP Version 5.2 Inventory (see
below). For many of these new SCCs, existing species profiles accurately
represented the THC composition of emissions. For others, however, a review
of emissions data revealed that no existing species profile adequately
mimicked this composition, and new profiles were developed to represent the
species breakdowns of these emissions.
Expansion of the Number of Photochemical Reactivity Classes—
At the request of NCAR, NAPAP has expanded the number of photochemical
reactivity classes into which THC emissions are allocated from 10 to 30. As
explained above, each of the 160 hydrocarbon species can be assigned to a
user-defined class on the basis of any scheme desired by the NAPAP user; in
this case the NCAR modelers have availed themselves of this flexible feature
of the NAPAP data handling system to request a species classification scheme
specific to their needs.
NCAR assisted NAPAP in matching each THC species to one of the
30 photochemical classes, and reviewed and approved all such assignments
before the speciation factors were processed through the FREDS system. The
148
-------
NAPAP Version 5.2 Species/Class file, which defines the assignment of each
SAROAD species to its photochemical class, is printed in Table t>-8.
Modifications to the PSPLIT Program—The PSPLIT program, installed on the
NCC UNIVAC, performs the function of merging the Species/Class, SCC/Prolile,
and Species/Profile files to create a Species Mole Factor file. PSPLIT was
originally written for the NECRMP modeling effort, and was used without major
modification for the NAPAP Version 4.2 effort. PSPLIT was written to accept
assignment of SAROAD species to only 10 classes; the program therefore had to
be modified before the 30 classes requested by the NCAR modelers could be
processed. This programming assignment was carried out by NAPAP, and the
modified PSPLIT remains available for further use in inventory development.
Expansion of the Number of SCCs—
The NAPAP Version 5.0 emissions inventory contains some 230 Source
Classification Codes not represented in earlier NAPAP inventories. These
additions reflect:
1. Expansion of the number of U.S. area source emission categories from
54 to 88;
2. Inclusion of 157 Canadian area source emission categories for the
first time; and
3. Addition of some 40 new point source emission categories.
After the nature of these added SCCs was known, it was possible to assign
appropriate species profiles. As explained above, in many cases existing
species profiles proved accurately to represent the THC composition of these
emissions classes; in others, however, new species profiles were generated
based on data on the composition of the hydrocarbon portion of these emissions.
Addition of TSP Speciation—
For approximately 10 percent of all point source SCCs, TSP emissions are
speciated in NAPAP Version 5.2 into five alkaline dust categories according to
weight percent; these categories are calcium (Ca), magnesium (Mg), potassium
(K), sodium (Na), and "other". TSP emissions for a total of approximately 140
8-digit SCCs are allocated among the five alkaline dust categories.
Speciation Files
A total of five files are relevant to the development and use of the
speciation factors. Three of these files serve as input to the PSPLIT program:
1. the SCC/Profile file, used to match each SCC with the appropriate
THC species profile;
2. the Species/Profile file, which specifies the relative contribution
of individual SAROAD species to each species profile; and
3. the Species/Class file, which assigns each SAROAD species to one of
30 photochemical classes.
149
-------
The remaining two files are the speciation files themselves, the files
which are processed by the FREDS system. The THC/NOX Species Mole Factor
file is output from PSPLIT, as described above. The separate TSP Species Hole
Factor file was developed from Canadian data on TSP speciation in a separate
development effort.
150
-------
SECTION 7
EMISSIONS INVENTORY SOFTWARE
DEVELOPMENT AND DATA PROCESSING
FREDS SYSTEM
The previous release of the 1980 NAPAP inventory, Version 4.0, was
converted into a format suitable for input into the RADM by the Regional Model
Data Handling System (RMDHS). RMDHS was originally developed to process the
NECRMP emissions inventory and was subsequently modified by Alliance to
accommodate the NAPAP 4.2 inventory requirements. Primarily due to
limitations placed on the number of pollutants that could be processed through
the system, RMDHS was judged unsuitable (Sellars, et al., 1984) for use in
modifying the 1980 NAPAP Version 5.0 inventory to produce the 5.2 inventory
modeler's tapes. Therefore, in order to meet the requirements of the
Version 5.0/5.2 inventories, the Flexible Regional Emissions Data System was
developed in 1985 (Lebowitz and Ackerman, 1987).
The FREDS system consists of a number of independent software modules
written in the language of the Statistical Analysis System (SAS) on the
National Computer Center's IBM 3090 computer. SAS was chosen due to its
flexibility with regard to file structure, its powerful "macro" commands, and
its diverse statistical and graphics capabilities which permit almost
unlimited analysis of the emissions data. The role of the FREDS system in the
development of the 1980 NAPAP 5.2 inventory is to extract pertinent emissions
data from the 1980 NAPAP 5.0 inventory, resolve emissions data temporally and
spatially, resolve composite emissions to individual species, and output the
data in a format suitable for use as input to the RADM. This is accomplished
by the execution of five independent FREDS modules; the Model Data Extraction
Module, the Speciation Module, the Temporal Allocation Module, the Spatial
Allocation Module, and the Model Input Preprocessor. A brief description of
each module appears in the following paragraphs.
Model Data Extraction Module
MDEM reads the NAPAP 5.0 annual emissions file to produce a SAS file
suitable for processing through the rest of the FREDS system. In addition,
MDEM can produce industry-specific subfiles and/or minor point source files.
Neither of these options was applied to the 5.0 inventory. MDEM must be the
first module executed in order to achieve file compatibility throughout the
rest of the FREDS system.
151
-------
Speciation Module
The Speciation Module accepts as input any FREDS-compatible file that has
not been speciated, and applies speciation factors to each record. Lt has
been designed to receive as input two files containing speciation factors.
One file, the output file of the PSPLIT program, contains mole fractions for
up to 30 hydrocarbon classes in addition to NO and N0£ percentages. The
other speciation factor file provides a mechanism for including speciation
factors for other pollutants; for the 5.0 inventory, this includes alkaline
dust species applied to TSP emissions. The Speciation Module can support
processing of up to 450 speciation factors and five levels of specificity
(SCC, state, county, plant, and point), ensuring maximum flexibility for
speciation strategies to be developed in future inventories.
Temporal Allocation Module
The temporal allocation of point source and area source data is carried
out in the Temporal Allocation Module. Any FREDS-compatible file is suitable
as input. The module applies to each emission record a time zone offset to
Greenwich Mean Time (GMT) and a daylight savings time indicator, as well as
seasonal, daily, and hourly temporal fractions. The temporal data are input
from two separate files: the time zone file, which contains the GMT offset
plus the daylight savings flag for every county in the NAPAP study area, and
the temporal allocation factor file described in the previous section. Each
emission record must have a time zone offset to be processed successfully.
Temporal allocation factors may have the same levels of specificity as the
speciation factors. Furthermore, any point source record that does not have a
corresponding match in the temporal allocation factor file will have a pattern
generated based on the operating rate data of the point source. If the
operating rate data is missing or incomplete, a uniform temporal pattern is
generated.
Spatial Allocation Module
The Spatial Allocation Module spatially allocates FREDS compatible
emissions files into the 20 x 20 km (1/4 degree longitude by 1/6 degree
latitude) grid system used by the RADM. For point sources, the module uses
either polar coordinates or UTM coordinates to calculate the proper column
(X coordinate) and row (Y coordinate) position of the source within the NAPAP
study area. Point sources with missing coordinates are placed in a separate
file. Area source emissions are allocated on a county-basis to the grid
according to known distributions of surrogate indicators as discussed in the
previous section. The Spatial Allocation Module has the ability to process
grid systems using sizes other than the 20 x 20 km grids used for the NAPAP
inventory. Point sources are checked for inclusion within county boundaries;
if they are outside the county, they are assigned to the county centroid.
Area sources with no spatial factor match are placed in an orphan file for
further consideration.
152
-------
Model Input Preprocessor
The Model Input Preprocessor is the last step of the FREDS system. For
point sources, this module combines the resolved FREDS-compatible files (those
files which have been processed through the four modules described above) to
produce a master file in SAS format and a point source modeler's tape in
EBCDIC format. Area sources, due to the large amount of data involved, are
processed in a different manner. The user must provide the number of the
temporal scenario desired (Table 3-7). The model input preprocessor will
combine the speciated, temporally, and spatially resolved area source data to
produce a condensed gridded hourly emission file for the chosen temporal
scenario.
DATA PROCESSING RESULTS
5.0 Inventory
The 1980 NAPAP Emissions Inventory Version 5.0 resides in four files:
U.S. point sources, Canadian point sources, U.S. area sources, and Canadian
area sources.
The U.S. point source file contains annual emissions data at the process
(SCO level for all 11 major NAPAP pollutants. In addition to emissions, the
file has complete stack information, fuel parameters, operating rate data,
emission factors, identification and location information, and control
equipment parameters. There are 50,159 records encompassing the contiguous
United States.
The Canadian point source file has annual pollutant data, reported at the
process level, for 8 of the 11 major NAPAP pollutants plus alkaline dust
species. Lead, HC1, and HF are not reported in the Canadian inventory. Since
the Canadian data were not based on NEDS submittals, they are incomplete in a
number of areas. At this time, only the emissions and identification and
location data can be considered accurate. The stack data are complete;
however, SCC averages were inserted to supplement missing values in
approximately two-thirds of the records. The file contains 2,745 records.
The U.S. area source data base is composed of identification information
and county-level emissions for the 11 major NAPAP pollutants. Emissions
within a county are divided into 88 area source categories (Appendix D). The
file contains 245,405 observations which cover 3,070 counties within the
contiguous U.S.
Canadian area source emissions are reported at the province level for
8 of the 11 major NAPAP pollutants. The pollutants missing in the area source
file are the same as those in the Canadian point source file: lead, HF and
HC1. Provincial emissions are divided into 157 area source categories
(Appendix D); these categories are different than the U.S. area source
categories. There are 1,255 records in the file, covering all 12 Canadian
provinces.
153
-------
5.2 Inventory
Each of the four 5.0 annual emissions files were processed through FREDS
separately to produce the 5.2 inventory. Processing results for each file are
summarized below.
The 5.0 U.S. point source annual emissions were processed by the Model
Data Extraction Module to extract pertinent modeling data. Next, the MDEM
output file was run through the Spatial Allociation Module, which identified
573 sources with either missing or invalid coordinate data. These sources
were placed at their respective county centroids. The data were then
processed successfully through the Speciation and Temporal Allocation
Modules. Processing results are summarized in Table 7-1. The Temporal
Allocation Module output file was used as input to the Model Input
Preprocessor, where point sources from the U.S. and Canada were combined to
form a single point source Version 5.2 SAS master file from which the
modeler's tape was produced.
The Canadian 5.0 point source annual emissions file successfully
completed MDEM. The Spatial Allocation Module identified 104 sources located
outside the NAPAP 5.2 study area; a number of these points were found to have
incorrect data. Those sources were corrected and resubmitted through the
Spatial Allocation Module. An additional 40 sources were not within the NAPAP
grid system. It should be noted that county centroid QA processing of the
Canadian data was not possible since the Canadian "counties" were not counties
in the U.S. sense, but rather census districts for which there were no
centroids available. Speciation Module processing of the Spatial Allocation
Module output file proceeded without incident. Temporal Allocation Module
results showed a large number of plants (2,574) were missing operating rate
data. Canadian point source results appear in Table 7-2.
Processing of the U.S. 5.0 area source annual emissions file through
FREDS proceeded through the Model Data Extraction Module and the Speciation
Module without incident. Upon Spatial Allocation Module execution, it became
apparent that, due to the large number of records output from the Spatial
Allocation Module, the U.S. file would have to be divided into smaller, more
manageable pieces. Thus, the Spatial Allocation Module output file was split
into four subfiles which were used as input to the Temporal Allocation Module,
which was run 12 times on each subfile, once for each temporal scenario. U.S.
area source processing is summarized in Table 7-3. The Model Input
Preprocessor combined the four U.S. subfiles with the Canadian file to form a
complete NAPAP area source modeler's tape. Twelve Model Input Preprocessor
runs were required to produce all of the 5.2 area source modeler's tapes.
The Canadian 5.0 area source annual emissions file proceeded through the
Model Data Extraction Module and the Speciation Module without incident. As
in the 5.0 inventory, Yukon and Northwest Territories were dropped since they
are outside the NAPAP study area. Due to the nature of the Canadian spatial
data, the Spatial Allocation Module was bypassed in favor of a customized
program which could accommodate the differences in the Canadian grid
percentages. The spatially allocated emissions were run through the Temporal
154
-------
TABLE 7-1. FREDS PROCESSING—U.S. POINT SOURCES
FREDS
module
Input
records
Output
records
Comments
MDEM
SAM
TAM
50,159
50,159
50,159
50,159
50,159
50,159
SM
50,159
50,158
573 sources placed in county centroids
Temporal pattern basis:
- 1,766 state specific factors
- 5,537 SCC specific factors
- 42,843 operating rate data
- 13 uniform distribution
1 source with invalid SCC code removed
155
-------
TABLE 7-2. FREDS PROCESSING—CANADIAN POINT SOURCES
FREDS
module
Input
records
Output
records
Comments
MDEM
SAM
TAM
2,745
2,745
2,705
2,745
2,705
2,705
SM
2,705
2,705
40 sources located outside NAPAP boundaries
Temporal pattern basis:
- 131 SCC specific factors
- 0 operating rate data
- 2,574 uniform distribution
156
-------
TABLE 7-3. FREDS PROCESSING--U.S. AREA SOURCES
FREDS
module
MDEM
SM
SAM
TAM
Input
records
245,405
245,405
245,405
3,184,248
Output
records
245,405
245,405
3,184,248
3,184,248
Comments
Divided into four subfiles
Temporal pattern basis:
- 551,043 state specific factors
- 2,633,205 SCC specific factors
157
-------
Allocation Module 12 times in order to produce one gridded, hourly emissions
file for each temporal scenario. Processing information may be found in
Table 7-4. As mentioned earlier, the Canadian Temporal Allocation Module
output was combined with the U.S. Temporal Allocation Module output subfiles
in the Model Input Preprocessor to produce the area source modeler's tapes.
5.3 Inventory
The 1980 NAPAP Version 5.3 inventory was produced from the NAPAP 5.0
data. It is identical to the NAPAP 5.2 inventory except in the area of
hydrocarbon speciation. The 5.3 inventory contains 10 hydrocarbon classes
apportioned using Carbon IV chemistry, whereas the 5.2 inventory employs 28
photochemical classes. Processing of the 5.3 inventory was similar to that of
the 5.2 inventory.
PRODUCTS AVAILABLE
Major files produced by FREDS processing and brief descriptions appear in
Table 7-5. In addition, intermediate FREDS processing files can be made
available if necessary. Formats for each product are included in Tables 7-6
through 7-11.
158
-------
TABLE 7-4. FREDS PROCESSING—CANADIAN AREA SOURCES
FREDS Input Output
module records records
Comments
MDEM
SM
1,255
1,255-
1,255
1,114
Yukon, N.W. Territories and province totals
removed
SAM - 1,114 545,851 Temporal pattern basis:
- 467,899 province specific factors
- 77,952 SCC specific factors
159
-------
TABLE 7-5. NAPAP VERSION 5 PRODUCTS
Version
Description
Temporal Character Format
resolution set tables
A
B
C
D
E
F
G
H
I
J
K
L
M
N
0
P
Q
R
S
T
U
V
W
X
Y
Z
AA
BB
CC
DD
EE
*
**
5.0/5.2/5.3 Development of the 1980 NAPAP
Emissions Inventory (Report)
5.0 U.S. Point Sources Annual
Canada Point Sources
* U.S. Area Sources
Canada Area Sources
5.2 Point Sources Hourly
** Area Sources - Winter Weekday
Area Sources - Winter Saturday
Area Sources - Winter Sunday
Area Sources - Spring Weekday
Area Sources - Spring Saturday
Area Sources - Spring Sunday
Area Sources - Summer Weekday
Area Sources - Summer Saturday
Area Sources - Summer Sunday
Area Sources - Fall Weekday
Area Sources - Fall Saturday
Area Sources - Fall Sunday
5.3 Point Sources Hourly
** Area Sources - Winter Weekday
Area Sources - Winter Saturday
Area Sources - Winter Sunday
Area Sources - Spring Weekday
Area Sources - Spring Saturday
Area Sources - Spring Sunday
Area Sources - Summer Weekday
Area Sources - Summer Saturday
Area Sources - Summer Sunday
Area Sources - Fall Weekday
Area Sources - Fall Saturday
Area Sources - Fall Sunday
This data set spans three tapes.
5.2 and S . "? Area Source data spt~s each snan two tanes .
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
, EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
EBCDIC
anH ar<» div
7-6
7-6
7-7
7-7
7-8
7-9
7-9
7-9
7-9
7-9
7-9
7-9
7-9
7-9
7-9
7-9
7-9
7-10
7-11
7-11
7-11
7-11
7-11
7-11
7-11
7-11
7-11
7-11
7-11
7-11
"i dfd
at 100°W longitude.
160
-------
TABLE 7-6. VERSION 5.0, U.S. AND CANADIAN POINT SOURCES
(SAS AND EBCDIC FORMAT)
Start
End
Format
(EBCDIC)
1
3
7
10
14
19
22
24
36
40
42
43
58
68
78
126
130
137
185
186
238
239
241
244
248
250
255
261
263
265
267
270
272
274
276
278
280
282
284
285
2
6
9
13
18
21
23
35
39
41
42
57
67
77
125
129
136
184
185
237
238
240
243
247
249
254
260
262
264
266
269
271
273
275
277
279
281
283
284
286
N2
N4
N3
A4
N5
A3
A2
A12
N4
N2
Al
A15
N10
A10
A48
N4
N7
A48
Al
A52
Al
A2
A3
N4
N2
N5
N6
N2
N2
N2
N3
N2
N2
N2
N2
N2
N2
N2
Nl
N2
Variable
(SAS)
STATE
COUNTY
AQCR
PLANT ID
TRDATE
UCONREG
LCONREG
UPLANTID
CITY
UTM ZONE
OWNER
CONTACT
PHONE
PRIPROD
NAME ADD
NUMEMP
PROPAREA
MAIL
NEDP1
NEDPLCOM
NEDPLCAR
POINT ID
UPOINTID
SIC
IPP
UTMX
UTMY
LAT DEC
LAT MIN
LAT SEC
LON DEC
LON MIN
LON SEC
WINTHRU
SPRTHRU
SUMTHRU
FALTHRU
HOURS
DAYS
WEEKS
Description
NEDS State Code
NEDS County Code
Air Quality Control Region Code
NEDS Plant ID Code
Date of Transaction Information (YYDDD)
User Control Region
Under Jurisdiction of Another UCONREG
User Plant ID
NEDS City Code
UTM Zone
Ownership Code (P-Private, L-Local Gov.,
S-State Gov., F-Federal Gov., U-Utility)
Person Responsible for Pollution Control
Telephone Number of Contact
Principal Product Produced at Plant
Plant Name and Mailing Address
Number of Employees
Area, in Acres, of Facility Land
Contact Mailing Address
NEDS PI Card Flag
NEDS P7 Plant Comment
NEDS P7 Plant Card Flag
NEDS Point ID
User Point ID
Standard Industrial Classification Code
NEDS Implementation Planning Process Code
UTM Horizontal Coordinate
UTM Vertical Coordinate
Degrees Latitude
Minutes Latitude
Seconds Latitude
Degrees Longitude
Minutes Longitude
Seconds Longitude
Winter Thruput %
Spring Thruput %
Summer Thruput %
Fall Thruput %
Hours per Day in Operation
Days per Week in Operation
Weeks per Year in Operation
(continued)
161
-------
TABLE 7-6 (continued)
Start End
(EBCDIC)
287
292
296
300
304
308
315
320
324
328
329
330
331
332
333
385
386
394
396
401
402
409
417
421
425
430
431
432
457
458
459
511
512
514
519
522
525
291
295
299
303
307
314
319
323
327
328
329
330
331
332
384
385
393
395
400
401
408
416
420
424
429
430
431
456
457
458
510
511
513
518
521
524
528
Format
N5
N4
N4
N4
N4
N7
N5
N4
A4
Al
Al
Al
Al
Al
A52
A I
N8
N2
N5
Al
N7
N8
N4
N4
N5
Nl
Al
A25
Al
Al
A52
Al
N2
N5
N3
N3
N4
Variable
(SAS)
BOILCAP
SPHEAT
STACK HT
STACK DI
STACK TP
FLOW
VELOCITY
PLUME HT
PTSCOMST
NEDP2
NEDP3
NEDP4
NEDP5
PWCS
NEDPTCOM
NEDPTCAR
EISSCC
NUMSCC
BEC
FUNITS
THRUPUT
MAXRATE
SCON
ASHCON
HEATCON
CONFID
SCECODE
SCEDESC
EMFORIG
NEDP6
NEDSCCOM
NEDSCCAR
NUMPOLL
SAROAD1-15
CONPRI1-15
CONSEC1-15
CONEFF1-15
Description
Boiler Design Capacity, Million Btu per Hour
Percent of Fuel Used for Space Heating
Stack Height, ft
Stack Diameter, ft
Stack Temperature, Degrees F
Exhaust Flow Rate, CFM
Velocity, ft per second
Plume Height, ft
Range of Points Using Common Stack
NEDS P2 Card Flag
NEDS P3 Card Flag
NEDS P4 Card Flag
NEDS P5 Card Flag
PWCS NEDS Flag
NEDS P7 Point Comment
NEDS P7 Point Card Flag
SCC-Source Classification Code
SCC Sequence Number
EEC-Basic Equipment Classification Code
Fuel Units (Not Used)
Fuel Process Rate (Thruput)-Ann. Operating
Rate
Maximum Hourly Design Rate
Sulfur Content Percent
Ash Content
Heat Content in Millions of Btu
Confidentiality (1-Yes, 2-No)
SCC Process Category (B-Boiler, P-Process,
C-Other Combustion, S-Solid Waste)
Source Description
Emission Factor Origin (F-Federal, S-State,
L-Local)
NEDS P6 Card Flag
NEDS P7 SCC Comment
NEDS P7 Card Flag
Number of Pollutants
Pollutant ID
Primary Control Equipment
Secondary Control Equipment
Estimated Control Efficiency Percent
(continued)
162
-------
TABLE 7-6 (continued)
Start End
(EBCDIC)
Format
Variable
(SAS)
Description
529
529
530
539
540
541
538
539
540
547
NOTE:
Nl ESTMET1-15 Estimation Method Used to Ascertain
Estimated Emissions (0-Not Applicable,
1-Stack Test, 2-Material Balance, 3-
Emission Factor, 4-Guess, 5-Special EMF,
6-New Construction, 7-Facility Closed)
A9 EMF1-15 Emission Factor
Al ASCODE1-15 Ash-Sulfur Code
Nl EMFUNI1-15 EMF Units
N7 EMISS1-15 Apportioned Emissions in tons/year
Columns 514 to 547 may be repeated
once for each pollutant.
'NUMPOLL' (up to 15) times,
Start/End positions refer to EBCDIC files; variables in SAS data sets are
referenced by name.
163
-------
TABLE 7-7. VERSION 5.0, U.S. AND CANADIAN AREA SOURCES (SAS AND EBCDIC FORMAT)
Start End
(EBCDIC)
1
3
7
10
30
32
40
94
98
102
106
110
115
120
121
129
131
136
140
144
149
153
160
166
172
178
184
190
196
201
203
228
230
239
246
248
260
261
285
2
6
9
29
31
39
93
97
101
105
109
114
119
120
128
130
135
139
143
148
152
159
165
171
177
183
189
195
200
202
227
229
238
245
247
259
260
284
286
Format
N2
N4
N3
A20
N2
N8
A54
N4
N4
N4
N4
N5
N5
Al
N8
A2
N5
N4
N4
N5
N4
N7
N6
N6
N6
N6
N6
N6
N5
N2
A25
N2
A9
A7
A2
A12
Al
12(N2)
N2
Variable
(SAS)
STATE
COUNTY
AQCR
AREANAME
POP RURAL
POP
AQCRNAME
SCONA
SCONB
SCOND
SCONR
ASHCONA
ASHCONB
SOURCE
LENAREA
LAUNITS
TSPSIP
S02SIP
NOXSIP
HCSIP
COSIP
GFLV
GFHV
DFHV
MVMLAR
MVMRR
MVMSR
MVMUR
EISSCC
DISAGG
CATDESC
CATYEAR
THRUPUT
CATADJ
UCODE
UDESC
UNITHRU
MTHRUl-12
HOURS
Description
NEDS State Code
NEDS County Code
Air Quality Control Region Code
County Name or Geographical Area
Rural Population Percentage
Population
AQCR Name
Sulfur Content - Anthracite Coal
Sulfur Content - Bituminous Coal
Sulfur Content - Distillate Oil
Sulfur Content - Residual Oil
Ash Content - Anthracite Coal
Ash Content - Bituminous Coal
Source Type (L-Line or Link, A-Area)
Length of Line Source or Area of Area Source
Units Code for Length or Area
TSP SIP Estimate (X100 tons/year)
S02 SIP Estimate (X100 tons/year)
NOX SIP Estimate (X100 tons/year)
Hydrocarbon SIP Estimate (X100 tons/year)
CO SIP Estimate (X100 tons/year)
Gas Fuel Consumed by Light Vehicles
(X1000 gal)
Gas Fuel Consumed by Heavy Vehicles
(X1000 gal)
Diesel Fuel Consumed by Heavy Vehicles
(X1000 gal)
Motor Vehicle Miles for Limited Access Roads
Motor Vehicle Miles for Rural Roads
Motor Vehicle Miles for Suburban Roads
Motor Vehicle Miles for Urban Roads
Area Source Category Number
Category Disaggregation Number
Category Description
Year of Information
Annual Process Rate (Thruput)
Category Adjustment Value
Units Code for Annual Thruput
Units Code Description
Uniform Monthly Thruput Indicator (Y or N)
Monthly Thruput Percentage (1-Jan, 2-Feb..)
Hours Per Day
(continued)
164
-------
TABLE 7-7 (continued)
Start End
(EBCDIC)
Format
Variable
(SAS)
Description
287 287 Nl DAYS Days Per Week
288 289 N2 WEEKS Weeks Per Year
290 294 N5 THRURAT Thruput Ratio
295 305 Nil MAXTHRU Maximum Hourly Thruput
306 306 Nl CONFRATE Data Confidence Rating
307 310 N4 NCON Nitrogen Content (Weight Percentage)
311 313 N3 SCON Sulfur Content (Weight Percentage)
314 317 N4 ASHCON Ash Content (Weight Percentage)
318 321 N4 HEATCON Heat Content (Percent 1 Million Btu)
322 322 Al HOURTHRU Uniform Hourly Thruput (Y or N)
323 370 24(N2) HTHRU1-24 Hourly Thruput Percentages
371 372 N2 NUMPOLL Number of Category Record Pollutants
373 377 N5 SAROAD1-15 Pollutant ID '
378 . 388 Nil EMF1-15 Emission Factor
389 389 Al EMFCR1-15 Emission Factor Confidence Rating
390 390 Al EMFSC1-15 Emission Factor Source Code
391 391 Al EMFORI1-15 Emission Factor Origin (F-Fed., S-St.,
L-Loc.)
392 401 A10 PSD1-15 Pollutant Specific Data
402 408 N7 EMINED1-15 NEDS A7 Emissions (tons/year)
409 423 A15 NAME1-L5 Pollutant Name
424 424 Al EIS5C1-15 EIS Category 5 Card Flag
425 431 N7 EMISS1-15 Emissions Estimate (tons/year)
432 432 Al CONRAT1-15 Confidence Rating
433 438 A6 EMIMAX1-15 Maximum Hourly Emissions
NOTE: Columns 373 to 438 may be repeated 'NUMPOLL'(up to 15)
times, once for each pollutant.
Start/End positions refer to EBCDIC files; variables in SAS data sets are
referenced by name.
165
-------
TABLE 7-8. VERSION 5.2, POINT SOURCES (SAS* AND EBCDIC FORMAT)
Start End
(EBCDIC)
Format
Variable
(SAS)
Description
SCC Code
State Code
County Code
Plant Identification Code
Point Identification Code
Air Quality Control Region
SIC Code
Source Type
Fractional Latitude
Fractional Longitude
Grid Column
Grid Row
Time Zone Offset
Daylight Savings Flag
Exhaust Gas Flow Rate (ft^/min)
Plume Height (ft)
Stack Diameter (ft)
Stack Height (ft)
Stack Temperature (F)
Stack Gas Velocity
Aldehyde and Methane Speciation Adjustment
Year of Emission Record
Number of EIS Pollutants
SAROAD Code of EIS Pollutant
Emissions (tons/year) of EIS Pollutant
NOTE: SAROAD and EMISS will be repeated NUMPOLL (up to 15) times,
once for each pollutant.
N2 NUM DAY Number of Temporal Factor Sets in Record
N4 SEAT-12 Seasonal Temporal Allocation Factor
N5 DAY1-12 Daily Temporal Allocation Factor
N4 HOUR1-288 Hourly Temporal Allocation Factors
NOTE: For EBCDIC files, each seasonal allocation factor is directly followed
by its corresponding daily and 24 hourly factors; this sequence is
repeated for each of the 12 NAPAP temporal scenarios. In the SAS data
set, HOUR1-24 corresponds to the hourly factors for scenario 1,
HOUR25-48 to scenario 2, and so on. All hourly factors for point
sources are expressed in local time.
1
9
11
15
19
21
25
29
31
41
51
55
59
60
61
68
72
76
80
84
89
94
96
98
8
10
14
18
20
24
28
30
40
50
54
58
59
60
67
71
75
79
83
88
93
95
97
N8
N2
N4
A4
A2
N4
N4
A2
N10
N10
N4
N4
Nl
Nl
N7
N4
N4
N4
N4
N5
N5
N2
N2
N5
N7
EISSCC
STATE
COUNTY
PLANT ID
POINT ID
AQCR
EISSIC
SOURCE
LAT
LON
COL
ROW
ZONE
DAYLITE
FLOW
PLUME HT
STACK DI
STACK HT
STACK TP
VELOCITY
HCHOWT
REC DATE
NUMPOLL
SAROAD 1-1 5
EMISS1-15
(continued)
166
-------
TABLE 7-8 (continued)
Start End
(EBCDIC)
Format
N3
37(N5)
37(N5)
37(N5)
Variable
(SAS)
NUMSP
CAT1-37
CLASS1-37
SF1-37
Description
Number of Speciation Factors
Major Pollutant SAROAD of Species
SAROAD Code of Pollutant Species
Speciation Factor of Species/100
NOTE: CAT, CLASS and SF are repeated 37 times,
once for each species.
N4 CONEFF1-15 Control Efficiency of Point Pollutant
Nl ESTMET1-15 Estimation Method Used for Point Pollutant
NOTE: CONEFF and ESTMET will be repeated NUMPOLL
(up to 15) times, once for each pollutant.
*SAS-formatted files contain two additional variables: SAP (the spatial
allocation fraction) and MAJOR (the major pollutant source flag); both are
equal to 1 for point sources.
Start/End positions refer to EBCDIC files; variables in SAS data sets are
referenced by name.
167
-------
TABLE 7-9. VERSION 5.2, AREA SOURCES (SAS AND EBCDIC FORMAT)
Start End
(EBCDIC)
1
5
9
11
21
31
41
51
61
71
81
91
101
111
121
131
141
151
161
171
181
191
201
211
221
231
241
251
261
271
281
291
301
311
321
331
341
351
361
371
381
391
401
411
421
4
8
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
310
320
330
340
350
360
370
380
390
400
410
420
430
Format
N4
N4
N2
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
ElO
E10
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
ElO
Variable Description
(SAS)
COL
ROW
GMT
TOT1
TOT2
TOT3
TOT4
TOTS
TOT6
TOT7
TOT8
TOT9
TOT 10
TOT 11
TOT 12
TOT 13
TOT 14
TOT 15
TOT 16
TOT 17
TOT 18
TOT 19
TOT20
TOT21
TOT22
TOT23
TOT24
TOT25
TOT26
TOT27
TOT28
TOT29
TOT30
TOT31
TOT32
TOT33
TOT34
TOT35
TOT36
TOT37
TOT38
TOT39
TOT40
TOT41
TOT42
Grid Column
Grid Row
Hour (Greenwich Mean Time)
S02 Emissions (tons/hour)
SO^ Emissions (tons/hour)
TSP Emissions (tons/hour)
Pb Emissions (tons/hour)
CO Emissions (tons/hour)
HC1 Emissions (tons/hour)
HF Emissions (tons/hour)
NOX Emissions (tons/hour)
NHj Emissions (tons/hour)
VOC Emissions (tons /hour)
Total HC Emissions (tons/hour)
Methane Emissions (moles/hour)
Ethane Emissions (moles/hour)
Propane Emissions (moles/hour)
n-Butane Emissions (moles/hour)
iso-Butane Emissions (moles/hour)
2,3-Dimethylbutane Emissions (moles/hour)
Pentane Emissions (moles/hour)
iso-Pentane Emissions (moles/hour)
Other Alkanes Emissions (moles/hour)
Ethylene Emissions (moles/hour)
Propylene Emissions (moles/hour)
(Not used)
iso-Butene Emissions (moles/hour)
trans-2-Butene Emissions (moles/hour)
Other Alkenes Emissions (moles/hour)
Benzene Emissions (moles/hour)
Toluene Emissions (moles/hour)
Xylenes Emissions (moles/hour)
Ethyl Benzenes Emissions (moles/hour)
Other Aroma tics Emissions (moles/hour)
Formaldehyde Emissions (moles/hour)
Acetaldehyde Emissions (moles/hour)
Propionaldehyde Emissions (moles/hour)
Other Aldehydes Emissions (moles/hour)
Acetone Emissions (moles/hour)
Other Ketones Emissions (moles/hour)
Formic Acid Emissions (moles/hour)
Acetic Acid Emissions (moles/hour)
Other Organic Acids Emissions (moles/hour)
NO Emissions (tons/hour)
N02 Emissions (tons/hour)
Start/End positions refer to EBCDIC files; variables in SAS data sets are
referenced by name.
168
-------
TABLE 7-10. VERSION 5.3, POINT SOURCES (SAS* AND EBCDIC FORMAT)
Start End Format Variable
(EBCDIC) (SAS)
Description
1
9
11
15
19
21
25
29
31
41
51
55
59
60
61
68
72
76
80
84
89
94
96
98
8
10
14
18
20
24
28
30
40
50
54
58
59
60
67
71
75
79
83
88
93
95
97
N8
N2
N4
A4
A2
N4
N4
A2
N10
N10
N4
N4
Nl
Nl
N7
N4
N4
N4
N4
N5
N5
N2
N2
N5
N7
EISSCC
STATE
COUNTY
PLANT ID
POINT ID
AQCR
EISSIC
SOURCE
LAT
LON
COL
ROW
ZONE
DAYLITE
FLOW
PLUME HT
STACK DI
STACK HT
STACK TP
VELOCITY
HCHOWT
REC DATE
NUMPOLL
SAROAD1-15
EMISS1-15
SCC Code
State Code
County Code
Plant Identification Code
Point Identification Code
Air Quality Control Region
SIC Code
Source Code
Fractional Latitude
Fractional Longitude
Grid Column
Grid Row
Time Zone Offset
Daylight Savings Flag
Exhaust Gas Flow Rate (ft3/min)
Plume Height (ft)
Stack Diameter (ft)
Stack Height (ft)
Stack Temperature (F)
Stack Gas Velocity
Aldehyde and Methane Speciation Adjustment
Year of Emission Record
Number of EIS Pollutants
SAROAD Code of EIS Pollutant
Emissions (tons/year) of EIS Pollutant
NOTE: SAROAD and EMISS will be repeated NUMPOLL (up to 15) times.
N2 NUM_DAY Number of Temporal Factor Sets in Record
N4 SEA1-12 Seasonal Temporal Allocation Factor
N5 DAY1-12 Daily Temporal Allocation Factor
N4 HOUR1-288 Hourly Temporal Allocation Factors
NOTE: For EBCDIC files, each seasonal allocation factor is directly followed
by its corresponding daily and 24 hourly factors; this sequence is
repeated for each of the 12 NAPAP temporal scenarios. In the SAS data
set, HOUR1-24 corresponds to the hourly factors for scenario 1,
HOUR25-48 to scenario 2, and so on. All hourly factors for point
sources are expressed in local time.
(continued)
169
-------
TABLE 7-10 (continued)
Start End Format
(EBCDIC)
Variable
(SAS)
Description
N3 NUMSP Number of Speciation Factors
17(N5) CAT1-17 Major Pollutant SAROAD of Species
17CN5) CLASS1-17 SAROAD Code of Pollutant Species
17(N5) SF1-17 Speciation Factor of Species
NOTE: CAT, CLASS and SF are repeated 17 times, once for each species.
N4 CONEFF1-15 Control Efficiency of Point Pollutant
Nl ESTMET1-15 Estimation Method Used for Point Pollutant
NOTE: CONEFF and ESTMET will be repeated NUMPOLL
(up to 15) times.
*SAS-formatted files contain two additional variables: SAF (the spatial
allocation fraction) and MAJOR (the major pollutant source flag); both are
equal to 1 for point sources.
Start/End positions refer to EBCDIC files; variables in SAS data sets are
referenced by name.
170
-------
TABLE 7-11. VERSION 5.3, AREA SOURCES (SAS AND EBCDIC FORMAT)
Start End Format Variable
(EBCDIC) (SAS)
Description
1
5
9
11
21
31
41
51
61
71
81
91
101
111
121
131
141
151
161
171
181
191
201
211
221
231
4
8
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
N4
N4
N2
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
E10
COL
ROW
GMT
TOT1
TOT2
TOT3
TOT4
TOTS
TOT6
TOT7
TOT8
TOT9
TOT 10
TOT 11
TOT 12
TOT 13
TOT 14
TOT 15
TOT 16
TOT 17
TOT 18
TOT 19
TOT20
TOT 21
TOT22
TOT23
Grid Column
Grid Row
Hour (Greenwich Mean Time)
S02 Emissions (tons/hour)
SO^ Emissions (tons/hour)
TSP Emissions (tons/hour)
Pb Emissions (tons/hour)
CO Emissions (tons /hour)
HC1 Emissions (tons/hour)
HF Emissions (tons/hour)
NOX Emissions (tons/hour)
NH-j Emissions (tons/hour)
VOC Emissions (tons/hour)
Total HC Emissions (tons/hour)
Olefin Emissions (moles/hour)
Paraffin Emissions (moles/hour)
Toluene Emissions (moles/hour)
Xylene Emissions (moles/hour)
Formaldehyde Emissions (moles/hour)
Other Aldehyde Emissions (moles/hour)
Ethylene Emissions (moles/hour)
Nonreactive Emissions (moles/hour)
Isoprene Emissions (moles/hour
Methane Emissions (moles/hour)
NO Emissions (tons/hour)
N02 Emissions (tons/hour)
Start/End positions refer to EBCDIC files; variables in SAS data sets are
referenced by name.
171
-------
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Inventory. EPA-600/7-85-036 (NTIS PB86-112570), September 1985.
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Klemm, H. A. and R. J. Brennan. Emissions Inventory for the SURE Region.
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Lebowitz, L. G. and A. S. Ackerman. Flexible Regional Emissions Data System
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National Anthropogenic Area Source Emissions. Supply and Services Canada.
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New Jersey Department of Environmental Protection. Emission Inventory—
State of New Jersey, Trenton, NJ, 1980.
New York Department of Environmental Conservation. Emission Inventory—
State of New York, Metropolitan New York Region, Albany, NY, 1980.
Pechan, 1985: E.H. Pechan & Associates, Inc., "Electric Utility Unit
Inventory: Database Technical Documentation", prepared for University of
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PEDCo, 1981: PEDCo Environmental, Inc., "FGDIS Primer", prepared for
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Roth, Ron. Personal communication. Mr. Roth, of the American Trucking
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Sellars, F. M., M. J. Geraghty, A. M. Kiddie, and B. J. Bosy. 1982a.
Northeast Corridor Regional Modeling Project Annual Emission Inventory
Compilation and Formatting—Volume III—Delaware Emission Inventory.
U.S. EPA, EPA-450/4-82-013a. Washington, DC, 1982.
Sellars, F. M., M. J. Geraghty, A. M. Kiddie, and B. J. Bosy. 1982b.
Northeast Corridor Regional Modeling Project Annual Emission Inventory
Compilation and Formatting—Volume VII—New Hampshire Emission
Inventory. U.S. EPA, EPA-450/4-82-013g. Washington, DC, 1982.
Sellars, F. M., M. J. Geraghty, A. M. Kiddie, and B. J. Bosy. 1982c.
Northeast Corridor Regional Modeling Project Annual Emission Inventory
Compilation and Formatting—Volume XIV—Virginia Emission Inventory.
U.S. EPA, EPA-450/4-82-013n. Washington, DC, 1982.
Sellars, F. M., M. J. Geraghty, A. M. Kiddie, B. J. Bosy, and S. V. Capone.
1982d. The Northeast Corridor Regional Modeling Project Annual Emission
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EPA-450/4-82-013q. Washington, DC, 1982.
Sellars, F. M., T. E. Fitzgerald, Jr., J. M. Lennon, L. J. Maiocco,
N. M. Monzione, and D. R. Neal, Jr. National Acid Precipitation
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EPA-600/7-85-035 (NTIS PB86-104247), Research Triangle Park, NC,
September 1985.
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Research Triangle Park, NC, December 1984.
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173
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175
-------
-------
APPENDIX A
DETAILED EMISSIONS SUMMARIES
The emissions data contained in Versions 5.0 and 5.2 of the NAPAP
Emissions Inventory are summarized at various levels of aggregation in the
following pages. Tables A-l and A-2 are provided below to facilitate the
location of individual listings.
The Version 5.0 inventory includes 11 major pollutants; emissions of
these materials are reported in tons as well as metric tons. Tables are also
presented in thousands of moles for hydrocarbon species in Version 5.2.
Certain pollutants' emissions are slightly lower in the 5.2 inventory
than in the 5.0 inventory. Some Canadian point sources, for example, were
found to lie outside of the NAPAP study area and were not accepted by the
FREDS Spatial Allocation Module. These differences are negligible on a
percentage basis, usually amounting to significantly less than 1 percent of
total emissions.
A-l
-------
TABLE A-l. KEY TO TABLES, I960 NAPAP EMISSIONS INVENTORY VERSION 5.0
National Level of
coverage Source type resolution
U.S. Area SCC
State
Region
Point SCC
State
Region
Area & Point State
Region
Canada Area SCC
Province
Point SCC
Province
Area & Point Province
U.S. & Area & Point Totals
Canada
Hydrocarbon
classes ?
No
No
No
No
No
No
No
No
No
No
No
No
No
No
Units
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Tons
Metric Tons
Page
A-4 - A- 5
A-6 - A- 7
A-8
A-9
A- 10
A- 10
A-ll - A-17
A-18 - A-24
A-25
A-26
A-27
A-27
A-28
A-29
A-30
A-30
A-31 - A-33
A-34 - A-36
A-37
A-37
A-38 - A-39
A-40 - A-41
A-4 2
A-4 2
A-4 3
A-43
A-44
A-44
U.S.
Area & Point State
(Emissions density)
No
Tons/sq mi. A-45 - A-46
A-2
-------
TABLE A-2. KEY TO TABLES, 1980 NAPAP EMISSIONS INVENTORY VERSION 5.2
National Level of
coverage Source type resolution
U.S. Area SCO
State
Region
Point SCO
State
Region
Area & Point State
Region
Canada Area SCC
Province
Point SCC
'Province
Area & Point Province
U.S. & Area & Point Totals
Canada
Hydrocarbon
classes ?
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
No
Yes
Un i t s
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Tons
Metric Tons
Moles
Page
A -4 7 - A -4 8
A-49 - A-50
A-H - A-54
A-55
A-56
A-57 - A-58
A-59
A-59
A -60
A-61 - A-67
A-68 - A-74
A-75 - A-88
A-89
A-90
A-91 - A-92
A-93
A-93
A- 94
A-95
A-96
A-97 - A-98
A-99
A-99
A-100
A-101 - A-103
A-104 - A-106
A-107 - A-112
A-113
A-113
A- 114
A-115 - A-116
A-117 - A-118
A-119 - A-122
A-123
A-123
A- 124
A-125
A-125
A- 126
A-127
A-127
A-128
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
A-3
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S EMISSIONS, AREA SOURCES
sec |
--*
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
28
30
32
34
36
38
39
41
43
1 44
45
46
47
48
49
50
51
52
54
55
56
57
58
59
60
61
S02
12,097
28,664
148,356
0
1,271
9,866
13,301
44,138
53,199
278,844
417
0
155
454,236
189
37,407
140,186
25
7
77
1,494
1,284
6,496
9,005
144
11
67,096
86,875
23,236
30,059
7,093
8,402
3,326
86,416
119,651
74,790
128,494
4,098
806
7,573
3,648
12,343
212,163
2,725
0
0
0
0
0
0
5,013
3,007
S04
169
1,322
28,388
0
0
98,827
161
1,700
9,270
25 , 790
0
2
1
16,227
1
5,631
2,877
0
284
0
1
1
16
3
0
0
3,591
4,621
414
856
1
46
76
1,534
2,409
1,100
2,270
6
0
20
155
946
16,972
0
0
0
0
0
0
0
6
4
NOX
1,279
1,511
90,714
0
257,245
82,533
5,534
8,108
33,329
65,818
98,432
1
63
119,649
49
32,792
30,219
1,941,195
105
86
3,289
1,284
10,042
62,147
1,548
188
1,662,082
2,064,936
501,126
637.663
193,531
208,408
76,076
767,745
1,158.752
907,391
833,812
31,732
8,264
76,575
177
92,176
34,861
10,670
0
0
0
0
0
0
139,445
81,983
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
70
0
2
0
0
0
7,417
7,404
2,877
2,721
1,998
1,247
2
0
0
0
0
0
0
0
0
0
0
0
0
2
0
0
0
0
0
0
CO
39,900
47,697
25,119
0
51,412
6,363,435
232
4,801
8,217
5,901
19,615
2
1
15,332
21
7,721
2,715
259,534
311
3
935,430
9,814
29,182
1,038,173
29,182
3,455
9,703,579
35,437,309
3,027,549
11,205,758
2.212,888
5,492,472
2,476,699
245,728
719,910
270,807
293,012
151,354
536,351
220,313
5,295
32,258
1,166
1,360,524
0
0
0
0
0
0
4,881,714
2,295,361
TONS/YEAR
HCL
119
21
0
0
0
0
108
59
0
0
0
0
0
1,065
0
0
0
0
0
0
1.494
5
94
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HF
1
1
0
0
0
0
2
2
0
0
0
0
0
283
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3 TSP
0 4,406
0 7,906
0 12,499
0 0
0 7,529
0 1,032,150
0 439
0 279
0 3,123
0 22,421
0 2,681
0 5
7 1
0 4,490
0 76
0 2,828
0 10,527
0 155
0 135
0 19
0 110,851
0 7,259
0 21,129
0 242,709
0 4,857
0 727
0 696,177
0 3,325,305
0 175,227
0 831,481
0 43,832
0 137,676
0 6,865
0 133,644
0 338,923
0 94,886
0 56,532
0 61,689
0 1,541
0 3,289
0 3,531
0 9.862
0 16,094
0 0
0 0
0 29,270,073
0 7,528
0 0
0 0
0 0
0 592,770
0 409,913
VOC
7,796
9,306
23,461
0
9,815
2,038,388
24
56
1,316
2,797
3,676
1
0
495
1
126
952
3,962
121
1
61.784
1,742
8,288
339,286
9,092
1,396
1,830,921
4,094,727
640,766
1,441,277
234,862
489,780
198,921
112,041
305,115
147,354
240,871
89,446
30,980
89,097
577
28,235
2,439
370,657
966,415
0
0
0
0
0
836,862
368,884
THC
7,963
9,506
23,461
0
22,234
2,082,113
25
57
1,316
3,141
8,327
1
0
506
1
126
1,069
8,975
124
1
311,790
8,792
41,823
339,286
9,092
1,396
1,974,069
4,414,869
690,863
1,553,962
253,225
528,073
214,720
113,984
310,406
154,748
245,048
90,823
31,457
90,468
589
28,235
2,739
400,096
966,415
0
0
0
0
0
836,862
368,884
A-4
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S EMISSIONS, AREA SOURCES
SCC | S02
62
63
64
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
0
0
64
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
374
739
0
320,535
Contig. U.S. | 2,449,395
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
17
41
0
24,503
250,259
NOX
8,446
0
6,595
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
207
5,465
5,679
348,181
12,709,138
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
297
24,037
IUN3/ICAK
CO HCL
397,513
0
230,339
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
1,196
905
83,619
90,180,829
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
19
0
0
3,888
6,872
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
1,961
2,251
NH3
0
0
0
97,193
129,780
97,606
44,793
21,163
50,355
148,502
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
19
0
0
3,779
593,197
TSP
60,465
0
56,693
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,282
3
0
418,641
38,253,123
voc
68,041
0
42,334
0
0
0
0
0
0
0
506,129
300,118
175,812
126,782
473,818
182,582
12,187
157,460
31,576
20,584
52,134
18,177
1,602
1,164
3,693
248,596
342,132
1,047,157
0
580
129
344,393
19,201,288
THC
68,041
0
42,334
0
0
0
0
0
0
0
506,129
300,118
175,812
126,782
473,818
182,582
12,187
157,460
31,576
20,584
52,134
18,177
1,602
1,164
3,693
250,820
345,193
1,047,157
0
652
291
350,452
20,320.417
A-5
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S EMISSIONS, AREA SOURCES
sec
1
2
3
4
5
6
7
8
9
10
11
12
13
H
15
16
17
18
19
20
21
22
23
24
25
26
28
30
32
34
36
38
39
41
43
I 44
45
46
47
48
49
50
51
52
54
55
56
57
58
59
60
61
S02
10,974
26,004
134,586
0
1,153
8,950
12,066
40,041
48,261
252,963
378
0
141
412,076
171
33,935
127,175
23
6
70
1,355
1,165
5,893
8,169
131
10
60,868
78,812
21,079
27,269
6,435
7,622
3,017
78,395
108,546
67,848
116,568
3,718
731
6,870
3,309
11,197
192,471
2,472
0
0
0
0
0
0
4,548
2,728
S04
153
1,199
25,753
0
0
89,654
146
1,542
8,410
23,396
0
2
1
14,721
1
5,108
2,610
0
258
0
1
1
15
3
0
0
3,258
4,192
376
777
1
42
69
1,392
2,185
998
2,059
5
0
18
141
858
15,397
0
0
0
0
0
0
0
5
4
NOX
1,160
1,371
82,294
0
233,369
74,873
5,020
7,355
30,236
59,709
89,296
1
57
108,544
44
29,748
27,414
1,761,022
95
78
2,984
1,165
9,110
56,379
1,404
171
1,507,815
1,873,278
454,614
578,478
175,568
189,065
69,015
696,487
1,051,202
823,171
756,422
28,787
7,497
69,468
161
83,621
31,625
9,680
0
0
0
0
0
0
126,502
74,374
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
' 0
0
0
64
0
2
0
0
0
6,729
6,717
2,610
2,468
1,813
1,131
2
0
0
0
0
0
0
0
0
0
0
0
0
2
0
0
0
0
0
0
METRIC
CO
36,197
43,270
22,788
0
46,640
5,772,811
210
4,355
7,454
5,353
17,794
2
1
13,909
19
7,004
2,463
235,445
282
3
848,608
8,903
26,473
941,815
26,473
3,134
8,802,939
32,148,186
2,746,546
10,165,693
2,007,498
4,982,687
2,246,824
222,921
653,091
245,672
265,816
137,306
486,569
199,865
4,804
29,264
1,058
1,234,247
0
0
0
0
0
0
4,428,616
2,082,316
TONS/TEAK
HCL
108
19
0
0
0
0
98
54
0
0
0
0
0
966
0
0
0
0
0
0
1,355
5
85
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HF
1
1
0
0
0
0
2
2
0
0
0
0
0
257
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
n
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
3,997
7,172
11,339
0
6,830
936,351
398
253
2,833
20,340
2.432
5
1
4,073
69
2,566
9,550
141
122
17
100,562
6,585
19,168
220,182
4,406
660
631,561
3,016,666
158,963
754,307
39,764
124,898
6,228
121,240
307,466
86,079
51,285
55,963
1,398
2,984
3,203
8,947
14,600
0
0
26,553,364
6,829
0
0
0
537,752
371,867
voc
7,072
8,443
21,284
0
8,904
1,849,195
22
51
1,194
2,537
3,335
1
0
449
1
114
863
3,594
110
1
56,050
1,581
7,518
307,795
8,248
1,266
1,660,984
3,714,674
581,293
1,307,505
213,063
444,321
180,458
101,642
276,795
133,677
218,515
81,144
28,105
80.827
523
25,614
2,213
336,254
876,717
0
0
0
0
0
759,188
334,646
THC
7,224
8,624
21,284
0
20,171
1,888,861
23
52
1,194
2,850
7,554
1
0
459
1
114
970
8,142
112
1
282,851
7,976
37,941
307,795
8,248
1,266
1,790,845
4,005,102
626,741
1,409,731
229,722
479,060
194,791
103,405
281,596
140,385
222,303
82,393
28,537
82.071
534
25,614
2,485
362,961
876,717
0
0
0
0
0
759,188
334,646
A-6
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S EMISSIONS, AREA SOURCES
SCC | S02
62
63
64
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
1 98
99
0
0
58
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
339
670
0
290,784
Cwitig. U.S.| 2,222,054
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
15
37
0
22,229
227,031
HOX
7,662
0
5,983
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
188
4,958
5,152
315,864
11,529,536
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
269
21,806
ntiKii 11
CO
360,618
0
208,960
•o
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
1,085
821
75,858
81,810,673
JNS/TtAK
HCL
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
17
0
0
3,527
6,234
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
1,779
2,042
NH3
0
0
0
88,172
117,734
88,547
40,635
19,198
45,682
134,719
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
17
0
0
3,428
538,140
TSP
54,853
0
51,431
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,163
3
0
379,785
34,702,650
VOC
61,726
0
38,405
0
0
0
0
0
0
0
459,153
272,262
159,494
115,015
429,840
165,636
11,056
142,845
28,645
18,673
47,295
16,490
1,453
1,056
3,350
225,523
310,377
949,965
0
526
117
312,428
17,419,116
THC
61,726
0
38,405
0
0
0
0
0
0
0
459,153
272,262
159,494
115,015
429,840
165,636
11,056
142,845
28,645
18,673
47,295
16,490
1,453
1,056
3,350
227,540
313,153
949,965
0
591
264
317,924
18,434,373
A-7
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY • ANNUAL U.S. EMISSIONS, AREA SOURCES
STATE S02
ALABAMA
ARIZONA
ARKANSAS
CALIFORNIA
COLORADO
CONNECTICUT
DELAWARE
DIST. OF COLUM.
FLORIDA
GEORGIA
IDANO
ILLINOIS
INDIANA
IOUA
KANSAS
KENTUCKY
LOUISIANA
MAINE
MARYLAND
MASSACHUSETTS
MICHIGAN
MINNESOTA
MISSISSIPPI
MISSOURI
MONTANA
NEBRASKA
NEVADA
NEW HAMPSHIRE
NEW JERSEY
NEW MEXICO
NEW YORK
NORTH CAROLINA
NORTH DAKOTA
OHIO
OKLAHOMA
OREGON '
PENNSYLVANIA
RHODE ISLAND
SOUTH CAROLINA
SOUTH DAKOTA
TENNESSEE
TEXAS
UTAH
VERMONT
VIRGINIA
WASHINGTON
WEST VIRGINIA
WISCONSIN
WYOMING
80,040
19,942
31,473
129,034
22,759
29,141
27,780
8,161
84,235
37,687
19,600
114,106
144,303
26,930
34,486
51,676
164,422
18,580
28,208
61,028
43,772
28,224
52,834
62,377
22,691
13,903
7,219
12,063
76,282
12,293
110,225
50,165
19,500
65,723
20,181
31,490
115,853
7,066
28.632
6,966
37,934
270,694
28,203
6,642
65,850
49,122
14,738
28,124
27,038
CONTIG U.S. | 2,449,595
SO4
4,252
1.566
2,142
13,116
1,721
5,882
2,680
722
5,532
2,882
2,078
9,120
9,345
1,381
1,281
5,090
10,581
3,981
4,524
8,521
8.153
4,969
4,230
5,851
1,544
690
553
2,248
14,170
1,263
19,585
8,377
1,386
9,197
2.226
4,616
16,547
1,203
2.727
546
4.925
11.972
1,707
1,727
8.420
5,551
2.378
5.666
1,435
250,259
NOX
255,739
157,130
167,618
1,056.864
165,261
117,244
36,296
22,736
393,835
311,133
83,054
506,040
327,514
180,446
299,084
237,911
273,726
46,327
169,757
193,145
379,705
231,804
198,022
261,760
102,299
120,336
49,281
32,050
285,110
96,923
448,945
275,716
63,744
563,634
294,801
181,873
545,877
32,382
153.172
54.016
245,044
2,021,732
98,147
23,493
260,122
223,387
122,674
225,751
116,478
12,709,138
PB
496
293
261
2,427
314
303
70
37
1,064
652
99
1,117
639
356
249
412
505
121
451
504
972
459
297
561
97
169
101
100
706
170
1,257
706
67
1,184
408
314
1,155
78
374
65
589
1,795
148
62
612
418
203
513
83
24,037
TONS/YEAR ---
CO HCL
1,528,003
1,245,599
910,150
9, 169,893
2,191,485
1,180,569
234,359
334,671
3,926,172
2.173,375
1,238,718
3,934,369
2,078,557
1,050,792
1,011,199
1,477,488
1,542,880
461,937
1,426,057
2,118,954
3,341,867
1,894,733
908,906
2,125,948
1,282,577
599,362
508,333
347,668
2,210,361
905,533
4,644,867
2,162,964
226,659
4,006,231
1,515,621
1,423,588
3,906,891
314,572
1.128,686
494,277
1,797,709
6,937,315
956,285
202,038
1,935,838
2,180,243
631,776
1,847,355
507,399
90,180,829
251
75
25
472
56
105
46
66
164
61
15
1,008
331
71
62
235
121
14
13
86
188
161
12
. 146
9
60
39
10
124
4
69
154
48
446
25
185
640
13
72
15
170
320
41
3
281
120
23
191
26
6,872
HF
21
16
32
14
0
0
0
16
198
17
69
47
120
5
7
73
98
2
47
2
11
7
0
18
0
5
2
0
26
0
5
240
13
755
5
0
21
0
52
1
114
59
16
0
67
28
0
18
4
2,251
NH3
11,362
6,912
13,094
27.360
17,192
1,946
2,050
59
6,906
15,470
8,012
28,657
17,666
61,150
34,093
8,069
4,454
417
2,991
103
10,205
32,196
7,452
17,258
3,705
44,329
704
1
68
4,374
13,959
12,455
6,441
14,322
13,862
4,249
15,758
0
3,420
12.941
7,824
50,179
1,909
3
6,374
8,021
327
31,403
1,500
593,197
TSP
357,944
814,038
840,635
1,400,475
1,081,969
112,066
32,807
14,236
819,404
840,251
318,708
735,514
295,397
1,086,371
1,809,113
324,834
440,200
108,957
191,542
192,880
736.339
1,068,450
562,973
2,566,115
861,449
1,037,379
891,181
62,310
304,009
1,214,514
556,823
584,611
1,246,423
792,991
1,039,691
1,816,674
1,244,910
31,258
308,963
682,573
541,485
5,549,442
628,938
99,345
357,304
261,465
321,511
607,920
458,736
38,253,123
voc
338,923
240,850
207,710
1,919,526
340,410
260,138
51,233
43,630
780,255
481,061
219,441
835,531
475,241
219,375
209,966
338,901
329,807
124,103
303,376
421,496
720,369
403,362
209,239
458,893
224,386
123,167
90,550
87,305
591,931
153,839
1,070,711
531,024
50,658
880,295
261,648
310,452
911,242
71,205
264.087
93,595
420,402
1,411,256
152,488
55,766
440,835
424,675
149,919
413,237
83,781
19,201,289
THC
358,755
257,295
217,992
2,061,809
362,939
274,319
53,859
47,231
816.959
501,843
225,750
892,629
507,003
238,339
225,356
352,949
347,058
130,105
318,323
450,443
770,614
427,656
220,899
489,566
230,514
132,498
96,164
91,764
629,848
162,467
1.125,410
555,007
54,742
941,935
273,463
326,865
950.321
75,722
279.079
98,137
443.920
1,481,514
163,138
58.435
461.677
450,724
156,298
442,178
88,907
20,320,417
A-8
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, AREA SOURCES
S02
S04
METRIC TONS/YEAR
HCL HF
NH3
TSP
ALABAMA
ARIZONA
ARKANSAS
CALIFORNIA
COLORADO
CONNECTICUT
DELAWARE
01 ST. OF COLUM.
FLORIDA
GEORGIA
IDAHO
ILLINOIS
INDIANA
IOWA
KANSAS
KENTUCKY
LOUISIANA
MAINE
MARYLAND
MASSACHUSETTS
MICHIGAN
MINNESOTA
MISSISSIPPI
MISSOURI
MONTANA
NEBRASKA
NEVADA
NEW HAMPSHIRE
NEW JERSEY
NEW MEXICO
NEW YORK
NORTH CAROLINA
NORTH DAKOTA
OHIO
OKLAHOMA
OREGON '
PENNSYLVANIA
RHODE ISLAND
SOUTH CAROLINA
SOUTH DAKOTA
TENNESSEE
TEXAS
UTAH
VERMONT
VIRGINIA
WASHINGTON
WEST VIRGINIA
WISCONSIN
WYOMING
72,611
18,091
28,552
117,058
20,647
26,436
25,202
7,404
76,417
34,189
17,781
103,515
130,909
24,430
31,285
46,880
149,161
16,855
25,590
55,364
39,709
25,604
47,930
56,587
20,585
12,613
6,549
10,943
69,202
11,152
99,994
45,509
17,690
59,623
18,308
28.567
105,100
6,410
25,975
6,319
34,413
245,569
25,585
6,026
59,738
44,563
13,370
25,514
24,528
3,857
1,421
1,943
11,899
1,561
5,336
2,431
655
5,019
2,615
1,885
8,274
8,478
1,253
1,162
4,618
9,599
3,612
4,104
7,730
7,396
4,508
3,837
5,308
1,401
626
502
2,039
12,855
1,146
17,767
7,599
1,257
8.343
2,019
4,188
15,011
1,091
2,474
495
4,468
10,861
1,549
1,567
7,638
5,036
2,157
5,140
1,302
232,003
142,546
152,060
958,771
149,922
106,362
32,927
20,626
357,281
282,255
75,345
459,072
297,116
163,698
271,324
215,829
248,320
42,027
154,001
175,218
344,463
210,289
179,643
237,465
92,804
109,167
44,707
29,075
258,647
87,927
407,276
250,125
57,828
511,320
267,439
164,992
495,211
29,376
138,955
49,002
222,300
1,834,084
89,037
21,312
235,979
202,653
111,288
204,798
105,667
450
266
239
2,202
285
275
64
34
965
591
90
1,013
580
323
226
374
458
112
409
457
882
416
269
509
88
153
92
91
640
154
1,140
640
61
1,074
370
285
1,048
71
339
59
534
1.628
134
56
555
379
184
465
75
1,386,181
1,129,988
825,674
8,318,787
1,988,082
1,070,994
212,607
303', 608
3,561,763
1,971,653
1,123,746
3,569,200
1,885,635
953,262
917,344
1,340.355
1,399,677
419,062
1,293,697
1,922,283
3,031,691
1,718,873
824,546
1,928,628
1,163,534
543,732
461,152
315,399
2,005,206
821,486
4,213,753
1,962,208
205,622
3,634,392
1,374,948
1,291,457
3,544,272
285,375
1,023,927
448,401
1,630,854
6,293,426
867,527
183,286
1,756,163
1.977,883
573,138
1,675,892
460,305
228
68
23
428
51
95
42
60
149
55
14
914
300
64
56
213
110
13
12
78
171
146
11
132
8
54
35
9
112
4
63
140
44
405
23
168
581
12
65
14
154
290
37
3
255
109
21
173
24
19
15
29
13
0
0
0
15
180
15
63
43
109
5
6
66
89
2
43
2
10
6
0
16
0
5
2
0
24
0
5
218
12
685
5
0
19
0
47
1
103
54
15
0
61
25
0
16
4
10,307
6,270
11,879
24,821
15,596
1,765
1,860
54
6,265
14,034
7,269
25,997
16,026
55,475
30,929
7,320
4,041
379
2,713
94
9,258
29,208
6,760
15,656
3,361
40,214
639
1
62
3,968
12,663
11,299
5,843
12,992
12,575
3,855
14,295
0
3,103
11,739
7,097
45,521
1,732
2
5,782
7,277
296
28,488
1,361
324,721
738,483
762,611
1,270,490
981,546
101,665
29,762
12,915
743,351
762,263
289,127
667,247
267,980
985,539
1,641,200
294,684
399,343
98,844
173,764
174,978
667,996
969,282
510,721
2,327,940
781,493
941,094
808,466
56,527
275,792
1,101,789
505,141
530,350
1,130,736
719,389
943,192
1,648,059
1,129,363
28,357
280,287
619,220
491,227
5,034,369
570,563
90,124
324,141
237,197
291,670
551,496
416,158
307,466
218,495
188,431
1,741,365
308,815
235,993
46,477
39,581
707,835
436,411
199,074
757,981
431,131
199,014
190,477
307,445
299,195
112,585
275,218
382,374
653,507
365,924
189,819
416,300
203,560
111,735
82,145
79,202
536,991
139,561
971,333
481,737
45,956
798,590
237,363
281,638
826,664
64,596
239.576
84,908
381,382
1,280*270
138.335
50,590
399,919
385,259
136,004
374,882
76,005
325,457
233,414
197,759
1,870,442
329,252
248,858
48,860
42,847
741,135
455,264
204,797
809,780
459,945
216,218
204,439
320,190
314,845
118,029
288,777
408,635
699,089
387,963
200,396
444,126
209,119
120,200
87,238
83,247
571,389
147,388
1,020,955
503,494
49,662
854,509
248,082
296,527
862,116
68,694
253,176
89,028
402,718
1,344,007
147,996
53,011
418,827
408,890
141,791
401,137
80,655
CONTIG U.S. | 2,222,054 227,031 11,529,536
21,806 81,810,673
6,234
2,042 538,140 34,702,650 17,419,117 18,434,372
A-9
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, AREA SOURCES
EPA REGION | S02
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
CONTIG
1
^-
O
1 134,520
2
3
4
5
6
7
8
9
186.507
260,590
423,203
424,252
499,063
137.696
127.157
156,195
10 100,212
U.S. | 2,449,395
S04
23,562
33,755
35,271
38,015
46,450
28,184
9.203
8,339
15,235
12,245
250,259
NOX
444,641
734,055
1,157,462
2,070,572
2,234,448
2,854,800
861,626
599,945
1,263,275
488.314
12,709.138
PB
1,170
1,963
2,528
4,590
4,884
3,141
1,335
774
2,821
831
24.037
IUNS/TtAK
CO HCL
4,625,738
6,855,228
8,469,592
15,103,303
17,103,112
11,811,499
4,787,301
5.658,682
10,923.825
4,842,549
90,180,829
EPA REGION | S02
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
CONTIG
1
2
3
4
5
6
7
8
9
10
122,034
169.196
236,403
383,923
384,875
452,742
124,916
115,355
141,698
90,911
U.S. | 2,222,054
S04
21,375
30,622
31,997
34,487
42,139
25,568
8,349
7,565
13,821
11,108
227,031
NOX
403,372
665,924
1,050,032
1,878,391
2,027,057
2,589,831
781,654
544,261
1,146,024
442,991
11,529,536
PB
1,061
1,781
2,293
4,164
4,431
2,849
1,211
702
2,559
754
21,806
CO
4.196,399
6,218,958
7,683,485
13,701,486
15,515,682
10,715,212
4,342,966
5,133,470
9,909,927
4,393,087
81,810,673
231
193
1,069
1,119
2.325
495
339
195
586
320
6,872
HCL
210
175
970
1,015
2,109
449
308
177
532
290
6,234
HF
4
31
151
715
958
194
35
34
32
97
2,251
HF
4
28
137
649
869
176
32
31
29
88
2,042
NH3
2,470
14.026
27.558
72,957
134,448
85.962
156.830
43,688
34,976
20.282
593.197
NH3
2,241
12,725
25,000
66,185
121,969
77,984
142,274
39,633
31,730
18,400
538,140
TSP
606,816
860,832
2.162.310
4,340,465
4.236,611
9,084,482
6.498,978
4,960,088
3,105,694
2,396,847
38,253,123
TSP
550,494
780,934
1,961,615
3,937,604
3.843,389
8,241,304
5,895,774
4,499,716
2,817,438
2,174,383
34,702,650
VOC
1,020.013
1,662,642
1,900,234
3,363,893
3,728,034
2.364,260
1.011,400
945,319
2,250,925
954,569
19,201,289
VOC
925,340
1,508,324
1,723,864
3,051,672
3,382,015
2,144,821
917,527
857,579
2,042,005
865,970
17,419,117
THC
1,080,788
1.755.258
1,987,708
3,529,412
3,982,016
2,482.493
1,085,758
998.377
2,415.267
1,003,339
20,320.417
THC
980,475
1,592.344
1,803.219
3,201,828
3,612,424
2,252,080
984.983
905.713
2,191,093
910,214
18,434,372
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY • ANNUAL U.S. EMISSIONS, POINT SOURCES
sec
101002
101003
101004
101005
101006
102001
102002
102003
102004
102005
102006
102007
102008
102009
102010
102011
102012
102013
103001
103002
103003
103004
103005
103006
103009
103012
103013
103900
105001
105002
199999
201001
201002
202001
202002
202003
202004
203001
203002
204001
204004
299999
301001
301003
301005
301006
301007
301008
301009
301010
301011
301012
S02
15,793,408
279.553
1,385,537
8,359
968
3,590
1,187,896
52,631
1,045,988
95,558
41,503
301,546
4,471
15,464
54
616
3,448
17,505
309
83,411
1,804
81,373
20,061
619
265
0
0
0
31,800
955
8,675
9,741
26
3,215
4,917
9
10
10
3
195
58
0
1,465
1,415
19,919
1,820
0
0
751
80
0
125
S04
338,017
36,021
41,110
1,035
0
277
43,699
3,039
22,414
4,104
204
1,114
16
70,815
0
0
0
0
17
3,087
119
10,099
990
0
1,418
0
0
0
165
615
0
17
0
13
0
0
0
0
0
0
0
0
0
4
0
0
0
0
0
0
0
0
NOx
4,979,030
201,285
393.478
5,247
744,528
2,008
391,054
11,804
281,449
39,258
514,983
101,959
1,206
97,272
178
1,885
1,860
2,807
110
19,098
339
32,493
3,491
39,538
2,739
0
0
0
11,095
907
2,518
31,411
81,740
13,573
642,808
165
702
506
818
678
884
535
4,584
6,967
1,262
20,580
0
0
118
2,363
0
0
Pb
30
5
0
0
0
0
28
0
0
0
0
0
0
0
0
0
0
366
0
1
0
0
0
0
0
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
160,708
13,569
39,829
1,105
68,311
116
35,225
3,691
53,251
7,814
107,103
14,157
19,147
103,091
23
1,443
15
114
4
4,435
341
2,352
1,010
4,936
1,711
0
0
0
43,506
222
498
6,994
16,567
3,656
112,937
6,440
183
80
1,366
474
1,200
118
28,485
62,182
1,841,589
70,711
0
100
23
0
160
0
1UNS/TtAK-
HCl
474,292
158
0
0
0
374
31,492
258
0
0
0
0
0
0
0
0
0
0
21
1,730
18
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
731
0
KF
57,413
158
0
0
0
16
12,210
44
0
0
0
0
0
0
0
0
0
0
0
185
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
133
7
0
0
0
0
10
1
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3,108
0
0
0
0
0
0
0
0
TSP
521,611
52,263
54,266
94
4,620
252
347,169
24,348
79,592
6,362
17,099
11,388
2,060
91,961
58
8,872
1,813
650
403
29,094
2,060
33,884
10,236
1,300
1,059
31
1
3
3,102
131
1,219
2,187
1,420
817
3,158
187
47
14
9
156
210
0
97
518
2,848
76,161
0
54
1,034
998
51
1,020
voc
25,827
2.022
12,677
45
1,362
10
6,455
132
50,266
16,029
12,809
7,567
296
62,442
10
4,053
22
64
3
950
29
1,353
877
1,174
926
0
6
0
3,470
218
1,230
1,984
2,018
1,517
12,183
274
17
19
10
76
370
1
9,119
15,468
189,542
94,612
727
370
599
714
42
0
THC
26,382
• 2,065
14,244
45
3,096
18
6,594
135
56,431
16,029
29,109
11,254
302
63,785
22
4,053
22
64
3
970
' 30
1,521
877
2,668
946
0
6
0
5,210
218
1,230
2,318
7,627
1,772
83,323
330
20
22
73
545
432
1
9,119
15,468
189,542
94,612
733
370
599
714
96
0
A-ll
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY • ANNUAL U.S. EMISSIONS, POINT SOURCES
sec
301013
3010U
301015
301016
301017
301018
301019
301020
301021
301022
301023
301024
301025
301026
301027
301028
301029
301030
301031
301032
301033
301034
301035
301036
301040
301041
301042
301050
301060
301091
301100
301111
301120
301125
301130
301132
' 301137
301156
301167
301169
301174
301181
301197
301202
301206
301250
301251
301253
301254
301258
301820
301830
S02
7,325
4,558
0
11,975
1
1,808
366
0
243
7,705
288,797
7,466
604
5,054
1,002
1,049
5,976
8,681
0
251,892
790
1,084
11,244
0
0
1,909
0
0
226
38
0
0
0
250
0
69
480
0
0
0
0
0
2,964
0
0
1
0
0
24
0
243
0
S04
0
0
0
0
0
0
5
0
0
0
1,430
0
0
0
0
0
0
0
0
3,078
0
0
4
0
0
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NOx
47,931
0
0
0
84
304
0
0
472
0
377
2
0
297
1,944
0
15
8,166
0
674
677
3,605
1,433
0
0
0
12
0
12
44
0
0
8
53
0
669
7
0
0
0
0
0
369
0
0
2,666
0
0
225
0
0
0
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
5,558
0
0
12
0
223
22,015
0
4,972
0
1,215
4,165
0
19,004
8,122
0
4
4
35,858
2,343
0
113
27,421
0
0
112
0
0
174
0
13,238
0
2
0
0
175
45
0
0
0
0
10
1,462
0
0
3,964
0
0
5,927
50
67
0
TONS/YEAR-
HCt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
c
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HF
0
0
0
1,650
0
0
0
0
0
0
0
0
0
0
0
0
29,824
1,933
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
224,793
0
0
766
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
1,331
1,862
10
1,067
376
58,550
7,193
6
4,872
360
15,830
1,206
42
1,440
11,234
3,410
616
8,205
289
982
27
415
1,645
315
4,807
334
20
0
3,947
0
0
87
378
16
63
271
0
0
0
0
0
0
61
0
0
5
0
0
0
3
30
182
voc
1,491
16,010
5,955
0
11
105,497
567
1,769
218
0
61
17,219
21,830
90,128
45
0
3
32
58,475
1,404
2,739
2,677
5
0
0
3,256
1,929
1,189
1,509
797
248
0
1,349
2,107
151
4,572
324
130
137
380
1,662
99
23,003
1,020
520
1,371
999
106
8,354
7,406
1,855
0
THC
1,491
16,010
5,955
0
11
106,322
2,042
1,769
218
0
63
17,219
22,219
90,128
45
0
3
32
58,475
1,404
2,739
2,711
6
0
0
3,31*
1,929
1,210
1,535
797
248
0
1,349
2,107
250
4,648
330
130
137
380
1,692
99
23,003
1,020
520
1,371
999
106
8,354
7,449
1,855
0
A-12
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
sec
301888
301900
301999
302001
302002
302004
302005
302006
302007
302008
302009
302010
302012
302013
302014
302015
302016
302017
302018
302019
302020
302026
302030
302031
302032
302033
302888
302999
303000
303001
303002
303003
303004
303005
303006
303007
303008
303009
303010
303011
303012
303013
303014
303023
303030
303888
303999
304001
304002
304003
304004
304005
S02
247
182,612
57,725
1
0
0
18
6
198
512
1,264
0
0
0
106
1,674
699
0
0
0
0
0
0
0
1,196
0
0
1,241
0
87,605
1,403
75,716
30
1,099,046
387
92
63,405
53,762
57,902
1,939
0
0
2,203
10,609
37,793
3
2,758
1,086
6
7,305
26,595
0
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
561
0
12,742
0
35,393
0
0
738
0
1,532
0
0
0
0
34
11,227
0
0
0
0
9
98
0
NOx
5
510
32,764
197
62
0
1
88
27
5
127
0
0
1
0
0
355
0
0
0
0
0
1
0
0
0
2
426
0
131.298
984
4.271
4
1,038
110
0
17,676
29.971
3
0
164
0
206
0
100
1
120
8,852
932
1,276
358
0
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
160
59
0
1,246
1,679
887
0
0
0
0
0
385
0
0
0
228
497
276
0
CO
36
24
241,373
15
48
0
0
53
3
17
14
0
0
72
0
18
25
0
0
0
0
0
0
0
0
0
26
16
0
678.962
163
37,997
11
7,211
282
363
1.115,635
369,322
43,930
0
4,993
0
5,941
0
17
0
552
983
3,732
491,060
160
0
TONS/TEAR-
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9,749
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
762
0
0
0
0
0
0
0
0
0
0
7,373
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
12,570
411
52,092
18,573
1,977
618
45.098
200,334
43,120
9,680
1,615
614
3
28
1,586
1,684
7,834
535
0
109
2,550
0
147
487
19
0
382
5,116
5,698
46,980
21,303
58,581
2,168
20,562
28,206
1,230
163,355
64,061
7,129
3,969
1
0
2,636
68,416
8,857
1,849
1,052
11,579
4,850
36,836
8,690
0
VOC
467
651
211,348
4
48
0
0
0
761
2
405
24,034
26
840
0
0
7
0
18
780
0
0
0
0
4
1,913
15
371
0
15,458
9
32,629
40
17
19
0
4,327
4,270
0
73
0
0
427
0
3
0
84
3,652
177
1,822
3,292
0
TKC
475
651
211,348
4
48
0
0
0
7,045
2
2,171
24,034
336
858
0
0
7
0
237
10,183
0
0
0
0
57
1,913
162
4,540
0
33,098
9
69,863
86
20
22
0
17,794
4,451.
0
73
0
0
427
0
6
0
205
5,769
280
4,468
5,201
0
A-13
-------
1980 KAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
sec |
304004
304007
304008
304009
304010
304020
304022
304034
304050
304888
304999
305001
305002
305003
305004
30500S
305006
305007
305008
305009
305010
305011
305012
305013
3050 H
305015
305016
305017
305018
305019
305020
305021
305022
305024
305025
305026
305031
305032
305040
305100
305103
305888
305999
306001
306002
306003
306004
306005
306006
306007
306008
306009
S02
32
6,809
1,714
0
0
767
1
67
0
0
2,677
10
42,343
6.288
166
829
187,090
158,859
457
472
11,673
0
5,532
0
28,602
259
15,937
1,278
0
26,487
2,003
440
0
0
78
3
0
0
5,514
120
0
292
6,910
296,609
263,612
9,474
12,150
1,344
1,229
0
1,984
16,083
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
26
1
0
2,266
7,611
0
0
36
0
15
0
87
13,205
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
747
8,594
11
56
0
0
0
0
0
NOx
3
3,731
616
0
0
33
885
170
0
0
273
3
9,600
3,675
0
901
53,312
58,727
126
187
3,643
4,386
5,, '25
0
42,809
68
27,491
128
0
648
652
621
0
64
64
10
0
0
2,468
0
0
0
1,773
194,109
45,604
451
8,553
14
118
0
2,486
1,804
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
302
207
0
0
0
0
0
0
991
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
6,390
5,332
17
0
0
3
27
0
554
0
252
2,330
5,992
1,981
45
64
1,296
2,227
1
4
137
86
1,030
0
10,815
16
29,711
10,806
0
3
33
0
0
43
3
6
0
1
382
0
0
258
8,282
18,384
1,363,517
102,795
1,910
34
9
0
132
104
TONS/YEAR-
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8,427
87
0
0
0
0
0
0
TSP
149
6,419
3,046
139
0
786
128
0
25
77
3,190
4,647
73,020
128,969
474
8,044
135,301
214,451
20,986
9,518
54,260
3,526
19,030
96
14,784
21,655
86,894
3,109
1,078
17,411
354,666
827
2,530
13,609
21,164
617
292
83
32,457
1,233
634
3,216
36,960
18,730
45,761
3,097
17
240
5
0
163
391
voc
0
104
4
0
0
166
206
0
477
1
563
2,875
619
819
306
19
433
452
35
10
2,267
6
1,480
74
1,950
8
1,009
49
49
0
60
0
0
0
1
0
0
946
41
0
0
174
2,158
6,278
63,337
2,294
15,632
107,178
34,549
6,851
81,570
5,809
THC
0
254
6
0
0
166
325
0
753
1
890
2,881
1,408
1,708
306
45
486
512
95
28
2,316
16
4,229
211
5,319
11
1,031
78
141
1
171
0
0
0
2
0
0
2,702
116
0
0
174
6,167
11,405
98,954
3,584
18,317
112,366
42,465
6,851
93,104
11,620
A-14
-------
1980 NAPAP 5.0 £MISSIONS INVENTOR? - ANNUAL U.S. EMISSIONS, POINT SOURCES
sec
306010
306011
306012
3060 U
306100
306888
306999
307001
307002
307003
307004
307005
307007
307008
307011
307013
307020
307030
307888
307999
308001
308006
308007
309001
309002
309010
309011
309020
309030
309060
309888
309999
310001
310002
312999
320999
330001
330002
330003
330004
390001
390002
390004
390005
390006
390007
390008
390009
390010
390012
390013
399999
S02
0
84
19,455
4,021
0
469
61,103
106,094
30,417
10
0
0
372
3,073
5
0
2
7
0
919
0
0
0
0
0
0
0
0
0
0
0
140
1,038
1,075
0
0
43
0
1
0
903
71.893
46,919
4,029
38.151
13,403
5,601
0
0
62
0
29,212
S04
0
0
0
0
0
0
0
41,572
5,444
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
0
0
0
0
0
0
0
192
64
9
109
0
2
0
0
0
0
0
NOx
0
52
2,090
1,211
0
241
5,656
47,450
1,846
0
55
0
4,800
3,668
0
0
0
48
0
683
0
122
0
0
0
0
0
4
0
0
0
390
0
2,904
7
0
19
0
1
0
2,029
2,763
6,687
3,550
28,222
2,379
1,111
342
10
0
0
14,600
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
0
388
6
47
0
0
57,420
713,756
276
0
0
0
1,471
763
0
0
0
148
0
9,561
0
34
0
0
0
0
0
1
0
0
0
3
0
1,593
2
0
3
0
1
0
120
29,478
1,005
1.785
52,259
22,220
34,160
0
1
0
0
77,163
TONS/TtAK-
HCI
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Hf
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
0
36
51,386
1,786
0
174
3,376
78,608
2,767
89
1,242
1
45,723
13,221
0
0
13,270
2,739
843
5,243
182
254
124
93
765
77
0
61
2,669
135
90,275
2,022
720
502
240
4
1,223
98
85
14
428
8,569
3,057
4,251
11,429
2,515
426
1,612
846
10
0
48,893
VOC
1,419
50,007
1,928
236
2,796
20,992
35,893
11,513
237
176
2,157
244
6,559
1,923
8,488
157
4,579
189
714
1,617
11,073
1,033
6,813
467
0
1,992
49
4,450
754
0
69
3,198
13,139
804
0
419
22,377
3,766
82
94
6
664
1,719
860
11,261
234
46
130
756
0
0
90,446
THC
1,419
60,326
3,012
536
2,796
30,153
54,718
11,682
237
176
2,157
244
6,559
1,923
8,488
157
4,579
189
714
1,617
11,073
1,033
6,813
737
0
2,758
67
7,031
1,045
0
96
3,198
13,139
862
0
419
22,377
3,766
82
94
6
678
1,931
860
25,493
404
46
130
1,718
0
0
205,538
A-15
-------
1980 NAPAP S.O EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
SCC | S02
401001
401002
401003
401888
401913
402001
402002
402003
402004
402005
402006
402007
402008
402009
402010
402011
402013
402014
402016
402017
402018
402019
402020
402021
402022
402023
402024
402025
402888
402901
402999
403001
403002
403003
403010
403011
403012
403888
403999
404001
404002
405001
405002
405003
405004
405005
405006
405888
406001
406002
406003
406004
0
327
0
0
0
2
0
0
0
0
0
2
193
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
0
0
425
0
0
0
4.350
0
0
223
0
0
0
0
0
0
0
0
3
0
0
0
0
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NOx
0
2
1
0
0
318
0
0
8
297
7
18
180
619
50
0
0
0
0
496
2
0
0
0
0
0
0
0
0
0
685
4
0
0
100
972
0
0
0
80
0
11
11
290
6
30
0
0
0
0
0
0
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TONS/YEAR--
CO HCl
0
3
0
0
0
84
0
0
1
183
1
2,048
575
42
13
0
0
0
0
83
0
0
0
0
0
0
0
0
0
0
557
1
0
0
66,886
33,443
0
0
88
0
0
U
0
38
0
17
0
0
100,329
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
0
205
0
0
0
1,093
0
103
455
486
1,129
69
1,504
818
11
0
0
0
3
0
0
0
0
0
0
49
2
0
0
0
8,724
1,720
134
0
357
1,110
0
0
359
2,982
0
53
0
45
0
423
0
0
1,737
2
32
16
VOC
7,633
100,419
921
407
66
245,536
2,015
34,008
140,729
122,551
78,612
22,573
21,367
221,147
3,858
1,928
16,518
103
923
31.769
314
337
475
HO
5,060
245
18
1,655
29,090
64
88,798
161,522
66,658
3,839
41,475
34,742
23,430
4,627
29,774
113,930
2,205
24,311
3,664
15,344
27,533
66,633
420
561
90,703
21,748
5,748
8,866
THC
7,633
100,419
921
407
66
245,536
2,015
34,008
140.729
122,551
78,612
22,573
61,451
221,147
3,858
1,928
16,518
103
923
32,037
314
337
519
140
5,060
245
18
1,655
29,090
64
88,798
170,891
67,330
3,868
42,274
34,984
23,430
4,736
29,774
113,930
2,205
101,339
15,157
15,344
27,533
66,633
420
1,055
91,457
22,615
5,748
8,866
A-16
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
sec
406888
490001
490999
501001
501002
501005
501900
501999
502001
502002
502003
502005
502900
503001
503002
503005
503007
503900
599999
S02
0
0
0
5,322
281
381
1,139
6
2,101
0
0
1,881
535
17,600
63
875
0
2,081
156
S04
0
0
0
9
0
0
0
0
4
0
0
12
0
4
0
2
0
0
0
NOx
0
0
3
5,580
1,747
1,602
0
0
1,988
16
0
11,794
10
7,847
666
2,690
0
806
0
Pb
0
0
0
143
0
2
0
0
79
0
0
23
0
93
0
4
0
0
0
I
CO
0
0
0
58,001
25,938
1,988
20
34
14,550
577
0
0
1
218,560
22,412
351
0
2,293
0
UNS/ICAK
HCI
0
0
0
5,357
0
26
0
0
2,104
0
0
0
0
3,091
0
0
0
0
0
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
JH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
0
0
445
12,541
4,905
5,968
287
30
1,837
70
0
1,924
125
19,264
1,765
16,130
95
589
0
VOC
3,147
2,116
95,261
1,311
12,612
72
0
6
1,228
35
0
382
82
5,500
4,243
80
0
181
19
THC
3,147
2,902
130,632
6,682
12,612
406
2
6
2,646
177
0
2,262
187
28,037
7,369
476
0
925
98
Contig. U.S. | 24,504,741 725,349 9,643,101 7,695 9,128,108 519,652 113,183 245,467 4,364,247 3,963,258 4,657,042
A-17
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY • ANNUAL U.S. EMISSIONS, POINT SOURCES
sec |
101002 | U
101003 |
101004 | 1
101005 |
101006 |
102001 |
102002 | 1
102003 |
102004 |
102005 |
102006 |
102007 |
102008 |
102009 |
102010 |
102011 |
102012 |
102013 |
103001 |
103002 |
103003 |
103004 |
10300S |
103006 |
103009 |
103012 |
103013 |
103900 |
105001 |
10S002 |
199999 |
201001 |
201002 |
202001 |
202002 |
202003 |
202004 |
203001 |
203002 |
204001 |
204004 |
299999 |
301001 |
101003 |
301005 |
301006 |
301007 |
301008 |
301009 |
301010 |
301011 |
301012 |
S02
,327,814
253,611
,256,962
7,583
878
3,257
,077,662
47,747
948,923
86,690
37,652
273,564
4,056
14,029
49
559
3,128
15,881
280
75,671
1,637
73.821
18,199
562
240
0
0
0
28,849
866
7,870
8,837
24
2,917
4,461
8
9
9
3
177
53
0
1,329
1,284
18,071
1,651
0
0
681
73
0
113
S04
306,650 4
32,678
37,295
939
0
251
39,644
2,757
20,334
3,723
IBS
1,011
15
64,244
0
0
0
0
15
2.801
108
9,162
898
0
1,286
0
0
0
150
558
0
15
0
12
0
0
0
0
0
0
0
0
0
4
0
0
0
0
0
0
0
0
NOx
,516,987
182,606
356,964
4,760
675,437
1,822
354,765
10,709
255,331
35,615
467,194
92,497
1,094
88,245
161
1,710
1,687
2,547
too
17,326
308
29,478
3,167
35,869
2,485
0
0
0
10,065
823
2,284
28.496
74,155
12,313
. 583,157
150
637
459
742
615
802
485
4,159
6,320
1,145
18,670
0
0
107
2,144
0
0
Pb
27
5
0
0
0
0
25
0
0
0
0
0
0
0
0
0
0
332
0
1
0
0
0
0
0
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
METRIC TONS/YEAR
CO HCl HF
145,795
12,310
36,133
1,002
61,972
105
31,956
3,348
48,309
7,089
97,164
12,843
17,370
93,524
21
1,309
14
103
4
4,023
309
2,134
916
4,478
1,552
0
0
0
39,469
201
452
6,345
15,030
3,317
102,457
5,842
166
73
1,239
430
1,089
107
25,842
56,412
1,670,694
64,149
0
91
• 21
0
145
0
430,279
143
0
0
0
339
28,570
234
0
0
0
0
0
0
0
0
0
0
19
1,569
16
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
663
0
52,085
143
0
0
0
15
11,077
40
0
0
0
0
0
0
0
0
0
0
0
168
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3 TSP
121 473,207
6 47,413
0 49,230
0 85
0 4,191
0 229
9 314,953
1 22,089
0 72,206
0 5,772
0 15,512
0 10,331
0 1,669
0 83,427
0 53
0 8,049
0 1,645
0 590
0 366
1 26,394
0 1,869
0 30,740
0 9,286
0 1,179
0 961
0 28
0 1
0 3
0 2.814
0 119
0 1.106
0 1,984
0 1,288
0 741
0 2,865
0 170
0 43
0 13
0 8
0 142
0 191
0 0
0 88
2,820 470
0 2,584
0 69,093
0 0
0 49
0 938
0 905
0 46
0 925
VOC
23,430
1.834
11,500
41
1,236
9
5,856
120
45,601
14,541
11,621
6,865
268
56,648
9
3,677
20
58
3
861
27 '
1,228
796
1,065
840
0
5
0
3,148
198
1,116
1,800
1,831
1,376
11,052
249
16
17
9
69
336
1
8,272
14,033
171,953
85,832
660
336
543
648
38
0
THC
23,934
1.873
12,922
41
2,809
17
5,982
122
51,239
14,541
26,408
10,210
274
57,866
20
3,677
20
58
3
880
27
1,379
796
2.420
858
0
5
0
4,727
198
1,116
2,103
6,919
1,608
75,591
290
18
20
66
494
392
1
8,272
14,033
171,953
85.832
665
336
543
648
87
0
A-18
-------
1980 NAPAP 5.0 EMISSIONS INVEMTORr • ANNUAL U.S. EMISSIONS, POINT SOURCES
SCC | S02
301013
301014
301015
301016
301017
301018
301019
301020
301021
301022
301023
301024
301025
301026
301027
301028
301029
301030
301031
301032
301033
301034
301035
301036
301040
301041
301042
301050
301060
301091
301100
301111
301120
301125
301130
301132
301137
301156
301167
301169
301174
301181
301197
301202
301206
301250
3012S1
301253
301254
301 258
301820
301830
6,645
4,135
0
10,864
1
1,640
332
0
220
6,990
261,997
'6,773
548
4,585
909
952
5,421
7,875
0
228,517
717
983
10,201
0
0
1,732
0
0
205
34
0
0
0
227
0
63
435
0
0
0
0
0
2,689
0
0
1
0
0
22
0
220
0
S04
0
0
0
0
0
0
5
0
0
0
1,297
0
0
0
0
0
0
0
0
2,792
0
0
4
0
0
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NOx
43,483
0
0
0
76
276
0
0
428
0
342
2
0
269
1,764
0
14
7,408
0
611
414
3,270
1,300
0
0
0
11
0
11
40
0
0
7
48
0
607
6
0
0
0
0
0
335
0
0
2,419
0
0
204
0
0
0
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
5,042
0
0
11
0
202
19,972
0
4,511
0
1,102
3,778
0
17,240
7,368
0
4
4
32,530
2,126
0
103
24,876
0
0
102
0
0
158
0
12,010
0
2
0
0
159
41
0
0
0
0
9
1,326
0
0
3,596
0
0
5,377
45
61
0
METRIC TONS/YEAR--
HCl MF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,497
0
0
0
0
0
0
0
0
0
0
0
0
27,056
1,754
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
203,933
0
0
695
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
1,207
1,689
9
968
341
53,117
6,526
5
4,420
327
14,361
1,094
38
1,306
10,192
3,094
559
7,444
262
891
24
J76
1,492
286
4,361
303
18
0
3,i81
0
0
79
343
15
57
246
0
0
0
0
0
q
55
0
0
5
0
0
0
3
27
165
voc
1,352
14,524
5,402
0
10
95,707
514
1,605
198
0
56
15,621
19,804
81,764
41
0
3
29
53,049
1,274
2,485
2,428
4
0
0
2,954
1,750
1,079
1,369
723
225
0
1,224
1,911
137
4,147
294
118
124
345
1,508
90
20,868
925
472
1,244
906
96
7,579
6,719
1,683
0
THC
1,352
14,524
5,402
0
10
96,456
1,853
1,605
198
0
57
15.621
20,157
81,764
41
0
3
29
53,049
1,274
2,485
2,460
6
0
0
3,006
1,750
1,098
1,392
723
225
0
1,224
1,911
227
4,217
299
118
124
345
1,535
90
20,868
925
472
1,244
906
96
7,579
6,758
1,683
0
A-19
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
SCC | S02
..„..-..„„..-- +
301888
301900
301999
302001
302002
302004
30200S
302006
302007
302008
302009
302010
302012
302013
3020U
302015
302016
302017
302018
302019
302020
302026
302030
302031
302032
302033
302888
302999
303000
303001
303002
303003
303004
303005
303006
303007
303008
303009
303010
30301 1
303012
303013
3030 H
303023
303030
303888
303999
304001
304002
304003
304004
304005
224
165,666
52,368
1
0
0
16
5
180
464
1,147
0
0
0
96
1,519
634
0
0
0
0
0
0
0
1,085
0
0
1,126
0
79,475
1,273
68,690
27
997,057
351
83
57,521
48,773
52,529
1,759
0
0
1,999
9,625
34,286
3
2,502
985
5
6,627
24,127
0
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
509
0
11,560
0
32,109
0
0
670
0
1,390
0
0
0
0
31
10,185
0
0
0
0
8
89
0
NOx
5
463
29,724
179
56
0
1
80
24
5
115
0
0
1
0
0
322
0
0
0
0
0
1
0
0
0
2
386
0
119,114
893
3,875
4
942
100
0
16,036
27,190
3
0
149
0
187
0
91
1
109
8,031
846
1,158
325
0
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
145
54
0
1,130
1,523
805
0
0
0
0
0
349
0
0
0
207
451
250
0
METRIC
CO HCI
33
22
218,974
14
44
0
0
48
3
15
13
0
0
65
0
16
23
0
0
0
0
0
0
0
0
0
24
15
0
615,956
148
34,471
10
6,542
256
329
1,012,107
335,050
39,853
0
4,530
0
5,390
0
15
0
501
892
3,386
445,491
145
0
TONS/TEAR-- -
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8,844
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NK3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
691
0
0
0
0
0
0
0
0
0
0
6,689
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
11,404
373
47,258
16,849
1,794
561
40,913
181,743
39,119
8,782
1,465
557
3
25
1,439
1,528
7,107
485
0
99
2,313
0
133
442
17
0
347
4,641
5,169
42,620
19,326
53,145
1,967
18,654
25,589
1,116
148,196
58,116
6,467
3,601
1
0
2,391
62,067
8,035
1,677
954
10,504
4,400
33,418
7,884
0
VOC
424
591
191,735
4
44
0
0
0
690
2
367
21,804
23
762
0
0
6
0
16
707
0
0
0
0
4
1,735
14
336
0
14,024
8
29,601
36
15
17
0
3,925
3,873
0
66
0
0
387
0
3
0
76
3,313
161
1,653
2,987
0
THC
431
591
191,735
4
44
0
0
0
6,391
2
1,970
21,804
305
778
0
0
6
0
215
9,238
0
0
0
0
52
1,735
147
4,391
0
30,027
8
63,380
78
18
20
0
16,143
4,038
0
66
0
0
387
0
5
0
186
5,234
254
4,053
4,718
0
A-20
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY • ANNUAL U.S. EMISSIONS, POIHI SOURCES
SCC | S02
304006
304007
304008
304009
304010
304020
304022
304034
3040SO
304888
304999
305001
305002
305003
305004
305005
305006
305007
305008
305009
305010
305011
30S012
305013
305014
305015
305016
305017
305018
305019
305020
305021
305022
305024
305025
305026
305031
305032
305040
305100
305103
305888
305999
306001
306002
306003
306004
306005
306006
306007
306008
306009
29
6,177
1,555
0
0
696
1
61
0
0
2,429
* 9
38,414
5,704
151
752
169,728
144,117
415
428
10,590
0
5,019
0
25,948
235
14,458
1,159
0
24,029
1,817
399
0
0
71
3
0
0
5,002
109
0
26S
6,269
269,085
239,149
8.595
11,023
1,219
1,115
0
1,800
14,591
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
24
1
0
2,056
6,905
0
0
33
0
14
0
79
11,980
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
678
7,796
10
51
0
0
0
0
0
NOx
3
3,385
559
0
0
30
803
154
0
0
248
3
8,709
3,334
0
817
48,365
53,277
114
170
3,305
3,979
5,194
0
38,836
62
24,940
116
0
588
591
563
0
58
58
»
0
0
2,239
0
0
0
1,608
176,096
41,372
409
7,759
13
107
0
2,255
1,637
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
274
188
0
0
0
0
0
0
899
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
5,797
4,837
15
0
0
3
24
0
501
0
229
2,114
5,436
1,797
11
58
1,176
2,020
1
4
124
7*
934
0
9,811
15
26,954
9,803
0
3
30
0
0
39
3
5
0
1
347
0
0
234
7,513
16,678
1,236,986
93,256
1,733
31
8
0
120
94
METRIC TONS/ YEAR- -
HCl HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7,645
79
0
0
0
0
0
0
TSP
135
5,923
2,763
126
0
713
116
0
23
70
2,894
4,216
66,244
117,001
430
7,298
122,745
194,550
19,039
8,635
49,225
3,1»9
17,264
87
13,412
19,645
78,830
2,820
978
15,795
321,754
750
2,295
12,346
19,200
560
265
75
29,445
1,119
575
2,918
33,530
16,992
41,514
2,810
15
218
5
0
148
355
voc
0
94
3
0
0
151
187
0
433
1
511
2,608
562
743
278
17
393
410
32
9
2,057
5
1,343
67
1,769
7
916
45
45
0
54
0
0
0
1
0
0
858
37
0
0
158
1,958
5,696
57,459
2,081
14,182
97,232
31,343
6,215
74,000
5,270
THC
0
231
6
0
0
151
295
0
683
1
807
2,614
1,277
1,549
278
41
441
465
86
26
2,101
15
3,836
191
4,825
10
935
71
128
1
155
0
0
0
2
0
0
2,452
105
0
0
158
5,595
10,347
89,771
3,251
16.617
101,939
38,524
6,215
84,464
10,542
A-21
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
sec
306010
306011
306012
306014
306100
306888
306999
307001
307002
307003
307004
307005
307007
307008
307011
307013
307020
307030
307888
307999
308001
308006
308007
309001
309002
309010
309011
309020
309030
309060
309888
309999
310001
310002
312999
320999
330001
330002
330003
330004
390001
390002
390004
390005
390006
390007
390008
390009
390010
390012
390013
399999
S02
0
76
17,650
3,648
0
425
55,433
96,249
27,594
9
0
0
337
2,788
5
0
2
6
0
834
0
0
0
0
0
0
0
0
0
0
0
127
942
975
0
0
39
0
1
0
819
65,221
42,565
3,655
34,611
12,159
5,081
0
0
56
0
26,501
S04
0
0
0
0
0
0
0
37.714
4.939
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
0
0
0
0
0
0
0
174
58
8
99
0
2
0
0
0
0
0
NOx
0
47
1,896
1,099
0
219
5,131
43,047
1.675
0
50
0
4,355
3,328
0
0
0
44
0
620
0
111
0
0
0
0
0
4
0
0
0
354
0
2,635
6
0
17
0
1
0
1,841
2,507
6,066
3,221
25,603
2,158
1,008
310
9
0
0
13.245
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ht IKiC
CO HCl
0
352
5
43
0
0
52,092
647,521
250
0
0
0
1,334
692
0
0
0
134
0
8,674
0
31
0
0
0
0
0
1
0
0
0
3
0
1,445
2
0
3
0
1
0
109
26,743
912
1,619
47,409
20,158
30,990
0
1
0
0
70,002
IUN
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5/rtAK
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
0
33
46,617
1,620
0
158
3,063
71,313
2,510
81
1,127
1
41,480
11,994
0
0
12,039
2,485
765
4,756
165
230
112
84
694
70
0
55
2,421
122
81,898
1,834
653
455
218
4
1,110
89
77
13
388
7,774
2,773
3,857
10,368
2,282
386
1,462
767
9
0
44,356
VOC
1,287
45,366
1,749
214
2,537
19.044
32,563
10,445
215
160
1,957
221
5,950
1,745
7,700
142
4.154
171
648
1.467
10,046
937
6,181
423
0
1,807
44
4,037
684
0
63
2,901
11,920
730
0
380
20.300
3,417
74
85
5
602
1,559
780
10,216
212
42
118
686
0
0
82,052
THC
1,287
54,728
2,733
486
2,537
27,355
49,640
10,598
215
160
1,957
221
5,950
1,745
7,700
142
4,154
171
648
1,467
10,046
937
• 6,181
669
0
2,502
61
6,378
948
0
87
2,901
11,920
782
0
380
20,300
3,417
74
85
5
615
1,752
780
23,127
367
42
118
1,558
0
0
186,464
A-22
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY • ANNUAL U.S. EMISSIONS, POINT SOURCES
SCC | 502
401001
401002
401003
401868
401913
402001
402002
40200}
402004
40200S
402006
402007
402008
402009
402010
40201 1
402013
402014
402016
402017
402018
402019
402020
402021
402022
402023
402024
402025
402888
402901
402999
403001
403002
403003
403010
403011
403012
403888
403999
404001
404002
405001
40S002
405003
405004
40500S
405006
405888
406001
406002
406003
0
297
0
0
0
2
0
0
0
0
0
2
175
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
0
0
386
0
0
0
3,946
0
0
202
0
0
0
0
0
0
0
0
3
0
0
0
406004 0
sen
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NOX
0
2
1
0
0
2B8
0
0
7
269
6
16
163
562
45
0
0
0
0
450
2
0
0
0
0
0
0
0
0
0
621
4
0
0
91
882
0
0
0
73
0
10
10
263
5
27
0
0
0
0
0
0
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
METRIC
CO HCl
0
3
0
0
0
76
0
0
1
166
1
1,858
522
38
12
0
0
0
0
75
0
0
0
0
0
0
0
0
0
0
505
1
0
0
60,679
30,340
0
0
80
0
0
13
0
34
0
15
0
0
91,019
0
0
0
lONS/YtAK
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
0
186
0
0
0
992
0
93
413
441
1,024
63
1,364
742
10
0
0
0
3
0
0
0
0
0
0
44
2
0
0
0
7,914
1,560
122
0
324
1,007
0
0
326
2,705
0
48
0
41
0
384
0
0
1,576
2
29
15
voc
6,925
91,100
836
369
60
222,751
1,828
30,852
127,670
111,179
71,317
20,478
19,384
200,625
3,500
1,749
14,985
93
837
28,821
285
306
431
127
4,590
222
16
1,501
26,391
58
80,558
146,533
60,472
3,482
37,626
31,518
21,256
4,198
27,011
103,358
2,000
22,055
3,324
13,920
24,978
60,450
381
509
62,286
19,730
5.215
8,043
THC
6,925
91,100
836
369
60
222,751
1,828
30,852
127,670
111,179
71,317
20,478
55,748
200,625
3,500
1,749
14,985
93
837
29,064
285
306
471
127
4,590
222
16
1,501
26,391
58
80,558
155,033
61,082
3,509
38,351
31,738
21,256
4,296
27,011
103,358
2,000
91,935
13,750
13,920
24,978
60,450
381
957
82,970
20,516
5,215
8,043
A-23
-------
1980 NAPAP S.O EMISSIONS INVENTORY • ANNUAL U.S. EMISSIONS, POINT SOURCES
SCC | S02
406888
490001
490999
501001
501002
501005
501900
501999
502001
502002
502003
502005
502900
503001
503002
503005
503007
503900
599999
0
0
0
4,828
255
346
1,033
5
1,906
0
0
1,706
485
15,967
57
794
0
1,888
142
Contig. U.S. | 22,230,755
S04
0
0
0
8
0
0
0
0
4
0
0
11
0
4
0
2
0
0
0
658,038
NOx
0
0
3
5,062
1,585
1,453
0
0
1,804
15
0
10,700
9
7,119
604
2,440
0
731
0
8,748,242
Pb
0
0
0
130
0
2
0
0
72
0
0
21
0
84
0
4
0
0
0
6,981
CO HCl HF NH3
0
0
0
52,619
23,531
1,804
18
31
13,200
523
0
0
1
198,278
20,332
318
0
2,080
0
8,281,040
0
0
0
4,860
0
24
0
0
1,909
0
0
0
0
2,804
0
0
0
0
0
471,429
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
102,680 222
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
,688
TSP
0
0
404
11,377
4,450
5,414
260
27
1,667
64
0
1,745
113
17,476
1,601
14,633
86
534
0
3,959,255
voc
2,855
1,920
86,421
1,189
11,442
66
0
5
1,114
31
0
347
75
4,989
3,849
73
0
165
17
3,595,476
THC
2,855
2,633
118,510
6,062
11,442
368
2
5
2,400
161
0
2,052
170
25,435
6,685
432
0
839
89
4,224,879
A-24
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS. POINT SOURCES
State
Alabama
Arizona
Arkansas
Cal ifornia
Colorado
Connecticut
Delaware
Oist. of Coluro.
Florida
Georgia
Idaho
i lUnois
I nd i ana
loua
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
Neu Hampshire
Neu Jersey
New Mexico
New York
North Carolina
North Dakota
Ohio
Oklahoma
Oregon
Pennsylvania
Rhode Island
South Carol ina
South Dakota
Tennessee
Texas
Utah
Vermont
Virginia
Washington
West Virginia
Wisconsin
Wyoming
Contig. U.S.
} S02
777,509
824,136
55,654
390,765
117,379
34,524
96,889
7,164
1,018,759
862,393
36,610
1,350,414
1,826,567
307,348
193,588
1,098,360
236,911
114,789
275,263
297,037
797,627
210,481
251,012
1,270,841
146,533
64,214
140.938
96,421
233,574
250,262
760,082
605,426
95,891
2,615,591
83,987
24,497
1,783,153
7,102
316.336
33,897
1,120,219
1,053,679
88,412
1,543
304,930
268,669
1,130,784
642,486
184,096
24,504,741
504
28,739
29,305
8,336
22,801
7,626
2,228
1,965
399
25.261
27,802
6,598
33,150
28,766
9,629
6.128
18,018
14,000
7,242
6,203
5,977
24,456
9,566
7,051
16,895
6,039
3,388
6,114
2.619
6,520
T.939
23,645
22.669
10,188
42,357
7,332
13,985
43,985
288
14,823
3.252
23,980
47,897
7,179
37
13,159
14,207
25,524
18,129
11.953
725.349
WOx
231,517
106,764
43,525
325,900
139,517
22,506
25,970
2,616
318,374
279,517
8,820
466,947
459,329
125,308
214,230
313,443
435,240
20,741
91,346
77,625
335,672
134,826
96,489
288,037
38,000
52,703
47,637
26.907
132,399
157,193
287,899
256.959
72,347
653,973
158,265
44,894
495,679
3,871
124,920
25.340
286,292
1,308,304
57,610
287
123,312
71,259
338,340
182,023
132,429
9,643,101
Pb
185
73
1
216
442
78
1
2
23
45
449
1,518
462
71
1
107
49
1
5
162
176
10
0
288
213
30
6
0
0
4
16
21
5
976
4
20
763
4
85
5
143
374
43
0
34
87
415
79
3
7,695
CO
283,116
64,834
135,410
354,357
110,700
11,759
8,526
4,109
145,583
162.451
41,789
312,428
296,070
54,874
61,361
117,028
998,666
44,700
33,723
14,048
271,202
33,932
82,975
80,142
139,579
10,148
13.032
4,914
83,692
26,933
113,978
126,370
55,560
690,969
338,386
30,413
470,810
2,014
79,221
15,218
153,761
2,126,155
33,766
39
386,565
221.531
153,195
45,510
82,566
9,128,108
lUNb/TfcAK
HCl
19,291
8,862
1,761
0
9,054
386
1,106
589
8,670
20,392
314
33,310
33,163
11,434
6,552
22,400
736
26
6,546
2,155
22,683
8,659
2,587
22,038
1,994
4,577
3.515
1,026
2,442
8,295
9,200
23,513
71
50,337
5,740
544
41,375
14
8,973
220
23,266
18,937
3,547
9
7,047
4,942
29,055
15,215
13,084
519,652
HF
3,518
1,071
1,413
131
1,186
0
184
7
29,030
2,486
173
7,890
4,487
1,701
792
3,768
1,663
3
1,260
84
3,139
1,113
314
2,663
243
577
442
124
302
977
1,875
3,070
47
7,179
763
92
5,504
0
1,596
37
4,243
5,841
495
0
1,318
1,488
4,861
2,310
1,723
113,183
«H3
602
5,009
12,324
4,653
7,795
0
1
0
21,887
19,889
121
39,976
11,695
19.260
96
116
21,860
0
2
0
228
16,428
358
6
185
354
1
0
12
150
3
8,664
200
1,802
1,405
0
8,552
0
1,020
1
10,293
11,535
52
0
4,539
10,076
8
651
3,660
245,467
TSP
81,327
27,451
33,610
135,939
53,026
8,160
16,575
863
100,437
41,780
12,020
197,188
201,252
151,474
43,258
127,561
118,871
18,217
36,069
17,624
143,924
130,576
24,231
311,839
19,205
43,613
28,465
4,000
98,206
34,495
245,892
115,851
48,845
277,919
67,489
33,286
187,784
1,065
142,530
33,423
114,674
388,434
61,873
1,544
109,050
86,100
60,484
98,764
27,984
4,364,247
voc
52,531
13,246
15,425
296,959
16,536
24,045
25,868
451
48,306
27,300
2,608
153,055
87,406
17,782
40,304
102,788
295,753
17,888
59,894
94,270
195,994
65,852
52,561
170,834
12,081
45,451
3,398
16,682
104,827
37,202
90,149
82,978
2,616
120,764
63,340
29,815
132,321
9,836
210,703
2,044
134,184
761,649
7,961
2,804
86,880
40,651
4,861
63,719
18,685
3,963,258
THC
66,836
13,948
16,385
353,118
22,616
24,771
27,329
1,169
51,735
28,379
4,649
200,212
116,818
20,263
73,307
116,606
322,789
18,945
76,098
117,747
216,766
68,438
57,773
183,961
15,086
46,423
3,562
17,636
119,935
51.033
141,636
100.142
3,423
150,742
73,889
36,281
162,706
11,124
221,994
3,023
143,795
900,425
9,248
3.047
99,831
43,628
5,487
70,106
22,183
4,657,042
A-25
-------
1980 NAPAP 5.0 EMISSIONS INVWORr • ANNUAL U.S. EMISSIONS, POINT SOURCES
State S02
Alabama
Arizona
Arkansas
Cal ifornia
Colorado
Connecticut
Delaware
Oist. of Co luti.
F I or i da
Georgia
Idaho
Illinois
I nd i ana
loua
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Hampshire
New Jersey
New Mexico
New York
North Carolina
North Dakota
Ohio
Oklahoma
Oregon
Pennsylvania
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Utah
Vermont
Virginia
Washington
Uest Virginia
Wisconsin
Wyoming
705,358
747,658
50,489
354,503
106,486
31,320
87,898
6,499
924,220
782,365
33,213
1,225,099
1,657,066
278,827
175,623
996,435
214,926
104,137
249,719
269,473
723,609
190,949
227,719
1,152,910
132,935
58,255
127,859
87,473
211,899
227,038
689,548
549,244
86,993
2,372,870
76, 193
22,224
1,617,680
6,443
286,981
30,751
1,016,265
955,900
80,207
1,400
276,633
243.737
1,025,850
582,865
167,012
Contig. U.S. | 22,230,755
S04
26,072
26,586
7,562
20,685
6,918
2,021
1,783
362
22,917
25,222
5,986
30,074
26,097
8, 735
5,559
16,346
12,701
6,570
5,627
5,422
22,187
8,678
6,397
15,327
5,479
3,074
5,547
2,376
5,915
7,202
21,451
20.565
9,243
38,426
6,652
12,687
39,903
261
13,447
2,950
21,755
43,452
6,513
34
11,938
12,889
23,155
16.447
10,844
658.038
NO*
210,033
96,857
39,486
295,657
126,570
20,417
23,560
2,373
288,830
253,578
8,002
423,615
416,704
113,680
194,350
284,356
394,851
18,816
82,869
70,422
304,522
122,31*
87,535
261,308
34,474
47,812
43,216
24,410
120,113
142,606
261 , 183
233,114
65.633
593,286
143,578
40,728
449,681
3,512
113,328
22,989
259,725
1,186,896
52,264
260
111,869
64,646
306,943
165,132
120,140
8,748,242
Pb
168
66
1
196
401
71
1
2
21
41
407
1,377
419
64
1
97
44
1
5
147
160
9
0
261
193
27
5
0
0
4
15
19
5
885
4
18
692
4
77
5
130
339
39
0
31
79
376
72
3
6,981
NtfXJk IUN3/TCAK
CO HCl HF
256,843
58,818
122,844
321,473
100,427
10,668
7,735
3,728
132,073
147,376
37,911
283,435
268,595
49,782
55,667
106.168
905,992
40,552
30,594
12,744
246,035
30,783
75,275
72,705
126,626
9.206
11,823
4,458
75,926
24,434
103,401
114,643
SO, 404
626,849
306,985
27,591
427,120
1,827
71,869
13,806
139,492
1,928,852
30,633
35
350,693
200,973
138,979
41,287
74,904
8,281,040
17,501
8,040
1,598
0
8,214
350
1,003
534
7,865
18,500
285
30,219
30.086
10,373
5,944
20,321
668
24
5,939
1,955
20,578
7,855
2,347
19,993
1,809
4,152
3,189
931
2,215
7,525
8,346
21,331
64
45,666
5,207
494
37,535
13
8,140
200
21 , 107
17,180
3,218
8
6,393
4,483
26,359
13,803
11,870
471,429
3,192
972
1,282
119
1,076
0
167
6
26,336
2,255
157
7,158
4,071
1,543
719
3,418
1,509
3
1,U3
76
2,848
1,010
285
2,416
220
523
401
112
274
886
1,701
2,785
43
6,513
692
83
4,993
0
1,448
34
3,849
5,299
449
0
1,196
1,350
4,410
2,096
1,563
102,680
NH3
546
4,544
11,180
4,221
7,072
0
1
0
19,856
18,043
110
36,266
10,610
17,473
87
105
19,831
0
2
0
207
14,903
324
6
168
322
1
0
11
136
2
7,860
182
1,635
1,274
0
7,758
0
925
1
9,338
10,464
47
0
4,118
9,141
8
591
3,320
222,688
TSP
73,780
24,904
30,491
123,324
48,106
7,403
15,037
783
91,117
37,903
10,905
178,889
182,576
137,417
39,244
115,724
107,840
16,527
32,722
15,989
130,568
118,459
21,982
282,901
17.423
39,566
25,824
3,629
89,093
31,294
223,074
105,100
44,312
252,129
61.226
30,197
170,358
966
129,304
30,321
104,033
352,388
56,131
1,401
98,930
78,110
54,871
89,599
25,387
3,959,255
VOC
47.657
12,017
13,994
269,401
15,002
21,814
23,468
409
43,824
24,766
2,366
138,852
79,295
16,132
36,564
93,249
268,308
16,228
54,336
85,522
177,806
59,741
47,683
154,981
10,960
41,233
3,083
15,134
95,099
33,750
81,784
75,278
2,374
109,557
57,462
27,048
120,042
8,924
191,151
1,854
121,732
690,969
7,222
2,544
78,818
36,878
4,410
57,806
16,951
3,595,476
THC
60,634
12,654
14,865
320,350
20,517
22,472
24,793
1,060
46,934
2S.746
4,217
181,633
105,977
18,383
66,504
105,785
292,835
17,187
69.036
106,820
196,651
62,087
52.411
166,890
13,686
42,115
3,231
15,999
108,806
46,297
128,493
90,849
3,106
136,754
67,032
32,915
147,607
10,092
201,394
2,743
130,451
816.867
8,390
2,764
90,567
39,580
4,978
63,600
20,125
4,224.879
A-26
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY • ANNUAL U.S. EMISSIONS, POINT SOURCES
EPA REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
Contig
1
2
3
4
5
6
7
8
9
10
U.S.
S02
551, 416
993,656
5,598,182
6, 050. OH
7,443,167
1,680,493
1,835,991
666,208
1.355,839
329,776
24,504,741
S04
18,391
30,165
91,235
168,343
156,424
85,504
36,040
46,237
58,220
34.790
725,349
NOx
151,937
420,298
1,077,263
1,907,511
2,232,770
2,102,527
680,278
465,243
480,301
124,973
9,643,101
Pb
245
16
1,220
609
3,221
432
390
711
295
556
7,695
CO
77,474
197,670
1,056,928
1,150,505
1,650,111
3,625.550
206.525
437.389
432,223
293,733
9,128,108
HCl
3,616
11,642
85,718
129,092
163,367
35,469
44,601
27,970
12,377
5,800
519,652
HF
211
2,177
13,134
48,025
26,118
10,657
5,733
3,731
1,644
1,753
113,183
NH3
1
15
13,102
62,827
70,781
47,272
19,717
11,893
9,663
10,197
245,467
TSP
50,610
344,098
410,825
748,391
1,049,623
642,899
550,184
244,356
191,855
131,406
4,364,247
voc
165,525
194,976
310,275
711,351
686,791
1,173,369
274,370
59,924
313,603
73,074
3,963,258
THC
193,270
261,572
372,620
787,258
823,082
1,364,521
323,954
75,580
370,628
84,559
4,657,042
EPA REGION | S02
S04
NOx
Pb
CO
HCl HF
NH3
TSP
VOC
THC
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
1
2
3
4
5
6
7
8
9
10
500,245
901,447
3,264,279
5,488,586
6,752,457
1,524,547
1,665,615
604,385
1,230,020
299,174
16,684
27,366
82,769
152,721
141,908
77,569
32,696
41,946
52,817
31,562
137,838
381,295
977,295
1,730,498
2,025,574
1,907,417
617,150
422,069
435,730
113,376
222
15
1,107
552
2,922
3?2
354
645
268
504
70,285
179,327
958,847
1,043,741
1,496,984
3,289,107
187,360
396,800
392,114
266,475
3,280
10,562
77,764
117,113
148,207
32,178
40,462
25,374
11,228
5,262
191
1,975
11,915
43,568
23,694
9,668
5,201
3,385
1,491
1,590
0
14
11,886
56,997
64,213
42,885
17.887
10,789
8,766
9,251
45,914
312,166
372.701
678,942
952,220
583,239
499,128
221,681
174,051
119,212
150,164
176,883
281,482
645,340
623,058
1,064,483
248,909
54,363
284,501
66,293
175,335
237,298
338,042
714,202
746,702
1,237,896
293,891
68,566
336,235
76,712
- CAntig. U.S. | 22,230,755 658,038 8,748,242 6,981 8,281,040 471,429 102,680 222,688 3,959,255 3,595,476 4,224,879
A-27
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY • ANNUAL U.S. EMISSIONS, AREA I POINT SOURCES
State | S02
-- -- +
Alabama
An zona
Arkansas
Cal ifornia
Colorado
Connecticut
Delaware
Dist. of Colum.
Florida
Georgia
Idaho
1 1 1 mots
Indiana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Hampshire
New Jersey
New Mexico
New York
North Carolina
North Dakota
Ohio
Oklahoma
Oregon
Pennsylvania
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Utah
Vermont
Virgi nia
Uashington
West Virginia
Ui scons in
Wyoming
857,549
844,078
87,127
519,799
140,138
63,665
124,669
15,325
1,102,994
900,080
56,210
1,464,520
1,970,870
334,278
228,074
1,150,036
401,333
133,369
303,471
358,065
841,399
238,705
303,846
1,333,218
169,224
78,117
148,157
108,484
309,856
262,555
870,307
655,591
115,391
2,681,314
104,168
55,987
1,899,006
14,168
344,968
40,863
1,158,153
1,324,373
116,615
8,185
370,780
317,791
1,145,522
670,610
211,134
Contig. U.S. | 26,954,136
S04
32,991
30,871
10,478
35,917
9,347
8,110
4,645
1.121
30,793
30,684
8,676
42,270
38,111
11,010
7,409
23,108
24,581
11,223
10,727
14,498
32,609
14,535
11,281
22,746
7,583
4,078
6.667
4,867
20,690
9,202
43,230
31,046
11,574
51,554
9,558
18,601
60,532
1,491
17,550
3,798
28,905
59,869
8,886
1,764
21,579
19,758
27,902
23.795
13,388
975,608
NOX
487,256
263,894
211,143
1,382,764
304,778
139,750
62,266
25,352
712,209
590,650
91,874
972,987
786,843
305,754
513,314
551,354
708,966
6/.068
261,103
270,770
715,377
366,630
294,511
549,797
140,299
173,039
96,918
58,957
417,509
254,116
736,844
532,675
136,091
1,217,607
453,066
226,767
1,041,556
36,253
278,092
79,356
531,336
3,330,036
155,757
23,780
383,434
294,646
461,014
407,774
248,907
22,152,239
Pb
681
366
264
2,643
756
381
71
39
1,087
697
548
2,635
1,101
427
250
519
554
124
456
666
1,148
469
297
849
310
199
107
100
706
174
1,273
727
72
2,160
412
314
1,918
82
459
70
732
2,169
191
62
646
505
618
592
86
31,732
TONS/YEAR-
CO HCl
1,811,119
1,310,433
1,045,560
9,524,250
2,302,185
1,192,328
242,885
338,780
4,071,755
2,335,826
1,280,507
4,246,797
2,374,627
1,105,666
1,072,560
1,594,516
2,541,546
506,637
1,459,780
2,133,002
3,613,069
1,928,665
991,881
2,206,090
1,422,156
609,510
521,365
352,582
2,294,053
932,466
4,758,845
2,289,334
282,219
4,697,200
1,854,007
1,454,001
4,377,701
316,586
1,207,907
509,495
1,951,470
9,063,470
990,051
202,077
2,322,403
2,401,774
784,971
1,892,865
589,965
99,308,937
19,542
8,937
1,786
472
9,110
491
1,152
655
8/834
20,453
329
34,318
33,494
11,505
6,614
22,635
857
40
6,559
2,241
22,871
8,820
2,599
22,184
2,003
4,637
3,554
1,036
2,566
8,299
9,269
23,667
119
50,783
5,765
729
42,015
27
9,045
235
23,436
19,257
3,588
12
7,328
5,062
29,078
15,406
11,110
526,524
HF
3,539
1,087
1,445
145
1,186
0
184
21
29,228
2,503
242
7,937
4,607
1,706
799
3,841
1,761
5
1,307
86
3,150
1,120
314
2,681
241
582
444
124
128
977
1,880
1,110
60
7,934
768
92
5,525
0
1,648
38
4,357
5,900
511
0
1,385
1,516
4,861
2,328
1,727
115,434
NX!
11,964
11,921
25,418
32,013
24,987
1,946
2,051
59
28,793
15,159
8,133
68,633
29,361
80,410
34,189
8,185
26,314
417
2,992
104
10,433
48,624
7,809
17,264
3,890
44,683
705
1
80
4,523
13,961
21,118
6,642
16,124
15,266
4,249
24,109
0
4,440
12,941
18,117
61,713
1,961
3
10,913
18,097
335
32,054
5,159
838,664
TSP
439,271
841,489
874.245
1,536,414
1,134,995
120,226
49,182
15,099
919,841
882,011
110,728
912,702
496,649
1,217,845
1,852,171
452,195
559,071
127,174
227,611
210,504
880,263
1,199,026
587,204
2,877,954
880,654
1,080,992
919,646
66,310
402,215
1,249,009
802,715
700,462
1,295,268
1,070,910
1,107,180
1,849,960
1,432,694
32,121
451,491
715,996
656,159
5,937,876
690,811
100,889
466,354
147,565
381,995
706,684
486,720
42,617,170
voc
391,455
254,096
223,135
2,216,485
356,946
284,183
77,101
44,081
828,561
508,361
222,050
988,586
562,647
237,157
250,269
441,688
625,559
141,991
363,270
515,765
916,363
469,214
261,800
629,726
236,467
168,618
91.948
101,987
696,758
191,042
1,160,860
614,002
53,274
1,001,059
324,988
340,267
1,043,561
81,042
474,791
95,639
554,586
2,172,905
160,449
58,570
527,715
465,326
154,780
476,956
102,467
23,164,547
THC
425,591
271,243
234,177
2,414,927
385,554
299,090
81,188
48,400
868,694
510,222
210,398
1,092,842
621,821
258,603
298,662
469,555
669,847
149,051
394,420
568,190
987,380
496,094
278,672
673,526
245,600
178,920
99,725
109,401
749,784
213,500
1,267,046
655,149
58,166
1,092,677
347,152
363,147
1,113,027
86,846
501,073
101,160
587,715
2,381,939
172,386
61,481
561,508
494,352
161,785
512,284
111,091
24,977,459
A-28
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, AREA t POINT SOURCES
State | S02
Alabama
Arizona
Arkansas
Cat ifornia
Colorado
Connecticut
Delaware
Dist. of Colum.
Florida
Georgia
Idaho
1 1 1 inois
I nd i ana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
Mi ssouri
Montana
Nebraska
Nevada
New Hampshire
New Jersey
New Mexico
Neu York
Worth Carol ma
North Dakota
.Ohio
Oklahoma
Oregon
Pennsylvania
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Utah
Vermont
Virginia
Washington
West Virginia
Wisconsin
Wyoming
777,969
765,749
79.041
471,560
127,133
57,756
113,099
13,903
1,000,637
816,554
50,993
1, 328,614
1,787,975
303,258
206,909
1,043,314
364,088
120,992
275,309
324,836
76J.319
216,554
275,649
1,209,497
153,520
70,868
134,408
98,417
281.101
238, 190
789.543
594,752
104,683
2,432,493
94,501
50,791
1,722,780
12,853
312,955
37,071
1,050,678
1,201,469
105,793
7,425
336,371
288,300
1,039,220
608,378
191,541
Contlg. U.S. | 24,452,809
S04
29,929
28,006
9,506
32,584
8,480
7,357
4,214
1,017
27,935
27,837
7,871
38,347
34,574
9,988
6,721
20,964
22,300
10,181
9,731
13,152
29,583
13,186
10,234
20,635
6,879
3,700
6,048
4,415
18,770
8,348
39,218
28,165
10,500
46,770
8,671
16,875
54,914
1,353
15,921
3,446
26,223
54,313
8.061
1,600
19,576
17,924
25,313
21,587
12,146
885,069
NOx
442,035
239,402
191,546
1,254,428
276,492
126,779
56,487
22,999
646,111
535,834
83,347
882,687
713,820
277,378
465,674
500,185
643,171
60,843
236,870
245,640
648,985
332,603
267,178
498,772
127,278
156,979
87,923
53,485
378,760
230,533
668,459
483,239
123,461
1,104,606
411,017
205,720
944,892
32,888
252,283
71,991
482,025
3,020,981
141,301
21,573
347,848
267,300
418,231
369,930
225,807
20,277,779
Pb
618
332
239
2,398
686
346
64
35
986
632
497
2,390
999
387
227
471
503
112
414
604
1,041
425
269
770
281
181
97
91
640
158
1,155
660
65
1,960
374
303
1,740
74
416
64
664
1,968
173
56
586
458
561
537
78
28.787
CO
1,643,024
1,188,806
948,518
8,640,261
2,088,509
1,081,662
220,342
307,336
3,693,837
2,119,029
1,161,657
3,852,635
2,154,231
1,003,044
973,011
1,446,523
2,305,669
459,614
1,324,291
1,935,027
3,277,726
1,749,656
899,821
2,001,333
1,290,161
552,938
472,975
319,857
2,081.131
845,919
4,317,154
2,076,851
256,026
4,261,240
1,681,933
1,319,048
3,971,392
287,202
1,095,796
462,206
1,770,347
8,222,279
898.160
183,321
2,106,855
2,178,857
712,116
1,717,179
535,209
90,091,712
METRIC TONS/YEAR---
HCt HF
17,729
8,108
1,620
428
8,265
445
1,045
594
8,014
18,555
298
31,133
30,386
10,437
6,000
20,535
777
36
5,950
2,033
20,749
8,002
2,358
20,125
1,817
4,207
3,224
940
2,328
7,529
8,409
21,471
108
46,070
5,230
661
38,116
24
8,206
213
21,261
17,470
3,255
11
6,648
4,592
26,380
13,976
11,893
477,664
3,211
986
1,311
132
1,076
0
167
21
26,516
2,271
220
7,200
4,179
1,548
725
5,485
1,598
5
1,186
78
2,858
1,016
285
2.432
220
528
403
112
298
886
1,706
3,003
54
7,198
697
83
5,012
0
1,495
34
3,953
5,352
464
0
1,256
1,375
4,410
2,112
1,567
104,722
NH3
10,854
10,815
23,059
29,042
22,668
1,765
1,861
54
26,121
32,077
7,378
62,263
26,636
72,947
31,016
7,425
23,872
379
2,715
94
9,465
44,111
7,084
15,662
3,529
40,536
640
1
73
4,103
12,665
19,158
6,025
14,627
13,849
3,855
22,053
0
4,028
11,740
16,435
55,986
1.779
2
9,900
16,418
304
29,079
4,681
760,828
TSP
398,501
763,386
793,102
1,393,814
1,029,651
109,067
44,799
13,698
834,467
800,166
300,032
846.136
450.556
1,122,956
1,680,443
410,408
507.183
115.371
206,486
190,966
798,564
1,087.740
532,703
2,610,841
798,916
980,660
834,289
60,155
364,885
1,133,083
728,215
635,450
1,175,048
971,518
1,004,418
1,678,256
1,299,721
29,323
409,590
649,541
595,260
5,386,757
626,694
91,525
423,071
315,307
346,541
641,095
441,545
38,661,904
VOC
355,123
230,512
202,425
2,010,766
323,817
257,807
69,945
39,990
751,659
461,178
201,440
896,833
510,426
215,146
227,041
400,695
567,503
128,812
329,554
467,896
831,314
425,665
237,502
571,281
214,520
152,968
85,228
94,335
632,090
173,311
1,053,116
557,015
48,330
908,147
294,825
308,686
946,707
73,520
430,726
86,762
503,114
1,971,239
145,557
53,134
478,736
422,137
140,414
432,688
92,956
21,014,593
THC
386,090
246,068
212,624
2,190,791
349,769
271,330
73,653
43,907
788,067
481,010
209,014
991,413
565,923
234,601
270,943
425,975
607,681
135,217
357,813
515,456
895,740
450,050
252,808
611,016
222,805
162,315
90,469
99,247
680,194
193,684
1,149,447
594,343
52,767
991,263
315,114
329,442
1,009,724
78,786
454,570
91,771
533,168
2,160,874
156,386
55,775
509,394
448,470
146,769
464,738
100,780
22,659,252
A-29
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, AREA & POINT SOURCES
U!
o
EPA REGION | S02
REGION 1
REGION 2
REGION 3
REGION 4
REGION 5
REGION 6
REGION 7
REGION 8
REGION 9
REGION 10
685,936
1,180,163
3,858,772
6,473,217
7,867,419
2,179,556
1,973,687
793,365
1,512,034
429,988
Contig. U.S.) 26,954,136
S04
41,953
63,920
126,506
206,358
202,874
113,688
45,243
54,576
73,455
47,035
975,608
NOx
596,578
1,154,353
2,234,725
3,978,083
4,467,218
4,957,327
1,541,904
1,065,188
1,743,576
613,287
22,352,239
Pb
1,415
1,979
3,748
5,199
8,105
3,573
1,725
1,485
3,116
1,387
31,732
CO
4,703,212
7,052,898
9,526,520
16,253,808
18,753,223
15,437,049
4,993,826
6,096,071
11,356,048
5,136,282
99,308,937
• IUN3/TCHK
HCl
3,847
11,835
86,787
130,211
165,692
35,964
44,940
28,165
12,963
6,120
526,524
HF
215
2,208
13,285
48,740
27,076
10,851
5,768
3,765
1,676
1,850
115,434
NH3
2,470
14,042
40,660
135,784
205,228
133,234
176,547
55,581
44,639
30,479
838,664
TSP
657,426
1,204,930
2,573,135
5,088,856
5,286,234
9,727,381
7,049,162
5,204,444
3,297,549
2,528,253
42,617,370
VOC
1,185,538
1,857,619
2,210,510
4,075,244
4,414,825
3.537,629
1,285,770
1,005,242
2,564,528
1,027,643
23,164,547
THC
1,274,058
2,016,830
2,360,328
4,316,670
4,805,098
3,847,014
1,409,712
1,073,957
2,785,895
1,087,898
24,977,459
EPA REGION | S02
REGION 1
REGION 2
REGION 3
REGION 4
REGION 5
REGION 6
REGION 7
REGION 8
REGION 9
REGION 10
622,280
1,070,643
3,500,682
5,872,509
7,137,332
1,977,289
1,790,531
719,740
1,371,718
390,084
Contig. U.S.) 24,452,809
S04
38,059
57,988
114,766
187,208
184,047
103,138
41,044
49,511
66,638
42,670
885,069
NOx
541,209
1,047,219
2,027,327
3,608,890
4,052,631
4,497,248
1,398,804
966,330
1,581,754
556,367
20,277,779
Pb
1,284
1,795
3,400
4,716
7,353
3,241
1,565
1,347
2,827
1,258
28,787
CO
4,266,684
6,398,285
8,642,332
14,745,227
17,012,667
14,004,319
4,530,326
5,530,270
10,302,041
4,659,562
90,091,712
HCl HF
3,490
10,737
78,733
118,128
150,316
32,627
40,770
25,551
1 1 , 760
5,552
477,664
195
2,003
12,052
44,217
24,563
9,844
5,233
3,416
1,520
1,678
104,722
NH3
2,241
12,738
36,886
123,182
186,181
120,869
160,161
50,423
40,496
27,651
760,828
TSP
596,408
1,093,100
2,334,316
4,616,546
4,795,609
8,824,543
6,394,901
4,721,397
2,991,490
2,293,595
38,661,904
VOC
1,075,505
1,685,207
2,005,346
3,697,012
4,005,073
3,209,303
1,166,436
911,942
2,326,506
932,263
21,014,593
THC
1,155,810
1,829,642
2,141,260
3,916,031
4,359,126
3,489,976
1,278,875
974,279
2,527,328
986,926
22,659,252
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, AREA SOURCES
sec
10101
10102
10103
10104
10105
10106
10201
10202
10203
10204
10206
10207
10208
10210
10211
10213
10214
10215
10217
10218
10220
10221
10301
10501
10601
10701
10801
11201
11301
11401
11402
11403
11404
11501
11502
If503
11504
11702
11703
11704
11705
11706
11711
11712
11713
11714
11715
11716
11721
11722
11723
11724
| S02
3,524
1,926
2,130
14,150
49
30
28
47
562
1,676
47
29
57
88
42
48
4,664
202
3,780
2,164
5,576
60,657
1,357
0
0
0
0
0
0
0
0
0
0
0
0
0
0
72
19
3,391
1,460
272
4,266
59,117
2,793
2
115
7,959
1,098
21,561
676
2
S04
151
20
49
969
0
0
0
0
0
0
0
0
0
0
0
0
201
0
0
0
0
0
0
0
0
0
145
0
0
0
0
0
0
0
0
0
0
3
0
201
20
0
82
3,855
301
0
1
859
19
2,888
90
0
NOX
75,089
51,612
51,816
315,962
327
347
46
155
5,986
36,613
294
38
85
695
53
342
117,994
205
4,399
16,437
1,692
11,638
29,013
168,590
20,018
0
0
0
0
0
0
0
0
0
0
0
0
116
31
560
10,072
4,055
265
24,581
2,812
1,097
19,235
1,295
195
6,756
757
826
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
IU
CO
1,100,692
1,035,780
782,189
4,087,204
51,875
33,909
460
1,550
11,978
1,536
68,717
12,674
61,680
373
16,498
770
42,910
102,292
4,045
3,295
0
718
967,453
6,743,663
1,145,919
11,111
0
0
0
0
0
0
0
0
0
0
0
6
2
44
3,143
139
7,457
6,719
770
232
6,731
124
668
1,742
199
147
O/TCAK
HCL
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
12,646
0
0
147,983
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
169
1,310
144
0
0
22
0
0
0
0
TSP
6,089
4,904
3,680
33,616
272
963
21
66
330
762
110
21
113
93
29
125
8,030
0
1,452
862
127
4,169
1,803
6,322,187
225,073
5,556
7,852
0
11,245
1,820
526
6,931
100,868
60,835
7,025
110
1,483
9
2
250
904
23
1,477
3,328
378
29
576
687
904
703
82
139
VOC
76,543
65,662
63,894
410,708
14,012
21,025
53
172
7,266
350
6,187
754
9,996
17
651
341
35,115
32,236
5,659
12,407
117
218
47,632
1,011,551
21, M3
5,556
0
18,243
0
0
165,936
0
0
0
250
9
119
2
0
14
831
6
1,462
6,374
715
44
733
60
631
357
39
25
THC
82,528
70,796
68,890
442,819
15,108
22,669
54
174
7,378
356
6,283
766
10,150
17
661
346
35,724
34,796
5,659
12,407
131
245
51,415
1,011,551
21,643
5,556
0
18,243
0
0
169,495
0
0
0
250
9
119
2
0
16
970
14
1,493
6,374
715
99
1,660
67
645
357
39
58
A-31
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, AREA SOURCES
sec
11725
11726
11731
11732
11733
11734
11735
11736
11740
11801
12001
12002
12101
12102
12103
12104
12111
12112
12113
12114
12115
12116
12117
12121
12501
12502
12601
12602
12603
12604
12605
12606
12613
12614
12615
12623
12624
12625
12626
12641
12642
12643
12644
12701
12702
12703
12704
12705
12801
12802
12803
12901
S02
115
69.506
72,651
6,569
172
2
178
320,833
2,?90
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
302
104
526
0
S04
g
6,249
1,166
704
17
0
13
26,967
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NOX
18,798
12,347
11,061
2,973
220
903
41,865
55,878
5,734
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
76,341
2,196
7,686
570
0
3.029
226
466
0
PS
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
6,580
1,177
5,556
762
55
228
10,467
5,334
428,957
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9,673
906
974
0
0
393,658
0
759
0
TONS/YEAR
HCL
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
KF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
'8
83
0
TSP
562
6,546
28,024
312
23
81
897
29,673
96,093
0
43,307
6,019
970
23,289
466
9.317
13
123
300
3
240
149
160
30
9,370
3,318
9,778
248
8,043
1,737
3,802
2,308
17,199
3,425
10,946
3,027
1,836
1,541
1,009
919
2.896
1,147
227
0
0
0
24
0
33,311
125
929
0
voc
716
574
304
158
8
16
826
2,597
3,550
1,934
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
14,416
63
1,451
4
1,880
6,601
0
42
55,130
TKC
1,623
645
311
158
8
36
1,871
2,917
3,626
4,382
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
32,657
142
3,287
9
4,258
33,311
0
212
55,130
A-32
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, AREA SOURCES
sec
12902
12903
12904
12905
12906
12907
13001
13002
13101
13201
13202
13203
13204
13205
13701
13702
13703
13704
13705
13706
13901
13902
14001
14101
14102
14201
14202
14203
14204
14205
14401
14501
14601
14602
14603
f4604
14701
14901
15101
15201
15202
99900
CANADA
--..-,. .<
S02
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
36,201
657
0
0
0
0
0
0
6,144
3,990
24,640
12,359
0
0
0
0
0
0
763,375
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
181
0
0
0
0
0
0
0
565
165
1,322
1,136
0
0
0
0
0
0
48,547
NOX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
66,752
67,714
126,285
187,733
0
0
0
0
0
0
1,670,876
PS
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
CO
0
0
0
0
0
0
0
0
0
1,045
4,682
0
0
2
0
0
0
0
0
0
0
0
2,132
0
0
0
0
0
0
0
0
0
23,746
11,862
60,210
40,756
0
0
0
0
0
0
17,326,935
TONS/YEAR
HCL
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
162,384
TSP
0
0
0
0
0
0
0
0
0
2,749
2,945
2,276
1,120
4
1,294,970
71,945
3,270,672
3,866,796
311,669
13,284,702
486
1,935
5,329
0
0
1.609
7,382
143,020
61,615
4,381
3,762
29,441
9,133
2,264
11,439
13,364
0
63,786
0
157,366
822,512
0
30,641,093
voc
26,538
3,317
35,068
5,055
30,013
2,843
81,760
74,060
31,456
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5,047
22,296
0
0
0
0
0
267
0
14,424
4,620
22,901
17,889
21,166
0
83,641
0
0
0
2,618,250
THC
26,538
3,317
35,068
5,055
30,013
2,843
81,760
74,060
2,019,013
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5,720
25,271
0
0
0
0
0
758
0
14,674
4,700
23,298
18,200
21,539
0
84,390
0
0
0
4,729,547
A-33
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, AREA SOURCES
sec
10101
10102
10103
10104
10105
10106
10201
10202
10203
10204
10206
10207
10208
10210
10211
10213
10214
10215
10217
10213
10220
10221
10301
10501
10601
10701
10801
11201
11301
11401
11402
11403
11404
11501
11502
1)503
11504
11702
11703
11704
11705
11706
11711
11712
11713
117U
11715
11716
11721
11722
1)723
11724
S02
3,197
1,747
1,932
12,837
44
27
25
43
510
1,520
43
26
52
ao
38
44
4,231
183
3,429
1,963
5,058
55,027
1,231
0
0
0
0
0
0
0
0
0
0
0
0
0
0
65
17
3,076
1,324
247
3,870
53,630
2,534
2
104
7,220
996
19,560
613
2
S04
137
18
44
879
0
0
0
0
0
0
0
0
0
0
0
0
182
0
0
0
0
0
0
0
0
0
132
0
0
0
0
0
0
0
0
0
0
3
0
182
18
0
74
3,497
273
0
1
779
17
2,620
82
0
NOX
68,120
46,822
47,007
286,636
297
315
42
141
5,430
33,215
267
34
77
630
48
310
107,042
186
3,991
14,911
1,535
10,558
26,320
152,942
18,160
0
0
0
0
0
0
0
0
0
0
0
0
105
28
508
9,137
3,679
240
22,300
2,551
995
17,450
1.175
177
6,129
687
749
P8
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
METRIC
CO
998,531
939,644
709,590
3,707,849
47,060
30,762
417
1,406
10,866
1,393
62,339
11,498
55,955
338
14,967
699
38,927
92,798
3,670
2,989
0
651
877,659
6,117,748
1,039,560
10,080
0
0
0
0
0
0
0
0
0
0
0
5
2
40
2,851
126
6,765
6,095
699
210
6,106
112
606
1,580
181
133
TOMS/YEAR
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
KF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
UK]
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11,472
0
0
134,248
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
153
1,188
131
0
0
20
0
0
0
0
TSP
5,524
4,449
3,338
30,496
247
874
19
60
299
691
100
19
103
84
26
113
7,285
0
1,317
782
115
3,782
1,636
5,735,392
204,183
5,040
7.123
0
10,201
1.651
477
6,288
91,524
55.189
6,373
100
1,345
8
2
227
820
21
1,340
3,019
343
26
523
623
820
638
74
126
VOC
69.439
59.568
57.96*
372,588
12,7)2
19,074
48
156
6,592
318
5,613
684
9,069
15
591
309
31,856
29,244
5,133
11,255
106
198
43,211
917,664
19,634
5,040
0
16,550
0
0
150,534
0
0
0
227
8
108
2
0
13
754
6
1,326
5,782
649
40
665
54
573
324
35
23
THC
74.868
64.225
62,496
401,718
13,706
20,565
49
158
6,693
323
5,699
695
9,208
16
600
314
32,408
31,566
5,133
11,255
119
222
46,643
917,664
19,634
5,040
0
16,550
0
0
153,763
0
0
0
227
8
108
2
0
14
880
13
1,354
5,782
649
90
1,506
61
58S
324
35
52
A-34
-------
1980 NAPAP S.O EMISSIONS INVENTORY • ANNUAL CANADIAN EMISSIONS, AREA SOURCES
sec
11725
11726
11731
H7J2
11733
1173*
11735
11736
11740
11801
12001
12002
12101
12102
12103
12104
12111
12112
12113
12114
12115
12116
12117
12121
12501
12502
12601
12602
12603
12604
12605
12606
12613
12614
12615
12623
12624
12625
12626
12641
12642
12643
12644
12701
12702
12703
12704
12705
12801
12802
12803
12901
S02
104
63,055
65,908
5,959
156
2
161
291,055
2,531
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
274
94
477
0
S04
7
5,669
1,058
639
15
0
12
24,464
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HOX
17,053
11,201
10,034
2,697
200
819
37,979
50,692
5,202
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
69.255
1,992
6,973
517
0
2,748
205
423
0
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
MtlKIt
CO
5,969
1,068
5,040
691
50
207
9,496
4,839
389,143
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
«,77S
822
884
0
0
357,121
0
689
0
TWS/TEAK
HCL
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
• 0
0
0
0
0
25
75
0
TSP
510
5,938
25,423
283
21
73
814
26,919
87,174
0
39,287
5,460
880
21,127
423
8,452
12
112
272
3
218
135
145
27
8,500
3,010
8,870
225
7,296
1,576
3,449
2,094
15,603
3,107
9,930
2,746
1,666
1,398
915
834
2,627
1,041
206
0
0
0
22
0
30,219
113
843
0
voc
650
521
276
143
7
14
749
2,356
3,220
1,755
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
13,078
57
1,316
3
1,705
5,988
0
38
50,013
THC
1,472
585
282
143
7
33
1,697
2,646
3,289
3,975
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
29,626
129
2,982
8
3,863
30,219
0
192
50,013
A-35
-------
1930 NAPAP S.O EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, AREA SOURCES
sec
12902
12903
12904
12905
12906
12907
13001
13002
13101
13201
13202
13203
13204
13205
13701
13702
13703
13704
13705
13706
13901
13902
U001
14101
U102
14201
H202
14203
14204
14205
14401
14501
14601
14602
14603
14604
14701
14901
15101
15201
15202
99900
S02
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
32,841
596
0
0
0
0
0
0
5,574
3,620
22,353
11,212
0
0
0
0
0
0
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
164
0
0
0
0
0
0
0
513
331
1,199
1,031
0
0
0
0
0
0
NOX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
60,556
61,429
114,564
170,309
0
0
0
0
0
0
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
--- METRIC
CO
0
0
0
0
0
0
0
0
0
948
4,247
0
0
2
0
0
0
0
0
0
0
0
1,934
0
0
0
0
0
0
0
0
0
21,542
10,761
54,622
36,973
0
0
0
0
0
0
TONS/TEAR
HCL
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
0
0
0
0
0
0
0
0
0
2,494
2,672
2,065
1,016
4
1,174,777
65,267
2,967,104
3,507,898
282,741
12,051,679
441
1,755
4,834
0
0
1,460
6,697
129,746
55,896
3,974
3,413
26,708
8,285
2,054
10,377
12,124
0
57,8
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, AREA SOURCES
Province
Alberta
British Columb.
Manitoba
S02
51,910
42,554
9,944
New Brunswick | 53,511
Newfoundland | 40,452
Nova Scotia | 41,146
Ontario | 162,161
Prince Edward | 2,782
Quebec
345,737
Saskatchewan | 13,178
Canada | 763,375
Province | S02
Alberta
British Columb.
Manitoba
New Brunswick
Newfoundland
Nova Scotia
Ontario
Prince Edward
Quebec
Saskatchewan
Canada
47,092
38,604
9,021
48,544
36,697
37,327
147,110
2,524
313,647
11,955
692,522
S04
1,291
3,123
531
4,302
3,217
3,230
8,702
214
23,244
693
48,547
S04
1,171
2,833
482
3.903
2.918
2.930
7.894
194
21.087
629
44,041
NOX
361,792
202,509
99,411
36,833
33,752
47,085
425,273
5,642
298,611
159,968
1,670,876
NOX
328,212
183,713
90,184
33,414
30,619
42,715
385,801
5,118
270,895
145,121
1,515,793
PB
0
0
0
0
0
0
0
0
0
0
NR
PB
0
0
0
0
0
0
0
0
0
0
NR
CO
3,005,269
2,035,935
1,599,921
341,763
197,060
378,427
4,108,803
57,909
2,236,111
3,365.737
17,326,935
CO
2,726,334
1,846,969
1,451,424
310,042
178,770
343,303
3,727,443
52,534
2,028,566
3,053,345
15,718,731
- lONS/TfcAR
HCL
0
0
0
0
0
0
0
0
0
0
NR
HCL HF
0
0
0
0
0
0
0
0
0
0
NR
HF
0
0
0
0
0
0
0
0
0
0
NR
0
0
0
0
0
0
0
0
0
0
NR
NH3
53,080
6,518
19,455
939
123
1,276
32,758
832
15,650
31,752
162,384
NH3
48,153
5,913
17,649
852
112
1,158
29,718
755
14,197
28,805
147,312
TSP
8,767,433
1,932,312
3,113,425
386,395
192,773
708,372
6,401,794
41,462
2,242,053
6,855,074
30,641,093
TSP
7,953,682
1,752,964
2.824,452
350.532
174,881
642,624
5,807,610
37,614
2,033,956
6,218,819
27,797,132
voc
537,586
260,165
225,491
42,010
26,981
63,195
637,371
6,492
322,901
496,059
2,618,250
VOC
487,690
236,018
204,562
38,111
24,477
57,329
578,213
5,889
292,930
450,017
2,375,236
THC
741,839
502,632
316,540
103,832
76,696
137,842
1,378,759
17,192
872,031
582,184
4,729,547
THC
672,985
455,980
287,160
94,195
69,577
125.049
1,250,789
15,596
791,093
528,148
4,290,573
NR => Not Reported
-------
1980 MAPAP 5.0 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, POINT SOURCES
sec |
-----•-••H
101002
101003
101004
101005
101006
102002
102004
102006
102008
1020U
105001
201001
201002
301003
301005
301013
301014
301017
301018
301019
301021
301023
301026
301027
301028
301029
301030
301035
301040
301130
301132
301157
301174
301250
301258
301830
1 303000
303001
303002
303003
303004
303005
303006
303008
303009
303010
303013
303023
303024
303030
303888
303999
S02
447,467
3,320
145,392
27,358
5,991
1,234
146,057
3,032
0
59,271
0
214,533
5
0
1,842
0
284
0
0
0
0
17,520
0
0
0
0
0
2,920
0
0
0
0
0
0
0
0
0
14,984
0
10,140
0
1,680,647
13,440
190,845
3,010
33,359
16,696
221
0
4,577
0
9,120
S04
8,485
46
8,077
1,086
0
99
4,531
258
0
190
0
33
0
0
0
0
2
0
0
0
0
862
0
0
0
0
0
14
0
0
0
0
0
0
0
0
0
71
0
830
0
31,882
2,359
528
26
1,195
0
0
0
176
0
45
NOx
136,282
870
23,122
5,112
12,585
0
17,563
12,112
0
3,022
3
54,72!
1,677
0
0
7,588
0
0
0
0
0
0
0
187
0
0
0
0
0
0
0
0
0
0
0
0
0
10,869
0
5
0
0
0
0
20
0
0
0
0
0
0
0
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
15,061
251
1,709
317
420
0
1,050
496
0
0
0
23
93
0
123,494
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
775
28
0
25,453
27.713
43,587
0
0
37.547
0
0
0
0
TONS/TEAR- --
HCI
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
29,636
0
0
0
0
0
0
1,482
0
0
499
0
0
0
0
10,795
0
0
0
0
0
0
0
0
0
0
560
0
0
0
0
72
0
0
0
0
0
0
0
TSP
116,032
12,215
11,744
62
428
0
13, "68
853
0
13,826
0
8,483
75
0
17
0
78
409
0
0
1,058
0
0
1,636
320
255
1,791
84
5,446
6
0
0
0
0
0
41
4
13,231
4,041
22,145
512
33,957
28,413
35,954
44,043
3,351
229
167,589
296
4,490
36,301
3,833
voc
4,498
71
499
146
12
0
212
119
0
0
0
2
3
115,309
66
0
0
0
50,439
81
0
0
9,042
0
0
0
0
0
0
0
1,458
1,655
2,470
7,078
8,504
0
0
0
0
672
21
0
0
0
381
0
0
0
0
0
0
0
IHC
4,595
73
560
146
27
0
238
271
0
0
0
2
10
115,309
66
0
0
0
50,708
413
0
0
9,042
0
0
0
0
0
0
0
1,484
1,685
2,514
7,078
8,504
0
0
0
0
1,438
46
0
0
0
429
0
0
0
0
0
0
0
A-38
-------
1980 NAPAP S.O EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, POINT SOURCES
- lUNVTtAK
sec | so2
304001
304006
304010
305005
305006
305007
305010
3050U
305015
305016
305019
305020
305021
305022
305025
305031
305032
305040
306001
306002
306006
306008
306012
306014
306808
307001
307002
310002
310004
310888
403001
501001
501002
501005
503001
503005
' 503007
35,491
0
571,740
0
0
0
0
0
0
0
1,288
0
0
0
0
0
0
0
51,645
35,655
68
0
33
704
10,785
33,054
76,491
446,224
277
1,851
0
1,201
98
7
11,757
1,077
12,552
CANADA | 4,345,263
S04
267
0
7,889
0
496
4
0
0
5,594
6
0
0
0
0
0
0
0
0
5,760
461
6
0
2
3
54
55,124
1,039
2,135
0
9
0
0
0
0
34
0
57
139,735
NO*
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
22,216
6,449
103
0
50
55
0
17,531
0
45,696
3,569
0
0
1,389
8
9
0
323
0
383,136
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
CO
148,413
0
0
0
0
0
0
p
0
0
0
0
0
0
0
0
0
0
1,627
191,381
8
0
3
58
0
66,540
0
5,784
7
0
0
16,477
674
0
0
0
0
708,989
HCt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4,021
0
0
0
6
0
0
0
0
0
0
0
188
17
0
0
15
0
47,290
TSP
22,499
77
16,933
625
15,325
131
5,536
1,102
8,771
22,090
15,896
1,059
8,734
16,177
1,254
45,491
15,743
10,841
4,222
9,593
30
0
294
919
0
118,481
1,385
2
112
0
0
1,869
326
34
0
286
0
933,053
voc
1,250
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
291
23,221
1
75,374
1
46
0
12,493
0
15,368
62
0
44,626
136
8
0
0
14
0
375,631
THC
1,975
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
384
36,280
2
79,023
2
104
0
13,737
0
20,455
87
0
50,597
693
8
2
0
81
0
408,066
A-39
-------
;ao IAP«P 5.0 EMISSIONS INVENTORY • ANNUAL CANADIAN EMISSIONS, POINT SOURCES
)CC $02
'01V.2
•3' 305
' '50*
' 'MS
' no*
102002
102004
'02006
102008
1020U
105001
2Q1Q01
201002
J01G03
501005
301013
3010U
501017
301018
301019
301021
301023
301026
301027
301028
301029
301030
301035
3010*0
301130
301132
301157
301174
301250
301258
S0 1830
303000
303001
305002
SOSOOJ
30300*
303005
301006
303008
503009
303010
3C3013
303023
30302*
303030
303888
301999
405,9*3
3,012
131,900
24,819
5,*35
1,119
132,503
2,751
0
53,771
0
19*, 625
5
0
1,671
0
258
0
0
0
0
15,89*
0
0
0
0
0
2,6*9
0
0
0
0
0
0
0
0
0
13,59*
0
9,199
0
1.524.687
12,193
173.135
2,731
30,263
15,1*7
200
0
4,152
0
8,274
SO*
7,698
42
7,327
985
0
90
*,111
23*
0
172
0
30
0
0
0
0
2
0
0
0
0
782
0
0
0
0
0
13
0
0
0
0
0
0
0
0
0
6*
0
753
0
28,923
2,140
479
2*
1,08*
0
0
0
160
0
41
NOx
123,635
789
20,976
4,638
11,*17
0
15,933
10,983
0
2,742
3
«9,6*3
1,521
0
0
6,88*
0
0
0
0
0
0
0
170
0
0
0
0
0
0
0
0
0
0
0
0
0
9,860
0
5
0
0
0
0
18
0
0
0
0
0
0
0
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
13,663
228
1,550
288
381
0
953
450
0
0
0
21
84
0
112,03*
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
703
25
0
23,091
25,141
39,542
0
0
34,063
0
0
0
0
METRIC TONS/TEAR--
HCt HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
o •
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
26,886
0
0
0
0
0
0
1,344
0
0
453
0
0
0
0
9,793
0
0
0
0
0
0
0
0
0
0
508
0
0
0
0
65
0
0
0
0
0
0
0
TSP
105,26*
11,081
10,654
56
388
0
12,672
774
0
12,543
0
7,696
68
0
15
0
71
371
0
0
960
0
0
1,484
290
231
1,625
76
4,941
5
0
0
0
0
0
37
*
12,003
3,666
20,090
*6*
30,806
25,776
32,618
39,956
3,040
208
152,037
269
4,073
32,932
3,477
voc
4,081
65
452
133
11
0
192
108
0
0
0
2
3
104,608
60
0
0
0
45,759
73
0
0
8,203
0
0
0
0
0
0
0
1,323
1,502
2,241
6,421
7,715
0
0
0
0
609
19
0
0
0
3*6
0
0
0
0
0
0
0
THC
4,169
66
508
133
25
0
216
246
0
0
0
2
9
104,608
60
0
0
0
46,002
375
0
0
8,203
0
0
0
0
0
0
0
1,346
1,528
2,281
6,421
7,715
0
0
0
0
1,305
42
0
0
0
389
0
0
0
0
0
0
0
A-40
-------
19SO NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, POINT SOURCES
SCC | S02
304001
304006
304010
305005
305006
305007
305010
305014
305015
305016
305019
305020
305021
305022
305025
305031
305032
305040
306001
306002
306006
306008
306012
306014
306888
307001
307002
310002
310004
310888
403001
501001
501002
50100S
503001
503005
'503007
32,198
0
518,684
0
0
0
0
0
0
0
1,168
0
0
0
0
0
0
0
46,852
32,346
62
0
30
639
9,784
29,987
69,393
404,815
251
1,679
0
1,090
89
6
10,664
977
11,387
CANADA | 3,942,032
S04
242
0
7,157
0
450
4
0
0
5,075
5
0
0
0
0
0
0
0
0
5,225
418
5
0
2
3
49
50,009
943
1,937
0
8
0
0
0
0
31
0
52
126,768
NOx
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
20,154
5,851
93
0
45
50
0
15,904
0
41,456
3,238
0
0
1,260
7
8
0
293
0
347,582
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
CO
134,641
0
0
0
0
0
0
. 0
0
0
0
0
0
0
0
0
0
0
1,476
173,621
7
0
3
53
0
60,365
0
5,247
6
0
0
14,948
611
0
0
0
0
643,196
MtTRIC TOKS/TEAR---
HCl HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3,648
0
0
0
5
0
0
0
0
0
0
0
171
15
0
0
14
0
42,902
TSP
20,411
70
15,362
567
13,903
119
5,022
1,000
7,957
20,040
14,421
961
7,924
14,676
1,138
41,270
14,282
9,835
3,830
8,703
27
0
267
834
0
107,486
1,256
2
102
0
0
1,696
296
31
0
259
0
846,468
voc
1,134
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
264
21,067
1
68,380
1
42
0
11,334
0
13,942
56
0
40,485
123
7
0
0
12
0
340,774
THC
1,791
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
348
32,913
2
71,690
2
95
0
12,462
0
18,557
79
0
45,902
629
7
2
0
73
0
370,199
A-41
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, POINT SOURCES
Province
Alberta
| S02
I 608,878
British Columbia | 141,552
Manitoba
New Brunswick
Newfoundland
Nova Scotia
Ontario
Prince Edward
Suebec
Saskatchewan
Canada
| 523,355
| 169,542
1 25,183
| 171,197
|1,791,964
lsland| 2,191
| 864,554
| 46,947
|4,34S,263
S04
6,386
31,792
13,259
10,661
1,387
7,864
37,245
129
27,455
3,557
139,735
NOx
123,772
19,286
2,981
21,927
2,178
36,391
138,476
488
23,388
14,249
383,136
Pb
0
0
0
0
0
0
0
0
0
0
NR
CO
18,417
167,979
3,589
6,202
263
15,358
315,383
38
173,600
8,160
708,989
TONS/YEAR-
HCl
0
0
0
0
0
0
0
0
0
0
NR
HF
0
0
0
0
0
0
0
0
0
0
NR
NH3
30,243
494
1,556
as
0
369
13,501
0
915
127
47,290
TSP
60,708
93,322
28,794
29,354
87,892
54,647
202,588
167
249,893
125.688
933,053
VOC
148,126
24,884
8,190
9,001
1,967
10,470
95,879
9
67,207
9,898
375,631
THC
157,123
28, 148
8,551
10,177
2,196
12,102
103,998
10
74,462
11,299
408,066
Province
1 S02
S04
N0«
Pb
CO
HCl HF
NH3
TSP
VOC
THC
Alberta
I 552,375
British Columbia I 128,416
Manitoba
New Brunswick
Newfoundland
Nova Scotia
Ontario
Prince Edward
Quebec
Saskatchewan
| 474,698
| 153,809
1 22,846
| 155,310
1 1,625, 674
Island| 1,988
| 784,325
1 42,590
5,793
28,842
12,029
9,672
1,258
7,134
33,789
117
24,907
3,227
112.286
17,496
2,704
19.892
1,976
33,014
125,426
4-3
21,218
12,927
0
0
0
0
0
0
0
0
0
0
16,708
152,391
3,256
5,626
239
13,933
286,116
34
157,490
7,401
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
27,437
448
1,412
77
0
335
12,248
0
830
115
55,074
84,662
26,122
26,630
79,736
49,576
183,788
152
226,703
114,024
134,380
22,575
7,430
8,165
1,784
9,498
86,982
8
60,971
8,979
142,542
25,536
7,757
9,232
1,992
10,979
94,347
9
67,552
10,250
|3,942,032 126,768 347,582
NR 643,196
NR
NR 42,902 846,468 340,773 370.199
A-42
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY • ANNUAL CANADIAN EMISSIONS, AREA t POINT SOURCES
Province
Albert!
British Coluifcia
Manitoba
New Brunswick
Newfoundland
Novi Scotia
Ontario
Prince Edward Island
Quebec
Saskatchewan
Canada |
Province
Alberta
British Columbia
Manitoba
New Brunswick
Newfoundland
Nova Scotia
Ontario
Prince Edward Island
Quebec
Saskatchewan
Canada |
S02
660,788
184,106
533,199
223,053
65,635
212,343
1,954,125
4,973
1,210,291
60,125
5,108,638
S02
599,467
167,021
483,719
202,353
59,544
192,637
1,772,784
4,511
1,097,971
54,545
4,634,554
S04
7,677
34,915
13,790
14.96J
4,604
11,094
45,947
343
50,699
4,250
188,282
S04
6,965
31,675
12.510
13,574
4,177
10,064
41,683
311
45,994
3,856
170,809
NO
485
221
102
58
35
83
563
6
321
174
2,054
NO
440
201
92
53
32
75
511
5
292
158
1,863
X
,564
,795
,392
,760
,930
,476
,749
,130
,999
,217
,012
X
,498
,209
,889
,307
,595
,729
,427
,561
,113
,047
,375
Pb
0
0
0
0
0
0
0
0
0
0
NR
Pb
0
0
0
0
0
0
0
0
0
0
NR
CO
3,023,686
2,203,914
1,603,510
347,965
197,323
393,785
4,424,186
57,947
2,409,711
3,373,897
18.035,924
CO
2,743,042
1,999,360
1,454,680
315,669
179,008
357,236
4,013,560
52,569
2,186,056
3,060,748
16,361,928
HCl HF
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
NR NR
HCt HF
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
NR NR
NH3
83,323
7,012
21,011
1,024
123
1,646
46,260
832
16,564
31,879
209,674
NH3
75,590
6,361
19,061
929
112
1,493
41,966
755
15,027
28,920
190,214
TSP
8,828,141
2,025,634
3,142,219
415,749
280,665
763,019
6,604,382
41,629
2,491,946
6,980,762
31,574,146
TSP
8,008,756
1,837,626
2,850,574
377,162
254,617
692,200
5,991,398
37,765
2,260,660
6,332,843
28,643,600
VOC
685,711
285,050
233,681
51,010
28,948
73,664
733,251
6,501
390,108
505,957
2,993,881
VOC
622,070
258,593
211,992
46,276
26,261
66,827
665,195
5,898
353,901
458,996
2,716,010
THC
898,962
530,780
325,091
114,009
78,892
149,945
1,482,757
17,202
946,493
593,482
5,137,613
THC
815,527
481,516
294,917
103,427
71,570
136,028
1,345,137
15,605
858,645
538,398
4,660,771
NR > NOT REPORTED
A-43
-------
1980 NAPAP 5.0 EMISSIONS INVENTORY - ANNUAL CANADIAN & U.S. EMISSIONS, AREA & POINT SOURCES
- TONS/YEAR
Country | S02 S04 NOx Pb CO HCl HF NH3 TSP VOC THC
+
Canada | 5,108.638 188,282 2,054,012 NR 18,035,924 NR NR 209,674 31,574,146 2,993,881 5,137,613
Contig. U.S.] 26,954,136 975,608 22,352,239 31.732 99,308,937 526,524 115,434 838,664 42,617,370 23,164.547 24,977,459
+ .
Total | 32,062,774 1,163,890 24,406,251 31,732 117,344,861 526,524 115,434 1,048,338 74,191,516 26,158,428 30,115,073
METRIC TONS/YEAR
Country | S02 S04 NOx Pb CO HCl HF NH3 TSP VOC THC
Canada | 4,634,554 170,809 1,863,375 NR 16,361,928 NR NR 190,214 28,643,600 2,716,010 4,660,771
Contig. U.S.j 24,452,809 885,069 20.277,779 28,787 90,091,712 477,664 104,722 760,828 38,661,904 21,014,593 22,659,252
Total | 29,087,363 1,055,878 22,141,154 28,787 106,453,640 477,664 104.722 951.042 67,305,504 23,730,603 27,320,023
NR = NOT REPORTED
-------
STATE EMISSION DENSITY - NAPAP EMISSIONS INVENTORY VERSION 5.0
State Emission Density
(Tons/Sq. Mi.)
State
Alabama
Arizona
Arkansas
California
Colorado
Connecticut
Delaware
Dist. of Colum.
Florida
Georgia
Idaho
Illinois
Indiana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Hampshire
New Jersey
New Mexico
New York
North Carolina
North Dakota
Ohio
Oklahoma
Oregon
Pennsylvania
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Utah
Vermont
Virginia
Washington
West Virginia
Wisconsin
Wyoming
S02
16.892
7.436
1.638
3.326
1.353
13.067
64.495
243.254
20.367
15.503
0.682
26.319
54.844
5.973
2.789
28.987
9.015
4.303
30.847
45.753
14.772
3.001
6.433
19.337
1.164
1.019
1.348
12.065
41.491
2.164
18.369
13.422
1.665
65.392
1.517
0.582
42.302
13.442
11.420
0.538
28.142
5.055
1.421
0.883
9.340
4.778
47.485
12.322
2.177
S04
0.6499
0.2720
0.1970
0.2298
0.0902
1.6646
2.4030
17.7937
0.5686
0.5285
0.1053
0.7596
1.0605
0.1967
0.0906
0.5824
0.5521
0.3621
1.0904
1.8525
0.5725
0.1827
0.2388
0.3299
0.0522
0.0532
0.0607
0.5413
2.7705
0.0758
0.9124
0.6356
0.1670
1.2573
0.1392
0.1934
1.3484
1.4146
0.5810
0.0500
0.7024
0.2285
0.1083
0.1902
0.5436
0.2971
1.1566
0.4372
0.1380
NOx
9.598
2.325
3.970
8.847
2.942
28.684
32.212
402.413
13.151
10.173
1.115
17.485
21.896
5.463
6.277
13.897
15.925
2.164
26.540
34.599
12.560
4.609
6.235
7.974
0.965
2.258
0.882
6.557
55.906
2.094
15.552
10.906
1.964
29.695
6.599
2.358
23.201
34.396
9.206
1.045
12.911
12.709
1.898
2.564
9.658
4.430
19.110
7.493
2.566
rb
0.013414
0.003224
0.004964
O.C16910
0.007297
0.078202
0.036730
0.619048
0.020071
0.012005
0.006649
0.047353
0.030638
0.007630
0.003057
0.013082
0.012444
0.004001
0.046351
0.085101
0.020155
0.0058^6
0.006288
0.012314
0.002132
0.002597
0.000974
0.011121
0.094537
0.001434
0.026868
0.014884
0.001039
0.052678
0.006001
0.003472
0.042725
0.077799
0.015195
0.000922
0.017787
0.008278
0.002327
0.006686
0.01627.
0.007593
0.025618
0.010878
0.000887
CO
35.68
11.54
19.66
60.94
22.22
244.73
125.65
5,377.46
75.18
40.23
15.54
76.32
66.08
19.76
13.11
40.19
57.09
16.35
148.38
272.55
63.43
24.25
21.00
32.00
9.78
7.95
4.74
39.21
307.18
7.63
100. -4-4
46. S~
4.0-
114.55
27.00
15. i:
9-. 5:
300.3-
30.00
p . "1
-* . -» -
3-*. 5-3
• ' ^ j.
2 . '-5
- N ^
N_;
3-v.'S
?.„'$
A-45
-------
STATE EMISSION DENSITY - NAPAP EMISSIONS INVENTORY VERSION 5.0 (continued)
State Emission Density
(Tons/Sq. Mi.)
State
Alabama
Arizona
Arkansas
California
Colorado
Connecticut
Delaware
Dist. of Colum.
Florida
Georgia
Idaho
Illinois
Indiana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Hampshire
New Jersey
New Mexico
New York
North Carolina
North Dakota
Ohio
Oklahoma
Oregon
Pennsylvania
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Utah
Vermont
Virginia
Washington
West Virginia
Wisconsin
Wyoming
HC1
0.3849
0.0787
0.0336
0.0030
0.0879
0.1008
0.5960
10.3968
0.1631
0.3523
0.0040
0.6167
0.9320
0.2056
0.0809
0.5705
0.0192
0.0013
0.6667
0.2864
0.4015
0.1109
0.0550
0.3218
0.0138
0.0605
0.0323
0.1152
0.3436
0.0684
0.1956
0.4846
0.0017
1.2385
0.0840
0.0076
0.9359
0.0256
0.2994
0.0031
0.5695
0.0735
0.0437
0.0013
0.1846
0.0761
1.2054
0.2831
0.1352
HF
0.069712
0.009576
0.027168
0.000928
0.011448
0.000000
0.095189
0.365079
0.539690
0.043111
0.002936
0.142634
0.128200
0.030483
0.009770
0.096814
0.039555
0.000161
0.132852
0.010989
0.055303
0.014080
0.006648
0.038886
0.001671
0.007594
0.004040
0.013790
0.043921
0.008052
0.039680
0.067768
0.000866
0.193493
0.011186
0.000956
0.123073
0.000000
0.054557
0.000500
0.105871
0.022518
0.006226
0.000000
0.034887
0.022793
0.201501
0.042775
0.017806
NH3
0.23567
0.10502
0.47790
0.20482
0.24120
0.39936
1.06118
0.93679
0.53165
0.60900
0.09869
1.23339
0.81703
1.43679
0.41805
0.20630
0.59106
0.01347
0.30418
0.01323
0.18317
0.61125
0.16533
0.25041
0.02676
0.58303
0.00641
0.00014
0.01075
0.03728
0.29467
0.43237
0.09584
0.39323
0.22236
0.04418
0.54151
.00000
0.14697
0.17038
0.44022
0.23553
0.02390
0.00027
0.27488
0.27209
0.01389
0.58897
0.05320
TSP
8.653
7.413
16.437
9.830
10.956
24.677
25.547
239.667
16.985
15.192
4.013
16.761
13.820
22.118
22.650
11.403
12.558
4.103
23.136
26.898
15.454
15.073
12.432
41.743
6.057
14.105
8.368
7.374
53.858
10.294
16.942
14.341
18.691
26.117
16.126
19.233
31.914
30.667
14.947
9.426
15.944
22.662
8.417
10.880
11.747
5.226
15.835
12.985
5.018
VOC
7.711
2.239
4.195
14.181
3.445
58.330
39.887
699.703
15.299
8.756
2.694
17.766
15.657
4.238
3.060
11.133
14.051
4.581
36.925
65.904
16.088
5.898
5.543
9.134
1.626
2.200
0.855
11.564
93.299
1.574
24.502
12.571
0.769
24.414
4.734
3.538
23.246
76.890
15.718
1.259
13.476
8.293
1.955
6.316
13.293
6.996
6.416
8.764
1.056
THC
8.383
2.390
4.407
15.451
3.722
61.389
42.001
768.247
16.040
9.132
2.796
19.639
17.359
4.621
3.652
11.835
15.046
4.809
40.092
72.603
17.335
6.236
5.900
9.769
1.689
2.335
0.907
12.166
100.400
1.760
26.743
13.413
0.839
26.648
5.059
3.775
24.793
82.397
16.588
1.332
14.281
9.091
2.100
6.630
14.144
7.433
6.706
9.413
1.145
A-46
-------
SCO | S02
1
2
3
4
5
6
7
8
9
10
11
12
13
U
15
16
17
18
19
20
21
22
23
24
25
26
28
30
32
34
36
38
39
41
43
44
45
46
47
48
49
50
51
52
54
55
56
5.'
58
59
60
61
12,097
28,664
148,356
0
1,271
9,866
13.301
44,138
53,199
278,844
417
0
155
454,236
189
37,407
140.186
25
7
77
1,494
1,284
6,496
9,005
144
11
67,096
86,875
23,236
30,059
7,093
8,402
3,326
86,416
119,651
74,790
128,494
4,098
806
7,573
3,648
12,343
212,161
2,725
0
0
0
0
0
0
5,013
3,007
S04
169
1,522
28,388
0
0
98,827
161
1,700
9,270
25,790
0
2
1
16,227
1
5,631
2,877
0
284
0
1
1
16
3
0
0
3,591
4,621
414
856
1
46
76
1,534
2,409
1,100
2,270
6
0
20
155
946
16,972
0
0
0
0
0
0
G
6
4
NO
1,241
1,466
88,900
0
244,383
80,057
5,368
7,865
32,662
64,502
93.510
1
61
116,060
48
32.136
29.615
1,844,135
102
82
2,796
1,091
8,536
52,825
1,316
160
1,495,874
1,858,442
451,013
573,897
174,178
187,567
68,468
690,971
1,042,877
816,652
750,431
•30,780
8,016
74,278
172
90,332
34,164
10,137
0
0
0
0
0
0
118,528
69,686
N02
38
45
1,814
0
12,862
2,476
166
243
667
1,316
4,922
0
2
3,589
1
656
604
97,060
3
4
493
193
1,506
9,322
232
28
166,208
206,494
50,113
63,766
19,353
20,841
7,608
76,775
115,875
90,739
83,381
952
248
2,297
5
1,844
697
534
0
0
0
0
0
0
20,917
12,297
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
70
0
2
0
0
0
7,417
7,404
2,877
2,721
1,998
1,247
2
0
0
0
0
0
0
0
0
0
0
0
0
2
0
0
0
0
0
0
CO
39,900
47,697
25,119
0
51,412
6,363,435
232
4,801
8,217
5,901
19,615
2
1
15,332
21
7,721
2.715
259.534
311
3
935,430
9,814
29,182
1,038,173
29,182
3,455
9,703,579
35,437,309
3,027,549
11,205,758
2,212,888
5,492,472
2,476,699
245,728
719,910
270.807
293,012
151,354
536,351
220,313
5.295
32,258
1,166
1,360,524
0
0
0
0
0
0
4,881,714
2,295.361
HCl
119
21
0
0
0
0
108
59
0
0
0
0
0
1,065
0
0
0
0
0
0
1,494
5
94
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HF
1
1
0
0
0
0
2
2
0
0
0
0
0
283
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-- TONS/YEAR
NH3 TSP
0
0
0
0
0
0
0
0
0
0
0
0
7
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4,406
7,906
12,499
0
7,529
1,032.150
439
279
3,123
22,421
2,681
5
1
4,490
76
2,828
10,527
155
135
19
110,851
7,259
21,129
242,709
4,857
727
696,177
3,325,305
175,227
831,481
43,832
137,676
6,865
133,644
338,923
94,886
56,532
61,689
1,541
3,289
3,531
9,862
16,094
0
0
29,270,073
7,528
0
0
0
592,770
409,913
CA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
MG
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
KA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
• o
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
7,796
9,306
23,461
0
9,815
2,038,388
24
56
1,316
2.797
3,676
1
0
495
1
126
952
3,962
121
1
61,784
1,742
8,288
339,286
9,092
1.396
1,830,921
4,094,727
640,766
1,441,277
234,862
489,780
198,921
112,041
305,115
147,354
240,871
89,446
30,980
89,097
577
28,235
2,439
370,657
966,415
0
0
0
0
0
836,862
368,884
TIIC
7,963
9,506
23,461
0
22,234
2,082,113
25
57
1,316
3,141
B.327
1
0
506
1
126
1,069
8,975
124
1
311,790
8,792
41,823
339,286
9,092
1,396
1,974,069
4,414,869
690,863
1,553,962
253,225
528,073
214,720
113,984
310,406
154,748
245,048
90,823
31,457
90,468
589
28,235
2,739
400,096
966,415
0
0
0
0
0
856,862
368.884
-------
1«80 NAPAP 5.2 EMISSIONS INVEN!0*t, ANNUAL U.S. EMISSIONS. AREA SOURCES
*-
00
SCC S02
&2
a
64
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
0
0
64
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
374
739
0
320,535
Contig. U.S.|2, 449,395
SO*
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
17
41
0
24,503
250,259
KG
7,179
0
5,606
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
201
5,356
5,395
313,363
11,592,476
N02
1,267
0
989
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
109
284
34.918
1,116,662
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
297
24,037 90,
CO
397,513
0
230,339
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
1,196
905
83,619
180,829
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
19
0
0
3,888
6,872
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
1,961
2,251
TONS/TEAR
NH3 TSP
0
0
0
97. 193
129,780
97.606
44,793
21,163
50,355
148,502
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
19
0
0
3,779
593,197
60,465
0
56,693
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,282
3
0
418,641
38,253,123
CA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Nil
MC
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
NA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
voc
68,041
0
42,334
0
0
0
0
0
0
0
506,129
300,118
175,812
126,782
473,818
182,582
12.187
157,460
31,576
20,584
52,134
18,177
1,602
1,164
3,693
248,596
342,132
1,047,157
0
580
129
344,393
19,201,288
IHC
68,041
0
42,334
0
0
0
0
0
0
0
506.129
300,118
175,812
126,782
473,818
182,582
12,187
157,460
31,576
20,584
52,134
18,177
1,602
1,164
3,693
250,820
345,193
1,047,157
0
652
291
350,452
20,320,417
NR *> Not Reported
-------
------------»
sec
1
2
3
4
5
6
7
8
9
10
11
12
13
U
15
16
17
18
19
20
21
22
23
24
25
26
26
30
32
34
36
38
39
41
43
44
45
46
47
48
49
SO
51
52
54
55
56
57
58
59
60
61
S02
10,974
26,004
134.586
0
1,153
8,950
12,066
40,041
48,261
252,963
378
0
141
412,076
171
33,935
127,175
23
6
70
1,355
1,165
5,893
8,169
131
10
60,868
78,812
21,079
27,269
6.435
7,622
3,017
78,395
108,546
67,848
116,568
3,718
731
6,870
3,309
11,197
192.471
2,472
0
0
0
0
0
0
4,548
2,728
S04
153
1.199
25,753
0
0
89,654
146
1,542
8,410
23,396
0
2
1
14,721
1
5,108
2,610
0
258
0
1
1
15
3
0
0
3,258
4,192
376
777
1
42
69
1,392
2,185
998
2,059
5
0
18
141
858
15,397
0
0
0
0
0
0
0
5
4
NO
1,125
1,330
80,648
0
221,700
72,626
4,870
7,135
29,631
58.515
84,831
1
55
105,287
43
29,153
26,866
1,672,971
92
74
2,536
990
7,743
47,922
1,194
145
1.357,034
1,685,950
409,152
520,630
158,012
170,158
62,113
626,838
946,082
740,854
680,779
27,923
7,272
67,384
156
81,948
30,993
9,196
0
0
0
0
0
0
107,527
63,218
N02
35
41
1,646
0
11,668
2,246
151
221
60S
1,194
4,465
0
2
3,256
1
595
548
88,051
3
4
448
175
1.366
8.457
211
26
150,782
187,328
45,461
57,848
17,557
18,906
6.901
69,649
105.120
82,317
75,642
864
225
2,084
S
1,672
633
484
0
0
0
0
0
0
18,975
11,156
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
64
0
2
0
0
0
6,7Z9
6,717
2,610
2,468
1,813
1,131
2
0
0
0
0
0
0
0
0
0
0
0
0
2
0
0
0
0
0
0
CO
36,197
43.270
22,788
0
46,640
5,772,811
210
4,355
7,454
5,353
17,794
2
1
13,909
19
7,004
2,463
235,445
282
3
848,608
8,903
26,473
941,815
26.473
3,134
8.802,939
32,148,186
2,746,546
10,165,693
2,007,498
4,982,687
2,246,824
222,921
653,091
245,672
265.816
137,306
486,569
199,865
4,804
29,264
1,058
1,234,247
0
0
0
0
0
0
4,428,616
2,082,316
HCl
108
19
0
0
0
0
98
54
0
0
0
0
0
966
0
0
0
0
0
0
1,355
5
85
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
nt i
HF
1
1
0
0
0
0
2
2
0
0
0
0
0
257
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Kit 1 UN
NH3
0
0
0
0
0
0
0
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
i/TtftK
TSP
3,997
7,172
11,339
0
6,830
936,351
398
253
2,833
20,340
2,432
5
1
4,073
69
2,566
9,550
141
122
17
100,562
6,585
19,168
220,182
4,406
660
631,561
3,016,666
158,963
754,307
39,764
124,898
6.228
121,240
307,466
86,079
51,285
55,963
1.398
2.984
3,203
8,947
14,600
0
0
26,553,364
6,829
0
0
0
537,752
371,867
CA
0
0
0
0
0
0
0
ro
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
MG
0
0
0
0
0
0
0
0
0
0
0
0
0 .
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
7,072
8,443
21,284
0
8,904
1,849,195
22
51
1,194
2,537
3,335
1
0
449
1
114
863
3,594
110
1
56,050
1,581
7,518
307,795
8,248
1,266
1,660,984
3,714,674
581,293
1,307,505
213,063
444,321
180,458
101,642
276,795
133,677
218,515
81,144
28,105
80,827
523
25.614
2,213
336,254
876,717
0
0
0
0
0
759.188
334,646
THC
7,22«
8,624
21,284
0
20,171
1,888,861
23
52
1,194
2,850
7,554
1
0
459
1
114
970
8,142
112
1
282,851
7,976
37,941
307,795
8,248
1,266
1.790,845
4,005,102
626.741
1,409,731
229,722
479,060
194,791
103,405
281.596
140,385
222,303
82,393
28,537
82,071
1 534
25,614
2,485
362,961
876,717
0
0
0
0
0
759,188
334,646
-------
1980 NAPAP S.2 EMISSIONS INVENTORY. ANNUAL U.S. EMISSIONS, AREA SOURCES
VI
O
sec
62
63
64
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
. 86
87
88
89
90
91
92
93
94
95
96
97
98
99
S02
0
0
58
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
339
670
0
290,784
Contig. U.S. |2,222,054
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
15
37
0
22,229
227,031
NO
6,513
0
5,085
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
182
4,859
4,894
284,278
10,516,517
N02
1,149
0
897
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
99
258
31,586
1,013,019
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
269
21,806
CO
360,618
0
208,960
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
1,085
821
75,858
81,810,673
HC1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
17
0
0
3,527
6,234
ntlKIL IUH
KF NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
1,779
2,042
0
0
0
88,172
117.734
88,547
40,635
19,198
45,682
134,719
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
17
0
0
3,428
538,140
»/TtAK
TSP
54,853
0
51,431
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,163
3
0
379,785
34,702,650
CA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
MG
0
0
0
0
0
0
0
0
0
0
0
0
0
0 '
0
0
0
0
q
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
NA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
voc
61,726
0
38,405
0
0
0
0
0
0
0
459,153
272,262
159,494
115,015
429,840
165,636
11,056
142,845
28.645
18.673
47,295
16,490
1,453
1,056
3,350
225,523
310,377
949,965
0
526
117
312,428
17,419,116
THC
61,726
0
38,405
0
0
0
0
0
0
0
459.153
272.262
159.494
115.015
429.840
165,636
11,056
142.845
28,645
18,673
47,295
16,490
1,453
1,056
3,350
227,540
313,153
949.965
0
591
264
317,924
18,434,373
-------
T
Ul
sec
1
2
3
4
5
6
7
8
9
10
11
12
13
H
15
16
17
18
. 1»
20
21
22
21
24
25
26
28
10
32
34
36
38
39
41
43
44
45
46
47
48
49
50
51
52
54
55
56
57
58
59
60
61
METHANE
0
0
0
0
765.467
0
0
0
0
33.682
286,681
0
0
0
0
0
11.462
108,986
0
5
14,026,514
395,526
1,881,494
0
0
0
7,485.696
16,741,239
2,619.762
5,892,643
960,231
2,002,459
512,297
133,392
363,257
437.998
286,770
0
a
0
0
0
29,375
954,582
0
0
0
0
0
0
0
0
ETHANE
5,057
6,037
0
0
0
1,322,196
16
36
0
0
a
1
0
321
1
0
0
0
79
7
79,198
2.233
10,623
0
0
0
501,434
1,121,423
175,486
394.722
64,322
134,136
204,529
0
0
21,058
0
' 51,083
17,693
50,884
374
0
0
381,107
0
0
0
0
0
0
0
0
PROPANE
2,890
3,449
11,230
0
19,969
755,540
9
21
633
0
7,479
0
0
184
0
61
0
8,061
45
5
48,084
1,356
6,450
132,351
3,547
545
0
0
0
a
0
0
0
0
0
0
0
0
0
0
214
13,575
0
0
341,918
0
0
0
0
0
326.449
143,897
BUTANE
1.228
1,466
87,049
0
33,886
321,105
4
9
4,882
11,826
12,691
0
0
78
0
468
4,024
13.678
19
4
87,683
2.473
11.762
101.572
2,722
418
1,916,195
4,28'., 437
670,609
1,508,404
245,801
512,591
0
0
0
88,442
0
0
0
0
91
104.762
10,314
0
2,866,849
0
0
0
0
0
250,531
110,433
ISO-BUTAKE
0
0
29.371
0
0
0
0
0
1,647
0
0
0
0
0
0
158
0
0
0
1
16,971
479
2,276
101,572
2,722
418
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
35,347
0
0
955.616
0
0
0
0
0
250,531
110.433
-- THOUSAND
PENIANE
0
a
27,030
0
18,153
0
0
0
1,516
0
6,799
0
0
0
0
145
0
7,328
0
0
0
0
0
80,026
2,145
329
0
0
0
0
0
0
0
0
0
39,307
0
0
0
0
0
32,530
0
0
1,253,699
0
0
0
0
0
197,388
87,007
MOLES/YEAR
ISO-PENTANE
1,228
1,466
0
0
0
321,105
4
9
0
0
0
0
0
78
0
0
0
0
19
0
0
a
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
91
0
0
0
0
0
0
0
0
0
0
0
AUANES
. 13,581
16,212
137.704
0
32,474
3,551,040
43
98
7,723
2,850
12,162
2
0
863
2
740
970
13.109
211
0
390,333
11,007
52,359
1,520,500
40,746
6,256
11,783,703
26,353,433
4,123,932
9,275,979
1,511,560
3,152,196
1,223.279
317,451
864,495
787,55*
682,468
168,081
58,215
167,425
1,005
165,723
2,485
2,279,383
5,251,507
0
0
0
0
0
3,750,371
1,653,142
CTHVLENE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
181,024
5,105
24,282
2,129,931
57,077
8,764
4,566,633
10.212,957
1,598,180
3,594,794
585,787
1,221,596
329,195
238,864
650,483
609,266
515,741
0
0
0
0
0
0
613,401
0
0
0
0
0
0
5.253,557
2,315,738
PROPYLENE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
175.367
4,945
23,523
0
0
0
2,149,004
4,806,097
752,085
1,691,668
275,664
574,869
816,169
44,464
121,086
151,615
95,590
0
0
0
0
0
0
1,520,799
0
0
0
0
0
0
0
0
ISO-BUTENE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
17,579
47,871
0
37,791
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ALKENES
9,897
11.814
0
0
0
2.587,726
31
71
0
0
0
1
0
629
1
0
0
0
154
0
5,657
160
759
1,360,447
36,457
5,598
2,722,071
6,087,723
952,641
2,142,779
349,175
728,167
0
58,940
160,509
0
126.712
144.187
49,940
143.624
732
0
0
0
1.025.753
0
a
0
0
0
3,355.595
1,479,127
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, AREA SOURCES
Ln
NJ
SCC | METHANE
62
63
64
71
72
73
74
75
76
77
78
79
SO
81
82
83
84
K
. 86
87
88
89
90
91
92
93
94
95
96
97
98
99
Contig. U.S.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
109.219
150,313
0
0
6,988
10,030
251,159
56,657,225
ETHANE
0
0
0
0
0
0
0.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9,102
12,526
0
0
0
0
50,868
4,616,552
PROPANE
26,542
0
16,514
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6,826
9,395
0
0
0
262
0
1.887,549
BUTANE
20,369
0
12,674
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11,377
15,658
0
0
2.453
444
0
13,332,479
I SO- BUTANE
20,369
0
12,674
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
54,609
75,156
873,963
0
0
0
0
2,544,314
-- THOUSAND MOLfcS/TfcAK
PENTANE ISO-PENTANE
16,049
0
9,985
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
13,652
18,789
0
0
0
238
0
1,812,116
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
324,000
ALKANES
304,924
0
189,719
0
0
0
0
0
0
0
2,832,956
1,429,370
1,220,122
1,197,297
4,354,261
0
111.995
689,939
290,175
189,161
235,056
77,832
14,722
10,697
33,938
2,170,721
2,987,468
15,835,826
0
591
426
1,799,443
115,361,007
ETHYLENE
427,140
0
265,760
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6,826
9,395
0
0
0
0
693,072
36,114,563
PROPYLENE ISO-BUTENE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 .
0
0
0
0
0
0
0
0
0
0
0
0
282.951
13,485,899
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
103,241
ALKENES
272,826
0
169,748
0
0
0
0
0
0
0
941,258
449,231
0
0
0
0
0
0
0
0
0
0
0
0
0
102,393
140,918
0
0
0
0
365,611
25,989.063
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY • ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, AREA SOURCES
sec
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
28
30
32
34
36
38
39
41
43
44
45
46
47
48
49
50
51
52
54
55
56
57
58
59
60
61
k- — --
BENZENE
0
0
0
0
11,295
0
0
0
0
0
4,230
0
0
0
0
0
0
4,559
0
0
53,741
1,515
7,209
0
0
0
644,701
1.441,829
225,625
507,500
82,699
172,461
66,228
0
0
39,307
0
7,415
2,568
7.384
0
0
0
123,406
131.507
0
0
0
0
0
0
0
TOLUENE
4,407
5,260
0
0
4,841
1,152,199
14
32
0
0
1,813
1
0
* 280
1
0
0
1,954
69
0
0
0
0
0
0
0
2,149,004
4,806.097
752,085
1,691,668
275,664
574,869
216,217
2,068
5,632
30,884
4,446
0
0
0
326
0
0
402,885
236,712
0
0
0
0
0
0
0
XYLENE
32,580
38,893
0
0
0
8,518,718
102
235
0
0
0
4
0
2,070
4
0
0
0
507
0
0
0
0
0
0
0
465,617
1,041,321
162,952
366,528
59,727
124,555
72,072
0
0
4,212
0
116,998
40,522
116,541
2,410
0
0
134,295
184,110
0
0
0
0
0
0
0
ETH BE HI
7,657
9,141
0
0
0
2,002,182
24
55
0
0
0
1
0
487
1
0
0
0
119
0
0
0
0
0
0
0
89,542
200,254
31,337
70,486
11,486
23,953
0
0
0
0
0
0
0
0
566
0
0
0
0
0
0
0
0
0
0
0
-• THOUSAND
AROMATICS
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
340,259
760,965
119,080
267,847
43,647
91,021
132,457
109,609
298,490
2,808
233,417
158,194
54,791
157,576
0
0
0
246,812
122,740
0
0
0
0
0
0
0
HOLES/YEAR -
FORMAIDEH
0
C
672,771
0
58,494
0
0
0
37,730
68.704
21.907
0
0
0
0
3,615
23,379
23.612
0
J
0
0
0
0
0
0
2,274,362
5,086,453
795,956
1,790,348
291,745
608,403
0
187,162
509.686
649,977
404,590
0
0
0
0
809,662
59,918
0
0
0
0
0
0
0
0
0
ACETAnEH
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
367,085
999,660
0
789,173
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ALDEHYDES
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
a
0
0
0
0
0
0
0
0
0
0
0
0
0
322.155
111,579
320,897
0
0
0
0
0
0
0
0
0
0
0
0
ACE TOME
0
0
0
0
0
0
0
0
0
23,680
0
0
0
0
0
0
8,058
0
0
0
333.763
9.412
44,770
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
20,652
0
0
0
0
0
0
0
0
o
ttiokEs M:
0
0
0
0
0
c
0
c
0
c
0
D
c
0
0
0
0
0
:•
0
c
c
c
c
c
c
UJ,?^
j?:>c*
if ,'S<
1i:, 'T
'S.JTt
M,i^
f
f
f
f
c
f
f
f
«•:«
c
c
o
c
0
0
o
c
c
c
c
r
t
c
c
c
c
t
r
:
»
t
1
i
f
c
'
•
"
c
•'
r
t
!
f
»
f
r
t
f
f
'
f
A-53
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, AREA SOURCES
SCC | BENZENE
------- . - . - -4
62
63
64
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
0
0
0
0
0
0
0
0
0
0
55,098
0
0
41,405
0
475,372
0
0
0
0
0
0
0
0
0
13,652
18,789
0
0
0
148
130,348
Conng. U.S.] 4,269,998
TOLUENE
0
0
0
0
0
0
0
0
0
0
179,069
0
207,341
4,601
249,306
155,697
6.412
145,701
16,614
10,831
51,551
21,931
843
612
1,943
65,986
90,814
0
0
0
63
79.481
13,608,223
XYLENE
0
0
0
0
0
0
0
0
0
0
73,464
0
0
0
103,161
0
2,653
0
6,875
4,482
31,215
0
349
253
804
52,334
72,025
0
0
0
0
25,434
11,858,021
ETH BENZ
0
0
0
0
0
0
0
0
0
0
0
0
0
0
176,234
0
4,533
0
11,744
7,656
0
0
596
433
1,374
15,928
21,921
0
0
0
0
0
2,687,709
-- THOUSAND
AROMATICS
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6,826
9,395
0
0
0
0
47.688
3,203,622
MOLES/TEAR -
FORHALDEH
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11,377
15,658
189,992
0
14,254
766
50,868
14,661,391
ACETALDEH ALDEHYDES
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
15,896
2,171,814
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9,538
764,170
ACETONE
0
0
0
0
0
0
0
0
0
0
110,196
0
22,329
0
236,411
1,964,428
6,081
0
15,755
10,270
105,941
0
799
581
1,843
134,248
184,760
227,990
0
4,913
0
1,179,493
4,646,372
KETONES
0
0
0
0
0
0
0
0
0
0
68,873
0
172,253
0
395,451
0
10,171
281,404
26,354
17,180
156,546
56,560
1,337
971
3,082
147,900
203,549
0
0
0
0
57,226
2,282,149
ORG ACIDS
0
0
0
0
0
0
0
0
0
0
0
0
.349,290
0
94,564
0
2,432
459,959
6,302
4,108
0
17,644
320
232
737
25,029
34,447
104,496
0
0
0
28,613
1,128,174
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
A-54
-------
STATE | S02
ALABAMA
ARI20NA
ARKANSAS
CALIFORNIA
COLORADO
CONNECTICUT
DELAWARE
01 ST. Of COLUH
FLORIDA
GEORGIA
IDAHO
ILLINOIS
INDIANA
IOWA
KANSAS
KENTUCKY
LOUISIANA
MAINE
MARYLAND
MASSACHUSETTS
MICHIGAN
MINNESOTA
MISSISSIPPI
MISSOURI
1
MONTANA
NEBRASKA
NEVADA
NEW HAMPSHIRE
NEW JERSEY
NEW MEXICO
NEW YORK
NORTH CAROLINA
NORTH DAKOTA
OHIO
OKLAHOMA
OREGON
PENNSYLVANIA
RHODE ISLAND
SOUTH CAROLINA
SOUTH DAKOTA
TENNESSEE
TEXAS
UTAH
VERMONT
VIRGINIA
WASHINGTON
WEST VIRGINIA
WISCONSIN
WYOMING
80,040
19,942
31,473
129,034
22,759
29,141
27,780
8,161
84,235
37,687
19,600
114,106
144.303
26,930
34,486
51,676
164,422
18,580
28,208
61.028
43.772
28.224
52.834
62,377
22,691
13,903
7,219
12,063
76,282
12.293
110.225
50,165
19,500
65.723
20.181
31.490
115.853
7.066
28,632
6,966
37,934
270.694
28,203
6,642
65,850
49,122
14,738
28, 124
27,038
CONT1G U.S. | 2,449,395
S04
4.252
1,566
2,142
13,116
1,721
5,882
2,680
722
5.532
2,882
2,078
9.120
9,345
1,381
1.281
5,090
10,581
3,981
4.524
8.521
8,153
4,969
4,230
5,851
1,544
690
553
2,248
14,170
1,263
19,585
8,377
1,386
9,197
2,226
4,616
16.547
1.203
2,727
546
4,925
11,972
1,707
1,727
8,420
5,551
2,378
5,666
1,435
250.259
NO
233.503
142,625
152,714
957,932
150,014
106,721
33,196
20,690
356.384
282,282
73.829
459,368
297,766
163,456
275,625
216,226
250,529
42.196
154,338
175,942
345.462
210,214
182.029
237,283
91,446
109,194
44.564
29.125
259,930
87,562
408,565
249.879
57,919
512,406
271.214
163,937
496,533
29.543
138,681
48.498
221,770
1,878,177
89,655
21,353
236,463
202,186
112,133
204,753
106,670
11,592,476
N02
22.237
14.505
14,904
98,932
15,247
10.523
3,100
2,046
37.452
28.851
9.225
46,672
29,748
16,990
23,459
21,685
23,197
4,132
15.419
17,203
34,243
21.590
15.993
24,477
10.853
11,142
4.718
2,925
25,180
9,361
40,380
25,837
5,825
51,228
23,587
17,936
49,344
2,839
14,491
5,518
23,274
143,555
8,492
2,140
23,660
21,201
10,541
20,998
9,808
1,116,662
PB
496
293
263
2,427
314
303
70
37
1.064
652
99
1,117
639
356
249
412
505
123
451
504
972
459
297
561
97
169
101
100
706
170
1.257
706
67
1.184
408
314
1.155
78
374
65
589
1,795
148
62
612
418
203
513
83
24,037
CO
1,528,003
1,245,599
910,150
9,169,893
2,191,485
1,180,569
234,359
334,671
3,926.172
2.173.375
1,238,718
3,934,369
2,078,557
1,050,792
1,011,199
1,477,488
1,542,880
461,937
1,426.057
2.118.954
3,341,867
1,894,733
908,906
2,125,948
1,282.577
599,362
508,333
347,668
2,210.361
905,533
4.644,867
2,162,964
226,659
4,006,231
1.515,621
1,423,588
3,906,891
314,572
1.128,686
494,277
1.797,709
6,937,315
956,285
202,038
1,935,838
2,180,243
631,776
1,847,355
507,399
90,180,829
TONS/YEAR --
HCL HF
251
75
25
472
56
105
46
66
164
61
15
1,008
331
71
62
235
121
14
13
86
188
161
12
146
9
60
39
10
124
4
69
154
48
446
25
185
640
13
72
15
170
320
41
3
281
120
23
191
26
6,872
21
16
32
14
0
0
0
16
198
17
69
47
120
5
7
73
98
2
47
2
11
7
0
18
0
5
2
0
26
0
5
240
13
755
5
0
21
0
52
1
114
59
16
0
67
28
0
18
4
2,251
NH3
11,362
6.912
13,094
27,360
17,192
1,946
2,050
59
6,906
15,470
8,012
28,657
17,666
61,150
34,093
8,069
4,454
417
2,991
103
10,205
32,196
7,452
17,258
3,705
44,329
704
1
68
4,374
13,959
12,455
6,441
14.322
13,862
4,249
15,758
0
3,420
12,941
7,824
50,179
1,909
3
6.374
8,021
327
31,403
1,500
593,197
TSP
357,944
814,038
840,635
1,400,475
1,081,969
112,066
32,807
14,236
819,404
840,251
318,708
735,514
295,397
1,086,371
1,809,113
324.834
440,200
108,957
191,542
192,880
736,339
1,068,450
562,973
2,566,115
861,449
1,037,379
891,181
62,310
304,009
1,214,514
556,823
584,611
1,246,423
792,991
1,039,691
1,816,674
1,244,910
31.258
308.963
682,573
541,485
5,549,442
628,938
99,345
357,304
261,465
321,511
607,920
458,736
38,253,123
CA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
MG
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
NA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
voc
338,923
240,850
207,710
1,919,526
340,410
260,138
51,233
43,630
780.255
481,061
219,441
835,531
475,241
219,375
209,966
338,901
329,807
124,103
303,376
421,496
720,369
403,362
209,239
458,893
224.386
123,167
90,550
87,305
591,931
153,839
1,070,711
531,024
50,658
880,295
261,648
310,452
911,242
71,205
264,087
93,595
420,402
1,411,256
152,488
55,766
440,835
424,675
149,919
413,237
83,781
19,201,289
TIIC
358,755
257,295
217,992
2.061,809
362,939
274,319
53,859
47,231
816.959
501,843
225,750
892,629
507,003
238,339
225,356
352,949
347,058
130.105
318,323
450,443
7/0,614
427,656
220,899
489,566
230,514
132,498
96,164
91,764
629,848
162,467
1,125,410
555,007
54,742
941,935
273,463
326,865
950,321
75,722
279,079
98,137
443,920
1,481,514
163,138
58,435
461,677
450,724
156,298
442,178
88,907
20,320,417
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, AREA SOURCES
STATE
ALABAMA
ARIZONA
ARKANSAS
CALIFORNIA
COLORADO
CONNECTICUT
DELAWARE
D1ST. OF COLUM.
FLORIDA
GEORGIA
IDAHO
ILLINOIS
INDIANA
IOWA
KANSAS
KENTUCKY
LOUISIANA
MAINE
MARYLAND
MASSACHUSETTS
MICHIGAN
MINNESOTA
MISSISSIPPI
MISSOURI
MONTANA
NEBRASKA
NEVADA
NEW HAMPSHIRE
NEW JERSEY
NEW MEXICO
NEW YORK
NORTH CAROLINA
NORTH DAKOTA
OHIO
OKLAHOMA
OREGON
PENNSYLVANIA
RHODE ISLAND
SOUTH CAROLINA
SOUTH DAKOTA
TENNESSEE
TEXAS
UTAH
VERMONT
VIRGINIA
WASHINGTON
WEST VIRGINIA
WISCONSIN
WYOMING
S02
72,611
18.091
28,552
117,058
20,647
26,436
25,202
7,404
76,417
34.189
17,781
103,515
130,909
24,430
31,285
46,880
149,161
16,855
25,590
55,364
39,709
25,604
47.930
56,587
20,585
12,613
6,549
10,943
69,202
11,152
99,994
45,509
17,690
59,623
18,308
28,567
105,100
6,410
25,975
6,319
34,413
245,569
25,585
6,026
59,738
44,563
13,370
25,514
24,528
S04
3.857
1,421
1,943
11,899
1,561
5,336
2,431
655
5,019
2,615
1.885
8,274
8.478
1.253
1.162
4.618
9,599
3,612
4,104
7,730
7,396
4.508
3,837
5,308
1,401
626
502
2,039
12,855
1,146
17.767
7,599
1.257
8.343
2.019
4,188
15,011
1,091
2,474
495
4.468
10,861
1,549
1,567
7,638
5,036
2,157
5,140
1,302
NO
211,830
129,388
138,540
869,021
136,090
96,816
30,115
18,770
323,306
256,082
66,976
416,732
270,129
148,285
250,043
196,157
227,276
38,279
140,013
159,612
313,398
190,703
165,134
215.260
82.958
99,059
40,427
26,422
235,805
79,435
370,644
226,686
52,543
464.847
246,041
148,722
450,447
26,801
125,810
43,996
201,186
1,703,854
81,333
19,371
214,515
183,420
101,725
185,749
96,769
N02
20,173
13,158
13,521
89,750
13,832
9,546
2,813
1,856
33,975
26,173
8,369
42,340
26.987
15.413
21,282
19,672
21,044
3,748
13,988
15,606
31,065
19,587
14,509
22,205
9,846
10,108
4,280
2,653
22,843
8.492
36,632
23,439
5,285
46,473
21,398
16,271
44,765
2,576
13,146
5,006
21,114
130.231
7,704
1,941
21,464
19,233
9,562
19,049
8,898
PB
450
266
239
2,202
285
275
64
34
965
591
90
1.013
580
323
226
374
458
112
409
457
882
416
269
509
88
153
92
91
640
154
1,140
640
61
1,074
370
285
1,048
71
339
59
534
1,628
134
56
555
379
184
465
75
CO
1.386,181
1,129,988
825,674
8,318,787
1,988,082
1,070,994
212,607
303,608
3,561,763
1,971,653
1,123,746
3,569.200
1,885,635
953,262
917.344
1.340,355
1,399,677
419,062
1.293,697
1.922.283
3.031.691
1,718.873
824,546
1,928,628
1,163,534
543,732
461,152
315,399
2,005,206
821,486
4.213,753
1,962,208
205,622
3,634,392
1,374,948
1,291,457
3,544,272
285.375
1,023,927
448,401
1,630,854
6,293,426
867,527
183,286
1,756,163
1,977,883
573,138
1,675,892
460,305
HCL
228
68
23
428
51
95
42
60
149
55
14
914
300
64
56
213
110
13
12
78
171
146
11
132
8
54
35
9
112
4
63
140
44
405
23
168
581
12
65
14
154
290
37
3
255
109
21
17?
24
nc IK ii IUNS • -
HF
19
15
29
13
0
0
0
15
180
15
63
43
109
5
6
66
89
2
43
2
10
6
0
16
0
5
2
0
24
0
5
218
12
685
5
0
19
0
47
1
103
54
15
0
61
25
0
16
4
NH3
10,307
6,270
11,879
24,821
15,596
1,765
1,860
54
6,265
14,034
7,269
25,997
16,026
55,475
30,929
7.320
4.041
379
2,713
94
9,258
29,208
6,760
15.656
3,361
40,214
639
1
62
3,968
12,663
11,299
5,843
12,992
12,575
3,855
14,295
0
3,103
11,739
7,097
45,521
1,732
2
5,782
7,277
296
28,488
1,361
TSP
324,721
738,483
762,611
1,270,490
981,546
101,665
29,762
12.915
743,351
762,263
289,127
667,247
267,980
985,539
1,641.200
294,684
399,343
98,844
173,764
174,978
667,996
969.282
510,721
2,327,940
781,493
941,094
808,466
56.527
275,792
1.101,789
505,141
530,350
1,130,736
719,389
943,192
1,648,059
1,129,363
28,357
280,287
619,220
491,227
5,034.369
570,563
90,124
324,141
237,197
291,670
551,496
416,158
CA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HG
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
307,466
218,495
188,431
1,741,365
308,815
235,995
46,477
39,581
707,835
436,411
199,0/4
757,981
431,131
199,014
190,4/7
307,445
299,195
112,585
275,218
382.374
653,507
365,924
189,819
416,300
203,560
111,735
82,145
79,202
536,991
139,561
971,335
481,737
45,956
798,590
237,363
281,638
826,664
64,596
239,576
84,908
381,382
1,280,270
138, 3i5
50,590
399,919
385,259
136,004
374,882
76,005
THC
325,457
233,414
197,759
1,870,442
329,252
248,858
48,860
42,847
741,133
455.264
204,797
809,780
459,945
216,218
204,439
320,190
314,845
118,029
288,777
408,635
699,089
387,963
200,396
444,126
209,119
120,200
87.238
83.247
571,389
147,388
1,020,955
503,494
49,662
854,509
248,082
296,527
862,116
68,694
253,176
89,028
402,718
1,344,007
147,996
53,011
418,827
408,890
141,791
401,137
80,655
2,222,054
227,031 10,516,517 1,013,019
21,806 81,810,673
6,234
2,042
538,140 34,702,650
NR 17,419,117 10,434,372
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U S. EMISSIONS OF HYDROCARBON SPECIES, AREA SOURCES
STATE | METHANE
ALABAMA
ARIZONA
ARKANSAS
CALIFORNIA
COLORADO
CONNECTICUT
DELAWARE
01 ST. OF COLUM.
FLORIDA
GEORGIA
IDAHO
ILLINOIS
INDIANA
IOWA
KANSAS
KENTUCKY
LOUISIANA
MAINE
MARYLAND
MASSACHUSETTS
MICHIGAN
MINNESOTA
MISSISSIPPI
MISSOURI
MONTANA
NEBRASKA
NEVADA
NEW HAMPSHIRE
HEW JERSEY
NEW MEXICO
NEW YORK
NORTH CAROLINA
NORTH DAKOTA
OHIO
OKLAHOMA
OREGON
eEHNSYLVAKIA
RHODE ISLAND
SOUTH CAROLINA
SOUTH DAKOTA
TENNESSEE
TEXAS
UTAH
VERMONT
VIRGINIA
WASHINGTON
UEST VIR'INIA
WISCONSIN
WYOMING
1,006,722
859,962
507,105
7,471,156
1,174,721
691,574
129,732
166,903
1,820,154
1,036,084
317,959
2,956,057
1,614,901
1,007,460
820,094
674,969
875,199
255,361
731,076
1,492,659
2,550,156
1,195,253
590,849
1,544,521
312.109
495,867
289,689
204,760
1.939,221
435.223
2,676,448
1,137.426
217.595
3,176,995
581.410
827.998
1,832.852
230.278
755,627
234,389
1,158,933
3,635,133
558,071
115,042
995,901
1,333,232
296,459
1,454,004
270,130
COIITIG U.S. |56,657,225
ETHANE
80,544
52,379
50,919
427,333
76,141
71,118
13,480
21,747
180,960
100,261
26,537
196,202
124,201
49,902
42,386
80,651
75,009
48,890
78,166
101,823
195,759
116,841
48,553
127,423
24,926
26,185
20,921
28,591
141,811
38,941
275,873
142,068
11,017
216,618
59,918
67,632
246,612
17,153
62.^5
15,667
112,779
267,130
34,742
21,030
120,932
96,904
42,121
119,623
17,386
4,616,552
PROPANE
32,894
21,176
22,491
138,442
27,697
24,758
3,834
702
57,752
47,456
58,708
58,175
44,446
14,121
15,743
44,159
28,924
22,732
25,006
28,620
66,994
44,304
25,704
51,214
60,938
8,179
7,436
13,082
44,667
11,878
99,802
59,545
3,494
75,275
32,880
49,331
97,997
5,350
26,348
19,313
45,058
129,482
10,484
10,246
43,696
56,325
21,195
42,639
6,853
1,887,549
BUTANE
236,403
147,539
136,187
1,469,099
263,790
177,595
37,347
17,888
584,929
356,264
104,213
578,903
318,845
173,465
156,909
229,541
249,301
62,697
231,979
315,030
498,735
265,582
139,238
319,950
105,580
97,859
69,617
49,786
414,929
119,001
712,633
344,569
39,334
606,783
176,549
189,163
578,053
49,168
181,589
54,188
284,122
1,011,080
117,082
28,794
311,657
287,745
98.707
272,044
60,941
13,332.479
IHUUiAND
ISO-BUTANE
46,247
24,629
29,068
252,663
37,203
29,829
6,127
2,925
110,420
75,184
47,989
101,539
54,760
30,042
27,410
49,999
51,782
11,528
40,853
53,674
91,025
46,587
31,935
54,565
48,748
16.373
10,746
9,463
72,989
14,920
145,119
66,910
7,113
104,434
40,610
47,653
110,299
8,847
38.332
18,762
51,131
210,281
15,967
5,587
53,758
62,747
20,635
47,096
7,804
2,544,314
MULti/TtAK
PENTANE
33,509
11,165
22,059
178,317
27,914
19,606
4,330
385
79,584
59,129
37,497
66,600
38,703
22,308
21,535
38,069
38,880
7,756
28,759
34,164
62,038
34,259
23,433
40,209
38,481
12,796
8,426
6,301
43,383
12,096
84,234
46,880
5,782
72,080
31,820
35,911
73,148
5,520
27.483
14.752
37.262
166,229
11,500
3,935
38,240
45,735
14.950
32,689
7,276
1,812,116
ISO-PENT
4,793
1,555
3,175
14,724
3,061
7,270
913
105
4,396
5,)38
2,177
12,444
11,190
1,128
1,034
7,697
2,106
8,059
5,732
5,826
16,095
10,194
3,460
12,457
2,130
622
739
4,348
10,553
2,514
27,191
14,509
207
17,888
4,694
5,660
28,688
1,284
3,565
671
11,052
2,808
1,328
3,521
11,822
6,379
5,194
11.066
840
324,000
ALKANES
2,038,501
1,455,417
1,236,663
12,069,466
2,049,828
1,552,607
310,588
290,342
4,829,449
2,911,021
1,099.704
5,264,179
2,800,201
1,423,644
1.297,866
1,922,222
2,051,293
578,620
1,876.443
2,712,644
4,412,612
2,326,042
1,233,233
2,648,867
1,098,161
779,023
529,155
463,192
3,677,126
885,888
6,677.461
3,064,158
311,649
5,365.673
1,528,458
1,706,956
5,290,006
450,030
1,618,386
514,883
2,415,745
8,655.100
921.474
262,908
2,574,230
2,470,341
831 ,609
2,421,096
456,850
115,361.007
ETHYLENE
606, 128
613,690
432,071
3,695,925
771,809
350,921
80,833
68,775
1,593,204
977,157
970,258
1,274,312
723,904
420,131
442,297
713,131
707,675
128,215
481,081
650,774
1,064,772
704,926
449,973
763,549
1,014,413
253.303
201,289
96,320
877,398
307,409
1,434,242
853,601
109,695
1,329,127
551,953
833,738
1,250,245
99,806
520,749
347,621
688,630
3,409,243
322,649
59,980
670.482
1, 043,843
264,131
621,835
207,354
36,114,563
PROPYLENE ISO-BUTENE
244,481
181,454
156,816
1,480.936
260,879
170,167
40,411
82,155
638,842
324,149
72,573
598,519
328,611
187,799
162,053
209,267
274,084
63,238
225,112
315,720
528,352
309,901
137,790
312,111
69,142
99,208
69,281
43,030
411,980
121,078
669,141
334,389
41,874
596,260
166,844
185.157
542,564
48,326
195,554
52,391
282,739
1,053,936
123,633
26,560
303,341
286,590
88,468
304,376
64,618
13,485,899
2,385
1,725
1,458
7,648
2,383
558
321
131
3,215
2,947
768
5,548
4,005
1,667
2,744
2,320
2,032
270
1,069
1,101
2. 214
1,813
1,196
2,317
1,429
1,233
866
127
1,914
1,856
2,106
2,193
768
6,018
1,373
2,155
4,951
150
1,120
367
2,761
8,657
1,875
126
2,319
1,814
1,106
1,832
2,287
103,241
ALKENES
467,679
393,545
291,925
2,530,776
514,027
305,801
58,358
31,552
1,079,736
689,205
627,881
950,824
557,914
266,563
278,262
506,022
457,735
146,146
365,446
494,895
852,649
521,172
315,291
589,752
652,896
156,644
135,458
104,788
674,652
205,836
1,231,589
686,509
63,624
1,028,418
398,523
564,325
1,068,480
82,557
363.185
220,751
527,477
2,197,503
208,124
68,327
534,561
714.198
207.356
482,048
118,080
25,989,063
A-57
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY • ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, AREA SOURCES
STATE | BEW2ENE
ALABAMA
ARIZONA
ARKANSAS
CALIFORNIA
COLORADO
CONNECTICUT
DELAWARE
DIST. OF COLUH.
FLORIDA
GEORGIA
IDAHO
ILLINOIS
INDIANA
I QUA
KANSAS
KENTUCKY
LOUISIANA
MAINE
MARYLAND
MASSACHUSETTS
MICHIGAN
MINNESOTA
MISSISSIPPI
MISSOURI
MONTANA
NEBRASKA
NEVADA
NEW HAMPSHIRE
NEW JERSEY
NEW MEXICO
NEW YORK
NORTH CAROLINA
NORTH DAKOTA
OHIO
OKLAHOMA
OREGON
PENNSYLVANIA
RHODE ISLAND
SOUTH CAROLINA
SOUTH DAKOTA
TENNESSEE
TEXAS
UTAH
VERMONT
VIRGINIA
WASHINGTON
WEST VIRGINIA
WISCONSIN
WYOMING
73,187
58,786
40,699
538,363
82,554
56,873
12,624
11,214
215,701
108,228
19,692
189,962
101,786
54,330
49,184
64,415
75,953
17,345
71,909
99,615
161,870
87,214
39,476
94.903
19.391
30,882
22,525
14.065
141,042
36.781
216.729
106,686
11,566
197,542
51,617
53,501
177,140
17,058
59,115
13,035
89,327
331.224
37,864
8,290
96.647
82.147
25,664
84,981
17,298
COHI 1C U.S. |4, 269. 998
TOLUENE
236,925
170,040
140,351
1,464.746
262,100
195,865
38,820
38,582
586,293
333,745
69,557
616,813
3-1.419
168,013
149.083
216.362
231,081
84.516
235,749
329,383
535,705
294,635
134,547
336,690
67,274
91,700
66,718
59,412
432,726
1)9.781
787,545
371 ,656
34,850
639,555
166,509
180,901
639,918
52,991
183,384
42,325
300.191
929, 757
118,725
36,728
329,609
278,087
100,400
309,194
57,270
13.608,223
XYLENE
188,409
86,257
118,944
757,446
146,202
235,996
33.462
15,050
280.358
220,630
73,930
478,356
373,532
71,183
64,152
253,086
115.693
228,013
207,327
233,561
551,788
336,137
126,776
405,520
71,609
39,381
38.820
126,966
378.940
95,622
897.992
473,576
15.176
619.920
166,045
190,838
899,765
46.651
140,002
28,705
359,068
326,379
63,807
99,704
387,017
235,926
158,901
360,169
35,236
11,858.021
ETH BENZ
41,644
18,351
26,430
165,768
31,509
54,915
7,518
1,976
56.079
48,562
16,650
109,934
86,289
15,689
13,936
58.143
24.726
53,094
47,333
53,368
127,056
76,510
28.350
93.226
16,168
8,608
7,712
29,664
87,453
21,038
211,044
108,087
3,075
144,306
37,590
43,421
210,314
10,812
31,311
6,169
82,608
64,336
13,991
23,279
89,141
52,5,9
37,125
82,794
7,728
2.687,709
THOUSAND 1
AROMATIC
65,134
48,823
37,998
333,689
64,829
34,341
9,551
16,965
164,885
84,784
18,365
144,590
81,593
42,367
45,516
53,239
64,764
13,804
49.884
65,776
107,974
65,519
35,455
71,950
21.230
25,472
22,473
9,084
85,305
35,154
139,868
81,567
13,104
141,702
42,170
46,300
131,788
9,855
44,049
12,021
68,109
264,999
33,696
5,764
70,463
45,171
22,982
64,283
24,215
3,203,622
WLES/YEAR
FORMALDEH ACETALOEH
241,190
184,575
142,012
1,536,069
287,242
204,283
48,346
24,223
634,024
337,754
76,462
620,033
349,683
193,543
181,550
323,730
336,037
69,152
264,929
372,323
494,381
289,784
146,515
334,883
83,576
115,943
73,645
52,060
527,852
138,049
814,902
348,743
54,252
642,340
162,683
192,389
664,008
56,079
180,171
49,077
302,734
1,181,458
138,278
32,114
345,554
324,739
104,891
290,730
92,403
14,661,391
49,935
36,076
30,464
161,253
49,907
11,868
6,751
2,737
67,244
61,616
16,064
116,840
84,081
34,862
57,484
48,970
42,850
5,730
22,400
23.305
46,636
38,090
24,988
48,522
29,867
25,764
18,123
2,705
41,937
38,933
44,484
46,186
16,039
126,469
28,889
45,198
104,468
3,210
23,587
7,671
58.225
183.323
39.184
2.662
48,774
37,994
23,116
38,561
47,772
2,171,814
ALDEH
21,587
21,823
7,377
96,374
19,947
5,351
1,901
6,187
79,247
24,013
4,698
28,478
8,619
4,958
6,750
10,406
15,006
3,550
11,536
14,539
15,765
8,832
11,715
14,962
3.776
5,019
12,298
2,241
12,246
9,236
30,349
24,748
4.298
17,696
12,180
7,404
23.263
1,921
9. 841
3.084
9,964
82,981
5.673
1,263
11,741
16,447
3,345
7,886
1,651
764,170
ACETONE
62,294
60,980
24,720
738,634
53,098
63,390
16, U7
4,129
257,016
102,220
9,822
216,141
120,889
41,246
43,957
71,256
85,696
18,221
60,037
94,655
168,924
81,067
33.875
74,843
10,447
23,413
18.113
13,860
256,135
26,463
216,515
118,195
6,750
220,738
51,547
50,721
205,879
23,115
64,019
6,396
108.206
432,597
26,468
11,020
97,893
60,091
12,591
77,557
4,356
4,646,372
KETONES ORG. ACID
40,978
22,358
26, 201
225,603
30,666
34,650
6,135
4,675
83.108
62,112
8,714
121,976
59,964
26,597
22,839
30,271
34,144
16,084
35,531
61,924
92,402
43,739
26,362
52,596
6,713
12,119
6,611
11,011
87,902
11,532
163,604
74,469
3,995
114,857
24,422
29,406
121,868
10,351
33,618
4,614
51,546
147,028
14,402
5,649
52,788
42,589
12,410
64,533
4,484
2,282,149
18,697
7,310
12.812
92.496
9,797
16,952
3,318
4,195
34,446
36,468
3,994
68,304
25,730
11,935
11,451
13.263
17.396
15,742
18,505
36.090
37,989
23,275
8,768
27,781
2,136
4,782
1,709
6,537
51,359
2,586
102,347
28,779
1,223
57,730
9,410
15,287
68,444
4,633
17,951
1.484
29,184
57,735
3,815
3,819
23.202
22,176
4.424
50,073
635
1,128,174
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
A-58
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, AREA SOURCES
EPA REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
C ONI 1C
1
Ul
VD
1
2
3
4
5
6
7
8
9
10
S02
134,520
186,507
260,590
423,203
424,252
499,063
137,696
127,157
156,195
100,212
U.S. | 2,449,395
S04
23.562
33,755
35,271
38,015
46,450
28,184
9.203
8,339
15,235
12,245
250,259
NO
404,880
668,495
1.053,352
1,880,752
2,029,969
2,640,196
785.558
544,200
1,145,121
439,953
11,592,476
N02
39,761
65,560
104,110
189,820
204,479
214,604
76.068
55,745
118.154
48,361
1,116,662
PB
1,170
1,963
2,528
4,590
4,884
3,141
1,335
774
2,821
831
24,037
CO
4,625,738
6,855,228
8,469,592
15,103,303
17,103,112
11,811,499
4,787.301
5,658,682
10,923,825
4,842,549
90,180,829
HCL
231
193
1,069
1,119
2,325
495
339
195
586
320
6,872
TONS/YEAR --
HF
4
31
151
715
958
194
35
34
32
97
2,251
NH3
2,470
14,026
27,558
72,957
134,448
85,962
156,830
43,688
34,976
20,282
593,197
TSP
606,816
860,832
2.162,310
4,340,465
4,236,611
9,084.482
6,498,978
4,960,088
3,105,694
2,396,847
38,253,123
CA
0
0
0
0
0
0
0
0
0
0
NR
HG
0
0
0
0
0
0
0
0
0
0
NR
NA
0
0
0
0
0
0
0
0
0
0
NR
K
0
0
0
0
0
0
0
0
0
0
NR
voc
1,020,013
1,662,642
1.900,234
3,363.893
3,728.034
2,364,260
1,011,400
945,319
2.250,925
954,569
19.201.2B9
THC
1,080,788
1,755,258
1,987,708
3,529,412
3,982,016
2,482,493
1,085,758
998,377
2,415,267
1,003,339
20,320,417
EPA REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
CC«1 1C
S02
1 122,034
2
3
4
5
6
7
8
9
10
U.S.
169,196
236.403
383,923
384.875
452,742
124,916
115,355
141,698
90,911
2,222,054
S04
21,375
30,622
31,997
34,487
42,139
25,568
8,349
7,565
13.821
11,108
227,031
NO
367,301
606,449
955,585
1,706,190
1,841,557
2,395,145
712,647
493,690
1,038,836
399,118
10,516,517
N02
36,071
59.475
94,447
172,202
185,500
194,685
69,008
50,571
107,188
43,873
1,013,019
PB
1,061
1,781
2,293
4,164
4,431
2,849
1,211
702
2,559
754
21,806
CO
4,196,399
6,218.958
7,683,485
13,701,486
15,515,682
10,715,212
4,342,966
5,133,470
9,909,927
4,393,087
81,810,673
HCL
210
175
970
1,015
2,109
449
308
177
532
290
6,234
HF NH3
4
28
137
649
869
176
32
31
29
88
2,042
2,241
12,725
25,000
66,185
121,969
77,984
142,274
39,633
31,730
18,400
538,140
TSP
550,494
780,934
1,961,615
3,937,604
3,843,389
8,241,304
5,895,774
4,499,716
2,817.438
2,174,383
34,702,650
CA
0
0
0
0
0
0
0
0
0
0
NR
MG
0
0
0
0
0
0
0
0
0
0
NR
NA
0
0
0
0
0
0
0
0
0
0
NR
K
0
0
0
0
0
0
0
0
0
0
NR
VOC
925,340
1,508,324
1.723,864
3,051,672
3,382,015
2,144,821
917,527
857,579
2,042,005
865,970
17,419,117
THC
980,475
1,592,344
1,803,219
3,201,828
3,612,424
2,252,080
984,983
905,713
2,191,093
910,214
18,434,372
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, AREA SOURCES
I
o
EPA REGION
REGION 1
REGION 2
REGION 3
REGION 4
REGION 5
REGION 6
REGION 7
REGION 8
REGION 9
REGION 10
CONTIG U.S.
1
METHANE
2.991.475
4,615.669
4,152.923
8,180.765
12.947.366
6.034.071
3,867,942
2.767,015
8,620,807
2,479,190
56,657,225
ETHANE
288,604
417,684
523,059
808,562
969,243
491,917
245,896
179,879
500,633
191,072
4,616,552
PROPANE
104,788
144,468
192,430
338,917
331 ,834
225,657
89,256
128,779
167,054
164,365
1,887,549
BUTANE
683,067
1,127,562
1,275,631
2,356,735
2,540,891
1,692,118
748,183
640,915
1,686,255
581,121
13,332,479
1 nUUAANU
I SO- BUTANE
118,929
218,108
234,601
470,159
445,442
346,662
128,388
135,597
288,039
158,389
2,544,314
nuLCa/TCHi'
PENTANE
77,282
132,616
159,812
345,350
306,369
271,083
96,848
105,704
197,908
119,143
1,812,116
j
ISO-PENT
30,308
37,743
52,453
54,609
78,878
15,298
15,241
8,237
17,017
14,216
324,000
ALKANES
6,020,002
10,354,587
11,173,216
20,032,714
22,589,803
14,357,402
6,149,400
5,352,845
14,054,038
5,277,001
115,361.007
ETHYLENE
1,386,017
2,311,640
2,815,546
6,462,573
5,718,876
5,408,350
1,879,279
2,773,540
4,510,904
2,847,838
36,114,563
PROPYLENE I
667,040
1,081,121
1,282,050
2,367,210
2,666,020
1,772,759
761,171
612,537
1,731,671
544,320
13,485,899
SO-BUTENE
2,332
4,020
9,897
18,138
21,432
15,376
7,961
9,109
10,240
4,737
103,241
E ALKENES
1,202,514
1,906,241
2,265,753
4,635,102
4,393,024
3,551,523
1,291,221
1,777,501
3,059,779
1,906,404
25,989,063
... -.+ — .
EPA REGION | BENZENE
REGION 1
REGION 2
REGION 3
REGION 4
REGION 5
REGION 6
REGION 7
REGION 8
REGION 9
REGION 10
213,247
357,770
395.218
756,136
825,356
536,274
229,299
181,687
619,673
155,339
CONTIG U.S. (4,269,998
TOLUENE
758,896
1,220,271 1
1,383,077 1
2,363,102 2
2,737,321 2
1,587,478
745,486
582,543
1,701,504
528,545
13,608,223 11
XYLENE
970,891
,276,932
,701,521
,041,904
,719,902
822,683
580,236
360,735
882,523
500,695
,858,021
ETH BENZ
225,132
298,497
393,408
454,784
626,890
174,120
131,459
78,640
191,830
112,950
2,687,709
THOUSAND
AROMATIC
138,625
225,173
301,633
597,223
605,661
445,085
185,306
170,096
404,985
129,835
3,203,622
For conversion of hydrocarbon classes to tons/year, see discussion
MOLES/TEAK
FORMALDEH
786,012
1,342,754
1,451,952
2,514,860
2,686,951
1,960,240
825,919
704,827
1,794,288
593,589
14,661,391
in Appendix
ACETALDEH
49,479
86,421
208,246
380,752
450,676
324,460
166,632
190,439
215,452
99,256
2,171,814
E.
ALDEH
28,865
42,595
57,973
191,521
87,276
126,780
31,689
38,428
130,495
28,549
764,170
ACETONE
224,261
472,650
396,705
817,082
885,316
621,023
183,459
107,515
817,727
120,635
4,646,372
KETONES
139,669
251,505
233,407
402,465
497,471
243,326
114,151
64,874
254,572
80,709
2,282,149
ORG. ACID
83,774
153,706
122,087
187,556
263,101
99,939
55,949
19,091
101,515
41,457
1,128,174
-------
«»ENIUK? - ANNUAL U.I. tMlSSlONS, POINT SOURCES
>
6-DIG1T SCC
101002
101003
101004
101005
101006
102001
102002
102003
102004
102005
102006
102007
102008
102009
102010
102011
102012
102013
103001
103002
103003
103004
103005
103006
103009
103012
103013
103900
105001
105002
199999
201001
201002
202001
202002
202003
202004
203001
203002
204001
204004
299999
301001
301003
301005
301006
301007
301008
301009
301010
301011
301012
301013
301014
S02
15,793.408
279,553
1.385,537
8,359
968
3,590
1.187,896
52,631
1,045,988
95,558
41,503
301,546
4,471
15,464
54
616
3,448
17,505
309
83.411
1,804
81.373
20,061
619
265
0
0
0
31,800
955
8,675
9.741
26
3,215
4,917
9
10
10
3
195
58
0
1,465
1,415
19,919
1,820
0
0
751
to
0
125
7,325
4,558
S04
338,017
36,021
41,110
1,035
0
2/f
43,699
3,039
22,414
4,104
204
1,114
16
70,815
0
0
0
0
17
3,087
119
10,099
990
0
1,418
0
0
0
165
615
0
17
0
13
0
0
0
0
0
0
0
0
0
4
0
0
0
0
0
0
0
0
0
0
NO
4,829,659
195,246
385,608
5,142
707,302
1,915
379,322
11,450
275,820
38,473
489,234
97,170
1,170
94,354
169
1,791
1,804
2,751
107
18,525
329
31,843
3,421
37,561
2,657
0
0
0
10,568
889
2,392
28,270
76,836
12.216
604,240
149
632
455
769
637
796
508
4,355
6.619
1,199
19,551
0
0
112
2,245
0
0
45,534
0
N02
149,371
6,039
7,870
105
37,226
93
11.732
354
5,629
785
25,749
4,789
36
2,918
9
94
56
56
3
573
10
650
70
1,977
82
0
0
0
527
18
126
3,141
4,904
1,357
38,568
17
70
51
49
41
88
27
229
348
63
1,029
0
0
6
118
0
0
2,397
0
Pb
30
5
0
0
0
0
28
0
0
0
0
0
0
0
0
0
0
366
0
1
0
0
0
0
0
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
160,708
13,569
39,829
1,105
68,311
116
35.225
3,691
53,251
7,814
107,103
14,157
19,147
103,091
23
1,443
15
114
4
4,435
341
2,352
1,010
4.936
1,711
0
0
0
43.506
222
498
6,994
16,567
3,656
112,937
6,440
183
80
1,366
474
1,200
118
28,485
62,182
1,841,589
70,711
0
100
23
0
160
0
5,558
0
HCI
474,292
158
0
0
0
374
31,492
258
0
0
0
0
0
0
0
0
0
0
21
1,730
18
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
731
0
0
0
TONS/YEA8-
HF
57,413
158
0
0
0
16
12,210
44
0
0
0
0
0
0
0
0
0
0
0
185
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
133
7
0
0
0
0
10
1
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3,108
0
0
0
0
0
0
Q
0
0
0
ISP
521,611
52,263
54,266
94
4,620
252
347,169
24,348
79,592
6,362
17,099
11.388
2,060
91,961
58
8,872
1,813
650
403
29,094
2,060
33,884
10.236
1.300
1.059
31
1
3
3,102
131
1,219
2,187
1,420
817
3,158
187
47
14
9
156
210
0
97
518
2,848
76,161
0
54
1.034
998
51
1,020
1,331
1,862
Ca
8,450
847
0
0
0
4
5,623
394
0
0
0
0
0
46
0
0
0
0
7
471
33
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Hg
8,920
894
0
0
0
4
5.935
416
0
0
0
0
0
37
0
0
0
0
7
498
35
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Na
4,277
429
0
0
0
2
2,846
200
0
0
0
0
0
37
0
0
. 0
0
3
239
17
0
Q
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1C
2,295
230
0
0
0
1
1,527
107
0
0
0
0
0
1,793
0
0
0
0
2
128
9
0
0
0
21
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
25,827
2,022
12,677
45
1,362
10
6,155
132
50,266
16,029
12,809
7,567
296
62,442
10
4,053
22
64
3
950
29
1,353
877
1,174
926
0
6
0
3,470
218
1,230
1,984
2.018
1,517
12,183
274
17
19
10
76
370
1
9,119
15,468
189,542
94,612
727
370
599
714
42
0
1,491
16,010
THC
26,382
2,065
14.244
45
3,096
18
6,594
135
56,481
16,029
29,109
11,254
302
63,785
22
4,053
22
64
3
970
30
1,521
877
2,668
946
0
6
0
5.210
218
1.230
2,318
7,627
1.772
83,323
320
20
22
73
545
432
1
9,119
15,468
189,542
94,612
733
370
599
714
96
0
1,491
16,010
-------
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-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
6-DIGIT SCC
304022
304034
304050
304888
304999
305001
305002
305003
305004
305005
305006
305007
305008
305009
305010
305011
305012
305013
305014
305015
3050 14
305017
305018
305019
305020
305021
305022
305024
305025
305026
305031
305032
305040
305100
305103
305888
305999
306001
306002
306003
306004
306005
306006
306007
306008
306009
306010
306011
306012
306014
306100
306888
306999
307001
S02
1
67
0
0
2,677
10
42.343
6,288
166
829
187,090
158,859
457
472
11,673
0
5,532
0
28.602
259
15,937
1.278
0
26,487
2,003
440
0
0
78
3
0
0
5,514
120
0
292
6,910
296.609
263.612
9,474
12,150
1,344
1.229
0
1,984
16,083
0
84
19,455
4.021
0
469
61,103
106,094
S04
0
0
0
0
0
0
0
26
1
0
2.266
7,611
0
0
36
0
15
0
87
13.205
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
747
8,594
11
56
0
0
0
0
0
0
0
0
0
0
0
0
41,572
NO
841
162
0
0
259
3
9,120
3,526
0
856
52,172
57,468
122
178
3,533
4,167
5,439
0
40,669
65
26,666
122
0
616
619
590
0
61
61
10
0
0
2,345
0
0
0
1.684
186,190
38,763
383
8,125
13
103
0
2.362
1,714
0
49
1,777
1,150
0
229
5,373
45,078
N02
44
9
0
0
14
0
480
149
0
45
1,140
1,259
4
9
110
219
286
0
2,140
3
825
6
0
32
33
31
0
3
3
1
0
0
123
0
0
0
89
7,919
6,841
68
428
1
15
0
124
90
0
3
314
61
0
12
283
2,373
Pb
0
0
0
0
0
0
0
0
0
0
302
207
0
0
0
0
0
0
991
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
27
0
554
0
252
2,330
5,992
1,981
45
64
1,296
2,227
1
4
137
86
1,030
0
10.815
16
29.711
10.806
0
3
33
0
0
43
3
6
0
1
382
0
0
258
8,282
18,384
1,363,517
102,795
1,910
34
9
0
132
104
0
388
6
47
0
0
57,420
713,756
HCL
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TONS/TtAK-
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8,427
87
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ISP
128
0
25
77
3,190
4,647
73.020
128,969
474
8,044
135.301
214,451
20,986
9,518
54,260
3,526
19,030
96
14,784
21,655
86,894
3,109
1,078
17,411
354,666
827
2,530
13,609
21,164
617
292
83
32,457
1,233
634
3,216
36,960
18,730
45,761
3,097
17
240
5
0
163
391
0
36
51,386
1,786
0
174
3,376
78,608
Ca
0
0
0
0
0
0
0
0
0
0
38,561
0
178
0
0
1,622
0
0
0
0
29,448
0
0
0
20,464
0
0
0
138
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
94
Mg
0
0
0
0
0
0
0
0
0
0
1,055
0
189
0
0
53
0
0
0
0
4,353
0
0
0
5,994
0
0
0
148
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ha
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
. 0
0
0
0
434
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,085
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
206
0
477
1
563
2,875
619
819
306
19
433
452
35
10
2,267
6
1,480
74
1,950
8
1,009
49
49
0
60
0
0
0
1
0
0
946
41
0
0
174
2,158
6,278
63,337
2,294
15,632
107,178
34,549
6,851
81,570
5,809
1,419
50,007
1,928
236
2,796
20,992
35,893
11,513
THC
325
0
753
1
890
2,881
1,408
1,708
306
45
486
512
95
28
2,316
16
4,229
211
5.319
11
1,031
78
141
1
171
0
0
0
2
0
0
2,702
116
0
0
174
6,167
11,405
98,954
3,584
18,317
112,366
42,465
6,851
93,104
1 1 , 620
1,419
60,326
3,012
536
2,796
30,153
54,718
11,682
-------
1980 NAPAP S.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POUT SOURCES
6-DIGIT SCC
307002
307003
307004
307005
307007
307008
307011
307013
307020
307030
307888
307999
308001
308006
308007
309001
309002
309010
309011
309020
309030
309060
309888
309999
310001
310002
312999
320999
330001
330002
330003
330004
390001
390002
390004
390005
390006
390007
390008
390009
390010
390012
390013
399999
401001
401002
401003
401888
401913
402001
402002
402003
402004
402005
S02
30.417
10
0
0
372
3.073
5
0
2
7
0
919
0
0
0
0
0
0
0
0
0
0
0
140
1.038
1,075
0
0
43
0
1
0
903
71,893
46,919
4,029
38,151
13,403
5,601
0
0
62
0
29,212
0
327
0
0
0
2
0
0
0
0
S04
5,444
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
0
0
0
0
0
0
0
192
64
9
109
0
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HO
1,754
0
52
0
4,560
3,485
0
0
0
46
0
649
0
116
0
0
0
0
0
4
0
0
0
371
0
2,759
7
0
18
0
1
0
1,968
2,680
6,549
3,479
26,811
2,260
1,055
325
10
0
0
13.870
0
2
1
0
0
302
0
C
£
28:
N02
92
0
3
0
240
183
0
0
0
2
0
34
0
6
0
0
0
0
0
0
0
0
0
20
0
145
0
0
1
0
0
0
61
83
138
71
1,411
119
56
17
1
0
0
730
0
0
0
0
0
16
0
0
0
15
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
276
0
0
0
1,471
763
0
0
0
148
0
9,561
0
34
0
0
0
0
0
1
0
0
0
3
0
1,593
2
0
3
0
1
0
120
29,478
1,005
1,785
52,259
22,220
34,160
0
1
0
0
77,163
0
3
0
0
0
84
0
0
1
183
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
JUS/ ICAK-
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
2,767
89
1,242
1
45,723
13.221
0
0
13,270
2,739
843
5,243
182
254
124
93
765
77
0
61
2,669
135
90,275
2,022
720
502
240
4
1,223
98
85
14
428
8,569
3,057
4,251
11,429
2,515
426
1,612
846
10
0
48,893 .
0
205
0
0
0
1.093
0
103
455
486
Ca
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7
139
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Hg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7
147
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ha
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
. 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
70
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2
38
0
0
0
0
0
31
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
237
176
2,157
244
6,559
1,923
8,488
157
4,579
189
714
1,617
11.073
1.033
6,813
467
0
1,992
49
4,450
754
0
69
3,198
13,139
804
0
419
22,377
3,766
82
94
6
664
1,719
860
11,261
234
46
130
756
0
0
90,446
7,633
100,419
921
407
66
245,536
2,015
34,008
140,729
122,551
THC
237
176
2,157
244
6,559
1,923
8,488
157
4, 579
189
714
1,617
11,073
1,033
6,813
737
0
2,758
67
7,031
1,045
0
96
3,198
13,139
862
0
419
22,377
3,766
82
94
6
678
1,931
860
25,493
404
46
130
1,718
0
0
205,538
7,633
100,419
921
407
66
245,536
2,015
34,008
140,729
122,551
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
6-OIGIT SCC
... ... ^
402006
402007
402008
402009
402010
402011
402013
402014
402016
402017
402018
402019
402020
402021
402022
402023
402024
402025
402888
402901
402999
403001
403002
403003
403010
403011
403012
403888
403999
404001
404002
405001
405002
405003
405004
405005
40S006
405888
406001
406002
406003
406004
406888
490001
490999
501001
501002
501005
501900
501999
502001
502002
502003
502005
S02
0
2
193
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
0
0
425
0
0
0
4,350
0
0
223
0
0
0
0
0
0
0
0
3
0
0
0
0
0
0
0
5,322
281
381
1,139
6
2,101
0
0
1,881
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9
0
0
0
0
4
0
0
12
NO
7
16
162
588
48
0
0
0
0
471
2
0
0
0
0
0
0
0
0
0
651
4
0
0
95
923
0
0
0
76
0
10
10
276
6
29
0
0
0
0
0
0
0
0
3
4,743
1,485
1,362
0
0
1,690
14
0
10,025
N02
0
2
18
31
3
0
0
0
0
25
0
0
0
0
0
0
0
0
0
0
34
0
0
0
5
49
0
0
0
4
0
1
1
15
0
2
0
0
0
0
0
0
0
0
0
837
262
240
0
0
298
2
0
1,769
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
143
0
2
0
0
79
0
0
23
CO
1
2,048
575
42
13
0
0
0
0
83
0
0
0
0
0
0
0
0
0
0
557
1
0
0
66,886
33,443
0
0
88
0
0
14
0
38
0
17
0
0
100,329
0
0
0
0
0
0
58,001
25,938
1,988
20
34
14,550
577
0
0
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5,357
0
26
0
0
2,104
0
0
0
TONS/YEAR-
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
1,129
69
1,504
818
11
0
0
0
3
0
0
0
0
0
0
49
2
0
0
0
8,724
1,720
134
0
357
1,110
0
0
359
2,982
0
53
0
45
0
423
0
0
1,737
2
32
16
0
0
445
12,541
4,905
5,968
287
30
1,837
70
0
1,924
Ca
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
71
26
1
0
0
10
0
0
0
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
18
6
0
0
0
3
0
0
0
Na
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
. 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
71
26
1
0
0
10
0
0
0
c
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
60
22
0
0
0
9
1
0
0
voc
78,612
22,573
21,367
221,147
3,858
1,928
16,518
103
923
31.769
314
337
475
140
5,060
245
18
1,655
29,090
64
88,798
161,522
66,658
3,839
41,475
34,742
23,430
4,627
29,774
113.930
2,205
24,311
3,664
15,344
27,533
66,633
420
561
90,703
21,748
5,748
8,866
3,147
2,116
95,261
1,311
12,612
72
0
6
1,228
35
0
382
THC
78,612
22,573
61,451
221,147
3,858
1,928
16,518
103
923
32,037
314
337
519
140
5,060
245
18
1,655
29,090
64
88,798
170,891
67,330
3,868
42,274
34,984
23,430
4,736
29,774
113,930
2,205
101,339
15,157
15,344
27,533
66,633
420
1,055
91,457
22,615
5,748
8,866
3,147
2.902
130,632
6,682
12,612
406
2
6
2,646
177
0
2,262
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
6-DIG1T SCC
502900
503001
503002
503005
503007
503900
599999
U.S. TOTAL
S02
535
17,600
63
87!
0
2,081
156
24,504,741
S04
0
4
0
2
0
0
0
725,149
NO
10
6,670
566
2,287
0
685
0
9,284,610
N02
1
1,177
100
404
0
121
0
358,489
Pb
0
93
0
4
0
0
0
7,695
CO
1
218,560
22,412
351
0
2,293
0
9,128,108
HCI
0
3,091
0
0
0
0
0
519,652
TONS/YEAR
HF
0
0
0
0
0
0
0
113,183
NH3
0
0
0
0
0
0
0
245,467
TSP
125
19,264
1,765
16.130
95
589
0
4,364,247
Ca
0
0
0
J>
0
0
0
113,808
Hg
0
0
0
0
0
0
0
32,025
Na
0
0
0
0
0
0
0
12,975
K
0
0
0
0
0
0
0
15.474
VOC
82
5,500
4,243
80
0
181
19
3,963,258
THC
187
28,037
7,369
476
0
925
98
4,657,042
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
6-DIGIT SCC SOZ
101002
101003
101004
101005
101006
102001
102002
102003
102004
102005
102006
102007
102008
102009
102010
102011
102012
102013
103001
103002
103003
103004
103005
£> 103006
1 103009
J£ 103012
00
103013
103900
105001
105002
199999
201001
201002
202001
202002
202003
202004
203001
203002
204001
204004
299999
301001
301003
301005
301006
301007
301008
301009
301010
301011
301012
301013
3010U
14.327,814
253,611
1,256,962
7,583
878
3,257
1,077,662
47,747
948,923
86,690
37,652
273.564
4,056
14,029
49
559
3,128
15,881
280
75.671
1,637
73,821
18,199
562
240
0
0
0
28,849
866
7.870
8,837
24
2,917
4,461
8
9
9
3
177
53
0
1.329
1.284
18,071
1,651
0
0
681
73
0
113
6,645
4,135
S04
306,650
32,678
37,295
939
0
251
39,644
2.757
20,334
3,723
185
1,011
15
64.244
0
0
0
0
15
2,801
108
9,162
898
0
1,286
0
0
0
150
558
0
15
0
12
0
0
0
0
0
0
0
0
0
4
0
0
0
0
0
0
0
0
0
0
NO
4,381,477
177,128
349,825
4,665
641,666
1,738
344,122
10,387
250,225
34.903
443.834
88,153
1,061
85,598
153
1,625
1,637
2,496
97
16,806
298
28,888
3,104
34,076
2,410
0
0
0
9,588
806
2,170
25,647
69,705
11,082
548,167
135
573
413
698
578
722
461
3.951
6.004
1,088
17,737
0
0
102
2,037
0
0
41,309
0
N02
135,510
5,478
7,139
95
33,772
84
10,643
321
5,107
712
23.360
4,344
33
2,647
8
86
51
51
3
520
9
590
63
1,793
75
0
0
0
478
16
114
2,850
4,449
1,231
34,989
15
64
46
45
37
80
24
208
316
57
934
0
0
5
107
0
0
2,174
0
Pb
27
5
0
0
0
0
25
0
0
0
0
0
0
0
0
0
0
332
0
1
0
0
0
0
0
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
145,795
12,310
36,133
1,002
61,972
105
31,956
3,348
48,309
7,089
97,164
12,843
17,370
93,524
21
1,309
14
103
4
4,023
309
2,134
916
4.478
1,552
0
0
0
39,469
201
452
6,345
15,030
3.317
102,457
5,842
166
73
1,239
430
1,089
107
25,842
56.412
1,670,694
64,149
0
91
21
0
145
0
5,042
0
HCl
430,279
143
0
0
0
339
28,570
234
0
0
0
0
0
0
0
0
0
0
19
1,569
16
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
663
0
0
0
METRIC TONS/YEAR-- -
HF NH3
52,085
143
0
0
0
15
11,077
40
0
0
0
0
0
0
0
0
0
0
0
168
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
121
6
0
0
0
0
9
1
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2,820
0
0
0
0
0
0
0
0
0
0
TSP
473,207
47,413
49,230
85
4,191
229
314,953
22,089
72,206
5,772
15,512
10,331
1,869
83,427
53
8,049
1,645
590
366
26,394
1,869
30,740
9,286
1,179
961
28
1
3
2,814
119
1,106
1,984
1,288
741
2,865
170
43
13
8
142
191
0
88
470
2,584
69,093
0
49
938
905
46
925
1,207
1,689
Ca
7,666
768
0
0
0
4
5,101
358
0
0
0
0
0
42
0
0
0
0
6
428
30
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Mg
8,092
811
0
0
0
4
5,385
378
0
0
0
0
0
33
0
0
0
0
6
451
32
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Na
3,880
389
0
0
0
2
2,582
181
0
0
0
0
0
33
0
0
0
0
3
216
15
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
K
2,082
209
0
0
0
1
1,385
97
0
0
0
0
0
1,627
0
0
0
0
2
116
8
0
0
0
19
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
23,430
1,834
11,500
41
1,236
9
5,856
120
45,601
14,541
11,621
6,865
268
56,648
9
3,677
20
58
3
861
27
1,228
796
1,065
840
0
5
0
3,148
198
1,116
1,800
1.831
1,376
11,052
249
16
17
9
69
336
1
8. 272
14,033
171,953
85,832
660
336
543
648
38
0
1,352
14,524
THC
23,934
1.873
12,922
41
2,809
17
5,982
122
51,239
14,541
26,408
10,210
274
57,866
20
3,677
20
58
3
880
27
1,379
796
2,420
858
0
5
0
4,727
198
1,116
2,103
6,919
1,608
75,591
290
18
20
66
494
392
1
8,272
14,033
171,953
85,832
665
336
543
648
87
0
1,352
14,524
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
ON
VO
6-D1GIT SCC S02
301015
301016
301017
301018
301019
301020
301021
301022
301023
301024
301025
301026
301027
301028
301029
301030
301031
301032
301033
301034
301035
301036
301040
301041
301042
301050
301060
301091
301100
301111
301120
301125
301130
301132
301137
301156
301167
301 169
301174
301181
301197
301202
301206
301250
301251
301253
301254
301258
301820
301830
301888
301900
301999
302001
0
10,864
1
1.640
332
0
220
6,990
261,997
6,773
548
4,585
909
952
5.421
7,875
0
228,517
717
983
10,201
0
0
1,732
0
0
20S
34
0
0
0
227
0
63
435
0
0
0
0
0
2.689
0
0
1
0
0
22
0
220
0
224
165,666
52,368
1
S04
0
0
0
0
5
0
0
0
1,297
0
0
0
0
0
0
0
0
2,792
0
0
4
0
0
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NO
0
0
72
262
0
0
407
0
325
2
0
256
1,675
0
13
7,038
0
581
583
3,107
1,235
0
0
0
10
0
10
38
0
0
7
46
0
577
6
0
0
0
0
0
318
0
0
2,298
0
0
194
0
0
0
4
440
28.237
170
N02
0
0
4
14
0
0
21
0
17
0
0
13
88
0
1
370
0
31
31
164
65
0
0
0
1
0
1
2
0
0
0
2
0
30
0
0
0
0
0
0
17
0
0
121
0
0
10
0
0
0
0
23
1,486
9
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
0
11
0
202
19,972
0
4,511
0
1,102
3.778
0
17,240
7,368
0
4
4
32,530
2,126
0
103
24,876
0
0
102
0
0
158
0
12,010
0
2
0
0
159
41
0
0
0
0
9
1.326
0
0
3,596
0
0
5,377
45
61
0
33
22
218,974
14
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HtlKIL lUNS/TtAK
HF NH3
0
1,497
0
0
0
0
0
0
0
0
0
0
0
0
27,056
1,754
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
203.933
0
0
695
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
9
968
341
53,117
6,526
5
4,420
327
14,361
1,094
38
1,306
10,192
3,094
559
7,444
262
891
24
376
1,492
286
4,361
303
18
0
3.581
0
0
79
343
15
57
246
0
0
0
0
0
0
55
0
0
5
0
0
0
3
27
165
11,404
373
47,258
16,849
Ca
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
M9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Q
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Na
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
5,402
0
10
95,707
514
1,605
198
0
56
15,621
19,804
81,764
41
0
3
29
53.049
1,274
2,485
2,428
4
0
0
2,954
1,750
1,079
1,369
723
225
0
1.224
1,911
137
4,147
294
118
124
345
1,508
90
20,868
925
472
1,244
906
96
7,579
6,719
1,683
0
424
591
191,735
4
THC
5,402
0
10
96.456
1,853
1,605
198
0
57
15,621
20,157
81,764
41
0
3
29
53,049
1,274
2,485
2,460
6
0
0
3,006
1.750
1,098
1,392
723
225
0
1,224
1,911
227
4,217
299
118
124
345
1,535
90
20,868
925
472
1,244
906
96
7,579
6,758
1,683
0
431
591
191,735
4
-------
1980 HAPAP S.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS. POINT SOURCES
6 DIGIT SCC S02
302002
302004
302005
302006
302007
302008
302009
302010
302012
302013
302014
302015
302016
302017
302018
302019
302020
302026
302030
302031
302032
302033
302888
^ 302999
I 303000
^ 303001
303002
303003
303004
303005
303006
303007
303008
303009
303010
303011
303012
303013
303014
303023
303030
303888
303999
304001
304002
304003
304004
304005
304006
304007
304008
304009
304010
304020
0
0
16
5
180
464
1.147
0
0
0
96
1,519
634
0
0
0
0
0
0
0
1,085
0
0
1,126
0
79,475
1,273
68,690
27
997,057
351
83
57,521
48,773
52,529
1,759
0
0
1,999
9,625
34,286
3
2,502
985
5
6,627
24,127
0
29
6,177
1,555
0
0
696
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
509
0
11,560
0
32,109
0
0
670
0
1.390
0
0
0
0
31
10.185
0
0
0
0
8
89
0
0
0
0
0
0
0
NO
53
0
1
76
23
4
109
0
0
1
0
0
306
0
0
0
0
0
1
0
0
0
2
367
0
113.158
848
3,681
3
895
95
0
14,956
25,042
2
0
141
0
178
0
86
1
93
7.629
803
984
309
0
3
2,877
531
0
0
2;
N02
3
0
0
4
1
0
6
0
0
0
0
0
16
0
0
0
0
0
0
0
0
0
0
19
0
5,956
45
194
0
47
5
0
1,079
2,148
0
0
7
0
9
0
5
0
16
402
42
174
16
0
0
508
28
0
0
1
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
145
54
0
1,130
1,523
805
0
0
0
0
0
349
0
0
0
207
451
250
0
0
0
0
0
0
0
CO
44
0
0
48
3
15
13
0
0
65
0
16
23
0
0
0
0
0
0
0
0
0
24
15
0
615,956
148
34.471
10
6,542
256
329
1,012,107
335,050
39,853
0
4,530
0
5,390
0
15
0
501
892
3,386
445,491
145
0
5,797
4,837
15
0
0
3
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HCIKIl lUNi/ TC«K-- -
HF NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8,844
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
691
0
0
0
0
0
0
0
0
0
0
6,689
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
1,794
561
40,913
181,743
39,119
8,782
1,465
557
3
25
1,439
1,528
7,107
485
0
99
2,313
0
133
442
17
0
347
4,641
5,169
42,620
19,326
53,145
1.967
18,654
25,589
1,116
148,196
58,116
6,467
3,601
1
0
2,391
62,067
8,035
1,677
954
10,504
4,400
33,418
7,884
0
135
5,823
2,763
126
0
713
Ca
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
271
0
5,898
0
0
0
0
0
0
304
0
0
0
0
0
0
0
0
32
0
0
0
0
0
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
371
0
2,460
0
0
0
0
0
0
149
0
0
0
0
0
0
0
0
19
0
0
0
0
0
Ha
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
345
0
2,579
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8,343
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
44
0
0
0
690
2
367
21,804
23
762
0
0
6
0
16
707
0
0
0
0
4
1,735
14
336
0
14,024
8
29.601
36
15
17
0
3,925
3,«73
0
66
0
0
387
0
3
0
76
3,313
161
1,653
2,987
0
0
94
3
0
0
151
THC
44
0
0
0
6,391
2
1,970
21,804
305
778
0
0
6
0
215
9,238
0
0
0
0
52
1,735
147
4,391
0
30,027
8
63,380
78
18
20
0
16,143
4,038
0
66
0
0
387
0
5
0
186
5,234
254
4,053
4,718
0
0
231
6
0
0
151
-------
1980 MAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS. POINT SOURCES
>
6-DlGlF SCC | SO2
304022
304034
304050
304888
304999
305001
305002
305003
305004
305005
305006
305007
305008
305009
305010
305011
305012
305013
3050H
305015
305016
305017
305018
305019
305020
305021
305022
305024
305025
305026
305031
305032
305040
305100
305103
305888
305999
306001
306002
306003
306004
306005
306006
306007
306008
306009
306010
306011
306012
306014
306100
306888
306999
307001
1
61
0
0
2,429
9
38,414
5,704
15)
752
169,728
144,117
415
428
10,590
0
5,019
0
25,948
235
14.458
1,159
0
24,029
1,817
399
0
0
71
3
0
0
5,002
109
0
265
6,269
269,085
239,149
8,595
11,023
1.219
1,115
0
1,800
14,591
0
76
17,650
3,648
0
425
55,433
96,249
S04
0
0
0
0
0
0
0
24
1
0
2,056
6,905
0
0
33
0
14
0
79
11,980
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
678
7,796
10
51
0
0
0
0
0
0
0
0
0
0
0
0
37.714
NO
763
147
0
0
235
3
8,274
3,199
0
777
47,330
52,135
111
161
3,205
3,780
4,934
0
34,895
59
24,192
110
0
558
562
535
0
55
55
9
0
0
2,127
0
0
0
1,528
168,912
35,166
348
7,371
12
94
0
2,143
1,555
0
45
1,612
1,044
0
20t
4,875
40,894
N02
40
8
0
0
12
0
435
135
0
41
1,035
1,142
4
8
100
199
260
0
1,942
2
748
6
0
29
30
28
0
3
3
0
0
0
112
0
0
0
80
7,184
6,206
61
388
1
14
0
113
82
0
2.
284"
55
0
11
257
2,152
Pb
0
0
0
0
0
0
0
0
0
0
274
188
0
0
0
0
0
0
899
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
24
0
503
0
229
2,114
5,436
1,797
41
58
1,176
2,020
1
4
124
78
934
0
9,811
15
26,954
9,803
0
3
30
0
0
39
3
5
0
1
347
0
0
234
7,513
16,678
1,236,986
93,256
1,733
31
8
0
120
94
0
352
5
43
0
0
52.092
647,521
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
METRIC TONS/YEAR---
HF NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7,645
79
0
0
0
0
0
0
• 0
0
0
0
0
0
0
0
TSP
116
0
23
70
2,894
4,216
66.244
117,001
430
7,298
122,745
194,550
19,039
6,635
49,225
3,199
17,264
87
13,412
19,645
78,830
2,820
978
15,795
321,754
750
2,295
12,346
19,200
560
265
75
29,445
1,119
575
2,918
33,530
16,992
41,514
2,810.
15
218
5
0
148
355
0
33
46,617
1,620
0
158
3,063
71,313
Ca
0
0
0
0
0
0
0
0
0
0
34,982
0
162
0
0
1,471
0
0
0
0
26,716
0
0
0
18,565
0
0
0
125
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
86
Mg
0
0
0
0
0
0
0
0
0
0
957
0
171
0
0
48
0
0
0
0
3,949
0
0
0
5,438
0
0
0
134
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ha
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
. 0
0
0
0
394
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
984
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0-
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
187
0
433
1
511
2,608
562
743
278
17
393
410
32
9
2,057
5
1,343
67
1,769
7
916
45
45
0
54
0
0
0
1
0
0
858
37
0
0
158
1,958
5,696
57,459
2,081
14,182
97,232
31,343
6,215
74,000
5,270
1.287
45,366
1,749
214
2,537
19.044
32.563
10,445
THC
295
0
683
1
807
2,614
1,277
1,549
278
41
441
465
86
26
2,101
15
3,836
191
4,825
10
935
71
128
1
155
0
0
0
2
0
0
2,452
105
0
0
158
5,595
10,347
89, 771
3,251
16.617
101,939
38,524
6,215
84,464
10,542
1,287
54,728
2,733
486
2,537
27,355
49,640
10,598
-------
1980 kAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
>
10
6-DIGIT SCC | S02
207002
507003
307004
307005
307007
307008
307011
307013
307020
307030
307888
307999
300001
308006
308007
309001
309002
309010
309011
309020
309030
309060
309888
309999
310001
310002
312999
320999
330001
330002
330003
330004
390001
390002
390004
390005
390006
390007
390008
390009
390010
390012
390013
399999
401001
401002
401003
401888
401913
402001
402002
402003
402004
402005
27,594
9
0
0
337
2,788
5
0
2
6
0
834
0
0
0
0
0
0
0
0
0
0
0
127
942
975
0
0
39
0
1
0
819
65,22*
42,565
3,655
34,611
12,159
5,081
0
0
56
0
26,501
0
297
0
0
0
2
0
0
0
0
S04
4.939
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
0
0
0
0
0
0
0
174
58
8
99
0
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NO
1,591
0
47
0
4,137
3,161
0
0
0
41
0
589
0
105
0
0
0
0
0
3
0
0
0
336
0
2,503
6
0
16
0
1
0
1,785
2,431
5,942
3,156
24,323
2.050
958
295
9
0
0
12,583
0
2
1
0
0
274
0
0
7
256
N02
84
0
2
0
218
166
0
0
0
2
0
31
0
6
0
0
0
0
0
0
0
0
0
18
0
132
0
0
1
0
0
0
55
75
125
64
1,280
108
50
16
0
0
0
662
0
0
0
0
0
14
0
0
0
13
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
250
0
0
0
1.334
692
0
0
0
134
0
8,674
0
31
0
0
0
0
0
1
0
0
0
3
0
1,445
2
0
3
0
1
0
109
26,743
912
1,619
47,409
20,158
30,990
0
1
0
0
70,002
0
3
0
0
0
76
0
0
1
166
METRIC
HCl HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TONS/TEAR- --
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
2,510
81
1,127
1
41,480
11,994
0
0
12,039
2,485
765
4,756
165
230
112
84
694
70
0
55
2,421
122
81,898
1,834
653
455
218
4
1,110
89
77
13
388
7,774
2,773
3,857
10,368
2,282
386
1,462
767
9
0
44,356
0
186
0
0
0
992
0
93
413
441
Ca
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
126
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
M9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7
133
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Na
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
64
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2
34
0
0
0
0
0
29
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
215
160
1,957
221
5,950
1,745
7,700
142
4,154
171
648
1,467
10,046
937
6,181
423
0
1,807
44
4,037
684
0
63
2,901
11,920
730
0
380
20,300
3,417
74
85
5
602
1,559
780
10,216
212
42
118
686
0
0
82,052
6,925
91,100
836
369
60
222,751
1,828
30,852
127,670
111,179
THC
215
160
1,957
221
5,950
1,745
7,700
142
4,154
171
648
1,467
10,046
937
6,181
669
0
2,502
61
6,378
948
0
87
2,901
11,920
782
0
380
20,300
3,417
74
85
5
615
1.752
780
23,127
367
42
118
1,558
0
0
186,464
6,925
91,100
836
369
60
222,751
1,828
30,852
127,670
111,179
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
^1
OJ
6-DIGIT SCC
402006
402007
402008
402009
402010
402011
402013
402014
402016
402017
402018
402019
402020
402021
402022
402023
402024
402025
402888
402901
402999
403001
403002
403003
403010
403011
403012
403888
403999
404001
404002
405001
405002
405003
405004
405005
405006
405888
406001
406002
406003
406004
406888
490001
490999
501001
501002
501005
501900
501999
502001
503002
502003
• 502005
S02
0
2
175
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
0
0
386
0
0
0
3,946
0
0
202
0
0
0
0
0
0
0
0
3
0
0
0
0
0
0
0
4,828
255
346
1,033
5
1,906
0
0
1,706
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8
0
0
0
0
4
0
0
11
HO
6
15
147
533
43
0
0
0
0
427
2
0
0
0
0
0
b
0
0
0
590
3
0
0
86
838
0
0
0
69
0
9
9
250
5
26
0
0
0
0
0
0
0
0
3
4,303
1,347
1,235
0
0
1,533
12
(•
9,091
N02
0
2
16
28
2
0
0
0
0
22
0
0
0
0
0
0
0
0
0
0
31
0
0
0
5
44
0
0
0
4
0
0
0
13
0
1
0
0
0
0
0
0
0
0
0
759
238 •
218
0
0
271
2
0
1,605
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
130
0
2
0
0
72
0
0
21
CO
1
1,858
522
38
12
0
0
0
0
75
0
0
0
0
0
0
0
0
0
0
505
1
0
0
60,679
30,340
0
0
80
0
0
13
0
34
0
15
0
0
91,019
0
0
0
0
0
0
52,619
23,531
1,804
18
31
13,200
523
0
0
HtlKll
HCI HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4,860
0
24
0
0
1.909
0
0
0
lUNb/TtAK
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TSP
1,024
63
1,364
742
10
0
0
0
3
0
0
0
0
0
0
44
2
0
0
0
7,914
1,560
122
0
324
1,007
0
0
326
2,705
0
48
0
41
0
384
0
0
1,576
2
29
15
0
0
404
11,377
4,450
5,414
260
27
1,667
64
0
1,745
Ca
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
65
23
1
0
0
9
0
0
0
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
16
6
0
0
0
2
0
0
0
Na
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
. 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
65
23
1
0
0
9
0
0
0
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
55
20
0
0
0
8
1
0
0
voc
71,317
20,478
19,384
200,625
3,500
1,749
14.985
93
837
28,821
285
306
431
127
4,590
222
16
1,501
26,391
58
80,558
146,533
60,472
' 3,482
37.626
31,518
21.256
4.198
27,011
103,358
2.000
22.055
3,324
13,920
24,978
60,450
381
509
82,286
19,730
5,215
8,043
2,855
1,920
86,421
1,189
11,442
66
0
5
1,114
31
0
347
THC
71,317
20,478
55,748
200,625
3,500
1,749
14,985
93
837
29,064
285
306
471
127
4,590
222
16
1,501
26,391
58
80,558
155.033
61,082
3.509
38.351
31,738
21,256
4,296
27.011
103,358
2,000
91.935
13,750
13,920
24,978
60,450
381
957
82,970
20,516
5,215
8,043
2,855
2,633
118,510
6,062
11,442
368
2
5
2,400
161
0
2.052
-------
1980 NAPAP 5.2 EMISSIONS INVENTORT - ANNUAL U.S. EMISSIONS. POINT SOURCES
6-DIGIT SCC
SOZ
S04
NO
N02
Pb
CO
HCI
-METRIC TONS/TEAI-
NF NHJ
C«
502900
503001
503002
503005
503007
501900
1PD3BB
>
485
15.947
57
794
0
i.aaa
U2
0
4
0
2
u
0
0
9
6.051
5H
2,074
0
622
0
0
1,068
91
366
0
110
0
0
84
0
4
0
0
0
1
198,278
20,332
118
0
2,080
0
0
2,804
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
113
17.476
1,601
14,613
86
534
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
75
4,989
3,849
73
0
165
17
170
25,435
6.685
432
0
839
89
U.S. TOTAL | 22,230.755 658.038 8,423,019 325,222 6,901 8,281,040 471,429 102,680 222,688 1,959,255 101,247 29,053 11,771 14,038 1,595,476 4,224,879
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
6-OIG1T SCC | Methane
101002
101003
101004
101005
101006
102001
102003
102003
102004
102005
102006
102007
102008
102009
102010
102011
102012
102013
103001
103002
103003
1030M
103005
103006
103009
103012
103013
103900
105001
105002
199999
201001
201002
202001
202002
202003
202004
203001
203002
204001
204004
299999
101001
301003
30100S
301006
301007
301008
301009
301010
301011
301012
301013
301014
0
0
88.645
0
98.0S2
482
0
0
351,502
0
921,908
84,333
0
0
689
0
0
0
0
0
0
9,463
0
84,487
0
0
0
0
98,396
0
0
15,204
307,687
11.623
3,570,313
2,099
111
144
3,126
23,404
2,834
7
0
0
0
0
234
0
0
0
3,030
0
0
0
Ethane
16,754
1,311
0
0
0
2
4,187
86
0
0
0
66,268
192
40,506
0
0
14
0
2
616
19
0
0
0
601
0
0
0
0
0
0
1,956
5,093
1,495
241,777
270
17
19
220
1,645
364
1
0
0
0
0
47
0
0
0
0
0
0
0
Propane
9,574
749
0
11
2,556
14
2,393
49
0
3,926
24.031
40.512
110
23,146
18
0
8
16
1
352
11
0
215
2.202
343
0
1
0
3,080
53
0
0
3.472
0
164.815
0
0
0
150
1.121
0
0
14.214
0
0
0
0
0
0
0
79
>)
Butane
4,069
318
31,142
85
4,354
22
1,017
21
123,487
30,537
40,933
37,490
47
9,837
31
0
3
123
0
150
5
3,325
1,671
3,751
146
0
11
0
8,376
416
0
0
260
0
12,343
0
0
0
11
84
0
0
33,823
0
0
0
0
0
0
0
135
0
0
0
1
Iso- Butane
0
0
0
29
0
0
0
0
0
10,324
0
7.177
0
0
0
0
0
41
0
0
0
0
565
0
0
0
4
0
1,355
141
0
0
260
0
12,343
0
0
0
11
84
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HUUMNU HU
Pentane
0
0
0
26
2,331
11
0
0
0
9,452
21,919
0
0
0
16
0
0
38
0
0
0
0
517
2,009
0
0
3
0
3,580
129
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
72
0
0
0
LtS/lfcAK
Iso-Pcntane
4,069
318
0
0
0
0
1,017
21
0
0
0
0
47
9,837
0
0
3
0
0
ISO
5
0
0
0
146
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Atkanes
44,995
3,522
7,495
135
4,157
26
11.246
230
29.719
48,277
39,084
238
515
108,788
29
42,762
38
194
5
1,654
51
600
2,642
3,582
1,613
0
18
0
10.506
658
12.977
9,127
0
6,977
0
1,260
79
87
0
0
1,701
4
54,339
161,350
1,018.211
484,949
3,751
3,904
3,070
7,533
128
0
7.640
6.972
Ethylene
0
0
0
0
0
0
0
0
0
0
0
3,197
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
21,513
551
16,445
26,138
2,970
186
204
24
178
4,009
9
19,025
2.384
1.263.935
660,904
3.486
0
4,184
0
0
0
10,413
0
Propylene
0
0
0
0
0
0
0
0
0
0
0
39.338
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8,643
0
6,607
0
1,193
75
82
0
0
1,611
4
5,287
662
351,275
183,680
1.054
0
1,163
0
0
0
2,894
0
Iso-Butene
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Alkencs
32,789
2,567
0
0
0
4
8.195
168
0
0
0
0
375
79,276
0
0
27
0
4
1,206
37
0
0
0
1,176
0
0
0
0
0
0
7,739
0
5,916
0
1,068
67
73
0
0
1,442
3
7,511
941
499,008
260,928
1,460
0
1,652
0
0
0
4,111
0
-------
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A-76
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
I
-J
-J
6-OIGIT SCC | Methane
302003
302004
302005
302006
302007
302008
302009
302010
302012
302013
3020 H
302015
302016
302017
302016
302019
302020
302026
302030
302031
302032
302033
302888
302999
303000
303001
303002
303003
303004
303005
303006
303007
303008
303009
303010
303011
303012
303013
303014
303023
303030
303888
303999
3M001
304002
304003
304004
304005
304006
304007
304008
304009
304010
304020
0
0
0
0
355.417
0
99.927
0
17,570
0
0
0
0
0
12,393
531,844
0
0
0
0
2,981
0
8.314
252,771
0
847.949
0
1,789,843
2.203
179
197
0
731,590
9,438
0
0
0
0
0
0
154
0
6,260
119,749
5,819
136,346
107,958
0
0
7,756
127
0
0
0
Ethane
0
0
0
0
0
0
0
0
0
545
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
79,871
0
168,590
208
0
0
0
16.053
445
0
0
0
0
0
0
14
0
326
0
0
7,093
0
0
0
403
0
0
0
0
Propane
0
0
0
0
247
0
69
0
12
311
0
0
0
0
9
370
0
0
0
0
2
0
6
176
0
3,303
0
6.972
9
0
0
0
10
1,182
0
0
0
0
0
0
1*
0
24
2,512
122
527
2,265
0
0
30
3
0
0
0
Butane
0
0
0
0
247
0
69
0
12
132
0
0
0
0
9
370
0
0
0
0
2
0
6
176
0
0
0
0
0
0
0
0
1
3
0
0
0
0
0
0
0
0
2
6,856
333
41
6,181
0
0
2
7
0
0
0
THOUSAND tWlES/YEAB
Iso-Butane Pentane Iso-Pentane
0
0
0
0
123
0
35
0
6
0
0
0
0
0
4
185
0
0
0
0
1
0
3
88
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,099
53
0
991
0
0
0
1
0
0
0
0
0
0
0
18S
0
52
0
9
0
0
0
0
0
6
277
0
0
0
0
2
0
4
132
0
0
0
0
0
0
0
0
1
3
0
0
0
0
0
0
0
0
2
2,983
145
41
2,690
0
0
2
3
0
0
0
0
0
0
0
0
0
0
0
0
132
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0-
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Alkanes
945
0
0
0
7.011
21
5,724
473,357
113
1,463
0
0
138
0
80
3,418
0
0
0
0
19
20,184
85
1,625
0
13,812
95
29,155
36
164
180
0
91,835
37,057
0
770
0
0
4,505
0
3
0
190
16,120
783
4,134
14,533
0
0
235
17
0
0
851
Ethylene
0
0
0
0
3,025
0
851
0
150
0
0
0
0
0
105
4,527
0
0
0
0
25
0
71
2,151
0
296,662
0
626,192
771
0
0
0
33,915
1,632
0
0
0
0
0
0
54
0
1,195
0
0
26,021
0
0
0
1,480
0
0
0
1,159
Propylene Iso-
0
0
0
0
617
0
174
0
31
0
0
0
0
0
22
924
0
0
0
0
5
0
14
439
0
13,512
0
28,521
35
0
0
0
11,337
109
0
0
0
0
0
0
2
0
80
0
0
1,743
0
0
0
99
0
0
0
322
lutene
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Alkenes
0
0
0
0
1,543
0
434
0
76
1,066
0
0
0
0
54
2,310
0
0
0
0
13
0
36
1,098
0
3,303
0
6,972
9
0
0
0
13
43
0
0
0
0
0
0
1
0
32
0
0
689
0
0
0
39
0
0
0
458
-------
1980 NAPAP 5.2 EMISSIONS INVENTOR* • ANNUAL U.S. EHiSSIONS OF HYDROCARBON SPECIES. POINT SOURCES
~J
00
6-DIGIT SCC | Methane
304022
304034
304050
304888
304999
305 001
305002
305003
305004
305005
305006
305007
305008
305009
305010
305011
305012
305013
305014
305015
305016
305017
305018
305019
305020
305021
305022
305024
305025
305026
305031
305032
305040
305100
305103
305888
305999
306001
306002
306003
306004
306005
306006
306007
306008
306009
306010
306011
306012
306014
306100
306888
306999
307001
6.755
0
15,636
0
18,470
0
44,585
49,586
0
1,459
2,993
3,395
3,286
1,005
0
574
151,073
7,534
186,039
179
0
1,619
5.023
34
6,099
0
0
0
36
0
0
96,542
4,124
0
0
0
220,313
289,960
2,014.467
72,956
7,972
184,509
424.946
0
493.389
131,456
0
30,648
61,323
16,973
0
430.702
885,084
9,571
Ethane
0
0
0
0
0
190
0
375
0
5
0
4
51
16
1,471
9
2,340
117
2,401
7
655
0
78
0
94
0
0
0
1
0
0
1,495
63
0
0
0
3,413
0
0
0
76,726
58,105
12,144
0
84,802
105,207
0
294,983
0
0
0
46,621
95,806
0
Propane
142
0
328
0
387
1,694
1,162
1,098
0
34
0
4
48
15
840
8
2,225
111
3,092
5
374
34
74
1
90
0
0
0
1
0
0
1,422
61
0
0
0
3,245
7,104
0
0
86,263
136,598
28,549
0
267,529
71.790
0
331,650
0
44 1
}
63, Kf
129, V \
2- '
Butane
387
0
895
0
1,057
1,780
1,980
2,004
0
57
1,052
1,109
73
20
357
12
3,031
151
4,487
5
159
93
101
2
122
0
0
0
1
0
0
1,937
84
0
0
0
4.420
18,222
0
0
55,374
250,769
52,412
0
204,879
0
0
212,891
0
754
0
76,091
156,367
425
!so-Butane
62
0
144
0
170
792
0
537
0
6
0
5
61
19
0
11
2,839
142
2,913
3
0
15
94
0
115
0
0
0
1
0
0
1,814
77
0
0
0
4,140
0
0
0
50,676
78,493
16,405
0
70,901
0
0
194,831
0
0
0
30,678
63,043
0
THOUSAND HOLES/TEAR
Pentane Iso-Pentane
168
0
390
0
460
1,430
1,060
968
0
30
0
2
32
10
0
6
1,458
73
2,233
2
0
40
48
1
59
0
0
0
0
0
0
932
40
0
0
0
2,126
6,480
0
0
427
169,218
35,367
0
111,250
0
0
1.642
0
404
0
25,847
53,115
228
0
0
0
0
0
0
0
7
0
0
0
0
0
0
357
0
0
0
0
1
159
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Alkanes
909
0
2,105
11
2.486
20,507
1,890
2,545
3,229
59
306
275
115
35
3,950
20
5,256
262
6,708
16
1,758
218
175
1
212
0
0
0
12
0
0
3,359
144
0
0
1,836
7,665
13,027
135,555
4,909
27,408
650,367
161,930
86,143
386,277
0
14,971
53,633
4,126
720
29,500
91,761
113,180
120,473
Ethylene
0
0
0
0
0
408
0
313
0
5
0
4
46
14
0
a
2,110
105
2,165
3
0
0
70
0
85
0
0
0
1
0
0
1,348
57
0
0
0
3,077
0
0
0
18,341
0
0
0
0
0
0
0
0
0
0
662
0
0
Propylene Iso-
0
0
0
0
0
0
0
194
0
3
0
2
28
9
0
5
1,304
65
1,338
2
0
0
43
0
53
0
0
0
0
0
0
834
35
0
0
0
1,902
0
0
0
5,097
0
0
0
27,257
0
0
0
0
0
0
667
993
0
Butene
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 .
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Alkenes
0
0
0
0
0
0
0
270
0
3
0
2
32
10
2,878
6
1,458
73
1,496
9
1,281
0
48
0
59
0
0
0
0
0
0
932
39
0
0
0
2,126
0
0
0
7,241
0
0
0
1,952
0
0
0
0
0
0
262
0
0
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY • ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
6-OIGIT SCC | Methane
307002
soroos
30700*
307005
307007
307008
307011
307013
307020
307030
307888
307999
3 0800 1
308006
308007
309001
309002
309010
309011
309020
309030
309060
309888
309999
310001
310002
312999
320999
330001
330002
330003
330004
390001
390002
390004
390005
390006
390007
390008
390009
390010
390012
390013
399999
401001
401002
401003
401888
401913
402001
402002
402003
402004
402005
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
15,307
0
43,315
1.057
145,935
16,408
0
1,507
0
0
870
0
0
0
0
0
0
0
0
11,985
0
804,971
9,300
0
0
54,397
0
0
6,509,452
0
0
0
0
0
0
0
0
0
0
Ethane
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
25
1
0
9
0
1
0
0
1,276
0
0
0
0
0
0
4
431
0
0
0
171
0
0
0
0
0
0
0
0
0
a
0
0
0
0
0
0
Propane
0
0
0
0
0
Q
0
0
0
0
0
0
0
0
0
321
0
751
18
3,062
284
0
26
0
0
788
0
0
0
0
0
0
2
246
0
211
20,983
0
0
0
1,418
0
0
169,682
0
0
0
0
0
0
0
0
0
•>
Butane
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
876
0
1.101
27
8,356
417
0
38
0
0
729
0
0
0
0
0
0
1
105
4,210
1,638
35,741
0
0
0
2,415
0
0
289,019
0
0
0
0
0
0
0
0
0
0
Iso-Butane
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
140
0
100
2
1,339
38
0
3
0
0
140
0
0
0
0
0
0
0
0
0
554
0
0
0
0
0
0
0
0
0
0
0
0
27
0
0
0
0
0
THOUSAND MOIES/YEAR
Pentane I so- Pentane
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
381
0
851
21
3,636
322
0
30
0
0
0
0
0
0
0
0
0
0
0
0
507
19,139
0
0
0
1,293
0
0
154,765
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
105
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
M. twines Ethylene
2,501
1,857
22,758
2,574
69.202
20,289
52,439
1,656
48,312
1,994
7,533
17,061
101,220
9,756
71,882
2,061
0
5,930
145
19,645
2,246
0
206
25,009
138,626
3,382
0
3,277
174,990
23,266
641
992
10
1,156
1,066
2,589
34,928
21
485
1,372
2,306
0
0
275,966
24.026
444,264
8,652
3,181
499
0
18,446
14,809
633,899
776,024
0
0
0
0
0
0
0
0
0
0
0
0
3.096
0
0
0
0
0
0
0
0
0
0
0
0
4,609
0
0
0
0
0
0
0
0
0
0
0
365
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Propylene Iso-
0
0
0
0
0
0
0
0
0
0
0
0
861
0
0
a
0
2,352
57
0
891
0
82
0
0
2,045
0
0
0
0
0
0
0
0
0
0
0
478
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
iutene Alkenes
0 0
0 0
0 0
0 0
0 0
0 0
0 4,620
0 0
0 0
0 0
0 0
0 0
0 1,222
0 0
0 0
0 0
0. 0
0 2,077
0 51
0 0
0 787
0 0
0 72
0 0
0 0
0 1.820
0 0
0 0
0 0
0 2,050
0 0
0 0
0 7
0 843
0 0
0 0
0 0
0 416
0 0
0 0
0 0
0 0
0 0
0 0
0 21,745
0 182,616
0 697
0 0
0 181
0 0
0 0
0 0
0 0
0 0
-------
1980 kAPAP S.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
OO
O
6-DIGIT SCC
402006
402007
402008
402009
402010
40201 1
402013
402014
402016
402017
402018
402019
402020
402021
402022
402023
402024
402025
402888
402901
402999
403001
403002
403003
403010
403011
403012
403888
403999
404001
404002
405001
405002
405003
405004
405005
405006
405888
406001
406002
406003
406004
406888
490001
490999
501001
501002
501005
501900
501999
502001
503002
502003
502005
Methane
0
0
2,110,984
0
0
0
0
0
0
11,992
0
0
2,327
0
0
0
0
0
0
0
0
369,250
29,086
0
34.555
10,478
0
4,683
0
0
0
3,955,033
590,099
0
0
0
0
23,059
36,371
32,211
0
0
0
37,779
1,700,609
300,610
0
18,397
90
0
78,314
7,963
0
102,851
Ethane
0
0
83,266
0
0
0
0
0
0
1,696
0
0
79
0
0
0
0
0
0
0
0
85,681
4,768
888
5,665
1,718
0
773
0
0
0
214,208
31,960
0
0
0
0
2,602
3.350
8,985
0
0
0
3,554
159,988
1,697
0
257
1
0
1,006
45
0
1,847
Propane
0
0
35,503
0
0
0
0
0
0
383
0
0
36
0
0
0
0
0
0
0
0
268,896
20,447
13,470
23,413
7,500
420
1,246
0
2,067
40
62,516
9,327
0
0
0
0
622
7,617
31,242
104
161
57
869
39,108
1,031
4,920
20
0
a
469
I!
Butane
0
0
202,257
0
0
0
0
0
0
1,011
0
0
199
0
0
0
0
0
0
0
0
299,232
40,042
896
30,887
18,076
7,985
3,695
0
39,276
760
47,806
7,133
0
0
0
0
1,387
33,196
40,962
1,982
3,056
1,085
1,685
75,846
1,879
3,776
37
1
0
477
50
0
0
1
Iso-Butane
0
0
0
0
0
0
0
0
0
158
0
0
0
0
0
0
0
0
0
0
0
96,006
13.468
232
12,049
5,716
1,891
1,504
0
9.302
180
15,629
2,332
0
0
0
0
230
9,065
8,531
469
724
257
316
14,221
364
3,776
7
0
0
314
10
0
0
HUUMHU HU
Pentane
0
0
503
0
0
0
0
0
0
0
0
0
44
0
0
0
0
0
0
0
0
227,088
101.146
3,986
45.965
52,617
35,513
2.105
0
174,674
3,381
0
0
0
0
0
0
0
124.717
34,435
8,813
13,593
4.825
0
0
0
2,975
0
0
0
216
0
0
0
Ifcb/TtAK
[so-Pentane
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Alkanes
507,062
0
26,544
1,420,862
0
11,911
101,923
1,087
6,179
191,840
2.025
2.546
2,713
865
53,387
1,514
153
10,225
179,719
395
730,657
603,329
243,284
9,506
171,062
127,376
86,150
25,306
163,416
416,530
8,062
0
294
222,941
290,493
485,486
0
565
348,213
78,243
21,015
32,414
11,505
17,007
765,570
8,365
56,522
165
3
63
5,009
222
0
0
Ethylene
0
0
35,614
0
0
0
0
0
0
0
0
0
32
0
0
0
0
0
0
0
0
0
0
0
0
1
0
43
0
0
0
425,658
63,509
0
0
0
0
431
5
0
0
0
0
2,185
98,363
3,880
79,176
847
1
0
9.005
103
0
6,361
Propylene Iso-
0
0
3,185
0
0
0
0
0
0
0
0
0
28
0
0
0
0
0
0
0
0
0
0
790
0
0
0
0
0
0
0
65,274
9,739
0
0
0
0
3,244
0
0
0
0
0
342
15,406
3,758
0
104
1
0
516
100
0
246
lutene
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 .
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Alkenes
0
0
2.794
65,089
0
1,049
8,953
0
41
16.679
0
0
24
76
0
133
0
901
15.834
35
0
29,858
23,848
1,014
9,453
12,751
9,036
1,633
0
44,444
860
16,548
2,469
0
0
921
0
1,665
31,174
4,573
2.242
3,459
1,228
79
3,555
121
50.572
2
0
0
3,686
3
0
0
-------
>
00
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
6-OIGIT SCC
502900
503001
503002
503005
503007
503900
599999
Methane
5,922
1,261,330
174,959
21,643
0
41,614
4,409
U.S. TOTAL | 35,336,921
Ethane
0
7,122
988
389
0
235
25
2,081,710
Propane
154
4,324
1,957
0
0
143
15
2,192,169
Butane Iso-Butane
263
7,885
2,136
0
0
260
28
2,639,566
0
1,526
1,254
0
0
SO
5
756,840
Pentane Iso-Pentane
141
0
821
0
0
0
0
1,482,177
0
0
0
0
0
0
0
16,375
Alkanes
251
35,101
20,465
0
0
1,158
123
19,086,558
Ethylene
0
16,279
24,105
1,339
0
537
57
5,497,167
Propylene Iso-Butene
0
15,770
2,187
52
0
520
55
1,971,765
0
0
0
0
0
0
0
0
Alkenes
0
509
14,025
0
0
17
2
2,733,450
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
>
00
6-OIGIT SCC | Benzene
101002
101003
101004
101005
101006
102001
102002
102003
102004
102005
102006
102007
102008
102009
102010
102011
102012
102013
103001
103002
103003
103004
103005
103006
103009
103012
103013
103900
105001
105002
199999
201001
201002
202001
202002
202003
202004
203001
203002
204001
204004
ZTTTTT
301001
301003
301005
301006
301007
301008
301009
301010
301011
301012
301013
301014
0
0
0
0
1.461
7
0
0
0
0
13.732
184
0
0
10
0
0
0
0
0
0
0
0
1,258
0
0
0
0
1,466
0
0
2,124
0
1,624
0
293
18
20
0
0
396
1
3,163
396
210,109
109,865
594
0
695
0
45
0
1,731
0
Toluene
U.600
1,143
0
0
618
5
3,649
75
0
0
5,810
0
167
35,298
4
0
12
0
2
537
17
0
0
532
524
0
0
0
620
0
0
0
0
0
0
0
0
0
0
0
0
0
1,087
136
72,225
37,766
236
0
239
0
19
0
595
0
Xylene
107,941
8,449
0
0
0
12
26.979
552
0
0
0
0
1,236
260,975
0
0
90
0
12
3.969
123
0
0
0
3,871
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
296
37
19.698
10,300
68
0
65
0
0
0
162
0
Eth Benz Arc
25,370
1,986
0
0
0
3
6,341
130
0
0
0
0
290
61,338
0
0
21
0
3
933
29
0
0
0
910
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.0
0
0
0
0
0
0
0
0
0
0
JU»ANV nu
IMtiCS F
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,334
167
88,640
46,349
244
0
293
0
0
0
730
0
.C3/TCAK
9n>aldeh
0
0
180,650
660
7,499
37
0
0
716.326
235,858
70,510
23,892
0
0
53
0
0
947
0
0
0
19,285
12,907
6.462
0
0
86
0
38,474
3,212
0
0
54,365
0
54,502
0
0
0
22
168
0
0
1,408
176
93,564
48.924
258
0
310
0
232
0
771
0
Acetaldeh
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
395
50
26,264
13,733
74
0
87
0
0
0
216
0
Aldeh
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
272
34
18.056
9,441
50
0
60
0
0
0
149
0
Acetone
0
0
62.284
0
0
0
0
0
246.974
0
0
0
0
0
0
0
0
0
0
0
0
6,649
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,091
0
0
0
0
0
0
96.732
Ketones
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
53
0
0
0
0
0
0
10S.061
Org Acid
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
148
19
9,849
5,150
49
0
33
0
0
0
81
0
-------
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A-83
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
>
00
6-OIGIT SCC | Benzene
502002
302004
302005
302006
302007
302008
302009
302010
302012
302013
3020U
302015
302016
302017
302018
302019
302020
302026
302030
302031
302032
302033
302888
302999
303000
303001
303002
303003
503004
305005
303006
303007
303008
303009
303010
303011
303012
303013
3030U
303023
303030
303888
303999
304001
30*002
304003
304004
304009
304006
304007
304008
304009
304010
304020
0
0
0
0
62
0
17
0
3
0
0
0
0
0
2
92
0
0
0
0
1
0
1
44
0
54.048
0
114,083
140
0
0
0
124
1,848
0
0
0
0
0
0
10
0
309
1,204
58
6,728
1,085
0
0
383
1
0
0
193
Toluene
0
0
0
0
0
0
0
0
0
475
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2,402
0
5,070
6
0
0
0
4
1.807
0
0
0
0
0
0
0
0
11
523
25
243
472
0
0
14
1
0
0
66
Xylene Eth
0
0
0
0
0
0
0
0
0
3,510
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Cl
1 .
Bent
0
0
0
0
0
0
0
0
0
825
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
imjuMMu r
Aroma tics
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
81
ULfc*/TtAK
Formal**
0
0
0
0
247
0
69
0
12
0
0
0
0
0
9
370
0
0
0
0
2
0
6
176
0
0
0
0
0
0
0
0
1
5
0
0
0
0
0
0
0
0
4
31.298
1,521
81
28,216
0
0
5
33
0
0
86
Acetaldeh
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
24
Atdeh
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
17
Acetone
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ketones Org
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Acid
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9
-------
WBO HAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS Of HYDROCARBON SPECIES, POUT SOURCES
00
6 DIGIT SCC
304022
304034
304050
304888
304999
305001
305002
305003
305004
305005
305006
305007
305008
305009
305010
30501)
305012
305013
305014
305015
305016
305017
305018
305019
305020
305021
305022
305024
305025
305026
305031
305032
305040
305100
305103
305888
305999
306001
306002
306003
306004
306005
306006
306007
306008
306009
306010
306011
306012
306014
306100
306888
306999
307001
Benzene
68
0
157
0
186
0
664
667
0
21
0
3
38
12
0
7
1,765
88
2,273
2
0
16
59
1
71
0
0
0
0
0
0
1,128
48
0
0
0
2,573
4,060
0
0
3,618
31,601
6,605
0
13,820
0
0
2,189
0
253
0
352
496
143
Totucne
30
0
68
0
81
0
281
201
0
7
0
0
1
0
1,282
0
38
2
235
3
571
7
1
0
2
0
0
0
0
0
0
25
1
0
0
0
56
1,717
0
0
2,329
0
0
0
3,783
0
0
4.925
0
107
0
1,246
2,482
60
Xytene
0
0
0
0
0
0
0
176
0
0
0
0
0
0
9,476
0
0
0
0
25
4,218
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,425
0
0
0
1,405
0
0
4,378
0
0
0
494
99J
0
Eth Ben:
0
0
0
0
0
0
0
41
0
0
0
0
0
0
2,227
0
0
0
0
6
991
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
I nuuannu nuL
Aromatics Fo
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 1,
0
1,286
0
0
0
0
0
0
0
0
0
0
46
0
0
C9/ICAK
rmaldetr Acet
1,766
0
4,087
0
4,827
1.693
3,410
4,796
0
88
6,100
6,407
55
4
0
2
537
27
2.924
1
0
423
IB
3
22
0
0
0
0
0
0
343
17
0
0
0
783
56,353
524.316
5S.204
1,358
0
292,370
0
23,830
70,208
0
0
46,402
1,298
0
49
0
732
sldeh
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
381
0
0
0
0
0
0
0
0
0
0
14
0
0
Aldeh
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
262
0
0
0
0
0
0
0
0
0
0
9
0
0
Acetone
0
0
0
0
0
0
0
0
0
0
2,103
2,209
15
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
12,243
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ketones Org
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Acid
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
a
0
0
0
0
0
0
0
0
0
0
0
0
0
c
0
0
0
143
0
0
0
0
0
0
0
0
0
0
5
0
0
-------
1980 NAPAP 5.2 EMISSIONS INVENTOR* - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
00
6-DIGIT SCC
507002
307003
307004
307005
307007
307008
JO 7011
307013
307020
307030
307888
307999
308001
308006
308007
309001
309002
309010
309011
309020
309030
309060
309888
309999
310001
310002
312999
320999
330001
330002
330003
330004
390001
390002
390004
390005
390006
390007
390008
390009
390010
390012
390013
399999
401001
401002
401003
401888
401913
402001
402002
402003
402004
402005
Benzene
0
0
0
0
0
0
0
0
0
0
0
0
1,733
337
0
154
0
250
6
1,467
95
0
9
0
0
766
0
0
0
0
0
0
0
0
0
0
11,990
2,006
0
0
810
0
0
96,961
0
0
0
0
0
0
0
0
0
0
Toluene
0
0
0
0
0
0
3,311
0
0
0
0
0
228
37
0
67
0
125
3
638
47
0
4
0
0
263
0
0
0
1,469
0
0
3
375
0
0
5,073
0
0
0
343
0
0
41,022
0
83,066
0
0
0
1,332,047
1,024
0
140,086
38,912
Xylene
0
0
0
0
0
0
2,926
0
0
0
0
0
48
0
0
0
0
0
0
0
0
0
0
0
0
72
0
0
0
1,298
0
0
25
2,774
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
467,776
439
0
82.8Ck,
42,24!
Eth Benz
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
652
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
750
0
0
0
THOUSAND 1
Aromatics
0
0
0
0
0
0
0
0
0
0
0
0
217
0
0
0
0
0
0
0
0
0
0
0
0
323
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
IDLES/TEAR
forma tdeh
0
0
0
0
0
0
0
0
0
0
0
0
229
0
0
4,001
0
7,807
190
38,142
2,957
0
272
0
0
806
0
0
0
0
0
0
0
0
24,423
12,649
61,566
0
0
0
4,160
0
0
497,858
0
0
0
0
6
0
0
0
0
0
Acetaldeh
0
0
0
0
0
0
0
0
0
0
0
0
64
0
0
0
0
0
0
0
0
0
0
0
0
96
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Aldeh
0
0
0
0
0
0
0
0
0
0
0
0
44
0
0
0
0
0
0
0
0
0
0
0
0
66
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
128
0
0
0
Acetone
0
0
0
0
0
0
13,245
0
0
0
0
0
0
0
0
0
0
5,680
139
0
2,152
0
198
9,980
0
0
0
1,308
69,833
5,876
256
0
0
0
8,421
0
0
0
0
0
0
0
0
0
0
0
0
0
7
467.776
1,005
205,475
281,037
120,073
Ketones
0
0
0
0
0
0
14,554
0
0
0
0
0
0
0
0
0
0
5,805
142
0
2,199
0
202
11,112
0
0
0
1,456
77,751
6,457
285
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
320,760
1,664
229,539
420,357
134,526
Org Acid
0
0
0
0
0
0
0
0
0
0
0
0
24
0
0
0
0
0
0
0
0
0
0
0
0
36
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
0
402
0
5,847
31,130
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, POUT SOURCES
00
-J
6-DIGIT SCC | Benzene
4020%
402007
402008
402009
402010
402011
402013
402014
402016
40201 7
402018
402019
402020
402021
402022
402023
402024
402025
402888
402901
402999
403001
403002
403003
403010
40301 1
403012
403888
403999
404001
404002
405001
405002
405003
405004
405005
405006
405888
406001
406002
406003
406004
406888
490001
490999
501001
501002
501005
501900
501999
502001
502002
502003
502005
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
40,586
19,149
7,095
8,766
9.768
6,514
902
0
32,041
620
0
0
0
0
0
0
0
22,959
4,765
1,617
2,493
885
0
0
1,152
0
269
0
0
1.030
31
0
2.032
Toluene
29,953
120,002
1,285
119,663
0
752
6,481
0
330
11,953
120
194
123
55
0
96
3
646
11,348
25
66,057
86,498
59,294
2,477
24,028
31,383
22,064
2,836
0
108.525
2,100
0
0
0
0
43,088
0
0
76,357
11,878
5,475
8,445
2,998
1,395
62,810
0
0
0
0
0
0
0
0
0
Xylene
32,806
42,390
0
116,905
0
665
5,670
0
355
10,563
131
0
95
48
0
84
4
571
10,028
22
49,946
88,186
70,435
2,996
27,920
37,512
26,687
0
0
131,264
2,540
0
0
0
0
583
0
0
92,072
13.508
6,623
10,215
3,626
0
0
0
0
0
0
0
0
0
0
0
Eth Benz
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
66,057
0
0
0
0
0
0
0
0
0
0
0
0
0
0
13.753
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
JHUUSAND MOLES/YEAR
Arontatics Formatdeh
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
92.353
73,763
3,137
29,239
39,332
27,948
1,590
0
137,465
2,661
0
0
0
0
12,547
0
0
96,422
14,146
6,935
10,698
3,797
0
0
0
0
0
0
0
0
0
0
0
0
0
6,147
0
0
0
0
0
0
0
0
0
K
0
0
0
0
0
0
0
0
0
0
0
0
3
0
86
0
0
0
0
0
0
0
0
0
2,918
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Acetaldeh
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Aldeh
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Acetone
87,007
45,871
615
325,545
0
3,008
25,665
0
990
52,840
348
0
326
218
0
382
10
2,582
45,392
100
0
0
0
0
0
162
0
5,285
0
0
0
0
0
0
0
7,209
0
0
0
0
0
0
0
158
7,111
7,153
0
141
2
0
7n
189
0
0
Ketones Org Acid
98,417
31,332
0
315,879
0
3,306
28,327
0
1,116
58,155
393
501
397
240
0
420
11
2,838
49,878
110
0
0
0
0
0
167
0
5,456
0
0
0
0
0
0
0
54,041
0
0
0
0
0
0
0
1,158
52.144
0
0
0
0
0
0
0
0
v 0
65,611
0
16,597
18,561
39,725
0
204
0
657
0
262
156
743
0
0
0
8
0
0
0
0
0
0
0
0
a
0
258
0
0
0
0
0
11,231
0
99,511
5,144
0
0
0
0
0
0
2,949
132,730
0
0
0
0
0
0
0
0
0
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
OO
00
6-DIGir SCC |
502900 |
503001 |
503002 |
503005 |
503007 |
503900 |
599999 |
U.S. TOTAL |
Benzene
88
4,833
670
428
0
159
17
1,222,772
Toluene
37
0
0
0
0
0
0
2.884,205
Xylene
0
0
0
0
0
0
0
1,904,454
Eth Benz 1
0
0
0
0
0
0
0
183,111
tromatics
0
0
0
0
0
0
0
807,915
Formaldeh 1
453
0
0
0
0
0
0
4,538,201
kcctaldeh
0
0
0
0
0
0
0
76,133
Aldeh
0
0
0
0
0
0
0
52,123
Acetone
0
30.013
4.163
0
0
990
105
2,607,605
Ketones
0
0
0
0
0
0
0
2,094,680
Org Acid
0
0
0
0
0
0
0
466,463
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
State | S02
Alabama
Arizona
Arkansas
Cal i fornia
Colorado
Connecticut
Delaware
Dist. of Colum.
F t or i da
Georgia
Idaho
Illinois
Indiana
lOUd
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Hampshire
Net* Jersey
Neu Mexico
New York
North Carol ina
North Dakota
Ohio
Oklahoma
Oregon
Pennsylvani a
Rhode Island
South Carol ina
South Dakota
Tennessee
Texas
Utah
Vermont
Virginia
Washington
Uest Virginia
Wisconsin
Wyoming
777,509
824,136
55,654
390,765
117,379
34,524
96,889
7,164
1,018.759
862,393
36.610
1,350,414
1,826,567
307,348
193,588
1,098,360
236, 911
114,789
275,263
297,037
797,627
210,481
251,012
1,270,841
146,533
64,214
140,938
96.421
233,574
250,262
760,082
605,426
95,891
2,615,591
83,987
24,497
1,783,155
7,102
316,336
33,897
1,120,219
1,053,679
88,412
1,543
304,930
268,669
1,110,784
642,486
184,096
Contig. U.S. | 24,504,741
S04
28,739
29,305
8,336
22,801
7,626
2,228
1,965
399
25,261
27,802
6,598
33,150
28,766
9,629
6,128
18.018
14,000
7,242
6,203
5,977
24,456
9,566
7.051
16,895
6.039
3,388
6, IK
2,619
6,520
7.939
23,645
22,669
10,188
42,357
7,332
13,985
43,985
288
14,823
3,252
23,980
47,897
7,179
37
13,159
14,207
25,524
18,129
11,953
725,349
NO
224,151
102,999
41,818
310,207
134,392
21,935
25,220
2,504
307,361
270,803
8,485
450,340
443,844
121,336
203,999
303,448
413,667
20,237
88,288
75,448
323,480
130,327
92,686
278,522
36,399
50.811
45,094
26,166
127,777
150,081
279,527
249,186
70,089
632,950
150,842
43,349
479,812
3,752
121,077
24.565
276,449
1,244,129
55,550
278
119,309
68,722
328,057
176,179
127,965
9,284,610
N02
7,366
3,765
1.707
15,693
5,125
571
750
113
11,013
8,714
335
16,607
15,485
3,972
10,231
9,995
21,573
504
3,058
2,177
12,192
4.499
3.803
9.515
1,601
1,892
1,543
741
4,623
7,112
8,372
7,773
2,258
21,023
7,423
1,545
15,867
119
3,843
775
9,843
64,174
2,060
9
4,003
2,537
10.283
5,844
4,464
358,489
Pb
185
73
1
216
442
78
1
2
23
45
449
1,518
462
71
1
107
49
1
5
162
176
10
0
288
213
30
6
0
0
4
16
21
5
976
4
20
763
4
85
5
143
374
43
0
34
87
415
79
3
7,695
CO
283,116
64,854
135,410
354,357
110,700
11,759
8,526
4,109
145,583
162,451
41,789
312,428
296,070
54,874
61,361
117,028
998.666
44,700
33,723
14.048
271,202
33,932
82,975
80,142
139,579
10,148
13,032
4,914
83,692
26,933
113,978
126,370
55,560
690,969
338,386
30,413
470,810
2.014
79,221
15.218
153,761
2,126,155
33,766
39
386,565
221,531
153,195
45,510
82,566
9,128,108
TONS/YEAR
HCl
19,291
8,862
1,761
0
9,054
386
1,106
589
8.670
20,392
314
33,310
33,163
11,434
6,552
22,400
736
26
6,546
2,155
22,683
8,659
2,587
22,038
1.994
4.577
3,515
1,026
2,442
8,295
9.200
23,513
71
50,337
5,740
544
41,375
14
8,973
220
23,266
18,937
3,547
9
7,047
4,942
29,055
15,215
13,084
519,652
HF
3.518
1,071
1,413
131
1,186
0
184
7
29.030
2,486
173
7,890
4,487
1,701
792
3,768
1,663
3
1,260
84
3,139
1,113
314
2,663
243
577
442
124
302
977
1,875
3,070
47
7.179
763
92
5,504
0
1,596
37
4,243
5,841
495
0
1.318
1,488
4,861
2,310
1,723
113,183
NH3
602
5,009
12,324
4,653
7,795
0
1
0
21,887
19,889
121
39,976
11,695
19,260
96
116
21,860
0
2
0
228
16,428
358
6
185
354
1
0
12
150
3
8,664
200
1,802
1,405
0
8,552
0
1,020
1
10,293
11,535
52
0
4,539
10,076
8
651
3,660
245,467
TSP
81,327
27,451
33,610
135,939
53,026
8,160
16,575
863
100,437
41,780
12,020
197,188
201.252
151,474
43,258
127,561
118,871
18.217
36,069
17,624
143,924
130,576
24,231
311,839
19,205
43,613
28,465
4,000
98,206
34,495
245,892
115,851
48,845
277.919
67,489
33,286
187,784
1,065
142,530
33,423
114,674
388,434
61,873
1.544
109,050
86,100
60,484
98,764
27,984
4,364,247
Ca
1,604
1,175
307
1,777
2,320
28
167
7
6.269
299
87
5,892
5,026
3.038
354
1.734
407
72
442
193
9,496
2,218
125
18,356
129
326
407
15
37
923
1,367
2.247
777
7,714
5,438
1,103
6,383
1
486
2,168
1,002
6,686
2,831
3
2,422
494
946
8.395
116
113,808
Mg
488
334
95
375
445
8
176
7
931
263
23
1,899
2,324
685
103
970
. 58
21
217
142
1,217
624
68
3,228
56
87
91
9
24
409
1,144
943
786
3,538
648
54
2,006
0
337
475
665
2,056
892
3
1,090
319
666
927
103
32,025
Na
356
111
23
48
177
3
84
4
201
201
10
708
1,694
386
42
349
133
75
101
65
482
160
86
685
23
12
21
23
11
178
548
303
371
1,500
34
54
826
1
.78
89
375
329
658
1
402
188
296
324
44
12,975
K
280
57
46
235
119
3
45
2
84
222
37
899
4,565
54
22
183
219
36
79
35
565
79
41
347
. 26
6
12
3
6
105
310
165
199
1,131
29
310
1,400
1
122
9
209
351
1,844
2
223
280
240
213
25
15,474
VOC
52,531
13,246
15,425
296,959
16,536
24,045
25,868
451
48,306
27,300
2,608
153,055
87,406
17,782
40,304
102,788
295,753
17,888
59,894
94,2/0
195,994
65,852
52,561
170,834
12,081
45,451
3,398
16,682
104,827
37,202
90,149
82,978
2,616
120,764
63,340
29,815
132,321
9,836
210,703
2,044
134,184
761,649
7,961
2,804
86,880
40,651
4,861
63,719
18,685
3,963,258
IHC
66,836
13,948
16,585
353,118
22,616
24, 7H
27,329
1,169
51,735
28,379
4,649
200,212
116,818
20,263
73,307
116,606
322,789
18,945
76,098
117,747
216,766
68,438
57,773
183.961
15.086
46,423
3.562
17,636
119,935
51,033
141,636
100,142
3,423
150,742
73,889
36,281
162,706
11,124
221,994
3,023
143,795
900,425
9,248
3,047
99,831
43,628
5,487
70,106
22,183
4,657,042
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, POINT SOURCES
VO
O
State S02
Alabama
Ar i zona
Arkansas
California
Colorado
Connect icut
Delaware
Dlst. of Colun.
Florida
Georgia
Idaho
1 Uinois
Indiana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
Neu Hampshire
Neu Jersey
Neu Mexico
Neu fork
North Carolina
North Dakota
Ohio
Oklahoma
Oregon
Pennsylvania
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Utah
Vermont
Virginia
Washington
West Virginia
Ui scons in
Wyoming
705,358
747,658
50,489
35-, 503
106,486
31,320
87,898
6,499
924,220
782,365
33,213
1.225,099
1.657.066
278,827
175,623
996,435
214,926
104.137
249,719
269,473
723,609
190,949
227,719
1,152,910
132,935
58,255
127,859
87,473
211.899
227,038
689,548
549.244
86,993
2,372,870
76, 193
22.224
1.617.680
6,443
286,981
30,751
1,016,265
955,900
80,207
1,400
276,633
243,737
1,025,850
582,865
167,012
Cootig. U.S. 22,230,755
S04
26,072
26,586
7,562
20,685
6,918
2,021
1,783
362
22,917
25,222
5,986
30,074
26,097
8,735
5,559
16,346
12,701
6,570
5,627
5,422
22.187
8.678
6,397
15,327
5,479
3,074
5,547
2,376
5,915
7,202
21,451
20,565
9,243
38,426
6,652
12,687
39,903
261
13,447
2,950
21,755
43,452
6,513
34
11,938
12.889
23,155
16,447
10.844
658,038
NO
203,350
93,441
37,937
281,420
121,921
19,899
22,880
2,271
278,839
245,673
7,697
408.549
402,656
110,076
185,068
275,289
375,280
18,359
80,095
68,447
293,462
118,233
84,085
252,676
33,021
46,096
41,817
23,738
115,919
136,154
253.587
226,062
63,585
574,214
136,844
39,326
435,287
3,404
109,841
22,286
250,795
1,128,677
50,396
252
108,238
62,344
297,614
159,830
116,090
8.415,019
N02
6,683
3,416
1,549
14,237
4,649
518
680
102
9,991 -
7,905
304
15,066
14,048
3,604
9,282
9,067
19,571
45/
2,774
1,975
11,061
4,082
3,450
8,632
1,453
1,716
1,399
672
4,194
6,452
7,595
7,052
2,049
19,072
6.734
1,402
14,394
108
3,486
703
8,930
58,219
1,868
8
3,631
2,302
9,328
5.302
4.050
325.222
Pb
168
66
1
196
401
71
1
2
21
41
407
1,377
419
64
1
97
44
1
5
147
160
9
0
261
193
27
5
0
0
4
15
19
5
885
4
18
692
4
77
5
130
339
39
.0
31
79
376
72
3
6,981
r
CO
256,843
58,818
122,844
321,473
100,427
10,668
7,735
3,728
132,073
147.376
37,911
283,435
268,595
49,782
55,667
106,168
905,992
40,552
30,594
12,744
246,035
30,783
75,275
72,705
126.626
9,206
11,823
4,458
75,926
24,434
103,401
114,643
50,404
626,849
306,985
27.591
427,120
1,827
71,869
13,806
139,492
1,928,852
30,633
35
350,693
200,973
138.979
41,287
74,904
8,281,040
EIKIL lUHb/TtAK
HCl HF
17,501
8,040
1,598
0
8,214
350
1,003
534
7,865
18.500
285
30,219
30.086
10,373
5,944
20,321
668
24
5,939
1.955
20,578
7.855
2,347
19,993
1,809
4,152
3,189
931
2,215
7,525
8,346
21,331
64
45,666
5,207
494
37,535
13
8,140
200
21,107
17,180
3.218
8
6,393
4,483
26,359
13,803
11,870
471,429
3,192
972
1,282
119
1,076
0
167
6
26,336
2,255
157
7,158
4,071
1,543
719
3,418
1,509
3
1,143
76
2,848
1,010
285
2.416
220
523
401
112
274
886
1,701
2,785
43
6,513
692
83
4,993
0
1,448
34
3,849
5,299
449
0
1,196
1,350
4,410
2,096
1,563
102,680
NH3
546
4,544
11,180
4,221
7,072
0
1
0
19,856
18,043
110
36.266
10,610
17,473
87
105
19,831
0
2
0
207
14,903
324
6
168
322
1
0
11
136
2
7,860
182
1,635
1,274
0
7,758
0
925
1
9,338
10,464
47
0
4,118
9,141
a
591
3,320
222,688
TSP
73,780
24,904
30,491
123,324
48,106
7,403
15,037
783
91,117
37,903
10,905
178,889
182,576
137,417
39,244
115.724
107,840
16,527
32,722
15,989
130,568
118,459
21,982
282,901
17,423
39,566
25,824
3,629
89,093
31,294
223,074
105,100
44.312
252,129
61,226
30,197
170,358
966
129,304
30,321
104,033
352,388
56,131
1,401
98,930
78,110
54,871
89,599
25,387
3,959,255
Ca
1,455
1,066
278
1,612
2,104
26
151
6
5,687
271
79
5,345
4,559
2,756
321
1,573
369
65
401
175
8,615
2,012
113
16,652
117
296
369
13
34
838
1,240
2,038
705
6,998
4,933
1,001
5.791
1
441
1,967
909
6,066
2,568
2
2,197
448
858
7,616
105
103,247
Mg
443
303
86
340
404
7
160
6
844
239
21
1,723
2.108
621
94
880
. 52
19
197
129
1,104
566
61
2,928
51
79
83
8
22
371
1,038
855
713
3,209
588
49
1.820
0
305
431
603
1,865
810
2
989
289
604
841
93
29,053
Na
323
101
21
44
160
3
77
3
183
182
9
642
1,537
350
38
317
120
68
92
59
438
145
78
621
21
11
19
21
10
161
497
275
336
1,361
31
49
749
1
161
80
340
298
597
1
365
171
268
294
40
11,771
K
254
52
44
213
108
3
41
2
76
202
33
816
4,142
49
20
166
199
33
72
32
512
71
37
315
24
6
11
3
5
95
281
150
180
1,026
26
281
1,270
1
110
8
190
318
1,672
2
203
254
218
193
22
14,038
voc
47,657
12,017
13,994
269,401
15,002
21,814
23,468
409
43,824
24,766
2,366
138,852
79,295
16,132
36,564
93.249
268,308
16,228
54,336
85.522
177,806
59,741
47,683
154,981
10,960
41,233
3,083
15.134
95,099
33,750
81,784
75,278
2,374
109,557
57,462
27,048
120,042
8,924
191,151
1,854
121,732
690,969
7,222
2,544
78,818
36,878
4,410
57,806
16,951
3,595,476
THC
60,634
12,654
14,86b
320,350
20,517
22.472
24,793
1,060
46,934
25,746
4.217
181,633
105,977
18,383
66,504
105.785
292.835
17.187
69,036
106,820
196,651
62,087
52,411
166,890
13.686
42,115
3.231
15.999
108,806
46,297
128,493
90,849
3,106
136,754
67,032
32,915
147.607
10,092
201.394
2,743
130,451
816,867
8,390
2,764
90,567
39,580
4,978
63,600
20,125
4,224,879
-------
1980 KAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
State | Methane
Alabama
Arizona
Arkansas
Cal i form a
Colorado
Connecticut
Delaware
Dist. of Colum.
Florida
Georgia
Idaho
I U inois
Indiana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Hampshire
New Jersey
New Mexico
New York
North Carolina
North Dakota
Ohio
Oklahoma
Oregon
Pennsylvania
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Utah
Vermont
Virginia
Washington
West Virginia
Wisconsin
Wyoming
Contig. U.S.
567,049
37,023
51,129
2,789,315
311,144
38, 703
75,445
37,499
176,335
49,813
112,601
2,424,888
1,532,962
132,336
1,654,723
699,206
1,209,209
54,106
662,307
1,273,859
1,049,034
136,787
285,072
685,726
156,200
50,970
8,530
48,711
817,987
689,571
2,809,552
880,476
42,915
1,528.261
462,091
318,559
1,557,948
67. 705
594,917
54,229
489, 758
7,314.138
63,988
13,703
647,728
143,256
30,758
324.624
174,075
35,336,921
Ethane
129,082
1,443
1,682
206,432
17,448
1,253
3,834
1,654
9,379
5,996
1.497
129,218
69,604
4,277
113,025
43,903
170.663
3,048
135,583
28,793
67.097
5,054
5,169
30.251
7,327
2,131
383
2,812
19,480
49,417
54,662
48,158
1,453
89,220
71,772
25.156
85,656
2.734
23,294
636
28.699
285,300
4,695
1
45,224
13,427
2,466
19,542
12,681
2,081,710
Propane
123,104
3,579
2,637
345,672
8,800
426
7,964
494
6,868
4,295
900
71,756
27,093
1.743
89,726
32,708
168,092
3,306
157,592
22,945
27,214
7,354
7,402
20,364
10.952
1,337
1,247
1,980
61,550
42,258
118,289
16,875
3,636
28,042
119,643
8,507
72,196
1,163
10,788
910
14,980
449,942
7,388
361
20,618
14,162
2,037
8,008
33,268
2,192,169
THOUSAND MOLES/YEAR
Butane Iso-Butane Pentane Iso-Pentane
84,044
3,242
4,390
393, 744
7,908
3,483
14,669
570
18,383
4,573
1,134
87,450
21,130
1,329
32,525
53,016
122,850
8,058
131,482
146,153
50,901
15,871
21,758
21.375
15.168
3,052
1,773
5,984
91 , 290
23,059
196,102
24,436
1,982
43,438
107,581
9,805
78,042
7.065
35,262
1,603
17,446
611,532
11,798
655
26,432
19,237
2.151
18,579
36,057
2,639,566
70.370
2,233
987
130,179
3,730
63
4,467
126
1,427
994
179
26,058
6,551
284
14,867
10,202
39,630
1,933
84,446
6,237
12,549
5,081
1,719
5,098
5,961
451
633
967
20,957
8,732
29,241
4,298
597
7,913
52,481
2,092
14,272
231
2,521
256
3,342
143,396
3,658
11
3.305
6,843
45
2,564
12,662
756,840
1,695
3,062
2,379
196,819
1,870
7
9,511
0
10,743
3,517
826
47,002
17,074
173
37,026
23,573
84,386
16,100
21,844
23,590
48,367
30,265
15,692
15,498
8,843
4,936
2,363
2,207
85,650
48,066
75,756
11,560
1,250
19,626
55,869
956
55,657
3,877
5,127
2,457
11,588
397.000
9,213
517
14,481
13,282
78
17,087
23,712
1,482,177
537
92
194
1,316
130
0
9
0
601
1,087
210
377
393
177
79
265
346
174
129
32
427
138
1,243
190
161
48
32
9
22
549
207
415
84
596
81
902
544
0
264
22
1,861
541
59
0
296
507
521
366
145
16,375
Alkancs
281,333
64,988
68,483
1,314,786
78,161
53,515
70,913
288
218,771
35,819
10,005
616,811
442,080
137,196
148,307
747,829
1,437,125
83,156
186,048
265,892
1,171,835
407,680
274.722
919,587
51,790
53,555
7,765
83,404
416.205
121,330
339,294
559.651
6,996
501,595
229,349
179,359
570,439
49,385
1,164,997
7,811
765,133
3,684,590
39,824
15,223
523,613
261,539
11,441
321,092
85,851
19,086,558
Ethyl ene
90.158
42,964
70,975
231,632
22,945
2,092
20,040
3,372
74,426
4,111
1,446
205,937
159,689
7,104
38,311
201,326
1,093,302
1,611
8,392
32,383
137,230
18,459
642
415,498
3,022
4,420
1,758
2,117
96,267
5,179
6,723
102,693
75
217,683
17,196
40,055
227.284
4,510
160,557
1,577
160,081
1,389,390
728
0
106,730
27,149
5,713
29,645
2,573
5,497,167
Propylcne Iso-Butene
12,789
241
20,213
60,674
3,001
707
5,702
618
21,445
1,426
1,401
34,665
13,295
6,812
8,023
61,659
553,154
580
1,426
4,959
11,664
5,430
202
113,648
1,608
433
0
510
30,328
372
5,252
19,345
241
30,782
10,052
7,106
28,165
924
42,625
646
53,642
754,977
1,176
0
26,720
5,971
1,421
4,279
1,456
1,971,765
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Alkcnos
14.737
28,523
29,876
153,351
3,469
3,777
21,782
1,032
73.301
11,238
1,944
136,395
37,050
2,375
20,270
175,868
474,206
6,846
21,933
35,110
69,657
27,384
21,749
175,610
2,385
3,247
1.859
6,776
61,942
15,639
20,393
25,022
811
81,783
14,831
14,203
65,688
3,327
91,834
1,311
131,235
530,426
1,485
155
63,655
13,915
5,960
25,659
2,427
2.733,450
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
State
Alabama
Ari £Ona
Arkansas
CaL tfornia
Colorado
Connecticut
Delaware
Dist. of Colum.
Florida
Georgia
Idaho
Illinois
Indiana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
M l cfi i gan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Hampshire
New Jersey
New Mexico
New York
North Carolina
North Dakota
Ohio
Oklahoma
Oregon
Pennsylvania
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Utah
Vermont
Virginia
Washington
West Virginia
Wisconsin
Wyoming
Contig. U.S.
Benzene
16,314
518
12,300
63,471
4,406
361
5,130
37
13,548
1,533
586
14,815
29,513
4,250
12.034
36,623
200,123
3.103
11,170
9,372
32.246
8.938
5,270
64,445
2.113
1,022
443
379
42,779
9,037
32,540
7,939
146
32,218
14,084
1,857
48,375
1,204
25,851
614
31,804
382,661
1,775
239
16.422
7,344
948
6,046
4,828
1,222,772
Toluene
6.678
4,525
10,968
119,728
24,103
85,200
65,825
1
31,629
89,261
1.262
155.927
91,055
8,376
25,303
45,974
110,317
12,090
41,571
42.503
107,396
36,020
38,229
110,870
1,102
174,553
7,648
17,855
62,460
29,731
54,271
41,833
626
96,735
38,964
15.271
135,452
11,232
279,857
1,393
64,040
446,086
2,313
3,455
45,510
11,574
2,162
71.231
4.039
2.884.205
Xylene E
17,552
4,589
8,886
95,862
12,206
30,248
23,989
8
, 32,480
60,271
6,180
87,814
52,611
7,262
24,818
25,391
56.449
17,142
23,050
20,370
82,963
34,115
52,373
111.112
4,866
66,127
4,480
9,612
49,732
47,650
26,146
31,690
2,562
61,227
29,547
26,732
77,008
6,078
97.426
2,152
80,845
267,881
4,016
1,874
31,955
21.626
13,902
44,246
7,334
1,904,454
th Benz
3,417
571
1,208
14,129
812
263
953
2
4,536
6.775
1,309
10,039
4,984
1,101
504
2,889
2.158
1,126
802
623
30,887
1,123
7,839
4.222
1,001
298
198
2.579
1.437
3,422
1.293
3,789
523
9,669
1,030
6,119
5,199
1,209
3,018
136
14,729
4,191
J69
689
8,252
3,314
3,251
4,215
907
183,111
NUU3ANU
Iromat ics
1,936
1,010
5,495
41,886
959
91
1,959
0
12.969
2,404
641
34,594
8,950
0
22.709
19,795
93,517
11,990
8,267
7,135
24,646
20,594
8,801
32,691
585
3,637
1,487
1,143
50,991
34,652
971
9,035
329
15,507
22,020
1,073
29,161
3,255
11,430
1,649
16,233
197,742
2,494
150
15.623
8,376
310
13.457
3,565
807,915
lULCS/ ICAK- -
Forma Ideh «
7,980
6,116
17,261
620,007
27,362
11,333
45,833
962
53,035
8,856
146
34,010
52,720
618
35.534
42,158
224,368
7,851
44,153
589.487
77,330
40,653
120,868
51,235
69,251
9,745
2,529
13.839
253.467
7,707
241,231
28,057
26,405
111,125
149,986
2.192
142.169
1,504
48,301
256
44,846
1,121,469
8,740
1,077
51,993
33,695
9,113
11,347
28,278
4,538,201
cetaldeh
436
0
1,459
3,064
0
30
418
0
1,313
70
0
413
159
0
511
3.537
21,425
0
35
11
0
355
3
7,560
0
0
0
0
1,916
0
34
580
1
744
332
214
655
60
2,926
0
2,857
23,155
6
0
1,334
372
92
52
3
76,133
A Ideh
300
0
1.003
2,095
0
18
285
0
903
46
0
281
107
0
352
2,429
14,706
7
23
14
0
287
18
5,193
0
0
0
0
1,311
0
21
441
1
491
228
147
440
41
2,008
0
1,902
15,781
4
0
885
256
63
35
2
52,123
Acetone
9.971
1,905
3.998
129,559
11,687
41.647
25,076
507
34.226
33.950
2.704
108.166
106,575
4.655
6,338
20,442
74,797
8,167
27,129
211,063
140,812
39,630
40.283
113.993
2.037
91,437
2,617
16.020
34,635
731
80,644
61,667
347
194,304
8,333
2,950
103.069
3,810
204,996
1,244
114,246
345,397
1,190
2.731
67,706
11,338
3,038
53,830
2,006
2.607,605
Ketones
4.079
1,512
2,314
95,483
9,223
28,057
15.297
0
19,632
20,503
0
99,055
100.731
4,151
6,968
25,468
52,235
5,864
35,224
59,628
171,805
42,629
20,864
124,222
884
73,992
1,521
18,889
26,311
0
56,067
76,076
0
109,469
6,749
5,612
83,415
6,279
249,991
0
62,209
262.027
293
3,385
43,748
3,257
0
59,562
0
2,094,680
3rg Acid
1,066
716
800
18,332
4,704
2,622
187
0
4,659
477
0
21,891
4,171
51
5,737
21,275
12,719
1,263
16,185
30,301
44,431
3,574
950
22,052
0
1,067
0
476
10,755
0
535
11,753
0
22,518
751
10,662
35,740
2,941
37,430
0
15,653
39,003
16
189
24,541
1,140
34
32,876
1
466,463
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
-------
1980 N4PAP 5.2 EMISSIONS INVENIORr - ANNUAL U S. EMISSIONS, POINT SOURCES
EPA REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
Coflt \g.
1
2
3
4
5
6
7
8
9
10
U.S.
S02
551,416
993,656
3,598,182
6,050,014
7,443,167
1,680,493
1,835,991
666,208
1,355,839
329,776
24,504,741
504
18,391
30,165
91,235
168,343
156,424
85,504
36,040
46,237
58,220
34,790
725,349
NO
147,817
407.303
1,043,191
1,845,161
2,157,119
2,000.537
654,668
448,960
459,300
120,555
9.284,610
N02
4,120
12,995
34,072
62,350
75,651
101,988
25,610
16,283
21,001
4,418
358,489
Pb
245
16
1,220
609
3,221
432
390
711
295
556
7,695
CO
77,474
197,670
1,056,928
1,150,505
1,650,111
3,625,550
206,525
437,389
432,223
293,733
9,128,108
HCl
3,616
11,642
85.718
129,092
163,367
35,469
44,601
27,970
12,377
5,800
519,652
HF
211
2, 177
13.134
48,025
26,118
10,657
5,733
3,731
1,644
1,753
113,183
NH3
1
15
13,102
62,827
70,781
47,272
19,717
11,893
9,663
10.197
245,467
ISP
50.610
344,098
410,825
748,391
1,049,623
642,899
550,184
244,356
191,855
131,406
4,364,247
Ca
312
1,404
10,367
13,766
38,742
13,762
22,074
8,339
3,359
1,684
113,808
Mg
183
1,168
4,162
4,664
10,528
3,265
4,103
2,758
BOO
396
32,025
Na
169
559
1,713
2,049
4,869
696
1,124
1,362
181
253
12,975
K
80
315
1,991
1,306
7,451
751
429
2,220
304
627
15,474
VOC
165,525
194,976
310,275
711,351
686,791
1,173,369
274,370
59,924
313,603
73,074
3,963,258
TBC
193,270
261,572
372,620
787, 258
823,082
1,364,521
323,954
75,580
370,628
84,559
4,657,042
EPA REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
REGION
Contlg.
1
2
3
4
5
6
7
8
9
10
U.S.
S02
500,245
901,447
3,264,279
5,488,586
6.752,457
1,524,547
1,665,615
604,385
1,230,020
299,174
22,230,755
S04
16,664
27,366
82,769
152,721
141,908
77,569
32,696
41,946
52,817
31,562
658,038
NO
134,100
369,506
946,385
1,673,934
1,956,943
1,814,892
593.916
407,298
416,678
109,367
8,423,019
N02
3,748
11.789
30,910
56,564
68,631
92,524
23,234
14,772
19,052
4,008
325,222
Pb
222
15
1,107
552
2,922
392
354
645
268
504
6,981
CO
70,285
179,327
958,847
1,043,741
1,496,984
3,289,107
187,360
396,800
392,114
266,475
8,281,040
HCl HF
3,280
10,562
77,764
117, H3
148,207
32,178
40,462
25,374
11,228
5,262
471,429
191
1,975
11,915
43,568
23,694
9,668
5,201
3,385
1,491
1,590
102,680
NH3
0
14
11,886
56,997
64,213
42,885
17,887
10,789
8,766
9,251
222,688
TSP
45,914
312,166
372,701
678,942
952,220
583,239
499.128
221,681
174,051
119,212
3,959,255
Ca
283
1,274
9,405
12,489
35,147
12,485
20,026
7,565
3,047
1,527
103,247
Mg
166
1,059
3,775
4,231
9,551
2,962
3,722
2,502
726
359
29,053
Na
153
507
1,554
1,859
4,417
632
1,020
1,236
164
229
11,771
K
72
286
1,806
1,185
6,760
682
389
2,014
275
569
14,038
VOC
150,164
176,883
281,482
645,340
623,058
1,064,483
248.909
54,363
284.501
66,293
3,595,476
IHC
175,335
237,298
338,042
714,202
746,702
1,237,896
293,891
68,566
336,235
76,712
4,224,879
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
EPA REGION
REGION 1
REGION 2
REGION 3
REGION 4
REGION 5
REGION 6
REGION 7
REGION 8
REGION 9
Methane
1,496,786
3,627,539
3,011,685
3,742,627
6,996,555
9,726,139
2,523,755
802,551
2,834,868
REGION 10 | 574,416
Contig. U.S.
35.336,921
Ethane
38,641
74,142
274,416
293,680
379,735
578,834
149,684
44,240
208,259
40,080
2,081,710
Propane
30,180
179,839
260,901
217,021
169,467
782,573
113,169
64,954
350,497
23,569
2,192,169
1 nUUdANU P1ULC5/ T t«K - - - -
Butane Iso-Butane Pentane Iso-Pentane Alkanes Ethylene
171,399
287,392
253,346
258,919
237,369
869,411
58,280
74,516
398,759
30,175
2,639,566
9,442 46
50,198 161
106,661 101
94,873 83
60,717 179
245.226 587
20,699 57
26,864 47
133,045 202
9,114 15
756,840 1,482
,297
,406
,572 1
,495 6
,422 2
,699 1
,633
,345
,244 1
,064 1
,177 16
215
229
,500 1,
,272 4,
,297 3,
,711 5,
493 1,
601
,439 1,
,619
,375 19,
550,574
755,498
362,742
048,255
461,093
540,877 2,
258,645
270,432
387,539
450,904
086,558 5,
42,713
102,990
371,530
793,994
768,644
576,042
465,332
30,920
276,353
68,649
497,167
Propylene Iso-Butene Alkenes
7,679
35,580
64,053
213,133
100,114
1,338,768
128,917
8,127
60,915
14,478
1,971,765
0 55,990
0 82,336
0 180,050
0 544,985
0 377,927
0 1,064,978
0 201,502
0 11,888
0 183,733
0 30,061
0 2,733,450
EPA REGION
Benzene
REGION 1 14,658
REGION 2
REGION 3
REGION 4
REGION 5
REGION 6
REGION 7
REGION 8
REGION 9
REGION 10
Contig. U.S.
75,319
82,083
138,881
123,776
618,203
81,751
13,883
64,431
9,787
1, 222, 772
Toluene
172,335
116,731
290,522
597,501
558,363
636,065
319,103
33,577
131,902
28,107
2,884,205
Xylene Eth Benz Aromatics Formaldeh
85,323
75,878
169,912
398,030
362,975
410,413
209,319
33,136
104,931
54,538
1,904,454
6,490 23,
2,730 51,
18,460 55,
46,993 82,
60,918 117,
12,009 353,
6,125 59,
3,747 9,
14,898 44,
10,742 10,
183,111 807,
763 625,091
962 494,697
320 294,224
603 354,101
748 327,185
426 1,520,791
037 97,133
582 160,293
383 628,653
090 36,033
915 4,538,201
Acetaldeh
101
1,950
2,534
11,723
1,723
46,371
8,071
10
3,064
586
76,133
Aldeh
81
1,332
1,697
8,047
1,201
31,718
5,544
7
2,095
402
52,123
Acetone
283,438
115,279
226,526
519,781
643,317
433,257
216,423
18,511
134,081
16,992
2,607,605
Ketones
122,102
82,378
177,684
478,821
583,250
323,325
209,334
10,401
98,515
8,869
2,094,680
Org Acid
37,992
11,289
76,708
93,263
129,461
53,272
28,907
It, 722
19,048
11,802
466,463
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, AREA £ POINT SOURCES
VO
State | S02
Alabama
Arizona
Arkansas
California
Colorado
Connecticut
Delaware
Dist. of Colum.
Florida
Georgia
Idaho
Illinois
Indiana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Hampshire
New Jersey
Mew Mexico
New York
North Carol ina
857,549
844,078
87,137
519,799
140,138
63,665
124,669
15,325
1,102,994
900,080
56,210
1,464,520
1,970,870
334,278
228,074
1,150,036
401,333
133,369
303,471
358,065
841,399
238,705
303,846
1,333,218
169,224
78,117
148,157
108,484
309,856
262,555
870,307
655,591
North Dakota | 115,391
Ohio 2, 681,314
Oklahoma 104,168
Oregon
Pennsylvania
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Utah
Vermont
VI rgini a
Washington
Uest Virginia
Ui sconsin
Wyoming
55,987
1,899,006
14,168
344,968
40,863
1,158,153
1,324,373
116,615
8,185
370,780
317,791
1,145,522
670,610
211,134
Contig. U.S. | 26,954,136
S04
32,991
30,871
10,478
35,917
9,347
8,110
4,645
1,121
30,793
30,684
8,676
42,270
38,111
11,010
7,409
23,108
24,581
11,223
10,727
14,498
32,609
14,535
11.281
22,746
7,583
4,078
6,667
4,867
20,690
9,202
43,230
31,046
11,574
51,554
9,558
18,601
60,532
1,491
17,550
3,798
28,905
59,869
8,886
1,764
21,579
19,758
27,902
23,795
13,388
975,608
NO
457,653
245,625
194,532
1,268,139
284,405
128,656
58,416
23,194
663,745
553,085
82,313
909,708
741,610
284,792
479,624
519,674
664,196
62,433
242,626
251,390
668,942
340,540
274,714
515,805
127,844
160,005
90,658
55,291
387,707
237,643
688,092
499,064
128,008
1,145,357
422,056
207,286
976,345
33,295
259,758
73,063
498,219
3,122,306
145,205
21,631
355,772
270,908
440,190
380,932
234,634
20,877,086
N02
29,603
18,269
16,611
114,625
20,372
11,094
3,850
2,158
48.464
37.561
9,561
63,279
45,233
20,962
33,690
31.680
44,770
4,635
18,477
19,380
46,435
26,090
19,797
33,992
12,455
13,034
6,260
3,666
29,802
16,473
48,752
33,611
8,083
72,251
31,010
19.481
65,211
2,958
18,334
6,293
33,117
207,728
10,552
2,149
27,662
23,738
20,824
26,842
14,273
1,475,151
Pb
681
366
264
2,643
756
381
71
39
1,087
697
548
2,635
1,101
427
250
519
554
124
456
666
1,148
469
297
849
310
199
107
100
70o
174
1,273
727
72
2,160
412
334
1,918
82
459
70
732
2,169
191
62
646
505
618
592
86
31,732
CO
1,811,119
1,310,433
1,045,560
9,524.250
2,302,185
1,192,328
242,885
338,780
4,071,755
2,335,826
1,280,507
4,2,6,797
2,374,627
1,105,666
1,072,560
1,594,516
2,541,546
506,637
1,459,780
2,133,002
3.613,069
1,928,665
991,881
2,206,090
1,422,156
609,510
521,365
352,582
2,294,053
932,466
4,758,845
2,289,334
282,219
4,697,200
1,854,007
1,454,001
4,377,701
316,586
1,207,907
509,495
1,951,470
9,063,470
990,051
202,077
2,322,403
2,401,774
784,971
1,892,865
589,965
99,308,937
TONS/YEAR
HCl
19,542
8,937
1,786
472
9.110
491
1,152
655
8,834
20.453
329
34,318
33,494
11,505
6,614
22,635
857
40
6,559
2,241
22.871
8,820
2,599
22,184
2,001
4,637
3,554
1.036
2,566
8,299
9,269
23,667
119
50,783
5,765
729
42,015
27
9,045
235
23,436
19,257
3,588
12
7,328
5,062
29,078
15,406
13,110
526,524
HF
3,539
1,087
1,445
145
1,186
0
184
23
29,228
2,503
242
7,937
4,607
1,706
799
3,841
1,761
5
1,307
86
3,150
1,120
314
2,681
243
582
444
124
328
977
1,880
3,310
60
7,934
768
92
5,525
0
1,648
38
4,357
5,900
511
0
1,385
1,516
4,861
2,328
1.727
115,434
NH3
11,964
11,921
25,418
32,013
24,987
1,946
2,051
59
28,793
35,359
8,133
68,633
29,361
80,410
34,189
8.185
26,314
417
2,992
104
10,433
48,624
7,809
17,264
3,890
44,683
705
1
80
4,523
13,961
21,118
6,642
16,124
15,266
4.249
24,309
0
4,440
12,941
18,117
61,713
1,961
3
10,913
18.097
335
32,054
5,159
838,664
TSP
439,271
841,489
874,245
1,536.414
1,134,995
120,226
49,382
15,099
919,841
882,031
330,728
932,702
496,649
1,237,545
1,852,371
452,395
559,071
127.174
227,611
210.504
880,263
1,199,026
587,204
2,877,954
880,654
1,080,992
919,646
66,310
402,215
1,249,009
802,715
700,462
1,295,268
1,070,910
1,107,180
1,849,960
1,432,694
32,323
451,493
715,996
656,159
5,937.876
690,811
100,889
466,354
347,565
381,995
706,684
486,720
42,617,370
Ca
1,604
1,175
307
1,777
2,320
28
167
7
6,269
299
87
5,892
5,026
3,038
354
1,734
407
72
442
193
9,496
2,218
125
18.356
129
326
407
15
37
923
1,367
2,247
777
7,714
5,438
1,103
6,383
1
486
2,168
1,002
6,686
2,831
3
2,422
494
946
8,395
116
113,808
Mg
488
334
95
375
445
8
176
7
931
263
23
1,899
2,324
685
103
970
58.
21
217
142
1,217
624
68
3,228
56
87
91
9
24
409
1,144
943
786
3,538
648
54
2,006
0
337
475
665
2,056
892
3
1,090
319
666
927
103
32,025
Na
356
111
23
48
177
3
84
4
201
201
10
708
1,694
386
42
349
133
75
101
65
482
160
86
685
23
12
21
23
11
178
548
303
371
1,500
34
54
826
1
178
89
375
329
658
1
402
188
296
324
44
12,975
K
280
57
48
235
119
3
45
2
84
222
37
899
4,565
54
22
183
219
36
79
35
565
79
41
347
26
6
12
3
6
105
310
165
199
1,131
29
310
1,400
1
122
9
209
351
1,844
2
223
280
240
213
25
15,474
VOC
391,455
254,096
223,135
2,216,485
356,946
284,183
77,101
44,081
828,561
508,361
222,050
988,586
562,647
237,157
250,269
441,688
625,559
141,991
363,270
515,765
916,363
469,214
261,800
629.726
236,467
168,618
93.948
103.987
696,758
191,042
1,160,860
614.002
53,274
1,001,059
324,988
340,267
1,043,563
81,042
474,791
95,639
554,586
2,172,905
160,449
58,570
527,715
465,326
154,780
476,956
102.467
23,164,547
THC
425,591
271,243
234,377
2,414,927
385.554
299,090
81,188
48,400
868,694
530,222
230,398
1,092,842
623,821
258,603
298,662
469,555
669,847
149,051
394,420
568,190
987,380
496,094
278,672
673,526
245,600
178,920
99,725
109,401
749,784
213,500
1,267,046
655,149
58,166
1,092,677
347,352
363,147
1,113,027
86,846
501,073
101,160
587,715
2,381,939
172,386
61,481
561,508
494,352
161,785
512,284
111,091
24,977,459
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS, AREA i POINT SOURCES
State | S02
Alabama
Arizona
Arkansas
Cal i forma
Colorado
Connecticut
Delaware
Dist. of Colum.
Florida
Georgia
Idaho
1 11 inols
Indiana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
M I ch i gan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Hampshire
New Jersey
New Mexico
New York
North Carol ma
North Dakota
Ohio
Ok I ahoina
Oregon
Pennsylvania
Rhode Island
South Carol ma
South Dakota
i ennessee
Texas
Utah
Vermont
Virginia
Washington
west Virginia
Ui scons! n
Wyoming
777.969
765,749
79,041
471,560
127,133
57,756
113,099
13,903
1,000,637
816.554
50.993
1,328,614
1.787,975
303,258
206,909
1,043.314
364,088
120,992
275,309
324,836
763,319
216,554
275,649
1,209,497
153,520
70,868
134,408
98,417
281,101
238,190
789,543
594,752
104,683
2,432,493
94,501
SO, 791
1,722.780
12,853
312,955
37,071
1,050,678
1,201,469
105,793
7,425
336,371
288.300
1,039,220
608,378
191,541
Contig. U.S. [ 24,452,809
S04
29,929
28,006
9,506
32,584
8,480
7,357
4,214
1,017
27,935
27,837
7,871
38,347
34,574
9,988
6,721
20,964
22,300
10,181
9,731
13,152
29,583
13,186
10,234
20,635
6,879
3,700
6,048
4,415
18,770
8,348
39,218
28,165
10,500
46,770
8,671
16,875
54,914
1,353
15,921
3,446
26,223
54,313
8,061
1,600
19,576
17,924
25,313
21,587
12,146
885,069
HO
415,180
222,829
176,477
1,150,441
258,011
116,715
52,994
21,041
602,144
501,755
74.674
825,281
672,785
258,361
435,111
471,446
602,556
56,638
220,108
228,058
606,860
308,935
249,218
467,935
115,979
145,155
82,244
50,160
351,724
215,589
624,231
452,748
116,128
1,039,061
382,885
188,047
885,733
30,205
235,651
66,282
451,981
2,832,530
131,729
19,624
322,753
245,765
399,340
345,578
212,859
18.939,136
N02
26,855
16.574
15,069
103,987
18,481
10,064
3.493
1.958
43.966
34,079
8,673
57.406
41,035
19,017
30,563
28.739
40,615
4,205
16,762
17,581
42,125
23,668
17,959
30,837
11,299
11,824
5.679
3.326
27,036
14,944
44,227
30,491
7,333
65,545
28,132
17,673
59,159
2,683
16,632
5,709
30,043
188,449
9,572
1,949
25,095
21,535
18,891
24.351
12,948
1,338,240
Pb
618
332
239
2,398
686
346
64
35
986
632
497
2,390
999
387
227
471
503
112
414
604
1,041
425
269
770
281
181
97
91
640
158
1,155
660
65
1,960
374
303
1,740
74
416
64
664
1,968
173
56
586
458
561
537
78
28,787
..p
CO
1.643,024
1,188,806
948,518
8,640,261
2,088,509
1,081,662
220,342
307,336
3,693,837
2,119,029
1,161,657
3.852,635
2,154,231
1,003,044
973,011
1,446,523
2,305,669
459,614
1,324,291
1,935,027
3,277,726
1,749.656
899,821
2,001,333
1,290,161
552.938
472,975
319,857
2,081,131
845,919
4,317,154
2,076,851
256,026
4,261,240
1,681,933
1,319,048
3,971,392
287,202
1,095,796
462,206
1,770,347
8,222,279
898,160
183,321
2,106,855
2,178,857
712,116
1,717,179
535,209
90,091,713
C 1 K1L lur
HCl
17,729
8,108
1,620
428
8,265
445
1,045
594
8,014
18,555
298
31,133
30,386
10,437
6,000
20,535
777
36
5,950
2,033
20,749
8,002
2,358
20,125
1.817
4,207
3,224
940
2,328
7,529
8,409
21,471
108
46,070
5,230
661
38,116
24
8,206
213
21,261
17,470
3,255
11
6,648
4,592
26,380
13,976
11,893
477,664
:>/ ICKK- - -
HF
3,211
986
1,311
132
1,076
0
167
21
26,516
2,271
220
7,200
4,179
1,548
725
3,485
1,598
5
1,186
78
2,858
1,016
285
2,432
220
528
403
112
298
886
1,706
3,003
54
7,198
697
83
5,012
0
1,495
34
3,953
5,352
464
0
1,256
1,375
4,410
2,112
1,567
104,722
NH3
10,854
10,815
23.059
29,042
22,668
1,765
1,861
54
26,121
32,077
7,378
62,263
26,636
72,947
31,016
7,425
23,872
379
2,715
94
9,465
44,111
7,084
15,662
3,529
40,536
640
1
73
4,103
12,665
19,158
6,025
14,627
13,849
3,855
22,053
0
4,028
11,740
16,435
55,986
1,779
2
9,900
16,418
304
29,079
4,681
760,828
TSP
398,501
763,386
793,102
1,393,814
1,029,652
109,067
44,799
13,698
834,467
800,166
300,032
846,136
450,556
1,122,956
1,680,443
410,408
507,183
115,371
206,486
190,966
798,564
1,087,740
532,703
2,610,841
798,916
980.660
834,289
60,155
364,885
1,133,083
728,215
635,450
1,175,048
971,518
1,004,418
1,678.256
1,299,721
29,323
409,590
649.541
595,260
5,386,757
626,694
91,525
423,071
315,307
346,541
641,095
441,545
38,661,905
Ca
1,455
1,066
278
1,612
2.104
26
151
6
5,687
271
79
5.345
4,559
2,756
321
1,573
369
65
401
175
8,615
2,012
113
16,652
117
296
369
13
34
838
1,240
2,038
705
6,998
4,933
1,001
5,791
1
441
1,967
909
6,066
2,568
2
2,197
448
858
7,616
105
103,247
Mg
443
303
86
340
404
7
160
6
844
239
21
1,723
2,108
621
94
8EO
52-
19
197
129
1,104
566
6)
2,928
51
79
83
8
22
371
1,038
855
713
3,209
588
49
1,820
0
305
431
603
1,865
810
2
989
289
604
841
93
29,053
Ha
323
101
21
44
160
3
77
3
183
182
9
642
1,537
350
38
317
120
68
92
59
438
145
78
621
21
11
19
21
10
161
497
275
336
1,361
31
49
749
1
161
80
340
298
597
1
365
171
268
294
40
11,771
K
254
52
44
213
108
3
41
2
76
202
33
816
4,142
49
20
166
199
33
72
32
512
71
37
315
24
6
11
3
5
95
281
150
180
1,026
26
281
1,270
1
110
8
190
318
1,672
2
203
254
218
193
22
14,038
VOC
355,123
230,512
202,425
2,010,766
323,817
257,807
69,945
39,990
751,659
461,178
201,440
896,833
510,426
215,146
227,041
400,695
567,503
128,812
329,554
467,896
831,314
425,665
237,502
571,281
214,520
152,968
85,228
94,335
632,090
173,311
1,053,116
557,015
48,330
908,147
294,825
308,686
946,707
73,520
430,726
86,762
503,114
1,971,239
145,557
53,134
478,736
422,137
140,414
432,688
92,956
21,014,593
THC
386,090
246,068
212,624
2,190,791
349,769
271,330
73,653
43.907
788,067
481,010
209,014
991,413
565,923
234,601
270,943
425,975
607,681
135,217
357,813
515,456
895,740
450,050
252,808
611,016
222,805
162,315
90,469
99,247
680,194
193,684
1,149,447
594,343
52,767
991,263
315,114
329,442
1,009,724
78,786
454,570
91,771
533,168
2,160,874
156,366
55,775
509,394
448,470
146,769
464,738
100,780
22,659,252
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS Of HYDROCARBON SPECIES, AREA & POINT SOURCES
State | Methane
Alabama | 1,573,771
Arizona 896,985
Arkansas
California
Colorado
Connecticut
Delaware
Dist. of Colum.
Florida
Georgi a
Idaho
1 1 1 inois
I nd i ana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Hanpshire
New Jersey
New Mexico
Hew York
North Carolina
North Dakota
Ohio
Oklahoma
Oregon
Pennsylvania
Rhode Island
South Carolina
South Dakota
558,234
10,260,471
1,485,865
732,077
205,177
204,402
1,996,490
1,085,897
430,560
5,380,945
3,147,863
1,139.796
2,474.816
1,374,175
2,084,408
309,467
1,393,384
2,766,519
3,599.190
1,332,039
875,921
2,230,248
468,310
546.837
298,220
253,471
2,757,208
1,124,795
5,486,000
2,017.901
260,510
4,705.255
1,043.501
1,146.557
3,390,799
297,983
1,350,544
288,618
Tennessee 1,648.692
Texas | 10,949,271
Utah 622,059
Vermont 128,745
Virginia | 1,643.629
Washington | 1.476,488
west Virginia | 327,217
Wisconsin | 1,778,628
Wyoming | 444,205
Contig. U.S. | 91,994,146
Ethane
209,627
53,822
52,601
633,765
93,589
72,370
17,314
23,401
190,339
106,257
28,034
325,420
193,805
54,180
155,411
124,553
245,672
51,938
213,749
130,616
262,855
121,895
53,722
157,675
32,253
28,316
21,304
31,403
161.291
88,358
330,535
190,226
12,471
305,838
131,690
92,788
332,268
19,886
86,039
16,303
141,478
552,430
39,437
21,031
166,156
J10, 331
44,587
139,165
30,067
6,698,261
Propane
155,998
24,755
25,129
484.114
36,497
25,185
11,797
1,196
64,620
51,751
59,608
129.931
71,539
15,863
105,469
76,867
197,016
26,038
182,598
51,565
94,209
51,657
33,106
71,577
71,890
9,516
8,682
15,062
106,216
54,137
218,091
76,421
7,131
103,317
152,523
57,838
170,193
6,513
37,137
20,223
60,037
579,425
17,872
10,607
64,313
70,487
23,232
50,648
40,121
4, Ore, 718
Butane
320,528
150,781
140,577
1,862,844
271,698
181,076
52,016
18,458
603,312
360,837
105,347
666,352
339,975
174,794
189,434
282,557
372,151
70,755
363,460
461,183
549,635
281,453
160,996
141,325
120,748
100,912
71,389
55,770
506,219
142,060
908,735
369,005
41,316
650,221
284,130
198,968
656,095
56,233
216,852
55,791
301,568
1,622,612
128,881
29,449
338,089
306,982
100.858
290,622
96,998
15,972,045
THOUSAND HOLES/YEAR---
Iso-Butane Pentane
116,617
26,862
30,055
382,842
40,933
29.891
10,594
3,051
111,848
76,178
48,168
127,598
61,311
30,326
42,278
60,201
91,413
13.461
125,305
59,912
103,574
51,668
33,654
59,661
54,709
16.823
11,379
10,431
93,946
23,652
174,360
71,208
7,710
112,347
93,091
49,745
124,571
9,077
40,853
19,018
54,473
353,678
19,625
5,599
57,062
69,590
20,680
49,660
20,467
3,301,153
35,204
14,227
24,437
375,136
29,784
19,613
13,841
385
90,327
62,646
38,322
113,602
55,777
22,480
58,562
61,642
123,265
23,856
50,603
57,754
110,405
64,524
39,125
55,707
47,323
17.732
10,789
8,508
134,033
60,161
159,989
58,440
7,032
91,706
87,690
36,867
128,805
9,398
32,610
17,209
48,850
563,229
20.713
4,452
52,722
59,018
15,028
49,776
30,988
3,294,293
Iso-Penta
5,329
1,646
3,369
16,040
3,191
7,270
922
105
4,996
6,224
2,387
12,821
11,583
1,305
1,112
7,962
2,452
8,232
5,860
5,858
16,521
10,332
4,703
12,647
2,290
670
770
4,357
10,574
3,063
27,398
14,924
291
18,485
4,775
6.562
29.232
1,284
3,829
693
12,913
3,349
1,387
3,521
12,118
6,886
5,716
11,432
986
340,374
Alkanes
2,319,833
1,520,405
1,305,146
13,384,252
2,127,989
1,606.122
381.500
290,630
5,048,220
2,946,840
1,109,709
5.880,990
3,242,282
1,560,840
1,446,173
2,670,051
3,488,418
661 , 775
2,062,491
2,978,536
5,584,447
2,733,721
1,507,955
3.568,453
1,149,951
832,578
536,920
546,596
4,093,330
1,007,218
7,016,755
3,623,809
318,645
5,867,268
1.757,806
1,886.315
5,860,445
499,415
2,783.383
522,694
3,180,878
12.339,690
961,298
278.131
3.097,842
2,731.880
843,050
2,742,188
542,700
134,447,565
Ethylene
756,285
656,653
503,046
3,927,557
794,754
353,013
100,872
72,146
1,667,630
981,268
971,704
1,480,249
883,593
427,234
480,608
914,457
1,800,977
129.8.&
489,473
683,158
1,202,002
723,385
450,615
1,179,046
1,017,435
257,722
203,047
98,438
973,665
312,587
1,440,965
956,294
109,770
1,546,811
569,149
873,792
1,477,528
104,316
681,306
349,198
848,711
4,798,633
323,377
59,980
777,212
1,070.991
269,844
651,480
209,926
41,611,730
Propylene
257,270
181,695
177,029
1,541,610
263,830
170,873
46,113
82.772
660,287
325,575
73,974
633,184
341,907
194,612
170,076
270,926
827,238
63,819
226,538
320,678
540,016
315,331
137.992
425,759
70,750
99,641
69,281
43,540
442,308
121,450
674,394
353,734
42,115
627,042
176,897
192,263
570,729
49,250
238,179
53,037
336,381
1,808,913
124,809
26,560
330,061
292,561
89,889
308,655
66,074
15,457,664
[so-Butcn Alkenes
2,385
1,725
1,458
7,648
2,383
558
321
131
3,215
2.947
768
5,548
4,005
1,667
2,744
2,320
2,032
270
1,069
1,101
2,214
1,813
1,196
2,317
1,429
1,233
866
127
1,914
1,856
2,106
2,193
768
6,018
1,373
2,155
4,951
150
1,120
367
2,761
8,657
1,875
126
2,319
1,814
1,106
1,832
2,287
103,241
482,416
422,069
321,801
2,684,126
517,496
309,577
80,139
32,585
1,153,057
700.443
629,825
1,087,219
594,963
268,958
298,532
681,889
931,941
152.992
387.379
530, UU6
922,305
548.556
337,040
765,362
655,280
159,891
137,317
111,563
736,594
221,475
1,251,982
711,531
64,435
1,110,201
413,355
578,528
1,134,168
85,884
455,019
222,061
658,712
2,727,929
209,609
68,482
598,216
728,113
213,316
507,707
120,507
28,722,513
-------
1980 HAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, AREA & POINT SOURCES
I
vO
OO
State | Benzene
...............4
A I abania
Art zona
Arkansas
Cal i form a
Colorado
Connect (cut
Delaware
Dist. of Colum.
F I or ida
Georgia
Idaho
I llinois
I nd 1 ana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Michigan
M innesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Hauipsh i re
Ney Jersey
Mew Mexico
New York
North Carol ma
North Dakota
Ohio
Oklahoma
Oregon
Penns> Ivania
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Utah
Vermont
Virginia
Washington
West Virginia
Ui sconsln
Uyoflilng
89,501
59,304
52,999
601,833
86,940
57,234
17,754
11,251
229,249
109,761
20,278
204,777
133,299
58,579
61,218
101,038
276,075
20,448
83,079
108,988
194,116
96,152
44,746
159,348
21,505
31,904
22,968
14,444
183,820
45,818
249,269
114,625
11,712
229,760
65,700
55,358
225,515
18,262
84,966
13,649
121,130
713,885
39,639
8,529
113,069
89,491
26,632
91,027
22,126
Contlg. U S. | 5,492,770
Toluene
243,603
174,565
151,319
1,584,475
286,203
281,066
104,644
38,583
617.922
423,006
70.819
772,740
432,474
176,389
174,385
262,336
341,397
96,607
277,321
371,886
643,102
330,655
172,776
447,560
68,376
266,253
74,367
77,267
495,186
149,511
841,816
413,488
35,477
736,290
205,473
196,172
775,370
64,222
463,241
43,718
364,231
1,375.843
121,038
40,183
375,119
289,661
102,562
380,425
61,308
16,492,428
Xylene
205.961
90,847
127,830
853,308
158,408
266,244
57,451
15,058
312.838
280,901
80,110
566,170
426,143
78,445
88,969
278,477
172,142
245,155
230,376
253,931
634,751
370,252
179,149
516,632
76,475
105,508
43.300
1.10,578
428,671
143,272
924,138
505,266
17,738
681,147
195,591
217,570
976,773
52,729
237,428
30,857
439,913
594,260
67,823
101,578
418,972
257,552
172,803
404,415
42,571
13,762,475
1 HOUSANO MO
Eth Benz Aromatics
45,062
18,922
27,638
17V, 397
32,321
55,178
8,471
1,978
60,615
55,337
17,959
119,973
91,273
16,790
14,440
61,032
26,884
54,220
48,135
53,991
157,943
77,633
36.189
97.448
17,169
8,906
7,910
32,243
88,890
24,461
212,338
111,876
3,598
153.V76
38,620
49,540
215,513
12,022
34,329
6,305
97,337
68,527
14,360
23,967
97,394
56.192
40,376
87,009
8,635
2,870,820
67,071
49,833
43,493
375,576
66,789
34,433
11.509
16.965
177,855
87,188
19,006
179.184
90,543
42,367
68,225
73,033
158,281
25,794
58,151
72,912
132,620
86,113
44,256
104,642
21,816
29,109
23,959
10.227
136,296
69,805
140,839
90,602
13,433
157,209
64,190
47,373
160,949
13.110
55,479
13,670
84,342
462,742
36, 190
5,913
86.0S6
73,547
23,292
77,741
27.780
4,011,537
LtS/YtAK
Formaldeh Acetaldeh
249,170
190,691
159,273
2,156,076
314,604
215,616
94,179
25,185
687,059
346,609
76,609
654,043
402,404
194,161
217,084
365,889
560,405
77,004
309.082
961,810
571,711
330,437
267,383
386,118
152,828
125,688
76,174
65.899
781,319
145,756
1,056,132
376,800
80,657
753,465
312.669
194,580
806,177
57,583
228,471
49,333
347.580
2,302,927
147,018
33,191
397,547
358,434
114,005
302,076
120,680
19,199,592
50.371
36,076
31,923
164,316
49,907
11,899
7,169
2,737
68,558
61,687
16,064
117,253
84,240
34,862
57,995
52.507
64,275
5,730
22,435
23,316
46,636
38,445
24,991
56,082
29,867
25,764
18,123
2,705
43,853
38.933
44,518
46,766
16,040
127,213
29,221
45,412
105,124
3,270
26,512
7,671
61,082
206,478
39,190
2,662
50,108
38,367
23,208
38,612
47,775
2,247,947
Aldeh
21,887
21,823
8,380
98.469
19,947
5.370
2,186
6,187
80,150
24,059
4,698
28,759
8,726
4,958
7,101
12,834
29,712
3,557
11,559
14,552
15,765
9,118
11,733
20,155
3,776
5,019
12.298
2,241
13,557
9,236
30,370
25,189
4,299
18,187
12,408
7,551
23,703
1,962
11.849
3,084
11,866
98.762
5,677
1,263
12,626
16,703
3,408
7,921
1.653
816,293
Acetone
72,265
62,885
28,718
868,194
64,785
105.038
41,253
4,636
291,242
136,169
12,527
324,306
227,464
45,902
50,294
91,699
160.493
26,388
87,166
305,718
309,737
120,696
74,158
188,836
12,484
114,850
20,730
29,880
290,770
27,194
297,159
179,863
7,096
415,042
59,881
53,671
308,948
26,925
269,015
7,640
222,452
777,994
27,658
13,751
165,600
71,429
15,629
131,387
6,362
7,253,977
Ketoncs
45,057
23,869
28,515
321,086
39,890
62,707
21,433
4,675
102,741
82,615
8,714
221,031
160,694
30,748
29,807
55,738
86,379
21,949
70,755
121,552
264,206
86,368
47,226
176,818
7,597
86.111
8,132
29,900
114,213
11,532
219,671
150,545
3,995
224,326
31,171
35,018
205,283
16,629
283,609
4,614
113,755
409,054
14,695
9,035
96,536
45,846
12,410
124,095
4,484
4,376,829
Org Acid
19,763
8,026
13,611
110,828
14,501
19,773
3,504
4,195
39,105
36,945
3,994
90,195
29,901
11,986
17,188
34,538
30,115
17,005
34,690
66,391
82,420
26,848
9,718
49.833
2,136
5,849
1,709
7.013
62,114
2,586
102,881
40,532
1,224
80,248
10,160
25,949
104,205
7,575
55,381
1,484
44,837
96,738
3,831
4,008
47,743
23,316
4,458
82,950
636
1,594,637
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
-------
1980 MAPAP 5 2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS. AREA i. POINT SOURCES
EPA REGION | S02
REGION 1
REGION 2
REGION 3
REGION 4
REGION 5
REGION 6
REGION 7
REGION 8
REGION 9
REGION 10
685,936
1.180.163
3,858.772
6,473,217
7,867,419
2.179.556
1,973.687
793,365
1.512.034
429,988
Contlg. U.S. | 26,954,136
EPA REGION
REGION 1
REGION 2
REGION 3
REGION 4
REGION 5
REGION 6
REGION 7
REGION 8
REGION 9
REGION 10
S02
622.280
1.070,643
3,500,682
5.872,509
7.137.332
1,977,289
1,790.531
719.740
1.371,718
390,084
S04
41,953
63,920
126,506
206,358
202,874
113,688
45,243
54,576
73,455
47,035
975.608
S04
38,059
57,988
114,766
187,208
184,047
103,138
41,044
49,511
66,638
42,670
NO
552.696
1,075,799
2,096,543
3,725,913
4,187,088
4.640,733
1,440,226
993, 160
1,604,421
560.507
20.877,086
NO
501,400
975,955
1,901,970
3,380,124
3,798,500
4,210,037
1,306,563
900,988
1,455,514
508,486
N02
43,882
78,555
138,182
252,170
280,130
316,592
101,678
72,028
139,155
52,780
1,475,151
N02
39,809
71,264
125,357
228,766
254,131
287,210
92,241
65,342
126.240
47,881
Pb
1,415
1,979
3,748
5,199
8,105
3,573
1.725
1,485
3,116
1.387
31,732
Pb
1,284
1,795
3,400
4.716
7.353
3.241
1.565
1.347
2,827
1,258
CO
4,703,212
7,052,898
9.526,520
16,253,808
18,753,223
15.437,049
4,993,826
6,096,071
11,356.048
5,136,282
99,308.937
CO
4,266,684
6,398,285
8,642,332
14.745,227
17,012.667
14,004,319
4,530,326
5,530,270
10,302,041
4,659,562
-TONS/rEAR
HCt
3,847
11,835
86,787
130,211
165,692
35,964
44,940
28,165
12,963
6,120
526,524
HF
215
2.208
13,285
48,740
27,076
10,851
5,768
3.765
1.676
1.850
115,434
METRIC TONS/TEAR--
HCl HF
3,490
10.737
78,733
118,128
150.316
32,627
40,770
25,551
11,760
5,552
195
2,003
12,052
44,217
24,563
9,844
5,233
3,416
1,520
1,678
NH3
2,470
14,042
40,660
135,784
205,228
133.234
176.547
55,581
44,639
30,479
838,664
NH3
2,241
12,738
36,886
123,182
186,181
120,869
160,161
50,423
40,496
27,651
TSP
657.426
1,204,930
2,573,135
5,088,856
5,286,234
9,727,381
7,049,162
5,204,444
3.297,549
2,528,253
42.617,370
TSP
596.408
1,093.100
2,334,316
4,616,546
4,795,609
8,824,543
6,394,901
4,721,397
2,991,490
2,293,595
Ca
312
1,404
10,367
13,766
38,742
13,762
22,074
8,339
3,359
1,684
113,808
Ca
283
1,274
9,405
12,489
35,147
12,485
20,026
7,565
3,047
1,527
Mg
183
1,168
4,162
4,664
10,528
3,265
4.103
2,758
800
396
32,025
Hg
166
1,059
3,775
4,231
9,551
2,962
3,722
2,502
726
359
Na
169
559
1,713
2,049
4,869
696
1,124
1,362
181
253
12,97!)
Na
153
507
1.554
1,859
4,417
632
1,020
1,236
164
229
It
80
315
1,991
1,306
7,451
751
429
2,220
304
627
15,474
K
72
286
1,806
1,185
6,760
682
389
2,014
275
569
voc
1,185,538
1,857,619
2,210,510
4,075,244
4,414,825
3,537.629
1,285,770
1,005,242
2,564,528
1,027,643
23,164.547
VOC
1,075,505
1,685,207
2,005,346
3,697,012
4,005,073
3,209,303
1,166,436
911,942
2,326,506
932,263
THC
1,274,058
2,016,830
2,360,328
4,316,670
4,805,098
3,847,014
1,409,712
1,073,957
2.785,895
1,087,898
24,977,459
THC
1,155,810
1,829,642
2.141,260
3.916,031
4.359,126
3,489,976
1,278,875
974,279
2,527,328
986,926
Contij. U.S.] 24,452,809 885,069 18,939,536 1,338,240 28,787 90,091,713 477,664 104,722
760,828 38,661,905 103,247 29.053 11,771 14,038 21,014,593 22,659,252
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL U.S. EMISSIONS OF HYDROCARBON SPECIES, AREA & POINT SOURCES
>
I
O
c
EPA REGION |
REGION 1
REGION 2
REGION 3
REGION 4
REGION 5
REGION 6
REGION 7
REGION 8
REGION 9
REGION 10
Contig. U.S.
Methane
4,488,261
8,243,208
7,164,608
11,923,392
19,943,921
15,760,210
6,391,697
3,569,567
11,455,675
3,053,606
91,994,146
Ethane
327,245
491,826
797,476
1,102,242
1,348,978
1,070,750
395,581
224,119
708,892
231,153
6,698,261
Propane
134,969
324,307
453,331
555,938
501,301
1,008,229
202,425
193,733
517,552
187,933
4,079,718
Butane
854,466
1,414,954
1,528,977
2,615,654
2,778,259
2,561,530
806,464
715,431
2,085,014
611,297
15,972,045
- I MUUbANU ni
Iso-Butane
128,371
268,306
341,262
565,032
506,159
591,888
149,087
162,461
421,084
167,503
3,301,153
JLtb/TtAK--
Pentane
123,580
294,022
261,384
428,845
485,791
858,782
154,481
153,049
400,152
134,208
3,294,293
I so- Pent Alkanes
30,523 6,570,576
37,972 11,110,085
53,953 12,535,958
60,880 24,080,968
81,174 26,050,896
17,009 19,898,278
15,734 7,408,045
8,838 5,623,277
18,456 15,441,577
15,835 5,727,904
340,374 134,447,565
Ethylene
1,428,731
2,414,630
3,187,076
7,256,567
6,487,520
7,984,392
2,344,611
2,804,459
4,787,257
2,916,488
41,611,730
Propylene
674,720
1,116,702
1,346,102
2,580,343
2,766,134
3,111,527
890,088
620,664
1,792,586
558,798
15,457,664
Iso-Buten
2,332
4,020
9,897
18,138
21,432
15,376
7,961
9,109
10,240
4,737
A I kenes
1,258,505
1,988,577
2,445,803
5,180,087
4,770,952
4,616,501
1,492,723
1,789,389
3,243,512
1,936,466
103,241 28,722,513
EPA REGION
REGION 1
REGION 2
REGION 3
REGION 4
REGION 5
REGION 6
REGION 7
REGION 8
REGION 9
REGION 10
Contig. U.S.
Benzene
227,905
433,089
477,301
895,017
949,131
1,154,477
311,050
195,570
684,105
165,126
^
5,492,770
Toluene
931,231
1,337,002
1,673,599
2,960,603
3,295,684
2,223,543
1,064,588
616,120
1,833,406
556,652
16,492,428
Xylene
1,056,215
1,352,810
1,871,433
2,439,933
3,082,877
1,233,095
789,555
393,871
987,454
555,232
13,762,475
Eth Benz
231,621
301,227
411,867
501,777
687,808
186,129
137,583
82,388
206,728
123,692
2,870,820
Aromatics Formaldeh
162,388
277,135
356,953
679,826
723,409
798,511
244,343
179,678
449,368
139,926
4,011,537
1,411,102
1,837,451
1,746,176
2,868,961
3,014,136
3,481,031
923,051
865,120
2,422,941
629,623
19,199,592
Acetaldeh Aldeh
49,580 28,945
88,371 43,927
210,780 59,670
392,474 199,568
452,399 88,477
370,831 158,497
174,703 37,233
190,449 38,435
218,516 132,590
99,842 28,951
2,247,947 816,293
Acetone
507,699
587,929
623,232
1,336,863
1,528,633
1,054,279
399,882
126,026
951,808
137,627
7,253,977
Ketones
261,771
333,884
411,091
881,286
1,080,721
566,651
323,485
75,275
353,087
89,578
4,376,829
Org. Acid
121,765
164,995
198,794
280,819
392,563
153,211
84,856
23,812
120,563
53,259
1,594,637
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, AREA SOURCES
sec
10101
10102
10103
10104
10105
10106
10201
10202
10203
10204
10206
10207
10208
10210
10211
10213
10214
10215
10217
10218
10220
10221
10301
10501
•| 10601
t— 10701
o 10801
1-1 11201
11301
11401
11402
11403
1K04
11501
11502
11503
11504
11 702
11703
11704
11705
11706
11711
11712
11713
11714,
11715
11716
11721
11722
11723
11724
S02
3.524
1,926
2,130
14.150
49
30
28
47
562
1,676
47
29
57
88
42
48
4,664
202
3.780
2,164
5.576
60,657
1,357
0
0
0
0
0
0
0
0
0
0
0
0
0
0
72
19
3.391
1,460
272
4,266
59.117
2.793
2
115
7,959
1,098
21,561
676
2
SO4
151
20
49
969
0
0
0
0
0
0
0
0
0
0
0
0
201
0
0
0
0
0
0
0
0
0
145
0
0
0
0
0
0
0
0
0
0
3
0
201
20
0
82
3,855
301
0
1
859
19
2,888
90
0
NO
67,580
46,451
46,634
284,366
294
312
45
150
5,806
35,515
285
37
82
674
51
332
106,195
195
4,311
16,108
1,658
11,405
26.112
143,302
17,015
0
0
0
0
0
0
0
0
0
0
0
0
114
28
549
9,065
3,852
257
24,089
2,756
1,042
18,273
1,269
189
6,1.21
;*2
85
N02
7,509
5,161
5,182
31,596
33
35
1
5
180
1,098
9
1
3
21
2
10
11.799
10
88
329
34
233
2,901
25.289
3.003
0
0
0
0
0
0
0
0
0
0
0
0
2
3
11
1,007
203
8
492
56
55
962
26
6
135
15
41
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
1,100,692
1,035,780
782,189
4,087,204
51,875
33,909
460
1,550
11,978
1,536
68,717
12,674
61,680
373
16.498
770
42,910
102.292
4,045
3,295
0
718
967,453
6,743,663
1,145,919
11,111
0
0
0
0
0
0
0
0
0
0
0
6
2
44
3,143
139
7,457
6,719
770
232
6,731
124
668
1.742
199
147
HCt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-- TONS/YEAR
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
12,646
0
0
147,983
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
169
1.310
144
0
0
22
0
0
0
0
TSP
6,089
4,904
3,680
33,616
272
963
21
66
330
762
110
21
113
93
29 .
125
8,030
0
1,452
862
127
4,169
1,803
6,322.187
225,073
5,556
7,852
0
11,245
1,820
526
6,931
100,888
60,835
7,025
110
1,483
9
2
250
904
23
- 1,477
3,328
378
29
576
687
904
703
82
139
CA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
MG
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
76.543
65,662
63,894
410,708
14,012
21,025
53
172
7,266
350
6,187
754
9,996
17
651
341
55,115
32,236
5,659
12,407
117
218
47,632
1,011,551
21,643
5,556
0
18,243
0
0
165,936
0
0
0
250
9
119
2
0
14
831
6
1.462
6,374
715
44
733
60
631
357
39
25
TKC
112,528
70,796
68,890
442,819
15,108
22,669
54
174
7,378
3i6
6,283
766
10,150
17
661
346
35.724
34,796
5,659
12,407
131
245
51,415
1,011,551
21,643
5,556
0
18.243
0
0
169,495
0
0
0
250
9
119
2
0
16
970
14
1,493
6.374
715
99
1,660
67
645
357
39
58
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, AREA SOURCES
sec |
11725
11726
11731
11732
11733
11734
11735
11736
11740
11801
12001
12002
12101
12102
12103
12104
12111
12112
12113
121U
12115
12116
12117
12121
12501
12502
12601
2602
12603
12604
12605
12606
12613
12614
12615
12623
12624
12625
12626
1264',
12642
126^3
12644
12701
12702
12703
'.2704
12705
12801
12802
12803
12901
S02
115
69,506
72,651
6,569
172
2
178
320,833
2,790
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
302
104
526
0
S04
8
6,249
1,166
704
17
0
13
26,967
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NO
17,858
12.100
10,729
2,914
216
858
39,772
54,760
5,562
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
72,524
2,086
7,302
542
0
2,575
192
.,96
0
N02
940
247
332
59
4
45
2,093
1,118
172
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3,817
110
384
29
0
454
34
70
0
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
6,580
1,177
5,556
762
55
228
10,467
5,334
428,957
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9,673
906
974
0
0
393,658
0
759
0
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
- TONS/YEAR --
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
28
83
0
TSP
562
6,546
28,024
312
23
81
897
29,673
96,093
0
43,307
6,019
970
23,289
466
9,317
13
123
300
3
240
149
160
30
9,370
3,318
9,778
248
8,043
1,737
3,802
2,308
17,199
3,425
10,946
3,027
1,836
1,541
1,009
919
2,896
1,147
227
0
0
0
24
0
33,311
125
929
0
CA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
MG
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
716
574
304
158
8
16
826
2,597
3,550
1,934
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
14,416
63
1,451
4
1,880
6,601
0
42
55,130
IHC
1,62i
645
311
Ii8
8
36
1,8/M
2,917
3,626
4,382
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
32,657
142
3,287
9
4,258
33,311
0
212
55,130
-------
1980 NAPAP 5.3 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, AREA SOURCES
>
I
sec
12902
12903
12904
12905
12906
12907
13001
13002
13101
13201
13202
13203
13204
13205
13701
13702
13703
13704
13705
13706
13901
13902
14001
14101
14102
14201
14202
14203
14204
14205
14401
14501
14601
14602
14603
14604
14701
14901
15101
15201
15202
CANADA
S02
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
o
0
0
0
0
0
0
36,201
657
0
0
0
0
0
0
6.144
3.990
24,640
12,359
0
0
0
0
0
763,375
S04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
181
0
0
0
0
0
0
0
565
365
1,322
1,136
0
0
0
0
0
48,547
NO
0
0
0
0
0
0
0
0
0
a
0
0
0
0
0
0
0
0
0
0
0
0
0
a
0
0
0
0
0
0
0
a
60,077
60,943
113,657
168,960
0
0
0
0
0
1,518,567
N02
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6,675
6,771
12.629
18,773
0
0
0
0
0
152,309
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Nit
CO
0
0
0
0
0
0
0
0
0
1,045
4,682
0
0
2
0
0
0
0
0
0
0
0
2,132
0
0
0
0
0
0
0
0
0
23,746
11,862
60,210
40,756
0
0
0
0
0
17,326,935
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
m
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
UK
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
162,384
TSP
0
0
0
0
0
0
0
0
0
2,749
2,945
2,276
1,120
4
1,294,970
71,945
3,270,672
3,866,796
311,669
13,284,702
4S6
1,935
5,329
0
0
1,609
7,382
143,020
61,615
4,381
3,762
29,441
9,133
2,264
11,439
13,364
0
63,786
0
157,366
822,512
30,641,093
CA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
a
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
MG
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
d
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
HA
0
0
0
0
u
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
MR
voc
26,538
3,317
35,068
5,055
30,013
2,843
81,760
74,060
31,456
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5,047
22,296
0
0
0
0
0
267
0
14,424
4,620
22,901
17.889
21,166
0
83,641
0
0
2,618,250
IHC
^6,538
3,317
35,068
5,055
30,013
2,843
81,760
74,060
2,019,013
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5,720
25.271
0
0
0
0
0
758
0
14,674
4,700
23,298
18,200
21,539
0
84 . 390
0
0
4,/29.547
-------
1980 HAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, AREA SOURCES
sec
10101
10102
10103
10104
10105
10106
10201
10202
10203
10204
10206
10207
10208
10210
10211
10213
10214
10215
10217
10218
10220
10221
a> 10301
| 10501
1— 10601
5 10701
10801
11201
11301
11401
11402
11403
11404
11501
11502
11503
11504
11702
11703
11704
11705
11706
11711
11712
11713
11714
11715
11716
11721
11722
11723
11724
| S02
3,197
1,747
1,932
12.837
44
27
25
43
510
1,520
43
26
52
80
38
44
4,231
183
3.429
1,963
5,058
55,027
1.231
0
0
0
0
0
0
0
0
0
0
0
0
0
0
65
17
3,076
1,324
247
3,870
53,630
2,534
2
104
7,220
996
19,560
613
2
S04
137
18
44
879
0
0
0
0
0
0
0
0
0
0
0
0
182
0
0
0
0
0
0
0
0
0
132
0
0
0
0
0
0
0
0
0
0
3
0
182
18
0
74
3,497
273
0
1
779
17
2,620
82
0
NO
61,308
42,139
42,306
257,972
267
283
40
136
5,267
32,218
259
33
75
612
47
301
96,338
177
3,911
14,613
1,504
10,347
23,688
130,001
15,436
0
0
0
0
0
0
0
0
0
0
0
0
103
25
498
8,223
3,495
233
21,854
2,500
945
16,577
1,151
172
6,006
6T
?12
N02
6,812
4,682
4,701
28,664
30
31
1
4
163
996
8
1
2
19
1
9
10,704
9
80
298
31
211
2,632
22,941
2.724
0
0
0
0
0
0
0
0
0
0
0
0
2
3
10
914
184
7
446
51
50
872
23
5
123
14
37
PB
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
998.531
939,644
709,590
3,707,849
47.060
30,762
417
1,406
10,866
1.393
62.339
11,498
55,955
338
14,967
699
38,927
92,798
3,670
2,989
0
651
877.659
6,117,748
1.039,560
10,080
0
0
0
0
0
0
0
0
0
0
0
5
2
40
2,851
126
6,765
6,095
699
210
6,106
112
606
1,580
181
133
HCI
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
METRIC TONS/YEAR
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 11
0
0
0 134
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 1
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
,472
0
0
,248
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
153
,188
131
0
0
20
0
0
0
0
TSP
5.524
4,449
3.338
30.496
247
874
19
60
299
691
100
19
103
84
26
113
7,285
0
1,317
782
115
3,782
1.636
5,735,392
204,183
5,040
7,123
0
10,201
1,651
477
6,288
91,524
55,189
6,373
100
1,345
8
2
227
820
21
1,340
3,019
343
26
523
623
820
638
74
126
CA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
MG
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
voc
69,439
59,568
57,964
3^2.588
12,712
19,074
48
156
6,592
318
5,613
684
9,069
15
591
309
31,856
29,244
5,133
11,255
106
198
43,211
917,664
19,634
5,040
0
16,550
0
0
150,534
0
0
0
227
a
108
2
0
13
754
6
1,326
5,782
649
40
665
54
573
324
35
23
THC
74,868
64,225
62,496
'.01,718
13.706
20,56b
49
158
6,693
323
5,699
69b
9,208
16
600
314
32,408
31,566
5,133
11,255
119
222
46,643
917,664
19,634
b,040
0
16,550
0
0
153,763
0
0
0
227
8
108
2
0
14
880
13
1,354
5,782
649
90
1,50o
61
585
324
35
5 2
-------
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-------
1980 IIAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, AREA SOURCES
>
H-
O
sec
12902
12901
12904
12905
12906
12907
13001
13002
13101
13201
13202
13203
13204
13205
13701
13702
13703
13704
13705
1370*
13901
13902
U001
14101
14102
14201
14202
14203
14204
14205
14401
14S01
14601
14602
14603
14604
14701
14901
15101
15201
15202
CANADA
| S02
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
32,141
596
0
0
0
0
0
0
5,574
3,620
22,353
11,212
0
0
0
0
0
692.522
SO4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
164
0
0
0
0
0
0
0
513
331
1,199
1,031
0
0
0
0
0
44,041
NO
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
54,501
55,286
103,107
153,278
0
0
0
0
0
1,377,621
N02
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6,056
6,143
11,456
17,031
0
0
0
0
0
138.172
PI
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
CO
0
0
0
0
0
0
0
0
0
948
4,247
0
0
2
0
0
0
0
0
0
0
0
1,914
0
0
0
0
0
0
0
0
0
21,542
10,761
54,622
36,973
0
0
0
0
0
15,718,731
NCI
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
METRIC TONS/TEAR -
NF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
o •
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR 147.
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
312
TSP
0
0
0
0
0
0
0
0
0
2.494
2,672
2,065
1,016
4
1,174,777
65,267
2,967,104
3,507,896
282,741
12.0S1.679
441
1,755
4,834
0
0
1,460
6,697
129,74*
55,896
3,974
3,413
26,708
8,285
2.054
10,377
12,124
0
57,866
0
142,760
746,170
27,797,132
CA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
MG
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
NA
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
voc
24,075
3,009
31,813
4,586
27,228
2,579
74,171
67.186
28.537
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4.578
20.227
0
0
0
0
0
242
0
13.085
4,191
20,775
16,229
19,202
0
75,878
0
0
2,375,236
IHC
24,075
3,009
31,813
4,586
?7,228
2,579
74.171
67,186
1,831,618
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5,189
22.925
0
0
0
0
0
688
0
13,312
4,264
21,136
16,511
19,540
0
76,557
0
0
4,290,573
NR -> Not Reported
-------
1980 NAPAP S.2 ENISSIONS INVENTORY - ANNUAL CANADIAN ENISSIONS Of HYDROCARBON SPECIES, AREA SOURCES
^-
o
SCC |
10101
10102
1010}
10104
10105
10106
10201
10202
10203
10204
10206
10207
10208
10210
10211
10213
10214
10215
10217
10218
10220
10221
10301
10501
10601
10701
10801
11201
11301
1U01
1U02
11403
1KM
11501
11502
11SOJ
11504
11702
11703
11704
11705
11706
11711
11712
11713
11714
11715
11716
11721
11722
11723
11724
METHANE
312,947
268,459
261,231
1,679,175
57,290
85,960
0
0
0
0
0
0
0
0
0
0
41,807
83,019
0
0
1,405
2,625
122,670
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
166
6,162
487
0
0
0
1,406
57.1*9
721
0
0
0
1,984
ETHANE
20,963
17.983
17,499
112,481
3,838
5,758
30
98
4,150
200
3,534
431
5.709
10
372
195
0
33,145
0
0
0
0
48,975
0
0
0
0
0
0
0
107,634
0
0
0
0
0
0
0
0
0
sit
0
948
0
0
0
. 0
0
410
0
0
0
PROPANE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2,721
5.965
0
0
0
394,593
8,443
2,167
0
0
0
0
61,505
0
0
0
0
0
0
1
0
0
0
13
542
3,065
344
89
1,491
0
iJ4
172
19
>2
BUTANE
80.108
68,720
66,870
429.837
14,665
22,004
0
0
0
0
0
0
0
0
0
0
0
0
20.996
46.034
493
922
0
302,827
6,479
1,663
0
0
0
0
26,140
0
0
0
0
0
0
7
0
58
0
22
230
23.650
2.654
151
2.530
253
99
1,324
145
88
ISO-BUTANE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7,084
15,532
0
0
0
302,827
6,479
1,663
0
0
0
0
0
0
0
0
0
0
0
2
0
0
0
0
0
7,980
896
0
0
0
0
447
49
0
- THOUSAND
PENTANE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6,519
14,294
0
0
0
238.591
5,105
1,310
0
0
0
0
0
0
0
0
0
0
0
2
0
0
0
12
0
7,344
824
81
1.355
0
0
411
45
47
HOLES/ YE AS -
I SO- PENTANE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
26. 140
0
0
0
0
0
0
0
0
0
0
0
230
0
0
0
0
0
99
0
0
0
AUANES
492.629
422.598
411,220
2,643,294
90,183
135.316
100
322
13,655
659
11,627
1,417
18,784
32
1,224
640
99,494
198,236
33,213
72,822
119
222
292,916
4,533,235
96,992
24,899
0
86,886
0
0
289,073
0
0
0
2,638
95
1.256
11
0
14
3.819
21
2,546
37,412
4.199
144
2,425
61
1,100
2.094
229
84
ETHTLENE
190,912
163,773
159,363
1,024,377
34,950
52,440
0
0
0
0
0
0
0
0
0
0
75.187
53,347
0
0
0
0
78,826
6,350,199
1 35,668
34,879
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9.002
0
0
0
0
0
0
0
0
0
0
0
PROPVLENE ISO
89,841
77,069
74,995
482,060
16.447
24,678
0
0
0
0
0
0
0
0
0 .
0
13.936
132,263
0
0
0
0
195.433
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3.617
0
0
0
0
0
0
0
0
0
0
0
BUTENE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5,509
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ALKENES
113,799
97,621
94,993
610,609
20.833
31.258
86
277
11.713
565
9.974
1,216
16,114
27
1,050
549
18,473
0
0
0
0
0
0
4.056,052
86,783
22.278
0
27,307
0
0
210,655
0
0
0
0
0
0
0
0
0
3,238
0
1,856
0
0
0
0
0
802
0
0
0
-------
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1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS OF HYDROCARBON SPECIES, AREA SOURCES
I
o
SCC | METHANE
13902
12903
12904
12905
12906
12907
13001
13002
13101
13201
13202
13203
13204
13205
13701
13702
13703
13704
13705
13706
13901
13902
14001
14101
14102
14201
14202
14203
14204
14205
14401
14501
14601
14602
14603
14604
14701
14901
15101
15201
15202
0
0
0
0
0
0
0
0
112,588,969
0
0
0
0
0
0
0
0
0
0
0
0
0
0
20,082
88,721
0
0
0
0
0
27.203
0
17,173
5,500
27,265
21,298
15,436
0
36,747
0
0
CANADA |119,043,212
ETHANE
0
0
0
0
0
0
0
0
54,948
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9,652
42,641
0
0
0
0
0
420
0
0
0
0
0
3,126
0
3,062
0
0
510,042
PROPANE
9,389
1.174
12,407
1,788
10,619
1,006
0
0
36.632
0
0
0
0
0
0
0
0
0
0
0
0
0
0
20,704
91,472
0
0
0
0
0
399
0
0
0
0
0
0
0
2,297
0
0
738,833
BUTANE
78,725
9,841
104,030
14.9V5
89,034
8,435
0
0
54,948
0
0
0
0
0
0
0
0
0
0
0
0
0
0
24,181
106,832
0
0
0
0
0
543
0
0
0
0
0
0
0
3,828
0
0
•1,875,523
I SO- BUTANE
26,242
3,280
34,677
4,998
29,678
2.812
0
0
36.632
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,349
5,961
0
0
0
0
0
509
0
0
0
0
0
0
0
18,374
0
0
564,017
-- THOUSAND MOLES/YEAR
PENTANE ISO-PENTANE
34,427
4.303
45,493
6,558
38,935
3,689
0
0
18,316
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10,482
46,309
0
0
0
0
0
261
0
0
0
0
0
0
0
4,593
0
0
600,425
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
27,077
AUANES
144,209
18.026
190,562
27,468
163,093
15,451
505,105
680,592
54,948
0
0
0
0
0
0
0
0
0
0
0
0
0
0
14,633
64.649
0
0
0
0
0
949
0
40,868
13.090
64,886
50,687
110,594
0
730,349
0
0
13,343,071
ETHYLENE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
378
0
30.751
9,849
48,823
38,139
42,596
0
2,297
0
0
8,555,420
PROPYLENE ISO-BUTENE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
234
0
5,724
1,833
9,088
7,099
17,390
0
0
0
0
1.170,561
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 .
0
0
0
0
0
0
0
0
0
0
0
0
0
2,263
725
3,593
2,807
0
0
0
0
0
14,897
ALKENES
28,168
3.521
37,222
5.365
31,856
3,018
44,503
0
54,948
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
261
0
7,588
2,430
12,047
9,411
22,471
0
34,450
0
0
5,799,402
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS OF HYDROCARBON SPECIES, AREA SOURCES
sec
10101
10102
10103
10104
10105
10106
10201
10202
10203
10204
10206
10207
10208
10210
10211
10213
102H
10215
10217
10218
10220
10221
10301
10501
10601
10701
10801
11201
11301
11401
1U02
1U03
11404
11501
11502
11503
11504
11702
11703
11704
11705
11706
11711
11712
11713
11714
11715
11716
11721
11722
11723
11724
BENZENE
26.952
23,121
22.498
144,618
4,934
7,403
4
14
602
29
513
63
829
1
54
28
0
10.733
0
0
0
0
15,859
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
889
7
0
0
0
50
843
0
0
0
0
29
TOLUENE
89,841
77,069
74,995
482,060
16,447
24,678
0
0
0
0
0
0
0
0
0
0
648
35,039
0
0
0
0
51,773
0
0
0
0
0
0
0
93,795
0
0
0
0
0
0
0
0
0
0
3,
826
0
0
22
361
0
357
0
0
13
XYLENE
19,466
16,698
16,249
104,446
3,563
5.347
70
224
9,505
458
8,093
986
13.075
22
852
446
0
11,680
0
0
0
0
17,258
0
0
0
0
0
0
0
693,469
0
0
0
0
0
0
0
0
0
0
0
6,108
0
0
0
0
0
2, 639
0
0
0
ETH BENZ
3,743
3,211
3,125
20,086
685
1,028
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
162,988
0
0
0
0
0
0
0
0
0
0
0
1,436
0
0
0
0
0
620
0
0
0
1 HUUiANU P
(ROMATICS
14,225
12,203
11,874
76,326
2,604
3,907
94
303
12,851
620
10,943
1.334
17,679
30
1,152
603
34,029
21,465
0
0
0
0
31,717
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ULfcb/TtAK - -
FORMALOEH
95,082
81,565
79,369
510,180
17,406
26,117
0
0
0
0
0
0
0
0
0
0
58,983
0
162,268
355,782
2,866
5.355
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
56
0
339
0
37
0
182,782
20,514
260
4,367
1,471
0
10,229
1,118
152
«:ETALDEH
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
115,050
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HLDEHYDES
0
0
0
0
0
0
192
618
26,171
1,262
22,285
2,716
36,003
61
2,346
1,227
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ACETONE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
988
1,846
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
117
0
0
0
0
0
0
0
507
0
0
0
0
KE10NES 08G
5,989
5,138
5,000
32,137
1,096
1,645
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ACIDS
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-------
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-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS OF HYDROCARBON SPECIES, AREA SOURCES
>
I
sec
12902
12903
12904
12905
12906
12907
13001
13002
13101
13201
13202
13203
13204
13205
13701
13702
13703
13704
13705
13706
13901
13902
K001
U101
14102
14201
14202
14203
14204
14205
14401
14501
14601
14602
14603
14604
14701
14901
15101
15201
15202
CANADA
| BENZENE
3.611
451
4,772
685
4,084
387
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
52
229
0
0
0
0
0
316
0
0
0
0
0
8,011
0
4,593
0
0
325.070
TOLUENE
6,500
813
8,590
1,238
7,351
696
31,894
38,968
18.316
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7
0
266
85
423
330
4,885
0
22,201
0
0
1,116,680
XYLENE
5.056
632
6,681
963
5,718
542
28,185
16,125
18.316
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,563
0
17,608
0
0
1,058,653
ETH BENZ
0
0
0
0
0
0
0
27,546
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5,359
0
0
233,614
-- THOUSAND
AROMATICS
3,370
421
4,454
642
3,812
361
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
14,111
4,520
22,404
17,501
2,931
0
2,297
0
0
337,784
MOLES/YEAR -
FORMALDEH
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
96
0
24,095
7,717
38,255
29,884
3,126
0
3,828
0
0
1,932,933
ACETALDEH
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
47,258
15,136
75,031
58,612
977
0
0
0
0
312,064
ALDEHYDES
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
586
0
0
0
0
93,467
ACETONE
0
0
0
0
0
0
127.574
36,952
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
72,492
0
45,168
0
0
348,381
KETONES
0
0
0
0
0
0
140,183
61,811
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3,517
0
49,762
0
0
306.279
ORG ACIDS
0
0
0
0
0
0
0
14,781
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,759
0
8,421
0
0
24,961
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY • ANNUAL CANADIAN EMISSIONS, AREA SOURCES
Provirxre
Alberta
British Cotunb.
Manitoba
New Brunswick
Hey found! and
Nova Scotia
Ontario
Prince Edward
Quebec
Saskatchewan
Canada
>
1
»>
.0
Province
Alberta
British Coturob.
Manitoba
New Brunswick
Newfoundland
Nova Scotia
Ontario
Prince Edward
Quebec
Saskatchewan
Canada
S02
51,910
42,554
9,944
53,511
40,452
41,146
162,161
2,782
345,737
13,178
763,375
S02
47,092
38.604
9,021
48,544
36,697
37,327
147.110
Z.524
313.647
11,955
692,522
S04
1,291
3,123
531
4,302
3,217
3,230
8,702
214
23,244
693
48,547
S04
1.171
2.833
482
3,903
2,918
2,930
7,894
194
21,087
629
44,041
NO
329,384
183,224
88.718
33,795
31,087
43,042
387,719
5,146
275,049
141,404
1,518,567
NO
298.812
166,218
80,483
30,659
28,201
39,047
351,732
4,668
249,520
128, 279 •
1,377,621
N02
32,408
19,285
10,693
3,038
2,665
4,043
37,554
496
23,563
18,564
152,309
N02
29,400
17,495
9,701
2,756
2,418
3.667
34,069
450
21,376
16,841
138,172
PB
0
0
0
0
0
0
0
0
0
0
NR
PB
0
0
0
0
0
0
0
0
0
0
NR
CO
3,005,269
2,035,935
1,599,921
341,763
197,060
378,427
4,108,803
57,909
2,236,111
3,365,737
17,326.935
CO
2,726,334
1,846,969
1,451,424
310,042
178,770
343,303
3,727,443
52,534
2,028,566
3,053,345
15.718,731
TONS/YEAR
HCL HF
0
0
0
0
0
0
0
0
0
0
NR
HCL
0
0
0
0
0
0
0
0
0
0
NR
0
0
0
0
0
0
0
0
0
0
NR
HF
0
0
0
0
0
0
0
0
0
0
NR
NH3
53,080
6,518
19,455
939
123
1,276
32,758
832
15,650
31,752
162,384
NH3
48,153
5,913
17,649
852
112
1,158
29,718
755
14,197
28,805
147,312
TSP
8,767,433
1,932,312
3,113,425
386,395
192,773
708,372
6.401,794
41,462
2,242,053
6.855,074
30,641,093
TSP
7,953,682
1.752,964
2,824,452
350.532
174,881
642,624
5,807,610
37,614
2,033,956
6,218,819
27,797,132
CA
0
0
0
0
0
0
0
0
0
0
NR
CA
0
0
0
0
0
0
0
0
0
0
NR
MG
0
0
0
0
0
0
0
0
0
0
NR
MG
0
0
0
0
0
0
0
0
0
0
NR
NA
0
0
0
0
0
0
0
0
0
0
NR
NA
0
0
0
0
0
0
0
0
0
0
NR
K
0
0
0
0
0
0
0
0
0
0
NR
K
0
0
0
0
0
0
0
0
0
0
NR
voc
537,586
260,165
225,491
42,010
26.V81
63,195
637,371
6,492
322,901
496,059
2,618,250
VOC
487,690
236,018
204,562
38,111
24,477
57.329
578,213
5,889
292,930
450,017
2,375,236
THC
741,839
502,632
316,540
103,832
76,696
137,842
1,378,759
17,192
872,031
582,184
4,729,547
THC
672,985
455,980
287,160
94,195
69,577
125,049
1,250,789
15,596
791,093
528,148
4,290,573
Not Reported
-------
1980 BAPAP 5 2 ENISSIONS INVENTC*r - ANNUAL CANADIAN EMISSIONS OF HrOROCARBON SPECIES. AP.EA SOURCES
Alberta | 11.489.078
Brit. Col.
Manitoba
New Brun.
Neatound.
Nova Scot
Ontario
Prince Ed
Quebec
Saskatch.
13.608.791
5.131.680
3.481,796
2,809,355
4,194,542
41,884,678
604,043
31,035,854
4,803.395
Canada J119.043.212
121.271
85.76B
20.986
15.270
7.039
23.557
111.814
1,756
74.960
47.622
510,042
257.014
51.618
67.034
15,089
3,696
16.76,
108,479
669
40,628
177.840
738,833 1
392. 120
189.119
104,871
52,030
29,666
61,304
510,048
6,853
332,541
196.972
875,523
109.219
38,813
56,023
8,918
6,047
9,565
137,337
1,302
69.163
127,630
564,017
163,149
39,608
47,061
13.871
6,370
13,147
134,651
1,382
72,394
108.791
600,425
11.367
8,916
93
257
48
2,292
163
28
248
3,664
27,077
2.365,672
1.268.775
1,106,019
235.484
160,549
317,359
3,627,363
39,327
1,956,759
2,265,764
13.343,071
THOUSAND HOLES/rEAR
ISO BUTENE
1,966.254
455,380
1,107,275
65,434
42,847
80,954
1,705,607
10,093
520,891
2,600,684
8.555.420 1
140.614
156.334
73.814
30.142
20,811
37,289
370,022
5.517
233.036
102,982
170.561
3,606
2,105
1.122
305
273
440
3,528
46
2,126
1,345
14,897
1.347.453
370.995
703,885
49,050
30,369
74,844
1.157,829
7,379
378,410
1.679,188
5,799,402
57,075
40,868
15,945
8,075
5,518
10,808
100,810
1,449
65,440
19,082
325.070
167.838
157,447
53,239
27,531
18,777
44,774
343,631
5,074
221,808
76.561
1,116,680 1
339.491
281.081
18.971
16.280
7.577
71.677
123.157
2.302
81,390
116,728
058,653
77.893
63.336
3,593
3,403
1.672
16.708
23.301
504
17,256
25,948
233.614
52.867
47.613
21.103
9.310
6,262
10,030
100.300
1,414
61.611
27,275
337.784
252.821
222.541
59.227
49.909
57.082
67.152
602.966
8,195
546.117
66.923
1 932.933
75,355 14,442
44,046 19,892
23,473 4.052
6.381 4.249
5.697 2.107
9.207 1.578
74,190 26.972
967 300
44,642 15,814
28,105 4.061
312,064 93,467
16.534
56.212
8.514
7.234
4,526
6,900
148.457
675
92,755
6.574
348.381
20. 3«
35,850
9.589
5.738
4,344
7.445
135.421
1.034
77.223
9.256
306.279
2 <-•>
2.7*6
1.644
633
5,3
831
9.158
IU
6.591
«!
24.911
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, POINT SOURCES
6-OIGIT SCC | S02
101002
10100}
101004
101005
101006
102002
102004
102006
102008
102014
105001
201001
201002
301003
301005
301013
3010U
301017
301016
301019
301021
301023
301026
301027
30102*
301029
301030
301035
301040
301130
301132
301157
301174
301250
301258
301030
303000
303001
303002
303003
303004
303005
303006
30300*
303009
303010
303013
303023
303024
303030
3030M
303999
447,467
3,320
145,392
27.J58
5,991
1,234
146,057
3,032
0
59,271
0
214,533
5
0
1,842
0
2S4
0
0
0
0
17,520
0
0
0
0
0
2,920
0
0
0
0
0
0
0
0
0
14,052
0
10,140
0
1,680,647
13,440
190,845
3,010
33,359
16.696
221
0
4,577
0
9,120
S04
8,485
46
8,077
1,086
0
99
4,531
258
0
190
0
33
0
0
0
0
2
0
0
0
0
862
0
0
0
0
0
14
0
0
0
0
0
0
0
0
0
71
0
830
0
31,882
2,359
528
26
1,195
0
0
0
176
0
45
NO
132,194
844
22,660
5,010
11,956
0
17,212
11,506
0
2.569
3
49,249
1.576
0
0
7,209
0
0
0
0
0
0
0
178
0
0
0
0
0
0
0
0
0
0
0
0
0
8,068
0
5
0
0
0
0
19
0
0
0
0
0
0
0
N02
4,088
26
462
102
629
0
351
606
0
453
0
5,472
101
0
0
379
0
0
0
0
0
0
0
9
0
0
0
0
0
0
0
0
0
0
0
0
0
425
0
0
0
0
0
0
1
0
0
0
0
0
0
0
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
15,061
251
1,709
317
420
0
1,050
496
0
0
0
23
93
0
123.494
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
775
28
0
25,453
27,713
43,587
0
0
37,547
0
0
0
0
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
IUN3/TCAK-
HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
29,636
0
0
0
0
0
0
1.482
0
0
499
0
0
0
0
10,795
0
0
0
0
0
0
0
0
0
0
560
0
0
0
0
72
0
0
0
0
0
0
0
TSP
116,032
12,215
1 1 , 744
62
428
0
13,968
853
0
13,826
0
8,483
75
0
17
0
78
409
0
0
1,058
0
0
1,636
320
255
1,791
84
5,446
6
0
0
0
0
0
41
4
10,328
3,668
22,145
512
33,957
28,413
35.954
44,043
3.351
229
167,296
247
4,490
31.948
3,833
C»
1,880
198
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
301
1,431
0
0
0
820
0
0
0
0
Mg
1,984
209
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
412
597
0
0
0
402
0
0
0
0
N>
951
100
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
384
626
0
0
0
0
0
0
0
0
1C
511
54
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
. 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2,024
0
0
0
0
0
0
0
0
voc
4,498
71
499
146
12
0
212
119
0
0
0
2
3
115,309
66
0
0
0
50.439
81
0
0
9.042
0
0
0
0
0
0
0
1,458
1,655
2.470
7,078
8.S04
0
0
0
0
672
21
0
0
0
381
0
0
0
0
0
0
0
THC
4.595
73
560
146
27
0
238
271
0
0
0
2
10
115,309
66
0
0
0
50,708
413
0
0
9,042
0
0
0
0
0
0
0
1.484
1,685
2,514
7,078
8,504
0
0
0
0
1.438
46
0
0
0
429
0
0
0
0
0
0
0
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY • ANNUAL CANADIAN EMISSIONS, POINT SOURCES
6-DIGIT SCC S02
. ....*„ _-__._
304001
304006
304010
305005
305006
305007
305010
3050U
305015
305016
305019
305020
305021
305022
305025
305031
305032
305040
306001
306002
306006
306008
306012
306014
306888
307001
307002
310002
310004
310888
403001
501001
501002
501005
503001
503005
503007
29,650
0
571,740
0
0
0
0
0
0
0
1,288
0
0
0
0
0
0
0
51.645
35.655
68
0
33
704
10,785
29,755
73,097
446,224
277
1,851
0
1,201
98
7
11,757
1,077
12,552
CANADA 4,331,797
S04
232
0
7.889
0
496
4
0
0
5,594
6
0
0
0
0
0
0
0
0
5,760
461
6
0
2
3
54
34,263
923
2,135
0
9
0
0
0
0
34
0
57
118,723
NO
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
21,434
5,482
88
0
43
52
0
14,524
0
43.411
3.391
0
0
1,181
7
8
0
275
0
360,149
N02
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
782
967
15
0
8
3
0
764
0
2,285
178
0
0
208
1
1
0
48
0
18,368
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
CO
106,787
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,627
191,381
8
0
3
58
0
57,965
0
5,784
7
0
0
16,477
674
0
0
0
0
658,788
IONS/YEAR
HCl HF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4,021
0
0
0
6
0
0
0
0
0
0
0
188
17
0
0
15
0
47,290
TSP
19,738
77
16,933
625
15,325
131
5,536
1,102
8,771
22,090
15,896
1.059
8.734
16,177
1,254
29,948
15,257
10,841
4,222
9,593
30
0
294
919
0
80,065
1,008
2
112
0
0
. 1,869
326
34
0
286
0
867,499
Ca
0
18
0
0
4.368
0
0
0
0
7,486
0
61
0
0
8
0
0
0
0
0
0
0
0
0
0
96
0
0
0
0
0
11
2
0
0
0
0
16,680
Mg
0
11
0
0
120
0
0
0
0
1,107
0
18
0
0
9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
0
0
0
0
0
4,870
Na
0
0
0
0
0
0
0
0
0
110
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,105
0
0
0
0
0
11
2
0
0
0
0
3,289
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9
2
0
0
0
0
2.599
voc
882
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
291
23,221
1
75,374
1
46
0
10,879
0
15,368
62
0
44,626
136
8
0
0
14
0
373,649
THC
1.393
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
384
36,280
2
79,023
2
104
0
11,962
0
20,455
87
0
50,597
693
8
2
0
81
0
405,710
NR - NOT REPORTED
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, POINT SOURCES
I
H-
•xl
6-DIGIT SCC | S02
101002
101003
101004
101005
101006
102002
102004
102006
102008
1020U
105001
201001
201002
501003
301005
3010)3
3010U
301017
301018
301019;
301021
301023
301026
301027
301028
301029
301030
301035
301040
301130
301132
301157
301174
3012SO
301258
301330
303000
303001
303002
303003
303004
303005
303006
303008
303009
303010
303013
303023
303024
303030
303888
303999
405,943
3,012
131,900
24,819
5,435
1,119
132,503
2,751
0
53,771
0
194,625
5
0
1,671
0
258
0
0
0
0
15,894
0
0
0
0
0
2,649
0
0
0
0
0
0
0
0
0
12,748
0
9,199
0
1,524,687
12.193
173,135
2,731
30.263
15,147
200
0
4.152
0
8.274
S04
7,698
42
7,327
985
0
90
4,111
234
0
172
0
30
0
0
0
0
2
0
0
0
0
782
0
0
0
0
0
13
0
0
0
0
0
0
0
0
0
64
0
753
0
28,923
2,140
479
24
1,084
0
0
0
160
0
41
NO
119,926
766
20,557
4,545
10,846
0
15,615
10,439
0
2,330
3
44,679
1,430
0
0
6,540
0
0
0
0
0
0
0
161
0
0
0
0
0
0
0
0
0
0
0
0
0
7,320
0
4
0
0
0
0
17
0
0
0
0
0
0
0
N02
3,709
24
420
93
571
0
319
549
0
411
0
4,964
91
0
0
344
0
0
0
0
0
0
0
8
0
0
0
0
0
0
0
0
0
0
0
0
0
385
0
0
0
0
0
0
1
0
0
0
0
0
0
0
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
CO
13,663
228
1,550
288
381
0
953
450
0
0
0
21
84
0
112,034
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
703
25
0
23.091
25,141
39,542
0
0
34,063
0
0
0
0
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
MtlKIL lUNb/YfcAK--
HF NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
26,886
0
0
0
0
0
0
1,344
0
0
453
0
0
0
0
9,793
0
0
0
0
0
0
0
0
0
0
508
0
0
0
0
65
0
0
0
0
0
0
0
ISP
105.264
11,081
10,654
56
388
0
12,672
774
0
12.543
0
7,696
68
0
15
0
71
371
0
0
960
0
0
1,484
290
231
1.625
76
4,941
5
0
0
0
0
0
37
4
9,370
3,328
20,090
464
30,806
25,776
32.618
39.956
3,040
208
151,771
224
4,073
28,983
3,477
Ca
1,705
180
0
0
0
0
' 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
273
1,298
0
0
0
744
0
0
0
0
Hg
1,800
189
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
374
541
0
0
0
364
0
0
0
0
Na
863
91
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
348
568
0
0
0
0
0
0
0
0
K
463
49
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
rt
0
0
0
0
0
0
0
0
0
1,836
0
0
0
0
0
0
0
0
voc
4,081
65
452
133
11
0
192
108
0
0
0
2
3
104,608
60
0
0
0
45,759
73
0
0
8,203
0
0
0
0
0
0
0
1,323
1,502
2,241
6,421
7, '15
0
0
0
0
609
19
0
0
0
346
0
0
0
0
0
0
0
THC
4,169
66
508
133
25
0
216
246
0
0
0
2
9
104,608
60
0
0
0
46,002
375
0
0
8,203
0
0
0
0
0
0
0
1,346
1,528
2,281
6,421
7,715
0
0
0
0
1,305
42
0
0
0
389
0
0
0
0
0
0
0
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, POINT SOURCES
>
I
00
6-DIGII SCC | S02
304001
304006
304010
305005
305006
305007
305010
305014
305015
305016
305019
305020
305021
305022
305025
305031
305032
305040
306001
306002
306006
306008
306012
3060U
306888
307001
307002
310002
310004
310888
403001
501001
501002
501005
503001
503005
503007
26,899
0
518,684
0
0
0
0
0
0
0
1,168
0
0
0
0
0
0
0
46,852
32.346
62
0
30
639
9,784
26,994
66,314
404.815
251
1,679
0
1,090
89
6
10,666
977
11.387
CANADA | 3,929.816
S04
210
0
7,157
0
450
4
0
0
5,075
5
0
0
0
0
0
0
0
0
5,225
4ie
5
0
2
3
49
31.083
837
1,937
0
8
0
0
0
0
31
0
52
107,706
NO
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
19,445
4,973
79
0
39
47
0
13,176
0
39,383
3,076
0
0
1,071
6
7
0
249
0
326,728
N02
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
709
878
14
0
7
2
0
693
0
2,073
162
0
0
189
1
1
0
44
0
16.663
Pb
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
CO
96,877
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,476
173,621
7
0
3
53
0
52,586
0
5,247
6
0
0
14.948
611
0
0
0
0
597.654
HCl
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
MMKIC IUNS/TtAK--
HF NH3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3,648
0
0
0
5
0
0
0
0
0
0
0
171
15
0
0
14
0
42,902
TSP
17,906
70
15,362
567
13,903
119
5,022
1,000
7,957
20,040
14,421
961
7,924
14,676
1,138
27,169
13,841
9,835
3,830
8,703
27
0
267
834
0
72,635
914
2
102
0
0
1,696
296
31
0
259
0
786,997
Ca
0
17
0
0
3,962
0
0
0
0
6,792
0
55
0
0
7
0
0
0
0
0
0
0
0
0
0
87
0
0
0
0
0
10
2
0
0
0
0
15,132
Mg
0
10
0
0
108
0
0
0
0
1,004
0
16
0
0
8
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2
0
0
0
0
0
4,418
Na
0
0
0
0
0
0
0
0
0 •
100
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,002
0
0
0
0
0
10
2
0
0
0
0
2,983
K
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8
1
0
0
0
0
2,358
voc
800
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
264
21,067
1
68,380
1
42
0
9,869
0
13.942
56
0
40,485
123
7
0
0
12
0
338,975
THC
1,264
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
348
32,913
2
71,690
2
95
0
10,852
0
18,557
79
0
45,902
629
7
2
0
73
0
368,061
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
I
H-
I—1
vO
6-DIG1T SCC
101002
101003
101004
101005
101006
102003
102004
102006
102008
102014
105001
201001
201002
301003
301005
301013
301 OK
301017
301018
301019
301021
301023
301026
301027
301028
301029
301030
301035
301040
301130
301132
301157
301174
301250
301258
301830
303000
303001
303002
303003
303004
303005
303006
303008
303009
303010
303013
303023
303024
303030
303888
303999
304001
304006
METHANE
0
0
3,487
0
861
0
1.481
8,573
0
0
0
13
396
0
0
0
0
0
11,004
18,689
0
0
0
0
0
0
0
0
0
0
1,063
1,207
1,802
0
0
0
0
0
0
36.841
1,178
0
0
0
2,693
0
0
0
0
0
0
0
28,919
0
ETHANE
2,918
46
0
0
0
0
0
0
0
0
0
2
0
0
0
0
0
0
2,229
49
0
0
0
0
0
0
0
0
0
0
215
245
365
0
0
0
0
0
0
3,470
111
0
0
0
0
0
0
0
0
0
0
0
0
0
PROPANE
1,667
26
0
36
22
0
0
223
0
0
0
0
0
0
0
0
0
0
0
75
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
144
5
0
0
0
3,522
0
0
0
0
0
0
0
607
0
BUTANE
709
11
1,225
279
38
0
520
381
0
0
0
0
0
0
0
0
0
0
0
142
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,656
0
[SO- BUTANE
0
0
0
94
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
26
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
265
0
THOUSAND
PENTANE
0
0
0
86
20
0
0
204
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
720
0
MOLES/YEAR-
ISO-PENTANE
709
11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ALKANES
7,837
125
295
440
36
0
125
363
0
0
0
8
0
591,036
338
0
0
0
78,419
633
0
0
85,392
0
0
0
0
0
0
0
7,579
8,604
12,839
200,404
0
0
0
0
0
600
19
0
0
0
2,047
0
0
0
0
0
0
0
3,893
0
ETHYLENE
0
0
0
0
0
0
0
0
0
0
0
19
0
805,482
461
0
0
0
30,226
0
0
0
0
0
0
0
0
0
0
0
2,921
3,316
4,949
0
0
0
0
0
0
12,889
412
0
0
0
0
0
0
0
0
0
0
0
0
0
PROPYIENE
0
0
0
0
0
0
0
0
0
0
0
7
0
223,861
128
0
0
0
528,813
277
0
0
0
0
0
0
0
0
0
0
1,198
1,360
2,030
0
0
0
0
0
0
587
19
0
0
0
0
0
0
0
0
0
0
0
0
0
ISO-8UTENE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
AUEMES
5,711
91
0
0
0
0
0
0
0
0
0
7
0
318,009
182
0
0
0
181,294
0
0
0
0
0
0
0
0
0
0
0
1,535
1,742
2,600
0
0
0
0
0
0
U4
5
0
0
0
0
0
0
0
0
0
0
0
0
0
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS OF HYDROCARBON SPECIES. POINT SOURCES
>
I
6-DIGIT SCC METHANE
304010
305005
305006
305007
305010
305014
305015
305016
305019
305020
305021
305022
305025
305031
305032
305040
306001
306002
306006
306008
306012
306014
306888
307001
307002
310002
310004
310888
403001
501001
501002
501005
503001
503005
503007
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5,265
738,573
42
129,758
42
3,305
0
61,248
0
76.748
372
0
177,639
31.177
0
91
J
3.683
0
CANADA 1,346,149
ETHANE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
40,863
0
0
0
0
0
112,532
546
0
85,377
176
0
2
0
66
0
249,211
PROPANE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
93
0
0
96,064
0
86
0
1,597
0
69.462
337
0
183,147
107
3
0
0
0
0
357,224
BUTANE ISO-BUTANE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
751
0
0
176,357
0
147
0
2,719
0
64,281
312
0
213,901
195
2
0
0
0
0
463,625
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
55,201
0
0
0
0
0
12,306
60
0
11,934
38
2
0
0
0
0
79,927
1 tlUU^ANU NULta/TtAK-
PENTANE ISO-PENTANE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
85
0
0
119,005
0
79
0
1,456
0
0
0
0
92,721
0
2
0
0
0
0
214,379
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
720
ALKANES ETHYLENE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
294
49,699
3
457,380
3
140
0
108,399
0
13,363
0
0
129,443
868
36
0
0
0
0
1,760,662
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
18,211
0
0
0
402
50
6
0
228
0
879,572
PROPYLENE ISO-BUTENE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
72,418
327
0
0
390
0
0
0
9
0
831,425
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
m
ALKENES
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7,190
0
0
0
13
32
0
0
0
0
518,552
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY • ANNUAL CANADIAN EMISSIONS OF HYDROCARBON SPECIES, POINT SOURCES
6-DIGIT SCC | BENZENE
101002
101003
101004
101005
101006
102002
102004
102006
102008
102014
105001
201001
201002
301003
301005
301013
3010K
301017
J01018
501019
301021
301023
301026
301027
301028
301029
301030
301035
301040
301130
301132
301157
301174
301250
301258
301830
303000
303001
303002
303003
303004
303005
303006
303008
303009
303010
303013
303023
303024
303030
303888
303999
304001
304006
0
0
0
0
13
0
0
128
0
0
0
2
0
133,898
77
0
0
0
5,711
0
0
0
2,953
0
0
0
0
0
0
0
552
627
935
0
48,051
0
0
0
0
2,348
75
0
0
0
0
0
0
0
0
0
0
0
291
0
TOLUENE
2,543
40
b
0
5
0
0
54
0
0
0
0
0
46,028
26
0
0
0
3,482
0
0
0
328
0
0
0
0
0
0
0
337
382
570
0
0
0
0
0
0
104
3
0
0
0
0
0
0
0
0
0
0
0
126
0
XYLENE
18,800
299
0
0
0
0
0
0
0
0
0
0
0
12,553
7
0
0
0
1,114
0
0
0
0
0
0
0
0
0
0
0
108
122
182
0
37,311
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ETH BENZ
4.419
70
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
MUUbANO ML
AROMA TICS
0
0
0
0
0
0
0
0
0
0
0
0
0
56,488
32
0
0
0
2,089
0
0
0
0
0
0
0
0
0
0
0
202
229
342
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Lti/YtAK-
FORHALDEH
0
0
7,106
2.151
66
0
3,017
656
0
0
0
0
91
59,627
34
0
0
0
2,229
0
0
0
0
0
0
0
0
0
0
0
215
245
365
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7,558
0
ACETALDEH
0
0
0
0
0
0
0
0
0
0
0
0
0
16,737
10
0
0
0
696
0
0
0
0
0
0
0
0
0
0
0
67
76
114
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ALDEHYDES
0
0
0
0
0
0
0
0
0
0
0
0
0
11,507
7
0
0
0
418
0
0
0
0
0
0
0
0
0
0
0
40
46
68
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ACETONE
0
0
2,450
0
0
0
1,040
0
0
0
0
0
0
0
0
0
0
0
51,397
555
0
0
0
0
0
0
0
0
0
0
4,967
5,639
8,415
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
KETONES
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2,507
0
0
0
0
0
0
0
0
0
0
0
242
275
410
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ORG ACIDS
0
0
0
0
0
0
0
0
0
0
0
0
0
6,276
4
0
0
0
1,254
0
0
0
0
0
0
0
0
0
0
0
121
138
205
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
A-12L
-------
1980 KAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS Of HYOftCCARRON SPECIES. POINT SOURCES
6-DIGIT SCC | BENZENE
304010
305005
305006
305007
305010
3050 U
305015
305016
305019
305020
305021
305022
305025
305031
305032
305040
306001
306002
306006
306008
106012
3060U
306888
30/001
307002
310002
310004
310888
403001
501001
501002
501005
503001
503005
503007
0
0
0
0
0
0
0
0
0
0
0
a
a
0
a
0
53
0
0
22,224
0
49
0
912
0
3,027
0
0
459
119
0
2
0
71
0
CANADA | 222,579
TOLUENE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
23
0
0
0
0
21
0
386
0
1,041
0
0
0
0
0
0
0
0
0
55,500
THOUSAND HOLES/TEAR
XYLENE ETH BENZ AROMA] I CS FOftNALDEH ACETALDEH ALDEHYDES
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
284
0
0
0
0
0
0
0
0
0
70.781
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4,489
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,277
0
0
0
0
0
0
0
0
0
60.660
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3,707
558,867
11
o •
31
251
0
4,684
0
42,113
199
0
0
0
0
a
0
0
0
693,444
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
178
0
0
0
0
0
0
0
0
0
18,079
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
260
0
0
0
0
0
0
0
0
0
12,346
ACETONE KE TONES 080 ACIDS
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,184
0
0
0
0
0
0
0
0
0
0
0
0
742
0
0
0
0
0
76.390
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3.435
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
142
0
0
0
0
0
0
0
0
0
8,140
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
A-122
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, POINT SOURCES
Province
Alberta
British Columbia
Manitoba
New Brunswick
Newfoundland
Nova Scotia
Ontario
Prince Edward
Quebec
Saskatchewan
Canada
Province
Alberta
British Columbia
Manitoba
Mew Brunswick
Newfoundland
Nova Scotia
Ontario
Prince Edward
Quebec
Saskatchewan
Canada
S02
608,878
128,086
523,255
169,542
25,183
171,197
1,791,964
2,191
864,554
46,947
4,331,797
S02
552,375
116,200
474,698
153,809
22,846
155,310
1.625,674
1,988
784,325
42,590
3,929,816
S04
6,386
10,780
13,259
10,661
1,387
7,864
37,245
129
27,455
3,557
118,723
S04
5,793
9,780
12,029
9,672
1,258
7,134
33,789
117
24,907
3,227
107,706
NO
118.267
13,892
2,864
21,325
2,134
35,332
130,014
478
22,166
' 13,678
360,149
NO
107,292
12,605
2,598
19,346
1,936
32,053
117,949
434
20,109
12,409
326,728
N02
5,505
775
117
602
44
1,059
8,462
10
1,222
571
18.368
M02
4,994
70J
107
546
40
961
7,677
9
1,109
518
16,663
Pb
0
0
0
0
0
0
0
0
0
0
NR
Pb
0
0
0
0
0
0
0
0
0
0
m
CO
18,417
117,778
3,589
6,202
263
15,358
315,383
38
173,600
8,160
658,788
CO
16,708
106,848
3,256
5,626
239
13.933
286.116
34
157,490
7,403
597,654
HCI
0
0
0
0
0
0
0
0
0
0
NR
HCI
0
0
0
0
0
0
0
0
0
0
KR
Hf NH3
0
0
0
0
0
0
0
0
0
0
NR
HF
0
0
0
0
0
0
0
0
0
0
m
30,243
494
1,556
85
0
369
13,501
0
915
127
47,290
NH3
27,437
448
1.412
77
0
335
12,248
0
830
115
42,902
TSP
60,708
34,777
28,794
29,354
87,892
54,647
202,588
167
242,884
125,688
867,499
ISP
55,074
31,550
26,122
26,630
79,736
49,576
183,788
152
220,345
114,024
786,997
Ca
709
1,354
602
743
508
483
6,461
0
3,883
1,936
16,680
Ca
643
1,228
547
674
460
438
5,861
0
3,523
1,757
15, 1JZ
Mg
249
159
153
233
178
250
1,265
0
761
1,623
4,870
Mg
226
145
139
211
161
227
1,147
0
690
1.472
4.418
Ka
1S2
266
55
232
1
238
838
0
687
821
3,289
Na
138
241
50
211
1
216
760
0
623
745
2.98J
K
66
19
28
53
0
389
1,350
0
282
412
2,599
K
60
17
25
48
0
353
1,225
0
255
374
2,158
VOC
148,126
22,902
8.190
9,001
1,967
10,470
95,879
9
67,207
9,898
373,648
VOC
134,380
20,776
7,430
8,165
1,784
9,498
86,982
8
60.971
8,979
338.975
THC
157,123
25,792
8,551
10,177
2,196
12,102
103,998
10
74,462
11,299
405,710
THC
142,542
23,398
7,757
9,232
1,992
10,979
94,347
9
67,552
10,250
368,061
NR = NOT REPORTED
-------
1980 NAPAP 5.2 EMISSIONS INVEUTODV - ANNUAL CANADIAN EMISSIONS OF HrDBOCABBC* SPECIES, POINT SOURCES
;>
1
^"
Alberta
Brit. Cot.
Manitoba
Hew Brun.
Newfound.
Nova Scot
Ontario
Prince Ed
Quebec
Saskatch.
Canada
278.610
135.346
11.626
59,116
7,182
76,375
403,452
64
321,193
53,186
1,346,149
122,828
14,996
4,667
3,943
3,077
8.524
29,735
0
47,550
13,891
249,211
96,447
26,671
10,148
9,228
6,645
18,654
57,364
0
102.926
29,141
357,224
105,390
35.829
13.023
16,801
8,286
25,273
82,695
23
141,208
35,099
463,625
20,516
5,872
1,540
4,572
687
4,086
17,802
0
21,877
2,976
79,927
25.163
17,887
6,409
10,444
3,729
13,234
47,290
0
74,086
16,136
214,379
266
0
7
9
0
38
275
0
0
125
720
787,472
124,507
39,424
50,561
6,763
44,682
408.362
5
264,299
34,585
1.760,662
645,732
40,292
31,864
0
0
1,004
144,366
0
15,224
1,090
879,572
THOUSAND HOIES/1EA8
273,317
13.831
8,856
0
0
8,107
361,419
0
165.741
155
831.425
0 353,366
0 15,832
0 12,636
0 71
0 0
0 316
0 117,323
0 0
0 17,828
0 1 , 182
M 518,552
111,192
8,880
5,735
1.893
131
1,630
64,880
0
27,400
838
222,579
39,218
2.453
1,853
66
0
166
9,309
0
1,926
509
55,500
17,567
1,189
681
233
0
1,002
31,355
0
15,404
3,329
70, 781
1,657
0
43
55
0
236
1,717
0
0
781
4,489
4.5,263
2.812
2,235
0
0
0
9,288
0
1,034
29
60,660
202,301
67,570
2.511
34.812
1,115
42,694
205,320
131
122,475
14.016
693,444
li.ttB
833
662
0
0
0
2,763
0
J45
9
18,079
9 ,?H
455
0
1 091
0
207
6
12, 146
37 898
75
76,390
31?
*
0 I
3,4ib 8.1.1,
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN EMISSIONS, AREA & POINT SOURCES
>
I
Province |
Alberta |
British Coluntola|
Manitoba |
New Brunswick |
Newfoundland |
Nova Scotia |
Ontario |
Prince Edward |
Quebec |
Saskatchewan |
Canada |
Province |
Alberta )
British Columbia)
Hani toba |
New Brunswick j
Newfoundland |
Nova Scotia J
Ontario |
Prince Edward |
Quebec |
Saskatchewan |
Canada |
S02
560.788
170,640
533,199
225,053
65,635
212,343
1,954,125
4,973
1,210,291
60,125
5.095.172
S02
599,467
154,804
483,719
202,353
59,544
192,637
1.772,784
4,511
1,097,972
54,545
4,622,338
S04
7,677
13,903
13,790
14,963
4,604
11.094
45,947
343
50,699
4,250
167,270
S04
6.965
12.613
12,510
13,574
4.177
10,064
41,683
311
45,994
3.856
151,747
NO
447,652
197,116
91,581
55,120
33,220
78,375
517,732
5,624
297,214
155,082
1,878,716
NO
406,105
178,821
83,081
50,004
30,137
71,101
469,681
5,102
269,629
140,688
1,704,349
N02
37,913
20,060
10,811
3,640
2,710
5,101
46,017
506
24.785
19,135
170,677
N02
34.394
18.198
9,807
3,302
2,458
4,628
41,746
459
22,484
17,359
154,836
Pb
0
0
0
0
0
0
0
0
0
0
NR
Pb
0
0
0
0
0
0
0
0
0
0
NR
CO
3,023,686
2,153,713
1,603,510
347,965
197,323
393,785
4,424,186
57,947
2,409,711
3,373,897
17,985.723
CO
2,743,042
1,953,818
1,454,680
315,669
179,008
357,236
4.013,560
52,569
2,186,056
3,060,748
16.316,385
HCl
0
0
0
0
0
0
0
0
0
0
NR
HCl
0
0
0
0
0
0
0
0
0
0
NR
TONS/YEAR
HF NH3
0
0
0
0
0
0
0
0
0
0
NR
HF
0
0
0
0
0
0
0
0
0
0
NR
83,323
7,012
21,011
1,024
123
1,646
46,260
832
16,564
31,879
209,674
NH3
75,590
6,361
19,061
929
112
1,493
41,966
755
15,027
28,920
190,214
TSP
8,828,141
1,967,089
3,142,219
415,749
2(JO,665
763,019
6,604,382
41,629
2,484,937
6,980,762
31,508,592
ISP
8,008,756
1,784,514
2,850,574
377,162
254,617
692,200
5,991,398
37,765
2,254,301
6,332,843
28,584,129
Ca
709
1,354
602
743
508
483
6,461
0
3,883
1,936
16,680
Ca
643
1,228
547
674
460
438
5.861
0
3,523
1,757
15,132
Mg
249
159
153
233
178
250
1,265
0
761
1,623
4,870
M9
226
145
139
211
161
227
1,147
0
690
1,472
4,418
Na
152
266
55
232
1
238
838
0
687
821
3,289
Na
138
241
50
211
1
216
760
0
623
745
2.983
K
66
19
28
53
0
389
1,350
0
282
412
2,599
K
60
17
25
48
0
353
1,225
0
255
374
2,358
voc
685,711
283,067
233,681
51,010
28.948
73,664
733,251
6,501
390,108
505,957
2,991,898
VOC
622,070
256,794
211,992
46,276
26,261
66,827
665,195
5,898
353,901
458.996
2,714,211
THC
898,962
528,424
325,091
114,009
78,892
149,945
1,482,757
17,202
946,493
593,482
5.135,257
THC
815,527
479,378
294,917
103,427
71,570
136,028
1,345,137
15,605
858,645
538,398
4,658,634
MR - NOT REPORTED
-------
1900 NAPAP 5.2 EMISSIONS INVENTOgr - ANNUAL CANADIAN EHISSIONS OF HYDROCARBON SPECIES, AREA I POINT SOURCES
Allerta
Brit. Col .
Manitoba
t^ New Brun.
| Newfound
t«i Nova Scot
|sj Ontario
O** Prince Ed
Quebec
Saskatch.
Canada
11.767.688
13.744.116
5, 143,306
3,540.911
2.816,537
4.270,917
42,288.130
604,107
31.157.047
4.156,581
120,389.161
244,099
100.764
25.654
19.211
10.116
32,081
141,549
1,756
122,510
61.512
759,253
353,461
78.290
77.185
24.317
10.341
35.417
165,843
669
143.555
206,981
1,096,057
utane so Butane
497,510
224,948
117,894
68,831
37,951
86,577
592,743
6,875
473.749
232.071
2,339,149
129,735
44,684
57.563
13,490
6,734
13,651
155,139
1.102
91.040
130,606
643,943
en ane
188,312
57,496
53,469
24,315
10,099
26,381
181,941
1,182
146,480
124,927
814,803
11,632
8,916
100
266
48
2,329
439
28
248
3.789
27.796
1,151,143
1,393,282
1,145,443
286,046
167,312
162,041
4,035,725
39,333
2,221,058
2,300,349
15.103,733
2,611,986
495,673
1,139,139
65,434
42.847
81,958
1.849,973
10,093
536,115
2,601.774
9,434,992
413,931
170,165
82,670
30.142
20.811
45,396
731.441
5,517
398.776
103.137
2,001.986
3,606
2.105
1,122
305
273
440
3.528
46
2,126
1,345
14,897
1,700.819 168.267
386,827 49,748
716,521 21,680
49,121 9,968
30,369 5,649
75,160 12,438
1,275,151 165,690
7,379 1,449
396,238 92,840
1,680,370 19,920
6,317,955 547,649
207,056
159,900
55,092
27,597
18,777
44,940
352,940
5,074
223,733
77,070
1,172,180 1
357,078
282,269
19,652
16,514
7,577
72.679
154.512
2,302
96,794
120.057
129,434
79,550
63,336
3,637
3.458
1,672
16,943
25,018
504
17,256
26.729
218,103
98,130
50,425
23,338
9.310
6,262
10.030
109,588
1,414
62,645
27,304
398,445
455,622
290,111
61,738
84.72!
58,197
109,845
808,285
8,326
668,593
80.939
2.626,378
88,824
44,880
24,135
6,381
5,697
9,207
76,953
967
44,986
28,114
330,143
23,656
20,464
4,507
4.249
2,107
1,578
28,863
300
16,021
4,067
105,814
54,432
56.317
8,537
8,719
4,911
7.533
157,779
720
119.173
6.649
424 , 770
22,220
35,850
9,589
5,738
4,344
7,44b
135,76'
1,034
78,463
9,256
309, 71i
8 i>2!
3,108
1,29,
6«
54
83
10,33
11
'.2!
9V
33,10,
For conversion of hydrocarbon classes to tons/year, see discussion in Appendix E.
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN i U.S. EMISSIONS, AREA & POINT SOURCES
- - TONS/YEAR - --- - - "'
Country | S02 S04 NO N02 Pb CO HCl HF NH3 TSP Ca Mg Na K VOC THC
Canada | 5,095,172 167,270 1,878,716 170,677 NR 17,985.723 NR NR 209,674 31.508,592 16,680 4,870 3,289 2,599 2,991,898 5,135,257
Contlg. U.S. | 26,954,136 975,608 20,877,086 1,475,151 31,732 99,308,937 526,524 115,434 838,664 42,617,370 113,808 32.025 12,975 15.474 23,164,547 24,977,459
Total | 32,049,308 1,142,878 22,755,802 1,645,828 31,732 117,294.660 526,524 115,434 1,048,338 74,125,962 130,487 36,895 16,263 18,073 26,156,446 30.112,716
ME TRIC TONS/YEAR ' " "
Country | S02 S04 NO N02 Pb CO HCl HF NH3 TSP Ca Mg Na K VOC THC
Canada | 4,622,338 151,747 1,704,349 154,836 NR 16,316.385 NR NR 190,214 28,584,129 15,132 4,418 2,983 2,358 2,714,211 4,658,634
Contig. U.S. | 24,452,809 885,069 18,939,536 1,338,240 28.787 90,091,713 477,664 104,722 760,828 38,661,905 103,247 29,053 11,771 14,038 21,014,593 22,659,252
.. +
J> Total | 29,075,147 1,036,816 20,643,885 1,493,076 28,787 106,408,098 477,664 104,722 951,042 67,246,034 118,378 33,471 14,754 16,396 23,728,804 27,317,885
I - - - - "
N3
^j NR = NOT REPORTED
-------
1980 NAPAP 5.2 EMISSIONS INVENTORY - ANNUAL CANADIAN & U.S. EMISSIONS OF HYDROCARBON SPECIES, AREA & POINT SOURCES
THOUSAND MOLES/YEAR - - - -
Country | Methane Ethane Propane Butane Iso-Butane Pentane Iso-Pentane Alkanes Ethylene Propylene Iso-Butene Alkenes
+
Canada | 120,389,361 759,253 1,096,057 2,339,149 643,943 814,803 27,796 15,103,733 9,434,992 2,001,986 14,897 6,317,955
Contig. U.S. | 91,994,146 6,698,261 4,079,718 15,972,045 3,301,153 3,294,293 340,374 134,447,565 41,611,730 15,457,664 103,241 28,722,513
+
Total | 212.383,507 7,457,514 5,175.775 18,311,194 3,945,097 4,109,096 368,171 149,551,298 51,046,722 17,459,650 118,138 35,040,468
• [[[ ---- THOUSAND MOLES/YEAR [[[
Country | Benzene Toluene Xylene Eth Benz Aromatics Formatdeh Acetaldeh Aldeh Acetone Ketones Org Acid
-------------- 1- --------- - ------------------------------------------------------------ ----------------------------------------------------
Canada | 547,649 1,172,180 1,129,434 238,103 398,445 2,626,378 330,143 105,814 424,770 309,714 33,100
Contig. U.S. | 5,492,770 16,492,428 13,762,475 2,870,820 4,011,537 19,199,592 2,247,947 816,293 7,253,977 4,376,829 1,594,637
------------- + ------------------------------------------ - ------------------------------------ - - - ----------------------------------------
-------
APPENDIX B
DEFAULT PARAMETER TABLES AND SAROAD LISTINGS
Tables B-l through B-5 list default values for control efficiencies, ash
and sulfur contents, and heat values utilized in the generation of the
Version 5.0 NAPAP Emissions Inventory. A detailed description of the
circumstances under which these values were applied can be found in
Section 3. Table B-6 is a listing of the SAROAD codes for pollutants in the
Version 5.0 and 5.2 inventories.
B-l
-------
TABLE B-l. ASSUMED CONTROL EFFICIENCIES3
AMMONIA
Control equipment code
001, 002, 003, 053 (wet scrubbers)
(for coal combustion only)
019, 020, 021, 022, 023 (afterburners)
034-040 and 067-071 (FGD)
SULFATE
Control equipment code
001, 002, 003, 053
010, Oil, 012 (ESPs)
016, 017, 018 (fabric filters)
034-040 and 067-071 (FGD)
Removal efficiency (%)
30.0
99.9
90.0
Removal efficiency (%)
20.0
20.0
30.0
35.0
aFor control devices in series, credit was given for the most efficient
device only. Removal efficiencies for all other control devices assumed to
be zero.
B-2
-------
TABLE B-2. ASSUMED CONTROL EFFICIENCIES FOR HC1 AND HFa
HC1 AND HF - COAL COMBUSTION
Control equipment code
001 (wet scrubber-high efficiency)
002 (wet scrubber-medium efficiency)
003 (wet scrubber-low efficiency)
013, 028, 034, 035, 036, 052, 067, 068, 069, 070 (other types
of scrubbers, steam or water injection, or spray tower)
042 (wet lime injection)
HC1 - INDUSTRIAL PROCESSES
Control equipment code
013 (gas scrubber)
001 (wet scrubber-high efficiency
002 (wet scrubber-medium efficiency)
003 (wet scrubber-low efficiency)
HF - INDUSTRIAL PROCESSES
Process
Control equipment code
Removal efficiency (%)
80
75
70
50
40
Removal efficiency (%)
93
90
85
80
Removal efficiency (%)
HF Manufacturing
Phosphoric Acid
Manufacturing
Triple Super Phosphate
Manufacturing
Diammonium Phosphate Mfg.~
Dryer/cooler
Ammonia tor /granula tor
Primary Aluminum Producton™
Prebake reduction cell
Horizontal soderberg stud
Cell
Primary Aluminum Production —
Vertical soderberg stud
Cell and HSS and VSS
Fugitive emissions
Anode baking furnace
Prebake fugitive emissions
013
001,
001
002
003
013
052
053
013,
050
013,
040
071
052
050
040,
001
002
003
052
040,
001
002
003
040,
052
040,
052
050
002, 003, 013
(spray tower)
(venturi scrubber)
052, 053
(packed gas absorption column)
050, 052, 053
(alkalized alumina)
(fluid bed dry scrubber)
071
052, 053, 071
071
071
99
98
99
95
90
95
95
95
90
90
83
99
99
94
71
96
99
95
90
62
99
97
95
93
99
96
99
94
71
aFor control devices in series, credit was given for the most efficient device only.
Removal efficiencies for all other control devices assumed to be zero.
B-3
-------
TABLE B-3. DEFAULT ASH AND SULFUR CONTENTS
sec
10X001XX
10X002XX
IOX003XX
10X004XX
10X005XX
10X007XX
IOX008XX
10X010XX
10500110
20X001XX
20X004XX
30500312
30500313
30500315
30500316
30600101
30600102
30600103
30600104
30600106
30600107
390001XX
39000201
390003XX
39000402
39000502
390007XX
390008XX
390010XX
Ash content
10.0
10.0
10.0
NR
NR
NR
10.0
NR
NR
NR
NR
NR
10.0
NR
10.0
NR
NR
NR
NR
NR
NR
10.0
10.0
10.0
NR
NR
NR
10.0
NR
Sulfur content
0.70
2.00
1.00
1.50
0.30
0.15
0.80
0.15
0. 15
0.30
0.30
0.30
0.70
0.30
0.70
0.30
0.15
0.30
0. 15
0.15
0. 15
0.70
2.00
1.00
1.50
0.30
0. 15
0.80
0.15
NR = Not required for emission calculation.
B-4
-------
TABLE B-4. DEFAULT CONTROL EFFICIENCIES
Control
equipment
code
001
002
003
006
006
007
008
009
010
Oil
012
013
014
015
016
017
018
019
020
021
022
023
039
040
043
045
046
047
050
052
053
060
Partlculates
97.5
87.5
60.0
50.0
50.0
97.5
87.5
55.0
97.5
87.5
65.0
80.0
80.0
70.0
99.0
99.0
99.0
90.0
90.0
60.0
60.0
85.0
—
—
—
—
50.0
—
90.0
80.0
95.0
—
Lead
97.5
87.5
60.0
50.0
50.0
97.5
87.5
55.0
97.5
87.5
65.0
80.0
80.0
70.0
99.0
99.0
99.0
90.0
90.0
60.0
60.0
85.0
—
—
—
—
50.0
—
90.0
80.0
95.0
—
SOX NOX
90.0
70.0
40.0
—
— —
—
—
—
—
— —
— —
25.0 80.0
— —
—
— —
—
—
—
—
—
—
—
80.0
80.0
80.0
90.0
50.0 50.0
—
81.0 80.0
80.0 80.0
80.0 80.0
—
VOC CO
— —
— —
— —
— —
—
— —
— —
— . —
— — — —
— —
70.0
— —
— —
— —
— — —
—
95.0
95.0
99.0
99.0
90.0
— —
— —
—
— —
50.0 50.0
80.0
50.0
80.0
80.0
95.0
B-5
-------
TABLE B-5. VALID HEAT VALUE RANGES FOR THE NAPAP EMISSIONS INVENTORY
Fuel
Acceptable range
Default
Anthracite coal
Bituminous coal
Lignite
Residual oil
Distillate oil
Natural gas
20-30 MMBtu/ton
20-30 MMBtu/ton
10-20 MMBtu/ton
130-155 x 103 Btu/gal
120-155 x 103 Btu/gal
800-1,200 Btu/ft3
25 MMBtu/ton
25 MMBtu/ton
16 MMBtu/ton
150 x 103 Btu/gal
140 x 103 Btu/gal
1,000 Btu/ft3
B-6
-------
TABLE B-6. 1980 NAPAP EMISSIONS INVENTORY VERSION 5.0 AND 5.2
POLLUTANT SAROAD CODE LISTING
POLLUTANT
S02
S04
TSP:
- Ca
- Mg
- K
- Na
Pb
CO
HC1
HF
NOX:
NH3
VOC
THC
(Hydrogen Chloride)
(Hydrogen Fluoride)
- NO
- N02
(Total Hydrocarbons):
- Methane
- Ethane
- Ethylene
- Propane
- Propylene
- N-butane
- Isobutane
- Isobutene
- Trans-2-butene
- Pentane
- Isopentane
- 2,3-dimethylbutane
- Other alkenes
- Other alkanes
- Formic acid
- Acetic acid
- Other organic acids
- Formaldehyde
- Acetaldehyde
- Propionaldehyde
- Acetone
- Other ketones
- Other aldehydes
- Xylene
- Benzene
- Toluene
- Ethylbenzene
- Other aromatics
SARO_AD CODE
42401
12403
11101
12111
12140
12180
12184
12128
42101
42302
42303
42602
42601
42602
42604
43104
43101
43201
43202
43203
43204
43205
43212
43214
43215
43216
43220
43221
43244
43298
43299
43403
43404
43499
43502
43503
43504
43551
43598
43599
45102
45201
45202
45203
45999
B-7
-------
-------
APPENDIX C
FIGURES DEPICTING UNITED STATES AREA SOURCE
TEMPORAL ALLOCATION FACTORS
The following pages illustrate temporal allocation patterns by U.S. area
source SCC. Where allocation patterns vary from state to state, these figures
represent national mean allocation values. A complete description of the
application of these factors is presented in Section 6.
Figure C-l depicts relative values of seasonal/daily temporal allocation
factors for the 12 temporal scenarios available under Version 5.2. Vertical
bars are comprised of asterisks, where each asterisk corresponds to roughly
1/20 percent of apportioned annual emissions for the respective SCC. Factors
sum to 100 percent via the equation:
* / 65 x \ / 13 x \ / 13 x \
2*i (weekday factor) + (Saturday factor I + (Sunday factor! * 1.0
season=l V ' \ ' \ '
That is, weekday emissions are weighted by a factor of 5, since there are five
times as many weekdays in a season as Saturdays or Sundays.
Figures C-2 through C-4 represent average hourly emissions allocations
over the four seasons for weekdays, Saturdays, and Sundays, respectively.
Each asterisk along the vertical axis represents approximately 1/2 percent of
apportioned emissions for the specified day type. The x-axis represents, hours
from 1 to 24, adjusted to local time.
The real value of these temporal allocation patterns is not, however, in
the absolute amount of emissions represented; the patterns serve as valuable
qualitative quality assurance checks of the temporal allocation factors.
_l
i
-------
StAMJNAL/LAlLY HtANS
• **
* «»
* *•
• »*
• **
***
* **
• «• **•
• •4 *»4
* »» *••
4 4
MIN SIR sun
SCC -
RLMULNT1AL FUbL
* **
» **
» **
4
FAL
»*•
***
***
**»
•**
*»*
«•*
»**
*•* »•*
*** *«•
»** ««*
»•» •»*
*** *••
• »*
**•
***
* **
* »*
* **
* «•
* •*
« •*
***
»*«
• »*
**»
*•»
»**
* ••
4 « 4
HIM SPM SUN PAL
HIM
**•
*•* ***
***
• **
***
4 4 4
Sl'R SUn FAL
**•
»«*
• **
*••
*••
»»*
***
»••
• **
**•
*»« ***
••• **»
»•* ••*
««• ••*
**« ••*
***
• **
• *•
SCC =
FUEL
SCC » J
PtSlDUmJ.L FUEL
hlM id. -SUr. K.L
SCC - <4
HILL
O
K5
4 •* *•*
*** ***
* **
» «»
***
* **
WIN
SUR f AL
SCC -
KLSiOtHllAL FULL
**•
»»*
*•*
*•*
•**
***
•** ***
*** *** ***
*** •** »«*
»** *•* **»
«** •*« »4«
4 4 4
WIN SPR SUn FAL
SCC = b
KES1DINT1AL FUPL
**
**
*»* »* •*
»** «« **
*»» ««* «»»
*•* *** »»* *»•
*** *»* *** ***
4 4 4
M1N SPR SUM FAL
SCC - 7
COMft/JHbT t'UkL
»*• •* •»
*** ** •*
*••*•• •« *
•«• *>* »»• •*»
»»» 4»» t** »«»
»«« *•* *»* *•*
4 4 4
H1N bi-H SUn thL
SCC = b
COHB/1NS1
Figure C-l. Seasonal/daily emissions allocation patterns by area source category.
-------
HtANS
* *
***** * *
***** * *
*** *•« * **
* ** *** * ** * **
*** **» * ** * *•
WIN bra sun (XL
bcc = y
conc./iN.sr FULL
** **
** **
** *»<
•*
**
***
* *** *** ***
*** »»* »** ***
»** *** *** •**
4 4 4
HIN SFR SUM FAL
SCC = 10
Culin/lNST FUEL
**
**
***** »*
***** * *
****** ***
*** *** **» ***
*** *** *** ***
--- t --- 4 --- 4 ---
WIM SPS SUn FAL
SCC =
COKH/1HST FUEL
11
»*
»•» •* •*
••* ** **
•** »»* ***
**• *•* *** •»»
«•* ««• ••* •*•
*** ••* *** **•
4 4 4~-
W1H bl-h SUB tAL
SCC =• 1
conn/INbi FULL
U>
• * »
» * *
*• *• **
• •« **• *•*
4 4- -- »
4111 Sl'R SUN fJ
** **
*** *•* ***
*
* «
**
1J
IKUUVlKlAL tail.
WIN SFR SUn fKL
SLC ' 11
IrtUllS-JKlAL FUtL
4 4 4.
KIN SFR SUtl PAL
IMt'USThl/IL MJtL
* * * *
••* ••* **•
KIN bid SOf. f»L
SCL - Jb
li JtL tUiL
Figure C-l. (continued)
-------
SLAEONA L/liA JLY BEANS
* * * *
* * * *
** »* ** 4*
* 9* 4 4+ * 44 * 44
4 4 4
rfiN SPR SUB FAL
4
4
44
444 444
*
*
*
*
* 44
44 444
17
INDUSTRIAL FUtL
WIN SPR SOn FAL
SCC = 1b
INDUSTRIAL FUFL
4444
4444
44 44 44 44
444 444 444 444
4 4 4
WIN SPR SUn FAL
scc = iy
INDUSTRIAL FUEL
** ** *»
«** *»* *»• ***
4 4 4
N1N ^tH bUH iAL
bCC =^ ^
JNDUbTHiAL HJhL
O
** t*
* t
**
«*
KIN ^FR SUrt FAL
oCC - 21
* «
* *
** *»
»• tt
** 4*
4 4 4
KIN SPR SUB FAL
SCC = it
UN-1>I'JE INC1NFRATIUN
44 44 44 44
44 44 44 44
44 44 44 44
4 4 4
WIN SPH SUrt FAL
SCC - 23
ON-SITE JNClMLUAflON
4 4 4
KIN Sfrk SUh t
SUC =
OPhN BUI KINO
Figure C-l. (continued)
-------
bFAbONAL/UMLY HtANS
« ** *** * ** * +*
»»* *»* * ** * **
* ** + ** * ** * *»
ttt «*« *«« « **
* ** * •* * ** * **
4 4. 4
WJN bt'R bUB FAL
SCC =
OPtN BURNING
*** *** *«* «*«
*** *** *** ***
4 4 +
WIN SPH SUM PAL
SCC = lt>
OPEN fcUKNING
* * * *
* * * * * ' * *
*«» *«* *** ***
««* *** **« » *«
*** *»« •*» ***
*«* «** *** ***
4 4 4
WIN SPh SUn FAL
SCC =
LD GAS VHCLS
27
• »« »*
* *•* *** ***
*** **« *** ***
*** ••* **» •**
*«• *** »«» ••«
WIN blh bur
LU GAS VIILLb
o
I
Ul
* * * *
+ * * + * * * <
* ** »»« * ** * t*
4 4 4
SIN Sl'K bUrt KAL
* » * *
»» ** «» «*
*** ** * ** * ** *
*»« *** »** *«*
*«* **» *** *«*
4 4 4
H1H SPR SUM FAL
* * # * * *
» *» *«* ***
LD GAS VllCLb
SCC =
LU GAS VHCLS
JO
*** *** *«* *«*
4 4 4
KIN SIS bUfl FAL
SCC = J1
fID GAS VHLLS
*** *** ***
4
KIM sth sun I-AL
sec = J/;
HU GAS »H(-LS
Figure C-l. (continued)
-------
i,LA SONA J./DA 1LY MrJAN,
* * * *
* * * * * * * *
+ ** *** * ** * **
- 4 4 4
,' S PR 5 UK F AL
SCC =
HU l-Ab VIICLS
* * * *
** ** + * »*
--- 4 --- 4 --- 4 ---
WIN SPK SUf FAL
E'JC =
Ml) OAS VHCI.S
*** » tt * *« t **
4 4 4
WIN SIR SUn PAL
sec = J5
HU GAS VIICLS
WIN ol H SUM tAL
see = jo
HD bAS VliCLb
O
I
t ., « tt ( >i « »«
t »t «*« * •. « **
*** *** *** **«
--- I --- + --- 4 ---
WIN bH< SUM r'AL
bCC = 3V
HL C-AS ViiCLS
««« *»* tt+ t»*
4 4 4
WIN SIR SUM FAL
sec -
HD GAS VIICLS
+ **
* *#
* *+ * **
--- 4 --- 4 --- 4 ---
WIN SIR SUM FAL
sec - jy
UfF HIGHWAY GAS VHCLS
4. 4 *
WIN Sth SUB
sec - MC
HD blEStL VHCLS
Figure C-l. (continued)
-------
SEA KONA L/DA ILY MEANS
#» *
44 *
* 44 44* 44* * **
* ** 44* 4 44 * **
* 44 *«« t (• * **
4 , 4
WINS IK S UB t" AL
bCC = Ml
III) lUEStL VHCLS
»**
**4 *** *** ***
*** **4 *** ***
*** *** 4** ***
4 4 4
WIN SPR SUN FAL
SCC = 4^1
HI) UltS£L VIICLS
* ** * t* * ** »»*
* ** * ** * ** * **
* »* *** **» »»*
*** **« »»* «t*
+ 4 4
WIN SPH SUB FAL
SCC = 13
HI) DIESLL VHCLS
4 4 4
WIN Sl'h SUfl tAL
iCC = MM
OFF HllallWAI UitStL VIICLb
o
i
1 1 « • « * • »
** ** ^* * +
* * 4* ** **
4*4 444 *44 4 44
--- 4 --- 4 --- 4 ---
WIN btK SUM KAL
bCC = tb
HAILhUAI) LOCO HO 11 Vib
*** •«»
444 44* 44* 444
44* *44 *** 4*4
444 *** 4*4 444
44* 444 44* *44
444 44* *** *44
4 4 4
WIN bl'Il SUM FAL
SCC = to
LIU'S - BJLITAHIf
*4* *44 444 444
44* 444 *** 444
44* 4*4 44* 4 **
4 + 4
WIN bPR SUB FAL
bCC =
LTU'b - LIVLL
'17
*44 4*4 4*4 444
*«* 444 444 »*»
4 4 4
WIN btH SUH 1-HL
:;c c - 1
LTO'b. - COfl 11 S i.C I « L
Figure C-l. (continued)
-------
SEASONAL/DAILY WEANS
* «* *** * ** * **
* +* *+* * tt * **
* ** *** * ** * **
4 4 4
WIN i>i>n sun FAL
sec - My
VESSELS
*** *** »** ***
*** *** »** ***
ttt ttt «** ***
*** »** *** *»*
4 4 4
»IH SPR S«n FAL
ttt ttt ttt ttt
ttt ttt ttt ttt
ttt ttt ttt ttt
ttt ttt »** ***
ttt ttt ttt ttt
4 4 4
WIN SPh SDH PAL
* *
* *
*«
**
• *
*« ** tt
»* *• *»
#• * * * *
** tt tt
tt tt tt
tt tt tt
tt tt tt
tt tt tt
tt tt tt
4* •* *»
* * * * **
scc =
VESSELS
sec =
VhSSELS
51
WIN am
sec =
VESSELS
O
I
* *** ttt
ttt ttt ttt ttt
4 4 4
WIN SPK SOn FAL
SCC = bb
UNPAVf.U FOAb IKAVbL
ttt ttt *** ttt
t t* t tt tt* ttt
ttt ttt ttt ttt
4 4 4
WIN Sl'E Sun FAL
sec = 5o
UHPAVtb AJRSTI.iE' LTD • S
t»« »*»
»* * ««»
ttt ttt
ttt ttt
ttt ttt
M1N M'K bUt,
sue -
(OKblil H1LU flli
Figure C-l. (continued)
-------
SEASGNhL/D.'i ILY KEANb
*#*
«**
***
*»*
***
* »«
***
»»*
**
*#
** * «*
** * **
* ** ** * »#
«»* *** • »*
WIN bER SUM FAL
*»*
»**
»**
***
***
***
*«*
*«*
»**
***
*«*
***•
**»
***
***
bCC =
MANAGED BURNiNO
b 1
WIN SPR SUM FAL
SCC =
AGB FIELD BUNN1NU
*** »** *** ***
*»« *** *** ***
*•* *** t«« ***
4 4 4
H1N SPit SUM FAL
SCC = 6M
STRUCTURAL FIRtS
** ** »*
*« *• ** *
** *• ** »
4 4 4
WIN bfh SUB JAL
n
BANUriE FitLl> AIPL1CAI10N
O
I
»*
** * *
** **
** « +
»* **
** ** » » **
*» «» t < **
« t ** * » **
** «« ** **
4 4 4
WIN SPh bUM FAL
bCC = 12.
f.A!lUI(L titLU AI'i'LIC A'llUN
**
**
t*
*t
*«
*t **
*t *»
4 4 4
WIN SI'R SUB FAL
bCC = 7J
BANUKE KltLl) APPLICAiiON
** *«
** »*
* * * *
** * * »*
* * * + **
** ** « *
** ** **
* * * * *»
WIN SPB SUB FAL
SCC » 71
KAHURh FltLO APPLICATION
**
4*
»* »*
** •*
»* *»
** •*
«» **
4 4_.
UN bl'K bl
iAL
SCC - /b
BANUNt Kli.1.1/ AltLjlAlJLUk
Figure C-l. (continued)
-------
SEASuKAt/bAlLT tlEIAHS
• * ••
»* »•
*« ••
• * ** •«
KIM SIR sun rt.L
bCC = 7b
ANUbhS NIUFLkl APtL
«•* «*» •»* *•*
•«* *«* ••* ••«
• ** •«• •** •••
»** »*• •** **•
-—»---« »---
WIN SPtt SUN FAL
!>CC - 77
BEtK CA1TLK FttU LOIS
* »
**•
*
»* ••
« »•
»• •••
VI* SVIt sun PAL
SCC = 78
DLUREASING
KIN SCK SUn FAL
DKTCLtANlNu
I
t-"
o
* *
• * * •
*
* *
KIN SIR i, UM FAL
SCC
FA HI 1C A
* *
* *
* *
* *
4 4 «
WIN see sun PAL
sec = at
I'.Ubbth AND PLASTICS flt\,
* * *
* » *
* * *
* * *
** ** ** »«
«•* •« *** ***
, * «
WIN SPH SUM FAL
SCC = 82
AfiClilTlCTUHAL COATIN«
** •
*»» ** •«• •»*
—_» — -» --- «---
hlH St'h ^Uh fkL
SLt = BJ
AU10
Figure C-l. (continued)
-------
SE/.SONAL/DA1LI BEANb
»*
* ** •«••*•
4 » 4
WIN SIM sun r«i
sec = »«
VUIK-LE fltv
** »* »*
*** *•* »** •*•
• IN SPR SDH PAL
ECC « 85
PACHi COAT1HG
»» **
*•• ***
* •«
*• ••»
«
• »
»«»
• •
*• •••
Mm sm sun PAL
sec = »»
fABUCATtD HtlALS
• in SI-H !>Uh fAL
see - t*
RACHINEKI BH,
O
I
*
*
*
*
*
»
4*
«* **
»»« ••*
4 4 4
WIN biR SUn FAL
HCt -
pURNiiuiit a
»e
WIN SPR SUn PAL
SCC = 89
FLAT KOOU PFOUUC1S
*
*
*
* **
** •• *»* ***
win SFK sun PAL
SCC = 90
ft ThAHs EVUIP nru
•
•
*
*
*
**
**
**
• ** *
•
*»
win ^ph ^un *J.L
sec * yi
ELtCMCAL fc^OiPMM
HtU
Figure C-l. (continued)
-------
L/UA1LY HKAMS
•4--
WiN SPR SUR FAL
SCC = 9/1
SHIP HLUG AND
* * *
** ** **
4 4 4
WIN SPR SUB PAL
SCC = 9J
MISC INDUSTRIAL HFG
• * * *»
*
**
WIN StH SUH FAL
SCC = 91
HISC 1NDUST SUL»E«T US£
WIN :>t'h bUR
Uit
I
I—"
NJ
* **
> »*
tt* » >* * ** * »«
»** « ** * «* * **
4 4 »
WIN SI-K SUM FAL
scc = yb
MINUK llliLITILS - ^.OA
*** ***
»** *»« *** ***
*** «** **» ***
**• *** *** *«*
4 4 4
KIN 31 h EtlH FAL
scc = y7
11NUK U11LITIIS - OIL
» «*
***
««t *** *** *»*
4 4 4
WIN SPR SUn FAL
SCC = 98
MINOR UTILIII tS - GAS
» * • •
* * * *
» * * 0
4 4 4
win st-h sun t-«L
set. -
B1NL.H 1HIJJI1
Figure C-l. (continued)
-------
HOUhLlT .1LANS
***
»**
***
***
***
*****
*********
»»*»»»***
*********
***
***
,,,
* ******
. ******
,,,«.........,,,,.,.,,.,
************************
** *
***
** *
***
***
*****
*********
*********
*** ** ** **
*********
***********
******* ** ** *
************
*************
...
...
...
......
******
***«*»*
***
*** •
*«*
*««
«**
*****
.........
»*»»»*««*
**,**»*»*
***,***,«
**,*«***»**
****»».»»**»
************
************************
***«***
******
...
,«*
...
******
******
****«*«»*«
*»*«*»««»
*********
,»*
***
...
...
...
***«*
*********
***,*»»**
*«**««,«,
*«»»,,*,,,*
*»«*«*«**.«»
************
»,,
,»«
,,,
******
******
»«««,*»
*******
i-CC
HE51L>hNll/iL FUEL
SCC =
RESIDtNTI AL FUEL
SCC =
RESIDENTIAL FUEL
bCC =
RfcSlUtNTlM. KILL
*•*
***
***
»**
***
*****
******
********* ***
********* ***
*********** ***
************ ******
************ ******
************************
************************
************************
SCL =
HESlUtNTlAL FUEL
***
***
«**
***
***
*****
*********
*********
*********
*********
*********
*********
*********
**;,<*«.«
***
****
************
************
.*.
***
** *
******
******
************************
«*«»««*****«****•»«***«*
bCC -
KESIDEKTIAL FULL
****************
****************
************************
************************
************************
************************
************************
t ---- » ----- * ----- «. ----- 4
SCC = 7
COPM/iNS'l FUtL
•»•-«**«*«**«.*.*«,.,...
***•»********•*«*.**•***
,>.*.....«..«.«,...«,...
************************
........................
4 ---- 4 --- 4 ----- 4 ----- 4
SCC - b
COHB/INST FUtL
Figure C-2. Hourly emissions allocation patterns by area source category, average weekday.
-------
WEEKDAY HOURLY HLAHS
******** **** ****
it**********************
******************* *****
4 4 4 4 +
sec = »
r FUEL
****************
****************
************************
************************
************************
************************
sec =
COhli/lNST FUEL
10
*********
****************
****************
************************
************************
************************
************************
sec = 11
COMM/XNS'l FUEL
4 ---- 4 ----- 4
bCC -
o
i—1
-F-
*********
******** *
*********
*********
*********
*********
***
• *«
***
SCC = 1J
1NUUS1MAL FUL'L
************************
4 4 4 4 4
1JCC = It
INDUSTRIAL FUEL
*********
*********
*********
************************
************************
************************
SCC =
INbUSThiAL FUEL
1b
************************
INDUSlhiAL 1-UlL
Figure C-2. (continued)
-------
WLLKL>A!f HUURLJ 1 hA NIi
*********
******** *
******** *
************************
*********** *************
******* ******** **** *****
ft**********************
************************
******************* *****
4 4 * -f +
sec = 17
INDUSTRIAL FUEL
*********
*********
*********
*********
************************
************************
************************
************************
************************
************************
4 4 4 4 4
scc = ia
1HDUSTB1AL FUEL
*********
*********
*********
************************
************************
************************
************************
************
sec =
INDUSTRIAL FUEL
19
************************
si,c =
INDUSTRIAL HIIL
o
I
********* **
***********
********* **
* ** ** ** ** **
***********
********* **
* ******** **
* ******** **
********* **
4 4 <
***********
***********
***********
***********
***********
***********
***********
***********
***********
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**•*••***•***•*
4 4-
SCC = 21
ON-SITE INCINERATION
SCC = 22
ON-SITE INCINERfcllOH
SCC =
ON-S11E
2J
SCC =
OPtd BUBNINt,
Figure C-2. (continued)
-------
(pamrpuoo)
STHIA SV) QH
tr
S13HA SVf> ail
= DOS
S1DHA TV9 OT
= DOS
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niiTNHns
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SBV3U nunnii
-------
°Z-3
an
S13HA sv
fif = 33S
Rf
S13IIA SVO *» *
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S1TIU SV3 OH
- ms
SF
S13HA SV9
= 33 S
t)C
siotu svo au
= 03S
S13HA SVO OH
= 3DS
************************
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***** ******
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***** *****
************************
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-------
HEEKDAY HOUR LI MEANS
* * **
**** **»*
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*******************
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4 ---- 4 ----- 4 ---- 4 ----- 4
SCC
<• 1
IIU
VHCLS
* * **
**** ****
**** *«**
***** ****
***** *****
***** *****
***** *****
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*******************
************************
4 4 + * +
SCC = 12
HO VLtStL VHCLS
* * **
**** ****
***** ****
***** *****
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** *********
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*******************
************************
4 . 4 4 4 4
StC = «3
IIU DlbSEL VHCLS
******•«•**»
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******************
******************
OfP HJUHkAI blLotL VHCLb
O
I
00
***********
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************
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************************
************************
************************
************************
************************
SCC = Mb
RAILROAD LOCOtlOUVEi.
************
******************
************************
************************
************************
************************
************************
************************
************************
4 4 4 4 4
SCC = 16
LID'S - B1LITART
***************
***************
*********** ****
***************
***************
***************
***************
***************
***************
***************
***************
***************
.4 4 4 4
***••**<
»*****•«
*****»*«
***
SCC
LTO'S - CIVIL
M7
************* *****
** ********************
************************
************************
4 4 4 4 4
SCC = «b
LTO'S - COIJHEhCIAL
Figure C-2. (continued)
-------
HOURLY hlA.'IS
*********
*************
**»
**«
************************
************************
************************
*********
»**»****»** **
*********************
• **•«»•*•«*«
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i.-CL -
VKSSLLi.
bCC =
VESSELS
bO
************************
************************
4 4 * 4 «
SCC = 51
VESSELS
SCC =
VESSELS
n
* *
**
***
***
***
* ****
* **** **** **** *
*****************
** **** **** **** *****
*******************
* *
* **
* **
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4* ********
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sec -
GAS KAHKtltU
SCC ^ b5
UNI'AVtO KOAO TRAVh'L
***************
*** ************
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*********** ****
*««****««******
***************
***************
f + 4 4
SCC = bb
UNPAVLU A1KSTRJP LTO'S
4 ---- 4 ----- 4
SLC =
FORKS'! WILD
bC
Figure C-2. (continued)
-------
WEEKDAY HOURLY MKANS
**»**»**»*•**** *************** **»«*»»»»»»»
*************** *************** «*«*«*«**»**
*************** *************** »*«**.**,*»«
»****»*******«* *************** *«»«•*»»«,,«
*************** ,«*»«**,»»*»*,, *»«««»**»««»«**«,»,««»,* *.,««»«»*,««
*************** *************** ************************ «»*«»•.,«.,*
*************** *************** ************************ ************
*************** *************** ************************ »*»««««*««««
*************** *************** ************************ ************************
*************** *************** «*«*«******,«»*»***,*«** •**««*»«*««»»»,,»,»»,«»*
*************** *************** ************************ ******»*****«»«*•»«*«»»*
*************** *************** ************************ ************************
— 4 4- * + 4 4 4 4 4- 4 4 4 4 4 * 4 « 4 4
SCC - t> 1 SCC = bt bCC = bl SLC = 71
HhNAGtiD BURNING AGB FIELD BURNING STRUCTURAL FIRES tUNOKL FifcLU APi'LJCAllON
O
O
****** ****** ****** ******
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************ »«*****««*** ************ «******«*»**
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************************ *«»**************»*»»«*« ************************ ************************
************************ ************************ ************************ ****•*****«**«,**«**«,*,
************************ ************************ ************************ ************************
************************ ************************ ************************ ************************
+ 4 4 4 4 4 4 4 4 » 4 4 4 4 + 4 4 4 4 4
SCC = ?.
-------
KtLKUAY HOURLY MiANS
******* ** **
4 4 4 4
SCC ^ 7b
AHHURS NH4FER1 M-tL
***********
***********
** ******** *
>*«*****
************************
4 4 4 4 4
bCC = 77
BEfct CATTLE FbKl) LOTS
*****************
*****************
*****************
*****************
*****************
****** *****
***********
***********
*••****•***
***********
***********
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sec
78
M.C =
DHTLLLAMlNb
o
NJ
******* **»
******* *»*
* ****** ***
******* «**
****************
****************
****************
4 4 4 4 4
SCC - IH>
GKAIH1C AhTb
***********
***********
***********
***********
************************
************************
4 4 4 4 4
SCC - 81
RUBBER AND PLAS'JICS tin.
**************
**************
******* *******
**************
**************
4 4 4 4
SCC = B2
AKCHIltCTURAL COATING
**********
******* ***
**«
4 4 4 4
SCC = BJ
AUTO B01JT htl'AJh
Figure C-2. (continued)
-------
WEEKDAY HOUPLY « Ki NS
***********
******** ***
******** ***
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** ****** ***
************************
************************
4 4 4
SCC - BM
VLHJLCLE HPG
***********
***********
***********
***********
***********
************************
************************
************************
************************
4 4 4 4 4
SCC = Bb
PAPER COATING
********** *
***********
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** *********
****** *****
***********
***********
************************
************************
************************
************************
4 4 4 4 4
SCC = 86
FABRICATED BE1ALS
***********
***********
********
4 4_.
SCC ^ b7
BACHINtHY BKG
n
I
Ni
(-0
**** *******
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************************
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SCC -
FURNITURE HFG
bfa
scc = oy
FLA'l MOOD PFOWJC1.S
SCC = 90
OTHER TRANS EVU1P HFG
SCC = 91
ELfcCRlCAL tylUl tiLHl IUG
Figure C-2. (continued)
-------
HitKDAT HOURLI HKANS
***********
*********** *********** ««*«*,«»»«»
*********** *********** *********** »*«•»««««**
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************************ ************************ ************************ ft**********************
************************ ************************ *****«*«***,******,*,*»* »*«*«*.»»**»..»».,*»».,,
************************ ************************ ************************ »«*•*«»*«*..»».».,,.*«,,
************************ ************************ ************************ ************************
* + + * * + » 4 » + 4 4 4 4 t 4 4 4 4 4
scc = 12 scc = 9J scc = 91 sec - 95
SHIP bLDG AND RLPJ.lh HISC INDUSTRIAL HtG fUSC INDUS'! SOLVENT USE BISC NONIND SOLVtNl USt
d
I
ho
U)
************** **************
************** **************
****************** *****************
******************* ************************ ************************ *********
******************* ************************ ************************ *********
******************* ************************ ************************ *********
+ 4 + 4 + 4 4 4 + 4 4 4 » 4 4 4 4 4 4
sec - yu scc = 97 scc = 98 scc = 99
UTILITIES - COAL B1NOP UTIL11IES - OIL MINOR UTILITIES - GAS D1HUR POINT SOUhCfS
Figure C-2. (continued)
-------
UAiUKDAY HOURLY BEANIi
«,« *.. *** »**
** * *** ** * ** *
«** *** *** ***
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************ ****** ************ ****** ************ ****** ************ ******
************************ 4*********************** ************************ ************************
r************* ************************ ************************
-4 4 4 4 4 + * + + * + + -»
i,cc ^ i sec = <; sec = 3 bcc -
FUtL hhSJDLNUAL FUEL RESiDtMTIAL FUEL fctSlDtN TiAL t UtL
r;
I •«* ***
K> *** ***
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********* ** **««**«** ** *******»*«»**»** ****************
****«*»«* *** *,,*,**,« *** *«,**»««****»*** ***,««»«,.«*»«*«
********** *** ********** *** *«»«*******««»** *«,,•**.,*,*..*•
************ *«**«* ************ ****** ************************ ***********************
************ ,,«*** »**«»»****** *»*««* it********************** ***********************
I*********************** **»,«*«**«************** »*»».**»******««**««*»** *»«»»»,*«*«*«»..*..««».
************************ ************************ ************************ I**********************
*«««***«*»******«**»**** ************************ *******»**«***•***«*«*«* ***********************
b SC.C = b SCC - 7 SCC = U
FUKL KtblUtNIiAL FULL COBM/INST fOEL COHH/INS'I HILL
Figure C-3. Hourly emissions allocation patterns by area source category, average Saturday.
-------
SATURUAT IIUUHLY MEANS
********* ********* «*«*»*««« *«*»*»,,»
****«***» ********* ********* »*»«»*»»«
*************** *************** *************** ***************
****«*»«•«****** **************** **************** »*«»•»*«».*«»,»»
**************** **************** **************** ****************
**************** **************** »***«********«*« *«*»**,,»»»,,.,»
************************ ************************ ************************ ************************
************************ ************************ ************************ ************************
************************ ************************ ************************ **************««•*«***«*
************************ **»*»*»******«***»*»*»*« ************************ ************************
************************ ************************ ************************ ************************
+ * » » » 4 + t » » « » + » 1 » 1 « « «
^CC - f SCC = 10 bCC = 11 bCC = 1^!
COOR/iNLT FUKL (.URB/INST FUEL COHM/1NST FULL CONB/1NLT KUtl,
o
I
********* ********* *********
********* ********* *********
********* ********* *********
************************ ************************ ************************
************************ ************************ ************************
************************ ************************ ************************
************************ ************************ ************************
************************ ************************ ************************
************************ ************************ ************************
************************ ************************ ************************
* 4 + + 4 4 4 4 4 4 4 4 4 4 4
SCL = U SCC = 11 bCC = 15 SCC = 10
INDUSTRIAL FULL 1NUUSTM A L KUtL INDUSTRIAL FUEL INDUSTRIAL JULL
Figure C-3. (continued)
-------
LiATUKDAIf IIOURLJ MEANS
********* ********* ********* «*»«*.««*
********* ********* ********* «»•*»«.,,
********* ********* ********* **»*.«»«»
************************ ************************ ************************ *»«***««»»*»*»••««»«**.,
************************ ************************ ************************ ************************
************************ ************************ ************************ ************************
************************ ************************ ************************ ***«•«*««»««..«».»».»,,,
************************ ************************ ************************ ****»«•**»»»*»»»»»»,»«,,
************************ ************************ ************************ ************************
************************ ************************ ************************ ************************
* * 4 * * 4 4 4 » 4 * 4 4 4 4 4 4 + 1 t
^CC - T/ SCC = 1b SCC - 19 Sl-C ^ ;0
INDUSTRIAL FULL INDUSTRIAL FUEL INDUSTRIAL FUEL INDUSThliL IV LL
n
i
^o ****«»»*»** *********** ***********
c* *********** *********** ***********
*********** **«»«***««* ***********
*********** ***«*»***»* ***********
*********** ***************
*********** ***************
*********** *********** *********** »,».*»««,,««*,«
*********** *«***«*«*** *********** ***•*«**«**,.*,
*********** *********** *********** ***************
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*********** *********** *********** ***************
**«•*****»* «**««***»** *********** *«*«*«,»«,,,,,«
*********** *********** *********** ***************
*********** *********** *********** ***************
*********** *********** *********** ««*««»*«*«,,*«»
*********** *********** *********** ****.*****«****»
t + » + * 4 4 4 4 4 4 4 4 4 4 4 4 «
iCC - 21 SCC = 22 3CC = 23 bee =
ON-Slrt, 1NCINEF A110N ON-S11E I NCIN h* ATION ON-SITE INCINERATION OTEK BUKMNO
Figure C-3. (continued)
-------
-£-3
IE
STDHA S
= 33S
1H
Of
ST3H& SV3
= D3S
ST.IIIA
m
*********•***•*******+*•
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= 331
tnjn
tr.
= 3DS
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***************
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* **** »***•*«***
-------
SATUHUAY HOURLY BEANS
* * **
**** «»**
** *
******
********* ********* ***** *****
l**«******* *********** ***********
**************** **************** ***********
**************** **************** *************
***************** * ***************** *************
t**************** ** ****************** *************
************************ ************************ ************************ ************************
4 4 4 4. 4 4 4 4 4 + 4- 4 * + -f 4 + + * 4
XC = JJ SCC = JM SCC = Jb bLC = Jt>
HD GAS VHCLS MO GAS VHCLS HD GAb VIICLS HD GAS VHCLS
o
N3
CC
**** **** **•* ****
* * ** *********
**** **** *********
***** ***** **********
***** ***** ***** ***** ***********
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*********** ************* ***********
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************* ************* *************
************* ************* *************
************* ************* *************
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******************* ************* ***•*««**•***.*«
************************ ************* *********************
4 4 4 --4 4 4 4 4 4 4 4 4 4 4
SCL = J7 SCC = 3b SCC = J* bCC - 1U
I1U GAS VHLLS till GAS VHCLS OFF HIGHWAY GA£ »HCLS HD UltSfcL VHLLS
Figure C-3. (continued)
-------
SATURDAY MOIIllLY MEANS
******** *«*
***************
*******************
* * **
**** ****
**** ****
***** ****
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********«****4****4
************************
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************************
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******************
SCC = M1
HI) bits EL VHCLS
SCC =
IIU DltSEL VIICLS
SCC = MJ
HL> DiKSEL VIICLS
bCC = tl
OFF IIIGHKA! UitbLL VHCLb
O
I
NJ
VO
********* ***
SCC = t!
lioAD LOCUtlOU V£:
************************
4***********************
•ft*********************
************************
************************
4 + ., t t
SCC = Mb
LIU'S - niLITAtiT
*** ************
***************
***************
***************
***************
***************
*********** ****
*********** ****
***************
SCC = <47
LIU'S - CIVIL
******************
******************
M8
Figure C-3. (continued)
-------
SAi'UKDAI 1IOOKL* HfcANS
*************** *********
bCC =
*********
*************
*************
************************
sec
VEbSfLS
***********t»
*********************
************************
************************
************************
SCC =
»ti.SELS
***•
****
*•*«•**<«t•*
«**•»•*•••*»
5LC
JtSSKLi.
o
o
** *
*» *
»» *
*****
, 4 4 4 «
^CC = b
-------
HOURLY MEANS
I**************
***************
***************
***************
***************
***************
***************
***************
************************
************************
************************
************************
************************
************************
************************
************************
************************
sec =
MANAbtU BUhNIMb
0 1
SCC = 62
AUR HELD BURNING
SCC = 61
bTEUCTUBAL FINES
71
HANURE PitLl) API-Lie A HUN
O
I
OJ
******* **** *
******* ««** *
******* *«** *
***** ** *****
******
************
************
************
************
************
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** ****
************
**««***** ***
********* ***
******* *****
***** *******
************************
************************
************************
7 J.
flANUKt F1U.D Ati'LlC A110N
SCC = 7J
HANURE FIELD APPLICATION
SCC = 71
RANUBE FIELD APPLICATION
S<_L = 75
(1ANUKE HE1.U Al-FLlLdliUN
Figure C-3. (continued)
-------
SATUKDAY IIUUKLY MKANS
*** ** ******
**** **** ** ** *
************************
4 4 4 4 4
SCC - '/b
ANlil'hS N1IJFEH1 AFM,
************************
************************
************************
************************
************************
4 4 4 4 4
SCC = 77
BttiF CAITLt fttl) LOIS
****** *****
** *********
***********
***********
***********
***********
******************
******+*»****•***
*****************
*****************
***********
***********
***********
***********
***********
*****************
*****************
4 4 4
SCC -
DtliHEASlNt.
78
scc -
n
i
sec =
GRAPHIC fthTS
***********
***********
***********
***********
************************
************************
************************
sec = bl
RDBBEh AND PLASTICS MFC
**************
**************
**************
**************
**************
**************
4 4 4
SCC = 82
AHCIUIECIURAL COATING
4 4
SCC
AUTO bOUY
Figure C-3. (continued)
-------
(panui^uoo) *£-0
1V3TH3913
= 33S
********•**••**»*•******
****#****•*******•*•****
I***********************
************************
***********
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***********
H3HT,o
06 = 3")S
« + » ». 1
************************
************************
************************
************************
***********
***********
***********
***********
***********
6fl
aoon
33S
H aan.iTNuru
= 335
************************
************************
************************
************************
***********
***********
***********
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************************
***** *******************
*************<*******»**
************************
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***********
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******* ****
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CO
en
Lf>
<>4U ia7NTH3Va
= D1S
= 33S
9NTXVO3 HJdVd
= 33S
f«M 3T3TH1A HO.TOH
»I8 = 33S
************************
************************
************************
************************
************************
***********
***********
***********
***********
***********
***********
***********
***********
* **********
* **********
************************
************************
************************
************************
*** ********
***********
***** ******
***********
***********
***********
***********
***********
***********
***********
************************
************************
*** *»** **«*
***** ******
*** ********
*** ********
*** ********
*** ********
*** ** ******
-------
SJLTUKUfcl HOUR LI RfcAKb
*•***•**••*
**•*•••**#*
**** **** **»
***********
***********
***********
****** ** ***
***********
************************
************************
************************
*********** **** **•* *****
4 4. 4 4 4
bCC - "it
SHIP BLDG AND RtrAik
***********
***********
***********
***********
***********
**** ***•***
***********
***********
***********
***********
»*******»»****»***•*****
************************
************************
************************
4 4 4 4 4
SCC = 9J
RISC INDUSTRIAL H«i
***********
***********
***********
***********
***********
***********
***********
***********
***********
************************
************* ***********
************************
************************
4 4 4 4 4
SCC = 9M
DISC IIIUIbT SOLVENT USE
***********
**•»**»****
***********
»•••*•**»**
******** •**
***********
*******•*****»*»**•«•*•*
************************
************************
****•******•*••***•*•**•
4 ---- 4 ---- 4 ----- 4 ----- 4
HISC HUMINU SULtrtNl USt
o
»*•«*••*•
•»•»**•**
•••»**•»•
••**•*••*
********* *****
********* •*** *
********* **** *
* ******** **** *
***»****»**»***•**
********************
************************
************************
************************
4 4 4 4 4
**************
**************
**************
**************
**************
******************
********************
************************
************************
************************
************************
4 4 4 4 4
*****«*»•••*»•
**************
*** ***********
***•******•*•*
**************
******************
********************
************************
************************
************************
************************
4 4 4 4 4
*********
***••*•**
*********
***••**••
*********
*********
*********
HINUH U11LJ11LS - COAL
SCC * 97
B1NOII UTIHT1FS - OIL
SCC = 96
BIHOH UTILITIES - GAS
S>CC =
HJNOH POINT
Figure C-3. (continued)
-------
38BJ3AB 'AaoSaneo aoanos
Xq suaaruBd
T.SNT/UHfn
= DOS
»»•**>•*******«*•****»**
»***«*»******•*•»**•****
****»****•»»*»****»««***
***•**«****«»***
****•*****•*•«**
*********
*********
************************
************************
************************
************************
************************
****************
****************
****************
***************
*********
*********
<» - DDS
» 1 » 4 «
************************
************************
************************
****** ************
****** ************
*** **********
*** *********
*» *********
*********
*********
*********
*********
*****
»**
***
»**
***
***
*****»**»*******•»»*****
************************
************************
****** »*»**»**»*»*
****** ************
*** **********
*** *********
*» »*»***»*»
*• *******
»• *******
**«»*»***
** *******
* ****
* **
***
***
***
»**
in
I
= DDS
130.1 TYIIMIOTSTH
= DDS
13fU 1VTT. HHnTSJI
I -- DOS
*»»»»•»»»»»»»»»»»»»»»»»»
************************
• »»*»»•**»*»***•***»*•«*
****** ************
****** ************
*** *«*•*****«
••• *********
** *»»«*****
***»»«»**
************************
************************
************************
****** ************
****** ************
»** »»***»*»*»
*** *********
>* *********
**** *****
*********
*****
***
***
*••
**»
»**
**** *****
*********
*** **
* **
* **
* **
* *»
* •»
************************
************************
************************
****** ************
****** ************
*** **********
*•* *********
** *********
*********
*********
*********
************************
************************
I***********************
****** ************
****** ************
*** **********
*** *********
** **«***•**
*****
*4*
***
4 **
***
***
*********
*********
*****
***
* **
***
* **
***
SNV1U
-------
SUNtlAlf HOURLY (ItANS
********* ********* **<
********* ***»«**** *«<
****** *************** *************** *•<
******* **************** **************** **<
******* **************** **************** ***
************************ ************************ ************************ ************************
ft********************** ************************ ************************ ************••****.*•*,*
************************ ************************ ************************ ************************
************************ ************************ ************************ ************************
************************ ************************ ************************ ************************
4 4 4 4 4 4 4 4 4 + -f * 4 4 4 4 4 4 4 4
bcc = y sec = 10 sec = 11 set = i<:
T FUt'L conn/iNST FUEL COHM/IHST FUEL
o
I
CT-
********* ********* *********
********* ********* *********
********* ********* *********
********* ********* *********
************************ ************************ ************************ **********•******«»**«**
************************ ************************ ************************ ************************
************************ ************************ ************************ ************************
************************ ************************ ************************ *************»*»*»**»*»*
ft********************** ************************ ************************ ************************
4 + 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4
sec = u sec = 11 sec = 15 sec -
1NDUSIPUL hUtL 1NUUS1P1AL I-UL'L INDUSTKiJ.L FUEL INDUSTRIAL f(l LI.
Figure C-4. (continued)
-------
SUNDAY
HOURLY
*********
******** «
************************
************************
************************
************************
************************
************************
4 » 4 4 (
17
INDUSTRIAL FUEL
scc =
INDUSTRIAL FUPL
1U
** *******
*********
************************
************************
***** **** **** **** *******
************************
***** ******** **** *******
************************
4 4 4 t »
SCC ^ 19
INDUSTRIAL FUEL
***
************************
************************
************************
************************
************************
************************
«. 4 4 « t
b<_C = ^U
INUU.MfUtl. tULL
***************
SCC = 2\
UN-SHE 1NC1NEHAT1UN
4 4 4 4
SCC = 22
ON-blTL IHCItlbRATloN
4 4 4 4
bCC = 23
OH-SI'lE INCINERATION
M.C -
Ul'tN DURNlNl,
Figure C-4. (continued)
-------
SUN LAY
HOURLY flKANb
**t
**«
***
4 4-
bCC =
BllhltiNt,
***************
***************
********** *****
******** *******
***************
4 ---- 4 ----- 4 ----- 4 ---
bCC = 2b
OPtN bURNlNG
******
***** **
**************
* ***************
** *****************.
*** ******************
************************
4 4 4 4 4
*****
******
*•**•»**»*
*»•*«****•**••
» *****»•***»»***
** *****************
4 4-
bLC -
LD GAS VHLLS
27
SUC =•
LD OAS VMtLb
I
u;
oc
* **
*****
******
****** **
****** »*
** ****************
** *****************
*** ******************
***
*****
******
********
********
**********
***** ******
*************
*************
* **************
»* ********«*+***«*
** *****************
*** ******************
************************
*
******
*******
*********
**********
***********
*************
*t *****************
*** ******************
**** *******************
************************
************************
4 4 4 4 4
*****
******
** 4
*** *<
LD
JO
Ll> GAb VI1CLS
bCC -
MD GAS VHCLS
3«
bCC -
KD GAS »HCLS
Figure C-4. (continued)
-------
JUNUAT
HOURLY MEANS
* **
* ** **
********
• « ****************
** *****************
»*» ******************
************************
************************
* *
* **
***
*****
******
********
**********
***********
*************
*********** »«
**************
****************
******************
*
*. 4 **
**** *«**
**** ****
***********
********** *
***********
*************
*********** **
**** ***********
*******************
************************
* * **
************** *
sec =
flU GAS VHCLS
sec =
HD GAS VHCLS
3D
sec =
Hl> GAS VHCLS
Sec = Jb
Ml> GAS VnCLS
o
I
* * **
**** ****
**** ** **
***** ****
***********
******** ***
> »* tt ********
**** ** * *
***** ****
***** *****
***** *****
***********
***********
***********
*************
*************
*************
***************
*******************
*********
*********
*********
**********
**********
***********
*********** **
*************
*************
*************
sec ~
UfJ !jib VHCLS
J7
sec =
Hi) GAS VHCLS
J8
sec = jy
OFF HIGHWAY GAS VHCLS
see =
Hl> 1/itSt.L VlieLS
Figure C-4. (continued)
-------
(pamrpuoo) '^-
- Si nn
nit
•mio -
•= DOS
iHVJ,T1IH - R.O.T/I
3DS
flYDHITVH
qt,
»»«»•»***»*»«•*••«««****
******************
»»»•«*««»«*•*»•*••
«•«*»•»»•*»•««»**«
t + 4 4
*»** ***********
************ ***
***************
***************
***************
***************
***************
**** ***********
***************
***************
***************
***************
***************
************************
************************
************************
************************
************************
************************
******************
************
************************
************************
*******************
* ** *********
»** *********
*** *********
*** ******** *
** ** ** ** ** *
S1DH/I
till
IVHHQTH J.JO
Fh
STDHA 13S3IQ <\H
= D3S
STDHA
GH
S13HA T*S3T<] nil
33S
*******»»»«**«*•»*
************
************
************
***»*»*«****»******<
*******************
***************
*************
*************
*************
***********
***********
***********
************************
*******************
***************
*************
*************
*******************
* **************
***
**<
*»** **»*
** * *
***********
***** *****
***** *****
***** *****
**** ****
**** *********
*************
*** ********
**» **** ****
***** *****
***** *****
**** *****
** ** *** *
t* * *
HIIVSH jinnoii
-------
SUNDAY
HOUhLY BLANS
**•«•*»»»**«
********* ****
* ************
* ************
* **** **** ****
******
************************
************************
4 4 4 4 4
*********
*************
*************
*************
*************
*********************
************************
************************
************************
******* ******
*************
*** **********
*************
*************
*********************
************************
************************
************************
************************
4 4 4 4 4
************
************
************
************
scc
VESSELS
SCC =
VESSELS
bO
SCC =
VESSELS
bl
SCC =
VESStLS
O
I
-p-
**
**
**
**
**
***
***
***
*****
** ** ****
»**** **** *
*
*
**
**
***
***
***
*****
*
**
***************
*******************
*******************
*********** **** *****
*********************
+ f 4 4
**
**
** ********
**************
**************
***************
***************
*****************
* *******************
** ********************
************************
***************
***************
***************
*********** ****
***************
***************
***************
***************
***************
***************
***************
***************
4 4 4
************************
************************
************************
************************
SCC =
GAS MARKE'ltb
SCC = bb
UHFAVtU ROAD TRAVEL
SCC = 56
UNPAVED AlhSThlP LTO'S
SCC =
FOHtSl KILO t lli
bO
Figure C-4. (continued)
-------
SUNDAY
IIOtlhLT DEADS
***»****•*»*•*•
***************
*•****•***•*»•*
***************
***************
******* ********
***************
***************
*********** ****
***************
***************
***************
*********** ****
4 4 4 4. 4.
SCC = 61
flANAGLD BURNING
***************
***************
***************
***************
***************
***************
***************
***************
***************
***************
***************
***************
***************
4 4 4 4
SCC = b2
AGh FIELD BURNING
************************
************************
************************
************************
***** *******************
************************
************************
************************
4 4 4 4 4
SCC = b«
S1KUCTORAL FIRES
*******•***•**•••••**•*•
*»»»•*«***•*•»•*,*,•»„,
*****•**•*»****»*»******
****•*****•******»•****•
***••*********•*•**»****
•*****•*•**»•»*****»**•*
A***********************
4 4 4 + 4
SCC = 71
fltLU <.l-fLl(.J.llUN
O
************************
************************
************************
»**«*»*»«»«***«***«*»*»*
************************
************************
I ---- 4 ----- 4 ----- 4 ----- »
************************
************************
************************
************************
************************
************************
************************
************************
4 ---- 4 ----- 4 ----- 4 ----- 4
i.CL = 7^
HANU11E F1LLU APPL1CM1OM
HCC = 7J
BANURt FIELD APPL1CA110H
SCC = 7H
BANURt FitLD API'LlCAliOH
SCC = /i
HAN UK t Plt-Li, AM-LiCAllUN
Figure C-4. (continued)
-------
(pamrpuoo)
HTV-IIH «ooq run?
9NUVOD
rn
DDS
fHH SOIlSVld QMV
in = DD<;
Oft
S11V DTHJVH5)
= D3S
**********
**********
**********
**********
**********
*•*•••****
• *••»»*•**
»******•••
*•**•***»•
••*••**•**
»*•*»»****
**************
**************
**************
**************
**************
**************
**************
**************
**************
**************
**************
*********** ***
**************
**************
************************
************************
************************
************************
***********
***********
***********
***********
***********
»*»»*****»*
** *********
** *********
***********
***********
****************
****************
****************
****************
****************
***********
**********
*•* **4•***
**********
**********
**********
ro
= D.T;
» • , »_
*»»**•*•***
***** ******
***********
***********
***********
>«*
**«•»***»**
***********
***********
***********
3NISV3HSTO
t » 1 + »
*****************
*****************
*****************
*****************
*****************
*****************
*****************
***********
***********
***********
***********
***********
***********
***********
***********
sim cmj
DD
-------
(pamrpuoo)
ifi
3ns
************************
************************
***********
***********
OJH dinoa <;NVIU HHH.IO
06 = ODS
************************
************************
************************
************************
***********
fi8
noon
= 33S
************************
************************
************************
************************
***********
***********
***********
***********
***********
***********
***********
***********
***********
***********
***********
***********
iiAV IHnlTNHfU
no = nos
+ 1 1 1 +
************************
************************
************************
*** ********
*** ********
***********
*** ********
*** ********
*** ********
**•********
*** ********
***********
o
Z.B
* *******
***********
********* ***************
************************
************************
************************
***********
***********
***********
************************
************************
************************
***********
***********
************************
************************
************************
************************
***********
*** ** **** **
********* **
***********
***********
***********
***********
***********
***********
***********
***********
***********
*»* ********
*** ********
SNV3li IIHQOH
-------
SUNDAY
HOURLY KEAHS
********tt4
******** ***
***********
***********
***********
***********
***********
******** ***
k**
***********»*******»** + *
************************
************************
4 ---- 4 --- 4 ----- 4 ----- 4
SHIP bLLG AND RhPAIR
************************
************************
************************
*********************** *
4 4 + 4 4
SCC = yj
HISC INDUSTRIAL (IFG
***********
****** *****
***********
***********
***********
********** *
***********
************************
************************
************************
************************
4 4 4 4 4
SCC = 9M
HISC INUUST SOLVENT USE
***********
***********
************************
************************
4 4 4 4 4
scc = yb
DISC NUN1NU bOLVtNi USfc
o
I
*********
*********
***•»**•*
*********
*********
*********
* ******** **** »
********* «*** *
************* *
********* **** *
********* **** «
******************
********************
************************
** • ******** **** **** *****
************************
************************
4 4 4 4 4
scc = y«.
BINGE OllLIlItlS - COAL
**************
**************
**************
**************
**************
******************
********************
************************
************************
************************
************************
4 4 4 4 4
scc = y?
MINOR UTILITIES - OIL
*********** ***
4*************
**************
**************
**************
******************
********************
************************
************************
************************
************************
4 4 4 4 4
see - ye
MINOR UTILITIES - GAS
scc - *y
H1NOH POINT bOUHCti
Figure C-4. (continued)
-------
-------
APPENDIX D
LISTING OF SOURCE CLASSIFICATION CODES FOR
U.S. AND CANADIAN POINT AND AREA SOURCES
D-l
-------
TABLE D-l,
SCC
101001
101002
101003
101004
101005
101006
101007
101008
101009
101010
101011
101012
101013
102001
102002
102003
102004
102005
102006
102007
102008
102009
102010
102011
102012
102013
102014
103001
103002
103003
103004
103005
103006
103007
103009
103010
103012
103013
105001
105002
201001
201002
201009
201010
202001
202002
202003
202004
202005
202009
NEDS SOURCE CLASSIFICATION CODES FOR U.S. AND
CANADIAN POINT SOURCES (SIX-DIGIT LEVEL)
SOURCE DESCRIPTION/PROCESS
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
EXTCOMB BOILER
INTERNLCOMBUSTION
INTERNLCOMBUSTION
INTERNLCOMBUSTION
INTERNLCOMBUSTION
INTERNLCOMBUSTION
INTERNLCOMBUSTION
INTERNLCOMBUSTION
INTERNLCOMBUSTION
INTERNLCOMBUSTION
INTERNLCOMBUSTION
ELECTRIC GENERATN
ELECTRIC GENERATN
ELECTRIC GENERATN
ELECTRIC GENERATN
ELECTRIC GENERATN
ELECTRIC GENERATN
ELECTRIC GENERATN
ELECTRIC GENERATN
ELECTRIC GENERATN
ELECTRIC GENERATN
ELECTRIC GENERATN
ELECTRIC GENERATN
ELECTRIC GENERATN
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
COMMERCL-INSTUTNL
COMMERCL-INSTUTNL
COMMERCL-INSTUTNL
COMMERCL-INSTUTNL
COMMERCL-INSTUTNL
COMMERCL-INSTUTNL
COMMERCL-INSTUTNL
COMMERCL-INSTUTNL
COMMERCL-INSTUTNL
COMMERCL-INSTUTNL
COMMERCL-INSTUTNL
SPACE HEATER
SPACE HEATER
ELECTRIC GENERATN
ELECTRIC GENERATN
ELECTRIC GENERATN
ELECTRIC GENERATN
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
ANTHRACITE COAL
BITUMINOUS COAL
LIGNITE
RESIDUAL OIL
DISTILLATE OIL
NATURAL GAS
PROCESS GAS
COKE
WOOD/BARK WASTE
LIQ PETROLEUM GAS
BAGASSE
SLD WASTE-SPECIFY
LIQ WASTE-SPECIFY
ANTHRACITE COAL
BITUMINOUS COAL
LIGNITE
RESIDUAL OIL
DISTILLATE OIL
NATURAL GAS
PROCESS GAS
COKE
WOOD/BARK WASTE
LIQ PETROLEUM GAS
BAGASSE
SLD WASTE-SPECIFY
LIQ WASTE-SPECIFY
CO BOILER
ANTHRACITE COAL
BITUMINOUS COAL
LIGNITE
RESIDUAL OIL
DISTILLATE OIL
NATURAL GAS
PROCESS GAS
WOOD/BARK WASTE
LIQ PETROLEUM GAS
SLD WASTE-SPECIFY
LIQ WASTE-SPECIFY
INDUSTRIAL
COMMERCL-INSTUTNL
DIST.OIL/DIESEL
NATURAL GAS
KERONAPTHA JET FL
GEYSERS/GEOTHERML
DIST.OIL/DIESEL
NATURAL GAS
GASOLINE
LARGE BORE ENGINE
RESIDUAL/CRUDEOIL
KERONAPTHA JET FL
D-2
-------
sec
TABLE D-l (continued)
SOURCE DESCRIPTION/PROCESS
202010 INTERNLCOMBUSTION
203001 INTERNLCOMBUSTION
203002 INTERNLCOMBUSTION
203003 INTERNLCOMBUSTION
203010 INTERNLCOMBUSTION
204001 INTERNLCOMBUSTION
204002 INTERNLCOMBUSTION
204003 INTERNLCOMBUSTION
204004 INTERNLCOMBUSTION
288888 INTERNLCOMBUSTION
301001 CHEMICAL MFC
301003 CHEMICAL MFC
301005 CHEMICAL MFC
301006 CHEMICAL MFC
301007 CHEMICAL MFC
301008 CHEMICAL MFC
301009 CHEMICAL MFC
301010 CHEMICAL MFC
301011 CHEMICAL MFC
301012 CHEMICAL MFC
301013 CHEMICAL MFC
301014 CHEMICAL MFC
301015 CHEMICAL MFC
301016 CHEMICAL MFC
301017 CHEMICAL MFC
301018 CHEMICAL MFC
301019 CHEMICAL MFC
301020 CHEMICAL MFC
301021 CHEMICAL MFC
301022 CHEMICAL MFC
301023 CHEMICAL MFC
301024 CHEMICAL MFC
301025 CHEMICAL MFC
301026 CHEMICAL MFC
301027 CHEMICAL MFC
301028 CHEMICAL MFC
301029 CHEMICAL MFC
301030 CHEMICAL MFC
301031 CHEMICAL MFC
301032 CHEMICAL MFC
301033 CHEMICAL MFC
301034 CHEMICAL MFC
301035 CHEMICAL MFC
301038 CHEMICAL MFC
301039 CHEMICAL MFC
301040 CHEMICAL MFC
301041 CHEMICAL MFC
301042 CHEMICAL MFC
301043 CHEMICAL MFC
301045 CHEMICAL MFC
INDUSTRIAL
COMMERCL-INSTUTNL
COMMERCL-INSTUTNL
COMMERCL-INSTUTNL
COMMERCL-INSTUTNL
ENGINE TESTING
ENGINE TESTING
ENGINE TESTING
ENGINE TESTING
FUGITIVE EMISSION
ORGANIC CHEMICALS
AGRICULTURAL CHEM
CARBON BLACK
ORGANIC CHEMICALS
INORGANIC CHEMCLS
INORGANIC CHEMCLS
SOAP/DETERGENTS
EXPLOSIVES
INORGANIC CHEMCLS
INORGANIC CHEMCLS
AGRICULTURAL CHEM
PAINT MFC
VARNISH MFC
AGRICULTURAL CHEM
AGRICULTURAL CHEM
PLASTICS PRODN
ORGANIC CHEMICALS
PRINTING INK MFC
INORGANIC CHEMCLS
INORGANIC CHEMCLS
INORGANIC CHEMCLS
PLASTICS PRODN
PLASTICS PRODN
PLASTICS PRODN
AGRICULTURAL CHEM
AGRICULTURAL CHEM
AGRICULTURAL CHEM
AGRICULTURAL CHEM
ORGANIC CHEMICALS
INORGANIC CHEMCLS
AGRICULTURAL CHEM
ORGANIC CHEMICALS
INORGANIC CHEMCLS
INORGANIC CHEMCLS
INORGANIC CHEMCLS
AGRICULTURAL CHEM
EXPLOSIVES
ORGANIC CHEMICALS
ORGANIC CHEMICALS
AGRICULTURAL CHEM
PROPANE
DIST.OIL/DIESEL
NATURAL GAS
GASOLINE
PROPANE
AIRCRAFT
ROCKET MOTOR
TURBINE
RECIPROCATING
NOT CLASSIFIED
ADIPIC ACID PROD
AMMONIA
CHANNEL PROCESS
CHARCOAL
CHLORINE
CHLORO-ALKALI
SOAP/DETERGENTS
TRINITROTOLUENE
HYDROCHLORIC ACID
HYDROFLUORIC ACID
NITRIC ACID
MIXING/BLENDING
BODYING OIL
PHOS ACD/WET PROC
PHOS ACID THERMAL
POLYVINYL CHLORID
PHTHALIC ANHYDRID
VEHICLE COOKING
SODIUM CARBONATE
H2S04-CHAMBER
H2S04-CONTACT
SYNTHC ORGNC FIBR
CELLULOSIC FIBER
SYNTHETIC RUBBER
FERTILIZ AMONNITR
NRM SPRPHSPHATE
TRPL SPRPHSPHATE
AMMONM PHOSPHATES
TEREPHTHALIC ACID
SULFUR(ELEMENTAL)
PESTICIDES
ANILINE
TI02 PIGMENT
SODIUM BICARBNATE
HYDROGEN CYANIDE
UREA
NITROCELLULOSE
LEAD ALKYL-NA/PB
LEAD ALKYLS
ORGANIC FERTILIZR
D-3
-------
sec
TABLE D-l (continued)
SOURCE DESCRIPTION/PROCESS
301050
301060
301070
301091
301100
301111
301120
301121
301124
301125
301126
301127
301130
301132
301133
301137
301140
301152
301153
301156
301157
301158
301167
301169
301174
301176
301181
301190
301195
301197
301202
301205
301206
301210
301211
301250
301251
301252
301253
301254
301258
301301
301302
301303
301304
301305
301800
301810
301820
301830
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
ORGANIC CHEMICALS
PHARMACEUTICALS
INORGANIC CHEMCLS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
INORGANIC CHEMCLS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
AGRICULTURAL CHEM
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ORGANIC CHEMICALS
ADHESIVES
GENERAL PROCESSES
GENERAL PROCESSES
KETONE PRODUCTION
MALEIC ANHYDRIDE
ASBESTOS CHEMICAL
FORMALDEHYDE
ORGNC DYE/PIGMENT
CHLOROPRENE
ETHYLENE DICHLORD
ORGANOHALOGENS
FLUOROCARBONS
AMMONIUM SULFATE
ORGANIC ACIDS PRO
ACETIC ANHYDRIDE
ESTERS PRODUCTN
ACETYLENE PRODN
BISPHENOL A
BUTADIENE
CUMENE
CYCLOHEXANE
CYCLOHEXANONE/CYC
VINYL ACETATE
ETHYLBENZENE
ETHYLENE OXIDE
GLYCERIN(GLYCERL)
TOLUENE DIISOCYNT
METHYL METHACRYLT
NITROBENZENE
ETHYLENE PRODCTN
PHENOL
PROPYLENE OXIDE
STYRENE
CAPROLACTUM
LINEAR ALKYLBENZE
METHANOL PRODCTN
ETHYLENE GLYCOL
ETHERS
GLYCOL ETHERS
NITRILES PROD
BENZENE
CHLOROBENZENE
CARBON TETRACHLOR
ALLYL CHLORIDE
ALLYL ALCOHOL
EPICHLOROHYDRIN
GENERAL PROCESSES
GENERAL PROCESSES
GENERAL PROCESSES
GENERAL PROCESSES
D-4
-------
sec
301840
301870
301875
301885
301888
301900
301999
302001
302002
302003
302004
302005
302006
302007
302008
302009
302010
302011
302012
302013
302014
302015
302016
302017
302018
302019
302020
302021
302022
302026
302028
302030
302031
302032
302033
302036
302038
302888
302900
302999
303000
303001
303002
303003
303004
303005
303006
303007
303008
303009
TABLE D-l (continued)
SOURCE DESCRIPTION/PROCESS
CHEMICAL MFC
INORGNC CHEM STRG
INORGNC CHEM STRG
INORGNC CHEM STRG
CHEMICAL MFC
CHEMICAL MFC
CHEMICAL MFC
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
FOOD/AGRICULTURE
MINING OPERATIONS
PRIMARY METALS
PRIMARY METALS
PRIMARY METALS
PRIMARY METALS
PRIMARY METALS
PRIMARY METALS
PRIMARY METALS
PRIMARY METALS
PRIMARY METALS
ORGANIC CHEMICALS
FIXED ROOF TANKS
FLOAT ROOF TANKS
PRESSURE TANKS
FUGITIVE EMISSION
FUEL-FIRED EQPMNT
MISCELLANEOUS
ALFALFA DEHYDRATI
COFFEE ROASTING
COFFEE PRODUCTS
AGRIC. SERVICES
GRAIN ELEVATORS
GRAIN ELEVATORS
GRAIN MILLING
FEED MANUFACTURE
FERMENTATION
FERMENTATION
FERMENTATION
FISH PROCESSING
MEAT SMOKING
STARCH MFC
SUGAR CANE PROCES
SUGAR BEET PROCES
PEANUT PROCESSING
CANDY MANUFACTURE
VEG OIL PROCESSNG
AGRIC.PRODUCTION
POULTRY/EGG PROD
AGRIC.PRODUCTION
AGRIC.PRODUCTION
AGRIC.PRODUCTION
DAIRY PRODUCTS
GRAIN ELEVATORS
BAKERIES
TOBACCO PRODUCTS
DEEP FAT FRYING
ANIMAL/POLTRY RND
FUGITIVE EMISSION
FUEL-FIRED EQPMNT
MISCELLANEOUS
METAL ORE MINING
ALUMINUM
ALUMINUM
IRON & STEEL
IRON & STEEL
COPPER SMELTING
FERROALLOY
FERROALLOY
IRON & STEEL
IRON & STEEL
GENERAL PROCESSES
HYDROCHLORIC ACID
CARBON DISULFIDE
AMMONIA
NOT CLASSIFIED
PROCESS HEATERS
NOT CLASSIFIED
GENERAL
ROASTER
INSTANT COFFEE
COTTON GINNING
TERMINAL ELEVATOR
COUNTRY ELEVATORS
CORN MEAL
BARLEY FEED
BEER PRODUCTION
WHISKEY PRODUCTN
WINE PRODUCTION
FISH MEAL
COMBINED OPERATNS
COMBINED OPERATNS
GENERAL
DRYER
NOT CLASSIFIED
NOT CLASSIFIED
CORN OIL
BEEF CATTLE
MANURE HANDLING
COTTON-ACID DELIN
SEED PROCESSING
MUSHROOM GROWING
MILK
EXPORT GRAIN ELEV
BREAD BAKING
NOT CLASSIFIED
COOKING VATS
RENDERING
NOT CLASSIFIED
PROCESS HEATERS
NOT CLASSIFIED
BAUXITE
ELECTRO-REDUCTION
HYDROXIDE CALCING
BY-PRODUCT COKE
BEEHIVE COKE
MULTIPLE HEARTH
OPEN FURNACE
SEMICOVERED FURNC
BLAST FURNACE
STEEL FURNACES
D-5
-------
sec
TABLE D-l (continued)
SOURCE DESCRIPTION/PROCESS
303010 PRIMARY METALS
303011 MINING OPERATIONS
303012 MINING OPERATIONS
303013 MINING OPERATIONS
303014 MINING OPERATIONS
303023 MINING OPERATIONS
303024 MINING OPERATIONS
303030 PRIMARY METALS
303888 PRIMARY METALS
303900 PRIMARY METALS
303999 PRIMARY METALS
304001 SECONDARY METALS
304002 SECONDARY METALS
304003 PRIMARY METALS
304004 SECONDARY METALS
304005 ELECTRICAL EQPMNT
304006 PRIMARY METALS
304007 PRIMARY METALS
304008 SECONDARY METALS
304009 PRIMARY METALS
304010 PRIMARY METALS
304020 ELECTRICAL EQPMNT
304022 SECONDARY METALS
304040 SECONDARY METALS
304049 SECONDARY METALS
304050 SECONDARY METALS
304888 SECONDARY METALS
304900 SECONDARY METALS
304999 SECONDARY METALS
305001 PETROLEUM INDRY
305002 PETROLEUM INDRY
305003 MINERAL PRODUCTS
305004 MINERAL PRODUCTS
305005 MINERAL PRODUCTS
305006 MINERAL PRODUCTS
305007 MINERAL PRODUCTS
305008 MINERAL PRODUCTS
305009 MINERAL PRODUCTS
305010 MINING OPERATIONS
305011 MINERAL PRODUCTS
305012 MINERAL PRODUCTS
305013 MINERAL PRODUCTS
305014 MINERAL PRODUCTS
305015 MINERAL PRODUCTS
305016 MINERAL PRODUCTS
305017 MINERAL PRODUCTS
305018 MINERAL PRODUCTS
305019 MINING OPERATIONS
305020 MINING OPERATIONS
305021 MINING OPERATIONS
LEAD SMELTING
METAL ORE MINING
METAL ORE MINING
METAL ORE MINING
METAL ORE MINING
METAL ORE MINING
METAL ORE MINING
ZINC SMELTING
FUGITIVE EMISSION
FUEL-FIRED EQPMNT
MISCELLANEOUS
SEC. ALUMINUM
SEC. COPPER
IRON/STEEL FOUNDY
SEC. LEAD
LEAD BATTERY MFC
MAGNESIUM
IRON/STEEL FOUNDY
SECONDARY ZINC
IRON/STEEL FOUNDY
NICKEL
FURNACE ELECTRODE
METAL HEAT TREATG
METALLIC COATING
MISC CAST/FABRCTN
MISC CAST/FABRCTN
FUGITIVE EMISSION
FUEL-FIRED EQPMNT
MISCELLNNEOUS
ASPHALT ROOFING
ASPHALT CONCRETE
BRICK MFG
CALCIUM CARBIDE
CASTABLE REFRACTY
CEMENT MFG
CEMENT MFG
CERAMIC CLAY MFG
CLAY/FLYASH SINTR
COAL CLEANING
CONCRETE BATCHING
FIBERGLASS
FRIT MFG
GLASS MFG
GYPSUM MFG
LIME MFG
MINERAL WOOL
PERLITE MFG
NONMETALLIC MINRL
NONMETALLIC MINRL
NONMETALLIC MINRL
SINTERING
MOLYBEDENUM
TITANIUM ORE
GOLD MINING
BARIUM ORE
TACONITE IRON ORE
LOW MOISTURE ORE
ROASTING
NOT CLASSIFIED
PROCESS HEATERS
NOT CLASSIFIED
SWEATING FURNACE
ELEC INDUCTION FN
GRAY IRON FOUNDRY
KETTLE REFINING
OVERALL PROCESS
POT FURNACE
STEEL FOUNDRY
RETORT FURNACE
MALLEABLE IRON
FLUX FURNACE
CALCINATION
FURNACE
LEAD CABLE COATNG
WAX BURNOUT OVEN
NOT CLASSIFIED
NOT CLASSIFIED
PROCESS HEATERS
NOT CLASSIFIED
ASPHALT BLOWING
ROTARY DRYER
RAW MATERIAL
ELECTRIC FURNACE
RAW MATERIAL
DRY PROCESS
WET PROCESS
DRYING
FLYASH
THERMAL DRYER
GENERAL
WOOL-TYPE FIBER
ROTARY FURNACE
SODA LIME
ROTARY ORE DRYER
PRIMARY CRUSHING
CUPOLA
VERTICAL FURNACE
PHOSPHATE ROCK
STONE QUARRYING
SALT MINING
D-6
-------
sec
TABLE D-l (continued)
SOURCE DESCRIPTION/PROCESS
305022 MINING OPERATIONS
305024 MINING OPERATIONS
305025 MINING OPERATIONS
305026 MINING OPERATIONS
305030 MINERAL PRODUCTS
305031 MINING OPERATIONS
305032 MINING OPERATIONS
305033 MINING OPERATIONS
305040 MINING OPERATIONS
305100 MINERAL PRODUCTS
305101 MINERAL PRODUCTS
305102 MINERAL PRODUCTS
305103 MINERAL PRODUCTS
305104 MINERAL PRODUCTS
305105 MINERAL PRODUCTS
305150 MINERAL PRODUCTS
305888 MINERAL PRODUCTS
305900 MINERAL PRODUCTS
305999 MINERAL PRODUCTS
306001 PETROLEUM INDRY
306002 PETROLEUM INDRY
306003 PETROLEUM INDRY
306004 PETROLEUM INDRY
306005 PETROLEUM INDRY
306006 PETROLEUM INDRY
306007 PETROLEUM INDRY
306008 PETROLEUM INDRY
306009 PETROLEUM INDRY
306010 PETROLEUM INDRY
306011 PETROLEUM INDRY
306012 PETROLEUM INDRY
306014 PETROLEUM INDRY
306015 PETROLEUM INDRY
306099 PETROLEUM INDRY
306100 PETROLEUM INDRY
306888 PETROLEUM INDRY
306999 PETROLEUM INDRY
307001 PULP & PAPER
307002 PULP & PAPER
307003 PULP & PAPER
307004 PULP & PAPER
307005 WOOD PRODUCTS
307007 WOOD PRODUCTS
307008 WOOD PRODUCTS
307011 PULP & PAPER
307013 PULP & PAPER
307020 WOOD PRODUCTS
307030 WOOD PRODUCTS
307888 WOOD PRODUCTS
307900 WOOD PRODUCTS
NONMETALLIC MINRL
NONMETALLIC MINRL
NONMETALLIC MINRL
NONMETALLIC MINRL
CERAMIC ELEC PRTS
NONMETALLIC MINRL
NONMETALLIC MINRL
NONMETALLIC MINRL
UNSPECIFIED ORE
BULK MATERIALS
BULK MATERIALS
BULK MATERIALS
BULK MATERIALS
BULK MATERIALS
BULK MATERIALS
NONMETALLIC MINRL
FUGITIVE EMISSION
FUEL-FIRED EQPMNT
MISCELLANEOUS
PETROLEUM REFNG
PETROLEUM REFNG
PETROLEUM REFNG
PETROLEUM REFNG
FUGITIVE HC EMIS
PETROLEUM REFNG
PETROLEUM REFNG
FUGITIVE HC EMIS
PETROLEUM REFNG
PETROLEUM REFNG
PETROLEUM REFNG
PETROLEUM REFNG
PETROLEUM REFNG
PETROLEUM REFNG
PETROLEUM REFNG
LUBE OIL MFC
FUGITIVE EMISSION
MISCELLANEOUS
KRAFT PULPING
SULFITE PULPING
SEMICHEMICAL PULP
PULPBOARD
WOOD PRESS TREAT
PLYWOOD/PARTBOARD
SAWMILL OPERATION
PAPER COATING
MISC. PAPER PROD
FURNITURE MFC
MISCELLANEOUS
FUGITIVE EMISSION
FUEL FIRED EQPMNT
POTASH PRODUCTION
MAGNESIUM CRBNATE
SAND/GRAVEL
DIATOMACOUS EARTH
NOT CLASSIFIED
ASBESTOS MINING
ASBESTOS MILLING
VERMICULITE
SEE COMMENT
ELEVATORS
CONVEYORS
STOAGE BINS
OPEN STOCKPILES
UNLOADING OPERATN
LOADING OPERATION
CALCINING-GENERAL
NOT CLASSIFIED
PROCESS HEATERS
NOT CLASSIFIED
PROCESS HEATERS
CATALYTIC CRACKNG
CATALYTIC CRACKNG
SLOWDOWN SYSTEM
PROCESS DRAINS
VACUUM DISTILATN
COOLING TOWERS
PIPELINE
FLARES
SLUDGE CONVERTER
ASPHALT BLOWING
FLUID COKING
PETROLEUM COKE
BAUXITE BURNING
INCINERATORS
GENERAL
NOT CLASSIFIED
NOT CLASSIFIED
DIGESTOR/BLOW TNK
DIGESTER/BLOW PIT
DIGESTER/BLOW PIT
PAPERBOARD
CREOSOTE
VENEER DRYERS
LOG DEBARKING
EXTRUSION COATING
INSULATION FROM
NOT CLASSIFIED
WOODWASTE STORAGE
NOT CLASSIFIED
PROCESS HEATERS
D-7
-------
sec
307999
308001
308005
308006
308007
308900
308999
309001
309002
309003
309010
309011
309015
309016
309020
309025
309030
309040
309060
309888
309900
309999
310001
310002
310004
310888
311001
311002
312999
313070
313900
313999
314009
314010
314011
314999
315010
315020
320999
330001
330002
330003
330004
330005
330888
360001
390001
390002
390003
390004
TABLE D-l (continued)
SOURCE DESCRIPTION/PROCESS
WOOD PRODUCTS
RUBBER/PLASTICS
RUBBER/PLASTICS
RUBBER/PLASTICS
RUBBER/PLASTICS
RUBBER/PLASTICS
RUBBER/PLASTICS
FABRICATED METALS
FABRICATED METALS
FABRICATED METALS
FABRICATED METALS
FABRICATED METALS
FABRICATED METALS
FABRICATED METALS
FABRICATED METALS
FABRICATED METALS
FABRICATED METALS
FABRICATED METALS
FABRICATED METALS
FABRICATED METALS
FABRICATED METALS
FABRICATED METALS
OIL & GAS PRODN
OIL & GAS PRODN
OIL & GAS PRODN
OIL & GAS PRODN
CONSTRUCTION
CONSTRUCTION
MACHINERY
ELECTRICAL EQPMNT
ELECTRICAL EQPMNT
ELECTRICAL EQPMNT
TRANSPORTN EQPMNT
TRANSPORTN EQPMNT
TRANSPORTN EQPMNT
TRANSPORTN EQPMNT
MISC. INDUSTRIES
MISC. INDUSTRIES
LEATHER PRODUCTS
TEXTILE PRODUCTS
RUBBER/PLASTICS
TEXTILE PRODUCTS
TEXTILE PRODUCTS
TEXTILE PRODUCTS
TEXTILE PRODUCTS
PRINTING/PUBLISH
INDUSTRIAL PROCES
INDUSTRIAL PROCES
INDUSTRIAL PROCES
INDUSTRIAL PROCES
MISCELLANEOUS
TIRE MFC
TIRE RETREADING
MISC.RUBBER PROD
FAB. PLASTIC PROD
FUEL FIRED EQPMNT
MISCELLANEOUS
IRON/STEEL
ABRASIVE BLASTING
ABRASIVE CLEANING
ELECTROPLATING
CONVERSION COATNG
CHEMICAL MILLING
PIPE COATING
CAN MAKING OPRNS
DRUMS/BARRELS
MACHINING OPRNS
METAL DEPOSITION
PORCELAIN ENAMEL/
FUGITIVE EMISSION
FUEL FIRED EQPMNT
MISCELLANEOUS
CRUDE OIL PRODN
NATURAL GAS PRODN
FUEL-FIRED EQPMNT
FUGITIVE EMISSION
BLDG CONTRACTORS
SPL TRADE CONTRCT
MISCELLANEOUS
WINDINGS RECLAMTN
FUEL FIRED EQPMNT
MISCELLANEOUS
GENERAL PROCESSES
BRAKE SHOE DEBOND
AUTO BODY SALVAGE
MISCELLANEOUS
PHOTOGRAPHIC EQPT
HOSPITALS
MISCELLANEOUS
GENERAL FABRICS
RUBBERIZED FABRIC
CARPET OPERATNS
FABRIC FINISHING
APPAREL
FUGITIVE EMISSION
TYPESETTING
INPROCESS FUEL
INPROCESS FUEL
INPROCESS FUEL
INPRO'CESS FUEL
NOT CLASSIFIED
UNDERTREAD & SIDE
TIRE BUFFING
NOT CLASSIFIED
PLASTICS MACHINNG
PROCESS HEATERS
NOT CLASSIFIED
NOT CLASSIFIED
OF METAL PARTS
OF METAL PARTS
ENTIRE PROCESS
ALKALINE CLEANING
OF METAL PARTS
ASPHALT DIPPING
NOT CLASSIFIED
DRUM CLEANING
GRINDING
METALLIZING(WIRE
CERAMIC GLAZE
NOT CLASSIFIED
PROCESS HEATERS
NOT CLASSIFIED
COMPLETE WELL
GAS SWEETENING
PROCESS HEATERS
NOT CLASSIFIED
NOT CLASSIFIED
NOT CLASSIFIED
NOT CLASSIFIED
INCINERATOR OVEN
PROCESS HEATERS
NOT CLASSIFIED
SOLDER JOINT
INCINERATOR OVEN
BODY SHREDDING
NOT CLASSIFIED
PHOTOCOPY MACHINE
STERILIZATION
NOT CLASSIFIED
NOT CLASSIFIED
IMPREGNATION
NOT CLASSIFIED
NOT CLASSIFIED
NOT CLASSIFIED
NOT CLASSIFIED
LEAD REMELTING
ANTHRACITE COAL
BITUMINOUS COAL
LIGNITE
RESIDUAL OIL
D-8
-------
sec
390005
390006
390007
390008
390009
390010
390012
390013
399900
399999
401001
401002
401003
401004
401888
402001
402002
402003
402004
402005
402006
402007
402008
402009
402010
402011
402012
402013
402014
402015
402016
402017
402018
402019
402020
402021
402022
402023
402024
402025
402026
402888
402900
402999
403001
403002
403003
403010
403011
403012
TABLE D-l (continued)
SOURCE DESCRIPTION/PROCESS
INDUSTRIAL PROCES
INDUSTRIAL PROCES
INDUSTRIAL PROCES
INDUSTRIAL PROCES
INDUSTRIAL PROCES
INDUSTRIAL PROCES
INDUSTRIAL PROCES
INDUSTRIAL PROCES
INDUSTRIAL PROCES
INDUSTRIAL PROCES
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
ORGANIC SOLVENT
PETROLEUM STORAGE
PETROLEUM STORAGE
PETROLEUM STORAGE
PETROLEUM STORAGE
PETROLEUM STORAGE
PETROLEUM STORAGE
INPROCESS FUEL
INPROCESS FUEL
INPROCESS FUEL
INPROCESS FUEL
INPROCESS FUEL
INPROCESS FUEL
INPROCESS FUEL
INPROCESS FUEL
MIS IND-FUEL EQPT
MISCELLANEOUS
DRY CLEANING
VAPOR DECREASING
COLD CLEANING
TEXTILE MFC
FUGITIVE EMISSION
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
SURFACE COATING
FIXED ROOF TANKS
FLOAT ROOF TANKS
VAR.VAPOR SP.TNKS
FIXED ROOF TANKS
FLOAT ROOF TANKS
VAR.VAPOR SP.TNKS
DISTILLATE OIL
NATURAL GAS
PROCESS GAS
COKE
WOOD
LPG
SOLID WASTE FUEL
LIQUID WASTE FUEL
PROCESS HEATERS
NOT CLASSIFIED
PERCHLOROETHYLENE
OPEN-TOP
METHANOL
FABRIC SCOURING
NOT CLASSIFIED
PAINT-GENERAL
PAINT-GENERAL
VARNISH/SHELLAC
LACQUER
ENAMEL
PRIMER
ADHESIVE
COATING OVEN
THINNING SOLVENT
OVEN HEATER
FABRIC COATING
FABRIC DYEING
PAPER COATING
LARGE APPLIANCES
MAGNET WIRE
AUTOS/LIGHT TRUCK
CAN COATING
COIL COATING
WOOD FURNITURE
METAL FURNITURE
FLATWOOD PRODUCTS
PLASTIC PARTS
LARGE SHIPS
LARGE AIRCRAFT
MISC.METAL PARTS
STEEL DRUMS
FUGITIVE EMISSION
FLARES
MISCELLANEOUS
BREATHING LOSS
STAND STG LOSS
WORKING LOSS
GASOLINE-RVP 13
GASOLINE-RVP 13
GASOLINE-RVP 13
D-9
-------
sec
403888
403999
404001
404002
404003
404004
405001
405002
405003
405004
405005
405006
405007
405888
406001
406002
406003
406004
406888
407004
407008
407016
407020
407032
407036
407040
407044
407048
407052
407056
407060
407064
407068
407076
407080
407084
407172
407176
407180
407208
407220
407228
407232
407816
407820
407824
407832
407848
407860
407864
TABLE D-l (continued)
SOURCE DESCRIPTION/PROCESS
PETROLEUM STORAGE
PETROLEUM STORAGE
BULK TERMINALS
BULK PLANTS
OIL & GAS PRODN
PETROLEUM STORAGE
PRINTING/PUBLISH
PRINTING/PUBLISH
PRINTING/PUBLISH
PRINTING/PUBLISH
PRINTING/PUBLISH
PRINTING/PUBLISH
PRINTING/PUBLISH
PRINTING/PUBLISH
PETROLEUM MARKTNG
PETROLEUM MARKTNG
PETROLEUM MARKTNG
PETROLEUM MARKTNG
PETROLEUM MARKTNG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
ORGANIC CHEM STRG
FUGITIVE EMISSION
MISCELLANEOUS
FIXED ROOF TANKS
FIXED ROOF TANKS
CRUDE OIL STORAGE
UNDERGROUND TANKS
PRINTING PROCESS
PRINTING PROCESS
PRINTING PROCESS
PRINTING PROCESS
PRINTING PROCESS
PRINTING PROCESS
PRINTING PROCESS
FUGITIVE EMISSION
TANK CARS/TRUCKS
MARINE VESSELS
SERVICE STATIONS
SERVICE STATIONS
FUGITIVE EMISSION
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FIXED ROOF TANKS
FLOAT ROOF TANKS
FLOAT ROOF TANKS
FLOAT ROOF TANKS
FLOAT ROOF TANKS
FLOAT ROOF TANKS
FLOAT ROOF TANKS
FLOAT ROOF TANKS
PRESSURE TANKS
PRESSURE TANKS
PRESSURE TANKS
PRESSURE TANKS
PRESSURE TANKS
PRESSURE TANKS
PRESSURE TANKS
NOT CLASSIFIED
NOT CLASSIFIED
GASOLINE-RVP 13
GASOLINE-RVP 13
FIXED ROOF TANK
GASOLINE-RVP 13
DRYER
LETTER PRESS
FLEXOGRAPHIC
LITHOGRAPHIC
ROTOGRAVURE
INK MIXING
SOLVENT STORAGE
NOT CLASSIFIED
GASOLINE-SPLASH
GASOLINE SHIP
STAGE I
STAGE II
NOT CLASSIFIED
ACETIC ANHYDRIDE
N-BUTYL ALCOHOL
N-DECANE
DODECENE
ANILINE
BENZENE
ACETIC ACID
BUTYL ACETATE
MTHL-TRT-BTYL ETH
BUTYL CARBITOL
1,4-BUTANEDIOL
BENZYL CHLORIDE
MDI
CYCLOHEXANONE
ACRYLONITRILE
NITROBENZENE
NONYPHENOL
ACETALDEHYDE
CYCLOHEXANE
ISOPRENE
ETHYL ETHER
CARBON TETRACHLRD
ACETONE
ETHYL MERCAPTAN
ETHANE
1,3-BUTADIENE
ACETYLENE
METHYLAMINE
ETHYLENE OXIDE
ETHYL CHLORIDE
METHYL ISOCYANATE
D-10
-------
TABLE D-l (continued)
SCC
SOURCE DESCRIPTION/PROCESS
407872 ORGANIC CHEM STRG
407999 ORGANIC CHEM STRG
408999 ORGNC CHEM TRNSPT
490001 ORGANIC SOLVENT
490002 ORGANIC SOLVENT
490003 ORGANIC SOLVENT
490004 ORGANIC SOLVENT
490900 ORGANIC SOLVENT
490999 ORGANIC SOLVENT
501001 SOLID WASTE DISPL
501002 SOLID WASTE DISPL
501005 SOLID WASTE DISPL
501006 SOLID WASTE
501007 SOLID WASTE DISPL
501900 SOLID WASTE DISPL
502001 SOLID WASTE DISPL
502002 SOLID WASTE DISPL
502003 SOLID WASTE DISPL
502005 SOLID WASTE DISPL
502006 SOLID WASTE DISPL
502900 SOLID WASTE DISPL
503001 SOLID WASTE DISPL
503002 SOLID WASTE DISPL
503005 SOLID WASTE DISPL
503006 SOLID WASTE DISPL
503007 SOLID WASTE DISPL
503008 SOLID WASTE DISPL
503900 SOLID WASTE DISPL
PRESSURE TANKS
MISCELLANEOUS
TANK CARS/TRUCKS
MISCELLANEOUS
MISCELLANEOUS
MISCELLANEOUS
MISCELLANEOUS
MISCELLANEOUS
MISCELLANEOUS
GOVERNMENT
GOVERNMENT
GOVERNMENT
GOVERNMENT
GOVERNMENT
GOVERNMENT
COMMERCL/INSTITNL
COMMERCL/INSTITNL
COMMERCL/INSTITNL
COMMERCL/INSTITNL
COMMERCL/INSTITNL
COMMERCL/INSTITNL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
INDUSTRIAL
METHYL MERCAPTAN
SPECIFY IN COMMTS
SPECIFY LIQUID
SOLVENT EXTRACTN
SOLVENT RECOVERY
RAILCAR CLEANING
TANK TRUCK CLEANG
INCINERATORS
NOT CLASSIFIED
MUNICIPAL INCIN
OPEN BURNING DUMP
OTHER INCINERATOR
FIRE FIGHTING
SEWAGE TREATMENT
AUX.FUEL/NO EMSNS
INCINERATION-GENL
OPEN BURNING
APARTMENT INCIN
INCINERATION-SPCL
LANDFILL DUMP
AUX.FUEL/NO EMSNS
INCINERATION
OPEN BURNING
INCINERATOR
LANDFILL DUMP
LIQUID WASTE
SURFACE IMPOUNDMT
AUX.FUEL/NO EMSNS
D-ll
-------
TABLE D-2. SOURCE CATEGORY CODES, U.S. AREA SOURCES
SCC
Category Description
001
002
003
004
005
006
007
008
009
010
Oil
012
013
014
015
016
017
018
019
020
021
022
023
024
025
026
027
028
029
030
031
032
033
034
035
036
037
038
039
040
041
042
043
044
045
046
047
048
049
Residential Fuel
Residential Fuel
Residential Fuel
Residential Fuel
Residential Fuel
Residential Fuel
Anthracite Coal
Bituminous Coal
Distillate Oil
Residual Oil
Natural Gas
Wood
Commercial/Institutional Fuel
Commercial/Institutional Fuel
Commercial/Institutional Fuel
Commercial/Institutional Fuel
Commercial/Institutional Fuel
Commercial/Institutional Fuel
Anthracite Coal
Bituminous Coal
Distillate Oil
Residual Oil
Natural Gas
Wood
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
Industrial Fuel
Anthracite Coal
Bituminous Coal
Coke
Distillate Oil
Residual Oil
Natural Gas
Wood
Process Gas
On-Site Incineration - Residential
On-Site Incineration - Industrial
On-Site Incineration - Commercial/Institutional
Open Burning - Residential
Open Burning - Industrial
Open Burning - Commercial/Institutional
Light Duty Gasoline Vehicles - Limited Access Roads
Light Duty Gasoline Vehicles - Rural Roads
Light Duty Gasoline Vehicles - Suburban Roads
Light Duty Gasoline Vehicles - Urban Roads
Medium Duty Gasoline Vehicles - Limited Access Roads
Medium Duty Gasoline Vehicles - Rural Roads
Medium Duty Gasoline Vehicles - Suburban Roads
Medium Duty Gasoline Vehicles - Urban Roads
Heavy Duty Gasoline Vehicles - Limited Access Roads
Heavy Duty Gasoline Vehicles - Rural Roads
Heavy Duty Gasoline Vehicles - Suburban Roads
Heavy Duty Gasoline Vehicles - Urban Roads
Off Highway Gasoline Vehicles
Heavy Duty Diesel Vehicles - Limited Access Roads
Heavy Duty Diesel Vehicles - Rural Roads
Heavy Duty Diesel Vehicles - Suburban Roads
Heavy Duty Diesel Vehicles - Urban Roads
Off Highway Diesel Vehicles
Railroad Locomotives
Aircraft LTOs - Military
Aircraft LTOs - Civil
Aircraft LTOs - Commercial
Vessels - Coal
D-12
-------
TABLE D-2 (continued)
SCC Category Description
050 Vessels - Diesel Oil
051 Vessels - Residual Oil
052 Vessels - Gasoline
054 Gasoline Marketed
055 Unpaved Road Travel
056 Unpaved Airstrip LTOs
057 Construction
058 Miscellaneous Wind Erosion
059 Land Tilling
060 Forest Wild Fires
061 Managed Burning - Prescribed
062 Agricultural Field Burning
063 Frost Control - Orchard Heaters
06A Structural Fires
071 Beef Cattle Manure Field Application
072 Dairy Cattle Manure Field Application
073 Hog and Pig Manure Field Application
074 Broiler Chicken Manure Field Application
075 Other Chicken Manure Field Application
076 Anhydrous Ammonia Fertilizer Application
077 Beef Cattle Feed Lots
078 Degreasing
079 Drycleaning
080 Graphic Arts (Printing)
081 Rubber and Plastics Manufacturing
082 Architectural Coating
083 Auto Body Repair
084 Motor Vehicle Manufacturing
085 Paper Coating
086 Fabricated Metals
087 Machinery Manufacturing
088 Furniture Manufacturing
089 Flat Wood Products
090 Other Transportation Equipment Manufacturing
091 Electrical Equipment Manufacturing
092 Ship Building and Repairing
093 Miscellaneous Industrial Manufacturing
094 Miscellaneous Industrial Solvent Use
095 Miscellaneous Nonindustrial Solvent Use
096 Minor Utility Sources - Coal
097 Minor Utility Sources - Oil
098 Minor Utility Sources - Gas
099 Minor Point Sources
D-13
-------
TABLE D-3. SOURCE CATEGORY CODES, CANADIAN AREA SOURCES
SCC
Category Description
10101
10102
10103
10104
10105
10106
10201
10202
10203
10204
10206
10207
10208
10210
10211
10213
10214
10215
10217
10218
10220
10221
10301
10501
10601
10701
10801
11201
11301
11401
11402
11403
11404
11501
11502
11503
11504
11702
11703
11704
11705
11706
11711
11712
11713
11714
11715
11721
Gasoline Powered Motor Ve -
Gasoline Powered Motor Ve -
Gasoline Powered Motor Ve -
Gasoline Powered Motor Ve -
Gasoline Powered Motor Ve -
Gasoline Powered Motor Ve -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Off-Highway Mobile Source -
Non-Highway Use of Gasoline
Forest Fires
Slash Burning
Structural Fires
Fertilizer Application
Dry Cleaning
Sand and Gravel Processing
Coal Industry - Coal Handling
Light Duty Trucks
Heavy Duty Trucks
Medium Duty Vehicles
Automobiles
Motorcycles
Snowmobiles
Helicopters
Helicopter Flight Em
Jet Aircraft
Jet Aircraft Flight
Local Aircraft Fligh
Piston Engine Aircra
Piston Engine Inflig
Piston Transport Inf
Small Piston Aircraf
Turboprop Aircraft
Diesel Oil - Railroa
Gasoline Outboards
Motorships Dockside
Motorships Underway
Steamship Dockside
Steamships Underway
Coal Industry
Coal Industry
Coal Industry
Wood Industry
Wood Industry
Wood Industry
Wood Industry
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Coal Mining
Overburden Removal F
Coal Transportation
Sawmill Production
Plywood and Veneer Pro
Hardwood Production
Pulpboard Production
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Elec Pwr
Elec Pwr
Elec Pwr
Elec Pwr
Elec Pwr
Dist. Oil
Diesel Tu
Heavy Oil
Misc. Dsl
Natural G
Residential Coal
Residential Dist. Oil
Residential Kerosene
Residential Liq. Pet
Residential Residual
Commercial Coal
D-14
-------
TABLE D-3 (continued)
SCC
Category Description
11722
11723
11724
11725
11726
11731
11732
11733
11734
11735
11736
11740
11801
12001
12002
12101
12102
12103
12104
12111
12112
12113
12114
12115
12116
12117
12121
12501
12502
12601
12602
12603
12604
12605
12606
12613
12614
12615
12623
12624
12625
12626
12641
12642
12643
12644
12701
12702
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Stationary So
Commercial Dist. Oil
Commercial Kerosene
Commercial Liq. Pet.
Commercial Natural G
Commercial Residual
Industrial Coal
Industrial Dist. Oil
Industrial Kerosene
Industrial Liq. Pet.
Industrial Natural G
Industrial Residual
Fuelwood Combustor
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Fuel Comb
Bakeries
Asphalt Production - Asphalt Drying
Asphalt Production - Asphalt Fugitive
Stone Processing
Stone Processing
Stone Processing
Stone Processing
Stone Processing
Stone Processing
Stone Processing
Stone Processing
Stone Processing
Stone Processing
Stone Processing
Stone Processing
Clay Products Manufacture
Clay Products Manufacture
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Grain Handling and Milling
Natural Gas Processing - Compressor Engin. Non
Natural Gas Processing - Compressor Turb. Non
Crush.Stn - Pri.Crushi
Crush.Stn - Scrn.Cnvy
Sec.Crush&
Sec.Crush.
Pri.Crushin
Recrush&Scr
Scrn,Cnvy&H
Sec.Crush&S
Sec.Crush.F
Fines Mills
Storage Pil
Building Stone - Cutt
Clay Prod. - Dryer - Gri
Crush.Stn
Crush.Stn
Pulv.Stn -
Pulv.Stn -
Pulv.Stn -
Pulv.Stn -
Pulv.Stn -
Pulv.Stn -
Pulv.Stn -
Clay Prod.
- Term.Elev
- Term.Elev
- Term.Elev
- Term.Elev
- Term.Elev
- Term.Elev
- Prim.Elev
- Prim.Elev
- Prim.Elev
- Xfer.Elev
- Xfer.Elev
- Xfer.Elev
- Xfer.Elev
• Proc.Elev
• Proc.Elev
- Proc.Elev
• Proc.Elev
Storage
Cleaning
Drying
Headhouse
Ship & Rec
Transfer C
Tripper(Ga
Headhouse
Ship & Rec
Transfer C
Headhouse
Ship & Rec
Transfer C
Tripper(Ga
Cleaning H
Millhouse
Preclean &
Receiving
D-15
-------
TABLE D-3 (continued)
SCC
Category Description
12703
1270A
12705
12801
12802
12803
12901
12902
12903
12904
12905
12906
12907
13001
13002
13101
13201
13202
13203
13204
13205
13701
13702
13703
13704
13705
13706
13901
13902
14001
14101
14102
14201
14202
14203
14204
14205
14401
14501
14601
14602
14603
14604
14701
14801
14802
14901
15001
Natural Gas Processing - Compressors In-Plant
Natural Gas Processing - Heaters Boilers In-P
Natural Gas Processing
Solid Waste Incineration - Wood Waste Disposal
Solid Waste Incineration - Controlled Air
Solid Waste Incineration - Multiple Chamber
Filling Vehicle Tank
Refinery Storage Tra
Spillage at Station
Station Storage Tran
Transfer to Cars
Vapor Loss at Static
Diesel Evaporation
Diesel and Gasoline Marketi
Diesel and Gasoline Marketi
Diesel and Gasoline Marketi
Diesel and Gasoline Marketi
Diesel and Gasoline Marketi
Diesel and Gasoline Marketi
Diesel and Gasoline Marketi
Application of Surface Co - Industrial Use
Application of Surface Co - Trade, Sales Use
Landfill Sites
Cupola Furnace (Hot
Cupola(+l Reverb.) Fu
Electric Arc Furnace
Induction Furnace (H
Rotary Oil Furnace (H
Trucks Earth Roads
Trucks Treated Grave
Ferrous Foundries
Ferrous Foundries
Ferrous Foundries
Ferrous Foundries
Ferrous Foundries
Dust from Unpaved Roads
Dust from Unpaved Roads
Trucks Untreated Gra
Vehicles Earth Roads
Vehicles Treated Gra
Vehicles Untreated G
Dust from Unpaved Roads
Dust from Unpaved Roads
Dust from Unpaved Roads
Dust from Unpaved Roads
Concrete Batching
Concrete Batching - Fugitive (Material H
Cigarette Smoking
Crude Oil Production - Evaporation from Shi
Crude Oil Production - Evaporation
Concentrate Dryers
Concentrate Transpor
Open Pit Mining
Overburden Removal F
Under Ground Mining
Mining and Rock Quarrying
Mining and Rock Quarrying
Mining and Rock Quarrying
Mining and Rock Quarrying
Mining and Rock Quarrying
Tire Wear
Pesticide Application
Diesel Powered Engines
Diesel Powered Engines
Diesel Powered Engines
Diesel Powered Engines
Plastics Fabrication
Agriculture - Wind Erosion of Crop
Agriculture - Fugitive Tilling Emi
Tailing Piles Erosion
Construction Sites - Bridges, Tunnels, Roads
Agriculture Diesel V
Construction Vehicle
Heavy Duty Vehicles
Other Industrial Eng
D-16
-------
TABLE D-3 (continued)
SCC Category Description
15002 Construction Sites - Heavy Construction
15003 Construction Sites - Non-Residential Cons
15004 Construction Sites - Residential Construe
15005 Construction Sites - Water,Sewer,Utility
15101 General Solvent Use
15201 Dust from Paved Roads - Trucks
15202 Dust from Paved Roads - Vehicles
D-17
-------
-------
APPENDIX E
SPECIATION FILES AND DISCUSSION OF
CONVERSION OF EMISSION RATES FROM MOLES/YEAR TO TONS/YEAR
SPECIATION FILES
Tables E-l through E-5 contain the SCC/Profile, Species/Profile, and
Species/Class assignments used to speciate hydrocarbons and NOx in the 1980
NAPAP inventory. These files are provided as input to the program PSPLIT,
which calculates speciation factors at the class level for each SCC in the
SCC/Profile file.
In the Species/Profile file (Table E-4), the first card for each profile
contains weight percentages for NO, N02, and formaldehyde. Subsequent cards,
1 per species, contain the species SAROAD code, percent contribution by
weight, molecular weight and species name. In the Species Class file (Table
E-5), data are presented for each hydrocarbon species, 1 card per species;
each card contains the species class, molecular weight and compound name.
CONVERSION OF EMISSION RATES FROM MOLES/YEAR TO TONS/YEAR
In the 1980 inventory output tables contained in this report, VOC and THC
emission rates for the 5.0 inventory are listed in units of tons/year.
Speciation factors from PSPLIT are expressed as moles of hydrocarbon class per
unit mass of total hydrocarbons. Hence, the output of the FREDS Speciation
Module for hydrocarbon classes is in moles/year. The conversion from a mass
basis to a mole basis is made so that data on the tape files will be in the
units preferred by modelers, i.e., moles. The data are aggregated into 23
hydrocarbon classes (17 compounds and 6 groups of compounds) to save computer
storage space and decrease computational time relative to that which would be
required if no aggregation were performed.
All of the hydrocarbon data presented in this report for the 5.0
inventory are presented as VOC and THC in units of tons/year. All of the
speciated hydrocarbon data presented in this report for the 5.2 inventory are
presented in terms of the 23 hydrocarbon classes in units of moles/year. It
is possible to convert the 5.2 inventory data for 17 of the 23 hydrocarbon
classes from moles/year to tons/year. Data for the 17 classes which are 17
identified compounds can be converted to tons/year using the compound
molecular weights listed in Table E-5. In most cases however, data for the
six hydrocarbon classes which are groups of compounds (alkanes, alkenes,
aromatics, aldehydes, ketones and organic acids) cannot be converted directly
to tons/year because the individual species makeup of the class may vary from
one profile to the next (see Table E-4). Therefore, the average molecular
weights for these six classes vary from SCC code to SCC code, from state ro
state, from province to province, etc. This point is illustrated below for a
particular 6-digit SCC code.
E-l
-------
Hydrocarbon class emission data were reviewed to find a 6-digit SCC code
with high emissions of alkanes, alkenes, aromatics, aldehydes, ketones and
organic acids. SCC code 301999 showed high emissions for a broad range of
organic compounds including the following classes: alkanes, alkenes,
aromatics, aldehydes and organic acids. Additionally, SCC code 301999 had a
single speciation profile, K0079. Using speciation profile data from Table E-
4, it was possible to calculate the emission rate for each hydrocarbon species
in tons/year, convert to 1000-mole/year, aggregate to the 23 hydrocarbon
classes, and assess the feasibility of recalculating the original 5.0 values
for VOC and THC.
SCC code 301999 data are shown in Table E-6. From the 5.0 inventory, it
is known that the annual THC emissions are 211,348 tons. Speciation
information (weight percent, molecular weight, compound and class) is
available from Table E-5 and is listed in columns 1 through 4 of Table E-6.
Column 5 is a conversion from weight percent to weight fraction. Column 6
lists the calculated emission rate for each compound in tons/year, equal to
(THC) * (weight fraction). Column 7 lists the calculated emission rate in
1000-mole/year. The emission rate in 1000-mole/year is equal to (the emission
rate in tons/year) * (conversion factor, i.e., 907.2 kg/ton) / (molecular
weight in kg/1000-mole). The last four lines of data in Table E-6 show the
weighted average molecular weights for the three multi-component classes
(alkanes, alkenes and aromatics). Table E-6 provides details of the
calculations which lead to species emission rates before aggregation into the
standard 23 hydrocarbon classes used for the 5.2 inventory.
Aggregated data for SCC code 301999 are presented in Table E-7. In
total, 12 of the standard 23 classes have hydrocarbon emissions. Class names
are listed in column 1 and emission rates in 1000-mole/year are provided in
column 2. These first two columns contain all of the data that is provided in
the 5.2 inventory tables in Appendix A and in the body of the 1980 inventory
report. The remaining columns illustrate the types of errors which can arise
when one attempts to convert aggregated hydrocarbon data back from units of
1000-mole/year to units of tons/year. Molecular weights are listed in column
3. All of the molecular weight values were obtained from Table E-5. This
would normally be the only source of information for molecular weights. For a
great many of the six-digit SCC codes and for all of the other types of
listings (e.g., by state, province, region or country) the multiple species
profiles prevent one from back-calculating the weight percentage
contributions to each of the six multi-component classes. Thus, for
aldehydes, alkanes, alkenes, aromatics and organic acids, we have selected
Table E-5 average molecular weight values of 72.61, 121.79, 80.41, 126.14 and
122.09. From Table E-6, it is clear that the actual values for SCC code
301999 were not equal to the average values from Table E-5. Column 4 of Table
E-7 provides the known emission rates (in tons/year) from Table E-6. Column 5
of Table E-7 lists the calculated emission rates in tons per year. The values
were calculated as (1000-mole/year, column 2) * (molecular weight, column 3) /
(conversion factor, i.e., 907.2 kg/1000-mole). The final column in Table E-7
shows the errors which occur when average molecular weights for multi-
component classes are used to convert from 5.2 inventory emission rates in
1000-moles/year to emission rates in tons/year.
E-2
-------
Table E-7 shows that for single-component hydrocarbon classes, no
calculation error is introduced when the 5.2 inventory emission rates are
converted from units of 1000-moles/year to units of tons/year. Note however
that for the multicomponent hydrocarbon classes, errors can range from
insignificant to quite large:
Class Error
aldehydes 1 %
alkanes 158 %
alkenes 40 %
aromatics 26 %
organic acids -47 %
calculated THC 50 %
The sources of these calculation errors can be assessed for each class. For
example, the (weighted) average molecular weight of alkanes in SCC code 301999
was 47.26, i.e., the number of tons/year (56,430) divided by the number of
moles/year (1,083,337,000) yields a molecular weight of 0.000052089 tons/mole
which is equal to 47.26 kg/1000-mole or 47.26 g/mole. On the other hand, the
grand average of all the alkane molecular weights in Table 3-5 is 121.79. The
ratio of these two molecular weight values (121.79/47.26) is 2.58 which leads
to the 158 % calculation error. For certain 6-digit SCC aggregations (such as
301999) which use only a single speciation profile, it is possible to
calculate the correct weighted molecular weight values and perform a proper
conversion between sets of units for emission rates. However, for 6-digit SCC
codes using more than one profile this is not possible; similarly for other
groupings (by state, by province, by region and by country) it is not possible
to back-calculate the required data.
It is possible to calculate the maximum potential errors which can be
introduced by converting from 1000-moles/year to tons/year. The maximum
possible errors can be determined by comparing the smallest and largest
molecular weight values to the average value for each multi-component class:
SCC 301999
class maximum error error
aldehydes - 1 % to + 1 % +1%
alkanes - 79 % to + 368 % + 158 %
alkenes - 51 % to + 106 % + 40 %
aromatics - 45 % to + 81 % + 26 %
ketones - 26 % to + 35 %
organic acids - 47 % to -t- 88 % - 47 %
For a particular SCC code these errors are possible. For aldehydes and
organic acids, the SCC 301999 observed errors were equal to the maximum
possible errors. For alkanes, alkenes and aromatics, the SCC 301999
observed errors were approximately equal to one-third of the maximum
possible error. For THC calculated from the aggregated 5.2 inventory
parameters in Table E-7, the net error was + 50 % relative to the 5.0
inventory value.
E-3
-------
In summary, it is advised that readers not attempt to convert 5.2
inventory multi-component hydrocarbon class data from units of 1000-moles/year
to tons/year using molecular weight averages, as large errors can result. The
original intent of the 1980 inventory was to provide basic data to modelers
and their preferred units are moles of hydrocarbons, not tons. For economic
reasons, it was determined that many of the more than 150 hydrocarbon species
would have to be aggregated into multi-component classes. This aggregation
process has resulted in a loss of information which prevents direct
interconversion of emission rates between various sets of units.
E-4
-------
TABLE E-l. SCC/PROFILE ASSIGNMENTS FOR U.S. AREA SOURCES,
1980 NAPAP INVENTORY VERSION 5.2
001
002
003
004
005
006
007
008
009
010
Oil
012
013
014
015
016
017
018
019
020
021
022
023
024
025
026
027
028
029
030
031
032
033
034
035
036
037
038
039
040
041
042
043
044
045
046
047
048
049
050
051
052
053
054
055
056
057
058
059
060
061
R0001
R0001
K0002
K0001
K0003
R0001
R0001
R0001
K0002
K0001
K0003
R0001
R0001
R0001
R0001
K0002
K0001
K0003
R0001
K0004
C0051
C0051
C0051
K0121
K0121
K0121
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
C0038
C0034
C0034
C0034
C0034
K0330
C0004
C0020
C0020
C0020
R0001
K0002
K0001
C0121
X0007
X0006
C0038
C0020
C0049
C0049
C0049
K0121
K0121
062
063
064
071
072
073
074
075
076
077
078
079
080
081
082
083
084
085
086
087
088
089
090
091
092
093
094
095
096
097
098
099
K0121
K0121
K0121
K0203
KT203
K0203
K0203
K0203
K0203
K0203
X0013
C0043
K0181
K0272
K0196
K0280
K0196
K0149
K0196
K0196
K0148
K0157
K0196
K0196
K0196
X0007
X0007
K0197
R0001
K0001
K0003
C0015
E-5
-------
TABLE E-2.
SCC/PROFILE ASSIGNMENTS FOR CANADIAN AREA SOURCES,
1980 NAPAP INVENTORY VERSION 5.2
10101
10102
10103
10104
10105
10106
10201
10202
10203
10204
10206
10207
10208
10210
10211
10213
10214
10215
10217
10218
10220
10221
10301
10501
10601
10701
10801
11201
11301
11401
11402
11403
11404
11501
11502
11503
11504
11702
11703
11704
11705
11706
11711
11711
11712
11713
11714
11715
11716
11721
11722
11723
11724
11725
11726
11731
11732
11733
11734
11735
11736
X0002
X0002
X0002
X0002
X0002
X0002
C0020
C0020
C0020
C0020
C0020
C0020
C0020
C0020
C0020
C0020
C0004
C0121
K0002
K0002
K0001
K0001
C0038
K0121
K0121
K0121
K0203
C0043
C0031
R0001
R0001
R0001
X0002
C0025
C0025
C0025
C0025
K0002
K0009
K0001
K0009
K0003
R0001
R0001
K0002
K0002
K0003
K0003
K0001
R0001
K0002
K0002
K0003
K0003
K0001
R0001
K0002
K0002
K0003
K0003
K0001
11740
11801
12001
12002
12101
12102
12103
12104
12111
12112
12113
12114
12115
12116
12117
12121
12501
12502
12601
12602
12603
12604
12605
12606
12613
12614
12615
12623
12624
12625
12626
12641
12642
12643
12644
12701
12702
12703
12704
12705
12801
12802
12803
12901
12902
12903
12904
12905
12906
12907
13001
13002
13101
13201
13202
13203
13204
13204
13205
13701
13702
13702
R0001
K0003
K0025
K0024
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0032
C0032
C0032
C0032
C0032
C0032
C0032
C0032
C0032
C0032
C0032
C0032
C0032
C0032
C0032
C0032
C0032
K0003
K0003
K0003
K0003
K0003
C0051
C0051
C0051
X0006
X0006
X0006
X0006
X0006
X0006
X0006
K0096
K0196
C0117
C0085
C0085
C0085
C0085
C0085
C0085
C0038
C0038
C0038
13703
13704
13705
13705
13706
13901
13902
14001
14101
14102
14201
14201
14202
14202
14203
14204
14205
14401
14501
14601
14602
14603
14604
14701
14801
14802
14901
15001
15002
15003
15004
15005
15101
15201
15202
C0038
C0038
G0038
C0038
C0038
K0025
K0025
C0025
K0296
K0296
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
K0076
C0034
C0034
C0034
C0034
C0015
C0049
C0049
C0049
C0049
C0049
C0049
C0049
C0049
X0007
X0002
X0002
E-6
-------
TABLE E-3. SCC/PROFILE ASSIGNMENTS FOR U.S. AND CANADIAN POINT SOURCES,
1980 NAPAP INVENTORY VERSION 5.2
10100101
10100102
10100201
10100202
10100203
10100204
10100205
10100209
10100212
10100221
10100222
10100223
10100224
10100226
10100299
10100301
10100302
10100303
10100306
10100401
10100402
10100404
10100501
10100504
10100505
10100601
10100602
10100604
10100702
10100801
10100901
10100902
10100903
10200101
10200104
10200107
10200201
10200202
10200203
10200204
10200205
10200206
10200208
10200209
10200210
10200211
10200212
10200213
10200214
10200225
10200299
10200301
10200302
10200304
10200306
10200401
10200402
10200403
10200404
10200501
10200502
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
K0001
K0001
K0001
K0002
K0002
K0002
K0003
K0003
K0003
K0004
R0001
K0001
K0001
K0003
K0003
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
K0001
K0001
K0001
K0001
K0002
K0002
10200503
10200504
10200601
10200602
10200603
10200701
10200702
10200704
10200705
10200707
10200708
10200799
10200802
10200804
10200901
10200902
10200903
10201002
10201101
10201201
10201301
10201302
10201404
10299997
10299998
10300101
10300102
10300205
10300206
10300207
10300208
10300209
10300210
10300211
10300212
10300213
10300214
10300224
10300225
10300299
10300305
10300307
10300309
10300401
10300402
10300403
10300404
10300501
10300502
10300503
10300504
10300601
10300602
10300603
10300901
10300902
10300903
10301201
10301302
10301303
10390006
10399997
K0002
K0002
K0003
K0003
K0003
K0004
K0004
K0004
K0004
K0005
K0005
K0004
R0001
R0001
R0001
R0001
R0001
K0003
C0035
R0001
K0002
K0002
K0029
K0003
K0003
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
K0001
K0001
K0001
K0001
K0002
K0002
K0002
K0002
K0003
K0003
K0003
R0001
R0001
R0001
K0003
K0002
K0002
C0035
C0049
10500102
10500105
10500106
10500110
10500202
10500205
10500501
10500601
19999999
20100101
20100102
20100201
20100202
20100301
20100302
20100501
20100901
20100902
20200101
20200102
20200201
20200202
20200301
20200401
20300101
20300201
20400101
20400401
20400402
20400499
29999999
30100101
30100103
30100104
30100106
30100305
30100306
30100307
30100308
30100309
30100399
30100502
30100503
30100504
30100505
30100507
30100509
30100599
30100601
30100699
30100701
30100799
30100801
30100802
30100899
30100901
30100902
30100910
30100999
30101011
30101013
30101015
K0002
K0002
K0003
K0003
K0002
K0002
K0002
K0003
C0049
K0009
K0009
K0007
K0010
K0008
K0008
K0008
K0008
K0008
K0009
K0009
K0007
K0010
K0009
K0009
K0009
K0010
K0010
K0009
K0008
C0081
K0008
K0071
K0079
C0035
C0015
C0035
C0035
C0035
C0035
C0035
K0079
C0035
K0079
K0079
C0015
C0035
C0035
K0079
K0079
K0079
C0015
K0079
C0035
C0035
C0035
K0079
K0079
K0079
K0079
C0035
C0035
C0035
E-7
-------
TABLE E-3 (continued)
30101099
30101101
30101199
30101202
30101203
30101301
30101302
30101303
30101304
30101399
30101401
30101402
30101499
30101501
30101502
30101503
30101505
30101599
30101601
30101602
30101612
30101699
30101702
30101704
30101722
30101799
30101800
30101801
30101802
30101803
30101805
30101807
30101812
30101817
30101822
30101827
30101838
30101839
30101840
30101847
30101891
30101892
30101893
30101899
30101901
30101902
30101903
30101904
30101905
30101906
30101907
30102005
30102099
30102102
30102110
30102111
30102113
30102199
30102201
30102301
30102306
30102308
C0035
K0025
C0015
C0035
C0035
K0079
K0079
C0035
C0035
K0079
K0066
K0066
K0066
K0066
K0066
K0066
K0066
K0066
C0035
C0035
C0015
C0035
K0079
C0035
C0049
C0049
K0067
K0067
K0068
C0015
C0015
C0015
C0015
C0035
C0035
C0015
C0015
C0015
C0015
C0035
C0015
C0035
C0035
C0015
K0276
K0276
K0071
K0276
C0035
C0035
C0035
K0072
K0072
C0035
C0035
C0035
K0025
C0049
C0035
C0015
C0049
C0035
30102310
30102312
30102314
30102318
30102321
30102399
30102401
30102402
30102406
30102410
30102414
30102415
30102499
30102501
30102505
30102599
30102601
30102602
30102608
30102615
30102620
30102624
30102625
30102630
30102699
30102701
30102704
30102705
30102706
30102709
30102711
30102712
30102713
30102717
30102718
30102721
30102722
30102723
30102727
30102728
30102801
30102905
30102906
30102908
30103001
30103002
30103003
30103099
30103101
30103199
30103201
30103202
30103203
30103204
30103299
30103301
30103399
30103401
30103402
30103410
30103415
30103499
C0035
C0035
C0035
C0035
C0035
C0015
K0067
K0068
K0079
K0274
K0068
C0035
K0274
C0015
C0015
C0015
K0272
K0272
K0272
C0035
K0272
C0035
C0035
C0035
K0272
C0049
C0035
C0035
C0049
C0035
C0035
C0035
C0035
C0035
C0035
C0035
C0035
C0035
C0035
C0035
C0049
C0035
K0025
C0035
C0035
C0049
C0035
C0049
C0035
C0035
C0017
C0017
C0035
C0035
C0035
C0024
C0024
C0015
C0035
C0015
C0035
C0015
30103501
30103550
30103599
30103601
30103999
30104001
30104002
30104003
30104004
30104006
30104101
30104102
30104104
30104199
30104201
30104202
30104203
30104204
30105001
30106001
30106002
30106003
30106004
30106005
30106006
30106007
30106009
30106010
30106099
30109099
30109101
30109199
30110001
30110002
30110099
30111001
30111102
30111199
30112001
30112002
30112011
30112021
30112099
30112501
30112502
30112520
30112530
30112599
30113001
30113004
30113210
30113299
30113799
30115601
30115701
30116799
30116901
30117401
30118101
30119701
30119705
30119710
K0025
C0049
K0079
C0017
C0017
C0049
C0049
C0049
C0049
C0035
C0015
C0035
C0015
C0015
C0035
C0035
C0035
C0035
C0015
C0015
C0015
C0035
C0015
C0015
C0015
C0015
C0015
C0015
C0015
C0015
C0035
C0035
C0017
C0035
C0017
C0017
K0079
K0079
K0002
K0002
C0035
C0035
C0035
K0078
K0078
C0035
C0035
K0078
C0017
K0025
C0035
C0015
C0015
C0035
C0015
C0035
C0035
C0015
C0035
C0035
C0035
C0035
E-8
-------
TABLE E-3 (continued)
30119799
30120201
30120601
30125001
30125005
30125015
30125020
30125099
30125101
30125301
30125405
30125801
30125810
30125815
30125899
30128501
30130001
30181001
30182001
30183001
30188801
30188802
30188803
30188804
30188805
30190099
30199999
30200101
30200102
30200103
30200104
30200199
30200201
30200202
30200203
30200299
30200301
30200401
30200402
30200403
30200404
30200410
30200499
30200501
30200502
30200503
30200504
30200505
30200506
30200507
30200508
30200509
30200601
30200602
30200603
30200604
30200605
30200606
30200607
30200608
30200699
30200701
C0035
C0035
C0035
K0291
C0035
C0035
C0035
K0079
C0035
C0035
C0035
K0287
K0223
C0035
C0015
C0015
C0015
C0015
C0035
C0049
C0015
C0035
C0035
C0035
C0035
K0079
K0079
C0035
K0211
K0211
K0211
K0211
K0211
K0211
K0211
K0211
K0211
K0211
K0211
K0211
K0211
K0211
C0035
C0032
C0035
K0211
C0032
C0032
C0032
K0211
K0211
K0211
C0035
C0035
C0032
C0032
K0211
C0032
K0211
K0211
C0035
C0032
30200702
30200703
30200704
30200705
30200711
30200713
30200730
30200731
30200732
30200733
30200734
30200742
30200743
30200744
30200745
30200752
30200754
30200755
30200756
30200760
30200781
30200782
30200784
30200789
30200790
30200799
30200801
30200802
30200803
30200804
30200805
30200806
30200899
30200901
30200902
30200903
30200998
30200999
30201001
30201002
30201003
30201201
30201203
30201299
30201301
30201401
30201501
30201599
30201601
30201799
30201899
30201901
30201902
30201903
30201999
30202001
30202002
30202601
30203001
30203099
30203103
30203104
C0032
K0211
K0211
C0032
K0211
K0211
C0035
K0211
C0032
K0211
C0032
K0211
C0032
C0032
K0211
K0211
C0032
C0032
K0211
C0032
K0211
K0211
K0211
K0211
K0211
C0035
C0035
C0032
C0032
C0032
C0032
C0032
C0035
C0032
C0032
K0211
K0211
K0211
C0032
K0211
K0211
C0032
K0211
C0032
R0001
K0211
K0211
K0211
K0211
K0211
C0032
C0032
C0032
C0032
C0032
C0035
C0035
K0211
K0211
C0032
K0211
C0032
30203105
30203106
30203109
30203299
30203399
30203601
30288801
30288804
30299998
30299999
30300001
30300101
30300102
30300103
30300104
30300105
30300107
30300199
30300201
30300301
30300302
30300303
30300304
30300305
30300306
30300307
30300308
30300309
30300310
30300311
30300312
30300313
30300316
30300399
30300401
30300502
30300503
30300504
30300505
30300506
30300507
30300508
30300509
30300510
30300512
30300513
30300515
30300521
30300523
30300599
30300601
30300602
30300603
30300604
30300605
30300610
30300611
30300614
30300616
30300699
30300701
30300702
C0032
C0032
K0211
C0032
C0035
C0032
C0032
C0035
C0032
C0032
C0085
K0011
K0011
K0011
C0049
K0011
K0011
K0011
C0049
K0011
K0011
K0011
K0011
K0011
K0011
K0011
K0011
K0011
K0011
C0049
K0011
K0011
K0011
K0011
K0011
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
K0012
E-9
-------
TABLE E-3 (continued)
30300801
30300802
30300803
30300805
30300807
30300808
30300809
30300811
30300812
30300813
30300814
30300815
30300817
30300823
30300824
30300825
30300899
30300901
30300903
30300904
30300906
30300908
30300910
30300911
30300912
30300913
30300914
30300915
30300916
30300917
30300918
30300919
30300920
30300922
30300923
30300924
30300931
30300932
30300933
30300934
30300935
30300999
30301001
30301002
30301004
30301005
30301016
30301017
30301024
30301099
30301199
30301201
30301301
30301401
30301403
30301499
30302301
30302302
30302304
30302310
30302312
30302314
K0012
K0012
K0013
K0012
K0012
K0012
K0012
K0012
K0012
K0013
K0012
K0012
K0012
K0012
K0012
K0012
C0085
K0306
K0016
K0016
K0016
K0012
K0016
K0016
K0016
K0016
K0016
K0016
K0016
K0016
K0306
K0306
K0306
C0085
K0306
K0306
K0306
K0306
K0306
C0085
C0085
C0085
K0013
C0085
K0016
C0085
K0013
K0013
K0013
C0035
C0035
C0035
C0031
C0035
C0035
C0035
C0031
C0031
C0031
C0031
C0031
C0031
30302402
30302404
30302411
30303002
30303003
30303005
30303009
30303012
30303051
30303099
30388801
30388802
30399999
30400101
30400102
30400103
30400104
30400106
30400107
30400108
30400109
30400110
30400111
30400120
30400150
30400199
30400204
30400212
30400215
30400217
30400219
30400223
30400224
30400230
30400238
30400299
30400301
30400302
30400303
30400304
30400315
30400320
30400325
30400330
30400331
30400340
30400350
30400351
30400352
30400353
30400360
30400399
30400401
30400402
30400403
30400404
30400407
30400408
30400409
30400499
30400501
30400502
C0031
C0031
C0031
C0085
K0011
K0011
C0085
K0011
C0031
C0035
K0012
C0035
C0085
C0086
C0086
C0086
C0086
C0086
C0086
C0086
C0086
C0086
C0086
C0086
C0086
C0086
C0035
C0086
C0086
C0086
C0086
C0086
C0086
C0086
C0086
C0086
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0086
C0086
C0086
C0086
C0086
C0086
C0086
C0086
K0079
K0079
30400503
30400506
30400507
30400509
30400699
30400701
30400702
30400703
30400704
30400705
30400706
30400707
30400708
30400709
30400710
30400715
30400799
30400802
30400805
30400806
30400824
30400899
30400999
30401001
30401099
30402002
30402004
30402099
30402201
30403499
30405001
30488801
30499999
30500101
30500102
30500104
30500105
30500199
30500201
30500202
30500203
30500204
30500205
30500206
30500207
30500208
30500299
30500301
30500302
30500303
30500304
30500305
30500308
30500309
30500311
30500312
30500313
30500314
30500315
30500316
30500399
30500401
K0079
K0079
K0079
K0079
K0025
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0085
C0086
C0086
C0086
C0086
C0086
C0035
C0086
C0086
K0079
K0079
K0079
C0086
C0035
C0086
C0035
C0086
K0021
K0022
K0022
K0022
K0024
K0025
K0025
K0025
K0025
K0025
K0025
K0025
K0025
K0025
C0031
C0031
C0031
K0025
K0025
C0031
C0031
K0025
K0002
R0001
K0025
K0002
R0001
C0031
C0035
E-10
-------
TABLE E-3 (continued)
30500403
30500501
30500502
30500503
30500504
30500505
30500599
30500606
30500607
30500608
30500609
30500610
30500611
30500612
30500613
30500614
30500615
30500616
30500617
30500618
30500619
30500699
30500705
30500706
30500707
30500708
30500709
30500710
30500711
30500712
30500714
30500715
30500716
30500717
30500718
30500719
30500799
30500801
30500802
30500803
30500899
30500901
30500902
30500903
30500904
30500905
30500906
30500907
30500999
30501001
30501002
30501003
30501004
30501007
30501008
30501009
30501010
30501011
30501012
30501013
30501014
30501015
C0035
K0025
C0031
C0031
C0031
C0031
C0031
K0001
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0035
C0031
K0001
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0035
K0001
C0031
C0031
C0031
K0025
C0031
C0031
C0031
C0031
C0031
C0031
C0031
R0001
R0001
R0001
R0001
K0025
R0001
R0001
R0001
R0001
R0001
R0001
R0001
R0001
30501021
30501023
30501024
30501099
30501101
30501107
30501108
30501110
30501111
30501120
30501199
30501201
30501202
30501203
30501204
30501205
30501206
30501215
30501299
30501399
30501401
30501402
30501403
30501404
30501406
30501407
30501408
30501410
30501411
30501412
30501499
30501501
30501502
30501503
30501504
30501505
30501508
30501520
30501599
30501601
30501602
30501603
30501604
30501605
30501606
30501607
30501608
30501610
30501611
30501612
30501613
30501614
30501615
30501616
30501699
30501701
30501703
30501704
30501705
30501799
30501801
30501899
R0001
R0001
R0001
R0001
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
K0025
K0025
K0025
C0031
C0031
C0031
C0031
C0031
C0031
C0031
K0025
C0031
C0031
R0001
C0031
C0031
C0031
C0031
C0031
COr'Sl
C0031
R0001
R0001
R0001
R0001
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0086
C0086
C0086
C0086
C0086
C0031
C0031
30501901
30501902
30501903
30501905
30501999
30502001
30502002
30502003
30502004
30502005
30502006
30502007
30502008
30502009
30502010
30502011
30502012
30502099
30502101
30502201
30502299
30502401
30502501
30502502
30502503
30502504
30502508
30502599
30502601
30502699
30503099
30503101
30503104
30503105
30503106
30503107
30503110
30503111
30503201
30503202
30503203
30503204
30503205
30503206
30503299
30504020
30504021
30504022
30504023
30504025
30504030
30504031
30504032
30504033
30504034
30504099
30510002
30510003
30510004
30510399
30588801
30599999
K0025
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
K0025
C0031
C0031
C0031
C0031
C0031
K0025
C0035
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
C0031
K0025
C0031
C0031
C0031
C0031
C0031
C0035
C0035
C0031
E-ll
-------
TABLE E-3 (continued)
30600101
30600102
30600103
30600104
30600105
30600201
30600301
30600401
30600402
30600501
30600502
30600503
30600504
30600505
30600506
30600602
30600603
30600701
30600702
30600801
30600802
30600803
30600804
30600805
30600806
30600807
30600901
30600999
30601001
30601101
30601201
30601401
30601613
30610001
30688801
30688802
30688803
30699898
30699998
30699999
30700101
30700103
30700104
30700105
30700106
30700107
30700108
30700110
30700199
30700203
30700211
30700212
30700221
30700222
30700223
30700232
30700233
30700234
30700299
30700301
30700302
30700401
K0001
K0003
K0001
K0003
K0003
K0029
K0029
K0079
K0053
K0031
K0031
K0031
K0031
K0031
K0031
K0031
K0029
K0035
K0035
K0316
K0047
K0321
K0039
K0031
K0029
K0029
K0051
K0051
C0035
K0053
K0029
K0025
K0029
C0035
K0316
K0079
C0035
K0316
K0316
K0316
C0025
C0025
C0025
C0025
K0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
30700402
30700499
30700501
30700599
30700701
30700702
30700703
30700799
30700804
30700806
30700898
30700899
30701199
30701399
30702099
30703001
30703002
30703099
30788801
30788802
30788803
30788804
30788805
30799999
30800101
30800102
30800105
30800106
30800107
30800108
30800197
30800198
30800199
30800699
30800799
30890246
30900001
30900199
30900201
30900202
30900205
30900299
30901001
30901099
30901102
30901103
30902099
30903001
30903002
30903003
30903004
30903005
30903099
30906001
30988801
30999999
31000199
31000201
31000202
31000203
31000205
31000299
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
K0096
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
C0025
K0272
K0274
K0274
K0273
K0274
K0272
K0079
K0272
K0274
K0272
C0025
K0274
C0005
C0086
C0005
C0005
C0005
C0005
C0005
C0005
C0005
C0005
C0086
C0005
C0005
C0005
C0035
C0005
C0005
C0035
C0005
K0060
C0035
K0004
K0004
K0004
K0079
31000404
31000414
31088805
32099199
32099998
32099999
33000101
33000102
33000103
33000104
33000199
33000201
33000202
33000203
33000298
33000299
33000399
33000499
39000199
39000201
39000203
39000299
39000402
39000403
39000408
39000489
39000499
39000501
39000502
39000503
39000589
39000599
39000602
39000603
39000605
39000608
39000689
39000690
39000699
39000701
39000702
39000789
39000797
39000798
39000799
39000801
39000899
39000999
39001099
39001299
39001399
39099997
39099999
39999998
39999999
40100101
40100102
40100103
40100104
40100105
40100199
40100201
K0004
K0004
K0079
K0060
C0090
K0060
K0060
K0060
K0060
K0060
K0060
K0096
K0096
K0096
K0096
K0096
K0060
C0035
R0001
R0001
R0001
R0001
K0001
K0001
K0001
C0035
K0001
K0002
K0002
K0002
C0035
K0002
K0003
K0003
C0035
K0003
C0035
K0003
K0003
K0217
K0217
C0035
K0217
K0217
K0217
R0001
C0035
C0035
K0003
C0035
C0035
K0003
K0003
C0035
K0003
K0085
K0086
K0085
K0086
K0088
K0085
K0086
E-12
-------
TABLE E-3 (continued)
40100202
40100203
40100204
40100205
40100206
40100207
40100225
40100299
40100303
40100306
40100399
40188801
40188802
40188898
40191302
40191303
40191304
40199999
40200101
40200102
40200103
40200110
40200199
40200201
40200205
40200210
40200299
40200301
40200310
40200399
40200401
40200402
40200403
40200406
40200410
40200499
40200501
40200502
40200503
40200504
40200505
40200510
40200599
40200601
40200603
40200604
40200610
40200699
40200701
40200705
40200706
40200710
40200799
40200801
40200802
40200803
40200810
40200821
40200898
40200899
40200901
40200902
K0087
K0085
K0275
K0271
K0090
K0088
K0271
K0087
K0271
K0271
C0035
K0088
C0035
K0085
C0026
K0085
C0026
K0090
K0125
K0125
K0125
K0125
K0125
com
com
C0110
com
K0127
K0127
K0127
K0148
K0147
K0148
K0148
K0147
K0147
K0156
K0156
K0156
K0156
K0156
K0156
K0156
K0134
K0134
K0134
K0134
K0134
K0141
K0141
K0141
K0141
K0141
K0092
K0092
K0092
K0092
K0092
K0092
K0162
K0096
K0219
40200903
40200904
40200905
40200906
40200907
40200908
40200909
40200910
40200911
40200912
40200913
40200914
40200915
40200916
40200917
40200918
40200919
40200920
40200921
40200922
40200923
40200924
40200925
40200998
40201001
40201004
40201101
40201103
40201301
40201399
40201437
40201601
40201606
40201632
40201702
40201705
40201721
40201722
40201723
40201725
40201726
40201727
40201728
40201799
40201801
40201806
40201901
40201999
40202001
40202031
40202101
40202103
40202106
40202107
40202108
40202109
40202199
40202201
40202205
40202301
40202306
40202401
K0288
K0289
K0096
K0290
K0222
K0292
K0220
K0226
K0038
K0227
K0228
C0035
K0229
X0012
K0291
K0221
X0005
K0283
K0282
K0090
C0035
K0223
K0287
K0096
K0220
C0035
K0096
K0096
K0096
K0149
C0035
K0134
K0096
C0035
K0096
K0096
K0096
K0096
K0096
K0096
K0333
K0127
K0127
K0096
K0134
K0096
K0157
C0035
X0010
C0035
K0096
K0096
K0096
K0096
K0096
K0096
K0096
C0035
C0035
K0134
K0096
K0134
40202406
40202499
40202501
40202502
40202532
40202535
40202599
40288801
40290101
40290104
40290106
40290302
40290304
40290305
40290306
40290404
40290601
40290603
40290604
40290701
40290702
40290703
40290806
40290809
40299998
40299999
40300002
40300101
40300102
40300103
40300104
40300105
40300106
40300107
40300108
40300109
40300111
40300112
40300115
40300116
40300150
40300151
40300152
40300153
40300154
40300156
40300157
40300160
40300161
40300198
40300199
40300201
40300202
40300203
40300204
40300205
40300206
40300207
40300208
40300211
40300212
40300216
K0096
C0035
K0096
K0096
K0096
K0096
K0096
K0096
K0096
K0096
K0096
C0044
K0096
C0044
C0044
C0044
K0096
C0044
K0096
K0096
C0044
C0044
C0044
C0044
K0294
K0293
K0098
K0098
K0296
K0098
K0297
K0100
K0100
K0100
K0298
C0035
K0301
K0230
C0035
K0185
K0100
K0100
K0100
K0298
C0035
C0035
K0230
K0303
K0185
K0188
K0100
K0098
K0098
K0297
K0297
K0100
K0100
K0100
K0298
K0301
K0230
K0185
E-13
-------
TABLE E-3 (continued)
40300299
40300302
40300304
40300305
40300306
40300310
40300312
40300398
40300399
40301001
40301002
40301003
40301004
40301007
40301008
40301009
40301010
40301011
40301012
40301013
40301014
40301015
40301016
40301017
40301018
40301019
40301020
40301021
40301097
40301099
40301101
40301102
40301103
40301104
40301105
40301106
40301107
40301108
40301109
40301110
40301111
40301112
40301113
40301115
40301117
40301120
40301151
40301197
40301198
40301199
40301201
40301202
40301203
40301204
40301206
40301299
40302001
40309103
40388801
40399999
40400101
40400102
K0100
K0098
K0100
C0091
K0298
C0094
K0231
C0091
K0232
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0297
K0297
K0297
K0098
K0303
K0100
K0100
K0100
K0100
K0100
K0100
K0100
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0100
K0100
K0100
C0091
K0297
C0091
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0100
K0100
K0098
C0091
K0098
C0091
K0100
K0098
K0098
40400103
40400104
40400105
40400107
40400108
40400109
40400110
40400111
40400112
40400113
40400114
40400115
40400116
40400118
40400119
40400120
40400153
40400156
40400161
40400199
40400201
40400202
40400204
40400205
40400207
40400209
40400210
40400212
40400250
40401199
40401999
40499999
40500101
40500199
40500201
40500202
40500203
40500299
40500301
40500303
40500304
40500305
40500306
40500307
40500311
40500401
40500411
40500499
40500501
40500503
40500506
40500507
40500510
40500511
40500598
40500599
40500601
40560101
40588801
40600101
40600104
40600105
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0334
K0334
K0334
K0100
K0283
K0166
K0172
K0290
K0226
K0227
K0172
K0282
K0172
C0035
C0035
K0333
K0181
K0220
K0221
K0221
K0096
K0181
K0182
K0182
X0012
C0113
C0113
K0100
K0098
K0098
40600126
40600127
40600129
40600130
40600131
40600132
40600133
40600134
40600135
40600136
40600137
40600138
40600139
40600140
40600141
40600143
40600144
40600146
40600147
40600148
40600149
40600151
40600197
40600198
40600199
40600231
40600232
40600233
40600234
40600236
40600238
40600239
40600240
40600241
40600242
40600243
40600244
40600245
40600246
40600248
40600249
40600250
40600251
40600253
40600255
40600298
40600299
40600301
40600302
40600303
40600305
40600306
40600307
40600399
40600401
40600402
40600403
40600499
40688801
40999999
49000105
49000199
K0098
K0098
K0098
K0098
K0098
K0297
K0100
K0100
K0100
K0098
K0297
K0100
K0100
K0100
K0098
K0100
K0098
K0100
K0098
K0297
K0100
K0098
C0010
C0010
C0010
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0297
K0100
K0098
K0100
K0297
K0100
K0098
K0100
K0305
K0100
C0035
C0035
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
K0098
X0003
X0003
E-U
-------
TABLE E-3 (continued)
49000299
49099998
49099999
50100101
50100102
50100199
50100201
50100202
50100506
50100507
50100508
50100599
50190005
50190006
50190010
50199999
50200101
50200102
50200103
50200104
50200105
50200106
50200201
50200301
50200399
50200505
50200506
50200599
50290005
50290006
50290010
50300101
50300102
50300103
50300104
50300105
50300106
50300108
50300199
50300201
50300202
50300203
50300506
50300599
50300701
50390005
50390006
50390010
59999999
60199998
X0003
C0035
X0003
C0051
C0051
C0051
K0121
K0121
K0122
C0051
C0051
C0051
C0051
C0051
C0051
C0035
K0122
K0121
K0121
C0051
C0051
C0051
C0051
C0051
K0121
C0051
K0122
C0051
C0051
K0003
C0051
C0051
C0051
C0051
C0051
C0051
K0121
C0051
C0035
K0121
K0121
C0051
K0122
K0122
K0079
C0051
C0051
C0051
C0051
K0195
E-15
-------
TABLE E-4. SPECIES/PROFILE ASSIGNMENTS, 1980 NAPAP INVENTORY VERSION 5.2
1:C0004
2:C0004
3:C0004
4:C0004
5:C0004
6:C0004
7:C0004
8:C0004
9:C0004
10:C0004
11:C0004
12:C0004
13:C0004
U:C0004
15:C0004
16:C0004
17:C0004
18:C0004
19:00004
20:C0004
21:COOM
22:C0004
23:C0004
24: COO W
25:C0004
26:C0004
27:C0004
28:COOOS
29:C0005
30:C0005
31:C0005
32:C0005
33:C0005
34;C0005
35:C0005
36:C0005
37:C0005
38:C0005
39:C0005
40:C0005
41:C0005
42:C0005
43:C0005
44:C0005
45:C0005
46:00005
47:00005
48:00005
49:00005
50:00005
51:00005
52:00005
53:C0005
54:00005
55:C0005
56:00005
57:00010
58:C0010
59:00010
90.00
43201
43203
43205
43206
43215
43224
43232
43235
43238
43241
43255
43258
43259
43260
43281
43282
43283
43284
43285
43286
43287
43502
43503
45202
45207
45221
00.00
43105
43106
43107
43122
43201
43202
43204
43205
43206
43212
43213
43214
43220
43224
43231
43232
43248
43301
43302
43304
43305
43502
43,551
43552
43560
45101
45201
45202
43201
43202
10.00 5.
1.96
6.15
1.71
0.65
0.89
3.79
0.23
1.30
1.93
4.06
7.32
6.04
6.50
6.00
5.37
3.80
3.16
2.43
2.55
1.34
0.70
5.16
14.80
0.21
0.27
11.42
, 16 C0004
16.04
28.05
42.08
26.04
56.12
70.14
100.21
128.26
142.29
156.32
170.34
184.37
198.40
212.42
226.45
240.48
254.51
268.53
282.56
296.59
310.61
30.03
44.05
92.15
120.19
118.15
00.00 09.36
.42
.11
.2C
2.05
27.77
.03
1.30
3.97
.51
2.59
1.45
.21
2.39
4.04
.47
.01
.20
1.09
.87
3.18
4.56
9.36
13.14
13.02
5.17
.69
.81
.40
00.
83.53
10.94
86.18
100.21
114.23
72.15
16.04
30.07
44.09
42.08
26.04
58.12
56.10
58.12
72.15
70.14
86.18
100.21
84.16
32.04
46.07
60.09
74.12
30.03
58.08
72.10
100.16
114.00
78.12
92.15
METHANE -
ETHYIENE
PROPYLENE
ACETYLENE
1SOBUTYLENE
1-PENTENE
N-HEPTANE
N-NONANE
N-DECANE
N-UNDECANE
N-OODECANE
N-TRIDECANE
N-TETRADECANE
N-PENTADECANE
N-HEXADECANE
N-HEPTADECANE
N-OCTADECANE
N-NONADECANE
N-EICOSANE
N-HENEICOSANE
N-DOCOSANE
FORMALDEHYDE
ACETALDEHYDE
TOLUENE
1,3,5-TRIMETHYLBENZENE
A-METHYLSTYRENE
C0005
1SOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
PROPYLENE
ACETYLENE
N- BUTANE
BUTENE
ISOBUTANE
N-PENTANE
1-PENTENE
N-HEXANE
N-HEPTANE
CYCLOHEXANE
METHYL ALCOHOL
ETHYL ALCOHOL
ISOPROPYL ALCOHOL
N-BUTYL ALCOHOL
FORMALDEHYDE
ACETONE
METHYL ETHYL ICETONE
METHYL ISOBUTYL ICETONE
NAPHTHA
BENZENE
TOLUENE
.03 C0010
16.04
30.07
METHANE
ETHANE
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
243
253
263
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
243
253
263
273
283
2
13
23
E-16
-------
TABLE E-4 (continued)
60:C0010
61:C0010
62:C0010
63:C0010
64:C0010
65:C0010
66:C0010
67:00010
68:C0010
69: C001 0
70:C0010
71:C0010
72:C0010
73:C0010
74:00010
75;C0010
76:C0010
77:C0010
78:C0010
79:00010
80:C0010
81:C0015
82:00015
83:C0015
84:C0015
85:C0015
86:C0015
87:C0015
88:C0015
89:C0015
90:C0015
91:00015
92:C0015
93:00015
94:C0015
95:C0015
96:C0015
97:C0015
98:C0015
99:C0015
100-.C0015
101:C0015
102:03015
103:C0015
104:00015
105:C0015
106:00015
107:00015
108:00015
109:00015
110:C0015
111:00015
112:00015
113:00015
1H:C0015
115:00015
116:00015
117:00015
118:00015
119:00015
43203
43204
43212
432 K
43220
43231
43232
43248
43108
43109
43122
43301
43302
43304
43502
43551
43552
43560
43817
45102
45202
43201
43202
43203
43205
43206
43213
43231
43232
43233
43105
43106
43107
43248
43115
43116
43118
43120
43301
43302
43304
43305
43367
43368
43433
43435
43438
43444
43502
43503
43510
43551
43552
43560
43601
43602
43704
43801
43812
.03
3.81
.52
.42
.10
.10
.10
.10
.03
.07
.10
.01
.01
.01
.03
.02
.02
.01
.02
.01
.01
00.
1.26
.47
6.10
3.75
.28
1.16
7.61
.22
.04
.01
.63
.06
3.89
5.66
.76
1.47
2.52
1.59
.44
.92
.37
.42
.34
.52
.18
.23
.02
.48
.20
.23
21.45
1.03
.41
1.30
.40
.85
.25
2.04
28.05
44.09
58.12
58.12
72.15
86.18
100.21
84.16
128.26
142.29
72.15
32.04
46.07
60.09
30.03
58.08
72.10
100.16
165.83
106.17
92.15
ETHYLENE
PROPANE
N- BUTANE
1SOBUTANE
N-PENTANE
N-HEXANE
N- HEPTANE
CYCLOHEXANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF PENTANE
METHYL ALCOHOL
ETHYL ALCOHOL
ISOPROPYL ALCOHOL
FORMALDEHYDE
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
PERCHLOROETHYLENE
ISOMERS OF XYLENE
TOLUENE
.48 00015
16.04
30.07
28.05
42.08
26.04
56.10
86.18
100.21
114.23
86.18
100.21
114.23
84.16
98.19
112.23
114.00
56.10
32.04
46.07
60.09
74.12
62.07
62.07
88.10
116.16
100.11
104.00
30.03
44.05
72.12
58.08
72.10
100.16
44.05
58.08
55.06
50.49
64.52
METHANE
ETHANE
ETHYLENE
PROPYLENE
ACETYLENE
BUTENE
N-HEXANE
N- HEPTANE
N-CCTANE
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
CYCLOHEXANE
0-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
MINERAL SPIRITS
ISOMERS OF BUTENE
METHYL ALCOHOL
ETHYL ALCOHOL
ISOPROPYL ALCOHOL
N-BUTYL ALCOHOL
GLYCOL ETHER
GLYCOL
ETHYL ACETATE
N-BUTYL ACETATE
ETHYL ACRYLATE
ISOPRORYL ACETATE
FORMALDEHYDE
ACETALEHYDE
BUTYRALDEHYOE
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
ETHYLENE OXIDE
PROPYLENE OXIDE
ACRYLONITRILE
METHYL CHLORIDE
ETHYL CHLORIDE
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
243
253
263
273
283
293
303
313
323
333
343
353
363
373
383
E-17
-------
TABLE E-4 (continued)
120:C0015
121:C0015
122:00015
123:00015
124:C0015
125:C0015
126:C0015
127:C0015
128:C0015
129:C0015
130:C0015
I31:C0015
132:C0017
133:00017
134:00020
135:00020
136:00020
137:00020
138:00020
139:00020
KO:C0020
141:00020
142:C0020
143:00020
144:C0020
U5: 00024
146:00024
147:00024
148:00024
149:00024
150:00024
151:00024
152:00024
153:00024
154:00024
155:00024
156:00024
157:00024
158:00024
159:00024
160:00025
161:00025
162:00026
163:00026
164:00026
165:00026
166:00026
167:00026
168:00026
169:00026
170:00026
171:C0026
172:00031
173:00031
174:00031
175:00031
176:00031
177:00031
178:00031
179:00031
43815
43817
43819
43860
45101
45102
45201
45202
45220
45106
45300
45401
43000
97.00
43202
43206
43235
43290
43513
45102
45201
45215
45104
45233
43204
43212
43214
43220
43231
43105
43115
43116
43118
43122
43819
45102
45201
45202
43000
432H
43302
43304
43367
43369
43435
43502
43551
45101
95.00
43201
43202
43203
43204
43205
43206
43P12
7.00 99.00 ETHYLENE DICHLOR1DE
3.65 165.83 PERCHLOROETHYLENE
.01 173.85 METHYLEHE BROMIDE
.58 62.50 VIKYL CHLORIDE
10.99 114.00 MARTHA
.82 106.17 ISOMERS OF XYLENE
3.21 78.12 BENZENE
2.33 92.15 TOLUENE
.96 104.16 STYRENE
.01 134.22 ISOMERS OF DIETHYLBENZENE
.57 94.11 PHENOLS
.37 230.00 XYLENE BASE ACIDS
00017
100.00 86.00 UNIDENTIFIED HYDROCARBONS
3.00 00.00 00020
1.86 30.07 ETHANE
0.23 26.04 ACETYLENE
24.98 128.26 N-NONANE
19.87 113.24 C8 OLEFIN UNK
11.35 29.00 ALDEHYDE
15.04 106.17 ISOMERS OF XYLENE
0.69 78.12 BENZENE
4.75 134.22 TERT-BUTYLBENZENE
15.97 120.19 ISOMERS OF ETHYLTOLUENE
5.25 219.50 TRI/TETRAALKYL BENZENE
00.00 C0024
1.80 44.09 PROPANE
4.40 58.12 N-BUTANE
1.40 58.12 ISOBUTANE
3.20 72.15 N-PENTANE
3.70 86.18 N-HEXANE
8.10 86.18 ISOMERS OF HEXANE
15.40 98.19 C-7 CYCLOPARAFFINS
1.60 112.23 C-8 CYCLOPASAFF1NS
15.00 114.00 MINERAL SPIRITS
3.10 72.15 ISOMERS OF PENTANE
10.00 173.85 METHYLENE BROMIDE
15.00 106.17 ISOMERS OF XYLENE
12.30 78.12 BENZENE
5.00 92.15 TOLUENE
00025
100.00 86.00 UNIDENTIFIED HYDROCARBONS
00.60 C0026
5.30 58.12 ISOBUTANE
36.90 46.07 ETHYL ALCOHOL
38.50 60.09 ISOPROPYL ALCOHOL
8.30 62.07 GLYCOL ETHER
3.20 76.00 PROPYLENE GLYCOL
1.30 116.16 N-BUTYL ACETATE
.60 30.03 FORMALDEHYDE
1.40 58.08 ACETONE
4.50 114.00 NAPHTHA
5.00 00.42 C0031
63.19 16.04 METHANE
1.84 30.07 ETHANE
1.55 28.05 ETHYLENE
2.56 44.09 PROPANE
1.41 42.08 PROPYLENE
.05 26.04 ACETYLENE
4.57 58.12 N-BUTANE
393
403
413
423
433
443
453
463
473
483
493
503
2
13
2
13
23
33
43
53
63
73
83
93
103
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
2
13
2
13
23
33
43
53
63
73
83
93
2
13
23
33
43
53
63
73
E-18
-------
TABLE E-4 (continued)
180:00031 43313
181:00031 43214
182:C0031 43220
183:C0031 43231
184:C0031 43232
185:C0031 43105
186:C0031 43106
187:C0031 43107
188:C0031 43248
189:C0031 43115
190:00031 43122
191:00031 43502
192:C0031 43552
193:00031 45101
194:00031 45201
195:00031 45202
196:C0032
197:C0032 43201
19B:C0032 43203
199:£0032 43204
200:C0032 43205
201:C0032 43206
202:00032 43212
203:00032 43213
204:00032 43214
205:00032 43220
206:00032 43224
207:00032 43231
208:00032 43232
209:00032 43233
210:00032 43105
211:00032 43248
212:00032 43121
213:00032 43122
214:00032 43502
215:00032 45201
216:00032 45202
217:00034 90.00
218:00034 43201
219:00034 43203
220:00034 43205
221:00034 43206
222:00034 43215
223:00034 43224
224:00034 43232
225:00034 43235
226:00034 43238
227:00034 43241
228:00034 43255
229:00034 43258
230:00034 43259
231:00034 43260
232:00034 43281
233:00034 43282
234:00034 43283
235:00034 43284
236:00034 43285
237:00034 43286
238:00034 43287
239:00034 43502
2.10
4.31
2.75
3.25
.53
3.39
.43
.06
.03
1.32
2.29
.42
.02
.30
3.61
.05
56.10 BUTEME
58.12 ISOBUTANE
72.15 N-PENTANE
86.18 N-HEXANE
100.21 N-HEPTANE
86.18 ISOHERS OF HEXANE
100.21 ISOHERS OF HEPTANE
114.23 ISOMERS OF OCTANE
84.16 CYCLOHEXANE
98.19 0-7 CYCLOFARAFFINS
72.15 ISOHERS OF PENTANE
30.03 FORMALDEHYDE
72.10 METHYL ETHYL KETONE
114.00 NAPTHA
78.12 BENZENE
92.15 TOLUENE
00.11 00032
92.36
1.37
.19
.42
.13
.26
.42
.13
.22
.42
.98
.98
.97
.01
.01
.83
.12
.11
.06
.03
16.04 METHANE
28.05 ETHYLENE
44.09 PROPANE
42.08 PROPYLENE
26.04 ACETYLENE
58.12 N- BUTANE
56.10 BUTENE
58.12 ISOBUTANE
72.15 N-PENTANE
70.14 1-PENTENE
86.18 N-HEXANE
100.21 N-HEPTANE
114.23 N-OCTANE
86.18 ISOMERS OF HEXANE
84.16 CYCLOHEXANE
70.14 ISOMERS OF PENTENE
72.15 ISOMERS OF PENTANE
30.03 FORMALDEHYDE
78.12 BENZENE
92.15 TOLUENE
10.00 05.26 00034
1.96
6.15
1.71
0.65
0.89
3.79
0.23
1.33
1.93
4.06
7.32
6.04
6.50
6.00
5.37
3.80
3.16
2.43
2.55
1.34
0.70
5.16
16.04 METHANE
28.05 ETHYLENE
42.08 PROPYLENE
26.04 ACETYLENE
56.12 ISOBUTYLENE
70.14 1-PENTENE
100.21 N-HEPTANE
128.26 N-NONANE
142.29 N-DECANE
156.32 N-UNDECANE
170.34 N-DODECANE
184.36 'J-TRIOECANE
198.40 N-TETRADECANE
212.42 N-PENTADECANE
226.45 N-HEXADECANE
240.48 N-HEPTADECANE
254.51 N-OCTADECANE
268.53 N-NONADECANE
282.56 N-EICOSANE
296.59 N-HENEICOSANE
310.61 N-DOCOSANE
30.03 FORMALDEHYDE
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
E-19
-------
TABLE E-4 (continued)
240:00034
241:00034
242:00034
243:00034
244:00035
245:00035
246:00038
247:00038
248:00038
249:00038
250:00038
251:00038
252:C0038
253:00038
254:00038
255:00038
256:C0038
257:00038
258:00038
259:00038
260:00040
261:00040
262:00040
263:00040
264:00040
265:00040
266:00040
267:00040
268:00040
269:00040
270:00040
271:00040
272:00040
273:00040
274:00040
275:00040
276:00040
277:00040
278:00040
279:00040
280:00040
281:00040
282:00040
283:00040
284:00040
285:00040
286:00040
287:00043
288:00043
289:00043
290:00043
291:00043
292:00043
293:00044
294:00044
295:00044
296:C0044
297:00044
298:00044
299:00045
43503
45202
45207
45221
43000
90.00
43201
43202
43203
43205
43206
43231
43232
45201
45202
45205
45207
45212
45232
14.80
0.21
0.27
11.65
100.00
10.00
4
3
4
17
5
7
31
2
10
3
3
4
.22
.16
.75
.61
.77
.49
.99
.66
.21
.92
.48
.44
0.28
44.05 ACETALDEHYDE
92.15 TOLUENE
120.19 1,3,5-TRiMETHYLBENZENE
118.15 A-METHYLSTYRENE
C0035
86.00 UNIDENTIFIED HYDROCARBONS
00038
16.04
30.07
28.05
42.08
26. M
86.18
100.21
78.12
92.15
106.17
120.19
120.19
132.00
METHANE
ETHANE
ETHYLENE
PROPYLENE
ACETYLENE
N-HEXANE
N- HEPTANE
BENZENE
TOLUENE
1,3 DIMETHYLBENZENE
1,3,5-TRIMETHYLBENZENE
M-ETHYLTOLUENE
TETRAMETHYLBENZENE
00040
43204
43212
43213
43214
43220
43224
43231
43232
43233
• 43235
43105
43106
43238
43107
43248
43108
43115
43122
45102
45201
45202
45103
45104
45105
45107
45108
1
18
1
6
10
5
.69
.76
.72
.25
.22
.98
2.58
0
0
0
8
2
0
2
2
0
0
27
2
1
2
0
0
0
0
0
.71
.17
.04
.90
.22
.15
.31
.19
.26
.25
.76
.30
.18
.55
.25
.86
.10
.59
.02
44.09
58.12
56.10
58.12
72.15
70. U
86.18
100.21
114.23
128.26
86. IB
100.21
142.29
114.23
84.16
128.26
98.19
72.15
106.17
78.12
92.15
134.22
120.19
134.22
120.19
120.19
PROPANE
N-BUTANE
BUTENE
ISOBUTANE
N-PENTANE
1-PEMTENE
N-HEXANE
N-HEPTANE
N-OCTANE
N-NONANE
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
N-DECANE
ISOMERS OF OCTANE
CYCLOHEXANE
ISOMERS OF NONANE
C-7 CYCLOPARAFFINS
ISOMERS OF PENTANE
ISOMERS OF XYLENE
BENZENE
TOLUENE
DIMETHYL ETHEL BENZENE
ISOMERS OF ETHYLTOLUENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
C0043
43107
43108
43109
43110
43817
43201
43202
43203
43204
43212
0
19
50
1
27
66
5
2
3
23
.58
.82
.32
.89
.40
.50
.00
.00
.10
.40
114.23
128.26
142.29
156.32
165.83
16.04
30.07
28.05
44.09
58. 12
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
PERCHLOROETHYLENE
C0044
METHANE
ETHANE
ETHYLENE
PROPANE
N-BUTANE
C0045
233
243
253
263
2
13
2
13
23
33
43
53
63
73
83
93
103
113
123
133
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
243
253
263
2
13
23
33
43
53
2
13
23
33
43
53
2
E-20
-------
TABLE E-4 (continued)
300:C0045
301:00045
302:00045
303:00045
304:00045
305:00045
306:C0045
307: COW 5
308:00045
309:C0045
310:00045
311:00045
312:00045
313:C0045
314:C0045
315:00045
316:00045
317:C0045
318:00045
319:C0045
320:CQ045
321:00045
122: C0045
323: COWS
324:C0045
325: COW 5
326:C0047
327: COM?
328:C0047
329:C0047
330:C0047
331:C0049
332:C0049
333: COOS 1
334: COOS 1
335: COOS 1
336: COOS 1
337: COOS 1
338: COOS 1
339: COOS 1
340:C0051
34 1: COOS 1
342-.C0051
343: COOS 1
344: COOS 1
345:C0051
346: COOS 1
347: COOS 1
348:00051
349: COOS 1
350:00051
35 1: COOS 1
352:C0051
35 3: COOS 1
354:C0081
355:C0081
356:00081
357:C0081
358:00081
359:C0081
43204
43212
43213
43214
43220
43224
43231
43232
43233
4323S
43 IDS
43106
43238
43107
43248
43108
43115
43122
4S102
45201
4S202
45103
45104
45105
45107
4S108
43107
43108
43109
43110
95.00
43000
85.00
43201
43202
43203
43204
43205
43206
43212
43213
43214
43220
43224
43231
43232
43233
43121
43122
43502
43551
45201
94.00
43201
43202
43203
43204
43212
43214
1.69
18.76
1.72
6.25
10.22
5.98
2.58
0.71
0.17
0.04
8.90
2.22
0.15
2.31
2.19
0.26
0.25
27.76
2.30
1.18
2.55
0.25
0.86
0.10
0.59
0.02
0.80
27.30
69.30
2.60
5.00
100.00
15.00 0
79.54
0.84
1.80
0.74
2.61
3.53
1.78
0.04
0.33
0.02
0.04
0.09
0.09
0.09
0.08
0.01
0.01
6.87
1.49
6.00 01,
75.40
9.91
.99
9.91
.99
.99
44.09 PROPANE
58.12 N-BUTANE
56.10 BUTENE ~
58.12 ISOBUTANE
72.15 N-PENTANE
70.14 1-PENTENE
86.18 N-HEXANE
100.21 N- HEPTANE
114.23 N-OCTANE
128.26 N- NONANE
86.18 ISOMERS OF HEXAHE
100.21 I SOMERS OF HEPTANE
142.29 N-DECANE
114.23 ISOMERS OF OCTANE
84.16 CYCLOHEXANE
128.26 ISOMERS OF NONANE
98.19 C-7 CYCLOPARAFFINS
72.15 ISOMERS OF PENTANE
106.17 ISOMERS OF XYLENE
78.12 BENZENE
92.15 TOLUENE
134.22 DIMETHYL ETHYL BENZENE
120.19 ISOMERS OF ETHYLTOLUENE
134.22 ISOMERS OF BUTYLBENZENE
120.19 ISOMERS OF TRIMETHYL8ENZENE
120.19 ISOMERS OF PROPYLBENZENE
C0047
114.23 ISOMERS OF OCTANE
128.26 ISOMERS OF NONANE
142.29 ISOMERS OF DECANE
156.32 ISOMERS OF UNOECANE
00049
86.00 UNIDENTIFIED HYDROCARBONS
.01 C0051
16.04 METHANE
30.07 ETHANE
28.05 ETHYLENE
44.09 PROPANE
42.08 PROPYLENE
26.04 ACETYLENE
58.12 N- BUTANE
56.10 BUTENE
58.12 ISOBUTANE
72.15 N-PENTANE
70.14 1-PENTENE
86.18 N-HEXANE
100.21 N-HEPTANE
114.23 N-OCTANE
70.14 ISOMERS OF PENTENE
72.15 ISOMERS OF PENTANE
30.03 FORMALDEHYDE
58.08 ACETONE
78.12 BENZENE
.81 C0081
16.04 METHANE
30.07 ETHANE
28.05 ETHYLENE
44.09 PROPANE
58.12 N-BUTANE
58.12 ISOBUTANE
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
243
253
263
2
13
23
33
43
2
13
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
2
13
23
33
43
53
63
E-21
-------
TABLE E-4 (continued)
360: COOS 1
361:00085
362:00085
363:00085
364:00085
365:C0085
366:00085
367:C0085
368:C0085
369:C0085
370:C0085
371:00085
372:00085
373:C0085
374:00085
375:C0085
376:C0085
377:00085
376:00085
379:00085
380:00085
381:00085
382:00085
383:00085
384:00085
385:00086
386:00086
387:00086
388:00086
389:00086
390:00086
391:00086
392:00086
393:00086
394:00086
395:00086
396.-C0086
397:00086
398:00086
399:00086
400:00086
401:00090
402:C0090
403:00090
404:00090
405:00090
406:00090
407:00090
408:00090
409:00090
410:00090
411:00090
412:00090
413:00090
4U-.C0090
415:00090
416:00090
417:00090
418:00090
419:00090
43502
85.00
43201
43202
43203
43204
43205
43206
43212
43213
43218
43220
43231
43232
43233
43235
43105
43248
43108
43116
43122
43502
43822
45201
45202
1.81
15.00 00
53.97
5.25
18.00
.58
1.79
1.46
.07
.63
.30
.04
.26
1.33
.03
.01
.01
.01
.01
.02
.07
.06
2.60
12.96
.57
30.03
FORMALDEHYDE
.06 C008S
16.04
30.07
28.05
44.09
42.08
26.04
58.12
56.10
54.09
72.15
86.18
100.21
114.23
128.26
86.18
84.16
128.26
112.23
72.15
30.03
93.19
78.12
92.15
METHANE -
ETHANE
ETHYLENE
PROPANE
PROPYLENE
ACETYLENE
N-BUTANE
BUTENE
1,3-BUTADIENE
N-PENTANE
N-HEXANE
N-HEPTANE
N-OCTANE
N-NONANE
I SOWERS OF HEXANE
CYCLOHEXANE
1SOHERS OF NONANE
0-8 CYCLOPARAFFINS
ISOHERS OF PENTANE
FORMALDEHYDE
TRIMETHYLFLUOROSILANE
BENZENE
TOLUENE
17.96 00086
43201
43204
43212
43214
43220
43231
43232
43105
43106
43107
43248
43122
43502
45201
45202
43105
43106
43107
43108
43109
43115
43116
43117
43122
43201
43202
43203
43Z04
43205
43206
43212
43213
43214
36.70
2.13
7.61
1.21
4.06
4.97
12.48
1.98
.77
1.39
.44
5.63
17.96
1.78
.89
11.
1.03
.48
.18
.13
.09
.23
.06
.03
1.40
9.05
14.96
.13
15.29
11.90
.01
21.11
.06
4.73
16.04
44.09
58.12
58.12
72.15
86.18
100.21
86.18
100.21
114.23
84.16
72.15
30.03
78.12
92.15
,29
86.18
100.21
114.23
128.26
142.29
98.19
112.23
126.26
72.15
16.04
30.07
28.05
44.09
42.08
26.04
58.12
56.10
58.12
METHANE
PROPANE
N-BUTANE
ISOBUTANE
N-PENTANE
N-HEXANE
N-HEPTANE
ISOHERS OF HEXANE
1SOMERS OF HEPTANE
ISOHERS OF OOTANE
CYCLOHEXANE
ISOHERS OF PENTANE
FORMALDEHYDE
BENZENE
TOLUENE
00090
1 SOBERS OF HEXANE
ISOHERS OF HEPTANE
ISOHERS OF OCTANE
ISOHERS OF NONANE
ISOMERS OF DECANE
0-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
ISOMERS OF PENTANE
METHANE
ETHANE
ETHYLENE
PROPANE
PROPYLENE
ACETYLENE
N-BUTANE
BUTENE
ISOBUTANE
73
2
13
23
33
34
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
E-22
-------
TABLE E-4 (continued)
420:00090 43220
421:00090 43231
422:0)090 43232
423:00090 43233
424:C0090 43235
425:C0090 43238
426:00090 43248
427:C0090 43502
428:00090 43551
429:00090 45102
430:C0090 45201
431:C0090 45202
432:C0091
433:C0091 43105
434:C0091 43106
435:C0091 43107
436:C0091 43108
437:C0091 43109
438:C0091 43110
439:00091 43115
440:00091 43122
441:00091 43201
442:00091 43202
443:00091 43203
444:00091 43204
445:00091 43205
446:00091 43212
447:00091 43213
448:00091 43214
449:00091 43220
450:00091 43224
451:00091 43231
452:00091 43232
453:00091 43233
454:00091 43248
455:00091 43301
456:00091 43302
457:00091 43304
458:00091 43306
459:00091 43432
460:00091 43433
461:00091 43502
462:00091 43551
463:00091 43552
464:00091 43560
465:00091 43815
466:00091 43817
467:00091 45104
468:00091 45201
469:00091 45202
470:00091 45221
471:00091 45107
472:00094
473:00094 43105
474:00094 43106
475:00094 43107
476:00094 43108
477:00094 43115
478:00094 43122
479:00094 43204
1.23
1.73
.23
.48
.08
.06
.02
11.29
3.61
.10
.11
.18
00,
.83
.39
1.08
6.85
17.31
.64
.48
6.70
1.74
.54
.02
1.27
.01
5.01
.05
2.02
3.52
.17
3.51
.41
.18
1.61
2.94
3.24
3.38
.30
.04
.49
.05
7.14
6.68
3.40
.05
5.83
.01
1.67
6.05
4.39
.01
8.90
2.00
1.90
.20
.20
29.00
1.80
72.15 N-PENTANE
86.18 N-HEXANE
100.21 N- HEPTANE
114.23 N-OCTANE
128.26 N- NONANE
142.29 N-DECANE
84.16 CYCLOHEXANE
30.03 FORMALDEHYDE
58.08 ACETONE
106.17 ISOMERS OF XYLENE
78.12 BENZENE
92.15 TOLUENE
.05 00091
86.18 ISOMERS OF HEXANE
100.21 ISOMERS OF HEPTANE
114.23 ISOMERS OF OCTANE
128.26 ISOMERS OF NONANE
142.29 ISOMERS OF DECANE
156.32 ISOMERS OF UNDEJCANE
98.19 C-7 CYCLOPARAFFINS
72.15 ISOMERS OF PENTANE
16.04 METHANE
30.07 ETHANE
28.05 ETHYLENE
44.09 PROPANE
42.08 PROPYLENE
58.12 N-BUTANE
56.10 BUTENE
58.12 ISOBUTANE
72.15 N-PENTANE
70.14 1-PENTENE
86.18 N-HEXANE
100.21 N-HEPTANE
114.23 N-OCTANE
84.16 CYCLOHEXANE
32.04 METHYL ALCOHOL
46.07 ETHYL ALCOHOL
60.09 ISOPROPYL ALCOHOL
74.12 ISOBUTYL ALCOHOL
74.08 METHYL ACETATE
88.10 ETHYL ACETATE
30.03 FORMALDEHYDE
58.08 ACETONE
72.10 METHYL ETHYL KETONE
100.16 METHYL ISOBUTYL KETONE
99.00 ETHYLENE DICHLORIDE
165.83 PERCHLOROETHYLENE
120.19 ISOMERS OF ETHYLTOLUENE
78.12 BENZENE
92.15 TOLUENE
118.15 A-METHYLSTYRENE
120.19 ISOMERS OF TRIMETHYLBENZENE
00094
86.18 ISOMERS OF HEXANE
100.21 ISOMERS OF HEPTANE
114.23 ISOMERS OF OCTANE
128.26 ISOMERS OF NONANE
98.19 C-7 CYCLOPARAFFINS
72.15 ISOMERS OF PENTANE
44.09 PROPANE
193
203
213
223
233
243
253
263
273
283
293
303
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
243
253
263
273
283
293
303
313
323
333
343
353
363
373
383
393
2
13
23
33
43
53
63
73
E-23
-------
TABLF E-4 (continued)
480:00094
481:00094
482:00094
483:C0094
484:00094
485:00094
486:00094
487:00094
488:00094
489:00094
490:00094
491:00094
492:00094
493:00094
494:00101
495:00101
496:00101
497:00101
498:00101
499:C0101
500:00101
501:00101
502:00101
503:00101
504:00101
505:00101
506:00101
507:00101
508:00101
509:C0101
510:00101
511:00101
512:00101
513:00101
514:00101
515:00101
516:00101
517:00103
518:00103
519:00103
520:C0103
521:00103
522:00103
523:00103
524:00103
525:00103
526:00103
527:00103
528:00103
529:00103
530:00103
531:00103
532:00103
533:00103
534:00103
535:00103
536:00103
537:00103
538:00103
539:00103
43212
43213
43214
43220
43224
43231
43232
43233
43248
45102
45103
45104
45201
45202
43204
43212
43213
43214
43220
43224
43231
43232
43233
43105
43106
43107
43248
43108
43115
43122
45102
45201
45202
45103
45104
45107
43201
43202
43204
43212
43214
43220
43231
43232
43233
43105
43106
43107
43248
43108
43109
43110
43122
43301
43302
43304
43551
43552
19.80
1.80
6.60
10.60
6.20
2.50
.60
.10
2.10
1.60
.40
.50
1.10
2.10
1.80
19.80
1.80
6.60
10.60
6.20
2.50
0.60
0.10
8.90
2.00
1.90
2.10
0.20
0.20
29.00
1.60
1.10
2.10
0.10
0.50
0.30
2.54
0.63
3.04
8.52
4.09
6.47
3.74
0.95
0.64
1.90
1.27
2.13
0.63
6.62
16.06
0.58
5.59
3.24
3.24
3.29
5.78
5.78
58.12
56.10
58.12
72.15
70.14
86.18
100.21
114.23
84.16
106.17
134.22
120.19
78.12
92.15
44.09
58.12
56.10
58.12
72.15
70.14
86.18
100.21
114.23
86.18
100.21
114.23
84.16
128.26
98.19
72.15
106.17
78.12
92.15
134.22
120.19
120.19
16.04
30.07
44.09
58.12
58.12
72.15
86.18
100.21
114.23
86.18
100.21
114.23
84.16
128.26
142.29
156.32
72.15
32.04
46.07
60.09
58.08
72.10
N-BUTANE
BUTEME
1SOBUTAKE
N-PENTANE
1-PENTENE
N-HEXANE
N-HEPTANE
N-OCTANE
CYCtOHEXANE
ISOMERS OF XYLENE
0IMETHYLETHYIBENZENE
ISOMERS OF ETHYLTOLUENE
BENZENE
TOLUENE
00101
PROPANE
N-BUTANE
BUTENE
1SOBUTANE
N-PENTANE
1-PENTENE
N-HEXANE
N-HEPTANE
N-OCTANE
ISOMERS OF HEXANE
ISOKERS OF HEPTANE
ISOMERS OF OCTANE
CYCLOHEXANE
ISOMERS OF NONANE
0-7 CYCLOPARAFF1NS
ISOMERS OF PENTANE
ISOMERS OF XYLENE
BENZENE
TOLUENE
DIMETHYL ETHEL BENZENE
ISOMERS OF ETHYLTOLUENE
ISOMERS OF TRIMETHYLBENZENE
00103
METHANE
ETHANE
PROPANE
N-BUTANE
ISOBUTANE
N-PENTANE
N-HEXANE
N-HEPTANE
N-OCTANE
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
CYOLOHEXANE
ISOMERS OF NONANE
ISOMERS OF OECANE
ISOMERS OF UNDECANE
ISOMERS OF PENTANE
METHYL ALCOHOL
ETHYL ALCOHOL
ISOPROPYL ALCOHOL
ACETONE
METHYL ETHYL KETONE
83
93
103
113
123
133
143
153
163
173
183
193
203
213
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
E-24
-------
TABLE E-4 (continued)
540: CO 103
541:00103
542:C0103
543:00103
544:C0110
545:00110
546:00110
547:00110
548:C0110
549:C0110
550:C0110
551:00110
552:00110
553:C0110
554:00110
555:C0110
556:C0110
557:00110
558:00110
559:00110
560:00110
561:00110
562:00110
563:00110
564:00110
565:00110
566:00111
567:00111
566:00111
569:00111
570:00111
571:00111
572:00111
573:00111
574:00111
575:00111
576:00111
577:00111
578:00111
579:00111
580:00111
581:00111
582:00111
583:00111
584:00111
585:00111
586:00111
587:00111
588:00113
589:00113
590:00113
591:00113
592:00113
593:00113
594:00113
595:00113
596:00113
597:00113
598:00113
599:C0113
43560
43817
45102
45202
43231
43248
43301
43302
43304
43305
43306
43369
43370
43435
43443
43446
43450
43451
43551
43552
43559
43560
45102
45202
45203
43231
43248
43301
43302
43304
43305
43306
43369
43370
43435
43443
43446
43450
43451
43551
43552
43559
43560
45102
45202
45203
43201
43202
43203
43204
43205
43212
43213
43214
43224
43304
43502
2.98
5.78
2.31
2.31
20.70
20.70
3.90
.60
16.40
1.60
.60
.80
.60
2.50
1.30
1.50
.50
6.10
3.20
5.60
.70
.60
2.60
5.20
4.30
20.70
20.70
3.90
.60
16.40
1.60
.60
.80
.60
2.50
1.30
1.50
.50
6.10
3.20
5.60
.70
.60
2.60
5.20
4.30
09.
38.66
8.20
1.24
2.87
14.27
8.45
5.77
1.37
5.01
.11
9.17
100.16
165.83
106.17
92.15
86.18
84.16
32.04
46.07
60.09
74.12
74.12
76.00
62.07
116.16
90.00
116.16
73.09
144.21
58.08
72.10
100.16
100.16
106.17
92.15
106.17
86.18
84.16
32.04
46.07
60.09
74.12
74.12
76.00
62.07
116.16
90.00
116.16
73.09
144.21
58.08
72.10
100.16
100.16
106.17
92.15
106.17
METHYL ISOBUTYL KETONE
PEROHLOROETHYLENE
1SOMERST3F XYLENE
TOLUENE
00110
N-HEXANE
CYCLOHEXANE
METHYL ALCOHOL
ETHYL ALCOHOL
ISOPROPYL ALCOHOL
N- BUTYL ALCOHOL
IS06UTYL ALCOHOL
PROPYLENE GLVCOL
ETHYLENE GLYCOL
N-BUTYL ACETATE
CELLOSOLVE ACETATE
ISOBUTYL ACETATE
DIMETHVLFORMAM1DE
ISOBUTVL ISOBUTYRATE
ACETONE
METHYL ETHYL KETONE
METHYL N-BUTYL KETONE
METHYL ISOBUTYL KETONE
ISOMERS OF XYLENE
TOLUENE
ETHYLBENZENE
com
N-HEXANE
CYCLOHEXANE
METHYL ALCOHOL
ETHYL ALCOHOL
ISOPROPYL ALCOHOL
N-BUTYL ALCOHOL
ISOBUTYL ALCOHOL
PROPYLENE GLYCOL
ETHYLENE GLYCOL
N-BUTYL ACETATE
CELLOSOVE ACETATE
ISOBUTYL ACETATE
DIMETHYLFORMAMIDE
ISOeUTYLISOBUTYRATE
ACETONE
METHYL ETHYL KETONE
METHYL N-BUTYL KETONE
METHYL ISOBUTYL KETONE
ISOMERS OF XYLENE
TOLUENE
ETHYLBENZENE
,17 C0113
16.04
30.07
28.05
44.09
42.08
58.12
56.10
58.12
70.14
60.09
30.03
METHANE
ETHANE
ETHYLENE
PROPANE
PROPYLENE
N-BUTANE
BUTENE
ISOBUTANE
1-PENTENE
ISOPROPYL ALCOHOL
FORMALDEHYDE
233
243
253
263
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
2
13
23
33
43
53
63
73
83
93
103
113
E-25
-------
TABLE E-4 (continued)
600:00113
601:C0116
602:C0116
603:00116
604:00116
60S:C0116
606:00116
607:C0116
608:C0116
609:C0116
610:C0117
611:C0117
612:00117
613:C0117
6H:C0117
615:C0117
616:C0117
617:C0117
618:C0117
619:C0117
620:00117
621:C0117
622:00120
623:00120
624:00120
625:00120
626:00120
627:00120
628:00121
629:00121
630:00121
631:00121
632:00121
633:00121
634:00121
635:00121
636:00121
637:00121
638:00121
639:00121
640:00121
641:00121
642:K0001
643:K0001
644:tt>001
645:K0001
646: K0001
647:K0001
648:K0002
649:K0002
650:K0002
651:K0002
652:K0002
653:K0002
654:K0002
655:K0002
656:K0002
657:K0002
658:K0002
659:K0002
43802
85.00
43201
43202
43302
43304
43434
43551
43721
43740
43201
43202
43204
43242
43212
43214
43220
43123
43817
45102
45202
97.00
43201
43212
43231
43502
43551
95.00
43201
43202
43203
43205
43206
43231
43232
45201
45202
45205
45207
45212
45232
98.00
43212
43231
43502
43551
43201
98.00
43105
43106
43107
43122
43204
43212
43214
43220
43231
43232
43502
4.89
15.00
70.00
20.00
2.00
2.00
2.00
2.00
1.00
1.00
00.
98.60
0.10
0.10
0.20
0.20
0.10
0.10
0.10
0.30
0.10
0.10
3.00 00.
11.00
14.00
5.00
.12
28.00
5.00
4.22
3.16
4.75
17.61
5.77
7.49
31.99
2.66
10.21
3.92
3.48
4.44
0.28
2.00 42.
14.00
5.00
42.00
28.00
11.00
2.00 48.
5.20
2.60
4.70
5.50
1.20
12.20
4.10
4.70
10.80
.30
48.70
84.94
D1CHLOROMETHANE
00116
16.04
30.07
46.07
60.09
102.
13
58.08
45.09
59.11
00
METHANE'
ETHANE
ETHYL ALCOHOL
ISOPROPYL ALCOHOL
PROPYL ACETATE
ACETONE
ETHYLAMINE
TRIMETHYLAM1NE
C0117
16.04
30.
07
44.09
70.
58.
58.
72.
136.
165.
106.
92.
12
14
12
12
15
23
83
17
15
METHANE
ETHANE
PROPANE
CrCLOPENTANE
N-BUTANE
I SO- BUTANE
N-PENTANE
TERPENES
PERCHLOROETHYLENE
ISOMERS OF XYLENE
TOLUENE
C0120
16.04
58.
86.
30.
58.
12
18
03
08
METHANE
N-BUTANE
N-HEXANE
FORMALDEHYDE
ACETONE
00121
16.
30.
28.
42.
26.
86.
100.
78.
92.
106.
120.
120.
132.
00
58.
86.
30.
58.
16.
70
86.
100.
114.
72.
44.
58.
58.
72.
86.
100.
30.
04
07
05
08
04
18
21
12
15
17
19
19
00
METHANE
ETHANE
ETHYLENE
PROPYLENE
ACETYLENE
N-HEXANE
N- HEPTANE
BENZENE
TOLUENE
1,3 DIMETHYLBENZENE
1,3,5-TRIMETHYLBENZENE
M-ETHYLTOLUENE
TETRAHETHYLBENZENE
101004
12
18
03
08
04
N-BUTANE
N-HEXANE
FORMALDEHYDE
ACETONE
METHANE
101005
18
21
23
15
09
12
12
15
18
21
03
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF PENTANE
PROPANE
N-BUTANE
ISOBUTANE
N-PENTANE
N-HEXANE
N-HEPTANE
FORMALDEHYDE
123
2
13
23
33
43
53
63
73
83
2
13
23
33
43
53
63
73
83
93
103
113
2
13
23
33
43
53
2
13
23
33
43
53
63
73
83
93
103
113
123
133
2
13
23
33
43
53
2
13
23
33
43
53
63
73
83
93
103
113
E-26
-------
TABLE E-4 (continued)
660:K0003
661:K0003
662:tt>003
663: 1C 0003
664:K0003
665:K0003
666:tf>003
667:K0003
668:1:0003
669:K0003
670-.K0003
671:K0004
672:K0004
673:IC0004
674:K0004
675.-K0004
676:K0004
677:K0004
678:K0004
679:1(0005
680:K0005
681:IC0005
682:K0005
683:K0005
684:10)005
68S-.KOOOS
686:K0007
687:K0007
688:K0007
689:K0008
690:K0008
691:1:0008
692:K0008
693:K0008
694:K0008
69S:K0008
696:K0008
697:K0008
698-.K0009
699:K0009
700:K0009
701:K0009
702:K0009
703: 1C 0009
704:K0009
705:K0009
706:1(0009
707:K0010
708:K0010
709:K0010
710:K0010
711:K0010
712:K0010
713-.K0010
7K:K0010
715:K0011
716:K0011
717:K)011
718:K0011
719.-K0011
95.00
43105
43122
43204
43212
43220
43248
45202
43502
43201
45201
95.00
43204
43212
43214
43205
43502
43201
43202
97.00
43203
43205
43206
43201
43202
45201
94.00
43502
43201
95.00
43201
43202
43203
43305
43206
43213
43218
45201
90.00
43203
43205
43213
43218
43206
43201
43202
45201
94.00
43204
43212
43214
43203
43502
43201
43202
95.00
43204
43203
43205
43213
5.00 8
1.00
9.00
4.00
9.00
6.00
1.00
2.00
8.00
56.00
4.00
5.00 7,
18.90
23.10
4.40
17.50
7.60
7.60
20.90
3.00
11.70
.30
.80
82.80
2.50
1.90
6.00 30.
30.00
70.00
5.00 00.
11.60
2.80
28.70
17.30
11.30
13.40
7.00
7.90
10.00
28.70
17.30
13.40
7.00
11.30
11.60
2.80
7.90
6.00 01.
10.00
1.00
1.00
1.00
1.00
76.00
10.00
5.00 00.
.50
27.70
1.90
.10
.00 101006
86.18 1 SOWERS OF HEXANE
72.15 ISOMERS'OF PENTANE
44.09 PROPANE
58.12 N-BUTANE
72.15 N-PENTANE
84.16 CYCLOHEXAME
92.15 TOLUENE
30.03 FORMALDEHYDE
16.04 METHANE
78.12 BENZENE
.60 101007
44.09 PROPANE
58.12 k- BUTANE
58.12 ISOBUTANE
42.08 PROPYLENE
30.03 FORMALDEHYDE
16.04 METHANE
30.07 ETHANE
102008
28.05 ETHYLENE
42.08 PROPYLENE
26.04 ACETYLENE
16.04 METHANE
30.07 ETHANE
78.12 BENZENE
.00 201002
30.03 FORMALDEHYDE
16.04 METHANE
.00 201003
16.04 METHANE
30.07 ETHANE
28.05 ETHYLENE
42.08 PROPYIENE
26.04 ACETYLENE
56.10 BLITENE
54.09 1,5 BUTADIENE
78.12 BENZENE
202001
28.05 ETHYLENE
42.08 PROPYLENE
56.10 BUTENE
54.09 1,3-BUTADIENE
26.04 ACETYLENE
16.04 METHANE
30.07 ETHANE
78.12 BENZENE
00 202002A
44.09 PROPANE
58.12 N-BUTANE
58.12 ISOBUTANE
28.05 ETHYLENE
30.03 FORMALDEHYDE
16.04 METHANE
30.07 ETHANE
00 303003
44.09 PROPANE
28.05 ETHYLENE
42.08 PROPYLENE
56.10 BUTENE
2
13
23
33
43
53
63
73
83
93
103
2
13
23
33
43
53
63
73
2
13
23
33
43
53
63
2
13
23
2
13
23
33
43
53
63
73
83
2
13
23
33
43
53
63
73
83
2
13
23
33
43
53
63
73
2
13
23
33
43
E-27
-------
TABLE E-4 (continued)
720:K0011
721:K0011
722:K0011
723:K0011
724:K0011
725:K0011
726:K0012
727:K0012
728:K0012
729:K0013
730:lt0013
731:K0013
732:KOOt3
733:K0013
734:10)013
735:K0016
736:K0016
737:K0016
738:K0016
739:K0021
740:K0021
741:K0021
742:K0021
743:1(0021
744:K0021
745.-K0021
746:K0022
747:K0022
748:ica022
749:K0022
750:K0022
751:K0022
752:tt>022
753:K0022
754:K0022
755:K0022
756:K0022
757:K0022
758:1(0024
759:1(0024
760:tt>024
761:K0024
762:K0024
763:K0024
764:K0024
765:K0024
766:K0024
767:K0024
768:K0024
769:K0024
770:K0024
771.-K0024
772:IC0024
773:K0024
774:K0024
775:IC0024
776:K0024
777:K0024
778:K0024
779:K0024
43218
45202
43206
43201
43202
45201
95.00
43822
43201
95.00
43203
43205
43206
43201
43202
95.00
43204
43822
43201
00.00
43105
43106
43231
43232
43233
43502
00.00
43105
43106
43107
43204
43212
43214
43220
43231
43232
43203
43202
90.00
43105
43107
43115
43116
43117
43122
43204
43212
43214
43220
43231
43232
43233
43242
43121
43203
43205
43213
43224
45202
43201
.50
.70
1.20
45.30
8.00
14.10
5.00 00.
84.20
15.80
5.00
5.90
3.00
14.80
73.30
3.00
5.00
39.90
49.00
11.10
00.00 02.
1.80
3.60
1.80
15.80
74.50
2.50
54.
92.
26.
16.
30.
78.
.00
93.
16.
09
15
04
04
07
12
1,3 -BUTADIENE
TOLUENE
ACETYLENE
METHANE
ETHANE
BENZENE
303008A
19
04
TR1METHYLFLUOROSILANE
METHANE
303008B
28.
42.
26.
16.
30.
05
08
04
04
07
ETHYLENE
PROPYLEME
ACETYLENE
METHANE
ETHANE
303009C
44.
93.
16.
.50
86.
100.
86.
100.
114.
30.
00.00 00.00
12.00
11.00
1.00
13.00
18.00
8.00
18.00
2.00
14.00
2.00
1.00
10.00 00.
3.40
7.40
2.90
.40
1.50
1.10
10.20
11.60
.70
6.30
4.90
2.00
2.70
2.50
.50
.30
2.00
7.00
3.20
1.90
21.30
86.
100.
114.
44.
58.
58.
72.
86.
09
19
04
PROPANE
TR1METHYLFLUOROSILANE
METHANE
305001*
18
21
18
21
23
03
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
N- HEXANE
M- HEPTANE
N-OCTANE
FORMALDEHYDE
305001B
18
21
23
09
12
12
15
18
100.21
28.
30.
.00
86.
114.
98.
112.
126.
72.
44.
58.
05
07
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
PROPANE
N- BUTANE
ISOBUTANE
N-PENTANE
N-HEXANE
N- HEPTANE
ETHYLENE
ETHANE
305001D
18
23
19
23
26
15
09
12
58.12
72.15
86.18
100.21
114.23
70.14
70.14
28.05
42.08
56.
.10
70.14
92.15
16.04
ISOMERS OF HEXANE
ISOMERS OF OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
ISOMERS OF PENTANE
PROPANE
N- BUTANE
ISOBUTANE
N-PENTANE
N-HEXANE
N-HEPTANE
N-OCTANE
CYCLOPENTANE
ISOMERS OF PENTENE
ETHYLEHE
PROPYLENE
BUTENE
1-PENTENE
TOLUENE
METHANE
53
63
73
83
93
103
2
13
23
2
13
23
33
43
53
2
13
23
33
2
13
23
33
43
53
63
2
13
23
33
43
53
63
73
83
93
103
113
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
E-28
-------
TABLE E-4 (continued)
780:K0024 43202
781:1:0024 45201
782:K0025 95.00
783:1:0025 45105
784:K0025 43122
785:K0025 43204
786:K0025 43212
787:K0025 43220
788:IC0025 43248
789:K0025 45202
790:K0025 43502
791:1(0025 43201
792:IC0025 45201
793:1(0026 95.00
794:K0026 43105
795:1(0026 43115
796:lt0026 43122
797:K0026 43204
79B:K0026 43212
799:1:0026 43214
800:K0026 43220
801:K0026 43203
802:1:0026 43205
803:K0026 43213
804:K0026 43201
805:K0026 43202
806:K0026 45201
807:K0029 85.00
808:K0029 43105
809:K0029 43502
810:l!0029 43201
811:K0031 00.00
812:K0031 43105
813:K0031 43115
814:K0031 43116
815:K0031 43122
816:K0031 43204
817:K0031 43212
818:1:0031 43214
819:K0031 43220
820:K0031 43231
821:1:0031 43201
822:K0031 43202
823:K0031 45201
824:K0035 00.00
825:K0035 43122
826:K0038
827:1:0038 43105
828:C0038 43106
829:K0038 43107
830:K0038 43108
831:K0038 43109
832:PC0038 43115
833:K0038 43116
834:K0038 43117
835:>:0038 43122
836:K0038 43204
837:K0038 43212
838:K0038 43214
839:C0038 43220
5.40
.80
30.07 ETHANE
78.12 BENZENE
5.00 8.00 305002A '
1.00
9.00
4.00
9.00
6.00
1.00
2.00
8.00
56.00
4.00
5.00
8.10
3.70
5.70
5.50
10.10
11.20
5.30
2.00
3.90
5.90
15.70
4.60
9.50
15.00 51.
13.00
51.00
36.00
00.00 00.
12.20
16.90
5.20
10.10
5.90
14.30
4.50
12.00
11.90
2.90
1.70
2.40
86.18 I SOBERS OF HEXANE
72.15 ISOMERS OF PENTANE
44.09 PROPANE
58.12 N-BUTANE
72.15 N-PENTANE
84.16 CYCLOHEXANE
92.15 TOLUENE
30.03 FORMALDEHYDE
16.04 METHANE
78.12 BENZENE
305002B
86.18 ISOMERS OF HEXANE
98.19 C-7 CYCLOPARAFFINS
72.15 ISOMERS OF PENTANE
44.09 PROPANE
58.12 N-BUTANE
58.12 ISOBUTANE
72.15 N-PENTANE
28.05 ETHYLENE
42.08 PROPYLENE
56.10 BUTENE
16.04 METHANE
30.07 ETHANE
78.12 BENZENE
.00 306002
86.18 ISOMERS OF HEXANE
30.03 FORMALDEHYDE
16.04 METHANE
.00 306005
86.18 ISOMERS OF HEXANE
98.19 C-7 CYCLOPARAFFINS
112.23 C-8 CYCLOPARAFFINS
72.15 ISOMERS OF PENTANE
44.09 PROPANE
58.12 N-BUTANE
58.12 ISOBUTANE
72.15 N-PENTANE
86.18 N-HEXANE
16.04 METHANE
30.07 ETHANE
78.12 BENZENE
00.00 00.00 306007
100.00
5.50
4.10
2.80
3.10
1.90
1.10
.10
.80
6.60
3.70
7.90
.80
11.10
72.15 ISOMERS OF PENTANE
306008X
86.18 ISOMERS OF HEXANE
100.21 ISOMERS OF HEPTANE
114.23 ISOMERS OF OCTANE
128.26 ISOMERS OF NONANE
142.29 ISOMERS OF DECANE
98.19 C-7 CYCLOPARAFFINS
112.23 C-8 CYCLOPARAFFINS
126.26 C-9 CYCLOPARAFFINS
72.15 ISOMERS OF PENTANE
44.09 PROPANE
58.12 N-BUTANE
58.12 ISOBUTANE
72.15 N-PENTANE
223
233
2
13
23
33
43
53
63
73
83
93
103
2
13
23
33
43
53
63
73
93
103
113
123
133
143
2
13
23
33
2
13
23
33
43
53
63
73
83
93
103
113
123
2
13
2
13
23
33
43
53
63
73
83
93
103
113
123
133
E-29
-------
TABLE E-A (continued)
840:K0038
841:K0038
842:W038
843:K0038
B44:IC0038
845:K0038
846: 1C 0038
S47:K0038
848:K0038
B49:K0038
850:K0038
851:K0038
8S2:K0039
853:1:0039
854:K0039
855:K0039
856:K0039
857:IC0039
858:K0039
859:K0039
860:tt>039
861:K0039
862:IC0039
863:K0039
864:K0039
865:K0047
866:K0047
S67:K0047
868:K0047
869:K0047
870:lt0051
871:K0051
872:K0051
873:lt0051
874:K0051
875:IC0053
876:K0053
B77:IC0053
878.-K0053
879:K0053
880:K0053
881:K0053
S82:K0053
883:K0053
884:K0053
885:K0053
886:K0053
887:K0053
888:K0053
889:1(0053
890:K0053
891:K0053
892:K0053
893:K0053
894:K0053
895:K0053
B96:K0053
897:K0056
898:K0056
899:K0056
43231
43232
43233
43235
43238
43248
43213
45102
45202
43201
43202
45201
00.00
43105
43106
43122
43204
43212
43214
43220
43231
43205
43213
43201
43202
00.00
43204
43214
43205
43202
95.00
43204
43502
43201
43202
11.00
8.50
12.00
3.90
5.10
.50
.20
1.30
3.00
3.30
1.20
.50
00.00 00
1.00
.10
8.60
16.00
23.20
10.00
7.60
4.60
8.80
1.20
13.30
5.60
00.00 00
90.40
.40
5.10
4.10
5.00 20
30.00
20.00
20.00
30.00
86.18
100.21
114.23
128.26
142.29
84.16
56.10
106.17
92.15
16.04
30.07
78.12
N-HEXANE
N-HEPTANE
N-OCTAkt
N-NONANE
N-DECANE
CYCLOHEXANE
BUTENE
ISOHERS OF
TOLUENE
METHANE
ETHANE
BENZENE
XYLENE
.00 306008Z
86.18
100.21
72.15
44.09
58.12
58.12
72.15
86.18
42.08
56.10
16.04
30.07
ISOHERS OF
ISOMERS OF
ISOMERS OF
PROPANE
N- BUTANE
IS06UTANE
N-PENTANE
N-HEXANE
PROPYLENE
BUTENE
METHANE
ETHANE
HEXANE
HEPTANE
PENTANE
.00 306008N
44.09
58.12
42.08
30.07
PROPANE
IS06UTANE
PROPYLENE
ETHANE
.00 306009
44.09
30.03
16.04
30.07
PROPANE
FORMALDEHYDE
METHANE
ETHANE
00.00 306013
43105
43107
43108
43109
43115
43117
43122
43204
43212
43214
43220
43231
43232
43233
43235
43248
45102
45202
43201
43202
45201
90.00
43106
43107
.80
.70
2.50
2.00
.30
.60
.90
26.70
22.60
20.70
.20
.80
.20
.80
1.00
.20
.80
.80
.90
16.20
.30
10.00
.70
.60
86.18
114.23
128.26
142.29
98.19
126.26
72.15
44.09
58.12
58.12
72.15
86.18
100.21
114.23
128.26
84.16
106.17
92.15
16.04
30.07
78.12
ISOHERS OF
ISOMERS OF
ISOHERS OF
ISOHERS OF
HEXANE
OCTANE
NONANE
DECANE
C-7 CrCLOPARAFFINS
C-9 CYCLOPARAFFINS
ISOHERS OF
PROPANE
N-BUTANE
ISOBUTANE
N-PENTANE
N-HEXANE
N-HEPTANE
N -OCTANE
N-NONANE
PENTANE
CYCLOHEXANE
ISOHERS OF
TOLUENE
METHANE
ETHANE
BENZENE
XYLENE
402008C
100.21
114.23
ISOHERS OF
ISOHERS OF
HEPTANE
OCTANE
143
153
163
173
183
193
203
213
223
233
243
253
2
13
23
33
43
53
63
73
83
93
103
113
123
2
13
23
33
43
2
13
23
33
43
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
2
13
23
E-30
-------
TABLE £-4 (continued)
900:110056
901:KOOS6
902:K0056
903:K0056
904:K0056
905:K0056
906-.K0056
907:K0056
908:K0056
909:K0056
910:K0060
911.-K0060
912.-IC0060
913:K0060
914:K0060
91 5: K 0060
916:K0060
917:K0060
918:K0066
919-.K0066
920 :K 0066
921 :K0066
922:K0066
923 :K 0067
924:K0067
925:K0068
926:K006S
927:K0071
928:K0071
929.-K0071
930:K0071
931:K0071
932:K0071
933:K0072
934-.K0072
935:K0072
936:K0072
937:K0072
938:K0072
939:K0072
940:K0072
941:K0072
942:K0072
943:K0072
944:K0072
945:K0076
946:K0076
947-.K0076
948:K0076
949:K0076
950:IC0076
951:K0076
952:»C0076
953:K0076
954:IC0076
955:K0076
956.-K0076
957:<0076
958:1(0076
959:K0076
13108
43115
43116
43117
43231
43232
43233
43235
45102
45202
00.00
43551
43552
43560
43301
43302
43304
43305
00.00
43551
43552
43560
43367
00.00
43860
00.00
43205
43122
43204
43212
43231
43248
00.00
43118
43248
45106
45203
43551
43552
43301
43302
43304
43305
43435
10.10
1.40
25.60
5.00
.20
1.40
46.50
7.30
1.00
.20
00.00 00
20.00
21.40
8.60
5.60
4.50
16.40
23.50
128.26 ISOMERS OF NCMANE
98.19 C-7 CYCLOPARAFFINS
112.23 C-8 CYCCOPAR/kFFlKS
126.26 C-9 CYCLOPARAFFINS
S6.18 N-HEXANE
100.21 N- HEPTANE
114.23 N -OCTANE
128.26 N-NOMANE
106.17 ISOMERS OF XYLENE
92.15 TOLUENE
.00 330001
58.08 ACETONE
72.10 METHYL ETHYL KETONE
100.16 METHYL ISOBUTYL KETONE
32.04 METHYL ALCOHOL
46.07 ETHYL ALCOHOL
60.09 ISOPROPYL ALCOHOL
74.12 N-BUTYL ALCOHOL
00.00 00.00 301015
38.70
41.60
16.70
3.00
00.00 00.
100.00
00.00 00.
100.00
22.60
10.80
33.90
21.40
11.30
00.00 00.
25.50
5.00
3.50
3.00
5.50
5.00
5.00
2.50
38.00
3.00
4.00
58.08 ACETONE
72.10 METHYL ETHYL KETONE
100.16 METHYL ISOBUTYL KETONE
62.07 GLYCOL ETHER
.00 301018A
62.50 VINYL CHLORIDE
00 3010188
42.08 PROPYLENE
301019A
72.15 ISOMERS OF PENTANE
44.09 PROPANE
58.12 N- BUTANE
86.18 N-HEXANE
84.16 CYCLOHEXANE
00 301020
114.00 MINERAL SPIRITS
84.16 CYCLOHEXANE
134.21 ISOMERS OF DIETHYLBENZENE
106.17 ETHYLBENZENE
58.08 ACETONE
72.10 METHYL ETHYL KETONE
32.04 METHYL ALCOHOL
46.07 ETHYL ALCOHOL
60.09 ISOPROPYL ALCOHOL
74.12 N-BUTYL ALCOHOL
116.16 N-BUTYL ACETATE
00.00 935705
43105
43115
43116
43118
43122
43204
43212
43214
43220
43231
45102
45202
43819
45201
8.10
15.40
1.60
15.00
3.10
1.80
4.40
1.40
3.20
3.70
15.00
5.00
10.00
12.30
86.18 ISOMERS OF HEXANE
98.19 C-7 CYCLOPARAFFINS
112.23 C-8 CYCLOPARAFFINS
114.00 MINERAL SPIRITS
72.15 ISOMERS OF PENTANE
44.09 PROPANE
58.12 N-3UTANE
58.12 ISOBUTANE
72.15 N-PENTANE
86.18 N-HEXANE
106.17 ISOMERS OF XYLENE
92.15 TOLUENE
173.85 METHYLENE BROMIDE
78.12 BENZENE
33
43
53
63
73
83
93
103
113
123
2
13
23
33
43
53
63
73
2
13
23
33
43
2
13
2
13
2
13
23
33
43
53
2
13
23
33
43
53
63
73
83
93
103
113
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
E-31
-------
TABLE E-4 (continued)
960:K0078
961:K0078
962:IC0079
963:K0079
964:K0079
965:K0079
966:K0079
967.-IC0079
968:K0079
969-.K0079
970:K0079
971:K0079
972:1(0079
973:K0079
974:K0079
975:IC0079
976:K0079
977:K0079
978:lt0079
979: 1C 00 79
980:IC0079
981:IC0079
982.-K0079
983:K0079
9S4-.K0079
985:K0079
986:1(0079
987:K0079
988:K0079
989:K0085
990:K0085
991:IC0086
992:K0086
993:K0086
994:K0086
995:K0086
996:K0087
997:K0087
998:IC008a
999:IC0088
1000:K0089
1001:K0089
1002:K0090
1003:K0090
1004:IC0092
1005:K0092
1006:1(0092
1007:K0092
1008:«092
1009:K0092
1010:K0096
1011:K0096
101Z:»C0096
1013:K0096
1014:K0096
1015:K0096
1016:K0096
1017:K0096
1018:1:0096
1019:K0096
00.00
43815
95.00
43248
43120
43203
43205
43213
45102
45202
45220
43502
43503
43510
43206
43301
43302
43304
43305
43438
43601
43602
43704
43812
43860
45300
45401
43801
45201
00.00
43817
00.00
43107
43108
43109
43110
00.00
43814
00.00 00.
100.00
5.00 1.
1.80
8.90
21.60
9.00
4.10
1.30
4.10
3.40
1.70
.70
.80
1.00
5.40
1.40
2.50
.50
.80
4.60
1.40
3.00
7.20
.60
2.00
1.30
.90
10.00
00.00 00.
100.00
.00
99.
.70
84.
56.
28.
301125
.00
ETHYLENE OICHLOR1DE
301999
.16
.10
,05
42.08
56.10
106.17
92.15
104.
.16
30.03
44.05
72.12
26.04
32.04
46.07
60.09
74.
.12
100.11
44.05
58.08
55.06
64.52
62.50
94.11
230.00
50.
.49
78.12
.00
165.
00.00 00.00
.80
27.30
69.30
2.60
00.00 00,
100.00
114.
CYCLOHEXANE
ISOMERS OF BUTENE
ETHYLENE
PROPYLEME
BUTENE
ISOMERS OF XYLENE
TOLUENE
STYRENE
FORMALDEHYDE
ACETALDEHYOE
BUTYRALDEKYDE
ACETYLENE
METHYL ALCOHOL
ETHYL ALCOHOL
ISOPROPYL ALCOHOL
N-BUTYL ALCOHOL
ETHYL ACRYLATE
ETHYLENE OXIDE
PROPYLENE OXIDE
ACRYLONITRUE
ETHYL CHLORIDE
VINYL CHLORIDE
PHENOLS
XYLENE BASE ACIDS
METHYL CHLORIDE
BENZENE
401001C
.83
PERCHLOROETHYLENE
401001B
,23
128.26
142.29
156.32
.00
133.
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
401001A
.42
1,1,1,-TRICMLOROETHANE
401002E
43811
00.00
43820
00.00
45202
90.00
43204
43212
43203
43201
43202
00.00
43107
43108
43109
43110
45102
45202
43551
43552
43560
100.00
137.37
00.00 00.00
100.00
TR I CHLOROFLDOROMETHANE
401002A
133.42
00.00 00.00
100.00
10.00 00
3.10
23.40
2.00
66.50
5.00
00.00 00
.40
10.90
27.80
1.00
4.00
4.00
10.00
10.00
5.00
1,1,2-TRlCHLOROETHANE
4010020
92.15
.00
TOLUENE
402008A
44.09
58
28
.12
.05
16.04
30
.00
114
128
142
156
106
92
58
72
100
.07
PROPANE
N-BUTANE
ETHYLENE
METHANE
ETHANE
402009A
.23
.26
.29
.32
.17
.15
.08
.10
.16
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
ISOMERS OF XYLENE
TOLUENE
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
2
13
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
243
253
263
2
13
2
13
23
33
43
2
13
2
13
2
13
2
3
2
13
23
33
43
53
2
13
23
33
43
53
63
73
83
E-32
-------
TABLE E-4 (continued)
1020:1:0096
1021:1(0096
1022:K0096
1023:1(0096
1024:K0098
1025:K009B
1026:K0098
1027:K0098
1028:K009e
1029:K0098
1030:K0098
1031:K0098
1032:K0098
1033:K0098
1034:K0098
1035:K0098
1036:1(0098
1037:K0098
1038:K0098
1039:K0098
1040:K0098
1041:K0098
1042:IC0100
1043:K0100
1044:K0100
1045:K0100
1046:K0100
1047:10)100
1048:K0100
1049:1:0100
1050:K0100
1051:K0100
1052:K0121
1053:K0121
1054: KOI 21
1055:K0121
1056:K0121
1057:K0121
1058:K0121
1059:K0121
1060:K0121
1061:K0121
1062:K0121
1063:K0121
1064:K0121
106S:K0122
1066: IC0 122
1067:K0122
1068:K0122
1069:IC0122
1070:K0122
1071:K0125
1072:K0125
1073:K0125
1074:K0125
1075:K0125
1076:K0127
1077:K0127
1078:K0127
1079:1:0127
43301
43302
43304
43817
43204
43212
43214
43220
43231
43232
43233
43235
43238
43213
43224
45102
45104
45105
45107
45202
45201
43232
43233
43235
43238
43241
43255
43258
43259
43260
85.00
43204
43212
43214
43220
43231
43232
43233
43121
43203
43213
43224
43206
85.00
43203
43205
43201
43202
45201
00.00
45102
45202
43551
43552
00.00
43551
43552
43560
5.60
5.60
5.70
10.00
.10
2.20
.50
12.20
16.30
9.30
10.10
1.80
2.60
.40
2.50
13.50
6.50
4.40
5.50
9.70
2.40
00
.10
.50
4.70
19.60
20.30
18.20
17.70
11.70
7.20
15.00
1.90
1.90
1.90
1.90
13.90
13.90
13.80
11.80
19.40
5.90
11.80
1.90
15.00
8.70
.50
80.40
2.70
7.70
32.04 METHYL ALCOHOL
46.07 ETHYL ALCOHOL
60.09 ISOPROPn ALCOHOL
165.83 PERCHLOROETHYLENE
403001A
44.09 PROPANE
58.12 N- BUTANE
58.12 IS06UIANE
72.15 N-PENTANE
86.18 N-HEXANE
100.21 N-HEPTANE
114.23 N-OCTANE
12S.26 N-MONANE
142.29 N-DECANE
56.10 BUTENE
70.14 1-PENTENE
106.17 1SOMERS OF XYLENE
120.19 ISOMERS OF ETHYLTOLUENE
134.22 ISOMERS OF BUTYLBENZENE
120.19 ISOMERS OF TR1METHYLBENZENE
92.15 TOLUENE
78.12 BENZENE
.00 403001E
100.21 N-HEPTANE
114.23 N-OCTANE
128.26 N-NONANE
142.29 N-DECANE
156.32 N-UNOECANE
170.34 N-DODECANE
184.37 N-TRIDECANE
198.40 N-TETRADECANE
212.42 N-PENTADECANE
501002
44.09 PROPANE
58.12 K- BUTANE
58.12 1SOBUTANE
72.15 N-PENTANE
86.18 N-HEXANE
100.21 N-HEPTANE
114.23 N-OCTANE
70.14 ISOMERS OF PENTENE
28.05 ETHYLENE
56.10 BUTENE
70.14 1-PENTENE
26.04 ACETYLENE
501005
28.05 ETHYLENE
42.08 PROPYLENE
16.04 METHANE
30.07 ETHANE
78.12 BENZENE
00.00 00.00 402001A
22.30
55.10
12.20
10.40
00.00 00
38.70
41.60
16.70
106.17 ISOMERS OF XYLENE
92.15 TOLUENE
58.08 ACETONE
72.10 METHYL ETHYL KETONE
.00 402003A
58.08 ACETONE
72.10 METHYL ETHYL KETONE
100.16 METHYL ISOBUTYL KETONE
103
113
123
133
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
2
13
23
33
43
53
63
73
83
93
2
13
23
33
43
53
63
73
83
93
103
113
123
2
13
23
33
43
53
2
13
23
33
43
2
13
23
33
E-33
-------
TABLE E-4 (continued)
1080:K0127
1081:K0134
1082:K0134
1083:K0134
1084:K01S4
1085:K0134
1086:K0134
1087:tt)134
1088:K01S4
t089:K0134
1090:K0134
1091.-K0134
1092:K0134
1093:K01S4
1094:K0134
1095:K01S4
1096:K0134
1097:K0141
1098:K0141
1099-.KOU1
1100:KOU1
1101:KOU1
1102:K0145
1103:K0145
1104:K0147
1105:ICOH7
1106:KOH7
1107:KOH7
1108.-IC0147
1109:K0147
1110:K0147
1111:ICOH7
1112:K0147
1113:K0147
1114:K0148
1115:K0148
1116:PCOK8
1117:K0148
1118:K0148
1119:K0148
1120:K0148
1121:K0148
1122:1(0148
1123:K0149
1124:K0149
1125.-KOK9
1126:IC0149
1127.-K0149
1128:lt0149
1129:K0156
1130:K0156
1131:K0156
1132:K0156
1133:K0156
1134:K0156
1135:K0156
1136:K0156
1137:K0156
1138:K0156
1139:K0156
43367
3.00
62.07
CLTC01. ETHER
40200&A
43118
45101
45102
45202
43551
43552
43560
43301
43302
43304
43305
43367
43433
43435
43444
90.00
45102
45202
43551
43552
41.00
1.00
4.90
3.90
7.10
7.70
3.10
1.00
.80
2.80
4.00
11.50
.90
9.50
.80
10.00 00.
22.00
54.00
13.00
11.00
114.00
114.00
106.17
92.15
58.08
72.
10
100.16
32.
04
46.07
60.09
74.
12
62.07
88.
10
116.16
104.
,00
106.
92.
58.
00
MINERAL 'SPIRITS
NAPHTHA
ISOMERS OF XYLENE
TOLUENE
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETOME
METHYL ALCOHOL
ETHYL ALCOHOL
ISOPROPYL ALCOHOL
k-BUTYL ALCOHOL
GLYCOL ETHER
ETHYL ACETATE
N-BUTYL ACETATE
ISOPROPYL ACETATE
402007A
17
15
08
72.10
ISOMERS OF XYLENE
TOLUENE
ACETONE
METHYL ETHYL KETONE
402007D
43817
00.00
43118
43Z33
43248
45202
43552
43304
43305
43308
43435
00.00
43118
45102
45202
43561
43551
43552
43304
43445
00.00
43118
45202
43552
43311
43433
00.00
43118
45102
45202
43551
43552
43560
43301
43302
43304
43305
100.00
00.00 00.
6.40
4.60
6.40
13.90
16.60
11.70
4.00
5.60
30.80
00.00 00.
25.00
7.00
10.00
8.00
13.00
18.00
15.00
4.00
00.00 00
21.40
9.40
14.20
26.60
28.40
00.00 00
67.60
4.00
3.20
6.30
6.80
2.70
.70
.50
1.90
2.80
165.
,00
114.
114.
83
PERCHLOROETHYLENE
402004C
00
23
84.16
92.15
72.10
60.09
74.12
102.00
116.16
.00
MINERAL SPIRITS
N -OCTANE
CYCLOHEXANE
TOLUENE
METHYL ETHYL KETONE
ISOPROPYL ALCOHOL
N-BUTYL ALCOHOL
BUTYL CELLOSOLVE
N-BUTYL ACETATE
402004B
114.00
106.17
92.15
98.15
58.08
72.10
60.09
140.00
.00
MINERAL SPIRITS
ISOMERS OF XYLENE
TOLUENE
CYCLOHEXANONE
ACETONE
METHYL ETHYL KETONE
ISOPROPYL ALCOHOL
METHYL AMYL ACETATE
402004A
114.00
92.15
72.10
90
.12
88.10
.00
114
106
92
58
72
MINERAL SPIRITS
TOLUENE
METHYL ETHYL KETONE
CELLOSOLVE
ETHYL ACETATE
402005A
.00
.17
.15
.08
.10
100.16
32
46
.04
.07
60.09
74
.12
MINERAL SPIRITS
ISOMERS OF XYLENE
TOLUENE
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
METHYL ALCOHOL
ETHYL ALCOHOL
ISOPROPYL ALCOHOL
N-BUTYL ALCOHOL
43
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
2
13
23
33
43
2
13
2
13
23
33
43
53
63
73
83
93
2
13
23
33
43
53
63
73
83
2
13
23
33
43
53
2
13
23
33
43
53
63
73
83
93
103
E-34
-------
TABLE E-4 (continued)
1140
11*1
1U2
1U3
11*4
1145
11*6
1147
1148
11*9
1150
1151
1152
1153
115*
1155
1156
1157
1158
1159
1160
1161
1162
1163
1164
1165
1166
1167
1168
1169
1170
1171
: KOI 56
: IC0 156
:K0156
:K0157
:K0157
:K0157
:K0157
:K0157
:K0157
:IC0157
:K0157
:K0157
:K0162
:K0162
•.K0162
:K0162
:K0162
:K0162
:K0162
:K0162
:«162
:K0162
:K0162
:K0162
:K0162
: IC0 162
:K0162
:K0162
:K0162
:K016*
:KQ16*
:K016*
1172:K016*
1173
1174
1175
1176
1177
1178
: IC0 166
:K0166
:K0166
:K0166
:K0166
:K0172
1179:tt>172
1180
1181
1182
1183
118*
:K0172
:K0172
:K0172
:K0172
:tt)172
1185:K0181
1186
1187
1186
1189
1190
1191
1192
1193
1194
1195
1196
1197
1198
1199
:K0181
:K0181
•.K0161
:K0181
:KQ181
:K0181
:K0181
:K0181
:K0181
: KOI 81
:K0181
:K0181
:K0181
:K0181
43433
43435
43444
00.00
43118
43233
43248
43435
43452
43552
43823
45202
95.00
43118
43204
43212
43220
43205
43213
4322*
43502
43551
43206
43304
43432
43435
434*4
43201
45202
2
.30
.90
.30
00.00 00.
13
5
11
12
5
24
' 13
12
.20
.30
.20
.40
.00
.70
.90
.30
05.00 3.
25
2
2
3
7
3
29
12
9
2
.80
.30
.10
.60
.40
.90
.40
.30
.60
.30
.00
.10
.60
.50
.00
.10
88
116
104
.00
11*
11*
8*
116
132
72
120
92
.30
11*
44
58
72
42
56
70
30
58
26
60
7*
116
104
16
92
.10
.16
.00
ETHYL ACETATE
N-BUTYL ACETATE
ISOPROPYL ACETATE
4020005C
.00
.23
.16
.16
.00
.10
.91
.15
MINERAL SPIRITS
N-OCTANE
CYCLOHEXANE
N-BUTYL ACETATE
2-ETNOXYETNYL ACETATE
METHYL ETHYL KETONE
D 1 CHLOROO I FlUOROMETHANE
TOLUENE
402008E
.00
.09
.12
.15
.08
.10
.1*
.03
.08
.0*
.09
.08
.16
.00
.0*
.15
MINERAL SPIRITS
PROPANE
N- BUTANE
N-PENTANE
PROPYLENE
BUTENE
1-PENTENE
FORMALDEHYDE
ACETONE
ACETYLENE
ISOPROPYL ALCOHOL
METHYL ACETATE
N-BUTYL ACETATE
ISOPROPYl ACETATE
METHANE
TOLUENE
4020050
43433
43*35
43444
7
8*
7
.90
.50
.60
88
116
10*
.10
.16
.00
ETHYL ACETATE
N-BUTYL ACETATE
ISOPROPYL ACETATE
405002
43201
43202
43204
43212
00.00
43302
43303
4330*
43351
43*33
43*52
00.00
43118
43231
43232
45202
43551
43552
43119
43302
43303
4330*
43433
43*34
43***
43452
63
2*
12
1
.00
.00
.00
.00
00.00 00
*7
2*
10
15
1
.60
.30
.70
.90
.10
.40
00.00 00
5
6
6
12
.40
.20
.60
.00
16
30
**
56
.00
46
60
60
74
88
132
.00
11*
86
100
92
.0*
.07
.09
.12
METHANE
ETHANE
PROPANE
N-BUTANE
405003A
.07
.09
.09
.12
.10
.00
ETHYL ALCOHOL
N-PROPVL ALCOHOL
ISOPROPYL ALCOHOL
ETHYL ETHER
ETHYL ACETATE
2-ETHOXYETHYL ACETATE
405005A
.00
.18
.21
.15
.60 58. 06
7
1
8
10
18
1
20
.80
.00
.60
.30
.80
.20
.30
.10
.90
72
114
46
60
60
88
102
10*
132
.10
.00
.07
.09
.09
.10
.13
.00
.00
MINERAL SPIRITS
N-HEXANE
N-HEPTANE
TOLUENE
ACETONE
METHYL ETHYL KETONE
LACTOL SPIRITS
ETHYL ALCOHOL
N-PROPYL ALCOHOL
ISOPROPYL ALCOHOL
ETHYL ACETATE
PROPYL ACETATE
ISOPROPYL ACETATE
2-ETHOXYETHYL ACETATE
113
123
133
2
13
23
33
43
53
63
73
83
2
13
23
33
43
53
63
73
93
103
113
123
133
1*3
153
163
83
2
13
23
33
2
13
23
33
*3
2
13
23
33
43
53
63
2
13
23
33
43
53
63
73
83
93
103
113
123
133
1*3
E-35
-------
TABLE E-4 (continued)
1200:K0182
1301:1(0182
1202:K0182
1203:K0182
1204:K01B2
1205: KOI 82
1206:K0182
1207: IC0 182
1208:K0182
1209:K0183
1210:1(0183
1211:(C0183
1212:K0183
1213:K0185
1214:K0185
1215:K0188
1216:K0188
1217:K0188
1218:1(0188
1219:1(0188
1220:K0188
1221:K01B8
1222:1(0188
1223:K0188
1224:K01B8
122S:K0188
1226: IC0 188
1227:K0188
1228:K0188
1229:K0195
1230:K0195
1231:K0196
1232:K0196
1233:lt0196
1234:K0196
1235:K0196
1234:1:0196
1237:K0196
1238:1(0196
1239:K0196
1240:1:0196
1241:1(0196
1242:K0196
1243:K0196
1244:K0196
1245:K0196
1246: KOI 96
1247:K0196
1248:K0196
1249-.K0196
1250:K0196
1251:K0196
1252:K0197
1253:K0197
1254:1:0197
1255:K0197
1256 .-C0 197
1257:K0197
1258.-K0197
1259:l£0197
00.00
43118
43248
45106
45203
43301
43304
43305
43435
00.00
43118
45102
45202
00.00
45202
43105
43112
43115
43116
43122
43204
43212
43214
43220
43231
43201
43202
45201
43201
43231
43248
45102
45202
45203
43551
43552
43559
43560
43301
43302
43304
43305
43306
43369
43370
43435
43446
43451
43452
43214
45101
43502
43551
43302
43304
43367
00.00 00
51.00
10.00
7.00
6.00
6.00
6.00
6.00
8.00
00.00 00
83.00
4.00
13.00
.00 405005D
114.00 MINERAL SPIRITS
84.16 CYCLOHEXANE
134.21 ISOMERS OF DIETHYIBEM7.ENE
106.17 ETHYLBENZENE
32.04 METHYL ALCOHOL
60.09 ISOPROPYL ALCOHOL
74.12 k-BUTYL ALCOHOL
116.16 N-BUTYL ACETATE
.00 405005B
114.00 MINERAL SPIRITS
106.17 ISOHERS OF XYLENE
92.15 TOLUENE
00.00 00.00 403001P
100.00
1.30
.30
4.50
1.30
7.10
21.30
16.60
8.30
5.80
4.20
16.80
11.90
.60
100.00
20.80
20.80
2.60
5.30
4.30
3.20
5.70
0.70
0.60
3.90
0.60
16.50
1.60
0.60
0.80
0.60
2.50
1.50
6.10
1.30
0,
5.30
4.50
0.60
1.40
36.90
38.50
8.30
92.15 TOLUENE
40300 1Q
86.18 I SIXERS OF NEXANE
170.33 1SOMERS OF DODECAME
98.19 C-7 CYCLOPARAFFINS
112.23 C-8 CYCLOPARAFFINS
72.15 1SOMERS Of PENTANE
44.09 PROPANE
58.12 N- BUTANE
58.12 ISOBUTANE
72.15 N-PENTANE
86.18 N-HEXANE
16.04 METHANE
30.07 ETHANE
78.12 BENZENE
901005
16.04 METHANE
935103
86.18 N-HEXANE
84.16 CYCLOHEXANE
106.17 ISOMERS OF XYLENE
92.15 TOLUENE
106.17 ETHYLBENZENE
58.03 ACETONE
72.10 METHYL ETHYL KETONE
100.16 METHYL N-BUTYL KETONE
100.16 METHYL ISOBUTYL KETONE
32.04 METHYL ALCOHOL
46.07 ETHYL ALCOHOL
60.09 ISOPROPYL ALCOHOL
74.12 N-BUTYL ALCOHOL
74.12 IS08UTYL ALCOHOL
76.00 PROPYLENE CLYCOL
62.07 ETHYLENE GLYCOL
116.16 N-BUTYL ACETATE
116.16 ISOBUTYL ACETATE
144.21 IS06UTYL ISOBUTYRATE
132.00 2-ETHOXYETHYL ACETATE
.60 935702
58.12 ISOBUTANE
114.00 NAPHTHA
30.03 FORMALDEHYDE
58.08 ACETONE
46.07 ETHYL ALCOHOL
60.09 ISOPROPYL ALCOHOL
62.07 GLYCOL ETHER
2
13
23
33
43
53
63
73
83
2
13
23
33
2
13
2
13
23
33
43
53
63
73
83
93
103
113
123
133
2
13
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
203
i13
2
13
23
33
43
53
63
73
E-36
-------
TABLE E-4 (continued)
1260:K0197
1261:1(0197
1262-.K0202
1263:1(0202
1264:K0202
1265:1(0202
1266:1(0202
1267:1:0202
126B:K0202
1269:K0202
1270:K0202
1271:IC0202
1272:K0202
1273:IC0202
1274:1:0203
1275:K0203
1276:»:0203
1277:K0203
1278:K0203
1279:K0203
1280:K0203
1281:K0203
1282:K0203
1283:K0211
1284:K0211
1285:IC0217
1286:K0217
1287:1:0217
1288:K0217
1289:K0217
1290:lt0217
1291:K0217
1292:K0219
1293:K0219
1294:K0220
1295:K0220
1296:K0221
1297:K0221
1298:K0222
1299:K0222
1300:K0223
1301:K0223
1302:K0226
1303:K0226
1304:K0227
1305:K0227
1306:K0228
1307:K0228
1308:K0229
1309:K0229
1310:K0230
1311:K0230
1312:1:0231
1313:K0231
13H:K0232
1315:K0232
1316:1(0232
1317:K0232
1318:K0232
1319:K0271
43369
43435
43123
43201
43202
43204
43212
43214
43220
43242
43817
45102
45202
00.00
43201
43202
43302
43304
43434
43551
43720
43740
00.00
43302
43203
43205
43213
43201
43202
45201
00.00
43551
00.00
43433
00.00
43552
00.00
43452
45102
43302
43304
00.00
43444
00.00
43119
00.00
43231
00.00
43122
43204
43214
43205
43202
00.00
3.20
1.30
.10
98.60
.10
.10
.20
.10
.10
.10
.30
.10
.10
00.00 00
70.00
20.00
2.00
2.00
2.00
2.00
1.00
1.00
76.00 PROPYLENE GLYCOL
116.16 N-BUTYL ACETATE
949999A -
136.23 TERPENES
16.04 METHANE
30.07 ETHANE
44.09 PROPANE
58.12 N-BUTANE
58.12 ISOBUTANE
72.15 N-PENTANE
70.14 CYCLOPENTANE
165.83 PERCHLOROETHYLENE
106.17 ISOMERS OF XYLENE
92.15 TOLUENE
.00 9499998
16.04 METHANE
30.07 ETHANE
46.07 ETHYL ALCOHOL
60.09 ISOPROPTL ALCOHOL
102.13 PROPYL ACETATE
58.08 ACETONE
31.06 METHVLAHINE
59.11 TRIMETHTL AMINE
00.00 00.00 302229
100.00
2.80
5.50
6.40
40.90
1.40
43.00
00.00 00
100.00
00.00 00
100.00
00.00 00
100.00
00.00 00
100.00
100.00
100.00
100.00
00.00 00
100.00
00.00 00
100.00
00.00 00
100.00
46.07 ETHYL ALCOHOL
390007
28.05 ETHYLENE
42.08 PROPYLENE
56.10 BUTENE
16.04 METHANE
30.07 ETHANE
78.12 BENZENE
.00 402001B
58.08 ACETONE
.00 402001C
88.10 ETHYL ACETATE
.00 4020010
72.10 METHYL ETHYL KETONE
.00 402005E
132.00 2-ETHOXYETHEL ACETATE
402003E
106.17 ISOMERS OF XYLENE
402009F
46.07 ETHYL ALCOHOL
402009G
60.09 ISOPROPYL ALCOHOL
.00 40200913
104.00 ISOPROPTL ACETATE
.00 40200915
114.00 LACTOL SPIRITS
.00 403001IC
86.18 N-HEXANE
00.00 00.00 403001M
100.00
90.60
.20
5.10
4.10
00.00 00
72.15 ISOMERS OF PENTANE
403003
44.09 PROPANE
58.12 ISOBUTANE
42.08 PROPYLENE
30.07 ETHANE
.00 401002C
83
93
2
33
43
53
63
73
83
93
103
113
123
133
2
13
23
33
43
53
63
73
83
2
13
2
13
23
33
43
53
63
2
13
2
13
2
13
2
13
2
13
2
13
2
13
2
13
2
13
2
13
2
13
2
13
23
33
43
2
E-37
-------
TABLE E-4 (continued)
1320:1:0271
1321:1(0272
1322:K0272
1323:tt>272
1324:K0272
1325:K0272
1326.-IC0272
1327:K0272
1328:K0272
1329:K0272
1330:IC0272
1331:IC0272
1332.-K0272
1333.-IC0273
1334:K0273
1335:K0273
1336:K0273
1337:K0273
1338:tC0273
1339:K0273
1340:tt>273
1341:«>274
1 342:10)274
1343:r0274
1344:K0274
1345:tt>274
1346:K0275
1347:lt0275
134S:K0276
1349:K0276
1350:K0276
1351;K0276
1352:1:0276
1353:1:0276
1354:K0276
1355:K0276
1356:K0276
1357:K0277
1358:1:0277
1359:K0279
1360-.K0279
1361.-K0279
1362.-K0279
1363:C0279
1364:K0279
1365:K0279
1366:1:0280
1367:1:0280
1368:K0280
1369:K0280
1370:K0282
1371:IC0282
1372:C0283
1373:C0283
1374:1:0287
1375:K0287
1376:K0288
1377:K0288
1378:(C0289
1379:K0289
43824
95.00
43106
43107
43115
43116
43231
43232
43233
43248
43262
45202
45201
00.00
43105
43106
43231
43242
43248
43262
45201
00.00
43115
43116
43248
43262
00.00
43802
00.00
43204
43212
43214
43205
43551
43206
43201
43202
00.00
43821
90.00
43203
45202
43551
43201
43202
45201
00.00
45202
43551
45201
00.00
45101
00.00
43118
00.00
45201
43435
43305
100.00
5.00 00
4.70
.80
43.20
6.00
5.80
1.90
.40
16.30
17.70
.40
2.80
00.00 00,
24.20
.20
33.60
.20
.40
33.70
7.70
00.00 00.
99.84
.08
.04
.04
00.00 00.
100.00
131.40 TRICHLOROETHYLENE
.00 301026A
100.21 ISOMERS'OF HEPTANE
114.23 ISOMERS OF OCTANE
98.19 C-7 CYCLOPARAFFINS
112.23 C-8 CYCLOPARAFFINS
86.18 N-HEXANE
100.21 N-HEPTANE
114.23 N-OCTANE
84.16 CYCLONEXANE
84.16 HETHYLCYCLOPENTANE
92.15 TOLUENE
78.12 BENZENE
.00 3010268
86.18 ISOMERS OF HEXANE
100.21 ISOMERS OF HEPTANE
86.18 N-HEXANE
70.14 CYCLOPENTANE
84.16 CYCLOHEXANE
84.16 METHYLCYCLOPENTANE
78.12 BENZENE
.00 301026C
98.19 C-7 CYCLOPARAFFINS
112.23 C-8 CYCLOPARAFFINS
84.16 CYCLONEXANE
84.16 METHYLCYCLOPENTANE
.00 4010026
84.94 D1CHLOROMETHANE
00.00 00.00 301019B
.90
2.20
.40
3.10
8.60
4.40
80.00
.40
00.00 00.
100.00
10.00 00.
2.40
10.60
30.20
39.90
2.40
14.50
44.09 PROPANE
58.12 N- BUTANE
58.12 ISOBUTANE
42.08 PROPYLENE
58.08 ACETONE
26.04 ACETYLENE
16.04 METHANE
30.07 ETHANE
00 491992F
187.38 TRICHLOROTRIFLUOROETHANE
.00 4020088
28.05 ETHYLENE
92.15 TOLUENE
58.08 ACETONE
16.04 METHANE
30.07 ETHANE
78.12 BENZENE
00.00 00.00 402006E
8.70
68.90
22.40
00.00 00.
100.00
92.15 TOLUENE
58.08 ACETONE
78.12 BENZENE
.00 4020006G
114.00 NAPHTHA
00.00 00.00 402006H
100.00
00.00 00,
100.00
100.00
100.00
114.00 MINERAL SPIRITS
.00 402007E
78.12 BENZENE
4020098
116.16 N-BUTYL ACETATE
402009C
74.12 N-BUTYL ALCOHOL
13
2
13
23
33
43
53
63
73
83
93
103
113
2
13
23
33
43
53
63
73
2
13
23
33
43
2
13
2
13
23
33
43
53
63
73
83
2
13
2
13
23
33
43
53
63
2
13
23
33
2
13
2
13
2
13
2
13
2
13
E-38
-------
TABLE E-4 (continued)
1380:K0290 00.00
1381:1(0290 43311
1382:K0291 00.00
1383:1(0291 43301
1384:K0292 00.00
1385:K0292 43450
1386:K0293
1387:K0293 43231
1388:K>293 43248
1389:K0293 45102
1390:K0293 45202
1391:K0293 45203
1392:K0294 00.00
1393:tt)294 45102
1394:K0294 45104
1395:K0294 45107
1396:K0294 45108
1397:K0294 45202
1398:K0294 45203
1399:K0296 00.00
1400:K0296 43115
1401:K0296 43116
1402:K0296 43122
1403:IC029& 43204
1404:K0296 43212
1405:K0296 43214
1406:K0296 43220
1407:K0296 43231
K08:«296 43232
1409:K0296 43233
1410:K0296 43201
K11:K0296 43202
1412:K0296 45201
1413:K0297 00.00
1414:K0297 43105
1415:K0297 43106
1416:IC0297 43107
1417:K0297 43122
1418:IC0297 43204
1419:K0297 43212
1420:IC0297 43214
K21:K0297 43220
K22:K0297 43231
1423:K0297 43232
1424:K0297 45202
1425:K0297 43201
K26:K0297 43202
1427:K0297 45201
1428:K0298 00.00
1429:K0298 45201
1430.-K0301 00.00
1431:«301 43232
1432:1C0303 00.00
1433:K0303 43220
1434:1(0305
1435:lt0305 43204
1436:K0305 43212
1437:K0305 43220
1438:K0305 43231
1439:K0305 43232
00.00 00.00 40200906
100.00 90.12 CELLOSOLVE
00.00 00.00 402009K -
100.00 32.04 METHYL ALCOHOL
00.00 00.00 49200908
100.00 73.09 D1METHYLFORMAM10E
402999A
34.00 86.18 N-HEXANE
43.10 84.16 CYCLOHEXANE
6.60 106.17 I SOWERS OF XYLENE
7.60 92.15 TOLUENE'
8.70 106.17 ETHYL8ENZENE
00.00 00.00 4029998
41.60 106.17 ISOMERS OF XYLENE
12.20 120.19 ISOMERS OF ETHYLTOLUENE
20.10 120.19 ISOMERS OF TRIMETHYLBENZENE
2.10 120.19 ISOHERS OF FROPYLBENZENE
13.70 92.13 TOLUENE
10.30 106.17 ETHYLBENZENE
00.00 00.00 403001C
1.30 98.19 C-7 CYCLOPARAFFINS
.50 112.23 C-8 CYCLOPARAFFINS
1.50 72.15 ISOMERS OF PENTANE
17.60 44.09 PROPANE
27.10 58.12 N-BUTANE
1.50 58.12 ISOBUTANE
14.60 72.15 N-PENTANE
7.90 86.18 N-HEXANE
9.20 100.21 N-HEPTANE
6.90 114.23 N-OCTANE
6.20 16.04 METHANE
5.60 30.07 ETHANE
.10 78.12 BENZENE
00.00 00.00 403001D
5.10 86.18 ISOMERS OF HEXANE ,
5.00 100.21 ISOMERS OF HEPTANE
.40 114.23 ISOMERS OF OCTANE
11.20 72.15 ISOMERS OF PENTANE
16.10 44.09 PROPANE
20.80 58.12 N-BUTANE
9.30 58.12 ISOBUTANE
10.10 72.15 N-PENTANE
4.70 86.18 N-HEXANE
2.00 100.21 N-HEPTANE
1.40 92.15 TOLUENE
8.80 16.04 METHANE
2.70 30.07 ETHANE
2.40 78.12 BENZENE
00.00 00.00 403001 F
100.00 78.12 BENZENE
00.00 00.00 4030011
100.00 100.21 N-HEPTANE
00.00 00.00 40300115
100.00 72.15 N-PENTANE
406002
15.80 44.09 PROPANE
30.20 58.12 N-BUTANE
18.50 72.15 N-PENTANE
8.80 86.18 N-HEXANE
10.80 100.21 N-HEPTANE
2
13
2
13
2
13
2
13
23
33
43
53
2
13
23
33
43
53
63
2
13
23
33
43
53
63
73
83
93
103
113
123
133
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
2
13
2
13
2
13
2
13
23
33
43
53
E-39
-------
TABLE E-4 (continued)
1440:K0305
1441:IC0305
1442:K0305
1443:K0306
1444.-W306
1445:IC0306
1446:K0306
1447:K0306
1448:K0306
1449-.IC0307
1450:IC0307
H51:IC0307
H52:IC0307
1453:K0307
1454:IC0307
H55:K0307
K56:K0307
1457:IC0307
US8:K0307
1459:K0307
H60.-K0307
1461:K0307
1462:K0307
1463-.K0307
1464:K0307
1465.-K0316
1466:K0316
1467:K0316
1468:K0316
1469:K0316
1470.-K0316
1471:K0316
1472:IC0316
1473:1(0316
1474:1(0316
1475.-K0316
1476:K0316
1477:lt0316
1478:K0316
1479:K0316
1480:H)316
1481:K0316
1482:IC0316
1483:K0316
1484:K0316
1485.-K0316
1486:K0316
1487:K0316
1488:K0316
1489:IC0316
1490.-IC0321
1491:K0321
K92:K0321
K93:K0321
H94:lt0321
I495:U0321
1496.-K0321
1497:K0321
1498:K0321
1499:K0321
43233
43201
43202
00.00
4323)
43232
43822
45201
45202
85.00
43122
43204
43212
43214
43120
43203
43205
43213
43218
43223
43000
43206
43209
43201
43202
00.00
43105
43106
43107
43108
43109
43115
43117
43122
43204
43212
43214
43220
43231
43232
43233
43235
43238
43248
43205
45102
45202
43201
43202
45201
00.00
43105
43106
43107
43108
43109
43115
43116
43117
43122
9.60
2.60
3.70
00.00 00.
1.67
6.86
83.86
3.05
4.56
15.00 00.
0.15
0.35
0.24
0.11
0.92
19.11
3.93
0.81
0.52
0.17
44.59
8.40
0.41
9.82
10.47
00.00 00.
1.60
.80
.40
.50
.30
.20
.10
7.80
11.50
18.30
7.40
7.70
3.40
1.40
1.80
.60
.80
.10
.10
.20
.50
28.60
5.80
.10
00.00 00
5.50
4.10
2.80
3.10
1.90
1.10
.10
.80
6.60
114.23
16.04
30.07
N-OCTANE
METHANE
ETHANE -
00 303009A
86.18
100.21
93.19
78.12
92.15
N-HEXANE
N-HEPTANE
TR1METHUFIUOR1S1LANE
BENZENE
TOLUENE
00 913081
72.15
44.09
58.12
58.12
56.10
28.05
42.08
56.10
54.09
70.14
86.00
26.04
40.06
16.04
30.07
1SOMERS OF PENTANE
PROPANE
N- BUTANE
IS06UTANE
ISOMERS OF BUTENE
ETHYLENE
PROmENE
BUTENE
1,3-BUTAOIENE
3-METHYL-1-BUTENE
UNIDENTIFIED HYDROCARBONS
ACETYLENE
METHYLACETYLENE
METHANE
ETHANE
00 306008A
86.18
100.21
114.23
128.26
142.29
98.19
126.26
72.15
44.09
58.12
58.12
72.15
86.18
100.21
114.23
128.26
142.29
84.16
42.08
106.17
92.15
16.04
30.07
78.12
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
C-7 CYCLOPARAFF1NS
C-9 CYCLOPARAFFINS
ISOMERS OF PENTANE
PROPANE
N-BUTANE
ISOBUTANE
N-PENTANE
N-HEXANE
N-HEPTANE
N-OCTANE
N- NONANE
N -DECANE
CYCLOHEXANE
PROPYLENE
ISOMERS OF XYLENE
TOLUENE
METHANE
ETHANE
BENZENE
.00 306008P
86.18
100.21
114.23
128.26
142.29
98.19
112.23
126.26
72.15
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
ISOMERS OF PENTANE
63
73
83
2
13
23
33
43
53
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
243
2
13
23
33
43
53
63
73
83
93
E-AO
-------
TABLE E-4 (continued)
1500:1:0321
1501:K0321
1502:K0321
1503:K0321
1504:K0321
1SOS:K0321
1S06:K0321
1507:K0321
1508:K0321
1509:IC0321
1S10:K0321
1511:1(0321
1512:K0321
1513:K0321
15U:K0321
1515:K0330
1516:K0330
1517:K0330
1518:K0330
1519:K0330
1520:K0330
1S21:K0330
1522:10)330
1523:K0330
1524:K0330
1525:K0330
1526:IC0330
1527:IC0330
152B:K0330
1S29:K0330
1530:1:0330
1531:K0330
1S32:K0330
1533:K0330
1534:K0333
1535:K0333
1536:K0333
1537:K0333
1538:K0333
1539:K0333
1540:K0333
1541:K0333
1542:1(0334
1543:K0334
1544:K0334
1545:1:0334
1546:1:0334
1547:K0334
1548:1:0334
1549:1:0334
1550:K0334
1551:R0001
1552:R0001
1553:R0001
1554:R0001
1555:R0001
1556:R0001
1557:R0001
1558:R0001
1559:R0001
43204
43212
43214
43220
43231
43232
43233
43235
43238
43248
45102
45202
43201
43202
45201
90.00
43212
43220
43231
43232
43233
43235
43260
43203
43205
45101
45102
45107
45202
43502
43206
43201
43202
45201
00.00
43204
43212
43214
43304
43802
43201
43202
43204
43212
43214
43203
43205
43213
43201
43202
97.00
43202
43204
43213
43212
43221
43227
43245
43231
3.
8.
11.
11.
8.
12.
3.
5.
1.
3.
3.
1.
70
10
80
10
00
50
00
90
10
50
30
00
30
20
50
10.00 12.
3.
1.
1.
0.
0.
0.
35.
10.
4.
17.
0.
0.
1.
12.
3.
4.
0.
1.
20
80
40
40
40
40
10
70
00
60
30
20
80
20
80
40
40
90
00.00 00,
3.30
11.50
1.80
.90
34.90
37.70
10.00
00
3.00
3.00
1.00
13.00
3.00
1.00
69.00
7.00
44.
58.
58.
72.
09
12
12
15
86.18
100.
114.
128.
142.
84.
106.
92.
16.
30.
78.
20
58.
72.
S6.
100.
114.
128.
212.
28.
42.
114.
106.
120.
92.
30.
26.
16.
30.
78.
.00
44.
58.
58.
21
23
26
29
16
17
15
04
07
12
PROPANE
N-BUTANE
ISOBUTARE
N-PENTANE
N-HEXANE
N-HEPTANE
K- OCTANE
N-NONANE
N-DECANE
CYCLOHEXANE
1SOHERS OF XYLENE
TOLUENE
METHANE
ETHANE
BENZENE
907021
12
15
18
21
23
26
42
05
08
00
17
19
15
03
04
04
07
12
N- BUTANE
N-PENTANE
N-HEXANE
N- HEPTANE
N-OCTANE
N-NONANE
N-PENTADECANE
ETHYLENE
PROPYLENE
NAPHTHA
I SOWERS OF XYLENE
1SOMERS OF TR1METHYLBENZENE
TOLUENE
FORMALDEHYDE
ACETYLENE
METHANE
ETHANE
BENZENE
405004A
09
12
12
60.09
84.94
16.04
30.07
.00
PROPANE
N-BUTANE
ISOBUTANE
ISOPROPYL ALCOHOL
DICHLOROMETHANE
METHANE
ETHANE
40500 2A
44.09
58.12
58.12
28.05
42.08
56.10
16.04
30.07
3.00
2.09
1.78
.79
.98
1.22
1.05
3.63
9.45
PROPANE
N-BUTANE
ISOBUTANE
ETHYLENE
PROPYLENE
BUTENE
METHANE
ETHANE
R0001 IP WOOD RIVER NO. 4
30.07
44.09
56.10
58.12
72.15
70.14
84.16
86.18
ETHANE
PROPANE
1 -BUTENE
N-BUTANE
ISOPENTANE
CIS.2-PENTENE
1-HEXENE
N-HEXANE
103
123
133
143
153
163
173
183
193
203
213
223
233
243
253
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
2
13
23
33
43
53
63
73
2
13
23
33
43
53
63
73
83
2
13
23
33
43
53
63
73
83
E-41
-------
TABLE E-4 (continued)
1560:R0001
1561:R0001
1562:R0001
1S63:R0001
1564:R0001
1565:R0001
1566:R0001
1$67:R0001
1568:80003
1569:R0003
1570.-R0003
1571:R0003
1572:R0003
1573:R0003
1574:
X0001
1575:X0001
1576:
1577:
1578:
1579:
1580:
1581:
1582:
1583:
1584:
1585:
1586:
1587:
1588:
1589:
1590:
1591:
1592:
1593:
1594:
1595:
1596:
1597:
1598:
1599:
1600:
1601:
1602:
1603:
1604:
1605:
1606:
1607:
1608:
1609:
1610:
1611:
1612:
1613:
1614:
1615:
1616:
1617:
1618:
1619:
X0001
X0001
X0001
X0001
X0002
X0002
X0002
X0002
X0002
X0002
X0002
XQ002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0002
X0003
X0003
X0003
X0003
X0003
X0003
X0003
X0003
X0003
X0003
X0003
X0003
X0003
X0003
X0003
43268
43247
43264
43232
45202
45203
45205
45204
96.00
43800
45201
43200
43200
45100
2.67
6.39
3.69
1.50
5.62
11.25
39.23
8.66
4.00
77.00
6.00
1.00
13.00
3.00
98.
19
100.21
98.
100.
92.
106.
106.
106.
19
21
15
17
17
17
3,3 DIMETHYL, 1-PENTENE
2,4 DIMETHYLPENTANE
1-HEPTEHE
N- HEPTANE
TOLUENE
ETHYL BENZENE
1,3 01METHYLBENZENE
ORTHOXYLENE
TABLE A-3
35.
78.
35.
35.
95.
00
12
00
00
64
C1-C3 PARAFFINS, NON-REACTIVES
BENZENE
C4» PARAFFINS, OLEFINS
C4+ PARAFFINS, OLEFINS
PRIM. AND SEC-ALKYL BENZENES
X0001 70X STODDARD/30X PERCHLOROETHYLENE
43107
43108
43109
43110
43817
90.00
43212
43122
43105
43106
43107
43108
43109
43203
43205
43120
43121
43245
43561
45102
45105
45107
45202
45203
43502
43206
43201
43202
45201
43265
00.00
43118
43119
43201
43202
43203
43204
43205
43212
43213
43214
43231
43232
43302
43303
.20
8.20
20.80
.80
70.00
10.00 03,
5.99
16.55
6.19
5.50
7.76
.98
0.39
6.87
4.84
4.15
3.95
1.26
0.76
2.64
0.06
2.15
10.61
0.56
3.67
5.16
6.45
0.80
2.69
0.05
00.00 00.
2.2
.41
23.02
4.06
2.34
1.46
.54
3.74
.18
.68
2.54
2.7
9.73
3.28
114.
128.
142.
156.
165.
.92
58.
72.
86.
100.
114.
128.
142.
28.
42.
56.
70.
84.
98.
106.
134.
120.
92.
106.
30.
26.
23
26
29
32
83
12
15
18
21
23
26
29
05
08
10
14
16
15
17
22
19
15
17
03
04
16.04
30.
78.
112.
.00
1H.
114.
16.
30.
28.
44.
42.
58.
56.
58.
86.
100.
46.
60.
07
12
14
1SOMERS OF OCTANE
ISOMERS OF NONANE
ISOHERS OF DECANE
ISOMERS OF UNDECANE
PERCHLOROETHYLENE
X0002 COM HGHWY VEH. PROFILE
N- BUTANE
ISOMERS OF PENTANE
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ETHYLENE
PROPYIEHE
ISOMERS OF BUTENE
ISOMERS OF PENTENE
1-HEXENE
CYCLOHEXANONE
ISOMERS OF XYLENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF TRIMETHYLBENZENE
TOLUENE
ETHYLBENZENE
FORMALDEHYDE
ACETYLENE
METHANE
ETHANE
BENZENE
1-OCTENE
K0334(18X>,K0172<13X>,D0333(28X),IC0181(41X>
00
00
04
07
05
09
08
12
10
12
18
21
07
09
MINERAL SPIRITS
LACTOL SPIRITS
METHANE
ETHANE
ETHYLENE
PROPANE
PROPYLENE
N- BUTANE
BUTENE
ISOBUTANE
N-HEXANE
N-HEPTANE
ETHYL ALCOHOL
N-PROPYL ALCOHOL
93
103
113
123
133
143
153
163
2
13
23
33
43
53
2
13
23
33
43
53
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
243
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
E-42
-------
TABLE E-4 (continued)
1620:X0003
1621.-X0003
1622:X0003
1623:X0003
1624:X0003
1625:X0003
1626:X0003
1627:X0003
162fl:X0003
1629:X0003
1630:X0004
1631:X0004
1632:X0004
1633:X0004
1634:X0004
1635:X0004
1636:X0004
1637:X0004
1638:X0004
1639:X0004
1640:X0004
1641:X0004
1642:X0004
1643-.X0004
1644-.X0004
1645:X0004
1646-.X0004
1647-.X0004
1648: X0004
1649-.X0004
1650:X0004
1651-.X0004
1652-.X0004
1653:X0004
1654:K0004
1655-.X0004
1656:X0004
1657:X0004
1658:X0004
1659:X0004
16&0:X0004
1661 :X0004
1662:X0005
1663:X0005
1664:X0006
1665:X0006
1666:X0006
1667:X0006
1668:X0006
1669:X0006
1670:X0006
1671:X0006
1672:X0006
1673:X0006
1674:X0006
167S:X0006
1676:X0006
1677:X0006
167B:X0006
1679:X0006
43304
43351
43433
43434
43444
43452
43551
43552
43802
45202
00.00
43105
43107
43108
43109
43115
43116
43117
43122
43204
43212
43213
43214
43220
43224
43228
43231
43232
43233
43235
43241
43248
43255
43258
43259
43260
45102
45104
45105
45107
45201
45202
00.00
43560
43105
43106
43107
43108
43115
43122
43204
43212
43213
43214
43220
43224
43231
43232
43233
6.07
.12
9.42
.53
8.24
.55
.33
3.20
9.80
4.9
60
74
88
102
104
132
58
72
84
92
00.00 00.00
2.20
1.87
6.87
5.53
.80
.20
1.60
.13
.23
.75
.13
.17
4.49
.83
7.40
7.50
3.73
5.67
4.94
6.77
.50
6.07
5.90
3.90
2.40
6.83
2.17
1.47
1.83
1.63
5.30
00.00 00.
100.00
8.90
2.19
2.24
.26
.24
27.56
1.71
18.94
t.73
6.31
10.28
6.02
2.56
.70
.16
86
114
128
142
96
112
126
72
44
58
56
58
72
70
70
86
100
114
128
156
84
170
184
198
212
106
120
.09
.12
.10
.13
.00
.00
.08
.10
.94
.15
ISOPROPYl ALCOHOL
ETHYL ETHER
ETHYL ACETATE
PROPYL ACETATE
ISOPROPYL ACETATE
2-ETHOXYETHYL ACETATE
ACETONE
METHYL ETHYL KETONE
OICHLOROMETHANE
TOLUENE
X0004 DOJ01«33X,K0098'33X,K0315«33X
.18
.23
.26
.29
.19
.23
.26
.15
.09
.12
.10
.12
.15
.14
.14
.18
.21
.23
.26
.32
.16
.34
.36
.40
.42
.17
.19
134.22
120
78
92
,00
100
86
100
114
128
98
72
44
58
56
58
72
.19
.12
.15
ISOMERS OF HEXANE
1SOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFflNS
C-9 CYCLOPARAFflNS
ISOMERS OF PENTANE
PROPANE
N- BUTANE
BUTENE
ISOBUTANE
N-PENTANE
1-PENTENE
2-METHYL-2-8UTENE
N- HEXANE
N-HEPTANE
N-OCTANE
N- NONANE
N-UNDECANE
CTCLOHEXANE
N-DCOECAME
N-TRIDECANE
N-TETRAOECANE
N-PENTAOECANE
ISOMERS OF XYLENE
ISOMERS OF ETHTLTOLUENE
ISOMERS OF BUTTLBENZENE
ISOMERS OF TRIMETHYL8ENZENE
BENZENE
TOLUENE
X0005 METHYL ISOBUTYL KETONE
.16
.18
.21
.23
.26
.19
.15
.09
.12
.10
.12
.15
70.14
86
100
114
.18
.21
.23
METHYL ISOBUTYL KETONE
X0006
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
C-7CYCLOPARAFF1NS
ISOMERS OF PENTANE
PROPANE
N -BUTANE
BUTENE
ISOBUTANE
N-PENTANE
1-PENTENE
N- HEXANE
N-HEPTANE
N-OCTANE
153
163
173
183
193
203
213
223
233
243
Z
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
243
253
263
273
283
293
303
313
2
13
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
E-43
-------
TABLE E-4 (continued)
1680:X0006
1681:X0006
1682:X0006
1683:X0006
1684:X0006
1685:1(0006
1686.-X0006
1687:X0006
1688:X0006
1589:X0006
1690:X0006
1691:X0007
1692:X0007
1693.-X0007
1694:X0007
1695:X0007
1696-.X0007
1697:X0007
1698:X0007
1699:X0007
1700.-X0007
1701:X0007
1702:X0007
1703:X0007
1704:X0007
1705:X0007
1706:X0007
1707:X0007
1708:X0007
1709:X0007
1710:X0007
1711-.X0007
1712:X0007
1713:X0007
1714:X0007
1715:X0007
1716:X0007
1717:X0007
1718:X0007
1719:X0007
1720:X0007
1721.-X0007
1722:X0007
1723:X0007
1724:X0007
1725:X0007
1726:X0007
1727:X0007
172B:X0007
1729:X0007
1730:X0007
1731:X0007
1732:X0007
1733:X0007
1734:X0007
1735:X0007
1736:X0007
1737:X0007
1738:X0007
1739:X0007
43235
43238
43248
45102
45103
45104
45105
45107
45108
45201
45202
00.00
43105
43107
43108
43109
43110
43115
43116
43117
43118
43119
43122
43201
43202
43203
43204
43205
43212
43213
43214
43220
43224
43228
43231
432S2
43233
43235
43241
43248
43255
432S8
43259
43260
43301
43302
43303
43304
43305
43306
43367
43369
43370
43433
43434
43435
43444
43446
43451
43452
.03
.12
2.20
2.18
.23
.80
.08
.54
.02
1.17
2.47
00.00 00.
.40
.35
7.22
17.54
.63
.52
.06
.11
.53
.01
.10
.76
.13
.08
.12
.02
.30
.02
1.41
.41
.04
.51
4.51
.35
.39
.34
.47
3.84
.42
.41
.27
.17
2.11
11.07
.11
14.29
.29
.11
2.08
.95
.11
.31
.02
.79
.27
.28
1.12
.26
128.26
142.29
84.16
106.17
134.22
120.19
134.22
120.19
120.19
78.12
92.15
,15
86.18
114.23
128.26
142.29
156.32
98.19
112.23
126.26
114.00
114.00
72.15
16.04
30.07
28.05
44.09
42.08
58.12
56.10
58.12
72.15
70.14
70.14
86.18
100.21
114.23
128.26
156.32
84.16
170.34
164.36
198.40
212.42
32.04
46.07
60.09
60.09
74.12
74.12
62.07
76.00
62.07
88.10
102.13
116.16
104.00
116.16
144.21
132.00
N-HONANE
N-OECANE
CTCLOHEXANE
ISOMERS Of XYLENE
DIMETHYLETHYLBENZENE
ISOMERS OF ETHYLTOLUENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
BENZENE
TOLUENE
X0007
ISOMERS OF HEXANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF UNOECANE
C-7 CYCLOPARAFF1VS
C-8 CYCLOPARAFF1NS
C-9 CYCLOPARAFFINS
MINERAL SPIRITS
LACTOL SPIRITS
ISOMERS OF PENTANE
METHANE
ETHANE
ETHYLENE
PROPANE
PROPYLENE
N-BUTANE
BUTENE
ISOBUTANE
N-PENTANE
1 PENTENE
2-METHYL 2-BUTENE
N- HEXANE
N-HEPTANE
N -OCTANE
N-NONANE
N-UNOECANE
CYCLOHEXANE
N-OOOECANE
N-TRIDECANE
N-TETRADECANE
N-PENTADECANE
METHYL ALCOHOL
ETHYL ALCOHOL
N-PROPYL ALCOHOL
ISOPROPYL ALCOHOL
N-BUTYL ALCOHOL
ISOBUTYL ALCOHOL
GLYCOL ETHER
PROPYLENE GLYCOL
ETHYLENE GLYCOL
ETHYL ACETATE
PROFYL ACETATE
N-BUTYL ACETATE
ISOPROPYL ACETATE
1SOBUTYL ACETATE
ISOBUTYL ISOBUTYRATE
2-ETMJXYETHYL ACETATE
163
173
183
193
203
213
223
233
243
253
263
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
243
253
263
273
283
293
303
313
323
333
343
353
363
373
383
393
403
413
423
433
443
453
463
473
483
E-44
-------
TABLE E-4 (continued)
1740:X0007 43502
1741:X0007 43551
1742:X0007 43552
1743:X0007 43559
1744:X0007 43560
1745:X0007 43802
1746:X0007 43817
1747:X0007 43819
1748:X0007 45101
1749:X0007 45102
1750:X0007 45104
1751:X0007 45105
1752:X0007 45107
1753:X0007 45201
1754:X0007 45202
1755:X0007 45203
1756:X0008
1757:X0008 43105
1758:X0008 43106
1759:X0008 43107
1760:X0008 43115
1761:X0008 43116
1762.-X0008 43231
1763:X0008 43232
1764:X0008 43233
1765:X0008 43242
1766:X0008 43248
1767:X0008 43262
1768:X0008 45202
1769:X0008 45201
1770:X0009
1771:X0009 43118
1772:X0009 45102
1773:X0009 45202
1774:X0009 43561
1775.-X0009 43551
1776:X0009 43552
1777:X0009 43304
1778:X0009 43445
1779:X0009 43560
1780:X0009 43301
1781:X0009 43302
1782:X0009 43305
1783:X0009 43433
1784:X0009 43435
1785:X0009 43444
1786:X0009 43233
1787:X0009 43248
1788:X0010
1789:X0010 43118
1790:X0010 45102
1791:X0010 45202
1792:X0010 43561
1793:X0010 43551
1794:X0010 43552
1795:X0010 43304
1796:X0010 43445
1797:X0010 43220
1798:X0010 45101
1799:X0010 43205
.15
3.40
3.63
.13
1.35
.32
6.10
.30
1.13
2.40
.15
.10
.13
.48
2.63
.79
30.03 FORMALDEHYDE
58.08 ACETONE
72.10 METHYL ETHYL ICETONE
100.16 METHYL N-BUTYL KETONE
100.16 METHYL ISOBUTYL KETONE
84.94 D1CHLORO METHANE
165.83 PERCHLOROETHYLENE
173.85 METHYLENE BROMIDE
114.00 NAPHTHA
106.17 ISOMERS OF XYLENE
120.19 ISOMERS OF ETHYLTOLUENE
134.22 ISOMERS OF BUTYLBENZENE
120.19 ISOMERS OF TRIMETHYLBENZENE
78.12 BENZENE
92.15 TOLUENE
106.17 ETHYL8ENZENE
00.00 K0272(33X),K0273(33X),K0274(33X>
8.10
1.60
0.30
47.70
2.10
13.10
0.60
0.10
0.10
5.60
17.10
0.10
3.50
00.
38.08
2.75
12.00
2.00
12.33
12.05
6.53
1.00
0.68
0.18
0.13
1.78
0.80
3.58
4.25
0.20
9.70
86.18 ISOMERS OF HEXANE
100.21 ISOMERS OF HEPTANE
114.23 ISOMERS OF OCTANE
98.19 C-7 CYCLOPARAFFINS
112.23 C-8 CYCLOPARAFFINS
86.18 HEXANE
100.21 HEPTANE
114.23 OCTANE
70.14 CYCLOPENTANE
84.16 CYCLOHEXANE
84.16 METHYLCYCLOPENTANE
92.15 TOLUENE
78.12 BENZENE
.00 K0148(25X),K0156(25X),402006C(25X>
114.00 MINERAL SPIRITS
106.16 XYLENE
92.13 TOLUENE
98.15 CYCLOHEXANONE
58.08 ACETONE
72.10 METHYL ETHLY ICETONE
60.09 ISO-PROPYL ALCOHOL
140.00 METHYL AHYL ACETATE
100.16 METHYL ISOBUTYL ICETONE
32.04 METHYL ALCOHOL
46.07 ETHYL ALCOHOL
74.12 N-BUTYL ALCOHOL
88.10 ETHYL ACETATE
116.16 N-BUTYL ACETATE
104.00 ISOPROPYL ACETATE
114.23 OCTANE
84.16 CYCLOHEXANE
493
503
513
523
533
543
553
563
573
583
593
603
613
623
633
643
2
13
23
33
43
53
63
73
83
93
103
113
123
133
,402007B(25X) 2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
00.00 12. 5X OF K0148;402004DSE;K0134,56;K0162,4;K0092 2
31.24
2.57
2.86
1.00
4.76
5.54
3.88
0.48
0.78
2.73
0.28
114.00 MINERAL SPIRITS
106.17 XYLENE
92.15 TOLUENE
98.19 CYCLOHEXANONE
58.08 ACETONE
72.10 METHYL ETHYL KETONE
60.09 ISOOPROPYL ALCOHOL
140.00 METHYL AMYL ACETATE
72.15 N-PENTANE
114.00 NAPTHA
42.08 PROPYLENE
13
23
33
43
53
63
73
83
93
110
113
E-45
-------
TABLE E-4 (continued)
180C:X0010
1801:X0010
1B02:X0010
1803:X0010
1S04:X0010
1805:X0010
1806:X0010
1807.-X0010
1808:X0010
1809:X0010
1810:X0010
1811:X0010
1812-.X0010
1813:X0010
1814:X0010
1815:X0010
1816:X0010
1817:X0011
1818.-XQ011
1819:X0011
1820:X0011
1821:X0011
1822:X0011
1823:X0011
1824:X0011
1825:X001t
1S26:X0011
1827:X0011
1828:X0011
1829.-X0011
1830:X0011
1831:X0011
1832:X0011
1B33.-X0011
1834:X0011
1835:X0011
1836:X0011
1837:X0011
1838:X0011
1839:X0011
1840:X0011
1841:X0011
1842:X0012
1843:X0012
1S44.-X0013
1845:X0013
1846-.X0013
1S47:XOQ13
1B48:X0013
1849:X0013
1850:X0013
1851:X0013
1852:X0013
1853:X0013
1854:X0013
1855:X0013
1856:X0013
1857:X0013
1S58:X0013
1859:
43500
43213
43301
43224
43302
43502
43305
43367
43*32
43433
43435
43444
43204
43212
43203
43201
43202
43204
43212
43201
43202
43302
43303
43304
43351
43433
43452
43203
4320S
43213
43224
43502
43118
45102
45202
43248
45106
45203
43301
43305
43435
43432
1.28
0.09
0.39
0.28
0.29
0.39
1.64
2.09
0.37
1.44
19.23
2.96
0.41
2.92
0.23
9.42
0.61
03.
1.71
0.14
11.44
3.43
6.80
17.76
2.39
0.13
2.16
0.20
0.29
4.80
1.94
1.70
3.11
31.00
1.14
3.71
1.43
1.00
0.86
0.86
0.86
1.14
00.
100.00
100.16
56.10
32.04
70.14
46.07
30.03
74.12
62.07
74.08
88.10
116.16
104.00
44.09
58.12
28.05
16.04
30.07
METHYL 1SOBUTYL KETONE
SUTENE
METHYL ALCOHOL
1-PENTENE
ETHYL ALCOHOL
FORMALDEHYDE
N-BUTYL ALCOHOL
GLYCOL ETHER
METHYL ACETATE
ETHYL ACETATE
N-BUTYL ACETATE
ISOPROPYL ACETATE
PROPANE
N-BUTANE
ETHYLEHE
METHANE
ETHANE
.11 14.3X OF IC0164,6;K>172,IC01B3,405004B,405005C
44.09
58.12
16.04
30.07
46.07
60.09
60.09
74.12
88.10
132.00
28.05
42.08
56.10
70.13
30.03
114.00
106.16
92.13
S4.16
134.21
106.16
32.04
74.12
116.16
PROPANE
N-BUTANE
METHANE
ETHANE
ETHYL ALCOHOL
N-PROPYL ALCOHOL
ISOPROPYL ALCOHOL
ETHYL ETHER
ETHYL ACETATE-
ACETIC ACID 2-ETHOXYETHYL ESTER
ETHYLENE
PROPYLENE
N-BUTANE
1-PENTENE
FORMALDEHYDE
MINERAL SPIRITS
XYLENE
TOLUENE
CYLCOHEXANE
ISOMERS OF DIETHYL8ENZEKE
ETHYLBENZENE
METHYL ALCOHOL
N-BUTYL ALCOHOL
N-BUTYL ACETATE
.00 X0012 METHYL ACETATE
74.08
MEWL ACETATE
00.00 X0013
43824
43814
43817
43802
43821
45201
45202
45102
43248
43551
43552
43305
43367
43105
21.07
22.31
7.44
4.13
4.13
0.96
3.58
1.65
0.14
1.38
1.11
0.69
0.83
30.58
131.40
133.42
165.83
84.94
187.30
78.12
92.15
106.17
84.16
58.08
72.10
74.12
62.07
86.18
TRICHLOROETHYLENE
1,1,1-TRICHLOROETKANE
PERCHLOROETHYLENE
METHYLENE CHLORIDE
TRICHLOROTRIFLUOROETHANE
BENZENE
TOLUENE
XYLENE
CYCLOHEXANE
ACETONE
METHYLETHYLKETONE
BUTANOL
GLYCOL ETHER
ISOMERS OF HEXANE
123
133
143
153
163
173
183
203
213
223
233
243
253
263
273
283
293
2
13
23
33
43
53
63
73
83
93
103
113
123
133
143
153
163
173
183
193
203
213
223
233
243
2
13
Z
13
23
33
43
53
63
73
83
93
103
113
123
133
143
E-46
-------
TABLE E-5. SPECIES/CLASS ASSIGNMENTS, 1980 NAPAP INVENTORY VERSION 5.2
Class
1
2
3
4
5
7
8
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
M.W.
16.04
30.07
44.09
58.12
58.12
72.15
72.15
133.42
133.42
98.97
88.12
100.21
132
26.04
118.17
98.19
112.23
126.26
331.67
90.12
132
119.39
84.16
70.14
42.08
120.91
84.94
46.07
64.52
74.12
45.09
44.05
99
62.07
62.07
62.07
116.16
74.12
144.21
142.29
170.33
100.21
86.18
128.26
114.23
212.41
72.15
198.38
184.36
156.32
Compound (Species) Name
METHANE
ETHANE
PROPANE
N- BUTANE
ISOBUTANE
N-PENTANE
ISOPENTANE
1,1,1, -TRI CHLOROETHANE
1,1, 2 -TRI CHLOROETHANE
1,1, D I CHLOROETHANE
1,4 DIOXANE
2,4, DIMETHYL PENTANE
2-ETHOXYETHYL ACETATE
ACETYLENE
BUTYL CELLOSOLVE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
CARBON TETRABROMIDE
CELLOSOLVE
CELLOSOLVE ACETATE
CHLOROFORM
CYCLOHEXANE
CYCLOPENTANE
CYCLOPROPANE
D I CHLOROD I FLUOROMETHANE
DICHLOROMETHANE
ETHYL ALCOHOL
ETHYL CHLORIDE
ETHYL ETHER
ETHYLAMINE
ETHYLENE OXIDE
ETHYLENE DICHLORIDE
ETHYLENE GLYCOL
GLYCOL
GLYCOL ETHER
ISOBUTYL ACETATE
ISOBUTYL ALCOHOL
ISOBUTYL ISOBUTYRATE
ISOMERS OF DECANE
ISOMERS OF DODECANE
ISOMERS OF HEPTANE
ISOMERS OF HEXANE
ISOMERS OF NONANE
ISOMERS OF OCTANE
ISOMERS OF PENTADECANE
ISOMERS OF PENTANE
ISOMERS OF TETRADECANE
ISOMERS OF TRIDECANE
ISOMERS OF UNDECANE
E-47
-------
TABLE E-5 (continued)
Class
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
10
11
13
15
15
15
15
15
15
M.W.
104
60.09
114
32.04
140
76.11
50.49
31.06
85
84.16
173.85
114
74.12
142.29
310.61
170.34
282.56
296.59
240.48
100.21
226.45
86.18
268.53
128.26
254.51
114.23
212.42
60.09
198.4
184.36
156.32
114
76
58.08
74.12
72.1
137.37
187.38
59.11
93.19
86
28.05
42.08
56.12
54.09
98.19
84.16
112.22
70.14
70.14
Compound (Species) Name
ISOPROPYL ACETATE
ISOPROPYL ALCOHOL
LACTOL SPIRITS
METHYL ALCOHOL
METHYL AMYL ACETATE
METHYL CELLOSOLVE
METHYL CHLORIDE
METHYLAMINE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
METHYLENE BROMIDE
MINERAL SPIRITS
N- BUTYL ALCOHOL
N-DECANE
N-DOCOSANE
N-DODECANE
N-EICOSANE
N-HENEICOSANE
N-HEPTADECANE
N- HEPTANE
N-HEXADECANE
N-HEXANE
N-NONADECANE
N-NONANE
N-OCTADECANE
N- OCTANE
N-PENTADECANE
N-PROPYL ALCOHOL
N-TETRADECANE
N-TRIDECANE
N-UNDECANE
NAPHTHA
PROPYLENE GLYCOL
PROPYLENE OXIDE
TERT- BUTYL ALCOHOL
TETRAHYDROFURAN
TRICHLORO - FLUOROMETHANE
TRI CHLOROTRIFLUOROMETHANE
TRIMETHYLAMINE
TRIMETHYLFLUOROSILANE
UNIDENTIFIED HYDROCARBONS
ETHYLENE
PROPYLENE
ISOBUTYLENE
1,3 -BUTADIENE
1-HEPTENE
1-HEXENE
1-OCTENE
1-PENTENE
2-METHYL.2-BUTENE
E-48
-------
TABLE E-5 (continued)
Class
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
16
17
18
18
18
19
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
21
22
24
24
25
26
M.W.
98.19
70.14
41.05
55.06
56.1
113.24
70.14
100.11
54.09
56.1
70.14
40.06
165.83
40.06
136.23
131.4
62.5
78.12
92.15
106.17
106.17
106.17
106.17
120.2
120.2
118.18
112.56
134.22
134.22
134.22
120.19
120.19
120.2
120.19
120.2
134.21
94.11
95.64
134.21
104.16
134.22
132
219.5
30.03
44.05
72.12
73.09
58.08
98.15
Compound (Species) Name
3,3 DIMETHYL, 1-PENTENE
3- METHYL- 1-BUTENE
ACETONITRILE
ACRYLONITRILE
BUTENE
C8 OLEFIN UNK
CIS, 2-PENTENE
ETHYL ACRYLATE
ETHYLACETYLENE
ISOMERS OF BUTENE
ISOMERS OF PENTENE
METHYLACETYLENE
PERCHLOROETHYLENE
PROPADIENE
TERPENES
TRICHLOROETHYLENE
VINYL CHLORIDE
BENZENE
TOLUENE
1,3 DIMETHYLBENZENE
ISOMERS OF XYLENE
ORTHO XYLENE
ETHYLBENZENE
1,2,3, -TRIMETHYLBENZENE
1,3,5- TRIMETHYLBENZENE
A-METHYLSTYRENE
CHLOROBENZENE
DIMETHYLETHYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF DIETHYLBENZENE
ISOMERS OF ETHYLTOLUENE
ISOMERS OF PROPYLBENZENE
ISOMERS OF TRIMETHYLBENZENE
ISOMERS OF TRIMETHYLBENZENE
M- ETHYLTOLUENE
N- BUTYLBENZENE
PHENOLS
PRIM. AND SEC-ALKYL BENZENES
SEC -BUTYLBENZENE
STYRENE
TERT - BUTYLBENZENE
TETRAMETHYLBENZENE
TRI/TETRAALKYL BENZENE
FORMALDEHYDE
ACETALDEHYDE
BUTYRALDEHYDE
DIMETHYLFORMAMIDE
ACETONE
CYCLOHEXANONE
E-49
-------
TABLE E-5 (continued)
Class M.W. Compound (Species) Name
26
26
26
26
28
29
29
29
29
29
116.16
72.1
100.16
100.16
60.05
88.1
74.08
116.16
102.13
230
DIACETONE ALCOHOL
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
METHYL N- BUTYL KETONE
ACETIC ACID
ETHYL ACETATE
METHYL ACETATE
N- BUTYL ACETATE
PROPYL ACETATE
XYLENE BASE ACIDS
E-50
-------
TABLE E-6. SPECIES-LEVEL ANALYSIS OF UNIT CONVERSION, SCC 301999
6-Digit SCC 301999
Speciation Profile K0079
THC (Tons/Year) 211348
Wt %
0.7
0.8
1
1.8
1.4
7.2
4.6
2.5
5.4
0.9
1.4
0.5
3
4.1
0.8
8.9
0.6
2
3.4
10
21.6
1.7
1.3
9
4.1
1.3
Weighted
26.7
17.4
5.4
MW Compound (Species)
44.05 Acetaldehyde
72.12 Butyraldehyde
26 . 04 Acetylene
84.16 Cy c 1 ohexane
46.07 Ethyl Alcohol
64.52 Ethyl chloride
44.05 Ethylene oxide
60.09 Isopropyl Alcohol
32.04 Methyl Alcohol
50.49 Methyl chloride
58.08 Propylene oxide
74.12 n-Butyl Alcohol
55.06 Acrylonitrile
56.1 Butene
100.11 Ethyl acrylate
56.1 Isomers of Butene
62.5 Vinyl chloride
94.11 Phenols
104.16 Styrene
78.12 Benzene
28.05 Ethylene
30.03 Formaldehyde
230 Xylene base acids
42.08 Propylene
92.15 Toluene
106.17 Isomers of Xylene
average molecular weights
47.26
57.27
100.20
Class
Acetalde
Aldehyde
Alkane
Alkane
Alkane
Alkane
Alkane
Alkane
Alkane
Alkane
Alkane
Alkane
Alkene
Alkene
Alkene
Alkene
Alkene
Aromatic
Aromatic
Benzene
Ethylene
Forma Ide
Org Acid
Propylen
Toluene
Xylene
Weight
Fraction
0.007
0.008
0.010
0.018
0.014
0.072
0.046
0.025
0.054
0.009
0.014
0.005
0.030
0.041
0.008
0.089
0.006
0.020
0.034
0.100
0.216
0.017
0.013
0.090
0.041
0.013
for multicomponent
Alkane
Alkene
Aromatic
0.267
0.174
0.054
CALC
TONS/YR
1,479
1,691
2,113
3,804
2,959
15,217
9,722
5,284
11,413
1,902
2,959
1,057
6,340
8,665
1,691
18,810
1,268
4,227
7,186
21,135
45,651
3,593
2,748
19,021
8,665
2,748
classes :
56,430
36,775
11,413
CALC
1000-MOLE/YR
30,469
21,268
73,631
41,008
58,265
213,963
200,223
79,770
323,149
34,177
46,217
12,934
104,469
140,127
15,322
304,178
18,407
40,747
62,586
245,436
1,476,461
108,541
10,837
410,079
85,308
23,477
1,083,337
582,503
103,333
E-51
-------
TABLE E-7. CLASS-LEVEL ANALYSIS OF UNIT CONVERSION, SCC 301999
6-Digit SCC
Speciation Profile
THC (Tons /Year)
Class
Acetaldehyde
Aldehyde
Alkane
Alkene
Aromatic
Benzene
Ethylene
Formaldehyde
Org Acids
Propylene
Toluene
Xylene
301999
K0079
211348
1000 -MOL
/YR
30,469
21,268
1,083,337
582,503
103,333
245,436
1,476,461
108,541
10,837
410,079
85,308
23,477
AVG
MOL WT
44.05
72.61
121.79
80.41
126.14
78.12
28.05
30.03
122.09
42.08
92.15
106.17
KNOWN
TONS/YR
1,479
1,691
56,430
36,775
11,413
21,135
45,651
3,593
2,748
19,021
8,665
2,748
CALC
TONS/YR
1,479
1,702
145,436
51,630
14,368
21,135
45,651
3,593
1,458
19,021
8,665
2,748
ERROR
(%)
0%
1%
158%
40%
26%
0%
0%
0%
-47%
0%
0%
0%
Calculated THC
4,181,051
211,349 316,887
50%
------- |